A 600/R-12/624 September 2012 | www.epa.gov/ord
United States
Environmental Protection
Agency
Interlaboratory Validation of the Leaching Environmental
Assessment Framework (LEAF) Method 1314 and Method
1315
Office of Research and Development
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EPA-600/R-12/624
September 2012
Interlaboratory Validation of the Leaching Environmental
Assessment Framework (LEAF) Method 1314 and Method 1315
Andrew C. Garrabrants1, David S. Kosson1, Rossane DeLapp1, Peter Kariher2,
Paul F.A.B. Seignette3, Hans A. van der Sloot4, Leonard Stefanski5, and Mark Baldwin6
1 Vanderbilt University
Civil and Environmental Engineering
Nashville, TN 37235
2 ARCADIS-US, Inc.
Research Triangle Park, NC 27711
3 Energy Research Centre of the Netherlands
Biomass, Coal and Environmental Research
1755 ZG Petten, the Netherlands
4 Hans van der Sloot Consultancy
1721 BV Langedijk, the Netherlands
5 North Carolina State University
Department of Statistics
Raleigh, NC 27695
6 U.S. Environmental Protection Agency
Office of Solid Waste and Emergency Response
Washington, DC 20460
Category III / Applied Research
Contract No. EP-C-09-027
Work Assignment No. 2-07
Prepared for
Susan A. Thorneloe
U.S. Environmental Protection Agency
Office of Research and Development
National Risk Management Research Laboratory
Air Pollution Prevention and Control Division
Research Triangle Park, NC 27711
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Notice
The U.S. Environmental Protection Agency through its
Office of Research and Development partially funded
and managed the research described here under
Contract Number EP-C-09-27 coordinated by
ARCADIS-US, Inc. This report has been subjected to
the Agency's peer and administrative review and has
been approved for publication as an EPA document.
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ACKNOWLEDGMENTS
This interlaboratory validation study was conducted under the United States Environmental Protection
Agency (EPA) Contract Number EP-C-09-27 coordinated by ARCADIS-US, Inc. (ARCADIS).
Completion of the validation study was a collaborative effort of the Organization Team - ARCADIS,
Vanderbilt University (VU), EPA Office of Solid Waste and Emergency Response (OSWER) and EPA
Office of Research and Development (ORD) - and the participating validation laboratories. Partial
financial support was provided by the U.S. Department of Energy, Office of Environmental Management
under Cooperative Agreement Number DE-FC01-06W07053 entitled 'The Consortium for Risk
Evaluation with Stakeholder Participation IIP awarded to Vanderbilt University.
Material preparation and distribution were carried out jointly by ARCADIS and VU. All chemical
analyses of eluate solutions were conducted at VU. Data assessment and reporting were conducted at VU
with review of final documentation by the Organization Team. Development and review of statistical
approaches were carried out at North Carolina State University.
The authors gratefully acknowledge the following laboratories and contact leads for donating time, effort,
and support as participating laboratories in the validation study:
Energy Research Centre of the Netherlands, Petten, the Netherlands (Rob Comans)
Oak Ridge National Laboratory, Oak Ridge, TN (Catherine Mattus)
The Ohio State University, Columbus, OH (Zuzana Bohrerova)
Pacific Northwest National Laboratory, Richland, WA (Michelle Valenta)
Savannah River National Laboratory, Aiken, SC (Charles Crawford)
The University of North Carolina, Charlotte, NC (John Daniels and Jenet Hattaway)
The University of Wisconsin, Madison, WI (James Tinjum)
URS Corporation, Inc., Austin, TX (Mandi Richardson)
The authors also thank Greg Helms (EPA OSWER), Richard Benware (EPA OSWER), and Susan
Thorneloe (EPA ORD) for guidance and significant contributions to the success of this program.
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ABSTRACT
This document summarizes the results of an interlaboratory study conducted to generate precision
estimates for two leaching methods, part of the Leaching Environmental Assessment Framework (LEAF)
and under review by the U.S. Environmental Protection Agency (EPA) Office of Solid Waste and
Emergency Response for potential inclusion into the EPA's Test Methods for Evaluating Solid Waste,
Physical/Chemical Methods (SW-846):
• Method 1314: Liquid-Solid Partitioning as a Function of Liquid-solid Ratio using an Up-flow
Percolation Column Procedure, and
• Method 1315: Mass Transfer Rates in Monolithic and Compacted Granular Materials using a
Semi-dynamic Tank Leaching Procedure.
For each of the test methods, method repeatability and reproducibility were based on results for study
materials selected to represent materials likely to be tested by these methods. A minimum of seven
laboratories participated in the interlaboratory validation study for each material. Method precision was
evaluated using repeatability relative standard deviation (RSDr) and reproducibility relative standard
deviation (RSDR).
The results of the validation study showed that Method 1314 cumulative release values are expected to
fall within 6% RSDr for single operator replicates and within 16% RSDR for multiple laboratory results.
Method 1314 precision for eluate concentrations was approximately twice of the precision for cumulative
release. The validation study for Method 1315 indicated that the mean interval flux values for single
operator replicates are expected within a variance of 12% RSDr while multi-laboratory results would be
expected within 30% RSDR. For Method 1315 cumulative release, precision estimates indicated that
results were within 8% for repeatability and within 21% reproducibility of the measured mean values.
For both Method 1314 and Method 1315, the distribution of reproducibility estimates for individual
analytes was considerably better than the reproducibility distribution reported for batch extraction test, the
Toxicity Characteristic Leaching Procedure (TCLP; SW-846 Method 1311).
In parallel, study materials were tested using analogous European leaching methods or technical
specifications (TSs) in the process of standardization through the Comite Europeen de Normalisation
(CEN). Comparison of results for the analogous European methods showed that CEN/TS 14415 column
test compares favorably to Method 1314. The Dutch monolith leaching test, NEN 7375, was shown to
agree to a large extent with Method 1315; while CEN/TS 15863 monolithic leaching results indicated
minor differences in the cumulative release of antimony, selenium and vanadium. Overall, the precision
estimates and favorable comparison to analogous EU leaching methods provide confidence that Method
1314 and Method 1315 provide data describing the characteristic leaching behavior that is intended by the
LEAF methods with a high degree of precision.
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EXECUTIVE SUMMARY
The potential impact to the environment from disposal or other forms of land placement for a solid
material has traditionally been determined from the results of one or more leaching tests. Currently, the
Toxicity Characteristic Leaching Procedure (TCLP; EPA, 1992a) is the leaching test promulgated by the
United States Environmental Protection Agency (EPA) for classification of wastes and for identification
of materials considered "hazardous" to the environment under the Resource Conservation and Recovery
Act (RCRA). TCLP simulates leaching under a plausible worst-case mismanagement scenario of co-
disposal of the test material with municipal solid waste. While a worst-case simulation test has merits for
classification purposes, simulation-based leaching approaches inherently limit the usefulness of the test
results to specific scenarios, waste materials, and disposal or use applications. A more flexible and robust
leaching assessment methodology could provide EPA and the waste management community with a
uniform basis for leaching characterization that is more broadly applicable to a wide range of waste types
and release scenarios. To this end, the EPA Office of Solid Waste and Emergency Response (OSWER)
has initiated further maturation of the leaching test methods contained within the Leaching Environmental
Assessment Framework (LEAF) based on a tier-testing approach (Kosson et al., 2002). The LEAF
methods are under consideration by OSWER for potential inclusion in EPA's compendium of laboratory
methods, Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, also known as SW-846.
Instead of simulating a particular release scenario, the LEAF methods challenge a solid material to a
broad range of leaching conditions that may plausibly occur during the course of waste management and
focus on a select set of key parameters considered to largely control the liquid-solid partitioning (LSP)
and the mass transport of constituents from most solid materials. The LEAF approach (i.e., test methods,
data management tools and leaching assessment methodologies) has been developed as a collaborative
effort between Vanderbilt University (VU), the Energy Research Centre of the Netherlands (ECN) and
DHI Denmark (DHI) with additional support and guidance from ARCADIS-US, Inc. (ARCADIS) and
EPA Office of Research and Development (ORD) and the EPA Office of Solid Waste and Emergency
Response (OSWER). LEAF provides considerable flexibility for environmental assessment in that no
specific leaching scenario is imposed. The LEAF methods rather focus on intrinsic leaching
characteristics and a range of conditions that affect leaching and vary in the disposal environment.
Therefore, the results of LEAF testing may be applied to specific release conditions or used to compare
multiple scenarios representing a range of plausible management options.
As part of the review for SW-846, documentation is required regarding the precision (i.e., repeatability
and reproducibility) of the methods for various types of potential waste materials. These precision data
are intended to provide perspective on the variation in test method results that may be anticipated (i) when
a single laboratory performs replicate testing of the method on the same homogeneous material sample
(i.e., repeatability), or (ii) when multiple laboratories perform the method on replicate samples of a single
material (i.e., reproducibility). In addition, the precision data support the development of guidance on the
use of the method and can be used to establish criteria for acceptable laboratory performance when using
the method.
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This report summarizes the results of an interlaboratory method validation study for two of the four LEAF
leaching methods::
• Method 1314: Liquid-Solid Partitioning as a Function of Liquid-solid Ratio using an Up-flow
Percolation Column Procedure, and
• Method 1315: Mass Transfer Rates in Monolithic and Compacted Granular Materials using a
Semi-dynamic Tank Leaching Procedure.
The objectives of the interlaboratory validation study were to determine the method precision, i.e.,
repeatability and reproducibility, for each of the two evaluated LEAF methods and to compare these
precision statistics to the results of analogous leaching tests under development for adoption within the
European Union (EU).
Method 1314 is a percolation column test designed to evaluate the release of constituents from solid
materials as a function of cumulative liquid-to-solid ratio (L/S). During Method 1314, fractions of a
continuous elution of water through a packed bed of granular material are collected at nine specified L/S
values. The concentrations of constituents in the collected eluates2 are used to derive the cumulative mass
release from the column. Both eluate concentration and cumulative release are reported as a function of
L/S and may be used as test outputs for assessment purposes. Method 1315 is a semi-dynamic tank
leaching procedure used to determine the rate of mass transport from monolithic materials (e.g., concrete
materials, bricks, tiles) and compacted granular materials (e.g., soils, sediments, fly ash) as a function of
time. Test samples are leached in a series of nine deionized water tanks for specified interval durations.
Although the direct method result is eluate concentrations, the test outputs for Method 1315 include the
mean interval flux during each test interval and the cumulative mass released through the end of a
leaching interval as derived from the eluate concentration and other test information.
The structure of the validation study followed the validation approaches recommended by EPA's
Guidance for Methods Development and Methods Validation for the RCRA Program (EPA, 1992b) and
ASTM International's E691 Standard Practice for Conducting an Interlaboratory Study to Determine the
Precision of a Test Method (ASTM, 1987). ARCADIS provided project management for the validation
study and distributed study materials and equipment kits to the participating laboratories. VU served as
the validation reference laboratory due to considerable experience with the development of the LEAF
methods. The minimum guidelines for the validation study were to provide for testing of two study
materials by at least six participating laboratories. Recognizing that participating laboratories would
donate time and support for the project and a certain level of attrition would be anticipated, additional
laboratories were targeted to provide for a minimum of six laboratories completing any phase of the
validation study. Each laboratory was asked to provide filtered and preserved analytical samples to VU
and to complete a laboratory data template provided to the laboratory prior to testing. Chemical analysis
of all analytical samples was conducted at VU using inductively coupled plasma-optical emission
spectrometry (ICP-OES) following EPA Method 6010 (EPA, 2007b). Analysis at a single facility was
1 Although the LEAF methods are numbered in a manner consistent with SW-846, these methods are currently considered
Preliminary Versions of EPA Methods that have not yet been endorsed by EPA pending method validation and final review.
2 This report follows the LEAF terminology where "eluate" is used to refer to the solution resulting from a leaching test and
"leachate" is used to refer to the solution collected from or measured in the field. The distinction is made within LEAF to
minimize confusion when comparing laboratory leaching test data to field leaching data.
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considered to minimize variation in test results due to different analytical techniques and operators. The
study design as well as all material handling approaches and analytical procedures with data quality
indicator (DQI) goals were written into a Quality Assurance Project Plan (QAPP) that was signed and
approved by quality assurance representatives of ARCADIS and the EPA.
For each method (Method 1314 and Method 1315), two study materials were chosen for the validation to
represent a selection of EPA-relevant material types. For Method 1314, these materials included
contaminated soil from a smelter facility (material code CFS) and spent casting sand from a brass foundry
(material code JaFS). For Method 1315, study materials included monolithic samples of solidified waste
analog (material code SWA) and the compacted granular samples of the aforementioned CFS material.
Prior to distribution to the participating laboratories, these materials were prepared and homogenized at
either ARCADIS (CFS and JaFS) or VU (SWA). The total contents of major, minor, and trace
constituents in each of study materials were determined by ARCADIS and VU using X-ray fluorescence
spectrometry (XRFS) and acid digestion following EPA Methods 3052 (EPA, 1996) and 3051 (EPA,
2007a) combined with ICP-OES analysis of digested solutions. XRFS results for a minimum of three
subsamples of study material were used to assess homogeneity of the samples prior to distribution. The
precision of the XRFS results for total content analysis were sufficient to conclude that all study materials
were considered sufficiently homogeneous prior to distribution to the participating laboratories.
Participating laboratories were asked to prepare analytical samples (e.g., filtered and preserved eluate
solutions) for each test method using the two study materials. Analytical samples were shipped by the
participating laboratories to VU for chemical analysis. Method 1314 validation was conducted with
seven participating laboratories due to the project costs associated with providing columns and pumps as
part of the validation equipment kits. All seven laboratories provided analytical samples for both Method
1314 study materials. For the validation of Method 1315, ten laboratories were asked to participate for
each testing of two study materials. All ten laboratories returned analytical samples for the SWA
material; however, due to financial and time commitments, only eight laboratories were able to provide
samples for the second material. As part of participation, laboratories were asked to record all laboratory
data (e.g., masses, collection times, etc.) in method data templates in the form of Microsoft Excel
spreadsheets provided to the laboratories. Filtered and preserved eluate solutions from leaching tests
carried out at participating laboratories were shipped to VU for chemical analysis. Data management and
analysis of this large data set was conducted using LeachXS™, a software program developed by VU,
ECN and DHI specifically for data management, visualization, and modeling of leaching data.
Preserved analytical samples generated by the participating laboratories were shipped to VU where eluate
concentrations were determined by ICP-OES following standard quality assurance/quality control
procedures as specified in the QAPP, including calibration checks, blanks and analytical spikes. Using
the eluate concentrations determined from ICP-OES analysis of the reference laboratory samples, ten
inorganic analytes from each material were selected for processing to generate statistical parameters and
precision measurements. The list of selected constituents differed based on the leaching behavior of each
material, but included eight analytes common to study materials for each method. The common analytes
for the Method 1314 included aluminum, barium, boron, calcium, copper, molybdenum, lead, thallium
and zinc, while common analytes for the Method 1315 validation included aluminum, antimony, barium,
boron, calcium, lead, potassium, selenium and vanadium. In all, the DQI values achieved in eluate
solution analysis were considerably better than the DQI goals established in the QAPP and provided
confidence that the measured eluate concentrations were valid within an analytical uncertainty of about
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5%. Method blanks (i.e., extract solutions without solid material that follow through the leaching test
procedure) were checked for potential sources of contamination during testing. For nearly all of the
selected analytes, method blank concentrations were below the minimum level of quantitation (ML) for
ICP-OES established by VU following guidance established by the EPA Office of Water (EPA, 2003).3
For those method blanks with concentrations above the ML, method blank concentrations were less than
20% of the eluate concentration in the associated test fraction and were not considered to affect measured
eluate concentration values.
For each method, test outputs (i.e., eluate concentration and cumulative mass release for Method 1314 or
mean interval flux and cumulative mass release for Method 1315) were Iogi0-transformed and linearly
interpolated/extrapolated to specified L/S or time values to yield a set of data used for statistical analysis.
Statistical analysis included generation of (i) means and standard deviations at each target L/S or time
value as specified in the methods, (ii) 95% prediction limits (PLs) about the mean of the reference
laboratory data, (iii) 95% robust confidence limits (RCLs) about the median of the laboratory means, and
(iv) estimates of repeatability and reproducibility expressed as the repeatability relative standard deviation
(RSDr) and reproducibility relative standard deviation (RSDR). Prediction limits and robust confidence
intervals, respectively, showed the ranges of leaching concentrations that would capture 95% of the data
for the reference laboratory performing replicate tests and for additional laboratories testing the same
material.
The mean Method 1314 repeatability values were determined to be 12% RSDr and 6% RSDr for eluate
concentration and cumulative mass release, respectively. These results indicate that a single operator
should be able to obtain replicate concentration results within 12% (i.e., the measure value ± 12%) and
replicate cumulative mass release results within 6%. The mean reproducibility of Method 1314 was 24%
RSDR for eluate concentration and 16% RSDR for cumulative mass release, meaning that the results of
Method 1314 testing on the same material at different laboratories would be expected to be within 24%
for eluate concentration and 26% RSDR for cumulative mass release. While these precision values appear
to be very good, no criteria are provided in EPA or ASTM guidance for acceptable precision of a test
method. Therefore, the distributions of Method 1314 precision values for ten selected analytes in each of
two study materials were placed into the context of reported precision for accepted standard methods, the
German column test, DIN 15928 (DIN, 2009), the current EPA regulatory leaching test, TCLP (EPA,
1992a). The distributions of RSDr and RSDR values for Method 1314 were shown to be consistent with
those of DIN 15928 and considerably better than the distribution of reproducibility reported for TCLP.
For Method 1315, the mean repeatability was determined to be 12% RSDr for mean interval flux and 8%
RSDr for cumulative release, indicating that single operator replicate results would be expected to fall
12% and 8% for interval flux and cumulative release, respectively. The reproducibility of Method 1315
was determined to be 30% RSDR for mean interval flux and 21% RSDR for cumulative release. These
3 The analytical data quality indicators for this report are based on the guidelines established by the EPA Office of Water and
include establishing a method detection limit (MDL) and minimum level of quantitation (ML) based on standard deviation of
seven non-consecutive analyses of a low-concentration standard analytical solution. However, the EPA Office of Resource
Conservation and Recovery (ORCR) has recommended that practitioners establish a lower limit of quantitation (LLOQ) for
analytes of concern as a demonstration of quantitation capability at low analyte concentration levels. The LLOQ demonstration
is a performance-based validation of recovery from a spiked analytical solution typically at concentration levels approximating
the lowest calibration standard.
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results suggest that Method 1315 testing of the same material conducted at different laboratories would
result in mean interval flux results within 30% and cumulative release results within 21%. When
cumulative release precision was evaluated after 14 days of leaching, precision values compared
favorably to the reported precision for 16-day release from NEN 7345, a Dutch standard monolithic
leaching test. The distribution of precision values was consistent with the precision for NEN 7345 found
in a European Commission validation study (van der Sloot et al., 1995). For both Method 1314 and
Method 1315, the distributions of reproducibility for individual analytes were considerably better than the
reproducibility distribution reported for TCLP used in regulatory determinations for identifying if a waste
is classified as hazardous (EPA, 1992a). Therefore, Method 1314 and Method 1315 can be performed
with the same precision as or better precision than other currently active standardized leaching
procedures.
In parallel to participating in the LEAF validation, the Energy Centre of the Netherlands (ECN) used the
study material to conduct a column test and two mass transfer tests commonly used in Europe. These
tests represent leaching approaches analogous to the LEAF methods that are currently adopted or under
development within the EU as Dutch national standards (NEN labeled tests) or technical specifications
(TSs) developed by the Comite Europeen de Normalisation (CEN).4 The cumulative mass release results
of the CEN/TS 14405 (CEN, 2004) column test compared favorably to the reproducibility limit interval
about the mean of the Method 1314 validation data indicating little to no difference in the output of these
tests. For the mass transfer tests, the cumulative mass release from NEN 7375 (NEN, 2004) and CEN/TS
15863 (CEN, 2009) were found to be consistent with the Method 1315 validation results for most
analytes. Minor differences in CEN/TS 15863 results were observed for antimony, selenium and
vanadium. Overall, the precision estimates and favorable comparisons to analogous EU leaching methods
provide confidence that Method 1314 and Method 1315 provide data describing the characteristic
leaching behavior that is intended by the LEAF leaching methods with a high degree of precision.
4 The "TS" designation within CEN denotes a method that has resulted from a multi-national consensus process and has been
approved by a CEN technical committee, but has not yet completed interlaboratory validation studies. Once method precision
has been established, the method will require public comment and consensus approval by CEN member to be designated as a full
European standard (EN). Although the TS designation does not carry the status of an EN, TS methods may be adopted as
national standards and written into regulation.
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ABBREVIATIONS
ANOVA Analysis of Variance
CEN Comite European de Normalisation (European Committee for Standardization)
CFS contaminated field soil (material code for validation study material)
CV(s) coefficient(s) of variation [%]
df degrees of freedom
DHI DHI, Hersholm, Denmark
DIG dissolved inorganic carbon
DIN Deutsches Institut fur Normung (German Institute for Standardization)
DOC dissolved organic carbon
DQI(s) data quality indicator(s)
ECN Energy Research Centre of the Netherlands, Petten, the Netherlands
EN European standard test method
EPA United States Environmental Protection Agency
EU European Union
HOPE high-density polyethylene
1C ion chromatography
ICP-MS inductively coupled plasma-mass spectrometry
ICP-OES inductively coupled plasma-optical emission spectroscopy
IQR interquartile range
ISO International Organization for Standardization
JaFS brass foundry sand (material code for validation study material)
LEAF Leaching Environmental Assessment Framework
L/S cumulative liquid-to-solid ratio [L/kg, dry basis]
L/Si liquid-to-solid ratio through end of interval or test fraction /' [mL/g, dry basis]
LSP liquid-solid partitioning
M median of laboratory means
MAD median absolute deviation
MDL method detection limit
ML minimum level of quantitation
NEN Netherlands standard test method
ORD Office of Research and Development (EPA)
ORP oxidation-reduction potential [mV]
OSWER Office of Solid Waste and Emergency Response (EPA)
ORCR Office of Resource Conservation and Recovery (EPA)
PL(s) prediction limit(s)
QAPP quality assurance project plan
QA/QC quality assurance/quality control
R reproducibility limit
RCL(s) robust confidence limit(s)
RCRA Resource Conservation and Recovery Act
RL reproducibility limit interval above or below the mean
RSD(s) relative standard deviation(s)
RSDr repeatability relative standard deviation [%]
RSDR reproducibility relative standard deviation [%]
SL standard deviation associated with between laboratory variance
sr standard deviation associated with repeatability
SR standard deviation associated with reproducibility
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SWA solidified waste analog (material code for validation study material)
SW-846 EPA's compendium, "Test Methods for Evaluating Solid Waste, Physical/Chemical Methods"
T cumulative leaching time [sec]
T; cumulative leaching time through end of interval or test fraction /' [sec]
t Student's / value required for the level of confidence and the appropriate number of degrees of
freedom
TC toxicity characteristic (as defined under RCRA)
TCLP toxicity characteristic leaching procedure
TS(s) technical specifications)
VU Vanderbilt University
XRFS X-ray fluorescence spectrometry
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TABLE OF CONTENTS
Acknowledgments iii
Abstract iv
Executive Summary v
Abbreviations x
List of Figures xv
List of Tables xvi
Introduction 1
Study Objectives 3
Method Descriptions 3
Method 1314: Liquid-Solid Partitioning as a Function of Liquid-Solid Ratio using an Up-
Flow Percolation Column Procedure 3
Method 1315: Mass Transfer Rates in Monolithic and Compacted Granular Materials using a
Semi-dynamic Tank Leaching Procedure 4
Data Management with LeachXS Lite™ 5
Validation Study Overview 5
Project Organization 6
Selection of Participating Laboratories 6
Laboratory Participation 7
Chemical Analysis and Data Management 7
Calculation of Precision Statistics 7
95% Prediction Limits (PLs) 7
95% Robust Confidence Limits (RCLs) 8
Standard Deviations about the Mean 8
Coefficient of Variation (CVs) 8
Relative Standard Deviations 8
Study Materials 8
Total Elemental Contents 9
Solidified Waste Analog 10
Contaminated Field Soil 10
Brass Foundry Sand 11
Analytical Methods 11
Supplemental Analysis for Reference Laboratory Eluates 12
Inductively Coupled Plasma - Mass Spectroscopy 12
Ion Chromatography 13
Total Carbon Analysis 13
Data Processing Methods 14
Method Blank Analysis and Data Filtering 14
Analyte Selection 14
Data Transformation and Linear Interpolation/Extrapolation to Target Values 15
Statistical Calculations 17
95% Prediction Limits (PLs) Based on Reference Laboratory Results 17
95% Robust Confidence Limits (RCLs) based on the Median of Laboratory Mean Data 17
Estimates of Variance Components and Standard Deviations 19
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Preliminary Calculations and Example ANOVA Table 19
Variance Components and Standard Deviations 20
Repeatability and Reproducibility 21
Reproducibility Limit 21
Application of Statistical Approach for Cumulative Results 22
QA/QC Summary 22
Homogeneity of Study Materials 22
Analytical QA/QC 23
Method Blank Analysis and Data Filtering 24
Filtering due to Method Blanks 25
Data Filtering for Cause 25
Method 1314 Results and Analysis 25
Evolution of pH from the Column 26
Eluate Concentrations and Cumulative Release 27
Consistency Check for LSP Data 27
Statistical Analysis of L/S-dependent Leaching 30
Linear Interpolation oflog10-TransformedData 32
Prediction Limit and Robust Confidence Limits 33
Standard Deviations Intervals and Coefficients of Variation 36
Method 1314 Repeatability and Reproducibility 39
Method 1314 Precision Data 39
RSDR (%) at Target L/S Value (mL/g-dry) 42
Overall Method 1314 Precision 45
Method 1314 Precision Compared to Other Leaching Method Validations 47
DIN 19528 Repeatability and Reproducibility 47
TCLP (SW-846Method 1311) Reproducibility 47
Comparison of Precision Distributions 47
Comparison of Method 1314 Statistics to Results of EU Tests 49
Description of CEN/TS 14405 Procedure 49
Comparison of EU Test Results to Method 1314 Statistics 49
Method 1315 Results and Analysis 53
Evolution of pH in Eluate from the Monolith and Compacted Granular Material 53
Collected Eluate Concentration Data 54
Consistency Check for Saturated Eluates 57
Interval Flux and Cumulative Release 59
Statistical Analysis of Method 1315 Output 59
Linear Interpolation ofloglO-transformedData 62
Prediction Limit and Robust Confidence Limits 62
Standard Deviation Intervals and Coefficients of Variation 66
Method 1315 Repeatability and Reproducibility 69
Method 1315 Precision Data 69
Overall Method 1315 Precision 75
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Method 1315 Precision Compared to Other Leaching Method Validations 77
NEN 7345 Repeatability and Reproducibility 77
TCLP(SW-846 Method 1311) Reproducibility 77
Comparison of Precision Distributions 77
Comparison of Method 1315 Statistics to Results of EU Tests 79
Description of NEN 7375 Procedure 79
Description of CEN/TS 15863 Procedure 79
Comparison of EU Test Results to Method 1315 Statistics 80
Influence of Sample Aging 82
Summary and Conclusions 84
Procedural Considerations 85
Repeatability and Reproducibility 86
References 87
List of Appendices
Appendix A. Method 1314
Appendix B. Method 1315
Appendix C. Quality Assurance Project Plan
Appendix D. Blank Analysis and Data Filtering
Appendix E. Method 1314 Results and Precision Estimates
Appendix F. Method 1315 Results and Precision Estimates
Appendix G. Comparison of EU Leaching Tests to LEAF Method Statistics
Appendix H. Summary of Analytical QA/QC for Selected Analytes
Appendix I. Detailed QA/QC Reports for ICP-OES Analytes5
Appendix I contains all of the details of the ICP-OES analysis and QA/QC results for each measured constituent in each
provided analytical solution (i.e., filtered and preserved eluate sample). Therefore, due to its size, the appendix is made available
electronically by request to the authors, through the link to the document page on the EPA website, or as a download at
http: //vanderbilt. edu/leaching.
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LIST OF FIGURES
Figure 1. Evolution of eluate pH from Method 1314 testing of validation study materials 26
Figure 2. Consistency check between Method 1314 data and LSP statistics from Method 1313 29
Figure 3. Example Method 1314 data presentation for boron eluate concentration in CFS material 31
Figure 4. Linear interpolation of logic-transformed eluate concentration data 32
Figure 5. Method 1314 95% prediction limits (95% PL) for eluate concentration from reference
laboratory results and 95% robust confidence limits (95% RCL) of all eluate concentrations. 34
Figure 6. Method 1314 95% prediction limits (PL) for cumulative release from reference laboratory
results and 95% robust confidence limits (RCL) of all cumulative release results 35
Figure 7. Example of Method 1314 variance component estimates and coefficients of variation for
eluate concentration 37
Figure 8. Example of Method 1314 variance component estimates and coefficients of variation for
cumulative release 38
Figure 9. Comparisons of statistical analyses for barium from Method 1314 validation study materials.40
Figure 10. Illustration of scenarios used to summarize precision for Method 1314 eluate concentration
(left) and cumulative release (right) 45
Figure 11. Distribution of Method 1314 repeatability (RSDr) and reproducibility (RSDR) by study
material compared to precision estimates reported for DIN 19528 and TCLP 48
Figure 12. CEN/TS 14405 cumulative release compared to the Method 1314 statistics 51
Figure 13. CEN/TS 14405 cumulative release compared to the Method 1314 statistics 52
Figure 14. pH evolution in Method 1315 53
Figure 15. Example collected eluate concentration results from Method 1315 testing of SWA material. 55
Figure 16. Example collected eluate concentration results from Method 1315 testing of CFS material... 56
Figure 17. Consistency check between M1315 eluate concentrations and M1313 statistics 58
Figure 18. Method 1315 data presentation for antimony interval flux for material SWA 61
Figure 19. Linear interpolation of Iogi0-transformed interval flux data 62
Figure 20. Method 1315 95% prediction limits (95% PLs) for mean interval flux from reference
laboratory results and 95% robust confidence limits (95%RCLs) of all laboratories for
interval flux 64
Figure 21. Method 1315 95% prediction limits (95% PLs) for cumulative release from reference
laboratory results and 95% robust confidence limits (95% RCLs) of all laboratories for
cumulative release 65
Figure 22. Example of Method 1315 variance component estimates and coefficients of variation for
mean interval flux 67
Figure 23. Example of Method 1315 variance component estimates and coefficients of variation for
cumulative release 68
Figure 24. Comparisons of statistical analyses for selenium from Method 1315 validation study
materials 70
Figure 25. Illustration of scenarios used to summarize precision for Method 1315: (A) mean interval
flux and (B) cumulative release (right) 75
Figure 26. Distribution of Method 1315 repeatability (RSDr) and reproducibility (RSDR) by study
material compared to precision estimates reported forNEN 7345 and TCLP 78
Figure 27. Cumulative release from CEN/TS 15863 and NEN 7375 compared to Method 1315
statistics 81
xv
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Figure 28. Check on the effect of SWA aging on cumulative release 83
LIST OF TABLES
Table 1. Summary of the Number of Targeted and Validation Laboratories 6
Table 2. Total Content Analysis of Study Materials 9
TableS. MDLs and MLs for ICP-OES 12
Table 4. MDL and ML Values for Supplemental ICP-MS Analysis 13
Table 5. MDL and ML Values for Supplemental 1C Analysis 13
Table 6. MDL and ML Values for Supplemental Total Carbon Analysis 14
Table 7. Candidate ICP-OES Analytes and Selected Analytes for Statistic Analysis 15
Table 8. Constants Cn for Constructing the Robust Confidence Limits 18
Table 9. Example ANOVA Table 20
Table 10. Homogeneity QA/QC for Total Content Derived from XRFS 23
Table 11. Data Quality Indicator Goals and Overall Results 23
Table 12. Data Quality Indicators for ICP-OES Analysis of Selected Analytes 24
Table 13. Method 1314 Eluate Concentration Repeatability (RSDr) across Study Materials 41
Table 14. Method 1314 Eluate Concentration Reproducibility (RSDR) across Study Materials 42
Table 15. Method 1314 Cumulative Release Repeatability (RSDr) across Study Materials 43
Table 16. Method 1314 Cumulative Release Reproducibility (RSDR) across Study Materials 44
Table 17. Method 1314 Precision Estimates for Scenario # 1 (Concentration in 2nd Fraction) 46
Table 18. Method 1314 Precision Summary for Eluate Concentration 46
Table 19. Method 1314 Precision Summary for Cumulative Release 46
Table 20. Method 1315 Interval Flux Repeatability (RSDr) across Study Materials 71
Table 21. Method 1315 Interval Flux Reproducibility (RSDR) across Study Materials 72
Table 22. Method 1315 Cumulative Release Repeatability (RSDr) across Study Materials 73
Table 23. Method 1315 Cumulative Release Reproducibility (RSDR) across Study Materials 74
Table 24. Method 1315 Precision Estimates for Scenario # 1 (Flux in 4th Interval) 76
Table 25. Method 1315 Precision Summary for Mean Interval Flux 76
Table 26. Method 1315 Precision Summary for Cumulative Release 77
Table 27. Comparison of Method 1315 andEU Mass Transfer Test Parameters 79
xvi
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INTRODUCTION
Leaching tests have traditionally been used to estimate the leaching potential of waste or other materials
for situations where the material is placed in a landfill or used on the land. The goal in conducting leach
testing has been to assess the potential for contaminant release and the likelihood of groundwater
contamination resulting from land application of wastes or other materials. Over 50 different leaching
tests have been identified in the literature (van der Sloot et al., 1997) with many individual testing
approaches developed specifically for the evaluation of a particular material or management application.
For example, the current regulatory leaching test, the Toxicity Characteristic Leaching Procedure or
TCLP (EPA, 1992a), is a single-batch extraction method that simulates leaching from a plausible worst-
case "mismanagement" scenario of co-disposal of potentially hazardous waste with municipal solid
waste. Rather than establishing individual tests for each application, a more robust and flexible approach
would allow for broad-based use of a limited set of leaching tests, designed to determine intrinsic
leaching characteristics of wastes and other solid materials, that provide leaching results comparable
between material types and applicable to a wide range of leaching conditions and release scenarios.
The Leaching Environmental Assessment Framework (LEAF) is a set of leaching test methods, scenario-
based leaching assessment mass transfer models, and information management tools designed to provide
more accurate estimates of constituent leaching under field conditions than provided by current
approaches based on single-extraction tests. The LEAF approach was developed collaboratively between
Vanderbilt University (VU), United States Environmental Protection Agency (EPA) Office of Solid
Waste and Emergency Response (OSWER), EPA Office of Research and Development (ORD), Energy
Research Centre of the Netherlands (ECN) and DHI Denmark (DHI). The LEAF methodology for
leaching assessment is based on a tiered approach of testing (Kosson et al., 2002) that accounts for the
impact of environmental conditions on leaching.
Unlike TCLP and other currently utilized leaching tests that are designed to simulate leaching for
particular environments, the LEAF leaching methods are intended to characterize material-specific
leaching behavior over a broad range of test conditions that encompassing the range of plausible waste
management conditions and measure intrinsic leaching properties (e.g., liquid-solid partitioning or
constituent release rate). Key parameters that are identified in LEAF to affect leaching include pH, the
liquid-to-solid ratio (L/S) or the volume of water in contact with a unit mass of solid material, and the
physical form of the solid material (e.g., monolithic or granular material). The leaching test data can be
integrated to define the characteristic leaching behavior that can be applied to estimate the potential for
constituent release under anticipated field conditions for a range of management scenarios.
Currently, the LEAF test methods are under review by the EPA OSWER for inclusion into the EPA's
"Test Methods for Evaluating Solid Waste, Physical/Chemical Methods" (SW-846), the compendium of
laboratory methods published to support the Resource Conservation and Recovery Act (RCRA) program.
A final stage in the review process is the documentation of method precision obtained through
interlaboratory validation to ensure that method performance can be achieved by laboratories outside of
the laboratory that developed the method. In the context of method standardization, precision is a
measure of the variability among test results conducted on the same material or type of material (ASTM,
2002) and is commonly conveyed in terms of method repeatability and method reproducibility. Method
repeatability refers to the closeness of agreement between independent results obtained with the same
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method on identical test materials, under the same conditions (Currie and Svehla, 1994). Repeatability is
a measure of the expectations of the method to provide similar results for replicate tests conducted by the
same laboratory and is expressed in terms of percentage as the repeatability relative standard deviation
(RSDr). Method reproducibility refers to the closeness of agreement between independent results
obtained with the same method on identical test material but under different conditions (Currie and
Svehla, 1994). Reproducibility provides an estimate of the variability that might be expected when
different laboratories measure the same property of the same material and is typically expressed in terms
of a percentage as the reproducibility standard deviation (RSDR).
This document reports on the method validation study, data processing and method precision estimates
for the following two LEAF leaching methods:1
• Method 1314: Liquid-Solid Partitioning as a Function of Liquid-Solid Ratio using an Up-
Flow Percolation Column Procedure
• Method 1315: Mass Transfer Rates from Monolithic and Compacted Granular Material
using a Semi-dynamic Tank Leaching Procedure
The intent of this interlaboratory study is to provide the method precision statistics for Method 1314 and
Method 1315 that may be used to support the establishment of initial performance guidelines and the
development of guidance on the use of these methods. The structure of the study was based on the
approach suggested by the EPA's Guidance for Methods Development and Methods Validation for the
RCRA Program (EPA, 1992b) and ASTM International (ASTM) E691 Standard Practice for Conducting
an Interlaboratory Study to Determine the Precision of a Test Method (ASTM, 1987). Since no pre-
established precision criteria for acceptability of a method exist within the guidance documents, this
report makes no conclusions regarding the acceptability of the LEAF methods based solely on precision.
Perspective on a reasonable level of precision, however, is discussed with regard to the precision
estimates reported for currently accepted leaching procedures. For example, interlaboratory studies to
provide precision estimates for the currently promulgated leaching method, TCLP, resulted in a mean
method reproducibility of 74% with a range of RSDR between 17 and 118% (EPA, 1992a).
Since the LEAF methods have been developed to determine characteristic or intrinsic leaching behavior
of a solid material, test results for any single material should be comparable between analogous test
methods designed with the same intent. The LEAF methods have been developed in coordination and in
parallel with European leaching methods currently adopted or under development within the European
Union (EU), including Dutch national standards (NEN-labeled tests) and technical specifications (TSs)
developed by the Comite Europeen de Normalisation (CEN).2 In parallel with this validation study, ECN
conducted L/S-dependence testing of Method 1314 study materials using the CEN/TS 14405 method and
the time-dependent mass transport leaching of Method 1315 study materials using CEN/TS 15863 and
1 Although the LEAF methods are numbered in a manner consistent with SW-846, these methods are currently considered
Preliminary Versions of EPA Methods that have not yet been endorsed by EPA pending method validation and final review.
2 The "TS" designation within CEN denotes a method that has resulted from a multi-national consensus process and has been
approved by a CEN technical committee, but has not yet completed interlaboratory validation studies. Once method precision
has been established, the method will require public comment and consensus approval by CEN members to be designated as a
full European standard (EN). Although the TS designation does not carry the status of an EN, TS methods may be adopted as
national standards and written into regulation.
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NEN 7375. Favorable comparison of LEAF method results to the results derived from analogous EU
leaching tests support that these methods adequately accomplish the goal of providing extraction eluates
consistent with their intended use.3
STUDY OBJECTIVES
The objectives of the method validation study were (i) to determine the method precision, i.e.,
repeatability and reproducibility, for LEAF Method 1314 and Method 1315 through statistical analysis of
method outputs derived from multi-laboratory testing for a selection of potential waste materials and
constituents, and (ii) to compare the results of analogous leaching methods under development or adopted
within the EU to the precision statistics generated for LEAF leaching methods.
METHOD DESCRIPTIONS
The method precision estimates for two LEAF leaching tests - Method 1314 and Method 1315 - are
documented as a result of this interlaboratory study. Brief overviews of these methods are included
below while the full text of Method 1314 and Method 1315 may be found in Appendix A and Appendix
B, respectively. In addition, the basis for selection of test parameters and specific values used in these
leaching methods has been described in a background information document on the LEAF leaching
methods (Garrabrants et al., 2010).
Method 1314: Liquid-Solid Partitioning as a Function of Liquid-Solid Ratio using an Up-Flow
Percolation Column Procedure
Method 1314 is an up-flow percolation column procedure used to evaluate the release of constituents
from solid materials as a function of cumulative liquid-to-solid ratio (L/S).4 Relative to field conditions,
L/S can be a useful surrogate measure for time when infiltration rates are considered. In the context of
the column test, L/S is defined as the volume of liquid passing through the column relative to the dry
equivalent mass of test material in the column bed and is expressed in units of mL/g-dry. Approximately
300-600 grams of "as is" or air-dried solid material (moisture content less than ca. 20% dry basis) is
packed under moderate compactive effort into a 5-cm diameter x 30-cm long column. The test material is
packed in five "lifts" with each lift hand tamped using a 1-cm diameter rod. Layers of clean silica sand
are used at the top and bottom of the column to provide flow regulation on the inlet side and coarse
filtration at the outlet. Leaching solution (eluent) is pumped upward through the material and eluate is
collected as nine discrete volume fractions of the continuous elution volume. The up-flow percolation
mode is intended to minimize air entrapment and flow channeling. The pump flow rate is adjusted to
provide a volume of eluent equivalent to 0.75 ± 0.25 L/S per day. For primarily inorganic materials,
3 This report uses the LEAF terminology where "eluate" refers to the solution resulting from a leaching test whereas "leachate"
refers to the solution collected from or measured in the field. The distinction between terms is made to minimize confusion when
comparing laboratory leaching test data to field leaching data.
4 For the purposes of this report, cumulative liquid-to-solid ratio will be denoted as L/S whereas the liquid-to-solid ratio for
individual leaching intervals or test fractions will be denoted as L/S; where the value i represents the endpoint L/S. For example,
L/S0.2 refers to first fraction of Method 1314 starting at L/S=0 mL/g-dry and ending at an L/S=0.2 mL/g-dry while L/S10 refers to
the last fraction of the test starting at L/S=9.5 mL/g-dry ending at L/S=10 mL/g-dry.
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deionized water is used as the eluent for testing; however, a 1 mM solution of CaCl2 may be used when
testing certain materials (e.g., organic soils, clayey materials) where deflocculation of clay layers or
dissolution of organic carbon may be a concern. The collection bottle is placed at a height of 6 to 12
inches above the column to provide sufficient hydraulic head to ensure flow while avoiding siphoning as
well as to minimize backpressure which can cause leaks in the system. The nine eluate fractions are
collected at specified L/S values of 0.2, 0.5, 1.0, 1.5, 2.0, 4.5, 5.0, 9.5, and 10 mL/g-dry. Analytical
sample compositing is allowed depending on the intended use of the test results. The eluate pH,
conductivity and (optionally) oxidation-reduction potential (ORP) are recorded for each fraction prior to
filtration through a 0.45-(im membrane and preservation of an analytical sample. After chemical analysis
of analytical samples, cumulative release from the column at the specified L/S values is calculated from
eluate concentrations and interval liquid-solid ratios (L/Sj). The outputs of Method 1314 include the
graphs of eluate concentration and cumulative release plotted as a function of L/S which are intended to
illustrate changes in leaching that develop as percolation progresses and L/S increases.
Method 1315: Mass Transfer Rates in Monolithic and Compacted Granular Materials using a
Semi-dynamic Tank Leaching Procedure
Method 1315 is a semi-dynamic tank leaching procedure used to determine the rate of mass transport
from either monolithic materials (e.g., concrete materials, bricks, tiles) or compacted granular materials
(e.g., soils, sediments, fly ash) as a function of time. Monolithic test specimens may be cylinders or
parallelepipeds, cast in molds or cut/cored to size from larger samples. Granular materials are compacted
into cylindrical molds at optimum moisture content by Proctor-type compaction methods such as ASTM
standards D698 (ASTM, 2007) or D1557 (ASTM, 2009). Monolithic specimens are unmolded and
exposed to leachant on all faces while compacted granular specimens are exposed only on the axial face
at the opening of the mold used to hold the compacted sample. Test specimens are leached in intervals in
a series of tanks containing deionized water with each leaching interval having a specified duration. The
volume of deionized water in each tank is based on the surface area of the test specimen at a liquid-to-
surface area ratio (L/A) of 9 mL/cm2. At the end of each leaching interval, the test specimen is removed
from the tank, the mass of the test specimen is recorded, and the specimen is submerged into another new
tank containing fresh deionized water. The cumulative times corresponding to the end of the nine
leaching intervals are 2, 25, 48 hours, 7, 14, 28, 42, 49, and 63 days. For each tank eluate, the pH,
conductivity, and (optionally) ORP are recorded prior to filtration through a 0.45-(im membrane and
preservation of an analytical sample. After chemical analysis, the mean flux of constituents in each
interval (i.e., mass released per surface area per unit time of the leaching interval) and the cumulative
release of constituents (total mass released per unit surface area as a function of time) are calculated from
the eluate concentration, the volume of eluate collected for each interval, the geometry and mass of the
test specimen, and the duration of each interval. In addition, mass transfer characteristics (e.g.,
diffusivity, tortuosity) may be calculated using assumed mathematical models. The outputs of Method
1315 typically used for environmental purposes include the interval mass flux (mg/m2 s) and the
cumulative mass release (mg/m2) as functions of cumulative time. This test is used to assess the
combined effects of pore water chemistry (e.g., dissolution, adsorption) and diffusion through a
monolithic or compacted granular material.
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TM
Data Management with LeachXS Lite
Typically, only those chemical species of environmental concern (e.g., heavy metals) are measured under
the current regulatory leaching structure. However, the LEAF methods are designed to provide a more
complete assessment of the leaching behavior of a material which benefits from the analysis and
evaluation of major and minor components of the solid matrix in addition to the typical species of direct
environmental concern. The combination of multi-point leach testing and more comprehensive chemical
analysis leads to a considerable amount of data to be assessed, compared and reported.
The leaching assessment and data management program LeachXS Lite™ has been developed to facilitate
handling and reporting of the large amount of data required for full characterization following the LEAF
approach. LeachXS Lite is a freely-licensed, limited capability version of the LeachXS™ program,
focused primarily on uploading LEAF test method results from data templates in the form of Microsoft
Excel spreadsheets, comparing leaching data between materials and test types, and outputting tabular and
graphical leaching results to Excel workbooks for incorporation into reports.5 The Lite version of
LeachXS was developed, in part, to facilitate EPA coal combustion residue reports (Sanchez et al., 2006;
Sanchez et al., 2008, Kosson et al., 2009), but can be used with any applicable material and is not
restricted to use for coal combustion residues.
For each of the LEAF methods, participating laboratories were requested to use and complete a data
template for each method. The data templates assist with method execution (e.g., calculations for the
leaching interval durations) and provide a uniform vehicle for recording pertinent bench-scale and
analytical data. After chemical analysis of the validation study analytical solutions, eluate concentrations
were loaded into the data templates and both laboratory and analytical information was uploaded into a
materials database usable within LeachXS and LeachXS Lite.
VALIDATION STUDY OVERVIEW
The validation of Method 1314 and Method 1315 was based on the approach published in EPA's
Guidance for Methods Development and Methods Validation for the RCRA Program (EPA, 1992b). This
document recommends that precision estimates be based on test results for materials conducted in
triplicate by a minimum of three participating laboratories. Since the minimum number of laboratories
suggested by EPA was deemed too small to produce adequate statistical analysis, the guideline of a
minimum of six laboratories, found in ASTM E691 Standard Practice for Conducting an Interlaboratory
Study to Determine the Precision of a Test Method (ASTM, 1987) was adopted. Although ASTM and
EPA guidance recommends a minimum of three materials, the validation of Method 1314 and Method
1315 was completed with two study materials for each test which was considered sufficient based on the
EPA quality assurance/quality control (QA/QC) and program office reviews. In addition, the statistical
analysis of validation results is consistent with the approach described in ASTM E691. The design and
execution of this validation study was supported by a quality assurance project plan (QAPP) describing
5 LeachXS Lite, which is a collaboration of VU, ECN, EPA ORD and ARCADIS, does not include the advanced formatting,
statistical calculations, or geochemical and reactive transport modeling capabilities native to the full LeachXS version. The
LEAF methods, data templates and LeachXS Lite are available free of charge at http://vanderbilt. edu/leaching.
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all material handling procedures and data quality goals. The QAPP, as approved by the EPA ORD, is
provided in Appendix C.
Project Organization
The project team for this validation study included personnel from EPA-ORD, ARCADIS and VU. The
project team was responsible for the selection of participating laboratories, the scheduling of method
validations, and the review of study documents. EPA ORD served as overall project manager while EPA
OSWERwas responsible for maintaining lines of communications with participating laboratories.
Distribution of equipment kits and study materials to participating laboratories was conducted through
ARCADIS. VU served as the reference laboratory for Method 1314 and Method 1315 based on their
collaboration in developing the column and tank leaching tests. To minimize variations in the test method
that would be expected if individual laboratories each conducted chemical analysis using different
analytical approaches, equipment and technicians, all eluate chemical analysis was conducted at VU using
inductively coupled plasma-optical emission spectroscopy (ICP-OES).
Selection of Participating Laboratories
Participating laboratories from academia, government, and the commercial sector were asked to donate
time, personnel and support for this study. Following the policy established for validation of the LEAF
batch methods (Garrabrants et al., 2012), the anonymity of the participating laboratories was ensured by
assigning each laboratory, eluate samples and data results a number (e.g., Laboratory #1 produced the
data shown with the L01 label).
Due to the pro bono nature of the laboratory participation, a certain level of attrition was expected
throughout the course of the study and, therefore, at least one additional laboratory was recruited for each
method above the minimum six laboratories recommended in ASTM guidance. A summary of the
number of targeted laboratories and the number of laboratories used in the validation study for each
method and material is presented in Table 1. In the Fall 2010, a total of ten laboratories participated in
validation of Method 1315 and returned analytical samples forthe first study material. However, two
laboratories - L05 and L09 - were not able to participate in testing of the second study material due to
financial and/or time commitments. Method 1314 was validated in the Winter 2011 with a total of seven
laboratories returning analytical samples for two study materials. The number of laboratories asked to
participate in the Method 1314 validation was limited by the costs to EPA associated with providing
capital equipment (i.e., columns and pumps) to the participating laboratories.
Table 1. Summary of the Number of Targeted and Validation Laboratories.
Target Validation
Laboratories Laboratories
Method
Method 1314
Materials
Contaminated Field Soil
Brass Foundry Sand
Method 1315 Solidified Waste Analog 10
Contaminated Field Soil 10
10
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Laboratory Participation
Each participating laboratory was asked to perform each test method as written in triplicate for two
materials and to produce filtered and preserved analytical solutions (i.e., filtered eluates with 1% by
volume Optima-grade nitric acid). In parallel, VU, serving as the reference laboratory for both Method
1314 and Method 1315, produced analytical samples for six test replicates of each test and material. All
laboratories were required to provide technician support and to cover the costs of any consumable
supplies (e.g., filtration membranes, reagents, etc.). The analytical samples were shipped under chain of
custody by the participating laboratories to VU for chemical analysis. As part of the validation study, all
laboratories were required to complete the laboratory data sections of a data template for each test method
and material.
Chemical Analysis and Data Management
The analytical solutions were chemically analyzed at VU for a suite of 25 analytes using ICP-OES.
During chemical analysis, the source of laboratory samples was masked using the laboratory numbering
system on all sample labels. The validity of the chemical analysis was assessed by the VU analytical staff
through a series of QA/QC checks, included initial and continuing calibration and analytical blank
verifications, periodic spiked sample measurement and spike recovery calculations, and examination of
relative standard deviation (RSD) of replicate analyses. All QA/QC checks were compared to the data
quality indicators (DQIs) established in the QAPP prior to the start of the validation study. Verified
analytical data for each material and test method were inserted into each of the corresponding data
templates submitted to VU from the participating laboratories. These data templates were used by VU
personnel to create and maintain a LeachXS Lite materials database for the validation study of all four
LEAF methods.
Calculation of Precision Statistics
For each material and test, participating laboratories were required to complete the laboratory data
sections of the provided Excel data template. When chemical analysis was complete and validated by VU
analytical staff, eluate concentrations were amended to the data template which was used to upload test
method and analytical data into LeachXS. The approach for analysis of validation data included standard
statistical calculations consistent with the methodologies presented in EPA and ASTM guidance and the
recommendations of the International Standards Organization (ISO) Accuracy (Trueness and Precision)
of Measurement Methods and Results (ISO, 1994). This data assessment approach was recommended by
collaborators at North Carolina State University and approved by EPA through the QAPP review process.
The statistical equations were implemented into a statistics module developed for LeachXS by
collaborators at ECN. The statistics module allows the user to merge datasets from the materials database
(e.g., each replicate of results from a single test of a method at a single laboratory is a separate dataset)
and calculate parametric and non-parametric statistics. The output was saved as an .xml file that then was
uploaded back into LeachXS for data processing and visualization. Using the standard statistical
functions implemented in LeachXS for this project, the following statistics were derived from interpolated
eluate concentrations and used to describe the validation data:
• 95% Prediction Limits (PLs)
Prediction limits were calculated using the reference laboratory data and used to create an interval
above and below the mean of the reference laboratory data. The interval about the mean indicate
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of the range within which future data from the reference laboratory would fall at the 95%
probability level.
• 95% Robust Confidence Limits (RCLs)
Confidence Limits using robust statistical approaches (Huber, 1968; Daszykowski et al, 2007)
were derived and used to create an interval about the median of the laboratory means. The
interval represents the range of response for the mean of a laboratory at the 95% probability level.
• Standard Deviations about the Mean
Standard deviations associated with "within laboratory", "between laboratory" and "overall"
variance factors were derived from the calculations used in a one-way analysis of variance
(ANOVA). These standard deviations were used to create intervals about the mean of the data set
to represent the range of uncertainty associated with each variance factor in the ANOVA. Since
not formal ANOVA was conducted, the significance statistics from the F-distribution was not
calculated.
• Coefficient of Variation (CVs) 6
Coefficients of variation are presented as standard deviations for "within laboratory", "between
laboratory" and "overall" variance factors normalized to the mean test output value in order to
compare relative contributions from these variance sources.
• Relative Standard Deviations
The CVs for "within laboratory" and "overall" variance factors are used to represent method
precision, respectively, as repeatability relative standard deviation (RSDr) and reproducibility
relative standard deviation (RSDR).
Method precision, based on RSDr and RSDR values, were determined for ten selected analytes in each of
the three study materials. Using the method precision data for eight analytes common to all study
materials, distributions of method repeatability and reproducibility results as a function of test parameters
(i.e., L/S for Method 1314 and time for Method 1315), analytes, and study materials were compared to
precision statistics published for accepted leaching tests.
STUDY MATERIALS
The study materials used to validate Method 1314 included contaminated field soil (material code CFS)
retained from remediation of a smelter site and spent casting sand collected from a brass foundry
(material code JaFS). These materials were chosen to provide a wide variety of constituent analytes with
enough common analytes to allow for comparison of precision estimates between materials. These
materials were also considered by the project team to represent typical granular materials that would
likely see percolation-controlled release in many environmental applications. For Method 1315, study
materials included a laboratory-formulated solidified waste material (material code SWA) and the
6 This report uses the terms "coefficients of variation" (CVs) and "relative standard deviations" (RSDs). Although
mathematically equivalent, these terms are used in the report to differentiate the analysis of variance sources (i.e., CVs for
"within laboratory", "between laboratory" and "overall" standard deviations) from measures of method precision determined as
the repeatability relative standard deviation (RSDr) and reproducibility relative standard deviation (RSDR).
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aforementioned CFS smelter soil. These materials were chosen to challenge the method with both
monolithic and compacted granular materials types while providing a variety of constituent analytes,
again, with enough common analytes to allow for comparison of precision between materials. The CFS
and SWA materials were previously used in the validation of batch extraction tests Method 1313 and
Method 1316 (Garrabrants et al., 2012).
Total Elemental Contents
The total element contents of the study materials used to validate Method 1314 and Method 1315 are
shown in Table 2.
Table 2. Total Content Analysis of Study Materials.
Analyte Symbol
Aluminum3 Al
Antimony Sb
Arsenic As
Barium Ba
Beryllium Be
Boronb B
Cadmium Cd
Calcium3 Ca
Carbon, inorganic0 TIC
Carbon, organic" TOC
Chromium Cr
Cobalt Co
Copper Cu
Iron3 Fe
Lead Pb
Lithium Li
Magnesium Mg
Manganese Mn
Molybdenum Mo
Nickel Ni
Phosphorus P
Potassium K
Selenium Se
Silicon3 Si
Sodium3 Na
Strontium Sr
Sulfur S
Thallium Tl
Titanium Ti
Vanadium V
Zinc Zn
SWA
(mg/kg)
59,000
2,100
1,100
3,000
3.5
3,600
2.6
220,000
2,000
5,000
1,200
18
67
21,000
330
4.3
33,0003
900
7.6
25.0
2,000
7,000
1,300
120,000
40,000
1,300
8,200
1.1
4,400
100
86
CFS
(mg/kg)
34,000
490
1,900
810
0.39
610
310
46,000
600
27,000
240
110
60,0003
87,000
6,0003
1.80
5,300
1,700
710
80.0
380
11,000A
52.0
150,000
11,000
280
64,0003
29.0
2,200
58.0
25,0003
JaFS
49,000
<10
<14
90
<2.4
460
<2.8
13,000
600
39,000
3.6
2.8
6,900
10,000
1,400
<2.4
12,0003
28
<1.5
50
120
2,600
<19
340,000
7,300
74
6,2003
<5.8
1,100
12
15,0003
Notes:
All determinations by digestion using EPA Method 3052 (EPA, 1996) and ICP-OES unless noted.
a Total content by XRFS using EPA MOP 5003.5 (EPA, 2010)
b Total boron by digestion using EPA Method 3051 (EPA, 2007a)
0 Total organic and inorganic carbon by catalytic combustion using EPA Method 9060 (EPA, 2004)
-------
For the purposes of interpreting total content and describing these materials, analytes are grouped into
major, minor, and trace species categories as follows:
• Major species - analytes with total content of at least 10,000 mg/kg (i.e., 1 % by mass);
• Minor species - analytes with total content less than 10,000 mg/kg but at least 1,000 mg/kg; and
• Trace species - analytes with total content less than 1,000 mg/kg.
Total content was determined by a combination of X-ray fluorescence spectrometry (XRFS) for major
species and microwave-assisted acid digestion using EPA Method 3052B (EPA, 1996) with chemical
analysis of digestions by inductively coupled plasma-optical emissions spectrometry (ICP-OES). XRFS
and digestions were conducted by ARCADIS while chemical analysis of digestions was performed at VU.
Solidified Waste Analog
A solidified waste analog material (material code SWA) was used in monolithic form for the validation of
Method 1315. The SWA material was designed by VU to simulate a waste stream treated by
solidification/stabilization comprised of 6 wt% Type I portland cement, 33 wt% class C coal combustion
fly ash, and 33 wt% ground granulated blast furnace slag and approximately 28 wt% waste water
containing several dissolved metal salts of antimony, arsenic, barium, cadmium, copper, lead, selenium
and zinc. The cementitious material was mixed in bulk at VU and cast into 10-cm diameter x 10-cm long
cylindrical plastic molds and cured at VU in a moist environment for a minimum of 28 days.7 Details on
preparation of the SWA materials are available in the Method 1313 and Method 1316 validation report
(Garrabrants et al., 2012). The major species in SWA included Al, Ca, Fe, Mg, Si, Na, and total carbon
while Sb, As, B, Ba, Cr, P, K, Se, Sr, S, and Ti were detected as minor species.
Four randomly selected monoliths (-1,500 g each) were distributed by ARCADIS to each of the
participating laboratories while eight randomly selected monoliths were retained by VU, the reference
laboratory for the validation of Method 1315. The extra monolith in each distribution package to the
participating laboratories was included to ensure that each laboratory would have a sufficient number of
test specimens in case of minor damage during shipment. In addition to the four monoliths used for
Method 1315 testing, the ECN received four additional monoliths slated for testing using analogous EU
methods. In Winter 2011, triplicate testing of SWA using a Dutch monolithic diffusion test, NEN 7375
(NEN, 2004), was conducted in parallel with the interlaboratory study. Approximately one year later, an
additional four monolith specimens were sent to the ECN for testing using the CEN/TS 15863 diffusion
test.
Contaminated Field Soil
A soil contaminated with heavy metals (material code CFS) was used in validation of both Method 1314
and Method 1315. Approximately 320 kg of contaminated field soil was collected from a smelter site
located in the United States and shipped to ARCADIS for processing in 5-gallon plastic buckets. The
entire batch of soil was sieved to pass a 2-mm opening in order to remove large rocks and other refuse
In parallel, bulk SWA material used for validation of Method 1313 and Method 1316 (Garrabrants et al., 2012) was cured in 10-
cm diameter by 20-cm long cylindrical molds under the same curing conditions.
10
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and transferred to a clean blue plastic tarp for mixing by coning and quartering as described in ASTM
D5231 (ASTM, 2008). After homogenization, the soil was divided into 1-L HDPE jars containing
approximately 1 kg each for distribution to the participating laboratories. Each participating laboratory
received six randomly selected jars (6 kg) of soil to be used in testing while the reference laboratory
retained 12 randomly selected jars (12 kg). Subsamples from 12 randomly selected containers were taken
for total mercury analysis and an additional three subsamples taken for total content analysis by Method
3052/ICP-OES. Total content analysis of CFS material showed that major species included Al, Ca, Cu,
Fe, K, Si, Na, S, and Zn while minor species included As, Pb, Mg, Mn and Ti.
Brass Foundry Sand
Spent casting sand (identified by material code JaFS) was used as a study material for validation of the
Method 1314 column test. A sample of spent casting sand was collected in twenty-five 5-gallon buckets
from a brass foundry located in the United States and shipped to ARCADIS for processing and
distribution. ARCADIS sieved the sample material to pass a 2-mm opening and homogenized the sample
using coning and quartering techniques. The homogenized foundry sand was returned to 5 gallon buckets
and subsamples from three of the 25 buckets were taken for total content analysis by Method 3052/ICP-
OES. Once homogenization was verified through comparison of total content subsamples, the foundry
sand was further divided into 1-kg portions and placed into 1-L high-density polyethylene (HDPE)
containers for distribution to the laboratories. Three randomly selected 1-L containers (3 kg) were sent to
each participating laboratory for triplicate testing using Method 1314. The reference laboratory retained
six randomly selected containers (6 kg), enough material to conduct six replicates of the test. Major
species in the JaFS material include Al, Ca, Fe, Mg, Si and Zn. Minor species include Cu, Pb, K, Na, S,
and Ti.
ANALYTICAL METHODS
All eluates were analyzed at VU to minimize variability in the results associated with individual
analytical methods and QA/QC assessments. The concentrations of a suite of analytes were measured by
ICP-OES on a Varian ICP Model 720-ES (Agilent Technologies, Santa Clara, CA) following SW-846
Method 6010 (EPA, 2007b). The suite of analytes included Al, As, B, Ba, Ca, Co, Cr, Cu, Fe, Li, Mg,
Mn, Mo, Ni, P, Pb, S, Sb, Se, Si, Sr, Ti, TI, V, and Zn.
The ICP-OES analytical range of approximately 0.1 mg/L to 25 mg/L for trace metals was calibrated
using five-point standard curves whereas the analytical range was extended to a maximum of 500 mg/L
using seven-point standard curves for major components. During analysis of solutions, blanks and
calibration check standards (~0.5 mg/L) were monitored every 10 to 20 samples with the requirement that
recoveries be within 20% of the specified value. Analyses were performed on undiluted samples when
possible and, when necessary, samples were diluted gravimetrically to within the targeted analytical range
using 1% (v/v) Optima grade nitric acid (Fisher Scientific) in deionized water. Yttrium at 10 mg/L was
used as an internal standard. Analytical matrix spikes were checked for three test positions for each
triplicate analysis of a laboratory data set. For each 5 mL sample aliquot, spikes were prepared by
addition of 100 uL of a 10 ug/L standard solution for trace species or 100 uL of a 1,000 ug/L standard
solution for major species.
11
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Table 3 presents the ICP-OES analytes and associated method detection limit (MDL) and minimum level
of quantitation (ML), determined by VU according to the Technical Support Document for the
Assessment of Detection and Quantitation Approaches (EPA, 2003).8 Concentrations measured at values
less than the MDL were reported as "non-detected" or "ND" in tabular formats, but were set to a value of
!/2 the MDL value for plotting and data analysis. Concentrations measured at less than the ML but greater
than the MDL were reported as "estimated values" and were maintained as measured for plotting and data
analysis.
Table 3. MDLs and MLs for ICP-OES.
Symbol
Al
Sb
As
Ba
Be
B
Cd
Ca
Cr
Co
MDL
(fig/L)
1.0
7.5
11.0
1.0
1.7
1.0
2.2
2.6
1.2
1.8
ML Symbol
(fig/L)
3.2
23.9
35.0
3.2
6.0
3.2
7.0
8.3
3.8
5.7
Cu
Fe
Pb
Li
Mg
Mn
Mo
Ni
P
K
MDL
(Mg/L)
3.7
2.0
6.8
1.9
1.0
2.0
1.2
1.8
3.7
1.6
ML Symbol
(Mg/L)
11.8
6.4
21.6
6.0
3.2
6.4
3.8
5.7
11.8
5.1
Se
Si
Na
Sr
S
Tl
Ti
V
Zn
MDL
(Hg/L)
15.0
1.1
2.5
1.0
6.8
4.6
2.0
1.5
1.0
ML
(Hg/L)
47.7
3.5
8.0
3.2
21.6
14.6
6.4
4.8
3.2
Supplemental Analysis for Reference Laboratory Eluates
For the six sets of replicate eluates provided for analysis by the reference laboratory, the standard
chemical characterization of 25 analytes by ICP-OES was supplemented with analysis of Cs, Sn, and U
by inductivity coupled plasma-mass spectroscopy (ICP-MS and analysis of dissolved inorganic carbon
(DIG) and dissolved organic carbon (DOC) by total carbon analysis. Supplemental analysis was
conducted to address specific regulatory concerns (e.g., Cs, Sn, and U) and to document the dissolution of
carbon species which can significantly influence leaching concentrations.
Prediction limits at the 95% probability level were calculated for all analytes (i.e., supplemental analytes
plus ICP-OES analytes) from chemical analysis of the six reference laboratory test replicates to illustrate
the range of within-laboratory data obtained during the validation study. The full set of analytical data is
presented in Appendices E (Method 1314) and F (Method 1315) for the reference laboratory test results.
Inductively Coupled Plasma -Mass Spectroscopy
ICP-MS analysis was carried out at VU following SW-846 Method 6020 (EPA, 2007c) using a Perkin
Elmer model ELAN DRC II (Perkin Elmer, Waltham, MA) in standard mode. Initially, analyses for 10:1
8 The analytical data quality indicators for this report are based on the guidelines established by the EPA Office of Water and
include establishing a method detection limit (MDL) and minimum level of quantitation (ML) based on standard deviation of
seven non-consecutive analyses of a low-concentration standard analytical solution. However, the EPA Office of Resource
Conservation and Recovery (ORCR) has recommended that practitioners establish a lower limit of quantitation (LLOQ) for
analytes of concern as a demonstration of quantitation capability at low analyte concentration levels. The LLOQ demonstration
is a performance-based validation of recovery from a spiked analytical solution typically at concentration levels approximating
the lowest calibration standard.
12
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(water: sample) volumetric dilutions were performed to minimize total dissolved solids loading to the
instrument. Additional dilutions at 100:1 and 1000:1 were analyzed as needed if the calibration range of
the 10:1 dilutions was exceeded. Internal standards consisting of 50 uL of each a 10 mg/L indium
solution and a 10 mg/L bismuth solution were added to each 10 mL diluted sample aliquot prior to
analysis. Internal standards of indium and bismuth are used to adjust for the centration response for
species with mass range below and above 150, respectively. MDL and ML values for supplemental ICP-
MS analyses as determined by the analytical laboratory are shown in Table 4.
Table 4. MDL and ML Values for Supplemental ICP-MS Analysis.
Symbol
Cs
Sn
U
MDL
(Mg/L)
0.49
0.70
0.30
ML
(Mg/L)
1.6
2.2
1.0
Ion Chromatography
Anion concentrations in reference laboratory analytical samples were determined by ion chromatography
(1C) using a Dionex DX600 system (Dionex Corporation, Sunnyvale, CA) with a conductivity detector
following EPA SW-846 Method 9056 (EPA, 2007d). A five-point standard curve was created by dilution
of a seven-anion bulk standard and used to calibrate the analytical range which varied based on the
relative concentrations of analytes in the bulk standard. Analytical blanks and calibration check standards
at approximately 1 mg/L were measured after every ten analytical samples and compared to acceptable
QA/QC criteria (i.e., calibration standard recoveries were required to be 85-115% and concentrations in
analytical blanks required to be non-detectable). MDL and ML values for supplemental 1C analytes as
calculated by the analytical laboratory are shown in Table 5.
Table 5. MDL and ML Values for Supplemental 1C Analysis.
Symbol
Cl
F
NO3
PO4
SO4
MDL
(Mg/L)
6.4
7.1
26
24
21
ML
(Mg/L)
21
22
82
75
66
Total Carbon Analysis
Total carbon analysis following SW-846 Method 9060 (EPA 2004) for all eluates was performed on a
Shimadzu model TOC-V CPH/CPN (Shimadzu Scientific Instruments Inc., Columbia, MD) to determine
the concentrations of DIC and DOC in reference laboratory analytical samples. Five-point calibration
curves, for both DIC and non-purgeable DOC analyses, were generated for an analytical range between 1
and 100 mg/L. The value for a minimum acceptable standard curve correlation coefficient was set at
0.995. An analytical blank and a calibration check standard at approximately 1 mg/L were measured after
every ten analytical solutions and the results compared to acceptable QA/QC criteria (i.e., the recovery of
13
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calibration checks were required to be 85-115% and concentrations in analytical blanks were required to
be non-detectable). Table 6 shows the MDL and ML values for supplemental DIG and DOC analyses.
Table 6. MDL and ML Values for Supplemental Total Carbon Analysis.
Symbol
DIC
DOC
MDL
(Mg/L)
130
170
ML
(Mg/L)
410
550
DATA PROCESSING METHODS
Data processing includes all operations used to prepare collected method results for use in statistical
analyses. These operations include initial evaluation of chemical analyses, test result validation through
assessment of chemical analysis of required method blanks and associated filtering of collected analytical
data due to significant method blank concentrations or identified causes of error, and logio-transformation
and interpolation/extrapolation of selected analyte results to L/S or time targets as specified in each
method.
Method Blank Analysis and Data Filtering
As specified in each test method, participating laboratories provided preserved analytical solutions
representing method blanks. For Method 1314, the required method blank is simply a sample of the
leaching solution used in the column test. For Method 1315, method blanks were a full set of analytical
solutions resulting from conducting one entire test replicate as a method blank (i.e., tank leaching
conducted without solid specimen, but otherwise carried through the process using all equipment and
following all handling procedures). Method blanks were chemically analyzed by ICP-OES along with the
test extractions and the results were evaluated to identify potential sources of contamination (e.g., contact
surfaces, contaminated reagents) that might bias the results of the test extractions. When concentrations
in the method blanks or the recorded values of other process variables (e.g., eluate pH, collection times, or
eluate volumes) indicated that analyte concentrations in the test extractions may have been biased,
removal or "filtering" of the corresponding test extraction result from the statistical analysis was
considered. A brief review of the results of method blank analysis and data filtering is presented with the
QA/QC summary. Detailed discussion of the method blank and data filtering processes is available in
Appendix D.
Analvte Selection
Eluate concentrations for ICP-OES analysis of reference laboratory analytical samples for Method 1314
(Appendix E) and Method 1315 (Appendix F) were used to identify candidate analyte s for use in the
validation study. The results of this initial screening are shown in Table 7. For each method and study
material, analytes with no more than one concentration value less than the MDL were indicated by a
check mark and considered candidates for estimation of precision. In the table, toxicity characteristic
(TC) priority metals based on the RCRA program are shown in red text.
For each method, a set of 10 analytes for each material was selected for statistical evaluation. These
analytes are shown in yellow in Table 7. The selection of the analytes for the validation considered: (i)
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relevance to potential risks to human health and the environment (e.g., TC metals), (ii) representativeness
of the range of characteristic pH-dependent leaching behaviors as a function of pH, and (iii)
concentrations at sufficient level to allow a single, undiluted ICP-OES analysis. Priority was given to
eight analytes present in both study materials to allow for comparisons of analyte-based precision across
material types.
Table 7. Candidate ICP-OES Analytes and Selected Analytes for Statistic Analysis.
Analyte
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Lithium
Magnesium
Manganese
Molybdenum
Nickel
Phosphorus
Potassium
Selenium
Silicon
Sodium
Strontium
Sulfur
Thallium
Titanium
Vanadium
Zinc
M1314 M1314 M1315 M1315
y CFS JaFS SWA CFS
Al
Sb
As
Ba
Be
B
Cd
Ca
Cr
Co
Cu
Fe
Pb
Li
Mg
Mn
Mo
Ni
P
K
Se
Si
Na
Sr
S
Tl
Ti
V
Zn
Total Selected Analytes
Common Analytes
*
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is a common statistical practice for data that cannot have negative values, e.g., concentration (Haldar and
Mahadevan, 2000) to lessen the impacts of extreme data values and to render the statistical distributions
closer to normal, thereby enhancing the suitability of statistical methods based on the normal distribution
(Ellison et al., 2009). Linear interpolation/extrapolation of Iogi0-transformed method output allowed for
statistical analysis of data within and between laboratories at the same L/S or time value.
For Method 1314, analytical samples of column eluates are collected at specified values of L/S between
0.2 and 10 mL/g-dry. In environmental applications, the method has two outputs: (i) the eluate
concentrations (mg/L) as a function of L/S and (ii) the cumulative mass release (mg/kg) as a function of
L/S. Logio-transferred eluate concentrations and cumulative mass releases were interpolated to the target
L/S value as necessary to adjust for variations in experimental L/S of the validation study eluates. In
some cases, extrapolation to either the lowest or highest target value was necessary.
Although the direct result of conducting Method 1315 is a series of eluate concentrations collected at
experimental values of cumulative time, the two method outputs that are used for environmental
assessment purposes are (i) the mean interval flux (mg/m2 s) as a function of cumulative time and (ii) the
cumulative mass release (mg/m2) as a function of cumulative time. These outputs are derived from eluate
concentrations and recorded test parameters (i.e., eluate volume, interval duration, and sample surface
area). For each Method 1315 test position, the mean interval flux and the cumulative release were
calculated directly from measured eluate concentrations at the experimental time values and laboratory
information recorded in the data templates by each laboratory. After Iogi0-transformation, these results
were interpolated or extrapolated to the target cumulative time values specified in Method 1315 to adjust
for variations in experimental time values. In some cases, extrapolation to either the lowest or highest
target value was necessary.
Linear interpolation and extrapolation of the logic-transformed data was based on values of the two data
points nearest to the target value. For example, if Method 1314 eluate concentrations are recorded at
experimental L/S values of 0.6, 1.1 and 1.6 mL/g-dry, the eluate concentrations recorded at L/S of 0.6 and
1.1 mL/g-dry are used to extrapolate results to the target L/S value of 0.5 mL/g-dry, while eluate
concentrations at L/S of 1.1 and 1.6 mL/g-dry are used to interpolate method results to the target L/S of
1.0 mL/g-dry.
The algorithm for interpolation is as follows:
Given a set of coordinate data {(x; JA): / = !,...«} sorted by the first coordinate (so that x\ < x2 < •••
< xn) and a target x-value, call it XT, an interpolated/extrapolated j-value, call it JT, is calculated
as:
JT = OT + bTxT
where:
• if XT < x\, then 6T = (y2 ~y\) I (x2 ~ Xi) and aT = y2 - bTx2 (extrapolation from the two
points with closest x-values);
• if XT > xn, then 6T =(j« ~JVi) / (xn ~ xn-i)and aT =yn - b^x,n (extrapolation from the two
points with closest x-values);
• if Xj-\ < XT < Xj, then 6T = (ty ~ Jy-i) / (x}- ~ Xy-^and aT = y}- - b^Xj (interpolation from the
two closest points surrounding XT).
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Extrapolation was limited to a band within 20% of a target L/S or cumulative time value to avoid the
creation of data points when analytical solutions were not submitted by the participating laboratory for a
test position.
STATISTICAL CALCULATIONS
Statistical analysis of interpolated, logic-transformed output focused on determination of the precision
parameters and other descriptive statistics described in this section. All calculations were implemented
within a module of LeachXS, output from LeachXS as a .xml file, and imported back into the LeachXS
materials database for visualization and comparison to other data sets.
95% Prediction Limits (PLs) Based on Reference Laboratory Results
Using only the reference laboratory data set of six test replicates, a prediction interval about the mean of
the data set at each target pH was constructed using standard normal distribution-based prediction
approaches at a 95% prediction level (Rao, 1998; Ellison, 2009).
Suppose that there are n replicate laboratory measurements y\,...,yn. The sample mean (y) and sample
standard deviation^) of these measurements are:
The prediction interval is divided into an upper limit (PLupper) and a lower limit (PLiower) calculated as:
PLlower
PUpper
where t is the upper 0.025 critical value from the Student t distribution with n-\ degrees of
freedom; the area to the right of tis 0.025, often denoted in literature as t(n-\, 0.025).
95% Robust Confidence Limits (RCLs) based on the Median of Laboratory Mean Data.
Intervals about the median of the laboratory means were constructed using robust confidence limits
(Huber, 1968; Daszykowski et al., 2007) at the 95% significance level. These intervals delineate the
reproducibility operating characteristics across laboratories in the sense that one would expect 95% of all
laboratories to produce a mean logio-transformed concentration value of three replicates to fall within
these bounds. To lessen the impact of outlying results from a small subset of laboratories and, thus, to
also facilitate identification of laboratories producing discrepant results, the limits were calculated
substituting robust measures of location and scale, the median and median absolute deviation (MAD), for
their more common non-robust counterparts, the mean and standard deviation (Maronna et al., 2006).
This substitution also requires modification of the usual ^-distribution critical values commonly seen in
confidence and prediction intervals to ensure the desired coverage probabilities. The robust limits and the
method of calculating adjusted critical values are described below.
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For each laboratory data set, the arithmetic mean of the laboratory replicates is calculated as denoted by
y-\>~->yn where the subscript refers to the laboratory number. Note that in most cases n = 10 for the
targeted ten participating laboratories, but this number may differ when data are missing or filtered. The
robust confidence limits depend on the median of the laboratory means (M) and the median absolute
deviation (MAD) of this group of means:
MAD = median { | ^ -M|,..., yn -M|}.
The robust confidence intervals are constructed of an upper limit (RCLupper) and a lower limit (RCLlower)
using the formulae
RCLlower =M- 1.96 Ctt (1.4826) MID,
RCLupper = M +1.96 Ctt (1.4826)M4Ł>,
where the constants Cn for n = 4,..., 12, 100, 200 are given in Table 8.
The factor 1 .4826 in the formulas for the robust confidence limits scales the MAD so that it is an unbiased
estimator of the population standard deviation in large sample sizes when the data are normally
distributed. The factor 1.96 is the 0.025 upper-tail critical value of the standard normal distribution
commonly seen in formulas for 95% confidence intervals based on the sample mean and sample standard
deviation. Although it would be mathematically equivalent to combine the product of Cn, 1 .96 and
1 .4826 into a single constant, keeping them separate makes evident that the interpretation of the constants
Cn in Table 8 as correction factors: (i) adjusts for small sample sizes (in a manner similar to the way that
the ^-distribution critical values adjust for small sample sizes relative to the standard normal critical
values); and (ii) accommodates the fact that limits are constructed using the sample median and sample
MAD (scaled by 1.4826) instead of the sample mean and sample standard deviation as estimators of the
population mean and standard deviation.
Table 8. Constants Cn for Constructing the Robust Confidence Limits.
4
5
6
7
8
9
10
11
.6233
.8633
.4433
.5033
.3300
.3500
.2567
.2700
12
13
14
15
16
20
21
25
.2100
.2233
.1833
.1833
.1567
.1233
.1233
.1033
26
30
31
40
41
50
51
75
.0967
.0833
.0833
.0633
.0633
.0500
.0500
.0300
76
100
101
200
201
.0300
.0233
.0233
.0100
.0100
Because the median and scaled MAD values are consistent estimators of the mean and standard deviation
of the normal distribution, the constants Cn are approximately 1 for very large sample sizes. Close
inspection of Table 8 reveals that the constants decrease monotonically to 1 as n increases for all odd
values of n, and for all even values of n, but that the change from neighboring even to odd n is not
decreasing. This phenomenon results from the alternating definition of the median for odd and even
sample sizes and diminishes in magnitude with increasing sample size.
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The constants Cn were determined by Monte Carlo simulation so that the limits have the desired coverage
properties when the laboratory means are a random sample from a normal distribution. Specifically, for
each value of n in Table 8, one million samples of size n were generated from a standard normal
distribution. For each sample, the fractions of the sample values lying between limits of the formM±
1.96 Cn (1.4826) MAD for a dense grid of values Cn were calculated. These fractions were then averaged
over the one million samples and the value of Cn that resulted in the average fraction being closest to 0.95
(and was always within 0.001 of 0.95) was identified. The Monte Carlo variation in the reported values
ofCn is less than the number of decimal places displayed.
Although the constants were generated in such a manner that the intervals have a very precise
interpretation for normally distributed data, their robustness (stemming from the use of the median and
MAD) ensures their utility for identifying aberrant values from a set of data more generally than for just
normally distributed data.
Estimates of Variance Components and Standard Deviations
The variance components are estimated using the approach of a standard random effects one-way
ANOVA model in which the laboratories are considered the "treatments." The notation and formulas that
follow are the same as in the book by Rao (1998; see in particular Section 14.3 and Box 14.2, pp 650-
653).
The "within laboratory" standard deviation is associated with the repeatability of the method and is a
statistical estimate of variability of replicate measurements from the same laboratory based on pooled
information for all laboratories. Therefore, within-laboratory standard deviation is not specific to any
particular laboratory. The "overall" standard deviation is associated with the reproducibility of the
method and is used to indicate the combined effects of within-laboratory and between-laboratory
variances.
Preliminary Calculations and Example ANOVA Table
YJJ = thej* replicate measurement from the /'* laboratory, j =l,...,nh i =\,...,t.
In most cases, t = 10 laboratories and nt =3 or 6 for the participating laboratories and reference laboratory,
respectively. However, these numbers can vary with missing (filtered) data.
ss[TOT] = yy(7!,-7+r = |yy7/, \-CM
SS[E] = XX(Y,,i ~ Y,,J = SS[TOT] - SS[T]
<=i ;=i
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Table 9 shows how the preliminary calculations described above fit into the ANOVA table. The table
proportions the overall or total error into sources of variation and accounts at each level for the degrees of
freedom (df), the sum of square errors and mean square errors.
Table 9. Example ANOVA Table
Source of
Variation
Treatments
Error
Total
df
t-l
N-\
N-\
Sum of Squares
SS[T]
SS[E]
SS[TOT]
Mean Squares
MS[T]=SS[T]/4f
MS[E]=SS[E]/4f
Fcalc = MS[T]/MS[E]
Variance Components and Standard Deviations
The "within laboratory" variance component, vw, is simply the MS[E] term derived in the ANOVA table.
The standard deviation associated with repeatability, sr, is determined as the square root of the within-
laboratory variance component:
S. = A V,,, =
The variance component associated with between-laboratory variance is:
/ Y _ MS[T]-MS[E]
(SL) ~ -
where D =
.
' &
The standard deviation associated with between-laboratory variance, SL, is calculated as the square root of
the between-laboratory variance component:
SL =
MS[T]-MS[E]
D
In some cases, the between laboratories variance component may be negative and, when it is, the variance
value is set to zero. Although there are more complicated ways of dealing with the negative variance
component problem, these approaches are not warranted in this application.
The total or overall variance component is the sum of the within-laboratory and between-laboratory
variance components and the standard deviation associated with the overall variance, SR, is associated
with the method reproducibility:
Because the term, SL, includes a divisor normalizing the variance to the average number of observations
per laboratory, the approach is numerically consistent with the approach for calculating repeatability and
reproducibility standard deviations in ASTM E691 Standard Practice for Conducting an Interlaboratory
Study to Determine the Precision of a Test Method (ASTM, 1987).
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Repeatability and Reproducibility
The statistic that is associated with the repeatability of a method is the repeatability relative standard
deviation, RSDr, which is calculated as the within-laboratory standard deviation on a percentage basis and
normalized to the overall mean value. The RSDr is numerically equivalent to the within-laboratory
coefficient of variation.
The statistic that is associated with the reproducibility of a method is the reproducibility relative standard
deviation, RSDR, which is a percentage-based measure of the overall standard deviation to the mean value
and numerically equivalent to the overall coefficient of variation.
Y+
Reproducibility Limit
The reproducibility limit (K) was used to create an interval of possible results about the mean of the
LEAF method data ( y ) to show the consistency between LEAF methods results and analogous EU
leaching methods.
The International Standards Organization (ISO) defines reproducibility limit as "the value less than or
equal to which the absolute difference between two test results obtained under reproducibility conditions
may be expected to be within a probability of 95%" (ISO 5725-1, 1994). The reproducibility limit (R) is
derived from the reproducibility standard deviation according to:
where nsthe Student's ^-distribution value required for the \-a level of confidence and the
appropriate number of degrees of freedom, and
SR is the reproducibility standard deviation.
Following the suggestion of Ellison et al. (2009), the value of t was approximated as t=2 to approach the
Student's ^-distribution value limit for a large number of degrees of freedom at the 95% confidence level.
Thus, the R at the 95% confidence limit is calculated as:
The reproducibility limit is applicable to data where errors are considered normally distributed and, thus,
the calculation of reproducibility limit was conducted as a Iogi0-tranform. For each target cumulative L/S
(Method 1314) or time (Method 1315) value, the reproducibility limits above and below the mean of the
validation data (RLupper and RLiower, respectively) were calculated using the validation study mean (y) and
the reproducibility standard deviation for the logio-tranformed data (SR:[og):
21
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and
- 2.8
When compared to the reproducibility limit interval (RL), the results from EU methods that fall within the
reproducibility limit interval about the mean may be considered statistically equivalent to the results of
the LEAF method.
Application of Statistical Approach for Cumulative Results
The cumulative release results for Method 1314 and Method 1315, taken as a whole, may be considered a
longitudinal dataset (i.e., a set of data that tracks the same type of information on the same subjects at
multiple points in time) due to the sequential nature of the data and the likelihood that measurements
recorded by the same laboratory at successive time points are correlated in time. When the objective of
data analysis is to study the evolution of longitudinal processes, the application of statistical methods that
account for the possibility of temporal correlation is essential. However, when the focus of data analysis
is on comparisons at fixed time points, standard statistical approaches where temporal correlation may be
considered negligible have some advantages (Verbeke and Molenberghs, 2009). Thus, since
measurements from different laboratories are independent, the validation of cumulative release results at
fixed L/S (Method 1314) or time points (Method 1315) follows the statistical approach described in the
sections above.
QA/QC SUMMARY
The QA/QC checks used to ensure the validity of the analyses in this study included assessment of initial
sample homogeneity through evaluation of total content replicates, comparison of replication and spike
recoveries during ICP-OES chemical analysis to DQI goals established in the project QAPP (Appendix
C), evaluation of method blank concentrations relative to concentrations in analytical samples, and overall
visual data consistency checks. QA/QC ensured that (i) study materials were adequately homogenized
prior to distribution by ARCADIS to participating laboratories, (ii) chemical analyses of eluate samples
were of sufficient quality for the validation, and (iii) the reported data were not significantly influenced
by outside sources of contamination such as reagents, test equipment, sample containers, etc.
Homogeneity of Study Materials
The homogeneity of collected and processed study materials was assessed through the calculated RSDs of
triplicate total content analyses by either XRFS or EPA Method 3052/ICP-OES. The DQI goals for
acceptable homogeneity were that RSD values from XRFS of replicate material subsamples would be less
than 10% for major species, 20% for minor species and 50% for trace species. Table 10 shows the overall
mean RSD and completeness (i.e., percentage of measured values complying with the RSD goal) as
derived from XRFS analysis of total content in each of the three study materials.
The total content values for JaFS and SWA materials used in the validation of Method 1314 and Method
1315, respectively, meet the criteria for homogeneity established in the QAPP. Based solely on the data
shown in Table 10, the homogeneity of CFS material would not meet the DQI goals for minor species
because the RSD for minor species is greater than 20%. However, the reported RSD value of 47% for
minor species is driven by the very high RSD values for XRFS analysis of Cr and Mg, neither of which
22
-------
are selected analytes in the CFS material for method validation. Removal of the RSD values for Cr and
Mg from the evaluation results in a mean RSD of 10% and a completeness of 100% for minor species in
CFS. With Cr and Mg removed from CFS homogeneity analysis, all materials were considered to be
sufficiently homogenized prior to distribution to the participating laboratories.
Table 10. Homogeneity QA/QC for Total Content Derived from XRFS
Mean RSD
AnalyteType Total Content DQIGoal SWA CFS JaFS
(mg/kg) for RSD
Major Species
> 10,000
< 10%
1.1%
7.4%
6.9%
Minor Species < 10,000 to > 1,000 < 20%
Trace Species < 1,000 < 50%
3.6%
11%
Overall Completeness 100%
47%
34%
10%
29%
Since the output of mass transfer based tests is usually normalized to a unit external surface area,
variability in the surface area of Method 1315 test specimens that is exposed to the leaching solution is a
potential source of test variation. The entire external surface area of the SWA monoliths is exposed to the
leaching solution, whereas the exposed surface area for CFS compacted into cylindrical molds is limited
to the circular face of the mold after compaction. Specimen dimensions, as measured by each
participating laboratory, were used to calculate exposed surface areas as a check that sample-to-sample
variations in specimen size was not a significant factor in the outcome of the leaching tests. For the 30
SWA monoliths used in the validation of Method 1315, the mean external surface area was 494.9 cm2
with a standard deviation of 15.4 cm2. The mean exposed surface area of the 24 compacted CFS
specimens used in the validation of Method 1315 was 83.0 cm2 with a standard deviation of 3.5 cm2. The
relative standard deviations for these exposed surface areas (i.e., 3.1% for SWA and 4.2% for CFS) were
considered to be sufficient to conclude that surface area between test specimens would not be significant
source of variation in test results.
Analytical OA/OC
The analytical DQI goals established in the project QAPP and overall results for critical measurements
are shown in Table 11. For parameters with more than two replicates (i.e., ICP-OES and ICP-MS
analyses, XRFS, and moisture content), analytical precision results are based on the overall mean of
replicate RSD values. Completeness was determined as the percentage of valid measurements meeting
DQI goals out of the total number of measurements. The precision results for XRFS include only the
major species for which the DQI goal in the QAPP was intended. All DQI goals established in the QAPP
were achieved on a global basis for analytical values used in the validation study.
Table 11. Data Quality Indicator Goals and Overall Results
Measurement
ICP-OES
pH, conductivity
moisture content
XRFS
• (Till
Method Precision
EPA Method 60 10
Electrode
ASTMD22 16-05
EPA SOP 5003.3
±10%
±2%
±10%
±10%
Goals Overall Results
Completeness Precision Completeness
>90%
100%
100%
100%
2% 93%
2% 100%
0.2% 100%
5% 100%
23
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A summary of the QA/QC results for each method, material and analyte is available in Appendix H while
detailed information regarding the QA/QC results for each ICP-OES analysis is available in Appendix I.9
Detailed QA/QC results for ICP-OES chemical analysis of the ten selected analytes used for validation of
each method (see Table 7) is presented in Table 12. The data show that while some analytes are more
difficult to quantify (e.g., As, Mo, V) than others, data quality for all analytes is consistently better than
the DQI goals of less than 10% RSD and greater than 90% completeness.
Table 12. Data Quality Indicators for ICP-OES Analysis of Selected Analytes.
Analyte
Aluminum
Antimony
Arsenic
Barium
Boron
Cadmium
Calcium
Chromium
Copper
Lead
Magnesium
Manganese
Molybdenum
Potassium
Selenium
Thallium
Vanadium
Zinc
Mean
RSD
3.5%
1.3%
4.3%
1.4%
2.0%
1.2%
1.2%
1.6%
1.4%
2.6%
1.4%
1.5%
4.3%
1.3%
3.6%
1.8%
4.7%
1.4%
Stdev of
Mean
RSD
0.6%
0.1%
0.6%
0.3%
0.3
0.1%
0.3%
0.4%
0.3%
0.4%
0.3%
0.2%
0.5%
0.2%
0.6%
0.4%
0.6%
0.3%
Complete-
ness
97.5%
99.4%
96.3%
99.9%
99.6%
100%
100%
100%
99.8%
98.3%
100%
100%
94.8%
100%
94.1%
99.5%
96.3%
99.5%
Max Spike
Recovery
1 12%
115%
103%
111%
114%
109%
98.5%
111%
110%
113%
103%
104%
109%
115%
112%
109%
108%
103%
Min Spike
Recovery
87%
85%
89%
83%
83%
90%
82%
88.4%
88%
87%
87%
90%
85%
83%
85%
96%
86%
86%
Method
1314
Materials
CFS, JaFS
-
-
CFS, JaFS
CFS, JaFS
CFS
CFS, JaFS
-
CFS, JaFS
CFS, JaFS
JaFS
JaFS
CFS, JaFS
-
-
CFS
-
CFS, JaFS
Method
1315
Materials
CFS, SWA
CFS, SWA
SWA
CFS, SWA
CFS, SWA
CFS
CFS, SWA
SWA
-
CFS
-
-
-
CFS, SWA
CFS, SWA
-
CFS, SWA
-
During analysis of eluate solutions, analytical blanks and continuing calibration check standards (~0.5
mg/L) were monitored after approximately every ten analytical samples. All calibration checks met the
acceptance criteria of recovery within 15% of the specified value and analytical blanks were measured at
less than the ML. Analytical matrix spikes were checked for three test positions of each set of triplicate
eluates and spike recoveries were calculated to range between 80% and 120%. These results are
consistent with the goals established in the QAPP and indicate that QA/QC goals for calibration checks,
blanks and analytical matrix spikes were met in all cases.
Method Blank Analysis and Data Filtering
Each of the LEAF test methods specifies the collection of method blanks to be used to assess the potential
for measurement bias resulting from contamination of reagents and/or equipment used for the test or for
Appendix I contains all of the details of the ICP-OES analysis and QA/QC results for each measured constituent in each
provided analytical solution (i.e., filtered and preserved eluate sample). Therefore, due to its size, the appendix is made available
electronically by request to the authors, through the link to the document page on the EPA website, or as a download at
http: //vanderbilt. edu/leaching.
24
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the collection and storage of eluates. The process for determining if any quantifiable method blank
concentrations represent a significant impact on the statistical results of this study was developed for the
validation of Methods 1313 and 1316 (Garrabrants et al., 2012). The results of method blank analyses for
Method 1314 and Method 1315 are summarized in the following paragraphs and available in detail as
Appendix D.
Filtering due to Method Blanks
Chemical analysis of Method 1314 method blanks indicated very high concentrations of calcium (~27
mg/L) in JaFS material results for Laboratory 10 (L10). After discussions with the contact lead for L10,
the source of the high calcium was determined to be the 1 mM CaCl2 solution used as an eluent for the
column test (not initially reported) and not a contamination from reagents or from equipment surfaces.
Since there is a known cause of interference for the L10 samples, the effect of high calcium and high
chloride concentrations on the leaching of the ten selected analytes for the validation study was evaluated
to see if L10 results were candidates for "filtering for cause" (see discussion below). No other method
blank concentrations for Method 1314 results were found to be quantifiable. For Method 1315 results,
calcium and potassium were quantifiable in the method blanks for both SWA and CFS materials.
However, in all cases, method blank concentrations were less than 20% of associated eluate
concentrations and, therefore, no data were filtered due to method blank analysis.
Data Filtering for Cause
In addition to filtration due to method blank concentrations, Method 1314 and Method 1315 data were
evaluated to determine if filtration based on known causes of errors was necessary. The only identified
deviation from the validation study instructions was the aforementioned use of 1 mM CaCl2 solution by
L10 as a column eluent for Method 1314 testing of JaFS. While not strictly a procedural mistake since
the method does recommend this solution as a potential eluent for high organic matter or high clay
content material, the use of 1 mM CaCl2 could result in differences between L10 results and the
remaining dataset which might skew the validation study results.
L10 data were compared to the mean and 95% reproducibility limit intervals calculated for a dataset
assuming filtration of L10 results to test whether filtering of L10 data would make a difference in the
validation test outcome. The comparison showed changes only to the range of eluate concentrations for
Al, Ca, and Mg concentration and only at a few high-L/S targets. Since these minor differences were not
considered to affect the results of the overall method precision statistics, the L10 results were included in
the validation dataset and no data were filtered for cause.
METHOD 1314 RESULTS AND ANALYSIS
Method 1314 is an up-flow column leaching procedure intended to provide analytical samples of eluates
as a function of L/S. When combined with one or more analytical techniques, this method can be used to
demonstrate changes in liquid-solid partitioning (LSP) under percolation conditions. For each test, the
Method 1314 yields recorded information on the evolution of eluate pH from the column and analytical
samples for nine eluate fractions collected at increasing L/S.
25
-------
Evolution of pH from the Column
The evolution of eluate pH for the two Method 1314 validation study materials is shown in Figure 1. In
each of the two figure panels, pH results are presented for Method 1314 testing (i.e., "M1314" in legend)
of triplicate materials (i.e., replicates A, B, and C) conducted by each of six participating laboratories (i.e.,
L01, L06, L07, L10, LI 1 and L14) and for six test replicates conducted by the reference laboratory (i.e.,
Ref).10 The panels also show the mean of the collected pH values (red dashed line) and the interval
representing one standard deviation above and below the pH mean (solid orange line).
•y •
fi ^ -
fi -
I 8
0.
Ł 7 R
a
E 7 .
6C .
6.
0
• •
'• S- ,Ł 4
r df-c
r~: !
: % • !
l
CFS Material
ifr & $j
P'l D<» ^
* . i
* • B
•
L 10 10
L/S (L/kg)
1 10
L/S (L/kg)
100
•
o
0
•
M1314L01-A
M1314L07-A
M1314L11-A
M1314Ref-A
pH Mean
A M1314 L01-B
A M1314 L07-B
A M1314 Lll-B
A M1314 Ref-B
pH Overall SD
• M1314 L01-C
D M1314 L07-C
• M1314 Lll-C
• M1314 Ref-C
O
O
o
o
M1314 L06-A
M1314 L10-A
M1314 L14-A
M1314 Ref-D
A M1314L06-B
A M1314L10-B
A M1314L14-B
A M1314Ref-E
D
D
D
D
M1314L06-C
M1314L10-C
M1314L14-C
M1314Ref-F
Figure 1. Evolution of eluate pH from Method 1314 testing of validation study materials.
Note: Data shown for CFS contaminated field soil (left) and JaFS brass foundry sand (right). Statistics show mean and one
standard deviation interval about the mean of the pH data. Legend labels identify the leaching method (i.e., "Ml 314" for Method
1314), participating laboratory (e.g., "L01" for Laboratory One) and replicate (i.e., A, B, or C).
Eluate pH in the CFS material remained fairly constant throughout the test with a mean value of
approximately 6.9. Much of the laboratory data falls within one standard deviation of the pH mean. The
recorded pH data for L01, however, lie entirely below the lower standard deviation bound, indicating the
possibility of residual acid from cleaning in eluate collection bottles. The mean value of pH for the JaFS
material is slightly higher than CFS material with a mean pH rising from 7.8 to 8.3 over the L/S range of
L/S 0.2 to L/S 5 mL/g-dry. In all, most data for JaFS falls within one standard deviation of the mean with
L14 just above the upper standard deviation interval and L01, again, at the low end of the interval.
1 Similar data presentation structure and legend formatting are used throughout the report.
26
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Eluate Concentrations and Cumulative Release
The direct output of conducting the Method 1314 test is the eluate concentration as a function of L/S. For
use in environmental applications, the L/S value may be related to leaching time through the use of
scenario- or site-specific information (e.g., known fill geometry, rate of percolation or groundwater flow).
However, a convenient way to compare leaching at different L/S ratios is to report leaching results on the
basis of cumulative mass release (i.e., leached mass of a constituent per unit mass of material; often
referred to as either "cumulative release" or just "release"). Concentrations in any eluate fraction of
Method 13 14 may be converted to express leaching on a mass release basis by multiplying the eluate
concentration (mg/L) by the volume of eluate collected (L) and dividing by the mass of material in the
column (kg). These interval mass release values can be totaled to calculate the cumulative mass release
through a particular L/S value as:
where Relj is the cumulative mass release through the end of test fraction/ (mg/kg-dry)
Cj is the concentration in test fraction/ (mg/L)
Vj is the volume of eluate collected in test fraction/ (L)
m is the dry mass of test material in the column (kg -dry)
For the validation of Method 1314, the statistical analysis of both eluate concentration and cumulative
mass release was conducted for each of the two study materials (i.e., CFS and JaFS). Thus, method
precision estimates are reported for eluate concentration and cumulative release.
Consistency Check for LSP Data
The eluate concentration data collected for Method 13 14 represents the LSP established between the solid
material and the eluting liquid as a function of L/S. Thus, it is reasonable to assume that the LSP data for
Method 13 14 is related to the LSP data collected for eluate concentration in the Method 1313 pH-
dependence test. Although not specifically written into the method, a useful check for comparing the LSP
data and identifying species under solubility control (aqueous saturated) or highly soluble (aqueous sub-
saturation) species in the eluates of the L/S-based test (e.g., Method 1314, Method 13 16) is performed by
plotting both Method 13 14 eluate concentration and cumulative release data from the L/S-based test as a
function of pH against analogous results derived from Method 1313. The results are a visual indication of
whether or not solubility (i.e., the mineral dissolution at near-equilibrium conditions) in eluate controls
the concentration and that mass release (or cumulative mass release) for highly soluble species matches
for similar L/S values.
As an example, the Method 1314 results for CFS testing provided by the reference laboratory (black and
grey data) are presented in Figure 2 compared to the CFS statistics for Method 1313 (Garrabrants et al.,
2012). Each row in the figure shows the comparison of a single analyte in the CFS study material with
eluate concentration (left) and cumulative release (right). Method 1313 statistics include the mean of the
collected values (red dashed line) and the interval about the mean representing the overall standard
deviation interval (orange solid lines). The figure shows characteristic differences between the behavior
of highly soluble species (e.g., Na, K, Cl, B) present in solution at less than aqueous saturation and
"solubility-controlled" species present in solution at aqueous saturation for the given conditions.
27
-------
• Highly soluble species tend to exhibit pH-dependent leaching behavior that is a weak function of
pH but with a strong influence of the L/S ratio. Soluble constituents show the patterns displayed
by boron and thallium leaching from CFS where the eluate concentrations from Method 1314
"cut across" the Method 1313 data curve. This pattern indicates that eluate concentration for
these materials is controlled by the quantity of liquid phase present that dilutes the amount
available for leaching (i.e., the L/S ratio of the fraction) rather than by equilibrium between the
solid phase and a saturated solution (i.e., dissolution of minerals at equilibrium).
• Solubility-controlled species have eluate concentrations from Method 1314 that fall along the pH-
dependence curve independent of L/S ratio. Thus, the solid phase (i.e., the solubility of the
constituent provided by the dissolution of the solid minerals) controls the concentration through
solid-liquid equilibrium with a saturated solution. In Figure 2, this behavior is clearly shown for
the eluate concentrations of aluminum and molybdenum in the CFS.
Regardless of whether the constituent is soluble or solubility-controlled, the cumulative release data
for Method 1314 start at a value below the pH-dependent release curve at low L/S and increase to a
value corresponding to the Method 1313 release at L/S of 10 mL/g-dry which is the extraction L/S for
Method 1313 and the end point L/S for Method 1314. These two leaching behaviors are only two
examples of the complex liquid-solid leaching chemistry that influences eluate concentrations as
observed during the Method 1314 test. Additional factors include changes in pH, the presence of one
aqueous species complexing with another species (such as chloride complexing with cadmium or
dissolved organic carbon complexing with copper), and adsorption-desorption phenomena. A more
extensive comparison of pH dependence testing and column testing can be found in Lopez-Meza et
al. (2008).
28
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Aluminum (mg/L)
I b P ^58
j. l_i l_i l_i O O O
!
i
[
Metho
' ,
d 1314 L
0 2
(A)
1 -
I
•=• 0.1 -
0.01 -
1
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»
•
/s — '
10
.-
M1314 CFS-Ref-A
M1314 CFS-Ref-B
M1314 CFS-Ref-C
M1314 CFS-Ref-D
M1314 CFS-Ref-E
M1314 CFS-Ref-F
CFS M1313 Mean
CFS M1313 Overall SD
Met
hod 131
• «
4 L/S0 2
C=»
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1000 -i
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it 100 -
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• M1313 Mean M1313 Overall SD
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tf
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=^3
• • M1314 CFS-Ref-A A M1314 CFS-Ref-B
• M1314 CFS-Ref-C O M1314 CFS-Ref-D
A M1314 CFS-Ref-E D M1314 CFS-Ref-F
• M1313 Mean M1313 Overall SD
4 6 8 10 12 14 0 2 4 6 8 10 12
pH pH
(B) H
• M1314CF
A M1314CF
• M1314CF
i O M1314CF
A M1314CF
• M1314CF
. • M1313 Me
M1313 Ov
i '
:
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s-Ref-A
s-Ref-B
s-Ref-C
s-Ref-D
s-Ref-E
s-Ref-F
an
erall SD
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v«
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0 2
(C)
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L/S =
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14
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,
•
ethod 13 14 —
= 0.2 mL/g-dry
. /
//
t
'
14
r — k
^» // • M1314CF
=s^b^- - A M1314CF
rtfc • M1314CF
Sfi O M1314CF
Jh A M1314CF
^B • M1314CF
-*^^ • M1313 M(
M1313 Ov
4 6 8 10 12 14 0 2 4 6 8 10 12
pH pH
(C) H
• M1314 CFS-Ref-C O M1314 CFS-Ref-D
A M1314 CFS-Ref-E d M1314 CFS-Ref-F "3
• M1313 Mean M1313 Overall SD Ł* m
<
•^
^K^
d 1314 L/S10
, -Me
J • ~
thod 13
• ***"
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•
•
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•
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/L/s =
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•
S-Ref-A
S-Ref-B
S-Ref-C
S-Ref-D
S-Ref-E
an
erall SD
14
14
-dry
» •
M1314 CFS-Ref-A A M1314 CFS-Ref-B
M1314 CFS-Ref-C • M1314 CFS-Ref-D
M1314 CFS-Ref-E D M1314 CFS-Ref-F
M1313 Mean M1313 Overall SD
4 6 8 10 12 14 0 2 4 6 8 10 12
P" ,„, P"
14
Figure 2. Consistency check between Method 1314 data and LSP statistics from Method 1313.
Note: Eluate concentration (left) and cumulative release (right) from Method 1314 plotted as a function of eluate pH against the
mean and overall standard deviation interval for Method 1313 (Garrabrants et al., 2012). Comparisons shown for (A) aluminum
in CFS, (B) boron in CFS, (C) molybdenum in CFS and (D) thallium in CFS.
29
-------
Statistical Analysis of L/S-dependent Leaching
The results of the statistical analysis for each of the ten selected analytes for each material (see Table 7)
are presented as six-panel figures using the same data presentation approach as the validation of Method
1313 and Method 1316 (Garrabrants et al., 2012). Figure 3 shows an illustration of the data presentation
format for the statistical results for boron eluate concentrations from Method 1314 testing of CFS. The
analogous figures for cumulative release of boron, as well as both eluate concentration and cumulative
release for the remaining selected analytes, are presented in Appendix E.
Data presentation of statistical analysis includes the following panels:
Panel A - Test output derived from eluate concentrations and test information provided by the
participating laboratories.
Panel B - Comparison of the reference laboratory mean (green dots) and the 95% prediction limit
(PL; green dashed lines) to the median of all laboratory means (red squares) and the 95%
robust confidence limit (RCL; solid red lines). The 95% prediction limits provide the
bounds within which 95% of additional test replicates conducted by the reference
laboratory would fall. The 95% robust confidence interval represents the bounds within
which the mean concentration value from 95% of laboratories would fall.
Panel C - Overlay of the RCLs from Panel B against the interpolated/extrapolated data.
Panel D - Overall data mean (red dots) with standard deviation intervals about the mean associated
with "within-laboratory" variance (green short-dashed line), "between-laboratory" variance
(blue long-dashed line), and overall variance (solid gold line).
Panel E - The coefficient of variation corresponding to the "within-laboratory" (green short-dashed
line), "between-laboratory" (blue long-dashed line) and "overall" (solid gold line) standard
deviations as a percentage of the mean analyte concentration. Horizontal grey dashed lines
at 20% and 50% RSD are provided for reference.
The unlabeled panel in each figure is a legend indicating color-coding of data by participating laboratory
and shape-coding of test replicates. Example panels from this figure and the others in Appendix E are
used in the discussion below to illustrate key observations from the Method 1314 validation.
30
-------
2 o.oi •
o
CD
n nni -
q ^
s
^-*4 c?
"
\
ML
MDL
0.1
(A)
H i-H i-H i-
° g |
(I/Bui) uojog
0.0001 -
L 10 100
L/S (L/kg)
^
^
^
ML
MDL
I
2 o.oi -
o
CD
0.001 -
-^^§5
0 M1314 CFS Ref Mean
" M1314CFS Ref 95% P
• M1314 CFS Median o
^
5^5^
ML
L
Lab Means
0.1 1
L/S (L/kg)
D)
• M1314CFS-L01-A A M1314 CFS-L01-B •
O M1314CFS-L06-A A M1314 CFS-L06-B D
0 M1314CFS-L07-A A M1314 CFS-L07-B D
O M1314CFS-L10-A A M1314 CFS-L10-B D
• M1314CFS-L11-A A M1314 CFS-L11-B D
• M1314CFS-L14-A A M1314 CFS-L14-B D
• M1314CFS-Ref-A A M1314 CFS-Ref-B •
0 M1314CFS-Ref-D A M1314 CFS-Ref-E D
M1314 CFS 95% RCL
MDL
10
M1314CFS-L01-C
M1314 CFS-L06-C
M1314 CFS-L07-C
M1314CFS-L10-C
M1314CFS-L11-C
M1314CFS-L14-C
M1314 CFS-Ref-C
M1314 CFS-Ref-F
(C)
0.1
01
o
2
o
CD
L/S (L/kg)
0.1
(D)
L/S (L/kg)
10
0.01 •
0.001 -
"******»*.
^
^*«
*™
ML
M1314 CFS Overall SD (v]DL
• M1314 CFS Mean
bSD
100
2
o
CD
10 -•
1 ICP-OESRSD
M1314 CFS Overall CV
M1314 CFS Between Lab CV
M1314 CFS Within Lab CV
10
0.1
10
(E)
L/S (L/kg)
Figure 3. Example Method 1314 data presentation for boron eluate concentration in CFS material.
Note: Figure shows (A) collected data as a function of L/S; (B) reference laboratory mean and prediction limits at 95%
significance level (95% PL; green dashed line) compared to the median of laboratory means and median-based robust confidence
limits at 95% significance level (95% RCL; red line); (C) interpolated data and 95% RCL intervals; (D) intervals about the mean
of all data for "overall" (gold line), "between lab" (blue, dashed line) and pooled "within labs" (green, dotted line) standard
deviation; (E) coefficient of variation for "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty (grey dashed lines indicate 20% and 50% RSD).
31
-------
Linear Interpolation of log ^Transformed Data
When plotted as a function of L/S (see left side of Figure 4), the data set for the eluate concentrations
determined from analytical samples provided from each laboratory contains variance associated with both
the eluate concentration (y-axis) and recorded L/S values at each eluate collection interval (x-axis).
Although target L/S values and tolerances about these values are specified in the method, the L/S values
for the collected data reflect experimental variability because the participating laboratories conducted
Method 1314 manually, without the benefit of monitoring and switching equipment capable of precise
eluate collection. Thus, the values of L/S for each eluate fraction vary slightly between laboratories and
test replicates.
Method 1314 results were interpolated or extrapolated to the target L/S values specified in the leaching
procedure so that statistical analysis would reflect variances in eluate concentration (or cumulative release
as appropriate) and not include effects due to the variability of collection L/S values. The panels in each
row of Figure 4 show the effect of interpolation/extrapolation of logio-transformed eluate concentrations
on the validation data sets for boron in CFS and manganese in JaFS. Red vertical dashed lines in each
panel indicate the target L/S values specified in Method 1314. The collected eluate concentration data
(panel A) show variability in both concentration value (i.e., vertical direction) and in collection L/S (i.e.,
horizontal direction) while the L/S variation is removed by interpolation/extrapolation of data to target
values (panel B).
5 1 "
I
e
00
L_i!
s
O M1314CFS-A
A M1314CFS-B
D M1314CFS-C
Target L/S
_
*«
k
1
* ,n
^n
^ <*
JB «
.
L
?
I
&
00
0.1
(A)
0.1 -:
g1 0.01 -:
10
0.001
0.1
10
L/S (L/kg)
O M1314JaFS-A
A M1314JaFS-B
D M1314JaFS-C
Target L/S
1 !"!
M
i
i
10
(B)
L/S (L/kg)
1 -
0-1
^J
.014—
0.1
.
c
!
O M1314CFS-A
A M1314CFS-B
D M1314CFS-C
Target L/S
,
.
3
r |
E
1
3 ,
f
'
±
1
ii
ii
ii
ii
ii
ii
ii
ii
ii
ii
ii
ii
ii
ii
i "
1 s
*B
ii
ii
ii
' ' ' ' \ ' • — ' — ' • ' ' \ — •
1 10
(A)
0.1
(B)
L/S (L/kg)
nni -
I
I
I
I
I i
I
i i i i i
il
i —
I!
• M1314JaFS-A
A M1314JaFS-B
D M1314JaFS-C
Target L/S
r— J
1
1
II
II
II
II
II
II
II
II
II
1
10
L/S (L/kg)
Figure 4. Linear interpolation of logio-transformed eluate concentration data.
Note: Collected eluate concentration data with random L/S variance shown on left and Iog10-transformed data to interpolated
target L/S values on right for (A) boron in CFS material and (B) manganese in JaFS material. Red dashed lines indicate target
L/S values.
32
-------
Comparison of collected and interpolated data for the analytes in Figure 4 shows that there is little change
in the eluate concentration over the indicated interpolation/extrapolation interval and that any change in
concentration is consistent with the linear trend in the data set as a whole. No interpolated data fall
outside the general trend in the data set. Therefore, any minor variability induced by linear
interpolation/extrapolation of logic-transformed data will have little bearing on the precision of Method
1314 and is unlikely to influence environmental decisions based on interpolated data significantly.
Prediction Limit and Robust Confidence Limits
A selection of mean-based prediction limits for the reference laboratory data and median-based robust
confidence limits for all data is shown for selected analytes in Figure 5 (concentration) and Figure 6
(cumulative release). These graphs cover a limited set of the statistical results for illustrative purposes
while the full set of graphs for selected analytes in the two study materials is included in Appendix E.
The 95% prediction limits (95% PL; green dashed line) define the prediction interval about the reference
laboratory mean (green dots) within which future replicate measurements made by the reference
laboratory are expected to lie with 95% probability. The 95% robust confidence limits (95% RCL; red
solid lines) were calculated by setting a 95% confidence interval about the median of laboratory means
based on a merged dataset. In general, there was good agreement between the PL and the RCL, which
indicates that the reference laboratory data are consistent with the data set as a whole. For many analytes
(e.g., boron and lead in Figure 5), PL intervals fall directly within the RCL intervals and the mean of the
reference laboratory data is indistinguishable from the median of the laboratory means.
33
-------
1000
M1314 CFS Ref Mean
M 1314 CFS Ref 95% PL
M1314CFSMed an of Lab Means
Boron (mg
0.001
0.0001
1000
100
^ 10
0.1
0.01
0.001
0.0001
O M1314 JaFS Ref Mean
• M1314 JaFS Ref 95% PL
• M1314 JaFS Median of Lab Means
M1314 JaFS 95% RCL
__ML
MDL
0.1
0.1
10
(A)
L/S (L/kg)
0.1 - •
0.01 - r
0.001 - r
0.0001
r • M1314 CFS Ref Mean
M 1314 CFS Ref 95% PL
D M1314 CFS Median of Lab Me
M 1314 CFS Ref 95% RCL
ML
ans
0.1 -
0.01 -
0.001 --T
0.0001
M1314JaFS Ref Mea
M1314 JaFS 95% PL
M1314 JaFS Median of Lab Means
0.1
10
0.1
10
L/S(L/kg)
(B)
L/S (L/kg)
1
-E o.i -r
0.001
1 -
01 -
i="= — -m *=~ f^
1
0 M1314 CFS Ref Mean
• M1314 CFS Median of Lab Means
~ ^ ••« ^Tfl
ML
MDL
10
1 - •
I 0.1.;
0.01 - :
0.001
M1314JaFS Ref Mean
- M1314 JaFS Ref 95% PL
M1314 JaFS Median of Lab Means
-M1314JaFS95%RCL
0.1
10
0.1
10
(C)
L/S (L/kg)
(C)
L/S (L/kg)
100 -
10 -
1 -
inm -
SE3M—
O M1314 CFS Ref Mean
M1314CFSRef95% PL
f • M1314 CFS Median of Lab Means
MDL
M1314JaFS Ref Mean
M1314JaFS Ref 95% PL
M1314 JaFS Median of Lab Means
M1315 JaFS 95% RCL
0.1
10
0.1
(D)
L/S (L/kg)
(D)
L/S (L/kg)
Figure 5. Method 1314 95% prediction limits (95% PL) for eluate concentration from reference laboratory
results and 95% robust confidence limits (95% RCL) of all eluate concentrations.
Note: Comparisons for CFS material shown on left and JaFS material shown on right for (A) boron, (B) barium, (C) lead and (D)
34
-------
100
oi 10
1
-------
Standard Deviations Intervals and Coefficients of Variation
The standard deviation intervals about the overall data mean indicate the variance in data: (i) within-
laboratory statistics associated with repeatability, (ii) between-laboratory statistics, and (iii) with overall
method performance associated with method reproducibility. When compared to the overall coefficient
of variation, the coefficients of variation (CVs) for the between-laboratory and within-laboratory standard
deviation provide a sense of whether the overall variability (reproducibility) can be attributed to within-
laboratory (repeatability) or between laboratory variation components. Figure 7 and Figure 8 show
standard deviation above and below the mean value and CVs for selected analytes in three study materials
for eluate concentration and cumulative release, respectively.
The within-laboratory standard deviations (repeatability) are generally significantly less than the standard
deviations associated with between-laboratory or overall (reproducibility) standard deviations. For eluate
concentration, the overall CVs are approximately 10-30% and are relatively constant over the domain of
L/S values. The overall CVs for cumulative release in the first test fraction are consistent with the eluate
concentration values; however, the cumulative release CVs decrease with increasing L/S to values
between 5 and 20% at L/S 10 mL/g-dry.
36
-------
(A)
(B)
8.
o
CO
(C)
N
(D)
1 -
0.01 •
nm -
[ ffzSsss^ssKsaMS*****1*"*"*™**"*
ML
i M1314 CFS Overall SD 1*1 LH-
M1314 CFS Between Lab SD
: M1314CFS Within Lab SD
• M1314 CFS Mean
100
M1314 CFS Overall CV
- M1314 CFS Between Lab CV
-M1314 CFS Within Lab CV
• ICP-OES RSD
0.1
10
0.1
10
L/S (L/kg)
(A)
L/S (L/kg)
D)
w
I
o
0.01
0.001
M1314 CFS Overall SD
- M1314 CFS Between Lab SD
- M1314 CFS Within Lab SD
M1314 CFS Mean
100
M1314 CFS Overall CV
M1314 CFS Between Lab CV
M1314 CFS Within Lab CV
0.1
10
0.1
10
L/S (L/kg)
(B)
L/S (L/kg)
100 -
1 -
0.01 -
nnm -
*********"
, 'fc*"K*'vs=a=!,
M1314JaFS Overall SD
MU14Jarj Between Lab SD
• M1314JaFS Mean ML
MDL
100
M1314JaFS Overall CV
M1314 JaFS Between Lab CV
M1314 JaFS Within Lab CV
0.1
10
0.1
10
L/S (L/kg)
(C)
L/S (L/kg)
nni -
^^^tS:
*aS:as«Vs^
ML
M1314 JaFS Overall SD MDL
M1314 JaFS Within Lab SD
• M1314 JaFS Mean
100
10
N
Ss^=^sfaf=:^
• ICP-OES RSD
M1314 JaFS Overall CV
M1314 JaFS Between L
I ; ; ? — . '. .'". fi
==^=\^^
,'---.. j
abCV
CV
0.1
10
0.1
10
L/S (L/kg)
(D)
L/S (L/kg)
Figure 7. Example of Method 1314 variance component estimates and coefficients of variation for eluate
concentration.
Note: Data shown for mean and standard deviation on left and coefficient of variation on right for (A) lead in CFS, (B)
molybdenum in CFS, (C) boron in JaFS and (D) zinc in JaFS.
37
-------
100
^
O
d Rele
b
h-^
M1314 CFS Overall SD
• — M1314 CFS Between Lab SD
M1314 CFS Within Lab SD
• M1314 CFS Mean
0.001
100
d Rele
10
M1314 CFS Overall CV
M1314 CFS Between Lab CV
M1314 CFS Within Lab CV
• ICP-OESRSD
0.1
0.1
10
L/S(L/kg)
L/S(L/kg)
Ł, 0.1 -r
lybdenum Rele
0.01 - •
0.001 - :
0.0001
. — M1314 CFS Between Lab SD
M1314 CFS Within Lab SD
• M1314 CFS Mean
100
0.1
10
0.1
L/S(L/kg)
L/S(L/kg)
100
10
Release
0.1 - r
0.01 -r
l§ 0.001 -t
0.0001
• — M1314 JaFS Between Lab SD
M1314 JaFS Within Lab SD
• M1314 JaFS Mean
100
jg 10
&
I
o
CO
M1314 JaFS Overall CV
M1314 JaFS Between Lab CV
M1314 JaFS Within Lab CV
• ICP-OES RSD
0.1
0.1
10
(C)
L/S (L/kg)
/ v / ay
(c)
L/S (L/kg)
/ v / ay
01
E 01
g
a
10 -
_ — " M1314 JaFS Overall SD c
• ML""" ' M1314 JaFS Between Lab SD N
Mm • M1314 JaFS Mean
1 .
=^=
....
• ICP-OES RSD
M1314 JaFS Between Lab CV
0.1
10
0.1
10
(D)
L/S (L/kg)
(D)
L/S (L/kg)
Figure 8. Example of Method 1314 variance component estimates and coefficients of variation for
cumulative release.
Note: Data shown for mean and standard deviation on left and coefficient of variation on right for (A) lead in CFS, (B)
molybdenum in CFS, (C) boron in JaFS, and (D) zinc in JaFS.
38
-------
Method 1314Repeatability andReproducibility
Graphical representations of the precision statistics, comparing results for the two Method 1314 study
materials (i.e., CFS and JaFS), are available in Appendix D for each of the common analytes highlighted
in Table 7. Figure 9 presents an example of the precision statistics for barium. In each figure, eluate
concentration results are shown in the top row of panels while the results for cumulative release are
shown in the bottom row of panels. The left-hand panel illustrates the mean behavior of the result
parameter and the overall standard deviation interval of the validation data set. These panels also show
the various levels of the mass transport behavior for the study materials as a function of time. In the
middle and right-hand panels, respectively, the RSDr and the RSDR are plotted at target cumulative times.
In the RSDr and RSDR figures, grey dashed lines are used facilitate interpretation by indicating the RSD
values of 20% and 50%
The repeatability of Method 1314 for barium (Figure 9B) is approximately 3-10% for the majority of the
L/S range for both concentration and cumulative release. Eluate concentration shows a slight increase to
approximately 20% in the last test fraction at L/S of 10 mL/g-dry. Method reproducibility (Figure 9C)
tends to increase as L/S increases with reproducibility reaching 10-20% at L/S of 10 mL/g-dry.
Method 1314 Precision Data
Method precision for eluate concentrations of Method 1314 is shown in terms of relative standard
deviations for repeatability (Table 13) and reproducibility (Table 14). Similar data is shown for
cumulative flux repeatability and reproducibility in Table 15 and Table 16, respectively. In each of these
tables, the RSDr or RSDR represents the method precision calculated for each of the selected analytes at
each target L/S value.
39
-------
1 T
0.1 •:
0.001
M1314CFS Overall SD
M1314CFSMean
M1314JaFS Overall SD
M1314JaFSMean
100
L/S (L/kg)
L/S (L/kg)
.fl
'u
100 -r
10 -;
ICP-OES RSD
0.1
1
L/S (L/kg)
10
10 -r
1 --
M1314 CFS Release Overall SD
• M1314 CFS Release Mean
M1314 JaFS Release Overall SD
• M1314 JaFS Release Mean
I
&
IS
00
10 •
1 .
M1314 CFS Release RSD-r
"""— • -»^ ^___
ICP-OES-RSCr ^ ^^
1
^%
I
5
% 10 •
3
•o
Q.
IS
00
1 .
.______. .-^--^-
• ^^^^"
"^fc^^^ ^^ — '
ICP-OES RSD
M1314 CFS Release RSD-R
M1314JaFS Release RSD-R
1
0.1
10
0.1
10
L/S (L/kg)
L/S (L/kg)
L/S (L/kg)
Figure 9. Comparisons of statistical analyses for barium from Method 1314 validation study materials.
Note: Mean interval flux (upper) and cumulative release (lower) comparisons showing overall standard deviation intervals about the mean compared to method detection limits and
method limits of quantitation (left), repeatability relative standard deviation (RSDr) (center) and reproducibility relative standard deviation (RSDR) (right). Grey dashed line in
repeatability and reproducibility panels indicate 20% and 50% reference lines.
40
-------
Table 13. Method 1314 Eluate Concentration Repeatability (RSDr) across Study Materials
RSDr (%) at Target L/S Value (mL/g-dry)
CFS - Contaminated Field Soil
Analvte
Symbol 0.2
Aluminum Al
Barium Ba
Boron B
Calcium Ca
Cadmium Cd
Copper Cu
Molybdenum Mo
Lead Pb
Thallium Tl
Zinc Zn
11
7
9
2
8
11
14
7
9
8
11
6
9
4
10
15
8
9
10
14
9
4
7
5
8
8
8
6
7
6
18
4
4
1
7
12
12
10
4
6
10
5
5
2
5
12
11
7
3
6
9
o
3
6
1
5
6
9
2
5
8
8
3
7
1
5
11
10
3
6
7
5
3
8
3
7
5
12
3
6
7
9
7
12
7
9
8
25
7
10
9
JaFS - Brass Foundry Sand
Analyte
Symbol 0.2
Antimony Sb
Arsenic As
Barium Ba
Boron B
Calcium Ca
Chromium Cr
Cobalt Co
Molybdenum Mo
Selenium Se
Vanadium V
8
4
8
9
12
9
10
9
11
11
12
7
8
10
9
8
15
9
12
8
14
14
16
7
9
11
27
13
10
12
14
9
8
8
6
10
19
7
11
9
12
7
7
6
7
12
12
11
9
15
7
8
5
5
11
9
16
19
13
10
9
9
10
5
10
6
20
16
9
12
14
10
14
5
7
7
15
17
14
12
13
14
14
6
13
8
22
28
12
23
41
-------
Table 14. Method 1314 Eluate Concentration Reproducibility (RSDjO across Study Materials
RSDR (%) at Target L/S Value (mL/g-dry)
CFS - Contaminated Field Soil
Analvte
Symbol 0.2
Aluminum Al
Barium Ba
Boron B
Calcium Ca
Cadmium Cd
Copper Cu
Molybdenum Mo
Lead Pb
Thallium Tl
Zinc Zn
33
16
19
11
21
38
18
25
19
22
16
12
20
13
16
31
15
15
14
25
14
20
16
8
17
25
20
18
13
21
20
27
12
8
14
26
16
17
11
18
22
26
21
8
12
26
14
15
8
16
16
26
22
8
12
20
16
13
19
15
16
25
13
8
8
17
19
11
12
11
14
22
13
8
11
10
19
10
13
11
17
23
14
13
15
15
28
15
19
16
JaFS - Brass Foundry Sand
Analvte
Symbol 0.2
Aluminum Al
Barium Ba
Boron B
Calcium Ca
Copper Cu
Magnesium Mg
Manganese Mn
Molybdenum Mo
Lead Pb
Zinc Zn
15
8
27
21
31
25
28
36
16
34
20
14
18
34
20
25
27
20
13
26
24
20
31
20
18
28
47
22
13
33
14
17
18
21
18
23
32
9
13
34
12
11
18
19
24
23
26
15
15
35
17
24
21
32
28
32
31
19
22
29
17
27
21
36
30
37
29
20
25
26
30
22
26
47
30
49
25
32
29
35
28
24
24
52
32
53
27
54
24
58
42
-------
Table 15. Method 1314 Cumulative Release Repeatability (RSDr) across Study Materials
RSDr (%) at Target L/S Value (mL/g-dry)
CFS - Contaminated Field Soil
Analvte
Symbol 0.2
Aluminum Al
Barium Ba
Boron B
Calcium Ca
Cadmium Cd
Copper Cu
Molybdenum Mo
Lead Pb
Thallium Tl
Zinc Zn
12
7
9
2
8
11
15
7
10
8
10
5
5
2
7
12
7
6
6
9
7
3
4
3
6
9
5
5
4
8
9
o
3
4
2
6
8
5
4
4
7
9
o
3
4
2
6
7
5
3
4
6
6
3
3
1
4
6
6
2
3
5
5
3
3
1
4
6
5
2
3
5
4
o
J
3
1
2
4
5
2
o
J
4
5
3
3
2
2
4
4
2
3
4
JaFS - Brass Foundry Sand
Analyte
Symbol 0.2
Antimony Sb
Arsenic As
Barium Ba
Boron B
Calcium Ca
Chromium Cr
Cobalt Co
Molybdenum Mo
Selenium Se
Vanadium V
8
4
8
9
12
9
9
9
11
11
8
5
5
7
10
6
7
6
9
9
9
6
5
7
8
6
7
6
8
8
8
6
5
6
7
6
7
5
8
8
8
6
5
6
6
5
7
5
8
8
6
6
5
5
5
5
7
4
9
7
6
6
5
5
5
5
7
4
9
7
7
6
4
4
5
4
7
5
10
7
7
6
4
4
5
4
7
4
9
7
43
-------
Table 16. Method 1314 Cumulative Release Reproducibility (RSDjO across Study Materials
RSDR (%) at Target L/S Value (mL/g-dry)
CFS - Contaminated Field Soil
Analvte
Symbol 0.2
Aluminum Al
Barium Ba
Boron B
Calcium Ca
Cadmium Cd
Copper Cu
Molybdenum Mo
Lead Pb
Thallium Tl
Zinc Zn
34
16
20
11
22
38
18
24
20
22
23
12
17
12
17
32
10
18
14
21
18
15
14
9
16
28
9
17
13
21
17
19
13
9
15
26
10
15
12
20
17
21
13
9
14
25
9
15
11
18
15
24
12
8
11
21
10
13
10
15
15
24
12
8
11
20
11
13
10
14
14
23
11
8
8
16
12
11
10
11
14
23
11
8
9
15
12
11
10
11
JaFS - Brass Foundry Sand
Analyte
Symbol 0.2
Aluminum Al
Barium Ba
Boron B
Calcium Ca
Copper Cu
Magnesium Mg
Manganese Mn
Molybdenum Mo
Lead Pb
Zinc Zn
15
9
28
21
31
25
28
36
16
35
12
8
12
16
24
19
23
21
12
29
14
6
8
12
20
14
20
15
11
29
12
7
8
9
19
11
19
14
10
28
11
8
8
8
19
10
18
13
11
27
9
8
7
10
20
9
18
10
12
22
9
8
7
10
20
10
17
10
12
21
12
11
6
20
21
17
15
11
15
19
13
11
6
20
21
17
15
11
15
19
44
-------
Overall Method 1314 Precision
There are several possible approaches for summarizing the overall precision of Method 1314 due, in part,
to the trends in the RSDr and RSDR curves and the fact that both eluate concentration and cumulative
release are quantified. The choice of an approach depends on what L/S values are considered important
enough to warrant summarizing precision estimates. Note that eluate concentration statistics are fully
independent of each other while precision estimates for cumulative release carry some, albeit small,
amount of cumulative variance due to the way that mass release from individual eluates is accumulated.
The simplest approach summary is to average the precision estimates at the end of the test. The red boxes
in Figure 10 show the location of this summary method on the RSDR versus cumulative L/S graphs for
eluate concentration (left) and cumulative mass release (right). For this scenario, summarizing Method
1314 precision for release makes sense in that it uses the cumulative release at the end of the test (L/S of
10 mL/g-dry) to establish overall method precision. However, the precision for the analogous eluate
concentration point is simply the repeatability and reproducibility for one eluate in a series of relatively
independent eluates.
Concentration in 9th Fraction (L/S10)
100
L/S (L/kg)
01
Ł io
0)
ICP-OES RSD
Release through 2nd Fraction
(L/S = 0.5 mL/g-dry)
0.1
10
L/S (L/kg)
Figure 10. Illustration of scenarios used to summarize precision for Method 1314 eluate concentration (left)
and cumulative release (right).
Since Method 1314 data could be used to provide insight into porewater composition or initial field
leachate concentrations, an alternative scenario might be to look at precision at low L/S. However, the
concentrations and release in the very first eluate in any column procedure are often influenced by the
methodology used to wet the column as well as any surface wash-off from material particles, leading to
typically greater variability of eluate concentration than the variability seen at higher L/S. Therefore,
Method 1314 precision for both eluate concentration and cumulative release was also summarized at the
second eluate at a cumulative L/S of 0.5 mL/g-dry as shown in orange in Figure 10.
Altogether, this provides four scenario-based estimates of precision for Method 1314:
#1 Eluate Concentration in 2nd Fraction (L/S05)
#2 Eluate Concentration in 9th Fraction (L/Sio)
#3 Cumulative Release at L/S=0.5 mL/g-dry (release at end of 2nd test fraction)
45
-------
#4 Cumulative Release at L/S=10 mL/g-dry (release at end of 9th test fraction)
RSDr and RSDR values were tabulated by analyte and test material as shown for Scenario #1 in Table 17
to summarize precision in each scenario. A similar table for each of the other scenarios may be found in
Appendix E. For each material, the mean repeatability and reproducibility are calculated from the
precision values of the ten analytes used in the validation study. These material-based means are then
averaged to provide a single estimate of method repeatability and reproducibility for the scenario.
Table 17. Method 1314 Precision Estimates for Scenario #1 (Concentration in 2 Fraction).
Analyte
Aluminum
Barium
Boron
Cadmium
Calcium
Copper
Magnesium
Manganese
Molybdenum
Lead
Thallium
Zinc
Symbol
Al
Ba
B
Cd
Ca
Cu
Mg
Mn
Mo
Pb
Tl
Zn
Material Mean
Overall Mean
Repeatability Reproducibility
CFS JaFS CFS JaFS
%RSDr %RSDr %RSDR %RSDR
11.1
6.2
9.0
12.3
7.3
8.1
10.0
3.8
15.0
5.6
8.6
8.5
14.6
8.3
8.8
9.3
11.8
9.8
14.0
10%
8.0
16.0
11.5
19.6
19.7
13.6
17.6
15.8
13.1
31.1
33.7
20.3
25.4
26.9
14.6
15.5
19.8
12.9
14.3
24.7
10% 18%
26.4
22%
10% Repeatability 20% Reproducibility
Evaluation of the four summary scenarios indicates that precision values are relatively consistent for
eluate concentration (Table 18) and cumulative release (Table 19) with cumulative release having slightly
better precision.
Table 18. Method 1314 Precision Summary for Eluate Concentration.
Scenario
Concentration in 2nd Fraction
Repeatability
Reproducibility
Concentration in 9 Fraction
Mean Eluate Concentration Precision
The mean Method 1314 precision for eluate concentration was 12% repeatability and 24% reproducibility
while the mean Method 1314 precision for cumulative release was slightly better at 6% repeatability and
16% reproducibility. As a whole, the mean precision estimates for Method 1314 across all analytes, study
materials, and summarization scenarios were 9% repeatability and 20% reproducibility.
Table 19. Method 1314 Precision Summary for Cumulative Release
Scenario
Cumulative Release at L/S=0.5
Repeatability
Reproducibility
Cumulative Release at L/S=10
Mean Cumulative Release Precision
46
-------
Method 1314 Precision Compared to Other Leaching Method Validations
The guidance provided by the EPA (EPA, 1992b) and ASTM (ASTM, 1987) do not provide criteria for
acceptable precision; therefore, there is no conclusive basis for determining if the repeatability and
reproducibility determined for Method 1314 are acceptable. However, the precision results for Method
1314 may be evaluated in comparison to validation results for accepted and adopted leaching test methods
to provide context to the precision estimates from this validation study. Few precision estimates for
leaching methods are available in the literature; however, validation results for eluate concentration were
reported within the text of the German national column test, DIN 19528 (DIN, 2009). The reproducibility
of the current waste classification leaching test in the U.S, TCLP (EPA, 1992a) is also reported with the
method text.
DIN 19528 Repeatability and Reproducibility
The validation study for DIN 19528 encompasses a wide variety of waste types (e.g., soils, construction
rubble, municipal incinerator ash and steel slag) with up to 30 laboratories participating. Precision results
were calculated for inorganic constituents (e.g., As, Cr, Cu, Mo, Ni, Pb, Sb, V, Zn, Cl, F, SO4) and
several polycyclic aromatic hydrocarbons (e.g., naphthalene, anthracene, pyrene, chrysene,
benzo(a)pyrene).16 Only data based on inorganic constituent leaching are used for comparison to Method
1314 tests to allow for comparison to inorganic constituent data in the current LEAF method validation.
TCLP (SW-846 Method 1311) Reproducibility
The TCLP method provided reproducibility data for Cd, Cr, and Pb contained in three study materials
(e.g., ammonia lime still bottoms, a mixture of American Petroleum Institute separator sludge and
electroplating waste, and fossil fuel fly ash). Each of the three study materials was tested with both the
acetic acid and buffered acetic acid extraction fluids specified in the test method. The reported results of
interlaboratory validation of TCLP are a mean %RSDR of 74% with a range of results from 17-118%
(EPA, 1992b).
Comparison of Precision Distributions
The distributions of RSDr and RSDR for Method 1314 eluate concentrations for each of the two study
materials are presented in Figure 11 in comparison to distributions of precision data reported for DIN
19528 and TCLP. For each distribution, stacked boxes represent the interquartile range (IQR) of the 25th
and 75th percentiles with the median shown as the line dividing the boxes. Whiskers indicate the
maximum and minimum values obtained for each distribution. For Method 1314 and DIN 19528,
precision data are compared at a common L/S value of 1.0 mL/g-dry because the endpoint L/S for DIN
19528 is 4.0 mL/g-dry and the specified collection L/S values for the two column methods differ slightly.
For TCLP, only reproducibility data was reported and is shown for eluate concentrations as measured in
the single batch extraction. The dashed vertical line is used as a separator between the LEAF tests (left)
and the other leaching tests (right).
16 The list of constituents with reported precision values in DIN 19528 varied by material as not all constituents were present in
all tested materials.
47
-------
Q
2
100
80 -
60 -
i= 40 -
!a
JS
M1314-CFS
M1314-JaFS
DIN 19528
eproducibility RSDR (%)
D 8 Ł S § S
MaxRSD,
@ 139%
T
: ^ ^
OS u '
MaxRSD,
@ 118%
1
1
M1314-CFS
M1314-JaFS
DIN 19528
TCLP
Figure 11. Distribution of Method 1314 repeatability (RSDr) and reproducibility (RSDiO by study material
compared to precision estimates reported for DIN 19528 and TCLP.
Note: Distribution of precision values for Method 1314 and DIN 19528 provided at a common L/S value of 1 mL/g-dry. TCLP
distribution reflects the range of precision determined for the single batch test.
Method 1314 and DIN 19528 are both column percolation leaching tests designed to determine the
equilibrium-based leaching as a function of L/S, so it would be expected that the precision estimates for
these leaching tests are similar. In contrast, TCLP is an equilibrium-based screening procedure that is
operationally different that either of these tests. However, comparisons of precision distributions as
shown in Figure 11 are useful to put the current interlaboratory study into context with the precision of
accepted and widely used leaching test methods. The distributions shown indicate Method 1314 statistics
compare favorably to the precision of accepted and adopted national standards. The IQRs for Method
1314 repeatability are narrower and within or below the IQR of DIN 19528. Reproducibility IQR for
CFS is below the precision values for both DIN and TCLP while the IQR for JaFS is consistent with the
lower end of the dataset for DIN 19528. For both study materials, the IQR for Method 1314
reproducibility is considerably better than the reproducibility reported for TCLP.
48
-------
COMPARISON OF METHOD 1314 STATISTICS TO RESULTS OF EU TESTS
In addition to participation in Method 1314 validation, the Energy Research Centre of the Netherland
(ECN) conducted parallel testing of validation materials CFS and JaFS using an analogous percolation
column test method designated as a technical specification (TS)17 of the Comite Europeen de
Normalisation (CEN). Although initially designed to test waste materials, the approach of these methods
has been adapted under the International Standards Organization (ISO) program for soils and soil-like
materials (ISO/TS 21267, 2007).
The CEN/TS 14405 procedure is similar in intent and procedure to Method 1314 with minor differences
in the number of eluates collected and, hence, the prescribed L/S values. CEN/TS 14405 allows for
collection of an eluate at L/S 0.1 mL/g-dry not specified in Method 1314 due to limitations of eluate
volume at this low L/S. In addition, while Method 1314 specifies a flow rate based on L/S passing
through the column (dependent on the mass of solid in the column) while CEN/TS 14405 specifies flow
rate in terms eluate volume per time (independent of the solid mass).
Description of CEN/TS 14405 Procedure
The CEN/TS 14405 method determines the release of constituents from granular material packed into a
column with a leachant percolating through the column packing. The test conditions, including the flow
rate of the leachant, enable conclusions to be drawn from the results as to which components are rapidly
washed out and which components are released under the influence of interaction with the matrix.
Test material, with or without particle size reduction, is packed into either a 5-cm or a 10-cm diameter
plastic or glass column that is 30-cm long. Packing is achieved in a standardized manner with a plastic
rammer. Demineralized water leachant is percolated in up-flow through the column at a specified flow
rate of 12 mL/h for a 5-cm diameter column or 48 mL/h for a 10-cm diameter column. The eluate is
collected at seven fixed values of cumulative liquid-to-solid ratio or L/S (i.e., 0.1, 0.2, 0.5, 1.0, 2.0, 5.0
and 10.0 mL/g-dry). Each eluate is characterized physically and chemically for pH, conductivity and
concentrations of constituents of interest according to existing standard methods. In the test procedure,
equilibrium conditions at the outlet of the column are verified after an initial equilibration period by
measuring a pH deviation between a small amount of eluate (~15 mL) and the first test fraction at L/S 0.1
mL/g-dry. The results of the test are expressed as a function of L/S, in terms of both eluate concentration
(mg/L) and cumulative mass release (mg/kg-dry).
Comparison of EU Test Results to Method 1314 Statistics
In order to illustrate the comparability between LEAF Method 1314 and CEN/TS 14405, the results of
triplicate testing of CFS and JaFS using CEN/TS 14405 were plotted against the reproducibility limit
interval about the mean of the LEAF validation data. The reproducibility limit interval forms a band of
data within which results gathered under reproducibility conditions (e.g., same material tested with the
17 The "technical specification" or "TS" designation within CEN denotes a method that has resulted from a multi-national
consensus process and has been approved by a CEN technical committee, but has not yet completed interlaboratory validation
studies. Once method precision has been established, the method will require public comment and consensus approval by CEN
members to be designated as a full European standard (EN). Although the TS designation does not carry the status of an EN, TS
methods may be adopted as national standards and written into regulation.
49
-------
same method conducted by different operator using different equipment) may be considered to be
statistically equivalent. The assumption in this comparison is that CEN/TS 14405 and Method 1314 are
sufficiently similar that a sample tested using both methods yields similar results.
Figure 12 and Figure 13 show the comparison of CEN/TS 14405 cumulative release data to Method 1314
statistics values for eluate pH and a selection of analytes. In each figure, release from CFS is presented in
the panels on the left while release from JaFS is shown in the panels on the right. Similar comparisons
between LEAF and CEN results for a wide suite of analytes, including those not used in the validation,
are presented in Appendix G.
In general, there is excellent agreement between the L/S-dependent cumulative release from CEN/TS
14405 and the Method 1314 reproducibility limit intervals for most analytes in the two study materials.
Only CEN/TS 14405 data for barium and lead release from the brass foundry sand (JaFS) does not
directly fall within the Method 1314 reproducibility limit intervals. Since these comparisons are based on
cumulative release, a significant deviation in the concentration of the first test fraction (e.g., due to wash-
off or minor pH changes) does not affect the overall agreement for cumulative release. Based on these
data, the results derived from LEAF Method 1314 and the CEN/TS 14405 methods are consistent.
50
-------
7 -
fi -
— *
• CFS-Lll-144
A CFS-Lll-144
• CFS-Lll-144
M1315CFS
, I I •
05-A
05-B
05-C
Vlean
35% RL
fi -
X"
• *o^-
_-l
S*
r
O JaFS-Lll-14405-A
A JaFS-Lll-14405-B
D JaFS-Lll-14405-C
M1315 JaFS 95% RL
(C)
0.01 0.1 1 10 100
L/S (L/kg)
)
1
Aluminum Release (rr
I § P e
3 O O .
^ h-1 h-1 h
0.(
)
10 -
"3
Barium Release (mg/
I § P o
3 0 0 P
- ^^^xj
^^x^
D
X
X
ML ^ ;S
MDL X
X>^
X
X
X
X'x^
" • c
X * c
:
\
=S-L11-14405-A
=S-L11-14405-B
=S-L11-14405-C
1314 CFS Mean
1314 CFS 95% RL
)1 0.1 1 10 100
L/S (L/kg)
• CFS-L11-14405-A
A CFS-L11-14405-B
• CFS-L11-14405-C
M1314 CFS Mean
M1314 CFS 95% RL
C
ML x"'^ '
MDL .
~,#?'
^^'
X -X^^
X ./^
0.01 0.1 1 10 100
L/S (L/kg)
100 -
10 -
1 -
A CFS-L11-14405-B
r
j
IV
^**
ML -^"
DL ^f
• CFS-L11-14405-C
M1314 CFS 95% RL
— —jTni
^,-
^^
i
0.01
0.1
10
100
(D)
L/S (L/kg)
(D)
0.01
)
1 -
i1 0.1 -
c "•*•
Aluminum Re
I § f
3 0 C
^ h-1 h
Barium Release (mg/kg)
3 C
3 P 0 C
3 0 P o C
3 0 0 P l-> C
J. 1— L h- L h- L h- l O h-
O
0.1 1 10 100
L/S (L/kg)
• JaFS-Lll-14405-A
A JaFS-Lll-14405-B
• JaFS-Lll-14405-C
M1314 JaFS 95% RL
X
ML'^X
MDL x
.;
X
X ^^"
X -X
Jl 0.1 1 10 100
L/S (L/kg)
A JaFS-Lll-14405-B
D JaFS-Lll-14405-C
M1314 JaFS 95% RL
~ B
X
ML x'' X
MDL . — '
^&&^*
^
''/^
'
0.01 0.1 1 10 100
t L/S (L/kg)
•3 100-
"5 10 -
is
o 0-01 -
in 0.001 -
. ^
ML ^-"
+"»• •••
• JaFS-Lll-14405-A
A JaFS-Lll-14405-B
• JaFS-Lll-14405-C
M1314 JaFS 95% RL
— '
<^^
MDL
0.01 0.1 1 10 100
L/S (L/kg)
Figure 12. CEN/TS 14405 cumulative release compared to the Method 1314 statistics.
Note: Method 1314 statistics include the mean of the validation data and the reproducibility limit at the 95% significance level
(95% RCL). Comparisons shown with CFS material on the left and JaFS material on the right for (A) eluate pH, (B) aluminum,
(C) barium and (D) boron.
51
-------
o
u
0.01 -
n nnm -
J
\
^^
1 ^"
**
ML ''^-^'
1DL
""^^^^
--'"—-
-- • CFS-L11-14405-A
--^^ 4 C
D C
W
=S-L11-14405-B
=S-L11-14405-C
1314 CFS Mean
1314 CFS 95% RL
8
2.
8.
i_
a
o
u
10 -
1 -
.001 -
A JaFS
• JaFS
M13
b
L11-14405-B
L11-14405-C
14JaFSMean
14 JaFS 95% RL
I ^^
ML ^S^
DL
^^"
^
,
>
Lead Release (mg/kg)
I b P 5
A |_l |_l |_l O O
.01 0.1
L/S(
• CFS-L
A CFS-L
• CFS-L
M131
r
r ^
i
1 r
11-14405-A
11-14405-B
11-14405-C
4 CFS Mean
4 CFS 95% RL
&&*'
^
ML ,-'
/1DI
1 10 10
L/kg)
X^g
F*5^
i
'-/^
0.01 0.1 1 10 10
,B) L/S (L/kg)
0.01
0.1
10
100
(A)
L/S (L/kg)
100
10 - r
JaFS-Lll-14405-A
JaFS-Lll-14405-B
JaFS-Lll-14405-C
-M1314JaFS Mean
JaFS 95% RL
0.01
0.1
100
(B)
L/S (L/kg)
^ 1-1
Ol
?
Molybdenum Release (r
i § p c
D O O .
_i (_i (_i (j
— • CFS-L11-14405-A
A CFS-L11-14405-B
• CFS-L11-14405-C
X
M1314CFS95% RL
Ł
-•^
*Ł^
S
S
MDL
&***?
^
\
t 01-
R)
v>
Molybdenum R
1 § f
DOC
-1 h-1 h
: iv
i -*
ML ^^^
DL '
^f^^
/ /
.S » JaFS-Lll-14405-A
' A JaFS-Lll-14405-B
• JaFS-Lll-14405-C
M1314 JaFS 95% RL
(C)
(D)
Zinc Release (mg/kg)
0.01 0.1 1 10 100
L/S (L/kg)
100 -
10 -
0.1 -
0.001 -
r
r r
: M
.*»*
^,"
DL —
&JŁt^^
• CFS-L11-14405-A
i CFS-L11-14405-B
• CFS-L11-14405-C
M1314 CFS 95% RL
^<-
^^
0.01 0.1 1 10 100
L/S (L/kg)
(D)
0.
)
100 -
•3 10 •
E, 1
w 0.1 -
(O
U
c
N 0.001 -
31 0.1 1 10 10
L/S (L/kg)
A JaFS-
• JaFS-
M13]
.11-14405-B
.11-14405-C
4 JaFS Mean
4 JaFS 95% RL
• t^=
__--
ML *•' ^^
M1DL ^
ffr3^
^ **
^^
3
0.01 0.1 1 10 10
L/S (L/kg)
Figure 13. CEN/TS 14405 cumulative release compared to the Method 1314 statistics.
Note: Method 1314 statistics include the mean of the validation data and the reproducibility limit at the 95% significance level
(95% RCL). Comparisons shown with CFS material on the left and JaFS material on the right for (A) copper, (B) lead, (C)
molybdenum and (D) zinc.
52
-------
METHOD 1315 RESULTS AND ANALYSIS
Method 1315 is a semi-dynamic tank leaching test in which a single monolithic or compacted granular
sample is exposed to deionized water over a series of nine steps that follow a prescribed schedule of
leaching interval durations. The eluate concentrations from each interval may be used individually to
determine the mean interval flux (i.e., the mass of a constituent passing through a unit exposed surface
area) or combined to calculate the cumulative constituent released (i.e., the total mass of a constituent
released per unit exposed surface area). In addition, the pH measured for each leaching interval provides
an assessment of the evolution of eluate pH from the material as a function of leaching time.
Evolution of pH in Eluate from the Monolith and Compacted Granular Material
Figure 14 shows the evolution of pH in tank leaching eluates based on data recorded into the Method
1315 data template by the participating and reference laboratories. The data in each panel represents pH
evolution for six test replicates conducted by the reference laboratory (i.e., Ref) and triplicate tests
conducted by each participating laboratory. For the SWA material (left), eight participating laboratories
(i.e., L01, L04, L05, L06, L07, L09, L10 and LI 1) provided eluates while seven participating laboratories
(i.e., L01, L04, L05, L06, L07, L10 and LI 1) provided eluates for the CFS material (right). The eluate
pH values recorded by the validation laboratories are compared to the overall mean of all pH data (dashed
red line) and the interval representing one standard deviation above and below the pH mean (solid orange
line).
a.
&
a
0.01
0.1 1
Time (days)
Q.
&
a
14
12 -•
10 -•
8 -•
6 -•
0.01
CFS Material
1
Time (days)
10
100
•
o
o
o
•
M1315 L01-A
M1315 L05-A
M1315 L07-A
M1315 L10-A
M1315 Ref-A
pH Mean
A M1315 L01-B
A M1315 L05-B
.A M1315 L07-B
.A M1315 L10-B
A M1315 Ref-B
pH Overall SO
m
D
D
D
•
M1315 L01-C
M1315 L05-C
M1315 L07-C
M1315 L10-C
M1315 Ref-C
•
O
O
O
o
M1315 L04-A
M1315 L06-A
M1315 L09-A
M1315 Lll-A
M1315 Ref-D
A M1315 L04-B
A M1315 L06-B
A M1315 L09-B
A M1315 Lll-B
A M1315 Ref-E
•
D
D
D
D
M1315 L04-C
M1315 L06-C
M1315 L09-C
M1315 Lll-C
M1315 Ref-F
Figure 14. pH evolution in Method 1315.
Note: Data shown for monolithic SWA solidified waste analog (left) and compacted granular contaminated field soil (right).
Statistics show mean and one standard deviation interval about the mean of the pH data.
The pH evolution is relatively constant across the time domain for both materials with the pH values
representing the dissolution and transport of alkaline constituents from SWA and near neutral constituents
53
-------
from CFS. The mean value of pH for SWA material ranges from 10.8 to 11.5 while the mean pH for the
CFS material is approximately 6.5. The high pH evolution for SWA is due to the dissolution of alkaline
minerals formed during hydration and curing of the cementitious components of the SWA material.
Collected Eluate Concentration Data
While conducting Method 1315, the constituent concentrations in the test eluates are measured as a
preliminary step in determining the rates of mass transfer. Eluate concentrations from Method 1315 are
not typically recommended as the metric for use in environmental assessments but rather are an
intermediate measurement for calculation of more useful parameters. Therefore, eluate concentration was
not used as the evaluation basis in the statistical analysis and validation of Method 1315. However, the
concentrations of selected analytes measured by ICP-OES at VU are available in Appendix F as part of
the documentation for this validation study. In Figure 15 and Figure 16, eluate concentrations are
presented for a selected set of analytes for SWA and CFS, respectively.
54
-------
"5 o.i -
c
S3 0.01 -
0.001 -
0.
1 -
^. 0.1 -
I
Ą
'a 0.01 -
00
0.001 -
0
100 -
10 -
•I o-i •
s
0.01 -
0.001 -
0
I
Ą
3
'E
01
& 1 H BIL
ft g B H B Hl|g
i a
ML
01 0.1 1 10 1C
Time (days)
|i PIS
A
y
ML
. . . PIP!,
01 0.1 1 10 1C
Time (days)
i
[ i
1
™
SS •
«•*
ML
MDL
01 0.1 1 10 1C
Time (days)
r «
!| !|ly
&k
ML
MDL
0.01 0.1 1 10 1C
Time (days)
^
1 :
0.0
I
i
0
E
0.001
0
D
• n
rS ^ a H H n
ft 1 1 °|f
ML
MDL
1 0.1 1 10 1C
Time (days)
i M w
ML
MP1,
01 0.1 1 10 1C
Time (days)
Ł A R BR
?' o fi ° B ^%&
IB
ML
MDL
01 0.1 1 10 1C
Time (days)
•
•
•
o
o
•
o
o
•
o
SWA-L01-A
SWA-L04-A
SWA-L05-A
SWA-L06-A
SWA-L07-A
SWA-L09-A
SWA-L10-A
SWA-L11-A
SWA-Ref-A
SWA-Ref-D
ML
A
A
A
A
A
A
A
A
A
A
SWA-L01-B
SWA-L04-B
SWA-L05-B
SWA-L06-B
SWA-L07-B
SWA-L09-B
SWA-L10-B
SWA-L11-B
SWA-Ref-B
SWA-Ref-E
— IVI DL
•
D
D
n
D
n
D
n
•
n
SWA-LOl-C
SWA-L04-C
SWA-L05-C
SWA-L06-C
SWA-L07-C
SWA-L09-C
SWA-L10-C
SWA-L11-C
SWA-Ref-C
SWA-Ref-F
Figure 15. Example collected eluate concentration results from Method 1315 testing of SWA material.
55
-------
i
c
I
i
o
CO
Ol
Ą
3
i
Ą
3
'E
01
Ol
in
0.1 -
0.01 -
0.001 -
0
1 -
0.1 -
0.01 -
0.001 -
0
1000 -
100 -
10 -
1 -
0.1 -
0.01 -
0.001 -
0.
0.1 -:
ML
: MDL •
ad)
01
as IB Bfili
0.1
1 10 1C
Time (days)
. o §4*
: ^ 8 1
^
01
I
1 — •
[
0.1
ti
i
ML
MDL
1 10 1C
Time (days)
<
,. °°B<*
ML
MDL
01
0.1
ML
MDL _ QW
1 10 1C
Time (days)
$
m n
&-14L
I § ^*1P
ll I
0.01
0.1
1 10 1C
Time (days)
I
•c
0.1 •:
0.01
0.001
10
o.i
5 o.oi
0.001
0.01
Z? 0.1 ••
o.oi
0.001
0.01
ML
0.01 0.1 1 10 100
Time (days)
0 B
MDL
0.1 1
Time (days)
10
100
ML
MDL
0.1 1
Time (days)
10
100
•
•
0
o
0
o
•
o
CFS-L01-A
CFS-L04-A
CFS-L06-A
CFS-L07-A
CFS-L10-A
CFS-L11-A
CFS-Ref-A
CFS-Ref-D
IVIL
A CFS-L01-B
A CFS-L04-B
-i CFS-L06-B
-i CFS-L07-B
-i CFS-L10-B
A CFS-L11-B
A CFS-Ref-B
A CFS-Ref-E
•
n
n
n
n
n
•
n
CFS-LOl-C
CFS-L04-C
CFS-L06-C
CFS-L07-C
CFS-L10-C
CFS-L11-C
CFS-Ref-C
CFS-Ref-F
Figure 16. Example collected eluate concentration results from Method 1315 testing of CFS material.
56
-------
Consistency Check for Saturated Eluates
Results from monolith mass transfer leaching tests, such as Method 1315, are often used to calculate
apparent diffusivities for the release of individual constituents, assuming simple Fickian diffusion from an
infinite solid into an infinite bath maintaining a dilute solution (Crank, 1975). For the infinite bath
assumptions implied in this calculation to be valid, the eluate concentration must remain dilute relative to
aqueous saturation. The dilute solution assumption for individual constituents in each eluate can be
verified by plotting the concentrations of individual constituents in eluates from Method 1315 in
conjunction with the results from Method 1313 (pH dependent leaching) as shown in Figure 17. If the
Method 1315 eluate concentrations are substantially lower than the Method 1313 eluate concentrations
measured at the same end-point pH (e.g., less than ca. 50% of the Method 1313 value), then the dilute
solution assumption is considered valid. For the cases displayed in Figure 17, the dilute solution
assumption would be considered valid for all eluates from Method 1315 except for a few eluates
associated with boron and selenium for the CFS sample.
57
-------
100
01
0.01
0.001
M1315 SWA-Ref-A
M1315 SWA-Ref-C
M1315 SWA-Ref-E
M1313 Mean
M1315 SWA-Ref-B
M1315 SWA-Ref-D
M1315 SWA-Ref-F
M1313 Overall SD
=F
=F
8
1 i '
10
_ML
MDL
12
14
(A)
PH
01
E
I
0.001
0.0001
1 -
1 -
«
t • j-
• p
A r
• r
- • r
A r
• r
f
,11315 SWA-Ref-A
,11315 SWA-Ref-B
,11315 SWA-Ref-C
,11315 SWA-Ref-D
,11315 SWA-Ref-E
,11315 SWA-Ref-F
,11313 Mean
,11313 Overall SD
— fc ^_
^*=^
^^;
^ -
"^S^^ I
flp
•
i .X
ML
MDL
10
12
14
(B)
PH
(B)
Ol
C -,
0 1
1 o.i-
1
** 0.01 -
0
)
10
1
01 o.l
| 0.01
1
0.001
0.0001
I
ML
MDL
^~-
V
aflfiP
M1315 CFS-Ref-A
M1315 CFS-Ref-B
M1315 CFS-Ref-C
M1315 CFS-Ref-D
M1315 CFS-Ref-E
M1315 CFS-Ref-F
M1313Mean
M1313 Overall SD
JL., ••-,
\»^
"*C
2 4 6 8 10 12 14
PH
•
«^^
• • • ,
• M1315C
A M1315C
• M1315C
MDL A M1315C
C3 —
FS-Ref-A
FS-Ref-B
FS-Ref-C
FS-Ref-D
FS-Ref-E
D M1315 CFS-Ref-F
• M1313 Mean
M1313 Overall SD
0 2 4 6 8 10 12 14
PH
Selenium (mg/L)
p ^ 5 i
I-* (-* O O C
1
;
r
r
<
• '
^
• M1315 SWA-Ref-A
A M1315 SWA-Ref-B
• M1315 SWA-Ref-C
• M1315 SWA-Ref-D
A M1315 SWA-Ref-E
D M1315 SWA-Ref-F
• M1313 Mean
M1313 Overall SD
• 1
» •
• 1
"1
B
1=3 —
ML
MDL
0 2 4 6 8 10 12 1
1000
Ol
I
^
a
I
1 •
0.1 •
.001 •
I c
r
• M1315 SWA-Ref-C O M1315 SWA-Ref-D
A M1315 SWA-Ref-E • M1315 SWA-Ref-F
• M1313 Mean M1313 Overall SD
:\
»
ML
• '
'• MDL
' •
^tr
•
01
•o
a
0.1 -
0.01 -
.001 -1
4
• M1315 CFS-Ref-A A M1315 CFS-Ref-B
• M1315 CFS-Ref-C O M1315 CFS-Ref-D
A M1315 CFS-Ref-E D M1315 CFS-Ref-F
• M1313Mean M1313 Overall SD
'
1
E^j.
«
E
nPa
Off
_a «
• •
ML
MDL
(D)
6 8
PH
10
12
14
10
12
14
(D)
PH
Figure 17. Consistency check between M1315 eluate concentrations and M1313 statistics.
Note: M1313 mean and standard deviation interval derived from validation of M1313 (Garrabrants et al, 2012). Comparisons
shown for SWA material on left and CFS material on right for (A) antimony, (B) boron, (C) selenium and (D) vanadium.
58
-------
Interval Flux and Cumulative Release
Using the measured eluate concentrations, the mean interval flux and cumulative mass release are derived
from test parameters such as eluate volume, interval duration and sample surface area. Mean interval flux
represents the average mass released across a unit exposed surface area during a particular leaching
interval. Mean interval flux is calculated from collected and measured test information as:
F- •
"
where Fj is the mean interval flux over test fraction/ (mg/m2 s)
Cj is the concentration in test fraction/ (mg/L)
Vj is the volume of eluate collected in test fraction /(L)
As is the surface area of the test specimen exposed to eluent (m2)
TJ is the cumulative time at the end of test fraction/ (s)
Tj_2 is the cumulative time at the end of test fraction j-1 (s)
The total mass released across a unit exposed surface area from the beginning of the test through the end
of a particular leaching interval/ is the cumulative release through leaching interval/. Cumulative release
is essentially the integration of the interval flux curve as a function of cumulative leaching time but is
often calculated directly from collected and measured test information as:
i C -v
Rel . =y_/_^L
3 i 4
where Relj is the cumulative release through the end of test fraction/ (mg/m2)
Cj is the concentration in test fraction/ (mg/L)
Vj is the volume of eluate collected in test fraction/ (L)
As is the surface area of the test specimen exposed to eluent (m2)
For this validation study, the mean interval flux and cumulative release were calculated within LeachXS
using the eluate concentrations measured at VU and the test information for each set of test results
provided by the participating reference laboratories. These test outputs were used in the statistical
analysis of selected analytes (Table 7) to estimate precision for Method 1315 testing of SWA and CFS.
Statistical Analysis of Method 1315 Output
For the validation of Method 1315, the results of statistical analysis for the two study materials (i.e., SWA
and CFS) are presented as six-panel figures in Appendix F. Statistical analysis was conducted separately
for mean interval flux and cumulative release. Each six-panel figure shows the results of statistical
analysis for a single analyte in a material (e.g., antimony in SWA, calcium in CFS) in the same manner
used to present data for Method 1314.
Figure 18 shows an illustration of the six-panel data presentation as the statistical result for the mean
interval flux of antimony from Method 1315 testing of SWA study material. An analogous figure is
presented in Appendix F for antimony cumulative release from SWA. Data presentation of statistical
analysis includes the following panels:
59
-------
Panel A - Test output data derived from measured eluate concentrations and test information
provided by the participating laboratories.
Panel B - Comparison of the reference laboratory mean (green dots) and the 95% prediction limit
(PL; green dashed lines) to median of all laboratory means (red squares) and the 95%
robust confidence limit (RCL; red solid lines). The 95% prediction limits provide the
bounds within which 95% of additional test replicates conducted by the reference
laboratory would fall. The 95% robust confidence interval represents that bounds within
which the mean concentration value from 95% of laboratories would fall.
Panel C - Overlay of the RCLs from Panel B against the interpolated/extrapolated data.
Panel D - Overall data mean (red dots) with standard deviations intervals about the mean associated
with "within-laboratory" variance (green short-dashed line), "between-laboratory" variance
(blue long-dashed line), and overall variance (gold solid line).
Panel E - The coefficient of variation corresponding to the "within-laboratory" (green short-dashed
line), "between-laboratory" (blue long-dashed line) and "overall" (gold solid line) standard
deviations as a percentage of the mean analyte concentration.
The sixth panel of each figure is a legend indicating color-coding by participating laboratory and shape-
coding for test replicates applied to the collected (Panel A) and interpolated/extrapolated data (Panel C).
In the discussion below, example panels from the figures in Appendix F are selected to illustrate key
observations of the Method 1315 validation.
60
-------
I 0.01 -
(N
"5; °-001 •
Ł• o.oooi -
o
c 0.00001 -
n nnnnm -
, 1
:
1
1
H F&-f
t
0.01 0.1 1 10 1C
Time (days)
"Ł 0.01 -
IN
"oi °-001 •
E
^>
Ł• o.oooi •
c 0.00001 •
<
.
i U
1
^
^fc^
^^4
«
0.01 0.1 1 10 1C
Time (days)
(C)
"Ł 0.01 -
IN
"oi °-001 '
E
^>
Ł• o.oooi •
c 0.00001 •
<
c
1
• M1315 SWA-Flux Mean
— Between LabSD
^W
*^s^
\
0.01 0.1 1 10 1C
O1
0.1
0.01
0.001 - •
0.000001
O SWA-FluxRefMean
SWA-Flux Ref 95% PL
• SWA-Flux Median of Lab Means
SWA-Flux 95% RCL
0.01
(B)
0.1 1 10
Time (days)
•
•
o
o
o
o
o
o
•
o
—
SWA-FluxLOl-A
SWA-FluxL04-A
SWA-FluxL05-A
SWA-FluxL06-A
SWA-FluxL07-A
SWA-FluxL09-A
SWA-FluxLlO-A
SWA-Flux Lll-A
SWA-FluxRef-A
SWA-FluxRef-D
SWA-Flux 95% RCL
A
A
A
A
A
A
A
A
A
A
SWA-FluxLOl-B
SWA-FluxL04-B
SWA-FluxL05-B
SWA-FluxL06-B
SWA-FluxL07-B
SWA-FluxL09-B
SWA-FluxLlO-B
SWA-Flux Lll-B
SWA-Flux Ref-B
SWA-Flux Ref-E
•
D
D
D
D
D
D
D
•
D
SWA-Flux L01-C
SWA-Flux L04-C
SWA-Flux L05-C
SWA-Flux L06-C
SWA-Flux L07-C
SWA-Flux L09-C
SWA-Flux L10-C
SWA-Flux Lll-C
SWA-Flux Ref-C
SWA-Flux Ref-F
o
M1315 SWA Overail CV
M1315 SWA Between Lab CV
M1315 SWA Within Lab CV
0.01
0.1
10
100
(D)
Time (days)
(E)
Time (days)
Figure 18. Method 1315 data presentation for antimony interval flux for material SWA.
Note: Figure shows (A) collected data as a function of time; (B) reference laboratory mean and prediction limits at 95%
significance level (95% PL; green dashed line) compared to the median of laboratory means and median-based robust confidence
limits at 95% significance level (95% RCL; red line); (C) interpolated data and 95% RCL intervals; (D) intervals about the mean
of all data for "overall" (gold line), "between lab" (blue, dashed line) and pooled "within labs" (green, dotted line) standard
deviation; (E) coefficient of variation for "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty (grey dashed lines indicate 20% and 50%).
61
-------
Linear Interpolation of loglO-transformed Data
The output of Method 1315 (i.e., interval flux or cumulative release) was logio-transformed and
interpolated/extrapolated to the target time values specified in the method text. The effect of linear
interpolation of logio-transformed data on the range of interval flux values is presented in Figure 19 for
arsenic in SWA and cadmium in CFS. These examples show only minor differences in the vertical spread
of the data, primarily in the last test fraction, which were not considered significant enough to change the
outcome of the validation study.
w
I
(A)
0.001 -
0.00001 -
— |
1
[
?
"
O M1315 SWA-Flux-A
A M1315 SWA-Flux-B
• M1315 SWA-Flux-C
TargetTime
i
n
i ....
'l
!i
u
u
u
u
u
u
u
1 1
u
1 1
u
u
u
u
Ift
in
ni
u
. 4 L
f
Ml
8
IN
Ol
u
'E
01
1
0.01 0.1 1 10 100
Time (days)
I
E
3
E
•o
5
0.0001 -
nnnm .
.
« I
0 M1315CFS-FIUX-A
A M1315CFS-FIUX-B
D M1315CFS-FIUX-C
Target Time
!!
L.
1
J
L|
<
u
u
u
u
u
u
u
1 1
n
n
u
$
r II
II
II
II
II
. .1 L
I
\
1
(B)
0.01 0.1 1 10
Time (days)
100
U.UJ.
0.001 -
0.0001 -
0.00001 -
nnnnm -
•
^ 1
.
1
1
i L
H
a K
i 1 i
: O M1315 SWA-Flux-A
A M1315 SWA-Flux-B
• M1315 SWA-Flux-C
TargetTime
1
8 1 r
"
1 c
. i i i ii.
B
1
,
u
u
u
u
u
u
u
1 1
u
u
u
u
u
u
u
1 1
j i j...
0.01
0.1
10
100
Time (days)
(B)
I
NŁ 0.001 -
1
^>
E
•| 0.0001 -
•O
3
-1
• M1315 CFS-Flux-A
A M1315 CFS-Flux-B
• M1315 CFS-Flux-C
Target Time
!!
j
1 j
h
'I
n
n
n i
n i
n i
0.01 0.1 1 10 10
Time (days)
Figure 19. Linear interpolation of Iog10-transformed interval flux data.
Note: Calculated interval flux with random time variance on left and transformed data to interpolated target collection times on
right for (A) arsenic in SWA material and (B) cadmium in CFS material.
Prediction Limit and Robust Confidence Limits
The mean-based prediction limits for the reference laboratory data and median-based robust confidence
limits for Method 1315 dataset as a whole were compared. The full set of comparisons for interval flux
and cumulative release results for the selected analytes in the two study materials are included in
Appendix F. Examples of comparisons for interval flux in Figure 20 and cumulative release in Figure 21
cover a limited set of the statistical results for illustrative purposes. In each of these figures, leaching
from the monolithic SWA material is shown in the panels on the left while leaching from compacted
granular CFS is shown on the right.
62
-------
The 95% Prediction Limits (PL; dashed green line) define a band of data about the reference laboratory
mean (green dot) that delineates a repeatability operating characteristic for the reference laboratory in the
sense that one would expect 95% of all replicate measurements made by the reference laboratory to lie
within these bounds. The 95% Robust Confidence Limits (RCL; solid red lines) were calculated by
merging all laboratory data, calculating the median of the laboratory means and setting the 95%
confidence interval about that median. In general, there was good agreement between the PL and the
RCL with the mean and PL for the reference laboratory falling directly within the RCL intervals for many
analytes. These observations indicate that the reference laboratory data are consistent with the data set as
a whole.
Comparison of the RCL curves between the study material for all three analytes in Figure 20 shows that
the SWA data tends to have wider spread in the first leaching interval (i.e., greater variability) than does
the CFS data. The effect is less noticeable, but still evident, in the cumulative release RCL values for the
analytes shown in Figure 21. The greater variability in the first interval of the SWA data is likely due to
wash-off of precipitated minerals from curing or leftover debris from cutting the monolithic material prior
to testing.
63
-------
0.01
gj 0.001 -
in
E
•5 o.oooi
Ł• o.ooooi
c 0.000001
^
0.0000001
SWA-FluxRef Mean
-SWA-FluxRef95%PL
SWA-Flux Median of Lab Means
-SWA-Flux95% RCL
"t-
0.01
ji! 0.001 - r
E
•5 o.oooi
Ł• 0.00001
c 0.000001 - r
0.0000001
O CFS-Flux Ref Mean
CFS-Flux Ref 95% PL
• CFS-Flux Median of Lab Means
CFS-Flux 95% RCL
0.01
0.1
10
100
0.01
0.1
10
100
Time (days)
(A)
Time (days)
CFS-Flux Ref Mea
CFS-Flux Ref 95% PL
• CFS-Flux Median of Lab Means
CFS-Flux 95% RCL
tA/A-Flux Ret Mea
SWA-Flux Ref 95% PL
• SWA-Flux Median of Lab Means
SWA-Flux 95% RCL
0.000001
0.01
0.1
100
0.01
(B)
Time (days)
(B)
0.1 1 10
Time (days)
100
E
(C)
1
0.1
0.01
0.001
0.0001
0.00001
0.000001
0.0000001
C
0.001
• SWA-Flux Ref Mean
SWA-Flux Ref 95% PL
• SWA-Flux Median of Lab Means
SWA-Flux 95% RCL
0.01
"")—
0.1
"4—
10
100
Time (days)
(C)
1
0.1
0.01
0.001 - r
0.0001 - r
0.00001 - f
0.000001
0.0000001
O CFS-Flux Ref Mean
CFS-Flux Ref 95% PL
• CFS-Flux Median of Lab Means
CFS-Flux 95% RCL
0.01 0.1 1 10
Time (days)
100
0.000001 -
$
0.0000001
SWA-Flux Ref Mean
SWA-Flux Ref 95% PL
• SWA-Flux Median of Lab Means
SWA-Flux 95% RCL
0.01
"")—
0.1
0.001
CFS-Flux Ref Mean
-CFS-Flux Ref 95% PL
CFS-Flux Median of Lab Means
-CFS-Flux 95% RCL
10
(D)
Time (days)
0.0000001
100 0.01
(D)
0.1 1 10
Time (days)
100
Figure 20. Method 1315 95% prediction limits (95% PLs) for mean interval flux from reference laboratory
results and 95% robust confidence limits (95%RCLs) of all laboratories for interval flux.
Note: Comparisons shown for SWA material shown on left and CFS material shown on right for (A) antimony, (B) barium, (C)
selenium and (D) vanadium.
64
-------
1000
100 -
0.1
SWA-Release Ref Mean
-SWA-Release Ref 95% PL
SWA-Release Median of Lab Means
-SWA-Release 95% RCL
1000
0.1
CFS-Release Ref 95% PL
CFS-Release Ref Mean
CFS-Release Median of Lab Means
-CFS-Release 95% RCL
0.01
0.1
10
100
0.01
0.1
10
100
(A)
Time (days)
(A)
Time (days)
100000 -E-
10000 - •
>-' 1000
100 -r
E
I
1
10
-SWA-Release Ref 95% PL
SWA-Release Ref Mean
SWA-Release Median of Lab Means
-SWA-Release 95% RCL
100000
CFS-Release Ref 95% PL
CFS-Release Ref Mean
CFS-Release Median of Lab Means
CFS-Release 95% RCL
10
0.01
0.1
10
100
0.01
0.1
10
100
(B)
Time (days)
10000
1000
-SWA-Release Ref 95% PL
SWA-Release Ref Mean
SWA-Release Median of Lab Means
-SWA-Release 95% RCL
(B)
M**
i
Ą
Time (days)
10000
1000
100
10
o.i
CFS-Release Ref 95% PL
CFS-Release Ref Mean
CFS-Release Median of Lab Means
-CFS-Release 95% RCL
0.01
0.1
10
100
0.01
0.1
10
100
(C)
Time (days)
(C)
Time (days)
100
10 -•
0.1
— SWA-Release Ref 95% PL
O SWA-Release Ref Mean
• SWA-Release Median of Lab Means
SWA-Release 95% RCL
0.01
-CFS-Release Ref 95% PL
O CFS-Release Ref Mean
D CFS-Release Median of Lab Means
CFS-Release 95% RCL
"t-
(D)
0.01 0.1 1
Time (days)
10
100
(D)
0.01 0.1 1
Time (days)
10
100
Figure 21. Method 1315 95% prediction limits (95% PLs) for cumulative release from reference laboratory
results and 95% robust confidence limits (95% RCLs) of all laboratories for cumulative release.
Note: Comparisons shown for SWA material shown on left and CFS material shown on right for (A) boron, (B) calcium, (C)
selenium and (D) vanadium.
65
-------
Standard Deviation Intervals and Coefficients of Variation
The standard deviations associated "within-laboratory," "between-laboratory" and "overall" variance
components were determined from ANOVA calculations of Iogi0-transformed data. Intervals for these
standard deviations about the mean of the validation dataset were calculated as shown in the left-hand
side of Figure 22 for interval flux and Figure 23 for cumulative release for illustrative analytes from the
study materials. On the right-hand side of each figure, the coefficients of variation (CVs) are presented as
a function of cumulative time for each of the selected analytes. The CVs normalize the standard deviation
for each source of error (i.e., within-laboratory, between-laboratory and overall) to the mean of the output
variable (i.e. eluate concentration or cumulative release).
The within-laboratory CV value, which is associated with method repeatability, is generally less than the
overall or between-laboratory standard deviations. Comparison of the CVs for an analyte provides a
sense of whether the overall standard deviation of the method results may be attributed to within-
laboratory or between laboratory variance components. For example, in Figure 22 and Figure 23, the
overall CV, is closely associated with between-laboratory variance and is not significantly influenced by
within-laboratory variance for most analytes and test positions.
For most analytes, the overall CV values in the first interval are noticeably higher than in subsequent
intervals and were sometimes in excess of 50%. These high values may reflect the variability associated
with dissolution of precipitated minerals from the sample surface and/or the physical removal of debris
that might remain from sample preparation - collectively called "wash-off." Therefore, the precision
estimates for the first interval of the Method 1315 test are considered to reveal minor heterogeneity of the
test material rather than the performance of the method and, subsequently, will not be used to estimate
method precision.
For interval flux (Figure 22), the overall CVs in the second through seventh intervals are relatively
constant at approximately 20-30%. These intervals represent a test regime where interval durations vary
from 1-14 days but generally increase with interval number. In the eighth interval, however, interval
duration is shortened to check for saturation at longer leaching intervals and the overall CV values spike
sharply. While the same general trend of decreasing overall CV with increasing cumulative time is seen
for the cumulative release CV values, there is no significant effect of shortening the interval duration in
the eighth interval. Figure 23 shows that the overall CVs for cumulative release start in the same range of
approximately 50% as the interval flux CVs (which is consistent with the cumulative release being based
on the mass released in only the one interval); however, the overall CV values for cumulative release
decrease with increasing cumulative time to values between 10 and 20% by the end of the test.
66
-------
1-1 1-1 1-1 1-1 T-
§ ! § § 1
° § I
(33S ZUI/6U|) 3JU3SJV
— {
I
^
• M1315SWA-FluxMean
Overall SD
Between Lab SD
Within LabSD
^
^
^
100
- ICP-OES RSD
M1315 SWA Overall CV
M1315 SWA Between Lab CV
M1315 SWA Within LabCV
0.01
0.1
10
100
0.01
0.1
10
100
(A)
Time (days)
(A)
Time (days)
0.001
0.0001 -
i, o.ooooi -
I
g 0.000001 -
u
0.0000001
M1315SWA-FluxMean
Overall SD
Between Lab SD
Within Lab SD
0.01
"")—
0.1
100
Chromium
M1315 SWA Overall CV
-- M1315 SWA Between Lab CV
----- M1315 SWA Within LabCV
10
100
0.01
0.1
10
100
(B)
Time (days)
(B)
Time (days)
U
%
i
E
5
n nnnm -
^
•
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""~-^
iSSt
» M1315CFS-FluxMean
Overall SD
— Between Lab SD
Within LabSD
c^ga..
^*""^S»-~»
^'^
100
M1315 CFS Overall CV
M1315 CFS Between Lab CV
M1315 CFS Within Lab CV
0.01
0.1
10
100
0.01
0.1
10
100
(C)
Time (days)
*. * J
Time (days)
v i i
0.1
0.01 -•
0.001
0.0001
M1315CFS-FluxMean
Overall SD
Between Lab SD
Within LabSD
100
M1315 CFS Overall CV
M1315 CFS Between Lab CV
M1315 CFS Within Lab CV
(D)
0.01 0.1 1 10
Time (days)
100
0.01
0.1
10
100
(D)
Time (days)
Figure 22. Example of Method 1315 variance component estimates and coefficients of variation for mean
interval flux.
Note: Data shown for mean and standard deviation on left and coefficient of variation on right for (A) arsenic in SWA, (B)
chromium in SWA, (C) cadmium in CFS and (D) lead in CFS.
67
-------
1000
100 -
10 -
M1315 SWA-Release Mean
Overall SD
Between Lab SD
Within Lab SD
0.01
0.1
(A)
Time (days)
100
I 10
Ł
M1315 SWA-Release Mear
-Overall SD
-Between Lab SD
-Within LabSD
0.01
0.1
(B)
Time (days)
1000
M1315 CFS-Release Mean
-Overall SD
-Between Lab SD
-Within LabSD
0.01
0.1
(C)
Time (days)
10000
1000 -t
E 100 - •
10 - :
M1315 CFS-Release Mean
Overall SD
Between Lab SD
Within LabSD
(D)
0.01 0.1 1
Time (days)
10
10
10
10
100
100
100
100
100
M1315 SWA Overail CV
M1315 SWA Between Lab CV
M1315 SWA Within Lab CV
0.01
0.1
10
100
(A)
Time (days)
100
I
M1315 SWA Overall CV
M1315 SWA Between Lab CV
M1315 SWA Within Lab CV
0.01
0.1
10
100
(B)
Time (days)
100
ra
U
M1315 CFS Overall CV
M1315 CFS Between Lab CV
M1315 CFS Within Lab CV
0.01
0.1
10
100
(C)
Time (days)
100
2.
8.
• ICP-OES RSD
M1315 CFS Overall CV
- M1315 CFS Between Lab CV
- M1315 CFS Within Lab CV
0.01
0.1
10
100
(D)
Time (days)
Figure 23. Example of Method 1315 variance component estimates and coefficients of variation for
cumulative release.
Note: Data shown for mean and standard deviation on left and coefficient of variation on right for (A) arsenic in SWA, (B)
chromium in SWA, (C) cadmium in CFS and (D) lead in CFS.
68
-------
Method 1315 Repeatability andReproducibility
The repeatability and reproducibility for a particular result are calculated in terms of the repeatability
relative standard deviation (RSDr) and the reproducibility relative standard deviation (RSDR) for each of
the selected validation analytes shown in Table 7. These relative standard deviations are derived from the
mean of the validation data and either the within-laboratory standard deviation (repeatability) or the
overall standard deviation (reproducibility).
Graphical representations of the precision statistics, comparing results for the two Method 1315 study
materials (i.e., SWA and CFS), are available in Appendix E for each of the common analytes highlighted
in Table 7. Figure 24 presents an example of the precision statistics for selenium. In each figure, eluate
concentration results are shown in the top row of panels while the results for cumulative release are
shown in the bottom row of panels. The left-hand panel illustrates the mean behavior of the result
parameter and the overall standard deviation interval of the validation dataset. These panels also show
the various levels of the mass transport behavior for the study materials as a function of time. In the
middle and right-hand panels, respectively, the RSDr and the RSDR are plotted at target cumulative times.
In the RSDr and RSDR figures, grey dashed lines are used facilitate interpretation by indicating the RSD
values of 20% and 50%
The examples in Figure 24 shows that mean interval flux and cumulative release of selenium for SWA are
significantly greater than for CFS. In fact, output values for CFS plotted between the output calculated
for the ML and MDL concentrations indicate that these concentrations are not truly quantifiable, but are
estimated. The repeatability (i.e., RSDr value) for interval flux is approximately 10 to 20% over the
majority of the time range while over the same time domain repeatability for cumulative release is
between 5 and 10%. The sudden increase in repeatability for CFS interval flux is likely due to the low
eluate concentration levels. Reproducibility values for interval flux of selenium range between 20 and
50%, although better reproducibility was generally seen for most other analytes. RSDR values for
cumulative release of selenium in both SWA and CFS tend to decrease as time increases, reaching
reproducibility values below 20% by the end of the 63-day test.
Method 1315 Precision Data
Method precision for interval flux from Method 1315 is shown in terms of relative standard deviations for
repeatability (Table 20) and reproducibility (Table 21). The analogous data for cumulative flux
repeatability and reproducibility are shown in Table 22 and Table 23, respectively. In each of these
tables, the RSDr or RSDR represents the method precision calculated for each analytes at each target L/S
value.
69
-------
l.E-01 T
l.E-02 -r
l.E-03-
E, l.E-04-f
.2 l.E-05
«
l.E-06 -t
l.E-07
• M1315CFS Flux Mean
M1315CFS Flux Overall SD
D M1315 SWA Flux Mean
M1315 SWA Flux Overall SD
|
0.01
0.1
1
Time (days)
10
100
10000 -r-r
1000 • :
Dl
^
E
3
• M1315 CFS Release Mean
M1315 CFS Release Overall SD
D M1315 SWA Release Mean
M1315 SWA Release Overall SD
0.1 1 10
Time (days)
100
iuu •
••->
1
w
Ł
(R in .
(0
&
Ł
d!
1 .
:
•n"
CP-OES RSD
•^.^
„-----"
****
M1315CFSFIuxRSD-r
M1315 SWA Flux RSD-r
, , , ,
/^
K
: t
\r
iuu •
1
^
Ł
2
'u m .
Se Re prod u
i-
-^ c
: ICP-OES RSD
M1315 CFS Flux RSD-R
M1315 SWA Flux RSD-R
^>^//
0.01 0.1 1 10 100 0.01 0.1 1 10 1C
Time (days) Time (days)
1 nn •" nn
••->
I
w
Ł
(R in .
(0
&
Ł
d!
1 .
• ICP-OES RSD
M1315 CFS Release RSD-r
M1315 SWA Release RSD-r
•^
S ^._..
^
1
^
Ł
5
'o m .
Se Re prod u
i-
-* c
: ICP-OES RSD
M1315 CFS Release RSD-R
M1315 SWA Release RSD-R
0.01 0.1 1 10 100 0.01 0.1 1 10 1C
Time (days) Time (days)
Figure 24. Comparisons of statistical analyses for selenium from Method 1315 validation study materials.
Note: Mean interval flux (upper) and cumulative release (lower) comparisons showing overall standard deviation intervals about the mean compared to method detection limits and
method limits of quantitation (left), repeatability relative standard deviation (RSDr) (center) and reproducibility relative standard deviation (RSDR) (right). Grey dashed line in
repeatability and reproducibility panels indicate 20% and 50% reference lines).
70
-------
Table 20. Method 1315 Interval Flux Repeatability (RSDr) across Study Materials
RSDr (%) at Target Cumulative Time (days)
SWA - Solidified Waste Analog
Analvte
Svmbol 0.08
Aluminum Al
Antimony Sb
Arsenic As
Barium Ba
Boron B
Calcium Ca
Chromium Cr
Potassium K
Selenium Se
Vanadium V
23
21
23
54
19
23
27
15
14
17
9
9
23
36
18
8
18
13
9
9
10
13
33
12
12
6
12
18
16
15
10
13
31
15
16
11
15
17
14
12
8
10
20
8
10
6
12
12
10
9
5
9
14
7
8
3
9
11
10
6
5
8
14
11
7
12
7
9
9
6
5
6
12
8
6
7
6
9
9
7
6
6
11
10
10
11
4
9
9
5
CFS - Contaminated Field Soil
Analyte
Symbol 0.08
Aluminum Al
Antimony Sb
Barium Ba
Boron B
Cadmium Cd
Calcium Ca
Lead Pb
Potassium K
Selenium Se
Vanadium V
19
11
27
27
21
12
17
21
8
12
13
11
10
12
10
10
6
13
11
15
18
11
8
11
9
10
5
15
16
14
17
20
7
5
7
7
4
13
11
11
9
14
7
5
6
5
o
6
7
10
11
6
12
5
3
5
3
2
9
7
9
16
18
8
5
6
4
o
6
7
10
6
17
19
8
11
12
8
9
11
24
18
10
14
7
5
7
6
4
12
15
6
71
-------
Table 21. Method 1315 Interval Flux Reproducibility
across Study Materials
RSDR (%) at Target Cumulative Time (days)
SWA - Solidified Waste Analog
Analvte
Svmbol 0.08
Aluminum Al
Antimony Sb
Arsenic As
Barium Ba
Boron B
Calcium Ca
Chromium Cr
Potassium K
Selenium Se
Vanadium V
57
63
70
104
39
59
41
47
52
50
28
25
44
60
37
37
28
37
47
26
27
22
43
30
21
31
14
26
34
27
21
20
34
36
23
19
17
23
24
20
18
18
23
30
20
27
21
24
21
18
17
15
23
37
15
19
18
20
20
13
19
11
19
43
17
21
17
25
26
14
36
34
28
74
49
49
35
30
32
34
36
28
34
48
36
25
40
45
43
27
CFS - Contaminated Field Soil
Aluminum
Antimony
Barium
Boron
Cadmium
Calcium
Lead
Potassium
Selenium
Vanadium
Symbol 0.08
72
-------
Table 22. Method 1315 Cumulative Release Repeatability (RSDr) across Study Materials
RSDr (%) at Target Cumulative Time (days)
SWA - Solidified Waste Analog
Analvte
Svmbol 0.08
Aluminum Al
Antimony Sb
Arsenic As
Barium Ba
Boron B
Calcium Ca
Chromium Cr
Potassium K
Selenium Se
Vanadium V
24
21
23
55
18
24
28
15
14
17
10
9
15
37
17
8
17
11
7
9
8
8
17
24
14
6
15
12
7
8
7
8
20
16
12
6
13
13
9
8
7
8
20
12
11
6
12
13
9
7
6
8
18
10
10
5
10
12
9
7
6
7
17
8
9
5
9
11
9
6
6
7
17
8
9
4
8
11
9
6
5
7
16
7
8
5
8
11
9
6
CFS - Contaminated Field Soil
Symbol 0.08
Aluminum Al
Antimony Sb
Barium Ba
Boron B
Cadmium Cd
Calcium Ca
Lead Pb
Potassium K
Selenium Se
Vanadium V
20
12
28
28
21
13
18
23
7
12
9
7
9
12
10
8
6
11
8
11
11
8
7
9
7
7
4
10
6
9
10
7
6
6
6
6
3
8
7
8
8
7
5
5
5
5
2
7
5
7
6
6
4
4
5
4
2
7
5
6
6
6
4
3
5
4
1
6
4
5
6
6
4
4
5
3
2
6
4
5
5
6
4
4
5
3
2
6
4
4
73
-------
Table 23. Method 1315 Cumulative Release Reproducibility (RSDjO across Study Materials
RSDR (%) at Target Cumulative Time (days)
SWA - Solidified Waste Analog
Svmbol 0.08
Analvte
Aluminum
Antimony
Arsenic
Barium
Boron
Calcium
Chromium
Potassium
Selenium
Vanadium
CFS - Contaminated Field Soil
Al
Sb
As
Ba
B
Ca
Cr
K
Se
V
58
64
71
105
40
60
29
24
41
62
29
36
40 26
47 32
54
36
51 27
27
21
38
41
25
31
21
29
33
24
24
20
31
36
23
24
18
25
27
21
21
18
28
31
22
24
15
24
23
20
Analvte
Svmbol 0.08
Aluminum Al
Antimony Sb
Barium Ba
Boron B
Cadmium Cd
Calcium Ca
Lead Pb
Potassium K
Selenium Se
Vanadium V
42
24
32
59
56
47
49
67
31
23
22
16
20
38
26
23
30
59
27
24
27
18
19
36
23
27
24
54
21
25
23
14
16
26
18
25
12
44
20
23
20
13
16
21
17
22
10
39
20
23
MMM
16
13
16
17
20
21
9
36
19
25
••M
14
12
17
16
17
18
9
33
18
20
HIM
13
13
15
17
17
18
9
33
19
20
MMM
13
13
15
17
16
15
10
31
20
19
74
-------
Overall Method 1315 Precision
As discussed for Method 1314, several possible scenarios are apparent for summarizing the overall
method precision of Method 1315. A selection of various summary scenarios is presented in Figure 25.
Since the precision estimates for mean interval flux are independent of each other, these values may be
averaged over a series of leaching intervals. Precision estimates for cumulative release are based on
cumulative variations and should only be evaluated at a particular value in the cumulative time scale.
The choice of an approach for summarizing precision depends on how the test results may be used. For
example, the most logical scenario for cumulative release would be to summarize method precision at the
end of the 63-day testing period (green box in Figure 25B). The analogous scenario for mean interval
flux would be the average of the flux values over the entire test time with the exclusion of the first
interval due to the variances associated with wash-off (see green box in Figure 25A).
1000
E
3
0.01
(A)
Time (days)
Release at End of Test
(63-day cumulative time
0.01
(B)
Time (days)
Figure 25. Illustration of scenarios used to summarize precision for Method 1315: (A) mean interval flux and
(B) cumulative release (right).
Due to the duration of Method 1315, shorter-term testing (e.g., perhaps after 7-days) might be useful in
terms of comparing mass transport between similar materials. Therefore, method precision is also
calculated for cumulative release after 7 days of leaching with the analogous representation for interval
flux determined as the average of the interval flux over the 2nd-4th leaching intervals (red boxes in Figure
25). Since the interval flux precision values are independent, an alternative estimate of method precision
for the short-term test duration would be a single target cumulative time, such at the end of the 4th
interval (blue box in Figure 25A).
Altogether, Figure 25 provides for five scenario-based estimates of precision for Method 1314:
# 1 Mean interval flux at the 4th interval
#2 Average of the interval flux values from Interval 2 through Interval 4
#3 Average of the interval flux values from Interval 2 through Interval 9
#4 Cumulative Release after 7 days (at end of the 4th interval)
#5 Cumulative Release after 63 days (at end of 9th interval)
75
-------
For each of the above scenarios, the RSDr and RSDR values were tabulated by analyte and by test material
as shown in the example for Scenario #1 presented in Table 24. Similar tables may be found in Appendix
E for each of the summary scenarios. For each of the study materials (i.e. SWA and CFS), the mean
repeatability and reproducibility is calculated from the precision values of the ten analytes used in the
validation study. The material means are then averaged to provide a single estimate of method
repeatability and reproducibility for each scenario.
Table 24. Method 1315 Precision Estimates for Scenario #1 (Flux in 4th Interval).
Analyte
Aluminum
Antimony
Arsenic
Barium
Boron
Cadmium
Calcium
Chromium
Lead
Potassium
Selenium
Vanadium
I i%.^|j^«i
Symb01 [_ o/!RSDr
Al
Sb
As
Ba
B
Cd
Ca
Cr
Pb
K
Se
V
10.2
12.5
31.4
15.2
15.6
-
10.8
14.9
-
16.7
14.4
11.5
Material Mean | 15%
Overall Mean 13% Rep
CFS SWA
%RSDr %RSDR
17.5
19.8
7.0
5.4
6.8
6.9
-
3.5
12.6
11.0
11.0
36.9
28.4
34.2
47.8
36.2
-
25.3
40.3
-
45.4
42.9
27.0
10% 36%
ucibility
CFS
%RSDR
24.9
27.1
13.1
35.0
27.5
28.5
-
43.6
26.2
54.7
31.8
31%
eatability 34% Reproducibility
The overall precision values for the summary scenarios are shown in Table 25 for interval flux and in
Table 26 for cumulative release. The precision values for cumulative release are somewhat better than
those for interval flux; however, all precision values are relatively consistent regardless of the summary
scenario.
Table 25. Method 1315 Precision Summary for Mean Interval Flux.
#1
#2
#3
Scenario
Flux in 4th Interval
Average Flux for Intervals 2-4
Average Flux for Intervals 2-9
Mean Method 1315 Precision for Interval Flux
Repeatability
13%
13%
11%
12%
Reproducibility
34%
29%
28%
30%
The mean Method 1315 precision for interval flux was determined to be 11% repeatability and 30%
reproducibility while the mean values of Method 1315 precision for cumulative release were
approximately 1/3 better at 8% repeatability and 21% reproducibility. Method 1315 overall precision was
determined to include a repeatability of 10% and a reproducibility of 27%.
76
-------
Table 26. Method 1315 Precision Summary for Cumulative Release.
^^^^^^^^^^E^^^^^^l
Cumulative Release after 7 days
epeatability Reproducibility
Cumulative Release after 63 days
Mean Method 1315 Precision Cumulative Release
Method 1315 Precision Compared to Other Leaching Method Validations
Since the guidance provided by the EPA (EPA, 1992b) and ASTM (ASTM, 1987) provide no criteria for
acceptable levels of method precision, no conclusions regarding the acceptability of Method 1315 can be
made based on precision alone. However, the precision of Method 1315 may be put into context of
accepted and adopted leaching test methods by comparing the Method 1315 precision to the reported
precision of NEN 7345, a Dutch monolithic tank leaching test. In addition, the reproducibility results
may also be compared to those found within the method text of the current U.S. waste classification
leaching test, the Method 1311 (EPA, 1992a) or the Toxicity Characteristic Leaching Procedure (TCLP).
NEN 7345 Repeatability and Reproducibility
In support of the NEN 7345 Dutch monolithic tank leaching test, the European Commission published a
validation study of tank leaching data with up to 21 participating laboratories (van der Sloot et al., 1995).
The single study material was a laboratory-formulated solidified matrix comprised of portland cement,
municipal solid waste incinerator fly ash, natural sand and water. Precision results were reported for 16-
day cumulative release for a limited set of inorganic constituents (e.g., Cl, Na, SO4, and Zn). Using the
relative standard deviations reported in the study, a distribution of RSDR values ranging from 15 to 55%
was created for comparison to Method 1315. Repeatability values between 4 and 17% were calculated
for comparison using the reported within-laboratory standard deviation and the mean cumulative release.
In a separate study supporting the development of a leaching approach specifically for construction-based
concretes, the precision of NEN 7345 was reported for the 64-day cumulative release of Na, As, Cl, Cr
and K from a spiked concrete mixture at ranges of 11-18% repeatability and 25-50% reproducibility
(Hohberg et al., 2000). Thus, the precision estimates reported by Hohberg for construction-grade
concrete are consistent with the European Commission report for waste-based materials. The values
derived from the European Commission report were used for comparison to Method 1315 precision.
TCLP (SW-846 Method 1311) Reproducibility
The TCLP method provided reproducibility data for Cd, Cr, and Pb contained in three study materials
(e.g., ammonia lime still bottoms, API/EW mixture, and fossil fuel fly ash). Each of the three study
materials was tested with both the acetic acid and buffered acetic acid extraction fluids specified in the
test method. The reported results of interlaboratory validation of TCLP are a mean RSDR of 74% with a
range of results from 17-118% (EPA, 1992b).
Comparison of Precision Distributions
The distributions of RSDr and RSDR in Figure 26 compare the Method 1315 precision for 14-day
cumulative release in each of the two study materials to the distributions of precision derived for NEN
7345 and reported for TCLP. The dashed vertical line in each figure panel separates the LEAF tests (left)
from the other leaching tests (right). For each distribution, stacked boxes represent the interquartile range
(IQR) of the 25th and 75th percentiles with the median shown as the line dividing the boxes. Whiskers
indicate the maximum and minimum values obtained for each distribution. Method 1315 precision was
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calculated for cumulative release at end of the 5th leaching interval (cumulative time of 14 days) to be
comparable to the 16-day cumulative release precision derived for NEN 7345. The difference in
cumulative time reflects the fact that the specified collection times for these methods differ slightly. For
TCLP, only reproducibility data was reported and is shown for eluate concentrations as measured in the
single batch extraction.
100
? 80 +
a 60 +
it 40 +
1
5 20 -
M1315-SWA
M1315-CFS
NEN 7345
o
3
100
80
60
40
20
0
Max BSD,
@ 118%
M1315-SWA M1315-CFS NEN 7345 TCLP
Figure 26. Distribution of Method 1315 repeatability (RSDr) and reproducibility (RSDjO by study material
compared to precision estimates reported for NEN 7345 and TCLP.
Note: Distribution of precision values for Method 1314 and DIN 19528 provided at a common L/S value of 1 mL/g-dry. TCLP
distribution reflects the range of precision determined for the single batch test.
NEN 7345 and Method 1315 are both tank leaching tests designed to determine the rate of mass transport
through a material as a function of time, so it would be expected that the precision estimate for these
leaching test methods are similar. However, TCLP is an equilibrium-based screening procedure that is
operationally different that either NEN 7345 or Method 1315. Given these limitations, the repeatability
for Method 1315 was significantly better than the reproducibility values reported in the TCLP while being
consistent with the precision generated for NEN 7345. Method 1315 IQRs for RSDr were narrower than,
but within the range of values of, the IQR of repeatability for NEN 7345. The reproducibility of Method
1315 is within the IRQ of the RSDR distribution for NEN 7345 and much better than the RSDR reported
for TCLP.
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COMPARISON OF METHOD 1315 STATISTICS TO RESULTS OF EU TESTS
In parallel to participating in the validation of Method 1315, ECN used specimens of SWA to prepare
analytical samples for the Dutch mass transfer standard test, NEN 7375 (NEN, 2004), during the Winter
2010. In addition during Spring 2011, ECN conducted the mass transfer based test on SWA specimens
following the CEN/TS 15863 (CEN, 2009) tank leaching test, designated as a TS under the support of the
CEN.
Both of these EU mass transfer leaching tests are similar in intent and procedure to Method 1315.
Differences include the total testing duration, the number and duration of the testing intervals, and the
basis for determination of the amount of liquid used in each leaching interval. The information in Table
27 shows the primary differences between these three leaching methods.
Table 27. Comparison of Method 1315 and EU Mass Transfer Test Parameters.
Parameter Method 1315 NEN 7375 CEN/TS
15863
Total Test Duration (days)
Eluate Volume Basis
Liquid Volume
Number of Intervals
Refresh Exchanges at
Cumulative Times (days)
63
specimen
surface area
9±1 mL/cm2
9
0.08
1.1
2.0
7
14
28
42
49
63
64
specimen
volume
2-5 cmVcm3
8
0.25
1.0
2.25
4
9
16
36
64
51
specimen
surface area
8±1 mL/cm3
8
0.08
1.0
2.25
8
14
15
28
36
Description of NEN 7375 Procedure
NEN 7375 is intended to define leaching from molded or monolithic materials under mass transfer
conditions as a function of time. The test determines the nature and properties of the material matrix by
placing a complete sample in a leaching fluid of demineralized water and replenishing the eluate at eight
specified cumulative times of 0.25, 1, 2.25, 4, 9, 16, 36, and 64 days. Test specimens should have a
minimum dimension of 40 mm and a geometric surface area of at least 75 cm2. The volume of eluent for
each leaching interval is based on the test specimen volume with 2-5 mL of eluent for every cm3 of test
specimen. From analytical samples of each eluate collection, the composition of the eluate is determined
using standard methods, and the leached quantity per unit area is calculated for each constituent.
Parameters that can be deduced from the development of release of constituent over time include the
extent of surface rinsing and the effective diffusion coefficient that can be used to estimate leaching over
longer periods.
Description of CEN/TS 15863 Procedure
The CEN/TS 15863 method describes a procedure for leaching of a solid monolithic material in a similar
manner as NEN 7375 or Method 1315. The test specifies that a regular shaped test specimen is prepared
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by cutting or coring in accordance with standard sampling methods. The test specimen is submerged in a
tank of demineralized or deionized water for specified interval durations for a series of eight leaching
intervals (see Table 26). The leachant is refreshed at cumulative times of 0.08, 1, 2.25, 8, 14, 15, 28, and
36 days. For each eluate, pH and conductivity are measured and recorded prior to preparation for
chemical analysis using standard methods. The results of the test are the cumulative mass release
(mg/m2) expressed as a function of time.
Comparison of EU Test Results to Method 1315 Statistics
The results of triplicate testing of SWA using NEN 7375 and CEN/TS 15863 are shown in Figure 27
along with the mean and reproducibility limit interval derived for SWA from the validation of Method
1315. The 95% reproducibility limit intervals form a band of data within which results gathered under
reproducibility conditions (e.g., same material tested with the same method conducted by different
operator using different equipment) may be considered to be statistically equivalent with 95% confidence.
The assumption in this comparison is that the differences in the NEN, CEN and LEAF methods are
sufficiently small that these mass transfer leaching procedures are essentially the same method.
Overall, the results obtained for NEN 7375 and CEN/TS 15863 are statistically equivalent to the results of
Method 1315 indicating that minor differences in these three leaching tests do not significantly affect the
test results. The comparisons between test results shown in Figure 27 indicate that the cumulative release
results of NEN 7375 are greater than the mean of the Method 1315 data but within the reproducibility
limit intervals for all analytes except chromium for which the release from NEN 7375 is slightly above
the interval.
Cumulative release derived from CEN/TS 15863 testing of SWA appears to be slightly lower than the
mean cumulative release data than Method 1315 but, in most cases, within the reproducibility limits. The
cumulative release from CEN/TS 15863 for several oxyanions, including antimony, selenium and
vanadium, were observed to fall just outside the lower reproducibility limit interval. Since the CEN/TS
15863 tests were conducted approximate one year after the NEN 7375 and Method 1315 tests18, it would
be easy to assume that differences in cumulative release resulted from aging of the SWA material.
18 Method 1314 validation tests on SWA material were carried out over a period between 4 and 8 months after sample
preparation. For the EU tests, NEN 7375 testing of SWA began 8 months after sample preparation, while CEN/TS tests were
started 18 months after SWA sample preparation.
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13
12 -•
11 -•
2 10 --
9 -•
•
A
SWA-L11-15863-A
SWA-L11-15863-B
-SWA M1315 Mean
A SWA-L11-7375-B
SWA M1315 95% RL
1000
(A)
0.01 0.1 1 10
Time (days)
100
0.1
0.01
0.1
10
100
(B)
Time (days)
10000
.E 1000 -t
I*
"JU" 100 - r
(A
ID
S 10 -I
a)
Ł
0.1
SWA-L11-15863-A
SWA-L11-15863-C
SWA-L11-7375-B
•SWA M1315 Mean
A SWA-L11-15863-B
O SWA-L11-7375-A
Q SWA-L11-7375-C
SWA M1315 95% Rl
1000
100
8
»
1 -I
•g o-1^
0.01
SWA-L11-15863-A
SWA-L11-15863-B
SWA-L11-15863-C
SWA-L11-7375-A
SWA-L11-7375-B
SWA-L11-7375-C
-SWA M1315 Mean
SWA M1315 95% R
(C)
0.01 0.1 1
Time (days)
10
100
0.01
0.1
"H—
10
100
(D)
M""*
D)
Time (days)
1000
100
5
o
10 -•
1 -•
0.1
0.1
0.01
A SWA-L11-15863-B
• SWA-L11-15863-C
SWA M1315 Mean
A SWA-L11-7375-B
Q SWA-L11-7375-C
SWA M1315 95% RL
0.01
10
100
(E)
Time (days)
(F)
0.01 0.1 1
Time (days)
10
100
10000
SWA-L11-15863-A
SWA-L11-15863-B
SWA-L11-15863-C
SWA-L11-7375-A
SWA-L11-7375-B
SWA-L11-7375-C
SWA M1315 Mear
SWA M1315 95
100 -E-r
0.1
• SWA-L11-15863-A O SWA-L11-7375-A
A SWA-L11-15863-B A SWA-L11-7375-B
• SWA-L11-15863-C D SWA-L11-7375-C
SWA M1315 Mean SWA M1315 95% RL
0.01
10
100
0.01
10
100
(G)
Time (days)
(H)
Time (days)
Figure 27. Cumulative release from CEN/TS 15863 and NEN 7375 compared to Method 1315 statistics.
Note: Method 1315 statistics include the mean of the validation data and the reproducibility limit at the 95% confidence level
(95% RCL). Comparisons shown for SWA material: (A) eluate pH, (B) antimony, (C) arsenic, (D) barium, (E) chromium, (F)
calcium, (G) selenium and (H) vanadium.
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Influence of Sample Aging
In order to test whether aging of the SWA material had affected the CEN/TS 15863 data, aged SWA
samples were testing by Method 1315 and compared to both CEN/TS 15863 results and Method 1315
validation statistics. Aged samples were tested by Method 1315 18 months after initial SWA preparation.
Comparisons for eluate pH and several oxyanions are presented in Figure 28. These comparisons show
that no apparent differences from the mean of the validation data were found for arsenic and chromium
when the aged SWA samples were tested using Method 1315. Iron, selenium, antimony and vanadium
cumulative release from aged SWA materials had a slight decrease relative the respective means of the
Method 1315 validation; however, Method 1315 testing of aged SWA specimens was still within the
reproducibility limit intervals of the validation data. The reduced cumulative release curves could be
indicative of specimen oxidation during the longer curing interval which may lead to reduced leaching of
redox-sensitive analytes. Since the CEN/TS 15863 cumulative release curves are noticeably lower than
the Method 1315 testing of aged SWA specimens, additional unidentified factors are likely causing the
observed effect, especially for the first leaching intervals. Therefore, the minor deviations in the CEN/TS
15863 data relative to Method 1315 validation statistics are probably not due to any differences in the
method procedures or test conditions, but to sample heterogeneity through oxidation of either the SWA
specimens (e.g., comparing Method 1315 testing of 18-month cured samples to validation results) or the
eluate solutions (comparing Method 1315 testing of 18-month cured samples to CEN/TS 15863 data).
82
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9 -•
1000
SWA-L11-15863-A
A SWA-L11-15863-B
• SWA-L11-15863-C
SWA M1315 Mean
SWA_18m M1315-A
A SWAJLSm M1315-B
• SWA_18m M1315-C
SWA M1315 95% RL
0.01
•—(—
0.1
10
100
SWA_18m M1315-A
SWA_18m M1315-B
SWA_18m M1315-C
SWA-L11-15863-A
SWA-L11-15863-B
SWA-L11-15863-C
SWA M1315 Mean
SWA M1315 95% RL
0.1
0.01
10
100
(A)
Time (days)
(B)
Time (days)
1000
100
10
1 -;
I 0.1 +
u
0.01
• SWA_18m M1315-A A SWA_18m M1315-B
• SWA_18m M1315-C • SWA-L11-15863-A
A SWA-L11-15863-B D SWA-L11-15863-C
SWA M1315 Mean SWA M1315 95% RL
0.01
0.1
10
100
0.01
10
100
(C)
Time (days)
(D)
Time (days)
10000
1000 - r
ti 100 - :
a
w
• SWA_18m M1315-A
• SWA_18m M1315-C
A SWA-L11-15863-B
SWA M1315 Mean
A SWAJLSm M1315-B
• SWA-L11-15863-A
• SWA-L11-15863-C
• SWAM131595%RL
SWA_18m M1315-A
SWA_18m M1315-B
SWA_18m M1315-C
SWA-L11-15863-A
SWA-L11-15863-B
SWA-L11-15863-C
SWA M1315 Mean
SWA M1315 95% RL
0.01
10
100
0.01
(E)
Time (days)
(F)
0.1 1 10
Time (days)
100
Figure 28. Check on the effect of SWA aging on cumulative release.
Note: Method 1315 statistics include the mean of the validation data and the reproducibility limit at the 95% probability level
(95% RL). Comparisons shown for (A) eluate pH, (B) antimony, (C) chromium, (D) iron, (E) selenium and (F) vanadium from
SWA material.
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SUMMARY AND CONCLUSIONS
The precision of LEAF Method 1314 and Method 1315 have been derived from interlaboratory testing
using two different study materials for each method. The study material types were intended to challenge
the performance of the method with selected materials seen in waste management and beneficial use
activities. For Method 1315, ten participating laboratories provided filtered and preserved eluates from
triplicate tests runs on each of a monolithic solidified waste analog and a granular contaminated field soil.
For Method 1314, at least seven laboratories provided data used to validate each test method, consistent
with recommendations of EPA (EPA, 1992b) and ASTM (ASTM, 1987). Vanderbilt University (VU)
served as a reference laboratory and provided six test replicates of each material for both methods.
Eluates were chemically analyzed by inductively coupled plasma-optical emission spectroscopy at VU.
From the overall dataset, a list often selected analytes for each method and material were chosen for
statistical analysis based on concentration levels and regulatory importance.
The collection and management of the large data set was achieved using standardized Excel templates in
conjunction with LeachXS data evaluation software developed by VU, the Energy Research Centre of the
Netherlands (ECN) and DHI (Denmark). Test outputs, specifically eluate concentration and cumulative
release for Method 1314 and interval flux and cumulative release for Method 1315 were derived from the
measured eluate concentrations and test information provided by each participating laboratory. All test
outputs were processed using logio-transforms and linear interpolation/extrapolation to yield the data sets
used in statistical analysis. Statistical measurements of data spread, within-laboratory standard deviation,
between-laboratory standard deviation and overall standard deviation were calculated for ten selected
analytes from each material. The reference laboratory data were used to develop intervals for 95%
prediction limits about the mean that were compared to 95% robust confidence limits about the median of
all the means from each laboratory. Standard deviations for within-laboratory, between-laboratory and
overall variance components were estimated using the equations of a one-way analysis of variance
approach implemented in LeachXS. Method precision in terms of repeatability relative standard
deviation (RSDr) and reproducibility relative standard deviation (RSDR) were derived from the within-
laboratory and overall standard deviation values, respectively.
For each test output, method precision was evaluated for several plausible summary scenarios using the
estimated precision for each of the ten analytes in each study material. In general, method precision for
cumulative release was better than method precision based on eluate concentrations (Method 1314) or
interval flux (Method 1315).
Method 1314
• Repeatability of 12% RSDr for eluate concentration
• Repeatability of 6% RSDr for cumulative release
• Reproducibility of 24% RSDR for eluate concentration
• Reproducibility of 16% RSDR for cumulative release
Method 1315
• Repeatability of 12% RSDr for eluate concentration
• Repeatability of 8% RSDr for cumulative release
• Reproducibility of 30% RSDR for eluate concentration
• Reproducibility of 21% RSDR for cumulative release
84
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Taking the greater of the two precision estimates for each test as a conservative estimate, what these
results mean to the single operator laboratory is that the variation in replicate tests on the same material
would be less than 12% for either Method 1314 or Method 1315. When multiple laboratories perform
these tests on the homogenized sample of the same material, the test results would vary less than 30% for
Method 1314 and less than 24% for Method 1315. These mean precision values were found to be
considerably better than the mean reproducibility RSD reported for TCLP (EPA 1992a).
The precision estimates for the ten analytes in each study material were used to formulate a distribution of
RSDr and RSDR values for comparison to similar distributions for accepted national standard methods.
The interquartile ranges for the distributions of RSDr and RSDR in Method 1314 and Method 1315 were
found to be in agreement with the reported and derived precision distributions found in the literature for a
German column test (DIN, 2009) and a Dutch monolithic leaching test (van der Sloot et al, 1995),
respectively.
In addition to participating in the Method 1314 and Method 1315 validations, the Energy Research Centre
of the Netherlands used the validation study material to prepare analytical solutions from leaching tests
accepted in the European Union (EU) through Dutch national standardization organization (NEN) or the
Comite Europeen de Normalisation (CEN). These test results from these EU leaching procedures were
compared with the mean and reproducibility limit intervals for Methods 1314 and Method 1315 in order
to show the consistency between leaching tests with similar intents and procedures. The cumulative
release from the CEN/TS 14405 percolation column test compared favorably to the Method 1314
statistics for both validation materials. Cumulative release from the Dutch monolith leaching standard,
NEN 7375, showed good agreement with Method 1315 statistics while the cumulative release for the
CEN/TS 15863 leaching test was favorable with slight deviations for antimony, selenium and vanadium.
Deviations in the cumulative release between Method 1315 and CEN/TS 15863 were shown not to be an
experimental artifact of the additional aging of the SWA material during the time between Method 1315
testing and testing using CEN/TS 15863. The cause of the deviations is unknown, but is likely due to
oxidation of either the material test samples or eluate samples during preparation of CEN/TS 15863
eluates. Overall, the consistency between the EU leaching test and the LEAF methods was good,
indicating that these methods adequately characterize the phenomena that control the release of
constituents from granular and monolithic solid material and that minor differences in test specifications
do not significantly affect method results.
Based on the method validation results and comparison presented in this report, the following statements
regarding LEAF Method 1314 and Method 1315 may be made:
Procedural Considerations
• Accurate pH measurement that considers appropriate instrument calibration (i.e., buffer solutions
that span the pH range of the solutions to be tested to the greatest degree possible) and proper pH
measurement techniques is essential to the performance of these methods. Measurement of pH
should be taken as rapidly as practical after collection of eluates to avoid carbonation of alkaline
solutions with limited pH buffering capacity.
• The data templates are recommended for use with Method 1314 and Method 1315 to provide
uniform calculations, data collection, and data input into LeachXS which greatly facilitates
management of large data sets. LeachXS Lite is a simplified, free version of LeachXS that can
85
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assist method users with method implementation as well as data management, graphing and
reporting.
Repeatability and Reproducibilitv
• Repeatability of Method 1314 and Method 1315 generally is expected to be approximately 5-10%
of the mean value (concentration or interval flux, respectively) which is consistent with the
variability associated with many chemical analytical methods. Reproducibility is expected to be
approximately 20-30% of the measured mean value.
• The precision of cumulated test output, specifically the cumulative mass release, is expected to be
slightly better than interval-based test output such as individual test fraction eluate concentrations
(Method 1314) or mean interval flux (Method 1315).
• Commercial and non-commercial laboratories should be readily able to implement Method 1314
and Method 1315 for both monolithic and compacted granular materials with a degree of
repeatability and reproducibility consistent with current regulatory leaching methods in the U.S
and Europe.
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600/R-10/170, U.S. Environmental Protection Agency, Air Pollution Prevention and Control Division,
December 2010.
Garrabrants, A.C., D.S. Kosson, L. Stefanski, R. DeLapp, P.F.A.B. Seignette, H.A. van der Sloot, P.
Kariher, and M. Baldwin (2012) "Interlaboratory Validation of the Leaching Environmental Assessment
Framework (LEAF) Method 1313 and Method 1316," DRAFT, U.S. Environmental Protection Agency,
Air Pollution Prevention and Control Division, January 2012.
Hohberg, I, G.J. de Groot, A.M.H. van der Veen, and W. Wassing (2000) "Development of a leaching
protocol for concrete," Waste Management, 20, 177-184.
Haldar, A. and S. Mahadevan (2000) Probability, Reliability and Statistical Method in Engineering
Design, John Wiley and Sons, New York.
Huber, P.J. (1968) "Robust confidence limits," Probability Theory and Related Fields, 10(4), 269-278.
ISO (1994) ISO 5725-1 Accuracy (Trueness and Precision) of Measurement Methods and Results - Part
1: General Principles and Definitions, International Organization for Standards, Geneva, Switzerland.
Kosson, D.S., F. Sanchez, P. Kariher, L.H. Turner, R. DeLapp, and P. Seignette (2009) "Characterization
of Coal Combustion Residues from Electric Utilities - Leaching and Characterization Data," EPA-600/R-
09/151, U.S. Environmental Protection Agency, Air Pollution Prevention and Control Division,
December 2009.
Kosson, D.S, H.A. van der Sloot, F. Sanchez and A.C. Garrabrants (2002) "An integrated framework for
evaluating leaching in waste management and utilization of secondary materials," Environmental
Engineering Science, 19(3), 159-204.
Lopez-Meza, S., A.C. Garrabrants, H. van der Sloot and D.S. Kosson (2008) "Comparison of the release
of constituents from granular materials under batch and column testing." Waste Management, 28:1853-
1867.
Maronna, R, D. Martin, and V. Yohai (2006) Robust Statistics: Theory and Methods'", John Wiley &
Sons, Ltd., Chichester, UK.
-------
NEN (1995) NEN 7345 Leaching Characteristics of Solid Earth and Stony Materials - Leaching Tests -
Determination of the Leaching of Inorganic Constituents from Molded and Monolithic Materials with the
Diffusion Test, Dutch Standardization Institute, Delft, The Netherlands.
NEN (2004) NEN 7375 Leaching Characteristics - Determination of the Leaching of Inorganic
Components from Moulded or Monolithic Materials with a Diffusion Test - Solid Earthy and Stony
Materials, Dutch Standardization Institute, Delft, The Netherlands, January 2004.
Rao, P.V. (1998) Statistical Research Methods in the Life Sciences, Duxbury Press, Pacific Grove CA.
Sanchez, F., R. Keeney, D. Kosson, and R. DeLapp (2006) "Characterization of Mercury-enriched Coal
Combustion Residues from Electric Utilities using Enhanced Sorbents for Mercury Control," EPA-600/R-
06/008, U.S. Environmental Protection Agency, Air Pollution Prevention and Control Division, February
2006.
Sanchez, F., D. Kosson, R. Keeney, R. DeLapp, L. Turner and P. Kariher (2008) "Characterization of
Coal Combustion Residues from Electric Utilities using Wet Scrubbers for Multi-pollutant Control,"
EPA-600/R-08/077, U.S. Environmental Protection Agency, Air Pollution Prevention and Control
Division, July 2008.
van der Sloot, H.A., L. Heasman, and P. Quevauviller (1997) Harmonization of Leaching/Extraction
Tests, Elsevier Science, Amsterdam.
van der Sloot, H.A., D. Hoede, G.J. de Groot, G.J.L. van der Wegen and P. Quevauviller (1995)
Intercomparison of Leaching Tests for Stabilized Waste, EUR 16133 EN, European Commission,
Community Bureau of Reference, Brussels, Belgium.
Verbeke, G. and Molenburghs, G. (2009) "Introduction to Longitudinal Data Analysis," available at
https://perswww.kuleuven.be/~uOO 18341/documents/longitudinal.pdf (accessed 6-11-12).
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Appendix A. Method 1314: Liquid-Solid Partitioning as a Function of Liquid-
Solid Ratio using an Up-Flow Percolation Column Procedure
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DRAFT METHOD 13141
LIQUID-SOLID PARTITIONING AS A FUNCTION OF LIQUID-SOLID RATIO FOR
CONSTITUENTS IN SOLID MATERIALS USING AN UP-FLOW PERCOLATION COLUMN
PROCEDURE
SW-846 is not intended to be an analytical training manual. Therefore, method
procedures are written based on the assumption that they will be performed by analysts who are
formally trained in at least the basic principles of chemical analysis and in the use of the subject
technology.
In addition, SW-846 methods, with the exception of required method use for the analysis
of method-defined parameters, are intended to be guidance methods which contain general
information on how to perform an analytical procedure or technique which a laboratory can use
as a basic starting point for generating its own detailed Standard Operating Procedure (SOP),
either for its own general use or for a specific project application. The performance data
included in this method are for guidance purposes only, and are not intended to be and must not
be used as absolute QC acceptance criteria for purposes of laboratory accreditation.
1.0 SCOPE AND APPLICATION
1.1 This method is designed to provide the liquid-solid partitioning (LSP) of
inorganic constituents (e.g., metals, radionuclides) and non-volatile organic constituents (e.g.,
polycyclic aromatic hydrocarbons (PAHs), dissolved organic carbon) in a granular solid material
as a function of liquid-to-solid ratio (L/S) under percolation conditions. The first eluates of the
column test may provide insight into the composition of pore solution either in a granular bed
(e.g., soil column) or in the pore space of low-permeability material (e.g., solidified monolithic or
compacted granular fill). Analyses of eluates for dissolved organic carbon and of the solid
phase for total organic carbon afford evaluation of the impact of organic carbon release and the
influence of dissolved organic carbon on the LSP of inorganic constituents.
1.2 This method is intended to be used as part of environmental leaching
assessment for the evaluation of disposal, beneficial use, treatment effectiveness and site
remediation.
1.3 This method is suitable to a wide range of granular solid materials. Example
materials include industrial wastes, soils, sludges, combustion residues, sediments, construction
materials, and mining wastes. This method is not suitable to monolithic materials (e.g., cement-
based and stabilized materials) without particle-size reduction prior to testing.
1 This method has been derived from the CT001 procedure (Ref. 4) and is analogous to column percolation method
CEN/TS14405 (Ref. 2) developed for the Comite Europeen de Normalisation (CEN).
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1.4 This test method is intended as a means for obtaining a series of extracts (i.e.,
the eluates) of a granular solid material which may be used to show eluate concentrations
and/or cumulative release as a function of L/S which can be related to a time scale when data
on mean infiltration rate, density and height of application are available.
1.5 This method provides options for the preparation of analytical samples that
provide flexibility based on the level of detail required. For example, when the purpose of
characterization is for comparison to previous testing, compositing of eluates may be possible to
create a reduced set of analytical samples. Table 1 outlines the eluate fractions and collection
options, based on whether concentration or cumulative release is to be reported. The collection
schemes are described below.
1.5.1 Complete characterization
For complete characterization of eluate concentration and cumulative release
as a function of US, nine discrete eluate collections and analyses are required (see
Table 1, Option A). No compositing of eluate fractions is performed for complete
characterization, and all eluate fractions are analyzed.
Eluate concentrations from complete characterization may be used in
conjunction with information regarding environmental management scenarios to
estimate anticipated leaching concentrations, release rates, and extents of release for
individual material constituents in the management scenarios evaluated. Eluate
concentrations may also be used along with geochemical speciation modeling to infer
the mineral phases that control the LSP in the pore structure of the solid material.
1.5.2 Limited analysis
Under a limited analysis approach, nine eluate collections and analysis of six
analytical samples are required. If evaluation is based on eluate concentrations, six
discrete eluate fractions are chemically analyzed (see
Table 1, Option B). If evaluation is based on cumulative release, some eluate fractions
are composited by volume-weighted averaging to create a set of six analytical samples
(see Table 1, Option C). The concentrations of composite analytical samples cannot be
interpreted along with eluate fractions on the basis of concentration.
1.5.3 Index testing
For the determination of consistency between the subject material and
previously characterized materials, nine eluate collections and analysis of three
analytical samples are required. If consistency is to be determined by eluate
concentrations, three discrete eluate fractions are chemically analyzed (see Table 1,
Option D). If consistency is to be determined by cumulative release, some eluate
fractions are composited by volume-weighted averaging to create a set of three
analytical samples (see Table 1, Option E). The concentrations of composited
analytical samples cannot be interpreted along with eluate fractions on the basis of
concentration.
1.6 This method is not applicable to characterize the release of volatile organic
analytes.
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1.7 This method provides eluate solutions considered indicative of leachate under
field conditions only where the field leaching pH is controlled by the alkalinity or acidity of the
solid material and the field leachate is not subject to dilution or other attenuation mechanisms.
The cumulative mass of constituent released over a L/S range may be considered an estimate
of the maximum mass of that constituent to be leached under field leaching over intermediate
time frames (e.g., up to 100 years) and the domain of laboratory test pH.
1.8 Prior to employing this method, analysts are advised to take reasonable
measures to ensure that the granular sample is homogenized to the extent practical. Particle-
size reduction may provide additional assurance of sample homogenization.
1.9 In preparation of solid materials for use in this method, particle-size reduction or
exclusion of samples with large grain size is used to enhance the approach towards liquid-solid
equilibrium over the residence time of eluent in the column.
1.10 The structure and use of this method is similar to that of MEN 7343 (see Ref. 1)
and CEN TS 14405 (see Ref. 2).
1.11 Prior to employing this method, analysts are advised to consult the base
method for each type of procedure that may be employed in the overall analysis (e.g., Methods
9040, 9045, and 9050, and the determinative methods for the target analytes), quality control
(QC) acceptance criteria, calculations, and general guidance. Analysts also should consult the
disclaimer statement at the front of the manual and the information in Chapter Two for guidance
on the intended flexibility in the choice of methods, apparatus, materials, reagents, and
supplies, and on the responsibilities of the analyst for demonstrating that the techniques
employed are appropriate for the analytes of interest, in the matrix of interest, and at the
concentration levels of concern.
In addition, analysts and data users are advised that, except where explicitly specified in
a regulation, the use of SW-846 methods is not mandatory in response to Federal testing
requirements. The information contained in this method is provided by EPA as guidance to be
used by the analyst and the regulated community in making judgments necessary to generate
results that meet the data quality objectives for the intended application. Guidance on defining
data quality objectives can be obtained at http://www.epa.gov/QUALITY/qs-docs/g4-final.pdf
1.12 Use of this method is restricted to use by, or under supervision of, properly
experienced and trained personnel. Each analyst must demonstrate the ability to generate
acceptable results with this method.
2.0 SUMMARY OF METHOD
Eluent is introduced into a column of moderately-packed granular material in an up-flow
pumping mode, with eluate collection performed as a function of the cumulative L/S. Up-flow
pumping is used to minimize air entrainment and flow channeling. The default eluent for most
materials is reagent water. However, a solution of 1.0 mM calcium chloride in reagent water is
used when testing materials with either a high clay content (i.e., to prevent deflocculation of clay
layers) or high organic matter (i.e., to moderate mobilization of dissolved organic carbon). The
flow rate is maintained between 0.5-1.0 L/S per day to increase the likelihood of local
equilibrium between the solid and liquid phases, due to residence times longer than 1 day.
Eluate volumes are chemically analyzed for a combination of inorganic and non-volatile organic
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analytes depending on the constituents of potential concern (COPC). For the purposes of
chemical speciation modeling, the entire eluent volume up to 10 ml_/g dry sample (g-dry) is
collected in nine specific aliquots of varying volume. A limited subset of eluents volumes within
the same L/S range may be collected and analyzed for regulatory and compliance purposes. A
flowchart for performing this method is shown in Figure 1.
3.0 DEFINITIONS
3.1 COPC — A chemical species of interest, which may or may not be regulated,
but may be characteristic of release-controlling properties of the sample geochemistry.
3.2 Release — The dissolution or partitioning of a COPC from the solid phase to
the aqueous phase during laboratory testing (or under field conditions). In this method, mass
release is expressed in units of mg COPC/kg dry solid material.
3.3 LSP — The distribution of COPCs between the solid and liquid phases at the
conclusion of the extraction.
3.4 Liquid-to-solid ratio (US) — The fraction of the total liquid volume (including the
moisture contained in the "as used" solid sample) to the dry mass equivalent of the solid
material. L/S is typically expressed in volume units of liquid per dry mass of solid material
(mL/g-dry).
3.5 "As-tested" sample — The solid sample at the conditions (e.g., moisture content
and particle-size distribution) present at the time of the start of the test procedure. The "as-
tested" conditions will differ from the "as-received" sample conditions if particle-size reduction
and drying were necessarily performed.
3.6 Dry-mass equivalent — The mass of "as-tested" (i.e., "wet") sample that
equates to the mass of dry solids plus associated moisture, based on the moisture content of
the "as-tested" material. The dry-mass equivalent is typically expressed in mass units of the
"as-tested" sample (g).
3.7 Refer to the SW-846 chapter of terms and acronyms for potentially applicable
definitions.
4.0 INTERFERENCES
4.1 Solvents, reagents, glassware, and other sample processing hardware may
yield artifacts and/or interferences to sample analysis. All of these materials must be
demonstrated to be free from interferences under the conditions of the analysis by analyzing
method blanks. Specific selection of reagents and purification of solvents by distillation in all-
glass systems may be necessary. Refer to each method to be used for specific guidance on
quality control procedures and to Chapters Three and Four for general guidance on the cleaning
of laboratory apparatus prior to use.
4.2 When the test method is applied to solid materials with a clay content greater
than 10% or an organic matter content greater than 1%, a solution of 1.0 mM calcium chloride in
reagent water is recommended to minimize deflocculation of clay minerals. However, the use of
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calcium chloride solution will interfere with the determination of actual calcium and chloride
release.
4.3 When this method is applied to fine-grained, granular materials, tamping during
column preparation may result in flow problems due to a low-permeability sample bed. This
problem can be resolved by incorporating 20-50% inert material (e.g., 20-30-mesh normal sand
or 2-mm borosilicate glass beads) into the solid sample. Alternatively, mass release from low-
permeability materials may be measured using Method 1315.
5.0 SAFETY
5.1 This method does not address all safety issues associated with its use. The
laboratory is responsible for maintaining a safe work environment and a current awareness file
of OSHA regulations regarding the safe handling of the chemicals listed in this method. A
reference file of material safety data sheets (MSDSs) should be available to all personnel
involved in these analyses.
6.0 EQUIPMENT AND SUPPLIES
The mention of trade names or commercial products in this manual is for illustrative
purposes only, and does not constitute an EPA endorsement or exclusive recommendation for
use. The products and instrument settings cited in SW-846 methods represent those products
and settings used during the method development or subsequently evaluated by the Agency.
Glassware, reagents, supplies, equipment, and setting other than those listed in this manual
may be employed provided that method performance appropriate for the intended application
has been demonstrated and documented.
This section does not list common laboratory glassware (e.g., beakers and flasks).
6.1 Column apparatus
This method recommends the use of a specific column apparatus (see Figure 2).
Equipment with equivalent specifications may be substituted. The apparatus should have
valves and quick connectors (e.g., Luer lock fittings) such that the column with end caps can be
removed for packing with test material and mass measurements.
6.1.2 A 30-cm, straight cylindrical column with an inner diameter (ID) of 5-
cm and constructed of inert material, resistant to high- and low-pH conditions and
interaction with constituents of interest.
6.1.2.1 For the evaluation of inorganic COPC mobility,
equipment composed of borosilicate glass (e.g., Kimble-Kontes CHROMAFLEX
#420830-3020 or equivalent), polytetra-fluoroethylene (PTFE), high density
polyethylene (HOPE), polypropylene (PP), or polyvinyl chloride (PVC) is
recommended.
6.1.2.2 For the evaluation of non-volatile organic and mixed
organic/inorganic COPCs, equipment composed of glass or Type 316 stainless
steel is recommended. PTFE is not recommended for_non-volatile organics,
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due sorption of species with high hydrophobicity (e.g., PAHs). Borosilicate
glass is recommended over other types of glass, especially when inorganic
analytes are of concern.
6.1.3 The column must be of sufficient volume to accommodate a
minimum of a 300-g-dry material plus a 1-cm layer of silica sand (20-30 mesh) used at
the bottom of the column to distribute eluent flow and at the top of the column to form a
coarse filter for eluate particulates.
6.1.4 The column must have end cap materials that form a leak-proof seal
and that can withstand pressures, such as encountered when pumping eluent through
the column.
6.2 Eluent feed stock container — Resealable bottle or other container, constructed
of inert material, capable of withstanding extreme pH conditions and interaction with any
constituents of interest (see guidance in Sec. 6.1.2.).
6.3 Eluent feed tubing — 2-mm or similarly small ID tubing composed of
chemically-inert material such as polyvinyl chloride or equivalent.
NOTE: Larger ID tubing may be required as a feed to the pump and manifold if a single eluent
stock container is used to feed multiple column set-ups.
6.4 Eluate collection bottles — capable of assembly with column apparatus using
simple water locks in order to prevent the intrusion of air (see Figure 2).
6.5 20-30-mesh normal washed quartz sand
6.6 Balance — Capable of 0.01-g resolution for masses less than 500 g.
6.7 Filtration apparatus — Pressure or vacuum filtration apparatus composed of
appropriate materials so as to maximize the collection of extracts and minimize loss of the
COPCs (e.g., Nalgene #300-4000 or equivalent) (see Sec. 6.1).
6.8 Filtration membranes — Composed of PP or equivalent material with an
effective pore size of 0.45-um (e.g., Gelman Sciences GH Polypro #66548 from Fisher Scientific
or equivalent).
6.9 pH Meter — Laboratory model with the capability for temperature compensation
(e.g., Accumet 20, Fisher Scientific or equivalent) and a minimum resolution of 0.1 pH units.
6.10 pH combination electrode — Composed of chemically-resistant materials.
6.11 Conductivity meter — Laboratory model (e.g., Accumet 20, Fisher Scientific or
equivalent), with a minimum resolution of 5% of the measured value.
6.12 Conductivity electrodes — Composed of chemically-resistant materials.
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7.0 REAGENTS AND STANDARDS
7.1 Reagent-grade chemical must be used in all tests. Unless otherwise indicated,
it is intended that all reagents conform to the specifications of the Committee on Analytical
Reagents of the American Chemical Society, where such specification are available. Other
grade may be used, provided it is first ascertained that the reagent is of sufficiently high purity to
permit its use without lessening the accuracy of the determination. Inorganic reagents and
extracts should be stored in plastic to prevent interaction of constituents from glass containers.
7.2 Reagent water must be interference free. All references to water in this method
refer to reagent water unless otherwise specified.
7.3 Calcium chloride (1.0 mM), CaCI2 — Prepared by dissolving 0.11 g of ACS
grade or better solid calcium chloride in 1 L of reagent water.
8.0 SAMPLE COLLECTION, PRESERVATION, AND STORAGE
8.1 See the introductory material to Chapter Three "Inorganic Analytes" and
Chapter Four "Organic Analytes."
8.2 All samples should be collected using an appropriate sampling plan.
8.3 All analytical sample containers should be composed of materials that minimize
interaction with solution COPCs. For further information, see Chapters Three and Four.
8.4 Preservatives should not be added to samples before extraction.
8.5 Samples can be refrigerated, unless refrigeration results in an irreversible
physical change to the sample.
8.6 Extracts should be preserved according to the guidance given in the individual
determinative methods for the COPCs.
8.7 Extract holding times should be consistent with the aqueous sample holding
times specified in the determinative methods for the COPCs.
9.0 QUALITY CONTROL
9.1 Refer to Chapter One for guidance on quality assurance (QA) and QC
protocols. When inconsistencies exist between QC guidelines, method-specific QC criteria take
precedence over both technique-specific criteria and those criteria given in Chapter One, and
technique-specific QC criteria take precedence over the criteria in Chapter One. Any effort
involving the collection of analytical data should include development of a structured and
systematic planning document, such as a Quality Assurance Project Plan (QAPP) or a Sampling
and Analysis Plan (SAP), which translates project objectives and specifications into directions
for those that will implement the project and assess the results. Each laboratory should
maintain a formal quality assurance program. The laboratory should also maintain records to
document the quality of the data generated. All data sheets and quality control data should be
maintained for reference or inspection.
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9.2 In order to demonstrate the purity of reagents, at least one eluent blank should
be tested. If multiple batches of eluent are employed, one eluent blank from each batch should
be analyzed.
9.3 The analysis of extracts should follow appropriate QC procedures, as specified
in the determinative methods for the COPCs. Refer to Chapter One for specific quality control
procedures.
9.4 Unless the "as-received" samples are part of a time-dependent (e.g., aging)
study, solid materials should be processed and tested within one month of their receipt.
9.5 Initial demonstration of proficiency (IDP)
Leachate methods are not amenable to typical initial demonstrations of proficiency as
reference materials with known values are usually not available. However, prior to using this
method an analyst should have documented proficiency in the skills required for successful
implementation of the method. For example, skill should be demonstrated in the use of an
analytical balance, the determination of pH using methods 9040 and 9045 and the
determination of conductance using method 9050.
10.0 CALIBRATION AND STANDARDIZATION
10.1 The balance should be calibrated and certified at a minimum annually or in
accordance with laboratory policy.
10.2 Prior to measurement of eluate pH, the pH meter should be calibrated using a
minimum of two standards that bracket the range of pH measurements. Refer to Methods 9040
and 9045 for additional guidance.
10.3 Prior to measurement of eluate conductivity, the meter should be calibrated
using at least one standard at a value greater than the range of conductivity measurements.
Refer to Method 9050 for additional guidance.
11.0 PREPARATORY PROCEDURES
A flowchart for the method procedure is presented in Figure 1. Microsoft Excel data
templates are available to aid in collection and archiving of laboratory and analytical data.2
11.1 Particle-size reduction (if required)
11.1.1 In this method, particle-size reduction is used to prepare large-
grained samples for the column test so that the approach toward liquid-solid equilibrium
is enhanced and fluid channeling along column walls is minimized. The maximum
particle size of the solid should < 1/20 of the column diameter. For the column
recommended in this method, a maximum particle size of 2.5 mm is acceptable.
Therefore, 85% of the test material should pass through a 2.38-mm (U.S. No. 8) sieve.
2 The Excel data templates form the basis for uploading method data into the data management program, LeachXS
Lite™. Both the data templates and LeachXS Lite are available at http://vanderbilt.edu/leachinq.
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If less than 15% of the solid material is larger than the maximum acceptable particle
size, this fraction of the solid may be excluded from the material tested, rather than
particle size-reduced. The mass and nature of the discarded fraction should be
documented.
11.1.2 Particle-size reduction of "as received" sample may be achieved
through crushing, milling or grinding with equipment made from chemically-inert
materials. During the reduction process, care should be taken to minimize the loss of
sample and potentially volatile constituents in the sample.
11.1.3 If the moisture content of the "as received" material is greater than
15% (wet basis), air drying or desiccation may be necessary. Oven drying is not
recommended for the preparation of test samples due to the potential for mineral
alteration and volatility loss. In all cases, the moisture content of the "as received"
material should be recorded.
NOTE: If the solid material is susceptible to interaction with the atmosphere (e.g.,
carbonation, oxidation), drying should be conducted in an inert environment.
11.1.4 When the material seems to be of a somewhat uniform particle size,
calculate the percentage less than the sieve size as follows:
% Passing = Msieved x 100%
Mfotal
Where: Msieved = mass of sample passing the sieve (g)
Mtotai = mass of total sample (g) (e.g., Msieved + mass not passing sieve)
11.1.5 The fraction retained by the sieve should be recycled for further
particle-size reduction until at least 85% of the initial mass has been reduced below the
designated maximum particle size. Calculate and record the final percentage passing
the sieve and the designated maximum particle size. For the uncrushable fraction of the
"as received" material, record the fraction mass and nature (e.g., rock, metal or glass
shards, etc).
11.1.6 Store the size-reduced material in an airtight container in order to
prevent contamination via gas exchange with the atmosphere. Store the container in a
cool, dark and dry place prior to use.
11.2 Determination of solids and moisture content
11.2.1 In order to calculate eluate collection as a function of the dry-mass
equivalent of "as tested" sample material, the solids content of the solid sample material
should be determined and recorded. In this method, the moisture content is determined
and recorded on the basis of the "wet" or "as-tested" sample.
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WARNING: The drying oven should be contained in a hood or otherwise properly
ventilated. Significant laboratory contamination or inhalation hazards may
result when drying heavily contaminated samples. Consult the laboratory
safety officer for proper handling procedures prior to drying samples that
may contain volatile, hazardous, flammable or explosive materials.
11.2.2 Place a 5-10-g sample of solid material into a clean, pre-tared dish
or crucible. Dry the sample to a constant mass at 105 ± 2 °C. Periodically check the
sample mass after allowing the sample to cool to room temperature (20 ± 2 °C) in a
desiccator.
NOTE: The oven-dried sample is not used for the extraction and should be properly
disposed of once the dry mass is determined.
11.2.3 Calculate and report the solids content as follows:
SC =
M
dry
Mfest
Where: SC = solids content (g-dry/g)
Mdry = mass of oven-dried sample (g-dry)
Mtest = mass of "as-tested" sample (g)
11.2.4 Calculate and report the moisture content (wet basis) as follows:
_Mtest-Mdry
'wet
lvltest
Where: MC(wet) = moisture content on a wet basis (gH2o/g)
Mdry = mass of oven-dried sample (g-dry)
Mtest = mass of "as-tested" sample (g)
11.3 Apparatus preparation
11.3.1 Prepare the column test apparatus as depicted in Figure 2. Eluent
feed should be directed through the lower end cap and upwards into the column to
minimize air retention in the packed bed and fluid channeling along the column walls.
NOTE: When solid samples may be affected by dissolved oxygen in the feed stock, an
inert gas (e.g., nitrogen or argon) may be bubbled through the feed solution to
displace oxygen or used to purge the headspace above the feed solution.
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NOTE: When alkaline or other air-sensitive eluates are expected, the vapor space of
empty collections bottles may be purged with an inert gas (e.g., nitrogen or
argon) prior to eluate collection.
11.4 Column packing
11.4.1 The column is packed with test material surrounded by layers of
quartz sand at the top and bottom of the column to provide flow pattern regulation and
coarse filtration.
NOTE: The following procedure describes the packing of the column from starting at
the outflow (top) of the column and ending with the inflow (bottom) of the
column. This is done to allow for a wider layer of quart sand on the inflow side
in cases where less than a full column of test material is available. The column
is inverted prior to assembly into the leaching apparatus and initial wetting.
11.4.2 Record the mass of the empty column with end caps and any tubing
leads or valves that would be needed to completely separate the column, with may
include both solid material and water, from the entire apparatus.
11.4.3 Secure one end cap to the outflow side of the column and invert the
column and end cap so that the outflow side of the column is facing downward.
11.4.4 Place an approximately 1-cm thick layer of quartz sand (Sec. 6.5)
on the outflow side of the column using a small scoop or spoon. Record the mass of the
column and sand layer. Level the sand layer by tapping the sides of the column.
11.4.5 Pack the main body of the column with a minimum 300-g dry-mass
equivalent of "as tested" sample in approximately five layers with light tamping with a
glass or plastic rod to level the material between layers. When enough test material is
available to produce a full column, the top of the packed sample should be
approximately 1 cm from the level of the column interface with the inflow end cap (the
end facing upwards). Record the mass of the column, lower sand layer, and "as tested"
sample.
11.4.6 Place a layer of sand to fill the remaining gap between the sample
packing and the interface between the column and inflow end cap. When enough test
material is available to pack a full column, the sand layer at the inflow end of the column
should be approximately 1-cm. This gap may be larger if less test material is used.
Record the total mass of the completely-packed column.
11.4.7 Secure the inflow end cap. Invert the column so that the inflow end
of the column is downward prior to inserting the column into the leaching apparatus.
11.4.8 Calculate the "as tested" mass of the sample packing by subtracting
the mass of the column and lower sand layer (Sec. 11.3.3) from the mass of the column,
sand layer and packing (Sec. 11.3.4).
11.4.9 Calculate the dry-mass equivalent packed of "as tested" sample into
the column using the solids content as follows:
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Mdry=SC-Mtest
Where: Mdry = dry-mass equivalent of sample in column (g-dry)
SC = solids content (g-dry/g)
Mtest = mass of "as tested" sample in column (g)
11.4 Pump setup
11.4.1 Prior to the start of the test, set the flow rate of the pump to a value
that will provide an eluate production rate of 0.75 ± 0.25 L/S per day. For example,
given a dry-mass equivalent of 300 g-dry, an L/S of 0.75 mL/g-dry would translate to a
volume of 225 mL/g-dry, in which case the pump should be set to a flow rate of 225 ml_
(0.75 L/S) per day.
11.4.2 Prime the tubing with eluent
11.4.2.1 Detach the inlet tubing from the bottom of the column
and place the open end into a waste container.
11.4.2.2 Turn on the pump and allow the inlet tubing to fill with
eluent. Remove any air bubbles trapped in the inlet tubing.
11.4.2.3 When the inlet tubing is full with eluent, stop the pump
and reconnect the tubing to the bottom of the column.
11.5 Eluent collection schedule
11.5.1 Table 2 provides a schedule of fraction end-point L/S, interval L/S,
and eluate fraction volumes for collection, assuming a dry-mass equivalent of 300 g-dry.
The minimum volume of each collection bottle should be scaled so as to capture the
entire eluate fraction.
11.5.2 Using the assumed pump rate and the dry-mass equivalent of the
sample, calculate the durations of column testing required to reach the target eluate
collection L/S shown in Table 2 as follows:
Where: T = target time from start for collection of eluent fraction i (day)
Mdry = dry-mass equivalent of sample in column (g-dry)
ŁL/S,- = target cumulative L/S for interval i from Table 1 (mL/g-dry)
Ri = pump rate assumed for interval i (mL/day)
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Alternatively, use the provided Microsoft® Excel spreadsheet template to
develop the schedule of target collection times.
NOTE: The schedule of predicted collection times is for reference purposes only.
Typically, the eluate collection rate is slower that predicted initially, due in part to
pump inefficiencies, back pressure and dead-volume lag times. The decision to
switch collection bottles should be made based on the volume of eluate
collected with time. The schedule may be revised with each eluate fraction
collected, so that the prediction of future collections may be more accurate.
Pump flow-rate adjustment may be necessary.
12.0 COLUMN TEST PROCEDURE
12.1 Column/eluent equilibration
12.1.1 Turn on the pump and allow the column to fill with eluent, thus
wetting the column packing.
12.1.2 When the column packing is completely wetted and the eluent level
is even with the top of the column (or just beginning to be seen through the effluent
tubing at the top of the column apparatus), stop the pump and allow the column to
equilibrate for 21 ± 3 hours.
12.2 Column test
12.2.1 Following equilibration, begin the column test by starting the pump
and recording the date and time.
NOTE: The eluate production rate should be monitored frequently during the column
test and the pump rate adjusted, such that the eluate production rate is
maintained at approximately 0.75 ± 0.25 L/S per day.
12.2.2 When the eluate fraction has reached the target volume according
to the predicted collection schedule, release the Luer lock connecting the active
collection bottle and attach the eluent tubing to a new collection bottle.
NOTE: Alkaline eluate solutions may be susceptible to neutralization due to carbon
dioxide uptake. When materials with alkaline pH are tested, precautions (e.g.,
purging collection bottles with inert gas) should be taken to prevent contact of
the eluate with air.
12.3. Eluate processing
12.3.1 Decant a minimum volume (~ 5 ml_) of the eluate fraction from the
collection vessel in order to measure the solution characteristics.
12.3.2 Measure and record the pH, specific conductivity, and oxidation-
reduction potential (ORP) of the eluate (see Methods 9040, 9045, and 9050).
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NOTE: Measurement of pH, conductivity and ORP should be taken within 15 minutes of
eluate processing (Sec. 12.3.1) to avoid neutralization of the solution due to
exposure to carbon dioxide, especially when alkaline materials are tested.
NOTE: The measurement of ORP is optional, but strongly recommended, especially
when testing materials where oxidation is likely to change the LSP of COPCs.
12.3.3 Separate any suspended particulates from the remaining liquid in
the collection bottle by pressure or vacuum filtration through a 0.45-um filtration
membrane (Sec.6.8).
NOTE: If either low-volatility organic species or mercury is a COPC, pressure filtration is
recommended over vacuum filtration in order to minimize volatility losses.
12.3.4 Immediately, preserve and store the volume(s) of eluate required for
chemical analysis. Preserve all analytical samples in a manner that is consistent with
the determinative chemical analyses to be performed.
12.4 Reiterate Sees. 12.2.2-12.3.4 until nine eluate fractions are collected up to an
LS ratio of 10 ± 0.2 mL/g-dry.
NOTE: The complete method requires that all nine eluate fractions be collected from the
column. However, for purposes of limiting chemical analysis or index testing
where interpretation may be based on cumulative release from the column,
eluate fractions may be composited by volume-weighted averaging to create a
single analytical sample from multiple eluate fractions (see Sec 12.5).
12.5. Analytical sample preparation options
This method allows for options in the preparation of analytical samples based on the
detail of characterization required (e.g., complete, limited or index) and the basis for data
reporting (e.g., concentration or cumulative release). However, the complete set of nine eluate
fractions must be collected in all cases.
12.5.1 Table 1 shows the analytical preparation scheme for Options A-E
described in the following sections. Each composite sample may be created either by
combining the total eluate volumes and preserving the total sample for analysis; or
combining aliquots of two eluate fractions using volume-weighted averages. However, it
is recommended that composite analytical samples be prepared using aliquots of eluate
fractions whenever possible, rather than whole eluate fractions as this approach allows
for potential analysis of discrete eluate fractions if desired at a later date.
12.5.1.1 Option A — This sample preparation option is used for complete
characterization and includes analysis of all eluate fractions. Since the entire cumulative
release curve is captured in nine discrete fractions, reported data may be based on
either eluate concentrations or cumulative release.
12.5.1.2 Option B — This sample preparation option is used only for limited
analyses based on eluate concentration. Six discrete eluate fractions are analyzed.
Data obtained using this option cannot be used for cumulative release since there
are sections of the cumulative release curve not analyzed.
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12.5.1.3 Option C — This sample preparation option is used only for limited
analysis based on cumulative release. Six analytical samples are created from
three discrete eluate fractions and three composite samples. In the scheme shown
in Table 1, the following fractions are composited:
• T04andT05
• T06andT07
• T08andT09
12.5.1.4 Option D — This sample preparation option is used only for index
testing based on eluate concentration. Three discrete eluate fractions are analyzed.
Data obtained using this option cannot be used for cumulative release since there are
sections of the cumulative release curve not analyzed.
12.5.1.5 Option E — This sample preparation option is used only for index
testing based on cumulative release. Three analytical samples are created from
one discrete eluate fraction and two composite samples. In the scheme shown in
Table 1, the following fractions are composited:
• T02, T03, T04, and T05
• T06, T07, T08, and T09
12.5.2 Volume-weighted composites
12.5.2.1 The volume of aliquots of eluate fractions for composite analytical
samples may be calculated using the Excel template provided or the following
formula:
"i n x "sample
Where: V, = the volume of an aliquot from eluate fraction i (ml)
FJ = the collected volume of eluate fraction i (ml)
Vsampie = the total volume of the analytical sample (ml)
n = total number of eluate fractions to be composited
As an illustration of volume-weighted averaging, eluate fraction aliquots are
calculated as required to create an analytical sample by compositing eluate fractions
T06 through T09 for index testing based on cumulative release. The calculation
follows the example volumes shown in Table 2 and assumes that an analytical
sample volume of 100 ml_ is required.
FT06 + FT07 + FT08 + FT09 = 450 ml +150 ml +1350 ml +150 ml = 2100 ml
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VT06 = 8- x Vsample = x 100 ml = 21 .5 ml
>/ 'TO7 >/ 150 mL .«,»,» , _ ^ ,
VT07 = -^ x Vsample = x 100 ml = 7.1 ml
i/ FT08 1350 mL .__ , _. _ ,
VTOS = -^ x Vsample = ..-- . x 100 mL = 64.3 mL
VT09 = *- x Vsample = x 100 ml = 7.1 ml
? '
i
Vsample = VT06 + VT07 + VT08 + VT09 = 21 -5 mL + 7 1 mL + 64.3 ml + 7.1 ml = 100.0 ml
NOTE: The above illustration uses example eluate fraction volumes based on
interval LS ratios and an assumed test material mass. When calculating the
aliquots of collected eluates fractions for composite samples, the actual collected
fraction volumes should be used.
13.0 DATA ANALYSIS AND CALCULATIONS (EXCEL TEMPLATE3)
13.1 Data reporting
Figure 3 presents an example of a data sheet that may be used to report the
concentration results of this method. This example is included in the Excel template. At
a minimum, the basic test report should include the following:
a) Name of the laboratory
b) Laboratory contact information
c) Date and time at the start of eluate flow (start of test)
d) Name or code of the solid material tested
e) Particle size (85 wt% less than)
f) Packed bed dimensions (column ID and bed depth (cm))
g) Mass of solid material in column packing
h) Moisture content of solid material packed in column (gH2o/g)
i) Eluate specific information (see below)
The minimum set of data that should be reported for each eluate includes:
a) Eluate sample ID
3 Excel data templates are provided to aid in collection and archiving of laboratory and analytical data. These
templates form the basis for uploading method data into the data management program, LeachXS Lite™. Both the
data templates and LeachXS Lite are available at http://vanderbilt.edu/leachinq.
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b) Eluate collection date and time
c) Amount of eluate collected (mass or volume)
d) Measured eluate pH
e) Measured eluate conductivity (mS/cm)
f) Measured ORP (mV) (optional)
g) Concentration of all COPCs
h) Analytical QC qualifiers as appropriate
13.2 Data Interpretation (optional)
13.2.1 Concentration as a function of LS ratio
13.2.1.1 A curve of the eluate concentration as a function of L/S can be
generated for each COPC after chemical analysis of all extracts by plotting the
constituent concentration in the liquid phase as a function of the cumulative collected LS
ratio. The curve indicates the nominal equilibrium concentration of the constituent of
interest as a function of L/S from 0 to 10 mL/g-dry at natural pH. An example such curve
is provided in Figure 4.
13.2.1.2 The lower limit of quantitation (LLOQ) of the determinative method
for each COPC may be shown as a horizontal line. COPC concentrations below this line
indicate negligible or non-quantitative concentrations.
NOTE: The lower limit of quantitation is highly matrix dependent and should be
determined as part of a QA/QC plan.
13.3 Cumulative release as a function of LS ratio
13.4.1 The cumulative mass release of a COPC per unit solid material may
be calculated as follows:
Where: EM, = the cumulative mass release through interval i (mg/kg-dry])
C, = the concentration of the COPC in the eluent collected during
interval i (mg/L)
EL/S, = the cumulative LS ratio of eluate collected through
interval i (L/kg-dry)
= the cumulative LS ratio of eluate collected through
interval i-1 (L/kg-dry)
13.4.2 Prepare a curve of the cumulative mass release generated for each
COPC by plotting the cumulative mass release calculated in Sec. 13.4.1 as a function of
the cumulative collected L/S. This curve provides an interpretation of the cumulative
mass expected to be leached from a column of material as a function of LS ratio
percolating through the column.
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13.4.3 A comparison of the slope of the mass release curve to a unity
slope, which is indicative of solubility-controlled release, may be made by plotting the
cumulative mass release calculated in Sec. 13.4.1 versus the logarithm of the
cumulative collected US. An example is provided in Figure 5.
13.3 Interpolation/extrapolation to target US values
The collected L/S-dependence data may be interpolation or extrapolated to the nearest
target US value for purposes of comparing different data sets (e.g., test replicates of the same
or different materials). The most transparent and straight-forward method is linear
interpolation/extrapolation of data after Iog10-transformation.
13.3.1 Log10-transform
Collected concentration values are transformed by taking the Iog10 of the
measured concentration at each test position, i:
C, =
Where: q = the concentration measured at test position, i, (mg/L)
d = Iog10-transformed concentration at test position, i, (Iog10[ml_/g-dry])
13.3.2 Linear interpolation/extrapolation
Given a set of coordinate data { (EUSj ,Cj) : i = 1,...n} sorted by into increasing
order by EUS value (e.g., EL/Si < EL/S2 < ••• < EUSn), an interpolated/extrapolated Iog10-
transformed concentration at a known L/S target is calculated as:
Where: EUST = a target pH value
CT = the concentration at target EUS value, EUST (Iog10[mg/l_])
Depending on the values of observed US values relative to target L/S values, the
calculations of the coefficients aT and bT in the equation may differ according to the
following algorithm:
• If EL/ST < EL/Si, then bT = (C2 - Ci) / (EUS2 - EL/Si) and aT = C2 - brEL/S2
(extrapolation from the two points with closest L/S values);
• If EL/ST ^ EL/Sn, then bT =(Cn - Cn-i) / (EL/Sn - EUSn-i) and aT = Cn - brEUSn
(extrapolation from the two points with closest L/S values);
• If EL/Sj-i < EUST < EL/Sj , then bT = (Cj - Chi) / (EUSj - EUSH)and aT = y -
brEL/Sj (interpolation from the two closest points surrounding EL/ST).
NOTE: Interpolation or extrapolation of data should only be conducted within a distance
of ±20% of the target L/S value. Since the allowable US tolerance about a target
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L/S values is variable (see Table 2), interpolation/extrapolation should not create
data at a target US value where collected data is missing.
14.0 METHOD PERFORMANCE
14.1 Performance data and related information are provided in SW-846 methods
only as examples and guidance. The data do not represent required performance criteria for
users of the methods. Instead, performance criteria should be developed on a project-specific
basis, and the laboratory should establish in-house QC performance criteria for the application
of this method. These performance data are not intended to be and must not be used as
absolute QC acceptance criteria for purposes of laboratory accreditation.
14.2 Interlaboratory validation of this method was conducted using a contaminated
smelter site soil (material code CFS) and a brass foundry sand (material code JaFS).
Repeatability and reproducibility was determined at an US of 10 mL/g-dry for eluate
concentration (see Table 3) and for cumulative mass released (see Table 4). More details on
the interlaboratory validation may be found in Ref. 3.
14.3 Refs. 4 and 5 may provide additional guidance and insight on the use,
performance and application of this method.
15.0 POLLUTION PREVENTION
15.1 Pollution prevention encompasses any technique that reduces or eliminates the
quantity and/or toxicity of waste at the point of generation. Numerous opportunities for pollution
prevention exist in laboratory operations. The EPA has established a preferred hierarchy of
environmental management techniques that places pollution prevention as the management
option of first choice. Whenever feasible, laboratory personnel should use pollution prevention
techniques to address their waste generation. When wastes cannot be feasibly reduced at the
source, the Agency recommends recycling as the next best option.
15.2 For information about pollution prevention that may be applicable to
laboratories and research institutions consult Less is Better: Laboratory Chemical Management
for Waste Reduction available from the American Chemical Society's Department of
Government Relations and Science Policy, 1155 16th St., N.W. Washington, D.C. 20036,
http://www.acs.org.
16.0 WASTE MANAGEMENT
The Environmental Protection Agency requires that laboratory waste management
practices be conducted consistent with all applicable rules and regulations. The Agency urges
laboratories to protect the air, water, and land by minimizing and controlling all releases from
hoods and bench operations, complying with the letter and spirit of any sewer discharge permits
and regulations, and by complying with all solid and hazardous waste regulations, particularly
the hazardous 1314 -18 Rev 0 January 2009 Pre-release DRAFT for comment waste
identification rules and land disposal restrictions. For further information on waste
management, consult The Waste Management Manual for Laboratory Personnel available from
the American Chemical Society at the address listed in Sec. 15.2.
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17.0 REFERENCES
1. MEN 7343 (1995) Leaching Characteristics of Solid Earth and Stony Materials -
Leaching Tests - Determination of the leaching of Inorganic Constituents from Powdery
and Granular Materials with the Percolation Test, Dutch Standardization Institute, Delft,
The Netherlands.
2. CEN/TS14405 (2004) Characterization of Waste - Leaching Behaviour Tests - Up-flow
Percolation Test (Under Specified Conditions), Comite Europeen de Normalisation,
Brussels, Belgium.
3. A.C. Garrabrants, D.S. Kosson, R. DeLapp, P. Kariher, P.F.A.B. Seignette, H.A. van der
Sloot, L. Stefanski, and M. Baldwin (2012) "Interlaboratory Validation of the Leaching
Environmental Assessment (LEAF) Method 1314 and Method 1315," Draft, U.S.
Environmental Protection Agency, Washington DC, April 2012.
4. D.S. Kosson, H.A. van der Sloot, F. Sanchez and A.C. Garrabrants, (2002), "An
Integrated Framework for Evaluating Leaching in Waste Management and Utilization of
Secondary Materials," Environmental Engineering Science, 19(3) 159-204.
5. A.C. Garrabrants, D.S. Kosson, H.A. van der Sloot, F. Sanchez and O. Hjelmar (2010)
"Background Information for the Leaching Environmental Assessment Framework
(LEAF) Test Methods," EPA/600/R-10-170, U.S. Environmental Protection Agency,
Washington, DC, December 2010.
18.0 TABLES, DIAGRAMS, FLOWCHARTS, AND VALIDATION DATA
The following pages contain the tables and figures referenced by this method.
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TABLE 1
SCHEDULE OF FRACTION COLLECTIONS AND ANALYTICAL SAMPLES
Option
Fraction
Label
T01
T02
T03
T04
T05
T06
T07
T08
T09
ZLS Ratio
(mL/g-dry)
0.2 ±0.1
0.5 ±0.1
1.0±0.1
1.5 ±0.2
2.0 ±0.2
4.5 ±0.2
5.0 ±0.2
9.5 ±0.2
10.0 ±0.2
A
Characterization
Cone.
S
S
s
s
s
s
s
s
s
ZRel
S
•/
s
•/
s
•/
s
•/
s
B
c
Limited Analysis
Cone.
S
S
s
s
s
s
ZRel
S
S
s
;
^T05c
^
^T07c
^
^T09c
D
E
Index Testing
Cone.
S
s
s
ZRel
S
^
^
^
^T05c
^
^
^
^T09c
NOTE: ZRel = Cumulative release.
•S = Collect eluate fraction (or pool of fractions) as analytical sample.
-i- = composite eluate fraction with next fraction to create analytical sample.
TABLE 2
SCHEDULE OF ELUATE FRACTIONS FOR COLLECTION
WITH EXAMPLE VOLUMES
Interval
Label
T01
T02
T03
T04
T05
T06
T07
T08
T09
B01
End Point
ZL/S Ratio
(mL/g-dry)
0.2 ±0.1
0.5 ±0.1
1.0±0.1
1.5 ±0.2
2.0 ±0.2
4.5 ±0.2
5.0 ±0.2
9.5 ±0.2
10.0 ±0.2
Eluent
Fraction
L/S Ratio
(mL/g-dry)
0.2
0.3
0.5
0.5
0.5
2.5
0.5
4.5
0.5
Example
Fraction
Volume
(mL)
60
90
150
150
150
750
150
1350
150
100
NOTE: Example fraction volumes based on assumed packing mass of 300 g-dry.
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TABLE 3
METHOD PRECISION FOR ELUATE CONCENTRATION AT L/S=10 mL/g-dry
Repeatability
Reproducibility
Analyte
Aluminum
Barium
Boron
Cadmium
Calcium
Copper
Magnesium
Manganese
Molybdenum
Lead
Thallium
Zinc
Symbol
Al
Ba
B
Cd
Ca
Cu
Mg
Mn
Mo
Pb
Tl
Zn
Material Mean
Overall Mean
CFS
%RSDr
8.6
6.9
11.9
9.2
6.9
8.1
-
-
25.2
7.3
9.6
8.6
10%
JaFS
%RSDr
12.7
13.9
14.4
-
5.6
13.3
7.7
22.0
27.5
12.4
-
23.0
15%
13%
CFS
%RSDR
16.6
23.0
14.3
14.6
12.7
15.2
-
-
28.4
14.8
19.2
16.0
18%
JaFS
%RSDR
28.2
24.2
23.9
-
52.5
31.8
53.3
26.6
54.4
23.5
-
58.5
38%
28%
Data taken from Reference 3.
TABLE 4
METHOD PRECISION FOR CUMULATIVE RELEASE AT L/S=10 mL/g-dry
Repeatability
Reproducibility
Analyte
Aluminum
Barium
Boron
Cadmium
Calcium
Copper
Magnesium
Manganese
Molybdenum
Lead
Thallium
Zinc
Symbol
Al
Ba
B
Cd
Ca
Cu
Mg
Mn
Mo
Pb
Tl
Zn
Material Mean
Overall Mean
CFS
%RSDr
4.6
3.4
2.9
2.2
2.1
3.9
-
-
4.4
1.8
2.9
4.0
3%
JaFS
%RSDr
7.2
6.2
4.4
-
3.6
4.6
4.2
7.0
4.5
9.5
-
7.3
6%
5%
CFS
%RSDR
14.3
23.0
11.1
8.5
8.2
15.3
-
-
12.3
10.8
10.2
11.3
13%
JaFS
%RSDR
13.1
10.9
6.3
-
19.9
21.4
17.2
14.9
11.1
15.1
-
18.6
15%
14%
Data taken from Reference 3.
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FIGURE 1
METHOD 1314 FLOWCHART
Material of
Interest
is mate rial at
appropriate
partidosizc?
Particle Size Reduction
(Section 11.1)
Solids/Moisture Content
(Section 11.2)
Column Packing
(Section 11.4)
Eluant Collection Schedule
(Section 11.6)
Column Test Procedure
(Section 12)
Collection 9 eluatc factions
Leachatc pH, EC, Eh
v
/or
Characterization
Option A
(Sec 12.5)
9 discrete samples
Limited Analysis
OptionB
(See 12.5)
6 discrete samples
Li mi ted Analysis
Option C
(Sec 12.5)
3 discrete samples
3 composite samples
i
IndexTesting
Option D
(Sec 12.5)
3 discrete samples
IndexTesting
Option E
(Sec 12.5)
1 discrete sample
2 composite samples
Extract Analysis
J^
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FIGURE 2
SCHEMATIC OF COLUMN TEST APPARATUS
Luer fitting
/"
Luer shut-off
valve x.
end cap ->
subject
material
end cap -> Ł
Luer shut-off
valve
A
air lock
eluant collection bottle(s)
(sized for fraction volume)
1-cm sand
layers
Luer fitting
pump
eluant
reservoir
N2or Ar
(optional)
NOTE: Figure not drawn to scale
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FIGURES
EXAMPLE DATA REPORT FORMAT
ABC Laboratories
123 Main Street
Anytown, USA
Contact: John Smith
(555) 111-1111
EPA METHOD 1314
Report of Analysis
Client Contact: Susan Jones
(555) 222-2222
Material Code: XYZ
Material Type: Coal Combustion Fly Ash
Test
Position
T01
Test
Position
T02
Date Received: 10/1/20xx
Test Date: 11/1/20xx
Report Date: 12/1/20xx
Replicate
A
Eluate Sample ID
Collection Date
Collection Time
Eluate Mass
Eluate pH
Eluate Conductivity
Eluate ORP
Chemical Analysis
Al
As
Cl
Replicate
A
Eluate Sample ID
Collection Date
Collection Time
Eluate Mass
Eluate pH
Eluate Conductivity
Eluate ORP
Chemical Analysis
Al
As
Cl
Value
Units
Particle Size:
Mass used in Column:
Moisture Content:
Column ID:
Packing Bed Depth:
Eluent:
Lab Temperature:
Method
88% passing 2-mm sieve
360 g
0.002 gH2o/g
4.8 cm
28 cm
ASTMTypellWater
21 ±2°C
Note
XYZ-1314-T01-A
11/1/20xx
12:35
70.4
8.82
5.4
NA
Value
4.72
0.12
5.42
Value
PM
g
-
mS/c
mv
Units
mg/L
mg/L
mg/L
Units
EPA 9040
EPA 9050
QC
Flag Method
EPA 6020
EPA 6020
EPA 9056
Method
Dilution
Date Factor
11/7/20xx 1000
11/7/20xx 10
11/9/20xx 1
Note
XYZ-1314-T02-A
11/1/20XX
9:15
105.1
9.15
2.3
NA
Value
2.99
0.21
4.20
AM
g
-
mS/c
mv
Units
mg/L
mg/L
mg/L
QC
Flag Method
EPA 6020
EPA 6020
U EPA 9056
Dilution
Date Factor
11/7/20xx 1000
11/7/20xx 10
11/7/20xx 1
QC Flag Key: U Value below lower limit of quantitation as reported (< "LLOQ")
A-25
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FIGURE 4
EXAMPLE ELUATE CONCENTRATION CURVES FOR COMPLETE CHARACTERIZATION
OF A COAL COMBUSTION FLY ASH
1 UUUUU -
10000 -
1000 -
B 10° '
10 -
01 -
*>•
f ML
\ MDL
)
o
1 UUUUU '
innnn -
1000 -
| 100 -
i= ID
3
•c
do
n 1 -
.01 u.u i
0 2 4 6 8 10 12 C
a> Cumulative LS Ratio b)
10000 -
1000 -
O> IUU
^.
I" 10 -
1
1X1
. 1
n m
O
O
0^
ML
L_«
0
0
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100 -
10 -
ra
Ł 0.1 -
1 0.01 -
'o
Ł 0.001 -
0.0001 -
n nnnm
0 2 4 6 8 10 12 C
c> Cumulative LS Ratio d)
100 -
10 -
I .;:
§
a> U.UI
o 0.001
0.
0.0001 -
P
°0c
f ML
MDl
>
_
0
o
w » — .
IU
1 -
17 0.1 -
E_
Ł
a
| 0.001 -
C/5
0.0001 -
.UUUU 1 u.uuuvj i
0 2 4 6 8 10 12 C
UUUU "
nnnn -
1000 -
i nn -
IUU
1U
i ,
n 1 -
n n i -
^0
oc
f ML
MDL
i • i i
>
i— 1— 1 — 1 —
00
0°
2 4 6 8 10
Cumulative LS Ratio
2 4 6 8 10
Cumulative LS Ratio
12
IUUU
100 -
10 -
I
! o.i -
0.01 -
.U(J1
Onnn-i
.UUUI
n nnnm .
QC
f n
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)
I I I
GO °0
12
boo
f
1 MD!
)
0
O
°0
Cumulative LS Ratio
'
2 4 6 8 1C
Cumulative LS Ratio
12
1314-26
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Intel-laboratory Validation of LEAF Method 1314 and Method 1315
FIGURES
EXAMPLE CUMULATIVE RELEASE CURVES FOR COMPLETE CHARACTERIZATION OF A
COAL COMBUSTION FLY ASH
iuu -
"E
I 1°-
ŁŁ.
QP
E,
•
! "
<
c
X
9'
X
•O
: / 0
- f/ 0
A
i ^x
x^slope= 1
X
/ . . .9 , ,
iuu -
?
7 10 -
51
"01
Ł
a
in ^
as 1 "
a:'
a)
QL
•
Q]
slop
/
e = l xH
/ '
/
/
X
xx 0
xX °
^xcP
y-
0
/
X
,A ,,
0.1 1 1 u.i T ' 1 1
0.1 1 10 100 0 1 10 1CO
a) Cumulative LS Ratio b' Cumulative LS Ratio
ifirm -j /-in.". «-i
1CULJ
5
7 100 -
1
Ł
10 -
m
slops =1 /
il
-o
X T
,,/ (
C
x9°
A
Vy/
Of
/
X
/
I UUUU "
^
Y 1000 -
I
Ł
V
1 10D "
u>
-aj
K
a
-4 iTH
A
.L — 1
xX slope =1
' j -
X J»» V
. 00° v
o/x
X
; / v^
• X
t
1 • "> ' IU
0 ' 10 100 0 1 ID ICO
Cumulative LS Ratio d' Cumulative LS Ratio
\ uuuu
7 1000 -
Ł
f~"
0
ra 1DO -
0
|
X
f
•f
jpe=l
/
X
- 0/6 ooo © <
X
X
X
I
;
1 UU
5
•9 10 -
s
E,
en
CO 1 ~
0)
Ł
*^ J
^ (Llnap = 1
x
X
rtX
O
X
/
Q
s
.
. /
'
10 T ' 1 u. i 1 ' 1 '
C 1 10 100 0.1 1 1C ICO
e) Cumulative LS Ratio 0 Cumulative LS Ratio
NOTE: Dashed line represents solubility control (slope = 1).
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Appendix B. Method 1315: Mass Transfer Rates from Monolithic and
Compacted Granular Materials using a Semi-Dynamic Tank
Leaching Procedure
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METHOD 13151
MASS TRANSFER RATES IN MONOLITHIC OR COMPACTED GRANULAR MATERIALS
USING A SEMI-DYNAMIC TANK LEACHING PROCEDURE
SW-846 is not intended to be an analytical training manual. Therefore, method
procedures are written based on the assumption that they will be performed by analysts who are
formally trained in at least the basic principles of chemical analysis and in the use of the subject
technology.
In addition, SW-846 methods, with the exception of required method use for the analysis
of method-defined parameters, are intended to be guidance methods which contain general
information on how to perform an analytical procedure or technique which a laboratory can use
as a basic starting point for generating its own detailed Standard Operating Procedure (SOP),
either for its own general use or for a specific project application. The performance data
included in this method are for guidance purposes only, and are not intended to be and must not
be used as absolute quality control (QC) acceptance criteria for purposes of laboratory
accreditation.
1.0 SCOPE AND APPLICATION
1.1 This method is designed to provide the mass transfer rates (release rates) of
inorganic analytes contained in a monolithic or compacted granular material, under diffusion-
controlled release conditions, as a function of leaching time. Observed diffusivity and tortuosity
may be estimated through analysis of the resulting leaching test data.
1.2 This method is suitable to a wide range of solid materials which may be in
monolithic form (e.g., cements, solidified wastes) or may be compacted granular materials (e.g.,
soils, sediments, stacked granular wastes) which behave as a monolith in that the predominant
water flow is around the material and release is controlled by diffusion to the boundary.
1.3 This leaching characterization method provides intrinsic material parameters for
release of inorganic species under mass transfer-controlled leaching conditions. This test
method is intended as a means for obtaining a series of eluents which may be used to estimate
the diffusivity of constituents and physical retention parameter of the solid material under
specified laboratory conditions.
1.4 This method is not applicable to characterize the release of volatile or semi-
volatile organic analytes.
1 This method has been derived from the MT001 and MT002 procedures (Ref. 1). The method is analogous to the
monolithic mass transfer methods NEN7345 (Ref 2) developed under Dutch regulation and CEN/TS15863 (Ref. 15)
developed for the Comite Europeen de Normalisation (CEN).
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1.5 This method is a characterization method and does not provide a solution
considered to be representative of eluate under field conditions. This method is similar in
structure and use to predecessor methods such as MT001.1 (see Ref. 1), MEN 7345 (see Ref.
2), ANSI/ANS 16.1 (see Ref. 3), and ASTM C1308 (see Ref. 4). However, this method differs
from previous methods in that: (a) leaching intervals are modified to improve quality control, (b)
sample preparation accounts for mass transfer from compacted granular samples, and (c) mass
transfer may be interpreted by more complex release models that account for physical retention
of the porous medium and chemical retention at the pore wall through geochemical speciation
modeling
1.7 The geometry of monolithic samples may be rectangular (e.g., bricks, tiles),
cubes, wafers, cylinders. Samples may also have a variety of faces exposed to eluent forming
anything from 1-dimensional (1-D) through 3-dimensional (3-D) mass transfer cases. In all
cases, a minimum sample size of 5 cm in the direction of mass transfer must be employed and
the liquid-surface-area ratio (L/A) must be maintained at 9 ± 1 mUcrn2.
Monolithic samples should be suspended or held in the leaching fluid such that at least
98% of the entire sample surface area is exposed to eluent and the bulk of the eluent (e.g., a
minimum of 2 cm between any exposed surface and the vessel wall) is in contact with the
exposed sample surface. Figure 1 provides examples of appropriate sample holders and
leaching configurations for 3-D and 1-D cases.
1.8 Compacted granular materials are granular solids, screened to pass a
2-mm sieve, compacted following a modified Proctor compaction effort (see Ref. 5). The
sample geometry must be open-faced cylinders due to limitations of mechanical packing.
However, the diameter and height of the sample holder may be altered to correspond
appropriately with the diameter and volume of the leaching vessel. In all cases, the sample size
of at least 5 cm in the direction of mass transfer must be employed and the L/A must be
maintained at 9 ± 1 mL/cm2.
The sample should be positioned at the bottom of the leaching vessel with a minimum of
5 cm of distance between the solid-liquid interface and the top of the vessel. The distance
between the non-leaching faces (i.e., outside of the mold surfaces) and the leaching vessel wall
should be minimized to < 0.5 cm, such that the majority of the eluent volume is on top of the
sample. Figure 2 shows an example of a holder and leaching configuration for a compacted
granular sample.
1.9 The solvent system used in this characterization method is reagent water.
Other systems (e.g., groundwater, seawater, and simulated liquids) may be used to infer
material performance under specific environmental conditions. However, interaction between
the eluent and the solid matrix may result in precipitation and pore blocking, which may interfere
with characterization or complicate data interpretation.
1.10 Prior to employing this method, analysts are advised to consult the base
method for each type of procedure that may be employed in the overall analysis (e.g., Methods
9040, 9045) for additional information on QC procedures, development of QC acceptance
criteria, calculations, and general guidance. Analysts also should consult the disclaimer
statement at the front of the manual and the information in Chapter Two for guidance on the
intended flexibility in the choice of methods, apparatus, materials, reagents, and supplies, and
on the responsibilities of the analyst for demonstrating that the techniques employed are
appropriate for the analytes of interest, in the matrix of interest, and at the levels of concern. In
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addition, analysts and data users are advised that, except where explicitly specified in a
regulation, the use of SW-846 methods is not mandatory in response to Federal testing
requirements. The information contained in this method is provided by EPA as guidance to be
used by the analyst and the regulated community in making judgments necessary to generate
results that meet the data quality objectives for the intended application.
1.11 Use of this method is restricted to use by, or under supervision of, properly
experienced and trained personnel. Each analyst must demonstrate the ability to generate
acceptable results with this method.
2.0 SUMMARY OF METHOD
This method comprises leaching of continuously water-saturated monolithic or
compacted granular material in an eluent-filled tank with periodic renewal of the leaching
solution. The vessel and sample dimensions are chosen such that the sample is fully immersed
in the leaching solution. Monolithic samples may be cylinders or parallelepipeds, while granular
materials are compacted into cylindrical molds at optimum moisture content using modified
Proctor compaction methods (see Ref. 5). In either case, the exposure of a regular geometric
area to the eluent is recommended. Samples are contacted with reagent water at a specified
L/A. The leaching solution is exchanged with fresh reagent water at nine pre-determined
intervals (see NOTE below). The sample is freely drained and the mass is recorded to monitor
the amount of eluent absorbed into the solid matrix at the end of each leaching interval. The
eluate pH and specific conductance is measured for each time interval and analytical samples
are collected and preserved accordingly based on the determinative methods to be performed.
Eluate concentrations are plotted as a function of time, as a mean interval flux and as
cumulative release as a function of time. These data are used to estimate mass transfer
parameters (i.e., observed diffusivity) for each constituent of potential concern (COPC). A
flowchart for performing this method is shown in Figure 3.
NOTE: The leaching schedule may be extended for additional exchanges with individual
intervals of 14 days to provide more information about longer-term release.
3.0 DEFINITIONS
3.1 COPC — A chemical species of interest, which may or may not be regulated,
but may be characteristic of release-controlling properties of the sample geochemistry.
3.2 Release — The dissolution or partitioning of a COPC from the solid phase to
the aqueous phase during laboratory testing (or under field conditions). In this method, mass
release is expressed in units of mg COPC/kg dry solid material.
3.3 Liquid-to-surface-area ratio (L/A) — The ratio representing the total liquid
volume used in the leaching interval to the external geometric surface area of the solid material.
L/A is typically expressed in units of mL of eluent/cm2 of exposed surface area.
3.4 Observed mass diffusivity —the apparent, macroscopic rate of release due to
mass transfer from a solid into a liquid as measured using a leaching test under conditions
where mass transfer controls release. The observed diffusivity accounts for all physical and
chemical retention factors influencing mass transfer and is typically expressed in units of cm2/s.
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3.5 Effective mass diffusivity — The intrinsic rate of mass transfer in a porous
medium accounting for physical retention. The effective mass diffusivity is typically expressed
in units of cm2/s.
3.6 Physical retention factor — A mass transfer rate term that describes the
retardation of diffusion due to intrinsic physical properties of a porous medium (e.g., effective
porosity, tortuosity).
3.7 Chemical retention factor — A mass transfer rate term that describes the
chemical processes (e.g., dissolution/precipitation, adsorption/desorption, complexation)
occurring at the pore water interface with the solid mineral phases within the porous structure of
the solid material.
3.8 Refer to the SW-846 chapter of terms and acronyms for potentially applicable
definitions.
4.0 INTERFERENCES
4.1 Solvents, reagents, glassware, and other sample processing hardware may
yield artifacts and/or interferences to sample analysis. All of these materials must be
demonstrated to be free from interferences under the conditions of the analysis by analyzing
method blanks. Specific selection of reagents and purification of solvents by distillation in all-
glass systems may be necessary. Refer to each method to be used for specific guidance on
QC procedures and to Chapters Three and Four for general guidance on the cleaning of
laboratory apparatus prior to use.
4.2 The reaction of atmospheric gases can influence the measured concentrations
of constituents in eluates. For example, reaction of carbon dioxide with eluents from highly
alkaline or strongly-reducing materials will result in neutralization of eluate pH and precipitation
of carbonates. Leaching vessels, especially those used when testing highly alkaline materials,
should be designed to be air-tight in order to minimize the reaction of samples with atmospheric
gases.
4.3 Use of certain solvent systems may lead to precipitation at the material surface
boundary which may reduce mass transport rates. For example, exposure of cement-based
materials to seawater leads to sealing of the porous block (see Ref. 6).
5.0 SAFETY
This method does not address all safety issues associated with its use. The laboratory
is responsible for maintaining a safe work environment and a current awareness file of OSHA
regulations regarding the safe handling of the chemicals listed in this method. A reference file
of material safety data sheets (MSDSs) should be available to all personnel involved in these
analyses.
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6.0 EQUIPMENT AND SUPPLIES
The mention of trade names or commercial products in this manual is for illustrative
purposes only, and does not constitute an EPA endorsement or exclusive recommendation for
use. The products and instrument settings cited in SW-846 methods represent those products
and setting used during the method development or subsequently evaluated by the Agency.
Glassware, reagents, supplies, equipment, and setting other than those listed in this manual
may be employed provided that method performance appropriate for the intended application
has been demonstrated and documented.
This section does not list common laboratory glassware (e.g., beakers and flasks).
6.1 Sample holder
6.1.1 Monolithic samples
6.1.1.1 A mesh or structured holder constructed of an inert
material such as high-density polyethylene (HOPE) or other material resistant to
high and low pHs is recommended.
6.1.1.2 The holder should be designed such that at least 98%
of the sample external surface area may be exposed to eluent.
6.1.1.3 The holder should be designed to match the geometry
of the mass transfer such that the bulk of the eluent may be in contact with the
sample and the exposed surfaces of the sample centered within the leaching
fluid.
NOTE: In the case of 1-D mass transfer from the axial face of a cylindrical
sample, the outer diameter (OD) of the holder should be matched as
closely as possible to the inner diameter (ID) of the leaching vessel so
that the majority of the eluent is above the sample (e.g., in contact with
the exposed material surface), while allowing for easy placement and
removal of the holder in the leaching vessel (see Figure 1).
6.1.2 Compacted granular samples
6.1.2.1 A cylindrical mold constructed of an inert material such
as HOPE or other material resistant to high and low pH is recommended.
6.1.2.2 The holder should be capable of withstanding the
compaction force required to prepare the sample (see Sec 11.3.5) without
breaking or distorting.
NOTE: The outer diameter of the holder for a compacted granular sample
should be matched as closely as possible to the inner diameter of the leaching
vessel so that the majority of the eluent is above the sample (e.g., in contact
with the exposed material surface) while allowing for easy placement and
removal of the holder in the leaching vessel.
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6.2 Leaching vessel
6.2.1 A straight-sided container constructed of a material resistant to high
and low pH is recommended. Jars or buckets composed of HOPE, polycarbonate (PC),
polypropylene (PP), or polyvinyl chloride (PVC) are recommended when evaluating the
mobility of inorganic species.
6.2.2 The leaching vessel should have an air-tight seal that can sustain
long periods of standing without gas exchange with the atmosphere.
6.2.3 The container must be of sufficient volume to accommodate both
the solid sample and an eluent volume based on an L/A of 9 ± 1 ml_ eluent/cm2 sample
surface area. Ideally, the vessel should be sized such that the headspace is minimized
within the tolerance of the L/A.
6.3 Leaching setup
Example photos of three possible leaching equipment arrangements for monolithic and
compacted granular samples are shown in Figures 1 and 2, respectively. The equipment used
in the each of these cases is described below.
6.3.1 Figure 1a shows a monolithic sample 3-D configuration with the
following accessories:
Sample holder— PP sink washers, 43-mm OD, 37-mm ID, 6-mm high, with
four holes drilled at the quadrants to accept
2-mm OD nylon string knotted at top.
Sample stand — PVC pipe, 47-mm OD, 51-mm high, cut to have four legs
approximately 8-mm wide and 30-mm high.
Leaching Vessel — PP bucket, 140-mm ID at top, 120-mm ID at bottom,
200-mm high (Berry Plastics #T51386CP3, VWR Scientific, or equivalent).
6.3.2 Figure 1b shows a monolithic sample 1-D configuration with the
following accessories:
Sample holder— Polyethylene (PE) mold, 54-mm OD, 100-mm high
(MA Industries, Peach Tree City, GA, or equivalent), with the test sample cured in mold
and cut to 51-mm high.
Leaching vessel — 250-mL PC jar, (60-mm ID, 100-mm high, (Nalgene#2116-
0250, Fisher Scientific, or equivalent).
6.3.3 Figure 2 shows a compacted granular sample 1-D Configuration
with the following accessories:
Sample holder— PE mold, 100-mm OD, 200-mm high, (MA Industries, Peach
Tree City, GA, or equivalent) cut to 63-mm high with three tabs drilled for 0.7-mm fishing
line knotted at the top.
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Leaching vessel — 1000-mL PC jar, 110-mm ID at top, 130-mm high (Nalgene
#2116-1000, Fisher Scientific, or equivalent).
Glass beads, borosilicate — 2-mm diameter
6.4 Filtration apparatus — Pressure- or vacuum-filtering apparatus made of
appropriate materials to maximize the collection of extracts and minimize the loss of COPCs
(Nalgene #300-4000 or equivalent).
6.5 Filtration membranes — Composed of hydrophilic PP or similar material with an
effective pore size of 0.45-um (e.g., Andwin Scientific GH Polypro 28143-288 or equivalent).
6.6 pH Meter — Laboratory model with the capability for temperature compensation
(e.g., Accumet 20, Fisher Scientific or equivalent) and a minimum resolution of 0.1 pH units.
6.7 pH combination electrode — Composed of chemically-resistant materials.
6.8 Conductivity meter — Laboratory model (e.g., Accumet 20, Fisher Scientific or
equivalent), with a minimum resolution of 5% of the measured value.
6.9 Conductivity electrodes — Composed of chemically-resistant materials.
6.10 Proctor compactor (for compacted granular samples only) — Equipped with a
slide hammer capable of dropping a 4.5-kg weight over a 0.46-m interval (see Ref. 5 for further
details).
7.0 REAGENTS AND STANDARDS
7.1 Reagent-grade chemicals must be used in all tests. Unless otherwise
indicated, it is intended that all reagents conform to the specifications of the Committee on
Analytical Reagents of the American Chemical Society, where such specification are available.
Other grade may be used, provided it is first ascertained that the reagent is of sufficiently high
purity to permit its use without lessening the accuracy of the determination.
7.2 Reagent water must be interference free. All references to water in this method
refer to reagent water unless otherwise specified.
7.3 Other reagents may be used in place of reagent water on a case-specific basis.
8.0 SAMPLE COLLECTION, PRESERVATION, AND STORAGE
8.1 See the introductory material to Chapter Three "Inorganic Analytes."
8.2 Both plastic and glass containers are suitable for the collection of samples. All
sample containers must be prewashed with a metal-free detergent and triple rinsed with nitric
acid and reagent water, depending on the history of the container. For further information, see
Chapter Three.
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9.0 QUALITY CONTROL
9.1 Refer to Chapter One for guidance on quality assurance (QA) and QC
protocols. When inconsistencies exist between QC guidelines, method-specific QC criteria take
precedence over both technique-specific criteria and those criteria given in Chapter One, and
technique-specific QC criteria take precedence over the criteria in Chapter One. Any effort
involving the collection of analytical data should include development of a structured and
systematic planning document, such as a Quality Assurance Project Plan (QAPP) or a Sampling
and Analysis Plan (SAP), which translates project objectives and specifications into directions
for those that will implement the project and assess the results. Each laboratory should
maintain a formal quality assurance program. The laboratory should also maintain records to
document the quality of the data generated. All data sheets and quality control data should be
maintained for reference or inspection.
9.2 Method blanks - In order to demonstrate the purity of reagents and container
surfaces, a method blank should be tested for each leaching interval. Refer to Chapter One for
specific QC procedures.
9.3 The analysis of extracts should follow appropriate QC procedures, as specified
in the determinative methods for the COPCs. Refer to Chapter One for specific quality control
procedures.
9.5 Initial demonstration of proficiency (IDP)
Leachate methods are not amenable to typical initial demonstrations of proficiency as
reference materials with known values are usually not available. However, prior to using this
method an analyst should have documented proficiency in the skills required for successful
implementation of the method. For example, skill should be demonstrated in the use of an
analytical balance, the determination of pH using methods 9040 and 9045 and the
determination of conductance using method 9050.
10.0 CALIBRATION AND STANDARDIZATION
10.1 The balance should be calibrated and certified at a minimum annually or in
accordance with laboratory policy.
10.2 Prior to measurement of eluate pH, the pH meter should be calibrated using a
minimum of two standards that bracket the range of pH measurements. Refer to Methods 9040
and 9045 for additional guidance.
10.3 Prior to measurement of eluate conductivity, the meter should be calibrated
using at least one standard at a value greater than the range of conductivity measurements.
Refer to Method 9050 for additional guidance.
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11.0 PREPARATORY PROCEDURES
A flowchart of this method, including preparatory and leaching procedures, is shown in
Figure 3. Microsoft Excel data templates are available to aid in collection and archiving of
laboratory and analytical data.2
11.1 Determination of solids and moisture content
The moisture and solids content of the sample material are used to relate
leaching results to dry-material masses. When preparing compacted granular samples
for testing, the moisture content or solid content is used to determine the optimum
moisture content following the modified Proctor test. This method calculates moisture
content on the basis of the "wet" or "as tested" sample.
WARNING: The drying oven should be contained in a hood or otherwise properly
ventilated. Significant laboratory contamination or inhalation hazards may
result when drying heavily contaminated samples. Consult the laboratory
safety officer for proper handling procedures prior to drying samples that
may contain volatile, hazardous, flammable or explosive materials.
11.1.1 Place a 5-10-g sample of solid material into a clean, pre-weighed
dish or crucible. Dry the sample to a constant mass at 105 ± 2 °C. Periodically check
the sample mass after allowing the sample to cool to room temperature (20 ± 2 °C) in a
desiccator.
NOTE: The oven-dried sample is not used for the extraction and should be properly
disposed of once the dry mass is determined.
11.1.2 Calculate and report the solids content as follows:
SC =
M
dry
Mfest
Where: SC = solids content (g-dry/g)
Mdry = mass of oven-dried sample (g-dry)
Mtest = mass of "as-tested" sample (g)
11.1.3 Calculate and report the moisture content (wet basis) as follows:
Mi x — M i
MO - test dry
lvl^wet -
Mtest
2 The Excel data templates form the basis for uploading method data into the data management program, LeachXS
Lite™. Both the data templates and LeachXS Lite are available at http://vanderbilt.edu/leachinq.
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Where: MC(wet) = moisture content on a wet basis (gH2o/g)
Mdry = mass of oven-dried sample (g-dry)
Mtest = mass of "as-tested" sample (g)
11.2 Preparation of monolithic samples
11.2.1 If the material to be tested is granular, disregard this section and
proceed to Sec. 11.3.
11.2.2 A representative sample of monolithic material should be obtained
by molding material components in place (e.g., cementitious media) or by coring or
cutting a sample from a larger existing specimen.
11.2.3 The geometry of monolithic samples may be rectangular (e.g.,
bricks, tiles), cubes, wafers, cylinders. Samples may also have a variety of faces
exposed to eluent forming 1-, 2-, or 3-D mass-transfer cases. Example monolithic
sample leaching setups are shown in Figure 1.
11.2.4 A minimum sample size of 5 cm in the direction of mass transfer
must be employed and the L/A must be maintained at 9 ± 1 mL/cm2.
NOTE: Since, the sample holder and leaching vessel must correspond to the
specifications in Sec 6.1, it is often easier to modify the sample size and
geometry rather than the holder and vessel dimensions.
11.2.5 Proceed to Sec. 12.0.
11.3 Preparation of compacted granular samples
Compacted granular materials, for most cases, must be open-faced cylinders due to the
limitations of mechanical packing. However, the diameter and height of the sample holder may
be altered to work appropriately with the diameter and volume of the leaching vessel. In all
cases, a minimum sample size of 5 cm in the direction of mass transfer must be employed and
the L/A must be maintained at 9 ± 1 mUcrn2.
Granular samples are compacted into the sample holder using a variation on the
modified Proctor compaction (see Ref. 5) to include the use of 6-cm high test molds. Shorter or
taller molds (or packing depths) may be used as long as the compaction effort of 56,000 ft-lbf/ft3.
The number of packing layers should be maintained at the five layers specified in Ref. 5;
however the number of blows per layer in a 4-in diameter molds may be changed according to
the follow formula:
65.2x/?blow
layer
Where: h \s the height of the mold (ft).
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56,000 ft -lbf
ft3
blow
1.5ftx10lbf
/ — / \2
TZ-fO.S/ftl xftft
5 layer
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Thus, for the mold height of 4.584 in (0.382 ft) specified in the ASTM procedure, 25 blows per
each of 5 layers are required. When a 6-cm (0.196 ft) mold height is used (as suggested in this
method), 13 blows per each of 5 layers are required to obtain the same compaction effort.
The granular sample should be compacted at a moisture content corresponding to 90% of the
Modified Proctor optimum packing density in order to provide a uniform approach to obtaining a
sample density that approximate field conditions. Optimum moisture content refers to the
amount of moisture or fractional mass of water (gH2o/9 material) in the granular sample that is
present at the optimum packing density (g-dry material/cm3). Optimum packing density is
defined in Ref. 5. The optimum moisture content of the test material is determined from a
pretest measuring the packing density of granular materials compacted at different levels of
moisture content.
11.3.1 Pre-test to determine optimum moisture content
The pre-test is conducted as a series of five batch-wise packing trials with
consecutive increases in moisture content until the maximum packing density has been
surpassed. The optimum moisture content is determined as the maximum of a third-
order polynomial fit through the graph of dry-packing density as a function of moisture
content (wet basis).
11.3.1.1 Place 1500 g of "as received" material into a pail or
bowl and mix well by hand to homogenize. As an alternate to hand mixing, a
mechanical paddle mixer may be used.
NOTE: The pretest may be conducted from a bulk supply of solid material
(e.g., 10 kg total for five batches) as long as the starting mass for each
trial is recorded and incremental water additions are used.
1.3.1.2 Mix a known amount of tap water with the bulk material
in the pail or bowl until homogenized based on visual inspection. For the first
point in the pre-test, no water needs to be added.
NOTE: The amount of water added should be enough increase the moisture
content in approximately 3-5% increments. Smaller additions may be
needed in order to provide finer resolution of the packing density as a
function of moisture content curve.
11.3.1.3 Calculate the new moisture content for the trial as
follows:
MCwet + Wadded
Mtest+Wadded
Where: MC(Wet) = moisture content (wet basis) of the pre-test trial (gH2o/g)
Mtest = mass of "as-tested" material used in the trial (g)
MC(Wet) = moisture content (wet basis) of the "as-tested" material
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(9H2o/g)
Wadded = mass of water added to the "as-tested" material (gH o/g)
11.3.1.4 Compact approximately 1000 g of material into a pre-
tared 10-cm diameter mold into three consecutive layers of material. The
compacted mass should have a level flat surface as a top face.
11.3.1.5 Measure and record the height, diameter, and mass of
the resulting compacted material.
11.3.1.6 Calculate and record the packing density (dry basis) as
follows:
m x SC (2
d
Where: ppack = packing density (dry basis) (g-dry/cm3)
m = mass of the compacted sample (g)
SC = solids content of the "as -received" granular material (g-
dry/g)
d = measured diameter of the compacted sample (cm)
h = measured height of the compacted sample (cm)
11.3.1.7 Repeat Sees. 11.3.1.1-11.3.1.6 for four subsequent
trials until the value of the calculated packing density decreases.
11.3.1.8 Plot the packing density as a function of moisture
content. Figure 4 shows an example of a packing density curve.
11.3.1.9 Determine the optimum moisture content at the
maximum of the packing density curve. This value may be read directly from
the graph or determined by the maximum of a third-order polynomial fit through
the five pre-test data points (see the Microsoft® Excel Template).
11.3.2 Compacted granular test sample preparation
11.3.2.1 Using the optimum moisture content determined in
Sec. 11.3.1.9, calculate the amount of "as-received" material that is required to
pack the sample holder to within 3 mm of the rim of the holder.
_Popt XTTx(h-0.3)f d
"test ~ ^
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Where: Mtest = mass of "as tested" sample (g)
popt = optimal packing density (dry basis) (g-dry/cm3)
determined in Sec. 11.3.1.9.
SC = solids content of the "as received" granular material (g-dry/g)
d = measured diameter of the sample mold (cm)
h = measured height of the sample mold (cm)
11.3.2.2 Adjust the moisture content of the "as-received"
material to the optimum moisture content using reagent water and mix until
homogenized.
11.3.2.3 Pack the sample material into the sample holder using
the modified Proctor compaction as described in Ref. 5.
11.3.2.4 Place a mono-layer of borosilicate glass beads (Sec.
6.3.3) on the exposed sample surface to minimize scouring and mass loss
during testing.
11.3.2.5 Begin the leach test procedure promptly or cover the
sample with plastic wrap to minimize moisture loss to the atmosphere.
12.0 LEACHING PROCEDURE
This protocol is a semi-dynamic, tank-leaching procedure (see schematic in Figure 5)
where the sample is exposed to eluate for a series of leaching intervals interspersed with eluent
exchanges. The chemical composition of each eluate is determined and mass transfer from the
bulk solid is determined as a function of cumulative leaching time. The schedule of leaching
intervals for this method is shown in Table 1.
12.1 Pre-test measurements
12.1.1 For the surface area calculation, measure and record the
dimensions of the test specimen (i.e., diameter and height for a cylinder; length,
width and depth for a parallelepiped; or diameter of exposed surface for a
compacted granular sample).
12.1.2 Measure and record the mass of the specimen. This value should
be monitored for each eluent exchange.
12.1.3 If a holder is used, place the specimen in the monolith holder.
12.1.4 Measure and record the mass of the specimen and holder, if
applicable.
12.1.5 The recommended temperature for conducting this method is room
temperature (20 ± 2 °C). When conducted at temperatures readings or variations other
than those recommended, record the ambient temperature at each eluent renewal.
12.2 Eluent exchange
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12.2.1 Fill a clean leaching vessel with the required volume of reagent
water based on an L/A of 9 ± 1 ml_/cm2. Record the amount of eluent used.
12.2.2 Carefully place the specimen or the specimen and holder in the
leaching vessel (Figure 6a) so that the sample is centered in the eluent (see Figure 6b).
Submersion should be gentle enough so that the physical integrity of the monolith is
maintained and scouring of the solid is minimized.
12.2.3 Cover the leaching vessel with the air-tight lid and place in a safe
location until the end of the leaching interval. Table 1 shows the schedule of leaching
intervals and cumulative release times for this method.
NOTE: Eluates of alkaline materials may be susceptible to neutralization through
reaction with carbon dioxide. Precautions (e.g., ensuring air-tight vessels or
purging headspace) should be taken to minimize the effect of carbonation on
eluates that may sit stationary for more than one week.
12.2.4 Prior to the end of the leaching interval, repeat Sec. 12.2.1 in order
to prepare a vessel for the next leaching interval.
12.2.5 At the end of the leaching interval (see Table 1), carefully remove
the specimen or the specimen and holder from the vessel (Figure 6c). Drain the
liquid from the surface of the specimen into the eluate for approximately 20 sec.
12.2.6 Measure and record the mass of the specimen or the mass of the
specimen and holder (Figure 6d).
NOTE: The change in sample mass between intervals is an indication of the potential
absorption of eluent by the matrix (mass gain) or erosion of the matrix (mass
loss). In the case where a holder is used, moisture may condense on the
holder during the leaching intervals and sample absorption may not be evident.
NOTE: Mass gain may also be indicative of carbonate precipitation if the vessel is not
tightly sealed and carbon dioxide is absorbed from the atmosphere.
12.2.7 Place the specimen or the specimen and holder into the clean
leaching vessel filled with new eluent as prepared in Sec. 12.2.4.
12.2.8 Cover the new leaching vessel with the air-tight lid and place in a
safe location until the end of the leaching interval.
12.3 Eluate processing
12.3.1 Measure and record the pH, specific conductivity, and oxidation-
reduction potential (ORP) of the eluate of the decanted eluate from the previous leaching
interval (see Methods 9040, 9045, and 9050).
NOTE: Measurement of pH, conductivity and ORP should be taken within 15 minutes of
eluent exchange (Sec. 12.2) to avoid neutralization of the solution due to
exposure to carbon dioxide, especially when alkaline materials are tested.
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NOTE: The measurement of ORP is optional, but strongly recommended, especially
when testing materials where oxidation is likely to change the chemistry of
COPCs.
12.3.2 Filter the remaining eluate through a 0.45-um membrane (Sec. 6.5).
12.3.3 Immediately, preserve and store the volume(s) of eluate required for
chemical analysis. Preserve all analytical samples in a manner that is consistent with
the determinative chemical analyses to be performed.
12.3.4 Collect all subsequent eluate by repeating the eluent exchange and
eluate processing procedures in Sees. 12.2 and 12.3.
13.0 DATA ANALYSIS AND CALCULATIONS
13.1 Data reporting
Figure 7 shows an example of a data sheet which may be used to report the
concentrations results of this method. This example is included in the Excel template. At a
minimum, the basic test report should include the following:
a) Name of the laboratory
b) Laboratory contact information
c) Date and time at the start of the test
d) Name or code of the solid material
e) Material Description (including monolithic or compacted granular)
f) Moisture content of material used (gH2o/g)
g) Dimensions (cm) and geometry of sample used
h) Mass of solid material used (g)
i) Mass of sample and holder at start of test (g)
j) Eluate type (e.g., reagent water)
k) Eluate specific information (see below)
The minimum set of data that should be reported for each eluate includes:
a) Eluate sample ID
b) Target eluent exchange date and time
c) Actual eluent exchange date and time
d) Volume of eluent used (mL)
e) Mass of sample and holder (g)
f) Measured eluate pH
g) Measured eluate conductivity (mS/cm)
h) Measured ORP (mV) (optional)
i) Concentration of all COPCs
j) Analytical QC qualifiers as appropriate
13.2 Data presentation
13.2.1 Interval concentrations
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13.2.1.1 At the conclusion of the schedule of leaching intervals
(see Table 1), the concentration of COPCs in each eluate may be plotted as a
function of cumulative leaching time. An example of this is shown in Figure 8
for mass transport from a monolithic field sample of fixated scrubber sludge and
lime.
13.2.1.2 If data is available from Method 1313, interval
concentrations and Method 1313 data may be plotted on the same graph as a
function of eluate pH. This QC step is conducted in order to determine if the
concentration of COPCs approached equilibrium in any leaching interval
(i.e., the driving force for mass transport from the matrix may not be constant
which is a common assumption of dynamic-tank leach testing). Figure 9 shows
this type of graph for the release from a field sample of fixated scrubber sludge
and lime.
13.2.2 Interval mass release
At the conclusion of the schedule of leaching intervals (see Table 1), the
interval mass released can be calculated for each leaching interval as follows:
Where: Mt. = Mass released during the current leaching interval i (mg/m2)
d = constituent concentration in the eluate for interval i (mg/L)
Vj = eluate volume in interval i (L)
A = specimen external geometric surface area exposed to
the eluent (m2)
13.2.3 Mean interval flux
The flux of a COPC in an interval may be plotted as a function of the
generalized mean of the square root of cumulative leaching time (Ji). An example of a
flux graph is show in Figure 10 for the release from a field sample of fixated scrubber
sludge with lime. This graph may be used to interpret the mechanism of release (see
Ref. 7. for further details).
13.2.3.1 The flux across the exposed surface of the sample can
be calculated by dividing the interval mass release by the interval duration as
follows:
F,=^!L
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Where F, = flux for interval, i (mg/m2-s)
MJ= mass released during the current leaching interval i (mg/m2)
t = cumulative time at the end of the current leaching interval i (s)
ti_i = cumulative time at the end of the previous leaching
interval i-1 (s)
13.2.3.2 The time used to plot each interval mass is the
generalized mean of the square root of the cumulative leaching time using the
cumulative time at the end of the ith interval, tj, and the cumulative time at the
end of the previous interval, tM.
Where t;: = generalized mean leaching time for the current interval, i (s)
tj = cumulative time at the end of the current leaching interval, i (s)
tM = cumulative time at the end of the previous leaching
interval, i-1 (s)
NOTE: If the concentrations of a COPC in the eluates approach that shown in
Method 1313 for liquid-solid equilibrium, the flux curve will show the
pattern in Figure 10 with intervals of the same duration having the same
flux value. When the eluate concentration approaches saturation, the
driving force for mass transfer approaches zero, interval flux is limited,
and intervals with like durations will display similar flux limitations.
13.2.4 Cumulative release
13.2.4.1 The interval release calculated in 13.2.2 can be
summed to provide the cumulative mass release as a function of leaching time.
Figure 11 shows the cumulative release curves for a field sample of fixated
scrubber sludge with lime.
13.2.4.2 Interpretation of the cumulative release of constituents
is illustrated using the analytical solution for simple radial diffusion from a
cylinder into an infinite bath presented by Crank (see Ref. 6).
M.-.PC.
Dobs 1
—
Where: Mt = cumulative mass released during leaching interval, i (mg/m2)
p = density of the "as-tested" sample (kg/m3)
C0 = concentration of available COPC in the solid matrix (mg/kg)
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Dobs = observed diffusivity (m2/s)
t = leaching time (s)
When transformed to a log-log scale, the analytical solution
presented by Crank becomes linear with the square root of time.
log[Mt ] = log
lt
2
Thus, under the assumptions of the analytical solution presented by
Crank, the mass release should be proportional to the square root of time. A
line showing the square root of time is plotted in Figure 11 along with the data.
Since flux is the derivative of release, a similar treatment of flux as a function of
leaching time using the simple diffusion model would be proportional to the
negative square root of time as shown in Figure 10.
Other models than the simple diffusion model presented by Crank
may also be used to interpret mass release. For example, the Shrinking
Unreacted Core Model (see Ref. 8) and the Coupled Dissolution-Diffusion
Model (see Ref. 9) incorporate chemical release parameters (e.g., as derived
from Method 1313 data) into the model to better estimate release mechanisms
and predictions (see Ref. 7 for further details).
13.2.5 Observed diffusivity
An observed diffusivity for each COPC can be determined using the logarithm
of the cumulative release plotted versus the logarithm of time. In the case of a diffusion-
controlled mechanism, this plot is expected to be a straight line with a slope of 0.5. An
observed diffusivity can then be determined for each leaching interval where the slope is
0.5 ±0.15 (see Refs. 10 and 11) by the following:
M,,
D°bs = n
Where: D°bs = observed diffusivity of a COPC for leaching
interval, i (m2/s)
M, = mass released during leaching interval, i (mg/m2)
tj = cumulative contact time after leaching interval, i (s)
ti_i = cumulative contact time after leaching interval, i -1 (s)
C0 = initial leachable content (i.e., available release
potential) (mg/kg)
p = sample density (kg-dry/m3)
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The mean observed diffusivity for each COPC is then determined by taking the
average of the interval observed diffusivities. It should be reported with the computed
uncertainty (i.e., standard deviation).
NOTE: Since the analysis presented above assumes a diffusion process, only those
interval mass transfer coefficients corresponding to leaching intervals with
slopes of 0.50 ±0.15 are included in the overall average mass-transfer
coefficient.
13.3 Data representation by constituent
A concise representation of all relevant data for a single constituent may be presented
as shown in Figure 12 for arsenic from a field core of FSSL material. The data shows eluate pH
generation as a function of leaching time (Figure 12a), comparison between eluate
concentrations and Method 1313 data as a function of eluate pH (Figure 12b), constituent flux
as a function of generalized mean cumulative leaching time (Figure 12c), and constituent
release as a function of cumulative leaching time (Figure 12d).
13.3 Interpolation/extrapolation to target time values
The collected time-dependence data may be interpolation or extrapolated to the nearest
target cumulative time (It) value for purposes of comparing different data sets (e.g., test
replicates of the same or different materials). The most transparent and straight-forward
method is linear interpolation/extrapolation of data after Iog10-transformation.
13.3.1 Log10-transform
Collected concentration values are transformed by taking the Iog10 of the
measured concentration at each test position, i:
C, =
Where: q = the concentration measured at test position, i, (mg/L)
d = Iog10-transformed concentration at test position, i, (Iog10[mg/l_])
13.3.2 Linear interpolation/extrapolation
Given a set of coordinate data {(Itj ,Cj): i = 1,...n} sorted by into increasing
order by It value (e.g., It1 < Et2 < ••• < Itn), an interpolated/extrapolated Iog10-
transformed concentration at a known It target is calculated as:
CT= aT + bj-Stj
Where: EtT = a target cumulative time value
CT = the concentration at target It value, EtT (Iog10[s])
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Depending on the values of observed It values relative to target It values, the
calculations of the coefficients aT and bT in the equation may differ according to the
following algorithm:
• If ItT < Iti, then bT = (C2 - CO / (It2 - ItO and aT = C2 - brlt2 (extrapolation from
the two points with closest It values);
• If EtT z Etn, then bT =(Cn - Cn-i) / (Itn - Itn-i) and aT = Cn - brltn (extrapolation
from the two points with closest It values);
• If Etj-i < StT < Etj, then bT = (Cj - Chi) / (Etj - Etj-Oand aT = y, - brEtj
(interpolation from the two closest points surrounding EtT).
NOTE: Interpolation or extrapolation of data should only be conducted within a distance
of ±20% of the target It value. Since the allowable L/S tolerance about a target
L/S values is variable (see Table 1), interpolation/extrapolation should not
create data at a target It value where collected data is missing.
14.0 METHOD PERFORMANCE
14.1 Performance data and related information are provided in SW-846 methods
only as examples and guidance. The data do not represent required performance criteria for
users of the methods. Instead, performance criteria should be developed on a project-specific
basis, and the laboratory should establish in-house QC performance criteria for the application
of this method. These performance data are not intended to be and must not be used as
absolute QC acceptance criteria for purposes of laboratory accreditation.
14.2 Interlaboratory validation of this method was conducted using a solidified waste
analog (material code SWA) and a contaminated smelter site soil (material code CFS).
Repeatability and reproducibility was determined for mean interval flux excluding the first wash-
off interval (see Table 2) and for cumulative mass released after 63-days of leaching (see Table
3). More details on the interlaboratory validation may be found in Ref. 14.
14.3 Refs. 1 and 7 may provide additional guidance and insight on the use,
performance and application of this method.
15.0 POLLUTION PREVENTION
15.1 Pollution prevention encompasses any technique that reduces or eliminates the
quantity and/or toxicity of waste at the point of generation. Numerous opportunities for pollution
prevention exist in laboratory operations. The EPA has established a preferred hierarchy of
environmental management techniques that places pollution prevention as the management
option of first choice. Whenever feasible, laboratory personnel should use pollution prevention
techniques to address their waste generation. When wastes cannot be feasibly reduced at the
source, the Agency recommends recycling as the next best option.
15.2 For information about pollution prevention that may be applicable to
laboratories and research institutions consult Less is Better: Laboratory Chemical Management
for Waste Reduction available from the American Chemical Society's Department of
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Government Relations and Science Policy, 1155 16th St., N.W. Washington, D.C. 20036,
http://www.acs.org.
16.0 WASTE MANAGEMENT
The Environmental Protection Agency requires that laboratory waste management
practices be conducted consistent with all applicable rules and regulations. The Agency urges
laboratories to protect the air, water, and land by minimizing and controlling all releases from
hoods and bench operations, complying with the letter and spirit of any sewer discharge permits
and regulations, and by complying with all solid and hazardous waste regulations, particularly
the hazardous waste identification rules and land disposal restrictions. For further information
on waste management, consult The Waste Management Manual for Laboratory Personnel
available from the American Chemical Society at the address listed in Sec. 15.2.
REFERENCES
1. D.S. Kosson, H.A. van der Sloot, F. Sanchez and A.C. Garrabrants (2002) "An
Integrated Framework for Evaluating Leaching in Waste Management and Utilization of
Secondary Materials," Environmental Engineering Science, 19(3) 159-204.
2. NEN 7345 (1995) "Leaching Characteristics of Solid Earth and Stony Materials -
Leaching Tests - Determination of the Leaching of Inorganic Constituents from Molded
and Monolithic Materials with the Diffusion Test," Dutch Standardization Institute, Delft,
The Netherlands.
3. ANSI/ANS 16.1 (1986) "American National Standard Measurement of the Leachability of
Solidified Low-Level Radioactive Wastes by a Short-term Test Procedure," American
Nuclear Society, La Grange Park, IL.
4. ASTM D1308-95 (2001) "Standard Method for Accelerated Leach Test for Diffusive
Releases from Solidified Waste and a Computer Program to Model Diffusive, Fractional
Leaching from Cylindrical Waste Forms," ASTM International, West Conshohocken, PA.
5. ASTM D1557-07 "Standard Method for Laboratory Compaction Characteristics of Soil
Using Modified Effort (56,000 ft-lbf/ft3 (2,700 kN-m/m3))," ASTM International, West
Conshohocken, PA.
6. D.E. Hockley and H.A. van der Sloot (1991) "Long-term Processes in a Stabilized Coal-
Waste Block Exposed to Seawater," Environmental Science and Technology, 25(8),
1408-1414.
7. A.C. Garrabrants, D.S. Kosson, H.A. van der Sloot, F. Sanchez and O. Hjelmar (2010)
"Background Information for the Leaching Environmental Assessment Framework
(LEAF) Test Methods," EPA/600/R-10-170, U.S. Environmental Protection Agency,
Washington, DC, December 2010.
8. Crank (1986) Mathematics of Diffusion, Oxford University Press, London.
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Intel-laboratory Validation of LEAF Method 1314 and Method 1315
9. Hinsenveld, and P.L. Bishop (1996) "Use of the shrinking core/exposure model to
describe the leachability from cement stabilized wastes," in Stabilization and
Solidification of Hazardous, Radioactive, and Mixed Wastes, 3rd Volume, ASTM STP
1240, T.M. Gilliam and C.C. Wiles (eds), American Society for Testing and Materials,
Philadelphia, PA.
10. Sanchez (1996) "Etude de la lixiviation de milieux poreux contenant des especes
solubles: Application au cas des dechets solidifies par Hants hydrauliques," doctoral
thesis, Institut National des Sciences Appliquees de Lyon, Lyon, France.
11. IAWG (1997) Municipal Solid Waste Incinerator Residues, International Ash Working
Group, Elsevier Science Publishers, Amsterdam, the Netherlands.
12. J. de Groot, and H. A. van der Sloot (1992) "Determination of Leaching Characteristics
of Waste Materials Leading to Environmental Product Certification," in Solidification and
Stabilization of Hazardous, Radioactive, and Mixed Wastes, 2nd Volume, ASTM STP
1123, T.M. Gilliam and C.C. Wiles (eds), American Society for Testing and Materials,
Philadelphia, PA.
13. A.C. Garrabrants and D.S. Kosson (2005) "Leaching Processes and Evaluation Tests for
Inorganic Constituents Release from Cement-Based Matrices," in
Solidification/Stabilization of Hazardous, Radioactive and Mixed Wastes, R Spence and
C. Shi (eds.), CRC Press.
14. A.C. Garrabrants, D.S. Kosson, R. DeLapp, P. Kariher, P.F.A.B. Seignette, H.A. van der
Sloot, L. Stefanski, and M. Baldwin (2012) "Interlaboratory Validation of the Leaching
Environmental Assessment (LEAF) Method 1314 and Method 1315," Draft, U.S.
Environmental Protection Agency, Washington DC, April 2012.
15. CEN/TS15863 (2009) Characterization of waste - Leaching Behaviour Tests - Dynamic
Monolithic Leaching Test with Periodic Leachant Renewal, Comite Europeen de
Normalisation, Brussels, Belgium.
18.0 TABLES, DIAGRAMS, FLOWCHARTS, AND VALIDATION DATA
The following pages contain the tables and figures referenced by this method
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TABLE 1
SCHEDULE OF ELUATE RENEWALS
Interval Label
T01
T02
T03
T04
T05
T06
T07
T08
T09
Interval
Duration
(h)
2.0 ± 0.25
23.0 ± 0.5
23.0 ± 0.5
-
-
-
-
-
-
Interval
Duration
(d)
—
—
-
5.0 ± 0.1
7.0 ± 0.1
14.0 ± 0.1
14.0 ± 0.1
7.0 ± 0.1
14.0 ± 0.1
Cumulative
Leaching Time
(d)
0.08
1.0
2.0
7.0
14.0
28.0
42.0
49.0
63.0
NOTE: This schedule may be extended for additional 14-day contact intervals
to provide more information regarding longer-term release.
TABLE 2
METHOD PRECISON FOR MEAN INTERVAL FLUX (2na - 9tn Intervals)
Repeatability
Reproducibility
Analyte
Aluminum
Antimony
Arsenic
Barium
Boron
Cadmium
Calcium
Chromium
Lead
Potassium
Selenium
Vanadium
Symbol
Al
Sb
As
Ba
B
Cd
Ca
Cr
Pb
K
Se
V
Material Mean
Overall Mean
SWA
%RSDr
7.3
9.2
19.9
13.2
10.8
-
8.1
10.2
-
12.4
10.9
8.5
11%
CFS
%RSDr
13.3
14.8
-
7.5
7.2
7.6
6.6
-
4.3
10.8
13.3
11.3
10%
11%
SWA
%RSDR
25.3
21.8
31.1
44.8
27.3
-
28.7
23.8
-
28.8
30.8
22.3
29%
CFS
%RSDR
25.3
23.8
-
18.3
27.1
23.2
26.0
-
19.8
40.1
32.4
30.6
27%
28%
NOTE: First interval is removed from mean interval flux because of variances associated with
wash-off of surface contaminants that do not pertain to the method precision.
Data taken from Reference 14.
B-23
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April 2012
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Intel-laboratory Validation of LEAF Method 1314 and Method 1315
TABLE 3
METHOD PRECISON FOR CUMULATIVE RELEASE AFTER 63-DAYS
Repeatability
Reproducibility
Analyte
Aluminum
Antimony
Arsenic
Barium
Boron
Cadmium
Calcium
Chromium
Lead
Potassium
Selenium
Vanadium
Symbol
Al
Sb
As
Ba
B
Cd
Ca
Cr
Pb
K
Se
V
Material Mean
Overall Mean
SWA
%RSDr
5.4
6.9
15.9
7.5
8.4
-
4.6
7.7
-
10.8
8.7
5.7
8%
CFS
%RSDr
5.3
5.9
-
3.9
3.7
4.8
3.2
-
1.6
6.3
3.6
4.2
4%
6%
SWA
%RSDR
23.6
19.7
31.0
35.6
22.6
-
23.9
17.7
-
24.8
26.7
21.1
25%
CFS
%RSDR
22.9
14.4
-
16.5
25.7
18.4
24.6
-
12.0
44.4
20.5
22.8
22%
23%
Data taken from Reference 14.
B-24
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April 2012
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Intel-laboratory Validation of LEAF Method 1314 and Method 1315
FIGURE 1
EXAMPLES OF MONOLITHIC SAMPLE HOLDERS
a) 3-D Configuration
Sample Holder
b) 1-D Configuration
Sample. Holder and Stand
3-D Leaching Setup
Empty Sample Holder
Full Sample Holder
1-D Leaching Setup
B-25
Revision 1
April 2012
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Intel-laboratory Validation of LEAF Method 1314 and Method 1315
FIGURE 2
EXAMPLE COMPACTED GRANULAR SAMPLE HOLDER AND SETUP
Empty Sample Holder
Compacted Sample
1-D Leaching Setup
B-26
Revision 1
April 2012
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Intel-laboratory Validation of LEAF Method 1314 and Method 1315
FIGURES
METHOD 1315 FLOWCHART
< Material of
Interest ^^
Solids/Moisture Content
(Section 11.1)
Is the
material
monolithic?
no
Compaction Pre-Test
(Section 11.3.1)
yes
Sample Preparation
(Section 11.2)
Sample Preparation
(Section 11.3.2)
Leaching Procedure
(Section 12)
Pre-Test Measurements (Sec 12.1)
Eluant Exchange (Sec 12,2)
Eluate Processing (Sec 12.3}
V
Extract Analysis
v
Documentation and
Graphing
B-27
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April 2012
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Intel-laboratory Validation of LEAF Method 1314 and Method 1315
FIGURE 4
EXAMPLE CURVE OF PACKING DENSITY AS A FUNCTION OF MOISTURE CONTENT
y = 55.975X3 - 65.036x2 + 1.8352
r2 = 0.983
o
en
oj
Q
O)
O
re
Q.
2.65
2.60
•2 2.55 -
2.50 -
2.30
maximum density
2.576 g-dry/cm3
0.00
optimum moisture
0.120gH20/g
0.05
0.10
0.15
0.20
Moisture Content [gH2o/g]
0.25
B-28
Revision 1
April 2012
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Intel-laboratory Validation of LEAF Method 1314 and Method 1315
FIGURES
SCHEMATIC OF SEMI-DYNAMIC MASS TRANSFER TEST PROCESS
1 Sample
Monolith
(allfacesexposed)
Compacted Granular
(1 circular face exposed)
A!
LI
n Leaching Intervals
OJ J/J
U) g
x
0)
JJ
N
analytical
samples
Figure obtained and modified from Ref. 11.
B-29
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April 2012
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Intel-laboratory Validation of LEAF Method 1314 and Method 1315
FIGURE 6
EXAMPLE LEACHING PROCEDURE STEPS
Start of Leaching Interval
Sample Centered in Eluant (top view)
Removing Sample for Exchange
Mass of Sample and Holder
B-30
Revision 1
April 2012
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Intel-laboratory Validation of LEAF Method 1314 and Method 1315
FIGURE?
EXAMPLE DATA REPORTING SHEET
ABC Laboratories
123 Main Street
Anytown, USA
Contact: John Smith
(555) 111-1111
EPA METHOD 1315
Report of Analysis
Client Contact: Susan Jones
(555) 222-2222
Test
Position
T01
Test
Position
T02
Material Code: XYZ
Material Type: Coal Combustion Fly Ash
Date Received: 10/1/20xx
Test Start Date: 11/1/20xx
Report Date: 12/1/20xx
Test Type: Compacted Granular
Eluent: ASTM Type II Water
Replicate Value Units
A
Eluate Sample ID XYZ-1315-T01-A
Exchange Date 1 1 /1 /20xx
Target Exchange Time 12:00 PM
Actual Exchange Time 12:15 PM
Mass of Sample & Holder 1026 g
Eluate Mass 730.4 g
Eluate pH 8.82
Eluate Conductivity 5.4 mS/c
Eluate ORP NA mv
Chemical Analysis Value Units
Al 4.72 mg/L
As 0.12 mg/L
Cl 5.42 mg/L
Replicate Value Units
A
Eluate Sample ID XYZ-1315-T02-A
Exchange Date 1 1 /1 /20xx
Target Exchange Time 12:00 PM
Actual Exchange Time 12:18 PM
Mass of Sample & Holder 1027 g
Eluate Mass 725.0 g
Eluate pH 9.15
Eluate Conductivity 2.8 mS/c
Eluate ORP NA mv
Chemical Analysis Value Units
Al 2.99 mg/L
As 0.21 mg/L
Cl 4.20 mg/L
Particle Size: 88% passing 2-mm sieve
Mass used in Column: 860 g
Moisture Content: 0.002 gH2o/g
Sample Geometry: Cylinder
Sample Diameter 10.0cm
Sample Depth: 60.3 cm
Mass of Sample & Holder 1020g
Lab Temperature: 21 ± 2 °C
Method Note
EPA 9040
EPA 9050
QC Dilution
Flag Method Date Factor
EPA 6020 11/7/20xx 1000
EPA 6020 11/7/20xx 10
EPA 9056 11/9/20xx 1
Method Note
EPA 9040
EPA 9050
QC Dilution
Flag Method Date Factor
EPA 6020 11/7/20xx 1000
EPA 6020 11/7/20xx 10
U EPA 9056 11/7/20xx 1
QC Flag Key: U Value below lower limit of quantitation as reported (< "LLOQ")
B-31
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Intel-laboratory Validation of LEAF Method 1314 and Method 1315
FIGURES
EXAMPLE INTERVAL CONCENTRATION GRAPHS
O)
^
o
'E
a)
uuu
100 7
1
10 1
I U
*
o 1 -
i m
p*2
!
2
AFSSL-A
OFSSL-B
Qy 0
20 40 60
Leaching Time [days]
80
c)
20 40 60
Leaching Time [days]
80
Cadmium [ug
b)
IUUU
100 -
"
1 10 i
Selenium
D
2 °
AFSSL-A
OFSSL-B
^ofl 2 Ł^ 2
j
•
U
"3
~Sn
a
Vanadium
uuu
100
1
<
0.1 -
i n-i
k
' A^ ^
0 O
AFSSL-A
OFSSL-B
O"
A OA
a
20 40 60
Leaching Time [days]
80
uuu
100 -
i
•in -
IU
0.1 -
i n-i
:
^a
;
Q
AFSSL-A
OFSSL-B
Q O
d)
0 20 40 60
Leaching Time [days]
80
NOTE: Orange lines represent cumulative release if all eluate extracts were at the quantitation limit
(dashed) and detection limit (solid). Chemical analyses below the detection limit are shown at
1/4 the detection limit value.
B-32
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April 2012
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Intel-laboratory Validation of LEAF Method 1314 and Method 1315
FIGURE 9
EXAMPLE OF SATURATION CHECK BETWEEN INTERVAL CONCENTRATIONS
AND METHOD 1313 DATA
IUUUUU •
10000 -
„ 1000 -
1 100 -
o
1 10 H
i
< 1 -
n 1 -
n n-i .
"
;
U
n
uivietnoa m j •
AFSSL-A
OFSSL-B
TOD
^
OF
l&
U. 1
On ^
.ul
C
a)
innnnn
IUUUUU
10000 -
5- 1000 -
13 100 -
1 10 -
0
•9
W 1 -1
0-j .
.1
) 2 4 6 8 10 12 1
Eluate pM
; n Mett
AFSS
: OFSS
: CP B
1 Qp&h
•4i ^
iod1313 '
L-A
L-B
•a,
4- —
^
0 2 4 6 8 10 12 1*
c) Eluate pH
O)
a
E
3
-5
3
IUUU •
100 -
10
Of
. 1
n n-i .
Qj
n
[
3
L~j [
\
i i i
uivietnoa i JTJ
AFSSL-A
OFSSL-B
na
^
?
Jg
b)
4 6 8
Eluate pH
10 12 14
100000 -
10000 -
5- 1000 -
— 100 -
T3 1U
re
c
n 1 -
n ni
D
n
•
0
~^V
O Method 1313 "
AFSSL-A
OFSSL-B
3
n
^
i
11 i 1 J 1 1
d)
4 6 8
Eluate pH
10 12 14
NOTE: Orange lines represent cumulative release if all eluate extracts were at the quantitation limit
(dashed) and detection limit (solid). Chemical analyses below the detection limit are shown at
1/4 the detection limit value.
B-33
Revision 1
April 2012
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Intel-laboratory Validation of LEAF Method 1314 and Method 1315
FIGURE 10
EXAMPLE INTERVAL FLUX GRAPHS
i.c-uo -
1.E-04 -
jE 1.E-05 -
01
E
7 1.E-06 -
o 1.E-07 -
0)
2 1 P OR
-.
O
^t
*^.
3 I
^
orvo
a)
0.01 0.1 1 10 100
Mean Interval [days]
1.
1.E-09
0.01 0.1 1 10 100
c) Mean Interval [days]
b)
0.01 0.1 1 10 100
Mean Interval [days]
1.E-03
1.E-04 -
1.E-05 -
* 1.E-06 -
_
LL
E
rc
to
d)
1.E-07
IE-OS -
1.E-09
slope = -1/2
AFSSL-A
OFSSL-B
~~r
0.01 0.1 1 10 100
Mean Interval [days]
NOTE: Orange data represent cumulative release if all eluate extracts were at the quantitation limit
(dashes) and detection limit (solid line).
B-34
Revision 1
April 2012
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
FIGURE 11
INTERVAL FLUX AT ELUATE SATURATION
1,000
M
E
"5>
.2
100 -:
co
X
X
ro
10 -:
Equalfluxfor
>, 23-hr intervals
Equalfluxfor
^-day intervals
Equalfluxfor 14-day intervals
0.01
0.1
10
100
Mean Flux Time [days]
NOTE: This figure assumes that the concentration in the eluate approaches saturation during the
leaching interval (i.e., the driving force for diffusion approaches zero). When the leaching
solution is saturated, the resulting mass release and interval flux is constant for intervals of
the same duration.
B-35
Revision 1
April 2012
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
FIGURE 12
EXAMPLE CUMULATIVE RELEASE GRAPHS
E
ra
E
Oi
w
a)
E
"Si
0>
tn
CO
o>
-inn -
IUU
10 J
1.
.1
.U1
i nn-i
\
i
•
A FSSL-A
0 FSSL-B
slope =j l/2_
•
:
i i i ii 1 1 a
._ .{.
•
— i — i
,6 ^
-L__J
«#>
j.
Z^
10
0.01 0.1 1 10 100
I Leaching Time [days]
2 0.01 -i
0.001
c)
0.01 0.1 1 10 100
I Leaching Time [days]
sr
O
ffi
9
1 -:
« 0.1 i
oe
T3
CO
O
b)
E
"5)
E,
s
re
_o;
QJ
cc
I
re
re
0,01 -:
0.001
t-
0.01
slope = 1/2
"t-
0.1 1 10 100
I Leaching Time [days]
1000
w
d)
0.01
0.001
0.01 0.1 1 10 100
s Leaching Time [days]
NOTE: Orange data represent cumulative release if all eluate extracts were at the quantitation limit
(dashes) and detection limit (solid line).
B-36
Revision 1
April 2012
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
FIGURE 13
DATA REPRESENTATION BY CONSTITUENT (QUAD FORMAT)
re
UJ
a)
10 -
9 i
a •
V -
2 o
22 A
f
I
n
*
AFSSL-A
OFSSL-B
1 1 111 1 ; : :
IUUUUU
10000 -
„ 1000 -
_l
1 100 -
0
= 10 -
< 1 -
0.1 -
n nt
i
Q]
!
Q
D
[
%
.
_
V
uivietnoa i JT j
AFSSL-A
OFSSL-B
•&
a*
ftb
20 40 60 80
Z Leaching Time [days]
b)
4 6 8 10 12 14
Eluate pH
1 r m
1.E-04 -
JE 1.E-05 -
OI
E
l~~l 'i c nc
x l.b-Ub
o 1.E-07 -
5 1.E-08 -
-i c no -
.
:
6^~
-
^
^x
AFSSL-A
OFSSL-B
Si
Q slope
U|
-
\-
- 1/2
i~-^
N^
— r-
100 -
"E
05 10 -
« 1 •
1
tt 0. 1 -
o
'E
? n n-i -
Cfl U.U I :
k
w 0.001 -
A FSSL-A
OFSSL-B
|
J3
•
'•
^
/*• O"'
C
=-—
, — -
J
- ~ .
^
z^
c)
0.01 0.1 1 10 100
Mean Interval [days]
d)
0.01 0.1 1 10 100
2 Leaching Time [days]
NOTE: Orange data represent cumulative release if all eluate extracts were at the quantitation limit
(dashes) and detection limit (solid line).
B-37
Revision 1
April 2012
-------
Interlaboratorv Validation of LEAF Method 1314 and Method 1315
v°/EPA
QAPP for the EPA Intel-laboratory
Validation Study of Proposed
SW846 Leaching Methods
Quality Assurance Project Plan
Category III / Technology Development
Draft
Contract No. EP-C-09-027
Work Assignment No. 2-7
November 2011
C-l
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
10/25/2011
Peter Kari her
ARCAD!SU.S.,lnc
Work Assignment Leader
Date
QAPP for the EPA Interlaboratory
Validation Study of Proposed SW846
Leaching Methods
Quality Assurance Project Plan
Category III /Technology Development
Final
10/25/2011
Libby
ARCADIS UX Inc.
Quality Assurance Officer
Date
Susan Thorneloe
U.S. Environmental Protection Agency
Work Assignment Manac
11/22/11
Date
RicharcTShores
U.S. Environmental Protection Agency
Chief, Emissions Characterization & PpeventionJBranch
Date
Robert Bright
U.S. Environmental Protection AgetfCy
Quality Assurance Representative
Date
Prepared for.
Susan Thorneloe
U.S. Environmental Protection Agency
National Risk Management Research Laboratory
Air Pollution Prevention and Control Division
Atmospheric Protection Branch
Research Triangle Partt, NC 27711
Prepared by:
ARCADIS U.S., Inc.
4915 Prospectus Drive
Suite F
Durham
North Carolina 27713
Tel 919 544 4535
Fax 919 544 5690
Our Ref.:
RN990272.0007
Dale:
November 2011
C-2
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
Project No.: RN990272.0007
Revision: 0
Date: November 2011
Page: i
Appendices ii
List of Figures iii
List of Acronyms and Abbreviations iii
Distribution List vi
1. Project Objectives and Organization 1
1.1 Purpose 1
1.2 Project Objectives 2
2. Project Organization 4
3. Experimental Approach 9
3.1 Task I: Preparing Homogenized CCR 11
3.2 Task II: Leaching of the CCR by Reference Laboratory and the Intercomparison Laboratories 14
3.3 Task III: Determination of the Reproducibility of Each Method 16
3.4 Task IV: Testing of Select Materials for Leaching by SW-846 Methods 1311 (TCLP) and 1312
(SPLP) 16
3.5 Task V: Testing of Fly Ashes and Cement Kiln Dust for Radionuclide Testing by Germanium
Detector 17
4. Sampling Procedures 18
4.1 Sample Custody Procedures 18
4.2 CCR, and Leaching Reference Material Samples 19
4.2.1 Physical and Chemical Characterization Samples 19
4.2.2 Leaching Study Samples 20
4.3 Leachate Collection 20
5. Testing and Measurement Protocols to be Used for Reference Material Characterization
and Eluate Characterization 23
5.1 Physical Characterization 23
5.1.1 pH and Conductivity 23
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
Project No.: RN990272.0007
Revision: 0
Date: November 2011
Page: ii
5.1.2 Moisture Content and Loss on Ignition (LOI) 23
5.2 Chemical Characterization 24
5.2.1 Dissolved Organic Carbon / Dissolved Inorganic Carbon (DOC/DIC) and Elemental
Carbon / Organic Carbon (EC/OC) 24
5.2.2 Mercury by Thermal Decomposition and Cold Vapor Atomic Adsorption (TD-CVAA)
Method 7473 25
5.2.3 Other Metals (ICP) 25
5.2.4 X-Ray Fluorescence (XRF) 29
5.2.5 XRF Detection Limits 30
5.2.6 Radionuclide Testing of CCRs using Ge-Detector 32
6. Quality Assurance/Quality Control 34
6.1 Data Quality Indicator Goals 34
6.2 QC Sample Types 35
7. Data Reduction, Validation, and Reporting 36
7.1 Data Analysis 36
7.2 Chemical (ICP, XRF, AE-OES, OC/EC) and Physical (Moisture) Characterization 41
7.3 Radionuclide Characterization 42
8. Assessments 44
9. References 46
Appendices
Appendix A Participating Laboratories
Appendix B Example Method Template Spreadsheet
Appendix C Documentation Sent to Each Participating Laboratory
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
Project No.: RN990272.0007
Revision: 0
Date: November 2011
Page: iii
List of Tables
Table 3-1. MDLs and RLs of the Metals to be Evaluated during the Validation Study 12
Table 3-2. Characterization Testing to Establish Homogeneity of the CCR 13
Table 3-3. Tentative Schedule for Interlaboratory Validation of Pre Method 1313 and Pre Method 1316 16
Table 4-1. Final Extract pH Targets 20
Table 4-2. Example Schedule for Extraction Setup 21
Table 5-1. MDL and MLQ of Total Organic Carbon Analyzer 24
Table 5-2. Method Detection Limits (MDLs) and Minimum Level of Quantification (ML) for ICP-OES Analysis
on Liquid Samples* 28
Table 5-3. XRF Reporting and Detection Limits 31
Table 6-1. Data Quality Indicator Goals 34
Table 8-1. PEA Parameters and Ranges 44
List of Figures
Figure 2-1. Project Organizational Chart
List of Acronyms and Abbreviations
AA atomic adsorption
ANOVA analysis of variance
APPCD Air Pollution Prevention and Control Division
ARCADIS ARCADIS, U.S., Inc.
CCR(s) coal combustion residue(s)
CCV continuing calibration verification
COPC(s) constituents) of potential concern
CVAA cold vapor atomic adsorption
DIG dissolved inorganic carbon
DOC dissolved organic carbon
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
Project No.: RN990272.0007
Revision: 0
Date: November 2011
Page: iv
DQI data quality indicator
EC elemental carbon
EPA U.S. Environmental Protection Agency
FGD flue-gas desulfurization
FWHM full width at half maximum
g gram
HPGe high purity germanium
1C inorganic carbon
ICP inductively couple plasma
ICV initial calibration verification
LOI loss on ignition
MDA minimum detectable activity
MDL method detection limit
ml milliliter
ML minimum level of quantification
MLQ minimum level of quantification
MS mass-spectrometry
NA not applicable
NCSU North Carolina State University
NIST National Institute of Science and Technology
NPOC non-purgeable organic carbon
OC organic carbon
OES optical emission spectroscopy
ORCR Office of Resource Conservation and Recovery
ORD Office of Research and Development
OSR Office of Solid Waste
QAPP quality assurance project plan
RL reporting limit
RPD relative percent difference
RSD relative standard deviation
SPLP synthetic precipitation leaching procedure
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
Project No.: RN990272.0007
Revision: 0
Date: November 2011
Page: v
SW-846 EPA Test Methods for Evaluating Solid Waste, Physical/Chemical Methods
TCLP toxicity characteristic leaching procedure
TD thermal decomposition
ISA technical system audit
XRF X-ray fluorescence spectrometry
C-7
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
Project No.: RN990271.0007
Revision: 0
Date: November 2011
Page: vi
Distribution List
Copies of this plan and all revisions will be initially sent to the following individuals. It is the responsibility of
the U.S. Environmental Protection Agency (EPA) Work Assignment Manager and of the ARCADIS, U.S.,
Inc. (ARCADIS) Work Assignment Leader to make copies of the plan available to all field personnel.
Susan Thorneloe, EPA Work Assignment Manager. Office of Research and Development, National Risk
Management Research Laboratory, Air Pollution Prevention and Control Division, Research Triangle Park,
NC.
Phone:(919)541-2709
Email: thorneloe.susan@epa.gov
Robert Wright, EPA Quality Assurance Officer. Office of Research and Development, National Risk
Management Research Laboratory, Air Pollution Prevention and Control Division, Research Triangle Park,
NC.
Phone:(919)541-4502
Email: wright.bob@epa.gov
Peter Kariher, ARCADIS Work Assignment Leader. Research Triangle Park, NC.
Phone:(919)541-5740
Email: peter.kariher@arcadis-us.com
Libby Nessley, ARCADIS Quality Assurance Officer. Durham, NC.
Phone: (919) 544-4535 x258
Email: libby.nesslev@arcadis-us.com
Dr. David Kosson, Methods Development. Vanderbilt University, Nashville, TN.
Phone:(615)322-1064
Email: David.Kosson@vanderbilt.edu
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
Project No.: RN990271.0007
Revision: 0
Date: November 2011
Page: vii
Dr. Florence Sanchez, Methods Development. Vanderbilt University, Nashville, TN.
Phone:(615)322-5135
E-mail: Florence.Sanchez@vanderbilt.edu
Dr. Andrew Garrabrants, Methods Development. Vanderbilt University, Nashville, TN.
Phone:(615)322-7226
Email: Andrew.Garrabrants@vanderbilt.edu
Dr. Hans van der Sloot, Methods Development. Hans van der Sloot Consultancy, The Netherlands.
Phone:+31 (0)226-341607
Email: hans@vanderslootconsultancy.nl
Dr. Leonard A Stefanski, Statistical Consultant. North Carolina State University, Raleigh, NC.
Phone:(919)515-1945
Email: stefanski@stat.ncsu.edu
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
Project No.: RN990272.0007
Revision: 0
Date: November 2011
Page: 1
1. Project Objectives and Organization
1.1 Purpose
The Air Pollution Prevention and Control Division (APPCD) of EPA's Office of Research and Development
(ORD) is conducting research to evaluate potential leaching and cross media transfers of mercury and other
constituents of potential concern (COPCs) resulting from the management of coal combustion residues
(CCRs) resulting from wider use of state-of-the art air pollution control technology. This research was cited
as a priority in EPA's Mercury Roadmap (http://www.epa.gov/mercury/roadmap.htm') to ensure that one
environmental problem is not being traded for another. The objective is to understand the fate of mercury
and other COPCs and ensure that emissions being controlled in the flue gas at power plants are not later
being released depending upon how the CCRs are managed.
As part of this research effort, individual leaching test methods have been developed for inclusion into
SW846. These methods were adapted by Dr. David Kosson, Dr. Florence Sanchez, and Dr. Andrew
Garrabrants of Vanderbilt University, and their consultant, Dr. Hans van der Sloot from The Netherlands,
from the publication titled An Integrated Framework for Evaluating Leaching in Waste Management and
Utilization of Secondary Materials (Kosson et al., 2002, Environmental Engineering Science, Volume 19,
Numbers, 159-203). Four test methods have been developed as preliminary versions of EPA methods1 and
can be found at http://www.vanderbilt.edu/leaching/downloads.html. The four leaching test methods include:
1. Pre Method 1313: Liquid-Solid Partitioning as a Function of Extract pH for Constituents in Solid
Materials using a Parallel Batch Extraction Procedure
2. Pre Method 1314: Liquid-Solid Partitioning as a Function of Liquid-Solid Ratio for Constituents in Solid
Materials using an Dp-flow Percolation Column Procedure
3. Pre Method 1315: Mass Transfer Rates of Constituents in Monolithic or Compacted Granular Materials
using a Semi-dynamic Tank Leaching Procedure
4. Pre Method 1316: Liquid-Solid Partitioning as a Function of Liquid-Solid Ratio for Constituents in Solid
Materials using a Parallel Batch Extraction Procedure
1 Preliminary Version denotes that this method has not been endorsed by EPA but is under consideration for inclusion
into SW-846.
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Multilaboratory validation data is necessary for a method to be considered for inclusion in SW-846 (per
Guidance for Methods Development and Validation for the RCRA Program). This Quality Assurance Project
Plan (QAPP) is being written to cover the EPA Interlaboratory Validation Study of the above four proposed
SW-846 leaching methods. A separate interlaboratory study will be performed for each of the four methods
separately. Due to similarities in equipment and procedures, the first methods to be tested are Pre Method
1313 and Pre Method 1316.
1.2 Project Objectives
US EPA's Office of Resource Conservation and Recovery (ORCR) formerly the Office of Solid Waste (OSW)
requires that an interlaboratory validation be conducted for a method to be considered for inclusion into
SW-846. This QAPP will detail the process by which each of the four proposed leaching methods will be
validated by at least five, and up to ten, different laboratories to establish reproducibility.
The determination of laboratory reproducibility is the final stage in the method development process, prior to
the submission of the method for ORCR review. By reproducibility, the Agency means that multiple
operators and multiple laboratories should be able to obtain comparable performance data on split samples
using the method. It is necessary to demonstrate that satisfactory method performance is not limited to the
individual operator or laboratory that developed the method. The minimum number of laboratories that are
needed to participate in a multilaboratory method validation is three, with preferably more. Developers of
new methods need to do a limited multilaboratory evaluation and provide the individual laboratory and
summary performance data in the method submission.
This QAPP is a replacement of the QAPP approved on June 21, 2010 (QTRAK# 03069-A00244). This
QAPP will provide details of the following tasks:
• Preparation and characterization of the CCR by APPCD's on-site laboratory support contractor,
ARCADIS, prior to distributing to each laboratory participating in the validation study (Task 1)
• Leaching of CCR and other method validation materials (by the proposed SW846 method) by
ARCADIS (to establish the baseline results) and by each participating laboratory. All leachates will be
submitted to Vanderbilt University for analysis (Task 2)
• Determination of the reproducibility (variability between laboratories), repeatability (single-operator
precision) and accuracy of each method (Task 3)
• Leaching of 5 fly ash, 3 scrubber sludge, the 3 other validation materials (foundry sand, solid waste
analog, and contaminated field soil), and a cement kiln dust sample using SW-846 Method 1311
"Toxicity Characteristic Leaching Procedure" (EPA, 1992) and SW-846 Method 1312 "Synthetic
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Precipitation Leaching Procedure" (EPA, 1994) with analysis for metals by ICP-OES for comparison
with the proposed new leaching methods (Task 4)
Vanderbilt will perform radionuclide testing on 35 fly ash samples, 6 flue-gas desulfurization (FGD)
gypsum and 1 cement kiln dust samples to determine uranium species and concentrations by the
measurement of Beta and Gamma decay particles (Task 5)
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2. Project Organization
The organizational chart for this project is shown in Figure 2-1. The roles and responsibilities of the project
personnel are discussed in the following paragraphs. In addition, contact information is also provided.
Appendix A identifies the nine laboratories participating in this interlaboratory validation study.
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QA Officer
Libby Nessley, ARCADIS
Interlaboratory Validation
Studv Particioants
Representing:
• EPA Laboratories
• DOE Laboratories
• Commercial Laboratories
Safety Officer
Jerry Revis, ARCADIS
Peter Kariher, ARCADIS
Rosanne Delapp, Vanderbilt
Leaching Sample
Generation
Eric Morris, ARCADIS
Methods Development /
Fvalnatinn
David Kosson, Vanderbilt
Florence Sanchez, Vanderbilt
Andrew Garrabrants, Vanderbilt
Hans van der Sloot, Consultant
ICPMS Analytical Manager
Kathryn Smith, Test America
Figure 2-1. Project Organizational Chart
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EPA Work Assignment Manager. Susan Thorneloe: The EPA WA Manager is responsible for
communicating the scope of work, and is the primary party responsible for review and approval of this QAPP
and all other deliverables under this work assignment. The EPA WA Manager is responsible for providing
ARCADIS with the various CCR to be used for this interlaboratory validation study. Ms. Thorneloe will also
send requests to a number of EPA, DOE and commercial laboratories asking for participation in this
interlaboratory study, and will be responsible for making the final selection of which laboratories will be
included in the study. She will receive the laboratory data packages, and oversee the evaluation of the
results by Vanderbilt, ARCADIS, and the NCSU statistician.
Phone: (919)541-2709
E-mail: thorneloe.susan@epamail.epa.gov
EPA QA Representative. Robert Wright: The EPA QA Representative will be responsible for reviewing
and approving this QAPP. This project has been assigned a QA category III and may be audited by EPA
QA. Mr. Wright is responsible for coordinating any EPA audits.
Phone (919) 541-4502
E-mail: wright.bob@epamail.epa.gov
ARCADIS Work Assignment Leader. Peter Kariher: The ARCADIS WA Leader is responsible for
preparing project deliverables and managing the work assignment. He will ensure the project meets
scheduled milestones and stays within budgetary constraints agreed upon by EPA. The WA Leader is also
responsible for communicating any delays in scheduling or changes in cost to the EPA WA Manager as
soon as possible. Mr. Kariher, along with Dr. Kosson (Vanderbilt) and Dr. Stefanski (NCSU) will review the
laboratory data packages.
Phone (919) 541-5740
E-mail: peter.kariher@arcadis-us.com
ARCADIS Inorganic Laboratory Manager. Peter Kariher: In addition to being the WA Leader, Peter
Kariher is also responsible for the operation of EPA's in-house Inorganic Laboratory. Mr. Kariher is
responsible for preparation of this QAPP, and will prepare the homogenized CCR(s) to be used in the
interlaboratory validation study. He will perform the characterization and leaching of each CCR by Pre-
Methods 1313 and 1316 prior to distributing the CCR to the labs for comparative analysis. Mr. Kariher will
operate the mercury analyzer and ion chromatograph, and forthe leaching studies and mercury and metals
analyses, will be supported by one technician: John Foley. Mr. Kariher will perform SW-846 Method 3052
digestion of solid CCR samples and also be responsible for mercury analysis of samples by CVAA. John
Foley will perform the leaching tests. Mr. Kariher will submit the remaining Method 3052 digestates to the
subcontract analytical laboratory, Test America-Savannah for ICP/MS analysis of the other target metals. He
will also be involved with the EPA WAM and the Vanderbilt University methods developers in evaluating the
results.
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Phone (919) 541-5740
E-mail: peter.kariher@arcadis-us.com
Test America-Savannah Analytical Manager. Kathryn Smith: Ms. Smith will review and validate the
ICP/MS results for total content digest samples and report them to Mr. Kariher.
Phone (912) 354-7858
E-mail: kathye.smith@testamericainc.com
ARCADIS Designated QA Officer. Lib by Nessley: The ARCADIS QA Manager, Libby Nessley, has been
assigned QA responsibilities for this work assignment. Ms. Nessley will be responsible for reviewing this
QAPP prior to submission to EPA QA for review. Ms. Nessley will perform an internal data quality audit on at
least 10% of the ARCADIS reported data. In addition, she will perform a Technical System Audit (TSA) if
requested by the EPA WAM or the ARCADIS WAL. All QA/QC related problems will be reported directly to
the ARCADIS WAL, Peter Kariher.
Phone:(919)544-4535
E-mail: libby.nesslev@arcadis-us.com
Vanderbilt University. Methods Development. Professors David Kosson. Florence Sanchez. Andrew
Garrabrants. and Rossane Delapp; Consultant. Methods Development. Hans van der Sloot: Dr.
Kosson in cooperation with Dr. Florence Sanchez, Dr. Andrew Garrabrants, and Dr. Hans van der Sloot
developed the leachability methods being evaluated during this interlaboratory validation study. All leachates
will be sent to Vanderbilt University for analysis by ICP-OES. Ms. Rossane Delapp will assist in the analysis
of the leachates for determination of the non-mercury metals concentrations and will develop the LeachXS
Lite analytical database for sample data viewing and reporting. Ms. Delapp will also be responsible for the
reference lab application of Pre-Methods 1313, 1314,1315 and 1316. Drs. Kosson, Sanchez, Garrabrants,
and van der Sloot will be available to consult with the EPA WAM and ARCADIS Inorganic Laboratory
Manager regarding the evaluation of the interlaboratory comparative results for each of the proposed
SW846 methods. Dr. Kosson, Dr. Garrabrants, Mr. Kariher (ARCADIS) and Dr. Stefanski (NCSU) will review
the laboratory data packages.
Dr. David Kosson
Phone:(615)322-1064
E-mail: David.Kosson@vanderbilt.edu
Dr. Florence Sanchez
Phone:(615)322-5135
E-mail: Florence.Sanchez@vanderbilt.edu
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Dr. Andrew Garrabrants
Phone:(615)322-7226
E-mail: Andrew.Garrabrants@vanderbilt.edu
Dr. Hans van der Sloot
Phone:+31 (0)226-341607
E-mail: hans@vanderslootconsultancy.nl
Ms. Rossane Delapp
Phone: (615)322-1064
E-mail: rossane.c.delapp@vanderbilt.edu
ARCADIS Project Manager. Johannes Lee: The ARCADIS Project Manager, Johannes Lee, has been
assigned financial, contractual and managerial responsibilities for this work assignment. Mr. Lee will be
responsible for communications with the EPA project officer, the oversight of financial status, and fulfilling
contractual requirements.
Phone: (919)544-4535
E-mail: iohannes.lee@arcadis-us.com
ARCADIS Safety Officer. Jerry Revis: The ARCADIS Safety Officer, Jerry Revis, has been assigned the
safety supervisor responsibilities for this work assignment. Mr. Revis will be responsible for reviewing safety
plans, performing periodic safety inspections, communicating with the EPA safety office, and oversight of
safety operations.
Phone:(919)544-4535
E-mail: ierry.revis@arcadis-us.com
North Carolina State University (NCSU). Statistical Consultant. Dr. Leonard A Stefanski: Dr. Stefanski
will provide statistical consultation on the planning and implementation of interlaboratory study to ensure
validity of the collected data. He will also provide advice on the choice and application of statistical methods
used to analyze the study data, and on the interpretation of results obtained from the statistical analyses. Dr.
Stefanski will report to Mr. Wright, the EPA QA Representative. He will assist Dr. Kosson (Vanderbilt) and
Mr. Kariher (ARCADIS) in reviewing the laboratory data packages.
Phone:919-515-1945
E-mail: stefanski@stat.ncsu.edu
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3. Experimental Approach
This interlaboratory comparison will include a comparison of leaching test methods performance by a
reference laboratory (either ARCADIS or Vanderbilt) and minimum of six participant laboratories (see
Appendix A; nine participant laboratories are currently planned) based on testing of three different materials
for each leaching test method to be evaluated. The goal of this study is to determine intra-laboratory and
inter-laboratory reproducibility for the four test methods under development. Following is a list of key
elements for regulatory methods development as specified in the SW-846 guidance document, and the
applicability of each element for this study:
Element 1: Identification of Scope and Application and Regulatory Need
The methods being developed through this study are intended to provide improved leaching
characterization of wastes and other materials for use and disposal under a range of field exposure
conditions by considering the materials physical characteristics that effect water flow (e.g., granular
or monolithic and thus controlling whether water flows through or around the material), and potential
field conditions (i.e., pH, water contact mode, liquid-solid ratio). These methods are planned to be
applicable for assessments where use of other leaching test methods are not statutorily required.
Element 2: QA/QC Requirements
QA/QC requirements for each method under development are indicated within each method
description and are consistent with SW-846 requirements. QA/QC requirements for this study are
indicated in this QAPP.
Element 3: Analytical Approach
This study is to evaluate leaching tests (e.g., aqueous extraction tests) that are operationally defined
and intended to provide estimation of underlying physical and chemical phenomena controlling
constituent release from a solid material to contacting water. Thus, the method of analysis selected
for leaching test eluates (i.e., ICP-OES) was a method that was suitably efficient and sensitive for
the purposes of this study (see Section 5.2.3). Additional characterization of materials to be tested
is being carried out using other analytical techniques (see Section 5).
Element 4: Method/Instrument Sensitivity
Method/instrument sensitivity is based on the chemical analysis technique for leaching test eluates
that is selected. This study uses previously standardized methods for chemical analysis.
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Element 5: Method Optimization and Ruqqedness Testing
An extensive study has been completed that provides an evaluation of related test methods
development and optimization based on compilation and evaluation of results from international
studies (van der Sloot, et al. 2010). This program is consistent with those findings.
Element 6: Accuracy, Precision and Repeatability (Clean Matrix)
Determination of accuracy is not possible for leaching tests because they are operationally defined
and there is no absolute correct value that can be verified using an independent characterization
technique. Precision and repeatability for a clean matrix is not possible because of the nature of the
materials being evaluated. Instead, intra-laboratory and inter-laboratory repeatability and
reproducibility is determined.
Element 7: Effect of Interferences
Method interferences for leaching test methods are either (i) difficulties in physical handling of
materials and liquid-solid separation as part of the test method, or (ii) analytical interferences
observed during chemical analysis of leaching test eluates. Physical handling and liquid-solid
separation difficulties will be noted based on the experience of the participant and reference
laboratories. Analytical interferences will be observed based on the analytical QA/QC program (See
Section 5) but are not expected based on prior experience testing similar materials.
Elements: Matrix Suitability
Not applicable.
Element 9: Quantitation and Detection Limits
Determination of quantitation and detection limits is not a goal of this study. Quantitiation and
detection limits for the chemical analysis techniques to be used in this study are provided in Section
5.
Element 10: Laboratory Reproducibility
This element is the primary focus of this study and addressed as part of this QAPP.
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Element 11: Document Submission and Workgroup Evaluation
Data reduction and evaluation is specified in this QAPP. The result will be separate detailed reports
documenting results for each test method. An EPA methods workgroup has been formed for these
methods following the SW-846 procedures. Mark Baldwin (EPA-OSWR) is the project's liaison with
the SW-846 methods workgroup.
The experimental design addresses determining within and between laboratory reproducibility for a set of
four leaching test methods. An unbalanced factorial design is being used with appropriate analysis of
variance statistical techniques used for data evaluation (see Section 7). Each method will be challenged
using three distinctly different materials (coal fly ash, blended Portland cement mortar that includes coal fly
ash, metals contaminated soil), selected to reflect a broad range of material properties. Six analytes will be
selected for each material to serve as the basis for evaluation. Each analyte will be selected to represent the
range of leaching behavior (e.g., concentration as a function of pH and liquid-solid ratio) typically observed
for the material being evaluated and be readily detected using a single analytical method (i.e., ICO-OES).
Each method is being treated as a separate evaluation from the other methods. Each material evaluated
will also be treated statistically as independent evaluations because of the wide range in leaching behavior
of individual constituents from material to material (these variations can span several orders of magnitude).
Within the statistical design for each method evaluated, the principal factor is testing laboratory (a minimum
of 6 independent laboratories and a reference laboratory). The selection of a minimum of 6 independent
laboratories is consistent with ASTM recommendations (ASTM, 1988). The reference laboratory and each
independent laboratory will carry out the designated test method 6 times and 3 times, respectively, on each
material to determine intra-laboratory reproducibility and inter-laboratory reproducibility based on intra-
laboratory and inter-laboratory variance. Individual laboratory bias will be evaluated based on deviation from
the mean values observed across all laboratories and the statistical significance of the deviation. Each
analyte will be treated independently for statistical analysis purposes.
The following discussion is specific to a coal fly ash as an example of the approach that will be used for
preparation and evaluation of all materials selected for the study. Coal fly ash from a single facility will be the
first material used in this study.
3.1 Task I: Preparing Homogenized CCR
An energy facility, which participated with EPA in an earlier study, has agreed to provide twenty-five, 5-
gallon buckets of raw ash for this interlaboratory validation study. The raw ash being supplied this time is
from the same facility that was included in an EPA study focused on leaching characterization of a range of
CCRs, thus providing extensive useful information on approximate testing results (EPA, 2009). ICP-OES
was used to analyze these samples. A list of eight metals have been selected (As, Sb, Ba, B, Ca, Cr, Co,
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Mo, Se, and V) as the focus of the intercomparison study, and their method detection limits (MDL) and
quantitation or reporting limits (RL) are shown in Table 3-1. From the previous work, graphs have been
generated showing the pH dependent concentration of each metal.
This section details how this CCR will be homogenized, split, and tested to ensure that each participating
laboratory receives like samples for analysis.
Table 3-1. MDLs and RLs of the Metals to be Evaluated during the Validation Study
Metal
As
Sb
Ba
B
Ca
Cr
Co
Mo
Se
V
MDL
(ug/L)
11.0
8.00
1.00
1.00
2.6
1.00
1.00
1.2
15.0
1.5
RL
(ug/L)
35.0
25.4
3.18
3.18
8.3
3.18
3.18
3.8
47.7
4.8
A core sample will be taken from 12 of the 25 homogenized buckets and tested to establish homogeneity
and to provide characterization data of the CCR. A summary of this testing is shown in Table 3-2. Detailed
descriptions of each testing procedure are presented in Section 5. The initial homogeneity testing will be
performed using the XRF analysis as the screening technique. Total mercury by thermal decomposition
using the Lumex and total digestion methods will be used to further evaluate the CCR leaching reference
material. Although further homogenization occurs for each method - as detailed below - this initial core
sampling and characterization testing is used to verify that the starting material (which will be used for all
validation testing) is indeed homogeneous. Previous results suggest that silicon, a major constituent of this
fly ash, will differ by less than 1 %. Other constituents can vary by up to 25%. Wider variation between core
sample results would indicate that additional homogenization between buckets would be required before
proceeding.
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Table 3-2. Characterization Testing to Establish Homogeneity of the CCR
Method Analytes Number of Replicates
XRF / solids Total metals content (%) Single pellet of twelve core samples
Lumex / solids Total mercury (Hg) Triplicate analysis of each core sample
Method 3052 / liquids Total metals Four cores, selected randomly
Method 3051 / liquids Total boron (B) Four cores, selected randomly
Method 1313 / liquids Leaching behavior by pH Aliquots of the four, randomly selected cores
EC/OC*/ solids Elemental and organic carbon Twelve cores, selected randomly
* Elemental carbon/organic carbon needed for accurate XRF calculations
The percent relative standard deviation (RSD) will be calculated with an RSD<10% for major constituents
and RSD<20% for trace constituents considered sufficient homogeneity for use in the study.
Each of the proposed SW846 methods will be tested with this ash as the CCR. The detailed procedure for
the further homogenization (to ensure that each laboratory is receiving the exact same material for each
method being tested) and distribution for testing for each method is detailed below.
Method 1313: Approximately 40 kg (two 5-gallon pails) of material will be combined into a single mixing
drum, mixed and then subdivided into approximately 1-kg (1 L) subsamples. Subdivision of the mixed batch
into portions will be by coring or a similar method to ensure that potential stratification of the mixed batch
does not bias the individual subsamples. The result of the homogenization will be approximately forty 1-L
subsamples in 1-L wide mouth HOPE containers with screw top lids. Each participating laboratory will
receive two randomly-selected 1-L subsamples for the purpose of carrying out 3 replicate Method 1313 tests
on the designated material. Four randomly selected 1-L subsamples will be used to conduct 6 replicate
Method 1313 tests by the referee laboratory (ARCADIS). The remaining unused subsamples will be
archived. For Phase I testing, the designated material is a coal fly ash.
Method 1314: Approximately 60 kg (three 5-gallon pails) of material will be combined into a single mixing
drum. Each batch will be mixed and then subdivided into approximately sixty 1-kg (1-L) subsamples.
Subdivision of the mixed batch into subsamples will be by coring or similar method to insure that potential
mixed batch stratification does not bias the individual subsamples. This homogenization process will result in
approximately sixty 1-L subsamples in 1-L wide mouth HOPE containers with screw top lids. Each
participating laboratory will receive four randomly-selected 1-L subsamples for the purpose of carrying out 3
replicate Method 1314 tests on the designated material. Eight randomly selected 1-L subsamples will be
used to carry out 6 replicate Method 1314 tests by the referee laboratory (Vanderbilt). The remaining unused
subsamples will be archived. For Phase I testing, the designated material is a coal fly ash.
Method 1315: Approximately 100 kg (five 5-gallon pails) of material will be combined to at most two batches
to be blended in mixing drum. Each batch will be mixed and then subdivided into approximately one hundred
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1-kg (1-L) subsamples. Subdivision of the mixed batch into subsamples will be by coring or similar method to
insure that potential mixed batch stratification does not bias the individual subsamples. This procedure will
result in approximately one hundred 1-L subsamples in 1-L wide mouth HOPE containers with screw top
lids. Eight randomly selected 1-L subsamples will be provided to each participating laboratory for purpose of
carrying out 3 replicate Method 1315 tests on the designated material. Sixteen randomly selected 1-L
subsamples will be used to carry out 6 replicate Method 1315 tests by the referee laboratory (Vanderbilt).
The remaining unused subsamples will be archived. For Phase I testing, the designated material is a coal fly
ash.
Method 1316: Approximately 60 kg (three 5-gallon pails) of material will be combined into a single mixing
drum. Each batch will be mixed and then subdivided into approximately one hundred 1-kg (1-L) subsamples.
Subdivision of the mixed batch into subsamples will be by coring or similar method to insure that potential
mixed batch stratification does not bias the individual subsamples. The homogenization process will result in
approximately sixty 1 -L subsamples in 1 -L wide mouth HOPE containers with screw top lids. Four randomly
selected 1-L subsamples will be provided to each participating laboratory for purpose of carrying out 3
replicate Method 1316 tests on the designated material. Eight randomly selected 1-L subsamples will be
used to carry out 6 replicate Method 1316 tests by the referee laboratory (ARCADIS). The remaining unused
subsamples will be archived. For Phase I testing, the designated material is a coal fly ash.
Overall Implications: Thirteen 5-gallon buckets of coal fly ash will be used; 260 1-L wide mouth HOPE jars
are needed.
Use of Spiked Samples
Spiking of field generated samples with constituents of concern is generally not recommended because of
the difficulty of achieving (i) uniform distribution of the constituent spike, and (ii) speciation of the spiked
constituent within reference material that is representative of the speciation of the same constituent originally
present. However, spiking of a laboratory-generated reference material (e.g., cement stabilized waste form)
for specific constituents of interest is practical because the added spikes will be the primary source of the
constituent of interest and uniform distribution can be achieved during the slurry mixing process used to
create the sample material. Any spiked samples utilized in this study will be approved by the EPA WAM and
fully documented in the project report.
3.2 Task II: Leaching of the CCR by Reference Laboratory and the Intercomparison Laboratories
ARCADIS, having extensive experience in these leaching methodologies as documented in earlier studies,
will be responsible for producing the reference leaching data. Six of the cores (as described in Section 3.1
for the characterization testing) will be randomly selected as the replicates to be analyzed by the reference
laboratory (ARCADIS or Vanderbilt) by the proposed SW846 method. These results will be compared to the
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historical data available for this ash (as described in Section 3.1) to establish the reference results for the
method being validated.
Each laboratory will be provided with the following:
1. An introductory letter reiterating the purpose of this study and the laboratory's participation
2. A copy of the SW846 method being validated
3. An amount of homogenized CCR which is adequate to conduct three test replicates
4. Method template spreadsheet
5. As recommended by ORCR, each lab will be asked to have their extractions performed by a single
operator on a single instrument in a single batch to minimize variability inherent to the determinative
method; all leaching test eluates will be analyzed by ICP-OES for selected constituents by Vanderbilt to
minimize variability associated with the metals analysis step since the focus of this study is on the
leaching test methods not chemical analysis.
The spreadsheet is very user-friendly and walks the participant through each step of the method and
provides a standardized mechanism for data entry into a database for this study as well as comparing
results of the materials tested in this study to results obtained from other studies. Appendix B contains a
printout of the pages in the Method 1313 spreadsheet showing the instructions and each of the data entry
sheets. Appendix C contains examples of the introductory letter, instruction sheet, questionnaires for
Methods 1313 and 1316, chain-of-custody form, and a page of sample labels sent to each participating
laboratory.
Each laboratory will be asked to perform the each of the four proposed methods in triplicate (e.g., 9 pH
levels + 3 blanks per test = 36 leachates for Method 1313) within one month. The leachates are to be
forwarded to Vanderbilt for analysis. In addition, they are to forward the completed data package to the EPA
WAM and Vanderbilt, which will include:
• The completed electronic data report forms (provided as Microsoft® Excel spreadsheets)
• Photocopies or printouts of all raw data, laboratory notebook documentation, calculations, results and
comments
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• A completed questionnaire indicating any deviations from the prescribed method that were necessary,
methodology clarifications needed or suggested, personnel time required to complete the method, and
any other suggestions.
The tentative schedule for the interlaboratory validation of the method is shown in Table 3-3.
Table 3-3. Tentative Schedule for Interlaboratory Validation of Proposed SW-846 Methods
Milestone Tentative Date
Receive ash from previously participating facility Complete in 2010
Initial characterization and baseline testing Completed in 2010
Lab's receive material for testing Completed in 2010 and 2011
Labs send leachates to Vanderbilt for analysis November 2011
Vanderbilt provides results to EPA December 2011
Provide final reports for the methods testing January 2012
3.3 Task III: Determination of the Reproducibility of Each Method
Following receipt of the completed data packages from each participating laboratory and the results of the
leachate analyses from Vanderbilt, statistical determination of the reproducibility (variability between
laboratories) and repeatability (single-operator precision) of each method will be determined. Leach testing
results and feedback will be compiled with like data from other laboratories performing the same method,
and will be submitted as part of a supportive data package for EPA ORCR method approval.
3.4 Task IV: Testing of Select Materials for Leaching by SW-846 Methods 1311 (TCLP) and 1312 (SPLP)
Testing of some selected CCRs and the materials from the interlaboratory methods validation study will be
performed by ARCADIS using SW-846 Methods 1311 "Toxicity Characteristic Leaching Procedure (TCLP)"
and 1312 "Synthetic Precipitation Leaching Procedure (SPLP)" for comparison with the proposed new SW-
846 methods. Leachate will be sent to Vanderbilt for analysis by ICP-OES. Results from these experiments
will be used to show the comparability of leaching behavior between these tests and the proposed new SW-
846 methods. TCLP uses a glacial acetic acid and sodium hydroxide buffer solution with a pH of 4.93 ±
0.05 (Extraction Fluid #1) at a 20 to 1 solid to liquid ratio. SPLP uses a weak sulfuric and nitric acid solution
with a pH of 4.2 ± 0.05 (Extraction Fluid #1) at a 20 to 1 liquid to solid ratio to simulate leaching for samples
east of the Mississippi river. Samples will be tumbled for 18 hours and filtered to remove the solids. The
extract will be preserved with 1 % nitric acid and analyzed by Vanderbilt University using ICP-OES. Table 3-
4 lists the samples currently selected for TCLP and SPLP testing.
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Table 3-4. Sample Testing List for TCLP and SPLP
Sample Name
CaFA
EaFA
KFA
UFA
ZFA
YSD
MAD
DGD
CKD
SWA
CFS
JaFS
CKD
Sample Type
Fly Ash
Fly Ash
Fly Ash
Fly Ash
Fly Ash
Spray Dryer Ash
FGD + Fly Ash Mix
Scrubber Sludge
Scrubber Sludge
Solid Waste Analog
Contaminated Field Soil
Brass Foundry Sands
Cement Kiln Dust
3.5 Task V: Testing of Fly Ashes and Cement Kiln Dust for Radionuclide Testing by Germanium Detector
Vanderbilt will perform radionuclide testing on 35 fly ash samples and 1 cement kiln dust sample to
determine uranium species and concentrations by the measurement of Beta and Gamma decay particles
using a Germanium (Ge) detector made by ???.
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4. Sampling Procedures
The following subsections describe the sampling procedures to be used for each task. Whenever possible,
standard methods will be followed. In some cases, draft methods may be evaluated and implemented. Each
method to be used will be cited and any deviations from the methods will be documented.
4.1 Sample Custody Procedures
The detailed procedures for preparing and distributing the homogenized CCR were presented in Section 3.1.
The following types of samples will be generated during these tests:
1. Solid samples for leaching and radionuclide testing: fly ash, solid waste analog, contaminated field soil,
brass foundry sands, scrubber sludge, and cement kiln dust
2. Post -leaching and post-thermal desorption of the CCR (solid samples)
3. Leachate samples (liquid samples) for Hg and other metals analysis
Each sample generated will be analyzed in-house or by outside laboratories. Chain-of-custody (COC)
procedures will be required, which will include signing and dating of COCs to indicate receipt of samples,
and archived of all COCs with other project documentation. CCRs will be logged as they are received by the
ARCADIS WAL, Mr. Peter Kariher. Information regarding where each CCR originated and any other
descriptive information available will be recorded in a dedicated laboratory notebook by Mr. Kariher. A core
sample will be taken from each 5-gallon bucket of homogenized material and processed for physical and
chemical characterization (see Section 3.1). All samples will be properly contained and identified with a
unique sample ID and sample label. Chain-of-custody forms will be generated for all samples prior to
transfer for analysis.
The sample labeling convention used to identify a particular solution consists of numerical identifiers for the
material, lab, test method, and test position along with an alphabetical identifier for the test replicate. The
layout for the sample label convention is as follows:
Maa-LJbJb-131c-Tcfcf-e (Test Positions T01 through T09)
Maa-LJbJb-131c-Bdd-e (QA/QC Blanks B01-B03)
"aa" is a two-digit number starting at zero that identifies the test material (e.g., the Phase I
material is M01),
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"bb" is a two-digit number starting at zero that identifies the participating laboratory (assigned
randomly by EPA-ORCR),
'c" is a single digit number that completes the test method ID (i.e., 1313,1314,1315,1316,
TCLP, or SPLP),
"dd" is a two-digit number starting at zero that identifies the test position or QA/QC blank.
"e" is a single letter representing the test replicate (i.e., A, B or C).
Four sets of completed labels were provided to be used for labeling extraction vessels (for the tree replicates
and a fourth set for replacements as needed) and two sets of 50-mL analytical samples.
For example. M01-L02-1313-B02-C would represent Phase I material being validated by the laboratory
randomly identified as "02". The sample is from Method 1313, is blank 02, and replicate C.
Handling of CCR samples for the leaching tests (Task III) is described in detail in each of the proposed
SW846 methods. These methods can be found on the Vanderbilt University website at
http://www.vanderbilt.edu/leaching/downloads.html.
4.2 CCR, and Leaching Reference Material Samples
As mentioned, the objective of this validation study is to obtain information on the reproducibility of the
preliminary versions of EPA methods for leaching Al, Sb, Ba, B, Cr, Co, Mg, and Zn from CCRs. The facility
descriptions will include information on the history/origin of each method validation sample, facility process
description, sample type, sampling location, sampling time and method, coal type, operating condition, and
sample storage condition. Section 4.1 describes the sampling custody procedure.
4.2.1 Physical and Chemical Characterization Samples
A core sample will be taken from twelve of the 5-gallon buckets of the homogenized method validation
material (as described in Section 3.1) and subjected to physical characterization measurements. These 12
core samples will be mixed together using a riffle splitter prior to XRF pellet preparation and analysis. To
ensure a good homogeneity of the final composite sample that will be used for the XRF characterization, the
first two composite samples exiting the splitter will be reintroduced at the top of the splitter. This procedure will
be repeated at least 6 times. At the end, the two resulting homogeneous composite samples will be combined
in the same sample container and stored until XRF testing. Method 3052 samples will also be performed on
each of the method validation materials to determine variability for trace elements.
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4.2.2 Leaching Study Samples
Method validation materials used for leaching studies will not require size reduction to acquire an adequate
sample for testing due to the small particle size inherent in fly ash. The size reduction method is outlined in
the leaching test methods (http://www.vanderbilt.edu/leachinq/downloads.html'). If the method validation
materials are altered in any way prior to leaching studies, a representative sample will be submitted for
physical and chemical characterization.
4.3 Leachate Collection
Each of the proposed SW-846 test methods will be used to conduct a leaching study. The proposed
methods can be found on the Vanderbilt University website at
http://www.vanderbilt.edu/leachinq/downloads.html. Table 4-1 shows the extraction schedule and the range
of tested pHs as outlined in the first study to be conducted on the Preliminary Version of EPA Method 1313:
Liquid-Solid Partitioning as a Function of Extract pH for Constituents in Solid Materials using a Parallel Batch
Extraction Procedure.
Table 4-1. Final Extract pH Targets for Method 1313
pH Target Rationale
Will Vary* Natural pH at LS 10 mL/g-dry (no acid/base addition)
2.0±0.5 Provides estimates of total or available COPC content
4.0±0.5 Lower pH limit of typical management scenario
5.5±0.5 Typical lower range of industrial waste landfills
7.0±0.5 Neutral pH region; high release of oxyanions
8.0±0.5 Endpoint pH of carbonated alkaline materials
9.0±0.5 Minimum of LSP curve for many cationic and amphoteric COPCs
12.0±0.5 Maximum in alkaline range for LSP curves of amphoteric COPCs
13.0±0.5 Upper bound (field conditions) for amphoteric COPCs
10.5±0.5 Substitution if natural pH falls within range of a mandatory target
This is the pH of the material as received with only deionized water added (i.e., no acid or base addition).
Table 4-2 shows an example schedule for the extraction setup to be conducted on the Preliminary Version
of EPA Method 1316: Liquid-Solid Partitioning as a Function of Liquid-Solid Ratio for Constituents in Solid
Materials using a Parallel Batch Extraction Procedure.
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Table 4-2. Example Schedule for Method 1316 Extraction Setup
A
Test
Position
T01
T02
T03
T04
T05
B01
Total
NOTE: 1)
B
Target
LS
10.0
5.0
2.0
1.0
0.5
QC
This schedule
c
Minimum Dry
Mass
(g-dry)
20
40
100
200
400
-
-
assumes a target
D
Mass of
"As-Tested1
Sample
(g)
22.2
44.4
111
222
444
844
liquid volume
E
Moisture in
"As-Tested"
Sample
(mL)
2.2
4.4
11.1
22.2
44.4
of 200 ml.
F
Volume of
Reagent
Water
(mL)
198
196
189
178
156
200
1120
G
Recommended
Bottle Size
(mL)
250
250
500
500
1000
250
2) This schedule is based on "as tested" solids content of 0.90 g-dry/g.
3) Test position marked B01 is a method blank of reagent water.
To demonstrate the versatility and robustness of the proposed new leach test methods, various solid
materials other than CCRs were chosen for testing. Table 4-3 shows the proposed test methods and each
of the materials to be tested. Table 4-4 gives a brief description of the various solid materials to be tested.
Table 4-3. Materials to be used with the Proposed New Leach Tests
Method
Materials
1313 Fly Ash (EaFA), CFS (Contaminated Field Soil), and SWA (Solid Waste
Analog)
1314 CFS (Contaminated Field Soil) and JaFS (Brass Foundry Sands)
1315 SWA (Solid Waste Analog) and CFS (Contaminated Field Soil)
1316 Fly Ash (EaFA), CFS (Contaminated Field Soil), and SWA (Solid Waste
Analog)
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Table 4-3. Description of Materials for the Proposed New Leach Testing
Material Description
EaFA Fly ash from a 2.4 G Watt power plant burning eastern-bituminous coal
CFS Contaminated field soil collected from an active copper and lead smelting
site
SWA Solid waste analog material containing Type I portland cement, class C
coal combustion fly ash, and ground granulated blast furnace slag) and
wastewater at a water/binder ratio of 0.41 (m/g). The wastewater used
was tap water spiked with powdered metal oxides or metal nitrates of
antimony, arsenic, barium, chromium, lead and selenium. This combined
material was used to produce both solid monoliths and ground for 2-mm
power
1316 Fly Ash (EaFA), CFS (Contaminated Field Soil), and SWA (Solid Waste
Analog)
1316 Fly Ash (EaFA), CFS (Contaminated Field Soil), and SWA (Solid Waste
Analog)
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5. Testing and Measurement Protocols to be Used for Reference Material Characterization and
Eluate Characterization
As part of the initial characterization of the raw fly ash CCR, ARCADIS will conduct physical and chemical
characterization analyses. In addition, total metals will be analyzed by Test America, and the metals in the
leaching extracts will be analyzed by Vanderbilt University. Whenever possible, standard methods will be
used to perform required measurements. Standard methods are cited in each applicable section. Where
standard methods are not available, operating procedures will be written to describe activities. In situations
where method development is ongoing, activities and method changes will be thoroughly documented in
dedicated laboratory notebooks.
5.1 Physical Characterization
5.1.1 pH and Conductivity
pH and conductivity will be measured on all aqueous extracts by the laboratory (reference and participant
laboratories) carrying out the leaching test method.. Conductivity is a measure of the ability of an aqueous
solution to carry an electric current. This ability is dependent upon the presence of ions; on their total
concentration, mobility, and variance; and on the temperature of the measurement.
pH of the leachates will be measured by using a combined pH electrode. A 3-point calibration will be done
using National Institute of Science and Technology (MIST) traceable pH buffer solutions. The pH meter will
be accurate and reproducible to 0.1 pH units with a range of 0 to 14.
Conductivity of the leachates will be measured using a standard conductivity probe. The conductivity probe
will be calibrated using appropriate standard conductivity solutions for the conductivity range of concern.
Conductivity meters are typically accurate to +1% and have a precision of +1%. The procedure to measure
pH and conductivity will be as follows:
Following a gross separation of the solid and liquid phases by centrifugation or settling, a minimum volume
of the supernatant to measure the solution pH and conductivity will be taken and poured in a test tube. The
remaining liquid will be separated by pressure filtration and filtrates will be appropriately labeled, preserved,
and stored for subsequent chemical analysis.
5.1.2 Moisture Content and Loss on Ignition (LOI)
Moisture content of the raw fly ash CCR will be determined using ASTM D 2216-05 (ASTM 2005) by
ARCADIS. This method, however, is not applicable to the materials containing gypsum (calcium sulfate
dihydrate or other compounds having significant amounts of hydrated water), since this material slowly
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dehydrates at the standard drying temperature (110°C). This slow dehydration results in the formation of
another compound (calcium sulfate hemihydrate) which is not normally present in natural material. The
ASTM method allows cooling at 60 °C to prevent the conversion and will be used to determine the moisture
content of materials containing gypsum.
Loss on ignition (LOI) will be performed on the raw fly ash CCR by placing dried samples in a furnace at
750 °C for 1 hour and measuring the mass lost during the combustion using ASTM D7348-08 (ASTM 2008).
5.2 Chemical Characterization
5.2.1 Dissolved Organic Carbon / Dissolved Inorganic Carbon (DOC/DIC) and Elemental Carbon / Organic Carbon
(EC/OC)
Analyses of total dissolved organic carbon (DOC) and dissolved inorganic carbon (DIG) will be performed on
the leachates as part of the baseline characterization by Vanderbilt University on a Shimadzu model TOC-V
CPH/CPN combustion catalytic oxidation NDIR analyzer. Five-point calibration curves, for both inorganic
(1C) and non-purgeable organic carbon (NPOC) analyses, are generated for an analytical range between 5
ppm and 100 ppm and are accepted with a correlation coefficient of at least 0.995. Reagent grade
potassium hydrogen phthalate is used as the NPOC standard and sodium hydrogen carbonate is used as
the 1C standard. An analytical blank and check standard at approximately 10 ppm are run every 10 samples.
The standard is required to be within 15% of the specified value. A new calibration curve is generated if the
check standard measurement does not meet specification. A volume of approximately 16 ml of undiluted
sample is loaded for analysis. Inorganic carbon analysis is performed first for the analytical blank and
standard and then the samples. Total carbon (non-purgeable organic carbon) analysis follows with addition
of 2M hydrochloric acid to a pH of 2 and a sparge gas flow rate of 50 mL/min. Method detection limit (MDL)
and minimum level of quantification (MLQ) are shown in Table 5-1.
Table 5-1. MDL and MLQ of Total Organic Carbon Analyzer
MDL (ppm) MLQ (ppm)
1C 0.07 0.20
NPOC 0.09 0.20
Elemental carbon (EC) and organic carbon (OC) will be determined on the solids by ARCADIS using a
Sunset Laboratory Carbon Aerosol Analysis Lab Instrument in EPA RTP Laboratory E-581 A. This method is
defined in NIOSH Method 5040 (CDC 2003). This equipment uses a furnace to heat the sample and
combust the carbon to carbon dioxide. The carbon dioxide is reduced to methane and a FID is used to
quantify the carbon emitted as the sample is heated from ambient to 870 °C over four heating steps.
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Samples are prepared by weighing 3 grams of the CCR into a 500 ml Nalgene high-density polyethylene
bottle. A 37 mm tarred pre-baked quartz filter is loaded into a 2.5 |jm participate sampler and attached to the
bottle. The particulate sampler is connected to a vacuum source and a rotometerto control the flow at 4
liters per minute. The CCR material is aspirated onto the quartz filter for 5 minutes and the filter is reweighed
to determine the mass loading. Duplicate filters are prepared for each material. Three analyses are
performed on each filter. Blank filters are provided to determine background levels.
5.2.2 Mercury by Thermal Decomposition and Cold Vapor Atomic Adsorption (TD-CVAA) Method 7473
As part of the baseline characterization, mercury analysis of the solid materials will be carried out by
ARCADIS using a thermal decomposition cold vapor atomic adsorption (TC/CVAA) according the EPA SW-
846 Method 7473 (EPA 1998).
The Lumex RA-915+ Mercury Analyzer is a portable instrument capable of measuring mercury
concentrations in air, liquids, and solids. Developed for use by the Russian Navy to detect elemental
mercury leaks on submarines (mercury is used as ballast), the analyzer is capable of measuring 1 ng/m3.
The instrument contains an internal sample pump, multi-pass optical cell and Zeeman Effect atomic
adsorption detector tuned to a wavelength of 253.7 nm for the detection of mercury. The Zeeman effect
atomic adsorption (AA) detector modulates the frequency of the source to eliminate matrix effects from air
samples and enhance the detector sensitivity for mercury. An optional RP-91C high temperature (>750 °C)
furnace can be used to convert any mercury species to elemental mercury for post combustion detection of
total mercury in the solids. Since the detector can only measure elemental mercury directly, this technique is
based on the thermal decomposition properties of mercury, as only elemental mercury can exist at these
high temperatures. Under high temperatures, any oxidized mercury compounds are converted to elemental
mercury.
To perform a mercury analysis on a solid sample, the solid of known mass is weighed into a quartz or
stainless steel combustion boat. The combustion boat is then inserted into the furnace combustion chamber
and as the elemental mercury is evolved from the sample, the detector measures the mass of mercury. The
mass of mercury is directly proportional to the area under the peak, similar to the quantitation principle used
in gas chromatography. By dividing the mass of mercury by the mass of sample introduced to the
instrument, a mercury concentration can be derived. For wet samples, a moisture measurement of the solid
must be determined to correct the mercury content to a dry basis.
5.2.3 Other Metals (ICP)
Test America Laboratories in Savannah, GA, will analyze a sample of the raw fly ash for the metal species
total content using an Agilent ICP-MS with octopole reaction system (ORS). Vanderbilt University
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(Department of Civil and Environmental Engineering) will analyze the metals content of the leachates using
a Varian inductively couple plasma optical emission spectroscopy (ICP-OES).
Test America will conduct their total metal analyzes on an ICP-MS using EPA SW-846 Method 6020A (EPA
2007d). Metals and estimated instrument detection limits are listed in the method. The ICP will be profiled
and calibrated for the target compounds and specific instrument detection limits will be determined. Mixed
calibration standards will be prepared at least 5 levels. Each target compound will also be analyzed
separately to determine possible spectral interference or the presence of impurities. Two types of blanks will
be run with each batch of samples. A calibration blank is used to establish the analytical curve and the
method blank is used to identify possible contamination from varying amounts of the acids used in the
sample processing. Additional daily QC checks include an Initial Calibration Verification (ICV) and a
Continuing Calibration Verification (CCV). The ICV is prepared by combining target elements from a
standard source different than that of the calibration standard and at a concentration within the linear
working range of the instrument. The CCV is prepared in the same acid matrix using the same standards
used for calibration at a concentration near the mid-point of the calibration curve. A calibration blank and a
CCV or ICV are analyzed after every tenth sample and at the end of each batch of samples. The CCV and
ICV results must verify that the instrument is within 10% of the initial calibration with an RSD < 5% from
replicate integrations. Procedures to incorporate the analysis of a MS/MSD for these CCR samples will be
evaluated.
Vanderbilt University (Department of Civil and Environmental Engineering) will also conduct ICP-MS
analyses on the reference laboratory leaching test eluates. This will provide a statistical assessment of
precision for constituents that are not analyzed for in eluates by the participant laboratories. This will provide
precision (intralaboratory, by ICP-MS and ICP-OES) for all elements of concern and reproducibility
(interlaboratory, by ICP-OES) fora representative set of constituents. Inferences may be possible
concerning the interlaboratory reproducibility for other elements, depending on the relative contributions to
variance, between intralaboratory and interlaboratory effects.
A Perkin Elmer model ELAN DRC II will be used in both standard and dynamic reaction chamber (DRC)
modes. Standard analysis mode will be used for all analytes except for As and Se, which will be run in DRC
mode with 0.5 mL/min of oxygen as the reaction gas. Seven-point standard curves will be used for an
analytical range between approximately 0.5 ug/L and 500 ug/L and completed before each analysis.
Analytical blanks and analytical check standards at approximately 50 ug/L will be run every 10 to 20
samples and are required to be within 15% of the specified value. Samples for analysis will be diluted
gravimetrically to within the targeted analytical range using 1% v/v Optima grade nitric acid (Fisher
Scientific). Initially, analyses for 10:1 dilutions will be performed to minimize total dissolved loading to the
instrument. Additional dilutions at 100:1 and 1000:1 will be analyzed if the calibration range is exceeded with
the 10:1 dilution. 50 uL of a 10 mg/L internal standard consisting of indium (In) (for mass range below 150)
and bismuth (Bi) (for mass range over 150) will be added to 10 mL of sample aliquot prior to analysis.
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Analytical matrix spikes will be completed for one of each of the replicate eluates from Method 1313. For
each analytical matrix spike, a volume between 10 |jl_ and 100 |jl_ of a 10 mg/L standard solution will be
added to 10 ml of sample aliquot.
ICP-OES Analyses
ICP-OES analyses of aqueous samples from laboratory leaching tests will be carried out at Vanderbilt
University (Department of Civil and Environmental Engineering) using a Varian ICP Model 720-ES. Five-
point standard curves will be used for an analytical range between approximately 0.1 mg/L and 25 mg/L for
trace metals. Seven-point standard curves will be used for an analytical range between approximately 0.1
mg/L and 500 mg/L for minerals. Analytical blanks and analytical check standards at approximately 0.5 mg/L
will be run every 10 to 20 samples and are required to be within 15% of the specified value. Initially,
analyses will be performed on undiluted samples to minimize total dissolved loading to the instrument.
Samples for analysis will be diluted gravimetrically to within the targeted analytical range using 1 % v/v
Optima grade nitric acid (Fisher Scientific) if the maximum calibration is exceeded. Yttrium at 10 mg/L will be
used as the internal standard. Analytical matrix spikes will be completed for three test positions from one of
the replicate eluates from Method 1313. For each analytical matrix spike, a volume of 500 uL of a 10 mg/L
standard solution will be added to 5 mL of sample aliquot.
Table 5-2 provides the element analyzed, method detection limit (MDL), and minimum level of quantification
(ML). Analyte concentrations measured that are less than the ML and greater than the MDL are reported as
estimated value using the instrument response.
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Table 5-2. Method Detection Limits (MDLs) and Minimum Level of Quantification (ML) for ICP-OES Analysis on
Liquid Samples*
Symbol
Al
Sb
As
Ba
Be
B
Cd
Ca
Cr
Co
Cu
Fe
Pb
Li
Mg
Mn
Mo
Ni
K
P
Se
Si
Ag
Na
Sr
S
Tl
Sn
Ti
V
Zn
Zr
Units
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
MDL
1.00
8.00
15.0
1.00
5.00
1.00
6.00
3.50
1.00
1.00
4.1
2.90
7.00
6.00
1.00
3.60
1.00
2.20
1.50
6.2
17.0
2.80
18.00
3.50
1.00
8.30
5.00
17.0
6.40
1.30
2.50
2.70
ML
3.18
25.4
47.7
3.18
15.9
3.18
19.1
11.1
3.18
3.18
13.0
9.22
22.3
19.1
3.18
11.4
3.18
7.00
4.77
19.7
54.1
8.90
57.2
11.1
3.18
26.4
15.9
54.1
20.3
4.13
7.95
8.59
* All elements indicated in Table 5.2 will be analyzed, however, only elements indicated in bold are reported as part of the
leaching studies.
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5.2.4 X-Ray Fluorescence (XRF)
X-Ray Fluorescence Spectrometry is used in the USEPA RTP, NC laboratories to analyze a sample of the
raw fly ash for the determination of total content for the major elements. A Philips model PW2404
wavelength dispersive instrument, equipped with a PW2540 VRC sample changer, is used for these
analyses. The manufacturer's software suite, "SuperQ", is used to operate the instrument, collect the data,
and perform quantification.
The instrument was calibrated using a manufacturer-supplied set of calibration standards at the time of
installation of the software plus a new X-ray tube. On a monthly basis, manufacturer-supplied drift correction
standards are used to create an updated drift correction factor for each potential analytical line. On a
monthly basis, a dedicated suite of QC samples are analyzed before and after the drift correction procedure.
This data is used to update and maintain the instrument's QC charts. The SOP for this QC procedure (SOP
No. 5003.3; "Procedure for the Philips PW2404 XRF Monthly Drift Correction, Quality Control Stability
Check, QC Chart Update, and Database Backup.") is maintained in a 3-ring binder located at the control
module for the spectrometer, along with all other operational SOPs. Any deviations from these QC
parameters will be documented to the EPA WAM.
The software suite's "Measure and Analyze" program collects and stores the sample data. This program has
two basic modes of operation, "scan" and "channels". The scan mode is used to collect the bulk of the data.
It operates in a stepwise scanning mode and uses the manufacturer supplied "IQ+" program to define
operating parameters. IQ+ scans the available wavelength range using a series of 10 sub-scans that vary in
terms of detector, radiant power, collimator crystal, and wavelength. While the instrument incorporates a
sample rotation capability, this is not used by IQ+ since the time spent at any one wavelength is only a
fraction of the pellet rotation time.
The channel mode is typically reserved for trace work. In this mode, the instrument moves to a specific
wavelength and goniometer position and collects data for defined periods of time. These data collection
periods are typically long enough to make use of the sample rotation function worth while. Other instrument
operation parameters, such as tube power and crystal, are taken from the scan function parameters. The
data collected in the channel mode is then incorporated into the sample's data file. The intent is to improve
detection limits for certain trace elements that are often of interest at a small cost in analytical time.
Quantification is performed post-data collection using the program, "IQ+". IQ+ is a "first principles"
quantification program that includes complex calculations to account for a wide variety of sample-specific
parameters. For this reason, sample-specific calibrations are not necessary. This program calculates both
peak heights and baseline values. The difference is then used, after adjustment by drift correction factors,
for elemental quantification versus the calibration data. Interelement effects are possible and the software
includes a library of such parameters. Data from secondary lines may be used for quantification where
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interelement effects are significant or the primary peak is overloading the DAQ. Where the difference
between the calculated peak height and baseline are of low quality, the program will not identify a peak and
will not report results. IQ+ permits the inclusion of data from other sources by manual entry. Carbon is an
example of this for these samples. Entry of other source data for elements indeterminable by XRF improves
the mass balance.
5.2.5 XRF Detection Limits
Table 5-3 presents detection limit data in two forms, which are not mutually exclusive. The reporting limit is
built into the software and reflects the manufacturer's willingness to report low-level data. Data listed under
"detection limit" are based upon the short-term reproducibility of replicate analyses and are sample matrix
specific. These calculations are likely to report higher detection limits for macro elements than what would
be calculated where the same element is present at trace levels. In this data set, calcium is a likely example
of this.
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Table 5-3. XRF Reporting and Detection Limits
Analyte Reporting Limit, (jg/g
Al
As
Ba
Br
Ca
Cd
Ce
Cl
Co
Cr
Cu
F
Fe
Ga
Ge
K
La
Mg
Mn
Mo
Na
Nb
Ni
Pb
Px
Rb
Sc
Se
Si
Sr
Sx
Ti
V
W
Y
Zn
Zr
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
Detection Limit %, 2a (wt. %)
0.016
0.038
0.0084
0.02
0.1
0.064
0.022
0.0046
0.0024
0.0028
0.0014
0.082
0.034
0.0016
0.0014
0.0048
0.0054
0.01
0.0032
0.0026
0.0076
0.0018
0.0048
0.0034
0.004
0.0016
0.0016
0.0018
0.092
0.0016
0.05
0.003
0.0038
0.0036
0.0018
0.0014
0.0024
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5.2.6 Radionuclide Testing of CCRs using Ge-Detector
Fly ash, gypsum, and other CCRs were collected and assessed to determine their specific activity [Bq/kg].
Samples were taken from a variety of different sources to compare trends in radioactivity, such as that of
bituminous and sub-bituminous CCRs. Samples will be analyzed using two High Purity Germanium (HPGe)
photon detector with low energy detection capabilities, in a common geometry.
Detector 1: Ortec model GMX35P4 high purity germanium coaxial detector, 55.6 mm diameter, 79 mm
length, 0.5 mm beryllium window, rated resolution 2.1 keV at 1332 keV, 31.5% relative efficiency at 1332
keV, GammaVision version 6.01 analytical software, 2003.
Detector 2: Canberra model BE3830 high purity germanium coaxial detector, 70 mm diameter, 30 mm
length, 0.6 mm beryllium window, rated resolution 1.6 keV at 1332 keV, 27.9% relative efficiency at 1332
keV, Genie 2000 version 32.1 analytical software, 2009.
Project samples of fly ash and other coal combustion residues are received as dry materials and will be
placed in plastic vials of approximately 250 ml and sealed to allow ingrowth of radon gas into equilibrium
with its parent nuclide, as peaks from the radon progeny are key to identification of the parent nuclide.
Sample containers are placed on the coaxial germanium photon detector systems and counted with shields
closed. Traceable calibration standards in the same geometry had previously been counted on these
systems to establish system calibrations. Samples are counted for times determined to be adequate to
attain reasonable Minimum Detectable Activity (MDA) levels, 8 hours for fly ash and 12 hours for other
residues. Results are given as values of activity per unit mass of sample, with associated uncertainties and
MDA values. As MDAs are derived by pre-established regions on the gamma spectroscopy spectra which
varies sample by sample, MDAs for a given nuclide on a particular system are slightly different for each
sample but are generally consistent on a given detector for a stated geometry and count time. Fly ash
samples are counted for 8 hrs, while all other samples are counted for 12 hr periods. The background
characteristics of a number of photopeaks essential to the detection of U-238 and Th-232 decay series were
determined over several weeks, and MDA levels were determined for each of the relevant regions.
The following photopeaks are used to determine activity in the U-238 decay series:
186keV(Ra-226)
295keV(Pb-214)
352keV(Pb-214)
609keV(Bi-214)
1754keV(Bi-214)
The following photopeaks are used to determine activity in the Th-232 decay series:
583 keV (TI-208)
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911 keV (Ac-228)
Other photopeaks are evaluated regularly as naturally occurring peaks:
511 keV (various)
662keV(Cs-137)
1460keV(K-40)
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6. Quality Assurance/Quality Control
6.1 Data Quality Indicator Goals
Data quality indicator (DQI) goals for critical measurements in terms of accuracy, precision and
completeness are shown in Table 6-1. In addition, critical data quality indicator goals are inclusion of at least
6 independent laboratories in addition to the referee laboratory and 3 materials for each leaching test
method evaluated.
These goals are based on past performance and will be assessed as the project is completed. Any
deviations from these stated DQIs will be documented to the EPA WAM.
Table 6-1. Data Quality Indicator Goals
Measurement
ICP-OES constituents (e.g., As, B, Ba,
Ca, Co, Cr, Mo, Sb, Se, V)
Concentration
pH, conductivity
Moisture
Hg
XRF
ICP/MS
Method
ICP-OES
Electrode
ASTM D2216-05
7470
SOP No. 5003.3
6020
Accuracy
±10%
±2%
NA
±10%
±2%
±10%
Precision
±10%
±2%
±10%
±10%
±10%
±10%
Completeness
>90%
100%
100%
90%
100%
90%
NA= not applicable.
For the ICP-OES, accuracy is assessed using calibration verifications and laboratory control samples.
Precision is assessed by replicate measurements. For the pH measurements, a standard of known pH will
be checked prior to taking sample measurements. Precision is assessed by replicate measurements. There
is not a standard reference material for moisture accuracy. Precision will again be assessed by replicate
measurements.
In addition to the DQI goals shown in Table 6-1, homogeneity of the reference material will be considered
acceptable if the following criteria are met by XRF. Major constituents are elements found at concentrations
of more than 1%.
• RSD<10% for major constituents (greater than 1 % total content)
• RSD<20% for minor constituents (greater than 0.1 to 1 % total content)
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• RSD<50% for trace constituents (less than 0.1 % total content.
Accuracy will be determined by calculating the percent bias from a known standard. Precision will be
calculated as relative percent difference (RPD) between duplicate values and relative standard deviation
(RSD) for parameters that have more than two replicates. Completeness is defined as the percentage of
measurements that meet DQI goals of the total number measurements taken.
6.2 QC Sample Types
Types of QC samples used in this project will include blanks, spiked samples, replicates, and mass balance
tests on the leaching reference material. For physical characterization testing, duplicate samples of the
CCR, leaching reference material will be processed through each analysis. The initial criteria will be
determined on the screening data (the six replicates conducted by the ARCADIS referee laboratory) through
a statistical review. This is done by looking at the leaching curves and bounding the data by the 5th and 95th
percentiles as predicted by linear interpolations. The individual criteria will be determined by OCRC, ORD,
Vanderbilt, and ARCADIS when they conduct this same statistical review on the data collected by each
laboratory.. As recommended by ORCR, each lab will be asked to have their extractions performed by a
single operator on a single instrument in a single batch to minimize variability inherent to the determinative
method; all leaching test eluates will be analyzed by ICP-OES for selected constituents by Vanderbilt to
minimize variability associated with the metals analysis step since the focus of this study is on the leaching
test methods not chemical analysis.
The EPA Metrology laboratory completes periodic and requested calibrations as described in SOPs and
standard methods for equipment such as balances.
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7. Data Reduction, Validation, and Reporting
7.1 Data Analysis
Interlaboratory comparisons of each method and material will be based on sets of analytes that are (i)
representative of the range of characteristic behaviors anticipated for the material being tested and the test
method being evaluated, and (ii) either analyzed as part of the laboratory procedure (e.g., pH) or analyzed
as part of a single ICP-OES analytical method. Thus, it is anticipated that although some analytes will be
common amongst different test materials being used in the interlaboratory comparisons, the complete set of
analytes will likely be different for each test material because of different characteristic behaviors (e.g., as a
function of pH and LS) and leaching concentrations relative to analytical detection limits. At least 6 analytes
will be used as the basis for evaluation for each test material with priority given to analytes that are of
regulatory interest and those that are major constituents of each test material. An initial set of analytes for
each test material will be selected based on prior knowledge of the type of each test material selected (e.g.,
coal fly ash, cement stabilized waste, blast furnace slag). The final set of analytes for each test material will
be selected based on the test method results obtained by the referee laboratory with the concurrence of the
project team, including the EPA QA Representative, and prior to beginning analysis of samples from the
participant laboratories.
The basis of the interlaboratory comparisons will be the dependent variables that are intended to be the
information derived from each test procedure using the set of constituents selected for the test material
being tested. The set of dependent variables for each test method are specified in the sub-sections that
follow. The variance of the following additional analytes will be evaluated as reported by the referee
laboratory and each participant laboratory to provide insights into material variability and methods
implementation: moisture content, eluate pH, eluate conductivity.
Method 1313
The primary information to be derived from this test method is (i) the pH dependent leaching behavior of
constituents of interest, and (ii) the pH titration curve of the material. The dependent variables that will serve
as the basis for evaluation will be (i) material natural pH (as defined in the test method), (ii) eluate analyte
concentration as determined forthe method target pH values (i.e., 2.0, 4.0, 5.5, 7.0, 8.0, 9.0,12.0,13.0,
natural pH, 10.5), and (iii) equivalents of acid or base required to be added to achieve the method target pH
values (i.e., the pH titration curve). Variation in the actual pH about the target pH value of each eluate but
within the tolerances specified in the test method will require interpolation or extrapolation of measured
analyte concentration values to the precise target value. The initial method will be linear interpolation of the
analyte concentration to the target pH value based on the log transform of the analyte concentration from the
eluates having the nearest pH value greater than and less than the target value. If this method is found to
provide poor representation of the overall pH dependent behavior of the analyte, then other interpolation
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methods such as cubic splines or fifth-order polynomial fitting will be considered. The decision on the
interpolation method will be based on the results obtained from the referee laboratory, prior to initiating
evaluation of data from the participant laboratories. The same approach will be used for interpolation
required to determine the equivalents of acid or base needed to be added to obtain the target eluate pH
values. An ANOVA statistical evaluation (see below for ANOVA specification) will be used to evaluate the
contributions to variance and method precision for the discrete values of the dependent variables at each
target value of the appropriate independent variable.
An alternate method of data interpretation of the dependent variables will be based on the functional
relationship of the dependent variable to the specified independent variable (i.e., analyte concentration as a
function of pH or eluate pH as a function of acid or base addition). Thus, potential functional relationships
(e.g., fifth order polynomials) will be regressed to the data set to provide a defined function to represent the
overall result for each analyte. The contributions to variance in the resulting function then would serve as the
basis for evaluating the method precision (see below for specification of statistical analysis of functional
relationships).
Method 1314
The primary information to be derived from this test method is (i) the eluate pH and analyte concentration as
a function of LS, and (ii) the cumulative release (i.e., mg of analyte per kg of material leached) of each
analyte as a function of LS. The analyte concentration measured for eluates obtained at cumulative LS
values of 0.2 and 0.5 can also be considered estimates of pore water composition and compared with
similar estimates obtained from Method 1316. This interlaboratory comparison will be based on a complete
characterization sampling scheme (Option A as specified in section 12.5.1.1 of the test method). The
dependent variables that will serve as the basis for evaluation will be (i) eluate pH as determined at the
method target LS values (i.e., 0.2, 0.5,1.0,1.5, 2.0, 4.5, 5.0, 9.5, 10.0), (ii) eluate analyte concentration as
determined at the method target LS values, and (iii) cumulative analyte release as determined at the method
target LS values. Variation in the actual LS about the target LS value of each eluate but within the tolerances
specified in the test method will require interpolation or extrapolation of measured analyte concentration
values to the precise target value. The initial method of interpolation considered will be linear interpolation of
the analyte concentration to the target LS value based on the log transform of the analyte concentration from
the eluates having the nearest LS value greater than and less than the target value. If this method is found
to provide poor representation of the overall LS dependent behavior of the analyte, then other interpolation
methods such as cubic splines or exponential decay or error function curves will be considered. A common
approach will be used for interpolation of eluate pH to the target LS values. The decision on the interpolation
method to be used will be based on the results obtained from the referee laboratory and prior to initiating
evaluation of data from the participant laboratories. An ANOVA statistical evaluation (see below for ANOVA
specification) will be used to evaluate the contributions to variance and method precision for the discrete
values of the dependent variables at each target value of the appropriate independent variable.
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An alternate method of data interpretation of the dependent variables will be based on the functional
relationship of the dependent variable to the specified independent variable (i.e., analyte concentration as a
function of LS or cumulative release as a function of LS). Thus, potential functional relationships (e.g.,
exponential decay, error function or polynomial functions) will be regressed to the data set to provide a
defined function to represent the overall result for each analyte. The contributions to variance in the resulting
function then would serve as the basis for evaluating the method precision (see below for specification of
statistical analysis of functional relationships).
Method 1315
The primary information to be derived from this test method is (i) the eluate pH and analyte flux as a function
of time, (ii) the cumulative release (i.e., mg of analyte perm2 of material leached based on the external
geometric surface area of exposed faces) of each analyte as a function of time, and (iii) the mean observed
diffusivity2 of each analyte when diffusion controlled release is indicated (see Section 13.2 of Method 1315).
The dependent variables that will serve as the basis for evaluation will be (i) eluate pH as determined at
each method leaching interval (i.e., cumulative leaching times of 0.08,1.0, 2.0, 7.0,14.0, 28.0, 42.0, 49.0
and 63.0 days; see Table 1 of Method 1315), (ii) eluate analyte concentration as determined for each
method leaching interval, (iii) cumulative analyte release for each leaching interval, (iv) analyte mean flux
over each leaching interval, and (v) observed diffusivity for each analyte when applicable. Interpolation for
determined concentrations and derived values of cumulative release and flux should not be necessary as
long as leaching intervals are maintained within tolerances specified in the test method. An analysis of
variance (ANOVA) statistical evaluation (see below) will be used to evaluate the contributions to variance
and method precision for the discrete values of the dependent variables at each target value of the
appropriate independent variable.
Method 1316
The primary information to be derived from this test method is (i) the eluate pH and analyte concentration as
a function of LS, and (ii) the release (i.e., mg of analyte per kg of material leached) of each analyte as a
function of LS. The dependent variables that will serve as the basis for evaluation will be (i) eluate pH as
determined at the method target LS values (i.e., 0.5,1.0, 2.0, 5.0,10.0), (ii) eluate analyte concentration as
determined at the method target LS values, (iii) analyte release as determined at the method target LS
values, and (iv) an estimate of analyte concentration at LS value of 0.2 which can also be compared with the
2 There will be up to 9 individual observations of observed diffusivity (one for each leaching interval) from each replicate
of each application of Method 1315 for each specified analyte. Thus, a mean and standard deviation will be reported for
each observed diffusivity value.
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analyte concentration at LS value of 0.2 from Method 1314. Discrete values of each analyte are measured at
each LS value and therefore interpolation will not be needed; however extrapolation of the functional
relationship of analyte concentration as a function of LS will be needed to estimate the concentration at LS
of 0.2. Extrapolation of analyte concentration as a function of LS to LS of 0.2 will be accomplished by
regressing a functional relationship (e.g., linear, exponential or polynomial) to measured analyte
concentrations in eluates from other LS values. Different functional relationships may be necessary for
different analytes. The decision on the interpolation method to be used will be based on the results obtained
from the referee laboratory and prior to initiating evaluation of data from the participant laboratories. An
ANOVA statistical evaluation (see below) will be used to evaluate the contributions to variance and method
precision for the discrete values of the dependent variables at each target value of the appropriate
independent variable.
Statistical Analysis of Variance
The basic method of data analysis is provided as follows in the context of Method 1313 fora single analyte
and a single material. The same approach will be used for Methods 1314, 1315 and 1316, as well as for
multiple materials. It assumes that the interpolation to target measurement values (i.e., target pH values for
Method 1313 and target LS values for Method 1314) has been performed and determined to be acceptable
as described in the section titled "Outlier Identification and Model Assumption Checking." In the definitions
given as follows, the convention is that a "measurement" refers to a log-transformed analyte concentration or
other dependent variable value:
Y..k =kth measurement at the fh target pH for the ith lab,
where
/' = 1,...,M (M =numberof labs in the study, where the reference lab is the Mth),
j = 1,...,9 (the number of pH levels), and
k = 1,2,3 for participant labs 1 through M -l;k = 1,...,6 for the reference lab M
The statistical model underlying the analysis of variance is a mixed-effects model with fixed effects for pH
level, and random effects for labs and lab-by-pH interactions. Specifically,
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where
/u and aj are fixed effects, to model the overall mean response at different pH levels,
/? and Yi; are random effects that model differences among labs, and
si j k is a random error term that models variation among replicates within a particular lab and pH
combination.
The standard assumptions for the model are that /?., yt j and si; k are independent normal random
variables with zero means and variances
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methods of interpolation, say via linear, polynomial, and spline curve fitting. If the results are sensitive to the
calibration method, then it is anticipated that a spline method will supplant the proposed linear interpolation.
The interpolation also introduces a secondary source of departure from the basic analysis of variance model
assumptions in the form of dependence between the interpolated measurements. This can be assessed
using advanced modeling features of Proc Mixed in SAS.
Outlier Identification. Possible outliers will be identified using standard methods of plotting residuals and
comparing laboratory-specific summary measures of variability. It should be emphasized that in a study of
this nature (interlaboratory study) there are multiple notions of what constitutes an "outlier" and these also
manifest themselves as other forms of model violations. For example, the random error term in the statistical
model is usually assumed to have the same variance at all pH levels where it is known that the variance is
different at different pH levels (and is also assumed to be the same at all laboratories). This is directly
checked by comparing between pH and within lab sample variances which can also be accomplished using
advanced features of SAS's Proc Mixed procedure. A lab with a much greater variance than other those of
other labs is a candidate for being declared an outlying lab. Regardless of how alleged outliers are identified,
their impact on the statistical results is most definitively assessed by direct comparison of statistical results
obtained via separate analyses using the full data set and the "cleaned" data set (with outliers removed).
More Advanced Modeling Options. For Method 1313, we are interpolating to the target pH values to have a
consistent comparison of measured concentrations in eluates. Although this approach appears to work quite
well for the fly ash data obtained so far, this may not prove to be the case with future materials. If this occurs,
the approach would be changed to compare "curves" rather than individual values, thus changing to
functional analysis (where "functional" refers to the types of curve fits used, such as polynomials)._The basic
idea is to fit a smooth curve to the analyte concentration as a function of pH (using the realized pH values)
and then to compare the curves so obtained within labs (to assess repeatability) and among labs (to assess
reproducibility). The basic methods and techniques of functional data analysis are described in the seminal
book by Ramsay and Silverman (1997).
7.2 Chemical (ICP, XRF, AE-OES, OC/EC) and Physical (Moisture) Characterization
These data are reduced and reports are generated automatically by the instrument software or through
spreadsheets. The primary analyst will review 100% of the report for completeness and to ensure that
quality control checks meet established criteria. If QC checks do not meet acceptance criteria, sample
analysis must be repeated. A secondary review will be performed by the Inorganic Laboratory Manager and
Vanderbilt University to validate the analytical report. If appropriate, certain chemical characterization data
will be compared to the XRF analyses. In addition, the ARCADIS QA Officer will review at least 10% of the
raw data generated by ARCADIS for completeness. Analytical data will be summarized in periodic reports to
the ARCADIS WAL. The procedures for reduction, validation and reporting of the leaching experiments
(Task III) are outlined in the methods (http://www.vanderbilt.edu/leachinq/downloads.html). ARCADIS WAL
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is responsible for the implementation of these procedures. ARCADIS and Vanderbilt University will be
responsible for publishing results and reports. QA/QC activities will be mentioned in any published materials.
A data quality report will be provided in the final report of this investigation.
Data generated for the leachate analysis and total composition are entered into a standard Excel
spreadsheet to ease uploading into the Vanderbilt metals database from the ICP-MS and other analyses.
This data along with QA/QC information can be viewed using the "LeachXS Lite" software program
developed by Vanderbilt University and the Energy Research Centre of the Netherlands. This software tool
will allow users to view the metals leaching information based on sample type, facility configuration, or CCR
coal type, or validation laboratory. This data viewer and database program will be available to the public on-
line when complete. In addition, all data generated from the interlaboratory validation study will be archived
by APPCD along with other project documentation.
7.3 Radionuclide Characterization
A Quality Assurance (QA) program involving verification of energy and Full Width at Half Maximum (FWHM)
for several key photopeaks will be implemented. The calibration standard used to establish the system
efficiency as a function of energy will be counted for 5 minutes daily. The photopeak energy, full width at
half-maximum (FWHM) and net peak area for Cs-137 (662 keV) will be measured and plotted, with the
FWHM for the 1332 keV peak of Co-60, for both detector systems. Any value occurring outside of 3
standard deviations of the mean (established in a preliminary study of about 20 measurements) must be
immediately recounted. If the recount values are within 3 standard deviations, the system may be used for
sample counting; if not an investigation into the detector reliability must be performed and a diagnosis and
correction of any problems carried out before samples are counted on this system.
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8. Assessments
Assessments and audits are an integral part of a quality system. This project is assigned a QA Category III
and, while desirable, does not require a planned technical systems audit (ISA). The ARCADIS QA Officer
may conduct a ISA at the request of either the EPA WAM or the ARCADIS WAL. Internal assessments will
be performed by project personnel to ensure acquired data meet data quality indicator goals established in
Section 6.
There are currently no planned performance evaluation audits but Table 8-1 lists the measurement
parameters and expected ranges should EPA determine a PEA should be provided.
Table 8-1. PEA Parameters and Ranges
Analyte or Measurement
As, B,
Ba, Ca, Co, Cr, Mo, Sb, Se, V
Hg
PH
Method
ICP-OES/3052/6020A
7470A
Electrode
Expected Range
1-100 |jg/ml_
0.25to10ug/L
0-14
The ARCADIS QA Officer will perform an internal data quality audit on at least 10% of the reported data.
Reported results will be verified by performing calculations using raw data and information recorded in
laboratory notebooks.
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9. References
ASTM, 1988. Standard Practice for Conducting an Interlaboratory Study to Determine the Precision of a
Test Method, Designation: E 691-87 American Society for Testing and Materials, 1988.
ASTM, 2005. Standard test methods for laboratory determination of water (moisture) content of soil and rock
by mass, Method D 2216-05, American Society for Testing and Materials, 2005
ASTM, 2008. Standard test methods for loss on ignition (LOI) of solid combustion residues, Method D 7348-
08, American Society for Testing and Materials, 2008.
ASTM, 2009. Standard test methods for carbon black—total and external surface area by nitrogen
adsorption, Method D 6556-09, American Society for Testing and Materials, 2009.
CDC 2003. Diesel particulate matter (as elemental carbon), Method 5040, Centers for Disease Control,
NIOSH Manual of Analytical Methods (NMAM), Fourth Edition, 2003.
EPA, 1992. Method 1311 "Toxicity Characteristic Leaching Procedure". Test Methods for Evaluating Solid
Waste, Physical/Chemical Methods (SW-846) U.S. Environmental Protection Agency, 1992.
EPA, 1994. Method 1312 "Synthetic Precipitation Leaching Procedure". Test Methods for Evaluating Solid
Waste, Physical/Chemical Methods (SW-846) U.S. Environmental Protection Agency, 1994.
EPA, 1996a. Method 3052 "Microwave Assisted Acid Digestion of Siliceous and Organically Based
Matrices". Test Methods for Evaluating Solid Waste, Physical/Chemical Methods (SW-846) U.S.
Environmental Protection Agency, 1996.
EPA, 1998. Method 7473, "Mercury in Solids and Solutions by Thermal Decomposition, Amalgamation, and
Atomic Absorption Spectrophotometry." Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods (SW-846). U.S. Environmental Protection Agency, 1998.
EPA, 2002a. Characterization and Management of Residues from Coal-Fired Power Plants, Interim Report.
EPA-600/R-02, 083, U.S. Environmental Protection Agency, December 2002.
EPA, 2002b. Reply to comments on EPA/OSWs Proposed Approach to Environmental Assessment of
CCRs. Discussed March 5, 2002.
EPA, 2006a. Sanchez, F., R. Keeney, D. S. Kosson, and R. Delapp, 2006. Characterization of Mercury-
Enriched Coal Combustion Residues from Electric Utilities Using Enhanced Sorbents for Mercury Control,
C-55
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
Project No.: RN990272.0007
Revision: 0
Date: November 2011
Page: 47
EPA-600/R-06/008. Prepared for the U.S. Environmental Protection Agency-Air Pollution Prevention and
Control Division, Contract No. EP-C-04-023, Work Assignment 1-31, February 2006.
www.epa.gov/nrmrl/pubs/600r06008/600r06008.pdf (Accessed November 12, 2009)
EPA, 2006b. Standard Operating Procedure for the Determination of Hexavalent Chromium in Ambient Air
Analyzed by Ion Chromatography (1C). December 2006. Internet address:
http://www.epa.gov/ttn/amtic/airtox.html (Accessed November 12, 2009)
EPA, 2007a. 2005 Urban Air Toxics Monitoring Program (UATMP) - Hexavalent Chromium, U.S.
Environmental Protection Agency, EPA-454/R-07-005, February 2007.
EPA, 2007b. Method 9056A "Determination of Inorganic Anions by Ion Chromatography". Test Methods for
Evaluating Solid Waste, Physical/Chemical Methods (SW-846), U.S. Environmental Protection Agency,
February 2007.
EPA, 2007c. Method 601OC "Inductively Coupled Plasma-Atomic Emission Spectrometry". Test Methods for
Evaluating Solid Waste, Physical/Chemical Methods (SW-846), U.S. Environmental Protection Agency,
February 2007.
EPA, 2007d. Method 6020A "Inductively Coupled Mass Spectrometry". Test Methods for Evaluating Solid
Waste, Physical/Chemical Methods (SW-846), U.S. Environmental Protection Agency, February 2007.
EPA, 2008. Sanchez, F., R. Keeney, D. S. Kosson, and R. Delapp, 2006. Characterization of Mercury-
Enriched Coal Combustion Residues from Electric Utilities Using Wet Scrubbers for Multi-Pollutant Control,
EPA-600/R-08/077. Prepared for the U.S. Environmental Protection Agency-Air Pollution Prevention and
Control Division, Contract No. EP-C-04-023, Work Assignment 4-26, July 2008.
http://www.epa.gov/nrmrl/pubs/600r08077/600r08077.htm (Accessed October 18, 2011)
EPA 2009, Kosson, D., F. Sanchez, P. Kariher, L.H. Turner, R. Delapp and P. Seignette. Characterization of
Coal Combustion Residues from Electric Utilities - Leaching and Characterization Data. U.S. Environmental
Protection Agency, EPA-600/R-09/151, December 2009.
EPA. Guidance for Methods Development and Validation for the RCRA Program.
http://www.epa.gov/epawaste/hazard/testmethods/pdfs/methdev.pdf, accessed October 18, 2011.
Kosson, D.S., van derSloot, H.A., Sanchez, F. and Garrabrants, A.C., 2002a. An Integrated Framework for
Evaluating Leaching in Waste Management and Utilization of Secondary Materials. Environmental
Engineering Science 19(3):159-204, 2002.
C-56
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
Project No.: RN990272.0007
Revision: 0
Date: November 2011
Page: 48
Ramsay, J.O. and Silverman, B.W. (1997). Functional Data Analysis. Springer-Verlag (New York).
van der Sloot, et al., 2010 (draft). Evaluation of Ruggedness Testing Needs for the Percolation Test, pH
Dependence Leaching Test and Monolith Leaching Tests based on Existing Information. The Energy
Research Centre of The Netherlands.
C-57
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
Appendix A
Laboratory Shipping Address
Name
Affiliation
Shipping Address
James M. Tinjum
University
of
Wisconsin-
Madison
James M. Tinjum, P.E., Ph.D.
University of Wisconsin-Madison
Department of Civil and Environmental Engineering
2214 Engineering Hall
1415 Engineering Drive
Madison, Wl 53706
Mandi Richardson
URS Corp.
Mandi Richardson
URS Corporation
9400 Amberglen Blvd.
Austin, TX 78729
Jianmin Wang
Missouri
University
of Science
and
Technology
Jianmin Wang
Dept. of Civil, Architectural & Environmental Engineering
223 Butler Carlton Hall University of Missouri-Rolla
(UMR)
Rolla, MO 65409
Zuzana Bohrerova
The Ohio
State
University
Zuzana Bohrerova
The Ohio State University
470 Hitchcock Hall
2070 Neil Avenue
Columbus, OH 43210-1275
Catherine Mattus
DOE- Oak
Ridge
National
Laboratory
Catherine Mattus
Oak Ridge National Laboratory
P. OBox2008
1 Bethel Valley Road
Oak Ridge, TN 37831-6181
Eric Pierce
DOE-
Pacific
Northwest
National
Laboratory
Eric M. Pierce
790 6th Street
Richland, WA 99338
C-58
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
Charles Crawford
DOE-
Savannah
River
National
Laboratory
Charles L. Crawford
Savannah River National Laboratory
Bldg. 773-42A
Savannah River Site
Aiken, SC 29808
Needs to have an internal number attached to the box:
P0# OT0580
Hwidong Kim
University
of Florida
Hwidong Kim
220 Black Hall
Department of Environmental Engineering & Sciences
University of Florida
Gainesville, FL, 32611.
Johnny Mitchell
Test
America
(TVA)
Johnny Mitchell
TestAmerica Laboratories - Nashville
2960 Foster Creighton Drive
Nashville, TN 37204
Rosanne Delapp
Vanderbilt
University
Rosanne Delapp
Vanderbilt University
Jacobs Hall 149
400 24th Avenue South
Nashville, TN 37235
Prof. Dr. Rob N.J.
Comans
ECN
Dr. Rob N.J. Comans
ECN Biomass, Coal and Environmental Research
Energy research Centre of the Netherlands
Westerduinweg 3, NL-1755 LE PETTEN
Neatherlands
Ole Hjelmar
DHI
Ole Hjelmar
DHI
Urban & Industrial Dept.
Agern Alle 5
DK-2970 H0rsholm
Denmark
Jenet T. Hattaway
University
of North
Carolina
Charlotte
Civil & Environmental Engineering
University of North Carolina Charlotte
Cameron Bldg. Rm 267
9201 University City Blvd.
Charlotte, NC 28223-0002
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
PRELIMINARY VERSION of EPA METHOD 1313
Liquid-Solid Partitioning as a Function of Extract pH using Parallel Batch Extractions
-TM
LeachXS Lite Data Template - Version 1.1, January 2010
PROJECT/MATERIAL TITLE SHEET
PROJECT INFORMATION
Project Code
Project Sponsor
Project Description
Material Code
Material Replicate
Material Originator
Material Description
Test Method Lab
Contact
Analytical Lab
Contact
DATABASE INFORMATIOr
Name of Database
Material Code
Material Class
Material Subclass
SIGNATURES
Data Compiler:
Data Reviewer:
Approved by:
LeachXS™ Lite Upload:
Date Complete
Phone
Date Complete
Phone
J
Date:
Date:
Date:
Date:
Page 1
Draft Method 1313 Template Rev 0
C-60
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
COAL COMBUSTION RESIDUE CLASSIFICATIONS
PROJECT & MATERIAL CODES
Project Code
Material Code
Material Replicate
LeachXS Database Information
Auto-inserted from "Title Sheet"
Auto-inserted from "Title Sheet"
Auto-inserted from "Title Sheet"
Name of Database
Material Code
RESIDUE DESCRIPTION
CCR Category I
Auto-inserted from "Title Sheet"
Auto-inserted from "Title Sheet"
Fly Ash Type
Residue Handling
Citation \please specify
SOURCE DESCRIPTION
Coal Type |
Coal Region
Facility \please specify
Facility Description
PROCESS DESCRIPTION
Particulate Capture [
Scrubber Type [
FGD Scrubber Additive [
NOxControlF
SO3 ControlF
Hg Sorbent Injection [
C-61
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
PRE METHOD 1313 LeachXS Lite Data Template
MOISTURE CONTENT (WET BASIS) AND SOLIDS CONTENT INSTRUCTIONS
Step 1: Enter the project, material and replicate codes as well as the name of the technician
conducting the test.
Step 2: Measure and record the mass of an empty drying or suitable weighing dish as well as
the dish containing 5-10 g the "wet" sample. Record data and time of measurement. Place
dish and sample into over at 105±5 °C for a minimum of 24 hr.
Step 3: Remove dish and sample from oven and allow to cool to room temperature in a
desiccator. Measure and record the mass of the dish and dry sample. Place the dish and
sample back into the oven for at least another 24-hr period.
••I^H ^^H
Step 4: Repeat cooling and measurement procedure as shown in Step 3 until constant mass
of the dish and sample is accheived. Record this mass and the final date and time. Discard
the sample.
Step 5: Moisture and solids content are calculated automatically. Mean SC cell may be
linked to the solids content cells in Pre-Test data and Test Data sheets. Alternately, copy the
Mean SC cell value to these sheets.
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
PRE METHOD 1313 LeachXS Lite Data Template
MOISTURE CONTENT (WET BASIS) AND SOLIDS CONTENT INSTRUCTIONS
r Project
Material
Test Replicate
Code Description (optional)
Auto-inserted from "Title Sheet"
Auto-inserted from "Title Sheet"
Empty Dish [g]
Dish + Sample [g]
Dish + Dry Sample [g]
Check (Dish + Dry Sample) [g]
Moisture Content (MC) [g-water/g]
Solids Content (SC) [g-dry/g]
MOISTURE CONTENT (WET BASIS) AND SOLIDS CONTENT INSTRUCTIONS
Code Description (optional) Test conducted by:
Project
Material
Test Replicate
Auto-inserted from "Title Sheet"
Auto-inserted from "Title Sheet"
Dish-1 Dish-2
Dish-3
Empty Dish [g]
Dish + Sample [g]
Dish + Dry Sample [g]
Check (Dish + Dry Sample) [g]
Moisture Content (MC) [g-water/g]
Solids Content (SC) [g-dry/g]
MOISTURE CONTENT (WET BASIS) AND SOLIDS CONTENT INSTRUCTIONS
Code Description (optional) Test conducted by:
Project
Material
Test Replicate
Auto-inserted from "Title Sheet"
Auto-inserted from "Title Sheet"
Dish-1 Dish-2
Dish-3
Empty Dish [g]
Dish + Sample [g]
Dish + Dry Sample [g]
Check (Dish + Dry Sample) [g]
Moisture Content (MC) [g-water/g]
Solids Content (SC) [g-dry/g]
C-63
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
,TM
PreMethod 1313 LeachXS"vl Lite Data Template
PRE-TEST TITRATION INSTRUCTIONS
Step 1: Enter the project, material and replicate codes as well as the technician name. In
order to initiate test extration setup, enter the maximum particle size, solids content, and
reagent type and normality.
Step 2: Enter target acid or base additions from prior knowledge or from prediction of
neutralization classifications in Draft Method 1313 Table 2 (note: base equivalents have a
negative sign).
Step 3: Prepare five bottles, labelled P01 through P05, with solid material. Add reagent
water and acid or base to the bottles according to the Schedule of Acid and Base Additions.
Enter date and time that agitation of extracts begins.
Step 4: At the conclusion of the test, enter date and time that agitation ends. Record
leachate pH. The pre-test titration curve for the material will be plotted automatically
(note: axis adjustments may be necessary).
Step 5: From the pre-test titration, select the additions of acid and base required to
complete the list of target pH (see Draft Method 1313 Table 5) plotted as horizontal blue
dashed lines. These acid/base additions are to be entered into the "Test Data" sheet to
create the Schedule of Acid and Base Additions.
C-64
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
PreMethod 1313 LeachXS
METHOD 1313 PRE-TESTTITRATION
Extraction Information
Code
Project
Material
Test Replicate
Test Start
Test End
Description (optional)
Auto-inserted from "Title Sheet"
Auto-inserted from "Title Sheet"
Test conducted by:
Date
Time
Required Contact Time :
[hr]
Solids Information
Particle Size (85 wt% less than)
Minimum Dry Equivalent Mass *
Solids Content (default = 1)
Mass of "As Tested" Material / Extraction
* Data based on Draft Method 1313 Table 1.
J mm
g-dry
] g-dry/g
LS Ratio
Liquid Volume / Extraction
Recommended Bottle Size *
Temperature
Acid Normality
Base Type
Base Normality
10
200
250
mL/g-dry
ml
ml
°C
Schedule of Acid and Base Addition (±0.05)
Test Position P01 P02 P03 P04
"As Tested" Solid [g] (±0.05g) -
Reagent Water [ml] (±5%) -
Acid Volume [ml] (±1%) '-
Base Volume [ml] (±1%) -
P05
additional extracts as needed
P06 P07 P08
P09
P10
Total Solid
Total Water
Total Acid
Total Base
Acid Addition [meq/g]
Eluate pH
Eluate pH
12 -
10 -
8 -
6 -
4 -
2 -
A Targets
X Natural pH
-3 -2.5 -2 -1.5 -1 -0.5 0 0.5 1 1.5
Acid Addition [meq/g]
2 2.5 3
Acid Addition
Required
[meg/g-dry] pH Target
Rationale
0
2.0
4.0
5.5
7.0
8.0
9.0
12.0
13.0
10.5
1
±0.5
±0.5
±0.5
±0.5
±0.5
±0.5
±0.5
±0.5
±0.5
Natural pH at LS 10 mL/g-dry (no acid/base addition)
Provides total or available content of COPCs
Lower pH limit of typical management scenario
Typical lower range of industrial waste landfills
Neutral pH region; high release of oxyanions
Endpoint pH of carbonated alkaline materials
Minimum of LSP curve for many cationic and amphoteric COPCs
Maximum in alkaline range for LSP curves of amphoteric COPCs
Upper bound (field conditions) for amphoteric COPCs
Substitution if natural pH falls within range of a mandatory pH target
C-65
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
TM
PreMethod 1313 LeachXS"vl Lite Data Template
Table 1 Extraction Parameters as a Function of Particle Size
Particle
Size
(85% less
[mm]
0.3
2
5
US Sieve
Size
than)
50
10
4
Minimum
Dry
Equivalent
[g-dry]
20±0.02
40±0.02
80±0.02
Contact
Time
[h]
24±2
48±2
72±2
Suggested
Vessel
Size
[ml]
250
500
1000
Table 3 Pre-Test Tiration Schedule
Neutralization
Classification
Low Alkalinity
Moderate Alkalinity
High Alkalinity
P01
-2
-2
0
Acid or Base Addition [meq/g-dry]
P02 P03 P04
-101
025
5 10 15
P05
2
10
25
Additional data points (e.g., T06, T07, T08 ...) may be needed to provide titration curve resolution
C-66
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
-TM
PRE METHOD 1313 LeachXS Lite Data Template
EXTRACTION TEST INSTRUCTIONS
Step 1: Enter the project, material and replicate codes as well as the technician name. To
initiate test setup, enter the maximum particle size, solids content, and reagent type and
normality
Step 2: Enter target acid or base additions from prior knowledge or from the pre-test
titration (note: base equivalents have a negative sign).
^^^^^^^^^^H •
Step 3: Add solid material to nine bottles, labelled T01 through T09. Label an additional
three bottles as blanks (B01, B02, and BOS). Add Dl water and acid or base to eleven
bottles (i.e,., TOx and BOx bottles) according to the Schedule of Acid and Base Additions.
Enter date/time that extract agitation begins.
Note: If the acid or base is too dilute, large volume addition will be necessary. The acid or
base normality may be adjusted for individual extractions.
Step 4: At the conclusion of the test, enter date and time that agitation ends. Record
leachate information. Leachate pH and electrical conductivity (EC) will be plotted
automatically (note: axis adjustments may be necessary).
Step 5: If the pH of the extract is within the target range and an analytical sample is to be
saved, enter the letter "a" in the last row (font converts "a" to a check mark). If the extract
will not be saved for chemical analysis, enter the letter "r" in the last row (font converts "r"
toanX).
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
TM
PRE METHOD 1313 LeachXS Lite Data Template
METHOD 1313 EXTRACTION DATA
Code
Project
Material
Test Replicate
Test Start
Test End
Description (optional) Test conducted by:[
Auto-inserted from "Title Sheet"
Auto-inserted from "Title Sheet"
Date
Time
Solids Information
Maximum Particle Size | | mm
Minimum Dry Equivalent Mass * g-dry
Solids Content (default = 1) ] g-dry/g
Mass of "As Tested" Material / Extraction I g
LS Ratio
Liquid Volume / Extraction
Recommended Bottle Size *
Extraction Information
mL/g-dry
ml
ml
Required Contact Time '
hr
* Data based on Draft Method 1313 Table 1.
Schedule of Acid and Base Addition
Test Position T01 T02 T03 T04
"As Tested" Solid [g] (±0.05g)
Reagent Water [ml] (±5%)
Acid Volume [ml] (±1%)
Base Volume [ml] (±1%)
Acid Normality [meq/mL]
Base Normality [meq/mL]
Nominal Reagent Information
Temperature[
Acid Normality
Base Type
Base Normality
T05
T06
T07
T08
T09
B01
B02
B03
totals
-
—
_
-
—
_
-
-
—
_
-
-
—
_
-
-
—
_
-
-
—
_
-
-
—
_
-
-
—
_
-
-
—
_
no solid
-
—
_
no solid
-
—
_
no solid
-
—
_
g
ml
ml
ml
Target pH
Acid Addition [meq/g]
EluatepH
Eluate EC [mS/cm]
EluateEh[mV]
Meets pH criteria?
Notes
13.0±0.5 12.0±0.5 10.5±0.5 9.0±0.5 8.0±0.5 7.0±0.5 5.5±0.5 4.0±0.5 2.0±0.5
Water
Acid
Base
Enter "a" for "yes" or
"r" for "no".
-------
Interlaboratorv Validation of LEAF Method 1314 and Method 1315
TM
PRE METHOD 1313 LeachXS Lite Data Template
METHOD 1313 EXTRACTION DATA
Extraction Information
Code
Project
Material
Test Replicate
Test Start
Test End
Description (optional)
Auto-inserted from "Title Sheet"
Auto-inserted from "Title Sheet"
Test conducted by:[_
Date
Time
Required Contact Time'
Test Position
"As Tested" Solid [g] (±0.05g)
Reagent Water [ml] (±5%)
Acid Volume [ml] (±1%)
Base Volume [ml] (±1%)
Acid Normality [meq/mL]
Base Normality [meq/mL]
Target pH
Acid Addition [meq/g]
Eluate pH
Eluate EC [mS/cm]
Eluate Eh [mV]
Save? (enter "a" or "r"
Notes
hr
Solids Information
Maximum Particle Size | | mm
Minimum Dry Equivalent Mass * g-dry
Solids Content (default = 1) | \ g-dry/g
Mass of "As Tested" Material / Extraction I g
* Data based on Draft Method 1313 Table 1.
LS Ratio
Liquid Volume / Extraction
Recommended Bottle Size *
10
Temperature[
Nominal Reagent Information
Acid Type
Acid Normality
Base Type
Base Normality
Schedule of Acid and Base Addition
T01 T02 T03 T04
T05
T06
T07
T08
T09
B01
B02
B03
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
no solid
-
-
-
:
no solid
-
-
-
:
no solid
-
-
-
:
13.0±0.5 12.0±0.5 10.5±0.5 9.0±0.5 8.0±0.5 7.0±0.5 5.5±0.5 4.0±0.5 2.0±0.5
Base
Note: If multiple
replicate tests are
carried out in
parallel, only one set
of method blanks is
necessary.
C-69
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
TM
PRE METHOD 1313 LeachXS Lite Data Template
METHOD 1313 EXTRACTION DATA
Extraction Information
Code
Project
Material
Test Replicate
Test Start
Test End
Description (optional)
Auto-inserted from "Title Sheet"
Auto-inserted from "Title Sheet"
Test conducted by:[_
Date
Time
Required Contact Time'
Test Position
"As Tested" Solid [g] (±0.05g)
Reagent Water [ml] (±5%)
Acid Volume [ml] (±1%)
Base Volume [ml] (±1%)
Acid Normality [meq/mL]
Base Normality [meq/mL]
Target pH
Acid Addition [meq/g]
Eluate pH
Eluate EC [mS/cm]
Eluate Eh [mV]
Save? (enter "a" or "r"
Notes
hr
Solids Information
Maximum Particle Size | | mm
Minimum Dry Equivalent Mass * g-dry
Solids Content (default = 1) | \ g-dry/g
Mass of "As Tested" Material / Extraction I g
* Data based on Draft Method 1313 Table 1.
LS Ratio
Liquid Volume / Extraction
Recommended Bottle Size *
10
Temperature[
Nominal Reagent Information
Acid Type
Acid Normality
Base Type
Base Normality
Schedule of Acid and Base Addition
T01 T02 T03 T04
T05
T06
T07
T08
T09
B01
B02
B03
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
-
-
-
-
:
no solid
-
-
-
:
no solid
-
-
-
:
no solid
-
-
-
:
13.0±0.5 12.0±0.5 10.5±0.5 9.0±0.5 8.0±0.5 7.0±0.5 5.5±0.5 4.0±0.5 2.0±0.5
Base
Note: If multiple
replicate tests are
carried out in
parallel, only one set
of method blanks is
necessary.
C-70
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
TM
PRE METHOD 1313 LeachXS Lite Data Template
Table 4
Extraction Parameters as a Function of Particle Size
Table 5 Final Extract pH Targets
Maximum
Particle
Size
[mm]
0.3
2
5
US Sieve
Size
50
10
4
Minimum
Dry
Equivalent
[g-dry]
20±0.02
40±0.02
80±0.02
Contact
Time
[h]
24±2
48±2
72±2
Suggested
Vessel
Size
[mL]
250
500
1000
pH Target Rationale
varies Natural pH at LS 10 mL/g-dry (no acid/base addition)
2.0±0.5 Provides total or available COPC content
4.0±0.5 Lower pH limit of typical management scenario
5.5±0.5 Typical lower range of industrial waste landfills
7.0±0.5 Neutral pH region; high release of oxyanions
8.0±0.5 Endpoint for carbonated alkaline materials
9.0±0.5 Minimum of LSP curve for many cationic and amphoteric COPCs
12.0±0.5 Maximum in alkaline range for LSP curves of amphoteric COPCs
13.0±0.5 Upper bound (field conditions) for amphoteric COPCs
10.5±0.5 Substitution if natural pH falls within another mandatory target
M_
1 O .
1 n -
_ Q .
Q_
$
ro
3 R -
UJ b
1 -0.5 0 0.5
Acid Added [meq/g-dry]
•
-*-
1
A
B
C
1000
.o
(0
•c
o
o
100 •
10 •
1 •
0.1
-1 -0.5 0
Acid Added [meq/g-dry]
0.5
C-71
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
PreMethod 1313 LeachXS™ Lite Data Template
SELECTION OF ANALYTICAL SOLUTIONS
This page is for selection of a final set of nine extractions per test replicate from the "Lab
Extractions" data. All data is manually input by the user based on if extraction meet the pH
criteria.
C-72
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
METHOD 1313 SELECTED ANALYTICAL SOLUTIONS
Test Replicate I
Description (optional)
Auto-inserted from "Title Sheet"
Auto-inserted from "Title Sheet"
Max Particle Size
Solids Content
Temperature
selected from drop-down menu
selected from drop-down menu
Test Position
Test Start Date
Extraction Duration [hr]
"As Tested" Solid [g]
Reagent Water [ml]
Acid Volume [ml]
Base Volume [ml]
Acid Normality [meq/mL]
Base Normality [meq/mL]
Acid Addition [meq/g]
Eluate pH
Eluate EC [mS/cm]
Eluate Eh [mV]
Remarks
T01 T02 T03 T04 T05 TOG T07 T08 T09 B01 B02 BOS
Water Acid Base
Test Replicate
Max Particle Size
Solids Content
Temperature
Acid Type
Base Type
Lab Technician
selected from drop-down menu
selected from drop-down menu
Test Position
Test Start Date
Extraction Duration [hr]
"As Tested" Solid [g]
Reagent Water [mL]
Acid Volume [mL]
Base Volume [mL]
Acid Normality [meq/mL]
Base Normality [meq/mL]
Acid Addition [meq/g]
Eluate pH
Eluate EC [mS/cm]
Eluate Eh [mV]
Remarks
TOl T02 T03 T04 T05 T06 T07 T08 T09 B01 B02 B03
Water Acid Base
Test Replicate
Max Particle Size
Solids Content
Temperature
Acid Type
Base Type
Lab Technician
selected from drop-down menu
selected from drop-down menu
Test Position
Test Start Date
Extraction Duration [hr]
"As Tested" Solid [g]
Reagent Water [mL]
Acid Volume [mL]
Base Volume [mL]
Acid Normality [meq/mL]
Base Normality [meq/mL]
Acid Addition [meq/g]
Eluate pH
Eluate EC [mS/cm]
Eluate Eh [mV]
Remarks
TOl T02 T03 T04 T05 TOG T07 T08 T09 B01 B02 BOS
Water Acid Base
C-73
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
TM
PreMethod 1313 LeachXS'"" Lite Data Template
Table 5 Final Extract pH Targets
pH Target Rationale
varies Natural pH at LS 10 mL/g-dry (no acid/base addition)
2.0±0.5 Provides total or available COPC content
4.0±0.5 Lower pH limit of typical management scenario
5.5±0.5 Typical lower range of industrial waste landfills
7.0±0.5 Neutral pH region; high release of oxyanions
8.0±0.5 Endpoint for carbonated alkaline materials
9.0±0.5 Minimum of LSP curve for many cationic and amphoteric COPCs
12.0±0.5 Maximum in alkaline range for LSP curves of amphoteric COPCs
13.0±0.5 Upper bound (field conditions) for amphoteric COPCs
10.5±0.5 Substitution if natural pH falls within another mandatory target
M_
1 O -
1 n -
X o
Q_
CO
LJJ
2.
H
1 -0.5 0 0.5
Acid Added [meq/g-dry]
•
-*-
1
A
B
C
1000 •
^ 100 •
.0
co
> 10-
o
•c
o
o
1 -
0.1 •
— <
I
•-A
1 B
-*-c
1 -0.5 0 0.5
Acid Added [meq/g-dry]
C-74
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
Pre Method 1313 LeachXS Lite Data Template
METHOD 1313 MASTER DATA LIST
Value greater than calibration
Value between MDL and ML
Project ID
Material ID
Test ID
Sample ID
-1313-T01-A
-1313-T02-A
-1313-T03-A
-1313-T04-A
-1313-T05-A
-1313-T06-A
-1313-T07-A
-1313-T08-A
-1313-T09-A
-1313-T01-B
-1313-T02-B
-1313-T03-B
-1313-T04-B
-1313-T05-B
-1313-T06-B
-1313-T07-B
-1313-T08-B
-1313-T09-B
-1313-T01-C
-1313-T02-C
-1313-T03-C
-1313-T04-C
-1313-T05-C
-1313-T06-C
-1313-T07-C
-1313-T08-C
-1313-T09-C
-1313-B01-A
-1313-B02-A
-1313-B03-A
Code
1313
"As Tested"
Solid
g
-
Description (optional) u Value less than MDL
Auto-inserted from "Title Sheet" Ul/2 Value less than MDL (shown at 1/2 MDL) MDL
Auto-inserted from "Title Sheet" ML
Acid Type Base Type Analytical Method
Test Rep A
Test Rep B
Test Rep C
Analysis Date
Analytical Lab Name
Eluate Composition
Moisture Water Acid Acid Base Base Acid Eluate Eluate Eluate
Content Added Added Stength Added Stength Added pH Cond. ORP
g-H2O/g mL mL N mL N meq/g-dry s.u. mS/cm mV
-
-
C-75
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
election and Quantification Limits
PreMethod 1313 LeachXS Lite Data Template
PreMethod 1313 LeachXS Lite Data Template
C-76
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
PreMethod 1313 LeachXS Lite Data Template
C-77
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
PreMethod 1313 LeachXS Lite Data Template
C-78
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
C-79
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Interlaboratory Validation of LEAF Method 1314 and Method 1315
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
I WASHINGTON, D.C. 20460
OFFICE OF
SOLID WASTE AND
Dear Leach Validation Participant, EMERGENCY RESPONSE
Welcome to the Phase I validation of PreMethods 1313 (pH dependent leach test) and
1316 (L/S ratio leach test). These methods represent a significant step forward in the science of
modeling material leaching into the environment. As a participatory laboratory, your assistance
in this effort will help ensure these methods are incorporated in EPA's publicly available method
compendium Test Methods for Evaluating Solid Waste Physical/Chemical Methods (SW-846).
As you review the methods, along with the instructions and materials enclosed in this
package, I would like to highlight a couple of key points. First, please make sure you downloand
and review the most current version of PreMethods 1313 and 1316 along with the laboratory
instruction sheet (enclosed) before running the methods (see w\v\v.vanderhik.edu/leaching),
Some minor changes and clarifications were recently made to the methods to help improve their
usability. Second, please check the list of materials provided on the instruction sheet to ensure
your kit is complete. Lastly, please note that since you will be shipping the extracted elluates to
Vanderbilt University for analysis, it is important that you follow the preservation instructions to
ensure accurate results.
From the start of this interlaboratory validation effort, one of our top priorities is to make
sure we are being responsive to the needs of our participating labs. As such, please do not
hesitate to contact me with any problem, issue, or concern you may have throughout this process.
You can contact me by phone at 703-308-0157 or by email at baldwin.markfojepa.gov. Again on
behalf of the EPA, I would like to thank you and your laboratory for your invaluable contribution
to this validation effort.
Internet Address (URL) • hitp://www_epa,gov
Recycled/Recyclable • Printed with Vegetable Oil Based Inks on 100% Postconsumer, Process Chlorine Free Recycled Paper
C-80
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Interlaboratory Validation of LEAF Method 1314 and Method 1315
Phase I of Method 1313/Method 1316 Validation
The subject material for Phase I of the Method 1313/Method 1316 inter-laboratory validation study is a coal
combustion fly ash. A generic MSDS for coal fly ash is included with the material shipment.
The subject material may be treated as a well homogenized sample with 85% < 0.3 mm particle size. Thus:
• the minimum equivalent dry mass for Method 1313 and Method 1316 will be 20 g-dry and all
extractions may be conducted in 250-mL bottles with the exception of two low liquid-solid (LS) ratio
test positions, 1316-T04 and T05, which will likely require higher amounts of solid materials in a 500
mL bottles in order to ensure 50 mL analytical solutions
• no particle size reduction or sieve analysis is required for this Phase I sample
Although the titration curve should be developed as part of the method validation, baseline characterization
has shown the titration curve for the Phase I material to be very sensitive to acid addition in the neutral
range. Extreme care should be taken to provide exact volumes of acid addition during (i) the pre-test
titration in order to produce an accurate titration curve and (ii) the extraction step in order to reproduce an
acceptable final pH. Test positions that meet pH tolerances should be processed for chemical analysis and
only those test positions that do not meet test position pH tolerances need to be rerun.
The kit supplied for the Phase I validation study includes:
• Four sets of completed bottle labels for each test replicate
• One chain of custody form
• Two questionnaires (one for each Method 1313 and Method 1316)
The sample labeling convention used to identify a particular solution consists of numerical identifiers for the
material, lab, test method, and test position along with an alphabetical identifier for the test replicate. The
layout for the sample label convention is as follows:
MadLbb-ttlc-Tdd-e (Test Positions T01 through T09)
MaaUb-l3lc-Edd-e (QA/QC Blanks B01-B03)
"aa " is a two-digit number starting at zero that identifies the test material (e.g., the Phase I material is
MOl),
"bb " is a two-digit number starting at zero that identifies the participating laboratory (assigned
randomly by EPA-ORCR),
"c " is a single digit number that completes the test method ID (i.e., 1313 or 1316),
"dd" is a two-digit number starting at zero that identifies the test position or QA/QC blank.
"e " is a single letter representing the test replicate (i.e., A, B or C).
Four sets of completed labels are provided to be used for labeling extraction vessels and two sets of 50-mL
analytical samples. The remaining fourth set may be reserved for replacements as needed.
Instructions for Phase I Validation
C-81
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
On or before June 7, 2010:
1. Prepare 3 test replicates of extracts for the supplied sample material according to the most current
versions of Method 1313 and Method 13161. Use the Excel data templates to calculate extract
"recipes" and return a completed Excel data template to the Vanderbilt project lead, Andy
Garrabrants (A.Garrabrants@vanderbilt.edu) via email. Each method should be conducted as
specified in the method draft to the extent possible; however, any necessary deviations should be
recorded and a log of deviations returned with the Excel data template.
2. For each test position and QA/QC blank, collect two 50-mL analytical samples in the DigiTubes
provided. Preserve each analytical sample with Optima grade (or similar purity) nitric acid to a final
concentration of 1% (v/v). Each analytical sample should have a label (prefilled and provided)
corresponding to its test position (e.g., T01-T09) and test replicate (e.g, A, B, and C).
3. Return one set test positions and QA/QC blanks in 50-mL DigiTubes for each Method 1313 and
Method 1316 to Vanderbilt University for chemical analysis and retain the remaining set of samples
onsite at least until the end of Phase I testing.
Shipments should be sent no later than June 7, 2010 and a completed chain of custody form
(provided) should be included. Please ship samples (Monday through Thursday pickup only as
Vanderbilt cannot accept Saturday deliveries) to following address:
Civil & Environmental Engineering
Vanderbilt University
c/o Rossane DeLapp
Jacobs Hall 149
400 24th Avenue South
Nashville, TN 3723 5
(615)322-3189
Please inform the ORCR study lead, Mark Baldwin (Baldwin.Mark@epa.gov), and Vanderbilt lead,
Andy Garrabrants (A.Garrabrants@vanderbilt.edu), of your intended ship date so that arrangements
may be made to receive the shipment.
4. Complete the method feedback questionnaire for each test method (available at
www.vanderbilt.edu/leaching/downloads.html) and return it to Mark Baldwin by email no later than
June 7, 2010.
Programmatic and technical questions may be directed to the ORCR lead, Mark Baldwin
(Baldwin.Mark@epa.gov. 703-308-0157).
1 The latest versions of these test methods and data templates may be downloaded at
www.vanderbilt.edu/leaching/downloads.html. Although the procedures themselves are not changed in any way, the method
drafts dated April 26, 2010 contain minor clarifications to the method which are intended to improve understanding of the method
C-82
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Interlaboratory Validation of LEAF Method 1314 and Method 1315
Arcadis Geraghty and Miller CHAIN OF CUSTODY RECORD
4915 Prospectus Drive
Durham, NC 27713
(919)544-4535
Project Description:
Arcadis GSM charge # :
Responsible EPA Party:
Phase I Lab Validation for1313and131(Page .
RN990271.0007.00001
Mark Baldwin
Peter Kariher
Sample ID
Method 1 31 3 Solid Material
Method 1 31 6 Solid Material
Sam pie ID
Date
Collected
04/26/10
04/26710
Sample Description
1 Liter HOPE container of lab validaton material
1 Liter HOPE container of lab validaton material
approximately 1 kq
approximately 1 kq
Number of
Containers
2
4
Special Instructions
Analyses Required
SW-846 Method 1313
SW-846 Method 1316
Report results to:
(phone)
(fax)
Samples shipped to:
Vanderbitl University
Civil A Hnvirnnmenuil engineering
V;inilerhilt University
c/o Rossane DeLapp
Jacobs Hall I49
400 24"' Avenue South
Nashville, TN -17235
Samples collected by: Peter H. Kariher
(signature)
Samples relinquished by:
(signature)
Samples received by:
(signature)
Date: 4/26/2010
Date:
Date shipped:
4/26/2010
Dale:
C-83
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
M01-L01-1313-T01-A M01-L01-1313-T01-B M01-L01-1313-T01-C
M01-L01-1313-T02-A M01-L01-1313-T02-B M01-L01-1313-T02-C
M01-L01-1313-T03-A M01-L01-1313-T03-B M01-L01-1313-T03-C
M01-L01-1313-T04-A M01-L01-1313-T04-B M01-L01-1313-T04-C
M01-L01-1313-T05-A M01-L01-1313-T05-B M01-L01-1313-T05-C
M01-L01-1313-T06-A M01-L01-1313-T06-B M01-L01-1313-T06-C
M01-L01-1313-T07-A M01-L01-1313-T07-B M01-L01-1313-T07-C
M01-L01-1313-T08-A M01-L01-1313-T08-B M01-L01-1313-T08-C
M01-L01-1313-T09-A M01-LOM313-T09-B M01-L01-1313-T09-C
M01-L01-1313-B01-A M01-L01-1313-B01-B M01-L01-1313-B01-C
C-84
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
Method Feedback Questionnaire
METHOD 1313: Liquid-Solid Partitioning as a Function of Eluate pH using a
Parallel Batch Procedure
1. Please indicate the amount of time (in professional hours) required to complete the following
steps of Method 1313:
Material Preparation (e.g., air drying, particle-size reduction, sieving) hrs
Pre-test Titration hrs
Extraction Setup (e.g., solids, water, acid/base additions) hrs
Eluate Processing (e.g., pH/cond, filtration, analytical prep) hrs
2. How would you rate the overall usability of Method 1313?
3. In total, how much time (in professional hours) was required to process three test replicates
of the test material using Method 1313?
4. Were the overall goals and instructions provided with the sample material clearly laid out and
easy to follow? If not, please suggest specific sections of the method where clarifications
could be made.
Method Feedback Questionnaire - Method 1313 Page 1 of 3
C-85
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
5. Were the procedures in the method draft clearly laid out and easy to follow? If not, please
suggest specific sections of the method where clarifications could be made.
6. Was the Excel data template clearly laid out and easy to follow? If not, please suggest
specific sections of the data template where clarifications could be made.
7. In preparing solid samples for the method, what difficulties (if any) were encountered? How
were these difficulties overcome?
8. While defining the pre-test titration curve, what difficulties (if any) were encountered? How
were these difficulties overcome?
When using the Excel data template sheets, what difficulties (if any) were encountered? How
were these difficulties overcome?
Method Feedback Questionnaire - Method 1313 Page 2 of 3
C-86
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
10. What difficulties (if any) did you encounter with acquiring or operating the required
equipment?
11. How much time did it take technical personnel to become familiar with the method?
12. Please provide any general feedback (e.g., comments, edits, questions, software glitches, or
concerns) below. Include any suggested modifications to the test procedure, the Excel data
template or to the method draft.
Method Feedback Questionnaire - Method 1313 Page 3 of 3
C-87
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
Method Feedback Questionnaire
METHOD 1316: Liquid-Solid Partitioning as a Function of Liquid-Solid
Ratio using a Parallel Batch Procedure
1. Please indicate the amount of time (in professional hours) required to complete the following
steps of Method 1316:
Material Preparation (e.g., air drying, particle-size reduction, sieving) hrs
Extraction Setup (e.g., solids, water, acid/base additions) hrs
Eluate Processing (e.g., pH/cond, filtration, analytical prep) hrs
2. How would you rate the overall usability of Method 1316?
3. In total, how much time (in professional hours) was required to process three test replicates
of the test material using Method 1316?
4. Were the overall goals and instructions provided with the sample material clearly laid out and
easy to follow? If not, please suggest specific sections of the method where clarifications
could be made.
Method Feedback Questionnaire - Method 1316 Page 1 of 3
C-88
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
5. Were the procedures in the method draft clearly laid out and easy to follow? If not, please
suggest specific sections of the method where clarifications could be made.
6. Was the Excel data template clearly laid out and easy to follow? If not, please suggest
specific sections of the data template where clarifications could be made.
7. In preparing solid samples for the method, what difficulties (if any) were encountered? How
were these difficulties overcome?
When using the Excel data template sheets, what difficulties (if any) were encountered? How
were these difficulties overcome?
9. What difficulties (if any) did you encounter with acquiring or operating the required
equipment?
Method Feedback Questionnaire - Method 1316 Page 2 of 3
C-89
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Interlaboratorv Validation of LEAF Method 1314 and Method 1315
10. How much time did it take technical personnel to become familiar with the method?
11. Please provide any general feedback (e.g., comments, edits, questions, software glitches, or
concerns) below. Include any suggested modifications to the test procedure, the Excel data
template or to the method draft.
Method Feedback Questionnaire - Method 1316 Page 3 of 3
C-90
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Interlaboratory Validation of LEAF Leaching Tests: Method 1314 and Method 1315
Appendix D. Blank Analysis and Data Filtering
TABLE OF CONTENTS
Table of Contents D-i
Blank Analysis and Data Filtering D-l
Method 1314 Method Blanks and Data Filtering D-l
Method Blank Analysis D-l
Filtering for Cause D-4
Effect of CaCl2 Eluent on Constituent Concentrations D-4
Effect of Data Filtering L10 Calcium Results on Statistical Analysis D-4
Method 1314 Filtration Summary D-6
Method 1315 Method BLank Analysis and Data Filtering D-7
Method Blank Analysis D-7
Data Filtering due to Method Blanks D-7
Data Filtering for Cause D-7
Method 1315 Filtering Summary D-7
D-i
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Inter-laboratory Validation of Parallel Batch Method 1314 and Method 1315
Blank Analysis and Data Filtering
During chemical analysis of preserved eluates for Method 1314 and Method 1315, several method blanks
(e.g., samples of eluates representing test runs conducted with all reagents and procedures but without the
subject material) showed significant concentrations of some analytes. These method blank signatures
were concluded to indicate some degree of external contamination which could have influenced the test
results and possibly the method precision results. Therefore, the process used for filtering data based on
method blank information was adopted from the Method 1313 and Method 1316 validation report
(Garrabrants et al., 2012) for these data. In that approach, filtering or removing an eluate concentration
from the statistical analysis was considered when either (i) known or suspected errors in performing the
method or in following the validation study instructions, or (ii) interpretation of the blank concentrations
and their effect on eluate concentrations.
METHOD 1314 METHOD BLANKS AND DATA FILTERING
Method 1314 specifies that one method blank should be collected, preserved for analysis and interpreted
as support that measured concentrations in the method test are not influenced by external sources of
contamination. This method blank is labeled "B01" and is a collected sample of the influent water
introduced to the column. As with all other eluate solutions, the method blank was preserved prior to
chemical analysis by ICP-OES by the addition of Optima grade nitric acid to a final concentration of 1%
(v/v).
Method Blank Analysis
An algorithm was developed to filter (remove) data from the data set if the concentration of an analyte in
the corresponding blank was greater than 20% of the measured concentration in the test method eluate.
This data filtering assessment was conducted to avoid confounding statistical analysis of the test results in
analytical solutions where background contamination (e.g., through reagent water or acid/base reagents)
represents a significant portion of the measured concentration.
As an initial screen, method blank concentrations for the selected analytes used in estimate precision (see
Table 5 in the report text) were compared to ICP-OES QA/QC values and the minimum measured
concentration in preserved eluates. The method blank concentrations of selected analytes for each
Method 1314 study material are shown in Figure 1 for the CFS material and in Figure 2 for the JaFS
material. In each panel, method blank concentrations are presented in comparison to the ICP-OES
method detection limit (MDL) and minimum level of quantitation (ML).
The following are observations from the Method 1314 Method Blank analysis:
• The concentration of analytes in the method blanks for most laboratories were reported as non-
detectable (i.e., below the MDL value) or non-quantifiable (i.e., between MDL and ML values).
Therefore, blank concentrations that did not pass minimum analytical QA/QC criteria were
considered insignificant.
• When analyte concentrations were detected above the ML value, the minimum measured
concentration for each analyte was plotted in the panels of Figure 1 and Figure 2 as a point of
comparison.
D-l
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Inter-laboratory Validation of Parallel Batch Method 1314 and Method 1315
0.1 •
E
C
3
0.0001 •
1 —
Dl
C
s
o
| MHax BOl (water)]
ML
MDL
n
LOl
n • n n • n
L06 L07 L10 Lll L14 Ref
Lab ID
• Max BOl (water)|
ML
MDL
n n n n n n n
LOl
"a
1
3
0.001 •
Lead (mg/
1 1 t
MDL
_B«M_
LOl
"S; n 1
| 0.01 •
re
CO
0.0001 -
1 —
Dl
^ 001-
3
E
~° 0.001 -
u
| BMax BOl (water) |
ML
MDL
XL
LOl
• •••••
L06 L07 L10 Lll L14 Ref
Lab ID
| BMax BOl (water)|
-ML
MDL
L06 L07 L10 Lll L14 Ref LOl
Lab ID
1
|«MaxB01(water)|
I 1 _ I 1 _ I 1 _ I 1 _ I 1 _ I 1
L06 L07 L10 Lll L14 Ref
Lab ID
| BMaxB01(water)|
ML
•MDL
n n n n n n n
LOl
n
1
?
L06 L07 L10 Lll L14 Ref
Lab ID
| • Max BOl (water) |
ML
MDL
n n n n n n n
1 — 01-
Q.
0.001 -
5 o.i.
Dl
i
2
> 0.001 •
o
1
^ 0.1
1
g 0.01
N
0.001
n i n n i n
L06 L07 L10 Lll L14 Ref
Lab ID
| BMax BOl (water) |
ML
MDL
-XX
LOl
• • • • • n
L06 L07 L10 Lll L14 Ref
Lab ID
• Max BOl (water)|
ML
MDL
n n n n n n n
LOl
ML
L06 L07 L10 Lll L14 Ref
Lab ID
• Max BOl (water) |
MDL
n n n n n n n
L06 L07 L10 Lll L14
Lab ID
L06 L07 L10 Lll L14 Ref
Lab ID
Figure 1. Maximum method blank concentrations for Method 1314 CFS material. Note: All solutions were
preserved for chemical analysis with Optima grade nitric acid at 1% (v/v).
D-2
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Inter-laboratory Validation of Parallel Batch Method 1314 and Method 1315
0.1 •
^
"S
C. 0.01 •
E
C
3
0.0001 •
_l
1
Ł
o
ML
• Max B01 (water)]
MDL
H
L01
n • n n • n
L06 L07 L10 Lll L14 Ref
Lab ID
• Max B01 (water)|
ML
MDL
n n n n n n n
L01
J 0.1 •
I
1 nnl
8
0.001 •
0.1 •
_l
"a
E
Dl
(0
S
1 -
_l
"5 o.i •
| 0.01 -
re
CO
0.0001 -
10 -
"a '
Ł 01
1
|u 0.01 •
n
U
0.001 •
'ML
| DMax B01 (water) |
MDL
XL
L01
• • • • •
L06 L07 L10 Lll L14 Ref
Lab ID
I BMax B01 (water)!
Minimum Sample Concentration • I ' '
0
ML
MDL | |
•_n
L06 L07 L10 Lll L14 Ref L01
Lab ID
• Max B01 (water)]
ML
MDL
_•_
L01
• •••••
L06 L07 L10 Lll L14 Ref
Lab ID
• MaxB01(water)|
ML
MDL
• III
L01
1 -.
_l
I "
3 0.01 •
c
-------
Inter-laboratory Validation of Parallel Batch Method 1314 and Method 1315
The method blank analysis for Method 1314 testing of the CFS material (Figure 1) showed no
quantifiable concentrations of any of the ten validation analytes. Therefore, no eluate concentration
assessment was conducted. The Method 1314 blanks for JaFS material, presented in Figure 2, indicated
that only calcium in the L10 method blank was quantifiable at a high value of 27 mg/L. Discussions with
L10 technical contacts indicated that the high concentration of calcium in the method blank was due to 1
mM CaCl2 solution being used as a test eluent. Therefore, calcium results for L10 were considered
potential candidates for "filtration for cause."
Filtering for Cause
When interferences due to procedural mistakes or laboratory practices are identified, data may be filtered
for cause. Often, these interferences are not shown directly through blank analysis, but are identified by
reviewing the collected data as a whole and through analysis of measured concentrations over the
spectrum on ICP-OES analytes. The high calcium concentrations in L10 method blanks were known to
be due to the use of 1 mM CaCl2 solution as an eluent. All other validation laboratories used deionized
water as a Method 1314 eluent. Although Method 1314 states that 1 mM CaCl2 may be used for testing
of materials with high organic content or high clay content in order to minimize the effects of organic
carbon dissolution or clay layer deflocculation, it was not intended for use during the Method 1314
validation and probably would not be appropriate for the JaFS brass foundry sand. While not strictly a
mistake, notable differences in results between the CaCl2 eluent and deionized water eluent could
potentially influence the validation results and further investigation into the effect of 1 mM CaCl2 eluent
was warranted.
Effect ofCaCl2 Eluent on Constituent Concentrations
Figure 3 shows the comparison between the statistical analysis for deionized water test results and L10
test results. The figure indicates that, for most of the analytes used in the validation of JaFS Method
1314, no statistical difference between the data sets is apparent. Minor differences in eluate concentration
for Al, Ca and Mg are evident at high L/S; however, these differences are not considered to be significant
enough to change the outcome of the validation study.
Effect of Data Filtering L10 Calcium Results on Statistical Analysis
The overall effect of filtering L10 calcium results from the data set on the number of observations
available for statistical analysis is shown in Table 1 by target EL/S (and test position label) and in Table 2
by analyte. These tables provide a summary of filtered values including the number of observations used
in statistical analysis for each analyte and each target pH value.
Table 1. Data Point Summary by SL/S after Blank Filtering and Filtering for Cause.
SL/S (ml/g-dry)
Test Position
Collected
Filtered
Used in Analysis
0.2
T01
24
3
21
0.5
T02
24
3
21
1.0
T03
24
3
21
1.5
T04
24
3
21
2.0
T05
24
3
21
4.5
T06
24
3
21
5.0
T07
24
3
21
9.5
T08
24
3
21
10.0
T09
24
3
21
D-4
-------
Inter-laboratory Validation of Parallel Batch Method 1314 and Method 1315
1 10
L/S (L/kg)
o
A
El
a
a
a
a
a
•=,-
S-
5-
S
S
1O-A
1O-B
1O-C
iltered Mean
iltered RL
1 10
L/S (L/kg)
1 10
L/S (L/kg)
0.1
0.01 -:
0.001
JaFS-LlO-A
JaFS-LlO-B
JaFS-LlO-C
-JaFS Filtered Mean
JaFS Filtered RL
__MJ_
. . MDL
0.1
L/S (L/kg)
O
A
ID
a
a
a
a
a
•=,-
S-
S-
s
S
1O-A
1O-B
IO-C
iltered Mean
iltered RL
1 10
L/S (L/kg)
1 10
L/S (L/kg)
1000
100 - !
10 - ;
1 - ;
0.1 - ,
0.01
0.001
-L1O-A
-L1O-B
-L1O-C
Filtered Mean
Filtered RL
ML,
MDL
0.1
1 10
L/S (L/kg)
Ti
nm -
O a S- 1O-A
A a S- 1O-B
n a s- io-c
a S iltere
d Mean
d RL
IVIUL
1 10
L/S (L/kg)
S.
o
A
a
a
a
a
a
S-L1O-A
S-L1O-B
S-L1O-C
S Filtered RL
. _Mk
MDL
1 10
L/S (L/kg)
Ł, 0.1 -r
1 10
L/S (L/kg)
Figure 3. Comparison of Method 1314 conducted with 1 mM CaCl2 eluent to Method 1314 statistics (mean
and reproducibility limit intervals) from a filtered data set with L10 data removed.
D-5
-------
Inter-laboratory Validation of Parallel Batch Method 1314 and Method 1315
Table 2. Data Point Summary by Analyte after Blank Filtering and Filtering for Cause.
By Analyte
Collected
Filtered
Used in Analysis
Al
216
0
216
B
216
0
216
Ba
216
0
216
Ca
216
3
213
Cu
216
0
216
Mg
216
0
216
Mn
216
0
216
Mo
216
0
216
Pb
216
0
216
Zn
216
0
216
Subsequent to data filtering, statistical analysis was carried out on both unfiltered and filtered data to
determine the impact of data filtering on final results and conclusions. The impact of the overall effect of
filtering data is illustrated in Figure 4 by comparing median-based 95% robust confidence limit statistics
between the collected data including L10 Ca and the filtered data set with L10 Ca removed.
1000
100
•5 0-1 -k
u
0.01
0.001
-JaFS95% RCL
JaFS Filtered 95% RCL
_ML
MDL
0.1
10
L/S (L/kg)
Figure 4. 95% robust confidence limits (RCLs) for the Method 1314 of JaFS material including all collected
data (red solid line) and with filtering of L10 data (green dashed line).
This comparison in Figure 4 indicates that removal of a triplicate analysis from one laboratory from the
validation study has only a minor effect on statistical analysis and is unlikely to change the outcomes of
the validation study. Therefore, in light of the significant effort required to filter the collected data into a
filtered data set, no filtration for cause was conducted for Method 1314 validation data.
Method 1314 Filtration Summary
Based on the above analyses, the final filtration scheme for Method 1314 data (Table 3) indicated that no
data was filtered due to method blank analysis or filtered for cause. All collected data was used in the
statistical analysis for validation of Method 1314.
Table 3. Final Filtered Data for Method 1314 Statistical Analysis.
[Material •Filtered Data
CFS
JaFS
None
None
D-6
-------
Inter-laboratory Validation of Parallel Batch Method 1314 and Method 1315
METHOD 1315 METHOD BLANK ANALYSIS AND DATA FILTERING
In Method 1315, the test material is contacted only with reagent water over a series of batch-type leaching
steps with periodic renewal of the leaching solution. Method blanks include a series of nine eluate
fractions collected by running the test using an empty holder (i.e., no solid material), but with all other
normal equipment and reagents.
Method Blank Analysis
According to Method 1315, a series of nine method blanks are collected - one method blank
corresponding to each of nine test fractions of Method 1315. This implies there is a one-to-one
relationship between an eluate fraction and its associated method blank. Method blank analysis is
conducted on eluate concentrations before calculation of interval flux or cumulative release which are
considered Method 1315 outputs.
As with the Method 1314 blank analysis, screening of method blank concentrations against QA/QC
values, shown Figure 5 for the SWA monolithic material and in Figure 6 for the CFS compacted granular
material, indicate which method blanks resulted in quantifiable concentrations. Both of these figures
show that of the ten selected analytes used in the method validation, only calcium and potassium were
found in method blanks at levels above the ML value. Quantifiable concentrations of calcium and
potassium were found in most if not all method blanks for both materials.
Data Filtering due to Method Blanks
When eluate concentrations for calcium and potassium were compared their corresponding method blanks
for each test fraction, no eluates were flagged as having an associate method blank concentration that was
20% or more of the eluate concentration. Therefore, no filtering of the data due to method blank analysis
was required.
Data Filtering for Cause
For Method 1315 testing of SWA and CFS materials, no known sources of interference were identified;
therefore, no data required filtering for cause.
Method 1315 Filtering Summary
Based on the above analyses, the final filtration scheme for Method 1315 data is shown in Table 4
showing that no data was filtered due to method blank analysis or filtered for cause.
Table 4. Final Filtered Data for Method 1315 Statistical Analysis.
•Material •Filtered Data
SWA None
CFS None
D-7
-------
Inter-laboratory Validation of Parallel Batch Method 1314 and Method 1315
G" 0.1 •
1 —
O)
E o.oi -
i M
1
^ 0.001 • —
n nnm -
• T01
DT06
L
DL
DT02 BT03 BT04 DT05
DT07 DT08 «T09
^ o-i-
> ™
O
.1 0.01 • M
+i —
1
U n nm -
DT
DT
01 DT02 BT03 BT04 DT05
06 DT07 DT08 BT09
L
DL
.
I
L01 L04 LOS L06 L07 L09 L10 Lll Ref
Lab ID
DTOl DT02 BT03 BT04 DT05
DT06 DT07 DT08 BT09
ML__
MDL
L01 L04 LOS L06 L07 L09 L10 Lll Ref
Lab ID
.§ 0.01 •
I
10 0.001
DT
DT
01 DT02 DT03 BT04 DT05
06 DT07 DT08 BT09
ML
MDL
1
I
L01 L04 LOS L06 L07 L09 L10 Lll Ref
Lab ID
I DTOl DT02 «T03 BT04 DTOS
DT06 DT07 DT08 BT09
ML
MDL
1
L01 L04 LOS L06 L07 L09 L10 Lll Ref
DT01 DT02 DT03 DT04 DTOS
DT06 DT07 DT08 BT09
L01 L04 LOS L06 L07 L09 L10 Lll Ref
L01 L04 LOS L06 L07 L09 L10 Lll Ref
Lab ID
0.001
DTOl DT02 BT03 BT04 DTOS
DT06 DT07 DT08 BT09
:.ML_
MDL
0 0001 plllllllllJIIIIIIIIHIIIIIIIIH i ni i i i
LOl L04 LOS L06 L07 L09 L10 Lll Ref
Lab ID
[Minimum EluateConcentration firo! QT02 i^03 BT04 DTOS I
f | DT06 DT07 DTPS »T09
LOl L04 LOS L06 L07 L09 L10 Lll Ref
T01 DT02 BT03 BT04 DTOS
T06 DT07 DT08 BTOS
_ _ _ _ _ _ _ _
LOl L04 LOS L06 L07 L09 L10 Lll Ref
^ 0.1 -
O)
1 °'0i • ML
•o
g MDL
•S 0.001 •
BTOl
DT06
DT02 DT03 BT04 DTOS
DT07 DT08 BT09
I
LOl L04 LOS L06 L07 L09 L10 Lll Ref
Lab ID
Figure 5. Method blank concentrations for Method 1315 SWA material. Note: All solutions were preserved
for chemical analysis with Optima grade nitric acid at 1% (v/v).
D-8
-------
Inter-laboratory Validation of Parallel Batch Method 1314 and Method 1315
uminum (mg/l
I § F
n nnm •
DT01 OT02 BT03 BT04
DT06 OT07 DT08 1T09
ML
MDL
m
III
ll tl
1
1 1
ITl
II
III
DT05
^ "-I"
>
c
o
.1 0.01 •
•P
<
n nm -
3T01 DT02 BT03 BT04 DT05
]T06 DT07 DT08 BT09
ML
MDL
1
LOl L04 L06 L07 L10 Lll Ref
Lab ID
nm •
ML
MDL
Illll
• TO
• TO
1
1 OT02 «T03 BT04 OT05
3 OT07 DT08 BT09
1
LOl L04 L06 L07 L10 Lll Ref
Lab ID
J, 0.01 • •_
E
DTO
DTO
1 DT02 OT03 BT04 DT05
3 OT07 OT08 BT09
.ML
MDL
1
II
II
LOl L04 L06 L07 L10 Lll Ref
Lab ID
0.01 • -MDL
DTOl OT02 «T03 BT04 OT05
DT06 OT07 OT08 BT09
LOl L04 L06 L07 L10 Lll Ref
Lab ID
o.oi ••
• TO
DTO
1 OT02 OT03 BT04 OT05
3 OT07 OT08 BT09
ML
MDL
1
fl
[
LOl L04 L06 L07 L10 Lll Ref
Lab ID
LOl L04 L06 L07 L10 Lll Ref
Lab ID
_l
'
Dl
C
Ł
o
n nnm •
ML
MDL
Illll
• TO
• TO
1
L OT02 «T03 BT04 OT05
3 DT07 DT08 BT09
1
LOl L04 L06 L07 L10 Lll Ref
Lab ID
G" 1 '
'
Dl
E o.i •
'u
° 0.01 •
ML
MDL
M n
mum Eluate Concen
• —
• TC
• TO
. OT02 BT03 BT04 DT05
6 DT07 QT08 «T09
t 1
1
ru n n_
lilt
Tfl
.Ik
III
1 If
. n...
II
Fh rlfl
flfljn-
Ml
1 1 1
ill
{I
ll
II
II
J
n n
Illl
LOl L04 L06 L07 L10 Lll Ref
DT01 OT02 DT03 «T04 DT05
DT06 OT07 DT08 «T09
Minimum E mate Concentration
LOl L04 L06 L07 L10 Lll Ref
5 o.i-
Dl
| 0.01 -
•o
Ł
> 0.001 •
• T01 n
DT06 n
r02 OT03 BT04 OT05
TO? OT08 DT09
ML
VIDL
IB
i
ii ii
LOl L04 L06 L07 L10 Lll Ref
Lab ID
Figure 6. Method blank concentrations for Method 1315 CFS material. Note: All solutions were preserved for
chemical analysis with Optima grade nitric acid at 1% (v/v).
D-9
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Appendix E. Method 1314 Results and Precision Estimates
TABLE OF CONTENTS
Collected Concentration Data
CFS Contaminated Field Soil E-l
JaFS Steel Foundry Sand E-6
Reference Laboratory Eluate Results (ICP-OES and Supplemental Analysis)
CFS Contaminated Field Soil E-ll
JaFS Steel Foundry Sand E-17
Statistical Analysis for Selected Constituents
CFS Concentration Results E-23
JaFS Concentration Results E-33
CFS Cumulative Release Results E-43
JaFS Cumulative Release Results E-53
Comparison of Statistics for Study Materials E-63
Method 1314 Precision Estimates E-71
E-i
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
7 .
S
a
3
0
a g
I ^
% • <
i
rg e* |
3 • »T d
i ft DO ^
> A. j
•
L 1
L/S (L/kg)
[_
f
!
0 1C
)0
• M1314CFS-L01-A AM1314 CFS-L01-B BM1314 CFS-L01-C
• M1314 CFS-L06-A A M1314 CFS-L06-B DM1314 CFS-L06-C
• M1314 CFS-L07-A A M1314 CFS-L07-B DM1314 CFS-L07-C
• M1314CFS-L10-A AM1314 CFS-L10-B DM1314 CFS-L10-C
• M1314CFS-L14-A AM1314 CFS-L14-B BM1314 CFS-L14-C
• M1314 CFS-Ref-A A M1314 CFS-Ref-B • M1314 CFS-Ref-C
O M1314 CFS-Ref-D A M1314 CFS-Ref-E DM1314 CFS-Ref-F
Figure 1. Method 1314 eluate pH for material CFS.
E-l
-------
Interlaboratory Validation of LEAF Method 1314 and Method 1315
j1
"oi 0.1 -
|
_c
_3
* 4^°&6
ML
MDL
O1
"S o.i -
^>
>>
=
•^ 001-
<
* 4 j
*^4
D
J ML
' MDL
0.1 1 10 100 0.1 1 10 100
L/S (L/kg) L/S (L/kg)
^ 0.1 •
01
u
'E
-------
Interlaboratory Validation of LEAF Method 1314 and Method 1315
100 -
i ":
1 0.1-
u
0.01 •
« "* ^^ ^ *
i
ML
! MDL
0.1 1 10 1C
L/S (L/kg)
Cobalt (mg/
I § F
•*• I-1 1-
8 n
-I,
1
ML
MDL
-\r-\r-\r-\r-\
,-: o o o c
b P 8
0
(l/6ui) umjuiojio
0
~-l~
at
!_ U.I
&
Q.
O
fi
« on c
.1
4 ^
aona ami «
ML
MDL
•
1 10 100
L/S (L/kg)
rS® Q^ <*
^i
^
ML
MDL
0.1 1 10 100 0.1 1 10 100
L/S (L/kg) L/S (L/kg)
_l U.I
01
c
J; o.oi •
0.001 •
0
Lithium (mg/L)
1 § P
•^ h-1 h-1 h
; A
o
4 ' J&L
ML
8 A n " MDL
ŁH — i — mt-i-v^~mrrmrm— Mnm»-i-nr^ 1 1 — i — i i i 1 1
11 10 1C
L/S (L/kg)
i*ii
W-t(
\
' ML
• MDL
0.1 1 10 1C
L/S (L/kg)
i -
j1
Ol
E 01 -
•a
(0
3
0.01 -
,.-
*»*,<
^
ML
MDL
)0 0.1 ]
• M1314CFS-L01-A A
OM1314CFS-L06-A &
OM1314CFS-L07-A i
OM1314CFS-L10-A i
• M1314CFS-L11-A A
• M1314CFS-L14-A A
• M1314CFS-Ref-A A
oM1314CFS-Ref-D /s
)0
10 100
L/S (L/kg)
M1314 CFS-L01-B
M1314 CFS-L06-B
M1314 CFS-L07-B
M1314 CFS-L10-B
M1314 CFS-L11-B
M1314 CFS-L14-B
M1314 CFS-Ref-B
M1314 CFS-Ref-E
• M1314CFS-L01-C
DM1314 CFS-L06-C
DM1314 CFS-L07-C
DM1314 CFS-L10-C
• M1314CFS-L11-C
• M1314CFS-L14-C
• M1314CFS-Ref-C
DM1314 CFS-Ref-F
Figure 3. Method 1314 eluate concentrations for material CFS measured by ICP-OES.
E-3
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
1000
5 100
01
I 1
M
g 0.1
Ol
^ 0.01
0.001
0.0001
c
Ol
E 0.1 -
Ą
3
c
a)
"o
''l * * *
' ^ ^
• r
y
ML
MDL
5 10-
OI
E ,
•c- 1 •
i
a 01-
01
c
a
0.01 -
i
* ***& D
%^
fc
ML
MDL
).l 1 10 100 0.1 1 10 100
L/S (L/kg) L/S (L/kg)
§
BBS! D5& ?? ML
IC-SIS! 3^L_fg
D
MDL
H**H
_l
Ol
I
U
z
A
i
,
ML
MDL
0.1 1 10 100 0.1 1 10 100
L/S (L/kg) L/S (L/kg)
phorus (mg/L)
I 9
* h-1 h
Q.
A, »
i • •
^ A A a& 4
f ML
ft • "S A* MDL
... - 0
0.1 1 10 1C
L/S (L/kg)
2" 1 -
1
E 0.1 -
'E
W 0.01 -
f
tftj?pi n> ML
A © C* MDL
o on
0.1 1 10 1C
L/S (L/kg)
100 -
5
01 10 -
*~*
1 1'
1 01
3 o.i -
Q.
0.01 -
A
^U
! I
)0 0.1 1 1
L/S (L/kg)
• M1314CFS-L01-A AM1314 CFS-L01-B
• M1314CFS-L06-A AM1314 CFS-L06-B
• M
• M
• M
• M
• M
• M
1314 CFS-L07-A AM1314 CFS-L07-B
1314 CFS-L10-A A M1314 CFS-L10-B
1314 CFS-L11-A A M1314 CFS-L11-B
1314 CFS-Ref-A AM1314 CFS-Ref-B
1314 CFS-Ref-D AM1314 CFS-Ref-E
)0
1
ML
MDL
0 100
• M1314CFS-L01-C
DM1314 CFS-L06-C
DM1314 CFS-L07-C
DM1314 CFS-L10-C
• M1314CFS-L11-C
• M1314CFS-Ref-C
DM1314 CFS-Ref-F
Figure 4. Method 1314 eluate concentrations for material CFS measured by ICP-OES.
E-4
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
^ 1 -
01
I 0.1-
o
55 0.01-
0.
10
^ 1
! 0.1
E
3
'•g 0.01
E
55 0.001
0.0001
c
n
_3
~a
1- 0.01 -
0.
100
10
5 i
01
.§, 0.1
U
c
N 0.01
0.001
0.0001
c
* -» 4
IW "*«
c
ML
MDL
100 -
=L 10-
01
| 1
"§ 0.1 -
0.01 -
€1
^
^^
I
ML
i MDL
1 1 10 100 0.1 1 10 100
L/S (L/kg) L/S (L/kg)
® & t
\
B*"aa<
»
ML
MDL
1000 -
^. 100 -
|* 10 -
"3
0.01 -
« «,
SUJBJ ' "ur gj
F
ML
MDL
.1 1 10 100 0.1 1 10 100
L/S (L/kg) L/S (L/kg)
* A J
V
^
ML
MDL
11 10 1C
L/S (L/kg)
« ^ d
&^^a,
i
ML
MDL
.1 1 10 1C
L/S (L/kg)
O1
* «*»•»»
ML
MDL
)0 0.1 1 1
L/S (L/kg)
• M1314CFS-L01-A i
OM1314CFS-L06-A t
OM1314CFS-L07-A t
OM1314CFS-L10-A t.
• M1314CFS-L11-A t
• M1314CFS-L14-A I
• M1314CFS-Ref-A I
• M1314CFS-Ref-D Ł
IM1314CFS-L01-B
iM1314CFS-L06-B
1M1314CFS-L07-B
1M1314CFS-L10-B
iM1314CFS-Lll-B
kM1314CFS-L14-B
lM1314CFS-Ref-B
iM1314CFS-Ref-E
)0
0 100
• M1314CFS-L01-C
DM1314 CFS-L06-C
DM1314 CFS-L07-C
DM1314 CFS-L10-C
• M1314CFS-L11-C
• M1314CFS-L14-C
• M1314CFS-Ref-C
DM1314 CFS-Ref-F
Figure 5. Method 1314 eluate concentrations for material CFS measured by ICP-OES.
E-5
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
(0 0
UJ
7 .
0
t I 1
I
1 ]
0
||f of |
AJ
*
1
L/S (L/kg)
D
|l
)
)
0 1C
)0
• M1314JaFS-L01-A AM1314 JaFS-LOl-B BM1314 JaFS-LOl-C
OM1314JaFS-L07-A AM1314 JaFS-L07-B DM1314 JaFS-L07-C
OM1314JaFS-L10-A AM1314 JaFS-LlO-B DM1314 JaFS-LlO-C
• M1314 JaFS-Lll-A AM1314 JaFS-Lll-B BM1314 JaFS-Lll-C
• M1314JaFS-L14-A AM1314 JaFS-L14-B BM1314 JaFS-L14-C
• M1314JaFS-Ref-A AM1314 JaFS-Ref-B BM1314 JaFS-Ref-C
OM1314JaFS-Ref-D AM1314 JaFS-Ref-E DM1314 JaFS-Ref-F
Figure 6. Method 1314 eluate pH for material JaFS.
E-6
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Ol
»w
3
C
E
3
! * ^
ML
MDL
Antimony (mg/L)
0.1 1 10 100
L/S (L/kg)
5 o.i -
1
u
'E
u
2 o.oi •
<
ML
MDL
nn m rn 1 1 • u i u 1 1 1 i n 1 1
0.1 -
ML
nn m rn i i • u i 1 1 1 1 1 i n M
0.1 1 10 IOC
L/S (L/kg)
^ 0.1
_1
01
"r" o.oi
_3
a
CD
0.1 1 10 100
L/S (L/kg)
j1
"5 o.oi
_Ł,
E
_3
Ł
ML
MDL
2
a
^
E
&
0.1 1 10 100
L/S (L/kg)
:admium (mg/L
I § f
-1 1— l 1-
0 0001
L-*.
*„
ML
MDL
tt Hu
* ML
MDL
0.1 1 10 IOC
L/S (L/kg)
100
10
I
9 * Q
aBt^
4fc
%
MDL
0.1 1 10 IOC
L/S (L/kg)
• M1314 J
OM1314 J
OM1314 J
OM1314 J
OM1314 J
OM1314 J
• M1314J
OM1314J
aFS-LOl-A »M1314JaFS-L01-B •M1314 JaFS-LOl-C
aFS-L06-A AM1314 JaFS-L06-B OM1314 JaFS-L06-C
aFS-L07-A AM1314JaFS-L07-B DM1314 JaFS-L07-C
aFS-LlO-A AM1314JaFS-L10-B DM1314 JaFS-LlO-C
aFS-Lll-A AM1314JaFS-Lll-B BM1314 JaFS-Lll-C
aFS-L14-A *M1314JaFS-L14-B BM1314 JaFS-L14-C
aFS-Ref-A 4M1314 JaFS-Ref-B BM1314 JaFS-Ref-C
aFS-Ref-D AM1314 JaFS-Ref-E DM1314 JaFS-Ref-F
0.1 1 10 100
L/S (L/kg)
Figure 7. Method 1314 eluate concentrations for material JaFS measured by ICP-OES.
E-7
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
100 -
i ":
"o
~a O-1 '
U
0.01 -
»
$ ftftft ^ o
3
ML
MDL
0.1 1 10 1C
L/S (L/kg)
Cobalt (mg/L)
I § P
3 O O .
ML
MDL
" rn m rn 1 1 • u i n i 1 1 i n 1 1
5 o.i
Ol
E 0.01
g 0.001
0.0001
)0 C
01
I
a.
o
0 0.01 -
ML
MDL
rTTTT, r^^,
.1 1 10 IOC
L/S (L/kg)
O m
ML
MDL
0.1 1 10 100 0.1 1 10 IOC
L/S (L/kg) L/S (L/kg)
Ol
ML
MDL
•3 o.i -
O!
•a
3 n m -
* &st *$ 4
MDL
0.1 1 10 100 0.1 1 10 IOC
L/S (L/kg) L/S (L/kg)
01
•i
0 0001
Ł
m
ML
1 MDL
• M1314
OM1314
OM1314
OM1314
• M1314
• M1314
• M1314
• M1314
JaFS-LOl-A *M1314JaFS-L01-B BM1314 JaFS-LOl-C
]aFS-L06-A a M1314 JaFS-L06-B DM1314 JaFS-L06-C
JaFS-L07-A a M1314 JaFS-L07-B DM1314 JaFS-L07-C
]aFS-L10-A AM1314JaFS-L10-B DM1314 JaFS-LlO-C
JaFS-Lll-A *M1314JaFS-Lll-B BM1314 JaFS-Lll-C
JaFS-L14-A A M1314 JaFS-L14-B BM1314 JaFS-L14-C
JaFS-Ref-A AM1314 JaFS-Ref-B BM1314 JaFS-Ref-C
JaFS-Ref-D AM1314 JaFS-Ref-E DM1314 JaFS-Ref-F
0.1 1 10 100
L/S (L/kg)
Figure 8. Method 1314 eluate concentrations for material JaFS measured by ICP-OES.
E-8
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
^ 10
1 '
1 °-1
'w
V
= 0.01
n
0.001
0.0001
c
1
^ 0.1
J1
Ol
^ 0.01
u
Z
0.001
0.0001
c
j"
O* n -i .
Phosphorus (m
o
b f
h-1 h
ff
I
ML
: MDL
^ 0.1 -
a
a
B
sln
^^ '1S' 33 ML
MDL
.1 1 10 100 0.1 1 10 IOC
L/S (L/kg) L/S (L/kg)
;a
ML
B § MDL
bdenum (mg/L)
1 P
-1 h-1 h
o
• &
4
5E, 04, ML
lp MDL
.1 1 10 100 0.1 1 10 IOC
L/S (L/kg) L/S (L/kg)
o c
ML
MDL
1 I"
a
°~ 0.01 -
* &
"* ^h
ML
MDL
0.1 1 10 100 0.1 1 10 IOC
L/S (L/kg) L/S (L/kg)
"5 o.i -
E.
E
.3
U
l/J
0.001 -
61
§
ML
MDL
1 — | 1 — | 1 —
• M1314 JaFS-LOl-A *M1314JaFS
• M1314 JaFS-L06-A &M1314JaFS
• M1314 JaFS-L07-A AM1314JaFS
• M1314 JaFS-LlO-A AM1314JaFS
• M1314 JaFS-Lll-A *M1314JaFS
• M1314 JaFS-L14-A »M1314JaFS
• M1314JaFS-Ref-A AM1314JaFS
• M1314JaFS-Ref-D AM1314JaFS
-L01-B BMlSWJaFS-LOl-C
-L06-B DM1314 JaFS-L06-C
-L07-B DM1314 JaFS-L07-C
-L10-B DM1314JaFS-L10-C
-Lll-B BMlSWJaFS-Lll-C
-L14-B BM1314JaFS-L14-C
-Ref-B BM1314JaFS-Ref-C
-Ref-E DM1314 JaFS-Ref-F
0.1
1 10 100
L/S (L/kg)
Figure 9. Method 1314 eluate concentrations for material JaFS measured by ICP-OES.
E-9
-------
Interlaboratory Validation of LEAF Method 1314 and Method 1315
1 -
_1
Ol
I 0.1-
O
O
55 o.oi-
*
x> IT] ^^
1.
ML
MDL
100 -
^ 10 -
O>
>-' -i .
Sodium
0.1 1 10 100
L/S (L/kg)
Strontium (mg/L)
IP ~ E
* !->• !->• O C
'»«*;
t
i
ML
MDL
0.1 -
&
a v
ft
^ t
ML
MDL
0.1 1 10 IOC
L/S (L/kg)
100 -
5 10 -
01
Ł
a
0.1 1 10 100
L/S (L/kg)
O)
1
^ 0.01 -
i-
0
10
1
O>
Ł 0.01
N
0.001
0.0001
C
ML
MDL
rn m rn i i • u i n i 1 1 i n 1 1
Vanadium (mg/L)
1 1 10 100
L/S (L/kg)
ft
ft,
-- t
. V- ML-
MDL
0.01 -
0.
1
0.1
0.01
0.001
0.0001
C
** *fc *
ML
MDL
1 1 10 IOC
L/S (L/kg)
&
_• ML
IT ^ f MDL
m i 11 M i iii M i ii 1 1
.1 1 10 IOC
L/S (L/kg)
• M1314 JaFS-LOl-A i M1314 JaFS-LOl-B BM1314 JaFS-LOl-C
OM1314 JaFS-L06-A a M1314 JaFS-L06-B DM1314 JaFS-L06-C
OM1314 JaFS-L07-A a M1314 JaFS-L07-B DM1314 JaFS-L07-C
OM1314 JaFS-LlO-A a M1314 JaFS-LlO-B DM1314 JaFS-LlO-C
• M1314 JaFS-Lll-A A M1314 JaFS-Lll-B BM1314 JaFS-Lll-C
• M1314 JaFS-L14-A A M1314 JaFS-L14-B BM1314 JaFS-L14-C
• M1314JaFS-Ref-A A M1314 JaFS-Ref-B BM1314 JaFS-Ref-C
• M1314JaFS-Ref-D a M1314 JaFS-Ref-E DM1314 JaFS-Ref-F
).l 1 10 100
L/S (L/kg)
Figure 10. Method 1314 eluate concentrations for material JaFS measured by ICP-OES.
E-10
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
3
_C
™
E
|
0
E
3
S
Bromide (mg
p
i-1 i-
0
0
i
0
i
3 •"— -"
i i
L/S (L/kg)
Nr5^4
i i
L/S (L/kg)
1 1 1
L/S (L/kg)
tx^
X^
1 1
L/S (L/kg)
a
ML
LO 1
ML
D 1C
ML
MDL
0 1C
P
>
ML
MDL
D 1C
Ł
g
5
DO 0
E
ra
00
0.001
0 C
o»
C
E
0 0.
0
!>,.
"**§Ł•""'"' ^ ••• ^. ^_
^•flff ^ fi ML
11 10 1C
L/S (L/kg)
1
• ^^ ~~ ~^^^
'I ML
MDL
.1 1 10 10
L/S (L/kg)
^
x^
V
^•t^
"tr~«
T
ML
MDL
11 10 10
L/S (L/kg)
• M1314CFS-Ref-A
A M1314CFS-Ref-B
• M1314CFS-Ref-C
• M1314CFS-Ref-D
A M1314CFS-Ref-E
D M1314CFS-Ref-F
M1313CFS-Ref 95% PL
Figure 11. Method 1314 results for reference laboratory testing of CFS material compared to 95%
prediction limits.
E-ll
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
10 •
G"
o»
Ł1
E
3
E
•a
n
° 0.01 •
0.
1
_ 0.1
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^ 0.01
3
1
U 0.001
0.0001
0
0.1
J1
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E
_3
0 0.001
5
0.0001
0
Lf
E
a.
O
U 0.01 -
0.001 -
J CT -.=^
h
ML
MDL
100 -
i io-
Ą 1 •
_3
'u
ID w. j.
U
0.01 -
* — ^=
f-mm ^~~ C
k
ML
MDL
1 1 10 100 0.1 1 10 1C
L/S (L/kg) L/S (L/kg)
**»^
^t"^
1
ML
MDL
100 -
^ 10 -
•D
| 0.1 -
u
0.01 -
\
\v
N
**fc^-r*
r
1
ML
MDL
.1 1 10 100 0.1 1 10 10
L/S (L/kg) L/S (L/kg)
• • 1
• •• • 1
ML
MDL
•
Cobalt (mg/
i § ?
*^
hx^l
\ X
|
h
»
ML
MDL
.1 1 10 100 0.1 1 10 1C
L/S (L/kg) L/S (L/kg)
*~X>
"'
i
ML
MDL
• M1314CFS-Ref-A
A M1314CFS-Ref-B
• M1314CFS-Ref-C
0 M1314CFS-Ref-D
A M1314CFS-Ref-E
D M1314CFS-Ref-F
M1313CFS-Ref 95% PL
10
100
L/S (L/kg)
Figure 12. Method 1314 results for reference laboratory testing of CFS material compared to 95%
prediction limits.
E-12
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
1
ra
U
o m -
™ j1
It
HH ^>
<1) 1
5
0.1 -
0
5
01
a 0.1
i
0.
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a
ML
MDL
0 1C
h
ML
0 1C
b
ML
MDL
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k
MDL
0 1
c
o
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n
° 10 -
15
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IA
Q
0.1 4
0 0.
^ 0.01
^
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ra °-1
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1
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j
0 0.
30
K
. ^*
Q
ML
MDL
, — | , — | i — I
11 10 10
L/S (L/kg)
: ML
MDL
' •-"--
•
.1 1 10 1C
L/S (L/kg)
K
VfisiTO
xi-/^ -» ML
MDL
11 10 10
L/S (L/kg)
• M1314CFS-Ref-A
A M1314CFS-Ref-B
• M1314CFS-Ref-C
A M1314CFS-Ref-E
M1313CFS-Ref 95% PL
Figure 13. Method 1314 results for reference laboratory testing of CFS material compared to 95%
prediction limits.
E-13
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Ol
0)
s
c n 1
Ol
c
n
0.001 -1
0
«
u
Z
0
G" n 1 -
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|
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1
L/S (L/kg)
^ii
1
1
L/S (L/kg)
1
L/S (L/kg)
fc«f:fci
i
L/S (L/kg)
>
ML
MDL
0 1C
,
1
ML
MDL
0 1C
ML
0 1C
MDL
0 1C
01
U.I
E
3
C
U
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0.001 -1
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5
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a
2 ! i
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Q.
f
Q.
)0 0
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t>
^x
\ .x^0Ł3^~* ML
MDL
11 10 10
L/S (L/kg)
\
\\
xis-
^vl^ ML
* MDL
p
1 10 1C
L/S (L/kg)
ML
MDL
11 10 1C
L/S (L/kg)
• M1314CFS-Ref-A
A M1314CFS-Ref-B
• M1314CFS-Ref-C
0 M1314CFS-Ref-D
A M1314CFS-Ref-E
D M1314CFS-Ref-F
M1313CFS-Ref 95% PL
Figure 14. Method 1314 results for reference laboratory testing of CFS material compared to 95%
prediction limits.
E-14
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
•3
^>
E 1 -
1
3 °'1 '
0.
0.001 -1
0
_1 1
1
U.I
3
c
a
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3
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%
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. v.
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b*»-.
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L/S (L/kg)
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^^
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1
L/S (L/kg)
%.
^*-
L 1
L/S (L/kg)
^ **=»=,
L 1
L/S (L/kg)
L
ML
0 1C
ML
MDL
•
0 1C
ML
MDL
0 1
•
ML
MDL
0 1C
01
3
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0.0001 -
0 0
G" :
1 :
c "-1 !
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0 0.
J1
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•*_-•
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55
0.001
DO C
0
V
NV
^\
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--Stt* ML
.1 1 10 10
L/S (L/kg)
U:=**fc==*=^
ML
LI 10 10
L/S (L/kg)
"= = =*=— *»*^
ML
MDL
.1 1 10 1C
L/S (L/kg)
• M1314CFS-Ref-A
A M1314CFS-Ref-B
• M1314CFS-Ref-C
0 M1314CFS-Ref-D
A M1314CFS-Ref-E
D M1314CFS-Ref-F
M1313CFS-Ref 95% PL
Figure 15. Method 1314 results for reference laboratory testing of CFS material compared to 95%
prediction limits.
E-15
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
1000 - r
2< 100 - r
l_
Ł 1-f
3
"1 0.1 -r
0.01 • f.
*= = _
^^^^ ^^
*""• "~*
1
ML
MUL
0.1 1 10 1C
L/S (L/kg)
^ 0.01 •
01
0
0.01
=5; 0.001
,§
|
S o.oooi
5
0.00001
5 i •
01
E n 1 -
u
c
N 0.01 -
ML
MDL
\ • • ^ — -dm on
1 1 10 1
L/S (L/kg)
ML
MDL
n • — rra •
•
Thallium (mg/L)
3 b P ^ g
0 0.
0.1
J1
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Ł
Ą
i 0.001
1-
0.0001
DO
adium (mg/L)
I 9
-1 h-1 h
5
^
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ML
MDL
11 10 10
L/S (L/kg)
: ML
MDL
0.1 1 10 1C
L/S (L/kg)
ML
~
MDL
D.I 1 10 100 0.1 1 10 10
L/S (L/kg) L/S (L/kg)
•^Ou3
•f**^:^
ML
MDL
• M1314CFS-Ref-A
A M1314CFS-Ref-B
• M1314CFS-Ref-C
• M1314CFS-Ref-D
A M1314CFS-Ref-E
D M1314CFS-Ref-F
M1313CFS-Ref 95% PL
0.1 1 10 100
L/S (L/kg)
Figure 16. Method 1314 results for reference laboratory testing of CFS material compared to 95%
prediction limits.
E-16
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
3
C
'g
0
5 o i -
01
u
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a
2 o.oi •
0.
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3
co o.ooi
0
CT
E
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Cadmium (mg/L)
ills.
0
0.01
^^
^. 0.001
Ol
3 o.oooi
u
0.00001
1
E
X\K
ML
MDL
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_3
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ID w. j.
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0.01 -
*
•*• =
ML
MDL
1 1 10 100 0.1 1 10 1C
L/S (L/kg) L/S (L/kg)
ML
MDL
• •• —
m-mm- — •• — •
D.I 1 10 1C
L/S (L/kg)
ML
MDL
"~ ~ -•--•-•-• - -"--•
0.1 1 10 1C
L/S (L/kg)
o»
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Q.
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N.
1
ML
MDL
•ide (mg/L)
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-1 h-1 O C
5
5
0.01 -
0 0.
1
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^ °-01
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0.001
0.0001
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L/S (L/kg)
• : • • 1
• -•-• — ^ — i
ML
MDL
D
.1 1 10 1C
L/S (L/kg)
• M1314JaFS-Ref-A
A M1314JaFS-Ref-B
• M1314JaFS-Ref-C
0 M1314JaFS-Ref-D
A M1314JaFS-Ref-E
D M1314JaFS-Ref-F
- M1314JaFS-Ref95%PL
0.1 1 10 100
L/S (L/kg)
Figure 18. Method 1314 results for reference laboratory testing of JaFS material compared to 95%
prediction limits.
E-18
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
1
CU
> 1
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0.1
0
5
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a 0.1
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01
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v,
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s
1—
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L/S (L/kg)
r^
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^
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L/S (L/kg)
§a*-^^
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L/S (L/kg)
t
ML
0 1C
ML
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3 1C
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0 0
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<*'***
// ^1-^
// ^
4' ^*
ML
MDL
11 10 10
L/S (L/kg)
ML
MDL
.1 1 10 1C
L/S (L/kg)
*S
v
JŁ ML
"i MDL
T^_
— »-• mt •
.1 1 10 10
L/S (L/kg)
• M1314JaFS-Ref-A
A M1314JaFS-Ref-B
• M1314JaFS-Ref-C
A M1314JaFS-Ref-E
D M1314JaFS-Ref-F
- M1314JaFS-Ref95%PL
Figure 19. Method 1314 results for reference laboratory testing of JaFS material compared to 95%
prediction limits.
E-19
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
G1
,§
cu
1
10
(0
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0.
.2
u
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c
G1
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0.
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1
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%
v,^
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11 10 1C
L/S (L/kg)
! A\ ML
X%. * MDL
.1 1 10 1C
L/S (L/kg)
^
^
^^
s
v
^_ ML
>. MDL
ta _
1= ^
11 10 1C
L/S (L/kg)
•tJ ~i"*"
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: x ~L--^ ML
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MDL
.1 1 10 10
L/S (L/kg)
\
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^^~ B
MDL
LI 10 1C
L/S (L/kg)
ML
MDL
• • »— •-• • •
.1 1 10 1C
L/S (L/kg)
• M1314JaFS-Ref-A
A M1314JaFS-Ref-B
• M1314JaFS-Ref-C
0 M1314JaFS-Ref-D
A M1314JaFS-Ref-E
a M1314JaFS-Ref-F
- M1314JaFS-Ref95% PL
0.1
1 10 100
L/S (L/kg)
Figure 20. Method 1314 results for reference laboratory testing of JaFS material compared to 95%
prediction limits.
E-20
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
5
E i
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|
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0.001 -1
0
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t^_
vi
j
i
L/S (L/kg)
1
L/S (L/kg)
^
Vv
T \
L 1
L/S (L/kg)
**-^~
^
1
L/S (L/kg)
,
'
ML
MDL
0 1C
ML
MDL
0 1C
i
ML
MDL
0 1
L_
ML
MDL
0 1C
J1
E
3
C
§
0.00001
0
G"
"i
C
c °'1
O
•^
n m -
0 0
5 100 -
01
"^ m .
I
(A
DO 0.
0
ML
MDL
m ^—^^.. — .^ _^
1
0.1 1 10 10
L/S (L/kg)
"^^^fc,
! ML
'
11 10 10
L/S (L/kg)
A
\
^^
ML
MDL
11 10 1C
L/S (L/kg)
• M1314JaFS-Ref-A
A M1314JaFS-Ref-B
• M1314JaFS-Ref-C
A M1314JaFS-Ref-E
- M1314JaFS-Ref95% PL
Figure 21. Method 1314 results for reference laboratory testing of JaFS material compared to 95%
prediction limits.
E-21
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
G"
3
•M
55
0.
O»
•*_-•
_n
H 0.001 -
0
o»
•— •
'E
c
G1
oi °'1
•*_-•
" n 01 -
N
0.
X
*«««=*.,
111
L/S (L/kg)
111
L/S (L/kg)
-- ^
\
!
XL
*• — •— •
>.i i i
L/S (L/kg)
*v
^^
^,,
'^
111
L/S (L/kg)
1
ML
MDL
0 1C
ML
MDL
n
0 1
ML
MDL
3
0 1C
1
ML
MDL
0 1C
j1
01 "-1
E
i-
0 0.
J1
01 u.ui
E
•— •
E
i 0.001
1-
DO
0»
•*_-•
3
•c
ra
0 C
0
ML
MDL
11 10 10
L/S (L/kg)
: ML
MDL
-r m---m--m-m+-^m-^m
D.I 1 10 1C
L/S (L/kg)
%
! ML
» iZ
^.B^ MDL
- \^
! ^
.1 1 10 10
L/S (L/kg)
• M1314JaFS-Ref-A
A M1314JaFS-Ref-B
• M1314JaFS-Ref-C
0 M1314JaFS-Ref-D
A M1314JaFS-Ref-E
D M1314JaFS-Ref-F
- M1314JaFS-Ref95% PL
Figure 22. Method 1314 results for reference laboratory testing of JaFS material compared to 95%
prediction limits.
E-22
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
*-*,
Dl
E
o
3
C
E
0.0001 H
0
1 •
J* 0.1 -
01
c
E
3
— n nni -
0 0001 •
0
(C)
•••.
o
3
_C
^ 0.001 •
0.0001 -1
A g| &JJ& J& J
1 1
§
i • Etjr
"^
i i
L/S (L/kg)
: M1314 CFS Between Lab SD
§
d
ML
10 10
• ~~""~@9~ — 6
ML
MDL
1
ML
MDL
3 i ML
E
5 0 001 • - O M1314CFS Ref Mean
! M1314CFSRef95%PL
i • M1314 CFS Median of Lab Means
0.0001 H ' ' — ' — 1 ' ' — ' — 1
0 0.1 1 10
(B, L/S(L/k9)
• M1314CFS-L01-A A M1314 CFS-L01-B • M1314 CFS-L01-C
O M1314CFS-L06-A A M1314 CFS-L06-B D M1314 CFS-L06-C
O M1314CFS-L14-A A M1314 CFS-L14-B • M1314 CFS-L14-C
• M1314CFS-Ref-A A M1314 CFS-Ref-B • M1314 CFS-Ref-C
0 M1314CFS-Ref-D A M1314 CFS-Ref-E • M1314 CFS-Ref-F
M1314 CFS 95% RCL
0
^
Em — " — " ***s- — -a*' \.
•| ' ICP-OESRSD ^*-j
3
M1314 CFS Between Lab CV
0.1
10
0.1
10
(D)
L/S(L/kg)
(E)
L/S (L/kg)
Figure 23. Aluminum concentration in CFS eluate using Method 1314. (A) collected data as a function of L/S;
(B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-23
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
n 1 .
HI-HI
* ° ;
(l/Bui) ulnueg
u.uui -
__ r
fl SB i
!
0.0001 1 i
0.1
(A)
1 -
01
3
•c
IB
CO
0.0001 -
f
»
ML
MDL
| 1 | |
L 10 100
L/S (L/kg)
rTf
B.,— a
1
ML
MDL
Barium (mg/L)
i g P
>• h-1 h-1 1-
u.uui -
C.~-f^
O M1314 CFS Ref Mean
M1314CFSRef95%P
• M1314 CFS Median d
ML
L
Lab Means
CL
0.1 1 10
L/S (L/kg)
D)
• M1314CFS-L01-A A M1314 CFS-L01-B • M1314 CFS-L01-C
0 M1314CFS-L06-A A M1314 CFS-L06-B D M1314 CFS-L06-C
0 M1314CFS-L07-A A M1314 CFS-L07-B D M1314 CFS-L07-C
O M1314CFS-L10-A A M1314 CFS-L10-B D M1314 CFS-L10-C
0 M1314CFS-L11-A A M1314 CFS-L11-B D M1314 CFS-L11-C
• M1314CFS-L14-A A M1314 CFS-L14-B D M1314 CFS-L14-C
• M1314CFS-Ref-A A M1314 CFS-Ref-B • M1314 CFS-Ref-C
0 M1314CFS-Ref-D A M1314 CFS-Ref-E • M1314 CFS-Ref-F
M1314CFS95%RCL
0.1
(C)
01
^>
E
3
10
L/S (L/kg)
n m -
0.001 -
nnm .
^n ^^ >y^^S» ^^ ^^ ^^ ^^ ~^^
^*^^SsJJ^By**
.
ML
MDL
M1314 CFS Between Lab Sd
M1314 CFS Within Lab SD
• M1314 CFS Mean
i .
100
10 -:
M1314CFS Overall CV
M1314 CFS Between Lab CV
M1314 CFS Within Lab CV
0.1
10
0.1
10
(D)
L/S (L/kg)
(E)
L/S (L/kg)
Figure 24. Barium concentration in CFS eluate using Method 1314. (A) collected data as a function of L/S; (B)
reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-24
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
15 m -
g o.Ol •
o
CO
€ A
\
' ML
MDL
C
o.oi ML
CO
0 M1314 CFS Ref Mean
• M1314 CFS Median of Lab Means
• M1314CFS95%RCL
0.1 1 10 100 0.1 1 10
L/S (L/kg) L/S (L/kg)
n nnm •
ML
MDL
• M1314CFS-L01-A A M1314 CFS-L01-B • M1314 CFS-L01-C
O M1314CFS-L06-A A M1314 CFS-L06-B D M1314 CFS-L06-C
O M1314CFS-L07-A A M1314 CFS-L07-B D M1314 CFS-L07-C
O M1314CFS-L10-A A M1314 CFS-L10-B D M1314 CFS-L10-C
' • M1314CFS-L11-A A M1314 CFS-L11-B • M1314 CFS-L11-C
• M1314CFS-L14-A A M1314 CFS-L14-B • M1314 CFS-L14-C
• M1314CFS-Ref-A A M1314 CFS-Ref-B • M1314 CFS-Ref-C
0 M1314CFS-Ref-D A M1314 CFS-Ref-E • M1314 CFS-Ref-F
M1314 CFS 95% RCL
0.1 1 10
, L/S (L/kg)
J*
I "-1'
2 o.oi •
Ł
0.001 •
0.0001 -1
^*^
1 *^
[ ML
'• • M1314 CFS Mean
U 10 - • ~~ ~~ i
E • ICP-OESRSD "*V , '
O — •'Z*'
— M1314 CFS Overall CV
M1314 CFS Between Lab CV
(D)
0.1
10
0.1
10
L/S(L/kg)
(E)
L/S(L/kg)
Figure 25. Boron concentration in CFS eluate using Method 1314. (A) collected data as a function of L/S; (B)
reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-25
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dl
E1 .
E
"8
o
0
)
100 •
10 •
E1 .
E
•o
(0
n nm •
0
)
m -
-i
*-*,
Ł1 .
c
E °'1
•o
(0
u
0
$ t*
^^a ^
MDL
1 1 10 10
L/S (L/kg)
i
^"^
ML
MDL
1 1 1
L/S (L/kg)
teaa*^^
*^^' ajBL— -^-^^^"*B-jMU^^—
~~'"*"*s*
: M1314 CFS Within Lab SD
i • M1314 CFS Mean
MDL
1 1 1
L/S (L/kg)
01
Ł1 - •
E ; O M1314 CFS Ref Mean
'Ł 01 •• ™~ — M1314CFS Ref95%PL
.| i • M1314 CFS Median of Lab Means
n m - . ML
MDL
0 0.1 1 10
(B) L/S(L/k9)
• M1314CFS-L01-A A M1314 CFS-L01-B • M1314 CFS-L01-C
O M1314CFS-L06-A A M1314 CFS-L06-B D M1314 CFS-L06-C
O M1314CFS-L07-A A M1314 CFS-L07-B D M1314 CFS-L07-C
O M1314CFS-L10-A A M1314 CFS-L10-B D M1314 CFS-L10-C
• M1314CFS-L11-A A M1314 CFS-L11-B • M1314 CFS-L11-C
• M1314CFS-L14-A A M1314 CFS-L14-B • M1314 CFS-L14-C
• M1314CFS-Ref-A A M1314 CFS-Ref-B • M1314 CFS-Ref-C
0 M1314CFS-Ref-D A M1314 CFS-Ref-E • M1314 CFS-Ref-F
M1314 CFS 95% RCL
0
: M1314 CFS Overall CV
'. M1314 CFS Between Lab CV
1
> ^ — .^^^^
& ^" • „ f~~ *" *"*•«•„
.E "~~~"\ v*' ^
E _ lcŁ;9 ES RSD \_ jŁt'—. -
~a
0
0 0.1 1 10
L/S (L/kg)
(D)
Figure 26. Cadmium concentration in CFS eluate using Method 1314. (A) collected data as a function of L/S;
(B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-26
-------
Interlaboratory Validation of LEAF Method 1314 and Method 1315
Calcium (mg/L)
5 P o C
3 O . I-* O C
i l_i l_i l_i O O C
• * '|W ** *
i
[
'
ML
MDL
J*
oi 10
o
| : • M1314 CFS Ref Mean
'o M1314CFSRef95%P
15 0.1 -j f M1314 CFS Median of
^^__^^^^^^^^^^^^^^^^^^^^^^ 1
^^P^^^^^^^™ ^^^J.^^" U 1
L
Lab Means
MDL
0.1 1 10 100 0.1 1 10
L/S (L/kg) L/S (L/kg)
) (B)
3 O i-l i-l i-l i-
3 1-1 _; o c
° 0- c
(T/Bui) uinpieo
B==i E
[
r
ML
MDL
0 M1314CFS-L07-A A M1314CFS-LO
• M1314CFS-L10-A A M1314CFS-L1
0 M1314CFS-L11-A A M1314CFS-L1
0 M1314CFS-L14-A A M1314CFS-L1
• M1314CFS-Ref-A A M1314CFS-Re
0 M1314CFS-Ref-D A M1314CFS-Re
M1314 CFS 95% RCL
0.1 1 10
, L/S (L/kg)
Calcium (mg/L)
3 P 0 C
DO. I-1 O C
j. l_i l_i l_i O O C
i ^^ _-^_ . — . —
!
i
M1314 CFS Overall SD
r M1314 CFS Between L
• M1314 CFS Mean
r
SD
ML
MDL
: M1314 CFS Overall CV
M1314 CFS Between Lab
1-B • M1314CFS-L01-C
6-B D M1314 CFS-L06-C
7-B D M1314 CFS-L07-C
0-B D M1314CFS-L10-C
1-B • M1314CFS-L11-C
4-B • M1314CFS-L14-C
f-B • M1314 CFS-Ref-C
f-E • M1314 CFS-Ref-F
CV . .
/
> , ^
C • ^ j
3 V.-
•„ ' ICP-OESRSD
-*•
ra '^
"""" V x--1
0.1 1 10 0.1 1 10
L/S (L/kg) |ci L/S (L/kg)
(D)
Figure 27. Calcium concentration in CFS eluate using Method 1314. (A) collected data as a function of L/S;
(B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-27
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
(A)
(C)
(D)
10
^ 1 -
"Si
.
5
0.01
0.001
0.1
10
Ci
Q.
5
0.1 •
0.01 -r-
0.001
0.1
01
^>
I
a.
8
•4-
4-
1 10
L/S (L/kg)
L/S (L/kg)
0.1
L/S (L/kg)
_ML_
MDL
100
_ML
MDL
10
0.01 •
.001 •
^SXEIXDSS^
ML
i M1314 CFS Overall SD
M1314 CFS Between Lab SD MDL
• M1314 CFS Mean
10
10 -F
^N
" '\/x!
M1314 CFS Between Lab CV
M1314 CFS Within Lab CV
0.1
10
(E)
L/S (L/kg)
Figure 28. Copper concentration in CFS eluate using Method 1314. (A) collected data as a function of L/S; (B)
reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-28
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
1 •
Dl
E 0.1 •
•o
0.01 •
:.,«.-,
)
"
ML
MDL
0.1 1 10 100
,A, L/S(L/k«>
10 •
1 •
01
E 01
•o
_i
0.01 •
0.001 -
r CUIJ
I It
i i
l^—1^- -^
ML
1 -
"Si
E 0.1 •
0.01 -
' •
• M1314 CFS Ref Mean
• M1314 CFS Median of
= = *i==ll
ML
Lab Means
0.001 -I • • — • — i —
0.1 1
L/S (L/kg)
D)
• M1314CF
O M1314CF
0 M1314CF
O M1314CF
• M1314CF
• M1314CF
• M1314CF
0 M1314CF
M1314CF
5-L01-A A M1314 CFS-LO
5-L06-A A M1314 CFS-LO
5-L07-A A M1314 CFS-LO
5-L10-A A M1314CFS-L1
5-L14-A A M1314CFS-L1
5-Ref-A A M1314 CFS-Re
5-Ref-D A M1314 CFS-Re
5 95% RCL
1-B •
6-B D
7-B D
0-B D
1-B •
4-B •
f-B •
f-E D
MDL
10
M1314CFS-L01-C
M1314 CFS-L06-C
M1314 CFS-L07-C
M1314CFS-L10-C
M1314CFS-L11-C
M1314CFS-L14-C
M1314 CFS-Ref-C
M1314 CFS-Ref-F
(C)
(D)
0.1
10
L/S (L/kg)
1 •
Ol
E 0.1 •
•o
0.01 •
n nni .
_____
ML
i — M1314 CFS Overall SD
M1314 CFS Between Lab SD
• M1314 CFS Mean
MDL
i
•o
1 -
M1314 CFS Between Lab CV
M1314 CFS Within Lab CV
^^r^
_ '.cŁ;9 ES RSD. _ _ *^<
"- „
/' \
\
\
\
V
0.1
10
0.1
10
L/S (L/kg)
(E)
L/S (L/kg)
Figure 29. Lead concentration in CFS eluate using Method 1314. (A) collected data as a function of L/S; (B)
reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-29
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Molybdenum (mg/L)
o
b p
h-1 h-1
0.001 -
0
(A)
1 •
^
Oi
E 0.1 -
Molybdenum
o
b
t-*
0.001 •
f
^^S
1 1
? ML
D
MDL
1 ' — 1
10 10
L/S (L/kg)
; •CI
ML \ I
MDL
hn
— •"••
jfi^^
1
-^^B
1
Molybdenum (mg/L)
o
b p
h-1 h-1
0.001 -1
0 0
O M1314 CFS Ref Mean
M1314CFSRef95%PL
• M1314 CFS Median of Lab Means
^^-\
ML ^^.5 33QC ^*- — 3
MDL
1 1 10
L/S (L/kg)
D)
• M1314CFS-L01-A A M1314 CFS-L01-B • M1314 CFS-L01-C
• M1314CFS-L06-A A M1314 CFS-L06-B D M1314 CFS-L06-C
O M1314CFS-L07-A A M1314 CFS-L07-B D M1314 CFS-L07-C
0 M1314CFS-L10-A A M1314 CFS-L10-B D M1314 CFS-L10-C
• M1314CFS-L11-A A M1314 CFS-L11-B D M1314 CFS-L11-C
• M1314CFS-L14-A A M1314 CFS-L14-B D M1314 CFS-L14-C
• M1314CFS-Ref-A A M1314 CFS-Ref-B • M1314 CFS-Ref-C
• M1314CFS-Ref-D A M1314 CFS-Ref-E • M1314 CFS-Ref-F
M1314 CFS 95% RCL
0.1
(C)
01
**>
E
i
s
•5
0.1 -;
0.01
ML
MDL
0.001
0.1
(D)
10
L/S (L/kg)
100
M1314 CFS Overall SD
M1314 CFS Between Lab SD
M1314 CFS Within Lab SD
• M1314 CFS Mean
Molybdenum CV (%)
10 -: —
ICP-OESRSD
'—:J
M1314 CFS Overall CV
M1314 CFS Between Lab CV
M1314 CFS Within Lab CV
10
0.1
10
L/S (L/kg)
(E)
L/S (L/kg)
Figure 30. Molybdenum concentration in CFS eluate using Method 1314. (A) collected data as a function of
L/S; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL
intervals (red lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed
line) and pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall",
"between lab" and "within lab" standard deviation compared to 5% marker indicating a generalized analytical
uncertainty.
E-30
-------
Interlaboratory Validation of LEAF Method 1314 and Method 1315
Ol
Thallium
! g F
* I-* i-
f
* ^di.
$
ML
"~
MDL
0.1 1
L/S(I
O 1 '
Dl
Thallium
1 g F
-•• h-1 1-
^^-tec,
,— > i ^*^^^*^r"'**'^L. —
I ^^^
T5 ML
jE 001 ° M1314 CFS Ref Mean
: M1314CFSRef95%PL MDL
• M1314CFS Median of Lab Means
1
10 100 0.1 1 10
-/kg) L/S (L/kg)
(D)
"^^
M
MDL
• M1314CFS-L01-A A M1314 CFS-L01-B • M1314 CFS-L01-C
O M1314CFS-L06-A A M1314 CFS-L06-B D M1314 CFS-L06-C
0 M1314CFS-L07-A A M1314 CFS-L07-B D M1314 CFS-L07-C
O M1314CFS-L10-A A M1314 CFS-L10-B D M1314 CFS-L10-C
• M1314CFS-L14-A A M1314 CFS-L14-B • M1314 CFS-L14-C
• M1314CFS-Ref-A A M1314 CFS-Ref-B • M1314 CFS-Ref-C
M1314 CFS 95% RCL
0.1 1 10
L/S (L/kg)
1
Ol
Thallium
1 g F
* I-* i-
«*=-_.
"^=*1
""^"v^.
ML
• M1314 CFS Mean
0.1
L/S(
=hcn MDL
SD
M1314 CFS Between Lab CV
S0
01"
> ^~~~~~~~. S\.
° """'--•^ S^ \ ^
1 g 10 • : __ -"*--.,.> ^^^*/^
•= ' ICP-OES RSD N_^ ,'
f :
L 10 0.1 1 10
L/kg) |ci L/S (L/kg)
(D)
Figure 31. Thallium concentration in CFS eluate using Method 1314. (A) collected data as a function of L/S;
(B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-31
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
100 •
^i 1 -
! « «<
IOT
*«
i
ML
T MDL
0.1
(A)
100 •
^5 i -
N o.oi •
0.0001 •
L 10 100
L/S (L/kg)
1 1
r
r*FF
MDL
100 -
Ol 1 -
"o" 0.1 -
N o.oi -
!
»•- — .Ł_ ,fm _ _ — •
0 M1314 CFS Ref Mean
M1314CFSRef95%F
• M1314 CFS Median o
SSlGESS*=^,
L
flab Means
ML
MDL
0.1 1
L/S (L/kg)
D)
10
• M1314CFS-L01-A A M1314 CFS-L01-B • M1314 CFS-L01-C
• M1314CFS-L06-A A M1314 CFS-L06-B D M1314 CFS-L06-C
0 M1314CFS-L07-A A M1314 CFS-L07-B D M1314 CFS-L07-C
O M1314CFS-L10-A A M1314 CFS-L10-B D M1314 CFS-L10-C
0 M1314CFS-L11-A A M1314 CFS-L11-B D M1314 CFS-L11-C
• M1314CFS-L14-A A M1314 CFS-L14-B D M1314 CFS-L14-C
• M1314CFS-Ref-A A M1314 CFS-Ref-B • M1314 CFS-Ref-C
0 M1314CFS-Ref-D A M1314 CFS-Ref-E • M1314 CFS-Ref-F
M1314 CFS 95% RCL
(C)
(D)
0.1
10
L/S (L/kg)
"o" 0.1 •
N o.oi •
n nnm .
"*™""**-— <
• M1314 CFS Mean
)
LabSD
bSD
ML
MDL
I
0 10 -
u
1 .
_
****S
M1314 CFS Between Lab CV
1 — ^»
' ICP-OESRSD *x
*- — —
0.1
10
0.1
10
L/S (L/kg)
(E)
L/S (L/kg)
Figure 32. Zinc concentration in CFS eluate using Method 1314. (A) collected data as a function of L/S; (B)
reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-32
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
j" 01-
01
c
E
3
0.0001 H
0
(A)
J* 0.1 -
Oi
E
C
E
3
— n nm -
0
(C)
*-*,
Dl
o
3
_C
0
* * ft
S1^ q^ "Ei
D ML
MDL
11 10 10
L/S (L/kg)
ML a
MDL
1 1 1
L/S (L/kg)
M1314JaFS Between Lab SD
• M1314JaFSMean
^•fcSlfr-
ML
""
MDL
1 1 1
L/S (L/kg)
^ n 1 - —-~_^
^ ^^-=-*-*^H5|!S^ i
3 ML
E
•j Hni
M1314JaFS Ref 95% PL
• M1314JaFS Median of Lab Means
0.0001 -1 ' ' — ' — 1 ' ' — ' — 1
0 0.1 1 10
(B, L/S(L/k9)
• M1314JaFS-L01-A A M1314JaFS-L01-B • M1314 JaFS-LOl-C
O M1314JaFS-L06-A A M1314JaFS-L06-B D M1314 JaFS-L06-C
O M1314JaFS-L07-A A M1314JaFS-L07-B O M1314 JaFS-L07-C
0 M1314JaFS-L10-A A M1314JaFS-L10-B D M1314 JaFS-LlO-C
• M1314 JaFS-Lll-A A M1314JaFS-Lll-B D M1314 JaFS-Lll-C
• M1314JaFS-L14-A A M1314JaFS-L14-B Q M1314 JaFS-L14-C
• M1314JaFS-Ref-A A M1314JaFS-Ref-B • M1314 JaFS-Ref-C
• M1314JaFS-Ref-D A M1314JaFS-Ref-E D M1314 JaFS-Ref-F
M1314JaFS95%RCL
0
100 -r 1
' M1314JaFS Between Lab CV
^ X^
b — -^"""^n^>^ *^^7^
Em -• . — * *•» / ***"
~ ' ICP-OESRSD 1 /
I ~\ /
! ,7
i ,1 1
0 0.1 1 10
L/S (L/kg)
Figure 33. Aluminum concentration in JaFS eluate using Method 1314. (A) collected data as a function of L/S;
(B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-33
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
j" °'1
E
3
0
(A)
G"
01
_3
(0
0
(C)
1 -
^> o-i •
01
E
.E
IS
CO
0.001 •
0.0001 -1
0
tti a
^ &
ML
MDL
11 10 10
L/S (L/kg)
ML
MDL
1 1 1
L/S (L/kg)
a^, ,_
~~*t:5^^
"**SrS,
ML
Mm
M1314 JaFS Between Lab SD
M1314 JaFS Within Lab SD
• M1314 JaFS Mean
1 1 1
L/S (L/kg)
S ' ^^'^•^^^•••S.
1 ^^^J
Ł • ML |
'C
M1314JaFS95%PL
: D M1314 JaFS Median of Lab Means
0 0.1 1 10
(B) L/S(L/k9)
• M1314JaFS-L01-A A M1314JaFS-L01-B • M1314 JaFS-LOl-C
O M1314JaFS-L06-A A M1314JaFS-L06-B D M1314 JaFS-L06-C
O M1314JaFS-L07-A A M1314JaFS-L07-B D M1314 JaFS-L07-C
O M1314JaFS-L10-A A M1314JaFS-L10-B D M1314 JaFS-LlO-C
• M1314JaFS-L14-A A M1314JaFS-L14-B D M1314 JaFS-L14-C
• M1314JaFS-Ref-A A M1314JaFS-Ref-B • M1314 JaFS-Ref-C
O M1314JaFS-Ref-D A M1314JaFS-Ref-E D M1314 JaFS-Ref-F
M1314JaFS95%RCL
0
100 T 1
: - M1314JaFS Overall CV
' M1314JaFS Between Lab CV
^->
? ^^^yy "
Ł 10-. ^ x ^, .
I _,--: .
g • .*'' ICP-OES RSD
0 0.1 1 10
L/S (L/kg)
Figure 34. Barium concentration in JaFS eluate using Method 1314. (A) collected data as a function of L/S;
(B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-34
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
100 •
Ol 1
Ł '
C n ! .
0 0.1
o
ffl 0.01 -
r [y jB
0.1
(A)
100 •
2< 10 •
01 ,
.§ '
c n 1 .
0 0.1
o
ffl 0.01 •
r
l^
*
1
L
L/S (L/kg)
^i
^
L
6
ML
MDL
10 10
5
^
MDL
0.1
(C)
1000 T
100 -
w
E 1 '
| o,.
o
ffl 0.01 •
n nnm .
«*•»•*»
1
L/S (L/kg)
"^
M1314JaF
r M1314JaF
M1314JaF
• M1314JaF
S Overall S
S Between
S Within La
S Mean
1UUU
100
^ 10
01 i
ffl 0.01
0.001
0.0001
0
(B)
• M1314J3
• M1314J3
• M1314J3
0 M1314J3
' 0 M1314J3
• M1314J3
• M1314J3
• M1314J3
M1314J3
10
mn
^
D
LabSD
bSd
*»
"*tt*'Va
^*Sass_
^
ML
MDL
-
0 10 -•
§ :
1 .
!
^^^
^^5^_
• M1314JaFSRefMean
— ^M1314JaFS Ref 95% PL
• M1314JaFS Median of Lab Means
M1314JaFS95%RCL ...
MDL
0.1 1 10
L/S (L/kg)
FS-LOl-A A M1314JaFS-L01-B • M1314 JaFS-LOl-C
FS-L06-A A M1314JaFS-L06-B D M1314 JaFS-L06-C
FS-L07-A A M1314JaFS-L07-B D M1314 JaFS-L07-C
FS-L10-A A M1314JaFS-L10-B D M1314 JaFS-LlO-C
FS-L11-A A M1314JaFS-Lll-B D M1314 JaFS-Lll-C
FS-L14-A A M1314JaFS-L14-B Q M1314 JaFS-L14-C
FS-Ref-D A M1314JaFS-Ref-E D M1314 JaFS-Ref-F
FS 95% RCL
M1314JaFS Overall CV
M1314JaFS Between Lab CV
'*!>5V <^^
** * ^**
+* ^ *
CP-OESRSD """*--.. .'
0.1
10
0.1
10
(D)
L/S (L/kg)
(E)
L/S (L/kg)
Figure 35. Boron concentration in JaFS eluate using Method 1314. (A) collected data as a function of L/S; (B)
reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-35
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
100 -
f-^
^i 10 '
E
^>
1 "•
0.01 •
1
J
[
a HDCP
rp O
d
ML
1 MDL
0.001 -1 • — 1 ' — 1 ' — 1
0.1 1 10 100
L/S (L/kg)
1 \
3 O i-l i-l i-l i-
3 1-1 _; o c
° ci =
(l/6ui) uinpieo
BV^
r \
!
|
!^i
r
r-R=R
1 CD 0
• — -m — n
ML
MDL
1
1
Calcium (mg/L)
P o - =
0 P I-L 0 C
h-L h-L h-L O O C
0 001 -
^"\
^^^*=3C=«=E3,I
O M1314 JaFS Ref Mean
M1314JaFS Ref 95% PL
• M1314 JaFS Median of Lab Means
M1314 JaFS 95% RCL
MDL
0.1 1 10
L/S (L/kg)
D)
• M1314JaF
O M1314JaF
O M1314JaF
0 M1314JaF
0 M1314JaF
• M1314JaF
• M1314JaF
• M1314JaF
S-L01-A A M1314JaFS-L01-B • M1314 JaFS-LOl-C
S-L07-A A M1314JaFS-L07-B O M1314 JaFS-L07-C
S-L10-A A M1314JaFS-L10-B D M1314 JaFS-LlO-C
S-L11-A A M1314JaFS-Lll-B D M1314 JaFS-Lll-C
S-L14-A A M1314JaFS-L14-B Q M1314 JaFS-L14-C
S-Ref-A A M1314JaFS-Ref-B • M1314 JaFS-Ref-C
S 95% RCL
0.1
(C)
E
3
|o
5
10
L/S (L/kg)
100 •
10 •
1 •
0.1 •
0.01 -
nm .
r
r
r
;
•
"*^
M1314 JaFS Overall SC
M1314 JaFS Between
• M1314 JaFS Mean
— ~«
abSD
DSD
ML
MDL
100 T
E
3
|o
IS
u
10 -:
• ICP-OESRSD
M1314 JaFS Overall CV
-- M1314 JaFS Between Lab CV
----- M1314 JaFS Within Lab CV
^F
0.1
10
0.1
10
(D)
L/S (L/kg)
(c)
L/S (L/kg)
Figure 36. Calcium concentration in JaFS eluate using Method 1314. (A) collected data as a function of L/S;
(B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-36
-------
Interlaboratory Validation of LEAF Method 1314 and Method 1315
j"
E
Q.
" nm -
g
1 St
Ł
o
3gl
•B 1
r
ML
MDL
0.1
(A)
:? 1 '
a
E
|
" nm
1
1 P^
L
01
^^ n 1 -
L. U-1
&
Q.
O
0 nm -
&-^-_
^^^v^^^^
^V^~- — "Tt***^.
•^^-a.
O M1314 JaFS Ref Mean
M1314JaFSRef95%PL |v|DL
• M1314 JaFS Median of Lab Means
10 100 0.1 1 10
L/S (L/kg)
fc-j
v|
N
Ml
^s
(B, L/S(L/k9)
v
^-^.
tfl
^ — i
M
MDL
0.1
L
• M1314JaFS-L01-A A M1314JaFS-L01-B • M1314 JaFS-LOl-C
• M1314JaFS-L06-A A M1314JaFS-L06-B O M1314 JaFS-L06-C
• M1314JaFS-L07-A A M1314JaFS-L07-B D M1314 JaFS-L07-C
• M1314JaFS-L10-A A M1314JaFS-L10-B D M1314 JaFS-LlO-C
• M1314 JaFS-Lll-A A M1314JaFS-Lll-B D M1314 JaFS-Lll-C
• M1314JaFS-L14-A A M1314JaFS-L14-B D M1314 JaFS-L14-C
• M1314JaFS-Ref-A A M1314 JaFS-Ref-B • M1314 JaFS-Ref-C
• M1314JaFS-Ref-D A M1314 JaFS-Ref-E D M1314 JaFS-Ref-F
M1314JaFS95%RCL
10
L/S (L/kg)
(D)
01
.
*
0.01 •
*a^**saa^
Ml
M1314 JaFS Between Lab SD MDL
" M1314 JaFS Within Lab SD
• M1314 JaFS Mean
Copper CV (%)
h-
!-•• C
-•• o c
^^^^
""•-«.«
1 ICP-OESRSD
^.-Ł^3 "*
'%V», .--•'**" *"*">'
M1314 JaFS Overall CV
' M1314 JaFS Between Lab CV
M1314 JaFS Within Lab CV
0.1
10
0.1
10
L/S (L/kg)
(E)
L/S (L/kg)
Figure 37. Copper concentration in JaFS eluate using Method 1314. (A) collected data as a function of L/S;
(B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-37
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
o n 1 •
Dl
•o
^ 0.01 -
' f * I
0.1
)
j* 0.1 •
01
Ł
•o
.3 o.oi -
n nm .
>*lt
L
L/S(I
_ •
^^
ML
4 1
r ML
MDL
10 100
-/kg) (
^ts
^=n
~*L\
;MDL
o n 1 -
I
•o
JS o.oi -
^™ II M~ ^^^^^
^Q^^l
: |y|pL 1
: 0 M1314 JaFS Ref Mean
M1314JaFSRef95%PL
D M1314 JaFS Median of Lab Means
0.1 1 10
• M1314JaFS-L01-A A M1314JaFS-L01-B • M1314 JaFS-LOl-C
• M1314JaFS-L06-A A M1314JaFS-L06-B O M1314 JaFS-L06-C
• M1314JaFS-L07-A A M1314JaFS-L07-B D M1314 JaFS-L07-C
• M1314JaFS-L10-A A M1314JaFS-L10-B D M1314 JaFS-LlO-C
• M1314JaFS-Lll-A A M1314JaFS-Lll-B D M1314 JaFS-Lll-C
• M1314JaFS-L14-A A M1314JaFS-L14-B D M1314 JaFS-L14-C
• M1314JaFS-Ref-A A M1314 JaFS-Ref-B • M1314 JaFS-Ref-C
• M1314JaFS-Ref-D A M1314 JaFS-Ref-E D M1314 JaFS-Ref-F
M1314JaFS95%RCL
0.1
(C)
10
L/S (L/kg)
j* 0.1 •
01
•o
j 0.01 -
' ML
: MUL
"*"""" ^cT-=*-j
^""-ss-J
^M1314 JaFS Overall SD
M1314 JaFS Between LabSD
M1314 JaFS Within LabSD
• M1314 JaFS Mean
o
1
: M1314JaFS Overall CV
! — —M1314JaFS Between LabCV
• M1314JaFS Within LabCV
^xr=rrr)
^ ^^
• "^- ^ / **
x ,s ^/
• ICP-OESRSD •^.^•^
0.1 1 10 0.1 1 1
, L/S(L/kg) (E) L/S(L/kg)
Figure 38. Lead concentration in JaFS eluate using Method 1314. (A) collected data as a function of L/S; (B)
reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-38
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Magnesium (mg/L)
I P 0
D 0 P h-L C
-L h-L h-L h-L O C
ff
A,
*(
0.1
(A)
J*
W -1
Ł
1
= 0.01 -
(0
n nnm .
^
[ \
"»*i
1
*_
•
MDL
Magnesium (mg/L)
5 b P 0
3 0 0 P h-L C
L L_L h-L h-L h-L O C
^^^X-
^^fcs^^
^ ^-
M1314JaFSRef95%
• M1314JaFS Mediant
M1314JaFS95%RCL
1
PL
f Lab Means
L 10 100 0.1 1
L/S (L/kg) L/S (L/kg)
(B)
^
i~~l~f — S-^|
ML
MDL
• M1314JaFS
• M1314JaFS
• M1314JaFS
• M1314JaFS
• M1314JaFS
0 M1314JaFS
• M1314JaFS
• M1314JaFS
M1314JaFS
-L01-A A M1314JaFS-LO
-L07-A A M1314JaFS-LO
-L10-A A M1314JaFS-Ll
-L14-A A M1314JaFS-Ll
-Ref-A A M1314JaFS-Re
-Ref-D A M1314JaFS-Re
95% RCL
1-B • b
6-B n h
7-B D ^
0-B D ^
1-B D h
4-B D ^
f-B • b
f-E n ^
MDL
10
/I1314J3FS-L01-C
/!1314JaFS-L07-C
/!1314JaFS-L10-C
/I1314J3FS-L14-C
/!1314JaFS-Ref-C
/11314 JaFS-Ref-F
(C)
(D)
0.1
Magnesium (mg
10
L/S (L/kg)
10 •
m -
\*.,
' M1314 JaFS Between Lab SD
• M1314 JaFS Mean
-~^
ML
MDL
100 T
E
3
|
Ol
IS
10-:
.....
ICP-OES RSD
M1314 JaFS Overall CV
-- M1314 JaFS Between Lab CV
----- M1314 JaFS Within Lab CV
H^
0.1
10
0.1
10
L/S (L/kg)
(E)
L/S (L/kg)
Figure 39. Magnesium concentration in JaFS eluate using Method 1314. (A) collected data as a function of
L/S; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL
intervals (red lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed
line) and pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall",
"between lab" and "within lab" standard deviation compared to 5% marker indicating a generalized analytical
uncertainty.
E-39
-------
Interlaboratory Validation of LEAF Method 1314 and Method 1315
ganese (mg/L)
1 P
-•• h-1 1-
(0
B
; Ii
1
4
1
ML
MDL
0.1 1
,
i •
Manganese (m
I g =
•*• h-1 1-
10
'S (L/kg)
8\
\
ML
' MDL
vl
\
O IV
IV
T ^\ " "
^ \^V
W n i . . ^ ^^.
E 01 \\^— •
^ X C*^
w \.\
8 \
IB \N
01 n m - . \ *
C U'U1 : \
IB :ML N
Z , ~
MDL
1314 JaFS Ref Mean
1314 JaFS Ref 95% PL
1314JaFS Median of Lab Means
1314 JaFS 95% RCL
s" • t ^— *
— - — — °* E
s. _^~~~-^l~V*i«c^
I
100 0.1 1 10
,„ L/S
m
^^.
i
0.1 1
} L/S (L/kg)
1 _
Manganese (mg/L)
i g P
i h-i h-i h
r^
ML
M1314J
M1314J
•
.^••i
-M1314J
M1314J
aFS Overa
aFS Betwe
aFS Withi
aFS Mean
^-^ffCT.
• M1314JaFS-L01-A A M1314JaFS-L01-B • M1314 JaFS-LOl-C
O M1314JaFS-L06-A A M1314JaFS-L06-B D M1314 JaFS-L06-C
O M1314JaFS-L07-A A M1314JaFS-L07-B D M1314 JaFS-L07-C
0 M1314JaFS-L10-A A M1314JaFS-L10-B D M1314 JaFS-LlO-C
• M1314JaFS-Lll-A A M1314JaFS-Lll-B D M1314 JaFS-Lll-C
• M1314JaFS-L14-A A M1314JaFS-L14-B Q M1314 JaFS-L14-C
• M1314JaFS-Ref-A A M1314JaFS-Ref-B • M1314 JaFS-Ref-C
] • M1314JaFS-Ref-D A M1314JaFS-Ref-E D M1314 JaFS-Ref-F
M1314JaFS95%RCL
10
mn
ISO
enLabSD
LabSD
^=a
1 MDL
u.uui -i • • — • — i • • — -
0.1 1
L/S (L/kg)
^N ' <*r
-5 S\,<
5 ;./ '
M *-•••''
M m - - --**
B) 1U .
c
IB ' ICP-OESRSD
> IB
^ M1314 JaFS Overall C
1 M1314 JaFS Between
M1314 JaFS Within La
^ ^^^
\ — *' ****(
i/
LabCV
bCV
1 1 1 1 1
10 0.1 1 10
L/S (L/kg)
(D)
Figure 40. Manganese concentration in JaFS eluate using Method 1314. (A) collected data as a function of
L/S; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL
intervals (red lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed
line) and pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall",
"between lab" and "within lab" standard deviation compared to 5% marker indicating a generalized analytical
uncertainty.
E-40
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
mg
3 0.01 ••
S
•o
.Q
"5 0.001 f
z
0.0001
&
5F rt
^^ ^g_ ™, ML
* MDL
"
0.1
10
100
01
I
c
1
"o
Z
0.0001
0.01 ••
0.001
0.1
(C)
L/S (L/kg)
O)
o
E
i
S
>,
o
0.01 T
0.001 -r
0.0001
M1314JaFS Overall SD
-M1314JaFS Between LabSD
•M1314JaFS Within Lab SD
M1314JaFSMean
_ML_
MDL
0.1
10
(D)
L/S(L/kg)
• M1314JaFS-L01-A
O M1314JaFS-L06-A
O M1314JaFS-L07-A
0 M1314JaFS-L10-A
• M1314JaFS-Lll-A
• M1314JaFS-L14-A
• M1314JaFS-Ref-A
• M1314JaFS-Ref-D
M1314JaFS95%RCL
A M1314JaFS-L01-B
A M1314JaFS-L06-B
A M1314JaFS-L07-B
A M1314JaFS-L10-B
A M1314JaFS-Lll-B
A M1314JaFS-L14-B
A M1314JaFS-Ref-B
A M1314JaFS-Ref-E
• M1314JaFS-L01-C
D M1314JaFS-L06-C
• M1314JaFS-L07-C
D M1314JaFS-L10-C
• M1314JaFS-Lll-C
• M1314JaFS-L14-C
• M1314JaFS-Ref-C
D M1314JaFS-Ref-F
100
E
3
01
E
"o
10 -:
M1314JaFS Overall CV
-- M1314 JaFS Between Lab CV
----- M1314 JaFS Within Lab CV
^F
0.1
10
(E)
L/S (L/kg)
Figure 41. Molybdenum concentration in JaFS eluate using Method 1314. (A) collected data as a function of
L/S; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL
intervals (red lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed
line) and pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall",
"between lab" and "within lab" standard deviation compared to 5% marker indicating a generalized analytical
uncertainty.
E-41
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
10 -r
oi
o
c
N
0.0001
(A)
(C)
(D)
0.01 -r
0.001
c
N
0.0001
1 10
L/S (L/kg)
L/S (L/kg)
0.1
L/S (L/kg)
100
10
o
u
R
0.0001
0.01
0.001
O M1314 JaFS Ref Mean
M1314JaFS Ref 95% PL
• M1314JaFS Median of Lab Means
M1315 JaFS 95% RCL
0.1
10
L/s(L/k»>
• M1314JaFS-L01-A
• M1314JaFS-L06-A
• M1314JaFS-L07-A
O M1314JaFS-L10-A
O M1314JaFS-Lll-A
• M1314JaFS-L14-A
• M1314JaFS-Ref-A
O M1314JaFS-Ref-D
M1314JaFS95%RCL
A M1314JaFS-L01-B
A M1314JaFS-L06-B
A M1314JaFS-L07-B
A M1314JaFS-L10-B
A M1314JaFS-Lll-B
A M1314JaFS-L14-B
A M1314JaFS-Ref-B
A M1314JaFS-Ref-E
• M1314JaFS-L01-C
D M1314JaFS-L06-C
• M1314JaFS-L07-C
D M1314JaFS-L10-C
• M1314JaFS-Lll-C
• M1314JaFS-L14-C
• M1314JaFS-Ref-C
D M1314JaFS-Ref-F
Zinc (mg/L)
1 •
0.01 •
o.oooi 4
^,
ML
• M1314 JaFS Mean
D
LabSD
bSD
MDL
I
>
0
R
10 •
1 -1
5!a^a^^=
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
0.01 ••
Si
8
w
ct
E
3
C
,E o.ooi
o.oooi
(A)
1 10
L/S (L/kg)
0.1 T
2. 0.01 ••
= 0.001 • •
0.0001
(C)
L/S (L/kg)
Ol
01
in
is
0.1 ••
•Ł 0.01 •;
,E o.ooi ••
o.oooi
M1314 CFS Overail SD
• M1314 CFS Between Lab SD
- M1314 CFS Within Lab SD
M1314 CFS Mean
o.i
10
(D)
L/S (L/kg)
E
_3
<
0.0001
100 0.1
(B)
M1314CFSRef95%PL
M1314CFSRefMean
• M1314CFS Median of Lab Means
M1314 CFS 95% RCL
10
L/S (L/kg)
• M1314CFS-L01-A
O M1314CFS-L06-A
O M1314CFS-L07-A
O M1314CFS-L10-A
• M1314CFS-L11-A
• M1314CFS-L14-A
• M1314CFS-Ref-A
O M1314CFS-Ref-D
M1314CFS95%RCL
A M1314CFS-L01-B
A M1314CFS-L06-B
A M1314CFS-L07-B
A M1314CFS-L10-B
A M1314CFS-L11-B
A M1314CFS-L14-B
A M1314 CFS-Ref-B
A M1314 CFS-Ref-E
• M1314CFS-L01-C
D M1314 CFS-L06-C
D M1314 CFS-L07-C
D M1314CFS-L10-C
• M1314CFS-L11-C
• M1314CFS-L14-C
• M1314 CFS-Ref-C
D M1314 CFS-Ref-F
E
3
C
E
3
— M1314 CFS Overall CV
M1314 CFS Between Lab CV
M1314 CFS Within Lab CV
ICP-OES RSD
0.1
10
(E)
L/S (L/kg)
Figure 43. Aluminum release from material CFS using Method 1314. (A) calculated data as a function of L/S;
(B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-43
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
(A)
(C)
(D)
L/S (L/kg)
01
JŁ
"Si
o
Si
E
3
•c
0.0001
0.01 -r
0.001 -•
0.1
L/S (L/kg)
10
I
01
2
E
3
•c
1 T
0.0001
— M1314 CFS Overall SD
M1314 CFS Between Lab SD
M1314 CFS Within Lab SD
• M1314 CFS Mean
0.1
L/S (L/kg)
01
01
in
is
.2
2
E
13
IS
CD
10
0.1
0.01
0.001
O M1314CFSRef95%PL
M1314CFS Ref Mean
• M1314 CFS Median of Lab Means
M1314 CFS 95% RCL
0.0001
(B)
L/S (L/kg)
• M1314CFS-L01-A
O M1314CFS-L06-A
O M1314CFS-L07-A
O M1314CFS-L10-A
• M1314CFS-L11-A
• M1314CFS-L14-A
• M1314CFS-Ref-A
O M1314CFS-Ref-D
M1314 CFS 95% RCL
A M1314CFS-L01-B
A M1314CFS-L06-B
A M1314CFS-L07-B
A M1314CFS-L10-B
A M1314CFS-L11-B
A M1314CFS-L14-B
A M1314 CFS-Ref-B
A M1314 CFS-Ref-E
• M1314CFS-L01-C
D M1314 CFS-L06-C
D M1314 CFS-L07-C
D M1314CFS-L10-C
• M1314CFS-L11-C
• M1314CFS-L14-C
• M1314 CFS-Ref-C
D M1314 CFS-Ref-F
100
u
Si
10
E
3
1
M1314 CFS Overall CV
M1314 CFS Between Lab CV
M1314 CFS Within Lab CV
ICP-OES RSD
0.1
10
(E)
L/S (L/kg)
Figure 44. Barium release from material CFS using Method 1314. (A) calculated data as a function of L/S; (B)
reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-44
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
10 T
Ol
JŁ
Ol
in
IS
0)
W
O
CD
0.0001
(A)
Ol
?
i
I
0.001 -•
(C)
0.0001
10
10
L/S (L/kg)
Ol
o
01
in
is
_«
&
o
CD
1 ••
0.01 v
0.001 v
0.0001
M1314 CFS Overail SD
M1314 CFS Between Lab SD
M1314 CFS Within Lab SD
• M1314 CFS Mean
(D)
L/S (L/kg)
10
Ol
JŁ
"oi
I
I
a!
E
o
o.i -
0.01
0.001 -
0.0001
O M1314CFSRef95%PL
M1314 CFS Ref Mean
• M1314 CFS Median of Lab Means
M1314 CFS 95% RCL
L/S(L/kg)
•
0
o
o
o
o
•
o
—
M1314CFS-L01-A
M1314CFS-L06-A
M1314CFS-L07-A
M1314CFS-L10-A
M1314CFS-L11-A
M1314CFS-L14-A
M1314CFS-Ref-A
M1314CFS-Ref-D
M1314CFS95%RCL
A
A
A
A
A
A
A
A
M1314CFS-L01-B
M1314CFS-L06-B
M1314CFS-L07-B
M1314CFS-L10-B
M1314CFS-L11-B
M1314CFS-L14-B
M1314 CFS-Ref-B
M1314 CFS-Ref-E
•
D
D
D
D
D
•
D
M1314CFS-L01-C
M1314 CFS-L06-C
M1314 CFS-L07-C
M1314CFS-L10-C
M1314CFS-L11-C
M1314CFS-L14-C
M1314 CFS-Ref-C
M1314 CFS-Ref-F
I
(E)
10 •
M1314 CFS Between Lab CV
• • s'^-^»
: *•»
• ICP-OESRSD
0.1 1 1
L/S (L/kg)
Figure 45. Boron release from material CFS using Method 1314. (A) calculated data as a function of L/S; (B)
reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-45
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
"3
^ m .
n Release (mg/
D P
-i h-i h-i C
_3
T5 0.001 •
0
n nnm .
-^ dD
M$&
A ^9
^J^MDL
^^^
^
ji m - ra'jtfr ^1^"^
1 r?****^
^ 1 -
™ O M1314CFSRef95%PL
IB M1314 CFS Ref Mean
.2 0.1 - • M1314 CFS Median of Lab Mea
En m - ^-— •
1 ~~~~^^'
-« nnm. ML — ^ —
O MDL — ""
n nnrn
0.1 1 10 100 0.1 1
L/S (L/kg) L/S (L/kg)
(A) ' V ' *' (B) ' V ' Sy
*3
- 10-
01
01
in
n 1 .
Cadmium Rel
i g P c
D O O .
-••I-1 I-1 I-
^^^
MDL "*
^——
ns ___
-"•"" ^___^_ — • — '
^^~
10
I • M1314CFS-L01-A A M1314 CFS-L01-B • M1314 CFS-L01-C
O M1314CFS-L06-A A M1314 CFS-L06-B D M1314 CFS-L06-C
0 M1314CFS-L07-A A M1314 CFS-L07-B D M1314 CFS-L07-C
O M1314CFS-L10-A A M1314 CFS-L10-B D M1314 CFS-L10-C
• M1314CFS-L11-A A M1314 CFS-L11-B • M1314 CFS-L11-C
• M1314CFS-L14-A A M1314 CFS-L14-B • M1314 CFS-L14-C
• M1314CFS-Ref-A A M1314 CFS-Ref-B • M1314 CFS-Ref-C
• M1314CFS-Ref-D A M1314 CFS-Ref-E • M1314 CFS-Ref-F
M1314 CFS 95% RCL
0.1 1 10
(0 L/S (L/kg)
i Release (mg/kg)
) P C
i h-i h-i O C
c u.ui •
,3
•0 0.001 •
0
n nnm .
.—— """"
— M1314 CFS Overall SD
M1314 CFS Between Lab SD
I M1314CFS Within Lab SD _
• M1314 CFS Mean ^.- — " "
-*'*'' •— ^^" — "
1 ML^^^^^"^
MDL — ^"*"
: M1314 CFS Overall CV
•P '. M1314 CFS Between Lab CV
3*
«
1 ^^^r==1=^t=^
D 10 :
Ł _ 7 —
3 • ICP-OESRSD
E
•o
IS
u
5 Within LabCV
•"^^»wwi<>ii^
!!>1S!S*»,
^V^
(D)
0.1
10
0.1
10
L/S (L/kg)
(E)
L/S (L/kg)
Figure 46. Cadmium release from material CFS using Method 1314. (A) calculated data as a function of L/S;
(B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-46
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Calcium Release (mg/kg
3 P 0
3 0 P <-, h-^ C
3 O O . i-J. O C
j.|_i|_i|_i|_iOOC
^4? d=3 &
A "^
0
ML
,,^''^— -MDL
^^^^
""""*
§ 100 ! «s^**
E i
W [ O M1314CFSRef95%PL
S1 : M1314 CFS Ref Mean
_ ; • M1314 CFS Median of Lab IV
E i
s ! ~~—~^~
J% n nm - n ML"*" -— • — — •""""""""""""^
MDL
0.1 1 10 100 0.1 1
"3 1000 •
"Si 100 •
E
8! 10
8 i-
«
Ł n 1 •
E
0 0001 •
^—^
\ \f~^
\
' -''•^^--••••"
i ML^^-.--^^ "
[ MDL ' '
I • M1314CFS-L01-A A M1314 CFS-L01-B
O M1314CFS-L06-A A M1314 CFS-L06-B
0 M1314CFS-L07-A A M1314 CFS-L07-B
O M1314CFS-L10-A A M1314 CFS-L10-B
0 M1314CFS-L11-A A M1314 CFS-L11-B
• M1314CFS-L14-A A M1314 CFS-L14-B
• M1314CFS-Ref-A A M1314 CFS-Ref-B
0 M1314CFS-Ref-D A M1314 CFS-Ref-E
M1314 CFS 95% RCL
0.1 1 10
(C) L/S (L/kg)
10000 T • inn
Q mnn -
Calcium Release (mg/kc
B § P o -
3 CD CD . l-^ O
_i I— i I— i I— i I— i CD CD
^ «•• '
-,^-*-"*1**C
— M1314 CFS Overall SD
. M1314 CFS Between Lab SD
• M1314 CFS Mean
MDL --^^
I M1314
~~-~~~
eans
_--~^^
— --
10
• M1314CFS-L01-C
D M1314 CFS-L06-C
D M1314 CFS-L07-C
D M1314CFS-L10-C
• M1314CFS-L11-C
• M1314CFS-L14-C
• M1314 CFS-Ref-C
D M1314 CFS-Ref-F
CFS Overall CV
CFS Between Lab CV
CFS Within LabCV
^
Si
8 10 — — "--.
| • ICP-OESRSD
— _
^E. . . . ~S
0.1
10
0.1
10
(D)
L/S (L/kg)
(E)
L/S (L/kg)
Figure 47. Calcium release from material CFS using Method 1314. (A) calculated data as a function of L/S;
(B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-47
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Release (mg/k
D P
•* h-i h-i C
Q.
§" 0.001 •
I { 4
*'
'"'^^
^^
i
ML
MDL
0.1 1 10 100
,A, L/S(L/k«>
mn
w in .
Dl
n m .
0
O n nm
n nnm
ML— — ''^~~~~
MDL— ' """""
pŁB
Z-^
C2*=^
~~~^~~
^•^'^
Release (mg/kg)
IP ~ E
•* h-1 h-1 O C
Q.
o n nni -
-——^z*^*^*
r^3^~~^
^-^^
_„— — •
ML—— 0 M1314CFSRef95%PL
— — M1314 CFS Ref Mean
• M1314 CFS Median of Lab Means
0.1 1 10
L/S (L/kg)
D)
• M1314CFS-L01-A A M1314 CFS-L01-B • M1314 CFS-L01-C
0 M1314CFS-L06-A A M1314 CFS-L06-B D M1314 CFS-L06-C
0 M1314CFS-L07-A A M1314 CFS-L07-B D M1314 CFS-L07-C
0 M1314CFS-L10-A A M1314 CFS-L10-B D M1314 CFS-L10-C
• M1314CFS-L11-A A M1314 CFS-L11-B D M1314 CFS-L11-C
• M1314CFS-L14-A A M1314 CFS-L14-B D M1314 CFS-L14-C
• M1314CFS-Ref-A A M1314 CFS-Ref-B • M1314 CFS-Ref-C
O M1314CFS-Ref-D A M1314 CFS-Ref-E • M1314 CFS-Ref-F
M1314 CFS 95% RCL
(C)
(D)
0.1
10
L/S (L/kg)
I
01
**>
Si
8
a.
o
u
10 •
1 •
n 1 -
i ni .
nni .
i ^-
&
ML "'~^~**^
MDL "
„.--
-^^^
M1314 CFS Between Lab SD
M1314 CFS Within Lab SD
• M1314 CFS Mean
100
u
Si
8 10
M1314 CFS Overall CV
M1314 CFS Between Lab CV
M1314 CFS Within LabCV
ICP-OES RSD
0.1
10
0.1
10
L/S (L/kg)
(E)
L/S (L/kg)
Figure 48. Copper release from material CFS using Method 1314. (A) calculated data as a function of L/S; (B)
reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-48
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
(A)
(C)
(D)
1 10
L/S (L/kg)
100
0.001
100
L/S (L/kg)
S? 10 -
0.001
M1314 CFS Overail SD
• M1314 CFS Between Lab SD
-M1314CFS Within Lab SD
M1314 CFS Mean
L/S (L/kg)
100
10 •:
01
JŁ
"Si
^ 1
%
I
Ł
O M1314CFSRef95%PL
M1314 CFS Ref Mean
• M1314 CFS Median of Lab Means
M1314 CFS 95% RCL
0.01 -•
0.001
(B)
L/S (L/kg)
• M1314CFS-L01-A
O M1314CFS-L06-A
O M1314CFS-L07-A
O M1314CFS-L10-A
• M1314CFS-L11-A
• M1314CFS-L14-A
• M1314CFS-Ref-A
O M1314CFS-Ref-D
M1314 CFS 95% RCL
A M1314CFS-L01-B
A M1314CFS-L06-B
A M1314CFS-L07-B
A M1314CFS-L10-B
A M1314CFS-L11-B
A M1314CFS-L14-B
A M1314 CFS-Ref-B
A M1314 CFS-Ref-E
• M1314CFS-L01-C
D M1314 CFS-L06-C
D M1314 CFS-L07-C
D M1314CFS-L10-C
• M1314CFS-L11-C
• M1314CFS-L14-C
• M1314 CFS-Ref-C
D M1314 CFS-Ref-F
100
Si
8
I
10 -:
M1314 CFS Overall CV
M1314 CFS Between Lab CV
M1314 CFS Within Lab CV
ICP-OES RSD
0.1
10
(E)
L/S (L/kg)
Figure 49. Lead release from material CFS using Method 1314. (A) calculated data as a function of L/S; (B)
reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-49
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
O
8
o.i -
• M1314CFSRef95%PL
M1314 CFS Ref Mean
• M1314 CFS Median of Lab Means
M1314 CFS 95% RCL
«! o.oi -
E
3
.jjj 0.001 -
0.0001
(A)
1 10
L/S (L/kg)
100
(B)
L/S (L/kg)
•
o
o
o
0
o
•
o
—
M1314CFS-L01-A
M1314 CFS-L06-A
M1314 CFS-L07-A
M1314CFS-L10-A
M1314CFS-L11-A
M1314CFS-L14-A
M1314 CFS-Ref-A
M1314CFS-Ref-D
M1314 CFS 95% RCL
A
A
A
A
A
A
A
A
M1314CFS-L01-B
M1314CFS-L06-B
M1314CFS-L07-B
M1314CFS-L10-B
M1314CFS-L11-B
M1314CFS-L14-B
M1314CFS-Ref-B
M1314CFS-Ref-E
•
a
D
D
D
a
•
D
M1314CFS-L01-C
M1314 CFS-L06-C
M1314CFS-L07-C
M1314CFS-L10-C
M1314CFS-L11-C
M1314CFS-L14-C
M1314 CFS-Ref-C
M1314CFS-Ref-F
(C)
L/S (L/kg)
.
Ol
M1314 CFS Overail SD
- M1314 CFS Between Lab SD
-M1314 CFS Within Lab SD
M1314 CFS Mean
M1314 CFS Overall CV
— M1314 CFS Between Lab CV
— M1314 CFS Within Lab CV
(D)
L/S (L/kg)
(E)
L/S (L/kg)
Figure 50. Molybdenum release from material CFS using Method 1314. (A) calculated data as a function of
L/S; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL
intervals (red lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed
line) and pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall",
"between lab" and "within lab" standard deviation compared to 5% marker indicating a generalized analytical
uncertainty.
E-50
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
5 1
Dl
•5
Thallium F
! g F
) O C
•• I-1 1-
*&>«**
q &
'"'^^
'^^
ML
MDL
Thallium Release (mg/kg)
1 § P o
) 0 0 P 1-
L |_L |_L |_L |_L C
eSSSZ*
Ml •-" ^---^*
-sf&f^*^
^-<^
~^^
^^----" 0 M1314CFSRef95%PL
MDL-" M1314 CFS Ref Mean
• M1314 CFS Median of Lab Means
'• M1314CFS95%RCL
0.1 1 10 100 0.1 1 10
, L/s(L/kg) ,B, L/s(L/kg)
D iH i-
C
(6>|/6ui) E
I
E
3
Ł
0.0001 •
HjHf
^^"
M L ^ "" *" ^ ""
crJ^
• M1314CFS-L01-A A M1314 CFS-L01-B • M1314 CFS-L01-C
• M1314CFS-L06-A A M1314 CFS-L06-B D M1314 CFS-L06-C
0 M1314CFS-L07-A A M1314 CFS-L07-B D M1314 CFS-L07-C
O M1314CFS-L10-A A M1314 CFS-L10-B D M1314 CFS-L10-C
• M1314CFS-L11-A A M1314 CFS-L11-B D M1314 CFS-L11-C
• M1314CFS-L14-A A M1314 CFS-L14-B D M1314 CFS-L14-C
• M1314CFS-Ref-A A M1314 CFS-Ref-B • M1314 CFS-Ref-C
0 M1314CFS-Ref-D A M1314 CFS-Ref-E • M1314 CFS-Ref-F
M1314 CFS 95% RCL
(C)
(D)
0.1
10
L/S (L/kg)
100
10'
Ł
E
3
M1314 CFS Overail SD
- M1314 CFS Between Lab SD
-M1314 CFS Within LabSD
M1314 CFS Mean
M1314 CFS Overall CV
- M1314 CFS Between Lab CV
-M1314 CFS Within LabCV
ICP-OES RSD
0.1
10
0.1
10
(E)
L/S (L/kg)
Figure 51. Thallium release from material CFS using Method 1314. (A) calculated data as a function of L/S;
(B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-51
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
1
E
S '
Sn 1 -
o 0.01 •
_e
R 0.001 -
a *
**• ^
[ ^^
0.1
^ 100 •
$
^ 1 •
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S n 1 .
n m -
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0 0001 •
X*09'
^ ,*- -
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L
L/S
Ł=
f
ML
10 10
3
' —--"*"""'"
: MDL.^^
0.1
(C)
inn -
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1 '"
Sn 1 -
_c
R 0.001 •
&#***^
____ — -
^^^
1
L/S (L/kg)
^idBB*^
r
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M131
— M131
M131
• M131
^ 100
"J5 10
**"' i
Si
S o.i
o 0.01
R 0.001
0.0001
0
(B)
^rT&Z***33^'
Ł^3^^^**
• M1314CFSRef95%PL
M1314 CFS Ref Mean
• M1314 CFS Median of Lab Means
--.-^^^"--"^
0.1 1 10
L/S (L/kg)
1 • M1314CFS-L01-A A M1314 CFS-L01-B • M1314 CFS-L01-C
O M1314CFS-L06-A A M1314 CFS-L06-B D M1314 CFS-L06-C
0 M1314CFS-L07-A A M1314 CFS-L07-B D M1314 CFS-L07-C
O M1314CFS-L10-A A M1314 CFS-L10-B D M1314 CFS-L10-C
0 M1314CFS-L11-A A M1314 CFS-L11-B • M1314 CFS-L11-C
• M1314CFS-L14-A A M1314 CFS-L14-B • M1314 CFS-L14-C
• M1314CFS-Ref-A A M1314 CFS-Ref-B • M1314 CFS-Ref-C
0 M1314CFS-Ref-D A M1314 CFS-Ref-E • M1314 CFS-Ref-F
M1314 CFS 95% RCL
10
4 CFS Overall SD
4 CFS Between Lab S[
4 CFS Within LabSD
4 CFS Mean
____ — — -
MDL "^"
0.1
1
L/S (L/kg)
- o
' 1 10--
.2 :
o • 1
N
10 0.1
_ __ M1314 CFS Between Lab CV
*^^^^-
:P-OES RSD
1 10
L/S (L/kg)
Figure 52. Zinc release from material CFS using Method 1314. (A) calculated data as a function of L/S; (B)
reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-52
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
(A)
1 10
L/S (L/kg)
100
0.1 ••
01
in
•3 0.01 -r
,E o.ooi ••
o.oooi
0.1
(C)
L/S (L/kg)
1 -E-
O1
M1314JaFS Overall SD
M1314 JaFS Between Lab SD
M1314 JaFS Within Lab SD
• M1314 JaFS Mean
(D)
L/S (L/kg)
1 -rf
I
01
O M1314JaFSRef95%PL
M1314 JaFS Ref Mean
• M1314JaFS Median of Lab Means
M1314 JaFS 95% RCL
(B)
L/S (L/kg)
• M1314JaFS-L01-A
O M1314JaFS-L06-A
O M1314JaFS-L07-A
O M1314JaFS-L10-A
• M1314JaFS-Lll-A
• M1314JaFS-L14-A
• M1314JaFS-Ref-A
0 M1314JaFS-Ref-D
M1314JaFS95%RCL
A
A
A
A
A
A
A
A
M1314JaFS-L01-B
M1314JaFS-L06-B
M1314JaFS-L07-B
M1314JaFS-L10-B
M1314JaFS-Lll-B
M1314JaFS-L14-B
M1314JaFS-Ref-B
M1314JaFS-Ref-E
• M1314JaFS-L01-C
D M1314JaFS-L06-C
D M1314JaFS-L07-C
D M1314JaFS-L10-C
• M1314JaFS-Lll-C
• M1314JaFS-L14-C
• M1314JaFS-Ref-C
D M1314JaFS-Ref-F
(E)
•g
d
M
8
•5 10 -
p
Aluminu
0
M1314 JaFS Between Lab CV
M1314 JaFS Within Lab CV
• ICP-OES RSD
1 1 1
L/S (L/kg)
Figure 53. Aluminum release from material JaFS using Method 1314. (A) calculated data as a function of L/S;
(B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-53
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
3
™ o.i -t
Si
g 0.01 ••
.3 0.001 -•
I
0.0001
•4-
•4-
0.1
(A)
1 10
L/S (L/kg)
100
(C)
L/S (L/kg)
1 T
Ol
M1314JaFS Overall SD
M1314 JaFS Between Lab SD
M1314 JaFS Within Lab SD
• M1314 JaFS Mean
(D)
L/S (L/kg)
0.0001
O M1314JaFSRef95%PL
M1314JaFSRefMean
• M1314JaFS Median of Lab Means
M1314JaFS95%RCL
0.1
10
(B)
L/S (L/kg)
• M1314JaFS-L01-A
O M1314JaFS-L06-A
• M1314JaFS-L07-A
• M1314JaFS-L10-A
• M1314JaFS-Lll-A
• M1314JaFS-L14-A
• M1314JaFS-Ref-A
O M1314JaFS-Ref-D
M1314JaFS95%RCL
A M1314JaFS-L01-B
A M1314JaFS-L06-B
A M1314JaFS-L07-B
A M1314JaFS-L10-B
A M1314JaFS-Lll-B
A M1314JaFS-L14-B
A M1314JaFS-Ref-B
A M1314JaFS-Ref-E
• M1314JaFS-L01-C
• M1314JaFS-L06-C
D M1314JaFS-L07-C
• M1314JaFS-L10-C
• M1314JaFS-Lll-C
• M1314JaFS-L14-C
• M1314JaFS-Ref-C
D M1314JaFS-Ref-F
100
Si
8
I
E
_3
1
10 -:
— M1314JaFS Overall CV
• — M1314 JaFS Between Lab CV
M1314 JaFS Within Lab CV
0.1
10
(E)
L/S (L/kg)
Figure 54. Barium release from material JaFS using Method 1314. (A) calculated data as a function of L/S; (B)
reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-54
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
iuu •
oi 10 •
OI
Ł 1 -
01
1 o-1-
s
,§ o.ooi •
I 03 tttP nrr}j mj-i
$
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| ^^^^^^MDL
^^
0.1 1 10 10
,A, L/SVW
•3 1n .
_§* 1U
OI
Boron Release (n
i g p o
3 0 0 P
* h-i h-i h-i 1-
MDL-^^^"
B 0
"ro
Boron Release (mg/kg)
1 g P 0
0 0 0 H l-i C
• M1314
0 M1314
O M1314
O M1314
O M1314
• M1314
• M1314
• M1314
M1314
0.1 1 10
(C) L/S (L/kg)
w 10 •
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o
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r
M1314JaFS Overall SD
. M1314JaFS Between Lab SD
• M1314JaFSMean — "
-^^^^
ML "'^.^-^•^^
MDL
^N
i :
u
Si
1U -;
I :
E :
o
CD
1 - -
1 '
0 M1314JaFSRef95%PL
M1314 JaFS Ref Mean
1 " • M1314 JaFS Median of Lab Means
1 ''1^^""
MDL— —•-'""'"""'
0.1 1
L/S (L/kg)
UU ^^11
^~~
>^-^
10
aFS-LOl-A A M1314JaFS-L01-B • M1314 JaFS-LOl-C
aFS-LOS-A A M1314JaFS-L06-B D M1314 JaFS-L06-C
3FS-L07-A A M1314JaFS-L07-B D M1314 JaFS-L07-C
aFS-LlO-A A M1314JaFS-L10-B D M1314 JaFS-LlO-C
3FS-L14-A A M1314JaFS-L14-B Q M1314 JaFS-L14-C
aFS-Ref-A A M1314JaFS-Ref-B • M1314JaFS-Ref-C
aFS-Ref-D A M1314JaFS-Ref-E D M1314JaFS-Ref-F
aFS 95% RCL
— M1314 JaFS Overall CV
M1314 JaFS Between Lab CV
/ithinLabCV
V.
X
ICP-OES RSD
(D)
0.1
10
0.1
10
L/S (L/kg)
(E)
L/S (L/kg)
Figure 55. Boron release from material JaFS using Method 1314. (A) calculated data as a function of L/S; (B)
reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-55
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
_gi 100 •
1
8
"3 01-
oŁ
73
9 *<
0® *
Ml
^ -* ""^ MDL
""^^^^^
\ ^
0.1
)
[3 100 •
| 10 -
i
oŁ
'u
Q 0.001 •
\ B==
r
L 10 10
L/S (L/kg)
a — •-**- "^
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ML — — "'
MDL
0.1
)
mnn
w inn-
s' m .
Calcium Release (IT
i S p o
D 0 0 P H
_i |_i |_i |_i |_i c
OKSKB
- • — "^ J-*-***- — *
01 100
E 10
O
8! i
8
Ł o.i
| 0.01
* 0.001
0.0001
0
\
^^mr-^Sf -r -m— "
0 M1314JaFSRef95%PL
M1314 JaFS Ref Mean
• M1314 JaFS Median of Lab N
" M1314JaFS95%RCL
ML~^'~r^----~~^
MDL"
jj_ UJgg^1
leans
— ^ — • •••
,^-'^_____-—
— — ^*
0.1 1 10
L/S (L/kg)
. • M1314JaFS-L01-A A M1314JaFS-L01-B
O M1314JaFS-L06-A A M1314JaFS-L06-B
O M1314JaFS-L07-A A M1314JaFS-L07-B
O M1314JaFS-L10-A A M1314JaFS-L10-B
0 M1314JaFS-Lll-A A M1314JaFS-Lll-B
• M1314JaFS-L14-A A M1314JaFS-L14-B
• M1314JaFS-Ref-A A M1314JaFS-Ref-B
0 M1314JaFS-Ref-D A M1314JaFS-Ref-E
M1314JaFS95%RCL
1 10
L/S (L/kg)
, M1314JaF
M1314JaF
M1314JaF
S Between LabSD
S Within Lab SD
• M1314 JaFS Mean __ — — ""
r ML "^^~—
MDL "
0.1
^^.*~ ' — — - —
i
U
(0
2 :
E
3
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5
1 10 0.1
L/S (L/kg)
• M1314JaFS-L01-C
D M1314JaFS-L06-C
D M1314JaFS-L07-C
D M1314JaFS-L10-C
• M1314JaFS-Lll-C
• M1314JaFS-L14-C
• M1314JaFS-Ref-C
D M1314JaFS-Ref-F
M1314
M1314
^^^
"^ x
CP-OES RSD ^-.
1
L/S (L/kg)
aFS Overall CV
aFS Between Lab CV
aFS Within Lab CV
^
^^"
10
(D)
Figure 56. Calcium release from material JaFS using Method 1314. (A) calculated data as a function of L/S;
(B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-56
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
(A)
(C)
(D)
10 T
01
^t
«•«.
01
1 T
0.1 ••
^ 0.01 ••
&
Q. 0.001 -t
w
u
0.0001
0.1
1 10
L/S (L/kg)
100
L/S (L/kg)
Si
«
a.
9- 0.001 ••
0.1 ••
0.01 -r
0.0001
MDL
M1314JaFSO«erallSD
- M1314 JaFS Between Lab SD
-M1314JaFS Within Lab SD
M1314JaFSMean
0.1
10
L/S (L/kg)
f™">
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8
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g. 0.001 -
u
0.0001 -
0
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^-^SsS3'
^ ^ *"" ^^
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) M1314JaFSRef95%PL
— M1314JaFSRef Mean
1 M1314JaFS Median of Lab Means
1 10
Title
• M1314JaFS-L01-A A M1314JaFS-L01-B • M1314 JaFS-LOl-C
• M1314JaFS-L06-A A M1314JaFS-L06-B D M1314 JaFS-L06-C
• M1314JaFS-L07-A A M1314JaFS-L07-B D M1314 JaFS-L07-C
• M1314JaFS-L10-A A M1314JaFS-L10-B D M1314 JaFS-LlO-C
• M1314JaFS-Lll-A A M1314JaFS-Lll-B D M1314 JaFS-Lll-C
0 M1314JaFS-L14-A A M1314JaFS-L14-B Q M1314 JaFS-L14-C
• M1314JaFS-Ref-A A M1314JaFS-Ref-B • M1314 JaFS-Ref-C
0 M1314JaFS-Ref-D A M1314JaFS-Ref-E D M1314 JaFS-Ref-F
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M1314 JaFS Between Lab CV
M1314 JaFS Within Lab CV
: ICP-OESRSD
0.1
10
(E)
L/S (L/kg)
Figure 57. Copper release from material JaFS using Method 1314. (A) calculated data as a function of L/S; (B)
reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-57
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
0.001
(A)
(C)
(D)
1 10
L/S (L/kg)
100
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L/S (L/kg)
0.001
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M1314 JaFS Between Lab SD
M1314 JaFS Within Lab SD
• M1314 JaFS Mean
0.1
10
L/S (L/kg)
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M1314 JaFS Ref Mean
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(B)
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O M1314JaFS-L06-A
• M1314JaFS-L07-A
• M1314JaFS-L10-A
• M1314JaFS-Lll-A
• M1314JaFS-L14-A
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O M1314JaFS-Ref-D
M1314JaFS95%RCL
A M1314JaFS-L01-B
A M1314JaFS-L06-B
A M1314JaFS-L07-B
A M1314JaFS-L10-B
A M1314JaFS-Lll-B
A M1314JaFS-L14-B
A M1314JaFS-Ref-B
A M1314JaFS-Ref-E
• M1314JaFS-L01-C
• M1314JaFS-L06-C
D M1314JaFS-L07-C
• M1314JaFS-L10-C
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— M1314 JaFS Overall CV
M1314 JaFS Between Lab CV
M1314 JaFS Within Lab CV
ICP-OES RSD
0.1
10
(E)
L/S (L/kg)
Figure 58. Lead release from material JaFS using Method 1314. (A) calculated data as a function of L/S; (B)
reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-58
-------
Interlaboratory Validation of LEAF Method 1314 and Method 1315
m Release (mg/kg)
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O M1314JaFS-L07-A A M1314JaFS-L07-B D M1314 JaFS-L07-C
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• M1314JaFS-L14-A A M1314JaFS-L14-B Q M1314 JaFS-L14-C
• M1314JaFS-Ref-A A M1314JaFS-Ref-B • M1314 JaFS-Ref-C
• M1314JaFS-Ref-D A M1314JaFS-Ref-E D M1314 JaFS-Ref-F
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(D)
Figure 59. Magnesium release from material JaFS using Method 1314. (A) calculated data as a function of
L/S; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL
intervals (red lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed
line) and pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall",
"between lab" and "within lab" standard deviation compared to 5% marker indicating a generalized analytical
uncertainty.
E-59
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
I
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0 M1314JaFS-L06-A A M1314JaFS-L06-B D M1314 JaFS-L06-C
• M1314JaFS-L07-A A M1314JaFS-L07-B D M1314 JaFS-L07-C
• M1314JaFS-L10-A A M1314JaFS-L10-B D M1314 JaFS-LlO-C
• M1314JaFS-Lll-A A M1314JaFS-Lll-B D M1314 JaFS-Lll-C
• M1314JaFS-L14-A A M1314JaFS-L14-B Q M1314 JaFS-L14-C
• M1314JaFS-Ref-A A M1314JaFS-Ref-B • M1314 JaFS-Ref-C
• M1314JaFS-Ref-D A M1314JaFS-Ref-E D M1314 JaFS-Ref-F
M1314JaFS95%RCL
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M1314 JaFS Between Lab CV
M1314 JaFS Within Lab CV
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01
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01
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0.1
1 10
L/S (L/kg)
Figure 60. Manganese release from material JaFS using Method 1314. (A) calculated data as a function of L/S;
(B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-60
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Si
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M1314JaFS-L14-B
M1314JaFS-Ref-B
M1314JaFS-Ref-E
• M1314JaFS-L01-C
D M1314JaFS-L06-C
D M1314JaFS-L07-C
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M1314JaFS Overall CV
M1314 JaFS Between Lab CV
M1314 JaFS Within Lab CV
ICP-OES RSD
0.1
10
(E)
L/S (L/kg)
Figure 61. Molybdenum release from material JaFS using Method 1314. (A) calculated data as a function of
L/S; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL
intervals (red lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed
line) and pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall",
"between lab" and "within lab" standard deviation compared to 5% marker indicating a generalized analytical
uncertainty.
E-61
-------
Interlaboratory Validation of LEAF Method 1314 and Method 1315
Zinc Release (mg/kg)
I § P o
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A M1314JaFS-L06-B D M1314 JaFS-L06-C
• M1314JaFS-L07-A A M1314JaFS-L07-B D M1314 JaFS-L07-C
O M1314JaFS-L10-A A M1314JaFS-L10-B D M1314 JaFS-LlO-C
• M1314JaFS-Lll-A A M1314JaFS-Lll-B D M1314 JaFS-Lll-C
• M1314JaFS-L14-A A M1314JaFS-L14-B Q M1314 JaFS-L14-C
• M1314JaFS-Ref-A A M1314JaFS-Ref-B • M1314 JaFS-Ref-C
0 M1314JaFS-Ref-D A M1314JaFS-Ref-E D M1314 JaFS-Ref-F
M1314JaFS95%RCL
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0.1 1 10 0.1
M1314 JaFS Overall CV
M1314 JaFS Between Lab CV
M1314 JaFS Within Lab CV
1 10
L/S (L/kg)
Figure 62. Zinc release from material JaFS using Method 1314. (A) calculated data as a function of L/S; (B)
reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab means and
median-based 95% robust confidence limits (RCL; red line); (C) interpolated data and 95% RCL intervals (red
lines); (D) intervals about the mean of all data for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation; (E) coefficient of variation for "overall", "between lab"
and "within lab" standard deviation compared to 5% marker indicating a generalized analytical uncertainty.
E-62
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
O)
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c
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0.01 -:
0.001
-M1314CFS Overall SD
M1314CFSMean
-M1314JaFS Overall SD
M1314JaFSMean
1
L/S (L/kg)
10
100
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
0.001
M1314CFS Overall SD
M1314CFSMean
M1314JaFS Overall SD
M1314JaFSMean
1
L/S (L/kg)
10
100
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0.1
M1314CFSRSD-r
M1314JaFSRSD-r
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0.1
M1314CFSRSD-R
M1314JaFSRSD-R
1
L/S (L/kg)
10
-M131J CK Roloaco nworall
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
-M1314CFS Overall SD
M1314CFSMean
-M1314JaFS Overall SD
M1314JaFSMean
L/S (L/kg)
100
10 •:
ICP-OES RSD
0.1
M1314 CFS RSD-r
M1314JaFS RSD-r
1
L/S (L/kg)
10
u
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a.
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0.1
M1314CFSRSD-R
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erall S[
Release Mean
M1314JaFS Release Overall SD
M1314JaFS Release Mean
1
L/S (L/kg)
10
100
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a
10 -:
ICP-OES RSD
0.1
M1314 CFS Release RSD-r
M1314 JaFS Release RSD-r
10
L/S (L/kg)
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00
100
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ICP-OES RSD
0.1
M1314 CFS Release RSD-R
M1314JaFS Release RSD-R
1
L/S (L/kg)
10
Figure 65. Comparisons of statistical analyses for boron from Method 1314 validation study materials.
Mean interval flux (upper) and cumulative release (lower) comparisons showing overall standard deviation intervals about the mean compared to method detection limits and
method limits of quantitation (left), repeatability relative standard deviation (RSDr) (center) and reproducibility relative standard deviation (RSDR) (right). Grey dashed line in
repeatability and reproducibility panels indicate 20% and 50% reference lines.
D-65
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
1000
100
10
1
0.1
0.01
0.001
-M1314CFS Overall SD
M1314CFSMean
-M1314JaFS Overall SD
M1314JaFSMean
0.1
F
1
L/S (L/kg)
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1
L/S (L/kg)
10
10000 T
1000
100
10
1
0.1 -fe
0.01
0.001
0.0001
M1314 CFS Release Overall SD
• M1314 CFS Release Mean
M1314 JaFS Release Overall SD
• M1314 JaFS Release Mean
100
0.1
10
L/S (L/kg)
I
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L/S (L/kg)
100
10
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ICP-OES RSD
0.1
-M1314CFS Release RSD-R
-M1314JaFS Release RSD-R
1
L/S (L/kg)
10
Figure 66. Comparisons of statistical analyses for calcium from Method 1314 validation study materials.
Mean interval flux (upper) and cumulative release (lower) comparisons showing overall standard deviation intervals about the mean compared to method detection limits and
method limits of quantitation (left), repeatability relative standard deviation (RSDr) (center) and reproducibility relative standard deviation (RSDR) (right). Grey dashed line in
repeatability and reproducibility panels indicate 20% and 50% reference lines.
D-66
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
— M1314 CFS Overall SD
• M1314 CFS Mean
— M1314 JaFS Overall Sd
n M1314 JaFS Mean
0.001
L/S (L/kg)
u
100
10 •:
ICP-OES RSD
0.1
M1314CFSRSD-r
M1314JaFSRSD-r
1
L/S (L/kg)
10
Ł
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a.
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100
10 -:
ICP-OES RSD
0.1
M1314CFSRSD-R
M1314JaFSRSD-R
1
L/S (L/kg)
10
100
• M1314CFS Release Mean
— M1314 JaFS Release Overall SD
• M1314 JaFS Release Mean
L/S (L/kg)
!5
s
a
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100
10 -:
M1314 CFS Release RSD-r
M1314JaFS Release RSD-r
ICP-OES RSD
0.1
10
L/S (L/kg)
'o
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100
10 -:
ICP-OES RSD
0.1
M1314 CFS Release RSD-R
M1314JaFS Release RSD-R
1
L/S (L/kg)
10
Figure 67. Comparisons of statistical analyses for copper from Method 1314 validation study materials.
Mean interval flux (upper) and cumulative release (lower) comparisons showing overall standard deviation intervals about the mean compared to method detection limits and
method limits of quantitation (left), repeatability relative standard deviation (RSDr) (center) and reproducibility relative standard deviation (RSDR) (right). Grey dashed line in
repeatability and reproducibility panels indicate 20% and 50% reference lines.
D-67
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
O)
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M1315 JaFS Mean
1
L/S (L/kg)
100
10
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M1314 JaFS Release Overall SD
• M1314 JaFS Release Mean
L/S (L/kg)
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100
10 -:
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0.1
-M1314CFS Release RSD-r
-M1314 JaFS Release RSD-r
10
L/S (L/kg)
0
100
10 -:
ICP-OESRSD
0.1
-- M1314CFS Release RSD-R
- M1314JaFS Release RSD-R
1
L/S (L/kg)
10
Figure 68. Comparisons of statistical analyses for molybdenum from Method 1314 validation study materials.
Mean interval flux (upper) and cumulative release (lower) comparisons showing overall standard deviation intervals about the mean compared to method detection limits and
method limits of quantitation (left), repeatability relative standard deviation (RSDr) (center) and reproducibility relative standard deviation (RSDR) (right). Grey dashed line in
repeatability and reproducibility panels indicate 20% and 50% reference lines.
D-68
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
10
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0.1 -•
0.01 -•
0.001
:FS Release Overall Sp
^»-*M1314CFS Release Mean
M1314JaFS Release Overall
100
L/S (L/kg)
.a
JS
IB
10 -:
-M1314CFS Release RSD-r
-M1314JaFS Release RSD-r
ICP-OES RSD
100
.Q
'o
Q.
01
U.
10 -:
ICP-OES RSD
0.1
10
0.1
L/S (L/kg)
M1314 CFS Release RSD-R
M1314JaFS Release RSD-R
1
L/S (L/kg)
10
Figure 69. Comparisons of statistical analyses for lead from Method 1314 validation study materials.
Mean interval flux (upper) and cumulative release (lower) comparisons showing overall standard deviation intervals about the mean compared to method detection limits and
method limits of quantitation (left), repeatability relative standard deviation (RSDr) (center) and reproducibility relative standard deviation (RSDR) (right). Grey dashed line in
repeatability and reproducibility panels indicate 20% and 50% reference lines.
D-69
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
10
1 ••
jj 0.1
N
0.01
0.001
-M1314 CFS Overall SD
M1314 CFS Mean
-M1314JaFS Overall SD
M1314JaFSMean
0.1
1
L/S (L/kg)
100
!5
S
O.
01
N
10 -:
ICP-OES RSD
0.1
\
M1314CFSRSD-r
M1314JaFSRSD-r
1
L/S (L/kg)
10
100
.Q
'u
N
10
. ICP-OES RSD
0.1
M1314CFSRSD-R
M1314JaFSRSD-R
1
L/S (L/kg)
10
I
Ol
1000
100
10
1
0.1
0.01
0.001
0.0001
=
M1314CFSReleasi
• M1314ŁtS-Ke1ease Mean
L/S (L/kg)
100
10 -:
• ICP-OES RSD
0.1
M1314 CFS Release RSD-r
M1314JaFS Release RSD-r
10
L/S (L/kg)
100
u
•o
10 -:
ICP-OES RSD
M1314 CFS Release RSD-R
M1314JaFS Release RSD-R
0.1
1
L/S (L/kg)
10
Figure 70. Comparisons of statistical analyses for vanadium from Method 1314 validation study materials.
Mean interval flux (upper) and cumulative release (lower) comparisons showing overall standard deviation intervals about the mean compared to method detection limits and
method limits of quantitation (left), repeatability relative standard deviation (RSDr) (center) and reproducibility relative standard deviation (RSDR) (right). Grey dashed line in
repeatability and reproducibility panels indicate 20% and 50% reference lines.
D-70
-------
Interlaboratory Validation of LEAF Method 1314 and Method 1315
100
Ł
^-*
at
o
2
I
c
I
<
• Concentration in 9th Fraction (L/S10) 1—
^^s. 1
^>~-
'
'
'' 'm ^— ~ — J
|
1 a
S 10 •
• 1 — 1 Concentration in 2nd Fraction (L/S05)| Ł
— ~T ^
. ICP-OES RSD
— •— M1314 CFS RSD-R
• M1314 JaFS RSD-R
1 1 1 1 —
a.
|
1 .
; — •— M1314 CFS RSD-R
" — • — M1314 JaFS RSD-R
~7 I
Release at End of Test
(L/S = 10 mL/g-dry )
-
D ' • m J
: cn i
- ICP-OES RSD Release through 2nd Fraction
(L/S = 0.5 mL/g-dry )
0.1
10
0.1
10
L/S (L/kg)
L/S (L/kg)
Figure 71. Illustration of scenarios used to summarize precision for Method 1314 concentration (left) and
cumulative release (right).
Table 1. Method 1314 Precision Estimates for Concentration (2nd Interval).
•MTOM mm\
Aluminum
Barium
Boron
Cadmium
Calcium
Copper
Al
Ba
B
Cd
Ca
Cu
Magnesium Mg
Manganese
Mn
Molybdenum Mo
Lead
Thallium
Zinc
Pb
Tl
Zn
| Repeatability |
ICFS •
%RSDr |
11.1
6.2
9.0
JaFS 1
%RSDr |
12.3
7.3
8.1
10.0
3.8
15.0
5.6
8.6
8.5
14.6
8.3
8.8
9.3
11.8
9.8
14.0
8.0
^^^Bffil
| Reproducibility |
ICFS • JaFS 1
%RSDR | %RSDR |
16.0
11.5
19.6
19.7
13.6
17.6
15.8
13.1
31.1
33.7
20.3
25.4
26.9
14.6
15.5
19.8
12.9
14.3
24.7
26.4
B^^l
| Overall Mean|| 10% Repeatability || 20% Reproducibility |
E-71
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Table 2. Method 1314 Precision Estimates for Concentration (9 Interval).
•MITOM mm
Aluminum
Barium
Boron
Cadmium
Calcium
Copper
Al
Ba
B
Cd
Ca
Cu
Magnesium Mg
Manganese
Mn
Molybdenum Mo
Lead
Thallium
Zinc
Pb
Tl
Zn
| Repeatability |
1 CFS • JaFS 1
| %RSDr | %RSDr |
8.6
6.9
11.9
12.7
13.9
14.4
9.2
6.9
8.1
5.6
13.3
7.7
22.0
25.2
7.3
27.5
12.4
9.6
8.6
23.0
^^•J
1 Reproducibility |
CFS • JaFS 1
%RSDR | %RSDR |
16.6
23.0
14.3
28.2
24.2
23.9
14.6
12.7
15.2
52.5
31.8
53.3
26.6
28.4
14.8
54.4
23.5
19.2
16.0
58.5
B^^l
| Overall Mean|| 13% Repeatability || 28% Reproducibility |
Table 3. Method 1314 Precision Estimates for Cumulative Release to L/S =0.5 mL/g-dry.
•MM mm\
Aluminum
Barium
Boron
Cadmium
Calcium
Copper
Al
Ba
B
Cd
Ca
Cu
Magnesium Mg
Manganese
Mn
Molybdenum Mo
Lead
Thallium
Zinc
1
1
Pb
Tl
Zn
| Repeatability |
ICFS |
%RSDr |
10.3
5.5
5.3
IjaFS 1
%RSDr |
8.1
4.7
5.1
6.9
2.3
11.8
7.3
9.5
6.4
7.1
6.6
5.8
6.4
8.6
5.5
9.4
8.7
Material Mean|| 7% | 7% |
Overall Mean|| 7% Repeatability |
| Reproducibility |
ICFS ~~B JaFS 1
%RSDR | %RSDR |
22.9
11.9
16.6
12.4
7.9
12.2
16.9
11.9
32.4
15.8
24.4
18.9
22.8
10.0
17.7
21.3
12.0
14.0
21.0
29.1
| 18% | 18% |
| 18% Reproducibility j
E-72
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Table 4. Method 1314 Precision Estimates for Cumulative Release at L/S=10 mL/g-dry.
•MITOM mm
Aluminum
Barium
Boron
Cadmium
Calcium
Copper
Al
Ba
B
Cd
Ca
Cu
Magnesium Mg
Manganese
Mn
Molybdenum Mo
Lead
Thallium
Zinc
Pb
Tl
Zn
| Repeatability |
1 CFS • JaFS 1
| %RSDr | %RSDr |
4.6
3.4
2.9
7.2
6.2
4.4
2.2
2.1
3.9
3.6
4.6
4.2
7.0
4.4
1.8
4.5
9.5
2.9
4.0
7.3
^^•22
1 Reproducibility |
CFS • JaFS 1
%RSDR | %RSDR |
14.3
23.0
11.1
13.1
10.9
6.3
8.5
8.2
15.3
19.9
21.4
17.2
14.9
12.3
10.8
11.1
15.1
10.2
11.3
18.6
HE^H
| Overall Mean|| 5% Repeatability || 14% Reproducibility |
Table 5. Method 1314 Precision Estimate Summary.
Scenario
II Repeatability II Reproducibility I
#1 Concentration; 2nd Interval
#2 Concentration; 9m Interval
10%
13%
20%
28%
#3 Cumulative Release; L/S=0.5
7%
18%
#4 Cumulative Release; L/S=10
5%
14%
Mean Method 1314 Precisionll 9%
E-73
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Appendix F. Method 1315 Results and Precision Estimates
TABLE OF CONTENTS
Collected Concentration Data
SWA Solidified Waste Analog F-l
CFS Contaminated Field Soil F-6
Reference Laboratory Eluate Results (ICP-OES and Supplemental Analysis)
SWA Solidified Waste Analog F-ll
CFS Contaminated Field Soil F-17
Statistical Analysis for Selected Constituents
SWA Interval Flux Results F-23
CFS Interval Flux Results F-33
SWA Cumulative Release Results F-43
CFS Cumulative Release Results F-53
Comparison of Statistics for Study Materials F-63
Method 1315 Precision Estimates F-71
F-i
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
12 -
m .
8 -
6.
4 -
r '» 8
9S$>
0.01 0.1 1 10 10
Time (days)
•
•
•
o
o
•
o
•
•
o
SWA-L01-A
SWA-L04-A
SWA-L05-A
SWA-L06-A
SWA-L07-A
SWA-L09-A
SWA-L10-A
SWA-L11-A
SWA-Ref-A
SWA-Ref-D
ML
A
A
A
A
A
A
A
A
A
A
SWA-L01-B
SWA-L04-B
SWA-L05-B
SWA-L06-B
SWA-L07-B
SWA-L09-B
SWA-L10-B
SWA-L11-B
SWA-Ref-B
SWA-Ref-E
-MDL
•
•
D
D
D
D
D
D
•
D
SWA-L01-C
SWA-L04-C
SWA-L05-C
SWA-L06-C
SWA-L07-C
SWA-L09-C
SWA-L10-C
SWA-L11-C
SWA-Ref-C
SWA-Ref-F
Figure 1. Measured eluate pH from Method 1315 for material SWA.
F-l
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Ol
Ł
1
_3
n nnm -
i i
[ D
i
?B B
B By-
ML
MDL
0.01 0.1 1 10
Time (days)
0.1 -:
0.01
0.01
01
E 0.01
_3
m o.ooi
o.oooi
0.01
100
MDL
o.i i
Time (days)
10
100
_ ML
MDL
0.1
10
100
,§
g
0.
i °-1 •
E
E
3
n 0.01 -
00
0.
5 o.i -
01
^>
1
CQ 0-01
0.
1 1 B IB
ft J B B B B^gi
8f S
ML
Dl 0.1 1 10 10
Time (days)
n 9 f *
r
i
Ą
A ML
~~» '
M.P1,
Dl 0.1 1 10 10
Time (days)
_ I 1 1 Dm
i i? n u
ML
Dl 0.1 1 10 10
Time (days)
Time (days)
01
E
3
E
•a
a
u
nm -
•
n a
ML
MDL
0.01 0.1 1
Time (days)
10
100
•
•
•
o
o
•
o
o
•
0
SWA-L01-A
SWA-L04-A
SWA-L05-A
SWA-L06-A
SWA-L07-A
SWA-L09-A
SWA-L10-A
SWA-L11-A
SWA-Ref-A
SWA-Ref-D
M L
A
A
A
A
A
A
A
A
A
A
SWA-L01-B
SWA-L04-B
SWA-L05-B
SWA-L06-B
SWA-L07-B
SWA-L09-B
SWA-L10-B
SWA-L11-B
SWA-Ref-B
SWA-Ref-E
~ MDL
•
D
D
n
D
D
D
n
•
D
SWA-L01-C
SWA-L04-C
SWA-L05-C
SWA-L06-C
SWA-L07-C
SWA-L09-C
SWA-L10-C
SWA-L11-C
SWA-Ref-C
SWA-Ref-F
Figure 2. ICP-OES concentrations from Method 1315 for material SWA.
F-2
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
10 -
J1
J o.i -
a
U
0.01 -
o.c
1
Ol
^ 0.01
1
° 0.001
0.0001
0
_l U.I
O»
o.c
1
01
'e' 0.01
•i
-1 o.ooi
0.0001
0
a B B B B5Ł
1
ML
MDL
g> 0.1 •
E
u
|
ft B a
ML
MDL
1 0.1 1 10 100 0.01 0.1 1 10 10
Time (days) Time (days)
! ML
MDL
i O D El D D D " " '•
>pper (mg/L)
I 9
-1 h-1 h
ML
MDL
DID on ID D in in •
01 0.1 1 10 100 0.01 0.1 1 10 10
Time (days) Time (days)
i ii u *f
•3 o.i -
01
•a
a
a n m -
ML
MDL
•I OH O D D n mm
1 0.1 1 10 100 0.01 0.1 1 10 10
Time (days) Time (days)
ML
MDL
: ED El El D D n mm
01 0.1 1 10 1C
• SW
• SW
• SW
O SW
0 SW
• SW
O SW
O SW
• SW
• SW
)0 n.
M-L01-A A SWA-L01-B • SWA-L01-C
M-L04-A A SWA-L04-B • SWA-L04-C
M-L06-A A SWA-L06-B D SWA-L06-C
M-L07-A A SWA-L07-B D SWA-L07-C
M-L09-A A SWA-L09-B • SWA-L09-C
M-L11-A A SWA-L11-B D SWA-L11-C
M-Ref-A A SWA-Ref-B • SWA-Ref-C
M-Ref-D A SWA-Ref-E D SWA-Ref-F
Time (days)
Figure 3. ICP-OES concentrations from Method 1315 for material SWA.
F-3
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
5 o.i-
0»
•w
-------
Interlaboratory Validation of LEAF Method 1314 and Method 1315
J1
Ol
8
OT n m -
n nm -
• 5
1
;
^
}l "
B DW
ML
MDL
100 -
5 10-
Ol
•w
(A
n nm -
,- i
»* e
3 B|ff
ML
MDL
0.01
_j 0.1 • r
0.01 • r
Ł
E
85
o.ooi
0.0001
o.oi
^>
u
c
N
0.1
10
100
Time (days)
ML
MDL
01
0.01
100
10 - •
1
0.1
0.01 -•
0.1
Time (days)
0.001
0.1
10
100
0.01
0.1
Time (days)
Time (days)
0.01 0.1 1
Time (days)
10
100
0.01 0.1 1
Time (days)
D.01 •
nm .
i
* D D Q B D j
MDL 1 Ml [I!*
• O D D D D ^Q
0.01 0.1 1 10
Time (days)
100
10
100
_ML_
MDL
10
100
Ol U'1
Ł
E
ML
; MDL
•
1 E
3 E n
D
n n mrii
•w
E
^
g 0.01 -
•2
0.001 -1
i
h 8
In g| IgA
3 B-r HK
MDL
10
100
•
•
•
0
o
•
o
•
•
o
SWA-L01-A
SWA-L04-A
SWA-L05-A
SWA-L06-A
SWA-L07-A
SWA-L09-A
SWA-L10-A
SWA-L11-A
SWA-Ref-A
SWA-Ref-D
l\/l 1
1 VI L
A
A
A
A
A
A
A
A
A
A
SWA-L01-B
SWA-L04-B
SWA-L05-B
SWA-L06-B
SWA-L07-B
SWA-L09-B
SWA-L10-B
SWA-L11-B
SWA-Ref-B
SWA-Ref-E
i\/ini
~ 1 VI U L
•
•
D
D
D
D
D
D
•
D
SWA-L01-C
SWA-L04-C
SWA-L05-C
SWA-L06-C
SWA-L07-C
SWA-L09-C
SWA-L10-C
SWA-L11-C
SWA-Ref-C
SWA-Ref-F
Figure 5. ICP-OES concentrations from Method 1315 for material SWA.
F-5
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
0.01
0.1
17
m .
a -
6 •
4 -
n .
at
~ I *
1 1
if 1
5 SSI
10
100
Time (days)
•
•
0
0
o
o
•
0
CFS-L01-A
CFS-L04-A
CFS-L06-A
CFS-L07-A
CFS-L10-A
CFS-L11-A
CFS-Ref-A
CFS-Ref-D
nn\
IVIL
A
A
A
A
A
A
A
A
CFS-L01-B
CFS-L04-B
CFS-L06-B
CFS-L07-B
CFS-L10-B
CFS-L11-B
CFS-Ref-B
CFS-Ref-E
nn pil
~ IVI U L
•
D
D
D
D
D
•
n
CFS-LOl-C
CFS-L04-C
CFS-L06-C
CFS-L07-C
CFS-L10-C
CFS-L11-C
CFS-Ref-C
CFS-Ref-F
Figure 6. Measured eluate pH from Method 1315 for material CFS.
F-6
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
uminum (mg/L)
O
0 P
< 0.001
0.0001
0
^ 0.1 -
01
u
'E
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
100 -
1 ,.
"o
To 0-1 -
u
0.01 -
o.c
1
at
•^ 0.01
1
° 0.001
0.0001
0
o»
,§ 0.01 -
• Off
Ł
,, iow
ML
MDL
)1 0.1 1 10 10
Time (days)
(
J
I & ML
_ * "fa B-
f p MDL
°
IT o.i
?
E 0.01
g 0.001
0.0001
0 0
>pper (mg/L)
= P
-1 h-1 h
u
-
• nm dm n
ML
MDL
n nina
01 0.1 1 10 10
Time (days)
'I ll '
B If
ML
MDL
01 0.1 1 10 100 0.01 0.1 1 10 10
Time (days) Time (days)
ML
MDL
•3 o.i -
01
•a
a
a n m -
% dp ° H
aj B *
DQ
B ^T
ML
MDL
0.01 0.1 1 10 100 0.01 0.1 1 10 10
Time (days) Time (days)
f ••'-
E
----a
" MDL M B
—
H-4!*
0.01 0.1 1 10 1
Time (days)
•
•
o
o
o
•
•
o
CFS-LOl-A A CFS-L01-B •
CFS-L04-A A CFS-L04-B •
CFS-L06-A A CFS-L06-B D
CFS-L07-A A CFS-L07-B D
CFS-L10-A A CFS-L10-B D
CFS-L11-A A CFS-L11-B D
CFS-Ref-A A CFS-Ref-B •
CFS-Ref-D A CFS-Ref-E D
CFS-L01-C
CFS-L04-C
CFS-L06-C
CFS-L07-C
CFS-L10-C
CFS-L11-C
CFS-Ref-C
CFS-Ref-F
Figure 8. ICP-OES concentrations from Method 1315 for material CFS.
F-8
-------
Interlaboratory Validation of LEAF Method 1314 and Method 1315
Phosphorus (mg/L) Molybdenum (mg/L) Magnesium (mg/L)
0 0 0
bP0 bP0 bP0 i-c
ooP ooP ooPi->oc
h-1 h-1 h-1 h-1 h-1 h-1 h-1 h-1 h-^h-^h-^h-^OOC
O O O
j"
0>
u.i :
3 :
'E
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
1 -
—I
Ol
t 0.1-
o
o
55 o.oi-
o.c
1
^1 0.1
1
E 0.01
3
1
E
55 o.ooi
0.0001
0
O1
o> o-1
^>
_3
^ 0.01 -
1-
o.c
100
10
5 1
Ol
.§, 0.1
u
c
N 0.01
0.001
0.0001
0
. §a*
y D gB
91
M fa.
ML
MDL
1 0.1 1 10 10
Time (days)
i i BW
D
$ 9
• B g
• 4
s
ML
MDL
01 0.1 1 10 10
Time (days)
B B V
fl
ML
"9 '
• Qfl? MDL
1 0.1 1 10 10
Time (days)
; 3 e
-^
MDL
01 0.1 1 10 10
10 -
Ł. 1 "
3 n 1
1
0.01 -
* fi
A
\
}
!• B
•
ML
MDL
0.01 0
100 -
5 10 -
01
1
0.01 -
<•*
11 10 10
Time (mg/L)
«
J
1
! 9
••*
ML
MDL
0.01 0.1 1 10 10
Time (days)
Vanadium (me
I § f
-J. h-1 1-
ML
S_
a Ba?
a | i"5 8 B-
MDL ^ g^ g i
0.01 0.1 1 10 100
Time (days)
Time (days)
•
•
o
0
0
•
•
o
CFS-L01-A
CFS-L04-A
CFS-L06-A
CFS-L07-A
CFS-L10-A
CFS-L11-A
CFS-Ref-A
CFS-Ref-D
M L
A
A
A
A
A
A
A
A
CFS-L01-B
CFS-L04-B
CFS-L06-B
CFS-L07-B
CFS-L10-B
CFS-L11-B
CFS-Ref-B
CFS-Ref-E
~ M DL
•
D
D
D
D
D
•
n
CFS-LOl-C
CFS-L04-C
CFS-L06-C
CFS-L07-C
CFS-L10-C
CFS-L11-C
CFS-Ref-C
CFS-Ref-F
Figure 10. ICP-OES concentrations from Method 1315 for material CFS.
F-10
-------
Interlaboratory Validation of LEAF Method 1314 and Method 1315
^ 1
_l
Ol
,§ 0.1
|
.E 0.01
E
< 0.001
0.0001
0
01
." :
1 ;
r"^"
• 9*'*'
^^r-"-^
~*^*v
ML
MDL
01 0.1 1 10 1
Time (days)
„
1
I •
0.01
0.1
J1
"Si o.oi
Ł
E
_3
Ł• o.ooi
Ł
0.0001
0
G1
01 "-1
•*_-•
V
•c
tt
A «
s •
^*
V
ML
MDL
0.1 1 10 1C
Time (days)
ML
MDL
mony (mg/L)
3 P
•*• I-1 1-
DO O.C
1
01
^ 0.01
10
01 0.001
0 0
1 -
0.1 -
Ol
^ 0.01 -
E
Ł
0.001 -
t xxx
ML
1 0.1 1 10 1C
Time (days)
/*&-*=***
MDL
01 0.1 1 10 10
Time (days)
srr-^rrJ-r^
ML
MDL
01 0.1 1 10 100 0.01 0.1 1 10 10
Time (days) Time (days)
ML
MDL
D .
1 •- -• •--••••
• M1315 SWA-Ref-A
A M1315 SWA-Ref-B
• M1315 SWA-Ref-C
• M1315 SWA-Ref-D
A M1315 SWA-Ref-E
D M1315 SWA-Ref-F
- M1315SWARef95%PL
0.01 0.1 1 10 100
Time (days)
Figure 11. Method 1315 results for reference laboratory testing of SWA material compared to 95%
prediction limits.
F-ll
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
G"
E
Ł
ra
U
0
O»
•*_-•
E
u
0
G"
E
3
f
0.0
d n 1 -
01
•*_-•
&
o
u
o.c
IBB B
01 0.1 1 1
Time (days)
• — — -B-— B »
01 0.1 1 1
Time (days)
— -T- -r
r:~;fi;:I
1 0.1 1 1
Time (days)
-. — —.-
1 0.1 1 1
ML
MDL
0 1C
ML
-B— B-BM
0 1C
-•-§-•_
0 .ty
ML
MDL
0 1C
ML
MDL
— -.—
0 1
j1
? 1
Ł 1
E
3 n 1 -
.- 0.1
a
U
0 O.C
3
c 1 -
E 1
^>
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
i Inorganic Carbon
(mg/L)
S E
<0
5
i
^""
^^~
Xw
ML
MDL
0.01 0.1 1 10 1C
Time (days)
01
Ł "
u
•o
u.
0.01 -
|
/
"^^
^-«
\
\
\
^-0
/
7
»
4
\ ,/*.
\ ^MDL
'"
0.01 0.1 1 10 1C
Time (days)
CT
•c
ra
5 0.01 •
o.c
5 o.i
CT
•*_-•
| 0.01
(A
U
C
01
S 0.001
0.0001
0
ML
NUL
— ~
c
o
.a
(0
0 m
S1 oi
0 E
•a "^
> 1
1
Q
o.i 4
0 O.C
i
0.1
OI
,§, 0.01
1
HH
0.001
0 0
0.1 -
^^
^. 0.01 -
Oi
Ł o.ooi -
j
-''\ VA
'X'jX'v
\. / \l
-* ' nt
MDL
)1 0.1 1 10 10
Time (days)
1
ML j .-JLj^ _| • *^_
MDL "-^_^~ ° fkg
v A
» f "
W
01 0.1 1 10 1C
Time (days)
ML
MDL
)1 0.1 1 10 100 0.01 0.1 1 10 10
Time (days) Time (days)
,,-'''
-t;if
•~—M ML
0 MDL
• M1315 SWA-Ref-A
A M1315 SWA-Ref-B
• M1315 SWA-Ref-C
• M1315 SWA-Ref-D
A M1315 SWA-Ref-E
D M1315 SWA-Ref-F
- M1315SWARef95%PL
.01 0.1 1 10 100
Time (days)
Figure 13. Method 1315 results for reference laboratory testing of SWA material compared to 95%
prediction limits.
F-13
-------
Interlaboratory Validation of LEAF Method 1314 and Method 1315
Is
ra
ra
0
5 o.oi
01
E
"3
0
E
"
.±i n m -
O.C
"Si n 1 .
(A
|
O
o_
O.C
ML
MDL
1^ „ „ „ „ „„
01 0.1 1 10 1C
Time (days)
ML
MDL
01 0.1 1 10 1C
Time (days)
ML
1 0.1 1 10 1C
Time (days)
ML
MDL
. ..______..„
1 0.1 1 10 1C
J1
? 001
c u-ul
E
3
C
"o
)0 0
_l i
•S
a <
E :
)0 0.01
V
Q.
Q.
)0 O.C
)0
ML _- -^^J^l^^ig.
I ^-^' V
MDL B^ — "
01 0.1 1 10 10
Time (days)
^
' \ / J
6 1"" "* ^6
-- / ~\T
^-^/
ML
MDL
0.1 1 10 1C
Time (days)
ML
MDL
m _-_-___-_Q Q mD
1 0.1 1 10 1C
Time (days)
• M1315SWA-Ref-A
A M1315SWA-Ref-B
• M1315SWA-Ref-C
• M1315SWA-Ref-D
A M1315SWA-Ref-E
D M1315SWA-Ref-F
- M1315SWARef95%PL
Time (days)
Figure 14. Method 1315 results for reference laboratory testing of SWA material compared to 95%
prediction limits.
F-14
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
5 10"
Ol
E i
^> 1
|
a o.i -
3
°- o.oi -
r i
„__-;]
\
Cf'*
a=*v
ML
MDL
0.01 0.1 1 10 1C
Time (days)
Selenium (mg/L)
P
I-* I-* <:
™) 1
•
^
^'~
*\
Ir
ML
MDL
j1
"5; o.ooi
,§
E
_3
_| o.oooi
5
0.00001
0 C
G" :
1 :
c °'1 :
o
_o
55 o 01 - -
ML
MDL
m ,._, B_^_Q mD
1
.01 0.1 1 10 10
Time (days)
*te*sT
.*'''
• ^
ML
MDL
0.01 0.1 1 10 100 0.01 0.1 1 10 10
Time (days) Time (days)
100 -
5 10 -
O)
| 1-
1 "-1-
0.01 -
_ — 1
1
[
l-e^
•—i---
•- v
ML
MDL
j1 0.1
01
E 0.01
3
1
E
55 o.ooi
+********'*
z
^ ML
MDL
0.01 0.1 1 10 100 0.01 0.1 1 10 1C
Time (days) Time (days)
01
1U
•— •
S i -
Ł
in 0.1 -
0.01 -
1
/
X
X
X
N
\
\
\
i y- -*
/
/
^v 7
A
1 \
1 \
•Vjl-
\ /
\ ; ML
vfMDL
r "•• •
• M1315SWA-Ref-A
A M1315SWA-Ref-B
• M1315SWA-Ref-C
• M1315SWA-Ref-D
A M1315SWA-Ref-E
D M1315SWA-Ref-F
- M1315SWARef95%PL
0.01 0.1 1 10 100
Tiem (days)
Figure 15. Method 1315 results for reference laboratory testing of SWA material compared to 95%
prediction limits.
F-15
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
.2 0.1 -r
3
W
0.01 - >
I ^\
t
--""
:**
**V
ML
Mm
1
|
1-
ML
= MDL
— -^ — — — -- —
0.01 0.1 1 10 100 0.01 0.1 1 10 10
Time (days) Time (days)
^ 0.01 •
01
i- o.ooi -
0.
0.01
"5; o-ooi
,§
S o.oooi
0.00001
0
Zinc (mg/L)
I § P
-1 h-1 h-1 1-
ML
MDL
— -I——-—.—
H 1-H 1-H T
§ 1 {
(~l/6ui) uin;ue)!i
: ML
MDL
"i *~ — •-• •-•-•-••
01 0.1 1 10 100 0.01 0.1 1 10 1C
Time (days) Time (days)
ML
MDL
• - -•--• •--•-•-«
adium (mg/L)
I 9
* h-1 h
(0
,====^^«^V
ML
MDL
.01 0.1 1 10 100 0.01 0.1 1 10 10
Time (days) Time (days)
ML *
MDL I
»^_,-'A^
/
'7
•^ 1
-V-
^
^ — • • *""*
• M1315SWA-Ref-A
A M1315SWA-Ref-B
• M1315SWA-Ref-C
A M1315SWA-Ref-E
D M1315SWA-Ref-F
- M1315SWARef95%PL
0.01 0.1 1 10 100
Time (days)
Figure 16. Method 1315 results for reference laboratory testing of SWA material compared to 95%
prediction limits.
F-16
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
j1 0.1
Ol
E 0.01
c
E
5 o.ooi
0.0001
0
5 o.i -
01
u
'E
a
2 o.oi •
O.C
0.1
"Si o.oi
E
_3
"E1 0.001
•c
00
! * *' ML
MDL
01 0.1 1 10 1
Time (days)
ML
MDL J"=*:^:*'A
p
1 0.1 1 10 1C
Time (days)
ML
MDL
01 0.1 1 10 1C
Time (days)
l\
ML / "I
MDL ^ \ \
/ \
f ^
Antimony (mg/L)
I § P
•* I-1 h-i 1-
DO O.C
1
01
'g' 0.01
10
01 0.001
0.0001
0 0
1
0.1
Ol
^ 0.01
E
Ł
0.001
0.0001
0 0
ML
.MDL m ^= =-=*:::;Ł:t:ri(i
)1 0.1 1 10 1C
Time (days)
ML
MDL
01 0.1 1 10 10
Time (days)
^
* ^
ML
MDL
01 0.1 1 10 10
Time (days)
• M1315CFS-Ref-A
A M1315CFS-Ref-B
• M1315CFS-Ref-C
0 M1315CFS-Ref-D
A M1315CFS-Ref-E
D M1315CFS-Ref-F
- M1315CFS-Ref95%PL
0.01 0.1 1 10 100
Time (days)
Figure 17. Method 1315 results for reference laboratory testing of CFS material compared to 95%
prediction limits.
F-17
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
_l 1
CT
•c
(O
o.c
i
Ol
^ 0.01
_3
'to
u
U 0.001
n nnm
* V
^.-^^
r-r"
r*"*^,'
ML
MDL
Ol
_3
"o
(0 >-». j.
u
0.01 •
•S^''*
^.-— =*=
|^B—
-««*=M
Q ^
ML
MDL
1 0.1 1 10 100 0.01 0.1 1 10 1C
Time (days) Time (days)
• 1
^
*J
-^V
ML
MDL
•ide (mg/L)
E
-1 h-1 O C
5
u
0.01 -
n nm .
ML _^,
^'"'
• MDL t ft. '
*~
/
' f
7
4
/\
/ I
"? ^
\ 1
\ 1
\
/lP
/
0.01 0.1 1 10
Time (days)
100
0.01 0.1 1
Time (days)
10
100
E
_3
O 0.001 -
f
n nnm -
m m
. .
._, f
ML
MDL
, , „
c
E
±!
a
&
O 0.01 •
n nm -
^^* s
s''
AT
x-x
^f*m
* f
ML
MDL
0.01 0.1 1 10 100
Time (days)
0.01 0.1 1 10 100
Time (days)
d n 1 -
01
E
I
O
u
n nm -
ji-v~lT
• i ^- B
: *"
'
-r-joj
Jf--^ r
ML
MDL
• M1315CFS-Ref-A
A M1315CFS-Ref-B
• M1315CFS-Ref-C
0 M1315CFS-Ref-D
& M1315CFS-Ref-E
D M1315CFS-Ref-F
- M1315CFS-Ref95%PL
0.01 0.1 1 10 100
Time (days)
Figure 18. Method 1315 results for reference laboratory testing of CFS material compared to 95%
prediction limits.
F-18
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dissolved Inorganic Carbon
(mg/L)
0
b P
h-1 !->• h-1 C
o
01
•o
'i
_3
• a
XV
/ f ML
-"T
-"
MDL
01 0.1 1 10 1C
Time (days)
ML
/=
7 ~
71
^ \
-\ i-
, i
MUL , , ^
• 0
.V
\T
V
0.01 0.1 1 10 1C
Time (days)
«^>
ra
5 0.01 - •
• i
•*•
— -XT:-^"*
ML
MDL
c
o
.a
(0
u
u
15
O ™ 1 -
0 E
1
1
a
0 0.
0.1
•3 o.oi
Ol
Ł 0.001
0.0001
0 0
01
^^ 0 01 -
J
,- ;:i*^
: ML
MDL
31 0.1 1 10 10
Time (days)
: ML
MDL
DmQ
01 0.1 1 10 1C
Time (days)
ML ^i'^TJ^S
MDL . fllli-'/
0.01 0.1 1 10 100 0.01 0.1 1 10 10
Time (days) Time (days)
Magnesium (mg/L)
§ § p
J. h-i h-i h-1 C
* *
i
f
___^.^J
-""
t^^
'•*• ^p
ML
MDL
• M1315CFS-Ref-A
A M1315CFS-Ref-B
• M1315CFS-Ref-C
0 M1315CFS-Ref-D
& M1315CFS-Ref-E
D M1315CFS-Ref-F
- M1315CFS-Ref95%PL
0.01 0.1 1 10 100
Time (days)
Figure 19. Method 1315 results for reference laboratory testing of CFS material compared to 95%
prediction limits.
F-19
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
_| 1 -
I
gi
8 U-1
C
a
Ol
c
Ł 0.01 -
* t
^-^
**
^t*±*
H
ML
MDL
0.01 0.1 1 10 1C
Time (days)
i^i
^ 0.1 •
1!
*r
— ^
4^7'
--T-*
/
:
-V
ML
MDL
o
Molybdenum (mg/L)
0
8 b P
J. O O O .
h-1 h-1 h-1 1-
o
5 o.i-
O)
•*_-•
E
z
ML
MDL • J
;::ii: "*B*8
01 0.1 1 10 10
Time (days)
• a
Ł*ru*
/ \ -\
/ \ \MDL
r
V
0.01 0.1 1 10 100 0.01 0.1 1 10 1C
Time (days) Time (days)
^ n 1 -
o»
|
| 0.01 •
ML
MDL
' ^~ ^~ ^~ ^~ ^
1 H ^— — • —
— -.«
J1
a
f
g o.oi -
f
Q.
• a
ML
MDL
m M m m mmm
0.01 0.1 1 10 100 0.01 0.1 1 10 1C
Time (days) Time (days)
5
Ul
|
& 0.01 -
O
J=
Q.
_ML__
MDL S ^
J-""
Łt-^
• M1315CFS-Ref-A
A M1315CFS-Ref-B
• M1315CFS-Ref-C
0 M1315CFS-Ref-D
A M1315CFS-Ref-E
D M1315CFS-Ref-F
- M1315CFS-Ref95%PL
0.01 0.1 1 10 100
Time (days)
Figure 20. Method 1315 results for reference laboratory testing of CFS material compared to 95%
prediction limits.
F-20
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
5 10
Ol
Ł 1
1
a o-i
3
°- o.oi
0.001
0
G"
1
Seleniun
c
h
o.c
100
10
J1
1 *
E
.= 0.1
•a
&
0.01
0.001
0
Sulfate (mg/L)
h
<~i I-1 C
P I-* 0 C
h-' I-1 0 0 C
1 J 1 J 1 1
r-Z*
i -** **'
* *-"
*.*<*
*'*t
ML
MDL
01 0.1 1 10 1C
Time (days)
ML
MDL u I"
^ — — i
i
&
XX
P
*-v
1 0.1 1 10 1C
Time (days)
.*m^ --f^
\
* 1
- •
•=-*'
•"*>
ML
• r
MDL
01 0.1 1 10 1
Time (days)
1A
^'
.""
1
/=
^/
1 Ą
/
A
i \
VJ,
\ i
\ i
\ >
\ • i
\ v
V ML
MDL
•3 o.i
01
*E o.oi
3
'E
a
§ 0.001
0.0001
0 0
G"
1
c 0.1
o
_o
55 001 -
0 0.0
i
j1 0.1
01
E 0.01
3
1
E
55 o.ooi
0.0001
DO 0
s*
^-^
*^V
•
ML
MDL
01 0.1 1 10 10
Time (days)
x'J'-
..-,-
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
h I h
3 0 T-l T-l
3 ^ 6
(l/6iu) jnjins
0 01 • •
^^*v
»~
„„--;::*
tr"
ML
MDL
^i o.i -
1
1-
Y/— '"v
x^xX ML
^x'F
: 1 MDL
0.01 0.1 1 10 100 0.01 0.1 1 10 10
Time (days) Time (days)
^ 0.01 •
01
0.
0.01
Ol
|
S o.oooi
0.00001
0
5 i •
01
E n 1 -
U
C
N 0.01 -
ML
MDL
; • • • -• ••• — m- n nun
H i-\ i-\ T
§ 1 {
(~l/6ui) uin;ue)!i
: ML
MDL
01 0.1 1 10 100 0.01 0.1 1 10 1C
Time (days) Time (days)
ML
MDL
• •-- -•--• m--m-m-mm
adium (mg/L)
I 9
-1 h-1 h
ra
ML ^•'tjf'^^f
MDL ^ f~~~~ 5Js'
.01 0.1 1 10 100 0.01 0.1 1 10 10
Tiem (days) Time (days)
* i.
^___— J
„ — • '
P-^^^
,~,
ML
MDL
• M1315CFS-Ref-A
A M1315CFS-Ref-B
• M1315CFS-Ref-C
0 M1315CFS-Ref-D
A M1315CFS-Ref-E
D M1315CFS-Ref-F
- M1315CFS-Ref95%PL
0.01 0.1 1 10 100
Time (days)
Figure 22. Method 1315 results for reference laboratory testing of CFS material compared to 95%
prediction limits.
F-22
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
"Si °-01
E,
| 0.001
c
E
5 0.0001
0.00001
0.01
(A)
OI
E
3
E
i
0.001
0.0001 -•
0.00001
0.01
(C)
,
i
OI
E
3
E
3
0.001
5 0.0001
0.00001
0.01
!
0.1 -•
0.01
0.001 -•
OI
o
E
3
c
E
5 o.oooi -•
• SWA-FluxRefMean
SWA-Flux Ref 95% PL
• SWA-Flux Median of Lab Means
SWA-Flux 95% RCL
0.00001
0.1
10
100
0.01
10
100
Time (days)
(B)
Time (days)
•
•
o
o
o
0
o
o
•
o
—
SWA-Flux L01-A
SWA-Flux L04-A
SWA-Flux L05-A
SWA-Flux L06-A
SWA-Flux L07-A
SWA-Flux L09-A
SWA-Flux L10-A
SWA-Flux Lll-A
SWA-Flux Ref-A
SWA-Flux Ref-D
SWA-Flux 95% RCL
A
A
A
A
A
A
A
A
A
A
SWA-Flux L01-B
SWA-Flux L04-B
SWA-Flux L05-B
SWA-Flux L06-B
SWA-Flux L07-B
SWA-Flux L09-B
SWA-Flux L10-B
SWA-Flux Lll-B
SWA-Flux Ref-B
SWA-Flux Ref-E
•
D
D
D
D
D
D
D
•
D
SWA-Flux L01-C
SWA-Flux L04-C
SWA-Flux L05-C
SWA-Flux L06-C
SWA-Flux L07-C
SWA-Flux L09-C
SWA-Flux L10-C
SWA-Flux Lll-C
SWA-Flux Ref-C
SWA-Flux Ref-F
0.1 1 10
Time (days)
100 T
u
X
3
E
E
3
E
10 -:
ICP-OES RSD
M1315 SWA Overall CV
M1315 SWA Between Lab CV
M1315 SWA Within Lab CV
(D)
0.1 1 10
Time (days)
0.01
0.1
10
100
(E)
Time (days)
Figure 23. Aluminum interval flux from Method 1315 for material SWA. (A) calculated data as a function of
leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of
lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-23
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
o.i
u
Si
01
o
0.01 -
0.001
0.0001 -
0.00001
0.000001
0.01
(A)
OJ 0.01 -
in
O)
0.001 •
0.0001
I
c 0.00001
<
0.000001
0.01
(C)
I
"t-
"I-
0.1
in
IN
Ł
O)
o
>,
|
S3
<
0.01 -
0.001 •
0.0001
0.00001 -
0.000001
O SWA-FluxRef Mean
SWA-Flux Ref 95% PL
• SWA-Flux Median of Lab Means
SWA-Flux 95% RCL
0.1 1 10
Time (days)
100
0.01
(B)
0.1 1 10
Time (days)
•
•
o
o
o
0
o
o
•
o
—
SWA-Flux L01-A
SWA-Flux L04-A
SWA-Flux L05-A
SWA-Flux L06-A
SWA-Flux L07-A
SWA-Flux L09-A
SWA-Flux L10-A
SWA-Flux Lll-A
SWA-Flux Ref-A
SWA-Flux Ref-D
SWA-Flux 95% RCL
A
A
A
A
A
A
A
A
A
A
SWA-Flux L01-B
SWA-Flux L04-B
SWA-Flux L05-B
SWA-Flux L06-B
SWA-Flux L07-B
SWA-Flux L09-B
SWA-Flux L10-B
SWA-Flux Lll-B
SWA-Flux Ref-B
SWA-Flux Ref-E
•
D
D
D
D
D
D
D
•
D
SWA-Flux L01-C
SWA-Flux L04-C
SWA-Flux L05-C
SWA-Flux L06-C
SWA-Flux L07-C
SWA-Flux L09-C
SWA-Flux L10-C
SWA-Flux Lll-C
SWA-Flux Ref-C
SWA-Flux Ref-F
0.1 1 10
Time (days)
*•->
(N
E
oi u.uui
Ł
•.p
n nnnnm -
f
i
• M1315 SWA-Flux Mean
— Overall SD
^
^^x
^^^
100 T
u
X
O
'Ł
I
10 •:
M1315 SWA Overall CV
M1315 SWA Between Lab CV
M1315 SWA Within Lab CV
(D)
0.01 0.1 1 10
Time (days)
100
(E)
0.01 0.1 1
Time (days)
10
100
Figure 24. Antimony interval flux from Method 1315 for material SWA. (A) calculated data as a function of
leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of
lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-24
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
o.i
01
(A)
(C)
0.01 -
0.001
0.0001
< 0.00001
0.000001
0.01
01
0.01 -
0.001 •
0.0001
0.00001 -
0.000001
0.01
"t-
0.1 1
Time (days)
0.1
01
0.01 -
0.001 •
0.0001
< 0.00001 -
0.000001
O SWA-Flux Ref Mean
SWA-Flux Ref 95% PL
• SWA-Flux Median of Lab Means
SWA-Flux 95% RCL
0.01
10
100
(B)
Time (days)
•
•
o
o
o
0
o
o
•
o
—
SWA-Flux L01-A
SWA-Flux L04-A
SWA-Flux L05-A
SWA-Flux L06-A
SWA-Flux L07-A
SWA-Flux L09-A
SWA-Flux L10-A
SWA-Flux Lll-A
SWA-Flux Ref-A
SWA-Flux Ref-D
SWA-Flux 95% RCL
A
A
A
A
A
A
A
A
A
A
SWA-Flux L01-B
SWA-Flux L04-B
SWA-Flux L05-B
SWA-Flux L06-B
SWA-Flux L07-B
SWA-Flux L09-B
SWA-Flux L10-B
SWA-Flux Lll-B
SWA-Flux Ref-B
SWA-Flux Ref-E
•
D
D
D
D
D
D
D
•
D
SWA-Flux L01-C
SWA-Flux L04-C
SWA-Flux L05-C
SWA-Flux L06-C
SWA-Flux L07-C
SWA-Flux L09-C
SWA-Flux L10-C
SWA-Flux Lll-C
SWA-Flux Ref-C
SWA-Flux Ref-F
0.1 1 10
Time (days)
^ 0.01 -
Si
IN
^ 0.001 •
01
^ 0.0001 •
01
< 0.00001 •
X
I
•
^^
M1315 SWA-Flux Mean
— Overall SD
— Between Lab SD
— Within LabSD
X
X
0.000001 -I — • — i — i — i —
0.01 0.1 1 10
Time (days)
Arsenic Flux CV (o/0)
h-1
' O
: 7:=^--^,
"^^PT^r^
^''x •
s
: ICP-OES RSD
M1315 SWA Overall CV
M1315 SWA Between Lab CV
M1315 SWA Within Lab CV
w
^» ^*r
-/"X
100 0.01 0.1 1 10 10
Time (days)
(D)
Figure 25. Arsenic interval flux from Method 1315 for material SWA. (A) calculated data as a function of
leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of
lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-25
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
f-^
y n nm •
M
(N
|* 0.0001 -
E
_3
CO
n nnnnm -
0.
(A)
f™">
(N
|" 0.0001 •
E
3
CD
0.
(C)
*•->
a! 0 001 •
(N
E
^
g 0.0001 •
E
3
0.
D
J
1
A
•
01 0
»
1
B
I
•
.
01 0
=•
01 0
]
Ii
§ B 1
8 • |||
11 10 10
Time (days)
.
^JK^
^Sji
11 10 10
Time (days)
• M1315 SWA-Flux Mean
— Overall SD
Between Lab SD
%^4
1 1 10 10
(D)
0.01
O SWA-Flux Ref Mean
S WA-FI ux Ref 95% PL
SWA-Flux Median of Lab Means
SWA-Flux95% RCL
0.000001
0.01
(B)
0.1 1 10
Time (days)
•
•
o
o
o
0
o
o
•
o
—
SWA-Flux L01-A
SWA-Flux L04-A
SWA-Flux L05-A
SWA-Flux L06-A
SWA-Flux L07-A
SWA-Flux L09-A
SWA-Flux L10-A
SWA-Flux Lll-A
SWA-Flux Ref-A
SWA-Flux Ref-D
SWA-Flux 95% RCL
A
A
A
A
A
A
A
A
A
A
SWA-Flux L01-B
SWA-Flux L04-B
SWA-Flux L05-B
SWA-Flux L06-B
SWA-Flux L07-B
SWA-Flux L09-B
SWA-Flux L10-B
SWA-Flux Lll-B
SWA-Flux Ref-B
SWA-Flux Ref-E
•
D
D
D
D
D
D
D
•
D
SWA-Flux L01-C
SWA-Flux L04-C
SWA-Flux L05-C
SWA-Flux L06-C
SWA-Flux L07-C
SWA-Flux L09-C
SWA-Flux L10-C
SWA-Flux Lll-C
SWA-Flux Ref-C
SWA-Flux Ref-F
100
u
X
5 10
u.
E
-3
IS
CD
1 «*.
: ICP-OES RSD
^—
M1315
• M1315
V
i
%
\
t
i
SWA Overall CV
SWA Between Lab CV
SWA Within Lab CV
A.
i^
\ / * *
0.01
0.1
10
100
Time (days)
(E)
Time (days)
Figure 26. Barium interval flux from Method 1315 for material SWA. (A) calculated data as a function of
leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of
lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-26
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
(A)
8
IN
«•«.
E
O
§
(C)
*
IN
«•«.
E
(D)
0.001
01
^>
s
o
CO
0.0001 -
0.00001 -
0.000001
0.001
0.0001 -
0.00001 •
0.000001
0.001
0.0001 -
0.00001 •
"I-
0.001
0.0001 -
0.00001 •
0.000001
0.01 0.1 1 10
Time (days)
100
• SWA-FluxRefMean
SWA-Flux Ref 95% PL
• SWA-Flux Median of Lab Means
SWA-Flux 95% RCL
0.01
""F
0.1
10
(B)
Time (days)
•
•
o
o
o
0
o
o
•
o
—
SWA-Flux L01-A
SWA-Flux L04-A
SWA-Flux L05-A
SWA-Flux L06-A
SWA-Flux L07-A
SWA-Flux L09-A
SWA-Flux L10-A
SWA-Flux Lll-A
SWA-Flux Ref-A
SWA-Flux Ref-D
SWA-Flux 95% RCL
A
A
A
A
A
A
A
A
A
A
SWA-Flux L01-B
SWA-Flux L04-B
SWA-Flux L05-B
SWA-Flux L06-B
SWA-Flux L07-B
SWA-Flux L09-B
SWA-Flux L10-B
SWA-Flux Lll-B
SWA-Flux Ref-B
SWA-Flux Ref-E
•
D
D
D
D
D
D
D
•
D
SWA-Flux L01-C
SWA-Flux L04-C
SWA-Flux L05-C
SWA-Flux L06-C
SWA-Flux L07-C
SWA-Flux L09-C
SWA-Flux L10-C
SWA-Flux Lll-C
SWA-Flux Ref-C
SWA-Flux Ref-F
0.01 0.1 1 10
Time (days)
0.000001
100 -r
o
x
u.
s
o
CD
10 •:
ICP-OES RSD
M1315 SWA Overall CV
M1315 SWA Between Lab CV
M1315 SWA Within Lab CV
0.01
1 10
Time (days)
100
(E)
0.01 0.1 1
Time (days)
10
100
Figure 27. Boron interval flux from Method 1315 for material SWA. (A) calculated data as a function of
leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of
lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-27
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
0.1 T
u
Si
" 0.01 •;
01
^>
3 0.001
u
0.0001
(A)
(C)
0.1 T
0.0001
u
Si
O)
E
13
'u
0.1 T
0.01 -:
0.001 •:
•4-
0.1
u
Si
0.01 -
.3 0.001 -
'u
0.0001
O SWA-FluxRefMean
SWA-Flux Ref 95% PL
• SWA-Flux Median of Lab Means
SWA-Flux 95% RCL
"t-
"f-
4-
0.01 0.1 1 10
Time (days)
0.0001
0.01
(D)
Time (days)
100
(B)
0.01 0.1 1 10
Time (days)
100
•
•
O
O
O
O
O
O
•
O
—
SWA-Flux L01-A
SWA-Flux L04-A
SWA-Flux L05-A
SWA-Flux L06-A
SWA-Flux L07-A
SWA-Flux L09-A
SWA-Flux L10-A
SWA-Flux Lll-A
SWA-Flux Ref-A
SWA-Flux Ref-D
SWA-Flux 95% RCL
A
A
A
A
A
A
A
A
A
A
SWA-Flux L01-B
SWA-Flux L04-B
SWA-Flux L05-B
SWA-Flux L06-B
SWA-Flux L07-B
SWA-Flux L09-B
SWA-Flux L10-B
SWA-Flux Lll-B
SWA-Flux Ref-B
SWA-Flux Ref-E
•
D
D
D
D
D
D
D
•
D
SWA-Flux L01-C
SWA-Flux L04-C
SWA-Flux L05-C
SWA-Flux L06-C
SWA-Flux L07-C
SWA-Flux L09-C
SWA-Flux L10-C
SWA-Flux Lll-C
SWA-Flux Ref-C
SWA-Flux Ref-F
0.01 0.1 1 10
Time (days)
100 T
.i 10 -:
E
3
IS
U
M1315 SWA Overall CV
M1315 SWA Between Lab CV
M1315 SWA Within Lab CV
0.01
0.1
10
100
(E)
Time (days)
Figure 28. Calcium interval flux from Method 1315 for material SWA. (A) calculated data as a function of
leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of
lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-28
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
(A)
Ol
O
E
3
0.001
0.0001 -
0.00001 -
O 0.000001 -
u
0.0000001
0.01
(C)
0.001
Ol
.E
E
3
0.0001 -
0.00001 -
O 0.000001 -
u
0.0000001
f-^
u
w n nnm -
(N
0»
E
3
E
u
n nnnnnm -
«
i
i — i
',
D
Ol
.E
E
3
0.001
0.0001 -
0.00001 -
p 0.000001 -
0.0000001
SWA-FluxRefMean
•SWA-FluxRef95%PL
SWA-Flux Median of Lab Means
-SWA-Flux95%RCL
0.01 0.1 1 10
Time (days)
100
(B)
0.01 0.1 1 10
Time (days)
100
•
•
O
O
O
0
O
O
•
O
—
SWA-Flux L01-A
SWA-Flux L04-A
SWA-Flux L05-A
SWA-Flux L06-A
SWA-Flux L07-A
SWA-Flux L09-A
SWA-Flux L10-A
SWA-Flux Lll-A
SWA-Flux Ref-A
SWA-Flux Ref-D
SWA-Flux 95% RCL
A
A
A
A
A
A
A
A
A
A
SWA-Flux L01-B
SWA-Flux L04-B
SWA-Flux L05-B
SWA-Flux L06-B
SWA-Flux L07-B
SWA-Flux L09-B
SWA-Flux L10-B
SWA-Flux Lll-B
SWA-Flux Ref-B
SWA-Flux Ref-E
•
D
D
D
D
D
D
D
•
D
SWA-Flux L01-C
SWA-Flux L04-C
SWA-Flux L05-C
SWA-Flux L06-C
SWA-Flux L07-C
SWA-Flux L09-C
SWA-Flux L10-C
SWA-Flux Lll-C
SWA-Flux Ref-C
SWA-Flux Ref-F
1 10
Time (days)
100
M1315 SWA-Flux Mean
Overall SD
-Between LabSD
-Within LabSD
100 -r
u
X
u. 10 •:
E
3
|
U
ICP-OES RSD
M1315 SWA Overall CV
M1315 SWA Between Lab CV
M1315 SWA Within Lab CV
4-
4-
(D)
0.01 0.1 1 10
Time (days)
100
(E)
0.01 0.1 1
Time (days)
10
100
Figure 29. Chromium interval flux from Method 1315 for material SWA. (A) calculated data as a function of
leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of
lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-29
-------
Interlaboratory Validation of LEAF Method 1314 and Method 1315
1 T-
01
^>
E
I
So
Q.
(A)
(C)
0.1 T
0.01 •:
0.001 -r
0.0001
O 0.01 ••
E
3
'in
in
1
0.001 ••
0.0001
0.01
0.1 ••
Dl
.E 0.01 ••
E
3
'in
jo 0.001 -•
o
Q.
0.0001
•4-
"t-
"t-
0.1 -
Ł. 0.01 -
E
3
'in
in
1
0.001 -
0.0001
SWA-Flux Ref Mean
SWA-Flux Ref 95% PL
SWA-Flux Median of Lab Means
-SWA-Flux 95% RCL
0.01 0.1 1 10 100
Time (days)
1 T
0.1 T
0.01
0.1
10
100
(B)
Time (days)
•
•
o
o
o
0
o
o
•
o
—
SWA-Flux L01-A
SWA-Flux L04-A
SWA-Flux L05-A
SWA-Flux L06-A
SWA-Flux L07-A
SWA-Flux L09-A
SWA-Flux L10-A
SWA-Flux Lll-A
SWA-Flux Ref-A
SWA-Flux Ref-D
SWA-Flux 95% RCL
A
A
A
A
A
A
A
A
A
A
SWA-Flux L01-B
SWA-Flux L04-B
SWA-Flux L05-B
SWA-Flux L06-B
SWA-Flux L07-B
SWA-Flux L09-B
SWA-Flux L10-B
SWA-Flux Lll-B
SWA-Flux Ref-B
SWA-Flux Ref-E
•
D
D
D
D
D
D
D
•
D
SWA-Flux L01-C
SWA-Flux L04-C
SWA-Flux L05-C
SWA-Flux L06-C
SWA-Flux L07-C
SWA-Flux L09-C
SWA-Flux L10-C
SWA-Flux Lll-C
SWA-Flux Ref-C
SWA-Flux Ref-F
0.1 1 10 100
Time (days)
• M1315 SWA-Flux Mean
— Overall SD
-- Between Lab SD
----- Within Lab SD
•4-
100 T
%
Potassium Flux
10 -:
ICP-OES RSD
M1315 SWA Overall CV
M1315 SWA Between Lab CV
M1315 SWA Within Lab CV
(D)
0.01 0.1 1 10 100
Time (days)
(E)
0.01 0.1 1
Time (days)
10
100
Figure 30. Potassium interval flux from Method 1315 for material SWA. (A) calculated data as a function of
leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of
lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-30
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
(A)
(C)
E
3
01
w
V)
(D)
0.1 -•
Oi
o.oi
0.001 -•
0.0001
0.00001
0.1 -•
0.00001
O SWA-FluxRefMean
SWA-Flux Ref 95% PL
• SWA-Flux Median of Lab Means
SWA-Flux 95% RCL
0.01
0.1
10
100
0.01
10
100
Time (days)
(B)
Time (days)
oi
o
E
_3
01
w
(A
0.00001
•
•
O
O
O
0
O
O
•
O
—
SWA-Flux L01-A
SWA-Flux L04-A
SWA-Flux L05-A
SWA-Flux L06-A
SWA-Flux L07-A
SWA-Flux L09-A
SWA-Flux L10-A
SWA-Flux Lll-A
SWA-Flux Ref-A
SWA-Flux Ref-D
SWA-Flux 95% RCL
A
A
A
A
A
A
A
A
A
A
SWA-Flux L01-B
SWA-Flux L04-B
SWA-Flux L05-B
SWA-Flux L06-B
SWA-Flux L07-B
SWA-Flux L09-B
SWA-Flux L10-B
SWA-Flux Lll-B
SWA-Flux Ref-B
SWA-Flux Ref-E
•
D
D
D
D
D
D
D
•
D
SWA-Flux L01-C
SWA-Flux L04-C
SWA-Flux L05-C
SWA-Flux L06-C
SWA-Flux L07-C
SWA-Flux L09-C
SWA-Flux L10-C
SWA-Flux Lll-C
SWA-Flux Ref-C
SWA-Flux Ref-F
0.01
0.1 1 10
Time (days)
n m -
n nnm -
s
Ł*.
^*<
(
^
5 M1315 SWA-Flux Mean
— Overall SD
^*
^X,
100
M1315 SWA Overall CV
M1315 SWA Between Lab CV
M1315 SWA Within Lab CV
4-
4-
0.01 0.1 1 10
Time (days)
100
(E)
0.01 0.1 1
Time (days)
10
100
Figure 31. Selenium interval flux from Method 1315 for material SWA. (A) calculated data as a function of
leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of
lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-31
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
f-^
u
tfl n nnm -
(N
""-*
01
E
_3
n nnnnnm -
0.
(A)
*•->
U
(N
Dl
E
3
'•5
S
0.
(C)
*•->
w 0.0001 •
(N
Ł
Dl
E
3
'•5
Ł
0.
i
01 0
01 0
01 0
^
a
B E
A R
|Jj
*
11 10 10
Time (days)
^^
M^
^L-B;^
iNNi
^M
UJ&D
1
11 10 10
Time (days)
• M1315 SWA-Flux Mean
— Overall SD
Between Lab SD
* S^^^
^Ł^s
"*\*
1 1 10 10
Time (days)
0.001
0.0001 -
,5 o.ooooi -
E
3
IB
I
0.000001 •
0.0000001
SWA-FluxRefMean
-SWA-FluxRef95%PL
SWA-Flux Median of Lab Means
-SWA-Flux95%RCL
"f-
0.01
0.1
10
100
(B)
Time (days)
•
•
o
o
o
0
o
o
•
o
—
SWA-Flux L01-A
SWA-Flux L04-A
SWA-Flux L05-A
SWA-Flux L06-A
SWA-Flux L07-A
SWA-Flux L09-A
SWA-Flux L10-A
SWA-Flux Lll-A
SWA-Flux Ref-A
SWA-Flux Ref-D
SWA-Flux 95% RCL
A
A
A
A
A
A
A
A
A
A
SWA-Flux L01-B
SWA-Flux L04-B
SWA-Flux L05-B
SWA-Flux L06-B
SWA-Flux L07-B
SWA-Flux L09-B
SWA-Flux L10-B
SWA-Flux Lll-B
SWA-Flux Ref-B
SWA-Flux Ref-E
•
D
D
D
D
D
D
D
•
D
SWA-Flux L01-C
SWA-Flux L04-C
SWA-Flux L05-C
SWA-Flux L06-C
SWA-Flux L07-C
SWA-Flux L09-C
SWA-Flux L10-C
SWA-Flux Lll-C
SWA-Flux Ref-C
SWA-Flux Ref-F
100 -fr
U
X
iZ 10
E
3
^
IS
I
~~,^
- ICP-OES RSD
X.-'\
— M1315 SWA Overall CV
M1315 SWA Between Lab CV
M1315 SWA Within Lab CV
0.01
0.1
(E)
"f-
Time (days)
10
100
Figure 32. Vanadium interval flux from Method 1315 for material SWA. (A) calculated data as a function of
leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of
lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-32
-------
Interlaboratory Validation of LEAF Method 1314 and Method 1315
?
(N
Dl
E
C n nnnm -
E
3
<
n nnnnm .
Ho
Hi
!
S
8
i I
8
1
1 5
n - ^af
°$i
(A)
0.001
0.000001
0.01
(C)
(D)
0.001
O)
E
3
E
3
0.0001 •
0.00001 -
0.000001
O CFS-Flux Ref Mean
- —CFS-Flux Ref 95% PL
• CFS-Flux Median of Lab Means
CFS-Flux 95% RCL
0.01 0.1 1 10
Time (days)
100
0.01
(B)
0.1 1 10
Time (days)
•
•
o
o
o
o
•
o
—
CFS-Flux L01-A
CFS-Flux L04-A
CFS-Flux L06-A
CFS-Flux L07-A
CFS-Flux L10-A
CFS-Flux Lll-A
CFS-Flux Ref-A
CFS-Flux Ref-D
95% RCL
A
A
A
A
A
A
A
A
CFS-Flux L01-B
CFS-Flux L04-B
CFS-Flux L06-B
CFS-Flux L07-B
CFS-Flux L10-B
CFS-Flux Lll-B
CFS-Flux Ref-B
CFS-Flux Ref-E
•
D
D
D
D
D
•
D
CFS-Flux L01-C
CFS-Flux L04-C
CFS-Flux L06-C
CFS-Flux L07-C
CFS-Flux L10-A
CFS-Flux Lll-C
CFS-Flux Ref-C
CFS-Flux Ref-F
0.1 1 10
Time (days)
*•->
%
in
IN
E 0 0001 •
^
01
o
E
c 0.00001 •
E
3
<
*
s
•^
^
• M1315 CFS
Overall SD
•^ —Between L
^
c^\
•^
-Flux Mean
bSD
SD
V
X
Aluminum F
i-
c
^^
: ICP-OES RSD
*"*'"••»•. *
//\\
^•'~\\
M1315 CFS Overall CV
• M1315 CFS Between Lab CV
M1315 CFS Within Lab CV
^
^V\
\/
0.01 0.1 1 10
Time (days)
100 0.01 0.1 1
Time (days)
(E)
10
100
Figure 33. Aluminum interval flux from Method 1315 for material CFS. (A) calculated data as a function of
leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of
lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-33
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
*•->
8
(N
Ł
m
>
§
<
n nnnnnm .
"B4
i
i
,1
i
i a
!S
I
1 gj^
(A)
0.001
0.001
w 0.0001 •
,§ 0.00001 -
I
B 0.000001 -
C
0.0000001
(D)
0.001
0.0000001
O CFS-FluxRefMean
CFS-FluxRef95%PL
• CFS-Flux Median of Lab Means
CFS-Flux 95% RCL
0.01 0.1 1 10 100
Time (days)
0.01
(B)
0.1 1 10
Time (days)
•
•
O
o
o
0
•
o
—
CFS-Flux L01-A
CFS-Flux L04-A
CFS-Flux L06-A
CFS-Flux L07-A
CFS-Flux L10-A
CFS-Flux Lll-A
CFS-Flux Ref-A
CFS-Flux Ref-D
95% RCL
A
A
A
A
A
A
A
A
CFS-Flux L01-B
CFS-Flux L04-B
CFS-Flux L06-B
CFS-Flux L07-B
CFS-Flux L10-B
CFS-Flux Lll-B
CFS-Flux Ref-B
CFS-Flux Ref-E
•
D
D
D
D
D
•
D
CFS-Flux L01-C
CFS-Flux L04-C
CFS-Flux L06-C
CFS-Flux L07-C
CFS-Flux L10-A
CFS-Flux Lll-C
CFS-Flux Ref-C
CFS-Flux Ref-F
• M1315 CFS-Flux Mean
— OverallSD
• — Between Lab SD
Within Lab SD
4-
4-
4-
100 T
mony Flux CV (%
10 •:
M1315 CFS Overall CV
M1315 CFS Between Lab CV
M1315 CFS Within Lab CV
4-
4-
0.01 0.1 1 10 100
Time (days)
0.01
0.1
10
100
(E)
Time (days)
Figure 34. Antimony interval flux from Method 1315 for material CFS. (A) calculated data as a function of
leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of
lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-34
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
0.001
01
o
E
3
IS
CD
0.0001 -
0.00001 •
0.000001
• a
(A)
0.001
0.000001
0.01
(C)
0.001
0.000001
(D)
0.01 0.1 1
Time (days)
0.001
01
o
E
3
IS
CD
0.0001 -
0.00001 •
0.000001
• CFS-FluxRef Mean
CFS-FluxRef95%PL
I CFS-Flux Median of Lab Means
CFS-Flux 95% RCL
0.01
10
100
(B)
Time (days)
•
•
o
o
o
0
•
o
—
CFS-Flux L01-A
CFS-Flux L04-A
CFS-Flux L06-A
CFS-Flux L07-A
CFS-Flux L10-A
CFS-Flux Lll-A
CFS-Flux Ref-A
CFS-Flux Ref-D
95% RCL
A
A
A
A
A
A
A
A
CFS-Flux L01-B
CFS-Flux L04-B
CFS-Flux L06-B
CFS-Flux L07-B
CFS-Flux L10-B
CFS-Flux Lll-B
CFS-Flux Ref-B
CFS-Flux Ref-E
•
D
D
D
D
D
•
D
CFS-Flux L01-C
CFS-Flux L04-C
CFS-Flux L06-C
CFS-Flux L07-C
CFS-Flux L10-A
CFS-Flux Lll-C
CFS-Flux Ref-C
CFS-Flux Ref-F
0.1 1 10
Time (days)
• M1315 CFS-Flux Mean
— OverallSD
Between LabSD
Within LabSD
4-
4-
100
u
X
2 10
u.
E
3
ICP-OES RSD
M1315 CFS Overall CV
-- M1315 CFS Between Lab CV
----- M1315 CFS Within Lab CV
4-
4-
0.01 0.1 1 10
Time (days)
100
0.01
0.1
10
100
(E)
Time (days)
Figure 35. Barium interval flux from Method 1315 for material CFS. (A) calculated data as a function of
leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of
lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-35
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
f™">
i
^ 0.0001 •
E
•••.
E
o
0 0.00001 •
I
4
A
g
"8 8
8|i
•
0.01 0.1 1 10
,A) Time (days)
f™">
i
^ 0.0001 •
E
•••.
E
o
0 0.00001 •
Ł
0 000001 •
r~\
\
5
^h
i
1C
^Ji
Y«
0.01 0.1 1 10
Time (days)
(C)
f™">
i
^ 0.0001 •
Ł
01
o
0 0.00001 •
&
n nnnnm -
• M1315 CFS
Overall SD
Between L<
^
-Flux Mean
bSD
SD
>
f™">
i
" o.o
•••.
E
o
0 0.00
0.000
)0
(B)
<
<
C
C
C
i
<
c
100
Boron Flux CV (%)
E
-•• O C
4- . ., . | 1
D01 -:
•
\ a
101 1 ' '
0.01
Lv
\^WJ\
\ . ^^ ft o>
| | ->.,•- x u LDO
CFS-Flux Ref Mean \_ D
- CFS-Flux Ref 95% PL y^
CFS-Flux Median of Lab Means
0.1 1 10 100
Time (days)
» CFS-Flux L01-A A CFS-Flux L01-B • CFS-Flux L01-C
» CFS-Flux L04-A A CFS-Flux L04-B • CFS-Flux L04-C
> CFS-Flux L06-A A CFS-Flux L06-B D CFS-Flux L06-C
) CFS-Flux L07-A A CFS-Flux L07-B D CFS-Flux L07-C
) CFS-Flux L10-A A CFS-Flux L10-B D CFS-Flux L10-A
> CFS-Flux Lll-A A CFS-Flux Lll-B • CFS-Flux Lll-C
( CFS-Flux Ref-A A CFS-Flux Ref-B • CFS-Flux Ref-C
) CFS-Flux Ref-D A CFS-Flux Ref-E D CFS-Flux Ref-F
—95% RCL
__=^^_.
CP-OES RSD
\;;;; ^^
\, T
'^S
— M1315 CFS Overall CV
M1315 CFS Between Lab CV
M1315 CFS Within Lab CV
(D)
0.01 0.1 1 10
Time (days)
100
0.01
0.1
10
100
(E)
Time (days)
Figure 36. Boron interval flux from Method 1315 for material CFS. (A) calculated data as a function of
leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of
lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-36
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
0.01
0.001
Dl
o
E
.2 0.0001 -;
•o
IS
u
0.00001
(A)
0.01
0.001
,
Dl
o
E
3
.2 0.0001
•c
IS
u
0.00001
(C)
In
8 D
4-
4-
4-
o.oi
I
1 0.001
.2 0.0001 -;
E
•c
IS
u
0.00001
CFS-FluxRefMean
-CFS-FluxRef95%PL
CFS-Flux Median of Lab Means
-CFS-Flux95%RCL
•M-
4-
0.01 0.1 1 10
Time (days)
100
(B)
0.01 0.1 1 10
Time (days)
100
•
•
o
o
o
0
•
o
—
CFS-Flux L01-A
CFS-Flux L04-A
CFS-Flux L06-A
CFS-Flux L07-A
CFS-Flux L10-A
CFS-Flux Lll-A
CFS-Flux Ref-A
CFS-Flux Ref-D
95% RCL
A
A
A
A
A
A
A
A
CFS-Flux L01-B
CFS-Flux L04-B
CFS-Flux L06-B
CFS-Flux L07-B
CFS-Flux L10-B
CFS-Flux Lll-B
CFS-Flux Ref-B
CFS-Flux Ref-E
•
D
D
D
D
D
•
D
CFS-Flux L01-C
CFS-Flux L04-C
CFS-Flux L06-C
CFS-Flux L07-C
CFS-Flux L10-A
CFS-Flux Lll-C
CFS-Flux Ref-C
CFS-Flux Ref-F
i
1 0.001 •
01
E
•2 0.0001 •
^
IS
U
>
•
•«>
iS"-.;*«sj
^^ "55*.
o.ooooi 4 — • — i — • — ~~
0.01 0.1
Vss
-LLU
• M1315 CFS-Flux Mean
— OverallSD
— Between Lab SD
trigs-
^^^X^^&
%>
*^^r^^*~^+^4 V
""^v.
•-» i>
: < \
• ICP-OES RSD *la,-'
M1315 CFS Overall CV
M1315 CFS Between Lab CV
M1315 CFS Within Lab CV
100 0.01 0.1 1 10 10
Time (days)
(D)
Figure 37. Cadmium interval flux from Method 1315 for material CFS. (A) calculated data as a function of
leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of
lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-37
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
O)
Ą
3
'o
0.1 •
0.01
0.001
(A)
0.001
0.01
(C)
(D)
4-
4-
4-
1 -F
Oi
o
E
3
'o
0.01
0.001
• CFS-Flux Ref Mean
CFS-Flux Ref 95% PL
• CFS-Flux Median of Lab Means
CFS-Flux 95% RCL
4-
4-
0.01 0.1 1 10
Time (days)
100
(B)
0.01 0.1 1
Time (days)
10
100
•
•
o
o
o
o
•
o
—
CFS-Flux L01-A
CFS-Flux L04-A
CFS-Flux L06-A
CFS-Flux L07-A
CFS-Flux L10-A
CFS-Flux Lll-A
CFS-Flux Ref-A
CFS-Flux Ref-D
95% RCL
A
A
A
A
A
A
A
A
CFS-Flux L01-B
CFS-Flux L04-B
CFS-Flux L06-B
CFS-Flux L07-B
CFS-Flux L10-B
CFS-Flux Lll-B
CFS-Flux Ref-B
CFS-Flux Ref-E
•
D
D
D
D
D
•
D
CFS-Flux L01-C
CFS-Flux L04-C
CFS-Flux L06-C
CFS-Flux L07-C
CFS-Flux L10-A
CFS-Flux Lll-C
CFS-Flux Ref-C
CFS-Flux Ref-F
1 10
Time (days)
100
1
NŁ 0.1 •
01
'o
IS
U
n nni -
N
: >
• M1315 CFS-Flux Mean
— Overall SD
Between Lab SD
• ^ Within Lab SD
"^%^
X^§».^
S;?^^
100
— M1315CFS Overall CV
M1315 CFS Between Lab CV
M1315 CFS Within Lab CV
0.01 0.1 1 10
Time (days)
100
0.01
0.1
10
100
(E)
Time (days)
Figure 38. Calcium interval flux from Method 1315 for material CFS. (A) calculated data as a function of
leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of
lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-38
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
0.1 T
01
0.01 ••
0.001 •;
o.oooi
0.01
(A)
in
IN
E
•««.
E
o
•o
0.01 -:
0.001 ••
(C)
0.0001
0.1
•o
IS
0.01 •:
0.001 •;
0.0001
(D)
0.1
8
<» 0.01
01
o
•5 o.ooi -
0.0001
CFS-Flux Ref Mean
- CFS-Flux Ref 95% PL
CFS-Flux Median of Lab Means
-CFS-Flux 95% RCL
4-
0.1
10
100
Time (days)
(B)
0.01 0.1 1
Time (days)
10
100
•
•
o
o
o
o
•
o
—
CFS-Flux L01-A
CFS-Flux L04-A
CFS-Flux L06-A
CFS-Flux L07-A
CFS-Flux L10-A
CFS-Flux Lll-A
CFS-Flux Ref-A
CFS-Flux Ref-D
95% RCL
A
A
A
A
A
A
A
A
CFS-Flux L01-B
CFS-Flux L04-B
CFS-Flux L06-B
CFS-Flux L07-B
CFS-Flux L10-B
CFS-Flux Lll-B
CFS-Flux Ref-B
CFS-Flux Ref-E
•
D
D
D
D
D
•
D
CFS-Flux L01-C
CFS-Flux L04-C
CFS-Flux L06-C
CFS-Flux L07-C
CFS-Flux L10-A
CFS-Flux Lll-C
CFS-Flux Ref-C
CFS-Flux Ref-F
Time (days)
• M1315 CFS-Flux Mean
— OverallSD
Between LabSD
Within LabSD
4-
4-
4-
100
M1315CFS Overall CV
M1315 CFS Between Lab CV
M1315 CFS Within Lab CV
0.01 0.1 1 10
Time (days)
100
(E)
0.01 0.1 1
Time (days)
10
100
Figure 39. Lead interval flux from Method 1315 for material CFS. (A) calculated data as a function of leaching
time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of lab
means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines) shown
with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line) and
pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of variation
for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker indicating
a generalized analytical uncertainty.
F-39
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
o.oi
0.001
Ul
• o.oooi -•
in
1
0.00001
'*.
(I
(A)
0.01
0.001 -
Ł. 0.0001 -
E
3
'in
in
1
0.00001 -
0.000001
(C)
4-
4-
4-
0.01
0.001 -
01
.E 0.0001 -
E
3
J3 o.ooooi -
s.
0.000001
• CFS-Flux Ref Mean
CFS-Flux Ref 95% PL
• CFS-Flux Median of Lab Means
CFS-Flux 95% RCL
^v
4-
4-
4-
0.01 0.1 1 10 100
Time (days)
(B)
0.01 0.1 1 10
Time (days)
100
•
•
o
o
o
0
•
o
—
CFS-Flux L01-A
CFS-Flux L04-A
CFS-Flux L06-A
CFS-Flux L07-A
CFS-Flux L10-A
CFS-Flux Lll-A
CFS-Flux Ref-A
CFS-Flux Ref-D
95% RCL
A
A
A
A
A
A
A
A
CFS-Flux L01-B
CFS-Flux L04-B
CFS-Flux L06-B
CFS-Flux L07-B
CFS-Flux L10-B
CFS-Flux Lll-B
CFS-Flux Ref-B
CFS-Flux Ref-E
•
D
D
D
D
D
•
D
CFS-Flux L01-C
CFS-Flux L04-C
CFS-Flux L06-C
CFS-Flux L07-C
CFS-Flux L10-A
CFS-Flux Lll-C
CFS-Flux Ref-C
CFS-Flux Ref-F
1
E 0.001 -
01
E
'in 0.0001 •
in
1
n nnnni -
,
' t
s
;>x
>X^N.
• M1315 CF!
Overall SD
Between L
X
— -\
•••
-Flux Mean
abSD
SD
***
Potassium Flux CV (%)
E
-* O C
: ICP-OES RSD
-^""^^"^^•^••^^
^^vA
----v.:;--; —
\^j
CFS-F
CFS-F
ux Overall CV
ux Between Lab CV
ux Within Lab CV
(D)
0.01 0.1 1 10 100
Time (days)
0.01
0.1
10
100
(E)
Time (days)
Figure 40. Potassium interval flux from Method 1315 for material CFS. (A) calculated data as a function of
leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of
lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-40
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
0.001
0.0001 -
Dl
,§ 0.00001 -
E
_3
«. 0.000001 -
01
0.0000001
1
1
,5
m
0.01
(A)
0.001
0.0000001
0.01
(C)
0.001
Ł 0.0001 -
•••.
01
.| 0.00001 •
01
w
W
0.000001
0.1 1 10
Time (days)
1 10
Time (days)
0.001
0.0001 -
,5 o.ooooi -
E
3
01
«
V)
0.000001 -
0.0000001
O CFS-Flux Ref Mean
CFS-Flux Ref 95% PL
• CFS-Flux Median of Lab Means
CFS-Flux 95% RCL
4-
4-
100
(B)
0.01 0.1 1 10
Time (days)
100
•
•
o
o
o
0
•
o
—
CFS-Flux L01-A
CFS-Flux L04-A
CFS-Flux L06-A
CFS-Flux L07-A
CFS-Flux L10-A
CFS-Flux Lll-A
CFS-Flux Ref-A
CFS-Flux Ref-D
95% RCL
A
A
A
A
A
A
A
A
CFS-Flux L01-B
CFS-Flux L04-B
CFS-Flux L06-B
CFS-Flux L07-B
CFS-Flux L10-B
CFS-Flux Lll-B
CFS-Flux Ref-B
CFS-Flux Ref-E
•
D
D
D
D
D
•
D
CFS-Flux L01-C
CFS-Flux L04-C
CFS-Flux L06-C
CFS-Flux L07-C
CFS-Flux L10-A
CFS-Flux Lll-C
CFS-Flux Ref-C
CFS-Flux Ref-F
100
• M1315 CFS-Flux Mean
— OverallSD
Between Lab SD
Within Lab SD
4-
4-
4-
(D)
0.01 0.1 1 10
Time (days)
100
(E)
*•->
5
X
3
E
3
'E
•5
w
"^^^
---"""""
: ICP-OES RSD
M1315 CFS Overall CV
M1315 CFS Between Lab CV
M1315 CFS Within Lab CV
0.01 0.1 1
[/
*Ł-+-
^ .'
•»/
10 10
Time (days)
Figure 41. Selenium interval flux from Method 1315 for material CFS. (A) calculated data as a function of
leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of
lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-41
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
0.0001
0.00001 •
O
E
| 0.000001 -
IS
I
0.0000001
(A)
0.0001
0.0000001
0.01
(C)
8 •
0.0001
0.0000001
O CFS-FluxRefMean
CFS-FluxRef95%PL
• CFS-Flux Median of Lab Means
CFS-Flux 95% RCL
0.01 0.1 1
Time (days)
10
100
0.01
(B)
0.1 1 10
Time (days)
•
•
O
O
O
O
•
O
—
CFS-Flux L01-A
CFS-Flux L04-A
CFS-Flux L06-A
CFS-Flux L07-A
CFS-Flux L10-A
CFS-Flux Lll-A
CFS-Flux Ref-A
CFS-Flux Ref-D
95% RCL
A
A
A
A
A
A
A
A
CFS-Flux L01-B
CFS-Flux L04-B
CFS-Flux L06-B
CFS-Flux L07-B
CFS-Flux L10-B
CFS-Flux Lll-B
CFS-Flux Ref-B
CFS-Flux Ref-E
•
D
D
D
D
D
•
D
CFS-Flux L01-C
CFS-Flux L04-C
CFS-Flux L06-C
CFS-Flux L07-C
CFS-Flux L10-A
CFS-Flux Lll-C
CFS-Flux Ref-C
CFS-Flux Ref-F
0.1 1 10
Time (days)
u.uuui •
f™">
1
1 0.00001 •
•••.
E
^^
E
•2 n nnnnm
^ U.UUUUUl
IS
c
IS
>
n nnnnnm -
t>
\
• M1315 CFS-Flux Mean
— Overall SD
•^ — Between Lab SD
\r
^>^
^N» **»*
^*^*$i** -^A
^•5^^^
100
X
E 10
E
_3
IS
I
M1315 CFS Overall CV
M1315 CFS Between Lab CV
M1315 CFS Within Lab CV
(D)
0.01 0.1 1 10
Time (days)
100
0.01
0.1
10
100
(E)
Time (days)
Figure 42. Vanadium interval flux from Method 1315 for material CFS. (A) calculated data as a function of
leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of
lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-42
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
10000 T
*Ł 1000 T
01
E
3
C
E
3
100 T
0.01
(A)
10000
1000 -•
I
100 T
E
3
_c
I 10
0.01
(C)
10000
1000
01
o
Ł 100 -;
3
I 1
0.01
(D)
I
4-
4-
4-
0.1 1 10
Time (days)
100
(B)
0.1
1 10
Time (days)
100
M1315 SWA-Release Mean
Overall SD
Between Lab SD
Within LabSD
0.1
10
100
Time (days)
(E)
—
inn -
s
1 -1 — 1
0.01 0.
• SWA-Release L01-A
• SWA-Release L04-A
• SWA-Release L05-A
• SWA-Release L06-A
0 SWA-Release L07-A
• SWA-Release L09-A
• SWA-Release L10-A
• SWA-Release Lll-A
• SWA-Release Ref-A
• SWA-Release Ref-D
95% RCL
:
^^
^
: ICP-OES RSD
^,-
""x^
z
-—- <.
^
^
• SWA-Re ease Ref Mean
SV
D SV
1
Time
VA-ReleaseRef95%PL
VA-Re ease Median of Lab Means
VA-Re ease 95% RCL
1 10 100
(days)
A SWA-Re ease L01-B •
A SWA-Re ease L04-B •
A SWA-Release L05-B •
A SWA-Release L06-B D
A SWA-Release L07-B D
A SWA-Release L09-B •
A SWA-Release L10-B D
A SWA-Release Lll-B •
A SWA-Release Ref-B •
A SWA-Release Ref-E D
^
*fc
*>.^
*»^
M1315 SV
1 M1315SV
0.01 0.1
"**^:
VAOverallCV
VA Between Lab CV
VA Within Lab CV
SWA-Release L01-C
SWA-Release L04-C
SWA-Release L05-C
SWA-Release L06-C
SWA-Release L07-C
SWA-Release L09-C
SWA-Release L10-C
SWA-Release Lll-C
SWA-Release Ref-C
SWA-Release Ref-F
^->X-SB- -
1 10 100
Time (days)
Figure 43. Aluminum cumulative release from Method 1315 for material SWA. (A) calculated data as a
function of leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to
the median of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals
(red lines) shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue,
dashed line) and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E)
coefficient of variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to
5% marker indicating a generalized analytical uncertainty.
F-43
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
1000
o
•a
100 •
10 -
0.01
(A)
1000
(C)
1000
o
•a
100 •
10 -
1000 T-r
o
•a
100 ••
10 -;
SWA-Release Ref 95% PL
O SWA-Release Ref Mean
• SWA-Release Median of Lab Means
SWA-Release 95% RCL
4-
4-
0.1
10
100
Time (days)
(B)
0.01 0.1 1
Time (days)
10
100
•
•
0
o
o
o
o
o
•
o
—
SWA-Release L01-A
SWA-Release L04-A
SWA-Release L05-A
SWA-Release L06-A
SWA-Release L07-A
SWA-Release L09-A
SWA-Release L10-A
SWA-Release Lll-A
SWA-Release Ref-A
SWA-Release Ref-D
95% RCL
A
A
A
A
A
A
A
A
A
A
SWA-Release L01-B
SWA-Release L04-B
SWA-Release L05-B
SWA-Release L06-B
SWA-Release L07-B
SWA-Release L09-B
SWA-Release L10-B
SWA-Release Lll-B
SWA-Release Ref-B
SWA-Release Ref-E
•
D
D
D
D
D
D
D
•
D
SWA-Release L01-C
SWA-Release L04-C
SWA-Release L05-C
SWA-Release L06-C
SWA-Release L07-C
SWA-Release L09-C
SWA-Release L10-C
SWA-Release Lll-C
SWA-Release Ref-C
SWA-Release Ref-F
0.1 1 10
Time (days)
100
M1315 SWA-Release Mean
Overall SD
-Between LabSD
-Within Lab SD
4-
4-
4-
100 T
o
•a
ICP-OES RSD
M1315 SWA Overall CV
M1315 SWA Between Lab CV
M1315 SWA Within Lab CV
4-
4-
(D)
0.01 0.1 1 10
Time (days)
100
(E)
0.01 0.1 1
Time (days)
10
100
Figure 44. Antimony cumulative release from Method 1315 for material SWA. (A) calculated data as a
function of leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to
the median of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals
(red lines) shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue,
dashed line) and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E)
coefficient of variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to
5% marker indicating a generalized analytical uncertainty.
F-44
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
1000
100 •
10 -
0.01
(A)
1000
(c)
1000
100 •
01
10 -
1000 -rf
100 ••
01
I
<
10 -;
O SWA-Release Ref Mean
SWA-Release Ref 95% PL
• SWA-Release Median of Lab Means
SWA-Release 95% RCL
4-
0.1
10
100
Time (days)
(B)
0.01 0.1 1
Time (days)
10
100
•
•
0
o
o
o
o
o
•
o
—
SWA-Release L01-A
SWA-Release L04-A
SWA-Release L05-A
SWA-Release L06-A
SWA-Release L07-A
SWA-Release L09-A
SWA-Release L10-A
SWA-Release Lll-A
SWA-Release Ref-A
SWA-Release Ref-D
95% RCL
A
A
A
A
A
A
A
A
A
A
SWA-Release L01-B
SWA-Release L04-B
SWA-Release L05-B
SWA-Release L06-B
SWA-Release L07-B
SWA-Release L09-B
SWA-Release L10-B
SWA-Release Lll-B
SWA-Release Ref-B
SWA-Release Ref-E
•
D
D
D
D
D
D
D
•
D
SWA-Release L01-C
SWA-Release L04-C
SWA-Release L05-C
SWA-Release L06-C
SWA-Release L07-C
SWA-Release L09-C
SWA-Release L10-C
SWA-Release Lll-C
SWA-Release Ref-C
SWA-Release Ref-F
0.1 1 10
Time (days)
100
M1315 SWA-Release Mean
Overall SD
-Between LabSD
-Within Lab SD
4-
4-
4-
100 T
0)
in
I
o
10 •:
ICP-OES RSD
M1315 SWA Overall CV
M1315 SWA Between Lab CV
M1315 SWA Within Lab CV
(D)
1.01 0.1 1 10
Time (days)
100
(E)
0.01 0.1 1
Time (days)
10
100
Figure 45. Arsenic cumulative release from Method 1315 for material SWA. (A) calculated data as a function
of leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-45
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
1000
(7> 100 -fe
01
10 -
E
3
0.1
o.oi
(A)
0.01
(C)
1000
0.01
(D)
i
1000 -E-r
0.1
10
100
o bWA-Re
— SWA-Release Ref 95% PL
I SWA-Release Median of Lab Means
SWA-Release 95% RCL
0.1
0.01
Time (days)
(B)
0.1 1
Time (days)
E
-«*,,
E
Łj in -
E
3
(0
0.1 •
y
i
§
D
A,
•
;
^^
/
/
/
/
\ !
EL*
j-HT
Hi JU
xr~*
x'
rflg
•rfi
•j-ty
• SWA-Release L01-A A SWA-Release L01-B • SWA-Release L01-C
• SWA-Release L04-A A SWA-Release L04-B • SWA-Release L04-C
• SWA-Release L05-A A SWA-Release L05-B • SWA-Release L05-C
O SWA-Release L06-A A SWA-Release L06-B D SWA-Release L06-C
0 SWA-Release L07-A A SWA-Release L07-B D SWA-Release L07-C
• SWA-Release L09-A A SWA-Release L09-B • SWA-Release L09-C
O SWA-Release L10-A A SWA-Release L10-B D SWA-Release L10-C
• SWA-Release Lll-A A SWA-Release Lll-B • SWA-Release Lll-C
• SWA-Release Ref-A A SWA-Release Ref-B • SWA-Release Ref-C
• SWA-Release Ref-D A SWA-Release Ref-E D SWA-Release Ref-F
95% RCL
0.1
10
100
Time (days)
100
u
01
in
E
_3
'C
is
CD
10 -:
ICP-OES RSD
M1315 SWA Overall CV
M1315 SWA Between Lab CV
M1315 SWA Within Lab CV
0.01
0.1
10
100
Time (days)
(E)
Time (days)
Figure 46. Barium cumulative release from Method 1315 for material SWA. (A) calculated data as a function
of leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-46
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
100
01
10 -:
Ł
o
CD
4-
4-
100 T
Oi
E
o
CD
O SWA-Release Ref Mean
SWA-Release Ref 95% PL
• SWA-Release Median of Lab Means
SWA-Release 95% RCL
(A)
0.01 0.1 1
Time (days)
10
100
0.01
(B)
0.1 1
Time (days)
•
•
0
o
o
o
o
o
•
o
—
SWA-Release L01-A
SWA-Release L04-A
SWA-Release L05-A
SWA-Release L06-A
SWA-Release L07-A
SWA-Release L09-A
SWA-Release L10-A
SWA-Release Lll-A
SWA-Release Ref-A
SWA-Release Ref-D
95% RCL
A
A
A
A
A
A
A
A
A
A
SWA-Release L01-B
SWA-Release L04-B
SWA-Release L05-B
SWA-Release L06-B
SWA-Release L07-B
SWA-Release L09-B
SWA-Release L10-B
SWA-Release Lll-B
SWA-Release Ref-B
SWA-Release Ref-E
•
D
D
D
D
D
D
D
•
D
SWA-Release L01-C
SWA-Release L04-C
SWA-Release L05-C
SWA-Release L06-C
SWA-Release L07-C
SWA-Release L09-C
SWA-Release L10-C
SWA-Release Lll-C
SWA-Release Ref-C
SWA-Release Ref-F
0.01
(C)
0.1 1
Time (days)
100
01
10 -:
S
o
CD
M1315 SWA-Release Mean
Overall SD
- Between Lab SD
-Within LabSD
4-
4-
(D)
0.01 0.1 1
Time (days)
10
100
(E)
Boron Release CV (%)
E
O C
• :r:r~:^
: ICP-OES RSD
"*"••-.. " """" """ *~~
"*"
SWA-Release Overall CV
SWA-Release Between
abCV
5CV
0.01 0.1 1 10 10
Time (days)
Figure 47. Boron cumulative release from Method 1315 for material SWA. (A) calculated data as a function of
leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of
lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-47
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
100000
10000 -;
01
^ 1000
E
3
a
u
100 -•
10
0.01
(A)
100000
10000 -;
,
Dl
^ 1000 -r
E
3
a
U
10
0.01
(C)
4-
4-
4-
10
u
100 -•
10
100000 --
10000 -;
01
^ 1000
E
3
'o
SWA-Release Ref 95% PL
O SWA-Release Ref Mean
• SWA-Release Median of Lab Means
SWA-Release 95% RCL
4-
4-
0.1 1 10
Time (days)
100
(B)
0.01 0.1 1
Time (days)
10
100
•
•
0
o
o
o
o
o
•
o
—
SWA-Release L01-A
SWA-Release L04-A
SWA-Release L05-A
SWA-Release L06-A
SWA-Release L07-A
SWA-Release L09-A
SWA-Release L10-A
SWA-Release Lll-A
SWA-Release Ref-A
SWA-Release Ref-D
95% RCL
A
A
A
A
A
A
A
A
A
A
SWA-Release L01-B
SWA-Release L04-B
SWA-Release L05-B
SWA-Release L06-B
SWA-Release L07-B
SWA-Release L09-B
SWA-Release L10-B
SWA-Release Lll-B
SWA-Release Ref-B
SWA-Release Ref-E
•
D
D
D
D
D
D
D
•
D
SWA-Release L01-C
SWA-Release L04-C
SWA-Release L05-C
SWA-Release L06-C
SWA-Release L07-C
SWA-Release L09-C
SWA-Release L10-C
SWA-Release Lll-C
SWA-Release Ref-C
SWA-Release Ref-F
0.1 1 10
Time (days)
:alcium (mg/m2
i-
!-•• C
-* O C
DOC
DOC
m -
r
• M131
__ _ Betwe
—t
5 SWA-Release Mean
USD
en LabSD
i Lab SD
^
*•
Y
*>
Calcium Release CV (%)
E
-•• O C
' \^
'• ICP-OES RSD
^X
*
•^
M131.
M131.
SWA Overall CV
SWA Between Lab CV
SWA Within Lab CV
(D)
0.01 0.1 1
Time (days)
10 100 0.01 0.1 1
Time (days)
10
100
Figure 48. Calcium cumulative release from Method 1315 for material SWA. (A) calculated data as a function
of leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-48
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
100 T
Ol
o
E
3
u
10 -:
4-
100
SWA-Release Ref 95% PL
O SWA-Release Ref Mean
• SWA-Release Median of Lab Means
SWA-Release 95% RCL
Ol
o
E
3
U
(A)
0.01 0.1 1
Time (days)
10
100
0.01
(B)
1 10
Time (days)
100
•
•
0
O
O
O
O
O
•
O
—
SWA-Release L01-A
SWA-Release L04-A
SWA-Release L05-A
SWA-Release L06-A
SWA-Release L07-A
SWA-Release L09-A
SWA-Release L10-A
SWA-Release Lll-A
SWA-Release Ref-A
SWA-Release Ref-D
95% RCL
A
A
A
A
A
A
A
A
A
A
SWA-Release L01-B
SWA-Release L04-B
SWA-Release L05-B
SWA-Release L06-B
SWA-Release L07-B
SWA-Release L09-B
SWA-Release L10-B
SWA-Release Lll-B
SWA-Release Ref-B
SWA-Release Ref-E
•
D
D
D
D
D
D
D
•
D
SWA-Release L01-C
SWA-Release L04-C
SWA-Release L05-C
SWA-Release L06-C
SWA-Release L07-C
SWA-Release L09-C
SWA-Release L10-C
SWA-Release Lll-C
SWA-Release Ref-C
SWA-Release Ref-F
0.01
(C)
0.1 1
Time (days)
100
01
o
E
3
I
u
10 -:
M1315 SWA-Release Mean
Overall SD
-Between LabSD
-Within Lab SD
4-
4-
100 T
U
01
in
is
0)
•
1
O
10 •:
ICP-OES RSD
M1315 SWA Overall CV
M1315 SWA Between Lab CV
M1315 SWA Within Lab CV
4-
4-
(D)
0.01 0.1 1
Time (days)
10
100
0.01
0.1
10
100
(E)
Time (days)
Figure 49. Chromium cumulative release from Method 1315 for material SWA. (A) calculated data as a
function of leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to
the median of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals
(red lines) shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue,
dashed line) and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E)
coefficient of variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to
5% marker indicating a generalized analytical uncertainty.
F-49
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
100000
10000 -;
Ul
o
E
3
s.
1000 -r
100 -•
10
0.01
(A)
100000
10000 -•
Ul
o
E
3
1000 -r
10
0.01
(C)
100000
10000
01
O
E
3
1000 -•
100 T
10
0.01
(D)
t
4-
4-
100000
10000 T
Ul
O
E
3
s.
1000 -r
100 -•
10
SWA-ReleaseRef95%PL
SWA-Release Ref Mean
SWA-Release Median of Lab Means
-SWA-Release 95% RCL
4-
0.1 1
Time (days)
10
100
(B)
0.01 0.1 1
Time (days)
",,—
10
100
• SWA-Release L01-A
• SWA-Release L04-A
• SWA-Release L05-A
O SWA-Release L06-A
O SWA-Release L07-A
• SWA-Release L09-A
O SWA-Release L10-A
• SWA-Release Lll-A
• SWA-Release Ref-A
• SWA-Release Ref-D
95% RCL
A SWA-Release L01-B
A SWA-Release L04-B
A SWA-Release L05-B
A SWA-Release L06-B
A SWA-Release L07-B
A SWA-Release L09-B
A SWA-Release L10-B
A SWA-Release Lll-B
A SWA-Release Ref-B
A SWA-Release Ref-E
• SWA-
• SWA-
• SWA-
• SWA-
D SWA
• SWA-
• SWA-
• SWA-
• SWA-
D SWA
Release L01-C
Release L04-C
Release L05-C
Release L06-C
Release L07-C
Release L09-C
Release L10-C
Release Lll-C
Release Ref-C
Release Ref-F
0.1 1 10
Time (days)
•
M1315 SWA-Release Mean
Between Lab SD
100
I
E
3
10 -:
M1315 SWA Overall CV
M1315 SWA Between Lab CV
M1315 SWA Within Lab CV
0.1
10
100
0.01
0.1
10
100
Time (days)
(E)
Time (days)
Figure 50. Potassium cumulative release from Method 1315 for material SWA. (A) calculated data as a
function of leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to
the median of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals
(red lines) shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue,
dashed line) and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E)
coefficient of variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to
5% marker indicating a generalized analytical uncertainty.
F-50
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
10000 T
1000 -•
01
o
E
3
100 T
10 -•
10000
1 1000 -
01
E
3
1
Ł
100 -
10 -
SWA-Release Ref 95% PL
O SWA-Release Ref Mean
• SWA-Release Median of Lab Means
SWA-Release 95% RCL
4-
4-
4-
"T
0.01
0.1
10
100
(A)
Time (days)
(B)
0.01 0.1 1
Time (days)
10
100
10000
1000 -r
Ul
o
E
3
•
•
0
o
o
o
o
o
•
o
—
SWA-Release L01-A
SWA-Release L04-A
SWA-Release L05-A
SWA-Release L06-A
SWA-Release L07-A
SWA-Release L09-A
SWA-Release L10-A
SWA-Release Lll-A
SWA-Release Ref-A
SWA-Release Ref-D
95% RCL
A
A
A
A
A
A
A
A
A
A
SWA-Release L01-B
SWA-Release L04-B
SWA-Release L05-B
SWA-Release L06-B
SWA-Release L07-B
SWA-Release L09-B
SWA-Release L10-B
SWA-Release Lll-B
SWA-Release Ref-B
SWA-Release Ref-E
•
D
D
D
D
D
D
D
•
D
SWA-Release L01-C
SWA-Release L04-C
SWA-Release L05-C
SWA-Release L06-C
SWA-Release L07-C
SWA-Release L09-C
SWA-Release L10-C
SWA-Release Lll-C
SWA-Release Ref-C
SWA-Release Ref-F
0.01
(C)
0.1 1
Time (days)
fp
^ 1000 -
m
Selenium
I-*
-* o
3 0
• M131
Betw
x
^
5 SWA-Release Mean
USD
2en LabSD
n LabSD
'"Ł
'•S^'
•*&•
<***
100 T
I
O
u
% 10 -:
IS
a
&
E
13
01
w
V)
M1315 SWA Overall CV
-- M1315 SWA Between Lab CV
----- M1315 SWA Within Lab CV
(D)
0.01 0.1 1 10
Time (days)
100
0.01
0.1
10
100
(E)
Time (days)
Figure 51. Selenium cumulative release from Method 1315 for material SWA. (A) calculated data as a function
of leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-51
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
100
01
o
E
3
'•5
IB
I
10 -•
1 -;
0.1
(A)
0.01
(C)
4-
4-
100
01
o
E
3
'•5
IB
I
10 -
1 -
0.1
SWA-Release Ref 95% PL
O SWA-Release Ref Mean
• SWA-Release Median of Lab Means
SWA-Release 95% RCL
4-
4-
0.01 0.1 1 10
Time (days)
100
(B)
0.01 0.1 1
Time (days)
10
100
• SWA-Release L01-A
• SWA-Release L04-A
• SWA-Release L05-A
O SWA-Release L06-A
O SWA-Release L07-A
• SWA-Release L09-A
O SWA-Release L10-A
• SWA-Release Lll-A
• SWA-Release Ref-A
• SWA-Release Ref-D
95% RCL
A SWA-Release L01-B
A SWA-Release L04-B
A SWA-Release L05-B
A SWA-Release L06-B
A SWA-Release L07-B
A SWA-Release L09-B
A SWA-Release L10-B
A SWA-Release Lll-B
A SWA-Release Ref-B
A SWA-Release Ref-E
• SWA-
• SWA-
• SWA-
• SWA-
D SWA
• SWA-
• SWA-
• SWA-
• SWA-
D SWA
Release L01-C
Release L04-C
Release L05-C
Release L06-C
Release L07-C
Release L09-C
Release L10-C
Release Lll-C
Release Ref-C
Release Ref-F
1 10
Time (days)
100
E
3
a
I
1 1 -
: • M1315 SWA-Release M
'. — Overall SD
' Between LabSD
"&&
""
ean
^
P*
100
I
O
U
8!
IB
a
&
E
3
'•5
IB
I
•a 10 -:
M1315 SWA Overail CV
M1315 SWA Between Lab CV
M1315 SWA Within Lab CV
(D)
0.01 0.1 1 10
Time (days)
100
0.01
0.1
10
100
(E)
Time (days)
Figure 52. Vanadium cumulative release from Method 1315 for material SWA. (A) calculated data as a
function of leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to
the median of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals
(red lines) shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue,
dashed line) and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E)
coefficient of variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to
5% marker indicating a generalized analytical uncertainty.
F-52
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
100
10 -•
fP
«•«.
01
E
3
c
1 1
0.1
0.01
(A)
100 -F
0.01
(C)
100
Ol
o
E
3
E
3
10 -•
1 -;
0.1
4-
0.1 1
Time (days)
10
0.1 1 10
Time (days)
• M1315 CFS-Release Mean
— Overall SD
Between Lab SD
Within Lab SD
(D)
0.01 0.1 1 10
Time (days)
100 -E-
fP
Ol
o
E
3
C
10 -
0.1
-CFS-ReleaseRef95%PL
CFS-Release Ref Mean
CFS-Release Median of Lab Means
-CFS-Release 95% RCL
4-
4-
100
(B)
0.01 0.1 1
Time (days)
10
100
• CFS-Release L01-A
• CFS-Release L04-A
• CFS-Release L06-A
• CFS-Release L07-A
• CFS-Release L10-A
• CFS-Release Lll-A
• CFS-Release Ref-A
O CFS-Release Ref-D
95% RCL
A CFS-
A CFS-
A CFS-
A CFS-
A CFS-
A CFS-
A CFS-
A CFS-
Release L01-B
Release L04-B
Release L06-B
Release L07-B
Release L10-B
Release Lll-B
Release Ref-B
Release Ref-E
• CFS-Release L01-C
• CFS-Release L04-C
D CFS-Release L06-C
• CFS-Release L07-C
• CFS-Release L10-C
• CFS-Release Lll-C
• CFS-Release Ref-C
D CFS-Release Ref-F
100
M1315CFS Overall CV
M1315 CFS Between Lab CV
M1315 CFS Within Lab CV
100
(E)
0.01 0.1 1
Time (days)
10
100
Figure 53. Aluminum cumulative release from Method 1315 for material CFS. (A) calculated data as a
function of leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to
the median of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals
(red lines) shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue,
dashed line) and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E)
coefficient of variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to
5% marker indicating a generalized analytical uncertainty.
F-53
-------
Interlaboratory Validation of LEAF Method 1314 and Method 1315
100 -F
•««.
E
O
•a
10 -•
1 -;
(A)
0.1
0.01
100
4-
E
o
B
10 -•
0.1
4-
(C)
100
01
o
•a
10 -•
1 -;
0.1
M1315 CFS-Release Mean
- Overall SD
-Between LabSD
-Within LabSD
4-
4-
(D)
4-
0.1 1 10
Time (days)
4-
0.01 0.1 1 10
Time (days)
4-
0.01 0.1 1 10
Time (days)
100
f™">
(N
1 10"
Ł
Antimony
h-i
0.1 -
0.
)
^^
^^^
"35 — — CFS-Release Ref 95% PL
O CFS-Release Ref Mean
^
Q
.n"
• CFS-Release Median of Lab Means
Dl 0.1 1 10
Time (days)
100
• CFS-Release LOl-A A CFS-Re ease L01-B • CFS-Release L01-C
• CFS-Release L04-A A CFS-Re ease L04-B • CFS-Release L04-C
• CFS-Release L06-A A CFS-Re ease L06-B D CFS-Release L06-C
0 CFS-Release L07-A A CFS-Re ease L07-B D CFS-Release L07-C
0 CFS-Release L10-A A CFS-Re ease L10-B D CFS-Release L10-C
• CFS-Release Lll-A A CFS-Re ease Lll-B • CFS-Release Lll-C
• CFS-Release Ref-A A CFS-Re ease Ref-B • CFS-Release Ref-C
• CFS-Release Ref-D A CFS-Re ease Ref-E D CFS-Release Ref-F
95% RCL
100
Antimony Release CV (%)
E
O C
^
: ICP-OES RSD
— — — ^___^
"•••"^^
^
rr^^
"""• -
M1315 CFS Overall CV
M1315 CFS Between Lab CV
M1315 CFS Within Lab CV
* ^ — -*~
100
(E)
0.01 0.1 1
Time (days)
10
100
Figure 54. Antimony cumulative release from Method 1315 for material CFS. (A) calculated data as a function
of leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-54
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
100 T
fP
«•«.
01
o
E
3
1
10 -:
1 -•
0.1
(A)
(D)
4-
4-
4-
100
fp
«•«.
01
E
3
10 -
i -
o.i
CFS-Release Ref 95% PI
O CFS-Release Ref Mean
• CFS-Release Median of Lab Means
CFS-Release 95% RCL
4-
4-
4-
o.oi o.i i 10
Time (days)
100
(B)
0.01 0.1 1
Time (days)
10
100
Dl
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3
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0 1 •
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0.01 0.1
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(0 v y '
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— — Between Lab SD
• CFS-Release L01-A A CFS-Release L01-B • CFS-Release L01-C
• CFS-Release L04-A A CFS-Release L04-B • CFS-Release L04-C
• CFS-Release L06-A A CFS-Release L06-B D CFS-Release L06-C
0 CFS-Release L07-A A CFS-Release L07-B D CFS-Release L07-C
0 CFS-Release L10-A A CFS-Release L10-B D CFS-Release L10-C
• CFS-Release Lll-A A CFS-Release Lll-B • CFS-Release Lll-C
• CFS-Release Ref-A A CFS-Release Ref-B • CFS-Release Ref-C
• CFS-Release Ref-D A CFS-Release Ref-E D CFS-Release Ref-F
95% RCL
100
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M1315 CFS Overall CV
M1315 CFS Between Lab CV
M1315 CFS Within Lab CV
0.01 0.1 1
Time (days)
10 100 0.01 0.1 1
Time (days)
10
100
Figure 55. Barium cumulative release from Method 1315 for material CFS. (A) calculated data as a function of
leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of
lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-55
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
1000
100 •
Ł
01
E
o
CO
10 -fe
0.1
4-
4-
(A)
1000
(C)
0.1
1000
Time (days)
100 •
01
I 10
s
o
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M1315CFS-ReleaseMean
Overall SD
Between Lab SD
Within Lab SD
ff'^f
0.01
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(D)
Time (days)
4-
0.01 0.1 1 10
Time (days)
10
100
100
(E)
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• CFS-Release L01-A
• CFS-Release L04-A
O CFS-Release L06-A
0 CFS-Release L07-A
0 CFS-Release L10-A
• CFS-Release Lll-A
• CFS-Release Ref-A
• CFS-Release Ref-D
95% RCL
lease CV (%)
5
O O
(±
1
1 -
0.0
^f^
^*/
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-^L>_
CFS-Release Ref 95% PL
*^ O CFS-Release Ref Mean
• CFS-Release Median of Lab Means
1 10 100
Time (days)
A CFS-Re ease L01-B • CFS-Release L01-C
A CFS-Re ease L04-B • CFS-Release L04-C
A CFS-Re ease L06-B D CFS-Release L06-C
A CFS-Re ease L07-B D CFS-Release L07-C
A CFS-Re ease L10-B D CFS-Release L10-C
A CFS-Re ease Lll-B • CFS-Release Lll-C
A CFS-Re ease Ref-B • CFS-Release Ref-C
A CFS-Re ease Ref-E D CFS-Release Ref-F
__:-^^
r"^\.
ICP-OES RSD
M1315 CFS
M1315CFS
1 0.1
^«, —
**
»>^
*"-^
**^~
Overall CV
Between Lab CV
Within Lab CV
1 10 1C
)0
Time (days)
Figure 56. Boron cumulative release from Method 1315 for material CFS. (A) calculated data as a function of
leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of
lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-56
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
1000
01
o
E
3
•c
5
100 •
10 -
(A)
1000
(C)
1000
01
o
E
3
•c
5
100 •
10 -
4-
4-
M1315CFS-ReleaseMean
Overall SD
-Between LabSD
-Within Lab SD
0.01
0.1
(D)
Time (days)
4-
0.01 0.1 1 10
Time (days)
0.1 1 10
Time (days)
10
1000
01
o
E
3
•c
5
100 ••
10 -;
-CFS-Release Ref 95% PL
• CFS-Release Ref Mean
• CFS-Release Median of Lab Means
CFS-Release 95% RCL
100
(B)
I— I—•-"
0.01 0.1 1
Time (days)
10
100
• CFS-Release LOl-A
• CFS-Release L04-A
• CFS-Release L06-A
O CFS-Release L07-A
O CFS-Release L10-A
• CFS-Release Lll-A
• CFS-Release Ref-A
O CFS-Release Ref-D
95% RCL
A CFS-
A CFS-
A CFS-
A CFS-
A CFS-
A CFS-
A CFS-
A CFS-
Release L01-B
Release L04-B
Release L06-B
Release L07-B
Release L10-B
Release Lll-B
Release Ref-B
Release Ref-E
• CFS-Release L01-C
• CFS-Release L04-C
• CFS-Release L06-C
• CFS-Release L07-C
• CFS-Release L10-C
• CFS-Release Lll-C
• CFS-Release Ref-C
D CFS-Release Ref-F
100
100
u
01
in
E
3
E
•c
IS
u
ICP-OES RSD
M1315CFS Overall CV
M1315 CFS Between Lab CV
M1315 CFS Within Lab CV
4-
4-
100
0.01
0.1
10
100
(E)
Time (days)
Figure 57. Cadmium cumulative release from Method 1315 for material CFS. (A) calculated data as a function
of leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-57
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
100000
^ 10000 -•
01
E
3
5 1000 -;
IS
u
100
0.01
(A)
100000
10000 -:
01
O
E
3
.0 1000 -:
0.01
(C)
100000
^ 10000 -•
I
Ą
5 1000 -;
5
100
4-
4-
4-
0.1 1 10
Time (days)
0.1 1 10
Time (days)
<->•
100000
^ 10000 -•
01
O
E
3
5 1000 -;
IS
u
CFS-Release Ref 95% PL
O CFS-Release Ref Mean
• CFS-Release Median of Lab Means
CFS-Release 95% RCL
100
(B)
100 -I I
0.01 0.1 1 10
Time (days)
••r
100
• CFS-Release L01-A
• CFS-Release L04-A
• CFS-Release L06-A
• CFS-Release L07-A
• CFS-Release L10-A
• CFS-Release Lll-A
• CFS-Release Ref-A
O CFS-Release Ref-D
95% RCL
A CFS-
A CFS-
A CFS-
A CFS-
A CFS-
A CFS-
A CFS-
A CFS-
Release L01-B
Release L04-B
Release L06-B
Release L07-B
Release L10-B
Release Lll-B
Release Ref-B
Release Ref-E
• CFS-Release L01-C
• CFS-Release L04-C
D CFS-Release L06-C
• CFS-Release L07-C
• CFS-Release L10-C
• CFS-Release Lll-C
• CFS-Release Ref-C
D CFS-Release Ref-F
M1315 CFS-Release Mean
Overall SD
-- Between Lab SD
100
u
Si
IS
.2 10
E
3
|o
5
M1315CFS Overall CV
M1315 CFS Between Lab CV
M1315 CFS Within Lab CV
(D)
0.01 0.1 1
Time (days)
10
100
0.01
0.1
10
100
(E)
Time (days)
Figure 58. Calcium cumulative release from Method 1315 for material CFS. (A) calculated data as a function
of leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-58
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
10000
o
•o
1000 -;
100 -r
10 -•
(A)
10000
1000 -•
o
•o
(C)
10000
1000 -;
.
01
o
•o
IS
01
100 -•
10 T
M1315 CFS-Release Mean
- Overall SD
-Between LabSD
-Within Lab SD
4-
4-
(D)
0.01 0.1 1 10
Time (days)
0.01 0.1 1 10
Time (days)
0.01 0.1 1 10
Time (days)
10000
100
0.01
10
100
(B)
Time (days)
• CFS-Release LOl-A
• CFS-Release L04-A
O CFS-Release L06-A
• CFS-Release L07-A
• CFS-Release L10-A
• CFS-Release Lll-A
• CFS-Release Ref-A
O CFS-Release Ref-D
95% RCL
A CFS-Release L01-B
A CFS-Release L04-B
A CFS-Release L06-B
A CFS-Release L07-B
A CFS-Release L10-B
A CFS-Release Lll-B
A CFS-Release Ref-B
A CFS-Release Ref-E
• CFS-Release L01-C
• CFS-Release L04-C
D CFS-Release L06-C
• CFS-Release L07-C
• CFS-Release L10-C
• CFS-Release Lll-C
• CFS-Release Ref-C
D CFS-Release Ref-F
100
3
0.01
0.1
(E)
Time (days)
Figure 59. Lead cumulative release from Method 1315 for material CFS. (A) calculated data as a function of
leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median of
lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-59
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
f?
E
Potassium (mg
i-
1-* C
' O C
• if
t 1 9
' 1 1 j 0
6*
: DQ
Potassium (mg/m2)
i-
0.01 0.1 1 10 100
Time (days)
(A) (B)
f?
E
Potassium (mg
i-
!-•• C
-^ O C
• ^^
0.01 0.1 1 10 1C
Time (days)
(0 v y J
Potassium (mg/m2)
h-
!-•• C
I-' O C
* O O C
• M1315 CFS-Release Mean
- — Overall SD
Between Lab SD /»^
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*-'''*• ^
0
Potassium Release CV (%)
i-*
0.01 0.1 1 10 100
LOO
10
1
0
01 0.1
• CFS-Release LOl-A
• CFS-Release L04-A
O CFS-Release L06-A
0 CFS-Release L07-A
0 CFS-Release L10-A
• CFS-Release Lll-A
• CFS-Release Ref-A
• CFS-Release Ref-D
95% RCL
LO •
^-;
— CFS-
0 CFS-
• CFS-
\ ^^
y s
Release Ref 95% PL
Release Ref Mean
Release Med an of Lab Means
Release 95% RCL
1 10 100
Time (days)
A CFS-Re ease L01-B •
A CFS-Re ease L04-B •
A CFS-Re ease L06-B D
A CFS-Re ease L07-B D
A CFS-Re ease L10-B D
A CFS-Re ease Lll-B •
A CFS-Re ease Ref-B •
A CFS-Re ease Ref-E D
^ — ^^^
ICP-OES RSD
^-,
i\~J~
M1315 CF
M1315CF
0.01 0.1
5 Overall CV
5 Between Lab CV
5 Within Lab CV
1
CFS-Release L01-C
CFS-Release L04-C
CFS-Release L06-C
CFS-Release L07-C
CFS-Release L10-C
CFS-Release Lll-C
CFS-Release Ref-C
CFS-Release Ref-F
" V-
10 100
(D)
Time (days)
(E)
Time (days)
Figure 60. Potassium cumulative release from Method 1315 for material CFS. (A) calculated data as a function
of leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-60
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
100 T
Ul
o
E
3
10 -:
1 -•
0.1
0.01
(A)
100 T
Ul
o
E
3
(D)
•4-
4-
4-
1 -
0.1
-CFS-Release Ref 95% PL
O CFS-Release Ref Mean
• CFS-Release Median of Lab Means
CFS-Release 95% RCL
4-
4-
4-
o.i i 10
Time (days)
100
(B)
0.01 0.1 1
Time (days)
10
100
• CFS-Release L01-A
• CFS-Release L04-A
• CFS-Release L06-A
O CFS-Release L07-A
O CFS-Release L10-A
• CFS-Release Lll-A
• CFS-Release Ref-A
O CFS-Release Ref-D
95% RCL
A CFS-
A CFS-
A CFS-
A CFS-
A CFS-
A CFS-
A CFS-
A CFS-
Release L01-B
Release L04-B
Release L06-B
Release L07-B
Release L10-B
Release Lll-B
Release Ref-B
Release Ref-E
• CFS-Release L01-C
• CFS-Release L04-C
• CFS-Release L06-C
• CFS-Release L07-C
• CFS-Release L10-C
• CFS-Release Lll-C
• CFS-Release Ref-C
D CFS-Release Ref-F
1 -
n»
.-s.-SsO?^'
xX*
'&&*'*''
• M1315 CFS-Release Mean
— Overall SD
Between Lab SD
100 -r
u
9)
in
IB
0)
.2
ICP-OES RSD
M1315 CFS Overall CV
M1315 CFS Between Lab CV
M1315 CFS Within Lab CV
•4-
0.01 0.1 1
Time (days)
10
100
0.01
0.1
10
100
(E)
Time (days)
Figure 61. Selenium cumulative release from Method 1315 for material CFS. (A) calculated data as a function
of leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-61
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
10
E
3
'•5
a
I
1 -•
0.1 -;
0.01
4-
4-
01
o
E
3
'•5
a
I
1 ••
0.1 -;
0.01
-CFS-Release Ref 95% PL
O CFS-Release Ref Mean
• CFS-Release Median of Lab Means
CFS-Release 95% RCL
4-
4-
(A)
0.01 0.1 1 10
Time (days)
100
(B)
0.01 0.1 1
Time (days)
10
100
Ol
o
E
3
'•5
a
I
0.01
0.1 -:
• CFS-Release LOl-A
• CFS-Release L04-A
• CFS-Release L06-A
• CFS-Release L07-A
• CFS-Release L10-A
• CFS-Release Lll-A
• CFS-Release Ref-A
O CFS-Release Ref-D
95% RCL
A CFS-
A CFS-
A CFS-
A CFS-
A CFS-
A CFS-
A CFS-
A CFS-
Release L01-B
Release L04-B
Release L06-B
Release L07-B
Release L10-B
Release Lll-B
Release Ref-B
Release Ref-E
• CFS-Release L01-C
• CFS-Release L04-C
D CFS-Release L06-C
• CFS-Release L07-C
• CFS-Release L10-C
• CFS-Release Lll-C
• CFS-Release Ref-C
D CFS-Release Ref-F
0.01
(C)
1 10
Time (days)
100
f?
E
oi 1
Ą
13
1
0.01 -1
{
^
C
> M1315 CFS-I
— OverallSD
— Between Lab
X
Release Mean
SD
D
lease CV (o/o)
3 C
Vanadium Re
i-
c
1 H
— .
;
•JCP-OES RSD_ _
•-
M1315 CFS Overall CV
• M1315 CFS Between Lab CV
M1315 CFS Within Lab CV
| | 1
-:-^-
(D)
0.01 0.1 1 10
Time (days)
100
0.01
0.1
10
100
(E)
Time (days)
Figure 62. Vanadium cumulative release from Method 1315 for material CFS. (A) calculated data as a function
of leaching time; (B) reference lab mean and 95% prediction limits (PL; green, dashed line) compared to the median
of lab means and median-based 95% robust confidence limits (RCL; red line); (C) 95% RCL intervals (red lines)
shown with respect to interpolated lab data; (D) intervals for "overall" (gold line), "between lab" (blue, dashed line)
and pooled "within labs" (green, dotted line) standard deviation about the mean of all data; (E) coefficient of
variation for upper values of "overall", "between lab" and "within lab" standard deviation compared to 5% marker
indicating a generalized analytical uncertainty.
F-62
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
l.E+00
l.E-01
l.E-02
l.E-03
l.E-04
l.E-05
l.E-06
l.E-07
l.E-08
-M1315CFS Flux Overall SD
M1315 SWA Flux Mean
M1315 SWA Flux Overall SD
4-
4-
0.01 0.1 1 10
Time (days)
100
100
!5
s
a
u •
0 -
1 •
0.
X
: ICP-OES RSD
M131
x""-- -
/ \
5 CFS flux RSD-r
5 SWA Flux RSD-r
v A
vv
01 0.1 1 10 10
Time (days)
0.01
Time (days)
100000
10000
Dl
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E
c
E
0.1
0.01
ivn^ib Lhb Kelease iviean
-M1315 CFS Release Overall SD
M1315 SWA Release Mean
M1315 SWA Release Overall SD
4-
4-
4-
0.01 0.1 1 10
Time (days)
100
100
«0 10 -t
8
Q.
ICP-OES RSD
M1315 CFS Release RSD-r
M1315 SWA Release RSD-r
100
.Q
'§ 10
ICP-OES RSD
0.01
0.1
1
Time (days)
10
100
M1315 CFS Release RSD-R
• — M1315 SWA Release RSD-R
4-
0.01 0.1 1 10
Time (days)
100
Figure 63. Comparisons of statistical analyses for aluminum from Method 1315 validation study materials.
Mean interval flux (upper) and cumulative release (lower) comparisons showing overall standard deviation intervals about the mean compared to method detection limits and
method limits of quantitation (left), repeatability relative standard deviation (RSDr) (center) and reproducibility relative standard deviation (RSDR) (right). Grey dashed line in
repeatability and reproducibility panels indicate 20% and 50% reference lines.
F-63
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
l.E-02
u
8!
l.E-03 -
l.E-04
l.E-05
l.E-06
l.E-07
• M1315CFS Flux Mean
M1315 CFS Flux Oveall SD
• M1315 SWA Flux Mean
M1315 SWA Flux Overall SD
0.01
Lm)_
0.1
I
1
Time (days)
100 T
5
s
I
.Q
w
10
ICP-OES RSD
M1315 CFS Flux RSD-r
M1315 SWA Flux RSD-r
100
u
•o
E
a.
w
10 •:
10
100
0.01
0.1
1
Time (days)
10
100
• ICP-OES RSD
-M1315 CFS Flux RSR-R
M1315 SWA Flux RSR-R
0.01
0.1
1
Time (days)
10
100
1000
NE 100 -
•••.
01
> 10
o
S3
I !
0.1
M1315CFSRy|ydsyMndM
-M1315 CFS Release Overall SD
M1315 SWA Release Mean
M1315 SWA Release Overall SD
100 T
w
10 -:
ICP-OES RSD
M1315 CFS Release RSD-r
M1315 SWA Release RSD-r
100
.Q
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Q.
01
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10 -:
• ICP-OES RSD
M1315 CFS Release RSD-R
M1315 SWA Release RSD-R
0.01 0.1 1
Time (days)
10
100
0.01
0.1
1
Time (days)
10
100
0.01
0.1
1
Time (days)
10
100
Figure 64. Comparisons of statistical analyses for antimony from Method 1315 validation study materials.
Mean interval flux (upper) and cumulative release (lower) comparisons showing overall standard deviation intervals about the mean compared to method detection limits and
method limits of quantitation (left), repeatability relative standard deviation (RSDr) (center) and reproducibility relative standard deviation (RSDR) (right). Grey dashed line in
repeatability and reproducibility panels indicate 20% and 50% reference lines.
F-64
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
l.E-03
• M1315CFS Flux Mean
— M1315CFS Flux Overall SD
D M1315 SWA Flux Mean
M1315 SWA Flux Overall SD
l.E-08
0.01
0.1 1 10
Time (days)
Time (days)
Time (days)
1000
01
_
i
100 -•
10 -•
1 -•
0.1
0.01
• M1315 CF5 Release Mean
M1315 CFS Release Overall SD
D M1315 SWA Release Mean
M1315 SWA Release Overall SD
0.01
100
0.1
1
Time (days)
10
100
S 10
n
-M1315 CFS Release RSD-r
M1315 SWA Release RSD-r
1000
u
1
Q.
01
U.
&
0.01 0.1 1
Time (days)
10
100
n
0 -
ICP-OES RSD
— M1315SWAf
rrrr-^
0.01 0.1
*~ — — .
;lease RSD-R
(elease RSD-R
—
L 10 1C
Time (days)
Figure 65. Comparisons of statistical analyses for barium from Method 1315 validation study materials.
Mean interval flux (upper) and cumulative release (lower) comparisons showing overall standard deviation intervals about the mean compared to method detection limits and
method limits of quantitation (left), repeatability relative standard deviation (RSDr) (center) and reproducibility relative standard deviation (RSDR) (right). Grey dashed line in
repeatability and reproducibility panels indicate 20% and 50% reference lines.
F-65
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
8!
(N
"Si
^>
I
l.E-03
l.E-04
l.E-05
l.E-06
l.E-07
l.E-08
MDL
• M1315CFS Flux Mean
M1315 CFS Flux Overall SD
• M1315 SWA Flux Mean
M1315 SWA Flux Overall SD
"4-
4-
4-
0.01 0.1 1 10
Time (days)
100
0.01
Time (days)
Time (days)
• M1315 CFS Release Mean
— M1315 CFS Release Overall SD
D M1315 SWA Release Mean
M1315 SWA Release Overall SD
0.01
0.01
1 10
Time (days)
100
.Q
s
8
Q.
10 -:
M1315 CFS Release RSD-r
M1315 SWA Release RSD-r
0.01 0.1 1
Time (days)
100
10
100
o
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E
Q.
10 -:
• ICP-OES RSD
M1315 CFS Release RSD-R
M1315 SWA Release RSD-R
0.01
0.1
1
Time (days)
10
100
Figure 66. Comparisons of statistical analyses for boron from Method 1315 validation study materials.
Mean interval flux (upper) and cumulative release (lower) comparisons showing overall standard deviation intervals about the mean compared to method detection limits and
method limits of quantitation (left), repeatability relative standard deviation (RSDr) (center) and reproducibility relative standard deviation (RSDR) (right). Grey dashed line in
repeatability and reproducibility panels indicate 20% and 50% reference lines.
F-66
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
l.E+00
l.E-01
l.E-02
l.E-03
l.E-04
l.E-05
l.E-06
l.E-07
0.01
ML
MDL
• M1315CFS Flux Mean
— M1315 CFS Flux Overall S\)
D M1315 SWA Flux Mean
M1315 SWA Flux Overal
0.1 1
Time (days)
100
100
0.01
Time (days)
3 10 -fc
I
Q.
• ICP-OES RSD
M1315 CFS Flux RSD-R
M1315 SWA Flux RSD-R
0.01
0.1
1
Time (days)
10
100
100000
^^
(N
E
^
Ol
E
"HMH*
E
3
'o
5
10000
1000
100
10
1
0.1
• M1315 CFS Release Mean
— M1315 CFS Release Overall SD
D M1315 SWA Release Mean
M1315 SWA Release Overall SD
100
0.01
Time (days)
JS 10
IB
-M1315 CFS Release RSD-r
M1315 SWA Release RSD-r
100
IB
U
-M1315 CFS Release RSD-R
M1315 SWA Release RSD-R
0.01
0.1
1
Time (days)
10
100
0.01
0.1
1
Time (days)
10
100
Figure 67. Comparisons of statistical analyses for calcium from Method 1315 validation study materials.
Mean interval flux (upper) and cumulative release (lower) comparisons showing overall standard deviation intervals about the mean compared to method detection limits and
method limits of quantitation (left), repeatability relative standard deviation (RSDr) (center) and reproducibility relative standard deviation (RSDR) (right). Grey dashed line in
repeatability and reproducibility panels indicate 20% and 50% reference lines.
F-67
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
i.c-t-uu •
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FS Flux Mean
FS Flux Overall SD
WA Flux Mean
WA Flux Overall SD
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Time (days) Time (days) Time (days)
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100000
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'I
s.
• M1315CFSRuludbuMudll
M1315 CFS Release Overall SD
D M1315 SWA Release Mean
M1315 SWA Release Overall SD
0.01
100 T
10 -:
s
Q.
-M1315 CFS Release RSD-r
M1315 SWA Release RSD-r
100
J3
o 10
• ICP-OES RSD
-M1315 CFS Release RSD-R
M1315 SWA Release RSD-R
4-
4-
Time (days)
0.01 0.1 1 10
Time (days)
100
0.01 0.1 1
Time (days)
10
100
Figure 68. Comparisons of statistical analyses for potassium from Method 1315 validation study materials.
Mean interval flux (upper) and cumulative release (lower) comparisons showing overall standard deviation intervals about the mean compared to method detection limits and
method limits of quantitation (left), repeatability relative standard deviation (RSDr) (center) and reproducibility relative standard deviation (RSDR) (right). Grey dashed line in
repeatability and reproducibility panels indicate 20% and 50% reference lines.
F-68
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
l.E-01
l.E-02
l.E-03
l.E-04
l.E-05 -
l.E-06
l.E-07
• M1315CFS Flux Mean
M1315 CFS Flux Overall SD
D M1315 SWA Flux Mean
M1315 SWA Flux Overall SD
I '
0.01
0.1
1
Time (days)
10
100 T
100
0.01
Time (days)
Time (days)
10000
E
•««.
I
|
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in
1000 -:
• M1315CFSRy|ydsyMndii
M1315 CFS Release Overall SD
D M1315 SWA Release Mean
M1315 SWA Release Overall SD
1
0.01 0.1 1 10
Time (days)
100
JS 10
s
Q.
01
%
M1315 CFS Release RSD-r
M1315 SWA Release RSD-r
100
0.01
0.1
1
Time (days)
10
100
10 -:
I
Q.
&
ICP-OES RSD
M1315 CFS Release RSD-R
M1315 SWA Release RSD-R
0.01 0.1 1
Time (days)
10
100
Figure 69. Comparisons of statistical analyses for selenium from Method 1315 validation study materials.
Mean interval flux (upper) and cumulative release (lower) comparisons showing overall standard deviation intervals about the mean compared to method detection limits and
method limits of quantitation (left), repeatability relative standard deviation (RSDr) (center) and reproducibility relative standard deviation (RSDR) (right). Grey dashed line in
repeatability and reproducibility panels indicate 20% and 50% reference lines.
F-69
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
u
8!
01
^>
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3
'o
IB
I
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l.E-05
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M1315 CFS Flux Overall SD
D M1315 SWA Flux Mean
M1315 SWA Flux Overall SD
4-
100 T
0.01 0.1 1 10
Time (days)
100
100
5
o
•o
10 •:
0.01
• ICP-OES RSD
-M1315 CFS Flux RSD-R
M1315 SWA Flux RSD-R
0.01
0.1
Time (days)
1
Time (days)
10
100
100
• M1315 CFS Release Mean
M1315 CFS Release Overall SD
D M1315 SWA Release Mean
M1315 SWA Release Overall SD
100
2 10
I
M1315 CFS Release RSD-r
M1315 SWA Release RSD-r
ICP-OES RSD
100
Ł
'o
10 -:
ICP-OES RSD
M1315 CFS Release RSD-R
M1315 SWA Release RSD-R
0.01
0.1 1
Time (days)
0.01 0.1 1 10
Time (days)
100
0.01
0.1
1
Time (days)
—
10
100
Figure 70. Comparisons of statistical analyses for vanadium from Method 1315 validation study materials.
Mean interval flux (upper) and cumulative release (lower) comparisons showing overall standard deviation intervals about the mean compared to method detection limits and
method limits of quantitation (left), repeatability relative standard deviation (RSDr) (center) and reproducibility relative standard deviation (RSDR) (right). Qrey dashed line in
repeatability and reproducibility panels indicate 20% and 50% reference lines.
F-70
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
1000
-i " „ 1 „-=*-
Release at End of Test
(63-day cumulative time)
0.01
Time (days)
0.1 1 10
Time (days)
Figure 71. Illustration of scenarios used to summarize precision for Method 1315 mean interval flux (left)
and cumulative release (right).
Table 1. Method 1315 Precision Estimates for Interval Flux (4th Interval).
Analvte
Aluminum
Al
Repeatability
SWA • CFS
%RSDr • %RSDr
10.2
17.5
Reproducibility
SWA • CFS
%RSDR • %RSDR
36.9
24.9
Antimony
Sb
12.5
19.8
28.4
27.1
Arsenic
As
31.4
34.2
Barium
Ba
15.2
7.0
13.1
Boron
B
15.6
5.4
36.2
35.0
Cadmium
Cd
27.5
Calcium
Ca
10.8
6.9
25.3
28.5
Chromium
Cr
14.9
40.3
Lead
Pb
3.5
43.6
Potassium
K
16.7
12.6
45.4
26.2
Selenium
Vanadium
Se
V
14.4
11.0
11.5
11.0
Material Meanll
Overall Meanll
42.9
27.0
54.7
13% Repeatability II 34% Reproducibility I
F-71
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Table 2. Method 1315 Precision Estimates for Mean Flux (2nd, 3rd, & 4th Intervals).
•MM mam
Aluminum
Antimony
Arsenic
Barium
Boron
Cadmium
Calcium
Chromium
Lead
Potassium
Selenium
Vanadium
Al
Sb
As
Ba
B
Cd
Ca
Cr
Pb
K
Se
V
| Repeatability |
ISWA 1
%RSDr |
29.2
13.2
ICFS 1
%RSDr |
16.1
13.9
15.1
8.1
21.0
8.1
9.5
8.4
15.0
9.0
16.1
4.6
11.1
11.5
15.1
13.4
12.7
13.5
1 Material Mean|| 16% | 11% |
Overall Mean|| 13% Repeatability |
1 Reproducibility |
SWA • CFS 1
%RSDR | %RSDR |
40.4
34.8
28.2
19.9
26.9
29.1
42.3
17.7
32.0
21.8
19.7
33.0
28.5
20.8
22.4
24.1
29.4
51.8
25.8
23.3
| 30% | 28% |
j 29% Reproducibility j
Table 3. Method 1315 Precision Estimates for Mean Flux (2nd - 9th Intervals).
mmsm mm
Aluminum
Antimony
Arsenic
Barium
Boron
Cadmium
Calcium
Chromium
Lead
Potassium
Selenium
Vanadium
Al
Sb
As
Ba
B
Cd
Ca
Cr
Pb
K
Se
V
| Repeatability |
ISWA 1
%RSDr |
7.3
9.2
ICFS 1
%RSDr |
13.3
14.8
19.9
13.2
10.8
7.5
7.2
7.6
8.1
6.6
10.2
4.3
12.4
10.9
8.5
10.8
13.3
11.3
| Material Mean|| 11% | 10% J
| Reproducibility |
1 SWA • CFS 1
| %RSDR | %RSDR |
25.3
21.8
25.3
23.8
31.1
44.8
27.3
18.3
27.1
23.2
28.7
26.0
23.8
19.8
28.8
30.8
22.3
40.1
32.4
30.6
^Q^H
| Overall Mean|| 11% Repeatability || 28% Reproducibility |
F-72
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Table 4. Method 1315 Precision Estimates for 7-day Cumulative Release.
•MM mm
Aluminum
Antimony
Arsenic
Barium
Boron
Cadmium
Calcium
Chromium
Lead
Potassium
Selenium
Vanadium
Al
Sb
As
Ba
B
Cd
Ca
Cr
Pb
K
Se
V
| Repeatability |
1 SWA • CFS 1
| %RSDr | %RSDr |
7.3
8.3
10.2
7.4
20.2
16.4
12.4
6.0
6.5
5.8
6.4
6.1
13.1
2.9
13.2
9.4
7.9
8.4
6.9
7.8
| Material Mean|| 12% | 7% |
1 Reproducibility |
SWA • CFS 1
%RSDR | %RSDR |
20.5
14.6
12.9
12.8
21.1
36.1
18.0
14.6
16.5
16.0
20.8
15.4
14.0
9.6
22.3
17.1
17.1
30.7
19.9
19.5
H|2|
| Overall Mean|| 9% Repeatability || 19% Reproducibility j
Table 5. Method 1315 Precision Estimates for 63-day Cumulative Release.
•MTOM mm\
Aluminum Al
Antimony Sb
Arsenic As
Barium Ba
Boron B
Cadmium Cd
Calcium Ca
Chromium Cr
Lead Pb
Potassium K
Selenium Se
Vanadium V
| Repeatability |
ISWA •
%RSDr |
5.4
6.9
CFS 1
%RSDr |
5.3
5.9
15.9
7.5
8.4
3.9
3.7
4.8
4.6
3.2
7.7
1.6
10.8
8.7
5.7
6.3
3.6
4.2
| Reproducibility |
ISWA • CFS 1
%RSDR | %RSDR |
23.6
19.7
22.9
14.4
31.0
35.6
22.6
16.5
25.7
18.4
23.9
24.6
17.7
12.0
24.8
26.7
21.1
44.4
20.5
22.8
| Material Mean|| 8% | 4% || 25% | 22% |
| Overall Mean|| 6% Repeatability j 23% Reproducibility j
F-73
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Table 6. Method 1315 Precision Estimate Summary.
#1
#2
#3
#4
#5
II Scenario II B
Flux; 4th Interval
Flux; Mean 2nd - 4th Intervals
Flux; Mean 2nd - 9th Intervals
Cumulative Release; 7-day
Cumulative Release; 63-day
Repeatability II Reproducibili
13%
13%
11%
9%
6%
| Mean Method 1315 Precision||
10% |
ty|
34%
29%
28%
19%
23%
^^•SESi^^H
F-74
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Appendix G. Comparison of EU Method Data to LEAF Method Statistics
TABLE OF CONTENTS
CEN TS 14405 compared to Method 1314 Statistics
CFS Contaminated Field Soil G-l
JaFS Steel Foundry Sand G-4
CEN TS 15683 and NEN 7375 compared to Method 1315 Statistics
SWA Solidified Waste Analog G-7
G-i
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
0.01
L/S(L/kg)
CFS-L11-14405-A
A CFS-L11-14405-B
CFS-L11-14405-C
•M1314CFSMean
M1315CFS95%RL
Figure 1. Eluate pH evolution from column testing using CEN TS 14405 compared to the 95%
reproducibility limit (RL) about the mean of Method 1314 validation data for material CFS.
G-l
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
*•->
1
? n 1 •
Ł U.I
I
(0
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Lead Release (mg/kg)
I P 0
3 0 P I-* 0
.* l_i l_i l_i O O
1 1 1 1 1 1
Thallium Release (mg/kg)
0 C
0 P o C
0 0 P ,-, C
O O O P I-* 1-
|_L |_L |_L |_L |_L O O
P . . . . . . o H
. • CFS-L1
A CFS-L1
• CFS-L1
M1314
B
W
1-144m-A
1- 14405- B
1-14405-C
CFS Mean
CFS 95% RL
X
VIL s'
DL
,^
X
X
X ^^
X X^
1 0.1 1 10 100
L/S (L/kg)
^t
^
X
X1
ML x- '
-T-^1^^^
x- ^
X* X^
. • CFS-L11-14405-A
A CFS-L11-14405-B
• CFS-L11-14405-C
M1314 CFS 95% RL
01 0.1 1 10 100
L/S (L/kg)
0.1 -
0.01 -
0.001 -
0.0001
L) L|-i-Lll-144Ui-A
A CFS-L11-14405-B
• CFS-L11-14405-C
M1314 CFS Mean
M1314CFS95%RL
0.01
w
0.01
L/S (L/kg)
100 •
10 -
n 1
Om -
Onm -
nnni .
I
1
f
M
>
^x
DL ^^
x^
• CFS-L11-14405-A
A CFS-L11-14405-B
• CFS-L11-14405-C
M1314CFS95%I1
^^
0.1
10
100
L/S (L/kg)
Figure 3. Cumulative release from CEN TS 14405 compared to the 95% reproducibility limit (RL) about
the mean of Method 1314 validation data for material CFS.
G-3
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
1U
9.
Q.
ŁJ 8 -
re
UJ
7 -
ft -
•
•
•
.
•
•
.
.
_ _
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s
^
n
^
•
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• JaFS-
A JaFS-
L11-14405-A
L11-14405-B
D JaFS-Lll-14405-C
M1314 JaFS Mean
M1315 JaFS 95% RL
0 JaFS-Lll-14405-A
A JaFS-Lll-14405-B
D JaFS-Lll-14405-C
M1314 JaFS Mean
M1315JaFS95%RL
0.01
0.1 1
L/S(L/kg)
10
100
Figure 4. Eluate pH evolution from column testing using CEN TS 14405 compared to the 95%
reproducibility limit (RL) about the mean of Method 1314 validation data for material JaFS.
G-4
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
I
01
0.1 T
^ 0.01 -r
of
E
3
= 0.001 - r
E
3
0.0001
• JaFS-Lll-14405-A
A JaFS-Lll-14405-B
• JaFS-Lll-14405-C
M1314JaFSMean
0.01
O1
«•«.
O1
01
in
is
_0)
&
E
13
0.01 -
0.0001
0.001 -
0.01
10
100
L/S (L/kg)
L/S (L/kg)
01
«•«.
01
01
in
is
0)
i
o
CD
0.01
100 •
10
n m -
:
[
: IV
i *^~
ML ^'
^ ^^
DL ^^
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• JaFS-Lll-14405-A
A JaFS-Lll-14405-B
• JaFS-Lll-14405-C
M1314JaFS95%RL
^•^
^
S-^
f 10 -
^>
V 1
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(2
c n m -
|w
n n nm -
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IV
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• J;
A J:
D Je
IV
^^:
^"
D
FS-L11-14405-;
FS-L11-14405-I
FS-L11-14405-C
1314 JaFS Mea
1314 JaFS 95%
l
RL
0.1
10
100
L/S (L/kg)
0.01
0.1
10
100
L/S (L/kg)
10 i-
1 -F
01
^t
~u>
o
Si
IS
_0)
&
&
0.01 ••
0.001
0.0001
0.01
MDL
-"H '
0.1
• JaFS-Lll-14405-A
A JaFS-Lll-14405-B
• JaFS-Lll-14405-C
M1314 JaFS Mean
M1314JaFS95%RL
*"(—
10
^T
100
o.ooi
0.01
10
100
L/S (L/kg)
L/S (L/kg)
Figure 5. Cumulative release from CEN TS 14405 compared to the 95% reproducibility limit (RL) about
the mean of Method 1314 validation data for material JaFS.
G-5
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
01
01
01
in
is
E
3
'in
0)
I
I
01
o
Si
E
3
01
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1 -
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n m -
n nm -
[-, __
1 .
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&*
^^
D
• J
A J
D J
1\
aFS-Lll-14405-A
aFS-Lll-14405-B
3FS-L11-14405-C
/!1314JaFSMean
/!1314JaFSMean
.,-*'
^x^
0.
0.0001 -1
0.
31 0
',
IV
31 0
1 1 10 100
L/S (L/kg)
'^^
s /
/ / • JaFS-Lll-14405-A
ML ./ • JaFS-Lll-14405-C
M1314JaFS95%RL
1 1 10 100
L/S (L/kg)
I
"Si
o
01
in
is
0)
I
01
I
IS
01
IS
0.1 -
0.01 -
0.001 -
0.0001
0.01
I
01
u
R
10
0.1
0.001
0.0001
0.01
• JaFS-Lll-14405-A
A JaFS-Lll-14405-C
• JaFS-Lll-14405-C
M1314JaFSMear
M1314JaFS95%
100
L/S (L/kg)
* JaFS-Lll-14405-A
A JaFS-Lll-14405-B
• JaFS-Lll-14405-C
M1314JaFSMear
M1314JaFS95%
4-
10
100
L/S (L/kg)
Figure 6. Cumulative release from CEN TS 14405 compared to the 95% reproducibility limit (RL) about
the mean of Method 1314 validation data for material JaFS.
G-6
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
re
0.01
0.1 1 10
Time (days)
• SWA-L11-15863-A
A SWA-L11-15863-B
• SWA-L11-15863-C
O SWA-L11-7375-A
A SWA-L11-7375-B
D SWA-L11-7375-C
M1315 SWA Mean
M1315 SWA 95% RL
Figure 7. Eluate pH evolution from tank testing using CEN TS 15683 and NEN 7375 compared to the 95%
reproducibility limit (RL) about the mean of Method 1315 validation data for material SWA.
G-7
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
0.01
0.01 0.1 1 10
Time (days)
1000
Ol
w
of
c
0.1 -•
0.01
0.01
0.1 1 10
Time (days)
1000
Time (days)
• SWA-L11-15863-A
A SWA-L11-15863-B
• SWA-L11-15863-C
O SWA-L11-7375-A
A SWA-L11-7375-B
D SWA-L11-7375-C
M1315 SWA Mean
M1315 SWA 95% RL
0.1 1 10
Time (days)
Figure 8. Cumulative release from CEN TS 15683 and NEN 7375 compared to the 95% reproducibility
limit (RL) about the mean of Method 1315 validation data for material SWA.
G-8
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
o.oi
100000
Is
Ol
E
^
Si
I
a
E
_3
'in
in
s
o
Q.
10000
1000
100
10
1
o.i
0.01
m
o
01
in
E
3
I
0.01
0.01
0.1 1 10
Time (days)
0.1 1 10
Time (days)
0.1 1 10
Time (days)
01
^>
0)
in
&
I
u
0.1 -r
0.01
0.01
10000
1000 -
01
in
.« 100 -
E
_3
01
«
V)
0.01
0.1 1 10
Time (days)
0.1 1 10
Time (days)
• SWA-L11-15863-A
A SWA-L11-15863-B
• SWA-L11-15863-C
O SWA-L11-7375-A
A SWA-L11-7375-B
D SWA-L11-7375-C
M1315 SWA Mean
M1315SWA95%RL
Figure 9. Cumulative release from CEN TS 15683 and NEN 7375 compared to the 95% reproducibility
limit (RL) about the mean of Method 1315 validation data for material SWA.
G-9
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Appendix H. QA/QC Reports for Analytical Samples
TABLE OF CONTENTS
Method 1314: Liquid-Solid Partitioning as a Function of Liquid-Solid Ratio using an Up-Flow
Percolation Column Procedure
CFS - Contaminated Field Soil H-l
JaFS - Brass Foundry Sand H-4
Method 1315: Mass Transport Rates in Monolithic or Compacted Granular Materials using a
Semi-Dynamic Tank Leaching Procedure
SWA-Solidified Waste Analog H-7
CFS - Contaminated Field Soil H-ll
H-i
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
CFS Contaminated Field Soil
Method 1314
Overall Mean RSD 1.8%
Stdev of Mean RSDs 1.4%
Overall Mean Completeness 99.2%
Min Spike Recovery 83%
Max Spike Recovery 113%
Aluminum
Al
Lab#
L01
L06
L07
L10
L11
L14
Ref
Mean
Mean
RSD
4.0%
3.7%
4.3%
4.8%
4.1%
4.1%
4.4%
4.2%
Stdev
RSD Complete
2.2% 100.0%
1 .8%
2.3%
2.6%
2.3%
1 .8%
2.1%
100.0%
100.0%
100.0%
96.3%
100.0%
100.0%
99.5%
Spike Spike
Rec Min Rec Max
99.0% 112.0%
99.7%
96.2%
99.0%
93.8%
96.7%
96.1%
94%
101.8%
103.2%
105.3%
100.6%
105.1%
106.7%
112% Min-Max
Boron
B
Lab#
L01
L06
L07
L10
L11
L14
Ref
Mean
RSD
1 .2%
1 .2%
1 .3%
1 .6%
1 .3%
1 .7%
1 .7%
1 .5%
Stdev
RSD Complete
1.1% 100.0%
1.1%
1 .0%
1 .2%
0.8%
1 .4%
1 .9%
100.0%
100.0%
100.0%
100.0%
100.0%
98.1%
99.5%
Spike Spike
Rec Min Rec Max
93.3% 97.3%
91 .0%
90.0%
86.5%
90.8%
87.2%
82.9%
83%
94.0%
96.9%
88.4%
90.8%
89.0%
90.8%
97% Min-Max
Barium
Ba
Lab#
L01
L06
L07
L10
L11
L14
Ref
Mean
Mean
RSD
0.8%
1 .2%
1 .0%
0.9%
1.1%
1 .2%
0.9%
1 .0%
Stdev
RSD Complete
0.9% 100.0%
1 .2%
0.8%
0.7%
0.5%
0.8%
1 .2%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
Spike Spike
Rec Min Rec Max
95.4% 101.8%
92.6%
95.9%
93.9%
99.5%
105.4%
100.1%
93%
98.3%
98.9%
96.9%
99.7%
108.2%
108.2%
108% Min-Max
H-l
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
CFS Contaminated Field Soil
Method 1314
Calcium
Ca
Lab#
L01
L06
L07
L10
L11
L14
Ref
Mean
Copper
Cu
L01
L06
L07
L10
L11
L14
Ref
Mean
Lead
Pb
Lab#
L01
L06
L07
L10
L11
L14
Ref
Mean
Mean
RSD
0.8%
0.9%
0.9%
0.7%
0.8%
1 .2%
0.9%
0.9%
Mean
RSD
0.6%
0.9%
0.8%
0.6%
0.6%
1.1%
0.9%
0.8%
Mean
RSD
1 .0%
1.1%
1 .2%
0.6%
1 .0%
1 .4%
1 .5%
1 .2%
Mean
RSD
0.9%
1 .0%
0.9%
1 .0%
1 .5%
1 .3%
1 .5%
1 .2%
Stdev
RSD
0.9%
0.8%
0.9%
0.4%
0.5%
0.8%
1 .3%
Stdev
RSD
0.9%
0.7%
0.8%
0.3%
0.3%
0.9%
1 .3%
Stdev
RSD
0.7%
0.6%
1 .2%
0.2%
0.9%
0.7%
1 .9%
Stdev
RSD
0.9%
0.7%
0.9%
0.5%
1 .5%
0.8%
2.6%
Complete
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
Complete
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
Complete
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
98.1%
99.5%
Complete
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
98.1%
99.5%
Spike
Rec Min
91.6%
94.9%
93.1%
93.7%
94.9%
96.8%
93.6%
92%
Spike
Rec Min
86.7%
86.2%
89.8%
83.5%
86.5%
88.5%
83.6%
84%
Spike
Rec Min
98.0%
95.3%
97.0%
95.6%
98.5%
95.9%
97.1%
95%
Spike
Rec Min
93.7%
93.8%
100.7%
90.9%
107.5%
92.0%
91.9%
91%
Spike
Rec Max
102.7%
96.7%
105.0%
99.3%
100.4%
102.7%
101.0%
105%
Spike
Rec Max
89.0%
88.4%
92.3%
90.6%
87.5%
91 .4%
95.3%
95%
Spike
Rec Max
104.0%
105.2%
107.3%
103.5%
106.0%
103.7%
109.5%
109%
Spike
Rec Max
100.2%
106.5%
102.7%
99.7%
113.3%
98.5%
97.1%
1 1 3%
Min-Max
Min-Max
Min-Max
Min-Max
H-2
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
CFS Contaminated Field Soil
Method 1314
Molybdenum
Mo
Lab#
L01
L06
L07
L10
L11
L14
Ref
Mean
Mean
RSD
5.1%
4.5%
4.6%
4.7%
4.4%
4.7%
4.1%
4.5%
Stdev
RSD Complete
3.6% 92.6%
3.6%
2.7%
3.1%
2.5%
2.9%
3.2%
92.6%
96.3%
96.3%
96.3%
96.3%
94.4%
94.9%
Spike Spike
Rec Min Rec Max
102.4% 103.8%
100.0%
99.4%
100.4%
100.0%
104.0%
99.0%
99%
103.2%
109.1%
107.1%
100.8%
108.9%
107.2%
109% Min-Max
Thallium
Tl
Lab#
L01
L06
L07
L10
L11
L14
Ref
Mean
Mean
RSD
1 .2%
1 .8%
1 .7%
2.5%
2.3%
2.0%
1 .7%
1 .8%
Stdev
RSD
1 .3%
1 .5%
0.9%
2.1%
1 .4%
1 .6%
1 .2%
Complete
100.0%
100.0%
100.0%
96.3%
100.0%
100.0%
100.0%
99.5%
Spike
Rec Min
96.6%
100.1%
95.5%
100.4%
97.5%
105.1%
100.2%
95%
Spike
Rec Max
100.1%
107.0%
106.8%
101.7%
105.1%
109.3%
108.2%
109% Min-Max
Zinc
Zn
Lab#
L01
L06
L07
L10
L11
L14
Ref
Mean
Mean
RSD
1 .0%
1 .2%
1 .7%
0.7%
0.9%
1 .4%
1 .7%
1 .3%
Stdev
RSD Complete
0.8% 100.0%
0.7%
2.6%
0.5%
0.4%
0.9%
2.9%
100.0%
96.3%
100.0%
100.0%
100.0%
98.1%
99.1%
Spike Spike
Rec Min Rec Max
92.9% 97.2%
86.3%
90.9%
91.5%
90.2%
86.8%
86.7%
86%
92.5%
94.1%
94.6%
100.5%
88.6%
94.0%
100% Min-Max
H-3
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
JaFS Foundry Sand
Method 1314
Overall Mean RSD 2.2%
Stdev of Mean RSDs 1.3%
Overall Mean Completeness 98.7%
Min Spike Recovery 85%
Max Spike Recovery 111 %
Aluminum
Al
Lab#
L01
L06
L07
L10
L11
L14
Ref
Mean
Mean
RSD
5.1%
4.8%
2.4%
3.6%
4.2%
2.3%
3.5%
3.7%
Stdev
RSD Complete
2.8% 92.6%
2.8%
1 .4%
1 .9%
2.8%
1 .5%
3.0%
96.3%
100.0%
100.0%
92.6%
96.3%
94.4%
95.8%
Spike Spike
Rec Min Rec Max
91 .5% 99.7%
100.5%
99.7%
101.2%
95.2%
102.2%
88.6%
89%
109.1%
102.8%
107.5%
95.4%
106.6%
95.4%
109% Min-Max
Boron
B
Lab#
L01
L06
L07
L10
L11
L14
Ref
Mean
RSD
1 .4%
1 .6%
1 .5%
1 .7%
1 .0%
1 .5%
1 .7%
1 .5%
Stdev
RSD Complete
0.7% 100.0%
0.7%
0.9%
1 .3%
0.7%
1 .0%
1 .2%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
Spike Spike
Rec Min Rec Max
89.4% 90.8%
86.5%
87.1%
89.3%
87.3%
87.0%
87.5%
86%
89.0%
90.1%
91 .5%
92.5%
93.6%
94.9%
95% Min-Max
Barium
Ba
Lab#
L01
L06
L07
L10
L11
L14
Ref
Mean
Mean
RSD
1 .0%
1 .6%
1 .5%
1 .8%
1 .3%
1 .7%
1 .6%
1 .5%
Stdev
RSD Complete
0.5% 100.0%
1 .2%
0.8%
1 .0%
1.1%
1 .3%
0.9%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
Spike Spike
Rec Min Rec Max
88.2% 94.3%
93.8%
97.4%
97.5%
91 .4%
96.7%
90.7%
88%
94.8%
103.0%
105.2%
99.5%
101.2%
97.4%
105% Min-Max
H-4
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
JaFS Foundry Sand
Method 1314
Copper
Cu
Lab#
L01
L06
L07
L10
L11
L14
Ref
Mean
Lead
Pb
L01
L06
L07
L10
L11
L14
Ref
Mean
Magnesium
Mg
Lab#
L01
L06
L07
L10
L11
L14
Ref
Mean
Mean
RSD
0.9%
1.1%
1.1%
1 .6%
0.6%
1 .4%
1 .5%
1 .2%
Mean
RSD
1 .0%
1 .8%
1 .6%
1 .7%
1 .2%
1 .7%
1 .9%
1 .6%
Mean
RSD
3.6%
3.3%
5.0%
5.0%
4.2%
4.2%
4.3%
4.2%
Mean
RSD
1 .2%
1 .2%
1 .2%
1 .7%
0.9%
1 .6%
1 .5%
1 .4%
Stdev
RSD
0.5%
0.8%
0.9%
1 .0%
0.3%
1 .2%
1.1%
Stdev
RSD
0.6%
1 .6%
1.1%
1.1%
0.8%
1 .8%
1 .2%
Stdev
RSD
2.5%
1 .7%
2.5%
2.9%
2.3%
2.9%
2.5%
Stdev
RSD
0.6%
0.8%
1 .0%
1 .4%
0.4%
1 .0%
0.9%
Complete
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
Complete
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
Complete
96.3%
100.0%
96.3%
88.9%
96.3%
96.3%
98.1%
96.3%
Complete
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
Spike
Rec Min
85.5%
85.6%
88.7%
87.9%
86.4%
88.7%
89.7%
86%
Spike
Rec Min
88.2%
104.2%
100.0%
101.4%
93.7%
96.2%
90.1%
88%
Spike
Rec Min
86.7%
88.4%
91 .0%
89.0%
89.5%
107.2%
88.9%
87%
Spike
Rec Min
86.8%
96.2%
90.0%
93.5%
91 .6%
99.8%
90.9%
87%
Spike
Rec Max
91.7%
89.3%
93.2%
91.4%
91.7%
94.8%
95.3%
95%
Spike
Rec Max
96.1%
108.7%
105.5%
105.5%
101.0%
106.0%
102.5%
109%
Spike
Rec Max
89.6%
91.6%
93.1%
98.1%
94.7%
1 1 1 .0%
101.0%
111%
Spike
Rec Max
91.9%
98.5%
95.7%
100.8%
96.9%
103.1%
96.8%
103%
Min-Max
Min-Max
Min-Max
Min-Max
H-5
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
JaFS Foundry Sand
Method 1314
Manganese
Mn "
Lab#
L01
L06
L07
L10
L11
L14
Ref
Mean
Mean
RSD
1 .3%
1 .6%
1 .2%
1 .5%
1 .5%
1 .7%
1 .7%
1 .5%
Stdev
RSD Complete
0.7% 100.0%
0.7% 100.0%
0.8% 100.0%
1.0% 100.0%
1.1% 100.0%
1.3% 100.0%
1.3% 100.0%
100.0%
Spike
Rec Min
91 .8%
89.5%
96.0%
93.2%
98.3%
100.7%
94.5%
90%
Spike
Rec Max
98.3%
90.7%
102.3%
96.1%
100.7%
103.9%
96.7%
104% Min-Max
Molybdenum
Mo
Lab#
L01
L06
L07
L10
L11
L14
Ref
Mean
Mean
RSD
3.4%
4.3%
4.9%
4.7%
4.6%
4.4%
3.5%
4.2%
Stdev
RSD Complete
2.3% 100.0%
3.5% 95.7%
3.1% 95.2%
3.3% 90.9%
3.2% 92.6%
3.2% 95.0%
2.8% 94.0%
94.7%
Spike
Rec Min
84.9%
84.9%
89.0%
91 .0%
94.3%
102.5%
92.2%
85%
Spike
Rec Max
93.2%
91.9%
94.0%
93.6%
99.9%
105.4%
97.7%
105% Min-Max
Zinc
Zn
Lab#
L01
L06
L07
L10
L11
L14
Ref
Mean
Mean
RSD
1 .0%
1 .3%
1 .4%
1 .6%
1 .5%
1 .5%
1 .7%
1 .5%
Stdev
RSD Complete
0.5% 100.0%
0.6%
0.6%
1.1%
1 .5%
1 .3%
0.9%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
Spike Spike
Rec Min Rec Max
92.9% 93.4%
90.0%
94.5%
90.7%
98.9%
90.9%
86.9%
87%
95.7%
103.3%
97.8%
101.2%
98.4%
96.1%
103% Min-Max
H-6
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
SWA Solidified Waste Analog
Method 1315
Overall Mean RSD 2.1%
Stdev of Mean RSDs 1.3%
Overall Mean Completeness 99.2%
Min Spike Recovery 82%
Max Spike Recovery 115%
Aluminum
Al
Lab#
L01
L04
LOS
L06
L07
L09
L10
L11
Ref
Mean
Mean
RSD
0.6%
1 .0%
1 .2%
1 .2%
0.7%
1 .4%
0.9%
1 .5%
0.6%
1 .0%
Stdev
RSD Complete
0.4% 100.0%
0.5%
0.5%
0.7%
0.4%
0.7%
1 .0%
1 .4%
0.4%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
Spike Spike
Rec Min Rec Max
93.5% 94.9%
87.5%
89.7%
87.2%
89.8%
91.2%
86.6%
98.3%
92.3%
87%
95.7%
93.4%
93.3%
100.6%
101.6%
93.0%
105.0%
104.0%
105% Min-Max
Antimony
Sb
Lab#
L01
L04
L05
L06
L07
L09
L10
L11
Ref
Mean
RSD
2.4%
2.7%
2.3%
2.8%
2.3%
2.8%
2.7%
2.5%
3.2%
2.7%
Stdev
RSD Complete
1.9% 100.0%
1 .8%
1.1%
1 .9%
1 .0%
1 .4%
1 .4%
1 .4%
2.7%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
94.4%
98.9%
Spike Spike
Rec Min Rec Max
113.1% 114.9%
90.7%
89.1%
97.0%
107.9%
107.4%
84.6%
98.2%
91.1%
85%
96.3%
107.1%
101.4%
109.5%
112.4%
87.5%
98.2%
103.7%
115% Min-Max
H-7
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
SWA Solidified Waste Analog
Method 1315
Arsenic
As
Lab#
L01
L04
LOS
L06
L07
L09
L10
L11
Ref
Mean
Mean
RSD
4.7%
3.4%
5.0%
4.5%
5.1%
3.9%
4.4%
3.7%
3.9%
4.3%
Stdev
RSD Complete
2.7% 92.6%
2.1%
2.9%
2.8%
2.2%
2.5%
2.6%
2.6%
2.5%
100.0%
92.6%
92.6%
96.3%
100.0%
96.3%
96.3%
98.1%
96.3%
Spike Spike
Rec Min Rec Max
94.8% 110.0%
91.1%
87.0%
107.2%
95.4%
106.1%
84.7%
104.7%
88.8%
85%
100.1%
94.8%
109.8%
106.4%
108.6%
89.0%
1 1 1 .3%
103.3%
111% Min-Max
Boron
B
Lab#
L01
L04
L05
L06
L07
L09
L10
L11
Ref
Mean
Mean
RSD
2.3%
2.4%
2.6%
2.4%
2.6%
3.1%
3.1%
2.8%
2.9%
2.7%
Stdev
RSD Complete
1.3% 100.0%
1 .7%
1 .3%
1.1%
1 .2%
2.0%
1 .9%
2.6%
2.1%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
96.3%
98.1%
99.3%
Spike Spike
Rec Min Rec Max
92.8% 102.0%
93.4%
91.9%
99.5%
92.1%
91.0%
84.6%
100.9%
92.1%
85%
94.8%
96.3%
100.2%
102.5%
104.3%
91 .9%
104.8%
101.0%
105% Min-Max
Barium
Ba
Lab#
L01
L04
L05
L06
L07
L09
L10
L11
Ref
Mean
Mean
RSD
0.8%
1 .3%
1 .3%
1 .2%
0.6%
1 .5%
0.9%
1 .5%
0.9%
1.1%
Stdev
RSD Complete
0.5% 100.0%
1 .4%
0.5%
0.7%
0.4%
0.7%
0.9%
1 .2%
1 .0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
Spike Spike
Rec Min Rec Max
83.7% 90.1%
89.1%
82.5%
101.6%
86.6%
88.2%
87.2%
94.9%
95.5%
83%
91 .5%
87.4%
104.1%
97.0%
94.9%
102.2%
110.5%
107.3%
110% Min-Max
H-8
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
SWA Solidified Waste Analog
Method 1315
Calcium
Ca
L01
L04
LOS
L06
L07
L09
L10
L11
Ref
Mean
Mean
RSD
0.9%
1 .6%
1 .6%
1 .4%
0.7%
1 .5%
0.7%
1 .6%
0.9%
1 .2%
Stdev
RSD Complete
0.9% 100.0%
1 .5%
0.8%
1.1%
0.5%
0.7%
0.8%
1 .2%
1 .0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
Spike Spike
Rec Min Rec Max
86.2% 92.4%
83.0%
84.9%
89.4%
89.1%
84.6%
81.6%
84.1%
85.8%
82%
89.2%
88.8%
92.3%
93.8%
88.8%
91 .3%
89.2%
93.5%
94% Min-Max
Chromium
Cr
Lab#
L01
L04
L05
L06
L07
L09
L10
L11
Ref
Mean
Mean
RSD
1.1%
1 .9%
1 .8%
2.1%
1 .0%
1 .7%
1 .4%
2.1%
1 .4%
1 .6%
Stdev
RSD
0.7%
1 .6%
0.9%
1 .0%
0.4%
0.9%
0.9%
1 .5%
1 .2%
Complete
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
Spike
Rec Min
93.9%
94.6%
91 .2%
102.8%
93.4%
97.3%
88.4%
106.2%
97.1%
88%
Spike
Rec Max
101.9%
95.6%
98.2%
104.2%
104.1%
110.8%
96.0%
108.0%
103.9%
111% Min-Max
Potassium
K
Lab#
L01
L04
L05
L06
L07
L09
L10
L11
Ref
Mean
Mean
RSD
0.8%
1 .3%
1 .3%
1 .4%
0.7%
1 .6%
0.8%
1 .5%
0.7%
1.1%
Stdev
RSD Complete
0.5% 100.0%
0.9%
0.7%
0.6%
0.4%
1 .0%
0.7%
1.1%
0.5%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
Spike Spike
Rec Min Rec Max
86.4% 90.3%
85.9%
85.1%
86.0%
90.4%
85.1%
83.0%
95.7%
85.7%
83%
91 .6%
90.4%
91 .5%
101.4%
89.9%
90.8%
106.1%
94.6%
106% Min-Max
H-9
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
SWA Solidified Waste Analog
Method 1315
Selenium
Se
Lab#
L01
L04
LOS
L06
L07
L09
L10
L11
Ref
Mean
Mean
RSD
1 .0%
1 .5%
1 .5%
1 .5%
1.1%
1 .7%
1 .3%
1 .7%
1 .6%
1 .4%
Stdev
RSD Complete
0.8% 100.0%
1 .4%
1 .2%
0.9%
0.7%
0.8%
1.1%
1 .2%
2.5%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
98.1%
99.6%
Spike Spike
Rec Min Rec Max
90.2% 92.1%
90.3%
94.9%
98.8%
96.3%
91.7%
84.6%
94.8%
87.8%
85%
94.5%
101.2%
1 1 1 .8%
101.5%
94.1%
87.0%
97.7%
103.1%
112% Min-Max
Vanadium
V
Lab#
L01
L04
L05
L06
L07
L09
L10
L11
Ref
Mean
Mean
RSD
3.1%
4.3%
4.8%
4.8%
3.5%
4.6%
4.0%
3.8%
4.6%
4.2%
Stdev
RSD Complete
2.2% 100.0%
2.1%
2.9%
2.4%
2.2%
2.0%
2.0%
2.6%
2.8%
100.0%
96.3%
100.0%
100.0%
96.3%
100.0%
100.0%
94.4%
98.1%
Spike Spike
Rec Min Rec Max
90.5% 98.1%
97.4%
90.8%
101.5%
90.7%
93.0%
85.7%
102.9%
95.8%
86%
98.0%
94.9%
101.5%
102.7%
108.3%
92.2%
107.7%
102.4%
108% Min-Max
H-10
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
CFS Contaminated Field Soil
Method 1315
Overall Mean RSD 3.0%
Stdev of Mean RSDs 1.7%
Overall Mean Completeness 97.3%
Min Spike Recovery 83%
Max Spike Recovery 115%
Aluminum
Al
Lab#
L01
L04
L06
L07
L10
L11
Ref
Mean
Antimony
Sb
Boron
B
Lab#
L01
L04
L06
L07
L10
L11
Ref
Mean
Lab#
L01
L04
L06
L07
L10
L11
Ref
Mean
Mean
RSD
4.7%
4.5%
6.0%
4.2%
5.4%
4.4%
5.1%
4.9%
Stdev
RSD
3.1%
2.9%
2.5%
2.8%
3.4%
2.8%
2.9%
Complete
96.3%
96.3%
92.6%
92.6%
92.6%
96.3%
94.4%
94.4%
All concentrations are between MDL
Mean
RSD
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
Mean
RSD
2.3%
2.3%
2.1%
1 .9%
2.8%
2.4%
2.7%
2.4%
Stdev
RSD
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
Stdev
RSD
1 .5%
1 .6%
1 .3%
1 .3%
1 .9%
1 .3%
2.2%
Complete
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
0.0%
Complete
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
98.1%
99.5%
Spike
Rec Min
91.0%
96.3%
100.6%
94.0%
88.6%
91.0%
102.5%
89%
and ML
Spike
Rec Min
92.2%
99.2%
95.4%
95.0%
86.6%
89.9%
99.7%
87%
Spike
Rec Min
85.0%
100.3%
92.8%
89.0%
85.3%
90.3%
95.6%
85%
Spike
Rec Max
96.6%
100.5%
109.6%
97.2%
94.9%
93.7%
107.0%
110% Min-Max
Spike
Rec Max
97.9%
102.3%
99.1%
97.8%
94.0%
89.9%
102.6%
103% Min-Max
Spike
Rec Max
86.2%
113.8%
97.4%
92.9%
100.9%
94.1%
109.8%
114% Min-Max
H-ll
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
CFS Contaminated Field Soil
Method 1315
Cadmium
Cd
Lab#
L01
L04
L06
L07
L10
L11
Ref
Mean
Calcium
Ca
L01
L04
L06
L07
L10
L11
Ref
Mean
Lead
Pb
Lab#
L01
L04
L06
L07
L10
L11
Ref
Mean
Mean
RSD
1 .9%
1 .4%
2.4%
1 .6%
1 .9%
3.0%
1 .9%
2.0%
Mean
RSD
1 .5%
1 .5%
1 .6%
1 .5%
1 .6%
1 .2%
1 .5%
1 .5%
Mean
RSD
1 .6%
1 .2%
1 .5%
1 .6%
1 .6%
1 .4%
1 .5%
1 .5%
Mean
RSD
2.3%
2.2%
2.9%
1 .7%
2.4%
2.2%
2.1%
2.2%
Stdev
RSD
1 .3%
0.8%
1 .5%
1 .3%
1.1%
2.8%
1 .6%
Stdev
RSD
1 .2%
0.8%
1 .3%
1 .3%
1 .0%
0.7%
0.9%
Stdev
RSD
1 .3%
0.7%
1 .2%
1 .3%
1.1%
1 .0%
0.9%
Stdev
RSD
1 .5%
2.9%
2.6%
1 .3%
1 .6%
1 .3%
1 .5%
Complete
100.0%
100.0%
100.0%
100.0%
100.0%
96.3%
100.0%
99.5%
Complete
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
Complete
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
Complete
100.0%
96.3%
96.3%
100.0%
100.0%
100.0%
100.0%
99.1%
Spike
Rec Min
91.7%
99.2%
91.9%
92.3%
85.9%
90.9%
103.9%
86%
Spike
Rec Min
90.6%
92.8%
98.5%
90.6%
90.2%
100.4%
94.2%
90%
Spike
Rec Min
91.6%
89.9%
87.1%
84.3%
84.7%
89.9%
83.3%
83%
Spike
Rec Min
88.6%
92.3%
89.8%
97.3%
90.0%
94.1%
92.3%
89%
Spike
Rec Max
94.6%
99.8%
96.8%
95.4%
90.8%
94.2%
109.2%
109%
Spike
Rec Max
103.9%
109.3%
108.8%
95.5%
92.2%
102.0%
103.3%
109%
Spike
Rec Max
98.5%
92.1%
88.8%
89.9%
86.7%
92.8%
89.6%
98%
Spike
Rec Max
93.9%
102.5%
92.0%
105.2%
108.2%
95.7%
104.8%
108%
Min-Max
Min-Max
Min-Max
Min-Max
H-12
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
CFS Contaminated Field Soil
Method 1315
Potassium
K
Lab#
L01
L04
L06
L07
L10
L11
Ref
Mean
Mean
RSD
1 .5%
1 .6%
1 .6%
1 .5%
1 .6%
1 .6%
1 .6%
1 .5%
Stdev
RSD
1 .3%
1 .2%
1 .2%
1 .2%
1.1%
1 .5%
0.9%
Complete
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
Spike
Rec Min
97.6%
92.8%
94.6%
84.5%
87.8%
87.1%
87.0%
85%
Spike
Rec Max
115.0%
99.1%
105.6%
89.3%
95.5%
91 .7%
95.3%
115% Min-Max
Selenium
Se
Lab#
L01
L04
L06
L07
L10
L11
Ref
Mean
Mean
RSD
5.5%
4.3%
5.0%
6.9%
6.5%
6.6%
5.4%
5.7%
Stdev
RSD
4.4%
3.6%
4.2%
3.4%
2.7%
3.4%
3.8%
Complete
83.3%
85.7%
90.0%
91.7%
88.9%
91.7%
88.5%
88.5%
Spike
Rec Min
87.2%
100.6%
89.9%
89.8%
85.5%
93.0%
98.1%
85%
Spike
Rec Max
94.1%
107.1%
96.7%
92.7%
95.1%
95.9%
106.5%
107% Min-Max
Vanadium
V
Lab#
L01
L04
L06
L07
L10
L11
Ref
Mean
Mean
RSD
5.0%
4.9%
5.5%
5.9%
5.1%
4.2%
5.4%
5.2%
Stdev
RSD Complete
3.8% 93.3%
3.0%
3.0%
3.9%
3.3%
2.4%
3.4%
94.4%
91 .7%
93.8%
94.4%
100.0%
93.9%
94.4%
Spike Spike
Rec Min Rec Max
91.2% 97.1%
99.9%
90.0%
93.1%
86.0%
96.4%
98.7%
86%
101.3%
96.8%
96.5%
91 .9%
98.2%
101.4%
101% Min-Max
H-13
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Appendix I. QA/QC Reports for Analytical Samples
TABLE OF CONTENTS I-i
INTRODUCTION 1-1
ORGANIZATION OF THE QA/QC TABLES 1-1
DESCRIPTION OF THE COLUMNS IN THE ANALYTICAL QA/QC TABLES 1-1
Method 1314: Liquid-Solid Partitioning as a Function of Liquid-Solid Ratio using an Up-flow
Percolation Column Procedure
CFS - Contaminated Field Soil
L01 1-4
L06 1-33
L07 1-62
L10 1-91
Lll 1-120
L14 1-149
LRef 1-178
JaFS - Brass Foundry Sand
L01 1-236
L06 1-265
L07 1-294
L10 1-323
Lll 1-352
L14 1-381
LRef 1-410
Method 1315: Mass Transport Rates in Monolithic or Compacted Granular Materials Using a
Semi-dynamic Tank Leaching Procedure
SWA - Solidified Waste Analog
L01 1-468
L04 1-497
L05 1-526
L06 1-555
L07 1-584
L09 1-613
I-i
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
L10 1-642
Lll 1-671
LRef 1-700
CFS - Contaminated Field Soil
L01 1-758
L04 1-787
L06 1-816
L07 1-845
L10 1-874
Lll 1-903
LRef 1-932
I-ii
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
INTRODUCTION
The tables in this appendix present the quality assurance/quality control results for the analytical
measurement of eluate concentrations from the preserved eluates submitted by each of the validation
laboratories. The data shown in this appendix is applicable only to the analytical solutions measured by
inductively coupled plasma - optical emissions spectrometry (ICP-OES) performed by Vanderbilt
University (VU). The analytical methods, instrument calibration, and analytical QA/QC program
followed throughout this project are detailed in the main report starting on Page 10.
ORGANIZATION OF THE QA/QC TABLES
Each table in the appendix represents the final eluate solution concentrations for a single element from a
single laboratory. The tables are ordered alphabetically by element symbol (e.g., "Al" for aluminum or
"Sb" for antimony) for each validation laboratory code (e.g., "L01" for Laboratory 1 or "LRef' for
reference laboratory) within each the leaching method (i.e., Method 1314 versus Method 1315). The
information within each table is ordered by the test position number within each leaching method.
DESCRIPTION OF THE COLUMNS IN THE ANALYTICAL QA/QC TABLES
The following is a description of the columns in each table in the appendix.
Element (1st Column)
Element symbol identifiers based on the periodic chart.
Sample ID (2nd Column)
Coded identifier for each sample comprised of the following items separated by dashes:
• material code (e.g., "CFS", "SWA", or "JaFS")
• laboratory code (e.g., "L01" for Laboratory 1 or "LRef for reference laboratory)
• method code (e.g., "1314" for Method 1314)
• test position number (e.g., "T01" for first eluate of the test)
• replicate letter (e.g., "A" for first test run)
Dilution Factor (3rd Column)
The dilution factor for the analytical sample measured in the instrument or the multiplier associated
with calculating final eluate concentrations from analytical sample concentration. Typically for ICP-
OES, full strength analytical samples are measured and the resultant dilution factor is "1". However,
dilution factors of at least "10" are common for inductively coupled plasma - mass spectrometry
(ICP-MS) analysis in order to minimize interferences from analytical solutions with high sodium and
potassium content.
Sample Cone, in ug/L (4th Column)
The concentration of the analytical sample in (ig/L as measured by the analytical method specified in
the 14th Column.
1-1
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Qualifier (5th Column)
A quality control qualifier used to flag analytical samples that are below the quantification or
detection limits. The following table of qualifiers was used.
iQualifier
E
U
Ul/2
•Meaning
Estimated value between the MDL and ML values
Non-detected values below the MDL
Non-detected values below the MDL set to 1A the MDL
1
for graphing purposes
ICP-OES Cone. (6th Column)
The final eluate concentration used in the validation study determined by multiplying the analytical
sample concentration (4th Column) by the dilution factor (3rd Column).
RSD (7th Column)
Relative standard deviation of the three analytical measurements of the sample analytical sample
calculated automatically through instrument software. The RSD does not represent the relative
standard deviation of replicate analysis using triplicate samples.
MDL (8th Column)
The method detection limit (MDL) in (ig/L for the analysis using the analytical method specified in
the 14th Column. The value is calculated by the VU laboratory manager based on the standard
deviation of analysis of seven low-level standard solutions measured on seven non-consecutive days
and the Student's ^-distribution value for the seven replicates at the 99% confidence level (EPA,
2003).
where S(n=7) is the standard deviation of seven non-consecutive measurements ((ig/L), and
t(n-i=6,i-a=o.99) is the Student ^-distribution value for seven replicates at the 99% confidence
level (3.14267).
ML (9th Column)
The estimated minimum level of quantification (ML) in (ig/L for the analysis using the analytical
method specified in the 14th Column. The value is calculated by the VU laboratory manager based on
the previously calculated MDL (EPA, 2003).
1-2
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Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Spike Cone. (10th Column) and Spike Volume (11th Column)
The concentration in (ig/L of the standard solution used to spike analytical samples and the volume of
the standard solution added to each analytical sample. When multiplied, these values provide the
theoretical mass of an element that is spiked into an analytical sample.
A/f
1V1QA/QC spike
where MQA/QC spike is the theoretical mass of spiked into the analytical sample (|ig),
Cstd is the concentration of the standard solution (|ig/L), and
Vstd is the volume of the standard solution added to the analytical sample (|iL).
Spike Cone. (12th Column)
The concentration of the spiked analytical solution in (ig/L as measured by the analytical method
specified in the 14th Column.
Spike Recovery (13th Column)
The percentage of spiked mass recovered during analysis of the spiked solution. The spike recovery
is calculated by the VU laboratory manager using the following formula:
\^ QA/QC spike *- sample ) X * QA/QC spike
QA/AC spike
xlOO%
where CQA/QCspike is the concentration of the spiked analytical sample (|ig/L),
th
C sampie is the concentration of the analytical sample in the 4t Column ((ig/L), and
V QA/QC spike is the final volume of the spiked analytical sample (L).
Instrument (14th Column)
The instrument used for the analytical measurement (e.g., "VU ICP-OES" denotes that the instrument
was the Vanderbilt University Varian 620 ICP-OES).
Date/Time (15th Column)
The date and time that the analytical sample measurement was recorded by the instrument software.
This column is used to uniquely identify each analysis and does not reflect the data and time of spiked
solution measurement.
Filename (16th Column)
The name of the instrument output file where the analytical data is stored.
1-3
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1314:
Element
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Dilution Sample
Sample ID Factor Cone. Qualifier
ug/L I
CFS-L01-1314-T01-A 1 4.97E+01
CFS-L01-1314-T02-A 1 4.50E+01
CFS-L01-1314-T03-A 1 4.07E+01
CFS-L01-1314-T04-A 1 4.21E+01
CFS-L01-1314-T05-A 1 3.61E+01
CFS-L01-1314-T06-A 1 3.80E+01
CFS-L01-1314-T07-A 1 3.45E+01
CFS-L01-1314-T08-A 1 3.95E+01
CFS-L01-1314-T09-A 1 3.63E+01
CFS-L01-1314-T01-B 1 5.00E+01
CFS-L01-1314-T02-B 1 4.34E+01
CFS-L01-1314-T03-B 1 3.81E+01
CFS-L01-1314-T04-B 1 4.34E+01
CFS-L01-1314-T05-B 1 3.80E+01
CFS-L01-1314-T06-B 1 3.71E+01
CFS-L01-1314-T07-B 1 3.20E+01
CFS-L01-1314-T08-B 1 3.56E+01
CFS-L01-1314-T09-B 1 3.73E+01
CFS-L01-1314-T01-C 1 5.22E+01
CFS-L01-1314-T02-C 1 5.11E+01
CFS-L01-1314-T03-C 1 4.59E+01
CFS-L01-1314-T04-C 1 4.31E+01
CFS-L01-1314-T05-C 1 3.80E+01
CFS-L01-1314-T06-C 1 3.61E+01
CFS-L01-1314-T07-C 1 3.54E+01
CFS-L01-1314-T08-C 1 3.70E+01
CFS-L01-1314-T09-C 1 3.53E+01
CFS-L01-1314-B01-A 1 5.00E-01 U1/2
ICP-OES
Cone. RSD MDL
ug/L % ug/L
4.97E+01 2.49 1.00
4.50E+01 3.23 1.00
4.07E+01 2.20 1.00
4.21E+01 2.11 1.00
3.61E+01 3.17 1.00
3.80E+01 3.35 1.00
3.45E+01 6.27 1.00
3.95E+01 3.54 1.00
3.63E+01 8.62 1.00
5.00E+01 2.48 1.00
4.34E+01 2.20 1.00
3.81 E+01 1.91 1.00
4.34E+01 5.05 1.00
3.80E+01 0.99 1.00
3.71 E+01 3.68 1.00
3.20E+01 3.70 1.00
3.56E+01 7.12 1.00
3.73E+01 7.56 1.00
5.22E+01 3.61 1.00
5.11E+01 1.76 1.00
4.59E+01 6.36 1.00
4.31 E+01 1.47 1.00
3.80E+01 2.40 1.00
3.61 E+01 7.83 1.00
3.54E+01 6.52 1.00
3.70E+01 5.64 1.00
3.53E+01 1.99 1.00
5.00E-01 4.45 1.00
Spike Sol'n
ML Cone. Volume
ug/L ug/L ML
3.18
3.18
3.18 10000 1000
3.18
3.18
3.18
3.18
3.18
3.18
3.18
3.18
3.18 10000 1000
3.18
3.18
3.18
3.18
3.18
3.18
3.18
3.18
3.18 10000 1000
3.18
3.18
3.18
3.18
3.18
3.18
3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.16E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time
3/7/12 1:37 PM
3/7/12 1:38PM
3/7/12 1:40PM
3/7/12 1:42PM
3/7/12 1:43PM
3/7/12 1:45PM
3/7/12 1:47PM
3/7/12 1:48PM
3/7/12 1:50PM
3/7/12 1:52PM
3/7/12 1:53PM
3/7/12 1:55PM
3/7/12 1:57PM
3/7/12 1:58PM
3/7/122:OOPM
3/7/122:02PM
3/7/122:03PM
3/7/122:05PM
3/7/122:07PM
3/7/122:08PM
3/7/12 2:10 PM
3/7/12 2:12 PM
3/7/12 2:13 PM
3/7/12 2:15 PM
3/7/12 2:17 PM
3/7/12 2:18 PM
3/7/122:20PM
3/7/12 1:35PM
Filename
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
EPA Interlab L01 1314 CFS
1-4
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Sb CFS-L01-1314-T01-A 1 9.57E+01
Sb CFS-L01-1314-T02-A 1 5.03E+01
Sb CFS-L01-1314-T03-A 1 3.51E+01
Sb CFS-L01-1314-T04-A 1 2.67E+01
Sb CFS-L01-1314-T05-A 1 2.98E+01
Sb CFS-L01-1314-T06-A 1 1.94E+01 E
Sb CFS-L01-1314-T07-A 1 1.92E+01 E
Sb CFS-L01-1314-T08-A 1 2.25E+01 E
Sb CFS-L01-1314-T09-A 1 1.30E+01 E
Sb CFS-L01-1314-T01-B 1 8.47E+01
Sb CFS-L01-1314-T02-B 1 4.51E+01
Sb CFS-L01-1314-T03-B 1 3.55E+01
Sb CFS-L01-1314-T04-B 1 2.72E+01
Sb CFS-L01-1314-T05-B 1 2.78E+01
Sb CFS-L01-1314-T06-B 1 2.51E+01
Sb CFS-L01-1314-T07-B 1 2.05E+01 E
Sb CFS-L01-1314-T08-B 1 2.14E+01 E
Sb CFS-L01-1314-T09-B 1 1.80E+01 E
Sb CFS-L01-1314-T01-C 1 8.95E+01
Sb CFS-L01-1314-T02-C 1 4.72E+01
Sb CFS-L01-1314-T03-C 1 3.17E+01
Sb CFS-L01-1314-T04-C 1 3.12E+01
Sb CFS-L01-1314-T05-C 1 2.39E+01
Sb CFS-L01-1314-T06-C 1 2.50E+01
Sb CFS-L01-1314-T07-C 1 2.66E+01
Sb CFS-L01-1314-T08-C 1 2.71E+01
Sb CFS-L01-1314-T09-C 1 1.99E+01 E
Sb CFS-L01-1314-B01-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.57E+01 4.85 7.50 23.90
5.03E+01 6.42 7.50 23.90
3.51 E+01 3.55 7.50 23.90 10000 1000
2.67E+01 2.03 7.50 23.90
2.98E+01 11.30 7.50 23.90
1.94E+01 26.77 7.50 23.90
1.92E+01 33.11 7.50 23.90
2.25E+01 15.91 7.50 23.90
1.30E+01 28.86 7.50 23.90
8.47E+01 1.42 7.50 23.90
4.51 E+01 7.77 7.50 23.90
3.55E+01 2.29 7.50 23.90 10000 1000
2.72E+01 2.71 7.50 23.90
2.78E+01 2.81 7.50 23.90
2.51E+01 11.18 7.50 23.90
2.05E+01 17.62 7.50 23.90
2.14E+01 27.59 7.50 23.90
1.80E+01 14.18 7.50 23.90
8.95E+01 6.80 7.50 23.90
4.72E+01 1.41 7.50 23.90
3.17E+01 2.06 7.50 23.90 10000 1000
3.12E+01 1.89 7.50 23.90
2.39E+01 2.74 7.50 23.90
2.50E+01 1.15 7.50 23.90
2.66E+01 1.89 7.50 23.90
2.71 E+01 1.76 7.50 23.90
1.99E+01 25.50 7.50 23.90
3.75E+00 42.79 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.13E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.11E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314 CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314 CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-5
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
As CFS-L01-1314-T01-A 1 4.46E+01
As CFS-L01-1314-T02-A 1 2.77E+01 E
As CFS-L01-1314-T03-A 1 1.64E+01 E
As CFS-L01-1314-T04-A 1 1.83E+01 E
As CFS-L01-1314-T05-A 1 1.38E+01 E
As CFS-L01-1314-T06-A 1 1.46E+01 E
As CFS-L01-1314-T07-A 1 2.21E+01 E
As CFS-L01-1314-T08-A 1 1.84E+01 E
As CFS-L01-1314-T09-A 1 1.46E+01 E
As CFS-L01-1314-T01-B 1 6.96E+01
As CFS-L01-1314-T02-B 1 2.70E+01 E
As CFS-L01-1314-T03-B 1 2.41E+01 E
As CFS-L01-1314-T04-B 1 1.65E+01 E
As CFS-L01-1314-T05-B 1 2.17E+01 E
As CFS-L01-1314-T06-B 1 2.10E+01 E
As CFS-L01-1314-T07-B 1 2.25E+01 E
As CFS-L01-1314-T08-B 1 2.45E+01 E
As CFS-L01-1314-T09-B 1 1.49E+01 E
As CFS-L01-1314-T01-C 1 6.73E+01
As CFS-L01-1314-T02-C 1 2.89E+01 E
As CFS-L01-1314-T03-C 1 1.17E+01 E
As CFS-L01-1314-T04-C 1 2.49E+01 E
As CFS-L01-1314-T05-C 1 1.68E+01 E
As CFS-L01-1314-T06-C 1 1.77E+01 E
As CFS-L01-1314-T07-C 1 1.32E+01 E
As CFS-L01-1314-T08-C 1 1.85E+01 E
As CFS-L01-1314-T09-C 1 1.63E+01 E
As CFS-L01-1314-B01-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.46E+01 8.72 11.00 35.00
2.77E+01 11.58 11.00 35.00
1.64E+01 13.96 11.00 35.00 10000 1000
1.83E+01 21.06 11.00 35.00
1.38E+01 27.75 11.00 35.00
1.46E+01 37.58 11.00 35.00
2.21 E+01 35.95 11.00 35.00
1.84E+01 24.22 11.00 35.00
1.46E+01 24.65 11.00 35.00
6.96E+01 4.10 11.00 35.00
2.70E+01 9.84 11.00 35.00
2.41 E+01 26.13 11.00 35.00 10000 1000
1.65E+01 27.75 11.00 35.00
2.17E+01 38.25 11.00 35.00
2.10E+01 30.83 11.00 35.00
2.25E+01 37.06 11.00 35.00
2.45E+01 24.29 11.00 35.00
1.49E+01 37.94 11.00 35.00
6.73E+01 1.90 11.00 35.00
2.89E+01 14.65 11.00 35.00
1.17E+01 31.16 11.00 35.00 10000 1000
2.49E+01 20.07 11.00 35.00
1.68E+01 8.80 11.00 35.00
1.77E+01 15.19 11.00 35.00
1.32E+01 16.79 11.00 35.00
1.85E+01 9.66 11.00 35.00
1.63E+01 6.03 11.00 35.00
5.50E+00 42.13 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.13E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.11E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314 CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314 CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-6
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
B CFS-L01-1314-T01-A 1 2.57E+03
B CFS-L01-1314-T02-A 1 1.58E+03
B CFS-L01-1314-T03-A 1 7.06E+02
B CFS-L01-1314-T04-A 1 3.18E+02
B CFS-L01-1314-T05-A 1 2.04E+02
B CFS-L01-1314-T06-A 1 1.36E+02
B CFS-L01-1314-T07-A 1 8.66E+01
B CFS-L01-1314-T08-A 1 6.20E+01
B CFS-L01-1314-T09-A 1 4.70E+01
B CFS-L01-1314-T01-B 1 2.71E+03
B CFS-L01-1314-T02-B 1 1.69E+03
B CFS-L01-1314-T03-B 1 7.12E+02
B CFS-L01-1314-T04-B 1 3.47E+02
B CFS-L01-1314-T05-B 1 2.32E+02
B CFS-L01-1314-T06-B 1 1.36E+02
B CFS-L01-1314-T07-B 1 9.10E+01
B CFS-L01-1314-T08-B 1 7.05E+01
B CFS-L01-1314-T09-B 1 5.29E+01
B CFS-L01-1314-T01-C 1 2.73E+03
B CFS-L01-1314-T02-C 1 1.70E+03
B CFS-L01-1314-T03-C 1 7.15E+02
B CFS-L01-1314-T04-C 1 3.50E+02
B CFS-L01-1314-T05-C 1 2.34E+02
B CFS-L01-1314-T06-C 1 1.34E+02
B CFS-L01-1314-T07-C 1 9.27E+01
B CFS-L01-1314-T08-C 1 6.96E+01
B CFS-L01-1314-T09-C 1 5.30E+01
B CFS-L01-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.57E+03 0.67 1.00 3.18
1.58E+03 0.88 1.00 3.18
7.06E+02 0.89 1.00 3.18 10000 1000
3.18E+02 0.95 1.00 3.18
2.04E+02 1.63 1.00 3.18
1.36E+02 0.58 1.00 3.18
8.66E+01 0.45 1.00 3.18
6.20E+01 1.07 1.00 3.18
4.70E+01 2.10 1.00 3.18
2.71E+03 0.22 1.00 3.18
1.69E+03 0.34 1.00 3.18
7.12E+02 0.71 1.00 3.18 10000 1000
3.47E+02 0.26 1.00 3.18
2.32E+02 0.30 1.00 3.18
1.36E+02 1.94 1.00 3.18
9.10E+01 1.58 1.00 3.18
7.05E+01 2.75 1.00 3.18
5.29E+01 2.22 1.00 3.18
2.73E+03 0.85 1.00 3.18
1.70E+03 0.45 1.00 3.18
7.15E+02 0.79 1.00 3.18 10000 1000
3.50E+02 0.30 1.00 3.18
2.34E+02 0.28 1.00 3.18
1.34E+02 1.04 1.00 3.18
9.27E+01 2.24 1.00 3.18
6.96E+01 1.54 1.00 3.18
5.30E+01 5.17 1.00 3.18
5.00E-01 1.00 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.64E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.68E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.69E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314 CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314 CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-7
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ba CFS-L01-1314-T01-A 1 3.55E+01
Ba CFS-L01-1314-T02-A 1 4.73E+01
Ba CFS-L01-1314-T03-A 1 5.50E+01
Ba CFS-L01-1314-T04-A 1 5.75E+01
Ba CFS-L01-1314-T05-A 1 6.15E+01
Ba CFS-L01-1314-T06-A 1 6.63E+01
Ba CFS-L01-1314-T07-A 1 7. 11 E+01
Ba CFS-L01-1314-T08-A 1 7.45E+01
Ba CFS-L01-1314-T09-A 1 7.89E+01
Ba CFS-L01-1314-T01-B 1 3.36E+01
Ba CFS-L01-1314-T02-B 1 4.72E+01
Ba CFS-L01-1314-T03-B 1 5.51 E+01
Ba CFS-L01-1314-T04-B 1 5.76E+01
Ba CFS-L01-1314-T05-B 1 5.90E+01
Ba CFS-L01-1314-T06-B 1 6.48E+01
Ba CFS-L01-1314-T07-B 1 7.05E+01
Ba CFS-L01-1314-T08-B 1 7.35E+01
Ba CFS-L01-1314-T09-B 1 7.72E+01
Ba CFS-L01-1314-T01-C 1 3.49E+01
Ba CFS-L01-1314-T02-C 1 4.81 E+01
Ba CFS-L01-1314-T03-C 1 5.56E+01
Ba CFS-L01-1314-T04-C 1 5.85E+01
Ba CFS-L01-1314-T05-C 1 5.97E+01
Ba CFS-L01-1314-T06-C 1 6.45E+01
Ba CFS-L01-1314-T07-C 1 7.01E+01
Ba CFS-L01-1314-T08-C 1 7.33E+01
Ba CFS-L01-1314-T09-C 1 7.76E+01
Ba CFS-L01-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.55E+01 0.78 1.00 3.18
4.73E+01 1.05 1.00 3.18
5.50E+01 0.83 1.00 3.18 10000 1000
5.75E+01 0.41 1.00 3.18
6.15E+01 1.60 1.00 3.18
6.63E+01 0.47 1.00 3.18
7. 11 E+01 1.03 1.00 3.18
7.45E+01 0.43 1.00 3.18
7.89E+01 0.49 1.00 3.18
3.36E+01 0.98 1.00 3.18
4.72E+01 0.28 1.00 3.18
5.51E+01 0.41 1.00 3.18 10000 1000
5.76E+01 0.39 1.00 3.18
5.90E+01 0.10 1.00 3.18
6.48E+01 1.03 1.00 3.18
7.05E+01 0.38 1.00 3.18
7.35E+01 0.51 1.00 3.18
7.72E+01 0.61 1.00 3.18
3.49E+01 0.24 1.00 3.18
4.81E+01 0.50 1.00 3.18
5.56E+01 0.49 1.00 3.18 10000 1000
5.85E+01 1.18 1.00 3.18
5.97E+01 0.27 1.00 3.18
6.45E+01 0.44 1.00 3.18
7.01E+01 0.06 1.00 3.18
7.33E+01 0.38 1.00 3.18
7.76E+01 5.00 1.00 3.18
5.00E-01 4.40 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.07E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314 CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314 CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L I
Be CFS-L01-1314-T01-A 1 9.50E-01 U1/2
Be CFS-L01-1314-T02-A 1 9.50E-01 U1/2
Be CFS-L01-1314-T03-A 1 9.50E-01 U1/2
Be CFS-L01-1314-T04-A 1 9.50E-01 U1/2
Be CFS-L01-1314-T05-A 1 9.50E-01 U1/2
Be CFS-L01-1314-T06-A 1 9.50E-01 U1/2
Be CFS-L01-1314-T07-A 1 9.50E-01 U1/2
Be CFS-L01-1314-T08-A 1 9.50E-01 U1/2
Be CFS-L01-1314-T09-A 1 9.50E-01 U1/2
Be CFS-L01-1314-T01-B 1 9.50E-01 U1/2
Be CFS-L01-1314-T02-B 1 9.50E-01 U1/2
Be CFS-L01-1314-T03-B 1 9.50E-01 U1/2
Be CFS-L01-1314-T04-B 1 9.50E-01 U1/2
Be CFS-L01-1314-T05-B 1 9.50E-01 U1/2
Be CFS-L01-1314-T06-B 1 9.50E-01 U1/2
Be CFS-L01-1314-T07-B 1 9.50E-01 U1/2
Be CFS-L01-1314-T08-B 1 9.50E-01 U1/2
Be CFS-L01-1314-T09-B 1 9.50E-01 U1/2
Be CFS-L01-1314-T01-C 1 9.50E-01 U1/2
Be CFS-L01-1314-T02-C 1 9.50E-01 U1/2
Be CFS-L01-1314-T03-C 1 9.50E-01 U1/2
Be CFS-L01-1314-T04-C 1 9.50E-01 U1/2
Be CFS-L01-1314-T05-C 1 9.50E-01 U1/2
Be CFS-L01-1314-T06-C 1 9.50E-01 U1/2
Be CFS-L01-1314-T07-C 1 9.50E-01 U1/2
Be CFS-L01-1314-T08-C 1 9.50E-01 U1/2
Be CFS-L01-1314-T09-C 1 9.50E-01 U1/2
Be CFS-L01-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 5.23 1.90 6.00
9.50E-01 18.48 1.90 6.00
9.50E-01 22.46 1.90 6.00 10000 1000
9.50E-01 27.70 1.90 6.00
9.50E-01 18.93 1.90 6.00
9.50E-01 35.00 1.90 6.00
9.50E-01 7.77 1.90 6.00
9.50E-01 32.84 1.90 6.00
9.50E-01 23.80 1.90 6.00
9.50E-01 10.77 1.90 6.00
9.50E-01 15.16 1.90 6.00
9.50E-01 24.31 1.90 6.00 10000 1000
9.50E-01 10.13 1.90 6.00
9.50E-01 22.46 1.90 6.00
9.50E-01 12.04 1.90 6.00
9.50E-01 28.50 1.90 6.00
9.50E-01 23.78 1.90 6.00
9.50E-01 18.45 1.90 6.00
9.50E-01 16.28 1.90 6.00
9.50E-01 41.55 1.90 6.00
9.50E-01 24.74 1.90 6.00 10000 1000
9.50E-01 29.75 1.90 6.00
9.50E-01 18.71 1.90 6.00
9.50E-01 33.34 1.90 6.00
9.50E-01 42.70 1.90 6.00
9.50E-01 34.08 1.90 6.00
9.50E-01 21.41 1.90 6.00
9.50E-01 31.04 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.07E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314 CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314 CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-9
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Cd CFS-L01-1314-T01-A 1 2.17E+04
Cd CFS-L01-1314-T02-A 1 1.23E+04
Cd CFS-L01-1314-T03-A 1 1.11E+04
Cd CFS-L01-1314-T04-A 1 1.05E+04
Cd CFS-L01-1314-T05-A 1 1.00E+04
Cd CFS-L01-1314-T06-A 1 8.05E+03
Cd CFS-L01-1314-T07-A 1 6.27E+03
Cd CFS-L01-1314-T08-A 1 4.58E+03
Cd CFS-L01-1314-T09-A 1 3.63E+03
Cd CFS-L01-1314-T01-B 1 2.29E+04
Cd CFS-L01-1314-T02-B 1 1.22E+04
Cd CFS-L01-1314-T03-B 1 1.09E+04
Cd CFS-L01-1314-T04-B 1 1.06E+04
Cd CFS-L01-1314-T05-B 1 1.00E+04
Cd CFS-L01-1314-T06-B 1 8.29E+03
Cd CFS-L01-1314-T07-B 1 6.52E+03
Cd CFS-L01-1314-T08-B 1 4.95E+03
Cd CFS-L01-1314-T09-B 1 4.12E+03
Cd CFS-L01-1314-T01-C 1 2.16E+04
Cd CFS-L01-1314-T02-C 1 1.18E+04
Cd CFS-L01-1314-T03-C 1 1.06E+04
Cd CFS-L01-1314-T04-C 1 1.04E+04
Cd CFS-L01-1314-T05-C 1 1.00E+04
Cd CFS-L01-1314-T06-C 1 8.19E+03
Cd CFS-L01-1314-T07-C 1 6.58E+03
Cd CFS-L01-1314-T08-C 1 5.01E+03
Cd CFS-L01-1314-T09-C 1 4.26E+03
Cd CFS-L01-1314-B01-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.17E+04 1.33 2.20 7.00
1.23E+04 0.68 2.20 7.00
1.11E+04 0.41 2.20 7.00 10000 1000
1.05E+04 0.34 2.20 7.00
1.00E+04 0.90 2.20 7.00
8.05E+03 0.40 2.20 7.00
6.27E+03 0.55 2.20 7.00
4.58E+03 0.42 2.20 7.00
3.63E+03 0.73 2.20 7.00
2.29E+04 0.56 2.20 7.00
1.22E+04 0.35 2.20 7.00
1.09E+04 0.50 2.20 7.00 10000 1000
1.06E+04 0.49 2.20 7.00
1.00E+04 0.36 2.20 7.00
8.29E+03 0.81 2.20 7.00
6.52E+03 0.34 2.20 7.00
4.95E+03 0.57 2.20 7.00
4.12E+03 0.58 2.20 7.00
2.16E+04 0.83 2.20 7.00
1.18E+04 1.16 2.20 7.00
1.06E+04 0.55 2.20 7.00 10000 1000
1.04E+04 0.94 2.20 7.00
1.00E+04 0.33 2.20 7.00
8.19E+03 0.57 2.20 7.00
6.58E+03 0.19 2.20 7.00
5.01 E+03 0.46 2.20 7.00
4.26E+03 5.06 2.20 7.00
1.10E+00 26.33 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.22E+04 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+04 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314 CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314 CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-10
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Ca CFS-L01-1314-T01-A 1 4.37E+05
Ca CFS-L01-1314-T02-A 1 4.88E+05
Ca CFS-L01-1314-T03-A 1 5.56E+05
Ca CFS-L01-1314-T04-A 1 5.89E+05
Ca CFS-L01-1314-T05-A 1 6.09E+05
Ca CFS-L01-1314-T06-A 1 6.08E+05
Ca CFS-L01-1314-T07-A 1 6.11E+05
Ca CFS-L01-1314-T08-A 1 6.14E+05
Ca CFS-L01-1314-T09-A 1 6.13E+05
Ca CFS-L01-1314-T01-B 1 4.31 E+05
Ca CFS-L01-1314-T02-B 1 4.91 E+05
Ca CFS-L01-1314-T03-B 1 5.52E+05
Ca CFS-L01-1314-T04-B 1 5.90E+05
Ca CFS-L01-1314-T05-B 1 5.93E+05
Ca CFS-L01-1314-T06-B 1 6.04E+05
Ca CFS-L01-1314-T07-B 1 6.12E+05
Ca CFS-L01-1314-T08-B 1 6.17E+05
Ca CFS-L01-1314-T09-B 1 6.30E+05
Ca CFS-L01-1314-T01-C 1 4.31 E+05
Ca CFS-L01-1314-T02-C 1 4.92E+05
Ca CFS-L01-1314-T03-C 1 5.54E+05
Ca CFS-L01-1314-T04-C 1 5.93E+05
Ca CFS-L01-1314-T05-C 1 6.02E+05
Ca CFS-L01-1314-T06-C 1 6.03E+05
Ca CFS-L01-1314-T07-C 1 6.12E+05
Ca CFS-L01-1314-T08-C 1 6.12E+05
Ca CFS-L01-1314-T09-C 1 6.38E+05
Ca CFS-L01-1314-B01-A 1 1.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.37E+05 0.49 2.60 8.30
4.88E+05 0.58 2.60 8.30
5.56E+05 0.39 2.60 8.30 10000 1000
5.89E+05 0.36 2.60 8.30
6.09E+05 0.66 2.60 8.30
6.08E+05 0.45 2.60 8.30
6. 11 E+05 0.33 2.60 8.30
6.14E+05 0.62 2.60 8.30
6.13E+05 0.53 2.60 8.30
4.31 E+05 0.73 2.60 8.30
4.91 E+05 0.27 2.60 8.30
5.52E+05 0.76 2.60 8.30 10000 1000
5.90E+05 0.68 2.60 8.30
5.93E+05 0.28 2.60 8.30
6.04E+05 0.85 2.60 8.30
6.12E+05 0.20 2.60 8.30
6.17E+05 0.38 2.60 8.30
6.30E+05 0.51 2.60 8.30
4.31 E+05 0.29 2.60 8.30
4.92E+05 0.50 2.60 8.30
5.54E+05 0.56 2.60 8.30 10000 1000
5.93E+05 0.83 2.60 8.30
6.02E+05 0.23 2.60 8.30
6.03E+05 0.46 2.60 8.30
6.12E+05 0.11 2.60 8.30
6.12E+05 0.42 2.60 8.30
6.38E+05 5.05 2.60 8.30
1.30E+00 18.97 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.57E+05 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.53E+05 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.54E+05 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314 CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314 CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-11
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L I
Cr CFS-L01-1314-T01-A 1 6.00E-01 U1/2
Cr CFS-L01-1314-T02-A 1 6.00E-01 U1/2
Cr CFS-L01-1314-T03-A 1 6.00E-01 U1/2
Cr CFS-L01-1314-T04-A 1 6.00E-01 U1/2
Cr CFS-L01-1314-T05-A 1 6.00E-01 U1/2
Cr CFS-L01-1314-T06-A 1 6.00E-01 U1/2
Cr CFS-L01-1314-T07-A 1 6.00E-01 U1/2
Cr CFS-L01-1314-T08-A 1 6.00E-01 U1/2
Cr CFS-L01-1314-T09-A 1 6.00E-01 U1/2
Cr CFS-L01-1314-T01-B 1 6.00E-01 U1/2
Cr CFS-L01-1314-T02-B 1 6.00E-01 U1/2
Cr CFS-L01-1314-T03-B 1 6.00E-01 U1/2
Cr CFS-L01-1314-T04-B 1 6.00E-01 U1/2
Cr CFS-L01-1314-T05-B 1 6.00E-01 U1/2
Cr CFS-L01-1314-T06-B 1 6.00E-01 U1/2
Cr CFS-L01-1314-T07-B 1 6.00E-01 U1/2
Cr CFS-L01-1314-T08-B 1 6.00E-01 U1/2
Cr CFS-L01-1314-T09-B 1 6.00E-01 U1/2
Cr CFS-L01-1314-T01-C 1 6.00E-01 U1/2
Cr CFS-L01-1314-T02-C 1 6.00E-01 U1/2
Cr CFS-L01-1314-T03-C 1 6.00E-01 U1/2
Cr CFS-L01-1314-T04-C 1 6.00E-01 U1/2
Cr CFS-L01-1314-T05-C 1 6.00E-01 U1/2
Cr CFS-L01-1314-T06-C 1 6.00E-01 U1/2
Cr CFS-L01-1314-T07-C 1 6.00E-01 U1/2
Cr CFS-L01-1314-T08-C 1 6.00E-01 U1/2
Cr CFS-L01-1314-T09-C 1 6.00E-01 U1/2
Cr CFS-L01-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 29.40 1.20 3.82
6.00E-01 76.82 1.20 3.82
6.00E-01 51.10 1.20 3.82 10000 1000
6.00E-01 31.11 1.20 3.82
6.00E-01 17.09 1.20 3.82
6.00E-01 70.83 1.20 3.82
6.00E-01 58.32 1.20 3.82
6.00E-01 48.53 1.20 3.82
6.00E-01 20.64 1.20 3.82
6.00E-01 33.23 1.20 3.82
6.00E-01 36.45 1.20 3.82
6.00E-01 76.66 1.20 3.82 10000 1000
6.00E-01 13.20 1.20 3.82
6.00E-01 49.80 1.20 3.82
6.00E-01 11.19 1.20 3.82
6.00E-01 4.12 1.20 3.82
6.00E-01 49.00 1.20 3.82
6.00E-01 38.08 1.20 3.82
6.00E-01 5.28 1.20 3.82
6.00E-01 52.37 1.20 3.82
6.00E-01 37.76 1.20 3.82 10000 1000
6.00E-01 26.14 1.20 3.82
6.00E-01 49.87 1.20 3.82
6.00E-01 10.76 1.20 3.82
6.00E-01 32.48 1.20 3.82
6.00E-01 33.85 1.20 3.82
6.00E-01 58.43 1.20 3.82
6.00E-01 23.39 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.82E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.93E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314 CFS
10/6/11 3:37 PM EPA Interlab L01 1314CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314 CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-12
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Co CFS-L01-1314-T01-A 1 9.53E+02
Co CFS-L01-1314-T02-A 1 4.95E+02
Co CFS-L01-1314-T03-A 1 4.00E+02
Co CFS-L01-1314-T04-A 1 3.42E+02
Co CFS-L01-1314-T05-A 1 2.79E+02
Co CFS-L01-1314-T06-A 1 1.55E+02
Co CFS-L01-1314-T07-A 1 7.70E+01
Co CFS-L01-1314-T08-A 1 4.94E+01
Co CFS-L01-1314-T09-A 1 3.60E+01
Co CFS-L01-1314-T01-B 1 9.73E+02
Co CFS-L01-1314-T02-B 1 4.81 E+02
Co CFS-L01-1314-T03-B 1 3.89E+02
Co CFS-L01-1314-T04-B 1 3.51 E+02
Co CFS-L01-1314-T05-B 1 3.02E+02
Co CFS-L01-1314-T06-B 1 1.68E+02
Co CFS-L01-1314-T07-B 1 8.52E+01
Co CFS-L01-1314-T08-B 1 5.63E+01
Co CFS-L01-1314-T09-B 1 4.20E+01
Co CFS-L01-1314-T01-C 1 9.08E+02
Co CFS-L01-1314-T02-C 1 4.57E+02
Co CFS-L01-1314-T03-C 1 3.83E+02
Co CFS-L01-1314-T04-C 1 3.49E+02
Co CFS-L01-1314-T05-C 1 3.09E+02
Co CFS-L01-1314-T06-C 1 1.66E+02
Co CFS-L01-1314-T07-C 1 8.34E+01
Co CFS-L01-1314-T08-C 1 5.67E+01
Co CFS-L01-1314-T09-C 1 4.31E+01
Co CFS-L01-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.53E+02 1.00 1.80 5.72
4.95E+02 0.46 1.80 5.72
4.00E+02 0.41 1.80 5.72 10000 1000
3.42E+02 0.21 1.80 5.72
2.79E+02 0.87 1.80 5.72
1.55E+02 0.38 1.80 5.72
7.70E+01 0.75 1.80 5.72
4.94E+01 0.64 1.80 5.72
3.60E+01 0.75 1.80 5.72
9.73E+02 1.83 1.80 5.72
4.81 E+02 0.47 1.80 5.72
3.89E+02 0.68 1.80 5.72 10000 1000
3.51 E+02 0.74 1.80 5.72
3.02E+02 0.61 1.80 5.72
1.68E+02 1.66 1.80 5.72
8.52E+01 0.75 1.80 5.72
5.63E+01 0.89 1.80 5.72
4.20E+01 3.20 1.80 5.72
9.08E+02 0.26 1.80 5.72
4.57E+02 0.98 1.80 5.72
3.83E+02 0.82 1.80 5.72 10000 1000
3.49E+02 0.75 1.80 5.72
3.09E+02 0.17 1.80 5.72
1.66E+02 0.47 1.80 5.72
8.34E+01 1.51 1.80 5.72
5.67E+01 2.14 1.80 5.72
4.31 E+01 3.75 1.80 5.72
9.00E-01 40.41 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.42E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.36E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.35E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314 CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314 CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-13
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Cu CFS-L01-1314-T01-A 1 4.45E+03
Cu CFS-L01-1314-T02-A 1 2.85E+03
Cu CFS-L01-1314-T03-A 1 2.52E+03
Cu CFS-L01-1314-T04-A 1 2.36E+03
Cu CFS-L01-1314-T05-A 1 2.23E+03
Cu CFS-L01-1314-T06-A 1 1.73E+03
Cu CFS-L01-1314-T07-A 1 1.36E+03
Cu CFS-L01-1314-T08-A 1 9.42E+02
Cu CFS-L01-1314-T09-A 1 8.03E+02
Cu CFS-L01-1314-T01-B 1 4.47E+03
Cu CFS-L01-1314-T02-B 1 2.84E+03
Cu CFS-L01-1314-T03-B 1 2.51E+03
Cu CFS-L01-1314-T04-B 1 2.48E+03
Cu CFS-L01-1314-T05-B 1 1.53E+03
Cu CFS-L01-1314-T06-B 1 1.74E+03
Cu CFS-L01-1314-T07-B 1 1.40E+03
Cu CFS-L01-1314-T08-B 1 1.05E+03
Cu CFS-L01-1314-T09-B 1 9.12E+02
Cu CFS-L01-1314-T01-C 1 4.00E+03
Cu CFS-L01-1314-T02-C 1 2.68E+03
Cu CFS-L01-1314-T03-C 1 2.30E+03
Cu CFS-L01-1314-T04-C 1 1.54E+03
Cu CFS-L01-1314-T05-C 1 2.24E+03
Cu CFS-L01-1314-T06-C 1 1.74E+03
Cu CFS-L01-1314-T07-C 1 1.38E+03
Cu CFS-L01-1314-T08-C 1 1.05E+03
Cu CFS-L01-1314-T09-C 1 8.94E+02
Cu CFS-L01-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.45E+03 1.42 3.70 11.80
2.85E+03 1.99 3.70 11.80
2.52E+03 0.56 3.70 11.80 10000 1000
2.36E+03 1.12 3.70 11.80
2.23E+03 2.00 3.70 11.80
1.73E+03 0.56 3.70 11.80
1.36E+03 1.09 3.70 11.80
9.42E+02 0.69 3.70 11.80
8.03E+02 0.93 3.70 11.80
4.47E+03 0.50 3.70 11.80
2.84E+03 1.22 3.70 11.80
2.51 E+03 0.65 3.70 11.80 10000 1000
2.48E+03 1.55 3.70 11.80
1.53E+03 0.49 3.70 11.80
1.74E+03 1.32 3.70 11.80
1.40E+03 0.61 3.70 11.80
1.05E+03 1.38 3.70 11.80
9.12E+02 0.86 3.70 11.80
4.00E+03 0.70 3.70 11.80
2.68E+03 0.36 3.70 11.80
2.30E+03 0.54 3.70 11.80 10000 1000
1.54E+03 0.57 3.70 11.80
2.24E+03 0.60 3.70 11.80
1.74E+03 0.96 3.70 11.80
1.38E+03 0.64 3.70 11.80
1.05E+03 0.14 3.70 11.80
8.94E+02 3.57 3.70 11.80
1.85E+00 16.14 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.51 E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.55E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.28E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-14
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Fe CFS-L01-1314-T01-A 1 3.08E+00 E
Fe CFS-L01-1314-T02-A 1 1.00E+00 U1/2
Fe CFS-L01-1314-T03-A 1 1.00E+00 U1/2
Fe CFS-L01-1314-T04-A 1 1.00E+00 U1/2
Fe CFS-L01-1314-T05-A 1 1.20E+01
Fe CFS-L01-1314-T06-A 1 7.75E+00
Fe CFS-L01-1314-T07-A 1 1.00E+00 U1/2
Fe CFS-L01-1314-T08-A 1 1.00E+00 U1/2
Fe CFS-L01-1314-T09-A 1 1.00E+00 U1/2
Fe CFS-L01-1314-T01-B 1 2.99E+00 E
Fe CFS-L01-1314-T02-B 1 1.00E+00 U1/2
Fe CFS-L01-1314-T03-B 1 8.09E+00
Fe CFS-L01-1314-T04-B 1 1.00E+00 U1/2
Fe CFS-L01-1314-T05-B 1 1.00E+00 U1/2
Fe CFS-L01-1314-T06-B 1 5.78E+00 E
Fe CFS-L01-1314-T07-B 1 6.33E+00 E
Fe CFS-L01-1314-T08-B 1 1.00E+00 U1/2
Fe CFS-L01-1314-T09-B 1 1.00E+00 U1/2
Fe CFS-L01-1314-T01-C 1 1.00E+00 U1/2
Fe CFS-L01-1314-T02-C 1 1.00E+00 U1/2
Fe CFS-L01-1314-T03-C 1 1.00E+00 U1/2
Fe CFS-L01-1314-T04-C 1 3.26E+00 E
Fe CFS-L01-1314-T05-C 1 1.00E+00 U1/2
Fe CFS-L01-1314-T06-C 1 1.97E+01
Fe CFS-L01-1314-T07-C 1 1.00E+00 U1/2
Fe CFS-L01-1314-T08-C 1 1.00E+00 U1/2
Fe CFS-L01-1314-T09-C 1 1.00E+00 U1/2
Fe CFS-L01-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.08E+00 4.47 2.00 6.40
1.00E+00 7.55 2.00 6.40
1.00E+00 5.52 2.00 6.40 10000 1000
1.00E+00 22.11 2.00 6.40
1.20E+01 2.49 2.00 6.40
7.75E+00 6.99 2.00 6.40
1.00E+00 20.50 2.00 6.40
1.00E+00 5.65 2.00 6.40
1.00E+00 11.73 2.00 6.40
2.99E+00 8.80 2.00 6.40
1.00E+00 5.76 2.00 6.40
8.09E+00 6.02 2.00 6.40 10000 1000
1.00E+00 9.76 2.00 6.40
1.00E+00 3.19 2.00 6.40
5.78E+00 3.86 2.00 6.40
6.33E+00 6.99 2.00 6.40
1.00E+00 18.22 2.00 6.40
1.00E+00 12.88 2.00 6.40
1.00E+00 3.62 2.00 6.40
1.00E+00 2.09 2.00 6.40
1.00E+00 2.53 2.00 6.40 10000 1000
3.26E+00 3.88 2.00 6.40
1.00E+00 30.51 2.00 6.40
1.97E+01 1.93 2.00 6.40
1.00E+00 7.28 2.00 6.40
1.00E+00 15.07 2.00 6.40
1.00E+00 8.66 2.00 6.40
1.00E+00 12.99 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.98E+02 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314 CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314CFS
10/6/11 3:55 PM EPA Interlab L01 1314CFS
10/6/11 4:00 PM EPA Interlab L01 1314CFS
10/6/11 4:05 PM EPA Interlab L01 1314CFS
10/6/113:12 PM EPA Interlab L01 1314CFS
1-15
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Pb CFS-L01-1314-T01-A 1 8.81E+02
Pb CFS-L01-1314-T02-A 1 8.41E+02
Pb CFS-L01-1314-T03-A 1 1.05E+03
Pb CFS-L01-1314-T04-A 1 1.14E+03
Pb CFS-L01-1314-T05-A 1 1.18E+03
Pb CFS-L01-1314-T06-A 1 1.12E+03
Pb CFS-L01-1314-T07-A 1 1.07E+03
Pb CFS-L01-1314-T08-A 1 9.46E+02
Pb CFS-L01-1314-T09-A 1 9.31E+02
Pb CFS-L01-1314-T01-B 1 9.39E+02
Pb CFS-L01-1314-T02-B 1 9.14E+02
Pb CFS-L01-1314-T03-B 1 1.07E+03
Pb CFS-L01-1314-T04-B 1 1.16E+03
Pb CFS-L01-1314-T05-B 1 8.91E+02
Pb CFS-L01-1314-T06-B 1 1.11E+03
Pb CFS-L01-1314-T07-B 1 1.09E+03
Pb CFS-L01-1314-T08-B 1 9.92E+02
Pb CFS-L01-1314-T09-B 1 9.91E+02
Pb CFS-L01-1314-T01-C 1 7.97E+02
Pb CFS-L01-1314-T02-C 1 8.36E+02
Pb CFS-L01-1314-T03-C 1 1.02E+03
Pb CFS-L01-1314-T04-C 1 8.79E+02
Pb CFS-L01-1314-T05-C 1 1.16E+03
Pb CFS-L01-1314-T06-C 1 1.11E+03
Pb CFS-L01-1314-T07-C 1 1.06E+03
Pb CFS-L01-1314-T08-C 1 9.80E+02
Pb CFS-L01-1314-T09-C 1 9.80E+02
Pb CFS-L01-1314-B01-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.81 E+02 1.04 6.80 21.60
8.41 E+02 0.94 6.80 21.60
1.05E+03 0.67 6.80 21.60 10000 1000
1.14E+03 0.30 6.80 21.60
1.18E+03 1.12 6.80 21.60
1.12E+03 1.16 6.80 21.60
1.07E+03 0.20 6.80 21.60
9.46E+02 1.49 6.80 21.60
9.31 E+02 0.53 6.80 21.60
9.39E+02 0.22 6.80 21.60
9.14E+02 0.29 6.80 21.60
1.07E+03 0.81 6.80 21.60 10000 1000
1.16E+03 0.99 6.80 21.60
8.91 E+02 0.77 6.80 21.60
1.11E+03 0.94 6.80 21.60
1.09E+03 0.43 6.80 21.60
9.92E+02 1.17 6.80 21.60
9.91E+02 0.14 6.80 21.60
7.97E+02 0.37 6.80 21.60
8.36E+02 0.74 6.80 21.60
1.02E+03 0.37 6.80 21.60 10000 1000
8.79E+02 1.20 6.80 21.60
1.16E+03 1.01 6.80 21.60
1.11E+03 0.79 6.80 21.60
1.06E+03 0.19 6.80 21.60
9.80E+02 0.92 6.80 21.60
9.80E+02 5.13 6.80 21.60
3.40E+00 32.93 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.04E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.07E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.96E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-16
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Li CFS-L01-1314-T01-A 1 4.11E+01
Li CFS-L01-1314-T02-A 1 2.51E+00 E
Li CFS-L01-1314-T03-A 1 6.27E+00
Li CFS-L01-1314-T04-A 1 8.65E+00
Li CFS-L01-1314-T05-A 1 7.85E+00
Li CFS-L01-1314-T06-A 1 9.94E+00
Li CFS-L01-1314-T07-A 1 6.16E+00
Li CFS-L01-1314-T08-A 1 9.38E+00
Li CFS-L01-1314-T09-A 1 8.85E+00
Li CFS-L01-1314-T01-B 1 5.32E+01
Li CFS-L01-1314-T02-B 1 2.57E+00 E
Li CFS-L01-1314-T03-B 1 6.99E+00
Li CFS-L01-1314-T04-B 1 5.73E+00 E
Li CFS-L01-1314-T05-B 1 8.92E+00
Li CFS-L01-1314-T06-B 1 1.03E+01
Li CFS-L01-1314-T07-B 1 8.09E+00
Li CFS-L01-1314-T08-B 1 9.01 E+00
Li CFS-L01-1314-T09-B 1 7.71E+00
Li CFS-L01-1314-T01-C 1 4.75E+01
Li CFS-L01-1314-T02-C 1 3.45E+00 E
Li CFS-L01-1314-T03-C 1 6.25E+00
Li CFS-L01-1314-T04-C 1 8.06E+00
Li CFS-L01-1314-T05-C 1 6.82E+00
Li CFS-L01-1314-T06-C 1 8.01 E+00
Li CFS-L01-1314-T07-C 1 8.15E+00
Li CFS-L01-1314-T08-C 1 9.29E+00
Li CFS-L01-1314-T09-C 1 7.55E+00
Li CFS-L01-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.11E+01 1.02 1.90 6.00
2.51 E+00 22.82 1.90 6.00
6.27E+00 7.61 1.90 6.00 10000 1000
8.65E+00 3.19 1.90 6.00
7.85E+00 2.96 1.90 6.00
9.94E+00 1.18 1.90 6.00
6.16E+00 9.87 1.90 6.00
9.38E+00 17.53 1.90 6.00
8.85E+00 2.12 1.90 6.00
5.32E+01 8.89 1.90 6.00
2.57E+00 18.69 1.90 6.00
6.99E+00 1.07 1.90 6.00 10000 1000
5.73E+00 38.44 1.90 6.00
8.92E+00 3.82 1.90 6.00
1.03E+01 8.25 1.90 6.00
8.09E+00 5.31 1.90 6.00
9.01 E+00 4.52 1.90 6.00
7.71E+00 2.61 1.90 6.00
4.75E+01 3.53 1.90 6.00
3.45E+00 27.12 1.90 6.00
6.25E+00 10.93 1.90 6.00 10000 1000
8.06E+00 6.50 1.90 6.00
6.82E+00 2.78 1.90 6.00
8.01 E+00 9.08 1.90 6.00
8.15E+00 2.42 1.90 6.00
9.29E+00 3.85 1.90 6.00
7.55E+00 2.65 1.90 6.00
9.50E-01 37.13 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.76E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.71 E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.74E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314 CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-17
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Mn CFS-L01-1314-T01-A 1 2.68E+04
Mn CFS-L01-1314-T02-A 1 1.18E+04
Mn CFS-L01-1314-T03-A 1 7.81 E+03
Mn CFS-L01-1314-T04-A 1 5.00E+03
Mn CFS-L01-1314-T05-A 1 2.85E+03
Mn CFS-L01-1314-T06-A 1 1.17E+03
Mn CFS-L01-1314-T07-A 1 6.27E+02
Mn CFS-L01-1314-T08-A 1 4.85E+02
Mn CFS-L01-1314-T09-A 1 3.94E+02
Mn CFS-L01-1314-T01-B 1 2.71E+04
Mn CFS-L01-1314-T02-B 1 1.16E+04
Mn CFS-L01-1314-T03-B 1 7.77E+03
Mn CFS-L01-1314-T04-B 1 5.42E+03
Mn CFS-L01-1314-T05-B 1 3.50E+03
Mn CFS-L01-1314-T06-B 1 1.26E+03
Mn CFS-L01-1314-T07-B 1 7.35E+02
Mn CFS-L01-1314-T08-B 1 5.63E+02
Mn CFS-L01-1314-T09-B 1 4.67E+02
Mn CFS-L01-1314-T01-C 1 2.58E+04
Mn CFS-L01-1314-T02-C 1 1.14E+04
Mn CFS-L01-1314-T03-C 1 7.75E+03
Mn CFS-L01-1314-T04-C 1 5.44E+03
Mn CFS-L01-1314-T05-C 1 3.53E+03
Mn CFS-L01-1314-T06-C 1 1.22E+03
Mn CFS-L01-1314-T07-C 1 7.39E+02
Mn CFS-L01-1314-T08-C 1 5.75E+02
Mn CFS-L01-1314-T09-C 1 4.84E+02
Mn CFS-L01-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.68E+04 1.15 2.00 6.40
1.18E+04 0.67 2.00 6.40
7.81E+03 0.78 2.00 6.40 10000 1000
5.00E+03 0.51 2.00 6.40
2.85E+03 1.56 2.00 6.40
1.17E+03 1.14 2.00 6.40
6.27E+02 1.20 2.00 6.40
4.85E+02 0.58 2.00 6.40
3.94E+02 2.27 2.00 6.40
2.71 E+04 0.49 2.00 6.40
1.16E+04 0.45 2.00 6.40
7.77E+03 0.51 2.00 6.40 10000 1000
5.42E+03 0.24 2.00 6.40
3.50E+03 1.35 2.00 6.40
1.26E+03 0.75 2.00 6.40
7.35E+02 0.64 2.00 6.40
5.63E+02 0.77 2.00 6.40
4.67E+02 1.33 2.00 6.40
2.58E+04 0.15 2.00 6.40
1.14E+04 0.20 2.00 6.40
7.75E+03 0.41 2.00 6.40 10000 1000
5.44E+03 0.88 2.00 6.40
3.53E+03 0.62 2.00 6.40
1.22E+03 0.98 2.00 6.40
7.39E+02 1.25 2.00 6.40
5.75E+02 0.43 2.00 6.40
4.84E+02 4.58 2.00 6.40
1.00E+00 7.51 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.80E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.69E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.71 E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314 CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314 CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-18
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Mg CFS-L01-1314-T01-A 1 2.19E+06
Mg CFS-L01-1314-T02-A 1 5.28E+05
Mg CFS-L01-1314-T03-A 1 1.65E+05
Mg CFS-L01-1314-T04-A 1 4.78E+04
Mg CFS-L01-1314-T05-A 1 2.53E+04
Mg CFS-L01-1314-T06-A 1 2.05E+04
Mg CFS-L01-1314-T07-A 1 1.28E+04
Mg CFS-L01-1314-T08-A 1 8.19E+03
Mg CFS-L01-1314-T09-A 1 5.29E+03
Mg CFS-L01-1314-T01-B 1 2.45E+06
Mg CFS-L01-1314-T02-B 1 5.47E+05
Mg CFS-L01-1314-T03-B 1 1.64E+05
Mg CFS-L01-1314-T04-B 1 5.21E+04
Mg CFS-L01-1314-T05-B 1 3.02E+04
Mg CFS-L01-1314-T06-B 1 2.02E+04
Mg CFS-L01-1314-T07-B 1 1.40E+04
Mg CFS-L01-1314-T08-B 1 9.07E+03
Mg CFS-L01-1314-T09-B 1 6.06E+03
Mg CFS-L01-1314-T01-C 1 2.42E+06
Mg CFS-L01-1314-T02-C 1 5.43E+05
Mg CFS-L01-1314-T03-C 1 1.65E+05
Mg CFS-L01-1314-T04-C 1 5.20E+04
Mg CFS-L01-1314-T05-C 1 3.09E+04
Mg CFS-L01-1314-T06-C 1 2.04E+04
Mg CFS-L01-1314-T07-C 1 1.44E+04
Mg CFS-L01-1314-T08-C 1 9.27E+03
Mg CFS-L01-1314-T09-C 1 6.05E+03
Mg CFS-L01-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.19E+06 0.72 1.00 3.18
5.28E+05 1.17 1.00 3.18
1.65E+05 1.01 1.00 3.18 10000 1000
4.78E+04 0.56 1.00 3.18
2.53E+04 1.15 1.00 3.18
2.05E+04 0.59 1.00 3.18
1.28E+04 0.91 1.00 3.18
8.19E+03 0.52 1.00 3.18
5.29E+03 0.88 1.00 3.18
2.45E+06 1.65 1.00 3.18
5.47E+05 0.59 1.00 3.18
1.64E+05 1.05 1.00 3.18 10000 1000
5.21E+04 0.38 1.00 3.18
3.02E+04 0.57 1.00 3.18
2.02E+04 0.78 1.00 3.18
1.40E+04 0.67 1.00 3.18
9.07E+03 1.25 1.00 3.18
6.06E+03 1.01 1.00 3.18
2.42E+06 1.09 1.00 3.18
5.43E+05 0.94 1.00 3.18
1.65E+05 0.27 1.00 3.18 10000 1000
5.20E+04 1.25 1.00 3.18
3.09E+04 0.25 1.00 3.18
2.04E+04 1.03 1.00 3.18
1.44E+04 0.45 1.00 3.18
9.27E+03 1.54 1.00 3.18
6.05E+03 5.57 1.00 3.18
5.00E-01 14.48 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.66E+05 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.65E+05 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.66E+05 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314 CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314 CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-19
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Mo CFS-L01-1314-T01-A 1 3.12E+01
Mo CFS-L01-1314-T02-A 1 1.30E+01
Mo CFS-L01-1314-T03-A 1 8.37E+00
Mo CFS-L01-1314-T04-A 1 8.66E+00
Mo CFS-L01-1314-T05-A 1 7.49E+00
Mo CFS-L01-1314-T06-A 1 7.54E+00
Mo CFS-L01-1314-T07-A 1 7.47E+00
Mo CFS-L01-1314-T08-A 1 8.29E+00
Mo CFS-L01-1314-T09-A 1 8.31 E+00
Mo CFS-L01-1314-T01-B 1 3.28E+01
Mo CFS-L01-1314-T02-B 1 1.33E+01
Mo CFS-L01-1314-T03-B 1 8.25E+00
Mo CFS-L01-1314-T04-B 1 7.63E+00
Mo CFS-L01-1314-T05-B 1 7.18E+00
Mo CFS-L01-1314-T06-B 1 6.06E+00
Mo CFS-L01-1314-T07-B 1 8.25E+00
Mo CFS-L01-1314-T08-B 1 8.56E+00
Mo CFS-L01-1314-T09-B 1 7.09E+00
Mo CFS-L01-1314-T01-C 1 3.08E+01
Mo CFS-L01-1314-T02-C 1 1.14E+01
Mo CFS-L01-1314-T03-C 1 9.23E+00
Mo CFS-L01-1314-T04-C 1 7.64E+00
Mo CFS-L01-1314-T05-C 1 8.50E+00
Mo CFS-L01-1314-T06-C 1 7.68E+00
Mo CFS-L01-1314-T07-C 1 8.52E+00
Mo CFS-L01-1314-T08-C 1 7.87E+00
Mo CFS-L01-1314-T09-C 1 7.69E+00
Mo CFS-L01-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.12E+01 2.33 1.20 3.82
1.30E+01 2.91 1.20 3.82
8.37E+00 10.51 1.20 3.82 10000 1000
8.66E+00 5.69 1.20 3.82
7.49E+00 7.64 1.20 3.82
7.54E+00 2.93 1.20 3.82
7.47E+00 1.83 1.20 3.82
8.29E+00 2.97 1.20 3.82
8.31 E+00 3.89 1.20 3.82
3.28E+01 7.46 1.20 3.82
1.33E+01 8.59 1.20 3.82
8.25E+00 14.87 1.20 3.82 10000 1000
7.63E+00 6.31 1.20 3.82
7.18E+00 1.93 1.20 3.82
6.06E+00 9.52 1.20 3.82
8.25E+00 1.64 1.20 3.82
8.56E+00 1.25 1.20 3.82
7.09E+00 1.82 1.20 3.82
3.08E+01 2.72 1.20 3.82
1.14E+01 8.78 1.20 3.82
9.23E+00 2.24 1.20 3.82 10000 1000
7.64E+00 1.50 1.20 3.82
8.50E+00 3.74 1.20 3.82
7.68E+00 9.05 1.20 3.82
8.52E+00 8.51 1.20 3.82
7.87E+00 6.72 1.20 3.82
7.69E+00 1.26 1.20 3.82
6.00E-01 16.79 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314 CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314 CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-20
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Ni CFS-L01-1314-T01-A 1 1.43E+03
Ni CFS-L01-1314-T02-A 1 7.77E+02
Ni CFS-L01-1314-T03-A 1 6.55E+02
Ni CFS-L01-1314-T04-A 1 5.91 E+02
Ni CFS-L01-1314-T05-A 1 5.18E+02
Ni CFS-L01-1314-T06-A 1 3.43E+02
Ni CFS-L01-1314-T07-A 1 2.09E+02
Ni CFS-L01-1314-T08-A 1 1.30E+02
Ni CFS-L01-1314-T09-A 1 9.41 E+01
Ni CFS-L01-1314-T01-B 1 1.47E+03
Ni CFS-L01-1314-T02-B 1 7.54E+02
Ni CFS-L01-1314-T03-B 1 6.32E+02
Ni CFS-L01-1314-T04-B 1 5.97E+02
Ni CFS-L01-1314-T05-B 1 5.42E+02
Ni CFS-L01-1314-T06-B 1 3.64E+02
Ni CFS-L01-1314-T07-B 1 2.20E+02
Ni CFS-L01-1314-T08-B 1 1.44E+02
Ni CFS-L01-1314-T09-B 1 1.07E+02
Ni CFS-L01-1314-T01-C 1 1.37E+03
Ni CFS-L01-1314-T02-C 1 7.21 E+02
Ni CFS-L01-1314-T03-C 1 6.17E+02
Ni CFS-L01-1314-T04-C 1 5.93E+02
Ni CFS-L01-1314-T05-C 1 5.43E+02
Ni CFS-L01-1314-T06-C 1 3.61E+02
Ni CFS-L01-1314-T07-C 1 2.24E+02
Ni CFS-L01-1314-T08-C 1 1.48E+02
Ni CFS-L01-1314-T09-C 1 1.10E+02
Ni CFS-L01-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.43E+03 0.62 1.80 5.70
7.77E+02 0.66 1.80 5.70
6.55E+02 0.57 1.80 5.70 10000 1000
5.91 E+02 0.98 1.80 5.70
5.18E+02 0.72 1.80 5.70
3.43E+02 0.43 1.80 5.70
2.09E+02 0.18 1.80 5.70
1.30E+02 1.36 1.80 5.70
9.41E+01 1.72 1.80 5.70
1.47E+03 1.01 1.80 5.70
7.54E+02 0.15 1.80 5.70
6.32E+02 0.90 1.80 5.70 10000 1000
5.97E+02 0.30 1.80 5.70
5.42E+02 0.40 1.80 5.70
3.64E+02 1.24 1.80 5.70
2.20E+02 1.06 1.80 5.70
1.44E+02 1.72 1.80 5.70
1.07E+02 1.58 1.80 5.70
1.37E+03 0.34 1.80 5.70
7.21E+02 0.88 1.80 5.70
6.17E+02 1.02 1.80 5.70 10000 1000
5.93E+02 1.12 1.80 5.70
5.43E+02 0.53 1.80 5.70
3.61 E+02 0.48 1.80 5.70
2.24E+02 0.25 1.80 5.70
1.48E+02 1.17 1.80 5.70
1.10E+02 6.28 1.80 5.70
9.00E-01 43.51 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.67E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.59E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.60E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314 CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314 CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-21
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
P CFS-L01-1314-T01-A 1 1.03E+02
P CFS-L01-1314-T02-A 1 6.42E+01
P CFS-L01-1314-T03-A 1 1.81E+01
P CFS-L01-1314-T04-A 1 4.69E+00 E
P CFS-L01-1314-T05-A 1 1.33E+02
P CFS-L01-1314-T06-A 1 9.95E+00 E
P CFS-L01-1314-T07-A 1 4.19E+00 E
P CFS-L01-1314-T08-A 1 1.85E+00 U1/2
P CFS-L01-1314-T09-A 1 5.38E+00 E
P CFS-L01-1314-T01-B 1 1.17E+02
P CFS-L01-1314-T02-B 1 2.20E+01
P CFS-L01-1314-T03-B 1 1.51E+01
P CFS-L01-1314-T04-B 1 9.50E+00 E
P CFS-L01-1314-T05-B 1 4.00E+01
P CFS-L01-1314-T06-B 1 1.85E+00 U1/2
P CFS-L01-1314-T07-B 1 1.05E+01 E
P CFS-L01-1314-T08-B 1 3.19E+01
P CFS-L01-1314-T09-B 1 1.85E+00 U1/2
P CFS-L01-1314-T01-C 1 9.55E+01
P CFS-L01-1314-T02-C 1 2.15E+01
P CFS-L01-1314-T03-C 1 6.06E+01
P CFS-L01-1314-T04-C 1 9.77E+01
P CFS-L01-1314-T05-C 1 1.18E+01
P CFS-L01-1314-T06-C 1 9.46E+00 E
P CFS-L01-1314-T07-C 1 1.85E+00 U1/2
P CFS-L01-1314-T08-C 1 1.40E+01
P CFS-L01-1314-T09-C 1 1.15E+01 E
P CFS-L01-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.03E+02 5.55 3.70 11.80
6.42E+01 7.44 3.70 11.80
1.81E+01 2.19 3.70 11.80 10000 1000
4.69E+00 26.24 3.70 11.80
1.33E+02 6.29 3.70 11.80
9.95E+00 5.86 3.70 11.80
4.19E+00 20.65 3.70 11.80
1.85E+00 40.55 3.70 11.80
5.38E+00 33.01 3.70 11.80
1.17E+02 2.53 3.70 11.80
2.20E+01 1.02 3.70 11.80
1.51E+01 6.40 3.70 11.80 10000 1000
9.50E+00 33.68 3.70 11.80
4.00E+01 3.30 3.70 11.80
1.85E+00 16.19 3.70 11.80
1.05E+01 20.21 3.70 11.80
3.19E+01 2.35 3.70 11.80
1.85E+00 48.73 3.70 11.80
9.55E+01 5.69 3.70 11.80
2.15E+01 3.81 3.70 11.80
6.06E+01 13.72 3.70 11.80 10000 1000
9.77E+01 1.58 3.70 11.80
1.18E+01 2.07 3.70 11.80
9.46E+00 23.14 3.70 11.80
1.85E+00 47.95 3.70 11.80
1.40E+01 2.04 3.70 11.80
1.15E+01 17.78 3.70 11.80
1.85E+00 53.52 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.09E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.11E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314 CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314 CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-22
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
K CFS-L01-1314-T01-A 1 1.45E+05
K CFS-L01-1314-T02-A 1 5.76E+04
K CFS-L01-1314-T03-A 1 3.33E+04
K CFS-L01-1314-T04-A 1 2.23E+04
K CFS-L01-1314-T05-A 1 1.53E+04
K CFS-L01-1314-T06-A 1 8.21E+03
K CFS-L01-1314-T07-A 1 4.75E+03
K CFS-L01-1314-T08-A 1 3.04E+03
K CFS-L01-1314-T09-A 1 2.17E+03
K CFS-L01-1314-T01-B 1 1.55E+05
K CFS-L01-1314-T02-B 1 5.94E+04
K CFS-L01-1314-T03-B 1 3.48E+04
K CFS-L01-1314-T04-B 1 2.43E+04
K CFS-L01-1314-T05-B 1 1.74E+04
K CFS-L01-1314-T06-B 1 8.80E+03
K CFS-L01-1314-T07-B 1 5.03E+03
K CFS-L01-1314-T08-B 1 3.24E+03
K CFS-L01-1314-T09-B 1 2.44E+03
K CFS-L01-1314-T01-C 1 1.55E+05
K CFS-L01-1314-T02-C 1 5.87E+04
K CFS-L01-1314-T03-C 1 3.49E+04
K CFS-L01-1314-T04-C 1 2.42E+04
K CFS-L01-1314-T05-C 1 1.75E+04
K CFS-L01-1314-T06-C 1 8.68E+03
K CFS-L01-1314-T07-C 1 5.07E+03
K CFS-L01-1314-T08-C 1 3.25E+03
K CFS-L01-1314-T09-C 1 2.46E+03
K CFS-L01-1314-B01-A 1 8.06E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.45E+05 0.89 1.60 5.09
5.76E+04 0.20 1.60 5.09
3.33E+04 0.64 1.60 5.09 10000 1000
2.23E+04 0.19 1.60 5.09
1.53E+04 0.98 1.60 5.09
8.21 E+03 0.62 1.60 5.09
4.75E+03 0.61 1.60 5.09
3.04E+03 0.20 1.60 5.09
2.17E+03 0.88 1.60 5.09
1.55E+05 0.90 1.60 5.09
5.94E+04 0.32 1.60 5.09
3.48E+04 0.75 1.60 5.09 10000 1000
2.43E+04 0.93 1.60 5.09
1.74E+04 0.40 1.60 5.09
8.80E+03 0.97 1.60 5.09
5.03E+03 0.45 1.60 5.09
3.24E+03 0.55 1.60 5.09
2.44E+03 0.59 1.60 5.09
1.55E+05 0.11 1.60 5.09
5.87E+04 0.99 1.60 5.09
3.49E+04 0.26 1.60 5.09 10000 1000
2.42E+04 1.46 1.60 5.09
1.75E+04 0.12 1.60 5.09
8.68E+03 0.36 1.60 5.09
5.07E+03 0.07 1.60 5.09
3.25E+03 0.28 1.60 5.09
2.46E+03 5.28 1.60 5.09
8.06E+00 2.96 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.42E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.57E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.59E+04 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314 CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314 CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-23
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Se CFS-L01-1314-T01-A 1 2.05E+03
Se CFS-L01-1314-T02-A 1 4.06E+02
Se CFS-L01-1314-T03-A 1 1.35E+02
Se CFS-L01-1314-T04-A 1 5.91E+01
Se CFS-L01-1314-T05-A 1 4.70E+01 E
Se CFS-L01-1314-T06-A 1 3.95E+01 E
Se CFS-L01-1314-T07-A 1 2.39E+01 E
Se CFS-L01-1314-T08-A 1 1.68E+01 E
Se CFS-L01-1314-T09-A 1 2.25E+01 E
Se CFS-L01-1314-T01-B 1 2.26E+03
Se CFS-L01-1314-T02-B 1 4.02E+02
Se CFS-L01-1314-T03-B 1 1.46E+02
Se CFS-L01-1314-T04-B 1 7.41E+01
Se CFS-L01-1314-T05-B 1 4.70E+01 E
Se CFS-L01-1314-T06-B 1 2.38E+01 E
Se CFS-L01-1314-T07-B 1 2.05E+01 E
Se CFS-L01-1314-T08-B 1 1.90E+01 E
Se CFS-L01-1314-T09-B 1 2.97E+01 E
Se CFS-L01-1314-T01-C 1 2.23E+03
Se CFS-L01-1314-T02-C 1 3.87E+02
Se CFS-L01-1314-T03-C 1 1.27E+02
Se CFS-L01-1314-T04-C 1 6.89E+01
Se CFS-L01-1314-T05-C 1 3.65E+01 E
Se CFS-L01-1314-T06-C 1 3.39E+01 E
Se CFS-L01-1314-T07-C 1 3.73E+01 E
Se CFS-L01-1314-T08-C 1 3.43E+01 E
Se CFS-L01-1314-T09-C 1 3.67E+01 E
Se CFS-L01-1314-B01-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.05E+03 1.61 15.00 47.70
4.06E+02 1.83 15.00 47.70
1.35E+02 4.22 15.00 47.70 10000 1000
5.91E+01 1.27 15.00 47.70
4.70E+01 21.60 15.00 47.70
3.95E+01 23.24 15.00 47.70
2.39E+01 10.98 15.00 47.70
1.68E+01 17.07 15.00 47.70
2.25E+01 25.02 15.00 47.70
2.26E+03 0.85 15.00 47.70
4.02E+02 2.58 15.00 47.70
1.46E+02 7.35 15.00 47.70 10000 1000
7.41E+01 5.41 15.00 47.70
4.70E+01 3.80 15.00 47.70
2.38E+01 21.29 15.00 47.70
2.05E+01 14.02 15.00 47.70
1.90E+01 29.31 15.00 47.70
2.97E+01 6.71 15.00 47.70
2.23E+03 1.79 15.00 47.70
3.87E+02 2.69 15.00 47.70
1.27E+02 1.97 15.00 47.70 10000 1000
6.89E+01 14.73 15.00 47.70
3.65E+01 9.13 15.00 47.70
3.39E+01 15.64 15.00 47.70
3.73E+01 6.83 15.00 47.70
3.43E+01 12.88 15.00 47.70
3.67E+01 24.04 15.00 47.70
7.50E+00 46.35 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.13E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314 CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314 CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-24
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Si CFS-L01-1314-T01-A 1 8.98E+03
Si CFS-L01-1314-T02-A 1 7.93E+03
Si CFS-L01-1314-T03-A 1 7.68E+03
Si CFS-L01-1314-T04-A 1 7.21E+03
Si CFS-L01-1314-T05-A 1 7.02E+03
Si CFS-L01-1314-T06-A 1 6.25E+03
Si CFS-L01-1314-T07-A 1 5.71E+03
Si CFS-L01-1314-T08-A 1 5.07E+03
Si CFS-L01-1314-T09-A 1 4.72E+03
Si CFS-L01-1314-T01-B 1 8.89E+03
Si CFS-L01-1314-T02-B 1 7.97E+03
Si CFS-L01-1314-T03-B 1 7.62E+03
Si CFS-L01-1314-T04-B 1 7.35E+03
Si CFS-L01-1314-T05-B 1 7.00E+03
Si CFS-L01-1314-T06-B 1 6.31 E+03
Si CFS-L01-1314-T07-B 1 5.83E+03
Si CFS-L01-1314-T08-B 1 5.24E+03
Si CFS-L01-1314-T09-B 1 5.05E+03
Si CFS-L01-1314-T01-C 1 8.63E+03
Si CFS-L01-1314-T02-C 1 7.86E+03
Si CFS-L01-1314-T03-C 1 7.51 E+03
Si CFS-L01-1314-T04-C 1 7.22E+03
Si CFS-L01-1314-T05-C 1 7.06E+03
Si CFS-L01-1314-T06-C 1 6.35E+03
Si CFS-L01-1314-T07-C 1 5.80E+03
Si CFS-L01-1314-T08-C 1 5.28E+03
Si CFS-L01-1314-T09-C 1 5.09E+03
Si CFS-L01-1314-B01-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.98E+03 0.61 1.10 3.50
7.93E+03 0.51 1.10 3.50
7.68E+03 0.60 1.10 3.50 10000 1000
7.21E+03 0.47 1.10 3.50
7.02E+03 2.28 1.10 3.50
6.25E+03 0.54 1.10 3.50
5.71E+03 1.48 1.10 3.50
5.07E+03 0.64 1.10 3.50
4.72E+03 0.91 1.10 3.50
8.89E+03 0.12 1.10 3.50
7.97E+03 0.14 1.10 3.50
7.62E+03 0.30 1.10 3.50 10000 1000
7.35E+03 0.65 1.10 3.50
7.00E+03 0.84 1.10 3.50
6.31E+03 1.37 1.10 3.50
5.83E+03 0.64 1.10 3.50
5.24E+03 0.85 1.10 3.50
5.05E+03 0.91 1.10 3.50
8.63E+03 0.56 1.10 3.50
7.86E+03 0.47 1.10 3.50
7.51E+03 0.71 1.10 3.50 10000 1000
7.22E+03 1.12 1.10 3.50
7.06E+03 0.83 1.10 3.50
6.35E+03 0.86 1.10 3.50
5.80E+03 0.55 1.10 3.50
5.28E+03 1.33 1.10 3.50
5.09E+03 3.60 1.10 3.50
5.50E-01 19.51 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.60E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.58E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.45E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314 CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314 CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-25
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Na CFS-L01-1314-T01-A 1 3.09E+05
Na CFS-L01-1314-T02-A 1 8.65E+04
Na CFS-L01-1314-T03-A 1 1.43E+04
Na CFS-L01-1314-T04-A 1 5.52E+03
Na CFS-L01-1314-T05-A 1 3.32E+03
Na CFS-L01-1314-T06-A 1 2.28E+03
Na CFS-L01-1314-T07-A 1 1.50E+03
Na CFS-L01-1314-T08-A 1 1.13E+03
Na CFS-L01-1314-T09-A 1 9.08E+02
Na CFS-L01-1314-T01-B 1 3.21E+05
Na CFS-L01-1314-T02-B 1 8.11E+04
Na CFS-L01-1314-T03-B 1 1.37E+04
Na CFS-L01-1314-T04-B 1 5.97E+03
Na CFS-L01-1314-T05-B 1 3.95E+03
Na CFS-L01-1314-T06-B 1 2.29E+03
Na CFS-L01-1314-T07-B 1 1.53E+03
Na CFS-L01-1314-T08-B 1 1.18E+03
Na CFS-L01-1314-T09-B 1 9.74E+02
Na CFS-L01-1314-T01-C 1 3.19E+05
Na CFS-L01-1314-T02-C 1 7.58E+04
Na CFS-L01-1314-T03-C 1 1.33E+04
Na CFS-L01-1314-T04-C 1 5.92E+03
Na CFS-L01-1314-T05-C 1 3.82E+03
Na CFS-L01-1314-T06-C 1 2.23E+03
Na CFS-L01-1314-T07-C 1 1.57E+03
Na CFS-L01-1314-T08-C 1 1.21E+03
Na CFS-L01-1314-T09-C 1 9.78E+02
Na CFS-L01-1314-B01-A 1 1.25E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.09E+05 0.30 2.50 8.00
8.65E+04 0.29 2.50 8.00
1.43E+04 1.25 2.50 8.00 10000 1000
5.52E+03 0.67 2.50 8.00
3.32E+03 1.37 2.50 8.00
2.28E+03 0.41 2.50 8.00
1.50E+03 0.44 2.50 8.00
1.13E+03 0.87 2.50 8.00
9.08E+02 0.96 2.50 8.00
3.21 E+05 0.36 2.50 8.00
8.11E+04 0.37 2.50 8.00
1.37E+04 0.92 2.50 8.00 10000 1000
5.97E+03 1.03 2.50 8.00
3.95E+03 1.16 2.50 8.00
2.29E+03 0.53 2.50 8.00
1.53E+03 0.11 2.50 8.00
1.18E+03 0.44 2.50 8.00
9.74E+02 1.23 2.50 8.00
3.19E+05 0.60 2.50 8.00
7.58E+04 0.44 2.50 8.00
1.33E+04 0.93 2.50 8.00 10000 1000
5.92E+03 0.53 2.50 8.00
3.82E+03 0.06 2.50 8.00
2.23E+03 0.35 2.50 8.00
1.57E+03 0.48 2.50 8.00
1.21E+03 0.61 2.50 8.00
9.78E+02 1.78 2.50 8.00
1.25E+00 1.98 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.52E+04 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.46E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.42E+04 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314 CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314 CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-26
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Sr CFS-L01-1314-T01-A 1 4.38E+03
Sr CFS-L01-1314-T02-A 1 3.42E+03
Sr CFS-L01-1314-T03-A 1 3.32E+03
Sr CFS-L01-1314-T04-A 1 3.01 E+03
Sr CFS-L01-1314-T05-A 1 2.66E+03
Sr CFS-L01-1314-T06-A 1 2. 11 E+03
Sr CFS-L01-1314-T07-A 1 1.80E+03
Sr CFS-L01-1314-T08-A 1 1.58E+03
Sr CFS-L01-1314-T09-A 1 1.45E+03
Sr CFS-L01-1314-T01-B 1 4.53E+03
Sr CFS-L01-1314-T02-B 1 3.53E+03
Sr CFS-L01-1314-T03-B 1 3.50E+03
Sr CFS-L01-1314-T04-B 1 3.28E+03
Sr CFS-L01-1314-T05-B 1 2.90E+03
Sr CFS-L01-1314-T06-B 1 2.15E+03
Sr CFS-L01-1314-T07-B 1 1.87E+03
Sr CFS-L01-1314-T08-B 1 1.63E+03
Sr CFS-L01-1314-T09-B 1 1.55E+03
Sr CFS-L01-1314-T01-C 1 4.61 E+03
Sr CFS-L01-1314-T02-C 1 3.57E+03
Sr CFS-L01-1314-T03-C 1 3.55E+03
Sr CFS-L01-1314-T04-C 1 3.36E+03
Sr CFS-L01-1314-T05-C 1 2.94E+03
Sr CFS-L01-1314-T06-C 1 2.14E+03
Sr CFS-L01-1314-T07-C 1 1.86E+03
Sr CFS-L01-1314-T08-C 1 1.64E+03
Sr CFS-L01-1314-T09-C 1 1.56E+03
Sr CFS-L01-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.38E+03 0.44 1.00 3.18
3.42E+03 1.78 1.00 3.18
3.32E+03 1.00 1.00 3.18 10000 1000
3.01E+03 0.64 1.00 3.18
2.66E+03 2.43 1.00 3.18
2.11E+03 1.11 1.00 3.18
1.80E+03 1.19 1.00 3.18
1.58E+03 0.71 1.00 3.18
1.45E+03 0.78 1.00 3.18
4.53E+03 1.55 1.00 3.18
3.53E+03 0.89 1.00 3.18
3.50E+03 0.64 1.00 3.18 10000 1000
3.28E+03 0.76 1.00 3.18
2.90E+03 0.74 1.00 3.18
2.15E+03 1.12 1.00 3.18
1.87E+03 0.62 1.00 3.18
1.63E+03 1.04 1.00 3.18
1.55E+03 0.85 1.00 3.18
4.61E+03 0.31 1.00 3.18
3.57E+03 0.24 1.00 3.18
3.55E+03 0.39 1.00 3.18 10000 1000
3.36E+03 0.48 1.00 3.18
2.94E+03 0.86 1.00 3.18
2.14E+03 1.18 1.00 3.18
1.86E+03 0.50 1.00 3.18
1.64E+03 1.02 1.00 3.18
1.56E+03 3.42 1.00 3.18
5.00E-01 30.90 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.19E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.41 E+03 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.52E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314 CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314 CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-27
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
S CFS-L01-1314-T01-A 1 2.45E+06
S CFS-L01-1314-T02-A 1 1.09E+06
S CFS-L01-1314-T03-A 1 7.05E+05
S CFS-L01-1314-T04-A 1 5.79E+05
S CFS-L01-1314-T05-A 1 5.63E+05
S CFS-L01-1314-T06-A 1 5.45E+05
S CFS-L01-1314-T07-A 1 5.35E+05
S CFS-L01-1314-T08-A 1 5.22E+05
S CFS-L01-1314-T09-A 1 5.14E+05
S CFS-L01-1314-T01-B 1 2.59E+06
S CFS-L01-1314-T02-B 1 1.11E+06
S CFS-L01-1314-T03-B 1 6.98E+05
S CFS-L01-1314-T04-B 1 5.89E+05
S CFS-L01-1314-T05-B 1 5.54E+05
S CFS-L01-1314-T06-B 1 5.45E+05
S CFS-L01-1314-T07-B 1 5.36E+05
S CFS-L01-1314-T08-B 1 5.24E+05
S CFS-L01-1314-T09-B 1 5.28E+05
S CFS-L01-1314-T01-C 1 2.58E+06
S CFS-L01-1314-T02-C 1 1.09E+06
S CFS-L01-1314-T03-C 1 6.99E+05
S CFS-L01-1314-T04-C 1 5.90E+05
S CFS-L01-1314-T05-C 1 5.63E+05
S CFS-L01-1314-T06-C 1 5.45E+05
S CFS-L01-1314-T07-C 1 5.36E+05
S CFS-L01-1314-T08-C 1 5.24E+05
S CFS-L01-1314-T09-C 1 5.34E+05
S CFS-L01-1314-B01-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.45E+06 0.48 6.80 21.60
1.09E+06 0.59 6.80 21.60
7.05E+05 0.51 6.80 21.60 10000 1000
5.79E+05 0.18 6.80 21.60
5.63E+05 0.90 6.80 21.60
5.45E+05 0.67 6.80 21.60
5.35E+05 0.34 6.80 21.60
5.22E+05 0.30 6.80 21.60
5.14E+05 0.92 6.80 21.60
2.59E+06 0.60 6.80 21.60
1.11E+06 0.16 6.80 21.60
6.98E+05 0.34 6.80 21.60 10000 1000
5.89E+05 0.95 6.80 21.60
5.54E+05 0.45 6.80 21.60
5.45E+05 0.83 6.80 21.60
5.36E+05 0.22 6.80 21.60
5.24E+05 0.26 6.80 21.60
5.28E+05 0.40 6.80 21.60
2.58E+06 0.42 6.80 21.60
1.09E+06 0.72 6.80 21.60
6.99E+05 0.63 6.80 21.60 10000 1000
5.90E+05 0.87 6.80 21.60
5.63E+05 0.08 6.80 21.60
5.45E+05 0.45 6.80 21.60
5.36E+05 0.34 6.80 21.60
5.24E+05 0.50 6.80 21.60
5.34E+05 5.02 6.80 21.60
3.40E+00 1.23 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
7.06E+05 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.99E+05 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.00E+05 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-28
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Tl CFS-L01-1314-T01-A 1 2.26E+03
Tl CFS-L01-1314-T02-A 1 1.11E+03
Tl CFS-L01-1314-T03-A 1 7.46E+02
Tl CFS-L01-1314-T04-A 1 5.39E+02
Tl CFS-L01-1314-T05-A 1 4.16E+02
Tl CFS-L01-1314-T06-A 1 2.74E+02
Tl CFS-L01-1314-T07-A 1 1.89E+02
Tl CFS-L01-1314-T08-A 1 1.42E+02
Tl CFS-L01-1314-T09-A 1 1.24E+02
Tl CFS-L01-1314-T01-B 1 2.40E+03
Tl CFS-L01-1314-T02-B 1 1.14E+03
Tl CFS-L01-1314-T03-B 1 7.64E+02
Tl CFS-L01-1314-T04-B 1 5.87E+02
Tl CFS-L01-1314-T05-B 1 4.64E+02
Tl CFS-L01-1314-T06-B 1 2.88E+02
Tl CFS-L01-1314-T07-B 1 2.06E+02
Tl CFS-L01-1314-T08-B 1 1.55E+02
Tl CFS-L01-1314-T09-B 1 1.34E+02
Tl CFS-L01-1314-T01-C 1 2.41E+03
Tl CFS-L01-1314-T02-C 1 1.12E+03
Tl CFS-L01-1314-T03-C 1 7.73E+02
Tl CFS-L01-1314-T04-C 1 5.85E+02
Tl CFS-L01-1314-T05-C 1 4.67E+02
Tl CFS-L01-1314-T06-C 1 2.81E+02
Tl CFS-L01-1314-T07-C 1 2.00E+02
Tl CFS-L01-1314-T08-C 1 1.52E+02
Tl CFS-L01-1314-T09-C 1 1.34E+02
Tl CFS-L01-1314-B01-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.26E+03 0.43 4.60 14.60
1.11E+03 0.58 4.60 14.60
7.46E+02 0.43 4.60 14.60 10000 1000
5.39E+02 1.07 4.60 14.60
4.16E+02 0.75 4.60 14.60
2.74E+02 0.23 4.60 14.60
1.89E+02 0.94 4.60 14.60
1.42E+02 1.67 4.60 14.60
1.24E+02 3.51 4.60 14.60
2.40E+03 0.67 4.60 14.60
1.14E+03 1.04 4.60 14.60
7.64E+02 0.56 4.60 14.60 10000 1000
5.87E+02 0.52 4.60 14.60
4.64E+02 0.52 4.60 14.60
2.88E+02 0.56 4.60 14.60
2.06E+02 2.72 4.60 14.60
1.55E+02 2.08 4.60 14.60
1.34E+02 2.70 4.60 14.60
2.41E+03 0.73 4.60 14.60
1.12E+03 0.37 4.60 14.60
7.73E+02 0.01 4.60 14.60 10000 1000
5.85E+02 1.58 4.60 14.60
4.67E+02 0.25 4.60 14.60
2.81E+02 1.00 4.60 14.60
2.00E+02 2.14 4.60 14.60
1.52E+02 0.75 4.60 14.60
1.34E+02 5.77 4.60 14.60
2.30E+00 29.67 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.75E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.75E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.74E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314 CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-29
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L I
Ti CFS-L01-1314-T01-A 1 1.00E+00 U1/2
Ti CFS-L01-1314-T02-A 1 1.00E+00 U1/2
Ti CFS-L01-1314-T03-A 1 1.00E+00 U1/2
Ti CFS-L01-1314-T04-A 1 1.00E+00 U1/2
Ti CFS-L01-1314-T05-A 1 1.00E+00 U1/2
Ti CFS-L01-1314-T06-A 1 1.00E+00 U1/2
Ti CFS-L01-1314-T07-A 1 1.00E+00 U1/2
Ti CFS-L01-1314-T08-A 1 1.00E+00 U1/2
Ti CFS-L01-1314-T09-A 1 1.00E+00 U1/2
Ti CFS-L01-1314-T01-B 1 1.00E+00 U1/2
Ti CFS-L01-1314-T02-B 1 1.00E+00 U1/2
Ti CFS-L01-1314-T03-B 1 1.00E+00 U1/2
Ti CFS-L01-1314-T04-B 1 1.00E+00 U1/2
Ti CFS-L01-1314-T05-B 1 1.00E+00 U1/2
Ti CFS-L01-1314-T06-B 1 1.00E+00 U1/2
Ti CFS-L01-1314-T07-B 1 1.00E+00 U1/2
Ti CFS-L01-1314-T08-B 1 1.00E+00 U1/2
Ti CFS-L01-1314-T09-B 1 1.00E+00 U1/2
Ti CFS-L01-1314-T01-C 1 1.00E+00 U1/2
Ti CFS-L01-1314-T02-C 1 1.00E+00 U1/2
Ti CFS-L01-1314-T03-C 1 1.00E+00 U1/2
Ti CFS-L01-1314-T04-C 1 1.00E+00 U1/2
Ti CFS-L01-1314-T05-C 1 1.00E+00 U1/2
Ti CFS-L01-1314-T06-C 1 1.00E+00 U1/2
Ti CFS-L01-1314-T07-C 1 1.00E+00 U1/2
Ti CFS-L01-1314-T08-C 1 1.00E+00 U1/2
Ti CFS-L01-1314-T09-C 1 1.00E+00 U1/2
Ti CFS-L01-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 11.87 2.00 6.40
1.00E+00 25.42 2.00 6.40
1.00E+00 41.86 2.00 6.40 10000 1000
1.00E+00 45.99 2.00 6.40
1.00E+00 20.25 2.00 6.40
1.00E+00 75.70 2.00 6.40
1.00E+00 15.34 2.00 6.40
1.00E+00 6.78 2.00 6.40
1.00E+00 55.42 2.00 6.40
1.00E+00 46.27 2.00 6.40
1.00E+00 67.50 2.00 6.40
1.00E+00 60.14 2.00 6.40 10000 1000
1.00E+00 38.75 2.00 6.40
1.00E+00 23.73 2.00 6.40
1.00E+00 50.37 2.00 6.40
1.00E+00 46.56 2.00 6.40
1.00E+00 77.12 2.00 6.40
1.00E+00 39.43 2.00 6.40
1.00E+00 55.28 2.00 6.40
1.00E+00 36.40 2.00 6.40
1.00E+00 34.26 2.00 6.40 10000 1000
1.00E+00 29.62 2.00 6.40
1.00E+00 36.82 2.00 6.40
1.00E+00 54.16 2.00 6.40
1.00E+00 42.91 2.00 6.40
1.00E+00 17.22 2.00 6.40
1.00E+00 50.75 2.00 6.40
1.00E+00 24.89 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314 CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314 CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-30
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
V CFS-L01-1314-T01-A 1 2.62E+01
V CFS-L01-1314-T02-A 1 2.88E+01
V CFS-L01-1314-T03-A 1 3.13E+01
V CFS-L01-1314-T04-A 1 3.44E+01
V CFS-L01-1314-T05-A 1 3.57E+01
V CFS-L01-1314-T06-A 1 3.45E+01
V CFS-L01-1314-T07-A 1 3.54E+01
V CFS-L01-1314-T08-A 1 3.50E+01
V CFS-L01-1314-T09-A 1 3.55E+01
V CFS-L01-1314-T01-B 1 2.48E+01
V CFS-L01-1314-T02-B 1 2.90E+01
V CFS-L01-1314-T03-B 1 3.16E+01
V CFS-L01-1314-T04-B 1 3.34E+01
V CFS-L01-1314-T05-B 1 3.43E+01
V CFS-L01-1314-T06-B 1 3.42E+01
V CFS-L01-1314-T07-B 1 3.55E+01
V CFS-L01-1314-T08-B 1 3.48E+01
V CFS-L01-1314-T09-B 1 3.56E+01
V CFS-L01-1314-T01-C 1 2.64E+01
V CFS-L01-1314-T02-C 1 2.86E+01
V CFS-L01-1314-T03-C 1 3.15E+01
V CFS-L01-1314-T04-C 1 3.44E+01
V CFS-L01-1314-T05-C 1 3.40E+01
V CFS-L01-1314-T06-C 1 3.35E+01
V CFS-L01-1314-T07-C 1 3.41E+01
V CFS-L01-1314-T08-C 1 3.46E+01
V CFS-L01-1314-T09-C 1 3.67E+01
V CFS-L01-1314-B01-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.62E+01 7.37 1.50 4.77
2.88E+01 2.06 1.50 4.77
3.13E+01 0.82 1.50 4.77 10000 1000
3.44E+01 3.66 1.50 4.77
3.57E+01 2.32 1.50 4.77
3.45E+01 1.38 1.50 4.77
3.54E+01 2.97 1.50 4.77
3.50E+01 1.36 1.50 4.77
3.55E+01 2.36 1.50 4.77
2.48E+01 9.60 1.50 4.77
2.90E+01 1.92 1.50 4.77
3.16E+01 1.41 1.50 4.77 10000 1000
3.34E+01 1.21 1.50 4.77
3.43E+01 1.53 1.50 4.77
3.42E+01 0.34 1.50 4.77
3.55E+01 4.11 1.50 4.77
3.48E+01 3.05 1.50 4.77
3.56E+01 0.45 1.50 4.77
2.64E+01 2.02 1.50 4.77
2.86E+01 1.88 1.50 4.77
3.15E+01 4.54 1.50 4.77 10000 1000
3.44E+01 1.06 1.50 4.77
3.40E+01 2.26 1.50 4.77
3.35E+01 2.92 1.50 4.77
3.41 E+01 0.48 1.50 4.77
3.46E+01 4.07 1.50 4.77
3.67E+01 7.39 1.50 4.77
7.50E-01 44.00 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314 CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314 CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-31
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Zn CFS-L01-1314-T01-A 1 9.21E+04
Zn CFS-L01-1314-T02-A 1 6.21E+04
Zn CFS-L01-1314-T03-A 1 5.69E+04
Zn CFS-L01-1314-T04-A 1 5.40E+04
Zn CFS-L01-1314-T05-A 1 5.12E+04
Zn CFS-L01-1314-T06-A 1 3.96E+04
Zn CFS-L01-1314-T07-A 1 2.95E+04
Zn CFS-L01-1314-T08-A 1 2.07E+04
Zn CFS-L01-1314-T09-A 1 1.64E+04
Zn CFS-L01-1314-T01-B 1 9.42E+04
Zn CFS-L01-1314-T02-B 1 6.10E+04
Zn CFS-L01-1314-T03-B 1 5.51 E+04
Zn CFS-L01-1314-T04-B 1 5.38E+04
Zn CFS-L01-1314-T05-B 1 5.08E+04
Zn CFS-L01-1314-T06-B 1 4.03E+04
Zn CFS-L01-1314-T07-B 1 3.06E+04
Zn CFS-L01-1314-T08-B 1 2.21E+04
Zn CFS-L01-1314-T09-B 1 1.83E+04
Zn CFS-L01-1314-T01-C 1 8.96E+04
Zn CFS-L01-1314-T02-C 1 5.80E+04
Zn CFS-L01-1314-T03-C 1 5.31 E+04
Zn CFS-L01-1314-T04-C 1 5.23E+04
Zn CFS-L01-1314-T05-C 1 5.07E+04
Zn CFS-L01-1314-T06-C 1 3.97E+04
Zn CFS-L01-1314-T07-C 1 3.04E+04
Zn CFS-L01-1314-T08-C 1 2.22E+04
Zn CFS-L01-1314-T09-C 1 1.87E+04
Zn CFS-L01-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.21E+04 0.56 1.00 3.18
6.21 E+04 0.92 1.00 3.18
5.69E+04 1.65 1.00 3.18 10000 1000
5.40E+04 0.76 1.00 3.18
5.12E+04 1.36 1.00 3.18
3.96E+04 0.19 1.00 3.18
2.95E+04 0.36 1.00 3.18
2.07E+04 0.87 1.00 3.18
1.64E+04 0.87 1.00 3.18
9.42E+04 1.42 1.00 3.18
6.10E+04 1.05 1.00 3.18
5.51E+04 0.77 1.00 3.18 10000 1000
5.38E+04 0.87 1.00 3.18
5.08E+04 0.89 1.00 3.18
4.03E+04 1.48 1.00 3.18
3.06E+04 0.60 1.00 3.18
2.21E+04 1.46 1.00 3.18
1.83E+04 1.80 1.00 3.18
8.96E+04 0.57 1.00 3.18
5.80E+04 0.76 1.00 3.18
5.31E+04 0.95 1.00 3.18 10000 1000
5.23E+04 0.86 1.00 3.18
5.07E+04 0.08 1.00 3.18
3.97E+04 1.10 1.00 3.18
3.04E+04 0.66 1.00 3.18
2.22E+04 0.71 1.00 3.18
1.87E+04 4.38 1.00 3.18
5.00E-01 4.30 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.78E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.60E+04 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.41 E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 3:17 PM EPA Interlab L01 1314 CFS
10/6/11 3:22 PM EPA Interlab L01 1314 CFS
10/6/11 3:27 PM EPA Interlab L01 1314 CFS
10/6/11 3:37 PM EPA Interlab L01 1314 CFS
10/6/11 3:42 PM EPA Interlab L01 1314 CFS
10/6/11 3:47 PM EPA Interlab L01 1314 CFS
10/6/11 3:52 PM EPA Interlab L01 1314 CFS
10/6/11 3:57 PM EPA Interlab L01 1314 CFS
10/6/11 4:02 PM EPA Interlab L01 1314 CFS
10/6/11 3:19 PM EPA Interlab L01 1314 CFS
10/6/11 3:24 PM EPA Interlab L01 1314 CFS
10/6/11 3:29 PM EPA Interlab L01 1314 CFS
10/6/11 3:38 PM EPA Interlab L01 1314 CFS
10/6/11 3:43 PM EPA Interlab L01 1314 CFS
10/6/11 3:48 PM EPA Interlab L01 1314 CFS
10/6/11 3:53 PM EPA Interlab L01 1314 CFS
10/6/11 3:58 PM EPA Interlab L01 1314 CFS
10/6/11 4:03 PM EPA Interlab L01 1314 CFS
10/6/11 3:20 PM EPA Interlab L01 1314 CFS
10/6/11 3:25 PM EPA Interlab L01 1314 CFS
10/6/11 3:30 PM EPA Interlab L01 1314 CFS
10/6/11 3:40 PM EPA Interlab L01 1314 CFS
10/6/11 3:45 PM EPA Interlab L01 1314 CFS
10/6/11 3:50 PM EPA Interlab L01 1314 CFS
10/6/11 3:55 PM EPA Interlab L01 1314 CFS
10/6/11 4:00 PM EPA Interlab L01 1314 CFS
10/6/11 4:05 PM EPA Interlab L01 1314 CFS
10/6/11 3:12 PM EPA Interlab L01 1314 CFS
1-32
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1314:
Dilut
Element Sample ID Fact
Al CFS-L06-1314-T01-A
Al CFS-L06-1314-T02-A
Al CFS-L06-1314-T03-A
Al CFS-L06-1314-T04-A
Al CFS-L06-1314-T05-A
Al CFS-L06-1314-T06-A
Al CFS-L06-1314-T07-A
Al CFS-L06-1314-T08-A
Al CFS-L06-1314-T09-A
Al CFS-L06-1314-T01-B
Al CFS-L06-1314-T02-B
Al CFS-L06-1314-T03-B
Al CFS-L06-1314-T04-B
Al CFS-L06-1314-T05-B
Al CFS-L06-1314-T06-B
Al CFS-L06-1314-T07-B
Al CFS-L06-1314-T08-B
Al CFS-L06-1314-T09-B
Al CFS-L06-1314-T01-C
Al CFS-L06-1314-T02-C
Al CFS-L06-1314-T03-C
Al CFS-L06-1314-T04-C
Al CFS-L06-1314-T05-C
Al CFS-L06-1314-T06-C
Al CFS-L06-1314-T07-C
Al CFS-L06-1314-T08-C
Al CFS-L06-1314-T09-C
Al CFS-L06-1314-B01-A
on Sample
or Cone. Qualifier
ug/L
1 4.98E+01
1 4.42E+01
1 3.93E+01
1 4.39E+01
1 3.85E+01
1 3.69E+01
1 3.58E+01
1 3.72E+01
1 3.55E+01
1 4.81 E+01
1 4.22E+01
1 5.61 E+01
1 3.91 E+01
1 3.84E+01
1 3.87E+01
1 4.18E+01
1 3.85E+01
1 3.69E+01
1 4.95E+01
1 4.04E+01
1 3.92E+01
1 3.78E+01
1 3.61 E+01
1 4.12E+01
1 3.96E+01
1 3.84E+01
1 4.70E+01
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.98E+01 5.64 1.00 3.18
4.42E+01 3.16 1.00 3.18
3.93E+01 0.47 1.00 3.18 10000 1000
4.39E+01 2.16 1.00 3.18
3.85E+01 1.85 1.00 3.18
3.69E+01 2.39 1.00 3.18
3.58E+01 5.28 1.00 3.18
3.72E+01 8.03 1.00 3.18
3.55E+01 5.47 1.00 3.18
4.81E+01 2.78 1.00 3.18
4.22E+01 5.44 1.00 3.18
5.61E+01 1.47 1.00 3.18 10000 1000
3.91E+01 4.86 1.00 3.18
3.84E+01 4.74 1.00 3.18
3.87E+01 5.41 1.00 3.18
4.18E+01 3.16 1.00 3.18
3.85E+01 2.87 1.00 3.18
3.69E+01 3.57 1.00 3.18
4.95E+01 1.75 1.00 3.18
4.04E+01 4.47 1.00 3.18
3.92E+01 5.48 1.00 3.18 10000 1000
3.78E+01 4.92 1.00 3.18
3.61E+01 6.16 1.00 3.18
4.12E+01 2.00 1.00 3.18
3.96E+01 1.20 1.00 3.18
3.84E+01 2.91 1.00 3.18
4.70E+01 3.39 1.00 3.18
5.00E-01 35.79 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.05E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/124:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-33
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Sb CFS-L06-1314-T01-A 1 7.15E+01
Sb CFS-L06-1314-T02-A 1 4.29E+01
Sb CFS-L06-1314-T03-A 1 3.36E+01
Sb CFS-L06-1314-T04-A 1 2.47E+01
Sb CFS-L06-1314-T05-A 1 2.34E+01 E
Sb CFS-L06-1314-T06-A 1 2.78E+01
Sb CFS-L06-1314-T07-A 1 1.76E+01 E
Sb CFS-L06-1314-T08-A 1 2.04E+01 E
Sb CFS-L06-1314-T09-A 1 2.53E+01
Sb CFS-L06-1314-T01-B 1 8.79E+01
Sb CFS-L06-1314-T02-B 1 3.72E+01
Sb CFS-L06-1314-T03-B 1 3.12E+01
Sb CFS-L06-1314-T04-B 1 3.76E+01
Sb CFS-L06-1314-T05-B 1 2.37E+01 E
Sb CFS-L06-1314-T06-B 1 2.91E+01
Sb CFS-L06-1314-T07-B 1 1.82E+01 E
Sb CFS-L06-1314-T08-B 1 2.49E+01
Sb CFS-L06-1314-T09-B 1 1.67E+01 E
Sb CFS-L06-1314-T01-C 1 7.55E+01
Sb CFS-L06-1314-T02-C 1 4.07E+01
Sb CFS-L06-1314-T03-C 1 2.30E+01 E
Sb CFS-L06-1314-T04-C 1 2.76E+01
Sb CFS-L06-1314-T05-C 1 2.98E+01
Sb CFS-L06-1314-T06-C 1 3.28E+01
Sb CFS-L06-1314-T07-C 1 2.60E+01
Sb CFS-L06-1314-T08-C 1 1.83E+01 E
Sb CFS-L06-1314-T09-C 1 2.02E+01 E
Sb CFS-L06-1314-B01-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.15E+01 4.43 7.50 23.90
4.29E+01 8.92 7.50 23.90
3.36E+01 12.08 7.50 23.90 10000 1000
2.47E+01 2.44 7.50 23.90
2.34E+01 15.59 7.50 23.90
2.78E+01 9.28 7.50 23.90
1.76E+01 32.89 7.50 23.90
2.04E+01 19.83 7.50 23.90
2.53E+01 2.54 7.50 23.90
8.79E+01 1.14 7.50 23.90
3.72E+01 2.79 7.50 23.90
3.12E+01 8.94 7.50 23.90 10000 1000
3.76E+01 7.53 7.50 23.90
2.37E+01 4.32 7.50 23.90
2.91E+01 5.93 7.50 23.90
1.82E+01 31.41 7.50 23.90
2.49E+01 11.12 7.50 23.90
1.67E+01 4.55 7.50 23.90
7.55E+01 8.23 7.50 23.90
4.07E+01 1.29 7.50 23.90
2.30E+01 17.29 7.50 23.90 10000 1000
2.76E+01 1.44 7.50 23.90
2.98E+01 6.94 7.50 23.90
3.28E+01 1.86 7.50 23.90
2.60E+01 2.49 7.50 23.90
1.83E+01 1.93 7.50 23.90
2.02E+01 9.20 7.50 23.90
3.75E+00 91.82 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.12E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-34
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
As CFS-L06-1314-T01-A 1 4.95E+01
As CFS-L06-1314-T02-A 1 1.69E+01 E
As CFS-L06-1314-T03-A 1 5.50E+00 U1/2
As CFS-L06-1314-T04-A 1 5.50E+00 U1/2
As CFS-L06-1314-T05-A 1 5.50E+00 U1/2
As CFS-L06-1314-T06-A 1 5.50E+00 U1/2
As CFS-L06-1314-T07-A 1 5.50E+00 U1/2
As CFS-L06-1314-T08-A 1 5.50E+00 U1/2
As CFS-L06-1314-T09-A 1 5.50E+00 U1/2
As CFS-L06-1314-T01-B 1 6.24E+01
As CFS-L06-1314-T02-B 1 1.24E+01 E
As CFS-L06-1314-T03-B 1 5.50E+00 U1/2
As CFS-L06-1314-T04-B 1 5.50E+00 U1/2
As CFS-L06-1314-T05-B 1 5.50E+00 U1/2
As CFS-L06-1314-T06-B 1 5.50E+00 U1/2
As CFS-L06-1314-T07-B 1 5.50E+00 U1/2
As CFS-L06-1314-T08-B 1 5.50E+00 U1/2
As CFS-L06-1314-T09-B 1 5.50E+00 U1/2
As CFS-L06-1314-T01-C 1 5.90E+01
As CFS-L06-1314-T02-C 1 2.00E+01 E
As CFS-L06-1314-T03-C 1 1.55E+01 E
As CFS-L06-1314-T04-C 1 5.50E+00 U1/2
As CFS-L06-1314-T05-C 1 5.50E+00 U1/2
As CFS-L06-1314-T06-C 1 5.50E+00 U1/2
As CFS-L06-1314-T07-C 1 5.50E+00 U1/2
As CFS-L06-1314-T08-C 1 5.50E+00 U1/2
As CFS-L06-1314-T09-C 1 5.50E+00 U1/2
As CFS-L06-1314-B01-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.95E+01 1.47 11.00 35.00
1.69E+01 29.59 11.00 35.00
5.50E+00 3.66 11.00 35.00 10000 1000
5.50E+00 15.94 11.00 35.00
5.50E+00 11.12 11.00 35.00
5.50E+00 42.18 11.00 35.00
5.50E+00 22.69 11.00 35.00
5.50E+00 27.57 11.00 35.00
5.50E+00 52.86 11.00 35.00
6.24E+01 1.59 11.00 35.00
1.24E+01 32.16 11.00 35.00
5.50E+00 11.77 11.00 35.00 10000 1000
5.50E+00 3.54 11.00 35.00
5.50E+00 41.39 11.00 35.00
5.50E+00 24.20 11.00 35.00
5.50E+00 40.09 11.00 35.00
5.50E+00 32.36 11.00 35.00
5.50E+00 24.27 11.00 35.00
5.90E+01 5.60 11.00 35.00
2.00E+01 16.20 11.00 35.00
1.55E+01 8.71 11.00 35.00 10000 1000
5.50E+00 36.14 11.00 35.00
5.50E+00 25.43 11.00 35.00
5.50E+00 12.01 11.00 35.00
5.50E+00 18.56 11.00 35.00
5.50E+00 45.44 11.00 35.00
5.50E+00 49.63 11.00 35.00
5.50E+00 24.73 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-35
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
B CFS-L06-1314-T01-A 1 2.32E+03
B CFS-L06-1314-T02-A 1 1.39E+03
B CFS-L06-1314-T03-A 1 5.97E+02
B CFS-L06-1314-T04-A 1 3.12E+02
B CFS-L06-1314-T05-A 1 1.94E+02
B CFS-L06-1314-T06-A 1 1.16E+02
B CFS-L06-1314-T07-A 1 7.16E+01
B CFS-L06-1314-T08-A 1 5.23E+01
B CFS-L06-1314-T09-A 1 5.15E+01
B CFS-L06-1314-T01-B 1 2.54E+03
B CFS-L06-1314-T02-B 1 1.36E+03
B CFS-L06-1314-T03-B 1 5.67E+02
B CFS-L06-1314-T04-B 1 3.08E+02
B CFS-L06-1314-T05-B 1 1.86E+02
B CFS-L06-1314-T06-B 1 1.04E+02
B CFS-L06-1314-T07-B 1 6.49E+01
B CFS-L06-1314-T08-B 1 4.89E+01
B CFS-L06-1314-T09-B 1 4.55E+01
B CFS-L06-1314-T01-C 1 2.53E+03
B CFS-L06-1314-T02-C 1 1.45E+03
B CFS-L06-1314-T03-C 1 5.78E+02
B CFS-L06-1314-T04-C 1 2.92E+02
B CFS-L06-1314-T05-C 1 1.88E+02
B CFS-L06-1314-T06-C 1 1.12E+02
B CFS-L06-1314-T07-C 1 7.11E+01
B CFS-L06-1314-T08-C 1 5.26E+01
B CFS-L06-1314-T09-C 1 4.91 E+01
B CFS-L06-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.32E+03 1.05 1.00 3.18
1.39E+03 0.17 1.00 3.18
5.97E+02 0.18 1.00 3.18 10000 1000
3.12E+02 0.89 1.00 3.18
1.94E+02 1.03 1.00 3.18
1.16E+02 3.14 1.00 3.18
7.16E+01 4.21 1.00 3.18
5.23E+01 0.96 1.00 3.18
5.15E+01 2.07 1.00 3.18
2.54E+03 0.30 1.00 3.18
1.36E+03 0.23 1.00 3.18
5.67E+02 0.27 1.00 3.18 10000 1000
3.08E+02 0.94 1.00 3.18
1.86E+02 2.46 1.00 3.18
1.04E+02 1.21 1.00 3.18
6.49E+01 0.88 1.00 3.18
4.89E+01 3.82 1.00 3.18
4.55E+01 0.79 1.00 3.18
2.53E+03 0.69 1.00 3.18
1.45E+03 1.25 1.00 3.18
5.78E+02 0.33 1.00 3.18 10000 1000
2.92E+02 1.15 1.00 3.18
1.88E+02 0.66 1.00 3.18
1.12E+02 0.86 1.00 3.18
7. 11 E+01 0.24 1.00 3.18
5.26E+01 2.41 1.00 3.18
4.91E+01 1.24 1.00 3.18
5.00E-01 4.93 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.51E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.50E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.52E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-36
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Ba CFS-L06-1314-T01-A 1 4.36E+01
Ba CFS-L06-1314-T02-A 1 4.66E+01
Ba CFS-L06-1314-T03-A 1 7.99E+01
Ba CFS-L06-1314-T04-A 1 9.54E+01
Ba CFS-L06-1314-T05-A 1 8.58E+01
Ba CFS-L06-1314-T06-A 1 9.01 E+01
Ba CFS-L06-1314-T07-A 1 1.01E+02
Ba CFS-L06-1314-T08-A 1 1.02E+02
Ba CFS-L06-1314-T09-A 1 1.03E+02
Ba CFS-L06-1314-T01-B 1 4.12E+01
Ba CFS-L06-1314-T02-B 1 4.66E+01
Ba CFS-L06-1314-T03-B 1 7.36E+01
Ba CFS-L06-1314-T04-B 1 9.13E+01
Ba CFS-L06-1314-T05-B 1 8.48E+01
Ba CFS-L06-1314-T06-B 1 8.91 E+01
Ba CFS-L06-1314-T07-B 1 1.00E+02
Ba CFS-L06-1314-T08-B 1 1.04E+02
Ba CFS-L06-1314-T09-B 1 1.13E+02
Ba CFS-L06-1314-T01-C 1 4.43E+01
Ba CFS-L06-1314-T02-C 1 4.81 E+01
Ba CFS-L06-1314-T03-C 1 7.73E+01
Ba CFS-L06-1314-T04-C 1 8.64E+01
Ba CFS-L06-1314-T05-C 1 8.28E+01
Ba CFS-L06-1314-T06-C 1 9.09E+01
Ba CFS-L06-1314-T07-C 1 9.29E+01
Ba CFS-L06-1314-T08-C 1 1.00E+02
Ba CFS-L06-1314-T09-C 1 1.10E+02
Ba CFS-L06-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.36E+01 0.23 1.00 3.18
4.66E+01 0.78 1.00 3.18
7.99E+01 1.11 1.00 3.18 10000 1000
9.54E+01 0.99 1.00 3.18
8.58E+01 0.80 1.00 3.18
9.01E+01 1.32 1.00 3.18
1.01E+02 4.32 1.00 3.18
1.02E+02 1.51 1.00 3.18
1.03E+02 1.11 1.00 3.18
4.12E+01 0.36 1.00 3.18
4.66E+01 0.44 1.00 3.18
7.36E+01 1.93 1.00 3.18 10000 1000
9.13E+01 1.22 1.00 3.18
8.48E+01 5.01 1.00 3.18
8.91E+01 0.41 1.00 3.18
1.00E+02 0.93 1.00 3.18
1.04E+02 3.13 1.00 3.18
1.13E+02 0.66 1.00 3.18
4.43E+01 0.33 1.00 3.18
4.81E+01 0.59 1.00 3.18
7.73E+01 0.25 1.00 3.18 10000 1000
8.64E+01 0.97 1.00 3.18
8.28E+01 0.56 1.00 3.18
9.09E+01 0.54 1.00 3.18
9.29E+01 1.26 1.00 3.18
1.00E+02 0.83 1.00 3.18
1.10E+02 1.50 1.00 3.18
5.00E-01 36.71 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-37
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Be CFS-L06-1314-T01-A 1 9.50E-01 U1/2
Be CFS-L06-1314-T02-A 1 9.50E-01 U1/2
Be CFS-L06-1314-T03-A 1 9.50E-01 U1/2
Be CFS-L06-1314-T04-A 1 9.50E-01 U1/2
Be CFS-L06-1314-T05-A 1 9.50E-01 U1/2
Be CFS-L06-1314-T06-A 1 9.50E-01 U1/2
Be CFS-L06-1314-T07-A 1 9.50E-01 U1/2
Be CFS-L06-1314-T08-A 1 9.50E-01 U1/2
Be CFS-L06-1314-T09-A 1 9.50E-01 U1/2
Be CFS-L06-1314-T01-B 1 9.50E-01 U1/2
Be CFS-L06-1314-T02-B 1 9.50E-01 U1/2
Be CFS-L06-1314-T03-B 1 9.50E-01 U1/2
Be CFS-L06-1314-T04-B 1 9.50E-01 U1/2
Be CFS-L06-1314-T05-B 1 9.50E-01 U1/2
Be CFS-L06-1314-T06-B 1 9.50E-01 U1/2
Be CFS-L06-1314-T07-B 1 9.50E-01 U1/2
Be CFS-L06-1314-T08-B 1 9.50E-01 U1/2
Be CFS-L06-1314-T09-B 1 9.50E-01 U1/2
Be CFS-L06-1314-T01-C 1 9.50E-01 U1/2
Be CFS-L06-1314-T02-C 1 9.50E-01 U1/2
Be CFS-L06-1314-T03-C 1 9.50E-01 U1/2
Be CFS-L06-1314-T04-C 1 9.50E-01 U1/2
Be CFS-L06-1314-T05-C 1 9.50E-01 U1/2
Be CFS-L06-1314-T06-C 1 9.50E-01 U1/2
Be CFS-L06-1314-T07-C 1 9.50E-01 U1/2
Be CFS-L06-1314-T08-C 1 9.50E-01 U1/2
Be CFS-L06-1314-T09-C 1 9.50E-01 U1/2
Be CFS-L06-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 17.81 1.90 6.00
9.50E-01 15.67 1.90 6.00
9.50E-01 27.51 1.90 6.00 10000 1000
9.50E-01 12.48 1.90 6.00
9.50E-01 45.88 1.90 6.00
9.50E-01 31.01 1.90 6.00
9.50E-01 50.73 1.90 6.00
9.50E-01 26.79 1.90 6.00
9.50E-01 54.80 1.90 6.00
9.50E-01 19.43 1.90 6.00
9.50E-01 16.62 1.90 6.00
9.50E-01 34.75 1.90 6.00 10000 1000
9.50E-01 21.38 1.90 6.00
9.50E-01 15.66 1.90 6.00
9.50E-01 22.49 1.90 6.00
9.50E-01 51.24 1.90 6.00
9.50E-01 21.97 1.90 6.00
9.50E-01 6.24 1.90 6.00
9.50E-01 26.69 1.90 6.00
9.50E-01 59.51 1.90 6.00
9.50E-01 25.80 1.90 6.00 10000 1000
9.50E-01 42.04 1.90 6.00
9.50E-01 27.32 1.90 6.00
9.50E-01 17.58 1.90 6.00
9.50E-01 25.20 1.90 6.00
9.50E-01 40.88 1.90 6.00
9.50E-01 52.14 1.90 6.00
9.50E-01 12.06 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.12E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.13E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.11E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-38
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Cd CFS-L06-1314-T01-A 1 1.64E+04
Cd CFS-L06-1314-T02-A 1 9.24E+03
Cd CFS-L06-1314-T03-A 1 8.36E+03
Cd CFS-L06-1314-T04-A 1 8.36E+03
Cd CFS-L06-1314-T05-A 1 8.02E+03
Cd CFS-L06-1314-T06-A 1 6.54E+03
Cd CFS-L06-1314-T07-A 1 5.27E+03
Cd CFS-L06-1314-T08-A 1 4.06E+03
Cd CFS-L06-1314-T09-A 1 3.40E+03
Cd CFS-L06-1314-T01-B 1 1.89E+04
Cd CFS-L06-1314-T02-B 1 9.47E+03
Cd CFS-L06-1314-T03-B 1 8.34E+03
Cd CFS-L06-1314-T04-B 1 8.68E+03
Cd CFS-L06-1314-T05-B 1 8.40E+03
Cd CFS-L06-1314-T06-B 1 6.59E+03
Cd CFS-L06-1314-T07-B 1 5.13E+03
Cd CFS-L06-1314-T08-B 1 4.01 E+03
Cd CFS-L06-1314-T09-B 1 3.31 E+03
Cd CFS-L06-1314-T01-C 1 1.70E+04
Cd CFS-L06-1314-T02-C 1 9.33E+03
Cd CFS-L06-1314-T03-C 1 8.37E+03
Cd CFS-L06-1314-T04-C 1 8.50E+03
Cd CFS-L06-1314-T05-C 1 8.61 E+03
Cd CFS-L06-1314-T06-C 1 6.91 E+03
Cd CFS-L06-1314-T07-C 1 5.51 E+03
Cd CFS-L06-1314-T08-C 1 4.30E+03
Cd CFS-L06-1314-T09-C 1 3.54E+03
Cd CFS-L06-1314-B01-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.64E+04 0.63 2.20 7.00
9.24E+03 0.09 2.20 7.00
8.36E+03 0.36 2.20 7.00 10000 1000
8.36E+03 0.87 2.20 7.00
8.02E+03 0.55 2.20 7.00
6.54E+03 1.12 2.20 7.00
5.27E+03 3.81 2.20 7.00
4.06E+03 1.20 2.20 7.00
3.40E+03 0.43 2.20 7.00
1.89E+04 0.21 2.20 7.00
9.47E+03 0.46 2.20 7.00
8.34E+03 0.56 2.20 7.00 10000 1000
8.68E+03 1.18 2.20 7.00
8.40E+03 2.84 2.20 7.00
6.59E+03 0.87 2.20 7.00
5.13E+03 0.73 2.20 7.00
4.01 E+03 2.41 2.20 7.00
3.31 E+03 0.24 2.20 7.00
1.70E+04 0.23 2.20 7.00
9.33E+03 1.08 2.20 7.00
8.37E+03 0.65 2.20 7.00 10000 1000
8.50E+03 0.81 2.20 7.00
8.61 E+03 0.50 2.20 7.00
6.91 E+03 0.64 2.20 7.00
5.51 E+03 0.94 2.20 7.00
4.30E+03 0.89 2.20 7.00
3.54E+03 0.42 2.20 7.00
1.10E+00 28.64 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.31 E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.31 E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.33E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-39
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
Ca CFS-L06-1314-T01-A 1 4.64E+05
Ca CFS-L06-1314-T02-A 1 5.18E+05
Ca CFS-L06-1314-T03-A 1 5.70E+05
Ca CFS-L06-1314-T04-A 1 6.07E+05
Ca CFS-L06-1314-T05-A 1 6.03E+05
Ca CFS-L06-1314-T06-A 1 6.01 E+05
Ca CFS-L06-1314-T07-A 1 6.14E+05
Ca CFS-L06-1314-T08-A 1 6.09E+05
Ca CFS-L06-1314-T09-A 1 6.18E+05
Ca CFS-L06-1314-T01-B 1 4.76E+05
Ca CFS-L06-1314-T02-B 1 5.15E+05
Ca CFS-L06-1314-T03-B 1 5.69E+05
Ca CFS-L06-1314-T04-B 1 6.05E+05
Ca CFS-L06-1314-T05-B 1 6.03E+05
Ca CFS-L06-1314-T06-B 1 6.08E+05
Ca CFS-L06-1314-T07-B 1 6.10E+05
Ca CFS-L06-1314-T08-B 1 6.17E+05
Ca CFS-L06-1314-T09-B 1 6.19E+05
Ca CFS-L06-1314-T01-C 1 4.65E+05
Ca CFS-L06-1314-T02-C 1 5.22E+05
Ca CFS-L06-1314-T03-C 1 5.66E+05
Ca CFS-L06-1314-T04-C 1 5.93E+05
Ca CFS-L06-1314-T05-C 1 6.01 E+05
Ca CFS-L06-1314-T06-C 1 6.04E+05
Ca CFS-L06-1314-T07-C 1 6. 11 E+05
Ca CFS-L06-1314-T08-C 1 6.20E+05
Ca CFS-L06-1314-T09-C 1 6.12E+05
Ca CFS-L06-1314-B01-A 1 1.30E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.64E+05 0.56 2.60 8.30
5.18E+05 0.30 2.60 8.30
5.70E+05 0.70 2.60 8.30 10000 1000
6.07E+05 1.15 2.60 8.30
6.03E+05 0.86 2.60 8.30
6.01 E+05 1.03 2.60 8.30
6.14E+05 3.07 2.60 8.30
6.09E+05 1.36 2.60 8.30
6.18E+05 0.46 2.60 8.30
4.76E+05 0.09 2.60 8.30
5.15E+05 0.50 2.60 8.30
5.69E+05 0.61 2.60 8.30 10000 1000
6.05E+05 1.00 2.60 8.30
6.03E+05 2.52 2.60 8.30
6.08E+05 0.60 2.60 8.30
6.10E+05 0.60 2.60 8.30
6.17E+05 2.04 2.60 8.30
6.19E+05 0.35 2.60 8.30
4.65E+05 0.50 2.60 8.30
5.22E+05 1.08 2.60 8.30
5.66E+05 0.54 2.60 8.30 10000 1000
5.93E+05 0.45 2.60 8.30
6.01 E+05 0.80 2.60 8.30
6.04E+05 1.18 2.60 8.30
6. 11 E+05 1.07 2.60 8.30
6.20E+05 1.14 2.60 8.30
6.12E+05 0.72 2.60 8.30
1.30E+00 28.32 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.71E+05 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.70E+05 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.67E+05 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-40
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Cr CFS-L06-1314-T01-A 1 6.00E-01 U1/2
Cr CFS-L06-1314-T02-A 1 6.00E-01 U1/2
Cr CFS-L06-1314-T03-A 1 6.00E-01 U1/2
Cr CFS-L06-1314-T04-A 1 6.00E-01 U1/2
Cr CFS-L06-1314-T05-A 1 6.00E-01 U1/2
Cr CFS-L06-1314-T06-A 1 6.00E-01 U1/2
Cr CFS-L06-1314-T07-A 1 6.00E-01 U1/2
Cr CFS-L06-1314-T08-A 1 6.00E-01 U1/2
Cr CFS-L06-1314-T09-A 1 6.00E-01 U1/2
Cr CFS-L06-1314-T01-B 1 6.00E-01 U1/2
Cr CFS-L06-1314-T02-B 1 6.00E-01 U1/2
Cr CFS-L06-1314-T03-B 1 6.00E-01 U1/2
Cr CFS-L06-1314-T04-B 1 6.00E-01 U1/2
Cr CFS-L06-1314-T05-B 1 6.00E-01 U1/2
Cr CFS-L06-1314-T06-B 1 6.00E-01 U1/2
Cr CFS-L06-1314-T07-B 1 6.00E-01 U1/2
Cr CFS-L06-1314-T08-B 1 6.00E-01 U1/2
Cr CFS-L06-1314-T09-B 1 6.00E-01 U1/2
Cr CFS-L06-1314-T01-C 1 6.00E-01 U1/2
Cr CFS-L06-1314-T02-C 1 6.00E-01 U1/2
Cr CFS-L06-1314-T03-C 1 6.00E-01 U1/2
Cr CFS-L06-1314-T04-C 1 6.00E-01 U1/2
Cr CFS-L06-1314-T05-C 1 6.00E-01 U1/2
Cr CFS-L06-1314-T06-C 1 6.00E-01 U1/2
Cr CFS-L06-1314-T07-C 1 6.00E-01 U1/2
Cr CFS-L06-1314-T08-C 1 6.00E-01 U1/2
Cr CFS-L06-1314-T09-C 1 6.00E-01 U1/2
Cr CFS-L06-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 36.82 1.20 3.82
6.00E-01 75.26 1.20 3.82
6.00E-01 36.21 1.20 3.82 10000 1000
6.00E-01 36.55 1.20 3.82
6.00E-01 24.97 1.20 3.82
6.00E-01 21.75 1.20 3.82
6.00E-01 30.54 1.20 3.82
6.00E-01 26.47 1.20 3.82
6.00E-01 41.12 1.20 3.82
6.00E-01 47.99 1.20 3.82
6.00E-01 70.99 1.20 3.82
6.00E-01 39.68 1.20 3.82 10000 1000
6.00E-01 23.09 1.20 3.82
6.00E-01 36.76 1.20 3.82
6.00E-01 74.45 1.20 3.82
6.00E-01 35.83 1.20 3.82
6.00E-01 9.72 1.20 3.82
6.00E-01 39.26 1.20 3.82
6.00E-01 44.67 1.20 3.82
6.00E-01 72.77 1.20 3.82
6.00E-01 74.30 1.20 3.82 10000 1000
6.00E-01 34.30 1.20 3.82
6.00E-01 33.46 1.20 3.82
6.00E-01 63.98 1.20 3.82
6.00E-01 48.86 1.20 3.82
6.00E-01 84.53 1.20 3.82
6.00E-01 24.67 1.20 3.82
6.00E-01 28.98 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.92E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.83E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.81 E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-41
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Co CFS-L06-1314-T01-A 1 7.25E+02
Co CFS-L06-1314-T02-A 1 3.58E+02
Co CFS-L06-1314-T03-A 1 2.94E+02
Co CFS-L06-1314-T04-A 1 2.72E+02
Co CFS-L06-1314-T05-A 1 2.35E+02
Co CFS-L06-1314-T06-A 1 1.23E+02
Co CFS-L06-1314-T07-A 1 6.33E+01
Co CFS-L06-1314-T08-A 1 4.10E+01
Co CFS-L06-1314-T09-A 1 3.25E+01
Co CFS-L06-1314-T01-B 1 8.16E+02
Co CFS-L06-1314-T02-B 1 3.52E+02
Co CFS-L06-1314-T03-B 1 2.90E+02
Co CFS-L06-1314-T04-B 1 2.86E+02
Co CFS-L06-1314-T05-B 1 2.47E+02
Co CFS-L06-1314-T06-B 1 1.10E+02
Co CFS-L06-1314-T07-B 1 5.67E+01
Co CFS-L06-1314-T08-B 1 3.71E+01
Co CFS-L06-1314-T09-B 1 2.99E+01
Co CFS-L06-1314-T01-C 1 7.19E+02
Co CFS-L06-1314-T02-C 1 3.57E+02
Co CFS-L06-1314-T03-C 1 2.98E+02
Co CFS-L06-1314-T04-C 1 2.93E+02
Co CFS-L06-1314-T05-C 1 2.64E+02
Co CFS-L06-1314-T06-C 1 1.24E+02
Co CFS-L06-1314-T07-C 1 6.50E+01
Co CFS-L06-1314-T08-C 1 4.20E+01
Co CFS-L06-1314-T09-C 1 3.37E+01
Co CFS-L06-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.25E+02 1.31 1.80 5.72
3.58E+02 0.70 1.80 5.72
2.94E+02 0.60 1.80 5.72 10000 1000
2.72E+02 1.47 1.80 5.72
2.35E+02 0.22 1.80 5.72
1.23E+02 1.82 1.80 5.72
6.33E+01 4.10 1.80 5.72
4.10E+01 0.79 1.80 5.72
3.25E+01 0.65 1.80 5.72
8.16E+02 0.63 1.80 5.72
3.52E+02 0.39 1.80 5.72
2.90E+02 0.69 1.80 5.72 10000 1000
2.86E+02 0.99 1.80 5.72
2.47E+02 3.32 1.80 5.72
1.10E+02 1.12 1.80 5.72
5.67E+01 0.14 1.80 5.72
3.71 E+01 2.65 1.80 5.72
2.99E+01 4.48 1.80 5.72
7.19E+02 0.90 1.80 5.72
3.57E+02 1.13 1.80 5.72
2.98E+02 0.34 1.80 5.72 10000 1000
2.93E+02 1.23 1.80 5.72
2.64E+02 0.57 1.80 5.72
1.24E+02 1.14 1.80 5.72
6.50E+01 2.62 1.80 5.72
4.20E+01 1.55 1.80 5.72
3.37E+01 1.59 1.80 5.72
9.00E-01 44.77 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.39E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.32E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.37E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-42
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Cu CFS-L06-1314-T01-A 1 2.86E+03
Cu CFS-L06-1314-T02-A 1 2.00E+03
Cu CFS-L06-1314-T03-A 1 1.76E+03
Cu CFS-L06-1314-T04-A 1 1.89E+03
Cu CFS-L06-1314-T05-A 1 1.80E+03
Cu CFS-L06-1314-T06-A 1 1.39E+03
Cu CFS-L06-1314-T07-A 1 1.14E+03
Cu CFS-L06-1314-T08-A 1 8.98E+02
Cu CFS-L06-1314-T09-A 1 7.83E+02
Cu CFS-L06-1314-T01-B 1 3.40E+03
Cu CFS-L06-1314-T02-B 1 2.07E+03
Cu CFS-L06-1314-T03-B 1 1.71E+03
Cu CFS-L06-1314-T04-B 1 1.99E+03
Cu CFS-L06-1314-T05-B 1 1.92E+03
Cu CFS-L06-1314-T06-B 1 1.44E+03
Cu CFS-L06-1314-T07-B 1 1.15E+03
Cu CFS-L06-1314-T08-B 1 9.29E+02
Cu CFS-L06-1314-T09-B 1 7.89E+02
Cu CFS-L06-1314-T01-C 1 2.83E+03
Cu CFS-L06-1314-T02-C 1 1.94E+03
Cu CFS-L06-1314-T03-C 1 1.65E+03
Cu CFS-L06-1314-T04-C 1 1.83E+03
Cu CFS-L06-1314-T05-C 1 1.80E+03
Cu CFS-L06-1314-T06-C 1 1.39E+03
Cu CFS-L06-1314-T07-C 1 1.16E+03
Cu CFS-L06-1314-T08-C 1 9.53E+02
Cu CFS-L06-1314-T09-C 1 8.11E+02
Cu CFS-L06-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.86E+03 0.11 3.70 11.80
2.00E+03 1.76 3.70 11.80
1.76E+03 0.64 3.70 11.80 10000 1000
1.89E+03 1.26 3.70 11.80
1.80E+03 0.53 3.70 11.80
1.39E+03 0.73 3.70 11.80
1.14E+03 2.92 3.70 11.80
8.98E+02 0.95 3.70 11.80
7.83E+02 0.93 3.70 11.80
3.40E+03 1.34 3.70 11.80
2.07E+03 1.17 3.70 11.80
1.71E+03 0.70 3.70 11.80 10000 1000
1.99E+03 1.09 3.70 11.80
1.92E+03 1.65 3.70 11.80
1.44E+03 0.95 3.70 11.80
1.15E+03 0.39 3.70 11.80
9.29E+02 1.92 3.70 11.80
7.89E+02 0.53 3.70 11.80
2.83E+03 0.51 3.70 11.80
1.94E+03 1.78 3.70 11.80
1.65E+03 0.59 3.70 11.80 10000 1000
1.83E+03 1.07 3.70 11.80
1.80E+03 0.97 3.70 11.80
1.39E+03 1.45 3.70 11.80
1.16E+03 1.73 3.70 11.80
9.53E+02 2.09 3.70 11.80
8.11E+02 0.64 3.70 11.80
1.85E+00 46.72 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.81E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.66E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.64E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/124:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-43
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Fe CFS-L06-1314-T01-A 1 3.72E+00 E
Fe CFS-L06-1314-T02-A 1 1.00E+00 U1/2
Fe CFS-L06-1314-T03-A 1 1.00E+00 U1/2
Fe CFS-L06-1314-T04-A 1 1.00E+00 U1/2
Fe CFS-L06-1314-T05-A 1 8.23E+00
Fe CFS-L06-1314-T06-A 1 1.00E+00 U1/2
Fe CFS-L06-1314-T07-A 1 1.00E+00 U1/2
Fe CFS-L06-1314-T08-A 1 2.61E+01
Fe CFS-L06-1314-T09-A 1 1.00E+00 U1/2
Fe CFS-L06-1314-T01-B 1 1.00E+00 U1/2
Fe CFS-L06-1314-T02-B 1 2.53E+00 E
Fe CFS-L06-1314-T03-B 1 1.00E+00 U1/2
Fe CFS-L06-1314-T04-B 1 1.00E+00 U1/2
Fe CFS-L06-1314-T05-B 1 1.00E+00 U1/2
Fe CFS-L06-1314-T06-B 1 1.00E+00 U1/2
Fe CFS-L06-1314-T07-B 1 1.00E+00 U1/2
Fe CFS-L06-1314-T08-B 1 1.00E+00 U1/2
Fe CFS-L06-1314-T09-B 1 1.00E+00 U1/2
Fe CFS-L06-1314-T01-C 1 1.00E+00 U1/2
Fe CFS-L06-1314-T02-C 1 1.00E+00 U1/2
Fe CFS-L06-1314-T03-C 1 3.46E+00 E
Fe CFS-L06-1314-T04-C 1 1.00E+00 U1/2
Fe CFS-L06-1314-T05-C 1 1.00E+00 U1/2
Fe CFS-L06-1314-T06-C 1 1.00E+00 U1/2
Fe CFS-L06-1314-T07-C 1 1.00E+00 U1/2
Fe CFS-L06-1314-T08-C 1 1.00E+00 U1/2
Fe CFS-L06-1314-T09-C 1 1.00E+00 U1/2
Fe CFS-L06-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.72E+00 10.02 2.00 6.40
1.00E+00 24.56 2.00 6.40
1.00E+00 12.68 2.00 6.40 10000 1000
1.00E+00 35.65 2.00 6.40
8.23E+00 2.65 2.00 6.40
1.00E+00 24.44 2.00 6.40
1.00E+00 10.73 2.00 6.40
2.61E+01 1.25 2.00 6.40
1.00E+00 13.72 2.00 6.40
1.00E+00 25.61 2.00 6.40
2.53E+00 13.56 2.00 6.40
1.00E+00 24.02 2.00 6.40 10000 1000
1.00E+00 15.33 2.00 6.40
1.00E+00 20.84 2.00 6.40
1.00E+00 11.43 2.00 6.40
1.00E+00 14.85 2.00 6.40
1.00E+00 15.14 2.00 6.40
1.00E+00 13.05 2.00 6.40
1.00E+00 11.67 2.00 6.40
1.00E+00 11.26 2.00 6.40
3.46E+00 5.81 2.00 6.40 10000 1000
1.00E+00 7.52 2.00 6.40
1.00E+00 1.18 2.00 6.40
1.00E+00 20.73 2.00 6.40
1.00E+00 5.49 2.00 6.40
1.00E+00 27.05 2.00 6.40
1.00E+00 3.84 2.00 6.40
1.00E+00 12.74 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.73E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.53E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.61 E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/124:11 PM EPA Interlab L06 131 4 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-44
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Pb CFS-L06-1314-T01-A 1 6.92E+02
Pb CFS-L06-1314-T02-A 1 7.74E+02
Pb CFS-L06-1314-T03-A 1 9.01 E+02
Pb CFS-L06-1314-T04-A 1 1.06E+03
Pb CFS-L06-1314-T05-A 1 1.10E+03
Pb CFS-L06-1314-T06-A 1 1.01E+03
Pb CFS-L06-1314-T07-A 1 9.55E+02
Pb CFS-L06-1314-T08-A 1 8.61 E+02
Pb CFS-L06-1314-T09-A 1 9.01 E+02
Pb CFS-L06-1314-T01-B 1 7.93E+02
Pb CFS-L06-1314-T02-B 1 6.74E+02
Pb CFS-L06-1314-T03-B 1 8.42E+02
Pb CFS-L06-1314-T04-B 1 1.04E+03
Pb CFS-L06-1314-T05-B 1 1.09E+03
Pb CFS-L06-1314-T06-B 1 9.92E+02
Pb CFS-L06-1314-T07-B 1 9.27E+02
Pb CFS-L06-1314-T08-B 1 8.71E+02
Pb CFS-L06-1314-T09-B 1 9.00E+02
Pb CFS-L06-1314-T01-C 1 6.98E+02
Pb CFS-L06-1314-T02-C 1 7.79E+02
Pb CFS-L06-1314-T03-C 1 8.88E+02
Pb CFS-L06-1314-T04-C 1 1.07E+03
Pb CFS-L06-1314-T05-C 1 1.12E+03
Pb CFS-L06-1314-T06-C 1 1.02E+03
Pb CFS-L06-1314-T07-C 1 9.67E+02
Pb CFS-L06-1314-T08-C 1 9.09E+02
Pb CFS-L06-1314-T09-C 1 9.18E+02
Pb CFS-L06-1314-B01-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.92E+02 0.34 6.80 21.60
7.74E+02 0.92 6.80 21.60
9.01E+02 0.72 6.80 21.60 10000 1000
1.06E+03 1.47 6.80 21.60
1.10E+03 0.55 6.80 21.60
1.01E+03 1.17 6.80 21.60
9.55E+02 3.21 6.80 21.60
8.61 E+02 1.45 6.80 21.60
9.01 E+02 0.62 6.80 21.60
7.93E+02 0.45 6.80 21.60
6.74E+02 0.24 6.80 21.60
8.42E+02 0.55 6.80 21.60 10000 1000
1.04E+03 1.61 6.80 21.60
1.09E+03 2.58 6.80 21.60
9.92E+02 0.75 6.80 21.60
9.27E+02 0.56 6.80 21.60
8.71 E+02 2.56 6.80 21.60
9.00E+02 0.39 6.80 21.60
6.98E+02 0.90 6.80 21.60
7.79E+02 1.09 6.80 21.60
8.88E+02 0.32 6.80 21.60 10000 1000
1.07E+03 0.41 6.80 21.60
1.12E+03 0.57 6.80 21.60
1.02E+03 0.88 6.80 21.60
9.67E+02 1.29 6.80 21.60
9.09E+02 1.18 6.80 21.60
9.18E+02 0.71 6.80 21.60
3.40E+00 17.14 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.89E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.91E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.83E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-45
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
Li CFS-L06-1314-T01-A 1 3.47E+01
Li CFS-L06-1314-T02-A 1 7.28E+00
Li CFS-L06-1314-T03-A 1 1.07E+01
Li CFS-L06-1314-T04-A 1 1.48E+01
Li CFS-L06-1314-T05-A 1 1.12E+01
Li CFS-L06-1314-T06-A 1 1.37E+01
Li CFS-L06-1314-T07-A 1 1.07E+01
Li CFS-L06-1314-T08-A 1 1.23E+01
Li CFS-L06-1314-T09-A 1 1.23E+01
Li CFS-L06-1314-T01-B 1 4.53E+01
Li CFS-L06-1314-T02-B 1 7.72E+00
Li CFS-L06-1314-T03-B 1 1.08E+01
Li CFS-L06-1314-T04-B 1 1.32E+01
Li CFS-L06-1314-T05-B 1 1.50E+01
Li CFS-L06-1314-T06-B 1 1.06E+01
Li CFS-L06-1314-T07-B 1 1.28E+01
Li CFS-L06-1314-T08-B 1 1.19E+01
Li CFS-L06-1314-T09-B 1 1.28E+01
Li CFS-L06-1314-T01-C 1 3.87E+01
Li CFS-L06-1314-T02-C 1 6.29E+00
Li CFS-L06-1314-T03-C 1 1.09E+01
Li CFS-L06-1314-T04-C 1 1.28E+01
Li CFS-L06-1314-T05-C 1 1.30E+01
Li CFS-L06-1314-T06-C 1 1.01E+01
Li CFS-L06-1314-T07-C 1 1.20E+01
Li CFS-L06-1314-T08-C 1 1.57E+01
Li CFS-L06-1314-T09-C 1 1.24E+01
Li CFS-L06-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.47E+01 5.95 1.90 6.00
7.28E+00 2.67 1.90 6.00
1.07E+01 5.83 1.90 6.00 10000 1000
1.48E+01 2.24 1.90 6.00
1.12E+01 1.66 1.90 6.00
1.37E+01 2.88 1.90 6.00
1.07E+01 2.37 1.90 6.00
1.23E+01 9.74 1.90 6.00
1.23E+01 7.76 1.90 6.00
4.53E+01 11.76 1.90 6.00
7.72E+00 8.01 1.90 6.00
1.08E+01 2.30 1.90 6.00 10000 1000
1.32E+01 9.30 1.90 6.00
1.50E+01 6.96 1.90 6.00
1.06E+01 2.28 1.90 6.00
1.28E+01 5.45 1.90 6.00
1.19E+01 4.91 1.90 6.00
1.28E+01 1.11 1.90 6.00
3.87E+01 1.21 1.90 6.00
6.29E+00 1.51 1.90 6.00
1.09E+01 1.87 1.90 6.00 10000 1000
1.28E+01 11.66 1.90 6.00
1.30E+01 9.65 1.90 6.00
1.01E+01 4.32 1.90 6.00
1.20E+01 9.17 1.90 6.00
1.57E+01 2.52 1.90 6.00
1.24E+01 3.71 1.90 6.00
9.50E-01 12.08 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.05E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-46
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Mn CFS-L06-1314-T01-A 1 1.99E+04
Mn CFS-L06-1314-T02-A 1 8.34E+03
Mn CFS-L06-1314-T03-A 1 5.79E+03
Mn CFS-L06-1314-T04-A 1 4.16E+03
Mn CFS-L06-1314-T05-A 1 2.31E+03
Mn CFS-L06-1314-T06-A 1 8.40E+02
Mn CFS-L06-1314-T07-A 1 5.07E+02
Mn CFS-L06-1314-T08-A 1 3.71E+02
Mn CFS-L06-1314-T09-A 1 3.71E+02
Mn CFS-L06-1314-T01-B 1 2.18E+04
Mn CFS-L06-1314-T02-B 1 8.02E+03
Mn CFS-L06-1314-T03-B 1 5.76E+03
Mn CFS-L06-1314-T04-B 1 4.28E+03
Mn CFS-L06-1314-T05-B 1 2.09E+03
Mn CFS-L06-1314-T06-B 1 7.41E+02
Mn CFS-L06-1314-T07-B 1 4.52E+02
Mn CFS-L06-1314-T08-B 1 3.30E+02
Mn CFS-L06-1314-T09-B 1 3.31E+02
Mn CFS-L06-1314-T01-C 1 2.02E+04
Mn CFS-L06-1314-T02-C 1 8.76E+03
Mn CFS-L06-1314-T03-C 1 6.17E+03
Mn CFS-L06-1314-T04-C 1 4.33E+03
Mn CFS-L06-1314-T05-C 1 2.10E+03
Mn CFS-L06-1314-T06-C 1 8.24E+02
Mn CFS-L06-1314-T07-C 1 5.17E+02
Mn CFS-L06-1314-T08-C 1 3.74E+02
Mn CFS-L06-1314-T09-C 1 3.66E+02
Mn CFS-L06-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.99E+04 0.57 2.00 6.40
8.34E+03 0.10 2.00 6.40
5.79E+03 0.05 2.00 6.40 10000 1000
4.16E+03 1.92 2.00 6.40
2.31 E+03 1.35 2.00 6.40
8.40E+02 1.59 2.00 6.40
5.07E+02 1.03 2.00 6.40
3.71 E+02 0.75 2.00 6.40
3.71 E+02 0.56 2.00 6.40
2.18E+04 0.57 2.00 6.40
8.02E+03 0.80 2.00 6.40
5.76E+03 0.43 2.00 6.40 10000 1000
4.28E+03 1.26 2.00 6.40
2.09E+03 1.79 2.00 6.40
7. 41 E+02 0.77 2.00 6.40
4.52E+02 1.04 2.00 6.40
3.30E+02 2.14 2.00 6.40
3.31 E+02 0.89 2.00 6.40
2.02E+04 0.18 2.00 6.40
8.76E+03 1.07 2.00 6.40
6.17E+03 1.14 2.00 6.40 10000 1000
4.33E+03 1.04 2.00 6.40
2.10E+03 0.66 2.00 6.40
8.24E+02 1.59 2.00 6.40
5.17E+02 1.08 2.00 6.40
3.74E+02 1.36 2.00 6.40
3.66E+02 1.08 2.00 6.40
1.00E+00 23.23 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.76E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.74E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.07E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-47
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Mg CFS-L06-1314-T01-A 1 2.06E+06
Mg CFS-L06-1314-T02-A 1 4.17E+05
Mg CFS-L06-1314-T03-A 1 1.28E+05
Mg CFS-L06-1314-T04-A 1 3.88E+04
Mg CFS-L06-1314-T05-A 1 2.22E+04
Mg CFS-L06-1314-T06-A 1 1.60E+04
Mg CFS-L06-1314-T07-A 1 1.02E+04
Mg CFS-L06-1314-T08-A 1 7.08E+03
Mg CFS-L06-1314-T09-A 1 6.32E+03
Mg CFS-L06-1314-T01-B 1 2.30E+06
Mg CFS-L06-1314-T02-B 1 4.19E+05
Mg CFS-L06-1314-T03-B 1 1.21E+05
Mg CFS-L06-1314-T04-B 1 3.50E+04
Mg CFS-L06-1314-T05-B 1 2.03E+04
Mg CFS-L06-1314-T06-B 1 1.41E+04
Mg CFS-L06-1314-T07-B 1 8.35E+03
Mg CFS-L06-1314-T08-B 1 6.13E+03
Mg CFS-L06-1314-T09-B 1 5.31 E+03
Mg CFS-L06-1314-T01-C 1 2.14E+06
Mg CFS-L06-1314-T02-C 1 4.21E+05
Mg CFS-L06-1314-T03-C 1 1.19E+05
Mg CFS-L06-1314-T04-C 1 3.22E+04
Mg CFS-L06-1314-T05-C 1 2.07E+04
Mg CFS-L06-1314-T06-C 1 1.54E+04
Mg CFS-L06-1314-T07-C 1 9.47E+03
Mg CFS-L06-1314-T08-C 1 6.83E+03
Mg CFS-L06-1314-T09-C 1 6.19E+03
Mg CFS-L06-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.06E+06 0.57 1.00 3.18
4.17E+05 1.23 1.00 3.18
1.28E+05 0.59 1.00 3.18 10000 1000
3.88E+04 0.97 1.00 3.18
2.22E+04 0.23 1.00 3.18
1.60E+04 1.12 1.00 3.18
1.02E+04 1.84 1.00 3.18
7.08E+03 1.07 1.00 3.18
6.32E+03 0.22 1.00 3.18
2.30E+06 0.69 1.00 3.18
4.19E+05 0.39 1.00 3.18
1.21E+05 0.66 1.00 3.18 10000 1000
3.50E+04 1.15 1.00 3.18
2.03E+04 4.00 1.00 3.18
1.41E+04 0.79 1.00 3.18
8.35E+03 1.03 1.00 3.18
6.13E+03 2.59 1.00 3.18
5.31E+03 0.39 1.00 3.18
2.14E+06 1.04 1.00 3.18
4.21E+05 2.22 1.00 3.18
1.19E+05 1.36 1.00 3.18 10000 1000
3.22E+04 1.04 1.00 3.18
2.07E+04 1.22 1.00 3.18
1.54E+04 0.59 1.00 3.18
9.47E+03 1.58 1.00 3.18
6.83E+03 0.64 1.00 3.18
6.19E+03 1.20 1.00 3.18
5.00E-01 17.52 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.29E+05 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.22E+05 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.20E+05 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-48
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Mo CFS-L06-1314-T01-A 1 2.70E+01
Mo CFS-L06-1314-T02-A 1 1.08E+01
Mo CFS-L06-1314-T03-A 1 7.86E+00
Mo CFS-L06-1314-T04-A 1 5.65E+00
Mo CFS-L06-1314-T05-A 1 6.11E+00
Mo CFS-L06-1314-T06-A 1 6.80E+00
Mo CFS-L06-1314-T07-A 1 6.39E+00
Mo CFS-L06-1314-T08-A 1 6.14E+00
Mo CFS-L06-1314-T09-A 1 6.33E+00
Mo CFS-L06-1314-T01-B 1 2.64E+01
Mo CFS-L06-1314-T02-B 1 1.10E+01
Mo CFS-L06-1314-T03-B 1 6.85E+00
Mo CFS-L06-1314-T04-B 1 7.05E+00
Mo CFS-L06-1314-T05-B 1 5.94E+00
Mo CFS-L06-1314-T06-B 1 6.10E+00
Mo CFS-L06-1314-T07-B 1 5.22E+00
Mo CFS-L06-1314-T08-B 1 5.08E+00
Mo CFS-L06-1314-T09-B 1 6.12E+00
Mo CFS-L06-1314-T01-C 1 2.39E+01
Mo CFS-L06-1314-T02-C 1 9.40E+00
Mo CFS-L06-1314-T03-C 1 6.83E+00
Mo CFS-L06-1314-T04-C 1 6.15E+00
Mo CFS-L06-1314-T05-C 1 5.85E+00
Mo CFS-L06-1314-T06-C 1 5.65E+00
Mo CFS-L06-1314-T07-C 1 6.17E+00
Mo CFS-L06-1314-T08-C 1 6.95E+00
Mo CFS-L06-1314-T09-C 1 6.09E+00
Mo CFS-L06-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.70E+01 0.89 1.20 3.82
1.08E+01 1.38 1.20 3.82
7.86E+00 7.16 1.20 3.82 10000 1000
5.65E+00 13.49 1.20 3.82
6.11E+00 2.19 1.20 3.82
6.80E+00 2.68 1.20 3.82
6.39E+00 0.31 1.20 3.82
6.14E+00 3.79 1.20 3.82
6.33E+00 8.40 1.20 3.82
2.64E+01 12.44 1.20 3.82
1.10E+01 9.00 1.20 3.82
6.85E+00 9.15 1.20 3.82 10000 1000
7.05E+00 2.18 1.20 3.82
5.94E+00 2.87 1.20 3.82
6.10E+00 2.12 1.20 3.82
5.22E+00 1.28 1.20 3.82
5.08E+00 1.94 1.20 3.82
6.12E+00 3.51 1.20 3.82
2.39E+01 5.97 1.20 3.82
9.40E+00 3.29 1.20 3.82
6.83E+00 1.14 1.20 3.82 10000 1000
6.15E+00 2.34 1.20 3.82
5.85E+00 2.36 1.20 3.82
5.65E+00 7.78 1.20 3.82
6.17E+00 5.11 1.20 3.82
6.95E+00 7.83 1.20 3.82
6.09E+00 1.27 1.20 3.82
6.00E-01 12.51 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-49
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Ni CFS-L06-1314-T01-A 1 1.01E+03
Ni CFS-L06-1314-T02-A 1 5.20E+02
Ni CFS-L06-1314-T03-A 1 4.41E+02
Ni CFS-L06-1314-T04-A 1 4.25E+02
Ni CFS-L06-1314-T05-A 1 3.89E+02
Ni CFS-L06-1314-T06-A 1 2.55E+02
Ni CFS-L06-1314-T07-A 1 1.62E+02
Ni CFS-L06-1314-T08-A 1 1.02E+02
Ni CFS-L06-1314-T09-A 1 8.22E+01
Ni CFS-L06-1314-T01-B 1 1.16E+03
Ni CFS-L06-1314-T02-B 1 5.25E+02
Ni CFS-L06-1314-T03-B 1 4.39E+02
Ni CFS-L06-1314-T04-B 1 4.47E+02
Ni CFS-L06-1314-T05-B 1 4.14E+02
Ni CFS-L06-1314-T06-B 1 2.47E+02
Ni CFS-L06-1314-T07-B 1 1.45E+02
Ni CFS-L06-1314-T08-B 1 9.79E+01
Ni CFS-L06-1314-T09-B 1 7.66E+01
Ni CFS-L06-1314-T01-C 1 9.94E+02
Ni CFS-L06-1314-T02-C 1 5.13E+02
Ni CFS-L06-1314-T03-C 1 4.42E+02
Ni CFS-L06-1314-T04-C 1 4.40E+02
Ni CFS-L06-1314-T05-C 1 4.34E+02
Ni CFS-L06-1314-T06-C 1 2.69E+02
Ni CFS-L06-1314-T07-C 1 1.65E+02
Ni CFS-L06-1314-T08-C 1 1.10E+02
Ni CFS-L06-1314-T09-C 1 8.40E+01
Ni CFS-L06-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.01E+03 0.34 1.80 5.70
5.20E+02 0.36 1.80 5.70
4.41E+02 0.79 1.80 5.70 10000 1000
4.25E+02 0.98 1.80 5.70
3.89E+02 0.68 1.80 5.70
2.55E+02 1.31 1.80 5.70
1.62E+02 4.40 1.80 5.70
1.02E+02 1.61 1.80 5.70
8.22E+01 1.01 1.80 5.70
1.16E+03 0.42 1.80 5.70
5.25E+02 0.18 1.80 5.70
4.39E+02 0.29 1.80 5.70 10000 1000
4.47E+02 1.41 1.80 5.70
4.14E+02 2.33 1.80 5.70
2.47E+02 1.16 1.80 5.70
1.45E+02 1.71 1.80 5.70
9.79E+01 0.94 1.80 5.70
7.66E+01 2.66 1.80 5.70
9.94E+02 0.24 1.80 5.70
5.13E+02 1.47 1.80 5.70
4.42E+02 0.50 1.80 5.70 10000 1000
4.40E+02 0.53 1.80 5.70
4.34E+02 0.28 1.80 5.70
2.69E+02 1.52 1.80 5.70
1.65E+02 1.47 1.80 5.70
1.10E+02 2.36 1.80 5.70
8.40E+01 1.45 1.80 5.70
9.00E-01 48.06 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.42E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.38E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.38E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-50
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
P CFS-L06-1314-T01-A 1 4.21E+01
P CFS-L06-1314-T02-A 1 1.34E+01
P CFS-L06-1314-T03-A 1 7.17E+00 E
P CFS-L06-1314-T04-A 1 1.85E+00 U1/2
P CFS-L06-1314-T05-A 1 1.85E+00 U1/2
P CFS-L06-1314-T06-A 1 1.14E+01 E
P CFS-L06-1314-T07-A 1 1.85E+00 U1/2
P CFS-L06-1314-T08-A 1 1.85E+00 U1/2
P CFS-L06-1314-T09-A 1 1.85E+00 U1/2
P CFS-L06-1314-T01-B 1 4.33E+01
P CFS-L06-1314-T02-B 1 1.24E+01
P CFS-L06-1314-T03-B 1 5.43E+00 E
P CFS-L06-1314-T04-B 1 6.83E+00 E
P CFS-L06-1314-T05-B 1 1.24E+01
P CFS-L06-1314-T06-B 1 6.93E+00 E
P CFS-L06-1314-T07-B 1 1.85E+00 U1/2
P CFS-L06-1314-T08-B 1 1.85E+00 U1/2
P CFS-L06-1314-T09-B 1 1.85E+00 U1/2
P CFS-L06-1314-T01-C 1 4.58E+01
P CFS-L06-1314-T02-C 1 6.60E+00 E
P CFS-L06-1314-T03-C 1 8.05E+00 E
P CFS-L06-1314-T04-C 1 7.18E+00 E
P CFS-L06-1314-T05-C 1 1.12E+01 E
P CFS-L06-1314-T06-C 1 1.85E+00 U1/2
P CFS-L06-1314-T07-C 1 1.85E+00 U1/2
P CFS-L06-1314-T08-C 1 1.85E+00 U1/2
P CFS-L06-1314-T09-C 1 1.85E+00 U1/2
P CFS-L06-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.21 E+01 1.64 3.70 11.80
1.34E+01 4.99 3.70 11.80
7.17E+00 13.45 3.70 11.80 10000 1000
1.85E+00 10.05 3.70 11.80
1.85E+00 44.96 3.70 11.80
1.14E+01 33.55 3.70 11.80
1.85E+00 24.62 3.70 11.80
1.85E+00 40.24 3.70 11.80
1.85E+00 61.34 3.70 11.80
4.33E+01 6.16 3.70 11.80
1.24E+01 20.48 3.70 11.80
5.43E+00 35.70 3.70 11.80 10000 1000
6.83E+00 36.15 3.70 11.80
1.24E+01 9.33 3.70 11.80
6.93E+00 21.89 3.70 11.80
1.85E+00 43.60 3.70 11.80
1.85E+00 26.80 3.70 11.80
1.85E+00 18.36 3.70 11.80
4.58E+01 2.31 3.70 11.80
6.60E+00 7.00 3.70 11.80
8.05E+00 10.05 3.70 11.80 10000 1000
7.18E+00 1.65 3.70 11.80
1.12E+01 16.98 3.70 11.80
1.85E+00 35.83 3.70 11.80
1.85E+00 24.59 3.70 11.80
1.85E+00 12.67 3.70 11.80
1.85E+00 29.00 3.70 11.80
1.85E+00 42.70 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.07E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-51
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
K CFS-L06-1314-T01-A 1 1.15E+05
K CFS-L06-1314-T02-A 1 4.20E+04
K CFS-L06-1314-T03-A 1 2.70E+04
K CFS-L06-1314-T04-A 1 1.93E+04
K CFS-L06-1314-T05-A 1 1.28E+04
K CFS-L06-1314-T06-A 1 6.24E+03
K CFS-L06-1314-T07-A 1 3.62E+03
K CFS-L06-1314-T08-A 1 2.42E+03
K CFS-L06-1314-T09-A 1 2.03E+03
K CFS-L06-1314-T01-B 1 1.27E+05
K CFS-L06-1314-T02-B 1 4.29E+04
K CFS-L06-1314-T03-B 1 2.76E+04
K CFS-L06-1314-T04-B 1 1.98E+04
K CFS-L06-1314-T05-B 1 1.26E+04
K CFS-L06-1314-T06-B 1 5.84E+03
K CFS-L06-1314-T07-B 1 3.36E+03
K CFS-L06-1314-T08-B 1 2.27E+03
K CFS-L06-1314-T09-B 1 1.91E+03
K CFS-L06-1314-T01-C 1 1.23E+05
K CFS-L06-1314-T02-C 1 4.32E+04
K CFS-L06-1314-T03-C 1 2.77E+04
K CFS-L06-1314-T04-C 1 1.92E+04
K CFS-L06-1314-T05-C 1 1.29E+04
K CFS-L06-1314-T06-C 1 6.23E+03
K CFS-L06-1314-T07-C 1 3.66E+03
K CFS-L06-1314-T08-C 1 2.46E+03
K CFS-L06-1314-T09-C 1 2.07E+03
K CFS-L06-1314-B01-A 1 2.18E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.15E+05 0.39 1.60 5.09
4.20E+04 0.15 1.60 5.09
2.70E+04 0.66 1.60 5.09 10000 1000
1.93E+04 2.24 1.60 5.09
1.28E+04 0.40 1.60 5.09
6.24E+03 1.16 1.60 5.09
3.62E+03 3.99 1.60 5.09
2.42E+03 0.84 1.60 5.09
2.03E+03 0.45 1.60 5.09
1.27E+05 0.33 1.60 5.09
4.29E+04 0.17 1.60 5.09
2.76E+04 1.09 1.60 5.09 10000 1000
1.98E+04 2.36 1.60 5.09
1.26E+04 2.89 1.60 5.09
5.84E+03 0.93 1.60 5.09
3.36E+03 0.60 1.60 5.09
2.27E+03 2.48 1.60 5.09
1.91E+03 0.14 1.60 5.09
1.23E+05 0.52 1.60 5.09
4.32E+04 1.07 1.60 5.09
2.77E+04 0.87 1.60 5.09 10000 1000
1.92E+04 2.26 1.60 5.09
1.29E+04 0.61 1.60 5.09
6.23E+03 0.41 1.60 5.09
3.66E+03 0.99 1.60 5.09
2.46E+03 0.91 1.60 5.09
2.07E+03 0.73 1.60 5.09
2.18E+01 1.67 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.78E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.85E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.86E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-52
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Se CFS-L06-1314-T01-A 1 1.84E+03
Se CFS-L06-1314-T02-A 1 2.80E+02
Se CFS-L06-1314-T03-A 1 9.76E+01
Se CFS-L06-1314-T04-A 1 4.26E+01 E
Se CFS-L06-1314-T05-A 1 3.10E+01 E
Se CFS-L06-1314-T06-A 1 2.04E+01 E
Se CFS-L06-1314-T07-A 1 2.66E+01 E
Se CFS-L06-1314-T08-A 1 1.87E+01 E
Se CFS-L06-1314-T09-A 1 7.50E+00 U1/2
Se CFS-L06-1314-T01-B 1 2.17E+03
Se CFS-L06-1314-T02-B 1 2.79E+02
Se CFS-L06-1314-T03-B 1 9.83E+01
Se CFS-L06-1314-T04-B 1 4.48E+01 E
Se CFS-L06-1314-T05-B 1 4.18E+01 E
Se CFS-L06-1314-T06-B 1 2.46E+01 E
Se CFS-L06-1314-T07-B 1 1.66E+01 E
Se CFS-L06-1314-T08-B 1 7.50E+00 U1/2
Se CFS-L06-1314-T09-B 1 7.50E+00 U1/2
Se CFS-L06-1314-T01-C 1 2.01E+03
Se CFS-L06-1314-T02-C 1 2.74E+02
Se CFS-L06-1314-T03-C 1 9.74E+01
Se CFS-L06-1314-T04-C 1 4.44E+01 E
Se CFS-L06-1314-T05-C 1 3.63E+01 E
Se CFS-L06-1314-T06-C 1 2.71E+01 E
Se CFS-L06-1314-T07-C 1 2.62E+01 E
Se CFS-L06-1314-T08-C 1 7.50E+00 U1/2
Se CFS-L06-1314-T09-C 1 7.50E+00 U1/2
Se CFS-L06-1314-B01-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.84E+03 0.75 15.00 47.70
2.80E+02 4.25 15.00 47.70
9.76E+01 2.33 15.00 47.70 10000 1000
4.26E+01 11.65 15.00 47.70
3.10E+01 11.34 15.00 47.70
2.04E+01 29.52 15.00 47.70
2.66E+01 16.58 15.00 47.70
1.87E+01 8.12 15.00 47.70
7.50E+00 23.65 15.00 47.70
2.17E+03 0.31 15.00 47.70
2.79E+02 3.79 15.00 47.70
9.83E+01 5.04 15.00 47.70 10000 1000
4.48E+01 19.21 15.00 47.70
4.18E+01 15.28 15.00 47.70
2.46E+01 24.53 15.00 47.70
1.66E+01 18.16 15.00 47.70
7.50E+00 16.77 15.00 47.70
7.50E+00 20.49 15.00 47.70
2.01E+03 0.93 15.00 47.70
2.74E+02 3.93 15.00 47.70
9.74E+01 1.31 15.00 47.70 10000 1000
4.44E+01 6.39 15.00 47.70
3.63E+01 16.38 15.00 47.70
2.71E+01 27.36 15.00 47.70
2.62E+01 19.15 15.00 47.70
7.50E+00 17.51 15.00 47.70
7.50E+00 31.80 15.00 47.70
7.50E+00 45.20 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.12E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-53
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Si CFS-L06-1314-T01-A 1 7.76E+03
Si CFS-L06-1314-T02-A 1 6.80E+03
Si CFS-L06-1314-T03-A 1 6.65E+03
Si CFS-L06-1314-T04-A 1 6.71E+03
Si CFS-L06-1314-T05-A 1 6.29E+03
Si CFS-L06-1314-T06-A 1 5.52E+03
Si CFS-L06-1314-T07-A 1 4.90E+03
Si CFS-L06-1314-T08-A 1 4.33E+03
Si CFS-L06-1314-T09-A 1 4.39E+03
Si CFS-L06-1314-T01-B 1 8.40E+03
Si CFS-L06-1314-T02-B 1 6.97E+03
Si CFS-L06-1314-T03-B 1 6.75E+03
Si CFS-L06-1314-T04-B 1 6.99E+03
Si CFS-L06-1314-T05-B 1 6.50E+03
Si CFS-L06-1314-T06-B 1 5.63E+03
Si CFS-L06-1314-T07-B 1 4.85E+03
Si CFS-L06-1314-T08-B 1 4.36E+03
Si CFS-L06-1314-T09-B 1 4.34E+03
Si CFS-L06-1314-T01-C 1 7.72E+03
Si CFS-L06-1314-T02-C 1 6.93E+03
Si CFS-L06-1314-T03-C 1 6.59E+03
Si CFS-L06-1314-T04-C 1 6.66E+03
Si CFS-L06-1314-T05-C 1 6.41 E+03
Si CFS-L06-1314-T06-C 1 5.58E+03
Si CFS-L06-1314-T07-C 1 4.94E+03
Si CFS-L06-1314-T08-C 1 4.46E+03
Si CFS-L06-1314-T09-C 1 4.43E+03
Si CFS-L06-1314-B01-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.76E+03 0.96 1.10 3.50
6.80E+03 0.11 1.10 3.50
6.65E+03 0.38 1.10 3.50 10000 1000
6.71 E+03 0.90 1.10 3.50
6.29E+03 0.88 1.10 3.50
5.52E+03 1.48 1.10 3.50
4.90E+03 2.91 1.10 3.50
4.33E+03 0.77 1.10 3.50
4.39E+03 1.39 1.10 3.50
8.40E+03 0.26 1.10 3.50
6.97E+03 0.39 1.10 3.50
6.75E+03 1.22 1.10 3.50 10000 1000
6.99E+03 1.51 1.10 3.50
6.50E+03 1.96 1.10 3.50
5.63E+03 1.35 1.10 3.50
4.85E+03 1.25 1.10 3.50
4.36E+03 2.32 1.10 3.50
4.34E+03 0.52 1.10 3.50
7.72E+03 0.50 1.10 3.50
6.93E+03 1.11 1.10 3.50
6.59E+03 0.85 1.10 3.50 10000 1000
6.66E+03 0.89 1.10 3.50
6.41 E+03 1.26 1.10 3.50
5.58E+03 1.81 1.10 3.50
4.94E+03 2.46 1.10 3.50
4.46E+03 1.71 1.10 3.50
4.43E+03 1.22 1.10 3.50
5.50E-01 4.75 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
7. 61 E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.68E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.53E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-54
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Na CFS-L06-1314-T01-A 1 2.96E+05
Na CFS-L06-1314-T02-A 1 5.65E+04
Na CFS-L06-1314-T03-A 1 1.13E+04
Na CFS-L06-1314-T04-A 1 5.49E+03
Na CFS-L06-1314-T05-A 1 3.45E+03
Na CFS-L06-1314-T06-A 1 2.18E+03
Na CFS-L06-1314-T07-A 1 1.42E+03
Na CFS-L06-1314-T08-A 1 1.15E+03
Na CFS-L06-1314-T09-A 1 1.16E+03
Na CFS-L06-1314-T01-B 1 3.19E+05
Na CFS-L06-1314-T02-B 1 5.58E+04
Na CFS-L06-1314-T03-B 1 1.07E+04
Na CFS-L06-1314-T04-B 1 5.53E+03
Na CFS-L06-1314-T05-B 1 3.29E+03
Na CFS-L06-1314-T06-B 1 1.96E+03
Na CFS-L06-1314-T07-B 1 1.33E+03
Na CFS-L06-1314-T08-B 1 1.07E+03
Na CFS-L06-1314-T09-B 1 1.12E+03
Na CFS-L06-1314-T01-C 1 3.14E+05
Na CFS-L06-1314-T02-C 1 5.21E+04
Na CFS-L06-1314-T03-C 1 1.03E+04
Na CFS-L06-1314-T04-C 1 4.90E+03
Na CFS-L06-1314-T05-C 1 3.32E+03
Na CFS-L06-1314-T06-C 1 2.08E+03
Na CFS-L06-1314-T07-C 1 1.40E+03
Na CFS-L06-1314-T08-C 1 1.09E+03
Na CFS-L06-1314-T09-C 1 1.19E+03
Na CFS-L06-1314-B01-A 1 1.25E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.96E+05 0.24 2.50 8.00
5.65E+04 0.78 2.50 8.00
1.13E+04 0.39 2.50 8.00 10000 1000
5.49E+03 0.59 2.50 8.00
3.45E+03 0.53 2.50 8.00
2.18E+03 0.53 2.50 8.00
1.42E+03 2.06 2.50 8.00
1.15E+03 1.63 2.50 8.00
1.16E+03 0.46 2.50 8.00
3.19E+05 0.58 2.50 8.00
5.58E+04 0.22 2.50 8.00
1.07E+04 0.59 2.50 8.00 10000 1000
5.53E+03 2.05 2.50 8.00
3.29E+03 3.93 2.50 8.00
1.96E+03 0.41 2.50 8.00
1.33E+03 0.99 2.50 8.00
1.07E+03 0.96 2.50 8.00
1.12E+03 1.00 2.50 8.00
3.14E+05 0.52 2.50 8.00
5.21 E+04 1.29 2.50 8.00
1.03E+04 0.96 2.50 8.00 10000 1000
4.90E+03 0.32 2.50 8.00
3.32E+03 0.71 2.50 8.00
2.08E+03 0.76 2.50 8.00
1.40E+03 0.55 2.50 8.00
1.09E+03 1.22 2.50 8.00
1.19E+03 1.01 2.50 8.00
1.25E+00 1.91 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.22E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.13E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-55
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Sr CFS-L06-1314-T01-A 1 3.88E+03
Sr CFS-L06-1314-T02-A 1 3.01 E+03
Sr CFS-L06-1314-T03-A 1 2.94E+03
Sr CFS-L06-1314-T04-A 1 2.79E+03
Sr CFS-L06-1314-T05-A 1 2.24E+03
Sr CFS-L06-1314-T06-A 1 1.73E+03
Sr CFS-L06-1314-T07-A 1 1.53E+03
Sr CFS-L06-1314-T08-A 1 1.36E+03
Sr CFS-L06-1314-T09-A 1 1.34E+03
Sr CFS-L06-1314-T01-B 1 4.14E+03
Sr CFS-L06-1314-T02-B 1 2.94E+03
Sr CFS-L06-1314-T03-B 1 2. 91 E+03
Sr CFS-L06-1314-T04-B 1 2.88E+03
Sr CFS-L06-1314-T05-B 1 2.18E+03
Sr CFS-L06-1314-T06-B 1 1.71E+03
Sr CFS-L06-1314-T07-B 1 1.47E+03
Sr CFS-L06-1314-T08-B 1 1.35E+03
Sr CFS-L06-1314-T09-B 1 1.31 E+03
Sr CFS-L06-1314-T01-C 1 3.86E+03
Sr CFS-L06-1314-T02-C 1 3.09E+03
Sr CFS-L06-1314-T03-C 1 3.01 E+03
Sr CFS-L06-1314-T04-C 1 2.84E+03
Sr CFS-L06-1314-T05-C 1 2.20E+03
Sr CFS-L06-1314-T06-C 1 1.75E+03
Sr CFS-L06-1314-T07-C 1 1.54E+03
Sr CFS-L06-1314-T08-C 1 1.39E+03
Sr CFS-L06-1314-T09-C 1 1.33E+03
Sr CFS-L06-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.88E+03 0.42 1.00 3.18
3.01E+03 1.16 1.00 3.18
2.94E+03 0.55 1.00 3.18 10000 1000
2.79E+03 0.87 1.00 3.18
2.24E+03 0.63 1.00 3.18
1.73E+03 1.81 1.00 3.18
1.53E+03 2.86 1.00 3.18
1.36E+03 1.10 1.00 3.18
1.34E+03 1.26 1.00 3.18
4.14E+03 0.74 1.00 3.18
2.94E+03 1.17 1.00 3.18
2.91E+03 1.34 1.00 3.18 10000 1000
2.88E+03 0.83 1.00 3.18
2.18E+03 1.34 1.00 3.18
1.71E+03 1.55 1.00 3.18
1.47E+03 0.79 1.00 3.18
1.35E+03 2.32 1.00 3.18
1.31E+03 0.71 1.00 3.18
3.86E+03 0.36 1.00 3.18
3.09E+03 1.27 1.00 3.18
3.01E+03 1.55 1.00 3.18 10000 1000
2.84E+03 1.81 1.00 3.18
2.20E+03 1.33 1.00 3.18
1.75E+03 1.38 1.00 3.18
1.54E+03 2.46 1.00 3.18
1.39E+03 1.55 1.00 3.18
1.33E+03 1.04 1.00 3.18
5.00E-01 31.22 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.88E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.87E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.99E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-56
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
S CFS-L06-1314-T01-A 1 2.39E+06
S CFS-L06-1314-T02-A 1 9.57E+05
S CFS-L06-1314-T03-A 1 6.45E+05
S CFS-L06-1314-T04-A 1 5.52E+05
S CFS-L06-1314-T05-A 1 5.28E+05
S CFS-L06-1314-T06-A 1 5.14E+05
S CFS-L06-1314-T07-A 1 5.10E+05
S CFS-L06-1314-T08-A 1 5.01 E+05
S CFS-L06-1314-T09-A 1 4.99E+05
S CFS-L06-1314-T01-B 1 2.55E+06
S CFS-L06-1314-T02-B 1 9.61 E+05
S CFS-L06-1314-T03-B 1 6.33E+05
S CFS-L06-1314-T04-B 1 5.58E+05
S CFS-L06-1314-T05-B 1 5.22E+05
S CFS-L06-1314-T06-B 1 5.06E+05
S CFS-L06-1314-T07-B 1 4.97E+05
S CFS-L06-1314-T08-B 1 4.93E+05
S CFS-L06-1314-T09-B 1 5.00E+05
S CFS-L06-1314-T01-C 1 2.46E+06
S CFS-L06-1314-T02-C 1 9.75E+05
S CFS-L06-1314-T03-C 1 6.33E+05
S CFS-L06-1314-T04-C 1 5.40E+05
S CFS-L06-1314-T05-C 1 5.30E+05
S CFS-L06-1314-T06-C 1 5.08E+05
S CFS-L06-1314-T07-C 1 5.04E+05
S CFS-L06-1314-T08-C 1 4.94E+05
S CFS-L06-1314-T09-C 1 4.96E+05
S CFS-L06-1314-B01-A 1 2.82E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.39E+06 0.25 6.80 21.60
9.57E+05 0.25 6.80 21.60
6.45E+05 0.10 6.80 21.60 10000 1000
5.52E+05 0.59 6.80 21.60
5.28E+05 0.43 6.80 21.60
5.14E+05 1.17 6.80 21.60
5.10E+05 4.08 6.80 21.60
5.01 E+05 1.21 6.80 21.60
4.99E+05 0.22 6.80 21.60
2.55E+06 0.76 6.80 21.60
9.61 E+05 0.47 6.80 21.60
6.33E+05 1.01 6.80 21.60 10000 1000
5.58E+05 1.46 6.80 21.60
5.22E+05 2.46 6.80 21.60
5.06E+05 0.93 6.80 21.60
4.97E+05 0.69 6.80 21.60
4.93E+05 2.85 6.80 21.60
5.00E+05 0.35 6.80 21.60
2.46E+06 0.74 6.80 21.60
9.75E+05 1.13 6.80 21.60
6.33E+05 0.59 6.80 21.60 10000 1000
5.40E+05 0.60 6.80 21.60
5.30E+05 0.73 6.80 21.60
5.08E+05 0.38 6.80 21.60
5.04E+05 1.26 6.80 21.60
4.94E+05 0.80 6.80 21.60
4.96E+05 0.65 6.80 21.60
2.82E+01 1.54 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.46E+05 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.33E+05 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.34E+05 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-57
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Tl CFS-L06-1314-T01-A 1 1.89E+03
Tl CFS-L06-1314-T02-A 1 8.82E+02
Tl CFS-L06-1314-T03-A 1 6.49E+02
Tl CFS-L06-1314-T04-A 1 5.21E+02
Tl CFS-L06-1314-T05-A 1 3.89E+02
Tl CFS-L06-1314-T06-A 1 2.37E+02
Tl CFS-L06-1314-T07-A 1 1.70E+02
Tl CFS-L06-1314-T08-A 1 1.25E+02
Tl CFS-L06-1314-T09-A 1 1.18E+02
Tl CFS-L06-1314-T01-B 1 2.05E+03
Tl CFS-L06-1314-T02-B 1 8.81 E+02
Tl CFS-L06-1314-T03-B 1 6.44E+02
Tl CFS-L06-1314-T04-B 1 5.27E+02
Tl CFS-L06-1314-T05-B 1 3.84E+02
Tl CFS-L06-1314-T06-B 1 2.28E+02
Tl CFS-L06-1314-T07-B 1 1.59E+02
Tl CFS-L06-1314-T08-B 1 1.20E+02
Tl CFS-L06-1314-T09-B 1 1.16E+02
Tl CFS-L06-1314-T01-C 1 1.99E+03
Tl CFS-L06-1314-T02-C 1 8.97E+02
Tl CFS-L06-1314-T03-C 1 6.62E+02
Tl CFS-L06-1314-T04-C 1 5.14E+02
Tl CFS-L06-1314-T05-C 1 3.90E+02
Tl CFS-L06-1314-T06-C 1 2. 41 E+02
Tl CFS-L06-1314-T07-C 1 1.67E+02
Tl CFS-L06-1314-T08-C 1 1.28E+02
Tl CFS-L06-1314-T09-C 1 1.22E+02
Tl CFS-L06-1314-B01-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.89E+03 0.61 4.60 14.60
8.82E+02 1.46 4.60 14.60
6.49E+02 0.74 4.60 14.60 10000 1000
5.21E+02 0.92 4.60 14.60
3.89E+02 2.11 4.60 14.60
2.37E+02 2.28 4.60 14.60
1.70E+02 4.61 4.60 14.60
1.25E+02 2.36 4.60 14.60
1.18E+02 3.87 4.60 14.60
2.05E+03 0.70 4.60 14.60
8.81E+02 0.74 4.60 14.60
6.44E+02 0.94 4.60 14.60 10000 1000
5.27E+02 2.24 4.60 14.60
3.84E+02 2.76 4.60 14.60
2.28E+02 0.56 4.60 14.60
1.59E+02 1.32 4.60 14.60
1.20E+02 6.57 4.60 14.60
1.16E+02 3.91 4.60 14.60
1.99E+03 0.56 4.60 14.60
8.97E+02 0.08 4.60 14.60
6.62E+02 0.58 4.60 14.60 10000 1000
5.14E+02 0.87 4.60 14.60
3.90E+02 1.40 4.60 14.60
2.41E+02 0.84 4.60 14.60
1.67E+02 2.20 4.60 14.60
1.28E+02 2.40 4.60 14.60
1.22E+02 0.87 4.60 14.60
2.30E+00 36.33 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.72E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.64E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.70E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-58
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ti CFS-L06-1314-T01-A 1 1.00E+00 U1/2
Ti CFS-L06-1314-T02-A 1 1.00E+00 U1/2
Ti CFS-L06-1314-T03-A 1 1.00E+00 U1/2
Ti CFS-L06-1314-T04-A 1 1.00E+00 U1/2
Ti CFS-L06-1314-T05-A 1 1.00E+00 U1/2
Ti CFS-L06-1314-T06-A 1 1.00E+00 U1/2
Ti CFS-L06-1314-T07-A 1 1.00E+00 U1/2
Ti CFS-L06-1314-T08-A 1 1.00E+00 U1/2
Ti CFS-L06-1314-T09-A 1 1.00E+00 U1/2
Ti CFS-L06-1314-T01-B 1 1.00E+00 U1/2
Ti CFS-L06-1314-T02-B 1 1.00E+00 U1/2
Ti CFS-L06-1314-T03-B 1 1.00E+00 U1/2
Ti CFS-L06-1314-T04-B 1 1.00E+00 U1/2
Ti CFS-L06-1314-T05-B 1 1.00E+00 U1/2
Ti CFS-L06-1314-T06-B 1 1.00E+00 U1/2
Ti CFS-L06-1314-T07-B 1 1.00E+00 U1/2
Ti CFS-L06-1314-T08-B 1 1.00E+00 U1/2
Ti CFS-L06-1314-T09-B 1 1.00E+00 U1/2
Ti CFS-L06-1314-T01-C 1 1.00E+00 U1/2
Ti CFS-L06-1314-T02-C 1 1.00E+00 U1/2
Ti CFS-L06-1314-T03-C 1 1.00E+00 U1/2
Ti CFS-L06-1314-T04-C 1 1.00E+00 U1/2
Ti CFS-L06-1314-T05-C 1 1.00E+00 U1/2
Ti CFS-L06-1314-T06-C 1 1.00E+00 U1/2
Ti CFS-L06-1314-T07-C 1 1.00E+00 U1/2
Ti CFS-L06-1314-T08-C 1 1.00E+00 U1/2
Ti CFS-L06-1314-T09-C 1 1.00E+00 U1/2
Ti CFS-L06-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 40.32 2.00 6.40
1.00E+00 16.47 2.00 6.40
1.00E+00 46.78 2.00 6.40 10000 1000
1.00E+00 37.87 2.00 6.40
1.00E+00 34.06 2.00 6.40
1.00E+00 67.79 2.00 6.40
1.00E+00 34.02 2.00 6.40
1.00E+00 11.68 2.00 6.40
1.00E+00 72.51 2.00 6.40
1.00E+00 20.02 2.00 6.40
1.00E+00 49.76 2.00 6.40
1.00E+00 17.53 2.00 6.40 10000 1000
1.00E+00 30.64 2.00 6.40
1.00E+00 18.02 2.00 6.40
1.00E+00 75.15 2.00 6.40
1.00E+00 61.82 2.00 6.40
1.00E+00 42.54 2.00 6.40
1.00E+00 38.21 2.00 6.40
1.00E+00 52.48 2.00 6.40
1.00E+00 69.64 2.00 6.40
1.00E+00 74.39 2.00 6.40 10000 1000
1.00E+00 34.27 2.00 6.40
1.00E+00 70.33 2.00 6.40
1.00E+00 40.92 2.00 6.40
1.00E+00 12.49 2.00 6.40
1.00E+00 42.95 2.00 6.40
1.00E+00 14.28 2.00 6.40
1.00E+00 25.74 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.75E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.54E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.60E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-59
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
V CFS-L06-1314-T01-A 1 2.58E+01
V CFS-L06-1314-T02-A 1 2.78E+01
V CFS-L06-1314-T03-A 1 3.07E+01
V CFS-L06-1314-T04-A 1 3.24E+01
V CFS-L06-1314-T05-A 1 3.25E+01
V CFS-L06-1314-T06-A 1 3.24E+01
V CFS-L06-1314-T07-A 1 3.32E+01
V CFS-L06-1314-T08-A 1 3.25E+01
V CFS-L06-1314-T09-A 1 3.24E+01
V CFS-L06-1314-T01-B 1 2.57E+01
V CFS-L06-1314-T02-B 1 2.65E+01
V CFS-L06-1314-T03-B 1 3.02E+01
V CFS-L06-1314-T04-B 1 3.28E+01
V CFS-L06-1314-T05-B 1 3.31 E+01
V CFS-L06-1314-T06-B 1 3.25E+01
V CFS-L06-1314-T07-B 1 3.30E+01
V CFS-L06-1314-T08-B 1 3.36E+01
V CFS-L06-1314-T09-B 1 3.35E+01
V CFS-L06-1314-T01-C 1 2.45E+01
V CFS-L06-1314-T02-C 1 2.78E+01
V CFS-L06-1314-T03-C 1 2.99E+01
V CFS-L06-1314-T04-C 1 3.13E+01
V CFS-L06-1314-T05-C 1 3.20E+01
V CFS-L06-1314-T06-C 1 3.20E+01
V CFS-L06-1314-T07-C 1 3.30E+01
V CFS-L06-1314-T08-C 1 3.28E+01
V CFS-L06-1314-T09-C 1 3.26E+01
V CFS-L06-1314-B01-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.58E+01 5.46 1.50 4.77
2.78E+01 0.82 1.50 4.77
3.07E+01 3.32 1.50 4.77 10000 1000
3.24E+01 1.86 1.50 4.77
3.25E+01 3.30 1.50 4.77
3.24E+01 3.63 1.50 4.77
3.32E+01 4.19 1.50 4.77
3.25E+01 1.17 1.50 4.77
3.24E+01 1.67 1.50 4.77
2.57E+01 1.61 1.50 4.77
2.65E+01 2.90 1.50 4.77
3.02E+01 1.73 1.50 4.77 10000 1000
3.28E+01 3.22 1.50 4.77
3.31 E+01 0.63 1.50 4.77
3.25E+01 2.06 1.50 4.77
3.30E+01 1.09 1.50 4.77
3.36E+01 2.24 1.50 4.77
3.35E+01 0.99 1.50 4.77
2.45E+01 9.83 1.50 4.77
2.78E+01 3.40 1.50 4.77
2.99E+01 2.78 1.50 4.77 10000 1000
3.13E+01 1.62 1.50 4.77
3.20E+01 1.89 1.50 4.77
3.20E+01 1.70 1.50 4.77
3.30E+01 1.95 1.50 4.77
3.28E+01 3.85 1.50 4.77
3.26E+01 2.04 1.50 4.77
7.50E-01 13.03 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.08E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-60
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Zn CFS-L06-1314-T01-A 1 7.38E+04
Zn CFS-L06-1314-T02-A 1 4.76E+04
Zn CFS-L06-1314-T03-A 1 4.28E+04
Zn CFS-L06-1314-T04-A 1 4.27E+04
Zn CFS-L06-1314-T05-A 1 4.07E+04
Zn CFS-L06-1314-T06-A 1 3.22E+04
Zn CFS-L06-1314-T07-A 1 2.54E+04
Zn CFS-L06-1314-T08-A 1 1.88E+04
Zn CFS-L06-1314-T09-A 1 1.55E+04
Zn CFS-L06-1314-T01-B 1 8.34E+04
Zn CFS-L06-1314-T02-B 1 4.94E+04
Zn CFS-L06-1314-T03-B 1 4.30E+04
Zn CFS-L06-1314-T04-B 1 4.37E+04
Zn CFS-L06-1314-T05-B 1 4.27E+04
Zn CFS-L06-1314-T06-B 1 3.24E+04
Zn CFS-L06-1314-T07-B 1 2.43E+04
Zn CFS-L06-1314-T08-B 1 1.87E+04
Zn CFS-L06-1314-T09-B 1 1.50E+04
Zn CFS-L06-1314-T01-C 1 7.28E+04
Zn CFS-L06-1314-T02-C 1 4.69E+04
Zn CFS-L06-1314-T03-C 1 4.23E+04
Zn CFS-L06-1314-T04-C 1 4.25E+04
Zn CFS-L06-1314-T05-C 1 4.29E+04
Zn CFS-L06-1314-T06-C 1 3.35E+04
Zn CFS-L06-1314-T07-C 1 2.60E+04
Zn CFS-L06-1314-T08-C 1 1.99E+04
Zn CFS-L06-1314-T09-C 1 1.59E+04
Zn CFS-L06-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.38E+04 0.34 1.00 3.18
4.76E+04 0.53 1.00 3.18
4.28E+04 0.43 1.00 3.18 10000 1000
4.27E+04 1.19 1.00 3.18
4.07E+04 0.94 1.00 3.18
3.22E+04 1.87 1.00 3.18
2.54E+04 3.24 1.00 3.18
1.88E+04 1.37 1.00 3.18
1.55E+04 0.38 1.00 3.18
8.34E+04 0.89 1.00 3.18
4.94E+04 0.23 1.00 3.18
4.30E+04 0.12 1.00 3.18 10000 1000
4.37E+04 0.93 1.00 3.18
4.27E+04 1.59 1.00 3.18
3.24E+04 1.50 1.00 3.18
2.43E+04 0.51 1.00 3.18
1.87E+04 1.73 1.00 3.18
1.50E+04 0.50 1.00 3.18
7.28E+04 1.64 1.00 3.18
4.69E+04 2.01 1.00 3.18
4.23E+04 1.46 1.00 3.18 10000 1000
4.25E+04 0.72 1.00 3.18
4.29E+04 0.82 1.00 3.18
3.35E+04 1.46 1.00 3.18
2.60E+04 2.40 1.00 3.18
1.99E+04 2.04 1.00 3.18
1.59E+04 1.45 1.00 3.18
5.00E-01 21.62 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.36E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.39E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.33E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 3:37 PM EPA Interlab L06 1314 CFS
1/2/12 3:38 PM EPA Interlab L06 1314 CFS
1/2/12 3:40 PM EPA Interlab L06 1314 CFS
1/2/12 3:42 PM EPA Interlab L06 1314 CFS
1/2/12 3:43 PM EPA Interlab L06 1314 CFS
1/2/12 3:45 PM EPA Interlab L06 1314 CFS
1/2/12 3:46 PM EPA Interlab L06 1314 CFS
1/2/12 3:48 PM EPA Interlab L06 1314 CFS
1/2/12 3:50 PM EPA Interlab L06 1314 CFS
1/2/12 3:51 PM EPA Interlab L06 1314 CFS
1/2/12 3:53 PM EPA Interlab L06 1314 CFS
1/2/12 3:55 PM EPA Interlab L06 1314 CFS
1/2/12 3:56 PM EPA Interlab L06 1314 CFS
1/2/12 3:58 PM EPA Interlab L06 1314 CFS
1/2/12 4:00 PM EPA Interlab L06 1314 CFS
1/2/12 4:01 PM EPA Interlab L06 1314 CFS
1/2/12 4:03 PM EPA Interlab L06 1314 CFS
1/2/12 4:05 PM EPA Interlab L06 1314 CFS
1/2/12 4:06 PM EPA Interlab L06 1314 CFS
1/2/12 4:08 PM EPA Interlab L06 1314 CFS
1/2/12 4:10 PM EPA Interlab L06 1314 CFS
1/2/12 4:11 PM EPA Interlab L06 1314 CFS
1/2/12 4:13 PM EPA Interlab L06 1314 CFS
1/2/12 4:14 PM EPA Interlab L06 1314 CFS
1/2/12 4:16 PM EPA Interlab L06 1314 CFS
1/2/12 4:18 PM EPA Interlab L06 1314 CFS
1/2/12 4:19 PM EPA Interlab L06 1314 CFS
1/2/12 3:35 PM EPA Interlab L06 1314 CFS
1-61
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1314:
Element Sample ID
Al CFS-L07-1314-T01-A
Al CFS-L07-1314-T02-A
Al CFS-L07-1314-T03-A
Al CFS-L07-1314-T04-A
Al CFS-L07-1314-T05-A
Al CFS-L07-1314-T06-A
Al CFS-L07-1314-T07-A
Al CFS-L07-1314-T08-A
Al CFS-L07-1314-T09-A
Al CFS-L07-1314-T01-B
Al CFS-L07-1314-T02-B
Al CFS-L07-1314-T03-B
Al CFS-L07-1314-T04-B
Al CFS-L07-1314-T05-B
Al CFS-L07-1314-T06-B
Al CFS-L07-1314-T07-B
Al CFS-L07-1314-T08-B
Al CFS-L07-1314-T09-B
Al CFS-L07-1314-T01-C
Al CFS-L07-1314-T02-C
Al CFS-L07-1314-T03-C
Al CFS-L07-1314-T04-C
Al CFS-L07-1314-T05-C
Al CFS-L07-1314-T06-C
Al CFS-L07-1314-T07-C
Al CFS-L07-1314-T08-C
Al CFS-L07-1314-T09-C
Al CFS-L07-1314-B01-A
Dilution Sample
Factor Cone. Qualifier
I ug/L I
1 5.75E+01
1 5.80E+01
1 5.47E+01
1 5.60E+01
1 5.14E+01
1 4.68E+01
1 5.04E+01
1 4.83E+01
1 4.56E+01
1 6.44E+01
1 5.22E+01
1 5.31 E+01
1 5.25E+01
1 5.23E+01
1 4.88E+01
1 4.85E+01
1 5.39E+01
1 5.19E+01
1 6.13E+01
1 5.61 E+01
1 5.51 E+01
1 5.51 E+01
1 5.14E+01
1 5.07E+01
1 5.02E+01
1 4.97E+01
1 5.68E+01
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.75E+01 6.52 1.00 3.18
5.80E+01 1.93 1.00 3.18
5.47E+01 7.34 1.00 3.18 10000 1000
5.60E+01 1.88 1.00 3.18
5.14E+01 5.73 1.00 3.18
4.68E+01 4.54 1.00 3.18
5.04E+01 2.47 1.00 3.18
4.83E+01 5.25 1.00 3.18
4.56E+01 1.32 1.00 3.18
6.44E+01 3.88 1.00 3.18
5.22E+01 1.51 1.00 3.18
5.31E+01 1.18 1.00 3.18 10000 1000
5.25E+01 7.78 1.00 3.18
5.23E+01 8.31 1.00 3.18
4.88E+01 2.03 1.00 3.18
4.85E+01 4.74 1.00 3.18
5.39E+01 8.18 1.00 3.18
5.19E+01 3.43 1.00 3.18
6.13E+01 4.37 1.00 3.18
5.61E+01 7.53 1.00 3.18
5.51E+01 2.76 1.00 3.18 10000 1000
5.51E+01 4.55 1.00 3.18
5.14E+01 2.75 1.00 3.18
5.07E+01 4.78 1.00 3.18
5.02E+01 2.08 1.00 3.18
4.97E+01 3.14 1.00 3.18
5.68E+01 7.18 1.00 3.18
5.00E-01 15.75 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.09E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-62
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L
Sb CFS-L07-1314-T01-A 1 4.31E+01
Sb CFS-L07-1314-T02-A 1 3.88E+01
Sb CFS-L07-1314-T03-A 1 2.07E+01 E
Sb CFS-L07-1314-T04-A 1 2.55E+01
Sb CFS-L07-1314-T05-A 1 2.37E+01 E
Sb CFS-L07-1314-T06-A 1 1.51E+01 E
Sb CFS-L07-1314-T07-A 1 1.99E+01 E
Sb CFS-L07-1314-T08-A 1 1.78E+01 E
Sb CFS-L07-1314-T09-A 1 1.36E+01 E
Sb CFS-L07-1314-T01-B 1 4.31E+01
Sb CFS-L07-1314-T02-B 1 2.90E+01
Sb CFS-L07-1314-T03-B 1 2.18E+01 E
Sb CFS-L07-1314-T04-B 1 2.35E+01 E
Sb CFS-L07-1314-T05-B 1 1.78E+01 E
Sb CFS-L07-1314-T06-B 1 2.01E+01 E
Sb CFS-L07-1314-T07-B 1 2.17E+01 E
Sb CFS-L07-1314-T08-B 1 1.53E+01 E
Sb CFS-L07-1314-T09-B 1 1.56E+01 E
Sb CFS-L07-1314-T01-C 1 5.87E+01
Sb CFS-L07-1314-T02-C 1 2.91E+01
Sb CFS-L07-1314-T03-C 1 2.13E+01 E
Sb CFS-L07-1314-T04-C 1 2.22E+01 E
Sb CFS-L07-1314-T05-C 1 3.08E+01
Sb CFS-L07-1314-T06-C 1 1.85E+01 E
Sb CFS-L07-1314-T07-C 1 2.01 E+01 E
Sb CFS-L07-1314-T08-C 1 1.80E+01 E
Sb CFS-L07-1314-T09-C 1 1.33E+01 E
Sb CFS-L07-1314-B01-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.31 E+01 2.84 7.50 23.90
3.88E+01 1.87 7.50 23.90
2.07E+01 15.09 7.50 23.90 10000 1000
2.55E+01 7.89 7.50 23.90
2.37E+01 10.03 7.50 23.90
1.51 E+01 3.25 7.50 23.90
1.99E+01 10.00 7.50 23.90
1.78E+01 11.16 7.50 23.90
1.36E+01 6.35 7.50 23.90
4.31 E+01 5.42 7.50 23.90
2.90E+01 4.57 7.50 23.90
2.18E+01 21.23 7.50 23.90 10000 1000
2.35E+01 17.69 7.50 23.90
1.78E+01 11.83 7.50 23.90
2. 01 E+01 21.26 7.50 23.90
2.17E+01 27.99 7.50 23.90
1.53E+01 23.15 7.50 23.90
1.56E+01 20.21 7.50 23.90
5.87E+01 2.06 7.50 23.90
2. 91 E+01 3.92 7.50 23.90
2.13E+01 19.65 7.50 23.90 10000 1000
2.22E+01 22.86 7.50 23.90
3.08E+01 10.36 7.50 23.90
1.85E+01 18.68 7.50 23.90
2.01E+01 15.11 7.50 23.90
1.80E+01 5.92 7.50 23.90
1.33E+01 6.84 7.50 23.90
3.75E+00 10.27 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.07E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-63
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L
As CFS-L07-1314-T01-A 1 3.79E+01
As CFS-L07-1314-T02-A 1 2.61 E+01 E
As CFS-L07-1314-T03-A 1 1.18E+01 E
As CFS-L07-1314-T04-A 1 1.18E+01 E
As CFS-L07-1314-T05-A 1 5.50E+00 U1/2
As CFS-L07-1314-T06-A 1 5.50E+00 U1/2
As CFS-L07-1314-T07-A 1 5.50E+00 U1/2
As CFS-L07-1314-T08-A 1 5.50E+00 U1/2
As CFS-L07-1314-T09-A 1 5.50E+00 U1/2
As CFS-L07-1314-T01-B 1 4.43E+01
As CFS-L07-1314-T02-B 1 1.92E+01 E
As CFS-L07-1314-T03-B 1 5.50E+00 U1/2
As CFS-L07-1314-T04-B 1 5.50E+00 U1/2
As CFS-L07-1314-T05-B 1 5.50E+00 U1/2
As CFS-L07-1314-T06-B 1 5.50E+00 U1/2
As CFS-L07-1314-T07-B 1 5.50E+00 U1/2
As CFS-L07-1314-T08-B 1 5.50E+00 U1/2
As CFS-L07-1314-T09-B 1 5.50E+00 U1/2
As CFS-L07-1314-T01-C 1 5.41E+01
As CFS-L07-1314-T02-C 1 2.18E+01 E
As CFS-L07-1314-T03-C 1 1.36E+01 E
As CFS-L07-1314-T04-C 1 5.50E+00 U1/2
As CFS-L07-1314-T05-C 1 5.50E+00 U1/2
As CFS-L07-1314-T06-C 1 5.50E+00 U1/2
As CFS-L07-1314-T07-C 1 5.50E+00 U1/2
As CFS-L07-1314-T08-C 1 5.50E+00 U1/2
As CFS-L07-1314-T09-C 1 5.50E+00 U1/2
As CFS-L07-1314-B01-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.79E+01 6.56 11.00 35.00
2.61E+01 3.37 11.00 35.00
1.18E+01 1.57 11.00 35.00 10000 1000
1.18E+01 6.65 11.00 35.00
5.50E+00 26.90 11.00 35.00
5.50E+00 22.75 11.00 35.00
5.50E+00 6.90 11.00 35.00
5.50E+00 15.40 11.00 35.00
5.50E+00 7.80 11.00 35.00
4.43E+01 4.74 11.00 35.00
1.92E+01 3.29 11.00 35.00
5.50E+00 18.71 11.00 35.00 10000 1000
5.50E+00 25.59 11.00 35.00
5.50E+00 22.56 11.00 35.00
5.50E+00 10.50 11.00 35.00
5.50E+00 27.06 11.00 35.00
5.50E+00 19.89 11.00 35.00
5.50E+00 12.25 11.00 35.00
5.41E+01 2.42 11.00 35.00
2.18E+01 8.56 11.00 35.00
1.36E+01 8.05 11.00 35.00 10000 1000
5.50E+00 11.28 11.00 35.00
5.50E+00 9.55 11.00 35.00
5.50E+00 20.99 11.00 35.00
5.50E+00 17.89 11.00 35.00
5.50E+00 6.02 11.00 35.00
5.50E+00 8.03 11.00 35.00
5.50E+00 19.21 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.87E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.55E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.79E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-64
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
B CFS-L07-1314-T01-A 1 1.64E+03
B CFS-L07-1314-T02-A 1 1.37E+03
B CFS-L07-1314-T03-A 1 7.19E+02
B CFS-L07-1314-T04-A 1 3.80E+02
B CFS-L07-1314-T05-A 1 2.48E+02
B CFS-L07-1314-T06-A 1 1.26E+02
B CFS-L07-1314-T07-A 1 9.22E+01
B CFS-L07-1314-T08-A 1 6.39E+01
B CFS-L07-1314-T09-A 1 3.95E+01
B CFS-L07-1314-T01-B 1 1.66E+03
B CFS-L07-1314-T02-B 1 1.07E+03
B CFS-L07-1314-T03-B 1 6.42E+02
B CFS-L07-1314-T04-B 1 3.31 E+02
B CFS-L07-1314-T05-B 1 2.27E+02
B CFS-L07-1314-T06-B 1 1.12E+02
B CFS-L07-1314-T07-B 1 8.77E+01
B CFS-L07-1314-T08-B 1 6.15E+01
B CFS-L07-1314-T09-B 1 4.55E+01
B CFS-L07-1314-T01-C 1 1.86E+03
B CFS-L07-1314-T02-C 1 1.36E+03
B CFS-L07-1314-T03-C 1 6.55E+02
B CFS-L07-1314-T04-C 1 3.30E+02
B CFS-L07-1314-T05-C 1 2.28E+02
B CFS-L07-1314-T06-C 1 1.18E+02
B CFS-L07-1314-T07-C 1 8.87E+01
B CFS-L07-1314-T08-C 1 6.37E+01
B CFS-L07-1314-T09-C 1 4.68E+01
B CFS-L07-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.64E+03 0.76 1.00 3.18
1.37E+03 0.62 1.00 3.18
7.19E+02 0.23 1.00 3.18 10000 1000
3.80E+02 0.83 1.00 3.18
2.48E+02 0.69 1.00 3.18
1.26E+02 1.34 1.00 3.18
9.22E+01 3.14 1.00 3.18
6.39E+01 0.50 1.00 3.18
3.95E+01 3.20 1.00 3.18
1.66E+03 0.72 1.00 3.18
1.07E+03 1.74 1.00 3.18
6.42E+02 0.52 1.00 3.18 10000 1000
3.31E+02 0.70 1.00 3.18
2.27E+02 1.43 1.00 3.18
1.12E+02 0.82 1.00 3.18
8.77E+01 0.75 1.00 3.18
6.15E+01 1.49 1.00 3.18
4.55E+01 0.54 1.00 3.18
1.86E+03 0.51 1.00 3.18
1.36E+03 0.79 1.00 3.18
6.55E+02 1.15 1.00 3.18 10000 1000
3.30E+02 4.42 1.00 3.18
2.28E+02 1.69 1.00 3.18
1.18E+02 0.36 1.00 3.18
8.87E+01 1.33 1.00 3.18
6.37E+01 1.37 1.00 3.18
4.68E+01 3.14 1.00 3.18
5.00E-01 1.77 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.64E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.54E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.62E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-65
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Ba CFS-L07-1314-T01-A 1 5.60E+01
Ba CFS-L07-1314-T02-A 1 5.62E+01
Ba CFS-L07-1314-T03-A 1 7.04E+01
Ba CFS-L07-1314-T04-A 1 7.44E+01
Ba CFS-L07-1314-T05-A 1 7.81 E+01
Ba CFS-L07-1314-T06-A 1 8.00E+01
Ba CFS-L07-1314-T07-A 1 8.65E+01
Ba CFS-L07-1314-T08-A 1 8.95E+01
Ba CFS-L07-1314-T09-A 1 7.50E+01
Ba CFS-L07-1314-T01-B 1 5.24E+01
Ba CFS-L07-1314-T02-B 1 5.39E+01
Ba CFS-L07-1314-T03-B 1 7.45E+01
Ba CFS-L07-1314-T04-B 1 7.81 E+01
Ba CFS-L07-1314-T05-B 1 8.16E+01
Ba CFS-L07-1314-T06-B 1 8.13E+01
Ba CFS-L07-1314-T07-B 1 8.90E+01
Ba CFS-L07-1314-T08-B 1 9.00E+01
Ba CFS-L07-1314-T09-B 1 9.36E+01
Ba CFS-L07-1314-T01-C 1 5.09E+01
Ba CFS-L07-1314-T02-C 1 5.88E+01
Ba CFS-L07-1314-T03-C 1 7.16E+01
Ba CFS-L07-1314-T04-C 1 7.44E+01
Ba CFS-L07-1314-T05-C 1 7.73E+01
Ba CFS-L07-1314-T06-C 1 8.05E+01
Ba CFS-L07-1314-T07-C 1 8.68E+01
Ba CFS-L07-1314-T08-C 1 9.08E+01
Ba CFS-L07-1314-T09-C 1 9.49E+01
Ba CFS-L07-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.60E+01 0.92 1.00 3.18
5.62E+01 1.39 1.00 3.18
7.04E+01 0.60 1.00 3.18 10000 1000
7.44E+01 0.78 1.00 3.18
7.81E+01 0.47 1.00 3.18
8.00E+01 1.07 1.00 3.18
8.65E+01 0.24 1.00 3.18
8.95E+01 0.88 1.00 3.18
7.50E+01 0.83 1.00 3.18
5.24E+01 1.08 1.00 3.18
5.39E+01 1.76 1.00 3.18
7.45E+01 0.88 1.00 3.18 10000 1000
7.81E+01 0.75 1.00 3.18
8.16E+01 1.35 1.00 3.18
8.13E+01 0.42 1.00 3.18
8.90E+01 0.54 1.00 3.18
9.00E+01 1.31 1.00 3.18
9.36E+01 1.01 1.00 3.18
5.09E+01 1.57 1.00 3.18
5.88E+01 0.39 1.00 3.18
7.16E+01 1.77 1.00 3.18 10000 1000
7.44E+01 4.45 1.00 3.18
7.73E+01 1.31 1.00 3.18
8.05E+01 0.66 1.00 3.18
8.68E+01 0.58 1.00 3.18
9.08E+01 0.70 1.00 3.18
9.49E+01 0.38 1.00 3.18
5.00E-01 9.77 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.06E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-66
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Be CFS-L07-1314-T01-A 1 9.50E-01 U1/2
Be CFS-L07-1314-T02-A 1 9.50E-01 U1/2
Be CFS-L07-1314-T03-A 1 9.50E-01 U1/2
Be CFS-L07-1314-T04-A 1 9.50E-01 U1/2
Be CFS-L07-1314-T05-A 1 9.50E-01 U1/2
Be CFS-L07-1314-T06-A 1 9.50E-01 U1/2
Be CFS-L07-1314-T07-A 1 9.50E-01 U1/2
Be CFS-L07-1314-T08-A 1 9.50E-01 U1/2
Be CFS-L07-1314-T09-A 1 9.50E-01 U1/2
Be CFS-L07-1314-T01-B 1 9.50E-01 U1/2
Be CFS-L07-1314-T02-B 1 9.50E-01 U1/2
Be CFS-L07-1314-T03-B 1 9.50E-01 U1/2
Be CFS-L07-1314-T04-B 1 9.50E-01 U1/2
Be CFS-L07-1314-T05-B 1 9.50E-01 U1/2
Be CFS-L07-1314-T06-B 1 9.50E-01 U1/2
Be CFS-L07-1314-T07-B 1 9.50E-01 U1/2
Be CFS-L07-1314-T08-B 1 9.50E-01 U1/2
Be CFS-L07-1314-T09-B 1 9.50E-01 U1/2
Be CFS-L07-1314-T01-C 1 9.50E-01 U1/2
Be CFS-L07-1314-T02-C 1 9.50E-01 U1/2
Be CFS-L07-1314-T03-C 1 9.50E-01 U1/2
Be CFS-L07-1314-T04-C 1 9.50E-01 U1/2
Be CFS-L07-1314-T05-C 1 9.50E-01 U1/2
Be CFS-L07-1314-T06-C 1 9.50E-01 U1/2
Be CFS-L07-1314-T07-C 1 9.50E-01 U1/2
Be CFS-L07-1314-T08-C 1 9.50E-01 U1/2
Be CFS-L07-1314-T09-C 1 9.50E-01 U1/2
Be CFS-L07-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 7.27 1.90 6.00
9.50E-01 18.99 1.90 6.00
9.50E-01 11.09 1.90 6.00 10000 1000
9.50E-01 32.34 1.90 6.00
9.50E-01 18.20 1.90 6.00
9.50E-01 12.92 1.90 6.00
9.50E-01 27.42 1.90 6.00
9.50E-01 20.11 1.90 6.00
9.50E-01 37.21 1.90 6.00
9.50E-01 3.84 1.90 6.00
9.50E-01 10.13 1.90 6.00
9.50E-01 29.20 1.90 6.00 10000 1000
9.50E-01 8.37 1.90 6.00
9.50E-01 13.12 1.90 6.00
9.50E-01 27.02 1.90 6.00
9.50E-01 4.42 1.90 6.00
9.50E-01 22.10 1.90 6.00
9.50E-01 8.95 1.90 6.00
9.50E-01 9.18 1.90 6.00
9.50E-01 12.10 1.90 6.00
9.50E-01 21.37 1.90 6.00 10000 1000
9.50E-01 28.71 1.90 6.00
9.50E-01 32.31 1.90 6.00
9.50E-01 19.42 1.90 6.00
9.50E-01 23.21 1.90 6.00
9.50E-01 22.42 1.90 6.00
9.50E-01 4.31 1.90 6.00
9.50E-01 30.98 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.10E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.13E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-67
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Cd CFS-L07-1314-T01-A 1 1.16E+04
Cd CFS-L07-1314-T02-A 1 9.29E+03
Cd CFS-L07-1314-T03-A 1 7.05E+03
Cd CFS-L07-1314-T04-A 1 6.96E+03
Cd CFS-L07-1314-T05-A 1 7.09E+03
Cd CFS-L07-1314-T06-A 1 6.46E+03
Cd CFS-L07-1314-T07-A 1 5.63E+03
Cd CFS-L07-1314-T08-A 1 4.43E+03
Cd CFS-L07-1314-T09-A 1 2.83E+03
Cd CFS-L07-1314-T01-B 1 1.16E+04
Cd CFS-L07-1314-T02-B 1 6.30E+03
Cd CFS-L07-1314-T03-B 1 6.56E+03
Cd CFS-L07-1314-T04-B 1 6.66E+03
Cd CFS-L07-1314-T05-B 1 6.86E+03
Cd CFS-L07-1314-T06-B 1 6.13E+03
Cd CFS-L07-1314-T07-B 1 5.52E+03
Cd CFS-L07-1314-T08-B 1 4.32E+03
Cd CFS-L07-1314-T09-B 1 3.49E+03
Cd CFS-L07-1314-T01-C 1 1.38E+04
Cd CFS-L07-1314-T02-C 1 8.51 E+03
Cd CFS-L07-1314-T03-C 1 7.23E+03
Cd CFS-L07-1314-T04-C 1 7.20E+03
Cd CFS-L07-1314-T05-C 1 7.49E+03
Cd CFS-L07-1314-T06-C 1 6.72E+03
Cd CFS-L07-1314-T07-C 1 5.73E+03
Cd CFS-L07-1314-T08-C 1 4.41 E+03
Cd CFS-L07-1314-T09-C 1 3.37E+03
Cd CFS-L07-1314-B01-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.16E+04 0.26 2.20 7.00
9.29E+03 0.71 2.20 7.00
7.05E+03 0.25 2.20 7.00 10000 1000
6.96E+03 1.12 2.20 7.00
7.09E+03 0.09 2.20 7.00
6.46E+03 1.09 2.20 7.00
5.63E+03 0.09 2.20 7.00
4.43E+03 0.53 2.20 7.00
2.83E+03 1.59 2.20 7.00
1.16E+04 0.92 2.20 7.00
6.30E+03 2.80 2.20 7.00
6.56E+03 0.87 2.20 7.00 10000 1000
6.66E+03 0.39 2.20 7.00
6.86E+03 1.10 2.20 7.00
6.13E+03 0.25 2.20 7.00
5.52E+03 0.65 2.20 7.00
4.32E+03 0.25 2.20 7.00
3.49E+03 0.99 2.20 7.00
1.38E+04 0.90 2.20 7.00
8.51 E+03 0.45 2.20 7.00
7.23E+03 1.10 2.20 7.00 10000 1000
7.20E+03 4.71 2.20 7.00
7.49E+03 0.87 2.20 7.00
6.72E+03 0.45 2.20 7.00
5.73E+03 0.80 2.20 7.00
4.41 E+03 0.30 2.20 7.00
3.37E+03 0.26 2.20 7.00
1.10E+00 28.22 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
7.98E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.52E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.28E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-68
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
Ca CFS-L07-1314-T01-A 1 3.81E+05
Ca CFS-L07-1314-T02-A 1 4.03E+05
Ca CFS-L07-1314-T03-A 1 4.62E+05
Ca CFS-L07-1314-T04-A 1 4.95E+05
Ca CFS-L07-1314-T05-A 1 5.10E+05
Ca CFS-L07-1314-T06-A 1 5.24E+05
Ca CFS-L07-1314-T07-A 1 5.27E+05
Ca CFS-L07-1314-T08-A 1 5.27E+05
Ca CFS-L07-1314-T09-A 1 4.17E+05
Ca CFS-L07-1314-T01-B 1 3.75E+05
Ca CFS-L07-1314-T02-B 1 3.45E+05
Ca CFS-L07-1314-T03-B 1 4.72E+05
Ca CFS-L07-1314-T04-B 1 5.03E+05
Ca CFS-L07-1314-T05-B 1 5.17E+05
Ca CFS-L07-1314-T06-B 1 5.12E+05
Ca CFS-L07-1314-T07-B 1 5.30E+05
Ca CFS-L07-1314-T08-B 1 5.26E+05
Ca CFS-L07-1314-T09-B 1 5.28E+05
Ca CFS-L07-1314-T01-C 1 3.71E+05
Ca CFS-L07-1314-T02-C 1 4.06E+05
Ca CFS-L07-1314-T03-C 1 4.72E+05
Ca CFS-L07-1314-T04-C 1 4.97E+05
Ca CFS-L07-1314-T05-C 1 5.14E+05
Ca CFS-L07-1314-T06-C 1 5.18E+05
Ca CFS-L07-1314-T07-C 1 5.23E+05
Ca CFS-L07-1314-T08-C 1 5.24E+05
Ca CFS-L07-1314-T09-C 1 5.24E+05
Ca CFS-L07-1314-B01-A 1 1.30E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.81 E+05 0.51 2.60 8.30
4.03E+05 0.41 2.60 8.30
4.62E+05 0.31 2.60 8.30 10000 1000
4.95E+05 0.97 2.60 8.30
5.10E+05 0.02 2.60 8.30
5.24E+05 1.04 2.60 8.30
5.27E+05 0.13 2.60 8.30
5.27E+05 0.85 2.60 8.30
4.17E+05 0.94 2.60 8.30
3.75E+05 0.60 2.60 8.30
3.45E+05 1.21 2.60 8.30
4.72E+05 0.68 2.60 8.30 10000 1000
5.03E+05 0.23 2.60 8.30
5.17E+05 1.41 2.60 8.30
5.12E+05 0.20 2.60 8.30
5.30E+05 0.85 2.60 8.30
5.26E+05 0.41 2.60 8.30
5.28E+05 0.65 2.60 8.30
3.71 E+05 0.73 2.60 8.30
4.06E+05 0.39 2.60 8.30
4.72E+05 0.86 2.60 8.30 10000 1000
4.97E+05 4.63 2.60 8.30
5.14E+05 1.00 2.60 8.30
5.18E+05 0.51 2.60 8.30
5.23E+05 0.67 2.60 8.30
5.24E+05 0.54 2.60 8.30
5.24E+05 0.39 2.60 8.30
1.30E+00 15.67 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.63E+05 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.73E+05 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.73E+05 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-69
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Cr CFS-L07-1314-T01-A 1 6.00E-01 U1/2
Cr CFS-L07-1314-T02-A 1 6.00E-01 U1/2
Cr CFS-L07-1314-T03-A 1 6.00E-01 U1/2
Cr CFS-L07-1314-T04-A 1 6.00E-01 U1/2
Cr CFS-L07-1314-T05-A 1 6.00E-01 U1/2
Cr CFS-L07-1314-T06-A 1 6.00E-01 U1/2
Cr CFS-L07-1314-T07-A 1 6.00E-01 U1/2
Cr CFS-L07-1314-T08-A 1 6.00E-01 U1/2
Cr CFS-L07-1314-T09-A 1 6.00E-01 U1/2
Cr CFS-L07-1314-T01-B 1 6.00E-01 U1/2
Cr CFS-L07-1314-T02-B 1 6.00E-01 U1/2
Cr CFS-L07-1314-T03-B 1 6.00E-01 U1/2
Cr CFS-L07-1314-T04-B 1 6.00E-01 U1/2
Cr CFS-L07-1314-T05-B 1 6.00E-01 U1/2
Cr CFS-L07-1314-T06-B 1 6.00E-01 U1/2
Cr CFS-L07-1314-T07-B 1 6.00E-01 U1/2
Cr CFS-L07-1314-T08-B 1 6.00E-01 U1/2
Cr CFS-L07-1314-T09-B 1 6.00E-01 U1/2
Cr CFS-L07-1314-T01-C 1 6.00E-01 U1/2
Cr CFS-L07-1314-T02-C 1 6.00E-01 U1/2
Cr CFS-L07-1314-T03-C 1 6.00E-01 U1/2
Cr CFS-L07-1314-T04-C 1 6.00E-01 U1/2
Cr CFS-L07-1314-T05-C 1 6.00E-01 U1/2
Cr CFS-L07-1314-T06-C 1 6.00E-01 U1/2
Cr CFS-L07-1314-T07-C 1 6.00E-01 U1/2
Cr CFS-L07-1314-T08-C 1 6.00E-01 U1/2
Cr CFS-L07-1314-T09-C 1 6.00E-01 U1/2
Cr CFS-L07-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 10.24 1.20 3.82
6.00E-01 21.53 1.20 3.82
6.00E-01 13.58 1.20 3.82 10000 1000
6.00E-01 5.56 1.20 3.82
6.00E-01 3.77 1.20 3.82
6.00E-01 20.04 1.20 3.82
6.00E-01 18.08 1.20 3.82
6.00E-01 13.72 1.20 3.82
6.00E-01 7.58 1.20 3.82
6.00E-01 2.59 1.20 3.82
6.00E-01 5.46 1.20 3.82
6.00E-01 14.15 1.20 3.82 10000 1000
6.00E-01 18.29 1.20 3.82
6.00E-01 6.04 1.20 3.82
6.00E-01 6.72 1.20 3.82
6.00E-01 7.62 1.20 3.82
6.00E-01 17.63 1.20 3.82
6.00E-01 20.69 1.20 3.82
6.00E-01 13.32 1.20 3.82
6.00E-01 14.10 1.20 3.82
6.00E-01 7.88 1.20 3.82 10000 1000
6.00E-01 14.36 1.20 3.82
6.00E-01 7.63 1.20 3.82
6.00E-01 5.71 1.20 3.82
6.00E-01 18.48 1.20 3.82
6.00E-01 12.35 1.20 3.82
6.00E-01 7.92 1.20 3.82
6.00E-01 5.68 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.07E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-70
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Co CFS-L07-1314-T01-A 1 4.08E+02
Co CFS-L07-1314-T02-A 1 3.08E+02
Co CFS-L07-1314-T03-A 1 2.16E+02
Co CFS-L07-1314-T04-A 1 2.00E+02
Co CFS-L07-1314-T05-A 1 1.98E+02
Co CFS-L07-1314-T06-A 1 1.36E+02
Co CFS-L07-1314-T07-A 1 8.24E+01
Co CFS-L07-1314-T08-A 1 4.85E+01
Co CFS-L07-1314-T09-A 1 2.42E+01
Co CFS-L07-1314-T01-B 1 4.06E+02
Co CFS-L07-1314-T02-B 1 2.03E+02
Co CFS-L07-1314-T03-B 1 1.98E+02
Co CFS-L07-1314-T04-B 1 1.91E+02
Co CFS-L07-1314-T05-B 1 1.89E+02
Co CFS-L07-1314-T06-B 1 1.26E+02
Co CFS-L07-1314-T07-B 1 7.48E+01
Co CFS-L07-1314-T08-B 1 4.53E+01
Co CFS-L07-1314-T09-B 1 2.89E+01
Co CFS-L07-1314-T01-C 1 5.25E+02
Co CFS-L07-1314-T02-C 1 2.97E+02
Co CFS-L07-1314-T03-C 1 2.30E+02
Co CFS-L07-1314-T04-C 1 2.21E+02
Co CFS-L07-1314-T05-C 1 2.23E+02
Co CFS-L07-1314-T06-C 1 1.38E+02
Co CFS-L07-1314-T07-C 1 7.41 E+01
Co CFS-L07-1314-T08-C 1 4.56E+01
Co CFS-L07-1314-T09-C 1 2.85E+01
Co CFS-L07-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.08E+02 0.50 1.80 5.72
3.08E+02 0.76 1.80 5.72
2.16E+02 0.82 1.80 5.72 10000 1000
2.00E+02 0.80 1.80 5.72
1.98E+02 0.40 1.80 5.72
1.36E+02 0.66 1.80 5.72
8.24E+01 0.34 1.80 5.72
4.85E+01 1.37 1.80 5.72
2.42E+01 1.04 1.80 5.72
4.06E+02 0.73 1.80 5.72
2.03E+02 2.62 1.80 5.72
1.98E+02 1.37 1.80 5.72 10000 1000
1.91E+02 0.79 1.80 5.72
1.89E+02 0.90 1.80 5.72
1.26E+02 0.44 1.80 5.72
7.48E+01 0.83 1.80 5.72
4.53E+01 1.78 1.80 5.72
2.89E+01 2.35 1.80 5.72
5.25E+02 1.11 1.80 5.72
2.97E+02 0.57 1.80 5.72
2.30E+02 0.94 1.80 5.72 10000 1000
2.21 E+02 4.25 1.80 5.72
2.23E+02 0.84 1.80 5.72
1.38E+02 0.91 1.80 5.72
7.41E+01 0.80 1.80 5.72
4.56E+01 1.96 1.80 5.72
2.85E+01 1.63 1.80 5.72
9.00E-01 10.70 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.20E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-71
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Cu CFS-L07-1314-T01-A 1 1.54E+03
Cu CFS-L07-1314-T02-A 1 1.60E+03
Cu CFS-L07-1314-T03-A 1 1.23E+03
Cu CFS-L07-1314-T04-A 1 1.19E+03
Cu CFS-L07-1314-T05-A 1 1.19E+03
Cu CFS-L07-1314-T06-A 1 1.12E+03
Cu CFS-L07-1314-T07-A 1 1.02E+03
Cu CFS-L07-1314-T08-A 1 8.04E+02
Cu CFS-L07-1314-T09-A 1 5.93E+02
Cu CFS-L07-1314-T01-B 1 1.31E+03
Cu CFS-L07-1314-T02-B 1 9.72E+02
Cu CFS-L07-1314-T03-B 1 1.00E+03
Cu CFS-L07-1314-T04-B 1 1.06E+03
Cu CFS-L07-1314-T05-B 1 1.06E+03
Cu CFS-L07-1314-T06-B 1 1.02E+03
Cu CFS-L07-1314-T07-B 1 9.34E+02
Cu CFS-L07-1314-T08-B 1 7.93E+02
Cu CFS-L07-1314-T09-B 1 6.77E+02
Cu CFS-L07-1314-T01-C 1 1.75E+03
Cu CFS-L07-1314-T02-C 1 1.40E+03
Cu CFS-L07-1314-T03-C 1 1.25E+03
Cu CFS-L07-1314-T04-C 1 1.27E+03
Cu CFS-L07-1314-T05-C 1 1.27E+03
Cu CFS-L07-1314-T06-C 1 1.16E+03
Cu CFS-L07-1314-T07-C 1 9.98E+02
Cu CFS-L07-1314-T08-C 1 7.99E+02
Cu CFS-L07-1314-T09-C 1 6.67E+02
Cu CFS-L07-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.54E+03 0.87 3.70 11.80
1.60E+03 0.42 3.70 11.80
1.23E+03 1.65 3.70 11.80 10000 1000
1.19E+03 1.07 3.70 11.80
1.19E+03 1.11 3.70 11.80
1.12E+03 0.90 3.70 11.80
1.02E+03 0.52 3.70 11.80
8.04E+02 1.75 3.70 11.80
5.93E+02 3.83 3.70 11.80
1.31E+03 0.97 3.70 11.80
972E+02 2.47 3.70 11.80
1.00E+03 1.64 3.70 11.80 10000 1000
1.06E+03 0.76 3.70 11.80
1.06E+03 0.66 3.70 11.80
1.02E+03 0.54 3.70 11.80
9.34E+02 1.12 3.70 11.80
7.93E+02 0.58 3.70 11.80
6.77E+02 0.54 3.70 11.80
1.75E+03 0.98 3.70 11.80
1.40E+03 0.46 3.70 11.80
1.25E+03 0.08 3.70 11.80 10000 1000
1.27E+03 5.73 3.70 11.80
1.27E+03 0.30 3.70 11.80
1.16E+03 0.59 3.70 11.80
9.98E+02 1.08 3.70 11.80
7.99E+02 0.88 3.70 11.80
6.67E+02 0.87 3.70 11.80
1.85E+00 13.48 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.24E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.08E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.22E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-72
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Fe CFS-L07-1314-T01-A 1 1.00E+00 U1/2
Fe CFS-L07-1314-T02-A 1 3.69E+00 E
Fe CFS-L07-1314-T03-A 1 1.00E+00 U1/2
Fe CFS-L07-1314-T04-A 1 1.00E+00 U1/2
Fe CFS-L07-1314-T05-A 1 1.00E+00 U1/2
Fe CFS-L07-1314-T06-A 1 1.00E+00 U1/2
Fe CFS-L07-1314-T07-A 1 1.00E+00 U1/2
Fe CFS-L07-1314-T08-A 1 1.00E+00 U1/2
Fe CFS-L07-1314-T09-A 1 1.00E+00 U1/2
Fe CFS-L07-1314-T01-B 1 1.00E+00 U1/2
Fe CFS-L07-1314-T02-B 1 1.00E+00 U1/2
Fe CFS-L07-1314-T03-B 1 1.00E+00 U1/2
Fe CFS-L07-1314-T04-B 1 1.00E+00 U1/2
Fe CFS-L07-1314-T05-B 1 1.00E+00 U1/2
Fe CFS-L07-1314-T06-B 1 1.00E+00 U1/2
Fe CFS-L07-1314-T07-B 1 1.00E+00 U1/2
Fe CFS-L07-1314-T08-B 1 1.00E+00 U1/2
Fe CFS-L07-1314-T09-B 1 1.00E+00 U1/2
Fe CFS-L07-1314-T01-C 1 2.78E+00 E
Fe CFS-L07-1314-T02-C 1 1.00E+00 U1/2
Fe CFS-L07-1314-T03-C 1 2.67E+00 E
Fe CFS-L07-1314-T04-C 1 1.00E+00 U1/2
Fe CFS-L07-1314-T05-C 1 1.00E+00 U1/2
Fe CFS-L07-1314-T06-C 1 1.00E+00 U1/2
Fe CFS-L07-1314-T07-C 1 1.00E+00 U1/2
Fe CFS-L07-1314-T08-C 1 1.00E+00 U1/2
Fe CFS-L07-1314-T09-C 1 1.00E+00 U1/2
Fe CFS-L07-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 10.31 2.00 6.40
3.69E+00 5.26 2.00 6.40
1.00E+00 4.66 2.00 6.40 10000 1000
1.00E+00 12.98 2.00 6.40
1.00E+00 16.68 2.00 6.40
1.00E+00 6.21 2.00 6.40
1.00E+00 14.16 2.00 6.40
1.00E+00 7.12 2.00 6.40
1.00E+00 3.30 2.00 6.40
1.00E+00 7.31 2.00 6.40
1.00E+00 10.43 2.00 6.40
1.00E+00 13.38 2.00 6.40 10000 1000
1.00E+00 11.62 2.00 6.40
1.00E+00 7.14 2.00 6.40
1.00E+00 1.87 2.00 6.40
1.00E+00 9.35 2.00 6.40
1.00E+00 8.69 2.00 6.40
1.00E+00 21.56 2.00 6.40
2.78E+00 12.93 2.00 6.40
1.00E+00 16.75 2.00 6.40
2.67E+00 8.17 2.00 6.40 10000 1000
1.00E+00 9.09 2.00 6.40
1.00E+00 17.54 2.00 6.40
1.00E+00 20.97 2.00 6.40
1.00E+00 1.45 2.00 6.40
1.00E+00 22.90 2.00 6.40
1.00E+00 14.23 2.00 6.40
1.00E+00 11.12 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-73
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Pb CFS-L07-1314-T01-A 1 6.48E+02
Pb CFS-L07-1314-T02-A 1 8.30E+02
Pb CFS-L07-1314-T03-A 1 7.00E+02
Pb CFS-L07-1314-T04-A 1 6.69E+02
Pb CFS-L07-1314-T05-A 1 7.44E+02
Pb CFS-L07-1314-T06-A 1 8.81 E+02
Pb CFS-L07-1314-T07-A 1 8.84E+02
Pb CFS-L07-1314-T08-A 1 8.24E+02
Pb CFS-L07-1314-T09-A 1 5.99E+02
Pb CFS-L07-1314-T01-B 1 6.65E+02
Pb CFS-L07-1314-T02-B 1 5.22E+02
Pb CFS-L07-1314-T03-B 1 6.31 E+02
Pb CFS-L07-1314-T04-B 1 7.28E+02
Pb CFS-L07-1314-T05-B 1 8.31 E+02
Pb CFS-L07-1314-T06-B 1 8.59E+02
Pb CFS-L07-1314-T07-B 1 8.93E+02
Pb CFS-L07-1314-T08-B 1 8.31 E+02
Pb CFS-L07-1314-T09-B 1 8.00E+02
Pb CFS-L07-1314-T01-C 1 6.50E+02
Pb CFS-L07-1314-T02-C 1 6.67E+02
Pb CFS-L07-1314-T03-C 1 6.35E+02
Pb CFS-L07-1314-T04-C 1 6.92E+02
Pb CFS-L07-1314-T05-C 1 8.03E+02
Pb CFS-L07-1314-T06-C 1 8.64E+02
Pb CFS-L07-1314-T07-C 1 8.65E+02
Pb CFS-L07-1314-T08-C 1 8.06E+02
Pb CFS-L07-1314-T09-C 1 7.55E+02
Pb CFS-L07-1314-B01-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.48E+02 1.12 6.80 21.60
8.30E+02 1.26 6.80 21.60
7.00E+02 0.37 6.80 21.60 10000 1000
6.69E+02 1.18 6.80 21.60
7.44E+02 0.51 6.80 21.60
8.81 E+02 0.80 6.80 21.60
8.84E+02 0.50 6.80 21.60
8.24E+02 0.58 6.80 21.60
5.99E+02 0.99 6.80 21.60
6.65E+02 0.25 6.80 21.60
5.22E+02 0.81 6.80 21.60
6.31E+02 0.46 6.80 21.60 10000 1000
7.28E+02 0.81 6.80 21.60
8.31 E+02 0.68 6.80 21.60
8.59E+02 0.47 6.80 21.60
8.93E+02 0.71 6.80 21.60
8.31 E+02 0.66 6.80 21.60
8.00E+02 1.27 6.80 21.60
6.50E+02 1.53 6.80 21.60
6.67E+02 0.81 6.80 21.60
6.35E+02 0.63 6.80 21.60 10000 1000
6.92E+02 5.04 6.80 21.60
8.03E+02 0.89 6.80 21.60
8.64E+02 0.59 6.80 21.60
8.65E+02 0.80 6.80 21.60
8.06E+02 0.75 6.80 21.60
7.55E+02 0.56 6.80 21.60
3.40E+00 31.47 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.71E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.66E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.64E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-74
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Li CFS-L07-1314-T01-A 1 1.37E+01
Li CFS-L07-1314-T02-A 1 7.01 E+00
Li CFS-L07-1314-T03-A 1 1.15E+01
Li CFS-L07-1314-T04-A 1 1.25E+01
Li CFS-L07-1314-T05-A 1 1.29E+01
Li CFS-L07-1314-T06-A 1 1.36E+01
Li CFS-L07-1314-T07-A 1 1.43E+01
Li CFS-L07-1314-T08-A 1 1.39E+01
Li CFS-L07-1314-T09-A 1 1.28E+01
Li CFS-L07-1314-T01-B 1 1.97E+01
Li CFS-L07-1314-T02-B 1 7.39E+00
Li CFS-L07-1314-T03-B 1 1.05E+01
Li CFS-L07-1314-T04-B 1 1.35E+01
Li CFS-L07-1314-T05-B 1 1.30E+01
Li CFS-L07-1314-T06-B 1 1.64E+01
Li CFS-L07-1314-T07-B 1 1.35E+01
Li CFS-L07-1314-T08-B 1 1.09E+01
Li CFS-L07-1314-T09-B 1 1.57E+01
Li CFS-L07-1314-T01-C 1 2.19E+01
Li CFS-L07-1314-T02-C 1 7.18E+00
Li CFS-L07-1314-T03-C 1 1.13E+01
Li CFS-L07-1314-T04-C 1 1.30E+01
Li CFS-L07-1314-T05-C 1 1.40E+01
Li CFS-L07-1314-T06-C 1 1.29E+01
Li CFS-L07-1314-T07-C 1 1.33E+01
Li CFS-L07-1314-T08-C 1 1.11E+01
Li CFS-L07-1314-T09-C 1 1.55E+01
Li CFS-L07-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.37E+01 1.77 1.90 6.00
7.01 E+00 1.20 1.90 6.00
1.15E+01 1.05 1.90 6.00 10000 1000
1.25E+01 0.75 1.90 6.00
1.29E+01 1.23 1.90 6.00
1.36E+01 1.24 1.90 6.00
1.43E+01 3.01 1.90 6.00
1.39E+01 2.95 1.90 6.00
1.28E+01 1.93 1.90 6.00
1.97E+01 12.63 1.90 6.00
7.39E+00 1.76 1.90 6.00
1.05E+01 1.00 1.90 6.00 10000 1000
1.35E+01 1.15 1.90 6.00
1.30E+01 1.14 1.90 6.00
1.64E+01 3.73 1.90 6.00
1.35E+01 3.68 1.90 6.00
1.09E+01 2.29 1.90 6.00
1.57E+01 0.41 1.90 6.00
2.19E+01 1.92 1.90 6.00
7.18E+00 14.48 1.90 6.00
1.13E+01 1.06 1.90 6.00 10000 1000
1.30E+01 0.73 1.90 6.00
1.40E+01 1.15 1.90 6.00
1.29E+01 1.51 1.90 6.00
1.33E+01 3.86 1.90 6.00
1.11E+01 1.94 1.90 6.00
1.55E+01 1.05 1.90 6.00
9.50E-01 16.12 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 . 1 1 E+03 1 09% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-75
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Mn CFS-L07-1314-T01-A 1 1.21E+04
Mn CFS-L07-1314-T02-A 1 8.78E+03
Mn CFS-L07-1314-T03-A 1 5.31E+03
Mn CFS-L07-1314-T04-A 1 4.00E+03
Mn CFS-L07-1314-T05-A 1 3.00E+03
Mn CFS-L07-1314-T06-A 1 1.19E+03
Mn CFS-L07-1314-T07-A 1 6.00E+02
Mn CFS-L07-1314-T08-A 1 4.55E+02
Mn CFS-L07-1314-T09-A 1 3.07E+02
Mn CFS-L07-1314-T01-B 1 1.31E+04
Mn CFS-L07-1314-T02-B 1 6.25E+03
Mn CFS-L07-1314-T03-B 1 4.90E+03
Mn CFS-L07-1314-T04-B 1 3.86E+03
Mn CFS-L07-1314-T05-B 1 2.87E+03
Mn CFS-L07-1314-T06-B 1 9.94E+02
Mn CFS-L07-1314-T07-B 1 5.43E+02
Mn CFS-L07-1314-T08-B 1 4.12E+02
Mn CFS-L07-1314-T09-B 1 3.01E+02
Mn CFS-L07-1314-T01-C 1 1.64E+04
Mn CFS-L07-1314-T02-C 1 8.36E+03
Mn CFS-L07-1314-T03-C 1 5.65E+03
Mn CFS-L07-1314-T04-C 1 4.47E+03
Mn CFS-L07-1314-T05-C 1 3.10E+03
Mn CFS-L07-1314-T06-C 1 1.01E+03
Mn CFS-L07-1314-T07-C 1 5.83E+02
Mn CFS-L07-1314-T08-C 1 4.58E+02
Mn CFS-L07-1314-T09-C 1 3.32E+02
Mn CFS-L07-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.21E+04 0.46 2.00 6.40
8.78E+03 0.78 2.00 6.40
5.31E+03 0.46 2.00 6.40 10000 1000
4.00E+03 0.94 2.00 6.40
3.00E+03 0.39 2.00 6.40
1.19E+03 0.81 2.00 6.40
6.00E+02 0.11 2.00 6.40
4.55E+02 0.94 2.00 6.40
3.07E+02 2.77 2.00 6.40
1.31E+04 0.62 2.00 6.40
6.25E+03 9.37 2.00 6.40
4.90E+03 1.21 2.00 6.40 10000 1000
3.86E+03 0.20 2.00 6.40
2.87E+03 0.99 2.00 6.40
9.94E+02 1.43 2.00 6.40
5.43E+02 0.67 2.00 6.40
4.12E+02 0.63 2.00 6.40
3.01 E+02 0.31 2.00 6.40
1.64E+04 0.66 2.00 6.40
8.36E+03 0.80 2.00 6.40
5.65E+03 1.24 2.00 6.40 10000 1000
4.47E+03 5.40 2.00 6.40
3.10E+03 0.62 2.00 6.40
1.01E+03 0.92 2.00 6.40
5.83E+02 0.52 2.00 6.40
4.58E+02 0.88 2.00 6.40
3.32E+02 0.87 2.00 6.40
1.00E+00 9.89 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.31 E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.86E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.62E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-76
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Mg CFS-L07-1314-T01-A 1 1.68E+06
Mg CFS-L07-1314-T02-A 1 1.00E+06
Mg CFS-L07-1314-T03-A 1 2.69E+05
Mg CFS-L07-1314-T04-A 1 7.98E+04
Mg CFS-L07-1314-T05-A 1 3.68E+04
Mg CFS-L07-1314-T06-A 1 1.76E+04
Mg CFS-L07-1314-T07-A 1 1.33E+04
Mg CFS-L07-1314-T08-A 1 8.61 E+03
Mg CFS-L07-1314-T09-A 1 3.99E+03
Mg CFS-L07-1314-T01-B 1 1.98E+06
Mg CFS-L07-1314-T02-B 1 5.82E+05
Mg CFS-L07-1314-T03-B 1 1.84E+05
Mg CFS-L07-1314-T04-B 1 5.97E+04
Mg CFS-L07-1314-T05-B 1 3.19E+04
Mg CFS-L07-1314-T06-B 1 1.60E+04
Mg CFS-L07-1314-T07-B 1 1.18E+04
Mg CFS-L07-1314-T08-B 1 7.40E+03
Mg CFS-L07-1314-T09-B 1 4.64E+03
Mg CFS-L07-1314-T01-C 1 2.19E+06
Mg CFS-L07-1314-T02-C 1 7.28E+05
Mg CFS-L07-1314-T03-C 1 1.93E+05
Mg CFS-L07-1314-T04-C 1 5.74E+04
Mg CFS-L07-1314-T05-C 1 3.08E+04
Mg CFS-L07-1314-T06-C 1 1.61E+04
Mg CFS-L07-1314-T07-C 1 1.22E+04
Mg CFS-L07-1314-T08-C 1 7.56E+03
Mg CFS-L07-1314-T09-C 1 4.51 E+03
Mg CFS-L07-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.68E+06 0.17 1.00 3.18
1.00E+06 1.05 1.00 3.18
2.69E+05 0.47 1.00 3.18 10000 1000
7.98E+04 0.62 1.00 3.18
3.68E+04 1.17 1.00 3.18
1.76E+04 1.55 1.00 3.18
1.33E+04 0.65 1.00 3.18
8.61E+03 0.95 1.00 3.18
3.99E+03 1.11 1.00 3.18
1.98E+06 1.07 1.00 3.18
5.82E+05 2.64 1.00 3.18
1.84E+05 0.27 1.00 3.18 10000 1000
5.97E+04 1.65 1.00 3.18
3.19E+04 1.56 1.00 3.18
1.60E+04 0.73 1.00 3.18
1.18E+04 1.39 1.00 3.18
7.40E+03 1.37 1.00 3.18
4.64E+03 1.18 1.00 3.18
2.19E+06 0.97 1.00 3.18
7.28E+05 0.39 1.00 3.18
1.93E+05 0.72 1.00 3.18 10000 1000
5.74E+04 3.46 1.00 3.18
3.08E+04 1.26 1.00 3.18
1.61E+04 0.98 1.00 3.18
1.22E+04 0.40 1.00 3.18
7.56E+03 0.79 1.00 3.18
4.51E+03 0.99 1.00 3.18
5.00E-01 8.72 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.70E+05 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.85E+05 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.93E+05 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-77
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Mo CFS-L07-1314-T01-A 1 2.17E+01
Mo CFS-L07-1314-T02-A 1 1.63E+01
Mo CFS-L07-1314-T03-A 1 8.44E+00
Mo CFS-L07-1314-T04-A 1 6.22E+00
Mo CFS-L07-1314-T05-A 1 6.28E+00
Mo CFS-L07-1314-T06-A 1 6.83E+00
Mo CFS-L07-1314-T07-A 1 6.66E+00
Mo CFS-L07-1314-T08-A 1 5.79E+00
Mo CFS-L07-1314-T09-A 1 4.86E+00
Mo CFS-L07-1314-T01-B 1 2.96E+01
Mo CFS-L07-1314-T02-B 1 1.23E+01
Mo CFS-L07-1314-T03-B 1 8.94E+00
Mo CFS-L07-1314-T04-B 1 8.07E+00
Mo CFS-L07-1314-T05-B 1 6.83E+00
Mo CFS-L07-1314-T06-B 1 7.00E+00
Mo CFS-L07-1314-T07-B 1 6.71E+00
Mo CFS-L07-1314-T08-B 1 5.73E+00
Mo CFS-L07-1314-T09-B 1 7.18E+00
Mo CFS-L07-1314-T01-C 1 2.68E+01
Mo CFS-L07-1314-T02-C 1 1.21E+01
Mo CFS-L07-1314-T03-C 1 8.34E+00
Mo CFS-L07-1314-T04-C 1 6.77E+00
Mo CFS-L07-1314-T05-C 1 8.69E+00
Mo CFS-L07-1314-T06-C 1 6.20E+00
Mo CFS-L07-1314-T07-C 1 6.82E+00
Mo CFS-L07-1314-T08-C 1 5.83E+00
Mo CFS-L07-1314-T09-C 1 7.59E+00
Mo CFS-L07-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.17E+01 7.58 1.20 3.82
1.63E+01 10.04 1.20 3.82
8.44E+00 7.22 1.20 3.82 10000 1000
6.22E+00 6.19 1.20 3.82
6.28E+00 2.12 1.20 3.82
6.83E+00 4.67 1.20 3.82
6.66E+00 1.13 1.20 3.82
5.79E+00 1.11 1.20 3.82
4.86E+00 4.37 1.20 3.82
2.96E+01 4.67 1.20 3.82
1.23E+01 2.23 1.20 3.82
8.94E+00 4.85 1.20 3.82 10000 1000
8.07E+00 2.55 1.20 3.82
6.83E+00 7.77 1.20 3.82
7.00E+00 1.19 1.20 3.82
6.71 E+00 2.84 1.20 3.82
5.73E+00 7.04 1.20 3.82
7.18E+00 8.50 1.20 3.82
2.68E+01 8.22 1.20 3.82
1.21E+01 5.56 1.20 3.82
8.34E+00 4.83 1.20 3.82 10000 1000
6.77E+00 1.26 1.20 3.82
8.69E+00 1.45 1.20 3.82
6.20E+00 7.46 1.20 3.82
6.82E+00 2.75 1.20 3.82
5.83E+00 2.17 1.20 3.82
7.59E+00 4.26 1.20 3.82
6.00E-01 14.75 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 . 1 0E+03 1 09% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-78
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Ni CFS-L07-1314-T01-A 1 5.84E+02
Ni CFS-L07-1314-T02-A 1 4.45E+02
Ni CFS-L07-1314-T03-A 1 3.18E+02
Ni CFS-L07-1314-T04-A 1 3.05E+02
Ni CFS-L07-1314-T05-A 1 3.05E+02
Ni CFS-L07-1314-T06-A 1 2.45E+02
Ni CFS-L07-1314-T07-A 1 1.79E+02
Ni CFS-L07-1314-T08-A 1 1.18E+02
Ni CFS-L07-1314-T09-A 1 6.22E+01
Ni CFS-L07-1314-T01-B 1 5.72E+02
Ni CFS-L07-1314-T02-B 1 2.87E+02
Ni CFS-L07-1314-T03-B 1 2.84E+02
Ni CFS-L07-1314-T04-B 1 2.82E+02
Ni CFS-L07-1314-T05-B 1 2.91E+02
Ni CFS-L07-1314-T06-B 1 2.28E+02
Ni CFS-L07-1314-T07-B 1 1.71E+02
Ni CFS-L07-1314-T08-B 1 1.11E+02
Ni CFS-L07-1314-T09-B 1 7.39E+01
Ni CFS-L07-1314-T01-C 1 7.28E+02
Ni CFS-L07-1314-T02-C 1 4.18E+02
Ni CFS-L07-1314-T03-C 1 3.30E+02
Ni CFS-L07-1314-T04-C 1 3.24E+02
Ni CFS-L07-1314-T05-C 1 3.38E+02
Ni CFS-L07-1314-T06-C 1 2.62E+02
Ni CFS-L07-1314-T07-C 1 1.75E+02
Ni CFS-L07-1314-T08-C 1 1.11E+02
Ni CFS-L07-1314-T09-C 1 7.20E+01
Ni CFS-L07-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.84E+02 0.23 1.80 5.70
4.45E+02 0.37 1.80 5.70
3.18E+02 0.71 1.80 5.70 10000 1000
3.05E+02 0.75 1.80 5.70
3.05E+02 0.81 1.80 5.70
2.45E+02 1.95 1.80 5.70
1.79E+02 0.53 1.80 5.70
1.18E+02 2.33 1.80 5.70
6.22E+01 1.06 1.80 5.70
5.72E+02 1.04 1.80 5.70
2.87E+02 2.65 1.80 5.70
2.84E+02 0.40 1.80 5.70 10000 1000
2.82E+02 0.31 1.80 5.70
2.91E+02 1.11 1.80 5.70
2.28E+02 1.10 1.80 5.70
1.71E+02 1.18 1.80 5.70
1.11E+02 1.47 1.80 5.70
7.39E+01 1.74 1.80 5.70
7.28E+02 0.33 1.80 5.70
4.18E+02 0.39 1.80 5.70
3.30E+02 1.69 1.80 5.70 10000 1000
3.24E+02 4.64 1.80 5.70
3.38E+02 0.78 1.80 5.70
2.62E+02 0.37 1.80 5.70
1.75E+02 1.02 1.80 5.70
1.11E+02 1.39 1.80 5.70
7.20E+01 2.14 1.80 5.70
9.00E-01 4.77 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.41E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.35E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.36E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-79
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
P CFS-L07-1314-T01-A 1 6.16E+01
P CFS-L07-1314-T02-A 1 6.54E+00 E
P CFS-L07-1314-T03-A 1 1.85E+00 U1/2
P CFS-L07-1314-T04-A 1 1.85E+00 U1/2
P CFS-L07-1314-T05-A 1 1.85E+00 U1/2
P CFS-L07-1314-T06-A 1 1.85E+00 U1/2
P CFS-L07-1314-T07-A 1 1.85E+00 U1/2
P CFS-L07-1314-T08-A 1 1.85E+00 U1/2
P CFS-L07-1314-T09-A 1 1.85E+00 U1/2
P CFS-L07-1314-T01-B 1 5.96E+01
P CFS-L07-1314-T02-B 1 7.33E+00 E
P CFS-L07-1314-T03-B 1 1.85E+00 U1/2
P CFS-L07-1314-T04-B 1 1.85E+00 U1/2
P CFS-L07-1314-T05-B 1 1.85E+00 U1/2
P CFS-L07-1314-T06-B 1 1.85E+00 U1/2
P CFS-L07-1314-T07-B 1 1.85E+00 U1/2
P CFS-L07-1314-T08-B 1 1.85E+00 U1/2
P CFS-L07-1314-T09-B 1 1.85E+00 U1/2
P CFS-L07-1314-T01-C 1 5.43E+01
P CFS-L07-1314-T02-C 1 8.28E+00 E
P CFS-L07-1314-T03-C 1 1.85E+00 U1/2
P CFS-L07-1314-T04-C 1 1.85E+00 U1/2
P CFS-L07-1314-T05-C 1 1.85E+00 U1/2
P CFS-L07-1314-T06-C 1 1.85E+00 U1/2
P CFS-L07-1314-T07-C 1 1.85E+00 U1/2
P CFS-L07-1314-T08-C 1 1.85E+00 U1/2
P CFS-L07-1314-T09-C 1 1.85E+00 U1/2
P CFS-L07-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.16E+01 21.53 3.70 11.80
6.54E+00 13.61 3.70 11.80
1.85E+00 3.16 3.70 11.80 10000 1000
1.85E+00 7.28 3.70 11.80
1.85E+00 11.33 3.70 11.80
1.85E+00 8.20 3.70 11.80
1.85E+00 9.88 3.70 11.80
1.85E+00 18.50 3.70 11.80
1.85E+00 11.56 3.70 11.80
5.96E+01 19.58 3.70 11.80
7.33E+00 10.12 3.70 11.80
1.85E+00 18.52 3.70 11.80 10000 1000
1.85E+00 3.98 3.70 11.80
1.85E+00 7.57 3.70 11.80
1.85E+00 7.70 3.70 11.80
1.85E+00 9.93 3.70 11.80
1.85E+00 16.54 3.70 11.80
1.85E+00 24.71 3.70 11.80
5.43E+01 14.35 3.70 11.80
8.28E+00 26.94 3.70 11.80
1.85E+00 15.67 3.70 11.80 10000 1000
1.85E+00 5.70 3.70 11.80
1.85E+00 8.22 3.70 11.80
1.85E+00 19.22 3.70 11.80
1.85E+00 14.78 3.70 11.80
1.85E+00 14.14 3.70 11.80
1.85E+00 6.17 3.70 11.80
1.85E+00 7.12 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-80
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
K CFS-L07-1314-T01-A 1 1.30E+05
K CFS-L07-1314-T02-A 1 7.07E+04
K CFS-L07-1314-T03-A 1 3.31 E+04
K CFS-L07-1314-T04-A 1 2.20E+04
K CFS-L07-1314-T05-A 1 1.63E+04
K CFS-L07-1314-T06-A 1 8.26E+03
K CFS-L07-1314-T07-A 1 5.15E+03
K CFS-L07-1314-T08-A 1 3.21E+03
K CFS-L07-1314-T09-A 1 1.75E+03
K CFS-L07-1314-T01-B 1 1.19E+05
K CFS-L07-1314-T02-B 1 4.52E+04
K CFS-L07-1314-T03-B 1 3.05E+04
K CFS-L07-1314-T04-B 1 2. 11 E+04
K CFS-L07-1314-T05-B 1 1.55E+04
K CFS-L07-1314-T06-B 1 7.48E+03
K CFS-L07-1314-T07-B 1 4.78E+03
K CFS-L07-1314-T08-B 1 3.02E+03
K CFS-L07-1314-T09-B 1 2.16E+03
K CFS-L07-1314-T01-C 1 1.35E+05
K CFS-L07-1314-T02-C 1 5.90E+04
K CFS-L07-1314-T03-C 1 3.20E+04
K CFS-L07-1314-T04-C 1 2.23E+04
K CFS-L07-1314-T05-C 1 1.65E+04
K CFS-L07-1314-T06-C 1 7.98E+03
K CFS-L07-1314-T07-C 1 4.96E+03
K CFS-L07-1314-T08-C 1 3.07E+03
K CFS-L07-1314-T09-C 1 2.10E+03
K CFS-L07-1314-B01-A 1 9.12E+00
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.30E+05 0.69 1.60 5.09
7.07E+04 0.16 1.60 5.09
3.31E+04 0.74 1.60 5.09 10000 1000
2.20E+04 1.22 1.60 5.09
1.63E+04 0.20 1.60 5.09
8.26E+03 1.00 1.60 5.09
5.15E+03 0.29 1.60 5.09
3.21 E+03 0.56 1.60 5.09
1.75E+03 2.38 1.60 5.09
1.19E+05 0.62 1.60 5.09
4.52E+04 1.81 1.60 5.09
3.05E+04 0.52 1.60 5.09 10000 1000
2. 11 E+04 0.33 1.60 5.09
1.55E+04 1.21 1.60 5.09
7.48E+03 0.13 1.60 5.09
4.78E+03 0.73 1.60 5.09
3.02E+03 0.50 1.60 5.09
2.16E+03 0.52 1.60 5.09
1.35E+05 0.40 1.60 5.09
5.90E+04 0.34 1.60 5.09
3.20E+04 0.57 1.60 5.09 10000 1000
2.23E+04 4.21 1.60 5.09
1.65E+04 0.59 1.60 5.09
7.98E+03 0.58 1.60 5.09
4.96E+03 0.69 1.60 5.09
3.07E+03 0.53 1.60 5.09
2.10E+03 0.54 1.60 5.09
9.12E+00 4.81 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.40E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.15E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.30E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-81
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L
Se CFS-L07-1314-T01-A 1 1.22E+03
Se CFS-L07-1314-T02-A 1 6.97E+02
Se CFS-L07-1314-T03-A 1 1.79E+02
Se CFS-L07-1314-T04-A 1 7.21E+01
Se CFS-L07-1314-T05-A 1 5.17E+01
Se CFS-L07-1314-T06-A 1 3.11E+01 E
Se CFS-L07-1314-T07-A 1 3.64E+01 E
Se CFS-L07-1314-T08-A 1 3.30E+01 E
Se CFS-L07-1314-T09-A 1 7.50E+00 U1/2
Se CFS-L07-1314-T01-B 1 1.52E+03
Se CFS-L07-1314-T02-B 1 3.36E+02
Se CFS-L07-1314-T03-B 1 1.24E+02
Se CFS-L07-1314-T04-B 1 6.04E+01
Se CFS-L07-1314-T05-B 1 5.03E+01
Se CFS-L07-1314-T06-B 1 3.55E+01 E
Se CFS-L07-1314-T07-B 1 3.09E+01 E
Se CFS-L07-1314-T08-B 1 1.79E+01 E
Se CFS-L07-1314-T09-B 1 7.50E+00 U1/2
Se CFS-L07-1314-T01-C 1 1.75E+03
Se CFS-L07-1314-T02-C 1 4.76E+02
Se CFS-L07-1314-T03-C 1 1.33E+02
Se CFS-L07-1314-T04-C 1 6.18E+01
Se CFS-L07-1314-T05-C 1 3.45E+01 E
Se CFS-L07-1314-T06-C 1 3.51 E+01 E
Se CFS-L07-1314-T07-C 1 2.05E+01 E
Se CFS-L07-1314-T08-C 1 1.88E+01 E
Se CFS-L07-1314-T09-C 1 7.50E+00 U1/2
Se CFS-L07-1314-B01-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.22E+03 1.26 15.00 47.70
6.97E+02 0.26 15.00 47.70
1.79E+02 2.65 15.00 47.70 10000 1000
7.21E+01 4.53 15.00 47.70
5.17E+01 7.66 15.00 47.70
3. 11 E+01 10.76 15.00 47.70
3.64E+01 4.93 15.00 47.70
3.30E+01 15.40 15.00 47.70
7.50E+00 32.80 15.00 47.70
1.52E+03 0.81 15.00 47.70
3.36E+02 3.05 15.00 47.70
1.24E+02 9.81 15.00 47.70 10000 1000
6.04E+01 11.55 15.00 47.70
5.03E+01 3.06 15.00 47.70
3.55E+01 16.16 15.00 47.70
3.09E+01 21.02 15.00 47.70
1.79E+01 19.37 15.00 47.70
7.50E+00 32.91 15.00 47.70
1.75E+03 1.63 15.00 47.70
4.76E+02 3.87 15.00 47.70
1.33E+02 1.94 15.00 47.70 10000 1000
6.18E+01 7.83 15.00 47.70
3.45E+01 8.44 15.00 47.70
3.51E+01 7.22 15.00 47.70
2.05E+01 23.56 15.00 47.70
1.88E+01 13.40 15.00 47.70
7.50E+00 22.20 15.00 47.70
7.50E+00 28.54 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.18E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.20E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.20E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-82
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Si CFS-L07-1314-T01-A 1 6.16E+03
Si CFS-L07-1314-T02-A 1 5.79E+03
Si CFS-L07-1314-T03-A 1 5.44E+03
Si CFS-L07-1314-T04-A 1 5.30E+03
Si CFS-L07-1314-T05-A 1 5.37E+03
Si CFS-L07-1314-T06-A 1 4.92E+03
Si CFS-L07-1314-T07-A 1 4.75E+03
Si CFS-L07-1314-T08-A 1 4.25E+03
Si CFS-L07-1314-T09-A 1 3.67E+03
Si CFS-L07-1314-T01-B 1 5.94E+03
Si CFS-L07-1314-T02-B 1 4.56E+03
Si CFS-L07-1314-T03-B 1 5.23E+03
Si CFS-L07-1314-T04-B 1 5.17E+03
Si CFS-L07-1314-T05-B 1 5.23E+03
Si CFS-L07-1314-T06-B 1 4.71E+03
Si CFS-L07-1314-T07-B 1 4.70E+03
Si CFS-L07-1314-T08-B 1 4.26E+03
Si CFS-L07-1314-T09-B 1 3.98E+03
Si CFS-L07-1314-T01-C 1 6.53E+03
Si CFS-L07-1314-T02-C 1 5.81 E+03
Si CFS-L07-1314-T03-C 1 5.63E+03
Si CFS-L07-1314-T04-C 1 5.47E+03
Si CFS-L07-1314-T05-C 1 5.58E+03
Si CFS-L07-1314-T06-C 1 5.00E+03
Si CFS-L07-1314-T07-C 1 4.87E+03
Si CFS-L07-1314-T08-C 1 4.32E+03
Si CFS-L07-1314-T09-C 1 3.98E+03
Si CFS-L07-1314-B01-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.16E+03 0.54 1.10 3.50
5.79E+03 0.52 1.10 3.50
5.44E+03 0.15 1.10 3.50 10000 1000
5.30E+03 0.44 1.10 3.50
5.37E+03 0.40 1.10 3.50
4.92E+03 0.84 1.10 3.50
4.75E+03 0.87 1.10 3.50
4.25E+03 1.84 1.10 3.50
3.67E+03 1.04 1.10 3.50
5.94E+03 0.52 1.10 3.50
4.56E+03 0.73 1.10 3.50
5.23E+03 0.75 1.10 3.50 10000 1000
5.17E+03 0.14 1.10 3.50
5.23E+03 1.75 1.10 3.50
4.71 E+03 0.63 1.10 3.50
4.70E+03 1.52 1.10 3.50
4.26E+03 0.71 1.10 3.50
3.98E+03 0.27 1.10 3.50
6.53E+03 0.58 1.10 3.50
5.81 E+03 0.51 1.10 3.50
5.63E+03 1.14 1.10 3.50 10000 1000
5.47E+03 5.45 1.10 3.50
5.58E+03 0.83 1.10 3.50
5.00E+03 0.89 1.10 3.50
4.87E+03 0.97 1.10 3.50
4.32E+03 0.98 1.10 3.50
3.98E+03 1.30 1.10 3.50
5.50E-01 22.50 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.44E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.20E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.65E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-83
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
Na CFS-L07-1314-T01-A 1 2.22E+05
Na CFS-L07-1314-T02-A 1 1.38E+05
Na CFS-L07-1314-T03-A 1 3.14E+04
Na CFS-L07-1314-T04-A 1 7.35E+03
Na CFS-L07-1314-T05-A 1 4.11E+03
Na CFS-L07-1314-T06-A 1 1.95E+03
Na CFS-L07-1314-T07-A 1 1.57E+03
Na CFS-L07-1314-T08-A 1 1.15E+03
Na CFS-L07-1314-T09-A 1 7.71E+02
Na CFS-L07-1314-T01-B 1 2.44E+05
Na CFS-L07-1314-T02-B 1 8.26E+04
Na CFS-L07-1314-T03-B 1 1.70E+04
Na CFS-L07-1314-T04-B 1 5.82E+03
Na CFS-L07-1314-T05-B 1 3.57E+03
Na CFS-L07-1314-T06-B 1 1.83E+03
Na CFS-L07-1314-T07-B 1 1.47E+03
Na CFS-L07-1314-T08-B 1 1.10E+03
Na CFS-L07-1314-T09-B 1 8.74E+02
Na CFS-L07-1314-T01-C 1 2.64E+05
Na CFS-L07-1314-T02-C 1 1.03E+05
Na CFS-L07-1314-T03-C 1 1.94E+04
Na CFS-L07-1314-T04-C 1 6.38E+03
Na CFS-L07-1314-T05-C 1 3.78E+03
Na CFS-L07-1314-T06-C 1 1.91E+03
Na CFS-L07-1314-T07-C 1 1.53E+03
Na CFS-L07-1314-T08-C 1 1.09E+03
Na CFS-L07-1314-T09-C 1 8.24E+02
Na CFS-L07-1314-B01-A 1 7.52E+00 E
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.22E+05 0.42 2.50 8.00
1.38E+05 0.39 2.50 8.00
3.14E+04 0.16 2.50 8.00 10000 1000
7.35E+03 0.77 2.50 8.00
4.11E+03 0.12 2.50 8.00
1.95E+03 0.37 2.50 8.00
1.57E+03 0.78 2.50 8.00
1.15E+03 0.20 2.50 8.00
7.71 E+02 0.67 2.50 8.00
2.44E+05 0.82 2.50 8.00
8.26E+04 1.44 2.50 8.00
1.70E+04 0.31 2.50 8.00 10000 1000
5.82E+03 0.80 2.50 8.00
3.57E+03 0.57 2.50 8.00
1.83E+03 1.25 2.50 8.00
1.47E+03 0.50 2.50 8.00
1.10E+03 1.05 2.50 8.00
8.74E+02 0.47 2.50 8.00
2.64E+05 0.21 2.50 8.00
1.03E+05 0.87 2.50 8.00
1.94E+04 0.22 2.50 8.00 10000 1000
6.38E+03 1.45 2.50 8.00
3.78E+03 0.37 2.50 8.00
1.91E+03 0.82 2.50 8.00
1.53E+03 0.75 2.50 8.00
1.09E+03 0.71 2.50 8.00
8.24E+02 0.96 2.50 8.00
7.52E+00 2.06 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.24E+04 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.80E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.03E+04 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-84
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Sr CFS-L07-1314-T01-A 1 4.00E+03
Sr CFS-L07-1314-T02-A 1 3.47E+03
Sr CFS-L07-1314-T03-A 1 3.04E+03
Sr CFS-L07-1314-T04-A 1 2.82E+03
Sr CFS-L07-1314-T05-A 1 2.47E+03
Sr CFS-L07-1314-T06-A 1 1.78E+03
Sr CFS-L07-1314-T07-A 1 1.53E+03
Sr CFS-L07-1314-T08-A 1 1.40E+03
Sr CFS-L07-1314-T09-A 1 1.19E+03
Sr CFS-L07-1314-T01-B 1 4.30E+03
Sr CFS-L07-1314-T02-B 1 3.04E+03
Sr CFS-L07-1314-T03-B 1 3.19E+03
Sr CFS-L07-1314-T04-B 1 2.94E+03
Sr CFS-L07-1314-T05-B 1 2.44E+03
Sr CFS-L07-1314-T06-B 1 1.64E+03
Sr CFS-L07-1314-T07-B 1 1.48E+03
Sr CFS-L07-1314-T08-B 1 1.37E+03
Sr CFS-L07-1314-T09-B 1 1.29E+03
Sr CFS-L07-1314-T01-C 1 4.31E+03
Sr CFS-L07-1314-T02-C 1 3.22E+03
Sr CFS-L07-1314-T03-C 1 3.13E+03
Sr CFS-L07-1314-T04-C 1 2.97E+03
Sr CFS-L07-1314-T05-C 1 2.44E+03
Sr CFS-L07-1314-T06-C 1 1.70E+03
Sr CFS-L07-1314-T07-C 1 1.52E+03
Sr CFS-L07-1314-T08-C 1 1.37E+03
Sr CFS-L07-1314-T09-C 1 1.27E+03
Sr CFS-L07-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.00E+03 1.09 1.00 3.18
3.47E+03 0.22 1.00 3.18
3.04E+03 1.68 1.00 3.18 10000 1000
2.82E+03 0.90 1.00 3.18
2.47E+03 0.56 1.00 3.18
1.78E+03 0.74 1.00 3.18
1.53E+03 0.26 1.00 3.18
1.40E+03 1.33 1.00 3.18
1.19E+03 1.07 1.00 3.18
4.30E+03 0.61 1.00 3.18
3.04E+03 1.37 1.00 3.18
3.19E+03 0.92 1.00 3.18 10000 1000
2.94E+03 0.35 1.00 3.18
2.44E+03 1.52 1.00 3.18
1.64E+03 0.32 1.00 3.18
1.48E+03 1.46 1.00 3.18
1.37E+03 0.45 1.00 3.18
1.29E+03 0.34 1.00 3.18
4.31E+03 1.53 1.00 3.18
3.22E+03 0.68 1.00 3.18
3.13E+03 0.71 1.00 3.18 10000 1000
2.97E+03 5.24 1.00 3.18
2.44E+03 0.77 1.00 3.18
1.70E+03 0.84 1.00 3.18
1.52E+03 1.28 1.00 3.18
1.37E+03 1.16 1.00 3.18
1.27E+03 0.87 1.00 3.18
5.00E-01 20.28 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.09E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.15E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.11E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-85
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
S CFS-L07-1314-T01-A 1 1.81E+06
S CFS-L07-1314-T02-A 1 1.32E+06
S CFS-L07-1314-T03-A 1 6.79E+05
S CFS-L07-1314-T04-A 1 5.05E+05
S CFS-L07-1314-T05-A 1 4.69E+05
S CFS-L07-1314-T06-A 1 4.54E+05
S CFS-L07-1314-T07-A 1 4.51 E+05
S CFS-L07-1314-T08-A 1 4.43E+05
S CFS-L07-1314-T09-A 1 3.43E+05
S CFS-L07-1314-T01-B 1 1.97E+06
S CFS-L07-1314-T02-B 1 8.71E+05
S CFS-L07-1314-T03-B 1 6.02E+05
S CFS-L07-1314-T04-B 1 4.88E+05
S CFS-L07-1314-T05-B 1 4.65E+05
S CFS-L07-1314-T06-B 1 4.43E+05
S CFS-L07-1314-T07-B 1 4.49E+05
S CFS-L07-1314-T08-B 1 4.38E+05
S CFS-L07-1314-T09-B 1 4.32E+05
S CFS-L07-1314-T01-C 1 2.09E+06
S CFS-L07-1314-T02-C 1 1.10E+06
S CFS-L07-1314-T03-C 1 6.17E+05
S CFS-L07-1314-T04-C 1 4.91 E+05
S CFS-L07-1314-T05-C 1 4.69E+05
S CFS-L07-1314-T06-C 1 4.52E+05
S CFS-L07-1314-T07-C 1 4.48E+05
S CFS-L07-1314-T08-C 1 4.38E+05
S CFS-L07-1314-T09-C 1 4.30E+05
S CFS-L07-1314-B01-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.81E+06 0.37 6.80 21.60
1.32E+06 0.36 6.80 21.60
6.79E+05 0.64 6.80 21.60 10000 1000
5.05E+05 1.03 6.80 21.60
4.69E+05 0.11 6.80 21.60
4.54E+05 1.25 6.80 21.60
4.51 E+05 0.31 6.80 21.60
4.43E+05 0.59 6.80 21.60
3.43E+05 1.82 6.80 21.60
1.97E+06 0.98 6.80 21.60
8.71 E+05 0.84 6.80 21.60
6.02E+05 0.71 6.80 21.60 10000 1000
4.88E+05 0.33 6.80 21.60
4.65E+05 1.42 6.80 21.60
4.43E+05 0.35 6.80 21.60
4.49E+05 0.91 6.80 21.60
4.38E+05 0.44 6.80 21.60
4.32E+05 0.88 6.80 21.60
2.09E+06 0.52 6.80 21.60
1.10E+06 0.31 6.80 21.60
6.17E+05 0.59 6.80 21.60 10000 1000
4.91 E+05 4.56 6.80 21.60
4.69E+05 0.71 6.80 21.60
4.52E+05 0.60 6.80 21.60
4.48E+05 0.68 6.80 21.60
4.38E+05 0.39 6.80 21.60
4.30E+05 0.48 6.80 21.60
3.40E+00 20.26 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.80E+05 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.03E+05 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.18E+05 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-86
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Tl CFS-L07-1314-T01-A 1 1.42E+03
Tl CFS-L07-1314-T02-A 1 1.14E+03
Tl CFS-L07-1314-T03-A 1 6.47E+02
Tl CFS-L07-1314-T04-A 1 4.71E+02
Tl CFS-L07-1314-T05-A 1 3.93E+02
Tl CFS-L07-1314-T06-A 1 2.44E+02
Tl CFS-L07-1314-T07-A 1 1.81E+02
Tl CFS-L07-1314-T08-A 1 1.30E+02
Tl CFS-L07-1314-T09-A 1 7.36E+01
Tl CFS-L07-1314-T01-B 1 1.55E+03
Tl CFS-L07-1314-T02-B 1 7.58E+02
Tl CFS-L07-1314-T03-B 1 5.83E+02
Tl CFS-L07-1314-T04-B 1 4.40E+02
Tl CFS-L07-1314-T05-B 1 3.69E+02
Tl CFS-L07-1314-T06-B 1 2.15E+02
Tl CFS-L07-1314-T07-B 1 1.67E+02
Tl CFS-L07-1314-T08-B 1 1.16E+02
Tl CFS-L07-1314-T09-B 1 9.58E+01
Tl CFS-L07-1314-T01-C 1 1.63E+03
Tl CFS-L07-1314-T02-C 1 9.53E+02
Tl CFS-L07-1314-T03-C 1 6.05E+02
Tl CFS-L07-1314-T04-C 1 4.62E+02
Tl CFS-L07-1314-T05-C 1 3.83E+02
Tl CFS-L07-1314-T06-C 1 2.29E+02
Tl CFS-L07-1314-T07-C 1 1.69E+02
Tl CFS-L07-1314-T08-C 1 1.21E+02
Tl CFS-L07-1314-T09-C 1 9.22E+01
Tl CFS-L07-1314-B01-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.42E+03 0.90 4.60 14.60
1.14E+03 0.63 4.60 14.60
6.47E+02 0.55 4.60 14.60 10000 1000
4.71E+02 1.47 4.60 14.60
3.93E+02 1.38 4.60 14.60
2.44E+02 2.58 4.60 14.60
1.81E+02 2.58 4.60 14.60
1.30E+02 1.18 4.60 14.60
7.36E+01 1.42 4.60 14.60
1.55E+03 0.38 4.60 14.60
7.58E+02 2.76 4.60 14.60
5.83E+02 2.55 4.60 14.60 10000 1000
4.40E+02 2.07 4.60 14.60
3.69E+02 1.08 4.60 14.60
2.15E+02 2.29 4.60 14.60
1.67E+02 1.19 4.60 14.60
1.16E+02 2.44 4.60 14.60
9.58E+01 3.05 4.60 14.60
1.63E+03 0.38 4.60 14.60
9.53E+02 1.04 4.60 14.60
6.05E+02 0.48 4.60 14.60 10000 1000
4.62E+02 3.46 4.60 14.60
3.83E+02 1.65 4.60 14.60
2.29E+02 2.77 4.60 14.60
1.69E+02 2.03 4.60 14.60
1.21E+02 1.32 4.60 14.60
9.22E+01 1.36 4.60 14.60
2.30E+00 22.15 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.70E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.54E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.67E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-87
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ti CFS-L07-1314-T01-A 1 1.00E+00 U1/2
Ti CFS-L07-1314-T02-A 1 1.00E+00 U1/2
Ti CFS-L07-1314-T03-A 1 1.00E+00 U1/2
Ti CFS-L07-1314-T04-A 1 1.00E+00 U1/2
Ti CFS-L07-1314-T05-A 1 1.00E+00 U1/2
Ti CFS-L07-1314-T06-A 1 1.00E+00 U1/2
Ti CFS-L07-1314-T07-A 1 1.00E+00 U1/2
Ti CFS-L07-1314-T08-A 1 1.00E+00 U1/2
Ti CFS-L07-1314-T09-A 1 1.00E+00 U1/2
Ti CFS-L07-1314-T01-B 1 1.00E+00 U1/2
Ti CFS-L07-1314-T02-B 1 1.00E+00 U1/2
Ti CFS-L07-1314-T03-B 1 1.00E+00 U1/2
Ti CFS-L07-1314-T04-B 1 1.00E+00 U1/2
Ti CFS-L07-1314-T05-B 1 1.00E+00 U1/2
Ti CFS-L07-1314-T06-B 1 1.00E+00 U1/2
Ti CFS-L07-1314-T07-B 1 1.00E+00 U1/2
Ti CFS-L07-1314-T08-B 1 1.00E+00 U1/2
Ti CFS-L07-1314-T09-B 1 1.00E+00 U1/2
Ti CFS-L07-1314-T01-C 1 1.00E+00 U1/2
Ti CFS-L07-1314-T02-C 1 1.00E+00 U1/2
Ti CFS-L07-1314-T03-C 1 1.00E+00 U1/2
Ti CFS-L07-1314-T04-C 1 1.00E+00 U1/2
Ti CFS-L07-1314-T05-C 1 1.00E+00 U1/2
Ti CFS-L07-1314-T06-C 1 1.00E+00 U1/2
Ti CFS-L07-1314-T07-C 1 1.00E+00 U1/2
Ti CFS-L07-1314-T08-C 1 1.00E+00 U1/2
Ti CFS-L07-1314-T09-C 1 1.00E+00 U1/2
Ti CFS-L07-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 33.54 2.00 6.40
1.00E+00 24.89 2.00 6.40
1.00E+00 40.49 2.00 6.40 10000 1000
1.00E+00 23.38 2.00 6.40
1.00E+00 18.60 2.00 6.40
1.00E+00 24.93 2.00 6.40
1.00E+00 17.19 2.00 6.40
1.00E+00 32.78 2.00 6.40
1.00E+00 23.41 2.00 6.40
1.00E+00 37.20 2.00 6.40
1.00E+00 13.25 2.00 6.40
1.00E+00 38.32 2.00 6.40 10000 1000
1.00E+00 24.74 2.00 6.40
1.00E+00 33.29 2.00 6.40
1.00E+00 24.91 2.00 6.40
1.00E+00 15.81 2.00 6.40
1.00E+00 18.59 2.00 6.40
1.00E+00 20.43 2.00 6.40
1.00E+00 9.75 2.00 6.40
1.00E+00 33.59 2.00 6.40
1.00E+00 17.30 2.00 6.40 10000 1000
1.00E+00 34.92 2.00 6.40
1.00E+00 21.21 2.00 6.40
1.00E+00 83.22 2.00 6.40
1.00E+00 25.03 2.00 6.40
1.00E+00 13.44 2.00 6.40
1.00E+00 17.76 2.00 6.40
1.00E+00 8.41 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.05E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-8
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
V CFS-L07-1314-T01-A 1 2.89E+01
V CFS-L07-1314-T02-A 1 3.12E+01
V CFS-L07-1314-T03-A 1 3.42E+01
V CFS-L07-1314-T04-A 1 3.64E+01
V CFS-L07-1314-T05-A 1 3.72E+01
V CFS-L07-1314-T06-A 1 3.84E+01
V CFS-L07-1314-T07-A 1 3.89E+01
V CFS-L07-1314-T08-A 1 3.85E+01
V CFS-L07-1314-T09-A 1 3.18E+01
V CFS-L07-1314-T01-B 1 2.92E+01
V CFS-L07-1314-T02-B 1 2.75E+01
V CFS-L07-1314-T03-B 1 3.49E+01
V CFS-L07-1314-T04-B 1 3.74E+01
V CFS-L07-1314-T05-B 1 3.90E+01
V CFS-L07-1314-T06-B 1 3.75E+01
V CFS-L07-1314-T07-B 1 3.98E+01
V CFS-L07-1314-T08-B 1 3.84E+01
V CFS-L07-1314-T09-B 1 3.90E+01
V CFS-L07-1314-T01-C 1 2.92E+01
V CFS-L07-1314-T02-C 1 3.07E+01
V CFS-L07-1314-T03-C 1 3.47E+01
V CFS-L07-1314-T04-C 1 3.64E+01
V CFS-L07-1314-T05-C 1 3.76E+01
V CFS-L07-1314-T06-C 1 3.90E+01
V CFS-L07-1314-T07-C 1 3.89E+01
V CFS-L07-1314-T08-C 1 3.93E+01
V CFS-L07-1314-T09-C 1 3.76E+01
V CFS-L07-1314-B01-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.89E+01 3.14 1.50 4.77
3.12E+01 1.07 1.50 4.77
3.42E+01 1.73 1.50 4.77 10000 1000
3.64E+01 0.61 1.50 4.77
3.72E+01 2.69 1.50 4.77
3.84E+01 1.89 1.50 4.77
3.89E+01 2.60 1.50 4.77
3.85E+01 2.95 1.50 4.77
3.18E+01 3.30 1.50 4.77
2.92E+01 1.79 1.50 4.77
2.75E+01 2.59 1.50 4.77
3.49E+01 1.74 1.50 4.77 10000 1000
3.74E+01 0.59 1.50 4.77
3.90E+01 1.60 1.50 4.77
3.75E+01 1.15 1.50 4.77
3.98E+01 3.54 1.50 4.77
3.84E+01 1.21 1.50 4.77
3.90E+01 2.43 1.50 4.77
2.92E+01 2.81 1.50 4.77
3.07E+01 1.65 1.50 4.77
3.47E+01 4.92 1.50 4.77 10000 1000
3.64E+01 2.65 1.50 4.77
3.76E+01 0.48 1.50 4.77
3.90E+01 1.67 1.50 4.77
3.89E+01 1.51 1.50 4.77
3.93E+01 2.25 1.50 4.77
3.76E+01 0.62 1.50 4.77
7.50E-01 27.53 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.56E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.37E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.26E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-89
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Zn CFS-L07-1314-T01-A 1 4.91E+04
Zn CFS-L07-1314-T02-A 1 4.02E+04
Zn CFS-L07-1314-T03-A 1 3.10E+04
Zn CFS-L07-1314-T04-A 1 3.06E+04
Zn CFS-L07-1314-T05-A 1 3.15E+04
Zn CFS-L07-1314-T06-A 1 2.85E+04
Zn CFS-L07-1314-T07-A 1 2.39E+04
Zn CFS-L07-1314-T08-A 1 1.85E+04
Zn CFS-L07-1314-T09-A 1 1.36E+04
Zn CFS-L07-1314-T01-B 1 4.50E+04
Zn CFS-L07-1314-T02-B 1 2.72E+04
Zn CFS-L07-1314-T03-B 1 2.73E+04
Zn CFS-L07-1314-T04-B 1 2.81 E+04
Zn CFS-L07-1314-T05-B 1 2.90E+04
Zn CFS-L07-1314-T06-B 1 2.60E+04
Zn CFS-L07-1314-T07-B 1 2.28E+04
Zn CFS-L07-1314-T08-B 1 1.81 E+04
Zn CFS-L07-1314-T09-B 1 1.49E+04
Zn CFS-L07-1314-T01-C 1 5.83E+04
Zn CFS-L07-1314-T02-C 1 3.73E+04
Zn CFS-L07-1314-T03-C 1 3.26E+04
Zn CFS-L07-1314-T04-C 1 3.29E+04
Zn CFS-L07-1314-T05-C 1 3.37E+04
Zn CFS-L07-1314-T06-C 1 2.98E+04
Zn CFS-L07-1314-T07-C 1 2.48E+04
Zn CFS-L07-1314-T08-C 1 1.90E+04
Zn CFS-L07-1314-T09-C 1 1.45E+04
Zn CFS-L07-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.91E+04 0.30 1.00 3.18
4.02E+04 0.93 1.00 3.18
3.10E+04 0.83 1.00 3.18 10000 1000
3.06E+04 0.80 1.00 3.18
3.15E+04 0.36 1.00 3.18
2.85E+04 0.99 1.00 3.18
2.39E+04 0.58 1.00 3.18
1.85E+04 2.28 1.00 3.18
1.36E+04 4.05 1.00 3.18
4.50E+04 1.05 1.00 3.18
2.72E+04 1.58 1.00 3.18
2.73E+04 13.82 1.00 3.18 10000 1000
2.81E+04 0.45 1.00 3.18
2.90E+04 1.25 1.00 3.18
2.60E+04 0.47 1.00 3.18
2.28E+04 1.11 1.00 3.18
1.81 E+04 0.77 1.00 3.18
1.49E+04 0.72 1.00 3.18
5.83E+04 1.10 1.00 3.18
3.73E+04 0.66 1.00 3.18
3.26E+04 1.14 1.00 3.18 10000 1000
3.29E+04 4.78 1.00 3.18
3.37E+04 0.64 1.00 3.18
2.98E+04 1.12 1.00 3.18
2.48E+04 0.65 1.00 3.18
1.90E+04 1.23 1.00 3.18
1.45E+04 2.07 1.00 3.18
5.00E-01 6.32 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.19E+04 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.82E+04 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.35E+04 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/8/11 2:47 PM EPA Interlab L07 1314 CFS
12/8/11 2:48 PM EPA Interlab L07 1314 CFS
12/8/11 2:50 PM EPA Interlab L07 1314 CFS
12/8/11 2:52 PM EPA Interlab L07 1314 CFS
12/8/11 2:53 PM EPA Interlab L07 1314 CFS
12/8/11 2:55 PM EPA Interlab L07 1314 CFS
12/8/11 2:57 PM EPA Interlab L07 1314 CFS
12/8/11 2:58 PM EPA Interlab L07 1314 CFS
12/8/11 3:00 PM EPA Interlab L07 1314 CFS
12/8/11 3:08 PM EPA Interlab L07 1314 CFS
12/8/11 3:10 PM EPA Interlab L07 1314 CFS
12/8/11 3:11 PM EPA Interlab L07 1314 CFS
12/8/11 3:13 PM EPA Interlab L07 1314 CFS
12/8/11 3:15 PM EPA Interlab L07 1314 CFS
12/8/11 3:16 PM EPA Interlab L07 1314 CFS
12/8/11 3:18 PM EPA Interlab L07 1314 CFS
12/8/11 3:20 PM EPA Interlab L07 1314 CFS
12/8/11 3:21 PM EPA Interlab L07 1314 CFS
12/8/11 3:23 PM EPA Interlab L07 1314 CFS
12/8/11 3:25 PM EPA Interlab L07 1314 CFS
12/8/11 3:26 PM EPA Interlab L07 1314 CFS
12/8/11 3:28 PM EPA Interlab L07 1314 CFS
12/8/11 3:30 PM EPA Interlab L07 1314 CFS
12/8/11 3:31 PM EPA Interlab L07 1314 CFS
12/8/11 3:33 PM EPA Interlab L07 1314 CFS
12/8/11 3:35 PM EPA Interlab L07 1314 CFS
12/8/11 3:36 PM EPA Interlab L07 1314 CFS
12/8/11 2:32 PM EPA Interlab L07 1314 CFS
1-90
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1314:
Element Sample ID
Al CFS-L10-1314-T01-A
Al CFS-L10-1314-T02-A
Al CFS-L10-1314-T03-A
Al CFS-L10-1314-T04-A
Al CFS-L10-1314-T05-A
Al CFS-L10-1314-T06-A
Al CFS-L10-1314-T07-A
Al CFS-L10-1314-T08-A
Al CFS-L10-1314-T09-A
Al CFS-L10-1314-T01-B
Al CFS-L10-1314-T02-B
Al CFS-L10-1314-T03-B
Al CFS-L10-1314-T04-B
Al CFS-L10-1314-T05-B
Al CFS-L10-1314-T06-B
Al CFS-L10-1314-T07-B
Al CFS-L10-1314-T08-B
Al CFS-L10-1314-T09-B
Al CFS-L10-1314-T01-C
Al CFS-L10-1314-T02-C
Al CFS-L10-1314-T03-C
Al CFS-L10-1314-T04-C
Al CFS-L10-1314-T05-C
Al CFS-L10-1314-T06-C
Al CFS-L10-1314-T07-C
Al CFS-L10-1314-T08-C
Al CFS-L10-1314-T09-C
Al CFS-L10-1314-B01-A
Dilution Sample
Factor Cone. Qualifier
I ug/L I
1 5.55E+01
1 4.81 E+01
1 4.68E+01
1 3.92E+01
1 4.79E+01
1 3.63E+01
1 4.96E+01
1 3.86E+01
1 3.63E+01
1 5.89E+01
1 4.53E+01
1 4.41 E+01
1 3.87E+01
1 4.31 E+01
1 3.85E+01
1 4.03E+01
1 3.35E+01
1 3.83E+01
1 5.66E+01
1 5.58E+01
1 4.85E+01
1 4.10E+01
1 4.05E+01
1 4.21 E+01
1 3.90E+01
1 3.55E+01
1 3.92E+01
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.55E+01 9.49 1.00 3.18
4.81E+01 4.04 1.00 3.18
4.68E+01 4.53 1.00 3.18 10000 1000
3.92E+01 7.20 1.00 3.18
4.79E+01 5.78 1.00 3.18
3.63E+01 2.61 1.00 3.18
4.96E+01 1.69 1.00 3.18
3.86E+01 3.52 1.00 3.18
3.63E+01 2.93 1.00 3.18
5.89E+01 6.81 1.00 3.18
4.53E+01 7.70 1.00 3.18
4.41E+01 6.27 1.00 3.18 10000 1000
3.87E+01 8.11 1.00 3.18
4.31E+01 1.22 1.00 3.18
3.85E+01 9.28 1.00 3.18
4.03E+01 4.36 1.00 3.18
3.35E+01 1.00 1.00 3.18
3.83E+01 3.43 1.00 3.18
5.66E+01 5.56 1.00 3.18
5.58E+01 5.22 1.00 3.18
4.85E+01 3.28 1.00 3.18 10000 1000
4.10E+01 1.76 1.00 3.18
4.05E+01 8.92 1.00 3.18
4.21E+01 2.58 1.00 3.18
3.90E+01 4.48 1.00 3.18
3.55E+01 6.42 1.00 3.18
3.92E+01 1.93 1.00 3.18
5.00E-01 38.03 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-91
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L
Sb CFS-L10-1314-T01-A 1 7.06E+01
Sb CFS-L10-1314-T02-A 1 3.54E+01
Sb CFS-L10-1314-T03-A 1 2.53E+01
Sb CFS-L10-1314-T04-A 1 1.93E+01 E
Sb CFS-L10-1314-T05-A 1 1.93E+01 E
Sb CFS-L10-1314-T06-A 1 1.87E+01 E
Sb CFS-L10-1314-T07-A 1 1.53E+01 E
Sb CFS-L10-1314-T08-A 1 1.38E+01 E
Sb CFS-L10-1314-T09-A 1 1.30E+01 E
Sb CFS-L10-1314-T01-B 1 6.52E+01
Sb CFS-L10-1314-T02-B 1 3.76E+01
Sb CFS-L10-1314-T03-B 1 2.63E+01
Sb CFS-L10-1314-T04-B 1 1.91E+01 E
Sb CFS-L10-1314-T05-B 1 2.06E+01 E
Sb CFS-L10-1314-T06-B 1 1.82E+01 E
Sb CFS-L10-1314-T07-B 1 1.49E+01 E
Sb CFS-L10-1314-T08-B 1 1.20E+01 E
Sb CFS-L10-1314-T09-B 1 1.11E+01 E
Sb CFS-L10-1314-T01-C 1 7.05E+01
Sb CFS-L10-1314-T02-C 1 3.47E+01
Sb CFS-L10-1314-T03-C 1 2.52E+01
Sb CFS-L10-1314-T04-C 1 2.07E+01 E
Sb CFS-L10-1314-T05-C 1 2.09E+01 E
Sb CFS-L10-1314-T06-C 1 1.88E+01 E
Sb CFS-L10-1314-T07-C 1 1.44E+01 E
Sb CFS-L10-1314-T08-C 1 1.12E+01 E
Sb CFS-L10-1314-T09-C 1 1.34E+01 E
Sb CFS-L10-1314-B01-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.06E+01 9.08 7.50 23.90
3.54E+01 5.83 7.50 23.90
2.53E+01 7.52 7.50 23.90 10000 1000
1.93E+01 6.77 7.50 23.90
1.93E+01 15.07 7.50 23.90
1.87E+01 4.38 7.50 23.90
1.53E+01 1.37 7.50 23.90
1.38E+01 6.43 7.50 23.90
1.30E+01 5.33 7.50 23.90
6.52E+01 2.51 7.50 23.90
3.76E+01 5.03 7.50 23.90
2.63E+01 4.61 7.50 23.90 10000 1000
1.91E+01 1.95 7.50 23.90
2.06E+01 12.11 7.50 23.90
1.82E+01 6.28 7.50 23.90
1.49E+01 13.35 7.50 23.90
1.20E+01 22.64 7.50 23.90
1.11E+01 7.65 7.50 23.90
7.05E+01 13.69 7.50 23.90
3.47E+01 2.21 7.50 23.90
2.52E+01 7.62 7.50 23.90 10000 1000
2.07E+01 3.36 7.50 23.90
2.09E+01 12.35 7.50 23.90
1.88E+01 8.64 7.50 23.90
1.44E+01 10.20 7.50 23.90
1.12E+01 0.87 7.50 23.90
1.34E+01 9.81 7.50 23.90
3.75E+00 7.38 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.18E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-92
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L
As CFS-L10-1314-T01-A 1 4.36E+01
As CFS-L10-1314-T02-A 1 3.12E+01 E
As CFS-L10-1314-T03-A 1 2.14E+01 E
As CFS-L10-1314-T04-A 1 2.30E+01 E
As CFS-L10-1314-T05-A 1 1.54E+01 E
As CFS-L10-1314-T06-A 1 1.63E+01 E
As CFS-L10-1314-T07-A 1 1.71E+01 E
As CFS-L10-1314-T08-A 1 1.30E+01 E
As CFS-L10-1314-T09-A 1 1.47E+01 E
As CFS-L10-1314-T01-B 1 4.27E+01
As CFS-L10-1314-T02-B 1 3.31E+01 E
As CFS-L10-1314-T03-B 1 2.37E+01 E
As CFS-L10-1314-T04-B 1 2.28E+01 E
As CFS-L10-1314-T05-B 1 1.50E+01 E
As CFS-L10-1314-T06-B 1 1.54E+01 E
As CFS-L10-1314-T07-B 1 1.60E+01 E
As CFS-L10-1314-T08-B 1 1.44E+01 E
As CFS-L10-1314-T09-B 1 1.56E+01 E
As CFS-L10-1314-T01-C 1 4.42E+01
As CFS-L10-1314-T02-C 1 3.55E+01
As CFS-L10-1314-T03-C 1 2.24E+01 E
As CFS-L10-1314-T04-C 1 2.14E+01 E
As CFS-L10-1314-T05-C 1 1.52E+01 E
As CFS-L10-1314-T06-C 1 1.75E+01 E
As CFS-L10-1314-T07-C 1 1.43E+01 E
As CFS-L10-1314-T08-C 1 1.25E+01 E
As CFS-L10-1314-T09-C 1 1.33E+01 E
As CFS-L10-1314-B01-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.36E+01 2.79 11.00 35.00
3.12E+01 1.76 11.00 35.00
2.14E+01 2.53 11.00 35.00 10000 1000
2.30E+01 3.32 11.00 35.00
1.54E+01 3.90 11.00 35.00
1.63E+01 3.35 11.00 35.00
1.71E+01 0.59 11.00 35.00
1.30E+01 4.01 11.00 35.00
1.47E+01 5.51 11.00 35.00
4.27E+01 1.03 11.00 35.00
3.31E+01 4.19 11.00 35.00
2.37E+01 3.44 11.00 35.00 10000 1000
2.28E+01 1.61 11.00 35.00
1.50E+01 3.38 11.00 35.00
1.54E+01 1.65 11.00 35.00
1.60E+01 1.96 11.00 35.00
1.44E+01 0.91 11.00 35.00
1.56E+01 1.08 11.00 35.00
4.42E+01 4.11 11.00 35.00
3.55E+01 5.42 11.00 35.00
2.24E+01 6.11 11.00 35.00 10000 1000
2.14E+01 5.03 11.00 35.00
1.52E+01 0.96 11.00 35.00
1.75E+01 5.74 11.00 35.00
1.43E+01 1.84 11.00 35.00
1.25E+01 2.40 11.00 35.00
1.33E+01 2.82 11.00 35.00
5.50E+00 2.00 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.09E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-93
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
B CFS-L10-1314-T01-A 1 2.06E+03
B CFS-L10-1314-T02-A 1 9.73E+02
B CFS-L10-1314-T03-A 1 4.73E+02
B CFS-L10-1314-T04-A 1 2.73E+02
B CFS-L10-1314-T05-A 1 1.81E+02
B CFS-L10-1314-T06-A 1 1.02E+02
B CFS-L10-1314-T07-A 1 7.87E+01
B CFS-L10-1314-T08-A 1 6.27E+01
B CFS-L10-1314-T09-A 1 4.86E+01
B CFS-L10-1314-T01-B 1 1.49E+03
B CFS-L10-1314-T02-B 1 1.40E+03
B CFS-L10-1314-T03-B 1 6.92E+02
B CFS-L10-1314-T04-B 1 3.45E+02
B CFS-L10-1314-T05-B 1 2.23E+02
B CFS-L10-1314-T06-B 1 1.19E+02
B CFS-L10-1314-T07-B 1 8.20E+01
B CFS-L10-1314-T08-B 1 5.07E+01
B CFS-L10-1314-T09-B 1 5.07E+01
B CFS-L10-1314-T01-C 1 1.59E+03
B CFS-L10-1314-T02-C 1 1.15E+03
B CFS-L10-1314-T03-C 1 6.01E+02
B CFS-L10-1314-T04-C 1 3.29E+02
B CFS-L10-1314-T05-C 1 2.18E+02
B CFS-L10-1314-T06-C 1 1.19E+02
B CFS-L10-1314-T07-C 1 7.67E+01
B CFS-L10-1314-T08-C 1 5.39E+01
B CFS-L10-1314-T09-C 1 5.02E+01
B CFS-L10-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.06E+03 1.13 1.00 3.18
9.73E+02 0.75 1.00 3.18
4.73E+02 2.07 1.00 3.18 10000 1000
2.73E+02 0.73 1.00 3.18
1.81E+02 0.36 1.00 3.18
1.02E+02 3.01 1.00 3.18
7.87E+01 2.34 1.00 3.18
6.27E+01 4.65 1.00 3.18
4.86E+01 3.14 1.00 3.18
1.49E+03 0.49 1.00 3.18
1.40E+03 0.35 1.00 3.18
6.92E+02 0.83 1.00 3.18 10000 1000
3.45E+02 0.61 1.00 3.18
2.23E+02 1.74 1.00 3.18
1.19E+02 1.21 1.00 3.18
8.20E+01 2.04 1.00 3.18
5.07E+01 5.05 1.00 3.18
5.07E+01 2.57 1.00 3.18
1.59E+03 1.00 1.00 3.18
1.15E+03 0.62 1.00 3.18
6.01E+02 0.80 1.00 3.18 10000 1000
3.29E+02 0.23 1.00 3.18
2.18E+02 1.19 1.00 3.18
1.19E+02 1.03 1.00 3.18
7.67E+01 1.64 1.00 3.18
5.39E+01 2.21 1.00 3.18
5.02E+01 2.21 1.00 3.18
5.00E-01 10.95 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.34E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.58E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.47E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-94
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Ba CFS-L10-1314-T01-A 1 4.57E+01
Ba CFS-L10-1314-T02-A 1 5.98E+01
Ba CFS-L10-1314-T03-A 1 7.07E+01
Ba CFS-L10-1314-T04-A 1 7.51E+01
Ba CFS-L10-1314-T05-A 1 7.76E+01
Ba CFS-L10-1314-T06-A 1 8.24E+01
Ba CFS-L10-1314-T07-A 1 8.91E+01
Ba CFS-L10-1314-T08-A 1 9.38E+01
Ba CFS-L10-1314-T09-A 1 9.89E+01
Ba CFS-L10-1314-T01-B 1 5.02E+01
Ba CFS-L10-1314-T02-B 1 5.40E+01
Ba CFS-L10-1314-T03-B 1 7.01E+01
Ba CFS-L10-1314-T04-B 1 7.67E+01
Ba CFS-L10-1314-T05-B 1 7.84E+01
Ba CFS-L10-1314-T06-B 1 8.23E+01
Ba CFS-L10-1314-T07-B 1 8.52E+01
Ba CFS-L10-1314-T08-B 1 9.87E+01
Ba CFS-L10-1314-T09-B 1 9.47E+01
Ba CFS-L10-1314-T01-C 1 5.04E+01
Ba CFS-L10-1314-T02-C 1 5.87E+01
Ba CFS-L10-1314-T03-C 1 7.20E+01
Ba CFS-L10-1314-T04-C 1 7.75E+01
Ba CFS-L10-1314-T05-C 1 8.01E+01
Ba CFS-L10-1314-T06-C 1 8.42E+01
Ba CFS-L10-1314-T07-C 1 8.69E+01
Ba CFS-L10-1314-T08-C 1 9.08E+01
Ba CFS-L10-1314-T09-C 1 1.08E+02
Ba CFS-L10-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.57E+01 1.63 1.00 3.18
5.98E+01 0.93 1.00 3.18
7.07E+01 1.82 1.00 3.18 10000 1000
7.51E+01 0.53 1.00 3.18
7.76E+01 0.24 1.00 3.18
8.24E+01 0.18 1.00 3.18
8.91E+01 0.80 1.00 3.18
9.38E+01 0.36 1.00 3.18
9.89E+01 0.47 1.00 3.18
5.02E+01 2.43 1.00 3.18
5.40E+01 0.89 1.00 3.18
7.01E+01 0.41 1.00 3.18 10000 1000
7.67E+01 0.35 1.00 3.18
7.84E+01 0.69 1.00 3.18
8.23E+01 1.13 1.00 3.18
8.52E+01 1.57 1.00 3.18
9.87E+01 0.49 1.00 3.18
9.47E+01 1.17 1.00 3.18
5.04E+01 1.66 1.00 3.18
5.87E+01 2.97 1.00 3.18
7.20E+01 0.72 1.00 3.18 10000 1000
7.75E+01 0.64 1.00 3.18
8.01E+01 0.68 1.00 3.18
8.42E+01 0.06 1.00 3.18
8.69E+01 0.21 1.00 3.18
9.08E+01 0.87 1.00 3.18
1.08E+02 0.86 1.00 3.18
5.00E-01 23.55 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.03E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-95
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Be CFS-L10-1314-T01-A 1 9.50E-01 U1/2
Be CFS-L10-1314-T02-A 1 9.50E-01 U1/2
Be CFS-L10-1314-T03-A 1 9.50E-01 U1/2
Be CFS-L10-1314-T04-A 1 9.50E-01 U1/2
Be CFS-L10-1314-T05-A 1 9.50E-01 U1/2
Be CFS-L10-1314-T06-A 1 9.50E-01 U1/2
Be CFS-L10-1314-T07-A 1 9.50E-01 U1/2
Be CFS-L10-1314-T08-A 1 9.50E-01 U1/2
Be CFS-L10-1314-T09-A 1 9.50E-01 U1/2
Be CFS-L10-1314-T01-B 1 9.50E-01 U1/2
Be CFS-L10-1314-T02-B 1 9.50E-01 U1/2
Be CFS-L10-1314-T03-B 1 9.50E-01 U1/2
Be CFS-L10-1314-T04-B 1 9.50E-01 U1/2
Be CFS-L10-1314-T05-B 1 9.50E-01 U1/2
Be CFS-L10-1314-T06-B 1 9.50E-01 U1/2
Be CFS-L10-1314-T07-B 1 9.50E-01 U1/2
Be CFS-L10-1314-T08-B 1 9.50E-01 U1/2
Be CFS-L10-1314-T09-B 1 9.50E-01 U1/2
Be CFS-L10-1314-T01-C 1 9.50E-01 U1/2
Be CFS-L10-1314-T02-C 1 9.50E-01 U1/2
Be CFS-L10-1314-T03-C 1 9.50E-01 U1/2
Be CFS-L10-1314-T04-C 1 9.50E-01 U1/2
Be CFS-L10-1314-T05-C 1 9.50E-01 U1/2
Be CFS-L10-1314-T06-C 1 9.50E-01 U1/2
Be CFS-L10-1314-T07-C 1 9.50E-01 U1/2
Be CFS-L10-1314-T08-C 1 9.50E-01 U1/2
Be CFS-L10-1314-T09-C 1 9.50E-01 U1/2
Be CFS-L10-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 5.92 1.90 6.00
9.50E-01 9.15 1.90 6.00
9.50E-01 6.00 1.90 6.00 10000 1000
9.50E-01 3.26 1.90 6.00
9.50E-01 12.01 1.90 6.00
9.50E-01 8.85 1.90 6.00
9.50E-01 4.80 1.90 6.00
9.50E-01 8.29 1.90 6.00
9.50E-01 22.12 1.90 6.00
9.50E-01 11.57 1.90 6.00
9.50E-01 15.03 1.90 6.00
9.50E-01 3.66 1.90 6.00 10000 1000
9.50E-01 14.96 1.90 6.00
9.50E-01 19.79 1.90 6.00
9.50E-01 23.86 1.90 6.00
9.50E-01 15.31 1.90 6.00
9.50E-01 19.89 1.90 6.00
9.50E-01 9.06 1.90 6.00
9.50E-01 9.26 1.90 6.00
9.50E-01 11.11 1.90 6.00
9.50E-01 17.95 1.90 6.00 10000 1000
9.50E-01 3.58 1.90 6.00
9.50E-01 15.54 1.90 6.00
9.50E-01 7.35 1.90 6.00
9.50E-01 18.47 1.90 6.00
9.50E-01 2.89 1.90 6.00
9.50E-01 6.89 1.90 6.00
9.50E-01 2.57 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.16E+03 116% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-96
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Cd CFS-L10-1314-T01-A 1 1.61E+04
Cd CFS-L10-1314-T02-A 1 1.00E+04
Cd CFS-L10-1314-T03-A 1 8.55E+03
Cd CFS-L10-1314-T04-A 1 8.19E+03
Cd CFS-L10-1314-T05-A 1 8.72E+03
Cd CFS-L10-1314-T06-A 1 7.09E+03
Cd CFS-L10-1314-T07-A 1 5.96E+03
Cd CFS-L10-1314-T08-A 1 4.12E+03
Cd CFS-L10-1314-T09-A 1 3.03E+03
Cd CFS-L10-1314-T01-B 1 1.19E+04
Cd CFS-L10-1314-T02-B 1 1.08E+04
Cd CFS-L10-1314-T03-B 1 8.46E+03
Cd CFS-L10-1314-T04-B 1 8.51E+03
Cd CFS-L10-1314-T05-B 1 8.36E+03
Cd CFS-L10-1314-T06-B 1 7.02E+03
Cd CFS-L10-1314-T07-B 1 5.84E+03
Cd CFS-L10-1314-T08-B 1 4.18E+03
Cd CFS-L10-1314-T09-B 1 3.40E+03
Cd CFS-L10-1314-T01-C 1 1.39E+04
Cd CFS-L10-1314-T02-C 1 1.04E+04
Cd CFS-L10-1314-T03-C 1 9.08E+03
Cd CFS-L10-1314-T04-C 1 8.29E+03
Cd CFS-L10-1314-T05-C 1 7.86E+03
Cd CFS-L10-1314-T06-C 1 6.68E+03
Cd CFS-L10-1314-T07-C 1 5.44E+03
Cd CFS-L10-1314-T08-C 1 4.41E+03
Cd CFS-L10-1314-T09-C 1 3.35E+03
Cd CFS-L10-1314-B01-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.61E+04 0.40 2.20 7.00
1.00E+04 0.77 2.20 7.00
8.55E+03 1.36 2.20 7.00 10000 1000
8.19E+03 0.79 2.20 7.00
8.72E+03 0.59 2.20 7.00
7.09E+03 0.07 2.20 7.00
5.96E+03 1.08 2.20 7.00
4.12E+03 0.52 2.20 7.00
3.03E+03 0.55 2.20 7.00
1.19E+04 0.63 2.20 7.00
1.08E+04 0.65 2.20 7.00
8.46E+03 0.50 2.20 7.00 10000 1000
8.51 E+03 0.32 2.20 7.00
8.36E+03 0.64 2.20 7.00
7.02E+03 0.66 2.20 7.00
5.84E+03 1.13 2.20 7.00
4.18E+03 0.70 2.20 7.00
3.40E+03 0.88 2.20 7.00
1.39E+04 1.21 2.20 7.00
1.04E+04 1.69 2.20 7.00
9.08E+03 0.72 2.20 7.00 10000 1000
8.29E+03 0.33 2.20 7.00
7.86E+03 0.59 2.20 7.00
6.68E+03 0.46 2.20 7.00
5.44E+03 0.62 2.20 7.00
4.41 E+03 0.72 2.20 7.00
3.35E+03 1.28 2.20 7.00
1.10E+00 8.15 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.54E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.40E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+04 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-97
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Ca CFS-L10-1314-T01-A 1 4.45E+05
Ca CFS-L10-1314-T02-A 1 5.20E+05
Ca CFS-L10-1314-T03-A 1 5.71E+05
Ca CFS-L10-1314-T04-A 1 5.97E+05
Ca CFS-L10-1314-T05-A 1 6.09E+05
Ca CFS-L10-1314-T06-A 1 6.09E+05
Ca CFS-L10-1314-T07-A 1 6.12E+05
Ca CFS-L10-1314-T08-A 1 6.24E+05
Ca CFS-L10-1314-T09-A 1 5.99E+05
Ca CFS-L10-1314-T01-B 1 4.80E+05
Ca CFS-L10-1314-T02-B 1 4.80E+05
Ca CFS-L10-1314-T03-B 1 5.50E+05
Ca CFS-L10-1314-T04-B 1 5.88E+05
Ca CFS-L10-1314-T05-B 1 6.00E+05
Ca CFS-L10-1314-T06-B 1 6.08E+05
Ca CFS-L10-1314-T07-B 1 6.08E+05
Ca CFS-L10-1314-T08-B 1 5.75E+05
Ca CFS-L10-1314-T09-B 1 6.16E+05
Ca CFS-L10-1314-T01-C 1 4.75E+05
Ca CFS-L10-1314-T02-C 1 5.09E+05
Ca CFS-L10-1314-T03-C 1 5.64E+05
Ca CFS-L10-1314-T04-C 1 5.96E+05
Ca CFS-L10-1314-T05-C 1 6.07E+05
Ca CFS-L10-1314-T06-C 1 6.11E+05
Ca CFS-L10-1314-T07-C 1 6.17E+05
Ca CFS-L10-1314-T08-C 1 6.14E+05
Ca CFS-L10-1314-T09-C 1 5.31E+05
Ca CFS-L10-1314-B01-A 1 1.30E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.45E+05 0.23 2.60 8.30
5.20E+05 0.74 2.60 8.30
5.71E+05 1.18 2.60 8.30 10000 1000
5.97E+05 0.43 2.60 8.30
6.09E+05 0.50 2.60 8.30
6.09E+05 0.31 2.60 8.30
6.12E+05 1.42 2.60 8.30
6.24E+05 0.21 2.60 8.30
5.99E+05 0.63 2.60 8.30
4.80E+05 0.49 2.60 8.30
4.80E+05 0.20 2.60 8.30
5.50E+05 0.40 2.60 8.30 10000 1000
5.88E+05 0.45 2.60 8.30
6.00E+05 0.35 2.60 8.30
6.08E+05 0.91 2.60 8.30
6.08E+05 0.80 2.60 8.30
5.75E+05 0.65 2.60 8.30
6.16E+05 0.80 2.60 8.30
4.75E+05 0.66 2.60 8.30
5.09E+05 0.57 2.60 8.30
5.64E+05 0.47 2.60 8.30 10000 1000
5.96E+05 0.58 2.60 8.30
6.07E+05 0.26 2.60 8.30
6.11E+05 0.27 2.60 8.30
6.17E+05 0.22 2.60 8.30
6.14E+05 0.53 2.60 8.30
5.31 E+05 0.99 2.60 8.30
1.30E+00 4.46 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.72E+05 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.51 E+05 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.65E+05 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-98
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Cr CFS-L10-1314-T01-A 1 6.00E-01 U1/2
Cr CFS-L10-1314-T02-A 1 6.00E-01 U1/2
Cr CFS-L10-1314-T03-A 1 6.00E-01 U1/2
Cr CFS-L10-1314-T04-A 1 6.00E-01 U1/2
Cr CFS-L10-1314-T05-A 1 6.00E-01 U1/2
Cr CFS-L10-1314-T06-A 1 6.00E-01 U1/2
Cr CFS-L10-1314-T07-A 1 6.00E-01 U1/2
Cr CFS-L10-1314-T08-A 1 6.00E-01 U1/2
Cr CFS-L10-1314-T09-A 1 6.00E-01 U1/2
Cr CFS-L10-1314-T01-B 1 6.00E-01 U1/2
Cr CFS-L10-1314-T02-B 1 6.00E-01 U1/2
Cr CFS-L10-1314-T03-B 1 6.00E-01 U1/2
Cr CFS-L10-1314-T04-B 1 6.00E-01 U1/2
Cr CFS-L10-1314-T05-B 1 6.00E-01 U1/2
Cr CFS-L10-1314-T06-B 1 6.00E-01 U1/2
Cr CFS-L10-1314-T07-B 1 6.00E-01 U1/2
Cr CFS-L10-1314-T08-B 1 6.00E-01 U1/2
Cr CFS-L10-1314-T09-B 1 6.00E-01 U1/2
Cr CFS-L10-1314-T01-C 1 6.00E-01 U1/2
Cr CFS-L10-1314-T02-C 1 6.00E-01 U1/2
Cr CFS-L10-1314-T03-C 1 6.00E-01 U1/2
Cr CFS-L10-1314-T04-C 1 6.00E-01 U1/2
Cr CFS-L10-1314-T05-C 1 6.00E-01 U1/2
Cr CFS-L10-1314-T06-C 1 6.00E-01 U1/2
Cr CFS-L10-1314-T07-C 1 6.00E-01 U1/2
Cr CFS-L10-1314-T08-C 1 6.00E-01 U1/2
Cr CFS-L10-1314-T09-C 1 6.00E-01 U1/2
Cr CFS-L10-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 4.63 1.20 3.82
6.00E-01 10.23 1.20 3.82
6.00E-01 16.96 1.20 3.82 10000 1000
6.00E-01 37.89 1.20 3.82
6.00E-01 51.53 1.20 3.82
6.00E-01 23.42 1.20 3.82
6.00E-01 34.57 1.20 3.82
6.00E-01 68.37 1.20 3.82
6.00E-01 22.63 1.20 3.82
6.00E-01 13.30 1.20 3.82
6.00E-01 13.70 1.20 3.82
6.00E-01 15.13 1.20 3.82 10000 1000
6.00E-01 26.98 1.20 3.82
6.00E-01 47.38 1.20 3.82
6.00E-01 54.24 1.20 3.82
6.00E-01 74.94 1.20 3.82
6.00E-01 46.83 1.20 3.82
6.00E-01 48.27 1.20 3.82
6.00E-01 17.93 1.20 3.82
6.00E-01 11.80 1.20 3.82
6.00E-01 26.22 1.20 3.82 10000 1000
6.00E-01 15.53 1.20 3.82
6.00E-01 35.54 1.20 3.82
6.00E-01 55.25 1.20 3.82
6.00E-01 50.99 1.20 3.82
6.00E-01 84.55 1.20 3.82
6.00E-01 17.11 1.20 3.82
6.00E-01 21.97 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-99
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Co CFS-L10-1314-T01-A 1 6.39E+02
Co CFS-L10-1314-T02-A 1 3.20E+02
Co CFS-L10-1314-T03-A 1 2.59E+02
Co CFS-L10-1314-T04-A 1 2.33E+02
Co CFS-L10-1314-T05-A 1 2.09E+02
Co CFS-L10-1314-T06-A 1 1.23E+02
Co CFS-L10-1314-T07-A 1 8.71E+01
Co CFS-L10-1314-T08-A 1 4.35E+01
Co CFS-L10-1314-T09-A 1 2.80E+01
Co CFS-L10-1314-T01-B 1 4.39E+02
Co CFS-L10-1314-T02-B 1 3.99E+02
Co CFS-L10-1314-T03-B 1 2.69E+02
Co CFS-L10-1314-T04-B 1 2.43E+02
Co CFS-L10-1314-T05-B 1 2.22E+02
Co CFS-L10-1314-T06-B 1 1.40E+02
Co CFS-L10-1314-T07-B 1 8.43E+01
Co CFS-L10-1314-T08-B 1 4.62E+01
Co CFS-L10-1314-T09-B 1 2.89E+01
Co CFS-L10-1314-T01-C 1 5.31E+02
Co CFS-L10-1314-T02-C 1 3.68E+02
Co CFS-L10-1314-T03-C 1 2.69E+02
Co CFS-L10-1314-T04-C 1 2.29E+02
Co CFS-L10-1314-T05-C 1 2.03E+02
Co CFS-L10-1314-T06-C 1 1.41E+02
Co CFS-L10-1314-T07-C 1 7.11E+01
Co CFS-L10-1314-T08-C 1 4.50E+01
Co CFS-L10-1314-T09-C 1 3.22E+01
Co CFS-L10-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.39E+02 0.16 1.80 5.72
3.20E+02 1.35 1.80 5.72
2.59E+02 1.63 1.80 5.72 10000 1000
2.33E+02 0.97 1.80 5.72
2.09E+02 0.30 1.80 5.72
1.23E+02 1.13 1.80 5.72
8.71 E+01 2.99 1.80 5.72
4.35E+01 0.67 1.80 5.72
2.80E+01 3.37 1.80 5.72
4.39E+02 0.52 1.80 5.72
3.99E+02 0.47 1.80 5.72
2.69E+02 0.19 1.80 5.72 10000 1000
2.43E+02 0.63 1.80 5.72
2.22E+02 0.62 1.80 5.72
1.40E+02 1.80 1.80 5.72
8.43E+01 1.06 1.80 5.72
4.62E+01 3.43 1.80 5.72
2.89E+01 4.49 1.80 5.72
5.31E+02 1.11 1.80 5.72
3.68E+02 0.17 1.80 5.72
2.69E+02 0.29 1.80 5.72 10000 1000
2.29E+02 1.53 1.80 5.72
2.03E+02 0.70 1.80 5.72
1.41E+02 0.99 1.80 5.72
7. 11 E+01 1.02 1.80 5.72
4.50E+01 3.40 1.80 5.72
3.22E+01 0.96 1.80 5.72
9.00E-01 8.72 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.18E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.25E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.20E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
I-100
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Cu CFS-L10-1314-T01-A 1 2.07E+03
Cu CFS-L10-1314-T02-A 1 1.67E+03
Cu CFS-L10-1314-T03-A 1 1.56E+03
Cu CFS-L10-1314-T04-A 1 1.53E+03
Cu CFS-L10-1314-T05-A 1 1.49E+03
Cu CFS-L10-1314-T06-A 1 1.22E+03
Cu CFS-L10-1314-T07-A 1 1.14E+03
Cu CFS-L10-1314-T08-A 1 8.62E+02
Cu CFS-L10-1314-T09-A 1 6.91E+02
Cu CFS-L10-1314-T01-B 1 1.90E+03
Cu CFS-L10-1314-T02-B 1 1.67E+03
Cu CFS-L10-1314-T03-B 1 1.40E+03
Cu CFS-L10-1314-T04-B 1 1.38E+03
Cu CFS-L10-1314-T05-B 1 1.40E+03
Cu CFS-L10-1314-T06-B 1 1.24E+03
Cu CFS-L10-1314-T07-B 1 1.07E+03
Cu CFS-L10-1314-T08-B 1 8.90E+02
Cu CFS-L10-1314-T09-B 1 6.88E+02
Cu CFS-L10-1314-T01-C 1 2.35E+03
Cu CFS-L10-1314-T02-C 1 2.00E+03
Cu CFS-L10-1314-T03-C 1 1.70E+03
Cu CFS-L10-1314-T04-C 1 1.60E+03
Cu CFS-L10-1314-T05-C 1 1.55E+03
Cu CFS-L10-1314-T06-C 1 1.32E+03
Cu CFS-L10-1314-T07-C 1 1.07E+03
Cu CFS-L10-1314-T08-C 1 8.61E+02
Cu CFS-L10-1314-T09-C 1 7.75E+02
Cu CFS-L10-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.07E+03 0.46 3.70 11.80
1.67E+03 0.61 3.70 11.80
1.56E+03 0.99 3.70 11.80 10000 1000
1.53E+03 0.36 3.70 11.80
1.49E+03 0.40 3.70 11.80
1.22E+03 0.27 3.70 11.80
1.14E+03 0.68 3.70 11.80
8.62E+02 0.78 3.70 11.80
6.91E+02 0.12 3.70 11.80
1.90E+03 0.54 3.70 11.80
1.67E+03 0.54 3.70 11.80
1.40E+03 0.55 3.70 11.80 10000 1000
1.38E+03 0.74 3.70 11.80
1.40E+03 0.68 3.70 11.80
1.24E+03 0.69 3.70 11.80
1.07E+03 1.05 3.70 11.80
8.90E+02 0.27 3.70 11.80
6.88E+02 0.90 3.70 11.80
2.35E+03 0.23 3.70 11.80
2.00E+03 0.62 3.70 11.80
1.70E+03 0.72 3.70 11.80 10000 1000
1.60E+03 0.99 3.70 11.80
1.55E+03 0.45 3.70 11.80
1.32E+03 0.52 3.70 11.80
1.07E+03 0.62 3.70 11.80
8.61E+02 0.55 3.70 11.80
7.75E+02 0.81 3.70 11.80
1.85E+00 29.78 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.52E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.44E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.73E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-101
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Fe CFS-L10-1314-T01-A 1 1.00E+00 U1/2
Fe CFS-L10-1314-T02-A 1 1.00E+00 U1/2
Fe CFS-L10-1314-T03-A 1 1.00E+00 U1/2
Fe CFS-L10-1314-T04-A 1 1.00E+00 U1/2
Fe CFS-L10-1314-T05-A 1 1.00E+00 U1/2
Fe CFS-L10-1314-T06-A 1 1.00E+00 U1/2
Fe CFS-L10-1314-T07-A 1 1.00E+00 U1/2
Fe CFS-L10-1314-T08-A 1 1.00E+00 U1/2
Fe CFS-L10-1314-T09-A 1 1.00E+00 U1/2
Fe CFS-L10-1314-T01-B 1 1.00E+00 U1/2
Fe CFS-L10-1314-T02-B 1 1.00E+00 U1/2
Fe CFS-L10-1314-T03-B 1 1.00E+00 U1/2
Fe CFS-L10-1314-T04-B 1 1.00E+00 U1/2
Fe CFS-L10-1314-T05-B 1 1.00E+00 U1/2
Fe CFS-L10-1314-T06-B 1 1.00E+00 U1/2
Fe CFS-L10-1314-T07-B 1 1.00E+00 U1/2
Fe CFS-L10-1314-T08-B 1 1.00E+00 U1/2
Fe CFS-L10-1314-T09-B 1 1.00E+00 U1/2
Fe CFS-L10-1314-T01-C 1 1.00E+00 U1/2
Fe CFS-L10-1314-T02-C 1 1.00E+00 U1/2
Fe CFS-L10-1314-T03-C 1 1.00E+00 U1/2
Fe CFS-L10-1314-T04-C 1 1.00E+00 U1/2
Fe CFS-L10-1314-T05-C 1 1.00E+00 U1/2
Fe CFS-L10-1314-T06-C 1 1.00E+00 U1/2
Fe CFS-L10-1314-T07-C 1 1.00E+00 U1/2
Fe CFS-L10-1314-T08-C 1 1.00E+00 U1/2
Fe CFS-L10-1314-T09-C 1 1.00E+00 U1/2
Fe CFS-L10-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 10.63 2.00 6.40
1.00E+00 5.24 2.00 6.40
1.00E+00 15.96 2.00 6.40 10000 1000
1.00E+00 2.58 2.00 6.40
1.00E+00 10.87 2.00 6.40
1.00E+00 7.48 2.00 6.40
1.00E+00 14.39 2.00 6.40
1.00E+00 8.02 2.00 6.40
1.00E+00 5.97 2.00 6.40
1.00E+00 6.00 2.00 6.40
1.00E+00 9.78 2.00 6.40
1.00E+00 8.23 2.00 6.40 10000 1000
1.00E+00 8.86 2.00 6.40
1.00E+00 6.72 2.00 6.40
1.00E+00 11.49 2.00 6.40
1.00E+00 5.64 2.00 6.40
1.00E+00 11.67 2.00 6.40
1.00E+00 9.33 2.00 6.40
1.00E+00 11.98 2.00 6.40
1.00E+00 8.33 2.00 6.40
1.00E+00 4.39 2.00 6.40 10000 1000
1.00E+00 4.01 2.00 6.40
1.00E+00 12.41 2.00 6.40
1.00E+00 4.46 2.00 6.40
1.00E+00 1.77 2.00 6.40
1.00E+00 2.14 2.00 6.40
1.00E+00 2.02 2.00 6.40
1.00E+00 5.12 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.17E+03 117% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.13E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-102
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Pb CFS-L10-1314-T01-A 1 6.94E+02
Pb CFS-L10-1314-T02-A 1 6.77E+02
Pb CFS-L10-1314-T03-A 1 7.64E+02
Pb CFS-L10-1314-T04-A 1 8.25E+02
Pb CFS-L10-1314-T05-A 1 8.63E+02
Pb CFS-L10-1314-T06-A 1 8.35E+02
Pb CFS-L10-1314-T07-A 1 8.43E+02
Pb CFS-L10-1314-T08-A 1 7.81E+02
Pb CFS-L10-1314-T09-A 1 7.18E+02
Pb CFS-L10-1314-T01-B 1 6.12E+02
Pb CFS-L10-1314-T02-B 1 6.83E+02
Pb CFS-L10-1314-T03-B 1 6.86E+02
Pb CFS-L10-1314-T04-B 1 7.81E+02
Pb CFS-L10-1314-T05-B 1 8.32E+02
Pb CFS-L10-1314-T06-B 1 8.54E+02
Pb CFS-L10-1314-T07-B 1 8.38E+02
Pb CFS-L10-1314-T08-B 1 7.76E+02
Pb CFS-L10-1314-T09-B 1 7.20E+02
Pb CFS-L10-1314-T01-C 1 5.14E+02
Pb CFS-L10-1314-T02-C 1 6.96E+02
Pb CFS-L10-1314-T03-C 1 7.72E+02
Pb CFS-L10-1314-T04-C 1 8.50E+02
Pb CFS-L10-1314-T05-C 1 8.82E+02
Pb CFS-L10-1314-T06-C 1 8.75E+02
Pb CFS-L10-1314-T07-C 1 8.32E+02
Pb CFS-L10-1314-T08-C 1 7.87E+02
Pb CFS-L10-1314-T09-C 1 7.46E+02
Pb CFS-L10-1314-B01-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.94E+02 1.25 6.80 21.60
6.77E+02 0.61 6.80 21.60
7.64E+02 1.80 6.80 21.60 10000 1000
8.25E+02 0.94 6.80 21.60
8.63E+02 0.52 6.80 21.60
8.35E+02 0.70 6.80 21.60
8.43E+02 1.46 6.80 21.60
7.81E+02 0.51 6.80 21.60
7.18E+02 1.80 6.80 21.60
6.12E+02 1.92 6.80 21.60
6.83E+02 1.29 6.80 21.60
6.86E+02 0.58 6.80 21.60 10000 1000
7.81 E+02 1.06 6.80 21.60
8.32E+02 1.10 6.80 21.60
8.54E+02 0.97 6.80 21.60
8.38E+02 0.76 6.80 21.60
7.76E+02 0.56 6.80 21.60
7.20E+02 0.96 6.80 21.60
5.14E+02 0.80 6.80 21.60
6.96E+02 0.58 6.80 21.60
7.72E+02 0.29 6.80 21.60 10000 1000
8.50E+02 0.84 6.80 21.60
8.82E+02 0.67 6.80 21.60
8.75E+02 0.43 6.80 21.60
8.32E+02 0.62 6.80 21.60
7.87E+02 1.05 6.80 21.60
7.46E+02 1.66 6.80 21.60
3.40E+00 44.57 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 .67E+03 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.68E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.73E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-103
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Li CFS-L10-1314-T01-A 1 2.22E+01
Li CFS-L10-1314-T02-A 1 1.16E+01
Li CFS-L10-1314-T03-A 1 1.33E+01
Li CFS-L10-1314-T04-A 1 1.34E+01
Li CFS-L10-1314-T05-A 1 1.35E+01
Li CFS-L10-1314-T06-A 1 1.14E+01
Li CFS-L10-1314-T07-A 1 1.26E+01
Li CFS-L10-1314-T08-A 1 1.16E+01
Li CFS-L10-1314-T09-A 1 1.26E+01
Li CFS-L10-1314-T01-B 1 1.55E+01
Li CFS-L10-1314-T02-B 1 9.92E+00
Li CFS-L10-1314-T03-B 1 1.13E+01
Li CFS-L10-1314-T04-B 1 1.25E+01
Li CFS-L10-1314-T05-B 1 1.25E+01
Li CFS-L10-1314-T06-B 1 1.19E+01
Li CFS-L10-1314-T07-B 1 1.46E+01
Li CFS-L10-1314-T08-B 1 1.13E+01
Li CFS-L10-1314-T09-B 1 1.38E+01
Li CFS-L10-1314-T01-C 1 1.72E+01
Li CFS-L10-1314-T02-C 1 9.24E+00
Li CFS-L10-1314-T03-C 1 1.25E+01
Li CFS-L10-1314-T04-C 1 1.31E+01
Li CFS-L10-1314-T05-C 1 1.14E+01
Li CFS-L10-1314-T06-C 1 1.39E+01
Li CFS-L10-1314-T07-C 1 1.32E+01
Li CFS-L10-1314-T08-C 1 1.43E+01
Li CFS-L10-1314-T09-C 1 1.25E+01
Li CFS-L10-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.22E+01 12.69 1.90 6.00
1.16E+01 14.95 1.90 6.00
1.33E+01 27.56 1.90 6.00 10000 1000
1.34E+01 15.44 1.90 6.00
1.35E+01 12.61 1.90 6.00
1.14E+01 19.89 1.90 6.00
1.26E+01 7.17 1.90 6.00
1.16E+01 40.93 1.90 6.00
1.26E+01 6.17 1.90 6.00
1.55E+01 8.79 1.90 6.00
9.92E+00 7.44 1.90 6.00
1.13E+01 12.03 1.90 6.00 10000 1000
1.25E+01 10.01 1.90 6.00
1.25E+01 11.31 1.90 6.00
1.19E+01 6.96 1.90 6.00
1.46E+01 10.67 1.90 6.00
1.13E+01 23.48 1.90 6.00
1.38E+01 16.70 1.90 6.00
1.72E+01 26.77 1.90 6.00
9.24E+00 6.17 1.90 6.00
1.25E+01 11.22 1.90 6.00 10000 1000
1.31E+01 9.66 1.90 6.00
1.14E+01 6.31 1.90 6.00
1.39E+01 15.30 1.90 6.00
1.32E+01 5.09 1.90 6.00
1.43E+01 4.13 1.90 6.00
1.25E+01 9.81 1.90 6.00
9.50E-01 8.10 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-104
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Mn CFS-L10-1314-T01-A 1 1.82E+04
Mn CFS-L10-1314-T02-A 1 7.23E+03
Mn CFS-L10-1314-T03-A 1 4.82E+03
Mn CFS-L10-1314-T04-A 1 3.51E+03
Mn CFS-L10-1314-T05-A 1 2.43E+03
Mn CFS-L10-1314-T06-A 1 9.55E+02
Mn CFS-L10-1314-T07-A 1 5.74E+02
Mn CFS-L10-1314-T08-A 1 3.50E+02
Mn CFS-L10-1314-T09-A 1 2.69E+02
Mn CFS-L10-1314-T01-B 1 1.12E+04
Mn CFS-L10-1314-T02-B 1 1.01E+04
Mn CFS-L10-1314-T03-B 1 5.75E+03
Mn CFS-L10-1314-T04-B 1 4.16E+03
Mn CFS-L10-1314-T05-B 1 3.06E+03
Mn CFS-L10-1314-T06-B 1 1.14E+03
Mn CFS-L10-1314-T07-B 1 6.63E+02
Mn CFS-L10-1314-T08-B 1 3.50E+02
Mn CFS-L10-1314-T09-B 1 2.65E+02
Mn CFS-L10-1314-T01-C 1 1.35E+04
Mn CFS-L10-1314-T02-C 1 8.45E+03
Mn CFS-L10-1314-T03-C 1 5.16E+03
Mn CFS-L10-1314-T04-C 1 3.72E+03
Mn CFS-L10-1314-T05-C 1 2.84E+03
Mn CFS-L10-1314-T06-C 1 1.29E+03
Mn CFS-L10-1314-T07-C 1 5.13E+02
Mn CFS-L10-1314-T08-C 1 3.76E+02
Mn CFS-L10-1314-T09-C 1 2.70E+02
Mn CFS-L10-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.82E+04 0.24 2.00 6.40
7.23E+03 1.30 2.00 6.40
4.82E+03 1.04 2.00 6.40 10000 1000
3.51 E+03 0.22 2.00 6.40
2.43E+03 0.60 2.00 6.40
9.55E+02 1.78 2.00 6.40
5.74E+02 1.38 2.00 6.40
3.50E+02 0.43 2.00 6.40
2.69E+02 1.68 2.00 6.40
1.12E+04 0.69 2.00 6.40
1.01E+04 0.32 2.00 6.40
5.75E+03 0.58 2.00 6.40 10000 1000
4.16E+03 0.68 2.00 6.40
3.06E+03 1.20 2.00 6.40
1.14E+03 0.62 2.00 6.40
6.63E+02 1.39 2.00 6.40
3.50E+02 0.80 2.00 6.40
2.65E+02 0.56 2.00 6.40
1.35E+04 0.95 2.00 6.40
8.45E+03 0.74 2.00 6.40
5.16E+03 0.67 2.00 6.40 10000 1000
3.72E+03 1.70 2.00 6.40
2.84E+03 0.17 2.00 6.40
1.29E+03 1.12 2.00 6.40
5.13E+02 1.37 2.00 6.40
3.76E+02 1.78 2.00 6.40
2.70E+02 0.90 2.00 6.40
1.00E+00 2.65 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.85E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.77E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.17E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-105
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Mg CFS-L10-1314-T01-A 1 2.03E+06
Mg CFS-L10-1314-T02-A 1 7.55E+05
Mg CFS-L10-1314-T03-A 1 1.14E+05
Mg CFS-L10-1314-T04-A 1 4.60E+04
Mg CFS-L10-1314-T05-A 1 2.76E+04
Mg CFS-L10-1314-T06-A 1 1.70E+04
Mg CFS-L10-1314-T07-A 1 1.12E+04
Mg CFS-L10-1314-T08-A 1 8.69E+03
Mg CFS-L10-1314-T09-A 1 6.02E+03
Mg CFS-L10-1314-T01-B 1 1.90E+06
Mg CFS-L10-1314-T02-B 1 8.15E+05
Mg CFS-L10-1314-T03-B 1 2.06E+05
Mg CFS-L10-1314-T04-B 1 6.16E+04
Mg CFS-L10-1314-T05-B 1 3.11E+04
Mg CFS-L10-1314-T06-B 1 1.70E+04
Mg CFS-L10-1314-T07-B 1 1.33E+04
Mg CFS-L10-1314-T08-B 1 7.14E+03
Mg CFS-L10-1314-T09-B 1 5.78E+03
Mg CFS-L10-1314-T01-C 1 1.92E+06
Mg CFS-L10-1314-T02-C 1 7.42E+05
Mg CFS-L10-1314-T03-C 1 1.65E+05
Mg CFS-L10-1314-T04-C 1 6.31E+04
Mg CFS-L10-1314-T05-C 1 3.10E+04
Mg CFS-L10-1314-T06-C 1 1.46E+04
Mg CFS-L10-1314-T07-C 1 1.27E+04
Mg CFS-L10-1314-T08-C 1 8.70E+03
Mg CFS-L10-1314-T09-C 1 5.17E+03
Mg CFS-L10-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.03E+06 0.57 1.00 3.18
7.55E+05 1.23 1.00 3.18
1.14E+05 0.44 1.00 3.18 10000 1000
4.60E+04 0.42 1.00 3.18
2.76E+04 0.68 1.00 3.18
1.70E+04 0.34 1.00 3.18
1.12E+04 0.54 1.00 3.18
8.69E+03 1.38 1.00 3.18
6.02E+03 0.43 1.00 3.18
1.90E+06 1.04 1.00 3.18
8.15E+05 0.64 1.00 3.18
2.06E+05 1.06 1.00 3.18 10000 1000
6.16E+04 0.73 1.00 3.18
3.11E+04 1.10 1.00 3.18
1.70E+04 1.38 1.00 3.18
1.33E+04 0.55 1.00 3.18
7.14E+03 1.21 1.00 3.18
5.78E+03 0.71 1.00 3.18
1.92E+06 0.37 1.00 3.18
7.42E+05 0.77 1.00 3.18
1.65E+05 1.14 1.00 3.18 10000 1000
6.31E+04 0.80 1.00 3.18
3.10E+04 0.15 1.00 3.18
1.46E+04 1.10 1.00 3.18
1.27E+04 0.69 1.00 3.18
8.70E+03 0.35 1.00 3.18
5.17E+03 1.31 1.00 3.18
5.00E-01 9.01 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.15E+05 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.07E+05 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.66E+05 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-106
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Mo CFS-L10-1314-T01-A 1 2.93E+01
Mo CFS-L10-1314-T02-A 1 1.36E+01
Mo CFS-L10-1314-T03-A 1 1.11E+01
Mo CFS-L10-1314-T04-A 1 9.59E+00
Mo CFS-L10-1314-T05-A 1 6.47E+00
Mo CFS-L10-1314-T06-A 1 6.12E+00
Mo CFS-L10-1314-T07-A 1 4.44E+00
Mo CFS-L10-1314-T08-A 1 6.46E+00
Mo CFS-L10-1314-T09-A 1 6.17E+00
Mo CFS-L10-1314-T01-B 1 1.84E+01
Mo CFS-L10-1314-T02-B 1 1.67E+01
Mo CFS-L10-1314-T03-B 1 1.21E+01
Mo CFS-L10-1314-T04-B 1 9.14E+00
Mo CFS-L10-1314-T05-B 1 6.60E+00
Mo CFS-L10-1314-T06-B 1 7.22E+00
Mo CFS-L10-1314-T07-B 1 6.07E+00
Mo CFS-L10-1314-T08-B 1 6.93E+00
Mo CFS-L10-1314-T09-B 1 7.42E+00
Mo CFS-L10-1314-T01-C 1 2.20E+01
Mo CFS-L10-1314-T02-C 1 1.41E+01
Mo CFS-L10-1314-T03-C 1 1.11E+01
Mo CFS-L10-1314-T04-C 1 1.08E+01
Mo CFS-L10-1314-T05-C 1 7.68E+00
Mo CFS-L10-1314-T06-C 1 5.10E+00
Mo CFS-L10-1314-T07-C 1 6.63E+00
Mo CFS-L10-1314-T08-C 1 5.55E+00
Mo CFS-L10-1314-T09-C 1 3.13E+00 E
Mo CFS-L10-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.93E+01 4.49 1.20 3.82
1.36E+01 8.40 1.20 3.82
1.11E+01 3.61 1.20 3.82 10000 1000
9.59E+00 1.12 1.20 3.82
6.47E+00 4.22 1.20 3.82
6.12E+00 1.38 1.20 3.82
4.44E+00 1.18 1.20 3.82
6.46E+00 2.94 1.20 3.82
6.17E+00 2.52 1.20 3.82
1.84E+01 11.79 1.20 3.82
1.67E+01 9.67 1.20 3.82
1.21E+01 2.59 1.20 3.82 10000 1000
9.14E+00 1.81 1.20 3.82
6.60E+00 5.78 1.20 3.82
7.22E+00 7.48 1.20 3.82
6.07E+00 1.09 1.20 3.82
6.93E+00 4.08 1.20 3.82
7.42E+00 3.16 1.20 3.82
2.20E+01 6.06 1.20 3.82
1.41E+01 8.19 1.20 3.82
1.11E+01 1.30 1.20 3.82 10000 1000
1.08E+01 5.34 1.20 3.82
7.68E+00 9.48 1.20 3.82
5.10E+00 1.76 1.20 3.82
6.63E+00 2.81 1.20 3.82
5.55E+00 6.33 1.20 3.82
3.13E+00 7.75 1.20 3.82
6.00E-01 4.60 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.07E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-107
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Ni CFS-L10-1314-T01-A 1 8.86E+02
Ni CFS-L10-1314-T02-A 1 4.63E+02
Ni CFS-L10-1314-T03-A 1 3.93E+02
Ni CFS-L10-1314-T04-A 1 3.60E+02
Ni CFS-L10-1314-T05-A 1 3.37E+02
Ni CFS-L10-1314-T06-A 1 2.30E+02
Ni CFS-L10-1314-T07-A 1 1.77E+02
Ni CFS-L10-1314-T08-A 1 1.01E+02
Ni CFS-L10-1314-T09-A 1 5.49E+01
Ni CFS-L10-1314-T01-B 1 6.35E+02
Ni CFS-L10-1314-T02-B 1 5.65E+02
Ni CFS-L10-1314-T03-B 1 3.91E+02
Ni CFS-L10-1314-T04-B 1 3.70E+02
Ni CFS-L10-1314-T05-B 1 3.49E+02
Ni CFS-L10-1314-T06-B 1 2.55E+02
Ni CFS-L10-1314-T07-B 1 1.78E+02
Ni CFS-L10-1314-T08-B 1 1.05E+02
Ni CFS-L10-1314-T09-B 1 6.47E+01
Ni CFS-L10-1314-T01-C 1 7.72E+02
Ni CFS-L10-1314-T02-C 1 5.41E+02
Ni CFS-L10-1314-T03-C 1 4.09E+02
Ni CFS-L10-1314-T04-C 1 3.61E+02
Ni CFS-L10-1314-T05-C 1 3.30E+02
Ni CFS-L10-1314-T06-C 1 2.48E+02
Ni CFS-L10-1314-T07-C 1 1.56E+02
Ni CFS-L10-1314-T08-C 1 1.06E+02
Ni CFS-L10-1314-T09-C 1 7.17E+01
Ni CFS-L10-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.86E+02 0.49 1.80 5.70
4.63E+02 0.36 1.80 5.70
3.93E+02 0.99 1.80 5.70 10000 1000
3.60E+02 1.02 1.80 5.70
3.37E+02 1.05 1.80 5.70
2.30E+02 0.94 1.80 5.70
1.77E+02 1.00 1.80 5.70
1.01E+02 1.16 1.80 5.70
5.49E+01 1.86 1.80 5.70
6.35E+02 1.16 1.80 5.70
5.65E+02 0.73 1.80 5.70
3.91E+02 0.26 1.80 5.70 10000 1000
3.70E+02 0.48 1.80 5.70
3.49E+02 0.40 1.80 5.70
2.55E+02 1.03 1.80 5.70
1.78E+02 2.98 1.80 5.70
1.05E+02 4.71 1.80 5.70
6.47E+01 4.10 1.80 5.70
7.72E+02 0.29 1.80 5.70
5.41 E+02 0.44 1.80 5.70
4.09E+02 1.05 1.80 5.70 10000 1000
3.61E+02 1.10 1.80 5.70
3.30E+02 1.14 1.80 5.70
2.48E+02 1.27 1.80 5.70
1.56E+02 1.74 1.80 5.70
1.06E+02 1.02 1.80 5.70
7.17E+01 1.68 1.80 5.70
9.00E-01 21.84 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.37E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.37E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.35E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-108
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
P CFS-L10-1314-T01-A 1 5.96E+01
P CFS-L10-1314-T02-A 1 3.32E+01
P CFS-L10-1314-T03-A 1 2.76E+01
P CFS-L10-1314-T04-A 1 2.21E+01
P CFS-L10-1314-T05-A 1 1.85E+01
P CFS-L10-1314-T06-A 1 1.64E+01
P CFS-L10-1314-T07-A 1 1.70E+01
P CFS-L10-1314-T08-A 1 1.39E+01
P CFS-L10-1314-T09-A 1 1.73E+01
P CFS-L10-1314-T01-B 1 6.94E+01
P CFS-L10-1314-T02-B 1 3.92E+01
P CFS-L10-1314-T03-B 1 2.83E+01
P CFS-L10-1314-T04-B 1 1.99E+01
P CFS-L10-1314-T05-B 1 1.69E+01
P CFS-L10-1314-T06-B 1 1.49E+01
P CFS-L10-1314-T07-B 1 1.28E+01
P CFS-L10-1314-T08-B 1 1.37E+01
P CFS-L10-1314-T09-B 1 1.62E+01
P CFS-L10-1314-T01-C 1 5.73E+01
P CFS-L10-1314-T02-C 1 3.88E+01
P CFS-L10-1314-T03-C 1 2.51E+01
P CFS-L10-1314-T04-C 1 2.08E+01
P CFS-L10-1314-T05-C 1 1.89E+01
P CFS-L10-1314-T06-C 1 1.67E+01
P CFS-L10-1314-T07-C 1 1.45E+01
P CFS-L10-1314-T08-C 1 1.48E+01
P CFS-L10-1314-T09-C 1 1.60E+01
P CFS-L10-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.96E+01 7.29 3.70 11.80
3.32E+01 9.58 3.70 11.80
2.76E+01 4.77 3.70 11.80 10000 1000
2.21E+01 11.78 3.70 11.80
1.85E+01 8.06 3.70 11.80
1.64E+01 10.99 3.70 11.80
1.70E+01 9.10 3.70 11.80
1.39E+01 16.77 3.70 11.80
1.73E+01 3.61 3.70 11.80
6.94E+01 15.88 3.70 11.80
3.92E+01 10.99 3.70 11.80
2.83E+01 14.79 3.70 11.80 10000 1000
1.99E+01 10.51 3.70 11.80
1.69E+01 4.62 3.70 11.80
1.49E+01 5.26 3.70 11.80
1.28E+01 11.72 3.70 11.80
1.37E+01 15.18 3.70 11.80
1.62E+01 3.90 3.70 11.80
5.73E+01 20.79 3.70 11.80
3.88E+01 11.17 3.70 11.80
2.51E+01 10.88 3.70 11.80 10000 1000
2.08E+01 19.17 3.70 11.80
1.89E+01 3.41 3.70 11.80
1.67E+01 5.41 3.70 11.80
1.45E+01 9.09 3.70 11.80
1.48E+01 11.81 3.70 11.80
1.60E+01 20.42 3.70 11.80
1.85E+00 13.15 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.16E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.20E+03 117% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-109
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
K CFS-L10-1314-T01-A 1 1.20E+05
K CFS-L10-1314-T02-A 1 4.97E+04
K CFS-L10-1314-T03-A 1 2.52E+04
K CFS-L10-1314-T04-A 1 1.92E+04
K CFS-L10-1314-T05-A 1 1.50E+04
K CFS-L10-1314-T06-A 1 8.06E+03
K CFS-L10-1314-T07-A 1 5.73E+03
K CFS-L10-1314-T08-A 1 3.26E+03
K CFS-L10-1314-T09-A 1 2.21E+03
K CFS-L10-1314-T01-B 1 1.19E+05
K CFS-L10-1314-T02-B 1 5.17E+04
K CFS-L10-1314-T03-B 1 3.07E+04
K CFS-L10-1314-T04-B 1 2.14E+04
K CFS-L10-1314-T05-B 1 1.71E+04
K CFS-L10-1314-T06-B 1 9.10E+03
K CFS-L10-1314-T07-B 1 5.88E+03
K CFS-L10-1314-T08-B 1 3.35E+03
K CFS-L10-1314-T09-B 1 2.34E+03
K CFS-L10-1314-T01-C 1 1.18E+05
K CFS-L10-1314-T02-C 1 4.76E+04
K CFS-L10-1314-T03-C 1 2.70E+04
K CFS-L10-1314-T04-C 1 1.96E+04
K CFS-L10-1314-T05-C 1 1.60E+04
K CFS-L10-1314-T06-C 1 9.34E+03
K CFS-L10-1314-T07-C 1 5.08E+03
K CFS-L10-1314-T08-C 1 3.50E+03
K CFS-L10-1314-T09-C 1 2.38E+03
K CFS-L10-1314-B01-A 1 1.28E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.20E+05 0.56 1.60 5.09
4.97E+04 0.91 1.60 5.09
2.52E+04 1.50 1.60 5.09 10000 1000
1.92E+04 0.29 1.60 5.09
1.50E+04 0.74 1.60 5.09
8.06E+03 0.34 1.60 5.09
5.73E+03 1.24 1.60 5.09
3.26E+03 0.19 1.60 5.09
2.21 E+03 0.89 1.60 5.09
1.19E+05 0.63 1.60 5.09
5.17E+04 0.36 1.60 5.09
3.07E+04 0.41 1.60 5.09 10000 1000
2.14E+04 0.35 1.60 5.09
1.71E+04 0.21 1.60 5.09
9.10E+03 0.91 1.60 5.09
5.88E+03 0.83 1.60 5.09
3.35E+03 0.72 1.60 5.09
2.34E+03 0.55 1.60 5.09
1.18E+05 1.10 1.60 5.09
4.76E+04 0.55 1.60 5.09
2.70E+04 0.59 1.60 5.09 10000 1000
1.96E+04 1.09 1.60 5.09
1.60E+04 0.53 1.60 5.09
9.34E+03 0.45 1.60 5.09
5.08E+03 0.33 1.60 5.09
3.50E+03 0.58 1.60 5.09
2.38E+03 1.12 1.60 5.09
1.28E+01 3.42 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.62E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.17E+04 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.79E+04 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-110
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Se CFS-L10-1314-T01-A 1 1.77E+03
Se CFS-L10-1314-T02-A 1 5.23E+02
Se CFS-L10-1314-T03-A 1 1.45E+02
Se CFS-L10-1314-T04-A 1 9.62E+01
Se CFS-L10-1314-T05-A 1 8.27E+01
Se CFS-L10-1314-T06-A 1 7.00E+01
Se CFS-L10-1314-T07-A 1 2.01E+01 E
Se CFS-L10-1314-T08-A 1 7.50E+00 U1/2
Se CFS-L10-1314-T09-A 1 7.50E+00 U1/2
Se CFS-L10-1314-T01-B 1 1.75E+03
Se CFS-L10-1314-T02-B 1 5.42E+02
Se CFS-L10-1314-T03-B 1 1.77E+02
Se CFS-L10-1314-T04-B 1 1.29E+02
Se CFS-L10-1314-T05-B 1 8.06E+01
Se CFS-L10-1314-T06-B 1 6.70E+01
Se CFS-L10-1314-T07-B 1 2.54E+01 E
Se CFS-L10-1314-T08-B 1 7.50E+00 U1/2
Se CFS-L10-1314-T09-B 1 7.50E+00 U1/2
Se CFS-L10-1314-T01-C 1 1.61E+03
Se CFS-L10-1314-T02-C 1 4.98E+02
Se CFS-L10-1314-T03-C 1 1.72E+02
Se CFS-L10-1314-T04-C 1 1.14E+02
Se CFS-L10-1314-T05-C 1 8.34E+01
Se CFS-L10-1314-T06-C 1 6.82E+01
Se CFS-L10-1314-T07-C 1 2.38E+01 E
Se CFS-L10-1314-T08-C 1 7.50E+00 U1/2
Se CFS-L10-1314-T09-C 1 7.50E+00 U1/2
Se CFS-L10-1314-B01-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.77E+03 2.85 15.00 47.70
5.23E+02 5.34 15.00 47.70
1.45E+02 13.93 15.00 47.70 10000 1000
9.62E+01 6.50 15.00 47.70
8.27E+01 11.48 15.00 47.70
7.00E+01 5.86 15.00 47.70
2.01E+01 28.20 15.00 47.70
7.50E+00 8.69 15.00 47.70
7.50E+00 18.95 15.00 47.70
1.75E+03 2.28 15.00 47.70
5.42E+02 3.36 15.00 47.70
1.77E+02 6.52 15.00 47.70 10000 1000
1.29E+02 15.78 15.00 47.70
8.06E+01 7.69 15.00 47.70
6.70E+01 5.07 15.00 47.70
2.54E+01 18.74 15.00 47.70
7.50E+00 8.18 15.00 47.70
7.50E+00 27.01 15.00 47.70
1.61E+03 2.46 15.00 47.70
4.98E+02 5.80 15.00 47.70
1.72E+02 4.94 15.00 47.70 10000 1000
1.14E+02 10.86 15.00 47.70
8.34E+01 23.80 15.00 47.70
6.82E+01 11.16 15.00 47.70
2.38E+01 21.85 15.00 47.70
7.50E+00 16.53 15.00 47.70
7.50E+00 29.37 15.00 47.70
7.50E+00 17.53 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.13E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-111
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Si CFS-L10-1314-T01-A 1 7.62E+03
Si CFS-L10-1314-T02-A 1 6.62E+03
Si CFS-L10-1314-T03-A 1 6.24E+03
Si CFS-L10-1314-T04-A 1 6.02E+03
Si CFS-L10-1314-T05-A 1 5.76E+03
Si CFS-L10-1314-T06-A 1 5.02E+03
Si CFS-L10-1314-T07-A 1 4.48E+03
Si CFS-L10-1314-T08-A 1 4.02E+03
Si CFS-L10-1314-T09-A 1 3.60E+03
Si CFS-L10-1314-T01-B 1 7.30E+03
Si CFS-L10-1314-T02-B 1 6.81E+03
Si CFS-L10-1314-T03-B 1 6.30E+03
Si CFS-L10-1314-T04-B 1 6.08E+03
Si CFS-L10-1314-T05-B 1 5.90E+03
Si CFS-L10-1314-T06-B 1 5.25E+03
Si CFS-L10-1314-T07-B 1 4.72E+03
Si CFS-L10-1314-T08-B 1 3.88E+03
Si CFS-L10-1314-T09-B 1 3.71E+03
Si CFS-L10-1314-T01-C 1 7.70E+03
Si CFS-L10-1314-T02-C 1 6.96E+03
Si CFS-L10-1314-T03-C 1 6.36E+03
Si CFS-L10-1314-T04-C 1 6.03E+03
Si CFS-L10-1314-T05-C 1 5.73E+03
Si CFS-L10-1314-T06-C 1 4.98E+03
Si CFS-L10-1314-T07-C 1 4.57E+03
Si CFS-L10-1314-T08-C 1 4.11E+03
Si CFS-L10-1314-T09-C 1 3.58E+03
Si CFS-L10-1314-B01-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.62E+03 0.65 1.10 3.50
6.62E+03 1.02 1.10 3.50
6.24E+03 1.16 1.10 3.50 10000 1000
6.02E+03 0.77 1.10 3.50
5.76E+03 0.61 1.10 3.50
5.02E+03 0.40 1.10 3.50
4.48E+03 3.06 1.10 3.50
4.02E+03 1.28 1.10 3.50
3.60E+03 1.43 1.10 3.50
7.30E+03 0.47 1.10 3.50
6.81E+03 0.17 1.10 3.50
6.30E+03 0.34 1.10 3.50 10000 1000
6.08E+03 0.13 1.10 3.50
5.90E+03 1.80 1.10 3.50
5.25E+03 1.04 1.10 3.50
4.72E+03 1.25 1.10 3.50
3.88E+03 0.75 1.10 3.50
3.71 E+03 0.89 1.10 3.50
7.70E+03 0.83 1.10 3.50
6.96E+03 0.59 1.10 3.50
6.36E+03 0.24 1.10 3.50 10000 1000
6.03E+03 2.04 1.10 3.50
5.73E+03 0.78 1.10 3.50
4.98E+03 1.40 1.10 3.50
4.57E+03 0.47 1.10 3.50
4. 11 E+03 0.37 1.10 3.50
3.58E+03 1.67 1.10 3.50
5.50E-01 4.22 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
7.22E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.32E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.32E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-112
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
Na CFS-L10-1314-T01-A 1 2.93E+05
Na CFS-L10-1314-T02-A 1 1.81E+05
Na CFS-L10-1314-T03-A 1 2.87E+04
Na CFS-L10-1314-T04-A 1 1.08E+04
Na CFS-L10-1314-T05-A 1 7.60E+03
Na CFS-L10-1314-T06-A 1 3.78E+03
Na CFS-L10-1314-T07-A 1 2.11E+03
Na CFS-L10-1314-T08-A 1 1.80E+03
Na CFS-L10-1314-T09-A 1 1.43E+03
Na CFS-L10-1314-T01-B 1 2.31E+05
Na CFS-L10-1314-T02-B 1 1.96E+05
Na CFS-L10-1314-T03-B 1 3.58E+04
Na CFS-L10-1314-T04-B 1 1.13E+04
Na CFS-L10-1314-T05-B 1 6.68E+03
Na CFS-L10-1314-T06-B 1 3.32E+03
Na CFS-L10-1314-T07-B 1 2.28E+03
Na CFS-L10-1314-T08-B 1 1.56E+03
Na CFS-L10-1314-T09-B 1 1.37E+03
Na CFS-L10-1314-T01-C 1 3.01E+05
Na CFS-L10-1314-T02-C 1 1.47E+05
Na CFS-L10-1314-T03-C 1 2.45E+04
Na CFS-L10-1314-T04-C 1 9.47E+03
Na CFS-L10-1314-T05-C 1 5.80E+03
Na CFS-L10-1314-T06-C 1 3.34E+03
Na CFS-L10-1314-T07-C 1 2.35E+03
Na CFS-L10-1314-T08-C 1 1.75E+03
Na CFS-L10-1314-T09-C 1 1.27E+03
Na CFS-L10-1314-B01-A 1 1.25E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.93E+05 0.96 2.50 8.00
1.81E+05 0.92 2.50 8.00
2.87E+04 1.95 2.50 8.00 10000 1000
1.08E+04 0.43 2.50 8.00
7.60E+03 0.77 2.50 8.00
3.78E+03 0.49 2.50 8.00
2.11E+03 1.21 2.50 8.00
1.80E+03 0.37 2.50 8.00
1.43E+03 0.67 2.50 8.00
2.31 E+05 0.49 2.50 8.00
1.96E+05 0.10 2.50 8.00
3.58E+04 0.46 2.50 8.00 10000 1000
1.13E+04 0.41 2.50 8.00
6.68E+03 0.32 2.50 8.00
3.32E+03 0.83 2.50 8.00
2.28E+03 1.15 2.50 8.00
1.56E+03 0.89 2.50 8.00
1.37E+03 0.59 2.50 8.00
3.01 E+05 0.87 2.50 8.00
1.47E+05 0.88 2.50 8.00
2.45E+04 0.54 2.50 8.00 10000 1000
9.47E+03 0.73 2.50 8.00
5.80E+03 0.40 2.50 8.00
3.34E+03 0.65 2.50 8.00
2.35E+03 0.23 2.50 8.00
1.75E+03 1.14 2.50 8.00
1.27E+03 0.63 2.50 8.00
1.25E+00 1.94 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.97E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.67E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.55E+04 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-113
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Sr CFS-L10-1314-T01-A 1 4.79E+03
Sr CFS-L10-1314-T02-A 1 3.29E+03
Sr CFS-L10-1314-T03-A 1 2.98E+03
Sr CFS-L10-1314-T04-A 1 2.66E+03
Sr CFS-L10-1314-T05-A 1 2.28E+03
Sr CFS-L10-1314-T06-A 1 1.73E+03
Sr CFS-L10-1314-T07-A 1 1.55E+03
Sr CFS-L10-1314-T08-A 1 1.41E+03
Sr CFS-L10-1314-T09-A 1 1.29E+03
Sr CFS-L10-1314-T01-B 1 3.91E+03
Sr CFS-L10-1314-T02-B 1 3.63E+03
Sr CFS-L10-1314-T03-B 1 3.10E+03
Sr CFS-L10-1314-T04-B 1 2.86E+03
Sr CFS-L10-1314-T05-B 1 2.52E+03
Sr CFS-L10-1314-T06-B 1 1.83E+03
Sr CFS-L10-1314-T07-B 1 1.62E+03
Sr CFS-L10-1314-T08-B 1 1.35E+03
Sr CFS-L10-1314-T09-B 1 1.33E+03
Sr CFS-L10-1314-T01-C 1 4.18E+03
Sr CFS-L10-1314-T02-C 1 3.33E+03
Sr CFS-L10-1314-T03-C 1 2.88E+03
Sr CFS-L10-1314-T04-C 1 2.60E+03
Sr CFS-L10-1314-T05-C 1 2.38E+03
Sr CFS-L10-1314-T06-C 1 1.83E+03
Sr CFS-L10-1314-T07-C 1 1.54E+03
Sr CFS-L10-1314-T08-C 1 1.42E+03
Sr CFS-L10-1314-T09-C 1 1.22E+03
Sr CFS-L10-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.79E+03 1.45 1.00 3.18
3.29E+03 0.94 1.00 3.18
2.98E+03 1.79 1.00 3.18 10000 1000
2.66E+03 0.71 1.00 3.18
2.28E+03 1.07 1.00 3.18
1.73E+03 0.80 1.00 3.18
1.55E+03 2.35 1.00 3.18
1.41E+03 1.86 1.00 3.18
1.29E+03 1.06 1.00 3.18
3.91E+03 0.28 1.00 3.18
3.63E+03 0.61 1.00 3.18
3.10E+03 0.57 1.00 3.18 10000 1000
2.86E+03 0.18 1.00 3.18
2.52E+03 1.94 1.00 3.18
1.83E+03 1.06 1.00 3.18
1.62E+03 0.92 1.00 3.18
1.35E+03 0.78 1.00 3.18
1.33E+03 0.90 1.00 3.18
4.18E+03 0.77 1.00 3.18
3.33E+03 0.43 1.00 3.18
2.88E+03 0.38 1.00 3.18 10000 1000
2.60E+03 2.48 1.00 3.18
2.38E+03 1.43 1.00 3.18
1.83E+03 0.98 1.00 3.18
1.54E+03 0.70 1.00 3.18
1.42E+03 0.64 1.00 3.18
1.22E+03 1.29 1.00 3.18
5.00E-01 32.98 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.97E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.14E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.83E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-114
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
S CFS-L10-1314-T01-A 1 2.39E+06
S CFS-L10-1314-T02-A 1 8.86E+05
S CFS-L10-1314-T03-A 1 6.30E+05
S CFS-L10-1314-T04-A 1 5.60E+05
S CFS-L10-1314-T05-A 1 5.46E+05
S CFS-L10-1314-T06-A 1 5.23E+05
S CFS-L10-1314-T07-A 1 5.18E+05
S CFS-L10-1314-T08-A 1 5.15E+05
S CFS-L10-1314-T09-A 1 4.93E+05
S CFS-L10-1314-T01-B 1 1.50E+06
S CFS-L10-1314-T02-B 1 1.40E+06
S CFS-L10-1314-T03-B 1 7.31E+05
S CFS-L10-1314-T04-B 1 5.79E+05
S CFS-L10-1314-T05-B 1 5.46E+05
S CFS-L10-1314-T06-B 1 5.28E+05
S CFS-L10-1314-T07-B 1 5.16E+05
S CFS-L10-1314-T08-B 1 4.80E+05
S CFS-L10-1314-T09-B 1 5.06E+05
S CFS-L10-1314-T01-C 1 1.75E+06
S CFS-L10-1314-T02-C 1 1.12E+06
S CFS-L10-1314-T03-C 1 6.91E+05
S CFS-L10-1314-T04-C 1 5.90E+05
S CFS-L10-1314-T05-C 1 5.55E+05
S CFS-L10-1314-T06-C 1 5.27E+05
S CFS-L10-1314-T07-C 1 5.26E+05
S CFS-L10-1314-T08-C 1 5.12E+05
S CFS-L10-1314-T09-C 1 4.42E+05
S CFS-L10-1314-B01-A 1 2.13E+01 E
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.39E+06 0.39 6.80 21.60
8.86E+05 0.61 6.80 21.60
6.30E+05 1.12 6.80 21.60 10000 1000
5.60E+05 0.41 6.80 21.60
5.46E+05 0.70 6.80 21.60
5.23E+05 0.25 6.80 21.60
5.18E+05 1.44 6.80 21.60
5.15E+05 0.62 6.80 21.60
4.93E+05 0.50 6.80 21.60
1.50E+06 0.57 6.80 21.60
1.40E+06 0.25 6.80 21.60
7.31E+05 0.28 6.80 21.60 10000 1000
5.79E+05 0.20 6.80 21.60
5.46E+05 0.54 6.80 21.60
5.28E+05 1.19 6.80 21.60
5.16E+05 1.06 6.80 21.60
4.80E+05 0.52 6.80 21.60
5.06E+05 0.70 6.80 21.60
1.75E+06 1.69 6.80 21.60
1.12E+06 0.68 6.80 21.60
6.91E+05 0.49 6.80 21.60 10000 1000
5.90E+05 0.58 6.80 21.60
5.55E+05 0.24 6.80 21.60
5.27E+05 0.58 6.80 21.60
5.26E+05 0.37 6.80 21.60
5.12E+05 0.48 6.80 21.60
4.42E+05 1.23 6.80 21.60
2.13E+01 0.56 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.31E+05 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.32E+05 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.92E+05 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-115
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Tl CFS-L10-1314-T01-A 1 1.79E+03
Tl CFS-L10-1314-T02-A 1 7.74E+02
Tl CFS-L10-1314-T03-A 1 5.49E+02
Tl CFS-L10-1314-T04-A 1 4.34E+02
Tl CFS-L10-1314-T05-A 1 3.55E+02
Tl CFS-L10-1314-T06-A 1 2.32E+02
Tl CFS-L10-1314-T07-A 1 1.74E+02
Tl CFS-L10-1314-T08-A 1 1.20E+02
Tl CFS-L10-1314-T09-A 1 9.25E+01
Tl CFS-L10-1314-T01-B 1 1.18E+03
Tl CFS-L10-1314-T02-B 1 1.08E+03
Tl CFS-L10-1314-T03-B 1 6.25E+02
Tl CFS-L10-1314-T04-B 1 4.65E+02
Tl CFS-L10-1314-T05-B 1 3.95E+02
Tl CFS-L10-1314-T06-B 1 2.51E+02
Tl CFS-L10-1314-T07-B 1 1.77E+02
Tl CFS-L10-1314-T08-B 1 1.12E+02
Tl CFS-L10-1314-T09-B 1 9.21E+01
Tl CFS-L10-1314-T01-C 1 1.36E+03
Tl CFS-L10-1314-T02-C 1 8.90E+02
Tl CFS-L10-1314-T03-C 1 5.59E+02
Tl CFS-L10-1314-T04-C 1 4.44E+02
Tl CFS-L10-1314-T05-C 1 3.67E+02
Tl CFS-L10-1314-T06-C 1 2.44E+02
Tl CFS-L10-1314-T07-C 1 1.69E+02
Tl CFS-L10-1314-T08-C 1 1.25E+02
Tl CFS-L10-1314-T09-C 1 9.45E+01
Tl CFS-L10-1314-B01-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.79E+03 0.86 4.60 14.60
7.74E+02 0.57 4.60 14.60
5.49E+02 0.67 4.60 14.60 10000 1000
4.34E+02 4.95 4.60 14.60
3.55E+02 0.04 4.60 14.60
2.32E+02 3.29 4.60 14.60
1.74E+02 2.50 4.60 14.60
1.20E+02 2.88 4.60 14.60
9.25E+01 3.48 4.60 14.60
1.18E+03 1.20 4.60 14.60
1.08E+03 1.22 4.60 14.60
6.25E+02 2.18 4.60 14.60 10000 1000
4.65E+02 1.43 4.60 14.60
3.95E+02 2.17 4.60 14.60
2.51E+02 1.98 4.60 14.60
1.77E+02 2.58 4.60 14.60
1.12E+02 2.38 4.60 14.60
9.21E+01 10.62 4.60 14.60
1.36E+03 0.97 4.60 14.60
8.90E+02 0.99 4.60 14.60
5.59E+02 0.69 4.60 14.60 10000 1000
4.44E+02 1.48 4.60 14.60
3.67E+02 3.05 4.60 14.60
2.44E+02 3.57 4.60 14.60
1.69E+02 3.53 4.60 14.60
1.25E+02 2.21 4.60 14.60
9.45E+01 4.72 4.60 14.60
2.30E+00 10.03 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.56E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.63E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.58E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-116
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ti CFS-L10-1314-T01-A 1 1.00E+00 U1/2
Ti CFS-L10-1314-T02-A 1 1.00E+00 U1/2
Ti CFS-L10-1314-T03-A 1 1.00E+00 U1/2
Ti CFS-L10-1314-T04-A 1 1.00E+00 U1/2
Ti CFS-L10-1314-T05-A 1 1.00E+00 U1/2
Ti CFS-L10-1314-T06-A 1 1.00E+00 U1/2
Ti CFS-L10-1314-T07-A 1 1.00E+00 U1/2
Ti CFS-L10-1314-T08-A 1 1.00E+00 U1/2
Ti CFS-L10-1314-T09-A 1 1.00E+00 U1/2
Ti CFS-L10-1314-T01-B 1 1.00E+00 U1/2
Ti CFS-L10-1314-T02-B 1 1.00E+00 U1/2
Ti CFS-L10-1314-T03-B 1 1.00E+00 U1/2
Ti CFS-L10-1314-T04-B 1 1.00E+00 U1/2
Ti CFS-L10-1314-T05-B 1 1.00E+00 U1/2
Ti CFS-L10-1314-T06-B 1 1.00E+00 U1/2
Ti CFS-L10-1314-T07-B 1 1.00E+00 U1/2
Ti CFS-L10-1314-T08-B 1 1.00E+00 U1/2
Ti CFS-L10-1314-T09-B 1 1.00E+00 U1/2
Ti CFS-L10-1314-T01-C 1 1.00E+00 U1/2
Ti CFS-L10-1314-T02-C 1 1.00E+00 U1/2
Ti CFS-L10-1314-T03-C 1 1.00E+00 U1/2
Ti CFS-L10-1314-T04-C 1 1.00E+00 U1/2
Ti CFS-L10-1314-T05-C 1 1.00E+00 U1/2
Ti CFS-L10-1314-T06-C 1 1.00E+00 U1/2
Ti CFS-L10-1314-T07-C 1 1.00E+00 U1/2
Ti CFS-L10-1314-T08-C 1 1.00E+00 U1/2
Ti CFS-L10-1314-T09-C 1 1.00E+00 U1/2
Ti CFS-L10-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 34.87 2.00 6.40
1.00E+00 603.16 2.00 6.40
1.00E+00 26.01 2.00 6.40 10000 1000
1.00E+00 64.41 2.00 6.40
1.00E+00 95.95 2.00 6.40
1.00E+00 86.81 2.00 6.40
1.00E+00 47.33 2.00 6.40
1.00E+00 13.32 2.00 6.40
1.00E+00 126.85 2.00 6.40
1.00E+00 79.73 2.00 6.40
1.00E+00 47.68 2.00 6.40
1.00E+00 31.56 2.00 6.40 10000 1000
1.00E+00 121.20 2.00 6.40
1.00E+00 64.33 2.00 6.40
1.00E+00 696.05 2.00 6.40
1.00E+00 51.68 2.00 6.40
1.00E+00 56.14 2.00 6.40
1.00E+00 179.50 2.00 6.40
1.00E+00 5.87 2.00 6.40
1.00E+00 68.05 2.00 6.40
1.00E+00 44.26 2.00 6.40 10000 1000
1.00E+00 3.98 2.00 6.40
1.00E+00 144.72 2.00 6.40
1.00E+00 92.27 2.00 6.40
1.00E+00 27.26 2.00 6.40
1.00E+00 79.10 2.00 6.40
1.00E+00 131.82 2.00 6.40
1.00E+00 158.16 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 . 1 1 E+03 1 1 1 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-117
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
V CFS-L10-1314-T01-A 1 2.61E+01
V CFS-L10-1314-T02-A 1 3.18E+01
V CFS-L10-1314-T03-A 1 3.56E+01
V CFS-L10-1314-T04-A 1 4.08E+01
V CFS-L10-1314-T05-A 1 4.00E+01
V CFS-L10-1314-T06-A 1 4.03E+01
V CFS-L10-1314-T07-A 1 4.04E+01
V CFS-L10-1314-T08-A 1 4.15E+01
V CFS-L10-1314-T09-A 1 3.93E+01
V CFS-L10-1314-T01-B 1 2.76E+01
V CFS-L10-1314-T02-B 1 2.72E+01
V CFS-L10-1314-T03-B 1 3.40E+01
V CFS-L10-1314-T04-B 1 3.72E+01
V CFS-L10-1314-T05-B 1 3.84E+01
V CFS-L10-1314-T06-B 1 3.97E+01
V CFS-L10-1314-T07-B 1 4.06E+01
V CFS-L10-1314-T08-B 1 3.61E+01
V CFS-L10-1314-T09-B 1 4.04E+01
V CFS-L10-1314-T01-C 1 2.68E+01
V CFS-L10-1314-T02-C 1 3.08E+01
V CFS-L10-1314-T03-C 1 3.53E+01
V CFS-L10-1314-T04-C 1 3.86E+01
V CFS-L10-1314-T05-C 1 3.91E+01
V CFS-L10-1314-T06-C 1 4.04E+01
V CFS-L10-1314-T07-C 1 4.08E+01
V CFS-L10-1314-T08-C 1 3.99E+01
V CFS-L10-1314-T09-C 1 3.27E+01
V CFS-L10-1314-B01-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.61 E+01 3.36 1.50 4.77
3.18E+01 2.09 1.50 4.77
3.56E+01 2.75 1.50 4.77 10000 1000
4.08E+01 1.35 1.50 4.77
4.00E+01 1.20 1.50 4.77
4.03E+01 2.73 1.50 4.77
4.04E+01 1.75 1.50 4.77
4.15E+01 2.06 1.50 4.77
3.93E+01 0.63 1.50 4.77
2.76E+01 1.70 1.50 4.77
2.72E+01 1.49 1.50 4.77
3.40E+01 1.57 1.50 4.77 10000 1000
3.72E+01 0.88 1.50 4.77
3.84E+01 1.44 1.50 4.77
3.97E+01 4.23 1.50 4.77
4.06E+01 1.32 1.50 4.77
3.61 E+01 0.85 1.50 4.77
4.04E+01 0.84 1.50 4.77
2.68E+01 2.04 1.50 4.77
3.08E+01 1.66 1.50 4.77
3.53E+01 1.84 1.50 4.77 10000 1000
3.86E+01 1.20 1.50 4.77
3.91 E+01 2.72 1.50 4.77
4.04E+01 0.76 1.50 4.77
4.08E+01 2.05 1.50 4.77
3.99E+01 1.33 1.50 4.77
3.27E+01 2.31 1.50 4.77
7.50E-01 13.28 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.08E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-118
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Zn CFS-L10-1314-T01-A 1 6.87E+04
Zn CFS-L10-1314-T02-A 1 4.43E+04
Zn CFS-L10-1314-T03-A 1 4.07E+04
Zn CFS-L10-1314-T04-A 1 3.96E+04
Zn CFS-L10-1314-T05-A 1 3.78E+04
Zn CFS-L10-1314-T06-A 1 3.04E+04
Zn CFS-L10-1314-T07-A 1 2.56E+04
Zn CFS-L10-1314-T08-A 1 1.81E+04
Zn CFS-L10-1314-T09-A 1 1.35E+04
Zn CFS-L10-1314-T01-B 1 5.56E+04
Zn CFS-L10-1314-T02-B 1 5.01E+04
Zn CFS-L10-1314-T03-B 1 3.97E+04
Zn CFS-L10-1314-T04-B 1 3.90E+04
Zn CFS-L10-1314-T05-B 1 3.82E+04
Zn CFS-L10-1314-T06-B 1 3.25E+04
Zn CFS-L10-1314-T07-B 1 2.64E+04
Zn CFS-L10-1314-T08-B 1 1.84E+04
Zn CFS-L10-1314-T09-B 1 1.50E+04
Zn CFS-L10-1314-T01-C 1 6.50E+04
Zn CFS-L10-1314-T02-C 1 5.11E+04
Zn CFS-L10-1314-T03-C 1 4.27E+04
Zn CFS-L10-1314-T04-C 1 3.99E+04
Zn CFS-L10-1314-T05-C 1 3.77E+04
Zn CFS-L10-1314-T06-C 1 3.19E+04
Zn CFS-L10-1314-T07-C 1 2.43E+04
Zn CFS-L10-1314-T08-C 1 1.93E+04
Zn CFS-L10-1314-T09-C 1 1.52E+04
Zn CFS-L10-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.87E+04 0.37 1.00 3.18
4.43E+04 0.96 1.00 3.18
4.07E+04 1.04 1.00 3.18 10000 1000
3.96E+04 0.27 1.00 3.18
3.78E+04 0.61 1.00 3.18
3.04E+04 0.09 1.00 3.18
2.56E+04 2.36 1.00 3.18
1.81E+04 0.95 1.00 3.18
1.35E+04 0.73 1.00 3.18
5.56E+04 0.56 1.00 3.18
5.01E+04 0.74 1.00 3.18
3.97E+04 0.17 1.00 3.18 10000 1000
3.90E+04 0.44 1.00 3.18
3.82E+04 0.99 1.00 3.18
3.25E+04 0.65 1.00 3.18
2.64E+04 0.77 1.00 3.18
1.84E+04 0.98 1.00 3.18
1.50E+04 0.29 1.00 3.18
6.50E+04 0.60 1.00 3.18
5.11E+04 1.12 1.00 3.18
4.27E+04 0.46 1.00 3.18 10000 1000
3.99E+04 1.60 1.00 3.18
3.77E+04 0.33 1.00 3.18
3.19E+04 1.43 1.00 3.18
2.43E+04 0.38 1.00 3.18
1.93E+04 0.21 1.00 3.18
1.52E+04 0.42 1.00 3.18
5.00E-01 2.64 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.17E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.06E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.37E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/28/12 11:53 AM EPA Interlab L10 1314 JaFS
2/28/12 11:55 AM EPA Interlab L10 1314 JaFS
2/28/12 11:56 AM EPA Interlab L10 1314 JaFS
2/28/12 11:58 AM EPA Interlab L10 1314 JaFS
2/28/12 12:00 PM EPA Interlab L10 1314 JaFS
2/28/12 12:01 PM EPA Interlab L10 1314 JaFS
2/28/12 12:03 PM EPA Interlab L10 1314 JaFS
2/28/12 12:05 PM EPA Interlab L10 1314 JaFS
2/28/12 12:06 PM EPA Interlab L10 1314 JaFS
2/28/12 12:13 PM EPA Interlab L10 1314 JaFS
2/28/12 12:15 PM EPA Interlab L10 1314 JaFS
2/28/12 12:16 PM EPA Interlab L10 1314 JaFS
2/28/12 12:18 PM EPA Interlab L10 1314 JaFS
2/28/12 12:19 PM EPA Interlab L10 1314 JaFS
2/28/12 12:21 PM EPA Interlab L10 1314 JaFS
2/28/12 12:23 PM EPA Interlab L10 1314 JaFS
2/28/12 12:24 PM EPA Interlab L10 1314 JaFS
2/28/12 12:26 PM EPA Interlab L10 1314 JaFS
2/28/12 12:28 PM EPA Interlab L10 1314 JaFS
2/28/12 12:29 PM EPA Interlab L10 1314 JaFS
2/28/12 12:31 PM EPA Interlab L10 1314 JaFS
2/28/12 12:33 PM EPA Interlab L10 1314 JaFS
2/28/12 12:34 PM EPA Interlab L10 1314 JaFS
2/28/12 12:36 PM EPA Interlab L10 1314 JaFS
2/28/12 12:38 PM EPA Interlab L10 1314 JaFS
2/28/12 12:39 PM EPA Interlab L10 1314 JaFS
2/28/12 12:41 PM EPA Interlab L10 1314 JaFS
2/28/12 11:52 AM EPA Interlab L10 1314 JaFS
1-119
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1314:
Element Sample ID
Al CFS-L11-1314-T01-A
Al CFS-L11-1314-T02-A
Al CFS-L11-1314-T03-A
Al CFS-L11-1314-T04-A
Al CFS-L11-1314-T05-A
Al CFS-L11-1314-T06-A
Al CFS-L11-1314-T07-A
Al CFS-L11-1314-T08-A
Al CFS-L11-1314-T09-A
Al CFS-L11-1314-T01-B
Al CFS-L11-1314-T02-B
Al CFS-L11-1314-T03-B
Al CFS-L11-1314-T04-B
Al CFS-L11-1314-T05-B
Al CFS-L11-1314-T06-B
Al CFS-L11-1314-T07-B
Al CFS-L11-1314-T08-B
Al CFS-L11-1314-T09-B
Al CFS-L11-1314-T01-C
Al CFS-L11-1314-T02-C
Al CFS-L11-1314-T03-C
Al CFS-L11-1314-T04-C
Al CFS-L11-1314-T05-C
Al CFS-L11-1314-T06-C
Al CFS-L11-1314-T07-C
Al CFS-L11-1314-T08-C
Al CFS-L11-1314-T09-C
Al CFS-L11-1314-B01-A
Dilution Sample
Factor Cone. Qualifier
I ug/L I
1 5.08E+01
1 5.29E+01
1 4.19E+01
1 3.77E+01
1 3.68E+01
1 3.86E+01
1 3.70E+01
1 3.56E+01
1 3.31 E+01
1 5.17E+01
1 5.01 E+01
1 4.32E+01
1 3.86E+01
1 3.66E+01
1 3.71 E+01
1 3.57E+01
1 3.60E+01
1 3.50E+01
1 5.35E+01
1 5.17E+01
1 4.40E+01
1 3.81 E+01
1 3.51 E+01
1 3.59E+01
1 3.64E+01
1 3.43E+01
1 3.45E+01
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.08E+01 3.89 1.00 3.18
5.29E+01 1.26 1.00 3.18
4.19E+01 5.86 1.00 3.18 10000 1000
3.77E+01 1.33 1.00 3.18
3.68E+01 6.38 1.00 3.18
3.86E+01 3.57 1.00 3.18
3.70E+01 6.53 1.00 3.18
3.56E+01 3.79 1.00 3.18
3.31E+01 2.65 1.00 3.18
5.17E+01 2.63 1.00 3.18
5.01E+01 10.83 1.00 3.18
4.32E+01 4.77 1.00 3.18 10000 1000
3.86E+01 5.73 1.00 3.18
3.66E+01 3.48 1.00 3.18
3.71E+01 1.71 1.00 3.18
3.57E+01 7.73 1.00 3.18
3.60E+01 3.72 1.00 3.18
3.50E+01 4.16 1.00 3.18
5.35E+01 4.60 1.00 3.18
5.17E+01 4.35 1.00 3.18
4.40E+01 4.18 1.00 3.18 10000 1000
3.81E+01 7.29 1.00 3.18
3.51E+01 1.35 1.00 3.18
3.59E+01 1.23 1.00 3.18
3.64E+01 3.21 1.00 3.18
3.43E+01 3.04 1.00 3.18
3.45E+01 1.82 1.00 3.18
5.00E-01 7.33 1.00 3.18
Spike Spike
Cone. Recovery Instrument Date/Time Filename
ug/L %
VU ICP-OES 3/6/12 12:03 PM EPA InterlabLH 1314 CFS
VU ICP-OES 3/6/12 12:04 PM EPA InterlabLH 1314 CFS
1.05E+03 101% VU ICP-OES 3/6/12 12:06 PM EPA Interlab L11 1314 CFS
VU ICP-OES 3/6/12 12:08 PM EPA Interlab L11 1314 CFS
VU ICP-OES 3/6/12 12:09 PM EPA Interlab L11 1314 CFS
VU ICP-OES 3/6/12 12:11 PM EPA Interlab L11 1314 CFS
VU ICP-OES 3/6/12 12:12 PM EPA Interlab L11 1314 CFS
VU ICP-OES 3/6/12 12:14 PM EPA Interlab L11 1314 CFS
VU ICP-OES 3/6/12 12:16 PM EPA Interlab L11 1314 CFS
VU ICP-OES 3/6/12 12:22 PM EPA Interlab L11 1314 CFS
VU ICP-OES 3/6/12 12:24 PM EPA Interlab L11 1314 CFS
9.81E+02 94%VUICP-OES 3/6/12 12:26 PM EPA Interlab L11 1314 CFS
VU ICP-OES 3/6/12 12:27 PM EPA Interlab L11 1314 CFS
VU ICP-OES 3/6/12 12:29 PM EPA Interlab L11 1314 CFS
VU ICP-OES 3/6/12 12:31 PM EPA Interlab L11 1314 CFS
VU ICP-OES 3/6/12 12:32 PM EPA Interlab L11 1314 CFS
VU ICP-OES 3/6/12 12:34 PM EPA Interlab L11 1314 CFS
VU ICP-OES 3/6/12 12:35 PM EPA Interlab L11 1314 CFS
VU ICP-OES 3/6/12 12:37 PM EPA Interlab L11 1314 CFS
VU ICP-OES 3/6/12 12:39 PM EPA Interlab L11 1314 CFS
9.83E+02 94%VUICP-OES 3/6/12 12:40 PM EPA Interlab L11 1314 CFS
VU ICP-OES 3/6/12 12:42 PM EPA Interlab L11 1314 CFS
VU ICP-OES 3/6/12 12:44 PM EPA Interlab L11 1314 CFS
VU ICP-OES 3/6/12 12:45 PM EPA Interlab L11 1314 CFS
VU ICP-OES 3/6/12 12:47 PM EPA Interlab L11 1314 CFS
VU ICP-OES 3/6/12 12:49 PM EPA Interlab L11 1314 CFS
VU ICP-OES 3/6/12 12:50 PM EPA Interlab L11 1314 CFS
VU ICP-OES 3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-120
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L
Sb CFS-L11-1314-T01-A 1 7.27E+01
Sb CFS-L11-1314-T02-A 1 4.22E+01
Sb CFS-L11-1314-T03-A 1 3.14E+01
Sb CFS-L11-1314-T04-A 1 2.53E+01
Sb CFS-L11-1314-T05-A 1 2.16E+01 E
Sb CFS-L11-1314-T06-A 1 2.28E+01 E
Sb CFS-L11-1314-T07-A 1 2.26E+01 E
Sb CFS-L11-1314-T08-A 1 2.03E+01 E
Sb CFS-L11-1314-T09-A 1 1.87E+01 E
Sb CFS-L11-1314-T01-B 1 7.63E+01
Sb CFS-L11-1314-T02-B 1 3.71E+01
Sb CFS-L11-1314-T03-B 1 2.91E+01
Sb CFS-L11-1314-T04-B 1 2.45E+01
Sb CFS-L11-1314-T05-B 1 2.26E+01 E
Sb CFS-L11-1314-T06-B 1 2.38E+01 E
Sb CFS-L11-1314-T07-B 1 2.07E+01 E
Sb CFS-L11-1314-T08-B 1 1.89E+01 E
Sb CFS-L11-1314-T09-B 1 1.95E+01 E
Sb CFS-L11-1314-T01-C 1 7.70E+01
Sb CFS-L11-1314-T02-C 1 4.31 E+01
Sb CFS-L11-1314-T03-C 1 2.74E+01
Sb CFS-L11-1314-T04-C 1 2.50E+01
Sb CFS-L11-1314-T05-C 1 2.21E+01 E
Sb CFS-L11-1314-T06-C 1 2.13E+01 E
Sb CFS-L11-1314-T07-C 1 1.99E+01 E
Sb CFS-L11-1314-T08-C 1 1.89E+01 E
Sb CFS-L11-1314-T09-C 1 1.88E+01 E
Sb CFS-L11-1314-B01-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
7.27E+01 4.55 7.50 23.90
4.22E+01 0.94 7.50 23.90
3.14E+01 1.41 7.50 23.90 10000 1000
2.53E+01 6.08 7.50 23.90
2.16E+01 3.08 7.50 23.90
2.28E+01 4.21 7.50 23.90
2.26E+01 4.66 7.50 23.90
2.03E+01 3.71 7.50 23.90
1.87E+01 8.01 7.50 23.90
7.63E+01 8.88 7.50 23.90
3.71E+01 3.17 7.50 23.90
2.91E+01 5.96 7.50 23.90 10000 1000
2.45E+01 7.99 7.50 23.90
2.26E+01 10.44 7.50 23.90
2.38E+01 7.18 7.50 23.90
2.07E+01 6.23 7.50 23.90
1.89E+01 1.70 7.50 23.90
1.95E+01 7.03 7.50 23.90
7.70E+01 3.78 7.50 23.90
4.31 E+01 3.23 7.50 23.90
2.74E+01 9.70 7.50 23.90 10000 1000
2.50E+01 1.74 7.50 23.90
2.21E+01 13.30 7.50 23.90
2.13E+01 5.91 7.50 23.90
1.99E+01 4.27 7.50 23.90
1.89E+01 0.59 7.50 23.90
1.88E+01 0.25 7.50 23.90
3.75E+00 20.34 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.06E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L11 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:26 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:45 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:52 PM EPA Interlab L1 1 1314 CFS
1-121
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
As CFS-L11-1314-T01-A 1 4.24E+01
As CFS-L11-1314-T02-A 1 3.65E+01
As CFS-L11-1314-T03-A 1 2.45E+01 E
As CFS-L11-1314-T04-A 1 2.15E+01 E
As CFS-L11-1314-T05-A 1 1.60E+01 E
As CFS-L11-1314-T06-A 1 1.89E+01 E
As CFS-L11-1314-T07-A 1 1.67E+01 E
As CFS-L11-1314-T08-A 1 1.22E+01 E
As CFS-L11-1314-T09-A 1 1.56E+01 E
As CFS-L11-1314-T01-B 1 4.42E+01
As CFS-L11-1314-T02-B 1 3.50E+01 E
As CFS-L11-1314-T03-B 1 2.50E+01 E
As CFS-L11-1314-T04-B 1 1.90E+01 E
As CFS-L11-1314-T05-B 1 1.54E+01 E
As CFS-L11-1314-T06-B 1 1.88E+01 E
As CFS-L11-1314-T07-B 1 1.99E+01 E
As CFS-L11-1314-T08-B 1 1.32E+01 E
As CFS-L11-1314-T09-B 1 1.34E+01 E
As CFS-L11-1314-T01-C 1 435E+01
As CFS-L11-1314-T02-C 1 342E+01 E
As CFS-L11-1314-T03-C 1 2.32E+01 E
As CFS-L11-1314-T04-C 1 1.98E+01 E
As CFS-L11-1314-T05-C 1 1.67E+01 E
As CFS-L11-1314-T06-C 1 1.62E+01 E
As CFS-L11-1314-T07-C 1 1.55E+01 E
As CFS-L11-1314-T08-C 1 1.29E+01 E
As CFS-L11-1314-T09-C 1 1.58E+01 E
As CFS-L11-1314-B01-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
4.24E+01 0.52 11.00 35.00
3.65E+01 6.05 11.00 35.00
2.45E+01 2.20 11.00 35.00 10000 1000
2.15E+01 1.03 11.00 35.00
1.60E+01 5.81 11.00 35.00
1.89E+01 2.05 11.00 35.00
1.67E+01 1.34 11.00 35.00
1.22E+01 2.72 11.00 35.00
1.56E+01 3.31 11.00 35.00
4.42E+01 4.26 11.00 35.00
3.50E+01 1.67 11.00 35.00
2.50E+01 0.53 11.00 35.00 10000 1000
1.90E+01 2.87 11.00 35.00
1.54E+01 1.27 11.00 35.00
1.88E+01 1.86 11.00 35.00
1.99E+01 3.44 11.00 35.00
1.32E+01 0.76 11.00 35.00
1.34E+01 0.48 11.00 35.00
4.35E+01 1.09 11.00 35.00
3.42E+01 1.91 11.00 35.00
2.32E+01 2.56 11.00 35.00 10000 1000
1.98E+01 0.73 11.00 35.00
1.67E+01 1.93 11.00 35.00
1.62E+01 2.44 11.00 35.00
1.55E+01 2.66 11.00 35.00
1.29E+01 0.38 11.00 35.00
1.58E+01 0.96 11.00 35.00
5.50E+00 8.80 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.14E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:26 PM EPA Interlab L11 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L11 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L11 1314 CFS
3/6/12 12:45 PM EPA Interlab L11 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L11 1314 CFS
3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-122
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
B CFS-L11-1314-T01-A 1 2.21E+03
B CFS-L11-1314-T02-A 1 1.36E+03
B CFS-L11-1314-T03-A 1 5.37E+02
B CFS-L11-1314-T04-A 1 3.25E+02
B CFS-L11-1314-T05-A 1 1.29E+02
B CFS-L11-1314-T06-A 1 1.02E+02
B CFS-L11-1314-T07-A 1 7.84E+01
B CFS-L11-1314-T08-A 1 6.49E+01
B CFS-L11-1314-T09-A 1 4.38E+01
B CFS-L11-1314-T01-B 1 2.29E+03
B CFS-L11-1314-T02-B 1 1.40E+03
B CFS-L11-1314-T03-B 1 5.65E+02
B CFS-L11-1314-T04-B 1 3.05E+02
B CFS-L11-1314-T05-B 1 1.48E+02
B CFS-L11-1314-T06-B 1 1.01E+02
B CFS-L11-1314-T07-B 1 7.71E+01
B CFS-L11-1314-T08-B 1 6.19E+01
B CFS-L11-1314-T09-B 1 4.96E+01
B CFS-L11-1314-T01-C 1 2.16E+03
B CFS-L11-1314-T02-C 1 1.36E+03
B CFS-L11-1314-T03-C 1 5.47E+02
B CFS-L11-1314-T04-C 1 3.11E+02
B CFS-L11-1314-T05-C 1 1.22E+02
B CFS-L11-1314-T06-C 1 9.47E+01
B CFS-L11-1314-T07-C 1 7.56E+01
B CFS-L11-1314-T08-C 1 6.27E+01
B CFS-L11-1314-T09-C 1 4.23E+01
B CFS-L11-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
2.21E+03 0.98 1.00 3.18
1.36E+03 0.88 1.00 3.18
5.37E+02 0.20 1.00 3.18 10000 1000
3.25E+02 0.16 1.00 3.18
1.29E+02 0.77 1.00 3.18
1.02E+02 1.52 1.00 3.18
7.84E+01 1.23 1.00 3.18
6.49E+01 2.49 1.00 3.18
4.38E+01 1.25 1.00 3.18
2.29E+03 0.85 1.00 3.18
1.40E+03 0.98 1.00 3.18
5.65E+02 1.31 1.00 3.18 10000 1000
3.05E+02 0.26 1.00 3.18
1.48E+02 1.76 1.00 3.18
1.01E+02 2.03 1.00 3.18
7.71E+01 2.60 1.00 3.18
6.19E+01 2.94 1.00 3.18
4.96E+01 0.90 1.00 3.18
2.16E+03 0.54 1.00 3.18
1.36E+03 1.28 1.00 3.18
5.47E+02 0.57 1.00 3.18 10000 1000
3.11E+02 1.60 1.00 3.18
1.22E+02 0.98 1.00 3.18
9.47E+01 1.39 1.00 3.18
7.56E+01 2.25 1.00 3.18
6.27E+01 1.03 1.00 3.18
4.23E+01 2.98 1.00 3.18
5.00E-01 1.74 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.47E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .47E+03 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.53E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L11 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:26 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:45 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-123
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Ba CFS-L11-1314-T01-A 1 4.39E+01
Ba CFS-L11-1314-T02-A 1 4.64E+01
Ba CFS-L11-1314-T03-A 1 5.58E+01
Ba CFS-L11-1314-T04-A 1 6.74E+01
Ba CFS-L11-1314-T05-A 1 7.32E+01
Ba CFS-L11-1314-T06-A 1 7.99E+01
Ba CFS-L11-1314-T07-A 1 8.52E+01
Ba CFS-L11-1314-T08-A 1 9.41 E+01
Ba CFS-L11-1314-T09-A 1 9.83E+01
Ba CFS-L11-1314-T01-B 1 4.55E+01
Ba CFS-L11-1314-T02-B 1 4.67E+01
Ba CFS-L11-1314-T03-B 1 5.57E+01
Ba CFS-L11-1314-T04-B 1 6.68E+01
Ba CFS-L11-1314-T05-B 1 7.63E+01
Ba CFS-L11-1314-T06-B 1 7.94E+01
Ba CFS-L11-1314-T07-B 1 8.64E+01
Ba CFS-L11-1314-T08-B 1 9.26E+01
Ba CFS-L11-1314-T09-B 1 9.64E+01
Ba CFS-L11-1314-T01-C 1 4.43E+01
Ba CFS-L11-1314-T02-C 1 5.06E+01
Ba CFS-L11-1314-T03-C 1 5.84E+01
Ba CFS-L11-1314-T04-C 1 6.78E+01
Ba CFS-L11-1314-T05-C 1 7.36E+01
Ba CFS-L11-1314-T06-C 1 7.96E+01
Ba CFS-L11-1314-T07-C 1 8.51 E+01
Ba CFS-L11-1314-T08-C 1 9.45E+01
Ba CFS-L11-1314-T09-C 1 9.75E+01
Ba CFS-L11-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
4.39E+01 1.32 1.00 3.18
4.64E+01 0.84 1.00 3.18
5.58E+01 1.55 1.00 3.18 10000 1000
6.74E+01 1.32 1.00 3.18
7.32E+01 0.60 1.00 3.18
7.99E+01 1.76 1.00 3.18
8.52E+01 0.66 1.00 3.18
9.41E+01 1.13 1.00 3.18
9.83E+01 1.00 1.00 3.18
4.55E+01 3.03 1.00 3.18
4.67E+01 1.32 1.00 3.18
5.57E+01 0.99 1.00 3.18 10000 1000
6.68E+01 0.41 1.00 3.18
7.63E+01 1.49 1.00 3.18
7.94E+01 0.63 1.00 3.18
8.64E+01 1.01 1.00 3.18
9.26E+01 0.57 1.00 3.18
9.64E+01 0.85 1.00 3.18
4.43E+01 1.50 1.00 3.18
5.06E+01 1.11 1.00 3.18
5.84E+01 0.53 1.00 3.18 10000 1000
6.78E+01 0.79 1.00 3.18
7.36E+01 1.30 1.00 3.18
7.96E+01 1.10 1.00 3.18
8.51E+01 1.57 1.00 3.18
9.45E+01 0.34 1.00 3.18
9.75E+01 1.05 1.00 3.18
5.00E-01 3.23 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.05E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L11 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:26 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:45 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-124
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Be CFS-L11-1314-T01-A 1 9.50E-01 U1/2
Be CFS-L11-1314-T02-A 1 9.50E-01 U1/2
Be CFS-L11-1314-T03-A 1 9.50E-01 U1/2
Be CFS-L11-1314-T04-A 1 9.50E-01 U1/2
Be CFS-L11-1314-T05-A 1 9.50E-01 U1/2
Be CFS-L11-1314-T06-A 1 9.50E-01 U1/2
Be CFS-L11-1314-T07-A 1 9.50E-01 U1/2
Be CFS-L11-1314-T08-A 1 9.50E-01 U1/2
Be CFS-L11-1314-T09-A 1 9.50E-01 U1/2
Be CFS-L11-1314-T01-B 1 9.50E-01 U1/2
Be CFS-L11-1314-T02-B 1 9.50E-01 U1/2
Be CFS-L11-1314-T03-B 1 9.50E-01 U1/2
Be CFS-L11-1314-T04-B 1 9.50E-01 U1/2
Be CFS-L11-1314-T05-B 1 9.50E-01 U1/2
Be CFS-L11-1314-T06-B 1 9.50E-01 U1/2
Be CFS-L11-1314-T07-B 1 9.50E-01 U1/2
Be CFS-L11-1314-T08-B 1 9.50E-01 U1/2
Be CFS-L11-1314-T09-B 1 9.50E-01 U1/2
Be CFS-L11-1314-T01-C 1 9.50E-01 U1/2
Be CFS-L11-1314-T02-C 1 9.50E-01 U1/2
Be CFS-L11-1314-T03-C 1 9.50E-01 U1/2
Be CFS-L11-1314-T04-C 1 9.50E-01 U1/2
Be CFS-L11-1314-T05-C 1 9.50E-01 U1/2
Be CFS-L11-1314-T06-C 1 9.50E-01 U1/2
Be CFS-L11-1314-T07-C 1 9.50E-01 U1/2
Be CFS-L11-1314-T08-C 1 9.50E-01 U1/2
Be CFS-L11-1314-T09-C 1 9.50E-01 U1/2
Be CFS-L11-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
9.50E-01 9.99 1.90 6.00
9.50E-01 7.43 1.90 6.00
9.50E-01 7.43 1.90 6.00 10000 1000
9.50E-01 11.81 1.90 6.00
9.50E-01 6.47 1.90 6.00
9.50E-01 8.06 1.90 6.00
9.50E-01 8.39 1.90 6.00
9.50E-01 15.57 1.90 6.00
9.50E-01 1.63 1.90 6.00
9.50E-01 13.16 1.90 6.00
9.50E-01 14.02 1.90 6.00
9.50E-01 8.58 1.90 6.00 10000 1000
9.50E-01 5.51 1.90 6.00
9.50E-01 14.36 1.90 6.00
9.50E-01 4.80 1.90 6.00
9.50E-01 12.88 1.90 6.00
9.50E-01 12.97 1.90 6.00
9.50E-01 11.15 1.90 6.00
9.50E-01 6.18 1.90 6.00
9.50E-01 16.32 1.90 6.00
9.50E-01 1.62 1.90 6.00 10000 1000
9.50E-01 10.55 1.90 6.00
9.50E-01 8.22 1.90 6.00
9.50E-01 10.06 1.90 6.00
9.50E-01 10.11 1.90 6.00
9.50E-01 9.14 1.90 6.00
9.50E-01 14.27 1.90 6.00
9.50E-01 25.33 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.05E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L11 1314 CFS
3/6/12 12:26 PM EPA Interlab L11 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L11 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L11 1314 CFS
3/6/12 12:45 PM EPA Interlab L11 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L11 1314 CFS
3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-125
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Cd CFS-L11-1314-T01-A 1 1.38E+04
Cd CFS-L11-1314-T02-A 1 1.06E+04
Cd CFS-L11-1314-T03-A 1 9.48E+03
Cd CFS-L11-1314-T04-A 1 7.86E+03
Cd CFS-L11-1314-T05-A 1 7.52E+03
Cd CFS-L11-1314-T06-A 1 6.07E+03
Cd CFS-L11-1314-T07-A 1 5.34E+03
Cd CFS-L11-1314-T08-A 1 4.69E+03
Cd CFS-L11-1314-T09-A 1 4.04E+03
Cd CFS-L11-1314-T01-B 1 1.36E+04
Cd CFS-L11-1314-T02-B 1 9.81 E+03
Cd CFS-L11-1314-T03-B 1 8.91 E+03
Cd CFS-L11-1314-T04-B 1 8.12E+03
Cd CFS-L11-1314-T05-B 1 7.57E+03
Cd CFS-L11-1314-T06-B 1 6.42E+03
Cd CFS-L11-1314-T07-B 1 5.78E+03
Cd CFS-L11-1314-T08-B 1 4.88E+03
Cd CFS-L11-1314-T09-B 1 3.74E+03
Cd CFS-L11-1314-T01-C 1 1.32E+04
Cd CFS-L11-1314-T02-C 1 1.05E+04
Cd CFS-L11-1314-T03-C 1 9.02E+03
Cd CFS-L11-1314-T04-C 1 7.96E+03
Cd CFS-L11-1314-T05-C 1 7.48E+03
Cd CFS-L11-1314-T06-C 1 6.05E+03
Cd CFS-L11-1314-T07-C 1 5.87E+03
Cd CFS-L11-1314-T08-C 1 4.94E+03
Cd CFS-L11-1314-T09-C 1 4.03E+03
Cd CFS-L11-1314-B01-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
1.38E+04 1.79 2.20 7.00
1.06E+04 1.05 2.20 7.00
9.48E+03 0.54 2.20 7.00 10000 1000
7.86E+03 0.66 2.20 7.00
7.52E+03 0.40 2.20 7.00
6.07E+03 1.07 2.20 7.00
5.34E+03 0.83 2.20 7.00
4.69E+03 0.30 2.20 7.00
4.04E+03 0.51 2.20 7.00
1.36E+04 0.47 2.20 7.00
9.81 E+03 1.01 2.20 7.00
8.91E+03 0.94 2.20 7.00 10000 1000
8.12E+03 0.26 2.20 7.00
7.57E+03 1.27 2.20 7.00
6.42E+03 0.40 2.20 7.00
5.78E+03 0.68 2.20 7.00
4.88E+03 0.51 2.20 7.00
3.74E+03 0.18 2.20 7.00
1.32E+04 0.08 2.20 7.00
1.05E+04 1.61 2.20 7.00
9.02E+03 0.79 2.20 7.00 10000 1000
7.96E+03 1.00 2.20 7.00
7.48E+03 1.01 2.20 7.00
6.05E+03 0.78 2.20 7.00
5.87E+03 1.37 2.20 7.00
4.94E+03 0.14 2.20 7.00
4.03E+03 1.29 2.20 7.00
1.10E+00 6.29 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.91E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.97E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L11 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:26 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:45 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-126
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Ca CFS-L11-1314-T01-A 1 4.43E+05
Ca CFS-L11-1314-T02-A 1 5.07E+05
Ca CFS-L11-1314-T03-A 1 5.61 E+05
Ca CFS-L11-1314-T04-A 1 5.86E+05
Ca CFS-L11-1314-T05-A 1 5.98E+05
Ca CFS-L11-1314-T06-A 1 6.01 E+05
Ca CFS-L11-1314-T07-A 1 6.12E+05
Ca CFS-L11-1314-T08-A 1 6.03E+05
Ca CFS-L11-1314-T09-A 1 6.10E+05
Ca CFS-L11-1314-T01-B 1 4.38E+05
Ca CFS-L11-1314-T02-B 1 5.08E+05
Ca CFS-L11-1314-T03-B 1 5.67E+05
Ca CFS-L11-1314-T04-B 1 5.89E+05
Ca CFS-L11-1314-T05-B 1 5.99E+05
Ca CFS-L11-1314-T06-B 1 6.05E+05
Ca CFS-L11-1314-T07-B 1 6. 11 E+05
Ca CFS-L11-1314-T08-B 1 6.02E+05
Ca CFS-L11-1314-T09-B 1 6.13E+05
Ca CFS-L11-1314-T01-C 1 4.40E+05
Ca CFS-L11-1314-T02-C 1 5.03E+05
Ca CFS-L11-1314-T03-C 1 5.66E+05
Ca CFS-L11-1314-T04-C 1 5.90E+05
Ca CFS-L11-1314-T05-C 1 5.96E+05
Ca CFS-L11-1314-T06-C 1 6.06E+05
Ca CFS-L11-1314-T07-C 1 6.08E+05
Ca CFS-L11-1314-T08-C 1 6.04E+05
Ca CFS-L11-1314-T09-C 1 6.14E+05
Ca CFS-L11-1314-B01-A 1 1.30E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
4.43E+05 0.80 2.60 8.30
5.07E+05 0.99 2.60 8.30
5.61E+05 0.57 2.60 8.30 10000 1000
5.86E+05 0.45 2.60 8.30
5.98E+05 0.65 2.60 8.30
6.01 E+05 0.99 2.60 8.30
6.12E+05 0.51 2.60 8.30
6.03E+05 0.27 2.60 8.30
6.10E+05 0.51 2.60 8.30
4.38E+05 0.67 2.60 8.30
5.08E+05 0.97 2.60 8.30
5.67E+05 0.70 2.60 8.30 10000 1000
5.89E+05 0.11 2.60 8.30
5.99E+05 0.72 2.60 8.30
6.05E+05 0.45 2.60 8.30
6. 11 E+05 0.41 2.60 8.30
6.02E+05 0.40 2.60 8.30
6.13E+05 0.35 2.60 8.30
4.40E+05 0.31 2.60 8.30
5.03E+05 0.67 2.60 8.30
5.66E+05 0.56 2.60 8.30 10000 1000
5.90E+05 0.81 2.60 8.30
5.96E+05 0.55 2.60 8.30
6.06E+05 0.70 2.60 8.30
6.08E+05 1.17 2.60 8.30
6.04E+05 0.12 2.60 8.30
6.14E+05 0.60 2.60 8.30
1.30E+00 1.15 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.62E+05 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.68E+05 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.67E+05 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L11 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:26 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:45 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-127
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Cr CFS-L11-1314-T01-A 1 6.00E-01 U1/2
Cr CFS-L11-1314-T02-A 1 6.00E-01 U1/2
Cr CFS-L11-1314-T03-A 1 6.00E-01 U1/2
Cr CFS-L11-1314-T04-A 1 6.00E-01 U1/2
Cr CFS-L11-1314-T05-A 1 6.00E-01 U1/2
Cr CFS-L11-1314-T06-A 1 6.00E-01 U1/2
Cr CFS-L11-1314-T07-A 1 6.00E-01 U1/2
Cr CFS-L11-1314-T08-A 1 6.00E-01 U1/2
Cr CFS-L11-1314-T09-A 1 6.00E-01 U1/2
Cr CFS-L11-1314-T01-B 1 6.00E-01 U1/2
Cr CFS-L11-1314-T02-B 1 6.00E-01 U1/2
Cr CFS-L11-1314-T03-B 1 6.00E-01 U1/2
Cr CFS-L11-1314-T04-B 1 6.00E-01 U1/2
Cr CFS-L11-1314-T05-B 1 6.00E-01 U1/2
Cr CFS-L11-1314-T06-B 1 6.00E-01 U1/2
Cr CFS-L11-1314-T07-B 1 6.00E-01 U1/2
Cr CFS-L11-1314-T08-B 1 6.00E-01 U1/2
Cr CFS-L11-1314-T09-B 1 6.00E-01 U1/2
Cr CFS-L11-1314-T01-C 1 6.00E-01 U1/2
Cr CFS-L11-1314-T02-C 1 6.00E-01 U1/2
Cr CFS-L11-1314-T03-C 1 6.00E-01 U1/2
Cr CFS-L11-1314-T04-C 1 6.00E-01 U1/2
Cr CFS-L11-1314-T05-C 1 6.00E-01 U1/2
Cr CFS-L11-1314-T06-C 1 6.00E-01 U1/2
Cr CFS-L11-1314-T07-C 1 6.00E-01 U1/2
Cr CFS-L11-1314-T08-C 1 6.00E-01 U1/2
Cr CFS-L11-1314-T09-C 1 6.00E-01 U1/2
Cr CFS-L11-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
6.00E-01 7.59 1.20 3.82
6.00E-01 13.45 1.20 3.82
6.00E-01 7.36 1.20 3.82 10000 1000
6.00E-01 18.96 1.20 3.82
6.00E-01 10.26 1.20 3.82
6.00E-01 2.85 1.20 3.82
6.00E-01 20.43 1.20 3.82
6.00E-01 7.59 1.20 3.82
6.00E-01 24.63 1.20 3.82
6.00E-01 6.25 1.20 3.82
6.00E-01 12.26 1.20 3.82
6.00E-01 22.66 1.20 3.82 10000 1000
6.00E-01 10.53 1.20 3.82
6.00E-01 7.60 1.20 3.82
6.00E-01 4.98 1.20 3.82
6.00E-01 12.67 1.20 3.82
6.00E-01 28.80 1.20 3.82
6.00E-01 28.82 1.20 3.82
6.00E-01 16.44 1.20 3.82
6.00E-01 11.92 1.20 3.82
6.00E-01 8.32 1.20 3.82 10000 1000
6.00E-01 34.61 1.20 3.82
6.00E-01 16.85 1.20 3.82
6.00E-01 10.96 1.20 3.82
6.00E-01 17.29 1.20 3.82
6.00E-01 5.74 1.20 3.82
6.00E-01 14.19 1.20 3.82
6.00E-01 23.14 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.03E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:26 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/1212:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:39 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:45 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:52 PM EPA Interlab L1 1 1314 CFS
1-128
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Co CFS-L11-1314-T01-A 1 7.35E+02
Co CFS-L11-1314-T02-A 1 3.25E+02
Co CFS-L11-1314-T03-A 1 2.64E+02
Co CFS-L11-1314-T04-A 1 2.24E+02
Co CFS-L11-1314-T05-A 1 1.97E+02
Co CFS-L11-1314-T06-A 1 1.35E+02
Co CFS-L11-1314-T07-A 1 1.04E+02
Co CFS-L11-1314-T08-A 1 6.49E+01
Co CFS-L11-1314-T09-A 1 4.98E+01
Co CFS-L11-1314-T01-B 1 7.18E+02
Co CFS-L11-1314-T02-B 1 3.31 E+02
Co CFS-L11-1314-T03-B 1 2.54E+02
Co CFS-L11-1314-T04-B 1 2.28E+02
Co CFS-L11-1314-T05-B 1 1.85E+02
Co CFS-L11-1314-T06-B 1 1.32E+02
Co CFS-L11-1314-T07-B 1 1.03E+02
Co CFS-L11-1314-T08-B 1 5.84E+01
Co CFS-L11-1314-T09-B 1 4.16E+01
Co CFS-L11-1314-T01-C 1 7.25E+02
Co CFS-L11-1314-T02-C 1 3.40E+02
Co CFS-L11-1314-T03-C 1 2.62E+02
Co CFS-L11-1314-T04-C 1 2.20E+02
Co CFS-L11-1314-T05-C 1 1.85E+02
Co CFS-L11-1314-T06-C 1 1.29E+02
Co CFS-L11-1314-T07-C 1 1.19E+02
Co CFS-L11-1314-T08-C 1 6.59E+01
Co CFS-L11-1314-T09-C 1 4.43E+01
Co CFS-L11-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
7.35E+02 0.49 1.80 5.72
3.25E+02 1.07 1.80 5.72
2.64E+02 0.89 1.80 5.72 10000 1000
2.24E+02 0.57 1.80 5.72
1.97E+02 0.79 1.80 5.72
1.35E+02 1.27 1.80 5.72
1.04E+02 1.68 1.80 5.72
6.49E+01 1.59 1.80 5.72
4.98E+01 2.43 1.80 5.72
7.18E+02 1.47 1.80 5.72
3.31 E+02 1.34 1.80 5.72
2.54E+02 0.85 1.80 5.72 10000 1000
2.28E+02 0.89 1.80 5.72
1.85E+02 0.55 1.80 5.72
1.32E+02 0.82 1.80 5.72
1.03E+02 1.23 1.80 5.72
5.84E+01 1.13 1.80 5.72
4.16E+01 2.04 1.80 5.72
7.25E+02 0.24 1.80 5.72
3.40E+02 1.02 1.80 5.72
2.62E+02 0.52 1.80 5.72 10000 1000
2.20E+02 1.44 1.80 5.72
1.85E+02 0.19 1.80 5.72
1.29E+02 1.00 1.80 5.72
1.19E+02 1.66 1.80 5.72
6.59E+01 1.69 1.80 5.72
4.43E+01 0.92 1.80 5.72
9.00E-01 3.92 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.28E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.31E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.25E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L11 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:26 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:45 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-129
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Cu CFS-L11-1314-T01-A 1 2.26E+03
Cu CFS-L11-1314-T02-A 1 1.82E+03
Cu CFS-L11-1314-T03-A 1 1.40E+03
Cu CFS-L11-1314-T04-A 1 1.44E+03
Cu CFS-L11-1314-T05-A 1 1.51E+03
Cu CFS-L11-1314-T06-A 1 1.10E+03
Cu CFS-L11-1314-T07-A 1 9.97E+02
Cu CFS-L11-1314-T08-A 1 9.35E+02
Cu CFS-L11-1314-T09-A 1 8.92E+02
Cu CFS-L11-1314-T01-B 1 2.30E+03
Cu CFS-L11-1314-T02-B 1 1.92E+03
Cu CFS-L11-1314-T03-B 1 1.43E+03
Cu CFS-L11-1314-T04-B 1 1.49E+03
Cu CFS-L11-1314-T05-B 1 1.54E+03
Cu CFS-L11-1314-T06-B 1 1.13E+03
Cu CFS-L11-1314-T07-B 1 1.02E+03
Cu CFS-L11-1314-T08-B 1 9.57E+02
Cu CFS-L11-1314-T09-B 1 9.14E+02
Cu CFS-L11-1314-T01-C 1 2.18E+03
Cu CFS-L11-1314-T02-C 1 1.85E+03
Cu CFS-L11-1314-T03-C 1 1.47E+03
Cu CFS-L11-1314-T04-C 1 1.50E+03
Cu CFS-L11-1314-T05-C 1 1.51E+03
Cu CFS-L11-1314-T06-C 1 1.02E+03
Cu CFS-L11-1314-T07-C 1 9.73E+02
Cu CFS-L11-1314-T08-C 1 9.27E+02
Cu CFS-L11-1314-T09-C 1 8.73E+02
Cu CFS-L11-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
2.26E+03 2.04 3.70 11.80
1.82E+03 0.74 3.70 11.80
1.40E+03 0.49 3.70 11.80 10000 1000
1.44E+03 0.75 3.70 11.80
1.51E+03 0.52 3.70 11.80
1.10E+03 1.12 3.70 11.80
9.97E+02 0.06 3.70 11.80
9.35E+02 0.15 3.70 11.80
8.92E+02 0.52 3.70 11.80
2.30E+03 1.06 3.70 11.80
1.92E+03 3.55 3.70 11.80
1.43E+03 2.14 3.70 11.80 10000 1000
1.49E+03 0.51 3.70 11.80
1.54E+03 0.74 3.70 11.80
1.13E+03 0.27 3.70 11.80
1.02E+03 0.52 3.70 11.80
9.57E+02 0.66 3.70 11.80
9.14E+02 0.51 3.70 11.80
2.18E+03 0.69 3.70 11.80
1.85E+03 3.45 3.70 11.80
1.47E+03 1.06 3.70 11.80 10000 1000
1.50E+03 0.96 3.70 11.80
1.51E+03 1.13 3.70 11.80
1.02E+03 0.17 3.70 11.80
9.73E+02 1.17 3.70 11.80
9.27E+02 0.36 3.70 11.80
8.73E+02 0.96 3.70 11.80
1.85E+00 3.48 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.46E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.42E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.50E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L11 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:26 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:45 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-130
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Fe CFS-L11-1314-T01-A 1 1.00E+00 U1/2
Fe CFS-L11-1314-T02-A 1 1.00E+00 U1/2
Fe CFS-L11-1314-T03-A 1 1.00E+00 U1/2
Fe CFS-L11-1314-T04-A 1 1.00E+00 U1/2
Fe CFS-L11-1314-T05-A 1 1.00E+00 U1/2
Fe CFS-L11-1314-T06-A 1 1.00E+00 U1/2
Fe CFS-L11-1314-T07-A 1 1.00E+00 U1/2
Fe CFS-L11-1314-T08-A 1 1.00E+00 U1/2
Fe CFS-L11-1314-T09-A 1 1.00E+00 U1/2
Fe CFS-L11-1314-T01-B 1 1.00E+00 U1/2
Fe CFS-L11-1314-T02-B 1 1.00E+00 U1/2
Fe CFS-L11-1314-T03-B 1 1.00E+00 U1/2
Fe CFS-L11-1314-T04-B 1 1.00E+00 U1/2
Fe CFS-L11-1314-T05-B 1 1.00E+00 U1/2
Fe CFS-L11-1314-T06-B 1 1.00E+00 U1/2
Fe CFS-L11-1314-T07-B 1 1.00E+00 U1/2
Fe CFS-L11-1314-T08-B 1 1.00E+00 U1/2
Fe CFS-L11-1314-T09-B 1 1.00E+00 U1/2
Fe CFS-L11-1314-T01-C 1 1.00E+00 U1/2
Fe CFS-L11-1314-T02-C 1 1.00E+00 U1/2
Fe CFS-L11-1314-T03-C 1 1.00E+00 U1/2
Fe CFS-L11-1314-T04-C 1 1.00E+00 U1/2
Fe CFS-L11-1314-T05-C 1 1.00E+00 U1/2
Fe CFS-L11-1314-T06-C 1 1.00E+00 U1/2
Fe CFS-L11-1314-T07-C 1 1.00E+00 U1/2
Fe CFS-L11-1314-T08-C 1 1.00E+00 U1/2
Fe CFS-L11-1314-T09-C 1 1.00E+00 U1/2
Fe CFS-L11-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
1.00E+00 16.35 2.00 6.40
1.00E+00 0.23 2.00 6.40
1.00E+00 5.51 2.00 6.40 10000 1000
1.00E+00 6.33 2.00 6.40
1.00E+00 11.81 2.00 6.40
1.00E+00 0.77 2.00 6.40
1.00E+00 3.47 2.00 6.40
1.00E+00 5.70 2.00 6.40
1.00E+00 1.49 2.00 6.40
1.00E+00 8.55 2.00 6.40
1.00E+00 9.37 2.00 6.40
1.00E+00 5.69 2.00 6.40 10000 1000
1.00E+00 6.13 2.00 6.40
1.00E+00 9.90 2.00 6.40
1.00E+00 3.98 2.00 6.40
1.00E+00 3.03 2.00 6.40
1.00E+00 2.30 2.00 6.40
1.00E+00 4.11 2.00 6.40
1.00E+00 2.82 2.00 6.40
1.00E+00 7.51 2.00 6.40
1.00E+00 10.03 2.00 6.40 10000 1000
1.00E+00 8.49 2.00 6.40
1.00E+00 3.27 2.00 6.40
1.00E+00 6.80 2.00 6.40
1.00E+00 5.33 2.00 6.40
1.00E+00 9.09 2.00 6.40
1.00E+00 6.08 2.00 6.40
1.00E+00 11.03 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L11 1314 CFS
3/6/12 12:26 PM EPA Interlab L11 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L11 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L11 1314 CFS
3/6/12 12:45 PM EPA Interlab L11 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L11 1314 CFS
3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-131
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Pb CFS-L11-1314-T01-A 1 6.05E+02
Pb CFS-L11-1314-T02-A 1 6.43E+02
Pb CFS-L11-1314-T03-A 1 7.46E+02
Pb CFS-L11-1314-T04-A 1 8.44E+02
Pb CFS-L11-1314-T05-A 1 8.99E+02
Pb CFS-L11-1314-T06-A 1 8.22E+02
Pb CFS-L11-1314-T07-A 1 8.32E+02
Pb CFS-L11-1314-T08-A 1 8.19E+02
Pb CFS-L11-1314-T09-A 1 7.64E+02
Pb CFS-L11-1314-T01-B 1 6.12E+02
Pb CFS-L11-1314-T02-B 1 6.43E+02
Pb CFS-L11-1314-T03-B 1 7.87E+02
Pb CFS-L11-1314-T04-B 1 8.94E+02
Pb CFS-L11-1314-T05-B 1 9.40E+02
Pb CFS-L11-1314-T06-B 1 8.00E+02
Pb CFS-L11-1314-T07-B 1 8.08E+02
Pb CFS-L11-1314-T08-B 1 8.47E+02
Pb CFS-L11-1314-T09-B 1 7.56E+02
Pb CFS-L11-1314-T01-C 1 6.17E+02
Pb CFS-L11-1314-T02-C 1 6.61 E+02
Pb CFS-L11-1314-T03-C 1 7.64E+02
Pb CFS-L11-1314-T04-C 1 8.46E+02
Pb CFS-L11-1314-T05-C 1 8.89E+02
Pb CFS-L11-1314-T06-C 1 8.10E+02
Pb CFS-L11-1314-T07-C 1 8.39E+02
Pb CFS-L11-1314-T08-C 1 8.12E+02
Pb CFS-L11-1314-T09-C 1 7.55E+02
Pb CFS-L11-1314-B01-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
6.05E+02 2.06 6.80 21.60
6.43E+02 0.49 6.80 21.60
7.46E+02 1.15 6.80 21.60 10000 1000
8.44E+02 0.25 6.80 21.60
8.99E+02 0.32 6.80 21.60
8.22E+02 1.68 6.80 21.60
8.32E+02 0.29 6.80 21.60
8.19E+02 0.56 6.80 21.60
7.64E+02 1.12 6.80 21.60
6.12E+02 3.42 6.80 21.60
6.43E+02 5.43 6.80 21.60
7.87E+02 1.54 6.80 21.60 10000 1000
8.94E+02 0.45 6.80 21.60
9.40E+02 0.80 6.80 21.60
8.00E+02 0.67 6.80 21.60
8.08E+02 1.52 6.80 21.60
8.47E+02 0.57 6.80 21.60
7.56E+02 0.42 6.80 21.60
6.17E+02 1.65 6.80 21.60
6.61 E+02 6.94 6.80 21.60
7.64E+02 1.92 6.80 21.60 10000 1000
8.46E+02 1.04 6.80 21.60
8.89E+02 1.38 6.80 21.60
8.10E+02 1.49 6.80 21.60
8.39E+02 1.05 6.80 21.60
8.12E+02 0.88 6.80 21.60
7.55E+02 0.87 6.80 21.60
3.40E+00 7.11 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.83E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.86E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.90E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L11 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:26 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:45 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-132
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Li CFS-L11-1314-T01-A 1 3.18E+01
Li CFS-L11-1314-T02-A 1 1.39E+01
Li CFS-L11-1314-T03-A 1 1.26E+01
Li CFS-L11-1314-T04-A 1 1.19E+01
Li CFS-L11-1314-T05-A 1 1.30E+01
Li CFS-L11-1314-T06-A 1 1.11E+01
Li CFS-L11-1314-T07-A 1 1.34E+01
Li CFS-L11-1314-T08-A 1 1.10E+01
Li CFS-L11-1314-T09-A 1 1.10E+01
Li CFS-L11-1314-T01-B 1 3.50E+01
Li CFS-L11-1314-T02-B 1 1.36E+01
Li CFS-L11-1314-T03-B 1 1.11E+01
Li CFS-L11-1314-T04-B 1 1.29E+01
Li CFS-L11-1314-T05-B 1 1.16E+01
Li CFS-L11-1314-T06-B 1 1.20E+01
Li CFS-L11-1314-T07-B 1 1.30E+01
Li CFS-L11-1314-T08-B 1 1.13E+01
Li CFS-L11-1314-T09-B 1 1.21E+01
Li CFS-L11-1314-T01-C 1 3.29E+01
Li CFS-L11-1314-T02-C 1 1.31E+01
Li CFS-L11-1314-T03-C 1 1.34E+01
Li CFS-L11-1314-T04-C 1 1.22E+01
Li CFS-L11-1314-T05-C 1 1.11E+01
Li CFS-L11-1314-T06-C 1 1.24E+01
Li CFS-L11-1314-T07-C 1 1.26E+01
Li CFS-L11-1314-T08-C 1 1.21E+01
Li CFS-L11-1314-T09-C 1 1.10E+01
Li CFS-L11-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
3.18E+01 1.70 1.90 6.00
1.39E+01 1.14 1.90 6.00
1.26E+01 9.02 1.90 6.00 10000 1000
1.19E+01 2.80 1.90 6.00
1.30E+01 7.94 1.90 6.00
1.11E+01 5.52 1.90 6.00
1.34E+01 4.80 1.90 6.00
1.10E+01 5.74 1.90 6.00
1.10E+01 4.36 1.90 6.00
3.50E+01 13.55 1.90 6.00
1.36E+01 7.82 1.90 6.00
1.11E+01 1.85 1.90 6.00 10000 1000
1.29E+01 6.80 1.90 6.00
1.16E+01 2.84 1.90 6.00
1.20E+01 3.72 1.90 6.00
1.30E+01 2.16 1.90 6.00
1.13E+01 3.65 1.90 6.00
1.21E+01 10.12 1.90 6.00
3.29E+01 5.54 1.90 6.00
1.31E+01 3.53 1.90 6.00
1.34E+01 7.60 1.90 6.00 10000 1000
1.22E+01 1.49 1.90 6.00
1.11E+01 3.08 1.90 6.00
1.24E+01 0.53 1.90 6.00
1.26E+01 4.95 1.90 6.00
1.21E+01 3.77 1.90 6.00
1.10E+01 1.67 1.90 6.00
9.50E-01 14.21 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.77E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.72E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.67E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L11 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:26 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:45 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-133
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Mn CFS-L11-1314-T01-A 1 1.75E+04
Mn CFS-L11-1314-T02-A 1 8.85E+03
Mn CFS-L11-1314-T03-A 1 6.16E+03
Mn CFS-L11-1314-T04-A 1 3.76E+03
Mn CFS-L11-1314-T05-A 1 2.41E+03
Mn CFS-L11-1314-T06-A 1 1.24E+03
Mn CFS-L11-1314-T07-A 1 7.06E+02
Mn CFS-L11-1314-T08-A 1 5.39E+02
Mn CFS-L11-1314-T09-A 1 4.67E+02
Mn CFS-L11-1314-T01-B 1 1.92E+04
Mn CFS-L11-1314-T02-B 1 8.61E+03
Mn CFS-L11-1314-T03-B 1 6.54E+03
Mn CFS-L11-1314-T04-B 1 3.76E+03
Mn CFS-L11-1314-T05-B 1 2.57E+03
Mn CFS-L11-1314-T06-B 1 1.17E+03
Mn CFS-L11-1314-T07-B 1 7.01E+02
Mn CFS-L11-1314-T08-B 1 5.36E+02
Mn CFS-L11-1314-T09-B 1 4.95E+02
Mn CFS-L11-1314-T01-C 1 1.78E+04
Mn CFS-L11-1314-T02-C 1 9.14E+03
Mn CFS-L11-1314-T03-C 1 5.87E+03
Mn CFS-L11-1314-T04-C 1 3.32E+03
Mn CFS-L11-1314-T05-C 1 2.53E+03
Mn CFS-L11-1314-T06-C 1 1.26E+03
Mn CFS-L11-1314-T07-C 1 6.56E+02
Mn CFS-L11-1314-T08-C 1 4.96E+02
Mn CFS-L11-1314-T09-C 1 4.32E+02
Mn CFS-L11-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
1.75E+04 1.20 2.00 6.40
8.85E+03 0.18 2.00 6.40
6.16E+03 0.92 2.00 6.40 10000 1000
3.76E+03 0.64 2.00 6.40
2.41E+03 1.18 2.00 6.40
1.24E+03 0.75 2.00 6.40
7.06E+02 0.96 2.00 6.40
5.39E+02 0.51 2.00 6.40
4.67E+02 0.46 2.00 6.40
1.92E+04 0.44 2.00 6.40
8.61 E+03 0.71 2.00 6.40
6.54E+03 0.78 2.00 6.40 10000 1000
3.76E+03 0.28 2.00 6.40
2.57E+03 1.64 2.00 6.40
1.17E+03 1.29 2.00 6.40
7.01E+02 1.26 2.00 6.40
5.36E+02 0.31 2.00 6.40
4.95E+02 2.34 2.00 6.40
1.78E+04 0.30 2.00 6.40
9.14E+03 0.63 2.00 6.40
5.87E+03 1.46 2.00 6.40 10000 1000
3.32E+03 1.78 2.00 6.40
2.53E+03 1.67 2.00 6.40
1.26E+03 1.54 2.00 6.40
6.56E+02 0.76 2.00 6.40
4.96E+02 1.95 2.00 6.40
4.32E+02 0.66 2.00 6.40
1.00E+00 4.32 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
7.10E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.54E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.80E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L11 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:26 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:45 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-134
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Mg CFS-L11-1314-T01-A 1 2.09E+06
Mg CFS-L11-1314-T02-A 1 7.42E+05
Mg CFS-L11-1314-T03-A 1 1.54E+05
Mg CFS-L11-1314-T04-A 1 4.11E+04
Mg CFS-L11-1314-T05-A 1 2.66E+04
Mg CFS-L11-1314-T06-A 1 1.72E+04
Mg CFS-L11-1314-T07-A 1 1.20E+04
Mg CFS-L11-1314-T08-A 1 1.00E+04
Mg CFS-L11-1314-T09-A 1 8.14E+03
Mg CFS-L11-1314-T01-B 1 2.02E+06
Mg CFS-L11-1314-T02-B 1 6.82E+05
Mg CFS-L11-1314-T03-B 1 1.45E+05
Mg CFS-L11-1314-T04-B 1 4.15E+04
Mg CFS-L11-1314-T05-B 1 2.54E+04
Mg CFS-L11-1314-T06-B 1 1.66E+04
Mg CFS-L11-1314-T07-B 1 1.19E+04
Mg CFS-L11-1314-T08-B 1 1.01E+04
Mg CFS-L11-1314-T09-B 1 8.95E+03
Mg CFS-L11-1314-T01-C 1 2.02E+06
Mg CFS-L11-1314-T02-C 1 7.37E+05
Mg CFS-L11-1314-T03-C 1 1.43E+05
Mg CFS-L11-1314-T04-C 1 4.24E+04
Mg CFS-L11-1314-T05-C 1 2.62E+04
Mg CFS-L11-1314-T06-C 1 1.62E+04
Mg CFS-L11-1314-T07-C 1 1.17E+04
Mg CFS-L11-1314-T08-C 1 1.01E+04
Mg CFS-L11-1314-T09-C 1 8.48E+03
Mg CFS-L11-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
2.09E+06 1.05 1.00 3.18
7.42E+05 0.95 1.00 3.18
1.54E+05 0.52 1.00 3.18 10000 1000
4.11E+04 0.58 1.00 3.18
2.66E+04 1.09 1.00 3.18
1.72E+04 0.30 1.00 3.18
1.20E+04 1.16 1.00 3.18
1.00E+04 0.98 1.00 3.18
8.14E+03 1.22 1.00 3.18
2.02E+06 0.84 1.00 3.18
6.82E+05 0.80 1.00 3.18
1.45E+05 0.57 1.00 3.18 10000 1000
4.15E+04 0.76 1.00 3.18
2.54E+04 0.51 1.00 3.18
1.66E+04 1.51 1.00 3.18
1.19E+04 0.81 1.00 3.18
1.01E+04 0.44 1.00 3.18
8.95E+03 0.75 1.00 3.18
2.02E+06 0.78 1.00 3.18
7.37E+05 1.29 1.00 3.18
1.43E+05 0.84 1.00 3.18 10000 1000
4.24E+04 1.71 1.00 3.18
2.62E+04 0.07 1.00 3.18
1.62E+04 2.25 1.00 3.18
1.17E+04 0.44 1.00 3.18
1.01E+04 0.43 1.00 3.18
8.48E+03 1.75 1.00 3.18
5.00E-01 1.54 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.55E+05 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.46E+05 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.44E+05 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L11 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:26 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:45 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-135
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Mo CFS-L11-1314-T01-A 1 3.18E+01
Mo CFS-L11-1314-T02-A 1 1.46E+01
Mo CFS-L11-1314-T03-A 1 1.03E+01
Mo CFS-L11-1314-T04-A 1 9.56E+00
Mo CFS-L11-1314-T05-A 1 7.94E+00
Mo CFS-L11-1314-T06-A 1 7.93E+00
Mo CFS-L11-1314-T07-A 1 8.10E+00
Mo CFS-L11-1314-T08-A 1 8.37E+00
Mo CFS-L11-1314-T09-A 1 8.36E+00
Mo CFS-L11-1314-T01-B 1 3.19E+01
Mo CFS-L11-1314-T02-B 1 1.31E+01
Mo CFS-L11-1314-T03-B 1 9.67E+00
Mo CFS-L11-1314-T04-B 1 7.74E+00
Mo CFS-L11-1314-T05-B 1 7.09E+00
Mo CFS-L11-1314-T06-B 1 7.90E+00
Mo CFS-L11-1314-T07-B 1 8.55E+00
Mo CFS-L11-1314-T08-B 1 8.38E+00
Mo CFS-L11-1314-T09-B 1 8.23E+00
Mo CFS-L11-1314-T01-C 1 3.36E+01
Mo CFS-L11-1314-T02-C 1 1.33E+01
Mo CFS-L11-1314-T03-C 1 1.07E+01
Mo CFS-L11-1314-T04-C 1 8.70E+00
Mo CFS-L11-1314-T05-C 1 8.00E+00
Mo CFS-L11-1314-T06-C 1 8.08E+00
Mo CFS-L11-1314-T07-C 1 8.34E+00
Mo CFS-L11-1314-T08-C 1 8.38E+00
Mo CFS-L11-1314-T09-C 1 7.81E+00
Mo CFS-L11-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
3.18E+01 5.11 1.20 3.82
1.46E+01 1.05 1.20 3.82
1.03E+01 1.00 1.20 3.82 10000 1000
9.56E+00 6.29 1.20 3.82
7.94E+00 3.18 1.20 3.82
7.93E+00 6.10 1.20 3.82
8.10E+00 3.13 1.20 3.82
8.37E+00 1.44 1.20 3.82
8.36E+00 10.69 1.20 3.82
3.19E+01 2.63 1.20 3.82
1.31E+01 1.17 1.20 3.82
9.67E+00 3.09 1.20 3.82 10000 1000
7.74E+00 2.41 1.20 3.82
7.09E+00 4.09 1.20 3.82
7.90E+00 7.89 1.20 3.82
8.55E+00 3.16 1.20 3.82
8.38E+00 4.38 1.20 3.82
8.23E+00 5.10 1.20 3.82
3.36E+01 3.74 1.20 3.82
1.33E+01 3.15 1.20 3.82
1.07E+01 4.99 1.20 3.82 10000 1000
8.70E+00 9.55 1.20 3.82
8.00E+00 2.82 1.20 3.82
8.08E+00 2.76 1.20 3.82
8.34E+00 6.17 1.20 3.82
8.38E+00 7.29 1.20 3.82
7.81E+00 5.70 1.20 3.82
6.00E-01 5.11 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L11 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:26 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:45 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-136
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Ni CFS-L11-1314-T01-A 1 1.03E+03
Ni CFS-L11-1314-T02-A 1 4.61E+02
Ni CFS-L11-1314-T03-A 1 3.79E+02
Ni CFS-L11-1314-T04-A 1 3.66E+02
Ni CFS-L11-1314-T05-A 1 3.71E+02
Ni CFS-L11-1314-T06-A 1 3.25E+02
Ni CFS-L11-1314-T07-A 1 2.52E+02
Ni CFS-L11-1314-T08-A 1 1.45E+02
Ni CFS-L11-1314-T09-A 1 1.11E+02
Ni CFS-L11-1314-T01-B 1 1.02E+03
Ni CFS-L11-1314-T02-B 1 4.56E+02
Ni CFS-L11-1314-T03-B 1 3.52E+02
Ni CFS-L11-1314-T04-B 1 3.46E+02
Ni CFS-L11-1314-T05-B 1 3.66E+02
Ni CFS-L11-1314-T06-B 1 3.35E+02
Ni CFS-L11-1314-T07-B 1 2.37E+02
Ni CFS-L11-1314-T08-B 1 1.37E+02
Ni CFS-L11-1314-T09-B 1 9.42E+01
Ni CFS-L11-1314-T01-C 1 1.02E+03
Ni CFS-L11-1314-T02-C 1 4.65E+02
Ni CFS-L11-1314-T03-C 1 3.63E+02
Ni CFS-L11-1314-T04-C 1 3.25E+02
Ni CFS-L11-1314-T05-C 1 3.73E+02
Ni CFS-L11-1314-T06-C 1 3.37E+02
Ni CFS-L11-1314-T07-C 1 2.43E+02
Ni CFS-L11-1314-T08-C 1 1.44E+02
Ni CFS-L11-1314-T09-C 1 1.03E+02
Ni CFS-L11-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
1.03E+03 1.06 1.80 5.70
4.61 E+02 1.39 1.80 5.70
3.79E+02 0.50 1.80 5.70 10000 1000
3.66E+02 0.90 1.80 5.70
3.71 E+02 0.73 1.80 5.70
3.25E+02 0.56 1.80 5.70
2.52E+02 1.42 1.80 5.70
1.45E+02 3.57 1.80 5.70
1.11 E+02 1.44 1.80 5.70
1.02E+03 1.60 1.80 5.70
4.56E+02 1.16 1.80 5.70
3.52E+02 0.93 1.80 5.70 10000 1000
3.46E+02 0.31 1.80 5.70
3.66E+02 1.93 1.80 5.70
3.35E+02 1.14 1.80 5.70
2.37E+02 0.44 1.80 5.70
1.37E+02 1.12 1.80 5.70
9.42E+01 3.60 1.80 5.70
1.02E+03 0.54 1.80 5.70
4.65E+02 0.70 1.80 5.70
3.63E+02 2.24 1.80 5.70 10000 1000
3.25E+02 0.50 1.80 5.70
3.73E+02 2.07 1.80 5.70
3.37E+02 2.30 1.80 5.70
2.43E+02 3.24 1.80 5.70
1.44E+02 2.96 1.80 5.70
1.03E+02 6.09 1.80 5.70
9.00E-01 8.83 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.31E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.29E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.24E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L11 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:26 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:45 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-137
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
P CFS-L11-1314-T01-A 1 4.61E+01
P CFS-L11-1314-T02-A 1 3.32E+01
P CFS-L11-1314-T03-A 1 2.65E+01
P CFS-L11-1314-T04-A 1 2.07E+01
P CFS-L11-1314-T05-A 1 2.23E+01
P CFS-L11-1314-T06-A 1 2.75E+01
P CFS-L11-1314-T07-A 1 2.22E+01
P CFS-L11-1314-T08-A 1 2.73E+01
P CFS-L11-1314-T09-A 1 2.80E+01
P CFS-L11-1314-T01-B 1 4.54E+01
P CFS-L11-1314-T02-B 1 3.24E+01
P CFS-L11-1314-T03-B 1 2.32E+01
P CFS-L11-1314-T04-B 1 2.49E+01
P CFS-L11-1314-T05-B 1 2.48E+01
P CFS-L11-1314-T06-B 1 2.89E+01
P CFS-L11-1314-T07-B 1 2.65E+01
P CFS-L11-1314-T08-B 1 2.23E+01
P CFS-L11-1314-T09-B 1 2.87E+01
P CFS-L11-1314-T01-C 1 4.98E+01
P CFS-L11-1314-T02-C 1 3.03E+01
P CFS-L11-1314-T03-C 1 2.76E+01
P CFS-L11-1314-T04-C 1 2.47E+01
P CFS-L11-1314-T05-C 1 2.10E+01
P CFS-L11-1314-T06-C 1 2.47E+01
P CFS-L11-1314-T07-C 1 2.17E+01
P CFS-L11-1314-T08-C 1 2.74E+01
P CFS-L11-1314-T09-C 1 2.53E+01
P CFS-L11-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
4.61 E+01 3.75 3.70 11.80
3.32E+01 8.26 3.70 11.80
2.65E+01 2.10 3.70 11.80 10000 1000
2.07E+01 4.07 3.70 11.80
2.23E+01 4.56 3.70 11.80
2.75E+01 4.89 3.70 11.80
2.22E+01 2.95 3.70 11.80
2.73E+01 1.90 3.70 11.80
2.80E+01 8.48 3.70 11.80
4.54E+01 4.37 3.70 11.80
3.24E+01 4.55 3.70 11.80
2.32E+01 10.78 3.70 11.80 10000 1000
2.49E+01 6.72 3.70 11.80
2.48E+01 2.52 3.70 11.80
2.89E+01 8.03 3.70 11.80
2.65E+01 7.26 3.70 11.80
2.23E+01 3.06 3.70 11.80
2.87E+01 6.63 3.70 11.80
4.98E+01 1.46 3.70 11.80
3.03E+01 9.95 3.70 11.80
2.76E+01 5.52 3.70 11.80 10000 1000
2.47E+01 4.14 3.70 11.80
2.10E+01 8.46 3.70 11.80
2.47E+01 3.70 3.70 11.80
2.17E+01 2.06 3.70 11.80
2.74E+01 1.87 3.70 11.80
2.53E+01 4.33 3.70 11.80
1.85E+00 16.40 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.11E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L11 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:26 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:45 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-138
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
K CFS-L11-1314-T01-A 1 1.29E+05
K CFS-L11-1314-T02-A 1 5.20E+04
K CFS-L11-1314-T03-A 1 2.78E+04
K CFS-L11-1314-T04-A 1 2.38E+04
K CFS-L11-1314-T05-A 1 1.84E+04
K CFS-L11-1314-T06-A 1 1.09E+04
K CFS-L11-1314-T07-A 1 6.88E+03
K CFS-L11-1314-T08-A 1 4.23E+03
K CFS-L11-1314-T09-A 1 3.06E+03
K CFS-L11-1314-T01-B 1 1.25E+05
K CFS-L11-1314-T02-B 1 4.96E+04
K CFS-L11-1314-T03-B 1 2.76E+04
K CFS-L11-1314-T04-B 1 2.30E+04
K CFS-L11-1314-T05-B 1 1.72E+04
K CFS-L11-1314-T06-B 1 9.97E+03
K CFS-L11-1314-T07-B 1 6.52E+03
K CFS-L11-1314-T08-B 1 3.99E+03
K CFS-L11-1314-T09-B 1 2.92E+03
K CFS-L11-1314-T01-C 1 1.24E+05
K CFS-L11-1314-T02-C 1 4.86E+04
K CFS-L11-1314-T03-C 1 2.64E+04
K CFS-L11-1314-T04-C 1 2.07E+04
K CFS-L11-1314-T05-C 1 1.71E+04
K CFS-L11-1314-T06-C 1 1.00E+04
K CFS-L11-1314-T07-C 1 6.57E+03
K CFS-L11-1314-T08-C 1 4.16E+03
K CFS-L11-1314-T09-C 1 2.88E+03
K CFS-L11-1314-B01-A 1 6.43E+00
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
1.29E+05 1.23 1.60 5.09
5.20E+04 0.86 1.60 5.09
2.78E+04 0.50 1.60 5.09 10000 1000
2.38E+04 0.65 1.60 5.09
1.84E+04 0.42 1.60 5.09
1.09E+04 1.32 1.60 5.09
6.88E+03 0.39 1.60 5.09
4.23E+03 0.21 1.60 5.09
3.06E+03 0.59 1.60 5.09
1.25E+05 0.68 1.60 5.09
4.96E+04 1.28 1.60 5.09
2.76E+04 0.59 1.60 5.09 10000 1000
2.30E+04 0.01 1.60 5.09
1.72E+04 0.82 1.60 5.09
9.97E+03 0.33 1.60 5.09
6.52E+03 0.72 1.60 5.09
3.99E+03 0.27 1.60 5.09
2.92E+03 0.11 1.60 5.09
1.24E+05 0.27 1.60 5.09
4.86E+04 1.37 1.60 5.09
2.64E+04 1.18 1.60 5.09 10000 1000
2.07E+04 1.55 1.60 5.09
1.71E+04 0.49 1.60 5.09
1.00E+04 0.77 1.60 5.09
6.57E+03 1.12 1.60 5.09
4.16E+03 0.17 1.60 5.09
2.88E+03 0.85 1.60 5.09
6.43E+00 1.94 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.87E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.84E+04 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.73E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L11 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:26 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:45 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-139
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L
Se CFS-L11-1314-T01-A 1 1.77E+03
Se CFS-L11-1314-T02-A 1 3.57E+02
Se CFS-L11-1314-T03-A 1 1.23E+02
Se CFS-L11-1314-T04-A 1 8.81 E+01
Se CFS-L11-1314-T05-A 1 6.61 E+01
Se CFS-L11-1314-T06-A 1 4.19E+01 E
Se CFS-L11-1314-T07-A 1 2.03E+01 E
Se CFS-L11-1314-T08-A 1 7.50E+00 U1/2
Se CFS-L11-1314-T09-A 1 7.50E+00 U1/2
Se CFS-L11-1314-T01-B 1 1.50E+03
Se CFS-L11-1314-T02-B 1 3.52E+02
Se CFS-L11-1314-T03-B 1 1.24E+02
Se CFS-L11-1314-T04-B 1 9.33E+01
Se CFS-L11-1314-T05-B 1 6.10E+01
Se CFS-L11-1314-T06-B 1 3.85E+01 E
Se CFS-L11-1314-T07-B 1 1.94E+01 E
Se CFS-L11-1314-T08-B 1 7.50E+00 U1/2
Se CFS-L11-1314-T09-B 1 7.50E+00 U1/2
Se CFS-L11-1314-T01-C 1 1.59E+03
Se CFS-L11-1314-T02-C 1 3.39E+02
Se CFS-L11-1314-T03-C 1 1.16E+02
Se CFS-L11-1314-T04-C 1 8.57E+01
Se CFS-L11-1314-T05-C 1 5.85E+01
Se CFS-L11-1314-T06-C 1 3.67E+01 E
Se CFS-L11-1314-T07-C 1 2.22E+01 E
Se CFS-L11-1314-T08-C 1 7.50E+00 U1/2
Se CFS-L11-1314-T09-C 1 7.50E+00 U1/2
Se CFS-L11-1314-B01-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
1.77E+03 2.13 15.00 47.70
3.57E+02 2.64 15.00 47.70
1.23E+02 9.53 15.00 47.70 10000 1000
8.81E+01 3.81 15.00 47.70
6.61E+01 1.32 15.00 47.70
4.19E+01 18.10 15.00 47.70
2.03E+01 8.59 15.00 47.70
7.50E+00 14.73 15.00 47.70
7.50E+00 12.23 15.00 47.70
1.50E+03 1.20 15.00 47.70
3.52E+02 5.86 15.00 47.70
1.24E+02 5.82 15.00 47.70 10000 1000
9.33E+01 1.45 15.00 47.70
6.10E+01 2.48 15.00 47.70
3.85E+01 4.92 15.00 47.70
1.94E+01 6.37 15.00 47.70
7.50E+00 12.25 15.00 47.70
7.50E+00 6.63 15.00 47.70
1.59E+03 0.83 15.00 47.70
3.39E+02 1.78 15.00 47.70
1.16E+02 8.09 15.00 47.70 10000 1000
8.57E+01 1.75 15.00 47.70
5.85E+01 5.78 15.00 47.70
3.67E+01 23.34 15.00 47.70
2.22E+01 16.77 15.00 47.70
7.50E+00 6.92 15.00 47.70
7.50E+00 13.09 15.00 47.70
7.50E+00 11.20 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.21E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:26 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/1212:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:39 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:45 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:52 PM EPA Interlab L1 1 1314 CFS
1-140
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Si CFS-L11-1314-T01-A 1 8.24E+03
Si CFS-L11-1314-T02-A 1 7.24E+03
Si CFS-L11-1314-T03-A 1 6.46E+03
Si CFS-L11-1314-T04-A 1 5.83E+03
Si CFS-L11-1314-T05-A 1 5.74E+03
Si CFS-L11-1314-T06-A 1 5.20E+03
Si CFS-L11-1314-T07-A 1 4.89E+03
Si CFS-L11-1314-T08-A 1 4.12E+03
Si CFS-L11-1314-T09-A 1 4.16E+03
Si CFS-L11-1314-T01-B 1 8.12E+03
Si CFS-L11-1314-T02-B 1 6.82E+03
Si CFS-L11-1314-T03-B 1 6.38E+03
Si CFS-L11-1314-T04-B 1 6.20E+03
Si CFS-L11-1314-T05-B 1 5.94E+03
Si CFS-L11-1314-T06-B 1 5.38E+03
Si CFS-L11-1314-T07-B 1 4.94E+03
Si CFS-L11-1314-T08-B 1 4.24E+03
Si CFS-L11-1314-T09-B 1 4.14E+03
Si CFS-L11-1314-T01-C 1 8.05E+03
Si CFS-L11-1314-T02-C 1 6.84E+03
Si CFS-L11-1314-T03-C 1 6.02E+03
Si CFS-L11-1314-T04-C 1 5.90E+03
Si CFS-L11-1314-T05-C 1 5.87E+03
Si CFS-L11-1314-T06-C 1 5.11E+03
Si CFS-L11-1314-T07-C 1 4.90E+03
Si CFS-L11-1314-T08-C 1 4.02E+03
Si CFS-L11-1314-T09-C 1 3.88E+03
Si CFS-L11-1314-B01-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
8.24E+03 0.91 1.10 3.50
7.24E+03 1.05 1.10 3.50
6.46E+03 0.50 1.10 3.50 10000 1000
5.83E+03 1.49 1.10 3.50
5.74E+03 1.22 1.10 3.50
5.20E+03 1.62 1.10 3.50
4.89E+03 0.91 1.10 3.50
4.12E+03 1.50 1.10 3.50
4.16E+03 1.48 1.10 3.50
8.12E+03 1.18 1.10 3.50
6.82E+03 1.06 1.10 3.50
6.38E+03 0.96 1.10 3.50 10000 1000
6.20E+03 0.56 1.10 3.50
5.94E+03 1.69 1.10 3.50
5.38E+03 0.65 1.10 3.50
4.94E+03 0.76 1.10 3.50
4.24E+03 1.45 1.10 3.50
4.14E+03 0.76 1.10 3.50
8.05E+03 0.40 1.10 3.50
6.84E+03 0.93 1.10 3.50
6.02E+03 0.66 1.10 3.50 10000 1000
5.90E+03 1.69 1.10 3.50
5.87E+03 0.20 1.10 3.50
5.11E+03 1.22 1.10 3.50
4.90E+03 1.99 1.10 3.50
4.02E+03 0.94 1.10 3.50
3.88E+03 0.79 1.10 3.50
5.50E-01 7.21 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
7.31E+03 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.27E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.88E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L11 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:26 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:45 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-141
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Na CFS-L11-1314-T01-A 1 3.12E+05
Na CFS-L11-1314-T02-A 1 1.48E+05
Na CFS-L11-1314-T03-A 1 2.23E+04
Na CFS-L11-1314-T04-A 1 9.55E+03
Na CFS-L11-1314-T05-A 1 5.71E+03
Na CFS-L11-1314-T06-A 1 3.74E+03
Na CFS-L11-1314-T07-A 1 2.87E+03
Na CFS-L11-1314-T08-A 1 2.24E+03
Na CFS-L11-1314-T09-A 1 1.97E+03
Na CFS-L11-1314-T01-B 1 3.16E+05
Na CFS-L11-1314-T02-B 1 1.52E+05
Na CFS-L11-1314-T03-B 1 2.47E+04
Na CFS-L11-1314-T04-B 1 9.37E+03
Na CFS-L11-1314-T05-B 1 5.43E+03
Na CFS-L11-1314-T06-B 1 3.44E+03
Na CFS-L11-1314-T07-B 1 2.67E+03
Na CFS-L11-1314-T08-B 1 2.03E+03
Na CFS-L11-1314-T09-B 1 1.81E+03
Na CFS-L11-1314-T01-C 1 3.09E+05
Na CFS-L11-1314-T02-C 1 1.46E+05
Na CFS-L11-1314-T03-C 1 2.28E+04
Na CFS-L11-1314-T04-C 1 9.41 E+03
Na CFS-L11-1314-T05-C 1 5.43E+03
Na CFS-L11-1314-T06-C 1 3.54E+03
Na CFS-L11-1314-T07-C 1 2.76E+03
Na CFS-L11-1314-T08-C 1 2.22E+03
Na CFS-L11-1314-T09-C 1 2.00E+03
Na CFS-L11-1314-B01-A 1 1.33E+01
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
3.12E+05 0.98 2.50 8.00
1.48E+05 1.01 2.50 8.00
2.23E+04 0.95 2.50 8.00 10000 1000
9.55E+03 0.54 2.50 8.00
5.71 E+03 0.66 2.50 8.00
3.74E+03 0.99 2.50 8.00
2.87E+03 0.48 2.50 8.00
2.24E+03 0.68 2.50 8.00
1.97E+03 0.90 2.50 8.00
3.16E+05 1.20 2.50 8.00
1.52E+05 1.40 2.50 8.00
2.47E+04 1.34 2.50 8.00 10000 1000
9.37E+03 0.25 2.50 8.00
5.43E+03 0.61 2.50 8.00
3.44E+03 0.79 2.50 8.00
2.67E+03 0.41 2.50 8.00
2.03E+03 0.53 2.50 8.00
1.81 E+03 0.18 2.50 8.00
3.09E+05 0.67 2.50 8.00
1.46E+05 0.93 2.50 8.00
2.28E+04 0.87 2.50 8.00 10000 1000
9.41 E+03 0.90 2.50 8.00
5.43E+03 0.43 2.50 8.00
3.54E+03 1.19 2.50 8.00
2.76E+03 1.10 2.50 8.00
2.22E+03 0.41 2.50 8.00
2.00E+03 0.83 2.50 8.00
1.33E+01 2.45 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.32E+04 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.56E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.37E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L11 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:26 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:45 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-142
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Sr CFS-L11-1314-T01-A 1 5.21E+03
Sr CFS-L11-1314-T02-A 1 3.54E+03
Sr CFS-L11-1314-T03-A 1 3.52E+03
Sr CFS-L11-1314-T04-A 1 3.27E+03
Sr CFS-L11-1314-T05-A 1 2.77E+03
Sr CFS-L11-1314-T06-A 1 2.02E+03
Sr CFS-L11-1314-T07-A 1 1.83E+03
Sr CFS-L11-1314-T08-A 1 1.61E+03
Sr CFS-L11-1314-T09-A 1 1.64E+03
Sr CFS-L11-1314-T01-B 1 5.01E+03
Sr CFS-L11-1314-T02-B 1 3.49E+03
Sr CFS-L11-1314-T03-B 1 3.40E+03
Sr CFS-L11-1314-T04-B 1 3.13E+03
Sr CFS-L11-1314-T05-B 1 2.55E+03
Sr CFS-L11-1314-T06-B 1 1.98E+03
Sr CFS-L11-1314-T07-B 1 1.81E+03
Sr CFS-L11-1314-T08-B 1 1.63E+03
Sr CFS-L11-1314-T09-B 1 1.63E+03
Sr CFS-L11-1314-T01-C 1 5.20E+03
Sr CFS-L11-1314-T02-C 1 3.74E+03
Sr CFS-L11-1314-T03-C 1 3.54E+03
Sr CFS-L11-1314-T04-C 1 3.08E+03
Sr CFS-L11-1314-T05-C 1 2.82E+03
Sr CFS-L11-1314-T06-C 1 1.93E+03
Sr CFS-L11-1314-T07-C 1 1.79E+03
Sr CFS-L11-1314-T08-C 1 1.61E+03
Sr CFS-L11-1314-T09-C 1 1.64E+03
Sr CFS-L11-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
5.21E+03 1.41 1.00 3.18
3.54E+03 1.42 1.00 3.18
3.52E+03 1.13 1.00 3.18 10000 1000
3.27E+03 1.83 1.00 3.18
2.77E+03 0.84 1.00 3.18
2.02E+03 1.64 1.00 3.18
1.83E+03 0.61 1.00 3.18
1.61E+03 1.03 1.00 3.18
1.64E+03 1.00 1.00 3.18
5.01E+03 0.98 1.00 3.18
3.49E+03 0.42 1.00 3.18
3.40E+03 0.62 1.00 3.18 10000 1000
3.13E+03 0.99 1.00 3.18
2.55E+03 1.71 1.00 3.18
1.98E+03 0.22 1.00 3.18
1.81E+03 0.71 1.00 3.18
1.63E+03 0.73 1.00 3.18
1.63E+03 0.56 1.00 3.18
5.20E+03 1.43 1.00 3.18
3.74E+03 1.25 1.00 3.18
3.54E+03 1.71 1.00 3.18 10000 1000
3.08E+03 0.86 1.00 3.18
2.82E+03 1.18 1.00 3.18
1.93E+03 0.98 1.00 3.18
1.79E+03 1.51 1.00 3.18
1.61E+03 0.93 1.00 3.18
1.64E+03 0.83 1.00 3.18
5.00E-01 3.39 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.47E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.32E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.52E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L11 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:26 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:45 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-143
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
S CFS-L11-1314-T01-A 1 2.42E+06
S CFS-L11-1314-T02-A 1 1.28E+06
S CFS-L11-1314-T03-A 1 7.21E+05
S CFS-L11-1314-T04-A 1 5.94E+05
S CFS-L11-1314-T05-A 1 5.73E+05
S CFS-L11-1314-T06-A 1 5.51 E+05
S CFS-L11-1314-T07-A 1 5.44E+05
S CFS-L11-1314-T08-A 1 5.25E+05
S CFS-L11-1314-T09-A 1 5.32E+05
S CFS-L11-1314-T01-B 1 2.34E+06
S CFS-L11-1314-T02-B 1 1.30E+06
S CFS-L11-1314-T03-B 1 7.15E+05
S CFS-L11-1314-T04-B 1 5.93E+05
S CFS-L11-1314-T05-B 1 5.72E+05
S CFS-L11-1314-T06-B 1 5.57E+05
S CFS-L11-1314-T07-B 1 5.47E+05
S CFS-L11-1314-T08-B 1 5.43E+05
S CFS-L11-1314-T09-B 1 5.25E+05
S CFS-L11-1314-T01-C 1 2.27E+06
S CFS-L11-1314-T02-C 1 1.23E+06
S CFS-L11-1314-T03-C 1 7. 11 E+05
S CFS-L11-1314-T04-C 1 5.81 E+05
S CFS-L11-1314-T05-C 1 5.62E+05
S CFS-L11-1314-T06-C 1 5.44E+05
S CFS-L11-1314-T07-C 1 5.45E+05
S CFS-L11-1314-T08-C 1 5.35E+05
S CFS-L11-1314-T09-C 1 5.52E+05
S CFS-L11-1314-B01-A 1 1.74E+01 E
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
2.42E+06 0.74 6.80 21.60
1.28E+06 0.08 6.80 21.60
7.21E+05 2.81 6.80 21.60 10000 1000
5.94E+05 1.85 6.80 21.60
5.73E+05 1.09 6.80 21.60
5.51 E+05 1.65 6.80 21.60
5.44E+05 3.28 6.80 21.60
5.25E+05 1.48 6.80 21.60
5.32E+05 1.72 6.80 21.60
2.34E+06 1.21 6.80 21.60
1.30E+06 0.39 6.80 21.60
7.15E+05 1.62 6.80 21.60 10000 1000
5.93E+05 1.01 6.80 21.60
5.72E+05 0.65 6.80 21.60
5.57E+05 2.38 6.80 21.60
5.47E+05 1.44 6.80 21.60
5.43E+05 1.60 6.80 21.60
5.25E+05 0.91 6.80 21.60
2.27E+06 0.54 6.80 21.60
1.23E+06 0.64 6.80 21.60
7.11E+05 2.24 6.80 21.60 10000 1000
5.81 E+05 3.01 6.80 21.60
5.62E+05 0.49 6.80 21.60
5.44E+05 0.60 6.80 21.60
5.45E+05 2.56 6.80 21.60
5.35E+05 2.11 6.80 21.60
5.52E+05 0.71 6.80 21.60
1.74E+01 2.99 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
7.22E+05 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.16E+05 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.12E+05 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L11 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:26 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:45 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-144
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Tl CFS-L11-1314-T01-A 1 1.92E+03
Tl CFS-L11-1314-T02-A 1 9.63E+02
Tl CFS-L11-1314-T03-A 1 6.33E+02
Tl CFS-L11-1314-T04-A 1 4.75E+02
Tl CFS-L11-1314-T05-A 1 3.87E+02
Tl CFS-L11-1314-T06-A 1 2.41 E+02
Tl CFS-L11-1314-T07-A 1 1.75E+02
Tl CFS-L11-1314-T08-A 1 1.14E+02
Tl CFS-L11-1314-T09-A 1 9.95E+01
Tl CFS-L11-1314-T01-B 1 1.91E+03
Tl CFS-L11-1314-T02-B 1 9.81 E+02
Tl CFS-L11-1314-T03-B 1 6.37E+02
Tl CFS-L11-1314-T04-B 1 4.82E+02
Tl CFS-L11-1314-T05-B 1 3.91 E+02
Tl CFS-L11-1314-T06-B 1 2.43E+02
Tl CFS-L11-1314-T07-B 1 1.69E+02
Tl CFS-L11-1314-T08-B 1 1.07E+02
Tl CFS-L11-1314-T09-B 1 9.47E+01
Tl CFS-L11-1314-T01-C 1 1.88E+03
Tl CFS-L11-1314-T02-C 1 8.51 E+02
Tl CFS-L11-1314-T03-C 1 5.82E+02
Tl CFS-L11-1314-T04-C 1 4.50E+02
Tl CFS-L11-1314-T05-C 1 3.53E+02
Tl CFS-L11-1314-T06-C 1 2.23E+02
Tl CFS-L11-1314-T07-C 1 1.58E+02
Tl CFS-L11-1314-T08-C 1 1.20E+02
Tl CFS-L11-1314-T09-C 1 8.46E+01
Tl CFS-L11-1314-B01-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
1.92E+03 1.02 4.60 14.60
9.63E+02 1.60 4.60 14.60
6.33E+02 0.79 4.60 14.60 10000 1000
4.75E+02 1.18 4.60 14.60
3.87E+02 2.64 4.60 14.60
2.41E+02 1.92 4.60 14.60
1.75E+02 2.04 4.60 14.60
1.14E+02 2.01 4.60 14.60
9.95E+01 3.14 4.60 14.60
1.91E+03 1.04 4.60 14.60
9.81E+02 1.91 4.60 14.60
6.37E+02 2.12 4.60 14.60 10000 1000
4.82E+02 2.45 4.60 14.60
3.91E+02 3.63 4.60 14.60
2.43E+02 1.93 4.60 14.60
1.69E+02 5.79 4.60 14.60
1.07E+02 3.34 4.60 14.60
9.47E+01 2.17 4.60 14.60
1.88E+03 1.18 4.60 14.60
8.51E+02 1.76 4.60 14.60
5.82E+02 1.25 4.60 14.60 10000 1000
4.50E+02 1.36 4.60 14.60
3.53E+02 1.16 4.60 14.60
2.23E+02 2.91 4.60 14.60
1.58E+02 4.28 4.60 14.60
1.20E+02 6.19 4.60 14.60
8.46E+01 1.85 4.60 14.60
2.30E+00 5.38 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.61E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.62E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.63E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L11 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:26 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:45 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-145
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ti CFS-L11-1314-T01-A 1 1.00E+00 U1/2
Ti CFS-L11-1314-T02-A 1 1.00E+00 U1/2
Ti CFS-L11-1314-T03-A 1 1.00E+00 U1/2
Ti CFS-L11-1314-T04-A 1 1.00E+00 U1/2
Ti CFS-L11-1314-T05-A 1 1.00E+00 U1/2
Ti CFS-L11-1314-T06-A 1 1.00E+00 U1/2
Ti CFS-L11-1314-T07-A 1 1.00E+00 U1/2
Ti CFS-L11-1314-T08-A 1 1.00E+00 U1/2
Ti CFS-L11-1314-T09-A 1 1.00E+00 U1/2
Ti CFS-L11-1314-T01-B 1 1.00E+00 U1/2
Ti CFS-L11-1314-T02-B 1 1.00E+00 U1/2
Ti CFS-L11-1314-T03-B 1 1.00E+00 U1/2
Ti CFS-L11-1314-T04-B 1 1.00E+00 U1/2
Ti CFS-L11-1314-T05-B 1 1.00E+00 U1/2
Ti CFS-L11-1314-T06-B 1 1.00E+00 U1/2
Ti CFS-L11-1314-T07-B 1 1.00E+00 U1/2
Ti CFS-L11-1314-T08-B 1 1.00E+00 U1/2
Ti CFS-L11-1314-T09-B 1 1.00E+00 U1/2
Ti CFS-L11-1314-T01-C 1 1.00E+00 U1/2
Ti CFS-L11-1314-T02-C 1 1.00E+00 U1/2
Ti CFS-L11-1314-T03-C 1 1.00E+00 U1/2
Ti CFS-L11-1314-T04-C 1 1.00E+00 U1/2
Ti CFS-L11-1314-T05-C 1 1.00E+00 U1/2
Ti CFS-L11-1314-T06-C 1 1.00E+00 U1/2
Ti CFS-L11-1314-T07-C 1 1.00E+00 U1/2
Ti CFS-L11-1314-T08-C 1 1.00E+00 U1/2
Ti CFS-L11-1314-T09-C 1 1.00E+00 U1/2
Ti CFS-L11-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
1.00E+00 13.18 2.00 6.40
1.00E+00 2.71 2.00 6.40
1.00E+00 5.24 2.00 6.40 10000 1000
1.00E+00 4.96 2.00 6.40
1.00E+00 10.87 2.00 6.40
1.00E+00 3.55 2.00 6.40
1.00E+00 2.19 2.00 6.40
1.00E+00 22.25 2.00 6.40
1.00E+00 8.40 2.00 6.40
1.00E+00 3.71 2.00 6.40
1.00E+00 3.51 2.00 6.40
1.00E+00 14.23 2.00 6.40 10000 1000
1.00E+00 11.34 2.00 6.40
1.00E+00 3.18 2.00 6.40
1.00E+00 10.60 2.00 6.40
1.00E+00 14.61 2.00 6.40
1.00E+00 14.11 2.00 6.40
1.00E+00 3.20 2.00 6.40
1.00E+00 2.77 2.00 6.40
1.00E+00 0.25 2.00 6.40
1.00E+00 22.41 2.00 6.40 10000 1000
1.00E+00 4.24 2.00 6.40
1.00E+00 3.42 2.00 6.40
1.00E+00 12.50 2.00 6.40
1.00E+00 16.83 2.00 6.40
1.00E+00 4.64 2.00 6.40
1.00E+00 5.66 2.00 6.40
1.00E+00 17.38 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L11 1314 CFS
3/6/12 12:26 PM EPA Interlab L11 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L11 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L11 1314 CFS
3/6/12 12:45 PM EPA Interlab L11 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L11 1314 CFS
3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-146
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
V CFS-L11-1314-T01-A 1 2.58E+01
V CFS-L11-1314-T02-A 1 3.28E+01
V CFS-L11-1314-T03-A 1 3.92E+01
V CFS-L11-1314-T04-A 1 3.70E+01
V CFS-L11-1314-T05-A 1 3.85E+01
V CFS-L11-1314-T06-A 1 3.95E+01
V CFS-L11-1314-T07-A 1 3.96E+01
V CFS-L11-1314-T08-A 1 3.85E+01
V CFS-L11-1314-T09-A 1 3.94E+01
V CFS-L11-1314-T01-B 1 2.41E+01
V CFS-L11-1314-T02-B 1 3.42E+01
V CFS-L11-1314-T03-B 1 3.98E+01
V CFS-L11-1314-T04-B 1 3.73E+01
V CFS-L11-1314-T05-B 1 3.79E+01
V CFS-L11-1314-T06-B 1 3.87E+01
V CFS-L11-1314-T07-B 1 3.95E+01
V CFS-L11-1314-T08-B 1 3.98E+01
V CFS-L11-1314-T09-B 1 4.05E+01
V CFS-L11-1314-T01-C 1 2.68E+01
V CFS-L11-1314-T02-C 1 3.36E+01
V CFS-L11-1314-T03-C 1 4.03E+01
V CFS-L11-1314-T04-C 1 3.65E+01
V CFS-L11-1314-T05-C 1 3.93E+01
V CFS-L11-1314-T06-C 1 3.92E+01
V CFS-L11-1314-T07-C 1 3.89E+01
V CFS-L11-1314-T08-C 1 3.88E+01
V CFS-L11-1314-T09-C 1 3.98E+01
V CFS-L11-1314-B01-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
2.58E+01 2.37 1.50 4.77
3.28E+01 2.22 1.50 4.77
3.92E+01 3.14 1.50 4.77 10000 1000
3.70E+01 1.30 1.50 4.77
3.85E+01 1.10 1.50 4.77
3.95E+01 2.06 1.50 4.77
3.96E+01 1.73 1.50 4.77
3.85E+01 2.17 1.50 4.77
3.94E+01 0.74 1.50 4.77
2.41 E+01 3.25 1.50 4.77
3.42E+01 2.43 1.50 4.77
3.98E+01 2.13 1.50 4.77 10000 1000
3.73E+01 0.71 1.50 4.77
3.79E+01 1.63 1.50 4.77
3.87E+01 0.84 1.50 4.77
3.95E+01 0.59 1.50 4.77
3.98E+01 0.58 1.50 4.77
4.05E+01 1.10 1.50 4.77
2.68E+01 2.91 1.50 4.77
3.36E+01 1.65 1.50 4.77
4.03E+01 1.55 1.50 4.77 10000 1000
3.65E+01 1.35 1.50 4.77
3.93E+01 1.02 1.50 4.77
3.92E+01 1.52 1.50 4.77
3.89E+01 1.70 1.50 4.77
3.88E+01 1.01 1.50 4.77
3.98E+01 1.33 1.50 4.77
7.50E-01 8.31 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.06E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L11 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:26 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:45 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-147
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Zn CFS-L11-1314-T01-A 1 5.81E+04
Zn CFS-L11-1314-T02-A 1 5.03E+04
Zn CFS-L11-1314-T03-A 1 4.31 E+04
Zn CFS-L11-1314-T04-A 1 3.77E+04
Zn CFS-L11-1314-T05-A 1 3.87E+04
Zn CFS-L11-1314-T06-A 1 3.53E+04
Zn CFS-L11-1314-T07-A 1 3.14E+04
Zn CFS-L11-1314-T08-A 1 2.28E+04
Zn CFS-L11-1314-T09-A 1 1.91 E+04
Zn CFS-L11-1314-T01-B 1 5.84E+04
Zn CFS-L11-1314-T02-B 1 5.13E+04
Zn CFS-L11-1314-T03-B 1 4.49E+04
Zn CFS-L11-1314-T04-B 1 3.84E+04
Zn CFS-L11-1314-T05-B 1 3.80E+04
Zn CFS-L11-1314-T06-B 1 3.37E+04
Zn CFS-L11-1314-T07-B 1 2.77E+04
Zn CFS-L11-1314-T08-B 1 2.31 E+04
Zn CFS-L11-1314-T09-B 1 1.72E+04
Zn CFS-L11-1314-T01-C 1 5.50E+04
Zn CFS-L11-1314-T02-C 1 4.96E+04
Zn CFS-L11-1314-T03-C 1 4.32E+04
Zn CFS-L11-1314-T04-C 1 3.65E+04
Zn CFS-L11-1314-T05-C 1 3.62E+04
Zn CFS-L11-1314-T06-C 1 3.42E+04
Zn CFS-L11-1314-T07-C 1 2.36E+04
Zn CFS-L11-1314-T08-C 1 1.99E+04
Zn CFS-L11-1314-T09-C 1 1.70E+04
Zn CFS-L11-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
MS/I- % MS/I- MS/I- MS/I- ML
5.81E+04 1.17 1.00 3.18
5.03E+04 1.39 1.00 3.18
4.31E+04 0.90 1.00 3.18 10000 1000
3.77E+04 0.19 1.00 3.18
3.87E+04 0.72 1.00 3.18
3.53E+04 0.98 1.00 3.18
3.14E+04 0.97 1.00 3.18
2.28E+04 0.69 1.00 3.18
1.91 E+04 0.32 1.00 3.18
5.84E+04 0.92 1.00 3.18
5.13E+04 1.17 1.00 3.18
4.49E+04 0.93 1.00 3.18 10000 1000
3.84E+04 0.22 1.00 3.18
3.80E+04 0.88 1.00 3.18
3.37E+04 0.72 1.00 3.18
2.77E+04 0.32 1.00 3.18
2.31E+04 0.75 1.00 3.18
1.72E+04 0.97 1.00 3.18
5.50E+04 1.23 1.00 3.18
4.96E+04 1.39 1.00 3.18
4.32E+04 1.75 1.00 3.18 10000 1000
3.65E+04 1.29 1.00 3.18
3.62E+04 1.09 1.00 3.18
3.42E+04 1.02 1.00 3.18
2.36E+04 1.65 1.00 3.18
1.99E+04 0.32 1.00 3.18
1.70E+04 1.53 1.00 3.18
5.00E-01 10.40 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.41E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.58E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.42E+04 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:03 PM EPA Interlab L11 1314 CFS
3/6/12 12:04 PM EPA Interlab L11 1314 CFS
3/6/12 12:06 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:08 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:09 PM EPA Interlab L11 1314 CFS
3/6/1212:11 PM EPA Interlab L11 1314 CFS
3/6/12 12:12 PM EPA Interlab L11 1314 CFS
3/6/12 12:14 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:16 PM EPA Interlab L11 1314 CFS
3/6/12 12:22 PM EPA Interlab L11 1314 CFS
3/6/12 12:24 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:26 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:27 PM EPA Interlab L11 1314 CFS
3/6/12 12:29 PM EPA Interlab L11 1314 CFS
3/6/12 12:31 PM EPA Interlab L11 1314 CFS
3/6/12 12:32 PM EPA Interlab L11 1314 CFS
3/6/12 12:34 PM EPA Interlab L11 1314 CFS
3/6/12 12:35 PM EPA Interlab L11 1314 CFS
3/6/12 12:37 PM EPA Interlab L11 1314 CFS
3/6/12 12:39 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:40 PM EPA Interlab L11 1314 CFS
3/6/12 12:42 PM EPA Interlab L11 1314 CFS
3/6/12 12:44 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:45 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:47 PM EPA Interlab L11 1314 CFS
3/6/12 12:49 PM EPA Interlab L11 1314 CFS
3/6/12 12:50 PM EPA Interlab L1 1 1314 CFS
3/6/12 12:52 PM EPA Interlab L11 1314 CFS
1-148
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1314:
Element
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Dilut
Sample ID Fact
CFS-L14-1314-T01-A
CFS-L14-1314-T02-A
CFS-L14-1314-T03-A
CFS-L14-1314-T04-A
CFS-L14-1314-T05-A
CFS-L14-1314-T06-A
CFS-L14-1314-T07-A
CFS-L14-1314-T08-A
CFS-L14-1314-T09-A
CFS-L14-1314-T01-B
CFS-L14-1314-T02-B
CFS-L14-1314-T03-B
CFS-L14-1314-T04-B
CFS-L14-1314-T05-B
CFS-L14-1314-T06-B
CFS-L14-1314-T07-B
CFS-L14-1314-T08-B
CFS-L14-1314-T09-B
CFS-L14-1314-T01-C
CFS-L14-1314-T02-C
CFS-L14-1314-T03-C
CFS-L14-1314-T04-C
CFS-L14-1314-T05-C
CFS-L14-1314-T06-C
CFS-L14-1314-T07-C
CFS-L14-1314-T08-C
CFS-L14-1314-T09-C
CFS-L14-1314-B01-A
on Sample
or Cone. Qualifier
ug/L
1 4.94E+01
1 5.75E+01
1 4.03E+01
1 3.73E+01
1 6.87E+01
1 4.20E+01
1 3.83E+01
1 4.03E+01
1 3.97E+01
1 4.77E+01
1 4.62E+01
1 3.94E+01
1 3.42E+01
1 4.61 E+01
1 4.95E+01
1 3.79E+01
1 3.50E+01
1 3.68E+01
1 4.90E+01
1 4.91 E+01
1 4.52E+01
1 6.88E+01
1 7.52E+01
1 5.44E+01
1 3.81 E+01
1 3.99E+01
1 4.38E+01
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.94E+01 6.33 1.00 3.18
5.75E+01 4.73 1.00 3.18
4.03E+01 6.36 1.00 3.18 10000 1000
3.73E+01 7.47 1.00 3.18
6.87E+01 2.46 1.00 3.18
4.20E+01 0.85 1.00 3.18
3.83E+01 4.46 1.00 3.18
4.03E+01 4.78 1.00 3.18
3.97E+01 2.74 1.00 3.18
4.77E+01 5.77 1.00 3.18
4.62E+01 2.10 1.00 3.18
3.94E+01 6.53 1.00 3.18 10000 1000
3.42E+01 3.77 1.00 3.18
4.61E+01 4.90 1.00 3.18
4.95E+01 3.36 1.00 3.18
3.79E+01 2.79 1.00 3.18
3.50E+01 6.12 1.00 3.18
3.68E+01 1.81 1.00 3.18
4.90E+01 5.51 1.00 3.18
4.91E+01 2.26 1.00 3.18
4.52E+01 5.95 1.00 3.18 10000 1000
6.88E+01 3.77 1.00 3.18
7.52E+01 2.54 1.00 3.18
5.44E+01 0.60 1.00 3.18
3.81E+01 4.59 1.00 3.18
3.99E+01 3.56 1.00 3.18
4.38E+01 3.58 1.00 3.18
5.00E-01 38.15 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.06E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-149
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Sb CFS-L14-1314-T01-A 1 6.38E+01
Sb CFS-L14-1314-T02-A 1 3.74E+01
Sb CFS-L14-1314-T03-A 1 2.43E+01
Sb CFS-L14-1314-T04-A 1 2.75E+01
Sb CFS-L14-1314-T05-A 1 2.38E+01 E
Sb CFS-L14-1314-T06-A 1 2.83E+01
Sb CFS-L14-1314-T07-A 1 2.73E+01
Sb CFS-L14-1314-T08-A 1 1.93E+01 E
Sb CFS-L14-1314-T09-A 1 2.14E+01 E
Sb CFS-L14-1314-T01-B 1 7.00E+01
Sb CFS-L14-1314-T02-B 1 4.79E+01
Sb CFS-L14-1314-T03-B 1 2.75E+01
Sb CFS-L14-1314-T04-B 1 3.19E+01
Sb CFS-L14-1314-T05-B 1 3.26E+01
Sb CFS-L14-1314-T06-B 1 2.91E+01
Sb CFS-L14-1314-T07-B 1 3.41E+01
Sb CFS-L14-1314-T08-B 1 2.83E+01
Sb CFS-L14-1314-T09-B 1 2.44E+01
Sb CFS-L14-1314-T01-C 1 6.21E+01
Sb CFS-L14-1314-T02-C 1 4.87E+01
Sb CFS-L14-1314-T03-C 1 3.17E+01
Sb CFS-L14-1314-T04-C 1 3.08E+01
Sb CFS-L14-1314-T05-C 1 3.26E+01
Sb CFS-L14-1314-T06-C 1 2.29E+01 E
Sb CFS-L14-1314-T07-C 1 2.68E+01
Sb CFS-L14-1314-T08-C 1 2.92E+01
Sb CFS-L14-1314-T09-C 1 2.34E+01 E
Sb CFS-L14-1314-B01-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.38E+01 1.60 7.50 23.90
3.74E+01 9.34 7.50 23.90
2.43E+01 3.04 7.50 23.90 10000 1000
2.75E+01 1.66 7.50 23.90
2.38E+01 9.43 7.50 23.90
2.83E+01 11.43 7.50 23.90
2.73E+01 2.13 7.50 23.90
1.93E+01 18.87 7.50 23.90
2.14E+01 7.12 7.50 23.90
7.00E+01 1.04 7.50 23.90
4.79E+01 1.11 7.50 23.90
2.75E+01 1.43 7.50 23.90 10000 1000
3.19E+01 1.11 7.50 23.90
3.26E+01 1.43 7.50 23.90
2.91E+01 1.15 7.50 23.90
3.41 E+01 5.00 7.50 23.90
2.83E+01 1.08 7.50 23.90
2.44E+01 13.97 7.50 23.90
6.21 E+01 3.09 7.50 23.90
4.87E+01 1.11 7.50 23.90
3.17E+01 1.42 7.50 23.90 10000 1000
3.08E+01 2.69 7.50 23.90
3.26E+01 1.29 7.50 23.90
2.29E+01 21.13 7.50 23.90
2.68E+01 3.52 7.50 23.90
2.92E+01 1.09 7.50 23.90
2.34E+01 10.24 7.50 23.90
3.75E+00 56.11 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.09E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-150
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L
As CFS-L14-1314-T01-A 1 5.80E+01
As CFS-L14-1314-T02-A 1 2.55E+01 E
As CFS-L14-1314-T03-A 1 1.52E+01 E
As CFS-L14-1314-T04-A 1 5.50E+00 U1/2
As CFS-L14-1314-T05-A 1 5.50E+00 U1/2
As CFS-L14-1314-T06-A 1 5.50E+00 U1/2
As CFS-L14-1314-T07-A 1 5.50E+00 U1/2
As CFS-L14-1314-T08-A 1 5.50E+00 U1/2
As CFS-L14-1314-T09-A 1 5.50E+00 U1/2
As CFS-L14-1314-T01-B 1 5.90E+01
As CFS-L14-1314-T02-B 1 3.05E+01 E
As CFS-L14-1314-T03-B 1 1.71E+01 E
As CFS-L14-1314-T04-B 1 5.50E+00 U1/2
As CFS-L14-1314-T05-B 1 5.50E+00 U1/2
As CFS-L14-1314-T06-B 1 5.50E+00 U1/2
As CFS-L14-1314-T07-B 1 5.50E+00 U1/2
As CFS-L14-1314-T08-B 1 5.50E+00 U1/2
As CFS-L14-1314-T09-B 1 5.50E+00 U1/2
As CFS-L14-1314-T01-C 1 5.86E+01
As CFS-L14-1314-T02-C 1 2.93E+01 E
As CFS-L14-1314-T03-C 1 1.24E+01 E
As CFS-L14-1314-T04-C 1 1.31E+01 E
As CFS-L14-1314-T05-C 1 5.50E+00 U1/2
As CFS-L14-1314-T06-C 1 5.50E+00 U1/2
As CFS-L14-1314-T07-C 1 5.50E+00 U1/2
As CFS-L14-1314-T08-C 1 5.50E+00 U1/2
As CFS-L14-1314-T09-C 1 5.50E+00 U1/2
As CFS-L14-1314-B01-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.80E+01 7.97 11.00 35.00
2.55E+01 13.49 11.00 35.00
1.52E+01 14.66 11.00 35.00 10000 1000
5.50E+00 31.51 11.00 35.00
5.50E+00 4.86 11.00 35.00
5.50E+00 38.48 11.00 35.00
5.50E+00 42.80 11.00 35.00
5.50E+00 20.12 11.00 35.00
5.50E+00 40.52 11.00 35.00
5.90E+01 5.91 11.00 35.00
3.05E+01 15.49 11.00 35.00
1.71E+01 29.67 11.00 35.00 10000 1000
5.50E+00 27.88 11.00 35.00
5.50E+00 2.77 11.00 35.00
5.50E+00 27.63 11.00 35.00
5.50E+00 9.87 11.00 35.00
5.50E+00 43.30 11.00 35.00
5.50E+00 22.58 11.00 35.00
5.86E+01 1.63 11.00 35.00
2.93E+01 1.31 11.00 35.00
1.24E+01 37.04 11.00 35.00 10000 1000
1.31E+01 16.76 11.00 35.00
5.50E+00 17.44 11.00 35.00
5.50E+00 36.23 11.00 35.00
5.50E+00 19.95 11.00 35.00
5.50E+00 5.56 11.00 35.00
5.50E+00 12.61 11.00 35.00
5.50E+00 20.60 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.90E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-151
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
B CFS-L14-1314-T01-A 1 2.08E+03
B CFS-L14-1314-T02-A 1 1.74E+03
B CFS-L14-1314-T03-A 1 5.83E+02
B CFS-L14-1314-T04-A 1 2.58E+02
B CFS-L14-1314-T05-A 1 2.02E+02
B CFS-L14-1314-T06-A 1 1.16E+02
B CFS-L14-1314-T07-A 1 7.64E+01
B CFS-L14-1314-T08-A 1 5.71E+01
B CFS-L14-1314-T09-A 1 4.95E+01
B CFS-L14-1314-T01-B 1 2.09E+03
B CFS-L14-1314-T02-B 1 1.96E+03
B CFS-L14-1314-T03-B 1 6.03E+02
B CFS-L14-1314-T04-B 1 2.98E+02
B CFS-L14-1314-T05-B 1 2.26E+02
B CFS-L14-1314-T06-B 1 1.28E+02
B CFS-L14-1314-T07-B 1 8.58E+01
B CFS-L14-1314-T08-B 1 5.90E+01
B CFS-L14-1314-T09-B 1 4.73E+01
B CFS-L14-1314-T01-C 1 2.43E+03
B CFS-L14-1314-T02-C 1 1.56E+03
B CFS-L14-1314-T03-C 1 5.68E+02
B CFS-L14-1314-T04-C 1 2.72E+02
B CFS-L14-1314-T05-C 1 2.09E+02
B CFS-L14-1314-T06-C 1 1.17E+02
B CFS-L14-1314-T07-C 1 7.76E+01
B CFS-L14-1314-T08-C 1 5.53E+01
B CFS-L14-1314-T09-C 1 4.29E+01
B CFS-L14-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.08E+03 0.59 1.00 3.18
1.74E+03 0.31 1.00 3.18
5.83E+02 1.15 1.00 3.18 10000 1000
2.58E+02 2.42 1.00 3.18
2.02E+02 1.62 1.00 3.18
1.16E+02 1.92 1.00 3.18
7.64E+01 3.30 1.00 3.18
5.71E+01 2.71 1.00 3.18
4.95E+01 6.14 1.00 3.18
2.09E+03 1.17 1.00 3.18
1.96E+03 0.65 1.00 3.18
6.03E+02 0.49 1.00 3.18 10000 1000
2.98E+02 0.90 1.00 3.18
2.26E+02 0.12 1.00 3.18
1.28E+02 2.08 1.00 3.18
8.58E+01 2.51 1.00 3.18
5.90E+01 3.90 1.00 3.18
4.73E+01 2.57 1.00 3.18
2.43E+03 0.83 1.00 3.18
1.56E+03 0.57 1.00 3.18
5.68E+02 0.32 1.00 3.18 10000 1000
2.72E+02 0.48 1.00 3.18
2.09E+02 0.21 1.00 3.18
1.17E+02 2.13 1.00 3.18
7.76E+01 1.27 1.00 3.18
5.53E+01 1.12 1.00 3.18
4.29E+01 3.10 1.00 3.18
5.00E-01 6.24 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.46E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.49E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.46E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-152
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Ba CFS-L14-1314-T01-A 1 5.14E+01
Ba CFS-L14-1314-T02-A 1 5.79E+01
Ba CFS-L14-1314-T03-A 1 7.30E+01
Ba CFS-L14-1314-T04-A 1 8.37E+01
Ba CFS-L14-1314-T05-A 1 8.61E+01
Ba CFS-L14-1314-T06-A 1 8.98E+01
Ba CFS-L14-1314-T07-A 1 9.56E+01
Ba CFS-L14-1314-T08-A 1 1.03E+02
Ba CFS-L14-1314-T09-A 1 1.07E+02
Ba CFS-L14-1314-T01-B 1 5.16E+01
Ba CFS-L14-1314-T02-B 1 6.00E+01
Ba CFS-L14-1314-T03-B 1 7.67E+01
Ba CFS-L14-1314-T04-B 1 8.82E+01
Ba CFS-L14-1314-T05-B 1 8.73E+01
Ba CFS-L14-1314-T06-B 1 9.14E+01
Ba CFS-L14-1314-T07-B 1 9.97E+01
Ba CFS-L14-1314-T08-B 1 1.02E+02
Ba CFS-L14-1314-T09-B 1 1.10E+02
Ba CFS-L14-1314-T01-C 1 5.15E+01
Ba CFS-L14-1314-T02-C 1 5.40E+01
Ba CFS-L14-1314-T03-C 1 7.66E+01
Ba CFS-L14-1314-T04-C 1 9.61E+01
Ba CFS-L14-1314-T05-C 1 9.76E+01
Ba CFS-L14-1314-T06-C 1 9.61E+01
Ba CFS-L14-1314-T07-C 1 1.03E+02
Ba CFS-L14-1314-T08-C 1 1.11E+02
Ba CFS-L14-1314-T09-C 1 1.05E+02
Ba CFS-L14-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.14E+01 0.75 1.00 3.18
5.79E+01 0.62 1.00 3.18
7.30E+01 1.06 1.00 3.18 10000 1000
8.37E+01 1.38 1.00 3.18
8.61E+01 1.27 1.00 3.18
8.98E+01 1.17 1.00 3.18
9.56E+01 2.57 1.00 3.18
1.03E+02 0.91 1.00 3.18
1.07E+02 0.71 1.00 3.18
5.16E+01 0.34 1.00 3.18
6.00E+01 0.60 1.00 3.18
7.67E+01 0.61 1.00 3.18 10000 1000
8.82E+01 0.38 1.00 3.18
8.73E+01 2.50 1.00 3.18
9.14E+01 0.22 1.00 3.18
9.97E+01 1.96 1.00 3.18
1.02E+02 3.28 1.00 3.18
1.10E+02 1.39 1.00 3.18
5.15E+01 0.10 1.00 3.18
5.40E+01 0.42 1.00 3.18
7.66E+01 0.17 1.00 3.18 10000 1000
9.61E+01 1.53 1.00 3.18
9.76E+01 1.06 1.00 3.18
9.61E+01 2.14 1.00 3.18
1.03E+02 1.68 1.00 3.18
1.11E+02 1.51 1.00 3.18
1.05E+02 1.23 1.00 3.18
5.00E-01 28.87 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.15E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 . 1 3E+03 1 05% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-153
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Be CFS-L14-1314-T01-A 1 9.50E-01 U1/2
Be CFS-L14-1314-T02-A 1 9.50E-01 U1/2
Be CFS-L14-1314-T03-A 1 9.50E-01 U1/2
Be CFS-L14-1314-T04-A 1 9.50E-01 U1/2
Be CFS-L14-1314-T05-A 1 9.50E-01 U1/2
Be CFS-L14-1314-T06-A 1 9.50E-01 U1/2
Be CFS-L14-1314-T07-A 1 9.50E-01 U1/2
Be CFS-L14-1314-T08-A 1 9.50E-01 U1/2
Be CFS-L14-1314-T09-A 1 9.50E-01 U1/2
Be CFS-L14-1314-T01-B 1 9.50E-01 U1/2
Be CFS-L14-1314-T02-B 1 9.50E-01 U1/2
Be CFS-L14-1314-T03-B 1 9.50E-01 U1/2
Be CFS-L14-1314-T04-B 1 9.50E-01 U1/2
Be CFS-L14-1314-T05-B 1 9.50E-01 U1/2
Be CFS-L14-1314-T06-B 1 9.50E-01 U1/2
Be CFS-L14-1314-T07-B 1 9.50E-01 U1/2
Be CFS-L14-1314-T08-B 1 9.50E-01 U1/2
Be CFS-L14-1314-T09-B 1 9.50E-01 U1/2
Be CFS-L14-1314-T01-C 1 9.50E-01 U1/2
Be CFS-L14-1314-T02-C 1 9.50E-01 U1/2
Be CFS-L14-1314-T03-C 1 9.50E-01 U1/2
Be CFS-L14-1314-T04-C 1 9.50E-01 U1/2
Be CFS-L14-1314-T05-C 1 9.50E-01 U1/2
Be CFS-L14-1314-T06-C 1 9.50E-01 U1/2
Be CFS-L14-1314-T07-C 1 9.50E-01 U1/2
Be CFS-L14-1314-T08-C 1 9.50E-01 U1/2
Be CFS-L14-1314-T09-C 1 9.50E-01 U1/2
Be CFS-L14-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 10.11 1.90 6.00
9.50E-01 25.87 1.90 6.00
9.50E-01 16.84 1.90 6.00 10000 1000
9.50E-01 6.71 1.90 6.00
9.50E-01 10.86 1.90 6.00
9.50E-01 41.55 1.90 6.00
9.50E-01 32.07 1.90 6.00
9.50E-01 38.79 1.90 6.00
9.50E-01 27.75 1.90 6.00
9.50E-01 15.39 1.90 6.00
9.50E-01 20.45 1.90 6.00
9.50E-01 16.82 1.90 6.00 10000 1000
9.50E-01 10.70 1.90 6.00
9.50E-01 25.55 1.90 6.00
9.50E-01 16.64 1.90 6.00
9.50E-01 31.47 1.90 6.00
9.50E-01 44.35 1.90 6.00
9.50E-01 36.69 1.90 6.00
9.50E-01 6.12 1.90 6.00
9.50E-01 18.11 1.90 6.00
9.50E-01 8.64 1.90 6.00 10000 1000
9.50E-01 50.17 1.90 6.00
9.50E-01 8.97 1.90 6.00
9.50E-01 7.74 1.90 6.00
9.50E-01 48.13 1.90 6.00
9.50E-01 5.47 1.90 6.00
9.50E-01 48.17 1.90 6.00
9.50E-01 17.84 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.08E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-154
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Cd CFS-L14-1314-T01-A 1 1.64E+04
Cd CFS-L14-1314-T02-A 1 8.60E+03
Cd CFS-L14-1314-T03-A 1 7.51E+03
Cd CFS-L14-1314-T04-A 1 7.84E+03
Cd CFS-L14-1314-T05-A 1 8.13E+03
Cd CFS-L14-1314-T06-A 1 6.85E+03
Cd CFS-L14-1314-T07-A 1 5.43E+03
Cd CFS-L14-1314-T08-A 1 4.20E+03
Cd CFS-L14-1314-T09-A 1 3.18E+03
Cd CFS-L14-1314-T01-B 1 1.78E+04
Cd CFS-L14-1314-T02-B 1 9.31E+03
Cd CFS-L14-1314-T03-B 1 7.91E+03
Cd CFS-L14-1314-T04-B 1 8.52E+03
Cd CFS-L14-1314-T05-B 1 8.34E+03
Cd CFS-L14-1314-T06-B 1 7.24E+03
Cd CFS-L14-1314-T07-B 1 5.96E+03
Cd CFS-L14-1314-T08-B 1 4.51E+03
Cd CFS-L14-1314-T09-B 1 3.62E+03
Cd CFS-L14-1314-T01-C 1 1.55E+04
Cd CFS-L14-1314-T02-C 1 9.11E+03
Cd CFS-L14-1314-T03-C 1 7.53E+03
Cd CFS-L14-1314-T04-C 1 7.60E+03
Cd CFS-L14-1314-T05-C 1 7.91E+03
Cd CFS-L14-1314-T06-C 1 6.87E+03
Cd CFS-L14-1314-T07-C 1 5.68E+03
Cd CFS-L14-1314-T08-C 1 4.36E+03
Cd CFS-L14-1314-T09-C 1 3.42E+03
Cd CFS-L14-1314-B01-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.64E+04 0.80 2.20 7.00
8.60E+03 0.43 2.20 7.00
7.51E+03 0.88 2.20 7.00 10000 1000
7.84E+03 1.88 2.20 7.00
8.13E+03 1.39 2.20 7.00
6.85E+03 1.72 2.20 7.00
5.43E+03 2.99 2.20 7.00
4.20E+03 0.84 2.20 7.00
3.18E+03 0.44 2.20 7.00
1.78E+04 0.47 2.20 7.00
9.31 E+03 0.63 2.20 7.00
7.91E+03 0.24 2.20 7.00 10000 1000
8.52E+03 1.31 2.20 7.00
8.34E+03 0.66 2.20 7.00
7.24E+03 0.31 2.20 7.00
5.96E+03 1.72 2.20 7.00
4.51 E+03 2.82 2.20 7.00
3.62E+03 1.79 2.20 7.00
1.55E+04 1.48 2.20 7.00
9. 11 E+03 0.05 2.20 7.00
7.53E+03 0.53 2.20 7.00 10000 1000
7.60E+03 0.72 2.20 7.00
7.91E+03 0.15 2.20 7.00
6.87E+03 3.04 2.20 7.00
5.68E+03 1.40 2.20 7.00
4.36E+03 1.20 2.20 7.00
3.42E+03 1.22 2.20 7.00
1.10E+00 23.19 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.53E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.93E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.50E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-155
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Ca CFS-L14-1314-T01-A 1 4.92E+05
Ca CFS-L14-1314-T02-A 1 5.04E+05
Ca CFS-L14-1314-T03-A 1 5.64E+05
Ca CFS-L14-1314-T04-A 1 5.84E+05
Ca CFS-L14-1314-T05-A 1 6.02E+05
Ca CFS-L14-1314-T06-A 1 6.11E+05
Ca CFS-L14-1314-T07-A 1 6.05E+05
Ca CFS-L14-1314-T08-A 1 6.10E+05
Ca CFS-L14-1314-T09-A 1 5.91E+05
Ca CFS-L14-1314-T01-B 1 4.94E+05
Ca CFS-L14-1314-T02-B 1 5.02E+05
Ca CFS-L14-1314-T03-B 1 5.74E+05
Ca CFS-L14-1314-T04-B 1 6.10E+05
Ca CFS-L14-1314-T05-B 1 6.02E+05
Ca CFS-L14-1314-T06-B 1 6.07E+05
Ca CFS-L14-1314-T07-B 1 6.13E+05
Ca CFS-L14-1314-T08-B 1 6.02E+05
Ca CFS-L14-1314-T09-B 1 6.04E+05
Ca CFS-L14-1314-T01-C 1 4.76E+05
Ca CFS-L14-1314-T02-C 1 5.12E+05
Ca CFS-L14-1314-T03-C 1 5.66E+05
Ca CFS-L14-1314-T04-C 1 5.95E+05
Ca CFS-L14-1314-T05-C 1 6.04E+05
Ca CFS-L14-1314-T06-C 1 6.03E+05
Ca CFS-L14-1314-T07-C 1 6.05E+05
Ca CFS-L14-1314-T08-C 1 6.17E+05
Ca CFS-L14-1314-T09-C 1 6.13E+05
Ca CFS-L14-1314-B01-A 1 1.30E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.92E+05 0.72 2.60 8.30
5.04E+05 0.58 2.60 8.30
5.64E+05 0.98 2.60 8.30 10000 1000
5.84E+05 2.06 2.60 8.30
6.02E+05 2.07 2.60 8.30
6.11E+05 2.42 2.60 8.30
6.05E+05 2.83 2.60 8.30
6.10E+05 1.03 2.60 8.30
5.91 E+05 0.33 2.60 8.30
4.94E+05 0.49 2.60 8.30
5.02E+05 0.39 2.60 8.30
5.74E+05 0.92 2.60 8.30 10000 1000
6.10E+05 0.09 2.60 8.30
6.02E+05 0.73 2.60 8.30
6.07E+05 0.53 2.60 8.30
6.13E+05 1.93 2.60 8.30
6.02E+05 2.70 2.60 8.30
6.04E+05 1.55 2.60 8.30
4.76E+05 0.16 2.60 8.30
5.12E+05 0.08 2.60 8.30
5.66E+05 0.70 2.60 8.30 10000 1000
5.95E+05 0.55 2.60 8.30
6.04E+05 0.38 2.60 8.30
6.03E+05 2.62 2.60 8.30
6.05E+05 1.37 2.60 8.30
6.17E+05 1.15 2.60 8.30
6.13E+05 0.68 2.60 8.30
1.30E+00 15.66 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.65E+05 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.75E+05 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.67E+05 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-156
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Cr CFS-L14-1314-T01-A 1 6.00E-01 U1/2
Cr CFS-L14-1314-T02-A 1 6.00E-01 U1/2
Cr CFS-L14-1314-T03-A 1 6.00E-01 U1/2
Cr CFS-L14-1314-T04-A 1 6.00E-01 U1/2
Cr CFS-L14-1314-T05-A 1 6.00E-01 U1/2
Cr CFS-L14-1314-T06-A 1 6.00E-01 U1/2
Cr CFS-L14-1314-T07-A 1 6.00E-01 U1/2
Cr CFS-L14-1314-T08-A 1 6.00E-01 U1/2
Cr CFS-L14-1314-T09-A 1 6.00E-01 U1/2
Cr CFS-L14-1314-T01-B 1 6.00E-01 U1/2
Cr CFS-L14-1314-T02-B 1 6.00E-01 U1/2
Cr CFS-L14-1314-T03-B 1 6.00E-01 U1/2
Cr CFS-L14-1314-T04-B 1 6.00E-01 U1/2
Cr CFS-L14-1314-T05-B 1 6.00E-01 U1/2
Cr CFS-L14-1314-T06-B 1 6.00E-01 U1/2
Cr CFS-L14-1314-T07-B 1 6.00E-01 U1/2
Cr CFS-L14-1314-T08-B 1 6.00E-01 U1/2
Cr CFS-L14-1314-T09-B 1 6.00E-01 U1/2
Cr CFS-L14-1314-T01-C 1 6.00E-01 U1/2
Cr CFS-L14-1314-T02-C 1 6.00E-01 U1/2
Cr CFS-L14-1314-T03-C 1 6.00E-01 U1/2
Cr CFS-L14-1314-T04-C 1 6.00E-01 U1/2
Cr CFS-L14-1314-T05-C 1 6.00E-01 U1/2
Cr CFS-L14-1314-T06-C 1 6.00E-01 U1/2
Cr CFS-L14-1314-T07-C 1 6.00E-01 U1/2
Cr CFS-L14-1314-T08-C 1 6.00E-01 U1/2
Cr CFS-L14-1314-T09-C 1 6.00E-01 U1/2
Cr CFS-L14-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 36.20 1.20 3.82
6.00E-01 44.87 1.20 3.82
6.00E-01 45.28 1.20 3.82 10000 1000
6.00E-01 80.65 1.20 3.82
6.00E-01 21.78 1.20 3.82
6.00E-01 44.72 1.20 3.82
6.00E-01 32.69 1.20 3.82
6.00E-01 22.36 1.20 3.82
6.00E-01 32.15 1.20 3.82
6.00E-01 36.29 1.20 3.82
6.00E-01 35.08 1.20 3.82
6.00E-01 38.06 1.20 3.82 10000 1000
6.00E-01 40.55 1.20 3.82
6.00E-01 17.15 1.20 3.82
6.00E-01 103.89 1.20 3.82
6.00E-01 16.58 1.20 3.82
6.00E-01 59.16 1.20 3.82
6.00E-01 28.26 1.20 3.82
6.00E-01 40.81 1.20 3.82
6.00E-01 48.03 1.20 3.82
6.00E-01 19.11 1.20 3.82 10000 1000
6.00E-01 43.94 1.20 3.82
6.00E-01 66.51 1.20 3.82
6.00E-01 98.30 1.20 3.82
6.00E-01 56.94 1.20 3.82
6.00E-01 61.74 1.20 3.82
6.00E-01 42.77 1.20 3.82
6.00E-01 24.54 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.49E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.49E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.40E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-157
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Co CFS-L14-1314-T01-A 1 6.02E+02
Co CFS-L14-1314-T02-A 1 3.30E+02
Co CFS-L14-1314-T03-A 1 2.55E+02
Co CFS-L14-1314-T04-A 1 2.60E+02
Co CFS-L14-1314-T05-A 1 2.58E+02
Co CFS-L14-1314-T06-A 1 1.34E+02
Co CFS-L14-1314-T07-A 1 6.46E+01
Co CFS-L14-1314-T08-A 1 4.10E+01
Co CFS-L14-1314-T09-A 1 2.84E+01
Co CFS-L14-1314-T01-B 1 6.56E+02
Co CFS-L14-1314-T02-B 1 3.54E+02
Co CFS-L14-1314-T03-B 1 2.74E+02
Co CFS-L14-1314-T04-B 1 2.82E+02
Co CFS-L14-1314-T05-B 1 2.77E+02
Co CFS-L14-1314-T06-B 1 1.61E+02
Co CFS-L14-1314-T07-B 1 7.87E+01
Co CFS-L14-1314-T08-B 1 4.69E+01
Co CFS-L14-1314-T09-B 1 3.29E+01
Co CFS-L14-1314-T01-C 1 6.15E+02
Co CFS-L14-1314-T02-C 1 3.43E+02
Co CFS-L14-1314-T03-C 1 2.55E+02
Co CFS-L14-1314-T04-C 1 2.51E+02
Co CFS-L14-1314-T05-C 1 2.57E+02
Co CFS-L14-1314-T06-C 1 1.50E+02
Co CFS-L14-1314-T07-C 1 7.26E+01
Co CFS-L14-1314-T08-C 1 4.29E+01
Co CFS-L14-1314-T09-C 1 2.88E+01
Co CFS-L14-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.02E+02 0.98 1.80 5.72
3.30E+02 0.88 1.80 5.72
2.55E+02 1.27 1.80 5.72 10000 1000
2.60E+02 1.95 1.80 5.72
2.58E+02 2.26 1.80 5.72
1.34E+02 1.97 1.80 5.72
6.46E+01 4.03 1.80 5.72
4.10E+01 1.72 1.80 5.72
2.84E+01 2.21 1.80 5.72
6.56E+02 1.31 1.80 5.72
3.54E+02 0.97 1.80 5.72
2.74E+02 0.89 1.80 5.72 10000 1000
2.82E+02 0.87 1.80 5.72
2.77E+02 1.08 1.80 5.72
1.61E+02 0.67 1.80 5.72
7.87E+01 1.46 1.80 5.72
4.69E+01 2.69 1.80 5.72
3.29E+01 1.47 1.80 5.72
6.15E+02 1.54 1.80 5.72
3.43E+02 0.76 1.80 5.72
2.55E+02 0.45 1.80 5.72 10000 1000
2.51 E+02 0.55 1.80 5.72
2.57E+02 0.50 1.80 5.72
1.50E+02 2.05 1.80 5.72
7.26E+01 1.18 1.80 5.72
4.29E+01 1.21 1.80 5.72
2.88E+01 4.68 1.80 5.72
9.00E-01 15.56 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.32E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.37E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.34E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-158
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Cu CFS-L14-1314-T01-A 1 2.81E+03
Cu CFS-L14-1314-T02-A 1 1.86E+03
Cu CFS-L14-1314-T03-A 1 1.55E+03
Cu CFS-L14-1314-T04-A 1 1.60E+03
Cu CFS-L14-1314-T05-A 1 1.59E+03
Cu CFS-L14-1314-T06-A 1 1.36E+03
Cu CFS-L14-1314-T07-A 1 1.08E+03
Cu CFS-L14-1314-T08-A 1 8.67E+02
Cu CFS-L14-1314-T09-A 1 7.88E+02
Cu CFS-L14-1314-T01-B 1 3.60E+03
Cu CFS-L14-1314-T02-B 1 2.10E+03
Cu CFS-L14-1314-T03-B 1 1.70E+03
Cu CFS-L14-1314-T04-B 1 1.36E+03
Cu CFS-L14-1314-T05-B 1 1.75E+03
Cu CFS-L14-1314-T06-B 1 1.44E+03
Cu CFS-L14-1314-T07-B 1 1.20E+03
Cu CFS-L14-1314-T08-B 1 9.55E+02
Cu CFS-L14-1314-T09-B 1 7.81E+02
Cu CFS-L14-1314-T01-C 1 2.46E+03
Cu CFS-L14-1314-T02-C 1 1.89E+03
Cu CFS-L14-1314-T03-C 1 1.61E+03
Cu CFS-L14-1314-T04-C 1 1.59E+03
Cu CFS-L14-1314-T05-C 1 1.59E+03
Cu CFS-L14-1314-T06-C 1 1.30E+03
Cu CFS-L14-1314-T07-C 1 1.13E+03
Cu CFS-L14-1314-T08-C 1 9.13E+02
Cu CFS-L14-1314-T09-C 1 7.27E+02
Cu CFS-L14-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.81 E+03 0.92 3.70 11.80
1.86E+03 1.50 3.70 11.80
1.55E+03 2.29 3.70 11.80 10000 1000
1.60E+03 1.29 3.70 11.80
1.59E+03 1.48 3.70 11.80
1.36E+03 2.01 3.70 11.80
1.08E+03 2.90 3.70 11.80
8.67E+02 1.12 3.70 11.80
7.88E+02 1.62 3.70 11.80
3.60E+03 1.98 3.70 11.80
2.10E+03 0.57 3.70 11.80
1.70E+03 1.23 3.70 11.80 10000 1000
1.36E+03 2.20 3.70 11.80
1.75E+03 1.03 3.70 11.80
1.44E+03 0.66 3.70 11.80
1.20E+03 1.19 3.70 11.80
9.55E+02 2.18 3.70 11.80
7.81E+02 1.57 3.70 11.80
2.46E+03 0.59 3.70 11.80
1.89E+03 0.27 3.70 11.80
1.61E+03 0.87 3.70 11.80 10000 1000
1.59E+03 0.32 3.70 11.80
1.59E+03 1.74 3.70 11.80
1.30E+03 2.43 3.70 11.80
1.13E+03 1.68 3.70 11.80
9.13E+02 1.73 3.70 11.80
7.27E+02 0.52 3.70 11.80
1.85E+00 43.45 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.59E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.71E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.57E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-159
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Fe CFS-L14-1314-T01-A 1 3.44E+00 E
Fe CFS-L14-1314-T02-A 1 1.00E+00 U1/2
Fe CFS-L14-1314-T03-A 1 1.00E+00 U1/2
Fe CFS-L14-1314-T04-A 1 1.00E+00 U1/2
Fe CFS-L14-1314-T05-A 1 1.00E+00 U1/2
Fe CFS-L14-1314-T06-A 1 1.00E+00 U1/2
Fe CFS-L14-1314-T07-A 1 1.00E+00 U1/2
Fe CFS-L14-1314-T08-A 1 1.00E+00 U1/2
Fe CFS-L14-1314-T09-A 1 1.00E+00 U1/2
Fe CFS-L14-1314-T01-B 1 1.00E+00 U1/2
Fe CFS-L14-1314-T02-B 1 8.11E+00
Fe CFS-L14-1314-T03-B 1 1.00E+00 U1/2
Fe CFS-L14-1314-T04-B 1 1.00E+00 U1/2
Fe CFS-L14-1314-T05-B 1 1.00E+00 U1/2
Fe CFS-L14-1314-T06-B 1 1.00E+00 U1/2
Fe CFS-L14-1314-T07-B 1 1.00E+00 U1/2
Fe CFS-L14-1314-T08-B 1 1.00E+00 U1/2
Fe CFS-L14-1314-T09-B 1 1.00E+00 U1/2
Fe CFS-L14-1314-T01-C 1 1.00E+00 U1/2
Fe CFS-L14-1314-T02-C 1 1.00E+00 U1/2
Fe CFS-L14-1314-T03-C 1 1.00E+00 U1/2
Fe CFS-L14-1314-T04-C 1 1.00E+00 U1/2
Fe CFS-L14-1314-T05-C 1 1.00E+00 U1/2
Fe CFS-L14-1314-T06-C 1 1.00E+00 U1/2
Fe CFS-L14-1314-T07-C 1 1.00E+00 U1/2
Fe CFS-L14-1314-T08-C 1 1.00E+00 U1/2
Fe CFS-L14-1314-T09-C 1 1.00E+00 U1/2
Fe CFS-L14-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.44E+00 5.24 2.00 6.40
1.00E+00 1.63 2.00 6.40
1.00E+00 8.08 2.00 6.40 10000 1000
1.00E+00 2.93 2.00 6.40
1.00E+00 2.34 2.00 6.40
1.00E+00 8.60 2.00 6.40
1.00E+00 3.84 2.00 6.40
1.00E+00 3.85 2.00 6.40
1.00E+00 2.52 2.00 6.40
1.00E+00 3.28 2.00 6.40
8.11E+00 2.08 2.00 6.40
1.00E+00 8.40 2.00 6.40 10000 1000
1.00E+00 6.46 2.00 6.40
1.00E+00 4.13 2.00 6.40
1.00E+00 5.37 2.00 6.40
1.00E+00 1.22 2.00 6.40
1.00E+00 2.67 2.00 6.40
1.00E+00 11.60 2.00 6.40
1.00E+00 3.18 2.00 6.40
1.00E+00 5.75 2.00 6.40
1.00E+00 1.67 2.00 6.40 10000 1000
1.00E+00 1.93 2.00 6.40
1.00E+00 6.08 2.00 6.40
1.00E+00 2.99 2.00 6.40
1.00E+00 1.90 2.00 6.40
1.00E+00 7.62 2.00 6.40
1.00E+00 1.18 2.00 6.40
1.00E+00 1.31 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.27E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.24E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.20E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-160
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Pb CFS-L14-1314-T01-A 1 9.45E+02
Pb CFS-L14-1314-T02-A 1 8.83E+02
Pb CFS-L14-1314-T03-A 1 9.97E+02
Pb CFS-L14-1314-T04-A 1 1.08E+03
Pb CFS-L14-1314-T05-A 1 1.14E+03
Pb CFS-L14-1314-T06-A 1 1.07E+03
Pb CFS-L14-1314-T07-A 1 9.84E+02
Pb CFS-L14-1314-T08-A 1 9.44E+02
Pb CFS-L14-1314-T09-A 1 9.30E+02
Pb CFS-L14-1314-T01-B 1 9.40E+02
Pb CFS-L14-1314-T02-B 1 8.78E+02
Pb CFS-L14-1314-T03-B 1 1.07E+03
Pb CFS-L14-1314-T04-B 1 7.49E+02
Pb CFS-L14-1314-T05-B 1 1.19E+03
Pb CFS-L14-1314-T06-B 1 1.11E+03
Pb CFS-L14-1314-T07-B 1 1.05E+03
Pb CFS-L14-1314-T08-B 1 9.95E+02
Pb CFS-L14-1314-T09-B 1 9.43E+02
Pb CFS-L14-1314-T01-C 1 9.38E+02
Pb CFS-L14-1314-T02-C 1 8.69E+02
Pb CFS-L14-1314-T03-C 1 9.64E+02
Pb CFS-L14-1314-T04-C 1 1.05E+03
Pb CFS-L14-1314-T05-C 1 1.13E+03
Pb CFS-L14-1314-T06-C 1 1.05E+03
Pb CFS-L14-1314-T07-C 1 1.03E+03
Pb CFS-L14-1314-T08-C 1 9.90E+02
Pb CFS-L14-1314-T09-C 1 9.29E+02
Pb CFS-L14-1314-B01-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.45E+02 0.93 6.80 21.60
8.83E+02 0.56 6.80 21.60
9.97E+02 1.74 6.80 21.60 10000 1000
1.08E+03 1.88 6.80 21.60
1.14E+03 2.10 6.80 21.60
1.07E+03 1.97 6.80 21.60
9.84E+02 3.31 6.80 21.60
9.44E+02 0.59 6.80 21.60
9.30E+02 1.32 6.80 21.60
9.40E+02 0.47 6.80 21.60
8.78E+02 0.93 6.80 21.60
1.07E+03 0.29 6.80 21.60 10000 1000
7.49E+02 1.23 6.80 21.60
1.19E+03 0.71 6.80 21.60
1.11E+03 0.35 6.80 21.60
1.05E+03 1.58 6.80 21.60
9.95E+02 2.72 6.80 21.60
9.43E+02 1.39 6.80 21.60
9.38E+02 1.30 6.80 21.60
8.69E+02 0.87 6.80 21.60
9.64E+02 0.53 6.80 21.60 10000 1000
1.05E+03 0.68 6.80 21.60
1.13E+03 0.71 6.80 21.60
1.05E+03 3.05 6.80 21.60
1.03E+03 1.27 6.80 21.60
9.90E+02 0.71 6.80 21.60
9.29E+02 0.56 6.80 21.60
3.40E+00 38.66 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.98E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.05E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.88E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-161
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Li CFS-L14-1314-T01-A 1 4.04E+01
Li CFS-L14-1314-T02-A 1 7.17E+00
Li CFS-L14-1314-T03-A 1 1.20E+01
Li CFS-L14-1314-T04-A 1 1.24E+01
Li CFS-L14-1314-T05-A 1 1.08E+01
Li CFS-L14-1314-T06-A 1 1.14E+01
Li CFS-L14-1314-T07-A 1 1.41E+01
Li CFS-L14-1314-T08-A 1 1.08E+01
Li CFS-L14-1314-T09-A 1 1.15E+01
Li CFS-L14-1314-T01-B 1 4.12E+01
Li CFS-L14-1314-T02-B 1 9.38E+00
Li CFS-L14-1314-T03-B 1 1.09E+01
Li CFS-L14-1314-T04-B 1 1.02E+01
Li CFS-L14-1314-T05-B 1 1.03E+01
Li CFS-L14-1314-T06-B 1 1.09E+01
Li CFS-L14-1314-T07-B 1 1.13E+01
Li CFS-L14-1314-T08-B 1 1.33E+01
Li CFS-L14-1314-T09-B 1 1.18E+01
Li CFS-L14-1314-T01-C 1 4.28E+01
Li CFS-L14-1314-T02-C 1 6.33E+00
Li CFS-L14-1314-T03-C 1 1.17E+01
Li CFS-L14-1314-T04-C 1 1.18E+01
Li CFS-L14-1314-T05-C 1 1.07E+01
Li CFS-L14-1314-T06-C 1 1.11E+01
Li CFS-L14-1314-T07-C 1 1.08E+01
Li CFS-L14-1314-T08-C 1 9.84E+00
Li CFS-L14-1314-T09-C 1 1.60E+01
Li CFS-L14-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.04E+01 1.83 1.90 6.00
7.17E+00 4.77 1.90 6.00
1.20E+01 2.20 1.90 6.00 10000 1000
1.24E+01 1.31 1.90 6.00
1.08E+01 16.51 1.90 6.00
1.14E+01 1.60 1.90 6.00
1.41E+01 2.15 1.90 6.00
1.08E+01 3.47 1.90 6.00
1.15E+01 8.07 1.90 6.00
4.12E+01 4.88 1.90 6.00
9.38E+00 2.49 1.90 6.00
1.09E+01 1.28 1.90 6.00 10000 1000
1.02E+01 1.25 1.90 6.00
1.03E+01 14.05 1.90 6.00
1.09E+01 1.84 1.90 6.00
1.13E+01 6.00 1.90 6.00
1.33E+01 2.72 1.90 6.00
1.18E+01 1.81 1.90 6.00
4.28E+01 1.27 1.90 6.00
6.33E+00 2.25 1.90 6.00
1.17E+01 2.81 1.90 6.00 10000 1000
1.18E+01 1.98 1.90 6.00
1.07E+01 1.16 1.90 6.00
1.11E+01 1.87 1.90 6.00
1.08E+01 1.95 1.90 6.00
9.84E+00 1.67 1.90 6.00
1.60E+01 2.05 1.90 6.00
9.50E-01 31.57 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-162
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Mn CFS-L14-1314-T01-A 1 1.75E+04
Mn CFS-L14-1314-T02-A 1 9.44E+03
Mn CFS-L14-1314-T03-A 1 5.95E+03
Mn CFS-L14-1314-T04-A 1 4.26E+03
Mn CFS-L14-1314-T05-A 1 2.58E+03
Mn CFS-L14-1314-T06-A 1 9.44E+02
Mn CFS-L14-1314-T07-A 1 5.35E+02
Mn CFS-L14-1314-T08-A 1 3.87E+02
Mn CFS-L14-1314-T09-A 1 3.07E+02
Mn CFS-L14-1314-T01-B 1 1.85E+04
Mn CFS-L14-1314-T02-B 1 1.00E+04
Mn CFS-L14-1314-T03-B 1 6.23E+03
Mn CFS-L14-1314-T04-B 1 5.16E+03
Mn CFS-L14-1314-T05-B 1 3.38E+03
Mn CFS-L14-1314-T06-B 1 1.10E+03
Mn CFS-L14-1314-T07-B 1 6.43E+02
Mn CFS-L14-1314-T08-B 1 4.62E+02
Mn CFS-L14-1314-T09-B 1 3.66E+02
Mn CFS-L14-1314-T01-C 1 1.81E+04
Mn CFS-L14-1314-T02-C 1 9.35E+03
Mn CFS-L14-1314-T03-C 1 5.82E+03
Mn CFS-L14-1314-T04-C 1 4.54E+03
Mn CFS-L14-1314-T05-C 1 3.10E+03
Mn CFS-L14-1314-T06-C 1 1.04E+03
Mn CFS-L14-1314-T07-C 1 5.40E+02
Mn CFS-L14-1314-T08-C 1 3.68E+02
Mn CFS-L14-1314-T09-C 1 2.91E+02
Mn CFS-L14-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.75E+04 0.76 2.00 6.40
9.44E+03 0.66 2.00 6.40
5.95E+03 1.57 2.00 6.40 10000 1000
4.26E+03 1.93 2.00 6.40
2.58E+03 2.27 2.00 6.40
9.44E+02 0.49 2.00 6.40
5.35E+02 1.79 2.00 6.40
3.87E+02 2.18 2.00 6.40
3.07E+02 0.62 2.00 6.40
1.85E+04 1.49 2.00 6.40
1.00E+04 0.34 2.00 6.40
6.23E+03 0.61 2.00 6.40 10000 1000
5.16E+03 0.78 2.00 6.40
3.38E+03 0.53 2.00 6.40
1.10E+03 1.00 2.00 6.40
6.43E+02 0.50 2.00 6.40
4.62E+02 1.22 2.00 6.40
3.66E+02 0.63 2.00 6.40
1.81E+04 0.83 2.00 6.40
9.35E+03 0.88 2.00 6.40
5.82E+03 0.91 2.00 6.40 10000 1000
4.54E+03 0.55 2.00 6.40
3.10E+03 0.86 2.00 6.40
1.04E+03 1.61 2.00 6.40
5.40E+02 1.00 2.00 6.40
3.68E+02 0.10 2.00 6.40
2.91E+02 1.11 2.00 6.40
1.00E+00 18.46 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.90E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.16E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.82E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-163
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Mg CFS-L14-1314-T01-A 1 1.96E+06
Mg CFS-L14-1314-T02-A 1 6.91E+05
Mg CFS-L14-1314-T03-A 1 1.22E+05
Mg CFS-L14-1314-T04-A 1 2.80E+04
Mg CFS-L14-1314-T05-A 1 2.16E+04
Mg CFS-L14-1314-T06-A 1 1.36E+04
Mg CFS-L14-1314-T07-A 1 8.54E+03
Mg CFS-L14-1314-T08-A 1 5.19E+03
Mg CFS-L14-1314-T09-A 1 3.46E+03
Mg CFS-L14-1314-T01-B 1 2.02E+06
Mg CFS-L14-1314-T02-B 1 7.57E+05
Mg CFS-L14-1314-T03-B 1 1.23E+05
Mg CFS-L14-1314-T04-B 1 3.48E+04
Mg CFS-L14-1314-T05-B 1 2.40E+04
Mg CFS-L14-1314-T06-B 1 1.56E+04
Mg CFS-L14-1314-T07-B 1 9.92E+03
Mg CFS-L14-1314-T08-B 1 5.72E+03
Mg CFS-L14-1314-T09-B 1 3.82E+03
Mg CFS-L14-1314-T01-C 1 1.90E+06
Mg CFS-L14-1314-T02-C 1 6.46E+05
Mg CFS-L14-1314-T03-C 1 1.26E+05
Mg CFS-L14-1314-T04-C 1 3.15E+04
Mg CFS-L14-1314-T05-C 1 2.28E+04
Mg CFS-L14-1314-T06-C 1 1.51E+04
Mg CFS-L14-1314-T07-C 1 9.01E+03
Mg CFS-L14-1314-T08-C 1 5.27E+03
Mg CFS-L14-1314-T09-C 1 3.43E+03
Mg CFS-L14-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.96E+06 0.64 1.00 3.18
6.91E+05 0.78 1.00 3.18
1.22E+05 1.17 1.00 3.18 10000 1000
2.80E+04 0.79 1.00 3.18
2.16E+04 0.95 1.00 3.18
1.36E+04 2.27 1.00 3.18
8.54E+03 3.31 1.00 3.18
5.19E+03 1.24 1.00 3.18
3.46E+03 1.58 1.00 3.18
2.02E+06 1.87 1.00 3.18
7.57E+05 0.67 1.00 3.18
1.23E+05 0.57 1.00 3.18 10000 1000
3.48E+04 2.05 1.00 3.18
2.40E+04 0.46 1.00 3.18
1.56E+04 0.81 1.00 3.18
9.92E+03 2.45 1.00 3.18
5.72E+03 3.24 1.00 3.18
3.82E+03 1.90 1.00 3.18
1.90E+06 1.13 1.00 3.18
6.46E+05 0.58 1.00 3.18
1.26E+05 0.46 1.00 3.18 10000 1000
3.15E+04 1.06 1.00 3.18
2.28E+04 0.74 1.00 3.18
1.51E+04 2.03 1.00 3.18
9.01E+03 1.77 1.00 3.18
5.27E+03 0.95 1.00 3.18
3.43E+03 1.28 1.00 3.18
5.00E-01 39.51 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.23E+05 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.24E+05 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.27E+05 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-164
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Mo CFS-L14-1314-T01-A 1 2.56E+01
Mo CFS-L14-1314-T02-A 1 1.40E+01
Mo CFS-L14-1314-T03-A 1 7.74E+00
Mo CFS-L14-1314-T04-A 1 6.35E+00
Mo CFS-L14-1314-T05-A 1 5.56E+00
Mo CFS-L14-1314-T06-A 1 6.26E+00
Mo CFS-L14-1314-T07-A 1 6.02E+00
Mo CFS-L14-1314-T08-A 1 6.04E+00
Mo CFS-L14-1314-T09-A 1 6.14E+00
Mo CFS-L14-1314-T01-B 1 2.84E+01
Mo CFS-L14-1314-T02-B 1 1.50E+01
Mo CFS-L14-1314-T03-B 1 8.02E+00
Mo CFS-L14-1314-T04-B 1 9.95E+00
Mo CFS-L14-1314-T05-B 1 6.26E+00
Mo CFS-L14-1314-T06-B 1 5.48E+00
Mo CFS-L14-1314-T07-B 1 7.31E+00
Mo CFS-L14-1314-T08-B 1 7.43E+00
Mo CFS-L14-1314-T09-B 1 7.20E+00
Mo CFS-L14-1314-T01-C 1 2.60E+01
Mo CFS-L14-1314-T02-C 1 1.42E+01
Mo CFS-L14-1314-T03-C 1 7.87E+00
Mo CFS-L14-1314-T04-C 1 6.89E+00
Mo CFS-L14-1314-T05-C 1 5.84E+00
Mo CFS-L14-1314-T06-C 1 6.50E+00
Mo CFS-L14-1314-T07-C 1 6.12E+00
Mo CFS-L14-1314-T08-C 1 6.12E+00
Mo CFS-L14-1314-T09-C 1 6.70E+00
Mo CFS-L14-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.56E+01 7.89 1.20 3.82
1.40E+01 4.53 1.20 3.82
7.74E+00 1.83 1.20 3.82 10000 1000
6.35E+00 6.92 1.20 3.82
5.56E+00 1.68 1.20 3.82
6.26E+00 3.28 1.20 3.82
6.02E+00 1.62 1.20 3.82
6.04E+00 6.23 1.20 3.82
6.14E+00 7.46 1.20 3.82
2.84E+01 2.84 1.20 3.82
1.50E+01 8.04 1.20 3.82
8.02E+00 2.15 1.20 3.82 10000 1000
9.95E+00 1.85 1.20 3.82
6.26E+00 2.46 1.20 3.82
5.48E+00 2.67 1.20 3.82
7.31E+00 9.95 1.20 3.82
7.43E+00 4.88 1.20 3.82
7.20E+00 5.50 1.20 3.82
2.60E+01 9.86 1.20 3.82
1.42E+01 5.62 1.20 3.82
7.87E+00 10.69 1.20 3.82 10000 1000
6.89E+00 2.99 1.20 3.82
5.84E+00 1.87 1.20 3.82
6.50E+00 1.45 1.20 3.82
6.12E+00 1.85 1.20 3.82
6.12E+00 4.25 1.20 3.82
6.70E+00 6.51 1.20 3.82
6.00E-01 40.24 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.05E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-165
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Ni CFS-L14-1314-T01-A 1 8.66E+02
Ni CFS-L14-1314-T02-A 1 4.58E+02
Ni CFS-L14-1314-T03-A 1 3.66E+02
Ni CFS-L14-1314-T04-A 1 3.77E+02
Ni CFS-L14-1314-T05-A 1 3.91E+02
Ni CFS-L14-1314-T06-A 1 2.65E+02
Ni CFS-L14-1314-T07-A 1 1.60E+02
Ni CFS-L14-1314-T08-A 1 1.05E+02
Ni CFS-L14-1314-T09-A 1 7.24E+01
Ni CFS-L14-1314-T01-B 1 9.51E+02
Ni CFS-L14-1314-T02-B 1 4.97E+02
Ni CFS-L14-1314-T03-B 1 3.92E+02
Ni CFS-L14-1314-T04-B 1 4.16E+02
Ni CFS-L14-1314-T05-B 1 4.13E+02
Ni CFS-L14-1314-T06-B 1 3.02E+02
Ni CFS-L14-1314-T07-B 1 1.88E+02
Ni CFS-L14-1314-T08-B 1 1.16E+02
Ni CFS-L14-1314-T09-B 1 8.31E+01
Ni CFS-L14-1314-T01-C 1 8.51E+02
Ni CFS-L14-1314-T02-C 1 4.84E+02
Ni CFS-L14-1314-T03-C 1 3.70E+02
Ni CFS-L14-1314-T04-C 1 3.68E+02
Ni CFS-L14-1314-T05-C 1 3.84E+02
Ni CFS-L14-1314-T06-C 1 2.78E+02
Ni CFS-L14-1314-T07-C 1 1.75E+02
Ni CFS-L14-1314-T08-C 1 1.11E+02
Ni CFS-L14-1314-T09-C 1 7.44E+01
Ni CFS-L14-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.66E+02 0.51 1.80 5.70
4.58E+02 1.40 1.80 5.70
3.66E+02 1.18 1.80 5.70 10000 1000
3.77E+02 1.58 1.80 5.70
3.91 E+02 1.46 1.80 5.70
2.65E+02 1.97 1.80 5.70
1.60E+02 0.91 1.80 5.70
1.05E+02 1.91 1.80 5.70
7.24E+01 1.28 1.80 5.70
9.51 E+02 0.77 1.80 5.70
4.97E+02 0.84 1.80 5.70
3.92E+02 0.80 1.80 5.70 10000 1000
4.16E+02 1.01 1.80 5.70
4.13E+02 1.05 1.80 5.70
3.02E+02 0.32 1.80 5.70
1.88E+02 2.50 1.80 5.70
1.16E+02 2.89 1.80 5.70
8.31 E+01 1.66 1.80 5.70
8.51 E+02 0.90 1.80 5.70
4.84E+02 0.04 1.80 5.70
3.70E+02 0.39 1.80 5.70 10000 1000
3.68E+02 1.08 1.80 5.70
3.84E+02 0.18 1.80 5.70
2.78E+02 3.12 1.80 5.70
1.75E+02 1.24 1.80 5.70
1.11E+02 1.48 1.80 5.70
7.44E+01 2.76 1.80 5.70
9.00E-01 49.08 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.32E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.39E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.33E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-166
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
P CFS-L14-1314-T01-A 1 3.88E+01
P CFS-L14-1314-T02-A 1 1.55E+01
P CFS-L14-1314-T03-A 1 1.85E+00 U1/2
P CFS-L14-1314-T04-A 1 1.85E+00 U1/2
P CFS-L14-1314-T05-A 1 1.85E+00 U1/2
P CFS-L14-1314-T06-A 1 1.21E+01
P CFS-L14-1314-T07-A 1 1.85E+00 U1/2
P CFS-L14-1314-T08-A 1 1.85E+00 U1/2
P CFS-L14-1314-T09-A 1 1.85E+00 U1/2
P CFS-L14-1314-T01-B 1 4.25E+01
P CFS-L14-1314-T02-B 1 1.14E+01 E
P CFS-L14-1314-T03-B 1 8.73E+00 E
P CFS-L14-1314-T04-B 1 1.85E+00 U1/2
P CFS-L14-1314-T05-B 1 1.85E+00 U1/2
P CFS-L14-1314-T06-B 1 5.83E+00 E
P CFS-L14-1314-T07-B 1 8.99E+00 E
P CFS-L14-1314-T08-B 1 6.57E+00 E
P CFS-L14-1314-T09-B 1 1.85E+00 U1/2
P CFS-L14-1314-T01-C 1 3.53E+01
P CFS-L14-1314-T02-C 1 1.90E+01
P CFS-L14-1314-T03-C 1 4.53E+00 E
P CFS-L14-1314-T04-C 1 6.44E+00 E
P CFS-L14-1314-T05-C 1 8.42E+00 E
P CFS-L14-1314-T06-C 1 1.85E+00 U1/2
P CFS-L14-1314-T07-C 1 5.24E+00 E
P CFS-L14-1314-T08-C 1 1.85E+00 U1/2
P CFS-L14-1314-T09-C 1 1.85E+00 U1/2
P CFS-L14-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.88E+01 7.25 3.70 11.80
1.55E+01 1.76 3.70 11.80
1.85E+00 31.11 3.70 11.80 10000 1000
1.85E+00 49.21 3.70 11.80
1.85E+00 10.79 3.70 11.80
1.21E+01 9.07 3.70 11.80
1.85E+00 14.05 3.70 11.80
1.85E+00 45.27 3.70 11.80
1.85E+00 3.28 3.70 11.80
4.25E+01 2.29 3.70 11.80
1.14E+01 13.26 3.70 11.80
8.73E+00 4.72 3.70 11.80 10000 1000
1.85E+00 47.47 3.70 11.80
1.85E+00 63.95 3.70 11.80
5.83E+00 11.89 3.70 11.80
8.99E+00 12.91 3.70 11.80
6.57E+00 19.19 3.70 11.80
1.85E+00 10.63 3.70 11.80
3.53E+01 12.56 3.70 11.80
1.90E+01 7.57 3.70 11.80
4.53E+00 7.53 3.70 11.80 10000 1000
6.44E+00 13.70 3.70 11.80
8.42E+00 6.35 3.70 11.80
1.85E+00 20.80 3.70 11.80
5.24E+00 11.32 3.70 11.80
1.85E+00 52.37 3.70 11.80
1.85E+00 35.97 3.70 11.80
1.85E+00 22.56 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.87E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-167
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
K CFS-L14-1314-T01-A 1 1.11E+05
K CFS-L14-1314-T02-A 1 5.51E+04
K CFS-L14-1314-T03-A 1 2.65E+04
K CFS-L14-1314-T04-A 1 1.80E+04
K CFS-L14-1314-T05-A 1 1.28E+04
K CFS-L14-1314-T06-A 1 6.17E+03
K CFS-L14-1314-T07-A 1 3.56E+03
K CFS-L14-1314-T08-A 1 2.37E+03
K CFS-L14-1314-T09-A 1 1.87E+03
K CFS-L14-1314-T01-B 1 1.09E+05
K CFS-L14-1314-T02-B 1 5.88E+04
K CFS-L14-1314-T03-B 1 2.78E+04
K CFS-L14-1314-T04-B 1 2.12E+04
K CFS-L14-1314-T05-B 1 1.50E+04
K CFS-L14-1314-T06-B 1 7.05E+03
K CFS-L14-1314-T07-B 1 4.05E+03
K CFS-L14-1314-T08-B 1 2.59E+03
K CFS-L14-1314-T09-B 1 1.86E+03
K CFS-L14-1314-T01-C 1 1.19E+05
K CFS-L14-1314-T02-C 1 5.32E+04
K CFS-L14-1314-T03-C 1 2.57E+04
K CFS-L14-1314-T04-C 1 1.76E+04
K CFS-L14-1314-T05-C 1 1.30E+04
K CFS-L14-1314-T06-C 1 6.36E+03
K CFS-L14-1314-T07-C 1 3.81E+03
K CFS-L14-1314-T08-C 1 2.38E+03
K CFS-L14-1314-T09-C 1 1.73E+03
K CFS-L14-1314-B01-A 1 3.19E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.11E+05 0.38 1.60 5.09
5.51 E+04 0.42 1.60 5.09
2.65E+04 0.86 1.60 5.09 10000 1000
1.80E+04 2.03 1.60 5.09
1.28E+04 1.68 1.60 5.09
6.17E+03 1.77 1.60 5.09
3.56E+03 2.55 1.60 5.09
2.37E+03 1.02 1.60 5.09
1.87E+03 0.36 1.60 5.09
1.09E+05 0.79 1.60 5.09
5.88E+04 0.35 1.60 5.09
2.78E+04 0.56 1.60 5.09 10000 1000
2.12E+04 1.14 1.60 5.09
1.50E+04 0.93 1.60 5.09
7.05E+03 0.51 1.60 5.09
4.05E+03 1.45 1.60 5.09
2.59E+03 2.90 1.60 5.09
1.86E+03 1.80 1.60 5.09
1.19E+05 0.58 1.60 5.09
5.32E+04 0.37 1.60 5.09
2.57E+04 0.71 1.60 5.09 10000 1000
1.76E+04 0.56 1.60 5.09
1.30E+04 0.45 1.60 5.09
6.36E+03 3.08 1.60 5.09
3.81 E+03 1.34 1.60 5.09
2.38E+03 1.31 1.60 5.09
1.73E+03 1.43 1.60 5.09
3.19E+01 9.15 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.73E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.86E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.66E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-168
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L
Se CFS-L14-1314-T01-A 1 1.88E+03
Se CFS-L14-1314-T02-A 1 5.07E+02
Se CFS-L14-1314-T03-A 1 8.42E+01
Se CFS-L14-1314-T04-A 1 2.88E+01 E
Se CFS-L14-1314-T05-A 1 3.11E+01 E
Se CFS-L14-1314-T06-A 1 2.16E+01 E
Se CFS-L14-1314-T07-A 1 7.50E+00 U1/2
Se CFS-L14-1314-T08-A 1 7.50E+00 U1/2
Se CFS-L14-1314-T09-A 1 7.50E+00 U1/2
Se CFS-L14-1314-T01-B 1 1.98E+03
Se CFS-L14-1314-T02-B 1 5.63E+02
Se CFS-L14-1314-T03-B 1 8.24E+01
Se CFS-L14-1314-T04-B 1 3.48E+01 E
Se CFS-L14-1314-T05-B 1 1.81E+01 E
Se CFS-L14-1314-T06-B 1 2.59E+01 E
Se CFS-L14-1314-T07-B 1 7.50E+00 U1/2
Se CFS-L14-1314-T08-B 1 7.50E+00 U1/2
Se CFS-L14-1314-T09-B 1 7.50E+00 U1/2
Se CFS-L14-1314-T01-C 1 1.77E+03
Se CFS-L14-1314-T02-C 1 4.70E+02
Se CFS-L14-1314-T03-C 1 1.02E+02
Se CFS-L14-1314-T04-C 1 3.27E+01 E
Se CFS-L14-1314-T05-C 1 3.49E+01 E
Se CFS-L14-1314-T06-C 1 1.63E+01 E
Se CFS-L14-1314-T07-C 1 7.50E+00 U1/2
Se CFS-L14-1314-T08-C 1 7.50E+00 U1/2
Se CFS-L14-1314-T09-C 1 7.50E+00 U1/2
Se CFS-L14-1314-B01-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.88E+03 1.30 15.00 47.70
5.07E+02 1.10 15.00 47.70
8.42E+01 7.35 15.00 47.70 10000 1000
2.88E+01 15.51 15.00 47.70
3.11E+01 10.54 15.00 47.70
2.16E+01 25.05 15.00 47.70
7.50E+00 24.63 15.00 47.70
7.50E+00 20.97 15.00 47.70
7.50E+00 33.30 15.00 47.70
1.98E+03 0.54 15.00 47.70
5.63E+02 3.52 15.00 47.70
8.24E+01 2.78 15.00 47.70 10000 1000
3.48E+01 13.94 15.00 47.70
1.81E+01 36.49 15.00 47.70
2.59E+01 3.09 15.00 47.70
7.50E+00 26.11 15.00 47.70
7.50E+00 13.50 15.00 47.70
7.50E+00 11.34 15.00 47.70
1.77E+03 0.75 15.00 47.70
4.70E+02 1.57 15.00 47.70
1.02E+02 9.57 15.00 47.70 10000 1000
3.27E+01 8.44 15.00 47.70
3.49E+01 10.72 15.00 47.70
1.63E+01 24.02 15.00 47.70
7.50E+00 33.36 15.00 47.70
7.50E+00 21.25 15.00 47.70
7.50E+00 42.85 15.00 47.70
7.50E+00 10.72 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.09E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-169
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Si CFS-L14-1314-T01-A 1 8.54E+03
Si CFS-L14-1314-T02-A 1 6.65E+03
Si CFS-L14-1314-T03-A 1 6.44E+03
Si CFS-L14-1314-T04-A 1 6.32E+03
Si CFS-L14-1314-T05-A 1 6.33E+03
Si CFS-L14-1314-T06-A 1 5.77E+03
Si CFS-L14-1314-T07-A 1 5.20E+03
Si CFS-L14-1314-T08-A 1 4.72E+03
Si CFS-L14-1314-T09-A 1 4.26E+03
Si CFS-L14-1314-T01-B 1 9.00E+03
Si CFS-L14-1314-T02-B 1 7.07E+03
Si CFS-L14-1314-T03-B 1 6.86E+03
Si CFS-L14-1314-T04-B 1 6.97E+03
Si CFS-L14-1314-T05-B 1 6.77E+03
Si CFS-L14-1314-T06-B 1 6.01E+03
Si CFS-L14-1314-T07-B 1 5.63E+03
Si CFS-L14-1314-T08-B 1 5.04E+03
Si CFS-L14-1314-T09-B 1 4.63E+03
Si CFS-L14-1314-T01-C 1 8.69E+03
Si CFS-L14-1314-T02-C 1 7.20E+03
Si CFS-L14-1314-T03-C 1 6.62E+03
Si CFS-L14-1314-T04-C 1 6.50E+03
Si CFS-L14-1314-T05-C 1 6.50E+03
Si CFS-L14-1314-T06-C 1 5.83E+03
Si CFS-L14-1314-T07-C 1 5.35E+03
Si CFS-L14-1314-T08-C 1 4.90E+03
Si CFS-L14-1314-T09-C 1 4.45E+03
Si CFS-L14-1314-B01-A 1 1.18E+00 E
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.54E+03 0.51 1.10 3.50
6.65E+03 0.53 1.10 3.50
6.44E+03 1.80 1.10 3.50 10000 1000
6.32E+03 1.56 1.10 3.50
6.33E+03 2.46 1.10 3.50
5.77E+03 2.64 1.10 3.50
5.20E+03 2.90 1.10 3.50
4.72E+03 1.38 1.10 3.50
4.26E+03 0.30 1.10 3.50
9.00E+03 0.92 1.10 3.50
7.07E+03 0.35 1.10 3.50
6.86E+03 1.24 1.10 3.50 10000 1000
6.97E+03 1.87 1.10 3.50
6.77E+03 0.93 1.10 3.50
6.01 E+03 0.41 1.10 3.50
5.63E+03 1.41 1.10 3.50
5.04E+03 1.97 1.10 3.50
4.63E+03 2.28 1.10 3.50
8.69E+03 0.72 1.10 3.50
7.20E+03 0.16 1.10 3.50
6.62E+03 0.88 1.10 3.50 10000 1000
6.50E+03 0.47 1.10 3.50
6.50E+03 0.92 1.10 3.50
5.83E+03 3.85 1.10 3.50
5.35E+03 1.41 1.10 3.50
4.90E+03 0.60 1.10 3.50
4.45E+03 0.40 1.10 3.50
1.18E+00 7.83 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
7. 41 E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.82E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.67E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-170
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
Na CFS-L14-1314-T01-A 1 2.93E+05
Na CFS-L14-1314-T02-A 1 1.12E+05
Na CFS-L14-1314-T03-A 1 1.06E+04
Na CFS-L14-1314-T04-A 1 3.98E+03
Na CFS-L14-1314-T05-A 1 3.34E+03
Na CFS-L14-1314-T06-A 1 1.80E+03
Na CFS-L14-1314-T07-A 1 1.33E+03
Na CFS-L14-1314-T08-A 1 1.06E+03
Na CFS-L14-1314-T09-A 1 9.39E+02
Na CFS-L14-1314-T01-B 1 3.03E+05
Na CFS-L14-1314-T02-B 1 1.20E+05
Na CFS-L14-1314-T03-B 1 1.03E+04
Na CFS-L14-1314-T04-B 1 5.24E+03
Na CFS-L14-1314-T05-B 1 3.84E+03
Na CFS-L14-1314-T06-B 1 1.92E+03
Na CFS-L14-1314-T07-B 1 1.50E+03
Na CFS-L14-1314-T08-B 1 1.11E+03
Na CFS-L14-1314-T09-B 1 9.40E+02
Na CFS-L14-1314-T01-C 1 2.91E+05
Na CFS-L14-1314-T02-C 1 9.89E+04
Na CFS-L14-1314-T03-C 1 9.93E+03
Na CFS-L14-1314-T04-C 1 4.24E+03
Na CFS-L14-1314-T05-C 1 3.67E+03
Na CFS-L14-1314-T06-C 1 1.90E+03
Na CFS-L14-1314-T07-C 1 1.36E+03
Na CFS-L14-1314-T08-C 1 1.04E+03
Na CFS-L14-1314-T09-C 1 9.02E+02
Na CFS-L14-1314-B01-A 1 1.25E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.93E+05 0.58 2.50 8.00
1.12E+05 0.39 2.50 8.00
1.06E+04 0.74 2.50 8.00 10000 1000
3.98E+03 0.78 2.50 8.00
3.34E+03 0.78 2.50 8.00
1.80E+03 1.16 2.50 8.00
1.33E+03 0.87 2.50 8.00
1.06E+03 0.58 2.50 8.00
9.39E+02 0.53 2.50 8.00
3.03E+05 0.29 2.50 8.00
1.20E+05 0.21 2.50 8.00
1.03E+04 0.90 2.50 8.00 10000 1000
5.24E+03 1.22 2.50 8.00
3.84E+03 0.86 2.50 8.00
1.92E+03 1.50 2.50 8.00
1.50E+03 0.75 2.50 8.00
1.11E+03 1.00 2.50 8.00
9.40E+02 1.17 2.50 8.00
2.91E+05 0.23 2.50 8.00
9.89E+04 0.25 2.50 8.00
9.93E+03 0.44 2.50 8.00 10000 1000
4.24E+03 0.92 2.50 8.00
3.67E+03 1.50 2.50 8.00
1.90E+03 1.14 2.50 8.00
1.36E+03 1.48 2.50 8.00
1.04E+03 0.61 2.50 8.00
9.02E+02 2.26 2.50 8.00
1.25E+00 1.46 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.15E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+04 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-171
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Sr CFS-L14-1314-T01-A 1 4.77E+03
Sr CFS-L14-1314-T02-A 1 3.07E+03
Sr CFS-L14-1314-T03-A 1 3.02E+03
Sr CFS-L14-1314-T04-A 1 2.59E+03
Sr CFS-L14-1314-T05-A 1 2.13E+03
Sr CFS-L14-1314-T06-A 1 1.71E+03
Sr CFS-L14-1314-T07-A 1 1.47E+03
Sr CFS-L14-1314-T08-A 1 1.33E+03
Sr CFS-L14-1314-T09-A 1 1.26E+03
Sr CFS-L14-1314-T01-B 1 4.54E+03
Sr CFS-L14-1314-T02-B 1 3.08E+03
Sr CFS-L14-1314-T03-B 1 3.15E+03
Sr CFS-L14-1314-T04-B 1 3.04E+03
Sr CFS-L14-1314-T05-B 1 2.37E+03
Sr CFS-L14-1314-T06-B 1 1.77E+03
Sr CFS-L14-1314-T07-B 1 1.58E+03
Sr CFS-L14-1314-T08-B 1 1.38E+03
Sr CFS-L14-1314-T09-B 1 1.29E+03
Sr CFS-L14-1314-T01-C 1 4.62E+03
Sr CFS-L14-1314-T02-C 1 3.38E+03
Sr CFS-L14-1314-T03-C 1 3.15E+03
Sr CFS-L14-1314-T04-C 1 2.85E+03
Sr CFS-L14-1314-T05-C 1 2.28E+03
Sr CFS-L14-1314-T06-C 1 1.71E+03
Sr CFS-L14-1314-T07-C 1 1.50E+03
Sr CFS-L14-1314-T08-C 1 1.38E+03
Sr CFS-L14-1314-T09-C 1 1.27E+03
Sr CFS-L14-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.77E+03 0.44 1.00 3.18
3.07E+03 1.21 1.00 3.18
3.02E+03 1.96 1.00 3.18 10000 1000
2.59E+03 1.91 1.00 3.18
2.13E+03 2.28 1.00 3.18
1.71E+03 2.60 1.00 3.18
1.47E+03 2.82 1.00 3.18
1.33E+03 1.00 1.00 3.18
1.26E+03 0.54 1.00 3.18
4.54E+03 0.61 1.00 3.18
3.08E+03 0.54 1.00 3.18
3.15E+03 1.02 1.00 3.18 10000 1000
3.04E+03 1.37 1.00 3.18
2.37E+03 0.38 1.00 3.18
1.77E+03 0.50 1.00 3.18
1.58E+03 1.54 1.00 3.18
1.38E+03 1.73 1.00 3.18
1.29E+03 2.18 1.00 3.18
4.62E+03 0.86 1.00 3.18
3.38E+03 0.28 1.00 3.18
3.15E+03 0.38 1.00 3.18 10000 1000
2.85E+03 0.24 1.00 3.18
2.28E+03 0.91 1.00 3.18
1.71E+03 4.14 1.00 3.18
1.50E+03 1.47 1.00 3.18
1.38E+03 0.87 1.00 3.18
1.27E+03 0.46 1.00 3.18
5.00E-01 21.89 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.99E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.08E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.11E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-172
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
S CFS-L14-1314-T01-A 1 2.34E+06
S CFS-L14-1314-T02-A 1 1.26E+06
S CFS-L14-1314-T03-A 1 6.25E+05
S CFS-L14-1314-T04-A 1 5.15E+05
S CFS-L14-1314-T05-A 1 5.14E+05
S CFS-L14-1314-T06-A 1 5.02E+05
S CFS-L14-1314-T07-A 1 4.89E+05
S CFS-L14-1314-T08-A 1 4.84E+05
S CFS-L14-1314-T09-A 1 4.66E+05
S CFS-L14-1314-T01-B 1 2.38E+06
S CFS-L14-1314-T02-B 1 1.33E+06
S CFS-L14-1314-T03-B 1 6.39E+05
S CFS-L14-1314-T04-B 1 5.66E+05
S CFS-L14-1314-T05-B 1 5.24E+05
S CFS-L14-1314-T06-B 1 5.02E+05
S CFS-L14-1314-T07-B 1 4.98E+05
S CFS-L14-1314-T08-B 1 4.79E+05
S CFS-L14-1314-T09-B 1 4.74E+05
S CFS-L14-1314-T01-C 1 2.27E+06
S CFS-L14-1314-T02-C 1 1.21E+06
S CFS-L14-1314-T03-C 1 6.23E+05
S CFS-L14-1314-T04-C 1 5.19E+05
S CFS-L14-1314-T05-C 1 5.21E+05
S CFS-L14-1314-T06-C 1 5.01E+05
S CFS-L14-1314-T07-C 1 4.97E+05
S CFS-L14-1314-T08-C 1 4.94E+05
S CFS-L14-1314-T09-C 1 4.86E+05
S CFS-L14-1314-B01-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.34E+06 0.46 6.80 21.60
1.26E+06 0.56 6.80 21.60
6.25E+05 1.09 6.80 21.60 10000 1000
5.15E+05 2.26 6.80 21.60
5.14E+05 1.36 6.80 21.60
5.02E+05 2.10 6.80 21.60
4.89E+05 2.76 6.80 21.60
4.84E+05 0.69 6.80 21.60
4.66E+05 0.27 6.80 21.60
2.38E+06 0.59 6.80 21.60
1.33E+06 0.54 6.80 21.60
6.39E+05 0.44 6.80 21.60 10000 1000
5.66E+05 0.62 6.80 21.60
5.24E+05 0.78 6.80 21.60
5.02E+05 0.39 6.80 21.60
4.98E+05 1.84 6.80 21.60
4.79E+05 2.74 6.80 21.60
4.74E+05 1.76 6.80 21.60
2.27E+06 0.77 6.80 21.60
1.21E+06 0.82 6.80 21.60
6.23E+05 0.54 6.80 21.60 10000 1000
5.19E+05 0.37 6.80 21.60
5.21 E+05 0.51 6.80 21.60
5.01 E+05 2.95 6.80 21.60
4.97E+05 1.37 6.80 21.60
4.94E+05 1.67 6.80 21.60
4.86E+05 1.28 6.80 21.60
3.40E+00 8.75 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.26E+05 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.40E+05 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.24E+05 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-173
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Tl CFS-L14-1314-T01-A 1 1.93E+03
Tl CFS-L14-1314-T02-A 1 1.10E+03
Tl CFS-L14-1314-T03-A 1 6.39E+02
Tl CFS-L14-1314-T04-A 1 4.59E+02
Tl CFS-L14-1314-T05-A 1 3.81E+02
Tl CFS-L14-1314-T06-A 1 2.34E+02
Tl CFS-L14-1314-T07-A 1 1.63E+02
Tl CFS-L14-1314-T08-A 1 1.26E+02
Tl CFS-L14-1314-T09-A 1 1.09E+02
Tl CFS-L14-1314-T01-B 1 1.99E+03
Tl CFS-L14-1314-T02-B 1 1.19E+03
Tl CFS-L14-1314-T03-B 1 6.71E+02
Tl CFS-L14-1314-T04-B 1 5.42E+02
Tl CFS-L14-1314-T05-B 1 4.26E+02
Tl CFS-L14-1314-T06-B 1 2.65E+02
Tl CFS-L14-1314-T07-B 1 1.81E+02
Tl CFS-L14-1314-T08-B 1 1.37E+02
Tl CFS-L14-1314-T09-B 1 1.16E+02
Tl CFS-L14-1314-T01-C 1 2.02E+03
Tl CFS-L14-1314-T02-C 1 1.09E+03
Tl CFS-L14-1314-T03-C 1 6.33E+02
Tl CFS-L14-1314-T04-C 1 4.85E+02
Tl CFS-L14-1314-T05-C 1 4.01E+02
Tl CFS-L14-1314-T06-C 1 2.47E+02
Tl CFS-L14-1314-T07-C 1 1.75E+02
Tl CFS-L14-1314-T08-C 1 1.43E+02
Tl CFS-L14-1314-T09-C 1 1.10E+02
Tl CFS-L14-1314-B01-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.93E+03 0.28 4.60 14.60
1.10E+03 0.61 4.60 14.60
6.39E+02 0.80 4.60 14.60 10000 1000
4.59E+02 3.16 4.60 14.60
3.81E+02 2.86 4.60 14.60
2.34E+02 2.67 4.60 14.60
1.63E+02 5.43 4.60 14.60
1.26E+02 2.05 4.60 14.60
1.09E+02 1.64 4.60 14.60
1.99E+03 0.49 4.60 14.60
1.19E+03 1.01 4.60 14.60
6.71E+02 0.43 4.60 14.60 10000 1000
5.42E+02 1.28 4.60 14.60
4.26E+02 2.12 4.60 14.60
2.65E+02 1.87 4.60 14.60
1.81E+02 2.53 4.60 14.60
1.37E+02 4.83 4.60 14.60
1.16E+02 4.61 4.60 14.60
2.02E+03 0.42 4.60 14.60
1.09E+03 1.33 4.60 14.60
6.33E+02 1.45 4.60 14.60 10000 1000
4.85E+02 0.10 4.60 14.60
4.01E+02 0.55 4.60 14.60
2.47E+02 4.00 4.60 14.60
1.75E+02 1.58 4.60 14.60
1.43E+02 0.97 4.60 14.60
1.10E+02 4.64 4.60 14.60
2.30E+00 25.84 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.73E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.72E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.70E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-174
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ti CFS-L14-1314-T01-A 1 1.00E+00 U1/2
Ti CFS-L14-1314-T02-A 1 1.00E+00 U1/2
Ti CFS-L14-1314-T03-A 1 1.00E+00 U1/2
Ti CFS-L14-1314-T04-A 1 1.00E+00 U1/2
Ti CFS-L14-1314-T05-A 1 1.00E+00 U1/2
Ti CFS-L14-1314-T06-A 1 1.00E+00 U1/2
Ti CFS-L14-1314-T07-A 1 1.00E+00 U1/2
Ti CFS-L14-1314-T08-A 1 1.00E+00 U1/2
Ti CFS-L14-1314-T09-A 1 1.00E+00 U1/2
Ti CFS-L14-1314-T01-B 1 1.00E+00 U1/2
Ti CFS-L14-1314-T02-B 1 1.00E+00 U1/2
Ti CFS-L14-1314-T03-B 1 1.00E+00 U1/2
Ti CFS-L14-1314-T04-B 1 1.00E+00 U1/2
Ti CFS-L14-1314-T05-B 1 1.00E+00 U1/2
Ti CFS-L14-1314-T06-B 1 1.00E+00 U1/2
Ti CFS-L14-1314-T07-B 1 1.00E+00 U1/2
Ti CFS-L14-1314-T08-B 1 1.00E+00 U1/2
Ti CFS-L14-1314-T09-B 1 1.00E+00 U1/2
Ti CFS-L14-1314-T01-C 1 1.00E+00 U1/2
Ti CFS-L14-1314-T02-C 1 1.00E+00 U1/2
Ti CFS-L14-1314-T03-C 1 1.00E+00 U1/2
Ti CFS-L14-1314-T04-C 1 1.00E+00 U1/2
Ti CFS-L14-1314-T05-C 1 1.00E+00 U1/2
Ti CFS-L14-1314-T06-C 1 1.00E+00 U1/2
Ti CFS-L14-1314-T07-C 1 1.00E+00 U1/2
Ti CFS-L14-1314-T08-C 1 1.00E+00 U1/2
Ti CFS-L14-1314-T09-C 1 1.00E+00 U1/2
Ti CFS-L14-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 9.27 2.00 6.40
1.00E+00 2.63 2.00 6.40
1.00E+00 13.05 2.00 6.40 10000 1000
1.00E+00 10.00 2.00 6.40
1.00E+00 18.48 2.00 6.40
1.00E+00 17.21 2.00 6.40
1.00E+00 17.56 2.00 6.40
1.00E+00 15.30 2.00 6.40
1.00E+00 11.11 2.00 6.40
1.00E+00 15.46 2.00 6.40
1.00E+00 19.89 2.00 6.40
1.00E+00 8.88 2.00 6.40 10000 1000
1.00E+00 21.74 2.00 6.40
1.00E+00 5.41 2.00 6.40
1.00E+00 4.31 2.00 6.40
1.00E+00 27.64 2.00 6.40
1.00E+00 33.81 2.00 6.40
1.00E+00 14.69 2.00 6.40
1.00E+00 1.61 2.00 6.40
1.00E+00 6.65 2.00 6.40
1.00E+00 3.09 2.00 6.40 10000 1000
1.00E+00 21.74 2.00 6.40
1.00E+00 2.05 2.00 6.40
1.00E+00 17.88 2.00 6.40
1.00E+00 14.48 2.00 6.40
1.00E+00 15.60 2.00 6.40
1.00E+00 27.51 2.00 6.40
1.00E+00 25.88 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.39E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.24E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.29E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-175
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
V CFS-L14-1314-T01-A 1 2.64E+01
V CFS-L14-1314-T02-A 1 2.67E+01
V CFS-L14-1314-T03-A 1 3.00E+01
V CFS-L14-1314-T04-A 1 3.03E+01
V CFS-L14-1314-T05-A 1 3.21E+01
V CFS-L14-1314-T06-A 1 3.27E+01
V CFS-L14-1314-T07-A 1 3.23E+01
V CFS-L14-1314-T08-A 1 3.22E+01
V CFS-L14-1314-T09-A 1 3.56E+01
V CFS-L14-1314-T01-B 1 2.75E+01
V CFS-L14-1314-T02-B 1 2.56E+01
V CFS-L14-1314-T03-B 1 3.01E+01
V CFS-L14-1314-T04-B 1 3.32E+01
V CFS-L14-1314-T05-B 1 3.13E+01
V CFS-L14-1314-T06-B 1 3.16E+01
V CFS-L14-1314-T07-B 1 3.29E+01
V CFS-L14-1314-T08-B 1 3.17E+01
V CFS-L14-1314-T09-B 1 3.27E+01
V CFS-L14-1314-T01-C 1 2.49E+01
V CFS-L14-1314-T02-C 1 2.68E+01
V CFS-L14-1314-T03-C 1 2.99E+01
V CFS-L14-1314-T04-C 1 3.25E+01
V CFS-L14-1314-T05-C 1 3.28E+01
V CFS-L14-1314-T06-C 1 3.22E+01
V CFS-L14-1314-T07-C 1 3.31E+01
V CFS-L14-1314-T08-C 1 3.31E+01
V CFS-L14-1314-T09-C 1 3.28E+01
V CFS-L14-1314-B01-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.64E+01 5.12 1.50 4.77
2.67E+01 4.49 1.50 4.77
3.00E+01 3.92 1.50 4.77 10000 1000
3.03E+01 0.95 1.50 4.77
3.21E+01 14.20 1.50 4.77
3.27E+01 4.39 1.50 4.77
3.23E+01 3.23 1.50 4.77
3.22E+01 3.15 1.50 4.77
3.56E+01 2.50 1.50 4.77
2.75E+01 1.13 1.50 4.77
2.56E+01 2.27 1.50 4.77
3.01E+01 1.68 1.50 4.77 10000 1000
3.32E+01 0.90 1.50 4.77
3.13E+01 4.25 1.50 4.77
3.16E+01 2.65 1.50 4.77
3.29E+01 2.66 1.50 4.77
3.17E+01 3.77 1.50 4.77
3.27E+01 3.94 1.50 4.77
2.49E+01 5.34 1.50 4.77
2.68E+01 7.40 1.50 4.77
2.99E+01 2.24 1.50 4.77 10000 1000
3.25E+01 2.67 1.50 4.77
3.28E+01 1.64 1.50 4.77
3.22E+01 2.97 1.50 4.77
3.31 E+01 1.77 1.50 4.77
3.31 E+01 4.51 1.50 4.77
3.28E+01 3.10 1.50 4.77
7.50E-01 12.62 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.05E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-176
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Zn CFS-L14-1314-T01-A 1 6.71E+04
Zn CFS-L14-1314-T02-A 1 3.92E+04
Zn CFS-L14-1314-T03-A 1 3.45E+04
Zn CFS-L14-1314-T04-A 1 3.66E+04
Zn CFS-L14-1314-T05-A 1 3.81E+04
Zn CFS-L14-1314-T06-A 1 3.16E+04
Zn CFS-L14-1314-T07-A 1 2.42E+04
Zn CFS-L14-1314-T08-A 1 1.83E+04
Zn CFS-L14-1314-T09-A 1 1.37E+04
Zn CFS-L14-1314-T01-B 1 7.30E+04
Zn CFS-L14-1314-T02-B 1 4.31E+04
Zn CFS-L14-1314-T03-B 1 3.75E+04
Zn CFS-L14-1314-T04-B 1 3.98E+04
Zn CFS-L14-1314-T05-B 1 3.97E+04
Zn CFS-L14-1314-T06-B 1 3.39E+04
Zn CFS-L14-1314-T07-B 1 2.68E+04
Zn CFS-L14-1314-T08-B 1 1.97E+04
Zn CFS-L14-1314-T09-B 1 1.55E+04
Zn CFS-L14-1314-T01-C 1 6.33E+04
Zn CFS-L14-1314-T02-C 1 4.22E+04
Zn CFS-L14-1314-T03-C 1 3.54E+04
Zn CFS-L14-1314-T04-C 1 3.57E+04
Zn CFS-L14-1314-T05-C 1 3.67E+04
Zn CFS-L14-1314-T06-C 1 3.12E+04
Zn CFS-L14-1314-T07-C 1 2.48E+04
Zn CFS-L14-1314-T08-C 1 1.88E+04
Zn CFS-L14-1314-T09-C 1 1.49E+04
Zn CFS-L14-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.71E+04 0.42 1.00 3.18
3.92E+04 0.58 1.00 3.18
3.45E+04 0.78 1.00 3.18 10000 1000
3.66E+04 2.15 1.00 3.18
3.81E+04 2.22 1.00 3.18
3.16E+04 2.64 1.00 3.18
2.42E+04 2.79 1.00 3.18
1.83E+04 0.85 1.00 3.18
1.37E+04 0.44 1.00 3.18
7.30E+04 1.63 1.00 3.18
4.31E+04 1.28 1.00 3.18
3.75E+04 0.04 1.00 3.18 10000 1000
3.98E+04 0.94 1.00 3.18
3.97E+04 0.36 1.00 3.18
3.39E+04 0.44 1.00 3.18
2.68E+04 1.92 1.00 3.18
1.97E+04 2.39 1.00 3.18
1.55E+04 1.79 1.00 3.18
6.33E+04 1.32 1.00 3.18
4.22E+04 0.30 1.00 3.18
3.54E+04 1.27 1.00 3.18 10000 1000
3.57E+04 0.83 1.00 3.18
3.67E+04 0.57 1.00 3.18
3.12E+04 3.79 1.00 3.18
2.48E+04 1.71 1.00 3.18
1.88E+04 1.45 1.00 3.18
1.49E+04 1.94 1.00 3.18
5.00E-01 9.17 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.54E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.83E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.63E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/2/12 2:35 PM EPA Interlab L14 1314 CFS
1/2/12 2:36 PM EPA Interlab L14 1314 CFS
1/2/12 2:38 PM EPA Interlab L14 1314 CFS
1/2/12 2:39 PM EPA Interlab L14 1314 CFS
1/2/12 2:41 PM EPA Interlab L14 1314 CFS
1/2/12 2:43 PM EPA Interlab L14 1314 CFS
1/2/12 2:44 PM EPA Interlab L14 1314 CFS
1/2/12 2:46 PM EPA Interlab L14 1314 CFS
1/2/12 2:50 PM EPA Interlab L14 1314 CFS
1/2/12 2:59 PM EPA Interlab L14 1314 CFS
1/2/12 3:00 PM EPA Interlab L14 1314 CFS
1/2/12 3:02 PM EPA Interlab L14 1314 CFS
1/2/12 3:04 PM EPA Interlab L14 1314 CFS
1/2/12 3:05 PM EPA Interlab L14 1314 CFS
1/2/12 3:07 PM EPA Interlab L14 1314 CFS
1/2/12 3:09 PM EPA Interlab L14 1314 CFS
1/2/12 3:10 PM EPA Interlab L14 1314 CFS
1/2/12 3:12 PM EPA Interlab L14 1314 CFS
1/2/12 3:14 PM EPA Interlab L14 1314 CFS
1/2/12 3:15 PM EPA Interlab L14 1314 CFS
1/2/12 3:17 PM EPA Interlab L14 1314 CFS
1/2/12 3:19 PM EPA Interlab L14 1314 CFS
1/2/12 3:20 PM EPA Interlab L14 1314 CFS
1/2/12 3:22 PM EPA Interlab L14 1314 CFS
1/2/12 3:23 PM EPA Interlab L14 1314 CFS
1/2/12 3:25 PM EPA Interlab L14 1314 CFS
1/2/12 3:27 PM EPA Interlab L14 1314 CFS
1/2/12 2:30 PM EPA Interlab L14 1314 CFS
1-177
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1314:
Element
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Dilution Sample
Sample ID Factor Cone. Qualifier
I I ug/L I
CFS-LRef-1314-T01-A 1 5.19E+01
CFS-LRef-1314-T02-A 1 4.70E+01
CFS-LRef-1314-T03-A 1 4.13E+01
CFS-LRef-1314-T04-A 1 4.45E+01
CFS-LRef-1314-T05-A 1 3.84E+01
CFS-LRef-1314-T06-A 1 3.54E+01
CFS-LRef-1314-T07-A 1 3.76E+01
CFS-LRef-1314-T08-A 1 3.65E+01
CFS-LRef-1314-T09-A 1 3.53E+01
CFS-LRef-1314-T01-B 1 4.92E+01
CFS-LRef-1314-T02-B 1 4.66E+01
CFS-LRef-1314-T03-B 1 4.07E+01
CFS-LRef-1314-T04-B 1 4.33E+01
CFS-LRef-1314-T05-B 1 3.70E+01
CFS-LRef-1314-T06-B 1 3.55E+01
CFS-LRef-1314-T07-B 1 3.79E+01
CFS-LRef-1314-T08-B 1 3.58E+01
CFS-LRef-1314-T09-B 1 3.52E+01
CFS-LRef-1314-T01-C 1 5.04E+01
CFS-LRef-1314-T02-C 1 4.62E+01
CFS-LRef-1314-T03-C 1 4.40E+01
CFS-LRef-1314-T04-C 1 4.46E+01
CFS-LRef-1314-T05-C 1 3.88E+01
CFS-LRef-1314-T06-C 1 3.49E+01
CFS-LRef-1314-T07-C 1 3.67E+01
CFS-LRef-1314-T08-C 1 3.58E+01
CFS-LRef-1314-T09-C 1 3.55E+01
CFS-LRef-1314-B01-A 1 5.00E-01 U1/2
ICP-OES
Cone. RSD MDL
ug/L % ug/L
5.19E+01 3.08 1.00
4.70E+01 5.14 1.00
4.13E+01 5.63 1.00
4.45E+01 5.43 1.00
3.84E+01 2.87 1.00
3.54E+01 0.89 1.00
3.76E+01 8.35 1.00
3.65E+01 3.91 1.00
3.53E+01 5.73 1.00
4.92E+01 2.10 1.00
4.66E+01 7.96 1.00
4.07E+01 6.70 1.00
4.33E+01 6.75 1.00
3.70E+01 2.84 1.00
3.55E+01 3.81 1.00
3.79E+01 4.09 1.00
3.58E+01 4.30 1.00
3.52E+01 5.18 1.00
5.04E+01 2.55 1.00
4.62E+01 2.39 1.00
4.40E+01 1.76 1.00
4.46E+01 4.39 1.00
3.88E+01 6.26 1.00
3.49E+01 1.59 1.00
3.67E+01 3.96 1.00
3.58E+01 7.10 1.00
3.55E+01 4.10 1.00
5.00E-01 11.88 1.00
Spike Sol'n
ML Cone. Volume
ug/L ug/L ML
3.18
3.18
3.18 10000 1000
3.18
3.18
3.18
3.18
3.18
3.18
3.18
3.18
3.18 10000 1000
3.18
3.18
3.18
3.18
3.18
3.18
3.18
3.18
3.18 10000 1000
3.18
3.18
3.18
3.18
3.18
3.18
3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/12 2:26 PM EPA Interlab LRef 1314 CFS
3/7/12 2:28 PM EPA Interlab LRef 1314 CFS
3/7/12 2:30 PM EPA Interlab LRef 1314 CFS
3/7/122:31 PM EPA Interlab LRef 1314 CFS
3/7/12 2:33 PM EPA Interlab LRef 1314 CFS
3/7/12 2:35 PM EPA Interlab LRef 1314 CFS
3/7/12 2:36 PM EPA Interlab LRef 1314 CFS
3/7/12 2:38 PM EPA Interlab LRef 1314 CFS
3/7/12 2:40 PM EPA Interlab LRef 1314 CFS
3/7/122:41 PM EPA Interlab LRef 1314 CFS
3/7/12 2:43 PM EPA Interlab LRef 1314 CFS
3/7/12 2:45 PM EPA Interlab LRef 1314 CFS
3/7/12 2:46 PM EPA Interlab LRef 1314 CFS
3/7/12 2:48 PM EPA Interlab LRef 1314 CFS
3/7/12 2:50 PM EPA Interlab LRef 1314 CFS
3/7/122:51 PM EPA Interlab LRef 1314 CFS
3/7/12 2:53 PM EPA Interlab LRef 1314 CFS
3/7/12 2:55 PM EPA Interlab LRef 1314 CFS
3/7/12 3:00 PM EPA Interlab LRef 1314 CFS
3/7/123:01 PM EPA Interlab LRef 1314 CFS
3/7/12 3:03 PM EPA Interlab LRef 1314 CFS
3/7/12 3:05 PM EPA Interlab LRef 1314 CFS
3/7/12 3:06 PM EPA Interlab LRef 1314 CFS
3/7/12 3:08 PM EPA Interlab LRef 1314 CFS
3/7/12 3:09 PM EPA Interlab LRef 1314 CFS
3/7/123:11 PM EPA Interlab LRef 1314 CFS
3/7/12 3:13 PM EPA Interlab LRef 1314 CFS
3/7/12 2:25 PM EPA Interlab LRef 1314 CFS
1-178
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Sb CFS-LRef-1314-T01-A 1 7.13E+01
Sb CFS-LRef-1314-T02-A 1 4.21E+01
Sb CFS-LRef-1314-T03-A 1 3.19E+01
Sb CFS-LRef-1314-T04-A 1 2.94E+01
Sb CFS-LRef-1314-T05-A 1 2.86E+01
Sb CFS-LRef-1314-T06-A 1 3.33E+01
Sb CFS-LRef-1314-T07-A 1 2.14E+01 E
Sb CFS-LRef-1314-T08-A 1 2.34E+01 E
Sb CFS-LRef-1314-T09-A 1 1.85E+01 E
Sb CFS-LRef-1314-T01-B 1 6.97E+01
Sb CFS-LRef-1314-T02-B 1 4.17E+01
Sb CFS-LRef-1314-T03-B 1 3.44E+01
Sb CFS-LRef-1314-T04-B 1 3.41E+01
Sb CFS-LRef-1314-T05-B 1 3.28E+01
Sb CFS-LRef-1314-T06-B 1 2.73E+01
Sb CFS-LRef-1314-T07-B 1 2.50E+01
Sb CFS-LRef-1314-T08-B 1 1.93E+01 E
Sb CFS-LRef-1314-T09-B 1 1.72E+01 E
Sb CFS-LRef-1314-T01-C 1 7.11E+01
Sb CFS-LRef-1314-T02-C 1 4.17E+01
Sb CFS-LRef-1314-T03-C 1 3.35E+01
Sb CFS-LRef-1314-T04-C 1 2.62E+01
Sb CFS-LRef-1314-T05-C 1 3.12E+01
Sb CFS-LRef-1314-T06-C 1 3.00E+01
Sb CFS-LRef-1314-T07-C 1 2.51E+01
Sb CFS-LRef-1314-T08-C 1 1.84E+01 E
Sb CFS-LRef-1314-T09-C 1 1.56E+01 E
Sb CFS-LRef-1314-B01-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.13E+01 1.21 7.50 23.90
4.21 E+01 4.04 7.50 23.90
3.19E+01 11.84 7.50 23.90 10000 1000
2.94E+01 3.22 7.50 23.90
2.86E+01 1.28 7.50 23.90
3.33E+01 2.27 7.50 23.90
2.14E+01 30.51 7.50 23.90
2.34E+01 31.67 7.50 23.90
1.85E+01 17.36 7.50 23.90
6.97E+01 2.87 7.50 23.90
4.17E+01 2.53 7.50 23.90
3.44E+01 1.14 7.50 23.90 10000 1000
3.41 E+01 3.75 7.50 23.90
3.28E+01 12.57 7.50 23.90
2.73E+01 4.39 7.50 23.90
2.50E+01 6.66 7.50 23.90
1.93E+01 17.16 7.50 23.90
1.72E+01 4.20 7.50 23.90
7.11E+01 9.30 7.50 23.90
4.17E+01 3.18 7.50 23.90
3.35E+01 7.51 7.50 23.90 10000 1000
2.62E+01 2.96 7.50 23.90
3.12E+01 1.24 7.50 23.90
3.00E+01 9.75 7.50 23.90
2.51 E+01 1.62 7.50 23.90
1.84E+01 12.42 7.50 23.90
1.56E+01 4.14 7.50 23.90
3.75E+00 56.65 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19 AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10 PM EPA Interlab LRef 1314 CFS
1-179
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
As CFS-LRef-1314-T01-A 1 4.10E+01
As CFS-LRef-1314-T02-A 1 3.19E+01 E
As CFS-LRef-1314-T03-A 1 2.04E+01 E
As CFS-LRef-1314-T04-A 1 1.99E+01 E
As CFS-LRef-1314-T05-A 1 1.87E+01 E
As CFS-LRef-1314-T06-A 1 2.17E+01 E
As CFS-LRef-1314-T07-A 1 2.06E+01 E
As CFS-LRef-1314-T08-A 1 1.88E+01 E
As CFS-LRef-1314-T09-A 1 1.43E+01 E
As CFS-LRef-1314-T01-B 1 4.04E+01
As CFS-LRef-1314-T02-B 1 3.17E+01 E
As CFS-LRef-1314-T03-B 1 1.95E+01 E
As CFS-LRef-1314-T04-B 1 2.02E+01 E
As CFS-LRef-1314-T05-B 1 1.79E+01 E
As CFS-LRef-1314-T06-B 1 1.61E+01 E
As CFS-LRef-1314-T07-B 1 2.29E+01 E
As CFS-LRef-1314-T08-B 1 1.93E+01 E
As CFS-LRef-1314-T09-B 1 1.55E+01 E
As CFS-LRef-1314-T01-C 1 4.15E+01
As CFS-LRef-1314-T02-C 1 3.37E+01 E
As CFS-LRef-1314-T03-C 1 2.13E+01 E
As CFS-LRef-1314-T04-C 1 1.50E+01 E
As CFS-LRef-1314-T05-C 1 2.02E+01 E
As CFS-LRef-1314-T06-C 1 1.94E+01 E
As CFS-LRef-1314-T07-C 1 1.71E+01 E
As CFS-LRef-1314-T08-C 1 1.68E+01 E
As CFS-LRef-1314-T09-C 1 1.34E+01 E
As CFS-LRef-1314-B01-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.10E+01 2.75 11.00 35.00
3.19E+01 5.11 11.00 35.00
2.04E+01 32.39 11.00 35.00 10000 1000
1.99E+01 23.27 11.00 35.00
1.87E+01 15.33 11.00 35.00
2.17E+01 13.31 11.00 35.00
2.06E+01 23.80 11.00 35.00
1.88E+01 25.71 11.00 35.00
1.43E+01 3.11 11.00 35.00
4.04E+01 2.88 11.00 35.00
3.17E+01 21.87 11.00 35.00
1.95E+01 13.77 11.00 35.00 10000 1000
2.02E+01 21.02 11.00 35.00
1.79E+01 21.92 11.00 35.00
1.61E+01 7.33 11.00 35.00
2.29E+01 15.10 11.00 35.00
1.93E+01 32.95 11.00 35.00
1.55E+01 9.77 11.00 35.00
4.15E+01 9.65 11.00 35.00
3.37E+01 16.88 11.00 35.00
2.13E+01 5.24 11.00 35.00 10000 1000
1.50E+01 24.68 11.00 35.00
2.02E+01 22.77 11.00 35.00
1.94E+01 7.09 11.00 35.00
1.71E+01 26.11 11.00 35.00
1.68E+01 16.99 11.00 35.00
1.34E+01 18.58 11.00 35.00
5.50E+00 52.27 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.03E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19 AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/1 1 1 1 :26 AM EPA Interlab LRef 1 31 4 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10 PM EPA Interlab LRef 1314 CFS
1-180
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
B CFS-LRef-1314-T01-A 1 2.20E+03
B CFS-LRef-1314-T02-A 1 1.42E+03
B CFS-LRef-1314-T03-A 1 4.68E+02
B CFS-LRef-1314-T04-A 1 2.46E+02
B CFS-LRef-1314-T05-A 1 1.78E+02
B CFS-LRef-1314-T06-A 1 1.07E+02
B CFS-LRef-1314-T07-A 1 7.45E+01
B CFS-LRef-1314-T08-A 1 5.17E+01
B CFS-LRef-1314-T09-A 1 3.53E+01
B CFS-LRef-1314-T01-B 1 2.00E+03
B CFS-LRef-1314-T02-B 1 1.23E+03
B CFS-LRef-1314-T03-B 1 4.79E+02
B CFS-LRef-1314-T04-B 1 2.45E+02
B CFS-LRef-1314-T05-B 1 1.50E+02
B CFS-LRef-1314-T06-B 1 1.03E+02
B CFS-LRef-1314-T07-B 1 7.44E+01
B CFS-LRef-1314-T08-B 1 5.12E+01
B CFS-LRef-1314-T09-B 1 4.26E+01
B CFS-LRef-1314-T01-C 1 2.19E+03
B CFS-LRef-1314-T02-C 1 1.38E+03
B CFS-LRef-1314-T03-C 1 4.52E+02
B CFS-LRef-1314-T04-C 1 2.34E+02
B CFS-LRef-1314-T05-C 1 1.57E+02
B CFS-LRef-1314-T06-C 1 9.85E+01
B CFS-LRef-1314-T07-C 1 6.99E+01
B CFS-LRef-1314-T08-C 1 5.72E+01
B CFS-LRef-1314-T09-C 1 4.04E+01
B CFS-LRef-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.20E+03 0.74 1.00 3.18
1.42E+03 0.82 1.00 3.18
4.68E+02 0.60 1.00 3.18 10000 1000
2.46E+02 0.83 1.00 3.18
1.78E+02 1.27 1.00 3.18
1.07E+02 0.97 1.00 3.18
7.45E+01 3.04 1.00 3.18
5.17E+01 4.13 1.00 3.18
3.53E+01 4.92 1.00 3.18
2.00E+03 1.33 1.00 3.18
1.23E+03 0.23 1.00 3.18
4.79E+02 1.28 1.00 3.18 10000 1000
2.45E+02 0.34 1.00 3.18
1.50E+02 1.88 1.00 3.18
1.03E+02 1.75 1.00 3.18
7.44E+01 0.14 1.00 3.18
5.12E+01 3.09 1.00 3.18
4.26E+01 2.37 1.00 3.18
2.19E+03 0.30 1.00 3.18
1.38E+03 1.75 1.00 3.18
4.52E+02 1.33 1.00 3.18 10000 1000
2.34E+02 0.53 1.00 3.18
1.57E+02 1.19 1.00 3.18
9.85E+01 1.15 1.00 3.18
6.99E+01 0.89 1.00 3.18
5.72E+01 1.67 1.00 3.18
4.04E+01 12.02 1.00 3.18
5.00E-01 1.91 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.37E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.31E+03 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.32E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19 AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10 PM EPA Interlab LRef 1314 CFS
1-181
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ba CFS-LRef-1314-T01-A 1 4.65E+01
Ba CFS-LRef-1314-T02-A 1 4.93E+01
Ba CFS-LRef-1314-T03-A 1 9.27E+01
Ba CFS-LRef-1314-T04-A 1 1.09E+02
Ba CFS-LRef-1314-T05-A 1 1.14E+02
Ba CFS-LRef-1314-T06-A 1 1.26E+02
Ba CFS-LRef-1314-T07-A 1 1.29E+02
Ba CFS-LRef-1314-T08-A 1 1.28E+02
Ba CFS-LRef-1314-T09-A 1 1.28E+02
Ba CFS-LRef-1314-T01-B 1 4.35E+01
Ba CFS-LRef-1314-T02-B 1 4.74E+01
Ba CFS-LRef-1314-T03-B 1 1.00E+02
Ba CFS-LRef-1314-T04-B 1 1.10E+02
Ba CFS-LRef-1314-T05-B 1 1.04E+02
Ba CFS-LRef-1314-T06-B 1 1.27E+02
Ba CFS-LRef-1314-T07-B 1 1.34E+02
Ba CFS-LRef-1314-T08-B 1 1.29E+02
Ba CFS-LRef-1314-T09-B 1 1.31E+02
Ba CFS-LRef-1314-T01-C 1 4.23E+01
Ba CFS-LRef-1314-T02-C 1 5.44E+01
Ba CFS-LRef-1314-T03-C 1 9.30E+01
Ba CFS-LRef-1314-T04-C 1 1.10E+02
Ba CFS-LRef-1314-T05-C 1 1.11E+02
Ba CFS-LRef-1314-T06-C 1 1.20E+02
Ba CFS-LRef-1314-T07-C 1 1.30E+02
Ba CFS-LRef-1314-T08-C 1 1.25E+02
Ba CFS-LRef-1314-T09-C 1 1.30E+02
Ba CFS-LRef-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.65E+01 1.18 1.00 3.18
4.93E+01 0.41 1.00 3.18
9.27E+01 0.43 1.00 3.18 10000 1000
1.09E+02 0.19 1.00 3.18
1.14E+02 0.47 1.00 3.18
1.26E+02 1.03 1.00 3.18
1.29E+02 0.56 1.00 3.18
1.28E+02 1.11 1.00 3.18
1.28E+02 0.59 1.00 3.18
4.35E+01 0.64 1.00 3.18
4.74E+01 0.32 1.00 3.18
1.00E+02 0.65 1.00 3.18 10000 1000
1.10E+02 0.65 1.00 3.18
1.04E+02 1.27 1.00 3.18
1.27E+02 2.67 1.00 3.18
1.34E+02 0.44 1.00 3.18
1.29E+02 0.83 1.00 3.18
1.31E+02 0.40 1.00 3.18
4.23E+01 0.09 1.00 3.18
5.44E+01 1.90 1.00 3.18
9.30E+01 2.08 1.00 3.18 10000 1000
1.10E+02 0.76 1.00 3.18
1.11E+02 0.84 1.00 3.18
1.20E+02 0.44 1.00 3.18
1.30E+02 0.31 1.00 3.18
1.25E+02 1.11 1.00 3.18
1.30E+02 0.51 1.00 3.18
5.00E-01 16.98 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.11E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.11E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19 AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10 PM EPA Interlab LRef 1314 CFS
1-182
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L I
Be CFS-LRef-1314-T01-A 1 9.50E-01 U1/2
Be CFS-LRef-1314-T02-A 1 9.50E-01 U1/2
Be CFS-LRef-1314-T03-A 1 9.50E-01 U1/2
Be CFS-LRef-1314-T04-A 1 9.50E-01 U1/2
Be CFS-LRef-1314-T05-A 1 9.50E-01 U1/2
Be CFS-LRef-1314-T06-A 1 9.50E-01 U1/2
Be CFS-LRef-1314-T07-A 1 9.50E-01 U1/2
Be CFS-LRef-1314-T08-A 1 9.50E-01 U1/2
Be CFS-LRef-1314-T09-A 1 9.50E-01 U1/2
Be CFS-LRef-1314-T01-B 1 9.50E-01 U1/2
Be CFS-LRef-1314-T02-B 1 9.50E-01 U1/2
Be CFS-LRef-1314-T03-B 1 9.50E-01 U1/2
Be CFS-LRef-1314-T04-B 1 9.50E-01 U1/2
Be CFS-LRef-1314-T05-B 1 9.50E-01 U1/2
Be CFS-LRef-1314-T06-B 1 9.50E-01 U1/2
Be CFS-LRef-1314-T07-B 1 9.50E-01 U1/2
Be CFS-LRef-1314-T08-B 1 9.50E-01 U1/2
Be CFS-LRef-1314-T09-B 1 9.50E-01 U1/2
Be CFS-LRef-1314-T01-C 1 9.50E-01 U1/2
Be CFS-LRef-1314-T02-C 1 9.50E-01 U1/2
Be CFS-LRef-1314-T03-C 1 9.50E-01 U1/2
Be CFS-LRef-1314-T04-C 1 9.50E-01 U1/2
Be CFS-LRef-1314-T05-C 1 9.50E-01 U1/2
Be CFS-LRef-1314-T06-C 1 9.50E-01 U1/2
Be CFS-LRef-1314-T07-C 1 9.50E-01 U1/2
Be CFS-LRef-1314-T08-C 1 9.50E-01 U1/2
Be CFS-LRef-1314-T09-C 1 9.50E-01 U1/2
Be CFS-LRef-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 20.97 1.90 6.00
9.50E-01 5.69 1.90 6.00
9.50E-01 20.20 1.90 6.00 10000 1000
9.50E-01 20.38 1.90 6.00
9.50E-01 21.74 1.90 6.00
9.50E-01 4.87 1.90 6.00
9.50E-01 23.51 1.90 6.00
9.50E-01 16.62 1.90 6.00
9.50E-01 27.23 1.90 6.00
9.50E-01 35.16 1.90 6.00
9.50E-01 23.93 1.90 6.00
9.50E-01 14.15 1.90 6.00 10000 1000
9.50E-01 30.12 1.90 6.00
9.50E-01 19.43 1.90 6.00
9.50E-01 10.46 1.90 6.00
9.50E-01 14.17 1.90 6.00
9.50E-01 28.39 1.90 6.00
9.50E-01 23.94 1.90 6.00
9.50E-01 13.70 1.90 6.00
9.50E-01 10.42 1.90 6.00
9.50E-01 39.48 1.90 6.00 10000 1000
9.50E-01 33.93 1.90 6.00
9.50E-01 37.43 1.90 6.00
9.50E-01 26.10 1.90 6.00
9.50E-01 50.94 1.90 6.00
9.50E-01 9.12 1.90 6.00
9.50E-01 50.75 1.90 6.00
9.50E-01 37.12 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.98E+02 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19 AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10 PM EPA Interlab LRef 1314 CFS
1-183
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Cd CFS-LRef-1314-T01-A 1 1.44E+04
Cd CFS-LRef-1314-T02-A 1 9.29E+03
Cd CFS-LRef-1314-T03-A 1 7.93E+03
Cd CFS-LRef-1314-T04-A 1 1.03E+04
Cd CFS-LRef-1314-T05-A 1 9.34E+03
Cd CFS-LRef-1314-T06-A 1 7.70E+03
Cd CFS-LRef-1314-T07-A 1 5.55E+03
Cd CFS-LRef-1314-T08-A 1 3.77E+03
Cd CFS-LRef-1314-T09-A 1 3.05E+03
Cd CFS-LRef-1314-T01-B 1 1.64E+04
Cd CFS-LRef-1314-T02-B 1 9.11E+03
Cd CFS-LRef-1314-T03-B 1 9.49E+03
Cd CFS-LRef-1314-T04-B 1 9.86E+03
Cd CFS-LRef-1314-T05-B 1 8.63E+03
Cd CFS-LRef-1314-T06-B 1 7.53E+03
Cd CFS-LRef-1314-T07-B 1 5.57E+03
Cd CFS-LRef-1314-T08-B 1 3.20E+03
Cd CFS-LRef-1314-T09-B 1 3.11E+03
Cd CFS-LRef-1314-T01-C 1 1.58E+04
Cd CFS-LRef-1314-T02-C 1 1.04E+04
Cd CFS-LRef-1314-T03-C 1 7.98E+03
Cd CFS-LRef-1314-T04-C 1 9.44E+03
Cd CFS-LRef-1314-T05-C 1 8.86E+03
Cd CFS-LRef-1314-T06-C 1 6.93E+03
Cd CFS-LRef-1314-T07-C 1 5.38E+03
Cd CFS-LRef-1314-T08-C 1 3.50E+03
Cd CFS-LRef-1314-T09-C 1 2.88E+03
Cd CFS-LRef-1314-B01-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
144E+04 0.63 2.20 7.00
9.29E+03 0.89 2.20 7.00
7.93E+03 0.16 2.20 7.00 10000 1000
1.03E+04 0.58 2.20 7.00
9.34E+03 0.44 2.20 7.00
7.70E+03 0.77 2.20 7.00
5.55E+03 0.81 2.20 7.00
3.77E+03 1.63 2.20 7.00
3.05E+03 0.77 2.20 7.00
1.64E+04 1.45 2.20 7.00
9.11E+03 0.62 2.20 7.00
9.49E+03 1.01 2.20 7.00 10000 1000
9.86E+03 0.15 2.20 7.00
8.63E+03 1.53 2.20 7.00
7.53E+03 1.33 2.20 7.00
5.57E+03 0.43 2.20 7.00
3.20E+03 0.73 2.20 7.00
3.11E+03 0.63 2.20 7.00
1.58E+04 0.52 2.20 7.00
1.04E+04 1.59 2.20 7.00
7.98E+03 2.60 2.20 7.00 10000 1000
9.44E+03 0.96 2.20 7.00
8.86E+03 0.39 2.20 7.00
6.93E+03 0.95 2.20 7.00
5.38E+03 0.52 2.20 7.00
3.50E+03 1.26 2.20 7.00
2.88E+03 0.11 2.20 7.00
1.10E+00 17.81 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.93E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+04 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.92E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19 AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10 PM EPA Interlab LRef 1314 CFS
1-184
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Ca CFS-LRef-1314-T01-A 1 5.13E+05
Ca CFS-LRef-1314-T02-A 1 5.24E+05
Ca CFS-LRef-1314-T03-A 1 5.21E+05
Ca CFS-LRef-1314-T04-A 1 6.48E+05
Ca CFS-LRef-1314-T05-A 1 6.80E+05
Ca CFS-LRef-1314-T06-A 1 6.84E+05
Ca CFS-LRef-1314-T07-A 1 6.58E+05
Ca CFS-LRef-1314-T08-A 1 6.26E+05
Ca CFS-LRef-1314-T09-A 1 6.47E+05
Ca CFS-LRef-1314-T01-B 1 5.09E+05
Ca CFS-LRef-1314-T02-B 1 5.61 E+05
Ca CFS-LRef-1314-T03-B 1 5.95E+05
Ca CFS-LRef-1314-T04-B 1 6.52E+05
Ca CFS-LRef-1314-T05-B 1 6.10E+05
Ca CFS-LRef-1314-T06-B 1 6.45E+05
Ca CFS-LRef-1314-T07-B 1 6.86E+05
Ca CFS-LRef-1314-T08-B 1 6.75E+05
Ca CFS-LRef-1314-T09-B 1 6.83E+05
Ca CFS-LRef-1314-T01-C 1 5.17E+05
Ca CFS-LRef-1314-T02-C 1 5.87E+05
Ca CFS-LRef-1314-T03-C 1 6.52E+05
Ca CFS-LRef-1314-T04-C 1 6.58E+05
Ca CFS-LRef-1314-T05-C 1 6.42E+05
Ca CFS-LRef-1314-T06-C 1 6.52E+05
Ca CFS-LRef-1314-T07-C 1 6.64E+05
Ca CFS-LRef-1314-T08-C 1 6.89E+05
Ca CFS-LRef-1314-T09-C 1 6.35E+05
Ca CFS-LRef-1314-B01-A 1 1.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.13E+05 0.92 2.60 8.30
5.24E+05 0.77 2.60 8.30
5.21E+05 0.14 2.60 8.30 10000 1000
6.48E+05 0.14 2.60 8.30
6.80E+05 0.46 2.60 8.30
6.84E+05 0.59 2.60 8.30
6.58E+05 0.66 2.60 8.30
6.26E+05 0.86 2.60 8.30
6.47E+05 0.72 2.60 8.30
5.09E+05 1.41 2.60 8.30
5.61E+05 0.16 2.60 8.30
5.95E+05 0.83 2.60 8.30 10000 1000
6.52E+05 0.71 2.60 8.30
6.10E+05 1.53 2.60 8.30
6.45E+05 2.37 2.60 8.30
6.86E+05 0.34 2.60 8.30
6.75E+05 0.85 2.60 8.30
6.83E+05 0.86 2.60 8.30
5.17E+05 0.18 2.60 8.30
5.87E+05 1.94 2.60 8.30
6.52E+05 1.23 2.60 8.30 10000 1000
6.58E+05 1.16 2.60 8.30
6.42E+05 0.57 2.60 8.30
6.52E+05 0.59 2.60 8.30
6.64E+05 0.55 2.60 8.30
6.89E+05 1.15 2.60 8.30
6.35E+05 0.33 2.60 8.30
1.30E+00 15.70 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.22E+05 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.96E+05 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.52E+05 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10 PM EPA Interlab LRef 1314 CFS
1-185
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L I
Cr CFS-LRef-1314-T01-A 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T02-A 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T03-A 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T04-A 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T05-A 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T06-A 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T07-A 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T08-A 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T09-A 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T01-B 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T02-B 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T03-B 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T04-B 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T05-B 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T06-B 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T07-B 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T08-B 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T09-B 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T01-C 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T02-C 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T03-C 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T04-C 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T05-C 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T06-C 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T07-C 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T08-C 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T09-C 1 6.00E-01 U1/2
Cr CFS-LRef-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 19.38 1.20 3.82
6.00E-01 30.13 1.20 3.82
6.00E-01 2.55 1.20 3.82 10000 1000
6.00E-01 52.91 1.20 3.82
6.00E-01 61.05 1.20 3.82
6.00E-01 71.23 1.20 3.82
6.00E-01 47.89 1.20 3.82
6.00E-01 22.03 1.20 3.82
6.00E-01 94.13 1.20 3.82
6.00E-01 37.56 1.20 3.82
6.00E-01 31.22 1.20 3.82
6.00E-01 14.67 1.20 3.82 10000 1000
6.00E-01 60.55 1.20 3.82
6.00E-01 67.59 1.20 3.82
6.00E-01 53.00 1.20 3.82
6.00E-01 25.20 1.20 3.82
6.00E-01 24.66 1.20 3.82
6.00E-01 30.77 1.20 3.82
6.00E-01 1.84 1.20 3.82
6.00E-01 14.94 1.20 3.82
6.00E-01 41.37 1.20 3.82 10000 1000
6.00E-01 18.69 1.20 3.82
6.00E-01 42.71 1.20 3.82
6.00E-01 50.79 1.20 3.82
6.00E-01 26.03 1.20 3.82
6.00E-01 27.11 1.20 3.82
6.00E-01 11.08 1.20 3.82
6.00E-01 24.63 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.36E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.31 E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.32E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19 AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/1 1 1 1 :26 AM EPA Interlab LRef 1 31 4 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10 PM EPA Interlab LRef 1314 CFS
1-186
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Co CFS-LRef-1314-T01-A 1 7.07E+02
Co CFS-LRef-1314-T02-A 1 2.62E+02
Co CFS-LRef-1314-T03-A 1 2.13E+02
Co CFS-LRef-1314-T04-A 1 2.90E+02
Co CFS-LRef-1314-T05-A 1 2.99E+02
Co CFS-LRef-1314-T06-A 1 1.26E+02
Co CFS-LRef-1314-T07-A 1 6.02E+01
Co CFS-LRef-1314-T08-A 1 3.56E+01
Co CFS-LRef-1314-T09-A 1 1.80E+01
Co CFS-LRef-1314-T01-B 1 7.24E+02
Co CFS-LRef-1314-T02-B 1 2.60E+02
Co CFS-LRef-1314-T03-B 1 2.35E+02
Co CFS-LRef-1314-T04-B 1 2.79E+02
Co CFS-LRef-1314-T05-B 1 2.54E+02
Co CFS-LRef-1314-T06-B 1 1.34E+02
Co CFS-LRef-1314-T07-B 1 5.86E+01
Co CFS-LRef-1314-T08-B 1 3.70E+01
Co CFS-LRef-1314-T09-B 1 2.63E+01
Co CFS-LRef-1314-T01-C 1 7.32E+02
Co CFS-LRef-1314-T02-C 1 2.85E+02
Co CFS-LRef-1314-T03-C 1 2.74E+02
Co CFS-LRef-1314-T04-C 1 3.15E+02
Co CFS-LRef-1314-T05-C 1 1.59E+02
Co CFS-LRef-1314-T06-C 1 1.10E+02
Co CFS-LRef-1314-T07-C 1 5.84E+01
Co CFS-LRef-1314-T08-C 1 4.28E+01
Co CFS-LRef-1314-T09-C 1 2.40E+01
Co CFS-LRef-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.07E+02 0.41 1.80 5.72
2.62E+02 1.03 1.80 5.72
2.13E+02 0.45 1.80 5.72 10000 1000
2.90E+02 0.34 1.80 5.72
2.99E+02 1.75 1.80 5.72
1.26E+02 0.62 1.80 5.72
6.02E+01 1.21 1.80 5.72
3.56E+01 1.48 1.80 5.72
1.80E+01 14.14 1.80 5.72
7.24E+02 3.23 1.80 5.72
2.60E+02 0.52 1.80 5.72
2.35E+02 1.50 1.80 5.72 10000 1000
2.79E+02 0.40 1.80 5.72
2.54E+02 1.55 1.80 5.72
1.34E+02 6.58 1.80 5.72
5.86E+01 2.40 1.80 5.72
3.70E+01 2.38 1.80 5.72
2.63E+01 1.18 1.80 5.72
7.32E+02 0.57 1.80 5.72
2.85E+02 1.83 1.80 5.72
2.74E+02 4.29 1.80 5.72 10000 1000
3.15E+02 0.77 1.80 5.72
1.59E+02 0.56 1.80 5.72
1.10E+02 0.61 1.80 5.72
5.84E+01 2.38 1.80 5.72
4.28E+01 3.43 1.80 5.72
2.40E+01 4.94 1.80 5.72
9.00E-01 59.53 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.33E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.38E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.29E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19 AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10 PM EPA Interlab LRef 1314 CFS
1-187
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Cu CFS-LRef-1314-T01-A 1 2.50E+03
Cu CFS-LRef-1314-T02-A 1 1.25E+03
Cu CFS-LRef-1314-T03-A 1 1.83E+03
Cu CFS-LRef-1314-T04-A 1 1.31E+03
Cu CFS-LRef-1314-T05-A 1 1.44E+03
Cu CFS-LRef-1314-T06-A 1 1.43E+03
Cu CFS-LRef-1314-T07-A 1 1.26E+03
Cu CFS-LRef-1314-T08-A 1 8.89E+02
Cu CFS-LRef-1314-T09-A 1 7.58E+02
Cu CFS-LRef-1314-T01-B 1 2.74E+03
Cu CFS-LRef-1314-T02-B 1 1.33E+03
Cu CFS-LRef-1314-T03-B 1 2.11E+03
Cu CFS-LRef-1314-T04-B 1 1.12E+03
Cu CFS-LRef-1314-T05-B 1 1.36E+03
Cu CFS-LRef-1314-T06-B 1 1.26E+03
Cu CFS-LRef-1314-T07-B 1 1.29E+03
Cu CFS-LRef-1314-T08-B 1 8.45E+02
Cu CFS-LRef-1314-T09-B 1 8.00E+02
Cu CFS-LRef-1314-T01-C 1 2.16E+03
Cu CFS-LRef-1314-T02-C 1 1.26E+03
Cu CFS-LRef-1314-T03-C 1 1.78E+03
Cu CFS-LRef-1314-T04-C 1 1.04E+03
Cu CFS-LRef-1314-T05-C 1 1.28E+03
Cu CFS-LRef-1314-T06-C 1 1.30E+03
Cu CFS-LRef-1314-T07-C 1 1.15E+03
Cu CFS-LRef-1314-T08-C 1 8.32E+02
Cu CFS-LRef-1314-T09-C 1 7.21E+02
Cu CFS-LRef-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.50E+03 0.78 3.70 11.80
1.25E+03 0.50 3.70 11.80
1.83E+03 0.57 3.70 11.80 10000 1000
1.31E+03 1.16 3.70 11.80
1.44E+03 1.71 3.70 11.80
1.43E+03 1.40 3.70 11.80
1.26E+03 0.49 3.70 11.80
8.89E+02 5.32 3.70 11.80
7.58E+02 0.39 3.70 11.80
2.74E+03 1.54 3.70 11.80
1.33E+03 1.22 3.70 11.80
2.11E+03 0.14 3.70 11.80 10000 1000
1.12E+03 1.02 3.70 11.80
1.36E+03 1.51 3.70 11.80
1.26E+03 3.21 3.70 11.80
1.29E+03 0.47 3.70 11.80
8.45E+02 0.57 3.70 11.80
8.00E+02 0.51 3.70 11.80
2.16E+03 0.54 3.70 11.80
1.26E+03 1.41 3.70 11.80
1.78E+03 4.83 3.70 11.80 10000 1000
1.04E+03 1.99 3.70 11.80
1.28E+03 0.92 3.70 11.80
1.30E+03 0.49 3.70 11.80
1.15E+03 0.16 3.70 11.80
8.32E+02 1.26 3.70 11.80
7.21E+02 0.49 3.70 11.80
1.85E+00 41.35 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.80E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.12E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.87E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19 AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10 PM EPA Interlab LRef 1314 CFS
1-188
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L I
Fe CFS-LRef-1314-T01-A 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T02-A 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T03-A 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T04-A 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T05-A 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T06-A 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T07-A 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T08-A 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T09-A 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T01-B 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T02-B 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T03-B 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T04-B 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T05-B 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T06-B 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T07-B 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T08-B 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T09-B 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T01-C 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T02-C 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T03-C 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T04-C 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T05-C 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T06-C 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T07-C 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T08-C 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T09-C 1 1.00E+00 U1/2
Fe CFS-LRef-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 25.67 2.00 6.40
1.00E+00 24.79 2.00 6.40
1.00E+00 22.07 2.00 6.40 10000 1000
1.00E+00 10.03 2.00 6.40
1.00E+00 38.08 2.00 6.40
1.00E+00 24.61 2.00 6.40
1.00E+00 21.38 2.00 6.40
1.00E+00 30.93 2.00 6.40
1.00E+00 32.56 2.00 6.40
1.00E+00 28.36 2.00 6.40
1.00E+00 24.41 2.00 6.40
1.00E+00 14.42 2.00 6.40 10000 1000
1.00E+00 45.06 2.00 6.40
1.00E+00 10.27 2.00 6.40
1.00E+00 16.06 2.00 6.40
1.00E+00 34.05 2.00 6.40
1.00E+00 21.52 2.00 6.40
1.00E+00 44.16 2.00 6.40
1.00E+00 10.26 2.00 6.40
1.00E+00 16.32 2.00 6.40
1.00E+00 41.96 2.00 6.40 10000 1000
1.00E+00 24.60 2.00 6.40
1.00E+00 21.63 2.00 6.40
1.00E+00 32.75 2.00 6.40
1.00E+00 27.68 2.00 6.40
1.00E+00 24.88 2.00 6.40
1.00E+00 37.06 2.00 6.40
1.00E+00 29.10 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.74E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.71 E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.68E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19 AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10 PM EPA Interlab LRef 1314 CFS
1-189
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Pb CFS-LRef-1314-T01-A 1 9.66E+02
Pb CFS-LRef-1314-T02-A 1 8.03E+02
Pb CFS-LRef-1314-T03-A 1 8.67E+02
Pb CFS-LRef-1314-T04-A 1 9.67E+02
Pb CFS-LRef-1314-T05-A 1 1.11E+03
Pb CFS-LRef-1314-T06-A 1 1.08E+03
Pb CFS-LRef-1314-T07-A 1 1.01E+03
Pb CFS-LRef-1314-T08-A 1 8.18E+02
Pb CFS-LRef-1314-T09-A 1 8.02E+02
Pb CFS-LRef-1314-T01-B 1 9.46E+02
Pb CFS-LRef-1314-T02-B 1 7.92E+02
Pb CFS-LRef-1314-T03-B 1 9.76E+02
Pb CFS-LRef-1314-T04-B 1 9.96E+02
Pb CFS-LRef-1314-T05-B 1 9.88E+02
Pb CFS-LRef-1314-T06-B 1 1.06E+03
Pb CFS-LRef-1314-T07-B 1 1.03E+03
Pb CFS-LRef-1314-T08-B 1 9.18E+02
Pb CFS-LRef-1314-T09-B 1 9.22E+02
Pb CFS-LRef-1314-T01-C 1 9.28E+02
Pb CFS-LRef-1314-T02-C 1 7.75E+02
Pb CFS-LRef-1314-T03-C 1 8.23E+02
Pb CFS-LRef-1314-T04-C 1 9.41E+02
Pb CFS-LRef-1314-T05-C 1 1.04E+03
Pb CFS-LRef-1314-T06-C 1 1.06E+03
Pb CFS-LRef-1314-T07-C 1 9.74E+02
Pb CFS-LRef-1314-T08-C 1 9.23E+02
Pb CFS-LRef-1314-T09-C 1 8.65E+02
Pb CFS-LRef-1314-B01-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.66E+02 0.51 6.80 21.60
8.03E+02 0.48 6.80 21.60
8.67E+02 0.52 6.80 21.60 10000 1000
9.67E+02 0.25 6.80 21.60
1.11E+03 0.94 6.80 21.60
1.08E+03 0.99 6.80 21.60
1.01E+03 0.86 6.80 21.60
8.18E+02 15.11 6.80 21.60
8.02E+02 0.61 6.80 21.60
9.46E+02 0.60 6.80 21.60
7.92E+02 0.45 6.80 21.60
9.76E+02 0.68 6.80 21.60 10000 1000
9.96E+02 0.02 6.80 21.60
9.88E+02 4.14 6.80 21.60
1.06E+03 5.00 6.80 21.60
1.03E+03 0.60 6.80 21.60
9.18E+02 1.24 6.80 21.60
9.22E+02 1.10 6.80 21.60
9.28E+02 0.37 6.80 21.60
7.75E+02 1.75 6.80 21.60
8.23E+02 8.18 6.80 21.60 10000 1000
9.41 E+02 1.43 6.80 21.60
1.04E+03 0.66 6.80 21.60
1.06E+03 0.74 6.80 21.60
9.74E+02 0.56 6.80 21.60
9.23E+02 1.80 6.80 21.60
8.65E+02 0.88 6.80 21.60
3.40E+00 20.68 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.83E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.91E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.79E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19 AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10PM EPA Interlab LRef 1314 CFS
1-190
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Li CFS-LRef-1314-T01-A 1 4.03E+01
Li CFS-LRef-1314-T02-A 1 8.28E+00
Li CFS-LRef-1314-T03-A 1 7.98E+00
Li CFS-LRef-1314-T04-A 1 1.29E+01
Li CFS-LRef-1314-T05-A 1 1.14E+01
Li CFS-LRef-1314-T06-A 1 1.45E+01
Li CFS-LRef-1314-T07-A 1 1.32E+01
Li CFS-LRef-1314-T08-A 1 1.33E+01
Li CFS-LRef-1314-T09-A 1 8.76E+00
Li CFS-LRef-1314-T01-B 1 4.25E+01
Li CFS-LRef-1314-T02-B 1 8.20E+00
Li CFS-LRef-1314-T03-B 1 1.31E+01
Li CFS-LRef-1314-T04-B 1 1.40E+01
Li CFS-LRef-1314-T05-B 1 1.21E+01
Li CFS-LRef-1314-T06-B 1 1.23E+01
Li CFS-LRef-1314-T07-B 1 1.44E+01
Li CFS-LRef-1314-T08-B 1 1.29E+01
Li CFS-LRef-1314-T09-B 1 1.33E+01
Li CFS-LRef-1314-T01-C 1 4.25E+01
Li CFS-LRef-1314-T02-C 1 1.03E+01
Li CFS-LRef-1314-T03-C 1 9.68E+00
Li CFS-LRef-1314-T04-C 1 1.27E+01
Li CFS-LRef-1314-T05-C 1 1.28E+01
Li CFS-LRef-1314-T06-C 1 1.33E+01
Li CFS-LRef-1314-T07-C 1 1.40E+01
Li CFS-LRef-1314-T08-C 1 7.14E+00
Li CFS-LRef-1314-T09-C 1 1.55E+01
Li CFS-LRef-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.03E+01 7.78 1.90 6.00
8.28E+00 7.35 1.90 6.00
7.98E+00 1.95 1.90 6.00 10000 1000
1.29E+01 1.54 1.90 6.00
1.14E+01 8.05 1.90 6.00
1.45E+01 3.47 1.90 6.00
1.32E+01 9.00 1.90 6.00
1.33E+01 3.00 1.90 6.00
8.76E+00 1.82 1.90 6.00
4.25E+01 6.48 1.90 6.00
8.20E+00 1.05 1.90 6.00
1.31E+01 1.38 1.90 6.00 10000 1000
1.40E+01 9.93 1.90 6.00
1.21E+01 1.94 1.90 6.00
1.23E+01 15.28 1.90 6.00
1.44E+01 3.45 1.90 6.00
1.29E+01 6.88 1.90 6.00
1.33E+01 12.39 1.90 6.00
4.25E+01 4.92 1.90 6.00
1.03E+01 1.47 1.90 6.00
9.68E+00 1.57 1.90 6.00 10000 1000
1.27E+01 2.26 1.90 6.00
1.28E+01 1.37 1.90 6.00
1.33E+01 1.49 1.90 6.00
1.40E+01 1.08 1.90 6.00
7.14E+00 1.01 1.90 6.00
1.55E+01 9.51 1.90 6.00
9.50E-01 35.25 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.60E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.70E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.66E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10 PM EPA Interlab LRef 1314 CFS
1-191
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Mn CFS-LRef-1314-T01-A 1 1.90E+04
Mn CFS-LRef-1314-T02-A 1 9.25E+03
Mn CFS-LRef-1314-T03-A 1 7.12E+03
Mn CFS-LRef-1314-T04-A 1 4.28E+03
Mn CFS-LRef-1314-T05-A 1 2.04E+03
Mn CFS-LRef-1314-T06-A 1 7.73E+02
Mn CFS-LRef-1314-T07-A 1 4.60E+02
Mn CFS-LRef-1314-T08-A 1 3.14E+02
Mn CFS-LRef-1314-T09-A 1 2.00E+02
Mn CFS-LRef-1314-T01-B 1 2.03E+04
Mn CFS-LRef-1314-T02-B 1 9.44E+03
Mn CFS-LRef-1314-T03-B 1 6.41 E+03
Mn CFS-LRef-1314-T04-B 1 4.26E+03
Mn CFS-LRef-1314-T05-B 1 1.77E+03
Mn CFS-LRef-1314-T06-B 1 8.12E+02
Mn CFS-LRef-1314-T07-B 1 4.66E+02
Mn CFS-LRef-1314-T08-B 1 3.19E+02
Mn CFS-LRef-1314-T09-B 1 2.52E+02
Mn CFS-LRef-1314-T01-C 1 1.91E+04
Mn CFS-LRef-1314-T02-C 1 9.04E+03
Mn CFS-LRef-1314-T03-C 1 6.70E+03
Mn CFS-LRef-1314-T04-C 1 4.87E+03
Mn CFS-LRef-1314-T05-C 1 1.72E+03
Mn CFS-LRef-1314-T06-C 1 6.89E+02
Mn CFS-LRef-1314-T07-C 1 4.30E+02
Mn CFS-LRef-1314-T08-C 1 2.51E+02
Mn CFS-LRef-1314-T09-C 1 2.41E+02
Mn CFS-LRef-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.90E+04 0.69 2.00 6.40
9.25E+03 1.20 2.00 6.40
7.12E+03 0.34 2.00 6.40 10000 1000
4.28E+03 0.37 2.00 6.40
2.04E+03 0.82 2.00 6.40
7.73E+02 0.54 2.00 6.40
4.60E+02 1.17 2.00 6.40
3.14E+02 17.49 2.00 6.40
2.00E+02 0.58 2.00 6.40
2.03E+04 1.48 2.00 6.40
9.44E+03 0.59 2.00 6.40
6.41E+03 0.74 2.00 6.40 10000 1000
4.26E+03 1.15 2.00 6.40
1.77E+03 8.81 2.00 6.40
8.12E+02 1.94 2.00 6.40
4.66E+02 0.97 2.00 6.40
3.19E+02 0.66 2.00 6.40
2.52E+02 0.26 2.00 6.40
1.91E+04 0.27 2.00 6.40
9.04E+03 1.62 2.00 6.40
6.70E+03 3.73 2.00 6.40 10000 1000
4.87E+03 1.06 2.00 6.40
1.72E+03 0.84 2.00 6.40
6.89E+02 1.67 2.00 6.40
4.30E+02 1.68 2.00 6.40
2.51 E+02 1.53 2.00 6.40
2.41 E+02 0.30 2.00 6.40
1.00E+00 8.62 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.10E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.34E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.64E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10 PM EPA Interlab LRef 1314 CFS
1-192
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Mg CFS-LRef-1314-T01-A 1 2.01E+06
Mg CFS-LRef-1314-T02-A 1 5.23E+05
Mg CFS-LRef-1314-T03-A 1 1.21E+05
Mg CFS-LRef-1314-T04-A 1 3.00E+04
Mg CFS-LRef-1314-T05-A 1 1.39E+04
Mg CFS-LRef-1314-T06-A 1 1.18E+04
Mg CFS-LRef-1314-T07-A 1 1.01E+04
Mg CFS-LRef-1314-T08-A 1 7.11E+03
Mg CFS-LRef-1314-T09-A 1 5.09E+03
Mg CFS-LRef-1314-T01-B 1 1.99E+06
Mg CFS-LRef-1314-T02-B 1 5.08E+05
Mg CFS-LRef-1314-T03-B 1 1.04E+05
Mg CFS-LRef-1314-T04-B 1 2.86E+04
Mg CFS-LRef-1314-T05-B 1 1.70E+04
Mg CFS-LRef-1314-T06-B 1 1.17E+04
Mg CFS-LRef-1314-T07-B 1 1.09E+04
Mg CFS-LRef-1314-T08-B 1 5.10E+03
Mg CFS-LRef-1314-T09-B 1 4.83E+03
Mg CFS-LRef-1314-T01-C 1 2.11E+06
Mg CFS-LRef-1314-T02-C 1 4.37E+05
Mg CFS-LRef-1314-T03-C 1 1.48E+05
Mg CFS-LRef-1314-T04-C 1 2.89E+04
Mg CFS-LRef-1314-T05-C 1 1.55E+04
Mg CFS-LRef-1314-T06-C 1 1.16E+04
Mg CFS-LRef-1314-T07-C 1 9.02E+03
Mg CFS-LRef-1314-T08-C 1 5.76E+03
Mg CFS-LRef-1314-T09-C 1 4.33E+03
Mg CFS-LRef-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.01E+06 1.14 1.00 3.18
5.23E+05 0.79 1.00 3.18
1.21E+05 0.40 1.00 3.18 10000 1000
3.00E+04 0.42 1.00 3.18
1.39E+04 0.67 1.00 3.18
1.18E+04 1.28 1.00 3.18
1.01E+04 1.20 1.00 3.18
7.11E+03 2.37 1.00 3.18
5.09E+03 0.50 1.00 3.18
1.99E+06 1.90 1.00 3.18
5.08E+05 0.25 1.00 3.18
1.04E+05 0.26 1.00 3.18 10000 1000
2.86E+04 0.82 1.00 3.18
1.70E+04 2.91 1.00 3.18
1.17E+04 2.82 1.00 3.18
1.09E+04 0.50 1.00 3.18
5.10E+03 0.26 1.00 3.18
4.83E+03 0.94 1.00 3.18
2.11E+06 0.23 1.00 3.18
4.37E+05 0.92 1.00 3.18
1.48E+05 3.19 1.00 3.18 10000 1000
2.89E+04 0.58 1.00 3.18
1.55E+04 0.99 1.00 3.18
1.16E+04 0.60 1.00 3.18
9.02E+03 0.64 1.00 3.18
5.76E+03 1.14 1.00 3.18
4.33E+03 0.26 1.00 3.18
5.00E-01 34.34 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.22E+05 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+05 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.49E+05 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10 PM EPA Interlab LRef 1314 CFS
1-193
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Mo CFS-LRef-1314-T01-A 1 2.66E+01
Mo CFS-LRef-1314-T02-A 1 1.55E+01
Mo CFS-LRef-1314-T03-A 1 7.13E+00
Mo CFS-LRef-1314-T04-A 1 6.93E+00
Mo CFS-LRef-1314-T05-A 1 8.38E+00
Mo CFS-LRef-1314-T06-A 1 9.04E+00
Mo CFS-LRef-1314-T07-A 1 7.14E+00
Mo CFS-LRef-1314-T08-A 1 6.29E+00
Mo CFS-LRef-1314-T09-A 1 6.60E+00
Mo CFS-LRef-1314-T01-B 1 2.25E+01
Mo CFS-LRef-1314-T02-B 1 1.65E+01
Mo CFS-LRef-1314-T03-B 1 7.11E+00
Mo CFS-LRef-1314-T04-B 1 6.55E+00
Mo CFS-LRef-1314-T05-B 1 5.83E+00
Mo CFS-LRef-1314-T06-B 1 6.32E+00
Mo CFS-LRef-1314-T07-B 1 7.80E+00
Mo CFS-LRef-1314-T08-B 1 7.34E+00
Mo CFS-LRef-1314-T09-B 1 7.44E+00
Mo CFS-LRef-1314-T01-C 1 2.58E+01
Mo CFS-LRef-1314-T02-C 1 1.60E+01
Mo CFS-LRef-1314-T03-C 1 6.71E+00
Mo CFS-LRef-1314-T04-C 1 7.23E+00
Mo CFS-LRef-1314-T05-C 1 8.43E+00
Mo CFS-LRef-1314-T06-C 1 8.32E+00
Mo CFS-LRef-1314-T07-C 1 8.13E+00
Mo CFS-LRef-1314-T08-C 1 7.54E+00
Mo CFS-LRef-1314-T09-C 1 7.81E+00
Mo CFS-LRef-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.66E+01 0.83 1.20 3.82
1.55E+01 2.30 1.20 3.82
7.13E+00 1.71 1.20 3.82 10000 1000
6.93E+00 9.66 1.20 3.82
8.38E+00 10.78 1.20 3.82
9.04E+00 1.40 1.20 3.82
7.14E+00 2.58 1.20 3.82
6.29E+00 2.40 1.20 3.82
6.60E+00 9.63 1.20 3.82
2.25E+01 3.90 1.20 3.82
1.65E+01 5.98 1.20 3.82
7.11E+00 1.61 1.20 3.82 10000 1000
6.55E+00 2.67 1.20 3.82
5.83E+00 2.61 1.20 3.82
6.32E+00 4.21 1.20 3.82
7.80E+00 2.12 1.20 3.82
7.34E+00 1.45 1.20 3.82
7.44E+00 2.13 1.20 3.82
2.58E+01 5.17 1.20 3.82
1.60E+01 1.29 1.20 3.82
6.71E+00 2.23 1.20 3.82 10000 1000
7.23E+00 11.88 1.20 3.82
8.43E+00 1.29 1.20 3.82
8.32E+00 4.36 1.20 3.82
8.13E+00 1.79 1.20 3.82
7.54E+00 1.44 1.20 3.82
7.81 E+00 1.66 1.20 3.82
6.00E-01 17.78 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19 AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/1 1 1 1 :48 AM EPA Interlab LRef 1 31 4 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10 PM EPA Interlab LRef 1314 CFS
1-194
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Ni CFS-LRef-1314-T01-A 1 1.06E+03
Ni CFS-LRef-1314-T02-A 1 6.47E+02
Ni CFS-LRef-1314-T03-A 1 4.38E+02
Ni CFS-LRef-1314-T04-A 1 5.35E+02
Ni CFS-LRef-1314-T05-A 1 5.41 E+02
Ni CFS-LRef-1314-T06-A 1 3.32E+02
Ni CFS-LRef-1314-T07-A 1 1.83E+02
Ni CFS-LRef-1314-T08-A 1 1.04E+02
Ni CFS-LRef-1314-T09-A 1 7.63E+01
Ni CFS-LRef-1314-T01-B 1 1.09E+03
Ni CFS-LRef-1314-T02-B 1 6.54E+02
Ni CFS-LRef-1314-T03-B 1 4.13E+02
Ni CFS-LRef-1314-T04-B 1 5.28E+02
Ni CFS-LRef-1314-T05-B 1 5.09E+02
Ni CFS-LRef-1314-T06-B 1 3.05E+02
Ni CFS-LRef-1314-T07-B 1 1.76E+02
Ni CFS-LRef-1314-T08-B 1 1.02E+02
Ni CFS-LRef-1314-T09-B 1 7.61 E+01
Ni CFS-LRef-1314-T01-C 1 1.16E+03
Ni CFS-LRef-1314-T02-C 1 6.38E+02
Ni CFS-LRef-1314-T03-C 1 3.94E+02
Ni CFS-LRef-1314-T04-C 1 5.53E+02
Ni CFS-LRef-1314-T05-C 1 4.87E+02
Ni CFS-LRef-1314-T06-C 1 2.93E+02
Ni CFS-LRef-1314-T07-C 1 1.74E+02
Ni CFS-LRef-1314-T08-C 1 1.04E+02
Ni CFS-LRef-1314-T09-C 1 7.26E+01
Ni CFS-LRef-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.06E+03 0.77 1.80 5.70
6.47E+02 0.81 1.80 5.70
4.38E+02 0.60 1.80 5.70 10000 1000
5.35E+02 3.52 1.80 5.70
5.41 E+02 0.68 1.80 5.70
3.32E+02 0.92 1.80 5.70
1.83E+02 0.93 1.80 5.70
1.04E+02 1.54 1.80 5.70
7.63E+01 1.90 1.80 5.70
1.09E+03 2.28 1.80 5.70
6.54E+02 1.03 1.80 5.70
4.13E+02 1.12 1.80 5.70 10000 1000
5.28E+02 0.58 1.80 5.70
5.09E+02 1.64 1.80 5.70
3.05E+02 1.76 1.80 5.70
1.76E+02 0.18 1.80 5.70
1.02E+02 0.63 1.80 5.70
7.61E+01 1.80 1.80 5.70
1.16E+03 0.49 1.80 5.70
6.38E+02 0.94 1.80 5.70
3.94E+02 3.65 1.80 5.70 10000 1000
5.53E+02 0.97 1.80 5.70
4.87E+02 0.51 1.80 5.70
2.93E+02 0.66 1.80 5.70
1.74E+02 1.51 1.80 5.70
1.04E+02 1.41 1.80 5.70
7.26E+01 3.01 1.80 5.70
9.00E-01 30.14 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.51E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.52E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.46E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19 AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10 PM EPA Interlab LRef 1314 CFS
1-195
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
P CFS-LRef-1314-T01-A 1 4.30E+01
P CFS-LRef-1314-T02-A 1 2.75E+01
P CFS-LRef-1314-T03-A 1 2.42E+01
P CFS-LRef-1314-T04-A 1 2.11E+01
P CFS-LRef-1314-T05-A 1 2.22E+01
P CFS-LRef-1314-T06-A 1 1.89E+01
P CFS-LRef-1314-T07-A 1 2.39E+01
P CFS-LRef-1314-T08-A 1 1.88E+01
P CFS-LRef-1314-T09-A 1 1.38E+01
P CFS-LRef-1314-T01-B 1 4.28E+01
P CFS-LRef-1314-T02-B 1 3.44E+01
P CFS-LRef-1314-T03-B 1 2.55E+01
P CFS-LRef-1314-T04-B 1 2.01E+01
P CFS-LRef-1314-T05-B 1 1.86E+01
P CFS-LRef-1314-T06-B 1 1.93E+01
P CFS-LRef-1314-T07-B 1 2.04E+01
P CFS-LRef-1314-T08-B 1 1.48E+01
P CFS-LRef-1314-T09-B 1 1.59E+01
P CFS-LRef-1314-T01-C 1 4.37E+01
P CFS-LRef-1314-T02-C 1 2.87E+01
P CFS-LRef-1314-T03-C 1 2.45E+01
P CFS-LRef-1314-T04-C 1 2.22E+01
P CFS-LRef-1314-T05-C 1 1.95E+01
P CFS-LRef-1314-T06-C 1 1.86E+01
P CFS-LRef-1314-T07-C 1 2.20E+01
P CFS-LRef-1314-T08-C 1 1.72E+01
P CFS-LRef-1314-T09-C 1 2.19E+01
P CFS-LRef-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.30E+01 42.14 3.70 11.80
2.75E+01 26.68 3.70 11.80
2.42E+01 28.25 3.70 11.80 10000 1000
2.11E+01 14.53 3.70 11.80
2.22E+01 49.66 3.70 11.80
1.89E+01 37.70 3.70 11.80
2.39E+01 38.25 3.70 11.80
1.88E+01 65.74 3.70 11.80
1.38E+01 12.69 3.70 11.80
4.28E+01 33.33 3.70 11.80
3.44E+01 27.15 3.70 11.80
2.55E+01 23.20 3.70 11.80 10000 1000
2.01 E+01 54.99 3.70 11.80
1.86E+01 11.62 3.70 11.80
1.93E+01 21.64 3.70 11.80
2.04E+01 17.78 3.70 11.80
1.48E+01 44.57 3.70 11.80
1.59E+01 29.13 3.70 11.80
4.37E+01 35.51 3.70 11.80
2.87E+01 48.87 3.70 11.80
2.45E+01 23.87 3.70 11.80 10000 1000
2.22E+01 83.82 3.70 11.80
1.95E+01 66.42 3.70 11.80
1.86E+01 56.42 3.70 11.80
2.20E+01 46.21 3.70 11.80
1.72E+01 29.29 3.70 11.80
2.19E+01 42.85 3.70 11.80
1.85E+00 24.91 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.77E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.98E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.87E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19 AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10PM EPA Interlab LRef 1314 CFS
1-196
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
K CFS-LRef-1314-T01-A 1 1.33E+05
K CFS-LRef-1314-T02-A 1 5.14E+04
K CFS-LRef-1314-T03-A 1 2.17E+04
K CFS-LRef-1314-T04-A 1 2.21E+04
K CFS-LRef-1314-T05-A 1 1.54E+04
K CFS-LRef-1314-T06-A 1 7.60E+03
K CFS-LRef-1314-T07-A 1 4.35E+03
K CFS-LRef-1314-T08-A 1 2.58E+03
K CFS-LRef-1314-T09-A 1 1.63E+03
K CFS-LRef-1314-T01-B 1 1.30E+05
K CFS-LRef-1314-T02-B 1 5.17E+04
K CFS-LRef-1314-T03-B 1 2.36E+04
K CFS-LRef-1314-T04-B 1 2.28E+04
K CFS-LRef-1314-T05-B 1 1.34E+04
K CFS-LRef-1314-T06-B 1 6.89E+03
K CFS-LRef-1314-T07-B 1 4.30E+03
K CFS-LRef-1314-T08-B 1 2.54E+03
K CFS-LRef-1314-T09-B 1 1.95E+03
K CFS-LRef-1314-T01-C 1 1.29E+05
K CFS-LRef-1314-T02-C 1 5.10E+04
K CFS-LRef-1314-T03-C 1 2.16E+04
K CFS-LRef-1314-T04-C 1 2.15E+04
K CFS-LRef-1314-T05-C 1 1.37E+04
K CFS-LRef-1314-T06-C 1 6.93E+03
K CFS-LRef-1314-T07-C 1 4.19E+03
K CFS-LRef-1314-T08-C 1 2.96E+03
K CFS-LRef-1314-T09-C 1 1.76E+03
K CFS-LRef-1314-B01-A 1 9.93E+00
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.33E+05 0.93 1.60 5.09
5.14E+04 0.99 1.60 5.09
2.17E+04 0.47 1.60 5.09 10000 1000
2.21 E+04 0.27 1.60 5.09
1.54E+04 0.49 1.60 5.09
7.60E+03 0.59 1.60 5.09
4.35E+03 0.50 1.60 5.09
2.58E+03 1.52 1.60 5.09
1.63E+03 0.81 1.60 5.09
1.30E+05 4.31 1.60 5.09
5.17E+04 0.23 1.60 5.09
2.36E+04 0.77 1.60 5.09 10000 1000
2.28E+04 0.47 1.60 5.09
1.34E+04 1.81 1.60 5.09
6.89E+03 2.55 1.60 5.09
4.30E+03 0.54 1.60 5.09
2.54E+03 0.51 1.60 5.09
1.95E+03 0.53 1.60 5.09
1.29E+05 0.33 1.60 5.09
5.10E+04 1.21 1.60 5.09
2.16E+04 2.16 1.60 5.09 10000 1000
2.15E+04 1.35 1.60 5.09
1.37E+04 0.56 1.60 5.09
6.93E+03 0.67 1.60 5.09
4.19E+03 0.69 1.60 5.09
2.96E+03 1.47 1.60 5.09
1.76E+03 0.36 1.60 5.09
9.93E+00 4.84 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.25E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.45E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.26E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19 AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10 PM EPA Interlab LRef 1314 CFS
1-197
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Se CFS-LRef-1314-T01-A 1 1.91E+03
Se CFS-LRef-1314-T02-A 1 2.97E+02
Se CFS-LRef-1314-T03-A 1 6.54E+01
Se CFS-LRef-1314-T04-A 1 4.67E+01 E
Se CFS-LRef-1314-T05-A 1 3.19E+01 E
Se CFS-LRef-1314-T06-A 1 1.63E+01 E
Se CFS-LRef-1314-T07-A 1 2.02E+01 E
Se CFS-LRef-1314-T08-A 1 7.50E+00 U1/2
Se CFS-LRef-1314-T09-A 1 7.50E+00 U1/2
Se CFS-LRef-1314-T01-B 1 1.74E+03
Se CFS-LRef-1314-T02-B 1 3.38E+02
Se CFS-LRef-1314-T03-B 1 7.03E+01
Se CFS-LRef-1314-T04-B 1 5.16E+01
Se CFS-LRef-1314-T05-B 1 3.76E+01 E
Se CFS-LRef-1314-T06-B 1 2.12E+01 E
Se CFS-LRef-1314-T07-B 1 1.80E+01 E
Se CFS-LRef-1314-T08-B 1 7.50E+00 U1/2
Se CFS-LRef-1314-T09-B 1 7.50E+00 U1/2
Se CFS-LRef-1314-T01-C 1 1.77E+03
Se CFS-LRef-1314-T02-C 1 3.18E+02
Se CFS-LRef-1314-T03-C 1 7.90E+01
Se CFS-LRef-1314-T04-C 1 4.70E+01 E
Se CFS-LRef-1314-T05-C 1 3.72E+01 E
Se CFS-LRef-1314-T06-C 1 2.60E+01 E
Se CFS-LRef-1314-T07-C 1 2.29E+01 E
Se CFS-LRef-1314-T08-C 1 7.50E+00 U1/2
Se CFS-LRef-1314-T09-C 1 7.50E+00 U1/2
Se CFS-LRef-1314-B01-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.91E+03 1.33 15.00 47.70
2.97E+02 5.11 15.00 47.70
6.54E+01 1.23 15.00 47.70 10000 1000
4.67E+01 4.35 15.00 47.70
3.19E+01 39.20 15.00 47.70
1.63E+01 31.35 15.00 47.70
2.02E+01 3.98 15.00 47.70
7.50E+00 10.27 15.00 47.70
7.50E+00 32.39 15.00 47.70
1.74E+03 3.47 15.00 47.70
3.38E+02 5.66 15.00 47.70
7.03E+01 13.98 15.00 47.70 10000 1000
5.16E+01 1.09 15.00 47.70
3.76E+01 3.73 15.00 47.70
2.12E+01 7.54 15.00 47.70
1.80E+01 33.15 15.00 47.70
7.50E+00 12.35 15.00 47.70
7.50E+00 27.64 15.00 47.70
1.77E+03 0.63 15.00 47.70
3.18E+02 3.33 15.00 47.70
7.90E+01 5.17 15.00 47.70 10000 1000
4.70E+01 10.70 15.00 47.70
3.72E+01 12.52 15.00 47.70
2.60E+01 38.42 15.00 47.70
2.29E+01 18.25 15.00 47.70
7.50E+00 36.04 15.00 47.70
7.50E+00 25.62 15.00 47.70
7.50E+00 20.25 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.12E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19 AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10 PM EPA Interlab LRef 1314 CFS
1-198
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Si CFS-LRef-1314-T01-A 1 8.26E+03
Si CFS-LRef-1314-T02-A 1 6.67E+03
Si CFS-LRef-1314-T03-A 1 6.59E+03
Si CFS-LRef-1314-T04-A 1 7.06E+03
Si CFS-LRef-1314-T05-A 1 7.05E+03
Si CFS-LRef-1314-T06-A 1 6.13E+03
Si CFS-LRef-1314-T07-A 1 5.40E+03
Si CFS-LRef-1314-T08-A 1 4.72E+03
Si CFS-LRef-1314-T09-A 1 4.59E+03
Si CFS-LRef-1314-T01-B 1 7.54E+03
Si CFS-LRef-1314-T02-B 1 6.38E+03
Si CFS-LRef-1314-T03-B 1 7.27E+03
Si CFS-LRef-1314-T04-B 1 7.29E+03
Si CFS-LRef-1314-T05-B 1 6.50E+03
Si CFS-LRef-1314-T06-B 1 5.42E+03
Si CFS-LRef-1314-T07-B 1 5.52E+03
Si CFS-LRef-1314-T08-B 1 4.62E+03
Si CFS-LRef-1314-T09-B 1 4.50E+03
Si CFS-LRef-1314-T01-C 1 7.36E+03
Si CFS-LRef-1314-T02-C 1 6.68E+03
Si CFS-LRef-1314-T03-C 1 6.88E+03
Si CFS-LRef-1314-T04-C 1 6.96E+03
Si CFS-LRef-1314-T05-C 1 6.43E+03
Si CFS-LRef-1314-T06-C 1 5.79E+03
Si CFS-LRef-1314-T07-C 1 5.30E+03
Si CFS-LRef-1314-T08-C 1 4.51E+03
Si CFS-LRef-1314-T09-C 1 4.41E+03
Si CFS-LRef-1314-B01-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.26E+03 0.67 1.10 3.50
6.67E+03 0.65 1.10 3.50
6.59E+03 0.63 1.10 3.50 10000 1000
7.06E+03 0.13 1.10 3.50
7.05E+03 1.05 1.10 3.50
6.13E+03 1.41 1.10 3.50
5.40E+03 1.72 1.10 3.50
4.72E+03 7.18 1.10 3.50
4.59E+03 0.56 1.10 3.50
7.54E+03 2.87 1.10 3.50
6.38E+03 0.10 1.10 3.50
7.27E+03 0.53 1.10 3.50 10000 1000
7.29E+03 0.69 1.10 3.50
6.50E+03 9.32 1.10 3.50
5.42E+03 2.24 1.10 3.50
5.52E+03 0.68 1.10 3.50
4.62E+03 0.43 1.10 3.50
4.50E+03 0.68 1.10 3.50
7.36E+03 0.45 1.10 3.50
6.68E+03 1.76 1.10 3.50
6.88E+03 6.85 1.10 3.50 10000 1000
6.96E+03 1.35 1.10 3.50
6.43E+03 1.21 1.10 3.50
5.79E+03 0.02 1.10 3.50
5.30E+03 0.92 1.10 3.50
4.51E+03 1.17 1.10 3.50
4.41E+03 0.37 1.10 3.50
5.50E-01 5.21 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
7.65E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.24E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.85E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19 AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10 PM EPA Interlab LRef 1314 CFS
1-199
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Na CFS-LRef-1314-T01-A 1 3.23E+05
Na CFS-LRef-1314-T02-A 1 6.61E+04
Na CFS-LRef-1314-T03-A 1 8.18E+03
Na CFS-LRef-1314-T04-A 1 4.41 E+03
Na CFS-LRef-1314-T05-A 1 3.06E+03
Na CFS-LRef-1314-T06-A 1 1.89E+03
Na CFS-LRef-1314-T07-A 1 1.39E+03
Na CFS-LRef-1314-T08-A 1 1.01 E+03
Na CFS-LRef-1314-T09-A 1 8.13E+02
Na CFS-LRef-1314-T01-B 1 3.23E+05
Na CFS-LRef-1314-T02-B 1 6.13E+04
Na CFS-LRef-1314-T03-B 1 9.67E+03
Na CFS-LRef-1314-T04-B 1 4.52E+03
Na CFS-LRef-1314-T05-B 1 2.88E+03
Na CFS-LRef-1314-T06-B 1 1.54E+03
Na CFS-LRef-1314-T07-B 1 1.30E+03
Na CFS-LRef-1314-T08-B 1 1.02E+03
Na CFS-LRef-1314-T09-B 1 7.98E+02
Na CFS-LRef-1314-T01-C 1 3.14E+05
Na CFS-LRef-1314-T02-C 1 7.58E+04
Na CFS-LRef-1314-T03-C 1 8.56E+03
Na CFS-LRef-1314-T04-C 1 4.33E+03
Na CFS-LRef-1314-T05-C 1 3.06E+03
Na CFS-LRef-1314-T06-C 1 1.91E+03
Na CFS-LRef-1314-T07-C 1 1.36E+03
Na CFS-LRef-1314-T08-C 1 9.56E+02
Na CFS-LRef-1314-T09-C 1 8.12E+02
Na CFS-LRef-1314-B01-A 1 1.25E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.23E+05 0.38 2.50 8.00
6.61 E+04 0.41 2.50 8.00
8.18E+03 0.45 2.50 8.00 10000 1000
4.41 E+03 0.72 2.50 8.00
3.06E+03 0.34 2.50 8.00
1.89E+03 0.64 2.50 8.00
1.39E+03 1.12 2.50 8.00
1.01 E+03 3.95 2.50 8.00
8.13E+02 0.55 2.50 8.00
3.23E+05 2.93 2.50 8.00
6.13E+04 0.10 2.50 8.00
9.67E+03 2.21 2.50 8.00 10000 1000
4.52E+03 0.59 2.50 8.00
2.88E+03 7.37 2.50 8.00
1.54E+03 0.37 2.50 8.00
1.30E+03 2.06 2.50 8.00
1.02E+03 0.37 2.50 8.00
7.98E+02 0.39 2.50 8.00
3.14E+05 0.44 2.50 8.00
7.58E+04 1.06 2.50 8.00
8.56E+03 1.56 2.50 8.00 10000 1000
4.33E+03 1.49 2.50 8.00
3.06E+03 0.38 2.50 8.00
1.91 E+03 1.39 2.50 8.00
1.36E+03 0.49 2.50 8.00
9.56E+02 0.23 2.50 8.00
8.12E+02 1.27 2.50 8.00
1.25E+00 1.23 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.10E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.50E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10 PM EPA Interlab LRef 1314 CFS
1-200
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Sr CFS-LRef-1314-T01-A 1 5.51E+03
Sr CFS-LRef-1314-T02-A 1 4.24E+03
Sr CFS-LRef-1314-T03-A 1 3.95E+03
Sr CFS-LRef-1314-T04-A 1 3.39E+03
Sr CFS-LRef-1314-T05-A 1 2.56E+03
Sr CFS-LRef-1314-T06-A 1 1.99E+03
Sr CFS-LRef-1314-T07-A 1 1.68E+03
Sr CFS-LRef-1314-T08-A 1 1.47E+03
Sr CFS-LRef-1314-T09-A 1 1.30E+03
Sr CFS-LRef-1314-T01-B 1 5.28E+03
Sr CFS-LRef-1314-T02-B 1 3.91E+03
Sr CFS-LRef-1314-T03-B 1 3.76E+03
Sr CFS-LRef-1314-T04-B 1 3.12E+03
Sr CFS-LRef-1314-T05-B 1 2.29E+03
Sr CFS-LRef-1314-T06-B 1 1.95E+03
Sr CFS-LRef-1314-T07-B 1 1.69E+03
Sr CFS-LRef-1314-T08-B 1 1.44E+03
Sr CFS-LRef-1314-T09-B 1 1.31E+03
Sr CFS-LRef-1314-T01-C 1 5.24E+03
Sr CFS-LRef-1314-T02-C 1 4.06E+03
Sr CFS-LRef-1314-T03-C 1 3.76E+03
Sr CFS-LRef-1314-T04-C 1 3.09E+03
Sr CFS-LRef-1314-T05-C 1 2.30E+03
Sr CFS-LRef-1314-T06-C 1 1.86E+03
Sr CFS-LRef-1314-T07-C 1 1.64E+03
Sr CFS-LRef-1314-T08-C 1 1.40E+03
Sr CFS-LRef-1314-T09-C 1 1.29E+03
Sr CFS-LRef-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.51E+03 0.85 1.00 3.18
4.24E+03 0.95 1.00 3.18
3.95E+03 0.84 1.00 3.18 10000 1000
3.39E+03 0.44 1.00 3.18
2.56E+03 1.14 1.00 3.18
1.99E+03 1.12 1.00 3.18
1.68E+03 1.31 1.00 3.18
1.47E+03 7.04 1.00 3.18
1.30E+03 0.56 1.00 3.18
5.28E+03 3.16 1.00 3.18
3.91E+03 1.38 1.00 3.18
3.76E+03 0.27 1.00 3.18 10000 1000
3.12E+03 1.11 1.00 3.18
2.29E+03 9.17 1.00 3.18
1.95E+03 2.69 1.00 3.18
1.69E+03 0.16 1.00 3.18
1.44E+03 0.32 1.00 3.18
1.31E+03 1.30 1.00 3.18
5.24E+03 0.74 1.00 3.18
4.06E+03 1.40 1.00 3.18
3.76E+03 2.40 1.00 3.18 10000 1000
3.09E+03 2.93 1.00 3.18
2.30E+03 0.84 1.00 3.18
1.86E+03 0.18 1.00 3.18
1.64E+03 1.16 1.00 3.18
1.40E+03 1.00 1.00 3.18
1.29E+03 1.09 1.00 3.18
5.00E-01 45.95 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.97E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.77E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.78E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19 AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10 PM EPA Interlab LRef 1314 CFS
1-201
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
S CFS-LRef-1314-T01-A 1 2.16E+06
S CFS-LRef-1314-T02-A 1 1.02E+06
S CFS-LRef-1314-T03-A 1 6.41E+05
S CFS-LRef-1314-T04-A 1 5.73E+05
S CFS-LRef-1314-T05-A 1 5.82E+05
S CFS-LRef-1314-T06-A 1 5.64E+05
S CFS-LRef-1314-T07-A 1 5.36E+05
S CFS-LRef-1314-T08-A 1 4.87E+05
S CFS-LRef-1314-T09-A 1 4.80E+05
S CFS-LRef-1314-T01-B 1 2.10E+06
S CFS-LRef-1314-T02-B 1 1.05E+06
S CFS-LRef-1314-T03-B 1 6.37E+05
S CFS-LRef-1314-T04-B 1 5.74E+05
S CFS-LRef-1314-T05-B 1 5.55E+05
S CFS-LRef-1314-T06-B 1 5.40E+05
S CFS-LRef-1314-T07-B 1 5.44E+05
S CFS-LRef-1314-T08-B 1 5.31E+05
S CFS-LRef-1314-T09-B 1 5.28E+05
S CFS-LRef-1314-T01-C 1 2.13E+06
S CFS-LRef-1314-T02-C 1 1.02E+06
S CFS-LRef-1314-T03-C 1 6.29E+05
S CFS-LRef-1314-T04-C 1 5.70E+05
S CFS-LRef-1314-T05-C 1 5.45E+05
S CFS-LRef-1314-T06-C 1 5.39E+05
S CFS-LRef-1314-T07-C 1 5.30E+05
S CFS-LRef-1314-T08-C 1 5.50E+05
S CFS-LRef-1314-T09-C 1 5.34E+05
S CFS-LRef-1314-B01-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.16E+06 0.68 6.80 21.60
1.02E+06 1.11 6.80 21.60
6.41E+05 0.32 6.80 21.60 10000 1000
5.73E+05 0.10 6.80 21.60
5.82E+05 0.50 6.80 21.60
5.64E+05 0.65 6.80 21.60
5.36E+05 0.51 6.80 21.60
4.87E+05 1.66 6.80 21.60
4.80E+05 0.71 6.80 21.60
2.10E+06 4.00 6.80 21.60
1.05E+06 0.26 6.80 21.60
6.37E+05 0.92 6.80 21.60 10000 1000
5.74E+05 0.34 6.80 21.60
5.55E+05 1.57 6.80 21.60
5.40E+05 2.87 6.80 21.60
5.44E+05 0.23 6.80 21.60
5.31 E+05 0.70 6.80 21.60
5.28E+05 0.77 6.80 21.60
2.13E+06 0.17 6.80 21.60
1.02E+06 1.65 6.80 21.60
6.29E+05 7.64 6.80 21.60 10000 1000
5.70E+05 1.29 6.80 21.60
5.45E+05 0.43 6.80 21.60
5.39E+05 0.81 6.80 21.60
5.30E+05 0.46 6.80 21.60
5.50E+05 1.34 6.80 21.60
5.34E+05 0.23 6.80 21.60
3.40E+00 10.90 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.42E+05 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.38E+05 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.30E+05 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19 AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10PM EPA Interlab LRef 1314 CFS
1-202
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
Tl CFS-LRef-1314-T01-A 1 1.79E+03
Tl CFS-LRef-1314-T02-A 1 8.57E+02
Tl CFS-LRef-1314-T03-A 1 5.40E+02
Tl CFS-LRef-1314-T04-A 1 5.16E+02
Tl CFS-LRef-1314-T05-A 1 4.08E+02
Tl CFS-LRef-1314-T06-A 1 2.60E+02
Tl CFS-LRef-1314-T07-A 1 1.75E+02
Tl CFS-LRef-1314-T08-A 1 1.24E+02
Tl CFS-LRef-1314-T09-A 1 9.97E+01
Tl CFS-LRef-1314-T01-B 1 1.70E+03
Tl CFS-LRef-1314-T02-B 1 8.44E+02
Tl CFS-LRef-1314-T03-B 1 6.74E+02
Tl CFS-LRef-1314-T04-B 1 5.36E+02
Tl CFS-LRef-1314-T05-B 1 3.65E+02
Tl CFS-LRef-1314-T06-B 1 2.22E+02
Tl CFS-LRef-1314-T07-B 1 1.79E+02
Tl CFS-LRef-1314-T08-B 1 1.04E+02
Tl CFS-LRef-1314-T09-B 1 1.03E+02
Tl CFS-LRef-1314-T01-C 1 1.85E+03
Tl CFS-LRef-1314-T02-C 1 9.47E+02
Tl CFS-LRef-1314-T03-C 1 5.46E+02
Tl CFS-LRef-1314-T04-C 1 5.05E+02
Tl CFS-LRef-1314-T05-C 1 3.69E+02
Tl CFS-LRef-1314-T06-C 1 2.36E+02
Tl CFS-LRef-1314-T07-C 1 1.72E+02
Tl CFS-LRef-1314-T08-C 1 1.20E+02
Tl CFS-LRef-1314-T09-C 1 9.47E+01
Tl CFS-LRef-1314-B01-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.79E+03 1.22 4.60 14.60
8.57E+02 1.71 4.60 14.60
5.40E+02 1.09 4.60 14.60 10000 1000
5.16E+02 0.46 4.60 14.60
4.08E+02 1.21 4.60 14.60
2.60E+02 0.51 4.60 14.60
1.75E+02 1.79 4.60 14.60
1.24E+02 1.36 4.60 14.60
9.97E+01 2.74 4.60 14.60
1.70E+03 3.57 4.60 14.60
8.44E+02 1.01 4.60 14.60
6.74E+02 1.59 4.60 14.60 10000 1000
5.36E+02 0.42 4.60 14.60
3.65E+02 1.54 4.60 14.60
2.22E+02 2.50 4.60 14.60
1.79E+02 1.20 4.60 14.60
1.04E+02 4.79 4.60 14.60
1.03E+02 1.55 4.60 14.60
1.85E+03 0.15 4.60 14.60
9.47E+02 1.12 4.60 14.60
5.46E+02 1.28 4.60 14.60 10000 1000
5.05E+02 0.70 4.60 14.60
3.69E+02 1.53 4.60 14.60
2.36E+02 0.75 4.60 14.60
1.72E+02 1.70 4.60 14.60
1.20E+02 3.91 4.60 14.60
9.47E+01 3.30 4.60 14.60
2.30E+00 4.49 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.62E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.69E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.60E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19 AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10 PM EPA Interlab LRef 1314 CFS
1-203
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L I
Ti CFS-LRef-1314-T01-A 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T02-A 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T03-A 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T04-A 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T05-A 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T06-A 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T07-A 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T08-A 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T09-A 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T01-B 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T02-B 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T03-B 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T04-B 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T05-B 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T06-B 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T07-B 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T08-B 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T09-B 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T01-C 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T02-C 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T03-C 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T04-C 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T05-C 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T06-C 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T07-C 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T08-C 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T09-C 1 1.00E+00 U1/2
Ti CFS-LRef-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 58.02 2.00 6.40
1.00E+00 9.57 2.00 6.40
1.00E+00 30.91 2.00 6.40 10000 1000
1.00E+00 47.32 2.00 6.40
1.00E+00 17.21 2.00 6.40
1.00E+00 18.65 2.00 6.40
1.00E+00 31.45 2.00 6.40
1.00E+00 10.08 2.00 6.40
1.00E+00 94.31 2.00 6.40
1.00E+00 58.29 2.00 6.40
1.00E+00 524.33 2.00 6.40
1.00E+00 76.01 2.00 6.40 10000 1000
1.00E+00 13.16 2.00 6.40
1.00E+00 81.76 2.00 6.40
1.00E+00 37.59 2.00 6.40
1.00E+00 42.56 2.00 6.40
1.00E+00 57.16 2.00 6.40
1.00E+00 70.25 2.00 6.40
1.00E+00 69.63 2.00 6.40
1.00E+00 42.24 2.00 6.40
1.00E+00 71.47 2.00 6.40 10000 1000
1.00E+00 60.45 2.00 6.40
1.00E+00 94.55 2.00 6.40
1.00E+00 28.08 2.00 6.40
1.00E+00 71.47 2.00 6.40
1.00E+00 21.55 2.00 6.40
1.00E+00 49.34 2.00 6.40
1.00E+00 17.72 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19 AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10PM EPA Interlab LRef 1314 CFS
1-204
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 ug/L
V CFS-LRef-1314-T01-A 1 2.00E+01
V CFS-LRef-1314-T02-A 1 3.32E+01
V CFS-LRef-1314-T03-A 1 3.05E+01
V CFS-LRef-1314-T04-A 1 4.07E+01
V CFS-LRef-1314-T05-A 1 4.23E+01
V CFS-LRef-1314-T06-A 1 4.26E+01
V CFS-LRef-1314-T07-A 1 4.07E+01
V CFS-LRef-1314-T08-A 1 3.99E+01
V CFS-LRef-1314-T09-A 1 3.87E+01
V CFS-LRef-1314-T01-B 1 1.94E+01
V CFS-LRef-1314-T02-B 1 2.62E+01
V CFS-LRef-1314-T03-B 1 3.68E+01
V CFS-LRef-1314-T04-B 1 4.04E+01
V CFS-LRef-1314-T05-B 1 3.76E+01
V CFS-LRef-1314-T06-B 1 4.20E+01
V CFS-LRef-1314-T07-B 1 4.20E+01
V CFS-LRef-1314-T08-B 1 4.17E+01
V CFS-LRef-1314-T09-B 1 3.97E+01
V CFS-LRef-1314-T01-C 1 2.44E+01
V CFS-LRef-1314-T02-C 1 3.65E+01
V CFS-LRef-1314-T03-C 1 2.12E+01
V CFS-LRef-1314-T04-C 1 3.93E+01
V CFS-LRef-1314-T05-C 1 3.93E+01
V CFS-LRef-1314-T06-C 1 3.99E+01
V CFS-LRef-1314-T07-C 1 4.12E+01
V CFS-LRef-1314-T08-C 1 4.04E+01
V CFS-LRef-1314-T09-C 1 3.86E+01
V CFS-LRef-1314-B01-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.00E+01 3.79 1.50 4.77
3.32E+01 2.82 1.50 4.77
3.05E+01 2.03 1.50 4.77 10000 1000
4.07E+01 1.07 1.50 4.77
4.23E+01 2.84 1.50 4.77
4.26E+01 1.61 1.50 4.77
4.07E+01 4.06 1.50 4.77
3.99E+01 1.15 1.50 4.77
3.87E+01 3.08 1.50 4.77
1.94E+01 6.27 1.50 4.77
2.62E+01 3.03 1.50 4.77
3.68E+01 1.67 1.50 4.77 10000 1000
4.04E+01 0.92 1.50 4.77
3.76E+01 16.31 1.50 4.77
4.20E+01 2.34 1.50 4.77
4.20E+01 1.53 1.50 4.77
4.17E+01 2.69 1.50 4.77
3.97E+01 1.86 1.50 4.77
2.44E+01 6.78 1.50 4.77
3.65E+01 3.37 1.50 4.77
2.12E+01 5.78 1.50 4.77 10000 1000
3.93E+01 1.76 1.50 4.77
3.93E+01 2.57 1.50 4.77
3.99E+01 1.70 1.50 4.77
4.12E+01 4.04 1.50 4.77
4.04E+01 1.02 1.50 4.77
3.86E+01 1.13 1.50 4.77
7.50E-01 29.86 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.03E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19 AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10 PM EPA Interlab LRef 1314 CFS
1-205
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Zn CFS-LRef-1314-T01-A 1 6.61E+04
Zn CFS-LRef-1314-T02-A 1 3.11E+04
Zn CFS-LRef-1314-T03-A 1 3.38E+04
Zn CFS-LRef-1314-T04-A 1 4.30E+04
Zn CFS-LRef-1314-T05-A 1 4.35E+04
Zn CFS-LRef-1314-T06-A 1 3.95E+04
Zn CFS-LRef-1314-T07-A 1 2.83E+04
Zn CFS-LRef-1314-T08-A 1 1.95E+04
Zn CFS-LRef-1314-T09-A 1 1.66E+04
Zn CFS-LRef-1314-T01-B 1 5.89E+04
Zn CFS-LRef-1314-T02-B 1 3.05E+04
Zn CFS-LRef-1314-T03-B 1 3.38E+04
Zn CFS-LRef-1314-T04-B 1 4.10E+04
Zn CFS-LRef-1314-T05-B 1 4.05E+04
Zn CFS-LRef-1314-T06-B 1 3.61E+04
Zn CFS-LRef-1314-T07-B 1 2.84E+04
Zn CFS-LRef-1314-T08-B 1 2.14E+04
Zn CFS-LRef-1314-T09-B 1 1.53E+04
Zn CFS-LRef-1314-T01-C 1 6.22E+04
Zn CFS-LRef-1314-T02-C 1 3.32E+04
Zn CFS-LRef-1314-T03-C 1 3.18E+04
Zn CFS-LRef-1314-T04-C 1 4.21E+04
Zn CFS-LRef-1314-T05-C 1 4.54E+04
Zn CFS-LRef-1314-T06-C 1 3.46E+04
Zn CFS-LRef-1314-T07-C 1 2.61 E+04
Zn CFS-LRef-1314-T08-C 1 1.87E+04
Zn CFS-LRef-1314-T09-C 1 1.49E+04
Zn CFS-LRef-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.61E+04 0.09 1.00 3.18
3.11E+04 1.02 1.00 3.18
3.38E+04 0.70 1.00 3.18 10000 1000
4.30E+04 1.77 1.00 3.18
4.35E+04 0.73 1.00 3.18
3.95E+04 0.88 1.00 3.18
2.83E+04 1.53 1.00 3.18
1.95E+04 6.34 1.00 3.18
1.66E+04 2.21 1.00 3.18
5.89E+04 19.30 1.00 3.18
3.05E+04 0.34 1.00 3.18
3.38E+04 0.55 1.00 3.18 10000 1000
4.10E+04 0.51 1.00 3.18
4.05E+04 8.82 1.00 3.18
3.61E+04 2.24 1.00 3.18
2.84E+04 0.52 1.00 3.18
2.14E+04 0.09 1.00 3.18
1.53E+04 0.66 1.00 3.18
6.22E+04 0.86 1.00 3.18
3.32E+04 1.08 1.00 3.18
3.18E+04 3.72 1.00 3.18 10000 1000
4.21E+04 1.45 1.00 3.18
4.54E+04 0.91 1.00 3.18
3.46E+04 0.95 1.00 3.18
2.61E+04 0.76 1.00 3.18
1.87E+04 1.97 1.00 3.18
1.49E+04 1.04 1.00 3.18
5.00E-01 11.50 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.47E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.47E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.27E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/11 3:12 PM EPA Interlab LRef 1314 CFS
8/29/11 11:17 AM EPA Interlab LRef 1314 CFS
8/29/11 11:19 AM EPA Interlab LRef 1314 CFS
8/29/11 3:17 PM EPA Interlab LRef 1314 CFS
8/29/11 3:18 PM EPA Interlab LRef 1314 CFS
8/29/11 3:20 PM EPA Interlab LRef 1314 CFS
8/29/11 3:22 PM EPA Interlab LRef 1314 CFS
8/29/11 3:23 PM EPA Interlab LRef 1314 CFS
8/29/11 11:21 AM EPA Interlab LRef 1314 CFS
8/29/11 3:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:22 AM EPA Interlab LRef 1314 CFS
8/29/11 3:30 PM EPA Interlab LRef 1314 CFS
8/29/11 3:31 PM EPA Interlab LRef 1314 CFS
8/29/11 3:33 PM EPA Interlab LRef 1314 CFS
8/29/11 3:35 PM EPA Interlab LRef 1314 CFS
8/29/11 3:36 PM EPA Interlab LRef 1314 CFS
8/29/11 11:24 AM EPA Interlab LRef 1314 CFS
8/29/11 3:40 PM EPA Interlab LRef 1314 CFS
8/29/11 11:26 AM EPA Interlab LRef 1314 CFS
8/29/11 3:50 PM EPA Interlab LRef 1314 CFS
8/29/11 11:39 AM EPA Interlab LRef 1314 CFS
8/29/11 3:53 PM EPA Interlab LRef 1314 CFS
8/29/11 3:54 PM EPA Interlab LRef 1314 CFS
8/29/11 3:56 PM EPA Interlab LRef 1314 CFS
8/29/11 3:58 PM EPA Interlab LRef 1314 CFS
8/29/11 11:48 AM EPA Interlab LRef 1314 CFS
8/29/11 4:01 PM EPA Interlab LRef 1314 CFS
8/29/11 3:10 PM EPA Interlab LRef 1314 CFS
1-206
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1314:
Element
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Dilution Sample
Sample ID Factor Cone. Qualifier
ug/L
CFS-LRef-1314-T01-D 1 5.27E+01
CFS-LRef-1314-T02-D 1 4.85E+01
CFS-LRef-1314-T03-D 1 4.02E+01
CFS-LRef-1314-T04-D 1 4.36E+01
CFS-LRef-1314-T05-D 1 3.93E+01
CFS-LRef-1314-T06-D 1 3.62E+01
CFS-LRef-1314-T07-D 1 3.44E+01
CFS-LRef-1314-T08-D 1 3.63E+01
CFS-LRef-1314-T09-D 1 3.55E+01
CFS-LRef-1314-T01-E 1 4.97E+01
CFS-LRef-1314-T02-E 1 4.56E+01
CFS-LRef-1314-T03-E 1 3.97E+01
CFS-LRef-1314-T04-E 1 4.22E+01
CFS-LRef-1314-T05-E 1 3.90E+01
CFS-LRef-1314-T06-E 1 3.59E+01
CFS-LRef-1314-T07-E 1 3.62E+01
CFS-LRef-1314-T08-E 1 3.61E+01
CFS-LRef-1314-T09-E 1 3.58E+01
CFS-LRef-1314-T01-F 1 5.06E+01
CFS-LRef-1314-T02-F 1 4.80E+01
CFS-LRef-1314-T03-F 1 4.16E+01
CFS-LRef-1314-T04-F 1 4.48E+01
CFS-LRef-1314-T05-F 1 3.90E+01
CFS-LRef-1314-T06-F 1 3.69E+01
CFS-LRef-1314-T07-F 1 3.40E+01
CFS-LRef-1314-T08-F 1 3.55E+01
CFS-LRef-1314-T09-F 1 3.58E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.27E+01 4.60 1.00 3.18
4.85E+01 6.46 1.00 3.18
4.02E+01 8.53 1.00 3.18 10000 1000
4.36E+01 2.40 1.00 3.18
3.93E+01 2.32 1.00 3.18
3.62E+01 4.27 1.00 3.18
3.44E+01 8.80 1.00 3.18
3.63E+01 2.45 1.00 3.18
3.55E+01 3.85 1.00 3.18
4.97E+01 3.42 1.00 3.18
4.56E+01 4.88 1.00 3.18
3.97E+01 5.63 1.00 3.18 10000 1000
4.22E+01 2.53 1.00 3.18
3.90E+01 9.13 1.00 3.18
3.59E+01 4.76 1.00 3.18
3.62E+01 2.29 1.00 3.18
3.61E+01 6.19 1.00 3.18
3.58E+01 6.22 1.00 3.18
5.06E+01 3.78 1.00 3.18
4.80E+01 1.46 1.00 3.18
4.16E+01 2.29 1.00 3.18 10000 1000
4.48E+01 2.73 1.00 3.18
3.90E+01 4.83 1.00 3.18
3.69E+01 5.42 1.00 3.18
3.40E+01 1.09 1.00 3.18
3.55E+01 5.24 1.00 3.18
3.58E+01 1.13 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.11E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/12 3:14 PM EPA Interlab LRef 1314 CFS
3/7/12 3:16 PM EPA Interlab LRef 1314 CFS
3/7/12 3:18 PM EPA Interlab LRef 1314 CFS
3/7/12 3:19 PM EPA Interlab LRef 1314 CFS
3/7/12 3:21 PM EPA Interlab LRef 1314 CFS
3/7/12 3:23 PM EPA Interlab LRef 1314 CFS
3/7/12 3:24 PM EPA Interlab LRef 1314 CFS
3/7/12 3:26 PM EPA Interlab LRef 1314 CFS
3/7/12 3:28 PM EPA Interlab LRef 1314 CFS
3/7/12 3:33 PM EPA Interlab LRef 1314 CFS
3/7/12 3:34 PM EPA Interlab LRef 1314 CFS
3/7/12 3:36 PM EPA Interlab LRef 1314 CFS
3/7/12 3:38 PM EPA Interlab LRef 1314 CFS
3/7/12 3:39 PM EPA Interlab LRef 1314 CFS
3/7/12 3:41 PM EPA Interlab LRef 1314 CFS
3/7/12 3:43 PM EPA Interlab LRef 1314 CFS
3/7/12 3:44 PM EPA Interlab LRef 1314 CFS
3/7/12 3:46 PM EPA Interlab LRef 1314 CFS
3/7/12 3:48 PM EPA Interlab LRef 1314 CFS
3/7/12 3:49 PM EPA Interlab LRef 1314 CFS
3/7/12 3:51 PM EPA Interlab LRef 1314 CFS
3/7/12 3:53 PM EPA Interlab LRef 1314 CFS
3/7/12 3:54 PM EPA Interlab LRef 1314 CFS
3/7/12 3:56 PM EPA Interlab LRef 1314 CFS
3/7/12 3:58 PM EPA Interlab LRef 1314 CFS
3/7/12 3:59 PM EPA Interlab LRef 1314 CFS
3/7/12 4:01 PM EPA Interlab LRef 1314 CFS
1-207
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Sb CFS-LRef-1314-T01-D 1 7.74E+01
Sb CFS-LRef-1314-T02-D 1 3.78E+01
Sb CFS-LRef-1314-T03-D 1 3.25E+01
Sb CFS-LRef-1314-T04-D 1 2.84E+01
Sb CFS-LRef-1314-T05-D 1 2.45E+01
Sb CFS-LRef-1314-T06-D 1 3.16E+01
Sb CFS-LRef-1314-T07-D 1 2.94E+01
Sb CFS-LRef-1314-T08-D 1 2.49E+01
Sb CFS-LRef-1314-T09-D 1 2.67E+01
Sb CFS-LRef-1314-T01-E 1 7.93E+01
Sb CFS-LRef-1314-T02-E 1 4.76E+01
Sb CFS-LRef-1314-T03-E 1 3.31E+01
Sb CFS-LRef-1314-T04-E 1 2.55E+01
Sb CFS-LRef-1314-T05-E 1 2.90E+01
Sb CFS-LRef-1314-T06-E 1 2.19E+01 E
Sb CFS-LRef-1314-T07-E 1 2.77E+01
Sb CFS-LRef-1314-T08-E 1 2.37E+01 E
Sb CFS-LRef-1314-T09-E 1 1.70E+01 E
Sb CFS-LRef-1314-T01-F 1 8.94E+01
Sb CFS-LRef-1314-T02-F 1 4.33E+01
Sb CFS-LRef-1314-T03-F 1 3.22E+01
Sb CFS-LRef-1314-T04-F 1 3.86E+01
Sb CFS-LRef-1314-T05-F 1 3.69E+01
Sb CFS-LRef-1314-T06-F 1 2.84E+01
Sb CFS-LRef-1314-T07-F 1 2.57E+01
Sb CFS-LRef-1314-T08-F 1 2.09E+01 E
Sb CFS-LRef-1314-T09-F 1 1.80E+01 E
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.74E+01 8.84 7.50 23.90
3.78E+01 1.56 7.50 23.90
3.25E+01 4.21 7.50 23.90 10000 1000
2.84E+01 3.37 7.50 23.90
2.45E+01 2.69 7.50 23.90
3.16E+01 0.33 7.50 23.90
2.94E+01 2.69 7.50 23.90
2.49E+01 1.61 7.50 23.90
2.67E+01 1.15 7.50 23.90
7.93E+01 19.08 7.50 23.90
4.76E+01 8.60 7.50 23.90
3.31E+01 2.16 7.50 23.90 10000 1000
2.55E+01 3.72 7.50 23.90
2.90E+01 8.72 7.50 23.90
2.19E+01 14.46 7.50 23.90
2.77E+01 1.15 7.50 23.90
2.37E+01 18.79 7.50 23.90
1.70E+01 8.67 7.50 23.90
8.94E+01 6.94 7.50 23.90
4.33E+01 1.41 7.50 23.90
3.22E+01 4.63 7.50 23.90 10000 1000
3.86E+01 2.68 7.50 23.90
3.69E+01 2.56 7.50 23.90
2.84E+01 0.68 7.50 23.90
2.57E+01 9.65 7.50 23.90
2.09E+01 13.62 7.50 23.90
1.80E+01 22.31 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/11 4:11 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:32 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:34 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:36 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:37 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:39 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:41 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:42 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:44 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:46 PM EPA Interlab LRef 1314 CFS
8/29/11 11:57 AM EPA Interlab LRef 1314 CFS
8/29/11 4:49 PM EPA Interlab LRef 1314 CFS
8/29/11 4:51 PM EPA Interlab LRef 1314 CFS
8/29/11 4:52 PM EPA Interlab LRef 1314 CFS
1-208
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L
As CFS-LRef-1314-T01-D 1 4.83E+01
As CFS-LRef-1314-T02-D 1 3.78E+01
As CFS-LRef-1314-T03-D 1 1.43E+01 E
As CFS-LRef-1314-T04-D 1 1.88E+01 E
As CFS-LRef-1314-T05-D 1 2.14E+01 E
As CFS-LRef-1314-T06-D 1 2.22E+01 E
As CFS-LRef-1314-T07-D 1 2.16E+01 E
As CFS-LRef-1314-T08-D 1 1.38E+01 E
As CFS-LRef-1314-T09-D 1 1.74E+01 E
As CFS-LRef-1314-T01-E 1 5.42E+01
As CFS-LRef-1314-T02-E 1 2.59E+01 E
As CFS-LRef-1314-T03-E 1 1.43E+01 E
As CFS-LRef-1314-T04-E 1 2.10E+01 E
As CFS-LRef-1314-T05-E 1 1.80E+01 E
As CFS-LRef-1314-T06-E 1 1.90E+01 E
As CFS-LRef-1314-T07-E 1 2.29E+01 E
As CFS-LRef-1314-T08-E 1 1.81E+01 E
As CFS-LRef-1314-T09-E 1 2.46E+01 E
As CFS-LRef-1314-T01-F 1 6.75E+01
As CFS-LRef-1314-T02-F 1 3.11E+01 E
As CFS-LRef-1314-T03-F 1 1.59E+01 E
As CFS-LRef-1314-T04-F 1 2.92E+01 E
As CFS-LRef-1314-T05-F 1 2.38E+01 E
As CFS-LRef-1314-T06-F 1 2.04E+01 E
As CFS-LRef-1314-T07-F 1 2.11E+01 E
As CFS-LRef-1314-T08-F 1 2.07E+01 E
As CFS-LRef-1314-T09-F 1 1.84E+01 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.83E+01 1.20 11.00 35.00
3.78E+01 2.01 11.00 35.00
1.43E+01 6.57 11.00 35.00 10000 1000
1.88E+01 24.16 11.00 35.00
2.14E+01 20.92 11.00 35.00
2.22E+01 2.82 11.00 35.00
2.16E+01 18.16 11.00 35.00
1.38E+01 5.09 11.00 35.00
1.74E+01 1.81 11.00 35.00
5.42E+01 10.62 11.00 35.00
2.59E+01 35.29 11.00 35.00
1.43E+01 15.42 11.00 35.00 10000 1000
2.10E+01 32.08 11.00 35.00
1.80E+01 33.68 11.00 35.00
1.90E+01 24.32 11.00 35.00
2.29E+01 31.86 11.00 35.00
1.81E+01 43.46 11.00 35.00
2.46E+01 1.73 11.00 35.00
6.75E+01 8.48 11.00 35.00
3.11E+01 3.61 11.00 35.00
1.59E+01 22.22 11.00 35.00 10000 1000
2.92E+01 32.86 11.00 35.00
2.38E+01 14.27 11.00 35.00
2.04E+01 30.68 11.00 35.00
2.11E+01 5.67 11.00 35.00
2.07E+01 5.15 11.00 35.00
1.84E+01 6.14 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 . 1 1 E+03 1 09% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:1 1 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:32 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:34 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:36 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:37 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:39 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:41 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:42 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:44 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:46 PM EPA Interlab LRef 1314 CFS
8/29/11 11:57 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:49 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:51 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:52 PM EPA Interlab LRef 1314 CFS
1-209
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
B CFS-LRef-1314-T01-D 1 1.90E+03
B CFS-LRef-1314-T02-D 1 1.39E+03
B CFS-LRef-1314-T03-D 1 4.61E+02
B CFS-LRef-1314-T04-D 1 2.42E+02
B CFS-LRef-1314-T05-D 1 1.57E+02
B CFS-LRef-1314-T06-D 1 9.23E+01
B CFS-LRef-1314-T07-D 1 6.76E+01
B CFS-LRef-1314-T08-D 1 4.81E+01
B CFS-LRef-1314-T09-D 1 3.98E+01
B CFS-LRef-1314-T01-E 1 2.10E+03
B CFS-LRef-1314-T02-E 1 1.47E+03
B CFS-LRef-1314-T03-E 1 4.37E+02
B CFS-LRef-1314-T04-E 1 2.41E+02
B CFS-LRef-1314-T05-E 1 1.53E+02
B CFS-LRef-1314-T06-E 1 9.79E+01
B CFS-LRef-1314-T07-E 1 7.03E+01
B CFS-LRef-1314-T08-E 1 5.04E+01
B CFS-LRef-1314-T09-E 1 3.96E+01
B CFS-LRef-1314-T01-F 1 2.32E+03
B CFS-LRef-1314-T02-F 1 1.54E+03
B CFS-LRef-1314-T03-F 1 4.87E+02
B CFS-LRef-1314-T04-F 1 2.47E+02
B CFS-LRef-1314-T05-F 1 1.62E+02
B CFS-LRef-1314-T06-F 1 9.40E+01
B CFS-LRef-1314-T07-F 1 6.91 E+01
B CFS-LRef-1314-T08-F 1 5.08E+01
B CFS-LRef-1314-T09-F 1 4.52E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.90E+03 0.23 1.00 3.18
1.39E+03 0.76 1.00 3.18
4.61E+02 0.37 1.00 3.18 10000 1000
2.42E+02 0.48 1.00 3.18
1.57E+02 0.36 1.00 3.18
9.23E+01 0.46 1.00 3.18
6.76E+01 2.91 1.00 3.18
4.81E+01 1.95 1.00 3.18
3.98E+01 4.26 1.00 3.18
2.10E+03 0.96 1.00 3.18
1.47E+03 0.39 1.00 3.18
4.37E+02 1.32 1.00 3.18 10000 1000
2.41E+02 1.03 1.00 3.18
1.53E+02 1.53 1.00 3.18
9.79E+01 0.76 1.00 3.18
7.03E+01 2.60 1.00 3.18
5.04E+01 2.48 1.00 3.18
3.96E+01 1.75 1.00 3.18
2.32E+03 0.30 1.00 3.18
1.54E+03 0.62 1.00 3.18
4.87E+02 2.31 1.00 3.18 10000 1000
2.47E+02 0.64 1.00 3.18
1.62E+02 2.14 1.00 3.18
9.40E+01 1.63 1.00 3.18
6.91E+01 1.24 1.00 3.18
5.08E+01 1.71 1.00 3.18
4.52E+01 6.74 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.37E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.33E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.32E+03 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:1 1 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/11 4:32 PM EPA Interlab LRef 1314 CFS
8/29/11 4:34 PM EPA Interlab LRef 1314 CFS
8/29/11 4:36 PM EPA Interlab LRef 1314 CFS
8/29/11 4:37 PM EPA Interlab LRef 1314 CFS
8/29/11 4:39 PM EPA Interlab LRef 1314 CFS
8/29/11 4:41 PM EPA Interlab LRef 1314 CFS
8/29/11 4:42 PM EPA Interlab LRef 1314 CFS
8/29/11 4:44 PM EPA Interlab LRef 1314 CFS
8/29/11 4:46 PM EPA Interlab LRef 1314 CFS
8/29/1 1 1 1 :57 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:49 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:51 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:52 PM EPA Interlab LRef 1314 CFS
1-210
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Ba CFS-LRef-1314-T01-D 1 4.29E+01
Ba CFS-LRef-1314-T02-D 1 5.25E+01
Ba CFS-LRef-1314-T03-D 1 9.35E+01
Ba CFS-LRef-1314-T04-D 1 1.25E+02
Ba CFS-LRef-1314-T05-D 1 1.24E+02
Ba CFS-LRef-1314-T06-D 1 1.24E+02
Ba CFS-LRef-1314-T07-D 1 1.36E+02
Ba CFS-LRef-1314-T08-D 1 1.31E+02
Ba CFS-LRef-1314-T09-D 1 1.36E+02
Ba CFS-LRef-1314-T01-E 1 4.73E+01
Ba CFS-LRef-1314-T02-E 1 4.94E+01
Ba CFS-LRef-1314-T03-E 1 9.27E+01
Ba CFS-LRef-1314-T04-E 1 1.20E+02
Ba CFS-LRef-1314-T05-E 1 1.17E+02
Ba CFS-LRef-1314-T06-E 1 1.31E+02
Ba CFS-LRef-1314-T07-E 1 1.39E+02
Ba CFS-LRef-1314-T08-E 1 1.38E+02
Ba CFS-LRef-1314-T09-E 1 1.43E+02
Ba CFS-LRef-1314-T01-F 1 5.65E+01
Ba CFS-LRef-1314-T02-F 1 6.09E+01
Ba CFS-LRef-1314-T03-F 1 9.79E+01
Ba CFS-LRef-1314-T04-F 1 1.23E+02
Ba CFS-LRef-1314-T05-F 1 1.24E+02
Ba CFS-LRef-1314-T06-F 1 1.31E+02
Ba CFS-LRef-1314-T07-F 1 1.39E+02
Ba CFS-LRef-1314-T08-F 1 1.42E+02
Ba CFS-LRef-1314-T09-F 1 1.53E+02
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.29E+01 1.03 1.00 3.18
5.25E+01 0.26 1.00 3.18
9.35E+01 0.40 1.00 3.18 10000 1000
1.25E+02 0.54 1.00 3.18
1.24E+02 0.80 1.00 3.18
1.24E+02 0.42 1.00 3.18
1.36E+02 0.70 1.00 3.18
1.31E+02 0.91 1.00 3.18
1.36E+02 0.40 1.00 3.18
4.73E+01 0.87 1.00 3.18
4.94E+01 0.95 1.00 3.18
9.27E+01 1.19 1.00 3.18 10000 1000
1.20E+02 0.60 1.00 3.18
1.17E+02 0.37 1.00 3.18
1.31E+02 0.71 1.00 3.18
1.39E+02 0.89 1.00 3.18
1.38E+02 0.34 1.00 3.18
1.43E+02 1.00 1.00 3.18
5.65E+01 0.56 1.00 3.18
6.09E+01 0.35 1.00 3.18
9.79E+01 3.64 1.00 3.18 10000 1000
1.23E+02 1.07 1.00 3.18
1.24E+02 0.80 1.00 3.18
1.31E+02 0.77 1.00 3.18
1.39E+02 0.53 1.00 3.18
1.42E+02 0.60 1.00 3.18
1.53E+02 8.40 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.09E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/11 4:11 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:32 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:34 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:36 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:37 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:39 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:41 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:42 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:44 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:46 PM EPA Interlab LRef 1314 CFS
8/29/11 11:57 AM EPA Interlab LRef 1314 CFS
8/29/11 4:49 PM EPA Interlab LRef 1314 CFS
8/29/11 4:51 PM EPA Interlab LRef 1314 CFS
8/29/11 4:52 PM EPA Interlab LRef 1314 CFS
1-211
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Be CFS-LRef-1314-T01-D 1 9.50E-01 U1/2
Be CFS-LRef-1314-T02-D 1 9.50E-01 U1/2
Be CFS-LRef-1314-T03-D 1 9.50E-01 U1/2
Be CFS-LRef-1314-T04-D 1 9.50E-01 U1/2
Be CFS-LRef-1314-T05-D 1 9.50E-01 U1/2
Be CFS-LRef-1314-T06-D 1 9.50E-01 U1/2
Be CFS-LRef-1314-T07-D 1 9.50E-01 U1/2
Be CFS-LRef-1314-T08-D 1 9.50E-01 U1/2
Be CFS-LRef-1314-T09-D 1 9.50E-01 U1/2
Be CFS-LRef-1314-T01-E 1 9.50E-01 U1/2
Be CFS-LRef-1314-T02-E 1 9.50E-01 U1/2
Be CFS-LRef-1314-T03-E 1 9.50E-01 U1/2
Be CFS-LRef-1314-T04-E 1 9.50E-01 U1/2
Be CFS-LRef-1314-T05-E 1 9.50E-01 U1/2
Be CFS-LRef-1314-T06-E 1 9.50E-01 U1/2
Be CFS-LRef-1314-T07-E 1 9.50E-01 U1/2
Be CFS-LRef-1314-T08-E 1 9.50E-01 U1/2
Be CFS-LRef-1314-T09-E 1 9.50E-01 U1/2
Be CFS-LRef-1314-T01-F 1 9.50E-01 U1/2
Be CFS-LRef-1314-T02-F 1 9.50E-01 U1/2
Be CFS-LRef-1314-T03-F 1 9.50E-01 U1/2
Be CFS-LRef-1314-T04-F 1 9.50E-01 U1/2
Be CFS-LRef-1314-T05-F 1 9.50E-01 U1/2
Be CFS-LRef-1314-T06-F 1 9.50E-01 U1/2
Be CFS-LRef-1314-T07-F 1 9.50E-01 U1/2
Be CFS-LRef-1314-T08-F 1 9.50E-01 U1/2
Be CFS-LRef-1314-T09-F 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 24.69 1.90 6.00
9.50E-01 34.32 1.90 6.00
9.50E-01 13.71 1.90 6.00 10000 1000
9.50E-01 24.01 1.90 6.00
9.50E-01 23.97 1.90 6.00
9.50E-01 41.02 1.90 6.00
9.50E-01 43.91 1.90 6.00
9.50E-01 7.80 1.90 6.00
9.50E-01 43.15 1.90 6.00
9.50E-01 5.75 1.90 6.00
9.50E-01 27.39 1.90 6.00
9.50E-01 12.70 1.90 6.00 10000 1000
9.50E-01 21.42 1.90 6.00
9.50E-01 28.97 1.90 6.00
9.50E-01 46.46 1.90 6.00
9.50E-01 20.89 1.90 6.00
9.50E-01 24.67 1.90 6.00
9.50E-01 59.98 1.90 6.00
9.50E-01 26.20 1.90 6.00
9.50E-01 38.84 1.90 6.00
9.50E-01 50.82 1.90 6.00 10000 1000
9.50E-01 27.72 1.90 6.00
9.50E-01 9.28 1.90 6.00
9.50E-01 19.81 1.90 6.00
9.50E-01 37.80 1.90 6.00
9.50E-01 20.15 1.90 6.00
9.50E-01 42.53 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.77E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:1 1 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:32 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:34 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:36 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:37 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:39 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:41 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:42 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:44 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:46 PM EPA Interlab LRef 1314 CFS
8/29/11 11:57 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:49 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:51 PM EPA Interlab LRef 1314 CFS
8/29/11 4:52 PM EPA Interlab LRef 1314 CFS
1-212
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Cd CFS-LRef-1314-T01-D 1 1.46E+04
Cd CFS-LRef-1314-T02-D 1 7.07E+03
Cd CFS-LRef-1314-T03-D 1 6.75E+03
Cd CFS-LRef-1314-T04-D 1 7.33E+03
Cd CFS-LRef-1314-T05-D 1 7.76E+03
Cd CFS-LRef-1314-T06-D 1 6.70E+03
Cd CFS-LRef-1314-T07-D 1 5.53E+03
Cd CFS-LRef-1314-T08-D 1 3.94E+03
Cd CFS-LRef-1314-T09-D 1 3.15E+03
Cd CFS-LRef-1314-T01-E 1 1.56E+04
Cd CFS-LRef-1314-T02-E 1 9.06E+03
Cd CFS-LRef-1314-T03-E 1 6.68E+03
Cd CFS-LRef-1314-T04-E 1 8.59E+03
Cd CFS-LRef-1314-T05-E 1 8.28E+03
Cd CFS-LRef-1314-T06-E 1 7.18E+03
Cd CFS-LRef-1314-T07-E 1 5.70E+03
Cd CFS-LRef-1314-T08-E 1 4.03E+03
Cd CFS-LRef-1314-T09-E 1 3.16E+03
Cd CFS-LRef-1314-T01-F 1 1.65E+04
Cd CFS-LRef-1314-T02-F 1 9.24E+03
Cd CFS-LRef-1314-T03-F 1 6.96E+03
Cd CFS-LRef-1314-T04-F 1 8.22E+03
Cd CFS-LRef-1314-T05-F 1 8.84E+03
Cd CFS-LRef-1314-T06-F 1 7.21E+03
Cd CFS-LRef-1314-T07-F 1 5.86E+03
Cd CFS-LRef-1314-T08-F 1 4.23E+03
Cd CFS-LRef-1314-T09-F 1 3.52E+03
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.46E+04 0.64 2.20 7.00
7.07E+03 0.37 2.20 7.00
6.75E+03 0.54 2.20 7.00 10000 1000
7.33E+03 0.45 2.20 7.00
7.76E+03 0.44 2.20 7.00
6.70E+03 0.56 2.20 7.00
5.53E+03 0.43 2.20 7.00
3.94E+03 0.94 2.20 7.00
3.15E+03 0.83 2.20 7.00
1.56E+04 1.17 2.20 7.00
9.06E+03 0.38 2.20 7.00
6.68E+03 1.14 2.20 7.00 10000 1000
8.59E+03 0.57 2.20 7.00
8.28E+03 0.57 2.20 7.00
7.18E+03 0.45 2.20 7.00
5.70E+03 1.08 2.20 7.00
4.03E+03 0.27 2.20 7.00
3.16E+03 1.15 2.20 7.00
1.65E+04 0.26 2.20 7.00
9.24E+03 0.61 2.20 7.00
6.96E+03 1.57 2.20 7.00 10000 1000
8.22E+03 1.11 2.20 7.00
8.84E+03 0.79 2.20 7.00
7.21E+03 0.23 2.20 7.00
5.86E+03 0.73 2.20 7.00
4.23E+03 1.14 2.20 7.00
3.52E+03 9.39 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
7.71E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.61E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.93E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/11 4:11 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:32 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:34 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:36 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:37 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:39 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:41 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:42 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:44 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:46 PM EPA Interlab LRef 1314 CFS
8/29/11 11:57 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:49 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:51 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:52 PM EPA Interlab LRef 1314 CFS
1-213
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Ca CFS-LRef-1314-T01-D 1 5.06E+05
Ca CFS-LRef-1314-T02-D 1 5.74E+05
Ca CFS-LRef-1314-T03-D 1 5.13E+05
Ca CFS-LRef-1314-T04-D 1 6.69E+05
Ca CFS-LRef-1314-T05-D 1 6.60E+05
Ca CFS-LRef-1314-T06-D 1 6.56E+05
Ca CFS-LRef-1314-T07-D 1 6.82E+05
Ca CFS-LRef-1314-T08-D 1 6.35E+05
Ca CFS-LRef-1314-T09-D 1 6.57E+05
Ca CFS-LRef-1314-T01-E 1 4.90E+05
Ca CFS-LRef-1314-T02-E 1 5.58E+05
Ca CFS-LRef-1314-T03-E 1 5.29E+05
Ca CFS-LRef-1314-T04-E 1 6.54E+05
Ca CFS-LRef-1314-T05-E 1 6.33E+05
Ca CFS-LRef-1314-T06-E 1 6.79E+05
Ca CFS-LRef-1314-T07-E 1 6.87E+05
Ca CFS-LRef-1314-T08-E 1 6.56E+05
Ca CFS-LRef-1314-T09-E 1 6.72E+05
Ca CFS-LRef-1314-T01-F 1 4.95E+05
Ca CFS-LRef-1314-T02-F 1 5.65E+05
Ca CFS-LRef-1314-T03-F 1 5.33E+05
Ca CFS-LRef-1314-T04-F 1 6.43E+05
Ca CFS-LRef-1314-T05-F 1 6.80E+05
Ca CFS-LRef-1314-T06-F 1 6.83E+05
Ca CFS-LRef-1314-T07-F 1 6.93E+05
Ca CFS-LRef-1314-T08-F 1 6.74E+05
Ca CFS-LRef-1314-T09-F 1 7.24E+05
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.06E+05 0.65 2.60 8.30
5.74E+05 0.13 2.60 8.30
5.13E+05 0.53 2.60 8.30 10000 1000
6.69E+05 0.13 2.60 8.30
6.60E+05 0.54 2.60 8.30
6.56E+05 0.48 2.60 8.30
6.82E+05 0.26 2.60 8.30
6.35E+05 0.92 2.60 8.30
6.57E+05 0.77 2.60 8.30
4.90E+05 1.27 2.60 8.30
5.58E+05 0.67 2.60 8.30
5.29E+05 1.09 2.60 8.30 10000 1000
6.54E+05 0.62 2.60 8.30
6.33E+05 0.51 2.60 8.30
6.79E+05 0.21 2.60 8.30
6.87E+05 1.09 2.60 8.30
6.56E+05 0.48 2.60 8.30
6.72E+05 1.29 2.60 8.30
4.95E+05 0.39 2.60 8.30
5.65E+05 0.39 2.60 8.30
5.33E+05 0.88 2.60 8.30 10000 1000
6.43E+05 1.34 2.60 8.30
6.80E+05 0.93 2.60 8.30
6.83E+05 0.42 2.60 8.30
6.93E+05 0.74 2.60 8.30
6.74E+05 0.91 2.60 8.30
7.24E+05 9.64 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.14E+05 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.30E+05 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.34E+05 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/11 4:11 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:32 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:34 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:36 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:37 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:39 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:41 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:42 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:44 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:46 PM EPA Interlab LRef 1314 CFS
8/29/11 11:57 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:49 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:51 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:52 PM EPA Interlab LRef 1314 CFS
1-214
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Cr CFS-LRef-1314-T01-D 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T02-D 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T03-D 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T04-D 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T05-D 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T06-D 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T07-D 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T08-D 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T09-D 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T01-E 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T02-E 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T03-E 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T04-E 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T05-E 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T06-E 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T07-E 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T08-E 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T09-E 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T01-F 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T02-F 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T03-F 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T04-F 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T05-F 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T06-F 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T07-F 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T08-F 1 6.00E-01 U1/2
Cr CFS-LRef-1314-T09-F 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 64.63 1.20 3.82
6.00E-01 10.53 1.20 3.82
6.00E-01 44.92 1.20 3.82 10000 1000
6.00E-01 37.50 1.20 3.82
6.00E-01 68.89 1.20 3.82
6.00E-01 47.52 1.20 3.82
6.00E-01 61.79 1.20 3.82
6.00E-01 22.27 1.20 3.82
6.00E-01 41.58 1.20 3.82
6.00E-01 13.56 1.20 3.82
6.00E-01 12.46 1.20 3.82
6.00E-01 50.67 1.20 3.82 10000 1000
6.00E-01 52.93 1.20 3.82
6.00E-01 72.81 1.20 3.82
6.00E-01 42.43 1.20 3.82
6.00E-01 25.07 1.20 3.82
6.00E-01 53.66 1.20 3.82
6.00E-01 15.96 1.20 3.82
6.00E-01 12.10 1.20 3.82
6.00E-01 30.60 1.20 3.82
6.00E-01 49.55 1.20 3.82 10000 1000
6.00E-01 0.75 1.20 3.82
6.00E-01 13.60 1.20 3.82
6.00E-01 37.52 1.20 3.82
6.00E-01 38.19 1.20 3.82
6.00E-01 11.66 1.20 3.82
6.00E-01 53.67 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.18E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.99E+02 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.37E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:1 1 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:32 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:34 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:36 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:37 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:39 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:41 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:42 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:44 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:46 PM EPA Interlab LRef 1314 CFS
8/29/11 11:57 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:49 PM EPA Interlab LRef 1314 CFS
8/29/11 4:51 PM EPA Interlab LRef 1314 CFS
8/29/11 4:52 PM EPA Interlab LRef 1314 CFS
1-215
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Co CFS-LRef-1314-T01-D 1 7.22E+02
Co CFS-LRef-1314-T02-D 1 2.66E+02
Co CFS-LRef-1314-T03-D 1 2.28E+02
Co CFS-LRef-1314-T04-D 1 2.90E+02
Co CFS-LRef-1314-T05-D 1 2.89E+02
Co CFS-LRef-1314-T06-D 1 1.39E+02
Co CFS-LRef-1314-T07-D 1 6.52E+01
Co CFS-LRef-1314-T08-D 1 3.58E+01
Co CFS-LRef-1314-T09-D 1 2.41E+01
Co CFS-LRef-1314-T01-E 1 7.21E+02
Co CFS-LRef-1314-T02-E 1 4.00E+02
Co CFS-LRef-1314-T03-E 1 2.46E+02
Co CFS-LRef-1314-T04-E 1 3.32E+02
Co CFS-LRef-1314-T05-E 1 2.81E+02
Co CFS-LRef-1314-T06-E 1 1.33E+02
Co CFS-LRef-1314-T07-E 1 6.18E+01
Co CFS-LRef-1314-T08-E 1 3.49E+01
Co CFS-LRef-1314-T09-E 1 2.38E+01
Co CFS-LRef-1314-T01-F 1 7.40E+02
Co CFS-LRef-1314-T02-F 1 3.98E+02
Co CFS-LRef-1314-T03-F 1 2.84E+02
Co CFS-LRef-1314-T04-F 1 3.41E+02
Co CFS-LRef-1314-T05-F 1 3.34E+02
Co CFS-LRef-1314-T06-F 1 1.37E+02
Co CFS-LRef-1314-T07-F 1 6.35E+01
Co CFS-LRef-1314-T08-F 1 3.78E+01
Co CFS-LRef-1314-T09-F 1 2.67E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.22E+02 0.42 1.80 5.72
2.66E+02 0.77 1.80 5.72
2.28E+02 0.37 1.80 5.72 10000 1000
2.90E+02 0.31 1.80 5.72
2.89E+02 0.73 1.80 5.72
1.39E+02 1.30 1.80 5.72
6.52E+01 1.65 1.80 5.72
3.58E+01 2.21 1.80 5.72
2.41 E+01 4.41 1.80 5.72
7.21 E+02 2.21 1.80 5.72
4.00E+02 0.32 1.80 5.72
2.46E+02 1.00 1.80 5.72 10000 1000
3.32E+02 1.12 1.80 5.72
2.81 E+02 1.00 1.80 5.72
1.33E+02 0.64 1.80 5.72
6.18E+01 1.41 1.80 5.72
3.49E+01 2.10 1.80 5.72
2.38E+01 7.88 1.80 5.72
7.40E+02 1.67 1.80 5.72
3.98E+02 0.45 1.80 5.72
2.84E+02 13.10 1.80 5.72 10000 1000
3.41 E+02 1.66 1.80 5.72
3.34E+02 0.91 1.80 5.72
1.37E+02 0.59 1.80 5.72
6.35E+01 0.96 1.80 5.72
3.78E+01 5.75 1.80 5.72
2.67E+01 6.89 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.18E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.38E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.30E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/11 4:11 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:32 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:34 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:36 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:37 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:39 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:41 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:42 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:44 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:46 PM EPA Interlab LRef 1314 CFS
8/29/11 11:57 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:49 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:51 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:52 PM EPA Interlab LRef 1314 CFS
1-216
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Cu CFS-LRef-1314-T01-D 1 2.51E+03
Cu CFS-LRef-1314-T02-D 1 1.28E+03
Cu CFS-LRef-1314-T03-D 1 1.64E+03
Cu CFS-LRef-1314-T04-D 1 1.08E+03
Cu CFS-LRef-1314-T05-D 1 9.42E+02
Cu CFS-LRef-1314-T06-D 1 1.14E+03
Cu CFS-LRef-1314-T07-D 1 8.13E+02
Cu CFS-LRef-1314-T08-D 1 7.88E+02
Cu CFS-LRef-1314-T09-D 1 7.02E+02
Cu CFS-LRef-1314-T01-E 1 2.64E+03
Cu CFS-LRef-1314-T02-E 1 1.81E+03
Cu CFS-LRef-1314-T03-E 1 1.51E+03
Cu CFS-LRef-1314-T04-E 1 1.13E+03
Cu CFS-LRef-1314-T05-E 1 1.14E+03
Cu CFS-LRef-1314-T06-E 1 1.21E+03
Cu CFS-LRef-1314-T07-E 1 9.26E+02
Cu CFS-LRef-1314-T08-E 1 8.47E+02
Cu CFS-LRef-1314-T09-E 1 7.93E+02
Cu CFS-LRef-1314-T01-F 1 2.71E+03
Cu CFS-LRef-1314-T02-F 1 1.95E+03
Cu CFS-LRef-1314-T03-F 1 1.69E+03
Cu CFS-LRef-1314-T04-F 1 9.89E+02
Cu CFS-LRef-1314-T05-F 1 1.15E+03
Cu CFS-LRef-1314-T06-F 1 1.22E+03
Cu CFS-LRef-1314-T07-F 1 1.23E+03
Cu CFS-LRef-1314-T08-F 1 8.10E+02
Cu CFS-LRef-1314-T09-F 1 8.79E+02
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.51 E+03 1.06 3.70 11.80
1.28E+03 1.30 3.70 11.80
1.64E+03 0.88 3.70 11.80 10000 1000
1.08E+03 10.59 3.70 11.80
9.42E+02 1.18 3.70 11.80
1.14E+03 0.81 3.70 11.80
8.13E+02 0.72 3.70 11.80
7.88E+02 0.86 3.70 11.80
7.02E+02 0.31 3.70 11.80
2.64E+03 2.12 3.70 11.80
1.81E+03 1.33 3.70 11.80
1.51E+03 2.06 3.70 11.80 10000 1000
1.13E+03 1.26 3.70 11.80
1.14E+03 0.47 3.70 11.80
1.21E+03 0.47 3.70 11.80
9.26E+02 1.07 3.70 11.80
8.47E+02 0.27 3.70 11.80
7.93E+02 0.75 3.70 11.80
2.71 E+03 1.51 3.70 11.80
1.95E+03 0.79 3.70 11.80
1.69E+03 7.56 3.70 11.80 10000 1000
9.89E+02 1.29 3.70 11.80
1.15E+03 0.64 3.70 11.80
1.22E+03 0.77 3.70 11.80
1.23E+03 1.27 3.70 11.80
8.10E+02 0.48 3.70 11.80
8.79E+02 6.59 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.64E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.61E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.74E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:1 1 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/11 11:53 AM EPA Interlab LRef 1314 CFS
8/29/11 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/11 4:29 PM EPA Interlab LRef 1314 CFS
8/29/11 4:31 PM EPA Interlab LRef 1314 CFS
8/29/11 4:32 PM EPA Interlab LRef 1314 CFS
8/29/11 4:34 PM EPA Interlab LRef 1314 CFS
8/29/11 4:36 PM EPA Interlab LRef 1314 CFS
8/29/11 4:37 PM EPA Interlab LRef 1314 CFS
8/29/11 4:39 PM EPA Interlab LRef 1314 CFS
8/29/11 4:41 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:42 PM EPA Interlab LRef 1314 CFS
8/29/11 4:44 PM EPA Interlab LRef 1314 CFS
8/29/11 4:46 PM EPA Interlab LRef 1314 CFS
8/29/11 11:57 AM EPA Interlab LRef 1314 CFS
8/29/11 4:49 PM EPA Interlab LRef 1314 CFS
8/29/11 4:51 PM EPA Interlab LRef 1314 CFS
8/29/11 4:52 PM EPA Interlab LRef 1314 CFS
1-217
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Fe CFS-LRef-1314-T01-D 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T02-D 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T03-D 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T04-D 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T05-D 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T06-D 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T07-D 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T08-D 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T09-D 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T01-E 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T02-E 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T03-E 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T04-E 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T05-E 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T06-E 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T07-E 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T08-E 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T09-E 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T01-F 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T02-F 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T03-F 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T04-F 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T05-F 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T06-F 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T07-F 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T08-F 1 1.00E+00 U1/2
Fe CFS-LRef-1314-T09-F 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 13.02 2.00 6.40
1.00E+00 15.32 2.00 6.40
1.00E+00 16.81 2.00 6.40 10000 1000
1.00E+00 12.52 2.00 6.40
1.00E+00 25.06 2.00 6.40
1.00E+00 32.10 2.00 6.40
1.00E+00 22.06 2.00 6.40
1.00E+00 13.92 2.00 6.40
1.00E+00 20.98 2.00 6.40
1.00E+00 9.67 2.00 6.40
1.00E+00 22.67 2.00 6.40
1.00E+00 5.33 2.00 6.40 10000 1000
1.00E+00 14.17 2.00 6.40
1.00E+00 31.33 2.00 6.40
1.00E+00 14.35 2.00 6.40
1.00E+00 21.85 2.00 6.40
1.00E+00 12.98 2.00 6.40
1.00E+00 9.43 2.00 6.40
1.00E+00 17.24 2.00 6.40
1.00E+00 39.80 2.00 6.40
1.00E+00 0.89 2.00 6.40 10000 1000
1.00E+00 2.02 2.00 6.40
1.00E+00 18.11 2.00 6.40
1.00E+00 34.80 2.00 6.40
1.00E+00 29.79 2.00 6.40
1.00E+00 13.15 2.00 6.40
1.00E+00 28.63 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.48E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.65E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:1 1 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:32 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:34 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:36 PM EPA Interlab LRef 1314 CFS
8/29/11 4:37 PM EPA Interlab LRef 1314 CFS
8/29/11 4:39 PM EPA Interlab LRef 1314 CFS
8/29/11 4:41 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:42 PM EPA Interlab LRef 1314 CFS
8/29/11 4:44 PM EPA Interlab LRef 1314 CFS
8/29/11 4:46 PM EPA Interlab LRef 1314 CFS
8/29/11 11:57 AM EPA Interlab LRef 1314 CFS
8/29/11 4:49 PM EPA Interlab LRef 1314 CFS
8/29/11 4:51 PM EPA Interlab LRef 1314 CFS
8/29/11 4:52 PM EPA Interlab LRef 1314 CFS
1-218
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 Mg/L
Pb CFS-LRef-1314-T01-D 1 9.44E+02
Pb CFS-LRef-1314-T02-D 1 8.12E+02
Pb CFS-LRef-1314-T03-D 1 8.00E+02
Pb CFS-LRef-1314-T04-D 1 9.31E+02
Pb CFS-LRef-1314-T05-D 1 9.95E+02
Pb CFS-LRef-1314-T06-D 1 1.00E+03
Pb CFS-LRef-1314-T07-D 1 8.76E+02
Pb CFS-LRef-1314-T08-D 1 8.75E+02
Pb CFS-LRef-1314-T09-D 1 8.64E+02
Pb CFS-LRef-1314-T01-E 1 9.62E+02
Pb CFS-LRef-1314-T02-E 1 8.45E+02
Pb CFS-LRef-1314-T03-E 1 8.30E+02
Pb CFS-LRef-1314-T04-E 1 8.44E+02
Pb CFS-LRef-1314-T05-E 1 1.00E+03
Pb CFS-LRef-1314-T06-E 1 1.07E+03
Pb CFS-LRef-1314-T07-E 1 1.02E+03
Pb CFS-LRef-1314-T08-E 1 8.90E+02
Pb CFS-LRef-1314-T09-E 1 9.28E+02
Pb CFS-LRef-1314-T01-F 1 9.92E+02
Pb CFS-LRef-1314-T02-F 1 9.05E+02
Pb CFS-LRef-1314-T03-F 1 8.65E+02
Pb CFS-LRef-1314-T04-F 1 8.03E+02
Pb CFS-LRef-1314-T05-F 1 9.01E+02
Pb CFS-LRef-1314-T06-F 1 1.03E+03
Pb CFS-LRef-1314-T07-F 1 1.05E+03
Pb CFS-LRef-1314-T08-F 1 9.09E+02
Pb CFS-LRef-1314-T09-F 1 1.01E+03
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.44E+02 2.26 6.80 21.60
8.12E+02 0.62 6.80 21.60
8.00E+02 1.30 6.80 21.60 10000 1000
9.31 E+02 0.93 6.80 21.60
9.95E+02 0.10 6.80 21.60
1.00E+03 0.50 6.80 21.60
8.76E+02 0.88 6.80 21.60
8.75E+02 0.38 6.80 21.60
8.64E+02 1.18 6.80 21.60
9.62E+02 2.33 6.80 21.60
8.45E+02 1.29 6.80 21.60
8.30E+02 1.31 6.80 21.60 10000 1000
8.44E+02 0.58 6.80 21.60
1.00E+03 0.49 6.80 21.60
1.07E+03 0.31 6.80 21.60
1.02E+03 1.74 6.80 21.60
8.90E+02 0.24 6.80 21.60
9.28E+02 1.13 6.80 21.60
9.92E+02 0.11 6.80 21.60
9.05E+02 0.63 6.80 21.60
8.65E+02 0.87 6.80 21.60 10000 1000
8.03E+02 0.34 6.80 21.60
9.01 E+02 0.90 6.80 21.60
1.03E+03 0.72 6.80 21.60
1.05E+03 1.10 6.80 21.60
9.09E+02 1.46 6.80 21.60
1.01E+03 9.45 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.74E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.76E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.78E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/11 4:11 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:32 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:34 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:36 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:37 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:39 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:41 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:42 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:44 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:46 PM EPA Interlab LRef 1314 CFS
8/29/11 11:57 AM EPA Interlab LRef 1314 CFS
8/29/11 4:49 PM EPA Interlab LRef 1314 CFS
8/29/11 4:51 PM EPA Interlab LRef 1314 CFS
8/29/11 4:52 PM EPA Interlab LRef 1314 CFS
1-219
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 Mg/L
Li CFS-LRef-1314-T01-D 1 4.79E+01
Li CFS-LRef-1314-T02-D 1 1.30E+01
Li CFS-LRef-1314-T03-D 1 1.16E+01
Li CFS-LRef-1314-T04-D 1 1.83E+01
Li CFS-LRef-1314-T05-D 1 1.79E+01
Li CFS-LRef-1314-T06-D 1 1.76E+01
Li CFS-LRef-1314-T07-D 1 1.95E+01
Li CFS-LRef-1314-T08-D 1 1.72E+01
Li CFS-LRef-1314-T09-D 1 1.73E+01
Li CFS-LRef-1314-T01-E 1 5.67E+01
Li CFS-LRef-1314-T02-E 1 1.34E+01
Li CFS-LRef-1314-T03-E 1 1.40E+01
Li CFS-LRef-1314-T04-E 1 1.68E+01
Li CFS-LRef-1314-T05-E 1 1.84E+01
Li CFS-LRef-1314-T06-E 1 1.80E+01
Li CFS-LRef-1314-T07-E 1 1.62E+01
Li CFS-LRef-1314-T08-E 1 1.68E+01
Li CFS-LRef-1314-T09-E 1 1.75E+01
Li CFS-LRef-1314-T01-F 1 5.65E+01
Li CFS-LRef-1314-T02-F 1 1.37E+01
Li CFS-LRef-1314-T03-F 1 1.74E+01
Li CFS-LRef-1314-T04-F 1 1.75E+01
Li CFS-LRef-1314-T05-F 1 1.84E+01
Li CFS-LRef-1314-T06-F 1 1.73E+01
Li CFS-LRef-1314-T07-F 1 1.86E+01
Li CFS-LRef-1314-T08-F 1 1.86E+01
Li CFS-LRef-1314-T09-F 1 1.91E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.79E+01 1.66 1.90 6.00
1.30E+01 7.73 1.90 6.00
1.16E+01 2.92 1.90 6.00 10000 1000
1.83E+01 12.50 1.90 6.00
1.79E+01 4.74 1.90 6.00
1.76E+01 2.28 1.90 6.00
1.95E+01 1.34 1.90 6.00
1.72E+01 7.46 1.90 6.00
1.73E+01 1.03 1.90 6.00
5.67E+01 1.27 1.90 6.00
1.34E+01 3.87 1.90 6.00
1.40E+01 4.10 1.90 6.00 10000 1000
1.68E+01 9.18 1.90 6.00
1.84E+01 1.12 1.90 6.00
1.80E+01 1.26 1.90 6.00
1.62E+01 2.09 1.90 6.00
1.68E+01 3.94 1.90 6.00
1.75E+01 7.54 1.90 6.00
5.65E+01 4.45 1.90 6.00
1.37E+01 8.10 1.90 6.00
1.74E+01 5.01 1.90 6.00 10000 1000
1.75E+01 2.57 1.90 6.00
1.84E+01 2.21 1.90 6.00
1.73E+01 11.84 1.90 6.00
1.86E+01 5.74 1.90 6.00
1.86E+01 4.18 1.90 6.00
1.91E+01 2.37 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.53E+02 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.10E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.84E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/11 4:11 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:32 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:34 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:36 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:37 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:39 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:41 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:42 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:44 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:46 PM EPA Interlab LRef 1314 CFS
8/29/11 11:57 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:49 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:51 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:52 PM EPA Interlab LRef 1314 CFS
1-220
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Mn CFS-LRef-1314-T01-D 1 1.87E+04
Mn CFS-LRef-1314-T02-D 1 8.07E+03
Mn CFS-LRef-1314-T03-D 1 7.08E+03
Mn CFS-LRef-1314-T04-D 1 5.14E+03
Mn CFS-LRef-1314-T05-D 1 2.52E+03
Mn CFS-LRef-1314-T06-D 1 7.22E+02
Mn CFS-LRef-1314-T07-D 1 4.13E+02
Mn CFS-LRef-1314-T08-D 1 2.61E+02
Mn CFS-LRef-1314-T09-D 1 2.00E+02
Mn CFS-LRef-1314-T01-E 1 1.99E+04
Mn CFS-LRef-1314-T02-E 1 1.02E+04
Mn CFS-LRef-1314-T03-E 1 6.89E+03
Mn CFS-LRef-1314-T04-E 1 4.78E+03
Mn CFS-LRef-1314-T05-E 1 2.18E+03
Mn CFS-LRef-1314-T06-E 1 7.42E+02
Mn CFS-LRef-1314-T07-E 1 4.33E+02
Mn CFS-LRef-1314-T08-E 1 2.82E+02
Mn CFS-LRef-1314-T09-E 1 2.10E+02
Mn CFS-LRef-1314-T01-F 1 2.19E+04
Mn CFS-LRef-1314-T02-F 1 1.03E+04
Mn CFS-LRef-1314-T03-F 1 7.03E+03
Mn CFS-LRef-1314-T04-F 1 5.49E+03
Mn CFS-LRef-1314-T05-F 1 2.55E+03
Mn CFS-LRef-1314-T06-F 1 7.24E+02
Mn CFS-LRef-1314-T07-F 1 4.56E+02
Mn CFS-LRef-1314-T08-F 1 3.01 E+02
Mn CFS-LRef-1314-T09-F 1 2.34E+02
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.87E+04 0.38 2.00 6.40
8.07E+03 0.16 2.00 6.40
7.08E+03 0.36 2.00 6.40 10000 1000
5.14E+03 0.84 2.00 6.40
2.52E+03 0.99 2.00 6.40
7.22E+02 0.65 2.00 6.40
4.13E+02 1.45 2.00 6.40
2. 61 E+02 1.39 2.00 6.40
2.00E+02 0.14 2.00 6.40
1.99E+04 1.59 2.00 6.40
1.02E+04 0.41 2.00 6.40
6.89E+03 1.77 2.00 6.40 10000 1000
4.78E+03 0.27 2.00 6.40
2.18E+03 0.14 2.00 6.40
7.42E+02 1.79 2.00 6.40
4.33E+02 0.91 2.00 6.40
2.82E+02 0.99 2.00 6.40
2.10E+02 0.72 2.00 6.40
2.19E+04 0.23 2.00 6.40
1.03E+04 0.39 2.00 6.40
7.03E+03 18.72 2.00 6.40 10000 1000
5.49E+03 1.63 2.00 6.40
2.55E+03 0.87 2.00 6.40
7.24E+02 1.25 2.00 6.40
4.56E+02 0.37 2.00 6.40
3.01 E+02 0.62 2.00 6.40
2.34E+02 7.37 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.07E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.85E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.03E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/11 4:11 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:32 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:34 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:36 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:37 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:39 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:41 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:42 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:44 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:46 PM EPA Interlab LRef 1314 CFS
8/29/11 11:57 AM EPA Interlab LRef 1314 CFS
8/29/11 4:49 PM EPA Interlab LRef 1314 CFS
8/29/11 4:51 PM EPA Interlab LRef 1314 CFS
8/29/11 4:52 PM EPA Interlab LRef 1314 CFS
1-221
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Mg CFS-LRef-1314-T01-D 1 2.09E+06
Mg CFS-LRef-1314-T02-D 1 4.59E+05
Mg CFS-LRef-1314-T03-D 1 1.25E+05
Mg CFS-LRef-1314-T04-D 1 2.48E+04
Mg CFS-LRef-1314-T05-D 1 1.49E+04
Mg CFS-LRef-1314-T06-D 1 1.13E+04
Mg CFS-LRef-1314-T07-D 1 8.97E+03
Mg CFS-LRef-1314-T08-D 1 5.27E+03
Mg CFS-LRef-1314-T09-D 1 3.60E+03
Mg CFS-LRef-1314-T01-E 1 2.02E+06
Mg CFS-LRef-1314-T02-E 1 5.11E+05
Mg CFS-LRef-1314-T03-E 1 1.26E+05
Mg CFS-LRef-1314-T04-E 1 2.44E+04
Mg CFS-LRef-1314-T05-E 1 1.35E+04
Mg CFS-LRef-1314-T06-E 1 1.10E+04
Mg CFS-LRef-1314-T07-E 1 8.75E+03
Mg CFS-LRef-1314-T08-E 1 5.52E+03
Mg CFS-LRef-1314-T09-E 1 3.81E+03
Mg CFS-LRef-1314-T01-F 1 2.31E+06
Mg CFS-LRef-1314-T02-F 1 5.54E+05
Mg CFS-LRef-1314-T03-F 1 1.26E+05
Mg CFS-LRef-1314-T04-F 1 2.65E+04
Mg CFS-LRef-1314-T05-F 1 1.43E+04
Mg CFS-LRef-1314-T06-F 1 1.13E+04
Mg CFS-LRef-1314-T07-F 1 8.96E+03
Mg CFS-LRef-1314-T08-F 1 5.60E+03
Mg CFS-LRef-1314-T09-F 1 4.01 E+03
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.09E+06 0.69 1.00 3.18
4.59E+05 0.50 1.00 3.18
1.25E+05 0.44 1.00 3.18 10000 1000
2.48E+04 0.79 1.00 3.18
1.49E+04 1.16 1.00 3.18
1.13E+04 1.27 1.00 3.18
8.97E+03 0.77 1.00 3.18
5.27E+03 0.71 1.00 3.18
3.60E+03 1.58 1.00 3.18
2.02E+06 1.72 1.00 3.18
5.11E+05 0.49 1.00 3.18
1.26E+05 2.13 1.00 3.18 10000 1000
2.44E+04 1.08 1.00 3.18
1.35E+04 0.31 1.00 3.18
1.10E+04 0.23 1.00 3.18
8.75E+03 1.24 1.00 3.18
5.52E+03 1.27 1.00 3.18
3.81E+03 2.10 1.00 3.18
2.31E+06 0.82 1.00 3.18
5.54E+05 0.84 1.00 3.18
1.26E+05 2.94 1.00 3.18 10000 1000
2.65E+04 1.60 1.00 3.18
1.43E+04 0.91 1.00 3.18
1.13E+04 0.35 1.00 3.18
8.96E+03 0.72 1.00 3.18
5.60E+03 0.74 1.00 3.18
4.01E+03 7.12 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.26E+05 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.26E+05 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.27E+05 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/11 4:11 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:32 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:34 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:36 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:37 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:39 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:41 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:42 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:44 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:46 PM EPA Interlab LRef 1314 CFS
8/29/11 11:57 AM EPA Interlab LRef 1314 CFS
8/29/11 4:49 PM EPA Interlab LRef 1314 CFS
8/29/11 4:51 PM EPA Interlab LRef 1314 CFS
8/29/11 4:52 PM EPA Interlab LRef 1314 CFS
1-222
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Mo CFS-LRef-1314-T01-D 1 2.63E+01
Mo CFS-LRef-1314-T02-D 1 1.55E+01
Mo CFS-LRef-1314-T03-D 1 5.43E+00
Mo CFS-LRef-1314-T04-D 1 7.70E+00
Mo CFS-LRef-1314-T05-D 1 8.35E+00
Mo CFS-LRef-1314-T06-D 1 8.31E+00
Mo CFS-LRef-1314-T07-D 1 8.00E+00
Mo CFS-LRef-1314-T08-D 1 6.24E+00
Mo CFS-LRef-1314-T09-D 1 7.69E+00
Mo CFS-LRef-1314-T01-E 1 3.15E+01
Mo CFS-LRef-1314-T02-E 1 1.41E+01
Mo CFS-LRef-1314-T03-E 1 5.86E+00
Mo CFS-LRef-1314-T04-E 1 8.02E+00
Mo CFS-LRef-1314-T05-E 1 5.75E+00
Mo CFS-LRef-1314-T06-E 1 7.91E+00
Mo CFS-LRef-1314-T07-E 1 8.22E+00
Mo CFS-LRef-1314-T08-E 1 7.25E+00
Mo CFS-LRef-1314-T09-E 1 7.80E+00
Mo CFS-LRef-1314-T01-F 1 3.53E+01
Mo CFS-LRef-1314-T02-F 1 1.51E+01
Mo CFS-LRef-1314-T03-F 1 6.11E+00
Mo CFS-LRef-1314-T04-F 1 8.27E+00
Mo CFS-LRef-1314-T05-F 1 7.49E+00
Mo CFS-LRef-1314-T06-F 1 8.05E+00
Mo CFS-LRef-1314-T07-F 1 9.56E+00
Mo CFS-LRef-1314-T08-F 1 6.57E+00
Mo CFS-LRef-1314-T09-F 1 7.93E+00
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.63E+01 3.34 1.20 3.82
1.55E+01 5.90 1.20 3.82
5.43E+00 8.86 1.20 3.82 10000 1000
7.70E+00 9.05 1.20 3.82
8.35E+00 4.63 1.20 3.82
8.31E+00 2.16 1.20 3.82
8.00E+00 6.81 1.20 3.82
6.24E+00 8.74 1.20 3.82
7.69E+00 5.61 1.20 3.82
3.15E+01 7.99 1.20 3.82
1.41E+01 1.29 1.20 3.82
5.86E+00 13.08 1.20 3.82 10000 1000
8.02E+00 2.63 1.20 3.82
5.75E+00 1.90 1.20 3.82
7.91E+00 1.96 1.20 3.82
8.22E+00 1.90 1.20 3.82
7.25E+00 4.91 1.20 3.82
7.80E+00 5.36 1.20 3.82
3.53E+01 6.87 1.20 3.82
1.51E+01 1.21 1.20 3.82
6.11E+00 2.43 1.20 3.82 10000 1000
8.27E+00 5.83 1.20 3.82
7.49E+00 2.64 1.20 3.82
8.05E+00 1.42 1.20 3.82
9.56E+00 1.18 1.20 3.82
6.57E+00 1.36 1.20 3.82
7.93E+00 1.14 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.96E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/11 4:11 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:32 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:34 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:36 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:37 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:39 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:41 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:42 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:44 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:46 PM EPA Interlab LRef 1314 CFS
8/29/11 11:57 AM EPA Interlab LRef 1314 CFS
8/29/11 4:49 PM EPA Interlab LRef 1314 CFS
8/29/11 4:51 PM EPA Interlab LRef 1314 CFS
8/29/11 4:52 PM EPA Interlab LRef 1314 CFS
1-223
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Ni CFS-LRef-1314-T01-D 1 1.04E+03
Ni CFS-LRef-1314-T02-D 1 4.11E+02
Ni CFS-LRef-1314-T03-D 1 4.24E+02
Ni CFS-LRef-1314-T04-D 1 4.35E+02
Ni CFS-LRef-1314-T05-D 1 4.60E+02
Ni CFS-LRef-1314-T06-D 1 3.11E+02
Ni CFS-LRef-1314-T07-D 1 1.89E+02
Ni CFS-LRef-1314-T08-D 1 1.11E+02
Ni CFS-LRef-1314-T09-D 1 7.59E+01
Ni CFS-LRef-1314-T01-E 1 1.03E+03
Ni CFS-LRef-1314-T02-E 1 6.25E+02
Ni CFS-LRef-1314-T03-E 1 4.36E+02
Ni CFS-LRef-1314-T04-E 1 5.40E+02
Ni CFS-LRef-1314-T05-E 1 5.01E+02
Ni CFS-LRef-1314-T06-E 1 3.21E+02
Ni CFS-LRef-1314-T07-E 1 1.86E+02
Ni CFS-LRef-1314-T08-E 1 1.09E+02
Ni CFS-LRef-1314-T09-E 1 7.58E+01
Ni CFS-LRef-1314-T01-F 1 1.16E+03
Ni CFS-LRef-1314-T02-F 1 6.25E+02
Ni CFS-LRef-1314-T03-F 1 4.50E+02
Ni CFS-LRef-1314-T04-F 1 5.36E+02
Ni CFS-LRef-1314-T05-F 1 5.63E+02
Ni CFS-LRef-1314-T06-F 1 3.12E+02
Ni CFS-LRef-1314-T07-F 1 1.93E+02
Ni CFS-LRef-1314-T08-F 1 1.16E+02
Ni CFS-LRef-1314-T09-F 1 8.24E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.04E+03 0.83 1.80 5.70
4.11E+02 0.66 1.80 5.70
4.24E+02 0.46 1.80 5.70 10000 1000
4.35E+02 0.71 1.80 5.70
4.60E+02 1.19 1.80 5.70
3.11E+02 0.66 1.80 5.70
1.89E+02 1.08 1.80 5.70
1.11E+02 2.70 1.80 5.70
7.59E+01 14.09 1.80 5.70
1.03E+03 1.05 1.80 5.70
6.25E+02 0.62 1.80 5.70
4.36E+02 1.99 1.80 5.70 10000 1000
5.40E+02 0.97 1.80 5.70
5.01 E+02 0.87 1.80 5.70
3.21 E+02 0.93 1.80 5.70
1.86E+02 1.17 1.80 5.70
1.09E+02 1.15 1.80 5.70
7.58E+01 1.08 1.80 5.70
1.16E+03 0.37 1.80 5.70
6.25E+02 0.34 1.80 5.70
4.50E+02 9.95 1.80 5.70 10000 1000
5.36E+02 1.20 1.80 5.70
5.63E+02 0.39 1.80 5.70
3.12E+02 0.69 1.80 5.70
1.93E+02 1.30 1.80 5.70
1.16E+02 2.74 1.80 5.70
8.24E+01 5.77 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.48E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 .54E+03 1 1 1 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.46E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/11 4:11 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:32 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:34 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:36 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:37 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:39 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:41 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:42 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:44 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:46 PM EPA Interlab LRef 1314 CFS
8/29/11 11:57 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:49 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:51 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:52 PM EPA Interlab LRef 1314 CFS
1-224
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
P CFS-LRef-1314-T01-D 1 4.41E+01
P CFS-LRef-1314-T02-D 1 2.55E+01
P CFS-LRef-1314-T03-D 1 2.05E+01
P CFS-LRef-1314-T04-D 1 1.90E+01
P CFS-LRef-1314-T05-D 1 2.17E+01
P CFS-LRef-1314-T06-D 1 3.05E+01
P CFS-LRef-1314-T07-D 1 1.67E+01
P CFS-LRef-1314-T08-D 1 2.04E+01
P CFS-LRef-1314-T09-D 1 2.51E+01
P CFS-LRef-1314-T01-E 1 4.85E+01
P CFS-LRef-1314-T02-E 1 2.80E+01
P CFS-LRef-1314-T03-E 1 2.48E+01
P CFS-LRef-1314-T04-E 1 2.23E+01
P CFS-LRef-1314-T05-E 1 1.41E+01
P CFS-LRef-1314-T06-E 1 2.82E+01
P CFS-LRef-1314-T07-E 1 2.36E+01
P CFS-LRef-1314-T08-E 1 2.00E+01
P CFS-LRef-1314-T09-E 1 1.79E+01
P CFS-LRef-1314-T01-F 1 5.62E+01
P CFS-LRef-1314-T02-F 1 3.97E+01
P CFS-LRef-1314-T03-F 1 2.81 E+01
P CFS-LRef-1314-T04-F 1 1.97E+01
P CFS-LRef-1314-T05-F 1 1.89E+01
P CFS-LRef-1314-T06-F 1 2.36E+01
P CFS-LRef-1314-T07-F 1 1.54E+01
P CFS-LRef-1314-T08-F 1 2.05E+01
P CFS-LRef-1314-T09-F 1 1.79E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.41 E+01 4.48 3.70 11.80
2.55E+01 1.39 3.70 11.80
2.05E+01 1.93 3.70 11.80 10000 1000
1.90E+01 5.08 3.70 11.80
2.17E+01 3.06 3.70 11.80
3.05E+01 8.88 3.70 11.80
1.67E+01 8.05 3.70 11.80
2.04E+01 5.46 3.70 11.80
2.51 E+01 2.69 3.70 11.80
4.85E+01 7.68 3.70 11.80
2.80E+01 1.78 3.70 11.80
2.48E+01 3.35 3.70 11.80 10000 1000
2.23E+01 4.29 3.70 11.80
1.41E+01 3.45 3.70 11.80
2.82E+01 13.41 3.70 11.80
2.36E+01 4.11 3.70 11.80
2.00E+01 2.43 3.70 11.80
1.79E+01 4.72 3.70 11.80
5.62E+01 3.90 3.70 11.80
3.97E+01 2.25 3.70 11.80
2.81E+01 3.58 3.70 11.80 10000 1000
1.97E+01 2.42 3.70 11.80
1.89E+01 2.10 3.70 11.80
2.36E+01 3.82 3.70 11.80
1.54E+01 2.40 3.70 11.80
2.05E+01 14.88 3.70 11.80
1.79E+01 2.19 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.82E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.91 E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:1 1 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/11 4:32 PM EPA Interlab LRef 1314 CFS
8/29/11 4:34 PM EPA Interlab LRef 1314 CFS
8/29/11 4:36 PM EPA Interlab LRef 1314 CFS
8/29/11 4:37 PM EPA Interlab LRef 1314 CFS
8/29/11 4:39 PM EPA Interlab LRef 1314 CFS
8/29/11 4:41 PM EPA Interlab LRef 1314 CFS
8/29/11 4:42 PM EPA Interlab LRef 1314 CFS
8/29/11 4:44 PM EPA Interlab LRef 1314 CFS
8/29/11 4:46 PM EPA Interlab LRef 1314 CFS
8/29/1 1 1 1 :57 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:49 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:51 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:52 PM EPA Interlab LRef 1314 CFS
1-225
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
K CFS-LRef-1314-T01-D 1 1.38E+05
K CFS-LRef-1314-T02-D 1 5.08E+04
K CFS-LRef-1314-T03-D 1 2.39E+04
K CFS-LRef-1314-T04-D 1 2.17E+04
K CFS-LRef-1314-T05-D 1 1.43E+04
K CFS-LRef-1314-T06-D 1 6.83E+03
K CFS-LRef-1314-T07-D 1 4.07E+03
K CFS-LRef-1314-T08-D 1 2.48E+03
K CFS-LRef-1314-T09-D 1 1.81E+03
K CFS-LRef-1314-T01-E 1 1.44E+05
K CFS-LRef-1314-T02-E 1 5.80E+04
K CFS-LRef-1314-T03-E 1 2.45E+04
K CFS-LRef-1314-T04-E 1 2.29E+04
K CFS-LRef-1314-T05-E 1 1.46E+04
K CFS-LRef-1314-T06-E 1 7.50E+03
K CFS-LRef-1314-T07-E 1 4.41 E+03
K CFS-LRef-1314-T08-E 1 2.68E+03
K CFS-LRef-1314-T09-E 1 1.89E+03
K CFS-LRef-1314-T01-F 1 1.48E+05
K CFS-LRef-1314-T02-F 1 5.65E+04
K CFS-LRef-1314-T03-F 1 2.92E+04
K CFS-LRef-1314-T04-F 1 2.30E+04
K CFS-LRef-1314-T05-F 1 1.53E+04
K CFS-LRef-1314-T06-F 1 7.32E+03
K CFS-LRef-1314-T07-F 1 4.42E+03
K CFS-LRef-1314-T08-F 1 2.76E+03
K CFS-LRef-1314-T09-F 1 2.07E+03
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.38E+05 0.64 1.60 5.09
5.08E+04 0.28 1.60 5.09
2.39E+04 0.79 1.60 5.09 10000 1000
2.17E+04 0.14 1.60 5.09
1.43E+04 0.43 1.60 5.09
6.83E+03 0.47 1.60 5.09
4.07E+03 0.08 1.60 5.09
2.48E+03 0.79 1.60 5.09
1.81 E+03 1.02 1.60 5.09
1.44E+05 1.49 1.60 5.09
5.80E+04 0.67 1.60 5.09
2.45E+04 1.26 1.60 5.09 10000 1000
2.29E+04 0.78 1.60 5.09
1.46E+04 0.51 1.60 5.09
7.50E+03 0.25 1.60 5.09
4.41E+03 1.11 1.60 5.09
2.68E+03 0.50 1.60 5.09
1.89E+03 1.66 1.60 5.09
1.48E+05 0.26 1.60 5.09
5.65E+04 0.12 1.60 5.09
2.92E+04 0.89 1.60 5.09 10000 1000
2.30E+04 1.27 1.60 5.09
1.53E+04 0.58 1.60 5.09
7.32E+03 0.26 1.60 5.09
4.42E+03 0.74 1.60 5.09
2.76E+03 1.06 1.60 5.09
2.07E+03 1.30 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.48E+04 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.54E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.01 E+04 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:1 1 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/11 4:32 PM EPA Interlab LRef 1314 CFS
8/29/11 4:34 PM EPA Interlab LRef 1314 CFS
8/29/11 4:36 PM EPA Interlab LRef 1314 CFS
8/29/11 4:37 PM EPA Interlab LRef 1314 CFS
8/29/11 4:39 PM EPA Interlab LRef 1314 CFS
8/29/11 4:41 PM EPA Interlab LRef 1314 CFS
8/29/11 4:42 PM EPA Interlab LRef 1314 CFS
8/29/11 4:44 PM EPA Interlab LRef 1314 CFS
8/29/11 4:46 PM EPA Interlab LRef 1314 CFS
8/29/1 1 1 1 :57 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:49 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:51 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:52 PM EPA Interlab LRef 1314 CFS
1-226
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Se CFS-LRef-1314-T01-D 1 1.97E+03
Se CFS-LRef-1314-T02-D 1 2.96E+02
Se CFS-LRef-1314-T03-D 1 7.14E+01
Se CFS-LRef-1314-T04-D 1 5.40E+01
Se CFS-LRef-1314-T05-D 1 3.32E+01 E
Se CFS-LRef-1314-T06-D 1 2.54E+01 E
Se CFS-LRef-1314-T07-D 1 2.60E+01 E
Se CFS-LRef-1314-T08-D 1 7.50E+00 U1/2
Se CFS-LRef-1314-T09-D 1 7.50E+00 U1/2
Se CFS-LRef-1314-T01-E 1 1.83E+03
Se CFS-LRef-1314-T02-E 1 3.52E+02
Se CFS-LRef-1314-T03-E 1 7.46E+01
Se CFS-LRef-1314-T04-E 1 5.00E+01
Se CFS-LRef-1314-T05-E 1 3.39E+01 E
Se CFS-LRef-1314-T06-E 1 2.66E+01 E
Se CFS-LRef-1314-T07-E 1 2.23E+01 E
Se CFS-LRef-1314-T08-E 1 7.50E+00 U1/2
Se CFS-LRef-1314-T09-E 1 7.50E+00 U1/2
Se CFS-LRef-1314-T01-F 1 1.95E+03
Se CFS-LRef-1314-T02-F 1 3.79E+02
Se CFS-LRef-1314-T03-F 1 8.98E+01
Se CFS-LRef-1314-T04-F 1 7.94E+01
Se CFS-LRef-1314-T05-F 1 3.83E+01 E
Se CFS-LRef-1314-T06-F 1 2.43E+01 E
Se CFS-LRef-1314-T07-F 1 2.19E+01 E
Se CFS-LRef-1314-T08-F 1 7.50E+00 U1/2
Se CFS-LRef-1314-T09-F 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.97E+03 1.09 15.00 47.70
2.96E+02 1.89 15.00 47.70
7.14E+01 5.58 15.00 47.70 10000 1000
5.40E+01 9.64 15.00 47.70
3.32E+01 3.56 15.00 47.70
2.54E+01 18.58 15.00 47.70
2.60E+01 24.68 15.00 47.70
7.50E+00 35.15 15.00 47.70
7.50E+00 20.55 15.00 47.70
1.83E+03 0.91 15.00 47.70
3.52E+02 4.23 15.00 47.70
7.46E+01 8.69 15.00 47.70 10000 1000
5.00E+01 3.30 15.00 47.70
3.39E+01 9.59 15.00 47.70
2.66E+01 16.94 15.00 47.70
2.23E+01 25.35 15.00 47.70
7.50E+00 13.55 15.00 47.70
7.50E+00 15.72 15.00 47.70
1.95E+03 0.89 15.00 47.70
3.79E+02 1.20 15.00 47.70
8.98E+01 1.32 15.00 47.70 10000 1000
7.94E+01 3.44 15.00 47.70
3.83E+01 10.48 15.00 47.70
2.43E+01 14.41 15.00 47.70
2.19E+01 11.20 15.00 47.70
7.50E+00 31.62 15.00 47.70
7.50E+00 38.38 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.14E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.13E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:1 1 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:32 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:34 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:36 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:37 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:39 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:41 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:42 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:44 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:46 PM EPA Interlab LRef 1314 CFS
8/29/11 11:57 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:49 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:51 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:52 PM EPA Interlab LRef 1314 CFS
1-227
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Si CFS-LRef-1314-T01-D 1 7.43E+03
Si CFS-LRef-1314-T02-D 1 6.78E+03
Si CFS-LRef-1314-T03-D 1 5.96E+03
Si CFS-LRef-1314-T04-D 1 6.33E+03
Si CFS-LRef-1314-T05-D 1 6.04E+03
Si CFS-LRef-1314-T06-D 1 5.41E+03
Si CFS-LRef-1314-T07-D 1 5.07E+03
Si CFS-LRef-1314-T08-D 1 4.42E+03
Si CFS-LRef-1314-T09-D 1 4.21E+03
Si CFS-LRef-1314-T01-E 1 7.94E+03
Si CFS-LRef-1314-T02-E 1 7.30E+03
Si CFS-LRef-1314-T03-E 1 6.19E+03
Si CFS-LRef-1314-T04-E 1 6.58E+03
Si CFS-LRef-1314-T05-E 1 6.13E+03
Si CFS-LRef-1314-T06-E 1 5.85E+03
Si CFS-LRef-1314-T07-E 1 5.43E+03
Si CFS-LRef-1314-T08-E 1 4.74E+03
Si CFS-LRef-1314-T09-E 1 4.53E+03
Si CFS-LRef-1314-T01-F 1 8.53E+03
Si CFS-LRef-1314-T02-F 1 7.57E+03
Si CFS-LRef-1314-T03-F 1 6.67E+03
Si CFS-LRef-1314-T04-F 1 7.22E+03
Si CFS-LRef-1314-T05-F 1 6.57E+03
Si CFS-LRef-1314-T06-F 1 5.67E+03
Si CFS-LRef-1314-T07-F 1 5.54E+03
Si CFS-LRef-1314-T08-F 1 4.93E+03
Si CFS-LRef-1314-T09-F 1 4.79E+03
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.43E+03 0.30 1.10 3.50
6.78E+03 0.23 1.10 3.50
5.96E+03 1.50 1.10 3.50 10000 1000
6.33E+03 0.74 1.10 3.50
6.04E+03 1.85 1.10 3.50
5.41 E+03 0.82 1.10 3.50
5.07E+03 0.52 1.10 3.50
4.42E+03 1.74 1.10 3.50
4.21E+03 0.17 1.10 3.50
7.94E+03 1.05 1.10 3.50
7.30E+03 0.56 1.10 3.50
6.19E+03 1.86 1.10 3.50 10000 1000
6.58E+03 1.20 1.10 3.50
6.13E+03 0.52 1.10 3.50
5.85E+03 0.24 1.10 3.50
5.43E+03 0.88 1.10 3.50
4.74E+03 1.49 1.10 3.50
4.53E+03 1.11 1.10 3.50
8.53E+03 0.03 1.10 3.50
7.57E+03 0.49 1.10 3.50
6.67E+03 5.99 1.10 3.50 10000 1000
7.22E+03 1.72 1.10 3.50
6.57E+03 1.00 1.10 3.50
5.67E+03 0.47 1.10 3.50
5.54E+03 0.56 1.10 3.50
4.93E+03 0.64 1.10 3.50
4.79E+03 7.60 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.93E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.12E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.70E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/11 4:11 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:32 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:34 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:36 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:37 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:39 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:41 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:42 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:44 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:46 PM EPA Interlab LRef 1314 CFS
8/29/11 11:57 AM EPA Interlab LRef 1314 CFS
8/29/11 4:49 PM EPA Interlab LRef 1314 CFS
8/29/11 4:51 PM EPA Interlab LRef 1314 CFS
8/29/11 4:52 PM EPA Interlab LRef 1314 CFS
1-228
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Na CFS-LRef-1314-T01-D 1 3.15E+05
Na CFS-LRef-1314-T02-D 1 4.83E+04
Na CFS-LRef-1314-T03-D 1 8.15E+03
Na CFS-LRef-1314-T04-D 1 3.29E+03
Na CFS-LRef-1314-T05-D 1 2.26E+03
Na CFS-LRef-1314-T06-D 1 1.42E+03
Na CFS-LRef-1314-T07-D 1 1.03E+03
Na CFS-LRef-1314-T08-D 1 8.54E+02
Na CFS-LRef-1314-T09-D 1 7.63E+02
Na CFS-LRef-1314-T01-E 1 3.14E+05
Na CFS-LRef-1314-T02-E 1 8.24E+04
Na CFS-LRef-1314-T03-E 1 8.59E+03
Na CFS-LRef-1314-T04-E 1 4.57E+03
Na CFS-LRef-1314-T05-E 1 2.88E+03
Na CFS-LRef-1314-T06-E 1 1.78E+03
Na CFS-LRef-1314-T07-E 1 1.32E+03
Na CFS-LRef-1314-T08-E 1 1.03E+03
Na CFS-LRef-1314-T09-E 1 8.40E+02
Na CFS-LRef-1314-T01-F 1 3.15E+05
Na CFS-LRef-1314-T02-F 1 6.92E+04
Na CFS-LRef-1314-T03-F 1 9.39E+03
Na CFS-LRef-1314-T04-F 1 4.81E+03
Na CFS-LRef-1314-T05-F 1 2.66E+03
Na CFS-LRef-1314-T06-F 1 1.60E+03
Na CFS-LRef-1314-T07-F 1 1.24E+03
Na CFS-LRef-1314-T08-F 1 1.02E+03
Na CFS-LRef-1314-T09-F 1 9.00E+02
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.15E+05 0.49 2.50 8.00
4.83E+04 0.31 2.50 8.00
8.15E+03 0.92 2.50 8.00 10000 1000
3.29E+03 0.38 2.50 8.00
2.26E+03 0.75 2.50 8.00
1.42E+03 0.95 2.50 8.00
1.03E+03 0.21 2.50 8.00
8.54E+02 1.01 2.50 8.00
7.63E+02 1.58 2.50 8.00
3.14E+05 0.53 2.50 8.00
8.24E+04 0.34 2.50 8.00
8.59E+03 0.74 2.50 8.00 10000 1000
4.57E+03 0.94 2.50 8.00
2.88E+03 0.36 2.50 8.00
1.78E+03 0.48 2.50 8.00
1.32E+03 0.22 2.50 8.00
1.03E+03 0.46 2.50 8.00
8.40E+02 1.34 2.50 8.00
3.15E+05 0.43 2.50 8.00
6.92E+04 0.27 2.50 8.00
9.39E+03 0.73 2.50 8.00 10000 1000
4.81 E+03 0.50 2.50 8.00
2.66E+03 0.32 2.50 8.00
1.60E+03 1.62 2.50 8.00
1.24E+03 0.61 2.50 8.00
1.02E+03 0.52 2.50 8.00
9.00E+02 1.81 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.09E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.50E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/11 4:11 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:32 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:34 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:36 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:37 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:39 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:41 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:42 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:44 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:46 PM EPA Interlab LRef 1314 CFS
8/29/11 11:57 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:49 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:51 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:52 PM EPA Interlab LRef 1314 CFS
1-229
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Sr CFS-LRef-1314-T01-D 1 5.41E+03
Sr CFS-LRef-1314-T02-D 1 4.69E+03
Sr CFS-LRef-1314-T03-D 1 3.81E+03
Sr CFS-LRef-1314-T04-D 1 3.56E+03
Sr CFS-LRef-1314-T05-D 1 2.33E+03
Sr CFS-LRef-1314-T06-D 1 1.72E+03
Sr CFS-LRef-1314-T07-D 1 1.58E+03
Sr CFS-LRef-1314-T08-D 1 1.35E+03
Sr CFS-LRef-1314-T09-D 1 1.35E+03
Sr CFS-LRef-1314-T01-E 1 5.48E+03
Sr CFS-LRef-1314-T02-E 1 4.10E+03
Sr CFS-LRef-1314-T03-E 1 3.86E+03
Sr CFS-LRef-1314-T04-E 1 3.39E+03
Sr CFS-LRef-1314-T05-E 1 2.28E+03
Sr CFS-LRef-1314-T06-E 1 1.83E+03
Sr CFS-LRef-1314-T07-E 1 1.65E+03
Sr CFS-LRef-1314-T08-E 1 1.44E+03
Sr CFS-LRef-1314-T09-E 1 1.37E+03
Sr CFS-LRef-1314-T01-F 1 5.76E+03
Sr CFS-LRef-1314-T02-F 1 4.25E+03
Sr CFS-LRef-1314-T03-F 1 3.90E+03
Sr CFS-LRef-1314-T04-F 1 3.45E+03
Sr CFS-LRef-1314-T05-F 1 2.43E+03
Sr CFS-LRef-1314-T06-F 1 1.72E+03
Sr CFS-LRef-1314-T07-F 1 1.68E+03
Sr CFS-LRef-1314-T08-F 1 1.47E+03
Sr CFS-LRef-1314-T09-F 1 1.45E+03
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.41E+03 1.34 1.00 3.18
4.69E+03 0.77 1.00 3.18
3.81E+03 0.75 1.00 3.18 10000 1000
3.56E+03 1.18 1.00 3.18
2.33E+03 1.72 1.00 3.18
1.72E+03 0.15 1.00 3.18
1.58E+03 0.76 1.00 3.18
1.35E+03 1.50 1.00 3.18
1.35E+03 0.38 1.00 3.18
5.48E+03 2.21 1.00 3.18
4.10E+03 0.98 1.00 3.18
3.86E+03 2.32 1.00 3.18 10000 1000
3.39E+03 1.29 1.00 3.18
2.28E+03 0.39 1.00 3.18
1.83E+03 0.62 1.00 3.18
1.65E+03 1.06 1.00 3.18
1.44E+03 1.09 1.00 3.18
1.37E+03 1.28 1.00 3.18
5.76E+03 1.81 1.00 3.18
4.25E+03 1.26 1.00 3.18
3.90E+03 7.03 1.00 3.18 10000 1000
3.45E+03 2.22 1.00 3.18
2.43E+03 0.82 1.00 3.18
1.72E+03 0.73 1.00 3.18
1.68E+03 0.44 1.00 3.18
1.47E+03 0.55 1.00 3.18
1.45E+03 6.93 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.82E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.85E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.93E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:1 1 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/11 4:32 PM EPA Interlab LRef 1314 CFS
8/29/11 4:34 PM EPA Interlab LRef 1314 CFS
8/29/11 4:36 PM EPA Interlab LRef 1314 CFS
8/29/11 4:37 PM EPA Interlab LRef 1314 CFS
8/29/11 4:39 PM EPA Interlab LRef 1314 CFS
8/29/11 4:41 PM EPA Interlab LRef 1314 CFS
8/29/11 4:42 PM EPA Interlab LRef 1314 CFS
8/29/11 4:44 PM EPA Interlab LRef 1314 CFS
8/29/11 4:46 PM EPA Interlab LRef 1314 CFS
8/29/1 1 1 1 :57 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:49 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:51 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:52 PM EPA Interlab LRef 1314 CFS
1-230
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
S CFS-LRef-1314-T01-D 1 2.35E+06
S CFS-LRef-1314-T02-D 1 1.01E+06
S CFS-LRef-1314-T03-D 1 5.40E+05
S CFS-LRef-1314-T04-D 1 5.56E+05
S CFS-LRef-1314-T05-D 1 5.43E+05
S CFS-LRef-1314-T06-D 1 5.25E+05
S CFS-LRef-1314-T07-D 1 5.26E+05
S CFS-LRef-1314-T08-D 1 5.00E+05
S CFS-LRef-1314-T09-D 1 5.07E+05
S CFS-LRef-1314-T01-E 1 2.49E+06
S CFS-LRef-1314-T02-E 1 1.08E+06
S CFS-LRef-1314-T03-E 1 5.48E+05
S CFS-LRef-1314-T04-E 1 5.61E+05
S CFS-LRef-1314-T05-E 1 5.25E+05
S CFS-LRef-1314-T06-E 1 5.48E+05
S CFS-LRef-1314-T07-E 1 5.45E+05
S CFS-LRef-1314-T08-E 1 5.16E+05
S CFS-LRef-1314-T09-E 1 5.52E+05
S CFS-LRef-1314-T01-F 1 2.62E+06
S CFS-LRef-1314-T02-F 1 1.12E+06
S CFS-LRef-1314-T03-F 1 5.72E+05
S CFS-LRef-1314-T04-F 1 5.54E+05
S CFS-LRef-1314-T05-F 1 5.52E+05
S CFS-LRef-1314-T06-F 1 5.67E+05
S CFS-LRef-1314-T07-F 1 5.43E+05
S CFS-LRef-1314-T08-F 1 5.25E+05
S CFS-LRef-1314-T09-F 1 5.57E+05
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.35E+06 0.71 6.80 21.60
1.01E+06 0.10 6.80 21.60
5.40E+05 0.78 6.80 21.60 10000 1000
5.56E+05 0.31 6.80 21.60
5.43E+05 0.40 6.80 21.60
5.25E+05 0.89 6.80 21.60
5.26E+05 0.33 6.80 21.60
5.00E+05 0.89 6.80 21.60
5.07E+05 1.08 6.80 21.60
2.49E+06 1.47 6.80 21.60
1.08E+06 0.69 6.80 21.60
5.48E+05 1.16 6.80 21.60 10000 1000
5.61 E+05 0.41 6.80 21.60
5.25E+05 0.75 6.80 21.60
5.48E+05 0.09 6.80 21.60
5.45E+05 1.09 6.80 21.60
5.16E+05 0.51 6.80 21.60
5.52E+05 1.25 6.80 21.60
2.62E+06 0.18 6.80 21.60
1.12E+06 0.34 6.80 21.60
5.72E+05 0.94 6.80 21.60 10000 1000
5.54E+05 1.18 6.80 21.60
5.52E+05 1.08 6.80 21.60
5.67E+05 0.35 6.80 21.60
5.43E+05 0.63 6.80 21.60
5.25E+05 0.95 6.80 21.60
5.57E+05 9.71 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.41E+05 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.49E+05 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.73E+05 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:1 1 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/11 4:32 PM EPA Interlab LRef 1314 CFS
8/29/11 4:34 PM EPA Interlab LRef 1314 CFS
8/29/11 4:36 PM EPA Interlab LRef 1314 CFS
8/29/11 4:37 PM EPA Interlab LRef 1314 CFS
8/29/11 4:39 PM EPA Interlab LRef 1314 CFS
8/29/11 4:41 PM EPA Interlab LRef 1314 CFS
8/29/11 4:42 PM EPA Interlab LRef 1314 CFS
8/29/11 4:44 PM EPA Interlab LRef 1314 CFS
8/29/11 4:46 PM EPA Interlab LRef 1314 CFS
8/29/1 1 1 1 :57 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:49 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:51 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:52 PM EPA Interlab LRef 1314 CFS
1-231
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Tl CFS-LRef-1314-T01-D 1 1.88E+03
Tl CFS-LRef-1314-T02-D 1 8.77E+02
Tl CFS-LRef-1314-T03-D 1 4.64E+02
Tl CFS-LRef-1314-T04-D 1 4.77E+02
Tl CFS-LRef-1314-T05-D 1 3.66E+02
Tl CFS-LRef-1314-T06-D 1 2.22E+02
Tl CFS-LRef-1314-T07-D 1 1.63E+02
Tl CFS-LRef-1314-T08-D 1 1.17E+02
Tl CFS-LRef-1314-T09-D 1 9.72E+01
Tl CFS-LRef-1314-T01-E 1 1.94E+03
Tl CFS-LRef-1314-T02-E 1 1.02E+03
Tl CFS-LRef-1314-T03-E 1 5.02E+02
Tl CFS-LRef-1314-T04-E 1 5.14E+02
Tl CFS-LRef-1314-T05-E 1 3.80E+02
Tl CFS-LRef-1314-T06-E 1 2.51E+02
Tl CFS-LRef-1314-T07-E 1 1.76E+02
Tl CFS-LRef-1314-T08-E 1 1.22E+02
Tl CFS-LRef-1314-T09-E 1 1.07E+02
Tl CFS-LRef-1314-T01-F 1 2.06E+03
Tl CFS-LRef-1314-T02-F 1 9.89E+02
Tl CFS-LRef-1314-T03-F 1 5.83E+02
Tl CFS-LRef-1314-T04-F 1 5.10E+02
Tl CFS-LRef-1314-T05-F 1 3.91 E+02
Tl CFS-LRef-1314-T06-F 1 2.38E+02
Tl CFS-LRef-1314-T07-F 1 1.76E+02
Tl CFS-LRef-1314-T08-F 1 1.28E+02
Tl CFS-LRef-1314-T09-F 1 1.16E+02
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.88E+03 1.21 4.60 14.60
8.77E+02 0.34 4.60 14.60
4.64E+02 1.92 4.60 14.60 10000 1000
4.77E+02 0.84 4.60 14.60
3.66E+02 1.21 4.60 14.60
2.22E+02 2.42 4.60 14.60
1.63E+02 1.96 4.60 14.60
1.17E+02 2.62 4.60 14.60
9.72E+01 3.39 4.60 14.60
1.94E+03 1.03 4.60 14.60
1.02E+03 0.28 4.60 14.60
5.02E+02 0.50 4.60 14.60 10000 1000
5.14E+02 1.28 4.60 14.60
3.80E+02 2.29 4.60 14.60
2.51 E+02 1.81 4.60 14.60
1.76E+02 3.29 4.60 14.60
1.22E+02 4.93 4.60 14.60
1.07E+02 5.09 4.60 14.60
2.06E+03 0.52 4.60 14.60
9.89E+02 0.25 4.60 14.60
5.83E+02 0.31 4.60 14.60 10000 1000
5.10E+02 0.81 4.60 14.60
3.91E+02 1.08 4.60 14.60
2.38E+02 1.45 4.60 14.60
1.76E+02 2.06 4.60 14.60
1.28E+02 0.83 4.60 14.60
1.16E+02 0.81 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.48E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.57E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.58E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:1 1 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/11 4:32 PM EPA Interlab LRef 1314 CFS
8/29/11 4:34 PM EPA Interlab LRef 1314 CFS
8/29/11 4:36 PM EPA Interlab LRef 1314 CFS
8/29/11 4:37 PM EPA Interlab LRef 1314 CFS
8/29/11 4:39 PM EPA Interlab LRef 1314 CFS
8/29/11 4:41 PM EPA Interlab LRef 1314 CFS
8/29/11 4:42 PM EPA Interlab LRef 1314 CFS
8/29/11 4:44 PM EPA Interlab LRef 1314 CFS
8/29/11 4:46 PM EPA Interlab LRef 1314 CFS
8/29/1 1 1 1 :57 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:49 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:51 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:52 PM EPA Interlab LRef 1314 CFS
1-232
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ti CFS-LRef-1314-T01-D 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T02-D 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T03-D 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T04-D 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T05-D 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T06-D 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T07-D 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T08-D 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T09-D 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T01-E 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T02-E 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T03-E 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T04-E 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T05-E 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T06-E 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T07-E 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T08-E 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T09-E 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T01-F 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T02-F 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T03-F 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T04-F 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T05-F 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T06-F 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T07-F 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T08-F 1 1.00E+00 U1/2
Ti CFS-LRef-1314-T09-F 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 26.24 2.00 6.40
1.00E+00 13.74 2.00 6.40
1.00E+00 30.23 2.00 6.40 10000 1000
1.00E+00 30.52 2.00 6.40
1.00E+00 43.21 2.00 6.40
1.00E+00 56.58 2.00 6.40
1.00E+00 74.29 2.00 6.40
1.00E+00 10.78 2.00 6.40
1.00E+00 44.01 2.00 6.40
1.00E+00 17.94 2.00 6.40
1.00E+00 25.56 2.00 6.40
1.00E+00 30.65 2.00 6.40 10000 1000
1.00E+00 41.83 2.00 6.40
1.00E+00 29.20 2.00 6.40
1.00E+00 14.31 2.00 6.40
1.00E+00 46.50 2.00 6.40
1.00E+00 65.08 2.00 6.40
1.00E+00 24.40 2.00 6.40
1.00E+00 16.35 2.00 6.40
1.00E+00 38.46 2.00 6.40
1.00E+00 32.46 2.00 6.40 10000 1000
1.00E+00 19.65 2.00 6.40
1.00E+00 50.69 2.00 6.40
1.00E+00 61.29 2.00 6.40
1.00E+00 10.19 2.00 6.40
1.00E+00 32.69 2.00 6.40
1.00E+00 31.26 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.87E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:1 1 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/11 4:31 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:32 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:34 PM EPA Interlab LRef 1314 CFS
8/29/11 4:36 PM EPA Interlab LRef 1314 CFS
8/29/11 4:37 PM EPA Interlab LRef 1314 CFS
8/29/11 4:39 PM EPA Interlab LRef 1314 CFS
8/29/11 4:41 PM EPA Interlab LRef 1314 CFS
8/29/11 4:42 PM EPA Interlab LRef 1314 CFS
8/29/11 4:44 PM EPA Interlab LRef 1314 CFS
8/29/11 4:46 PM EPA Interlab LRef 1314 CFS
8/29/11 11:57 AM EPA Interlab LRef 1314 CFS
8/29/11 4:49 PM EPA Interlab LRef 1314 CFS
8/29/11 4:51 PM EPA Interlab LRef 1314 CFS
8/29/11 4:52 PM EPA Interlab LRef 1314 CFS
1-233
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
V CFS-LRef-1314-T01-D 1 2.15E+01
V CFS-LRef-1314-T02-D 1 3.42E+01
V CFS-LRef-1314-T03-D 1 2.40E+01
V CFS-LRef-1314-T04-D 1 4.02E+01
V CFS-LRef-1314-T05-D 1 4.04E+01
V CFS-LRef-1314-T06-D 1 4.01E+01
V CFS-LRef-1314-T07-D 1 4.22E+01
V CFS-LRef-1314-T08-D 1 3.82E+01
V CFS-LRef-1314-T09-D 1 3.93E+01
V CFS-LRef-1314-T01-E 1 2.24E+01
V CFS-LRef-1314-T02-E 1 3.38E+01
V CFS-LRef-1314-T03-E 1 2.59E+01
V CFS-LRef-1314-T04-E 1 3.90E+01
V CFS-LRef-1314-T05-E 1 3.77E+01
V CFS-LRef-1314-T06-E 1 4.05E+01
V CFS-LRef-1314-T07-E 1 4.11E+01
V CFS-LRef-1314-T08-E 1 3.90E+01
V CFS-LRef-1314-T09-E 1 4.08E+01
V CFS-LRef-1314-T01-F 1 2.96E+01
V CFS-LRef-1314-T02-F 1 3.32E+01
V CFS-LRef-1314-T03-F 1 3.09E+01
V CFS-LRef-1314-T04-F 1 3.98E+01
V CFS-LRef-1314-T05-F 1 4.13E+01
V CFS-LRef-1314-T06-F 1 4.03E+01
V CFS-LRef-1314-T07-F 1 4.13E+01
V CFS-LRef-1314-T08-F 1 4.07E+01
V CFS-LRef-1314-T09-F 1 4.32E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.15E+01 8.17 1.50 4.77
3.42E+01 4.31 1.50 4.77
2.40E+01 0.32 1.50 4.77 10000 1000
4.02E+01 1.13 1.50 4.77
4.04E+01 2.20 1.50 4.77
4.01 E+01 1.09 1.50 4.77
4.22E+01 1.56 1.50 4.77
3.82E+01 15.18 1.50 4.77
3.93E+01 0.64 1.50 4.77
2.24E+01 9.49 1.50 4.77
3.38E+01 3.92 1.50 4.77
2.59E+01 1.12 1.50 4.77 10000 1000
3.90E+01 1.72 1.50 4.77
3.77E+01 2.33 1.50 4.77
4.05E+01 3.78 1.50 4.77
4.11E+01 2.37 1.50 4.77
3.90E+01 0.27 1.50 4.77
4.08E+01 1.83 1.50 4.77
2.96E+01 4.70 1.50 4.77
3.32E+01 2.20 1.50 4.77
3.09E+01 2.55 1.50 4.77 10000 1000
3.98E+01 1.01 1.50 4.77
4.13E+01 2.04 1.50 4.77
4.03E+01 2.50 1.50 4.77
4.13E+01 3.52 1.50 4.77
4.07E+01 1.71 1.50 4.77
4.32E+01 1.33 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 . 1 1 E+03 1 08% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:1 1 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/11 4:32 PM EPA Interlab LRef 1314 CFS
8/29/11 4:34 PM EPA Interlab LRef 1314 CFS
8/29/11 4:36 PM EPA Interlab LRef 1314 CFS
8/29/11 4:37 PM EPA Interlab LRef 1314 CFS
8/29/11 4:39 PM EPA Interlab LRef 1314 CFS
8/29/11 4:41 PM EPA Interlab LRef 1314 CFS
8/29/11 4:42 PM EPA Interlab LRef 1314 CFS
8/29/11 4:44 PM EPA Interlab LRef 1314 CFS
8/29/11 4:46 PM EPA Interlab LRef 1314 CFS
8/29/1 1 1 1 :57 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:49 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:51 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:52 PM EPA Interlab LRef 1314 CFS
1-234
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Zn CFS-LRef-1314-T01-D 1 6.24E+04
Zn CFS-LRef-1314-T02-D 1 3.25E+04
Zn CFS-LRef-1314-T03-D 1 3.40E+04
Zn CFS-LRef-1314-T04-D 1 3.38E+04
Zn CFS-LRef-1314-T05-D 1 3.55E+04
Zn CFS-LRef-1314-T06-D 1 3.00E+04
Zn CFS-LRef-1314-T07-D 1 2.41E+04
Zn CFS-LRef-1314-T08-D 1 1.75E+04
Zn CFS-LRef-1314-T09-D 1 1.44E+04
Zn CFS-LRef-1314-T01-E 1 6.41E+04
Zn CFS-LRef-1314-T02-E 1 4.74E+04
Zn CFS-LRef-1314-T03-E 1 3.52E+04
Zn CFS-LRef-1314-T04-E 1 4.48E+04
Zn CFS-LRef-1314-T05-E 1 4.32E+04
Zn CFS-LRef-1314-T06-E 1 3.55E+04
Zn CFS-LRef-1314-T07-E 1 2.70E+04
Zn CFS-LRef-1314-T08-E 1 1.89E+04
Zn CFS-LRef-1314-T09-E 1 1.51E+04
Zn CFS-LRef-1314-T01-F 1 7.21E+04
Zn CFS-LRef-1314-T02-F 1 4.81 E+04
Zn CFS-LRef-1314-T03-F 1 3.90E+04
Zn CFS-LRef-1314-T04-F 1 4.27E+04
Zn CFS-LRef-1314-T05-F 1 4.60E+04
Zn CFS-LRef-1314-T06-F 1 2.77E+04
Zn CFS-LRef-1314-T07-F 1 2.78E+04
Zn CFS-LRef-1314-T08-F 1 1.99E+04
Zn CFS-LRef-1314-T09-F 1 1.63E+04
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.24E+04 0.21 1.00 3.18
3.25E+04 0.80 1.00 3.18
3.40E+04 0.59 1.00 3.18 10000 1000
3.38E+04 0.98 1.00 3.18
3.55E+04 0.90 1.00 3.18
3.00E+04 0.93 1.00 3.18
2.41E+04 1.26 1.00 3.18
1.75E+04 1.70 1.00 3.18
1.44E+04 0.54 1.00 3.18
6.41E+04 1.10 1.00 3.18
4.74E+04 0.63 1.00 3.18
3.52E+04 0.92 1.00 3.18 10000 1000
4.48E+04 0.80 1.00 3.18
4.32E+04 1.46 1.00 3.18
3.55E+04 0.71 1.00 3.18
2.70E+04 1.56 1.00 3.18
1.89E+04 0.59 1.00 3.18
1.51E+04 0.93 1.00 3.18
7.21E+04 0.58 1.00 3.18
4.81E+04 0.79 1.00 3.18
3.90E+04 1.87 1.00 3.18 10000 1000
4.27E+04 1.88 1.00 3.18
4.60E+04 1.02 1.00 3.18
2.77E+04 0.71 1.00 3.18
2.78E+04 0.49 1.00 3.18
1.99E+04 0.38 1.00 3.18
1.63E+04 5.91 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.50E+04 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.61 E+04 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.99E+04 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/29/1 1 11 :50 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:04 PM EPA Interlab LRef 1314 CFS
8/29/11 11:52 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:08 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:09 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:1 1 PM EPA Interlab LRef 1314 CFS
8/29/11 4:13 PM EPA Interlab LRef 1314 CFS
8/29/11 4:14 PM EPA Interlab LRef 1314 CFS
8/29/11 4:16 PM EPA Interlab LRef 1314 CFS
8/29/1 1 11 :53 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:26 PM EPA Interlab LRef 1314 CFS
8/29/11 11:55 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:29 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:31 PM EPA Interlab LRef 1314 CFS
8/29/11 4:32 PM EPA Interlab LRef 1314 CFS
8/29/11 4:34 PM EPA Interlab LRef 1314 CFS
8/29/11 4:36 PM EPA Interlab LRef 1314 CFS
8/29/11 4:37 PM EPA Interlab LRef 1314 CFS
8/29/11 4:39 PM EPA Interlab LRef 1314 CFS
8/29/11 4:41 PM EPA Interlab LRef 1314 CFS
8/29/11 4:42 PM EPA Interlab LRef 1314 CFS
8/29/11 4:44 PM EPA Interlab LRef 1314 CFS
8/29/11 4:46 PM EPA Interlab LRef 1314 CFS
8/29/1 1 1 1 :57 AM EPA Interlab LRef 1314 CFS
8/29/1 1 4:49 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:51 PM EPA Interlab LRef 1314 CFS
8/29/1 1 4:52 PM EPA Interlab LRef 1314 CFS
1-235
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1314:
Dilution Sample
Element Sample ID Factor Cone. Qualifier
I I M9/L I
Al JaFS-L01-1314-T01-A 1 6.97E+01
Al JaFS-L01-1314-T02-A 1 1.48E+01
Al JaFS-L01-1314-T03-A 1 2.03E+01
Al JaFS-L01-1314-T04-A 1 2.51E+01
Al JaFS-L01-1314-T05-A 1 1.24E+01
Al JaFS-L01-1314-T06-A 1 1.77E+01
Al JaFS-L01-1314-T07-A 1 1.58E+01
Al JaFS-L01-1314-T08-A 1 1.95E+01
Al JaFS-L01-1314-T09-A 1 3.13E+01
Al JaFS-L01-1314-T01-B 1 9.16E+01
Al JaFS-L01-1314-T02-B 1 5.16E+01
Al JaFS-L01-1314-T03-B 1 1.56E+01
Al JaFS-L01-1314-T04-B 1 1.79E+01
Al JaFS-L01-1314-T05-B 1 1.17E+01
Al JaFS-L01-1314-T06-B 1 2.13E+01
Al JaFS-L01-1314-T07-B 1 2.09E+01
Al JaFS-L01-1314-T08-B 1 2.14E+01
Al JaFS-L01-1314-T09-B 1 1.07E+01
Al JaFS-L01-1314-T01-C 1 9.73E+01
Al JaFS-L01-1314-T02-C 1 2.08E+01
Al JaFS-L01-1314-T03-C 1 1.15E+01
Al JaFS-L01-1314-T04-C 1 1.15E+01
Al JaFS-L01-1314-T05-C 1 8.22E+00
Al JaFS-L01-1314-T06-C 1 7.01E+01
Al JaFS-L01-1314-T07-C 1 5.94E+00
Al JaFS-L01-1314-T08-C 1 1.11E+01
Al JaFS-L01-1314-T09-C 1 8.00E+00
Al JaFS-L01-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.97E+01 2.00 1.00 3.18
1.48E+01 6.68 1.00 3.18
2.03E+01 2.92 1.00 3.18 10000 1000
2.51E+01 1.47 1.00 3.18
1.24E+01 5.29 1.00 3.18
1.77E+01 6.79 1.00 3.18
1.58E+01 9.37 1.00 3.18
1.95E+01 5.16 1.00 3.18
3.13E+01 4.86 1.00 3.18
9.16E+01 0.80 1.00 3.18
5.16E+01 4.29 1.00 3.18
1.56E+01 8.25 1.00 3.18 10000 1000
1.79E+01 4.36 1.00 3.18
1.17E+01 10.06 1.00 3.18
2.13E+01 5.89 1.00 3.18
2.09E+01 6.06 1.00 3.18
2.14E+01 4.45 1.00 3.18
1.07E+01 7.90 1.00 3.18
9.73E+01 3.21 1.00 3.18
2.08E+01 1.45 1.00 3.18
1.15E+01 5.53 1.00 3.18 10000 1000
1.15E+01 7.25 1.00 3.18
8.22E+00 3.29 1.00 3.18
7.01E+01 1.52 1.00 3.18
5.94E+00 1.12 1.00 3.18
1.11E+01 10.84 1.00 3.18
8.00E+00 7.82 1.00 3.18
5.00E-01 48.06 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.77E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.26E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-236
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Sb JaFS-L01-1314-T01-A 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T02-A 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T03-A 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T04-A 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T05-A 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T06-A 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T07-A 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T08-A 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T09-A 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T01-B 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T02-B 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T03-B 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T04-B 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T05-B 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T06-B 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T07-B 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T08-B 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T09-B 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T01-C 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T02-C 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T03-C 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T04-C 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T05-C 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T06-C 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T07-C 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T08-C 1 3.75E+00 U1/2
Sb JaFS-L01-1314-T09-C 1 3.75E+00 U1/2
Sb JaFS-L01-1314-B01-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.75E+00 19.68 7.50 23.90
3.75E+00 10.71 7.50 23.90
3.75E+00 10.39 7.50 23.90 10000 1000
3.75E+00 12.38 7.50 23.90
3.75E+00 29.26 7.50 23.90
3.75E+00 14.07 7.50 23.90
3.75E+00 23.97 7.50 23.90
3.75E+00 35.17 7.50 23.90
3.75E+00 30.09 7.50 23.90
3.75E+00 34.87 7.50 23.90
3.75E+00 24.01 7.50 23.90
3.75E+00 32.92 7.50 23.90 10000 1000
3.75E+00 18.11 7.50 23.90
3.75E+00 37.79 7.50 23.90
3.75E+00 31.91 7.50 23.90
3.75E+00 22.12 7.50 23.90
3.75E+00 16.32 7.50 23.90
3.75E+00 23.90 7.50 23.90
3.75E+00 25.73 7.50 23.90
3.75E+00 12.07 7.50 23.90
3.75E+00 22.51 7.50 23.90 10000 1000
3.75E+00 33.79 7.50 23.90
3.75E+00 24.91 7.50 23.90
3.75E+00 30.80 7.50 23.90
3.75E+00 27.99 7.50 23.90
3.75E+00 14.90 7.50 23.90
3.75E+00 37.86 7.50 23.90
3.75E+00 26.70 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.31E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.26E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.33E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-237
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
As JaFS-L01-1314-T01-A 1 5.50E+00 U1/2
As JaFS-L01-1314-T02-A 1 5.50E+00 U1/2
As JaFS-L01-1314-T03-A 1 5.50E+00 U1/2
As JaFS-L01-1314-T04-A 1 5.50E+00 U1/2
As JaFS-L01-1314-T05-A 1 5.50E+00 U1/2
As JaFS-L01-1314-T06-A 1 5.50E+00 U1/2
As JaFS-L01-1314-T07-A 1 5.50E+00 U1/2
As JaFS-L01-1314-T08-A 1 5.50E+00 U1/2
As JaFS-L01-1314-T09-A 1 5.50E+00 U1/2
As JaFS-L01-1314-T01-B 1 5.50E+00 U1/2
As JaFS-L01-1314-T02-B 1 5.50E+00 U1/2
As JaFS-L01-1314-T03-B 1 5.50E+00 U1/2
As JaFS-L01-1314-T04-B 1 5.50E+00 U1/2
As JaFS-L01-1314-T05-B 1 5.50E+00 U1/2
As JaFS-L01-1314-T06-B 1 5.50E+00 U1/2
As JaFS-L01-1314-T07-B 1 5.50E+00 U1/2
As JaFS-L01-1314-T08-B 1 5.50E+00 U1/2
As JaFS-L01-1314-T09-B 1 5.50E+00 U1/2
As JaFS-L01-1314-T01-C 1 5.50E+00 U1/2
As JaFS-L01-1314-T02-C 1 5.50E+00 U1/2
As JaFS-L01-1314-T03-C 1 5.50E+00 U1/2
As JaFS-L01-1314-T04-C 1 5.50E+00 U1/2
As JaFS-L01-1314-T05-C 1 5.50E+00 U1/2
As JaFS-L01-1314-T06-C 1 5.50E+00 U1/2
As JaFS-L01-1314-T07-C 1 5.50E+00 U1/2
As JaFS-L01-1314-T08-C 1 5.50E+00 U1/2
As JaFS-L01-1314-T09-C 1 5.50E+00 U1/2
As JaFS-L01-1314-B01-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.50E+00 23.14 11.00 35.00
5.50E+00 25.69 11.00 35.00
5.50E+00 23.84 11.00 35.00 10000 1000
5.50E+00 11.52 11.00 35.00
5.50E+00 22.09 11.00 35.00
5.50E+00 30.54 11.00 35.00
5.50E+00 33.16 11.00 35.00
5.50E+00 19.57 11.00 35.00
5.50E+00 4.30 11.00 35.00
5.50E+00 37.33 11.00 35.00
5.50E+00 10.36 11.00 35.00
5.50E+00 24.52 11.00 35.00 10000 1000
5.50E+00 20.63 11.00 35.00
5.50E+00 37.58 11.00 35.00
5.50E+00 24.86 11.00 35.00
5.50E+00 31.17 11.00 35.00
5.50E+00 25.96 11.00 35.00
5.50E+00 36.93 11.00 35.00
5.50E+00 14.99 11.00 35.00
5.50E+00 33.44 11.00 35.00
5.50E+00 31.50 11.00 35.00 10000 1000
5.50E+00 21.29 11.00 35.00
5.50E+00 35.13 11.00 35.00
5.50E+00 27.87 11.00 35.00
5.50E+00 9.64 11.00 35.00
5.50E+00 45.78 11.00 35.00
5.50E+00 20.85 11.00 35.00
5.50E+00 44.37 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.26E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.18E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.05E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-238
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
B JaFS-L01-1314-T01-A 1 1.77E+05
B JaFS-L01-1314-T02-A 1 6.08E+04
B JaFS-L01-1314-T03-A 1 2.15E+04
B JaFS-L01-1314-T04-A 1 8.76E+03
B JaFS-L01-1314-T05-A 1 5.46E+03
B JaFS-L01-1314-T06-A 1 2.38E+03
B JaFS-L01-1314-T07-A 1 1.39E+03
B JaFS-L01-1314-T08-A 1 8.33E+02
B JaFS-L01-1314-T09-A 1 5.93E+02
B JaFS-L01-1314-T01-B 1 2.03E+05
B JaFS-L01-1314-T02-B 1 6.45E+04
B JaFS-L01-1314-T03-B 1 2.19E+04
B JaFS-L01-1314-T04-B 1 9.13E+03
B JaFS-L01-1314-T05-B 1 5.15E+03
B JaFS-L01-1314-T06-B 1 2.43E+03
B JaFS-L01-1314-T07-B 1 1.41E+03
B JaFS-L01-1314-T08-B 1 8.43E+02
B JaFS-L01-1314-T09-B 1 6.08E+02
B JaFS-L01-1314-T01-C 1 1.97E+05
B JaFS-L01-1314-T02-C 1 6.11E+04
B JaFS-L01-1314-T03-C 1 2.14E+04
B JaFS-L01-1314-T04-C 1 8.94E+03
B JaFS-L01-1314-T05-C 1 5.46E+03
B JaFS-L01-1314-T06-C 1 2.45E+03
B JaFS-L01-1314-T07-C 1 1.41E+03
B JaFS-L01-1314-T08-C 1 8.89E+02
B JaFS-L01-1314-T09-C 1 6.31E+02
B JaFS-L01-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.77E+05 0.95 1.00 3.18
6.08E+04 1.47 1.00 3.18
2.15E+04 1.20 1.00 3.18 10000 1000
8.76E+03 1.50 1.00 3.18
5.46E+03 1.64 1.00 3.18
2.38E+03 1.14 1.00 3.18
1.39E+03 1.36 1.00 3.18
8.33E+02 2.71 1.00 3.18
5.93E+02 1.37 1.00 3.18
2.03E+05 1.08 1.00 3.18
6.45E+04 0.17 1.00 3.18
2.19E+04 0.95 1.00 3.18 10000 1000
9.13E+03 1.47 1.00 3.18
5.15E+03 0.34 1.00 3.18
2.43E+03 0.46 1.00 3.18
1.41E+03 1.55 1.00 3.18
8.43E+02 1.95 1.00 3.18
6.08E+02 2.59 1.00 3.18
1.97E+05 0.30 1.00 3.18
6.11E+04 2.47 1.00 3.18
2.14E+04 1.96 1.00 3.18 10000 1000
8.94E+03 1.22 1.00 3.18
5.46E+03 2.72 1.00 3.18
2.45E+03 0.76 1.00 3.18
1.41E+03 2.28 1.00 3.18
8.89E+02 1.62 1.00 3.18
6.31E+02 0.41 1.00 3.18
5.00E-01 9.13 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.24E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.28E+04 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.23E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-239
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Ba JaFS-L01-1314-T01-A 1 1.29E+02
Ba JaFS-L01-1314-T02-A 1 9.14E+01
Ba JaFS-L01-1314-T03-A 1 4.21E+01
Ba JaFS-L01-1314-T04-A 1 3.03E+01
Ba JaFS-L01-1314-T05-A 1 3.22E+01
Ba JaFS-L01-1314-T06-A 1 2.33E+01
Ba JaFS-L01-1314-T07-A 1 1.64E+01
Ba JaFS-L01-1314-T08-A 1 1.24E+01
Ba JaFS-L01-1314-T09-A 1 1.06E+01
Ba JaFS-L01-1314-T01-B 1 1.17E+02
Ba JaFS-L01-1314-T02-B 1 8.66E+01
Ba JaFS-L01-1314-T03-B 1 4.38E+01
Ba JaFS-L01-1314-T04-B 1 3.09E+01
Ba JaFS-L01-1314-T05-B 1 3.30E+01
Ba JaFS-L01-1314-T06-B 1 2.37E+01
Ba JaFS-L01-1314-T07-B 1 1.76E+01
Ba JaFS-L01-1314-T08-B 1 1.28E+01
Ba JaFS-L01-1314-T09-B 1 1.04E+01
Ba JaFS-L01-1314-T01-C 1 1.23E+02
Ba JaFS-L01-1314-T02-C 1 1.12E+02
Ba JaFS-L01-1314-T03-C 1 4.89E+01
Ba JaFS-L01-1314-T04-C 1 3.71E+01
Ba JaFS-L01-1314-T05-C 1 3.69E+01
Ba JaFS-L01-1314-T06-C 1 2.99E+01
Ba JaFS-L01-1314-T07-C 1 2.22E+01
Ba JaFS-L01-1314-T08-C 1 1.58E+01
Ba JaFS-L01-1314-T09-C 1 1.13E+01
Ba JaFS-L01-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.29E+02 0.90 1.00 3.18
9.14E+01 1.67 1.00 3.18
4.21E+01 1.03 1.00 3.18 10000 1000
3.03E+01 0.06 1.00 3.18
3.22E+01 0.76 1.00 3.18
2.33E+01 1.04 1.00 3.18
1.64E+01 0.47 1.00 3.18
1.24E+01 1.92 1.00 3.18
1.06E+01 1.51 1.00 3.18
1.17E+02 0.93 1.00 3.18
8.66E+01 0.12 1.00 3.18
4.38E+01 0.77 1.00 3.18 10000 1000
3.09E+01 1.72 1.00 3.18
3.30E+01 0.54 1.00 3.18
2.37E+01 0.43 1.00 3.18
1.76E+01 1.75 1.00 3.18
1.28E+01 1.10 1.00 3.18
1.04E+01 2.14 1.00 3.18
1.23E+02 0.89 1.00 3.18
1.12E+02 1.03 1.00 3.18
4.89E+01 0.86 1.00 3.18 10000 1000
3.71E+01 0.83 1.00 3.18
3.69E+01 1.04 1.00 3.18
2.99E+01 1.14 1.00 3.18
2.22E+01 0.98 1.00 3.18
1.58E+01 0.80 1.00 3.18
1.13E+01 0.19 1.00 3.18
5.00E-01 10.62 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.85E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.39E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.31 E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-240
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Be JaFS-L01-1314-T01-A 1 9.50E-01 U1/2
Be JaFS-L01-1314-T02-A 1 9.50E-01 U1/2
Be JaFS-L01-1314-T03-A 1 9.50E-01 U1/2
Be JaFS-L01-1314-T04-A 1 9.50E-01 U1/2
Be JaFS-L01-1314-T05-A 1 9.50E-01 U1/2
Be JaFS-L01-1314-T06-A 1 9.50E-01 U1/2
Be JaFS-L01-1314-T07-A 1 9.50E-01 U1/2
Be JaFS-L01-1314-T08-A 1 9.50E-01 U1/2
Be JaFS-L01-1314-T09-A 1 9.50E-01 U1/2
Be JaFS-L01-1314-T01-B 1 9.50E-01 U1/2
Be JaFS-L01-1314-T02-B 1 9.50E-01 U1/2
Be JaFS-L01-1314-T03-B 1 9.50E-01 U1/2
Be JaFS-L01-1314-T04-B 1 9.50E-01 U1/2
Be JaFS-L01-1314-T05-B 1 9.50E-01 U1/2
Be JaFS-L01-1314-T06-B 1 9.50E-01 U1/2
Be JaFS-L01-1314-T07-B 1 9.50E-01 U1/2
Be JaFS-L01-1314-T08-B 1 9.50E-01 U1/2
Be JaFS-L01-1314-T09-B 1 9.50E-01 U1/2
Be JaFS-L01-1314-T01-C 1 9.50E-01 U1/2
Be JaFS-L01-1314-T02-C 1 9.50E-01 U1/2
Be JaFS-L01-1314-T03-C 1 9.50E-01 U1/2
Be JaFS-L01-1314-T04-C 1 9.50E-01 U1/2
Be JaFS-L01-1314-T05-C 1 9.50E-01 U1/2
Be JaFS-L01-1314-T06-C 1 9.50E-01 U1/2
Be JaFS-L01-1314-T07-C 1 9.50E-01 U1/2
Be JaFS-L01-1314-T08-C 1 9.50E-01 U1/2
Be JaFS-L01-1314-T09-C 1 9.50E-01 U1/2
Be JaFS-L01-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 39.01 1.90 6.00
9.50E-01 7.32 1.90 6.00
9.50E-01 21.16 1.90 6.00 10000 1000
9.50E-01 36.81 1.90 6.00
9.50E-01 12.46 1.90 6.00
9.50E-01 27.63 1.90 6.00
9.50E-01 24.76 1.90 6.00
9.50E-01 43.13 1.90 6.00
9.50E-01 26.60 1.90 6.00
9.50E-01 34.97 1.90 6.00
9.50E-01 27.58 1.90 6.00
9.50E-01 14.12 1.90 6.00 10000 1000
9.50E-01 15.77 1.90 6.00
9.50E-01 18.15 1.90 6.00
9.50E-01 26.47 1.90 6.00
9.50E-01 25.41 1.90 6.00
9.50E-01 35.86 1.90 6.00
9.50E-01 11.92 1.90 6.00
9.50E-01 24.33 1.90 6.00
9.50E-01 4.32 1.90 6.00
9.50E-01 18.58 1.90 6.00 10000 1000
9.50E-01 18.23 1.90 6.00
9.50E-01 30.67 1.90 6.00
9.50E-01 24.02 1.90 6.00
9.50E-01 26.55 1.90 6.00
9.50E-01 16.79 1.90 6.00
9.50E-01 37.61 1.90 6.00
9.50E-01 6.30 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.13E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.01E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.26E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-241
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cd JaFS-L01-1314-T01-A 1 1.52E+01
Cd JaFS-L01-1314-T02-A 1 1.10E+00 U1/2
Cd JaFS-L01-1314-T03-A 1 1.10E+00 U1/2
Cd JaFS-L01-1314-T04-A 1 1.10E+00 U1/2
Cd JaFS-L01-1314-T05-A 1 1.10E+00 U1/2
Cd JaFS-L01-1314-T06-A 1 1.10E+00 U1/2
Cd JaFS-L01-1314-T07-A 1 1.10E+00 U1/2
Cd JaFS-L01-1314-T08-A 1 1.10E+00 U1/2
Cd JaFS-L01-1314-T09-A 1 1.10E+00 U1/2
Cd JaFS-L01-1314-T01-B 1 2.09E+01
Cd JaFS-L01-1314-T02-B 1 1.10E+00 U1/2
Cd JaFS-L01-1314-T03-B 1 1.10E+00 U1/2
Cd JaFS-L01-1314-T04-B 1 1.10E+00 U1/2
Cd JaFS-L01-1314-T05-B 1 1.10E+00 U1/2
Cd JaFS-L01-1314-T06-B 1 1.10E+00 U1/2
Cd JaFS-L01-1314-T07-B 1 1.10E+00 U1/2
Cd JaFS-L01-1314-T08-B 1 1.10E+00 U1/2
Cd JaFS-L01-1314-T09-B 1 1.10E+00 U1/2
Cd JaFS-L01-1314-T01-C 1 2.12E+01
Cd JaFS-L01-1314-T02-C 1 1.10E+00 U1/2
Cd JaFS-L01-1314-T03-C 1 1.10E+00 U1/2
Cd JaFS-L01-1314-T04-C 1 1.10E+00 U1/2
Cd JaFS-L01-1314-T05-C 1 1.10E+00 U1/2
Cd JaFS-L01-1314-T06-C 1 1.10E+00 U1/2
Cd JaFS-L01-1314-T07-C 1 1.10E+00 U1/2
Cd JaFS-L01-1314-T08-C 1 1.10E+00 U1/2
Cd JaFS-L01-1314-T09-C 1 1.10E+00 U1/2
Cd JaFS-L01-1314-B01-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.52E+01 3.44 2.20 7.00
1.10E+00 11.11 2.20 7.00
1.10E+00 26.66 2.20 7.00 10000 1000
1.10E+00 8.96 2.20 7.00
1.10E+00 11.67 2.20 7.00
1.10E+00 14.19 2.20 7.00
1.10E+00 13.07 2.20 7.00
1.10E+00 23.26 2.20 7.00
1.10E+00 25.01 2.20 7.00
2.09E+01 0.44 2.20 7.00
1.10E+00 8.71 2.20 7.00
1.10E+00 20.01 2.20 7.00 10000 1000
1.10E+00 18.56 2.20 7.00
1.10E+00 20.93 2.20 7.00
1.10E+00 20.90 2.20 7.00
1.10E+00 18.68 2.20 7.00
1.10E+00 24.38 2.20 7.00
1.10E+00 28.80 2.20 7.00
2.12E+01 1.79 2.20 7.00
1.10E+00 1.47 2.20 7.00
1.10E+00 18.88 2.20 7.00 10000 1000
1.10E+00 11.66 2.20 7.00
1.10E+00 7.44 2.20 7.00
1.10E+00 5.90 2.20 7.00
1.10E+00 12.96 2.20 7.00
1.10E+00 26.28 2.20 7.00
1.10E+00 21.30 2.20 7.00
1.10E+00 15.83 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.13E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.26E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.05E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-242
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Ca JaFS-L01-1314-T01-A 1 2.99E+05
Ca JaFS-L01-1314-T02-A 1 2.42E+04
Ca JaFS-L01-1314-T03-A 1 1.56E+04
Ca JaFS-L01-1314-T04-A 1 1.47E+04
Ca JaFS-L01-1314-T05-A 1 1.62E+04
Ca JaFS-L01-1314-T06-A 1 1.36E+04
Ca JaFS-L01-1314-T07-A 1 1.12E+04
Ca JaFS-L01-1314-T08-A 1 9.74E+03
Ca JaFS-L01-1314-T09-A 1 9.21E+03
Ca JaFS-L01-1314-T01-B 1 3.89E+05
Ca JaFS-L01-1314-T02-B 1 3.19E+04
Ca JaFS-L01-1314-T03-B 1 1.61E+04
Ca JaFS-L01-1314-T04-B 1 1.50E+04
Ca JaFS-L01-1314-T05-B 1 1.65E+04
Ca JaFS-L01-1314-T06-B 1 1.38E+04
Ca JaFS-L01-1314-T07-B 1 1.17E+04
Ca JaFS-L01-1314-T08-B 1 9.86E+03
Ca JaFS-L01-1314-T09-B 1 9.16E+03
Ca JaFS-L01-1314-T01-C 1 3.26E+05
Ca JaFS-L01-1314-T02-C 1 3.26E+04
Ca JaFS-L01-1314-T03-C 1 1.79E+04
Ca JaFS-L01-1314-T04-C 1 1.69E+04
Ca JaFS-L01-1314-T05-C 1 1.77E+04
Ca JaFS-L01-1314-T06-C 1 1.54E+04
Ca JaFS-L01-1314-T07-C 1 1.36E+04
Ca JaFS-L01-1314-T08-C 1 1.13E+04
Ca JaFS-L01-1314-T09-C 1 9.98E+03
Ca JaFS-L01-1314-B01-A 1 1.30E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.99E+05 1.21 2.60 8.30
2.42E+04 0.82 2.60 8.30
1.56E+04 1.10 2.60 8.30 10000 1000
1.47E+04 0.24 2.60 8.30
1.62E+04 0.77 2.60 8.30
1.36E+04 0.82 2.60 8.30
1.12E+04 0.53 2.60 8.30
9.74E+03 1.57 2.60 8.30
9.21 E+03 1.34 2.60 8.30
3.89E+05 0.67 2.60 8.30
3.19E+04 0.03 2.60 8.30
1.61E+04 0.96 2.60 8.30 10000 1000
1.50E+04 1.05 2.60 8.30
1.65E+04 0.88 2.60 8.30
1.38E+04 0.51 2.60 8.30
1.17E+04 1.61 2.60 8.30
9.86E+03 1.23 2.60 8.30
9.16E+03 2.04 2.60 8.30
3.26E+05 0.47 2.60 8.30
3.26E+04 0.96 2.60 8.30
1.79E+04 1.02 2.60 8.30 10000 1000
1.69E+04 1.42 2.60 8.30
1.77E+04 0.90 2.60 8.30
1.54E+04 1.37 2.60 8.30
1.36E+04 0.87 2.60 8.30
1.13E+04 0.51 2.60 8.30
9.98E+03 0.31 2.60 8.30
1.30E+00 10.20 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.65E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.71E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.88E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-243
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cr JaFS-L01-1314-T01-A 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T02-A 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T03-A 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T04-A 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T05-A 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T06-A 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T07-A 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T08-A 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T09-A 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T01-B 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T02-B 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T03-B 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T04-B 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T05-B 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T06-B 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T07-B 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T08-B 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T09-B 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T01-C 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T02-C 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T03-C 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T04-C 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T05-C 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T06-C 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T07-C 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T08-C 1 6.00E-01 U1/2
Cr JaFS-L01-1314-T09-C 1 6.00E-01 U1/2
Cr JaFS-L01-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 28.40 1.20 3.82
6.00E-01 31.40 1.20 3.82
6.00E-01 8.04 1.20 3.82 10000 1000
6.00E-01 14.83 1.20 3.82
6.00E-01 11.12 1.20 3.82
6.00E-01 7.42 1.20 3.82
6.00E-01 9.82 1.20 3.82
6.00E-01 16.76 1.20 3.82
6.00E-01 24.28 1.20 3.82
6.00E-01 22.28 1.20 3.82
6.00E-01 11.60 1.20 3.82
6.00E-01 14.33 1.20 3.82 10000 1000
6.00E-01 12.85 1.20 3.82
6.00E-01 9.17 1.20 3.82
6.00E-01 15.96 1.20 3.82
6.00E-01 24.74 1.20 3.82
6.00E-01 24.56 1.20 3.82
6.00E-01 18.53 1.20 3.82
6.00E-01 12.53 1.20 3.82
6.00E-01 9.99 1.20 3.82
6.00E-01 20.47 1.20 3.82 10000 1000
6.00E-01 13.63 1.20 3.82
6.00E-01 10.33 1.20 3.82
6.00E-01 24.35 1.20 3.82
6.00E-01 8.22 1.20 3.82
6.00E-01 18.06 1.20 3.82
6.00E-01 32.17 1.20 3.82
6.00E-01 20.58 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.01E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.40E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.22E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-244
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Co JaFS-L01-1314-T01-A 1 9.00E-01 U1/2
Co JaFS-L01-1314-T02-A 1 9.00E-01 U1/2
Co JaFS-L01-1314-T03-A 1 9.00E-01 U1/2
Co JaFS-L01-1314-T04-A 1 9.00E-01 U1/2
Co JaFS-L01-1314-T05-A 1 9.00E-01 U1/2
Co JaFS-L01-1314-T06-A 1 9.00E-01 U1/2
Co JaFS-L01-1314-T07-A 1 9.00E-01 U1/2
Co JaFS-L01-1314-T08-A 1 9.00E-01 U1/2
Co JaFS-L01-1314-T09-A 1 9.00E-01 U1/2
Co JaFS-L01-1314-T01-B 1 9.00E-01 U1/2
Co JaFS-L01-1314-T02-B 1 9.00E-01 U1/2
Co JaFS-L01-1314-T03-B 1 9.00E-01 U1/2
Co JaFS-L01-1314-T04-B 1 9.00E-01 U1/2
Co JaFS-L01-1314-T05-B 1 9.00E-01 U1/2
Co JaFS-L01-1314-T06-B 1 9.00E-01 U1/2
Co JaFS-L01-1314-T07-B 1 9.00E-01 U1/2
Co JaFS-L01-1314-T08-B 1 9.00E-01 U1/2
Co JaFS-L01-1314-T09-B 1 9.00E-01 U1/2
Co JaFS-L01-1314-T01-C 1 9.00E-01 U1/2
Co JaFS-L01-1314-T02-C 1 9.00E-01 U1/2
Co JaFS-L01-1314-T03-C 1 9.00E-01 U1/2
Co JaFS-L01-1314-T04-C 1 9.00E-01 U1/2
Co JaFS-L01-1314-T05-C 1 9.00E-01 U1/2
Co JaFS-L01-1314-T06-C 1 9.00E-01 U1/2
Co JaFS-L01-1314-T07-C 1 9.00E-01 U1/2
Co JaFS-L01-1314-T08-C 1 9.00E-01 U1/2
Co JaFS-L01-1314-T09-C 1 9.00E-01 U1/2
Co JaFS-L01-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 21.38 1.80 5.72
9.00E-01 16.56 1.80 5.72
9.00E-01 17.43 1.80 5.72 10000 1000
9.00E-01 20.56 1.80 5.72
9.00E-01 22.73 1.80 5.72
9.00E-01 32.85 1.80 5.72
9.00E-01 14.41 1.80 5.72
9.00E-01 30.83 1.80 5.72
9.00E-01 20.27 1.80 5.72
9.00E-01 32.95 1.80 5.72
9.00E-01 26.30 1.80 5.72
9.00E-01 31.62 1.80 5.72 10000 1000
9.00E-01 28.07 1.80 5.72
9.00E-01 17.33 1.80 5.72
9.00E-01 13.92 1.80 5.72
9.00E-01 18.24 1.80 5.72
9.00E-01 23.49 1.80 5.72
9.00E-01 13.27 1.80 5.72
9.00E-01 9.68 1.80 5.72
9.00E-01 8.82 1.80 5.72
9.00E-01 14.32 1.80 5.72 10000 1000
9.00E-01 8.20 1.80 5.72
9.00E-01 22.47 1.80 5.72
9.00E-01 23.09 1.80 5.72
9.00E-01 16.73 1.80 5.72
9.00E-01 28.03 1.80 5.72
9.00E-01 31.78 1.80 5.72
9.00E-01 17.03 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.04E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.10E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.15E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-245
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Cu JaFS-L01-1314-T01-A 1 1.20E+03
Cu JaFS-L01-1314-T02-A 1 8.26E+02
Cu JaFS-L01-1314-T03-A 1 5.20E+02
Cu JaFS-L01-1314-T04-A 1 3.30E+02
Cu JaFS-L01-1314-T05-A 1 2.56E+02
Cu JaFS-L01-1314-T06-A 1 1.94E+02
Cu JaFS-L01-1314-T07-A 1 1.53E+02
Cu JaFS-L01-1314-T08-A 1 1.02E+02
Cu JaFS-L01-1314-T09-A 1 7.32E+01
Cu JaFS-L01-1314-T01-B 1 1.37E+03
Cu JaFS-L01-1314-T02-B 1 8.88E+02
Cu JaFS-L01-1314-T03-B 1 5.29E+02
Cu JaFS-L01-1314-T04-B 1 3.44E+02
Cu JaFS-L01-1314-T05-B 1 2.68E+02
Cu JaFS-L01-1314-T06-B 1 2.00E+02
Cu JaFS-L01-1314-T07-B 1 1.59E+02
Cu JaFS-L01-1314-T08-B 1 9.99E+01
Cu JaFS-L01-1314-T09-B 1 6.73E+01
Cu JaFS-L01-1314-T01-C 1 1.39E+03
Cu JaFS-L01-1314-T02-C 1 8.63E+02
Cu JaFS-L01-1314-T03-C 1 5.17E+02
Cu JaFS-L01-1314-T04-C 1 3.36E+02
Cu JaFS-L01-1314-T05-C 1 2.64E+02
Cu JaFS-L01-1314-T06-C 1 1.77E+02
Cu JaFS-L01-1314-T07-C 1 1.26E+02
Cu JaFS-L01-1314-T08-C 1 9.09E+01
Cu JaFS-L01-1314-T09-C 1 6.32E+01
Cu JaFS-L01-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.20E+03 1.54 3.70 11.80
8.26E+02 0.89 3.70 11.80
5.20E+02 1.16 3.70 11.80 10000 1000
3.30E+02 1.04 3.70 11.80
2.56E+02 0.54 3.70 11.80
1.94E+02 0.83 3.70 11.80
1.53E+02 1.70 3.70 11.80
1.02E+02 1.84 3.70 11.80
7.32E+01 0.80 3.70 11.80
1.37E+03 0.99 3.70 11.80
8.88E+02 0.61 3.70 11.80
5.29E+02 1.03 3.70 11.80 10000 1000
3.44E+02 1.18 3.70 11.80
2.68E+02 0.46 3.70 11.80
2.00E+02 0.47 3.70 11.80
1.59E+02 0.27 3.70 11.80
9.99E+01 1.85 3.70 11.80
6.73E+01 2.88 3.70 11.80
1.39E+03 0.76 3.70 11.80
8.63E+02 1.63 3.70 11.80
5.17E+02 0.48 3.70 11.80 10000 1000
3.36E+02 1.14 3.70 11.80
2.64E+02 0.91 3.70 11.80
1.77E+02 0.43 3.70 11.80
1.26E+02 1.40 3.70 11.80
9.09E+01 0.62 3.70 11.80
6.32E+01 0.43 3.70 11.80
1.85E+00 30.94 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.46E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.49E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.40E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-246
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Fe JaFS-L01-1314-T01-A 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T02-A 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T03-A 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T04-A 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T05-A 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T06-A 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T07-A 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T08-A 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T09-A 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T01-B 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T02-B 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T03-B 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T04-B 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T05-B 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T06-B 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T07-B 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T08-B 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T09-B 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T01-C 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T02-C 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T03-C 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T04-C 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T05-C 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T06-C 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T07-C 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T08-C 1 1.00E+00 U1/2
Fe JaFS-L01-1314-T09-C 1 1.00E+00 U1/2
Fe JaFS-L01-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 9.25 2.00 6.40
1.00E+00 5.59 2.00 6.40
1.00E+00 9.44 2.00 6.40 10000 1000
1.00E+00 1.55 2.00 6.40
1.00E+00 24.06 2.00 6.40
1.00E+00 3.83 2.00 6.40
1.00E+00 2.83 2.00 6.40
1.00E+00 6.45 2.00 6.40
1.00E+00 1.59 2.00 6.40
1.00E+00 13.39 2.00 6.40
1.00E+00 9.34 2.00 6.40
1.00E+00 4.10 2.00 6.40 10000 1000
1.00E+00 5.41 2.00 6.40
1.00E+00 12.38 2.00 6.40
1.00E+00 5.36 2.00 6.40
1.00E+00 3.76 2.00 6.40
1.00E+00 2.26 2.00 6.40
1.00E+00 3.95 2.00 6.40
1.00E+00 11.99 2.00 6.40
1.00E+00 4.35 2.00 6.40
1.00E+00 9.25 2.00 6.40 10000 1000
1.00E+00 1.49 2.00 6.40
1.00E+00 19.53 2.00 6.40
1.00E+00 1.62 2.00 6.40
1.00E+00 15.21 2.00 6.40
1.00E+00 4.09 2.00 6.40
1.00E+00 13.10 2.00 6.40
1.00E+00 20.72 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.21E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.14E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.22E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-247
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
Pb JaFS-L01-1314-T01-A 1 7.50E+01
Pb JaFS-L01-1314-T02-A 1 1.18E+02
Pb JaFS-L01-1314-T03-A 1 9.59E+01
Pb JaFS-L01-1314-T04-A 1 8.62E+01
Pb JaFS-L01-1314-T05-A 1 6.61E+01
Pb JaFS-L01-1314-T06-A 1 5.42E+01
Pb JaFS-L01-1314-T07-A 1 4.83E+01
Pb JaFS-L01-1314-T08-A 1 4.24E+01
Pb JaFS-L01-1314-T09-A 1 3.98E+01
Pb JaFS-L01-1314-T01-B 1 8.57E+01
Pb JaFS-L01-1314-T02-B 1 1.17E+02
Pb JaFS-L01-1314-T03-B 1 1.07E+02
Pb JaFS-L01-1314-T04-B 1 8.21E+01
Pb JaFS-L01-1314-T05-B 1 7.18E+01
Pb JaFS-L01-1314-T06-B 1 6.18E+01
Pb JaFS-L01-1314-T07-B 1 5.16E+01
Pb JaFS-L01-1314-T08-B 1 4.54E+01
Pb JaFS-L01-1314-T09-B 1 3.09E+01
Pb JaFS-L01-1314-T01-C 1 8.77E+01
Pb JaFS-L01-1314-T02-C 1 1.24E+02
Pb JaFS-L01-1314-T03-C 1 1.04E+02
Pb JaFS-L01-1314-T04-C 1 9.54E+01
Pb JaFS-L01-1314-T05-C 1 8.28E+01
Pb JaFS-L01-1314-T06-C 1 7.41E+01
Pb JaFS-L01-1314-T07-C 1 6.25E+01
Pb JaFS-L01-1314-T08-C 1 5.40E+01
Pb JaFS-L01-1314-T09-C 1 3.57E+01
Pb JaFS-L01-1314-B01-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.50E+01 3.04 6.80 21.60
1.18E+02 2.87 6.80 21.60
9.59E+01 1.01 6.80 21.60 10000 1000
8.62E+01 1.11 6.80 21.60
6.61 E+01 1.84 6.80 21.60
5.42E+01 3.46 6.80 21.60
4.83E+01 8.16 6.80 21.60
4.24E+01 5.74 6.80 21.60
3.98E+01 3.39 6.80 21.60
8.57E+01 1.43 6.80 21.60
1.17E+02 1.45 6.80 21.60
1.07E+02 3.49 6.80 21.60 10000 1000
8.21 E+01 6.22 6.80 21.60
7.18E+01 0.83 6.80 21.60
6.18E+01 3.54 6.80 21.60
5.16E+01 11.66 6.80 21.60
4.54E+01 2.99 6.80 21.60
3.09E+01 3.61 6.80 21.60
8.77E+01 1.78 6.80 21.60
1.24E+02 0.82 6.80 21.60
1.04E+02 1.64 6.80 21.60 10000 1000
9.54E+01 3.98 6.80 21.60
8.28E+01 4.87 6.80 21.60
7.41 E+01 1.86 6.80 21.60
6.25E+01 3.34 6.80 21.60
5.40E+01 4.75 6.80 21.60
3.57E+01 7.30 6.80 21.60
3.40E+00 57.72 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.68E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.74E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-248
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
Li JaFS-L01-1314-T01-A 1 6.86E+01
Li JaFS-L01-1314-T02-A 1 5.53E+00 E
Li JaFS-L01-1314-T03-A 1 1.92E+00 E
Li JaFS-L01-1314-T04-A 1 9.50E-01 U1/2
Li JaFS-L01-1314-T05-A 1 9.50E-01 U1/2
Li JaFS-L01-1314-T06-A 1 9.50E-01 U1/2
Li JaFS-L01-1314-T07-A 1 9.50E-01 U1/2
Li JaFS-L01-1314-T08-A 1 9.50E-01 U1/2
Li JaFS-L01-1314-T09-A 1 9.50E-01 U1/2
Li JaFS-L01-1314-T01-B 1 7.08E+01
Li JaFS-L01-1314-T02-B 1 8.36E+00
Li JaFS-L01-1314-T03-B 1 9.50E-01 U1/2
Li JaFS-L01-1314-T04-B 1 9.50E-01 U1/2
Li JaFS-L01-1314-T05-B 1 9.50E-01 U1/2
Li JaFS-L01-1314-T06-B 1 9.50E-01 U1/2
Li JaFS-L01-1314-T07-B 1 9.50E-01 U1/2
Li JaFS-L01-1314-T08-B 1 9.50E-01 U1/2
Li JaFS-L01-1314-T09-B 1 9.50E-01 U1/2
Li JaFS-L01-1314-T01-C 1 7.33E+01
Li JaFS-L01-1314-T02-C 1 1.18E+01
Li JaFS-L01-1314-T03-C 1 2.58E+00 E
Li JaFS-L01-1314-T04-C 1 9.50E-01 U1/2
Li JaFS-L01-1314-T05-C 1 9.50E-01 U1/2
Li JaFS-L01-1314-T06-C 1 9.50E-01 U1/2
Li JaFS-L01-1314-T07-C 1 9.50E-01 U1/2
Li JaFS-L01-1314-T08-C 1 9.50E-01 U1/2
Li JaFS-L01-1314-T09-C 1 9.50E-01 U1/2
Li JaFS-L01-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.86E+01 4.66 1.90 6.00
5.53E+00 3.89 1.90 6.00
1.92E+00 15.95 1.90 6.00 10000 1000
9.50E-01 12.11 1.90 6.00
9.50E-01 6.54 1.90 6.00
9.50E-01 7.51 1.90 6.00
9.50E-01 15.55 1.90 6.00
9.50E-01 14.22 1.90 6.00
9.50E-01 9.14 1.90 6.00
7.08E+01 2.99 1.90 6.00
8.36E+00 4.04 1.90 6.00
9.50E-01 8.36 1.90 6.00 10000 1000
9.50E-01 29.26 1.90 6.00
9.50E-01 14.66 1.90 6.00
9.50E-01 32.15 1.90 6.00
9.50E-01 27.51 1.90 6.00
9.50E-01 23.97 1.90 6.00
9.50E-01 13.71 1.90 6.00
7.33E+01 1.95 1.90 6.00
1.18E+01 12.03 1.90 6.00
2.58E+00 14.51 1.90 6.00 10000 1000
9.50E-01 9.96 1.90 6.00
9.50E-01 20.13 1.90 6.00
9.50E-01 16.52 1.90 6.00
9.50E-01 13.66 1.90 6.00
9.50E-01 10.72 1.90 6.00
9.50E-01 12.26 1.90 6.00
9.50E-01 7.37 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.91 E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.79E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.78E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-249
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Mn JaFS-L01-1314-T01-A 1 2.25E+02
Mn JaFS-L01-1314-T02-A 1 2.52E+01
Mn JaFS-L01-1314-T03-A 1 1.81E+01
Mn JaFS-L01-1314-T04-A 1 1.60E+01
Mn JaFS-L01-1314-T05-A 1 1.51E+01
Mn JaFS-L01-1314-T06-A 1 9.98E+00
Mn JaFS-L01-1314-T07-A 1 7.74E+00
Mn JaFS-L01-1314-T08-A 1 4.81E+00 E
Mn JaFS-L01-1314-T09-A 1 3.92E+00 E
Mn JaFS-L01-1314-T01-B 1 3.27E+02
Mn JaFS-L01-1314-T02-B 1 2.50E+01
Mn JaFS-L01-1314-T03-B 1 1.65E+01
Mn JaFS-L01-1314-T04-B 1 1.42E+01
Mn JaFS-L01-1314-T05-B 1 1.37E+01
Mn JaFS-L01-1314-T06-B 1 9.95E+00
Mn JaFS-L01-1314-T07-B 1 8.03E+00
Mn JaFS-L01-1314-T08-B 1 5.22E+00 E
Mn JaFS-L01-1314-T09-B 1 4.54E+00 E
Mn JaFS-L01-1314-T01-C 1 2.76E+02
Mn JaFS-L01-1314-T02-C 1 2.97E+01
Mn JaFS-L01-1314-T03-C 1 2.15E+01
Mn JaFS-L01-1314-T04-C 1 1.65E+01
Mn JaFS-L01-1314-T05-C 1 1.61E+01
Mn JaFS-L01-1314-T06-C 1 1.46E+01
Mn JaFS-L01-1314-T07-C 1 1.01E+01
Mn JaFS-L01-1314-T08-C 1 6.71E+00
Mn JaFS-L01-1314-T09-C 1 4.32E+00 E
Mn JaFS-L01-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.25E+02 1.35 2.00 6.40
2.52E+01 1.05 2.00 6.40
1.81E+01 0.68 2.00 6.40 10000 1000
1.60E+01 0.59 2.00 6.40
1.51E+01 0.48 2.00 6.40
9.98E+00 0.64 2.00 6.40
7.74E+00 0.78 2.00 6.40
4.81 E+00 2.57 2.00 6.40
3.92E+00 2.84 2.00 6.40
3.27E+02 0.57 2.00 6.40
2.50E+01 0.37 2.00 6.40
1.65E+01 0.64 2.00 6.40 10000 1000
1.42E+01 1.43 2.00 6.40
1.37E+01 0.96 2.00 6.40
9.95E+00 0.78 2.00 6.40
8.03E+00 1.81 2.00 6.40
5.22E+00 2.31 2.00 6.40
4.54E+00 1.96 2.00 6.40
2.76E+02 0.74 2.00 6.40
2.97E+01 2.45 2.00 6.40
2.15E+01 1.57 2.00 6.40 10000 1000
1.65E+01 1.06 2.00 6.40
1.61E+01 1.03 2.00 6.40
1.46E+01 1.91 2.00 6.40
1.01E+01 0.89 2.00 6.40
6.71 E+00 1.35 2.00 6.40
4.32E+00 1.12 2.00 6.40
1.00E+00 11.81 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.42E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.40E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-250
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Mg JaFS-L01-1314-T01-A 1 6.54E+04
Mg JaFS-L01-1314-T02-A 1 7.58E+03
Mg JaFS-L01-1314-T03-A 1 2.28E+03
Mg JaFS-L01-1314-T04-A 1 2.09E+03
Mg JaFS-L01-1314-T05-A 1 2.27E+03
Mg JaFS-L01-1314-T06-A 1 1.80E+03
Mg JaFS-L01-1314-T07-A 1 1.39E+03
Mg JaFS-L01-1314-T08-A 1 1.13E+03
Mg JaFS-L01-1314-T09-A 1 1.05E+03
Mg JaFS-L01-1314-T01-B 1 6.71E+04
Mg JaFS-L01-1314-T02-B 1 8.07E+03
Mg JaFS-L01-1314-T03-B 1 2.16E+03
Mg JaFS-L01-1314-T04-B 1 1.99E+03
Mg JaFS-L01-1314-T05-B 1 2.21E+03
Mg JaFS-L01-1314-T06-B 1 1.77E+03
Mg JaFS-L01-1314-T07-B 1 1.44E+03
Mg JaFS-L01-1314-T08-B 1 1.14E+03
Mg JaFS-L01-1314-T09-B 1 1.01E+03
Mg JaFS-L01-1314-T01-C 1 6.75E+04
Mg JaFS-L01-1314-T02-C 1 7.98E+03
Mg JaFS-L01-1314-T03-C 1 2.89E+03
Mg JaFS-L01-1314-T04-C 1 2.62E+03
Mg JaFS-L01-1314-T05-C 1 2.71E+03
Mg JaFS-L01-1314-T06-C 1 2.27E+03
Mg JaFS-L01-1314-T07-C 1 1.80E+03
Mg JaFS-L01-1314-T08-C 1 1.38E+03
Mg JaFS-L01-1314-T09-C 1 1.15E+03
Mg JaFS-L01-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.54E+04 0.53 1.00 3.18
7.58E+03 1.51 1.00 3.18
2.28E+03 0.72 1.00 3.18 10000 1000
2.09E+03 0.79 1.00 3.18
2.27E+03 0.65 1.00 3.18
1.80E+03 1.44 1.00 3.18
1.39E+03 1.71 1.00 3.18
1.13E+03 1.94 1.00 3.18
1.05E+03 1.03 1.00 3.18
6.71E+04 0.44 1.00 3.18
8.07E+03 0.86 1.00 3.18
2.16E+03 1.05 1.00 3.18 10000 1000
1.99E+03 2.21 1.00 3.18
2.21E+03 0.82 1.00 3.18
1.77E+03 0.64 1.00 3.18
1.44E+03 1.90 1.00 3.18
1.14E+03 1.14 1.00 3.18
1.01E+03 2.03 1.00 3.18
6.75E+04 0.85 1.00 3.18
7.98E+03 1.27 1.00 3.18
2.89E+03 1.49 1.00 3.18 10000 1000
2.62E+03 1.22 1.00 3.18
2.71E+03 1.41 1.00 3.18
2.27E+03 1.35 1.00 3.18
1.80E+03 2.29 1.00 3.18
1.38E+03 0.47 1.00 3.18
1.15E+03 0.17 1.00 3.18
5.00E-01 5.92 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.18E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.08E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.76E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-251
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Mo JaFS-L01-1314-T01-A 1 1.42E+02
Mo JaFS-L01-1314-T02-A 1 4.88E+01
Mo JaFS-L01-1314-T03-A 1 1.77E+01
Mo JaFS-L01-1314-T04-A 1 1.40E+01
Mo JaFS-L01-1314-T05-A 1 9.87E+00
Mo JaFS-L01-1314-T06-A 1 6.43E+00
Mo JaFS-L01-1314-T07-A 1 4.43E+00
Mo JaFS-L01-1314-T08-A 1 3.25E+00 E
Mo JaFS-L01-1314-T09-A 1 1.78E+00 E
Mo JaFS-L01-1314-T01-B 1 1.54E+02
Mo JaFS-L01-1314-T02-B 1 5.39E+01
Mo JaFS-L01-1314-T03-B 1 1.82E+01
Mo JaFS-L01-1314-T04-B 1 1.35E+01
Mo JaFS-L01-1314-T05-B 1 1.10E+01
Mo JaFS-L01-1314-T06-B 1 5.88E+00
Mo JaFS-L01-1314-T07-B 1 4.61E+00
Mo JaFS-L01-1314-T08-B 1 2.61E+00 E
Mo JaFS-L01-1314-T09-B 1 1.23E+00 E
Mo JaFS-L01-1314-T01-C 1 1.40E+02
Mo JaFS-L01-1314-T02-C 1 5.58E+01
Mo JaFS-L01-1314-T03-C 1 1.90E+01
Mo JaFS-L01-1314-T04-C 1 1.40E+01
Mo JaFS-L01-1314-T05-C 1 1.11E+01
Mo JaFS-L01-1314-T06-C 1 6.47E+00
Mo JaFS-L01-1314-T07-C 1 4.81E+00
Mo JaFS-L01-1314-T08-C 1 3.68E+00 E
Mo JaFS-L01-1314-T09-C 1 2.51E+00 E
Mo JaFS-L01-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.42E+02 2.67 1.20 3.82
4.88E+01 1.97 1.20 3.82
1.77E+01 5.92 1.20 3.82 10000 1000
1.40E+01 1.18 1.20 3.82
9.87E+00 7.34 1.20 3.82
6.43E+00 1.24 1.20 3.82
4.43E+00 4.59 1.20 3.82
3.25E+00 12.43 1.20 3.82
1.78E+00 26.37 1.20 3.82
1.54E+02 0.87 1.20 3.82
5.39E+01 0.88 1.20 3.82
1.82E+01 2.45 1.20 3.82 10000 1000
1.35E+01 3.28 1.20 3.82
1.10E+01 3.54 1.20 3.82
5.88E+00 2.46 1.20 3.82
4.61 E+00 5.99 1.20 3.82
2.61E+00 12.61 1.20 3.82
1.23E+00 24.38 1.20 3.82
1.40E+02 1.55 1.20 3.82
5.58E+01 1.17 1.20 3.82
1.90E+01 4.25 1.20 3.82 10000 1000
1.40E+01 3.64 1.20 3.82
1.11E+01 5.41 1.20 3.82
6.47E+00 9.07 1.20 3.82
4.81 E+00 2.61 1.20 3.82
3.68E+00 11.21 1.20 3.82
2.51E+00 16.62 1.20 3.82
6.00E-01 8.85 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.50E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.67E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.10E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-252
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ni JaFS-L01-1314-T01-A 1 1.10E+01
Ni JaFS-L01-1314-T02-A 1 2.58E+00 E
Ni JaFS-L01-1314-T03-A 1 2.74E+00 E
Ni JaFS-L01-1314-T04-A 1 9.00E-01 U1/2
Ni JaFS-L01-1314-T05-A 1 9.00E-01 U1/2
Ni JaFS-L01-1314-T06-A 1 9.00E-01 U1/2
Ni JaFS-L01-1314-T07-A 1 9.00E-01 U1/2
Ni JaFS-L01-1314-T08-A 1 9.00E-01 U1/2
Ni JaFS-L01-1314-T09-A 1 9.00E-01 U1/2
Ni JaFS-L01-1314-T01-B 1 1.57E+01
Ni JaFS-L01-1314-T02-B 1 3.29E+00 E
Ni JaFS-L01-1314-T03-B 1 2.35E+00 E
Ni JaFS-L01-1314-T04-B 1 9.00E-01 U1/2
Ni JaFS-L01-1314-T05-B 1 9.00E-01 U1/2
Ni JaFS-L01-1314-T06-B 1 9.00E-01 U1/2
Ni JaFS-L01-1314-T07-B 1 9.00E-01 U1/2
Ni JaFS-L01-1314-T08-B 1 9.00E-01 U1/2
Ni JaFS-L01-1314-T09-B 1 9.00E-01 U1/2
Ni JaFS-L01-1314-T01-C 1 1.18E+01
Ni JaFS-L01-1314-T02-C 1 3.12E+00 E
Ni JaFS-L01-1314-T03-C 1 2.38E+00 E
Ni JaFS-L01-1314-T04-C 1 9.00E-01 U1/2
Ni JaFS-L01-1314-T05-C 1 9.00E-01 U1/2
Ni JaFS-L01-1314-T06-C 1 9.00E-01 U1/2
Ni JaFS-L01-1314-T07-C 1 9.00E-01 U1/2
Ni JaFS-L01-1314-T08-C 1 9.00E-01 U1/2
Ni JaFS-L01-1314-T09-C 1 9.00E-01 U1/2
Ni JaFS-L01-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+01 9.64 1.80 5.70
2.58E+00 15.97 1.80 5.70
2.74E+00 27.16 1.80 5.70 10000 1000
9.00E-01 21.43 1.80 5.70
9.00E-01 35.65 1.80 5.70
9.00E-01 19.63 1.80 5.70
9.00E-01 24.30 1.80 5.70
9.00E-01 36.83 1.80 5.70
9.00E-01 80.70 1.80 5.70
1.57E+01 7.24 1.80 5.70
3.29E+00 22.36 1.80 5.70
2.35E+00 30.56 1.80 5.70 10000 1000
9.00E-01 19.62 1.80 5.70
9.00E-01 23.48 1.80 5.70
9.00E-01 32.48 1.80 5.70
9.00E-01 39.03 1.80 5.70
9.00E-01 25.61 1.80 5.70
9.00E-01 29.70 1.80 5.70
1.18E+01 3.56 1.80 5.70
3.12E+00 7.83 1.80 5.70
2.38E+00 20.58 1.80 5.70 10000 1000
9.00E-01 14.70 1.80 5.70
9.00E-01 25.03 1.80 5.70
9.00E-01 30.15 1.80 5.70
9.00E-01 29.13 1.80 5.70
9.00E-01 23.16 1.80 5.70
9.00E-01 31.71 1.80 5.70
9.00E-01 38.18 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.05E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.35E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.33E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-253
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
P JaFS-L01-1314-T01-A 1 5.41E+01
P JaFS-L01-1314-T02-A 1 5.54E+01
P JaFS-L01-1314-T03-A 1 4.63E+01
P JaFS-L01-1314-T04-A 1 2.78E+01
P JaFS-L01-1314-T05-A 1 2.48E+01
P JaFS-L01-1314-T06-A 1 2.97E+01
P JaFS-L01-1314-T07-A 1 3.17E+01
P JaFS-L01-1314-T08-A 1 4.40E+01
P JaFS-L01-1314-T09-A 1 6.89E+01
P JaFS-L01-1314-T01-B 1 6.05E+01
P JaFS-L01-1314-T02-B 1 5.63E+01
P JaFS-L01-1314-T03-B 1 3.54E+01
P JaFS-L01-1314-T04-B 1 2.63E+01
P JaFS-L01-1314-T05-B 1 1.20E+01
P JaFS-L01-1314-T06-B 1 1.81E+01
P JaFS-L01-1314-T07-B 1 3.15E+01
P JaFS-L01-1314-T08-B 1 2.42E+01
P JaFS-L01-1314-T09-B 1 5.20E+01
P JaFS-L01-1314-T01-C 1 9.54E+01
P JaFS-L01-1314-T02-C 1 5.69E+01
P JaFS-L01-1314-T03-C 1 2.91E+01
P JaFS-L01-1314-T04-C 1 3.48E+01
P JaFS-L01-1314-T05-C 1 1.36E+01
P JaFS-L01-1314-T06-C 1 2.41E+01
P JaFS-L01-1314-T07-C 1 8.75E+01
P JaFS-L01-1314-T08-C 1 3.55E+01
P JaFS-L01-1314-T09-C 1 4.93E+01
P JaFS-L01-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.41 E+01 8.03 3.70 11.80
5.54E+01 3.18 3.70 11.80
4.63E+01 1.84 3.70 11.80 10000 1000
2.78E+01 1.15 3.70 11.80
2.48E+01 11.62 3.70 11.80
2.97E+01 1.93 3.70 11.80
3.17E+01 0.78 3.70 11.80
4.40E+01 1.06 3.70 11.80
6.89E+01 0.36 3.70 11.80
6.05E+01 1.74 3.70 11.80
5.63E+01 0.98 3.70 11.80
3.54E+01 2.55 3.70 11.80 10000 1000
2.63E+01 0.64 3.70 11.80
1.20E+01 2.48 3.70 11.80
1.81 E+01 3.08 3.70 11.80
3.15E+01 1.69 3.70 11.80
2.42E+01 1.95 3.70 11.80
5.20E+01 0.98 3.70 11.80
9.54E+01 0.43 3.70 11.80
5.69E+01 2.11 3.70 11.80
2.91E+01 1.19 3.70 11.80 10000 1000
3.48E+01 0.62 3.70 11.80
1.36E+01 12.22 3.70 11.80
2. 41 E+01 3.63 3.70 11.80
8.75E+01 1.13 3.70 11.80
3.55E+01 1.17 3.70 11.80
4.93E+01 1.10 3.70 11.80
1.85E+00 30.84 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.63E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.46E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-254
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
K JaFS-L01-1314-T01-A 1 5.32E+04
K JaFS-L01-1314-T02-A 1 1.25E+04
K JaFS-L01-1314-T03-A 1 9.90E+03
K JaFS-L01-1314-T04-A 1 8.67E+03
K JaFS-L01-1314-T05-A 1 8.09E+03
K JaFS-L01-1314-T06-A 1 5.66E+03
K JaFS-L01-1314-T07-A 1 4.03E+03
K JaFS-L01-1314-T08-A 1 2.98E+03
K JaFS-L01-1314-T09-A 1 2.24E+03
K JaFS-L01-1314-T01-B 1 6.47E+04
K JaFS-L01-1314-T02-B 1 1.30E+04
K JaFS-L01-1314-T03-B 1 9.70E+03
K JaFS-L01-1314-T04-B 1 8.61E+03
K JaFS-L01-1314-T05-B 1 8.14E+03
K JaFS-L01-1314-T06-B 1 5.69E+03
K JaFS-L01-1314-T07-B 1 4.17E+03
K JaFS-L01-1314-T08-B 1 3.03E+03
K JaFS-L01-1314-T09-B 1 2.31E+03
K JaFS-L01-1314-T01-C 1 5.88E+04
K JaFS-L01-1314-T02-C 1 1.53E+04
K JaFS-L01-1314-T03-C 1 1.11E+04
K JaFS-L01-1314-T04-C 1 9.39E+03
K JaFS-L01-1314-T05-C 1 8.46E+03
K JaFS-L01-1314-T06-C 1 5.97E+03
K JaFS-L01-1314-T07-C 1 4.45E+03
K JaFS-L01-1314-T08-C 1 3.08E+03
K JaFS-L01-1314-T09-C 1 2.12E+03
K JaFS-L01-1314-B01-A 1 1.82E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.32E+04 0.14 1.60 5.09
1.25E+04 0.67 1.60 5.09
9.90E+03 1.06 1.60 5.09 10000 1000
8.67E+03 0.88 1.60 5.09
8.09E+03 0.90 1.60 5.09
5.66E+03 0.86 1.60 5.09
4.03E+03 0.49 1.60 5.09
2.98E+03 1.73 1.60 5.09
2.24E+03 1.55 1.60 5.09
6.47E+04 0.77 1.60 5.09
1.30E+04 0.03 1.60 5.09
9.70E+03 1.20 1.60 5.09 10000 1000
8.61 E+03 1.70 1.60 5.09
8.14E+03 0.90 1.60 5.09
5.69E+03 0.47 1.60 5.09
4.17E+03 1.79 1.60 5.09
3.03E+03 1.46 1.60 5.09
2.31E+03 2.18 1.60 5.09
5.88E+04 0.68 1.60 5.09
1.53E+04 1.25 1.60 5.09
1.11E+04 1.12 1.60 5.09 10000 1000
9.39E+03 1.10 1.60 5.09
8.46E+03 0.90 1.60 5.09
5.97E+03 1.40 1.60 5.09
4.45E+03 0.91 1.60 5.09
3.08E+03 0.68 1.60 5.09
2.12E+03 0.41 1.60 5.09
1.82E+01 3.46 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.08E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.20E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-255
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Se JaFS-L01-1314-T01-A 1 5.36E+01
Se JaFS-L01-1314-T02-A 1 1.86E+01 E
Se JaFS-L01-1314-T03-A 1 7.50E+00 U1/2
Se JaFS-L01-1314-T04-A 1 7.50E+00 U1/2
Se JaFS-L01-1314-T05-A 1 7.50E+00 U1/2
Se JaFS-L01-1314-T06-A 1 7.50E+00 U1/2
Se JaFS-L01-1314-T07-A 1 7.50E+00 U1/2
Se JaFS-L01-1314-T08-A 1 7.50E+00 U1/2
Se JaFS-L01-1314-T09-A 1 7.50E+00 U1/2
Se JaFS-L01-1314-T01-B 1 5.73E+01
Se JaFS-L01-1314-T02-B 1 2.09E+01 E
Se JaFS-L01-1314-T03-B 1 1.53E+01 E
Se JaFS-L01-1314-T04-B 1 7.50E+00 U1/2
Se JaFS-L01-1314-T05-B 1 7.50E+00 U1/2
Se JaFS-L01-1314-T06-B 1 7.50E+00 U1/2
Se JaFS-L01-1314-T07-B 1 7.50E+00 U1/2
Se JaFS-L01-1314-T08-B 1 7.50E+00 U1/2
Se JaFS-L01-1314-T09-B 1 7.50E+00 U1/2
Se JaFS-L01-1314-T01-C 1 5.99E+01
Se JaFS-L01-1314-T02-C 1 1.91E+01 E
Se JaFS-L01-1314-T03-C 1 7.50E+00 U1/2
Se JaFS-L01-1314-T04-C 1 7.50E+00 U1/2
Se JaFS-L01-1314-T05-C 1 7.50E+00 U1/2
Se JaFS-L01-1314-T06-C 1 7.50E+00 U1/2
Se JaFS-L01-1314-T07-C 1 7.50E+00 U1/2
Se JaFS-L01-1314-T08-C 1 7.50E+00 U1/2
Se JaFS-L01-1314-T09-C 1 7.50E+00 U1/2
Se JaFS-L01-1314-B01-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.36E+01 11.67 15.00 47.70
1.86E+01 10.55 15.00 47.70
7.50E+00 33.09 15.00 47.70 10000 1000
7.50E+00 15.72 15.00 47.70
7.50E+00 19.79 15.00 47.70
7.50E+00 11.18 15.00 47.70
7.50E+00 18.05 15.00 47.70
7.50E+00 5.38 15.00 47.70
7.50E+00 11.57 15.00 47.70
5.73E+01 10.18 15.00 47.70
2.09E+01 10.65 15.00 47.70
1.53E+01 10.80 15.00 47.70 10000 1000
7.50E+00 18.30 15.00 47.70
7.50E+00 8.22 15.00 47.70
7.50E+00 19.25 15.00 47.70
7.50E+00 10.85 15.00 47.70
7.50E+00 6.58 15.00 47.70
7.50E+00 20.31 15.00 47.70
5.99E+01 9.71 15.00 47.70
1.91E+01 14.26 15.00 47.70
7.50E+00 36.18 15.00 47.70 10000 1000
7.50E+00 24.94 15.00 47.70
7.50E+00 40.46 15.00 47.70
7.50E+00 21.46 15.00 47.70
7.50E+00 13.00 15.00 47.70
7.50E+00 7.17 15.00 47.70
7.50E+00 13.34 15.00 47.70
7.50E+00 9.20 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.70E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.48E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.28E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-256
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Si JaFS-L01-1314-T01-A 1 4.82E+03
Si JaFS-L01-1314-T02-A 1 3.15E+03
Si JaFS-L01-1314-T03-A 1 2.15E+03
Si JaFS-L01-1314-T04-A 1 2.02E+03
Si JaFS-L01-1314-T05-A 1 2.00E+03
Si JaFS-L01-1314-T06-A 1 2.00E+03
Si JaFS-L01-1314-T07-A 1 2.04E+03
Si JaFS-L01-1314-T08-A 1 2.28E+03
Si JaFS-L01-1314-T09-A 1 2.56E+03
Si JaFS-L01-1314-T01-B 1 4.87E+03
Si JaFS-L01-1314-T02-B 1 3.38E+03
Si JaFS-L01-1314-T03-B 1 2.11E+03
Si JaFS-L01-1314-T04-B 1 1.99E+03
Si JaFS-L01-1314-T05-B 1 1.99E+03
Si JaFS-L01-1314-T06-B 1 1.97E+03
Si JaFS-L01-1314-T07-B 1 2.09E+03
Si JaFS-L01-1314-T08-B 1 2.25E+03
Si JaFS-L01-1314-T09-B 1 2.58E+03
Si JaFS-L01-1314-T01-C 1 4.88E+03
Si JaFS-L01-1314-T02-C 1 3.28E+03
Si JaFS-L01-1314-T03-C 1 2.01E+03
Si JaFS-L01-1314-T04-C 1 1.86E+03
Si JaFS-L01-1314-T05-C 1 1.87E+03
Si JaFS-L01-1314-T06-C 1 1.91E+03
Si JaFS-L01-1314-T07-C 1 1.98E+03
Si JaFS-L01-1314-T08-C 1 2.20E+03
Si JaFS-L01-1314-T09-C 1 2.45E+03
Si JaFS-L01-1314-B01-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.82E+03 0.48 1.10 3.50
3.15E+03 1.55 1.10 3.50
2.15E+03 0.81 1.10 3.50 10000 1000
2.02E+03 0.52 1.10 3.50
2.00E+03 0.34 1.10 3.50
2.00E+03 0.91 1.10 3.50
2.04E+03 0.29 1.10 3.50
2.28E+03 1.88 1.10 3.50
2.56E+03 1.02 1.10 3.50
4.87E+03 0.26 1.10 3.50
3.38E+03 0.36 1.10 3.50
2.11E+03 1.25 1.10 3.50 10000 1000
1.99E+03 1.77 1.10 3.50
1.99E+03 0.83 1.10 3.50
1.97E+03 0.41 1.10 3.50
2.09E+03 1.58 1.10 3.50
2.25E+03 0.77 1.10 3.50
2.58E+03 2.16 1.10 3.50
4.88E+03 0.80 1.10 3.50
3.28E+03 1.57 1.10 3.50
2.01E+03 0.96 1.10 3.50 10000 1000
1.86E+03 1.23 1.10 3.50
1.87E+03 0.93 1.10 3.50
1.91E+03 1.53 1.10 3.50
1.98E+03 1.11 1.10 3.50
2.20E+03 0.69 1.10 3.50
2.45E+03 0.82 1.10 3.50
5.50E-01 8.56 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.09E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.10E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-257
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Na JaFS-L01-1314-T01-A 1 1.97E+05
Na JaFS-L01-1314-T02-A 1 6.02E+04
Na JaFS-L01-1314-T03-A 1 3.60E+04
Na JaFS-L01-1314-T04-A 1 1.65E+04
Na JaFS-L01-1314-T05-A 1 3.58E+03
Na JaFS-L01-1314-T06-A 1 1.04E+03
Na JaFS-L01-1314-T07-A 1 6.07E+02
Na JaFS-L01-1314-T08-A 1 4.33E+02
Na JaFS-L01-1314-T09-A 1 3.36E+02
Na JaFS-L01-1314-T01-B 1 2.27E+05
Na JaFS-L01-1314-T02-B 1 6.24E+04
Na JaFS-L01-1314-T03-B 1 3.69E+04
Na JaFS-L01-1314-T04-B 1 1.79E+04
Na JaFS-L01-1314-T05-B 1 4.65E+03
Na JaFS-L01-1314-T06-B 1 1.10E+03
Na JaFS-L01-1314-T07-B 1 6.33E+02
Na JaFS-L01-1314-T08-B 1 4.46E+02
Na JaFS-L01-1314-T09-B 1 3.43E+02
Na JaFS-L01-1314-T01-C 1 2.10E+05
Na JaFS-L01-1314-T02-C 1 7.08E+04
Na JaFS-L01-1314-T03-C 1 3.73E+04
Na JaFS-L01-1314-T04-C 1 1.56E+04
Na JaFS-L01-1314-T05-C 1 4.93E+03
Na JaFS-L01-1314-T06-C 1 1.14E+03
Na JaFS-L01-1314-T07-C 1 6.39E+02
Na JaFS-L01-1314-T08-C 1 4.35E+02
Na JaFS-L01-1314-T09-C 1 3.51 E+02
Na JaFS-L01-1314-B01-A 1 1.25E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.97E+05 0.77 2.50 8.00
6.02E+04 0.33 2.50 8.00
3.60E+04 0.37 2.50 8.00 10000 1000
1.65E+04 0.85 2.50 8.00
3.58E+03 0.60 2.50 8.00
1.04E+03 0.36 2.50 8.00
6.07E+02 1.29 2.50 8.00
4.33E+02 0.45 2.50 8.00
3.36E+02 0.47 2.50 8.00
2.27E+05 0.60 2.50 8.00
6.24E+04 0.04 2.50 8.00
3.69E+04 0.23 2.50 8.00 10000 1000
1.79E+04 0.12 2.50 8.00
4.65E+03 0.49 2.50 8.00
1.10E+03 0.63 2.50 8.00
6.33E+02 1.09 2.50 8.00
4.46E+02 0.70 2.50 8.00
3.43E+02 0.80 2.50 8.00
2.10E+05 0.61 2.50 8.00
7.08E+04 0.49 2.50 8.00
3.73E+04 0.56 2.50 8.00 10000 1000
1.56E+04 0.55 2.50 8.00
4.93E+03 0.39 2.50 8.00
1.14E+03 0.79 2.50 8.00
6.39E+02 0.08 2.50 8.00
4.35E+02 0.82 2.50 8.00
3.51E+02 1.12 2.50 8.00
1.25E+00 0.83 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.69E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.78E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.83E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-258
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Sr JaFS-L01-1314-T01-A 1 9.12E+03
Sr JaFS-L01-1314-T02-A 1 6.69E+02
Sr JaFS-L01-1314-T03-A 1 4.34E+02
Sr JaFS-L01-1314-T04-A 1 4.05E+02
Sr JaFS-L01-1314-T05-A 1 4.47E+02
Sr JaFS-L01-1314-T06-A 1 3.65E+02
Sr JaFS-L01-1314-T07-A 1 2.92E+02
Sr JaFS-L01-1314-T08-A 1 2.46E+02
Sr JaFS-L01-1314-T09-A 1 2.29E+02
Sr JaFS-L01-1314-T01-B 1 1.22E+04
Sr JaFS-L01-1314-T02-B 1 8.06E+02
Sr JaFS-L01-1314-T03-B 1 4.29E+02
Sr JaFS-L01-1314-T04-B 1 3.98E+02
Sr JaFS-L01-1314-T05-B 1 4.45E+02
Sr JaFS-L01-1314-T06-B 1 3.62E+02
Sr JaFS-L01-1314-T07-B 1 3.00E+02
Sr JaFS-L01-1314-T08-B 1 2.48E+02
Sr JaFS-L01-1314-T09-B 1 2.26E+02
Sr JaFS-L01-1314-T01-C 1 1.00E+04
Sr JaFS-L01-1314-T02-C 1 9.67E+02
Sr JaFS-L01-1314-T03-C 1 5.26E+02
Sr JaFS-L01-1314-T04-C 1 4.86E+02
Sr JaFS-L01-1314-T05-C 1 5.10E+02
Sr JaFS-L01-1314-T06-C 1 4.26E+02
Sr JaFS-L01-1314-T07-C 1 3.63E+02
Sr JaFS-L01-1314-T08-C 1 2.91E+02
Sr JaFS-L01-1314-T09-C 1 2.50E+02
Sr JaFS-L01-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.12E+03 1.41 1.00 3.18
6.69E+02 0.84 1.00 3.18
4.34E+02 0.94 1.00 3.18 10000 1000
4.05E+02 0.81 1.00 3.18
4.47E+02 0.69 1.00 3.18
3.65E+02 0.49 1.00 3.18
2.92E+02 0.20 1.00 3.18
2.46E+02 2.14 1.00 3.18
2.29E+02 1.47 1.00 3.18
1.22E+04 0.51 1.00 3.18
8.06E+02 0.94 1.00 3.18
4.29E+02 1.19 1.00 3.18 10000 1000
3.98E+02 1.70 1.00 3.18
4.45E+02 1.30 1.00 3.18
3.62E+02 0.76 1.00 3.18
3.00E+02 1.45 1.00 3.18
2.48E+02 1.85 1.00 3.18
2.26E+02 2.37 1.00 3.18
1.00E+04 0.39 1.00 3.18
9.67E+02 1.86 1.00 3.18
5.26E+02 0.85 1.00 3.18 10000 1000
4.86E+02 0.46 1.00 3.18
5.10E+02 1.48 1.00 3.18
4.26E+02 1.56 1.00 3.18
3.63E+02 0.67 1.00 3.18
2.91E+02 0.96 1.00 3.18
2.50E+02 0.54 1.00 3.18
5.00E-01 36.46 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.46E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.40E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.47E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-259
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
S JaFS-L01-1314-T01-A 1 5.56E+05
S JaFS-L01-1314-T02-A 1 1.94E+04
S JaFS-L01-1314-T03-A 1 6.59E+03
S JaFS-L01-1314-T04-A 1 4.15E+03
S JaFS-L01-1314-T05-A 1 3.49E+03
S JaFS-L01-1314-T06-A 1 2.56E+03
S JaFS-L01-1314-T07-A 1 1.78E+03
S JaFS-L01-1314-T08-A 1 1.13E+03
S JaFS-L01-1314-T09-A 1 9.08E+02
S JaFS-L01-1314-T01-B 1 7.12E+05
S JaFS-L01-1314-T02-B 1 2.62E+04
S JaFS-L01-1314-T03-B 1 6.17E+03
S JaFS-L01-1314-T04-B 1 4.27E+03
S JaFS-L01-1314-T05-B 1 3.54E+03
S JaFS-L01-1314-T06-B 1 2.56E+03
S JaFS-L01-1314-T07-B 1 1.80E+03
S JaFS-L01-1314-T08-B 1 1.13E+03
S JaFS-L01-1314-T09-B 1 8.87E+02
S JaFS-L01-1314-T01-C 1 6.09E+05
S JaFS-L01-1314-T02-C 1 3.41E+04
S JaFS-L01-1314-T03-C 1 6.93E+03
S JaFS-L01-1314-T04-C 1 4.30E+03
S JaFS-L01-1314-T05-C 1 3.39E+03
S JaFS-L01-1314-T06-C 1 2.24E+03
S JaFS-L01-1314-T07-C 1 1.78E+03
S JaFS-L01-1314-T08-C 1 1.27E+03
S JaFS-L01-1314-T09-C 1 9.38E+02
S JaFS-L01-1314-B01-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.56E+05 0.40 6.80 21.60
1.94E+04 0.79 6.80 21.60
6.59E+03 0.94 6.80 21.60 10000 1000
4.15E+03 1.13 6.80 21.60
3.49E+03 1.12 6.80 21.60
2.56E+03 1.65 6.80 21.60
1.78E+03 0.94 6.80 21.60
1.13E+03 2.00 6.80 21.60
9.08E+02 1.76 6.80 21.60
7.12E+05 0.75 6.80 21.60
2.62E+04 0.47 6.80 21.60
6.17E+03 1.19 6.80 21.60 10000 1000
4.27E+03 1.54 6.80 21.60
3.54E+03 1.16 6.80 21.60
2.56E+03 0.91 6.80 21.60
1.80E+03 1.78 6.80 21.60
1.13E+03 1.51 6.80 21.60
8.87E+02 2.79 6.80 21.60
6.09E+05 0.22 6.80 21.60
3.41 E+04 1.39 6.80 21.60
6.93E+03 1.24 6.80 21.60 10000 1000
4.30E+03 1.32 6.80 21.60
3.39E+03 2.02 6.80 21.60
2.24E+03 1.25 6.80 21.60
1.78E+03 1.71 6.80 21.60
1.27E+03 1.54 6.80 21.60
9.38E+02 1.07 6.80 21.60
3.40E+00 3.64 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
7.48E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.12E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.83E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-260
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Tl JaFS-L01-1314-T01-A 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T02-A 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T03-A 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T04-A 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T05-A 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T06-A 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T07-A 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T08-A 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T09-A 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T01-B 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T02-B 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T03-B 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T04-B 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T05-B 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T06-B 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T07-B 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T08-B 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T09-B 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T01-C 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T02-C 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T03-C 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T04-C 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T05-C 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T06-C 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T07-C 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T08-C 1 2.30E+00 U1/2
Tl JaFS-L01-1314-T09-C 1 2.30E+00 U1/2
Tl JaFS-L01-1314-B01-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 32.52 4.60 14.60
2.30E+00 49.32 4.60 14.60
2.30E+00 34.60 4.60 14.60 10000 1000
2.30E+00 4.04 4.60 14.60
2.30E+00 18.85 4.60 14.60
2.30E+00 38.01 4.60 14.60
2.30E+00 46.85 4.60 14.60
2.30E+00 25.91 4.60 14.60
2.30E+00 31.81 4.60 14.60
2.30E+00 38.50 4.60 14.60
2.30E+00 20.48 4.60 14.60
2.30E+00 16.65 4.60 14.60 10000 1000
2.30E+00 41.36 4.60 14.60
2.30E+00 33.06 4.60 14.60
2.30E+00 29.67 4.60 14.60
2.30E+00 16.06 4.60 14.60
2.30E+00 21.98 4.60 14.60
2.30E+00 36.21 4.60 14.60
2.30E+00 26.01 4.60 14.60
2.30E+00 12.09 4.60 14.60
2.30E+00 29.86 4.60 14.60 10000 1000
2.30E+00 26.54 4.60 14.60
2.30E+00 36.52 4.60 14.60
2.30E+00 25.73 4.60 14.60
2.30E+00 15.01 4.60 14.60
2.30E+00 7.52 4.60 14.60
2.30E+00 16.35 4.60 14.60
2.30E+00 34.60 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.01E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.26E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.28E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-261
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Ti JaFS-L01-1314-T01-A 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T02-A 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T03-A 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T04-A 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T05-A 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T06-A 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T07-A 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T08-A 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T09-A 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T01-B 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T02-B 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T03-B 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T04-B 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T05-B 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T06-B 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T07-B 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T08-B 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T09-B 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T01-C 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T02-C 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T03-C 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T04-C 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T05-C 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T06-C 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T07-C 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T08-C 1 1.00E+00 U1/2
Ti JaFS-L01-1314-T09-C 1 1.00E+00 U1/2
Ti JaFS-L01-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 13.72 2.00 6.40
1.00E+00 24.44 2.00 6.40
1.00E+00 21.80 2.00 6.40 10000 1000
1.00E+00 1.85 2.00 6.40
1.00E+00 8.39 2.00 6.40
1.00E+00 6.74 2.00 6.40
1.00E+00 26.78 2.00 6.40
1.00E+00 29.15 2.00 6.40
1.00E+00 1.27 2.00 6.40
1.00E+00 12.42 2.00 6.40
1.00E+00 7.26 2.00 6.40
1.00E+00 20.26 2.00 6.40 10000 1000
1.00E+00 12.17 2.00 6.40
1.00E+00 9.40 2.00 6.40
1.00E+00 15.34 2.00 6.40
1.00E+00 17.35 2.00 6.40
1.00E+00 4.85 2.00 6.40
1.00E+00 10.21 2.00 6.40
1.00E+00 15.41 2.00 6.40
1.00E+00 9.30 2.00 6.40
1.00E+00 19.41 2.00 6.40 10000 1000
1.00E+00 9.71 2.00 6.40
1.00E+00 4.02 2.00 6.40
1.00E+00 1.39 2.00 6.40
1.00E+00 21.21 2.00 6.40
1.00E+00 24.71 2.00 6.40
1.00E+00 13.56 2.00 6.40
1.00E+00 7.49 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.26E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.22E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.67E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-262
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
V JaFS-L01-1314-T01-A 1 2.11E+01
V JaFS-L01-1314-T02-A 1 2.11E+OOE
V JaFS-L01-1314-T03-A 1 7.50E-01 U1/2
V JaFS-L01-1314-T04-A 1 7.50E-01 U1/2
V JaFS-L01-1314-T05-A 1 7.50E-01 U1/2
V JaFS-L01-1314-T06-A 1 7.50E-01 U1/2
V JaFS-L01-1314-T07-A 1 7.50E-01 U1/2
V JaFS-L01-1314-T08-A 1 7.50E-01 U1/2
V JaFS-L01-1314-T09-A 1 7.50E-01 U1/2
V JaFS-L01-1314-T01-B 1 2.36E+01
V JaFS-L01-1314-T02-B 1 2.42E+00 E
V JaFS-L01-1314-T03-B 1 7.50E-01 U1/2
V JaFS-L01-1314-T04-B 1 7.50E-01 U1/2
V JaFS-L01-1314-T05-B 1 7.50E-01 U1/2
V JaFS-L01-1314-T06-B 1 7.50E-01 U1/2
V JaFS-L01-1314-T07-B 1 7.50E-01 U1/2
V JaFS-L01-1314-T08-B 1 7.50E-01 U1/2
V JaFS-L01-1314-T09-B 1 7.50E-01 U1/2
V JaFS-L01-1314-T01-C 1 2.11E+01
V JaFS-L01-1314-T02-C 1 2.34E+00 E
V JaFS-L01-1314-T03-C 1 7.50E-01 U1/2
V JaFS-L01-1314-T04-C 1 7.50E-01 U1/2
V JaFS-L01-1314-T05-C 1 7.50E-01 U1/2
V JaFS-L01-1314-T06-C 1 7.50E-01 U1/2
V JaFS-L01-1314-T07-C 1 7.50E-01 U1/2
V JaFS-L01-1314-T08-C 1 7.50E-01 U1/2
V JaFS-L01-1314-T09-C 1 7.50E-01 U1/2
V JaFS-L01-1314-B01-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.11E+01 2.48 1.50 4.77
2.11E+00 22.62 1.50 4.77
7.50E-01 4.94 1.50 4.77 10000 1000
7.50E-01 22.61 1.50 4.77
7.50E-01 33.36 1.50 4.77
7.50E-01 37.91 1.50 4.77
7.50E-01 26.74 1.50 4.77
7.50E-01 20.12 1.50 4.77
7.50E-01 30.65 1.50 4.77
2.36E+01 1.63 1.50 4.77
2.42E+00 19.48 1.50 4.77
7.50E-01 11.64 1.50 4.77 10000 1000
7.50E-01 25.22 1.50 4.77
7.50E-01 18.80 1.50 4.77
7.50E-01 19.98 1.50 4.77
7.50E-01 30.24 1.50 4.77
7.50E-01 39.80 1.50 4.77
7.50E-01 12.14 1.50 4.77
2.11E+01 4.49 1.50 4.77
2.34E+00 22.62 1.50 4.77
7.50E-01 17.38 1.50 4.77 10000 1000
7.50E-01 4.97 1.50 4.77
7.50E-01 20.50 1.50 4.77
7.50E-01 19.94 1.50 4.77
7.50E-01 19.97 1.50 4.77
7.50E-01 30.95 1.50 4.77
7.50E-01 23.91 1.50 4.77
7.50E-01 14.27 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.06E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.51E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.77E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/6/11 4:18 PM EPA Interlab L01 1314 JaFS
10/6/11 4:23 PM EPA Interlab L01 1314 JaFS
10/6/11 4:28 PM EPA Interlab L01 1314 JaFS
10/6/11 4:38 PM EPA Interlab L01 1314 JaFS
10/6/11 4:43 PM EPA Interlab L01 1314 JaFS
10/6/11 2:40 PM EPA Interlab L01 1314 JaFS
10/6/11 2:45 PM EPA Interlab L01 1314 JaFS
10/6/11 2:50 PM EPA Interlab L01 1314 JaFS
10/6/11 2:55 PM EPA Interlab L01 1314 JaFS
10/6/11 4:20 PM EPA Interlab L01 1314 JaFS
10/6/11 4:25 PM EPA Interlab L01 1314 JaFS
10/6/11 4:30 PM EPA Interlab L01 1314 JaFS
10/6/11 4:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:37 PM EPA Interlab L01 1314 JaFS
10/6/11 2:42 PM EPA Interlab L01 1314 JaFS
10/6/11 2:47 PM EPA Interlab L01 1314 JaFS
10/6/11 2:52 PM EPA Interlab L01 1314 JaFS
10/6/11 2:57 PM EPA Interlab L01 1314 JaFS
10/6/11 4:21 PM EPA Interlab L01 1314 JaFS
10/6/11 4:26 PM EPA Interlab L01 1314 JaFS
10/6/11 4:31 PM EPA Interlab L01 1314 JaFS
10/6/11 4:41 PM EPA Interlab L01 1314 JaFS
10/6/11 2:39 PM EPA Interlab L01 1314 JaFS
10/6/11 2:44 PM EPA Interlab L01 1314 JaFS
10/6/11 2:49 PM EPA Interlab L01 1314 JaFS
10/6/11 2:54 PM EPA Interlab L01 1314 JaFS
10/6/11 2:58 PM EPA Interlab L01 1314 JaFS
10/6/11 4:13 PM EPA Interlab L01 1314 JaFS
1-263
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Zn JaFS-L01-1314-T01-A 1 1.31E+03
Zn JaFS-L01-1314-T02-A 1 5.45E+02
Zn JaFS-L01-1314-T03-A 1 2.06E+02
Zn JaFS-L01-1314-T04-A 1 1.01E+02
Zn JaFS-L01-1314-T05-A 1 9.04E+01
Zn JaFS-L01-1314-T06-A 1 7.31E+01
Zn JaFS-L01-1314-T07-A 1 6.25E+01
Zn JaFS-L01-1314-T08-A 1 2.94E+01
Zn JaFS-L01-1314-T09-A 1 2.35E+01
Zn JaFS-L01-1314-T01-B 1 1.28E+03
Zn JaFS-L01-1314-T02-B 1 5.40E+02
Zn JaFS-L01-1314-T03-B 1 2.20E+02
Zn JaFS-L01-1314-T04-B 1 1.13E+02
Zn JaFS-L01-1314-T05-B 1 9.49E+01
Zn JaFS-L01-1314-T06-B 1 7.75E+01
Zn JaFS-L01-1314-T07-B 1 5.75E+01
Zn JaFS-L01-1314-T08-B 1 2.85E+01
Zn JaFS-L01-1314-T09-B 1 2.10E+01
Zn JaFS-L01-1314-T01-C 1 1.27E+03
Zn JaFS-L01-1314-T02-C 1 5.30E+02
Zn JaFS-L01-1314-T03-C 1 2.39E+02
Zn JaFS-L01-1314-T04-C 1 1.22E+02
Zn JaFS-L01-1314-T05-C 1 9.37E+01
Zn JaFS-L01-1314-T06-C 1 7.59E+01
Zn JaFS-L01-1314-T07-C 1 6.31E+01
Zn JaFS-L01-1314-T08-C 1 3.02E+01
Zn JaFS-L01-1314-T09-C 1 2.37E+01
Zn JaFS-L01-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.31E+03 1.47 1.00 3.18
5.45E+02 0.70 1.00 3.18
2.06E+02 0.90 1.00 3.18 10000 1000
1.01E+02 0.47 1.00 3.18
9.04E+01 1.35 1.00 3.18
7.31E+01 0.98 1.00 3.18
6.25E+01 0.41 1.00 3.18
2.94E+01 1.72 1.00 3.18
2.35E+01 1.95 1.00 3.18
1.28E+03 0.76 1.00 3.18
5.40E+02 0.55 1.00 3.18
2.20E+02 1.19 1.00 3.18 10000 1000
1.13E+02 1.53 1.00 3.18
9.49E+01 0.53 1.00 3.18
7.75E+01 1.22 1.00 3.18
5.75E+01 1.21 1.00 3.18
2.85E+01 1.64 1.00 3.18
2.10E+01 1.67 1.00 3.18
1.27E+03 0.38 1.00 3.18
5.30E+02 2.01 1.00 3.18
2.39E+02 0.32 1.00 3.18 10000 1000
1.22E+02 0.90 1.00 3.18
9.37E+01 0.91 1.00 3.18
7.59E+01 1.33 1.00 3.18
6.31E+01 0.58 1.00 3.18
3.02E+01 0.97 1.00 3.18
2.37E+01 0.26 1.00 3.18
5.00E-01 11.77 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.14E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/12 11:27 AM EPA Interlab L01 1314 JaFS
3/7/12 11:28 AM EPA Interlab L01 1314 JaFS
3/7/12 11:30 AM EPA Interlab L01 1314 JaFS
3/7/12 11:32 AM EPA Interlab L01 1314 JaFS
3/7/12 11:33 AM EPA Interlab L01 1314 JaFS
3/7/12 11:35 AM EPA Interlab L01 1314 JaFS
3/7/12 11:37 AM EPA Interlab L01 1314 JaFS
3/7/12 11:38 AM EPA Interlab L01 1314 JaFS
3/7/12 11:40 AM EPA Interlab L01 1314 JaFS
3/7/12 11:42 AM EPA Interlab L01 1314 JaFS
3/7/12 11:43 AM EPA Interlab L01 1314 JaFS
3/7/12 11:45 AM EPA Interlab L01 1314 JaFS
3/7/12 11:46 AM EPA Interlab L01 1314 JaFS
3/7/12 11:48 AM EPA Interlab L01 1314 JaFS
3/7/12 11:50 AM EPA Interlab L01 1314 JaFS
3/7/12 11:51 AM EPA Interlab L01 1314 JaFS
3/7/12 11:53 AM EPA Interlab L01 1314 JaFS
3/7/12 11:55 AM EPA Interlab L01 1314 JaFS
3/7/12 12:00 PM EPA Interlab L01 1314 JaFS
3/7/12 12:01 PM EPA Interlab L01 1314 JaFS
3/7/12 12:03 PM EPA Interlab L01 1314 JaFS
3/7/12 12:05 PM EPA Interlab L01 1314 JaFS
3/7/12 12:06 PM EPA Interlab L01 1314 JaFS
3/7/12 12:08 PM EPA Interlab L01 1314 JaFS
3/7/12 12:09 PM EPA Interlab L01 1314 JaFS
3/7/12 12:11 PM EPA Interlab L01 1314 JaFS
3/7/12 12:13 PM EPA Interlab L01 1314 JaFS
3/7/12 11:25 AM EPA Interlab L01 1314 JaFS
1-264
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1314:
Dilution Sample
Element Sample ID Factor Cone. Qualifier
I I M9/L I
Al JaFS-L06-1314-T01-A 1 7.68E+01
Al JaFS-L06-1314-T02-A 1 5.10E+01
Al JaFS-L06-1314-T03-A 1 2.11E+01
Al JaFS-L06-1314-T04-A 1 1.74E+01
Al JaFS-L06-1314-T05-A 1 1.74E+01
Al JaFS-L06-1314-T06-A 1 1.80E+01
Al JaFS-L06-1314-T07-A 1 2.06E+01
Al JaFS-L06-1314-T08-A 1 1.22E+01
Al JaFS-L06-1314-T09-A 1 1.80E+01
Al JaFS-L06-1314-T01-B 1 7.45E+01
Al JaFS-L06-1314-T02-B 1 5.51E+01
Al JaFS-L06-1314-T03-B 1 2.44E+01
Al JaFS-L06-1314-T04-B 1 1.75E+01
Al JaFS-L06-1314-T05-B 1 1.92E+01
Al JaFS-L06-1314-T06-B 1 2.21E+01
Al JaFS-L06-1314-T07-B 1 1.77E+01
Al JaFS-L06-1314-T08-B 1 1.73E+01
Al JaFS-L06-1314-T09-B 1 1.62E+01
Al JaFS-L06-1314-T01-C 1 8.16E+01
Al JaFS-L06-1314-T02-C 1 3.76E+01
Al JaFS-L06-1314-T03-C 1 2.22E+01
Al JaFS-L06-1314-T04-C 1 2.45E+01
Al JaFS-L06-1314-T05-C 1 1.88E+01
Al JaFS-L06-1314-T06-C 1 2.17E+01
Al JaFS-L06-1314-T07-C 1 2.31E+01
Al JaFS-L06-1314-T08-C 1 1.60E+01
Al JaFS-L06-1314-T09-C 1 1.31E+01
Al JaFS-L06-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.68E+01 1.73 1.00 3.18
5.10E+01 2.76 1.00 3.18
2.11E+01 8.19 1.00 3.18 10000 1000
1.74E+01 3.48 1.00 3.18
1.74E+01 1.41 1.00 3.18
1.80E+01 3.73 1.00 3.18
2.06E+01 10.75 1.00 3.18
1.22E+01 0.42 1.00 3.18
1.80E+01 6.14 1.00 3.18
7.45E+01 3.10 1.00 3.18
5.51E+01 6.24 1.00 3.18
2.44E+01 4.34 1.00 3.18 10000 1000
1.75E+01 7.72 1.00 3.18
1.92E+01 4.18 1.00 3.18
2.21E+01 3.59 1.00 3.18
1.77E+01 9.86 1.00 3.18
1.73E+01 1.30 1.00 3.18
1.62E+01 1.58 1.00 3.18
8.16E+01 3.65 1.00 3.18
3.76E+01 8.11 1.00 3.18
2.22E+01 4.17 1.00 3.18 10000 1000
2.45E+01 8.61 1.00 3.18
1.88E+01 7.06 1.00 3.18
2.17E+01 2.79 1.00 3.18
2.31E+01 2.97 1.00 3.18
1.60E+01 7.18 1.00 3.18
1.31E+01 3.67 1.00 3.18
5.00E-01 42.98 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/12 10:18 AM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
3/7/12 10:33 AM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 12:33 PM EPA Interlab L06 1314 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
3/7/12 10:51 AM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
12/14/11 12:48 PM EPA Interlab L06 1314 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-265
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Sb JaFS-L06-1314-T01-A 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T02-A 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T03-A 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T04-A 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T05-A 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T06-A 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T07-A 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T08-A 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T09-A 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T01-B 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T02-B 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T03-B 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T04-B 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T05-B 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T06-B 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T07-B 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T08-B 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T09-B 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T01-C 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T02-C 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T03-C 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T04-C 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T05-C 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T06-C 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T07-C 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T08-C 1 3.75E+00 U1/2
Sb JaFS-L06-1314-T09-C 1 3.75E+00 U1/2
Sb JaFS-L06-1314-B01-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.75E+00 6.63 7.50 23.90
3.75E+00 9.44 7.50 23.90
3.75E+00 16.83 7.50 23.90 10000 1000
3.75E+00 28.29 7.50 23.90
3.75E+00 56.31 7.50 23.90
3.75E+00 30.46 7.50 23.90
3.75E+00 33.02 7.50 23.90
3.75E+00 11.65 7.50 23.90
3.75E+00 39.20 7.50 23.90
3.75E+00 25.79 7.50 23.90
3.75E+00 49.44 7.50 23.90
3.75E+00 11.72 7.50 23.90 10000 1000
3.75E+00 48.43 7.50 23.90
3.75E+00 29.00 7.50 23.90
3.75E+00 57.87 7.50 23.90
3.75E+00 40.65 7.50 23.90
3.75E+00 42.57 7.50 23.90
3.75E+00 26.80 7.50 23.90
3.75E+00 27.20 7.50 23.90
3.75E+00 49.36 7.50 23.90
3.75E+00 23.76 7.50 23.90 10000 1000
3.75E+00 10.80 7.50 23.90
3.75E+00 10.52 7.50 23.90
3.75E+00 39.20 7.50 23.90
3.75E+00 55.39 7.50 23.90
3.75E+00 11.81 7.50 23.90
3.75E+00 21.15 7.50 23.90
3.75E+00 24.35 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.48E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.64E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.19E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 12:33 PM EPA Interlab L06 1314 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
12/14/11 12:48 PM EPA Interlab L06 1314 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-266
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
As JaFS-L06-1314-T01-A 1 5.50E+00 U1/2
As JaFS-L06-1314-T02-A 1 5.50E+00 U1/2
As JaFS-L06-1314-T03-A 1 5.50E+00 U1/2
As JaFS-L06-1314-T04-A 1 5.50E+00 U1/2
As JaFS-L06-1314-T05-A 1 5.50E+00 U1/2
As JaFS-L06-1314-T06-A 1 5.50E+00 U1/2
As JaFS-L06-1314-T07-A 1 5.50E+00 U1/2
As JaFS-L06-1314-T08-A 1 5.50E+00 U1/2
As JaFS-L06-1314-T09-A 1 5.50E+00 U1/2
As JaFS-L06-1314-T01-B 1 5.50E+00 U1/2
As JaFS-L06-1314-T02-B 1 5.50E+00 U1/2
As JaFS-L06-1314-T03-B 1 5.50E+00 U1/2
As JaFS-L06-1314-T04-B 1 5.50E+00 U1/2
As JaFS-L06-1314-T05-B 1 5.50E+00 U1/2
As JaFS-L06-1314-T06-B 1 5.50E+00 U1/2
As JaFS-L06-1314-T07-B 1 5.50E+00 U1/2
As JaFS-L06-1314-T08-B 1 5.50E+00 U1/2
As JaFS-L06-1314-T09-B 1 5.50E+00 U1/2
As JaFS-L06-1314-T01-C 1 5.50E+00 U1/2
As JaFS-L06-1314-T02-C 1 5.50E+00 U1/2
As JaFS-L06-1314-T03-C 1 5.50E+00 U1/2
As JaFS-L06-1314-T04-C 1 5.50E+00 U1/2
As JaFS-L06-1314-T05-C 1 5.50E+00 U1/2
As JaFS-L06-1314-T06-C 1 5.50E+00 U1/2
As JaFS-L06-1314-T07-C 1 5.50E+00 U1/2
As JaFS-L06-1314-T08-C 1 5.50E+00 U1/2
As JaFS-L06-1314-T09-C 1 5.50E+00 U1/2
As JaFS-L06-1314-B01-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.50E+00 36.17 11.00 35.00
5.50E+00 38.57 11.00 35.00
5.50E+00 41.80 11.00 35.00 10000 1000
5.50E+00 59.10 11.00 35.00
5.50E+00 34.79 11.00 35.00
5.50E+00 24.78 11.00 35.00
5.50E+00 28.02 11.00 35.00
5.50E+00 15.35 11.00 35.00
5.50E+00 41.62 11.00 35.00
5.50E+00 42.85 11.00 35.00
5.50E+00 50.11 11.00 35.00
5.50E+00 30.71 11.00 35.00 10000 1000
5.50E+00 63.05 11.00 35.00
5.50E+00 47.71 11.00 35.00
5.50E+00 44.94 11.00 35.00
5.50E+00 7.63 11.00 35.00
5.50E+00 35.92 11.00 35.00
5.50E+00 20.88 11.00 35.00
5.50E+00 47.43 11.00 35.00
5.50E+00 59.09 11.00 35.00
5.50E+00 15.73 11.00 35.00 10000 1000
5.50E+00 35.30 11.00 35.00
5.50E+00 40.47 11.00 35.00
5.50E+00 28.46 11.00 35.00
5.50E+00 13.16 11.00 35.00
5.50E+00 8.08 11.00 35.00
5.50E+00 15.49 11.00 35.00
5.50E+00 50.24 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.61 E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.78E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.47E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 12:33PM EPA Interlab L06 1314 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
12/14/11 12:48 PM EPA Interlab L06 1314 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-267
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
B JaFS-L06-1314-T01-A 1 1.57E+05
B JaFS-L06-1314-T02-A 1 7.74E+04
B JaFS-L06-1314-T03-A 1 2.37E+04
B JaFS-L06-1314-T04-A 1 8.16E+03
B JaFS-L06-1314-T05-A 1 5.53E+03
B JaFS-L06-1314-T06-A 1 2.48E+03
B JaFS-L06-1314-T07-A 1 1.20E+03
B JaFS-L06-1314-T08-A 1 7.93E+02
B JaFS-L06-1314-T09-A 1 5.13E+02
B JaFS-L06-1314-T01-B 1 1.71E+05
B JaFS-L06-1314-T02-B 1 8.41E+04
B JaFS-L06-1314-T03-B 1 2.46E+04
B JaFS-L06-1314-T04-B 1 1.04E+04
B JaFS-L06-1314-T05-B 1 5.86E+03
B JaFS-L06-1314-T06-B 1 2.66E+03
B JaFS-L06-1314-T07-B 1 1.26E+03
B JaFS-L06-1314-T08-B 1 7.85E+02
B JaFS-L06-1314-T09-B 1 5.34E+02
B JaFS-L06-1314-T01-C 1 1.94E+05
B JaFS-L06-1314-T02-C 1 7.22E+04
B JaFS-L06-1314-T03-C 1 2.10E+04
B JaFS-L06-1314-T04-C 1 9.50E+03
B JaFS-L06-1314-T05-C 1 5.58E+03
B JaFS-L06-1314-T06-C 1 2.60E+03
B JaFS-L06-1314-T07-C 1 1.26E+03
B JaFS-L06-1314-T08-C 1 8.03E+02
B JaFS-L06-1314-T09-C 1 5.30E+02
B JaFS-L06-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.57E+05 1.24 1.00 3.18
7.74E+04 0.78 1.00 3.18
2.37E+04 0.82 1.00 3.18 10000 1000
8.16E+03 2.70 1.00 3.18
5.53E+03 1.77 1.00 3.18
2.48E+03 1.54 1.00 3.18
1.20E+03 2.40 1.00 3.18
7.93E+02 1.54 1.00 3.18
5.13E+02 1.88 1.00 3.18
1.71E+05 0.92 1.00 3.18
8.41E+04 0.84 1.00 3.18
2.46E+04 1.41 1.00 3.18 10000 1000
1.04E+04 1.13 1.00 3.18
5.86E+03 1.02 1.00 3.18
2.66E+03 2.82 1.00 3.18
1.26E+03 1.84 1.00 3.18
7.85E+02 1.78 1.00 3.18
5.34E+02 1.55 1.00 3.18
1.94E+05 2.98 1.00 3.18
7.22E+04 1.50 1.00 3.18
2.10E+04 1.79 1.00 3.18 10000 1000
9.50E+03 1.11 1.00 3.18
5.58E+03 1.13 1.00 3.18
2.60E+03 0.90 1.00 3.18
1.26E+03 1.21 1.00 3.18
8.03E+02 2.97 1.00 3.18
5.30E+02 0.48 1.00 3.18
5.00E-01 4.28 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.46E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.55E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.19E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 1 2:33 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
1 2/1 4/1 1 1 2:48 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-268
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Ba JaFS-L06-1314-T01-A 1 1.16E+02
Ba JaFS-L06-1314-T02-A 1 9.71E+01
Ba JaFS-L06-1314-T03-A 1 5.16E+01
Ba JaFS-L06-1314-T04-A 1 3.92E+01
Ba JaFS-L06-1314-T05-A 1 3.10E+01
Ba JaFS-L06-1314-T06-A 1 2.69E+01
Ba JaFS-L06-1314-T07-A 1 2.01E+01
Ba JaFS-L06-1314-T08-A 1 1.38E+01
Ba JaFS-L06-1314-T09-A 1 1.08E+01
Ba JaFS-L06-1314-T01-B 1 1.26E+02
Ba JaFS-L06-1314-T02-B 1 9.55E+01
Ba JaFS-L06-1314-T03-B 1 4.86E+01
Ba JaFS-L06-1314-T04-B 1 3.32E+01
Ba JaFS-L06-1314-T05-B 1 3.59E+01
Ba JaFS-L06-1314-T06-B 1 3.03E+01
Ba JaFS-L06-1314-T07-B 1 2.01E+01
Ba JaFS-L06-1314-T08-B 1 1.50E+01
Ba JaFS-L06-1314-T09-B 1 1.04E+01
Ba JaFS-L06-1314-T01-C 1 1.15E+02
Ba JaFS-L06-1314-T02-C 1 9.25E+01
Ba JaFS-L06-1314-T03-C 1 5.49E+01
Ba JaFS-L06-1314-T04-C 1 3.51E+01
Ba JaFS-L06-1314-T05-C 1 3.25E+01
Ba JaFS-L06-1314-T06-C 1 3.00E+01
Ba JaFS-L06-1314-T07-C 1 2.00E+01
Ba JaFS-L06-1314-T08-C 1 1.37E+01
Ba JaFS-L06-1314-T09-C 1 9.54E+00
Ba JaFS-L06-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.16E+02 0.24 1.00 3.18
9.71E+01 0.30 1.00 3.18
5.16E+01 0.79 1.00 3.18 10000 1000
3.92E+01 1.66 1.00 3.18
3.10E+01 1.40 1.00 3.18
2.69E+01 2.19 1.00 3.18
2.01E+01 6.17 1.00 3.18
1.38E+01 1.45 1.00 3.18
1.08E+01 1.99 1.00 3.18
1.26E+02 0.94 1.00 3.18
9.55E+01 0.50 1.00 3.18
4.86E+01 1.95 1.00 3.18 10000 1000
3.32E+01 1.44 1.00 3.18
3.59E+01 1.15 1.00 3.18
3.03E+01 1.39 1.00 3.18
2.01E+01 3.01 1.00 3.18
1.50E+01 2.45 1.00 3.18
1.04E+01 0.16 1.00 3.18
1.15E+02 3.38 1.00 3.18
9.25E+01 1.24 1.00 3.18
5.49E+01 1.49 1.00 3.18 10000 1000
3.51E+01 1.39 1.00 3.18
3.25E+01 1.73 1.00 3.18
3.00E+01 0.55 1.00 3.18
2.00E+01 1.30 1.00 3.18
1.37E+01 1.05 1.00 3.18
9.54E+00 1.65 1.00 3.18
5.00E-01 20.03 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.94E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.97E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.93E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 1 2:33 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
1 2/1 4/1 1 1 2:48 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-269
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Be JaFS-L06-1314-T01-A 1 9.50E-01 U1/2
Be JaFS-L06-1314-T02-A 1 9.50E-01 U1/2
Be JaFS-L06-1314-T03-A 1 9.50E-01 U1/2
Be JaFS-L06-1314-T04-A 1 9.50E-01 U1/2
Be JaFS-L06-1314-T05-A 1 9.50E-01 U1/2
Be JaFS-L06-1314-T06-A 1 9.50E-01 U1/2
Be JaFS-L06-1314-T07-A 1 9.50E-01 U1/2
Be JaFS-L06-1314-T08-A 1 9.50E-01 U1/2
Be JaFS-L06-1314-T09-A 1 9.50E-01 U1/2
Be JaFS-L06-1314-T01-B 1 9.50E-01 U1/2
Be JaFS-L06-1314-T02-B 1 9.50E-01 U1/2
Be JaFS-L06-1314-T03-B 1 9.50E-01 U1/2
Be JaFS-L06-1314-T04-B 1 9.50E-01 U1/2
Be JaFS-L06-1314-T05-B 1 9.50E-01 U1/2
Be JaFS-L06-1314-T06-B 1 9.50E-01 U1/2
Be JaFS-L06-1314-T07-B 1 9.50E-01 U1/2
Be JaFS-L06-1314-T08-B 1 9.50E-01 U1/2
Be JaFS-L06-1314-T09-B 1 9.50E-01 U1/2
Be JaFS-L06-1314-T01-C 1 9.50E-01 U1/2
Be JaFS-L06-1314-T02-C 1 9.50E-01 U1/2
Be JaFS-L06-1314-T03-C 1 9.50E-01 U1/2
Be JaFS-L06-1314-T04-C 1 9.50E-01 U1/2
Be JaFS-L06-1314-T05-C 1 9.50E-01 U1/2
Be JaFS-L06-1314-T06-C 1 9.50E-01 U1/2
Be JaFS-L06-1314-T07-C 1 9.50E-01 U1/2
Be JaFS-L06-1314-T08-C 1 9.50E-01 U1/2
Be JaFS-L06-1314-T09-C 1 9.50E-01 U1/2
Be JaFS-L06-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 44.32 1.90 6.00
9.50E-01 55.13 1.90 6.00
9.50E-01 28.67 1.90 6.00 10000 1000
9.50E-01 23.65 1.90 6.00
9.50E-01 50.66 1.90 6.00
9.50E-01 11.60 1.90 6.00
9.50E-01 58.61 1.90 6.00
9.50E-01 74.34 1.90 6.00
9.50E-01 35.57 1.90 6.00
9.50E-01 11.08 1.90 6.00
9.50E-01 59.83 1.90 6.00
9.50E-01 8.77 1.90 6.00 10000 1000
9.50E-01 22.96 1.90 6.00
9.50E-01 74.17 1.90 6.00
9.50E-01 41.41 1.90 6.00
9.50E-01 74.37 1.90 6.00
9.50E-01 10.93 1.90 6.00
9.50E-01 58.98 1.90 6.00
9.50E-01 6.39 1.90 6.00
9.50E-01 35.16 1.90 6.00
9.50E-01 66.75 1.90 6.00 10000 1000
9.50E-01 25.77 1.90 6.00
9.50E-01 6.32 1.90 6.00
9.50E-01 27.99 1.90 6.00
9.50E-01 37.45 1.90 6.00
9.50E-01 67.54 1.90 6.00
9.50E-01 27.09 1.90 6.00
9.50E-01 51.16 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.67E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.79E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.42E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 12:33 PM EPA Interlab L06 1314 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
12/14/11 12:48 PM EPA Interlab L06 1314 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-270
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cd JaFS-L06-1314-T01-A 1 1.52E+01
Cd JaFS-L06-1314-T02-A 1 4.16E+00 E
Cd JaFS-L06-1314-T03-A 1 1.10E+00 U1/2
Cd JaFS-L06-1314-T04-A 1 1.10E+00 U1/2
Cd JaFS-L06-1314-T05-A 1 1.10E+00 U1/2
Cd JaFS-L06-1314-T06-A 1 1.10E+00 U1/2
Cd JaFS-L06-1314-T07-A 1 1.10E+00 U1/2
Cd JaFS-L06-1314-T08-A 1 1.10E+00 U1/2
Cd JaFS-L06-1314-T09-A 1 1.10E+00 U1/2
Cd JaFS-L06-1314-T01-B 1 1.80E+01
Cd JaFS-L06-1314-T02-B 1 4.42E+00 E
Cd JaFS-L06-1314-T03-B 1 1.10E+00 U1/2
Cd JaFS-L06-1314-T04-B 1 1.10E+00 U1/2
Cd JaFS-L06-1314-T05-B 1 1.10E+00 U1/2
Cd JaFS-L06-1314-T06-B 1 1.10E+00 U1/2
Cd JaFS-L06-1314-T07-B 1 1.10E+00 U1/2
Cd JaFS-L06-1314-T08-B 1 1.10E+00 U1/2
Cd JaFS-L06-1314-T09-B 1 1.10E+00 U1/2
Cd JaFS-L06-1314-T01-C 1 2.18E+01
Cd JaFS-L06-1314-T02-C 1 3.01E+00 E
Cd JaFS-L06-1314-T03-C 1 1.10E+00 U1/2
Cd JaFS-L06-1314-T04-C 1 1.10E+00 U1/2
Cd JaFS-L06-1314-T05-C 1 1.10E+00 U1/2
Cd JaFS-L06-1314-T06-C 1 1.10E+00 U1/2
Cd JaFS-L06-1314-T07-C 1 1.10E+00 U1/2
Cd JaFS-L06-1314-T08-C 1 1.10E+00 U1/2
Cd JaFS-L06-1314-T09-C 1 1.10E+00 U1/2
Cd JaFS-L06-1314-B01-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.52E+01 3.25 2.20 7.00
4.16E+00 7.79 2.20 7.00
1.10E+00 28.15 2.20 7.00 10000 1000
1.10E+00 21.65 2.20 7.00
1.10E+00 6.13 2.20 7.00
1.10E+00 36.41 2.20 7.00
1.10E+00 53.01 2.20 7.00
1.10E+00 32.75 2.20 7.00
1.10E+00 23.28 2.20 7.00
1.80E+01 1.92 2.20 7.00
4.42E+00 4.84 2.20 7.00
1.10E+00 11.12 2.20 7.00 10000 1000
1.10E+00 37.42 2.20 7.00
1.10E+00 10.35 2.20 7.00
1.10E+00 21.60 2.20 7.00
1.10E+00 29.01 2.20 7.00
1.10E+00 51.93 2.20 7.00
1.10E+00 47.09 2.20 7.00
2.18E+01 5.63 2.20 7.00
3.01 E+00 3.64 2.20 7.00
1.10E+00 8.74 2.20 7.00 10000 1000
1.10E+00 9.40 2.20 7.00
1.10E+00 4.24 2.20 7.00
1.10E+00 17.69 2.20 7.00
1.10E+00 18.90 2.20 7.00
1.10E+00 14.60 2.20 7.00
1.10E+00 22.69 2.20 7.00
1.10E+00 59.95 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.60E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.69E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.34E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 1 2:33 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
12/14/11 12:48 PM EPA Interlab L06 1314 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-271
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Ca JaFS-L06-1314-T01-A 1 3.31E+05
Ca JaFS-L06-1314-T02-A 1 5.37E+04
Ca JaFS-L06-1314-T03-A 1 1.63E+04
Ca JaFS-L06-1314-T04-A 1 1.44E+04
Ca JaFS-L06-1314-T05-A 1 1.85E+04
Ca JaFS-L06-1314-T06-A 1 1.57E+04
Ca JaFS-L06-1314-T07-A 1 1.32E+04
Ca JaFS-L06-1314-T08-A 1 1.07E+04
Ca JaFS-L06-1314-T09-A 1 1.07E+04
Ca JaFS-L06-1314-T01-B 1 3.75E+05
Ca JaFS-L06-1314-T02-B 1 5.11E+04
Ca JaFS-L06-1314-T03-B 1 1.62E+04
Ca JaFS-L06-1314-T04-B 1 1.77E+04
Ca JaFS-L06-1314-T05-B 1 1.88E+04
Ca JaFS-L06-1314-T06-B 1 1.63E+04
Ca JaFS-L06-1314-T07-B 1 1.32E+04
Ca JaFS-L06-1314-T08-B 1 1.08E+04
Ca JaFS-L06-1314-T09-B 1 1.02E+04
Ca JaFS-L06-1314-T01-C 1 4.28E+05
Ca JaFS-L06-1314-T02-C 1 5.11E+04
Ca JaFS-L06-1314-T03-C 1 1.56E+04
Ca JaFS-L06-1314-T04-C 1 1.72E+04
Ca JaFS-L06-1314-T05-C 1 1.87E+04
Ca JaFS-L06-1314-T06-C 1 1.61E+04
Ca JaFS-L06-1314-T07-C 1 1.30E+04
Ca JaFS-L06-1314-T08-C 1 1.03E+04
Ca JaFS-L06-1314-T09-C 1 9.14E+03
Ca JaFS-L06-1314-B01-A 1 1.30E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.31 E+05 0.37 2.60 8.30
5.37E+04 0.21 2.60 8.30
1.63E+04 0.19 2.60 8.30 10000 1000
1.44E+04 0.30 2.60 8.30
1.85E+04 1.38 2.60 8.30
1.57E+04 1.33 2.60 8.30
1.32E+04 2.88 2.60 8.30
1.07E+04 0.58 2.60 8.30
1.07E+04 1.22 2.60 8.30
3.75E+05 0.64 2.60 8.30
5.11E+04 0.50 2.60 8.30
1.62E+04 1.44 2.60 8.30 10000 1000
1.77E+04 2.01 2.60 8.30
1.88E+04 1.55 2.60 8.30
1.63E+04 1.79 2.60 8.30
1.32E+04 1.70 2.60 8.30
1.08E+04 1.65 2.60 8.30
1.02E+04 0.64 2.60 8.30
4.28E+05 2.81 2.60 8.30
5.11E+04 1.44 2.60 8.30
1.56E+04 0.68 2.60 8.30 10000 1000
1.72E+04 1.30 2.60 8.30
1.87E+04 0.40 2.60 8.30
1.61E+04 0.59 2.60 8.30
1.30E+04 0.42 2.60 8.30
1.03E+04 1.96 2.60 8.30
9.14E+03 0.37 2.60 8.30
1.30E+00 5.14 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.72E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.70E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.65E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 1 2:33 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
12/14/11 12:48 PM EPA Interlab L06 1314 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-272
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cr JaFS-L06-1314-T01-A 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T02-A 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T03-A 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T04-A 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T05-A 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T06-A 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T07-A 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T08-A 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T09-A 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T01-B 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T02-B 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T03-B 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T04-B 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T05-B 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T06-B 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T07-B 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T08-B 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T09-B 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T01-C 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T02-C 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T03-C 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T04-C 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T05-C 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T06-C 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T07-C 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T08-C 1 6.00E-01 U1/2
Cr JaFS-L06-1314-T09-C 1 6.00E-01 U1/2
Cr JaFS-L06-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 26.64 1.20 3.82
6.00E-01 37.11 1.20 3.82
6.00E-01 36.79 1.20 3.82 10000 1000
6.00E-01 36.67 1.20 3.82
6.00E-01 3.40 1.20 3.82
6.00E-01 17.22 1.20 3.82
6.00E-01 9.85 1.20 3.82
6.00E-01 19.36 1.20 3.82
6.00E-01 22.63 1.20 3.82
6.00E-01 17.16 1.20 3.82
6.00E-01 18.32 1.20 3.82
6.00E-01 22.47 1.20 3.82 10000 1000
6.00E-01 74.39 1.20 3.82
6.00E-01 37.49 1.20 3.82
6.00E-01 27.62 1.20 3.82
6.00E-01 44.17 1.20 3.82
6.00E-01 27.82 1.20 3.82
6.00E-01 14.45 1.20 3.82
6.00E-01 8.26 1.20 3.82
6.00E-01 42.71 1.20 3.82
6.00E-01 66.22 1.20 3.82 10000 1000
6.00E-01 46.58 1.20 3.82
6.00E-01 12.51 1.20 3.82
6.00E-01 36.08 1.20 3.82
6.00E-01 6.05 1.20 3.82
6.00E-01 63.17 1.20 3.82
6.00E-01 29.87 1.20 3.82
6.00E-01 44.41 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.57E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.72E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.38E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 12:33 PM EPA Interlab L06 1314 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
12/14/11 12:48 PM EPA Interlab L06 1314 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-273
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Co JaFS-L06-1314-T01-A 1 9.00E-01 U1/2
Co JaFS-L06-1314-T02-A 1 9.00E-01 U1/2
Co JaFS-L06-1314-T03-A 1 9.00E-01 U1/2
Co JaFS-L06-1314-T04-A 1 9.00E-01 U1/2
Co JaFS-L06-1314-T05-A 1 9.00E-01 U1/2
Co JaFS-L06-1314-T06-A 1 9.00E-01 U1/2
Co JaFS-L06-1314-T07-A 1 9.00E-01 U1/2
Co JaFS-L06-1314-T08-A 1 9.00E-01 U1/2
Co JaFS-L06-1314-T09-A 1 9.00E-01 U1/2
Co JaFS-L06-1314-T01-B 1 9.00E-01 U1/2
Co JaFS-L06-1314-T02-B 1 9.00E-01 U1/2
Co JaFS-L06-1314-T03-B 1 9.00E-01 U1/2
Co JaFS-L06-1314-T04-B 1 9.00E-01 U1/2
Co JaFS-L06-1314-T05-B 1 9.00E-01 U1/2
Co JaFS-L06-1314-T06-B 1 9.00E-01 U1/2
Co JaFS-L06-1314-T07-B 1 9.00E-01 U1/2
Co JaFS-L06-1314-T08-B 1 9.00E-01 U1/2
Co JaFS-L06-1314-T09-B 1 9.00E-01 U1/2
Co JaFS-L06-1314-T01-C 1 9.00E-01 U1/2
Co JaFS-L06-1314-T02-C 1 9.00E-01 U1/2
Co JaFS-L06-1314-T03-C 1 9.00E-01 U1/2
Co JaFS-L06-1314-T04-C 1 9.00E-01 U1/2
Co JaFS-L06-1314-T05-C 1 9.00E-01 U1/2
Co JaFS-L06-1314-T06-C 1 9.00E-01 U1/2
Co JaFS-L06-1314-T07-C 1 9.00E-01 U1/2
Co JaFS-L06-1314-T08-C 1 9.00E-01 U1/2
Co JaFS-L06-1314-T09-C 1 9.00E-01 U1/2
Co JaFS-L06-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 7.35 1.80 5.72
9.00E-01 50.46 1.80 5.72
9.00E-01 28.71 1.80 5.72 10000 1000
9.00E-01 19.85 1.80 5.72
9.00E-01 36.29 1.80 5.72
9.00E-01 36.35 1.80 5.72
9.00E-01 12.61 1.80 5.72
9.00E-01 10.21 1.80 5.72
9.00E-01 40.15 1.80 5.72
9.00E-01 35.22 1.80 5.72
9.00E-01 44.86 1.80 5.72
9.00E-01 245.54 1.80 5.72 10000 1000
9.00E-01 35.82 1.80 5.72
9.00E-01 51.08 1.80 5.72
9.00E-01 26.56 1.80 5.72
9.00E-01 35.80 1.80 5.72
9.00E-01 24.76 1.80 5.72
9.00E-01 25.09 1.80 5.72
9.00E-01 34.56 1.80 5.72
9.00E-01 55.80 1.80 5.72
9.00E-01 47.39 1.80 5.72 10000 1000
9.00E-01 50.79 1.80 5.72
9.00E-01 23.81 1.80 5.72
9.00E-01 47.71 1.80 5.72
9.00E-01 27.86 1.80 5.72
9.00E-01 9.40 1.80 5.72
9.00E-01 33.49 1.80 5.72
9.00E-01 23.11 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.40E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.55E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.23E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 12:33 PM EPA Interlab L06 1314 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
12/14/11 12:48 PM EPA Interlab L06 1314 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-274
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Cu JaFS-L06-1314-T01-A 1 1.17E+03
Cu JaFS-L06-1314-T02-A 1 8.77E+02
Cu JaFS-L06-1314-T03-A 1 4.59E+02
Cu JaFS-L06-1314-T04-A 1 2.48E+02
Cu JaFS-L06-1314-T05-A 1 2.14E+02
Cu JaFS-L06-1314-T06-A 1 1.53E+02
Cu JaFS-L06-1314-T07-A 1 1.03E+02
Cu JaFS-L06-1314-T08-A 1 8.15E+01
Cu JaFS-L06-1314-T09-A 1 6.92E+01
Cu JaFS-L06-1314-T01-B 1 1.05E+03
Cu JaFS-L06-1314-T02-B 1 8.21E+02
Cu JaFS-L06-1314-T03-B 1 4.56E+02
Cu JaFS-L06-1314-T04-B 1 2.79E+02
Cu JaFS-L06-1314-T05-B 1 2.18E+02
Cu JaFS-L06-1314-T06-B 1 1.54E+02
Cu JaFS-L06-1314-T07-B 1 1.14E+02
Cu JaFS-L06-1314-T08-B 1 8.64E+01
Cu JaFS-L06-1314-T09-B 1 6.82E+01
Cu JaFS-L06-1314-T01-C 1 1.18E+03
Cu JaFS-L06-1314-T02-C 1 8.09E+02
Cu JaFS-L06-1314-T03-C 1 4.41E+02
Cu JaFS-L06-1314-T04-C 1 2.79E+02
Cu JaFS-L06-1314-T05-C 1 2.29E+02
Cu JaFS-L06-1314-T06-C 1 1.69E+02
Cu JaFS-L06-1314-T07-C 1 1.28E+02
Cu JaFS-L06-1314-T08-C 1 9.70E+01
Cu JaFS-L06-1314-T09-C 1 7.05E+01
Cu JaFS-L06-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.17E+03 0.88 3.70 11.80
8.77E+02 0.76 3.70 11.80
4.59E+02 0.54 3.70 11.80 10000 1000
2.48E+02 8.20 3.70 11.80
2.14E+02 1.47 3.70 11.80
1.53E+02 0.98 3.70 11.80
1.03E+02 2.26 3.70 11.80
8.15E+01 1.45 3.70 11.80
6.92E+01 2.48 3.70 11.80
1.05E+03 0.59 3.70 11.80
8.21E+02 0.66 3.70 11.80
4.56E+02 2.17 3.70 11.80 10000 1000
2.79E+02 1.59 3.70 11.80
2.18E+02 1.11 3.70 11.80
1.54E+02 2.44 3.70 11.80
1.14E+02 1.19 3.70 11.80
8.64E+01 1.34 3.70 11.80
6.82E+01 0.66 3.70 11.80
1.18E+03 3.04 3.70 11.80
8.09E+02 1.34 3.70 11.80
4.41E+02 1.52 3.70 11.80 10000 1000
2.79E+02 2.00 3.70 11.80
2.29E+02 1.20 3.70 11.80
1.69E+02 0.57 3.70 11.80
1.28E+02 2.05 3.70 11.80
9.70E+01 4.67 3.70 11.80
7.05E+01 1.54 3.70 11.80
1.85E+00 33.55 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.50E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.53E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.53E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 12:33 PM EPA Interlab L06 1314 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
12/14/11 12:48 PM EPA Interlab L06 1314 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-275
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Fe JaFS-L06-1314-T01-A 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T02-A 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T03-A 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T04-A 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T05-A 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T06-A 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T07-A 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T08-A 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T09-A 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T01-B 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T02-B 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T03-B 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T04-B 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T05-B 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T06-B 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T07-B 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T08-B 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T09-B 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T01-C 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T02-C 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T03-C 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T04-C 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T05-C 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T06-C 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T07-C 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T08-C 1 1.00E+00 U1/2
Fe JaFS-L06-1314-T09-C 1 1.00E+00 U1/2
Fe JaFS-L06-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 19.22 2.00 6.40
1.00E+00 8.47 2.00 6.40
1.00E+00 5.86 2.00 6.40 10000 1000
1.00E+00 18.28 2.00 6.40
1.00E+00 11.18 2.00 6.40
1.00E+00 3.33 2.00 6.40
1.00E+00 6.45 2.00 6.40
1.00E+00 8.29 2.00 6.40
1.00E+00 6.48 2.00 6.40
1.00E+00 3.75 2.00 6.40
1.00E+00 0.98 2.00 6.40
1.00E+00 5.25 2.00 6.40 10000 1000
1.00E+00 3.80 2.00 6.40
1.00E+00 2.94 2.00 6.40
1.00E+00 7.17 2.00 6.40
1.00E+00 4.90 2.00 6.40
1.00E+00 6.83 2.00 6.40
1.00E+00 2.30 2.00 6.40
1.00E+00 12.50 2.00 6.40
1.00E+00 7.82 2.00 6.40
1.00E+00 6.89 2.00 6.40 10000 1000
1.00E+00 2.62 2.00 6.40
1.00E+00 11.33 2.00 6.40
1.00E+00 2.70 2.00 6.40
1.00E+00 5.62 2.00 6.40
1.00E+00 9.26 2.00 6.40
1.00E+00 16.36 2.00 6.40
1.00E+00 13.67 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.15E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.29E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.99E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 1 2:33 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
1 2/1 4/1 1 1 2:48 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-276
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
Pb JaFS-L06-1314-T01-A 1 9.54E+01
Pb JaFS-L06-1314-T02-A 1 1.35E+02
Pb JaFS-L06-1314-T03-A 1 1.17E+02
Pb JaFS-L06-1314-T04-A 1 7.08E+01
Pb JaFS-L06-1314-T05-A 1 8.84E+01
Pb JaFS-L06-1314-T06-A 1 4.06E+01
Pb JaFS-L06-1314-T07-A 1 2.66E+01
Pb JaFS-L06-1314-T08-A 1 2.49E+01
Pb JaFS-L06-1314-T09-A 1 2.21E+01
Pb JaFS-L06-1314-T01-B 1 1.18E+02
Pb JaFS-L06-1314-T02-B 1 1.27E+02
Pb JaFS-L06-1314-T03-B 1 1.33E+02
Pb JaFS-L06-1314-T04-B 1 1.07E+02
Pb JaFS-L06-1314-T05-B 1 8.84E+01
Pb JaFS-L06-1314-T06-B 1 7.15E+01
Pb JaFS-L06-1314-T07-B 1 3.50E+01
Pb JaFS-L06-1314-T08-B 1 2.81E+01
Pb JaFS-L06-1314-T09-B 1 2.44E+01
Pb JaFS-L06-1314-T01-C 1 9.29E+01
Pb JaFS-L06-1314-T02-C 1 1.31E+02
Pb JaFS-L06-1314-T03-C 1 1.32E+02
Pb JaFS-L06-1314-T04-C 1 1.03E+02
Pb JaFS-L06-1314-T05-C 1 7.52E+01
Pb JaFS-L06-1314-T06-C 1 7.09E+01
Pb JaFS-L06-1314-T07-C 1 3.27E+01
Pb JaFS-L06-1314-T08-C 1 2.87E+01
Pb JaFS-L06-1314-T09-C 1 2.53E+01
Pb JaFS-L06-1314-B01-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.54E+01 4.71 6.80 21.60
1.35E+02 1.30 6.80 21.60
1.17E+02 4.54 6.80 21.60 10000 1000
7.08E+01 0.98 6.80 21.60
8.84E+01 0.69 6.80 21.60
4.06E+01 1.75 6.80 21.60
2.66E+01 3.10 6.80 21.60
2.49E+01 7.26 6.80 21.60
2.21 E+01 5.64 6.80 21.60
1.18E+02 3.92 6.80 21.60
1.27E+02 1.98 6.80 21.60
1.33E+02 2.50 6.80 21.60 10000 1000
1.07E+02 3.08 6.80 21.60
8.84E+01 3.46 6.80 21.60
7.15E+01 3.14 6.80 21.60
3.50E+01 4.65 6.80 21.60
2.81 E+01 5.90 6.80 21.60
2.44E+01 7.48 6.80 21.60
9.29E+01 6.99 6.80 21.60
1.31E+02 2.56 6.80 21.60
1.32E+02 4.49 6.80 21.60 10000 1000
1.03E+02 2.65 6.80 21.60
7.52E+01 1.48 6.80 21.60
7.09E+01 3.02 6.80 21.60
3.27E+01 5.86 6.80 21.60
2.87E+01 7.48 6.80 21.60
2.53E+01 6.68 6.80 21.60
3.40E+00 30.56 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.03E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 12:33 PM EPA Interlab L06 1314 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
12/14/11 12:48 PM EPA Interlab L06 1314 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-277
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Li JaFS-L06-1314-T01-A 1 7.19E+01
Li JaFS-L06-1314-T02-A 1 2.24E+01
Li JaFS-L06-1314-T03-A 1 9.50E-01 U1/2
Li JaFS-L06-1314-T04-A 1 9.50E-01 U1/2
Li JaFS-L06-1314-T05-A 1 9.50E-01 U1/2
Li JaFS-L06-1314-T06-A 1 9.50E-01 U1/2
Li JaFS-L06-1314-T07-A 1 9.50E-01 U1/2
Li JaFS-L06-1314-T08-A 1 9.50E-01 U1/2
Li JaFS-L06-1314-T09-A 1 9.50E-01 U1/2
Li JaFS-L06-1314-T01-B 1 7.57E+01
Li JaFS-L06-1314-T02-B 1 2.29E+01
Li JaFS-L06-1314-T03-B 1 9.50E-01 U1/2
Li JaFS-L06-1314-T04-B 1 9.50E-01 U1/2
Li JaFS-L06-1314-T05-B 1 9.50E-01 U1/2
Li JaFS-L06-1314-T06-B 1 9.50E-01 U1/2
Li JaFS-L06-1314-T07-B 1 9.50E-01 U1/2
Li JaFS-L06-1314-T08-B 1 9.50E-01 U1/2
Li JaFS-L06-1314-T09-B 1 9.50E-01 U1/2
Li JaFS-L06-1314-T01-C 1 8.85E+01
Li JaFS-L06-1314-T02-C 1 1.41E+01
Li JaFS-L06-1314-T03-C 1 9.50E-01 U1/2
Li JaFS-L06-1314-T04-C 1 9.50E-01 U1/2
Li JaFS-L06-1314-T05-C 1 9.50E-01 U1/2
Li JaFS-L06-1314-T06-C 1 9.50E-01 U1/2
Li JaFS-L06-1314-T07-C 1 9.50E-01 U1/2
Li JaFS-L06-1314-T08-C 1 9.50E-01 U1/2
Li JaFS-L06-1314-T09-C 1 9.50E-01 U1/2
Li JaFS-L06-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.19E+01 1.75 1.90 6.00
2.24E+01 8.70 1.90 6.00
9.50E-01 2.74 1.90 6.00 10000 1000
9.50E-01 1.55 1.90 6.00
9.50E-01 5.39 1.90 6.00
9.50E-01 4.42 1.90 6.00
9.50E-01 4.95 1.90 6.00
9.50E-01 9.34 1.90 6.00
9.50E-01 3.17 1.90 6.00
7.57E+01 3.43 1.90 6.00
2.29E+01 2.55 1.90 6.00
9.50E-01 2.60 1.90 6.00 10000 1000
9.50E-01 18.77 1.90 6.00
9.50E-01 5.63 1.90 6.00
9.50E-01 1.25 1.90 6.00
9.50E-01 2.79 1.90 6.00
9.50E-01 5.50 1.90 6.00
9.50E-01 12.37 1.90 6.00
8.85E+01 3.79 1.90 6.00
1.41E+01 1.26 1.90 6.00
9.50E-01 2.64 1.90 6.00 10000 1000
9.50E-01 5.67 1.90 6.00
9.50E-01 3.95 1.90 6.00
9.50E-01 2.47 1.90 6.00
9.50E-01 6.20 1.90 6.00
9.50E-01 14.87 1.90 6.00
9.50E-01 1.31 1.90 6.00
9.50E-01 5.45 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.91E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.94E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.67E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 12:33 PM EPA Interlab L06 1314 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
12/14/11 12:48 PM EPA Interlab L06 1314 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-278
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Mn JaFS-L06-1314-T01-A 1 2.40E+02
Mn JaFS-L06-1314-T02-A 1 5.26E+01
Mn JaFS-L06-1314-T03-A 1 1.05E+01
Mn JaFS-L06-1314-T04-A 1 9.20E+00
Mn JaFS-L06-1314-T05-A 1 1.26E+01
Mn JaFS-L06-1314-T06-A 1 1.31E+01
Mn JaFS-L06-1314-T07-A 1 9.90E+00
Mn JaFS-L06-1314-T08-A 1 5.72E+00 E
Mn JaFS-L06-1314-T09-A 1 6.50E+00
Mn JaFS-L06-1314-T01-B 1 2.65E+02
Mn JaFS-L06-1314-T02-B 1 5.32E+01
Mn JaFS-L06-1314-T03-B 1 1.03E+01
Mn JaFS-L06-1314-T04-B 1 1.06E+01
Mn JaFS-L06-1314-T05-B 1 1.05E+01
Mn JaFS-L06-1314-T06-B 1 1.02E+01
Mn JaFS-L06-1314-T07-B 1 7.41E+00
Mn JaFS-L06-1314-T08-B 1 4.89E+00 E
Mn JaFS-L06-1314-T09-B 1 6.16E+00 E
Mn JaFS-L06-1314-T01-C 1 3.22E+02
Mn JaFS-L06-1314-T02-C 1 3.26E+01
Mn JaFS-L06-1314-T03-C 1 9.83E+00
Mn JaFS-L06-1314-T04-C 1 9.76E+00
Mn JaFS-L06-1314-T05-C 1 1.03E+01
Mn JaFS-L06-1314-T06-C 1 9.37E+00
Mn JaFS-L06-1314-T07-C 1 6.77E+00
Mn JaFS-L06-1314-T08-C 1 4.40E+00 E
Mn JaFS-L06-1314-T09-C 1 3.51E+00 E
Mn JaFS-L06-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.40E+02 1.46 2.00 6.40
5.26E+01 1.57 2.00 6.40
1.05E+01 0.20 2.00 6.40 10000 1000
9.20E+00 2.68 2.00 6.40
1.26E+01 1.93 2.00 6.40
1.31E+01 1.51 2.00 6.40
9.90E+00 2.56 2.00 6.40
5.72E+00 0.96 2.00 6.40
6.50E+00 1.61 2.00 6.40
2.65E+02 1.11 2.00 6.40
5.32E+01 0.73 2.00 6.40
1.03E+01 2.02 2.00 6.40 10000 1000
1.06E+01 1.95 2.00 6.40
1.05E+01 2.53 2.00 6.40
1.02E+01 2.70 2.00 6.40
7.41E+00 1.45 2.00 6.40
4.89E+00 2.11 2.00 6.40
6.16E+00 1.85 2.00 6.40
3.22E+02 1.72 2.00 6.40
3.26E+01 1.09 2.00 6.40
9.83E+00 1.07 2.00 6.40 10000 1000
9.76E+00 1.40 2.00 6.40
1.03E+01 1.15 2.00 6.40
9.37E+00 0.61 2.00 6.40
6.77E+00 2.57 2.00 6.40
4.40E+00 1.96 2.00 6.40
3.51E+00 1.18 2.00 6.40
1.00E+00 14.38 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.06E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.16E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.16E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 12:33 PM EPA Interlab L06 1314 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
1 2/1 4/1 1 1 2:43 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 1 2:45 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 1 2:46 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 12:48 PM EPA Interlab L06 1314 JaFS
1 2/1 4/1 1 1 2:50 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 12:51 PM EPA Interlab L06 131 4 JaFS
12/14/11 1 2:53 PM EPA Interlab L06 1 31 4 JaFS
1 2/1 4/1 1 1 2:55 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-279
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Mg JaFS-L06-1314-T01-A 1 5.92E+04
Mg JaFS-L06-1314-T02-A 1 8.52E+03
Mg JaFS-L06-1314-T03-A 1 2.83E+03
Mg JaFS-L06-1314-T04-A 1 2.32E+03
Mg JaFS-L06-1314-T05-A 1 3.00E+03
Mg JaFS-L06-1314-T06-A 1 2.34E+03
Mg JaFS-L06-1314-T07-A 1 1.84E+03
Mg JaFS-L06-1314-T08-A 1 1.36E+03
Mg JaFS-L06-1314-T09-A 1 1.27E+03
Mg JaFS-L06-1314-T01-B 1 6.65E+04
Mg JaFS-L06-1314-T02-B 1 8.34E+03
Mg JaFS-L06-1314-T03-B 1 2.70E+03
Mg JaFS-L06-1314-T04-B 1 2.83E+03
Mg JaFS-L06-1314-T05-B 1 2.95E+03
Mg JaFS-L06-1314-T06-B 1 2.41E+03
Mg JaFS-L06-1314-T07-B 1 1.85E+03
Mg JaFS-L06-1314-T08-B 1 1.39E+03
Mg JaFS-L06-1314-T09-B 1 1.21E+03
Mg JaFS-L06-1314-T01-C 1 7.91E+04
Mg JaFS-L06-1314-T02-C 1 8.13E+03
Mg JaFS-L06-1314-T03-C 1 2.47E+03
Mg JaFS-L06-1314-T04-C 1 2.62E+03
Mg JaFS-L06-1314-T05-C 1 2.81E+03
Mg JaFS-L06-1314-T06-C 1 2.26E+03
Mg JaFS-L06-1314-T07-C 1 1.76E+03
Mg JaFS-L06-1314-T08-C 1 1.31E+03
Mg JaFS-L06-1314-T09-C 1 1.09E+03
Mg JaFS-L06-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.92E+04 0.51 1.00 3.18
8.52E+03 0.54 1.00 3.18
2.83E+03 0.54 1.00 3.18 10000 1000
2.32E+03 0.88 1.00 3.18
3.00E+03 0.90 1.00 3.18
2.34E+03 0.75 1.00 3.18
1.84E+03 2.86 1.00 3.18
1.36E+03 0.43 1.00 3.18
1.27E+03 0.31 1.00 3.18
6.65E+04 0.96 1.00 3.18
8.34E+03 1.13 1.00 3.18
2.70E+03 1.30 1.00 3.18 10000 1000
2.83E+03 1.43 1.00 3.18
2.95E+03 1.50 1.00 3.18
2.41E+03 2.54 1.00 3.18
1.85E+03 1.90 1.00 3.18
1.39E+03 1.81 1.00 3.18
1.21E+03 0.18 1.00 3.18
7.91E+04 3.31 1.00 3.18
8.13E+03 1.72 1.00 3.18
2.47E+03 0.62 1.00 3.18 10000 1000
2.62E+03 1.53 1.00 3.18
2.81E+03 0.76 1.00 3.18
2.26E+03 0.86 1.00 3.18
1.76E+03 0.67 1.00 3.18
1.31E+03 1.34 1.00 3.18
1.09E+03 0.42 1.00 3.18
5.00E-01 9.78 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.81 E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.66E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.44E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 1 2:33 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
1 2/1 4/1 1 1 2:48 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-280
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Mo JaFS-L06-1314-T01-A 1 9.26E+01
Mo JaFS-L06-1314-T02-A 1 6.17E+01
Mo JaFS-L06-1314-T03-A 1 1.42E+01
Mo JaFS-L06-1314-T04-A 1 1.14E+01
Mo JaFS-L06-1314-T05-A 1 1.17E+01
Mo JaFS-L06-1314-T06-A 1 7.82E+00
Mo JaFS-L06-1314-T07-A 1 5.46E+00
Mo JaFS-L06-1314-T08-A 1 2.28E+00 E
Mo JaFS-L06-1314-T09-A 1 4.09E+00
Mo JaFS-L06-1314-T01-B 1 1.03E+02
Mo JaFS-L06-1314-T02-B 1 6.68E+01
Mo JaFS-L06-1314-T03-B 1 1.48E+01
Mo JaFS-L06-1314-T04-B 1 1.45E+01
Mo JaFS-L06-1314-T05-B 1 1.11E+01
Mo JaFS-L06-1314-T06-B 1 7.69E+00
Mo JaFS-L06-1314-T07-B 1 4.73E+00
Mo JaFS-L06-1314-T08-B 1 3.67E+00 E
Mo JaFS-L06-1314-T09-B 1 4.23E+00
Mo JaFS-L06-1314-T01-C 1 1.09E+02
Mo JaFS-L06-1314-T02-C 1 5.79E+01
Mo JaFS-L06-1314-T03-C 1 1.35E+01
Mo JaFS-L06-1314-T04-C 1 1.41E+01
Mo JaFS-L06-1314-T05-C 1 1.23E+01
Mo JaFS-L06-1314-T06-C 1 7.15E+00
Mo JaFS-L06-1314-T07-C 1 4.63E+00
Mo JaFS-L06-1314-T08-C 1 3.60E+00 E
Mo JaFS-L06-1314-T09-C 1 2.61E+00 E
Mo JaFS-L06-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.26E+01 1.44 1.20 3.82
6.17E+01 1.21 1.20 3.82
1.42E+01 1.88 1.20 3.82 10000 1000
1.14E+01 1.23 1.20 3.82
1.17E+01 0.93 1.20 3.82
7.82E+00 9.95 1.20 3.82
5.46E+00 1.88 1.20 3.82
2.28E+00 10.20 1.20 3.82
4.09E+00 4.75 1.20 3.82
1.03E+02 0.67 1.20 3.82
6.68E+01 1.74 1.20 3.82
1.48E+01 6.98 1.20 3.82 10000 1000
1.45E+01 4.70 1.20 3.82
1.11E+01 3.74 1.20 3.82
7.69E+00 5.50 1.20 3.82
4.73E+00 8.26 1.20 3.82
3.67E+00 9.97 1.20 3.82
4.23E+00 15.26 1.20 3.82
1.09E+02 3.45 1.20 3.82
5.79E+01 2.71 1.20 3.82
1.35E+01 4.33 1.20 3.82 10000 1000
1.41E+01 3.61 1.20 3.82
1.23E+01 4.11 1.20 3.82
7.15E+00 2.68 1.20 3.82
4.63E+00 8.03 1.20 3.82
3.60E+00 13.46 1.20 3.82
2.61E+00 15.55 1.20 3.82
6.00E-01 17.54 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.68E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.34E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.62E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 1 2:33 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
12/14/11 12:48 PM EPA Interlab L06 1314 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-281
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ni JaFS-L06-1314-T01-A 1 7.66E+00
Ni JaFS-L06-1314-T02-A 1 3.18E+00 E
Ni JaFS-L06-1314-T03-A 1 2.02E+00 E
Ni JaFS-L06-1314-T04-A 1 9.00E-01 U1/2
Ni JaFS-L06-1314-T05-A 1 9.00E-01 U1/2
Ni JaFS-L06-1314-T06-A 1 9.00E-01 U1/2
Ni JaFS-L06-1314-T07-A 1 9.00E-01 U1/2
Ni JaFS-L06-1314-T08-A 1 9.00E-01 U1/2
Ni JaFS-L06-1314-T09-A 1 9.00E-01 U1/2
Ni JaFS-L06-1314-T01-B 1 9.16E+00
Ni JaFS-L06-1314-T02-B 1 3.10E+00 E
Ni JaFS-L06-1314-T03-B 1 1.92E+00 E
Ni JaFS-L06-1314-T04-B 1 9.00E-01 U1/2
Ni JaFS-L06-1314-T05-B 1 9.00E-01 U1/2
Ni JaFS-L06-1314-T06-B 1 9.00E-01 U1/2
Ni JaFS-L06-1314-T07-B 1 9.00E-01 U1/2
Ni JaFS-L06-1314-T08-B 1 9.00E-01 U1/2
Ni JaFS-L06-1314-T09-B 1 9.00E-01 U1/2
Ni JaFS-L06-1314-T01-C 1 1.60E+01
Ni JaFS-L06-1314-T02-C 1 2.44E+00 E
Ni JaFS-L06-1314-T03-C 1 1.90E+00 E
Ni JaFS-L06-1314-T04-C 1 9.00E-01 U1/2
Ni JaFS-L06-1314-T05-C 1 9.00E-01 U1/2
Ni JaFS-L06-1314-T06-C 1 9.00E-01 U1/2
Ni JaFS-L06-1314-T07-C 1 9.00E-01 U1/2
Ni JaFS-L06-1314-T08-C 1 9.00E-01 U1/2
Ni JaFS-L06-1314-T09-C 1 9.00E-01 U1/2
Ni JaFS-L06-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.66E+00 3.36 1.80 5.70
3.18E+00 13.46 1.80 5.70
2.02E+00 27.87 1.80 5.70 10000 1000
9.00E-01 48.76 1.80 5.70
9.00E-01 43.51 1.80 5.70
9.00E-01 11.80 1.80 5.70
9.00E-01 30.81 1.80 5.70
9.00E-01 35.96 1.80 5.70
9.00E-01 22.80 1.80 5.70
9.16E+00 7.24 1.80 5.70
3.10E+00 12.65 1.80 5.70
1.92E+00 24.71 1.80 5.70 10000 1000
9.00E-01 60.29 1.80 5.70
9.00E-01 47.03 1.80 5.70
9.00E-01 22.93 1.80 5.70
9.00E-01 29.91 1.80 5.70
9.00E-01 52.41 1.80 5.70
9.00E-01 48.44 1.80 5.70
1.60E+01 6.00 1.80 5.70
2.44E+00 34.61 1.80 5.70
1.90E+00 18.38 1.80 5.70 10000 1000
9.00E-01 19.15 1.80 5.70
9.00E-01 9.76 1.80 5.70
9.00E-01 51.53 1.80 5.70
9.00E-01 50.30 1.80 5.70
9.00E-01 18.27 1.80 5.70
9.00E-01 25.92 1.80 5.70
9.00E-01 44.62 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.44E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.51 E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.21E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 1 2:33 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
12/14/11 12:48 PM EPA Interlab L06 1314 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-282
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
P JaFS-L06-1314-T01-A 1 7.03E+01
P JaFS-L06-1314-T02-A 1 4.48E+01
P JaFS-L06-1314-T03-A 1 3.71E+01
P JaFS-L06-1314-T04-A 1 3.19E+01
P JaFS-L06-1314-T05-A 1 3.24E+01
P JaFS-L06-1314-T06-A 1 2.66E+01
P JaFS-L06-1314-T07-A 1 2.32E+01
P JaFS-L06-1314-T08-A 1 2.16E+01
P JaFS-L06-1314-T09-A 1 3.78E+01
P JaFS-L06-1314-T01-B 1 8.64E+01
P JaFS-L06-1314-T02-B 1 5.70E+01
P JaFS-L06-1314-T03-B 1 3.65E+01
P JaFS-L06-1314-T04-B 1 4.50E+01
P JaFS-L06-1314-T05-B 1 2.58E+01
P JaFS-L06-1314-T06-B 1 2.26E+01
P JaFS-L06-1314-T07-B 1 2.36E+01
P JaFS-L06-1314-T08-B 1 3.14E+01
P JaFS-L06-1314-T09-B 1 4.03E+01
P JaFS-L06-1314-T01-C 1 9.65E+01
P JaFS-L06-1314-T02-C 1 5.94E+01
P JaFS-L06-1314-T03-C 1 4.19E+01
P JaFS-L06-1314-T04-C 1 3.71E+01
P JaFS-L06-1314-T05-C 1 2.76E+01
P JaFS-L06-1314-T06-C 1 2.72E+01
P JaFS-L06-1314-T07-C 1 2.78E+01
P JaFS-L06-1314-T08-C 1 3.36E+01
P JaFS-L06-1314-T09-C 1 5.59E+01
P JaFS-L06-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.03E+01 1.92 3.70 11.80
4.48E+01 4.60 3.70 11.80
3.71E+01 16.26 3.70 11.80 10000 1000
3.19E+01 3.09 3.70 11.80
3.24E+01 2.22 3.70 11.80
2.66E+01 3.97 3.70 11.80
2.32E+01 3.61 3.70 11.80
2.16E+01 3.34 3.70 11.80
3.78E+01 2.03 3.70 11.80
8.64E+01 2.27 3.70 11.80
5.70E+01 2.27 3.70 11.80
3.65E+01 1.07 3.70 11.80 10000 1000
4.50E+01 10.58 3.70 11.80
2.58E+01 9.85 3.70 11.80
2.26E+01 4.25 3.70 11.80
2.36E+01 2.83 3.70 11.80
3.14E+01 3.18 3.70 11.80
4.03E+01 1.50 3.70 11.80
9.65E+01 1.18 3.70 11.80
5.94E+01 6.36 3.70 11.80
4.19E+01 2.84 3.70 11.80 10000 1000
3.71 E+01 2.51 3.70 11.80
2.76E+01 1.84 3.70 11.80
2.72E+01 1.85 3.70 11.80
2.78E+01 2.57 3.70 11.80
3.36E+01 0.24 3.70 11.80
5.59E+01 1.52 3.70 11.80
1.85E+00 25.07 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.05E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.31E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.96E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 12:33 PM EPA Interlab L06 1314 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
12/14/11 12:48 PM EPA Interlab L06 1314 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-283
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
K JaFS-L06-1314-T01-A 1 5.90E+04
K JaFS-L06-1314-T02-A 1 2.45E+04
K JaFS-L06-1314-T03-A 1 1.03E+04
K JaFS-L06-1314-T04-A 1 7.93E+03
K JaFS-L06-1314-T05-A 1 8.39E+03
K JaFS-L06-1314-T06-A 1 5.80E+03
K JaFS-L06-1314-T07-A 1 3.99E+03
K JaFS-L06-1314-T08-A 1 2.81E+03
K JaFS-L06-1314-T09-A 1 2.22E+03
K JaFS-L06-1314-T01-B 1 6.34E+04
K JaFS-L06-1314-T02-B 1 2.44E+04
K JaFS-L06-1314-T03-B 1 1.06E+04
K JaFS-L06-1314-T04-B 1 9.75E+03
K JaFS-L06-1314-T05-B 1 8.66E+03
K JaFS-L06-1314-T06-B 1 6.08E+03
K JaFS-L06-1314-T07-B 1 4.05E+03
K JaFS-L06-1314-T08-B 1 2.94E+03
K JaFS-L06-1314-T09-B 1 2.24E+03
K JaFS-L06-1314-T01-C 1 6.85E+04
K JaFS-L06-1314-T02-C 1 1.77E+04
K JaFS-L06-1314-T03-C 1 1.02E+04
K JaFS-L06-1314-T04-C 1 9.55E+03
K JaFS-L06-1314-T05-C 1 8.70E+03
K JaFS-L06-1314-T06-C 1 6.14E+03
K JaFS-L06-1314-T07-C 1 4.13E+03
K JaFS-L06-1314-T08-C 1 3.01E+03
K JaFS-L06-1314-T09-C 1 2.24E+03
K JaFS-L06-1314-B01-A 1 1.73E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.90E+04 0.38 1.60 5.09
2.45E+04 0.46 1.60 5.09
1.03E+04 0.31 1.60 5.09 10000 1000
7.93E+03 0.52 1.60 5.09
8.39E+03 1.53 1.60 5.09
5.80E+03 1.05 1.60 5.09
3.99E+03 2.46 1.60 5.09
2.81E+03 0.42 1.60 5.09
2.22E+03 1.02 1.60 5.09
6.34E+04 1.09 1.60 5.09
2.44E+04 0.49 1.60 5.09
1.06E+04 1.59 1.60 5.09 10000 1000
9.75E+03 1.65 1.60 5.09
8.66E+03 1.35 1.60 5.09
6.08E+03 2.02 1.60 5.09
4.05E+03 1.71 1.60 5.09
2.94E+03 2.17 1.60 5.09
2.24E+03 0.93 1.60 5.09
6.85E+04 3.13 1.60 5.09
1.77E+04 1.53 1.60 5.09
1.02E+04 0.82 1.60 5.09 10000 1000
9.55E+03 1.63 1.60 5.09
8.70E+03 0.36 1.60 5.09
6.14E+03 0.20 1.60 5.09
4.13E+03 0.67 1.60 5.09
3.01 E+03 1.69 1.60 5.09
2.24E+03 0.51 1.60 5.09
1.73E+01 3.27 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.12E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.11E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 1 2:33 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
1 2/1 4/1 1 1 2:48 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-284
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
Se JaFS-L06-1314-T01-A 1 5.30E+01
Se JaFS-L06-1314-T02-A 1 1.98E+01 E
Se JaFS-L06-1314-T03-A 1 7.50E+00 U1/2
Se JaFS-L06-1314-T04-A 1 7.50E+00 U1/2
Se JaFS-L06-1314-T05-A 1 7.50E+00 U1/2
Se JaFS-L06-1314-T06-A 1 7.50E+00 U1/2
Se JaFS-L06-1314-T07-A 1 7.50E+00 U1/2
Se JaFS-L06-1314-T08-A 1 7.50E+00 U1/2
Se JaFS-L06-1314-T09-A 1 7.50E+00 U1/2
Se JaFS-L06-1314-T01-B 1 5.30E+01
Se JaFS-L06-1314-T02-B 1 1.98E+01 E
Se JaFS-L06-1314-T03-B 1 7.50E+00 U1/2
Se JaFS-L06-1314-T04-B 1 7.50E+00 U1/2
Se JaFS-L06-1314-T05-B 1 7.50E+00 U1/2
Se JaFS-L06-1314-T06-B 1 7.50E+00 U1/2
Se JaFS-L06-1314-T07-B 1 7.50E+00 U1/2
Se JaFS-L06-1314-T08-B 1 7.50E+00 U1/2
Se JaFS-L06-1314-T09-B 1 7.50E+00 U1/2
Se JaFS-L06-1314-T01-C 1 5.30E+01
Se JaFS-L06-1314-T02-C 1 1.98E+01 E
Se JaFS-L06-1314-T03-C 1 7.50E+00 U1/2
Se JaFS-L06-1314-T04-C 1 7.50E+00 U1/2
Se JaFS-L06-1314-T05-C 1 7.50E+00 U1/2
Se JaFS-L06-1314-T06-C 1 7.50E+00 U1/2
Se JaFS-L06-1314-T07-C 1 7.50E+00 U1/2
Se JaFS-L06-1314-T08-C 1 7.50E+00 U1/2
Se JaFS-L06-1314-T09-C 1 7.50E+00 U1/2
Se JaFS-L06-1314-B01-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.30E+01 1.50 15.00 47.70
1.98E+01 18.11 15.00 47.70
7.50E+00 3.76 15.00 47.70 10000 1000
7.50E+00 46.69 15.00 47.70
7.50E+00 35.01 15.00 47.70
7.50E+00 42.77 15.00 47.70
7.50E+00 28.60 15.00 47.70
7.50E+00 9.34 15.00 47.70
7.50E+00 28.41 15.00 47.70
5.30E+01 3.12 15.00 47.70
1.98E+01 17.13 15.00 47.70
7.50E+00 38.34 15.00 47.70 10000 1000
7.50E+00 17.27 15.00 47.70
7.50E+00 24.69 15.00 47.70
7.50E+00 17.18 15.00 47.70
7.50E+00 9.11 15.00 47.70
7.50E+00 35.41 15.00 47.70
7.50E+00 29.31 15.00 47.70
5.30E+01 1.23 15.00 47.70
1.98E+01 19.72 15.00 47.70
7.50E+00 30.35 15.00 47.70 10000 1000
7.50E+00 23.97 15.00 47.70
7.50E+00 54.13 15.00 47.70
7.50E+00 15.60 15.00 47.70
7.50E+00 29.14 15.00 47.70
7.50E+00 22.78 15.00 47.70
7.50E+00 37.73 15.00 47.70
7.50E+00 26.05 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.82E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.98E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.71E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 12:33PM EPA Interlab L06 1314 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
12/14/11 12:48 PM EPA Interlab L06 1314 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-285
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Si JaFS-L06-1314-T01-A 1 5.82E+03
Si JaFS-L06-1314-T02-A 1 3.25E+03
Si JaFS-L06-1314-T03-A 1 2.45E+03
Si JaFS-L06-1314-T04-A 1 2.00E+03
Si JaFS-L06-1314-T05-A 1 2.23E+03
Si JaFS-L06-1314-T06-A 1 2.21E+03
Si JaFS-L06-1314-T07-A 1 2.06E+03
Si JaFS-L06-1314-T08-A 1 2.39E+03
Si JaFS-L06-1314-T09-A 1 2.80E+03
Si JaFS-L06-1314-T01-B 1 5.38E+03
Si JaFS-L06-1314-T02-B 1 3.25E+03
Si JaFS-L06-1314-T03-B 1 2.45E+03
Si JaFS-L06-1314-T04-B 1 2.44E+03
Si JaFS-L06-1314-T05-B 1 2.22E+03
Si JaFS-L06-1314-T06-B 1 2.16E+03
Si JaFS-L06-1314-T07-B 1 2.02E+03
Si JaFS-L06-1314-T08-B 1 2.39E+03
Si JaFS-L06-1314-T09-B 1 2.76E+03
Si JaFS-L06-1314-T01-C 1 5.38E+03
Si JaFS-L06-1314-T02-C 1 3.10E+03
Si JaFS-L06-1314-T03-C 1 2.40E+03
Si JaFS-L06-1314-T04-C 1 2.40E+03
Si JaFS-L06-1314-T05-C 1 2.30E+03
Si JaFS-L06-1314-T06-C 1 2.18E+03
Si JaFS-L06-1314-T07-C 1 2.07E+03
Si JaFS-L06-1314-T08-C 1 2.40E+03
Si JaFS-L06-1314-T09-C 1 2.74E+03
Si JaFS-L06-1314-B01-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.82E+03 0.55 1.10 3.50
3.25E+03 0.53 1.10 3.50
2.45E+03 0.57 1.10 3.50 10000 1000
2.00E+03 2.77 1.10 3.50
2.23E+03 1.53 1.10 3.50
2.21 E+03 1.20 1.10 3.50
2.06E+03 2.90 1.10 3.50
2.39E+03 0.93 1.10 3.50
2.80E+03 1.93 1.10 3.50
5.38E+03 0.72 1.10 3.50
3.25E+03 0.41 1.10 3.50
2.45E+03 1.12 1.10 3.50 10000 1000
2.44E+03 1.44 1.10 3.50
2.22E+03 1.19 1.10 3.50
2.16E+03 2.15 1.10 3.50
2.02E+03 1.94 1.10 3.50
2.39E+03 1.69 1.10 3.50
2.76E+03 1.31 1.10 3.50
5.38E+03 3.31 1.10 3.50
3.10E+03 1.69 1.10 3.50
2.40E+03 0.65 1.10 3.50 10000 1000
2.40E+03 1.37 1.10 3.50
2.30E+03 0.34 1.10 3.50
2.18E+03 0.75 1.10 3.50
2.07E+03 0.40 1.10 3.50
2.40E+03 2.05 1.10 3.50
2.74E+03 0.82 1.10 3.50
5.50E-01 12.88 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.33E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.35E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.31 E+03 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 1 2:33 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
1 2/1 4/1 1 1 2:48 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-286
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
Na JaFS-L06-1314-T01-A 1 2.16E+05
Na JaFS-L06-1314-T02-A 1 1.10E+05
Na JaFS-L06-1314-T03-A 1 3.96E+04
Na JaFS-L06-1314-T04-A 1 1.34E+04
Na JaFS-L06-1314-T05-A 1 3.80E+03
Na JaFS-L06-1314-T06-A 1 9.85E+02
Na JaFS-L06-1314-T07-A 1 5.82E+02
Na JaFS-L06-1314-T08-A 1 3.80E+02
Na JaFS-L06-1314-T09-A 1 3.58E+02
Na JaFS-L06-1314-T01-B 1 2.26E+05
Na JaFS-L06-1314-T02-B 1 1.14E+05
Na JaFS-L06-1314-T03-B 1 4.23E+04
Na JaFS-L06-1314-T04-B 1 1.78E+04
Na JaFS-L06-1314-T05-B 1 3.90E+03
Na JaFS-L06-1314-T06-B 1 1.02E+03
Na JaFS-L06-1314-T07-B 1 5.60E+02
Na JaFS-L06-1314-T08-B 1 4.21E+02
Na JaFS-L06-1314-T09-B 1 3.52E+02
Na JaFS-L06-1314-T01-C 1 2.43E+05
Na JaFS-L06-1314-T02-C 1 8.86E+04
Na JaFS-L06-1314-T03-C 1 3.97E+04
Na JaFS-L06-1314-T04-C 1 1.50E+04
Na JaFS-L06-1314-T05-C 1 3.22E+03
Na JaFS-L06-1314-T06-C 1 1.02E+03
Na JaFS-L06-1314-T07-C 1 5.71E+02
Na JaFS-L06-1314-T08-C 1 4.27E+02
Na JaFS-L06-1314-T09-C 1 3.50E+02
Na JaFS-L06-1314-B01-A 1 1.25E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.16E+05 0.08 2.50 8.00
1.10E+05 0.09 2.50 8.00
3.96E+04 0.87 2.50 8.00 10000 1000
1.34E+04 0.92 2.50 8.00
3.80E+03 0.37 2.50 8.00
9.85E+02 1.06 2.50 8.00
5.82E+02 1.23 2.50 8.00
3.80E+02 0.87 2.50 8.00
3.58E+02 0.90 2.50 8.00
2.26E+05 0.50 2.50 8.00
1.14E+05 0.64 2.50 8.00
4.23E+04 0.35 2.50 8.00 10000 1000
1.78E+04 0.37 2.50 8.00
3.90E+03 0.35 2.50 8.00
1.02E+03 1.41 2.50 8.00
5.60E+02 0.93 2.50 8.00
4.21 E+02 1.49 2.50 8.00
3.52E+02 0.66 2.50 8.00
2.43E+05 0.61 2.50 8.00
8.86E+04 0.56 2.50 8.00
3.97E+04 1.04 2.50 8.00 10000 1000
1.50E+04 0.61 2.50 8.00
3.22E+03 0.15 2.50 8.00
1.02E+03 0.45 2.50 8.00
5.71 E+02 1.47 2.50 8.00
4.27E+02 0.49 2.50 8.00
3.50E+02 0.37 2.50 8.00
1.25E+00 2.07 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.05E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.32E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.06E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 1 2:33 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
12/14/11 12:48 PM EPA Interlab L06 1314 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-287
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Sr JaFS-L06-1314-T01-A 1 9.34E+03
Sr JaFS-L06-1314-T02-A 1 1.28E+03
Sr JaFS-L06-1314-T03-A 1 4.66E+02
Sr JaFS-L06-1314-T04-A 1 4.61E+02
Sr JaFS-L06-1314-T05-A 1 5.15E+02
Sr JaFS-L06-1314-T06-A 1 4.23E+02
Sr JaFS-L06-1314-T07-A 1 3.46E+02
Sr JaFS-L06-1314-T08-A 1 2.73E+02
Sr JaFS-L06-1314-T09-A 1 2.64E+02
Sr JaFS-L06-1314-T01-B 1 1.04E+04
Sr JaFS-L06-1314-T02-B 1 1.24E+03
Sr JaFS-L06-1314-T03-B 1 4.55E+02
Sr JaFS-L06-1314-T04-B 1 4.85E+02
Sr JaFS-L06-1314-T05-B 1 5.24E+02
Sr JaFS-L06-1314-T06-B 1 4.38E+02
Sr JaFS-L06-1314-T07-B 1 3.48E+02
Sr JaFS-L06-1314-T08-B 1 2.76E+02
Sr JaFS-L06-1314-T09-B 1 2.51E+02
Sr JaFS-L06-1314-T01-C 1 1.21E+04
Sr JaFS-L06-1314-T02-C 1 1.38E+03
Sr JaFS-L06-1314-T03-C 1 4.31E+02
Sr JaFS-L06-1314-T04-C 1 4.72E+02
Sr JaFS-L06-1314-T05-C 1 5.04E+02
Sr JaFS-L06-1314-T06-C 1 4.23E+02
Sr JaFS-L06-1314-T07-C 1 3.34E+02
Sr JaFS-L06-1314-T08-C 1 2.63E+02
Sr JaFS-L06-1314-T09-C 1 2.24E+02
Sr JaFS-L06-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.34E+03 1.40 1.00 3.18
1.28E+03 1.79 1.00 3.18
4.66E+02 0.18 1.00 3.18 10000 1000
4.61E+02 7.36 1.00 3.18
5.15E+02 1.68 1.00 3.18
4.23E+02 1.27 1.00 3.18
3.46E+02 2.77 1.00 3.18
2.73E+02 0.89 1.00 3.18
2.64E+02 1.39 1.00 3.18
1.04E+04 1.30 1.00 3.18
1.24E+03 1.24 1.00 3.18
4.55E+02 1.64 1.00 3.18 10000 1000
4.85E+02 1.85 1.00 3.18
5.24E+02 1.08 1.00 3.18
4.38E+02 1.89 1.00 3.18
3.48E+02 1.51 1.00 3.18
2.76E+02 1.82 1.00 3.18
2.51E+02 1.26 1.00 3.18
1.21E+04 1.35 1.00 3.18
1.38E+03 0.77 1.00 3.18
4.31E+02 1.01 1.00 3.18 10000 1000
4.72E+02 1.82 1.00 3.18
5.04E+02 1.19 1.00 3.18
4.23E+02 0.69 1.00 3.18
3.34E+02 1.04 1.00 3.18
2.63E+02 1.68 1.00 3.18
2.24E+02 0.68 1.00 3.18
5.00E-01 17.94 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.42E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.37E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.34E+03 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 1 2:33 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
1 2/1 4/1 1 1 2:48 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-288
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
S JaFS-L06-1314-T01-A 1 5.63E+05
S JaFS-L06-1314-T02-A 1 6.75E+04
S JaFS-L06-1314-T03-A 1 6.07E+03
S JaFS-L06-1314-T04-A 1 3.87E+03
S JaFS-L06-1314-T05-A 1 4.19E+03
S JaFS-L06-1314-T06-A 1 3.24E+03
S JaFS-L06-1314-T07-A 1 2.70E+03
S JaFS-L06-1314-T08-A 1 1.90E+03
S JaFS-L06-1314-T09-A 1 1.93E+03
S JaFS-L06-1314-T01-B 1 6.24E+05
S JaFS-L06-1314-T02-B 1 6.68E+04
S JaFS-L06-1314-T03-B 1 6.18E+03
S JaFS-L06-1314-T04-B 1 5.10E+03
S JaFS-L06-1314-T05-B 1 4.29E+03
S JaFS-L06-1314-T06-B 1 3.42E+03
S JaFS-L06-1314-T07-B 1 2.64E+03
S JaFS-L06-1314-T08-B 1 1.97E+03
S JaFS-L06-1314-T09-B 1 1.88E+03
S JaFS-L06-1314-T01-C 1 7.10E+05
S JaFS-L06-1314-T02-C 1 6.52E+04
S JaFS-L06-1314-T03-C 1 5.55E+03
S JaFS-L06-1314-T04-C 1 4.80E+03
S JaFS-L06-1314-T05-C 1 4.28E+03
S JaFS-L06-1314-T06-C 1 3.37E+03
S JaFS-L06-1314-T07-C 1 2.61E+03
S JaFS-L06-1314-T08-C 1 1.96E+03
S JaFS-L06-1314-T09-C 1 1.39E+03
S JaFS-L06-1314-B01-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.63E+05 0.26 6.80 21.60
6.75E+04 0.31 6.80 21.60
6.07E+03 0.67 6.80 21.60 10000 1000
3.87E+03 0.86 6.80 21.60
4.19E+03 1.97 6.80 21.60
3.24E+03 1.26 6.80 21.60
2.70E+03 2.83 6.80 21.60
1.90E+03 0.37 6.80 21.60
1.93E+03 0.96 6.80 21.60
6.24E+05 0.88 6.80 21.60
6.68E+04 0.38 6.80 21.60
6.18E+03 1.33 6.80 21.60 10000 1000
5.10E+03 1.53 6.80 21.60
4.29E+03 2.18 6.80 21.60
3.42E+03 1.75 6.80 21.60
2.64E+03 0.93 6.80 21.60
1.97E+03 2.23 6.80 21.60
1.88E+03 1.19 6.80 21.60
7.10E+05 3.19 6.80 21.60
6.52E+04 1.31 6.80 21.60
5.55E+03 1.44 6.80 21.60 10000 1000
4.80E+03 1.75 6.80 21.60
4.28E+03 0.82 6.80 21.60
3.37E+03 1.00 6.80 21.60
2.61 E+03 0.45 6.80 21.60
1.96E+03 2.15 6.80 21.60
1.39E+03 2.97 6.80 21.60
3.40E+00 18.25 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.98E+03 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.09E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.49E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 12:33 PM EPA Interlab L06 1314 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
12/14/11 12:48 PM EPA Interlab L06 1314 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-289
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Tl JaFS-L06-1314-T01-A 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T02-A 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T03-A 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T04-A 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T05-A 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T06-A 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T07-A 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T08-A 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T09-A 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T01-B 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T02-B 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T03-B 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T04-B 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T05-B 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T06-B 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T07-B 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T08-B 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T09-B 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T01-C 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T02-C 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T03-C 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T04-C 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T05-C 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T06-C 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T07-C 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T08-C 1 2.30E+00 U1/2
Tl JaFS-L06-1314-T09-C 1 2.30E+00 U1/2
Tl JaFS-L06-1314-B01-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 45.78 4.60 14.60
2.30E+00 25.31 4.60 14.60
2.30E+00 4.83 4.60 14.60 10000 1000
2.30E+00 15.49 4.60 14.60
2.30E+00 26.38 4.60 14.60
2.30E+00 22.42 4.60 14.60
2.30E+00 43.38 4.60 14.60
2.30E+00 36.94 4.60 14.60
2.30E+00 14.81 4.60 14.60
2.30E+00 30.27 4.60 14.60
2.30E+00 14.83 4.60 14.60
2.30E+00 55.91 4.60 14.60 10000 1000
2.30E+00 45.46 4.60 14.60
2.30E+00 23.04 4.60 14.60
2.30E+00 29.31 4.60 14.60
2.30E+00 38.97 4.60 14.60
2.30E+00 5.83 4.60 14.60
2.30E+00 43.55 4.60 14.60
2.30E+00 73.70 4.60 14.60
2.30E+00 37.63 4.60 14.60
2.30E+00 52.88 4.60 14.60 10000 1000
2.30E+00 77.87 4.60 14.60
2.30E+00 14.14 4.60 14.60
2.30E+00 43.99 4.60 14.60
2.30E+00 32.28 4.60 14.60
2.30E+00 44.29 4.60 14.60
2.30E+00 26.19 4.60 14.60
2.30E+00 52.84 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.32E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.38E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.03E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 12:33 PM EPA Interlab L06 1314 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
12/14/11 12:48 PM EPA Interlab L06 1314 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-290
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Ti JaFS-L06-1314-T01-A 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T02-A 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T03-A 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T04-A 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T05-A 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T06-A 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T07-A 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T08-A 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T09-A 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T01-B 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T02-B 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T03-B 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T04-B 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T05-B 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T06-B 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T07-B 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T08-B 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T09-B 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T01-C 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T02-C 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T03-C 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T04-C 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T05-C 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T06-C 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T07-C 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T08-C 1 1.00E+00 U1/2
Ti JaFS-L06-1314-T09-C 1 1.00E+00 U1/2
Ti JaFS-L06-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 39.93 2.00 6.40
1.00E+00 6.40 2.00 6.40
1.00E+00 6.54 2.00 6.40 10000 1000
1.00E+00 15.80 2.00 6.40
1.00E+00 17.00 2.00 6.40
1.00E+00 17.90 2.00 6.40
1.00E+00 16.94 2.00 6.40
1.00E+00 24.37 2.00 6.40
1.00E+00 7.41 2.00 6.40
1.00E+00 32.31 2.00 6.40
1.00E+00 26.36 2.00 6.40
1.00E+00 4.36 2.00 6.40 10000 1000
1.00E+00 1.24 2.00 6.40
1.00E+00 32.75 2.00 6.40
1.00E+00 24.83 2.00 6.40
1.00E+00 15.19 2.00 6.40
1.00E+00 4.01 2.00 6.40
1.00E+00 6.47 2.00 6.40
1.00E+00 18.17 2.00 6.40
1.00E+00 33.31 2.00 6.40
1.00E+00 35.44 2.00 6.40 10000 1000
1.00E+00 12.12 2.00 6.40
1.00E+00 14.46 2.00 6.40
1.00E+00 38.74 2.00 6.40
1.00E+00 26.67 2.00 6.40
1.00E+00 5.74 2.00 6.40
1.00E+00 6.55 2.00 6.40
1.00E+00 11.79 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.22E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.34E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.02E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 1 2:33 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
1 2/1 4/1 1 1 2:48 PM EPA Interlab L06 1 31 4 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-291
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L I
V JaFS-L06-1314-T01-A 1 2.14E+01
V JaFS-L06-1314-T02-A 1 5.73E+00
V JaFS-L06-1314-T03-A 1 7.50E-01 U1/2
V JaFS-L06-1314-T04-A 1 7.50E-01 U1/2
V JaFS-L06-1314-T05-A 1 7.50E-01 U1/2
V JaFS-L06-1314-T06-A 1 7.50E-01 U1/2
V JaFS-L06-1314-T07-A 1 7.50E-01 U1/2
V JaFS-L06-1314-T08-A 1 7.50E-01 U1/2
V JaFS-L06-1314-T09-A 1 7.50E-01 U1/2
V JaFS-L06-1314-T01-B 1 2.41E+01
V JaFS-L06-1314-T02-B 1 6.30E+00
V JaFS-L06-1314-T03-B 1 7.50E-01 U1/2
V JaFS-L06-1314-T04-B 1 7.50E-01 U1/2
V JaFS-L06-1314-T05-B 1 7.50E-01 U1/2
V JaFS-L06-1314-T06-B 1 7.50E-01 U1/2
V JaFS-L06-1314-T07-B 1 7.50E-01 U1/2
V JaFS-L06-1314-T08-B 1 7.50E-01 U1/2
V JaFS-L06-1314-T09-B 1 7.50E-01 U1/2
V JaFS-L06-1314-T01-C 1 2.68E+01
V JaFS-L06-1314-T02-C 1 3.27E+00 E
V JaFS-L06-1314-T03-C 1 7.50E-01 U1/2
V JaFS-L06-1314-T04-C 1 7.50E-01 U1/2
V JaFS-L06-1314-T05-C 1 7.50E-01 U1/2
V JaFS-L06-1314-T06-C 1 1.52E+00 E
V JaFS-L06-1314-T07-C 1 7.50E-01 U1/2
V JaFS-L06-1314-T08-C 1 7.50E-01 U1/2
V JaFS-L06-1314-T09-C 1 7.50E-01 U1/2
V JaFS-L06-1314-B01-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.14E+01 3.20 1.50 4.77
5.73E+00 8.85 1.50 4.77
7.50E-01 26.23 1.50 4.77 10000 1000
7.50E-01 3.97 1.50 4.77
7.50E-01 26.55 1.50 4.77
7.50E-01 23.92 1.50 4.77
7.50E-01 23.85 1.50 4.77
7.50E-01 44.07 1.50 4.77
7.50E-01 16.06 1.50 4.77
2.41 E+01 2.91 1.50 4.77
6.30E+00 6.12 1.50 4.77
7.50E-01 22.21 1.50 4.77 10000 1000
7.50E-01 12.96 1.50 4.77
7.50E-01 39.41 1.50 4.77
7.50E-01 18.59 1.50 4.77
7.50E-01 23.90 1.50 4.77
7.50E-01 34.52 1.50 4.77
7.50E-01 2.54 1.50 4.77
2.68E+01 1.99 1.50 4.77
3.27E+00 11.82 1.50 4.77
7.50E-01 11.97 1.50 4.77 10000 1000
7.50E-01 28.08 1.50 4.77
7.50E-01 36.87 1.50 4.77
1.52E+00 16.21 1.50 4.77
7.50E-01 14.65 1.50 4.77
7.50E-01 30.01 1.50 4.77
7.50E-01 43.36 1.50 4.77
7.50E-01 54.24 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.63E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.72E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.34E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
12/14/11 12:10 PM EPA Interlab L06 1314 JaFS
12/14/11 12:12 PM EPA Interlab L06 1314 JaFS
12/14/11 12:13 PM EPA Interlab L06 1314 JaFS
12/14/11 12:15 PM EPA Interlab L06 1314 JaFS
12/14/11 12:17 PM EPA Interlab L06 1314 JaFS
12/14/11 12:18 PM EPA Interlab L06 1314 JaFS
12/14/11 12:20 PM EPA Interlab L06 1314 JaFS
12/14/11 12:22 PM EPA Interlab L06 1314 JaFS
12/14/11 12:23 PM EPA Interlab L06 1314 JaFS
12/14/11 12:30 PM EPA Interlab L06 1314 JaFS
12/14/11 12:31 PM EPA Interlab L06 1314 JaFS
12/14/11 12:33 PM EPA Interlab L06 1314 JaFS
12/14/11 12:35 PM EPA Interlab L06 1314 JaFS
12/14/11 12:36 PM EPA Interlab L06 1314 JaFS
12/14/11 12:38 PM EPA Interlab L06 1314 JaFS
12/14/11 12:40 PM EPA Interlab L06 1314 JaFS
12/14/11 12:41 PM EPA Interlab L06 1314 JaFS
12/14/11 12:43 PM EPA Interlab L06 1314 JaFS
12/14/11 12:45 PM EPA Interlab L06 1314 JaFS
12/14/11 12:46 PM EPA Interlab L06 1314 JaFS
12/14/11 12:48 PM EPA Interlab L06 1314 JaFS
12/14/11 12:50 PM EPA Interlab L06 1314 JaFS
12/14/11 12:51 PM EPA Interlab L06 1314 JaFS
12/14/11 12:53 PM EPA Interlab L06 1314 JaFS
12/14/11 12:55 PM EPA Interlab L06 1314 JaFS
12/14/11 12:56 PM EPA Interlab L06 1314 JaFS
12/14/11 12:58 PM EPA Interlab L06 1314 JaFS
12/14/11 12:08 PM EPA Interlab L06 1314 JaFS
1-292
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Zn JaFS-L06-1314-T01-A 1 1.25E+03
Zn JaFS-L06-1314-T02-A 1 5.73E+02
Zn JaFS-L06-1314-T03-A 1 2.18E+02
Zn JaFS-L06-1314-T04-A 1 1.23E+02
Zn JaFS-L06-1314-T05-A 1 7.17E+01
Zn JaFS-L06-1314-T06-A 1 5.62E+01
Zn JaFS-L06-1314-T07-A 1 4.50E+01
Zn JaFS-L06-1314-T08-A 1 3.26E+01
Zn JaFS-L06-1314-T09-A 1 2.56E+01
Zn JaFS-L06-1314-T01-B 1 1.22E+03
Zn JaFS-L06-1314-T02-B 1 5.81E+02
Zn JaFS-L06-1314-T03-B 1 2.33E+02
Zn JaFS-L06-1314-T04-B 1 1.27E+02
Zn JaFS-L06-1314-T05-B 1 7.40E+01
Zn JaFS-L06-1314-T06-B 1 5.30E+01
Zn JaFS-L06-1314-T07-B 1 4.34E+01
Zn JaFS-L06-1314-T08-B 1 2.79E+01
Zn JaFS-L06-1314-T09-B 1 2.13E+01
Zn JaFS-L06-1314-T01-C 1 1.44E+03
Zn JaFS-L06-1314-T02-C 1 6.11E+02
Zn JaFS-L06-1314-T03-C 1 2.24E+02
Zn JaFS-L06-1314-T04-C 1 1.31E+02
Zn JaFS-L06-1314-T05-C 1 7.80E+01
Zn JaFS-L06-1314-T06-C 1 5.31E+01
Zn JaFS-L06-1314-T07-C 1 4.74E+01
Zn JaFS-L06-1314-T08-C 1 2.49E+01
Zn JaFS-L06-1314-T09-C 1 2.26E+01
Zn JaFS-L06-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.25E+03 1.61 1.00 3.18
5.73E+02 1.62 1.00 3.18
2.18E+02 0.43 1.00 3.18 10000 1000
1.23E+02 0.87 1.00 3.18
7.17E+01 1.54 1.00 3.18
5.62E+01 2.04 1.00 3.18
4.50E+01 2.10 1.00 3.18
3.26E+01 0.98 1.00 3.18
2.56E+01 1.39 1.00 3.18
1.22E+03 0.89 1.00 3.18
5.81E+02 0.68 1.00 3.18
2.33E+02 1.17 1.00 3.18 10000 1000
1.27E+02 1.61 1.00 3.18
7.40E+01 1.38 1.00 3.18
5.30E+01 2.12 1.00 3.18
4.34E+01 1.81 1.00 3.18
2.79E+01 1.24 1.00 3.18
2.13E+01 1.32 1.00 3.18
1.44E+03 1.97 1.00 3.18
6.11E+02 1.26 1.00 3.18
2.24E+02 1.20 1.00 3.18 10000 1000
1.31E+02 1.55 1.00 3.18
7.80E+01 0.85 1.00 3.18
5.31E+01 0.59 1.00 3.18
4.74E+01 0.37 1.00 3.18
2.49E+01 2.74 1.00 3.18
2.26E+01 0.25 1.00 3.18
5.00E-01 1.40 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.17E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.13E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/12 10:18 AM EPA Interlab L06 1314 JaFS
3/7/12 10:20 AM EPA Interlab L06 1314 JaFS
3/7/12 10:22 AM EPA Interlab L06 1314 JaFS
3/7/12 10:23 AM EPA Interlab L06 1314 JaFS
3/7/12 10:25 AM EPA Interlab L06 1314 JaFS
3/7/12 10:26 AM EPA Interlab L06 1314 JaFS
3/7/12 10:28 AM EPA Interlab L06 1314 JaFS
3/7/12 10:30 AM EPA Interlab L06 1314 JaFS
3/7/12 10:31 AM EPA Interlab L06 1314 JaFS
3/7/12 10:33 AM EPA Interlab L06 1314 JaFS
3/7/12 10:35 AM EPA Interlab L06 1314 JaFS
3/7/12 10:36 AM EPA Interlab L06 1314 JaFS
3/7/12 10:38 AM EPA Interlab L06 1314 JaFS
3/7/12 10:40 AM EPA Interlab L06 1314 JaFS
3/7/12 10:41 AM EPA Interlab L06 1314 JaFS
3/7/12 10:43 AM EPA Interlab L06 1314 JaFS
3/7/12 10:44 AM EPA Interlab L06 1314 JaFS
3/7/12 10:46 AM EPA Interlab L06 1314 JaFS
3/7/12 10:51 AM EPA Interlab L06 1314 JaFS
3/7/12 10:53 AM EPA Interlab L06 1314 JaFS
3/7/12 10:54 AM EPA Interlab L06 1314 JaFS
3/7/12 10:56 AM EPA Interlab L06 1314 JaFS
3/7/12 10:57 AM EPA Interlab L06 1314 JaFS
3/7/12 10:59 AM EPA Interlab L06 1314 JaFS
3/7/12 11:01 AM EPA Interlab L06 1314 JaFS
3/7/12 11:02 AM EPA Interlab L06 1314 JaFS
3/7/12 11:04 AM EPA Interlab L06 1314 JaFS
3/7/12 10:17 AM EPA Interlab L06 1314 JaFS
1-293
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1314:
Dilution Sample
Element Sample ID Factor Cone. Qualifier
I I M9/L I
Al JaFS-L07-1314-T01-A 1 5.70E+01
Al JaFS-L07-1314-T02-A 1 5.49E+01
Al JaFS-L07-1314-T03-A 1 1.89E+01
Al JaFS-L07-1314-T04-A 1 1.95E+01
Al JaFS-L07-1314-T05-A 1 1.53E+01
Al JaFS-L07-1314-T06-A 1 1.60E+01
Al JaFS-L07-1314-T07-A 1 1.65E+01
Al JaFS-L07-1314-T08-A 1 1.75E+01
Al JaFS-L07-1314-T09-A 1 1.86E+01
Al JaFS-L07-1314-T01-B 1 6.12E+01
Al JaFS-L07-1314-T02-B 1 4.88E+01
Al JaFS-L07-1314-T03-B 1 1.68E+01
Al JaFS-L07-1314-T04-B 1 1.65E+01
Al JaFS-L07-1314-T05-B 1 1.54E+01
Al JaFS-L07-1314-T06-B 1 1.48E+01
Al JaFS-L07-1314-T07-B 1 1.57E+01
Al JaFS-L07-1314-T08-B 1 1.74E+01
Al JaFS-L07-1314-T09-B 1 1.85E+01
Al JaFS-L07-1314-T01-C 1 6.50E+01
Al JaFS-L07-1314-T02-C 1 4.84E+01
Al JaFS-L07-1314-T03-C 1 2.02E+01
Al JaFS-L07-1314-T04-C 1 1.99E+01
Al JaFS-L07-1314-T05-C 1 1.56E+01
Al JaFS-L07-1314-T06-C 1 1.51E+01
Al JaFS-L07-1314-T07-C 1 1.67E+01
Al JaFS-L07-1314-T08-C 1 1.66E+01
Al JaFS-L07-1314-T09-C 1 1.43E+01
Al JaFS-L07-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.70E+01 0.47 1.00 3.18
5.49E+01 3.64 1.00 3.18
1.89E+01 2.65 1.00 3.18 10000 1000
1.95E+01 0.94 1.00 3.18
1.53E+01 5.56 1.00 3.18
1.60E+01 2.02 1.00 3.18
1.65E+01 1.07 1.00 3.18
1.75E+01 2.25 1.00 3.18
1.86E+01 2.83 1.00 3.18
6.12E+01 3.24 1.00 3.18
4.88E+01 2.54 1.00 3.18
1.68E+01 3.30 1.00 3.18 10000 1000
1.65E+01 5.62 1.00 3.18
1.54E+01 3.98 1.00 3.18
1.48E+01 2.11 1.00 3.18
1.57E+01 1.23 1.00 3.18
1.74E+01 0.32 1.00 3.18
1.85E+01 1.71 1.00 3.18
6.50E+01 0.92 1.00 3.18
4.84E+01 1.92 1.00 3.18
2.02E+01 2.18 1.00 3.18 10000 1000
1.99E+01 2.27 1.00 3.18
1.56E+01 1.79 1.00 3.18
1.51E+01 1.22 1.00 3.18
1.67E+01 3.29 1.00 3.18
1.66E+01 1.23 1.00 3.18
1.43E+01 4.47 1.00 3.18
5.00E-01 2.20 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.05E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-294
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
Sb JaFS-L07-1314-T01-A 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T02-A 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T03-A 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T04-A 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T05-A 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T06-A 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T07-A 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T08-A 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T09-A 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T01-B 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T02-B 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T03-B 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T04-B 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T05-B 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T06-B 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T07-B 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T08-B 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T09-B 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T01-C 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T02-C 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T03-C 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T04-C 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T05-C 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T06-C 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T07-C 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T08-C 1 3.75E+00 U1/2
Sb JaFS-L07-1314-T09-C 1 3.75E+00 U1/2
Sb JaFS-L07-1314-B01-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.75E+00 25.14 7.50 23.90
3.75E+00 59.36 7.50 23.90
3.75E+00 46.87 7.50 23.90 10000 1000
3.75E+00 84.02 7.50 23.90
3.75E+00 58.45 7.50 23.90
3.75E+00 51.65 7.50 23.90
3.75E+00 29.38 7.50 23.90
3.75E+00 15.52 7.50 23.90
3.75E+00 45.02 7.50 23.90
3.75E+00 37.62 7.50 23.90
3.75E+00 81.61 7.50 23.90
3.75E+00 85.13 7.50 23.90 10000 1000
3.75E+00 6.61 7.50 23.90
3.75E+00 41.03 7.50 23.90
3.75E+00 27.14 7.50 23.90
3.75E+00 19.55 7.50 23.90
3.75E+00 62.29 7.50 23.90
3.75E+00 56.31 7.50 23.90
3.75E+00 73.86 7.50 23.90
3.75E+00 73.73 7.50 23.90
3.75E+00 45.63 7.50 23.90 10000 1000
3.75E+00 39.29 7.50 23.90
3.75E+00 11.55 7.50 23.90
3.75E+00 53.44 7.50 23.90
3.75E+00 94.53 7.50 23.90
3.75E+00 54.85 7.50 23.90
3.75E+00 60.37 7.50 23.90
3.75E+00 38.52 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.70E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-295
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
As JaFS-L07-1314-T01-A 1 5.50E+00 U1/2
As JaFS-L07-1314-T02-A 1 5.50E+00 U1/2
As JaFS-L07-1314-T03-A 1 5.50E+00 U1/2
As JaFS-L07-1314-T04-A 1 5.50E+00 U1/2
As JaFS-L07-1314-T05-A 1 5.50E+00 U1/2
As JaFS-L07-1314-T06-A 1 5.50E+00 U1/2
As JaFS-L07-1314-T07-A 1 5.50E+00 U1/2
As JaFS-L07-1314-T08-A 1 5.50E+00 U1/2
As JaFS-L07-1314-T09-A 1 5.50E+00 U1/2
As JaFS-L07-1314-T01-B 1 5.50E+00 U1/2
As JaFS-L07-1314-T02-B 1 5.50E+00 U1/2
As JaFS-L07-1314-T03-B 1 5.50E+00 U1/2
As JaFS-L07-1314-T04-B 1 5.50E+00 U1/2
As JaFS-L07-1314-T05-B 1 5.50E+00 U1/2
As JaFS-L07-1314-T06-B 1 5.50E+00 U1/2
As JaFS-L07-1314-T07-B 1 5.50E+00 U1/2
As JaFS-L07-1314-T08-B 1 5.50E+00 U1/2
As JaFS-L07-1314-T09-B 1 5.50E+00 U1/2
As JaFS-L07-1314-T01-C 1 5.50E+00 U1/2
As JaFS-L07-1314-T02-C 1 5.50E+00 U1/2
As JaFS-L07-1314-T03-C 1 5.50E+00 U1/2
As JaFS-L07-1314-T04-C 1 5.50E+00 U1/2
As JaFS-L07-1314-T05-C 1 5.50E+00 U1/2
As JaFS-L07-1314-T06-C 1 5.50E+00 U1/2
As JaFS-L07-1314-T07-C 1 5.50E+00 U1/2
As JaFS-L07-1314-T08-C 1 5.50E+00 U1/2
As JaFS-L07-1314-T09-C 1 5.50E+00 U1/2
As JaFS-L07-1314-B01-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.50E+00 28.54 11.00 35.00
5.50E+00 23.84 11.00 35.00
5.50E+00 56.32 11.00 35.00 10000 1000
5.50E+00 13.08 11.00 35.00
5.50E+00 27.56 11.00 35.00
5.50E+00 9.20 11.00 35.00
5.50E+00 42.73 11.00 35.00
5.50E+00 4.88 11.00 35.00
5.50E+00 35.42 11.00 35.00
5.50E+00 33.31 11.00 35.00
5.50E+00 29.21 11.00 35.00
5.50E+00 27.39 11.00 35.00 10000 1000
5.50E+00 18.54 11.00 35.00
5.50E+00 26.06 11.00 35.00
5.50E+00 17.99 11.00 35.00
5.50E+00 25.63 11.00 35.00
5.50E+00 22.23 11.00 35.00
5.50E+00 12.38 11.00 35.00
5.50E+00 34.81 11.00 35.00
5.50E+00 16.14 11.00 35.00
5.50E+00 33.49 11.00 35.00 10000 1000
5.50E+00 32.68 11.00 35.00
5.50E+00 30.60 11.00 35.00
5.50E+00 42.97 11.00 35.00
5.50E+00 45.64 11.00 35.00
5.50E+00 10.87 11.00 35.00
5.50E+00 42.72 11.00 35.00
5.50E+00 48.13 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.84E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-296
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
B JaFS-L07-1314-T01-A 1 1.06E+05
B JaFS-L07-1314-T02-A 1 8.87E+04
B JaFS-L07-1314-T03-A 1 4.60E+04
B JaFS-L07-1314-T04-A 1 1.46E+04
B JaFS-L07-1314-T05-A 1 7.68E+03
B JaFS-L07-1314-T06-A 1 3.25E+03
B JaFS-L07-1314-T07-A 1 1.90E+03
B JaFS-L07-1314-T08-A 1 1.20E+03
B JaFS-L07-1314-T09-A 1 7.72E+02
B JaFS-L07-1314-T01-B 1 1.34E+05
B JaFS-L07-1314-T02-B 1 8.80E+04
B JaFS-L07-1314-T03-B 1 3.40E+04
B JaFS-L07-1314-T04-B 1 1.28E+04
B JaFS-L07-1314-T05-B 1 7.23E+03
B JaFS-L07-1314-T06-B 1 3.08E+03
B JaFS-L07-1314-T07-B 1 1.85E+03
B JaFS-L07-1314-T08-B 1 1.14E+03
B JaFS-L07-1314-T09-B 1 8.30E+02
B JaFS-L07-1314-T01-C 1 1.34E+05
B JaFS-L07-1314-T02-C 1 9.18E+04
B JaFS-L07-1314-T03-C 1 3.62E+04
B JaFS-L07-1314-T04-C 1 1.24E+04
B JaFS-L07-1314-T05-C 1 7.02E+03
B JaFS-L07-1314-T06-C 1 3.13E+03
B JaFS-L07-1314-T07-C 1 1.90E+03
B JaFS-L07-1314-T08-C 1 1.19E+03
B JaFS-L07-1314-T09-C 1 7.52E+02
B JaFS-L07-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.06E+05 0.65 1.00 3.18
8.87E+04 1.92 1.00 3.18
4.60E+04 0.79 1.00 3.18 10000 1000
1.46E+04 1.02 1.00 3.18
7.68E+03 1.52 1.00 3.18
3.25E+03 1.75 1.00 3.18
1.90E+03 1.19 1.00 3.18
1.20E+03 0.95 1.00 3.18
7.72E+02 1.68 1.00 3.18
1.34E+05 1.45 1.00 3.18
8.80E+04 1.60 1.00 3.18
3.40E+04 0.21 1.00 3.18 10000 1000
1.28E+04 3.71 1.00 3.18
7.23E+03 3.23 1.00 3.18
3.08E+03 2.34 1.00 3.18
1.85E+03 0.92 1.00 3.18
1.14E+03 3.38 1.00 3.18
8.30E+02 0.87 1.00 3.18
1.34E+05 0.61 1.00 3.18
9.18E+04 2.49 1.00 3.18
3.62E+04 1.39 1.00 3.18 10000 1000
1.24E+04 1.74 1.00 3.18
7.02E+03 0.44 1.00 3.18
3.13E+03 2.66 1.00 3.18
1.90E+03 1.28 1.00 3.18
1.19E+03 0.93 1.00 3.18
7.52E+02 0.40 1.00 3.18
5.00E-01 8.36 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.68E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.48E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.71E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-297
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Ba JaFS-L07-1314-T01-A 1 1.35E+02
Ba JaFS-L07-1314-T02-A 1 7.59E+01
Ba JaFS-L07-1314-T03-A 1 4.44E+01
Ba JaFS-L07-1314-T04-A 1 2.69E+01
Ba JaFS-L07-1314-T05-A 1 2.64E+01
Ba JaFS-L07-1314-T06-A 1 2.32E+01
Ba JaFS-L07-1314-T07-A 1 2.11E+01
Ba JaFS-L07-1314-T08-A 1 1.46E+01
Ba JaFS-L07-1314-T09-A 1 1.10E+01
Ba JaFS-L07-1314-T01-B 1 1.42E+02
Ba JaFS-L07-1314-T02-B 1 8.02E+01
Ba JaFS-L07-1314-T03-B 1 3.18E+01
Ba JaFS-L07-1314-T04-B 1 2.66E+01
Ba JaFS-L07-1314-T05-B 1 2.77E+01
Ba JaFS-L07-1314-T06-B 1 2.15E+01
Ba JaFS-L07-1314-T07-B 1 2.11E+01
Ba JaFS-L07-1314-T08-B 1 1.44E+01
Ba JaFS-L07-1314-T09-B 1 1.20E+01
Ba JaFS-L07-1314-T01-C 1 1.33E+02
Ba JaFS-L07-1314-T02-C 1 8.37E+01
Ba JaFS-L07-1314-T03-C 1 2.75E+01
Ba JaFS-L07-1314-T04-C 1 2.48E+01
Ba JaFS-L07-1314-T05-C 1 2.65E+01
Ba JaFS-L07-1314-T06-C 1 2.29E+01
Ba JaFS-L07-1314-T07-C 1 2.25E+01
Ba JaFS-L07-1314-T08-C 1 1.47E+01
Ba JaFS-L07-1314-T09-C 1 1.12E+01
Ba JaFS-L07-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.35E+02 1.29 1.00 3.18
7.59E+01 1.52 1.00 3.18
4.44E+01 1.54 1.00 3.18 10000 1000
2.69E+01 1.08 1.00 3.18
2.64E+01 1.16 1.00 3.18
2.32E+01 1.34 1.00 3.18
2.11E+01 2.91 1.00 3.18
1.46E+01 1.92 1.00 3.18
1.10E+01 1.45 1.00 3.18
1.42E+02 0.85 1.00 3.18
8.02E+01 0.39 1.00 3.18
3.18E+01 1.77 1.00 3.18 10000 1000
2.66E+01 3.62 1.00 3.18
2.77E+01 2.79 1.00 3.18
2.15E+01 0.82 1.00 3.18
2.11E+01 0.92 1.00 3.18
1.44E+01 2.77 1.00 3.18
1.20E+01 0.80 1.00 3.18
1.33E+02 0.98 1.00 3.18
8.37E+01 1.78 1.00 3.18
2.75E+01 1.58 1.00 3.18 10000 1000
2.48E+01 0.77 1.00 3.18
2.65E+01 0.95 1.00 3.18
2.29E+01 0.79 1.00 3.18
2.25E+01 1.25 1.00 3.18
1.47E+01 1.54 1.00 3.18
1.12E+01 1.48 1.00 3.18
5.00E-01 16.69 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.07E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-298
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
Be JaFS-L07-1314-T01-A 1 9.50E-01 U1/2
Be JaFS-L07-1314-T02-A 1 9.50E-01 U1/2
Be JaFS-L07-1314-T03-A 1 9.50E-01 U1/2
Be JaFS-L07-1314-T04-A 1 9.50E-01 U1/2
Be JaFS-L07-1314-T05-A 1 9.50E-01 U1/2
Be JaFS-L07-1314-T06-A 1 9.50E-01 U1/2
Be JaFS-L07-1314-T07-A 1 9.50E-01 U1/2
Be JaFS-L07-1314-T08-A 1 9.50E-01 U1/2
Be JaFS-L07-1314-T09-A 1 9.50E-01 U1/2
Be JaFS-L07-1314-T01-B 1 9.50E-01 U1/2
Be JaFS-L07-1314-T02-B 1 9.50E-01 U1/2
Be JaFS-L07-1314-T03-B 1 9.50E-01 U1/2
Be JaFS-L07-1314-T04-B 1 9.50E-01 U1/2
Be JaFS-L07-1314-T05-B 1 9.50E-01 U1/2
Be JaFS-L07-1314-T06-B 1 9.50E-01 U1/2
Be JaFS-L07-1314-T07-B 1 9.50E-01 U1/2
Be JaFS-L07-1314-T08-B 1 9.50E-01 U1/2
Be JaFS-L07-1314-T09-B 1 9.50E-01 U1/2
Be JaFS-L07-1314-T01-C 1 9.50E-01 U1/2
Be JaFS-L07-1314-T02-C 1 9.50E-01 U1/2
Be JaFS-L07-1314-T03-C 1 9.50E-01 U1/2
Be JaFS-L07-1314-T04-C 1 9.50E-01 U1/2
Be JaFS-L07-1314-T05-C 1 9.50E-01 U1/2
Be JaFS-L07-1314-T06-C 1 9.50E-01 U1/2
Be JaFS-L07-1314-T07-C 1 9.50E-01 U1/2
Be JaFS-L07-1314-T08-C 1 9.50E-01 U1/2
Be JaFS-L07-1314-T09-C 1 9.50E-01 U1/2
Be JaFS-L07-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 24.68 1.90 6.00
9.50E-01 32.83 1.90 6.00
9.50E-01 13.78 1.90 6.00 10000 1000
9.50E-01 64.96 1.90 6.00
9.50E-01 6.22 1.90 6.00
9.50E-01 38.15 1.90 6.00
9.50E-01 62.63 1.90 6.00
9.50E-01 38.93 1.90 6.00
9.50E-01 60.04 1.90 6.00
9.50E-01 38.25 1.90 6.00
9.50E-01 23.66 1.90 6.00
9.50E-01 48.12 1.90 6.00 10000 1000
9.50E-01 32.50 1.90 6.00
9.50E-01 48.88 1.90 6.00
9.50E-01 10.34 1.90 6.00
9.50E-01 39.38 1.90 6.00
9.50E-01 43.69 1.90 6.00
9.50E-01 53.25 1.90 6.00
9.50E-01 59.17 1.90 6.00
9.50E-01 60.20 1.90 6.00
9.50E-01 9.19 1.90 6.00 10000 1000
9.50E-01 63.68 1.90 6.00
9.50E-01 33.21 1.90 6.00
9.50E-01 53.98 1.90 6.00
9.50E-01 28.56 1.90 6.00
9.50E-01 54.65 1.90 6.00
9.50E-01 32.10 1.90 6.00
9.50E-01 17.61 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.06E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-299
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
Cd JaFS-L07-1314-T01-A 1 1.86E+01
Cd JaFS-L07-1314-T02-A 1 4.84E+00 E
Cd JaFS-L07-1314-T03-A 1 1.10E+00 U1/2
Cd JaFS-L07-1314-T04-A 1 1.10E+00 U1/2
Cd JaFS-L07-1314-T05-A 1 1.10E+00 U1/2
Cd JaFS-L07-1314-T06-A 1 1.10E+00 U1/2
Cd JaFS-L07-1314-T07-A 1 1.10E+00 U1/2
Cd JaFS-L07-1314-T08-A 1 1.10E+00 U1/2
Cd JaFS-L07-1314-T09-A 1 1.10E+00 U1/2
Cd JaFS-L07-1314-T01-B 1 1.65E+01
Cd JaFS-L07-1314-T02-B 1 5.93E+00 E
Cd JaFS-L07-1314-T03-B 1 1.10E+00 U1/2
Cd JaFS-L07-1314-T04-B 1 1.10E+00 U1/2
Cd JaFS-L07-1314-T05-B 1 1.10E+00 U1/2
Cd JaFS-L07-1314-T06-B 1 1.10E+00 U1/2
Cd JaFS-L07-1314-T07-B 1 1.10E+00 U1/2
Cd JaFS-L07-1314-T08-B 1 1.10E+00 U1/2
Cd JaFS-L07-1314-T09-B 1 1.10E+00 U1/2
Cd JaFS-L07-1314-T01-C 1 1.83E+01
Cd JaFS-L07-1314-T02-C 1 6.44E+00 E
Cd JaFS-L07-1314-T03-C 1 1.10E+00 U1/2
Cd JaFS-L07-1314-T04-C 1 1.10E+00 U1/2
Cd JaFS-L07-1314-T05-C 1 1.10E+00 U1/2
Cd JaFS-L07-1314-T06-C 1 1.10E+00 U1/2
Cd JaFS-L07-1314-T07-C 1 1.10E+00 U1/2
Cd JaFS-L07-1314-T08-C 1 1.10E+00 U1/2
Cd JaFS-L07-1314-T09-C 1 1.10E+00 U1/2
Cd JaFS-L07-1314-B01-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.86E+01 2.09 2.20 7.00
4.84E+00 1.49 2.20 7.00
1.10E+00 5.71 2.20 7.00 10000 1000
1.10E+00 12.61 2.20 7.00
1.10E+00 19.32 2.20 7.00
1.10E+00 7.51 2.20 7.00
1.10E+00 28.42 2.20 7.00
1.10E+00 25.80 2.20 7.00
1.10E+00 36.80 2.20 7.00
1.65E+01 0.82 2.20 7.00
5.93E+00 1.86 2.20 7.00
1.10E+00 11.04 2.20 7.00 10000 1000
1.10E+00 7.44 2.20 7.00
1.10E+00 13.86 2.20 7.00
1.10E+00 22.83 2.20 7.00
1.10E+00 19.68 2.20 7.00
1.10E+00 3.18 2.20 7.00
1.10E+00 13.23 2.20 7.00
1.83E+01 1.36 2.20 7.00
6.44E+00 2.69 2.20 7.00
1.10E+00 9.11 2.20 7.00 10000 1000
1.10E+00 5.83 2.20 7.00
1.10E+00 10.52 2.20 7.00
1.10E+00 11.97 2.20 7.00
1.10E+00 23.59 2.20 7.00
1.10E+00 20.22 2.20 7.00
1.10E+00 31.15 2.20 7.00
1.10E+00 34.46 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-300
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Ca JaFS-L07-1314-T01-A 1 2.96E+05
Ca JaFS-L07-1314-T02-A 1 3.58E+04
Ca JaFS-L07-1314-T03-A 1 2.03E+04
Ca JaFS-L07-1314-T04-A 1 1.64E+04
Ca JaFS-L07-1314-T05-A 1 1.53E+04
Ca JaFS-L07-1314-T06-A 1 1.31E+04
Ca JaFS-L07-1314-T07-A 1 1.24E+04
Ca JaFS-L07-1314-T08-A 1 1.08E+04
Ca JaFS-L07-1314-T09-A 1 1.02E+04
Ca JaFS-L07-1314-T01-B 1 3.12E+05
Ca JaFS-L07-1314-T02-B 1 4.21E+04
Ca JaFS-L07-1314-T03-B 1 2.21E+04
Ca JaFS-L07-1314-T04-B 1 1.65E+04
Ca JaFS-L07-1314-T05-B 1 1.64E+04
Ca JaFS-L07-1314-T06-B 1 1.29E+04
Ca JaFS-L07-1314-T07-B 1 1.18E+04
Ca JaFS-L07-1314-T08-B 1 1.04E+04
Ca JaFS-L07-1314-T09-B 1 1.06E+04
Ca JaFS-L07-1314-T01-C 1 3.22E+05
Ca JaFS-L07-1314-T02-C 1 3.86E+04
Ca JaFS-L07-1314-T03-C 1 2.09E+04
Ca JaFS-L07-1314-T04-C 1 1.52E+04
Ca JaFS-L07-1314-T05-C 1 1.53E+04
Ca JaFS-L07-1314-T06-C 1 1.30E+04
Ca JaFS-L07-1314-T07-C 1 1.20E+04
Ca JaFS-L07-1314-T08-C 1 1.06E+04
Ca JaFS-L07-1314-T09-C 1 1.01E+04
Ca JaFS-L07-1314-B01-A 1 1.30E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.96E+05 0.27 2.60 8.30
3.58E+04 1.74 2.60 8.30
2.03E+04 0.54 2.60 8.30 10000 1000
1.64E+04 0.70 2.60 8.30
1.53E+04 0.46 2.60 8.30
1.31E+04 0.94 2.60 8.30
1.24E+04 1.83 2.60 8.30
1.08E+04 0.96 2.60 8.30
1.02E+04 0.67 2.60 8.30
3.12E+05 1.48 2.60 8.30
4.21 E+04 0.69 2.60 8.30
2.21E+04 1.77 2.60 8.30 10000 1000
1.65E+04 2.62 2.60 8.30
1.64E+04 2.35 2.60 8.30
1.29E+04 0.35 2.60 8.30
1.18E+04 1.12 2.60 8.30
1.04E+04 4.33 2.60 8.30
1.06E+04 1.00 2.60 8.30
3.22E+05 1.00 2.60 8.30
3.86E+04 1.48 2.60 8.30
2.09E+04 0.93 2.60 8.30 10000 1000
1.52E+04 0.83 2.60 8.30
1.53E+04 0.27 2.60 8.30
1.30E+04 0.30 2.60 8.30
1.20E+04 0.54 2.60 8.30
1.06E+04 0.30 2.60 8.30
1.01E+04 0.62 2.60 8.30
1.30E+00 2.25 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.12E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.30E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.18E+04 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-301
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
Cr JaFS-L07-1314-T01-A 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T02-A 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T03-A 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T04-A 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T05-A 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T06-A 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T07-A 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T08-A 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T09-A 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T01-B 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T02-B 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T03-B 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T04-B 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T05-B 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T06-B 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T07-B 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T08-B 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T09-B 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T01-C 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T02-C 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T03-C 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T04-C 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T05-C 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T06-C 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T07-C 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T08-C 1 6.00E-01 U1/2
Cr JaFS-L07-1314-T09-C 1 6.00E-01 U1/2
Cr JaFS-L07-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 35.74 1.20 3.82
6.00E-01 49.09 1.20 3.82
6.00E-01 73.73 1.20 3.82 10000 1000
6.00E-01 70.91 1.20 3.82
6.00E-01 3.05 1.20 3.82
6.00E-01 53.28 1.20 3.82
6.00E-01 39.78 1.20 3.82
6.00E-01 56.86 1.20 3.82
6.00E-01 60.53 1.20 3.82
6.00E-01 55.69 1.20 3.82
6.00E-01 56.35 1.20 3.82
6.00E-01 29.78 1.20 3.82 10000 1000
6.00E-01 4.72 1.20 3.82
6.00E-01 35.80 1.20 3.82
6.00E-01 47.43 1.20 3.82
6.00E-01 5.93 1.20 3.82
6.00E-01 56.24 1.20 3.82
6.00E-01 50.75 1.20 3.82
6.00E-01 63.73 1.20 3.82
6.00E-01 87.23 1.20 3.82
6.00E-01 36.63 1.20 3.82 10000 1000
6.00E-01 2.77 1.20 3.82
6.00E-01 14.15 1.20 3.82
6.00E-01 7.09 1.20 3.82
6.00E-01 10.94 1.20 3.82
6.00E-01 46.11 1.20 3.82
6.00E-01 50.79 1.20 3.82
6.00E-01 17.59 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.54E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.43E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.98E+02 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-302
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
Co JaFS-L07-1314-T01-A 1 9.00E-01 U1/2
Co JaFS-L07-1314-T02-A 1 9.00E-01 U1/2
Co JaFS-L07-1314-T03-A 1 9.00E-01 U1/2
Co JaFS-L07-1314-T04-A 1 9.00E-01 U1/2
Co JaFS-L07-1314-T05-A 1 9.00E-01 U1/2
Co JaFS-L07-1314-T06-A 1 9.00E-01 U1/2
Co JaFS-L07-1314-T07-A 1 9.00E-01 U1/2
Co JaFS-L07-1314-T08-A 1 9.00E-01 U1/2
Co JaFS-L07-1314-T09-A 1 9.00E-01 U1/2
Co JaFS-L07-1314-T01-B 1 9.00E-01 U1/2
Co JaFS-L07-1314-T02-B 1 9.00E-01 U1/2
Co JaFS-L07-1314-T03-B 1 9.00E-01 U1/2
Co JaFS-L07-1314-T04-B 1 9.00E-01 U1/2
Co JaFS-L07-1314-T05-B 1 9.00E-01 U1/2
Co JaFS-L07-1314-T06-B 1 9.00E-01 U1/2
Co JaFS-L07-1314-T07-B 1 9.00E-01 U1/2
Co JaFS-L07-1314-T08-B 1 9.00E-01 U1/2
Co JaFS-L07-1314-T09-B 1 9.00E-01 U1/2
Co JaFS-L07-1314-T01-C 1 9.00E-01 U1/2
Co JaFS-L07-1314-T02-C 1 9.00E-01 U1/2
Co JaFS-L07-1314-T03-C 1 9.00E-01 U1/2
Co JaFS-L07-1314-T04-C 1 9.00E-01 U1/2
Co JaFS-L07-1314-T05-C 1 9.00E-01 U1/2
Co JaFS-L07-1314-T06-C 1 9.00E-01 U1/2
Co JaFS-L07-1314-T07-C 1 9.00E-01 U1/2
Co JaFS-L07-1314-T08-C 1 9.00E-01 U1/2
Co JaFS-L07-1314-T09-C 1 9.00E-01 U1/2
Co JaFS-L07-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 76.06 1.80 5.72
9.00E-01 38.57 1.80 5.72
9.00E-01 37.74 1.80 5.72 10000 1000
9.00E-01 5.03 1.80 5.72
9.00E-01 36.44 1.80 5.72
9.00E-01 31.82 1.80 5.72
9.00E-01 27.69 1.80 5.72
9.00E-01 16.09 1.80 5.72
9.00E-01 15.55 1.80 5.72
9.00E-01 45.11 1.80 5.72
9.00E-01 97.24 1.80 5.72
9.00E-01 22.79 1.80 5.72 10000 1000
9.00E-01 48.21 1.80 5.72
9.00E-01 57.34 1.80 5.72
9.00E-01 34.71 1.80 5.72
9.00E-01 25.13 1.80 5.72
9.00E-01 32.21 1.80 5.72
9.00E-01 6.56 1.80 5.72
9.00E-01 25.25 1.80 5.72
9.00E-01 37.71 1.80 5.72
9.00E-01 41.50 1.80 5.72 10000 1000
9.00E-01 17.47 1.80 5.72
9.00E-01 27.90 1.80 5.72
9.00E-01 39.32 1.80 5.72
9.00E-01 15.87 1.80 5.72
9.00E-01 9.15 1.80 5.72
9.00E-01 24.45 1.80 5.72
9.00E-01 50.34 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.95E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.83E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.37E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-303
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Cu JaFS-L07-1314-T01-A 1 1.00E+03
Cu JaFS-L07-1314-T02-A 1 8.29E+02
Cu JaFS-L07-1314-T03-A 1 6.68E+02
Cu JaFS-L07-1314-T04-A 1 3.56E+02
Cu JaFS-L07-1314-T05-A 1 2.46E+02
Cu JaFS-L07-1314-T06-A 1 1.69E+02
Cu JaFS-L07-1314-T07-A 1 1.28E+02
Cu JaFS-L07-1314-T08-A 1 8.97E+01
Cu JaFS-L07-1314-T09-A 1 6.39E+01
Cu JaFS-L07-1314-T01-B 1 1.05E+03
Cu JaFS-L07-1314-T02-B 1 9.01 E+02
Cu JaFS-L07-1314-T03-B 1 5.73E+02
Cu JaFS-L07-1314-T04-B 1 3.17E+02
Cu JaFS-L07-1314-T05-B 1 2.37E+02
Cu JaFS-L07-1314-T06-B 1 1.70E+02
Cu JaFS-L07-1314-T07-B 1 1.16E+02
Cu JaFS-L07-1314-T08-B 1 8.45E+01
Cu JaFS-L07-1314-T09-B 1 6.14E+01
Cu JaFS-L07-1314-T01-C 1 1.08E+03
Cu JaFS-L07-1314-T02-C 1 8.65E+02
Cu JaFS-L07-1314-T03-C 1 5.91E+02
Cu JaFS-L07-1314-T04-C 1 3.30E+02
Cu JaFS-L07-1314-T05-C 1 2.44E+02
Cu JaFS-L07-1314-T06-C 1 1.74E+02
Cu JaFS-L07-1314-T07-C 1 1.34E+02
Cu JaFS-L07-1314-T08-C 1 9.41E+01
Cu JaFS-L07-1314-T09-C 1 6.28E+01
Cu JaFS-L07-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+03 0.18 3.70 11.80
8.29E+02 2.20 3.70 11.80
6.68E+02 1.04 3.70 11.80 10000 1000
3.56E+02 1.42 3.70 11.80
2.46E+02 1.46 3.70 11.80
1.69E+02 1.32 3.70 11.80
1.28E+02 2.04 3.70 11.80
8.97E+01 0.64 3.70 11.80
6.39E+01 2.64 3.70 11.80
1.05E+03 0.76 3.70 11.80
9.01E+02 2.08 3.70 11.80
5.73E+02 1.65 3.70 11.80 10000 1000
3.17E+02 1.86 3.70 11.80
2.37E+02 1.81 3.70 11.80
1.70E+02 1.13 3.70 11.80
1.16E+02 0.91 3.70 11.80
8.45E+01 5.48 3.70 11.80
6.14E+01 1.92 3.70 11.80
1.08E+03 0.73 3.70 11.80
8.65E+02 1.86 3.70 11.80
5.91E+02 3.37 3.70 11.80 10000 1000
3.30E+02 0.78 3.70 11.80
2.44E+02 0.50 3.70 11.80
1.74E+02 2.18 3.70 11.80
1.34E+02 0.84 3.70 11.80
9.41E+01 0.36 3.70 11.80
6.28E+01 1.60 3.70 11.80
1.85E+00 18.04 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.67E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.63E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.63E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-304
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
Fe JaFS-L07-1314-T01-A 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T02-A 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T03-A 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T04-A 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T05-A 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T06-A 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T07-A 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T08-A 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T09-A 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T01-B 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T02-B 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T03-B 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T04-B 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T05-B 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T06-B 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T07-B 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T08-B 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T09-B 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T01-C 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T02-C 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T03-C 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T04-C 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T05-C 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T06-C 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T07-C 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T08-C 1 1.00E+00 U1/2
Fe JaFS-L07-1314-T09-C 1 1.00E+00 U1/2
Fe JaFS-L07-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 2.52 2.00 6.40
1.00E+00 5.84 2.00 6.40
1.00E+00 11.07 2.00 6.40 10000 1000
1.00E+00 13.39 2.00 6.40
1.00E+00 13.33 2.00 6.40
1.00E+00 8.25 2.00 6.40
1.00E+00 7.66 2.00 6.40
1.00E+00 1.58 2.00 6.40
1.00E+00 4.37 2.00 6.40
1.00E+00 0.88 2.00 6.40
1.00E+00 2.45 2.00 6.40
1.00E+00 3.29 2.00 6.40 10000 1000
1.00E+00 3.08 2.00 6.40
1.00E+00 6.73 2.00 6.40
1.00E+00 4.54 2.00 6.40
1.00E+00 8.89 2.00 6.40
1.00E+00 8.43 2.00 6.40
1.00E+00 2.74 2.00 6.40
1.00E+00 5.55 2.00 6.40
1.00E+00 8.75 2.00 6.40
1.00E+00 3.49 2.00 6.40 10000 1000
1.00E+00 6.80 2.00 6.40
1.00E+00 3.39 2.00 6.40
1.00E+00 11.41 2.00 6.40
1.00E+00 8.77 2.00 6.40
1.00E+00 4.37 2.00 6.40
1.00E+00 12.31 2.00 6.40
1.00E+00 8.49 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.00E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.86E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.39E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-305
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
ug/L
Pb JaFS-L07-1314-T01-A 1 8.96E+01
Pb JaFS-L07-1314-T02-A 1 1.13E+02
Pb JaFS-L07-1314-T03-A 1 1.19E+02
Pb JaFS-L07-1314-T04-A 1 8.36E+01
Pb JaFS-L07-1314-T05-A 1 6.40E+01
Pb JaFS-L07-1314-T06-A 1 5.34E+01
Pb JaFS-L07-1314-T07-A 1 5.31E+01
Pb JaFS-L07-1314-T08-A 1 4.76E+01
Pb JaFS-L07-1314-T09-A 1 3.57E+01
Pb JaFS-L07-1314-T01-B 1 9.42E+01
Pb JaFS-L07-1314-T02-B 1 1.32E+02
Pb JaFS-L07-1314-T03-B 1 1.03E+02
Pb JaFS-L07-1314-T04-B 1 7.03E+01
Pb JaFS-L07-1314-T05-B 1 6.31E+01
Pb JaFS-L07-1314-T06-B 1 5.39E+01
Pb JaFS-L07-1314-T07-B 1 4.85E+01
Pb JaFS-L07-1314-T08-B 1 3.94E+01
Pb JaFS-L07-1314-T09-B 1 3.70E+01
Pb JaFS-L07-1314-T01-C 1 8.39E+01
Pb JaFS-L07-1314-T02-C 1 1.26E+02
Pb JaFS-L07-1314-T03-C 1 1.18E+02
Pb JaFS-L07-1314-T04-C 1 7.93E+01
Pb JaFS-L07-1314-T05-C 1 6.54E+01
Pb JaFS-L07-1314-T06-C 1 5.46E+01
Pb JaFS-L07-1314-T07-C 1 4.46E+01
Pb JaFS-L07-1314-T08-C 1 3.50E+01
Pb JaFS-L07-1314-T09-C 1 3.68E+01
Pb JaFS-L07-1314-B01-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.96E+01 3.14 6.80 21.60
1.13E+02 1.85 6.80 21.60
1.19E+02 3.94 6.80 21.60 10000 1000
8.36E+01 1.47 6.80 21.60
6.40E+01 4.04 6.80 21.60
5.34E+01 5.60 6.80 21.60
5.31 E+01 8.08 6.80 21.60
4.76E+01 4.81 6.80 21.60
3.57E+01 9.86 6.80 21.60
9.42E+01 3.75 6.80 21.60
1.32E+02 2.84 6.80 21.60
1.03E+02 6.55 6.80 21.60 10000 1000
7.03E+01 6.80 6.80 21.60
6.31 E+01 3.70 6.80 21.60
5.39E+01 4.01 6.80 21.60
4.85E+01 7.37 6.80 21.60
3.94E+01 3.33 6.80 21.60
3.70E+01 7.75 6.80 21.60
8.39E+01 4.22 6.80 21.60
1.26E+02 4.42 6.80 21.60
1.18E+02 2.69 6.80 21.60 10000 1000
7.93E+01 6.40 6.80 21.60
6.54E+01 3.45 6.80 21.60
5.46E+01 4.77 6.80 21.60
4.46E+01 3.64 6.80 21.60
3.50E+01 12.39 6.80 21.60
3.68E+01 5.35 6.80 21.60
3.40E+00 46.41 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-306
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
Li JaFS-L07-1314-T01-A 1 7.12E+01
Li JaFS-L07-1314-T02-A 1 1.20E+01
Li JaFS-L07-1314-T03-A 1 3.43E+00 E
Li JaFS-L07-1314-T04-A 1 9.50E-01 U1/2
Li JaFS-L07-1314-T05-A 1 9.50E-01 U1/2
Li JaFS-L07-1314-T06-A 1 9.50E-01 U1/2
Li JaFS-L07-1314-T07-A 1 9.50E-01 U1/2
Li JaFS-L07-1314-T08-A 1 9.50E-01 U1/2
Li JaFS-L07-1314-T09-A 1 9.50E-01 U1/2
Li JaFS-L07-1314-T01-B 1 7.49E+01
Li JaFS-L07-1314-T02-B 1 1.34E+01
Li JaFS-L07-1314-T03-B 1 2.60E+00 E
Li JaFS-L07-1314-T04-B 1 9.50E-01 U1/2
Li JaFS-L07-1314-T05-B 1 9.50E-01 U1/2
Li JaFS-L07-1314-T06-B 1 9.50E-01 U1/2
Li JaFS-L07-1314-T07-B 1 9.50E-01 U1/2
Li JaFS-L07-1314-T08-B 1 9.50E-01 U1/2
Li JaFS-L07-1314-T09-B 1 9.50E-01 U1/2
Li JaFS-L07-1314-T01-C 1 7.21E+01
Li JaFS-L07-1314-T02-C 1 1.27E+01
Li JaFS-L07-1314-T03-C 1 2.65E+00 E
Li JaFS-L07-1314-T04-C 1 9.50E-01 U1/2
Li JaFS-L07-1314-T05-C 1 9.50E-01 U1/2
Li JaFS-L07-1314-T06-C 1 9.50E-01 U1/2
Li JaFS-L07-1314-T07-C 1 9.50E-01 U1/2
Li JaFS-L07-1314-T08-C 1 9.50E-01 U1/2
Li JaFS-L07-1314-T09-C 1 9.50E-01 U1/2
Li JaFS-L07-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.12E+01 5.04 1.90 6.00
1.20E+01 3.56 1.90 6.00
3.43E+00 13.99 1.90 6.00 10000 1000
9.50E-01 30.59 1.90 6.00
9.50E-01 35.81 1.90 6.00
9.50E-01 80.70 1.90 6.00
9.50E-01 28.29 1.90 6.00
9.50E-01 17.72 1.90 6.00
9.50E-01 29.37 1.90 6.00
7.49E+01 5.48 1.90 6.00
1.34E+01 4.42 1.90 6.00
2.60E+00 29.82 1.90 6.00 10000 1000
9.50E-01 19.73 1.90 6.00
9.50E-01 51.40 1.90 6.00
9.50E-01 28.48 1.90 6.00
9.50E-01 12.66 1.90 6.00
9.50E-01 14.10 1.90 6.00
9.50E-01 10.40 1.90 6.00
7.21E+01 2.62 1.90 6.00
1.27E+01 3.48 1.90 6.00
2.65E+00 12.58 1.90 6.00 10000 1000
9.50E-01 40.58 1.90 6.00
9.50E-01 7.87 1.90 6.00
9.50E-01 88.35 1.90 6.00
9.50E-01 63.54 1.90 6.00
9.50E-01 49.50 1.90 6.00
9.50E-01 13.20 1.90 6.00
9.50E-01 48.86 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.08E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.94E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.87E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-307
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Mn JaFS-L07-1314-T01-A 1 2.57E+02
Mn JaFS-L07-1314-T02-A 1 4.73E+01
Mn JaFS-L07-1314-T03-A 1 3.06E+01
Mn JaFS-L07-1314-T04-A 1 1.99E+01
Mn JaFS-L07-1314-T05-A 1 1.84E+01
Mn JaFS-L07-1314-T06-A 1 1.10E+01
Mn JaFS-L07-1314-T07-A 1 1.00E+01
Mn JaFS-L07-1314-T08-A 1 6.42E+00
Mn JaFS-L07-1314-T09-A 1 6.13E+00 E
Mn JaFS-L07-1314-T01-B 1 2.30E+02
Mn JaFS-L07-1314-T02-B 1 5.31E+01
Mn JaFS-L07-1314-T03-B 1 2.23E+01
Mn JaFS-L07-1314-T04-B 1 1.64E+01
Mn JaFS-L07-1314-T05-B 1 1.70E+01
Mn JaFS-L07-1314-T06-B 1 1.40E+01
Mn JaFS-L07-1314-T07-B 1 1.28E+01
Mn JaFS-L07-1314-T08-B 1 8.47E+00
Mn JaFS-L07-1314-T09-B 1 7.47E+00
Mn JaFS-L07-1314-T01-C 1 2.52E+02
Mn JaFS-L07-1314-T02-C 1 4.42E+01
Mn JaFS-L07-1314-T03-C 1 2.47E+01
Mn JaFS-L07-1314-T04-C 1 1.97E+01
Mn JaFS-L07-1314-T05-C 1 1.86E+01
Mn JaFS-L07-1314-T06-C 1 1.48E+01
Mn JaFS-L07-1314-T07-C 1 1.27E+01
Mn JaFS-L07-1314-T08-C 1 8.09E+00
Mn JaFS-L07-1314-T09-C 1 6.03E+00 E
Mn JaFS-L07-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.57E+02 0.11 2.00 6.40
4.73E+01 1.77 2.00 6.40
3.06E+01 1.26 2.00 6.40 10000 1000
1.99E+01 1.28 2.00 6.40
1.84E+01 0.86 2.00 6.40
1.10E+01 0.82 2.00 6.40
1.00E+01 1.25 2.00 6.40
6.42E+00 0.21 2.00 6.40
6.13E+00 1.78 2.00 6.40
2.30E+02 0.43 2.00 6.40
5.31 E+01 1.46 2.00 6.40
2.23E+01 2.05 2.00 6.40 10000 1000
1.64E+01 2.60 2.00 6.40
1.70E+01 2.25 2.00 6.40
1.40E+01 1.71 2.00 6.40
1.28E+01 0.56 2.00 6.40
8.47E+00 3.62 2.00 6.40
7.47E+00 0.92 2.00 6.40
2.52E+02 1.47 2.00 6.40
4.42E+01 1.78 2.00 6.40
2.47E+01 1.30 2.00 6.40 10000 1000
1.97E+01 0.30 2.00 6.40
1.86E+01 0.28 2.00 6.40
1.48E+01 1.18 2.00 6.40
1.27E+01 0.82 2.00 6.40
8.09E+00 0.76 2.00 6.40
6.03E+00 0.27 2.00 6.40
1.00E+00 18.21 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.82E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-308
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Mg JaFS-L07-1314-T01-A 1 4.81E+04
Mg JaFS-L07-1314-T02-A 1 6.78E+03
Mg JaFS-L07-1314-T03-A 1 4.19E+03
Mg JaFS-L07-1314-T04-A 1 2.64E+03
Mg JaFS-L07-1314-T05-A 1 2.36E+03
Mg JaFS-L07-1314-T06-A 1 1.91E+03
Mg JaFS-L07-1314-T07-A 1 1.71E+03
Mg JaFS-L07-1314-T08-A 1 1.41E+03
Mg JaFS-L07-1314-T09-A 1 1.26E+03
Mg JaFS-L07-1314-T01-B 1 4.72E+04
Mg JaFS-L07-1314-T02-B 1 6.92E+03
Mg JaFS-L07-1314-T03-B 1 4.61E+03
Mg JaFS-L07-1314-T04-B 1 2.69E+03
Mg JaFS-L07-1314-T05-B 1 2.59E+03
Mg JaFS-L07-1314-T06-B 1 1.91E+03
Mg JaFS-L07-1314-T07-B 1 1.63E+03
Mg JaFS-L07-1314-T08-B 1 1.38E+03
Mg JaFS-L07-1314-T09-B 1 1.32E+03
Mg JaFS-L07-1314-T01-C 1 4.87E+04
Mg JaFS-L07-1314-T02-C 1 6.87E+03
Mg JaFS-L07-1314-T03-C 1 4.40E+03
Mg JaFS-L07-1314-T04-C 1 2.47E+03
Mg JaFS-L07-1314-T05-C 1 2.40E+03
Mg JaFS-L07-1314-T06-C 1 1.92E+03
Mg JaFS-L07-1314-T07-C 1 1.67E+03
Mg JaFS-L07-1314-T08-C 1 1.38E+03
Mg JaFS-L07-1314-T09-C 1 1.28E+03
Mg JaFS-L07-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.81E+04 1.03 1.00 3.18
6.78E+03 1.97 1.00 3.18
4.19E+03 0.72 1.00 3.18 10000 1000
2.64E+03 1.09 1.00 3.18
2.36E+03 0.65 1.00 3.18
1.91E+03 1.80 1.00 3.18
1.71E+03 1.37 1.00 3.18
1.41E+03 1.14 1.00 3.18
1.26E+03 0.86 1.00 3.18
4.72E+04 1.02 1.00 3.18
6.92E+03 0.26 1.00 3.18
4.61E+03 2.09 1.00 3.18 10000 1000
2.69E+03 2.64 1.00 3.18
2.59E+03 1.66 1.00 3.18
1.91E+03 0.28 1.00 3.18
1.63E+03 0.34 1.00 3.18
1.38E+03 5.02 1.00 3.18
1.32E+03 1.19 1.00 3.18
4.87E+04 1.67 1.00 3.18
6.87E+03 1.58 1.00 3.18
4.40E+03 0.61 1.00 3.18 10000 1000
2.47E+03 0.24 1.00 3.18
2.40E+03 0.56 1.00 3.18
1.92E+03 1.74 1.00 3.18
1.67E+03 0.71 1.00 3.18
1.38E+03 0.22 1.00 3.18
1.28E+03 1.19 1.00 3.18
5.00E-01 14.83 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.14E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.51 E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.34E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-309
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Mo JaFS-L07-1314-T01-A 1 6.10E+01
Mo JaFS-L07-1314-T02-A 1 5.38E+01
Mo JaFS-L07-1314-T03-A 1 2.90E+01
Mo JaFS-L07-1314-T04-A 1 1.40E+01
Mo JaFS-L07-1314-T05-A 1 1.20E+01
Mo JaFS-L07-1314-T06-A 1 5.12E+00
Mo JaFS-L07-1314-T07-A 1 5.04E+00
Mo JaFS-L07-1314-T08-A 1 2.99E+00 E
Mo JaFS-L07-1314-T09-A 1 1.48E+00 E
Mo JaFS-L07-1314-T01-B 1 7.45E+01
Mo JaFS-L07-1314-T02-B 1 5.37E+01
Mo JaFS-L07-1314-T03-B 1 2.32E+01
Mo JaFS-L07-1314-T04-B 1 1.42E+01
Mo JaFS-L07-1314-T05-B 1 1.13E+01
Mo JaFS-L07-1314-T06-B 1 6.65E+00
Mo JaFS-L07-1314-T07-B 1 4.59E+00
Mo JaFS-L07-1314-T08-B 1 3.03E+00 E
Mo JaFS-L07-1314-T09-B 1 2.89E+00 E
Mo JaFS-L07-1314-T01-C 1 6.98E+01
Mo JaFS-L07-1314-T02-C 1 5.73E+01
Mo JaFS-L07-1314-T03-C 1 2.43E+01
Mo JaFS-L07-1314-T04-C 1 1.30E+01
Mo JaFS-L07-1314-T05-C 1 9.53E+00
Mo JaFS-L07-1314-T06-C 1 5.61E+00
Mo JaFS-L07-1314-T07-C 1 5.91E+00
Mo JaFS-L07-1314-T08-C 1 3.23E+00 E
Mo JaFS-L07-1314-T09-C 1 1.29E+00 E
Mo JaFS-L07-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.10E+01 5.58 1.20 3.82
5.38E+01 4.19 1.20 3.82
2.90E+01 3.50 1.20 3.82 10000 1000
1.40E+01 3.22 1.20 3.82
1.20E+01 8.91 1.20 3.82
5.12E+00 8.53 1.20 3.82
5.04E+00 3.66 1.20 3.82
2.99E+00 5.94 1.20 3.82
1.48E+00 14.77 1.20 3.82
7.45E+01 0.93 1.20 3.82
5.37E+01 2.79 1.20 3.82
2.32E+01 4.08 1.20 3.82 10000 1000
1.42E+01 5.92 1.20 3.82
1.13E+01 6.86 1.20 3.82
6.65E+00 1.92 1.20 3.82
4.59E+00 1.21 1.20 3.82
3.03E+00 12.80 1.20 3.82
2.89E+00 18.56 1.20 3.82
6.98E+01 4.23 1.20 3.82
5.73E+01 0.48 1.20 3.82
2.43E+01 2.44 1.20 3.82 10000 1000
1.30E+01 7.20 1.20 3.82
9.53E+00 12.74 1.20 3.82
5.61 E+00 6.61 1.20 3.82
5.91 E+00 8.43 1.20 3.82
3.23E+00 13.51 1.20 3.82
1.29E+00 23.99 1.20 3.82
6.00E-01 23.95 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.37E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.13E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.65E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-310
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
Ni JaFS-L07-1314-T01-A 1 1.30E+01
Ni JaFS-L07-1314-T02-A 1 7.05E+00
Ni JaFS-L07-1314-T03-A 1 9.00E-01 U1/2
Ni JaFS-L07-1314-T04-A 1 9.00E-01 U1/2
Ni JaFS-L07-1314-T05-A 1 9.00E-01 U1/2
Ni JaFS-L07-1314-T06-A 1 9.00E-01 U1/2
Ni JaFS-L07-1314-T07-A 1 9.00E-01 U1/2
Ni JaFS-L07-1314-T08-A 1 9.00E-01 U1/2
Ni JaFS-L07-1314-T09-A 1 9.00E-01 U1/2
Ni JaFS-L07-1314-T01-B 1 9.68E+00
Ni JaFS-L07-1314-T02-B 1 6.77E+00
Ni JaFS-L07-1314-T03-B 1 9.00E-01 U1/2
Ni JaFS-L07-1314-T04-B 1 9.00E-01 U1/2
Ni JaFS-L07-1314-T05-B 1 9.00E-01 U1/2
Ni JaFS-L07-1314-T06-B 1 9.00E-01 U1/2
Ni JaFS-L07-1314-T07-B 1 9.00E-01 U1/2
Ni JaFS-L07-1314-T08-B 1 9.00E-01 U1/2
Ni JaFS-L07-1314-T09-B 1 9.00E-01 U1/2
Ni JaFS-L07-1314-T01-C 1 9.84E+00
Ni JaFS-L07-1314-T02-C 1 6.20E+00
Ni JaFS-L07-1314-T03-C 1 9.00E-01 U1/2
Ni JaFS-L07-1314-T04-C 1 9.00E-01 U1/2
Ni JaFS-L07-1314-T05-C 1 9.00E-01 U1/2
Ni JaFS-L07-1314-T06-C 1 9.00E-01 U1/2
Ni JaFS-L07-1314-T07-C 1 9.00E-01 U1/2
Ni JaFS-L07-1314-T08-C 1 9.00E-01 U1/2
Ni JaFS-L07-1314-T09-C 1 9.00E-01 U1/2
Ni JaFS-L07-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.30E+01 1.44 1.80 5.70
7.05E+00 2.16 1.80 5.70
9.00E-01 18.19 1.80 5.70 10000 1000
9.00E-01 31.00 1.80 5.70
9.00E-01 31.80 1.80 5.70
9.00E-01 40.62 1.80 5.70
9.00E-01 57.95 1.80 5.70
9.00E-01 49.35 1.80 5.70
9.00E-01 31.61 1.80 5.70
9.68E+00 17.87 1.80 5.70
6.77E+00 2.89 1.80 5.70
9.00E-01 17.06 1.80 5.70 10000 1000
9.00E-01 31.21 1.80 5.70
9.00E-01 28.98 1.80 5.70
9.00E-01 51.70 1.80 5.70
9.00E-01 27.75 1.80 5.70
9.00E-01 13.01 1.80 5.70
9.00E-01 39.30 1.80 5.70
9.84E+00 2.79 1.80 5.70
6.20E+00 2.75 1.80 5.70
9.00E-01 44.80 1.80 5.70 10000 1000
9.00E-01 20.73 1.80 5.70
9.00E-01 12.82 1.80 5.70
9.00E-01 26.61 1.80 5.70
9.00E-01 24.42 1.80 5.70
9.00E-01 14.57 1.80 5.70
9.00E-01 47.77 1.80 5.70
9.00E-01 42.51 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.79E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-311
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
P JaFS-L07-1314-T01-A 1 6.87E+01
P JaFS-L07-1314-T02-A 1 4.10E+01
P JaFS-L07-1314-T03-A 1 3.54E+01
P JaFS-L07-1314-T04-A 1 2.96E+01
P JaFS-L07-1314-T05-A 1 1.85E+01
P JaFS-L07-1314-T06-A 1 1.98E+01
P JaFS-L07-1314-T07-A 1 3.29E+01
P JaFS-L07-1314-T08-A 1 3.89E+01
P JaFS-L07-1314-T09-A 1 3.26E+01
P JaFS-L07-1314-T01-B 1 7.68E+01
P JaFS-L07-1314-T02-B 1 4.58E+01
P JaFS-L07-1314-T03-B 1 3.47E+01
P JaFS-L07-1314-T04-B 1 2.28E+01
P JaFS-L07-1314-T05-B 1 1.19E+01
P JaFS-L07-1314-T06-B 1 1.22E+01
P JaFS-L07-1314-T07-B 1 2.90E+01
P JaFS-L07-1314-T08-B 1 3.76E+01
P JaFS-L07-1314-T09-B 1 5.26E+01
P JaFS-L07-1314-T01-C 1 7.84E+01
P JaFS-L07-1314-T02-C 1 3.57E+01
P JaFS-L07-1314-T03-C 1 3.15E+01
P JaFS-L07-1314-T04-C 1 2.57E+01
P JaFS-L07-1314-T05-C 1 2.02E+01
P JaFS-L07-1314-T06-C 1 1.65E+01
P JaFS-L07-1314-T07-C 1 2.31E+01
P JaFS-L07-1314-T08-C 1 2.73E+01
P JaFS-L07-1314-T09-C 1 4.03E+01
P JaFS-L07-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.87E+01 5.41 3.70 11.80
4.10E+01 1.63 3.70 11.80
3.54E+01 1.96 3.70 11.80 10000 1000
2.96E+01 3.07 3.70 11.80
1.85E+01 1.56 3.70 11.80
1.98E+01 2.49 3.70 11.80
3.29E+01 11.17 3.70 11.80
3.89E+01 9.05 3.70 11.80
3.26E+01 1.17 3.70 11.80
7.68E+01 2.10 3.70 11.80
4.58E+01 2.37 3.70 11.80
3.47E+01 2.28 3.70 11.80 10000 1000
2.28E+01 2.34 3.70 11.80
1.19E+01 1.17 3.70 11.80
1.22E+01 4.32 3.70 11.80
2.90E+01 6.11 3.70 11.80
3.76E+01 11.32 3.70 11.80
5.26E+01 10.49 3.70 11.80
7.84E+01 6.32 3.70 11.80
3.57E+01 2.11 3.70 11.80
3.15E+01 1.15 3.70 11.80 10000 1000
2.57E+01 1.36 3.70 11.80
2.02E+01 2.39 3.70 11.80
1.65E+01 1.62 3.70 11.80
2.31 E+01 7.60 3.70 11.80
2.73E+01 3.35 3.70 11.80
4.03E+01 1.10 3.70 11.80
1.85E+00 12.96 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.13E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.13E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-312
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
K JaFS-L07-1314-T01-A 1 5.14E+04
K JaFS-L07-1314-T02-A 1 3.28E+04
K JaFS-L07-1314-T03-A 1 1.46E+04
K JaFS-L07-1314-T04-A 1 9.01E+03
K JaFS-L07-1314-T05-A 1 7.85E+03
K JaFS-L07-1314-T06-A 1 5.49E+03
K JaFS-L07-1314-T07-A 1 4.40E+03
K JaFS-L07-1314-T08-A 1 3.13E+03
K JaFS-L07-1314-T09-A 1 2.33E+03
K JaFS-L07-1314-T01-B 1 5.05E+04
K JaFS-L07-1314-T02-B 1 2.82E+04
K JaFS-L07-1314-T03-B 1 1.17E+04
K JaFS-L07-1314-T04-B 1 8.76E+03
K JaFS-L07-1314-T05-B 1 7.98E+03
K JaFS-L07-1314-T06-B 1 5.38E+03
K JaFS-L07-1314-T07-B 1 4.18E+03
K JaFS-L07-1314-T08-B 1 3.02E+03
K JaFS-L07-1314-T09-B 1 2.42E+03
K JaFS-L07-1314-T01-C 1 5.19E+04
K JaFS-L07-1314-T02-C 1 2.95E+04
K JaFS-L07-1314-T03-C 1 1.15E+04
K JaFS-L07-1314-T04-C 1 8.39E+03
K JaFS-L07-1314-T05-C 1 7.51E+03
K JaFS-L07-1314-T06-C 1 5.38E+03
K JaFS-L07-1314-T07-C 1 4.23E+03
K JaFS-L07-1314-T08-C 1 3.08E+03
K JaFS-L07-1314-T09-C 1 2.33E+03
K JaFS-L07-1314-B01-A 1 4.68E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.14E+04 0.13 1.60 5.09
3.28E+04 1.65 1.60 5.09
1.46E+04 0.79 1.60 5.09 10000 1000
9.01 E+03 0.92 1.60 5.09
7.85E+03 0.83 1.60 5.09
5.49E+03 1.02 1.60 5.09
4.40E+03 1.67 1.60 5.09
3.13E+03 0.62 1.60 5.09
2.33E+03 0.94 1.60 5.09
5.05E+04 1.38 1.60 5.09
2.82E+04 0.75 1.60 5.09
1.17E+04 2.31 1.60 5.09 10000 1000
8.76E+03 2.70 1.60 5.09
7.98E+03 2.04 1.60 5.09
5.38E+03 0.60 1.60 5.09
4.18E+03 0.97 1.60 5.09
3.02E+03 4.31 1.60 5.09
2.42E+03 1.72 1.60 5.09
5.19E+04 1.14 1.60 5.09
2.95E+04 1.63 1.60 5.09
1.15E+04 1.19 1.60 5.09 10000 1000
8.39E+03 0.89 1.60 5.09
7. 51 E+03 0.34 1.60 5.09
5.38E+03 0.87 1.60 5.09
4.23E+03 0.47 1.60 5.09
3.08E+03 0.46 1.60 5.09
2.33E+03 0.45 1.60 5.09
4.68E+01 4.28 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.54E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.26E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.24E+04 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-313
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
Se JaFS-L07-1314-T01-A 1 6.26E+01
Se JaFS-L07-1314-T02-A 1 2.57E+01 E
Se JaFS-L07-1314-T03-A 1 1.71E+01 E
Se JaFS-L07-1314-T04-A 1 7.50E+00 U1/2
Se JaFS-L07-1314-T05-A 1 7.50E+00 U1/2
Se JaFS-L07-1314-T06-A 1 7.50E+00 U1/2
Se JaFS-L07-1314-T07-A 1 7.50E+00 U1/2
Se JaFS-L07-1314-T08-A 1 7.50E+00 U1/2
Se JaFS-L07-1314-T09-A 1 7.50E+00 U1/2
Se JaFS-L07-1314-T01-B 1 5.92E+01
Se JaFS-L07-1314-T02-B 1 2.21E+01 E
Se JaFS-L07-1314-T03-B 1 1.53E+01 E
Se JaFS-L07-1314-T04-B 1 7.50E+00 U1/2
Se JaFS-L07-1314-T05-B 1 7.50E+00 U1/2
Se JaFS-L07-1314-T06-B 1 7.50E+00 U1/2
Se JaFS-L07-1314-T07-B 1 7.50E+00 U1/2
Se JaFS-L07-1314-T08-B 1 7.50E+00 U1/2
Se JaFS-L07-1314-T09-B 1 7.50E+00 U1/2
Se JaFS-L07-1314-T01-C 1 5.53E+01
Se JaFS-L07-1314-T02-C 1 2.17E+01 E
Se JaFS-L07-1314-T03-C 1 1.59E+01 E
Se JaFS-L07-1314-T04-C 1 7.50E+00 U1/2
Se JaFS-L07-1314-T05-C 1 7.50E+00 U1/2
Se JaFS-L07-1314-T06-C 1 7.50E+00 U1/2
Se JaFS-L07-1314-T07-C 1 7.50E+00 U1/2
Se JaFS-L07-1314-T08-C 1 7.50E+00 U1/2
Se JaFS-L07-1314-T09-C 1 7.50E+00 U1/2
Se JaFS-L07-1314-B01-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.26E+01 3.25 15.00 47.70
2.57E+01 6.53 15.00 47.70
1.71E+01 30.80 15.00 47.70 10000 1000
7.50E+00 24.62 15.00 47.70
7.50E+00 23.47 15.00 47.70
7.50E+00 20.03 15.00 47.70
7.50E+00 21.93 15.00 47.70
7.50E+00 7.90 15.00 47.70
7.50E+00 15.88 15.00 47.70
5.92E+01 1.75 15.00 47.70
2.21E+01 18.41 15.00 47.70
1.53E+01 34.28 15.00 47.70 10000 1000
7.50E+00 11.70 15.00 47.70
7.50E+00 12.92 15.00 47.70
7.50E+00 28.32 15.00 47.70
7.50E+00 18.00 15.00 47.70
7.50E+00 9.34 15.00 47.70
7.50E+00 33.27 15.00 47.70
5.53E+01 5.59 15.00 47.70
2.17E+01 18.15 15.00 47.70
1.59E+01 21.93 15.00 47.70 10000 1000
7.50E+00 18.31 15.00 47.70
7.50E+00 12.64 15.00 47.70
7.50E+00 15.25 15.00 47.70
7.50E+00 28.32 15.00 47.70
7.50E+00 8.64 15.00 47.70
7.50E+00 12.44 15.00 47.70
7.50E+00 41.17 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.89E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-314
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Si JaFS-L07-1314-T01-A 1 5.03E+03
Si JaFS-L07-1314-T02-A 1 3.54E+03
Si JaFS-L07-1314-T03-A 1 2.32E+03
Si JaFS-L07-1314-T04-A 1 2.03E+03
Si JaFS-L07-1314-T05-A 1 1.80E+03
Si JaFS-L07-1314-T06-A 1 1.83E+03
Si JaFS-L07-1314-T07-A 1 1.75E+03
Si JaFS-L07-1314-T08-A 1 1.64E+03
Si JaFS-L07-1314-T09-A 1 1.66E+03
Si JaFS-L07-1314-T01-B 1 5.21E+03
Si JaFS-L07-1314-T02-B 1 3.33E+03
Si JaFS-L07-1314-T03-B 1 2.47E+03
Si JaFS-L07-1314-T04-B 1 2.14E+03
Si JaFS-L07-1314-T05-B 1 1.77E+03
Si JaFS-L07-1314-T06-B 1 1.80E+03
Si JaFS-L07-1314-T07-B 1 1.88E+03
Si JaFS-L07-1314-T08-B 1 1.69E+03
Si JaFS-L07-1314-T09-B 1 1.77E+03
Si JaFS-L07-1314-T01-C 1 5.03E+03
Si JaFS-L07-1314-T02-C 1 3.57E+03
Si JaFS-L07-1314-T03-C 1 2.24E+03
Si JaFS-L07-1314-T04-C 1 1.93E+03
Si JaFS-L07-1314-T05-C 1 1.85E+03
Si JaFS-L07-1314-T06-C 1 1.81E+03
Si JaFS-L07-1314-T07-C 1 1.70E+03
Si JaFS-L07-1314-T08-C 1 1.62E+03
Si JaFS-L07-1314-T09-C 1 1.73E+03
Si JaFS-L07-1314-B01-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.03E+03 0.45 1.10 3.50
3.54E+03 2.31 1.10 3.50
2.32E+03 1.11 1.10 3.50 10000 1000
2.03E+03 1.98 1.10 3.50
1.80E+03 0.68 1.10 3.50
1.83E+03 1.01 1.10 3.50
1.75E+03 1.90 1.10 3.50
1.64E+03 0.68 1.10 3.50
1.66E+03 0.90 1.10 3.50
5.21 E+03 1.32 1.10 3.50
3.33E+03 0.87 1.10 3.50
2.47E+03 2.13 1.10 3.50 10000 1000
2.14E+03 2.38 1.10 3.50
1.77E+03 2.30 1.10 3.50
1.80E+03 0.71 1.10 3.50
1.88E+03 0.72 1.10 3.50
1.69E+03 5.00 1.10 3.50
1.77E+03 1.46 1.10 3.50
5.03E+03 1.12 1.10 3.50
3.57E+03 1.53 1.10 3.50
2.24E+03 1.71 1.10 3.50 10000 1000
1.93E+03 0.80 1.10 3.50
1.85E+03 0.64 1.10 3.50
1.81E+03 1.12 1.10 3.50
1.70E+03 0.17 1.10 3.50
1.62E+03 0.60 1.10 3.50
1.73E+03 0.11 1.10 3.50
5.50E-01 17.78 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.22E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.40E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.21E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-315
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
ug/L
Na JaFS-L07-1314-T01-A 1 2.15E+05
Na JaFS-L07-1314-T02-A 1 1.11E+05
Na JaFS-L07-1314-T03-A 1 4.00E+04
Na JaFS-L07-1314-T04-A 1 1.94E+04
Na JaFS-L07-1314-T05-A 1 8.24E+03
Na JaFS-L07-1314-T06-A 1 1.22E+03
Na JaFS-L07-1314-T07-A 1 5.22E+02
Na JaFS-L07-1314-T08-A 1 3.74E+02
Na JaFS-L07-1314-T09-A 1 2.68E+02
Na JaFS-L07-1314-T01-B 1 2.04E+05
Na JaFS-L07-1314-T02-B 1 1.02E+05
Na JaFS-L07-1314-T03-B 1 3.95E+04
Na JaFS-L07-1314-T04-B 1 1.62E+04
Na JaFS-L07-1314-T05-B 1 5.32E+03
Na JaFS-L07-1314-T06-B 1 9.54E+02
Na JaFS-L07-1314-T07-B 1 5.07E+02
Na JaFS-L07-1314-T08-B 1 3.69E+02
Na JaFS-L07-1314-T09-B 1 2.83E+02
Na JaFS-L07-1314-T01-C 1 2.04E+05
Na JaFS-L07-1314-T02-C 1 1.07E+05
Na JaFS-L07-1314-T03-C 1 3.84E+04
Na JaFS-L07-1314-T04-C 1 1.67E+04
Na JaFS-L07-1314-T05-C 1 5.89E+03
Na JaFS-L07-1314-T06-C 1 1.01E+03
Na JaFS-L07-1314-T07-C 1 5.11E+02
Na JaFS-L07-1314-T08-C 1 3.67E+02
Na JaFS-L07-1314-T09-C 1 2.64E+02
Na JaFS-L07-1314-B01-A 1 1.25E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.15E+05 1.01 2.50 8.00
1.11E+05 0.47 2.50 8.00
4.00E+04 1.05 2.50 8.00 10000 1000
1.94E+04 0.66 2.50 8.00
8.24E+03 0.73 2.50 8.00
1.22E+03 0.73 2.50 8.00
5.22E+02 0.85 2.50 8.00
3.74E+02 0.78 2.50 8.00
2.68E+02 0.66 2.50 8.00
2.04E+05 0.16 2.50 8.00
1.02E+05 0.40 2.50 8.00
3.95E+04 1.01 2.50 8.00 10000 1000
1.62E+04 0.57 2.50 8.00
5.32E+03 0.29 2.50 8.00
9.54E+02 1.11 2.50 8.00
5.07E+02 0.30 2.50 8.00
3.69E+02 3.07 2.50 8.00
2.83E+02 0.93 2.50 8.00
2.04E+05 0.35 2.50 8.00
1.07E+05 0.42 2.50 8.00
3.84E+04 0.63 2.50 8.00 10000 1000
1.67E+04 0.84 2.50 8.00
5.89E+03 0.50 2.50 8.00
1.01E+03 0.42 2.50 8.00
5.11E+02 0.12 2.50 8.00
3.67E+02 0.37 2.50 8.00
2.64E+02 0.91 2.50 8.00
1.25E+00 0.06 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.09E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.04E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.93E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-316
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Sr JaFS-L07-1314-T01-A 1 8.54E+03
Sr JaFS-L07-1314-T02-A 1 1.35E+03
Sr JaFS-L07-1314-T03-A 1 6.80E+02
Sr JaFS-L07-1314-T04-A 1 4.33E+02
Sr JaFS-L07-1314-T05-A 1 3.98E+02
Sr JaFS-L07-1314-T06-A 1 3.35E+02
Sr JaFS-L07-1314-T07-A 1 3.09E+02
Sr JaFS-L07-1314-T08-A 1 2.63E+02
Sr JaFS-L07-1314-T09-A 1 2.41E+02
Sr JaFS-L07-1314-T01-B 1 9.15E+03
Sr JaFS-L07-1314-T02-B 1 1.39E+03
Sr JaFS-L07-1314-T03-B 1 7.12E+02
Sr JaFS-L07-1314-T04-B 1 4.39E+02
Sr JaFS-L07-1314-T05-B 1 4.34E+02
Sr JaFS-L07-1314-T06-B 1 3.31E+02
Sr JaFS-L07-1314-T07-B 1 2.97E+02
Sr JaFS-L07-1314-T08-B 1 2.54E+02
Sr JaFS-L07-1314-T09-B 1 2.54E+02
Sr JaFS-L07-1314-T01-C 1 8.40E+03
Sr JaFS-L07-1314-T02-C 1 1.33E+03
Sr JaFS-L07-1314-T03-C 1 6.90E+02
Sr JaFS-L07-1314-T04-C 1 4.05E+02
Sr JaFS-L07-1314-T05-C 1 4.07E+02
Sr JaFS-L07-1314-T06-C 1 3.34E+02
Sr JaFS-L07-1314-T07-C 1 2.98E+02
Sr JaFS-L07-1314-T08-C 1 2.57E+02
Sr JaFS-L07-1314-T09-C 1 2.42E+02
Sr JaFS-L07-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.54E+03 0.75 1.00 3.18
1.35E+03 1.97 1.00 3.18
6.80E+02 1.30 1.00 3.18 10000 1000
4.33E+02 1.67 1.00 3.18
3.98E+02 1.18 1.00 3.18
3.35E+02 1.23 1.00 3.18
3.09E+02 1.62 1.00 3.18
2.63E+02 0.61 1.00 3.18
2.41E+02 1.02 1.00 3.18
9.15E+03 2.27 1.00 3.18
1.39E+03 0.65 1.00 3.18
7.12E+02 2.23 1.00 3.18 10000 1000
4.39E+02 2.65 1.00 3.18
4.34E+02 1.78 1.00 3.18
3.31E+02 0.26 1.00 3.18
2.97E+02 0.84 1.00 3.18
2.54E+02 4.55 1.00 3.18
2.54E+02 1.37 1.00 3.18
8.40E+03 2.14 1.00 3.18
1.33E+03 1.72 1.00 3.18
6.90E+02 1.87 1.00 3.18 10000 1000
4.05E+02 0.66 1.00 3.18
4.07E+02 0.77 1.00 3.18
3.34E+02 0.88 1.00 3.18
2.98E+02 0.64 1.00 3.18
2.57E+02 0.67 1.00 3.18
2.42E+02 0.22 1.00 3.18
5.00E-01 16.70 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.65E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.72E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.68E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-317
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
S JaFS-L07-1314-T01-A 1 5.44E+05
S JaFS-L07-1314-T02-A 1 4.68E+04
S JaFS-L07-1314-T03-A 1 1.31E+04
S JaFS-L07-1314-T04-A 1 7.34E+03
S JaFS-L07-1314-T05-A 1 4.06E+03
S JaFS-L07-1314-T06-A 1 2.38E+03
S JaFS-L07-1314-T07-A 1 2.03E+03
S JaFS-L07-1314-T08-A 1 1.45E+03
S JaFS-L07-1314-T09-A 1 1.09E+03
S JaFS-L07-1314-T01-B 1 5.56E+05
S JaFS-L07-1314-T02-B 1 5.07E+04
S JaFS-L07-1314-T03-B 1 1.22E+04
S JaFS-L07-1314-T04-B 1 8.09E+03
S JaFS-L07-1314-T05-B 1 4.71E+03
S JaFS-L07-1314-T06-B 1 2.39E+03
S JaFS-L07-1314-T07-B 1 2.08E+03
S JaFS-L07-1314-T08-B 1 1.37E+03
S JaFS-L07-1314-T09-B 1 1.32E+03
S JaFS-L07-1314-T01-C 1 5.24E+05
S JaFS-L07-1314-T02-C 1 4.82E+04
S JaFS-L07-1314-T03-C 1 1.25E+04
S JaFS-L07-1314-T04-C 1 6.00E+03
S JaFS-L07-1314-T05-C 1 3.80E+03
S JaFS-L07-1314-T06-C 1 2.38E+03
S JaFS-L07-1314-T07-C 1 2.16E+03
S JaFS-L07-1314-T08-C 1 1.41E+03
S JaFS-L07-1314-T09-C 1 1.04E+03
S JaFS-L07-1314-B01-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.44E+05 0.11 6.80 21.60
4.68E+04 1.95 6.80 21.60
1.31E+04 0.75 6.80 21.60 10000 1000
7.34E+03 0.39 6.80 21.60
4.06E+03 1.46 6.80 21.60
2.38E+03 0.64 6.80 21.60
2.03E+03 4.03 6.80 21.60
1.45E+03 1.12 6.80 21.60
1.09E+03 1.84 6.80 21.60
5.56E+05 1.56 6.80 21.60
5.07E+04 0.89 6.80 21.60
1.22E+04 2.23 6.80 21.60 10000 1000
8.09E+03 2.72 6.80 21.60
4.71 E+03 1.88 6.80 21.60
2.39E+03 0.74 6.80 21.60
2.08E+03 0.85 6.80 21.60
1.37E+03 3.67 6.80 21.60
1.32E+03 0.87 6.80 21.60
5.24E+05 1.19 6.80 21.60
4.82E+04 1.50 6.80 21.60
1.25E+04 1.14 6.80 21.60 10000 1000
6.00E+03 0.68 6.80 21.60
3.80E+03 0.61 6.80 21.60
2.38E+03 1.72 6.80 21.60
2.16E+03 1.86 6.80 21.60
1.41 E+03 0.63 6.80 21.60
1.04E+03 2.43 6.80 21.60
3.40E+00 22.03 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 .40E+04 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.31E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.34E+04 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-318
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
Tl JaFS-L07-1314-T01-A 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T02-A 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T03-A 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T04-A 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T05-A 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T06-A 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T07-A 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T08-A 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T09-A 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T01-B 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T02-B 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T03-B 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T04-B 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T05-B 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T06-B 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T07-B 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T08-B 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T09-B 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T01-C 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T02-C 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T03-C 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T04-C 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T05-C 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T06-C 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T07-C 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T08-C 1 2.30E+00 U1/2
Tl JaFS-L07-1314-T09-C 1 2.30E+00 U1/2
Tl JaFS-L07-1314-B01-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 6.73 4.60 14.60
2.30E+00 6.66 4.60 14.60
2.30E+00 12.17 4.60 14.60 10000 1000
2.30E+00 28.57 4.60 14.60
2.30E+00 39.91 4.60 14.60
2.30E+00 71.24 4.60 14.60
2.30E+00 28.09 4.60 14.60
2.30E+00 27.43 4.60 14.60
2.30E+00 67.91 4.60 14.60
2.30E+00 40.59 4.60 14.60
2.30E+00 75.17 4.60 14.60
2.30E+00 76.82 4.60 14.60 10000 1000
2.30E+00 29.53 4.60 14.60
2.30E+00 63.94 4.60 14.60
2.30E+00 19.47 4.60 14.60
2.30E+00 9.20 4.60 14.60
2.30E+00 21.45 4.60 14.60
2.30E+00 16.18 4.60 14.60
2.30E+00 56.84 4.60 14.60
2.30E+00 22.70 4.60 14.60
2.30E+00 23.25 4.60 14.60 10000 1000
2.30E+00 20.79 4.60 14.60
2.30E+00 18.18 4.60 14.60
2.30E+00 42.05 4.60 14.60
2.30E+00 37.63 4.60 14.60
2.30E+00 16.52 4.60 14.60
2.30E+00 26.25 4.60 14.60
2.30E+00 33.25 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.49E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.26E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.68E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-319
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
Ti JaFS-L07-1314-T01-A 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T02-A 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T03-A 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T04-A 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T05-A 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T06-A 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T07-A 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T08-A 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T09-A 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T01-B 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T02-B 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T03-B 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T04-B 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T05-B 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T06-B 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T07-B 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T08-B 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T09-B 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T01-C 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T02-C 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T03-C 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T04-C 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T05-C 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T06-C 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T07-C 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T08-C 1 1.00E+00 U1/2
Ti JaFS-L07-1314-T09-C 1 1.00E+00 U1/2
Ti JaFS-L07-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 39.67 2.00 6.40
1.00E+00 41.25 2.00 6.40
1.00E+00 16.82 2.00 6.40 10000 1000
1.00E+00 45.15 2.00 6.40
1.00E+00 39.41 2.00 6.40
1.00E+00 14.30 2.00 6.40
1.00E+00 19.66 2.00 6.40
1.00E+00 8.70 2.00 6.40
1.00E+00 53.13 2.00 6.40
1.00E+00 36.77 2.00 6.40
1.00E+00 34.83 2.00 6.40
1.00E+00 15.59 2.00 6.40 10000 1000
1.00E+00 12.82 2.00 6.40
1.00E+00 5.73 2.00 6.40
1.00E+00 9.31 2.00 6.40
1.00E+00 30.20 2.00 6.40
1.00E+00 25.06 2.00 6.40
1.00E+00 51.56 2.00 6.40
1.00E+00 42.51 2.00 6.40
1.00E+00 12.77 2.00 6.40
1.00E+00 62.37 2.00 6.40 10000 1000
1.00E+00 19.21 2.00 6.40
1.00E+00 34.00 2.00 6.40
1.00E+00 16.10 2.00 6.40
1.00E+00 29.16 2.00 6.40
1.00E+00 29.58 2.00 6.40
1.00E+00 23.76 2.00 6.40
1.00E+00 23.64 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.95E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.76E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.72E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-320
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
V JaFS-L07-1314-T01-A 1 1.55E+01
V JaFS-L07-1314-T02-A 1 5.19E+00
V JaFS-L07-1314-T03-A 1 1.68E+00 E
V JaFS-L07-1314-T04-A 1 7.50E-01 U1/2
V JaFS-L07-1314-T05-A 1 7.50E-01 U1/2
V JaFS-L07-1314-T06-A 1 7.50E-01 U1/2
V JaFS-L07-1314-T07-A 1 7.50E-01 U1/2
V JaFS-L07-1314-T08-A 1 7.50E-01 U1/2
V JaFS-L07-1314-T09-A 1 7.50E-01 U1/2
V JaFS-L07-1314-T01-B 1 1.45E+01
V JaFS-L07-1314-T02-B 1 5.90E+00
V JaFS-L07-1314-T03-B 1 2.34E+00 E
V JaFS-L07-1314-T04-B 1 7.50E-01 U1/2
V JaFS-L07-1314-T05-B 1 7.50E-01 U1/2
V JaFS-L07-1314-T06-B 1 7.50E-01 U1/2
V JaFS-L07-1314-T07-B 1 7.50E-01 U1/2
V JaFS-L07-1314-T08-B 1 7.50E-01 U1/2
V JaFS-L07-1314-T09-B 1 7.50E-01 U1/2
V JaFS-L07-1314-T01-C 1 1.63E+01
V JaFS-L07-1314-T02-C 1 6.27E+00
V JaFS-L07-1314-T03-C 1 2.03E+00 E
V JaFS-L07-1314-T04-C 1 7.50E-01 U1/2
V JaFS-L07-1314-T05-C 1 7.50E-01 U1/2
V JaFS-L07-1314-T06-C 1 7.50E-01 U1/2
V JaFS-L07-1314-T07-C 1 7.50E-01 U1/2
V JaFS-L07-1314-T08-C 1 7.50E-01 U1/2
V JaFS-L07-1314-T09-C 1 7.50E-01 U1/2
V JaFS-L07-1314-B01-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.55E+01 1.04 1.50 4.77
5.19E+00 1.82 1.50 4.77
1.68E+00 32.93 1.50 4.77 10000 1000
7.50E-01 43.57 1.50 4.77
7.50E-01 59.54 1.50 4.77
7.50E-01 4.37 1.50 4.77
7.50E-01 39.86 1.50 4.77
7.50E-01 69.74 1.50 4.77
7.50E-01 33.25 1.50 4.77
1.45E+01 1.19 1.50 4.77
5.90E+00 1.65 1.50 4.77
2.34E+00 3.82 1.50 4.77 10000 1000
7.50E-01 30.13 1.50 4.77
7.50E-01 36.49 1.50 4.77
7.50E-01 24.91 1.50 4.77
7.50E-01 52.51 1.50 4.77
7.50E-01 14.92 1.50 4.77
7.50E-01 19.82 1.50 4.77
1.63E+01 7.50 1.50 4.77
6.27E+00 2.35 1.50 4.77
2.03E+00 3.41 1.50 4.77 10000 1000
7.50E-01 29.70 1.50 4.77
7.50E-01 44.63 1.50 4.77
7.50E-01 53.19 1.50 4.77
7.50E-01 61.39 1.50 4.77
7.50E-01 42.69 1.50 4.77
7.50E-01 23.59 1.50 4.77
7.50E-01 54.70 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.47E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.15E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.67E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-321
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Zn JaFS-L07-1314-T01-A 1 1.25E+03
Zn JaFS-L07-1314-T02-A 1 5.39E+02
Zn JaFS-L07-1314-T03-A 1 2.16E+02
Zn JaFS-L07-1314-T04-A 1 9.80E+01
Zn JaFS-L07-1314-T05-A 1 6.79E+01
Zn JaFS-L07-1314-T06-A 1 4.71E+01
Zn JaFS-L07-1314-T07-A 1 3.44E+01
Zn JaFS-L07-1314-T08-A 1 2.17E+01
Zn JaFS-L07-1314-T09-A 1 1.79E+01
Zn JaFS-L07-1314-T01-B 1 1.29E+03
Zn JaFS-L07-1314-T02-B 1 5.18E+02
Zn JaFS-L07-1314-T03-B 1 1.73E+02
Zn JaFS-L07-1314-T04-B 1 8.45E+01
Zn JaFS-L07-1314-T05-B 1 6.01E+01
Zn JaFS-L07-1314-T06-B 1 5.10E+01
Zn JaFS-L07-1314-T07-B 1 3.98E+01
Zn JaFS-L07-1314-T08-B 1 2.82E+01
Zn JaFS-L07-1314-T09-B 1 1.64E+01
Zn JaFS-L07-1314-T01-C 1 1.23E+03
Zn JaFS-L07-1314-T02-C 1 5.16E+02
Zn JaFS-L07-1314-T03-C 1 1.51E+02
Zn JaFS-L07-1314-T04-C 1 7.46E+01
Zn JaFS-L07-1314-T05-C 1 4.94E+01
Zn JaFS-L07-1314-T06-C 1 3.63E+01
Zn JaFS-L07-1314-T07-C 1 2.86E+01
Zn JaFS-L07-1314-T08-C 1 2.18E+01
Zn JaFS-L07-1314-T09-C 1 1.71E+01
Zn JaFS-L07-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.25E+03 0.77 1.00 3.18
5.39E+02 2.35 1.00 3.18
2.16E+02 0.75 1.00 3.18 10000 1000
9.80E+01 1.31 1.00 3.18
6.79E+01 1.42 1.00 3.18
4.71E+01 1.31 1.00 3.18
3.44E+01 1.11 1.00 3.18
2.17E+01 1.82 1.00 3.18
1.79E+01 0.89 1.00 3.18
1.29E+03 1.43 1.00 3.18
5.18E+02 1.61 1.00 3.18
1.73E+02 1.96 1.00 3.18 10000 1000
8.45E+01 2.14 1.00 3.18
6.01E+01 2.10 1.00 3.18
5.10E+01 1.57 1.00 3.18
3.98E+01 1.02 1.00 3.18
2.82E+01 2.78 1.00 3.18
1.64E+01 0.21 1.00 3.18
1.23E+03 0.91 1.00 3.18
5.16E+02 1.69 1.00 3.18
1.51E+02 0.78 1.00 3.18 10000 1000
7.46E+01 0.42 1.00 3.18
4.94E+01 0.48 1.00 3.18
3.63E+01 2.46 1.00 3.18
2.86E+01 1.59 1.00 3.18
2.18E+01 1.31 1.00 3.18
1.71E+01 1.25 1.00 3.18
5.00E-01 3.63 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.25E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 12:31 PM EPA Interlab L07 1314 JaFS
1/12/12 12:33 PM EPA Interlab L07 1314 JaFS
1/12/12 12:34 PM EPA Interlab L07 1314 JaFS
1/12/12 12:36 PM EPA Interlab L07 1314 JaFS
1/12/12 12:38 PM EPA Interlab L07 1314 JaFS
1/12/12 12:39 PM EPA Interlab L07 1314 JaFS
1/12/12 12:41 PM EPA Interlab L07 1314 JaFS
1/12/12 12:43 PM EPA Interlab L07 1314 JaFS
1/12/12 12:44 PM EPA Interlab L07 1314 JaFS
1/12/12 12:52 PM EPA Interlab L07 1314 JaFS
1/12/12 12:54 PM EPA Interlab L07 1314 JaFS
1/12/12 12:56 PM EPA Interlab L07 1314 JaFS
1/12/12 12:57 PM EPA Interlab L07 1314 JaFS
1/12/12 12:59 PM EPA Interlab L07 1314 JaFS
1/12/12 1:01 PM EPA Interlab L07 1314 JaFS
1/12/12 1:02 PM EPA Interlab L07 1314 JaFS
1/12/12 1:04 PM EPA Interlab L07 1314 JaFS
1/12/12 1:06 PM EPA Interlab L07 1314 JaFS
1/12/12 1:07 PM EPA Interlab L07 1314 JaFS
1/12/12 1:09 PM EPA Interlab L07 1314 JaFS
1/12/12 1:11 PM EPA Interlab L07 1314 JaFS
1/12/12 1:12 PM EPA Interlab L07 1314 JaFS
1/12/12 1:14 PM EPA Interlab L07 1314 JaFS
1/12/12 1:16 PM EPA Interlab L07 1314 JaFS
1/12/12 1:17 PM EPA Interlab L07 1314 JaFS
1/12/12 1:19 PM EPA Interlab L07 1314 JaFS
1/12/12 1:21 PM EPA Interlab L07 1314 JaFS
1/12/12 12:16 PM EPA Interlab L07 1314 JaFS
1-322
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1314:
Dilution Sample
Element Sample ID Factor Cone. Qualifier
I I I M9/L I
Al JaFS-L10-1314-T01-A 1 6.75E+01
Al JaFS-L10-1314-T02-A 1 5.74E+01
Al JaFS-L10-1314-T03-A 1 2.86E+01
Al JaFS-L10-1314-T04-A 1 1.66E+01
Al JaFS-L10-1314-T05-A 1 1.40E+01
Al JaFS-L10-1314-T06-A 1 1.30E+01
Al JaFS-L10-1314-T07-A 1 1.29E+01
Al JaFS-L10-1314-T08-A 1 8.89E+00
Al JaFS-L10-1314-T09-A 1 9.80E+00
Al JaFS-L10-1314-T01-B 1 7.04E+01
Al JaFS-L10-1314-T02-B 1 6.61E+01
Al JaFS-L10-1314-T03-B 1 3.16E+01
Al JaFS-L10-1314-T04-B 1 2.37E+01
Al JaFS-L10-1314-T05-B 1 2.20E+01
Al JaFS-L10-1314-T06-B 1 1.43E+01
Al JaFS-L10-1314-T07-B 1 1.25E+01
Al JaFS-L10-1314-T08-B 1 1.02E+01
Al JaFS-L10-1314-T09-B 1 1.04E+01
Al JaFS-L10-1314-T01-C 1 6.69E+01
Al JaFS-L10-1314-T02-C 1 6.30E+01
Al JaFS-L10-1314-T03-C 1 2.80E+01
Al JaFS-L10-1314-T04-C 1 1.47E+01
Al JaFS-L10-1314-T05-C 1 1.27E+01
Al JaFS-L10-1314-T06-C 1 1.07E+01
Al JaFS-L10-1314-T07-C 1 1.11E+01
Al JaFS-L10-1314-T08-C 1 6.11E+00
Al JaFS-L10-1314-T09-C 1 6.46E+00
Al JaFS-L10-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.75E+01 2.05 1.00 3.18
5.74E+01 4.47 1.00 3.18
2.86E+01 1.94 1.00 3.18 10000 1000
1.66E+01 4.01 1.00 3.18
1.40E+01 4.77 1.00 3.18
1.30E+01 3.09 1.00 3.18
1.29E+01 2.43 1.00 3.18
8.89E+00 7.95 1.00 3.18
9.80E+00 5.44 1.00 3.18
7.04E+01 2.48 1.00 3.18
6.61E+01 1.74 1.00 3.18
3.16E+01 3.82 1.00 3.18 10000 1000
2.37E+01 0.92 1.00 3.18
2.20E+01 2.02 1.00 3.18
1.43E+01 2.41 1.00 3.18
1.25E+01 5.14 1.00 3.18
1.02E+01 2.90 1.00 3.18
1.04E+01 5.64 1.00 3.18
6.69E+01 2.99 1.00 3.18
6.30E+01 2.41 1.00 3.18
2.80E+01 1.58 1.00 3.18 10000 1000
1.47E+01 2.43 1.00 3.18
1.27E+01 2.87 1.00 3.18
1.07E+01 8.61 1.00 3.18
1.11E+01 6.25 1.00 3.18
6.11E+00 2.88 1.00 3.18
6.46E+00 4.39 1.00 3.18
5.00E-01 6.41 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 . 1 0E+03 1 08% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-323
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Sb JaFS-L10-1314-T01-A 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T02-A 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T03-A 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T04-A 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T05-A 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T06-A 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T07-A 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T08-A 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T09-A 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T01-B 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T02-B 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T03-B 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T04-B 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T05-B 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T06-B 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T07-B 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T08-B 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T09-B 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T01-C 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T02-C 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T03-C 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T04-C 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T05-C 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T06-C 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T07-C 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T08-C 1 3.75E+00 U1/2
Sb JaFS-L10-1314-T09-C 1 3.75E+00 U1/2
Sb JaFS-L10-1314-B01-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.75E+00 17.81 7.50 23.90
3.75E+00 65.11 7.50 23.90
3.75E+00 29.12 7.50 23.90 10000 1000
3.75E+00 61.22 7.50 23.90
3.75E+00 58.90 7.50 23.90
3.75E+00 32.12 7.50 23.90
3.75E+00 14.98 7.50 23.90
3.75E+00 50.21 7.50 23.90
3.75E+00 19.83 7.50 23.90
3.75E+00 37.47 7.50 23.90
3.75E+00 29.25 7.50 23.90
3.75E+00 8.18 7.50 23.90 10000 1000
3.75E+00 15.67 7.50 23.90
3.75E+00 11.62 7.50 23.90
3.75E+00 33.10 7.50 23.90
3.75E+00 9.98 7.50 23.90
3.75E+00 49.24 7.50 23.90
3.75E+00 73.19 7.50 23.90
3.75E+00 55.66 7.50 23.90
3.75E+00 11.11 7.50 23.90
3.75E+00 33.92 7.50 23.90 10000 1000
3.75E+00 31.03 7.50 23.90
3.75E+00 16.36 7.50 23.90
3.75E+00 30.57 7.50 23.90
3.75E+00 65.47 7.50 23.90
3.75E+00 6.39 7.50 23.90
3.75E+00 9.25 7.50 23.90
3.75E+00 55.52 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.33E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.11E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-324
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
As JaFS-L10-1314-T01-A 1 5.50E+00 U1/2
As JaFS-L10-1314-T02-A 1 5.50E+00 U1/2
As JaFS-L10-1314-T03-A 1 5.50E+00 U1/2
As JaFS-L10-1314-T04-A 1 5.50E+00 U1/2
As JaFS-L10-1314-T05-A 1 5.50E+00 U1/2
As JaFS-L10-1314-T06-A 1 5.50E+00 U1/2
As JaFS-L10-1314-T07-A 1 5.50E+00 U1/2
As JaFS-L10-1314-T08-A 1 5.50E+00 U1/2
As JaFS-L10-1314-T09-A 1 5.50E+00 U1/2
As JaFS-L10-1314-T01-B 1 5.50E+00 U1/2
As JaFS-L10-1314-T02-B 1 5.50E+00 U1/2
As JaFS-L10-1314-T03-B 1 5.50E+00 U1/2
As JaFS-L10-1314-T04-B 1 5.50E+00 U1/2
As JaFS-L10-1314-T05-B 1 5.50E+00 U1/2
As JaFS-L10-1314-T06-B 1 5.50E+00 U1/2
As JaFS-L10-1314-T07-B 1 5.50E+00 U1/2
As JaFS-L10-1314-T08-B 1 5.50E+00 U1/2
As JaFS-L10-1314-T09-B 1 5.50E+00 U1/2
As JaFS-L10-1314-T01-C 1 5.50E+00 U1/2
As JaFS-L10-1314-T02-C 1 5.50E+00 U1/2
As JaFS-L10-1314-T03-C 1 5.50E+00 U1/2
As JaFS-L10-1314-T04-C 1 5.50E+00 U1/2
As JaFS-L10-1314-T05-C 1 5.50E+00 U1/2
As JaFS-L10-1314-T06-C 1 5.50E+00 U1/2
As JaFS-L10-1314-T07-C 1 5.50E+00 U1/2
As JaFS-L10-1314-T08-C 1 5.50E+00 U1/2
As JaFS-L10-1314-T09-C 1 5.50E+00 U1/2
As JaFS-L10-1314-B01-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.50E+00 32.79 11.00 35.00
5.50E+00 19.47 11.00 35.00
5.50E+00 35.42 11.00 35.00 10000 1000
5.50E+00 21.60 11.00 35.00
5.50E+00 39.39 11.00 35.00
5.50E+00 14.13 11.00 35.00
5.50E+00 13.62 11.00 35.00
5.50E+00 36.96 11.00 35.00
5.50E+00 50.62 11.00 35.00
5.50E+00 22.38 11.00 35.00
5.50E+00 18.23 11.00 35.00
5.50E+00 49.45 11.00 35.00 10000 1000
5.50E+00 38.04 11.00 35.00
5.50E+00 32.65 11.00 35.00
5.50E+00 34.43 11.00 35.00
5.50E+00 51.44 11.00 35.00
5.50E+00 39.36 11.00 35.00
5.50E+00 66.72 11.00 35.00
5.50E+00 56.51 11.00 35.00
5.50E+00 38.73 11.00 35.00
5.50E+00 26.83 11.00 35.00 10000 1000
5.50E+00 67.27 11.00 35.00
5.50E+00 24.78 11.00 35.00
5.50E+00 11.89 11.00 35.00
5.50E+00 60.08 11.00 35.00
5.50E+00 44.46 11.00 35.00
5.50E+00 31.36 11.00 35.00
5.50E+00 35.59 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.95E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.36E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.28E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-325
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
B JaFS-L10-1314-T01-A 1 1.13E+05
B JaFS-L10-1314-T02-A 1 5.62E+04
B JaFS-L10-1314-T03-A 1 1.82E+04
B JaFS-L10-1314-T04-A 1 8.67E+03
B JaFS-L10-1314-T05-A 1 5.58E+03
B JaFS-L10-1314-T06-A 1 2.88E+03
B JaFS-L10-1314-T07-A 1 1.64E+03
B JaFS-L10-1314-T08-A 1 1.07E+03
B JaFS-L10-1314-T09-A 1 8.89E+02
B JaFS-L10-1314-T01-B 1 1.08E+05
B JaFS-L10-1314-T02-B 1 8.49E+04
B JaFS-L10-1314-T03-B 1 2.97E+04
B JaFS-L10-1314-T04-B 1 1.19E+04
B JaFS-L10-1314-T05-B 1 7.23E+03
B JaFS-L10-1314-T06-B 1 3.48E+03
B JaFS-L10-1314-T07-B 1 2.03E+03
B JaFS-L10-1314-T08-B 1 1.26E+03
B JaFS-L10-1314-T09-B 1 9.67E+02
B JaFS-L10-1314-T01-C 1 9.42E+04
B JaFS-L10-1314-T02-C 1 7.09E+04
B JaFS-L10-1314-T03-C 1 3.99E+04
B JaFS-L10-1314-T04-C 1 1.44E+04
B JaFS-L10-1314-T05-C 1 8.35E+03
B JaFS-L10-1314-T06-C 1 3.85E+03
B JaFS-L10-1314-T07-C 1 2.17E+03
B JaFS-L10-1314-T08-C 1 1.33E+03
B JaFS-L10-1314-T09-C 1 8.57E+02
B JaFS-L10-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.13E+05 3.33 1.00 3.18
5.62E+04 5.97 1.00 3.18
1.82E+04 1.09 1.00 3.18 10000 1000
8.67E+03 0.58 1.00 3.18
5.58E+03 1.20 1.00 3.18
2.88E+03 5.03 1.00 3.18
1.64E+03 2.48 1.00 3.18
1.07E+03 1.23 1.00 3.18
8.89E+02 2.20 1.00 3.18
1.08E+05 3.14 1.00 3.18
8.49E+04 1.70 1.00 3.18
2.97E+04 1.34 1.00 3.18 10000 1000
1.19E+04 1.43 1.00 3.18
7.23E+03 1.77 1.00 3.18
3.48E+03 0.68 1.00 3.18
2.03E+03 2.01 1.00 3.18
1.26E+03 1.47 1.00 3.18
9.67E+02 2.22 1.00 3.18
9.42E+04 0.28 1.00 3.18
7.09E+04 0.25 1.00 3.18
3.99E+04 1.08 1.00 3.18 10000 1000
1.44E+04 0.58 1.00 3.18
8.35E+03 2.15 1.00 3.18
3.85E+03 0.72 1.00 3.18
2.17E+03 1.06 1.00 3.18
1.33E+03 0.97 1.00 3.18
8.57E+02 0.83 1.00 3.18
5.00E-01 3.69 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.91E+04 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.06E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.08E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-326
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Ba JaFS-L10-1314-T01-A 1 1.26E+02
Ba JaFS-L10-1314-T02-A 1 6.31E+01
Ba JaFS-L10-1314-T03-A 1 4.80E+01
Ba JaFS-L10-1314-T04-A 1 3.67E+01
Ba JaFS-L10-1314-T05-A 1 3.21E+01
Ba JaFS-L10-1314-T06-A 1 3.05E+01
Ba JaFS-L10-1314-T07-A 1 2.68E+01
Ba JaFS-L10-1314-T08-A 1 2.18E+01
Ba JaFS-L10-1314-T09-A 1 1.96E+01
Ba JaFS-L10-1314-T01-B 1 1.29E+02
Ba JaFS-L10-1314-T02-B 1 6.46E+01
Ba JaFS-L10-1314-T03-B 1 4.94E+01
Ba JaFS-L10-1314-T04-B 1 3.86E+01
Ba JaFS-L10-1314-T05-B 1 3.08E+01
Ba JaFS-L10-1314-T06-B 1 2.90E+01
Ba JaFS-L10-1314-T07-B 1 2.77E+01
Ba JaFS-L10-1314-T08-B 1 2.36E+01
Ba JaFS-L10-1314-T09-B 1 2.16E+01
Ba JaFS-L10-1314-T01-C 1 1.35E+02
Ba JaFS-L10-1314-T02-C 1 7.18E+01
Ba JaFS-L10-1314-T03-C 1 5.25E+01
Ba JaFS-L10-1314-T04-C 1 4.33E+01
Ba JaFS-L10-1314-T05-C 1 3.13E+01
Ba JaFS-L10-1314-T06-C 1 2.90E+01
Ba JaFS-L10-1314-T07-C 1 2.58E+01
Ba JaFS-L10-1314-T08-C 1 2.29E+01
Ba JaFS-L10-1314-T09-C 1 1.79E+01
Ba JaFS-L10-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.26E+02 2.65 1.00 3.18
6.31E+01 4.74 1.00 3.18
4.80E+01 1.08 1.00 3.18 10000 1000
3.67E+01 1.15 1.00 3.18
3.21E+01 1.45 1.00 3.18
3.05E+01 3.43 1.00 3.18
2.68E+01 1.18 1.00 3.18
2.18E+01 1.28 1.00 3.18
1.96E+01 2.74 1.00 3.18
1.29E+02 2.23 1.00 3.18
6.46E+01 1.93 1.00 3.18
4.94E+01 1.96 1.00 3.18 10000 1000
3.86E+01 1.85 1.00 3.18
3.08E+01 1.76 1.00 3.18
2.90E+01 1.26 1.00 3.18
2.77E+01 2.63 1.00 3.18
2.36E+01 1.82 1.00 3.18
2.16E+01 3.31 1.00 3.18
1.35E+02 1.43 1.00 3.18
7.18E+01 0.99 1.00 3.18
5.25E+01 0.83 1.00 3.18 10000 1000
4.33E+01 0.82 1.00 3.18
3.13E+01 2.53 1.00 3.18
2.90E+01 1.01 1.00 3.18
2.58E+01 0.29 1.00 3.18
2.29E+01 1.69 1.00 3.18
1.79E+01 1.21 1.00 3.18
5.00E-01 19.44 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/7/12 11:07 AM EPA Interlab L10 1314 JaFS
3/7/12 11:09 AM EPA Interlab L10 1314 JaFS
3/7/12 11:10 AM EPA Interlab L10 1314 JaFS
3/7/12 11:12 AM EPA Interlab L10 1314 JaFS
3/7/12 11:14 AM EPA Interlab L10 1314 JaFS
3/7/12 11:15 AM EPA Interlab L10 1314 JaFS
3/7/12 11:17 AM EPA Interlab L10 1314 JaFS
3/7/12 11:19 AM EPA Interlab L10 1314 JaFS
3/7/12 11:20 AM EPA Interlab L10 1314 JaFS
3/7/12 11:22 AM EPA Interlab L10 1314 JaFS
3/7/12 11:24 AM EPA Interlab L10 1314 JaFS
3/7/12 11:25 AM EPA Interlab L10 1314 JaFS
3/7/12 11:27 AM EPA Interlab L10 1314 JaFS
3/7/12 11:28 AM EPA Interlab L10 1314 JaFS
3/7/12 11:30 AM EPA Interlab L10 1314 JaFS
3/7/12 11:32 AM EPA Interlab L10 1314 JaFS
3/7/12 11:33 AM EPA Interlab L10 1314 JaFS
3/7/12 11:35 AM EPA Interlab L10 1314 JaFS
3/7/12 11:37 AM EPA Interlab L10 1314 JaFS
3/7/12 11:38 AM EPA Interlab L10 1314 JaFS
3/7/12 11:40 AM EPA Interlab L10 1314 JaFS
3/7/12 11:41 AM EPA Interlab L10 1314 JaFS
3/7/12 11:43 AM EPA Interlab L10 1314 JaFS
3/7/12 11:45 AM EPA Interlab L10 1314 JaFS
3/7/12 11:46 AM EPA Interlab L10 1314 JaFS
3/7/12 11:48 AM EPA Interlab L10 1314 JaFS
3/7/12 11:50 AM EPA Interlab L10 1314 JaFS
3/7/12 11:06 AM EPA Interlab L10 1314 JaFS
1-327
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Be JaFS-L10-1314-T01-A 1 9.50E-01 U1/2
Be JaFS-L10-1314-T02-A 1 9.50E-01 U1/2
Be JaFS-L10-1314-T03-A 1 9.50E-01 U1/2
Be JaFS-L10-1314-T04-A 1 9.50E-01 U1/2
Be JaFS-L10-1314-T05-A 1 9.50E-01 U1/2
Be JaFS-L10-1314-T06-A 1 9.50E-01 U1/2
Be JaFS-L10-1314-T07-A 1 9.50E-01 U1/2
Be JaFS-L10-1314-T08-A 1 9.50E-01 U1/2
Be JaFS-L10-1314-T09-A 1 9.50E-01 U1/2
Be JaFS-L10-1314-T01-B 1 9.50E-01 U1/2
Be JaFS-L10-1314-T02-B 1 9.50E-01 U1/2
Be JaFS-L10-1314-T03-B 1 9.50E-01 U1/2
Be JaFS-L10-1314-T04-B 1 9.50E-01 U1/2
Be JaFS-L10-1314-T05-B 1 9.50E-01 U1/2
Be JaFS-L10-1314-T06-B 1 9.50E-01 U1/2
Be JaFS-L10-1314-T07-B 1 9.50E-01 U1/2
Be JaFS-L10-1314-T08-B 1 9.50E-01 U1/2
Be JaFS-L10-1314-T09-B 1 9.50E-01 U1/2
Be JaFS-L10-1314-T01-C 1 9.50E-01 U1/2
Be JaFS-L10-1314-T02-C 1 9.50E-01 U1/2
Be JaFS-L10-1314-T03-C 1 9.50E-01 U1/2
Be JaFS-L10-1314-T04-C 1 9.50E-01 U1/2
Be JaFS-L10-1314-T05-C 1 9.50E-01 U1/2
Be JaFS-L10-1314-T06-C 1 9.50E-01 U1/2
Be JaFS-L10-1314-T07-C 1 9.50E-01 U1/2
Be JaFS-L10-1314-T08-C 1 9.50E-01 U1/2
Be JaFS-L10-1314-T09-C 1 9.50E-01 U1/2
Be JaFS-L10-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 36.92 1.90 6.00
9.50E-01 25.96 1.90 6.00
9.50E-01 15.22 1.90 6.00 10000 1000
9.50E-01 23.70 1.90 6.00
9.50E-01 30.30 1.90 6.00
9.50E-01 23.19 1.90 6.00
9.50E-01 35.27 1.90 6.00
9.50E-01 16.59 1.90 6.00
9.50E-01 39.47 1.90 6.00
9.50E-01 53.08 1.90 6.00
9.50E-01 63.94 1.90 6.00
9.50E-01 55.21 1.90 6.00 10000 1000
9.50E-01 34.03 1.90 6.00
9.50E-01 39.36 1.90 6.00
9.50E-01 34.76 1.90 6.00
9.50E-01 9.98 1.90 6.00
9.50E-01 27.77 1.90 6.00
9.50E-01 38.84 1.90 6.00
9.50E-01 60.61 1.90 6.00
9.50E-01 72.20 1.90 6.00
9.50E-01 68.80 1.90 6.00 10000 1000
9.50E-01 40.66 1.90 6.00
9.50E-01 44.88 1.90 6.00
9.50E-01 54.99 1.90 6.00
9.50E-01 9.46 1.90 6.00
9.50E-01 50.05 1.90 6.00
9.50E-01 61.61 1.90 6.00
9.50E-01 40.54 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.95E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.48E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.18E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-328
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
Cd JaFS-L10-1314-T01-A 1 9.81E+00
Cd JaFS-L10-1314-T02-A 1 3.06E+00 E
Cd JaFS-L10-1314-T03-A 1 1.10E+00 U1/2
Cd JaFS-L10-1314-T04-A 1 1.10E+00 U1/2
Cd JaFS-L10-1314-T05-A 1 1.10E+00 U1/2
Cd JaFS-L10-1314-T06-A 1 1.10E+00 U1/2
Cd JaFS-L10-1314-T07-A 1 1.10E+00 U1/2
Cd JaFS-L10-1314-T08-A 1 1.10E+00 U1/2
Cd JaFS-L10-1314-T09-A 1 1.10E+00 U1/2
Cd JaFS-L10-1314-T01-B 1 1.18E+01
Cd JaFS-L10-1314-T02-B 1 3.42E+00 E
Cd JaFS-L10-1314-T03-B 1 1.10E+00 U1/2
Cd JaFS-L10-1314-T04-B 1 1.10E+00 U1/2
Cd JaFS-L10-1314-T05-B 1 1.10E+00 U1/2
Cd JaFS-L10-1314-T06-B 1 1.10E+00 U1/2
Cd JaFS-L10-1314-T07-B 1 1.10E+00 U1/2
Cd JaFS-L10-1314-T08-B 1 1.10E+00 U1/2
Cd JaFS-L10-1314-T09-B 1 1.10E+00 U1/2
Cd JaFS-L10-1314-T01-C 1 9.72E+00
Cd JaFS-L10-1314-T02-C 1 4.78E+00 E
Cd JaFS-L10-1314-T03-C 1 2.51E+00 E
Cd JaFS-L10-1314-T04-C 1 1.10E+00 U1/2
Cd JaFS-L10-1314-T05-C 1 1.10E+00 U1/2
Cd JaFS-L10-1314-T06-C 1 1.10E+00 U1/2
Cd JaFS-L10-1314-T07-C 1 1.10E+00 U1/2
Cd JaFS-L10-1314-T08-C 1 1.10E+00 U1/2
Cd JaFS-L10-1314-T09-C 1 1.10E+00 U1/2
Cd JaFS-L10-1314-B01-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.81 E+00 3.94 2.20 7.00
3.06E+00 14.22 2.20 7.00
1.10E+00 6.34 2.20 7.00 10000 1000
1.10E+00 5.13 2.20 7.00
1.10E+00 18.83 2.20 7.00
1.10E+00 4.37 2.20 7.00
1.10E+00 21.18 2.20 7.00
1.10E+00 15.68 2.20 7.00
1.10E+00 19.83 2.20 7.00
1.18E+01 1.95 2.20 7.00
3.42E+00 3.03 2.20 7.00
1.10E+00 12.66 2.20 7.00 10000 1000
1.10E+00 3.53 2.20 7.00
1.10E+00 17.07 2.20 7.00
1.10E+00 16.66 2.20 7.00
1.10E+00 27.90 2.20 7.00
1.10E+00 9.91 2.20 7.00
1.10E+00 6.74 2.20 7.00
9.72E+00 0.26 2.20 7.00
4.78E+00 2.24 2.20 7.00
2.51E+00 6.43 2.20 7.00 10000 1000
1.10E+00 12.82 2.20 7.00
1.10E+00 9.97 2.20 7.00
1.10E+00 19.19 2.20 7.00
1.10E+00 27.45 2.20 7.00
1.10E+00 18.85 2.20 7.00
1.10E+00 47.53 2.20 7.00
1.10E+00 34.15 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.59E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.96E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.69E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-329
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Ca JaFS-L10-1314-T01-A 1 2.09E+05
Ca JaFS-L10-1314-T02-A 1 5.46E+04
Ca JaFS-L10-1314-T03-A 1 2.65E+04
Ca JaFS-L10-1314-T04-A 1 2.64E+04
Ca JaFS-L10-1314-T05-A 1 2.61E+04
Ca JaFS-L10-1314-T06-A 1 2.54E+04
Ca JaFS-L10-1314-T07-A 1 2.49E+04
Ca JaFS-L10-1314-T08-A 1 2.82E+04
Ca JaFS-L10-1314-T09-A 1 3.15E+04
Ca JaFS-L10-1314-T01-B 1 2.39E+05
Ca JaFS-L10-1314-T02-B 1 5.53E+04
Ca JaFS-L10-1314-T03-B 1 2.92E+04
Ca JaFS-L10-1314-T04-B 1 2.58E+04
Ca JaFS-L10-1314-T05-B 1 2.72E+04
Ca JaFS-L10-1314-T06-B 1 2.69E+04
Ca JaFS-L10-1314-T07-B 1 2.76E+04
Ca JaFS-L10-1314-T08-B 1 2.95E+04
Ca JaFS-L10-1314-T09-B 1 3.18E+04
Ca JaFS-L10-1314-T01-C 1 1.77E+05
Ca JaFS-L10-1314-T02-C 1 5.69E+04
Ca JaFS-L10-1314-T03-C 1 2.56E+04
Ca JaFS-L10-1314-T04-C 1 2.88E+04
Ca JaFS-L10-1314-T05-C 1 2.55E+04
Ca JaFS-L10-1314-T06-C 1 2.55E+04
Ca JaFS-L10-1314-T07-C 1 2.66E+04
Ca JaFS-L10-1314-T08-C 1 2.86E+04
Ca JaFS-L10-1314-T09-C 1 3.03E+04
Ca JaFS-L10-1314-B01-A 1 2.72E+04
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.09E+05 2.80 2.60 8.30
5.46E+04 4.91 2.60 8.30
2.65E+04 1.52 2.60 8.30 10000 1000
2.64E+04 1.06 2.60 8.30
2.61 E+04 1.03 2.60 8.30
2.54E+04 2.86 2.60 8.30
2.49E+04 1.09 2.60 8.30
2.82E+04 1.97 2.60 8.30
3.15E+04 1.45 2.60 8.30
2.39E+05 2.76 2.60 8.30
5.53E+04 2.36 2.60 8.30
2.92E+04 2.11 2.60 8.30 10000 1000
2.58E+04 1.43 2.60 8.30
2.72E+04 1.72 2.60 8.30
2.69E+04 0.86 2.60 8.30
2.76E+04 1.49 2.60 8.30
2.95E+04 1.96 2.60 8.30
3.18E+04 1.26 2.60 8.30
1.77E+05 0.87 2.60 8.30
5.69E+04 1.29 2.60 8.30
2.56E+04 0.72 2.60 8.30 10000 1000
2.88E+04 0.39 2.60 8.30
2.55E+04 1.87 2.60 8.30
2.55E+04 0.65 2.60 8.30
2.66E+04 0.88 2.60 8.30
2.86E+04 1.01 2.60 8.30
3.03E+04 0.54 2.60 8.30
2.72E+04 0.65 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.74E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.01 E+04 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.65E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-330
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cr JaFS-L10-1314-T01-A 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T02-A 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T03-A 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T04-A 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T05-A 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T06-A 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T07-A 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T08-A 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T09-A 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T01-B 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T02-B 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T03-B 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T04-B 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T05-B 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T06-B 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T07-B 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T08-B 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T09-B 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T01-C 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T02-C 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T03-C 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T04-C 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T05-C 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T06-C 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T07-C 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T08-C 1 6.00E-01 U1/2
Cr JaFS-L10-1314-T09-C 1 6.00E-01 U1/2
Cr JaFS-L10-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 49.52 1.20 3.82
6.00E-01 38.65 1.20 3.82
6.00E-01 45.31 1.20 3.82 10000 1000
6.00E-01 17.02 1.20 3.82
6.00E-01 22.39 1.20 3.82
6.00E-01 24.27 1.20 3.82
6.00E-01 11.76 1.20 3.82
6.00E-01 24.59 1.20 3.82
6.00E-01 37.44 1.20 3.82
6.00E-01 10.26 1.20 3.82
6.00E-01 66.77 1.20 3.82
6.00E-01 59.53 1.20 3.82 10000 1000
6.00E-01 46.04 1.20 3.82
6.00E-01 41.47 1.20 3.82
6.00E-01 29.46 1.20 3.82
6.00E-01 5.63 1.20 3.82
6.00E-01 29.47 1.20 3.82
6.00E-01 14.56 1.20 3.82
6.00E-01 20.38 1.20 3.82
6.00E-01 22.09 1.20 3.82
6.00E-01 41.21 1.20 3.82 10000 1000
6.00E-01 36.40 1.20 3.82
6.00E-01 42.74 1.20 3.82
6.00E-01 36.80 1.20 3.82
6.00E-01 3.77 1.20 3.82
6.00E-01 11.67 1.20 3.82
6.00E-01 56.03 1.20 3.82
6.00E-01 43.82 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.41E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.07E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-331
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Co JaFS-L10-1314-T01-A 1 9.00E-01 U1/2
Co JaFS-L10-1314-T02-A 1 9.00E-01 U1/2
Co JaFS-L10-1314-T03-A 1 9.00E-01 U1/2
Co JaFS-L10-1314-T04-A 1 9.00E-01 U1/2
Co JaFS-L10-1314-T05-A 1 9.00E-01 U1/2
Co JaFS-L10-1314-T06-A 1 9.00E-01 U1/2
Co JaFS-L10-1314-T07-A 1 9.00E-01 U1/2
Co JaFS-L10-1314-T08-A 1 9.00E-01 U1/2
Co JaFS-L10-1314-T09-A 1 9.00E-01 U1/2
Co JaFS-L10-1314-T01-B 1 9.00E-01 U1/2
Co JaFS-L10-1314-T02-B 1 9.00E-01 U1/2
Co JaFS-L10-1314-T03-B 1 9.00E-01 U1/2
Co JaFS-L10-1314-T04-B 1 9.00E-01 U1/2
Co JaFS-L10-1314-T05-B 1 9.00E-01 U1/2
Co JaFS-L10-1314-T06-B 1 9.00E-01 U1/2
Co JaFS-L10-1314-T07-B 1 9.00E-01 U1/2
Co JaFS-L10-1314-T08-B 1 9.00E-01 U1/2
Co JaFS-L10-1314-T09-B 1 9.00E-01 U1/2
Co JaFS-L10-1314-T01-C 1 9.00E-01 U1/2
Co JaFS-L10-1314-T02-C 1 9.00E-01 U1/2
Co JaFS-L10-1314-T03-C 1 9.00E-01 U1/2
Co JaFS-L10-1314-T04-C 1 9.00E-01 U1/2
Co JaFS-L10-1314-T05-C 1 9.00E-01 U1/2
Co JaFS-L10-1314-T06-C 1 9.00E-01 U1/2
Co JaFS-L10-1314-T07-C 1 9.00E-01 U1/2
Co JaFS-L10-1314-T08-C 1 9.00E-01 U1/2
Co JaFS-L10-1314-T09-C 1 9.00E-01 U1/2
Co JaFS-L10-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 29.15 1.80 5.72
9.00E-01 31.89 1.80 5.72
9.00E-01 36.95 1.80 5.72 10000 1000
9.00E-01 34.90 1.80 5.72
9.00E-01 54.00 1.80 5.72
9.00E-01 32.27 1.80 5.72
9.00E-01 16.19 1.80 5.72
9.00E-01 44.93 1.80 5.72
9.00E-01 48.54 1.80 5.72
9.00E-01 16.77 1.80 5.72
9.00E-01 47.44 1.80 5.72
9.00E-01 37.86 1.80 5.72 10000 1000
9.00E-01 33.65 1.80 5.72
9.00E-01 16.65 1.80 5.72
9.00E-01 31.84 1.80 5.72
9.00E-01 10.72 1.80 5.72
9.00E-01 7.04 1.80 5.72
9.00E-01 44.91 1.80 5.72
9.00E-01 12.67 1.80 5.72
9.00E-01 1.46 1.80 5.72
9.00E-01 56.11 1.80 5.72 10000 1000
9.00E-01 37.70 1.80 5.72
9.00E-01 37.42 1.80 5.72
9.00E-01 68.12 1.80 5.72
9.00E-01 17.50 1.80 5.72
9.00E-01 45.11 1.80 5.72
9.00E-01 22.91 1.80 5.72
9.00E-01 52.50 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.85E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.16E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.92E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-332
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Cu JaFS-L10-1314-T01-A 1 7.61E+02
Cu JaFS-L10-1314-T02-A 1 6.06E+02
Cu JaFS-L10-1314-T03-A 1 3.14E+02
Cu JaFS-L10-1314-T04-A 1 2.11E+02
Cu JaFS-L10-1314-T05-A 1 1.83E+02
Cu JaFS-L10-1314-T06-A 1 1.20E+02
Cu JaFS-L10-1314-T07-A 1 7.62E+01
Cu JaFS-L10-1314-T08-A 1 4.98E+01
Cu JaFS-L10-1314-T09-A 1 3.57E+01
Cu JaFS-L10-1314-T01-B 1 8.84E+02
Cu JaFS-L10-1314-T02-B 1 6.95E+02
Cu JaFS-L10-1314-T03-B 1 4.36E+02
Cu JaFS-L10-1314-T04-B 1 2.39E+02
Cu JaFS-L10-1314-T05-B 1 1.77E+02
Cu JaFS-L10-1314-T06-B 1 1.10E+02
Cu JaFS-L10-1314-T07-B 1 7.26E+01
Cu JaFS-L10-1314-T08-B 1 4.97E+01
Cu JaFS-L10-1314-T09-B 1 3.89E+01
Cu JaFS-L10-1314-T01-C 1 6.11E+02
Cu JaFS-L10-1314-T02-C 1 5.59E+02
Cu JaFS-L10-1314-T03-C 1 4.42E+02
Cu JaFS-L10-1314-T04-C 1 2.53E+02
Cu JaFS-L10-1314-T05-C 1 1.80E+02
Cu JaFS-L10-1314-T06-C 1 1.11E+02
Cu JaFS-L10-1314-T07-C 1 7.27E+01
Cu JaFS-L10-1314-T08-C 1 4.76E+01
Cu JaFS-L10-1314-T09-C 1 3.91E+01
Cu JaFS-L10-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.61E+02 2.18 3.70 11.80
6.06E+02 4.31 3.70 11.80
3.14E+02 1.26 3.70 11.80 10000 1000
2.11E+02 1.57 3.70 11.80
1.83E+02 0.64 3.70 11.80
1.20E+02 3.23 3.70 11.80
7.62E+01 1.33 3.70 11.80
4.98E+01 3.42 3.70 11.80
3.57E+01 0.47 3.70 11.80
8.84E+02 2.37 3.70 11.80
6.95E+02 2.50 3.70 11.80
4.36E+02 1.68 3.70 11.80 10000 1000
2.39E+02 0.59 3.70 11.80
1.77E+02 1.16 3.70 11.80
1.10E+02 0.80 3.70 11.80
7.26E+01 1.82 3.70 11.80
4.97E+01 4.05 3.70 11.80
3.89E+01 1.71 3.70 11.80
6.11E+02 0.47 3.70 11.80
5.59E+02 1.22 3.70 11.80
4.42E+02 0.76 3.70 11.80 10000 1000
2.53E+02 1.64 3.70 11.80
1.80E+02 1.24 3.70 11.80
1.11E+02 0.27 3.70 11.80
7.27E+01 1.23 3.70 11.80
4.76E+01 1.67 3.70 11.80
3.91E+01 1.74 3.70 11.80
1.85E+00 13.46 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.33E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.49E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.46E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11 :57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-333
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Fe JaFS-L10-1314-T01-A 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T02-A 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T03-A 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T04-A 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T05-A 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T06-A 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T07-A 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T08-A 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T09-A 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T01-B 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T02-B 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T03-B 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T04-B 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T05-B 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T06-B 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T07-B 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T08-B 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T09-B 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T01-C 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T02-C 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T03-C 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T04-C 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T05-C 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T06-C 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T07-C 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T08-C 1 1.00E+00 U1/2
Fe JaFS-L10-1314-T09-C 1 1.00E+00 U1/2
Fe JaFS-L10-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 4.48 2.00 6.40
1.00E+00 11.07 2.00 6.40
1.00E+00 4.44 2.00 6.40 10000 1000
1.00E+00 25.64 2.00 6.40
1.00E+00 16.40 2.00 6.40
1.00E+00 5.82 2.00 6.40
1.00E+00 3.24 2.00 6.40
1.00E+00 5.40 2.00 6.40
1.00E+00 3.67 2.00 6.40
1.00E+00 1.51 2.00 6.40
1.00E+00 6.03 2.00 6.40
1.00E+00 3.43 2.00 6.40 10000 1000
1.00E+00 15.66 2.00 6.40
1.00E+00 9.24 2.00 6.40
1.00E+00 7.84 2.00 6.40
1.00E+00 10.18 2.00 6.40
1.00E+00 12.82 2.00 6.40
1.00E+00 9.05 2.00 6.40
1.00E+00 2.36 2.00 6.40
1.00E+00 4.73 2.00 6.40
1.00E+00 10.76 2.00 6.40 10000 1000
1.00E+00 8.62 2.00 6.40
1.00E+00 6.96 2.00 6.40
1.00E+00 6.14 2.00 6.40
1.00E+00 5.01 2.00 6.40
1.00E+00 13.17 2.00 6.40
1.00E+00 20.64 2.00 6.40
1.00E+00 22.84 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.50E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.19E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-334
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
Pb JaFS-L10-1314-T01-A 1 8.33E+01
Pb JaFS-L10-1314-T02-A 1 1.01E+02
Pb JaFS-L10-1314-T03-A 1 1.01E+02
Pb JaFS-L10-1314-T04-A 1 7.40E+01
Pb JaFS-L10-1314-T05-A 1 6.72E+01
Pb JaFS-L10-1314-T06-A 1 5.74E+01
Pb JaFS-L10-1314-T07-A 1 5.19E+01
Pb JaFS-L10-1314-T08-A 1 3.06E+01
Pb JaFS-L10-1314-T09-A 1 2.76E+01
Pb JaFS-L10-1314-T01-B 1 8.21E+01
Pb JaFS-L10-1314-T02-B 1 1.02E+02
Pb JaFS-L10-1314-T03-B 1 1.04E+02
Pb JaFS-L10-1314-T04-B 1 7.40E+01
Pb JaFS-L10-1314-T05-B 1 6.99E+01
Pb JaFS-L10-1314-T06-B 1 5.81E+01
Pb JaFS-L10-1314-T07-B 1 5.34E+01
Pb JaFS-L10-1314-T08-B 1 3.52E+01
Pb JaFS-L10-1314-T09-B 1 3.07E+01
Pb JaFS-L10-1314-T01-C 1 8.69E+01
Pb JaFS-L10-1314-T02-C 1 1.10E+02
Pb JaFS-L10-1314-T03-C 1 1.10E+02
Pb JaFS-L10-1314-T04-C 1 7.19E+01
Pb JaFS-L10-1314-T05-C 1 6.83E+01
Pb JaFS-L10-1314-T06-C 1 5.65E+01
Pb JaFS-L10-1314-T07-C 1 4.87E+01
Pb JaFS-L10-1314-T08-C 1 3.35E+01
Pb JaFS-L10-1314-T09-C 1 2.85E+01
Pb JaFS-L10-1314-B01-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.33E+01 5.36 6.80 21.60
1.01E+02 3.30 6.80 21.60
1.01E+02 2.22 6.80 21.60 10000 1000
7.40E+01 5.40 6.80 21.60
6.72E+01 3.74 6.80 21.60
5.74E+01 3.94 6.80 21.60
5.19E+01 6.65 6.80 21.60
3.06E+01 2.21 6.80 21.60
2.76E+01 5.54 6.80 21.60
8.21E+01 9.11 6.80 21.60
1.02E+02 14.28 6.80 21.60
1.04E+02 2.52 6.80 21.60 10000 1000
7.40E+01 7.77 6.80 21.60
6.99E+01 6.59 6.80 21.60
5.81 E+01 1.69 6.80 21.60
5.34E+01 7.81 6.80 21.60
3.52E+01 2.47 6.80 21.60
3.07E+01 10.16 6.80 21.60
8.69E+01 2.31 6.80 21.60
1.10E+02 5.40 6.80 21.60
1.10E+02 2.62 6.80 21.60 10000 1000
7.19E+01 3.86 6.80 21.60
6.83E+01 2.46 6.80 21.60
5.65E+01 3.66 6.80 21.60
4.87E+01 5.90 6.80 21.60
3.35E+01 19.19 6.80 21.60
2.85E+01 2.35 6.80 21.60
3.40E+00 36.11 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.91E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-335
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
Li JaFS-L10-1314-T01-A 1 4.93E+01
Li JaFS-L10-1314-T02-A 1 1.30E+01
Li JaFS-L10-1314-T03-A 1 9.50E-01 U1/2
Li JaFS-L10-1314-T04-A 1 9.50E-01 U1/2
Li JaFS-L10-1314-T05-A 1 9.50E-01 U1/2
Li JaFS-L10-1314-T06-A 1 9.50E-01 U1/2
Li JaFS-L10-1314-T07-A 1 9.50E-01 U1/2
Li JaFS-L10-1314-T08-A 1 9.50E-01 U1/2
Li JaFS-L10-1314-T09-A 1 9.50E-01 U1/2
Li JaFS-L10-1314-T01-B 1 5.01E+01
Li JaFS-L10-1314-T02-B 1 1.42E+01
Li JaFS-L10-1314-T03-B 1 2.15E+00 E
Li JaFS-L10-1314-T04-B 1 9.50E-01 U1/2
Li JaFS-L10-1314-T05-B 1 9.50E-01 U1/2
Li JaFS-L10-1314-T06-B 1 9.50E-01 U1/2
Li JaFS-L10-1314-T07-B 1 9.50E-01 U1/2
Li JaFS-L10-1314-T08-B 1 9.50E-01 U1/2
Li JaFS-L10-1314-T09-B 1 9.50E-01 U1/2
Li JaFS-L10-1314-T01-C 1 5.00E+01
Li JaFS-L10-1314-T02-C 1 1.30E+01
Li JaFS-L10-1314-T03-C 1 5.78E+00 E
Li JaFS-L10-1314-T04-C 1 9.50E-01 U1/2
Li JaFS-L10-1314-T05-C 1 9.50E-01 U1/2
Li JaFS-L10-1314-T06-C 1 9.50E-01 U1/2
Li JaFS-L10-1314-T07-C 1 9.50E-01 U1/2
Li JaFS-L10-1314-T08-C 1 9.50E-01 U1/2
Li JaFS-L10-1314-T09-C 1 9.50E-01 U1/2
Li JaFS-L10-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.93E+01 5.45 1.90 6.00
1.30E+01 12.33 1.90 6.00
9.50E-01 14.47 1.90 6.00 10000 1000
9.50E-01 0.75 1.90 6.00
9.50E-01 34.91 1.90 6.00
9.50E-01 7.93 1.90 6.00
9.50E-01 36.83 1.90 6.00
9.50E-01 20.70 1.90 6.00
9.50E-01 27.69 1.90 6.00
5.01 E+01 3.38 1.90 6.00
1.42E+01 2.36 1.90 6.00
2.15E+00 18.20 1.90 6.00 10000 1000
9.50E-01 35.89 1.90 6.00
9.50E-01 40.50 1.90 6.00
9.50E-01 21.03 1.90 6.00
9.50E-01 2.71 1.90 6.00
9.50E-01 44.46 1.90 6.00
9.50E-01 20.82 1.90 6.00
5.00E+01 1.22 1.90 6.00
1.30E+01 6.16 1.90 6.00
5.78E+00 24.68 1.90 6.00 10000 1000
9.50E-01 25.37 1.90 6.00
9.50E-01 42.33 1.90 6.00
9.50E-01 14.76 1.90 6.00
9.50E-01 15.77 1.90 6.00
9.50E-01 21.44 1.90 6.00
9.50E-01 46.34 1.90 6.00
9.50E-01 10.41 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.58E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.23E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.91 E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-336
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Mn JaFS-L10-1314-T01-A 1 1.48E+02
Mn JaFS-L10-1314-T02-A 1 3.09E+01
Mn JaFS-L10-1314-T03-A 1 1.13E+01
Mn JaFS-L10-1314-T04-A 1 1.16E+01
Mn JaFS-L10-1314-T05-A 1 1.02E+01
Mn JaFS-L10-1314-T06-A 1 8.25E+00
Mn JaFS-L10-1314-T07-A 1 6.64E+00
Mn JaFS-L10-1314-T08-A 1 6.12E+00 E
Mn JaFS-L10-1314-T09-A 1 7.67E+00
Mn JaFS-L10-1314-T01-B 1 1.44E+02
Mn JaFS-L10-1314-T02-B 1 3.37E+01
Mn JaFS-L10-1314-T03-B 1 2.24E+01
Mn JaFS-L10-1314-T04-B 1 1.56E+01
Mn JaFS-L10-1314-T05-B 1 1.41E+01
Mn JaFS-L10-1314-T06-B 1 1.07E+01
Mn JaFS-L10-1314-T07-B 1 8.80E+00
Mn JaFS-L10-1314-T08-B 1 8.10E+00
Mn JaFS-L10-1314-T09-B 1 8.83E+00
Mn JaFS-L10-1314-T01-C 1 1.54E+02
Mn JaFS-L10-1314-T02-C 1 3.29E+01
Mn JaFS-L10-1314-T03-C 1 1.35E+01
Mn JaFS-L10-1314-T04-C 1 1.22E+01
Mn JaFS-L10-1314-T05-C 1 1.10E+01
Mn JaFS-L10-1314-T06-C 1 9.00E+00
Mn JaFS-L10-1314-T07-C 1 8.67E+00
Mn JaFS-L10-1314-T08-C 1 7.57E+00
Mn JaFS-L10-1314-T09-C 1 6.00E+00 E
Mn JaFS-L10-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.48E+02 3.11 2.00 6.40
3.09E+01 4.27 2.00 6.40
1.13E+01 1.26 2.00 6.40 10000 1000
1.16E+01 0.53 2.00 6.40
1.02E+01 1.06 2.00 6.40
8.25E+00 3.52 2.00 6.40
6.64E+00 1.07 2.00 6.40
6.12E+00 1.86 2.00 6.40
7.67E+00 2.07 2.00 6.40
1.44E+02 2.31 2.00 6.40
3.37E+01 2.06 2.00 6.40
2.24E+01 1.67 2.00 6.40 10000 1000
1.56E+01 1.15 2.00 6.40
1.41E+01 2.11 2.00 6.40
1.07E+01 1.10 2.00 6.40
8.80E+00 1.95 2.00 6.40
8.10E+00 1.53 2.00 6.40
8.83E+00 1.15 2.00 6.40
1.54E+02 0.21 2.00 6.40
3.29E+01 0.74 2.00 6.40
1.35E+01 0.65 2.00 6.40 10000 1000
1.22E+01 0.21 2.00 6.40
1.10E+01 2.10 2.00 6.40
9.00E+00 0.40 2.00 6.40
8.67E+00 0.18 2.00 6.40
7.57E+00 1.01 2.00 6.40
6.00E+00 0.34 2.00 6.40
1.00E+00 19.29 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.43E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.84E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.60E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-337
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Mg JaFS-L10-1314-T01-A 1 3.57E+04
Mg JaFS-L10-1314-T02-A 1 9.20E+03
Mg JaFS-L10-1314-T03-A 1 4.49E+03
Mg JaFS-L10-1314-T04-A 1 4.16E+03
Mg JaFS-L10-1314-T05-A 1 4.04E+03
Mg JaFS-L10-1314-T06-A 1 3.65E+03
Mg JaFS-L10-1314-T07-A 1 3.37E+03
Mg JaFS-L10-1314-T08-A 1 3.59E+03
Mg JaFS-L10-1314-T09-A 1 3.92E+03
Mg JaFS-L10-1314-T01-B 1 4.31E+04
Mg JaFS-L10-1314-T02-B 1 1.01E+04
Mg JaFS-L10-1314-T03-B 1 4.94E+03
Mg JaFS-L10-1314-T04-B 1 4.27E+03
Mg JaFS-L10-1314-T05-B 1 4.39E+03
Mg JaFS-L10-1314-T06-B 1 4.05E+03
Mg JaFS-L10-1314-T07-B 1 3.90E+03
Mg JaFS-L10-1314-T08-B 1 3.91E+03
Mg JaFS-L10-1314-T09-B 1 4.04E+03
Mg JaFS-L10-1314-T01-C 1 3.02E+04
Mg JaFS-L10-1314-T02-C 1 1.02E+04
Mg JaFS-L10-1314-T03-C 1 4.43E+03
Mg JaFS-L10-1314-T04-C 1 3.75E+03
Mg JaFS-L10-1314-T05-C 1 3.92E+03
Mg JaFS-L10-1314-T06-C 1 3.73E+03
Mg JaFS-L10-1314-T07-C 1 3.68E+03
Mg JaFS-L10-1314-T08-C 1 3.72E+03
Mg JaFS-L10-1314-T09-C 1 3.67E+03
Mg JaFS-L10-1314-B01-A 1 1.08E+00 E
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.57E+04 2.80 1.00 3.18
9.20E+03 7.33 1.00 3.18
4.49E+03 2.07 1.00 3.18 10000 1000
4.16E+03 1.36 1.00 3.18
4.04E+03 0.58 1.00 3.18
3.65E+03 3.27 1.00 3.18
3.37E+03 0.88 1.00 3.18
3.59E+03 1.86 1.00 3.18
3.92E+03 1.80 1.00 3.18
4.31E+04 2.71 1.00 3.18
1.01E+04 1.68 1.00 3.18
4.94E+03 1.54 1.00 3.18 10000 1000
4.27E+03 1.61 1.00 3.18
4.39E+03 1.00 1.00 3.18
4.05E+03 1.18 1.00 3.18
3.90E+03 2.21 1.00 3.18
3.91E+03 2.67 1.00 3.18
4.04E+03 0.82 1.00 3.18
3.02E+04 1.91 1.00 3.18
1.02E+04 0.82 1.00 3.18
4.43E+03 1.06 1.00 3.18 10000 1000
3.75E+03 0.43 1.00 3.18
3.92E+03 2.13 1.00 3.18
3.73E+03 0.75 1.00 3.18
3.68E+03 0.78 1.00 3.18
3.72E+03 1.16 1.00 3.18
3.67E+03 0.71 1.00 3.18
1.08E+00 23.47 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.44E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.87E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.43E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-338
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Mo JaFS-L10-1314-T01-A 1 7.63E+01
Mo JaFS-L10-1314-T02-A 1 3.45E+01
Mo JaFS-L10-1314-T03-A 1 1.23E+01
Mo JaFS-L10-1314-T04-A 1 1.10E+01
Mo JaFS-L10-1314-T05-A 1 9.06E+00
Mo JaFS-L10-1314-T06-A 1 6.95E+00
Mo JaFS-L10-1314-T07-A 1 4.61E+00
Mo JaFS-L10-1314-T08-A 1 3.36E+00 E
Mo JaFS-L10-1314-T09-A 1 2.66E+00 E
Mo JaFS-L10-1314-T01-B 1 7.02E+01
Mo JaFS-L10-1314-T02-B 1 4.36E+01
Mo JaFS-L10-1314-T03-B 1 1.69E+01
Mo JaFS-L10-1314-T04-B 1 1.14E+01
Mo JaFS-L10-1314-T05-B 1 1.04E+01
Mo JaFS-L10-1314-T06-B 1 7.98E+00
Mo JaFS-L10-1314-T07-B 1 5.22E+00
Mo JaFS-L10-1314-T08-B 1 3.40E+00 E
Mo JaFS-L10-1314-T09-B 1 3.70E+00 E
Mo JaFS-L10-1314-T01-C 1 6.25E+01
Mo JaFS-L10-1314-T02-C 1 4.65E+01
Mo JaFS-L10-1314-T03-C 1 2.28E+01
Mo JaFS-L10-1314-T04-C 1 1.22E+01
Mo JaFS-L10-1314-T05-C 1 8.77E+00
Mo JaFS-L10-1314-T06-C 1 7.07E+00
Mo JaFS-L10-1314-T07-C 1 5.32E+00
Mo JaFS-L10-1314-T08-C 1 3.89E+00
Mo JaFS-L10-1314-T09-C 1 3.05E+00 E
Mo JaFS-L10-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.63E+01 4.78 1.20 3.82
3.45E+01 6.17 1.20 3.82
1.23E+01 0.85 1.20 3.82 10000 1000
1.10E+01 2.73 1.20 3.82
9.06E+00 8.96 1.20 3.82
6.95E+00 4.34 1.20 3.82
4.61 E+00 11.84 1.20 3.82
3.36E+00 12.59 1.20 3.82
2.66E+00 21.11 1.20 3.82
7.02E+01 0.60 1.20 3.82
4.36E+01 3.71 1.20 3.82
1.69E+01 5.01 1.20 3.82 10000 1000
1.14E+01 6.24 1.20 3.82
1.04E+01 5.48 1.20 3.82
7.98E+00 4.54 1.20 3.82
5.22E+00 3.33 1.20 3.82
3.40E+00 17.01 1.20 3.82
3.70E+00 11.86 1.20 3.82
6.25E+01 1.00 1.20 3.82
4.65E+01 1.20 1.20 3.82
2.28E+01 1.56 1.20 3.82 10000 1000
1.22E+01 3.07 1.20 3.82
8.77E+00 10.39 1.20 3.82
7.07E+00 1.03 1.20 3.82
5.32E+00 6.80 1.20 3.82
3.89E+00 9.61 1.20 3.82
3.05E+00 14.58 1.20 3.82
6.00E-01 49.71 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.48E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.27E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.54E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-339
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
Ni JaFS-L10-1314-T01-A 1 7.34E+00
Ni JaFS-L10-1314-T02-A 1 5.36E+00 E
Ni JaFS-L10-1314-T03-A 1 9.00E-01 U1/2
Ni JaFS-L10-1314-T04-A 1 9.00E-01 U1/2
Ni JaFS-L10-1314-T05-A 1 9.00E-01 U1/2
Ni JaFS-L10-1314-T06-A 1 9.00E-01 U1/2
Ni JaFS-L10-1314-T07-A 1 9.00E-01 U1/2
Ni JaFS-L10-1314-T08-A 1 9.00E-01 U1/2
Ni JaFS-L10-1314-T09-A 1 9.00E-01 U1/2
Ni JaFS-L10-1314-T01-B 1 9.07E+00
Ni JaFS-L10-1314-T02-B 1 8.43E+00
Ni JaFS-L10-1314-T03-B 1 9.00E-01 U1/2
Ni JaFS-L10-1314-T04-B 1 9.00E-01 U1/2
Ni JaFS-L10-1314-T05-B 1 9.00E-01 U1/2
Ni JaFS-L10-1314-T06-B 1 9.00E-01 U1/2
Ni JaFS-L10-1314-T07-B 1 9.00E-01 U1/2
Ni JaFS-L10-1314-T08-B 1 9.00E-01 U1/2
Ni JaFS-L10-1314-T09-B 1 9.00E-01 U1/2
Ni JaFS-L10-1314-T01-C 1 8.88E+00
Ni JaFS-L10-1314-T02-C 1 6.75E+00
Ni JaFS-L10-1314-T03-C 1 9.00E-01 U1/2
Ni JaFS-L10-1314-T04-C 1 9.00E-01 U1/2
Ni JaFS-L10-1314-T05-C 1 9.00E-01 U1/2
Ni JaFS-L10-1314-T06-C 1 9.00E-01 U1/2
Ni JaFS-L10-1314-T07-C 1 9.00E-01 U1/2
Ni JaFS-L10-1314-T08-C 1 9.00E-01 U1/2
Ni JaFS-L10-1314-T09-C 1 9.00E-01 U1/2
Ni JaFS-L10-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.34E+00 3.77 1.80 5.70
5.36E+00 25.00 1.80 5.70
9.00E-01 43.17 1.80 5.70 10000 1000
9.00E-01 41.12 1.80 5.70
9.00E-01 34.45 1.80 5.70
9.00E-01 23.88 1.80 5.70
9.00E-01 32.30 1.80 5.70
9.00E-01 46.59 1.80 5.70
9.00E-01 50.72 1.80 5.70
9.07E+00 1.16 1.80 5.70
8.43E+00 15.16 1.80 5.70
9.00E-01 37.02 1.80 5.70 10000 1000
9.00E-01 28.09 1.80 5.70
9.00E-01 40.09 1.80 5.70
9.00E-01 33.41 1.80 5.70
9.00E-01 2.79 1.80 5.70
9.00E-01 5.67 1.80 5.70
9.00E-01 34.29 1.80 5.70
8.88E+00 3.29 1.80 5.70
6.75E+00 8.96 1.80 5.70
9.00E-01 16.07 1.80 5.70 10000 1000
9.00E-01 51.05 1.80 5.70
9.00E-01 25.97 1.80 5.70
9.00E-01 24.65 1.80 5.70
9.00E-01 30.80 1.80 5.70
9.00E-01 14.85 1.80 5.70
9.00E-01 44.22 1.80 5.70
9.00E-01 58.98 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.62E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.98E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.72E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-340
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
P JaFS-L10-1314-T01-A 1 7.26E+01
P JaFS-L10-1314-T02-A 1 5.85E+01
P JaFS-L10-1314-T03-A 1 4.60E+01
P JaFS-L10-1314-T04-A 1 3.76E+01
P JaFS-L10-1314-T05-A 1 2.99E+01
P JaFS-L10-1314-T06-A 1 1.49E+01
P JaFS-L10-1314-T07-A 1 1.53E+01
P JaFS-L10-1314-T08-A 1 1.34E+01
P JaFS-L10-1314-T09-A 1 1.93E+01
P JaFS-L10-1314-T01-B 1 7.61E+01
P JaFS-L10-1314-T02-B 1 6.48E+01
P JaFS-L10-1314-T03-B 1 4.78E+01
P JaFS-L10-1314-T04-B 1 3.38E+01
P JaFS-L10-1314-T05-B 1 2.66E+01
P JaFS-L10-1314-T06-B 1 2.32E+01
P JaFS-L10-1314-T07-B 1 2.28E+01
P JaFS-L10-1314-T08-B 1 1.58E+01
P JaFS-L10-1314-T09-B 1 1.32E+01
P JaFS-L10-1314-T01-C 1 6.20E+01
P JaFS-L10-1314-T02-C 1 4.66E+01
P JaFS-L10-1314-T03-C 1 4.33E+01
P JaFS-L10-1314-T04-C 1 3.08E+01
P JaFS-L10-1314-T05-C 1 2.53E+01
P JaFS-L10-1314-T06-C 1 2.28E+01
P JaFS-L10-1314-T07-C 1 1.91E+01
P JaFS-L10-1314-T08-C 1 1.34E+01
P JaFS-L10-1314-T09-C 1 1.38E+01
P JaFS-L10-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.26E+01 1.31 3.70 11.80
5.85E+01 9.25 3.70 11.80
4.60E+01 6.36 3.70 11.80 10000 1000
3.76E+01 2.02 3.70 11.80
2.99E+01 2.40 3.70 11.80
1.49E+01 1.66 3.70 11.80
1.53E+01 4.49 3.70 11.80
1.34E+01 3.16 3.70 11.80
1.93E+01 3.30 3.70 11.80
7.61 E+01 9.29 3.70 11.80
6.48E+01 1.11 3.70 11.80
4.78E+01 13.00 3.70 11.80 10000 1000
3.38E+01 3.07 3.70 11.80
2.66E+01 2.85 3.70 11.80
2.32E+01 2.56 3.70 11.80
2.28E+01 4.18 3.70 11.80
1.58E+01 7.22 3.70 11.80
1.32E+01 3.36 3.70 11.80
6.20E+01 3.68 3.70 11.80
4.66E+01 14.62 3.70 11.80
4.33E+01 3.33 3.70 11.80 10000 1000
3.08E+01 2.63 3.70 11.80
2.53E+01 1.25 3.70 11.80
2.28E+01 2.80 3.70 11.80
1.91 E+01 1.88 3.70 11.80
1.34E+01 3.91 3.70 11.80
1.38E+01 2.54 3.70 11.80
1.85E+00 59.85 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.16E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-341
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
K JaFS-L10-1314-T01-A 1 4.20E+04
K JaFS-L10-1314-T02-A 1 1.80E+04
K JaFS-L10-1314-T03-A 1 1.15E+04
K JaFS-L10-1314-T04-A 1 1.13E+04
K JaFS-L10-1314-T05-A 1 1.02E+04
K JaFS-L10-1314-T06-A 1 8.08E+03
K JaFS-L10-1314-T07-A 1 5.76E+03
K JaFS-L10-1314-T08-A 1 3.73E+03
K JaFS-L10-1314-T09-A 1 2.73E+03
K JaFS-L10-1314-T01-B 1 4.74E+04
K JaFS-L10-1314-T02-B 1 1.48E+04
K JaFS-L10-1314-T03-B 1 1.37E+04
K JaFS-L10-1314-T04-B 1 1.18E+04
K JaFS-L10-1314-T05-B 1 1.07E+04
K JaFS-L10-1314-T06-B 1 7.98E+03
K JaFS-L10-1314-T07-B 1 5.96E+03
K JaFS-L10-1314-T08-B 1 3.95E+03
K JaFS-L10-1314-T09-B 1 2.85E+03
K JaFS-L10-1314-T01-C 1 3.71E+04
K JaFS-L10-1314-T02-C 1 1.34E+04
K JaFS-L10-1314-T03-C 1 1.12E+04
K JaFS-L10-1314-T04-C 1 1.10E+04
K JaFS-L10-1314-T05-C 1 1.02E+04
K JaFS-L10-1314-T06-C 1 7.79E+03
K JaFS-L10-1314-T07-C 1 6.05E+03
K JaFS-L10-1314-T08-C 1 3.96E+03
K JaFS-L10-1314-T09-C 1 2.72E+03
K JaFS-L10-1314-B01-A 1 3.31E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.20E+04 2.36 1.60 5.09
1.80E+04 4.55 1.60 5.09
1.15E+04 1.63 1.60 5.09 10000 1000
1.13E+04 0.98 1.60 5.09
1.02E+04 0.82 1.60 5.09
8.08E+03 3.28 1.60 5.09
5.76E+03 1.51 1.60 5.09
3.73E+03 1.45 1.60 5.09
2.73E+03 1.40 1.60 5.09
4.74E+04 2.50 1.60 5.09
1.48E+04 2.42 1.60 5.09
1.37E+04 2.10 1.60 5.09 10000 1000
1.18E+04 1.29 1.60 5.09
1.07E+04 1.62 1.60 5.09
7.98E+03 0.94 1.60 5.09
5.96E+03 2.13 1.60 5.09
3.95E+03 1.88 1.60 5.09
2.85E+03 1.14 1.60 5.09
3.71 E+04 0.84 1.60 5.09
1.34E+04 1.05 1.60 5.09
1.12E+04 0.74 1.60 5.09 10000 1000
1.10E+04 0.45 1.60 5.09
1.02E+04 1.67 1.60 5.09
7.79E+03 0.39 1.60 5.09
6.05E+03 1.17 1.60 5.09
3.96E+03 0.98 1.60 5.09
2.72E+03 0.56 1.60 5.09
3.31 E+01 1.25 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.23E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.46E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.21E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-342
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Se JaFS-L10-1314-T01-A 1 4.16E+01 E
Se JaFS-L10-1314-T02-A 1 3.59E+01 E
Se JaFS-L10-1314-T03-A 1 2.20E+01 E
Se JaFS-L10-1314-T04-A 1 7.50E+00 U1/2
Se JaFS-L10-1314-T05-A 1 7.50E+00 U1/2
Se JaFS-L10-1314-T06-A 1 7.50E+00 U1/2
Se JaFS-L10-1314-T07-A 1 7.50E+00 U1/2
Se JaFS-L10-1314-T08-A 1 7.50E+00 U1/2
Se JaFS-L10-1314-T09-A 1 7.50E+00 U1/2
Se JaFS-L10-1314-T01-B 1 4.30E+01 E
Se JaFS-L10-1314-T02-B 1 3.20E+01 E
Se JaFS-L10-1314-T03-B 1 2.10E+01 E
Se JaFS-L10-1314-T04-B 1 7.50E+00 U1/2
Se JaFS-L10-1314-T05-B 1 7.50E+00 U1/2
Se JaFS-L10-1314-T06-B 1 7.50E+00 U1/2
Se JaFS-L10-1314-T07-B 1 7.50E+00 U1/2
Se JaFS-L10-1314-T08-B 1 7.50E+00 U1/2
Se JaFS-L10-1314-T09-B 1 7.50E+00 U1/2
Se JaFS-L10-1314-T01-C 1 4.37E+01 E
Se JaFS-L10-1314-T02-C 1 3.49E+01 E
Se JaFS-L10-1314-T03-C 1 1.90E+01 E
Se JaFS-L10-1314-T04-C 1 7.50E+00 U1/2
Se JaFS-L10-1314-T05-C 1 7.50E+00 U1/2
Se JaFS-L10-1314-T06-C 1 7.50E+00 U1/2
Se JaFS-L10-1314-T07-C 1 7.50E+00 U1/2
Se JaFS-L10-1314-T08-C 1 7.50E+00 U1/2
Se JaFS-L10-1314-T09-C 1 7.50E+00 U1/2
Se JaFS-L10-1314-B01-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.16E+01 6.14 15.00 47.70
3.59E+01 11.88 15.00 47.70
2.20E+01 15.40 15.00 47.70 10000 1000
7.50E+00 31.64 15.00 47.70
7.50E+00 53.04 15.00 47.70
7.50E+00 12.72 15.00 47.70
7.50E+00 16.53 15.00 47.70
7.50E+00 2.59 15.00 47.70
7.50E+00 13.48 15.00 47.70
4.30E+01 33.16 15.00 47.70
3.20E+01 18.05 15.00 47.70
2.10E+01 35.03 15.00 47.70 10000 1000
7.50E+00 40.72 15.00 47.70
7.50E+00 52.59 15.00 47.70
7.50E+00 27.86 15.00 47.70
7.50E+00 41.73 15.00 47.70
7.50E+00 44.06 15.00 47.70
7.50E+00 51.68 15.00 47.70
4.37E+01 18.06 15.00 47.70
3.49E+01 36.23 15.00 47.70
1.90E+01 35.07 15.00 47.70 10000 1000
7.50E+00 30.85 15.00 47.70
7.50E+00 16.73 15.00 47.70
7.50E+00 21.43 15.00 47.70
7.50E+00 16.59 15.00 47.70
7.50E+00 5.80 15.00 47.70
7.50E+00 13.70 15.00 47.70
7.50E+00 9.14 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.64E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.40E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-343
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Si JaFS-L10-1314-T01-A 1 3.70E+03
Si JaFS-L10-1314-T02-A 1 2.86E+03
Si JaFS-L10-1314-T03-A 1 2.35E+03
Si JaFS-L10-1314-T04-A 1 2.15E+03
Si JaFS-L10-1314-T05-A 1 2.01E+03
Si JaFS-L10-1314-T06-A 1 1.84E+03
Si JaFS-L10-1314-T07-A 1 1.67E+03
Si JaFS-L10-1314-T08-A 1 1.64E+03
Si JaFS-L10-1314-T09-A 1 1.73E+03
Si JaFS-L10-1314-T01-B 1 3.56E+03
Si JaFS-L10-1314-T02-B 1 3.12E+03
Si JaFS-L10-1314-T03-B 1 2.43E+03
Si JaFS-L10-1314-T04-B 1 2.15E+03
Si JaFS-L10-1314-T05-B 1 1.98E+03
Si JaFS-L10-1314-T06-B 1 1.81E+03
Si JaFS-L10-1314-T07-B 1 1.71E+03
Si JaFS-L10-1314-T08-B 1 1.65E+03
Si JaFS-L10-1314-T09-B 1 1.72E+03
Si JaFS-L10-1314-T01-C 1 3.23E+03
Si JaFS-L10-1314-T02-C 1 2.88E+03
Si JaFS-L10-1314-T03-C 1 2.40E+03
Si JaFS-L10-1314-T04-C 1 2.03E+03
Si JaFS-L10-1314-T05-C 1 1.92E+03
Si JaFS-L10-1314-T06-C 1 1.74E+03
Si JaFS-L10-1314-T07-C 1 1.71E+03
Si JaFS-L10-1314-T08-C 1 1.66E+03
Si JaFS-L10-1314-T09-C 1 1.70E+03
Si JaFS-L10-1314-B01-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.70E+03 2.76 1.10 3.50
2.86E+03 7.77 1.10 3.50
2.35E+03 2.05 1.10 3.50 10000 1000
2.15E+03 1.24 1.10 3.50
2.01 E+03 1.38 1.10 3.50
1.84E+03 3.76 1.10 3.50
1.67E+03 1.79 1.10 3.50
1.64E+03 1.92 1.10 3.50
1.73E+03 1.62 1.10 3.50
3.56E+03 2.59 1.10 3.50
3.12E+03 0.74 1.10 3.50
2.43E+03 2.19 1.10 3.50 10000 1000
2.15E+03 1.23 1.10 3.50
1.98E+03 1.59 1.10 3.50
1.81 E+03 0.61 1.10 3.50
1.71 E+03 1.77 1.10 3.50
1.65E+03 1.80 1.10 3.50
1.72E+03 1.29 1.10 3.50
3.23E+03 1.40 1.10 3.50
2.88E+03 0.55 1.10 3.50
2.40E+03 1.00 1.10 3.50 10000 1000
2.03E+03 0.61 1.10 3.50
1.92E+03 1.36 1.10 3.50
1.74E+03 0.20 1.10 3.50
1.71 E+03 0.97 1.10 3.50
1.66E+03 0.69 1.10 3.50
1.70E+03 0.67 1.10 3.50
5.50E-01 14.53 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.28E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.39E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.31 E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-344
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Na JaFS-L10-1314-T01-A 1 1.75E+05
Na JaFS-L10-1314-T02-A 1 9.09E+04
Na JaFS-L10-1314-T03-A 1 3.85E+04
Na JaFS-L10-1314-T04-A 1 7.88E+03
Na JaFS-L10-1314-T05-A 1 2.94E+03
Na JaFS-L10-1314-T06-A 1 1.16E+03
Na JaFS-L10-1314-T07-A 1 6.67E+02
Na JaFS-L10-1314-T08-A 1 3.87E+02
Na JaFS-L10-1314-T09-A 1 3.75E+02
Na JaFS-L10-1314-T01-B 1 1.84E+05
Na JaFS-L10-1314-T02-B 1 9.42E+04
Na JaFS-L10-1314-T03-B 1 4.17E+04
Na JaFS-L10-1314-T04-B 1 9.83E+03
Na JaFS-L10-1314-T05-B 1 4.93E+03
Na JaFS-L10-1314-T06-B 1 1.67E+03
Na JaFS-L10-1314-T07-B 1 8.27E+02
Na JaFS-L10-1314-T08-B 1 4.49E+02
Na JaFS-L10-1314-T09-B 1 3.36E+02
Na JaFS-L10-1314-T01-C 1 1.56E+05
Na JaFS-L10-1314-T02-C 1 9.37E+04
Na JaFS-L10-1314-T03-C 1 4.23E+04
Na JaFS-L10-1314-T04-C 1 8.54E+03
Na JaFS-L10-1314-T05-C 1 4.87E+03
Na JaFS-L10-1314-T06-C 1 2.52E+03
Na JaFS-L10-1314-T07-C 1 1.07E+03
Na JaFS-L10-1314-T08-C 1 5.47E+02
Na JaFS-L10-1314-T09-C 1 3.03E+02
Na JaFS-L10-1314-B01-A 1 7.63E+00 E
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.75E+05 0.19 2.50 8.00
9.09E+04 2.07 2.50 8.00
3.85E+04 0.57 2.50 8.00 10000 1000
7.88E+03 0.53 2.50 8.00
2.94E+03 1.09 2.50 8.00
1.16E+03 1.13 2.50 8.00
6.67E+02 0.81 2.50 8.00
3.87E+02 0.51 2.50 8.00
3.75E+02 1.02 2.50 8.00
1.84E+05 0.72 2.50 8.00
9.42E+04 0.36 2.50 8.00
4.17E+04 0.34 2.50 8.00 10000 1000
9.83E+03 0.90 2.50 8.00
4.93E+03 0.85 2.50 8.00
1.67E+03 0.28 2.50 8.00
8.27E+02 0.46 2.50 8.00
4.49E+02 0.53 2.50 8.00
3.36E+02 0.42 2.50 8.00
1.56E+05 0.48 2.50 8.00
9.37E+04 1.61 2.50 8.00
4.23E+04 0.08 2.50 8.00 10000 1000
8.54E+03 0.68 2.50 8.00
4.87E+03 0.69 2.50 8.00
2.52E+03 0.23 2.50 8.00
1.07E+03 0.33 2.50 8.00
5.47E+02 0.71 2.50 8.00
3.03E+02 0.58 2.50 8.00
7.63E+00 2.60 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.94E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.26E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.32E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-345
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Sr JaFS-L10-1314-T01-A 1 6.06E+03
Sr JaFS-L10-1314-T02-A 1 1.56E+03
Sr JaFS-L10-1314-T03-A 1 8.28E+02
Sr JaFS-L10-1314-T04-A 1 7.63E+02
Sr JaFS-L10-1314-T05-A 1 7.56E+02
Sr JaFS-L10-1314-T06-A 1 7.11E+02
Sr JaFS-L10-1314-T07-A 1 6.75E+02
Sr JaFS-L10-1314-T08-A 1 7.47E+02
Sr JaFS-L10-1314-T09-A 1 8.19E+02
Sr JaFS-L10-1314-T01-B 1 7.04E+03
Sr JaFS-L10-1314-T02-B 1 1.44E+03
Sr JaFS-L10-1314-T03-B 1 8.64E+02
Sr JaFS-L10-1314-T04-B 1 7.51E+02
Sr JaFS-L10-1314-T05-B 1 7.92E+02
Sr JaFS-L10-1314-T06-B 1 7.51E+02
Sr JaFS-L10-1314-T07-B 1 7.52E+02
Sr JaFS-L10-1314-T08-B 1 7.78E+02
Sr JaFS-L10-1314-T09-B 1 8.24E+02
Sr JaFS-L10-1314-T01-C 1 5.11E+03
Sr JaFS-L10-1314-T02-C 1 1.85E+03
Sr JaFS-L10-1314-T03-C 1 9.03E+02
Sr JaFS-L10-1314-T04-C 1 6.78E+02
Sr JaFS-L10-1314-T05-C 1 7.17E+02
Sr JaFS-L10-1314-T06-C 1 7.13E+02
Sr JaFS-L10-1314-T07-C 1 7.28E+02
Sr JaFS-L10-1314-T08-C 1 7.61E+02
Sr JaFS-L10-1314-T09-C 1 7.85E+02
Sr JaFS-L10-1314-B01-A 1 2.55E+00 E
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.06E+03 2.75 1.00 3.18
1.56E+03 4.64 1.00 3.18
8.28E+02 1.27 1.00 3.18 10000 1000
7.63E+02 0.51 1.00 3.18
7.56E+02 1.71 1.00 3.18
7.11E+02 3.46 1.00 3.18
6.75E+02 2.04 1.00 3.18
7.47E+02 1.31 1.00 3.18
8.19E+02 2.07 1.00 3.18
7.04E+03 1.24 1.00 3.18
1.44E+03 1.53 1.00 3.18
8.64E+02 1.27 1.00 3.18 10000 1000
7.51E+02 0.36 1.00 3.18
7.92E+02 1.04 1.00 3.18
7.51E+02 1.73 1.00 3.18
7.52E+02 2.18 1.00 3.18
7.78E+02 1.78 1.00 3.18
8.24E+02 2.14 1.00 3.18
5.11E+03 0.41 1.00 3.18
1.85E+03 0.44 1.00 3.18
9.03E+02 0.73 1.00 3.18 10000 1000
6.78E+02 1.53 1.00 3.18
7.17E+02 1.64 1.00 3.18
7.13E+02 0.78 1.00 3.18
7.28E+02 1.16 1.00 3.18
7.61E+02 0.69 1.00 3.18
7.85E+02 0.78 1.00 3.18
2.55E+00 0.85 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.77E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.77E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.76E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-346
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
S JaFS-L10-1314-T01-A 1 4.15E+05
S JaFS-L10-1314-T02-A 1 8.37E+04
S JaFS-L10-1314-T03-A 1 9.77E+03
S JaFS-L10-1314-T04-A 1 6.66E+03
S JaFS-L10-1314-T05-A 1 5.06E+03
S JaFS-L10-1314-T06-A 1 3.23E+03
S JaFS-L10-1314-T07-A 1 2.27E+03
S JaFS-L10-1314-T08-A 1 1.76E+03
S JaFS-L10-1314-T09-A 1 1.63E+03
S JaFS-L10-1314-T01-B 1 4.92E+05
S JaFS-L10-1314-T02-B 1 8.95E+04
S JaFS-L10-1314-T03-B 1 1.02E+04
S JaFS-L10-1314-T04-B 1 8.23E+03
S JaFS-L10-1314-T05-B 1 5.77E+03
S JaFS-L10-1314-T06-B 1 3.70E+03
S JaFS-L10-1314-T07-B 1 2.78E+03
S JaFS-L10-1314-T08-B 1 2.01E+03
S JaFS-L10-1314-T09-B 1 1.64E+03
S JaFS-L10-1314-T01-C 1 3.57E+05
S JaFS-L10-1314-T02-C 1 8.26E+04
S JaFS-L10-1314-T03-C 1 1.06E+04
S JaFS-L10-1314-T04-C 1 9.13E+03
S JaFS-L10-1314-T05-C 1 6.46E+03
S JaFS-L10-1314-T06-C 1 3.82E+03
S JaFS-L10-1314-T07-C 1 2.75E+03
S JaFS-L10-1314-T08-C 1 1.94E+03
S JaFS-L10-1314-T09-C 1 1.45E+03
S JaFS-L10-1314-B01-A 1 1.92E+01 E
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.15E+05 2.85 6.80 21.60
8.37E+04 4.39 6.80 21.60
9.77E+03 1.26 6.80 21.60 10000 1000
6.66E+03 0.67 6.80 21.60
5.06E+03 1.33 6.80 21.60
3.23E+03 3.09 6.80 21.60
2.27E+03 1.78 6.80 21.60
1.76E+03 3.49 6.80 21.60
1.63E+03 1.86 6.80 21.60
4.92E+05 2.22 6.80 21.60
8.95E+04 1.75 6.80 21.60
1.02E+04 1.84 6.80 21.60 10000 1000
8.23E+03 1.10 6.80 21.60
5.77E+03 2.07 6.80 21.60
3.70E+03 0.48 6.80 21.60
2.78E+03 1.30 6.80 21.60
2.01 E+03 1.31 6.80 21.60
1.64E+03 1.16 6.80 21.60
3.57E+05 1.02 6.80 21.60
8.26E+04 1.03 6.80 21.60
1.06E+04 0.40 6.80 21.60 10000 1000
9.13E+03 0.49 6.80 21.60
6.46E+03 1.83 6.80 21.60
3.82E+03 1.19 6.80 21.60
2.75E+03 0.63 6.80 21.60
1.94E+03 2.02 6.80 21.60
1.45E+03 1.72 6.80 21.60
1.92E+01 4.58 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.06E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+04 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-347
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Tl JaFS-L10-1314-T01-A 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T02-A 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T03-A 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T04-A 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T05-A 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T06-A 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T07-A 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T08-A 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T09-A 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T01-B 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T02-B 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T03-B 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T04-B 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T05-B 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T06-B 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T07-B 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T08-B 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T09-B 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T01-C 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T02-C 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T03-C 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T04-C 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T05-C 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T06-C 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T07-C 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T08-C 1 2.30E+00 U1/2
Tl JaFS-L10-1314-T09-C 1 2.30E+00 U1/2
Tl JaFS-L10-1314-B01-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 27.03 4.60 14.60
2.30E+00 53.94 4.60 14.60
2.30E+00 57.63 4.60 14.60 10000 1000
2.30E+00 46.30 4.60 14.60
2.30E+00 46.26 4.60 14.60
2.30E+00 59.74 4.60 14.60
2.30E+00 21.41 4.60 14.60
2.30E+00 13.30 4.60 14.60
2.30E+00 12.75 4.60 14.60
2.30E+00 20.34 4.60 14.60
2.30E+00 47.84 4.60 14.60
2.30E+00 35.47 4.60 14.60 10000 1000
2.30E+00 8.62 4.60 14.60
2.30E+00 6.18 4.60 14.60
2.30E+00 34.32 4.60 14.60
2.30E+00 11.83 4.60 14.60
2.30E+00 48.56 4.60 14.60
2.30E+00 39.24 4.60 14.60
2.30E+00 10.88 4.60 14.60
2.30E+00 54.90 4.60 14.60
2.30E+00 51.03 4.60 14.60 10000 1000
2.30E+00 33.60 4.60 14.60
2.30E+00 7.35 4.60 14.60
2.30E+00 9.69 4.60 14.60
2.30E+00 37.95 4.60 14.60
2.30E+00 5.36 4.60 14.60
2.30E+00 52.86 4.60 14.60
2.30E+00 23.22 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.78E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.17E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.80E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-348
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Ti JaFS-L10-1314-T01-A 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T02-A 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T03-A 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T04-A 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T05-A 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T06-A 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T07-A 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T08-A 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T09-A 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T01-B 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T02-B 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T03-B 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T04-B 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T05-B 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T06-B 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T07-B 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T08-B 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T09-B 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T01-C 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T02-C 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T03-C 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T04-C 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T05-C 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T06-C 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T07-C 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T08-C 1 1.00E+00 U1/2
Ti JaFS-L10-1314-T09-C 1 1.00E+00 U1/2
Ti JaFS-L10-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 57.18 2.00 6.40
1.00E+00 8.44 2.00 6.40
1.00E+00 2.54 2.00 6.40 10000 1000
1.00E+00 38.45 2.00 6.40
1.00E+00 3.34 2.00 6.40
1.00E+00 47.59 2.00 6.40
1.00E+00 23.68 2.00 6.40
1.00E+00 60.42 2.00 6.40
1.00E+00 8.39 2.00 6.40
1.00E+00 34.91 2.00 6.40
1.00E+00 47.55 2.00 6.40
1.00E+00 7.82 2.00 6.40 10000 1000
1.00E+00 33.16 2.00 6.40
1.00E+00 14.41 2.00 6.40
1.00E+00 19.73 2.00 6.40
1.00E+00 21.39 2.00 6.40
1.00E+00 9.54 2.00 6.40
1.00E+00 31.55 2.00 6.40
1.00E+00 52.50 2.00 6.40
1.00E+00 10.98 2.00 6.40
1.00E+00 25.43 2.00 6.40 10000 1000
1.00E+00 30.88 2.00 6.40
1.00E+00 9.74 2.00 6.40
1.00E+00 53.52 2.00 6.40
1.00E+00 26.67 2.00 6.40
1.00E+00 54.89 2.00 6.40
1.00E+00 31.02 2.00 6.40
1.00E+00 11.84 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.85E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.41 E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.13E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-349
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
V JaFS-L10-1314-T01-A 1 1.41E+01
V JaFS-L10-1314-T02-A 1 3.81E+00 E
V JaFS-L10-1314-T03-A 1 2.12E+00 E
V JaFS-L10-1314-T04-A 1 7.50E-01 U1/2
V JaFS-L10-1314-T05-A 1 7.50E-01 U1/2
V JaFS-L10-1314-T06-A 1 7.50E-01 U1/2
V JaFS-L10-1314-T07-A 1 7.50E-01 U1/2
V JaFS-L10-1314-T08-A 1 7.50E-01 U1/2
V JaFS-L10-1314-T09-A 1 7.50E-01 U1/2
V JaFS-L10-1314-T01-B 1 1.47E+01
V JaFS-L10-1314-T02-B 1 5.29E+00
V JaFS-L10-1314-T03-B 1 1.71E+00 E
V JaFS-L10-1314-T04-B 1 7.50E-01 U1/2
V JaFS-L10-1314-T05-B 1 7.50E-01 U1/2
V JaFS-L10-1314-T06-B 1 7.50E-01 U1/2
V JaFS-L10-1314-T07-B 1 7.50E-01 U1/2
V JaFS-L10-1314-T08-B 1 7.50E-01 U1/2
V JaFS-L10-1314-T09-B 1 7.50E-01 U1/2
V JaFS-L10-1314-T01-C 1 1.32E+01
V JaFS-L10-1314-T02-C 1 4.04E+00 E
V JaFS-L10-1314-T03-C 1 3.49E+00 E
V JaFS-L10-1314-T04-C 1 7.50E-01 U1/2
V JaFS-L10-1314-T05-C 1 7.50E-01 U1/2
V JaFS-L10-1314-T06-C 1 7.50E-01 U1/2
V JaFS-L10-1314-T07-C 1 7.50E-01 U1/2
V JaFS-L10-1314-T08-C 1 7.50E-01 U1/2
V JaFS-L10-1314-T09-C 1 7.50E-01 U1/2
V JaFS-L10-1314-B01-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.41E+01 5.66 1.50 4.77
3.81E+00 16.25 1.50 4.77
2.12E+00 4.16 1.50 4.77 10000 1000
7.50E-01 4.45 1.50 4.77
7.50E-01 27.88 1.50 4.77
7.50E-01 24.78 1.50 4.77
7.50E-01 23.45 1.50 4.77
7.50E-01 52.61 1.50 4.77
7.50E-01 20.21 1.50 4.77
1.47E+01 1.52 1.50 4.77
5.29E+00 4.83 1.50 4.77
1.71E+00 12.18 1.50 4.77 10000 1000
7.50E-01 20.87 1.50 4.77
7.50E-01 31.93 1.50 4.77
7.50E-01 8.81 1.50 4.77
7.50E-01 11.28 1.50 4.77
7.50E-01 24.64 1.50 4.77
7.50E-01 41.49 1.50 4.77
1.32E+01 11.49 1.50 4.77
4.04E+00 6.38 1.50 4.77
3.49E+00 15.05 1.50 4.77 10000 1000
7.50E-01 30.58 1.50 4.77
7.50E-01 18.97 1.50 4.77
7.50E-01 19.28 1.50 4.77
7.50E-01 6.10 1.50 4.77
7.50E-01 2.49 1.50 4.77
7.50E-01 24.59 1.50 4.77
7.50E-01 13.49 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.52E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.25E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-350
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Zn JaFS-L10-1314-T01-A 1 7.44E+02
Zn JaFS-L10-1314-T02-A 1 2.76E+02
Zn JaFS-L10-1314-T03-A 1 1.08E+02
Zn JaFS-L10-1314-T04-A 1 8.69E+01
Zn JaFS-L10-1314-T05-A 1 7.76E+01
Zn JaFS-L10-1314-T06-A 1 5.80E+01
Zn JaFS-L10-1314-T07-A 1 4.20E+01
Zn JaFS-L10-1314-T08-A 1 3.00E+01
Zn JaFS-L10-1314-T09-A 1 3.08E+01
Zn JaFS-L10-1314-T01-B 1 7.51E+02
Zn JaFS-L10-1314-T02-B 1 2.83E+02
Zn JaFS-L10-1314-T03-B 1 1.14E+02
Zn JaFS-L10-1314-T04-B 1 9.17E+01
Zn JaFS-L10-1314-T05-B 1 7.84E+01
Zn JaFS-L10-1314-T06-B 1 7.13E+01
Zn JaFS-L10-1314-T07-B 1 5.48E+01
Zn JaFS-L10-1314-T08-B 1 3.78E+01
Zn JaFS-L10-1314-T09-B 1 3.09E+01
Zn JaFS-L10-1314-T01-C 1 6.90E+02
Zn JaFS-L10-1314-T02-C 1 2.76E+02
Zn JaFS-L10-1314-T03-C 1 1.26E+02
Zn JaFS-L10-1314-T04-C 1 9.34E+01
Zn JaFS-L10-1314-T05-C 1 7.84E+01
Zn JaFS-L10-1314-T06-C 1 6.66E+01
Zn JaFS-L10-1314-T07-C 1 4.98E+01
Zn JaFS-L10-1314-T08-C 1 3.63E+01
Zn JaFS-L10-1314-T09-C 1 2.70E+01
Zn JaFS-L10-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.44E+02 2.81 1.00 3.18
2.76E+02 4.84 1.00 3.18
1.08E+02 1.72 1.00 3.18 10000 1000
8.69E+01 0.81 1.00 3.18
7.76E+01 1.92 1.00 3.18
5.80E+01 3.66 1.00 3.18
4.20E+01 2.07 1.00 3.18
3.00E+01 2.33 1.00 3.18
3.08E+01 3.06 1.00 3.18
7.51E+02 2.72 1.00 3.18
2.83E+02 2.15 1.00 3.18
1.14E+02 2.07 1.00 3.18 10000 1000
9.17E+01 1.23 1.00 3.18
7.84E+01 1.37 1.00 3.18
7.13E+01 0.70 1.00 3.18
5.48E+01 1.73 1.00 3.18
3.78E+01 1.97 1.00 3.18
3.09E+01 1.38 1.00 3.18
6.90E+02 0.03 1.00 3.18
2.76E+02 0.72 1.00 3.18
1.26E+02 0.53 1.00 3.18 10000 1000
9.34E+01 0.48 1.00 3.18
7.84E+01 0.92 1.00 3.18
6.66E+01 0.12 1.00 3.18
4.98E+01 1.68 1.00 3.18
3.63E+01 1.04 1.00 3.18
2.70E+01 0.34 1.00 3.18
5.00E-01 2.74 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/9/12 11:33 AM EPA Interlab L10 1314 JaFS
2/9/12 11:34 AM EPA Interlab L10 1314 JaFS
2/9/12 11:36 AM EPA Interlab L10 1314 JaFS
2/9/12 11:38 AM EPA Interlab L10 1314 JaFS
2/9/12 11:39 AM EPA Interlab L10 1314 JaFS
2/9/12 11:41 AM EPA Interlab L10 1314 JaFS
2/9/12 11:43 AM EPA Interlab L10 1314 JaFS
2/9/12 11:44 AM EPA Interlab L10 1314 JaFS
2/9/12 11:46 AM EPA Interlab L10 1314 JaFS
2/9/12 11:51 AM EPA Interlab L10 1314 JaFS
2/9/12 11:52 AM EPA Interlab L10 1314 JaFS
2/9/12 11:54 AM EPA Interlab L10 1314 JaFS
2/9/12 11:56 AM EPA Interlab L10 1314 JaFS
2/9/12 11:57 AM EPA Interlab L10 1314 JaFS
2/9/12 11:59 AM EPA Interlab L10 1314 JaFS
2/9/12 12:01 PM EPA Interlab L10 1314 JaFS
2/9/12 12:02 PM EPA Interlab L10 1314 JaFS
2/9/12 12:04 PM EPA Interlab L10 1314 JaFS
2/9/12 12:06 PM EPA Interlab L10 1314 JaFS
2/9/12 12:07 PM EPA Interlab L10 1314 JaFS
2/9/12 12:09 PM EPA Interlab L10 1314 JaFS
2/9/12 12:10 PM EPA Interlab L10 1314 JaFS
2/9/12 12:12 PM EPA Interlab L10 1314 JaFS
2/9/12 12:14 PM EPA Interlab L10 1314 JaFS
2/9/12 12:15 PM EPA Interlab L10 1314 JaFS
2/9/12 12:17 PM EPA Interlab L10 1314 JaFS
2/9/12 12:19 PM EPA Interlab L10 1314 JaFS
2/9/12 11:31 AM EPA Interlab L10 1314 JaFS
1-351
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1314:
Dilution Sample
Element Sample ID Factor Cone. Qualifier
I I M9/L I
Al JaFS-L11-1314-T01-A 1 5.80E+01
Al JaFS-L11-1314-T02-A 1 5.39E+01
Al JaFS-L11-1314-T03-A 1 1.97E+01
Al JaFS-L11-1314-T04-A 1 1.81E+01
Al JaFS-L11-1314-T05-A 1 1.63E+01
Al JaFS-L11-1314-T06-A 1 1.62E+01
Al JaFS-L11-1314-T07-A 1 1.43E+01
Al JaFS-L11-1314-T08-A 1 1.61E+01
Al JaFS-L11-1314-T09-A 1 1.74E+01
Al JaFS-L11-1314-T01-B 1 6.08E+01
Al JaFS-L11-1314-T02-B 1 5.74E+01
Al JaFS-L11-1314-T03-B 1 1.80E+01
Al JaFS-L11-1314-T04-B 1 1.84E+01
Al JaFS-L11-1314-T05-B 1 1.68E+01
Al JaFS-L11-1314-T06-B 1 1.54E+01
Al JaFS-L11-1314-T07-B 1 1.51E+01
Al JaFS-L11-1314-T08-B 1 1.80E+01
Al JaFS-L11-1314-T09-B 1 1.84E+01
Al JaFS-L11-1314-T01-C 1 6.08E+01
Al JaFS-L11-1314-T02-C 1 5.39E+01
Al JaFS-L11-1314-T03-C 1 2.14E+01
Al JaFS-L11-1314-T04-C 1 1.97E+01
Al JaFS-L11-1314-T05-C 1 1.79E+01
Al JaFS-L11-1314-T06-C 1 1.56E+01
Al JaFS-L11-1314-T07-C 1 1.54E+01
Al JaFS-L11-1314-T08-C 1 1.81E+01
Al JaFS-L11-1314-T09-C 1 1.83E+01
Al JaFS-L11-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.80E+01 1.18 1.00 3.18
5.39E+01 6.42 1.00 3.18
1.97E+01 2.57 1.00 3.18 10000 1000
1.81E+01 3.69 1.00 3.18
1.63E+01 1.83 1.00 3.18
1.62E+01 1.75 1.00 3.18
1.43E+01 3.54 1.00 3.18
1.61E+01 0.60 1.00 3.18
1.74E+01 9.98 1.00 3.18
6.08E+01 6.36 1.00 3.18
5.74E+01 1.91 1.00 3.18
1.80E+01 4.25 1.00 3.18 10000 1000
1.84E+01 6.61 1.00 3.18
1.68E+01 11.78 1.00 3.18
1.54E+01 3.49 1.00 3.18
1.51E+01 6.61 1.00 3.18
1.80E+01 3.31 1.00 3.18
1.84E+01 2.79 1.00 3.18
6.08E+01 3.03 1.00 3.18
5.39E+01 1.84 1.00 3.18
2.14E+01 2.91 1.00 3.18 10000 1000
1.97E+01 1.63 1.00 3.18
1.79E+01 3.01 1.00 3.18
1.56E+01 3.08 1.00 3.18
1.54E+01 7.77 1.00 3.18
1.81E+01 6.03 1.00 3.18
1.83E+01 12.33 1.00 3.18
5.00E-01 22.92 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.72E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.72E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.75E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:03 PM EPA Interlab L11 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L11 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L11 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/12 1:38 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:40 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L11 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L1 1 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-352
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Sb JaFS-L11-1314-T01-A 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T02-A 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T03-A 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T04-A 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T05-A 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T06-A 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T07-A 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T08-A 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T09-A 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T01-B 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T02-B 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T03-B 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T04-B 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T05-B 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T06-B 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T07-B 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T08-B 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T09-B 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T01-C 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T02-C 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T03-C 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T04-C 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T05-C 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T06-C 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T07-C 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T08-C 1 3.75E+00 U1/2
Sb JaFS-L11-1314-T09-C 1 3.75E+00 U1/2
Sb JaFS-L11-1314-B01-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.75E+00 7.76 7.50 23.90
3.75E+00 15.35 7.50 23.90
3.75E+00 3.56 7.50 23.90 10000 1000
3.75E+00 1.67 7.50 23.90
3.75E+00 3.20 7.50 23.90
3.75E+00 3.95 7.50 23.90
3.75E+00 9.09 7.50 23.90
3.75E+00 4.93 7.50 23.90
3.75E+00 11.27 7.50 23.90
3.75E+00 4.32 7.50 23.90
3.75E+00 3.77 7.50 23.90
3.75E+00 7.07 7.50 23.90 10000 1000
3.75E+00 5.07 7.50 23.90
3.75E+00 8.59 7.50 23.90
3.75E+00 3.40 7.50 23.90
3.75E+00 10.67 7.50 23.90
3.75E+00 8.27 7.50 23.90
3.75E+00 8.05 7.50 23.90
3.75E+00 9.62 7.50 23.90
3.75E+00 2.88 7.50 23.90
3.75E+00 4.95 7.50 23.90 10000 1000
3.75E+00 10.88 7.50 23.90
3.75E+00 6.46 7.50 23.90
3.75E+00 10.86 7.50 23.90
3.75E+00 6.18 7.50 23.90
3.75E+00 12.53 7.50 23.90
3.75E+00 17.03 7.50 23.90
3.75E+00 20.20 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.21E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/121:38PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L1 1 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-353
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
As JaFS-L11-1314-T01-A 1 5.50E+00 U1/2
As JaFS-L11-1314-T02-A 1 5.50E+00 U1/2
As JaFS-L11-1314-T03-A 1 5.50E+00 U1/2
As JaFS-L11-1314-T04-A 1 5.50E+00 U1/2
As JaFS-L11-1314-T05-A 1 5.50E+00 U1/2
As JaFS-L11-1314-T06-A 1 5.50E+00 U1/2
As JaFS-L11-1314-T07-A 1 5.50E+00 U1/2
As JaFS-L11-1314-T08-A 1 5.50E+00 U1/2
As JaFS-L11-1314-T09-A 1 5.50E+00 U1/2
As JaFS-L11-1314-T01-B 1 5.50E+00 U1/2
As JaFS-L11-1314-T02-B 1 5.50E+00 U1/2
As JaFS-L11-1314-T03-B 1 5.50E+00 U1/2
As JaFS-L11-1314-T04-B 1 5.50E+00 U1/2
As JaFS-L11-1314-T05-B 1 5.50E+00 U1/2
As JaFS-L11-1314-T06-B 1 5.50E+00 U1/2
As JaFS-L11-1314-T07-B 1 5.50E+00 U1/2
As JaFS-L11-1314-T08-B 1 5.50E+00 U1/2
As JaFS-L11-1314-T09-B 1 5.50E+00 U1/2
As JaFS-L11-1314-T01-C 1 5.50E+00 U1/2
As JaFS-L11-1314-T02-C 1 5.50E+00 U1/2
As JaFS-L11-1314-T03-C 1 5.50E+00 U1/2
As JaFS-L11-1314-T04-C 1 5.50E+00 U1/2
As JaFS-L11-1314-T05-C 1 5.50E+00 U1/2
As JaFS-L11-1314-T06-C 1 5.50E+00 U1/2
As JaFS-L11-1314-T07-C 1 5.50E+00 U1/2
As JaFS-L11-1314-T08-C 1 5.50E+00 U1/2
As JaFS-L11-1314-T09-C 1 5.50E+00 U1/2
As JaFS-L11-1314-B01-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.50E+00 2.68 11.00 35.00
5.50E+00 0.38 11.00 35.00
5.50E+00 4.05 11.00 35.00 10000 1000
5.50E+00 2.60 11.00 35.00
5.50E+00 1.76 11.00 35.00
5.50E+00 2.31 11.00 35.00
5.50E+00 1.72 11.00 35.00
5.50E+00 4.71 11.00 35.00
5.50E+00 3.42 11.00 35.00
5.50E+00 3.36 11.00 35.00
5.50E+00 3.29 11.00 35.00
5.50E+00 0.22 11.00 35.00 10000 1000
5.50E+00 3.14 11.00 35.00
5.50E+00 4.19 11.00 35.00
5.50E+00 2.23 11.00 35.00
5.50E+00 1.87 11.00 35.00
5.50E+00 3.47 11.00 35.00
5.50E+00 1.37 11.00 35.00
5.50E+00 3.24 11.00 35.00
5.50E+00 2.04 11.00 35.00
5.50E+00 1.48 11.00 35.00 10000 1000
5.50E+00 1.06 11.00 35.00
5.50E+00 1.81 11.00 35.00
5.50E+00 0.93 11.00 35.00
5.50E+00 2.99 11.00 35.00
5.50E+00 2.80 11.00 35.00
5.50E+00 2.59 11.00 35.00
5.50E+00 5.20 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.23E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/121:38PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L1 1 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-354
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
B JaFS-L11-1314-T01-A 1 2.09E+05
B JaFS-L11-1314-T02-A 1 5.72E+04
B JaFS-L11-1314-T03-A 1 1.91E+04
B JaFS-L11-1314-T04-A 1 8.71E+03
B JaFS-L11-1314-T05-A 1 4.61E+03
B JaFS-L11-1314-T06-A 1 2.99E+03
B JaFS-L11-1314-T07-A 1 1.99E+03
B JaFS-L11-1314-T08-A 1 1.23E+03
B JaFS-L11-1314-T09-A 1 9.25E+02
B JaFS-L11-1314-T01-B 1 2.05E+05
B JaFS-L11-1314-T02-B 1 5.84E+04
B JaFS-L11-1314-T03-B 1 1.87E+04
B JaFS-L11-1314-T04-B 1 8.81E+03
B JaFS-L11-1314-T05-B 1 4.49E+03
B JaFS-L11-1314-T06-B 1 3.06E+03
B JaFS-L11-1314-T07-B 1 2.01E+03
B JaFS-L11-1314-T08-B 1 1.27E+03
B JaFS-L11-1314-T09-B 1 9.09E+02
B JaFS-L11-1314-T01-C 1 2.04E+05
B JaFS-L11-1314-T02-C 1 5.61E+04
B JaFS-L11-1314-T03-C 1 1.85E+04
B JaFS-L11-1314-T04-C 1 8.97E+03
B JaFS-L11-1314-T05-C 1 4.80E+03
B JaFS-L11-1314-T06-C 1 3.31E+03
B JaFS-L11-1314-T07-C 1 2.18E+03
B JaFS-L11-1314-T08-C 1 1.33E+03
B JaFS-L11-1314-T09-C 1 8.44E+02
B JaFS-L11-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.09E+05 0.88 1.00 3.18
5.72E+04 0.55 1.00 3.18
1.91E+04 0.68 1.00 3.18 10000 1000
8.71E+03 0.66 1.00 3.18
4.61E+03 0.60 1.00 3.18
2.99E+03 1.13 1.00 3.18
1.99E+03 0.53 1.00 3.18
1.23E+03 1.39 1.00 3.18
9.25E+02 0.81 1.00 3.18
2.05E+05 0.72 1.00 3.18
5.84E+04 0.83 1.00 3.18
1.87E+04 1.64 1.00 3.18 10000 1000
8.81E+03 3.57 1.00 3.18
4.49E+03 1.70 1.00 3.18
3.06E+03 0.53 1.00 3.18
2.01E+03 0.38 1.00 3.18
1.27E+03 1.07 1.00 3.18
9.09E+02 0.32 1.00 3.18
2.04E+05 0.84 1.00 3.18
5.61E+04 1.16 1.00 3.18
1.85E+04 1.50 1.00 3.18 10000 1000
8.97E+03 1.86 1.00 3.18
4.80E+03 1.19 1.00 3.18
3.31E+03 0.67 1.00 3.18
2.18E+03 0.40 1.00 3.18
1.33E+03 0.82 1.00 3.18
8.44E+02 0.07 1.00 3.18
5.00E-01 8.40 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.00E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.96E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.95E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/121:38PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L1 1 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-355
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Ba JaFS-L11-1314-T01-A 1 1.29E+02
Ba JaFS-L11-1314-T02-A 1 8.79E+01
Ba JaFS-L11-1314-T03-A 1 4.74E+01
Ba JaFS-L11-1314-T04-A 1 3.51E+01
Ba JaFS-L11-1314-T05-A 1 2.98E+01
Ba JaFS-L11-1314-T06-A 1 2.10E+01
Ba JaFS-L11-1314-T07-A 1 1.78E+01
Ba JaFS-L11-1314-T08-A 1 1.68E+01
Ba JaFS-L11-1314-T09-A 1 1.05E+01
Ba JaFS-L11-1314-T01-B 1 1.31E+02
Ba JaFS-L11-1314-T02-B 1 9.04E+01
Ba JaFS-L11-1314-T03-B 1 4.77E+01
Ba JaFS-L11-1314-T04-B 1 3.47E+01
Ba JaFS-L11-1314-T05-B 1 3.12E+01
Ba JaFS-L11-1314-T06-B 1 2.17E+01
Ba JaFS-L11-1314-T07-B 1 1.70E+01
Ba JaFS-L11-1314-T08-B 1 1.30E+01
Ba JaFS-L11-1314-T09-B 1 1.27E+01
Ba JaFS-L11-1314-T01-C 1 1.34E+02
Ba JaFS-L11-1314-T02-C 1 8.74E+01
Ba JaFS-L11-1314-T03-C 1 4.60E+01
Ba JaFS-L11-1314-T04-C 1 3.37E+01
Ba JaFS-L11-1314-T05-C 1 2.89E+01
Ba JaFS-L11-1314-T06-C 1 2.07E+01
Ba JaFS-L11-1314-T07-C 1 1.54E+01
Ba JaFS-L11-1314-T08-C 1 1.36E+01
Ba JaFS-L11-1314-T09-C 1 1.26E+01
Ba JaFS-L11-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.29E+02 1.06 1.00 3.18
8.79E+01 0.63 1.00 3.18
4.74E+01 1.80 1.00 3.18 10000 1000
3.51E+01 1.34 1.00 3.18
2.98E+01 0.43 1.00 3.18
2.10E+01 1.67 1.00 3.18
1.78E+01 3.66 1.00 3.18
1.68E+01 1.04 1.00 3.18
1.05E+01 4.62 1.00 3.18
1.31E+02 0.98 1.00 3.18
9.04E+01 0.76 1.00 3.18
4.77E+01 0.75 1.00 3.18 10000 1000
3.47E+01 0.35 1.00 3.18
3.12E+01 0.47 1.00 3.18
2.17E+01 1.04 1.00 3.18
1.70E+01 3.01 1.00 3.18
1.30E+01 0.88 1.00 3.18
1.27E+01 1.99 1.00 3.18
1.34E+02 0.85 1.00 3.18
8.74E+01 0.46 1.00 3.18
4.60E+01 2.20 1.00 3.18 10000 1000
3.37E+01 2.03 1.00 3.18
2.89E+01 0.40 1.00 3.18
2.07E+01 1.05 1.00 3.18
1.54E+01 1.03 1.00 3.18
1.36E+01 0.22 1.00 3.18
1.26E+01 1.89 1.00 3.18
5.00E-01 3.21 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.62E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.95E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/121:38PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L1 1 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-356
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Be JaFS-L11-1314-T01-A 1 9.50E-01 U1/2
Be JaFS-L11-1314-T02-A 1 9.50E-01 U1/2
Be JaFS-L11-1314-T03-A 1 9.50E-01 U1/2
Be JaFS-L11-1314-T04-A 1 9.50E-01 U1/2
Be JaFS-L11-1314-T05-A 1 9.50E-01 U1/2
Be JaFS-L11-1314-T06-A 1 9.50E-01 U1/2
Be JaFS-L11-1314-T07-A 1 9.50E-01 U1/2
Be JaFS-L11-1314-T08-A 1 9.50E-01 U1/2
Be JaFS-L11-1314-T09-A 1 9.50E-01 U1/2
Be JaFS-L11-1314-T01-B 1 9.50E-01 U1/2
Be JaFS-L11-1314-T02-B 1 9.50E-01 U1/2
Be JaFS-L11-1314-T03-B 1 9.50E-01 U1/2
Be JaFS-L11-1314-T04-B 1 9.50E-01 U1/2
Be JaFS-L11-1314-T05-B 1 9.50E-01 U1/2
Be JaFS-L11-1314-T06-B 1 9.50E-01 U1/2
Be JaFS-L11-1314-T07-B 1 9.50E-01 U1/2
Be JaFS-L11-1314-T08-B 1 9.50E-01 U1/2
Be JaFS-L11-1314-T09-B 1 9.50E-01 U1/2
Be JaFS-L11-1314-T01-C 1 9.50E-01 U1/2
Be JaFS-L11-1314-T02-C 1 9.50E-01 U1/2
Be JaFS-L11-1314-T03-C 1 9.50E-01 U1/2
Be JaFS-L11-1314-T04-C 1 9.50E-01 U1/2
Be JaFS-L11-1314-T05-C 1 9.50E-01 U1/2
Be JaFS-L11-1314-T06-C 1 9.50E-01 U1/2
Be JaFS-L11-1314-T07-C 1 9.50E-01 U1/2
Be JaFS-L11-1314-T08-C 1 9.50E-01 U1/2
Be JaFS-L11-1314-T09-C 1 9.50E-01 U1/2
Be JaFS-L11-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 14.70 1.90 6.00
9.50E-01 4.82 1.90 6.00
9.50E-01 5.26 1.90 6.00 10000 1000
9.50E-01 1.54 1.90 6.00
9.50E-01 9.59 1.90 6.00
9.50E-01 10.23 1.90 6.00
9.50E-01 6.76 1.90 6.00
9.50E-01 9.47 1.90 6.00
9.50E-01 8.17 1.90 6.00
9.50E-01 0.72 1.90 6.00
9.50E-01 17.13 1.90 6.00
9.50E-01 8.47 1.90 6.00 10000 1000
9.50E-01 19.27 1.90 6.00
9.50E-01 8.80 1.90 6.00
9.50E-01 10.71 1.90 6.00
9.50E-01 3.80 1.90 6.00
9.50E-01 6.10 1.90 6.00
9.50E-01 3.65 1.90 6.00
9.50E-01 13.69 1.90 6.00
9.50E-01 9.28 1.90 6.00
9.50E-01 1.14 1.90 6.00 10000 1000
9.50E-01 3.11 1.90 6.00
9.50E-01 10.78 1.90 6.00
9.50E-01 5.42 1.90 6.00
9.50E-01 7.87 1.90 6.00
9.50E-01 8.15 1.90 6.00
9.50E-01 8.15 1.90 6.00
9.50E-01 14.39 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.99E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.91 E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/121:38PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L1 1 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-357
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cd JaFS-L11-1314-T01-A 1 1.94E+01
Cd JaFS-L11-1314-T02-A 1 3.59E+00 E
Cd JaFS-L11-1314-T03-A 1 1.10E+00 U1/2
Cd JaFS-L11-1314-T04-A 1 1.10E+00 U1/2
Cd JaFS-L11-1314-T05-A 1 1.10E+00 U1/2
Cd JaFS-L11-1314-T06-A 1 1.10E+00 U1/2
Cd JaFS-L11-1314-T07-A 1 1.10E+00 U1/2
Cd JaFS-L11-1314-T08-A 1 1.10E+00 U1/2
Cd JaFS-L11-1314-T09-A 1 1.10E+00 U1/2
Cd JaFS-L11-1314-T01-B 1 1.80E+01
Cd JaFS-L11-1314-T02-B 1 3.40E+00 E
Cd JaFS-L11-1314-T03-B 1 1.10E+00 U1/2
Cd JaFS-L11-1314-T04-B 1 1.10E+00 U1/2
Cd JaFS-L11-1314-T05-B 1 1.10E+00 U1/2
Cd JaFS-L11-1314-T06-B 1 1.10E+00 U1/2
Cd JaFS-L11-1314-T07-B 1 1.10E+00 U1/2
Cd JaFS-L11-1314-T08-B 1 1.10E+00 U1/2
Cd JaFS-L11-1314-T09-B 1 1.10E+00 U1/2
Cd JaFS-L11-1314-T01-C 1 1.69E+01
Cd JaFS-L11-1314-T02-C 1 3.12E+00 E
Cd JaFS-L11-1314-T03-C 1 1.10E+00 U1/2
Cd JaFS-L11-1314-T04-C 1 1.10E+00 U1/2
Cd JaFS-L11-1314-T05-C 1 1.10E+00 U1/2
Cd JaFS-L11-1314-T06-C 1 1.10E+00 U1/2
Cd JaFS-L11-1314-T07-C 1 1.10E+00 U1/2
Cd JaFS-L11-1314-T08-C 1 1.10E+00 U1/2
Cd JaFS-L11-1314-T09-C 1 1.10E+00 U1/2
Cd JaFS-L11-1314-B01-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.94E+01 4.66 2.20 7.00
3.59E+00 12.86 2.20 7.00
1.10E+00 5.46 2.20 7.00 10000 1000
1.10E+00 17.99 2.20 7.00
1.10E+00 21.65 2.20 7.00
1.10E+00 9.30 2.20 7.00
1.10E+00 4.10 2.20 7.00
1.10E+00 1.22 2.20 7.00
1.10E+00 4.54 2.20 7.00
1.80E+01 3.40 2.20 7.00
3.40E+00 7.62 2.20 7.00
1.10E+00 12.71 2.20 7.00 10000 1000
1.10E+00 14.38 2.20 7.00
1.10E+00 18.62 2.20 7.00
1.10E+00 15.20 2.20 7.00
1.10E+00 1.46 2.20 7.00
1.10E+00 18.93 2.20 7.00
1.10E+00 8.05 2.20 7.00
1.69E+01 5.92 2.20 7.00
3.12E+00 14.47 2.20 7.00
1.10E+00 17.87 2.20 7.00 10000 1000
1.10E+00 12.51 2.20 7.00
1.10E+00 16.12 2.20 7.00
1.10E+00 9.30 2.20 7.00
1.10E+00 9.89 2.20 7.00
1.10E+00 4.98 2.20 7.00
1.10E+00 6.01 2.20 7.00
1.10E+00 18.40 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.60E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.10E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.61 E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/12 1:38 PM EPA Interlab L11 1314 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L1 1 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-358
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Ca JaFS-L11-1314-T01-A 1 3.30E+05
Ca JaFS-L11-1314-T02-A 1 3.57E+04
Ca JaFS-L11-1314-T03-A 1 2.02E+04
Ca JaFS-L11-1314-T04-A 1 1.83E+04
Ca JaFS-L11-1314-T05-A 1 1.72E+04
Ca JaFS-L11-1314-T06-A 1 1.15E+04
Ca JaFS-L11-1314-T07-A 1 1.03E+04
Ca JaFS-L11-1314-T08-A 1 9.62E+03
Ca JaFS-L11-1314-T09-A 1 9.89E+03
Ca JaFS-L11-1314-T01-B 1 3.34E+05
Ca JaFS-L11-1314-T02-B 1 3.81E+04
Ca JaFS-L11-1314-T03-B 1 2.03E+04
Ca JaFS-L11-1314-T04-B 1 1.81E+04
Ca JaFS-L11-1314-T05-B 1 1.68E+04
Ca JaFS-L11-1314-T06-B 1 1.19E+04
Ca JaFS-L11-1314-T07-B 1 1.04E+04
Ca JaFS-L11-1314-T08-B 1 9.69E+03
Ca JaFS-L11-1314-T09-B 1 9.78E+03
Ca JaFS-L11-1314-T01-C 1 3.27E+05
Ca JaFS-L11-1314-T02-C 1 4.03E+04
Ca JaFS-L11-1314-T03-C 1 2.18E+04
Ca JaFS-L11-1314-T04-C 1 1.86E+04
Ca JaFS-L11-1314-T05-C 1 1.69E+04
Ca JaFS-L11-1314-T06-C 1 1.13E+04
Ca JaFS-L11-1314-T07-C 1 1.13E+04
Ca JaFS-L11-1314-T08-C 1 9.89E+03
Ca JaFS-L11-1314-T09-C 1 1.01E+04
Ca JaFS-L11-1314-B01-A 1 1.30E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.30E+05 0.45 2.60 8.30
3.57E+04 1.29 2.60 8.30
2.02E+04 0.70 2.60 8.30 10000 1000
1.83E+04 0.31 2.60 8.30
1.72E+04 0.33 2.60 8.30
1.15E+04 0.28 2.60 8.30
1.03E+04 0.50 2.60 8.30
9.62E+03 0.27 2.60 8.30
9.89E+03 0.64 2.60 8.30
3.34E+05 0.67 2.60 8.30
3.81 E+04 0.66 2.60 8.30
2.03E+04 1.32 2.60 8.30 10000 1000
1.81 E+04 0.31 2.60 8.30
1.68E+04 0.50 2.60 8.30
1.19E+04 0.38 2.60 8.30
1.04E+04 0.33 2.60 8.30
9.69E+03 1.04 2.60 8.30
9.78E+03 0.45 2.60 8.30
3.27E+05 0.38 2.60 8.30
4.03E+04 0.51 2.60 8.30
2.18E+04 0.53 2.60 8.30 10000 1000
1.86E+04 0.49 2.60 8.30
1.69E+04 0.70 2.60 8.30
1.13E+04 0.65 2.60 8.30
1.13E+04 0.75 2.60 8.30
9.89E+03 0.99 2.60 8.30
1.01E+04 0.92 2.60 8.30
1.30E+00 2.38 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.11E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.11E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.27E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/12 1:38 PM EPA Interlab L11 1314 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:43 PM EPA Interlab L11 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L11 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-359
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cr JaFS-L11-1314-T01-A 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T02-A 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T03-A 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T04-A 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T05-A 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T06-A 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T07-A 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T08-A 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T09-A 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T01-B 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T02-B 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T03-B 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T04-B 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T05-B 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T06-B 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T07-B 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T08-B 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T09-B 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T01-C 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T02-C 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T03-C 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T04-C 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T05-C 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T06-C 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T07-C 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T08-C 1 6.00E-01 U1/2
Cr JaFS-L11-1314-T09-C 1 6.00E-01 U1/2
Cr JaFS-L11-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 34.91 1.20 3.82
6.00E-01 50.21 1.20 3.82
6.00E-01 30.44 1.20 3.82 10000 1000
6.00E-01 51.24 1.20 3.82
6.00E-01 33.45 1.20 3.82
6.00E-01 25.41 1.20 3.82
6.00E-01 49.62 1.20 3.82
6.00E-01 18.96 1.20 3.82
6.00E-01 20.47 1.20 3.82
6.00E-01 27.06 1.20 3.82
6.00E-01 7.11 1.20 3.82
6.00E-01 49.93 1.20 3.82 10000 1000
6.00E-01 13.63 1.20 3.82
6.00E-01 54.49 1.20 3.82
6.00E-01 32.11 1.20 3.82
6.00E-01 9.53 1.20 3.82
6.00E-01 29.96 1.20 3.82
6.00E-01 41.36 1.20 3.82
6.00E-01 54.26 1.20 3.82
6.00E-01 46.14 1.20 3.82
6.00E-01 59.17 1.20 3.82 10000 1000
6.00E-01 29.08 1.20 3.82
6.00E-01 40.70 1.20 3.82
6.00E-01 33.33 1.20 3.82
6.00E-01 56.67 1.20 3.82
6.00E-01 45.86 1.20 3.82
6.00E-01 43.11 1.20 3.82
6.00E-01 39.18 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.15E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.80E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/121:38PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L1 1 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-360
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Co JaFS-L11-1314-T01-A 1 9.00E-01 U1/2
Co JaFS-L11-1314-T02-A 1 9.00E-01 U1/2
Co JaFS-L11-1314-T03-A 1 9.00E-01 U1/2
Co JaFS-L11-1314-T04-A 1 9.00E-01 U1/2
Co JaFS-L11-1314-T05-A 1 9.00E-01 U1/2
Co JaFS-L11-1314-T06-A 1 9.00E-01 U1/2
Co JaFS-L11-1314-T07-A 1 9.00E-01 U1/2
Co JaFS-L11-1314-T08-A 1 9.00E-01 U1/2
Co JaFS-L11-1314-T09-A 1 9.00E-01 U1/2
Co JaFS-L11-1314-T01-B 1 9.00E-01 U1/2
Co JaFS-L11-1314-T02-B 1 9.00E-01 U1/2
Co JaFS-L11-1314-T03-B 1 9.00E-01 U1/2
Co JaFS-L11-1314-T04-B 1 9.00E-01 U1/2
Co JaFS-L11-1314-T05-B 1 9.00E-01 U1/2
Co JaFS-L11-1314-T06-B 1 9.00E-01 U1/2
Co JaFS-L11-1314-T07-B 1 9.00E-01 U1/2
Co JaFS-L11-1314-T08-B 1 9.00E-01 U1/2
Co JaFS-L11-1314-T09-B 1 9.00E-01 U1/2
Co JaFS-L11-1314-T01-C 1 9.00E-01 U1/2
Co JaFS-L11-1314-T02-C 1 9.00E-01 U1/2
Co JaFS-L11-1314-T03-C 1 9.00E-01 U1/2
Co JaFS-L11-1314-T04-C 1 9.00E-01 U1/2
Co JaFS-L11-1314-T05-C 1 9.00E-01 U1/2
Co JaFS-L11-1314-T06-C 1 9.00E-01 U1/2
Co JaFS-L11-1314-T07-C 1 9.00E-01 U1/2
Co JaFS-L11-1314-T08-C 1 9.00E-01 U1/2
Co JaFS-L11-1314-T09-C 1 9.00E-01 U1/2
Co JaFS-L11-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 6.86 1.80 5.72
9.00E-01 6.53 1.80 5.72
9.00E-01 7.04 1.80 5.72 10000 1000
9.00E-01 1.76 1.80 5.72
9.00E-01 12.32 1.80 5.72
9.00E-01 14.41 1.80 5.72
9.00E-01 5.09 1.80 5.72
9.00E-01 6.58 1.80 5.72
9.00E-01 9.24 1.80 5.72
9.00E-01 2.95 1.80 5.72
9.00E-01 7.78 1.80 5.72
9.00E-01 9.48 1.80 5.72 10000 1000
9.00E-01 3.58 1.80 5.72
9.00E-01 9.86 1.80 5.72
9.00E-01 7.98 1.80 5.72
9.00E-01 6.42 1.80 5.72
9.00E-01 5.25 1.80 5.72
9.00E-01 6.03 1.80 5.72
9.00E-01 7.54 1.80 5.72
9.00E-01 4.06 1.80 5.72
9.00E-01 10.46 1.80 5.72 10000 1000
9.00E-01 6.95 1.80 5.72
9.00E-01 10.51 1.80 5.72
9.00E-01 5.07 1.80 5.72
9.00E-01 4.34 1.80 5.72
9.00E-01 1.66 1.80 5.72
9.00E-01 8.00 1.80 5.72
9.00E-01 12.33 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.92E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.55E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.75E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/121:38PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L1 1 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-361
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Cu JaFS-L11-1314-T01-A 1 1.27E+03
Cu JaFS-L11-1314-T02-A 1 8.45E+02
Cu JaFS-L11-1314-T03-A 1 5.48E+02
Cu JaFS-L11-1314-T04-A 1 3.57E+02
Cu JaFS-L11-1314-T05-A 1 2.85E+02
Cu JaFS-L11-1314-T06-A 1 2.06E+02
Cu JaFS-L11-1314-T07-A 1 1.40E+02
Cu JaFS-L11-1314-T08-A 1 8.61 E+01
Cu JaFS-L11-1314-T09-A 1 7.24E+01
Cu JaFS-L11-1314-T01-B 1 1.28E+03
Cu JaFS-L11-1314-T02-B 1 8.30E+02
Cu JaFS-L11-1314-T03-B 1 5.53E+02
Cu JaFS-L11-1314-T04-B 1 3.63E+02
Cu JaFS-L11-1314-T05-B 1 2.94E+02
Cu JaFS-L11-1314-T06-B 1 2.14E+02
Cu JaFS-L11-1314-T07-B 1 1.48E+02
Cu JaFS-L11-1314-T08-B 1 8.56E+01
Cu JaFS-L11-1314-T09-B 1 6.85E+01
Cu JaFS-L11-1314-T01-C 1 1.28E+03
Cu JaFS-L11-1314-T02-C 1 8.84E+02
Cu JaFS-L11-1314-T03-C 1 5.11E+02
Cu JaFS-L11-1314-T04-C 1 3.31E+02
Cu JaFS-L11-1314-T05-C 1 2.80E+02
Cu JaFS-L11-1314-T06-C 1 2.27E+02
Cu JaFS-L11-1314-T07-C 1 1.44E+02
Cu JaFS-L11-1314-T08-C 1 8.70E+01
Cu JaFS-L11-1314-T09-C 1 6.55E+01
Cu JaFS-L11-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.27E+03 0.91 3.70 11.80
8.45E+02 0.44 3.70 11.80
5.48E+02 0.84 3.70 11.80 10000 1000
3.57E+02 1.92 3.70 11.80
2.85E+02 0.94 3.70 11.80
2.06E+02 0.76 3.70 11.80
1.40E+02 2.44 3.70 11.80
8.61 E+01 3.03 3.70 11.80
7.24E+01 3.51 3.70 11.80
1.28E+03 0.99 3.70 11.80
8.30E+02 1.11 3.70 11.80
5.53E+02 1.13 3.70 11.80 10000 1000
363E+02 0.39 3.70 11.80
2.94E+02 1.32 3.70 11.80
2.14E+02 0.51 3.70 11.80
1.48E+02 1.00 3.70 11.80
8.56E+01 2.32 3.70 11.80
6.85E+01 0.60 3.70 11.80
1.28E+03 0.29 3.70 11.80
8.84E+02 0.44 3.70 11.80
5.11E+02 0.96 3.70 11.80 10000 1000
3.31E+02 0.80 3.70 11.80
2.80E+02 1.39 3.70 11.80
2.27E+02 1.34 3.70 11.80
1.44E+02 0.50 3.70 11.80
8.70E+01 1.04 3.70 11.80
6.55E+01 1.41 3.70 11.80
1.85E+00 7.37 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.51E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.49E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.52E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L11 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:20 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L11 1314 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L11 1314 JaFS
3/6/12 1:30 PM EPA Interlab L11 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L11 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/12 1:38 PM EPA Interlab L11 1314 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L11 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314JaFS
3/6/12 1:48 PM EPA Interlab L11 1314JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-362
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Fe JaFS-L11-1314-T01-A 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T02-A 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T03-A 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T04-A 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T05-A 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T06-A 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T07-A 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T08-A 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T09-A 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T01-B 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T02-B 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T03-B 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T04-B 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T05-B 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T06-B 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T07-B 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T08-B 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T09-B 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T01-C 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T02-C 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T03-C 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T04-C 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T05-C 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T06-C 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T07-C 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T08-C 1 1.00E+00 U1/2
Fe JaFS-L11-1314-T09-C 1 1.00E+00 U1/2
Fe JaFS-L11-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 6.69 2.00 6.40
1.00E+00 1.98 2.00 6.40
1.00E+00 6.81 2.00 6.40 10000 1000
1.00E+00 0.64 2.00 6.40
1.00E+00 5.69 2.00 6.40
1.00E+00 7.18 2.00 6.40
1.00E+00 6.43 2.00 6.40
1.00E+00 1.51 2.00 6.40
1.00E+00 1.01 2.00 6.40
1.00E+00 5.27 2.00 6.40
1.00E+00 6.62 2.00 6.40
1.00E+00 2.09 2.00 6.40 10000 1000
1.00E+00 1.99 2.00 6.40
1.00E+00 2.16 2.00 6.40
1.00E+00 7.05 2.00 6.40
1.00E+00 2.60 2.00 6.40
1.00E+00 6.32 2.00 6.40
1.00E+00 0.98 2.00 6.40
1.00E+00 6.19 2.00 6.40
1.00E+00 3.75 2.00 6.40
1.00E+00 2.17 2.00 6.40 10000 1000
1.00E+00 4.74 2.00 6.40
1.00E+00 2.73 2.00 6.40
1.00E+00 11.33 2.00 6.40
1.00E+00 0.66 2.00 6.40
1.00E+00 5.12 2.00 6.40
1.00E+00 5.82 2.00 6.40
1.00E+00 10.39 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.37E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/121:38PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L1 1 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-363
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
ug/L
Pb JaFS-L11-1314-T01-A 1 9.45E+01
Pb JaFS-L11-1314-T02-A 1 1.10E+02
Pb JaFS-L11-1314-T03-A 1 1.01E+02
Pb JaFS-L11-1314-T04-A 1 8.25E+01
Pb JaFS-L11-1314-T05-A 1 7.92E+01
Pb JaFS-L11-1314-T06-A 1 4.43E+01
Pb JaFS-L11-1314-T07-A 1 3.85E+01
Pb JaFS-L11-1314-T08-A 1 2.85E+01
Pb JaFS-L11-1314-T09-A 1 2.89E+01
Pb JaFS-L11-1314-T01-B 1 9.56E+01
Pb JaFS-L11-1314-T02-B 1 1.25E+02
Pb JaFS-L11-1314-T03-B 1 1.10E+02
Pb JaFS-L11-1314-T04-B 1 9.05E+01
Pb JaFS-L11-1314-T05-B 1 7.68E+01
Pb JaFS-L11-1314-T06-B 1 5.16E+01
Pb JaFS-L11-1314-T07-B 1 4.39E+01
Pb JaFS-L11-1314-T08-B 1 2.76E+01
Pb JaFS-L11-1314-T09-B 1 2.52E+01
Pb JaFS-L11-1314-T01-C 1 9.43E+01
Pb JaFS-L11-1314-T02-C 1 1.17E+02
Pb JaFS-L11-1314-T03-C 1 1.05E+02
Pb JaFS-L11-1314-T04-C 1 8.32E+01
Pb JaFS-L11-1314-T05-C 1 7.38E+01
Pb JaFS-L11-1314-T06-C 1 4.64E+01
Pb JaFS-L11-1314-T07-C 1 3.86E+01
Pb JaFS-L11-1314-T08-C 1 2.65E+01
Pb JaFS-L11-1314-T09-C 1 2.73E+01
Pb JaFS-L11-1314-B01-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.45E+01 4.10 6.80 21.60
1.10E+02 2.99 6.80 21.60
1.01E+02 3.48 6.80 21.60 10000 1000
8.25E+01 7.40 6.80 21.60
7.92E+01 4.98 6.80 21.60
4.43E+01 10.87 6.80 21.60
3.85E+01 1.15 6.80 21.60
2.85E+01 4.31 6.80 21.60
2.89E+01 0.96 6.80 21.60
9.56E+01 5.24 6.80 21.60
1.25E+02 7.41 6.80 21.60
1.10E+02 3.11 6.80 21.60 10000 1000
9.05E+01 3.61 6.80 21.60
7.68E+01 2.59 6.80 21.60
5.16E+01 6.83 6.80 21.60
4.39E+01 6.01 6.80 21.60
2.76E+01 3.28 6.80 21.60
2.52E+01 1.48 6.80 21.60
9.43E+01 2.04 6.80 21.60
1.17E+02 1.11 6.80 21.60
1.05E+02 4.15 6.80 21.60 10000 1000
8.32E+01 2.97 6.80 21.60
7.38E+01 3.02 6.80 21.60
464E+01 4.68 6.80 21.60
386E+01 6.00 6.80 21.60
2.65E+01 5.87 6.80 21.60
2.73E+01 8.07 6.80 21.60
340E+00 23.59 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.96E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/12 1:38 PM EPA Interlab L11 1314 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:43 PM EPA Interlab L11 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L11 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-364
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Li JaFS-L11-1314-T01-A 1 6.73E+01
Li JaFS-L11-1314-T02-A 1 9.24E+00
Li JaFS-L11-1314-T03-A 1 3.51E+00 E
Li JaFS-L11-1314-T04-A 1 9.50E-01 U1/2
Li JaFS-L11-1314-T05-A 1 9.50E-01 U1/2
Li JaFS-L11-1314-T06-A 1 9.50E-01 U1/2
Li JaFS-L11-1314-T07-A 1 9.50E-01 U1/2
Li JaFS-L11-1314-T08-A 1 9.50E-01 U1/2
Li JaFS-L11-1314-T09-A 1 9.50E-01 U1/2
Li JaFS-L11-1314-T01-B 1 6.49E+01
Li JaFS-L11-1314-T02-B 1 8.74E+00
Li JaFS-L11-1314-T03-B 1 3.58E+00 E
Li JaFS-L11-1314-T04-B 1 9.50E-01 U1/2
Li JaFS-L11-1314-T05-B 1 9.50E-01 U1/2
Li JaFS-L11-1314-T06-B 1 9.50E-01 U1/2
Li JaFS-L11-1314-T07-B 1 9.50E-01 U1/2
Li JaFS-L11-1314-T08-B 1 9.50E-01 U1/2
Li JaFS-L11-1314-T09-B 1 9.50E-01 U1/2
Li JaFS-L11-1314-T01-C 1 6.64E+01
Li JaFS-L11-1314-T02-C 1 8.65E+00
Li JaFS-L11-1314-T03-C 1 3.60E+00 E
Li JaFS-L11-1314-T04-C 1 9.50E-01 U1/2
Li JaFS-L11-1314-T05-C 1 9.50E-01 U1/2
Li JaFS-L11-1314-T06-C 1 9.50E-01 U1/2
Li JaFS-L11-1314-T07-C 1 9.50E-01 U1/2
Li JaFS-L11-1314-T08-C 1 9.50E-01 U1/2
Li JaFS-L11-1314-T09-C 1 9.50E-01 U1/2
Li JaFS-L11-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.73E+01 2.50 1.90 6.00
9.24E+00 7.82 1.90 6.00
3.51E+00 20.55 1.90 6.00 10000 1000
9.50E-01 15.06 1.90 6.00
9.50E-01 21.07 1.90 6.00
9.50E-01 5.80 1.90 6.00
9.50E-01 17.93 1.90 6.00
9.50E-01 36.00 1.90 6.00
9.50E-01 7.75 1.90 6.00
6.49E+01 5.06 1.90 6.00
8.74E+00 3.55 1.90 6.00
3.58E+00 8.74 1.90 6.00 10000 1000
9.50E-01 9.46 1.90 6.00
9.50E-01 23.94 1.90 6.00
9.50E-01 22.95 1.90 6.00
9.50E-01 20.19 1.90 6.00
9.50E-01 5.40 1.90 6.00
9.50E-01 17.73 1.90 6.00
6.64E+01 0.74 1.90 6.00
8.65E+00 18.82 1.90 6.00
3.60E+00 16.33 1.90 6.00 10000 1000
9.50E-01 11.79 1.90 6.00
9.50E-01 6.84 1.90 6.00
9.50E-01 10.43 1.90 6.00
9.50E-01 11.54 1.90 6.00
9.50E-01 20.74 1.90 6.00
9.50E-01 22.17 1.90 6.00
9.50E-01 41.77 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.41 E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.96E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/12 1:38 PM EPA Interlab L11 1314 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L1 1 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-365
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Mn JaFS-L11-1314-T01-A 1 2.85E+02
Mn JaFS-L11-1314-T02-A 1 3.38E+01
Mn JaFS-L11-1314-T03-A 1 2.43E+01
Mn JaFS-L11-1314-T04-A 1 1.60E+01
Mn JaFS-L11-1314-T05-A 1 1.28E+01
Mn JaFS-L11-1314-T06-A 1 9.34E+00
Mn JaFS-L11-1314-T07-A 1 8.23E+00
Mn JaFS-L11-1314-T08-A 1 6.94E+00
Mn JaFS-L11-1314-T09-A 1 6.82E+00
Mn JaFS-L11-1314-T01-B 1 2.89E+02
Mn JaFS-L11-1314-T02-B 1 3.58E+01
Mn JaFS-L11-1314-T03-B 1 2.47E+01
Mn JaFS-L11-1314-T04-B 1 1.68E+01
Mn JaFS-L11-1314-T05-B 1 1.23E+01
Mn JaFS-L11-1314-T06-B 1 9.56E+00
Mn JaFS-L11-1314-T07-B 1 8.70E+00
Mn JaFS-L11-1314-T08-B 1 7.24E+00
Mn JaFS-L11-1314-T09-B 1 5.84E+00 E
Mn JaFS-L11-1314-T01-C 1 2.85E+02
Mn JaFS-L11-1314-T02-C 1 3.71E+01
Mn JaFS-L11-1314-T03-C 1 2.52E+01
Mn JaFS-L11-1314-T04-C 1 1.59E+01
Mn JaFS-L11-1314-T05-C 1 1.21E+01
Mn JaFS-L11-1314-T06-C 1 9.74E+00
Mn JaFS-L11-1314-T07-C 1 7.88E+00
Mn JaFS-L11-1314-T08-C 1 7.37E+00
Mn JaFS-L11-1314-T09-C 1 6.29E+00 E
Mn JaFS-L11-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.85E+02 1.06 2.00 6.40
3.38E+01 0.95 2.00 6.40
2.43E+01 1.19 2.00 6.40 10000 1000
1.60E+01 0.74 2.00 6.40
1.28E+01 1.48 2.00 6.40
9.34E+00 1.37 2.00 6.40
8.23E+00 3.83 2.00 6.40
6.94E+00 1.39 2.00 6.40
6.82E+00 1.28 2.00 6.40
2.89E+02 0.96 2.00 6.40
3.58E+01 1.97 2.00 6.40
2.47E+01 2.75 2.00 6.40 10000 1000
1.68E+01 1.21 2.00 6.40
1.23E+01 0.64 2.00 6.40
9.56E+00 3.84 2.00 6.40
8.70E+00 2.60 2.00 6.40
7.24E+00 2.62 2.00 6.40
5.84E+00 3.70 2.00 6.40
2.85E+02 0.22 2.00 6.40
3.71 E+01 0.63 2.00 6.40
2.52E+01 1.76 2.00 6.40 10000 1000
1.59E+01 0.97 2.00 6.40
1.21 E+01 0.59 2.00 6.40
9.74E+00 1.91 2.00 6.40
7.88E+00 0.47 2.00 6.40
7.37E+00 0.07 2.00 6.40
6.29E+00 1.03 2.00 6.40
1.00E+00 4.10 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/121:38PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L1 1 1314 JaFS
3/6/12 12:57 PM EPA Interlab L1 1 1314 JaFS
1-366
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Mg JaFS-L11-1314-T01-A 1 6.05E+04
Mg JaFS-L11-1314-T02-A 1 7.50E+03
Mg JaFS-L11-1314-T03-A 1 2.63E+03
Mg JaFS-L11-1314-T04-A 1 2.20E+03
Mg JaFS-L11-1314-T05-A 1 2.22E+03
Mg JaFS-L11-1314-T06-A 1 1.83E+03
Mg JaFS-L11-1314-T07-A 1 1.57E+03
Mg JaFS-L11-1314-T08-A 1 1.28E+03
Mg JaFS-L11-1314-T09-A 1 1.10E+03
Mg JaFS-L11-1314-T01-B 1 6.04E+04
Mg JaFS-L11-1314-T02-B 1 7.12E+03
Mg JaFS-L11-1314-T03-B 1 2.55E+03
Mg JaFS-L11-1314-T04-B 1 2.18E+03
Mg JaFS-L11-1314-T05-B 1 2.28E+03
Mg JaFS-L11-1314-T06-B 1 1.86E+03
Mg JaFS-L11-1314-T07-B 1 1.57E+03
Mg JaFS-L11-1314-T08-B 1 1.21E+03
Mg JaFS-L11-1314-T09-B 1 1.30E+03
Mg JaFS-L11-1314-T01-C 1 5.84E+04
Mg JaFS-L11-1314-T02-C 1 7.73E+03
Mg JaFS-L11-1314-T03-C 1 3.06E+03
Mg JaFS-L11-1314-T04-C 1 2.33E+03
Mg JaFS-L11-1314-T05-C 1 2.42E+03
Mg JaFS-L11-1314-T06-C 1 1.85E+03
Mg JaFS-L11-1314-T07-C 1 1.52E+03
Mg JaFS-L11-1314-T08-C 1 1.39E+03
Mg JaFS-L11-1314-T09-C 1 1.40E+03
Mg JaFS-L11-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.05E+04 1.07 1.00 3.18
7.50E+03 1.67 1.00 3.18
2.63E+03 0.54 1.00 3.18 10000 1000
2.20E+03 1.08 1.00 3.18
2.22E+03 1.37 1.00 3.18
1.83E+03 0.14 1.00 3.18
1.57E+03 0.92 1.00 3.18
1.28E+03 0.53 1.00 3.18
1.10E+03 0.97 1.00 3.18
6.04E+04 0.77 1.00 3.18
7.12E+03 0.68 1.00 3.18
2.55E+03 1.49 1.00 3.18 10000 1000
2.18E+03 0.98 1.00 3.18
2.28E+03 1.67 1.00 3.18
1.86E+03 0.61 1.00 3.18
1.57E+03 0.47 1.00 3.18
1.21E+03 0.73 1.00 3.18
1.30E+03 1.34 1.00 3.18
5.84E+04 0.82 1.00 3.18
7.73E+03 0.83 1.00 3.18
3.06E+03 0.54 1.00 3.18 10000 1000
2.33E+03 1.02 1.00 3.18
2.42E+03 0.43 1.00 3.18
1.85E+03 0.64 1.00 3.18
1.52E+03 0.25 1.00 3.18
1.39E+03 1.76 1.00 3.18
1.40E+03 1.23 1.00 3.18
5.00E-01 3.30 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.58E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.52E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.98E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/121:38PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L1 1 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-367
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Mo JaFS-L11-1314-T01-A 1 1.53E+02
Mo JaFS-L11-1314-T02-A 1 4.23E+01
Mo JaFS-L11-1314-T03-A 1 1.90E+01
Mo JaFS-L11-1314-T04-A 1 1.19E+01
Mo JaFS-L11-1314-T05-A 1 1.28E+01
Mo JaFS-L11-1314-T06-A 1 1.01E+01
Mo JaFS-L11-1314-T07-A 1 8.34E+00
Mo JaFS-L11-1314-T08-A 1 5.49E+00
Mo JaFS-L11-1314-T09-A 1 5.01E+00
Mo JaFS-L11-1314-T01-B 1 1.38E+02
Mo JaFS-L11-1314-T02-B 1 4.04E+01
Mo JaFS-L11-1314-T03-B 1 1.74E+01
Mo JaFS-L11-1314-T04-B 1 1.36E+01
Mo JaFS-L11-1314-T05-B 1 9.17E+00
Mo JaFS-L11-1314-T06-B 1 9.27E+00
Mo JaFS-L11-1314-T07-B 1 6.53E+00
Mo JaFS-L11-1314-T08-B 1 4.21E+00
Mo JaFS-L11-1314-T09-B 1 6.00E+00
Mo JaFS-L11-1314-T01-C 1 1.31E+02
Mo JaFS-L11-1314-T02-C 1 3.79E+01
Mo JaFS-L11-1314-T03-C 1 1.82E+01
Mo JaFS-L11-1314-T04-C 1 1.14E+01
Mo JaFS-L11-1314-T05-C 1 1.45E+01
Mo JaFS-L11-1314-T06-C 1 6.44E+00
Mo JaFS-L11-1314-T07-C 1 8.19E+00
Mo JaFS-L11-1314-T08-C 1 6.14E+00
Mo JaFS-L11-1314-T09-C 1 5.28E+00
Mo JaFS-L11-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.53E+02 0.65 1.20 3.82
4.23E+01 2.46 1.20 3.82
1.90E+01 6.32 1.20 3.82 10000 1000
1.19E+01 4.57 1.20 3.82
1.28E+01 8.01 1.20 3.82
1.01E+01 8.00 1.20 3.82
8.34E+00 2.74 1.20 3.82
5.49E+00 4.53 1.20 3.82
5.01 E+00 11.41 1.20 3.82
1.38E+02 0.86 1.20 3.82
4.04E+01 0.93 1.20 3.82
1.74E+01 6.82 1.20 3.82 10000 1000
1.36E+01 6.23 1.20 3.82
9.17E+00 10.05 1.20 3.82
9.27E+00 1.44 1.20 3.82
6.53E+00 1.14 1.20 3.82
4.21 E+00 3.86 1.20 3.82
6.00E+00 9.01 1.20 3.82
1.31E+02 2.73 1.20 3.82
3.79E+01 1.73 1.20 3.82
1.82E+01 4.84 1.20 3.82 10000 1000
1.14E+01 7.90 1.20 3.82
1.45E+01 7.42 1.20 3.82
6.44E+00 4.41 1.20 3.82
8.19E+00 0.70 1.20 3.82
6.14E+00 0.68 1.20 3.82
5.28E+00 4.49 1.20 3.82
6.00E-01 17.31 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.62E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/121:38PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L1 1 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-368
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ni JaFS-L11-1314-T01-A 1 9.98E+00
Ni JaFS-L11-1314-T02-A 1 4.81E+00 E
Ni JaFS-L11-1314-T03-A 1 2.56E+00 E
Ni JaFS-L11-1314-T04-A 1 9.00E-01 U1/2
Ni JaFS-L11-1314-T05-A 1 9.00E-01 U1/2
Ni JaFS-L11-1314-T06-A 1 9.00E-01 U1/2
Ni JaFS-L11-1314-T07-A 1 9.00E-01 U1/2
Ni JaFS-L11-1314-T08-A 1 9.00E-01 U1/2
Ni JaFS-L11-1314-T09-A 1 9.00E-01 U1/2
Ni JaFS-L11-1314-T01-B 1 9.64E+00
Ni JaFS-L11-1314-T02-B 1 5.54E+00 E
Ni JaFS-L11-1314-T03-B 1 2.62E+00 E
Ni JaFS-L11-1314-T04-B 1 9.00E-01 U1/2
Ni JaFS-L11-1314-T05-B 1 9.00E-01 U1/2
Ni JaFS-L11-1314-T06-B 1 9.00E-01 U1/2
Ni JaFS-L11-1314-T07-B 1 9.00E-01 U1/2
Ni JaFS-L11-1314-T08-B 1 9.00E-01 U1/2
Ni JaFS-L11-1314-T09-B 1 9.00E-01 U1/2
Ni JaFS-L11-1314-T01-C 1 1.10E+01
Ni JaFS-L11-1314-T02-C 1 5.10E+00 E
Ni JaFS-L11-1314-T03-C 1 2.59E+00 E
Ni JaFS-L11-1314-T04-C 1 9.00E-01 U1/2
Ni JaFS-L11-1314-T05-C 1 9.00E-01 U1/2
Ni JaFS-L11-1314-T06-C 1 9.00E-01 U1/2
Ni JaFS-L11-1314-T07-C 1 9.00E-01 U1/2
Ni JaFS-L11-1314-T08-C 1 9.00E-01 U1/2
Ni JaFS-L11-1314-T09-C 1 9.00E-01 U1/2
Ni JaFS-L11-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.98E+00 1.90 1.80 5.70
4.81E+00 18.93 1.80 5.70
2.56E+00 7.91 1.80 5.70 10000 1000
9.00E-01 2.99 1.80 5.70
9.00E-01 6.78 1.80 5.70
9.00E-01 25.14 1.80 5.70
9.00E-01 12.35 1.80 5.70
9.00E-01 12.09 1.80 5.70
9.00E-01 19.45 1.80 5.70
9.64E+00 2.34 1.80 5.70
5.54E+00 4.29 1.80 5.70
2.62E+00 23.03 1.80 5.70 10000 1000
9.00E-01 32.35 1.80 5.70
9.00E-01 9.03 1.80 5.70
9.00E-01 9.24 1.80 5.70
9.00E-01 18.30 1.80 5.70
9.00E-01 26.70 1.80 5.70
9.00E-01 7.70 1.80 5.70
1.10E+01 1.02 1.80 5.70
5.10E+00 13.16 1.80 5.70
2.59E+00 11.88 1.80 5.70 10000 1000
9.00E-01 23.85 1.80 5.70
9.00E-01 16.77 1.80 5.70
9.00E-01 5.98 1.80 5.70
9.00E-01 12.42 1.80 5.70
9.00E-01 10.91 1.80 5.70
9.00E-01 5.40 1.80 5.70
9.00E-01 27.12 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.04E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/12 1:38 PM EPA Interlab L11 1314 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L1 1 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-369
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
P JaFS-L11-1314-T01-A 1 8.63E+01
P JaFS-L11-1314-T02-A 1 3.60E+01
P JaFS-L11-1314-T03-A 1 3.36E+01
P JaFS-L11-1314-T04-A 1 3.02E+01
P JaFS-L11-1314-T05-A 1 2.48E+01
P JaFS-L11-1314-T06-A 1 2.01E+01
P JaFS-L11-1314-T07-A 1 2.80E+01
P JaFS-L11-1314-T08-A 1 3.06E+01
P JaFS-L11-1314-T09-A 1 2.58E+01
P JaFS-L11-1314-T01-B 1 7.64E+01
P JaFS-L11-1314-T02-B 1 4.11E+01
P JaFS-L11-1314-T03-B 1 3.83E+01
P JaFS-L11-1314-T04-B 1 2.54E+01
P JaFS-L11-1314-T05-B 1 2.13E+01
P JaFS-L11-1314-T06-B 1 1.95E+01
P JaFS-L11-1314-T07-B 1 2.48E+01
P JaFS-L11-1314-T08-B 1 2.77E+01
P JaFS-L11-1314-T09-B 1 2.38E+01
P JaFS-L11-1314-T01-C 1 7.43E+01
P JaFS-L11-1314-T02-C 1 3.60E+01
P JaFS-L11-1314-T03-C 1 3.42E+01
P JaFS-L11-1314-T04-C 1 2.94E+01
P JaFS-L11-1314-T05-C 1 2.39E+01
P JaFS-L11-1314-T06-C 1 2.09E+01
P JaFS-L11-1314-T07-C 1 2.15E+01
P JaFS-L11-1314-T08-C 1 2.59E+01
P JaFS-L11-1314-T09-C 1 2.89E+01
P JaFS-L11-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.63E+01 2.74 3.70 11.80
3.60E+01 8.64 3.70 11.80
3.36E+01 1.23 3.70 11.80 10000 1000
3.02E+01 1.57 3.70 11.80
2.48E+01 1.07 3.70 11.80
2.01 E+01 1.95 3.70 11.80
2.80E+01 2.80 3.70 11.80
3.06E+01 17.10 3.70 11.80
2.58E+01 8.95 3.70 11.80
7.64E+01 1.25 3.70 11.80
4. 11 E+01 2.30 3.70 11.80
3.83E+01 11.65 3.70 11.80 10000 1000
2.54E+01 1.11 3.70 11.80
2.13E+01 9.76 3.70 11.80
1.95E+01 9.33 3.70 11.80
2.48E+01 9.30 3.70 11.80
2.77E+01 1.51 3.70 11.80
2.38E+01 4.25 3.70 11.80
7.43E+01 2.00 3.70 11.80
3.60E+01 1.42 3.70 11.80
3.42E+01 1.46 3.70 11.80 10000 1000
2.94E+01 3.19 3.70 11.80
2.39E+01 1.07 3.70 11.80
2.09E+01 1.23 3.70 11.80
2.15E+01 1.21 3.70 11.80
2.59E+01 1.23 3.70 11.80
2.89E+01 1.16 3.70 11.80
1.85E+00 25.11 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/121:38PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L1 1 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-370
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
K JaFS-L11-1314-T01-A 1 5.07E+04
K JaFS-L11-1314-T02-A 1 2.37E+04
K JaFS-L11-1314-T03-A 1 1.36E+04
K JaFS-L11-1314-T04-A 1 8.94E+03
K JaFS-L11-1314-T05-A 1 7.62E+03
K JaFS-L11-1314-T06-A 1 6.33E+03
K JaFS-L11-1314-T07-A 1 5.12E+03
K JaFS-L11-1314-T08-A 1 3.47E+03
K JaFS-L11-1314-T09-A 1 2.61E+03
K JaFS-L11-1314-T01-B 1 5.60E+04
K JaFS-L11-1314-T02-B 1 2.66E+04
K JaFS-L11-1314-T03-B 1 1.38E+04
K JaFS-L11-1314-T04-B 1 8.52E+03
K JaFS-L11-1314-T05-B 1 7.12E+03
K JaFS-L11-1314-T06-B 1 6.52E+03
K JaFS-L11-1314-T07-B 1 5.16E+03
K JaFS-L11-1314-T08-B 1 3.69E+03
K JaFS-L11-1314-T09-B 1 2.45E+03
K JaFS-L11-1314-T01-C 1 5.38E+04
K JaFS-L11-1314-T02-C 1 2.50E+04
K JaFS-L11-1314-T03-C 1 1.39E+04
K JaFS-L11-1314-T04-C 1 8.80E+03
K JaFS-L11-1314-T05-C 1 7.46E+03
K JaFS-L11-1314-T06-C 1 6.20E+03
K JaFS-L11-1314-T07-C 1 4.98E+03
K JaFS-L11-1314-T08-C 1 3.34E+03
K JaFS-L11-1314-T09-C 1 2.55E+03
K JaFS-L11-1314-B01-A 1 5.16E+00
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.07E+04 0.67 1.60 5.09
2.37E+04 1.11 1.60 5.09
1.36E+04 0.51 1.60 5.09 10000 1000
8.94E+03 0.33 1.60 5.09
7.62E+03 0.14 1.60 5.09
6.33E+03 0.61 1.60 5.09
5.12E+03 0.50 1.60 5.09
3.47E+03 0.33 1.60 5.09
2.61 E+03 1.22 1.60 5.09
5.60E+04 0.68 1.60 5.09
2.66E+04 0.92 1.60 5.09
1.38E+04 1.06 1.60 5.09 10000 1000
8.52E+03 0.55 1.60 5.09
7.12E+03 0.91 1.60 5.09
6.52E+03 0.06 1.60 5.09
5.16E+03 0.37 1.60 5.09
3.69E+03 0.84 1.60 5.09
2.45E+03 0.34 1.60 5.09
5.38E+04 0.62 1.60 5.09
2.50E+04 0.52 1.60 5.09
1.39E+04 0.12 1.60 5.09 10000 1000
8.80E+03 0.34 1.60 5.09
7.46E+03 0.36 1.60 5.09
6.20E+03 0.55 1.60 5.09
4.98E+03 0.21 1.60 5.09
3.34E+03 0.89 1.60 5.09
2.55E+03 1.04 1.60 5.09
5.16E+00 2.20 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.45E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.46E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.48E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/121:38PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L1 1 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-371
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Se JaFS-L11-1314-T01-A 1 5.71E+01
Se JaFS-L11-1314-T02-A 1 2.45E+01 E
Se JaFS-L11-1314-T03-A 1 7.50E+00 U1/2
Se JaFS-L11-1314-T04-A 1 7.50E+00 U1/2
Se JaFS-L11-1314-T05-A 1 7.50E+00 U1/2
Se JaFS-L11-1314-T06-A 1 7.50E+00 U1/2
Se JaFS-L11-1314-T07-A 1 7.50E+00 U1/2
Se JaFS-L11-1314-T08-A 1 7.50E+00 U1/2
Se JaFS-L11-1314-T09-A 1 7.50E+00 U1/2
Se JaFS-L11-1314-T01-B 1 5.66E+01
Se JaFS-L11-1314-T02-B 1 2.53E+01 E
Se JaFS-L11-1314-T03-B 1 7.50E+00 U1/2
Se JaFS-L11-1314-T04-B 1 7.50E+00 U1/2
Se JaFS-L11-1314-T05-B 1 7.50E+00 U1/2
Se JaFS-L11-1314-T06-B 1 7.50E+00 U1/2
Se JaFS-L11-1314-T07-B 1 7.50E+00 U1/2
Se JaFS-L11-1314-T08-B 1 7.50E+00 U1/2
Se JaFS-L11-1314-T09-B 1 7.50E+00 U1/2
Se JaFS-L11-1314-T01-C 1 6.06E+01
Se JaFS-L11-1314-T02-C 1 2.25E+01 E
Se JaFS-L11-1314-T03-C 1 7.50E+00 U1/2
Se JaFS-L11-1314-T04-C 1 7.50E+00 U1/2
Se JaFS-L11-1314-T05-C 1 7.50E+00 U1/2
Se JaFS-L11-1314-T06-C 1 7.50E+00 U1/2
Se JaFS-L11-1314-T07-C 1 7.50E+00 U1/2
Se JaFS-L11-1314-T08-C 1 7.50E+00 U1/2
Se JaFS-L11-1314-T09-C 1 7.50E+00 U1/2
Se JaFS-L11-1314-B01-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.71E+01 1.14 15.00 47.70
2.45E+01 3.31 15.00 47.70
7.50E+00 13.64 15.00 47.70 10000 1000
7.50E+00 6.99 15.00 47.70
7.50E+00 19.03 15.00 47.70
7.50E+00 5.17 15.00 47.70
7.50E+00 17.52 15.00 47.70
7.50E+00 10.11 15.00 47.70
7.50E+00 12.35 15.00 47.70
5.66E+01 8.04 15.00 47.70
2.53E+01 10.35 15.00 47.70
7.50E+00 4.11 15.00 47.70 10000 1000
7.50E+00 5.83 15.00 47.70
7.50E+00 5.32 15.00 47.70
7.50E+00 9.90 15.00 47.70
7.50E+00 16.72 15.00 47.70
7.50E+00 25.23 15.00 47.70
7.50E+00 6.26 15.00 47.70
6.06E+01 1.96 15.00 47.70
2.25E+01 13.92 15.00 47.70
7.50E+00 6.06 15.00 47.70 10000 1000
7.50E+00 6.16 15.00 47.70
7.50E+00 6.82 15.00 47.70
7.50E+00 20.61 15.00 47.70
7.50E+00 13.43 15.00 47.70
7.50E+00 6.17 15.00 47.70
7.50E+00 12.51 15.00 47.70
7.50E+00 28.15 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.55E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.70E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/121:38PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L1 1 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-372
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Si JaFS-L11-1314-T01-A 1 4.93E+03
Si JaFS-L11-1314-T02-A 1 3.30E+03
Si JaFS-L11-1314-T03-A 1 2.78E+03
Si JaFS-L11-1314-T04-A 1 2.35E+03
Si JaFS-L11-1314-T05-A 1 2.04E+03
Si JaFS-L11-1314-T06-A 1 1.80E+03
Si JaFS-L11-1314-T07-A 1 1.74E+03
Si JaFS-L11-1314-T08-A 1 1.69E+03
Si JaFS-L11-1314-T09-A 1 1.87E+03
Si JaFS-L11-1314-T01-B 1 4.60E+03
Si JaFS-L11-1314-T02-B 1 3.24E+03
Si JaFS-L11-1314-T03-B 1 2.90E+03
Si JaFS-L11-1314-T04-B 1 2.36E+03
Si JaFS-L11-1314-T05-B 1 1.94E+03
Si JaFS-L11-1314-T06-B 1 1.85E+03
Si JaFS-L11-1314-T07-B 1 1.71E+03
Si JaFS-L11-1314-T08-B 1 1.62E+03
Si JaFS-L11-1314-T09-B 1 1.87E+03
Si JaFS-L11-1314-T01-C 1 4.85E+03
Si JaFS-L11-1314-T02-C 1 3.34E+03
Si JaFS-L11-1314-T03-C 1 2.77E+03
Si JaFS-L11-1314-T04-C 1 2.43E+03
Si JaFS-L11-1314-T05-C 1 2.04E+03
Si JaFS-L11-1314-T06-C 1 1.86E+03
Si JaFS-L11-1314-T07-C 1 1.74E+03
Si JaFS-L11-1314-T08-C 1 1.60E+03
Si JaFS-L11-1314-T09-C 1 1.80E+03
Si JaFS-L11-1314-B01-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.93E+03 0.48 1.10 3.50
3.30E+03 1.76 1.10 3.50
2.78E+03 0.46 1.10 3.50 10000 1000
2.35E+03 1.21 1.10 3.50
2.04E+03 0.75 1.10 3.50
1.80E+03 1.01 1.10 3.50
1.74E+03 0.32 1.10 3.50
1.69E+03 1.11 1.10 3.50
1.87E+03 1.86 1.10 3.50
4.60E+03 0.64 1.10 3.50
3.24E+03 0.50 1.10 3.50
2.90E+03 0.69 1.10 3.50 10000 1000
2.36E+03 1.12 1.10 3.50
1.94E+03 0.73 1.10 3.50
1.85E+03 0.28 1.10 3.50
1.71E+03 0.19 1.10 3.50
1.62E+03 1.12 1.10 3.50
1.87E+03 0.24 1.10 3.50
4.85E+03 0.83 1.10 3.50
3.34E+03 0.29 1.10 3.50
2.77E+03 0.16 1.10 3.50 10000 1000
2.43E+03 0.18 1.10 3.50
2.04E+03 0.54 1.10 3.50
1.86E+03 0.37 1.10 3.50
1.74E+03 1.28 1.10 3.50
1.60E+03 0.56 1.10 3.50
1.80E+03 0.31 1.10 3.50
5.50E-01 2.47 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.70E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.86E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.69E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/121:38PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L1 1 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-373
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Na JaFS-L11-1314-T01-A 1 2.33E+05
Na JaFS-L11-1314-T02-A 1 8.10E+04
Na JaFS-L11-1314-T03-A 1 4.01E+04
Na JaFS-L11-1314-T04-A 1 1.64E+04
Na JaFS-L11-1314-T05-A 1 9.06E+03
Na JaFS-L11-1314-T06-A 1 1.49E+03
Na JaFS-L11-1314-T07-A 1 1.20E+03
Na JaFS-L11-1314-T08-A 1 6.37E+02
Na JaFS-L11-1314-T09-A 1 4.24E+02
Na JaFS-L11-1314-T01-B 1 2.44E+05
Na JaFS-L11-1314-T02-B 1 8.21E+04
Na JaFS-L11-1314-T03-B 1 4.35E+04
Na JaFS-L11-1314-T04-B 1 1.72E+04
Na JaFS-L11-1314-T05-B 1 8.72E+03
Na JaFS-L11-1314-T06-B 1 1.43E+03
Na JaFS-L11-1314-T07-B 1 1.24E+03
Na JaFS-L11-1314-T08-B 1 6.83E+02
Na JaFS-L11-1314-T09-B 1 4.41E+02
Na JaFS-L11-1314-T01-C 1 2.44E+05
Na JaFS-L11-1314-T02-C 1 8.02E+04
Na JaFS-L11-1314-T03-C 1 4.36E+04
Na JaFS-L11-1314-T04-C 1 1.64E+04
Na JaFS-L11-1314-T05-C 1 9.71E+03
Na JaFS-L11-1314-T06-C 1 1.33E+03
Na JaFS-L11-1314-T07-C 1 1.13E+03
Na JaFS-L11-1314-T08-C 1 6.38E+02
Na JaFS-L11-1314-T09-C 1 4.59E+02
Na JaFS-L11-1314-B01-A 1 1.22E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.33E+05 0.49 2.50 8.00
8.10E+04 1.23 2.50 8.00
4.01E+04 0.85 2.50 8.00 10000 1000
1.64E+04 0.24 2.50 8.00
9.06E+03 0.78 2.50 8.00
1.49E+03 0.54 2.50 8.00
1.20E+03 0.75 2.50 8.00
6.37E+02 0.15 2.50 8.00
4.24E+02 0.74 2.50 8.00
2.44E+05 1.00 2.50 8.00
8.21 E+04 0.85 2.50 8.00
4.35E+04 0.41 2.50 8.00 10000 1000
1.72E+04 0.44 2.50 8.00
8.72E+03 0.80 2.50 8.00
1.43E+03 0.28 2.50 8.00
1.24E+03 1.61 2.50 8.00
6.83E+02 0.39 2.50 8.00
4.41 E+02 1.05 2.50 8.00
2.44E+05 1.04 2.50 8.00
8.02E+04 0.10 2.50 8.00
4.36E+04 0.81 2.50 8.00 10000 1000
1.64E+04 0.23 2.50 8.00
9.71 E+03 1.26 2.50 8.00
1.33E+03 0.46 2.50 8.00
1.13E+03 0.30 2.50 8.00
6.38E+02 0.84 2.50 8.00
459E+02 1.55 2.50 8.00
1.22E+01 1.75 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.10E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.44E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.46E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/12 1:38 PM EPA Interlab L11 1314 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:43 PM EPA Interlab L11 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L11 1314 JaFS
3/6/12 12:57 PM EPA Interlab L1 1 1314 JaFS
1-374
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Sr JaFS-L11-1314-T01-A 1 8.97E+03
Sr JaFS-L11-1314-T02-A 1 1.41E+03
Sr JaFS-L11-1314-T03-A 1 5.63E+02
Sr JaFS-L11-1314-T04-A 1 4.11E+02
Sr JaFS-L11-1314-T05-A 1 4.07E+02
Sr JaFS-L11-1314-T06-A 1 3.48E+02
Sr JaFS-L11-1314-T07-A 1 3.08E+02
Sr JaFS-L11-1314-T08-A 1 2.79E+02
Sr JaFS-L11-1314-T09-A 1 2.40E+02
Sr JaFS-L11-1314-T01-B 1 8.89E+03
Sr JaFS-L11-1314-T02-B 1 1.43E+03
Sr JaFS-L11-1314-T03-B 1 5.40E+02
Sr JaFS-L11-1314-T04-B 1 4.08E+02
Sr JaFS-L11-1314-T05-B 1 4.05E+02
Sr JaFS-L11-1314-T06-B 1 3.59E+02
Sr JaFS-L11-1314-T07-B 1 3.09E+02
Sr JaFS-L11-1314-T08-B 1 2.84E+02
Sr JaFS-L11-1314-T09-B 1 2.32E+02
Sr JaFS-L11-1314-T01-C 1 8.93E+03
Sr JaFS-L11-1314-T02-C 1 1.42E+03
Sr JaFS-L11-1314-T03-C 1 5.23E+02
Sr JaFS-L11-1314-T04-C 1 4.16E+02
Sr JaFS-L11-1314-T05-C 1 4.10E+02
Sr JaFS-L11-1314-T06-C 1 3.43E+02
Sr JaFS-L11-1314-T07-C 1 2.94E+02
Sr JaFS-L11-1314-T08-C 1 2.81E+02
Sr JaFS-L11-1314-T09-C 1 2.43E+02
Sr JaFS-L11-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.97E+03 0.69 1.00 3.18
1.41E+03 1.24 1.00 3.18
5.63E+02 0.18 1.00 3.18 10000 1000
4.11E+02 1.31 1.00 3.18
4.07E+02 0.26 1.00 3.18
3.48E+02 0.45 1.00 3.18
3.08E+02 0.69 1.00 3.18
2.79E+02 0.31 1.00 3.18
2.40E+02 0.90 1.00 3.18
8.89E+03 1.13 1.00 3.18
1.43E+03 0.96 1.00 3.18
5.40E+02 0.75 1.00 3.18 10000 1000
4.08E+02 0.80 1.00 3.18
4.05E+02 1.39 1.00 3.18
3.59E+02 0.28 1.00 3.18
3.09E+02 0.76 1.00 3.18
2.84E+02 1.31 1.00 3.18
2.32E+02 0.88 1.00 3.18
8.93E+03 0.80 1.00 3.18
1.42E+03 1.05 1.00 3.18
5.23E+02 0.63 1.00 3.18 10000 1000
4.16E+02 1.65 1.00 3.18
4.10E+02 1.11 1.00 3.18
3.43E+02 0.60 1.00 3.18
2.94E+02 0.48 1.00 3.18
2.81E+02 0.61 1.00 3.18
2.43E+02 1.07 1.00 3.18
5.00E-01 2.70 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.50E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.45E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.49E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/121:38PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L1 1 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-375
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
S JaFS-L11-1314-T01-A 1 5.74E+05
S JaFS-L11-1314-T02-A 1 4.36E+04
S JaFS-L11-1314-T03-A 1 1.07E+04
S JaFS-L11-1314-T04-A 1 7.48E+03
S JaFS-L11-1314-T05-A 1 5.75E+03
S JaFS-L11-1314-T06-A 1 3.27E+03
S JaFS-L11-1314-T07-A 1 2.63E+03
S JaFS-L11-1314-T08-A 1 2.05E+03
S JaFS-L11-1314-T09-A 1 1.89E+03
S JaFS-L11-1314-T01-B 1 5.63E+05
S JaFS-L11-1314-T02-B 1 4.49E+04
S JaFS-L11-1314-T03-B 1 1.09E+04
S JaFS-L11-1314-T04-B 1 6.88E+03
S JaFS-L11-1314-T05-B 1 5.49E+03
S JaFS-L11-1314-T06-B 1 3.29E+03
S JaFS-L11-1314-T07-B 1 2.74E+03
S JaFS-L11-1314-T08-B 1 1.95E+03
S JaFS-L11-1314-T09-B 1 2.07E+03
S JaFS-L11-1314-T01-C 1 5.61E+05
S JaFS-L11-1314-T02-C 1 4.35E+04
S JaFS-L11-1314-T03-C 1 1.17E+04
S JaFS-L11-1314-T04-C 1 6.89E+03
S JaFS-L11-1314-T05-C 1 5.64E+03
S JaFS-L11-1314-T06-C 1 3.48E+03
S JaFS-L11-1314-T07-C 1 2.70E+03
S JaFS-L11-1314-T08-C 1 2.02E+03
S JaFS-L11-1314-T09-C 1 2.00E+03
S JaFS-L11-1314-B01-A 1 2.25E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.74E+05 1.68 6.80 21.60
4.36E+04 1.32 6.80 21.60
1.07E+04 0.80 6.80 21.60 10000 1000
7.48E+03 1.14 6.80 21.60
5.75E+03 0.72 6.80 21.60
3.27E+03 0.65 6.80 21.60
2.63E+03 1.14 6.80 21.60
2.05E+03 0.59 6.80 21.60
1.89E+03 0.87 6.80 21.60
5.63E+05 2.30 6.80 21.60
4.49E+04 1.61 6.80 21.60
1.09E+04 0.63 6.80 21.60 10000 1000
6.88E+03 0.35 6.80 21.60
5.49E+03 0.82 6.80 21.60
3.29E+03 1.37 6.80 21.60
2.74E+03 1.00 6.80 21.60
1.95E+03 1.94 6.80 21.60
2.07E+03 0.95 6.80 21.60
5.61 E+05 0.90 6.80 21.60
4.35E+04 1.62 6.80 21.60
1.17E+04 1.30 6.80 21.60 10000 1000
6.89E+03 0.38 6.80 21.60
5.64E+03 0.44 6.80 21.60
3.48E+03 0.46 6.80 21.60
2.70E+03 0.74 6.80 21.60
2.02E+03 0.49 6.80 21.60
2.00E+03 0.74 6.80 21.60
2.25E+01 1.20 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.16E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.26E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/121:38PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L1 1 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-376
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Tl JaFS-L11-1314-T01-A 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T02-A 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T03-A 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T04-A 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T05-A 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T06-A 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T07-A 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T08-A 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T09-A 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T01-B 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T02-B 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T03-B 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T04-B 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T05-B 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T06-B 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T07-B 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T08-B 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T09-B 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T01-C 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T02-C 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T03-C 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T04-C 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T05-C 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T06-C 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T07-C 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T08-C 1 2.30E+00 U1/2
Tl JaFS-L11-1314-T09-C 1 2.30E+00 U1/2
Tl JaFS-L11-1314-B01-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 16.35 4.60 14.60
2.30E+00 10.02 4.60 14.60
2.30E+00 5.72 4.60 14.60 10000 1000
2.30E+00 12.14 4.60 14.60
2.30E+00 9.07 4.60 14.60
2.30E+00 9.85 4.60 14.60
2.30E+00 9.74 4.60 14.60
2.30E+00 24.42 4.60 14.60
2.30E+00 4.56 4.60 14.60
2.30E+00 17.85 4.60 14.60
2.30E+00 4.88 4.60 14.60
2.30E+00 8.13 4.60 14.60 10000 1000
2.30E+00 7.60 4.60 14.60
2.30E+00 18.77 4.60 14.60
2.30E+00 7.80 4.60 14.60
2.30E+00 14.64 4.60 14.60
2.30E+00 5.51 4.60 14.60
2.30E+00 6.80 4.60 14.60
2.30E+00 12.35 4.60 14.60
2.30E+00 14.16 4.60 14.60
2.30E+00 25.00 4.60 14.60 10000 1000
2.30E+00 7.43 4.60 14.60
2.30E+00 6.01 4.60 14.60
2.30E+00 4.74 4.60 14.60
2.30E+00 11.00 4.60 14.60
2.30E+00 15.12 4.60 14.60
2.30E+00 2.62 4.60 14.60
2.30E+00 28.50 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.66E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.96E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.60E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/121:38PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L1 1 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-377
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Ti JaFS-L11-1314-T01-A 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T02-A 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T03-A 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T04-A 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T05-A 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T06-A 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T07-A 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T08-A 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T09-A 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T01-B 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T02-B 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T03-B 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T04-B 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T05-B 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T06-B 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T07-B 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T08-B 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T09-B 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T01-C 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T02-C 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T03-C 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T04-C 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T05-C 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T06-C 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T07-C 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T08-C 1 1.00E+00 U1/2
Ti JaFS-L11-1314-T09-C 1 1.00E+00 U1/2
Ti JaFS-L11-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 30.67 2.00 6.40
1.00E+00 21.79 2.00 6.40
1.00E+00 29.02 2.00 6.40 10000 1000
1.00E+00 46.28 2.00 6.40
1.00E+00 41.96 2.00 6.40
1.00E+00 16.26 2.00 6.40
1.00E+00 71.07 2.00 6.40
1.00E+00 30.01 2.00 6.40
1.00E+00 58.78 2.00 6.40
1.00E+00 28.87 2.00 6.40
1.00E+00 51.70 2.00 6.40
1.00E+00 22.84 2.00 6.40 10000 1000
1.00E+00 43.40 2.00 6.40
1.00E+00 10.59 2.00 6.40
1.00E+00 45.09 2.00 6.40
1.00E+00 52.30 2.00 6.40
1.00E+00 27.97 2.00 6.40
1.00E+00 40.24 2.00 6.40
1.00E+00 66.60 2.00 6.40
1.00E+00 16.13 2.00 6.40
1.00E+00 39.43 2.00 6.40 10000 1000
1.00E+00 58.75 2.00 6.40
1.00E+00 24.62 2.00 6.40
1.00E+00 27.82 2.00 6.40
1.00E+00 93.65 2.00 6.40
1.00E+00 80.78 2.00 6.40
1.00E+00 8.07 2.00 6.40
1.00E+00 55.40 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.50E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/121:38PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L1 1 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-378
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
V JaFS-L11-1314-T01-A 1 1.83E+01
V JaFS-L11-1314-T02-A 1 6.13E+00
V JaFS-L11-1314-T03-A 1 1.96E+00 E
V JaFS-L11-1314-T04-A 1 7.50E-01 U1/2
V JaFS-L11-1314-T05-A 1 7.50E-01 U1/2
V JaFS-L11-1314-T06-A 1 7.50E-01 U1/2
V JaFS-L11-1314-T07-A 1 7.50E-01 U1/2
V JaFS-L11-1314-T08-A 1 7.50E-01 U1/2
V JaFS-L11-1314-T09-A 1 7.50E-01 U1/2
V JaFS-L11-1314-T01-B 1 1.67E+01
V JaFS-L11-1314-T02-B 1 6.26E+00
V JaFS-L11-1314-T03-B 1 1.94E+00 E
V JaFS-L11-1314-T04-B 1 7.50E-01 U1/2
V JaFS-L11-1314-T05-B 1 7.50E-01 U1/2
V JaFS-L11-1314-T06-B 1 7.50E-01 U1/2
V JaFS-L11-1314-T07-B 1 7.50E-01 U1/2
V JaFS-L11-1314-T08-B 1 7.50E-01 U1/2
V JaFS-L11-1314-T09-B 1 7.50E-01 U1/2
V JaFS-L11-1314-T01-C 1 1.69E+01
V JaFS-L11-1314-T02-C 1 6.08E+00
V JaFS-L11-1314-T03-C 1 2.21E+00 E
V JaFS-L11-1314-T04-C 1 7.50E-01 U1/2
V JaFS-L11-1314-T05-C 1 7.50E-01 U1/2
V JaFS-L11-1314-T06-C 1 7.50E-01 U1/2
V JaFS-L11-1314-T07-C 1 7.50E-01 U1/2
V JaFS-L11-1314-T08-C 1 7.50E-01 U1/2
V JaFS-L11-1314-T09-C 1 7.50E-01 U1/2
V JaFS-L11-1314-B01-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.83E+01 0.23 1.50 4.77
6.13E+00 2.27 1.50 4.77
1.96E+00 12.99 1.50 4.77 10000 1000
7.50E-01 14.59 1.50 4.77
7.50E-01 28.53 1.50 4.77
7.50E-01 27.76 1.50 4.77
7.50E-01 7.22 1.50 4.77
7.50E-01 20.76 1.50 4.77
7.50E-01 14.39 1.50 4.77
1.67E+01 2.23 1.50 4.77
6.26E+00 14.38 1.50 4.77
1.94E+00 16.08 1.50 4.77 10000 1000
7.50E-01 9.54 1.50 4.77
7.50E-01 14.52 1.50 4.77
7.50E-01 15.39 1.50 4.77
7.50E-01 15.19 1.50 4.77
7.50E-01 22.23 1.50 4.77
7.50E-01 11.44 1.50 4.77
1.69E+01 1.98 1.50 4.77
6.08E+00 1.66 1.50 4.77
2.21E+00 2.74 1.50 4.77 10000 1000
7.50E-01 15.73 1.50 4.77
7.50E-01 11.74 1.50 4.77
7.50E-01 15.68 1.50 4.77
7.50E-01 25.46 1.50 4.77
7.50E-01 21.57 1.50 4.77
7.50E-01 3.88 1.50 4.77
7.50E-01 37.53 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.24E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.64E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/121:38PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L1 1 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-379
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Zn JaFS-L11-1314-T01-A 1 1.73E+03
Zn JaFS-L11-1314-T02-A 1 4.83E+02
Zn JaFS-L11-1314-T03-A 1 2.33E+02
Zn JaFS-L11-1314-T04-A 1 9.83E+01
Zn JaFS-L11-1314-T05-A 1 7.38E+01
Zn JaFS-L11-1314-T06-A 1 4.55E+01
Zn JaFS-L11-1314-T07-A 1 4.18E+01
Zn JaFS-L11-1314-T08-A 1 2.28E+01
Zn JaFS-L11-1314-T09-A 1 1.69E+01
Zn JaFS-L11-1314-T01-B 1 1.62E+03
Zn JaFS-L11-1314-T02-B 1 4.77E+02
Zn JaFS-L11-1314-T03-B 1 2.59E+02
Zn JaFS-L11-1314-T04-B 1 9.78E+01
Zn JaFS-L11-1314-T05-B 1 7.44E+01
Zn JaFS-L11-1314-T06-B 1 5.33E+01
Zn JaFS-L11-1314-T07-B 1 4.61E+01
Zn JaFS-L11-1314-T08-B 1 2.77E+01
Zn JaFS-L11-1314-T09-B 1 2.31E+01
Zn JaFS-L11-1314-T01-C 1 1.37E+03
Zn JaFS-L11-1314-T02-C 1 4.74E+02
Zn JaFS-L11-1314-T03-C 1 2.33E+02
Zn JaFS-L11-1314-T04-C 1 9.35E+01
Zn JaFS-L11-1314-T05-C 1 7.31E+01
Zn JaFS-L11-1314-T06-C 1 5.49E+01
Zn JaFS-L11-1314-T07-C 1 3.62E+01
Zn JaFS-L11-1314-T08-C 1 2.84E+01
Zn JaFS-L11-1314-T09-C 1 2.32E+01
Zn JaFS-L11-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.73E+03 0.61 1.00 3.18
4.83E+02 0.58 1.00 3.18
2.33E+02 4.88 1.00 3.18 10000 1000
9.83E+01 0.57 1.00 3.18
7.38E+01 0.67 1.00 3.18
4.55E+01 0.91 1.00 3.18
4.18E+01 2.11 1.00 3.18
2.28E+01 0.93 1.00 3.18
1.69E+01 0.62 1.00 3.18
1.62E+03 0.58 1.00 3.18
4.77E+02 0.57 1.00 3.18
2.59E+02 6.58 1.00 3.18 10000 1000
9.78E+01 1.17 1.00 3.18
7.44E+01 1.11 1.00 3.18
5.33E+01 1.62 1.00 3.18
4.61E+01 1.13 1.00 3.18
2.77E+01 3.76 1.00 3.18
2.31E+01 0.95 1.00 3.18
1.37E+03 1.94 1.00 3.18
4.74E+02 0.28 1.00 3.18
2.33E+02 3.29 1.00 3.18 10000 1000
9.35E+01 0.88 1.00 3.18
7.31E+01 0.59 1.00 3.18
5.49E+01 1.38 1.00 3.18
3.62E+01 1.23 1.00 3.18
2.84E+01 0.69 1.00 3.18
2.32E+01 2.92 1.00 3.18
5.00E-01 4.40 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.24E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.25E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.23E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/6/12 12:59 PM EPA Interlab L11 1314 JaFS
3/6/12 1:00 PM EPA Interlab L11 1314 JaFS
3/6/12 1:02 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:03 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:05 PM EPA Interlab L11 1314 JaFS
3/6/12 1:07 PM EPA Interlab L11 1314 JaFS
3/6/12 1:08 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:10 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:12 PM EPA Interlab L11 1314 JaFS
3/6/12 1:20 PM EPA Interlab L11 1314 JaFS
3/6/12 1:22 PM EPA Interlab L11 1314 JaFS
3/6/12 1:24 PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:25 PM EPA Interlab L11 1314 JaFS
3/6/12 1:27 PM EPA Interlab L11 1314 JaFS
3/6/12 1:28 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:30 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:32 PM EPA Interlab L11 1314 JaFS
3/6/12 1:33 PM EPA Interlab L11 1314 JaFS
3/6/12 1:35 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:37 PM EPA Interlab L11 1314 JaFS
3/6/121:38PM EPA Interlab L1 1 131 4 JaFS
3/6/12 1:40 PM EPA Interlab L11 1314 JaFS
3/6/12 1:42 PM EPA Interlab L11 1314 JaFS
3/6/12 1:43 PM EPA Interlab L1 1 1314 JaFS
3/6/12 1:45 PM EPA Interlab L11 1314 JaFS
3/6/12 1:47 PM EPA Interlab L11 1314 JaFS
3/6/12 1:48 PM EPA Interlab L1 1 1314 JaFS
3/6/12 12:57 PM EPA Interlab L11 1314 JaFS
1-380
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1314:
Element
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Dilution Sample
Sample ID Factor Cone.
ug/L
ICP-OES Spike Sol'n
Qualifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L Mi-
JaFS-L14-1314-T01-A 1 6.41E+01 6.41E+01 0.72 1.00 3.18
JaFS-L14-1314-T02-A 1 3.63E+01 3.63E+01 0.25 1.00 3.18
JaFS-L14-1314-T03-A 1 1.94E+01 1.94E+01 6.78 1.00 3.18 10000 1000
JaFS-L14-1314-T04-A 1 1.77E+01 1.77E+01 4.65 1.00 3.18
JaFS-L14-1314-T05-A 1 1.67E+01 1.67E+01 10.49 1.00 3.18
JaFS-L14-1314-T06-A 1 1.68E+01 1.68E+01 7.88 1.00 3.18
JaFS-L14-1314-T07-A 1 1.49E+01 1.49E+01 5.62 1.00 3.18
JaFS-L14-1314-T08-A 1 1.48E+01 1.48E+01 7.08 1.00 3.18
JaFS-L14-1314-T09-A 1 1.48E+01 1.48E+01 7.59 1.00 3.18
JaFS-L14-1314-T01-B 1 6.48E+01 6.48E+01 2.83 1.00 3.18
JaFS-L14-1314-T02-B 1 4.14E+01 4.14E+01 4.78 1.00 3.18
JaFS-L14-1314-T03-B 1 2.12E+01 2.12E+01 1.92 1.00 3.18 10000 1000
JaFS-L14-1314-T04-B 1 1.98E+01 1.98E+01 5.60 1.00 3.18
JaFS-L14-1314-T05-B 1 1.85E+01 1.85E+01 3.79 1.00 3.18
JaFS-L14-1314-T06-B 1 1.77E+01 1.77E+01 4.35 1.00 3.18
JaFS-L14-1314-T07-B 1 1.75E+01 1.75E+01 8.65 1.00 3.18
JaFS-L14-1314-T08-B 1 1.69E+01 1.69E+01 3.32 1.00 3.18
JaFS-L14-1314-T09-B 1 1.61E+01 1.61E+01 5.04 1.00 3.18
JaFS-L14-1314-T01-C 1 6.69E+01 6.69E+01 3.26 1.00 3.18
JaFS-L14-1314-T02-C 1 3.11E+01 3.11E+01 2.02 1.00 3.18
JaFS-L14-1314-T03-C 1 1.95E+01 1.95E+01 4.25 1.00 3.18 10000 1000
JaFS-L14-1314-T04-C 1 1.81E+01 1.81E+01 9.04 1.00 3.18
JaFS-L14-1314-T05-C 1 1.78E+01 1.78E+01 2.47 1.00 3.18
JaFS-L14-1314-T06-C 1 1.77E+01 1.77E+01 6.15 1.00 3.18
JaFS-L14-1314-T07-C 1 1.62E+01 1.62E+01 5.01 1.00 3.18
JaFS-L14-1314-T08-C 1 1.59E+01 1.59E+01 3.56 1.00 3.18
JaFS-L14-1314-T09-C 1 1.52E+01 1.52E+01 5.14 1.00 3.18
JaFS-L14-1314-B01-A 1 5.00E-01 U1/2 5.00E-01 12.78 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.08E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-381
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Sb JaFS-L14-1314-T01-A 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T02-A 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T03-A 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T04-A 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T05-A 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T06-A 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T07-A 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T08-A 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T09-A 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T01-B 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T02-B 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T03-B 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T04-B 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T05-B 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T06-B 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T07-B 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T08-B 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T09-B 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T01-C 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T02-C 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T03-C 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T04-C 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T05-C 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T06-C 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T07-C 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T08-C 1 3.75E+00 U1/2
Sb JaFS-L14-1314-T09-C 1 3.75E+00 U1/2
Sb JaFS-L14-1314-B01-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.75E+00 38.38 7.50 23.90
3.75E+00 41.22 7.50 23.90
3.75E+00 46.43 7.50 23.90 10000 1000
3.75E+00 36.26 7.50 23.90
3.75E+00 27.71 7.50 23.90
3.75E+00 14.68 7.50 23.90
3.75E+00 31.36 7.50 23.90
3.75E+00 40.47 7.50 23.90
3.75E+00 16.68 7.50 23.90
3.75E+00 38.03 7.50 23.90
3.75E+00 44.07 7.50 23.90
3.75E+00 40.75 7.50 23.90 10000 1000
3.75E+00 10.31 7.50 23.90
3.75E+00 50.00 7.50 23.90
3.75E+00 14.67 7.50 23.90
3.75E+00 28.94 7.50 23.90
3.75E+00 41.05 7.50 23.90
3.75E+00 29.54 7.50 23.90
3.75E+00 40.88 7.50 23.90
3.75E+00 37.31 7.50 23.90
3.75E+00 32.88 7.50 23.90 10000 1000
3.75E+00 27.93 7.50 23.90
3.75E+00 15.85 7.50 23.90
3.75E+00 50.22 7.50 23.90
3.75E+00 16.57 7.50 23.90
3.75E+00 61.68 7.50 23.90
3.75E+00 16.87 7.50 23.90
3.75E+00 35.30 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.05E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.88E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-382
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
As JaFS-L14-1314-T01-A 1 5.50E+00 U1/2
As JaFS-L14-1314-T02-A 1 5.50E+00 U1/2
As JaFS-L14-1314-T03-A 1 5.50E+00 U1/2
As JaFS-L14-1314-T04-A 1 5.50E+00 U1/2
As JaFS-L14-1314-T05-A 1 5.50E+00 U1/2
As JaFS-L14-1314-T06-A 1 5.50E+00 U1/2
As JaFS-L14-1314-T07-A 1 5.50E+00 U1/2
As JaFS-L14-1314-T08-A 1 5.50E+00 U1/2
As JaFS-L14-1314-T09-A 1 5.50E+00 U1/2
As JaFS-L14-1314-T01-B 1 5.50E+00 U1/2
As JaFS-L14-1314-T02-B 1 5.50E+00 U1/2
As JaFS-L14-1314-T03-B 1 5.50E+00 U1/2
As JaFS-L14-1314-T04-B 1 5.50E+00 U1/2
As JaFS-L14-1314-T05-B 1 5.50E+00 U1/2
As JaFS-L14-1314-T06-B 1 5.50E+00 U1/2
As JaFS-L14-1314-T07-B 1 5.50E+00 U1/2
As JaFS-L14-1314-T08-B 1 5.50E+00 U1/2
As JaFS-L14-1314-T09-B 1 5.50E+00 U1/2
As JaFS-L14-1314-T01-C 1 5.50E+00 U1/2
As JaFS-L14-1314-T02-C 1 5.50E+00 U1/2
As JaFS-L14-1314-T03-C 1 5.50E+00 U1/2
As JaFS-L14-1314-T04-C 1 5.50E+00 U1/2
As JaFS-L14-1314-T05-C 1 5.50E+00 U1/2
As JaFS-L14-1314-T06-C 1 5.50E+00 U1/2
As JaFS-L14-1314-T07-C 1 5.50E+00 U1/2
As JaFS-L14-1314-T08-C 1 5.50E+00 U1/2
As JaFS-L14-1314-T09-C 1 5.50E+00 U1/2
As JaFS-L14-1314-B01-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.50E+00 20.32 11.00 35.00
5.50E+00 15.28 11.00 35.00
5.50E+00 13.61 11.00 35.00 10000 1000
5.50E+00 34.62 11.00 35.00
5.50E+00 14.35 11.00 35.00
5.50E+00 31.85 11.00 35.00
5.50E+00 9.92 11.00 35.00
5.50E+00 22.15 11.00 35.00
5.50E+00 34.18 11.00 35.00
5.50E+00 21.13 11.00 35.00
5.50E+00 28.91 11.00 35.00
5.50E+00 19.71 11.00 35.00 10000 1000
5.50E+00 24.56 11.00 35.00
5.50E+00 30.01 11.00 35.00
5.50E+00 20.17 11.00 35.00
5.50E+00 15.95 11.00 35.00
5.50E+00 47.81 11.00 35.00
5.50E+00 44.66 11.00 35.00
5.50E+00 47.84 11.00 35.00
5.50E+00 40.80 11.00 35.00
5.50E+00 29.96 11.00 35.00 10000 1000
5.50E+00 47.50 11.00 35.00
5.50E+00 36.39 11.00 35.00
5.50E+00 24.36 11.00 35.00
5.50E+00 42.14 11.00 35.00
5.50E+00 12.72 11.00 35.00
5.50E+00 21.92 11.00 35.00
5.50E+00 27.91 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.06E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-383
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
B JaFS-L14-1314-T01-A 1 1.76E+05
B JaFS-L14-1314-T02-A 1 6.42E+04
B JaFS-L14-1314-T03-A 1 1.94E+04
B JaFS-L14-1314-T04-A 1 9.12E+03
B JaFS-L14-1314-T05-A 1 5.78E+03
B JaFS-L14-1314-T06-A 1 2.86E+03
B JaFS-L14-1314-T07-A 1 1.73E+03
B JaFS-L14-1314-T08-A 1 1.20E+03
B JaFS-L14-1314-T09-A 1 8.03E+02
B JaFS-L14-1314-T01-B 1 1.70E+05
B JaFS-L14-1314-T02-B 1 7.42E+04
B JaFS-L14-1314-T03-B 1 2.42E+04
B JaFS-L14-1314-T04-B 1 1.04E+04
B JaFS-L14-1314-T05-B 1 6.26E+03
B JaFS-L14-1314-T06-B 1 2.99E+03
B JaFS-L14-1314-T07-B 1 1.85E+03
B JaFS-L14-1314-T08-B 1 1.26E+03
B JaFS-L14-1314-T09-B 1 8.28E+02
B JaFS-L14-1314-T01-C 1 1.78E+05
B JaFS-L14-1314-T02-C 1 5.84E+04
B JaFS-L14-1314-T03-C 1 1.66E+04
B JaFS-L14-1314-T04-C 1 8.01E+03
B JaFS-L14-1314-T05-C 1 5.11E+03
B JaFS-L14-1314-T06-C 1 2.58E+03
B JaFS-L14-1314-T07-C 1 1.59E+03
B JaFS-L14-1314-T08-C 1 1.05E+03
B JaFS-L14-1314-T09-C 1 5.73E+02
B JaFS-L14-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.76E+05 0.84 1.00 3.18
6.42E+04 1.76 1.00 3.18
1.94E+04 1.53 1.00 3.18 10000 1000
9.12E+03 1.12 1.00 3.18
5.78E+03 0.58 1.00 3.18
2.86E+03 1.37 1.00 3.18
1.73E+03 1.30 1.00 3.18
1.20E+03 1.10 1.00 3.18
8.03E+02 1.76 1.00 3.18
1.70E+05 1.42 1.00 3.18
7.42E+04 0.47 1.00 3.18
2.42E+04 1.41 1.00 3.18 10000 1000
1.04E+04 1.55 1.00 3.18
6.26E+03 4.05 1.00 3.18
2.99E+03 4.48 1.00 3.18
1.85E+03 1.34 1.00 3.18
1.26E+03 0.87 1.00 3.18
8.28E+02 0.54 1.00 3.18
1.78E+05 0.86 1.00 3.18
5.84E+04 1.27 1.00 3.18
1.66E+04 0.69 1.00 3.18 10000 1000
8.01E+03 2.84 1.00 3.18
5.11E+03 0.68 1.00 3.18
2.58E+03 0.84 1.00 3.18
1.59E+03 2.39 1.00 3.18
1.05E+03 2.30 1.00 3.18
5.73E+02 1.01 1.00 3.18
5.00E-01 4.69 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.02E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.52E+04 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.76E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-384
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Ba JaFS-L14-1314-T01-A 1 1.10E+02
Ba JaFS-L14-1314-T02-A 1 6.88E+01
Ba JaFS-L14-1314-T03-A 1 4.25E+01
Ba JaFS-L14-1314-T04-A 1 2.61E+01
Ba JaFS-L14-1314-T05-A 1 2.60E+01
Ba JaFS-L14-1314-T06-A 1 2.75E+01
Ba JaFS-L14-1314-T07-A 1 2.07E+01
Ba JaFS-L14-1314-T08-A 1 1.60E+01
Ba JaFS-L14-1314-T09-A 1 1.20E+01
Ba JaFS-L14-1314-T01-B 1 1.11E+02
Ba JaFS-L14-1314-T02-B 1 8.14E+01
Ba JaFS-L14-1314-T03-B 1 6.83E+01
Ba JaFS-L14-1314-T04-B 1 3.47E+01
Ba JaFS-L14-1314-T05-B 1 3.43E+01
Ba JaFS-L14-1314-T06-B 1 3.38E+01
Ba JaFS-L14-1314-T07-B 1 2.48E+01
Ba JaFS-L14-1314-T08-B 1 1.99E+01
Ba JaFS-L14-1314-T09-B 1 1.47E+01
Ba JaFS-L14-1314-T01-C 1 1.08E+02
Ba JaFS-L14-1314-T02-C 1 7.63E+01
Ba JaFS-L14-1314-T03-C 1 4.27E+01
Ba JaFS-L14-1314-T04-C 1 2.89E+01
Ba JaFS-L14-1314-T05-C 1 2.98E+01
Ba JaFS-L14-1314-T06-C 1 2.90E+01
Ba JaFS-L14-1314-T07-C 1 2.05E+01
Ba JaFS-L14-1314-T08-C 1 1.47E+01
Ba JaFS-L14-1314-T09-C 1 1.09E+01
Ba JaFS-L14-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+02 0.50 1.00 3.18
6.88E+01 2.94 1.00 3.18
4.25E+01 0.41 1.00 3.18 10000 1000
2.61E+01 0.28 1.00 3.18
2.60E+01 1.91 1.00 3.18
2.75E+01 1.03 1.00 3.18
2.07E+01 1.82 1.00 3.18
1.60E+01 1.02 1.00 3.18
1.20E+01 2.35 1.00 3.18
1.11E+02 1.55 1.00 3.18
8.14E+01 0.54 1.00 3.18
6.83E+01 1.67 1.00 3.18 10000 1000
3.47E+01 0.64 1.00 3.18
3.43E+01 5.66 1.00 3.18
3.38E+01 4.47 1.00 3.18
2.48E+01 0.94 1.00 3.18
1.99E+01 1.77 1.00 3.18
1.47E+01 3.13 1.00 3.18
1.08E+02 0.50 1.00 3.18
7.63E+01 2.21 1.00 3.18
4.27E+01 2.45 1.00 3.18 10000 1000
2.89E+01 1.89 1.00 3.18
2.98E+01 0.27 1.00 3.18
2.90E+01 2.32 1.00 3.18
2.05E+01 1.82 1.00 3.18
1.47E+01 0.78 1.00 3.18
1.09E+01 2.30 1.00 3.18
5.00E-01 27.31 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.05E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-385
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Be JaFS-L14-1314-T01-A 1 9.50E-01 U1/2
Be JaFS-L14-1314-T02-A 1 9.50E-01 U1/2
Be JaFS-L14-1314-T03-A 1 9.50E-01 U1/2
Be JaFS-L14-1314-T04-A 1 9.50E-01 U1/2
Be JaFS-L14-1314-T05-A 1 9.50E-01 U1/2
Be JaFS-L14-1314-T06-A 1 9.50E-01 U1/2
Be JaFS-L14-1314-T07-A 1 9.50E-01 U1/2
Be JaFS-L14-1314-T08-A 1 9.50E-01 U1/2
Be JaFS-L14-1314-T09-A 1 9.50E-01 U1/2
Be JaFS-L14-1314-T01-B 1 9.50E-01 U1/2
Be JaFS-L14-1314-T02-B 1 9.50E-01 U1/2
Be JaFS-L14-1314-T03-B 1 9.50E-01 U1/2
Be JaFS-L14-1314-T04-B 1 9.50E-01 U1/2
Be JaFS-L14-1314-T05-B 1 9.50E-01 U1/2
Be JaFS-L14-1314-T06-B 1 9.50E-01 U1/2
Be JaFS-L14-1314-T07-B 1 9.50E-01 U1/2
Be JaFS-L14-1314-T08-B 1 9.50E-01 U1/2
Be JaFS-L14-1314-T09-B 1 9.50E-01 U1/2
Be JaFS-L14-1314-T01-C 1 9.50E-01 U1/2
Be JaFS-L14-1314-T02-C 1 9.50E-01 U1/2
Be JaFS-L14-1314-T03-C 1 9.50E-01 U1/2
Be JaFS-L14-1314-T04-C 1 9.50E-01 U1/2
Be JaFS-L14-1314-T05-C 1 9.50E-01 U1/2
Be JaFS-L14-1314-T06-C 1 9.50E-01 U1/2
Be JaFS-L14-1314-T07-C 1 9.50E-01 U1/2
Be JaFS-L14-1314-T08-C 1 9.50E-01 U1/2
Be JaFS-L14-1314-T09-C 1 9.50E-01 U1/2
Be JaFS-L14-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 37.76 1.90 6.00
9.50E-01 63.78 1.90 6.00
9.50E-01 52.93 1.90 6.00 10000 1000
9.50E-01 36.08 1.90 6.00
9.50E-01 14.06 1.90 6.00
9.50E-01 22.77 1.90 6.00
9.50E-01 71.92 1.90 6.00
9.50E-01 11.35 1.90 6.00
9.50E-01 38.19 1.90 6.00
9.50E-01 10.84 1.90 6.00
9.50E-01 18.74 1.90 6.00
9.50E-01 39.24 1.90 6.00 10000 1000
9.50E-01 19.80 1.90 6.00
9.50E-01 36.10 1.90 6.00
9.50E-01 51.46 1.90 6.00
9.50E-01 74.12 1.90 6.00
9.50E-01 17.15 1.90 6.00
9.50E-01 50.44 1.90 6.00
9.50E-01 14.33 1.90 6.00
9.50E-01 66.75 1.90 6.00
9.50E-01 55.47 1.90 6.00 10000 1000
9.50E-01 25.39 1.90 6.00
9.50E-01 7.63 1.90 6.00
9.50E-01 6.99 1.90 6.00
9.50E-01 41.53 1.90 6.00
9.50E-01 54.46 1.90 6.00
9.50E-01 33.83 1.90 6.00
9.50E-01 9.86 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.09E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-386
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
Cd JaFS-L14-1314-T01-A 1 1.76E+01
Cd JaFS-L14-1314-T02-A 1 3.40E+00 E
Cd JaFS-L14-1314-T03-A 1 1.10E+00 U1/2
Cd JaFS-L14-1314-T04-A 1 1.10E+00 U1/2
Cd JaFS-L14-1314-T05-A 1 1.10E+00 U1/2
Cd JaFS-L14-1314-T06-A 1 1.10E+00 U1/2
Cd JaFS-L14-1314-T07-A 1 1.10E+00 U1/2
Cd JaFS-L14-1314-T08-A 1 1.10E+00 U1/2
Cd JaFS-L14-1314-T09-A 1 1.10E+00 U1/2
Cd JaFS-L14-1314-T01-B 1 1.84E+01
Cd JaFS-L14-1314-T02-B 1 4.86E+00 E
Cd JaFS-L14-1314-T03-B 1 1.10E+00 U1/2
Cd JaFS-L14-1314-T04-B 1 1.10E+00 U1/2
Cd JaFS-L14-1314-T05-B 1 1.10E+00 U1/2
Cd JaFS-L14-1314-T06-B 1 1.10E+00 U1/2
Cd JaFS-L14-1314-T07-B 1 1.10E+00 U1/2
Cd JaFS-L14-1314-T08-B 1 1.10E+00 U1/2
Cd JaFS-L14-1314-T09-B 1 1.10E+00 U1/2
Cd JaFS-L14-1314-T01-C 1 1.85E+01
Cd JaFS-L14-1314-T02-C 1 3.36E+00 E
Cd JaFS-L14-1314-T03-C 1 1.10E+00 U1/2
Cd JaFS-L14-1314-T04-C 1 1.10E+00 U1/2
Cd JaFS-L14-1314-T05-C 1 1.10E+00 U1/2
Cd JaFS-L14-1314-T06-C 1 1.10E+00 U1/2
Cd JaFS-L14-1314-T07-C 1 1.10E+00 U1/2
Cd JaFS-L14-1314-T08-C 1 1.10E+00 U1/2
Cd JaFS-L14-1314-T09-C 1 1.10E+00 U1/2
Cd JaFS-L14-1314-B01-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.76E+01 1.98 2.20 7.00
3.40E+00 0.34 2.20 7.00
1.10E+00 3.89 2.20 7.00 10000 1000
1.10E+00 18.28 2.20 7.00
1.10E+00 13.85 2.20 7.00
1.10E+00 29.00 2.20 7.00
1.10E+00 38.68 2.20 7.00
1.10E+00 10.01 2.20 7.00
1.10E+00 21.82 2.20 7.00
1.84E+01 0.62 2.20 7.00
4.86E+00 1.13 2.20 7.00
1.10E+00 14.63 2.20 7.00 10000 1000
1.10E+00 16.78 2.20 7.00
1.10E+00 35.31 2.20 7.00
1.10E+00 26.98 2.20 7.00
1.10E+00 20.55 2.20 7.00
1.10E+00 14.94 2.20 7.00
1.10E+00 24.03 2.20 7.00
1.85E+01 0.87 2.20 7.00
3.36E+00 1.98 2.20 7.00
1.10E+00 11.44 2.20 7.00 10000 1000
1.10E+00 9.54 2.20 7.00
1.10E+00 16.51 2.20 7.00
1.10E+00 18.24 2.20 7.00
1.10E+00 25.04 2.20 7.00
1.10E+00 24.21 2.20 7.00
1.10E+00 50.53 2.20 7.00
1.10E+00 47.10 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.12E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-387
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Ca JaFS-L14-1314-T01-A 1 3.39E+05
Ca JaFS-L14-1314-T02-A 1 5.70E+04
Ca JaFS-L14-1314-T03-A 1 1.54E+04
Ca JaFS-L14-1314-T04-A 1 1.48E+04
Ca JaFS-L14-1314-T05-A 1 1.57E+04
Ca JaFS-L14-1314-T06-A 1 1.33E+04
Ca JaFS-L14-1314-T07-A 1 1.16E+04
Ca JaFS-L14-1314-T08-A 1 1.02E+04
Ca JaFS-L14-1314-T09-A 1 9.24E+03
Ca JaFS-L14-1314-T01-B 1 3.15E+05
Ca JaFS-L14-1314-T02-B 1 8.00E+04
Ca JaFS-L14-1314-T03-B 1 1.88E+04
Ca JaFS-L14-1314-T04-B 1 1.76E+04
Ca JaFS-L14-1314-T05-B 1 1.78E+04
Ca JaFS-L14-1314-T06-B 1 1.46E+04
Ca JaFS-L14-1314-T07-B 1 1.31E+04
Ca JaFS-L14-1314-T08-B 1 1.15E+04
Ca JaFS-L14-1314-T09-B 1 1.07E+04
Ca JaFS-L14-1314-T01-C 1 3.29E+05
Ca JaFS-L14-1314-T02-C 1 5.33E+04
Ca JaFS-L14-1314-T03-C 1 1.57E+04
Ca JaFS-L14-1314-T04-C 1 1.59E+04
Ca JaFS-L14-1314-T05-C 1 1.61E+04
Ca JaFS-L14-1314-T06-C 1 1.31E+04
Ca JaFS-L14-1314-T07-C 1 1.11E+04
Ca JaFS-L14-1314-T08-C 1 9.64E+03
Ca JaFS-L14-1314-T09-C 1 8.13E+03
Ca JaFS-L14-1314-B01-A 1 1.30E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.39E+05 0.19 2.60 8.30
5.70E+04 1.97 2.60 8.30
1.54E+04 1.66 2.60 8.30 10000 1000
1.48E+04 0.32 2.60 8.30
1.57E+04 1.67 2.60 8.30
1.33E+04 0.54 2.60 8.30
1.16E+04 1.02 2.60 8.30
1.02E+04 0.81 2.60 8.30
9.24E+03 1.30 2.60 8.30
3.15E+05 1.15 2.60 8.30
8.00E+04 1.10 2.60 8.30
1.88E+04 0.89 2.60 8.30 10000 1000
1.76E+04 0.45 2.60 8.30
1.78E+04 5.13 2.60 8.30
1.46E+04 4.80 2.60 8.30
1.31E+04 0.62 2.60 8.30
1.15E+04 0.67 2.60 8.30
1.07E+04 1.06 2.60 8.30
3.29E+05 0.34 2.60 8.30
5.33E+04 1.70 2.60 8.30
1.57E+04 2.34 2.60 8.30 10000 1000
1.59E+04 2.10 2.60 8.30
1.61E+04 1.37 2.60 8.30
1.31E+04 1.31 2.60 8.30
1.11E+04 1.81 2.60 8.30
9.64E+03 0.68 2.60 8.30
8.13E+03 1.89 2.60 8.30
1.30E+00 5.95 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.63E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.98E+04 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.66E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-388
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cr JaFS-L14-1314-T01-A 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T02-A 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T03-A 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T04-A 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T05-A 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T06-A 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T07-A 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T08-A 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T09-A 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T01-B 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T02-B 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T03-B 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T04-B 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T05-B 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T06-B 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T07-B 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T08-B 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T09-B 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T01-C 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T02-C 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T03-C 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T04-C 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T05-C 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T06-C 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T07-C 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T08-C 1 6.00E-01 U1/2
Cr JaFS-L14-1314-T09-C 1 6.00E-01 U1/2
Cr JaFS-L14-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 31.35 1.20 3.82
6.00E-01 31.93 1.20 3.82
6.00E-01 19.87 1.20 3.82 10000 1000
6.00E-01 25.30 1.20 3.82
6.00E-01 40.23 1.20 3.82
6.00E-01 73.25 1.20 3.82
6.00E-01 39.25 1.20 3.82
6.00E-01 15.98 1.20 3.82
6.00E-01 50.46 1.20 3.82
6.00E-01 21.72 1.20 3.82
6.00E-01 60.15 1.20 3.82
6.00E-01 12.97 1.20 3.82 10000 1000
6.00E-01 10.26 1.20 3.82
6.00E-01 44.57 1.20 3.82
6.00E-01 41.64 1.20 3.82
6.00E-01 24.55 1.20 3.82
6.00E-01 51.56 1.20 3.82
6.00E-01 49.87 1.20 3.82
6.00E-01 35.53 1.20 3.82
6.00E-01 51.79 1.20 3.82
6.00E-01 22.69 1.20 3.82 10000 1000
6.00E-01 7.57 1.20 3.82
6.00E-01 41.47 1.20 3.82
6.00E-01 34.86 1.20 3.82
6.00E-01 53.95 1.20 3.82
6.00E-01 32.37 1.20 3.82
6.00E-01 24.35 1.20 3.82
6.00E-01 10.03 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.66E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.82E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-389
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Co JaFS-L14-1314-T01-A 1 9.00E-01 U1/2
Co JaFS-L14-1314-T02-A 1 9.00E-01 U1/2
Co JaFS-L14-1314-T03-A 1 9.00E-01 U1/2
Co JaFS-L14-1314-T04-A 1 9.00E-01 U1/2
Co JaFS-L14-1314-T05-A 1 9.00E-01 U1/2
Co JaFS-L14-1314-T06-A 1 9.00E-01 U1/2
Co JaFS-L14-1314-T07-A 1 9.00E-01 U1/2
Co JaFS-L14-1314-T08-A 1 9.00E-01 U1/2
Co JaFS-L14-1314-T09-A 1 9.00E-01 U1/2
Co JaFS-L14-1314-T01-B 1 9.00E-01 U1/2
Co JaFS-L14-1314-T02-B 1 9.00E-01 U1/2
Co JaFS-L14-1314-T03-B 1 9.00E-01 U1/2
Co JaFS-L14-1314-T04-B 1 9.00E-01 U1/2
Co JaFS-L14-1314-T05-B 1 9.00E-01 U1/2
Co JaFS-L14-1314-T06-B 1 9.00E-01 U1/2
Co JaFS-L14-1314-T07-B 1 9.00E-01 U1/2
Co JaFS-L14-1314-T08-B 1 9.00E-01 U1/2
Co JaFS-L14-1314-T09-B 1 9.00E-01 U1/2
Co JaFS-L14-1314-T01-C 1 9.00E-01 U1/2
Co JaFS-L14-1314-T02-C 1 9.00E-01 U1/2
Co JaFS-L14-1314-T03-C 1 9.00E-01 U1/2
Co JaFS-L14-1314-T04-C 1 9.00E-01 U1/2
Co JaFS-L14-1314-T05-C 1 9.00E-01 U1/2
Co JaFS-L14-1314-T06-C 1 9.00E-01 U1/2
Co JaFS-L14-1314-T07-C 1 9.00E-01 U1/2
Co JaFS-L14-1314-T08-C 1 9.00E-01 U1/2
Co JaFS-L14-1314-T09-C 1 9.00E-01 U1/2
Co JaFS-L14-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 24.09 1.80 5.72
9.00E-01 46.30 1.80 5.72
9.00E-01 22.19 1.80 5.72 10000 1000
9.00E-01 18.55 1.80 5.72
9.00E-01 44.36 1.80 5.72
9.00E-01 33.35 1.80 5.72
9.00E-01 15.14 1.80 5.72
9.00E-01 22.86 1.80 5.72
9.00E-01 11.96 1.80 5.72
9.00E-01 47.91 1.80 5.72
9.00E-01 24.80 1.80 5.72
9.00E-01 47.75 1.80 5.72 10000 1000
9.00E-01 1.91 1.80 5.72
9.00E-01 50.81 1.80 5.72
9.00E-01 51.91 1.80 5.72
9.00E-01 13.63 1.80 5.72
9.00E-01 38.10 1.80 5.72
9.00E-01 46.63 1.80 5.72
9.00E-01 33.23 1.80 5.72
9.00E-01 52.52 1.80 5.72
9.00E-01 46.55 1.80 5.72 10000 1000
9.00E-01 11.58 1.80 5.72
9.00E-01 18.09 1.80 5.72
9.00E-01 9.22 1.80 5.72
9.00E-01 20.18 1.80 5.72
9.00E-01 62.13 1.80 5.72
9.00E-01 19.82 1.80 5.72
9.00E-01 52.81 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.63E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.09E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.27E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-390
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Cu JaFS-L14-1314-T01-A 1 1.84E+03
Cu JaFS-L14-1314-T02-A 1 1.18E+03
Cu JaFS-L14-1314-T03-A 1 5.52E+02
Cu JaFS-L14-1314-T04-A 1 3.37E+02
Cu JaFS-L14-1314-T05-A 1 2.79E+02
Cu JaFS-L14-1314-T06-A 1 2.06E+02
Cu JaFS-L14-1314-T07-A 1 1.50E+02
Cu JaFS-L14-1314-T08-A 1 1.12E+02
Cu JaFS-L14-1314-T09-A 1 8.10E+01
Cu JaFS-L14-1314-T01-B 1 1.40E+03
Cu JaFS-L14-1314-T02-B 1 9.59E+02
Cu JaFS-L14-1314-T03-B 1 5.39E+02
Cu JaFS-L14-1314-T04-B 1 3.31E+02
Cu JaFS-L14-1314-T05-B 1 2.64E+02
Cu JaFS-L14-1314-T06-B 1 1.77E+02
Cu JaFS-L14-1314-T07-B 1 1.35E+02
Cu JaFS-L14-1314-T08-B 1 1.00E+02
Cu JaFS-L14-1314-T09-B 1 7.11E+01
Cu JaFS-L14-1314-T01-C 1 2.22E+03
Cu JaFS-L14-1314-T02-C 1 1.19E+03
Cu JaFS-L14-1314-T03-C 1 5.35E+02
Cu JaFS-L14-1314-T04-C 1 3.31E+02
Cu JaFS-L14-1314-T05-C 1 2.81E+02
Cu JaFS-L14-1314-T06-C 1 1.94E+02
Cu JaFS-L14-1314-T07-C 1 1.37E+02
Cu JaFS-L14-1314-T08-C 1 1.01E+02
Cu JaFS-L14-1314-T09-C 1 7.06E+01
Cu JaFS-L14-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.84E+03 0.91 3.70 11.80
1.18E+03 2.20 3.70 11.80
5.52E+02 1.57 3.70 11.80 10000 1000
3.37E+02 0.69 3.70 11.80
2.79E+02 1.01 3.70 11.80
2.06E+02 0.66 3.70 11.80
1.50E+02 1.36 3.70 11.80
1.12E+02 1.84 3.70 11.80
8.10E+01 1.32 3.70 11.80
1.40E+03 0.72 3.70 11.80
9.59E+02 1.05 3.70 11.80
5.39E+02 0.72 3.70 11.80 10000 1000
3.31E+02 0.52 3.70 11.80
2.64E+02 9.12 3.70 11.80
1.77E+02 5.57 3.70 11.80
1.35E+02 0.84 3.70 11.80
1.00E+02 0.76 3.70 11.80
7.11E+01 2.20 3.70 11.80
2.22E+03 0.72 3.70 11.80
1.19E+03 1.20 3.70 11.80
5.35E+02 1.49 3.70 11.80 10000 1000
3.31E+02 2.30 3.70 11.80
2.81E+02 1.63 3.70 11.80
1.94E+02 1.01 3.70 11.80
1.37E+02 1.38 3.70 11.80
1.01E+02 0.85 3.70 11.80
7.06E+01 2.61 3.70 11.80
1.85E+00 43.57 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.51E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.60E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.57E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/123:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-391
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Fe JaFS-L14-1314-T01-A 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T02-A 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T03-A 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T04-A 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T05-A 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T06-A 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T07-A 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T08-A 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T09-A 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T01-B 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T02-B 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T03-B 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T04-B 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T05-B 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T06-B 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T07-B 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T08-B 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T09-B 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T01-C 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T02-C 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T03-C 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T04-C 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T05-C 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T06-C 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T07-C 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T08-C 1 1.00E+00 U1/2
Fe JaFS-L14-1314-T09-C 1 1.00E+00 U1/2
Fe JaFS-L14-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 6.80 2.00 6.40
1.00E+00 1.90 2.00 6.40
1.00E+00 9.25 2.00 6.40 10000 1000
1.00E+00 3.98 2.00 6.40
1.00E+00 25.34 2.00 6.40
1.00E+00 7.04 2.00 6.40
1.00E+00 6.21 2.00 6.40
1.00E+00 9.31 2.00 6.40
1.00E+00 5.21 2.00 6.40
1.00E+00 22.06 2.00 6.40
1.00E+00 12.89 2.00 6.40
1.00E+00 0.74 2.00 6.40 10000 1000
1.00E+00 5.76 2.00 6.40
1.00E+00 6.51 2.00 6.40
1.00E+00 20.58 2.00 6.40
1.00E+00 14.51 2.00 6.40
1.00E+00 12.28 2.00 6.40
1.00E+00 12.35 2.00 6.40
1.00E+00 5.33 2.00 6.40
1.00E+00 9.83 2.00 6.40
1.00E+00 5.00 2.00 6.40 10000 1000
1.00E+00 16.26 2.00 6.40
1.00E+00 10.32 2.00 6.40
1.00E+00 18.95 2.00 6.40
1.00E+00 2.62 2.00 6.40
1.00E+00 6.58 2.00 6.40
1.00E+00 11.07 2.00 6.40
1.00E+00 2.04 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.76E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.19E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.34E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-392
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Pb JaFS-L14-1314-T01-A 1 1.24E+02
Pb JaFS-L14-1314-T02-A 1 9.51E+01
Pb JaFS-L14-1314-T03-A 1 8.98E+01
Pb JaFS-L14-1314-T04-A 1 8.13E+01
Pb JaFS-L14-1314-T05-A 1 7.94E+01
Pb JaFS-L14-1314-T06-A 1 6.53E+01
Pb JaFS-L14-1314-T07-A 1 5.69E+01
Pb JaFS-L14-1314-T08-A 1 4.77E+01
Pb JaFS-L14-1314-T09-A 1 3.70E+01
Pb JaFS-L14-1314-T01-B 1 1.09E+02
Pb JaFS-L14-1314-T02-B 1 1.50E+02
Pb JaFS-L14-1314-T03-B 1 1.32E+02
Pb JaFS-L14-1314-T04-B 1 1.12E+02
Pb JaFS-L14-1314-T05-B 1 1.09E+02
Pb JaFS-L14-1314-T06-B 1 7.88E+01
Pb JaFS-L14-1314-T07-B 1 7.07E+01
Pb JaFS-L14-1314-T08-B 1 5.53E+01
Pb JaFS-L14-1314-T09-B 1 4.58E+01
Pb JaFS-L14-1314-T01-C 1 1.31E+02
Pb JaFS-L14-1314-T02-C 1 1.66E+02
Pb JaFS-L14-1314-T03-C 1 1.13E+02
Pb JaFS-L14-1314-T04-C 1 9.07E+01
Pb JaFS-L14-1314-T05-C 1 8.80E+01
Pb JaFS-L14-1314-T06-C 1 6.15E+01
Pb JaFS-L14-1314-T07-C 1 5.35E+01
Pb JaFS-L14-1314-T08-C 1 4.15E+01
Pb JaFS-L14-1314-T09-C 1 3.12E+01
Pb JaFS-L14-1314-B01-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.24E+02 13.00 6.80 21.60
9.51 E+01 6.79 6.80 21.60
8.98E+01 5.50 6.80 21.60 10000 1000
8.13E+01 2.64 6.80 21.60
7.94E+01 3.08 6.80 21.60
6.53E+01 5.53 6.80 21.60
5.69E+01 6.46 6.80 21.60
4.77E+01 9.32 6.80 21.60
3.70E+01 2.60 6.80 21.60
1.09E+02 2.78 6.80 21.60
1.50E+02 4.30 6.80 21.60
1.32E+02 1.97 6.80 21.60 10000 1000
1.12E+02 0.58 6.80 21.60
1.09E+02 2.20 6.80 21.60
7.88E+01 1.15 6.80 21.60
7.07E+01 6.32 6.80 21.60
5.53E+01 1.83 6.80 21.60
4.58E+01 1.16 6.80 21.60
1.31E+02 1.50 6.80 21.60
1.66E+02 2.89 6.80 21.60
1.13E+02 2.23 6.80 21.60 10000 1000
9.07E+01 4.97 6.80 21.60
8.80E+01 0.77 6.80 21.60
6.15E+01 6.82 6.80 21.60
5.35E+01 5.19 6.80 21.60
4.15E+01 6.93 6.80 21.60
3.12E+01 5.99 6.80 21.60
3.40E+00 28.49 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.19E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.20E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.22E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-393
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Li JaFS-L14-1314-T01-A 1 9.15E+01
Li JaFS-L14-1314-T02-A 1 1.44E+01
Li JaFS-L14-1314-T03-A 1 2.69E+00 E
Li JaFS-L14-1314-T04-A 1 9.50E-01 U1/2
Li JaFS-L14-1314-T05-A 1 9.50E-01 U1/2
Li JaFS-L14-1314-T06-A 1 9.50E-01 U1/2
Li JaFS-L14-1314-T07-A 1 9.50E-01 U1/2
Li JaFS-L14-1314-T08-A 1 9.50E-01 U1/2
Li JaFS-L14-1314-T09-A 1 9.50E-01 U1/2
Li JaFS-L14-1314-T01-B 1 1.05E+02
Li JaFS-L14-1314-T02-B 1 1.46E+01
Li JaFS-L14-1314-T03-B 1 4.84E+00 E
Li JaFS-L14-1314-T04-B 1 9.50E-01 U1/2
Li JaFS-L14-1314-T05-B 1 9.50E-01 U1/2
Li JaFS-L14-1314-T06-B 1 9.50E-01 U1/2
Li JaFS-L14-1314-T07-B 1 9.50E-01 U1/2
Li JaFS-L14-1314-T08-B 1 9.50E-01 U1/2
Li JaFS-L14-1314-T09-B 1 9.50E-01 U1/2
Li JaFS-L14-1314-T01-C 1 1.02E+02
Li JaFS-L14-1314-T02-C 1 1.15E+01
Li JaFS-L14-1314-T03-C 1 3.42E+00 E
Li JaFS-L14-1314-T04-C 1 9.50E-01 U1/2
Li JaFS-L14-1314-T05-C 1 9.50E-01 U1/2
Li JaFS-L14-1314-T06-C 1 9.50E-01 U1/2
Li JaFS-L14-1314-T07-C 1 9.50E-01 U1/2
Li JaFS-L14-1314-T08-C 1 9.50E-01 U1/2
Li JaFS-L14-1314-T09-C 1 9.50E-01 U1/2
Li JaFS-L14-1314-B01-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.15E+01 0.88 1.90 6.00
1.44E+01 11.26 1.90 6.00
2.69E+00 11.24 1.90 6.00 10000 1000
9.50E-01 41.25 1.90 6.00
9.50E-01 21.18 1.90 6.00
9.50E-01 44.81 1.90 6.00
9.50E-01 11.25 1.90 6.00
9.50E-01 36.55 1.90 6.00
9.50E-01 5.66 1.90 6.00
1.05E+02 2.15 1.90 6.00
1.46E+01 4.62 1.90 6.00
4.84E+00 28.22 1.90 6.00 10000 1000
9.50E-01 48.23 1.90 6.00
9.50E-01 31.55 1.90 6.00
9.50E-01 51.92 1.90 6.00
9.50E-01 60.49 1.90 6.00
9.50E-01 31.47 1.90 6.00
9.50E-01 24.46 1.90 6.00
1.02E+02 0.86 1.90 6.00
1.15E+01 1.35 1.90 6.00
3.42E+00 8.85 1.90 6.00 10000 1000
9.50E-01 22.47 1.90 6.00
9.50E-01 38.81 1.90 6.00
9.50E-01 154.83 1.90 6.00
9.50E-01 29.07 1.90 6.00
9.50E-01 55.77 1.90 6.00
9.50E-01 29.27 1.90 6.00
9.50E-01 159.91 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.89E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.41 E+02 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.50E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-394
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Mn JaFS-L14-1314-T01-A 1 3.05E+02
Mn JaFS-L14-1314-T02-A 1 3.35E+01
Mn JaFS-L14-1314-T03-A 1 9.56E+00
Mn JaFS-L14-1314-T04-A 1 8.66E+00
Mn JaFS-L14-1314-T05-A 1 9.65E+00
Mn JaFS-L14-1314-T06-A 1 1.68E+01
Mn JaFS-L14-1314-T07-A 1 1.39E+01
Mn JaFS-L14-1314-T08-A 1 8.14E+00
Mn JaFS-L14-1314-T09-A 1 6.05E+00 E
Mn JaFS-L14-1314-T01-B 1 3.28E+02
Mn JaFS-L14-1314-T02-B 1 3.64E+01
Mn JaFS-L14-1314-T03-B 1 1.40E+01
Mn JaFS-L14-1314-T04-B 1 1.20E+01
Mn JaFS-L14-1314-T05-B 1 1.17E+01
Mn JaFS-L14-1314-T06-B 1 1.81E+01
Mn JaFS-L14-1314-T07-B 1 1.58E+01
Mn JaFS-L14-1314-T08-B 1 1.06E+01
Mn JaFS-L14-1314-T09-B 1 7.52E+00
Mn JaFS-L14-1314-T01-C 1 2.98E+02
Mn JaFS-L14-1314-T02-C 1 3.37E+01
Mn JaFS-L14-1314-T03-C 1 9.25E+00
Mn JaFS-L14-1314-T04-C 1 8.73E+00
Mn JaFS-L14-1314-T05-C 1 9.99E+00
Mn JaFS-L14-1314-T06-C 1 1.32E+01
Mn JaFS-L14-1314-T07-C 1 8.49E+00
Mn JaFS-L14-1314-T08-C 1 8.39E+00
Mn JaFS-L14-1314-T09-C 1 3.72E+00 E
Mn JaFS-L14-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.05E+02 0.78 2.00 6.40
3.35E+01 2.84 2.00 6.40
9.56E+00 2.16 2.00 6.40 10000 1000
8.66E+00 0.64 2.00 6.40
9.65E+00 1.28 2.00 6.40
1.68E+01 0.32 2.00 6.40
1.39E+01 2.03 2.00 6.40
8.14E+00 1.69 2.00 6.40
6.05E+00 1.50 2.00 6.40
3.28E+02 0.84 2.00 6.40
3.64E+01 1.01 2.00 6.40
1.40E+01 0.45 2.00 6.40 10000 1000
1.20E+01 0.22 2.00 6.40
1.17E+01 5.97 2.00 6.40
1.81E+01 4.37 2.00 6.40
1.58E+01 1.27 2.00 6.40
1.06E+01 0.66 2.00 6.40
7.52E+00 1.90 2.00 6.40
2.98E+02 0.58 2.00 6.40
3.37E+01 1.16 2.00 6.40
9.25E+00 1.37 2.00 6.40 10000 1000
8.73E+00 2.61 2.00 6.40
9.99E+00 1.55 2.00 6.40
1.32E+01 1.69 2.00 6.40
8.49E+00 2.00 2.00 6.40
8.39E+00 1.50 2.00 6.40
3.72E+00 3.11 2.00 6.40
1.00E+00 21.01 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.05E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-395
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Mg JaFS-L14-1314-T01-A 1 6.45E+04
Mg JaFS-L14-1314-T02-A 1 9.44E+03
Mg JaFS-L14-1314-T03-A 1 2.48E+03
Mg JaFS-L14-1314-T04-A 1 2.31E+03
Mg JaFS-L14-1314-T05-A 1 2.39E+03
Mg JaFS-L14-1314-T06-A 1 1.92E+03
Mg JaFS-L14-1314-T07-A 1 1.59E+03
Mg JaFS-L14-1314-T08-A 1 1.31E+03
Mg JaFS-L14-1314-T09-A 1 1.12E+03
Mg JaFS-L14-1314-T01-B 1 6.26E+04
Mg JaFS-L14-1314-T02-B 1 1.48E+04
Mg JaFS-L14-1314-T03-B 1 3.34E+03
Mg JaFS-L14-1314-T04-B 1 2.99E+03
Mg JaFS-L14-1314-T05-B 1 2.90E+03
Mg JaFS-L14-1314-T06-B 1 2.22E+03
Mg JaFS-L14-1314-T07-B 1 1.84E+03
Mg JaFS-L14-1314-T08-B 1 1.49E+03
Mg JaFS-L14-1314-T09-B 1 1.28E+03
Mg JaFS-L14-1314-T01-C 1 6.46E+04
Mg JaFS-L14-1314-T02-C 1 9.76E+03
Mg JaFS-L14-1314-T03-C 1 2.63E+03
Mg JaFS-L14-1314-T04-C 1 2.54E+03
Mg JaFS-L14-1314-T05-C 1 2.50E+03
Mg JaFS-L14-1314-T06-C 1 1.89E+03
Mg JaFS-L14-1314-T07-C 1 1.48E+03
Mg JaFS-L14-1314-T08-C 1 1.17E+03
Mg JaFS-L14-1314-T09-C 1 9.47E+02
Mg JaFS-L14-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.45E+04 0.51 1.00 3.18
9.44E+03 2.17 1.00 3.18
2.48E+03 1.12 1.00 3.18 10000 1000
2.31E+03 0.94 1.00 3.18
2.39E+03 1.33 1.00 3.18
1.92E+03 1.42 1.00 3.18
1.59E+03 1.20 1.00 3.18
1.31E+03 3.21 1.00 3.18
1.12E+03 1.01 1.00 3.18
6.26E+04 0.52 1.00 3.18
1.48E+04 1.45 1.00 3.18
3.34E+03 0.83 1.00 3.18 10000 1000
2.99E+03 0.91 1.00 3.18
2.90E+03 5.07 1.00 3.18
2.22E+03 3.23 1.00 3.18
1.84E+03 1.09 1.00 3.18
1.49E+03 0.63 1.00 3.18
1.28E+03 1.96 1.00 3.18
6.46E+04 0.88 1.00 3.18
9.76E+03 1.22 1.00 3.18
2.63E+03 2.91 1.00 3.18 10000 1000
2.54E+03 2.13 1.00 3.18
2.50E+03 1.28 1.00 3.18
1.89E+03 1.81 1.00 3.18
1.48E+03 0.99 1.00 3.18
1.17E+03 1.01 1.00 3.18
9.47E+02 2.08 1.00 3.18
5.00E-01 12.72 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.48E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.34E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.66E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-396
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Mo JaFS-L14-1314-T01-A 1 1.02E+02
Mo JaFS-L14-1314-T02-A 1 3.71E+01
Mo JaFS-L14-1314-T03-A 1 1.61E+01
Mo JaFS-L14-1314-T04-A 1 1.32E+01
Mo JaFS-L14-1314-T05-A 1 1.05E+01
Mo JaFS-L14-1314-T06-A 1 6.30E+00
Mo JaFS-L14-1314-T07-A 1 4.60E+00
Mo JaFS-L14-1314-T08-A 1 3.54E+00 E
Mo JaFS-L14-1314-T09-A 1 2.19E+00 E
Mo JaFS-L14-1314-T01-B 1 9.88E+01
Mo JaFS-L14-1314-T02-B 1 4.47E+01
Mo JaFS-L14-1314-T03-B 1 1.91E+01
Mo JaFS-L14-1314-T04-B 1 1.37E+01
Mo JaFS-L14-1314-T05-B 1 1.06E+01
Mo JaFS-L14-1314-T06-B 1 6.81E+00
Mo JaFS-L14-1314-T07-B 1 5.03E+00
Mo JaFS-L14-1314-T08-B 1 2.37E+00 E
Mo JaFS-L14-1314-T09-B 1 1.68E+00 E
Mo JaFS-L14-1314-T01-C 1 9.56E+01
Mo JaFS-L14-1314-T02-C 1 3.22E+01
Mo JaFS-L14-1314-T03-C 1 1.69E+01
Mo JaFS-L14-1314-T04-C 1 1.20E+01
Mo JaFS-L14-1314-T05-C 1 9.65E+00
Mo JaFS-L14-1314-T06-C 1 7.10E+00
Mo JaFS-L14-1314-T07-C 1 3.44E+00 E
Mo JaFS-L14-1314-T08-C 1 2.39E+00 E
Mo JaFS-L14-1314-T09-C 1 1.64E+00 E
Mo JaFS-L14-1314-B01-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.02E+02 2.55 1.20 3.82
3.71E+01 3.13 1.20 3.82
1.61E+01 2.06 1.20 3.82 10000 1000
1.32E+01 9.37 1.20 3.82
1.05E+01 3.09 1.20 3.82
6.30E+00 3.69 1.20 3.82
4.60E+00 2.26 1.20 3.82
3.54E+00 4.97 1.20 3.82
2.19E+00 16.26 1.20 3.82
9.88E+01 2.10 1.20 3.82
4.47E+01 2.05 1.20 3.82
1.91E+01 2.79 1.20 3.82 10000 1000
1.37E+01 3.85 1.20 3.82
1.06E+01 1.86 1.20 3.82
6.81E+00 13.50 1.20 3.82
5.03E+00 7.52 1.20 3.82
2.37E+00 8.25 1.20 3.82
1.68E+00 26.06 1.20 3.82
9.56E+01 2.11 1.20 3.82
3.22E+01 1.96 1.20 3.82
1.69E+01 3.63 1.20 3.82 10000 1000
1.20E+01 5.16 1.20 3.82
9.65E+00 9.52 1.20 3.82
7.10E+00 4.80 1.20 3.82
3.44E+00 12.49 1.20 3.82
2.39E+00 13.38 1.20 3.82
1.64E+00 5.55 1.20 3.82
6.00E-01 11.17 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.07E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-397
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ni JaFS-L14-1314-T01-A 1 7.61E+00
Ni JaFS-L14-1314-T02-A 1 9.00E-01 U1/2
Ni JaFS-L14-1314-T03-A 1 9.00E-01 U1/2
Ni JaFS-L14-1314-T04-A 1 9.00E-01 U1/2
Ni JaFS-L14-1314-T05-A 1 9.00E-01 U1/2
Ni JaFS-L14-1314-T06-A 1 9.00E-01 U1/2
Ni JaFS-L14-1314-T07-A 1 9.00E-01 U1/2
Ni JaFS-L14-1314-T08-A 1 9.00E-01 U1/2
Ni JaFS-L14-1314-T09-A 1 9.00E-01 U1/2
Ni JaFS-L14-1314-T01-B 1 8.47E+00
Ni JaFS-L14-1314-T02-B 1 9.00E-01 U1/2
Ni JaFS-L14-1314-T03-B 1 9.00E-01 U1/2
Ni JaFS-L14-1314-T04-B 1 9.00E-01 U1/2
Ni JaFS-L14-1314-T05-B 1 9.00E-01 U1/2
Ni JaFS-L14-1314-T06-B 1 9.00E-01 U1/2
Ni JaFS-L14-1314-T07-B 1 9.00E-01 U1/2
Ni JaFS-L14-1314-T08-B 1 9.00E-01 U1/2
Ni JaFS-L14-1314-T09-B 1 9.00E-01 U1/2
Ni JaFS-L14-1314-T01-C 1 8.51E+00
Ni JaFS-L14-1314-T02-C 1 9.00E-01 U1/2
Ni JaFS-L14-1314-T03-C 1 9.00E-01 U1/2
Ni JaFS-L14-1314-T04-C 1 9.00E-01 U1/2
Ni JaFS-L14-1314-T05-C 1 9.00E-01 U1/2
Ni JaFS-L14-1314-T06-C 1 9.00E-01 U1/2
Ni JaFS-L14-1314-T07-C 1 9.00E-01 U1/2
Ni JaFS-L14-1314-T08-C 1 9.00E-01 U1/2
Ni JaFS-L14-1314-T09-C 1 9.00E-01 U1/2
Ni JaFS-L14-1314-B01-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.61 E+00 1.22 1.80 5.70
9.00E-01 16.75 1.80 5.70
9.00E-01 32.96 1.80 5.70 10000 1000
9.00E-01 25.15 1.80 5.70
9.00E-01 41.90 1.80 5.70
9.00E-01 25.93 1.80 5.70
9.00E-01 54.38 1.80 5.70
9.00E-01 46.14 1.80 5.70
9.00E-01 8.57 1.80 5.70
8.47E+00 1.59 1.80 5.70
9.00E-01 25.86 1.80 5.70
9.00E-01 47.70 1.80 5.70 10000 1000
9.00E-01 36.15 1.80 5.70
9.00E-01 26.16 1.80 5.70
9.00E-01 9.91 1.80 5.70
9.00E-01 84.83 1.80 5.70
9.00E-01 46.79 1.80 5.70
9.00E-01 28.09 1.80 5.70
8.51 E+00 1.28 1.80 5.70
9.00E-01 47.75 1.80 5.70
9.00E-01 45.07 1.80 5.70 10000 1000
9.00E-01 6.33 1.80 5.70
9.00E-01 7.96 1.80 5.70
9.00E-01 31.99 1.80 5.70
9.00E-01 16.75 1.80 5.70
9.00E-01 27.60 1.80 5.70
9.00E-01 53.83 1.80 5.70
9.00E-01 33.39 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.07E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-398
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
P JaFS-L14-1314-T01-A 1 1.00E+02
P JaFS-L14-1314-T02-A 1 5.95E+01
P JaFS-L14-1314-T03-A 1 6.74E+01
P JaFS-L14-1314-T04-A 1 5.27E+01
P JaFS-L14-1314-T05-A 1 4.27E+01
P JaFS-L14-1314-T06-A 1 4.51E+01
P JaFS-L14-1314-T07-A 1 5.47E+01
P JaFS-L14-1314-T08-A 1 6.51E+01
P JaFS-L14-1314-T09-A 1 9.83E+01
P JaFS-L14-1314-T01-B 1 9.00E+01
P JaFS-L14-1314-T02-B 1 7.64E+01
P JaFS-L14-1314-T03-B 1 6.92E+01
P JaFS-L14-1314-T04-B 1 5.14E+01
P JaFS-L14-1314-T05-B 1 4.52E+01
P JaFS-L14-1314-T06-B 1 2.66E+01
P JaFS-L14-1314-T07-B 1 5.16E+01
P JaFS-L14-1314-T08-B 1 3.72E+01
P JaFS-L14-1314-T09-B 1 7.60E+01
P JaFS-L14-1314-T01-C 1 1.33E+02
P JaFS-L14-1314-T02-C 1 6.06E+01
P JaFS-L14-1314-T03-C 1 5.10E+01
P JaFS-L14-1314-T04-C 1 4.82E+01
P JaFS-L14-1314-T05-C 1 4.71E+01
P JaFS-L14-1314-T06-C 1 3.28E+01
P JaFS-L14-1314-T07-C 1 5.28E+01
P JaFS-L14-1314-T08-C 1 6.70E+01
P JaFS-L14-1314-T09-C 1 9.49E+01
P JaFS-L14-1314-B01-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+02 5.89 3.70 11.80
5.95E+01 2.03 3.70 11.80
6.74E+01 1.76 3.70 11.80 10000 1000
5.27E+01 3.63 3.70 11.80
4.27E+01 1.20 3.70 11.80
4.51E+01 1.16 3.70 11.80
5.47E+01 1.27 3.70 11.80
6.51 E+01 6.47 3.70 11.80
9.83E+01 3.54 3.70 11.80
9.00E+01 18.51 3.70 11.80
7.64E+01 8.48 3.70 11.80
6.92E+01 9.18 3.70 11.80 10000 1000
5.14E+01 0.69 3.70 11.80
4.52E+01 1.62 3.70 11.80
2.66E+01 1.73 3.70 11.80
5.16E+01 3.64 3.70 11.80
3.72E+01 2.09 3.70 11.80
7.60E+01 1.77 3.70 11.80
1.33E+02 9.13 3.70 11.80
6.06E+01 1.18 3.70 11.80
5.10E+01 1.08 3.70 11.80 10000 1000
4.82E+01 2.44 3.70 11.80
4.71E+01 1.13 3.70 11.80
3.28E+01 1.56 3.70 11.80
5.28E+01 4.02 3.70 11.80
6.70E+01 2.38 3.70 11.80
9.49E+01 16.42 3.70 11.80
1.85E+00 8.32 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.26E+03 119% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.19E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.21E+03 116% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-399
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
K JaFS-L14-1314-T01-A 1 6.39E+04
K JaFS-L14-1314-T02-A 1 1.83E+04
K JaFS-L14-1314-T03-A 1 9.90E+03
K JaFS-L14-1314-T04-A 1 9.12E+03
K JaFS-L14-1314-T05-A 1 8.90E+03
K JaFS-L14-1314-T06-A 1 5.53E+03
K JaFS-L14-1314-T07-A 1 4.69E+03
K JaFS-L14-1314-T08-A 1 3.07E+03
K JaFS-L14-1314-T09-A 1 2.89E+03
K JaFS-L14-1314-T01-B 1 6.04E+04
K JaFS-L14-1314-T02-B 1 2.33E+04
K JaFS-L14-1314-T03-B 1 1.15E+04
K JaFS-L14-1314-T04-B 1 9.65E+03
K JaFS-L14-1314-T05-B 1 8.48E+03
K JaFS-L14-1314-T06-B 1 5.70E+03
K JaFS-L14-1314-T07-B 1 4.21E+03
K JaFS-L14-1314-T08-B 1 3.01E+03
K JaFS-L14-1314-T09-B 1 2.31E+03
K JaFS-L14-1314-T01-C 1 5.95E+04
K JaFS-L14-1314-T02-C 1 1.67E+04
K JaFS-L14-1314-T03-C 1 9.45E+03
K JaFS-L14-1314-T04-C 1 8.26E+03
K JaFS-L14-1314-T05-C 1 7.45E+03
K JaFS-L14-1314-T06-C 1 5.13E+03
K JaFS-L14-1314-T07-C 1 3.75E+03
K JaFS-L14-1314-T08-C 1 2.67E+03
K JaFS-L14-1314-T09-C 1 1.84E+03
K JaFS-L14-1314-B01-A 1 5.37E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.39E+04 0.32 1.60 5.09
1.83E+04 1.94 1.60 5.09
9.90E+03 1.13 1.60 5.09 10000 1000
9.12E+03 0.25 1.60 5.09
8.90E+03 0.82 1.60 5.09
5.53E+03 0.57 1.60 5.09
4.69E+03 0.80 1.60 5.09
3.07E+03 1.41 1.60 5.09
2.89E+03 1.44 1.60 5.09
6.04E+04 1.27 1.60 5.09
2.33E+04 0.87 1.60 5.09
1.15E+04 0.43 1.60 5.09 10000 1000
9.65E+03 0.14 1.60 5.09
8.48E+03 5.19 1.60 5.09
5.70E+03 4.92 1.60 5.09
4.21 E+03 0.56 1.60 5.09
3.01 E+03 0.84 1.60 5.09
2.31 E+03 0.61 1.60 5.09
5.95E+04 0.22 1.60 5.09
1.67E+04 1.59 1.60 5.09
9.45E+03 2.30 1.60 5.09 10000 1000
8.26E+03 2.15 1.60 5.09
7.45E+03 1.03 1.60 5.09
5.13E+03 1.58 1.60 5.09
3.75E+03 1.54 1.60 5.09
2.67E+03 0.25 1.60 5.09
1.84E+03 1.70 1.60 5.09
5.37E+01 9.29 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.07E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.23E+04 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-400
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
Se JaFS-L14-1314-T01-A 1 5.80E+01
Se JaFS-L14-1314-T02-A 1 2.26E+01 E
Se JaFS-L14-1314-T03-A 1 1.87E+01 E
Se JaFS-L14-1314-T04-A 1 7.50E+00 U1/2
Se JaFS-L14-1314-T05-A 1 7.50E+00 U1/2
Se JaFS-L14-1314-T06-A 1 7.50E+00 U1/2
Se JaFS-L14-1314-T07-A 1 7.50E+00 U1/2
Se JaFS-L14-1314-T08-A 1 7.50E+00 U1/2
Se JaFS-L14-1314-T09-A 1 7.50E+00 U1/2
Se JaFS-L14-1314-T01-B 1 5.38E+01
Se JaFS-L14-1314-T02-B 1 1.79E+01 E
Se JaFS-L14-1314-T03-B 1 7.50E+00 U1/2
Se JaFS-L14-1314-T04-B 1 7.50E+00 U1/2
Se JaFS-L14-1314-T05-B 1 7.50E+00 U1/2
Se JaFS-L14-1314-T06-B 1 7.50E+00 U1/2
Se JaFS-L14-1314-T07-B 1 7.50E+00 U1/2
Se JaFS-L14-1314-T08-B 1 7.50E+00 U1/2
Se JaFS-L14-1314-T09-B 1 7.50E+00 U1/2
Se JaFS-L14-1314-T01-C 1 5.60E+01
Se JaFS-L14-1314-T02-C 1 2.48E+01 E
Se JaFS-L14-1314-T03-C 1 1.68E+01 E
Se JaFS-L14-1314-T04-C 1 7.50E+00 U1/2
Se JaFS-L14-1314-T05-C 1 7.50E+00 U1/2
Se JaFS-L14-1314-T06-C 1 7.50E+00 U1/2
Se JaFS-L14-1314-T07-C 1 7.50E+00 U1/2
Se JaFS-L14-1314-T08-C 1 7.50E+00 U1/2
Se JaFS-L14-1314-T09-C 1 7.50E+00 U1/2
Se JaFS-L14-1314-B01-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.80E+01 5.64 15.00 47.70
2.26E+01 8.95 15.00 47.70
1.87E+01 3.71 15.00 47.70 10000 1000
7.50E+00 32.80 15.00 47.70
7.50E+00 15.52 15.00 47.70
7.50E+00 16.75 15.00 47.70
7.50E+00 27.86 15.00 47.70
7.50E+00 22.61 15.00 47.70
7.50E+00 25.77 15.00 47.70
5.38E+01 2.41 15.00 47.70
1.79E+01 14.58 15.00 47.70
7.50E+00 10.43 15.00 47.70 10000 1000
7.50E+00 11.39 15.00 47.70
7.50E+00 4.61 15.00 47.70
7.50E+00 27.49 15.00 47.70
7.50E+00 16.07 15.00 47.70
7.50E+00 15.67 15.00 47.70
7.50E+00 16.33 15.00 47.70
5.60E+01 1.27 15.00 47.70
2.48E+01 7.77 15.00 47.70
1.68E+01 24.05 15.00 47.70 10000 1000
7.50E+00 33.08 15.00 47.70
7.50E+00 33.18 15.00 47.70
7.50E+00 35.66 15.00 47.70
7.50E+00 46.96 15.00 47.70
7.50E+00 7.85 15.00 47.70
7.50E+00 21.28 15.00 47.70
7.50E+00 39.44 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.08E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-401
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Si JaFS-L14-1314-T01-A 1 4.42E+03
Si JaFS-L14-1314-T02-A 1 3.77E+03
Si JaFS-L14-1314-T03-A 1 2.55E+03
Si JaFS-L14-1314-T04-A 1 2.00E+03
Si JaFS-L14-1314-T05-A 1 1.90E+03
Si JaFS-L14-1314-T06-A 1 1.99E+03
Si JaFS-L14-1314-T07-A 1 1.78E+03
Si JaFS-L14-1314-T08-A 1 1.76E+03
Si JaFS-L14-1314-T09-A 1 1.52E+03
Si JaFS-L14-1314-T01-B 1 4.75E+03
Si JaFS-L14-1314-T02-B 1 3.80E+03
Si JaFS-L14-1314-T03-B 1 2.55E+03
Si JaFS-L14-1314-T04-B 1 2.12E+03
Si JaFS-L14-1314-T05-B 1 2.07E+03
Si JaFS-L14-1314-T06-B 1 1.82E+03
Si JaFS-L14-1314-T07-B 1 1.87E+03
Si JaFS-L14-1314-T08-B 1 1.64E+03
Si JaFS-L14-1314-T09-B 1 1.59E+03
Si JaFS-L14-1314-T01-C 1 4.97E+03
Si JaFS-L14-1314-T02-C 1 3.66E+03
Si JaFS-L14-1314-T03-C 1 2.63E+03
Si JaFS-L14-1314-T04-C 1 2.21E+03
Si JaFS-L14-1314-T05-C 1 2.05E+03
Si JaFS-L14-1314-T06-C 1 1.94E+03
Si JaFS-L14-1314-T07-C 1 1.89E+03
Si JaFS-L14-1314-T08-C 1 1.81E+03
Si JaFS-L14-1314-T09-C 1 1.66E+03
Si JaFS-L14-1314-B01-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.42E+03 0.45 1.10 3.50
3.77E+03 2.41 1.10 3.50
2.55E+03 1.47 1.10 3.50 10000 1000
2.00E+03 0.68 1.10 3.50
1.90E+03 1.75 1.10 3.50
1.99E+03 0.78 1.10 3.50
1.78E+03 0.82 1.10 3.50
1.76E+03 1.00 1.10 3.50
1.52E+03 1.42 1.10 3.50
4.75E+03 1.30 1.10 3.50
3.80E+03 0.95 1.10 3.50
2.55E+03 1.17 1.10 3.50 10000 1000
2.12E+03 0.69 1.10 3.50
2.07E+03 7.90 1.10 3.50
1.82E+03 4.00 1.10 3.50
1.87E+03 1.19 1.10 3.50
1.64E+03 0.93 1.10 3.50
1.59E+03 0.66 1.10 3.50
4.97E+03 0.43 1.10 3.50
3.66E+03 2.35 1.10 3.50
2.63E+03 1.13 1.10 3.50 10000 1000
2.21 E+03 2.82 1.10 3.50
2.05E+03 1.18 1.10 3.50
1.94E+03 1.59 1.10 3.50
1.89E+03 1.38 1.10 3.50
1.81 E+03 1.78 1.10 3.50
1.66E+03 1.66 1.10 3.50
5.50E-01 8.24 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.45E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.42E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.55E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-402
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Na JaFS-L14-1314-T01-A 1 1.84E+05
Na JaFS-L14-1314-T02-A 1 6.54E+04
Na JaFS-L14-1314-T03-A 1 2.93E+04
Na JaFS-L14-1314-T04-A 1 1.20E+04
Na JaFS-L14-1314-T05-A 1 2.93E+03
Na JaFS-L14-1314-T06-A 1 8.57E+02
Na JaFS-L14-1314-T07-A 1 5.24E+02
Na JaFS-L14-1314-T08-A 1 3.87E+02
Na JaFS-L14-1314-T09-A 1 3.52E+02
Na JaFS-L14-1314-T01-B 1 1.79E+05
Na JaFS-L14-1314-T02-B 1 8.05E+04
Na JaFS-L14-1314-T03-B 1 3.44E+04
Na JaFS-L14-1314-T04-B 1 1.35E+04
Na JaFS-L14-1314-T05-B 1 4.00E+03
Na JaFS-L14-1314-T06-B 1 1.03E+03
Na JaFS-L14-1314-T07-B 1 5.35E+02
Na JaFS-L14-1314-T08-B 1 4.03E+02
Na JaFS-L14-1314-T09-B 1 3.22E+02
Na JaFS-L14-1314-T01-C 1 1.83E+05
Na JaFS-L14-1314-T02-C 1 6.05E+04
Na JaFS-L14-1314-T03-C 1 2.66E+04
Na JaFS-L14-1314-T04-C 1 8.61E+03
Na JaFS-L14-1314-T05-C 1 2.25E+03
Na JaFS-L14-1314-T06-C 1 7.79E+02
Na JaFS-L14-1314-T07-C 1 4.61E+02
Na JaFS-L14-1314-T08-C 1 3.55E+02
Na JaFS-L14-1314-T09-C 1 2.62E+02
Na JaFS-L14-1314-B01-A 1 1.25E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.84E+05 0.22 2.50 8.00
6.54E+04 0.31 2.50 8.00
2.93E+04 0.46 2.50 8.00 10000 1000
1.20E+04 0.47 2.50 8.00
2.93E+03 0.55 2.50 8.00
8.57E+02 0.52 2.50 8.00
5.24E+02 0.23 2.50 8.00
3.87E+02 1.27 2.50 8.00
3.52E+02 0.40 2.50 8.00
1.79E+05 0.74 2.50 8.00
8.05E+04 0.52 2.50 8.00
3.44E+04 0.24 2.50 8.00 10000 1000
1.35E+04 0.96 2.50 8.00
4.00E+03 3.05 2.50 8.00
1.03E+03 2.90 2.50 8.00
5.35E+02 0.28 2.50 8.00
4.03E+02 0.09 2.50 8.00
3.22E+02 0.71 2.50 8.00
1.83E+05 0.39 2.50 8.00
6.05E+04 0.16 2.50 8.00
2.66E+04 1.03 2.50 8.00 10000 1000
8.61 E+03 0.71 2.50 8.00
2.25E+03 0.60 2.50 8.00
7.79E+02 0.69 2.50 8.00
4.61 E+02 0.49 2.50 8.00
3.55E+02 0.39 2.50 8.00
2.62E+02 0.64 2.50 8.00
1.25E+00 1.44 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.02E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.52E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.75E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-403
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Sr JaFS-L14-1314-T01-A 1 9.55E+03
Sr JaFS-L14-1314-T02-A 1 1.49E+03
Sr JaFS-L14-1314-T03-A 1 4.10E+02
Sr JaFS-L14-1314-T04-A 1 3.93E+02
Sr JaFS-L14-1314-T05-A 1 4.17E+02
Sr JaFS-L14-1314-T06-A 1 3.39E+02
Sr JaFS-L14-1314-T07-A 1 2.91E+02
Sr JaFS-L14-1314-T08-A 1 2.48E+02
Sr JaFS-L14-1314-T09-A 1 2.18E+02
Sr JaFS-L14-1314-T01-B 1 8.89E+03
Sr JaFS-L14-1314-T02-B 1 2.20E+03
Sr JaFS-L14-1314-T03-B 1 5.21E+02
Sr JaFS-L14-1314-T04-B 1 4.85E+02
Sr JaFS-L14-1314-T05-B 1 4.86E+02
Sr JaFS-L14-1314-T06-B 1 3.85E+02
Sr JaFS-L14-1314-T07-B 1 3.32E+02
Sr JaFS-L14-1314-T08-B 1 2.84E+02
Sr JaFS-L14-1314-T09-B 1 2.57E+02
Sr JaFS-L14-1314-T01-C 1 9.39E+03
Sr JaFS-L14-1314-T02-C 1 1.47E+03
Sr JaFS-L14-1314-T03-C 1 4.25E+02
Sr JaFS-L14-1314-T04-C 1 4.25E+02
Sr JaFS-L14-1314-T05-C 1 4.27E+02
Sr JaFS-L14-1314-T06-C 1 3.37E+02
Sr JaFS-L14-1314-T07-C 1 2.75E+02
Sr JaFS-L14-1314-T08-C 1 2.32E+02
Sr JaFS-L14-1314-T09-C 1 1.89E+02
Sr JaFS-L14-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.55E+03 0.16 1.00 3.18
1.49E+03 2.25 1.00 3.18
4.10E+02 0.83 1.00 3.18 10000 1000
3.93E+02 1.01 1.00 3.18
4.17E+02 1.38 1.00 3.18
3.39E+02 0.67 1.00 3.18
2.91E+02 1.09 1.00 3.18
2.48E+02 1.58 1.00 3.18
2.18E+02 1.38 1.00 3.18
8.89E+03 1.61 1.00 3.18
2.20E+03 0.69 1.00 3.18
5.21E+02 1.25 1.00 3.18 10000 1000
4.85E+02 0.41 1.00 3.18
4.86E+02 5.59 1.00 3.18
3.85E+02 4.51 1.00 3.18
3.32E+02 0.78 1.00 3.18
2.84E+02 0.89 1.00 3.18
2.57E+02 1.62 1.00 3.18
9.39E+03 1.02 1.00 3.18
1.47E+03 0.94 1.00 3.18
4.25E+02 2.30 1.00 3.18 10000 1000
4.25E+02 2.07 1.00 3.18
4.27E+02 1.34 1.00 3.18
3.37E+02 1.50 1.00 3.18
2.75E+02 0.85 1.00 3.18
2.32E+02 0.65 1.00 3.18
1.89E+02 2.25 1.00 3.18
5.00E-01 24.61 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.37E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.44E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.37E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-404
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
S JaFS-L14-1314-T01-A 1 5.88E+05
S JaFS-L14-1314-T02-A 1 7.77E+04
S JaFS-L14-1314-T03-A 1 8.00E+03
S JaFS-L14-1314-T04-A 1 5.21E+03
S JaFS-L14-1314-T05-A 1 3.92E+03
S JaFS-L14-1314-T06-A 1 2.61E+03
S JaFS-L14-1314-T07-A 1 2.17E+03
S JaFS-L14-1314-T08-A 1 1.64E+03
S JaFS-L14-1314-T09-A 1 1.25E+03
S JaFS-L14-1314-T01-B 1 5.63E+05
S JaFS-L14-1314-T02-B 1 7.60E+04
S JaFS-L14-1314-T03-B 1 1.06E+04
S JaFS-L14-1314-T04-B 1 6.61E+03
S JaFS-L14-1314-T05-B 1 4.85E+03
S JaFS-L14-1314-T06-B 1 2.85E+03
S JaFS-L14-1314-T07-B 1 2.36E+03
S JaFS-L14-1314-T08-B 1 1.72E+03
S JaFS-L14-1314-T09-B 1 1.31E+03
S JaFS-L14-1314-T01-C 1 5.79E+05
S JaFS-L14-1314-T02-C 1 7.04E+04
S JaFS-L14-1314-T03-C 1 8.00E+03
S JaFS-L14-1314-T04-C 1 5.02E+03
S JaFS-L14-1314-T05-C 1 4.02E+03
S JaFS-L14-1314-T06-C 1 2.56E+03
S JaFS-L14-1314-T07-C 1 2.04E+03
S JaFS-L14-1314-T08-C 1 1.48E+03
S JaFS-L14-1314-T09-C 1 7.68E+02
S JaFS-L14-1314-B01-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.88E+05 0.18 6.80 21.60
7.77E+04 1.99 6.80 21.60
8.00E+03 1.12 6.80 21.60 10000 1000
5.21E+03 1.14 6.80 21.60
3.92E+03 1.01 6.80 21.60
2.61 E+03 0.77 6.80 21.60
2.17E+03 2.27 6.80 21.60
1.64E+03 1.19 6.80 21.60
1.25E+03 3.07 6.80 21.60
5.63E+05 1.11 6.80 21.60
7.60E+04 1.13 6.80 21.60
1.06E+04 0.70 6.80 21.60 10000 1000
6.61 E+03 0.27 6.80 21.60
4.85E+03 4.63 6.80 21.60
2.85E+03 4.07 6.80 21.60
2.36E+03 2.20 6.80 21.60
1.72E+03 0.30 6.80 21.60
1.31 E+03 0.41 6.80 21.60
5.79E+05 0.17 6.80 21.60
7.04E+04 1.84 6.80 21.60
8.00E+03 1.37 6.80 21.60 10000 1000
5.02E+03 2.51 6.80 21.60
4.02E+03 1.85 6.80 21.60
2.56E+03 0.94 6.80 21.60
2.04E+03 1.62 6.80 21.60
1.48E+03 2.20 6.80 21.60
7.68E+02 1.41 6.80 21.60
3.40E+00 13.39 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.91E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.93E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-405
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Tl JaFS-L14-1314-T01-A 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T02-A 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T03-A 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T04-A 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T05-A 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T06-A 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T07-A 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T08-A 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T09-A 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T01-B 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T02-B 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T03-B 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T04-B 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T05-B 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T06-B 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T07-B 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T08-B 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T09-B 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T01-C 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T02-C 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T03-C 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T04-C 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T05-C 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T06-C 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T07-C 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T08-C 1 2.30E+00 U1/2
Tl JaFS-L14-1314-T09-C 1 2.30E+00 U1/2
Tl JaFS-L14-1314-B01-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 23.93 4.60 14.60
2.30E+00 60.03 4.60 14.60
2.30E+00 8.41 4.60 14.60 10000 1000
2.30E+00 19.87 4.60 14.60
2.30E+00 23.85 4.60 14.60
2.30E+00 24.82 4.60 14.60
2.30E+00 40.55 4.60 14.60
2.30E+00 36.77 4.60 14.60
2.30E+00 41.52 4.60 14.60
2.30E+00 41.19 4.60 14.60
2.30E+00 8.76 4.60 14.60
2.30E+00 29.31 4.60 14.60 10000 1000
2.30E+00 24.81 4.60 14.60
2.30E+00 72.01 4.60 14.60
2.30E+00 41.28 4.60 14.60
2.30E+00 56.46 4.60 14.60
2.30E+00 31.73 4.60 14.60
2.30E+00 76.97 4.60 14.60
2.30E+00 28.10 4.60 14.60
2.30E+00 65.81 4.60 14.60
2.30E+00 52.15 4.60 14.60 10000 1000
2.30E+00 27.58 4.60 14.60
2.30E+00 27.09 4.60 14.60
2.30E+00 35.31 4.60 14.60
2.30E+00 17.19 4.60 14.60
2.30E+00 46.86 4.60 14.60
2.30E+00 47.17 4.60 14.60
2.30E+00 51.87 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.50E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.92E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-406
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Ti JaFS-L14-1314-T01-A 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T02-A 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T03-A 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T04-A 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T05-A 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T06-A 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T07-A 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T08-A 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T09-A 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T01-B 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T02-B 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T03-B 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T04-B 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T05-B 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T06-B 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T07-B 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T08-B 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T09-B 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T01-C 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T02-C 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T03-C 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T04-C 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T05-C 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T06-C 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T07-C 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T08-C 1 1.00E+00 U1/2
Ti JaFS-L14-1314-T09-C 1 1.00E+00 U1/2
Ti JaFS-L14-1314-B01-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 23.20 2.00 6.40
1.00E+00 27.83 2.00 6.40
1.00E+00 30.56 2.00 6.40 10000 1000
1.00E+00 22.62 2.00 6.40
1.00E+00 10.27 2.00 6.40
1.00E+00 23.38 2.00 6.40
1.00E+00 20.47 2.00 6.40
1.00E+00 20.27 2.00 6.40
1.00E+00 32.38 2.00 6.40
1.00E+00 33.14 2.00 6.40
1.00E+00 23.20 2.00 6.40
1.00E+00 30.89 2.00 6.40 10000 1000
1.00E+00 37.15 2.00 6.40
1.00E+00 17.39 2.00 6.40
1.00E+00 70.48 2.00 6.40
1.00E+00 19.97 2.00 6.40
1.00E+00 34.48 2.00 6.40
1.00E+00 14.74 2.00 6.40
1.00E+00 31.18 2.00 6.40
1.00E+00 26.07 2.00 6.40
1.00E+00 47.13 2.00 6.40 10000 1000
1.00E+00 23.46 2.00 6.40
1.00E+00 37.16 2.00 6.40
1.00E+00 16.14 2.00 6.40
1.00E+00 20.66 2.00 6.40
1.00E+00 12.20 2.00 6.40
1.00E+00 30.02 2.00 6.40
1.00E+00 8.37 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.22E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.66E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.80E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-407
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
V JaFS-L14-1314-T01-A 1 1.77E+01
V JaFS-L14-1314-T02-A 1 3.56E+00 E
V JaFS-L14-1314-T03-A 1 1.73E+00 E
V JaFS-L14-1314-T04-A 1 7.50E-01 U1/2
V JaFS-L14-1314-T05-A 1 7.50E-01 U1/2
V JaFS-L14-1314-T06-A 1 7.50E-01 U1/2
V JaFS-L14-1314-T07-A 1 7.50E-01 U1/2
V JaFS-L14-1314-T08-A 1 7.50E-01 U1/2
V JaFS-L14-1314-T09-A 1 7.50E-01 U1/2
V JaFS-L14-1314-T01-B 1 1.71E+01
V JaFS-L14-1314-T02-B 1 5.22E+00
V JaFS-L14-1314-T03-B 1 1.50E+00 E
V JaFS-L14-1314-T04-B 1 7.50E-01 U1/2
V JaFS-L14-1314-T05-B 1 7.50E-01 U1/2
V JaFS-L14-1314-T06-B 1 7.50E-01 U1/2
V JaFS-L14-1314-T07-B 1 7.50E-01 U1/2
V JaFS-L14-1314-T08-B 1 7.50E-01 U1/2
V JaFS-L14-1314-T09-B 1 7.50E-01 U1/2
V JaFS-L14-1314-T01-C 1 1.65E+01
V JaFS-L14-1314-T02-C 1 3.01E+00 E
V JaFS-L14-1314-T03-C 1 7.50E-01 U1/2
V JaFS-L14-1314-T04-C 1 7.50E-01 U1/2
V JaFS-L14-1314-T05-C 1 7.50E-01 U1/2
V JaFS-L14-1314-T06-C 1 7.50E-01 U1/2
V JaFS-L14-1314-T07-C 1 7.50E-01 U1/2
V JaFS-L14-1314-T08-C 1 7.50E-01 U1/2
V JaFS-L14-1314-T09-C 1 7.50E-01 U1/2
V JaFS-L14-1314-B01-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.77E+01 3.75 1.50 4.77
3.56E+00 19.30 1.50 4.77
1.73E+00 32.35 1.50 4.77 10000 1000
7.50E-01 4.29 1.50 4.77
7.50E-01 35.01 1.50 4.77
7.50E-01 43.79 1.50 4.77
7.50E-01 51.30 1.50 4.77
7.50E-01 16.01 1.50 4.77
7.50E-01 15.82 1.50 4.77
1.71E+01 4.03 1.50 4.77
5.22E+00 4.77 1.50 4.77
1.50E+00 26.14 1.50 4.77 10000 1000
7.50E-01 23.95 1.50 4.77
7.50E-01 4.19 1.50 4.77
7.50E-01 20.13 1.50 4.77
7.50E-01 61.50 1.50 4.77
7.50E-01 35.13 1.50 4.77
7.50E-01 59.38 1.50 4.77
1.65E+01 3.25 1.50 4.77
3.01E+00 12.90 1.50 4.77
7.50E-01 39.70 1.50 4.77 10000 1000
7.50E-01 51.84 1.50 4.77
7.50E-01 22.12 1.50 4.77
7.50E-01 13.73 1.50 4.77
7.50E-01 15.38 1.50 4.77
7.50E-01 22.12 1.50 4.77
7.50E-01 48.95 1.50 4.77
7.50E-01 40.96 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.47E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.65E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-408
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Zn JaFS-L14-1314-T01-A 1 1.12E+03
Zn JaFS-L14-1314-T02-A 1 3.39E+02
Zn JaFS-L14-1314-T03-A 1 1.38E+02
Zn JaFS-L14-1314-T04-A 1 9.17E+01
Zn JaFS-L14-1314-T05-A 1 8.06E+01
Zn JaFS-L14-1314-T06-A 1 4.76E+01
Zn JaFS-L14-1314-T07-A 1 2.87E+01
Zn JaFS-L14-1314-T08-A 1 1.46E+01
Zn JaFS-L14-1314-T09-A 1 6.30E+00
Zn JaFS-L14-1314-T01-B 1 1.61E+03
Zn JaFS-L14-1314-T02-B 1 4.00E+02
Zn JaFS-L14-1314-T03-B 1 2.12E+02
Zn JaFS-L14-1314-T04-B 1 1.34E+02
Zn JaFS-L14-1314-T05-B 1 1.11E+02
Zn JaFS-L14-1314-T06-B 1 6.34E+01
Zn JaFS-L14-1314-T07-B 1 4.04E+01
Zn JaFS-L14-1314-T08-B 1 2.27E+01
Zn JaFS-L14-1314-T09-B 1 9.23E+00
Zn JaFS-L14-1314-T01-C 1 1.48E+03
Zn JaFS-L14-1314-T02-C 1 3.84E+02
Zn JaFS-L14-1314-T03-C 1 1.50E+02
Zn JaFS-L14-1314-T04-C 1 9.66E+01
Zn JaFS-L14-1314-T05-C 1 8.60E+01
Zn JaFS-L14-1314-T06-C 1 4.66E+01
Zn JaFS-L14-1314-T07-C 1 2.78E+01
Zn JaFS-L14-1314-T08-C 1 1.24E+01
Zn JaFS-L14-1314-T09-C 1 4.72E+00
Zn JaFS-L14-1314-B01-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.12E+03 0.48 1.00 3.18
3.39E+02 3.76 1.00 3.18
1.38E+02 0.42 1.00 3.18 10000 1000
9.17E+01 0.26 1.00 3.18
8.06E+01 1.82 1.00 3.18
4.76E+01 0.54 1.00 3.18
2.87E+01 0.21 1.00 3.18
1.46E+01 2.23 1.00 3.18
6.30E+00 0.92 1.00 3.18
1.61E+03 0.72 1.00 3.18
4.00E+02 0.86 1.00 3.18
2.12E+02 0.71 1.00 3.18 10000 1000
1.34E+02 0.12 1.00 3.18
1.11E+02 5.17 1.00 3.18
6.34E+01 3.88 1.00 3.18
4.04E+01 1.28 1.00 3.18
2.27E+01 1.12 1.00 3.18
9.23E+00 0.95 1.00 3.18
1.48E+03 0.17 1.00 3.18
3.84E+02 1.14 1.00 3.18
1.50E+02 2.69 1.00 3.18 10000 1000
9.66E+01 2.10 1.00 3.18
8.60E+01 1.56 1.00 3.18
4.66E+01 1.94 1.00 3.18
2.78E+01 3.31 1.00 3.18
1.24E+01 0.57 1.00 3.18
4.72E+00 1.80 1.00 3.18
5.00E-01 2.44 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.12E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.13E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/12/12 2:46 PM EPA Interlab L14 1314 JaFS
1/12/12 2:48 PM EPA Interlab L14 1314 JaFS
1/12/12 2:49 PM EPA Interlab L14 1314 JaFS
1/12/12 2:51 PM EPA Interlab L14 1314 JaFS
1/12/12 2:53 PM EPA Interlab L14 1314 JaFS
1/12/12 2:54 PM EPA Interlab L14 1314 JaFS
1/12/12 2:56 PM EPA Interlab L14 1314 JaFS
1/12/12 2:58 PM EPA Interlab L14 1314 JaFS
1/12/12 2:59 PM EPA Interlab L14 1314 JaFS
1/12/12 3:06 PM EPA Interlab L14 1314 JaFS
1/12/12 3:08 PM EPA Interlab L14 1314 JaFS
1/12/12 3:09 PM EPA Interlab L14 1314 JaFS
1/12/12 3:11 PM EPA Interlab L14 1314 JaFS
1/12/12 3:13 PM EPA Interlab L14 1314 JaFS
1/12/12 3:14 PM EPA Interlab L14 1314 JaFS
1/12/12 3:16 PM EPA Interlab L14 1314 JaFS
1/12/12 3:18 PM EPA Interlab L14 1314 JaFS
1/12/12 3:19 PM EPA Interlab L14 1314 JaFS
1/12/12 3:21 PM EPA Interlab L14 1314 JaFS
1/12/12 3:22 PM EPA Interlab L14 1314 JaFS
1/12/12 3:24 PM EPA Interlab L14 1314 JaFS
1/12/12 3:26 PM EPA Interlab L14 1314 JaFS
1/12/12 3:27 PM EPA Interlab L14 1314 JaFS
1/12/12 3:29 PM EPA Interlab L14 1314 JaFS
1/12/12 3:31 PM EPA Interlab L14 1314 JaFS
1/12/12 3:32 PM EPA Interlab L14 1314 JaFS
1/12/12 3:34 PM EPA Interlab L14 1314 JaFS
1/12/12 2:43 PM EPA Interlab L14 1314 JaFS
1-409
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1314:
Dilution Sample
Element Sample ID Factor Cone. Qualifier
I I I M9/L I
Al JaFS-LRef-1314-T01-A 1 8.20E+01
Al JaFS-LRef-1314-T02-A 1 6.12E+01
Al JaFS-LRef-1314-T03-A 1 3.30E+01
Al JaFS-LRef-1314-T04-A 1 2.04E+01
Al JaFS-LRef-1314-T05-A 1 1.77E+01
Al JaFS-LRef-1314-T06-A 1 1.79E+01
Al JaFS-LRef-1314-T07-A 1 1.59E+01
Al JaFS-LRef-1314-T08-A 1 1.56E+01
Al JaFS-LRef-1314-T09-A 1 1.44E+01
Al JaFS-LRef-1314-T01-B 1 7.32E+01
Al JaFS-LRef-1314-T02-B 1 6.28E+01
Al JaFS-LRef-1314-T03-B 1 3.12E+01
Al JaFS-LRef-1314-T04-B 1 2.17E+01
Al JaFS-LRef-1314-T05-B 1 1.85E+01
Al JaFS-LRef-1314-T06-B 1 1.75E+01
Al JaFS-LRef-1314-T07-B 1 1.68E+01
Al JaFS-LRef-1314-T08-B 1 1.55E+01
Al JaFS-LRef-1314-T09-B 1 1.52E+01
Al JaFS-LRef-1314-T01-C 1 8.05E+01
Al JaFS-LRef-1314-T02-C 1 6.15E+01
Al JaFS-LRef-1314-T03-C 1 3.28E+01
Al JaFS-LRef-1314-T04-C 1 2.02E+01
Al JaFS-LRef-1314-T05-C 1 1.86E+01
Al JaFS-LRef-1314-T06-C 1 1.78E+01
Al JaFS-LRef-1314-T07-C 1 1.63E+01
Al JaFS-LRef-1314-T08-C 1 1.53E+01
Al JaFS-LRef-1314-T09-C 1 1.56E+01
Al JaFS-LRef-1314-B01-A 1 5.00E-01 U1/2
Al JaFS-LRef-1314-B02-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.20E+01 1.23 1.00 3.18
6.12E+01 3.45 1.00 3.18
3.30E+01 2.44 1.00 3.18 10000 1000
2.04E+01 1.07 1.00 3.18
1.77E+01 0.69 1.00 3.18
1.79E+01 5.35 1.00 3.18
1.59E+01 12.43 1.00 3.18
1.56E+01 3.93 1.00 3.18
1.44E+01 1.80 1.00 3.18
7.32E+01 2.39 1.00 3.18
6.28E+01 0.65 1.00 3.18
3.12E+01 4.91 1.00 3.18 10000 1000
2.17E+01 1.02 1.00 3.18
1.85E+01 1.42 1.00 3.18
1.75E+01 2.04 1.00 3.18
1.68E+01 1.93 1.00 3.18
1.55E+01 2.13 1.00 3.18
1.52E+01 1.82 1.00 3.18
8.05E+01 1.52 1.00 3.18
6.15E+01 0.67 1.00 3.18
3.28E+01 1.77 1.00 3.18 10000 1000
2.02E+01 5.27 1.00 3.18
1.86E+01 3.67 1.00 3.18
1.78E+01 1.81 1.00 3.18
1.63E+01 1.45 1.00 3.18
1.53E+01 1.36 1.00 3.18
1.56E+01 3.24 1.00 3.18
5.00E-01 11.88 1.00 3.18
5.00E-01 23.81 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.35E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.26E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.18E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :28 PM EPA Interlab LRef 1314 JaFS
1-410
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Sb JaFS-LRef-1314-T01-A 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T02-A 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T03-A 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T04-A 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T05-A 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T06-A 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T07-A 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T08-A 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T09-A 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T01-B 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T02-B 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T03-B 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T04-B 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T05-B 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T06-B 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T07-B 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T08-B 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T09-B 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T01-C 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T02-C 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T03-C 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T04-C 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T05-C 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T06-C 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T07-C 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T08-C 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T09-C 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-B01-A 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-B02-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.75E+00 12.93 7.50 23.90
3.75E+00 32.35 7.50 23.90
3.75E+00 30.31 7.50 23.90 10000 1000
3.75E+00 32.31 7.50 23.90
3.75E+00 20.88 7.50 23.90
3.75E+00 29.41 7.50 23.90
3.75E+00 14.73 7.50 23.90
3.75E+00 16.67 7.50 23.90
3.75E+00 28.85 7.50 23.90
3.75E+00 55.73 7.50 23.90
3.75E+00 31.57 7.50 23.90
3.75E+00 33.21 7.50 23.90 10000 1000
3.75E+00 26.27 7.50 23.90
3.75E+00 30.54 7.50 23.90
3.75E+00 19.61 7.50 23.90
3.75E+00 40.18 7.50 23.90
3.75E+00 27.96 7.50 23.90
3.75E+00 39.74 7.50 23.90
3.75E+00 84.65 7.50 23.90
3.75E+00 14.10 7.50 23.90
3.75E+00 24.99 7.50 23.90 10000 1000
3.75E+00 21.56 7.50 23.90
3.75E+00 30.49 7.50 23.90
3.75E+00 31.84 7.50 23.90
3.75E+00 10.06 7.50 23.90
3.75E+00 13.53 7.50 23.90
3.75E+00 20.14 7.50 23.90
3.75E+00 76.65 7.50 23.90
3.75E+00 38.92 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.97E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.00E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.15E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 131 4 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/11 1:28 PM EPA Interlab LRef 1314 JaFS
1-411
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
As JaFS-LRef-1314-T01-A 1 5.50E+00 U1/2
As JaFS-LRef-1314-T02-A 1 5.50E+00 U1/2
As JaFS-LRef-1314-T03-A 1 5.50E+00 U1/2
As JaFS-LRef-1314-T04-A 1 5.50E+00 U1/2
As JaFS-LRef-1314-T05-A 1 5.50E+00 U1/2
As JaFS-LRef-1314-T06-A 1 5.50E+00 U1/2
As JaFS-LRef-1314-T07-A 1 5.50E+00 U1/2
As JaFS-LRef-1314-T08-A 1 5.50E+00 U1/2
As JaFS-LRef-1314-T09-A 1 5.50E+00 U1/2
As JaFS-LRef-1314-T01-B 1 5.50E+00 U1/2
As JaFS-LRef-1314-T02-B 1 5.50E+00 U1/2
As JaFS-LRef-1314-T03-B 1 5.50E+00 U1/2
As JaFS-LRef-1314-T04-B 1 5.50E+00 U1/2
As JaFS-LRef-1314-T05-B 1 5.50E+00 U1/2
As JaFS-LRef-1314-T06-B 1 5.50E+00 U1/2
As JaFS-LRef-1314-T07-B 1 5.50E+00 U1/2
As JaFS-LRef-1314-T08-B 1 5.50E+00 U1/2
As JaFS-LRef-1314-T09-B 1 5.50E+00 U1/2
As JaFS-LRef-1314-T01-C 1 5.50E+00 U1/2
As JaFS-LRef-1314-T02-C 1 5.50E+00 U1/2
As JaFS-LRef-1314-T03-C 1 5.50E+00 U1/2
As JaFS-LRef-1314-T04-C 1 5.50E+00 U1/2
As JaFS-LRef-1314-T05-C 1 5.50E+00 U1/2
As JaFS-LRef-1314-T06-C 1 5.50E+00 U1/2
As JaFS-LRef-1314-T07-C 1 5.50E+00 U1/2
As JaFS-LRef-1314-T08-C 1 5.50E+00 U1/2
As JaFS-LRef-1314-T09-C 1 5.50E+00 U1/2
As JaFS-LRef-1314-B01-A 1 5.50E+00 U1/2
As JaFS-LRef-1314-B02-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.50E+00 7.26 11.00 35.00
5.50E+00 16.11 11.00 35.00
5.50E+00 34.25 11.00 35.00 10000 1000
5.50E+00 5.15 11.00 35.00
5.50E+00 54.87 11.00 35.00
5.50E+00 20.85 11.00 35.00
5.50E+00 25.94 11.00 35.00
5.50E+00 8.59 11.00 35.00
5.50E+00 54.59 11.00 35.00
5.50E+00 32.63 11.00 35.00
5.50E+00 21.01 11.00 35.00
5.50E+00 39.10 11.00 35.00 10000 1000
5.50E+00 39.18 11.00 35.00
5.50E+00 52.33 11.00 35.00
5.50E+00 9.70 11.00 35.00
5.50E+00 10.40 11.00 35.00
5.50E+00 21.46 11.00 35.00
5.50E+00 21.36 11.00 35.00
5.50E+00 10.26 11.00 35.00
5.50E+00 15.29 11.00 35.00
5.50E+00 15.09 11.00 35.00 10000 1000
5.50E+00 42.12 11.00 35.00
5.50E+00 12.76 11.00 35.00
5.50E+00 26.85 11.00 35.00
5.50E+00 5.76 11.00 35.00
5.50E+00 5.10 11.00 35.00
5.50E+00 42.27 11.00 35.00
5.50E+00 52.27 11.00 35.00
5.50E+00 32.30 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.70E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.51 E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.43E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 131 4 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/11 1:28 PM EPA Interlab LRef 1314 JaFS
1-412
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
B JaFS-LRef-1314-T01-A 1 1.82E+05
B JaFS-LRef-1314-T02-A 1 6.69E+04
B JaFS-LRef-1314-T03-A 1 2.17E+04
B JaFS-LRef-1314-T04-A 1 9.32E+03
B JaFS-LRef-1314-T05-A 1 5.39E+03
B JaFS-LRef-1314-T06-A 1 3.14E+03
B JaFS-LRef-1314-T07-A 1 2.48E+03
B JaFS-LRef-1314-T08-A 1 1.11E+03
B JaFS-LRef-1314-T09-A 1 7.69E+02
B JaFS-LRef-1314-T01-B 1 1.79E+05
B JaFS-LRef-1314-T02-B 1 6.41E+04
B JaFS-LRef-1314-T03-B 1 2.12E+04
B JaFS-LRef-1314-T04-B 1 9.22E+03
B JaFS-LRef-1314-T05-B 1 5.20E+03
B JaFS-LRef-1314-T06-B 1 3.23E+03
B JaFS-LRef-1314-T07-B 1 2.29E+03
B JaFS-LRef-1314-T08-B 1 1.08E+03
B JaFS-LRef-1314-T09-B 1 8.26E+02
B JaFS-LRef-1314-T01-C 1 1.83E+05
B JaFS-LRef-1314-T02-C 1 6.53E+04
B JaFS-LRef-1314-T03-C 1 2.20E+04
B JaFS-LRef-1314-T04-C 1 9.18E+03
B JaFS-LRef-1314-T05-C 1 4.93E+03
B JaFS-LRef-1314-T06-C 1 3.69E+03
B JaFS-LRef-1314-T07-C 1 2.09E+03
B JaFS-LRef-1314-T08-C 1 9.83E+02
B JaFS-LRef-1314-T09-C 1 7.09E+02
B JaFS-LRef-1314-B01-A 1 5.00E-01 U1/2
B JaFS-LRef-1314-B02-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.82E+05 1.29 1.00 3.18
6.69E+04 2.14 1.00 3.18
2.17E+04 2.11 1.00 3.18 10000 1000
9.32E+03 0.37 1.00 3.18
5.39E+03 1.31 1.00 3.18
3.14E+03 0.62 1.00 3.18
2.48E+03 1.34 1.00 3.18
1.11E+03 0.93 1.00 3.18
7.69E+02 1.34 1.00 3.18
1.79E+05 0.43 1.00 3.18
6.41E+04 1.28 1.00 3.18
2.12E+04 6.35 1.00 3.18 10000 1000
9.22E+03 6.49 1.00 3.18
5.20E+03 1.12 1.00 3.18
3.23E+03 2.19 1.00 3.18
2.29E+03 1.80 1.00 3.18
1.08E+03 0.82 1.00 3.18
8.26E+02 2.65 1.00 3.18
1.83E+05 1.84 1.00 3.18
6.53E+04 1.09 1.00 3.18
2.20E+04 2.00 1.00 3.18 10000 1000
9.18E+03 2.78 1.00 3.18
4.93E+03 0.95 1.00 3.18
3.69E+03 0.24 1.00 3.18
2.09E+03 1.70 1.00 3.18
9.83E+02 2.09 1.00 3.18
7.09E+02 2.97 1.00 3.18
5.00E-01 1.91 1.00 3.18
5.00E-01 9.80 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.26E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.21E+04 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.29E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/11 1:28 PM EPA Interlab LRef 1314 JaFS
1-413
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Ba JaFS-LRef-1314-T01-A 1 1.26E+02
Ba JaFS-LRef-1314-T02-A 1 8.56E+01
Ba JaFS-LRef-1314-T03-A 1 5.41E+01
Ba JaFS-LRef-1314-T04-A 1 3.51E+01
Ba JaFS-LRef-1314-T05-A 1 3.23E+01
Ba JaFS-LRef-1314-T06-A 1 2.42E+01
Ba JaFS-LRef-1314-T07-A 1 1.42E+01
Ba JaFS-LRef-1314-T08-A 1 1.55E+01
Ba JaFS-LRef-1314-T09-A 1 1.40E+01
Ba JaFS-LRef-1314-T01-B 1 1.13E+02
Ba JaFS-LRef-1314-T02-B 1 7.42E+01
Ba JaFS-LRef-1314-T03-B 1 5.58E+01
Ba JaFS-LRef-1314-T04-B 1 3.68E+01
Ba JaFS-LRef-1314-T05-B 1 3.49E+01
Ba JaFS-LRef-1314-T06-B 1 2.23E+01
Ba JaFS-LRef-1314-T07-B 1 1.28E+01
Ba JaFS-LRef-1314-T08-B 1 1.32E+01
Ba JaFS-LRef-1314-T09-B 1 1.14E+01
Ba JaFS-LRef-1314-T01-C 1 1.18E+02
Ba JaFS-LRef-1314-T02-C 1 8.71E+01
Ba JaFS-LRef-1314-T03-C 1 5.97E+01
Ba JaFS-LRef-1314-T04-C 1 4.16E+01
Ba JaFS-LRef-1314-T05-C 1 3.32E+01
Ba JaFS-LRef-1314-T06-C 1 2.38E+01
Ba JaFS-LRef-1314-T07-C 1 1.57E+01
Ba JaFS-LRef-1314-T08-C 1 1.39E+01
Ba JaFS-LRef-1314-T09-C 1 1.22E+01
Ba JaFS-LRef-1314-B01-A 1 5.00E-01 U1/2
Ba JaFS-LRef-1314-B02-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.26E+02 0.39 1.00 3.18
8.56E+01 1.95 1.00 3.18
5.41E+01 1.01 1.00 3.18 10000 1000
3.51E+01 1.27 1.00 3.18
3.23E+01 0.93 1.00 3.18
2.42E+01 1.41 1.00 3.18
1.42E+01 2.76 1.00 3.18
1.55E+01 0.88 1.00 3.18
1.40E+01 1.55 1.00 3.18
1.13E+02 1.18 1.00 3.18
7.42E+01 1.11 1.00 3.18
5.58E+01 2.44 1.00 3.18 10000 1000
3.68E+01 2.80 1.00 3.18
3.49E+01 1.59 1.00 3.18
2.23E+01 1.19 1.00 3.18
1.28E+01 1.37 1.00 3.18
1.32E+01 1.02 1.00 3.18
1.14E+01 1.82 1.00 3.18
1.18E+02 1.17 1.00 3.18
8.71E+01 0.90 1.00 3.18
5.97E+01 0.27 1.00 3.18 10000 1000
4.16E+01 0.86 1.00 3.18
3.32E+01 1.23 1.00 3.18
2.38E+01 0.37 1.00 3.18
1.57E+01 0.72 1.00 3.18
1.39E+01 1.94 1.00 3.18
1.22E+01 2.47 1.00 3.18
5.00E-01 16.98 1.00 3.18
5.00E-01 1.52 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.61 E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.76E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.90E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/11 1:28 PM EPA Interlab LRef 1314 JaFS
1-414
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Be JaFS-LRef-1314-T01-A 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T02-A 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T03-A 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T04-A 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T05-A 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T06-A 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T07-A 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T08-A 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T09-A 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T01-B 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T02-B 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T03-B 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T04-B 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T05-B 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T06-B 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T07-B 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T08-B 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T09-B 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T01-C 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T02-C 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T03-C 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T04-C 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T05-C 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T06-C 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T07-C 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T08-C 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T09-C 1 9.50E-01 U1/2
Be JaFS-LRef-1314-B01-A 1 9.50E-01 U1/2
Be JaFS-LRef-1314-B02-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 28.98 1.90 6.00
9.50E-01 7.98 1.90 6.00
9.50E-01 39.81 1.90 6.00 10000 1000
9.50E-01 10.91 1.90 6.00
9.50E-01 21.70 1.90 6.00
9.50E-01 18.65 1.90 6.00
9.50E-01 27.15 1.90 6.00
9.50E-01 21.29 1.90 6.00
9.50E-01 48.82 1.90 6.00
9.50E-01 14.23 1.90 6.00
9.50E-01 15.93 1.90 6.00
9.50E-01 63.80 1.90 6.00 10000 1000
9.50E-01 41.90 1.90 6.00
9.50E-01 27.78 1.90 6.00
9.50E-01 15.28 1.90 6.00
9.50E-01 27.05 1.90 6.00
9.50E-01 32.89 1.90 6.00
9.50E-01 9.57 1.90 6.00
9.50E-01 107.21 1.90 6.00
9.50E-01 33.20 1.90 6.00
9.50E-01 6.98 1.90 6.00 10000 1000
9.50E-01 6.27 1.90 6.00
9.50E-01 50.09 1.90 6.00
9.50E-01 75.72 1.90 6.00
9.50E-01 76.31 1.90 6.00
9.50E-01 47.07 1.90 6.00
9.50E-01 28.58 1.90 6.00
9.50E-01 37.12 1.90 6.00
9.50E-01 46.67 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.35E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.25E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.38E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 131 4 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/11 1:28 PM EPA Interlab LRef 1314 JaFS
1-415
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cd JaFS-LRef-1314-T01-A 1 1.74E+01
Cd JaFS-LRef-1314-T02-A 1 4.84E+00 E
Cd JaFS-LRef-1314-T03-A 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T04-A 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T05-A 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T06-A 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T07-A 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T08-A 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T09-A 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T01-B 1 1.60E+01
Cd JaFS-LRef-1314-T02-B 1 3.95E+00 E
Cd JaFS-LRef-1314-T03-B 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T04-B 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T05-B 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T06-B 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T07-B 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T08-B 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T09-B 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T01-C 1 1.54E+01
Cd JaFS-LRef-1314-T02-C 1 4.52E+00 E
Cd JaFS-LRef-1314-T03-C 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T04-C 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T05-C 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T06-C 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T07-C 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T08-C 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T09-C 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-B01-A 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-B02-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.74E+01 2.76 2.20 7.00
4.84E+00 6.10 2.20 7.00
1.10E+00 7.48 2.20 7.00 10000 1000
1.10E+00 6.07 2.20 7.00
1.10E+00 7.48 2.20 7.00
1.10E+00 21.08 2.20 7.00
1.10E+00 5.91 2.20 7.00
1.10E+00 33.99 2.20 7.00
1.10E+00 30.64 2.20 7.00
1.60E+01 1.47 2.20 7.00
3.95E+00 2.34 2.20 7.00
1.10E+00 2.75 2.20 7.00 10000 1000
1.10E+00 9.91 2.20 7.00
1.10E+00 17.33 2.20 7.00
1.10E+00 16.47 2.20 7.00
1.10E+00 30.82 2.20 7.00
1.10E+00 25.11 2.20 7.00
1.10E+00 21.87 2.20 7.00
1.54E+01 57.33 2.20 7.00
4.52E+00 12.19 2.20 7.00
1.10E+00 16.77 2.20 7.00 10000 1000
1.10E+00 29.60 2.20 7.00
1.10E+00 44.99 2.20 7.00
1.10E+00 21.81 2.20 7.00
1.10E+00 25.41 2.20 7.00
1.10E+00 32.24 2.20 7.00
1.10E+00 7.87 2.20 7.00
1.10E+00 17.81 2.20 7.00
1.10E+00 54.75 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.84E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.81E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.61 E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :28 PM EPA Interlab LRef 1314 JaFS
1-416
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Ca JaFS-LRef-1314-T01-A 1 3.14E+05
Ca JaFS-LRef-1314-T02-A 1 4.10E+04
Ca JaFS-LRef-1314-T03-A 1 2.02E+04
Ca JaFS-LRef-1314-T04-A 1 1.85E+04
Ca JaFS-LRef-1314-T05-A 1 1.61E+04
Ca JaFS-LRef-1314-T06-A 1 1.43E+04
Ca JaFS-LRef-1314-T07-A 1 1.10E+04
Ca JaFS-LRef-1314-T08-A 1 9.83E+03
Ca JaFS-LRef-1314-T09-A 1 9.37E+03
Ca JaFS-LRef-1314-T01-B 1 3.10E+05
Ca JaFS-LRef-1314-T02-B 1 3.95E+04
Ca JaFS-LRef-1314-T03-B 1 1.85E+04
Ca JaFS-LRef-1314-T04-B 1 1.92E+04
Ca JaFS-LRef-1314-T05-B 1 1.71E+04
Ca JaFS-LRef-1314-T06-B 1 1.38E+04
Ca JaFS-LRef-1314-T07-B 1 1.08E+04
Ca JaFS-LRef-1314-T08-B 1 9.97E+03
Ca JaFS-LRef-1314-T09-B 1 9.14E+03
Ca JaFS-LRef-1314-T01-C 1 3.08E+05
Ca JaFS-LRef-1314-T02-C 1 4.26E+04
Ca JaFS-LRef-1314-T03-C 1 2.08E+04
Ca JaFS-LRef-1314-T04-C 1 1.95E+04
Ca JaFS-LRef-1314-T05-C 1 1.90E+04
Ca JaFS-LRef-1314-T06-C 1 1.48E+04
Ca JaFS-LRef-1314-T07-C 1 1.16E+04
Ca JaFS-LRef-1314-T08-C 1 9.89E+03
Ca JaFS-LRef-1314-T09-C 1 9.03E+03
Ca JaFS-LRef-1314-B01-A 1 1.30E+00 U1/2
Ca JaFS-LRef-1314-B02-A 1 1.30E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.14E+05 0.32 2.60 8.30
4.10E+04 1.76 2.60 8.30
2.02E+04 1.15 2.60 8.30 10000 1000
1.85E+04 1.22 2.60 8.30
1.61E+04 0.77 2.60 8.30
1.43E+04 1.77 2.60 8.30
1.10E+04 7.45 2.60 8.30
9.83E+03 0.61 2.60 8.30
9.37E+03 0.60 2.60 8.30
3.10E+05 0.62 2.60 8.30
3.95E+04 1.37 2.60 8.30
1.85E+04 3.09 2.60 8.30 10000 1000
1.92E+04 0.69 2.60 8.30
1.71E+04 1.31 2.60 8.30
1.38E+04 1.25 2.60 8.30
1.08E+04 1.52 2.60 8.30
9.97E+03 1.41 2.60 8.30
9.14E+03 1.04 2.60 8.30
3.08E+05 1.14 2.60 8.30
4.26E+04 1.42 2.60 8.30
2.08E+04 0.54 2.60 8.30 10000 1000
1.95E+04 0.82 2.60 8.30
1.90E+04 1.85 2.60 8.30
1.48E+04 0.86 2.60 8.30
1.16E+04 0.30 2.60 8.30
9.89E+03 2.01 2.60 8.30
9.03E+03 2.86 2.60 8.30
1.30E+00 13.70 2.60 8.30
1.30E+00 3.89 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.12E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.94E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.18E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :28 PM EPA Interlab LRef 1314 JaFS
1-417
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cr JaFS-LRef-1314-T01-A 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T02-A 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T03-A 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T04-A 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T05-A 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T06-A 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T07-A 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T08-A 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T09-A 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T01-B 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T02-B 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T03-B 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T04-B 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T05-B 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T06-B 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T07-B 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T08-B 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T09-B 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T01-C 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T02-C 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T03-C 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T04-C 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T05-C 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T06-C 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T07-C 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T08-C 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T09-C 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-B01-A 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-B02-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 22.84 1.20 3.82
6.00E-01 44.70 1.20 3.82
6.00E-01 26.72 1.20 3.82 10000 1000
6.00E-01 7.60 1.20 3.82
6.00E-01 38.89 1.20 3.82
6.00E-01 34.10 1.20 3.82
6.00E-01 20.47 1.20 3.82
6.00E-01 28.17 1.20 3.82
6.00E-01 26.48 1.20 3.82
6.00E-01 39.44 1.20 3.82
6.00E-01 7.11 1.20 3.82
6.00E-01 59.63 1.20 3.82 10000 1000
6.00E-01 15.02 1.20 3.82
6.00E-01 58.11 1.20 3.82
6.00E-01 32.51 1.20 3.82
6.00E-01 18.03 1.20 3.82
6.00E-01 32.99 1.20 3.82
6.00E-01 18.14 1.20 3.82
6.00E-01 41.75 1.20 3.82
6.00E-01 39.17 1.20 3.82
6.00E-01 36.45 1.20 3.82 10000 1000
6.00E-01 10.65 1.20 3.82
6.00E-01 35.76 1.20 3.82
6.00E-01 62.89 1.20 3.82
6.00E-01 22.91 1.20 3.82
6.00E-01 15.62 1.20 3.82
6.00E-01 21.84 1.20 3.82
6.00E-01 24.63 1.20 3.82
6.00E-01 56.71 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.04E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.04E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.18E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 131 4 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/11 1:28 PM EPA Interlab LRef 1314 JaFS
1-418
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Co JaFS-LRef-1314-T01-A 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T02-A 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T03-A 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T04-A 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T05-A 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T06-A 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T07-A 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T08-A 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T09-A 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T01-B 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T02-B 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T03-B 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T04-B 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T05-B 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T06-B 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T07-B 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T08-B 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T09-B 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T01-C 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T02-C 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T03-C 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T04-C 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T05-C 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T06-C 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T07-C 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T08-C 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T09-C 1 9.00E-01 U1/2
Co JaFS-LRef-1314-B01-A 1 9.00E-01 U1/2
Co JaFS-LRef-1314-B02-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 51.97 1.80 5.72
9.00E-01 51.32 1.80 5.72
9.00E-01 35.04 1.80 5.72 10000 1000
9.00E-01 56.84 1.80 5.72
9.00E-01 38.18 1.80 5.72
9.00E-01 19.50 1.80 5.72
9.00E-01 60.92 1.80 5.72
9.00E-01 35.87 1.80 5.72
9.00E-01 28.64 1.80 5.72
9.00E-01 12.65 1.80 5.72
9.00E-01 43.60 1.80 5.72
9.00E-01 88.97 1.80 5.72 10000 1000
9.00E-01 61.67 1.80 5.72
9.00E-01 59.73 1.80 5.72
9.00E-01 41.96 1.80 5.72
9.00E-01 30.30 1.80 5.72
9.00E-01 10.58 1.80 5.72
9.00E-01 60.69 1.80 5.72
9.00E-01 44.88 1.80 5.72
9.00E-01 46.81 1.80 5.72
9.00E-01 30.82 1.80 5.72 10000 1000
9.00E-01 63.45 1.80 5.72
9.00E-01 77.37 1.80 5.72
9.00E-01 16.48 1.80 5.72
9.00E-01 65.98 1.80 5.72
9.00E-01 24.20 1.80 5.72
9.00E-01 61.98 1.80 5.72
9.00E-01 69.53 1.80 5.72
9.00E-01 25.68 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.15E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.14E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.28E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :28 PM EPA Interlab LRef 1314 JaFS
1-419
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Cu JaFS-LRef-1314-T01-A 1 1.18E+03
Cu JaFS-LRef-1314-T02-A 1 7.81 E+02
Cu JaFS-LRef-1314-T03-A 1 4.56E+02
Cu JaFS-LRef-1314-T04-A 1 3.03E+02
Cu JaFS-LRef-1314-T05-A 1 1.51 E+02
Cu JaFS-LRef-1314-T06-A 1 1.09E+02
Cu JaFS-LRef-1314-T07-A 1 8.36E+01
Cu JaFS-LRef-1314-T08-A 1 6.58E+01
Cu JaFS-LRef-1314-T09-A 1 5.49E+01
Cu JaFS-LRef-1314-T01-B 1 1.26E+03
Cu JaFS-LRef-1314-T02-B 1 8.54E+02
Cu JaFS-LRef-1314-T03-B 1 5.33E+02
Cu JaFS-LRef-1314-T04-B 1 2.99E+02
Cu JaFS-LRef-1314-T05-B 1 1.81 E+02
Cu JaFS-LRef-1314-T06-B 1 1.05E+02
Cu JaFS-LRef-1314-T07-B 1 9.16E+01
Cu JaFS-LRef-1314-T08-B 1 7.70E+01
Cu JaFS-LRef-1314-T09-B 1 5.03E+01
Cu JaFS-LRef-1314-T01-C 1 1.27E+03
Cu JaFS-LRef-1314-T02-C 1 8.61 E+02
Cu JaFS-LRef-1314-T03-C 1 5.09E+02
Cu JaFS-LRef-1314-T04-C 1 2.94E+02
Cu JaFS-LRef-1314-T05-C 1 1.73E+02
Cu JaFS-LRef-1314-T06-C 1 1.04E+02
Cu JaFS-LRef-1314-T07-C 1 9.18E+01
Cu JaFS-LRef-1314-T08-C 1 7.04E+01
Cu JaFS-LRef-1314-T09-C 1 4.95E+01
Cu JaFS-LRef-1314-B01-A 1 1.85E+00 U1/2
Cu JaFS-LRef-1314-B02-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.18E+03 0.63 3.70 11.80
7.81 E+02 1.66 3.70 11.80
4.56E+02 0.60 3.70 11.80 10000 1000
3.03E+02 2.16 3.70 11.80
1.51 E+02 0.86 3.70 11.80
1.09E+02 3.25 3.70 11.80
8.36E+01 5.22 3.70 11.80
6.58E+01 0.78 3.70 11.80
5.49E+01 2.06 3.70 11.80
1.26E+03 1.06 3.70 11.80
8.54E+02 1.09 3.70 11.80
5.33E+02 1.69 3.70 11.80 10000 1000
2.99E+02 0.91 3.70 11.80
1.81 E+02 1.10 3.70 11.80
1.05E+02 2.39 3.70 11.80
9.16E+01 2.38 3.70 11.80
7.70E+01 1.34 3.70 11.80
5.03E+01 3.03 3.70 11.80
1.27E+03 1.57 3.70 11.80
8.61E+02 1.17 3.70 11.80
5.09E+02 0.97 3.70 11.80 10000 1000
2.94E+02 7.10 3.70 11.80
1.73E+02 1.89 3.70 11.80
1.04E+02 0.80 3.70 11.80
9.18E+01 1.52 3.70 11.80
7.04E+01 2.11 3.70 11.80
4.95E+01 2.13 3.70 11.80
1.85E+00 41.35 3.70 11.80
1.85E+00 30.96 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.36E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.49E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.45E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :28 PM EPA Interlab LRef 1314 JaFS
1-420
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Fe JaFS-LRef-1314-T01-A 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T02-A 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T03-A 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T04-A 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T05-A 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T06-A 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T07-A 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T08-A 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T09-A 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T01-B 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T02-B 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T03-B 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T04-B 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T05-B 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T06-B 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T07-B 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T08-B 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T09-B 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T01-C 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T02-C 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T03-C 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T04-C 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T05-C 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T06-C 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T07-C 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T08-C 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T09-C 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-B01-A 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-B02-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 2.76 2.00 6.40
1.00E+00 6.50 2.00 6.40
1.00E+00 15.68 2.00 6.40 10000 1000
1.00E+00 30.96 2.00 6.40
1.00E+00 12.73 2.00 6.40
1.00E+00 3.81 2.00 6.40
1.00E+00 4.84 2.00 6.40
1.00E+00 32.98 2.00 6.40
1.00E+00 15.75 2.00 6.40
1.00E+00 1.10 2.00 6.40
1.00E+00 8.92 2.00 6.40
1.00E+00 6.54 2.00 6.40 10000 1000
1.00E+00 38.77 2.00 6.40
1.00E+00 26.90 2.00 6.40
1.00E+00 19.43 2.00 6.40
1.00E+00 10.21 2.00 6.40
1.00E+00 7.25 2.00 6.40
1.00E+00 11.02 2.00 6.40
1.00E+00 36.33 2.00 6.40
1.00E+00 5.06 2.00 6.40
1.00E+00 3.41 2.00 6.40 10000 1000
1.00E+00 36.42 2.00 6.40
1.00E+00 10.21 2.00 6.40
1.00E+00 11.35 2.00 6.40
1.00E+00 20.63 2.00 6.40
1.00E+00 48.80 2.00 6.40
1.00E+00 7.60 2.00 6.40
1.00E+00 29.10 2.00 6.40
1.00E+00 22.04 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.12E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.13E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.27E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :28 PM EPA Interlab LRef 1314 JaFS
1-421
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Pb JaFS-LRef-1314-T01-A 1 1.02E+02
Pb JaFS-LRef-1314-T02-A 1 1.21E+02
Pb JaFS-LRef-1314-T03-A 1 9.97E+01
Pb JaFS-LRef-1314-T04-A 1 8.41E+01
Pb JaFS-LRef-1314-T05-A 1 6.75E+01
Pb JaFS-LRef-1314-T06-A 1 5.38E+01
Pb JaFS-LRef-1314-T07-A 1 4.98E+01
Pb JaFS-LRef-1314-T08-A 1 3.45E+01
Pb JaFS-LRef-1314-T09-A 1 2.58E+01
Pb JaFS-LRef-1314-T01-B 1 1.01E+02
Pb JaFS-LRef-1314-T02-B 1 1.15E+02
Pb JaFS-LRef-1314-T03-B 1 8.59E+01
Pb JaFS-LRef-1314-T04-B 1 8.03E+01
Pb JaFS-LRef-1314-T05-B 1 6.41 E+01
Pb JaFS-LRef-1314-T06-B 1 5.83E+01
Pb JaFS-LRef-1314-T07-B 1 4.80E+01
Pb JaFS-LRef-1314-T08-B 1 3.22E+01
Pb JaFS-LRef-1314-T09-B 1 2.45E+01
Pb JaFS-LRef-1314-T01-C 1 1.12E+02
Pb JaFS-LRef-1314-T02-C 1 1.24E+02
Pb JaFS-LRef-1314-T03-C 1 9.14E+01
Pb JaFS-LRef-1314-T04-C 1 8.27E+01
Pb JaFS-LRef-1314-T05-C 1 7.02E+01
Pb JaFS-LRef-1314-T06-C 1 5.44E+01
Pb JaFS-LRef-1314-T07-C 1 4.68E+01
Pb JaFS-LRef-1314-T08-C 1 3.45E+01
Pb JaFS-LRef-1314-T09-C 1 2.66E+01
Pb JaFS-LRef-1314-B01-A 1 3.40E+00 U1/2
Pb JaFS-LRef-1314-B02-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.02E+02 2.44 6.80 21.60
1.21E+02 3.34 6.80 21.60
9.97E+01 1.53 6.80 21.60 10000 1000
8.41E+01 2.10 6.80 21.60
6.75E+01 4.28 6.80 21.60
5.38E+01 1.82 6.80 21.60
4.98E+01 9.11 6.80 21.60
3.45E+01 7.84 6.80 21.60
2.58E+01 2.12 6.80 21.60
1.01E+02 0.67 6.80 21.60
1.15E+02 2.83 6.80 21.60
8.59E+01 1.85 6.80 21.60 10000 1000
8.03E+01 3.01 6.80 21.60
6.41E+01 5.58 6.80 21.60
5.83E+01 1.18 6.80 21.60
4.80E+01 2.64 6.80 21.60
3.22E+01 7.07 6.80 21.60
2.45E+01 5.86 6.80 21.60
1.12E+02 5.49 6.80 21.60
1.24E+02 1.90 6.80 21.60
9.14E+01 8.10 6.80 21.60 10000 1000
8.27E+01 3.93 6.80 21.60
7.02E+01 8.15 6.80 21.60
5.44E+01 1.53 6.80 21.60
4.68E+01 5.25 6.80 21.60
3.45E+01 6.85 6.80 21.60
2.66E+01 9.13 6.80 21.60
3.40E+00 20.68 6.80 21.60
3.40E+00 39.99 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.07E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/11 1:28 PM EPA Interlab LRef 1314 JaFS
1-422
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
Li JaFS-LRef-1314-T01-A 1 7.94E+01
Li JaFS-LRef-1314-T02-A 1 1.20E+01
Li JaFS-LRef-1314-T03-A 1 2.99E+00 E
Li JaFS-LRef-1314-T04-A 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T05-A 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T06-A 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T07-A 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T08-A 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T09-A 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T01-B 1 8.01 E+01
Li JaFS-LRef-1314-T02-B 1 1.38E+01
Li JaFS-LRef-1314-T03-B 1 3.01E+00 E
Li JaFS-LRef-1314-T04-B 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T05-B 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T06-B 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T07-B 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T08-B 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T09-B 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T01-C 1 7.65E+01
Li JaFS-LRef-1314-T02-C 1 1.23E+01
Li JaFS-LRef-1314-T03-C 1 2.94E+00 E
Li JaFS-LRef-1314-T04-C 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T05-C 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T06-C 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T07-C 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T08-C 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T09-C 1 9.50E-01 U1/2
Li JaFS-LRef-1314-B01-A 1 9.50E-01 U1/2
Li JaFS-LRef-1314-B02-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.94E+01 4.25 1.90 6.00
1.20E+01 3.36 1.90 6.00
2.99E+00 10.32 1.90 6.00 10000 1000
9.50E-01 25.77 1.90 6.00
9.50E-01 41.67 1.90 6.00
9.50E-01 21.35 1.90 6.00
9.50E-01 57.27 1.90 6.00
9.50E-01 13.84 1.90 6.00
9.50E-01 23.20 1.90 6.00
8.01 E+01 1.46 1.90 6.00
1.38E+01 12.75 1.90 6.00
3.01E+00 9.79 1.90 6.00 10000 1000
9.50E-01 41.93 1.90 6.00
9.50E-01 77.35 1.90 6.00
9.50E-01 56.01 1.90 6.00
9.50E-01 44.19 1.90 6.00
9.50E-01 27.24 1.90 6.00
9.50E-01 22.49 1.90 6.00
7.65E+01 5.17 1.90 6.00
1.23E+01 8.13 1.90 6.00
2.94E+00 17.94 1.90 6.00 10000 1000
9.50E-01 84.69 1.90 6.00
9.50E-01 42.74 1.90 6.00
9.50E-01 13.74 1.90 6.00
9.50E-01 14.41 1.90 6.00
9.50E-01 30.98 1.90 6.00
9.50E-01 55.85 1.90 6.00
9.50E-01 5.25 1.90 6.00
9.50E-01 22.65 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.77E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.53E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.71E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :28 PM EPA Interlab LRef 1314 JaFS
1-423
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Mn JaFS-LRef-1314-T01-A 1 2.71E+02
Mn JaFS-LRef-1314-T02-A 1 3.57E+01
Mn JaFS-LRef-1314-T03-A 1 2.58E+01
Mn JaFS-LRef-1314-T04-A 1 1.46E+01
Mn JaFS-LRef-1314-T05-A 1 1.16E+01
Mn JaFS-LRef-1314-T06-A 1 8.90E+00
Mn JaFS-LRef-1314-T07-A 1 7.99E+00
Mn JaFS-LRef-1314-T08-A 1 7.58E+00
Mn JaFS-LRef-1314-T09-A 1 5.69E+00 E
Mn JaFS-LRef-1314-T01-B 1 2.56E+02
Mn JaFS-LRef-1314-T02-B 1 3.64E+01
Mn JaFS-LRef-1314-T03-B 1 2.61E+01
Mn JaFS-LRef-1314-T04-B 1 1.93E+01
Mn JaFS-LRef-1314-T05-B 1 1.04E+01
Mn JaFS-LRef-1314-T06-B 1 9.24E+00
Mn JaFS-LRef-1314-T07-B 1 7.50E+00
Mn JaFS-LRef-1314-T08-B 1 7.76E+00
Mn JaFS-LRef-1314-T09-B 1 6.02E+00 E
Mn JaFS-LRef-1314-T01-C 1 2.57E+02
Mn JaFS-LRef-1314-T02-C 1 2.93E+01
Mn JaFS-LRef-1314-T03-C 1 1.96E+01
Mn JaFS-LRef-1314-T04-C 1 1.59E+01
Mn JaFS-LRef-1314-T05-C 1 1.14E+01
Mn JaFS-LRef-1314-T06-C 1 8.95E+00
Mn JaFS-LRef-1314-T07-C 1 8.39E+00
Mn JaFS-LRef-1314-T08-C 1 6.59E+00
Mn JaFS-LRef-1314-T09-C 1 5.81E+00 E
Mn JaFS-LRef-1314-B01-A 1 1.00E+00 U1/2
Mn JaFS-LRef-1314-B02-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.71E+02 1.10 2.00 6.40
3.57E+01 2.02 2.00 6.40
2.58E+01 0.88 2.00 6.40 10000 1000
1.46E+01 0.48 2.00 6.40
1.16E+01 0.86 2.00 6.40
8.90E+00 1.59 2.00 6.40
7.99E+00 6.07 2.00 6.40
7.58E+00 1.17 2.00 6.40
5.69E+00 13.54 2.00 6.40
2.56E+02 0.95 2.00 6.40
3.64E+01 1.17 2.00 6.40
2.61E+01 2.29 2.00 6.40 10000 1000
1.93E+01 2.29 2.00 6.40
1.04E+01 1.31 2.00 6.40
9.24E+00 1.00 2.00 6.40
7.50E+00 1.44 2.00 6.40
7.76E+00 1.04 2.00 6.40
6.02E+00 11.27 2.00 6.40
2.57E+02 2.52 2.00 6.40
2.93E+01 1.76 2.00 6.40
1.96E+01 0.25 2.00 6.40 10000 1000
1.59E+01 7.14 2.00 6.40
1.14E+01 2.28 2.00 6.40
8.95E+00 0.86 2.00 6.40
8.39E+00 0.95 2.00 6.40
6.59E+00 0.93 2.00 6.40
5.81E+00 2.20 2.00 6.40
1.00E+00 8.62 2.00 6.40
1.00E+00 11.69 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.88E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.92E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.86E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :28 PM EPA Interlab LRef 1314 JaFS
1-424
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Mg JaFS-LRef-1314-T01-A 1 5.70E+04
Mg JaFS-LRef-1314-T02-A 1 7.21E+03
Mg JaFS-LRef-1314-T03-A 1 3.79E+03
Mg JaFS-LRef-1314-T04-A 1 3.36E+03
Mg JaFS-LRef-1314-T05-A 1 2.89E+03
Mg JaFS-LRef-1314-T06-A 1 2.11E+03
Mg JaFS-LRef-1314-T07-A 1 1.50E+03
Mg JaFS-LRef-1314-T08-A 1 1.20E+03
Mg JaFS-LRef-1314-T09-A 1 1.21E+03
Mg JaFS-LRef-1314-T01-B 1 5.75E+04
Mg JaFS-LRef-1314-T02-B 1 6.86E+03
Mg JaFS-LRef-1314-T03-B 1 3.19E+03
Mg JaFS-LRef-1314-T04-B 1 3.05E+03
Mg JaFS-LRef-1314-T05-B 1 2.73E+03
Mg JaFS-LRef-1314-T06-B 1 2.12E+03
Mg JaFS-LRef-1314-T07-B 1 1.48E+03
Mg JaFS-LRef-1314-T08-B 1 1.23E+03
Mg JaFS-LRef-1314-T09-B 1 1.14E+03
Mg JaFS-LRef-1314-T01-C 1 5.77E+04
Mg JaFS-LRef-1314-T02-C 1 6.94E+03
Mg JaFS-LRef-1314-T03-C 1 3.54E+03
Mg JaFS-LRef-1314-T04-C 1 3.13E+03
Mg JaFS-LRef-1314-T05-C 1 3.04E+03
Mg JaFS-LRef-1314-T06-C 1 2.17E+03
Mg JaFS-LRef-1314-T07-C 1 1.50E+03
Mg JaFS-LRef-1314-T08-C 1 1.07E+03
Mg JaFS-LRef-1314-T09-C 1 1.38E+03
Mg JaFS-LRef-1314-B01-A 1 5.00E-01 U1/2
Mg JaFS-LRef-1314-B02-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.70E+04 0.59 1.00 3.18
7.21E+03 1.69 1.00 3.18
3.79E+03 1.35 1.00 3.18 10000 1000
3.36E+03 0.32 1.00 3.18
2.89E+03 0.96 1.00 3.18
2.11E+03 1.27 1.00 3.18
1.50E+03 1.62 1.00 3.18
1.20E+03 1.35 1.00 3.18
1.21E+03 1.35 1.00 3.18
5.75E+04 1.41 1.00 3.18
6.86E+03 2.28 1.00 3.18
3.19E+03 4.08 1.00 3.18 10000 1000
3.05E+03 1.03 1.00 3.18
2.73E+03 1.51 1.00 3.18
2.12E+03 0.96 1.00 3.18
1.48E+03 0.89 1.00 3.18
1.23E+03 1.25 1.00 3.18
1.14E+03 0.88 1.00 3.18
5.77E+04 1.15 1.00 3.18
6.94E+03 2.14 1.00 3.18
3.54E+03 0.51 1.00 3.18 10000 1000
3.13E+03 1.61 1.00 3.18
3.04E+03 3.15 1.00 3.18
2.17E+03 1.01 1.00 3.18
1.50E+03 0.71 1.00 3.18
1.07E+03 1.53 1.00 3.18
1.38E+03 2.78 1.00 3.18
5.00E-01 40.34 1.00 3.18
5.00E-01 40.53 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.70E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.10E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.51 E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/11 1:28 PM EPA Interlab LRef 1314 JaFS
1-425
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Mo JaFS-LRef-1314-T01-A 1 1.26E+02
Mo JaFS-LRef-1314-T02-A 1 5.69E+01
Mo JaFS-LRef-1314-T03-A 1 1.56E+01
Mo JaFS-LRef-1314-T04-A 1 1.21E+01
Mo JaFS-LRef-1314-T05-A 1 9.34E+00
Mo JaFS-LRef-1314-T06-A 1 5.69E+00
Mo JaFS-LRef-1314-T07-A 1 3.91E+00
Mo JaFS-LRef-1314-T08-A 1 4.28E+00
Mo JaFS-LRef-1314-T09-A 1 3.94E+00
Mo JaFS-LRef-1314-T01-B 1 1.45E+02
Mo JaFS-LRef-1314-T02-B 1 5.81E+01
Mo JaFS-LRef-1314-T03-B 1 1.41E+01
Mo JaFS-LRef-1314-T04-B 1 1.16E+01
Mo JaFS-LRef-1314-T05-B 1 8.85E+00
Mo JaFS-LRef-1314-T06-B 1 4.24E+00
Mo JaFS-LRef-1314-T07-B 1 3.88E+00
Mo JaFS-LRef-1314-T08-B 1 3.64E+00 E
Mo JaFS-LRef-1314-T09-B 1 3.54E+00 E
Mo JaFS-LRef-1314-T01-C 1 1.25E+02
Mo JaFS-LRef-1314-T02-C 1 5.96E+01
Mo JaFS-LRef-1314-T03-C 1 1.93E+01
Mo JaFS-LRef-1314-T04-C 1 1.35E+01
Mo JaFS-LRef-1314-T05-C 1 1.09E+01
Mo JaFS-LRef-1314-T06-C 1 6.02E+00
Mo JaFS-LRef-1314-T07-C 1 3.88E+00
Mo JaFS-LRef-1314-T08-C 1 3.56E+00 E
Mo JaFS-LRef-1314-T09-C 1 3.61E+00 E
Mo JaFS-LRef-1314-B01-A 1 6.00E-01 U1/2
Mo JaFS-LRef-1314-B02-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.26E+02 0.80 1.20 3.82
5.69E+01 4.79 1.20 3.82
1.56E+01 1.41 1.20 3.82 10000 1000
1.21E+01 4.61 1.20 3.82
9.34E+00 7.54 1.20 3.82
5.69E+00 1.35 1.20 3.82
3.91E+00 1.11 1.20 3.82
4.28E+00 5.47 1.20 3.82
3.94E+00 13.59 1.20 3.82
1.45E+02 1.54 1.20 3.82
5.81E+01 1.58 1.20 3.82
1.41E+01 3.62 1.20 3.82 10000 1000
1.16E+01 4.19 1.20 3.82
8.85E+00 1.19 1.20 3.82
4.24E+00 3.84 1.20 3.82
3.88E+00 2.04 1.20 3.82
3.64E+00 7.54 1.20 3.82
3.54E+00 4.94 1.20 3.82
1.25E+02 10.35 1.20 3.82
5.96E+01 2.74 1.20 3.82
1.93E+01 0.95 1.20 3.82 10000 1000
1.35E+01 0.99 1.20 3.82
1.09E+01 0.88 1.20 3.82
6.02E+00 9.71 1.20 3.82
3.88E+00 3.75 1.20 3.82
3.56E+00 8.74 1.20 3.82
3.61E+00 16.57 1.20 3.82
6.00E-01 17.78 1.20 3.82
6.00E-01 33.67 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.77E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.78E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.97E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :28 PM EPA Interlab LRef 1314 JaFS
1-426
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ni JaFS-LRef-1314-T01-A 1 1.05E+01
Ni JaFS-LRef-1314-T02-A 1 6.66E+00
Ni JaFS-LRef-1314-T03-A 1 2.49E+00 E
Ni JaFS-LRef-1314-T04-A 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T05-A 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T06-A 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T07-A 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T08-A 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T09-A 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T01-B 1 9.19E+00
Ni JaFS-LRef-1314-T02-B 1 7.12E+00
Ni JaFS-LRef-1314-T03-B 1 3.08E+00 E
Ni JaFS-LRef-1314-T04-B 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T05-B 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T06-B 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T07-B 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T08-B 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T09-B 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T01-C 1 9.19E+00
Ni JaFS-LRef-1314-T02-C 1 5.68E+00 E
Ni JaFS-LRef-1314-T03-C 1 2.19E+00 E
Ni JaFS-LRef-1314-T04-C 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T05-C 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T06-C 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T07-C 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T08-C 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T09-C 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-B01-A 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-B02-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.05E+01 7.88 1.80 5.70
6.66E+00 1.76 1.80 5.70
2.49E+00 3.45 1.80 5.70 10000 1000
9.00E-01 32.23 1.80 5.70
9.00E-01 57.57 1.80 5.70
9.00E-01 50.45 1.80 5.70
9.00E-01 35.98 1.80 5.70
9.00E-01 14.11 1.80 5.70
9.00E-01 110.10 1.80 5.70
9.19E+00 4.98 1.80 5.70
7.12E+00 9.36 1.80 5.70
3.08E+00 37.29 1.80 5.70 10000 1000
9.00E-01 26.03 1.80 5.70
9.00E-01 13.50 1.80 5.70
9.00E-01 39.67 1.80 5.70
9.00E-01 25.19 1.80 5.70
9.00E-01 19.61 1.80 5.70
9.00E-01 42.19 1.80 5.70
9.19E+00 7.43 1.80 5.70
5.68E+00 4.77 1.80 5.70
2.19E+00 2.19 1.80 5.70 10000 1000
9.00E-01 53.37 1.80 5.70
9.00E-01 32.43 1.80 5.70
9.00E-01 13.06 1.80 5.70
9.00E-01 15.89 1.80 5.70
9.00E-01 60.03 1.80 5.70
9.00E-01 39.43 1.80 5.70
9.00E-01 60.14 1.80 5.70
9.00E-01 31.86 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.70E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.70E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.83E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :28 PM EPA Interlab LRef 1314 JaFS
1-427
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
P JaFS-LRef-1314-T01-A 1 6.64E+01
P JaFS-LRef-1314-T02-A 1 6.02E+01
P JaFS-LRef-1314-T03-A 1 3.56E+01
P JaFS-LRef-1314-T04-A 1 2.92E+01
P JaFS-LRef-1314-T05-A 1 2.83E+01
P JaFS-LRef-1314-T06-A 1 2.11E+01
P JaFS-LRef-1314-T07-A 1 2.24E+01
P JaFS-LRef-1314-T08-A 1 2.84E+01
P JaFS-LRef-1314-T09-A 1 3.07E+01
P JaFS-LRef-1314-T01-B 1 6.99E+01
P JaFS-LRef-1314-T02-B 1 5.98E+01
P JaFS-LRef-1314-T03-B 1 2.87E+01
P JaFS-LRef-1314-T04-B 1 2.52E+01
P JaFS-LRef-1314-T05-B 1 2.14E+01
P JaFS-LRef-1314-T06-B 1 2.54E+01
P JaFS-LRef-1314-T07-B 1 2.44E+01
P JaFS-LRef-1314-T08-B 1 2.61E+01
P JaFS-LRef-1314-T09-B 1 2.80E+01
P JaFS-LRef-1314-T01-C 1 6.99E+01
P JaFS-LRef-1314-T02-C 1 5.67E+01
P JaFS-LRef-1314-T03-C 1 3.46E+01
P JaFS-LRef-1314-T04-C 1 2.77E+01
P JaFS-LRef-1314-T05-C 1 2.52E+01
P JaFS-LRef-1314-T06-C 1 1.94E+01
P JaFS-LRef-1314-T07-C 1 2.51E+01
P JaFS-LRef-1314-T08-C 1 2.40E+01
P JaFS-LRef-1314-T09-C 1 2.97E+01
P JaFS-LRef-1314-B01-A 1 1.85E+00 U1/2
P JaFS-LRef-1314-B02-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.64E+01 2.32 3.70 11.80
6.02E+01 1.18 3.70 11.80
3.56E+01 14.76 3.70 11.80 10000 1000
2.92E+01 2.00 3.70 11.80
2.83E+01 5.23 3.70 11.80
2.11E+01 4.30 3.70 11.80
2.24E+01 6.97 3.70 11.80
2.84E+01 1.33 3.70 11.80
3.07E+01 7.58 3.70 11.80
6.99E+01 2.60 3.70 11.80
5.98E+01 4.09 3.70 11.80
2.87E+01 1.89 3.70 11.80 10000 1000
2.52E+01 4.66 3.70 11.80
2.14E+01 15.87 3.70 11.80
2.54E+01 2.66 3.70 11.80
2.44E+01 6.39 3.70 11.80
2.61E+01 3.04 3.70 11.80
2.80E+01 1.37 3.70 11.80
6.99E+01 5.05 3.70 11.80
5.67E+01 3.72 3.70 11.80
3.46E+01 5.78 3.70 11.80 10000 1000
2.77E+01 3.40 3.70 11.80
2.52E+01 6.00 3.70 11.80
1.94E+01 9.89 3.70 11.80
2.51E+01 1.54 3.70 11.80
2.40E+01 2.55 3.70 11.80
2.97E+01 1.58 3.70 11.80
1.85E+00 5.49 3.70 11.80
1.85E+00 39.94 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.65E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.60E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.79E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/11 1:28 PM EPA Interlab LRef 1314 JaFS
1-428
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
K JaFS-LRef-1314-T01-A 1 5.14E+04
K JaFS-LRef-1314-T02-A 1 2.36E+04
K JaFS-LRef-1314-T03-A 1 1.33E+04
K JaFS-LRef-1314-T04-A 1 1.09E+04
K JaFS-LRef-1314-T05-A 1 8.68E+03
K JaFS-LRef-1314-T06-A 1 5.58E+03
K JaFS-LRef-1314-T07-A 1 3.79E+03
K JaFS-LRef-1314-T08-A 1 2.59E+03
K JaFS-LRef-1314-T09-A 1 1.76E+03
K JaFS-LRef-1314-T01-B 1 5.52E+04
K JaFS-LRef-1314-T02-B 1 1.90E+04
K JaFS-LRef-1314-T03-B 1 1.18E+04
K JaFS-LRef-1314-T04-B 1 1.07E+04
K JaFS-LRef-1314-T05-B 1 8.60E+03
K JaFS-LRef-1314-T06-B 1 5.64E+03
K JaFS-LRef-1314-T07-B 1 3.89E+03
K JaFS-LRef-1314-T08-B 1 2.83E+03
K JaFS-LRef-1314-T09-B 1 1.77E+03
K JaFS-LRef-1314-T01-C 1 5.76E+04
K JaFS-LRef-1314-T02-C 1 2.13E+04
K JaFS-LRef-1314-T03-C 1 1.27E+04
K JaFS-LRef-1314-T04-C 1 1.18E+04
K JaFS-LRef-1314-T05-C 1 9.25E+03
K JaFS-LRef-1314-T06-C 1 5.70E+03
K JaFS-LRef-1314-T07-C 1 3.47E+03
K JaFS-LRef-1314-T08-C 1 2.44E+03
K JaFS-LRef-1314-T09-C 1 1.90E+03
K JaFS-LRef-1314-B01-A 1 1.21E+01
K JaFS-LRef-1314-B02-A 1 1.53E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.14E+04 0.29 1.60 5.09
2.36E+04 1.68 1.60 5.09
1.33E+04 1.15 1.60 5.09 10000 1000
1.09E+04 0.91 1.60 5.09
8.68E+03 0.96 1.60 5.09
5.58E+03 1.42 1.60 5.09
3.79E+03 5.25 1.60 5.09
2.59E+03 0.34 1.60 5.09
1.76E+03 1.52 1.60 5.09
5.52E+04 0.67 1.60 5.09
1.90E+04 1.28 1.60 5.09
1.18E+04 2.05 1.60 5.09 10000 1000
1.07E+04 0.69 1.60 5.09
8.60E+03 0.91 1.60 5.09
5.64E+03 0.74 1.60 5.09
3.89E+03 1.37 1.60 5.09
2.83E+03 1.25 1.60 5.09
1.77E+03 0.52 1.60 5.09
5.76E+04 1.19 1.60 5.09
2.13E+04 1.50 1.60 5.09
1.27E+04 0.54 1.60 5.09 10000 1000
1.18E+04 0.99 1.60 5.09
9.25E+03 1.63 1.60 5.09
5.70E+03 0.83 1.60 5.09
3.47E+03 0.74 1.60 5.09
2.44E+03 1.94 1.60 5.09
1.90E+03 2.75 1.60 5.09
1.21E+01 4.84 1.60 5.09
1.53E+01 9.54 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.41E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.26E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.35E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/11 1:28 PM EPA Interlab LRef 1314 JaFS
1-429
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L
Se JaFS-LRef-1314-T01-A 1 6.48E+01
Se JaFS-LRef-1314-T02-A 1 1.94E+01 E
Se JaFS-LRef-1314-T03-A 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T04-A 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T05-A 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T06-A 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T07-A 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T08-A 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T09-A 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T01-B 1 6.56E+01
Se JaFS-LRef-1314-T02-B 1 1.92E+01 E
Se JaFS-LRef-1314-T03-B 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T04-B 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T05-B 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T06-B 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T07-B 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T08-B 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T09-B 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T01-C 1 5.99E+01
Se JaFS-LRef-1314-T02-C 1 2.19E+01 E
Se JaFS-LRef-1314-T03-C 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T04-C 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T05-C 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T06-C 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T07-C 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T08-C 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T09-C 1 7.50E+00 U1/2
Se JaFS-LRef-1314-B01-A 1 7.50E+00 U1/2
Se JaFS-LRef-1314-B02-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.48E+01 1.03 15.00 47.70
1.94E+01 11.48 15.00 47.70
7.50E+00 21.87 15.00 47.70 10000 1000
7.50E+00 23.70 15.00 47.70
7.50E+00 28.43 15.00 47.70
7.50E+00 24.37 15.00 47.70
7.50E+00 19.85 15.00 47.70
7.50E+00 42.48 15.00 47.70
7.50E+00 6.72 15.00 47.70
6.56E+01 3.02 15.00 47.70
1.92E+01 16.03 15.00 47.70
7.50E+00 29.92 15.00 47.70 10000 1000
7.50E+00 10.56 15.00 47.70
7.50E+00 38.95 15.00 47.70
7.50E+00 11.65 15.00 47.70
7.50E+00 28.17 15.00 47.70
7.50E+00 25.85 15.00 47.70
7.50E+00 33.00 15.00 47.70
5.99E+01 10.92 15.00 47.70
2.19E+01 14.69 15.00 47.70
7.50E+00 8.88 15.00 47.70 10000 1000
7.50E+00 11.10 15.00 47.70
7.50E+00 25.58 15.00 47.70
7.50E+00 19.37 15.00 47.70
7.50E+00 31.80 15.00 47.70
7.50E+00 31.82 15.00 47.70
7.50E+00 18.62 15.00 47.70
7.50E+00 20.25 15.00 47.70
7.50E+00 58.84 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.31 E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.35E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.63E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 131 4 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :28 PM EPA Interlab LRef 1314 JaFS
1-430
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Si JaFS-LRef-1314-T01-A 1 4.82E+03
Si JaFS-LRef-1314-T02-A 1 3.28E+03
Si JaFS-LRef-1314-T03-A 1 2.67E+03
Si JaFS-LRef-1314-T04-A 1 2.03E+03
Si JaFS-LRef-1314-T05-A 1 1.82E+03
Si JaFS-LRef-1314-T06-A 1 1.92E+03
Si JaFS-LRef-1314-T07-A 1 1.79E+03
Si JaFS-LRef-1314-T08-A 1 1.75E+03
Si JaFS-LRef-1314-T09-A 1 1.95E+03
Si JaFS-LRef-1314-T01-B 1 5.06E+03
Si JaFS-LRef-1314-T02-B 1 3.34E+03
Si JaFS-LRef-1314-T03-B 1 2.58E+03
Si JaFS-LRef-1314-T04-B 1 2.50E+03
Si JaFS-LRef-1314-T05-B 1 1.97E+03
Si JaFS-LRef-1314-T06-B 1 1.87E+03
Si JaFS-LRef-1314-T07-B 1 1.97E+03
Si JaFS-LRef-1314-T08-B 1 1.78E+03
Si JaFS-LRef-1314-T09-B 1 1.85E+03
Si JaFS-LRef-1314-T01-C 1 5.34E+03
Si JaFS-LRef-1314-T02-C 1 3.21E+03
Si JaFS-LRef-1314-T03-C 1 2.70E+03
Si JaFS-LRef-1314-T04-C 1 2.02E+03
Si JaFS-LRef-1314-T05-C 1 1.98E+03
Si JaFS-LRef-1314-T06-C 1 1.84E+03
Si JaFS-LRef-1314-T07-C 1 1.86E+03
Si JaFS-LRef-1314-T08-C 1 1.79E+03
Si JaFS-LRef-1314-T09-C 1 1.84E+03
Si JaFS-LRef-1314-B01-A 1 5.50E-01 U1/2
Si JaFS-LRef-1314-B02-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.82E+03 1.07 1.10 3.50
3.28E+03 1.84 1.10 3.50
2.67E+03 1.73 1.10 3.50 10000 1000
2.03E+03 0.59 1.10 3.50
1.82E+03 0.41 1.10 3.50
1.92E+03 1.51 1.10 3.50
1.79E+03 5.95 1.10 3.50
1.75E+03 0.62 1.10 3.50
1.95E+03 1.48 1.10 3.50
5.06E+03 1.00 1.10 3.50
3.34E+03 2.04 1.10 3.50
2.58E+03 2.37 1.10 3.50 10000 1000
2.50E+03 3.92 1.10 3.50
1.97E+03 1.46 1.10 3.50
1.87E+03 0.93 1.10 3.50
1.97E+03 2.19 1.10 3.50
1.78E+03 0.91 1.10 3.50
1.85E+03 6.44 1.10 3.50
5.34E+03 10.66 1.10 3.50
3.21 E+03 1.35 1.10 3.50
2.70E+03 0.45 1.10 3.50 10000 1000
2.02E+03 4.91 1.10 3.50
1.98E+03 2.59 1.10 3.50
1.84E+03 3.34 1.10 3.50
1.86E+03 0.78 1.10 3.50
1.79E+03 1.75 1.10 3.50
1.84E+03 2.61 1.10 3.50
5.50E-01 5.21 1.10 3.50
5.50E-01 4.82 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.63E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.55E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.70E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :28 PM EPA Interlab LRef 1314 JaFS
1-431
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Na JaFS-LRef-1314-T01-A 1 2.22E+05
Na JaFS-LRef-1314-T02-A 1 7.60E+04
Na JaFS-LRef-1314-T03-A 1 3.46E+04
Na JaFS-LRef-1314-T04-A 1 9.53E+03
Na JaFS-LRef-1314-T05-A 1 3.86E+03
Na JaFS-LRef-1314-T06-A 1 1.67E+03
Na JaFS-LRef-1314-T07-A 1 1.14E+03
Na JaFS-LRef-1314-T08-A 1 7.72E+02
Na JaFS-LRef-1314-T09-A 1 3.71E+02
Na JaFS-LRef-1314-T01-B 1 2.22E+05
Na JaFS-LRef-1314-T02-B 1 8.50E+04
Na JaFS-LRef-1314-T03-B 1 3.72E+04
Na JaFS-LRef-1314-T04-B 1 9.15E+03
Na JaFS-LRef-1314-T05-B 1 3.32E+03
Na JaFS-LRef-1314-T06-B 1 1.71E+03
Na JaFS-LRef-1314-T07-B 1 1.09E+03
Na JaFS-LRef-1314-T08-B 1 7.23E+02
Na JaFS-LRef-1314-T09-B 1 3.56E+02
Na JaFS-LRef-1314-T01-C 1 2.21E+05
Na JaFS-LRef-1314-T02-C 1 8.05E+04
Na JaFS-LRef-1314-T03-C 1 4.32E+04
Na JaFS-LRef-1314-T04-C 1 9.15E+03
Na JaFS-LRef-1314-T05-C 1 3.86E+03
Na JaFS-LRef-1314-T06-C 1 1.68E+03
Na JaFS-LRef-1314-T07-C 1 1.06E+03
Na JaFS-LRef-1314-T08-C 1 7.48E+02
Na JaFS-LRef-1314-T09-C 1 3.85E+02
Na JaFS-LRef-1314-B01-A 1 1.25E+00 U1/2
Na JaFS-LRef-1314-B02-A 1 1.25E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.22E+05 0.46 2.50 8.00
7.60E+04 0.54 2.50 8.00
3.46E+04 0.65 2.50 8.00 10000 1000
9.53E+03 0.59 2.50 8.00
3.86E+03 0.57 2.50 8.00
1.67E+03 0.62 2.50 8.00
1.14E+03 6.07 2.50 8.00
7.72E+02 0.85 2.50 8.00
3.71 E+02 7.26 2.50 8.00
2.22E+05 0.64 2.50 8.00
8.50E+04 0.74 2.50 8.00
3.72E+04 0.32 2.50 8.00 10000 1000
9.15E+03 4.35 2.50 8.00
3.32E+03 1.12 2.50 8.00
1.71E+03 0.68 2.50 8.00
1.09E+03 1.19 2.50 8.00
7.23E+02 0.72 2.50 8.00
3.56E+02 5.40 2.50 8.00
2.21E+05 8.93 2.50 8.00
8.05E+04 1.12 2.50 8.00
4.32E+04 0.88 2.50 8.00 10000 1000
9.15E+03 4.28 2.50 8.00
3.86E+03 1.69 2.50 8.00
1.68E+03 0.51 2.50 8.00
1.06E+03 0.95 2.50 8.00
7.48E+02 0.52 2.50 8.00
3.85E+02 0.49 2.50 8.00
1.25E+00 1.23 2.50 8.00
1.25E+00 6.40 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.55E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.81 E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.41 E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :28 PM EPA Interlab LRef 1314 JaFS
1-432
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Sr JaFS-LRef-1314-T01-A 1 9.29E+03
Sr JaFS-LRef-1314-T02-A 1 1.24E+03
Sr JaFS-LRef-1314-T03-A 1 5.37E+02
Sr JaFS-LRef-1314-T04-A 1 4.74E+02
Sr JaFS-LRef-1314-T05-A 1 3.81E+02
Sr JaFS-LRef-1314-T06-A 1 3.37E+02
Sr JaFS-LRef-1314-T07-A 1 3.32E+02
Sr JaFS-LRef-1314-T08-A 1 2.78E+02
Sr JaFS-LRef-1314-T09-A 1 2.37E+02
Sr JaFS-LRef-1314-T01-B 1 9.22E+03
Sr JaFS-LRef-1314-T02-B 1 1.30E+03
Sr JaFS-LRef-1314-T03-B 1 6.13E+02
Sr JaFS-LRef-1314-T04-B 1 4.97E+02
Sr JaFS-LRef-1314-T05-B 1 4.51 E+02
Sr JaFS-LRef-1314-T06-B 1 3.74E+02
Sr JaFS-LRef-1314-T07-B 1 3.24E+02
Sr JaFS-LRef-1314-T08-B 1 2.84E+02
Sr JaFS-LRef-1314-T09-B 1 2.26E+02
Sr JaFS-LRef-1314-T01-C 1 9.09E+03
Sr JaFS-LRef-1314-T02-C 1 1.24E+03
Sr JaFS-LRef-1314-T03-C 1 6.10E+02
Sr JaFS-LRef-1314-T04-C 1 5.25E+02
Sr JaFS-LRef-1314-T05-C 1 4. 11 E+02
Sr JaFS-LRef-1314-T06-C 1 3.63E+02
Sr JaFS-LRef-1314-T07-C 1 3.44E+02
Sr JaFS-LRef-1314-T08-C 1 2.60E+02
Sr JaFS-LRef-1314-T09-C 1 2.41E+02
Sr JaFS-LRef-1314-B01-A 1 5.00E-01 U1/2
Sr JaFS-LRef-1314-B02-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.29E+03 1.57 1.00 3.18
1.24E+03 1.72 1.00 3.18
5.37E+02 0.45 1.00 3.18 10000 1000
4.74E+02 1.30 1.00 3.18
3.81E+02 0.79 1.00 3.18
3.37E+02 1.53 1.00 3.18
3.32E+02 6.79 1.00 3.18
2.78E+02 0.31 1.00 3.18
2.37E+02 1.59 1.00 3.18
9.22E+03 1.79 1.00 3.18
1.30E+03 0.64 1.00 3.18
6.13E+02 1.36 1.00 3.18 10000 1000
4.97E+02 0.70 1.00 3.18
4.51 E+02 0.89 1.00 3.18
3.74E+02 1.45 1.00 3.18
3.24E+02 3.27 1.00 3.18
2.84E+02 0.41 1.00 3.18
2.26E+02 0.95 1.00 3.18
9.09E+03 1.21 1.00 3.18
1.24E+03 1.67 1.00 3.18
6.10E+02 0.42 1.00 3.18 10000 1000
5.25E+02 0.86 1.00 3.18
4.11E+02 1.88 1.00 3.18
3.63E+02 0.87 1.00 3.18
3.44E+02 0.70 1.00 3.18
2.60E+02 1.98 1.00 3.18
2.41E+02 2.62 1.00 3.18
5.00E-01 0.46 1.00 3.18
5.00E-01 0.90 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.53E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.64E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.63E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/11 1:28 PM EPA Interlab LRef 1314 JaFS
1-433
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
S JaFS-LRef-1314-T01-A 1 5.61 E+05
S JaFS-LRef-1314-T02-A 1 4.82E+04
S JaFS-LRef-1314-T03-A 1 1.10E+04
S JaFS-LRef-1314-T04-A 1 7.46E+03
S JaFS-LRef-1314-T05-A 1 5.32E+03
S JaFS-LRef-1314-T06-A 1 4.58E+03
S JaFS-LRef-1314-T07-A 1 3.80E+03
S JaFS-LRef-1314-T08-A 1 2.66E+03
S JaFS-LRef-1314-T09-A 1 1.45E+03
S JaFS-LRef-1314-T01-B 1 6.00E+05
S JaFS-LRef-1314-T02-B 1 3.94E+04
S JaFS-LRef-1314-T03-B 1 1.09E+04
S JaFS-LRef-1314-T04-B 1 7.17E+03
S JaFS-LRef-1314-T05-B 1 5.19E+03
S JaFS-LRef-1314-T06-B 1 4.43E+03
S JaFS-LRef-1314-T07-B 1 4.17E+03
S JaFS-LRef-1314-T08-B 1 2.60E+03
S JaFS-LRef-1314-T09-B 1 1.31E+03
S JaFS-LRef-1314-T01-C 1 5.67E+05
S JaFS-LRef-1314-T02-C 1 4.46E+04
S JaFS-LRef-1314-T03-C 1 9.31E+03
S JaFS-LRef-1314-T04-C 1 7.19E+03
S JaFS-LRef-1314-T05-C 1 5.22E+03
S JaFS-LRef-1314-T06-C 1 4.15E+03
S JaFS-LRef-1314-T07-C 1 3.58E+03
S JaFS-LRef-1314-T08-C 1 2.02E+03
S JaFS-LRef-1314-T09-C 1 1.27E+03
S JaFS-LRef-1314-B01-A 1 7.63E+00 E
S JaFS-LRef-1314-B02-A 1 1.06E+01 E
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.61 E+05 0.30 6.80 21.60
4.82E+04 1.53 6.80 21.60
1.10E+04 0.78 6.80 21.60 10000 1000
7.46E+03 0.96 6.80 21.60
5.32E+03 0.93 6.80 21.60
4.58E+03 1.22 6.80 21.60
3.80E+03 8.20 6.80 21.60
2.66E+03 1.41 6.80 21.60
1.45E+03 1.20 6.80 21.60
6.00E+05 0.74 6.80 21.60
3.94E+04 1.87 6.80 21.60
1.09E+04 3.09 6.80 21.60 10000 1000
7.17E+03 0.32 6.80 21.60
5.19E+03 1.79 6.80 21.60
4.43E+03 1.80 6.80 21.60
4.17E+03 8.30 6.80 21.60
2.60E+03 0.27 6.80 21.60
1.31E+03 0.23 6.80 21.60
5.67E+05 1.14 6.80 21.60
4.46E+04 1.87 6.80 21.60
9.31E+03 0.91 6.80 21.60 10000 1000
7.19E+03 0.26 6.80 21.60
5.22E+03 3.60 6.80 21.60
4.15E+03 0.56 6.80 21.60
3.58E+03 0.68 6.80 21.60
2.02E+03 2.18 6.80 21.60
1.27E+03 1.31 6.80 21.60
7.63E+00 10.90 6.80 21.60
1.06E+01 3.33 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.19E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/11 1:28 PM EPA Interlab LRef 1314 JaFS
1-434
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Tl JaFS-LRef-1314-T01-A 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T02-A 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T03-A 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T04-A 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T05-A 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T06-A 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T07-A 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T08-A 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T09-A 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T01-B 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T02-B 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T03-B 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T04-B 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T05-B 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T06-B 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T07-B 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T08-B 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T09-B 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T01-C 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T02-C 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T03-C 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T04-C 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T05-C 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T06-C 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T07-C 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T08-C 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T09-C 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-B01-A 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-B02-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 10.92 4.60 14.60
2.30E+00 38.46 4.60 14.60
2.30E+00 33.65 4.60 14.60 10000 1000
2.30E+00 64.27 4.60 14.60
2.30E+00 25.65 4.60 14.60
2.30E+00 23.46 4.60 14.60
2.30E+00 16.40 4.60 14.60
2.30E+00 18.44 4.60 14.60
2.30E+00 5.45 4.60 14.60
2.30E+00 31.74 4.60 14.60
2.30E+00 45.96 4.60 14.60
2.30E+00 52.62 4.60 14.60 10000 1000
2.30E+00 33.77 4.60 14.60
2.30E+00 8.51 4.60 14.60
2.30E+00 36.07 4.60 14.60
2.30E+00 51.03 4.60 14.60
2.30E+00 32.00 4.60 14.60
2.30E+00 24.90 4.60 14.60
2.30E+00 40.12 4.60 14.60
2.30E+00 24.38 4.60 14.60
2.30E+00 46.66 4.60 14.60 10000 1000
2.30E+00 45.09 4.60 14.60
2.30E+00 61.35 4.60 14.60
2.30E+00 49.91 4.60 14.60
2.30E+00 71.11 4.60 14.60
2.30E+00 53.96 4.60 14.60
2.30E+00 12.72 4.60 14.60
2.30E+00 4.49 4.60 14.60
2.30E+00 48.17 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.27E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.22E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.41 E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 131 4 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/11 1:28 PM EPA Interlab LRef 1314 JaFS
1-435
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Ti JaFS-LRef-1314-T01-A 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T02-A 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T03-A 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T04-A 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T05-A 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T06-A 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T07-A 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T08-A 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T09-A 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T01-B 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T02-B 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T03-B 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T04-B 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T05-B 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T06-B 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T07-B 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T08-B 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T09-B 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T01-C 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T02-C 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T03-C 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T04-C 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T05-C 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T06-C 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T07-C 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T08-C 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T09-C 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-B01-A 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-B02-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 14.17 2.00 6.40
1.00E+00 28.48 2.00 6.40
1.00E+00 37.51 2.00 6.40 10000 1000
1.00E+00 50.66 2.00 6.40
1.00E+00 80.36 2.00 6.40
1.00E+00 32.44 2.00 6.40
1.00E+00 53.15 2.00 6.40
1.00E+00 16.85 2.00 6.40
1.00E+00 53.97 2.00 6.40
1.00E+00 48.72 2.00 6.40
1.00E+00 19.76 2.00 6.40
1.00E+00 26.25 2.00 6.40 10000 1000
1.00E+00 11.33 2.00 6.40
1.00E+00 34.21 2.00 6.40
1.00E+00 25.81 2.00 6.40
1.00E+00 40.40 2.00 6.40
1.00E+00 41.62 2.00 6.40
1.00E+00 38.56 2.00 6.40
1.00E+00 68.12 2.00 6.40
1.00E+00 24.16 2.00 6.40
1.00E+00 10.75 2.00 6.40 10000 1000
1.00E+00 25.57 2.00 6.40
1.00E+00 19.59 2.00 6.40
1.00E+00 49.49 2.00 6.40
1.00E+00 68.58 2.00 6.40
1.00E+00 34.46 2.00 6.40
1.00E+00 64.89 2.00 6.40
1.00E+00 17.72 2.00 6.40
1.00E+00 57.78 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.07E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.04E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.12E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :28 PM EPA Interlab LRef 1314 JaFS
1-436
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
V JaFS-LRef-1314-T01-A 1 1.87E+01
V JaFS-LRef-1314-T02-A 1 4.80E+00
V JaFS-LRef-1314-T03-A 1 1.66E+00 E
V JaFS-LRef-1314-T04-A 1 1.54E+00 E
V JaFS-LRef-1314-T05-A 1 7.50E-01 U1/2
V JaFS-LRef-1314-T06-A 1 7.50E-01 U1/2
V JaFS-LRef-1314-T07-A 1 7.50E-01 U1/2
V JaFS-LRef-1314-T08-A 1 7.50E-01 U1/2
V JaFS-LRef-1314-T09-A 1 7.50E-01 U1/2
V JaFS-LRef-1314-T01-B 1 1.73E+01
V JaFS-LRef-1314-T02-B 1 3.87E+00 E
V JaFS-LRef-1314-T03-B 1 1.91E+00 E
V JaFS-LRef-1314-T04-B 1 1.64E+00 E
V JaFS-LRef-1314-T05-B 1 7.50E-01 U1/2
V JaFS-LRef-1314-T06-B 1 7.50E-01 U1/2
V JaFS-LRef-1314-T07-B 1 7.50E-01 U1/2
V JaFS-LRef-1314-T08-B 1 7.50E-01 U1/2
V JaFS-LRef-1314-T09-B 1 7.50E-01 U1/2
V JaFS-LRef-1314-T01-C 1 1.94E+01
V JaFS-LRef-1314-T02-C 1 4.73E+00 E
V JaFS-LRef-1314-T03-C 1 1.83E+00 E
V JaFS-LRef-1314-T04-C 1 1.70E+00 E
V JaFS-LRef-1314-T05-C 1 7.50E-01 U1/2
V JaFS-LRef-1314-T06-C 1 7.50E-01 U1/2
V JaFS-LRef-1314-T07-C 1 7.50E-01 U1/2
V JaFS-LRef-1314-T08-C 1 7.50E-01 U1/2
V JaFS-LRef-1314-T09-C 1 7.50E-01 U1/2
V JaFS-LRef-1314-B01-A 1 7.50E-01 U1/2
V JaFS-LRef-1314-B02-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.87E+01 2.13 1.50 4.77
4.80E+00 8.98 1.50 4.77
1.66E+00 23.82 1.50 4.77 10000 1000
1.54E+00 11.96 1.50 4.77
7.50E-01 27.97 1.50 4.77
7.50E-01 7.73 1.50 4.77
7.50E-01 25.04 1.50 4.77
7.50E-01 8.00 1.50 4.77
7.50E-01 28.80 1.50 4.77
1.73E+01 6.13 1.50 4.77
3.87E+00 21.19 1.50 4.77
1.91E+00 39.31 1.50 4.77 10000 1000
1.64E+00 19.02 1.50 4.77
7.50E-01 23.84 1.50 4.77
7.50E-01 9.20 1.50 4.77
7.50E-01 24.19 1.50 4.77
7.50E-01 26.35 1.50 4.77
7.50E-01 19.97 1.50 4.77
1.94E+01 1.15 1.50 4.77
4.73E+00 2.85 1.50 4.77
1.83E+00 2.58 1.50 4.77 10000 1000
1.70E+00 3.76 1.50 4.77
7.50E-01 2.56 1.50 4.77
7.50E-01 12.08 1.50 4.77
7.50E-01 2.69 1.50 4.77
7.50E-01 0.57 1.50 4.77
7.50E-01 4.80 1.50 4.77
7.50E-01 29.86 1.50 4.77
7.50E-01 8.29 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.40E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.39E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.84E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :28 PM EPA Interlab LRef 1314 JaFS
1-437
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Zn JaFS-LRef-1314-T01-A 1 1.42E+03
Zn JaFS-LRef-1314-T02-A 1 4.64E+02
Zn JaFS-LRef-1314-T03-A 1 2.54E+02
Zn JaFS-LRef-1314-T04-A 1 1.85E+02
Zn JaFS-LRef-1314-T05-A 1 1.33E+02
Zn JaFS-LRef-1314-T06-A 1 7.17E+01
Zn JaFS-LRef-1314-T07-A 1 4.86E+01
Zn JaFS-LRef-1314-T08-A 1 3.41E+01
Zn JaFS-LRef-1314-T09-A 1 2.16E+01
Zn JaFS-LRef-1314-T01-B 1 1.86E+03
Zn JaFS-LRef-1314-T02-B 1 5.17E+02
Zn JaFS-LRef-1314-T03-B 1 2.91E+02
Zn JaFS-LRef-1314-T04-B 1 1.81E+02
Zn JaFS-LRef-1314-T05-B 1 1.56E+02
Zn JaFS-LRef-1314-T06-B 1 7.89E+01
Zn JaFS-LRef-1314-T07-B 1 5.54E+01
Zn JaFS-LRef-1314-T08-B 1 3.51E+01
Zn JaFS-LRef-1314-T09-B 1 2.04E+01
Zn JaFS-LRef-1314-T01-C 1 1.81E+03
Zn JaFS-LRef-1314-T02-C 1 4.69E+02
Zn JaFS-LRef-1314-T03-C 1 2.54E+02
Zn JaFS-LRef-1314-T04-C 1 1.75E+02
Zn JaFS-LRef-1314-T05-C 1 1.34E+02
Zn JaFS-LRef-1314-T06-C 1 7.12E+01
Zn JaFS-LRef-1314-T07-C 1 4.49E+01
Zn JaFS-LRef-1314-T08-C 1 3.63E+01
Zn JaFS-LRef-1314-T09-C 1 2.36E+01
Zn JaFS-LRef-1314-B01-A 1 5.00E-01 U1/2
Zn JaFS-LRef-1314-B02-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.42E+03 1.80 1.00 3.18
4.64E+02 2.30 1.00 3.18
2.54E+02 0.40 1.00 3.18 10000 1000
1.85E+02 0.73 1.00 3.18
1.33E+02 0.78 1.00 3.18
7.17E+01 1.39 1.00 3.18
4.86E+01 4.81 1.00 3.18
3.41E+01 0.83 1.00 3.18
2.16E+01 1.28 1.00 3.18
1.86E+03 0.86 1.00 3.18
5.17E+02 1.72 1.00 3.18
2.91E+02 1.84 1.00 3.18 10000 1000
1.81E+02 0.88 1.00 3.18
1.56E+02 1.49 1.00 3.18
7.89E+01 1.51 1.00 3.18
5.54E+01 0.93 1.00 3.18
3.51E+01 2.19 1.00 3.18
2.04E+01 2.79 1.00 3.18
1.81E+03 1.94 1.00 3.18
4.69E+02 1.91 1.00 3.18
2.54E+02 1.05 1.00 3.18 10000 1000
1.75E+02 2.78 1.00 3.18
1.34E+02 2.28 1.00 3.18
7.12E+01 1.49 1.00 3.18
4.49E+01 0.29 1.00 3.18
3.63E+01 1.46 1.00 3.18
2.36E+01 1.79 1.00 3.18
5.00E-01 11.50 1.00 3.18
5.00E-01 1.07 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.21E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.23E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.13E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
5/6/11 12:01 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:03 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:05 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:06 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:08 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:10 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:11 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:13 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:15 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:16 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:18 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:20 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:21 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:23 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:45 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:25 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:26 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:28 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:30 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:31 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:33 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:35 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:36 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:38 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:40 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:41 PM EPA Interlab LRef 1314 JaFS
5/6/11 12:43 PM EPA Interlab LRef 1314 JaFS
5/5/11 3:10 PM EPA Interlab LRef 1314 JaFS
9/2/11 1:28 PM EPA Interlab LRef 1314 JaFS
1-438
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1314:
Dilution Sample
Element Sample ID Factor Cone. Qualifier
I I I M9/L I
Al JaFS-LRef-1314-T01-D 1 7.00E+01
Al JaFS-LRef-1314-T02-D 1 4.32E+01
Al JaFS-LRef-1314-T03-D 1 2.01E+01
Al JaFS-LRef-1314-T04-D 1 1.78E+01
Al JaFS-LRef-1314-T05-D 1 1.68E+01
Al JaFS-LRef-1314-T06-D 1 1.74E+01
Al JaFS-LRef-1314-T07-D 1 1.73E+01
Al JaFS-LRef-1314-T08-D 1 1.56E+01
Al JaFS-LRef-1314-T09-D 1 1.53E+01
Al JaFS-LRef-1314-T01-E 1 7.58E+01
Al JaFS-LRef-1314-T02-E 1 5.41 E+01
Al JaFS-LRef-1314-T03-E 1 2.80E+01
Al JaFS-LRef-1314-T04-E 1 2.03E+01
Al JaFS-LRef-1314-T05-E 1 1.68E+01
Al JaFS-LRef-1314-T06-E 1 1.71E+01
Al JaFS-LRef-1314-T07-E 1 1.60E+01
Al JaFS-LRef-1314-T08-E 1 1.48E+01
Al JaFS-LRef-1314-T09-E 1 1.43E+01
Al JaFS-LRef-1314-T01-F 1 6.78E+01
Al JaFS-LRef-1314-T02-F 1 5. 11 E+01
Al JaFS-LRef-1314-T03-F 1 2.39E+01
Al JaFS-LRef-1314-T04-F 1 2.03E+01
Al JaFS-LRef-1314-T05-F 1 1.64E+01
Al JaFS-LRef-1314-T06-F 1 1.77E+01
Al JaFS-LRef-1314-T07-F 1 1.79E+01
Al JaFS-LRef-1314-T08-F 1 1.68E+01
Al JaFS-LRef-1314-T09-F 1 1.54E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.00E+01 3.38 1.00 3.18
4.32E+01 3.51 1.00 3.18
2.01E+01 6.99 1.00 3.18 10000 1000
1.78E+01 2.58 1.00 3.18
1.68E+01 5.05 1.00 3.18
1.74E+01 7.25 1.00 3.18
1.73E+01 2.67 1.00 3.18
1.56E+01 1.86 1.00 3.18
1.53E+01 10.10 1.00 3.18
7.58E+01 0.30 1.00 3.18
5.41E+01 1.36 1.00 3.18
2.80E+01 7.64 1.00 3.18 10000 1000
2.03E+01 1.46 1.00 3.18
1.68E+01 3.53 1.00 3.18
1.71E+01 2.51 1.00 3.18
1.60E+01 1.60 1.00 3.18
1.48E+01 2.74 1.00 3.18
1.43E+01 3.52 1.00 3.18
6.78E+01 3.86 1.00 3.18
5. 11 E+01 8.51 1.00 3.18
2.39E+01 6.23 1.00 3.18 10000 1000
2.03E+01 4.06 1.00 3.18
1.64E+01 2.30 1.00 3.18
1.77E+01 15.93 1.00 3.18
1.79E+01 2.10 1.00 3.18
1.68E+01 3.14 1.00 3.18
1.54E+01 2.48 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.31 E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.62E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.78E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 131 4 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-439
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Sb JaFS-LRef-1314-T01-D 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T02-D 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T03-D 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T04-D 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T05-D 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T06-D 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T07-D 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T08-D 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T09-D 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T01-E 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T02-E 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T03-E 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T04-E 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T05-E 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T06-E 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T07-E 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T08-E 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T09-E 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T01-F 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T02-F 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T03-F 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T04-F 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T05-F 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T06-F 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T07-F 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T08-F 1 3.75E+00 U1/2
Sb JaFS-LRef-1314-T09-F 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.75E+00 6.19 7.50 23.90
3.75E+00 31.86 7.50 23.90
3.75E+00 58.41 7.50 23.90 10000 1000
3.75E+00 24.34 7.50 23.90
3.75E+00 47.96 7.50 23.90
3.75E+00 25.08 7.50 23.90
3.75E+00 42.56 7.50 23.90
3.75E+00 53.08 7.50 23.90
3.75E+00 54.35 7.50 23.90
3.75E+00 14.76 7.50 23.90
3.75E+00 63.77 7.50 23.90
3.75E+00 13.60 7.50 23.90 10000 1000
3.75E+00 53.01 7.50 23.90
3.75E+00 23.53 7.50 23.90
3.75E+00 47.69 7.50 23.90
3.75E+00 30.92 7.50 23.90
3.75E+00 59.39 7.50 23.90
3.75E+00 26.70 7.50 23.90
3.75E+00 26.62 7.50 23.90
3.75E+00 18.67 7.50 23.90
3.75E+00 44.49 7.50 23.90 10000 1000
3.75E+00 62.87 7.50 23.90
3.75E+00 45.30 7.50 23.90
3.75E+00 64.86 7.50 23.90
3.75E+00 45.12 7.50 23.90
3.75E+00 3.56 7.50 23.90
3.75E+00 59.92 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.96E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.15E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.32E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/11 1:51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-440
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
As JaFS-LRef-1314-T01-D 1 5.50E+00 U1/2
As JaFS-LRef-1314-T02-D 1 5.50E+00 U1/2
As JaFS-LRef-1314-T03-D 1 5.50E+00 U1/2
As JaFS-LRef-1314-T04-D 1 5.50E+00 U1/2
As JaFS-LRef-1314-T05-D 1 5.50E+00 U1/2
As JaFS-LRef-1314-T06-D 1 5.50E+00 U1/2
As JaFS-LRef-1314-T07-D 1 5.50E+00 U1/2
As JaFS-LRef-1314-T08-D 1 5.50E+00 U1/2
As JaFS-LRef-1314-T09-D 1 5.50E+00 U1/2
As JaFS-LRef-1314-T01-E 1 5.50E+00 U1/2
As JaFS-LRef-1314-T02-E 1 5.50E+00 U1/2
As JaFS-LRef-1314-T03-E 1 5.50E+00 U1/2
As JaFS-LRef-1314-T04-E 1 5.50E+00 U1/2
As JaFS-LRef-1314-T05-E 1 5.50E+00 U1/2
As JaFS-LRef-1314-T06-E 1 5.50E+00 U1/2
As JaFS-LRef-1314-T07-E 1 5.50E+00 U1/2
As JaFS-LRef-1314-T08-E 1 5.50E+00 U1/2
As JaFS-LRef-1314-T09-E 1 5.50E+00 U1/2
As JaFS-LRef-1314-T01-F 1 5.50E+00 U1/2
As JaFS-LRef-1314-T02-F 1 5.50E+00 U1/2
As JaFS-LRef-1314-T03-F 1 5.50E+00 U1/2
As JaFS-LRef-1314-T04-F 1 5.50E+00 U1/2
As JaFS-LRef-1314-T05-F 1 5.50E+00 U1/2
As JaFS-LRef-1314-T06-F 1 5.50E+00 U1/2
As JaFS-LRef-1314-T07-F 1 5.50E+00 U1/2
As JaFS-LRef-1314-T08-F 1 5.50E+00 U1/2
As JaFS-LRef-1314-T09-F 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.50E+00 21.31 11.00 35.00
5.50E+00 49.70 11.00 35.00
5.50E+00 28.93 11.00 35.00 10000 1000
5.50E+00 9.58 11.00 35.00
5.50E+00 51.93 11.00 35.00
5.50E+00 56.06 11.00 35.00
5.50E+00 20.85 11.00 35.00
5.50E+00 21.39 11.00 35.00
5.50E+00 12.93 11.00 35.00
5.50E+00 71.67 11.00 35.00
5.50E+00 68.99 11.00 35.00
5.50E+00 85.75 11.00 35.00 10000 1000
5.50E+00 22.35 11.00 35.00
5.50E+00 22.66 11.00 35.00
5.50E+00 25.13 11.00 35.00
5.50E+00 36.03 11.00 35.00
5.50E+00 26.58 11.00 35.00
5.50E+00 1.04 11.00 35.00
5.50E+00 33.33 11.00 35.00
5.50E+00 18.63 11.00 35.00
5.50E+00 17.27 11.00 35.00 10000 1000
5.50E+00 14.94 11.00 35.00
5.50E+00 36.60 11.00 35.00
5.50E+00 22.27 11.00 35.00
5.50E+00 76.78 11.00 35.00
5.50E+00 3.70 11.00 35.00
5.50E+00 46.01 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.34E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.30E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.44E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/11 1:51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-441
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
B JaFS-LRef-1314-T01-D 1 1.76E+05
B JaFS-LRef-1314-T02-D 1 6.25E+04
B JaFS-LRef-1314-T03-D 1 1.91E+04
B JaFS-LRef-1314-T04-D 1 9.38E+03
B JaFS-LRef-1314-T05-D 1 5.54E+03
B JaFS-LRef-1314-T06-D 1 3.62E+03
B JaFS-LRef-1314-T07-D 1 2.04E+03
B JaFS-LRef-1314-T08-D 1 1.53E+03
B JaFS-LRef-1314-T09-D 1 8.75E+02
B JaFS-LRef-1314-T01-E 1 1.76E+05
B JaFS-LRef-1314-T02-E 1 6.17E+04
B JaFS-LRef-1314-T03-E 1 1.90E+04
B JaFS-LRef-1314-T04-E 1 9.02E+03
B JaFS-LRef-1314-T05-E 1 5.65E+03
B JaFS-LRef-1314-T06-E 1 3.11E+03
B JaFS-LRef-1314-T07-E 1 2.11E+03
B JaFS-LRef-1314-T08-E 1 1.53E+03
B JaFS-LRef-1314-T09-E 1 7.92E+02
B JaFS-LRef-1314-T01-F 1 1.76E+05
B JaFS-LRef-1314-T02-F 1 6.14E+04
B JaFS-LRef-1314-T03-F 1 1.91E+04
B JaFS-LRef-1314-T04-F 1 9.20E+03
B JaFS-LRef-1314-T05-F 1 5.17E+03
B JaFS-LRef-1314-T06-F 1 3.62E+03
B JaFS-LRef-1314-T07-F 1 2.16E+03
B JaFS-LRef-1314-T08-F 1 1.68E+03
B JaFS-LRef-1314-T09-F 1 7.52E+02
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.76E+05 0.85 1.00 3.18
6.25E+04 2.30 1.00 3.18
1.91E+04 3.70 1.00 3.18 10000 1000
9.38E+03 0.83 1.00 3.18
5.54E+03 1.62 1.00 3.18
3.62E+03 2.38 1.00 3.18
2.04E+03 1.17 1.00 3.18
1.53E+03 3.03 1.00 3.18
8.75E+02 3.29 1.00 3.18
1.76E+05 0.95 1.00 3.18
6.17E+04 2.37 1.00 3.18
1.90E+04 0.71 1.00 3.18 10000 1000
902E+03 1.74 1.00 3.18
5.65E+03 2.33 1.00 3.18
3.11E+03 2.81 1.00 3.18
2.11E+03 0.52 1.00 3.18
1.53E+03 1.65 1.00 3.18
7.92E+02 0.89 1.00 3.18
1.76E+05 1.54 1.00 3.18
6.14E+04 2.06 1.00 3.18
1.91E+04 3.28 1.00 3.18 10000 1000
9.20E+03 0.72 1.00 3.18
5.17E+03 1.81 1.00 3.18
3.62E+03 1.66 1.00 3.18
2.16E+03 0.50 1.00 3.18
1.68E+03 3.18 1.00 3.18
7.52E+02 2.24 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.01E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.99E+04 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.01 E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-442
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Ba JaFS-LRef-1314-T01-D 1 1.21E+02
Ba JaFS-LRef-1314-T02-D 1 8.86E+01
Ba JaFS-LRef-1314-T03-D 1 4.79E+01
Ba JaFS-LRef-1314-T04-D 1 3.64E+01
Ba JaFS-LRef-1314-T05-D 1 3.35E+01
Ba JaFS-LRef-1314-T06-D 1 2.15E+01
Ba JaFS-LRef-1314-T07-D 1 1.60E+01
Ba JaFS-LRef-1314-T08-D 1 1.14E+01
Ba JaFS-LRef-1314-T09-D 1 1.08E+01
Ba JaFS-LRef-1314-T01-E 1 1.14E+02
Ba JaFS-LRef-1314-T02-E 1 8.65E+01
Ba JaFS-LRef-1314-T03-E 1 4.91E+01
Ba JaFS-LRef-1314-T04-E 1 3.31E+01
Ba JaFS-LRef-1314-T05-E 1 3.22E+01
Ba JaFS-LRef-1314-T06-E 1 2.52E+01
Ba JaFS-LRef-1314-T07-E 1 1.51E+01
Ba JaFS-LRef-1314-T08-E 1 1.20E+01
Ba JaFS-LRef-1314-T09-E 1 1.14E+01
Ba JaFS-LRef-1314-T01-F 1 1.19E+02
Ba JaFS-LRef-1314-T02-F 1 8.54E+01
Ba JaFS-LRef-1314-T03-F 1 5.37E+01
Ba JaFS-LRef-1314-T04-F 1 4.03E+01
Ba JaFS-LRef-1314-T05-F 1 3.61 E+01
Ba JaFS-LRef-1314-T06-F 1 2.26E+01
Ba JaFS-LRef-1314-T07-F 1 1.55E+01
Ba JaFS-LRef-1314-T08-F 1 1.05E+01
Ba JaFS-LRef-1314-T09-F 1 9.11E+00
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.21E+02 0.85 1.00 3.18
8.86E+01 2.30 1.00 3.18
4.79E+01 3.70 1.00 3.18 10000 1000
3.64E+01 0.83 1.00 3.18
3.35E+01 1.62 1.00 3.18
2.15E+01 2.38 1.00 3.18
1.60E+01 1.17 1.00 3.18
1.14E+01 3.03 1.00 3.18
1.08E+01 3.29 1.00 3.18
1.14E+02 0.95 1.00 3.18
8.65E+01 2.37 1.00 3.18
4.91E+01 0.71 1.00 3.18 10000 1000
3.31E+01 1.74 1.00 3.18
3.22E+01 2.33 1.00 3.18
2.52E+01 2.81 1.00 3.18
1.51E+01 0.52 1.00 3.18
1.20E+01 1.65 1.00 3.18
1.14E+01 0.89 1.00 3.18
1.19E+02 1.54 1.00 3.18
8.54E+01 2.06 1.00 3.18
5.37E+01 3.28 1.00 3.18 10000 1000
4.03E+01 0.72 1.00 3.18
3.61E+01 1.81 1.00 3.18
2.26E+01 1.66 1.00 3.18
1.55E+01 0.50 1.00 3.18
1.05E+01 3.18 1.00 3.18
9.11E+00 27.24 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.86E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.65E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-443
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Be JaFS-LRef-1314-T01-D 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T02-D 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T03-D 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T04-D 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T05-D 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T06-D 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T07-D 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T08-D 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T09-D 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T01-E 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T02-E 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T03-E 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T04-E 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T05-E 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T06-E 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T07-E 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T08-E 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T09-E 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T01-F 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T02-F 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T03-F 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T04-F 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T05-F 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T06-F 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T07-F 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T08-F 1 9.50E-01 U1/2
Be JaFS-LRef-1314-T09-F 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 38.31 1.90 6.00
9.50E-01 39.38 1.90 6.00
9.50E-01 32.80 1.90 6.00 10000 1000
9.50E-01 41.65 1.90 6.00
9.50E-01 22.36 1.90 6.00
9.50E-01 39.73 1.90 6.00
9.50E-01 40.76 1.90 6.00
9.50E-01 16.24 1.90 6.00
9.50E-01 27.07 1.90 6.00
9.50E-01 68.66 1.90 6.00
9.50E-01 17.89 1.90 6.00
9.50E-01 2.66 1.90 6.00 10000 1000
9.50E-01 24.95 1.90 6.00
9.50E-01 35.75 1.90 6.00
9.50E-01 51.10 1.90 6.00
9.50E-01 60.64 1.90 6.00
9.50E-01 13.88 1.90 6.00
9.50E-01 25.19 1.90 6.00
9.50E-01 62.41 1.90 6.00
9.50E-01 22.85 1.90 6.00
9.50E-01 33.52 1.90 6.00 10000 1000
9.50E-01 15.56 1.90 6.00
9.50E-01 34.20 1.90 6.00
9.50E-01 14.45 1.90 6.00
9.50E-01 33.25 1.90 6.00
9.50E-01 4.02 1.90 6.00
9.50E-01 38.85 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.40E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.26E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.20E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/11 1:51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-444
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L I
Cd JaFS-LRef-1314-T01-D 1 1.72E+01
Cd JaFS-LRef-1314-T02-D 1 2.61E+00 E
Cd JaFS-LRef-1314-T03-D 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T04-D 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T05-D 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T06-D 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T07-D 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T08-D 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T09-D 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T01-E 1 2.08E+01
Cd JaFS-LRef-1314-T02-E 1 2.73E+00 E
Cd JaFS-LRef-1314-T03-E 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T04-E 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T05-E 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T06-E 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T07-E 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T08-E 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T09-E 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T01-F 1 1.61E+01
Cd JaFS-LRef-1314-T02-F 1 2.42E+00 E
Cd JaFS-LRef-1314-T03-F 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T04-F 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T05-F 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T06-F 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T07-F 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T08-F 1 1.10E+00 U1/2
Cd JaFS-LRef-1314-T09-F 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.72E+01 2.92 2.20 7.00
2.61 E+00 2.97 2.20 7.00
1.10E+00 7.63 2.20 7.00 10000 1000
1.10E+00 5.52 2.20 7.00
1.10E+00 49.28 2.20 7.00
1.10E+00 19.77 2.20 7.00
1.10E+00 21.55 2.20 7.00
1.10E+00 24.14 2.20 7.00
1.10E+00 88.66 2.20 7.00
2.08E+01 0.89 2.20 7.00
2.73E+00 6.38 2.20 7.00
1.10E+00 10.98 2.20 7.00 10000 1000
1.10E+00 11.17 2.20 7.00
1.10E+00 10.46 2.20 7.00
1.10E+00 9.93 2.20 7.00
1.10E+00 43.72 2.20 7.00
1.10E+00 41.48 2.20 7.00
1.10E+00 18.19 2.20 7.00
1.61E+01 8.28 2.20 7.00
2.42E+00 14.24 2.20 7.00
1.10E+00 21.65 2.20 7.00 10000 1000
1.10E+00 14.39 2.20 7.00
1.10E+00 23.49 2.20 7.00
1.10E+00 9.97 2.20 7.00
1.10E+00 59.11 2.20 7.00
1.10E+00 3.53 2.20 7.00
1.10E+00 13.36 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.88E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.20E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.43E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/11 1:51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 131 4 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-445
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Ca JaFS-LRef-1314-T01-D 1 3.10E+05
Ca JaFS-LRef-1314-T02-D 1 3.85E+04
Ca JaFS-LRef-1314-T03-D 1 1.83E+04
Ca JaFS-LRef-1314-T04-D 1 1.68E+04
Ca JaFS-LRef-1314-T05-D 1 1.63E+04
Ca JaFS-LRef-1314-T06-D 1 1.31E+04
Ca JaFS-LRef-1314-T07-D 1 1.09E+04
Ca JaFS-LRef-1314-T08-D 1 9.75E+03
Ca JaFS-LRef-1314-T09-D 1 1.03E+04
Ca JaFS-LRef-1314-T01-E 1 3.13E+05
Ca JaFS-LRef-1314-T02-E 1 4.11E+04
Ca JaFS-LRef-1314-T03-E 1 1.73E+04
Ca JaFS-LRef-1314-T04-E 1 1.68E+04
Ca JaFS-LRef-1314-T05-E 1 1.55E+04
Ca JaFS-LRef-1314-T06-E 1 1.26E+04
Ca JaFS-LRef-1314-T07-E 1 1.11E+04
Ca JaFS-LRef-1314-T08-E 1 9.79E+03
Ca JaFS-LRef-1314-T09-E 1 1.01E+04
Ca JaFS-LRef-1314-T01-F 1 3.03E+05
Ca JaFS-LRef-1314-T02-F 1 4.04E+04
Ca JaFS-LRef-1314-T03-F 1 1.68E+04
Ca JaFS-LRef-1314-T04-F 1 1.50E+04
Ca JaFS-LRef-1314-T05-F 1 1.47E+04
Ca JaFS-LRef-1314-T06-F 1 1.19E+04
Ca JaFS-LRef-1314-T07-F 1 1.05E+04
Ca JaFS-LRef-1314-T08-F 1 9.85E+03
Ca JaFS-LRef-1314-T09-F 1 1.02E+04
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.10E+05 0.67 2.60 8.30
3.85E+04 1.37 2.60 8.30
1.83E+04 3.04 2.60 8.30 10000 1000
1.68E+04 0.35 2.60 8.30
1.63E+04 0.20 2.60 8.30
1.31E+04 2.05 2.60 8.30
1.09E+04 1.39 2.60 8.30
9.75E+03 2.55 2.60 8.30
1.03E+04 1.27 2.60 8.30
3.13E+05 1.20 2.60 8.30
4.11E+04 2.18 2.60 8.30
1.73E+04 0.57 2.60 8.30 10000 1000
1.68E+04 1.94 2.60 8.30
1.55E+04 2.30 2.60 8.30
1.26E+04 1.71 2.60 8.30
1.11E+04 1.11 2.60 8.30
9.79E+03 1.05 2.60 8.30
1.01E+04 2.15 2.60 8.30
3.03E+05 1.66 2.60 8.30
4.04E+04 1.84 2.60 8.30
1.68E+04 2.69 2.60 8.30 10000 1000
1.50E+04 0.85 2.60 8.30
1.47E+04 2.66 2.60 8.30
1.19E+04 0.76 2.60 8.30
1.05E+04 1.69 2.60 8.30
9.85E+03 0.98 2.60 8.30
1.02E+04 0.61 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.92E+04 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.82E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.77E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-446
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cr JaFS-LRef-1314-T01-D 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T02-D 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T03-D 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T04-D 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T05-D 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T06-D 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T07-D 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T08-D 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T09-D 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T01-E 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T02-E 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T03-E 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T04-E 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T05-E 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T06-E 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T07-E 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T08-E 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T09-E 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T01-F 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T02-F 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T03-F 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T04-F 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T05-F 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T06-F 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T07-F 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T08-F 1 6.00E-01 U1/2
Cr JaFS-LRef-1314-T09-F 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 24.69 1.20 3.82
6.00E-01 14.05 1.20 3.82
6.00E-01 5.78 1.20 3.82 10000 1000
6.00E-01 59.56 1.20 3.82
6.00E-01 47.43 1.20 3.82
6.00E-01 51.47 1.20 3.82
6.00E-01 19.11 1.20 3.82
6.00E-01 27.76 1.20 3.82
6.00E-01 29.22 1.20 3.82
6.00E-01 23.03 1.20 3.82
6.00E-01 59.61 1.20 3.82
6.00E-01 12.67 1.20 3.82 10000 1000
6.00E-01 40.94 1.20 3.82
6.00E-01 26.52 1.20 3.82
6.00E-01 33.34 1.20 3.82
6.00E-01 32.77 1.20 3.82
6.00E-01 5.73 1.20 3.82
6.00E-01 10.65 1.20 3.82
6.00E-01 51.14 1.20 3.82
6.00E-01 32.55 1.20 3.82
6.00E-01 88.10 1.20 3.82 10000 1000
6.00E-01 7.28 1.20 3.82
6.00E-01 35.58 1.20 3.82
6.00E-01 33.19 1.20 3.82
6.00E-01 37.69 1.20 3.82
6.00E-01 3.13 1.20 3.82
6.00E-01 5.82 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.23E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.31 E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.34E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-447
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Co JaFS-LRef-1314-T01-D 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T02-D 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T03-D 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T04-D 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T05-D 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T06-D 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T07-D 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T08-D 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T09-D 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T01-E 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T02-E 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T03-E 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T04-E 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T05-E 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T06-E 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T07-E 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T08-E 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T09-E 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T01-F 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T02-F 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T03-F 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T04-F 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T05-F 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T06-F 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T07-F 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T08-F 1 9.00E-01 U1/2
Co JaFS-LRef-1314-T09-F 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 16.56 1.80 5.72
9.00E-01 35.18 1.80 5.72
9.00E-01 37.48 1.80 5.72 10000 1000
9.00E-01 53.02 1.80 5.72
9.00E-01 54.63 1.80 5.72
9.00E-01 26.65 1.80 5.72
9.00E-01 18.80 1.80 5.72
9.00E-01 28.11 1.80 5.72
9.00E-01 56.44 1.80 5.72
9.00E-01 47.30 1.80 5.72
9.00E-01 19.75 1.80 5.72
9.00E-01 41.81 1.80 5.72 10000 1000
9.00E-01 15.88 1.80 5.72
9.00E-01 31.21 1.80 5.72
9.00E-01 17.35 1.80 5.72
9.00E-01 37.72 1.80 5.72
9.00E-01 42.74 1.80 5.72
9.00E-01 53.91 1.80 5.72
9.00E-01 41.32 1.80 5.72
9.00E-01 41.20 1.80 5.72
9.00E-01 33.48 1.80 5.72 10000 1000
9.00E-01 22.79 1.80 5.72
9.00E-01 4.49 1.80 5.72
9.00E-01 23.17 1.80 5.72
9.00E-01 25.12 1.80 5.72
9.00E-01 3.38 1.80 5.72
9.00E-01 28.51 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.14E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.36E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.26E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-448
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Cu JaFS-LRef-1314-T01-D 1 1.21E+03
Cu JaFS-LRef-1314-T02-D 1 7.71E+02
Cu JaFS-LRef-1314-T03-D 1 4.38E+02
Cu JaFS-LRef-1314-T04-D 1 2.54E+02
Cu JaFS-LRef-1314-T05-D 1 1.56E+02
Cu JaFS-LRef-1314-T06-D 1 1.23E+02
Cu JaFS-LRef-1314-T07-D 1 1.12E+02
Cu JaFS-LRef-1314-T08-D 1 7.50E+01
Cu JaFS-LRef-1314-T09-D 1 5.27E+01
Cu JaFS-LRef-1314-T01-E 1 1.24E+03
Cu JaFS-LRef-1314-T02-E 1 7.35E+02
Cu JaFS-LRef-1314-T03-E 1 4.17E+02
Cu JaFS-LRef-1314-T04-E 1 2.55E+02
Cu JaFS-LRef-1314-T05-E 1 2.04E+02
Cu JaFS-LRef-1314-T06-E 1 1.51E+02
Cu JaFS-LRef-1314-T07-E 1 1.02E+02
Cu JaFS-LRef-1314-T08-E 1 7.58E+01
Cu JaFS-LRef-1314-T09-E 1 5.94E+01
Cu JaFS-LRef-1314-T01-F 1 1.23E+03
Cu JaFS-LRef-1314-T02-F 1 7.41E+02
Cu JaFS-LRef-1314-T03-F 1 4.26E+02
Cu JaFS-LRef-1314-T04-F 1 2.65E+02
Cu JaFS-LRef-1314-T05-F 1 2.06E+02
Cu JaFS-LRef-1314-T06-F 1 1.53E+02
Cu JaFS-LRef-1314-T07-F 1 9.62E+01
Cu JaFS-LRef-1314-T08-F 1 7.11E+01
Cu JaFS-LRef-1314-T09-F 1 5.48E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.21E+03 0.47 3.70 11.80
7.71 E+02 0.87 3.70 11.80
4.38E+02 2.68 3.70 11.80 10000 1000
2.54E+02 0.58 3.70 11.80
1.56E+02 1.75 3.70 11.80
1.23E+02 1.77 3.70 11.80
1.12E+02 0.56 3.70 11.80
7.50E+01 1.88 3.70 11.80
5.27E+01 2.23 3.70 11.80
1.24E+03 1.91 3.70 11.80
7.35E+02 2.15 3.70 11.80
4.17E+02 0.60 3.70 11.80 10000 1000
2.55E+02 0.77 3.70 11.80
2.04E+02 2.15 3.70 11.80
1.51E+02 1.11 3.70 11.80
1.02E+02 2.01 3.70 11.80
7.58E+01 1.04 3.70 11.80
5.94E+01 1.36 3.70 11.80
1.23E+03 2.02 3.70 11.80
7.41 E+02 2.82 3.70 11.80
4.26E+02 4.87 3.70 11.80 10000 1000
2.65E+02 2.64 3.70 11.80
2.06E+02 2.50 3.70 11.80
1.53E+02 1.91 3.70 11.80
9.62E+01 1.74 3.70 11.80
7.11E+01 2.11 3.70 11.80
5.48E+01 4.13 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.42E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.44E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.40E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/11 1:41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/11 1:51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-449
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Fe JaFS-LRef-1314-T01-D 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T02-D 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T03-D 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T04-D 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T05-D 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T06-D 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T07-D 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T08-D 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T09-D 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T01-E 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T02-E 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T03-E 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T04-E 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T05-E 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T06-E 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T07-E 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T08-E 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T09-E 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T01-F 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T02-F 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T03-F 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T04-F 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T05-F 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T06-F 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T07-F 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T08-F 1 1.00E+00 U1/2
Fe JaFS-LRef-1314-T09-F 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 7.46 2.00 6.40
1.00E+00 7.52 2.00 6.40
1.00E+00 14.43 2.00 6.40 10000 1000
1.00E+00 4.95 2.00 6.40
1.00E+00 18.56 2.00 6.40
1.00E+00 4.12 2.00 6.40
1.00E+00 22.09 2.00 6.40
1.00E+00 17.92 2.00 6.40
1.00E+00 21.37 2.00 6.40
1.00E+00 1.79 2.00 6.40
1.00E+00 8.50 2.00 6.40
1.00E+00 14.03 2.00 6.40 10000 1000
1.00E+00 2.38 2.00 6.40
1.00E+00 10.51 2.00 6.40
1.00E+00 16.93 2.00 6.40
1.00E+00 1.37 2.00 6.40
1.00E+00 14.13 2.00 6.40
1.00E+00 20.42 2.00 6.40
1.00E+00 18.89 2.00 6.40
1.00E+00 18.63 2.00 6.40
1.00E+00 18.21 2.00 6.40 10000 1000
1.00E+00 22.03 2.00 6.40
1.00E+00 4.46 2.00 6.40
1.00E+00 10.94 2.00 6.40
1.00E+00 6.98 2.00 6.40
1.00E+00 3.19 2.00 6.40
1.00E+00 1.11 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.34E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.68E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.55E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-450
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
Pb JaFS-LRef-1314-T01-D 1 7.67E+01
Pb JaFS-LRef-1314-T02-D 1 1.11E+02
Pb JaFS-LRef-1314-T03-D 1 9.50E+01
Pb JaFS-LRef-1314-T04-D 1 8.62E+01
Pb JaFS-LRef-1314-T05-D 1 7.13E+01
Pb JaFS-LRef-1314-T06-D 1 5.95E+01
Pb JaFS-LRef-1314-T07-D 1 4.02E+01
Pb JaFS-LRef-1314-T08-D 1 3.24E+01
Pb JaFS-LRef-1314-T09-D 1 3.15E+01
Pb JaFS-LRef-1314-T01-E 1 8.36E+01
Pb JaFS-LRef-1314-T02-E 1 1.29E+02
Pb JaFS-LRef-1314-T03-E 1 1.09E+02
Pb JaFS-LRef-1314-T04-E 1 9.59E+01
Pb JaFS-LRef-1314-T05-E 1 8.01E+01
Pb JaFS-LRef-1314-T06-E 1 6.80E+01
Pb JaFS-LRef-1314-T07-E 1 5.17E+01
Pb JaFS-LRef-1314-T08-E 1 5.36E+01
Pb JaFS-LRef-1314-T09-E 1 4.08E+01
Pb JaFS-LRef-1314-T01-F 1 8.07E+01
Pb JaFS-LRef-1314-T02-F 1 1.04E+02
Pb JaFS-LRef-1314-T03-F 1 9.54E+01
Pb JaFS-LRef-1314-T04-F 1 7.89E+01
Pb JaFS-LRef-1314-T05-F 1 6.08E+01
Pb JaFS-LRef-1314-T06-F 1 5.60E+01
Pb JaFS-LRef-1314-T07-F 1 4.83E+01
Pb JaFS-LRef-1314-T08-F 1 3.65E+01
Pb JaFS-LRef-1314-T09-F 1 3.20E+01
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.67E+01 9.49 6.80 21.60
1.11E+02 2.79 6.80 21.60
9.50E+01 1.61 6.80 21.60 10000 1000
8.62E+01 6.27 6.80 21.60
7.13E+01 2.44 6.80 21.60
5.95E+01 3.26 6.80 21.60
4.02E+01 8.41 6.80 21.60
3.24E+01 9.70 6.80 21.60
3.15E+01 10.77 6.80 21.60
8.36E+01 2.30 6.80 21.60
1.29E+02 3.51 6.80 21.60
1.09E+02 3.50 6.80 21.60 10000 1000
9.59E+01 5.03 6.80 21.60
8.01 E+01 3.76 6.80 21.60
6.80E+01 5.06 6.80 21.60
5.17E+01 4.07 6.80 21.60
5.36E+01 2.75 6.80 21.60
4.08E+01 6.19 6.80 21.60
8.07E+01 2.82 6.80 21.60
1.04E+02 2.92 6.80 21.60
9.54E+01 5.20 6.80 21.60 10000 1000
7.89E+01 4.87 6.80 21.60
6.08E+01 1.38 6.80 21.60
5.60E+01 8.81 6.80 21.60
4.83E+01 7.52 6.80 21.60
3.65E+01 2.78 6.80 21.60
3.20E+01 1.71 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.06E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.98E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-451
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Li JaFS-LRef-1314-T01-D 1 8.30E+01
Li JaFS-LRef-1314-T02-D 1 1.23E+01
Li JaFS-LRef-1314-T03-D 1 2.36E+00 E
Li JaFS-LRef-1314-T04-D 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T05-D 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T06-D 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T07-D 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T08-D 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T09-D 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T01-E 1 8.38E+01
Li JaFS-LRef-1314-T02-E 1 1.33E+01
Li JaFS-LRef-1314-T03-E 1 2.70E+00 E
Li JaFS-LRef-1314-T04-E 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T05-E 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T06-E 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T07-E 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T08-E 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T09-E 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T01-F 1 8.24E+01
Li JaFS-LRef-1314-T02-F 1 1.12E+01
Li JaFS-LRef-1314-T03-F 1 2.19E+00 E
Li JaFS-LRef-1314-T04-F 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T05-F 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T06-F 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T07-F 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T08-F 1 9.50E-01 U1/2
Li JaFS-LRef-1314-T09-F 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.30E+01 5.52 1.90 6.00
1.23E+01 1.22 1.90 6.00
2.36E+00 8.10 1.90 6.00 10000 1000
9.50E-01 30.37 1.90 6.00
9.50E-01 13.70 1.90 6.00
9.50E-01 53.01 1.90 6.00
9.50E-01 65.32 1.90 6.00
9.50E-01 24.58 1.90 6.00
9.50E-01 11.50 1.90 6.00
8.38E+01 1.77 1.90 6.00
1.33E+01 1.45 1.90 6.00
2.70E+00 17.46 1.90 6.00 10000 1000
9.50E-01 15.52 1.90 6.00
9.50E-01 56.32 1.90 6.00
9.50E-01 49.67 1.90 6.00
9.50E-01 33.48 1.90 6.00
9.50E-01 11.41 1.90 6.00
9.50E-01 54.70 1.90 6.00
8.24E+01 6.84 1.90 6.00
1.12E+01 4.98 1.90 6.00
2.19E+00 6.06 1.90 6.00 10000 1000
9.50E-01 9.57 1.90 6.00
9.50E-01 32.01 1.90 6.00
9.50E-01 17.13 1.90 6.00
9.50E-01 6.63 1.90 6.00
9.50E-01 3.19 1.90 6.00
9.50E-01 8.13 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.75E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.01 E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.90E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-452
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Mn JaFS-LRef-1314-T01-D 1 2.55E+02
Mn JaFS-LRef-1314-T02-D 1 2.74E+01
Mn JaFS-LRef-1314-T03-D 1 1.33E+01
Mn JaFS-LRef-1314-T04-D 1 1.09E+01
Mn JaFS-LRef-1314-T05-D 1 1.01E+01
Mn JaFS-LRef-1314-T06-D 1 9.53E+00
Mn JaFS-LRef-1314-T07-D 1 1.47E+01
Mn JaFS-LRef-1314-T08-D 1 9.14E+00
Mn JaFS-LRef-1314-T09-D 1 8.06E+00
Mn JaFS-LRef-1314-T01-E 1 2.79E+02
Mn JaFS-LRef-1314-T02-E 1 3.51 E+01
Mn JaFS-LRef-1314-T03-E 1 1.25E+01
Mn JaFS-LRef-1314-T04-E 1 1.02E+01
Mn JaFS-LRef-1314-T05-E 1 8.29E+00
Mn JaFS-LRef-1314-T06-E 1 6.51E+00
Mn JaFS-LRef-1314-T07-E 1 9.24E+00
Mn JaFS-LRef-1314-T08-E 1 8.73E+00
Mn JaFS-LRef-1314-T09-E 1 8.63E+00
Mn JaFS-LRef-1314-T01-F 1 2.52E+02
Mn JaFS-LRef-1314-T02-F 1 2.94E+01
Mn JaFS-LRef-1314-T03-F 1 1.26E+01
Mn JaFS-LRef-1314-T04-F 1 1.00E+01
Mn JaFS-LRef-1314-T05-F 1 9.33E+00
Mn JaFS-LRef-1314-T06-F 1 7.96E+00
Mn JaFS-LRef-1314-T07-F 1 8.91 E+00
Mn JaFS-LRef-1314-T08-F 1 8.33E+00
Mn JaFS-LRef-1314-T09-F 1 7.26E+00
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.55E+02 1.79 2.00 6.40
2.74E+01 0.79 2.00 6.40
1.33E+01 2.60 2.00 6.40 10000 1000
1.09E+01 0.51 2.00 6.40
1.01 E+01 0.77 2.00 6.40
9.53E+00 1.89 2.00 6.40
1.47E+01 0.44 2.00 6.40
9.14E+00 2.79 2.00 6.40
8.06E+00 1.75 2.00 6.40
2.79E+02 0.24 2.00 6.40
3.51 E+01 2.53 2.00 6.40
1.25E+01 0.56 2.00 6.40 10000 1000
1.02E+01 1.81 2.00 6.40
8.29E+00 2.57 2.00 6.40
6.51 E+00 2.06 2.00 6.40
9.24E+00 2.00 2.00 6.40
8.73E+00 0.65 2.00 6.40
8.63E+00 1.09 2.00 6.40
2.52E+02 1.59 2.00 6.40
2.94E+01 1.47 2.00 6.40
1.26E+01 3.28 2.00 6.40 10000 1000
1.00E+01 1.38 2.00 6.40
9.33E+00 2.57 2.00 6.40
7.96E+00 1.39 2.00 6.40
8.91E+00 2.11 2.00 6.40
8.33E+00 3.37 2.00 6.40
7.26E+00 5.05 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.80E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.57E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.75E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-453
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Mg JaFS-LRef-1314-T01-D 1 5.91 E+04
Mg JaFS-LRef-1314-T02-D 1 6.73E+03
Mg JaFS-LRef-1314-T03-D 1 3.00E+03
Mg JaFS-LRef-1314-T04-D 1 2.65E+03
Mg JaFS-LRef-1314-T05-D 1 1.86E+03
Mg JaFS-LRef-1314-T06-D 1 2.49E+03
Mg JaFS-LRef-1314-T07-D 1 1.45E+03
Mg JaFS-LRef-1314-T08-D 1 1.20E+03
Mg JaFS-LRef-1314-T09-D 1 1.21E+03
Mg JaFS-LRef-1314-T01-E 1 5.87E+04
Mg JaFS-LRef-1314-T02-E 1 7.34E+03
Mg JaFS-LRef-1314-T03-E 1 2.91E+03
Mg JaFS-LRef-1314-T04-E 1 2.66E+03
Mg JaFS-LRef-1314-T05-E 1 2.41E+03
Mg JaFS-LRef-1314-T06-E 1 1.80E+03
Mg JaFS-LRef-1314-T07-E 1 1.45E+03
Mg JaFS-LRef-1314-T08-E 1 1.21E+03
Mg JaFS-LRef-1314-T09-E 1 1.17E+03
Mg JaFS-LRef-1314-T01-F 1 5.79E+04
Mg JaFS-LRef-1314-T02-F 1 6.63E+03
Mg JaFS-LRef-1314-T03-F 1 3.26E+03
Mg JaFS-LRef-1314-T04-F 1 2.65E+03
Mg JaFS-LRef-1314-T05-F 1 2.45E+03
Mg JaFS-LRef-1314-T06-F 1 1.75E+03
Mg JaFS-LRef-1314-T07-F 1 1.43E+03
Mg JaFS-LRef-1314-T08-F 1 1.23E+03
Mg JaFS-LRef-1314-T09-F 1 1.13E+03
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.91E+04 1.35 1.00 3.18
6.73E+03 0.81 1.00 3.18
3.00E+03 3.50 1.00 3.18 10000 1000
2.65E+03 0.90 1.00 3.18
1.86E+03 0.16 1.00 3.18
2.49E+03 1.45 1.00 3.18
1.45E+03 0.64 1.00 3.18
1.20E+03 1.67 1.00 3.18
1.21E+03 0.83 1.00 3.18
5.87E+04 0.81 1.00 3.18
7.34E+03 2.18 1.00 3.18
2.91E+03 1.26 1.00 3.18 10000 1000
2.66E+03 1.84 1.00 3.18
2.41E+03 2.28 1.00 3.18
1.80E+03 1.29 1.00 3.18
1.45E+03 0.40 1.00 3.18
1.21E+03 1.39 1.00 3.18
1.17E+03 0.94 1.00 3.18
5.79E+04 2.18 1.00 3.18
6.63E+03 1.41 1.00 3.18
3.26E+03 3.39 1.00 3.18 10000 1000
2.65E+03 0.54 1.00 3.18
2.45E+03 2.85 1.00 3.18
1.75E+03 1.74 1.00 3.18
1.43E+03 1.13 1.00 3.18
1.23E+03 0.68 1.00 3.18
1.13E+03 3.18 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.96E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.84E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.19E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-454
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Mo JaFS-LRef-1314-T01-D 1 1.21E+02
Mo JaFS-LRef-1314-T02-D 1 4.62E+01
Mo JaFS-LRef-1314-T03-D 1 1.79E+01
Mo JaFS-LRef-1314-T04-D 1 1.35E+01
Mo JaFS-LRef-1314-T05-D 1 7.95E+00
Mo JaFS-LRef-1314-T06-D 1 1.06E+01
Mo JaFS-LRef-1314-T07-D 1 4.98E+00
Mo JaFS-LRef-1314-T08-D 1 5.29E+00
Mo JaFS-LRef-1314-T09-D 1 3.89E+00
Mo JaFS-LRef-1314-T01-E 1 1.12E+02
Mo JaFS-LRef-1314-T02-E 1 4.91 E+01
Mo JaFS-LRef-1314-T03-E 1 1.62E+01
Mo JaFS-LRef-1314-T04-E 1 1.33E+01
Mo JaFS-LRef-1314-T05-E 1 9.70E+00
Mo JaFS-LRef-1314-T06-E 1 7.81E+00
Mo JaFS-LRef-1314-T07-E 1 5.19E+00
Mo JaFS-LRef-1314-T08-E 1 4.03E+00
Mo JaFS-LRef-1314-T09-E 1 4.53E+00
Mo JaFS-LRef-1314-T01-F 1 1.18E+02
Mo JaFS-LRef-1314-T02-F 1 5.33E+01
Mo JaFS-LRef-1314-T03-F 1 1.63E+01
Mo JaFS-LRef-1314-T04-F 1 1.24E+01
Mo JaFS-LRef-1314-T05-F 1 8.64E+00
Mo JaFS-LRef-1314-T06-F 1 6.95E+00
Mo JaFS-LRef-1314-T07-F 1 5.91 E+00
Mo JaFS-LRef-1314-T08-F 1 4.95E+00
Mo JaFS-LRef-1314-T09-F 1 4.05E+00
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.21E+02 0.60 1.20 3.82
4.62E+01 0.81 1.20 3.82
1.79E+01 3.06 1.20 3.82 10000 1000
1.35E+01 6.00 1.20 3.82
7.95E+00 5.04 1.20 3.82
1.06E+01 3.05 1.20 3.82
4.98E+00 1.19 1.20 3.82
5.29E+00 10.68 1.20 3.82
3.89E+00 2.97 1.20 3.82
1.12E+02 0.25 1.20 3.82
4.91 E+01 2.92 1.20 3.82
1.62E+01 7.74 1.20 3.82 10000 1000
1.33E+01 3.35 1.20 3.82
9.70E+00 1.91 1.20 3.82
7.81E+00 2.92 1.20 3.82
5.19E+00 1.52 1.20 3.82
4.03E+00 1.80 1.20 3.82
4.53E+00 9.49 1.20 3.82
1.18E+02 3.32 1.20 3.82
5.33E+01 1.13 1.20 3.82
1.63E+01 3.66 1.20 3.82 10000 1000
1.24E+01 1.47 1.20 3.82
8.64E+00 1.42 1.20 3.82
6.95E+00 5.08 1.20 3.82
5.91E+00 7.70 1.20 3.82
4.95E+00 3.50 1.20 3.82
4.05E+00 8.19 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.85E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.38E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.79E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-455
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ni JaFS-LRef-1314-T01-D 1 9.33E+00
Ni JaFS-LRef-1314-T02-D 1 3.18E+00 E
Ni JaFS-LRef-1314-T03-D 1 2.78E+00 E
Ni JaFS-LRef-1314-T04-D 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T05-D 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T06-D 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T07-D 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T08-D 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T09-D 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T01-E 1 1.20E+01
Ni JaFS-LRef-1314-T02-E 1 4.32E+00 E
Ni JaFS-LRef-1314-T03-E 1 2.06E+00 E
Ni JaFS-LRef-1314-T04-E 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T05-E 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T06-E 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T07-E 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T08-E 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T09-E 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T01-F 1 1.07E+01
Ni JaFS-LRef-1314-T02-F 1 3.87E+00 E
Ni JaFS-LRef-1314-T03-F 1 2.88E+00 E
Ni JaFS-LRef-1314-T04-F 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T05-F 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T06-F 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T07-F 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T08-F 1 9.00E-01 U1/2
Ni JaFS-LRef-1314-T09-F 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.33E+00 2.34 1.80 5.70
3.18E+00 22.42 1.80 5.70
2.78E+00 26.29 1.80 5.70 10000 1000
9.00E-01 48.00 1.80 5.70
9.00E-01 28.95 1.80 5.70
9.00E-01 3.26 1.80 5.70
9.00E-01 66.34 1.80 5.70
9.00E-01 35.47 1.80 5.70
9.00E-01 30.25 1.80 5.70
1.20E+01 5.13 1.80 5.70
4.32E+00 14.67 1.80 5.70
2.06E+00 15.00 1.80 5.70 10000 1000
9.00E-01 28.43 1.80 5.70
9.00E-01 14.92 1.80 5.70
9.00E-01 25.81 1.80 5.70
9.00E-01 44.57 1.80 5.70
9.00E-01 34.96 1.80 5.70
9.00E-01 16.60 1.80 5.70
1.07E+01 4.63 1.80 5.70
3.87E+00 22.45 1.80 5.70
2.88E+00 12.72 1.80 5.70 10000 1000
9.00E-01 25.25 1.80 5.70
9.00E-01 31.47 1.80 5.70
9.00E-01 66.88 1.80 5.70
9.00E-01 15.50 1.80 5.70
9.00E-01 3.14 1.80 5.70
9.00E-01 17.11 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.87E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.21E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.66E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/11 1:51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 131 4 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-456
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
P JaFS-LRef-1314-T01-D 1 6.45E+01
P JaFS-LRef-1314-T02-D 1 5.59E+01
P JaFS-LRef-1314-T03-D 1 4.39E+01
P JaFS-LRef-1314-T04-D 1 3.01 E+01
P JaFS-LRef-1314-T05-D 1 2.56E+01
P JaFS-LRef-1314-T06-D 1 1.91 E+01
P JaFS-LRef-1314-T07-D 1 2.69E+01
P JaFS-LRef-1314-T08-D 1 3.14E+01
P JaFS-LRef-1314-T09-D 1 3.38E+01
P JaFS-LRef-1314-T01-E 1 6.94E+01
P JaFS-LRef-1314-T02-E 1 5.94E+01
P JaFS-LRef-1314-T03-E 1 4.51E+01
P JaFS-LRef-1314-T04-E 1 3.25E+01
P JaFS-LRef-1314-T05-E 1 1.81 E+01
P JaFS-LRef-1314-T06-E 1 2.07E+01
P JaFS-LRef-1314-T07-E 1 2.66E+01
P JaFS-LRef-1314-T08-E 1 3.38E+01
P JaFS-LRef-1314-T09-E 1 3.66E+01
P JaFS-LRef-1314-T01-F 1 5.34E+01
P JaFS-LRef-1314-T02-F 1 4.71E+01
P JaFS-LRef-1314-T03-F 1 3.68E+01
P JaFS-LRef-1314-T04-F 1 2.51 E+01
P JaFS-LRef-1314-T05-F 1 1.60E+01
P JaFS-LRef-1314-T06-F 1 2.17E+01
P JaFS-LRef-1314-T07-F 1 2.89E+01
P JaFS-LRef-1314-T08-F 1 3.80E+01
P JaFS-LRef-1314-T09-F 1 4.33E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.45E+01 1.03 3.70 11.80
5.59E+01 3.30 3.70 11.80
4.39E+01 7.60 3.70 11.80 10000 1000
3.01E+01 4.12 3.70 11.80
2.56E+01 5.88 3.70 11.80
1.91 E+01 3.35 3.70 11.80
2.69E+01 6.02 3.70 11.80
3.14E+01 1.54 3.70 11.80
3.38E+01 4.06 3.70 11.80
6.94E+01 10.12 3.70 11.80
5.94E+01 7.96 3.70 11.80
4.51E+01 3.39 3.70 11.80 10000 1000
3.25E+01 3.57 3.70 11.80
1.81E+01 3.69 3.70 11.80
2.07E+01 6.97 3.70 11.80
2.66E+01 7.85 3.70 11.80
3.38E+01 5.13 3.70 11.80
3.66E+01 8.77 3.70 11.80
5.34E+01 2.34 3.70 11.80
4.71E+01 5.49 3.70 11.80
3.68E+01 17.32 3.70 11.80 10000 1000
2.51E+01 4.82 3.70 11.80
1.60E+01 2.59 3.70 11.80
2.17E+01 2.59 3.70 11.80
2.89E+01 2.03 3.70 11.80
3.80E+01 4.69 3.70 11.80
4.33E+01 4.15 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.73E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.60E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.42E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-457
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
K JaFS-LRef-1314-T01-D 1 5.83E+04
K JaFS-LRef-1314-T02-D 1 1.65E+04
K JaFS-LRef-1314-T03-D 1 1.07E+04
K JaFS-LRef-1314-T04-D 1 8.92E+03
K JaFS-LRef-1314-T05-D 1 7.68E+03
K JaFS-LRef-1314-T06-D 1 5.34E+03
K JaFS-LRef-1314-T07-D 1 3.84E+03
K JaFS-LRef-1314-T08-D 1 2.73E+03
K JaFS-LRef-1314-T09-D 1 2.22E+03
K JaFS-LRef-1314-T01-E 1 5.72E+04
K JaFS-LRef-1314-T02-E 1 1.74E+04
K JaFS-LRef-1314-T03-E 1 1.05E+04
K JaFS-LRef-1314-T04-E 1 9.13E+03
K JaFS-LRef-1314-T05-E 1 7.68E+03
K JaFS-LRef-1314-T06-E 1 5.21E+03
K JaFS-LRef-1314-T07-E 1 3.82E+03
K JaFS-LRef-1314-T08-E 1 2.68E+03
K JaFS-LRef-1314-T09-E 1 2.15E+03
K JaFS-LRef-1314-T01-F 1 5.74E+04
K JaFS-LRef-1314-T02-F 1 1.68E+04
K JaFS-LRef-1314-T03-F 1 1.08E+04
K JaFS-LRef-1314-T04-F 1 8.86E+03
K JaFS-LRef-1314-T05-F 1 7.71E+03
K JaFS-LRef-1314-T06-F 1 5.21E+03
K JaFS-LRef-1314-T07-F 1 3.81 E+03
K JaFS-LRef-1314-T08-F 1 2.65E+03
K JaFS-LRef-1314-T09-F 1 2.14E+03
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.83E+04 0.65 1.60 5.09
1.65E+04 1.03 1.60 5.09
1.07E+04 3.12 1.60 5.09 10000 1000
8.92E+03 0.44 1.60 5.09
7.68E+03 0.46 1.60 5.09
5.34E+03 1.92 1.60 5.09
3.84E+03 0.88 1.60 5.09
2.73E+03 2.50 1.60 5.09
2.22E+03 0.98 1.60 5.09
5.72E+04 1.26 1.60 5.09
1.74E+04 2.52 1.60 5.09
1.05E+04 0.85 1.60 5.09 10000 1000
9.13E+03 1.39 1.60 5.09
7.68E+03 2.30 1.60 5.09
5.21E+03 1.68 1.60 5.09
3.82E+03 1.31 1.60 5.09
2.68E+03 1.31 1.60 5.09
2.15E+03 1.39 1.60 5.09
5.74E+04 1.82 1.60 5.09
1.68E+04 1.82 1.60 5.09
1.08E+04 2.94 1.60 5.09 10000 1000
8.86E+03 0.52 1.60 5.09
7.71E+03 2.71 1.60 5.09
5.21E+03 0.95 1.60 5.09
3.81 E+03 1.08 1.60 5.09
2.65E+03 0.31 1.60 5.09
2.14E+03 1.47 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.16E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-458
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Se JaFS-LRef-1314-T01-D 1 6.50E+01
Se JaFS-LRef-1314-T02-D 1 2.17E+01 E
Se JaFS-LRef-1314-T03-D 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T04-D 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T05-D 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T06-D 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T07-D 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T08-D 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T09-D 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T01-E 1 5.28E+01
Se JaFS-LRef-1314-T02-E 1 2.06E+01 E
Se JaFS-LRef-1314-T03-E 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T04-E 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T05-E 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T06-E 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T07-E 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T08-E 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T09-E 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T01-F 1 5.63E+01
Se JaFS-LRef-1314-T02-F 1 1.85E+01 E
Se JaFS-LRef-1314-T03-F 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T04-F 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T05-F 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T06-F 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T07-F 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T08-F 1 7.50E+00 U1/2
Se JaFS-LRef-1314-T09-F 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.50E+01 4.84 15.00 47.70
2.17E+01 15.94 15.00 47.70
7.50E+00 33.62 15.00 47.70 10000 1000
7.50E+00 11.55 15.00 47.70
7.50E+00 36.27 15.00 47.70
7.50E+00 35.97 15.00 47.70
7.50E+00 6.81 15.00 47.70
7.50E+00 8.21 15.00 47.70
7.50E+00 17.37 15.00 47.70
5.28E+01 2.74 15.00 47.70
2.06E+01 17.60 15.00 47.70
7.50E+00 42.14 15.00 47.70 10000 1000
7.50E+00 28.47 15.00 47.70
7.50E+00 28.19 15.00 47.70
7.50E+00 18.34 15.00 47.70
7.50E+00 18.91 15.00 47.70
7.50E+00 29.23 15.00 47.70
7.50E+00 13.39 15.00 47.70
5.63E+01 5.36 15.00 47.70
1.85E+01 7.89 15.00 47.70
7.50E+00 10.66 15.00 47.70 10000 1000
7.50E+00 21.49 15.00 47.70
7.50E+00 10.39 15.00 47.70
7.50E+00 5.48 15.00 47.70
7.50E+00 9.04 15.00 47.70
7.50E+00 2.98 15.00 47.70
7.50E+00 15.40 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.25E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.72E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.14E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-459
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Si JaFS-LRef-1314-T01-D 1 5.26E+03
Si JaFS-LRef-1314-T02-D 1 2.92E+03
Si JaFS-LRef-1314-T03-D 1 2.33E+03
Si JaFS-LRef-1314-T04-D 1 2.06E+03
Si JaFS-LRef-1314-T05-D 1 1.82E+03
Si JaFS-LRef-1314-T06-D 1 1.94E+03
Si JaFS-LRef-1314-T07-D 1 1.73E+03
Si JaFS-LRef-1314-T08-D 1 1.84E+03
Si JaFS-LRef-1314-T09-D 1 2.00E+03
Si JaFS-LRef-1314-T01-E 1 4.95E+03
Si JaFS-LRef-1314-T02-E 1 3.22E+03
Si JaFS-LRef-1314-T03-E 1 2.32E+03
Si JaFS-LRef-1314-T04-E 1 2.06E+03
Si JaFS-LRef-1314-T05-E 1 1.92E+03
Si JaFS-LRef-1314-T06-E 1 1.74E+03
Si JaFS-LRef-1314-T07-E 1 1.66E+03
Si JaFS-LRef-1314-T08-E 1 1.79E+03
Si JaFS-LRef-1314-T09-E 1 1.91E+03
Si JaFS-LRef-1314-T01-F 1 5.26E+03
Si JaFS-LRef-1314-T02-F 1 3.00E+03
Si JaFS-LRef-1314-T03-F 1 2.20E+03
Si JaFS-LRef-1314-T04-F 1 1.98E+03
Si JaFS-LRef-1314-T05-F 1 1.78E+03
Si JaFS-LRef-1314-T06-F 1 1.80E+03
Si JaFS-LRef-1314-T07-F 1 1.73E+03
Si JaFS-LRef-1314-T08-F 1 1.73E+03
Si JaFS-LRef-1314-T09-F 1 1.96E+03
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.26E+03 1.02 1.10 3.50
2.92E+03 0.80 1.10 3.50
2.33E+03 3.08 1.10 3.50 10000 1000
2.06E+03 0.36 1.10 3.50
1.82E+03 0.87 1.10 3.50
1.94E+03 1.39 1.10 3.50
1.73E+03 0.58 1.10 3.50
1.84E+03 2.50 1.10 3.50
2.00E+03 1.52 1.10 3.50
4.95E+03 1.36 1.10 3.50
3.22E+03 2.43 1.10 3.50
2.32E+03 1.06 1.10 3.50 10000 1000
2.06E+03 1.35 1.10 3.50
1.92E+03 2.35 1.10 3.50
1.74E+03 1.58 1.10 3.50
1.66E+03 1.35 1.10 3.50
1.79E+03 1.39 1.10 3.50
1.91E+03 1.49 1.10 3.50
5.26E+03 1.66 1.10 3.50
3.00E+03 1.56 1.10 3.50
2.20E+03 2.71 1.10 3.50 10000 1000
1.98E+03 1.31 1.10 3.50
1.78E+03 2.46 1.10 3.50
1.80E+03 0.81 1.10 3.50
1.73E+03 1.32 1.10 3.50
1.73E+03 1.14 1.10 3.50
1.96E+03 1.77 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.34E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.26E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.11E+03 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 131 4 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-460
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Na JaFS-LRef-1314-T01-D 1 2.23E+05
Na JaFS-LRef-1314-T02-D 1 7.80E+04
Na JaFS-LRef-1314-T03-D 1 3.62E+04
Na JaFS-LRef-1314-T04-D 1 1.32E+04
Na JaFS-LRef-1314-T05-D 1 5.21E+03
Na JaFS-LRef-1314-T06-D 1 1.94E+03
Na JaFS-LRef-1314-T07-D 1 8.76E+02
Na JaFS-LRef-1314-T08-D 1 5.13E+02
Na JaFS-LRef-1314-T09-D 1 3.99E+02
Na JaFS-LRef-1314-T01-E 1 2.21E+05
Na JaFS-LRef-1314-T02-E 1 8.02E+04
Na JaFS-LRef-1314-T03-E 1 3.60E+04
Na JaFS-LRef-1314-T04-E 1 1.29E+04
Na JaFS-LRef-1314-T05-E 1 5.32E+03
Na JaFS-LRef-1314-T06-E 1 2.22E+03
Na JaFS-LRef-1314-T07-E 1 9.31 E+02
Na JaFS-LRef-1314-T08-E 1 5.31 E+02
Na JaFS-LRef-1314-T09-E 1 3.49E+02
Na JaFS-LRef-1314-T01-F 1 2.24E+05
Na JaFS-LRef-1314-T02-F 1 8.29E+04
Na JaFS-LRef-1314-T03-F 1 3.46E+04
Na JaFS-LRef-1314-T04-F 1 1.28E+04
Na JaFS-LRef-1314-T05-F 1 5.20E+03
Na JaFS-LRef-1314-T06-F 1 1.92E+03
Na JaFS-LRef-1314-T07-F 1 1.01E+03
Na JaFS-LRef-1314-T08-F 1 6.27E+02
Na JaFS-LRef-1314-T09-F 1 4.23E+02
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.23E+05 0.64 2.50 8.00
7.80E+04 0.47 2.50 8.00
3.62E+04 1.32 2.50 8.00 10000 1000
1.32E+04 0.51 2.50 8.00
5.21 E+03 1.05 2.50 8.00
1.94E+03 0.87 2.50 8.00
8.76E+02 0.32 2.50 8.00
5.13E+02 1.09 2.50 8.00
3.99E+02 0.56 2.50 8.00
2.21 E+05 0.64 2.50 8.00
8.02E+04 0.12 2.50 8.00
3.60E+04 0.58 2.50 8.00 10000 1000
1.29E+04 0.36 2.50 8.00
5.32E+03 0.50 2.50 8.00
2.22E+03 1.02 2.50 8.00
9.31 E+02 1.27 2.50 8.00
5.31 E+02 0.87 2.50 8.00
3.49E+02 0.36 2.50 8.00
2.24E+05 0.53 2.50 8.00
8.29E+04 1.54 2.50 8.00
3.46E+04 0.65 2.50 8.00 10000 1000
1.28E+04 0.89 2.50 8.00
5.20E+03 0.53 2.50 8.00
1.92E+03 0.64 2.50 8.00
1.01 E+03 0.88 2.50 8.00
6.27E+02 0.80 2.50 8.00
4.23E+02 1.49 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.71E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.69E+04 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.55E+04 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-461
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Sr JaFS-LRef-1314-T01-D 1 9.47E+03
Sr JaFS-LRef-1314-T02-D 1 1.15E+03
Sr JaFS-LRef-1314-T03-D 1 5.27E+02
Sr JaFS-LRef-1314-T04-D 1 4.73E+02
Sr JaFS-LRef-1314-T05-D 1 4.52E+02
Sr JaFS-LRef-1314-T06-D 1 3.48E+02
Sr JaFS-LRef-1314-T07-D 1 2.83E+02
Sr JaFS-LRef-1314-T08-D 1 2.45E+02
Sr JaFS-LRef-1314-T09-D 1 2.57E+02
Sr JaFS-LRef-1314-T01-E 1 9.43E+03
Sr JaFS-LRef-1314-T02-E 1 1.20E+03
Sr JaFS-LRef-1314-T03-E 1 5.01E+02
Sr JaFS-LRef-1314-T04-E 1 4.70E+02
Sr JaFS-LRef-1314-T05-E 1 4.32E+02
Sr JaFS-LRef-1314-T06-E 1 3.35E+02
Sr JaFS-LRef-1314-T07-E 1 2.81E+02
Sr JaFS-LRef-1314-T08-E 1 2.47E+02
Sr JaFS-LRef-1314-T09-E 1 2.50E+02
Sr JaFS-LRef-1314-T01-F 1 9.50E+03
Sr JaFS-LRef-1314-T02-F 1 1.17E+03
Sr JaFS-LRef-1314-T03-F 1 4.93E+02
Sr JaFS-LRef-1314-T04-F 1 4.63E+02
Sr JaFS-LRef-1314-T05-F 1 4.28E+02
Sr JaFS-LRef-1314-T06-F 1 3.26E+02
Sr JaFS-LRef-1314-T07-F 1 2.66E+02
Sr JaFS-LRef-1314-T08-F 1 2.47E+02
Sr JaFS-LRef-1314-T09-F 1 2.52E+02
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.47E+03 1.78 1.00 3.18
1.15E+03 1.50 1.00 3.18
5.27E+02 2.86 1.00 3.18 10000 1000
4.73E+02 0.40 1.00 3.18
4.52E+02 0.26 1.00 3.18
3.48E+02 2.00 1.00 3.18
2.83E+02 1.36 1.00 3.18
2.45E+02 2.75 1.00 3.18
2.57E+02 1.11 1.00 3.18
9.43E+03 0.74 1.00 3.18
1.20E+03 2.08 1.00 3.18
5.01E+02 0.78 1.00 3.18 10000 1000
4.70E+02 1.39 1.00 3.18
4.32E+02 2.37 1.00 3.18
3.35E+02 1.68 1.00 3.18
2.81E+02 1.65 1.00 3.18
2.47E+02 0.80 1.00 3.18
2.50E+02 1.93 1.00 3.18
9.50E+03 2.05 1.00 3.18
1.17E+03 1.64 1.00 3.18
4.93E+02 2.50 1.00 3.18 10000 1000
4.63E+02 0.77 1.00 3.18
4.28E+02 2.60 1.00 3.18
3.26E+02 0.81 1.00 3.18
2.66E+02 1.24 1.00 3.18
2.47E+02 1.78 1.00 3.18
2.52E+02 1.64 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.53E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.45E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.48E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-462
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
S JaFS-LRef-1314-T01-D 1 6.28E+05
S JaFS-LRef-1314-T02-D 1 5.29E+04
S JaFS-LRef-1314-T03-D 1 1.17E+04
S JaFS-LRef-1314-T04-D 1 7.67E+03
S JaFS-LRef-1314-T05-D 1 6.59E+03
S JaFS-LRef-1314-T06-D 1 4.31 E+03
S JaFS-LRef-1314-T07-D 1 3.26E+03
S JaFS-LRef-1314-T08-D 1 2.72E+03
S JaFS-LRef-1314-T09-D 1 1.54E+03
S JaFS-LRef-1314-T01-E 1 6.34E+05
S JaFS-LRef-1314-T02-E 1 6.29E+04
S JaFS-LRef-1314-T03-E 1 1.15E+04
S JaFS-LRef-1314-T04-E 1 8.26E+03
S JaFS-LRef-1314-T05-E 1 6.38E+03
S JaFS-LRef-1314-T06-E 1 4.57E+03
S JaFS-LRef-1314-T07-E 1 3.65E+03
S JaFS-LRef-1314-T08-E 1 2.61E+03
S JaFS-LRef-1314-T09-E 1 1.43E+03
S JaFS-LRef-1314-T01-F 1 6.21E+05
S JaFS-LRef-1314-T02-F 1 6.72E+04
S JaFS-LRef-1314-T03-F 1 1.12E+04
S JaFS-LRef-1314-T04-F 1 8.31 E+03
S JaFS-LRef-1314-T05-F 1 6.27E+03
S JaFS-LRef-1314-T06-F 1 4.46E+03
S JaFS-LRef-1314-T07-F 1 3.36E+03
S JaFS-LRef-1314-T08-F 1 2.65E+03
S JaFS-LRef-1314-T09-F 1 1.30E+03
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.28E+05 0.84 6.80 21.60
5.29E+04 1.11 6.80 21.60
1.17E+04 3.31 6.80 21.60 10000 1000
7.67E+03 0.68 6.80 21.60
6.59E+03 1.07 6.80 21.60
4.31 E+03 1.40 6.80 21.60
3.26E+03 1.29 6.80 21.60
2.72E+03 2.55 6.80 21.60
1.54E+03 1.54 6.80 21.60
6.34E+05 1.48 6.80 21.60
6.29E+04 2.14 6.80 21.60
1.15E+04 0.91 6.80 21.60 10000 1000
8.26E+03 0.71 6.80 21.60
6.38E+03 3.03 6.80 21.60
4.57E+03 1.75 6.80 21.60
3.65E+03 1.93 6.80 21.60
2.61 E+03 1.58 6.80 21.60
1.43E+03 2.87 6.80 21.60
6.21E+05 1.56 6.80 21.60
6.72E+04 1.92 6.80 21.60
1.12E+04 3.14 6.80 21.60 10000 1000
8.31E+03 1.43 6.80 21.60
6.27E+03 2.72 6.80 21.60
4.46E+03 2.53 6.80 21.60
3.36E+03 2.55 6.80 21.60
2.65E+03 0.83 6.80 21.60
1.30E+03 0.36 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.26E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.24E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.21E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-463
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Tl JaFS-LRef-1314-T01-D 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T02-D 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T03-D 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T04-D 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T05-D 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T06-D 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T07-D 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T08-D 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T09-D 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T01-E 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T02-E 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T03-E 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T04-E 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T05-E 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T06-E 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T07-E 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T08-E 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T09-E 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T01-F 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T02-F 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T03-F 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T04-F 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T05-F 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T06-F 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T07-F 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T08-F 1 2.30E+00 U1/2
Tl JaFS-LRef-1314-T09-F 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 11.38 4.60 14.60
2.30E+00 55.72 4.60 14.60
2.30E+00 5.45 4.60 14.60 10000 1000
2.30E+00 25.39 4.60 14.60
2.30E+00 9.90 4.60 14.60
2.30E+00 10.02 4.60 14.60
2.30E+00 16.90 4.60 14.60
2.30E+00 31.87 4.60 14.60
2.30E+00 54.11 4.60 14.60
2.30E+00 74.88 4.60 14.60
2.30E+00 74.86 4.60 14.60
2.30E+00 39.38 4.60 14.60 10000 1000
2.30E+00 46.74 4.60 14.60
2.30E+00 24.25 4.60 14.60
2.30E+00 31.55 4.60 14.60
2.30E+00 30.69 4.60 14.60
2.30E+00 13.93 4.60 14.60
2.30E+00 88.35 4.60 14.60
2.30E+00 7.59 4.60 14.60
2.30E+00 48.77 4.60 14.60
2.30E+00 59.90 4.60 14.60 10000 1000
2.30E+00 66.00 4.60 14.60
2.30E+00 20.81 4.60 14.60
2.30E+00 26.87 4.60 14.60
2.30E+00 9.56 4.60 14.60
2.30E+00 3.18 4.60 14.60
2.30E+00 18.51 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.35E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.33E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.66E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/11 1:51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-464
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Ti JaFS-LRef-1314-T01-D 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T02-D 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T03-D 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T04-D 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T05-D 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T06-D 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T07-D 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T08-D 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T09-D 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T01-E 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T02-E 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T03-E 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T04-E 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T05-E 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T06-E 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T07-E 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T08-E 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T09-E 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T01-F 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T02-F 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T03-F 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T04-F 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T05-F 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T06-F 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T07-F 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T08-F 1 1.00E+00 U1/2
Ti JaFS-LRef-1314-T09-F 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 62.15 2.00 6.40
1.00E+00 40.15 2.00 6.40
1.00E+00 41.39 2.00 6.40 10000 1000
1.00E+00 43.41 2.00 6.40
1.00E+00 39.01 2.00 6.40
1.00E+00 57.27 2.00 6.40
1.00E+00 29.96 2.00 6.40
1.00E+00 38.85 2.00 6.40
1.00E+00 39.14 2.00 6.40
1.00E+00 10.65 2.00 6.40
1.00E+00 39.30 2.00 6.40
1.00E+00 43.88 2.00 6.40 10000 1000
1.00E+00 8.40 2.00 6.40
1.00E+00 12.91 2.00 6.40
1.00E+00 41.99 2.00 6.40
1.00E+00 11.21 2.00 6.40
1.00E+00 24.19 2.00 6.40
1.00E+00 12.46 2.00 6.40
1.00E+00 40.83 2.00 6.40
1.00E+00 52.65 2.00 6.40
1.00E+00 85.70 2.00 6.40 10000 1000
1.00E+00 18.21 2.00 6.40
1.00E+00 40.67 2.00 6.40
1.00E+00 51.12 2.00 6.40
1.00E+00 12.40 2.00 6.40
1.00E+00 2.91 2.00 6.40
1.00E+00 10.48 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.05E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.45E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.60E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-465
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
V JaFS-LRef-1314-T01-D 1 1.90E+01
V JaFS-LRef-1314-T02-D 1 3.47E+00 E
V JaFS-LRef-1314-T03-D 1 1.81E+00 E
V JaFS-LRef-1314-T04-D 1 7.50E-01 U1/2
V JaFS-LRef-1314-T05-D 1 7.50E-01 U1/2
V JaFS-LRef-1314-T06-D 1 7.50E-01 U1/2
V JaFS-LRef-1314-T07-D 1 7.50E-01 U1/2
V JaFS-LRef-1314-T08-D 1 7.50E-01 U1/2
V JaFS-LRef-1314-T09-D 1 7.50E-01 U1/2
V JaFS-LRef-1314-T01-E 1 1.90E+01
V JaFS-LRef-1314-T02-E 1 3.54E+00 E
V JaFS-LRef-1314-T03-E 1 2.91E+00 E
V JaFS-LRef-1314-T04-E 1 7.50E-01 U1/2
V JaFS-LRef-1314-T05-E 1 7.50E-01 U1/2
V JaFS-LRef-1314-T06-E 1 7.50E-01 U1/2
V JaFS-LRef-1314-T07-E 1 7.50E-01 U1/2
V JaFS-LRef-1314-T08-E 1 7.50E-01 U1/2
V JaFS-LRef-1314-T09-E 1 7.50E-01 U1/2
V JaFS-LRef-1314-T01-F 1 1.86E+01
V JaFS-LRef-1314-T02-F 1 3.56E+00 E
V JaFS-LRef-1314-T03-F 1 2.60E+00 E
V JaFS-LRef-1314-T04-F 1 7.50E-01 U1/2
V JaFS-LRef-1314-T05-F 1 7.50E-01 U1/2
V JaFS-LRef-1314-T06-F 1 7.50E-01 U1/2
V JaFS-LRef-1314-T07-F 1 7.50E-01 U1/2
V JaFS-LRef-1314-T08-F 1 7.50E-01 U1/2
V JaFS-LRef-1314-T09-F 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.90E+01 9.93 1.50 4.77
3.47E+00 20.90 1.50 4.77
1.81E+00 10.37 1.50 4.77 10000 1000
7.50E-01 31.67 1.50 4.77
7.50E-01 12.08 1.50 4.77
7.50E-01 58.65 1.50 4.77
7.50E-01 9.91 1.50 4.77
7.50E-01 19.05 1.50 4.77
7.50E-01 28.14 1.50 4.77
1.90E+01 2.94 1.50 4.77
3.54E+00 11.39 1.50 4.77
2.91E+00 25.02 1.50 4.77 10000 1000
7.50E-01 27.18 1.50 4.77
7.50E-01 36.74 1.50 4.77
7.50E-01 32.32 1.50 4.77
7.50E-01 27.95 1.50 4.77
7.50E-01 39.67 1.50 4.77
7.50E-01 6.26 1.50 4.77
1.86E+01 3.51 1.50 4.77
3.56E+00 5.01 1.50 4.77
2.60E+00 35.34 1.50 4.77 10000 1000
7.50E-01 35.42 1.50 4.77
7.50E-01 17.73 1.50 4.77
7.50E-01 10.54 1.50 4.77
7.50E-01 21.49 1.50 4.77
7.50E-01 3.74 1.50 4.77
7.50E-01 15.75 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.93E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.23E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.47E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/11 1:41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-466
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Zn JaFS-LRef-1314-T01-D 1 1.83E+03
Zn JaFS-LRef-1314-T02-D 1 4.59E+02
Zn JaFS-LRef-1314-T03-D 1 2.54E+02
Zn JaFS-LRef-1314-T04-D 1 1.76E+02
Zn JaFS-LRef-1314-T05-D 1 8.22E+01
Zn JaFS-LRef-1314-T06-D 1 7.18E+01
Zn JaFS-LRef-1314-T07-D 1 4.92E+01
Zn JaFS-LRef-1314-T08-D 1 3.09E+01
Zn JaFS-LRef-1314-T09-D 1 2.36E+01
Zn JaFS-LRef-1314-T01-E 1 1.80E+03
Zn JaFS-LRef-1314-T02-E 1 4.02E+02
Zn JaFS-LRef-1314-T03-E 1 2.41E+02
Zn JaFS-LRef-1314-T04-E 1 1.71E+02
Zn JaFS-LRef-1314-T05-E 1 1.37E+02
Zn JaFS-LRef-1314-T06-E 1 7.52E+01
Zn JaFS-LRef-1314-T07-E 1 4.97E+01
Zn JaFS-LRef-1314-T08-E 1 3.07E+01
Zn JaFS-LRef-1314-T09-E 1 3.52E+01
Zn JaFS-LRef-1314-T01-F 1 1.91E+03
Zn JaFS-LRef-1314-T02-F 1 4.16E+02
Zn JaFS-LRef-1314-T03-F 1 2.21E+02
Zn JaFS-LRef-1314-T04-F 1 1.77E+02
Zn JaFS-LRef-1314-T05-F 1 1.43E+02
Zn JaFS-LRef-1314-T06-F 1 6.88E+01
Zn JaFS-LRef-1314-T07-F 1 5.43E+01
Zn JaFS-LRef-1314-T08-F 1 2.82E+01
Zn JaFS-LRef-1314-T09-F 1 2.96E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.83E+03 2.05 1.00 3.18
4.59E+02 1.40 1.00 3.18
2.54E+02 3.11 1.00 3.18 10000 1000
1.76E+02 0.38 1.00 3.18
8.22E+01 0.41 1.00 3.18
7.18E+01 1.97 1.00 3.18
4.92E+01 1.00 1.00 3.18
3.09E+01 2.32 1.00 3.18
2.36E+01 1.48 1.00 3.18
1.80E+03 0.87 1.00 3.18
4.02E+02 2.49 1.00 3.18
2.41E+02 0.87 1.00 3.18 10000 1000
1.71E+02 1.78 1.00 3.18
1.37E+02 2.20 1.00 3.18
7.52E+01 2.63 1.00 3.18
4.97E+01 1.35 1.00 3.18
3.07E+01 1.83 1.00 3.18
3.52E+01 1.34 1.00 3.18
1.91E+03 1.84 1.00 3.18
4.16E+02 1.94 1.00 3.18
2.21E+02 3.41 1.00 3.18 10000 1000
1.77E+02 1.11 1.00 3.18
1.43E+02 3.08 1.00 3.18
6.88E+01 0.99 1.00 3.18
5.43E+01 2.48 1.00 3.18
2.82E+01 2.52 1.00 3.18
2.96E+01 3.22 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.18E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.11E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/2/1 1 1 :30 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :31 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :33 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :35 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :36 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :38 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :40 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :41 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :43 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :45 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :46 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :48 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :50 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :51 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :53 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :55 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :56 PM EPA Interlab LRef 1314 JaFS
9/2/1 1 1 :58 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:06 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:08 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:09 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:11 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:13 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:14 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:16 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:18 PM EPA Interlab LRef 1314 JaFS
9/2/11 2:19 PM EPA Interlab LRef 1314 JaFS
1-467
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1315:
Dilut
Element Sample ID Fact
Al SWA-L01-1315-T01-A
Al SWA-L01-1315-T02-A
Al SWA-L01-1315-T03-A
Al SWA-L01-1315-T04-A
Al SWA-L01-1315-T05-A
Al SWA-L01-1315-T06-A
Al SWA-L01-1315-T07-A
Al SWA-L01-1315-T08-A
Al SWA-L01-1315-T09-A
Al SWA-L01-1315-T01-B
Al SWA-L01-1315-T02-B
Al SWA-L01-1315-T03-B
Al SWA-L01-1315-T04-B
Al SWA-L01-1315-T05-B
Al SWA-L01-1315-T06-B
Al SWA-L01-1315-T07-B
Al SWA-L01-1315-T08-B
Al SWA-L01-1315-T09-B
Al SWA-L01-1315-T01-C
Al SWA-L01-1315-T02-C
Al SWA-L01-1315-T03-C
Al SWA-L01-1315-T04-C
Al SWA-L01-1315-T05-C
Al SWA-L01-1315-T06-C
Al SWA-L01-1315-T07-C
Al SWA-L01-1315-T08-C
Al SWA-L01-1315-T09-C
Al SWA-L01-1315-M01-A
Al SWA-L01-1315-M02-A
Al SWA-L01-1315-M03-A
Al SWA-L01-1315-M04-A
Al SWA-L01-1315-M05-A
Al SWA-L01-1315-M06-A
Al SWA-L01-1315-M07-A
Al SWA-L01-1315-M08-A
Al SWA-L01-1315-M09-A
on Sample
or Cone. Quallf
ug/L
1 9.33E+02
1 4.35E+03
1 2.38E+03
1 5.39E+03
1 4.75E+03
1 5.29E+03
1 4.52E+03
1 3.05E+03
1 3.77E+03
1 9.95E+02
1 5.18E+03
1 3.17E+03
1 4.31 E+03
1 5.38E+03
1 5.84E+03
1 4.89E+03
1 3.19E+03
1 4.05E+03
1 1.03E+03
1 6.07E+03
1 3.25E+03
1 6.78E+03
1 5.85E+03
1 6.47E+03
1 5.38E+03
1 3.52E+03
1 4.51 E+03
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
er Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.33E+02 0.31 1.00 3.18
4.35E+03 0.52 1.00 3.18
2.38E+03 0.15 1.00 3.18 10000 1000
5.39E+03 0.20 1.00 3.18
4.75E+03 0.83 1.00 3.18
5.29E+03 0.23 1.00 3.18
4.52E+03 0.44 1.00 3.18
3.05E+03 0.78 1.00 3.18
3.77E+03 1.26 1.00 3.18
9.95E+02 0.19 1.00 3.18
5.18E+03 0.31 1.00 3.18
3.17E+03 0.62 1.00 3.18 10000 1000
4.31E+03 1.61 1.00 3.18
5.38E+03 0.79 1.00 3.18
5.84E+03 0.82 1.00 3.18
4.89E+03 0.39 1.00 3.18
3.19E+03 1.41 1.00 3.18
4.05E+03 1.02 1.00 3.18
1.03E+03 0.44 1.00 3.18
6.07E+03 0.71 1.00 3.18
3.25E+03 1.36 1.00 3.18 10000 1000
6.78E+03 0.79 1.00 3.18
5.85E+03 0.32 1.00 3.18
6.47E+03 0.25 1.00 3.18
5.38E+03 0.02 1.00 3.18
3.52E+03 0.56 1.00 3.18
4.51E+03 0.41 1.00 3.18
5.00E-01 6.12 1.00 3.18
5.00E-01 5.09 1.00 3.18
5.00E-01 2.60 1.00 3.18
5.00E-01 6.64 1.00 3.18
5.00E-01 12.11 1.00 3.18
5.00E-01 2.14 1.00 3.18
5.00E-01 7.30 1.00 3.18
5.00E-01 5.65 1.00 3.18
5.00E-01 4.23 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.32E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.12E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.18E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-468
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Sb SWA-L01-1315-T01-A 1 1.27E+02
Sb SWA-L01-1315-T02-A 1 4.81E+02
Sb SWA-L01-1315-T03-A 1 2.80E+02
Sb SWA-L01-1315-T04-A 1 4.54E+02
Sb SWA-L01-1315-T05-A 1 3.92E+02
Sb SWA-L01-1315-T06-A 1 3.74E+02
Sb SWA-L01-1315-T07-A 1 3.02E+02
Sb SWA-L01-1315-T08-A 1 2.51E+02
Sb SWA-L01-1315-T09-A 1 2.56E+02
Sb SWA-L01-1315-T01-B 1 1.38E+02
Sb SWA-L01-1315-T02-B 1 4.82E+02
Sb SWA-L01-1315-T03-B 1 2.82E+02
Sb SWA-L01-1315-T04-B 1 4.67E+02
Sb SWA-L01-1315-T05-B 1 4.14E+02
Sb SWA-L01-1315-T06-B 1 4.15E+02
Sb SWA-L01-1315-T07-B 1 3.20E+02
Sb SWA-L01-1315-T08-B 1 2.54E+02
Sb SWA-L01-1315-T09-B 1 2.65E+02
Sb SWA-L01-1315-T01-C 1 1.39E+02
Sb SWA-L01-1315-T02-C 1 4.72E+02
Sb SWA-L01-1315-T03-C 1 2.87E+02
Sb SWA-L01-1315-T04-C 1 4.61E+02
Sb SWA-L01-1315-T05-C 1 4.09E+02
Sb SWA-L01-1315-T06-C 1 3.25E+02
Sb SWA-L01-1315-T07-C 1 3.22E+02
Sb SWA-L01-1315-T08-C 1 2.41E+02
Sb SWA-L01-1315-T09-C 1 2.54E+02
Sb SWA-L01-1315-M01-A 1 3.75E+00 U1/2
Sb SWA-L01-1315-M02-A 1 3.75E+00 U1/2
Sb SWA-L01-1315-M03-A 1 3.75E+00 U1/2
Sb SWA-L01-1315-M04-A 1 3.75E+00 U1/2
Sb SWA-L01-1315-M05-A 1 3.75E+00 U1/2
Sb SWA-L01-1315-M06-A 1 3.75E+00 U1/2
Sb SWA-L01-1315-M07-A 1 3.75E+00 U1/2
Sb SWA-L01-1315-M08-A 1 3.75E+00 U1/2
Sb SWA-L01-1315-M09-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.27E+02 1.39 7.50 23.90
4.81 E+02 0.34 7.50 23.90
2.80E+02 1.72 7.50 23.90 10000 1000
4.54E+02 1.55 7.50 23.90
3.92E+02 2.75 7.50 23.90
3.74E+02 1.68 7.50 23.90
3.02E+02 0.85 7.50 23.90
2.51 E+02 3.97 7.50 23.90
2.56E+02 3.66 7.50 23.90
1.38E+02 4.08 7.50 23.90
4.82E+02 1.48 7.50 23.90
2.82E+02 1.86 7.50 23.90 10000 1000
4.67E+02 1.99 7.50 23.90
4.14E+02 1.46 7.50 23.90
4.15E+02 2.12 7.50 23.90
3.20E+02 2.38 7.50 23.90
2.54E+02 9.46 7.50 23.90
2.65E+02 1.08 7.50 23.90
1.39E+02 6.04 7.50 23.90
4.72E+02 0.94 7.50 23.90
2.87E+02 0.69 7.50 23.90 10000 1000
4.61E+02 1.68 7.50 23.90
4.09E+02 1.34 7.50 23.90
3.25E+02 1.59 7.50 23.90
3.22E+02 1.51 7.50 23.90
2.41E+02 2.67 7.50 23.90
2.54E+02 3.56 7.50 23.90
3.75E+00 65.29 7.50 23.90
3.75E+00 57.61 7.50 23.90
3.75E+00 53.36 7.50 23.90
3.75E+00 38.43 7.50 23.90
3.75E+00 96.50 7.50 23.90
3.75E+00 41.06 7.50 23.90
3.75E+00 43.59 7.50 23.90
3.75E+00 45.29 7.50 23.90
3.75E+00 39.83 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.43E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.41E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.44E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/25/12 11:48 AM EPA Interlab L01 1315SWA
1/25/12 11:50 AM EPA Interlab L01 1315SWA
1/25/12 11:51 AM EPA Interlab L01 1315SWA
1/25/12 11:53 AM EPA Interlab L01 1315 SWA
1/25/12 11:55 AM EPA Interlab L01 1315 SWA
1/25/12 11:56 AM EPA Interlab L01 1315 SWA
1/25/12 11:58 AM EPA Interlab L01 1315 SWA
1/25/12 12:00 PM EPA Interlab L01 1315 SWA
1/25/12 12:01 PM EPA Interlab L01 1315 SWA
1/25/12 12:06 PM EPA Interlab L01 1315 SWA
1/25/12 12:08 PM EPA Interlab L01 1315 SWA
1/25/12 12:09 PM EPA Interlab L01 1315 SWA
1/25/1212:11 PM EPA Interlab L01 1315 SWA
1/25/12 12:13 PM EPA Interlab L01 1315 SWA
1/25/12 12:14 PM EPA Interlab L01 1315 SWA
1/25/12 12:16 PM EPA Interlab L01 1315 SWA
1/25/12 12:18 PM EPA Interlab L01 1315 SWA
1/25/12 12:19 PM EPA Interlab L01 1315 SWA
1/25/12 12:21 PM EPA Interlab L01 1315 SWA
1/25/12 12:23 PM EPA Interlab L01 1315 SWA
1/25/12 12:24 PM EPA Interlab L01 1315 SWA
1/25/12 12:26 PM EPA Interlab L01 1315 SWA
1/25/12 12:27 PM EPA Interlab L01 1315 SWA
1/25/12 12:29 PM EPA Interlab L01 1315 SWA
1/25/12 12:31 PM EPA Interlab L01 1315 SWA
1/25/12 12:32 PM EPA Interlab L01 1315 SWA
1/25/12 12:34 PM EPA Interlab L01 1315 SWA
1/25/12 11:33 AM EPA Interlab L01 1315 SWA
1/25/12 11:35 AM EPA Interlab L01 1315 SWA
1/25/12 11:36 AM EPA Interlab L01 1315 SWA
1/25/12 11:38 AM EPA Interlab L01 1315 SWA
1/25/12 11:40 AM EPA Interlab L01 1315 SWA
1/25/1211:41 AM EPA Interlab L01 1315 SWA
1/25/12 11:43 AM EPA Interlab L01 1315 SWA
1/25/12 11:45 AM EPA Interlab L01 1315 SWA
1/25/12 11:46 AM EPA Interlab L01 1315 SWA
1-469
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
As SWA-L01-1315-T01-A 1 1.44E+02
As SWA-L01-1315-T02-A 1 2.69E+02
As SWA-L01-1315-T03-A 1 9.14E+01
As SWA-L01-1315-T04-A 1 1.85E+02
As SWA-L01-1315-T05-A 1 1.37E+02
As SWA-L01-1315-T06-A 1 1.40E+02
As SWA-L01-1315-T07-A 1 8.84E+01
As SWA-L01-1315-T08-A 1 6.66E+01
As SWA-L01-1315-T09-A 1 7.90E+01
As SWA-L01-1315-T01-B 1 1.52E+02
As SWA-L01-1315-T02-B 1 3.16E+02
As SWA-L01-1315-T03-B 1 1.34E+02
As SWA-L01-1315-T04-B 1 1.65E+02
As SWA-L01-1315-T05-B 1 1.55E+02
As SWA-L01-1315-T06-B 1 1.58E+02
As SWA-L01-1315-T07-B 1 1.07E+02
As SWA-L01-1315-T08-B 1 7.68E+01
As SWA-L01-1315-T09-B 1 8.15E+01
As SWA-L01-1315-T01-C 1 2.18E+02
As SWA-L01-1315-T02-C 1 4.88E+02
As SWA-L01-1315-T03-C 1 1.43E+02
As SWA-L01-1315-T04-C 1 2.55E+02
As SWA-L01-1315-T05-C 1 1.76E+02
As SWA-L01-1315-T06-C 1 1.75E+02
As SWA-L01-1315-T07-C 1 1.32E+02
As SWA-L01-1315-T08-C 1 7.56E+01
As SWA-L01-1315-T09-C 1 1.01E+02
As SWA-L01-1315-M01-A 1 5.50E+00 U1/2
As SWA-L01-1315-M02-A 1 5.50E+00 U1/2
As SWA-L01-1315-M03-A 1 5.50E+00 U1/2
As SWA-L01-1315-M04-A 1 5.50E+00 U1/2
As SWA-L01-1315-M05-A 1 5.50E+00 U1/2
As SWA-L01-1315-M06-A 1 5.50E+00 U1/2
As SWA-L01-1315-M07-A 1 5.50E+00 U1/2
As SWA-L01-1315-M08-A 1 5.50E+00 U1/2
As SWA-L01-1315-M09-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.44E+02 5.36 11.00 35.00
2.69E+02 4.17 11.00 35.00
9.14E+01 7.70 11.00 35.00 10000 1000
1.85E+02 2.51 11.00 35.00
1.37E+02 6.93 11.00 35.00
1.40E+02 7.25 11.00 35.00
8.84E+01 7.31 11.00 35.00
6.66E+01 5.12 11.00 35.00
7.90E+01 2.81 11.00 35.00
1.52E+02 4.36 11.00 35.00
3.16E+02 1.08 11.00 35.00
1.34E+02 4.13 11.00 35.00 10000 1000
1.65E+02 3.88 11.00 35.00
1.55E+02 1.46 11.00 35.00
1.58E+02 4.66 11.00 35.00
1.07E+02 5.28 11.00 35.00
7.68E+01 10.09 11.00 35.00
8.15E+01 2.90 11.00 35.00
2.18E+02 3.30 11.00 35.00
4.88E+02 1.36 11.00 35.00
1.43E+02 4.03 11.00 35.00 10000 1000
2.55E+02 1.12 11.00 35.00
1.76E+02 2.17 11.00 35.00
1.75E+02 6.70 11.00 35.00
1.32E+02 3.81 11.00 35.00
7.56E+01 12.49 11.00 35.00
1.01E+02 3.83 11.00 35.00
5.50E+00 47.46 11.00 35.00
5.50E+00 42.35 11.00 35.00
5.50E+00 11.96 11.00 35.00
5.50E+00 18.01 11.00 35.00
5.50E+00 33.68 11.00 35.00
5.50E+00 16.39 11.00 35.00
5.50E+00 23.95 11.00 35.00
5.50E+00 35.96 11.00 35.00
5.50E+00 32.10 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.19E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-470
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
B SWA-L01-1315-T01-A 1 3.28E+01
B SWA-L01-1315-T02-A 1 9.55E+01
B SWA-L01-1315-T03-A 1 4.64E+01
B SWA-L01-1315-T04-A 1 1.07E+02
B SWA-L01-1315-T05-A 1 8.29E+01
B SWA-L01-1315-T06-A 1 9.76E+01
B SWA-L01-1315-T07-A 1 7.90E+01
B SWA-L01-1315-T08-A 1 5.37E+01
B SWA-L01-1315-T09-A 1 7.23E+01
B SWA-L01-1315-T01-B 1 3.75E+01
B SWA-L01-1315-T02-B 1 9.11E+01
B SWA-L01-1315-T03-B 1 4.89E+01
B SWA-L01-1315-T04-B 1 6.65E+01
B SWA-L01-1315-T05-B 1 7.41E+01
B SWA-L01-1315-T06-B 1 8.46E+01
B SWA-L01-1315-T07-B 1 6.88E+01
B SWA-L01-1315-T08-B 1 4.98E+01
B SWA-L01-1315-T09-B 1 6.74E+01
B SWA-L01-1315-T01-C 1 4.98E+01
B SWA-L01-1315-T02-C 1 1.38E+02
B SWA-L01-1315-T03-C 1 5.88E+01
B SWA-L01-1315-T04-C 1 1.24E+02
B SWA-L01-1315-T05-C 1 9.65E+01
B SWA-L01-1315-T06-C 1 1.08E+02
B SWA-L01-1315-T07-C 1 8.57E+01
B SWA-L01-1315-T08-C 1 5.63E+01
B SWA-L01-1315-T09-C 1 7.58E+01
B SWA-L01-1315-M01-A 1 5.00E-01 U1/2
B SWA-L01-1315-M02-A 1 5.00E-01 U1/2
B SWA-L01-1315-M03-A 1 5.00E-01 U1/2
B SWA-L01-1315-M04-A 1 5.00E-01 U1/2
B SWA-L01-1315-M05-A 1 5.00E-01 U1/2
B SWA-L01-1315-M06-A 1 5.00E-01 U1/2
B SWA-L01-1315-M07-A 1 5.00E-01 U1/2
B SWA-L01-1315-M08-A 1 5.00E-01 U1/2
B SWA-L01-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.28E+01 5.33 1.00 3.18
9.55E+01 3.91 1.00 3.18
4.64E+01 1.30 1.00 3.18 10000 1000
1.07E+02 2.15 1.00 3.18
8.29E+01 4.05 1.00 3.18
9.76E+01 1.20 1.00 3.18
7.90E+01 0.83 1.00 3.18
5.37E+01 1.69 1.00 3.18
7.23E+01 1.36 1.00 3.18
3.75E+01 5.22 1.00 3.18
9.11E+01 2.07 1.00 3.18
4.89E+01 1.71 1.00 3.18 10000 1000
6.65E+01 3.46 1.00 3.18
7.41E+01 1.61 1.00 3.18
8.46E+01 0.68 1.00 3.18
6.88E+01 3.70 1.00 3.18
4.98E+01 2.58 1.00 3.18
6.74E+01 3.01 1.00 3.18
4.98E+01 1.32 1.00 3.18
1.38E+02 0.48 1.00 3.18
5.88E+01 1.87 1.00 3.18 10000 1000
1.24E+02 2.15 1.00 3.18
9.65E+01 1.62 1.00 3.18
1.08E+02 0.33 1.00 3.18
8.57E+01 2.01 1.00 3.18
5.63E+01 3.16 1.00 3.18
7.58E+01 3.18 1.00 3.18
5.00E-01 9.97 1.00 3.18
5.00E-01 1.94 1.00 3.18
5.00E-01 2.84 1.00 3.18
5.00E-01 2.16 1.00 3.18
5.00E-01 1.60 1.00 3.18
5.00E-01 2.64 1.00 3.18
5.00E-01 1.22 1.00 3.18
5.00E-01 2.45 1.00 3.18
5.00E-01 1.53 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.03E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.77E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-471
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
Ba SWA-L01-1315-T01-A 1 4.36E+00
Ba SWA-L01-1315-T02-A 1 7.35E+01
Ba SWA-L01-1315-T03-A 1 1.36E+02
Ba SWA-L01-1315-T04-A 1 2.59E+02
Ba SWA-L01-1315-T05-A 1 3.42E+02
Ba SWA-L01-1315-T06-A 1 3.96E+02
Ba SWA-L01-1315-T07-A 1 3.95E+02
Ba SWA-L01-1315-T08-A 1 4.36E+02
Ba SWA-L01-1315-T09-A 1 3.58E+02
Ba SWA-L01-1315-T01-B 1 7.73E+00
Ba SWA-L01-1315-T02-B 1 7.95E+01
Ba SWA-L01-1315-T03-B 1 1.26E+02
Ba SWA-L01-1315-T04-B 1 1.47E+02
Ba SWA-L01-1315-T05-B 1 3.05E+02
Ba SWA-L01-1315-T06-B 1 3.55E+02
Ba SWA-L01-1315-T07-B 1 3.86E+02
Ba SWA-L01-1315-T08-B 1 4.11E+02
Ba SWA-L01-1315-T09-B 1 3.56E+02
Ba SWA-L01-1315-T01-C 1 1.40E+01
Ba SWA-L01-1315-T02-C 1 8.91E+01
Ba SWA-L01-1315-T03-C 1 1.30E+02
Ba SWA-L01-1315-T04-C 1 2.30E+02
Ba SWA-L01-1315-T05-C 1 3.08E+02
Ba SWA-L01-1315-T06-C 1 3.39E+02
Ba SWA-L01-1315-T07-C 1 4.01E+02
Ba SWA-L01-1315-T08-C 1 4.08E+02
Ba SWA-L01-1315-T09-C 1 4.20E+02
Ba SWA-L01-1315-M01-A 1 5.00E-01 U1/2
Ba SWA-L01-1315-M02-A 1 5.00E-01 U1/2
Ba SWA-L01-1315-M03-A 1 5.00E-01 U1/2
Ba SWA-L01-1315-M04-A 1 5.00E-01 U1/2
Ba SWA-L01-1315-M05-A 1 5.00E-01 U1/2
Ba SWA-L01-1315-M06-A 1 5.00E-01 U1/2
Ba SWA-L01-1315-M07-A 1 5.00E-01 U1/2
Ba SWA-L01-1315-M08-A 1 5.00E-01 U1/2
Ba SWA-L01-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.36E+00 0.19 1.00 3.18
7.35E+01 0.50 1.00 3.18
1.36E+02 0.17 1.00 3.18 10000 1000
2.59E+02 0.93 1.00 3.18
3.42E+02 0.48 1.00 3.18
3.96E+02 0.27 1.00 3.18
3.95E+02 0.69 1.00 3.18
4.36E+02 0.82 1.00 3.18
3.58E+02 0.44 1.00 3.18
7.73E+00 1.04 1.00 3.18
7.95E+01 0.30 1.00 3.18
1.26E+02 1.05 1.00 3.18 10000 1000
1.47E+02 0.96 1.00 3.18
3.05E+02 1.21 1.00 3.18
3.55E+02 0.47 1.00 3.18
3.86E+02 0.54 1.00 3.18
4.11E+02 2.38 1.00 3.18
3.56E+02 0.97 1.00 3.18
1.40E+01 0.70 1.00 3.18
8.91E+01 1.21 1.00 3.18
1.30E+02 0.61 1.00 3.18 10000 1000
2.30E+02 0.59 1.00 3.18
3.08E+02 0.46 1.00 3.18
3.39E+02 0.69 1.00 3.18
4.01E+02 0.94 1.00 3.18
4.08E+02 0.25 1.00 3.18
4.20E+02 1.70 1.00 3.18
5.00E-01 9.83 1.00 3.18
5.00E-01 7.15 1.00 3.18
5.00E-01 7.49 1.00 3.18
5.00E-01 14.80 1.00 3.18
5.00E-01 13.25 1.00 3.18
5.00E-01 3.15 1.00 3.18
5.00E-01 5.78 1.00 3.18
5.00E-01 26.87 1.00 3.18
5.00E-01 16.60 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.62E+02 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-472
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Be SWA-L01-1315-T01-A 1 9.50E-01 U1/2
Be SWA-L01-1315-T02-A 1 9.50E-01 U1/2
Be SWA-L01-1315-T03-A 1 9.50E-01 U1/2
Be SWA-L01-1315-T04-A 1 9.50E-01 U1/2
Be SWA-L01-1315-T05-A 1 9.50E-01 U1/2
Be SWA-L01-1315-T06-A 1 9.50E-01 U1/2
Be SWA-L01-1315-T07-A 1 9.50E-01 U1/2
Be SWA-L01-1315-T08-A 1 9.50E-01 U1/2
Be SWA-L01-1315-T09-A 1 9.50E-01 U1/2
Be SWA-L01-1315-T01-B 1 9.50E-01 U1/2
Be SWA-L01-1315-T02-B 1 9.50E-01 U1/2
Be SWA-L01-1315-T03-B 1 9.50E-01 U1/2
Be SWA-L01-1315-T04-B 1 9.50E-01 U1/2
Be SWA-L01-1315-T05-B 1 9.50E-01 U1/2
Be SWA-L01-1315-T06-B 1 9.50E-01 U1/2
Be SWA-L01-1315-T07-B 1 9.50E-01 U1/2
Be SWA-L01-1315-T08-B 1 9.50E-01 U1/2
Be SWA-L01-1315-T09-B 1 9.50E-01 U1/2
Be SWA-L01-1315-T01-C 1 9.50E-01 U1/2
Be SWA-L01-1315-T02-C 1 9.50E-01 U1/2
Be SWA-L01-1315-T03-C 1 9.50E-01 U1/2
Be SWA-L01-1315-T04-C 1 9.50E-01 U1/2
Be SWA-L01-1315-T05-C 1 9.50E-01 U1/2
Be SWA-L01-1315-T06-C 1 9.50E-01 U1/2
Be SWA-L01-1315-T07-C 1 9.50E-01 U1/2
Be SWA-L01-1315-T08-C 1 9.50E-01 U1/2
Be SWA-L01-1315-T09-C 1 9.50E-01 U1/2
Be SWA-L01-1315-M01-A 1 9.50E-01 U1/2
Be SWA-L01-1315-M02-A 1 9.50E-01 U1/2
Be SWA-L01-1315-M03-A 1 9.50E-01 U1/2
Be SWA-L01-1315-M04-A 1 9.50E-01 U1/2
Be SWA-L01-1315-M05-A 1 9.50E-01 U1/2
Be SWA-L01-1315-M06-A 1 9.50E-01 U1/2
Be SWA-L01-1315-M07-A 1 9.50E-01 U1/2
Be SWA-L01-1315-M08-A 1 9.50E-01 U1/2
Be SWA-L01-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 49.83 1.90 6.00
9.50E-01 76.28 1.90 6.00
9.50E-01 50.93 1.90 6.00 10000 1000
9.50E-01 21.10 1.90 6.00
9.50E-01 15.69 1.90 6.00
9.50E-01 13.28 1.90 6.00
9.50E-01 15.27 1.90 6.00
9.50E-01 87.93 1.90 6.00
9.50E-01 16.75 1.90 6.00
9.50E-01 33.06 1.90 6.00
9.50E-01 93.03 1.90 6.00
9.50E-01 44.89 1.90 6.00 10000 1000
9.50E-01 39.37 1.90 6.00
9.50E-01 13.78 1.90 6.00
9.50E-01 14.46 1.90 6.00
9.50E-01 96.22 1.90 6.00
9.50E-01 22.47 1.90 6.00
9.50E-01 77.44 1.90 6.00
9.50E-01 37.98 1.90 6.00
9.50E-01 23.57 1.90 6.00
9.50E-01 19.39 1.90 6.00 10000 1000
9.50E-01 10.26 1.90 6.00
9.50E-01 10.38 1.90 6.00
9.50E-01 13.80 1.90 6.00
9.50E-01 16.18 1.90 6.00
9.50E-01 50.97 1.90 6.00
9.50E-01 17.13 1.90 6.00
9.50E-01 27.97 1.90 6.00
9.50E-01 23.46 1.90 6.00
9.50E-01 17.29 1.90 6.00
9.50E-01 10.87 1.90 6.00
9.50E-01 62.92 1.90 6.00
9.50E-01 20.05 1.90 6.00
9.50E-01 25.16 1.90 6.00
9.50E-01 60.03 1.90 6.00
9.50E-01 68.92 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.62E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.04E+02 80% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.66E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-473
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cd SWA-L01-1315-T01-A 1 1.10E+00 U1/2
Cd SWA-L01-1315-T02-A 1 1.10E+00 U1/2
Cd SWA-L01-1315-T03-A 1 1.10E+00 U1/2
Cd SWA-L01-1315-T04-A 1 1.10E+00 U1/2
Cd SWA-L01-1315-T05-A 1 1.10E+00 U1/2
Cd SWA-L01-1315-T06-A 1 1.10E+00 U1/2
Cd SWA-L01-1315-T07-A 1 1.10E+00 U1/2
Cd SWA-L01-1315-T08-A 1 1.10E+00 U1/2
Cd SWA-L01-1315-T09-A 1 1.10E+00 U1/2
Cd SWA-L01-1315-T01-B 1 1.10E+00 U1/2
Cd SWA-L01-1315-T02-B 1 1.10E+00 U1/2
Cd SWA-L01-1315-T03-B 1 1.10E+00 U1/2
Cd SWA-L01-1315-T04-B 1 1.10E+00 U1/2
Cd SWA-L01-1315-T05-B 1 1.10E+00 U1/2
Cd SWA-L01-1315-T06-B 1 1.10E+00 U1/2
Cd SWA-L01-1315-T07-B 1 1.10E+00 U1/2
Cd SWA-L01-1315-T08-B 1 1.10E+00 U1/2
Cd SWA-L01-1315-T09-B 1 1.10E+00 U1/2
Cd SWA-L01-1315-T01-C 1 1.10E+00 U1/2
Cd SWA-L01-1315-T02-C 1 1.10E+00 U1/2
Cd SWA-L01-1315-T03-C 1 1.10E+00 U1/2
Cd SWA-L01-1315-T04-C 1 1.10E+00 U1/2
Cd SWA-L01-1315-T05-C 1 1.10E+00 U1/2
Cd SWA-L01-1315-T06-C 1 1.10E+00 U1/2
Cd SWA-L01-1315-T07-C 1 1.10E+00 U1/2
Cd SWA-L01-1315-T08-C 1 1.10E+00 U1/2
Cd SWA-L01-1315-T09-C 1 1.10E+00 U1/2
Cd SWA-L01-1315-M01-A 1 1.10E+00 U1/2
Cd SWA-L01-1315-M02-A 1 1.10E+00 U1/2
Cd SWA-L01-1315-M03-A 1 1.10E+00 U1/2
Cd SWA-L01-1315-M04-A 1 1.10E+00 U1/2
Cd SWA-L01-1315-M05-A 1 1.10E+00 U1/2
Cd SWA-L01-1315-M06-A 1 1.10E+00 U1/2
Cd SWA-L01-1315-M07-A 1 1.10E+00 U1/2
Cd SWA-L01-1315-M08-A 1 1.10E+00 U1/2
Cd SWA-L01-1315-M09-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 20.67 2.20 7.00
1.10E+00 20.49 2.20 7.00
1.10E+00 33.03 2.20 7.00 10000 1000
1.10E+00 29.00 2.20 7.00
1.10E+00 29.12 2.20 7.00
1.10E+00 67.72 2.20 7.00
1.10E+00 19.41 2.20 7.00
1.10E+00 86.69 2.20 7.00
1.10E+00 20.28 2.20 7.00
1.10E+00 16.99 2.20 7.00
1.10E+00 83.37 2.20 7.00
1.10E+00 46.53 2.20 7.00 10000 1000
1.10E+00 47.24 2.20 7.00
1.10E+00 46.88 2.20 7.00
1.10E+00 13.02 2.20 7.00
1.10E+00 16.24 2.20 7.00
1.10E+00 82.70 2.20 7.00
1.10E+00 51.83 2.20 7.00
1.10E+00 31.67 2.20 7.00
1.10E+00 11.24 2.20 7.00
1.10E+00 41.42 2.20 7.00 10000 1000
1.10E+00 56.45 2.20 7.00
1.10E+00 14.40 2.20 7.00
1.10E+00 14.71 2.20 7.00
1.10E+00 12.96 2.20 7.00
1.10E+00 28.48 2.20 7.00
1.10E+00 11.56 2.20 7.00
1.10E+00 20.51 2.20 7.00
1.10E+00 36.80 2.20 7.00
1.10E+00 26.97 2.20 7.00
1.10E+00 99.94 2.20 7.00
1.10E+00 21.78 2.20 7.00
1.10E+00 39.88 2.20 7.00
1.10E+00 99.82 2.20 7.00
1.10E+00 91.44 2.20 7.00
1.10E+00 12.63 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.81 E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.68E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.80E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-474
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Ca SWA-L01-1315-T01-A 1 6.14E+02
Ca SWA-L01-1315-T02-A 1 8.88E+03
Ca SWA-L01-1315-T03-A 1 1.50E+04
Ca SWA-L01-1315-T04-A 1 2.88E+04
Ca SWA-L01-1315-T05-A 1 3.29E+04
Ca SWA-L01-1315-T06-A 1 3.61E+04
Ca SWA-L01-1315-T07-A 1 3.03E+04
Ca SWA-L01-1315-T08-A 1 3.08E+04
Ca SWA-L01-1315-T09-A 1 2.37E+04
Ca SWA-L01-1315-T01-B 1 5.83E+02
Ca SWA-L01-1315-T02-B 1 7.69E+03
Ca SWA-L01-1315-T03-B 1 1.45E+04
Ca SWA-L01-1315-T04-B 1 1.71E+04
Ca SWA-L01-1315-T05-B 1 3.05E+04
Ca SWA-L01-1315-T06-B 1 3.35E+04
Ca SWA-L01-1315-T07-B 1 3.20E+04
Ca SWA-L01-1315-T08-B 1 3.09E+04
Ca SWA-L01-1315-T09-B 1 2.63E+04
Ca SWA-L01-1315-T01-C 1 7.69E+02
Ca SWA-L01-1315-T02-C 1 8.28E+03
Ca SWA-L01-1315-T03-C 1 1.42E+04
Ca SWA-L01-1315-T04-C 1 2.60E+04
Ca SWA-L01-1315-T05-C 1 3.28E+04
Ca SWA-L01-1315-T06-C 1 3.50E+04
Ca SWA-L01-1315-T07-C 1 3.71E+04
Ca SWA-L01-1315-T08-C 1 3.29E+04
Ca SWA-L01-1315-T09-C 1 3.42E+04
Ca SWA-L01-1315-M01-A 1 1.38E+02
Ca SWA-L01-1315-M02-A 1 7.67E+01
Ca SWA-L01-1315-M03-A 1 1.35E+01
Ca SWA-L01-1315-M04-A 1 9.87E+01
Ca SWA-L01-1315-M05-A 1 1.51E+02
Ca SWA-L01-1315-M06-A 1 1.77E+02
Ca SWA-L01-1315-M07-A 1 9.75E+01
Ca SWA-L01-1315-M08-A 1 8.02E+01
Ca SWA-L01-1315-M09-A 1 1.00E+02
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.14E+02 3.03 2.60 8.30
8.88E+03 0.72 2.60 8.30
1.50E+04 0.34 2.60 8.30 10000 1000
2.88E+04 0.51 2.60 8.30
3.29E+04 0.90 2.60 8.30
3.61 E+04 0.37 2.60 8.30
3.03E+04 0.36 2.60 8.30
3.08E+04 0.69 2.60 8.30
2.37E+04 0.94 2.60 8.30
5.83E+02 4.81 2.60 8.30
7.69E+03 0.51 2.60 8.30
1.45E+04 0.78 2.60 8.30 10000 1000
1.71 E+04 0.90 2.60 8.30
3.05E+04 1.06 2.60 8.30
3.35E+04 0.37 2.60 8.30
3.20E+04 0.46 2.60 8.30
3.09E+04 1.21 2.60 8.30
2.63E+04 0.72 2.60 8.30
7.69E+02 1.47 2.60 8.30
8.28E+03 0.72 2.60 8.30
1.42E+04 0.69 2.60 8.30 10000 1000
2.60E+04 0.44 2.60 8.30
3.28E+04 0.81 2.60 8.30
3.50E+04 0.65 2.60 8.30
3.71 E+04 1.01 2.60 8.30
3.29E+04 0.59 2.60 8.30
3.42E+04 0.29 2.60 8.30
1.38E+02 3.38 2.60 8.30
7.67E+01 1.61 2.60 8.30
1.35E+01 3.90 2.60 8.30
9.87E+01 7.76 2.60 8.30
1.51E+02 2.08 2.60 8.30
1.77E+02 1.15 2.60 8.30
9.75E+01 1.62 2.60 8.30
8.02E+01 1.63 2.60 8.30
1.00E+02 6.51 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.58E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.54E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.51 E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-475
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Cr SWA-L01-1315-T01-A 1 3.28E+01
Cr SWA-L01-1315-T02-A 1 6.41E+01
Cr SWA-L01-1315-T03-A 1 2.47E+01
Cr SWA-L01-1315-T04-A 1 5.64E+01
Cr SWA-L01-1315-T05-A 1 5.74E+01
Cr SWA-L01-1315-T06-A 1 6.49E+01
Cr SWA-L01-1315-T07-A 1 5.86E+01
Cr SWA-L01-1315-T08-A 1 4.07E+01
Cr SWA-L01-1315-T09-A 1 5.22E+01
Cr SWA-L01-1315-T01-B 1 3.47E+01
Cr SWA-L01-1315-T02-B 1 6.84E+01
Cr SWA-L01-1315-T03-B 1 2.92E+01
Cr SWA-L01-1315-T04-B 1 4.18E+01
Cr SWA-L01-1315-T05-B 1 6.05E+01
Cr SWA-L01-1315-T06-B 1 6.69E+01
Cr SWA-L01-1315-T07-B 1 5.91E+01
Cr SWA-L01-1315-T08-B 1 4.07E+01
Cr SWA-L01-1315-T09-B 1 5.10E+01
Cr SWA-L01-1315-T01-C 1 4.44E+01
Cr SWA-L01-1315-T02-C 1 1.18E+02
Cr SWA-L01-1315-T03-C 1 4.13E+01
Cr SWA-L01-1315-T04-C 1 8.04E+01
Cr SWA-L01-1315-T05-C 1 7.25E+01
Cr SWA-L01-1315-T06-C 1 7.59E+01
Cr SWA-L01-1315-T07-C 1 7.11E+01
Cr SWA-L01-1315-T08-C 1 4.55E+01
Cr SWA-L01-1315-T09-C 1 6.16E+01
Cr SWA-L01-1315-M01-A 1 6.00E-01 U1/2
Cr SWA-L01-1315-M02-A 1 6.00E-01 U1/2
Cr SWA-L01-1315-M03-A 1 6.00E-01 U1/2
Cr SWA-L01-1315-M04-A 1 6.00E-01 U1/2
Cr SWA-L01-1315-M05-A 1 6.00E-01 U1/2
Cr SWA-L01-1315-M06-A 1 6.00E-01 U1/2
Cr SWA-L01-1315-M07-A 1 6.00E-01 U1/2
Cr SWA-L01-1315-M08-A 1 6.00E-01 U1/2
Cr SWA-L01-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.28E+01 0.25 1.20 3.82
6.41 E+01 0.39 1.20 3.82
2.47E+01 2.64 1.20 3.82 10000 1000
5.64E+01 1.31 1.20 3.82
5.74E+01 1.74 1.20 3.82
6.49E+01 0.32 1.20 3.82
5.86E+01 1.24 1.20 3.82
4.07E+01 1.13 1.20 3.82
5.22E+01 1.94 1.20 3.82
3.47E+01 1.08 1.20 3.82
6.84E+01 0.02 1.20 3.82
2.92E+01 1.70 1.20 3.82 10000 1000
4.18E+01 1.70 1.20 3.82
6.05E+01 0.73 1.20 3.82
6.69E+01 0.63 1.20 3.82
5.91E+01 0.91 1.20 3.82
4.07E+01 1.47 1.20 3.82
5.10E+01 0.38 1.20 3.82
4.44E+01 0.84 1.20 3.82
1.18E+02 0.61 1.20 3.82
4.13E+01 1.23 1.20 3.82 10000 1000
8.04E+01 0.55 1.20 3.82
7.25E+01 0.95 1.20 3.82
7.59E+01 0.56 1.20 3.82
7.11E+01 1.20 1.20 3.82
4.55E+01 2.51 1.20 3.82
6.16E+01 1.01 1.20 3.82
6.00E-01 52.27 1.20 3.82
6.00E-01 69.31 1.20 3.82
6.00E-01 38.74 1.20 3.82
6.00E-01 48.66 1.20 3.82
6.00E-01 24.21 1.20 3.82
6.00E-01 12.43 1.20 3.82
6.00E-01 61.55 1.20 3.82
6.00E-01 47.94 1.20 3.82
6.00E-01 32.94 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.68E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-476
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Co SWA-L01-1315-T01-A 1 9.00E-01 U1/2
Co SWA-L01-1315-T02-A 1 9.00E-01 U1/2
Co SWA-L01-1315-T03-A 1 9.00E-01 U1/2
Co SWA-L01-1315-T04-A 1 9.00E-01 U1/2
Co SWA-L01-1315-T05-A 1 9.00E-01 U1/2
Co SWA-L01-1315-T06-A 1 9.00E-01 U1/2
Co SWA-L01-1315-T07-A 1 9.00E-01 U1/2
Co SWA-L01-1315-T08-A 1 9.00E-01 U1/2
Co SWA-L01-1315-T09-A 1 9.00E-01 U1/2
Co SWA-L01-1315-T01-B 1 9.00E-01 U1/2
Co SWA-L01-1315-T02-B 1 9.00E-01 U1/2
Co SWA-L01-1315-T03-B 1 9.00E-01 U1/2
Co SWA-L01-1315-T04-B 1 9.00E-01 U1/2
Co SWA-L01-1315-T05-B 1 9.00E-01 U1/2
Co SWA-L01-1315-T06-B 1 9.00E-01 U1/2
Co SWA-L01-1315-T07-B 1 9.00E-01 U1/2
Co SWA-L01-1315-T08-B 1 9.00E-01 U1/2
Co SWA-L01-1315-T09-B 1 9.00E-01 U1/2
Co SWA-L01-1315-T01-C 1 9.00E-01 U1/2
Co SWA-L01-1315-T02-C 1 9.00E-01 U1/2
Co SWA-L01-1315-T03-C 1 9.00E-01 U1/2
Co SWA-L01-1315-T04-C 1 9.00E-01 U1/2
Co SWA-L01-1315-T05-C 1 9.00E-01 U1/2
Co SWA-L01-1315-T06-C 1 9.00E-01 U1/2
Co SWA-L01-1315-T07-C 1 9.00E-01 U1/2
Co SWA-L01-1315-T08-C 1 9.00E-01 U1/2
Co SWA-L01-1315-T09-C 1 9.00E-01 U1/2
Co SWA-L01-1315-M01-A 1 9.00E-01 U1/2
Co SWA-L01-1315-M02-A 1 9.00E-01 U1/2
Co SWA-L01-1315-M03-A 1 9.00E-01 U1/2
Co SWA-L01-1315-M04-A 1 9.00E-01 U1/2
Co SWA-L01-1315-M05-A 1 9.00E-01 U1/2
Co SWA-L01-1315-M06-A 1 9.00E-01 U1/2
Co SWA-L01-1315-M07-A 1 9.00E-01 U1/2
Co SWA-L01-1315-M08-A 1 9.00E-01 U1/2
Co SWA-L01-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 93.64 1.80 5.72
9.00E-01 15.45 1.80 5.72
9.00E-01 12.50 1.80 5.72 10000 1000
9.00E-01 51.36 1.80 5.72
9.00E-01 27.30 1.80 5.72
9.00E-01 43.79 1.80 5.72
9.00E-01 96.42 1.80 5.72
9.00E-01 38.99 1.80 5.72
9.00E-01 15.42 1.80 5.72
9.00E-01 73.77 1.80 5.72
9.00E-01 97.57 1.80 5.72
9.00E-01 16.47 1.80 5.72 10000 1000
9.00E-01 71.82 1.80 5.72
9.00E-01 29.54 1.80 5.72
9.00E-01 53.09 1.80 5.72
9.00E-01 16.77 1.80 5.72
9.00E-01 46.96 1.80 5.72
9.00E-01 66.02 1.80 5.72
9.00E-01 12.62 1.80 5.72
9.00E-01 26.83 1.80 5.72
9.00E-01 10.30 1.80 5.72 10000 1000
9.00E-01 96.03 1.80 5.72
9.00E-01 6.25 1.80 5.72
9.00E-01 22.89 1.80 5.72
9.00E-01 66.69 1.80 5.72
9.00E-01 38.88 1.80 5.72
9.00E-01 97.20 1.80 5.72
9.00E-01 11.14 1.80 5.72
9.00E-01 5.58 1.80 5.72
9.00E-01 38.41 1.80 5.72
9.00E-01 3.41 1.80 5.72
9.00E-01 25.12 1.80 5.72
9.00E-01 26.66 1.80 5.72
9.00E-01 46.90 1.80 5.72
9.00E-01 71.21 1.80 5.72
9.00E-01 51.29 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.49E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.78E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.50E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-477
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cu SWA-L01-1315-T01-A 1 1.85E+00 U1/2
Cu SWA-L01-1315-T02-A 1 1.85E+00 U1/2
Cu SWA-L01-1315-T03-A 1 1.85E+00 U1/2
Cu SWA-L01-1315-T04-A 1 1.85E+00 U1/2
Cu SWA-L01-1315-T05-A 1 1.85E+00 U1/2
Cu SWA-L01-1315-T06-A 1 1.85E+00 U1/2
Cu SWA-L01-1315-T07-A 1 1.85E+00 U1/2
Cu SWA-L01-1315-T08-A 1 1.85E+00 U1/2
Cu SWA-L01-1315-T09-A 1 1.85E+00 U1/2
Cu SWA-L01-1315-T01-B 1 1.85E+00 U1/2
Cu SWA-L01-1315-T02-B 1 1.85E+00 U1/2
Cu SWA-L01-1315-T03-B 1 1.85E+00 U1/2
Cu SWA-L01-1315-T04-B 1 1.85E+00 U1/2
Cu SWA-L01-1315-T05-B 1 1.85E+00 U1/2
Cu SWA-L01-1315-T06-B 1 1.85E+00 U1/2
Cu SWA-L01-1315-T07-B 1 1.85E+00 U1/2
Cu SWA-L01-1315-T08-B 1 1.85E+00 U1/2
Cu SWA-L01-1315-T09-B 1 1.85E+00 U1/2
Cu SWA-L01-1315-T01-C 1 1.85E+00 U1/2
Cu SWA-L01-1315-T02-C 1 1.85E+00 U1/2
Cu SWA-L01-1315-T03-C 1 1.85E+00 U1/2
Cu SWA-L01-1315-T04-C 1 1.85E+00 U1/2
Cu SWA-L01-1315-T05-C 1 1.85E+00 U1/2
Cu SWA-L01-1315-T06-C 1 1.85E+00 U1/2
Cu SWA-L01-1315-T07-C 1 3.89E+00 E
Cu SWA-L01-1315-T08-C 1 1.85E+00 U1/2
Cu SWA-L01-1315-T09-C 1 1.85E+00 U1/2
Cu SWA-L01-1315-M01-A 1 1.85E+00 U1/2
Cu SWA-L01-1315-M02-A 1 1.85E+00 U1/2
Cu SWA-L01-1315-M03-A 1 1.85E+00 U1/2
Cu SWA-L01-1315-M04-A 1 1.85E+00 U1/2
Cu SWA-L01-1315-M05-A 1 1.85E+00 U1/2
Cu SWA-L01-1315-M06-A 1 1.85E+00 U1/2
Cu SWA-L01-1315-M07-A 1 1.85E+00 U1/2
Cu SWA-L01-1315-M08-A 1 1.85E+00 U1/2
Cu SWA-L01-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 78.00 3.70 11.80
1.85E+00 87.18 3.70 11.80
1.85E+00 67.95 3.70 11.80 10000 1000
1.85E+00 69.08 3.70 11.80
1.85E+00 14.20 3.70 11.80
1.85E+00 48.81 3.70 11.80
1.85E+00 40.09 3.70 11.80
1.85E+00 63.25 3.70 11.80
1.85E+00 18.90 3.70 11.80
1.85E+00 10.27 3.70 11.80
1.85E+00 17.82 3.70 11.80
1.85E+00 38.86 3.70 11.80 10000 1000
1.85E+00 62.56 3.70 11.80
1.85E+00 46.83 3.70 11.80
1.85E+00 24.94 3.70 11.80
1.85E+00 84.52 3.70 11.80
1.85E+00 63.33 3.70 11.80
1.85E+00 62.38 3.70 11.80
1.85E+00 27.74 3.70 11.80
1.85E+00 13.20 3.70 11.80
1.85E+00 31.79 3.70 11.80 10000 1000
1.85E+00 71.50 3.70 11.80
1.85E+00 66.26 3.70 11.80
1.85E+00 57.19 3.70 11.80
3.89E+00 14.90 3.70 11.80
1.85E+00 45.62 3.70 11.80
1.85E+00 27.23 3.70 11.80
1.85E+00 74.87 3.70 11.80
1.85E+00 47.25 3.70 11.80
1.85E+00 56.98 3.70 11.80
1.85E+00 38.44 3.70 11.80
1.85E+00 18.97 3.70 11.80
1.85E+00 8.71 3.70 11.80
1.85E+00 42.96 3.70 11.80
1.85E+00 16.36 3.70 11.80
1.85E+00 53.57 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.42E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.37E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.40E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-478
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Fe SWA-L01-1315-T01-A 1 7.12E+00
Fe SWA-L01-1315-T02-A 1 1.14E+01
Fe SWA-L01-1315-T03-A 1 4.80E+00 E
Fe SWA-L01-1315-T04-A 1 4.02E+00 E
Fe SWA-L01-1315-T05-A 1 4.23E+00 E
Fe SWA-L01-1315-T06-A 1 3.92E+00 E
Fe SWA-L01-1315-T07-A 1 2.77E+00 E
Fe SWA-L01-1315-T08-A 1 3.76E+00 E
Fe SWA-L01-1315-T09-A 1 1.62E+01
Fe SWA-L01-1315-T01-B 1 5.70E+00 E
Fe SWA-L01-1315-T02-B 1 1.25E+01
Fe SWA-L01-1315-T03-B 1 4.95E+00 E
Fe SWA-L01-1315-T04-B 1 4.92E+00 E
Fe SWA-L01-1315-T05-B 1 7.46E+00
Fe SWA-L01-1315-T06-B 1 3.81E+00 E
Fe SWA-L01-1315-T07-B 1 1.48E+01
Fe SWA-L01-1315-T08-B 1 3.22E+00 E
Fe SWA-L01-1315-T09-B 1 3.51E+00 E
Fe SWA-L01-1315-T01-C 1 6.02E+00 E
Fe SWA-L01-1315-T02-C 1 1.69E+01
Fe SWA-L01-1315-T03-C 1 5.06E+00 E
Fe SWA-L01-1315-T04-C 1 6.62E+00
Fe SWA-L01-1315-T05-C 1 4.94E+00 E
Fe SWA-L01-1315-T06-C 1 4.06E+00 E
Fe SWA-L01-1315-T07-C 1 5.75E+00 E
Fe SWA-L01-1315-T08-C 1 2.68E+00 E
Fe SWA-L01-1315-T09-C 1 3.11E+OOE
Fe SWA-L01-1315-M01-A 1 5.00E-01 U1/2
Fe SWA-L01-1315-M02-A 1 5.00E-01 U1/2
Fe SWA-L01-1315-M03-A 1 5.00E-01 U1/2
Fe SWA-L01-1315-M04-A 1 5.00E-01 U1/2
Fe SWA-L01-1315-M05-A 1 5.00E-01 U1/2
Fe SWA-L01-1315-M06-A 1 5.00E-01 U1/2
Fe SWA-L01-1315-M07-A 1 5.00E-01 U1/2
Fe SWA-L01-1315-M08-A 1 5.00E-01 U1/2
Fe SWA-L01-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.12E+00 7.11 2.00 6.40
1.14E+01 0.93 2.00 6.40
4.80E+00 7.03 2.00 6.40 10000 1000
4.02E+00 8.33 2.00 6.40
4.23E+00 6.34 2.00 6.40
3.92E+00 6.55 2.00 6.40
2.77E+00 7.82 2.00 6.40
3.76E+00 10.86 2.00 6.40
1.62E+01 9.15 2.00 6.40
5.70E+00 7.37 2.00 6.40
1.25E+01 1.66 2.00 6.40
4.95E+00 4.73 2.00 6.40 10000 1000
4.92E+00 9.15 2.00 6.40
7.46E+00 4.31 2.00 6.40
3.81 E+00 5.01 2.00 6.40
1.48E+01 4.74 2.00 6.40
3.22E+00 8.76 2.00 6.40
3.51E+00 1.13 2.00 6.40
6.02E+00 4.63 2.00 6.40
1.69E+01 2.42 2.00 6.40
5.06E+00 1.87 2.00 6.40 10000 1000
6.62E+00 8.63 2.00 6.40
4.94E+00 6.78 2.00 6.40
4.06E+00 9.25 2.00 6.40
5.75E+00 5.24 2.00 6.40
2.68E+00 6.87 2.00 6.40
3.11E+00 12.48 2.00 6.40
5.00E-01 11.67 2.00 6.40
5.00E-01 13.80 2.00 6.40
5.00E-01 30.62 2.00 6.40
5.00E-01 21.62 2.00 6.40
5.00E-01 26.80 2.00 6.40
5.00E-01 5.85 2.00 6.40
5.00E-01 2.45 2.00 6.40
5.00E-01 7.95 2.00 6.40
5.00E-01 18.15 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.61 E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.80E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.71 E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-479
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Pb SWA-L01-1315-T01-A 1 3.40E+00 U1/2
Pb SWA-L01-1315-T02-A 1 3.40E+00 U1/2
Pb SWA-L01-1315-T03-A 1 3.40E+00 U1/2
Pb SWA-L01-1315-T04-A 1 3.40E+00 U1/2
Pb SWA-L01-1315-T05-A 1 3.40E+00 U1/2
Pb SWA-L01-1315-T06-A 1 3.40E+00 U1/2
Pb SWA-L01-1315-T07-A 1 3.40E+00 U1/2
Pb SWA-L01-1315-T08-A 1 3.40E+00 U1/2
Pb SWA-L01-1315-T09-A 1 3.40E+00 U1/2
Pb SWA-L01-1315-T01-B 1 3.40E+00 U1/2
Pb SWA-L01-1315-T02-B 1 3.40E+00 U1/2
Pb SWA-L01-1315-T03-B 1 3.40E+00 U1/2
Pb SWA-L01-1315-T04-B 1 3.40E+00 U1/2
Pb SWA-L01-1315-T05-B 1 3.40E+00 U1/2
Pb SWA-L01-1315-T06-B 1 3.40E+00 U1/2
Pb SWA-L01-1315-T07-B 1 3.40E+00 U1/2
Pb SWA-L01-1315-T08-B 1 3.40E+00 U1/2
Pb SWA-L01-1315-T09-B 1 3.40E+00 U1/2
Pb SWA-L01-1315-T01-C 1 3.40E+00 U1/2
Pb SWA-L01-1315-T02-C 1 3.40E+00 U1/2
Pb SWA-L01-1315-T03-C 1 3.40E+00 U1/2
Pb SWA-L01-1315-T04-C 1 3.40E+00 U1/2
Pb SWA-L01-1315-T05-C 1 3.40E+00 U1/2
Pb SWA-L01-1315-T06-C 1 3.40E+00 U1/2
Pb SWA-L01-1315-T07-C 1 3.40E+00 U1/2
Pb SWA-L01-1315-T08-C 1 3.40E+00 U1/2
Pb SWA-L01-1315-T09-C 1 3.40E+00 U1/2
Pb SWA-L01-1315-M01-A 1 3.40E+00 U1/2
Pb SWA-L01-1315-M02-A 1 3.40E+00 U1/2
Pb SWA-L01-1315-M03-A 1 3.40E+00 U1/2
Pb SWA-L01-1315-M04-A 1 3.40E+00 U1/2
Pb SWA-L01-1315-M05-A 1 3.40E+00 U1/2
Pb SWA-L01-1315-M06-A 1 3.40E+00 U1/2
Pb SWA-L01-1315-M07-A 1 3.40E+00 U1/2
Pb SWA-L01-1315-M08-A 1 3.40E+00 U1/2
Pb SWA-L01-1315-M09-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 66.25 6.80 21.60
3.40E+00 9.31 6.80 21.60
3.40E+00 50.21 6.80 21.60 10000 1000
3.40E+00 79.85 6.80 21.60
3.40E+00 51.81 6.80 21.60
3.40E+00 77.65 6.80 21.60
3.40E+00 22.48 6.80 21.60
3.40E+00 88.80 6.80 21.60
3.40E+00 45.28 6.80 21.60
3.40E+00 33.38 6.80 21.60
3.40E+00 91.83 6.80 21.60
3.40E+00 70.99 6.80 21.60 10000 1000
3.40E+00 90.69 6.80 21.60
3.40E+00 79.46 6.80 21.60
3.40E+00 35.79 6.80 21.60
3.40E+00 31.02 6.80 21.60
3.40E+00 74.91 6.80 21.60
3.40E+00 46.07 6.80 21.60
3.40E+00 11.05 6.80 21.60
3.40E+00 18.19 6.80 21.60
3.40E+00 35.66 6.80 21.60 10000 1000
3.40E+00 49.26 6.80 21.60
3.40E+00 80.01 6.80 21.60
3.40E+00 43.86 6.80 21.60
3.40E+00 37.91 6.80 21.60
3.40E+00 71.02 6.80 21.60
3.40E+00 32.05 6.80 21.60
3.40E+00 81.35 6.80 21.60
3.40E+00 53.78 6.80 21.60
3.40E+00 30.14 6.80 21.60
3.40E+00 95.62 6.80 21.60
3.40E+00 57.75 6.80 21.60
3.40E+00 80.74 6.80 21.60
3.40E+00 44.03 6.80 21.60
3.40E+00 96.35 6.80 21.60
3.40E+00 45.33 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.33E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.79E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.33E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-480
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Li SWA-L01-1315-T01-A 1 9.50E-01 U1/2
Li SWA-L01-1315-T02-A 1 9.50E-01 U1/2
Li SWA-L01-1315-T03-A 1 9.50E-01 U1/2
Li SWA-L01-1315-T04-A 1 9.50E-01 U1/2
Li SWA-L01-1315-T05-A 1 9.50E-01 U1/2
Li SWA-L01-1315-T06-A 1 9.50E-01 U1/2
Li SWA-L01-1315-T07-A 1 9.50E-01 U1/2
Li SWA-L01-1315-T08-A 1 9.50E-01 U1/2
Li SWA-L01-1315-T09-A 1 9.50E-01 U1/2
Li SWA-L01-1315-T01-B 1 9.50E-01 U1/2
Li SWA-L01-1315-T02-B 1 9.50E-01 U1/2
Li SWA-L01-1315-T03-B 1 9.50E-01 U1/2
Li SWA-L01-1315-T04-B 1 9.50E-01 U1/2
Li SWA-L01-1315-T05-B 1 9.50E-01 U1/2
Li SWA-L01-1315-T06-B 1 9.50E-01 U1/2
Li SWA-L01-1315-T07-B 1 9.50E-01 U1/2
Li SWA-L01-1315-T08-B 1 9.50E-01 U1/2
Li SWA-L01-1315-T09-B 1 9.50E-01 U1/2
Li SWA-L01-1315-T01-C 1 9.50E-01 U1/2
Li SWA-L01-1315-T02-C 1 9.50E-01 U1/2
Li SWA-L01-1315-T03-C 1 9.50E-01 U1/2
Li SWA-L01-1315-T04-C 1 9.50E-01 U1/2
Li SWA-L01-1315-T05-C 1 9.50E-01 U1/2
Li SWA-L01-1315-T06-C 1 9.50E-01 U1/2
Li SWA-L01-1315-T07-C 1 9.50E-01 U1/2
Li SWA-L01-1315-T08-C 1 9.50E-01 U1/2
Li SWA-L01-1315-T09-C 1 9.50E-01 U1/2
Li SWA-L01-1315-M01-A 1 9.50E-01 U1/2
Li SWA-L01-1315-M02-A 1 9.50E-01 U1/2
Li SWA-L01-1315-M03-A 1 9.50E-01 U1/2
Li SWA-L01-1315-M04-A 1 9.50E-01 U1/2
Li SWA-L01-1315-M05-A 1 9.50E-01 U1/2
Li SWA-L01-1315-M06-A 1 9.50E-01 U1/2
Li SWA-L01-1315-M07-A 1 9.50E-01 U1/2
Li SWA-L01-1315-M08-A 1 9.50E-01 U1/2
Li SWA-L01-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 5.23 1.90 6.00
9.50E-01 9.25 1.90 6.00
9.50E-01 18.61 1.90 6.00 10000 1000
9.50E-01 24.76 1.90 6.00
9.50E-01 29.79 1.90 6.00
9.50E-01 6.47 1.90 6.00
9.50E-01 19.85 1.90 6.00
9.50E-01 37.87 1.90 6.00
9.50E-01 13.09 1.90 6.00
9.50E-01 29.54 1.90 6.00
9.50E-01 9.27 1.90 6.00
9.50E-01 4.41 1.90 6.00 10000 1000
9.50E-01 16.25 1.90 6.00
9.50E-01 36.07 1.90 6.00
9.50E-01 29.17 1.90 6.00
9.50E-01 10.47 1.90 6.00
9.50E-01 12.38 1.90 6.00
9.50E-01 43.37 1.90 6.00
9.50E-01 21.42 1.90 6.00
9.50E-01 7.25 1.90 6.00
9.50E-01 19.58 1.90 6.00 10000 1000
9.50E-01 19.82 1.90 6.00
9.50E-01 22.74 1.90 6.00
9.50E-01 4.86 1.90 6.00
9.50E-01 6.20 1.90 6.00
9.50E-01 14.18 1.90 6.00
9.50E-01 6.35 1.90 6.00
9.50E-01 19.97 1.90 6.00
9.50E-01 23.82 1.90 6.00
9.50E-01 27.33 1.90 6.00
9.50E-01 15.45 1.90 6.00
9.50E-01 19.53 1.90 6.00
9.50E-01 18.74 1.90 6.00
9.50E-01 28.68 1.90 6.00
9.50E-01 21.14 1.90 6.00
9.50E-01 29.43 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.98E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.65E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.79E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-481
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Mn SWA-L01-1315-T01-A 1 1.00E+00 U1/2
Mn SWA-L01-1315-T02-A 1 1.00E+00 U1/2
Mn SWA-L01-1315-T03-A 1 1.00E+00 U1/2
Mn SWA-L01-1315-T04-A 1 1.00E+00 U1/2
Mn SWA-L01-1315-T05-A 1 1.00E+00 U1/2
Mn SWA-L01-1315-T06-A 1 1.00E+00 U1/2
Mn SWA-L01-1315-T07-A 1 1.00E+00 U1/2
Mn SWA-L01-1315-T08-A 1 1.00E+00 U1/2
Mn SWA-L01-1315-T09-A 1 1.00E+00 U1/2
Mn SWA-L01-1315-T01-B 1 1.00E+00 U1/2
Mn SWA-L01-1315-T02-B 1 1.00E+00 U1/2
Mn SWA-L01-1315-T03-B 1 1.00E+00 U1/2
Mn SWA-L01-1315-T04-B 1 1.00E+00 U1/2
Mn SWA-L01-1315-T05-B 1 1.00E+00 U1/2
Mn SWA-L01-1315-T06-B 1 1.00E+00 U1/2
Mn SWA-L01-1315-T07-B 1 1.00E+00 U1/2
Mn SWA-L01-1315-T08-B 1 1.00E+00 U1/2
Mn SWA-L01-1315-T09-B 1 1.00E+00 U1/2
Mn SWA-L01-1315-T01-C 1 1.00E+00 U1/2
Mn SWA-L01-1315-T02-C 1 1.00E+00 U1/2
Mn SWA-L01-1315-T03-C 1 1.00E+00 U1/2
Mn SWA-L01-1315-T04-C 1 1.00E+00 U1/2
Mn SWA-L01-1315-T05-C 1 1.00E+00 U1/2
Mn SWA-L01-1315-T06-C 1 1.00E+00 U1/2
Mn SWA-L01-1315-T07-C 1 1.00E+00 U1/2
Mn SWA-L01-1315-T08-C 1 1.00E+00 U1/2
Mn SWA-L01-1315-T09-C 1 1.00E+00 U1/2
Mn SWA-L01-1315-M01-A 1 1.00E+00 U1/2
Mn SWA-L01-1315-M02-A 1 1.00E+00 U1/2
Mn SWA-L01-1315-M03-A 1 1.00E+00 U1/2
Mn SWA-L01-1315-M04-A 1 1.00E+00 U1/2
Mn SWA-L01-1315-M05-A 1 1.00E+00 U1/2
Mn SWA-L01-1315-M06-A 1 1.00E+00 U1/2
Mn SWA-L01-1315-M07-A 1 1.00E+00 U1/2
Mn SWA-L01-1315-M08-A 1 1.00E+00 U1/2
Mn SWA-L01-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 15.82 2.00 6.40
1.00E+00 26.39 2.00 6.40
1.00E+00 14.60 2.00 6.40 10000 1000
1.00E+00 18.24 2.00 6.40
1.00E+00 30.93 2.00 6.40
1.00E+00 23.48 2.00 6.40
1.00E+00 9.86 2.00 6.40
1.00E+00 10.77 2.00 6.40
1.00E+00 6.59 2.00 6.40
1.00E+00 21.32 2.00 6.40
1.00E+00 40.97 2.00 6.40
1.00E+00 1.66 2.00 6.40 10000 1000
1.00E+00 28.78 2.00 6.40
1.00E+00 11.92 2.00 6.40
1.00E+00 32.45 2.00 6.40
1.00E+00 3.66 2.00 6.40
1.00E+00 22.50 2.00 6.40
1.00E+00 10.85 2.00 6.40
1.00E+00 1.33 2.00 6.40
1.00E+00 26.61 2.00 6.40
1.00E+00 10.87 2.00 6.40 10000 1000
1.00E+00 42.68 2.00 6.40
1.00E+00 5.89 2.00 6.40
1.00E+00 32.00 2.00 6.40
1.00E+00 24.50 2.00 6.40
1.00E+00 20.21 2.00 6.40
1.00E+00 22.41 2.00 6.40
1.00E+00 9.54 2.00 6.40
1.00E+00 102.08 2.00 6.40
1.00E+00 38.97 2.00 6.40
1.00E+00 15.06 2.00 6.40
1.00E+00 41.40 2.00 6.40
1.00E+00 14.31 2.00 6.40
1.00E+00 8.43 2.00 6.40
1.00E+00 18.11 2.00 6.40
1.00E+00 1.89 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.51 E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.91 E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.58E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-482
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Mg SWA-L01-1315-T01-A 1 2.54E+01
Mg SWA-L01-1315-T02-A 1 2.79E+01
Mg SWA-L01-1315-T03-A 1 3.96E+01
Mg SWA-L01-1315-T04-A 1 3.78E+01
Mg SWA-L01-1315-T05-A 1 2.92E+01
Mg SWA-L01-1315-T06-A 1 2.18E+01
Mg SWA-L01-1315-T07-A 1 3.90E+01
Mg SWA-L01-1315-T08-A 1 6.95E+01
Mg SWA-L01-1315-T09-A 1 1.60E+02
Mg SWA-L01-1315-T01-B 1 2.10E+01
Mg SWA-L01-1315-T02-B 1 2.56E+01
Mg SWA-L01-1315-T03-B 1 3.36E+01
Mg SWA-L01-1315-T04-B 1 1.71E+01
Mg SWA-L01-1315-T05-B 1 2.57E+01
Mg SWA-L01-1315-T06-B 1 2.59E+01
Mg SWA-L01-1315-T07-B 1 3.16E+01
Mg SWA-L01-1315-T08-B 1 5.29E+01
Mg SWA-L01-1315-T09-B 1 3.59E+01
Mg SWA-L01-1315-T01-C 1 2.96E+01
Mg SWA-L01-1315-T02-C 1 3.15E+01
Mg SWA-L01-1315-T03-C 1 3.77E+01
Mg SWA-L01-1315-T04-C 1 2.77E+01
Mg SWA-L01-1315-T05-C 1 1.74E+01
Mg SWA-L01-1315-T06-C 1 1.74E+01
Mg SWA-L01-1315-T07-C 1 2.96E+01
Mg SWA-L01-1315-T08-C 1 5.58E+01
Mg SWA-L01-1315-T09-C 1 3.65E+01
Mg SWA-L01-1315-M01-A 1 1.24E+01
Mg SWA-L01-1315-M02-A 1 4.70E+00
Mg SWA-L01-1315-M03-A 1 4.06E+00
Mg SWA-L01-1315-M04-A 1 8.87E+00
Mg SWA-L01-1315-M05-A 1 6.90E+00
Mg SWA-L01-1315-M06-A 1 6.55E+00
Mg SWA-L01-1315-M07-A 1 6.13E+00
Mg SWA-L01-1315-M08-A 1 4.44E+00
Mg SWA-L01-1315-M09-A 1 3.73E+00
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.54E+01 2.48 1.00 3.18
2.79E+01 3.21 1.00 3.18
3.96E+01 0.87 1.00 3.18 10000 1000
3.78E+01 1.53 1.00 3.18
2.92E+01 2.63 1.00 3.18
2.18E+01 1.63 1.00 3.18
3.90E+01 2.37 1.00 3.18
6.95E+01 0.98 1.00 3.18
1.60E+02 0.83 1.00 3.18
2.10E+01 1.99 1.00 3.18
2.56E+01 2.63 1.00 3.18
3.36E+01 2.43 1.00 3.18 10000 1000
1.71E+01 10.29 1.00 3.18
2.57E+01 3.11 1.00 3.18
2.59E+01 6.59 1.00 3.18
3.16E+01 2.75 1.00 3.18
5.29E+01 1.52 1.00 3.18
3.59E+01 1.39 1.00 3.18
2.96E+01 3.79 1.00 3.18
3.15E+01 2.85 1.00 3.18
3.77E+01 0.20 1.00 3.18 10000 1000
2.77E+01 1.88 1.00 3.18
1.74E+01 4.10 1.00 3.18
1.74E+01 3.80 1.00 3.18
2.96E+01 3.95 1.00 3.18
5.58E+01 1.01 1.00 3.18
3.65E+01 1.65 1.00 3.18
1.24E+01 2.27 1.00 3.18
4.70E+00 0.96 1.00 3.18
4.06E+00 3.46 1.00 3.18
8.87E+00 1.24 1.00 3.18
6.90E+00 0.49 1.00 3.18
6.55E+00 1.28 1.00 3.18
6.13E+00 0.80 1.00 3.18
4.44E+00 5.09 1.00 3.18
3.73E+00 1.05 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.76E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-483
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Mo SWA-L01-1315-T01-A 1 6.22E+00
Mo SWA-L01-1315-T02-A 1 1.41E+01
Mo SWA-L01-1315-T03-A 1 5.74E+00
Mo SWA-L01-1315-T04-A 1 1.35E+01
Mo SWA-L01-1315-T05-A 1 7.09E+00
Mo SWA-L01-1315-T06-A 1 8.04E+00
Mo SWA-L01-1315-T07-A 1 4.71E+00
Mo SWA-L01-1315-T08-A 1 3.24E+00 E
Mo SWA-L01-1315-T09-A 1 4.94E+00
Mo SWA-L01-1315-T01-B 1 4.38E+00
Mo SWA-L01-1315-T02-B 1 1.56E+01
Mo SWA-L01-1315-T03-B 1 7.84E+00
Mo SWA-L01-1315-T04-B 1 9.94E+00
Mo SWA-L01-1315-T05-B 1 7.78E+00
Mo SWA-L01-1315-T06-B 1 7.02E+00
Mo SWA-L01-1315-T07-B 1 5.99E+00
Mo SWA-L01-1315-T08-B 1 3.75E+00 E
Mo SWA-L01-1315-T09-B 1 3.63E+00 E
Mo SWA-L01-1315-T01-C 1 8.04E+00
Mo SWA-L01-1315-T02-C 1 1.95E+01
Mo SWA-L01-1315-T03-C 1 8.40E+00
Mo SWA-L01-1315-T04-C 1 1.52E+01
Mo SWA-L01-1315-T05-C 1 9.43E+00
Mo SWA-L01-1315-T06-C 1 1.05E+01
Mo SWA-L01-1315-T07-C 1 7.00E+00
Mo SWA-L01-1315-T08-C 1 3.05E+00 E
Mo SWA-L01-1315-T09-C 1 5.32E+00
Mo SWA-L01-1315-M01-A 1 6.00E-01 U1/2
Mo SWA-L01-1315-M02-A 1 6.00E-01 U1/2
Mo SWA-L01-1315-M03-A 1 6.00E-01 U1/2
Mo SWA-L01-1315-M04-A 1 6.00E-01 U1/2
Mo SWA-L01-1315-M05-A 1 6.00E-01 U1/2
Mo SWA-L01-1315-M06-A 1 6.00E-01 U1/2
Mo SWA-L01-1315-M07-A 1 6.00E-01 U1/2
Mo SWA-L01-1315-M08-A 1 6.00E-01 U1/2
Mo SWA-L01-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.22E+00 9.66 1.20 3.82
1.41E+01 5.77 1.20 3.82
5.74E+00 1.31 1.20 3.82 10000 1000
1.35E+01 7.76 1.20 3.82
7.09E+00 5.59 1.20 3.82
8.04E+00 10.22 1.20 3.82
4.71E+00 2.35 1.20 3.82
3.24E+00 17.22 1.20 3.82
4.94E+00 9.25 1.20 3.82
4.38E+00 3.32 1.20 3.82
1.56E+01 5.59 1.20 3.82
7.84E+00 8.74 1.20 3.82 10000 1000
9.94E+00 3.94 1.20 3.82
7.78E+00 1.38 1.20 3.82
7.02E+00 4.47 1.20 3.82
5.99E+00 1.92 1.20 3.82
3.75E+00 12.03 1.20 3.82
3.63E+00 28.89 1.20 3.82
8.04E+00 7.27 1.20 3.82
1.95E+01 7.32 1.20 3.82
8.40E+00 5.61 1.20 3.82 10000 1000
1.52E+01 3.48 1.20 3.82
9.43E+00 1.16 1.20 3.82
1.05E+01 10.25 1.20 3.82
7.00E+00 8.42 1.20 3.82
3.05E+00 14.16 1.20 3.82
5.32E+00 4.46 1.20 3.82
6.00E-01 3.56 1.20 3.82
6.00E-01 34.03 1.20 3.82
6.00E-01 54.37 1.20 3.82
6.00E-01 28.68 1.20 3.82
6.00E-01 26.39 1.20 3.82
6.00E-01 5.60 1.20 3.82
6.00E-01 15.51 1.20 3.82
6.00E-01 38.05 1.20 3.82
6.00E-01 17.60 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.55E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.70E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.66E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-484
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ni SWA-L01-1315-T01-A 1 9.00E-01 U1/2
Ni SWA-L01-1315-T02-A 1 9.00E-01 U1/2
Ni SWA-L01-1315-T03-A 1 9.00E-01 U1/2
Ni SWA-L01-1315-T04-A 1 9.00E-01 U1/2
Ni SWA-L01-1315-T05-A 1 9.00E-01 U1/2
Ni SWA-L01-1315-T06-A 1 9.00E-01 U1/2
Ni SWA-L01-1315-T07-A 1 9.00E-01 U1/2
Ni SWA-L01-1315-T08-A 1 9.00E-01 U1/2
Ni SWA-L01-1315-T09-A 1 9.00E-01 U1/2
Ni SWA-L01-1315-T01-B 1 9.00E-01 U1/2
Ni SWA-L01-1315-T02-B 1 9.00E-01 U1/2
Ni SWA-L01-1315-T03-B 1 9.00E-01 U1/2
Ni SWA-L01-1315-T04-B 1 9.00E-01 U1/2
Ni SWA-L01-1315-T05-B 1 9.00E-01 U1/2
Ni SWA-L01-1315-T06-B 1 9.00E-01 U1/2
Ni SWA-L01-1315-T07-B 1 9.00E-01 U1/2
Ni SWA-L01-1315-T08-B 1 9.00E-01 U1/2
Ni SWA-L01-1315-T09-B 1 9.00E-01 U1/2
Ni SWA-L01-1315-T01-C 1 9.00E-01 U1/2
Ni SWA-L01-1315-T02-C 1 9.00E-01 U1/2
Ni SWA-L01-1315-T03-C 1 9.00E-01 U1/2
Ni SWA-L01-1315-T04-C 1 9.00E-01 U1/2
Ni SWA-L01-1315-T05-C 1 9.00E-01 U1/2
Ni SWA-L01-1315-T06-C 1 9.00E-01 U1/2
Ni SWA-L01-1315-T07-C 1 9.00E-01 U1/2
Ni SWA-L01-1315-T08-C 1 9.00E-01 U1/2
Ni SWA-L01-1315-T09-C 1 9.00E-01 U1/2
Ni SWA-L01-1315-M01-A 1 9.00E-01 U1/2
Ni SWA-L01-1315-M02-A 1 9.00E-01 U1/2
Ni SWA-L01-1315-M03-A 1 9.00E-01 U1/2
Ni SWA-L01-1315-M04-A 1 9.00E-01 U1/2
Ni SWA-L01-1315-M05-A 1 9.00E-01 U1/2
Ni SWA-L01-1315-M06-A 1 9.00E-01 U1/2
Ni SWA-L01-1315-M07-A 1 9.00E-01 U1/2
Ni SWA-L01-1315-M08-A 1 9.00E-01 U1/2
Ni SWA-L01-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 43.81 1.80 5.70
9.00E-01 32.45 1.80 5.70
9.00E-01 8.14 1.80 5.70 10000 1000
9.00E-01 4.29 1.80 5.70
9.00E-01 21.06 1.80 5.70
9.00E-01 40.11 1.80 5.70
9.00E-01 51.25 1.80 5.70
9.00E-01 22.42 1.80 5.70
9.00E-01 24.23 1.80 5.70
9.00E-01 55.39 1.80 5.70
9.00E-01 32.88 1.80 5.70
9.00E-01 33.52 1.80 5.70 10000 1000
9.00E-01 46.69 1.80 5.70
9.00E-01 45.95 1.80 5.70
9.00E-01 45.85 1.80 5.70
9.00E-01 55.41 1.80 5.70
9.00E-01 36.85 1.80 5.70
9.00E-01 18.28 1.80 5.70
9.00E-01 26.78 1.80 5.70
9.00E-01 60.90 1.80 5.70
9.00E-01 43.51 1.80 5.70 10000 1000
9.00E-01 46.51 1.80 5.70
9.00E-01 73.18 1.80 5.70
9.00E-01 28.89 1.80 5.70
9.00E-01 26.97 1.80 5.70
9.00E-01 35.99 1.80 5.70
9.00E-01 41.09 1.80 5.70
9.00E-01 36.09 1.80 5.70
9.00E-01 29.13 1.80 5.70
9.00E-01 46.00 1.80 5.70
9.00E-01 42.98 1.80 5.70
9.00E-01 53.73 1.80 5.70
9.00E-01 26.10 1.80 5.70
9.00E-01 17.62 1.80 5.70
9.00E-01 22.91 1.80 5.70
9.00E-01 33.73 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.49E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.73E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.54E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-485
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L I
P SWA-L01-1315-T01-A 1 1.85E+00 U1/2
P SWA-L01-1315-T02-A 1 1.80E+01
P SWA-L01-1315-T03-A 1 1.85E+00 U1/2
P SWA-L01-1315-T04-A 1 1.85E+00 U1/2
P SWA-L01-1315-T05-A 1 1.85E+00 U1/2
P SWA-L01-1315-T06-A 1 1.92E+01
P SWA-L01-1315-T07-A 1 1.85E+00 U1/2
P SWA-L01-1315-T08-A 1 1.85E+00 U1/2
P SWA-L01-1315-T09-A 1 1.85E+00 U1/2
P SWA-L01-1315-T01-B 1 2.45E+01
P SWA-L01-1315-T02-B 1 1.14E+01 E
P SWA-L01-1315-T03-B 1 1.85E+00 U1/2
P SWA-L01-1315-T04-B 1 1.85E+00 U1/2
P SWA-L01-1315-T05-B 1 1.85E+00 U1/2
P SWA-L01-1315-T06-B 1 1.85E+00 U1/2
P SWA-L01-1315-T07-B 1 1.85E+00 U1/2
P SWA-L01-1315-T08-B 1 1.02E+01 E
P SWA-L01-1315-T09-B 1 1.96E+01
P SWA-L01-1315-T01-C 1 2.81E+01
P SWA-L01-1315-T02-C 1 1.85E+00 U1/2
P SWA-L01-1315-T03-C 1 1.05E+01 E
P SWA-L01-1315-T04-C 1 1.85E+00 U1/2
P SWA-L01-1315-T05-C 1 1.85E+00 U1/2
P SWA-L01-1315-T06-C 1 3.93E+01
P SWA-L01-1315-T07-C 1 1.21E+01
P SWA-L01-1315-T08-C 1 6.60E+00 E
P SWA-L01-1315-T09-C 1 1.85E+00 U1/2
P SWA-L01-1315-M01-A 1 1.85E+00 U1/2
P SWA-L01-1315-M02-A 1 1.85E+00 U1/2
P SWA-L01-1315-M03-A 1 1.85E+00 U1/2
P SWA-L01-1315-M04-A 1 1.85E+00 U1/2
P SWA-L01-1315-M05-A 1 1.85E+00 U1/2
P SWA-L01-1315-M06-A 1 1.85E+00 U1/2
P SWA-L01-1315-M07-A 1 1.85E+00 U1/2
P SWA-L01-1315-M08-A 1 1.85E+00 U1/2
P SWA-L01-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 5.43 3.70 11.80
1.80E+01 8.51 3.70 11.80
1.85E+00 2.87 3.70 11.80 10000 1000
1.85E+00 2.53 3.70 11.80
1.85E+00 5.70 3.70 11.80
1.92E+01 0.74 3.70 11.80
1.85E+00 10.48 3.70 11.80
1.85E+00 1.59 3.70 11.80
1.85E+00 2.39 3.70 11.80
2.45E+01 4.16 3.70 11.80
1.14E+01 6.38 3.70 11.80
1.85E+00 9.31 3.70 11.80 10000 1000
1.85E+00 9.93 3.70 11.80
1.85E+00 6.15 3.70 11.80
1.85E+00 5.96 3.70 11.80
1.85E+00 6.48 3.70 11.80
1.02E+01 2.81 3.70 11.80
1.96E+01 5.83 3.70 11.80
2.81E+01 5.45 3.70 11.80
1.85E+00 1.95 3.70 11.80
1.05E+01 4.24 3.70 11.80 10000 1000
1.85E+00 3.42 3.70 11.80
1.85E+00 1.88 3.70 11.80
3.93E+01 3.18 3.70 11.80
1.21E+01 5.27 3.70 11.80
6.60E+00 6.17 3.70 11.80
1.85E+00 3.14 3.70 11.80
1.85E+00 8.28 3.70 11.80
1.85E+00 5.69 3.70 11.80
1.85E+00 11.84 3.70 11.80
1.85E+00 2.07 3.70 11.80
1.85E+00 3.52 3.70 11.80
1.85E+00 1.29 3.70 11.80
1.85E+00 9.18 3.70 11.80
1.85E+00 4.55 3.70 11.80
1.85E+00 6.62 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.05E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-486
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
K SWA-L01-1315-T01-A 1 8.19E+03
K SWA-L01-1315-T02-A 1 3.35E+04
K SWA-L01-1315-T03-A 1 1.58E+04
K SWA-L01-1315-T04-A 1 3.84E+04
K SWA-L01-1315-T05-A 1 2.66E+04
K SWA-L01-1315-T06-A 1 2.91 E+04
K SWA-L01-1315-T07-A 1 2.02E+04
K SWA-L01-1315-T08-A 1 8.53E+03
K SWA-L01-1315-T09-A 1 1.27E+04
K SWA-L01-1315-T01-B 1 8.24E+03
K SWA-L01-1315-T02-B 1 3.76E+04
K SWA-L01-1315-T03-B 1 2.12E+04
K SWA-L01-1315-T04-B 1 3.32E+04
K SWA-L01-1315-T05-B 1 3.37E+04
K SWA-L01-1315-T06-B 1 3.61E+04
K SWA-L01-1315-T07-B 1 2.44E+04
K SWA-L01-1315-T08-B 1 1.04E+04
K SWA-L01-1315-T09-B 1 1.57E+04
K SWA-L01-1315-T01-C 1 1.02E+04
K SWA-L01-1315-T02-C 1 4.58E+04
K SWA-L01-1315-T03-C 1 2.15E+04
K SWA-L01-1315-T04-C 1 5.04E+04
K SWA-L01-1315-T05-C 1 3.62E+04
K SWA-L01-1315-T06-C 1 3.89E+04
K SWA-L01-1315-T07-C 1 2.70E+04
K SWA-L01-1315-T08-C 1 1.18E+04
K SWA-L01-1315-T09-C 1 1.71E+04
K SWA-L01-1315-M01-A 1 6.04E+01
K SWA-L01-1315-M02-A 1 4.94E+01
K SWA-L01-1315-M03-A 1 4.48E+01
K SWA-L01-1315-M04-A 1 4.39E+01
K SWA-L01-1315-M05-A 1 4.11E+01
K SWA-L01-1315-M06-A 1 4.28E+01
K SWA-L01-1315-M07-A 1 5.98E+01
K SWA-L01-1315-M08-A 1 3.60E+01
K SWA-L01-1315-M09-A 1 5.26E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.19E+03 0.16 1.60 5.09
3.35E+04 0.97 1.60 5.09
1.58E+04 0.48 1.60 5.09 10000 1000
3.84E+04 0.60 1.60 5.09
2.66E+04 0.79 1.60 5.09
2.91E+04 0.37 1.60 5.09
2.02E+04 0.26 1.60 5.09
8.53E+03 0.88 1.60 5.09
1.27E+04 0.86 1.60 5.09
8.24E+03 0.25 1.60 5.09
3.76E+04 0.80 1.60 5.09
2.12E+04 0.93 1.60 5.09 10000 1000
3.32E+04 0.92 1.60 5.09
3.37E+04 1.39 1.60 5.09
3.61E+04 0.61 1.60 5.09
2.44E+04 0.75 1.60 5.09
1.04E+04 1.49 1.60 5.09
1.57E+04 0.61 1.60 5.09
1.02E+04 0.68 1.60 5.09
4.58E+04 0.61 1.60 5.09
2.15E+04 0.57 1.60 5.09 10000 1000
5.04E+04 1.00 1.60 5.09
3.62E+04 0.69 1.60 5.09
3.89E+04 0.93 1.60 5.09
2.70E+04 2.42 1.60 5.09
1.18E+04 0.21 1.60 5.09
1.71E+04 0.15 1.60 5.09
6.04E+01 1.57 1.60 5.09
4.94E+01 0.77 1.60 5.09
4.48E+01 4.05 1.60 5.09
4.39E+01 1.25 1.60 5.09
4.11E+01 3.47 1.60 5.09
4.28E+01 1.19 1.60 5.09
5.98E+01 2.72 1.60 5.09
3.60E+01 3.87 1.60 5.09
5.26E+01 2.89 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.67E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.21E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.24E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-487
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Se SWA-L01-1315-T01-A 1 1.63E+03
Se SWA-L01-1315-T02-A 1 5.23E+03
Se SWA-L01-1315-T03-A 1 2.32E+03
Se SWA-L01-1315-T04-A 1 5.00E+03
Se SWA-L01-1315-T05-A 1 3.59E+03
Se SWA-L01-1315-T06-A 1 3.44E+03
Se SWA-L01-1315-T07-A 1 1.34E+03
Se SWA-L01-1315-T08-A 1 4.72E+02
Se SWA-L01-1315-T09-A 1 7.66E+02
Se SWA-L01-1315-T01-B 1 1.64E+03
Se SWA-L01-1315-T02-B 1 5.45E+03
Se SWA-L01-1315-T03-B 1 2.49E+03
Se SWA-L01-1315-T04-B 1 4.98E+03
Se SWA-L01-1315-T05-B 1 3.66E+03
Se SWA-L01-1315-T06-B 1 3.25E+03
Se SWA-L01-1315-T07-B 1 1.37E+03
Se SWA-L01-1315-T08-B 1 4.81E+02
Se SWA-L01-1315-T09-B 1 8.46E+02
Se SWA-L01-1315-T01-C 1 1.73E+03
Se SWA-L01-1315-T02-C 1 5.67E+03
Se SWA-L01-1315-T03-C 1 2.49E+03
Se SWA-L01-1315-T04-C 1 5.10E+03
Se SWA-L01-1315-T05-C 1 3.67E+03
Se SWA-L01-1315-T06-C 1 3.55E+03
Se SWA-L01-1315-T07-C 1 1.49E+03
Se SWA-L01-1315-T08-C 1 5.09E+02
Se SWA-L01-1315-T09-C 1 9.44E+02
Se SWA-L01-1315-M01-A 1 7.50E+00 U1/2
Se SWA-L01-1315-M02-A 1 7.50E+00 U1/2
Se SWA-L01-1315-M03-A 1 7.50E+00 U1/2
Se SWA-L01-1315-M04-A 1 7.50E+00 U1/2
Se SWA-L01-1315-M05-A 1 7.50E+00 U1/2
Se SWA-L01-1315-M06-A 1 7.50E+00 U1/2
Se SWA-L01-1315-M07-A 1 7.50E+00 U1/2
Se SWA-L01-1315-M08-A 1 7.50E+00 U1/2
Se SWA-L01-1315-M09-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.63E+03 0.74 15.00 47.70
5.23E+03 0.28 15.00 47.70
2.32E+03 0.84 15.00 47.70 10000 1000
5.00E+03 0.36 15.00 47.70
3.59E+03 1.25 15.00 47.70
3.44E+03 0.17 15.00 47.70
1.34E+03 1.12 15.00 47.70
4.72E+02 4.01 15.00 47.70
7.66E+02 2.56 15.00 47.70
1.64E+03 1.21 15.00 47.70
5.45E+03 0.46 15.00 47.70
2.49E+03 1.18 15.00 47.70 10000 1000
4.98E+03 1.75 15.00 47.70
3.66E+03 0.73 15.00 47.70
3.25E+03 0.93 15.00 47.70
1.37E+03 0.63 15.00 47.70
4.81E+02 1.83 15.00 47.70
8.46E+02 0.58 15.00 47.70
1.73E+03 0.82 15.00 47.70
5.67E+03 0.71 15.00 47.70
2.49E+03 1.11 15.00 47.70 10000 1000
5.10E+03 0.16 15.00 47.70
3.67E+03 0.90 15.00 47.70
3.55E+03 0.50 15.00 47.70
1.49E+03 0.34 15.00 47.70
5.09E+02 1.31 15.00 47.70
9.44E+02 0.60 15.00 47.70
7.50E+00 14.13 15.00 47.70
7.50E+00 11.61 15.00 47.70
7.50E+00 22.98 15.00 47.70
7.50E+00 13.96 15.00 47.70
7.50E+00 20.06 15.00 47.70
7.50E+00 20.78 15.00 47.70
7.50E+00 11.84 15.00 47.70
7.50E+00 9.93 15.00 47.70
7.50E+00 21.88 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.24E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.39E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.39E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/25/12 11:48 AM EPA Interlab L01 1315SWA
1/25/12 11:50 AM EPA Interlab L01 1315SWA
1/25/12 11:51 AM EPA Interlab L01 1315SWA
1/25/12 11:53 AM EPA Interlab L01 1315 SWA
1/25/12 11:55 AM EPA Interlab L01 1315 SWA
1/25/12 11:56 AM EPA Interlab L01 1315 SWA
1/25/12 11:58 AM EPA Interlab L01 1315 SWA
1/25/12 12:00 PM EPA Interlab L01 1315 SWA
1/25/12 12:01 PM EPA Interlab L01 1315 SWA
1/25/12 12:06 PM EPA Interlab L01 1315 SWA
1/25/12 12:08 PM EPA Interlab L01 1315 SWA
1/25/12 12:09 PM EPA Interlab L01 1315 SWA
1/25/1212:11 PM EPA Interlab L01 1315 SWA
1/25/12 12:13 PM EPA Interlab L01 1315 SWA
1/25/12 12:14 PM EPA Interlab L01 1315 SWA
1/25/12 12:16 PM EPA Interlab L01 1315 SWA
1/25/12 12:18 PM EPA Interlab L01 1315 SWA
1/25/12 12:19 PM EPA Interlab L01 1315 SWA
1/25/12 12:21 PM EPA Interlab L01 1315 SWA
1/25/12 12:23 PM EPA Interlab L01 1315 SWA
1/25/12 12:24 PM EPA Interlab L01 1315 SWA
1/25/12 12:26 PM EPA Interlab L01 1315 SWA
1/25/12 12:27 PM EPA Interlab L01 1315 SWA
1/25/12 12:29 PM EPA Interlab L01 1315 SWA
1/25/12 12:31 PM EPA Interlab L01 1315 SWA
1/25/12 12:32 PM EPA Interlab L01 1315 SWA
1/25/12 12:34 PM EPA Interlab L01 1315 SWA
1/25/12 11:33 AM EPA Interlab L01 1315 SWA
1/25/12 11:35 AM EPA Interlab L01 1315 SWA
1/25/12 11:36 AM EPA Interlab L01 1315 SWA
1/25/12 11:38 AM EPA Interlab L01 1315 SWA
1/25/12 11:40 AM EPA Interlab L01 1315 SWA
1/25/1211:41 AM EPA Interlab L01 1315 SWA
1/25/12 11:43 AM EPA Interlab L01 1315 SWA
1/25/12 11:45 AM EPA Interlab L01 1315 SWA
1/25/12 11:46 AM EPA Interlab L01 1315 SWA
1-488
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Si SWA-L01-1315-T01-A 1 5.62E+02
Si SWA-L01-1315-T02-A 1 4.55E+03
Si SWA-L01-1315-T03-A 1 3.41E+03
Si SWA-L01-1315-T04-A 1 8.38E+03
Si SWA-L01-1315-T05-A 1 7.55E+03
Si SWA-L01-1315-T06-A 1 8.09E+03
Si SWA-L01-1315-T07-A 1 7.32E+03
Si SWA-L01-1315-T08-A 1 5.30E+03
Si SWA-L01-1315-T09-A 1 6.85E+03
Si SWA-L01-1315-T01-B 1 5.47E+02
Si SWA-L01-1315-T02-B 1 5.10E+03
Si SWA-L01-1315-T03-B 1 4.08E+03
Si SWA-L01-1315-T04-B 1 5.89E+03
Si SWA-L01-1315-T05-B 1 7.59E+03
Si SWA-L01-1315-T06-B 1 8.12E+03
Si SWA-L01-1315-T07-B 1 7.31E+03
Si SWA-L01-1315-T08-B 1 5.27E+03
Si SWA-L01-1315-T09-B 1 6.89E+03
Si SWA-L01-1315-T01-C 1 6.37E+02
Si SWA-L01-1315-T02-C 1 5.88E+03
Si SWA-L01-1315-T03-C 1 4.10E+03
Si SWA-L01-1315-T04-C 1 8.59E+03
Si SWA-L01-1315-T05-C 1 7.77E+03
Si SWA-L01-1315-T06-C 1 8.39E+03
Si SWA-L01-1315-T07-C 1 7.39E+03
Si SWA-L01-1315-T08-C 1 5.34E+03
Si SWA-L01-1315-T09-C 1 6.67E+03
Si SWA-L01-1315-M01-A 1 5.50E-01 U1/2
Si SWA-L01-1315-M02-A 1 5.50E-01 U1/2
Si SWA-L01-1315-M03-A 1 5.50E-01 U1/2
Si SWA-L01-1315-M04-A 1 5.50E-01 U1/2
Si SWA-L01-1315-M05-A 1 5.50E-01 U1/2
Si SWA-L01-1315-M06-A 1 5.50E-01 U1/2
Si SWA-L01-1315-M07-A 1 5.50E-01 U1/2
Si SWA-L01-1315-M08-A 1 5.50E-01 U1/2
Si SWA-L01-1315-M09-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.62E+02 1.01 1.10 3.50
4.55E+03 0.22 1.10 3.50
3.41E+03 0.33 1.10 3.50 10000 1000
8.38E+03 1.61 1.10 3.50
7.55E+03 0.43 1.10 3.50
8.09E+03 0.92 1.10 3.50
7.32E+03 1.23 1.10 3.50
5.30E+03 1.19 1.10 3.50
6.85E+03 0.88 1.10 3.50
5.47E+02 0.87 1.10 3.50
5.10E+03 0.79 1.10 3.50
4.08E+03 0.25 1.10 3.50 10000 1000
5.89E+03 0.79 1.10 3.50
7.59E+03 0.55 1.10 3.50
8.12E+03 2.00 1.10 3.50
7.31E+03 2.42 1.10 3.50
5.27E+03 1.71 1.10 3.50
6.89E+03 1.93 1.10 3.50
6.37E+02 0.73 1.10 3.50
5.88E+03 0.19 1.10 3.50
4.10E+03 0.58 1.10 3.50 10000 1000
8.59E+03 0.12 1.10 3.50
7.77E+03 1.04 1.10 3.50
8.39E+03 0.07 1.10 3.50
7.39E+03 2.65 1.10 3.50
5.34E+03 0.66 1.10 3.50
6.67E+03 0.40 1.10 3.50
5.50E-01 6.74 1.10 3.50
5.50E-01 7.39 1.10 3.50
5.50E-01 7.28 1.10 3.50
5.50E-01 13.74 1.10 3.50
5.50E-01 18.41 1.10 3.50
5.50E-01 7.21 1.10 3.50
5.50E-01 10.81 1.10 3.50
5.50E-01 12.60 1.10 3.50
5.50E-01 17.45 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.36E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.01 E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.07E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-489
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Na SWA-L01-1315-T01-A 1 3.50E+04
Na SWA-L01-1315-T02-A 1 1.08E+05
Na SWA-L01-1315-T03-A 1 6.35E+04
Na SWA-L01-1315-T04-A 1 1.23E+05
Na SWA-L01-1315-T05-A 1 9.46E+04
Na SWA-L01-1315-T06-A 1 1.02E+05
Na SWA-L01-1315-T07-A 1 7.88E+04
Na SWA-L01-1315-T08-A 1 3.83E+04
Na SWA-L01-1315-T09-A 1 5.69E+04
Na SWA-L01-1315-T01-B 1 3.56E+04
Na SWA-L01-1315-T02-B 1 1.15E+05
Na SWA-L01-1315-T03-B 1 7.96E+04
Na SWA-L01-1315-T04-B 1 1.00E+05
Na SWA-L01-1315-T05-B 1 1.12E+05
Na SWA-L01-1315-T06-B 1 1.20E+05
Na SWA-L01-1315-T07-B 1 8.91E+04
Na SWA-L01-1315-T08-B 1 4.52E+04
Na SWA-L01-1315-T09-B 1 6.67E+04
Na SWA-L01-1315-T01-C 1 4.37E+04
Na SWA-L01-1315-T02-C 1 1.33E+05
Na SWA-L01-1315-T03-C 1 7.90E+04
Na SWA-L01-1315-T04-C 1 1.47E+05
Na SWA-L01-1315-T05-C 1 1.16E+05
Na SWA-L01-1315-T06-C 1 1.25E+05
Na SWA-L01-1315-T07-C 1 9.51E+04
Na SWA-L01-1315-T08-C 1 4.94E+04
Na SWA-L01-1315-T09-C 1 7.01E+04
Na SWA-L01-1315-M01-A 1 1.86E+01
Na SWA-L01-1315-M02-A 1 2.66E+01
Na SWA-L01-1315-M03-A 1 1.40E+01
Na SWA-L01-1315-M04-A 1 9.06E+00
Na SWA-L01-1315-M05-A 1 1.45E+01
Na SWA-L01-1315-M06-A 1 1.43E+01
Na SWA-L01-1315-M07-A 1 7.27E+00 E
Na SWA-L01-1315-M08-A 1 7.42E+00 E
Na SWA-L01-1315-M09-A 1 9.56E+00
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.50E+04 0.39 2.50 8.00
1.08E+05 0.23 2.50 8.00
6.35E+04 0.36 2.50 8.00 10000 1000
1.23E+05 0.35 2.50 8.00
9.46E+04 0.47 2.50 8.00
1.02E+05 0.18 2.50 8.00
7.88E+04 1.13 2.50 8.00
3.83E+04 0.58 2.50 8.00
5.69E+04 0.68 2.50 8.00
3.56E+04 0.45 2.50 8.00
1.15E+05 0.74 2.50 8.00
7.96E+04 0.72 2.50 8.00 10000 1000
1.00E+05 0.74 2.50 8.00
1.12E+05 0.38 2.50 8.00
1.20E+05 0.58 2.50 8.00
8.91 E+04 0.81 2.50 8.00
4.52E+04 0.81 2.50 8.00
6.67E+04 1.15 2.50 8.00
4.37E+04 0.58 2.50 8.00
1.33E+05 0.17 2.50 8.00
7.90E+04 0.31 2.50 8.00 10000 1000
1.47E+05 0.34 2.50 8.00
1.16E+05 0.41 2.50 8.00
1.25E+05 0.49 2.50 8.00
9.51E+04 1.18 2.50 8.00
4.94E+04 0.20 2.50 8.00
7. 01 E+04 0.73 2.50 8.00
1.86E+01 9.39 2.50 8.00
2.66E+01 8.20 2.50 8.00
1.40E+01 9.78 2.50 8.00
9.06E+00 1.27 2.50 8.00
1.45E+01 1.36 2.50 8.00
1.43E+01 9.35 2.50 8.00
7.27E+00 0.34 2.50 8.00
7.42E+00 10.15 2.50 8.00
9.56E+00 4.22 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.43E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.04E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.99E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-490
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Sr SWA-L01-1315-T01-A 1 3.33E+00
Sr SWA-L01-1315-T02-A 1 8.64E+01
Sr SWA-L01-1315-T03-A 1 1.21E+02
Sr SWA-L01-1315-T04-A 1 2.52E+02
Sr SWA-L01-1315-T05-A 1 2.91E+02
Sr SWA-L01-1315-T06-A 1 3.49E+02
Sr SWA-L01-1315-T07-A 1 3.22E+02
Sr SWA-L01-1315-T08-A 1 2.88E+02
Sr SWA-L01-1315-T09-A 1 2.63E+02
Sr SWA-L01-1315-T01-B 1 3.78E+00
Sr SWA-L01-1315-T02-B 1 7.75E+01
Sr SWA-L01-1315-T03-B 1 1.27E+02
Sr SWA-L01-1315-T04-B 1 1.63E+02
Sr SWA-L01-1315-T05-B 1 2.92E+02
Sr SWA-L01-1315-T06-B 1 3.47E+02
Sr SWA-L01-1315-T07-B 1 3.43E+02
Sr SWA-L01-1315-T08-B 1 3.00E+02
Sr SWA-L01-1315-T09-B 1 2.91E+02
Sr SWA-L01-1315-T01-C 1 4.40E+00
Sr SWA-L01-1315-T02-C 1 8.66E+01
Sr SWA-L01-1315-T03-C 1 1.27E+02
Sr SWA-L01-1315-T04-C 1 2.62E+02
Sr SWA-L01-1315-T05-C 1 3.35E+02
Sr SWA-L01-1315-T06-C 1 3.91E+02
Sr SWA-L01-1315-T07-C 1 4.13E+02
Sr SWA-L01-1315-T08-C 1 3.40E+02
Sr SWA-L01-1315-T09-C 1 3.69E+02
Sr SWA-L01-1315-M01-A 1 5.00E-01 U1/2
Sr SWA-L01-1315-M02-A 1 5.00E-01 U1/2
Sr SWA-L01-1315-M03-A 1 5.00E-01 U1/2
Sr SWA-L01-1315-M04-A 1 5.00E-01 U1/2
Sr SWA-L01-1315-M05-A 1 5.00E-01 U1/2
Sr SWA-L01-1315-M06-A 1 5.00E-01 U1/2
Sr SWA-L01-1315-M07-A 1 5.00E-01 U1/2
Sr SWA-L01-1315-M08-A 1 5.00E-01 U1/2
Sr SWA-L01-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.33E+00 0.99 1.00 3.18
8.64E+01 0.93 1.00 3.18
1.21E+02 0.79 1.00 3.18 10000 1000
2.52E+02 0.33 1.00 3.18
2.91E+02 1.19 1.00 3.18
3.49E+02 0.47 1.00 3.18
3.22E+02 0.45 1.00 3.18
2.88E+02 0.49 1.00 3.18
2.63E+02 1.26 1.00 3.18
3.78E+00 1.57 1.00 3.18
7.75E+01 0.86 1.00 3.18
1.27E+02 0.25 1.00 3.18 10000 1000
1.63E+02 0.80 1.00 3.18
2.92E+02 1.07 1.00 3.18
3.47E+02 0.51 1.00 3.18
3.43E+02 0.33 1.00 3.18
3.00E+02 1.81 1.00 3.18
2.91E+02 0.26 1.00 3.18
4.40E+00 1.53 1.00 3.18
8.66E+01 1.07 1.00 3.18
1.27E+02 0.79 1.00 3.18 10000 1000
2.62E+02 0.40 1.00 3.18
3.35E+02 0.86 1.00 3.18
3.91E+02 0.44 1.00 3.18
4.13E+02 0.47 1.00 3.18
3.40E+02 0.50 1.00 3.18
3.69E+02 0.25 1.00 3.18
5.00E-01 16.66 1.00 3.18
5.00E-01 7.31 1.00 3.18
5.00E-01 24.10 1.00 3.18
5.00E-01 20.01 1.00 3.18
5.00E-01 30.64 1.00 3.18
5.00E-01 6.83 1.00 3.18
5.00E-01 16.59 1.00 3.18
5.00E-01 8.76 1.00 3.18
5.00E-01 7.33 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-491
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
S SWA-L01-1315-T01-A 1 6.01E+03
S SWA-L01-1315-T02-A 1 2.12E+04
S SWA-L01-1315-T03-A 1 7.73E+03
S SWA-L01-1315-T04-A 1 1.76E+04
S SWA-L01-1315-T05-A 1 9.71E+03
S SWA-L01-1315-T06-A 1 9.83E+03
S SWA-L01-1315-T07-A 1 5.77E+03
S SWA-L01-1315-T08-A 1 2.23E+03
S SWA-L01-1315-T09-A 1 5.45E+03
S SWA-L01-1315-T01-B 1 5.94E+03
S SWA-L01-1315-T02-B 1 2.19E+04
S SWA-L01-1315-T03-B 1 9.88E+03
S SWA-L01-1315-T04-B 1 1.38E+04
S SWA-L01-1315-T05-B 1 1.32E+04
S SWA-L01-1315-T06-B 1 1.11E+04
S SWA-L01-1315-T07-B 1 6.51E+03
S SWA-L01-1315-T08-B 1 2.46E+03
S SWA-L01-1315-T09-B 1 6.13E+03
S SWA-L01-1315-T01-C 1 8.65E+03
S SWA-L01-1315-T02-C 1 2.98E+04
S SWA-L01-1315-T03-C 1 1.04E+04
S SWA-L01-1315-T04-C 1 2.33E+04
S SWA-L01-1315-T05-C 1 1.41E+04
S SWA-L01-1315-T06-C 1 1.35E+04
S SWA-L01-1315-T07-C 1 8.14E+03
S SWA-L01-1315-T08-C 1 3.15E+03
S SWA-L01-1315-T09-C 1 7.40E+03
S SWA-L01-1315-M01-A 1 3.40E+00 U1/2
S SWA-L01-1315-M02-A 1 3.40E+00 U1/2
S SWA-L01-1315-M03-A 1 3.40E+00 U1/2
S SWA-L01-1315-M04-A 1 3.40E+00 U1/2
S SWA-L01-1315-M05-A 1 3.40E+00 U1/2
S SWA-L01-1315-M06-A 1 3.40E+00 U1/2
S SWA-L01-1315-M07-A 1 3.40E+00 U1/2
S SWA-L01-1315-M08-A 1 3.40E+00 U1/2
S SWA-L01-1315-M09-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.01 E+03 0.77 6.80 21.60
2.12E+04 0.63 6.80 21.60
7.73E+03 0.63 6.80 21.60 10000 1000
1.76E+04 0.75 6.80 21.60
9.71 E+03 0.77 6.80 21.60
9.83E+03 0.03 6.80 21.60
5.77E+03 0.37 6.80 21.60
2.23E+03 1.27 6.80 21.60
5.45E+03 1.48 6.80 21.60
5.94E+03 0.52 6.80 21.60
2.19E+04 0.28 6.80 21.60
9.88E+03 1.35 6.80 21.60 10000 1000
1.38E+04 1.24 6.80 21.60
1.32E+04 1.08 6.80 21.60
1.11E+04 0.47 6.80 21.60
6.51E+03 1.16 6.80 21.60
2.46E+03 1.51 6.80 21.60
6.13E+03 1.56 6.80 21.60
8.65E+03 0.60 6.80 21.60
2.98E+04 0.44 6.80 21.60
1.04E+04 1.12 6.80 21.60 10000 1000
2.33E+04 0.08 6.80 21.60
1.41E+04 0.87 6.80 21.60
1.35E+04 1.12 6.80 21.60
8.14E+03 0.60 6.80 21.60
3.15E+03 0.88 6.80 21.60
7.40E+03 1.36 6.80 21.60
3.40E+00 2.26 6.80 21.60
3.40E+00 5.69 6.80 21.60
3.40E+00 1.84 6.80 21.60
3.40E+00 1.86 6.80 21.60
3.40E+00 3.38 6.80 21.60
3.40E+00 2.95 6.80 21.60
3.40E+00 3.47 6.80 21.60
3.40E+00 0.92 6.80 21.60
3.40E+00 1.45 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.69E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+04 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-492
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Tl SWA-L01-1315-T01-A 1 2.30E+00 U1/2
Tl SWA-L01-1315-T02-A 1 2.30E+00 U1/2
Tl SWA-L01-1315-T03-A 1 2.30E+00 U1/2
Tl SWA-L01-1315-T04-A 1 2.30E+00 U1/2
Tl SWA-L01-1315-T05-A 1 2.30E+00 U1/2
Tl SWA-L01-1315-T06-A 1 2.30E+00 U1/2
Tl SWA-L01-1315-T07-A 1 2.30E+00 U1/2
Tl SWA-L01-1315-T08-A 1 2.30E+00 U1/2
Tl SWA-L01-1315-T09-A 1 2.30E+00 U1/2
Tl SWA-L01-1315-T01-B 1 2.30E+00 U1/2
Tl SWA-L01-1315-T02-B 1 2.30E+00 U1/2
Tl SWA-L01-1315-T03-B 1 2.30E+00 U1/2
Tl SWA-L01-1315-T04-B 1 2.30E+00 U1/2
Tl SWA-L01-1315-T05-B 1 2.30E+00 U1/2
Tl SWA-L01-1315-T06-B 1 2.30E+00 U1/2
Tl SWA-L01-1315-T07-B 1 2.30E+00 U1/2
Tl SWA-L01-1315-T08-B 1 2.30E+00 U1/2
Tl SWA-L01-1315-T09-B 1 2.30E+00 U1/2
Tl SWA-L01-1315-T01-C 1 2.30E+00 U1/2
Tl SWA-L01-1315-T02-C 1 2.30E+00 U1/2
Tl SWA-L01-1315-T03-C 1 2.30E+00 U1/2
Tl SWA-L01-1315-T04-C 1 2.30E+00 U1/2
Tl SWA-L01-1315-T05-C 1 2.30E+00 U1/2
Tl SWA-L01-1315-T06-C 1 2.30E+00 U1/2
Tl SWA-L01-1315-T07-C 1 2.30E+00 U1/2
Tl SWA-L01-1315-T08-C 1 2.30E+00 U1/2
Tl SWA-L01-1315-T09-C 1 2.30E+00 U1/2
Tl SWA-L01-1315-M01-A 1 2.30E+00 U1/2
Tl SWA-L01-1315-M02-A 1 2.30E+00 U1/2
Tl SWA-L01-1315-M03-A 1 2.30E+00 U1/2
Tl SWA-L01-1315-M04-A 1 2.30E+00 U1/2
Tl SWA-L01-1315-M05-A 1 2.30E+00 U1/2
Tl SWA-L01-1315-M06-A 1 2.30E+00 U1/2
Tl SWA-L01-1315-M07-A 1 2.30E+00 U1/2
Tl SWA-L01-1315-M08-A 1 2.30E+00 U1/2
Tl SWA-L01-1315-M09-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 16.35 4.60 14.60
2.30E+00 22.04 4.60 14.60
2.30E+00 21.89 4.60 14.60 10000 1000
2.30E+00 5.70 4.60 14.60
2.30E+00 3.96 4.60 14.60
2.30E+00 7.99 4.60 14.60
2.30E+00 28.93 4.60 14.60
2.30E+00 10.64 4.60 14.60
2.30E+00 18.52 4.60 14.60
2.30E+00 49.90 4.60 14.60
2.30E+00 28.51 4.60 14.60
2.30E+00 25.45 4.60 14.60 10000 1000
2.30E+00 31.05 4.60 14.60
2.30E+00 13.87 4.60 14.60
2.30E+00 33.58 4.60 14.60
2.30E+00 22.35 4.60 14.60
2.30E+00 39.40 4.60 14.60
2.30E+00 34.79 4.60 14.60
2.30E+00 31.62 4.60 14.60
2.30E+00 41.51 4.60 14.60
2.30E+00 25.60 4.60 14.60 10000 1000
2.30E+00 13.68 4.60 14.60
2.30E+00 17.91 4.60 14.60
2.30E+00 20.16 4.60 14.60
2.30E+00 48.58 4.60 14.60
2.30E+00 6.48 4.60 14.60
2.30E+00 46.58 4.60 14.60
2.30E+00 14.38 4.60 14.60
2.30E+00 9.08 4.60 14.60
2.30E+00 8.44 4.60 14.60
2.30E+00 18.88 4.60 14.60
2.30E+00 17.48 4.60 14.60
2.30E+00 25.05 4.60 14.60
2.30E+00 22.94 4.60 14.60
2.30E+00 19.45 4.60 14.60
2.30E+00 17.71 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.42E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.21E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.39E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-493
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Ti SWA-L01-1315-T01-A 1 1.00E+00 U1/2
Ti SWA-L01-1315-T02-A 1 1.00E+00 U1/2
Ti SWA-L01-1315-T03-A 1 1.00E+00 U1/2
Ti SWA-L01-1315-T04-A 1 1.00E+00 U1/2
Ti SWA-L01-1315-T05-A 1 1.00E+00 U1/2
Ti SWA-L01-1315-T06-A 1 1.00E+00 U1/2
Ti SWA-L01-1315-T07-A 1 1.00E+00 U1/2
Ti SWA-L01-1315-T08-A 1 1.00E+00 U1/2
Ti SWA-L01-1315-T09-A 1 1.00E+00 U1/2
Ti SWA-L01-1315-T01-B 1 1.00E+00 U1/2
Ti SWA-L01-1315-T02-B 1 1.00E+00 U1/2
Ti SWA-L01-1315-T03-B 1 1.00E+00 U1/2
Ti SWA-L01-1315-T04-B 1 1.00E+00 U1/2
Ti SWA-L01-1315-T05-B 1 1.00E+00 U1/2
Ti SWA-L01-1315-T06-B 1 1.00E+00 U1/2
Ti SWA-L01-1315-T07-B 1 1.00E+00 U1/2
Ti SWA-L01-1315-T08-B 1 1.00E+00 U1/2
Ti SWA-L01-1315-T09-B 1 1.00E+00 U1/2
Ti SWA-L01-1315-T01-C 1 1.00E+00 U1/2
Ti SWA-L01-1315-T02-C 1 1.00E+00 U1/2
Ti SWA-L01-1315-T03-C 1 1.00E+00 U1/2
Ti SWA-L01-1315-T04-C 1 1.00E+00 U1/2
Ti SWA-L01-1315-T05-C 1 1.00E+00 U1/2
Ti SWA-L01-1315-T06-C 1 1.00E+00 U1/2
Ti SWA-L01-1315-T07-C 1 1.00E+00 U1/2
Ti SWA-L01-1315-T08-C 1 1.00E+00 U1/2
Ti SWA-L01-1315-T09-C 1 1.00E+00 U1/2
Ti SWA-L01-1315-M01-A 1 1.00E+00 U1/2
Ti SWA-L01-1315-M02-A 1 1.00E+00 U1/2
Ti SWA-L01-1315-M03-A 1 1.00E+00 U1/2
Ti SWA-L01-1315-M04-A 1 1.00E+00 U1/2
Ti SWA-L01-1315-M05-A 1 1.00E+00 U1/2
Ti SWA-L01-1315-M06-A 1 1.00E+00 U1/2
Ti SWA-L01-1315-M07-A 1 1.00E+00 U1/2
Ti SWA-L01-1315-M08-A 1 1.00E+00 U1/2
Ti SWA-L01-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 31.00 2.00 6.40
1.00E+00 50.28 2.00 6.40
1.00E+00 78.97 2.00 6.40 10000 1000
1.00E+00 64.02 2.00 6.40
1.00E+00 24.09 2.00 6.40
1.00E+00 67.00 2.00 6.40
1.00E+00 89.67 2.00 6.40
1.00E+00 53.70 2.00 6.40
1.00E+00 20.73 2.00 6.40
1.00E+00 46.34 2.00 6.40
1.00E+00 34.90 2.00 6.40
1.00E+00 45.18 2.00 6.40 10000 1000
1.00E+00 21.15 2.00 6.40
1.00E+00 16.77 2.00 6.40
1.00E+00 80.57 2.00 6.40
1.00E+00 63.09 2.00 6.40
1.00E+00 47.95 2.00 6.40
1.00E+00 61.44 2.00 6.40
1.00E+00 43.32 2.00 6.40
1.00E+00 72.31 2.00 6.40
1.00E+00 73.98 2.00 6.40 10000 1000
1.00E+00 68.18 2.00 6.40
1.00E+00 69.68 2.00 6.40
1.00E+00 60.23 2.00 6.40
1.00E+00 72.47 2.00 6.40
1.00E+00 43.93 2.00 6.40
1.00E+00 58.26 2.00 6.40
1.00E+00 58.59 2.00 6.40
1.00E+00 29.88 2.00 6.40
1.00E+00 24.21 2.00 6.40
1.00E+00 16.01 2.00 6.40
1.00E+00 30.08 2.00 6.40
1.00E+00 52.67 2.00 6.40
1.00E+00 17.09 2.00 6.40
1.00E+00 20.27 2.00 6.40
1.00E+00 32.33 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.43E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.31 E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.44E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-494
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
V SWA-L01-1315-T01-A 1 1.16E+01
V SWA-L01-1315-T02-A 1 2.40E+01
V SWA-L01-1315-T03-A 1 1.30E+01
V SWA-L01-1315-T04-A 1 2.08E+01
V SWA-L01-1315-T05-A 1 2.06E+01
V SWA-L01-1315-T06-A 1 2.25E+01
V SWA-L01-1315-T07-A 1 1.81E+01
V SWA-L01-1315-T08-A 1 1.21E+01
V SWA-L01-1315-T09-A 1 1.71E+01
V SWA-L01-1315-T01-B 1 1.22E+01
V SWA-L01-1315-T02-B 1 2.37E+01
V SWA-L01-1315-T03-B 1 1.61E+01
V SWA-L01-1315-T04-B 1 1.99E+01
V SWA-L01-1315-T05-B 1 2.20E+01
V SWA-L01-1315-T06-B 1 2.34E+01
V SWA-L01-1315-T07-B 1 1.96E+01
V SWA-L01-1315-T08-B 1 1.30E+01
V SWA-L01-1315-T09-B 1 1.71E+01
V SWA-L01-1315-T01-C 1 1.49E+01
V SWA-L01-1315-T02-C 1 2.54E+01
V SWA-L01-1315-T03-C 1 1.65E+01
V SWA-L01-1315-T04-C 1 2.14E+01
V SWA-L01-1315-T05-C 1 2.18E+01
V SWA-L01-1315-T06-C 1 2.40E+01
V SWA-L01-1315-T07-C 1 2.03E+01
V SWA-L01-1315-T08-C 1 1.50E+01
V SWA-L01-1315-T09-C 1 1.78E+01
V SWA-L01-1315-M01-A 1 7.50E-01 U1/2
V SWA-L01-1315-M02-A 1 7.50E-01 U1/2
V SWA-L01-1315-M03-A 1 7.50E-01 U1/2
V SWA-L01-1315-M04-A 1 7.50E-01 U1/2
V SWA-L01-1315-M05-A 1 7.50E-01 U1/2
V SWA-L01-1315-M06-A 1 7.50E-01 U1/2
V SWA-L01-1315-M07-A 1 7.50E-01 U1/2
V SWA-L01-1315-M08-A 1 7.50E-01 U1/2
V SWA-L01-1315-M09-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.16E+01 6.94 1.50 4.77
2.40E+01 3.14 1.50 4.77
1.30E+01 2.70 1.50 4.77 10000 1000
2.08E+01 2.11 1.50 4.77
2.06E+01 0.72 1.50 4.77
2.25E+01 1.80 1.50 4.77
1.81E+01 2.64 1.50 4.77
1.21E+01 8.56 1.50 4.77
1.71E+01 5.73 1.50 4.77
1.22E+01 4.10 1.50 4.77
2.37E+01 0.88 1.50 4.77
1.61E+01 3.00 1.50 4.77 10000 1000
1.99E+01 2.11 1.50 4.77
2.20E+01 4.20 1.50 4.77
2.34E+01 3.65 1.50 4.77
1.96E+01 0.93 1.50 4.77
1.30E+01 1.36 1.50 4.77
1.71E+01 0.57 1.50 4.77
1.49E+01 8.17 1.50 4.77
2.54E+01 0.51 1.50 4.77
1.65E+01 3.13 1.50 4.77 10000 1000
2.14E+01 1.88 1.50 4.77
2.18E+01 3.91 1.50 4.77
2.40E+01 1.20 1.50 4.77
2.03E+01 3.09 1.50 4.77
1.50E+01 3.41 1.50 4.77
1.78E+01 2.59 1.50 4.77
7.50E-01 27.91 1.50 4.77
7.50E-01 42.39 1.50 4.77
7.50E-01 4.94 1.50 4.77
7.50E-01 28.15 1.50 4.77
7.50E-01 10.53 1.50 4.77
7.50E-01 5.35 1.50 4.77
7.50E-01 12.47 1.50 4.77
7.50E-01 38.63 1.50 4.77
7.50E-01 23.47 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.73E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.21 E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.97E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/25/12 11:48 AM EPA Interlab L01 1315SWA
1/25/12 11:50 AM EPA Interlab L01 1315SWA
1/25/12 11:51 AM EPA Interlab L01 1315SWA
1/25/12 11:53 AM EPA Interlab L01 1315 SWA
1/25/12 11:55 AM EPA Interlab L01 1315 SWA
1/25/12 11:56 AM EPA Interlab L01 1315 SWA
1/25/12 11:58 AM EPA Interlab L01 1315 SWA
1/25/12 12:00 PM EPA Interlab L01 1315 SWA
1/25/12 12:01 PM EPA Interlab L01 1315 SWA
1/25/12 12:06 PM EPA Interlab L01 1315 SWA
1/25/12 12:08 PM EPA Interlab L01 1315 SWA
1/25/12 12:09 PM EPA Interlab L01 1315 SWA
1/25/1212:11 PM EPA Interlab L01 1315 SWA
1/25/12 12:13 PM EPA Interlab L01 1315 SWA
1/25/12 12:14 PM EPA Interlab L01 1315 SWA
1/25/12 12:16 PM EPA Interlab L01 1315 SWA
1/25/12 12:18 PM EPA Interlab L01 1315 SWA
1/25/12 12:19 PM EPA Interlab L01 1315 SWA
1/25/12 12:21 PM EPA Interlab L01 1315 SWA
1/25/12 12:23 PM EPA Interlab L01 1315 SWA
1/25/12 12:24 PM EPA Interlab L01 1315 SWA
1/25/12 12:26 PM EPA Interlab L01 1315 SWA
1/25/12 12:27 PM EPA Interlab L01 1315 SWA
1/25/12 12:29 PM EPA Interlab L01 1315 SWA
1/25/12 12:31 PM EPA Interlab L01 1315 SWA
1/25/12 12:32 PM EPA Interlab L01 1315 SWA
1/25/12 12:34 PM EPA Interlab L01 1315 SWA
1/25/12 11:33 AM EPA Interlab L01 1315 SWA
1/25/12 11:35 AM EPA Interlab L01 1315 SWA
1/25/12 11:36 AM EPA Interlab L01 1315 SWA
1/25/12 11:38 AM EPA Interlab L01 1315 SWA
1/25/12 11:40 AM EPA Interlab L01 1315 SWA
1/25/1211:41 AM EPA Interlab L01 1315 SWA
1/25/12 11:43 AM EPA Interlab L01 1315 SWA
1/25/12 11:45 AM EPA Interlab L01 1315 SWA
1/25/12 11:46 AM EPA Interlab L01 1315 SWA
1-495
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Zn SWA-L01-1315-T01-A 1 5.00E-01 U1/2
Zn SWA-L01-1315-T02-A 1 5.00E-01 U1/2
Zn SWA-L01-1315-T03-A 1 5.00E-01 U1/2
Zn SWA-L01-1315-T04-A 1 5.00E-01 U1/2
Zn SWA-L01-1315-T05-A 1 1.08E+00 E
Zn SWA-L01-1315-T06-A 1 5.00E-01 U1/2
Zn SWA-L01-1315-T07-A 1 5.00E-01 U1/2
Zn SWA-L01-1315-T08-A 1 5.00E-01 U1/2
Zn SWA-L01-1315-T09-A 1 5.00E-01 U1/2
Zn SWA-L01-1315-T01-B 1 5.00E-01 U1/2
Zn SWA-L01-1315-T02-B 1 5.00E-01 U1/2
Zn SWA-L01-1315-T03-B 1 5.00E-01 U1/2
Zn SWA-L01-1315-T04-B 1 1.09E+00 E
Zn SWA-L01-1315-T05-B 1 1.45E+00 E
Zn SWA-L01-1315-T06-B 1 5.00E-01 U1/2
Zn SWA-L01-1315-T07-B 1 5.00E-01 U1/2
Zn SWA-L01-1315-T08-B 1 5.00E-01 U1/2
Zn SWA-L01-1315-T09-B 1 5.00E-01 U1/2
Zn SWA-L01-1315-T01-C 1 5.00E-01 U1/2
Zn SWA-L01-1315-T02-C 1 5.00E-01 U1/2
Zn SWA-L01-1315-T03-C 1 5.00E-01 U1/2
Zn SWA-L01-1315-T04-C 1 5.00E-01 U1/2
Zn SWA-L01-1315-T05-C 1 5.00E-01 U1/2
Zn SWA-L01-1315-T06-C 1 5.00E-01 U1/2
Zn SWA-L01-1315-T07-C 1 5.00E-01 U1/2
Zn SWA-L01-1315-T08-C 1 5.00E-01 U1/2
Zn SWA-L01-1315-T09-C 1 5.00E-01 U1/2
Zn SWA-L01-1315-M01-A 1 5.00E-01 U1/2
Zn SWA-L01-1315-M02-A 1 5.00E-01 U1/2
Zn SWA-L01-1315-M03-A 1 5.00E-01 U1/2
Zn SWA-L01-1315-M04-A 1 5.00E-01 U1/2
Zn SWA-L01-1315-M05-A 1 5.00E-01 U1/2
Zn SWA-L01-1315-M06-A 1 5.00E-01 U1/2
Zn SWA-L01-1315-M07-A 1 5.00E-01 U1/2
Zn SWA-L01-1315-M08-A 1 5.00E-01 U1/2
Zn SWA-L01-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E-01 43.72 1.00 3.18
5.00E-01 28.56 1.00 3.18
5.00E-01 62.37 1.00 3.18 10000 1000
5.00E-01 14.30 1.00 3.18
1.08E+00 29.57 1.00 3.18
5.00E-01 38.52 1.00 3.18
5.00E-01 52.35 1.00 3.18
5.00E-01 24.96 1.00 3.18
5.00E-01 50.53 1.00 3.18
5.00E-01 27.19 1.00 3.18
5.00E-01 52.57 1.00 3.18
5.00E-01 23.34 1.00 3.18 10000 1000
1.09E+00 17.72 1.00 3.18
1.45E+00 11.81 1.00 3.18
5.00E-01 57.23 1.00 3.18
5.00E-01 29.49 1.00 3.18
5.00E-01 31.70 1.00 3.18
5.00E-01 20.65 1.00 3.18
5.00E-01 40.60 1.00 3.18
5.00E-01 19.87 1.00 3.18
5.00E-01 40.05 1.00 3.18 10000 1000
5.00E-01 19.33 1.00 3.18
5.00E-01 68.70 1.00 3.18
5.00E-01 42.97 1.00 3.18
5.00E-01 31.47 1.00 3.18
5.00E-01 18.41 1.00 3.18
5.00E-01 28.49 1.00 3.18
5.00E-01 27.16 1.00 3.18
5.00E-01 22.94 1.00 3.18
5.00E-01 18.13 1.00 3.18
5.00E-01 13.28 1.00 3.18
5.00E-01 25.37 1.00 3.18
5.00E-01 4.44 1.00 3.18
5.00E-01 33.92 1.00 3.18
5.00E-01 5.04 1.00 3.18
5.00E-01 8.76 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.97E+02 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.85E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/16/11 3:10 PM EPA Interlab L01 1315 SWA
2/16/11 3:11 PM EPA Interlab L01 1315 SWA
2/16/11 3:13 PM EPA Interlab L01 1315 SWA
2/16/11 3:15 PM EPA Interlab L01 1315 SWA
2/16/11 3:16 PM EPA Interlab L01 1315 SWA
2/16/11 3:18 PM EPA Interlab L01 1315 SWA
2/16/11 3:20 PM EPA Interlab L01 1315 SWA
2/16/11 3:21 PM EPA Interlab L01 1315 SWA
2/16/11 3:23 PM EPA Interlab L01 1315 SWA
2/16/11 3:25 PM EPA Interlab L01 1315 SWA
2/16/11 3:26 PM EPA Interlab L01 1315 SWA
2/16/11 3:28 PM EPA Interlab L01 1315 SWA
2/16/11 3:29 PM EPA Interlab L01 1315 SWA
2/16/11 3:31 PM EPA Interlab L01 1315 SWA
2/16/11 3:33 PM EPA Interlab L01 1315 SWA
2/16/11 3:34 PM EPA Interlab L01 1315 SWA
2/16/11 3:36 PM EPA Interlab L01 1315 SWA
2/16/11 3:38 PM EPA Interlab L01 1315 SWA
2/16/11 3:46 PM EPA Interlab L01 1315 SWA
2/16/11 3:48 PM EPA Interlab L01 1315 SWA
2/16/11 3:49 PM EPA Interlab L01 1315 SWA
2/16/11 3:51 PM EPA Interlab L01 1315 SWA
2/16/11 3:53 PM EPA Interlab L01 1315 SWA
2/16/11 3:54 PM EPA Interlab L01 1315 SWA
2/16/11 3:56 PM EPA Interlab L01 1315 SWA
2/16/11 3:57 PM EPA Interlab L01 1315 SWA
2/16/11 3:59 PM EPA Interlab L01 1315 SWA
2/16/11 2:27 PM EPA Interlab L01 1315 SWA
2/16/11 2:28 PM EPA Interlab L01 1315 SWA
2/16/11 2:53 PM EPA Interlab L01 1315 SWA
2/16/11 2:55 PM EPA Interlab L01 1315 SWA
2/16/11 2:57 PM EPA Interlab L01 1315 SWA
2/16/11 2:58 PM EPA Interlab L01 1315 SWA
2/16/11 3:00 PM EPA Interlab L01 1315 SWA
2/16/11 3:01 PM EPA Interlab L01 1315 SWA
2/16/11 3:03 PM EPA Interlab L01 1315 SWA
1-496
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1315:
Dilut
Element Sample ID Fact
Al SWA-L04-1315-T01-A
Al SWA-L04-1315-T02-A
Al SWA-L04-1315-T03-A
Al SWA-L04-1315-T04-A
Al SWA-L04-1315-T05-A
Al SWA-L04-1315-T06-A
Al SWA-L04-1315-T07-A
Al SWA-L04-1315-T08-A
Al SWA-L04-1315-T09-A
Al SWA-L04-1315-T01-B
Al SWA-L04-1315-T02-B
Al SWA-L04-1315-T03-B
Al SWA-L04-1315-T04-B
Al SWA-L04-1315-T05-B
Al SWA-L04-1315-T06-B
Al SWA-L04-1315-T07-B
Al SWA-L04-1315-T08-B
Al SWA-L04-1315-T09-B
Al SWA-L04-1315-T01-C
Al SWA-L04-1315-T02-C
Al SWA-L04-1315-T03-C
Al SWA-L04-1315-T04-C
Al SWA-L04-1315-T05-C
Al SWA-L04-1315-T06-C
Al SWA-L04-1315-T07-C
Al SWA-L04-1315-T08-C
Al SWA-L04-1315-T09-C
Al SWA-L04-1315-M01-A
Al SWA-L04-1315-M02-A
Al SWA-L04-1315-M03-A
Al SWA-L04-1315-M04-A
Al SWA-L04-1315-M05-A
Al SWA-L04-1315-M06-A
Al SWA-L04-1315-M07-A
Al SWA-L04-1315-M08-A
Al SWA-L04-1315-M09-A
on Sample
or Cone. Quallf
ug/L
1 4.24E+02
1 3.48E+03
1 2.38E+03
1 4.96E+03
1 4.55E+03
1 5.38E+03
1 4.12E+03
1 2.26E+03
1 3.96E+03
1 7.73E+02
1 3.79E+03
1 2.32E+03
1 4.94E+03
1 4.58E+03
1 5.05E+03
1 4.03E+03
1 2.19E+03
1 3.90E+03
1 6.98E+02
1 3.42E+03
1 2.49E+03
1 4.76E+03
1 4.51 E+03
1 5.13E+03
1 4. 11 E+03
1 2.27E+03
1 3.94E+03
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
er Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.24E+02 0.75 1.00 3.18
3.48E+03 0.83 1.00 3.18
2.38E+03 0.93 1.00 3.18 10000 1000
4.96E+03 0.38 1.00 3.18
4.55E+03 0.83 1.00 3.18
5.38E+03 0.83 1.00 3.18
4.12E+03 0.54 1.00 3.18
2.26E+03 2.35 1.00 3.18
3.96E+03 0.14 1.00 3.18
7.73E+02 0.19 1.00 3.18
3.79E+03 1.14 1.00 3.18
2.32E+03 1.51 1.00 3.18 10000 1000
4.94E+03 0.87 1.00 3.18
4.58E+03 1.34 1.00 3.18
5.05E+03 1.02 1.00 3.18
4.03E+03 1.90 1.00 3.18
2.19E+03 0.99 1.00 3.18
3.90E+03 1.25 1.00 3.18
6.98E+02 0.63 1.00 3.18
3.42E+03 0.98 1.00 3.18
2.49E+03 1.75 1.00 3.18 10000 1000
4.76E+03 0.87 1.00 3.18
4.51E+03 0.82 1.00 3.18
5.13E+03 0.74 1.00 3.18
4.11E+03 1.21 1.00 3.18
2.27E+03 0.80 1.00 3.18
3.94E+03 1.69 1.00 3.18
5.00E-01 11.87 1.00 3.18
5.00E-01 1.51 1.00 3.18
5.00E-01 8.42 1.00 3.18
5.00E-01 11.09 1.00 3.18
5.00E-01 24.51 1.00 3.18
5.00E-01 22.88 1.00 3.18
5.00E-01 34.94 1.00 3.18
5.00E-01 17.86 1.00 3.18
5.00E-01 11.03 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.30E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.27E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.36E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 1315 SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-497
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Sb SWA-L04-1315-T01-A 1 1.07E+02
Sb SWA-L04-1315-T02-A 1 4.61E+02
Sb SWA-L04-1315-T03-A 1 2.68E+02
Sb SWA-L04-1315-T04-A 1 4.58E+02
Sb SWA-L04-1315-T05-A 1 4.10E+02
Sb SWA-L04-1315-T06-A 1 4.82E+02
Sb SWA-L04-1315-T07-A 1 3.61 E+02
Sb SWA-L04-1315-T08-A 1 1.82E+02
Sb SWA-L04-1315-T09-A 1 3.23E+02
Sb SWA-L04-1315-T01-B 1 1.60E+02
Sb SWA-L04-1315-T02-B 1 4.55E+02
Sb SWA-L04-1315-T03-B 1 2.51E+02
Sb SWA-L04-1315-T04-B 1 4.80E+02
Sb SWA-L04-1315-T05-B 1 4.18E+02
Sb SWA-L04-1315-T06-B 1 4.49E+02
Sb SWA-L04-1315-T07-B 1 3.39E+02
Sb SWA-L04-1315-T08-B 1 1.97E+02
Sb SWA-L04-1315-T09-B 1 3.18E+02
Sb SWA-L04-1315-T01-C 1 1.70E+02
Sb SWA-L04-1315-T02-C 1 4.61E+02
Sb SWA-L04-1315-T03-C 1 2.26E+02
Sb SWA-L04-1315-T04-C 1 3.80E+02
Sb SWA-L04-1315-T05-C 1 3.68E+02
Sb SWA-L04-1315-T06-C 1 4.25E+02
Sb SWA-L04-1315-T07-C 1 3.45E+02
Sb SWA-L04-1315-T08-C 1 1.75E+02
Sb SWA-L04-1315-T09-C 1 3.21E+02
Sb SWA-L04-1315-M01-A 1 3.75E+00 U1/2
Sb SWA-L04-1315-M02-A 1 3.75E+00 U1/2
Sb SWA-L04-1315-M03-A 1 3.75E+00 U1/2
Sb SWA-L04-1315-M04-A 1 3.75E+00 U1/2
Sb SWA-L04-1315-M05-A 1 3.75E+00 U1/2
Sb SWA-L04-1315-M06-A 1 3.75E+00 U1/2
Sb SWA-L04-1315-M07-A 1 3.75E+00 U1/2
Sb SWA-L04-1315-M08-A 1 3.75E+00 U1/2
Sb SWA-L04-1315-M09-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.07E+02 2.67 7.50 23.90
4.61 E+02 6.71 7.50 23.90
2.68E+02 3.32 7.50 23.90 10000 1000
4.58E+02 0.82 7.50 23.90
4.10E+02 1.19 7.50 23.90
4.82E+02 0.89 7.50 23.90
3.61E+02 3.14 7.50 23.90
1.82E+02 2.82 7.50 23.90
3.23E+02 2.45 7.50 23.90
1.60E+02 2.05 7.50 23.90
4.55E+02 8.41 7.50 23.90
2.51E+02 1.34 7.50 23.90 10000 1000
4.80E+02 0.72 7.50 23.90
4.18E+02 1.66 7.50 23.90
4.49E+02 1.14 7.50 23.90
3.39E+02 2.73 7.50 23.90
1.97E+02 1.94 7.50 23.90
3.18E+02 2.43 7.50 23.90
1.70E+02 2.86 7.50 23.90
4.61E+02 4.27 7.50 23.90
2.26E+02 4.13 7.50 23.90 10000 1000
3.80E+02 2.68 7.50 23.90
3.68E+02 4.45 7.50 23.90
4.25E+02 2.73 7.50 23.90
3.45E+02 1.72 7.50 23.90
1.75E+02 2.45 7.50 23.90
3.21E+02 1.00 7.50 23.90
3.75E+00 11.08 7.50 23.90
3.75E+00 2.37 7.50 23.90
3.75E+00 27.91 7.50 23.90
3.75E+00 38.36 7.50 23.90
3.75E+00 36.04 7.50 23.90
3.75E+00 23.92 7.50 23.90
3.75E+00 8.31 7.50 23.90
3.75E+00 16.40 7.50 23.90
3.75E+00 33.57 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.18E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.19E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 131 5 SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-498
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
As SWA-L04-1315-T01-A 1 9.05E+01
As SWA-L04-1315-T02-A 1 2.62E+02
As SWA-L04-1315-T03-A 1 1.50E+02
As SWA-L04-1315-T04-A 1 3.16E+02
As SWA-L04-1315-T05-A 1 2.27E+02
As SWA-L04-1315-T06-A 1 2.49E+02
As SWA-L04-1315-T07-A 1 1.52E+02
As SWA-L04-1315-T08-A 1 7.06E+01
As SWA-L04-1315-T09-A 1 1.33E+02
As SWA-L04-1315-T01-B 1 1.24E+02
As SWA-L04-1315-T02-B 1 2.45E+02
As SWA-L04-1315-T03-B 1 1.55E+02
As SWA-L04-1315-T04-B 1 3.58E+02
As SWA-L04-1315-T05-B 1 2.61E+02
As SWA-L04-1315-T06-B 1 2.55E+02
As SWA-L04-1315-T07-B 1 1.67E+02
As SWA-L04-1315-T08-B 1 8.02E+01
As SWA-L04-1315-T09-B 1 1.36E+02
As SWA-L04-1315-T01-C 1 1.22E+02
As SWA-L04-1315-T02-C 1 2.52E+02
As SWA-L04-1315-T03-C 1 1.04E+02
As SWA-L04-1315-T04-C 1 2.11E+02
As SWA-L04-1315-T05-C 1 1.82E+02
As SWA-L04-1315-T06-C 1 1.95E+02
As SWA-L04-1315-T07-C 1 1.29E+02
As SWA-L04-1315-T08-C 1 6.42E+01
As SWA-L04-1315-T09-C 1 1.24E+02
As SWA-L04-1315-M01-A 1 5.50E+00 U1/2
As SWA-L04-1315-M02-A 1 5.50E+00 U1/2
As SWA-L04-1315-M03-A 1 5.50E+00 U1/2
As SWA-L04-1315-M04-A 1 5.50E+00 U1/2
As SWA-L04-1315-M05-A 1 5.50E+00 U1/2
As SWA-L04-1315-M06-A 1 5.50E+00 U1/2
As SWA-L04-1315-M07-A 1 5.50E+00 U1/2
As SWA-L04-1315-M08-A 1 5.50E+00 U1/2
As SWA-L04-1315-M09-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.05E+01 3.20 11.00 35.00
2.62E+02 8.02 11.00 35.00
1.50E+02 4.62 11.00 35.00 10000 1000
3.16E+02 1.84 11.00 35.00
2.27E+02 1.11 11.00 35.00
2.49E+02 1.80 11.00 35.00
1.52E+02 2.95 11.00 35.00
7.06E+01 4.01 11.00 35.00
1.33E+02 3.40 11.00 35.00
1.24E+02 0.51 11.00 35.00
2.45E+02 3.29 11.00 35.00
1.55E+02 2.78 11.00 35.00 10000 1000
3.58E+02 1.91 11.00 35.00
2.61E+02 1.52 11.00 35.00
2.55E+02 2.64 11.00 35.00
1.67E+02 4.06 11.00 35.00
8.02E+01 2.81 11.00 35.00
1.36E+02 7.16 11.00 35.00
1.22E+02 2.32 11.00 35.00
2.52E+02 8.92 11.00 35.00
1.04E+02 1.92 11.00 35.00 10000 1000
2.11E+02 2.20 11.00 35.00
1.82E+02 2.82 11.00 35.00
1.95E+02 3.40 11.00 35.00
1.29E+02 2.26 11.00 35.00
6.42E+01 3.29 11.00 35.00
1.24E+02 7.08 11.00 35.00
5.50E+00 7.33 11.00 35.00
5.50E+00 4.88 11.00 35.00
5.50E+00 13.29 11.00 35.00
5.50E+00 37.06 11.00 35.00
5.50E+00 49.64 11.00 35.00
5.50E+00 47.72 11.00 35.00
5.50E+00 11.12 11.00 35.00
5.50E+00 38.37 11.00 35.00
5.50E+00 26.65 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.08E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 131 5 SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-499
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
B SWA-L04-1315-T01-A 1 3.55E+01
B SWA-L04-1315-T02-A 1 1.16E+02
B SWA-L04-1315-T03-A 1 5.88E+01
B SWA-L04-1315-T04-A 1 9.33E+01
B SWA-L04-1315-T05-A 1 7.74E+01
B SWA-L04-1315-T06-A 1 8.78E+01
B SWA-L04-1315-T07-A 1 6.76E+01
B SWA-L04-1315-T08-A 1 3.55E+01
B SWA-L04-1315-T09-A 1 6.47E+01
B SWA-L04-1315-T01-B 1 3.95E+01
B SWA-L04-1315-T02-B 1 9.32E+01
B SWA-L04-1315-T03-B 1 4.93E+01
B SWA-L04-1315-T04-B 1 8.06E+01
B SWA-L04-1315-T05-B 1 6.90E+01
B SWA-L04-1315-T06-B 1 7.45E+01
B SWA-L04-1315-T07-B 1 5.76E+01
B SWA-L04-1315-T08-B 1 3.42E+01
B SWA-L04-1315-T09-B 1 5.60E+01
B SWA-L04-1315-T01-C 1 3.62E+01
B SWA-L04-1315-T02-C 1 9.31E+01
B SWA-L04-1315-T03-C 1 5.02E+01
B SWA-L04-1315-T04-C 1 7.18E+01
B SWA-L04-1315-T05-C 1 6.45E+01
B SWA-L04-1315-T06-C 1 7.22E+01
B SWA-L04-1315-T07-C 1 5.76E+01
B SWA-L04-1315-T08-C 1 3.21E+01
B SWA-L04-1315-T09-C 1 5.80E+01
B SWA-L04-1315-M01-A 1 5.00E-01 U1/2
B SWA-L04-1315-M02-A 1 5.00E-01 U1/2
B SWA-L04-1315-M03-A 1 5.00E-01 U1/2
B SWA-L04-1315-M04-A 1 5.00E-01 U1/2
B SWA-L04-1315-M05-A 1 5.00E-01 U1/2
B SWA-L04-1315-M06-A 1 5.00E-01 U1/2
B SWA-L04-1315-M07-A 1 5.00E-01 U1/2
B SWA-L04-1315-M08-A 1 5.00E-01 U1/2
B SWA-L04-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.55E+01 3.53 1.00 3.18
1.16E+02 8.03 1.00 3.18
5.88E+01 1.03 1.00 3.18 10000 1000
9.33E+01 1.06 1.00 3.18
7.74E+01 0.82 1.00 3.18
8.78E+01 2.34 1.00 3.18
6.76E+01 1.00 1.00 3.18
3.55E+01 1.78 1.00 3.18
6.47E+01 2.94 1.00 3.18
3.95E+01 1.78 1.00 3.18
9.32E+01 1.81 1.00 3.18
4.93E+01 1.69 1.00 3.18 10000 1000
8.06E+01 2.07 1.00 3.18
6.90E+01 2.98 1.00 3.18
7.45E+01 1.68 1.00 3.18
5.76E+01 2.65 1.00 3.18
3.42E+01 0.88 1.00 3.18
5.60E+01 3.07 1.00 3.18
3.62E+01 1.86 1.00 3.18
9.31E+01 4.49 1.00 3.18
5.02E+01 0.82 1.00 3.18 10000 1000
7.18E+01 2.20 1.00 3.18
6.45E+01 1.34 1.00 3.18
7.22E+01 0.59 1.00 3.18
5.76E+01 4.42 1.00 3.18
3.21E+01 2.85 1.00 3.18
5.80E+01 6.42 1.00 3.18
5.00E-01 5.37 1.00 3.18
5.00E-01 2.04 1.00 3.18
5.00E-01 7.06 1.00 3.18
5.00E-01 7.03 1.00 3.18
5.00E-01 8.97 1.00 3.18
5.00E-01 4.34 1.00 3.18
5.00E-01 3.59 1.00 3.18
5.00E-01 5.17 1.00 3.18
5.00E-01 2.20 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.93E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.98E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.92E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 131 5 SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-500
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
Ba SWA-L04-1315-T01-A 1 2.92E+01
Ba SWA-L04-1315-T02-A 1 2.59E+02
Ba SWA-L04-1315-T03-A 1 1.58E+02
Ba SWA-L04-1315-T04-A 1 2.19E+02
Ba SWA-L04-1315-T05-A 1 2.70E+02
Ba SWA-L04-1315-T06-A 1 2.85E+02
Ba SWA-L04-1315-T07-A 1 3.18E+02
Ba SWA-L04-1315-T08-A 1 3.13E+02
Ba SWA-L04-1315-T09-A 1 3.12E+02
Ba SWA-L04-1315-T01-B 1 1.79E+01
Ba SWA-L04-1315-T02-B 1 1.79E+02
Ba SWA-L04-1315-T03-B 1 1.44E+02
Ba SWA-L04-1315-T04-B 1 2.22E+02
Ba SWA-L04-1315-T05-B 1 2.69E+02
Ba SWA-L04-1315-T06-B 1 2.84E+02
Ba SWA-L04-1315-T07-B 1 2.80E+02
Ba SWA-L04-1315-T08-B 1 2.59E+02
Ba SWA-L04-1315-T09-B 1 2.61E+02
Ba SWA-L04-1315-T01-C 1 6.59E+01
Ba SWA-L04-1315-T02-C 1 2.87E+02
Ba SWA-L04-1315-T03-C 1 1.71E+02
Ba SWA-L04-1315-T04-C 1 2.36E+02
Ba SWA-L04-1315-T05-C 1 2.92E+02
Ba SWA-L04-1315-T06-C 1 3.08E+02
Ba SWA-L04-1315-T07-C 1 2.41E+02
Ba SWA-L04-1315-T08-C 1 3.04E+02
Ba SWA-L04-1315-T09-C 1 3.21E+02
Ba SWA-L04-1315-M01-A 1 5.00E-01 U1/2
Ba SWA-L04-1315-M02-A 1 5.00E-01 U1/2
Ba SWA-L04-1315-M03-A 1 5.00E-01 U1/2
Ba SWA-L04-1315-M04-A 1 5.00E-01 U1/2
Ba SWA-L04-1315-M05-A 1 5.00E-01 U1/2
Ba SWA-L04-1315-M06-A 1 5.00E-01 U1/2
Ba SWA-L04-1315-M07-A 1 5.00E-01 U1/2
Ba SWA-L04-1315-M08-A 1 5.00E-01 U1/2
Ba SWA-L04-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.92E+01 0.15 1.00 3.18
2.59E+02 7.70 1.00 3.18
1.58E+02 0.75 1.00 3.18 10000 1000
2.19E+02 0.19 1.00 3.18
2.70E+02 0.98 1.00 3.18
2.85E+02 0.49 1.00 3.18
3.18E+02 0.30 1.00 3.18
3.13E+02 1.97 1.00 3.18
3.12E+02 0.30 1.00 3.18
1.79E+01 0.44 1.00 3.18
1.79E+02 1.38 1.00 3.18
1.44E+02 1.92 1.00 3.18 10000 1000
2.22E+02 0.81 1.00 3.18
2.69E+02 1.13 1.00 3.18
2.84E+02 0.89 1.00 3.18
2.80E+02 0.90 1.00 3.18
2.59E+02 0.87 1.00 3.18
2.61E+02 1.32 1.00 3.18
6.59E+01 0.47 1.00 3.18
2.87E+02 3.16 1.00 3.18
1.71E+02 1.25 1.00 3.18 10000 1000
2.36E+02 1.80 1.00 3.18
2.92E+02 0.87 1.00 3.18
3.08E+02 0.84 1.00 3.18
2.41E+02 1.02 1.00 3.18
3.04E+02 0.71 1.00 3.18
3.21E+02 1.58 1.00 3.18
5.00E-01 17.32 1.00 3.18
5.00E-01 1.99 1.00 3.18
5.00E-01 10.44 1.00 3.18
5.00E-01 8.63 1.00 3.18
5.00E-01 9.46 1.00 3.18
5.00E-01 8.48 1.00 3.18
5.00E-01 14.75 1.00 3.18
5.00E-01 13.63 1.00 3.18
5.00E-01 5.60 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.05E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 131 5 SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-501
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Be SWA-L04-1315-T01-A 1 9.50E-01 U1/2
Be SWA-L04-1315-T02-A 1 9.50E-01 U1/2
Be SWA-L04-1315-T03-A 1 9.50E-01 U1/2
Be SWA-L04-1315-T04-A 1 9.50E-01 U1/2
Be SWA-L04-1315-T05-A 1 9.50E-01 U1/2
Be SWA-L04-1315-T06-A 1 9.50E-01 U1/2
Be SWA-L04-1315-T07-A 1 9.50E-01 U1/2
Be SWA-L04-1315-T08-A 1 9.50E-01 U1/2
Be SWA-L04-1315-T09-A 1 9.50E-01 U1/2
Be SWA-L04-1315-T01-B 1 9.50E-01 U1/2
Be SWA-L04-1315-T02-B 1 9.50E-01 U1/2
Be SWA-L04-1315-T03-B 1 9.50E-01 U1/2
Be SWA-L04-1315-T04-B 1 9.50E-01 U1/2
Be SWA-L04-1315-T05-B 1 9.50E-01 U1/2
Be SWA-L04-1315-T06-B 1 9.50E-01 U1/2
Be SWA-L04-1315-T07-B 1 9.50E-01 U1/2
Be SWA-L04-1315-T08-B 1 9.50E-01 U1/2
Be SWA-L04-1315-T09-B 1 9.50E-01 U1/2
Be SWA-L04-1315-T01-C 1 9.50E-01 U1/2
Be SWA-L04-1315-T02-C 1 9.50E-01 U1/2
Be SWA-L04-1315-T03-C 1 9.50E-01 U1/2
Be SWA-L04-1315-T04-C 1 9.50E-01 U1/2
Be SWA-L04-1315-T05-C 1 9.50E-01 U1/2
Be SWA-L04-1315-T06-C 1 9.50E-01 U1/2
Be SWA-L04-1315-T07-C 1 9.50E-01 U1/2
Be SWA-L04-1315-T08-C 1 9.50E-01 U1/2
Be SWA-L04-1315-T09-C 1 9.50E-01 U1/2
Be SWA-L04-1315-M01-A 1 9.50E-01 U1/2
Be SWA-L04-1315-M02-A 1 9.50E-01 U1/2
Be SWA-L04-1315-M03-A 1 9.50E-01 U1/2
Be SWA-L04-1315-M04-A 1 9.50E-01 U1/2
Be SWA-L04-1315-M05-A 1 9.50E-01 U1/2
Be SWA-L04-1315-M06-A 1 9.50E-01 U1/2
Be SWA-L04-1315-M07-A 1 9.50E-01 U1/2
Be SWA-L04-1315-M08-A 1 9.50E-01 U1/2
Be SWA-L04-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 15.96 1.90 6.00
9.50E-01 45.35 1.90 6.00
9.50E-01 34.88 1.90 6.00 10000 1000
9.50E-01 29.60 1.90 6.00
9.50E-01 11.36 1.90 6.00
9.50E-01 15.86 1.90 6.00
9.50E-01 30.18 1.90 6.00
9.50E-01 26.61 1.90 6.00
9.50E-01 29.24 1.90 6.00
9.50E-01 38.69 1.90 6.00
9.50E-01 41.24 1.90 6.00
9.50E-01 16.59 1.90 6.00 10000 1000
9.50E-01 18.69 1.90 6.00
9.50E-01 42.29 1.90 6.00
9.50E-01 34.85 1.90 6.00
9.50E-01 8.73 1.90 6.00
9.50E-01 7.13 1.90 6.00
9.50E-01 35.38 1.90 6.00
9.50E-01 40.95 1.90 6.00
9.50E-01 23.57 1.90 6.00
9.50E-01 8.79 1.90 6.00 10000 1000
9.50E-01 40.34 1.90 6.00
9.50E-01 9.52 1.90 6.00
9.50E-01 19.39 1.90 6.00
9.50E-01 49.13 1.90 6.00
9.50E-01 32.71 1.90 6.00
9.50E-01 52.27 1.90 6.00
9.50E-01 38.53 1.90 6.00
9.50E-01 22.51 1.90 6.00
9.50E-01 59.91 1.90 6.00
9.50E-01 13.17 1.90 6.00
9.50E-01 29.10 1.90 6.00
9.50E-01 26.08 1.90 6.00
9.50E-01 26.38 1.90 6.00
9.50E-01 9.38 1.90 6.00
9.50E-01 7.42 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.09E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.60E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.11E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 1315 SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-502
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cd SWA-L04-1315-T01-A 1 1.10E+00 U1/2
Cd SWA-L04-1315-T02-A 1 1.10E+00 U1/2
Cd SWA-L04-1315-T03-A 1 1.10E+00 U1/2
Cd SWA-L04-1315-T04-A 1 1.10E+00 U1/2
Cd SWA-L04-1315-T05-A 1 1.10E+00 U1/2
Cd SWA-L04-1315-T06-A 1 1.10E+00 U1/2
Cd SWA-L04-1315-T07-A 1 1.10E+00 U1/2
Cd SWA-L04-1315-T08-A 1 1.10E+00 U1/2
Cd SWA-L04-1315-T09-A 1 1.10E+00 U1/2
Cd SWA-L04-1315-T01-B 1 1.10E+00 U1/2
Cd SWA-L04-1315-T02-B 1 1.10E+00 U1/2
Cd SWA-L04-1315-T03-B 1 1.10E+00 U1/2
Cd SWA-L04-1315-T04-B 1 1.10E+00 U1/2
Cd SWA-L04-1315-T05-B 1 1.10E+00 U1/2
Cd SWA-L04-1315-T06-B 1 1.10E+00 U1/2
Cd SWA-L04-1315-T07-B 1 1.10E+00 U1/2
Cd SWA-L04-1315-T08-B 1 1.10E+00 U1/2
Cd SWA-L04-1315-T09-B 1 1.10E+00 U1/2
Cd SWA-L04-1315-T01-C 1 1.10E+00 U1/2
Cd SWA-L04-1315-T02-C 1 1.10E+00 U1/2
Cd SWA-L04-1315-T03-C 1 1.10E+00 U1/2
Cd SWA-L04-1315-T04-C 1 1.10E+00 U1/2
Cd SWA-L04-1315-T05-C 1 1.10E+00 U1/2
Cd SWA-L04-1315-T06-C 1 1.10E+00 U1/2
Cd SWA-L04-1315-T07-C 1 1.10E+00 U1/2
Cd SWA-L04-1315-T08-C 1 1.10E+00 U1/2
Cd SWA-L04-1315-T09-C 1 1.10E+00 U1/2
Cd SWA-L04-1315-M01-A 1 1.10E+00 U1/2
Cd SWA-L04-1315-M02-A 1 1.10E+00 U1/2
Cd SWA-L04-1315-M03-A 1 1.10E+00 U1/2
Cd SWA-L04-1315-M04-A 1 1.10E+00 U1/2
Cd SWA-L04-1315-M05-A 1 1.10E+00 U1/2
Cd SWA-L04-1315-M06-A 1 1.10E+00 U1/2
Cd SWA-L04-1315-M07-A 1 1.10E+00 U1/2
Cd SWA-L04-1315-M08-A 1 1.10E+00 U1/2
Cd SWA-L04-1315-M09-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 28.01 2.20 7.00
1.10E+00 19.43 2.20 7.00
1.10E+00 38.76 2.20 7.00 10000 1000
1.10E+00 41.82 2.20 7.00
1.10E+00 21.81 2.20 7.00
1.10E+00 31.14 2.20 7.00
1.10E+00 89.48 2.20 7.00
1.10E+00 9.55 2.20 7.00
1.10E+00 39.79 2.20 7.00
1.10E+00 18.85 2.20 7.00
1.10E+00 20.98 2.20 7.00
1.10E+00 29.01 2.20 7.00 10000 1000
1.10E+00 13.89 2.20 7.00
1.10E+00 62.60 2.20 7.00
1.10E+00 56.52 2.20 7.00
1.10E+00 34.07 2.20 7.00
1.10E+00 29.54 2.20 7.00
1.10E+00 51.38 2.20 7.00
1.10E+00 28.06 2.20 7.00
1.10E+00 44.67 2.20 7.00
1.10E+00 23.98 2.20 7.00 10000 1000
1.10E+00 43.61 2.20 7.00
1.10E+00 49.34 2.20 7.00
1.10E+00 56.36 2.20 7.00
1.10E+00 44.04 2.20 7.00
1.10E+00 28.23 2.20 7.00
1.10E+00 32.47 2.20 7.00
1.10E+00 18.38 2.20 7.00
1.10E+00 31.91 2.20 7.00
1.10E+00 16.96 2.20 7.00
1.10E+00 22.70 2.20 7.00
1.10E+00 73.74 2.20 7.00
1.10E+00 27.27 2.20 7.00
1.10E+00 17.05 2.20 7.00
1.10E+00 47.70 2.20 7.00
1.10E+00 18.54 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.69E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.49E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.06E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 1315SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-503
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Ca SWA-L04-1315-T01-A 1 1.12E+03
Ca SWA-L04-1315-T02-A 1 1.11E+04
Ca SWA-L04-1315-T03-A 1 1.17E+04
Ca SWA-L04-1315-T04-A 1 2.00E+04
Ca SWA-L04-1315-T05-A 1 2.24E+04
Ca SWA-L04-1315-T06-A 1 2.34E+04
Ca SWA-L04-1315-T07-A 1 2.40E+04
Ca SWA-L04-1315-T08-A 1 2.26E+04
Ca SWA-L04-1315-T09-A 1 2.36E+04
Ca SWA-L04-1315-T01-B 1 1.65E+03
Ca SWA-L04-1315-T02-B 1 1.19E+04
Ca SWA-L04-1315-T03-B 1 1.15E+04
Ca SWA-L04-1315-T04-B 1 2.02E+04
Ca SWA-L04-1315-T05-B 1 2.29E+04
Ca SWA-L04-1315-T06-B 1 2.42E+04
Ca SWA-L04-1315-T07-B 1 2.24E+04
Ca SWA-L04-1315-T08-B 1 1.97E+04
Ca SWA-L04-1315-T09-B 1 2.02E+04
Ca SWA-L04-1315-T01-C 1 1.44E+03
Ca SWA-L04-1315-T02-C 1 1.20E+04
Ca SWA-L04-1315-T03-C 1 1.27E+04
Ca SWA-L04-1315-T04-C 1 2.11E+04
Ca SWA-L04-1315-T05-C 1 2.39E+04
Ca SWA-L04-1315-T06-C 1 2.48E+04
Ca SWA-L04-1315-T07-C 1 1.70E+04
Ca SWA-L04-1315-T08-C 1 2.25E+04
Ca SWA-L04-1315-T09-C 1 2.39E+04
Ca SWA-L04-1315-M01-A 1 1.89E+02
Ca SWA-L04-1315-M02-A 1 1.19E+02
Ca SWA-L04-1315-M03-A 1 6.01E+01
Ca SWA-L04-1315-M04-A 1 1.27E+02
Ca SWA-L04-1315-M05-A 1 1.56E+02
Ca SWA-L04-1315-M06-A 1 2.36E+02
Ca SWA-L04-1315-M07-A 1 1.75E+02
Ca SWA-L04-1315-M08-A 1 1.62E+02
Ca SWA-L04-1315-M09-A 1 9.19E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.12E+03 2.88 2.60 8.30
1.11E+04 6.91 2.60 8.30
1.17E+04 0.49 2.60 8.30 10000 1000
2.00E+04 0.35 2.60 8.30
2.24E+04 1.24 2.60 8.30
2.34E+04 0.84 2.60 8.30
2.40E+04 0.49 2.60 8.30
2.26E+04 2.30 2.60 8.30
2.36E+04 0.24 2.60 8.30
1.65E+03 1.31 2.60 8.30
1.19E+04 1.60 2.60 8.30
1.15E+04 1.97 2.60 8.30 10000 1000
2.02E+04 0.51 2.60 8.30
2.29E+04 0.86 2.60 8.30
2.42E+04 1.12 2.60 8.30
2.24E+04 1.43 2.60 8.30
1.97E+04 0.72 2.60 8.30
2.02E+04 1.26 2.60 8.30
1.44E+03 2.10 2.60 8.30
1.20E+04 5.56 2.60 8.30
1.27E+04 2.22 2.60 8.30 10000 1000
2.11E+04 1.73 2.60 8.30
2.39E+04 0.86 2.60 8.30
2.48E+04 0.93 2.60 8.30
1.70E+04 0.88 2.60 8.30
2.25E+04 1.44 2.60 8.30
2.39E+04 1.17 2.60 8.30
1.89E+02 6.13 2.60 8.30
1.19E+02 1.88 2.60 8.30
6.01 E+01 7.83 2.60 8.30
1.27E+02 4.51 2.60 8.30
1.56E+02 3.62 2.60 8.30
2.36E+02 2.90 2.60 8.30
1.75E+02 2.56 2.60 8.30
1.62E+02 2.74 2.60 8.30
9.19E+01 7.22 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.26E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.23E+04 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.35E+04 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 1315 SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-504
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Cr SWA-L04-1315-T01-A 1 2.10E+01
Cr SWA-L04-1315-T02-A 1 8.21E+01
Cr SWA-L04-1315-T03-A 1 3.14E+01
Cr SWA-L04-1315-T04-A 1 5.49E+01
Cr SWA-L04-1315-T05-A 1 4.82E+01
Cr SWA-L04-1315-T06-A 1 5.33E+01
Cr SWA-L04-1315-T07-A 1 4.36E+01
Cr SWA-L04-1315-T08-A 1 2.34E+01
Cr SWA-L04-1315-T09-A 1 4.04E+01
Cr SWA-L04-1315-T01-B 1 3.11E+01
Cr SWA-L04-1315-T02-B 1 7.21E+01
Cr SWA-L04-1315-T03-B 1 2.47E+01
Cr SWA-L04-1315-T04-B 1 4.11E+01
Cr SWA-L04-1315-T05-B 1 3.84E+01
Cr SWA-L04-1315-T06-B 1 4.15E+01
Cr SWA-L04-1315-T07-B 1 3.78E+01
Cr SWA-L04-1315-T08-B 1 2.33E+01
Cr SWA-L04-1315-T09-B 1 3.81E+01
Cr SWA-L04-1315-T01-C 1 2.81E+01
Cr SWA-L04-1315-T02-C 1 6.67E+01
Cr SWA-L04-1315-T03-C 1 2.80E+01
Cr SWA-L04-1315-T04-C 1 4.77E+01
Cr SWA-L04-1315-T05-C 1 4.33E+01
Cr SWA-L04-1315-T06-C 1 4.71E+01
Cr SWA-L04-1315-T07-C 1 4.24E+01
Cr SWA-L04-1315-T08-C 1 2.37E+01
Cr SWA-L04-1315-T09-C 1 4.27E+01
Cr SWA-L04-1315-M01-A 1 6.00E-01 U1/2
Cr SWA-L04-1315-M02-A 1 6.00E-01 U1/2
Cr SWA-L04-1315-M03-A 1 6.00E-01 U1/2
Cr SWA-L04-1315-M04-A 1 6.00E-01 U1/2
Cr SWA-L04-1315-M05-A 1 6.00E-01 U1/2
Cr SWA-L04-1315-M06-A 1 6.00E-01 U1/2
Cr SWA-L04-1315-M07-A 1 6.00E-01 U1/2
Cr SWA-L04-1315-M08-A 1 6.00E-01 U1/2
Cr SWA-L04-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.10E+01 2.25 1.20 3.82
8.21 E+01 8.37 1.20 3.82
3.14E+01 0.82 1.20 3.82 10000 1000
5.49E+01 0.46 1.20 3.82
4.82E+01 2.04 1.20 3.82
5.33E+01 1.52 1.20 3.82
4.36E+01 0.52 1.20 3.82
2.34E+01 3.69 1.20 3.82
4.04E+01 2.16 1.20 3.82
3.11E+01 1.47 1.20 3.82
7.21E+01 1.68 1.20 3.82
2.47E+01 3.94 1.20 3.82 10000 1000
4.11E+01 1.08 1.20 3.82
3.84E+01 2.14 1.20 3.82
4.15E+01 1.20 1.20 3.82
3.78E+01 1.77 1.20 3.82
2.33E+01 1.15 1.20 3.82
3.81E+01 2.16 1.20 3.82
2.81E+01 2.40 1.20 3.82
6.67E+01 0.35 1.20 3.82
2.80E+01 2.58 1.20 3.82 10000 1000
4.77E+01 0.80 1.20 3.82
4.33E+01 0.81 1.20 3.82
4.71E+01 0.94 1.20 3.82
4.24E+01 1.58 1.20 3.82
2.37E+01 0.97 1.20 3.82
4.27E+01 3.23 1.20 3.82
6.00E-01 12.79 1.20 3.82
6.00E-01 2.18 1.20 3.82
6.00E-01 47.13 1.20 3.82
6.00E-01 21.01 1.20 3.82
6.00E-01 14.24 1.20 3.82
6.00E-01 36.43 1.20 3.82
6.00E-01 41.09 1.20 3.82
6.00E-01 44.84 1.20 3.82
6.00E-01 25.03 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.77E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.81 E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.82E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 131 5 SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-505
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Co SWA-L04-1315-T01-A 1 9.00E-01 U1/2
Co SWA-L04-1315-T02-A 1 9.00E-01 U1/2
Co SWA-L04-1315-T03-A 1 9.00E-01 U1/2
Co SWA-L04-1315-T04-A 1 9.00E-01 U1/2
Co SWA-L04-1315-T05-A 1 9.00E-01 U1/2
Co SWA-L04-1315-T06-A 1 9.00E-01 U1/2
Co SWA-L04-1315-T07-A 1 9.00E-01 U1/2
Co SWA-L04-1315-T08-A 1 9.00E-01 U1/2
Co SWA-L04-1315-T09-A 1 9.00E-01 U1/2
Co SWA-L04-1315-T01-B 1 9.00E-01 U1/2
Co SWA-L04-1315-T02-B 1 9.00E-01 U1/2
Co SWA-L04-1315-T03-B 1 9.00E-01 U1/2
Co SWA-L04-1315-T04-B 1 9.00E-01 U1/2
Co SWA-L04-1315-T05-B 1 9.00E-01 U1/2
Co SWA-L04-1315-T06-B 1 9.00E-01 U1/2
Co SWA-L04-1315-T07-B 1 9.00E-01 U1/2
Co SWA-L04-1315-T08-B 1 9.00E-01 U1/2
Co SWA-L04-1315-T09-B 1 9.00E-01 U1/2
Co SWA-L04-1315-T01-C 1 9.00E-01 U1/2
Co SWA-L04-1315-T02-C 1 9.00E-01 U1/2
Co SWA-L04-1315-T03-C 1 9.00E-01 U1/2
Co SWA-L04-1315-T04-C 1 9.00E-01 U1/2
Co SWA-L04-1315-T05-C 1 9.00E-01 U1/2
Co SWA-L04-1315-T06-C 1 9.00E-01 U1/2
Co SWA-L04-1315-T07-C 1 9.00E-01 U1/2
Co SWA-L04-1315-T08-C 1 9.00E-01 U1/2
Co SWA-L04-1315-T09-C 1 9.00E-01 U1/2
Co SWA-L04-1315-M01-A 1 9.00E-01 U1/2
Co SWA-L04-1315-M02-A 1 9.00E-01 U1/2
Co SWA-L04-1315-M03-A 1 9.00E-01 U1/2
Co SWA-L04-1315-M04-A 1 9.00E-01 U1/2
Co SWA-L04-1315-M05-A 1 9.00E-01 U1/2
Co SWA-L04-1315-M06-A 1 9.00E-01 U1/2
Co SWA-L04-1315-M07-A 1 9.00E-01 U1/2
Co SWA-L04-1315-M08-A 1 9.00E-01 U1/2
Co SWA-L04-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 22.05 1.80 5.72
9.00E-01 28.99 1.80 5.72
9.00E-01 39.48 1.80 5.72 10000 1000
9.00E-01 15.44 1.80 5.72
9.00E-01 33.06 1.80 5.72
9.00E-01 37.12 1.80 5.72
9.00E-01 46.83 1.80 5.72
9.00E-01 36.19 1.80 5.72
9.00E-01 63.36 1.80 5.72
9.00E-01 33.00 1.80 5.72
9.00E-01 24.62 1.80 5.72
9.00E-01 21.81 1.80 5.72 10000 1000
9.00E-01 22.78 1.80 5.72
9.00E-01 38.31 1.80 5.72
9.00E-01 26.94 1.80 5.72
9.00E-01 73.22 1.80 5.72
9.00E-01 59.48 1.80 5.72
9.00E-01 44.19 1.80 5.72
9.00E-01 31.12 1.80 5.72
9.00E-01 28.55 1.80 5.72
9.00E-01 27.96 1.80 5.72 10000 1000
9.00E-01 22.95 1.80 5.72
9.00E-01 77.61 1.80 5.72
9.00E-01 11.36 1.80 5.72
9.00E-01 25.63 1.80 5.72
9.00E-01 30.32 1.80 5.72
9.00E-01 33.25 1.80 5.72
9.00E-01 24.89 1.80 5.72
9.00E-01 19.26 1.80 5.72
9.00E-01 7.89 1.80 5.72
9.00E-01 48.38 1.80 5.72
9.00E-01 35.55 1.80 5.72
9.00E-01 57.22 1.80 5.72
9.00E-01 35.43 1.80 5.72
9.00E-01 7.07 1.80 5.72
9.00E-01 14.82 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.12E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.33E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.84E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 1315SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-506
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cu SWA-L04-1315-T01-A 1 1.85E+00 U1/2
Cu SWA-L04-1315-T02-A 1 1.85E+00 U1/2
Cu SWA-L04-1315-T03-A 1 1.85E+00 U1/2
Cu SWA-L04-1315-T04-A 1 1.85E+00 U1/2
Cu SWA-L04-1315-T05-A 1 1.85E+00 U1/2
Cu SWA-L04-1315-T06-A 1 1.85E+00 U1/2
Cu SWA-L04-1315-T07-A 1 1.85E+00 U1/2
Cu SWA-L04-1315-T08-A 1 1.85E+00 U1/2
Cu SWA-L04-1315-T09-A 1 1.85E+00 U1/2
Cu SWA-L04-1315-T01-B 1 1.85E+00 U1/2
Cu SWA-L04-1315-T02-B 1 1.85E+00 U1/2
Cu SWA-L04-1315-T03-B 1 1.85E+00 U1/2
Cu SWA-L04-1315-T04-B 1 1.85E+00 U1/2
Cu SWA-L04-1315-T05-B 1 1.85E+00 U1/2
Cu SWA-L04-1315-T06-B 1 1.85E+00 U1/2
Cu SWA-L04-1315-T07-B 1 1.85E+00 U1/2
Cu SWA-L04-1315-T08-B 1 1.85E+00 U1/2
Cu SWA-L04-1315-T09-B 1 1.85E+00 U1/2
Cu SWA-L04-1315-T01-C 1 1.85E+00 U1/2
Cu SWA-L04-1315-T02-C 1 1.85E+00 U1/2
Cu SWA-L04-1315-T03-C 1 1.85E+00 U1/2
Cu SWA-L04-1315-T04-C 1 1.85E+00 U1/2
Cu SWA-L04-1315-T05-C 1 1.85E+00 U1/2
Cu SWA-L04-1315-T06-C 1 1.85E+00 U1/2
Cu SWA-L04-1315-T07-C 1 1.85E+00 U1/2
Cu SWA-L04-1315-T08-C 1 1.85E+00 U1/2
Cu SWA-L04-1315-T09-C 1 1.85E+00 U1/2
Cu SWA-L04-1315-M01-A 1 1.85E+00 U1/2
Cu SWA-L04-1315-M02-A 1 1.85E+00 U1/2
Cu SWA-L04-1315-M03-A 1 1.85E+00 U1/2
Cu SWA-L04-1315-M04-A 1 1.85E+00 U1/2
Cu SWA-L04-1315-M05-A 1 1.85E+00 U1/2
Cu SWA-L04-1315-M06-A 1 1.85E+00 U1/2
Cu SWA-L04-1315-M07-A 1 1.85E+00 U1/2
Cu SWA-L04-1315-M08-A 1 1.85E+00 U1/2
Cu SWA-L04-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 29.46 3.70 11.80
1.85E+00 17.30 3.70 11.80
1.85E+00 31.23 3.70 11.80 10000 1000
1.85E+00 18.59 3.70 11.80
1.85E+00 45.90 3.70 11.80
1.85E+00 19.08 3.70 11.80
1.85E+00 17.51 3.70 11.80
1.85E+00 32.38 3.70 11.80
1.85E+00 20.86 3.70 11.80
1.85E+00 7.29 3.70 11.80
1.85E+00 13.80 3.70 11.80
1.85E+00 17.57 3.70 11.80 10000 1000
1.85E+00 21.81 3.70 11.80
1.85E+00 17.84 3.70 11.80
1.85E+00 12.61 3.70 11.80
1.85E+00 7.57 3.70 11.80
1.85E+00 27.09 3.70 11.80
1.85E+00 34.34 3.70 11.80
1.85E+00 20.14 3.70 11.80
1.85E+00 33.97 3.70 11.80
1.85E+00 34.03 3.70 11.80 10000 1000
1.85E+00 29.40 3.70 11.80
1.85E+00 23.75 3.70 11.80
1.85E+00 12.56 3.70 11.80
1.85E+00 10.13 3.70 11.80
1.85E+00 32.59 3.70 11.80
1.85E+00 33.78 3.70 11.80
1.85E+00 8.36 3.70 11.80
1.85E+00 49.02 3.70 11.80
1.85E+00 48.19 3.70 11.80
1.85E+00 36.76 3.70 11.80
1.85E+00 29.31 3.70 11.80
1.85E+00 5.14 3.70 11.80
1.85E+00 25.16 3.70 11.80
1.85E+00 28.47 3.70 11.80
1.85E+00 16.57 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.90E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.19E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.67E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 1315SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-507
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Fe SWA-L04-1315-T01-A 1 6.23E+00 E
Fe SWA-L04-1315-T02-A 1 1.10E+01
Fe SWA-L04-1315-T03-A 1 4.98E+00 E
Fe SWA-L04-1315-T04-A 1 5.63E+00 E
Fe SWA-L04-1315-T05-A 1 3.99E+00 E
Fe SWA-L04-1315-T06-A 1 4.17E+00 E
Fe SWA-L04-1315-T07-A 1 3.15E+00 E
Fe SWA-L04-1315-T08-A 1 1.00E+00 U1/2
Fe SWA-L04-1315-T09-A 1 2.22E+00 E
Fe SWA-L04-1315-T01-B 1 8.48E+00
Fe SWA-L04-1315-T02-B 1 1.30E+01
Fe SWA-L04-1315-T03-B 1 5.74E+00 E
Fe SWA-L04-1315-T04-B 1 5.48E+00 E
Fe SWA-L04-1315-T05-B 1 4.06E+00 E
Fe SWA-L04-1315-T06-B 1 4.22E+00 E
Fe SWA-L04-1315-T07-B 1 3.08E+00 E
Fe SWA-L04-1315-T08-B 1 1.00E+00 U1/2
Fe SWA-L04-1315-T09-B 1 2.21E+00 E
Fe SWA-L04-1315-T01-C 1 9.67E+00
Fe SWA-L04-1315-T02-C 1 1.22E+01
Fe SWA-L04-1315-T03-C 1 5.37E+00 E
Fe SWA-L04-1315-T04-C 1 4.53E+00 E
Fe SWA-L04-1315-T05-C 1 4.14E+00 E
Fe SWA-L04-1315-T06-C 1 4.14E+00 E
Fe SWA-L04-1315-T07-C 1 3.10E+00 E
Fe SWA-L04-1315-T08-C 1 1.00E+00 U1/2
Fe SWA-L04-1315-T09-C 1 2.83E+00 E
Fe SWA-L04-1315-M01-A 1 1.00E+00 U1/2
Fe SWA-L04-1315-M02-A 1 1.00E+00 U1/2
Fe SWA-L04-1315-M03-A 1 1.00E+00 U1/2
Fe SWA-L04-1315-M04-A 1 1.00E+00 U1/2
Fe SWA-L04-1315-M05-A 1 1.00E+00 U1/2
Fe SWA-L04-1315-M06-A 1 1.00E+00 U1/2
Fe SWA-L04-1315-M07-A 1 1.00E+00 U1/2
Fe SWA-L04-1315-M08-A 1 1.00E+00 U1/2
Fe SWA-L04-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.23E+00 5.47 2.00 6.40
1.10E+01 5.51 2.00 6.40
4.98E+00 7.02 2.00 6.40 10000 1000
5.63E+00 4.16 2.00 6.40
3.99E+00 3.89 2.00 6.40
4.17E+00 4.18 2.00 6.40
3.15E+00 1.38 2.00 6.40
1.00E+00 8.37 2.00 6.40
2.22E+00 4.38 2.00 6.40
8.48E+00 4.27 2.00 6.40
1.30E+01 1.88 2.00 6.40
5.74E+00 3.34 2.00 6.40 10000 1000
5.48E+00 5.05 2.00 6.40
4.06E+00 3.85 2.00 6.40
4.22E+00 3.96 2.00 6.40
3.08E+00 3.19 2.00 6.40
1.00E+00 5.47 2.00 6.40
2.21 E+00 17.35 2.00 6.40
9.67E+00 2.36 2.00 6.40
1.22E+01 9.85 2.00 6.40
5.37E+00 1.35 2.00 6.40 10000 1000
4.53E+00 2.17 2.00 6.40
4.14E+00 3.73 2.00 6.40
4.14E+00 1.29 2.00 6.40
3.10E+00 8.18 2.00 6.40
1.00E+00 3.02 2.00 6.40
2.83E+00 0.85 2.00 6.40
1.00E+00 12.20 2.00 6.40
1.00E+00 0.18 2.00 6.40
1.00E+00 15.16 2.00 6.40
1.00E+00 4.57 2.00 6.40
1.00E+00 1.38 2.00 6.40
1.00E+00 14.89 2.00 6.40
1.00E+00 13.65 2.00 6.40
1.00E+00 22.45 2.00 6.40
1.00E+00 17.11 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.42E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.20E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.66E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 1315 SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 131 5 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 131 5 SWA
10/10/11 2:17 PM EPA Interlab L04 131 5 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-508
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Pb SWA-L04-1315-T01-A 1 3.40E+00 U1/2
Pb SWA-L04-1315-T02-A 1 3.40E+00 U1/2
Pb SWA-L04-1315-T03-A 1 3.40E+00 U1/2
Pb SWA-L04-1315-T04-A 1 3.40E+00 U1/2
Pb SWA-L04-1315-T05-A 1 3.40E+00 U1/2
Pb SWA-L04-1315-T06-A 1 3.40E+00 U1/2
Pb SWA-L04-1315-T07-A 1 3.40E+00 U1/2
Pb SWA-L04-1315-T08-A 1 3.40E+00 U1/2
Pb SWA-L04-1315-T09-A 1 3.40E+00 U1/2
Pb SWA-L04-1315-T01-B 1 3.40E+00 U1/2
Pb SWA-L04-1315-T02-B 1 3.40E+00 U1/2
Pb SWA-L04-1315-T03-B 1 3.40E+00 U1/2
Pb SWA-L04-1315-T04-B 1 3.40E+00 U1/2
Pb SWA-L04-1315-T05-B 1 3.40E+00 U1/2
Pb SWA-L04-1315-T06-B 1 3.40E+00 U1/2
Pb SWA-L04-1315-T07-B 1 3.40E+00 U1/2
Pb SWA-L04-1315-T08-B 1 3.40E+00 U1/2
Pb SWA-L04-1315-T09-B 1 3.40E+00 U1/2
Pb SWA-L04-1315-T01-C 1 3.40E+00 U1/2
Pb SWA-L04-1315-T02-C 1 3.40E+00 U1/2
Pb SWA-L04-1315-T03-C 1 3.40E+00 U1/2
Pb SWA-L04-1315-T04-C 1 3.40E+00 U1/2
Pb SWA-L04-1315-T05-C 1 3.40E+00 U1/2
Pb SWA-L04-1315-T06-C 1 3.40E+00 U1/2
Pb SWA-L04-1315-T07-C 1 3.40E+00 U1/2
Pb SWA-L04-1315-T08-C 1 3.40E+00 U1/2
Pb SWA-L04-1315-T09-C 1 3.40E+00 U1/2
Pb SWA-L04-1315-M01-A 1 3.40E+00 U1/2
Pb SWA-L04-1315-M02-A 1 3.40E+00 U1/2
Pb SWA-L04-1315-M03-A 1 3.40E+00 U1/2
Pb SWA-L04-1315-M04-A 1 3.40E+00 U1/2
Pb SWA-L04-1315-M05-A 1 3.40E+00 U1/2
Pb SWA-L04-1315-M06-A 1 3.40E+00 U1/2
Pb SWA-L04-1315-M07-A 1 3.40E+00 U1/2
Pb SWA-L04-1315-M08-A 1 3.40E+00 U1/2
Pb SWA-L04-1315-M09-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 4.07 6.80 21.60
3.40E+00 17.37 6.80 21.60
3.40E+00 33.62 6.80 21.60 10000 1000
3.40E+00 66.70 6.80 21.60
3.40E+00 32.38 6.80 21.60
3.40E+00 27.21 6.80 21.60
3.40E+00 56.88 6.80 21.60
3.40E+00 13.81 6.80 21.60
3.40E+00 42.00 6.80 21.60
3.40E+00 15.82 6.80 21.60
3.40E+00 26.55 6.80 21.60
3.40E+00 52.69 6.80 21.60 10000 1000
3.40E+00 46.12 6.80 21.60
3.40E+00 63.41 6.80 21.60
3.40E+00 16.66 6.80 21.60
3.40E+00 34.12 6.80 21.60
3.40E+00 45.25 6.80 21.60
3.40E+00 6.07 6.80 21.60
3.40E+00 3.86 6.80 21.60
3.40E+00 18.52 6.80 21.60
3.40E+00 34.19 6.80 21.60 10000 1000
3.40E+00 29.99 6.80 21.60
3.40E+00 73.99 6.80 21.60
3.40E+00 8.20 6.80 21.60
3.40E+00 18.26 6.80 21.60
3.40E+00 19.85 6.80 21.60
3.40E+00 62.73 6.80 21.60
3.40E+00 72.36 6.80 21.60
3.40E+00 27.51 6.80 21.60
3.40E+00 72.13 6.80 21.60
3.40E+00 51.90 6.80 21.60
3.40E+00 30.45 6.80 21.60
3.40E+00 42.10 6.80 21.60
3.40E+00 27.69 6.80 21.60
3.40E+00 32.45 6.80 21.60
3.40E+00 65.53 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.39E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.19E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.73E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 1315 SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-509
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Li SWA-L04-1315-T01-A 1 9.50E-01 U1/2
Li SWA-L04-1315-T02-A 1 9.50E-01 U1/2
Li SWA-L04-1315-T03-A 1 9.50E-01 U1/2
Li SWA-L04-1315-T04-A 1 9.50E-01 U1/2
Li SWA-L04-1315-T05-A 1 9.50E-01 U1/2
Li SWA-L04-1315-T06-A 1 9.50E-01 U1/2
Li SWA-L04-1315-T07-A 1 9.50E-01 U1/2
Li SWA-L04-1315-T08-A 1 9.50E-01 U1/2
Li SWA-L04-1315-T09-A 1 9.50E-01 U1/2
Li SWA-L04-1315-T01-B 1 9.50E-01 U1/2
Li SWA-L04-1315-T02-B 1 9.50E-01 U1/2
Li SWA-L04-1315-T03-B 1 9.50E-01 U1/2
Li SWA-L04-1315-T04-B 1 9.50E-01 U1/2
Li SWA-L04-1315-T05-B 1 9.50E-01 U1/2
Li SWA-L04-1315-T06-B 1 9.50E-01 U1/2
Li SWA-L04-1315-T07-B 1 9.50E-01 U1/2
Li SWA-L04-1315-T08-B 1 9.50E-01 U1/2
Li SWA-L04-1315-T09-B 1 9.50E-01 U1/2
Li SWA-L04-1315-T01-C 1 9.50E-01 U1/2
Li SWA-L04-1315-T02-C 1 9.50E-01 U1/2
Li SWA-L04-1315-T03-C 1 9.50E-01 U1/2
Li SWA-L04-1315-T04-C 1 9.50E-01 U1/2
Li SWA-L04-1315-T05-C 1 9.50E-01 U1/2
Li SWA-L04-1315-T06-C 1 9.50E-01 U1/2
Li SWA-L04-1315-T07-C 1 9.50E-01 U1/2
Li SWA-L04-1315-T08-C 1 9.50E-01 U1/2
Li SWA-L04-1315-T09-C 1 9.50E-01 U1/2
Li SWA-L04-1315-M01-A 1 9.50E-01 U1/2
Li SWA-L04-1315-M02-A 1 9.50E-01 U1/2
Li SWA-L04-1315-M03-A 1 9.50E-01 U1/2
Li SWA-L04-1315-M04-A 1 9.50E-01 U1/2
Li SWA-L04-1315-M05-A 1 9.50E-01 U1/2
Li SWA-L04-1315-M06-A 1 9.50E-01 U1/2
Li SWA-L04-1315-M07-A 1 9.50E-01 U1/2
Li SWA-L04-1315-M08-A 1 9.50E-01 U1/2
Li SWA-L04-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 11.71 1.90 6.00
9.50E-01 38.49 1.90 6.00
9.50E-01 23.92 1.90 6.00 10000 1000
9.50E-01 13.12 1.90 6.00
9.50E-01 17.27 1.90 6.00
9.50E-01 1384.25 1.90 6.00
9.50E-01 27.23 1.90 6.00
9.50E-01 19.86 1.90 6.00
9.50E-01 35.14 1.90 6.00
9.50E-01 70.40 1.90 6.00
9.50E-01 94.91 1.90 6.00
9.50E-01 21.22 1.90 6.00 10000 1000
9.50E-01 46.07 1.90 6.00
9.50E-01 11.02 1.90 6.00
9.50E-01 32.29 1.90 6.00
9.50E-01 54.55 1.90 6.00
9.50E-01 61.41 1.90 6.00
9.50E-01 41.55 1.90 6.00
9.50E-01 47.05 1.90 6.00
9.50E-01 21.86 1.90 6.00
9.50E-01 25.39 1.90 6.00 10000 1000
9.50E-01 73.94 1.90 6.00
9.50E-01 21.74 1.90 6.00
9.50E-01 13.81 1.90 6.00
9.50E-01 34.70 1.90 6.00
9.50E-01 21.10 1.90 6.00
9.50E-01 57.24 1.90 6.00
9.50E-01 53.14 1.90 6.00
9.50E-01 18.34 1.90 6.00
9.50E-01 67.00 1.90 6.00
9.50E-01 67.65 1.90 6.00
9.50E-01 63.29 1.90 6.00
9.50E-01 28.82 1.90 6.00
9.50E-01 17.55 1.90 6.00
9.50E-01 49.86 1.90 6.00
9.50E-01 14.46 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.87E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.79E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.73E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 1315 SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-510
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Mn SWA-L04-1315-T01-A 1 1.00E+00 U1/2
Mn SWA-L04-1315-T02-A 1 1.00E+00 U1/2
Mn SWA-L04-1315-T03-A 1 1.00E+00 U1/2
Mn SWA-L04-1315-T04-A 1 1.00E+00 U1/2
Mn SWA-L04-1315-T05-A 1 1.00E+00 U1/2
Mn SWA-L04-1315-T06-A 1 1.00E+00 U1/2
Mn SWA-L04-1315-T07-A 1 1.00E+00 U1/2
Mn SWA-L04-1315-T08-A 1 1.00E+00 U1/2
Mn SWA-L04-1315-T09-A 1 1.00E+00 U1/2
Mn SWA-L04-1315-T01-B 1 1.00E+00 U1/2
Mn SWA-L04-1315-T02-B 1 1.00E+00 U1/2
Mn SWA-L04-1315-T03-B 1 1.00E+00 U1/2
Mn SWA-L04-1315-T04-B 1 1.00E+00 U1/2
Mn SWA-L04-1315-T05-B 1 1.00E+00 U1/2
Mn SWA-L04-1315-T06-B 1 1.00E+00 U1/2
Mn SWA-L04-1315-T07-B 1 1.00E+00 U1/2
Mn SWA-L04-1315-T08-B 1 1.00E+00 U1/2
Mn SWA-L04-1315-T09-B 1 1.00E+00 U1/2
Mn SWA-L04-1315-T01-C 1 1.00E+00 U1/2
Mn SWA-L04-1315-T02-C 1 1.00E+00 U1/2
Mn SWA-L04-1315-T03-C 1 1.00E+00 U1/2
Mn SWA-L04-1315-T04-C 1 1.00E+00 U1/2
Mn SWA-L04-1315-T05-C 1 1.00E+00 U1/2
Mn SWA-L04-1315-T06-C 1 1.00E+00 U1/2
Mn SWA-L04-1315-T07-C 1 1.00E+00 U1/2
Mn SWA-L04-1315-T08-C 1 1.00E+00 U1/2
Mn SWA-L04-1315-T09-C 1 1.00E+00 U1/2
Mn SWA-L04-1315-M01-A 1 1.00E+00 U1/2
Mn SWA-L04-1315-M02-A 1 1.00E+00 U1/2
Mn SWA-L04-1315-M03-A 1 1.00E+00 U1/2
Mn SWA-L04-1315-M04-A 1 1.00E+00 U1/2
Mn SWA-L04-1315-M05-A 1 1.00E+00 U1/2
Mn SWA-L04-1315-M06-A 1 1.00E+00 U1/2
Mn SWA-L04-1315-M07-A 1 1.00E+00 U1/2
Mn SWA-L04-1315-M08-A 1 1.00E+00 U1/2
Mn SWA-L04-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 8.22 2.00 6.40
1.00E+00 9.38 2.00 6.40
1.00E+00 17.27 2.00 6.40 10000 1000
1.00E+00 4.35 2.00 6.40
1.00E+00 0.40 2.00 6.40
1.00E+00 6.10 2.00 6.40
1.00E+00 9.92 2.00 6.40
1.00E+00 3.00 2.00 6.40
1.00E+00 13.11 2.00 6.40
1.00E+00 14.26 2.00 6.40
1.00E+00 3.79 2.00 6.40
1.00E+00 2.29 2.00 6.40 10000 1000
1.00E+00 19.87 2.00 6.40
1.00E+00 4.79 2.00 6.40
1.00E+00 9.13 2.00 6.40
1.00E+00 10.70 2.00 6.40
1.00E+00 5.49 2.00 6.40
1.00E+00 11.30 2.00 6.40
1.00E+00 16.63 2.00 6.40
1.00E+00 4.43 2.00 6.40
1.00E+00 6.41 2.00 6.40 10000 1000
1.00E+00 10.62 2.00 6.40
1.00E+00 10.32 2.00 6.40
1.00E+00 4.74 2.00 6.40
1.00E+00 26.79 2.00 6.40
1.00E+00 3.25 2.00 6.40
1.00E+00 7.38 2.00 6.40
1.00E+00 1.44 2.00 6.40
1.00E+00 4.21 2.00 6.40
1.00E+00 6.11 2.00 6.40
1.00E+00 7.91 2.00 6.40
1.00E+00 1.35 2.00 6.40
1.00E+00 7.48 2.00 6.40
1.00E+00 4.11 2.00 6.40
1.00E+00 1.44 2.00 6.40
1.00E+00 6.25 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.69E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.58E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.62E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 131 5 SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-511
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Mg SWA-L04-1315-T01-A 1 8.19E+00
Mg SWA-L04-1315-T02-A 1 1.97E+01
Mg SWA-L04-1315-T03-A 1 3.38E+01
Mg SWA-L04-1315-T04-A 1 7.16E+00
Mg SWA-L04-1315-T05-A 1 1.55E+01
Mg SWA-L04-1315-T06-A 1 8.95E+00
Mg SWA-L04-1315-T07-A 1 1.15E+01
Mg SWA-L04-1315-T08-A 1 4.93E+01
Mg SWA-L04-1315-T09-A 1 8.26E+00
Mg SWA-L04-1315-T01-B 1 1.45E+01
Mg SWA-L04-1315-T02-B 1 1.49E+01
Mg SWA-L04-1315-T03-B 1 2.99E+01
Mg SWA-L04-1315-T04-B 1 1.47E+01
Mg SWA-L04-1315-T05-B 1 1.51E+01
Mg SWA-L04-1315-T06-B 1 7.91E+00
Mg SWA-L04-1315-T07-B 1 1.73E+01
Mg SWA-L04-1315-T08-B 1 6.59E+01
Mg SWA-L04-1315-T09-B 1 1.74E+01
Mg SWA-L04-1315-T01-C 1 8.39E+00
Mg SWA-L04-1315-T02-C 1 2.67E+01
Mg SWA-L04-1315-T03-C 1 3.15E+01
Mg SWA-L04-1315-T04-C 1 1.38E+01
Mg SWA-L04-1315-T05-C 1 2.03E+01
Mg SWA-L04-1315-T06-C 1 4.52E+00
Mg SWA-L04-1315-T07-C 1 1.67E+01
Mg SWA-L04-1315-T08-C 1 5.83E+01
Mg SWA-L04-1315-T09-C 1 5.66E+00
Mg SWA-L04-1315-M01-A 1 1.66E+01
Mg SWA-L04-1315-M02-A 1 1.24E+01
Mg SWA-L04-1315-M03-A 1 7.45E+00
Mg SWA-L04-1315-M04-A 1 8.60E+00
Mg SWA-L04-1315-M05-A 1 2.22E+00 E
Mg SWA-L04-1315-M06-A 1 5.57E+00
Mg SWA-L04-1315-M07-A 1 4.89E+00
Mg SWA-L04-1315-M08-A 1 1.35E+00 E
Mg SWA-L04-1315-M09-A 1 3.55E+00
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.19E+00 3.81 1.00 3.18
1.97E+01 1.87 1.00 3.18
3.38E+01 4.46 1.00 3.18 10000 1000
7.16E+00 3.45 1.00 3.18
1.55E+01 2.76 1.00 3.18
8.95E+00 1.29 1.00 3.18
1.15E+01 2.64 1.00 3.18
4.93E+01 1.85 1.00 3.18
8.26E+00 1.34 1.00 3.18
1.45E+01 1.11 1.00 3.18
1.49E+01 2.65 1.00 3.18
2.99E+01 7.97 1.00 3.18 10000 1000
1.47E+01 2.21 1.00 3.18
1.51E+01 2.51 1.00 3.18
7.91E+00 2.65 1.00 3.18
1.73E+01 4.69 1.00 3.18
6.59E+01 4.68 1.00 3.18
1.74E+01 5.65 1.00 3.18
8.39E+00 8.78 1.00 3.18
2.67E+01 1.40 1.00 3.18
3.15E+01 1.23 1.00 3.18 10000 1000
1.38E+01 8.65 1.00 3.18
2.03E+01 1.77 1.00 3.18
4.52E+00 3.10 1.00 3.18
1.67E+01 14.40 1.00 3.18
5.83E+01 1.68 1.00 3.18
5.66E+00 3.45 1.00 3.18
1.66E+01 1.41 1.00 3.18
1.24E+01 1.64 1.00 3.18
7.45E+00 1.20 1.00 3.18
8.60E+00 7.86 1.00 3.18
2.22E+00 9.54 1.00 3.18
5.57E+00 1.80 1.00 3.18
4.89E+00 8.04 1.00 3.18
1.35E+00 4.78 1.00 3.18
3.55E+00 2.21 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.10E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.39E+02 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.89E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 131 5 SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-512
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Mo SWA-L04-1315-T01-A 1 2.97E+00 E
Mo SWA-L04-1315-T02-A 1 7.03E+00
Mo SWA-L04-1315-T03-A 1 4.09E+00
Mo SWA-L04-1315-T04-A 1 1.23E+01
Mo SWA-L04-1315-T05-A 1 9.43E+00
Mo SWA-L04-1315-T06-A 1 1.27E+01
Mo SWA-L04-1315-T07-A 1 7.88E+00
Mo SWA-L04-1315-T08-A 1 2.59E+00 E
Mo SWA-L04-1315-T09-A 1 6.25E+00
Mo SWA-L04-1315-T01-B 1 2.96E+00 E
Mo SWA-L04-1315-T02-B 1 6.30E+00
Mo SWA-L04-1315-T03-B 1 5.08E+00
Mo SWA-L04-1315-T04-B 1 1.14E+01
Mo SWA-L04-1315-T05-B 1 9.64E+00
Mo SWA-L04-1315-T06-B 1 1.06E+01
Mo SWA-L04-1315-T07-B 1 6.71E+00
Mo SWA-L04-1315-T08-B 1 2.66E+00 E
Mo SWA-L04-1315-T09-B 1 6.89E+00
Mo SWA-L04-1315-T01-C 1 3.24E+00 E
Mo SWA-L04-1315-T02-C 1 5.86E+00
Mo SWA-L04-1315-T03-C 1 4.45E+00
Mo SWA-L04-1315-T04-C 1 8.84E+00
Mo SWA-L04-1315-T05-C 1 8.12E+00
Mo SWA-L04-1315-T06-C 1 9.75E+00
Mo SWA-L04-1315-T07-C 1 6.33E+00
Mo SWA-L04-1315-T08-C 1 3.94E+00
Mo SWA-L04-1315-T09-C 1 6.92E+00
Mo SWA-L04-1315-M01-A 1 6.00E-01 U1/2
Mo SWA-L04-1315-M02-A 1 6.00E-01 U1/2
Mo SWA-L04-1315-M03-A 1 6.00E-01 U1/2
Mo SWA-L04-1315-M04-A 1 6.00E-01 U1/2
Mo SWA-L04-1315-M05-A 1 6.00E-01 U1/2
Mo SWA-L04-1315-M06-A 1 6.00E-01 U1/2
Mo SWA-L04-1315-M07-A 1 6.00E-01 U1/2
Mo SWA-L04-1315-M08-A 1 6.00E-01 U1/2
Mo SWA-L04-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.97E+00 3.62 1.20 3.82
7.03E+00 2.00 1.20 3.82
4.09E+00 2.09 1.20 3.82 10000 1000
1.23E+01 1.47 1.20 3.82
9.43E+00 2.21 1.20 3.82
1.27E+01 6.53 1.20 3.82
7.88E+00 3.65 1.20 3.82
2.59E+00 12.50 1.20 3.82
6.25E+00 4.61 1.20 3.82
2.96E+00 16.31 1.20 3.82
6.30E+00 12.93 1.20 3.82
5.08E+00 9.59 1.20 3.82 10000 1000
1.14E+01 9.58 1.20 3.82
9.64E+00 2.94 1.20 3.82
1.06E+01 3.33 1.20 3.82
6.71E+00 6.85 1.20 3.82
2.66E+00 8.57 1.20 3.82
6.89E+00 9.27 1.20 3.82
3.24E+00 1.97 1.20 3.82
5.86E+00 1.30 1.20 3.82
4.45E+00 3.23 1.20 3.82 10000 1000
8.84E+00 1.19 1.20 3.82
8.12E+00 8.82 1.20 3.82
9.75E+00 2.19 1.20 3.82
6.33E+00 1.02 1.20 3.82
3.94E+00 1.79 1.20 3.82
6.92E+00 2.15 1.20 3.82
6.00E-01 14.22 1.20 3.82
6.00E-01 12.29 1.20 3.82
6.00E-01 27.86 1.20 3.82
6.00E-01 15.61 1.20 3.82
6.00E-01 9.94 1.20 3.82
6.00E-01 20.64 1.20 3.82
6.00E-01 17.47 1.20 3.82
6.00E-01 6.21 1.20 3.82
6.00E-01 8.55 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.29E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.57E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.03E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 1315 SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2: 10PM EPA Interlab L04 131 5 SWA
10/10/11 2: 12PM EPA Interlab L04 131 5 SWA
10/10/11 2: 14PM EPA Interlab L04 131 5 SWA
10/10/11 2: 15PM EPA Interlab L04 131 5 SWA
10/10/11 2: 17PM EPA Interlab L04 131 5 SWA
10/10/11 2: 19PM EPA Interlab L04 131 5 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-513
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ni SWA-L04-1315-T01-A 1 9.00E-01 U1/2
Ni SWA-L04-1315-T02-A 1 9.00E-01 U1/2
Ni SWA-L04-1315-T03-A 1 9.00E-01 U1/2
Ni SWA-L04-1315-T04-A 1 9.00E-01 U1/2
Ni SWA-L04-1315-T05-A 1 9.00E-01 U1/2
Ni SWA-L04-1315-T06-A 1 9.00E-01 U1/2
Ni SWA-L04-1315-T07-A 1 9.00E-01 U1/2
Ni SWA-L04-1315-T08-A 1 9.00E-01 U1/2
Ni SWA-L04-1315-T09-A 1 9.00E-01 U1/2
Ni SWA-L04-1315-T01-B 1 9.00E-01 U1/2
Ni SWA-L04-1315-T02-B 1 9.00E-01 U1/2
Ni SWA-L04-1315-T03-B 1 9.00E-01 U1/2
Ni SWA-L04-1315-T04-B 1 9.00E-01 U1/2
Ni SWA-L04-1315-T05-B 1 9.00E-01 U1/2
Ni SWA-L04-1315-T06-B 1 9.00E-01 U1/2
Ni SWA-L04-1315-T07-B 1 9.00E-01 U1/2
Ni SWA-L04-1315-T08-B 1 9.00E-01 U1/2
Ni SWA-L04-1315-T09-B 1 9.00E-01 U1/2
Ni SWA-L04-1315-T01-C 1 9.00E-01 U1/2
Ni SWA-L04-1315-T02-C 1 9.00E-01 U1/2
Ni SWA-L04-1315-T03-C 1 9.00E-01 U1/2
Ni SWA-L04-1315-T04-C 1 9.00E-01 U1/2
Ni SWA-L04-1315-T05-C 1 9.00E-01 U1/2
Ni SWA-L04-1315-T06-C 1 9.00E-01 U1/2
Ni SWA-L04-1315-T07-C 1 9.00E-01 U1/2
Ni SWA-L04-1315-T08-C 1 9.00E-01 U1/2
Ni SWA-L04-1315-T09-C 1 9.00E-01 U1/2
Ni SWA-L04-1315-M01-A 1 9.00E-01 U1/2
Ni SWA-L04-1315-M02-A 1 9.00E-01 U1/2
Ni SWA-L04-1315-M03-A 1 9.00E-01 U1/2
Ni SWA-L04-1315-M04-A 1 9.00E-01 U1/2
Ni SWA-L04-1315-M05-A 1 9.00E-01 U1/2
Ni SWA-L04-1315-M06-A 1 9.00E-01 U1/2
Ni SWA-L04-1315-M07-A 1 9.00E-01 U1/2
Ni SWA-L04-1315-M08-A 1 9.00E-01 U1/2
Ni SWA-L04-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 55.62 1.80 5.70
9.00E-01 30.51 1.80 5.70
9.00E-01 23.58 1.80 5.70 10000 1000
9.00E-01 26.28 1.80 5.70
9.00E-01 17.65 1.80 5.70
9.00E-01 35.38 1.80 5.70
9.00E-01 42.37 1.80 5.70
9.00E-01 74.61 1.80 5.70
9.00E-01 66.33 1.80 5.70
9.00E-01 31.03 1.80 5.70
9.00E-01 40.51 1.80 5.70
9.00E-01 15.21 1.80 5.70 10000 1000
9.00E-01 54.95 1.80 5.70
9.00E-01 42.38 1.80 5.70
9.00E-01 13.52 1.80 5.70
9.00E-01 34.40 1.80 5.70
9.00E-01 3.89 1.80 5.70
9.00E-01 63.98 1.80 5.70
9.00E-01 40.36 1.80 5.70
9.00E-01 90.11 1.80 5.70
9.00E-01 43.75 1.80 5.70 10000 1000
9.00E-01 15.02 1.80 5.70
9.00E-01 68.23 1.80 5.70
9.00E-01 30.85 1.80 5.70
9.00E-01 50.01 1.80 5.70
9.00E-01 52.82 1.80 5.70
9.00E-01 35.81 1.80 5.70
9.00E-01 10.27 1.80 5.70
9.00E-01 26.28 1.80 5.70
9.00E-01 24.55 1.80 5.70
9.00E-01 56.15 1.80 5.70
9.00E-01 26.66 1.80 5.70
9.00E-01 41.61 1.80 5.70
9.00E-01 25.49 1.80 5.70
9.00E-01 9.09 1.80 5.70
9.00E-01 15.82 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.80E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.66E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.75E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 1315SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-514
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
P SWA-L04-1315-T01-A 1 1.51E+01
P SWA-L04-1315-T02-A 1 6.73E+00 E
P SWA-L04-1315-T03-A 1 1.85E+00 U1/2
P SWA-L04-1315-T04-A 1 1.47E+01
P SWA-L04-1315-T05-A 1 9.40E+00 E
P SWA-L04-1315-T06-A 1 9.14E+00 E
P SWA-L04-1315-T07-A 1 1.39E+01
P SWA-L04-1315-T08-A 1 1.81E+01
P SWA-L04-1315-T09-A 1 8.39E+00 E
P SWA-L04-1315-T01-B 1 2.40E+01
P SWA-L04-1315-T02-B 1 1.52E+01
P SWA-L04-1315-T03-B 1 1.85E+00 U1/2
P SWA-L04-1315-T04-B 1 7.87E+00 E
P SWA-L04-1315-T05-B 1 1.85E+00 U1/2
P SWA-L04-1315-T06-B 1 1.85E+00 U1/2
P SWA-L04-1315-T07-B 1 7.74E+00 E
P SWA-L04-1315-T08-B 1 1.85E+00 U1/2
P SWA-L04-1315-T09-B 1 7.91E+00 E
P SWA-L04-1315-T01-C 1 2.32E+01
P SWA-L04-1315-T02-C 1 2.63E+01
P SWA-L04-1315-T03-C 1 1.85E+00 U1/2
P SWA-L04-1315-T04-C 1 9.60E+00 E
P SWA-L04-1315-T05-C 1 1.85E+00 U1/2
P SWA-L04-1315-T06-C 1 7.51E+00 E
P SWA-L04-1315-T07-C 1 6.13E+00 E
P SWA-L04-1315-T08-C 1 1.32E+01
P SWA-L04-1315-T09-C 1 1.01E+01 E
P SWA-L04-1315-M01-A 1 1.85E+00 U1/2
P SWA-L04-1315-M02-A 1 1.85E+00 U1/2
P SWA-L04-1315-M03-A 1 1.85E+00 U1/2
P SWA-L04-1315-M04-A 1 1.85E+00 U1/2
P SWA-L04-1315-M05-A 1 1.85E+00 U1/2
P SWA-L04-1315-M06-A 1 1.85E+00 U1/2
P SWA-L04-1315-M07-A 1 1.85E+00 U1/2
P SWA-L04-1315-M08-A 1 1.85E+00 U1/2
P SWA-L04-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.51E+01 3.15 3.70 11.80
6.73E+00 58.26 3.70 11.80
1.85E+00 18.20 3.70 11.80 10000 1000
1.47E+01 2.72 3.70 11.80
9.40E+00 37.63 3.70 11.80
9.14E+00 45.53 3.70 11.80
1.39E+01 7.06 3.70 11.80
1.81E+01 8.76 3.70 11.80
8.39E+00 40.74 3.70 11.80
2.40E+01 22.21 3.70 11.80
1.52E+01 1.99 3.70 11.80
1.85E+00 33.61 3.70 11.80 10000 1000
7.87E+00 42.07 3.70 11.80
1.85E+00 17.76 3.70 11.80
1.85E+00 8.40 3.70 11.80
7.74E+00 26.76 3.70 11.80
1.85E+00 31.20 3.70 11.80
7.91E+00 30.42 3.70 11.80
2.32E+01 17.93 3.70 11.80
2.63E+01 6.70 3.70 11.80
1.85E+00 5.37 3.70 11.80 10000 1000
9.60E+00 5.64 3.70 11.80
1.85E+00 8.59 3.70 11.80
7.51 E+00 4.90 3.70 11.80
6.13E+00 4.17 3.70 11.80
1.32E+01 4.92 3.70 11.80
1.01E+01 9.82 3.70 11.80
1.85E+00 8.60 3.70 11.80
1.85E+00 21.13 3.70 11.80
1.85E+00 25.64 3.70 11.80
1.85E+00 7.06 3.70 11.80
1.85E+00 14.36 3.70 11.80
1.85E+00 5.02 3.70 11.80
1.85E+00 3.78 3.70 11.80
1.85E+00 14.71 3.70 11.80
1.85E+00 1.65 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.95E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.02E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.04E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 1315 SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 131 5 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-515
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
K SWA-L04-1315-T01-A 1 4.77E+03
K SWA-L04-1315-T02-A 1 2.43E+04
K SWA-L04-1315-T03-A 1 1.37E+04
K SWA-L04-1315-T04-A 1 4.07E+04
K SWA-L04-1315-T05-A 1 3.55E+04
K SWA-L04-1315-T06-A 1 4.56E+04
K SWA-L04-1315-T07-A 1 2.91E+04
K SWA-L04-1315-T08-A 1 9.62E+03
K SWA-L04-1315-T09-A 1 2.69E+04
K SWA-L04-1315-T01-B 1 7.13E+03
K SWA-L04-1315-T02-B 1 2.46E+04
K SWA-L04-1315-T03-B 1 1.39E+04
K SWA-L04-1315-T04-B 1 4.30E+04
K SWA-L04-1315-T05-B 1 3.75E+04
K SWA-L04-1315-T06-B 1 4.48E+04
K SWA-L04-1315-T07-B 1 2.91E+04
K SWA-L04-1315-T08-B 1 9.76E+03
K SWA-L04-1315-T09-B 1 2.69E+04
K SWA-L04-1315-T01-C 1 7.65E+03
K SWA-L04-1315-T02-C 1 2.34E+04
K SWA-L04-1315-T03-C 1 1.28E+04
K SWA-L04-1315-T04-C 1 3.68E+04
K SWA-L04-1315-T05-C 1 3.35E+04
K SWA-L04-1315-T06-C 1 4.20E+04
K SWA-L04-1315-T07-C 1 2.69E+04
K SWA-L04-1315-T08-C 1 8.99E+03
K SWA-L04-1315-T09-C 1 2.55E+04
K SWA-L04-1315-M01-A 1 1.55E+01
K SWA-L04-1315-M02-A 1 4.33E+00 E
K SWA-L04-1315-M03-A 1 5.56E+00
K SWA-L04-1315-M04-A 1 8.45E+00
K SWA-L04-1315-M05-A 1 5.04E+00 E
K SWA-L04-1315-M06-A 1 7.68E+00
K SWA-L04-1315-M07-A 1 3.44E+00 E
K SWA-L04-1315-M08-A 1 1.13E+01
K SWA-L04-1315-M09-A 1 8.27E+00
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.77E+03 0.38 1.60 5.09
2.43E+04 3.51 1.60 5.09
1.37E+04 0.58 1.60 5.09 10000 1000
4.07E+04 0.19 1.60 5.09
3.55E+04 0.79 1.60 5.09
4.56E+04 0.51 1.60 5.09
2.91E+04 0.38 1.60 5.09
9.62E+03 2.44 1.60 5.09
2.69E+04 0.21 1.60 5.09
7.13E+03 0.53 1.60 5.09
2.46E+04 1.82 1.60 5.09
1.39E+04 1.90 1.60 5.09 10000 1000
4.30E+04 1.00 1.60 5.09
3.75E+04 0.94 1.60 5.09
4.48E+04 1.17 1.60 5.09
2.91E+04 1.31 1.60 5.09
9.76E+03 0.68 1.60 5.09
2.69E+04 1.25 1.60 5.09
7.65E+03 2.96 1.60 5.09
2.34E+04 3.52 1.60 5.09
1.28E+04 1.46 1.60 5.09 10000 1000
3.68E+04 1.72 1.60 5.09
3.35E+04 0.57 1.60 5.09
4.20E+04 0.43 1.60 5.09
2.69E+04 1.05 1.60 5.09
8.99E+03 1.17 1.60 5.09
2.55E+04 1.32 1.60 5.09
1.55E+01 4.00 1.60 5.09
4.33E+00 1.64 1.60 5.09
5.56E+00 2.18 1.60 5.09
8.45E+00 2.64 1.60 5.09
5.04E+00 6.77 1.60 5.09
7.68E+00 4.90 1.60 5.09
3.44E+00 2.95 1.60 5.09
1.13E+01 9.21 1.60 5.09
8.27E+00 11.45 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.46E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.48E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.37E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 131 5 SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-516
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Se SWA-L04-1315-T01-A 1 6.79E+02
Se SWA-L04-1315-T02-A 1 3.07E+03
Se SWA-L04-1315-T03-A 1 1.86E+03
Se SWA-L04-1315-T04-A 1 5.83E+03
Se SWA-L04-1315-T05-A 1 4.87E+03
Se SWA-L04-1315-T06-A 1 6.12E+03
Se SWA-L04-1315-T07-A 1 3.43E+03
Se SWA-L04-1315-T08-A 1 9.20E+02
Se SWA-L04-1315-T09-A 1 3.16E+03
Se SWA-L04-1315-T01-B 1 1.04E+03
Se SWA-L04-1315-T02-B 1 2.81E+03
Se SWA-L04-1315-T03-B 1 1.74E+03
Se SWA-L04-1315-T04-B 1 5.73E+03
Se SWA-L04-1315-T05-B 1 4.52E+03
Se SWA-L04-1315-T06-B 1 5.08E+03
Se SWA-L04-1315-T07-B 1 2.91E+03
Se SWA-L04-1315-T08-B 1 7.96E+02
Se SWA-L04-1315-T09-B 1 2.69E+03
Se SWA-L04-1315-T01-C 1 1.06E+03
Se SWA-L04-1315-T02-C 1 2.55E+03
Se SWA-L04-1315-T03-C 1 1.44E+03
Se SWA-L04-1315-T04-C 1 4.20E+03
Se SWA-L04-1315-T05-C 1 3.66E+03
Se SWA-L04-1315-T06-C 1 4.45E+03
Se SWA-L04-1315-T07-C 1 2.55E+03
Se SWA-L04-1315-T08-C 1 7.33E+02
Se SWA-L04-1315-T09-C 1 2.47E+03
Se SWA-L04-1315-M01-A 1 7.50E+00 U1/2
Se SWA-L04-1315-M02-A 1 7.50E+00 U1/2
Se SWA-L04-1315-M03-A 1 7.50E+00 U1/2
Se SWA-L04-1315-M04-A 1 7.50E+00 U1/2
Se SWA-L04-1315-M05-A 1 7.50E+00 U1/2
Se SWA-L04-1315-M06-A 1 7.50E+00 U1/2
Se SWA-L04-1315-M07-A 1 7.50E+00 U1/2
Se SWA-L04-1315-M08-A 1 7.50E+00 U1/2
Se SWA-L04-1315-M09-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.79E+02 0.99 15.00 47.70
3.07E+03 7.81 15.00 47.70
1.86E+03 1.22 15.00 47.70 10000 1000
5.83E+03 0.31 15.00 47.70
4.87E+03 0.36 15.00 47.70
6.12E+03 1.22 15.00 47.70
3.43E+03 0.33 15.00 47.70
9.20E+02 1.79 15.00 47.70
3.16E+03 0.67 15.00 47.70
1.04E+03 0.81 15.00 47.70
2.81E+03 1.79 15.00 47.70
1.74E+03 2.46 15.00 47.70 10000 1000
5.73E+03 0.94 15.00 47.70
4.52E+03 1.56 15.00 47.70
5.08E+03 1.49 15.00 47.70
2.91E+03 0.76 15.00 47.70
7.96E+02 0.84 15.00 47.70
2.69E+03 1.81 15.00 47.70
1.06E+03 2.37 15.00 47.70
2.55E+03 1.14 15.00 47.70
1.44E+03 1.38 15.00 47.70 10000 1000
4.20E+03 1.61 15.00 47.70
3.66E+03 0.95 15.00 47.70
4.45E+03 0.88 15.00 47.70
2.55E+03 0.46 15.00 47.70
7.33E+02 1.70 15.00 47.70
2.47E+03 2.29 15.00 47.70
7.50E+00 40.03 15.00 47.70
7.50E+00 1.03 15.00 47.70
7.50E+00 36.00 15.00 47.70
7.50E+00 57.49 15.00 47.70
7.50E+00 32.58 15.00 47.70
7.50E+00 48.08 15.00 47.70
7.50E+00 23.78 15.00 47.70
7.50E+00 20.85 15.00 47.70
7.50E+00 39.10 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.76E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.69E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.37E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 131 5 SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-517
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Si SWA-L04-1315-T01-A 1 4.63E+02
Si SWA-L04-1315-T02-A 1 3.59E+03
Si SWA-L04-1315-T03-A 1 2.92E+03
Si SWA-L04-1315-T04-A 1 7.65E+03
Si SWA-L04-1315-T05-A 1 7.96E+03
Si SWA-L04-1315-T06-A 1 9.66E+03
Si SWA-L04-1315-T07-A 1 8.25E+03
Si SWA-L04-1315-T08-A 1 5.75E+03
Si SWA-L04-1315-T09-A 1 8.34E+03
Si SWA-L04-1315-T01-B 1 7.26E+02
Si SWA-L04-1315-T02-B 1 3.64E+03
Si SWA-L04-1315-T03-B 1 2.92E+03
Si SWA-L04-1315-T04-B 1 7.93E+03
Si SWA-L04-1315-T05-B 1 8.25E+03
Si SWA-L04-1315-T06-B 1 9.53E+03
Si SWA-L04-1315-T07-B 1 8.49E+03
Si SWA-L04-1315-T08-B 1 6.11E+03
Si SWA-L04-1315-T09-B 1 8.68E+03
Si SWA-L04-1315-T01-C 1 8.00E+02
Si SWA-L04-1315-T02-C 1 3.52E+03
Si SWA-L04-1315-T03-C 1 2.99E+03
Si SWA-L04-1315-T04-C 1 7.47E+03
Si SWA-L04-1315-T05-C 1 8.00E+03
Si SWA-L04-1315-T06-C 1 9.34E+03
Si SWA-L04-1315-T07-C 1 8.52E+03
Si SWA-L04-1315-T08-C 1 5.89E+03
Si SWA-L04-1315-T09-C 1 8.35E+03
Si SWA-L04-1315-M01-A 1 5.50E-01 U1/2
Si SWA-L04-1315-M02-A 1 5.50E-01 U1/2
Si SWA-L04-1315-M03-A 1 5.50E-01 U1/2
Si SWA-L04-1315-M04-A 1 5.50E-01 U1/2
Si SWA-L04-1315-M05-A 1 5.50E-01 U1/2
Si SWA-L04-1315-M06-A 1 5.50E-01 U1/2
Si SWA-L04-1315-M07-A 1 5.50E-01 U1/2
Si SWA-L04-1315-M08-A 1 5.50E-01 U1/2
Si SWA-L04-1315-M09-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.63E+02 0.32 1.10 3.50
3.59E+03 2.62 1.10 3.50
2.92E+03 0.62 1.10 3.50 10000 1000
7.65E+03 0.74 1.10 3.50
7.96E+03 0.38 1.10 3.50
9.66E+03 1.00 1.10 3.50
8.25E+03 0.84 1.10 3.50
5.75E+03 2.48 1.10 3.50
8.34E+03 0.38 1.10 3.50
7.26E+02 0.80 1.10 3.50
3.64E+03 1.32 1.10 3.50
2.92E+03 2.72 1.10 3.50 10000 1000
7.93E+03 1.07 1.10 3.50
8.25E+03 0.83 1.10 3.50
9.53E+03 0.76 1.10 3.50
8.49E+03 3.18 1.10 3.50
6.11E+03 1.00 1.10 3.50
8.68E+03 2.20 1.10 3.50
8.00E+02 2.22 1.10 3.50
3.52E+03 1.15 1.10 3.50
2.99E+03 1.84 1.10 3.50 10000 1000
7.47E+03 1.59 1.10 3.50
8.00E+03 0.74 1.10 3.50
9.34E+03 1.82 1.10 3.50
8.52E+03 0.52 1.10 3.50
5.89E+03 0.66 1.10 3.50
8.35E+03 1.59 1.10 3.50
5.50E-01 13.59 1.10 3.50
5.50E-01 1.77 1.10 3.50
5.50E-01 3.03 1.10 3.50
5.50E-01 0.51 1.10 3.50
5.50E-01 10.27 1.10 3.50
5.50E-01 5.61 1.10 3.50
5.50E-01 7.29 1.10 3.50
5.50E-01 9.77 1.10 3.50
5.50E-01 5.13 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.89E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.82E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.93E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 1315 SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-518
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Na SWA-L04-1315-T01-A 1 2.18E+04
Na SWA-L04-1315-T02-A 1 9.04E+04
Na SWA-L04-1315-T03-A 1 5.48E+04
Na SWA-L04-1315-T04-A 1 1.24E+05
Na SWA-L04-1315-T05-A 1 1.13E+05
Na SWA-L04-1315-T06-A 1 1.36E+05
Na SWA-L04-1315-T07-A 1 1.03E+05
Na SWA-L04-1315-T08-A 1 4.06E+04
Na SWA-L04-1315-T09-A 1 9.77E+04
Na SWA-L04-1315-T01-B 1 3.21E+04
Na SWA-L04-1315-T02-B 1 8.92E+04
Na SWA-L04-1315-T03-B 1 5.44E+04
Na SWA-L04-1315-T04-B 1 1.31E+05
Na SWA-L04-1315-T05-B 1 1.15E+05
Na SWA-L04-1315-T06-B 1 1.34E+05
Na SWA-L04-1315-T07-B 1 1.03E+05
Na SWA-L04-1315-T08-B 1 4.03E+04
Na SWA-L04-1315-T09-B 1 9.91E+04
Na SWA-L04-1315-T01-C 1 3.35E+04
Na SWA-L04-1315-T02-C 1 8.63E+04
Na SWA-L04-1315-T03-C 1 5.08E+04
Na SWA-L04-1315-T04-C 1 1.16E+05
Na SWA-L04-1315-T05-C 1 1.11E+05
Na SWA-L04-1315-T06-C 1 1.29E+05
Na SWA-L04-1315-T07-C 1 9.81E+04
Na SWA-L04-1315-T08-C 1 3.76E+04
Na SWA-L04-1315-T09-C 1 9.41E+04
Na SWA-L04-1315-M01-A 1 2.66E+01
Na SWA-L04-1315-M02-A 1 1.52E+01
Na SWA-L04-1315-M03-A 1 1.35E+01
Na SWA-L04-1315-M04-A 1 1.43E+01
Na SWA-L04-1315-M05-A 1 7.59E+00 E
Na SWA-L04-1315-M06-A 1 7.62E+00 E
Na SWA-L04-1315-M07-A 1 8.17E+00
Na SWA-L04-1315-M08-A 1 7.82E+00 E
Na SWA-L04-1315-M09-A 1 3.16E+00 E
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.18E+04 0.14 2.50 8.00
9.04E+04 0.78 2.50 8.00
5.48E+04 0.66 2.50 8.00 10000 1000
1.24E+05 0.52 2.50 8.00
1.13E+05 0.83 2.50 8.00
1.36E+05 0.29 2.50 8.00
1.03E+05 0.54 2.50 8.00
4.06E+04 0.91 2.50 8.00
9.77E+04 0.56 2.50 8.00
3.21 E+04 0.30 2.50 8.00
8.92E+04 0.19 2.50 8.00
5.44E+04 0.47 2.50 8.00 10000 1000
1.31E+05 0.77 2.50 8.00
1.15E+05 0.63 2.50 8.00
1.34E+05 0.30 2.50 8.00
1.03E+05 1.38 2.50 8.00
4.03E+04 0.47 2.50 8.00
9.91 E+04 0.47 2.50 8.00
3.35E+04 2.28 2.50 8.00
8.63E+04 4.77 2.50 8.00
5.08E+04 0.15 2.50 8.00 10000 1000
1.16E+05 0.42 2.50 8.00
1.11E+05 0.12 2.50 8.00
1.29E+05 0.90 2.50 8.00
9.81 E+04 0.53 2.50 8.00
3.76E+04 0.68 2.50 8.00
9.41 E+04 0.31 2.50 8.00
2.66E+01 2.61 2.50 8.00
1.52E+01 0.08 2.50 8.00
1.35E+01 3.51 2.50 8.00
1.43E+01 1.88 2.50 8.00
7.59E+00 2.55 2.50 8.00
7.62E+00 2.43 2.50 8.00
8.17E+00 1.85 2.50 8.00
7.82E+00 1.75 2.50 8.00
3.16E+00 3.29 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.57E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.53E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.17E+04 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 1315 SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-519
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Sr SWA-L04-1315-T01-A 1 7.53E+00
Sr SWA-L04-1315-T02-A 1 9.42E+01
Sr SWA-L04-1315-T03-A 1 8.71E+01
Sr SWA-L04-1315-T04-A 1 1.60E+02
Sr SWA-L04-1315-T05-A 1 1.79E+02
Sr SWA-L04-1315-T06-A 1 2.07E+02
Sr SWA-L04-1315-T07-A 1 2.09E+02
Sr SWA-L04-1315-T08-A 1 1.70E+02
Sr SWA-L04-1315-T09-A 1 2.12E+02
Sr SWA-L04-1315-T01-B 1 1.33E+01
Sr SWA-L04-1315-T02-B 1 9.92E+01
Sr SWA-L04-1315-T03-B 1 8.23E+01
Sr SWA-L04-1315-T04-B 1 1.57E+02
Sr SWA-L04-1315-T05-B 1 1.74E+02
Sr SWA-L04-1315-T06-B 1 1.96E+02
Sr SWA-L04-1315-T07-B 1 1.84E+02
Sr SWA-L04-1315-T08-B 1 1.53E+02
Sr SWA-L04-1315-T09-B 1 1.83E+02
Sr SWA-L04-1315-T01-C 1 1.16E+01
Sr SWA-L04-1315-T02-C 1 1.06E+02
Sr SWA-L04-1315-T03-C 1 9.41E+01
Sr SWA-L04-1315-T04-C 1 1.70E+02
Sr SWA-L04-1315-T05-C 1 1.90E+02
Sr SWA-L04-1315-T06-C 1 2.16E+02
Sr SWA-L04-1315-T07-C 1 1.70E+02
Sr SWA-L04-1315-T08-C 1 1.74E+02
Sr SWA-L04-1315-T09-C 1 2.24E+02
Sr SWA-L04-1315-M01-A 1 5.00E-01 U1/2
Sr SWA-L04-1315-M02-A 1 5.00E-01 U1/2
Sr SWA-L04-1315-M03-A 1 5.00E-01 U1/2
Sr SWA-L04-1315-M04-A 1 5.00E-01 U1/2
Sr SWA-L04-1315-M05-A 1 5.00E-01 U1/2
Sr SWA-L04-1315-M06-A 1 5.00E-01 U1/2
Sr SWA-L04-1315-M07-A 1 5.00E-01 U1/2
Sr SWA-L04-1315-M08-A 1 5.00E-01 U1/2
Sr SWA-L04-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.53E+00 0.89 1.00 3.18
9.42E+01 6.36 1.00 3.18
8.71E+01 0.51 1.00 3.18 10000 1000
1.60E+02 0.06 1.00 3.18
1.79E+02 0.68 1.00 3.18
2.07E+02 1.24 1.00 3.18
2.09E+02 0.99 1.00 3.18
1.70E+02 2.25 1.00 3.18
2.12E+02 0.37 1.00 3.18
1.33E+01 7.36 1.00 3.18
9.92E+01 2.17 1.00 3.18
8.23E+01 0.19 1.00 3.18 10000 1000
1.57E+02 1.16 1.00 3.18
1.74E+02 0.34 1.00 3.18
1.96E+02 1.78 1.00 3.18
1.84E+02 1.01 1.00 3.18
1.53E+02 0.79 1.00 3.18
1.83E+02 1.30 1.00 3.18
1.16E+01 2.42 1.00 3.18
1.06E+02 1.42 1.00 3.18
9.41E+01 2.40 1.00 3.18 10000 1000
1.70E+02 1.81 1.00 3.18
1.90E+02 0.26 1.00 3.18
2.16E+02 0.81 1.00 3.18
1.70E+02 0.22 1.00 3.18
1.74E+02 1.37 1.00 3.18
2.24E+02 0.38 1.00 3.18
5.00E-01 31.57 1.00 3.18
5.00E-01 2.52 1.00 3.18
5.00E-01 37.98 1.00 3.18
5.00E-01 15.63 1.00 3.18
5.00E-01 15.37 1.00 3.18
5.00E-01 16.95 1.00 3.18
5.00E-01 11.68 1.00 3.18
5.00E-01 11.57 1.00 3.18
5.00E-01 4.12 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.80E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.87E+02 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 131 5 SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-520
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
S SWA-L04-1315-T01-A 1 2.36E+03
S SWA-L04-1315-T02-A 1 8.93E+03
S SWA-L04-1315-T03-A 1 5.25E+03
S SWA-L04-1315-T04-A 1 1.56E+04
S SWA-L04-1315-T05-A 1 1.55E+04
S SWA-L04-1315-T06-A 1 2.40E+04
S SWA-L04-1315-T07-A 1 1.58E+04
S SWA-L04-1315-T08-A 1 2.67E+03
S SWA-L04-1315-T09-A 1 1.60E+04
S SWA-L04-1315-T01-B 1 3.45E+03
S SWA-L04-1315-T02-B 1 7.89E+03
S SWA-L04-1315-T03-B 1 4.61E+03
S SWA-L04-1315-T04-B 1 1.46E+04
S SWA-L04-1315-T05-B 1 1.35E+04
S SWA-L04-1315-T06-B 1 1.38E+04
S SWA-L04-1315-T07-B 1 1.06E+04
S SWA-L04-1315-T08-B 1 2.62E+03
S SWA-L04-1315-T09-B 1 1.14E+04
S SWA-L04-1315-T01-C 1 3.18E+03
S SWA-L04-1315-T02-C 1 7.13E+03
S SWA-L04-1315-T03-C 1 3.90E+03
S SWA-L04-1315-T04-C 1 1.21E+04
S SWA-L04-1315-T05-C 1 9.88E+03
S SWA-L04-1315-T06-C 1 1.50E+04
S SWA-L04-1315-T07-C 1 9.73E+03
S SWA-L04-1315-T08-C 1 2.10E+03
S SWA-L04-1315-T09-C 1 1.03E+04
S SWA-L04-1315-M01-A 1 2.63E+01
S SWA-L04-1315-M02-A 1 2.33E+01
S SWA-L04-1315-M03-A 1 1.78E+01 E
S SWA-L04-1315-M04-A 1 2.14E+01 E
S SWA-L04-1315-M05-A 1 3.05E+01
S SWA-L04-1315-M06-A 1 2.98E+01
S SWA-L04-1315-M07-A 1 3.45E+01
S SWA-L04-1315-M08-A 1 2.53E+01
S SWA-L04-1315-M09-A 1 1.61E+01 E
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.36E+03 0.61 6.80 21.60
8.93E+03 8.63 6.80 21.60
5.25E+03 0.87 6.80 21.60 10000 1000
1.56E+04 0.36 6.80 21.60
1.55E+04 0.95 6.80 21.60
2.40E+04 0.73 6.80 21.60
1.58E+04 0.89 6.80 21.60
2.67E+03 3.54 6.80 21.60
1.60E+04 0.32 6.80 21.60
3.45E+03 0.91 6.80 21.60
7.89E+03 1.13 6.80 21.60
4.61E+03 2.34 6.80 21.60 10000 1000
1.46E+04 1.09 6.80 21.60
1.35E+04 0.61 6.80 21.60
1.38E+04 1.56 6.80 21.60
1.06E+04 0.58 6.80 21.60
2.62E+03 0.22 6.80 21.60
1.14E+04 2.44 6.80 21.60
3.18E+03 2.58 6.80 21.60
7.13E+03 1.77 6.80 21.60
3.90E+03 2.39 6.80 21.60 10000 1000
1.21E+04 1.12 6.80 21.60
9.88E+03 0.78 6.80 21.60
1.50E+04 0.36 6.80 21.60
9.73E+03 0.53 6.80 21.60
2.10E+03 0.59 6.80 21.60
1.03E+04 2.26 6.80 21.60
2.63E+01 5.14 6.80 21.60
2.33E+01 2.31 6.80 21.60
1.78E+01 9.77 6.80 21.60
2.14E+01 4.63 6.80 21.60
3.05E+01 8.52 6.80 21.60
2.98E+01 3.42 6.80 21.60
3.45E+01 6.67 6.80 21.60
2.53E+01 6.44 6.80 21.60
1.61E+01 1.00 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.15E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.55E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.77E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 131 5 SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-521
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Tl SWA-L04-1315-T01-A 1 2.30E+00 U1/2
Tl SWA-L04-1315-T02-A 1 2.30E+00 U1/2
Tl SWA-L04-1315-T03-A 1 2.30E+00 U1/2
Tl SWA-L04-1315-T04-A 1 2.30E+00 U1/2
Tl SWA-L04-1315-T05-A 1 2.30E+00 U1/2
Tl SWA-L04-1315-T06-A 1 2.30E+00 U1/2
Tl SWA-L04-1315-T07-A 1 2.30E+00 U1/2
Tl SWA-L04-1315-T08-A 1 2.30E+00 U1/2
Tl SWA-L04-1315-T09-A 1 2.30E+00 U1/2
Tl SWA-L04-1315-T01-B 1 2.30E+00 U1/2
Tl SWA-L04-1315-T02-B 1 2.30E+00 U1/2
Tl SWA-L04-1315-T03-B 1 2.30E+00 U1/2
Tl SWA-L04-1315-T04-B 1 2.30E+00 U1/2
Tl SWA-L04-1315-T05-B 1 2.30E+00 U1/2
Tl SWA-L04-1315-T06-B 1 2.30E+00 U1/2
Tl SWA-L04-1315-T07-B 1 2.30E+00 U1/2
Tl SWA-L04-1315-T08-B 1 2.30E+00 U1/2
Tl SWA-L04-1315-T09-B 1 2.30E+00 U1/2
Tl SWA-L04-1315-T01-C 1 2.30E+00 U1/2
Tl SWA-L04-1315-T02-C 1 2.30E+00 U1/2
Tl SWA-L04-1315-T03-C 1 2.30E+00 U1/2
Tl SWA-L04-1315-T04-C 1 2.30E+00 U1/2
Tl SWA-L04-1315-T05-C 1 2.30E+00 U1/2
Tl SWA-L04-1315-T06-C 1 2.30E+00 U1/2
Tl SWA-L04-1315-T07-C 1 2.30E+00 U1/2
Tl SWA-L04-1315-T08-C 1 2.30E+00 U1/2
Tl SWA-L04-1315-T09-C 1 2.30E+00 U1/2
Tl SWA-L04-1315-M01-A 1 2.30E+00 U1/2
Tl SWA-L04-1315-M02-A 1 2.30E+00 U1/2
Tl SWA-L04-1315-M03-A 1 2.30E+00 U1/2
Tl SWA-L04-1315-M04-A 1 2.30E+00 U1/2
Tl SWA-L04-1315-M05-A 1 2.30E+00 U1/2
Tl SWA-L04-1315-M06-A 1 2.30E+00 U1/2
Tl SWA-L04-1315-M07-A 1 2.30E+00 U1/2
Tl SWA-L04-1315-M08-A 1 2.30E+00 U1/2
Tl SWA-L04-1315-M09-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 38.45 4.60 14.60
2.30E+00 40.30 4.60 14.60
2.30E+00 22.73 4.60 14.60 10000 1000
2.30E+00 58.28 4.60 14.60
2.30E+00 42.60 4.60 14.60
2.30E+00 5.45 4.60 14.60
2.30E+00 26.75 4.60 14.60
2.30E+00 26.75 4.60 14.60
2.30E+00 34.01 4.60 14.60
2.30E+00 23.88 4.60 14.60
2.30E+00 44.33 4.60 14.60
2.30E+00 57.98 4.60 14.60 10000 1000
2.30E+00 59.39 4.60 14.60
2.30E+00 14.41 4.60 14.60
2.30E+00 25.08 4.60 14.60
2.30E+00 23.89 4.60 14.60
2.30E+00 52.27 4.60 14.60
2.30E+00 15.36 4.60 14.60
2.30E+00 56.07 4.60 14.60
2.30E+00 30.96 4.60 14.60
2.30E+00 75.22 4.60 14.60 10000 1000
2.30E+00 18.54 4.60 14.60
2.30E+00 34.52 4.60 14.60
2.30E+00 47.49 4.60 14.60
2.30E+00 53.30 4.60 14.60
2.30E+00 36.10 4.60 14.60
2.30E+00 9.64 4.60 14.60
2.30E+00 27.68 4.60 14.60
2.30E+00 41.04 4.60 14.60
2.30E+00 75.00 4.60 14.60
2.30E+00 41.93 4.60 14.60
2.30E+00 28.54 4.60 14.60
2.30E+00 11.47 4.60 14.60
2.30E+00 54.34 4.60 14.60
2.30E+00 30.69 4.60 14.60
2.30E+00 11.13 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.91 E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.77E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.71 E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 1315 SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-522
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Ti SWA-L04-1315-T01-A 1 1.00E+00 U1/2
Ti SWA-L04-1315-T02-A 1 1.00E+00 U1/2
Ti SWA-L04-1315-T03-A 1 1.00E+00 U1/2
Ti SWA-L04-1315-T04-A 1 1.00E+00 U1/2
Ti SWA-L04-1315-T05-A 1 1.00E+00 U1/2
Ti SWA-L04-1315-T06-A 1 1.00E+00 U1/2
Ti SWA-L04-1315-T07-A 1 1.00E+00 U1/2
Ti SWA-L04-1315-T08-A 1 1.00E+00 U1/2
Ti SWA-L04-1315-T09-A 1 1.00E+00 U1/2
Ti SWA-L04-1315-T01-B 1 1.00E+00 U1/2
Ti SWA-L04-1315-T02-B 1 1.00E+00 U1/2
Ti SWA-L04-1315-T03-B 1 1.00E+00 U1/2
Ti SWA-L04-1315-T04-B 1 1.00E+00 U1/2
Ti SWA-L04-1315-T05-B 1 1.00E+00 U1/2
Ti SWA-L04-1315-T06-B 1 1.00E+00 U1/2
Ti SWA-L04-1315-T07-B 1 1.00E+00 U1/2
Ti SWA-L04-1315-T08-B 1 1.00E+00 U1/2
Ti SWA-L04-1315-T09-B 1 1.00E+00 U1/2
Ti SWA-L04-1315-T01-C 1 1.00E+00 U1/2
Ti SWA-L04-1315-T02-C 1 1.00E+00 U1/2
Ti SWA-L04-1315-T03-C 1 1.00E+00 U1/2
Ti SWA-L04-1315-T04-C 1 1.00E+00 U1/2
Ti SWA-L04-1315-T05-C 1 1.00E+00 U1/2
Ti SWA-L04-1315-T06-C 1 1.00E+00 U1/2
Ti SWA-L04-1315-T07-C 1 1.00E+00 U1/2
Ti SWA-L04-1315-T08-C 1 1.00E+00 U1/2
Ti SWA-L04-1315-T09-C 1 1.00E+00 U1/2
Ti SWA-L04-1315-M01-A 1 1.00E+00 U1/2
Ti SWA-L04-1315-M02-A 1 1.00E+00 U1/2
Ti SWA-L04-1315-M03-A 1 1.00E+00 U1/2
Ti SWA-L04-1315-M04-A 1 1.00E+00 U1/2
Ti SWA-L04-1315-M05-A 1 1.00E+00 U1/2
Ti SWA-L04-1315-M06-A 1 1.00E+00 U1/2
Ti SWA-L04-1315-M07-A 1 1.00E+00 U1/2
Ti SWA-L04-1315-M08-A 1 1.00E+00 U1/2
Ti SWA-L04-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 45.95 2.00 6.40
1.00E+00 16.31 2.00 6.40
1.00E+00 55.39 2.00 6.40 10000 1000
1.00E+00 25.74 2.00 6.40
1.00E+00 59.04 2.00 6.40
1.00E+00 10.25 2.00 6.40
1.00E+00 17.36 2.00 6.40
1.00E+00 33.57 2.00 6.40
1.00E+00 33.55 2.00 6.40
1.00E+00 19.91 2.00 6.40
1.00E+00 9.17 2.00 6.40
1.00E+00 12.59 2.00 6.40 10000 1000
1.00E+00 37.69 2.00 6.40
1.00E+00 40.76 2.00 6.40
1.00E+00 42.53 2.00 6.40
1.00E+00 60.15 2.00 6.40
1.00E+00 19.05 2.00 6.40
1.00E+00 37.90 2.00 6.40
1.00E+00 18.92 2.00 6.40
1.00E+00 29.60 2.00 6.40
1.00E+00 0.77 2.00 6.40 10000 1000
1.00E+00 39.62 2.00 6.40
1.00E+00 32.94 2.00 6.40
1.00E+00 14.70 2.00 6.40
1.00E+00 53.39 2.00 6.40
1.00E+00 45.33 2.00 6.40
1.00E+00 50.17 2.00 6.40
1.00E+00 29.18 2.00 6.40
1.00E+00 39.88 2.00 6.40
1.00E+00 10.67 2.00 6.40
1.00E+00 6.25 2.00 6.40
1.00E+00 23.75 2.00 6.40
1.00E+00 43.04 2.00 6.40
1.00E+00 29.77 2.00 6.40
1.00E+00 15.01 2.00 6.40
1.00E+00 9.40 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.79E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.31 E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.79E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 1315 SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-523
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualil
1 1 ug/L
V SWA-L04-1315-T01-A 1 5.26E+00
V SWA-L04-1315-T02-A 1 2.02E+01
V SWA-L04-1315-T03-A 1 1.11E+01
V SWA-L04-1315-T04-A 1 2.32E+01
V SWA-L04-1315-T05-A 1 1.93E+01
V SWA-L04-1315-T06-A 1 2.39E+01
V SWA-L04-1315-T07-A 1 1.67E+01
V SWA-L04-1315-T08-A 1 8.31 E+00
V SWA-L04-1315-T09-A 1 1.63E+01
V SWA-L04-1315-T01-B 1 7.68E+00
V SWA-L04-1315-T02-B 1 2.05E+01
V SWA-L04-1315-T03-B 1 1.01E+01
V SWA-L04-1315-T04-B 1 2.40E+01
V SWA-L04-1315-T05-B 1 1.95E+01
V SWA-L04-1315-T06-B 1 2.17E+01
V SWA-L04-1315-T07-B 1 1.59E+01
V SWA-L04-1315-T08-B 1 8.92E+00
V SWA-L04-1315-T09-B 1 1.61E+01
V SWA-L04-1315-T01-C 1 7.37E+00
V SWA-L04-1315-T02-C 1 1.81E+01
V SWA-L04-1315-T03-C 1 8.89E+00
V SWA-L04-1315-T04-C 1 1.96E+01
V SWA-L04-1315-T05-C 1 1.78E+01
V SWA-L04-1315-T06-C 1 2.09E+01
V SWA-L04-1315-T07-C 1 1.69E+01
V SWA-L04-1315-T08-C 1 8.13E+00
V SWA-L04-1315-T09-C 1 1.56E+01
V SWA-L04-1315-M01-A 1 7.50E-01 U1/2
V SWA-L04-1315-M02-A 1 7.50E-01 U1/2
V SWA-L04-1315-M03-A 1 7.50E-01 U1/2
V SWA-L04-1315-M04-A 1 7.50E-01 U1/2
V SWA-L04-1315-M05-A 1 7.50E-01 U1/2
V SWA-L04-1315-M06-A 1 7.50E-01 U1/2
V SWA-L04-1315-M07-A 1 7.50E-01 U1/2
V SWA-L04-1315-M08-A 1 7.50E-01 U1/2
V SWA-L04-1315-M09-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
ier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.26E+00 5.66 1.50 4.77
2.02E+01 5.84 1.50 4.77
1.11E+01 7.85 1.50 4.77 10000 1000
2.32E+01 1.44 1.50 4.77
1.93E+01 2.23 1.50 4.77
2.39E+01 4.42 1.50 4.77
1.67E+01 4.94 1.50 4.77
8.31E+00 3.70 1.50 4.77
1.63E+01 9.05 1.50 4.77
7.68E+00 5.39 1.50 4.77
2.05E+01 5.45 1.50 4.77
1.01E+01 5.09 1.50 4.77 10000 1000
2.40E+01 1.51 1.50 4.77
1.95E+01 4.12 1.50 4.77
2.17E+01 2.27 1.50 4.77
1.59E+01 0.98 1.50 4.77
8.92E+00 3.67 1.50 4.77
1.61E+01 2.88 1.50 4.77
7.37E+00 2.88 1.50 4.77
1.81E+01 2.02 1.50 4.77
8.89E+00 3.68 1.50 4.77 10000 1000
1.96E+01 5.17 1.50 4.77
1.78E+01 6.97 1.50 4.77
2.09E+01 5.51 1.50 4.77
1.69E+01 1.19 1.50 4.77
8.13E+00 6.92 1.50 4.77
1.56E+01 5.08 1.50 4.77
7.50E-01 30.19 1.50 4.77
7.50E-01 3.62 1.50 4.77
7.50E-01 22.90 1.50 4.77
7.50E-01 21.16 1.50 4.77
7.50E-01 38.98 1.50 4.77
7.50E-01 28.48 1.50 4.77
7.50E-01 30.27 1.50 4.77
7.50E-01 44.36 1.50 4.77
7.50E-01 27.63 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.90E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.90E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.83E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 131 5 SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-524
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Zn SWA-L04-1315-T01-A 1 5.00E-01 U1/2
Zn SWA-L04-1315-T02-A 1 5.00E-01 U1/2
Zn SWA-L04-1315-T03-A 1 5.00E-01 U1/2
Zn SWA-L04-1315-T04-A 1 5.00E-01 U1/2
Zn SWA-L04-1315-T05-A 1 5.00E-01 U1/2
Zn SWA-L04-1315-T06-A 1 5.00E-01 U1/2
Zn SWA-L04-1315-T07-A 1 5.00E-01 U1/2
Zn SWA-L04-1315-T08-A 1 5.00E-01 U1/2
Zn SWA-L04-1315-T09-A 1 5.00E-01 U1/2
Zn SWA-L04-1315-T01-B 1 5.00E-01 U1/2
Zn SWA-L04-1315-T02-B 1 5.00E-01 U1/2
Zn SWA-L04-1315-T03-B 1 5.00E-01 U1/2
Zn SWA-L04-1315-T04-B 1 5.00E-01 U1/2
Zn SWA-L04-1315-T05-B 1 5.00E-01 U1/2
Zn SWA-L04-1315-T06-B 1 5.00E-01 U1/2
Zn SWA-L04-1315-T07-B 1 5.00E-01 U1/2
Zn SWA-L04-1315-T08-B 1 5.00E-01 U1/2
Zn SWA-L04-1315-T09-B 1 5.00E-01 U1/2
Zn SWA-L04-1315-T01-C 1 5.00E-01 U1/2
Zn SWA-L04-1315-T02-C 1 5.00E-01 U1/2
Zn SWA-L04-1315-T03-C 1 5.00E-01 U1/2
Zn SWA-L04-1315-T04-C 1 5.00E-01 U1/2
Zn SWA-L04-1315-T05-C 1 5.00E-01 U1/2
Zn SWA-L04-1315-T06-C 1 5.00E-01 U1/2
Zn SWA-L04-1315-T07-C 1 5.00E-01 U1/2
Zn SWA-L04-1315-T08-C 1 5.00E-01 U1/2
Zn SWA-L04-1315-T09-C 1 5.00E-01 U1/2
Zn SWA-L04-1315-M01-A 1 5.00E-01 U1/2
Zn SWA-L04-1315-M02-A 1 5.00E-01 U1/2
Zn SWA-L04-1315-M03-A 1 5.00E-01 U1/2
Zn SWA-L04-1315-M04-A 1 5.00E-01 U1/2
Zn SWA-L04-1315-M05-A 1 5.00E-01 U1/2
Zn SWA-L04-1315-M06-A 1 5.00E-01 U1/2
Zn SWA-L04-1315-M07-A 1 5.00E-01 U1/2
Zn SWA-L04-1315-M08-A 1 5.00E-01 U1/2
Zn SWA-L04-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E-01 3.07 1.00 3.18
5.00E-01 3.03 1.00 3.18
5.00E-01 6.40 1.00 3.18 10000 1000
5.00E-01 9.54 1.00 3.18
5.00E-01 7.26 1.00 3.18
5.00E-01 9.78 1.00 3.18
5.00E-01 5.73 1.00 3.18
5.00E-01 4.72 1.00 3.18
5.00E-01 1.66 1.00 3.18
5.00E-01 1.12 1.00 3.18
5.00E-01 5.34 1.00 3.18
5.00E-01 7.81 1.00 3.18 10000 1000
5.00E-01 8.65 1.00 3.18
5.00E-01 5.30 1.00 3.18
5.00E-01 1.01 1.00 3.18
5.00E-01 16.03 1.00 3.18
5.00E-01 1.28 1.00 3.18
5.00E-01 1.61 1.00 3.18
5.00E-01 1.95 1.00 3.18
5.00E-01 9.19 1.00 3.18
5.00E-01 8.43 1.00 3.18 10000 1000
5.00E-01 7.51 1.00 3.18
5.00E-01 4.45 1.00 3.18
5.00E-01 1.49 1.00 3.18
5.00E-01 1.78 1.00 3.18
5.00E-01 1.75 1.00 3.18
5.00E-01 2.37 1.00 3.18
5.00E-01 8.82 1.00 3.18
5.00E-01 1.25 1.00 3.18
5.00E-01 11.21 1.00 3.18
5.00E-01 8.83 1.00 3.18
5.00E-01 1.10 1.00 3.18
5.00E-01 8.06 1.00 3.18
5.00E-01 1.42 1.00 3.18
5.00E-01 2.72 1.00 3.18
5.00E-01 8.40 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.06E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.26E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.00E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 2:25 PM EPA Interlab L04 1315 SWA
10/10/11 2:30 PM EPA Interlab L04 1315 SWA
10/10/11 2:35 PM EPA Interlab L04 1315 SWA
10/10/11 2:46 PM EPA Interlab L04 1315 SWA
10/10/11 2:51 PM EPA Interlab L04 1315 SWA
10/10/11 2:56 PM EPA Interlab L04 1315 SWA
10/10/11 3:01 PM EPA Interlab L04 1315 SWA
10/10/11 3:06 PM EPA Interlab L04 1315 SWA
10/10/11 3:11 PM EPA Interlab L04 1315 SWA
10/10/11 2:27 PM EPA Interlab L04 1315 SWA
10/10/11 2:32 PM EPA Interlab L04 1315 SWA
10/10/11 2:37 PM EPA Interlab L04 1315 SWA
10/10/11 2:48 PM EPA Interlab L04 1315 SWA
10/10/11 2:53 PM EPA Interlab L04 1315 SWA
10/10/11 2:58 PM EPA Interlab L04 1315 SWA
10/10/11 3:03 PM EPA Interlab L04 1315 SWA
10/10/11 3:08 PM EPA Interlab L04 1315 SWA
10/10/11 3:13 PM EPA Interlab L04 1315 SWA
10/10/11 2:28 PM EPA Interlab L04 1315 SWA
10/10/11 2:33 PM EPA Interlab L04 1315 SWA
10/10/11 2:38 PM EPA Interlab L04 1315 SWA
10/10/11 2:50 PM EPA Interlab L04 1315 SWA
10/10/11 2:55 PM EPA Interlab L04 1315 SWA
10/10/11 3:00 PM EPA Interlab L04 1315 SWA
10/10/11 3:05 PM EPA Interlab L04 1315 SWA
10/10/11 3:10 PM EPA Interlab L04 1315 SWA
10/10/11 3:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:10 PM EPA Interlab L04 1315 SWA
10/10/11 2:12 PM EPA Interlab L04 1315 SWA
10/10/11 2:14 PM EPA Interlab L04 1315 SWA
10/10/11 2:15 PM EPA Interlab L04 1315 SWA
10/10/11 2:17 PM EPA Interlab L04 1315 SWA
10/10/11 2:19 PM EPA Interlab L04 1315 SWA
10/10/11 2:20 PM EPA Interlab L04 1315 SWA
10/10/11 2:22 PM EPA Interlab L04 1315 SWA
10/10/11 2:23 PM EPA Interlab L04 1315 SWA
1-525
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1315:
Element Sample ID
Al SWA-L05-1315-T01-A
Al SWA-L05-1315-T02-A
Al SWA-L05-1315-T03-A
Al SWA-L05-1315-T04-A
Al SWA-L05-1315-T05-A
Al SWA-L05-1315-T06-A
Al SWA-L05-1315-T07-A
Al SWA-L05-1315-T08-A
Al SWA-L05-1315-T09-A
Al SWA-L05-1315-T01-B
Al SWA-L05-1315-T02-B
Al SWA-L05-1315-T03-B
Al SWA-L05-1315-T04-B
Al SWA-L05-1315-T05-B
Al SWA-L05-1315-T06-B
Al SWA-L05-1315-T07-B
Al SWA-L05-1315-T08-B
Al SWA-L05-1315-T09-B
Al SWA-L05-1315-T01-C
Al SWA-L05-1315-T02-C
Al SWA-L05-1315-T03-C
Al SWA-L05-1315-T04-C
Al SWA-L05-1315-T05-C
Al SWA-L05-1315-T06-C
Al SWA-L05-1315-T07-C
Al SWA-L05-1315-T08-C
Al SWA-L05-1315-T09-C
Al SWA-L05-1315-M01-A
Al SWA-L05-1315-M02-A
Al SWA-L05-1315-M03-A
Al SWA-L05-1315-M04-A
Al SWA-L05-1315-M05-A
Al SWA-L05-1315-M06-A
Al SWA-L05-1315-M07-A
Al SWA-L05-1315-M08-A
Al SWA-L05-1315-M09-A
Dilution Sample
Factor Cone. Qualifier
I ug/L I
1 1.78E+03
1 4.10E+03
1 3.26E+03
1 5.38E+03
1 4.78E+03
1 5.08E+03
1 4.70E+03
1 3.38E+03
1 3.56E+03
1 1.66E+03
1 4.64E+03
1 3.20E+03
1 5.47E+03
1 4.09E+03
1 5.21 E+03
1 4.83E+03
1 3.40E+03
1 3.53E+03
1 1.41 E+03
1 4.38E+03
1 3.90E+03
1 5.12E+03
1 4.01 E+03
1 5.23E+03
1 4.90E+03
1 3.02E+03
1 3.73E+03
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.78E+03 0.52 1.00 3.18
4.10E+03 1.90 1.00 3.18
3.26E+03 1.57 1.00 3.18 10000 1000
5.38E+03 1.34 1.00 3.18
4.78E+03 0.83 1.00 3.18
5.08E+03 0.96 1.00 3.18
4.70E+03 1.18 1.00 3.18
3.38E+03 1.63 1.00 3.18
3.56E+03 1.62 1.00 3.18
1.66E+03 0.25 1.00 3.18
4.64E+03 0.44 1.00 3.18
3.20E+03 1.05 1.00 3.18 10000 1000
5.47E+03 1.52 1.00 3.18
4.09E+03 1.12 1.00 3.18
5.21E+03 1.19 1.00 3.18
4.83E+03 0.88 1.00 3.18
3.40E+03 1.25 1.00 3.18
3.53E+03 1.03 1.00 3.18
1.41E+03 0.93 1.00 3.18
4.38E+03 0.73 1.00 3.18
3.90E+03 1.10 1.00 3.18 10000 1000
5.12E+03 1.47 1.00 3.18
4.01E+03 1.24 1.00 3.18
5.23E+03 1.46 1.00 3.18
4.90E+03 1.61 1.00 3.18
3.02E+03 1.30 1.00 3.18
3.73E+03 2.57 1.00 3.18
5.00E-01 43.37 1.00 3.18
5.00E-01 17.59 1.00 3.18
5.00E-01 30.21 1.00 3.18
5.00E-01 10.45 1.00 3.18
5.00E-01 22.35 1.00 3.18
5.00E-01 38.61 1.00 3.18
5.00E-01 14.45 1.00 3.18
5.00E-01 12.00 1.00 3.18
5.00E-01 15.60 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.20E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.09E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.83E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab LOS 1315 SWA
11/16/11 3:21 PM EPA Interlab LOS 1315 SWA
11/16/11 3:22 PM EPA Interlab L05 1315SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab LOS 1315SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 1315SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab LOS 1315SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab 105 1315SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab LOS 1315SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab LOS 1315SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab 105 1315SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-526
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Sb SWA-L05-1315-T01-A 1 2.02E+02
Sb SWA-L05-1315-T02-A 1 3.70E+02
Sb SWA-L05-1315-T03-A 1 2.49E+02
Sb SWA-L05-1315-T04-A 1 3.68E+02
Sb SWA-L05-1315-T05-A 1 3.08E+02
Sb SWA-L05-1315-T06-A 1 3.82E+02
Sb SWA-L05-1315-T07-A 1 2.90E+02
Sb SWA-L05-1315-T08-A 1 2.06E+02
Sb SWA-L05-1315-T09-A 1 2.42E+02
Sb SWA-L05-1315-T01-B 1 2.04E+02
Sb SWA-L05-1315-T02-B 1 4.37E+02
Sb SWA-L05-1315-T03-B 1 2.24E+02
Sb SWA-L05-1315-T04-B 1 3.92E+02
Sb SWA-L05-1315-T05-B 1 3.09E+02
Sb SWA-L05-1315-T06-B 1 3.86E+02
Sb SWA-L05-1315-T07-B 1 3.06E+02
Sb SWA-L05-1315-T08-B 1 2.04E+02
Sb SWA-L05-1315-T09-B 1 2.39E+02
Sb SWA-L05-1315-T01-C 1 2.44E+02
Sb SWA-L05-1315-T02-C 1 3.73E+02
Sb SWA-L05-1315-T03-C 1 2.37E+02
Sb SWA-L05-1315-T04-C 1 3.78E+02
Sb SWA-L05-1315-T05-C 1 3.09E+02
Sb SWA-L05-1315-T06-C 1 3.89E+02
Sb SWA-L05-1315-T07-C 1 3.08E+02
Sb SWA-L05-1315-T08-C 1 2.06E+02
Sb SWA-L05-1315-T09-C 1 2.39E+02
Sb SWA-L05-1315-M01-A 1 3.75E+00 U1/2
Sb SWA-L05-1315-M02-A 1 3.75E+00 U1/2
Sb SWA-L05-1315-M03-A 1 3.75E+00 U1/2
Sb SWA-L05-1315-M04-A 1 3.75E+00 U1/2
Sb SWA-L05-1315-M05-A 1 3.75E+00 U1/2
Sb SWA-L05-1315-M06-A 1 3.75E+00 U1/2
Sb SWA-L05-1315-M07-A 1 3.75E+00 U1/2
Sb SWA-L05-1315-M08-A 1 3.75E+00 U1/2
Sb SWA-L05-1315-M09-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.02E+02 1.65 7.50 23.90
3.70E+02 3.62 7.50 23.90
2.49E+02 2.40 7.50 23.90 10000 1000
3.68E+02 1.19 7.50 23.90
3.08E+02 3.20 7.50 23.90
3.82E+02 0.32 7.50 23.90
2.90E+02 3.42 7.50 23.90
2.06E+02 1.82 7.50 23.90
2.42E+02 2.88 7.50 23.90
2.04E+02 2.77 7.50 23.90
4.37E+02 1.46 7.50 23.90
2.24E+02 2.56 7.50 23.90 10000 1000
3.92E+02 2.63 7.50 23.90
3.09E+02 1.27 7.50 23.90
3.86E+02 2.18 7.50 23.90
3.06E+02 1.72 7.50 23.90
2.04E+02 2.14 7.50 23.90
2.39E+02 1.04 7.50 23.90
2.44E+02 2.07 7.50 23.90
3.73E+02 0.94 7.50 23.90
2.37E+02 2.55 7.50 23.90 10000 1000
3.78E+02 2.07 7.50 23.90
3.09E+02 1.56 7.50 23.90
3.89E+02 4.16 7.50 23.90
3.08E+02 1.00 7.50 23.90
2.06E+02 4.30 7.50 23.90
2.39E+02 4.16 7.50 23.90
3.75E+00 60.31 7.50 23.90
3.75E+00 43.28 7.50 23.90
3.75E+00 35.59 7.50 23.90
3.75E+00 35.06 7.50 23.90
3.75E+00 14.23 7.50 23.90
3.75E+00 56.67 7.50 23.90
3.75E+00 21.22 7.50 23.90
3.75E+00 66.90 7.50 23.90
3.75E+00 14.67 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.14E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.29E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.26E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab 105 1315SWA
11/16/11 3:22 PM EPA Interlab LOS 1315 SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315 SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 131 5 SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab LOS 1315 SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315 SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315 SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315 SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-527
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
As SWA-L05-1315-T01-A 1 2.27E+02
As SWA-L05-1315-T02-A 1 1.43E+02
As SWA-L05-1315-T03-A 1 1.08E+02
As SWA-L05-1315-T04-A 1 1.79E+02
As SWA-L05-1315-T05-A 1 1.33E+02
As SWA-L05-1315-T06-A 1 8.36E+01
As SWA-L05-1315-T07-A 1 8.77E+01
As SWA-L05-1315-T08-A 1 6.75E+01
As SWA-L05-1315-T09-A 1 1.04E+02
As SWA-L05-1315-T01-B 1 2.14E+02
As SWA-L05-1315-T02-B 1 2.12E+02
As SWA-L05-1315-T03-B 1 1.02E+02
As SWA-L05-1315-T04-B 1 1.58E+02
As SWA-L05-1315-T05-B 1 1.25E+02
As SWA-L05-1315-T06-B 1 9.00E+01
As SWA-L05-1315-T07-B 1 7.42E+01
As SWA-L05-1315-T08-B 1 8.34E+01
As SWA-L05-1315-T09-B 1 1.17E+02
As SWA-L05-1315-T01-C 1 2.48E+02
As SWA-L05-1315-T02-C 1 2.04E+02
As SWA-L05-1315-T03-C 1 1.27E+02
As SWA-L05-1315-T04-C 1 2.06E+02
As SWA-L05-1315-T05-C 1 1.51E+02
As SWA-L05-1315-T06-C 1 1.06E+02
As SWA-L05-1315-T07-C 1 9.57E+01
As SWA-L05-1315-T08-C 1 7.17E+01
As SWA-L05-1315-T09-C 1 1.20E+02
As SWA-L05-1315-M01-A 1 5.50E+00 U1/2
As SWA-L05-1315-M02-A 1 5.50E+00 U1/2
As SWA-L05-1315-M03-A 1 5.50E+00 U1/2
As SWA-L05-1315-M04-A 1 5.50E+00 U1/2
As SWA-L05-1315-M05-A 1 5.50E+00 U1/2
As SWA-L05-1315-M06-A 1 5.50E+00 U1/2
As SWA-L05-1315-M07-A 1 5.50E+00 U1/2
As SWA-L05-1315-M08-A 1 5.50E+00 U1/2
As SWA-L05-1315-M09-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.27E+02 2.15 11.00 35.00
1.43E+02 3.63 11.00 35.00
1.08E+02 1.38 11.00 35.00 10000 1000
1.79E+02 4.43 11.00 35.00
1.33E+02 6.75 11.00 35.00
8.36E+01 3.45 11.00 35.00
8.77E+01 4.52 11.00 35.00
6.75E+01 9.78 11.00 35.00
1.04E+02 4.21 11.00 35.00
2.14E+02 4.40 11.00 35.00
2.12E+02 4.38 11.00 35.00
1.02E+02 12.15 11.00 35.00 10000 1000
1.58E+02 3.35 11.00 35.00
1.25E+02 6.75 11.00 35.00
9.00E+01 8.12 11.00 35.00
7.42E+01 1.24 11.00 35.00
8.34E+01 10.91 11.00 35.00
1.17E+02 4.96 11.00 35.00
2.48E+02 2.67 11.00 35.00
2.04E+02 1.73 11.00 35.00
1.27E+02 1.97 11.00 35.00 10000 1000
2.06E+02 2.72 11.00 35.00
1.51E+02 4.87 11.00 35.00
1.06E+02 9.20 11.00 35.00
9.57E+01 6.65 11.00 35.00
7.17E+01 5.58 11.00 35.00
1.20E+02 3.62 11.00 35.00
5.50E+00 24.79 11.00 35.00
5.50E+00 26.13 11.00 35.00
5.50E+00 34.99 11.00 35.00
5.50E+00 48.38 11.00 35.00
5.50E+00 50.64 11.00 35.00
5.50E+00 36.78 11.00 35.00
5.50E+00 12.60 11.00 35.00
5.50E+00 38.03 11.00 35.00
5.50E+00 40.56 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.77E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab L05 1315SWA
11/16/11 3:19 PM EPA Interlab LOS 1315 SWA
11/16/11 3:21 PM EPA Interlab 105 1315SWA
11/16/11 3:22 PM EPA Interlab L05 1315 SWA
11/16/11 3:24 PM EPA Interlab L05 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315 SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 131 5 SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab LOS 1315 SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315 SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315 SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315 SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-528
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
B SWA-L05-1315-T01-A 1 4.06E+01
B SWA-L05-1315-T02-A 1 4.39E+01
B SWA-L05-1315-T03-A 1 2.75E+01
B SWA-L05-1315-T04-A 1 5.34E+01
B SWA-L05-1315-T05-A 1 4.81 E+01
B SWA-L05-1315-T06-A 1 5.93E+01
B SWA-L05-1315-T07-A 1 4.96E+01
B SWA-L05-1315-T08-A 1 3.37E+01
B SWA-L05-1315-T09-A 1 4.57E+01
B SWA-L05-1315-T01-B 1 4.51 E+01
B SWA-L05-1315-T02-B 1 6. 11 E+01
B SWA-L05-1315-T03-B 1 3.39E+01
B SWA-L05-1315-T04-B 1 6.47E+01
B SWA-L05-1315-T05-B 1 5.25E+01
B SWA-L05-1315-T06-B 1 6.01E+01
B SWA-L05-1315-T07-B 1 4.88E+01
B SWA-L05-1315-T08-B 1 3.23E+01
B SWA-L05-1315-T09-B 1 4.37E+01
B SWA-L05-1315-T01-C 1 4.31E+01
B SWA-L05-1315-T02-C 1 5.44E+01
B SWA-L05-1315-T03-C 1 3.53E+01
B SWA-L05-1315-T04-C 1 5.85E+01
B SWA-L05-1315-T05-C 1 5.10E+01
B SWA-L05-1315-T06-C 1 5.79E+01
B SWA-L05-1315-T07-C 1 4.76E+01
B SWA-L05-1315-T08-C 1 3.23E+01
B SWA-L05-1315-T09-C 1 4.20E+01
B SWA-L05-1315-M01-A 1 5.00E-01 U1/2
B SWA-L05-1315-M02-A 1 5.00E-01 U1/2
B SWA-L05-1315-M03-A 1 5.00E-01 U1/2
B SWA-L05-1315-M04-A 1 5.00E-01 U1/2
B SWA-L05-1315-M05-A 1 5.00E-01 U1/2
B SWA-L05-1315-M06-A 1 5.00E-01 U1/2
B SWA-L05-1315-M07-A 1 5.00E-01 U1/2
B SWA-L05-1315-M08-A 1 5.00E-01 U1/2
B SWA-L05-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.06E+01 1.83 1.00 3.18
4.39E+01 1.54 1.00 3.18
2.75E+01 3.46 1.00 3.18 10000 1000
5.34E+01 1.63 1.00 3.18
4.81E+01 0.44 1.00 3.18
5.93E+01 1.22 1.00 3.18
4.96E+01 3.40 1.00 3.18
3.37E+01 3.00 1.00 3.18
4.57E+01 1.69 1.00 3.18
4.51E+01 0.89 1.00 3.18
6.11E+01 1.65 1.00 3.18
3.39E+01 4.99 1.00 3.18 10000 1000
6.47E+01 2.46 1.00 3.18
5.25E+01 4.85 1.00 3.18
6.01E+01 3.12 1.00 3.18
4.88E+01 3.22 1.00 3.18
3.23E+01 4.35 1.00 3.18
4.37E+01 1.69 1.00 3.18
4.31E+01 2.09 1.00 3.18
5.44E+01 1.58 1.00 3.18
3.53E+01 1.89 1.00 3.18 10000 1000
5.85E+01 3.26 1.00 3.18
5.10E+01 2.37 1.00 3.18
5.79E+01 4.33 1.00 3.18
4.76E+01 2.91 1.00 3.18
3.23E+01 0.22 1.00 3.18
4.20E+01 4.81 1.00 3.18
5.00E-01 3.58 1.00 3.18
5.00E-01 3.03 1.00 3.18
5.00E-01 8.22 1.00 3.18
5.00E-01 4.81 1.00 3.18
5.00E-01 5.75 1.00 3.18
5.00E-01 13.45 1.00 3.18
5.00E-01 4.79 1.00 3.18
5.00E-01 7.07 1.00 3.18
5.00E-01 9.89 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.46E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.79E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.98E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab 105 1315SWA
11/16/11 3:22 PM EPA Interlab LOS 1315 SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315 SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 131 5 SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab LOS 1315 SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315 SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315 SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315 SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-529
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Ba SWA-L05-1315-T01-A 1 1.56E+01
Ba SWA-L05-1315-T02-A 1 9.37E+01
Ba SWA-L05-1315-T03-A 1 1.69E+02
Ba SWA-L05-1315-T04-A 1 2.96E+02
Ba SWA-L05-1315-T05-A 1 3.40E+02
Ba SWA-L05-1315-T06-A 1 2.70E+02
Ba SWA-L05-1315-T07-A 1 3.87E+02
Ba SWA-L05-1315-T08-A 1 3.45E+02
Ba SWA-L05-1315-T09-A 1 3.84E+02
Ba SWA-L05-1315-T01-B 1 1.54E+01
Ba SWA-L05-1315-T02-B 1 1.15E+02
Ba SWA-L05-1315-T03-B 1 1.22E+02
Ba SWA-L05-1315-T04-B 1 2.03E+02
Ba SWA-L05-1315-T05-B 1 2.78E+02
Ba SWA-L05-1315-T06-B 1 2.45E+02
Ba SWA-L05-1315-T07-B 1 3.05E+02
Ba SWA-L05-1315-T08-B 1 3.37E+02
Ba SWA-L05-1315-T09-B 1 3.16E+02
Ba SWA-L05-1315-T01-C 1 1.68E+01
Ba SWA-L05-1315-T02-C 1 1.58E+02
Ba SWA-L05-1315-T03-C 1 1.66E+02
Ba SWA-L05-1315-T04-C 1 2.62E+02
Ba SWA-L05-1315-T05-C 1 3.30E+02
Ba SWA-L05-1315-T06-C 1 2.63E+02
Ba SWA-L05-1315-T07-C 1 2.77E+02
Ba SWA-L05-1315-T08-C 1 3.18E+02
Ba SWA-L05-1315-T09-C 1 3.87E+02
Ba SWA-L05-1315-M01-A 1 5.00E-01 U1/2
Ba SWA-L05-1315-M02-A 1 5.00E-01 U1/2
Ba SWA-L05-1315-M03-A 1 5.00E-01 U1/2
Ba SWA-L05-1315-M04-A 1 5.00E-01 U1/2
Ba SWA-L05-1315-M05-A 1 5.00E-01 U1/2
Ba SWA-L05-1315-M06-A 1 5.00E-01 U1/2
Ba SWA-L05-1315-M07-A 1 5.00E-01 U1/2
Ba SWA-L05-1315-M08-A 1 5.00E-01 U1/2
Ba SWA-L05-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.56E+01 1.48 1.00 3.18
9.37E+01 1.29 1.00 3.18
1.69E+02 0.64 1.00 3.18 10000 1000
2.96E+02 1.80 1.00 3.18
3.40E+02 1.92 1.00 3.18
2.70E+02 1.18 1.00 3.18
3.87E+02 1.14 1.00 3.18
3.45E+02 0.71 1.00 3.18
3.84E+02 1.76 1.00 3.18
1.54E+01 1.57 1.00 3.18
1.15E+02 0.30 1.00 3.18
1.22E+02 0.67 1.00 3.18 10000 1000
2.03E+02 1.15 1.00 3.18
2.78E+02 0.95 1.00 3.18
2.45E+02 1.60 1.00 3.18
3.05E+02 1.46 1.00 3.18
3.37E+02 1.07 1.00 3.18
3.16E+02 0.88 1.00 3.18
1.68E+01 0.62 1.00 3.18
1.58E+02 1.14 1.00 3.18
1.66E+02 0.92 1.00 3.18 10000 1000
2.62E+02 1.20 1.00 3.18
3.30E+02 1.80 1.00 3.18
2.63E+02 1.22 1.00 3.18
2.77E+02 1.41 1.00 3.18
3.18E+02 1.25 1.00 3.18
3.87E+02 2.74 1.00 3.18
5.00E-01 17.91 1.00 3.18
5.00E-01 5.72 1.00 3.18
5.00E-01 27.88 1.00 3.18
5.00E-01 16.71 1.00 3.18
5.00E-01 8.09 1.00 3.18
5.00E-01 15.50 1.00 3.18
5.00E-01 16.60 1.00 3.18
5.00E-01 33.68 1.00 3.18
5.00E-01 11.25 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.80E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.91 E+02 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab 105 1315SWA
11/16/11 3:22 PM EPA Interlab LOS 1315 SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315 SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 131 5 SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab LOS 1315 SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315 SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315 SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315 SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-530
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Be SWA-L05-1315-T01-A 1 9.50E-01 U1/2
Be SWA-L05-1315-T02-A 1 9.50E-01 U1/2
Be SWA-L05-1315-T03-A 1 9.50E-01 U1/2
Be SWA-L05-1315-T04-A 1 9.50E-01 U1/2
Be SWA-L05-1315-T05-A 1 9.50E-01 U1/2
Be SWA-L05-1315-T06-A 1 9.50E-01 U1/2
Be SWA-L05-1315-T07-A 1 9.50E-01 U1/2
Be SWA-L05-1315-T08-A 1 9.50E-01 U1/2
Be SWA-L05-1315-T09-A 1 9.50E-01 U1/2
Be SWA-L05-1315-T01-B 1 9.50E-01 U1/2
Be SWA-L05-1315-T02-B 1 9.50E-01 U1/2
Be SWA-L05-1315-T03-B 1 9.50E-01 U1/2
Be SWA-L05-1315-T04-B 1 9.50E-01 U1/2
Be SWA-L05-1315-T05-B 1 9.50E-01 U1/2
Be SWA-L05-1315-T06-B 1 9.50E-01 U1/2
Be SWA-L05-1315-T07-B 1 9.50E-01 U1/2
Be SWA-L05-1315-T08-B 1 9.50E-01 U1/2
Be SWA-L05-1315-T09-B 1 9.50E-01 U1/2
Be SWA-L05-1315-T01-C 1 9.50E-01 U1/2
Be SWA-L05-1315-T02-C 1 9.50E-01 U1/2
Be SWA-L05-1315-T03-C 1 9.50E-01 U1/2
Be SWA-L05-1315-T04-C 1 9.50E-01 U1/2
Be SWA-L05-1315-T05-C 1 9.50E-01 U1/2
Be SWA-L05-1315-T06-C 1 9.50E-01 U1/2
Be SWA-L05-1315-T07-C 1 9.50E-01 U1/2
Be SWA-L05-1315-T08-C 1 9.50E-01 U1/2
Be SWA-L05-1315-T09-C 1 9.50E-01 U1/2
Be SWA-L05-1315-M01-A 1 9.50E-01 U1/2
Be SWA-L05-1315-M02-A 1 9.50E-01 U1/2
Be SWA-L05-1315-M03-A 1 9.50E-01 U1/2
Be SWA-L05-1315-M04-A 1 9.50E-01 U1/2
Be SWA-L05-1315-M05-A 1 9.50E-01 U1/2
Be SWA-L05-1315-M06-A 1 9.50E-01 U1/2
Be SWA-L05-1315-M07-A 1 9.50E-01 U1/2
Be SWA-L05-1315-M08-A 1 9.50E-01 U1/2
Be SWA-L05-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 14.60 1.90 6.00
9.50E-01 4.27 1.90 6.00
9.50E-01 52.23 1.90 6.00 10000 1000
9.50E-01 21.35 1.90 6.00
9.50E-01 4.26 1.90 6.00
9.50E-01 39.41 1.90 6.00
9.50E-01 25.49 1.90 6.00
9.50E-01 38.26 1.90 6.00
9.50E-01 47.49 1.90 6.00
9.50E-01 64.29 1.90 6.00
9.50E-01 5.91 1.90 6.00
9.50E-01 28.65 1.90 6.00 10000 1000
9.50E-01 29.70 1.90 6.00
9.50E-01 26.00 1.90 6.00
9.50E-01 38.05 1.90 6.00
9.50E-01 49.90 1.90 6.00
9.50E-01 51.04 1.90 6.00
9.50E-01 45.43 1.90 6.00
9.50E-01 23.08 1.90 6.00
9.50E-01 35.49 1.90 6.00
9.50E-01 16.78 1.90 6.00 10000 1000
9.50E-01 34.03 1.90 6.00
9.50E-01 42.32 1.90 6.00
9.50E-01 21.81 1.90 6.00
9.50E-01 10.97 1.90 6.00
9.50E-01 5.84 1.90 6.00
9.50E-01 44.12 1.90 6.00
9.50E-01 39.15 1.90 6.00
9.50E-01 32.93 1.90 6.00
9.50E-01 12.49 1.90 6.00
9.50E-01 19.08 1.90 6.00
9.50E-01 20.93 1.90 6.00
9.50E-01 23.64 1.90 6.00
9.50E-01 27.08 1.90 6.00
9.50E-01 39.28 1.90 6.00
9.50E-01 14.98 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.03E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.14E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.40E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab 105 1315SWA
11/16/11 3:22 PM EPA Interlab LOS 1315SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315 SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 1315 SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab LOS 1315 SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315 SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315 SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315 SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-531
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cd SWA-L05-1315-T01-A 1 1.10E+00 U1/2
Cd SWA-L05-1315-T02-A 1 1.10E+00 U1/2
Cd SWA-L05-1315-T03-A 1 1.10E+00 U1/2
Cd SWA-L05-1315-T04-A 1 1.10E+00 U1/2
Cd SWA-L05-1315-T05-A 1 1.10E+00 U1/2
Cd SWA-L05-1315-T06-A 1 1.10E+00 U1/2
Cd SWA-L05-1315-T07-A 1 1.10E+00 U1/2
Cd SWA-L05-1315-T08-A 1 1.10E+00 U1/2
Cd SWA-L05-1315-T09-A 1 1.10E+00 U1/2
Cd SWA-L05-1315-T01-B 1 1.10E+00 U1/2
Cd SWA-L05-1315-T02-B 1 1.10E+00 U1/2
Cd SWA-L05-1315-T03-B 1 1.10E+00 U1/2
Cd SWA-L05-1315-T04-B 1 1.10E+00 U1/2
Cd SWA-L05-1315-T05-B 1 1.10E+00 U1/2
Cd SWA-L05-1315-T06-B 1 1.10E+00 U1/2
Cd SWA-L05-1315-T07-B 1 1.10E+00 U1/2
Cd SWA-L05-1315-T08-B 1 1.10E+00 U1/2
Cd SWA-L05-1315-T09-B 1 1.10E+00 U1/2
Cd SWA-L05-1315-T01-C 1 1.10E+00 U1/2
Cd SWA-L05-1315-T02-C 1 1.10E+00 U1/2
Cd SWA-L05-1315-T03-C 1 1.10E+00 U1/2
Cd SWA-L05-1315-T04-C 1 1.10E+00 U1/2
Cd SWA-L05-1315-T05-C 1 1.10E+00 U1/2
Cd SWA-L05-1315-T06-C 1 1.10E+00 U1/2
Cd SWA-L05-1315-T07-C 1 1.10E+00 U1/2
Cd SWA-L05-1315-T08-C 1 1.10E+00 U1/2
Cd SWA-L05-1315-T09-C 1 1.10E+00 U1/2
Cd SWA-L05-1315-M01-A 1 1.10E+00 U1/2
Cd SWA-L05-1315-M02-A 1 1.10E+00 U1/2
Cd SWA-L05-1315-M03-A 1 1.10E+00 U1/2
Cd SWA-L05-1315-M04-A 1 1.10E+00 U1/2
Cd SWA-L05-1315-M05-A 1 1.10E+00 U1/2
Cd SWA-L05-1315-M06-A 1 1.10E+00 U1/2
Cd SWA-L05-1315-M07-A 1 1.10E+00 U1/2
Cd SWA-L05-1315-M08-A 1 1.10E+00 U1/2
Cd SWA-L05-1315-M09-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 33.32 2.20 7.00
1.10E+00 17.42 2.20 7.00
1.10E+00 10.55 2.20 7.00 10000 1000
1.10E+00 49.13 2.20 7.00
1.10E+00 44.05 2.20 7.00
1.10E+00 18.48 2.20 7.00
1.10E+00 29.69 2.20 7.00
1.10E+00 56.31 2.20 7.00
1.10E+00 46.56 2.20 7.00
1.10E+00 34.69 2.20 7.00
1.10E+00 25.00 2.20 7.00
1.10E+00 26.78 2.20 7.00 10000 1000
1.10E+00 63.59 2.20 7.00
1.10E+00 14.25 2.20 7.00
1.10E+00 40.78 2.20 7.00
1.10E+00 18.84 2.20 7.00
1.10E+00 44.56 2.20 7.00
1.10E+00 27.60 2.20 7.00
1.10E+00 34.69 2.20 7.00
1.10E+00 36.16 2.20 7.00
1.10E+00 21.75 2.20 7.00 10000 1000
1.10E+00 30.86 2.20 7.00
1.10E+00 46.63 2.20 7.00
1.10E+00 15.26 2.20 7.00
1.10E+00 30.37 2.20 7.00
1.10E+00 17.00 2.20 7.00
1.10E+00 12.58 2.20 7.00
1.10E+00 14.08 2.20 7.00
1.10E+00 10.65 2.20 7.00
1.10E+00 50.30 2.20 7.00
1.10E+00 39.21 2.20 7.00
1.10E+00 31.74 2.20 7.00
1.10E+00 27.67 2.20 7.00
1.10E+00 17.78 2.20 7.00
1.10E+00 35.50 2.20 7.00
1.10E+00 27.64 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.02E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.07E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.26E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab LOS 131 5 SWA
11/16/11 3:22 PM EPA Interlab LOS 1315SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 1315SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab 105 1315SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab 105 1315SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab 105 1315SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-532
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Ca SWA-L05-1315-T01-A 1 1.29E+03
Ca SWA-L05-1315-T02-A 1 1.61E+04
Ca SWA-L05-1315-T03-A 1 1.76E+04
Ca SWA-L05-1315-T04-A 1 2.02E+04
Ca SWA-L05-1315-T05-A 1 3.21E+04
Ca SWA-L05-1315-T06-A 1 3.00E+04
Ca SWA-L05-1315-T07-A 1 2.62E+04
Ca SWA-L05-1315-T08-A 1 2.50E+04
Ca SWA-L05-1315-T09-A 1 2.48E+04
Ca SWA-L05-1315-T01-B 1 1.48E+03
Ca SWA-L05-1315-T02-B 1 1.70E+04
Ca SWA-L05-1315-T03-B 1 1.73E+04
Ca SWA-L05-1315-T04-B 1 1.96E+04
Ca SWA-L05-1315-T05-B 1 3.15E+04
Ca SWA-L05-1315-T06-B 1 2.96E+04
Ca SWA-L05-1315-T07-B 1 2.54E+04
Ca SWA-L05-1315-T08-B 1 2.34E+04
Ca SWA-L05-1315-T09-B 1 2.34E+04
Ca SWA-L05-1315-T01-C 1 1.25E+03
Ca SWA-L05-1315-T02-C 1 1.72E+04
Ca SWA-L05-1315-T03-C 1 1.89E+04
Ca SWA-L05-1315-T04-C 1 2.19E+04
Ca SWA-L05-1315-T05-C 1 3.88E+04
Ca SWA-L05-1315-T06-C 1 3.17E+04
Ca SWA-L05-1315-T07-C 1 2.61E+04
Ca SWA-L05-1315-T08-C 1 2.30E+04
Ca SWA-L05-1315-T09-C 1 2.47E+04
Ca SWA-L05-1315-M01-A 1 8.34E+01
Ca SWA-L05-1315-M02-A 1 5.47E+01
Ca SWA-L05-1315-M03-A 1 1.21E+01
Ca SWA-L05-1315-M04-A 1 9.54E+01
Ca SWA-L05-1315-M05-A 1 1.23E+02
Ca SWA-L05-1315-M06-A 1 1.38E+02
Ca SWA-L05-1315-M07-A 1 1.07E+02
Ca SWA-L05-1315-M08-A 1 2.03E+01
Ca SWA-L05-1315-M09-A 1 4.65E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.29E+03 1.41 2.60 8.30
1.61E+04 2.39 2.60 8.30
1.76E+04 0.73 2.60 8.30 10000 1000
2.02E+04 1.43 2.60 8.30
3.21 E+04 1.99 2.60 8.30
3.00E+04 1.79 2.60 8.30
2.62E+04 1.51 2.60 8.30
2.50E+04 1.52 2.60 8.30
2.48E+04 1.09 2.60 8.30
1.48E+03 4.23 2.60 8.30
1.70E+04 0.48 2.60 8.30
1.73E+04 1.08 2.60 8.30 10000 1000
1.96E+04 2.17 2.60 8.30
3.15E+04 1.43 2.60 8.30
2.96E+04 1.32 2.60 8.30
2.54E+04 1.47 2.60 8.30
2.34E+04 0.89 2.60 8.30
2.34E+04 0.62 2.60 8.30
1.25E+03 1.08 2.60 8.30
1.72E+04 1.39 2.60 8.30
1.89E+04 0.94 2.60 8.30 10000 1000
2.19E+04 1.33 2.60 8.30
3.88E+04 1.97 2.60 8.30
3.17E+04 1.23 2.60 8.30
2.61 E+04 1.82 2.60 8.30
2.30E+04 1.47 2.60 8.30
2.47E+04 3.16 2.60 8.30
8.34E+01 1.21 2.60 8.30
5.47E+01 1.09 2.60 8.30
1.21E+01 2.26 2.60 8.30
9.54E+01 1.35 2.60 8.30
1.23E+02 5.09 2.60 8.30
1.38E+02 2.07 2.60 8.30
1.07E+02 2.94 2.60 8.30
2.03E+01 8.48 2.60 8.30
4.65E+01 6.36 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.85E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.81 E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.98E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab LOS 131 5 SWA
11/16/11 3:22 PM EPA Interlab LOS 1315SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 1315SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab 105 1315SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab 105 1315SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab 105 1315SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-533
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Cr SWA-L05-1315-T01-A 1 3.16E+01
Cr SWA-L05-1315-T02-A 1 4.97E+01
Cr SWA-L05-1315-T03-A 1 2.41E+01
Cr SWA-L05-1315-T04-A 1 4.29E+01
Cr SWA-L05-1315-T05-A 1 3.62E+01
Cr SWA-L05-1315-T06-A 1 3.85E+01
Cr SWA-L05-1315-T07-A 1 3.55E+01
Cr SWA-L05-1315-T08-A 1 2.48E+01
Cr SWA-L05-1315-T09-A 1 3.16E+01
Cr SWA-L05-1315-T01-B 1 2.80E+01
Cr SWA-L05-1315-T02-B 1 6.76E+01
Cr SWA-L05-1315-T03-B 1 1.98E+01
Cr SWA-L05-1315-T04-B 1 4.45E+01
Cr SWA-L05-1315-T05-B 1 3.49E+01
Cr SWA-L05-1315-T06-B 1 4.16E+01
Cr SWA-L05-1315-T07-B 1 3.66E+01
Cr SWA-L05-1315-T08-B 1 2.56E+01
Cr SWA-L05-1315-T09-B 1 3.27E+01
Cr SWA-L05-1315-T01-C 1 2.93E+01
Cr SWA-L05-1315-T02-C 1 5.90E+01
Cr SWA-L05-1315-T03-C 1 2.29E+01
Cr SWA-L05-1315-T04-C 1 3.91E+01
Cr SWA-L05-1315-T05-C 1 3.44E+01
Cr SWA-L05-1315-T06-C 1 4.13E+01
Cr SWA-L05-1315-T07-C 1 3.73E+01
Cr SWA-L05-1315-T08-C 1 2.55E+01
Cr SWA-L05-1315-T09-C 1 3.24E+01
Cr SWA-L05-1315-M01-A 1 6.00E-01 U1/2
Cr SWA-L05-1315-M02-A 1 6.00E-01 U1/2
Cr SWA-L05-1315-M03-A 1 6.00E-01 U1/2
Cr SWA-L05-1315-M04-A 1 6.00E-01 U1/2
Cr SWA-L05-1315-M05-A 1 6.00E-01 U1/2
Cr SWA-L05-1315-M06-A 1 6.00E-01 U1/2
Cr SWA-L05-1315-M07-A 1 6.00E-01 U1/2
Cr SWA-L05-1315-M08-A 1 6.00E-01 U1/2
Cr SWA-L05-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.16E+01 1.26 1.20 3.82
4.97E+01 2.54 1.20 3.82
2.41E+01 2.15 1.20 3.82 10000 1000
4.29E+01 2.54 1.20 3.82
3.62E+01 2.39 1.20 3.82
3.85E+01 1.16 1.20 3.82
3.55E+01 0.87 1.20 3.82
2.48E+01 2.10 1.20 3.82
3.16E+01 0.67 1.20 3.82
2.80E+01 0.99 1.20 3.82
6.76E+01 0.60 1.20 3.82
1.98E+01 1.99 1.20 3.82 10000 1000
4.45E+01 1.42 1.20 3.82
3.49E+01 2.15 1.20 3.82
4.16E+01 2.50 1.20 3.82
3.66E+01 1.44 1.20 3.82
2.56E+01 4.00 1.20 3.82
3.27E+01 0.76 1.20 3.82
2.93E+01 1.29 1.20 3.82
5.90E+01 0.98 1.20 3.82
2.29E+01 1.56 1.20 3.82 10000 1000
3.91E+01 0.98 1.20 3.82
3.44E+01 2.95 1.20 3.82
4.13E+01 1.20 1.20 3.82
3.73E+01 1.53 1.20 3.82
2.55E+01 2.72 1.20 3.82
3.24E+01 3.39 1.20 3.82
6.00E-01 21.30 1.20 3.82
6.00E-01 42.28 1.20 3.82
6.00E-01 66.19 1.20 3.82
6.00E-01 45.80 1.20 3.82
6.00E-01 55.19 1.20 3.82
6.00E-01 60.76 1.20 3.82
6.00E-01 22.19 1.20 3.82
6.00E-01 49.87 1.20 3.82
6.00E-01 55.68 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.36E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.80E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab 105 1315SWA
11/16/11 3:22 PM EPA Interlab LOS 1315 SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315 SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 131 5 SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab LOS 1315 SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315 SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315 SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315 SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-534
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Co SWA-L05-1315-T01-A 1 9.00E-01 U1/2
Co SWA-L05-1315-T02-A 1 9.00E-01 U1/2
Co SWA-L05-1315-T03-A 1 9.00E-01 U1/2
Co SWA-L05-1315-T04-A 1 9.00E-01 U1/2
Co SWA-L05-1315-T05-A 1 9.00E-01 U1/2
Co SWA-L05-1315-T06-A 1 9.00E-01 U1/2
Co SWA-L05-1315-T07-A 1 9.00E-01 U1/2
Co SWA-L05-1315-T08-A 1 9.00E-01 U1/2
Co SWA-L05-1315-T09-A 1 9.00E-01 U1/2
Co SWA-L05-1315-T01-B 1 9.00E-01 U1/2
Co SWA-L05-1315-T02-B 1 9.00E-01 U1/2
Co SWA-L05-1315-T03-B 1 9.00E-01 U1/2
Co SWA-L05-1315-T04-B 1 9.00E-01 U1/2
Co SWA-L05-1315-T05-B 1 9.00E-01 U1/2
Co SWA-L05-1315-T06-B 1 9.00E-01 U1/2
Co SWA-L05-1315-T07-B 1 9.00E-01 U1/2
Co SWA-L05-1315-T08-B 1 9.00E-01 U1/2
Co SWA-L05-1315-T09-B 1 9.00E-01 U1/2
Co SWA-L05-1315-T01-C 1 9.00E-01 U1/2
Co SWA-L05-1315-T02-C 1 9.00E-01 U1/2
Co SWA-L05-1315-T03-C 1 9.00E-01 U1/2
Co SWA-L05-1315-T04-C 1 9.00E-01 U1/2
Co SWA-L05-1315-T05-C 1 9.00E-01 U1/2
Co SWA-L05-1315-T06-C 1 9.00E-01 U1/2
Co SWA-L05-1315-T07-C 1 9.00E-01 U1/2
Co SWA-L05-1315-T08-C 1 9.00E-01 U1/2
Co SWA-L05-1315-T09-C 1 9.00E-01 U1/2
Co SWA-L05-1315-M01-A 1 9.00E-01 U1/2
Co SWA-L05-1315-M02-A 1 9.00E-01 U1/2
Co SWA-L05-1315-M03-A 1 9.00E-01 U1/2
Co SWA-L05-1315-M04-A 1 9.00E-01 U1/2
Co SWA-L05-1315-M05-A 1 9.00E-01 U1/2
Co SWA-L05-1315-M06-A 1 9.00E-01 U1/2
Co SWA-L05-1315-M07-A 1 9.00E-01 U1/2
Co SWA-L05-1315-M08-A 1 9.00E-01 U1/2
Co SWA-L05-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 50.97 1.80 5.72
9.00E-01 31.40 1.80 5.72
9.00E-01 32.46 1.80 5.72 10000 1000
9.00E-01 49.61 1.80 5.72
9.00E-01 24.29 1.80 5.72
9.00E-01 38.98 1.80 5.72
9.00E-01 69.23 1.80 5.72
9.00E-01 52.00 1.80 5.72
9.00E-01 28.09 1.80 5.72
9.00E-01 36.69 1.80 5.72
9.00E-01 74.88 1.80 5.72
9.00E-01 41.06 1.80 5.72 10000 1000
9.00E-01 11.07 1.80 5.72
9.00E-01 72.65 1.80 5.72
9.00E-01 73.23 1.80 5.72
9.00E-01 26.02 1.80 5.72
9.00E-01 59.86 1.80 5.72
9.00E-01 37.85 1.80 5.72
9.00E-01 17.50 1.80 5.72
9.00E-01 24.34 1.80 5.72
9.00E-01 26.76 1.80 5.72 10000 1000
9.00E-01 39.49 1.80 5.72
9.00E-01 40.51 1.80 5.72
9.00E-01 59.78 1.80 5.72
9.00E-01 65.32 1.80 5.72
9.00E-01 150.77 1.80 5.72
9.00E-01 29.08 1.80 5.72
9.00E-01 78.99 1.80 5.72
9.00E-01 25.73 1.80 5.72
9.00E-01 20.38 1.80 5.72
9.00E-01 25.93 1.80 5.72
9.00E-01 32.18 1.80 5.72
9.00E-01 43.00 1.80 5.72
9.00E-01 22.49 1.80 5.72
9.00E-01 24.26 1.80 5.72
9.00E-01 31.73 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.13E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.29E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.57E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab LOS 131 5 SWA
11/16/11 3:22 PM EPA Interlab LOS 1315SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 1315SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab 105 1315SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab 105 1315SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab 105 1315SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-535
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cu SWA-L05-1315-T01-A 1 1.85E+00 U1/2
Cu SWA-L05-1315-T02-A 1 1.85E+00 U1/2
Cu SWA-L05-1315-T03-A 1 1.85E+00 U1/2
Cu SWA-L05-1315-T04-A 1 1.85E+00 U1/2
Cu SWA-L05-1315-T05-A 1 1.85E+00 U1/2
Cu SWA-L05-1315-T06-A 1 1.85E+00 U1/2
Cu SWA-L05-1315-T07-A 1 1.85E+00 U1/2
Cu SWA-L05-1315-T08-A 1 1.85E+00 U1/2
Cu SWA-L05-1315-T09-A 1 1.85E+00 U1/2
Cu SWA-L05-1315-T01-B 1 1.85E+00 U1/2
Cu SWA-L05-1315-T02-B 1 1.85E+00 U1/2
Cu SWA-L05-1315-T03-B 1 1.85E+00 U1/2
Cu SWA-L05-1315-T04-B 1 1.85E+00 U1/2
Cu SWA-L05-1315-T05-B 1 1.85E+00 U1/2
Cu SWA-L05-1315-T06-B 1 1.85E+00 U1/2
Cu SWA-L05-1315-T07-B 1 1.85E+00 U1/2
Cu SWA-L05-1315-T08-B 1 1.85E+00 U1/2
Cu SWA-L05-1315-T09-B 1 1.85E+00 U1/2
Cu SWA-L05-1315-T01-C 1 1.85E+00 U1/2
Cu SWA-L05-1315-T02-C 1 1.85E+00 U1/2
Cu SWA-L05-1315-T03-C 1 1.85E+00 U1/2
Cu SWA-L05-1315-T04-C 1 1.85E+00 U1/2
Cu SWA-L05-1315-T05-C 1 1.85E+00 U1/2
Cu SWA-L05-1315-T06-C 1 1.85E+00 U1/2
Cu SWA-L05-1315-T07-C 1 1.85E+00 U1/2
Cu SWA-L05-1315-T08-C 1 1.85E+00 U1/2
Cu SWA-L05-1315-T09-C 1 1.85E+00 U1/2
Cu SWA-L05-1315-M01-A 1 1.85E+00 U1/2
Cu SWA-L05-1315-M02-A 1 1.85E+00 U1/2
Cu SWA-L05-1315-M03-A 1 1.85E+00 U1/2
Cu SWA-L05-1315-M04-A 1 1.85E+00 U1/2
Cu SWA-L05-1315-M05-A 1 1.85E+00 U1/2
Cu SWA-L05-1315-M06-A 1 1.85E+00 U1/2
Cu SWA-L05-1315-M07-A 1 1.85E+00 U1/2
Cu SWA-L05-1315-M08-A 1 1.85E+00 U1/2
Cu SWA-L05-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 72.76 3.70 11.80
1.85E+00 21.80 3.70 11.80
1.85E+00 33.76 3.70 11.80 10000 1000
1.85E+00 36.04 3.70 11.80
1.85E+00 53.69 3.70 11.80
1.85E+00 15.25 3.70 11.80
1.85E+00 31.30 3.70 11.80
1.85E+00 21.52 3.70 11.80
1.85E+00 16.37 3.70 11.80
1.85E+00 30.87 3.70 11.80
1.85E+00 41.35 3.70 11.80
1.85E+00 29.43 3.70 11.80 10000 1000
1.85E+00 39.77 3.70 11.80
1.85E+00 37.78 3.70 11.80
1.85E+00 37.30 3.70 11.80
1.85E+00 36.73 3.70 11.80
1.85E+00 38.10 3.70 11.80
1.85E+00 29.91 3.70 11.80
1.85E+00 48.04 3.70 11.80
1.85E+00 11.47 3.70 11.80
1.85E+00 14.91 3.70 11.80 10000 1000
1.85E+00 14.26 3.70 11.80
1.85E+00 35.53 3.70 11.80
1.85E+00 32.67 3.70 11.80
1.85E+00 50.95 3.70 11.80
1.85E+00 39.72 3.70 11.80
1.85E+00 9.79 3.70 11.80
1.85E+00 38.05 3.70 11.80
1.85E+00 47.84 3.70 11.80
1.85E+00 18.33 3.70 11.80
1.85E+00 20.67 3.70 11.80
1.85E+00 46.24 3.70 11.80
1.85E+00 34.22 3.70 11.80
1.85E+00 36.24 3.70 11.80
1.85E+00 34.94 3.70 11.80
1.85E+00 20.14 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.07E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.27E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.42E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab LOS 131 5 SWA
11/16/11 3:22 PM EPA Interlab LOS 1315SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 1315SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab 105 1315SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab 105 1315SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab 105 1315SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-536
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
Fe SWA-L05-1315-T01-A 1 1.19E+01
Fe SWA-L05-1315-T02-A 1 1.31E+01
Fe SWA-L05-1315-T03-A 1 4.92E+00 E
Fe SWA-L05-1315-T04-A 1 3.08E+00 E
Fe SWA-L05-1315-T05-A 1 3.30E+00 E
Fe SWA-L05-1315-T06-A 1 2.95E+00 E
Fe SWA-L05-1315-T07-A 1 2.02E+00 E
Fe SWA-L05-1315-T08-A 1 1.00E+00 U1/2
Fe SWA-L05-1315-T09-A 1 1.00E+00 U1/2
Fe SWA-L05-1315-T01-B 1 1.14E+01
Fe SWA-L05-1315-T02-B 1 1.64E+01
Fe SWA-L05-1315-T03-B 1 4.81E+00 E
Fe SWA-L05-1315-T04-B 1 4.21E+00 E
Fe SWA-L05-1315-T05-B 1 4.18E+00 E
Fe SWA-L05-1315-T06-B 1 2.51E+00 E
Fe SWA-L05-1315-T07-B 1 2.12E+00 E
Fe SWA-L05-1315-T08-B 1 1.00E+00 U1/2
Fe SWA-L05-1315-T09-B 1 1.00E+00 U1/2
Fe SWA-L05-1315-T01-C 1 1.54E+01
Fe SWA-L05-1315-T02-C 1 1.70E+01
Fe SWA-L05-1315-T03-C 1 6.90E+00
Fe SWA-L05-1315-T04-C 1 5.32E+00 E
Fe SWA-L05-1315-T05-C 1 5.22E+00 E
Fe SWA-L05-1315-T06-C 1 2.33E+00 E
Fe SWA-L05-1315-T07-C 1 2.48E+00 E
Fe SWA-L05-1315-T08-C 1 1.00E+00 U1/2
Fe SWA-L05-1315-T09-C 1 1.00E+00 U1/2
Fe SWA-L05-1315-M01-A 1 1.00E+00 U1/2
Fe SWA-L05-1315-M02-A 1 1.00E+00 U1/2
Fe SWA-L05-1315-M03-A 1 1.00E+00 U1/2
Fe SWA-L05-1315-M04-A 1 1.00E+00 U1/2
Fe SWA-L05-1315-M05-A 1 1.00E+00 U1/2
Fe SWA-L05-1315-M06-A 1 1.00E+00 U1/2
Fe SWA-L05-1315-M07-A 1 1.00E+00 U1/2
Fe SWA-L05-1315-M08-A 1 1.00E+00 U1/2
Fe SWA-L05-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.19E+01 5.87 2.00 6.40
1.31E+01 3.23 2.00 6.40
4.92E+00 5.29 2.00 6.40 10000 1000
3.08E+00 6.52 2.00 6.40
3.30E+00 7.35 2.00 6.40
2.95E+00 16.34 2.00 6.40
2.02E+00 1.77 2.00 6.40
1.00E+00 7.79 2.00 6.40
1.00E+00 5.84 2.00 6.40
1.14E+01 0.78 2.00 6.40
1.64E+01 3.30 2.00 6.40
4.81E+00 1.57 2.00 6.40 10000 1000
4.21 E+00 4.28 2.00 6.40
4.18E+00 7.16 2.00 6.40
2.51 E+00 4.93 2.00 6.40
2.12E+00 12.80 2.00 6.40
1.00E+00 9.36 2.00 6.40
1.00E+00 4.41 2.00 6.40
1.54E+01 0.39 2.00 6.40
1.70E+01 1.55 2.00 6.40
6.90E+00 3.42 2.00 6.40 10000 1000
5.32E+00 5.88 2.00 6.40
5.22E+00 7.05 2.00 6.40
2.33E+00 4.65 2.00 6.40
2.48E+00 10.52 2.00 6.40
1.00E+00 17.12 2.00 6.40
1.00E+00 17.26 2.00 6.40
1.00E+00 3.37 2.00 6.40
1.00E+00 16.91 2.00 6.40
1.00E+00 13.62 2.00 6.40
1.00E+00 10.98 2.00 6.40
1.00E+00 19.79 2.00 6.40
1.00E+00 23.99 2.00 6.40
1.00E+00 17.78 2.00 6.40
1.00E+00 27.97 2.00 6.40
1.00E+00 30.59 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.44E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.64E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab 105 1315SWA
11/16/11 3:22 PM EPA Interlab LOS 1315SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 1315SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab 105 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab 105 1315 SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315 SWA
11/16/11 3:54 PM EPA Interlab 105 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab 105 1315SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab 105 1315SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-537
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Pb SWA-L05-1315-T01-A 1 3.40E+00 U1/2
Pb SWA-L05-1315-T02-A 1 3.40E+00 U1/2
Pb SWA-L05-1315-T03-A 1 3.40E+00 U1/2
Pb SWA-L05-1315-T04-A 1 3.40E+00 U1/2
Pb SWA-L05-1315-T05-A 1 3.40E+00 U1/2
Pb SWA-L05-1315-T06-A 1 3.40E+00 U1/2
Pb SWA-L05-1315-T07-A 1 3.40E+00 U1/2
Pb SWA-L05-1315-T08-A 1 3.40E+00 U1/2
Pb SWA-L05-1315-T09-A 1 3.40E+00 U1/2
Pb SWA-L05-1315-T01-B 1 3.40E+00 U1/2
Pb SWA-L05-1315-T02-B 1 3.40E+00 U1/2
Pb SWA-L05-1315-T03-B 1 3.40E+00 U1/2
Pb SWA-L05-1315-T04-B 1 3.40E+00 U1/2
Pb SWA-L05-1315-T05-B 1 3.40E+00 U1/2
Pb SWA-L05-1315-T06-B 1 3.40E+00 U1/2
Pb SWA-L05-1315-T07-B 1 3.40E+00 U1/2
Pb SWA-L05-1315-T08-B 1 3.40E+00 U1/2
Pb SWA-L05-1315-T09-B 1 3.40E+00 U1/2
Pb SWA-L05-1315-T01-C 1 3.40E+00 U1/2
Pb SWA-L05-1315-T02-C 1 3.40E+00 U1/2
Pb SWA-L05-1315-T03-C 1 3.40E+00 U1/2
Pb SWA-L05-1315-T04-C 1 3.40E+00 U1/2
Pb SWA-L05-1315-T05-C 1 3.40E+00 U1/2
Pb SWA-L05-1315-T06-C 1 3.40E+00 U1/2
Pb SWA-L05-1315-T07-C 1 3.40E+00 U1/2
Pb SWA-L05-1315-T08-C 1 3.40E+00 U1/2
Pb SWA-L05-1315-T09-C 1 3.40E+00 U1/2
Pb SWA-L05-1315-M01-A 1 3.40E+00 U1/2
Pb SWA-L05-1315-M02-A 1 3.40E+00 U1/2
Pb SWA-L05-1315-M03-A 1 3.40E+00 U1/2
Pb SWA-L05-1315-M04-A 1 3.40E+00 U1/2
Pb SWA-L05-1315-M05-A 1 3.40E+00 U1/2
Pb SWA-L05-1315-M06-A 1 3.40E+00 U1/2
Pb SWA-L05-1315-M07-A 1 3.40E+00 U1/2
Pb SWA-L05-1315-M08-A 1 3.40E+00 U1/2
Pb SWA-L05-1315-M09-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 53.89 6.80 21.60
3.40E+00 37.82 6.80 21.60
3.40E+00 24.56 6.80 21.60 10000 1000
3.40E+00 48.61 6.80 21.60
3.40E+00 29.66 6.80 21.60
3.40E+00 48.61 6.80 21.60
3.40E+00 35.42 6.80 21.60
3.40E+00 43.71 6.80 21.60
3.40E+00 32.49 6.80 21.60
3.40E+00 54.67 6.80 21.60
3.40E+00 34.97 6.80 21.60
3.40E+00 27.88 6.80 21.60 10000 1000
3.40E+00 17.17 6.80 21.60
3.40E+00 27.93 6.80 21.60
3.40E+00 68.08 6.80 21.60
3.40E+00 59.69 6.80 21.60
3.40E+00 54.07 6.80 21.60
3.40E+00 43.80 6.80 21.60
3.40E+00 47.65 6.80 21.60
3.40E+00 29.85 6.80 21.60
3.40E+00 25.17 6.80 21.60 10000 1000
3.40E+00 25.34 6.80 21.60
3.40E+00 21.87 6.80 21.60
3.40E+00 71.44 6.80 21.60
3.40E+00 38.97 6.80 21.60
3.40E+00 61.29 6.80 21.60
3.40E+00 41.86 6.80 21.60
3.40E+00 35.33 6.80 21.60
3.40E+00 23.76 6.80 21.60
3.40E+00 31.04 6.80 21.60
3.40E+00 47.09 6.80 21.60
3.40E+00 34.34 6.80 21.60
3.40E+00 1.23 6.80 21.60
3.40E+00 13.24 6.80 21.60
3.40E+00 41.43 6.80 21.60
3.40E+00 25.43 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.20E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.18E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.43E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab 105 1315SWA
11/16/11 3:22 PM EPA Interlab LOS 1315SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315 SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 1315 SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab LOS 1315 SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315 SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315 SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315 SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-538
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Li SWA-L05-1315-T01-A 1 9.50E-01 U1/2
Li SWA-L05-1315-T02-A 1 9.50E-01 U1/2
Li SWA-L05-1315-T03-A 1 9.50E-01 U1/2
Li SWA-L05-1315-T04-A 1 9.50E-01 U1/2
Li SWA-L05-1315-T05-A 1 9.50E-01 U1/2
Li SWA-L05-1315-T06-A 1 9.50E-01 U1/2
Li SWA-L05-1315-T07-A 1 9.50E-01 U1/2
Li SWA-L05-1315-T08-A 1 9.50E-01 U1/2
Li SWA-L05-1315-T09-A 1 9.50E-01 U1/2
Li SWA-L05-1315-T01-B 1 9.50E-01 U1/2
Li SWA-L05-1315-T02-B 1 9.50E-01 U1/2
Li SWA-L05-1315-T03-B 1 9.50E-01 U1/2
Li SWA-L05-1315-T04-B 1 9.50E-01 U1/2
Li SWA-L05-1315-T05-B 1 9.50E-01 U1/2
Li SWA-L05-1315-T06-B 1 9.50E-01 U1/2
Li SWA-L05-1315-T07-B 1 9.50E-01 U1/2
Li SWA-L05-1315-T08-B 1 9.50E-01 U1/2
Li SWA-L05-1315-T09-B 1 9.50E-01 U1/2
Li SWA-L05-1315-T01-C 1 9.50E-01 U1/2
Li SWA-L05-1315-T02-C 1 9.50E-01 U1/2
Li SWA-L05-1315-T03-C 1 9.50E-01 U1/2
Li SWA-L05-1315-T04-C 1 9.50E-01 U1/2
Li SWA-L05-1315-T05-C 1 9.50E-01 U1/2
Li SWA-L05-1315-T06-C 1 9.50E-01 U1/2
Li SWA-L05-1315-T07-C 1 9.50E-01 U1/2
Li SWA-L05-1315-T08-C 1 9.50E-01 U1/2
Li SWA-L05-1315-T09-C 1 9.50E-01 U1/2
Li SWA-L05-1315-M01-A 1 9.50E-01 U1/2
Li SWA-L05-1315-M02-A 1 9.50E-01 U1/2
Li SWA-L05-1315-M03-A 1 9.50E-01 U1/2
Li SWA-L05-1315-M04-A 1 9.50E-01 U1/2
Li SWA-L05-1315-M05-A 1 9.50E-01 U1/2
Li SWA-L05-1315-M06-A 1 9.50E-01 U1/2
Li SWA-L05-1315-M07-A 1 9.50E-01 U1/2
Li SWA-L05-1315-M08-A 1 9.50E-01 U1/2
Li SWA-L05-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 26.02 1.90 6.00
9.50E-01 10.84 1.90 6.00
9.50E-01 67.25 1.90 6.00 10000 1000
9.50E-01 52.26 1.90 6.00
9.50E-01 23.44 1.90 6.00
9.50E-01 12.27 1.90 6.00
9.50E-01 16.25 1.90 6.00
9.50E-01 13.76 1.90 6.00
9.50E-01 68.69 1.90 6.00
9.50E-01 41.27 1.90 6.00
9.50E-01 20.55 1.90 6.00
9.50E-01 63.99 1.90 6.00 10000 1000
9.50E-01 12.46 1.90 6.00
9.50E-01 10.15 1.90 6.00
9.50E-01 29.03 1.90 6.00
9.50E-01 21.53 1.90 6.00
9.50E-01 16.96 1.90 6.00
9.50E-01 97.49 1.90 6.00
9.50E-01 1.33 1.90 6.00
9.50E-01 10.44 1.90 6.00
9.50E-01 11.17 1.90 6.00 10000 1000
9.50E-01 31.53 1.90 6.00
9.50E-01 15.89 1.90 6.00
9.50E-01 24.28 1.90 6.00
9.50E-01 8.26 1.90 6.00
9.50E-01 33.80 1.90 6.00
9.50E-01 49.77 1.90 6.00
9.50E-01 26.10 1.90 6.00
9.50E-01 4.59 1.90 6.00
9.50E-01 3.65 1.90 6.00
9.50E-01 5.41 1.90 6.00
9.50E-01 37.06 1.90 6.00
9.50E-01 38.19 1.90 6.00
9.50E-01 46.43 1.90 6.00
9.50E-01 18.31 1.90 6.00
9.50E-01 3.20 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.80E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.94E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.09E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab LOS 131 5 SWA
11/16/11 3:22 PM EPA Interlab LOS 1315SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 1315SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab 105 1315SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab 105 1315SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab 105 1315SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-539
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Mn SWA-L05-1315-T01-A 1 1.00E+00 U1/2
Mn SWA-L05-1315-T02-A 1 1.00E+00 U1/2
Mn SWA-L05-1315-T03-A 1 1.00E+00 U1/2
Mn SWA-L05-1315-T04-A 1 1.00E+00 U1/2
Mn SWA-L05-1315-T05-A 1 1.00E+00 U1/2
Mn SWA-L05-1315-T06-A 1 1.00E+00 U1/2
Mn SWA-L05-1315-T07-A 1 1.00E+00 U1/2
Mn SWA-L05-1315-T08-A 1 1.00E+00 U1/2
Mn SWA-L05-1315-T09-A 1 1.00E+00 U1/2
Mn SWA-L05-1315-T01-B 1 1.00E+00 U1/2
Mn SWA-L05-1315-T02-B 1 1.00E+00 U1/2
Mn SWA-L05-1315-T03-B 1 1.00E+00 U1/2
Mn SWA-L05-1315-T04-B 1 1.00E+00 U1/2
Mn SWA-L05-1315-T05-B 1 1.00E+00 U1/2
Mn SWA-L05-1315-T06-B 1 1.00E+00 U1/2
Mn SWA-L05-1315-T07-B 1 1.00E+00 U1/2
Mn SWA-L05-1315-T08-B 1 1.00E+00 U1/2
Mn SWA-L05-1315-T09-B 1 1.00E+00 U1/2
Mn SWA-L05-1315-T01-C 1 1.00E+00 U1/2
Mn SWA-L05-1315-T02-C 1 1.00E+00 U1/2
Mn SWA-L05-1315-T03-C 1 1.00E+00 U1/2
Mn SWA-L05-1315-T04-C 1 1.00E+00 U1/2
Mn SWA-L05-1315-T05-C 1 1.00E+00 U1/2
Mn SWA-L05-1315-T06-C 1 1.00E+00 U1/2
Mn SWA-L05-1315-T07-C 1 1.00E+00 U1/2
Mn SWA-L05-1315-T08-C 1 1.00E+00 U1/2
Mn SWA-L05-1315-T09-C 1 1.00E+00 U1/2
Mn SWA-L05-1315-M01-A 1 1.00E+00 U1/2
Mn SWA-L05-1315-M02-A 1 1.00E+00 U1/2
Mn SWA-L05-1315-M03-A 1 1.00E+00 U1/2
Mn SWA-L05-1315-M04-A 1 1.00E+00 U1/2
Mn SWA-L05-1315-M05-A 1 1.00E+00 U1/2
Mn SWA-L05-1315-M06-A 1 1.00E+00 U1/2
Mn SWA-L05-1315-M07-A 1 1.00E+00 U1/2
Mn SWA-L05-1315-M08-A 1 1.00E+00 U1/2
Mn SWA-L05-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 11.78 2.00 6.40
1.00E+00 16.31 2.00 6.40
1.00E+00 18.20 2.00 6.40 10000 1000
1.00E+00 16.79 2.00 6.40
1.00E+00 4.78 2.00 6.40
1.00E+00 13.41 2.00 6.40
1.00E+00 12.47 2.00 6.40
1.00E+00 3.65 2.00 6.40
1.00E+00 26.78 2.00 6.40
1.00E+00 5.28 2.00 6.40
1.00E+00 12.24 2.00 6.40
1.00E+00 13.95 2.00 6.40 10000 1000
1.00E+00 27.22 2.00 6.40
1.00E+00 15.13 2.00 6.40
1.00E+00 15.23 2.00 6.40
1.00E+00 11.21 2.00 6.40
1.00E+00 22.77 2.00 6.40
1.00E+00 21.12 2.00 6.40
1.00E+00 2.16 2.00 6.40
1.00E+00 21.25 2.00 6.40
1.00E+00 1.71 2.00 6.40 10000 1000
1.00E+00 15.22 2.00 6.40
1.00E+00 14.85 2.00 6.40
1.00E+00 48.49 2.00 6.40
1.00E+00 34.09 2.00 6.40
1.00E+00 9.69 2.00 6.40
1.00E+00 8.32 2.00 6.40
1.00E+00 21.44 2.00 6.40
1.00E+00 1.67 2.00 6.40
1.00E+00 19.38 2.00 6.40
1.00E+00 14.63 2.00 6.40
1.00E+00 45.58 2.00 6.40
1.00E+00 23.77 2.00 6.40
1.00E+00 26.46 2.00 6.40
1.00E+00 49.55 2.00 6.40
1.00E+00 39.97 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.30E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.44E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.63E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab 105 1315SWA
11/16/11 3:22 PM EPA Interlab LOS 1315 SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315 SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 131 5 SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab LOS 1315 SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315 SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315 SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315 SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-540
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Mg SWA-L05-1315-T01-A 1 2.42E+00 E
Mg SWA-L05-1315-T02-A 1 2.26E+01
Mg SWA-L05-1315-T03-A 1 2.57E+01
Mg SWA-L05-1315-T04-A 1 1.81E+01
Mg SWA-L05-1315-T05-A 1 1.68E+01
Mg SWA-L05-1315-T06-A 1 1.07E+01
Mg SWA-L05-1315-T07-A 1 1.54E+01
Mg SWA-L05-1315-T08-A 1 4.86E+01
Mg SWA-L05-1315-T09-A 1 2.75E+01
Mg SWA-L05-1315-T01-B 1 2.13E+00 E
Mg SWA-L05-1315-T02-B 1 2.07E+01
Mg SWA-L05-1315-T03-B 1 2.35E+01
Mg SWA-L05-1315-T04-B 1 1.70E+01
Mg SWA-L05-1315-T05-B 1 1.58E+01
Mg SWA-L05-1315-T06-B 1 1.43E+01
Mg SWA-L05-1315-T07-B 1 1.85E+01
Mg SWA-L05-1315-T08-B 1 3.78E+01
Mg SWA-L05-1315-T09-B 1 1.85E+01
Mg SWA-L05-1315-T01-C 1 3.99E+00
Mg SWA-L05-1315-T02-C 1 2.12E+01
Mg SWA-L05-1315-T03-C 1 2.47E+01
Mg SWA-L05-1315-T04-C 1 1.77E+01
Mg SWA-L05-1315-T05-C 1 1.75E+01
Mg SWA-L05-1315-T06-C 1 1.05E+01
Mg SWA-L05-1315-T07-C 1 1.71E+01
Mg SWA-L05-1315-T08-C 1 3.32E+01
Mg SWA-L05-1315-T09-C 1 1.72E+01
Mg SWA-L05-1315-M01-A 1 5.00E-01 U1/2
Mg SWA-L05-1315-M02-A 1 5.00E-01 U1/2
Mg SWA-L05-1315-M03-A 1 5.00E-01 U1/2
Mg SWA-L05-1315-M04-A 1 5.00E-01 U1/2
Mg SWA-L05-1315-M05-A 1 5.00E-01 U1/2
Mg SWA-L05-1315-M06-A 1 5.00E-01 U1/2
Mg SWA-L05-1315-M07-A 1 5.00E-01 U1/2
Mg SWA-L05-1315-M08-A 1 5.00E-01 U1/2
Mg SWA-L05-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.42E+00 2.51 1.00 3.18
2.26E+01 1.26 1.00 3.18
2.57E+01 9.06 1.00 3.18 10000 1000
1.81E+01 7.26 1.00 3.18
1.68E+01 1.61 1.00 3.18
1.07E+01 2.08 1.00 3.18
1.54E+01 8.32 1.00 3.18
4.86E+01 6.02 1.00 3.18
2.75E+01 6.46 1.00 3.18
2.13E+00 3.77 1.00 3.18
2.07E+01 1.68 1.00 3.18
2.35E+01 3.20 1.00 3.18 10000 1000
1.70E+01 1.29 1.00 3.18
1.58E+01 8.39 1.00 3.18
1.43E+01 1.48 1.00 3.18
1.85E+01 1.49 1.00 3.18
3.78E+01 7.81 1.00 3.18
1.85E+01 6.57 1.00 3.18
3.99E+00 1.73 1.00 3.18
2.12E+01 1.30 1.00 3.18
2.47E+01 6.12 1.00 3.18 10000 1000
1.77E+01 1.20 1.00 3.18
1.75E+01 8.89 1.00 3.18
1.05E+01 15.51 1.00 3.18
1.71E+01 8.01 1.00 3.18
3.32E+01 1.76 1.00 3.18
1.72E+01 1.47 1.00 3.18
5.00E-01 23.55 1.00 3.18
5.00E-01 10.82 1.00 3.18
5.00E-01 17.53 1.00 3.18
5.00E-01 8.47 1.00 3.18
5.00E-01 5.51 1.00 3.18
5.00E-01 8.37 1.00 3.18
5.00E-01 1.12 1.00 3.18
5.00E-01 22.08 1.00 3.18
5.00E-01 26.13 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab 105 1315SWA
11/16/11 3:22 PM EPA Interlab LOS 1315 SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315 SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 131 5 SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab LOS 1315 SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315 SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315 SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315 SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-541
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Mo SWA-L05-1315-T01-A 1 6.69E+00
Mo SWA-L05-1315-T02-A 1 7.15E+00
Mo SWA-L05-1315-T03-A 1 5.20E+00
Mo SWA-L05-1315-T04-A 1 7.34E+00
Mo SWA-L05-1315-T05-A 1 5.71E+00
Mo SWA-L05-1315-T06-A 1 6.56E+00
Mo SWA-L05-1315-T07-A 1 5.62E+00
Mo SWA-L05-1315-T08-A 1 2.76E+00 E
Mo SWA-L05-1315-T09-A 1 4.06E+00
Mo SWA-L05-1315-T01-B 1 5.57E+00
Mo SWA-L05-1315-T02-B 1 8.59E+00
Mo SWA-L05-1315-T03-B 1 5.77E+00
Mo SWA-L05-1315-T04-B 1 1.13E+01
Mo SWA-L05-1315-T05-B 1 9.56E+00
Mo SWA-L05-1315-T06-B 1 9.64E+00
Mo SWA-L05-1315-T07-B 1 6.35E+00
Mo SWA-L05-1315-T08-B 1 4.40E+00
Mo SWA-L05-1315-T09-B 1 4.87E+00
Mo SWA-L05-1315-T01-C 1 6.29E+00
Mo SWA-L05-1315-T02-C 1 7.31E+00
Mo SWA-L05-1315-T03-C 1 5.39E+00
Mo SWA-L05-1315-T04-C 1 9.28E+00
Mo SWA-L05-1315-T05-C 1 7.64E+00
Mo SWA-L05-1315-T06-C 1 7.40E+00
Mo SWA-L05-1315-T07-C 1 6.27E+00
Mo SWA-L05-1315-T08-C 1 3.28E+00 E
Mo SWA-L05-1315-T09-C 1 4.66E+00
Mo SWA-L05-1315-M01-A 1 6.00E-01 U1/2
Mo SWA-L05-1315-M02-A 1 6.00E-01 U1/2
Mo SWA-L05-1315-M03-A 1 6.00E-01 U1/2
Mo SWA-L05-1315-M04-A 1 6.00E-01 U1/2
Mo SWA-L05-1315-M05-A 1 6.00E-01 U1/2
Mo SWA-L05-1315-M06-A 1 6.00E-01 U1/2
Mo SWA-L05-1315-M07-A 1 6.00E-01 U1/2
Mo SWA-L05-1315-M08-A 1 6.00E-01 U1/2
Mo SWA-L05-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.69E+00 1.46 1.20 3.82
7.15E+00 11.64 1.20 3.82
5.20E+00 3.68 1.20 3.82 10000 1000
7.34E+00 1.71 1.20 3.82
5.71E+00 3.90 1.20 3.82
6.56E+00 8.03 1.20 3.82
5.62E+00 1.29 1.20 3.82
2.76E+00 10.64 1.20 3.82
4.06E+00 10.81 1.20 3.82
5.57E+00 7.14 1.20 3.82
8.59E+00 8.81 1.20 3.82
5.77E+00 3.27 1.20 3.82 10000 1000
1.13E+01 7.37 1.20 3.82
9.56E+00 3.41 1.20 3.82
9.64E+00 1.41 1.20 3.82
6.35E+00 4.72 1.20 3.82
4.40E+00 2.38 1.20 3.82
4.87E+00 1.53 1.20 3.82
6.29E+00 1.05 1.20 3.82
7.31E+00 6.80 1.20 3.82
5.39E+00 1.34 1.20 3.82 10000 1000
9.28E+00 6.51 1.20 3.82
7.64E+00 1.34 1.20 3.82
7.40E+00 1.39 1.20 3.82
6.27E+00 1.63 1.20 3.82
3.28E+00 3.08 1.20 3.82
4.66E+00 2.76 1.20 3.82
6.00E-01 1.31 1.20 3.82
6.00E-01 10.16 1.20 3.82
6.00E-01 1.62 1.20 3.82
6.00E-01 6.13 1.20 3.82
6.00E-01 30.81 1.20 3.82
6.00E-01 32.72 1.20 3.82
6.00E-01 12.19 1.20 3.82
6.00E-01 1.40 1.20 3.82
6.00E-01 6.45 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.22E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.36E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.66E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab 105 1315SWA
11/16/11 3:22 PM EPA Interlab LOS 1315 SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315 SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 131 5 SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab LOS 1315 SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315 SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315 SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315 SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-542
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ni SWA-L05-1315-T01-A 1 9.00E-01 U1/2
Ni SWA-L05-1315-T02-A 1 9.00E-01 U1/2
Ni SWA-L05-1315-T03-A 1 9.00E-01 U1/2
Ni SWA-L05-1315-T04-A 1 9.00E-01 U1/2
Ni SWA-L05-1315-T05-A 1 9.00E-01 U1/2
Ni SWA-L05-1315-T06-A 1 9.00E-01 U1/2
Ni SWA-L05-1315-T07-A 1 9.00E-01 U1/2
Ni SWA-L05-1315-T08-A 1 9.00E-01 U1/2
Ni SWA-L05-1315-T09-A 1 9.00E-01 U1/2
Ni SWA-L05-1315-T01-B 1 9.00E-01 U1/2
Ni SWA-L05-1315-T02-B 1 9.00E-01 U1/2
Ni SWA-L05-1315-T03-B 1 9.00E-01 U1/2
Ni SWA-L05-1315-T04-B 1 9.00E-01 U1/2
Ni SWA-L05-1315-T05-B 1 9.00E-01 U1/2
Ni SWA-L05-1315-T06-B 1 9.00E-01 U1/2
Ni SWA-L05-1315-T07-B 1 9.00E-01 U1/2
Ni SWA-L05-1315-T08-B 1 9.00E-01 U1/2
Ni SWA-L05-1315-T09-B 1 9.00E-01 U1/2
Ni SWA-L05-1315-T01-C 1 9.00E-01 U1/2
Ni SWA-L05-1315-T02-C 1 9.00E-01 U1/2
Ni SWA-L05-1315-T03-C 1 9.00E-01 U1/2
Ni SWA-L05-1315-T04-C 1 9.00E-01 U1/2
Ni SWA-L05-1315-T05-C 1 9.00E-01 U1/2
Ni SWA-L05-1315-T06-C 1 9.00E-01 U1/2
Ni SWA-L05-1315-T07-C 1 9.00E-01 U1/2
Ni SWA-L05-1315-T08-C 1 9.00E-01 U1/2
Ni SWA-L05-1315-T09-C 1 9.00E-01 U1/2
Ni SWA-L05-1315-M01-A 1 9.00E-01 U1/2
Ni SWA-L05-1315-M02-A 1 9.00E-01 U1/2
Ni SWA-L05-1315-M03-A 1 9.00E-01 U1/2
Ni SWA-L05-1315-M04-A 1 9.00E-01 U1/2
Ni SWA-L05-1315-M05-A 1 9.00E-01 U1/2
Ni SWA-L05-1315-M06-A 1 9.00E-01 U1/2
Ni SWA-L05-1315-M07-A 1 9.00E-01 U1/2
Ni SWA-L05-1315-M08-A 1 9.00E-01 U1/2
Ni SWA-L05-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 32.15 1.80 5.70
9.00E-01 19.54 1.80 5.70
9.00E-01 27.09 1.80 5.70 10000 1000
9.00E-01 25.93 1.80 5.70
9.00E-01 44.12 1.80 5.70
9.00E-01 44.47 1.80 5.70
9.00E-01 26.03 1.80 5.70
9.00E-01 14.91 1.80 5.70
9.00E-01 49.26 1.80 5.70
9.00E-01 22.87 1.80 5.70
9.00E-01 53.82 1.80 5.70
9.00E-01 24.23 1.80 5.70 10000 1000
9.00E-01 31.88 1.80 5.70
9.00E-01 39.92 1.80 5.70
9.00E-01 28.06 1.80 5.70
9.00E-01 22.16 1.80 5.70
9.00E-01 22.84 1.80 5.70
9.00E-01 79.84 1.80 5.70
9.00E-01 38.47 1.80 5.70
9.00E-01 58.41 1.80 5.70
9.00E-01 55.12 1.80 5.70 10000 1000
9.00E-01 18.99 1.80 5.70
9.00E-01 48.41 1.80 5.70
9.00E-01 60.22 1.80 5.70
9.00E-01 25.94 1.80 5.70
9.00E-01 57.93 1.80 5.70
9.00E-01 13.30 1.80 5.70
9.00E-01 32.26 1.80 5.70
9.00E-01 31.94 1.80 5.70
9.00E-01 17.80 1.80 5.70
9.00E-01 31.22 1.80 5.70
9.00E-01 68.71 1.80 5.70
9.00E-01 26.67 1.80 5.70
9.00E-01 43.92 1.80 5.70
9.00E-01 46.28 1.80 5.70
9.00E-01 34.36 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.08E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.19E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.39E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab LOS 131 5 SWA
11/16/11 3:22 PM EPA Interlab LOS 1315SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 1315SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab 105 1315SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab 105 1315SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab 105 1315SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-543
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
P SWA-L05-1315-T01-A 1 1.37E+01
P SWA-L05-1315-T02-A 1 1.91E+01
P SWA-L05-1315-T03-A 1 1.71E+01
P SWA-L05-1315-T04-A 1 1.40E+01
P SWA-L05-1315-T05-A 1 1.03E+01 E
P SWA-L05-1315-T06-A 1 1.38E+01
P SWA-L05-1315-T07-A 1 1.00E+01 E
P SWA-L05-1315-T08-A 1 7.46E+00 E
P SWA-L05-1315-T09-A 1 9.40E+00 E
P SWA-L05-1315-T01-B 1 1.25E+01
P SWA-L05-1315-T02-B 1 2.18E+01
P SWA-L05-1315-T03-B 1 1.59E+01
P SWA-L05-1315-T04-B 1 1.39E+01
P SWA-L05-1315-T05-B 1 1.27E+01
P SWA-L05-1315-T06-B 1 1.47E+01
P SWA-L05-1315-T07-B 1 1.46E+01
P SWA-L05-1315-T08-B 1 6.36E+00 E
P SWA-L05-1315-T09-B 1 7.76E+00 E
P SWA-L05-1315-T01-C 1 1.90E+01
P SWA-L05-1315-T02-C 1 1.46E+01
P SWA-L05-1315-T03-C 1 1.43E+01
P SWA-L05-1315-T04-C 1 1.62E+01
P SWA-L05-1315-T05-C 1 1.18E+01 E
P SWA-L05-1315-T06-C 1 1.28E+01
P SWA-L05-1315-T07-C 1 9.16E+00 E
P SWA-L05-1315-T08-C 1 8.54E+00 E
P SWA-L05-1315-T09-C 1 1.09E+01 E
P SWA-L05-1315-M01-A 1 1.85E+00 U1/2
P SWA-L05-1315-M02-A 1 1.85E+00 U1/2
P SWA-L05-1315-M03-A 1 1.85E+00 U1/2
P SWA-L05-1315-M04-A 1 1.85E+00 U1/2
P SWA-L05-1315-M05-A 1 1.85E+00 U1/2
P SWA-L05-1315-M06-A 1 1.85E+00 U1/2
P SWA-L05-1315-M07-A 1 1.85E+00 U1/2
P SWA-L05-1315-M08-A 1 1.85E+00 U1/2
P SWA-L05-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.37E+01 1.98 3.70 11.80
1.91E+01 5.20 3.70 11.80
1.71E+01 15.01 3.70 11.80 10000 1000
1.40E+01 5.02 3.70 11.80
1.03E+01 36.93 3.70 11.80
1.38E+01 3.60 3.70 11.80
1.00E+01 23.83 3.70 11.80
7.46E+00 34.38 3.70 11.80
9.40E+00 23.01 3.70 11.80
1.25E+01 2.27 3.70 11.80
2.18E+01 16.19 3.70 11.80
1.59E+01 2.45 3.70 11.80 10000 1000
1.39E+01 2.24 3.70 11.80
1.27E+01 2.36 3.70 11.80
1.47E+01 3.60 3.70 11.80
1.46E+01 4.38 3.70 11.80
6.36E+00 3.83 3.70 11.80
7.76E+00 29.30 3.70 11.80
1.90E+01 2.04 3.70 11.80
1.46E+01 2.31 3.70 11.80
1.43E+01 6.60 3.70 11.80 10000 1000
1.62E+01 14.91 3.70 11.80
1.18E+01 33.82 3.70 11.80
1.28E+01 5.35 3.70 11.80
9.16E+00 44.85 3.70 11.80
8.54E+00 44.56 3.70 11.80
1.09E+01 22.75 3.70 11.80
1.85E+00 9.43 3.70 11.80
1.85E+00 9.00 3.70 11.80
1.85E+00 43.96 3.70 11.80
1.85E+00 10.84 3.70 11.80
1.85E+00 40.95 3.70 11.80
1.85E+00 28.74 3.70 11.80
1.85E+00 34.65 3.70 11.80
1.85E+00 13.46 3.70 11.80
1.85E+00 50.71 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.92E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.93E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.16E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab 105 1315SWA
11/16/11 3:22 PM EPA Interlab LOS 1315 SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315 SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 1315 SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab 105 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab LOS 1315 SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315 SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 131 5 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315 SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 131 5 SWA
11/16/11 3:12 PM EPA Interlab LOS 131 5 SWA
11/16/11 3:14 PM EPA Interlab LOS 131 5 SWA
11/16/11 3:16 PM EPA Interlab LOS 131 5 SWA
1-544
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
K SWA-L05-1315-T01-A 1 1.43E+04
K SWA-L05-1315-T02-A 1 2.80E+04
K SWA-L05-1315-T03-A 1 1.43E+04
K SWA-L05-1315-T04-A 1 4.06E+04
K SWA-L05-1315-T05-A 1 3.84E+04
K SWA-L05-1315-T06-A 1 4.31 E+04
K SWA-L05-1315-T07-A 1 3.36E+04
K SWA-L05-1315-T08-A 1 1.31 E+04
K SWA-L05-1315-T09-A 1 2.15E+04
K SWA-L05-1315-T01-B 1 1.57E+04
K SWA-L05-1315-T02-B 1 3.01 E+04
K SWA-L05-1315-T03-B 1 1.37E+04
K SWA-L05-1315-T04-B 1 4.24E+04
K SWA-L05-1315-T05-B 1 3.92E+04
K SWA-L05-1315-T06-B 1 4.33E+04
K SWA-L05-1315-T07-B 1 3.54E+04
K SWA-L05-1315-T08-B 1 1.40E+04
K SWA-L05-1315-T09-B 1 2.25E+04
K SWA-L05-1315-T01-C 1 1.46E+04
K SWA-L05-1315-T02-C 1 3.05E+04
K SWA-L05-1315-T03-C 1 1.38E+04
K SWA-L05-1315-T04-C 1 4.26E+04
K SWA-L05-1315-T05-C 1 4.03E+04
K SWA-L05-1315-T06-C 1 4.40E+04
K SWA-L05-1315-T07-C 1 3.71E+04
K SWA-L05-1315-T08-C 1 1.48E+04
K SWA-L05-1315-T09-C 1 2.43E+04
K SWA-L05-1315-M01-A 1 1.47E+01
K SWA-L05-1315-M02-A 1 6.88E+00
K SWA-L05-1315-M03-A 1 4.79E+00 E
K SWA-L05-1315-M04-A 1 1.96E+00 E
K SWA-L05-1315-M05-A 1 6.89E+00
K SWA-L05-1315-M06-A 1 4.57E+00 E
K SWA-L05-1315-M07-A 1 7.81E+00
K SWA-L05-1315-M08-A 1 7.59E+00
K SWA-L05-1315-M09-A 1 4.21E+00 E
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.43E+04 0.27 1.60 5.09
2.80E+04 1.46 1.60 5.09
1.43E+04 0.68 1.60 5.09 10000 1000
4.06E+04 2.25 1.60 5.09
3.84E+04 1.79 1.60 5.09
4.31E+04 0.92 1.60 5.09
3.36E+04 1.22 1.60 5.09
1.31 E+04 1.48 1.60 5.09
2.15E+04 1.41 1.60 5.09
1.57E+04 0.42 1.60 5.09
3.01E+04 0.32 1.60 5.09
1.37E+04 0.45 1.60 5.09 10000 1000
4.24E+04 1.88 1.60 5.09
3.92E+04 1.20 1.60 5.09
4.33E+04 1.98 1.60 5.09
3.54E+04 1.47 1.60 5.09
1.40E+04 0.74 1.60 5.09
2.25E+04 1.12 1.60 5.09
1.46E+04 0.96 1.60 5.09
3.05E+04 1.00 1.60 5.09
1.38E+04 1.24 1.60 5.09 10000 1000
4.26E+04 1.44 1.60 5.09
4.03E+04 2.44 1.60 5.09
4.40E+04 1.12 1.60 5.09
3.71E+04 0.91 1.60 5.09
1.48E+04 1.11 1.60 5.09
2.43E+04 3.00 1.60 5.09
1.47E+01 6.15 1.60 5.09
6.88E+00 1.53 1.60 5.09
4.79E+00 7.51 1.60 5.09
1.96E+00 6.75 1.60 5.09
6.89E+00 3.74 1.60 5.09
4.57E+00 3.43 1.60 5.09
7.81E+00 7.15 1.60 5.09
7.59E+00 2.04 1.60 5.09
4.21E+00 8.57 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.52E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.45E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.47E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab 105 1315SWA
11/16/11 3:22 PM EPA Interlab LOS 1315 SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315 SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 131 5 SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab LOS 1315 SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315 SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315 SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315 SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-545
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Se SWA-L05-1315-T01-A 1 1.71E+03
Se SWA-L05-1315-T02-A 1 2.72E+03
Se SWA-L05-1315-T03-A 1 1.46E+03
Se SWA-L05-1315-T04-A 1 4.19E+03
Se SWA-L05-1315-T05-A 1 2.62E+03
Se SWA-L05-1315-T06-A 1 3.05E+03
Se SWA-L05-1315-T07-A 1 1.59E+03
Se SWA-L05-1315-T08-A 1 5.86E+02
Se SWA-L05-1315-T09-A 1 1.16E+03
Se SWA-L05-1315-T01-B 1 1.74E+03
Se SWA-L05-1315-T02-B 1 3.12E+03
Se SWA-L05-1315-T03-B 1 1.24E+03
Se SWA-L05-1315-T04-B 1 4.37E+03
Se SWA-L05-1315-T05-B 1 2.96E+03
Se SWA-L05-1315-T06-B 1 3.11E+03
Se SWA-L05-1315-T07-B 1 1.70E+03
Se SWA-L05-1315-T08-B 1 5.72E+02
Se SWA-L05-1315-T09-B 1 1.04E+03
Se SWA-L05-1315-T01-C 1 2.24E+03
Se SWA-L05-1315-T02-C 1 2.84E+03
Se SWA-L05-1315-T03-C 1 1.54E+03
Se SWA-L05-1315-T04-C 1 4.21E+03
Se SWA-L05-1315-T05-C 1 2.91E+03
Se SWA-L05-1315-T06-C 1 3.09E+03
Se SWA-L05-1315-T07-C 1 1.77E+03
Se SWA-L05-1315-T08-C 1 6.24E+02
Se SWA-L05-1315-T09-C 1 1.14E+03
Se SWA-L05-1315-M01-A 1 7.50E+00 U1/2
Se SWA-L05-1315-M02-A 1 7.50E+00 U1/2
Se SWA-L05-1315-M03-A 1 7.50E+00 U1/2
Se SWA-L05-1315-M04-A 1 7.50E+00 U1/2
Se SWA-L05-1315-M05-A 1 7.50E+00 U1/2
Se SWA-L05-1315-M06-A 1 7.50E+00 U1/2
Se SWA-L05-1315-M07-A 1 7.50E+00 U1/2
Se SWA-L05-1315-M08-A 1 7.50E+00 U1/2
Se SWA-L05-1315-M09-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.71E+03 0.16 15.00 47.70
2.72E+03 1.07 15.00 47.70
1.46E+03 0.11 15.00 47.70 10000 1000
4.19E+03 1.81 15.00 47.70
2.62E+03 1.96 15.00 47.70
3.05E+03 0.80 15.00 47.70
1.59E+03 2.38 15.00 47.70
5.86E+02 4.60 15.00 47.70
1.16E+03 1.74 15.00 47.70
1.74E+03 0.54 15.00 47.70
3.12E+03 0.49 15.00 47.70
1.24E+03 0.99 15.00 47.70 10000 1000
4.37E+03 2.10 15.00 47.70
2.96E+03 1.08 15.00 47.70
3.11E+03 2.18 15.00 47.70
1.70E+03 1.75 15.00 47.70
5.72E+02 1.32 15.00 47.70
1.04E+03 1.36 15.00 47.70
2.24E+03 1.67 15.00 47.70
2.84E+03 0.49 15.00 47.70
1.54E+03 0.25 15.00 47.70 10000 1000
4.21E+03 0.99 15.00 47.70
2.91E+03 2.40 15.00 47.70
3.09E+03 2.16 15.00 47.70
1.77E+03 0.26 15.00 47.70
6.24E+02 1.03 15.00 47.70
1.14E+03 4.68 15.00 47.70
7.50E+00 44.05 15.00 47.70
7.50E+00 87.30 15.00 47.70
7.50E+00 85.23 15.00 47.70
7.50E+00 27.79 15.00 47.70
7.50E+00 27.74 15.00 47.70
7.50E+00 22.47 15.00 47.70
7.50E+00 36.71 15.00 47.70
7.50E+00 37.88 15.00 47.70
7.50E+00 27.07 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.48E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.22E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.49E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab 105 1315SWA
11/16/11 3:22 PM EPA Interlab LOS 1315 SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315 SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 131 5 SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab LOS 1315 SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315 SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315 SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315 SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-546
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Si SWA-L05-1315-T01-A 1 7.51E+02
Si SWA-L05-1315-T02-A 1 3.59E+03
Si SWA-L05-1315-T03-A 1 2.52E+03
Si SWA-L05-1315-T04-A 1 6.87E+03
Si SWA-L05-1315-T05-A 1 6.61E+03
Si SWA-L05-1315-T06-A 1 7.82E+03
Si SWA-L05-1315-T07-A 1 7.19E+03
Si SWA-L05-1315-T08-A 1 5.20E+03
Si SWA-L05-1315-T09-A 1 6.79E+03
Si SWA-L05-1315-T01-B 1 6.68E+02
Si SWA-L05-1315-T02-B 1 3.21E+03
Si SWA-L05-1315-T03-B 1 2.62E+03
Si SWA-L05-1315-T04-B 1 7.09E+03
Si SWA-L05-1315-T05-B 1 6.84E+03
Si SWA-L05-1315-T06-B 1 7.93E+03
Si SWA-L05-1315-T07-B 1 7.27E+03
Si SWA-L05-1315-T08-B 1 5.22E+03
Si SWA-L05-1315-T09-B 1 7.00E+03
Si SWA-L05-1315-T01-C 1 1.04E+03
Si SWA-L05-1315-T02-C 1 3.31E+03
Si SWA-L05-1315-T03-C 1 2.66E+03
Si SWA-L05-1315-T04-C 1 7.02E+03
Si SWA-L05-1315-T05-C 1 6.62E+03
Si SWA-L05-1315-T06-C 1 7.88E+03
Si SWA-L05-1315-T07-C 1 7.46E+03
Si SWA-L05-1315-T08-C 1 5.38E+03
Si SWA-L05-1315-T09-C 1 7.04E+03
Si SWA-L05-1315-M01-A 1 5.50E-01 U1/2
Si SWA-L05-1315-M02-A 1 5.50E-01 U1/2
Si SWA-L05-1315-M03-A 1 5.50E-01 U1/2
Si SWA-L05-1315-M04-A 1 5.50E-01 U1/2
Si SWA-L05-1315-M05-A 1 5.50E-01 U1/2
Si SWA-L05-1315-M06-A 1 5.50E-01 U1/2
Si SWA-L05-1315-M07-A 1 5.50E-01 U1/2
Si SWA-L05-1315-M08-A 1 5.50E-01 U1/2
Si SWA-L05-1315-M09-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.51 E+02 0.45 1.10 3.50
3.59E+03 0.18 1.10 3.50
2.52E+03 0.37 1.10 3.50 10000 1000
6.87E+03 1.48 1.10 3.50
6.61 E+03 2.42 1.10 3.50
7.82E+03 0.59 1.10 3.50
7.19E+03 1.35 1.10 3.50
5.20E+03 2.26 1.10 3.50
6.79E+03 1.56 1.10 3.50
6.68E+02 0.42 1.10 3.50
3.21 E+03 0.29 1.10 3.50
2.62E+03 0.67 1.10 3.50 10000 1000
7.09E+03 1.92 1.10 3.50
6.84E+03 0.19 1.10 3.50
7.93E+03 2.30 1.10 3.50
7.27E+03 1.53 1.10 3.50
5.22E+03 1.77 1.10 3.50
7.00E+03 0.67 1.10 3.50
1.04E+03 1.44 1.10 3.50
3.31 E+03 1.09 1.10 3.50
2.66E+03 1.46 1.10 3.50 10000 1000
7.02E+03 1.47 1.10 3.50
6.62E+03 1.64 1.10 3.50
7.88E+03 1.33 1.10 3.50
7.46E+03 1.83 1.10 3.50
5.38E+03 1.28 1.10 3.50
7.04E+03 2.48 1.10 3.50
5.50E-01 4.42 1.10 3.50
5.50E-01 2.64 1.10 3.50
5.50E-01 1.57 1.10 3.50
5.50E-01 1.59 1.10 3.50
5.50E-01 4.64 1.10 3.50
5.50E-01 10.04 1.10 3.50
5.50E-01 25.11 1.10 3.50
5.50E-01 9.71 1.10 3.50
5.50E-01 13.90 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.37E+03 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.44E+03 82% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.49E+03 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab LOS 131 5 SWA
11/16/11 3:22 PM EPA Interlab LOS 1315SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 1315SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab 105 1315SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab 105 1315SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab 105 1315SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-547
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Na SWA-L05-1315-T01-A 1 4.83E+04
Na SWA-L05-1315-T02-A 1 8.23E+04
Na SWA-L05-1315-T03-A 1 5.77E+04
Na SWA-L05-1315-T04-A 1 1.45E+05
Na SWA-L05-1315-T05-A 1 1.21E+05
Na SWA-L05-1315-T06-A 1 1.40E+05
Na SWA-L05-1315-T07-A 1 1.03E+05
Na SWA-L05-1315-T08-A 1 4.52E+04
Na SWA-L05-1315-T09-A 1 7.31E+04
Na SWA-L05-1315-T01-B 1 5.00E+04
Na SWA-L05-1315-T02-B 1 9.17E+04
Na SWA-L05-1315-T03-B 1 5.62E+04
Na SWA-L05-1315-T04-B 1 1.56E+05
Na SWA-L05-1315-T05-B 1 1.29E+05
Na SWA-L05-1315-T06-B 1 1.41E+05
Na SWA-L05-1315-T07-B 1 1.07E+05
Na SWA-L05-1315-T08-B 1 4.77E+04
Na SWA-L05-1315-T09-B 1 7.65E+04
Na SWA-L05-1315-T01-C 1 4.92E+04
Na SWA-L05-1315-T02-C 1 8.53E+04
Na SWA-L05-1315-T03-C 1 5.77E+04
Na SWA-L05-1315-T04-C 1 1.48E+05
Na SWA-L05-1315-T05-C 1 1.29E+05
Na SWA-L05-1315-T06-C 1 1.41E+05
Na SWA-L05-1315-T07-C 1 1.13E+05
Na SWA-L05-1315-T08-C 1 4.98E+04
Na SWA-L05-1315-T09-C 1 7.99E+04
Na SWA-L05-1315-M01-A 1 4.09E+01
Na SWA-L05-1315-M02-A 1 3.21E+01
Na SWA-L05-1315-M03-A 1 2.90E+01
Na SWA-L05-1315-M04-A 1 3.62E+01
Na SWA-L05-1315-M05-A 1 3.85E+01
Na SWA-L05-1315-M06-A 1 2.41E+01
Na SWA-L05-1315-M07-A 1 2.10E+01
Na SWA-L05-1315-M08-A 1 1.70E+01
Na SWA-L05-1315-M09-A 1 1.80E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.83E+04 0.24 2.50 8.00
8.23E+04 1.03 2.50 8.00
5.77E+04 0.46 2.50 8.00 10000 1000
1.45E+05 0.76 2.50 8.00
1.21E+05 0.50 2.50 8.00
1.40E+05 0.32 2.50 8.00
1.03E+05 1.14 2.50 8.00
4.52E+04 0.84 2.50 8.00
7.31 E+04 0.79 2.50 8.00
5.00E+04 0.93 2.50 8.00
9.17E+04 0.23 2.50 8.00
5.62E+04 0.68 2.50 8.00 10000 1000
1.56E+05 0.60 2.50 8.00
1.29E+05 0.09 2.50 8.00
1.41E+05 1.80 2.50 8.00
1.07E+05 0.51 2.50 8.00
4.77E+04 0.30 2.50 8.00
7.65E+04 0.36 2.50 8.00
4.92E+04 0.09 2.50 8.00
8.53E+04 0.93 2.50 8.00
5.77E+04 0.09 2.50 8.00 10000 1000
1.48E+05 0.31 2.50 8.00
1.29E+05 0.25 2.50 8.00
1.41E+05 0.39 2.50 8.00
1.13E+05 0.63 2.50 8.00
4.98E+04 0.64 2.50 8.00
7.99E+04 0.66 2.50 8.00
4.09E+01 0.62 2.50 8.00
3.21 E+01 1.22 2.50 8.00
2.90E+01 1.23 2.50 8.00
3.62E+01 1.86 2.50 8.00
3.85E+01 1.40 2.50 8.00
2.41 E+01 1.24 2.50 8.00
2.10E+01 0.54 2.50 8.00
1.70E+01 2.68 2.50 8.00
1.80E+01 2.99 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.86E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.71E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.86E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab LOS 131 5 SWA
11/16/11 3:22 PM EPA Interlab LOS 1315SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 1315SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab 105 1315SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab 105 1315SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab 105 1315SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-548
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Sr SWA-L05-1315-T01-A 1 4.92E+00
Sr SWA-L05-1315-T02-A 1 1.06E+02
Sr SWA-L05-1315-T03-A 1 9.25E+01
Sr SWA-L05-1315-T04-A 1 1.93E+02
Sr SWA-L05-1315-T05-A 1 2.37E+02
Sr SWA-L05-1315-T06-A 1 1.96E+02
Sr SWA-L05-1315-T07-A 1 2.58E+02
Sr SWA-L05-1315-T08-A 1 2.27E+02
Sr SWA-L05-1315-T09-A 1 2.32E+02
Sr SWA-L05-1315-T01-B 1 6.00E+00
Sr SWA-L05-1315-T02-B 1 1.06E+02
Sr SWA-L05-1315-T03-B 1 9.49E+01
Sr SWA-L05-1315-T04-B 1 1.90E+02
Sr SWA-L05-1315-T05-B 1 2.36E+02
Sr SWA-L05-1315-T06-B 1 2.01E+02
Sr SWA-L05-1315-T07-B 1 2.33E+02
Sr SWA-L05-1315-T08-B 1 2.20E+02
Sr SWA-L05-1315-T09-B 1 2.26E+02
Sr SWA-L05-1315-T01-C 1 5.18E+00
Sr SWA-L05-1315-T02-C 1 1.22E+02
Sr SWA-L05-1315-T03-C 1 1.16E+02
Sr SWA-L05-1315-T04-C 1 2.24E+02
Sr SWA-L05-1315-T05-C 1 2.47E+02
Sr SWA-L05-1315-T06-C 1 2.03E+02
Sr SWA-L05-1315-T07-C 1 2.02E+02
Sr SWA-L05-1315-T08-C 1 2.02E+02
Sr SWA-L05-1315-T09-C 1 2.68E+02
Sr SWA-L05-1315-M01-A 1 5.00E-01 U1/2
Sr SWA-L05-1315-M02-A 1 5.00E-01 U1/2
Sr SWA-L05-1315-M03-A 1 5.00E-01 U1/2
Sr SWA-L05-1315-M04-A 1 5.00E-01 U1/2
Sr SWA-L05-1315-M05-A 1 5.00E-01 U1/2
Sr SWA-L05-1315-M06-A 1 5.00E-01 U1/2
Sr SWA-L05-1315-M07-A 1 5.00E-01 U1/2
Sr SWA-L05-1315-M08-A 1 5.00E-01 U1/2
Sr SWA-L05-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.92E+00 18.41 1.00 3.18
1.06E+02 1.96 1.00 3.18
9.25E+01 0.85 1.00 3.18 10000 1000
1.93E+02 0.55 1.00 3.18
2.37E+02 2.73 1.00 3.18
1.96E+02 1.89 1.00 3.18
2.58E+02 0.94 1.00 3.18
2.27E+02 1.13 1.00 3.18
2.32E+02 1.24 1.00 3.18
6.00E+00 1.12 1.00 3.18
1.06E+02 0.70 1.00 3.18
9.49E+01 1.51 1.00 3.18 10000 1000
1.90E+02 2.60 1.00 3.18
2.36E+02 1.36 1.00 3.18
2.01E+02 2.03 1.00 3.18
2.33E+02 2.16 1.00 3.18
2.20E+02 0.50 1.00 3.18
2.26E+02 1.29 1.00 3.18
5.18E+00 2.22 1.00 3.18
1.22E+02 2.20 1.00 3.18
1.16E+02 1.10 1.00 3.18 10000 1000
2.24E+02 1.52 1.00 3.18
2.47E+02 1.63 1.00 3.18
2.03E+02 0.64 1.00 3.18
2.02E+02 1.78 1.00 3.18
2.02E+02 0.72 1.00 3.18
2.68E+02 3.40 1.00 3.18
5.00E-01 20.77 1.00 3.18
5.00E-01 31.31 1.00 3.18
5.00E-01 26.60 1.00 3.18
5.00E-01 34.95 1.00 3.18
5.00E-01 9.63 1.00 3.18
5.00E-01 33.12 1.00 3.18
5.00E-01 32.60 1.00 3.18
5.00E-01 12.23 1.00 3.18
5.00E-01 9.02 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.59E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.93E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab 105 1315SWA
11/16/11 3:22 PM EPA Interlab LOS 1315 SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315 SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 131 5 SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab LOS 1315 SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315 SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315 SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315 SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-549
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
S SWA-L05-1315-T01-A 1 8.79E+03
S SWA-L05-1315-T02-A 1 1.33E+04
S SWA-L05-1315-T03-A 1 6.86E+03
S SWA-L05-1315-T04-A 1 1.97E+04
S SWA-L05-1315-T05-A 1 1.41E+04
S SWA-L05-1315-T06-A 1 1.70E+04
S SWA-L05-1315-T07-A 1 1.16E+04
S SWA-L05-1315-T08-A 1 3.70E+03
S SWA-L05-1315-T09-A 1 7.12E+03
S SWA-L05-1315-T01-B 1 9.74E+03
S SWA-L05-1315-T02-B 1 1.20E+04
S SWA-L05-1315-T03-B 1 6.28E+03
S SWA-L05-1315-T04-B 1 1.95E+04
S SWA-L05-1315-T05-B 1 1.44E+04
S SWA-L05-1315-T06-B 1 1.81E+04
S SWA-L05-1315-T07-B 1 1.16E+04
S SWA-L05-1315-T08-B 1 4.39E+03
S SWA-L05-1315-T09-B 1 8.37E+03
S SWA-L05-1315-T01-C 1 9.47E+03
S SWA-L05-1315-T02-C 1 1.32E+04
S SWA-L05-1315-T03-C 1 6.82E+03
S SWA-L05-1315-T04-C 1 2.19E+04
S SWA-L05-1315-T05-C 1 1.31E+04
S SWA-L05-1315-T06-C 1 1.70E+04
S SWA-L05-1315-T07-C 1 1.08E+04
S SWA-L05-1315-T08-C 1 4.61E+03
S SWA-L05-1315-T09-C 1 9.56E+03
S SWA-L05-1315-M01-A 1 3.95E+01
S SWA-L05-1315-M02-A 1 3.82E+01
S SWA-L05-1315-M03-A 1 3.26E+01
S SWA-L05-1315-M04-A 1 2.46E+01
S SWA-L05-1315-M05-A 1 2.61E+01
S SWA-L05-1315-M06-A 1 2.69E+01
S SWA-L05-1315-M07-A 1 2.55E+01
S SWA-L05-1315-M08-A 1 2.05E+01 E
S SWA-L05-1315-M09-A 1 2.15E+01 E
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.79E+03 0.21 6.80 21.60
1.33E+04 1.99 6.80 21.60
6.86E+03 1.45 6.80 21.60 10000 1000
1.97E+04 1.19 6.80 21.60
1.41E+04 2.48 6.80 21.60
1.70E+04 1.45 6.80 21.60
1.16E+04 0.93 6.80 21.60
3.70E+03 1.81 6.80 21.60
7.12E+03 1.43 6.80 21.60
9.74E+03 0.77 6.80 21.60
1.20E+04 1.19 6.80 21.60
6.28E+03 0.26 6.80 21.60 10000 1000
1.95E+04 2.34 6.80 21.60
1.44E+04 1.20 6.80 21.60
1.81E+04 1.10 6.80 21.60
1.16E+04 1.82 6.80 21.60
4.39E+03 1.00 6.80 21.60
8.37E+03 1.86 6.80 21.60
9.47E+03 0.82 6.80 21.60
1.32E+04 1.74 6.80 21.60
6.82E+03 1.67 6.80 21.60 10000 1000
2.19E+04 1.62 6.80 21.60
1.31E+04 1.29 6.80 21.60
1.70E+04 1.69 6.80 21.60
1.08E+04 0.28 6.80 21.60
4.61E+03 1.85 6.80 21.60
9.56E+03 2.65 6.80 21.60
3.95E+01 1.68 6.80 21.60
3.82E+01 5.58 6.80 21.60
3.26E+01 5.35 6.80 21.60
2.46E+01 1.68 6.80 21.60
2.61E+01 5.72 6.80 21.60
2.69E+01 1.13 6.80 21.60
2.55E+01 7.73 6.80 21.60
2.05E+01 9.03 6.80 21.60
2.15E+01 3.12 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
7.75E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.15E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.75E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab 105 1315SWA
11/16/11 3:22 PM EPA Interlab LOS 1315 SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315 SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 131 5 SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab LOS 1315 SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315 SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315 SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315 SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-550
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Tl SWA-L05-1315-T01-A 1 2.30E+00 U1/2
Tl SWA-L05-1315-T02-A 1 2.30E+00 U1/2
Tl SWA-L05-1315-T03-A 1 2.30E+00 U1/2
Tl SWA-L05-1315-T04-A 1 2.30E+00 U1/2
Tl SWA-L05-1315-T05-A 1 2.30E+00 U1/2
Tl SWA-L05-1315-T06-A 1 2.30E+00 U1/2
Tl SWA-L05-1315-T07-A 1 2.30E+00 U1/2
Tl SWA-L05-1315-T08-A 1 2.30E+00 U1/2
Tl SWA-L05-1315-T09-A 1 2.30E+00 U1/2
Tl SWA-L05-1315-T01-B 1 2.30E+00 U1/2
Tl SWA-L05-1315-T02-B 1 2.30E+00 U1/2
Tl SWA-L05-1315-T03-B 1 2.30E+00 U1/2
Tl SWA-L05-1315-T04-B 1 2.30E+00 U1/2
Tl SWA-L05-1315-T05-B 1 2.30E+00 U1/2
Tl SWA-L05-1315-T06-B 1 2.30E+00 U1/2
Tl SWA-L05-1315-T07-B 1 2.30E+00 U1/2
Tl SWA-L05-1315-T08-B 1 2.30E+00 U1/2
Tl SWA-L05-1315-T09-B 1 2.30E+00 U1/2
Tl SWA-L05-1315-T01-C 1 2.30E+00 U1/2
Tl SWA-L05-1315-T02-C 1 2.30E+00 U1/2
Tl SWA-L05-1315-T03-C 1 2.30E+00 U1/2
Tl SWA-L05-1315-T04-C 1 2.30E+00 U1/2
Tl SWA-L05-1315-T05-C 1 2.30E+00 U1/2
Tl SWA-L05-1315-T06-C 1 2.30E+00 U1/2
Tl SWA-L05-1315-T07-C 1 2.30E+00 U1/2
Tl SWA-L05-1315-T08-C 1 2.30E+00 U1/2
Tl SWA-L05-1315-T09-C 1 2.30E+00 U1/2
Tl SWA-L05-1315-M01-A 1 2.30E+00 U1/2
Tl SWA-L05-1315-M02-A 1 2.30E+00 U1/2
Tl SWA-L05-1315-M03-A 1 2.30E+00 U1/2
Tl SWA-L05-1315-M04-A 1 2.30E+00 U1/2
Tl SWA-L05-1315-M05-A 1 2.30E+00 U1/2
Tl SWA-L05-1315-M06-A 1 2.30E+00 U1/2
Tl SWA-L05-1315-M07-A 1 2.30E+00 U1/2
Tl SWA-L05-1315-M08-A 1 2.30E+00 U1/2
Tl SWA-L05-1315-M09-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 25.79 4.60 14.60
2.30E+00 12.65 4.60 14.60
2.30E+00 45.48 4.60 14.60 10000 1000
2.30E+00 63.09 4.60 14.60
2.30E+00 18.84 4.60 14.60
2.30E+00 67.00 4.60 14.60
2.30E+00 14.21 4.60 14.60
2.30E+00 85.23 4.60 14.60
2.30E+00 44.28 4.60 14.60
2.30E+00 25.66 4.60 14.60
2.30E+00 41.80 4.60 14.60
2.30E+00 42.58 4.60 14.60 10000 1000
2.30E+00 72.34 4.60 14.60
2.30E+00 33.42 4.60 14.60
2.30E+00 72.35 4.60 14.60
2.30E+00 46.65 4.60 14.60
2.30E+00 41.38 4.60 14.60
2.30E+00 20.71 4.60 14.60
2.30E+00 6.60 4.60 14.60
2.30E+00 42.79 4.60 14.60
2.30E+00 54.56 4.60 14.60 10000 1000
2.30E+00 81.31 4.60 14.60
2.30E+00 26.20 4.60 14.60
2.30E+00 26.72 4.60 14.60
2.30E+00 38.74 4.60 14.60
2.30E+00 77.89 4.60 14.60
2.30E+00 83.14 4.60 14.60
2.30E+00 70.13 4.60 14.60
2.30E+00 6.64 4.60 14.60
2.30E+00 12.01 4.60 14.60
2.30E+00 54.67 4.60 14.60
2.30E+00 74.55 4.60 14.60
2.30E+00 48.44 4.60 14.60
2.30E+00 68.67 4.60 14.60
2.30E+00 13.19 4.60 14.60
2.30E+00 62.36 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.88E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.93E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.13E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab 105 1315SWA
11/16/11 3:22 PM EPA Interlab LOS 1315SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315 SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 1315 SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab LOS 1315 SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315 SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315 SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315 SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-551
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Ti SWA-L05-1315-T01-A 1 1.00E+00 U1/2
Ti SWA-L05-1315-T02-A 1 1.00E+00 U1/2
Ti SWA-L05-1315-T03-A 1 1.00E+00 U1/2
Ti SWA-L05-1315-T04-A 1 1.00E+00 U1/2
Ti SWA-L05-1315-T05-A 1 1.00E+00 U1/2
Ti SWA-L05-1315-T06-A 1 1.00E+00 U1/2
Ti SWA-L05-1315-T07-A 1 1.00E+00 U1/2
Ti SWA-L05-1315-T08-A 1 1.00E+00 U1/2
Ti SWA-L05-1315-T09-A 1 1.00E+00 U1/2
Ti SWA-L05-1315-T01-B 1 1.00E+00 U1/2
Ti SWA-L05-1315-T02-B 1 1.00E+00 U1/2
Ti SWA-L05-1315-T03-B 1 1.00E+00 U1/2
Ti SWA-L05-1315-T04-B 1 1.00E+00 U1/2
Ti SWA-L05-1315-T05-B 1 1.00E+00 U1/2
Ti SWA-L05-1315-T06-B 1 1.00E+00 U1/2
Ti SWA-L05-1315-T07-B 1 1.00E+00 U1/2
Ti SWA-L05-1315-T08-B 1 1.00E+00 U1/2
Ti SWA-L05-1315-T09-B 1 1.00E+00 U1/2
Ti SWA-L05-1315-T01-C 1 1.00E+00 U1/2
Ti SWA-L05-1315-T02-C 1 1.00E+00 U1/2
Ti SWA-L05-1315-T03-C 1 1.00E+00 U1/2
Ti SWA-L05-1315-T04-C 1 1.00E+00 U1/2
Ti SWA-L05-1315-T05-C 1 1.00E+00 U1/2
Ti SWA-L05-1315-T06-C 1 1.00E+00 U1/2
Ti SWA-L05-1315-T07-C 1 1.00E+00 U1/2
Ti SWA-L05-1315-T08-C 1 1.00E+00 U1/2
Ti SWA-L05-1315-T09-C 1 1.00E+00 U1/2
Ti SWA-L05-1315-M01-A 1 1.00E+00 U1/2
Ti SWA-L05-1315-M02-A 1 1.00E+00 U1/2
Ti SWA-L05-1315-M03-A 1 1.00E+00 U1/2
Ti SWA-L05-1315-M04-A 1 1.00E+00 U1/2
Ti SWA-L05-1315-M05-A 1 1.00E+00 U1/2
Ti SWA-L05-1315-M06-A 1 1.00E+00 U1/2
Ti SWA-L05-1315-M07-A 1 1.00E+00 U1/2
Ti SWA-L05-1315-M08-A 1 1.00E+00 U1/2
Ti SWA-L05-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 6.11 2.00 6.40
1.00E+00 26.72 2.00 6.40
1.00E+00 10.69 2.00 6.40 10000 1000
1.00E+00 25.28 2.00 6.40
1.00E+00 13.85 2.00 6.40
1.00E+00 18.60 2.00 6.40
1.00E+00 26.34 2.00 6.40
1.00E+00 14.54 2.00 6.40
1.00E+00 12.56 2.00 6.40
1.00E+00 12.93 2.00 6.40
1.00E+00 38.61 2.00 6.40
1.00E+00 27.32 2.00 6.40 10000 1000
1.00E+00 25.81 2.00 6.40
1.00E+00 12.42 2.00 6.40
1.00E+00 14.98 2.00 6.40
1.00E+00 24.21 2.00 6.40
1.00E+00 24.19 2.00 6.40
1.00E+00 13.81 2.00 6.40
1.00E+00 5.55 2.00 6.40
1.00E+00 13.77 2.00 6.40
1.00E+00 16.81 2.00 6.40 10000 1000
1.00E+00 18.56 2.00 6.40
1.00E+00 40.52 2.00 6.40
1.00E+00 20.24 2.00 6.40
1.00E+00 21.87 2.00 6.40
1.00E+00 21.90 2.00 6.40
1.00E+00 8.38 2.00 6.40
1.00E+00 1.73 2.00 6.40
1.00E+00 23.33 2.00 6.40
1.00E+00 14.62 2.00 6.40
1.00E+00 9.72 2.00 6.40
1.00E+00 9.08 2.00 6.40
1.00E+00 29.92 2.00 6.40
1.00E+00 6.08 2.00 6.40
1.00E+00 17.57 2.00 6.40
1.00E+00 30.68 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.34E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.48E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.75E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab LOS 1315 SWA
11/16/11 3:22 PM EPA Interlab LOS 1315SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 1315SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab 105 1315SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab 105 1315SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab 105 1315SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-552
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
V SWA-L05-1315-T01-A 1 1.10E+01
V SWA-L05-1315-T02-A 1 1.89E+01
V SWA-L05-1315-T03-A 1 6.03E+00
V SWA-L05-1315-T04-A 1 2.25E+01
V SWA-L05-1315-T05-A 1 1.71E+01
V SWA-L05-1315-T06-A 1 1.99E+01
V SWA-L05-1315-T07-A 1 1.58E+01
V SWA-L05-1315-T08-A 1 9.27E+00
V SWA-L05-1315-T09-A 1 1.46E+01
V SWA-L05-1315-T01-B 1 1.24E+01
V SWA-L05-1315-T02-B 1 1.83E+01
V SWA-L05-1315-T03-B 1 6.07E+00
V SWA-L05-1315-T04-B 1 2.19E+01
V SWA-L05-1315-T05-B 1 1.83E+01
V SWA-L05-1315-T06-B 1 2.10E+01
V SWA-L05-1315-T07-B 1 1.70E+01
V SWA-L05-1315-T08-B 1 1.01E+01
V SWA-L05-1315-T09-B 1 1.59E+01
V SWA-L05-1315-T01-C 1 1.40E+01
V SWA-L05-1315-T02-C 1 1.56E+01
V SWA-L05-1315-T03-C 1 7.63E+00
V SWA-L05-1315-T04-C 1 2.20E+01
V SWA-L05-1315-T05-C 1 1.88E+01
V SWA-L05-1315-T06-C 1 2.03E+01
V SWA-L05-1315-T07-C 1 1.73E+01
V SWA-L05-1315-T08-C 1 9.74E+00
V SWA-L05-1315-T09-C 1 1.56E+01
V SWA-L05-1315-M01-A 1 7.50E-01 U1/2
V SWA-L05-1315-M02-A 1 7.50E-01 U1/2
V SWA-L05-1315-M03-A 1 7.50E-01 U1/2
V SWA-L05-1315-M04-A 1 7.50E-01 U1/2
V SWA-L05-1315-M05-A 1 7.50E-01 U1/2
V SWA-L05-1315-M06-A 1 7.50E-01 U1/2
V SWA-L05-1315-M07-A 1 7.50E-01 U1/2
V SWA-L05-1315-M08-A 1 7.50E-01 U1/2
V SWA-L05-1315-M09-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+01 1.19 1.50 4.77
1.89E+01 11.67 1.50 4.77
6.03E+00 1.96 1.50 4.77 10000 1000
2.25E+01 8.13 1.50 4.77
1.71E+01 6.78 1.50 4.77
1.99E+01 3.78 1.50 4.77
1.58E+01 2.68 1.50 4.77
9.27E+00 5.15 1.50 4.77
1.46E+01 8.33 1.50 4.77
1.24E+01 0.71 1.50 4.77
1.83E+01 1.40 1.50 4.77
6.07E+00 9.76 1.50 4.77 10000 1000
2.19E+01 3.76 1.50 4.77
1.83E+01 5.82 1.50 4.77
2.10E+01 7.51 1.50 4.77
1.70E+01 5.03 1.50 4.77
1.01E+01 8.66 1.50 4.77
1.59E+01 4.47 1.50 4.77
1.40E+01 3.49 1.50 4.77
1.56E+01 2.32 1.50 4.77
7.63E+00 1.02 1.50 4.77 10000 1000
2.20E+01 1.88 1.50 4.77
1.88E+01 6.64 1.50 4.77
2.03E+01 3.95 1.50 4.77
1.73E+01 4.56 1.50 4.77
9.74E+00 2.85 1.50 4.77
1.56E+01 5.84 1.50 4.77
7.50E-01 52.92 1.50 4.77
7.50E-01 34.27 1.50 4.77
7.50E-01 46.39 1.50 4.77
7.50E-01 41.93 1.50 4.77
7.50E-01 44.24 1.50 4.77
7.50E-01 37.29 1.50 4.77
7.50E-01 33.47 1.50 4.77
7.50E-01 54.79 1.50 4.77
7.50E-01 14.56 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.14E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.36E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.57E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab 105 1315SWA
11/16/11 3:22 PM EPA Interlab LOS 1315 SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315 SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 131 5 SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315 SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab LOS 1315 SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315 SWA
11/16/11 3:54 PM EPA Interlab LOS 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315 SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315 SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab LOS 1315 SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315 SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-553
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Zn SWA-L05-1315-T01-A 1 2.68E+00 E
Zn SWA-L05-1315-T02-A 1 2.87E+00 E
Zn SWA-L05-1315-T03-A 1 2.82E+00 E
Zn SWA-L05-1315-T04-A 1 2.11E+OOE
Zn SWA-L05-1315-T05-A 1 1.98E+00 E
Zn SWA-L05-1315-T06-A 1 5.00E-01 U1/2
Zn SWA-L05-1315-T07-A 1 5.00E-01 U1/2
Zn SWA-L05-1315-T08-A 1 5.00E-01 U1/2
Zn SWA-L05-1315-T09-A 1 1.12E+00 E
Zn SWA-L05-1315-T01-B 1 3.82E+00
Zn SWA-L05-1315-T02-B 1 2.88E+00 E
Zn SWA-L05-1315-T03-B 1 3.14E+00 E
Zn SWA-L05-1315-T04-B 1 2.19E+00 E
Zn SWA-L05-1315-T05-B 1 2.19E+00 E
Zn SWA-L05-1315-T06-B 1 5.00E-01 U1/2
Zn SWA-L05-1315-T07-B 1 5.00E-01 U1/2
Zn SWA-L05-1315-T08-B 1 5.00E-01 U1/2
Zn SWA-L05-1315-T09-B 1 1.50E+00 E
Zn SWA-L05-1315-T01-C 1 3.42E+00
Zn SWA-L05-1315-T02-C 1 2.93E+00 E
Zn SWA-L05-1315-T03-C 1 2.55E+00 E
Zn SWA-L05-1315-T04-C 1 2.80E+00 E
Zn SWA-L05-1315-T05-C 1 2.38E+00 E
Zn SWA-L05-1315-T06-C 1 5.00E-01 U1/2
Zn SWA-L05-1315-T07-C 1 5.00E-01 U1/2
Zn SWA-L05-1315-T08-C 1 5.00E-01 U1/2
Zn SWA-L05-1315-T09-C 1 1.62E+00 E
Zn SWA-L05-1315-M01-A 1 5.00E-01 U1/2
Zn SWA-L05-1315-M02-A 1 5.00E-01 U1/2
Zn SWA-L05-1315-M03-A 1 5.00E-01 U1/2
Zn SWA-L05-1315-M04-A 1 5.00E-01 U1/2
Zn SWA-L05-1315-M05-A 1 5.00E-01 U1/2
Zn SWA-L05-1315-M06-A 1 5.00E-01 U1/2
Zn SWA-L05-1315-M07-A 1 5.00E-01 U1/2
Zn SWA-L05-1315-M08-A 1 5.00E-01 U1/2
Zn SWA-L05-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.68E+00 7.88 1.00 3.18
2.87E+00 12.65 1.00 3.18
2.82E+00 2.53 1.00 3.18 10000 1000
2.11E+00 5.52 1.00 3.18
1.98E+00 3.09 1.00 3.18
5.00E-01 14.10 1.00 3.18
5.00E-01 3.21 1.00 3.18
5.00E-01 7.36 1.00 3.18
1.12E+00 11.47 1.00 3.18
3.82E+00 2.18 1.00 3.18
2.88E+00 3.13 1.00 3.18
3.14E+00 6.22 1.00 3.18 10000 1000
2.19E+00 11.19 1.00 3.18
2.19E+00 6.54 1.00 3.18
5.00E-01 3.92 1.00 3.18
5.00E-01 11.83 1.00 3.18
5.00E-01 12.51 1.00 3.18
1.50E+00 8.16 1.00 3.18
3.42E+00 4.73 1.00 3.18
2.93E+00 5.45 1.00 3.18
2.55E+00 4.79 1.00 3.18 10000 1000
2.80E+00 2.85 1.00 3.18
2.38E+00 12.04 1.00 3.18
5.00E-01 14.48 1.00 3.18
5.00E-01 5.97 1.00 3.18
5.00E-01 0.94 1.00 3.18
1.62E+00 2.60 1.00 3.18
5.00E-01 5.78 1.00 3.18
5.00E-01 2.46 1.00 3.18
5.00E-01 3.90 1.00 3.18
5.00E-01 8.00 1.00 3.18
5.00E-01 6.96 1.00 3.18
5.00E-01 1.38 1.00 3.18
5.00E-01 4.23 1.00 3.18
5.00E-01 3.99 1.00 3.18
5.00E-01 17.52 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.20E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.36E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.58E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/16/11 3:17 PM EPA Interlab LOS 1315SWA
11/16/11 3:19 PM EPA Interlab L05 1315 SWA
11/16/11 3:21 PM EPA Interlab LOS 1315 SWA
11/16/11 3:22 PM EPA Interlab LOS 1315SWA
11/16/11 3:24 PM EPA Interlab LOS 1315 SWA
11/16/11 3:26 PM EPA Interlab LOS 1315 SWA
11/16/11 3:27 PM EPA Interlab 105 1315SWA
11/16/11 3:29 PM EPA Interlab LOS 1315 SWA
11/16/11 3:31 PM EPA Interlab LOS 1315SWA
11/16/11 3:39 PM EPA Interlab LOS 1315 SWA
11/16/11 3:40 PM EPA Interlab LOS 1315 SWA
11/16/11 3:42 PM EPA Interlab LOS 1315SWA
11/16/11 3:44 PM EPA Interlab LOS 1315 SWA
11/16/11 3:45 PM EPA Interlab LOS 1315 SWA
11/16/11 3:47 PM EPA Interlab 105 1315SWA
11/16/11 3:49 PM EPA Interlab LOS 1315 SWA
11/16/11 3:50 PM EPA Interlab LOS 1315 SWA
11/16/11 3:52 PM EPA Interlab LOS 1315 SWA
11/16/11 3:54 PM EPA Interlab 105 1315 SWA
11/16/11 3:55 PM EPA Interlab LOS 1315 SWA
11/16/11 3:57 PM EPA Interlab LOS 1315SWA
11/16/11 3:58 PM EPA Interlab LOS 1315 SWA
11/16/11 4:00 PM EPA Interlab LOS 1315 SWA
11/16/11 4:02 PM EPA Interlab LOS 1315SWA
11/16/11 4:03 PM EPA Interlab LOS 1315 SWA
11/16/11 4:05 PM EPA Interlab LOS 1315 SWA
11/16/11 4:07 PM EPA Interlab 105 1315SWA
11/16/11 3:03 PM EPA Interlab LOS 1315 SWA
11/16/11 3:04 PM EPA Interlab LOS 1315 SWA
11/16/11 3:06 PM EPA Interlab LOS 1315 SWA
11/16/11 3:07 PM EPA Interlab 105 1315SWA
11/16/11 3:09 PM EPA Interlab LOS 1315 SWA
11/16/11 3:11 PM EPA Interlab LOS 1315 SWA
11/16/11 3:12 PM EPA Interlab LOS 1315SWA
11/16/11 3:14 PM EPA Interlab LOS 1315 SWA
11/16/11 3:16 PM EPA Interlab LOS 1315 SWA
1-554
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1315:
Element Sample ID
Al SWA-L06-1315-T01-A
Al SWA-L06-1315-T02-A
Al SWA-L06-1315-T03-A
Al SWA-L06-1315-T04-A
Al SWA-L06-1315-T05-A
Al SWA-L06-1315-T06-A
Al SWA-L06-1315-T07-A
Al SWA-L06-1315-T08-A
Al SWA-L06-1315-T09-A
Al SWA-L06-1315-T01-B
Al SWA-L06-1315-T02-B
Al SWA-L06-1315-T03-B
Al SWA-L06-1315-T04-B
Al SWA-L06-1315-T05-B
Al SWA-L06-1315-T06-B
Al SWA-L06-1315-T07-B
Al SWA-L06-1315-T08-B
Al SWA-L06-1315-T09-B
Al SWA-L06-1315-T01-C
Al SWA-L06-1315-T02-C
Al SWA-L06-1315-T03-C
Al SWA-L06-1315-T04-C
Al SWA-L06-1315-T05-C
Al SWA-L06-1315-T06-C
Al SWA-L06-1315-T07-C
Al SWA-L06-1315-T08-C
Al SWA-L06-1315-T09-C
Al SWA-L06-1315-M01-A
Al SWA-L06-1315-M02-A
Al SWA-L06-1315-M03-A
Al SWA-L06-1315-M04-A
Al SWA-L06-1315-M05-A
Al SWA-L06-1315-M06-A
Al SWA-L06-1315-M07-A
Al SWA-L06-1315-M08-A
Al SWA-L06-1315-M09-A
Dilution Sample
Factor Cone. Qualifier
I ug/L I
1 1.00E+03
1 4.49E+03
1 2.58E+03
1 5.79E+03
1 4.99E+03
1 5.77E+03
1 4.53E+03
1 2.81 E+03
1 3.69E+03
1 9.15E+02
1 3.77E+03
1 2.60E+03
1 5.55E+03
1 4.91 E+03
1 5.69E+03
1 4.69E+03
1 2.69E+03
1 3.52E+03
1 8.77E+02
1 3.78E+03
1 2.53E+03
1 6.44E+03
1 5.20E+03
1 6.15E+03
1 4.38E+03
1 2.84E+03
1 3.81 E+03
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+03 1.82 1.00 3.18
4.49E+03 1.08 1.00 3.18
2.58E+03 1.07 1.00 3.18 10000 1000
5.79E+03 1.23 1.00 3.18
4.99E+03 2.49 1.00 3.18
5.77E+03 1.79 1.00 3.18
4.53E+03 0.40 1.00 3.18
2.81E+03 0.90 1.00 3.18
3.69E+03 0.76 1.00 3.18
9.15E+02 2.82 1.00 3.18
3.77E+03 0.54 1.00 3.18
2.60E+03 1.03 1.00 3.18 10000 1000
5.55E+03 0.77 1.00 3.18
4.91E+03 0.34 1.00 3.18
5.69E+03 0.19 1.00 3.18
4.69E+03 0.70 1.00 3.18
2.69E+03 1.01 1.00 3.18
3.52E+03 0.77 1.00 3.18
8.77E+02 2.58 1.00 3.18
3.78E+03 0.95 1.00 3.18
2.53E+03 1.47 1.00 3.18 10000 1000
6.44E+03 1.21 1.00 3.18
5.20E+03 0.62 1.00 3.18
6.15E+03 1.28 1.00 3.18
4.38E+03 1.92 1.00 3.18
2.84E+03 2.73 1.00 3.18
3.81E+03 1.23 1.00 3.18
5.00E-01 8.90 1.00 3.18
5.00E-01 13.97 1.00 3.18
5.00E-01 3.40 1.00 3.18
5.00E-01 6.83 1.00 3.18
5.00E-01 12.04 1.00 3.18
5.00E-01 12.20 1.00 3.18
5.00E-01 11.25 1.00 3.18
5.00E-01 3.63 1.00 3.18
5.00E-01 6.37 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.51 E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.47E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.46E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/2011 11:37 EPA Interlab L06 1315SWA
6/16/2011 11:39 EPA Interlab L06 1315SWA
6/16/2011 11:41 EPA Interlab L06 1315 SWA
6/16/2011 11:42 EPA Interlab L06 1315SWA
6/16/2011 11:44 EPA Interlab L06 1315SWA
6/16/2011 11:46 EPA Interlab L06 1315SWA
6/16/2011 11:47 EPA Interlab L06 1315SWA
6/16/2011 11:49 EPA Interlab L06 1315SWA
6/16/2011 11:51 EPA Interlab L06 1315SWA
6/16/2011 11:57 EPA Interlab L06 1315SWA
6/16/2011 11:59 EPA Interlab L06 1315SWA
6/16/2011 12:00 EPA Interlab L06 1315 SWA
6/16/2011 12:02 EPA Interlab L06 1315 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/2011 12:07 EPA Interlab L06 1315 SWA
6/16/2011 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:14 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:18 EPA Interlab L06 1315 SWA
6/16/2011 12:20 EPA Interlab L06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25 EPA Interlab L06 1315 SWA
6/16/2011 11:23 EPA Interlab L06 1315 SWA
6/16/2011 11:24 EPA Interlab L06 1315 SWA
6/16/2011 11:26 EPA Interlab L06 1315 SWA
6/16/2011 11:28 EPA Interlab L06 1315 SWA
6/16/2011 11:29 EPA Interlab L06 1315 SWA
6/16/2011 11:31 EPA Interlab L06 1315 SWA
6/16/2011 11:32 EPA Interlab L06 1315 SWA
6/16/2011 11:34 EPA Interlab L06 1315 SWA
6/16/2011 11:36 EPA Interlab L06 1315 SWA
1-555
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Sb SWA-L06-1315-T01-A 1 1.73E+02
Sb SWA-L06-1315-T02-A 1 4.51E+02
Sb SWA-L06-1315-T03-A 1 2.02E+02
Sb SWA-L06-1315-T04-A 1 4.67E+02
Sb SWA-L06-1315-T05-A 1 3.78E+02
Sb SWA-L06-1315-T06-A 1 4.30E+02
Sb SWA-L06-1315-T07-A 1 3.17E+02
Sb SWA-L06-1315-T08-A 1 1.98E+02
Sb SWA-L06-1315-T09-A 1 2.48E+02
Sb SWA-L06-1315-T01-B 1 1.89E+02
Sb SWA-L06-1315-T02-B 1 4.11E+02
Sb SWA-L06-1315-T03-B 1 2.05E+02
Sb SWA-L06-1315-T04-B 1 4.65E+02
Sb SWA-L06-1315-T05-B 1 3.81E+02
Sb SWA-L06-1315-T06-B 1 4.35E+02
Sb SWA-L06-1315-T07-B 1 3.71E+02
Sb SWA-L06-1315-T08-B 1 1.86E+02
Sb SWA-L06-1315-T09-B 1 2.49E+02
Sb SWA-L06-1315-T01-C 1 1.77E+02
Sb SWA-L06-1315-T02-C 1 5.38E+02
Sb SWA-L06-1315-T03-C 1 2.90E+02
Sb SWA-L06-1315-T04-C 1 6.97E+02
Sb SWA-L06-1315-T05-C 1 4.93E+02
Sb SWA-L06-1315-T06-C 1 5.40E+02
Sb SWA-L06-1315-T07-C 1 3.11E+02
Sb SWA-L06-1315-T08-C 1 2.11E+02
Sb SWA-L06-1315-T09-C 1 2.78E+02
Sb SWA-L06-1315-M01-A 1 3.75E+00 U1/2
Sb SWA-L06-1315-M02-A 1 3.75E+00 U1/2
Sb SWA-L06-1315-M03-A 1 3.75E+00 U1/2
Sb SWA-L06-1315-M04-A 1 3.75E+00 U1/2
Sb SWA-L06-1315-M05-A 1 3.75E+00 U1/2
Sb SWA-L06-1315-M06-A 1 3.75E+00 U1/2
Sb SWA-L06-1315-M07-A 1 3.75E+00 U1/2
Sb SWA-L06-1315-M08-A 1 3.75E+00 U1/2
Sb SWA-L06-1315-M09-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.73E+02 1.97 7.50 23.90
4.51 E+02 0.79 7.50 23.90
2.02E+02 3.94 7.50 23.90 10000 1000
4.67E+02 2.39 7.50 23.90
3.78E+02 2.98 7.50 23.90
4.30E+02 1.94 7.50 23.90
3.17E+02 1.92 7.50 23.90
1.98E+02 1.06 7.50 23.90
2.48E+02 2.58 7.50 23.90
1.89E+02 6.28 7.50 23.90
4.11E+02 1.87 7.50 23.90
2.05E+02 3.65 7.50 23.90 10000 1000
4.65E+02 1.28 7.50 23.90
3.81E+02 2.74 7.50 23.90
4.35E+02 2.95 7.50 23.90
3.71E+02 5.44 7.50 23.90
1.86E+02 1.65 7.50 23.90
2.49E+02 2.45 7.50 23.90
1.77E+02 0.94 7.50 23.90
5.38E+02 3.61 7.50 23.90
2.90E+02 2.38 7.50 23.90 10000 1000
6.97E+02 0.69 7.50 23.90
4.93E+02 2.24 7.50 23.90
5.40E+02 0.77 7.50 23.90
3.11E+02 4.06 7.50 23.90
2.11E+02 9.75 7.50 23.90
2.78E+02 2.12 7.50 23.90
3.75E+00 11.79 7.50 23.90
3.75E+00 11.90 7.50 23.90
3.75E+00 14.81 7.50 23.90
3.75E+00 38.79 7.50 23.90
3.75E+00 85.85 7.50 23.90
3.75E+00 33.90 7.50 23.90
3.75E+00 20.12 7.50 23.90
3.75E+00 82.16 7.50 23.90
3.75E+00 44.82 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.22E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.28E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/2011 11:37 EPA Interlab L06 1315SWA
6/16/2011 11:39 EPA Interlab L06 1315SWA
6/16/2011 11:41 EPA Interlab L06 1315 SWA
6/16/2011 11:42 EPA Interlab L06 1315 SWA
6/16/2011 11:44 EPA Interlab L06 1315 SWA
6/16/2011 11:46 EPA Interlab L06 1315 SWA
6/16/2011 11:47 EPA Interlab L06 1315 SWA
6/16/2011 11:49 EPA Interlab L06 1315 SWA
6/16/2011 11:51 EPA Interlab L06 1315 SWA
6/1 6/201 1 1 1 :57 EPA Interlab L06 1 31 5 SWA
6/16/2011 11:59 EPA Interlab L06 131 5 SWA
6/16/2011 12:00 EPA Interlab L06 1315 SWA
6/16/2011 1 2:02 EPA Interlab L06 131 5 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/201 1 12:07 EPA Interlab L06 1315 SWA
6/16/2011 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:1 4 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:1 8 EPA Interlab L06 1315 SWA
6/16/2011 12:20EPAInterlabl_06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25EPAInterlabl_06 1315 SWA
6/16/201 1 1 1 :23 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :24 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :26 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :28 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :29 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :31 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :32 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :34 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :36 EPA Interlab L06 1315 SWA
1-556
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
As SWA-L06-1315-T01-A 1 1.84E+02
As SWA-L06-1315-T02-A 1 1.65E+02
As SWA-L06-1315-T03-A 1 7.44E+01
As SWA-L06-1315-T04-A 1 1.68E+02
As SWA-L06-1315-T05-A 1 1.33E+02
As SWA-L06-1315-T06-A 1 1.49E+02
As SWA-L06-1315-T07-A 1 9.91 E+01
As SWA-L06-1315-T08-A 1 6.95E+01
As SWA-L06-1315-T09-A 1 8.25E+01
As SWA-L06-1315-T01-B 1 2.02E+02
As SWA-L06-1315-T02-B 1 1.62E+02
As SWA-L06-1315-T03-B 1 8.25E+01
As SWA-L06-1315-T04-B 1 1.87E+02
As SWA-L06-1315-T05-B 1 1.40E+02
As SWA-L06-1315-T06-B 1 1.51E+02
As SWA-L06-1315-T07-B 1 1.16E+02
As SWA-L06-1315-T08-B 1 6.03E+01
As SWA-L06-1315-T09-B 1 8.07E+01
As SWA-L06-1315-T01-C 1 1.89E+02
As SWA-L06-1315-T02-C 1 2.57E+02
As SWA-L06-1315-T03-C 1 1.59E+02
As SWA-L06-1315-T04-C 1 3.48E+02
As SWA-L06-1315-T05-C 1 2.01E+02
As SWA-L06-1315-T06-C 1 1.89E+02
As SWA-L06-1315-T07-C 1 9.24E+01
As SWA-L06-1315-T08-C 1 7.20E+01
As SWA-L06-1315-T09-C 1 9.79E+01
As SWA-L06-1315-M01-A 1 5.50E+00 U1/2
As SWA-L06-1315-M02-A 1 5.50E+00 U1/2
As SWA-L06-1315-M03-A 1 5.50E+00 U1/2
As SWA-L06-1315-M04-A 1 5.50E+00 U1/2
As SWA-L06-1315-M05-A 1 5.50E+00 U1/2
As SWA-L06-1315-M06-A 1 5.50E+00 U1/2
As SWA-L06-1315-M07-A 1 5.50E+00 U1/2
As SWA-L06-1315-M08-A 1 5.50E+00 U1/2
As SWA-L06-1315-M09-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.84E+02 8.92 11.00 35.00
1.65E+02 0.65 11.00 35.00
7.44E+01 4.74 11.00 35.00 10000 1000
1.68E+02 4.68 11.00 35.00
1.33E+02 2.65 11.00 35.00
1.49E+02 1.21 11.00 35.00
9.91 E+01 3.56 11.00 35.00
6.95E+01 10.44 11.00 35.00
8.25E+01 9.65 11.00 35.00
2.02E+02 5.04 11.00 35.00
1.62E+02 2.47 11.00 35.00
8.25E+01 10.76 11.00 35.00 10000 1000
1.87E+02 5.59 11.00 35.00
1.40E+02 6.43 11.00 35.00
1.51E+02 3.59 11.00 35.00
1.16E+02 5.54 11.00 35.00
6.03E+01 5.13 11.00 35.00
8.07E+01 4.46 11.00 35.00
1.89E+02 1.24 11.00 35.00
2.57E+02 3.08 11.00 35.00
1.59E+02 3.34 11.00 35.00 10000 1000
3.48E+02 3.07 11.00 35.00
2.01E+02 3.28 11.00 35.00
1.89E+02 2.89 11.00 35.00
9.24E+01 6.67 11.00 35.00
7.20E+01 0.80 11.00 35.00
9.79E+01 2.08 11.00 35.00
5.50E+00 14.67 11.00 35.00
5.50E+00 33.06 11.00 35.00
5.50E+00 6.59 11.00 35.00
5.50E+00 46.01 11.00 35.00
5.50E+00 11.90 11.00 35.00
5.50E+00 25.74 11.00 35.00
5.50E+00 24.98 11.00 35.00
5.50E+00 18.25 11.00 35.00
5.50E+00 48.02 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.17E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.25E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/2011 11:37 EPA Interlab L06 1315SWA
6/16/2011 11:39 EPA Interlab L06 1315SWA
6/16/2011 11:41 EPA Interlab L06 1315 SWA
6/16/2011 11:42 EPA Interlab L06 1315 SWA
6/16/2011 11:44 EPA Interlab L06 1315 SWA
6/16/2011 11:46 EPA Interlab L06 1315 SWA
6/16/2011 11:47 EPA Interlab L06 1315 SWA
6/16/2011 11:49 EPA Interlab L06 1315 SWA
6/16/2011 11:51 EPA Interlab L06 1315 SWA
6/1 6/201 1 1 1 :57 EPA Interlab L06 1 31 5 SWA
6/16/2011 11:59 EPA Interlab L06 131 5 SWA
6/16/201 1 12:00 EPA Interlab L06 1315 SWA
6/16/2011 1 2:02 EPA Interlab L06 131 5 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/201 1 12:07 EPA Interlab L06 1315 SWA
6/16/2011 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:1 4 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:1 8 EPA Interlab L06 1315 SWA
6/16/2011 12:20EPAInterlabl_06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25EPAInterlabl_06 1315 SWA
6/16/201 1 1 1 :23 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :24 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :26 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :28 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :29 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :31 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :32 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :34 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :36 EPA Interlab L06 1315 SWA
1-557
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
B SWA-L06-1315-T01-A 1 4.41E+01
B SWA-L06-1315-T02-A 1 6.87E+01
B SWA-L06-1315-T03-A 1 3.47E+01
B SWA-L06-1315-T04-A 1 7.36E+01
B SWA-L06-1315-T05-A 1 6.21E+01
B SWA-L06-1315-T06-A 1 7.57E+01
B SWA-L06-1315-T07-A 1 5.76E+01
B SWA-L06-1315-T08-A 1 3.81 E+01
B SWA-L06-1315-T09-A 1 5.20E+01
B SWA-L06-1315-T01-B 1 5.48E+01
B SWA-L06-1315-T02-B 1 6.29E+01
B SWA-L06-1315-T03-B 1 3.37E+01
B SWA-L06-1315-T04-B 1 6.80E+01
B SWA-L06-1315-T05-B 1 6.04E+01
B SWA-L06-1315-T06-B 1 7.53E+01
B SWA-L06-1315-T07-B 1 5.56E+01
B SWA-L06-1315-T08-B 1 3.62E+01
B SWA-L06-1315-T09-B 1 4.94E+01
B SWA-L06-1315-T01-C 1 4.79E+01
B SWA-L06-1315-T02-C 1 6.78E+01
B SWA-L06-1315-T03-C 1 3.46E+01
B SWA-L06-1315-T04-C 1 7.66E+01
B SWA-L06-1315-T05-C 1 5.84E+01
B SWA-L06-1315-T06-C 1 7.59E+01
B SWA-L06-1315-T07-C 1 5.59E+01
B SWA-L06-1315-T08-C 1 3.54E+01
B SWA-L06-1315-T09-C 1 4.60E+01
B SWA-L06-1315-M01-A 1 5.00E-01 U1/2
B SWA-L06-1315-M02-A 1 5.00E-01 U1/2
B SWA-L06-1315-M03-A 1 5.00E-01 U1/2
B SWA-L06-1315-M04-A 1 5.00E-01 U1/2
B SWA-L06-1315-M05-A 1 5.00E-01 U1/2
B SWA-L06-1315-M06-A 1 5.00E-01 U1/2
B SWA-L06-1315-M07-A 1 5.00E-01 U1/2
B SWA-L06-1315-M08-A 1 5.00E-01 U1/2
B SWA-L06-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.41E+01 3.54 1.00 3.18
6.87E+01 3.32 1.00 3.18
3.47E+01 2.14 1.00 3.18 10000 1000
7.36E+01 0.92 1.00 3.18
6.21E+01 2.38 1.00 3.18
7.57E+01 2.11 1.00 3.18
5.76E+01 1.81 1.00 3.18
3.81E+01 1.27 1.00 3.18
5.20E+01 2.68 1.00 3.18
5.48E+01 3.68 1.00 3.18
6.29E+01 4.43 1.00 3.18
3.37E+01 2.45 1.00 3.18 10000 1000
6.80E+01 1.33 1.00 3.18
6.04E+01 3.05 1.00 3.18
7.53E+01 3.65 1.00 3.18
5.56E+01 3.60 1.00 3.18
3.62E+01 0.51 1.00 3.18
4.94E+01 2.44 1.00 3.18
4.79E+01 4.53 1.00 3.18
6.78E+01 1.73 1.00 3.18
3.46E+01 3.14 1.00 3.18 10000 1000
7.66E+01 1.71 1.00 3.18
5.84E+01 1.15 1.00 3.18
7.59E+01 1.86 1.00 3.18
5.59E+01 1.34 1.00 3.18
3.54E+01 1.95 1.00 3.18
4.60E+01 1.96 1.00 3.18
5.00E-01 1.91 1.00 3.18
5.00E-01 2.31 1.00 3.18
5.00E-01 13.11 1.00 3.18
5.00E-01 6.34 1.00 3.18
5.00E-01 1.95 1.00 3.18
5.00E-01 2.80 1.00 3.18
5.00E-01 1.25 1.00 3.18
5.00E-01 1.57 1.00 3.18
5.00E-01 1.68 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/2011 11:37 EPA Interlab L06 1315SWA
6/16/2011 11:39 EPA Interlab L06 1315SWA
6/16/2011 11:41 EPA Interlab L06 1315SWA
6/16/2011 11:42 EPA Interlab L06 1315 SWA
6/16/2011 11:44 EPA Interlab L06 1315 SWA
6/16/2011 11:46 EPA Interlab L06 1315 SWA
6/16/2011 11:47 EPA Interlab L06 1315 SWA
6/16/2011 11:49 EPA Interlab L06 1315 SWA
6/16/2011 11:51 EPA Interlab L06 1315 SWA
6/1 6/201 1 1 1 :57 EPA Interlab L06 1 31 5 SWA
6/16/2011 11:59 EPA Interlab L06 131 5 SWA
6/16/201 1 12:00 EPA Interlab L06 1315 SWA
6/16/2011 1 2:02 EPA Interlab L06 131 5 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/201 1 12:07 EPA Interlab L06 1315 SWA
6/16/2011 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:1 4 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:1 8 EPA Interlab L06 1315 SWA
6/16/2011 12:20EPAInterlabl_06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25EPAInterlabl_06 1315 SWA
6/16/201 1 1 1 :23 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :24 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :26 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :28 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :29 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :31 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :32 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :34 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :36 EPA Interlab L06 1315 SWA
1-558
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
Ba SWA-L06-1315-T01-A 1 3.98E+01
Ba SWA-L06-1315-T02-A 1 1.80E+02
Ba SWA-L06-1315-T03-A 1 2.45E+02
Ba SWA-L06-1315-T04-A 1 3.68E+02
Ba SWA-L06-1315-T05-A 1 4.43E+02
Ba SWA-L06-1315-T06-A 1 4.87E+02
Ba SWA-L06-1315-T07-A 1 5.98E+02
Ba SWA-L06-1315-T08-A 1 5.80E+02
Ba SWA-L06-1315-T09-A 1 5.57E+02
Ba SWA-L06-1315-T01-B 1 2.37E+01
Ba SWA-L06-1315-T02-B 1 1.63E+02
Ba SWA-L06-1315-T03-B 1 2.54E+02
Ba SWA-L06-1315-T04-B 1 3.66E+02
Ba SWA-L06-1315-T05-B 1 4.42E+02
Ba SWA-L06-1315-T06-B 1 4.87E+02
Ba SWA-L06-1315-T07-B 1 5.94E+02
Ba SWA-L06-1315-T08-B 1 5.86E+02
Ba SWA-L06-1315-T09-B 1 5.49E+02
Ba SWA-L06-1315-T01-C 1 2.69E+01
Ba SWA-L06-1315-T02-C 1 1.28E+02
Ba SWA-L06-1315-T03-C 1 2.54E+02
Ba SWA-L06-1315-T04-C 1 3.61E+02
Ba SWA-L06-1315-T05-C 1 4.44E+02
Ba SWA-L06-1315-T06-C 1 4.87E+02
Ba SWA-L06-1315-T07-C 1 5.93E+02
Ba SWA-L06-1315-T08-C 1 5.88E+02
Ba SWA-L06-1315-T09-C 1 5.48E+02
Ba SWA-L06-1315-M01-A 1 5.00E-01 U1/2
Ba SWA-L06-1315-M02-A 1 5.00E-01 U1/2
Ba SWA-L06-1315-M03-A 1 5.00E-01 U1/2
Ba SWA-L06-1315-M04-A 1 5.00E-01 U1/2
Ba SWA-L06-1315-M05-A 1 5.00E-01 U1/2
Ba SWA-L06-1315-M06-A 1 5.00E-01 U1/2
Ba SWA-L06-1315-M07-A 1 5.00E-01 U1/2
Ba SWA-L06-1315-M08-A 1 5.00E-01 U1/2
Ba SWA-L06-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.98E+01 0.63 1.00 3.18
1.80E+02 0.47 1.00 3.18
2.45E+02 1.04 1.00 3.18 10000 1000
3.68E+02 1.08 1.00 3.18
4.43E+02 1.20 1.00 3.18
4.87E+02 2.09 1.00 3.18
5.98E+02 0.65 1.00 3.18
5.80E+02 0.83 1.00 3.18
5.57E+02 1.78 1.00 3.18
2.37E+01 3.40 1.00 3.18
1.63E+02 1.05 1.00 3.18
2.54E+02 1.84 1.00 3.18 10000 1000
3.66E+02 0.94 1.00 3.18
4.42E+02 0.40 1.00 3.18
4.87E+02 0.66 1.00 3.18
5.94E+02 1.13 1.00 3.18
5.86E+02 1.24 1.00 3.18
5.49E+02 0.87 1.00 3.18
2.69E+01 1.28 1.00 3.18
1.28E+02 1.16 1.00 3.18
2.54E+02 1.09 1.00 3.18 10000 1000
3.61E+02 1.17 1.00 3.18
4.44E+02 0.70 1.00 3.18
4.87E+02 0.90 1.00 3.18
5.93E+02 2.44 1.00 3.18
5.88E+02 1.74 1.00 3.18
5.48E+02 1.20 1.00 3.18
5.00E-01 7.32 1.00 3.18
5.00E-01 7.34 1.00 3.18
5.00E-01 7.96 1.00 3.18
5.00E-01 7.67 1.00 3.18
5.00E-01 10.03 1.00 3.18
5.00E-01 12.71 1.00 3.18
5.00E-01 9.62 1.00 3.18
5.00E-01 13.10 1.00 3.18
5.00E-01 5.60 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.29E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.29E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.27E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/25/12 1:09 PM EPA Interlab L06 1315 SWA
1/25/12 1:10 PM EPA Interlab L06 1315 SWA
1/25/12 1:12 PM EPA Interlab L06 1315 SWA
1/25/12 1:14 PM EPA Interlab L06 1315 SWA
1/25/12 1:15 PM EPA Interlab L06 1315 SWA
1/25/12 1:17 PM EPA Interlab L06 1315 SWA
1/25/12 1:19 PM EPA Interlab L06 1315 SWA
1/25/12 1:20 PM EPA Interlab L06 1315 SWA
1/25/12 1:22 PM EPA Interlab L06 1315 SWA
1/25/12 1:24 PM EPA Interlab L06 1315 SWA
1/25/12 1:25 PM EPA Interlab L06 1315 SWA
1/25/12 1:27 PM EPA Interlab L06 1315 SWA
1/25/12 1:29 PM EPA Interlab L06 1315 SWA
1/25/12 1:30 PM EPA Interlab L06 1315 SWA
1/25/12 1:32 PM EPA Interlab L06 1315 SWA
1/25/12 1:34 PM EPA Interlab L06 1315 SWA
1/25/12 1:35 PM EPA Interlab L06 1315 SWA
1/25/12 1:37 PM EPA Interlab L06 1315 SWA
1/25/12 1:39 PM EPA Interlab L06 1315 SWA
1/25/12 1:40 PM EPA Interlab L06 1315 SWA
1/25/12 1:42 PM EPA Interlab L06 1315 SWA
1/25/12 1:44 PM EPA Interlab L06 1315 SWA
1/25/12 1:45 PM EPA Interlab L06 1315 SWA
1/25/12 1:47 PM EPA Interlab L06 1315 SWA
1/25/12 1:49 PM EPA Interlab L06 1315 SWA
1/25/12 1:50 PM EPA Interlab L06 1315 SWA
1/25/12 1:52 PM EPA Interlab L06 1315 SWA
1/25/12 12:53 PM EPA Interlab L06 1315 SWA
1/25/12 12:55 PM EPA Interlab L06 1315 SWA
1/25/12 12:56 PM EPA Interlab L06 1315 SWA
1/25/12 12:58 PM EPA Interlab L06 1315 SWA
1/25/12 12:59 PM EPA Interlab L06 1315 SWA
1/25/12 1:02 PM EPA Interlab L06 1315 SWA
1/25/12 1:04 PM EPA Interlab L06 1315 SWA
1/25/12 1:05 PM EPA Interlab L06 1315 SWA
1/25/12 1:07 PM EPA Interlab L06 1315 SWA
1-559
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Be SWA-L06-1315-T01-A 1 9.50E-01 U1/2
Be SWA-L06-1315-T02-A 1 9.50E-01 U1/2
Be SWA-L06-1315-T03-A 1 9.50E-01 U1/2
Be SWA-L06-1315-T04-A 1 9.50E-01 U1/2
Be SWA-L06-1315-T05-A 1 9.50E-01 U1/2
Be SWA-L06-1315-T06-A 1 9.50E-01 U1/2
Be SWA-L06-1315-T07-A 1 9.50E-01 U1/2
Be SWA-L06-1315-T08-A 1 9.50E-01 U1/2
Be SWA-L06-1315-T09-A 1 9.50E-01 U1/2
Be SWA-L06-1315-T01-B 1 9.50E-01 U1/2
Be SWA-L06-1315-T02-B 1 9.50E-01 U1/2
Be SWA-L06-1315-T03-B 1 9.50E-01 U1/2
Be SWA-L06-1315-T04-B 1 9.50E-01 U1/2
Be SWA-L06-1315-T05-B 1 9.50E-01 U1/2
Be SWA-L06-1315-T06-B 1 9.50E-01 U1/2
Be SWA-L06-1315-T07-B 1 9.50E-01 U1/2
Be SWA-L06-1315-T08-B 1 9.50E-01 U1/2
Be SWA-L06-1315-T09-B 1 9.50E-01 U1/2
Be SWA-L06-1315-T01-C 1 9.50E-01 U1/2
Be SWA-L06-1315-T02-C 1 9.50E-01 U1/2
Be SWA-L06-1315-T03-C 1 9.50E-01 U1/2
Be SWA-L06-1315-T04-C 1 9.50E-01 U1/2
Be SWA-L06-1315-T05-C 1 9.50E-01 U1/2
Be SWA-L06-1315-T06-C 1 9.50E-01 U1/2
Be SWA-L06-1315-T07-C 1 9.50E-01 U1/2
Be SWA-L06-1315-T08-C 1 9.50E-01 U1/2
Be SWA-L06-1315-T09-C 1 9.50E-01 U1/2
Be SWA-L06-1315-M01-A 1 9.50E-01 U1/2
Be SWA-L06-1315-M02-A 1 9.50E-01 U1/2
Be SWA-L06-1315-M03-A 1 9.50E-01 U1/2
Be SWA-L06-1315-M04-A 1 9.50E-01 U1/2
Be SWA-L06-1315-M05-A 1 9.50E-01 U1/2
Be SWA-L06-1315-M06-A 1 9.50E-01 U1/2
Be SWA-L06-1315-M07-A 1 9.50E-01 U1/2
Be SWA-L06-1315-M08-A 1 9.50E-01 U1/2
Be SWA-L06-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 44.62 1.90 6.00
9.50E-01 18.15 1.90 6.00
9.50E-01 10.73 1.90 6.00 10000 1000
9.50E-01 10.75 1.90 6.00
9.50E-01 65.32 1.90 6.00
9.50E-01 24.24 1.90 6.00
9.50E-01 12.62 1.90 6.00
9.50E-01 53.57 1.90 6.00
9.50E-01 74.02 1.90 6.00
9.50E-01 11.77 1.90 6.00
9.50E-01 41.99 1.90 6.00
9.50E-01 36.46 1.90 6.00 10000 1000
9.50E-01 59.22 1.90 6.00
9.50E-01 36.93 1.90 6.00
9.50E-01 10.19 1.90 6.00
9.50E-01 63.76 1.90 6.00
9.50E-01 31.13 1.90 6.00
9.50E-01 25.28 1.90 6.00
9.50E-01 14.85 1.90 6.00
9.50E-01 22.47 1.90 6.00
9.50E-01 22.02 1.90 6.00 10000 1000
9.50E-01 27.80 1.90 6.00
9.50E-01 25.82 1.90 6.00
9.50E-01 33.02 1.90 6.00
9.50E-01 36.51 1.90 6.00
9.50E-01 14.28 1.90 6.00
9.50E-01 20.67 1.90 6.00
9.50E-01 41.48 1.90 6.00
9.50E-01 51.37 1.90 6.00
9.50E-01 12.75 1.90 6.00
9.50E-01 28.55 1.90 6.00
9.50E-01 28.98 1.90 6.00
9.50E-01 18.35 1.90 6.00
9.50E-01 35.90 1.90 6.00
9.50E-01 41.37 1.90 6.00
9.50E-01 35.13 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/2011 11:37 EPA Interlab L06 1315SWA
6/16/2011 11:39 EPA Interlab L06 1315SWA
6/16/2011 11:41 EPA Interlab L06 1315 SWA
6/16/2011 11:42 EPA Interlab L06 1315SWA
6/16/2011 11:44 EPA Interlab L06 1315SWA
6/16/2011 11:46 EPA Interlab L06 1315 SWA
6/16/2011 11:47 EPA Interlab L06 1315 SWA
6/16/2011 11:49 EPA Interlab L06 1315 SWA
6/16/2011 11:51 EPA Interlab L06 1315 SWA
6/16/2011 11:57 EPA Interlab L06 1315 SWA
6/16/2011 11:59 EPA Interlab L06 1315 SWA
6/16/2011 12:00 EPA Interlab L06 1315 SWA
6/16/201 1 12:02 EPA Interlab L06 1315 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/2011 12:07 EPA Interlab L06 1315 SWA
6/16/2011 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:14 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:18 EPA Interlab L06 1315 SWA
6/16/2011 12:20 EPA Interlab L06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :23 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :24 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :26 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :28 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :29 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :31 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :32 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :34 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :36 EPA Interlab L06 1315 SWA
1-560
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cd SWA-L06-1315-T01-A 1 1.10E+00 U1/2
Cd SWA-L06-1315-T02-A 1 1.10E+00 U1/2
Cd SWA-L06-1315-T03-A 1 1.10E+00 U1/2
Cd SWA-L06-1315-T04-A 1 1.10E+00 U1/2
Cd SWA-L06-1315-T05-A 1 1.10E+00 U1/2
Cd SWA-L06-1315-T06-A 1 1.10E+00 U1/2
Cd SWA-L06-1315-T07-A 1 1.10E+00 U1/2
Cd SWA-L06-1315-T08-A 1 1.10E+00 U1/2
Cd SWA-L06-1315-T09-A 1 1.10E+00 U1/2
Cd SWA-L06-1315-T01-B 1 1.10E+00 U1/2
Cd SWA-L06-1315-T02-B 1 1.10E+00 U1/2
Cd SWA-L06-1315-T03-B 1 1.10E+00 U1/2
Cd SWA-L06-1315-T04-B 1 1.10E+00 U1/2
Cd SWA-L06-1315-T05-B 1 1.10E+00 U1/2
Cd SWA-L06-1315-T06-B 1 1.10E+00 U1/2
Cd SWA-L06-1315-T07-B 1 1.10E+00 U1/2
Cd SWA-L06-1315-T08-B 1 1.10E+00 U1/2
Cd SWA-L06-1315-T09-B 1 1.10E+00 U1/2
Cd SWA-L06-1315-T01-C 1 1.10E+00 U1/2
Cd SWA-L06-1315-T02-C 1 1.10E+00 U1/2
Cd SWA-L06-1315-T03-C 1 1.10E+00 U1/2
Cd SWA-L06-1315-T04-C 1 1.10E+00 U1/2
Cd SWA-L06-1315-T05-C 1 1.10E+00 U1/2
Cd SWA-L06-1315-T06-C 1 1.10E+00 U1/2
Cd SWA-L06-1315-T07-C 1 1.10E+00 U1/2
Cd SWA-L06-1315-T08-C 1 1.10E+00 U1/2
Cd SWA-L06-1315-T09-C 1 1.10E+00 U1/2
Cd SWA-L06-1315-M01-A 1 1.10E+00 U1/2
Cd SWA-L06-1315-M02-A 1 1.10E+00 U1/2
Cd SWA-L06-1315-M03-A 1 1.10E+00 U1/2
Cd SWA-L06-1315-M04-A 1 1.10E+00 U1/2
Cd SWA-L06-1315-M05-A 1 1.10E+00 U1/2
Cd SWA-L06-1315-M06-A 1 1.10E+00 U1/2
Cd SWA-L06-1315-M07-A 1 1.10E+00 U1/2
Cd SWA-L06-1315-M08-A 1 1.10E+00 U1/2
Cd SWA-L06-1315-M09-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 20.38 2.20 7.00
1.10E+00 45.35 2.20 7.00
1.10E+00 53.73 2.20 7.00 10000 1000
1.10E+00 69.63 2.20 7.00
1.10E+00 48.06 2.20 7.00
1.10E+00 34.89 2.20 7.00
1.10E+00 31.31 2.20 7.00
1.10E+00 44.69 2.20 7.00
1.10E+00 19.88 2.20 7.00
1.10E+00 12.98 2.20 7.00
1.10E+00 53.36 2.20 7.00
1.10E+00 20.82 2.20 7.00 10000 1000
1.10E+00 12.96 2.20 7.00
1.10E+00 10.01 2.20 7.00
1.10E+00 18.45 2.20 7.00
1.10E+00 15.26 2.20 7.00
1.10E+00 88.67 2.20 7.00
1.10E+00 20.86 2.20 7.00
1.10E+00 39.35 2.20 7.00
1.10E+00 70.48 2.20 7.00
1.10E+00 33.63 2.20 7.00 10000 1000
1.10E+00 17.37 2.20 7.00
1.10E+00 77.61 2.20 7.00
1.10E+00 16.57 2.20 7.00
1.10E+00 57.67 2.20 7.00
1.10E+00 37.15 2.20 7.00
1.10E+00 15.10 2.20 7.00
1.10E+00 17.42 2.20 7.00
1.10E+00 60.51 2.20 7.00
1.10E+00 58.12 2.20 7.00
1.10E+00 29.62 2.20 7.00
1.10E+00 36.64 2.20 7.00
1.10E+00 19.74 2.20 7.00
1.10E+00 39.06 2.20 7.00
1.10E+00 22.35 2.20 7.00
1.10E+00 17.20 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.95E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.95E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/201 1 11 :37 EPA Interlab L06 1315 SWA
6/16/2011 11:39 EPA Interlab L06 1315 SWA
6/16/2011 11:41 EPA Interlab L06 1315 SWA
6/16/2011 11:42 EPA Interlab L06 1315 SWA
6/16/2011 11:44 EPA Interlab L06 1315 SWA
6/16/2011 11:46 EPA Interlab L06 1315 SWA
6/16/2011 11:47 EPA Interlab L06 1315 SWA
6/16/2011 11:49 EPA Interlab L06 1315 SWA
6/16/2011 11:51 EPA Interlab L06 1315 SWA
6/16/201 1 11 :57 EPA Interlab L06 1315 SWA
6/16/2011 11:59 EPA Interlab L06 1315 SWA
6/16/2011 12:00 EPA Interlab L06 1315 SWA
6/16/2011 12:02 EPA Interlab L06 1315 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/2011 12:07 EPA Interlab L06 1315 SWA
6/16/2011 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:14 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:18 EPA Interlab L06 1315 SWA
6/16/2011 12:20 EPA Interlab L06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25 EPA Interlab L06 1315 SWA
6/16/2011 11:23 EPA Interlab L06 1315 SWA
6/16/2011 11:24 EPA Interlab L06 1315 SWA
6/16/2011 11:26 EPA Interlab L06 1315 SWA
6/16/2011 11:28 EPA Interlab L06 1315 SWA
6/16/2011 11:29 EPA Interlab L06 1315 SWA
6/16/2011 11:31 EPA Interlab L06 1315 SWA
6/16/201 1 11 :32 EPA Interlab L06 1315 SWA
6/16/2011 11:34 EPA Interlab L06 1315 SWA
6/16/2011 11:36 EPA Interlab L06 1315 SWA
1-561
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Ca SWA-L06-1315-T01-A 1 9.03E+02
Ca SWA-L06-1315-T02-A 1 1.10E+04
Ca SWA-L06-1315-T03-A 1 1.23E+04
Ca SWA-L06-1315-T04-A 1 2.34E+04
Ca SWA-L06-1315-T05-A 1 2.58E+04
Ca SWA-L06-1315-T06-A 1 2.89E+04
Ca SWA-L06-1315-T07-A 1 2.65E+04
Ca SWA-L06-1315-T08-A 1 2.34E+04
Ca SWA-L06-1315-T09-A 1 2.46E+04
Ca SWA-L06-1315-T01-B 1 8.85E+02
Ca SWA-L06-1315-T02-B 1 9.00E+03
Ca SWA-L06-1315-T03-B 1 1.16E+04
Ca SWA-L06-1315-T04-B 1 2.17E+04
Ca SWA-L06-1315-T05-B 1 2.43E+04
Ca SWA-L06-1315-T06-B 1 2.71E+04
Ca SWA-L06-1315-T07-B 1 2.44E+04
Ca SWA-L06-1315-T08-B 1 2.09E+04
Ca SWA-L06-1315-T09-B 1 2.23E+04
Ca SWA-L06-1315-T01-C 1 1.03E+03
Ca SWA-L06-1315-T02-C 1 9.33E+03
Ca SWA-L06-1315-T03-C 1 1.08E+04
Ca SWA-L06-1315-T04-C 1 2.11E+04
Ca SWA-L06-1315-T05-C 1 2.39E+04
Ca SWA-L06-1315-T06-C 1 2.57E+04
Ca SWA-L06-1315-T07-C 1 2.52E+04
Ca SWA-L06-1315-T08-C 1 2.22E+04
Ca SWA-L06-1315-T09-C 1 2.24E+04
Ca SWA-L06-1315-M01-A 1 7.45E+01
Ca SWA-L06-1315-M02-A 1 1.10E+02
Ca SWA-L06-1315-M03-A 1 7.12E+01
Ca SWA-L06-1315-M04-A 1 1.28E+02
Ca SWA-L06-1315-M05-A 1 1.11E+02
Ca SWA-L06-1315-M06-A 1 1.48E+02
Ca SWA-L06-1315-M07-A 1 1.41E+02
Ca SWA-L06-1315-M08-A 1 3.48E+01
Ca SWA-L06-1315-M09-A 1 1.52E+02
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.03E+02 1.26 2.60 8.30
1.10E+04 0.82 2.60 8.30
1.23E+04 0.87 2.60 8.30 10000 1000
2.34E+04 1.15 2.60 8.30
2.58E+04 1.98 2.60 8.30
2.89E+04 1.74 2.60 8.30
2.65E+04 0.68 2.60 8.30
2.34E+04 1.20 2.60 8.30
2.46E+04 1.24 2.60 8.30
8.85E+02 6.45 2.60 8.30
9.00E+03 0.71 2.60 8.30
1.16E+04 1.28 2.60 8.30 10000 1000
2.17E+04 1.05 2.60 8.30
2.43E+04 0.40 2.60 8.30
2.71E+04 0.65 2.60 8.30
2.44E+04 1.27 2.60 8.30
2.09E+04 1.35 2.60 8.30
2.23E+04 0.88 2.60 8.30
1.03E+03 1.63 2.60 8.30
9.33E+03 1.28 2.60 8.30
1.08E+04 0.97 2.60 8.30 10000 1000
2.11E+04 0.94 2.60 8.30
2.39E+04 1.22 2.60 8.30
2.57E+04 1.10 2.60 8.30
2.52E+04 2.31 2.60 8.30
2.22E+04 2.04 2.60 8.30
2.24E+04 0.94 2.60 8.30
7.45E+01 5.33 2.60 8.30
1.10E+02 5.48 2.60 8.30
7.12E+01 2.18 2.60 8.30
1.28E+02 4.59 2.60 8.30
1.11E+02 8.16 2.60 8.30
1.48E+02 4.40 2.60 8.30
1.41E+02 3.32 2.60 8.30
3.48E+01 3.60 2.60 8.30
1.52E+02 2.37 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.32E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.25E+04 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/2011 11:37 EPA Interlab L06 1315SWA
6/16/2011 11:39 EPA Interlab L06 1315SWA
6/16/2011 11:41 EPA Interlab L06 1315 SWA
6/16/2011 11:42 EPA Interlab L06 1315SWA
6/16/2011 11:44 EPA Interlab L06 1315SWA
6/16/2011 11:46 EPA Interlab L06 1315SWA
6/16/2011 11:47 EPA Interlab L06 1315SWA
6/16/2011 11:49 EPA Interlab L06 1315SWA
6/16/2011 11:51 EPA Interlab L06 1315SWA
6/16/2011 11:57 EPA Interlab L06 1315SWA
6/16/2011 11:59 EPA Interlab L06 1315SWA
6/16/2011 12:00 EPA Interlab L06 1315 SWA
6/16/2011 12:02 EPA Interlab L06 1315 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/2011 12:07 EPA Interlab L06 1315 SWA
6/16/2011 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:14 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:18 EPA Interlab L06 1315 SWA
6/16/2011 12:20 EPA Interlab L06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25 EPA Interlab L06 1315 SWA
6/16/2011 11:23 EPA Interlab L06 1315SWA
6/16/2011 11:24 EPA Interlab L06 1315SWA
6/16/2011 11:26 EPA Interlab L06 1315SWA
6/16/2011 11:28 EPA Interlab L06 1315SWA
6/16/2011 11:29 EPA Interlab L06 1315SWA
6/16/2011 11:31 EPA Interlab L06 1315SWA
6/16/2011 11:32 EPA Interlab L06 1315SWA
6/16/2011 11:34 EPA Interlab L06 1315SWA
6/16/2011 11:36 EPA Interlab L06 1315SWA
1-562
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Cr SWA-L06-1315-T01-A 1 3.85E+01
Cr SWA-L06-1315-T02-A 1 6.67E+01
Cr SWA-L06-1315-T03-A 1 2.48E+01
Cr SWA-L06-1315-T04-A 1 5.07E+01
Cr SWA-L06-1315-T05-A 1 4.73E+01
Cr SWA-L06-1315-T06-A 1 5.65E+01
Cr SWA-L06-1315-T07-A 1 4.77E+01
Cr SWA-L06-1315-T08-A 1 2.96E+01
Cr SWA-L06-1315-T09-A 1 4.14E+01
Cr SWA-L06-1315-T01-B 1 4.57E+01
Cr SWA-L06-1315-T02-B 1 6.10E+01
Cr SWA-L06-1315-T03-B 1 2.45E+01
Cr SWA-L06-1315-T04-B 1 4.56E+01
Cr SWA-L06-1315-T05-B 1 4.04E+01
Cr SWA-L06-1315-T06-B 1 5.06E+01
Cr SWA-L06-1315-T07-B 1 4.11E+01
Cr SWA-L06-1315-T08-B 1 2.63E+01
Cr SWA-L06-1315-T09-B 1 3.78E+01
Cr SWA-L06-1315-T01-C 1 4.00E+01
Cr SWA-L06-1315-T02-C 1 5.78E+01
Cr SWA-L06-1315-T03-C 1 2.15E+01
Cr SWA-L06-1315-T04-C 1 4.20E+01
Cr SWA-L06-1315-T05-C 1 3.94E+01
Cr SWA-L06-1315-T06-C 1 4.83E+01
Cr SWA-L06-1315-T07-C 1 4.25E+01
Cr SWA-L06-1315-T08-C 1 2.61E+01
Cr SWA-L06-1315-T09-C 1 3.82E+01
Cr SWA-L06-1315-M01-A 1 6.00E-01 U1/2
Cr SWA-L06-1315-M02-A 1 6.00E-01 U1/2
Cr SWA-L06-1315-M03-A 1 6.00E-01 U1/2
Cr SWA-L06-1315-M04-A 1 6.00E-01 U1/2
Cr SWA-L06-1315-M05-A 1 6.00E-01 U1/2
Cr SWA-L06-1315-M06-A 1 6.00E-01 U1/2
Cr SWA-L06-1315-M07-A 1 6.00E-01 U1/2
Cr SWA-L06-1315-M08-A 1 6.00E-01 U1/2
Cr SWA-L06-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.85E+01 3.61 1.20 3.82
6.67E+01 0.91 1.20 3.82
2.48E+01 0.94 1.20 3.82 10000 1000
5.07E+01 1.62 1.20 3.82
4.73E+01 1.96 1.20 3.82
5.65E+01 2.31 1.20 3.82
4.77E+01 0.69 1.20 3.82
2.96E+01 2.38 1.20 3.82
4.14E+01 1.85 1.20 3.82
4.57E+01 4.25 1.20 3.82
6.10E+01 0.90 1.20 3.82
2.45E+01 3.39 1.20 3.82 10000 1000
4.56E+01 2.21 1.20 3.82
4.04E+01 0.72 1.20 3.82
5.06E+01 0.65 1.20 3.82
4.11E+01 2.64 1.20 3.82
2.63E+01 1.65 1.20 3.82
3.78E+01 2.41 1.20 3.82
4.00E+01 3.46 1.20 3.82
5.78E+01 2.34 1.20 3.82
2.15E+01 2.37 1.20 3.82 10000 1000
4.20E+01 2.76 1.20 3.82
3.94E+01 2.29 1.20 3.82
4.83E+01 2.47 1.20 3.82
4.25E+01 3.43 1.20 3.82
2.61E+01 2.08 1.20 3.82
3.82E+01 1.16 1.20 3.82
6.00E-01 43.94 1.20 3.82
6.00E-01 12.10 1.20 3.82
6.00E-01 36.33 1.20 3.82
6.00E-01 22.46 1.20 3.82
6.00E-01 36.57 1.20 3.82
6.00E-01 11.29 1.20 3.82
6.00E-01 15.61 1.20 3.82
6.00E-01 26.51 1.20 3.82
6.00E-01 42.20 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.07E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/2011 11:37 EPA Interlab L06 1315SWA
6/16/2011 11:39 EPA Interlab L06 1315SWA
6/16/2011 11:41 EPA Interlab L06 1315SWA
6/16/2011 11:42 EPA Interlab L06 1315 SWA
6/16/2011 11:44 EPA Interlab L06 1315 SWA
6/16/2011 11:46 EPA Interlab L06 1315 SWA
6/16/2011 11:47 EPA Interlab L06 1315 SWA
6/16/2011 11:49 EPA Interlab L06 1315 SWA
6/16/2011 11:51 EPA Interlab L06 1315 SWA
6/1 6/201 1 1 1 :57 EPA Interlab L06 1 31 5 SWA
6/16/2011 11:59 EPA Interlab L06 131 5 SWA
6/16/201 1 12:00 EPA Interlab L06 1315 SWA
6/16/2011 1 2:02 EPA Interlab L06 131 5 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/201 1 12:07 EPA Interlab L06 1315 SWA
6/16/2011 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:1 4 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:1 8 EPA Interlab L06 1315 SWA
6/16/2011 12:20EPAInterlabl_06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25EPAInterlabl_06 1315 SWA
6/16/201 1 1 1 :23 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :24 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :26 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :28 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :29 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :31 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :32 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :34 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :36 EPA Interlab L06 1315 SWA
1-563
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Co SWA-L06-1315-T01-A 1 9.00E-01 U1/2
Co SWA-L06-1315-T02-A 1 9.00E-01 U1/2
Co SWA-L06-1315-T03-A 1 9.00E-01 U1/2
Co SWA-L06-1315-T04-A 1 9.00E-01 U1/2
Co SWA-L06-1315-T05-A 1 9.00E-01 U1/2
Co SWA-L06-1315-T06-A 1 9.00E-01 U1/2
Co SWA-L06-1315-T07-A 1 9.00E-01 U1/2
Co SWA-L06-1315-T08-A 1 9.00E-01 U1/2
Co SWA-L06-1315-T09-A 1 9.00E-01 U1/2
Co SWA-L06-1315-T01-B 1 9.00E-01 U1/2
Co SWA-L06-1315-T02-B 1 9.00E-01 U1/2
Co SWA-L06-1315-T03-B 1 9.00E-01 U1/2
Co SWA-L06-1315-T04-B 1 9.00E-01 U1/2
Co SWA-L06-1315-T05-B 1 9.00E-01 U1/2
Co SWA-L06-1315-T06-B 1 9.00E-01 U1/2
Co SWA-L06-1315-T07-B 1 9.00E-01 U1/2
Co SWA-L06-1315-T08-B 1 9.00E-01 U1/2
Co SWA-L06-1315-T09-B 1 9.00E-01 U1/2
Co SWA-L06-1315-T01-C 1 9.00E-01 U1/2
Co SWA-L06-1315-T02-C 1 9.00E-01 U1/2
Co SWA-L06-1315-T03-C 1 9.00E-01 U1/2
Co SWA-L06-1315-T04-C 1 9.00E-01 U1/2
Co SWA-L06-1315-T05-C 1 9.00E-01 U1/2
Co SWA-L06-1315-T06-C 1 9.00E-01 U1/2
Co SWA-L06-1315-T07-C 1 9.00E-01 U1/2
Co SWA-L06-1315-T08-C 1 9.00E-01 U1/2
Co SWA-L06-1315-T09-C 1 9.00E-01 U1/2
Co SWA-L06-1315-M01-A 1 9.00E-01 U1/2
Co SWA-L06-1315-M02-A 1 9.00E-01 U1/2
Co SWA-L06-1315-M03-A 1 9.00E-01 U1/2
Co SWA-L06-1315-M04-A 1 9.00E-01 U1/2
Co SWA-L06-1315-M05-A 1 9.00E-01 U1/2
Co SWA-L06-1315-M06-A 1 9.00E-01 U1/2
Co SWA-L06-1315-M07-A 1 9.00E-01 U1/2
Co SWA-L06-1315-M08-A 1 9.00E-01 U1/2
Co SWA-L06-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 52.53 1.80 5.72
9.00E-01 34.43 1.80 5.72
9.00E-01 41.97 1.80 5.72 10000 1000
9.00E-01 10.66 1.80 5.72
9.00E-01 53.08 1.80 5.72
9.00E-01 16.18 1.80 5.72
9.00E-01 90.97 1.80 5.72
9.00E-01 53.76 1.80 5.72
9.00E-01 84.80 1.80 5.72
9.00E-01 64.08 1.80 5.72
9.00E-01 84.22 1.80 5.72
9.00E-01 15.47 1.80 5.72 10000 1000
9.00E-01 59.65 1.80 5.72
9.00E-01 49.19 1.80 5.72
9.00E-01 14.97 1.80 5.72
9.00E-01 45.15 1.80 5.72
9.00E-01 39.96 1.80 5.72
9.00E-01 46.30 1.80 5.72
9.00E-01 12.64 1.80 5.72
9.00E-01 13.18 1.80 5.72
9.00E-01 25.87 1.80 5.72 10000 1000
9.00E-01 10.50 1.80 5.72
9.00E-01 32.77 1.80 5.72
9.00E-01 59.96 1.80 5.72
9.00E-01 18.60 1.80 5.72
9.00E-01 19.62 1.80 5.72
9.00E-01 40.58 1.80 5.72
9.00E-01 11.60 1.80 5.72
9.00E-01 12.62 1.80 5.72
9.00E-01 89.02 1.80 5.72
9.00E-01 55.97 1.80 5.72
9.00E-01 15.54 1.80 5.72
9.00E-01 48.87 1.80 5.72
9.00E-01 76.91 1.80 5.72
9.00E-01 13.26 1.80 5.72
9.00E-01 35.32 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.98E+02 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.92E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.88E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/201 1 11 :37 EPA Interlab L06 1315 SWA
6/16/2011 11:39 EPA Interlab L06 1315 SWA
6/16/2011 11:41 EPA Interlab L06 1315 SWA
6/16/2011 11:42 EPA Interlab L06 1315 SWA
6/16/2011 11:44 EPA Interlab L06 1315 SWA
6/16/2011 11:46 EPA Interlab L06 1315 SWA
6/16/2011 11:47 EPA Interlab L06 1315 SWA
6/16/2011 11:49 EPA Interlab L06 1315 SWA
6/16/2011 11:51 EPA Interlab L06 1315 SWA
6/16/201 1 11 :57 EPA Interlab L06 1315 SWA
6/16/2011 11:59 EPA Interlab L06 1315 SWA
6/16/2011 12:00 EPA Interlab L06 1315 SWA
6/16/2011 12:02 EPA Interlab L06 1315 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/2011 12:07 EPA Interlab L06 1315 SWA
6/16/2011 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:14 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:18 EPA Interlab L06 1315 SWA
6/16/2011 12:20 EPA Interlab L06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25 EPA Interlab L06 1315 SWA
6/16/2011 11:23 EPA Interlab L06 1315 SWA
6/16/2011 11:24 EPA Interlab L06 1315 SWA
6/16/2011 11:26 EPA Interlab L06 1315 SWA
6/16/2011 11:28 EPA Interlab L06 1315 SWA
6/16/2011 11:29 EPA Interlab L06 1315 SWA
6/16/2011 11:31 EPA Interlab L06 1315 SWA
6/16/201 1 11 :32 EPA Interlab L06 1315 SWA
6/16/2011 11:34 EPA Interlab L06 1315 SWA
6/16/2011 11:36 EPA Interlab L06 1315 SWA
1-564
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cu SWA-L06-1315-T01-A 1 1.85E+00 U1/2
Cu SWA-L06-1315-T02-A 1 1.85E+00 U1/2
Cu SWA-L06-1315-T03-A 1 1.85E+00 U1/2
Cu SWA-L06-1315-T04-A 1 1.85E+00 U1/2
Cu SWA-L06-1315-T05-A 1 1.85E+00 U1/2
Cu SWA-L06-1315-T06-A 1 1.85E+00 U1/2
Cu SWA-L06-1315-T07-A 1 1.85E+00 U1/2
Cu SWA-L06-1315-T08-A 1 1.85E+00 U1/2
Cu SWA-L06-1315-T09-A 1 1.85E+00 U1/2
Cu SWA-L06-1315-T01-B 1 1.85E+00 U1/2
Cu SWA-L06-1315-T02-B 1 1.85E+00 U1/2
Cu SWA-L06-1315-T03-B 1 1.85E+00 U1/2
Cu SWA-L06-1315-T04-B 1 1.85E+00 U1/2
Cu SWA-L06-1315-T05-B 1 1.85E+00 U1/2
Cu SWA-L06-1315-T06-B 1 1.85E+00 U1/2
Cu SWA-L06-1315-T07-B 1 1.85E+00 U1/2
Cu SWA-L06-1315-T08-B 1 1.85E+00 U1/2
Cu SWA-L06-1315-T09-B 1 1.85E+00 U1/2
Cu SWA-L06-1315-T01-C 1 1.85E+00 U1/2
Cu SWA-L06-1315-T02-C 1 1.85E+00 U1/2
Cu SWA-L06-1315-T03-C 1 1.85E+00 U1/2
Cu SWA-L06-1315-T04-C 1 1.85E+00 U1/2
Cu SWA-L06-1315-T05-C 1 1.85E+00 U1/2
Cu SWA-L06-1315-T06-C 1 1.85E+00 U1/2
Cu SWA-L06-1315-T07-C 1 1.85E+00 U1/2
Cu SWA-L06-1315-T08-C 1 1.85E+00 U1/2
Cu SWA-L06-1315-T09-C 1 1.85E+00 U1/2
Cu SWA-L06-1315-M01-A 1 1.85E+00 U1/2
Cu SWA-L06-1315-M02-A 1 1.85E+00 U1/2
Cu SWA-L06-1315-M03-A 1 1.85E+00 U1/2
Cu SWA-L06-1315-M04-A 1 1.85E+00 U1/2
Cu SWA-L06-1315-M05-A 1 1.85E+00 U1/2
Cu SWA-L06-1315-M06-A 1 1.85E+00 U1/2
Cu SWA-L06-1315-M07-A 1 1.85E+00 U1/2
Cu SWA-L06-1315-M08-A 1 1.85E+00 U1/2
Cu SWA-L06-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 37.83 3.70 11.80
1.85E+00 18.93 3.70 11.80
1.85E+00 73.58 3.70 11.80 10000 1000
1.85E+00 35.17 3.70 11.80
1.85E+00 47.21 3.70 11.80
1.85E+00 16.68 3.70 11.80
1.85E+00 19.89 3.70 11.80
1.85E+00 46.62 3.70 11.80
1.85E+00 5.69 3.70 11.80
1.85E+00 52.32 3.70 11.80
1.85E+00 23.49 3.70 11.80
1.85E+00 27.87 3.70 11.80 10000 1000
1.85E+00 25.40 3.70 11.80
1.85E+00 30.34 3.70 11.80
1.85E+00 25.71 3.70 11.80
1.85E+00 8.66 3.70 11.80
1.85E+00 27.01 3.70 11.80
1.85E+00 6.67 3.70 11.80
1.85E+00 9.85 3.70 11.80
1.85E+00 29.10 3.70 11.80
1.85E+00 8.72 3.70 11.80 10000 1000
1.85E+00 5.49 3.70 11.80
1.85E+00 11.59 3.70 11.80
1.85E+00 33.24 3.70 11.80
1.85E+00 38.93 3.70 11.80
1.85E+00 38.64 3.70 11.80
1.85E+00 13.50 3.70 11.80
1.85E+00 38.50 3.70 11.80
1.85E+00 48.65 3.70 11.80
1.85E+00 83.82 3.70 11.80
1.85E+00 14.35 3.70 11.80
1.85E+00 51.31 3.70 11.80
1.85E+00 9.23 3.70 11.80
1.85E+00 6.57 3.70 11.80
1.85E+00 9.86 3.70 11.80
1.85E+00 15.10 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.99E+02 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.99E+02 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/201 1 11 :37 EPA Interlab L06 1315 SWA
6/16/2011 11:39 EPA Interlab L06 1315 SWA
6/16/2011 11:41 EPA Interlab L06 1315 SWA
6/16/2011 11:42 EPA Interlab L06 1315 SWA
6/16/2011 11:44 EPA Interlab L06 1315 SWA
6/16/2011 11:46 EPA Interlab L06 1315 SWA
6/16/2011 11:47 EPA Interlab L06 1315 SWA
6/16/2011 11:49 EPA Interlab L06 1315 SWA
6/16/2011 11:51 EPA Interlab L06 1315 SWA
6/16/201 1 11 :57 EPA Interlab L06 1315 SWA
6/16/2011 11:59 EPA Interlab L06 1315 SWA
6/16/2011 12:00 EPA Interlab L06 1315 SWA
6/16/2011 12:02 EPA Interlab L06 1315 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/2011 12:07 EPA Interlab L06 1315 SWA
6/16/2011 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:14 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:18 EPA Interlab L06 1315 SWA
6/16/2011 12:20 EPA Interlab L06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25 EPA Interlab L06 1315 SWA
6/16/2011 11:23 EPA Interlab L06 1315 SWA
6/16/2011 11:24 EPA Interlab L06 1315 SWA
6/16/2011 11:26 EPA Interlab L06 1315 SWA
6/16/2011 11:28 EPA Interlab L06 1315 SWA
6/16/2011 11:29 EPA Interlab L06 1315 SWA
6/16/2011 11:31 EPA Interlab L06 1315 SWA
6/16/201 1 11 :32 EPA Interlab L06 1315 SWA
6/16/2011 11:34 EPA Interlab L06 1315 SWA
6/16/2011 11:36 EPA Interlab L06 1315 SWA
1-565
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
Fe SWA-L06-1315-T01-A 1 1.27E+01
Fe SWA-L06-1315-T02-A 1 1.25E+01
Fe SWA-L06-1315-T03-A 1 7.22E+00
Fe SWA-L06-1315-T04-A 1 5.89E+00 E
Fe SWA-L06-1315-T05-A 1 3.38E+00 E
Fe SWA-L06-1315-T06-A 1 4.05E+00 E
Fe SWA-L06-1315-T07-A 1 3.65E+00 E
Fe SWA-L06-1315-T08-A 1 4.75E+00 E
Fe SWA-L06-1315-T09-A 1 5.15E+00 E
Fe SWA-L06-1315-T01-B 1 1.05E+01
Fe SWA-L06-1315-T02-B 1 1.17E+01
Fe SWA-L06-1315-T03-B 1 8.75E+00
Fe SWA-L06-1315-T04-B 1 6.58E+00
Fe SWA-L06-1315-T05-B 1 4.38E+00 E
Fe SWA-L06-1315-T06-B 1 4.24E+00 E
Fe SWA-L06-1315-T07-B 1 4.53E+00 E
Fe SWA-L06-1315-T08-B 1 3.83E+00 E
Fe SWA-L06-1315-T09-B 1 1.00E+00 U1/2
Fe SWA-L06-1315-T01-C 1 8.42E+00
Fe SWA-L06-1315-T02-C 1 1.04E+01
Fe SWA-L06-1315-T03-C 1 1.47E+01
Fe SWA-L06-1315-T04-C 1 7.12E+00
Fe SWA-L06-1315-T05-C 1 4.31E+00 E
Fe SWA-L06-1315-T06-C 1 3.78E+00 E
Fe SWA-L06-1315-T07-C 1 4.12E+00 E
Fe SWA-L06-1315-T08-C 1 4.03E+00 E
Fe SWA-L06-1315-T09-C 1 2.75E+00 E
Fe SWA-L06-1315-M01-A 1 1.00E+00 U1/2
Fe SWA-L06-1315-M02-A 1 1.00E+00 U1/2
Fe SWA-L06-1315-M03-A 1 1.00E+00 U1/2
Fe SWA-L06-1315-M04-A 1 1.00E+00 U1/2
Fe SWA-L06-1315-M05-A 1 1.00E+00 U1/2
Fe SWA-L06-1315-M06-A 1 1.00E+00 U1/2
Fe SWA-L06-1315-M07-A 1 1.00E+00 U1/2
Fe SWA-L06-1315-M08-A 1 1.00E+00 U1/2
Fe SWA-L06-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.27E+01 3.27 2.00 6.40
1.25E+01 6.68 2.00 6.40
7.22E+00 4.69 2.00 6.40 10000 1000
5.89E+00 3.54 2.00 6.40
3.38E+00 10.31 2.00 6.40
4.05E+00 7.79 2.00 6.40
3.65E+00 14.09 2.00 6.40
4.75E+00 8.21 2.00 6.40
5.15E+00 10.10 2.00 6.40
1.05E+01 8.22 2.00 6.40
1.17E+01 3.59 2.00 6.40
8.75E+00 4.33 2.00 6.40 10000 1000
6.58E+00 5.68 2.00 6.40
4.38E+00 8.54 2.00 6.40
4.24E+00 9.16 2.00 6.40
4.53E+00 5.63 2.00 6.40
3.83E+00 21.03 2.00 6.40
1.00E+00 31.87 2.00 6.40
8.42E+00 1.43 2.00 6.40
1.04E+01 2.64 2.00 6.40
1.47E+01 1.37 2.00 6.40 10000 1000
7.12E+00 2.66 2.00 6.40
4.31 E+00 13.47 2.00 6.40
3.78E+00 12.55 2.00 6.40
4.12E+00 20.95 2.00 6.40
4.03E+00 10.83 2.00 6.40
2.75E+00 5.73 2.00 6.40
1.00E+00 34.54 2.00 6.40
1.00E+00 26.39 2.00 6.40
1.00E+00 12.16 2.00 6.40
1.00E+00 8.39 2.00 6.40
1.00E+00 30.89 2.00 6.40
1.00E+00 17.40 2.00 6.40
1.00E+00 5.19 2.00 6.40
1.00E+00 46.88 2.00 6.40
1.00E+00 24.64 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.96E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.94E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/2011 11:37 EPA Interlab L06 1315SWA
6/16/2011 11:39 EPA Interlab L06 1315SWA
6/16/2011 11:41 EPA Interlab L06 1315SWA
6/16/2011 11:42 EPA Interlab L06 1315SWA
6/16/2011 11:44 EPA Interlab L06 1315SWA
6/16/2011 11:46 EPA Interlab L06 1315SWA
6/16/2011 11:47 EPA Interlab L06 1315SWA
6/16/2011 11:49 EPA Interlab L06 1315SWA
6/16/2011 11:51 EPA Interlab L06 1315SWA
6/16/201 1 1 1 :57 EPA Interlab L06 1315 SWA
6/16/2011 11:59 EPA Interlab L06 1315 SWA
6/16/2011 12:00 EPA Interlab L06 1315 SWA
6/16/2011 12:02 EPA Interlab L06 1315 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/2011 12:07 EPA Interlab L06 1315 SWA
6/16/2011 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:14 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:18 EPA Interlab L06 1315 SWA
6/16/2011 12:20 EPA Interlab L06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25 EPA Interlab L06 1315 SWA
6/16/2011 11:23 EPA Interlab L06 1315SWA
6/16/2011 11:24 EPA Interlab L06 1315SWA
6/16/2011 11:26 EPA Interlab L06 1315SWA
6/16/2011 11:28 EPA Interlab L06 1315SWA
6/16/2011 11:29 EPA Interlab L06 1315SWA
6/16/2011 11:31 EPA Interlab L06 1315SWA
6/16/2011 11:32 EPA Interlab L06 1315SWA
6/16/2011 11:34 EPA Interlab L06 1315SWA
6/16/2011 11:36 EPA Interlab L06 1315SWA
1-566
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Pb SWA-L06-1315-T01-A 1 3.40E+00 U1/2
Pb SWA-L06-1315-T02-A 1 3.40E+00 U1/2
Pb SWA-L06-1315-T03-A 1 3.40E+00 U1/2
Pb SWA-L06-1315-T04-A 1 3.40E+00 U1/2
Pb SWA-L06-1315-T05-A 1 3.40E+00 U1/2
Pb SWA-L06-1315-T06-A 1 3.40E+00 U1/2
Pb SWA-L06-1315-T07-A 1 3.40E+00 U1/2
Pb SWA-L06-1315-T08-A 1 3.40E+00 U1/2
Pb SWA-L06-1315-T09-A 1 3.40E+00 U1/2
Pb SWA-L06-1315-T01-B 1 3.40E+00 U1/2
Pb SWA-L06-1315-T02-B 1 3.40E+00 U1/2
Pb SWA-L06-1315-T03-B 1 3.40E+00 U1/2
Pb SWA-L06-1315-T04-B 1 3.40E+00 U1/2
Pb SWA-L06-1315-T05-B 1 3.40E+00 U1/2
Pb SWA-L06-1315-T06-B 1 3.40E+00 U1/2
Pb SWA-L06-1315-T07-B 1 3.40E+00 U1/2
Pb SWA-L06-1315-T08-B 1 3.40E+00 U1/2
Pb SWA-L06-1315-T09-B 1 3.40E+00 U1/2
Pb SWA-L06-1315-T01-C 1 3.40E+00 U1/2
Pb SWA-L06-1315-T02-C 1 3.40E+00 U1/2
Pb SWA-L06-1315-T03-C 1 3.40E+00 U1/2
Pb SWA-L06-1315-T04-C 1 3.40E+00 U1/2
Pb SWA-L06-1315-T05-C 1 3.40E+00 U1/2
Pb SWA-L06-1315-T06-C 1 3.40E+00 U1/2
Pb SWA-L06-1315-T07-C 1 3.40E+00 U1/2
Pb SWA-L06-1315-T08-C 1 3.40E+00 U1/2
Pb SWA-L06-1315-T09-C 1 3.40E+00 U1/2
Pb SWA-L06-1315-M01-A 1 3.40E+00 U1/2
Pb SWA-L06-1315-M02-A 1 3.40E+00 U1/2
Pb SWA-L06-1315-M03-A 1 3.40E+00 U1/2
Pb SWA-L06-1315-M04-A 1 3.40E+00 U1/2
Pb SWA-L06-1315-M05-A 1 3.40E+00 U1/2
Pb SWA-L06-1315-M06-A 1 3.40E+00 U1/2
Pb SWA-L06-1315-M07-A 1 3.40E+00 U1/2
Pb SWA-L06-1315-M08-A 1 3.40E+00 U1/2
Pb SWA-L06-1315-M09-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 13.12 6.80 21.60
3.40E+00 72.01 6.80 21.60
3.40E+00 14.76 6.80 21.60 10000 1000
3.40E+00 46.67 6.80 21.60
3.40E+00 52.56 6.80 21.60
3.40E+00 42.73 6.80 21.60
3.40E+00 20.98 6.80 21.60
3.40E+00 12.17 6.80 21.60
3.40E+00 23.90 6.80 21.60
3.40E+00 11.86 6.80 21.60
3.40E+00 45.81 6.80 21.60
3.40E+00 21.02 6.80 21.60 10000 1000
3.40E+00 36.57 6.80 21.60
3.40E+00 14.36 6.80 21.60
3.40E+00 83.06 6.80 21.60
3.40E+00 12.22 6.80 21.60
3.40E+00 41.33 6.80 21.60
3.40E+00 50.92 6.80 21.60
3.40E+00 21.22 6.80 21.60
3.40E+00 64.99 6.80 21.60
3.40E+00 45.00 6.80 21.60 10000 1000
3.40E+00 40.76 6.80 21.60
3.40E+00 28.56 6.80 21.60
3.40E+00 32.96 6.80 21.60
3.40E+00 134.45 6.80 21.60
3.40E+00 87.01 6.80 21.60
3.40E+00 32.72 6.80 21.60
3.40E+00 26.38 6.80 21.60
3.40E+00 63.14 6.80 21.60
3.40E+00 17.96 6.80 21.60
3.40E+00 69.04 6.80 21.60
3.40E+00 32.29 6.80 21.60
3.40E+00 69.89 6.80 21.60
3.40E+00 54.83 6.80 21.60
3.40E+00 43.59 6.80 21.60
3.40E+00 175.10 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.27E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.26E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.21 E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/2011 11:37 EPA Interlab L06 1315SWA
6/16/2011 11:39 EPA Interlab L06 1315SWA
6/16/2011 11:41 EPA Interlab L06 1315 SWA
6/16/2011 11:42 EPA Interlab L06 1315SWA
6/16/2011 11:44 EPA Interlab L06 1315SWA
6/16/2011 11:46 EPA Interlab L06 1315 SWA
6/16/2011 11:47 EPA Interlab L06 1315 SWA
6/16/2011 11:49 EPA Interlab L06 1315 SWA
6/16/2011 11:51 EPA Interlab L06 1315 SWA
6/16/2011 11:57 EPA Interlab L06 1315 SWA
6/16/2011 11:59 EPA Interlab L06 1315 SWA
6/16/2011 12:00 EPA Interlab L06 1315 SWA
6/16/201 1 12:02 EPA Interlab L06 1315 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/2011 12:07 EPA Interlab L06 1315 SWA
6/16/2011 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:14 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:18 EPA Interlab L06 1315 SWA
6/16/2011 12:20 EPA Interlab L06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25 EPA Interlab L06 1315 SWA
6/16/2011 11:23 EPA Interlab L06 1315 SWA
6/16/2011 11:24 EPA Interlab L06 1315 SWA
6/16/2011 11:26 EPA Interlab L06 1315 SWA
6/16/2011 11:28 EPA Interlab L06 1315 SWA
6/16/2011 11:29 EPA Interlab L06 1315 SWA
6/16/2011 11:31 EPA Interlab L06 1315 SWA
6/16/201 1 1 1:32 EPA Interlab L06 1315 SWA
6/16/2011 11:34 EPA Interlab L06 1315 SWA
6/16/2011 11:36 EPA Interlab L06 131 5 SWA
1-567
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Li SWA-L06-1315-T01-A 1 9.50E-01 U1/2
Li SWA-L06-1315-T02-A 1 9.50E-01 U1/2
Li SWA-L06-1315-T03-A 1 9.50E-01 U1/2
Li SWA-L06-1315-T04-A 1 9.50E-01 U1/2
Li SWA-L06-1315-T05-A 1 9.50E-01 U1/2
Li SWA-L06-1315-T06-A 1 9.50E-01 U1/2
Li SWA-L06-1315-T07-A 1 9.50E-01 U1/2
Li SWA-L06-1315-T08-A 1 9.50E-01 U1/2
Li SWA-L06-1315-T09-A 1 9.50E-01 U1/2
Li SWA-L06-1315-T01-B 1 9.50E-01 U1/2
Li SWA-L06-1315-T02-B 1 9.50E-01 U1/2
Li SWA-L06-1315-T03-B 1 9.50E-01 U1/2
Li SWA-L06-1315-T04-B 1 9.50E-01 U1/2
Li SWA-L06-1315-T05-B 1 9.50E-01 U1/2
Li SWA-L06-1315-T06-B 1 9.50E-01 U1/2
Li SWA-L06-1315-T07-B 1 9.50E-01 U1/2
Li SWA-L06-1315-T08-B 1 9.50E-01 U1/2
Li SWA-L06-1315-T09-B 1 9.50E-01 U1/2
Li SWA-L06-1315-T01-C 1 9.50E-01 U1/2
Li SWA-L06-1315-T02-C 1 9.50E-01 U1/2
Li SWA-L06-1315-T03-C 1 9.50E-01 U1/2
Li SWA-L06-1315-T04-C 1 9.50E-01 U1/2
Li SWA-L06-1315-T05-C 1 9.50E-01 U1/2
Li SWA-L06-1315-T06-C 1 9.50E-01 U1/2
Li SWA-L06-1315-T07-C 1 9.50E-01 U1/2
Li SWA-L06-1315-T08-C 1 9.50E-01 U1/2
Li SWA-L06-1315-T09-C 1 9.50E-01 U1/2
Li SWA-L06-1315-M01-A 1 9.50E-01 U1/2
Li SWA-L06-1315-M02-A 1 9.50E-01 U1/2
Li SWA-L06-1315-M03-A 1 9.50E-01 U1/2
Li SWA-L06-1315-M04-A 1 9.50E-01 U1/2
Li SWA-L06-1315-M05-A 1 9.50E-01 U1/2
Li SWA-L06-1315-M06-A 1 9.50E-01 U1/2
Li SWA-L06-1315-M07-A 1 9.50E-01 U1/2
Li SWA-L06-1315-M08-A 1 9.50E-01 U1/2
Li SWA-L06-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 4.44 1.90 6.00
9.50E-01 5.94 1.90 6.00
9.50E-01 32.55 1.90 6.00 10000 1000
9.50E-01 15.45 1.90 6.00
9.50E-01 7.26 1.90 6.00
9.50E-01 11.25 1.90 6.00
9.50E-01 14.61 1.90 6.00
9.50E-01 15.78 1.90 6.00
9.50E-01 17.33 1.90 6.00
9.50E-01 44.31 1.90 6.00
9.50E-01 35.28 1.90 6.00
9.50E-01 65.98 1.90 6.00 10000 1000
9.50E-01 19.99 1.90 6.00
9.50E-01 19.54 1.90 6.00
9.50E-01 16.98 1.90 6.00
9.50E-01 18.05 1.90 6.00
9.50E-01 16.32 1.90 6.00
9.50E-01 15.82 1.90 6.00
9.50E-01 46.87 1.90 6.00
9.50E-01 13.47 1.90 6.00
9.50E-01 59.35 1.90 6.00 10000 1000
9.50E-01 19.91 1.90 6.00
9.50E-01 8.69 1.90 6.00
9.50E-01 20.26 1.90 6.00
9.50E-01 8.51 1.90 6.00
9.50E-01 18.30 1.90 6.00
9.50E-01 18.47 1.90 6.00
9.50E-01 22.36 1.90 6.00
9.50E-01 14.49 1.90 6.00
9.50E-01 5.80 1.90 6.00
9.50E-01 37.14 1.90 6.00
9.50E-01 30.89 1.90 6.00
9.50E-01 24.30 1.90 6.00
9.50E-01 6.66 1.90 6.00
9.50E-01 28.95 1.90 6.00
9.50E-01 37.06 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.87E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.80E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.78E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/201 1 11 :37 EPA Interlab L06 1315 SWA
6/16/2011 11:39 EPA Interlab L06 1315 SWA
6/16/2011 11:41 EPA Interlab L06 1315 SWA
6/16/2011 11:42 EPA Interlab L06 1315 SWA
6/16/2011 11:44 EPA Interlab L06 1315 SWA
6/16/2011 11:46 EPA Interlab L06 1315 SWA
6/16/2011 11:47 EPA Interlab L06 1315 SWA
6/16/2011 11:49 EPA Interlab L06 1315 SWA
6/16/2011 11:51 EPA Interlab L06 1315 SWA
6/16/201 1 11 :57 EPA Interlab L06 1315 SWA
6/16/2011 11:59 EPA Interlab L06 1315 SWA
6/16/2011 12:00 EPA Interlab L06 1315 SWA
6/16/2011 12:02 EPA Interlab L06 1315 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/2011 12:07 EPA Interlab L06 1315 SWA
6/16/2011 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:14 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:18 EPA Interlab L06 1315 SWA
6/16/2011 12:20 EPA Interlab L06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25 EPA Interlab L06 1315 SWA
6/16/2011 11:23 EPA Interlab L06 1315 SWA
6/16/2011 11:24 EPA Interlab L06 1315 SWA
6/16/2011 11:26 EPA Interlab L06 1315 SWA
6/16/2011 11:28 EPA Interlab L06 1315 SWA
6/16/2011 11:29 EPA Interlab L06 1315 SWA
6/16/2011 11:31 EPA Interlab L06 1315 SWA
6/16/201 1 11 :32 EPA Interlab L06 1315 SWA
6/16/2011 11:34 EPA Interlab L06 1315 SWA
6/16/2011 11:36 EPA Interlab L06 1315 SWA
1-568
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Mn SWA-L06-1315-T01-A 1 1.00E+00 U1/2
Mn SWA-L06-1315-T02-A 1 1.00E+00 U1/2
Mn SWA-L06-1315-T03-A 1 1.00E+00 U1/2
Mn SWA-L06-1315-T04-A 1 1.00E+00 U1/2
Mn SWA-L06-1315-T05-A 1 1.00E+00 U1/2
Mn SWA-L06-1315-T06-A 1 1.00E+00 U1/2
Mn SWA-L06-1315-T07-A 1 1.00E+00 U1/2
Mn SWA-L06-1315-T08-A 1 1.00E+00 U1/2
Mn SWA-L06-1315-T09-A 1 1.00E+00 U1/2
Mn SWA-L06-1315-T01-B 1 1.00E+00 U1/2
Mn SWA-L06-1315-T02-B 1 1.00E+00 U1/2
Mn SWA-L06-1315-T03-B 1 1.00E+00 U1/2
Mn SWA-L06-1315-T04-B 1 1.00E+00 U1/2
Mn SWA-L06-1315-T05-B 1 1.00E+00 U1/2
Mn SWA-L06-1315-T06-B 1 1.00E+00 U1/2
Mn SWA-L06-1315-T07-B 1 1.00E+00 U1/2
Mn SWA-L06-1315-T08-B 1 1.00E+00 U1/2
Mn SWA-L06-1315-T09-B 1 1.00E+00 U1/2
Mn SWA-L06-1315-T01-C 1 1.00E+00 U1/2
Mn SWA-L06-1315-T02-C 1 1.00E+00 U1/2
Mn SWA-L06-1315-T03-C 1 1.00E+00 U1/2
Mn SWA-L06-1315-T04-C 1 1.00E+00 U1/2
Mn SWA-L06-1315-T05-C 1 1.00E+00 U1/2
Mn SWA-L06-1315-T06-C 1 1.00E+00 U1/2
Mn SWA-L06-1315-T07-C 1 1.00E+00 U1/2
Mn SWA-L06-1315-T08-C 1 1.00E+00 U1/2
Mn SWA-L06-1315-T09-C 1 1.00E+00 U1/2
Mn SWA-L06-1315-M01-A 1 1.00E+00 U1/2
Mn SWA-L06-1315-M02-A 1 1.00E+00 U1/2
Mn SWA-L06-1315-M03-A 1 1.00E+00 U1/2
Mn SWA-L06-1315-M04-A 1 1.00E+00 U1/2
Mn SWA-L06-1315-M05-A 1 1.00E+00 U1/2
Mn SWA-L06-1315-M06-A 1 1.00E+00 U1/2
Mn SWA-L06-1315-M07-A 1 1.00E+00 U1/2
Mn SWA-L06-1315-M08-A 1 1.00E+00 U1/2
Mn SWA-L06-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 19.55 2.00 6.40
1.00E+00 20.14 2.00 6.40
1.00E+00 48.72 2.00 6.40 10000 1000
1.00E+00 57.58 2.00 6.40
1.00E+00 35.23 2.00 6.40
1.00E+00 18.35 2.00 6.40
1.00E+00 40.65 2.00 6.40
1.00E+00 28.12 2.00 6.40
1.00E+00 45.37 2.00 6.40
1.00E+00 4.24 2.00 6.40
1.00E+00 36.74 2.00 6.40
1.00E+00 16.23 2.00 6.40 10000 1000
1.00E+00 42.35 2.00 6.40
1.00E+00 23.08 2.00 6.40
1.00E+00 16.18 2.00 6.40
1.00E+00 28.52 2.00 6.40
1.00E+00 50.13 2.00 6.40
1.00E+00 45.06 2.00 6.40
1.00E+00 39.10 2.00 6.40
1.00E+00 29.74 2.00 6.40
1.00E+00 50.19 2.00 6.40 10000 1000
1.00E+00 30.72 2.00 6.40
1.00E+00 23.54 2.00 6.40
1.00E+00 47.41 2.00 6.40
1.00E+00 13.69 2.00 6.40
1.00E+00 43.98 2.00 6.40
1.00E+00 9.24 2.00 6.40
1.00E+00 12.91 2.00 6.40
1.00E+00 22.00 2.00 6.40
1.00E+00 9.55 2.00 6.40
1.00E+00 20.86 2.00 6.40
1.00E+00 13.57 2.00 6.40
1.00E+00 2.27 2.00 6.40
1.00E+00 27.31 2.00 6.40
1.00E+00 14.51 2.00 6.40
1.00E+00 23.26 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/2011 11:37 EPA Interlab L06 1315SWA
6/16/2011 11:39 EPA Interlab L06 1315SWA
6/16/2011 11:41 EPA Interlab L06 1315SWA
6/16/2011 11:42 EPA Interlab L06 1315SWA
6/16/2011 11:44 EPA Interlab L06 1315 SWA
6/16/2011 11:46 EPA Interlab L06 1315 SWA
6/16/2011 11:47 EPA Interlab L06 1315 SWA
6/16/2011 11:49 EPA Interlab L06 1315 SWA
6/16/2011 11:51 EPA Interlab L06 1315 SWA
6/16/2011 11:57 EPA Interlab L06 1315 SWA
6/1 6/201 1 1 1 :59 EPA Interlab L06 1 31 5 SWA
6/16/201 1 12:00 EPA Interlab L06 1315 SWA
6/16/2011 1 2:02 EPA Interlab L06 131 5 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/2011 12:07 EPA Interlab L06 1315 SWA
6/16/201 1 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:1 4 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:1 8 EPA Interlab L06 1315 SWA
6/16/2011 12:20EPAInterlabl_06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25EPAInterlabl_06 1315 SWA
6/16/201 1 1 1 :23 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :24 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :26 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :28 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :29 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :31 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :32 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :34 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :36 EPA Interlab L06 1315 SWA
1-569
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Mg SWA-L06-1315-T01-A 1 2.07E+01
Mg SWA-L06-1315-T02-A 1 1.37E+01
Mg SWA-L06-1315-T03-A 1 3.49E+01
Mg SWA-L06-1315-T04-A 1 2.67E+01
Mg SWA-L06-1315-T05-A 1 1.35E+01
Mg SWA-L06-1315-T06-A 1 1.06E+01
Mg SWA-L06-1315-T07-A 1 1.65E+01
Mg SWA-L06-1315-T08-A 1 6.19E+01
Mg SWA-L06-1315-T09-A 1 4.17E+01
Mg SWA-L06-1315-T01-B 1 1.16E+01
Mg SWA-L06-1315-T02-B 1 3.44E+01
Mg SWA-L06-1315-T03-B 1 4.17E+01
Mg SWA-L06-1315-T04-B 1 1.68E+01
Mg SWA-L06-1315-T05-B 1 2.07E+01
Mg SWA-L06-1315-T06-B 1 2.50E+01
Mg SWA-L06-1315-T07-B 1 2.45E+01
Mg SWA-L06-1315-T08-B 1 5.94E+01
Mg SWA-L06-1315-T09-B 1 3.45E+01
Mg SWA-L06-1315-T01-C 1 1.28E+01
Mg SWA-L06-1315-T02-C 1 2.61E+01
Mg SWA-L06-1315-T03-C 1 5.42E+01
Mg SWA-L06-1315-T04-C 1 2.78E+01
Mg SWA-L06-1315-T05-C 1 2.36E+01
Mg SWA-L06-1315-T06-C 1 3.19E+01
Mg SWA-L06-1315-T07-C 1 2.54E+01
Mg SWA-L06-1315-T08-C 1 7.26E+01
Mg SWA-L06-1315-T09-C 1 3.78E+01
Mg SWA-L06-1315-M01-A 1 1.78E+01
Mg SWA-L06-1315-M02-A 1 1.79E+01
Mg SWA-L06-1315-M03-A 1 1.78E+01
Mg SWA-L06-1315-M04-A 1 2.35E+01
Mg SWA-L06-1315-M05-A 1 2.02E+01
Mg SWA-L06-1315-M06-A 1 2.59E+01
Mg SWA-L06-1315-M07-A 1 2.29E+01
Mg SWA-L06-1315-M08-A 1 1.43E+01
Mg SWA-L06-1315-M09-A 1 2.42E+01
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.07E+01 1.63 1.00 3.18
1.37E+01 4.73 1.00 3.18
3.49E+01 1.99 1.00 3.18 10000 1000
2.67E+01 3.71 1.00 3.18
1.35E+01 7.86 1.00 3.18
1.06E+01 9.12 1.00 3.18
1.65E+01 4.26 1.00 3.18
6.19E+01 1.50 1.00 3.18
4.17E+01 1.24 1.00 3.18
1.16E+01 3.16 1.00 3.18
3.44E+01 2.47 1.00 3.18
4.17E+01 6.11 1.00 3.18 10000 1000
1.68E+01 3.54 1.00 3.18
2.07E+01 6.87 1.00 3.18
2.50E+01 3.45 1.00 3.18
2.45E+01 4.76 1.00 3.18
5.94E+01 1.22 1.00 3.18
3.45E+01 5.52 1.00 3.18
1.28E+01 4.54 1.00 3.18
2.61E+01 2.12 1.00 3.18
5.42E+01 8.95 1.00 3.18 10000 1000
2.78E+01 7.90 1.00 3.18
2.36E+01 1.78 1.00 3.18
3.19E+01 1.88 1.00 3.18
2.54E+01 2.79 1.00 3.18
7.26E+01 14.43 1.00 3.18
3.78E+01 1.99 1.00 3.18
1.78E+01 2.89 1.00 3.18
1.79E+01 2.66 1.00 3.18
1.78E+01 1.84 1.00 3.18
2.35E+01 0.74 1.00 3.18
2.02E+01 4.80 1.00 3.18
2.59E+01 3.49 1.00 3.18
2.29E+01 11.87 1.00 3.18
1.43E+01 1.81 1.00 3.18
2.42E+01 5.74 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.03E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/2011 11:37 EPA Interlab L06 1315SWA
6/16/2011 11:39 EPA Interlab L06 1315SWA
6/16/2011 11:41 EPA Interlab L06 1315SWA
6/16/2011 11:42 EPA Interlab L06 1315 SWA
6/16/2011 11:44 EPA Interlab L06 1315 SWA
6/16/2011 11:46 EPA Interlab L06 1315 SWA
6/16/2011 11:47 EPA Interlab L06 1315 SWA
6/16/2011 11:49 EPA Interlab L06 1315 SWA
6/16/2011 11:51 EPA Interlab L06 1315 SWA
6/1 6/201 1 1 1 :57 EPA Interlab L06 1 31 5 SWA
6/16/2011 11:59 EPA Interlab L06 131 5 SWA
6/16/201 1 12:00 EPA Interlab L06 1315 SWA
6/16/2011 1 2:02 EPA Interlab L06 131 5 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/201 1 12:07 EPA Interlab L06 1315 SWA
6/16/2011 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:1 4 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:1 8 EPA Interlab L06 1315 SWA
6/16/2011 12:20EPAInterlabl_06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25EPAInterlabl_06 1315 SWA
6/16/201 1 1 1 :23 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :24 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :26 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :28 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :29 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :31 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :32 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :34 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :36 EPA Interlab L06 1315 SWA
1-570
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Mo SWA-L06-1315-T01-A 1 7.21E+00
Mo SWA-L06-1315-T02-A 1 7.89E+00
Mo SWA-L06-1315-T03-A 1 4.50E+00
Mo SWA-L06-1315-T04-A 1 1.13E+01
Mo SWA-L06-1315-T05-A 1 7.64E+00
Mo SWA-L06-1315-T06-A 1 9.01 E+00
Mo SWA-L06-1315-T07-A 1 6.88E+00
Mo SWA-L06-1315-T08-A 1 5.28E+00
Mo SWA-L06-1315-T09-A 1 4.67E+00
Mo SWA-L06-1315-T01-B 1 6.82E+00
Mo SWA-L06-1315-T02-B 1 9.31 E+00
Mo SWA-L06-1315-T03-B 1 6.07E+00
Mo SWA-L06-1315-T04-B 1 1.28E+01
Mo SWA-L06-1315-T05-B 1 9.73E+00
Mo SWA-L06-1315-T06-B 1 9.95E+00
Mo SWA-L06-1315-T07-B 1 6.99E+00
Mo SWA-L06-1315-T08-B 1 3.74E+00 E
Mo SWA-L06-1315-T09-B 1 5.86E+00
Mo SWA-L06-1315-T01-C 1 6.54E+00
Mo SWA-L06-1315-T02-C 1 9.49E+00
Mo SWA-L06-1315-T03-C 1 7.50E+00
Mo SWA-L06-1315-T04-C 1 1.61E+01
Mo SWA-L06-1315-T05-C 1 9.97E+00
Mo SWA-L06-1315-T06-C 1 1.20E+01
Mo SWA-L06-1315-T07-C 1 7.71E+00
Mo SWA-L06-1315-T08-C 1 4.48E+00
Mo SWA-L06-1315-T09-C 1 6.75E+00
Mo SWA-L06-1315-M01-A 1 6.00E-01 U1/2
Mo SWA-L06-1315-M02-A 1 6.00E-01 U1/2
Mo SWA-L06-1315-M03-A 1 6.00E-01 U1/2
Mo SWA-L06-1315-M04-A 1 6.00E-01 U1/2
Mo SWA-L06-1315-M05-A 1 6.00E-01 U1/2
Mo SWA-L06-1315-M06-A 1 6.00E-01 U1/2
Mo SWA-L06-1315-M07-A 1 6.00E-01 U1/2
Mo SWA-L06-1315-M08-A 1 6.00E-01 U1/2
Mo SWA-L06-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.21 E+00 8.91 1.20 3.82
7.89E+00 8.98 1.20 3.82
4.50E+00 0.43 1.20 3.82 10000 1000
1.13E+01 8.71 1.20 3.82
7.64E+00 9.37 1.20 3.82
9.01E+00 7.95 1.20 3.82
6.88E+00 0.14 1.20 3.82
5.28E+00 10.88 1.20 3.82
4.67E+00 0.24 1.20 3.82
6.82E+00 0.26 1.20 3.82
9.31E+00 0.12 1.20 3.82
6.07E+00 1.47 1.20 3.82 10000 1000
1.28E+01 8.22 1.20 3.82
9.73E+00 0.10 1.20 3.82
9.95E+00 0.14 1.20 3.82
6.99E+00 14.52 1.20 3.82
3.74E+00 22.08 1.20 3.82
5.86E+00 1.73 1.20 3.82
6.54E+00 0.11 1.20 3.82
9.49E+00 7.67 1.20 3.82
7.50E+00 0.15 1.20 3.82 10000 1000
1.61E+01 0.11 1.20 3.82
9.97E+00 7.96 1.20 3.82
1.20E+01 1.68 1.20 3.82
7.71E+00 0.22 1.20 3.82
4.48E+00 0.35 1.20 3.82
6.75E+00 0.15 1.20 3.82
6.00E-01 0.74 1.20 3.82
6.00E-01 23.11 1.20 3.82
6.00E-01 0.84 1.20 3.82
6.00E-01 17.09 1.20 3.82
6.00E-01 14.64 1.20 3.82
6.00E-01 0.34 1.20 3.82
6.00E-01 0.23 1.20 3.82
6.00E-01 22.54 1.20 3.82
6.00E-01 0.60 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/2011 11:37 EPA Interlab L06 1315SWA
6/16/2011 11:39 EPA Interlab L06 1315SWA
6/16/2011 11:41 EPA Interlab L06 1315SWA
6/16/2011 11:42 EPA Interlab L06 1315 SWA
6/16/2011 11:44 EPA Interlab L06 1315 SWA
6/16/2011 11:46 EPA Interlab L06 1315 SWA
6/16/2011 11:47 EPA Interlab L06 1315 SWA
6/16/2011 11:49 EPA Interlab L06 1315 SWA
6/16/2011 11:51 EPA Interlab L06 1315 SWA
6/1 6/201 1 1 1 :57 EPA Interlab L06 1 31 5 SWA
6/16/2011 11:59 EPA Interlab L06 131 5 SWA
6/16/201 1 12:00 EPA Interlab L06 1315 SWA
6/16/2011 1 2:02 EPA Interlab L06 131 5 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/201 1 12:07 EPA Interlab L06 1315 SWA
6/16/201 1 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:1 4 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:1 8 EPA Interlab L06 1315 SWA
6/16/2011 12:20EPAInterlabl_06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25EPAInterlabl_06 1315 SWA
6/16/201 1 1 1 :23 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :24 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :26 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :28 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :29 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :31 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :32 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :34 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :36 EPA Interlab L06 1315 SWA
1-571
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ni SWA-L06-1315-T01-A 1 9.00E-01 U1/2
Ni SWA-L06-1315-T02-A 1 9.00E-01 U1/2
Ni SWA-L06-1315-T03-A 1 9.00E-01 U1/2
Ni SWA-L06-1315-T04-A 1 9.00E-01 U1/2
Ni SWA-L06-1315-T05-A 1 9.00E-01 U1/2
Ni SWA-L06-1315-T06-A 1 9.00E-01 U1/2
Ni SWA-L06-1315-T07-A 1 9.00E-01 U1/2
Ni SWA-L06-1315-T08-A 1 9.00E-01 U1/2
Ni SWA-L06-1315-T09-A 1 9.00E-01 U1/2
Ni SWA-L06-1315-T01-B 1 9.00E-01 U1/2
Ni SWA-L06-1315-T02-B 1 9.00E-01 U1/2
Ni SWA-L06-1315-T03-B 1 9.00E-01 U1/2
Ni SWA-L06-1315-T04-B 1 9.00E-01 U1/2
Ni SWA-L06-1315-T05-B 1 9.00E-01 U1/2
Ni SWA-L06-1315-T06-B 1 9.00E-01 U1/2
Ni SWA-L06-1315-T07-B 1 9.00E-01 U1/2
Ni SWA-L06-1315-T08-B 1 9.00E-01 U1/2
Ni SWA-L06-1315-T09-B 1 9.00E-01 U1/2
Ni SWA-L06-1315-T01-C 1 9.00E-01 U1/2
Ni SWA-L06-1315-T02-C 1 9.00E-01 U1/2
Ni SWA-L06-1315-T03-C 1 9.00E-01 U1/2
Ni SWA-L06-1315-T04-C 1 9.00E-01 U1/2
Ni SWA-L06-1315-T05-C 1 9.00E-01 U1/2
Ni SWA-L06-1315-T06-C 1 9.00E-01 U1/2
Ni SWA-L06-1315-T07-C 1 9.00E-01 U1/2
Ni SWA-L06-1315-T08-C 1 9.00E-01 U1/2
Ni SWA-L06-1315-T09-C 1 9.00E-01 U1/2
Ni SWA-L06-1315-M01-A 1 9.00E-01 U1/2
Ni SWA-L06-1315-M02-A 1 9.00E-01 U1/2
Ni SWA-L06-1315-M03-A 1 9.00E-01 U1/2
Ni SWA-L06-1315-M04-A 1 9.00E-01 U1/2
Ni SWA-L06-1315-M05-A 1 9.00E-01 U1/2
Ni SWA-L06-1315-M06-A 1 9.00E-01 U1/2
Ni SWA-L06-1315-M07-A 1 9.00E-01 U1/2
Ni SWA-L06-1315-M08-A 1 9.00E-01 U1/2
Ni SWA-L06-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 18.22 1.80 5.70
9.00E-01 17.95 1.80 5.70
9.00E-01 32.88 1.80 5.70 10000 1000
9.00E-01 11.57 1.80 5.70
9.00E-01 43.18 1.80 5.70
9.00E-01 45.31 1.80 5.70
9.00E-01 31.73 1.80 5.70
9.00E-01 68.84 1.80 5.70
9.00E-01 10.95 1.80 5.70
9.00E-01 68.12 1.80 5.70
9.00E-01 38.01 1.80 5.70
9.00E-01 10.90 1.80 5.70 10000 1000
9.00E-01 30.11 1.80 5.70
9.00E-01 80.37 1.80 5.70
9.00E-01 27.42 1.80 5.70
9.00E-01 12.51 1.80 5.70
9.00E-01 57.83 1.80 5.70
9.00E-01 60.70 1.80 5.70
9.00E-01 96.19 1.80 5.70
9.00E-01 43.52 1.80 5.70
9.00E-01 15.86 1.80 5.70 10000 1000
9.00E-01 10.61 1.80 5.70
9.00E-01 35.60 1.80 5.70
9.00E-01 22.65 1.80 5.70
9.00E-01 20.43 1.80 5.70
9.00E-01 51.61 1.80 5.70
9.00E-01 25.20 1.80 5.70
9.00E-01 7.80 1.80 5.70
9.00E-01 75.83 1.80 5.70
9.00E-01 54.20 1.80 5.70
9.00E-01 37.68 1.80 5.70
9.00E-01 12.73 1.80 5.70
9.00E-01 52.57 1.80 5.70
9.00E-01 54.41 1.80 5.70
9.00E-01 50.13 1.80 5.70
9.00E-01 14.96 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.93E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.89E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.91 E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/201 1 11 :37 EPA Interlab L06 1315 SWA
6/16/2011 11:39 EPA Interlab L06 1315 SWA
6/16/2011 11:41 EPA Interlab L06 1315 SWA
6/16/2011 11:42 EPA Interlab L06 1315 SWA
6/16/2011 11:44 EPA Interlab L06 1315 SWA
6/16/2011 11:46 EPA Interlab L06 1315 SWA
6/16/2011 11:47 EPA Interlab L06 1315 SWA
6/16/2011 11:49 EPA Interlab L06 1315 SWA
6/16/2011 11:51 EPA Interlab L06 1315 SWA
6/16/201 1 11 :57 EPA Interlab L06 1315 SWA
6/16/2011 11:59 EPA Interlab L06 1315 SWA
6/16/2011 12:00 EPA Interlab L06 1315 SWA
6/16/2011 12:02 EPA Interlab L06 1315 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/2011 12:07 EPA Interlab L06 1315 SWA
6/16/2011 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:14 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:18 EPA Interlab L06 1315 SWA
6/16/2011 12:20 EPA Interlab L06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25 EPA Interlab L06 1315 SWA
6/16/2011 11:23 EPA Interlab L06 1315 SWA
6/16/2011 11:24 EPA Interlab L06 1315 SWA
6/16/2011 11:26 EPA Interlab L06 1315 SWA
6/16/2011 11:28 EPA Interlab L06 1315 SWA
6/16/2011 11:29 EPA Interlab L06 1315 SWA
6/16/2011 11:31 EPA Interlab L06 1315 SWA
6/16/201 1 11 :32 EPA Interlab L06 1315 SWA
6/16/2011 11:34 EPA Interlab L06 1315 SWA
6/16/2011 11:36 EPA Interlab L06 1315 SWA
1-572
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
P SWA-L06-1315-T01-A 1 2.31E+01
P SWA-L06-1315-T02-A 1 8.43E+00 E
P SWA-L06-1315-T03-A 1 8.05E+00 E
P SWA-L06-1315-T04-A 1 1.85E+00 U1/2
P SWA-L06-1315-T05-A 1 1.85E+00 U1/2
P SWA-L06-1315-T06-A 1 1.30E+01
P SWA-L06-1315-T07-A 1 1.74E+01
P SWA-L06-1315-T08-A 1 8.06E+00 E
P SWA-L06-1315-T09-A 1 1.85E+00 U1/2
P SWA-L06-1315-T01-B 1 2.78E+01
P SWA-L06-1315-T02-B 1 1.10E+01 E
P SWA-L06-1315-T03-B 1 1.69E+01
P SWA-L06-1315-T04-B 1 2.24E+01
P SWA-L06-1315-T05-B 1 1.85E+00 U1/2
P SWA-L06-1315-T06-B 1 1.44E+01
P SWA-L06-1315-T07-B 1 1.71E+01
P SWA-L06-1315-T08-B 1 6.38E+00 E
P SWA-L06-1315-T09-B 1 6.76E+00 E
P SWA-L06-1315-T01-C 1 2.39E+01
P SWA-L06-1315-T02-C 1 2.38E+01
P SWA-L06-1315-T03-C 1 1.31E+01
P SWA-L06-1315-T04-C 1 2.45E+01
P SWA-L06-1315-T05-C 1 1.86E+01
P SWA-L06-1315-T06-C 1 8.09E+00 E
P SWA-L06-1315-T07-C 1 8.28E+00 E
P SWA-L06-1315-T08-C 1 1.85E+00 U1/2
P SWA-L06-1315-T09-C 1 6.89E+00 E
P SWA-L06-1315-M01-A 1 1.85E+00 U1/2
P SWA-L06-1315-M02-A 1 1.85E+00 U1/2
P SWA-L06-1315-M03-A 1 1.85E+00 U1/2
P SWA-L06-1315-M04-A 1 1.85E+00 U1/2
P SWA-L06-1315-M05-A 1 1.85E+00 U1/2
P SWA-L06-1315-M06-A 1 1.85E+00 U1/2
P SWA-L06-1315-M07-A 1 1.85E+00 U1/2
P SWA-L06-1315-M08-A 1 1.85E+00 U1/2
P SWA-L06-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.31 E+01 3.43 3.70 11.80
8.43E+00 17.69 3.70 11.80
8.05E+00 12.97 3.70 11.80 10000 1000
1.85E+00 15.32 3.70 11.80
1.85E+00 18.06 3.70 11.80
1.30E+01 3.23 3.70 11.80
1.74E+01 13.96 3.70 11.80
8.06E+00 13.66 3.70 11.80
1.85E+00 27.04 3.70 11.80
2.78E+01 2.47 3.70 11.80
1.10E+01 12.31 3.70 11.80
1.69E+01 5.91 3.70 11.80 10000 1000
2.24E+01 29.63 3.70 11.80
1.85E+00 47.14 3.70 11.80
1.44E+01 55.86 3.70 11.80
1.71E+01 4.20 3.70 11.80
6.38E+00 17.63 3.70 11.80
6.76E+00 45.27 3.70 11.80
2.39E+01 2.45 3.70 11.80
2.38E+01 2.65 3.70 11.80
1.31E+01 10.26 3.70 11.80 10000 1000
2.45E+01 3.41 3.70 11.80
1.86E+01 3.50 3.70 11.80
8.09E+00 17.68 3.70 11.80
8.28E+00 23.20 3.70 11.80
1.85E+00 48.98 3.70 11.80
6.89E+00 9.56 3.70 11.80
1.85E+00 4.26 3.70 11.80
1.85E+00 8.90 3.70 11.80
1.85E+00 11.68 3.70 11.80
1.85E+00 8.08 3.70 11.80
1.85E+00 6.45 3.70 11.80
1.85E+00 14.38 3.70 11.80
1.85E+00 9.63 3.70 11.80
1.85E+00 32.17 3.70 11.80
1.85E+00 15.22 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/2011 11:37 EPA Interlab L06 1315SWA
6/16/2011 11:39 EPA Interlab L06 1315SWA
6/16/2011 11:41 EPA Interlab L06 1315 SWA
6/16/2011 11:42 EPA Interlab L06 1315SWA
6/16/2011 11:44 EPA Interlab L06 1315SWA
6/16/2011 11:46 EPA Interlab L06 1315 SWA
6/16/2011 11:47 EPA Interlab L06 1315 SWA
6/16/2011 11:49 EPA Interlab L06 1315 SWA
6/16/2011 11:51 EPA Interlab L06 1315 SWA
6/16/2011 11:57 EPA Interlab L06 1315 SWA
6/16/2011 11:59 EPA Interlab L06 1315 SWA
6/16/2011 12:00 EPA Interlab L06 1315 SWA
6/16/201 1 12:02 EPA Interlab L06 1315 SWA
6/16/201 1 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/2011 12:07 EPA Interlab L06 1315 SWA
6/16/2011 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:14 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 1 2: 1 7 EPA Interlab L06 131 5 SWA
6/16/2011 12:18 EPA Interlab L06 1315 SWA
6/16/2011 12:20 EPA Interlab L06 1315 SWA
6/16/2011 1 2:22 EPA Interlab L06 131 5 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25 EPA Interlab L06 1315 SWA
6/16/2011 11:23 EPA Interlab L06 1315 SWA
6/16/201 1 1 1:24 EPA Interlab L06 1315 SWA
6/16/201 1 1 1:26 EPA Interlab L06 1315 SWA
6/16/2011 11:28 EPA Interlab L06 1315 SWA
6/16/2011 11:29 EPA Interlab L06 1315 SWA
6/16/2011 11:31 EPA Interlab L06 1315 SWA
6/1 6/201 1 1 1 :32 EPA Interlab L06 1 31 5 SWA
6/1 6/201 1 1 1 :34 EPA Interlab L06 1 31 5 SWA
6/1 6/201 1 1 1 :36 EPA Interlab L06 1 31 5 SWA
1-573
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
K SWA-L06-1315-T01-A 1 8.54E+03
K SWA-L06-1315-T02-A 1 2.64E+04
K SWA-L06-1315-T03-A 1 1.20E+04
K SWA-L06-1315-T04-A 1 3.52E+04
K SWA-L06-1315-T05-A 1 2.75E+04
K SWA-L06-1315-T06-A 1 3.44E+04
K SWA-L06-1315-T07-A 1 2.28E+04
K SWA-L06-1315-T08-A 1 8.97E+03
K SWA-L06-1315-T09-A 1 1.45E+04
K SWA-L06-1315-T01-B 1 7.62E+03
K SWA-L06-1315-T02-B 1 2.27E+04
K SWA-L06-1315-T03-B 1 1.31E+04
K SWA-L06-1315-T04-B 1 3.68E+04
K SWA-L06-1315-T05-B 1 2.97E+04
K SWA-L06-1315-T06-B 1 3.63E+04
K SWA-L06-1315-T07-B 1 2.59E+04
K SWA-L06-1315-T08-B 1 9.30E+03
K SWA-L06-1315-T09-B 1 1.49E+04
K SWA-L06-1315-T01-C 1 8.01E+03
K SWA-L06-1315-T02-C 1 2.73E+04
K SWA-L06-1315-T03-C 1 1.65E+04
K SWA-L06-1315-T04-C 1 4.76E+04
K SWA-L06-1315-T05-C 1 3.31E+04
K SWA-L06-1315-T06-C 1 4.03E+04
K SWA-L06-1315-T07-C 1 2.38E+04
K SWA-L06-1315-T08-C 1 9.92E+03
K SWA-L06-1315-T09-C 1 1.63E+04
K SWA-L06-1315-M01-A 1 6.04E+00
K SWA-L06-1315-M02-A 1 4.21E+00 E
K SWA-L06-1315-M03-A 1 2.56E+00 E
K SWA-L06-1315-M04-A 1 7.71E+00
K SWA-L06-1315-M05-A 1 4.32E+00 E
K SWA-L06-1315-M06-A 1 3.59E+00 E
K SWA-L06-1315-M07-A 1 5.24E+00
K SWA-L06-1315-M08-A 1 4.14E+00 E
K SWA-L06-1315-M09-A 1 8.40E+00
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.54E+03 1.14 1.60 5.09
2.64E+04 0.81 1.60 5.09
1.20E+04 0.94 1.60 5.09 10000 1000
3.52E+04 1.67 1.60 5.09
2.75E+04 1.53 1.60 5.09
3.44E+04 1.78 1.60 5.09
2.28E+04 0.56 1.60 5.09
8.97E+03 1.02 1.60 5.09
1.45E+04 1.21 1.60 5.09
7.62E+03 2.87 1.60 5.09
2.27E+04 0.75 1.60 5.09
1.31E+04 1.54 1.60 5.09 10000 1000
3.68E+04 1.07 1.60 5.09
2.97E+04 0.60 1.60 5.09
3.63E+04 0.79 1.60 5.09
2.59E+04 1.43 1.60 5.09
9.30E+03 1.53 1.60 5.09
1.49E+04 1.08 1.60 5.09
8.01E+03 2.32 1.60 5.09
2.73E+04 2.49 1.60 5.09
1.65E+04 0.76 1.60 5.09 10000 1000
4.76E+04 0.83 1.60 5.09
3.31E+04 1.62 1.60 5.09
4.03E+04 1.14 1.60 5.09
2.38E+04 2.44 1.60 5.09
9.92E+03 2.05 1.60 5.09
1.63E+04 0.97 1.60 5.09
6.04E+00 2.75 1.60 5.09
4.21E+00 7.16 1.60 5.09
2.56E+00 1.19 1.60 5.09
7.71E+00 1.89 1.60 5.09
4.32E+00 6.58 1.60 5.09
3.59E+00 6.06 1.60 5.09
5.24E+00 0.44 1.60 5.09
4.14E+00 3.75 1.60 5.09
8.40E+00 3.73 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.29E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.40E+04 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.74E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/2011 11:37 EPA Interlab L06 1315SWA
6/16/2011 11:39 EPA Interlab L06 1315SWA
6/16/2011 11:41 EPA Interlab L06 1315SWA
6/16/2011 11:42 EPA Interlab L06 1315 SWA
6/16/2011 11:44 EPA Interlab L06 1315 SWA
6/16/2011 11:46 EPA Interlab L06 1315 SWA
6/16/2011 11:47 EPA Interlab L06 1315 SWA
6/16/2011 11:49 EPA Interlab L06 1315 SWA
6/16/2011 11:51 EPA Interlab L06 1315 SWA
6/1 6/201 1 1 1 :57 EPA Interlab L06 1 31 5 SWA
6/16/2011 11:59 EPA Interlab L06 131 5 SWA
6/16/201 1 12:00 EPA Interlab L06 1315 SWA
6/16/2011 1 2:02 EPA Interlab L06 131 5 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/201 1 12:07 EPA Interlab L06 1315 SWA
6/16/2011 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:1 4 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:1 8 EPA Interlab L06 1315 SWA
6/16/2011 12:20EPAInterlabl_06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25EPAInterlabl_06 1315 SWA
6/16/201 1 1 1 :23 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :24 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :26 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :28 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :29 EPA Interlab L06 1315 SWA
6/16/2011 11:31 EPA Interlab L06 1315 SWA
6/16/201 1 1 1:32 EPA Interlab L06 1315 SWA
6/16/2011 11:34 EPA Interlab L06 131 5 SWA
6/16/2011 11:36 EPA Interlab L06 131 5 SWA
1-574
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Se SWA-L06-1315-T01-A 1 1.74E+03
Se SWA-L06-1315-T02-A 1 3.83E+03
Se SWA-L06-1315-T03-A 1 1.57E+03
Se SWA-L06-1315-T04-A 1 4.60E+03
Se SWA-L06-1315-T05-A 1 3.25E+03
Se SWA-L06-1315-T06-A 1 3.71E+03
Se SWA-L06-1315-T07-A 1 2.08E+03
Se SWA-L06-1315-T08-A 1 7.49E+02
Se SWA-L06-1315-T09-A 1 1.29E+03
Se SWA-L06-1315-T01-B 1 1.56E+03
Se SWA-L06-1315-T02-B 1 3.03E+03
Se SWA-L06-1315-T03-B 1 1.69E+03
Se SWA-L06-1315-T04-B 1 4.96E+03
Se SWA-L06-1315-T05-B 1 3.63E+03
Se SWA-L06-1315-T06-B 1 4.17E+03
Se SWA-L06-1315-T07-B 1 2.54E+03
Se SWA-L06-1315-T08-B 1 8.14E+02
Se SWA-L06-1315-T09-B 1 1.42E+03
Se SWA-L06-1315-T01-C 1 1.59E+03
Se SWA-L06-1315-T02-C 1 3.89E+03
Se SWA-L06-1315-T03-C 1 2.38E+03
Se SWA-L06-1315-T04-C 1 7.04E+03
Se SWA-L06-1315-T05-C 1 4.21E+03
Se SWA-L06-1315-T06-C 1 4.81E+03
Se SWA-L06-1315-T07-C 1 2.30E+03
Se SWA-L06-1315-T08-C 1 9.03E+02
Se SWA-L06-1315-T09-C 1 1.56E+03
Se SWA-L06-1315-M01-A 1 7.50E+00 U1/2
Se SWA-L06-1315-M02-A 1 7.50E+00 U1/2
Se SWA-L06-1315-M03-A 1 7.50E+00 U1/2
Se SWA-L06-1315-M04-A 1 7.50E+00 U1/2
Se SWA-L06-1315-M05-A 1 7.50E+00 U1/2
Se SWA-L06-1315-M06-A 1 7.50E+00 U1/2
Se SWA-L06-1315-M07-A 1 7.50E+00 U1/2
Se SWA-L06-1315-M08-A 1 7.50E+00 U1/2
Se SWA-L06-1315-M09-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.74E+03 1.32 15.00 47.70
3.83E+03 1.02 15.00 47.70
1.57E+03 0.80 15.00 47.70 10000 1000
4.60E+03 1.48 15.00 47.70
3.25E+03 1.52 15.00 47.70
3.71E+03 1.00 15.00 47.70
2.08E+03 1.33 15.00 47.70
7.49E+02 3.09 15.00 47.70
1.29E+03 1.07 15.00 47.70
1.56E+03 2.81 15.00 47.70
3.03E+03 0.52 15.00 47.70
1.69E+03 3.24 15.00 47.70 10000 1000
4.96E+03 1.36 15.00 47.70
3.63E+03 0.77 15.00 47.70
4.17E+03 0.72 15.00 47.70
2.54E+03 2.00 15.00 47.70
8.14E+02 2.28 15.00 47.70
1.42E+03 0.22 15.00 47.70
1.59E+03 3.68 15.00 47.70
3.89E+03 1.13 15.00 47.70
2.38E+03 1.14 15.00 47.70 10000 1000
7.04E+03 0.91 15.00 47.70
4.21E+03 0.76 15.00 47.70
4.81E+03 1.29 15.00 47.70
2.30E+03 1.89 15.00 47.70
9.03E+02 2.11 15.00 47.70
1.56E+03 1.94 15.00 47.70
7.50E+00 33.21 15.00 47.70
7.50E+00 20.95 15.00 47.70
7.50E+00 34.92 15.00 47.70
7.50E+00 10.77 15.00 47.70
7.50E+00 37.69 15.00 47.70
7.50E+00 18.34 15.00 47.70
7.50E+00 16.66 15.00 47.70
7.50E+00 30.93 15.00 47.70
7.50E+00 21.52 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.69E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.68E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.38E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/2011 11:37 EPA Interlab L06 1315SWA
6/16/2011 11:39 EPA Interlab L06 1315SWA
6/16/2011 11:41 EPA Interlab L06 1315 SWA
6/16/2011 11:42 EPA Interlab L06 1315 SWA
6/16/2011 11:44 EPA Interlab L06 1315 SWA
6/16/2011 11:46 EPA Interlab L06 1315 SWA
6/16/2011 11:47 EPA Interlab L06 1315 SWA
6/16/2011 11:49 EPA Interlab L06 1315 SWA
6/16/2011 11:51 EPA Interlab L06 1315 SWA
6/1 6/201 1 1 1 :57 EPA Interlab L06 1 31 5 SWA
6/16/2011 11:59 EPA Interlab L06 131 5 SWA
6/16/2011 12:00 EPA Interlab L06 1315 SWA
6/16/2011 1 2:02 EPA Interlab L06 131 5 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/201 1 12:07 EPA Interlab L06 1315 SWA
6/16/2011 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:1 4 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:1 8 EPA Interlab L06 1315 SWA
6/16/2011 12:20EPAInterlabl_06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25EPAInterlabl_06 1315 SWA
6/16/201 1 1 1 :23 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :24 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :26 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :28 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :29 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :31 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :32 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :34 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :36 EPA Interlab L06 1315 SWA
1-575
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Si SWA-L06-1315-T01-A 1 8.98E+02
Si SWA-L06-1315-T02-A 1 4.04E+03
Si SWA-L06-1315-T03-A 1 2.77E+03
Si SWA-L06-1315-T04-A 1 7.15E+03
Si SWA-L06-1315-T05-A 1 7.04E+03
Si SWA-L06-1315-T06-A 1 7.88E+03
Si SWA-L06-1315-T07-A 1 7.06E+03
Si SWA-L06-1315-T08-A 1 5.20E+03
Si SWA-L06-1315-T09-A 1 6.64E+03
Si SWA-L06-1315-T01-B 1 7.87E+02
Si SWA-L06-1315-T02-B 1 3.90E+03
Si SWA-L06-1315-T03-B 1 3.26E+03
Si SWA-L06-1315-T04-B 1 7.98E+03
Si SWA-L06-1315-T05-B 1 7.96E+03
Si SWA-L06-1315-T06-B 1 8.70E+03
Si SWA-L06-1315-T07-B 1 7.30E+03
Si SWA-L06-1315-T08-B 1 5.59E+03
Si SWA-L06-1315-T09-B 1 7.08E+03
Si SWA-L06-1315-T01-C 1 8.17E+02
Si SWA-L06-1315-T02-C 1 4.26E+03
Si SWA-L06-1315-T03-C 1 3.11E+03
Si SWA-L06-1315-T04-C 1 8.41E+03
Si SWA-L06-1315-T05-C 1 7.47E+03
Si SWA-L06-1315-T06-C 1 8.62E+03
Si SWA-L06-1315-T07-C 1 7.54E+03
Si SWA-L06-1315-T08-C 1 5.25E+03
Si SWA-L06-1315-T09-C 1 6.95E+03
Si SWA-L06-1315-M01-A 1 2.23E+01
Si SWA-L06-1315-M02-A 1 1.74E+01
Si SWA-L06-1315-M03-A 1 1.59E+01
Si SWA-L06-1315-M04-A 1 1.83E+01
Si SWA-L06-1315-M05-A 1 1.18E+01
Si SWA-L06-1315-M06-A 1 1.01E+01
Si SWA-L06-1315-M07-A 1 1.14E+01
Si SWA-L06-1315-M08-A 1 1.37E+01
Si SWA-L06-1315-M09-A 1 1.16E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.98E+02 2.82 1.10 3.50
4.04E+03 0.29 1.10 3.50
2.77E+03 0.92 1.10 3.50 10000 1000
7.15E+03 2.48 1.10 3.50
7.04E+03 1.94 1.10 3.50
7.88E+03 2.44 1.10 3.50
7.06E+03 0.78 1.10 3.50
5.20E+03 1.46 1.10 3.50
6.64E+03 0.94 1.10 3.50
7.87E+02 2.78 1.10 3.50
3.90E+03 0.10 1.10 3.50
3.26E+03 1.48 1.10 3.50 10000 1000
7.98E+03 2.12 1.10 3.50
7.96E+03 1.43 1.10 3.50
8.70E+03 0.95 1.10 3.50
7.30E+03 1.48 1.10 3.50
5.59E+03 1.79 1.10 3.50
7.08E+03 1.77 1.10 3.50
8.17E+02 2.42 1.10 3.50
4.26E+03 1.54 1.10 3.50
3.11E+03 0.99 1.10 3.50 10000 1000
8.41 E+03 0.85 1.10 3.50
7.47E+03 1.70 1.10 3.50
8.62E+03 0.77 1.10 3.50
7.54E+03 2.35 1.10 3.50
5.25E+03 0.75 1.10 3.50
6.95E+03 0.72 1.10 3.50
2.23E+01 1.06 1.10 3.50
1.74E+01 7.71 1.10 3.50
1.59E+01 2.28 1.10 3.50
1.83E+01 3.56 1.10 3.50
1.18E+01 1.03 1.10 3.50
1.01E+01 1.34 1.10 3.50
1.14E+01 4.06 1.10 3.50
1.37E+01 6.05 1.10 3.50
1.16E+01 9.43 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.62E+03 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.12E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.03E+03 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/2011 11:37 EPA Interlab L06 1315SWA
6/16/2011 11:39 EPA Interlab L06 1315SWA
6/16/2011 11:41 EPA Interlab L06 1315 SWA
6/16/2011 11:42 EPA Interlab L06 1315SWA
6/16/2011 11:44 EPA Interlab L06 1315SWA
6/16/2011 11:46 EPA Interlab L06 1315SWA
6/16/2011 11:47 EPA Interlab L06 1315SWA
6/16/2011 11:49 EPA Interlab L06 1315SWA
6/16/2011 11:51 EPA Interlab L06 1315SWA
6/16/2011 11:57 EPA Interlab L06 1315SWA
6/16/2011 11:59 EPA Interlab L06 1315SWA
6/16/2011 12:00 EPA Interlab L06 1315 SWA
6/16/2011 12:02 EPA Interlab L06 1315 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/2011 12:07 EPA Interlab L06 1315 SWA
6/16/2011 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:14 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:18 EPA Interlab L06 1315 SWA
6/16/2011 12:20 EPA Interlab L06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25 EPA Interlab L06 1315 SWA
6/16/2011 11:23 EPA Interlab L06 1315SWA
6/16/2011 11:24 EPA Interlab L06 1315SWA
6/16/2011 11:26 EPA Interlab L06 1315SWA
6/16/2011 11:28 EPA Interlab L06 1315SWA
6/16/2011 11:29 EPA Interlab L06 1315SWA
6/16/2011 11:31 EPA Interlab L06 1315SWA
6/16/2011 11:32 EPA Interlab L06 1315SWA
6/16/2011 11:34 EPA Interlab L06 1315SWA
6/16/2011 11:36 EPA Interlab L06 1315SWA
1-576
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Na SWA-L06-1315-T01-A 1 3.92E+04
Na SWA-L06-1315-T02-A 1 1.05E+05
Na SWA-L06-1315-T03-A 1 5.23E+04
Na SWA-L06-1315-T04-A 1 1.32E+05
Na SWA-L06-1315-T05-A 1 1.12E+05
Na SWA-L06-1315-T06-A 1 1.32E+05
Na SWA-L06-1315-T07-A 1 9.59E+04
Na SWA-L06-1315-T08-A 1 4.16E+04
Na SWA-L06-1315-T09-A 1 6.59E+04
Na SWA-L06-1315-T01-B 1 3.68E+04
Na SWA-L06-1315-T02-B 1 9.05E+04
Na SWA-L06-1315-T03-B 1 5.60E+04
Na SWA-L06-1315-T04-B 1 1.34E+05
Na SWA-L06-1315-T05-B 1 1.15E+05
Na SWA-L06-1315-T06-B 1 1.35E+05
Na SWA-L06-1315-T07-B 1 1.06E+05
Na SWA-L06-1315-T08-B 1 4.41E+04
Na SWA-L06-1315-T09-B 1 6.99E+04
Na SWA-L06-1315-T01-C 1 3.81E+04
Na SWA-L06-1315-T02-C 1 1.10E+05
Na SWA-L06-1315-T03-C 1 7.18E+04
Na SWA-L06-1315-T04-C 1 1.61E+05
Na SWA-L06-1315-T05-C 1 1.28E+05
Na SWA-L06-1315-T06-C 1 1.46E+05
Na SWA-L06-1315-T07-C 1 1.00E+05
Na SWA-L06-1315-T08-C 1 4.64E+04
Na SWA-L06-1315-T09-C 1 7.44E+04
Na SWA-L06-1315-M01-A 1 2.30E+01
Na SWA-L06-1315-M02-A 1 1.13E+01
Na SWA-L06-1315-M03-A 1 2.66E+01
Na SWA-L06-1315-M04-A 1 1.43E+01
Na SWA-L06-1315-M05-A 1 8.76E+00
Na SWA-L06-1315-M06-A 1 1.53E+01
Na SWA-L06-1315-M07-A 1 1.85E+01
Na SWA-L06-1315-M08-A 1 1.78E+01
Na SWA-L06-1315-M09-A 1 1.83E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.92E+04 0.62 2.50 8.00
1.05E+05 0.57 2.50 8.00
5.23E+04 0.51 2.50 8.00 10000 1000
1.32E+05 0.40 2.50 8.00
1.12E+05 1.49 2.50 8.00
1.32E+05 0.43 2.50 8.00
9.59E+04 0.66 2.50 8.00
4.16E+04 0.91 2.50 8.00
6.59E+04 0.75 2.50 8.00
3.68E+04 0.52 2.50 8.00
9.05E+04 0.65 2.50 8.00
5.60E+04 0.17 2.50 8.00 10000 1000
1.34E+05 0.66 2.50 8.00
1.15E+05 1.30 2.50 8.00
1.35E+05 0.44 2.50 8.00
1.06E+05 0.95 2.50 8.00
4.41 E+04 0.40 2.50 8.00
6.99E+04 0.80 2.50 8.00
3.81 E+04 0.96 2.50 8.00
1.10E+05 1.46 2.50 8.00
7.18E+04 0.24 2.50 8.00 10000 1000
1.61E+05 0.70 2.50 8.00
1.28E+05 1.55 2.50 8.00
1.46E+05 1.28 2.50 8.00
1.00E+05 0.45 2.50 8.00
4.64E+04 1.14 2.50 8.00
7.44E+04 0.22 2.50 8.00
2.30E+01 6.67 2.50 8.00
1.13E+01 2.15 2.50 8.00
2.66E+01 1.84 2.50 8.00
1.43E+01 1.28 2.50 8.00
8.76E+00 1.86 2.50 8.00
1.53E+01 1.55 2.50 8.00
1.85E+01 3.95 2.50 8.00
1.78E+01 4.90 2.50 8.00
1.83E+01 3.44 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.31 E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.68E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.26E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/2011 11:37 EPA Interlab L06 1315SWA
6/16/2011 11:39 EPA Interlab L06 1315SWA
6/16/2011 11:41 EPA Interlab L06 1315 SWA
6/16/2011 11:42 EPA Interlab L06 1315SWA
6/16/2011 11:44 EPA Interlab L06 1315SWA
6/16/2011 11:46 EPA Interlab L06 1315SWA
6/16/2011 11:47 EPA Interlab L06 1315SWA
6/16/2011 11:49 EPA Interlab L06 1315SWA
6/16/2011 11:51 EPA Interlab L06 1315SWA
6/16/2011 11:57 EPA Interlab L06 1315SWA
6/16/2011 11:59 EPA Interlab L06 1315SWA
6/16/2011 12:00 EPA Interlab L06 1315 SWA
6/16/2011 12:02 EPA Interlab L06 1315 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/2011 12:07 EPA Interlab L06 1315 SWA
6/16/2011 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:14 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:18 EPA Interlab L06 1315 SWA
6/16/2011 12:20 EPA Interlab L06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25 EPA Interlab L06 1315 SWA
6/16/2011 11:23 EPA Interlab L06 1315SWA
6/16/2011 11:24 EPA Interlab L06 1315SWA
6/16/2011 11:26 EPA Interlab L06 1315SWA
6/16/2011 11:28 EPA Interlab L06 1315SWA
6/16/2011 11:29 EPA Interlab L06 1315SWA
6/16/2011 11:31 EPA Interlab L06 1315SWA
6/16/2011 11:32 EPA Interlab L06 1315SWA
6/16/2011 11:34 EPA Interlab L06 1315SWA
6/16/2011 11:36 EPA Interlab L06 1315SWA
1-577
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Sr SWA-L06-1315-T01-A 1 4.84E+00
Sr SWA-L06-1315-T02-A 1 9.83E+01
Sr SWA-L06-1315-T03-A 1 1.02E+02
Sr SWA-L06-1315-T04-A 1 2.17E+02
Sr SWA-L06-1315-T05-A 1 2.40E+02
Sr SWA-L06-1315-T06-A 1 2.87E+02
Sr SWA-L06-1315-T07-A 1 2.69E+02
Sr SWA-L06-1315-T08-A 1 2.13E+02
Sr SWA-L06-1315-T09-A 1 2.31 E+02
Sr SWA-L06-1315-T01-B 1 3.97E+00
Sr SWA-L06-1315-T02-B 1 7.60E+01
Sr SWA-L06-1315-T03-B 1 9.43E+01
Sr SWA-L06-1315-T04-B 1 1.92E+02
Sr SWA-L06-1315-T05-B 1 2.15E+02
Sr SWA-L06-1315-T06-B 1 2.54E+02
Sr SWA-L06-1315-T07-B 1 2.48E+02
Sr SWA-L06-1315-T08-B 1 1.89E+02
Sr SWA-L06-1315-T09-B 1 2.09E+02
Sr SWA-L06-1315-T01-C 1 5.07E+00
Sr SWA-L06-1315-T02-C 1 7.98E+01
Sr SWA-L06-1315-T03-C 1 8.84E+01
Sr SWA-L06-1315-T04-C 1 1.90E+02
Sr SWA-L06-1315-T05-C 1 2.14E+02
Sr SWA-L06-1315-T06-C 1 2.57E+02
Sr SWA-L06-1315-T07-C 1 2.44E+02
Sr SWA-L06-1315-T08-C 1 1.96E+02
Sr SWA-L06-1315-T09-C 1 2.15E+02
Sr SWA-L06-1315-M01-A 1 5.00E-01 U1/2
Sr SWA-L06-1315-M02-A 1 5.00E-01 U1/2
Sr SWA-L06-1315-M03-A 1 5.00E-01 U1/2
Sr SWA-L06-1315-M04-A 1 5.00E-01 U1/2
Sr SWA-L06-1315-M05-A 1 5.00E-01 U1/2
Sr SWA-L06-1315-M06-A 1 5.00E-01 U1/2
Sr SWA-L06-1315-M07-A 1 5.00E-01 U1/2
Sr SWA-L06-1315-M08-A 1 5.00E-01 U1/2
Sr SWA-L06-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.84E+00 29.01 1.00 3.18
9.83E+01 2.03 1.00 3.18
1.02E+02 1.99 1.00 3.18 10000 1000
2.17E+02 1.13 1.00 3.18
2.40E+02 2.11 1.00 3.18
2.87E+02 2.09 1.00 3.18
2.69E+02 0.47 1.00 3.18
2.13E+02 1.79 1.00 3.18
2.31E+02 1.32 1.00 3.18
3.97E+00 1.47 1.00 3.18
7.60E+01 0.68 1.00 3.18
9.43E+01 1.92 1.00 3.18 10000 1000
1.92E+02 1.82 1.00 3.18
2.15E+02 1.22 1.00 3.18
2.54E+02 0.61 1.00 3.18
2.48E+02 1.65 1.00 3.18
1.89E+02 2.25 1.00 3.18
2.09E+02 0.76 1.00 3.18
5.07E+00 1.90 1.00 3.18
7.98E+01 1.99 1.00 3.18
8.84E+01 0.92 1.00 3.18 10000 1000
1.90E+02 1.30 1.00 3.18
2.14E+02 1.90 1.00 3.18
2.57E+02 1.42 1.00 3.18
2.44E+02 2.52 1.00 3.18
1.96E+02 2.36 1.00 3.18
2.15E+02 1.15 1.00 3.18
5.00E-01 21.10 1.00 3.18
5.00E-01 13.19 1.00 3.18
5.00E-01 6.64 1.00 3.18
5.00E-01 2.03 1.00 3.18
5.00E-01 26.74 1.00 3.18
5.00E-01 3.59 1.00 3.18
5.00E-01 17.13 1.00 3.18
5.00E-01 23.08 1.00 3.18
5.00E-01 26.46 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 . 1 0E+03 1 00% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/2011 11:37 EPA Interlab L06 1315SWA
6/16/2011 11:39 EPA Interlab L06 1315SWA
6/16/2011 11:41 EPA Interlab L06 1315SWA
6/16/2011 11:42 EPA Interlab L06 1315 SWA
6/16/2011 11:44 EPA Interlab L06 1315 SWA
6/16/2011 11:46 EPA Interlab L06 1315 SWA
6/16/2011 11:47 EPA Interlab L06 1315 SWA
6/16/2011 11:49 EPA Interlab L06 1315 SWA
6/16/2011 11:51 EPA Interlab L06 1315 SWA
6/1 6/201 1 1 1 :57 EPA Interlab L06 1 31 5 SWA
6/16/2011 11:59 EPA Interlab L06 131 5 SWA
6/16/201 1 12:00 EPA Interlab L06 1315 SWA
6/16/2011 1 2:02 EPA Interlab L06 131 5 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/201 1 12:07 EPA Interlab L06 1315 SWA
6/16/2011 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:1 4 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:1 8 EPA Interlab L06 1315 SWA
6/16/2011 12:20EPAInterlabl_06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25EPAInterlabl_06 1315 SWA
6/16/201 1 1 1 :23 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :24 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :26 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :28 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :29 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :31 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :32 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :34 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :36 EPA Interlab L06 1315 SWA
1-578
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
S SWA-L06-1315-T01-A 1 5.70E+03
S SWA-L06-1315-T02-A 1 1.17E+04
S SWA-L06-1315-T03-A 1 4.85E+03
S SWA-L06-1315-T04-A 1 1.34E+04
S SWA-L06-1315-T05-A 1 9.72E+03
S SWA-L06-1315-T06-A 1 1.15E+04
S SWA-L06-1315-T07-A 1 7.36E+03
S SWA-L06-1315-T08-A 1 2.69E+03
S SWA-L06-1315-T09-A 1 4.60E+03
S SWA-L06-1315-T01-B 1 5.34E+03
S SWA-L06-1315-T02-B 1 9.89E+03
S SWA-L06-1315-T03-B 1 5.29E+03
S SWA-L06-1315-T04-B 1 1.51E+04
S SWA-L06-1315-T05-B 1 1.12E+04
S SWA-L06-1315-T06-B 1 1.24E+04
S SWA-L06-1315-T07-B 1 7.95E+03
S SWA-L06-1315-T08-B 1 2.85E+03
S SWA-L06-1315-T09-B 1 5.41E+03
S SWA-L06-1315-T01-C 1 5.16E+03
S SWA-L06-1315-T02-C 1 1.22E+04
S SWA-L06-1315-T03-C 1 7.02E+03
S SWA-L06-1315-T04-C 1 2.07E+04
S SWA-L06-1315-T05-C 1 1.21E+04
S SWA-L06-1315-T06-C 1 1.37E+04
S SWA-L06-1315-T07-C 1 8.22E+03
S SWA-L06-1315-T08-C 1 2.97E+03
S SWA-L06-1315-T09-C 1 5.38E+03
S SWA-L06-1315-M01-A 1 3.40E+00 U1/2
S SWA-L06-1315-M02-A 1 3.40E+00 U1/2
S SWA-L06-1315-M03-A 1 3.40E+00 U1/2
S SWA-L06-1315-M04-A 1 3.40E+00 U1/2
S SWA-L06-1315-M05-A 1 3.40E+00 U1/2
S SWA-L06-1315-M06-A 1 3.40E+00 U1/2
S SWA-L06-1315-M07-A 1 3.40E+00 U1/2
S SWA-L06-1315-M08-A 1 3.40E+00 U1/2
S SWA-L06-1315-M09-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.70E+03 0.62 6.80 21.60
1.17E+04 0.75 6.80 21.60
4.85E+03 0.73 6.80 21.60 10000 1000
1.34E+04 1.71 6.80 21.60
9.72E+03 1.47 6.80 21.60
1.15E+04 1.77 6.80 21.60
7.36E+03 1.24 6.80 21.60
2.69E+03 2.19 6.80 21.60
4.60E+03 1.49 6.80 21.60
5.34E+03 2.97 6.80 21.60
9.89E+03 0.87 6.80 21.60
5.29E+03 1.29 6.80 21.60 10000 1000
1.51E+04 1.58 6.80 21.60
1.12E+04 0.67 6.80 21.60
1.24E+04 0.56 6.80 21.60
7.95E+03 1.39 6.80 21.60
2.85E+03 1.48 6.80 21.60
5.41E+03 0.93 6.80 21.60
5.16E+03 1.97 6.80 21.60
1.22E+04 1.40 6.80 21.60
7.02E+03 1.28 6.80 21.60 10000 1000
2.07E+04 0.84 6.80 21.60
1.21E+04 1.16 6.80 21.60
1.37E+04 1.18 6.80 21.60
8.22E+03 3.06 6.80 21.60
2.97E+03 3.11 6.80 21.60
5.38E+03 1.73 6.80 21.60
3.40E+00 15.21 6.80 21.60
3.40E+00 28.80 6.80 21.60
3.40E+00 11.61 6.80 21.60
3.40E+00 27.26 6.80 21.60
3.40E+00 15.44 6.80 21.60
3.40E+00 13.01 6.80 21.60
3.40E+00 20.33 6.80 21.60
3.40E+00 22.50 6.80 21.60
3.40E+00 16.83 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.76E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.16E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.94E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/2011 11:37 EPA Interlab L06 1315SWA
6/16/2011 11:39 EPA Interlab L06 1315SWA
6/16/2011 11:41 EPA Interlab L06 1315 SWA
6/16/2011 11:42 EPA Interlab L06 1315 SWA
6/16/2011 11:44 EPA Interlab L06 1315 SWA
6/16/2011 11:46 EPA Interlab L06 1315 SWA
6/16/2011 11:47 EPA Interlab L06 1315 SWA
6/16/2011 11:49 EPA Interlab L06 1315 SWA
6/16/2011 11:51 EPA Interlab L06 1315 SWA
6/1 6/201 1 1 1 :57 EPA Interlab L06 1 31 5 SWA
6/16/2011 11:59 EPA Interlab L06 131 5 SWA
6/16/2011 12:00 EPA Interlab L06 1315 SWA
6/16/2011 1 2:02 EPA Interlab L06 131 5 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/201 1 12:07 EPA Interlab L06 1315 SWA
6/16/2011 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:1 4 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:1 8 EPA Interlab L06 1315 SWA
6/16/2011 12:20EPAInterlabl_06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25EPAInterlabl_06 1315 SWA
6/16/201 1 1 1 :23 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :24 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :26 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :28 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :29 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :31 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :32 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :34 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :36 EPA Interlab L06 1315 SWA
1-579
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Tl SWA-L06-1315-T01-A 1 2.30E+00 U1/2
Tl SWA-L06-1315-T02-A 1 2.30E+00 U1/2
Tl SWA-L06-1315-T03-A 1 2.30E+00 U1/2
Tl SWA-L06-1315-T04-A 1 2.30E+00 U1/2
Tl SWA-L06-1315-T05-A 1 2.30E+00 U1/2
Tl SWA-L06-1315-T06-A 1 2.30E+00 U1/2
Tl SWA-L06-1315-T07-A 1 2.30E+00 U1/2
Tl SWA-L06-1315-T08-A 1 2.30E+00 U1/2
Tl SWA-L06-1315-T09-A 1 2.30E+00 U1/2
Tl SWA-L06-1315-T01-B 1 2.30E+00 U1/2
Tl SWA-L06-1315-T02-B 1 2.30E+00 U1/2
Tl SWA-L06-1315-T03-B 1 2.30E+00 U1/2
Tl SWA-L06-1315-T04-B 1 2.30E+00 U1/2
Tl SWA-L06-1315-T05-B 1 2.30E+00 U1/2
Tl SWA-L06-1315-T06-B 1 2.30E+00 U1/2
Tl SWA-L06-1315-T07-B 1 2.30E+00 U1/2
Tl SWA-L06-1315-T08-B 1 2.30E+00 U1/2
Tl SWA-L06-1315-T09-B 1 2.30E+00 U1/2
Tl SWA-L06-1315-T01-C 1 2.30E+00 U1/2
Tl SWA-L06-1315-T02-C 1 2.30E+00 U1/2
Tl SWA-L06-1315-T03-C 1 2.30E+00 U1/2
Tl SWA-L06-1315-T04-C 1 2.30E+00 U1/2
Tl SWA-L06-1315-T05-C 1 2.30E+00 U1/2
Tl SWA-L06-1315-T06-C 1 2.30E+00 U1/2
Tl SWA-L06-1315-T07-C 1 2.30E+00 U1/2
Tl SWA-L06-1315-T08-C 1 2.30E+00 U1/2
Tl SWA-L06-1315-T09-C 1 2.30E+00 U1/2
Tl SWA-L06-1315-M01-A 1 2.30E+00 U1/2
Tl SWA-L06-1315-M02-A 1 2.30E+00 U1/2
Tl SWA-L06-1315-M03-A 1 2.30E+00 U1/2
Tl SWA-L06-1315-M04-A 1 2.30E+00 U1/2
Tl SWA-L06-1315-M05-A 1 2.30E+00 U1/2
Tl SWA-L06-1315-M06-A 1 2.30E+00 U1/2
Tl SWA-L06-1315-M07-A 1 2.30E+00 U1/2
Tl SWA-L06-1315-M08-A 1 2.30E+00 U1/2
Tl SWA-L06-1315-M09-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 24.92 4.60 14.60
2.30E+00 57.16 4.60 14.60
2.30E+00 54.01 4.60 14.60 10000 1000
2.30E+00 14.51 4.60 14.60
2.30E+00 18.32 4.60 14.60
2.30E+00 13.26 4.60 14.60
2.30E+00 34.92 4.60 14.60
2.30E+00 14.00 4.60 14.60
2.30E+00 14.57 4.60 14.60
2.30E+00 29.38 4.60 14.60
2.30E+00 13.35 4.60 14.60
2.30E+00 55.68 4.60 14.60 10000 1000
2.30E+00 32.23 4.60 14.60
2.30E+00 11.05 4.60 14.60
2.30E+00 37.74 4.60 14.60
2.30E+00 23.88 4.60 14.60
2.30E+00 12.78 4.60 14.60
2.30E+00 18.84 4.60 14.60
2.30E+00 43.15 4.60 14.60
2.30E+00 32.82 4.60 14.60
2.30E+00 85.61 4.60 14.60 10000 1000
2.30E+00 87.53 4.60 14.60
2.30E+00 59.00 4.60 14.60
2.30E+00 52.70 4.60 14.60
2.30E+00 20.67 4.60 14.60
2.30E+00 14.46 4.60 14.60
2.30E+00 68.70 4.60 14.60
2.30E+00 29.46 4.60 14.60
2.30E+00 61.36 4.60 14.60
2.30E+00 44.68 4.60 14.60
2.30E+00 34.67 4.60 14.60
2.30E+00 10.20 4.60 14.60
2.30E+00 62.34 4.60 14.60
2.30E+00 63.54 4.60 14.60
2.30E+00 13.53 4.60 14.60
2.30E+00 73.35 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.77E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.76E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.86E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/2011 11:37 EPA Interlab L06 1315SWA
6/16/2011 11:39 EPA Interlab L06 1315SWA
6/16/2011 11:41 EPA Interlab L06 1315 SWA
6/16/2011 11:42 EPA Interlab L06 1315SWA
6/16/2011 11:44 EPA Interlab L06 1315SWA
6/16/2011 11:46 EPA Interlab L06 1315 SWA
6/16/2011 11:47 EPA Interlab L06 1315 SWA
6/16/2011 11:49 EPA Interlab L06 1315 SWA
6/16/2011 11:51 EPA Interlab L06 1315 SWA
6/16/2011 11:57 EPA Interlab L06 1315 SWA
6/16/2011 11:59 EPA Interlab L06 1315 SWA
6/16/2011 12:00 EPA Interlab L06 1315 SWA
6/16/201 1 12:02 EPA Interlab L06 1315 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/2011 12:07 EPA Interlab L06 1315 SWA
6/16/2011 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:14 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:18 EPA Interlab L06 1315 SWA
6/16/2011 12:20 EPA Interlab L06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :23 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :24 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :26 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :28 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :29 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :31 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :32 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :34 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :36 EPA Interlab L06 1315 SWA
1-580
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Ti SWA-L06-1315-T01-A 1 1.00E+00 U1/2
Ti SWA-L06-1315-T02-A 1 1.00E+00 U1/2
Ti SWA-L06-1315-T03-A 1 1.00E+00 U1/2
Ti SWA-L06-1315-T04-A 1 1.00E+00 U1/2
Ti SWA-L06-1315-T05-A 1 1.00E+00 U1/2
Ti SWA-L06-1315-T06-A 1 1.00E+00 U1/2
Ti SWA-L06-1315-T07-A 1 1.00E+00 U1/2
Ti SWA-L06-1315-T08-A 1 1.00E+00 U1/2
Ti SWA-L06-1315-T09-A 1 1.00E+00 U1/2
Ti SWA-L06-1315-T01-B 1 1.00E+00 U1/2
Ti SWA-L06-1315-T02-B 1 1.00E+00 U1/2
Ti SWA-L06-1315-T03-B 1 1.00E+00 U1/2
Ti SWA-L06-1315-T04-B 1 1.00E+00 U1/2
Ti SWA-L06-1315-T05-B 1 1.00E+00 U1/2
Ti SWA-L06-1315-T06-B 1 1.00E+00 U1/2
Ti SWA-L06-1315-T07-B 1 1.00E+00 U1/2
Ti SWA-L06-1315-T08-B 1 1.00E+00 U1/2
Ti SWA-L06-1315-T09-B 1 1.00E+00 U1/2
Ti SWA-L06-1315-T01-C 1 1.00E+00 U1/2
Ti SWA-L06-1315-T02-C 1 1.00E+00 U1/2
Ti SWA-L06-1315-T03-C 1 1.00E+00 U1/2
Ti SWA-L06-1315-T04-C 1 1.00E+00 U1/2
Ti SWA-L06-1315-T05-C 1 1.00E+00 U1/2
Ti SWA-L06-1315-T06-C 1 1.00E+00 U1/2
Ti SWA-L06-1315-T07-C 1 1.00E+00 U1/2
Ti SWA-L06-1315-T08-C 1 1.00E+00 U1/2
Ti SWA-L06-1315-T09-C 1 1.00E+00 U1/2
Ti SWA-L06-1315-M01-A 1 1.00E+00 U1/2
Ti SWA-L06-1315-M02-A 1 1.00E+00 U1/2
Ti SWA-L06-1315-M03-A 1 1.00E+00 U1/2
Ti SWA-L06-1315-M04-A 1 1.00E+00 U1/2
Ti SWA-L06-1315-M05-A 1 1.00E+00 U1/2
Ti SWA-L06-1315-M06-A 1 1.00E+00 U1/2
Ti SWA-L06-1315-M07-A 1 1.00E+00 U1/2
Ti SWA-L06-1315-M08-A 1 1.00E+00 U1/2
Ti SWA-L06-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 7.15 2.00 6.40
1.00E+00 80.45 2.00 6.40
1.00E+00 56.42 2.00 6.40 10000 1000
1.00E+00 12.59 2.00 6.40
1.00E+00 49.31 2.00 6.40
1.00E+00 53.29 2.00 6.40
1.00E+00 67.71 2.00 6.40
1.00E+00 25.18 2.00 6.40
1.00E+00 7.57 2.00 6.40
1.00E+00 26.71 2.00 6.40
1.00E+00 53.16 2.00 6.40
1.00E+00 53.26 2.00 6.40 10000 1000
1.00E+00 71.95 2.00 6.40
1.00E+00 33.12 2.00 6.40
1.00E+00 28.37 2.00 6.40
1.00E+00 11.49 2.00 6.40
1.00E+00 21.99 2.00 6.40
1.00E+00 20.12 2.00 6.40
1.00E+00 43.60 2.00 6.40
1.00E+00 76.88 2.00 6.40
1.00E+00 24.85 2.00 6.40 10000 1000
1.00E+00 52.67 2.00 6.40
1.00E+00 27.86 2.00 6.40
1.00E+00 41.40 2.00 6.40
1.00E+00 89.66 2.00 6.40
1.00E+00 28.91 2.00 6.40
1.00E+00 46.23 2.00 6.40
1.00E+00 52.14 2.00 6.40
1.00E+00 116.26 2.00 6.40
1.00E+00 40.86 2.00 6.40
1.00E+00 40.92 2.00 6.40
1.00E+00 71.60 2.00 6.40
1.00E+00 24.62 2.00 6.40
1.00E+00 32.85 2.00 6.40
1.00E+00 12.99 2.00 6.40
1.00E+00 28.38 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/2011 11:37 EPA Interlab L06 1315SWA
6/16/2011 11:39 EPA Interlab L06 1315SWA
6/16/2011 11:41 EPA Interlab L06 1315 SWA
6/16/2011 11:42 EPA Interlab L06 1315SWA
6/16/2011 11:44 EPA Interlab L06 1315SWA
6/16/2011 11:46 EPA Interlab L06 1315SWA
6/16/2011 11:47 EPA Interlab L06 1315SWA
6/16/2011 11:49 EPA Interlab L06 1315SWA
6/16/2011 11:51 EPA Interlab L06 1315SWA
6/16/2011 11:57 EPA Interlab L06 1315SWA
6/16/2011 11:59 EPA Interlab L06 1315SWA
6/16/2011 12:00 EPA Interlab L06 1315 SWA
6/16/2011 12:02 EPA Interlab L06 1315 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/2011 12:07 EPA Interlab L06 1315 SWA
6/16/2011 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:14 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:18 EPA Interlab L06 1315 SWA
6/16/2011 12:20 EPA Interlab L06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25 EPA Interlab L06 1315 SWA
6/16/2011 11:23 EPA Interlab L06 1315 SWA
6/16/2011 11:24 EPA Interlab L06 1315 SWA
6/16/2011 11:26 EPA Interlab L06 1315 SWA
6/16/2011 11:28 EPA Interlab L06 1315 SWA
6/16/2011 11:29 EPA Interlab L06 1315 SWA
6/16/2011 11:31 EPA Interlab L06 1315 SWA
6/16/201 1 11 :32 EPA Interlab L06 1315 SWA
6/16/2011 11:34 EPA Interlab L06 1315 SWA
6/16/2011 11:36 EPA Interlab L06 1315 SWA
1-581
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
V SWA-L06-1315-T01-A 1 1.21E+01
V SWA-L06-1315-T02-A 1 1.89E+01
V SWA-L06-1315-T03-A 1 9.15E+00
V SWA-L06-1315-T04-A 1 2.09E+01
V SWA-L06-1315-T05-A 1 1.77E+01
V SWA-L06-1315-T06-A 1 2.04E+01
V SWA-L06-1315-T07-A 1 1.56E+01
V SWA-L06-1315-T08-A 1 1.00E+01
V SWA-L06-1315-T09-A 1 1.45E+01
V SWA-L06-1315-T01-B 1 1.27E+01
V SWA-L06-1315-T02-B 1 1.79E+01
V SWA-L06-1315-T03-B 1 9.41E+00
V SWA-L06-1315-T04-B 1 2.09E+01
V SWA-L06-1315-T05-B 1 1.76E+01
V SWA-L06-1315-T06-B 1 2.16E+01
V SWA-L06-1315-T07-B 1 1.61E+01
V SWA-L06-1315-T08-B 1 9.57E+00
V SWA-L06-1315-T09-B 1 1.39E+01
V SWA-L06-1315-T01-C 1 1.21E+01
V SWA-L06-1315-T02-C 1 2.03E+01
V SWA-L06-1315-T03-C 1 1.11E+01
V SWA-L06-1315-T04-C 1 2.70E+01
V SWA-L06-1315-T05-C 1 1.87E+01
V SWA-L06-1315-T06-C 1 2.29E+01
V SWA-L06-1315-T07-C 1 1.53E+01
V SWA-L06-1315-T08-C 1 1.00E+01
V SWA-L06-1315-T09-C 1 1.44E+01
V SWA-L06-1315-M01-A 1 7.50E-01 U1/2
V SWA-L06-1315-M02-A 1 7.50E-01 U1/2
V SWA-L06-1315-M03-A 1 7.50E-01 U1/2
V SWA-L06-1315-M04-A 1 7.50E-01 U1/2
V SWA-L06-1315-M05-A 1 7.50E-01 U1/2
V SWA-L06-1315-M06-A 1 7.50E-01 U1/2
V SWA-L06-1315-M07-A 1 7.50E-01 U1/2
V SWA-L06-1315-M08-A 1 7.50E-01 U1/2
V SWA-L06-1315-M09-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.21E+01 5.60 1.50 4.77
1.89E+01 2.45 1.50 4.77
9.15E+00 6.01 1.50 4.77 10000 1000
2.09E+01 3.69 1.50 4.77
1.77E+01 3.31 1.50 4.77
2.04E+01 2.98 1.50 4.77
1.56E+01 3.62 1.50 4.77
1.00E+01 6.53 1.50 4.77
1.45E+01 7.11 1.50 4.77
1.27E+01 7.91 1.50 4.77
1.79E+01 8.76 1.50 4.77
9.41E+00 5.01 1.50 4.77 10000 1000
2.09E+01 2.49 1.50 4.77
1.76E+01 7.07 1.50 4.77
2.16E+01 5.16 1.50 4.77
1.61E+01 3.96 1.50 4.77
9.57E+00 6.61 1.50 4.77
1.39E+01 8.28 1.50 4.77
1.21E+01 6.28 1.50 4.77
2.03E+01 2.51 1.50 4.77
1.11E+01 9.22 1.50 4.77 10000 1000
2.70E+01 1.43 1.50 4.77
1.87E+01 0.84 1.50 4.77
2.29E+01 2.02 1.50 4.77
1.53E+01 3.68 1.50 4.77
1.00E+01 5.36 1.50 4.77
1.44E+01 1.84 1.50 4.77
7.50E-01 31.32 1.50 4.77
7.50E-01 37.19 1.50 4.77
7.50E-01 23.67 1.50 4.77
7.50E-01 14.72 1.50 4.77
7.50E-01 10.80 1.50 4.77
7.50E-01 26.58 1.50 4.77
7.50E-01 15.32 1.50 4.77
7.50E-01 17.56 1.50 4.77
7.50E-01 34.53 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/2011 11:37 EPA Interlab L06 1315SWA
6/16/2011 11:39 EPA Interlab L06 1315SWA
6/16/2011 11:41 EPA Interlab L06 1315SWA
6/16/2011 11:42 EPA Interlab L06 1315 SWA
6/16/2011 11:44 EPA Interlab L06 1315 SWA
6/16/2011 11:46 EPA Interlab L06 1315 SWA
6/16/2011 11:47 EPA Interlab L06 1315 SWA
6/16/2011 11:49 EPA Interlab L06 1315 SWA
6/16/2011 11:51 EPA Interlab L06 1315 SWA
6/1 6/201 1 1 1 :57 EPA Interlab L06 1 31 5 SWA
6/16/2011 11:59 EPA Interlab L06 131 5 SWA
6/16/201 1 12:00 EPA Interlab L06 1315 SWA
6/16/2011 1 2:02 EPA Interlab L06 131 5 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/201 1 12:07 EPA Interlab L06 1315 SWA
6/16/2011 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:1 4 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:1 8 EPA Interlab L06 1315 SWA
6/16/2011 12:20EPAInterlabl_06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25EPAInterlabl_06 1315 SWA
6/16/201 1 1 1 :23 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :24 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :26 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :28 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :29 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :31 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :32 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :34 EPA Interlab L06 1315 SWA
6/16/201 1 1 1 :36 EPA Interlab L06 1315 SWA
1-582
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L
Zn SWA-L06-1315-T01-A 1 4.54E+00
Zn SWA-L06-1315-T02-A 1 2.57E+00 E
Zn SWA-L06-1315-T03-A 1 3.24E+00
Zn SWA-L06-1315-T04-A 1 2.71E+00 E
Zn SWA-L06-1315-T05-A 1 3.44E+00
Zn SWA-L06-1315-T06-A 1 3.11E+OOE
Zn SWA-L06-1315-T07-A 1 2.93E+00 E
Zn SWA-L06-1315-T08-A 1 5.00E-01 U1/2
Zn SWA-L06-1315-T09-A 1 5.00E-01 U1/2
Zn SWA-L06-1315-T01-B 1 3.74E+00
Zn SWA-L06-1315-T02-B 1 2.50E+00 E
Zn SWA-L06-1315-T03-B 1 1.72E+00 E
Zn SWA-L06-1315-T04-B 1 4.03E+00
Zn SWA-L06-1315-T05-B 1 3.15E+00 E
Zn SWA-L06-1315-T06-B 1 4.35E+00
Zn SWA-L06-1315-T07-B 1 3.35E+00
Zn SWA-L06-1315-T08-B 1 2.00E+00 E
Zn SWA-L06-1315-T09-B 1 5.00E-01 U1/2
Zn SWA-L06-1315-T01-C 1 3.08E+00 E
Zn SWA-L06-1315-T02-C 1 2.60E+00 E
Zn SWA-L06-1315-T03-C 1 1.99E+00 E
Zn SWA-L06-1315-T04-C 1 3.46E+00
Zn SWA-L06-1315-T05-C 1 1.05E+00 E
Zn SWA-L06-1315-T06-C 1 1.74E+01
Zn SWA-L06-1315-T07-C 1 1.28E+00 E
Zn SWA-L06-1315-T08-C 1 5.00E-01 U1/2
Zn SWA-L06-1315-T09-C 1 5.00E-01 U1/2
Zn SWA-L06-1315-M01-A 1 5.00E-01 U1/2
Zn SWA-L06-1315-M02-A 1 5.00E-01 U1/2
Zn SWA-L06-1315-M03-A 1 5.00E-01 U1/2
Zn SWA-L06-1315-M04-A 1 5.00E-01 U1/2
Zn SWA-L06-1315-M05-A 1 5.00E-01 U1/2
Zn SWA-L06-1315-M06-A 1 5.00E-01 U1/2
Zn SWA-L06-1315-M07-A 1 5.00E-01 U1/2
Zn SWA-L06-1315-M08-A 1 5.00E-01 U1/2
Zn SWA-L06-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.54E+00 3.23 1.00 3.18
2.57E+00 13.39 1.00 3.18
3.24E+00 4.14 1.00 3.18 10000 1000
2.71E+00 16.75 1.00 3.18
3.44E+00 11.02 1.00 3.18
3.11E+00 12.18 1.00 3.18
2.93E+00 6.82 1.00 3.18
5.00E-01 69.05 1.00 3.18
5.00E-01 48.86 1.00 3.18
3.74E+00 5.05 1.00 3.18
2.50E+00 13.36 1.00 3.18
1.72E+00 29.07 1.00 3.18 10000 1000
4.03E+00 5.68 1.00 3.18
3.15E+00 11.23 1.00 3.18
4.35E+00 3.38 1.00 3.18
3.35E+00 8.10 1.00 3.18
2.00E+00 8.09 1.00 3.18
5.00E-01 16.25 1.00 3.18
3.08E+00 2.00 1.00 3.18
2.60E+00 12.37 1.00 3.18
1.99E+00 11.87 1.00 3.18 10000 1000
3.46E+00 6.54 1.00 3.18
1.05E+00 11.76 1.00 3.18
1.74E+01 0.97 1.00 3.18
1.28E+00 30.00 1.00 3.18
5.00E-01 62.54 1.00 3.18
5.00E-01 58.65 1.00 3.18
5.00E-01 6.79 1.00 3.18
5.00E-01 23.32 1.00 3.18
5.00E-01 6.74 1.00 3.18
5.00E-01 26.87 1.00 3.18
5.00E-01 17.55 1.00 3.18
5.00E-01 0.43 1.00 3.18
5.00E-01 7.23 1.00 3.18
5.00E-01 50.30 1.00 3.18
5.00E-01 56.92 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/16/2011 11:37 EPA Interlab L06 1315SWA
6/16/2011 11:39 EPA Interlab L06 1315SWA
6/16/2011 11:41 EPA Interlab L06 1315 SWA
6/16/2011 11:42 EPA Interlab L06 1315SWA
6/16/2011 11:44 EPA Interlab L06 1315SWA
6/16/2011 11:46 EPA Interlab L06 1315SWA
6/16/2011 11:47 EPA Interlab L06 1315SWA
6/16/2011 11:49 EPA Interlab L06 1315SWA
6/16/2011 11:51 EPA Interlab L06 1315 SWA
6/16/2011 11:57 EPA Interlab L06 1315 SWA
6/16/2011 11:59 EPA Interlab L06 1315 SWA
6/16/2011 12:00 EPA Interlab L06 1315 SWA
6/16/2011 12:02 EPA Interlab L06 1315 SWA
6/16/2011 12:04 EPA Interlab L06 1315 SWA
6/16/2011 12:05 EPA Interlab L06 1315 SWA
6/16/201 1 12:07 EPA Interlab L06 1315 SWA
6/16/201 1 12:09 EPA Interlab L06 1315 SWA
6/16/2011 12:10 EPA Interlab L06 1315 SWA
6/16/2011 12:12 EPA Interlab L06 1315 SWA
6/16/2011 12:14 EPA Interlab L06 1315 SWA
6/16/2011 12:15 EPA Interlab L06 1315 SWA
6/16/2011 12:17 EPA Interlab L06 1315 SWA
6/16/2011 12:18 EPA Interlab L06 1315 SWA
6/16/2011 12:20 EPA Interlab L06 1315 SWA
6/16/2011 12:22 EPA Interlab L06 1315 SWA
6/16/2011 12:23 EPA Interlab L06 1315 SWA
6/16/2011 12:25 EPA Interlab L06 1315 SWA
6/16/2011 11:23 EPA Interlab L06 1315 SWA
6/16/2011 11:24 EPA Interlab L06 1315 SWA
6/16/2011 11:26 EPA Interlab L06 1315 SWA
6/16/2011 11:28 EPA Interlab L06 1315 SWA
6/16/2011 11:29 EPA Interlab L06 1315 SWA
6/16/2011 11:31 EPA Interlab L06 1315 SWA
6/16/2011 11:32 EPA Interlab L06 1315 SWA
6/16/2011 11:34 EPA Interlab L06 1315 SWA
6/16/2011 11:36 EPA Interlab L06 1315 SWA
1-583
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1315:
Element Sample ID
Al SWA-L07-1315-T01-A
Al SWA-L07-1315-T02-A
Al SWA-L07-1315-T03-A
Al SWA-L07-1315-T04-A
Al SWA-L07-1315-T05-A
Al SWA-L07-1315-T06-A
Al SWA-L07-1315-T07-A
Al SWA-L07-1315-T08-A
Al SWA-L07-1315-T09-A
Al SWA-L07-1315-T01-B
Al SWA-L07-1315-T02-B
Al SWA-L07-1315-T03-B
Al SWA-L07-1315-T04-B
Al SWA-L07-1315-T05-B
Al SWA-L07-1315-T06-B
Al SWA-L07-1315-T07-B
Al SWA-L07-1315-T08-B
Al SWA-L07-1315-T09-B
Al SWA-L07-1315-T01-C
Al SWA-L07-1315-T02-C
Al SWA-L07-1315-T03-C
Al SWA-L07-1315-T04-C
Al SWA-L07-1315-T05-C
Al SWA-L07-1315-T06-C
Al SWA-L07-1315-T07-C
Al SWA-L07-1315-T08-C
Al SWA-L07-1315-T09-C
Al SWA-L07-1315-M01-A
Al SWA-L07-1315-M02-A
Al SWA-L07-1315-M03-A
Al SWA-L07-1315-M04-A
Al SWA-L07-1315-M05-A
Al SWA-L07-1315-M06-A
Al SWA-L07-1315-M07-A
Al SWA-L07-1315-M08-A
Al SWA-L07-1315-M09-A
Dilution Sample
Factor Cone. Qualifier
I ug/L I
1 1.88E+03
1 4.61 E+03
1 2.80E+03
1 5.73E+03
1 4.63E+03
1 5.26E+03
1 4.39E+03
1 2.64E+03
1 3.42E+03
1 1.69E+03
1 4.41 E+03
1 2.69E+03
1 5.58E+03
1 4.67E+03
1 5.22E+03
1 4.25E+03
1 2.66E+03
1 3.41 E+03
1 1.85E+03
1 4.61 E+03
1 2.81 E+03
1 5.57E+03
1 3.99E+03
1 5. 11 E+03
1 4.31 E+03
1 2.72E+03
1 3.42E+03
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.88E+03 0.14 1.00 3.18
4.61E+03 0.47 1.00 3.18
2.80E+03 0.69 1.00 3.18 10000 1000
5.73E+03 0.83 1.00 3.18
4.63E+03 0.36 1.00 3.18
5.26E+03 0.46 1.00 3.18
4.39E+03 0.54 1.00 3.18
2.64E+03 1.21 1.00 3.18
3.42E+03 1.20 1.00 3.18
1.69E+03 0.08 1.00 3.18
4.41E+03 0.66 1.00 3.18
2.69E+03 0.16 1.00 3.18 10000 1000
5.58E+03 0.90 1.00 3.18
4.67E+03 1.23 1.00 3.18
5.22E+03 0.54 1.00 3.18
4.25E+03 0.84 1.00 3.18
2.66E+03 0.18 1.00 3.18
3.41E+03 1.27 1.00 3.18
1.85E+03 2.04 1.00 3.18
4.61E+03 0.73 1.00 3.18
2.81E+03 0.38 1.00 3.18 10000 1000
5.57E+03 0.60 1.00 3.18
3.99E+03 0.42 1.00 3.18
5.11E+03 0.33 1.00 3.18
4.31E+03 0.68 1.00 3.18
2.72E+03 0.49 1.00 3.18
3.42E+03 0.60 1.00 3.18
5.00E-01 4.50 1.00 3.18
5.00E-01 7.59 1.00 3.18
5.00E-01 8.59 1.00 3.18
5.00E-01 7.74 1.00 3.18
5.00E-01 13.28 1.00 3.18
5.00E-01 14.56 1.00 3.18
5.00E-01 10.14 1.00 3.18
5.00E-01 9.10 1.00 3.18
5.00E-01 7.98 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.81 E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.60E+03 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.71E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 1315 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :02 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :04 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :06 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :07 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :09 PM EPA Interlab L07 1315 SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-584
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Sb SWA-L07-1315-T01-A 1 3.23E+02
Sb SWA-L07-1315-T02-A 1 4.01E+02
Sb SWA-L07-1315-T03-A 1 2.13E+02
Sb SWA-L07-1315-T04-A 1 4.55E+02
Sb SWA-L07-1315-T05-A 1 3.41 E+02
Sb SWA-L07-1315-T06-A 1 3.85E+02
Sb SWA-L07-1315-T07-A 1 3.09E+02
Sb SWA-L07-1315-T08-A 1 2.02E+02
Sb SWA-L07-1315-T09-A 1 2.67E+02
Sb SWA-L07-1315-T01-B 1 2.80E+02
Sb SWA-L07-1315-T02-B 1 3.93E+02
Sb SWA-L07-1315-T03-B 1 2.25E+02
Sb SWA-L07-1315-T04-B 1 4.25E+02
Sb SWA-L07-1315-T05-B 1 3.34E+02
Sb SWA-L07-1315-T06-B 1 3.65E+02
Sb SWA-L07-1315-T07-B 1 2.95E+02
Sb SWA-L07-1315-T08-B 1 2.00E+02
Sb SWA-L07-1315-T09-B 1 2.60E+02
Sb SWA-L07-1315-T01-C 1 2.90E+02
Sb SWA-L07-1315-T02-C 1 4.20E+02
Sb SWA-L07-1315-T03-C 1 2.38E+02
Sb SWA-L07-1315-T04-C 1 4.60E+02
Sb SWA-L07-1315-T05-C 1 3.41E+02
Sb SWA-L07-1315-T06-C 1 3.97E+02
Sb SWA-L07-1315-T07-C 1 3.39E+02
Sb SWA-L07-1315-T08-C 1 2.16E+02
Sb SWA-L07-1315-T09-C 1 3.04E+02
Sb SWA-L07-1315-M01-A 1 3.75E+00 U1/2
Sb SWA-L07-1315-M02-A 1 3.75E+00 U1/2
Sb SWA-L07-1315-M03-A 1 3.75E+00 U1/2
Sb SWA-L07-1315-M04-A 1 3.75E+00 U1/2
Sb SWA-L07-1315-M05-A 1 3.75E+00 U1/2
Sb SWA-L07-1315-M06-A 1 3.75E+00 U1/2
Sb SWA-L07-1315-M07-A 1 3.75E+00 U1/2
Sb SWA-L07-1315-M08-A 1 3.75E+00 U1/2
Sb SWA-L07-1315-M09-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.23E+02 2.81 7.50 23.90
4.01 E+02 0.83 7.50 23.90
2.13E+02 3.44 7.50 23.90 10000 1000
4.55E+02 3.22 7.50 23.90
3.41 E+02 0.91 7.50 23.90
3.85E+02 0.66 7.50 23.90
3.09E+02 2.17 7.50 23.90
2.02E+02 1.56 7.50 23.90
2.67E+02 2.30 7.50 23.90
2.80E+02 2.67 7.50 23.90
3.93E+02 3.74 7.50 23.90
2.25E+02 4.55 7.50 23.90 10000 1000
4.25E+02 1.02 7.50 23.90
3.34E+02 2.37 7.50 23.90
3.65E+02 3.05 7.50 23.90
2.95E+02 2.11 7.50 23.90
2.00E+02 3.68 7.50 23.90
2.60E+02 2.22 7.50 23.90
2.90E+02 3.34 7.50 23.90
4.20E+02 1.95 7.50 23.90
2.38E+02 2.80 7.50 23.90 10000 1000
4.60E+02 2.22 7.50 23.90
3.41E+02 1.34 7.50 23.90
3.97E+02 1.87 7.50 23.90
3.39E+02 2.14 7.50 23.90
2.16E+02 1.67 7.50 23.90
3.04E+02 1.76 7.50 23.90
3.75E+00 20.03 7.50 23.90
3.75E+00 14.55 7.50 23.90
3.75E+00 11.32 7.50 23.90
3.75E+00 15.02 7.50 23.90
3.75E+00 13.67 7.50 23.90
3.75E+00 33.97 7.50 23.90
3.75E+00 59.89 7.50 23.90
3.75E+00 24.40 7.50 23.90
3.75E+00 21.90 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.29E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.32E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.32E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 1315 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315SWA
3/1/11 1:02 PM EPA Interlab L07 1315SWA
3/1/11 1:04 PM EPA Interlab L07 1315SWA
3/1/11 1:06 PM EPA Interlab L07 1315SWA
3/1/11 1:07 PM EPA Interlab L07 1315SWA
3/1/11 1:09 PM EPA Interlab L07 1315SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-585
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
As SWA-L07-1315-T01-A 1 2.19E+02
As SWA-L07-1315-T02-A 1 1.38E+02
As SWA-L07-1315-T03-A 1 1.02E+02
As SWA-L07-1315-T04-A 1 2.14E+02
As SWA-L07-1315-T05-A 1 1.54E+02
As SWA-L07-1315-T06-A 1 1.59E+02
As SWA-L07-1315-T07-A 1 1.20E+02
As SWA-L07-1315-T08-A 1 7.35E+01
As SWA-L07-1315-T09-A 1 9.64E+01
As SWA-L07-1315-T01-B 1 2.11E+02
As SWA-L07-1315-T02-B 1 1.22E+02
As SWA-L07-1315-T03-B 1 9.43E+01
As SWA-L07-1315-T04-B 1 1.81E+02
As SWA-L07-1315-T05-B 1 1.50E+02
As SWA-L07-1315-T06-B 1 1.59E+02
As SWA-L07-1315-T07-B 1 1.23E+02
As SWA-L07-1315-T08-B 1 7.03E+01
As SWA-L07-1315-T09-B 1 9.01E+01
As SWA-L07-1315-T01-C 1 2.05E+02
As SWA-L07-1315-T02-C 1 1.25E+02
As SWA-L07-1315-T03-C 1 8.02E+01
As SWA-L07-1315-T04-C 1 1.65E+02
As SWA-L07-1315-T05-C 1 1.31E+02
As SWA-L07-1315-T06-C 1 1.45E+02
As SWA-L07-1315-T07-C 1 1.15E+02
As SWA-L07-1315-T08-C 1 6.64E+01
As SWA-L07-1315-T09-C 1 1.24E+02
As SWA-L07-1315-M01-A 1 5.50E+00 U1/2
As SWA-L07-1315-M02-A 1 5.50E+00 U1/2
As SWA-L07-1315-M03-A 1 5.50E+00 U1/2
As SWA-L07-1315-M04-A 1 5.50E+00 U1/2
As SWA-L07-1315-M05-A 1 5.50E+00 U1/2
As SWA-L07-1315-M06-A 1 5.50E+00 U1/2
As SWA-L07-1315-M07-A 1 5.50E+00 U1/2
As SWA-L07-1315-M08-A 1 5.50E+00 U1/2
As SWA-L07-1315-M09-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.19E+02 3.19 11.00 35.00
1.38E+02 3.08 11.00 35.00
1.02E+02 4.35 11.00 35.00 10000 1000
2.14E+02 4.30 11.00 35.00
1.54E+02 6.37 11.00 35.00
1.59E+02 4.55 11.00 35.00
1.20E+02 6.87 11.00 35.00
7.35E+01 1.39 11.00 35.00
9.64E+01 3.41 11.00 35.00
2.11E+02 1.81 11.00 35.00
1.22E+02 6.36 11.00 35.00
9.43E+01 2.16 11.00 35.00 10000 1000
1.81E+02 6.96 11.00 35.00
1.50E+02 4.82 11.00 35.00
1.59E+02 6.60 11.00 35.00
1.23E+02 5.45 11.00 35.00
7.03E+01 6.22 11.00 35.00
9.01E+01 3.44 11.00 35.00
2.05E+02 4.74 11.00 35.00
1.25E+02 7.16 11.00 35.00
8.02E+01 8.03 11.00 35.00 10000 1000
1.65E+02 3.44 11.00 35.00
1.31E+02 11.76 11.00 35.00
1.45E+02 3.36 11.00 35.00
1.15E+02 6.40 11.00 35.00
6.64E+01 5.71 11.00 35.00
1.24E+02 4.91 11.00 35.00
5.50E+00 51.96 11.00 35.00
5.50E+00 45.04 11.00 35.00
5.50E+00 26.00 11.00 35.00
5.50E+00 67.05 11.00 35.00
5.50E+00 46.23 11.00 35.00
5.50E+00 20.53 11.00 35.00
5.50E+00 48.50 11.00 35.00
5.50E+00 30.77 11.00 35.00
5.50E+00 17.76 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.17E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 1315 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315SWA
3/1/11 1:02 PM EPA Interlab L07 1315SWA
3/1/11 1:04 PM EPA Interlab L07 1315SWA
3/1/11 1:06 PM EPA Interlab L07 1315SWA
3/1/11 1:07 PM EPA Interlab L07 1315SWA
3/1/11 1:09 PM EPA Interlab L07 1315SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-586
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
B SWA-L07-1315-T01-A 1 4.79E+01
B SWA-L07-1315-T02-A 1 4.94E+01
B SWA-L07-1315-T03-A 1 3.65E+01
B SWA-L07-1315-T04-A 1 7.27E+01
B SWA-L07-1315-T05-A 1 6.08E+01
B SWA-L07-1315-T06-A 1 7.23E+01
B SWA-L07-1315-T07-A 1 6.06E+01
B SWA-L07-1315-T08-A 1 4.11E+01
B SWA-L07-1315-T09-A 1 5.40E+01
B SWA-L07-1315-T01-B 1 5.22E+01
B SWA-L07-1315-T02-B 1 5.46E+01
B SWA-L07-1315-T03-B 1 3.90E+01
B SWA-L07-1315-T04-B 1 7.11E+01
B SWA-L07-1315-T05-B 1 6.08E+01
B SWA-L07-1315-T06-B 1 6.98E+01
B SWA-L07-1315-T07-B 1 5.78E+01
B SWA-L07-1315-T08-B 1 4.25E+01
B SWA-L07-1315-T09-B 1 5.46E+01
B SWA-L07-1315-T01-C 1 5.39E+01
B SWA-L07-1315-T02-C 1 5.85E+01
B SWA-L07-1315-T03-C 1 4.07E+01
B SWA-L07-1315-T04-C 1 7.34E+01
B SWA-L07-1315-T05-C 1 5.50E+01
B SWA-L07-1315-T06-C 1 6.79E+01
B SWA-L07-1315-T07-C 1 5.85E+01
B SWA-L07-1315-T08-C 1 4.46E+01
B SWA-L07-1315-T09-C 1 5.67E+01
B SWA-L07-1315-M01-A 1 5.00E-01 U1/2
B SWA-L07-1315-M02-A 1 5.00E-01 U1/2
B SWA-L07-1315-M03-A 1 5.00E-01 U1/2
B SWA-L07-1315-M04-A 1 5.00E-01 U1/2
B SWA-L07-1315-M05-A 1 5.00E-01 U1/2
B SWA-L07-1315-M06-A 1 5.00E-01 U1/2
B SWA-L07-1315-M07-A 1 5.00E-01 U1/2
B SWA-L07-1315-M08-A 1 5.00E-01 U1/2
B SWA-L07-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.79E+01 0.45 1.00 3.18
4.94E+01 2.33 1.00 3.18
3.65E+01 2.02 1.00 3.18 10000 1000
7.27E+01 2.83 1.00 3.18
6.08E+01 1.77 1.00 3.18
7.23E+01 3.29 1.00 3.18
6.06E+01 2.31 1.00 3.18
4.11E+01 4.38 1.00 3.18
5.40E+01 1.96 1.00 3.18
5.22E+01 1.34 1.00 3.18
5.46E+01 4.35 1.00 3.18
3.90E+01 3.12 1.00 3.18 10000 1000
7.11E+01 2.28 1.00 3.18
6.08E+01 4.81 1.00 3.18
6.98E+01 5.21 1.00 3.18
5.78E+01 2.22 1.00 3.18
4.25E+01 1.80 1.00 3.18
5.46E+01 3.16 1.00 3.18
5.39E+01 1.71 1.00 3.18
5.85E+01 3.39 1.00 3.18
4.07E+01 1.95 1.00 3.18 10000 1000
7.34E+01 1.10 1.00 3.18
5.50E+01 1.09 1.00 3.18
6.79E+01 2.02 1.00 3.18
5.85E+01 4.36 1.00 3.18
4.46E+01 2.13 1.00 3.18
5.67E+01 3.83 1.00 3.18
5.00E-01 1.08 1.00 3.18
5.00E-01 1.31 1.00 3.18
5.00E-01 1.17 1.00 3.18
5.00E-01 19.00 1.00 3.18
5.00E-01 5.64 1.00 3.18
5.00E-01 5.89 1.00 3.18
5.00E-01 3.16 1.00 3.18
5.00E-01 1.97 1.00 3.18
5.00E-01 1.77 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.06E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.91 E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.62E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 1315 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315SWA
3/1/11 1:02 PM EPA Interlab L07 1315SWA
3/1/11 1:04 PM EPA Interlab L07 1315SWA
3/1/11 1:06 PM EPA Interlab L07 1315SWA
3/1/11 1:07 PM EPA Interlab L07 1315SWA
3/1/11 1:09 PM EPA Interlab L07 1315SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-587
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
ug/L
Ba SWA-L07-1315-T01-A 1 2.01E+01
Ba SWA-L07-1315-T02-A 1 1.70E+02
Ba SWA-L07-1315-T03-A 1 1.75E+02
Ba SWA-L07-1315-T04-A 1 2.83E+02
Ba SWA-L07-1315-T05-A 1 3.25E+02
Ba SWA-L07-1315-T06-A 1 3.53E+02
Ba SWA-L07-1315-T07-A 1 3.60E+02
Ba SWA-L07-1315-T08-A 1 3.31 E+02
Ba SWA-L07-1315-T09-A 1 2.80E+02
Ba SWA-L07-1315-T01-B 1 1.83E+01
Ba SWA-L07-1315-T02-B 1 1.63E+02
Ba SWA-L07-1315-T03-B 1 1.83E+02
Ba SWA-L07-1315-T04-B 1 3.56E+02
Ba SWA-L07-1315-T05-B 1 3.82E+02
Ba SWA-L07-1315-T06-B 1 3.76E+02
Ba SWA-L07-1315-T07-B 1 3.49E+02
Ba SWA-L07-1315-T08-B 1 3.55E+02
Ba SWA-L07-1315-T09-B 1 3.00E+02
Ba SWA-L07-1315-T01-C 1 1.84E+01
Ba SWA-L07-1315-T02-C 1 1.62E+02
Ba SWA-L07-1315-T03-C 1 1.73E+02
Ba SWA-L07-1315-T04-C 1 2.95E+02
Ba SWA-L07-1315-T05-C 1 3.40E+02
Ba SWA-L07-1315-T06-C 1 3.77E+02
Ba SWA-L07-1315-T07-C 1 2.72E+02
Ba SWA-L07-1315-T08-C 1 3.42E+02
Ba SWA-L07-1315-T09-C 1 2.04E+02
Ba SWA-L07-1315-M01-A 1 5.00E-01 U1/2
Ba SWA-L07-1315-M02-A 1 5.00E-01 U1/2
Ba SWA-L07-1315-M03-A 1 5.00E-01 U1/2
Ba SWA-L07-1315-M04-A 1 5.00E-01 U1/2
Ba SWA-L07-1315-M05-A 1 5.00E-01 U1/2
Ba SWA-L07-1315-M06-A 1 5.00E-01 U1/2
Ba SWA-L07-1315-M07-A 1 5.00E-01 U1/2
Ba SWA-L07-1315-M08-A 1 5.00E-01 U1/2
Ba SWA-L07-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.01E+01 0.32 1.00 3.18
1.70E+02 0.14 1.00 3.18
1.75E+02 0.16 1.00 3.18 10000 1000
2.83E+02 0.58 1.00 3.18
3.25E+02 0.13 1.00 3.18
3.53E+02 0.44 1.00 3.18
3.60E+02 0.50 1.00 3.18
3.31E+02 0.41 1.00 3.18
2.80E+02 1.33 1.00 3.18
1.83E+01 1.24 1.00 3.18
1.63E+02 0.87 1.00 3.18
1.83E+02 0.66 1.00 3.18 10000 1000
3.56E+02 0.84 1.00 3.18
3.82E+02 1.04 1.00 3.18
3.76E+02 1.02 1.00 3.18
3.49E+02 0.95 1.00 3.18
3.55E+02 0.39 1.00 3.18
3.00E+02 0.66 1.00 3.18
1.84E+01 1.49 1.00 3.18
1.62E+02 0.09 1.00 3.18
1.73E+02 0.18 1.00 3.18 10000 1000
2.95E+02 0.62 1.00 3.18
3.40E+02 1.02 1.00 3.18
3.77E+02 0.45 1.00 3.18
2.72E+02 0.22 1.00 3.18
3.42E+02 0.30 1.00 3.18
2.04E+02 1.01 1.00 3.18
5.00E-01 11.24 1.00 3.18
5.00E-01 30.52 1.00 3.18
5.00E-01 74.61 1.00 3.18
5.00E-01 10.89 1.00 3.18
5.00E-01 44.08 1.00 3.18
5.00E-01 75.34 1.00 3.18
5.00E-01 63.88 1.00 3.18
5.00E-01 19.07 1.00 3.18
5.00E-01 52.22 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.15E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 1315 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315SWA
3/1/11 1:02 PM EPA Interlab L07 1315SWA
3/1/11 1:04 PM EPA Interlab L07 1315SWA
3/1/11 1:06 PM EPA Interlab L07 1315SWA
3/1/11 1:07 PM EPA Interlab L07 1315SWA
3/1/11 1:09 PM EPA Interlab L07 1315SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-588
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Be SWA-L07-1315-T01-A 1 9.50E-01 U1/2
Be SWA-L07-1315-T02-A 1 9.50E-01 U1/2
Be SWA-L07-1315-T03-A 1 9.50E-01 U1/2
Be SWA-L07-1315-T04-A 1 9.50E-01 U1/2
Be SWA-L07-1315-T05-A 1 9.50E-01 U1/2
Be SWA-L07-1315-T06-A 1 9.50E-01 U1/2
Be SWA-L07-1315-T07-A 1 9.50E-01 U1/2
Be SWA-L07-1315-T08-A 1 9.50E-01 U1/2
Be SWA-L07-1315-T09-A 1 9.50E-01 U1/2
Be SWA-L07-1315-T01-B 1 9.50E-01 U1/2
Be SWA-L07-1315-T02-B 1 9.50E-01 U1/2
Be SWA-L07-1315-T03-B 1 9.50E-01 U1/2
Be SWA-L07-1315-T04-B 1 9.50E-01 U1/2
Be SWA-L07-1315-T05-B 1 9.50E-01 U1/2
Be SWA-L07-1315-T06-B 1 9.50E-01 U1/2
Be SWA-L07-1315-T07-B 1 9.50E-01 U1/2
Be SWA-L07-1315-T08-B 1 9.50E-01 U1/2
Be SWA-L07-1315-T09-B 1 9.50E-01 U1/2
Be SWA-L07-1315-T01-C 1 9.50E-01 U1/2
Be SWA-L07-1315-T02-C 1 9.50E-01 U1/2
Be SWA-L07-1315-T03-C 1 9.50E-01 U1/2
Be SWA-L07-1315-T04-C 1 9.50E-01 U1/2
Be SWA-L07-1315-T05-C 1 9.50E-01 U1/2
Be SWA-L07-1315-T06-C 1 9.50E-01 U1/2
Be SWA-L07-1315-T07-C 1 9.50E-01 U1/2
Be SWA-L07-1315-T08-C 1 9.50E-01 U1/2
Be SWA-L07-1315-T09-C 1 9.50E-01 U1/2
Be SWA-L07-1315-M01-A 1 9.50E-01 U1/2
Be SWA-L07-1315-M02-A 1 9.50E-01 U1/2
Be SWA-L07-1315-M03-A 1 9.50E-01 U1/2
Be SWA-L07-1315-M04-A 1 9.50E-01 U1/2
Be SWA-L07-1315-M05-A 1 9.50E-01 U1/2
Be SWA-L07-1315-M06-A 1 9.50E-01 U1/2
Be SWA-L07-1315-M07-A 1 9.50E-01 U1/2
Be SWA-L07-1315-M08-A 1 9.50E-01 U1/2
Be SWA-L07-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 33.65 1.90 6.00
9.50E-01 20.90 1.90 6.00
9.50E-01 30.69 1.90 6.00 10000 1000
9.50E-01 23.25 1.90 6.00
9.50E-01 10.05 1.90 6.00
9.50E-01 25.12 1.90 6.00
9.50E-01 17.16 1.90 6.00
9.50E-01 8.72 1.90 6.00
9.50E-01 12.40 1.90 6.00
9.50E-01 67.96 1.90 6.00
9.50E-01 22.20 1.90 6.00
9.50E-01 16.41 1.90 6.00 10000 1000
9.50E-01 14.45 1.90 6.00
9.50E-01 13.57 1.90 6.00
9.50E-01 25.43 1.90 6.00
9.50E-01 10.84 1.90 6.00
9.50E-01 25.95 1.90 6.00
9.50E-01 10.10 1.90 6.00
9.50E-01 63.80 1.90 6.00
9.50E-01 53.53 1.90 6.00
9.50E-01 21.38 1.90 6.00 10000 1000
9.50E-01 32.89 1.90 6.00
9.50E-01 59.87 1.90 6.00
9.50E-01 59.18 1.90 6.00
9.50E-01 21.06 1.90 6.00
9.50E-01 25.68 1.90 6.00
9.50E-01 15.39 1.90 6.00
9.50E-01 75.87 1.90 6.00
9.50E-01 11.40 1.90 6.00
9.50E-01 26.25 1.90 6.00
9.50E-01 30.88 1.90 6.00
9.50E-01 46.45 1.90 6.00
9.50E-01 14.92 1.90 6.00
9.50E-01 53.63 1.90 6.00
9.50E-01 17.15 1.90 6.00
9.50E-01 25.53 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.05E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.59E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.30E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 131 5 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315SWA
3/1/11 1:02 PM EPA Interlab L07 1315SWA
3/1/11 1:04 PM EPA Interlab L07 1315SWA
3/1/11 1:06 PM EPA Interlab L07 1315SWA
3/1/11 1:07 PM EPA Interlab L07 1315SWA
3/1/11 1:09 PM EPA Interlab L07 1315SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-589
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cd SWA-L07-1315-T01-A 1 1.10E+00 U1/2
Cd SWA-L07-1315-T02-A 1 1.10E+00 U1/2
Cd SWA-L07-1315-T03-A 1 1.10E+00 U1/2
Cd SWA-L07-1315-T04-A 1 1.10E+00 U1/2
Cd SWA-L07-1315-T05-A 1 1.10E+00 U1/2
Cd SWA-L07-1315-T06-A 1 1.10E+00 U1/2
Cd SWA-L07-1315-T07-A 1 1.10E+00 U1/2
Cd SWA-L07-1315-T08-A 1 1.10E+00 U1/2
Cd SWA-L07-1315-T09-A 1 1.10E+00 U1/2
Cd SWA-L07-1315-T01-B 1 1.10E+00 U1/2
Cd SWA-L07-1315-T02-B 1 1.10E+00 U1/2
Cd SWA-L07-1315-T03-B 1 1.10E+00 U1/2
Cd SWA-L07-1315-T04-B 1 1.10E+00 U1/2
Cd SWA-L07-1315-T05-B 1 1.10E+00 U1/2
Cd SWA-L07-1315-T06-B 1 1.10E+00 U1/2
Cd SWA-L07-1315-T07-B 1 1.10E+00 U1/2
Cd SWA-L07-1315-T08-B 1 1.10E+00 U1/2
Cd SWA-L07-1315-T09-B 1 1.10E+00 U1/2
Cd SWA-L07-1315-T01-C 1 1.10E+00 U1/2
Cd SWA-L07-1315-T02-C 1 1.10E+00 U1/2
Cd SWA-L07-1315-T03-C 1 1.10E+00 U1/2
Cd SWA-L07-1315-T04-C 1 1.10E+00 U1/2
Cd SWA-L07-1315-T05-C 1 1.10E+00 U1/2
Cd SWA-L07-1315-T06-C 1 1.10E+00 U1/2
Cd SWA-L07-1315-T07-C 1 1.10E+00 U1/2
Cd SWA-L07-1315-T08-C 1 1.10E+00 U1/2
Cd SWA-L07-1315-T09-C 1 1.10E+00 U1/2
Cd SWA-L07-1315-M01-A 1 1.10E+00 U1/2
Cd SWA-L07-1315-M02-A 1 1.10E+00 U1/2
Cd SWA-L07-1315-M03-A 1 1.10E+00 U1/2
Cd SWA-L07-1315-M04-A 1 1.10E+00 U1/2
Cd SWA-L07-1315-M05-A 1 1.10E+00 U1/2
Cd SWA-L07-1315-M06-A 1 1.10E+00 U1/2
Cd SWA-L07-1315-M07-A 1 1.10E+00 U1/2
Cd SWA-L07-1315-M08-A 1 1.10E+00 U1/2
Cd SWA-L07-1315-M09-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 35.82 2.20 7.00
1.10E+00 21.06 2.20 7.00
1.10E+00 27.96 2.20 7.00 10000 1000
1.10E+00 24.08 2.20 7.00
1.10E+00 50.69 2.20 7.00
1.10E+00 28.95 2.20 7.00
1.10E+00 25.04 2.20 7.00
1.10E+00 21.65 2.20 7.00
1.10E+00 11.45 2.20 7.00
1.10E+00 29.63 2.20 7.00
1.10E+00 7.36 2.20 7.00
1.10E+00 25.03 2.20 7.00 10000 1000
1.10E+00 62.93 2.20 7.00
1.10E+00 18.19 2.20 7.00
1.10E+00 8.84 2.20 7.00
1.10E+00 11.62 2.20 7.00
1.10E+00 68.89 2.20 7.00
1.10E+00 68.69 2.20 7.00
1.10E+00 23.93 2.20 7.00
1.10E+00 11.16 2.20 7.00
1.10E+00 16.29 2.20 7.00 10000 1000
1.10E+00 7.74 2.20 7.00
1.10E+00 12.14 2.20 7.00
1.10E+00 19.88 2.20 7.00
1.10E+00 41.05 2.20 7.00
1.10E+00 16.64 2.20 7.00
1.10E+00 66.38 2.20 7.00
1.10E+00 13.23 2.20 7.00
1.10E+00 28.11 2.20 7.00
1.10E+00 18.79 2.20 7.00
1.10E+00 82.05 2.20 7.00
1.10E+00 42.93 2.20 7.00
1.10E+00 10.62 2.20 7.00
1.10E+00 33.78 2.20 7.00
1.10E+00 45.71 2.20 7.00
1.10E+00 6.00 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.06E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.70E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.46E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 1315 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :02 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :04 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :06 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :07 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :09 PM EPA Interlab L07 1315 SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-590
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Ca SWA-L07-1315-T01-A 1 2.08E+03
Ca SWA-L07-1315-T02-A 1 1.82E+04
Ca SWA-L07-1315-T03-A 1 1.75E+04
Ca SWA-L07-1315-T04-A 1 2.77E+04
Ca SWA-L07-1315-T05-A 1 2.81E+04
Ca SWA-L07-1315-T06-A 1 2.90E+04
Ca SWA-L07-1315-T07-A 1 2.63E+04
Ca SWA-L07-1315-T08-A 1 2.22E+04
Ca SWA-L07-1315-T09-A 1 1.88E+04
Ca SWA-L07-1315-T01-B 1 1.98E+03
Ca SWA-L07-1315-T02-B 1 1.55E+04
Ca SWA-L07-1315-T03-B 1 1.55E+04
Ca SWA-L07-1315-T04-B 1 2.61E+04
Ca SWA-L07-1315-T05-B 1 2.74E+04
Ca SWA-L07-1315-T06-B 1 2.86E+04
Ca SWA-L07-1315-T07-B 1 2.35E+04
Ca SWA-L07-1315-T08-B 1 2.25E+04
Ca SWA-L07-1315-T09-B 1 1.92E+04
Ca SWA-L07-1315-T01-C 1 2.11E+03
Ca SWA-L07-1315-T02-C 1 1.64E+04
Ca SWA-L07-1315-T03-C 1 1.69E+04
Ca SWA-L07-1315-T04-C 1 2.74E+04
Ca SWA-L07-1315-T05-C 1 2.69E+04
Ca SWA-L07-1315-T06-C 1 2.93E+04
Ca SWA-L07-1315-T07-C 1 1.75E+04
Ca SWA-L07-1315-T08-C 1 2.17E+04
Ca SWA-L07-1315-T09-C 1 1.28E+04
Ca SWA-L07-1315-M01-A 1 1.86E+02
Ca SWA-L07-1315-M02-A 1 1.27E+02
Ca SWA-L07-1315-M03-A 1 4.25E+01
Ca SWA-L07-1315-M04-A 1 1.26E+02
Ca SWA-L07-1315-M05-A 1 9.36E+01
Ca SWA-L07-1315-M06-A 1 7.32E+01
Ca SWA-L07-1315-M07-A 1 5.03E+01
Ca SWA-L07-1315-M08-A 1 2.37E+01
Ca SWA-L07-1315-M09-A 1 5.65E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.08E+03 0.17 2.60 8.30
1.82E+04 0.38 2.60 8.30
1.75E+04 0.30 2.60 8.30 10000 1000
2.77E+04 0.36 2.60 8.30
2.81 E+04 0.29 2.60 8.30
2.90E+04 0.35 2.60 8.30
2.63E+04 0.65 2.60 8.30
2.22E+04 0.81 2.60 8.30
1.88E+04 0.96 2.60 8.30
1.98E+03 1.11 2.60 8.30
1.55E+04 0.51 2.60 8.30
1.55E+04 0.36 2.60 8.30 10000 1000
2.61 E+04 0.64 2.60 8.30
2.74E+04 0.77 2.60 8.30
2.86E+04 0.88 2.60 8.30
2.35E+04 0.71 2.60 8.30
2.25E+04 0.32 2.60 8.30
1.92E+04 0.60 2.60 8.30
2.11E+03 2.44 2.60 8.30
1.64E+04 0.46 2.60 8.30
1.69E+04 0.19 2.60 8.30 10000 1000
2.74E+04 0.67 2.60 8.30
2.69E+04 1.93 2.60 8.30
2.93E+04 0.58 2.60 8.30
1.75E+04 0.61 2.60 8.30
2.17E+04 0.03 2.60 8.30
1.28E+04 0.49 2.60 8.30
1.86E+02 3.96 2.60 8.30
1.27E+02 6.91 2.60 8.30
4.25E+01 10.37 2.60 8.30
1.26E+02 6.34 2.60 8.30
9.36E+01 4.18 2.60 8.30
7.32E+01 3.30 2.60 8.30
5.03E+01 6.48 2.60 8.30
2.37E+01 3.65 2.60 8.30
5.65E+01 6.55 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.84E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.65E+04 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.78E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 1315 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :02 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :04 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :06 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :07 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :09 PM EPA Interlab L07 1315 SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-591
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Cr SWA-L07-1315-T01-A 1 5.09E+01
Cr SWA-L07-1315-T02-A 1 4.94E+01
Cr SWA-L07-1315-T03-A 1 2.68E+01
Cr SWA-L07-1315-T04-A 1 5.11E+01
Cr SWA-L07-1315-T05-A 1 4.99E+01
Cr SWA-L07-1315-T06-A 1 5.81 E+01
Cr SWA-L07-1315-T07-A 1 5.32E+01
Cr SWA-L07-1315-T08-A 1 3.41 E+01
Cr SWA-L07-1315-T09-A 1 4.82E+01
Cr SWA-L07-1315-T01-B 1 4.96E+01
Cr SWA-L07-1315-T02-B 1 5.35E+01
Cr SWA-L07-1315-T03-B 1 2.70E+01
Cr SWA-L07-1315-T04-B 1 5.08E+01
Cr SWA-L07-1315-T05-B 1 4.71E+01
Cr SWA-L07-1315-T06-B 1 5.52E+01
Cr SWA-L07-1315-T07-B 1 5.04E+01
Cr SWA-L07-1315-T08-B 1 3.36E+01
Cr SWA-L07-1315-T09-B 1 4.64E+01
Cr SWA-L07-1315-T01-C 1 4.41E+01
Cr SWA-L07-1315-T02-C 1 5.60E+01
Cr SWA-L07-1315-T03-C 1 2.84E+01
Cr SWA-L07-1315-T04-C 1 5.50E+01
Cr SWA-L07-1315-T05-C 1 4.75E+01
Cr SWA-L07-1315-T06-C 1 5.85E+01
Cr SWA-L07-1315-T07-C 1 5.50E+01
Cr SWA-L07-1315-T08-C 1 3.46E+01
Cr SWA-L07-1315-T09-C 1 5.43E+01
Cr SWA-L07-1315-M01-A 1 6.00E-01 U1/2
Cr SWA-L07-1315-M02-A 1 6.00E-01 U1/2
Cr SWA-L07-1315-M03-A 1 6.00E-01 U1/2
Cr SWA-L07-1315-M04-A 1 6.00E-01 U1/2
Cr SWA-L07-1315-M05-A 1 6.00E-01 U1/2
Cr SWA-L07-1315-M06-A 1 6.00E-01 U1/2
Cr SWA-L07-1315-M07-A 1 6.00E-01 U1/2
Cr SWA-L07-1315-M08-A 1 6.00E-01 U1/2
Cr SWA-L07-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.09E+01 1.20 1.20 3.82
4.94E+01 0.49 1.20 3.82
2.68E+01 0.96 1.20 3.82 10000 1000
5. 11 E+01 1.35 1.20 3.82
4.99E+01 1.73 1.20 3.82
5.81E+01 1.13 1.20 3.82
5.32E+01 0.83 1.20 3.82
3.41E+01 0.60 1.20 3.82
4.82E+01 0.90 1.20 3.82
4.96E+01 2.12 1.20 3.82
5.35E+01 0.72 1.20 3.82
2.70E+01 0.79 1.20 3.82 10000 1000
5.08E+01 0.36 1.20 3.82
4.71E+01 0.61 1.20 3.82
5.52E+01 1.16 1.20 3.82
5.04E+01 0.90 1.20 3.82
3.36E+01 1.63 1.20 3.82
4.64E+01 0.51 1.20 3.82
4.41E+01 1.48 1.20 3.82
5.60E+01 1.42 1.20 3.82
2.84E+01 0.68 1.20 3.82 10000 1000
5.50E+01 1.71 1.20 3.82
4.75E+01 1.05 1.20 3.82
5.85E+01 0.69 1.20 3.82
5.50E+01 0.80 1.20 3.82
3.46E+01 0.64 1.20 3.82
5.43E+01 0.84 1.20 3.82
6.00E-01 17.89 1.20 3.82
6.00E-01 42.38 1.20 3.82
6.00E-01 18.96 1.20 3.82
6.00E-01 22.75 1.20 3.82
6.00E-01 58.08 1.20 3.82
6.00E-01 20.05 1.20 3.82
6.00E-01 39.84 1.20 3.82
6.00E-01 35.23 1.20 3.82
6.00E-01 23.78 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.07E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.87E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.62E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 1315 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315SWA
3/1/11 1:02 PM EPA Interlab L07 1315SWA
3/1/11 1:04 PM EPA Interlab L07 1315SWA
3/1/11 1:06 PM EPA Interlab L07 1315SWA
3/1/11 1:07 PM EPA Interlab L07 1315SWA
3/1/11 1:09 PM EPA Interlab L07 1315SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-592
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Co SWA-L07-1315-T01-A 1 9.00E-01 U1/2
Co SWA-L07-1315-T02-A 1 9.00E-01 U1/2
Co SWA-L07-1315-T03-A 1 9.00E-01 U1/2
Co SWA-L07-1315-T04-A 1 9.00E-01 U1/2
Co SWA-L07-1315-T05-A 1 9.00E-01 U1/2
Co SWA-L07-1315-T06-A 1 9.00E-01 U1/2
Co SWA-L07-1315-T07-A 1 9.00E-01 U1/2
Co SWA-L07-1315-T08-A 1 9.00E-01 U1/2
Co SWA-L07-1315-T09-A 1 9.00E-01 U1/2
Co SWA-L07-1315-T01-B 1 9.00E-01 U1/2
Co SWA-L07-1315-T02-B 1 9.00E-01 U1/2
Co SWA-L07-1315-T03-B 1 9.00E-01 U1/2
Co SWA-L07-1315-T04-B 1 9.00E-01 U1/2
Co SWA-L07-1315-T05-B 1 9.00E-01 U1/2
Co SWA-L07-1315-T06-B 1 9.00E-01 U1/2
Co SWA-L07-1315-T07-B 1 9.00E-01 U1/2
Co SWA-L07-1315-T08-B 1 9.00E-01 U1/2
Co SWA-L07-1315-T09-B 1 9.00E-01 U1/2
Co SWA-L07-1315-T01-C 1 9.00E-01 U1/2
Co SWA-L07-1315-T02-C 1 9.00E-01 U1/2
Co SWA-L07-1315-T03-C 1 9.00E-01 U1/2
Co SWA-L07-1315-T04-C 1 9.00E-01 U1/2
Co SWA-L07-1315-T05-C 1 9.00E-01 U1/2
Co SWA-L07-1315-T06-C 1 9.00E-01 U1/2
Co SWA-L07-1315-T07-C 1 9.00E-01 U1/2
Co SWA-L07-1315-T08-C 1 9.00E-01 U1/2
Co SWA-L07-1315-T09-C 1 9.00E-01 U1/2
Co SWA-L07-1315-M01-A 1 9.00E-01 U1/2
Co SWA-L07-1315-M02-A 1 9.00E-01 U1/2
Co SWA-L07-1315-M03-A 1 9.00E-01 U1/2
Co SWA-L07-1315-M04-A 1 9.00E-01 U1/2
Co SWA-L07-1315-M05-A 1 9.00E-01 U1/2
Co SWA-L07-1315-M06-A 1 9.00E-01 U1/2
Co SWA-L07-1315-M07-A 1 9.00E-01 U1/2
Co SWA-L07-1315-M08-A 1 9.00E-01 U1/2
Co SWA-L07-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 29.73 1.80 5.72
9.00E-01 15.18 1.80 5.72
9.00E-01 47.84 1.80 5.72 10000 1000
9.00E-01 18.56 1.80 5.72
9.00E-01 18.53 1.80 5.72
9.00E-01 64.15 1.80 5.72
9.00E-01 16.00 1.80 5.72
9.00E-01 13.35 1.80 5.72
9.00E-01 17.64 1.80 5.72
9.00E-01 34.69 1.80 5.72
9.00E-01 14.26 1.80 5.72
9.00E-01 17.35 1.80 5.72 10000 1000
9.00E-01 45.77 1.80 5.72
9.00E-01 23.28 1.80 5.72
9.00E-01 14.95 1.80 5.72
9.00E-01 12.26 1.80 5.72
9.00E-01 13.84 1.80 5.72
9.00E-01 30.49 1.80 5.72
9.00E-01 29.81 1.80 5.72
9.00E-01 26.50 1.80 5.72
9.00E-01 49.27 1.80 5.72 10000 1000
9.00E-01 19.93 1.80 5.72
9.00E-01 37.98 1.80 5.72
9.00E-01 16.11 1.80 5.72
9.00E-01 42.97 1.80 5.72
9.00E-01 39.57 1.80 5.72
9.00E-01 45.16 1.80 5.72
9.00E-01 15.96 1.80 5.72
9.00E-01 35.77 1.80 5.72
9.00E-01 11.91 1.80 5.72
9.00E-01 61.48 1.80 5.72
9.00E-01 7.57 1.80 5.72
9.00E-01 30.89 1.80 5.72
9.00E-01 15.56 1.80 5.72
9.00E-01 25.47 1.80 5.72
9.00E-01 27.11 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.31E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.03E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 1315 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :02 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :04 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :06 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :07 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :09 PM EPA Interlab L07 1315 SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-593
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cu SWA-L07-1315-T01-A 1 1.85E+00 U1/2
Cu SWA-L07-1315-T02-A 1 1.85E+00 U1/2
Cu SWA-L07-1315-T03-A 1 1.85E+00 U1/2
Cu SWA-L07-1315-T04-A 1 1.85E+00 U1/2
Cu SWA-L07-1315-T05-A 1 1.85E+00 U1/2
Cu SWA-L07-1315-T06-A 1 1.85E+00 U1/2
Cu SWA-L07-1315-T07-A 1 1.85E+00 U1/2
Cu SWA-L07-1315-T08-A 1 1.85E+00 U1/2
Cu SWA-L07-1315-T09-A 1 1.85E+00 U1/2
Cu SWA-L07-1315-T01-B 1 1.85E+00 U1/2
Cu SWA-L07-1315-T02-B 1 1.85E+00 U1/2
Cu SWA-L07-1315-T03-B 1 1.85E+00 U1/2
Cu SWA-L07-1315-T04-B 1 1.85E+00 U1/2
Cu SWA-L07-1315-T05-B 1 1.85E+00 U1/2
Cu SWA-L07-1315-T06-B 1 1.85E+00 U1/2
Cu SWA-L07-1315-T07-B 1 1.85E+00 U1/2
Cu SWA-L07-1315-T08-B 1 1.85E+00 U1/2
Cu SWA-L07-1315-T09-B 1 1.85E+00 U1/2
Cu SWA-L07-1315-T01-C 1 1.85E+00 U1/2
Cu SWA-L07-1315-T02-C 1 1.85E+00 U1/2
Cu SWA-L07-1315-T03-C 1 1.85E+00 U1/2
Cu SWA-L07-1315-T04-C 1 1.85E+00 U1/2
Cu SWA-L07-1315-T05-C 1 1.85E+00 U1/2
Cu SWA-L07-1315-T06-C 1 1.85E+00 U1/2
Cu SWA-L07-1315-T07-C 1 1.85E+00 U1/2
Cu SWA-L07-1315-T08-C 1 1.85E+00 U1/2
Cu SWA-L07-1315-T09-C 1 1.85E+00 U1/2
Cu SWA-L07-1315-M01-A 1 1.85E+00 U1/2
Cu SWA-L07-1315-M02-A 1 1.85E+00 U1/2
Cu SWA-L07-1315-M03-A 1 1.85E+00 U1/2
Cu SWA-L07-1315-M04-A 1 1.85E+00 U1/2
Cu SWA-L07-1315-M05-A 1 1.85E+00 U1/2
Cu SWA-L07-1315-M06-A 1 1.85E+00 U1/2
Cu SWA-L07-1315-M07-A 1 1.85E+00 U1/2
Cu SWA-L07-1315-M08-A 1 1.85E+00 U1/2
Cu SWA-L07-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 10.61 3.70 11.80
1.85E+00 27.34 3.70 11.80
1.85E+00 10.37 3.70 11.80 10000 1000
1.85E+00 53.50 3.70 11.80
1.85E+00 32.71 3.70 11.80
1.85E+00 42.02 3.70 11.80
1.85E+00 30.28 3.70 11.80
1.85E+00 51.50 3.70 11.80
1.85E+00 47.25 3.70 11.80
1.85E+00 22.12 3.70 11.80
1.85E+00 66.98 3.70 11.80
1.85E+00 13.42 3.70 11.80 10000 1000
1.85E+00 37.04 3.70 11.80
1.85E+00 61.65 3.70 11.80
1.85E+00 15.17 3.70 11.80
1.85E+00 60.84 3.70 11.80
1.85E+00 8.01 3.70 11.80
1.85E+00 9.69 3.70 11.80
1.85E+00 25.06 3.70 11.80
1.85E+00 39.92 3.70 11.80
1.85E+00 52.46 3.70 11.80 10000 1000
1.85E+00 28.36 3.70 11.80
1.85E+00 55.39 3.70 11.80
1.85E+00 14.12 3.70 11.80
1.85E+00 34.61 3.70 11.80
1.85E+00 9.02 3.70 11.80
1.85E+00 13.65 3.70 11.80
1.85E+00 10.01 3.70 11.80
1.85E+00 70.58 3.70 11.80
1.85E+00 46.55 3.70 11.80
1.85E+00 23.89 3.70 11.80
1.85E+00 44.75 3.70 11.80
1.85E+00 23.84 3.70 11.80
1.85E+00 20.79 3.70 11.80
1.85E+00 25.21 3.70 11.80
1.85E+00 58.11 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.20E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.89E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 1315 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :02 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :04 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :06 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :07 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :09 PM EPA Interlab L07 1315 SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-594
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Fe SWA-L07-1315-T01-A 1 1.08E+01
Fe SWA-L07-1315-T02-A 1 9.10E+00
Fe SWA-L07-1315-T03-A 1 4.73E+00 E
Fe SWA-L07-1315-T04-A 1 5.29E+00 E
Fe SWA-L07-1315-T05-A 1 4.29E+00 E
Fe SWA-L07-1315-T06-A 1 3.28E+00 E
Fe SWA-L07-1315-T07-A 1 3.64E+00 E
Fe SWA-L07-1315-T08-A 1 2.34E+00 E
Fe SWA-L07-1315-T09-A 1 1.00E+00 U1/2
Fe SWA-L07-1315-T01-B 1 1.17E+01
Fe SWA-L07-1315-T02-B 1 9.00E+00
Fe SWA-L07-1315-T03-B 1 4.22E+00 E
Fe SWA-L07-1315-T04-B 1 6.00E+00 E
Fe SWA-L07-1315-T05-B 1 3.95E+00 E
Fe SWA-L07-1315-T06-B 1 5.55E+00 E
Fe SWA-L07-1315-T07-B 1 2.79E+00 E
Fe SWA-L07-1315-T08-B 1 5.98E+00 E
Fe SWA-L07-1315-T09-B 1 2.29E+00 E
Fe SWA-L07-1315-T01-C 1 1.21E+01
Fe SWA-L07-1315-T02-C 1 9.85E+00
Fe SWA-L07-1315-T03-C 1 5.08E+00 E
Fe SWA-L07-1315-T04-C 1 5.40E+00 E
Fe SWA-L07-1315-T05-C 1 3.38E+00 E
Fe SWA-L07-1315-T06-C 1 3.32E+00 E
Fe SWA-L07-1315-T07-C 1 6.22E+00 E
Fe SWA-L07-1315-T08-C 1 2.41E+00 E
Fe SWA-L07-1315-T09-C 1 1.97E+01
Fe SWA-L07-1315-M01-A 1 1.00E+00 U1/2
Fe SWA-L07-1315-M02-A 1 1.00E+00 U1/2
Fe SWA-L07-1315-M03-A 1 1.00E+00 U1/2
Fe SWA-L07-1315-M04-A 1 1.00E+00 U1/2
Fe SWA-L07-1315-M05-A 1 1.00E+00 U1/2
Fe SWA-L07-1315-M06-A 1 1.00E+00 U1/2
Fe SWA-L07-1315-M07-A 1 1.00E+00 U1/2
Fe SWA-L07-1315-M08-A 1 1.00E+00 U1/2
Fe SWA-L07-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.08E+01 4.89 2.00 6.40
9.10E+00 1.11 2.00 6.40
4.73E+00 8.11 2.00 6.40 10000 1000
5.29E+00 6.22 2.00 6.40
4.29E+00 13.03 2.00 6.40
3.28E+00 12.35 2.00 6.40
3.64E+00 5.26 2.00 6.40
2.34E+00 12.92 2.00 6.40
1.00E+00 8.90 2.00 6.40
1.17E+01 4.18 2.00 6.40
9.00E+00 2.73 2.00 6.40
4.22E+00 10.14 2.00 6.40 10000 1000
6.00E+00 6.49 2.00 6.40
3.95E+00 3.28 2.00 6.40
5.55E+00 8.87 2.00 6.40
2.79E+00 14.85 2.00 6.40
5.98E+00 9.29 2.00 6.40
2.29E+00 1.99 2.00 6.40
1.21E+01 3.86 2.00 6.40
9.85E+00 0.62 2.00 6.40
5.08E+00 6.40 2.00 6.40 10000 1000
5.40E+00 6.83 2.00 6.40
3.38E+00 2.51 2.00 6.40
3.32E+00 8.28 2.00 6.40
6.22E+00 2.17 2.00 6.40
2.41 E+00 1.53 2.00 6.40
1.97E+01 3.21 2.00 6.40
1.00E+00 29.98 2.00 6.40
1.00E+00 10.86 2.00 6.40
1.00E+00 32.55 2.00 6.40
1.00E+00 10.28 2.00 6.40
1.00E+00 33.18 2.00 6.40
1.00E+00 13.30 2.00 6.40
1.00E+00 10.73 2.00 6.40
1.00E+00 33.10 2.00 6.40
1.00E+00 28.41 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.09E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.99E+02 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.56E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 1315 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :02 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :04 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :06 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :07 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :09 PM EPA Interlab L07 1315 SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315 SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-595
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Pb SWA-L07-1315-T01-A 1 3.40E+00 U1/2
Pb SWA-L07-1315-T02-A 1 3.40E+00 U1/2
Pb SWA-L07-1315-T03-A 1 3.40E+00 U1/2
Pb SWA-L07-1315-T04-A 1 3.40E+00 U1/2
Pb SWA-L07-1315-T05-A 1 3.40E+00 U1/2
Pb SWA-L07-1315-T06-A 1 3.40E+00 U1/2
Pb SWA-L07-1315-T07-A 1 3.40E+00 U1/2
Pb SWA-L07-1315-T08-A 1 3.40E+00 U1/2
Pb SWA-L07-1315-T09-A 1 3.40E+00 U1/2
Pb SWA-L07-1315-T01-B 1 3.40E+00 U1/2
Pb SWA-L07-1315-T02-B 1 3.40E+00 U1/2
Pb SWA-L07-1315-T03-B 1 3.40E+00 U1/2
Pb SWA-L07-1315-T04-B 1 3.40E+00 U1/2
Pb SWA-L07-1315-T05-B 1 3.40E+00 U1/2
Pb SWA-L07-1315-T06-B 1 3.40E+00 U1/2
Pb SWA-L07-1315-T07-B 1 3.40E+00 U1/2
Pb SWA-L07-1315-T08-B 1 3.40E+00 U1/2
Pb SWA-L07-1315-T09-B 1 3.40E+00 U1/2
Pb SWA-L07-1315-T01-C 1 3.40E+00 U1/2
Pb SWA-L07-1315-T02-C 1 3.40E+00 U1/2
Pb SWA-L07-1315-T03-C 1 3.40E+00 U1/2
Pb SWA-L07-1315-T04-C 1 3.40E+00 U1/2
Pb SWA-L07-1315-T05-C 1 3.40E+00 U1/2
Pb SWA-L07-1315-T06-C 1 3.40E+00 U1/2
Pb SWA-L07-1315-T07-C 1 3.40E+00 U1/2
Pb SWA-L07-1315-T08-C 1 3.40E+00 U1/2
Pb SWA-L07-1315-T09-C 1 3.40E+00 U1/2
Pb SWA-L07-1315-M01-A 1 3.40E+00 U1/2
Pb SWA-L07-1315-M02-A 1 3.40E+00 U1/2
Pb SWA-L07-1315-M03-A 1 3.40E+00 U1/2
Pb SWA-L07-1315-M04-A 1 3.40E+00 U1/2
Pb SWA-L07-1315-M05-A 1 3.40E+00 U1/2
Pb SWA-L07-1315-M06-A 1 3.40E+00 U1/2
Pb SWA-L07-1315-M07-A 1 3.40E+00 U1/2
Pb SWA-L07-1315-M08-A 1 3.40E+00 U1/2
Pb SWA-L07-1315-M09-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 14.89 6.80 21.60
3.40E+00 23.92 6.80 21.60
3.40E+00 14.09 6.80 21.60 10000 1000
3.40E+00 46.66 6.80 21.60
3.40E+00 30.12 6.80 21.60
3.40E+00 29.92 6.80 21.60
3.40E+00 37.23 6.80 21.60
3.40E+00 31.46 6.80 21.60
3.40E+00 20.99 6.80 21.60
3.40E+00 22.35 6.80 21.60
3.40E+00 33.83 6.80 21.60
3.40E+00 16.32 6.80 21.60 10000 1000
3.40E+00 22.26 6.80 21.60
3.40E+00 57.93 6.80 21.60
3.40E+00 39.74 6.80 21.60
3.40E+00 12.12 6.80 21.60
3.40E+00 18.38 6.80 21.60
3.40E+00 38.88 6.80 21.60
3.40E+00 28.26 6.80 21.60
3.40E+00 6.94 6.80 21.60
3.40E+00 37.07 6.80 21.60 10000 1000
3.40E+00 16.60 6.80 21.60
3.40E+00 17.28 6.80 21.60
3.40E+00 29.11 6.80 21.60
3.40E+00 41.50 6.80 21.60
3.40E+00 37.67 6.80 21.60
3.40E+00 17.81 6.80 21.60
3.40E+00 17.01 6.80 21.60
3.40E+00 47.79 6.80 21.60
3.40E+00 37.87 6.80 21.60
3.40E+00 17.99 6.80 21.60
3.40E+00 24.56 6.80 21.60
3.40E+00 10.34 6.80 21.60
3.40E+00 10.59 6.80 21.60
3.40E+00 14.40 6.80 21.60
3.40E+00 25.29 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.26E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.02E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 131 5 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315SWA
3/1/11 1:02 PM EPA Interlab L07 1315SWA
3/1/11 1:04 PM EPA Interlab L07 1315SWA
3/1/11 1:06 PM EPA Interlab L07 1315SWA
3/1/11 1:07 PM EPA Interlab L07 1315SWA
3/1/11 1:09 PM EPA Interlab L07 1315SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-596
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Li SWA-L07-1315-T01-A 1 9.50E-01 U1/2
Li SWA-L07-1315-T02-A 1 9.50E-01 U1/2
Li SWA-L07-1315-T03-A 1 9.50E-01 U1/2
Li SWA-L07-1315-T04-A 1 9.50E-01 U1/2
Li SWA-L07-1315-T05-A 1 9.50E-01 U1/2
Li SWA-L07-1315-T06-A 1 9.50E-01 U1/2
Li SWA-L07-1315-T07-A 1 9.50E-01 U1/2
Li SWA-L07-1315-T08-A 1 9.50E-01 U1/2
Li SWA-L07-1315-T09-A 1 9.50E-01 U1/2
Li SWA-L07-1315-T01-B 1 9.50E-01 U1/2
Li SWA-L07-1315-T02-B 1 9.50E-01 U1/2
Li SWA-L07-1315-T03-B 1 9.50E-01 U1/2
Li SWA-L07-1315-T04-B 1 9.50E-01 U1/2
Li SWA-L07-1315-T05-B 1 9.50E-01 U1/2
Li SWA-L07-1315-T06-B 1 9.50E-01 U1/2
Li SWA-L07-1315-T07-B 1 9.50E-01 U1/2
Li SWA-L07-1315-T08-B 1 9.50E-01 U1/2
Li SWA-L07-1315-T09-B 1 9.50E-01 U1/2
Li SWA-L07-1315-T01-C 1 9.50E-01 U1/2
Li SWA-L07-1315-T02-C 1 9.50E-01 U1/2
Li SWA-L07-1315-T03-C 1 9.50E-01 U1/2
Li SWA-L07-1315-T04-C 1 9.50E-01 U1/2
Li SWA-L07-1315-T05-C 1 9.50E-01 U1/2
Li SWA-L07-1315-T06-C 1 9.50E-01 U1/2
Li SWA-L07-1315-T07-C 1 9.50E-01 U1/2
Li SWA-L07-1315-T08-C 1 9.50E-01 U1/2
Li SWA-L07-1315-T09-C 1 9.50E-01 U1/2
Li SWA-L07-1315-M01-A 1 9.50E-01 U1/2
Li SWA-L07-1315-M02-A 1 9.50E-01 U1/2
Li SWA-L07-1315-M03-A 1 9.50E-01 U1/2
Li SWA-L07-1315-M04-A 1 9.50E-01 U1/2
Li SWA-L07-1315-M05-A 1 9.50E-01 U1/2
Li SWA-L07-1315-M06-A 1 9.50E-01 U1/2
Li SWA-L07-1315-M07-A 1 9.50E-01 U1/2
Li SWA-L07-1315-M08-A 1 9.50E-01 U1/2
Li SWA-L07-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 3.36 1.90 6.00
9.50E-01 5.25 1.90 6.00
9.50E-01 13.36 1.90 6.00 10000 1000
9.50E-01 5.25 1.90 6.00
9.50E-01 1.56 1.90 6.00
9.50E-01 6.07 1.90 6.00
9.50E-01 2.09 1.90 6.00
9.50E-01 6.73 1.90 6.00
9.50E-01 5.93 1.90 6.00
9.50E-01 2.10 1.90 6.00
9.50E-01 2.61 1.90 6.00
9.50E-01 7.23 1.90 6.00 10000 1000
9.50E-01 1.62 1.90 6.00
9.50E-01 3.87 1.90 6.00
9.50E-01 5.20 1.90 6.00
9.50E-01 9.19 1.90 6.00
9.50E-01 1.21 1.90 6.00
9.50E-01 7.83 1.90 6.00
9.50E-01 1.79 1.90 6.00
9.50E-01 11.06 1.90 6.00
9.50E-01 1.05 1.90 6.00 10000 1000
9.50E-01 8.23 1.90 6.00
9.50E-01 8.02 1.90 6.00
9.50E-01 4.35 1.90 6.00
9.50E-01 3.76 1.90 6.00
9.50E-01 6.11 1.90 6.00
9.50E-01 4.55 1.90 6.00
9.50E-01 5.45 1.90 6.00
9.50E-01 1.37 1.90 6.00
9.50E-01 6.14 1.90 6.00
9.50E-01 5.85 1.90 6.00
9.50E-01 5.84 1.90 6.00
9.50E-01 6.30 1.90 6.00
9.50E-01 6.04 1.90 6.00
9.50E-01 7.43 1.90 6.00
9.50E-01 7.57 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.55E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.17E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.81 E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 1315 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :02 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :04 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :06 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :07 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :09 PM EPA Interlab L07 1315 SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-597
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Mn SWA-L07-1315-T01-A 1 1.00E+00 U1/2
Mn SWA-L07-1315-T02-A 1 1.00E+00 U1/2
Mn SWA-L07-1315-T03-A 1 1.00E+00 U1/2
Mn SWA-L07-1315-T04-A 1 1.00E+00 U1/2
Mn SWA-L07-1315-T05-A 1 1.00E+00 U1/2
Mn SWA-L07-1315-T06-A 1 1.00E+00 U1/2
Mn SWA-L07-1315-T07-A 1 1.00E+00 U1/2
Mn SWA-L07-1315-T08-A 1 1.00E+00 U1/2
Mn SWA-L07-1315-T09-A 1 1.00E+00 U1/2
Mn SWA-L07-1315-T01-B 1 1.00E+00 U1/2
Mn SWA-L07-1315-T02-B 1 1.00E+00 U1/2
Mn SWA-L07-1315-T03-B 1 1.00E+00 U1/2
Mn SWA-L07-1315-T04-B 1 1.00E+00 U1/2
Mn SWA-L07-1315-T05-B 1 1.00E+00 U1/2
Mn SWA-L07-1315-T06-B 1 1.00E+00 U1/2
Mn SWA-L07-1315-T07-B 1 1.00E+00 U1/2
Mn SWA-L07-1315-T08-B 1 1.00E+00 U1/2
Mn SWA-L07-1315-T09-B 1 1.00E+00 U1/2
Mn SWA-L07-1315-T01-C 1 1.00E+00 U1/2
Mn SWA-L07-1315-T02-C 1 1.00E+00 U1/2
Mn SWA-L07-1315-T03-C 1 1.00E+00 U1/2
Mn SWA-L07-1315-T04-C 1 1.00E+00 U1/2
Mn SWA-L07-1315-T05-C 1 1.00E+00 U1/2
Mn SWA-L07-1315-T06-C 1 1.00E+00 U1/2
Mn SWA-L07-1315-T07-C 1 1.00E+00 U1/2
Mn SWA-L07-1315-T08-C 1 1.00E+00 U1/2
Mn SWA-L07-1315-T09-C 1 1.00E+00 U1/2
Mn SWA-L07-1315-M01-A 1 1.00E+00 U1/2
Mn SWA-L07-1315-M02-A 1 1.00E+00 U1/2
Mn SWA-L07-1315-M03-A 1 1.00E+00 U1/2
Mn SWA-L07-1315-M04-A 1 1.00E+00 U1/2
Mn SWA-L07-1315-M05-A 1 1.00E+00 U1/2
Mn SWA-L07-1315-M06-A 1 1.00E+00 U1/2
Mn SWA-L07-1315-M07-A 1 1.00E+00 U1/2
Mn SWA-L07-1315-M08-A 1 1.00E+00 U1/2
Mn SWA-L07-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 5.55 2.00 6.40
1.00E+00 6.86 2.00 6.40
1.00E+00 20.08 2.00 6.40 10000 1000
1.00E+00 30.94 2.00 6.40
1.00E+00 11.76 2.00 6.40
1.00E+00 20.25 2.00 6.40
1.00E+00 23.22 2.00 6.40
1.00E+00 9.86 2.00 6.40
1.00E+00 10.24 2.00 6.40
1.00E+00 14.49 2.00 6.40
1.00E+00 27.41 2.00 6.40
1.00E+00 23.81 2.00 6.40 10000 1000
1.00E+00 38.87 2.00 6.40
1.00E+00 16.95 2.00 6.40
1.00E+00 24.66 2.00 6.40
1.00E+00 8.30 2.00 6.40
1.00E+00 3.04 2.00 6.40
1.00E+00 6.70 2.00 6.40
1.00E+00 27.39 2.00 6.40
1.00E+00 44.87 2.00 6.40
1.00E+00 16.03 2.00 6.40 10000 1000
1.00E+00 39.65 2.00 6.40
1.00E+00 55.47 2.00 6.40
1.00E+00 8.38 2.00 6.40
1.00E+00 5.79 2.00 6.40
1.00E+00 9.36 2.00 6.40
1.00E+00 25.00 2.00 6.40
1.00E+00 1.21 2.00 6.40
1.00E+00 1.17 2.00 6.40
1.00E+00 35.20 2.00 6.40
1.00E+00 8.19 2.00 6.40
1.00E+00 26.15 2.00 6.40
1.00E+00 33.16 2.00 6.40
1.00E+00 37.43 2.00 6.40
1.00E+00 7.42 2.00 6.40
1.00E+00 118.74 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.53E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.13E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 1315 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315SWA
3/1/11 1:02 PM EPA Interlab L07 1315SWA
3/1/11 1:04 PM EPA Interlab L07 1315SWA
3/1/11 1:06 PM EPA Interlab L07 1315SWA
3/1/11 1:07 PM EPA Interlab L07 1315SWA
3/1/11 1:09 PM EPA Interlab L07 1315SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-598
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Mg SWA-L07-1315-T01-A 1 1.56E+00 E
Mg SWA-L07-1315-T02-A 1 3.04E+01
Mg SWA-L07-1315-T03-A 1 3.99E+01
Mg SWA-L07-1315-T04-A 1 2.00E+01
Mg SWA-L07-1315-T05-A 1 9.22E+00
Mg SWA-L07-1315-T06-A 1 1.16E+01
Mg SWA-L07-1315-T07-A 1 2.81E+01
Mg SWA-L07-1315-T08-A 1 6.36E+01
Mg SWA-L07-1315-T09-A 1 3.37E+01
Mg SWA-L07-1315-T01-B 1 1.62E+01
Mg SWA-L07-1315-T02-B 1 2.28E+01
Mg SWA-L07-1315-T03-B 1 3.05E+01
Mg SWA-L07-1315-T04-B 1 5.31E+00
Mg SWA-L07-1315-T05-B 1 2.44E+01
Mg SWA-L07-1315-T06-B 1 1.31E+01
Mg SWA-L07-1315-T07-B 1 1.55E+01
Mg SWA-L07-1315-T08-B 1 7.27E+01
Mg SWA-L07-1315-T09-B 1 4.26E+01
Mg SWA-L07-1315-T01-C 1 1.19E+01
Mg SWA-L07-1315-T02-C 1 1.71E+01
Mg SWA-L07-1315-T03-C 1 2.25E+01
Mg SWA-L07-1315-T04-C 1 1.70E+01
Mg SWA-L07-1315-T05-C 1 1.75E+01
Mg SWA-L07-1315-T06-C 1 7.32E+00
Mg SWA-L07-1315-T07-C 1 1.36E+01
Mg SWA-L07-1315-T08-C 1 6.64E+01
Mg SWA-L07-1315-T09-C 1 4.73E+01
Mg SWA-L07-1315-M01-A 1 1.04E+01
Mg SWA-L07-1315-M02-A 1 1.15E+01
Mg SWA-L07-1315-M03-A 1 4.57E+00
Mg SWA-L07-1315-M04-A 1 5.08E+00
Mg SWA-L07-1315-M05-A 1 1.26E+00 E
Mg SWA-L07-1315-M06-A 1 2.84E+00 E
Mg SWA-L07-1315-M07-A 1 2.15E+00 E
Mg SWA-L07-1315-M08-A 1 1.08E+00 E
Mg SWA-L07-1315-M09-A 1 2.57E+00 E
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.56E+00 25.53 1.00 3.18
3.04E+01 3.62 1.00 3.18
3.99E+01 10.42 1.00 3.18 10000 1000
2.00E+01 4.62 1.00 3.18
9.22E+00 3.76 1.00 3.18
1.16E+01 7.01 1.00 3.18
2.81E+01 6.26 1.00 3.18
6.36E+01 1.66 1.00 3.18
3.37E+01 1.95 1.00 3.18
1.62E+01 8.97 1.00 3.18
2.28E+01 1.90 1.00 3.18
3.05E+01 1.36 1.00 3.18 10000 1000
5.31E+00 7.38 1.00 3.18
2.44E+01 1.96 1.00 3.18
1.31E+01 5.42 1.00 3.18
1.55E+01 6.83 1.00 3.18
7.27E+01 1.65 1.00 3.18
4.26E+01 10.54 1.00 3.18
1.19E+01 5.99 1.00 3.18
1.71E+01 8.96 1.00 3.18
2.25E+01 2.22 1.00 3.18 10000 1000
1.70E+01 9.42 1.00 3.18
1.75E+01 5.44 1.00 3.18
7.32E+00 5.82 1.00 3.18
1.36E+01 6.44 1.00 3.18
6.64E+01 1.84 1.00 3.18
4.73E+01 1.42 1.00 3.18
1.04E+01 1.93 1.00 3.18
1.15E+01 2.23 1.00 3.18
4.57E+00 9.08 1.00 3.18
5.08E+00 6.66 1.00 3.18
1.26E+00 3.92 1.00 3.18
2.84E+00 9.63 1.00 3.18
2.15E+00 1.45 1.00 3.18
1.08E+00 7.79 1.00 3.18
2.57E+00 3.06 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.06E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.64E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.32E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 1315 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315SWA
3/1/11 1:02 PM EPA Interlab L07 1315SWA
3/1/11 1:04 PM EPA Interlab L07 1315SWA
3/1/11 1:06 PM EPA Interlab L07 1315SWA
3/1/11 1:07 PM EPA Interlab L07 1315SWA
3/1/11 1:09 PM EPA Interlab L07 1315SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315 SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-599
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L
Mo SWA-L07-1315-T01-A 1 5.44E+00
Mo SWA-L07-1315-T02-A 1 4.18E+00
Mo SWA-L07-1315-T03-A 1 3.06E+00 E
Mo SWA-L07-1315-T04-A 1 8.34E+00
Mo SWA-L07-1315-T05-A 1 5.08E+00
Mo SWA-L07-1315-T06-A 1 5.00E+00
Mo SWA-L07-1315-T07-A 1 4.59E+00
Mo SWA-L07-1315-T08-A 1 3.84E+00
Mo SWA-L07-1315-T09-A 1 4.31 E+00
Mo SWA-L07-1315-T01-B 1 3.59E+00 E
Mo SWA-L07-1315-T02-B 1 5.17E+00
Mo SWA-L07-1315-T03-B 1 2.26E+00 E
Mo SWA-L07-1315-T04-B 1 7.23E+00
Mo SWA-L07-1315-T05-B 1 4.83E+00
Mo SWA-L07-1315-T06-B 1 5.13E+00
Mo SWA-L07-1315-T07-B 1 4.82E+00
Mo SWA-L07-1315-T08-B 1 3.93E+00
Mo SWA-L07-1315-T09-B 1 4.80E+00
Mo SWA-L07-1315-T01-C 1 6.81E+00
Mo SWA-L07-1315-T02-C 1 7.72E+00
Mo SWA-L07-1315-T03-C 1 3.53E+00 E
Mo SWA-L07-1315-T04-C 1 6.58E+00
Mo SWA-L07-1315-T05-C 1 5.86E+00
Mo SWA-L07-1315-T06-C 1 5.88E+00
Mo SWA-L07-1315-T07-C 1 5.33E+00
Mo SWA-L07-1315-T08-C 1 4.51E+00
Mo SWA-L07-1315-T09-C 1 5.03E+00
Mo SWA-L07-1315-M01-A 1 6.00E-01 U1/2
Mo SWA-L07-1315-M02-A 1 6.00E-01 U1/2
Mo SWA-L07-1315-M03-A 1 6.00E-01 U1/2
Mo SWA-L07-1315-M04-A 1 6.00E-01 U1/2
Mo SWA-L07-1315-M05-A 1 6.00E-01 U1/2
Mo SWA-L07-1315-M06-A 1 6.00E-01 U1/2
Mo SWA-L07-1315-M07-A 1 6.00E-01 U1/2
Mo SWA-L07-1315-M08-A 1 6.00E-01 U1/2
Mo SWA-L07-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.44E+00 8.45 1.20 3.82
4.18E+00 9.24 1.20 3.82
3.06E+00 19.54 1.20 3.82 10000 1000
8.34E+00 2.89 1.20 3.82
5.08E+00 1.45 1.20 3.82
5.00E+00 2.53 1.20 3.82
4.59E+00 12.89 1.20 3.82
3.84E+00 32.61 1.20 3.82
4.31E+00 12.51 1.20 3.82
3.59E+00 21.52 1.20 3.82
5.17E+00 1.11 1.20 3.82
2.26E+00 18.19 1.20 3.82 10000 1000
7.23E+00 8.97 1.20 3.82
4.83E+00 2.45 1.20 3.82
5.13E+00 10.03 1.20 3.82
4.82E+00 2.26 1.20 3.82
3.93E+00 31.77 1.20 3.82
4.80E+00 5.38 1.20 3.82
6.81E+00 7.00 1.20 3.82
7.72E+00 1.14 1.20 3.82
3.53E+00 21.12 1.20 3.82 10000 1000
6.58E+00 14.61 1.20 3.82
5.86E+00 1.82 1.20 3.82
5.88E+00 2.23 1.20 3.82
5.33E+00 2.74 1.20 3.82
4.51E+00 5.95 1.20 3.82
5.03E+00 24.62 1.20 3.82
6.00E-01 28.79 1.20 3.82
6.00E-01 47.84 1.20 3.82
6.00E-01 24.25 1.20 3.82
6.00E-01 22.64 1.20 3.82
6.00E-01 3.99 1.20 3.82
6.00E-01 16.90 1.20 3.82
6.00E-01 39.24 1.20 3.82
6.00E-01 43.47 1.20 3.82
6.00E-01 26.65 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.31 E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.95E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 1315 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315SWA
3/1/11 1:02 PM EPA Interlab L07 1315SWA
3/1/11 1:04 PM EPA Interlab L07 1315SWA
3/1/11 1:06 PM EPA Interlab L07 1315SWA
3/1/11 1:07 PM EPA Interlab L07 1315SWA
3/1/11 1:09 PM EPA Interlab L07 1315SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-600
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ni SWA-L07-1315-T01-A 1 9.00E-01 U1/2
Ni SWA-L07-1315-T02-A 1 9.00E-01 U1/2
Ni SWA-L07-1315-T03-A 1 9.00E-01 U1/2
Ni SWA-L07-1315-T04-A 1 9.00E-01 U1/2
Ni SWA-L07-1315-T05-A 1 9.00E-01 U1/2
Ni SWA-L07-1315-T06-A 1 9.00E-01 U1/2
Ni SWA-L07-1315-T07-A 1 9.00E-01 U1/2
Ni SWA-L07-1315-T08-A 1 9.00E-01 U1/2
Ni SWA-L07-1315-T09-A 1 9.00E-01 U1/2
Ni SWA-L07-1315-T01-B 1 9.00E-01 U1/2
Ni SWA-L07-1315-T02-B 1 9.00E-01 U1/2
Ni SWA-L07-1315-T03-B 1 9.00E-01 U1/2
Ni SWA-L07-1315-T04-B 1 9.00E-01 U1/2
Ni SWA-L07-1315-T05-B 1 9.00E-01 U1/2
Ni SWA-L07-1315-T06-B 1 9.00E-01 U1/2
Ni SWA-L07-1315-T07-B 1 9.00E-01 U1/2
Ni SWA-L07-1315-T08-B 1 9.00E-01 U1/2
Ni SWA-L07-1315-T09-B 1 9.00E-01 U1/2
Ni SWA-L07-1315-T01-C 1 9.00E-01 U1/2
Ni SWA-L07-1315-T02-C 1 9.00E-01 U1/2
Ni SWA-L07-1315-T03-C 1 9.00E-01 U1/2
Ni SWA-L07-1315-T04-C 1 9.00E-01 U1/2
Ni SWA-L07-1315-T05-C 1 9.00E-01 U1/2
Ni SWA-L07-1315-T06-C 1 9.00E-01 U1/2
Ni SWA-L07-1315-T07-C 1 9.00E-01 U1/2
Ni SWA-L07-1315-T08-C 1 9.00E-01 U1/2
Ni SWA-L07-1315-T09-C 1 9.00E-01 U1/2
Ni SWA-L07-1315-M01-A 1 9.00E-01 U1/2
Ni SWA-L07-1315-M02-A 1 9.00E-01 U1/2
Ni SWA-L07-1315-M03-A 1 9.00E-01 U1/2
Ni SWA-L07-1315-M04-A 1 9.00E-01 U1/2
Ni SWA-L07-1315-M05-A 1 9.00E-01 U1/2
Ni SWA-L07-1315-M06-A 1 9.00E-01 U1/2
Ni SWA-L07-1315-M07-A 1 9.00E-01 U1/2
Ni SWA-L07-1315-M08-A 1 9.00E-01 U1/2
Ni SWA-L07-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 60.89 1.80 5.70
9.00E-01 24.95 1.80 5.70
9.00E-01 84.50 1.80 5.70 10000 1000
9.00E-01 22.94 1.80 5.70
9.00E-01 64.19 1.80 5.70
9.00E-01 71.98 1.80 5.70
9.00E-01 16.91 1.80 5.70
9.00E-01 69.00 1.80 5.70
9.00E-01 62.54 1.80 5.70
9.00E-01 15.53 1.80 5.70
9.00E-01 55.28 1.80 5.70
9.00E-01 18.63 1.80 5.70 10000 1000
9.00E-01 21.22 1.80 5.70
9.00E-01 46.85 1.80 5.70
9.00E-01 14.33 1.80 5.70
9.00E-01 11.96 1.80 5.70
9.00E-01 40.07 1.80 5.70
9.00E-01 17.00 1.80 5.70
9.00E-01 12.99 1.80 5.70
9.00E-01 41.36 1.80 5.70
9.00E-01 15.87 1.80 5.70 10000 1000
9.00E-01 30.56 1.80 5.70
9.00E-01 3.99 1.80 5.70
9.00E-01 29.64 1.80 5.70
9.00E-01 3.49 1.80 5.70
9.00E-01 52.90 1.80 5.70
9.00E-01 12.61 1.80 5.70
9.00E-01 18.54 1.80 5.70
9.00E-01 62.30 1.80 5.70
9.00E-01 13.33 1.80 5.70
9.00E-01 37.07 1.80 5.70
9.00E-01 13.38 1.80 5.70
9.00E-01 55.17 1.80 5.70
9.00E-01 62.72 1.80 5.70
9.00E-01 38.30 1.80 5.70
9.00E-01 22.48 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.03E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.45E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.18E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 1315 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :02 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :04 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :06 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :07 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :09 PM EPA Interlab L07 1315 SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-601
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
P SWA-L07-1315-T01-A 1 2.72E+01
P SWA-L07-1315-T02-A 1 8.85E+00 E
P SWA-L07-1315-T03-A 1 1.51E+01
P SWA-L07-1315-T04-A 1 9.22E+00 E
P SWA-L07-1315-T05-A 1 1.01E+01 E
P SWA-L07-1315-T06-A 1 1.67E+01
P SWA-L07-1315-T07-A 1 1.28E+01
P SWA-L07-1315-T08-A 1 1.85E+00 U1/2
P SWA-L07-1315-T09-A 1 2.00E+01
P SWA-L07-1315-T01-B 1 2.62E+01
P SWA-L07-1315-T02-B 1 2.25E+01
P SWA-L07-1315-T03-B 1 1.27E+01
P SWA-L07-1315-T04-B 1 7.61E+00 E
P SWA-L07-1315-T05-B 1 1.98E+01
P SWA-L07-1315-T06-B 1 1.48E+01
P SWA-L07-1315-T07-B 1 1.51E+01
P SWA-L07-1315-T08-B 1 5.01E+00 E
P SWA-L07-1315-T09-B 1 1.56E+01
P SWA-L07-1315-T01-C 1 1.86E+01
P SWA-L07-1315-T02-C 1 1.49E+01
P SWA-L07-1315-T03-C 1 1.86E+01
P SWA-L07-1315-T04-C 1 1.50E+01
P SWA-L07-1315-T05-C 1 7.74E+00 E
P SWA-L07-1315-T06-C 1 1.85E+00 U1/2
P SWA-L07-1315-T07-C 1 8.17E+00 E
P SWA-L07-1315-T08-C 1 1.25E+01
P SWA-L07-1315-T09-C 1 1.21E+01
P SWA-L07-1315-M01-A 1 1.85E+00 U1/2
P SWA-L07-1315-M02-A 1 1.85E+00 U1/2
P SWA-L07-1315-M03-A 1 1.85E+00 U1/2
P SWA-L07-1315-M04-A 1 1.85E+00 U1/2
P SWA-L07-1315-M05-A 1 1.85E+00 U1/2
P SWA-L07-1315-M06-A 1 1.85E+00 U1/2
P SWA-L07-1315-M07-A 1 1.85E+00 U1/2
P SWA-L07-1315-M08-A 1 1.85E+00 U1/2
P SWA-L07-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.72E+01 2.03 3.70 11.80
8.85E+00 10.05 3.70 11.80
1.51E+01 8.67 3.70 11.80 10000 1000
9.22E+00 11.99 3.70 11.80
1.01E+01 4.71 3.70 11.80
1.67E+01 7.04 3.70 11.80
1.28E+01 7.15 3.70 11.80
1.85E+00 20.42 3.70 11.80
2.00E+01 8.82 3.70 11.80
2.62E+01 13.37 3.70 11.80
2.25E+01 5.29 3.70 11.80
1.27E+01 6.27 3.70 11.80 10000 1000
7.61E+00 6.33 3.70 11.80
1.98E+01 5.54 3.70 11.80
1.48E+01 6.44 3.70 11.80
1.51E+01 8.82 3.70 11.80
5.01E+00 12.75 3.70 11.80
1.56E+01 6.30 3.70 11.80
1.86E+01 3.78 3.70 11.80
1.49E+01 3.61 3.70 11.80
1.86E+01 4.13 3.70 11.80 10000 1000
1.50E+01 8.93 3.70 11.80
7.74E+00 11.87 3.70 11.80
1.85E+00 27.21 3.70 11.80
8.17E+00 12.65 3.70 11.80
1.25E+01 13.41 3.70 11.80
1.21E+01 11.57 3.70 11.80
1.85E+00 5.89 3.70 11.80
1.85E+00 5.12 3.70 11.80
1.85E+00 21.35 3.70 11.80
1.85E+00 4.08 3.70 11.80
1.85E+00 5.05 3.70 11.80
1.85E+00 11.80 3.70 11.80
1.85E+00 48.03 3.70 11.80
1.85E+00 17.26 3.70 11.80
1.85E+00 24.75 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.07E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.83E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.53E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 131 5 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :02 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :04 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :06 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :07 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :09 PM EPA Interlab L07 1315 SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 131 5 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 131 5 SWA
3/1/11 12:11 PM EPA Interlab L07 1315 SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-602
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
K SWA-L07-1315-T01-A 1 1.36E+04
K SWA-L07-1315-T02-A 1 2.52E+04
K SWA-L07-1315-T03-A 1 1.32E+04
K SWA-L07-1315-T04-A 1 3.75E+04
K SWA-L07-1315-T05-A 1 2.68E+04
K SWA-L07-1315-T06-A 1 3.19E+04
K SWA-L07-1315-T07-A 1 2.19E+04
K SWA-L07-1315-T08-A 1 8.68E+03
K SWA-L07-1315-T09-A 1 1.34E+04
K SWA-L07-1315-T01-B 1 1.30E+04
K SWA-L07-1315-T02-B 1 2.40E+04
K SWA-L07-1315-T03-B 1 1.26E+04
K SWA-L07-1315-T04-B 1 3.50E+04
K SWA-L07-1315-T05-B 1 2.57E+04
K SWA-L07-1315-T06-B 1 3.06E+04
K SWA-L07-1315-T07-B 1 2.10E+04
K SWA-L07-1315-T08-B 1 8.32E+03
K SWA-L07-1315-T09-B 1 1.31E+04
K SWA-L07-1315-T01-C 1 1.39E+04
K SWA-L07-1315-T02-C 1 2.51E+04
K SWA-L07-1315-T03-C 1 1.27E+04
K SWA-L07-1315-T04-C 1 3.50E+04
K SWA-L07-1315-T05-C 1 2.44E+04
K SWA-L07-1315-T06-C 1 3.08E+04
K SWA-L07-1315-T07-C 1 2.11E+04
K SWA-L07-1315-T08-C 1 8.82E+03
K SWA-L07-1315-T09-C 1 1.34E+04
K SWA-L07-1315-M01-A 1 1.43E+01
K SWA-L07-1315-M02-A 1 1.13E+01
K SWA-L07-1315-M03-A 1 2.27E+00 E
K SWA-L07-1315-M04-A 1 2.50E+00 E
K SWA-L07-1315-M05-A 1 3.45E+00 E
K SWA-L07-1315-M06-A 1 5.28E+00
K SWA-L07-1315-M07-A 1 4.84E+00 E
K SWA-L07-1315-M08-A 1 5.57E+00
K SWA-L07-1315-M09-A 1 8.03E+00
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.36E+04 0.52 1.60 5.09
2.52E+04 0.73 1.60 5.09
1.32E+04 0.29 1.60 5.09 10000 1000
3.75E+04 0.36 1.60 5.09
2.68E+04 0.76 1.60 5.09
3.19E+04 0.56 1.60 5.09
2.19E+04 1.08 1.60 5.09
8.68E+03 0.80 1.60 5.09
1.34E+04 0.70 1.60 5.09
1.30E+04 0.81 1.60 5.09
2.40E+04 0.60 1.60 5.09
1.26E+04 0.38 1.60 5.09 10000 1000
3.50E+04 0.65 1.60 5.09
2.57E+04 0.64 1.60 5.09
3.06E+04 1.39 1.60 5.09
2.10E+04 0.77 1.60 5.09
8.32E+03 0.38 1.60 5.09
1.31E+04 0.67 1.60 5.09
1.39E+04 1.13 1.60 5.09
2.51E+04 0.29 1.60 5.09
1.27E+04 0.04 1.60 5.09 10000 1000
3.50E+04 0.57 1.60 5.09
2.44E+04 1.19 1.60 5.09
3.08E+04 1.14 1.60 5.09
2.11E+04 1.69 1.60 5.09
8.82E+03 0.24 1.60 5.09
1.34E+04 0.59 1.60 5.09
1.43E+01 5.10 1.60 5.09
1.13E+01 7.62 1.60 5.09
2.27E+00 2.00 1.60 5.09
2.50E+00 1.27 1.60 5.09
3.45E+00 2.33 1.60 5.09
5.28E+00 2.02 1.60 5.09
4.84E+00 1.32 1.60 5.09
5.57E+00 1.74 1.60 5.09
8.03E+00 9.79 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.41E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.36E+04 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.36E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 1315 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315SWA
3/1/11 1:02 PM EPA Interlab L07 1315SWA
3/1/11 1:04 PM EPA Interlab L07 1315SWA
3/1/11 1:06 PM EPA Interlab L07 1315SWA
3/1/11 1:07 PM EPA Interlab L07 1315SWA
3/1/11 1:09 PM EPA Interlab L07 1315SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315 SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-603
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Se SWA-L07-1315-T01-A 1 2.80E+03
Se SWA-L07-1315-T02-A 1 3.51E+03
Se SWA-L07-1315-T03-A 1 1.64E+03
Se SWA-L07-1315-T04-A 1 4.54E+03
Se SWA-L07-1315-T05-A 1 2.79E+03
Se SWA-L07-1315-T06-A 1 3.02E+03
Se SWA-L07-1315-T07-A 1 1.80E+03
Se SWA-L07-1315-T08-A 1 5.65E+02
Se SWA-L07-1315-T09-A 1 1.00E+03
Se SWA-L07-1315-T01-B 1 2.76E+03
Se SWA-L07-1315-T02-B 1 3.33E+03
Se SWA-L07-1315-T03-B 1 1.57E+03
Se SWA-L07-1315-T04-B 1 4.26E+03
Se SWA-L07-1315-T05-B 1 2.73E+03
Se SWA-L07-1315-T06-B 1 2.94E+03
Se SWA-L07-1315-T07-B 1 1.70E+03
Se SWA-L07-1315-T08-B 1 5.70E+02
Se SWA-L07-1315-T09-B 1 9.91E+02
Se SWA-L07-1315-T01-C 1 2.83E+03
Se SWA-L07-1315-T02-C 1 3.38E+03
Se SWA-L07-1315-T03-C 1 1.49E+03
Se SWA-L07-1315-T04-C 1 3.99E+03
Se SWA-L07-1315-T05-C 1 2.34E+03
Se SWA-L07-1315-T06-C 1 2.77E+03
Se SWA-L07-1315-T07-C 1 1.57E+03
Se SWA-L07-1315-T08-C 1 5.34E+02
Se SWA-L07-1315-T09-C 1 9.37E+02
Se SWA-L07-1315-M01-A 1 7.50E+00 U1/2
Se SWA-L07-1315-M02-A 1 7.50E+00 U1/2
Se SWA-L07-1315-M03-A 1 7.50E+00 U1/2
Se SWA-L07-1315-M04-A 1 7.50E+00 U1/2
Se SWA-L07-1315-M05-A 1 7.50E+00 U1/2
Se SWA-L07-1315-M06-A 1 7.50E+00 U1/2
Se SWA-L07-1315-M07-A 1 7.50E+00 U1/2
Se SWA-L07-1315-M08-A 1 7.50E+00 U1/2
Se SWA-L07-1315-M09-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.80E+03 0.74 15.00 47.70
3.51E+03 0.97 15.00 47.70
1.64E+03 0.45 15.00 47.70 10000 1000
4.54E+03 0.39 15.00 47.70
2.79E+03 1.45 15.00 47.70
3.02E+03 0.64 15.00 47.70
1.80E+03 0.46 15.00 47.70
5.65E+02 2.64 15.00 47.70
1.00E+03 0.78 15.00 47.70
2.76E+03 0.91 15.00 47.70
3.33E+03 1.55 15.00 47.70
1.57E+03 0.47 15.00 47.70 10000 1000
4.26E+03 0.55 15.00 47.70
2.73E+03 1.46 15.00 47.70
2.94E+03 0.48 15.00 47.70
1.70E+03 0.73 15.00 47.70
5.70E+02 1.85 15.00 47.70
9.91E+02 0.93 15.00 47.70
2.83E+03 1.80 15.00 47.70
3.38E+03 1.02 15.00 47.70
1.49E+03 1.98 15.00 47.70 10000 1000
3.99E+03 0.95 15.00 47.70
2.34E+03 0.97 15.00 47.70
2.77E+03 0.16 15.00 47.70
1.57E+03 1.59 15.00 47.70
5.34E+02 1.29 15.00 47.70
9.37E+02 2.63 15.00 47.70
7.50E+00 36.93 15.00 47.70
7.50E+00 24.62 15.00 47.70
7.50E+00 23.16 15.00 47.70
7.50E+00 29.07 15.00 47.70
7.50E+00 19.78 15.00 47.70
7.50E+00 9.92 15.00 47.70
7.50E+00 34.96 15.00 47.70
7.50E+00 39.89 15.00 47.70
7.50E+00 19.72 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.60E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.58E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.47E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 1315 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315SWA
3/1/11 1:02 PM EPA Interlab L07 1315SWA
3/1/11 1:04 PM EPA Interlab L07 1315SWA
3/1/11 1:06 PM EPA Interlab L07 1315SWA
3/1/11 1:07 PM EPA Interlab L07 1315SWA
3/1/11 1:09 PM EPA Interlab L07 1315SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-604
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Si SWA-L07-1315-T01-A 1 1.41E+03
Si SWA-L07-1315-T02-A 1 4.11E+03
Si SWA-L07-1315-T03-A 1 3.16E+03
Si SWA-L07-1315-T04-A 1 7.52E+03
Si SWA-L07-1315-T05-A 1 7.04E+03
Si SWA-L07-1315-T06-A 1 8.16E+03
Si SWA-L07-1315-T07-A 1 7.65E+03
Si SWA-L07-1315-T08-A 1 5.53E+03
Si SWA-L07-1315-T09-A 1 7.38E+03
Si SWA-L07-1315-T01-B 1 1.24E+03
Si SWA-L07-1315-T02-B 1 3.73E+03
Si SWA-L07-1315-T03-B 1 2.88E+03
Si SWA-L07-1315-T04-B 1 7.04E+03
Si SWA-L07-1315-T05-B 1 6.70E+03
Si SWA-L07-1315-T06-B 1 7.79E+03
Si SWA-L07-1315-T07-B 1 7.26E+03
Si SWA-L07-1315-T08-B 1 5.32E+03
Si SWA-L07-1315-T09-B 1 7.13E+03
Si SWA-L07-1315-T01-C 1 1.31E+03
Si SWA-L07-1315-T02-C 1 3.76E+03
Si SWA-L07-1315-T03-C 1 2.95E+03
Si SWA-L07-1315-T04-C 1 7.04E+03
Si SWA-L07-1315-T05-C 1 6.82E+03
Si SWA-L07-1315-T06-C 1 7.92E+03
Si SWA-L07-1315-T07-C 1 7.74E+03
Si SWA-L07-1315-T08-C 1 5.58E+03
Si SWA-L07-1315-T09-C 1 7.92E+03
Si SWA-L07-1315-M01-A 1 5.50E-01 U1/2
Si SWA-L07-1315-M02-A 1 5.50E-01 U1/2
Si SWA-L07-1315-M03-A 1 5.50E-01 U1/2
Si SWA-L07-1315-M04-A 1 5.50E-01 U1/2
Si SWA-L07-1315-M05-A 1 5.50E-01 U1/2
Si SWA-L07-1315-M06-A 1 5.50E-01 U1/2
Si SWA-L07-1315-M07-A 1 5.50E-01 U1/2
Si SWA-L07-1315-M08-A 1 5.50E-01 U1/2
Si SWA-L07-1315-M09-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.41E+03 0.35 1.10 3.50
4.11E+03 0.86 1.10 3.50
3.16E+03 0.83 1.10 3.50 10000 1000
7.52E+03 1.14 1.10 3.50
7.04E+03 0.25 1.10 3.50
8.16E+03 0.89 1.10 3.50
7.65E+03 0.42 1.10 3.50
5.53E+03 0.54 1.10 3.50
7.38E+03 0.95 1.10 3.50
1.24E+03 1.36 1.10 3.50
3.73E+03 0.41 1.10 3.50
2.88E+03 0.31 1.10 3.50 10000 1000
7.04E+03 0.34 1.10 3.50
6.70E+03 0.44 1.10 3.50
7.79E+03 1.92 1.10 3.50
7.26E+03 1.05 1.10 3.50
5.32E+03 0.46 1.10 3.50
7.13E+03 0.69 1.10 3.50
1.31E+03 0.80 1.10 3.50
3.76E+03 1.16 1.10 3.50
2.95E+03 0.46 1.10 3.50 10000 1000
7.04E+03 0.34 1.10 3.50
6.82E+03 5.00 1.10 3.50
7.92E+03 0.79 1.10 3.50
7.74E+03 0.86 1.10 3.50
5.58E+03 0.66 1.10 3.50
7.92E+03 1.46 1.10 3.50
5.50E-01 1.56 1.10 3.50
5.50E-01 8.98 1.10 3.50
5.50E-01 51.33 1.10 3.50
5.50E-01 20.95 1.10 3.50
5.50E-01 81.70 1.10 3.50
5.50E-01 30.84 1.10 3.50
5.50E-01 33.60 1.10 3.50
5.50E-01 12.64 1.10 3.50
5.50E-01 35.43 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.20E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.86E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.89E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 1315 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :02 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :04 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :06 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :07 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :09 PM EPA Interlab L07 1315 SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-605
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Na SWA-L07-1315-T01-A 1 5.58E+04
Na SWA-L07-1315-T02-A 1 8.29E+04
Na SWA-L07-1315-T03-A 1 5.28E+04
Na SWA-L07-1315-T04-A 1 1.14E+05
Na SWA-L07-1315-T05-A 1 9.05E+04
Na SWA-L07-1315-T06-A 1 1.05E+05
Na SWA-L07-1315-T07-A 1 8.00E+04
Na SWA-L07-1315-T08-A 1 3.85E+04
Na SWA-L07-1315-T09-A 1 5.85E+04
Na SWA-L07-1315-T01-B 1 5.31E+04
Na SWA-L07-1315-T02-B 1 8.14E+04
Na SWA-L07-1315-T03-B 1 4.96E+04
Na SWA-L07-1315-T04-B 1 1.08E+05
Na SWA-L07-1315-T05-B 1 8.74E+04
Na SWA-L07-1315-T06-B 1 1.01E+05
Na SWA-L07-1315-T07-B 1 7.64E+04
Na SWA-L07-1315-T08-B 1 3.64E+04
Na SWA-L07-1315-T09-B 1 5.58E+04
Na SWA-L07-1315-T01-C 1 5.50E+04
Na SWA-L07-1315-T02-C 1 8.32E+04
Na SWA-L07-1315-T03-C 1 4.97E+04
Na SWA-L07-1315-T04-C 1 1.07E+05
Na SWA-L07-1315-T05-C 1 8.16E+04
Na SWA-L07-1315-T06-C 1 9.94E+04
Na SWA-L07-1315-T07-C 1 7.62E+04
Na SWA-L07-1315-T08-C 1 3.72E+04
Na SWA-L07-1315-T09-C 1 5.64E+04
Na SWA-L07-1315-M01-A 1 2.90E+01
Na SWA-L07-1315-M02-A 1 2.50E+01
Na SWA-L07-1315-M03-A 1 1.96E+01
Na SWA-L07-1315-M04-A 1 1.59E+01
Na SWA-L07-1315-M05-A 1 1.43E+01
Na SWA-L07-1315-M06-A 1 1.10E+01
Na SWA-L07-1315-M07-A 1 7.60E+00 E
Na SWA-L07-1315-M08-A 1 1.19E+01
Na SWA-L07-1315-M09-A 1 1.68E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.58E+04 0.05 2.50 8.00
8.29E+04 0.62 2.50 8.00
5.28E+04 0.23 2.50 8.00 10000 1000
1.14E+05 0.66 2.50 8.00
9.05E+04 1.03 2.50 8.00
1.05E+05 0.59 2.50 8.00
8.00E+04 0.33 2.50 8.00
3.85E+04 0.30 2.50 8.00
5.85E+04 0.47 2.50 8.00
5.31E+04 0.11 2.50 8.00
8.14E+04 1.03 2.50 8.00
4.96E+04 0.68 2.50 8.00 10000 1000
1.08E+05 0.65 2.50 8.00
8.74E+04 0.12 2.50 8.00
1.01E+05 0.08 2.50 8.00
7.64E+04 0.28 2.50 8.00
3.64E+04 0.72 2.50 8.00
5.58E+04 0.20 2.50 8.00
5.50E+04 0.58 2.50 8.00
8.32E+04 0.76 2.50 8.00
4.97E+04 0.63 2.50 8.00 10000 1000
1.07E+05 0.93 2.50 8.00
8.16E+04 1.22 2.50 8.00
9.94E+04 0.15 2.50 8.00
7.62E+04 0.95 2.50 8.00
3.72E+04 0.83 2.50 8.00
5.64E+04 1.09 2.50 8.00
2.90E+01 2.66 2.50 8.00
2.50E+01 1.21 2.50 8.00
1.96E+01 11.45 2.50 8.00
1.59E+01 32.18 2.50 8.00
1.43E+01 27.43 2.50 8.00
1.10E+01 44.92 2.50 8.00
7.60E+00 3.18 2.50 8.00
1.19E+01 28.33 2.50 8.00
1.68E+01 2.99 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.38E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.05E+04 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.05E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 1315 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :02 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :04 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :06 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :07 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :09 PM EPA Interlab L07 1315 SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-606
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Sr SWA-L07-1315-T01-A 1 2.09E+01
Sr SWA-L07-1315-T02-A 1 1.63E+02
Sr SWA-L07-1315-T03-A 1 1.28E+02
Sr SWA-L07-1315-T04-A 1 2.29E+02
Sr SWA-L07-1315-T05-A 1 2.31 E+02
Sr SWA-L07-1315-T06-A 1 2.59E+02
Sr SWA-L07-1315-T07-A 1 2. 41 E+02
Sr SWA-L07-1315-T08-A 1 1.96E+02
Sr SWA-L07-1315-T09-A 1 1.87E+02
Sr SWA-L07-1315-T01-B 1 1.89E+01
Sr SWA-L07-1315-T02-B 1 1.43E+02
Sr SWA-L07-1315-T03-B 1 1.22E+02
Sr SWA-L07-1315-T04-B 1 2.26E+02
Sr SWA-L07-1315-T05-B 1 2.31E+02
Sr SWA-L07-1315-T06-B 1 2.57E+02
Sr SWA-L07-1315-T07-B 1 2.28E+02
Sr SWA-L07-1315-T08-B 1 2.00E+02
Sr SWA-L07-1315-T09-B 1 1.90E+02
Sr SWA-L07-1315-T01-C 1 2.05E+01
Sr SWA-L07-1315-T02-C 1 1.54E+02
Sr SWA-L07-1315-T03-C 1 1.32E+02
Sr SWA-L07-1315-T04-C 1 2.37E+02
Sr SWA-L07-1315-T05-C 1 2.27E+02
Sr SWA-L07-1315-T06-C 1 2.66E+02
Sr SWA-L07-1315-T07-C 1 1.90E+02
Sr SWA-L07-1315-T08-C 1 2.18E+02
Sr SWA-L07-1315-T09-C 1 1.44E+02
Sr SWA-L07-1315-M01-A 1 5.00E-01 U1/2
Sr SWA-L07-1315-M02-A 1 5.00E-01 U1/2
Sr SWA-L07-1315-M03-A 1 5.00E-01 U1/2
Sr SWA-L07-1315-M04-A 1 5.00E-01 U1/2
Sr SWA-L07-1315-M05-A 1 5.00E-01 U1/2
Sr SWA-L07-1315-M06-A 1 5.00E-01 U1/2
Sr SWA-L07-1315-M07-A 1 5.00E-01 U1/2
Sr SWA-L07-1315-M08-A 1 5.00E-01 U1/2
Sr SWA-L07-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.09E+01 1.01 1.00 3.18
1.63E+02 0.84 1.00 3.18
1.28E+02 0.59 1.00 3.18 10000 1000
2.29E+02 0.72 1.00 3.18
2.31E+02 0.07 1.00 3.18
2.59E+02 0.14 1.00 3.18
2.41E+02 0.78 1.00 3.18
1.96E+02 1.08 1.00 3.18
1.87E+02 1.53 1.00 3.18
1.89E+01 5.85 1.00 3.18
1.43E+02 0.99 1.00 3.18
1.22E+02 1.16 1.00 3.18 10000 1000
2.26E+02 0.05 1.00 3.18
2.31E+02 0.45 1.00 3.18
2.57E+02 0.96 1.00 3.18
2.28E+02 0.61 1.00 3.18
2.00E+02 1.08 1.00 3.18
1.90E+02 0.27 1.00 3.18
2.05E+01 3.19 1.00 3.18
1.54E+02 0.21 1.00 3.18
1.32E+02 0.94 1.00 3.18 10000 1000
2.37E+02 0.55 1.00 3.18
2.27E+02 1.54 1.00 3.18
2.66E+02 0.45 1.00 3.18
1.90E+02 1.06 1.00 3.18
2.18E+02 0.49 1.00 3.18
1.44E+02 0.56 1.00 3.18
5.00E-01 36.77 1.00 3.18
5.00E-01 6.91 1.00 3.18
5.00E-01 17.57 1.00 3.18
5.00E-01 11.53 1.00 3.18
5.00E-01 16.90 1.00 3.18
5.00E-01 24.35 1.00 3.18
5.00E-01 28.76 1.00 3.18
5.00E-01 38.06 1.00 3.18
5.00E-01 18.39 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 . 1 9E+03 1 06% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 1315 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315SWA
3/1/11 1:02 PM EPA Interlab L07 1315SWA
3/1/11 1:04 PM EPA Interlab L07 1315SWA
3/1/11 1:06 PM EPA Interlab L07 1315SWA
3/1/11 1:07 PM EPA Interlab L07 1315SWA
3/1/11 1:09 PM EPA Interlab L07 1315SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-607
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
S SWA-L07-1315-T01-A 1 1.13E+04
S SWA-L07-1315-T02-A 1 1.51E+04
S SWA-L07-1315-T03-A 1 6.89E+03
S SWA-L07-1315-T04-A 1 2.22E+04
S SWA-L07-1315-T05-A 1 1.42E+04
S SWA-L07-1315-T06-A 1 1.77E+04
S SWA-L07-1315-T07-A 1 9.67E+03
S SWA-L07-1315-T08-A 1 2.53E+03
S SWA-L07-1315-T09-A 1 5.10E+03
S SWA-L07-1315-T01-B 1 1.16E+04
S SWA-L07-1315-T02-B 1 1.50E+04
S SWA-L07-1315-T03-B 1 6.50E+03
S SWA-L07-1315-T04-B 1 2.18E+04
S SWA-L07-1315-T05-B 1 1.38E+04
S SWA-L07-1315-T06-B 1 1.82E+04
S SWA-L07-1315-T07-B 1 1.04E+04
S SWA-L07-1315-T08-B 1 2.51E+03
S SWA-L07-1315-T09-B 1 5.16E+03
S SWA-L07-1315-T01-C 1 1.14E+04
S SWA-L07-1315-T02-C 1 1.55E+04
S SWA-L07-1315-T03-C 1 6.30E+03
S SWA-L07-1315-T04-C 1 1.96E+04
S SWA-L07-1315-T05-C 1 1.19E+04
S SWA-L07-1315-T06-C 1 1.51E+04
S SWA-L07-1315-T07-C 1 8.13E+03
S SWA-L07-1315-T08-C 1 2.43E+03
S SWA-L07-1315-T09-C 1 4.58E+03
S SWA-L07-1315-M01-A 1 3.40E+00 U1/2
S SWA-L07-1315-M02-A 1 3.40E+00 U1/2
S SWA-L07-1315-M03-A 1 3.40E+00 U1/2
S SWA-L07-1315-M04-A 1 3.40E+00 U1/2
S SWA-L07-1315-M05-A 1 3.40E+00 U1/2
S SWA-L07-1315-M06-A 1 3.40E+00 U1/2
S SWA-L07-1315-M07-A 1 3.40E+00 U1/2
S SWA-L07-1315-M08-A 1 3.40E+00 U1/2
S SWA-L07-1315-M09-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.13E+04 1.09 6.80 21.60
1.51E+04 0.14 6.80 21.60
6.89E+03 1.16 6.80 21.60 10000 1000
2.22E+04 1.26 6.80 21.60
1.42E+04 0.92 6.80 21.60
1.77E+04 0.30 6.80 21.60
9.67E+03 1.94 6.80 21.60
2.53E+03 0.49 6.80 21.60
5.10E+03 0.84 6.80 21.60
1.16E+04 0.69 6.80 21.60
1.50E+04 0.61 6.80 21.60
6.50E+03 0.58 6.80 21.60 10000 1000
2.18E+04 0.95 6.80 21.60
1.38E+04 0.38 6.80 21.60
1.82E+04 0.99 6.80 21.60
1.04E+04 0.37 6.80 21.60
2.51E+03 2.54 6.80 21.60
5.16E+03 1.11 6.80 21.60
1.14E+04 1.03 6.80 21.60
1.55E+04 0.80 6.80 21.60
6.30E+03 1.14 6.80 21.60 10000 1000
1.96E+04 0.80 6.80 21.60
1.19E+04 1.38 6.80 21.60
1.51E+04 0.96 6.80 21.60
8.13E+03 0.99 6.80 21.60
2.43E+03 1.26 6.80 21.60
4.58E+03 0.53 6.80 21.60
3.40E+00 12.87 6.80 21.60
3.40E+00 16.44 6.80 21.60
3.40E+00 6.93 6.80 21.60
3.40E+00 10.76 6.80 21.60
3.40E+00 14.60 6.80 21.60
3.40E+00 10.17 6.80 21.60
3.40E+00 11.94 6.80 21.60
3.40E+00 9.57 6.80 21.60
3.40E+00 13.24 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
7.80E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.45E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.16E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 1315 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315SWA
3/1/11 1:02 PM EPA Interlab L07 1315SWA
3/1/11 1:04 PM EPA Interlab L07 1315SWA
3/1/11 1:06 PM EPA Interlab L07 1315SWA
3/1/11 1:07 PM EPA Interlab L07 1315SWA
3/1/11 1:09 PM EPA Interlab L07 1315SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-608
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Tl SWA-L07-1315-T01-A 1 2.30E+00 U1/2
Tl SWA-L07-1315-T02-A 1 2.30E+00 U1/2
Tl SWA-L07-1315-T03-A 1 2.30E+00 U1/2
Tl SWA-L07-1315-T04-A 1 2.30E+00 U1/2
Tl SWA-L07-1315-T05-A 1 2.30E+00 U1/2
Tl SWA-L07-1315-T06-A 1 2.30E+00 U1/2
Tl SWA-L07-1315-T07-A 1 2.30E+00 U1/2
Tl SWA-L07-1315-T08-A 1 2.30E+00 U1/2
Tl SWA-L07-1315-T09-A 1 2.30E+00 U1/2
Tl SWA-L07-1315-T01-B 1 2.30E+00 U1/2
Tl SWA-L07-1315-T02-B 1 2.30E+00 U1/2
Tl SWA-L07-1315-T03-B 1 2.30E+00 U1/2
Tl SWA-L07-1315-T04-B 1 2.30E+00 U1/2
Tl SWA-L07-1315-T05-B 1 2.30E+00 U1/2
Tl SWA-L07-1315-T06-B 1 2.30E+00 U1/2
Tl SWA-L07-1315-T07-B 1 2.30E+00 U1/2
Tl SWA-L07-1315-T08-B 1 2.30E+00 U1/2
Tl SWA-L07-1315-T09-B 1 2.30E+00 U1/2
Tl SWA-L07-1315-T01-C 1 2.30E+00 U1/2
Tl SWA-L07-1315-T02-C 1 2.30E+00 U1/2
Tl SWA-L07-1315-T03-C 1 2.30E+00 U1/2
Tl SWA-L07-1315-T04-C 1 2.30E+00 U1/2
Tl SWA-L07-1315-T05-C 1 2.30E+00 U1/2
Tl SWA-L07-1315-T06-C 1 2.30E+00 U1/2
Tl SWA-L07-1315-T07-C 1 2.30E+00 U1/2
Tl SWA-L07-1315-T08-C 1 2.30E+00 U1/2
Tl SWA-L07-1315-T09-C 1 2.30E+00 U1/2
Tl SWA-L07-1315-M01-A 1 2.30E+00 U1/2
Tl SWA-L07-1315-M02-A 1 2.30E+00 U1/2
Tl SWA-L07-1315-M03-A 1 2.30E+00 U1/2
Tl SWA-L07-1315-M04-A 1 2.30E+00 U1/2
Tl SWA-L07-1315-M05-A 1 2.30E+00 U1/2
Tl SWA-L07-1315-M06-A 1 2.30E+00 U1/2
Tl SWA-L07-1315-M07-A 1 2.30E+00 U1/2
Tl SWA-L07-1315-M08-A 1 2.30E+00 U1/2
Tl SWA-L07-1315-M09-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 62.87 4.60 14.60
2.30E+00 53.72 4.60 14.60
2.30E+00 39.88 4.60 14.60 10000 1000
2.30E+00 43.73 4.60 14.60
2.30E+00 19.40 4.60 14.60
2.30E+00 29.32 4.60 14.60
2.30E+00 12.81 4.60 14.60
2.30E+00 54.27 4.60 14.60
2.30E+00 83.13 4.60 14.60
2.30E+00 15.89 4.60 14.60
2.30E+00 33.23 4.60 14.60
2.30E+00 27.30 4.60 14.60 10000 1000
2.30E+00 15.73 4.60 14.60
2.30E+00 65.41 4.60 14.60
2.30E+00 10.58 4.60 14.60
2.30E+00 98.08 4.60 14.60
2.30E+00 49.45 4.60 14.60
2.30E+00 36.17 4.60 14.60
2.30E+00 23.19 4.60 14.60
2.30E+00 77.93 4.60 14.60
2.30E+00 14.88 4.60 14.60 10000 1000
2.30E+00 11.90 4.60 14.60
2.30E+00 70.46 4.60 14.60
2.30E+00 31.43 4.60 14.60
2.30E+00 59.26 4.60 14.60
2.30E+00 39.96 4.60 14.60
2.30E+00 17.57 4.60 14.60
2.30E+00 16.71 4.60 14.60
2.30E+00 38.84 4.60 14.60
2.30E+00 84.03 4.60 14.60
2.30E+00 10.15 4.60 14.60
2.30E+00 43.19 4.60 14.60
2.30E+00 93.82 4.60 14.60
2.30E+00 12.16 4.60 14.60
2.30E+00 85.80 4.60 14.60
2.30E+00 14.53 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.38E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.13E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 131 5 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315SWA
3/1/11 1:02 PM EPA Interlab L07 1315SWA
3/1/11 1:04 PM EPA Interlab L07 1315SWA
3/1/11 1:06 PM EPA Interlab L07 1315SWA
3/1/11 1:07 PM EPA Interlab L07 1315SWA
3/1/11 1:09 PM EPA Interlab L07 1315SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-609
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Ti SWA-L07-1315-T01-A 1 1.00E+00 U1/2
Ti SWA-L07-1315-T02-A 1 1.00E+00 U1/2
Ti SWA-L07-1315-T03-A 1 1.00E+00 U1/2
Ti SWA-L07-1315-T04-A 1 1.00E+00 U1/2
Ti SWA-L07-1315-T05-A 1 1.00E+00 U1/2
Ti SWA-L07-1315-T06-A 1 1.00E+00 U1/2
Ti SWA-L07-1315-T07-A 1 1.00E+00 U1/2
Ti SWA-L07-1315-T08-A 1 1.00E+00 U1/2
Ti SWA-L07-1315-T09-A 1 1.00E+00 U1/2
Ti SWA-L07-1315-T01-B 1 1.00E+00 U1/2
Ti SWA-L07-1315-T02-B 1 1.00E+00 U1/2
Ti SWA-L07-1315-T03-B 1 1.00E+00 U1/2
Ti SWA-L07-1315-T04-B 1 1.00E+00 U1/2
Ti SWA-L07-1315-T05-B 1 1.00E+00 U1/2
Ti SWA-L07-1315-T06-B 1 1.00E+00 U1/2
Ti SWA-L07-1315-T07-B 1 1.00E+00 U1/2
Ti SWA-L07-1315-T08-B 1 1.00E+00 U1/2
Ti SWA-L07-1315-T09-B 1 1.00E+00 U1/2
Ti SWA-L07-1315-T01-C 1 1.00E+00 U1/2
Ti SWA-L07-1315-T02-C 1 1.00E+00 U1/2
Ti SWA-L07-1315-T03-C 1 1.00E+00 U1/2
Ti SWA-L07-1315-T04-C 1 1.00E+00 U1/2
Ti SWA-L07-1315-T05-C 1 1.00E+00 U1/2
Ti SWA-L07-1315-T06-C 1 1.00E+00 U1/2
Ti SWA-L07-1315-T07-C 1 1.00E+00 U1/2
Ti SWA-L07-1315-T08-C 1 1.00E+00 U1/2
Ti SWA-L07-1315-T09-C 1 1.00E+00 U1/2
Ti SWA-L07-1315-M01-A 1 1.00E+00 U1/2
Ti SWA-L07-1315-M02-A 1 1.00E+00 U1/2
Ti SWA-L07-1315-M03-A 1 1.00E+00 U1/2
Ti SWA-L07-1315-M04-A 1 1.00E+00 U1/2
Ti SWA-L07-1315-M05-A 1 1.00E+00 U1/2
Ti SWA-L07-1315-M06-A 1 1.00E+00 U1/2
Ti SWA-L07-1315-M07-A 1 1.00E+00 U1/2
Ti SWA-L07-1315-M08-A 1 1.00E+00 U1/2
Ti SWA-L07-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 47.88 2.00 6.40
1.00E+00 16.21 2.00 6.40
1.00E+00 90.03 2.00 6.40 10000 1000
1.00E+00 85.26 2.00 6.40
1.00E+00 11.68 2.00 6.40
1.00E+00 40.55 2.00 6.40
1.00E+00 22.30 2.00 6.40
1.00E+00 22.34 2.00 6.40
1.00E+00 52.60 2.00 6.40
1.00E+00 64.44 2.00 6.40
1.00E+00 56.63 2.00 6.40
1.00E+00 14.59 2.00 6.40 10000 1000
1.00E+00 12.42 2.00 6.40
1.00E+00 79.10 2.00 6.40
1.00E+00 69.37 2.00 6.40
1.00E+00 46.75 2.00 6.40
1.00E+00 15.93 2.00 6.40
1.00E+00 11.20 2.00 6.40
1.00E+00 31.68 2.00 6.40
1.00E+00 10.87 2.00 6.40
1.00E+00 10.54 2.00 6.40 10000 1000
1.00E+00 87.24 2.00 6.40
1.00E+00 22.73 2.00 6.40
1.00E+00 16.21 2.00 6.40
1.00E+00 10.02 2.00 6.40
1.00E+00 17.60 2.00 6.40
1.00E+00 39.36 2.00 6.40
1.00E+00 76.84 2.00 6.40
1.00E+00 93.87 2.00 6.40
1.00E+00 53.85 2.00 6.40
1.00E+00 62.18 2.00 6.40
1.00E+00 9.34 2.00 6.40
1.00E+00 15.30 2.00 6.40
1.00E+00 36.64 2.00 6.40
1.00E+00 17.56 2.00 6.40
1.00E+00 65.96 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.23E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.79E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 1315 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :02 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :04 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :06 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :07 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :09 PM EPA Interlab L07 1315 SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-610
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
V SWA-L07-1315-T01-A 1 1.59E+01
V SWA-L07-1315-T02-A 1 1.62E+01
V SWA-L07-1315-T03-A 1 1.07E+01
V SWA-L07-1315-T04-A 1 2.22E+01
V SWA-L07-1315-T05-A 1 1.74E+01
V SWA-L07-1315-T06-A 1 2.07E+01
V SWA-L07-1315-T07-A 1 1.81E+01
V SWA-L07-1315-T08-A 1 9.40E+00
V SWA-L07-1315-T09-A 1 1.51E+01
V SWA-L07-1315-T01-B 1 1.48E+01
V SWA-L07-1315-T02-B 1 1.53E+01
V SWA-L07-1315-T03-B 1 8.88E+00
V SWA-L07-1315-T04-B 1 2.14E+01
V SWA-L07-1315-T05-B 1 1.78E+01
V SWA-L07-1315-T06-B 1 2.07E+01
V SWA-L07-1315-T07-B 1 1.60E+01
V SWA-L07-1315-T08-B 1 1.03E+01
V SWA-L07-1315-T09-B 1 1.42E+01
V SWA-L07-1315-T01-C 1 1.55E+01
V SWA-L07-1315-T02-C 1 1.57E+01
V SWA-L07-1315-T03-C 1 9.79E+00
V SWA-L07-1315-T04-C 1 2.16E+01
V SWA-L07-1315-T05-C 1 1.77E+01
V SWA-L07-1315-T06-C 1 2.11E+01
V SWA-L07-1315-T07-C 1 1.78E+01
V SWA-L07-1315-T08-C 1 9.96E+00
V SWA-L07-1315-T09-C 1 1.64E+01
V SWA-L07-1315-M01-A 1 7.50E-01 U1/2
V SWA-L07-1315-M02-A 1 7.50E-01 U1/2
V SWA-L07-1315-M03-A 1 7.50E-01 U1/2
V SWA-L07-1315-M04-A 1 7.50E-01 U1/2
V SWA-L07-1315-M05-A 1 7.50E-01 U1/2
V SWA-L07-1315-M06-A 1 7.50E-01 U1/2
V SWA-L07-1315-M07-A 1 7.50E-01 U1/2
V SWA-L07-1315-M08-A 1 7.50E-01 U1/2
V SWA-L07-1315-M09-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.59E+01 3.24 1.50 4.77
1.62E+01 5.93 1.50 4.77
1.07E+01 6.11 1.50 4.77 10000 1000
2.22E+01 3.56 1.50 4.77
1.74E+01 6.99 1.50 4.77
2.07E+01 2.39 1.50 4.77
1.81E+01 1.65 1.50 4.77
9.40E+00 6.78 1.50 4.77
1.51E+01 6.59 1.50 4.77
1.48E+01 4.65 1.50 4.77
1.53E+01 0.93 1.50 4.77
8.88E+00 2.37 1.50 4.77 10000 1000
2.14E+01 4.21 1.50 4.77
1.78E+01 4.07 1.50 4.77
2.07E+01 3.87 1.50 4.77
1.60E+01 3.15 1.50 4.77
1.03E+01 3.80 1.50 4.77
1.42E+01 4.55 1.50 4.77
1.55E+01 1.49 1.50 4.77
1.57E+01 1.72 1.50 4.77
9.79E+00 2.00 1.50 4.77 10000 1000
2.16E+01 0.48 1.50 4.77
1.77E+01 1.88 1.50 4.77
2.11E+01 0.98 1.50 4.77
1.78E+01 1.07 1.50 4.77
9.96E+00 8.52 1.50 4.77
1.64E+01 2.29 1.50 4.77
7.50E-01 35.59 1.50 4.77
7.50E-01 27.30 1.50 4.77
7.50E-01 37.68 1.50 4.77
7.50E-01 32.41 1.50 4.77
7.50E-01 46.44 1.50 4.77
7.50E-01 40.23 1.50 4.77
7.50E-01 54.90 1.50 4.77
7.50E-01 28.72 1.50 4.77
7.50E-01 34.27 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.50E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.17E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 1315 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315SWA
3/1/11 1:02 PM EPA Interlab L07 1315SWA
3/1/11 1:04 PM EPA Interlab L07 1315SWA
3/1/11 1:06 PM EPA Interlab L07 1315SWA
3/1/11 1:07 PM EPA Interlab L07 1315SWA
3/1/11 1:09 PM EPA Interlab L07 1315SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-611
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L
Zn SWA-L07-1315-T01-A 1 3.53E+00
Zn SWA-L07-1315-T02-A 1 3.01E+00 E
Zn SWA-L07-1315-T03-A 1 1.11E+OOE
Zn SWA-L07-1315-T04-A 1 2.14E+00 E
Zn SWA-L07-1315-T05-A 1 5.00E-01 U1/2
Zn SWA-L07-1315-T06-A 1 5.00E-01 U1/2
Zn SWA-L07-1315-T07-A 1 6.51E+00
Zn SWA-L07-1315-T08-A 1 1.39E+00 E
Zn SWA-L07-1315-T09-A 1 1.23E+00 E
Zn SWA-L07-1315-T01-B 1 5.04E+00
Zn SWA-L07-1315-T02-B 1 2.78E+00 E
Zn SWA-L07-1315-T03-B 1 1.54E+00 E
Zn SWA-L07-1315-T04-B 1 5.00E-01 U1/2
Zn SWA-L07-1315-T05-B 1 1.03E+00 E
Zn SWA-L07-1315-T06-B 1 1.24E+00 E
Zn SWA-L07-1315-T07-B 1 8.20E+00
Zn SWA-L07-1315-T08-B 1 2.71E+00 E
Zn SWA-L07-1315-T09-B 1 2.94E+00 E
Zn SWA-L07-1315-T01-C 1 3.12E+00 E
Zn SWA-L07-1315-T02-C 1 1.64E+00 E
Zn SWA-L07-1315-T03-C 1 1.78E+00 E
Zn SWA-L07-1315-T04-C 1 1.57E+00 E
Zn SWA-L07-1315-T05-C 1 1.43E+00 E
Zn SWA-L07-1315-T06-C 1 1.30E+00 E
Zn SWA-L07-1315-T07-C 1 2.07E+01
Zn SWA-L07-1315-T08-C 1 1.58E+00 E
Zn SWA-L07-1315-T09-C 1 2.78E+00 E
Zn SWA-L07-1315-M01-A 1 5.00E-01 U1/2
Zn SWA-L07-1315-M02-A 1 5.00E-01 U1/2
Zn SWA-L07-1315-M03-A 1 5.00E-01 U1/2
Zn SWA-L07-1315-M04-A 1 5.00E-01 U1/2
Zn SWA-L07-1315-M05-A 1 5.00E-01 U1/2
Zn SWA-L07-1315-M06-A 1 5.00E-01 U1/2
Zn SWA-L07-1315-M07-A 1 5.00E-01 U1/2
Zn SWA-L07-1315-M08-A 1 5.00E-01 U1/2
Zn SWA-L07-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.53E+00 5.35 1.00 3.18
3.01E+00 17.75 1.00 3.18
1.11E+00 16.04 1.00 3.18 10000 1000
2.14E+00 22.05 1.00 3.18
5.00E-01 59.93 1.00 3.18
5.00E-01 55.93 1.00 3.18
6.51E+00 5.70 1.00 3.18
1.39E+00 7.94 1.00 3.18
1.23E+00 35.61 1.00 3.18
5.04E+00 1.83 1.00 3.18
2.78E+00 14.31 1.00 3.18
1.54E+00 16.19 1.00 3.18 10000 1000
5.00E-01 46.46 1.00 3.18
1.03E+00 30.20 1.00 3.18
1.24E+00 21.46 1.00 3.18
8.20E+00 2.67 1.00 3.18
2.71E+00 2.51 1.00 3.18
2.94E+00 1.77 1.00 3.18
3.12E+00 14.17 1.00 3.18
1.64E+00 26.32 1.00 3.18
1.78E+00 10.82 1.00 3.18 10000 1000
1.57E+00 19.73 1.00 3.18
1.43E+00 33.71 1.00 3.18
1.30E+00 27.82 1.00 3.18
2.07E+01 3.36 1.00 3.18
1.58E+00 15.68 1.00 3.18
2.78E+00 9.96 1.00 3.18
5.00E-01 0.78 1.00 3.18
5.00E-01 6.38 1.00 3.18
5.00E-01 35.48 1.00 3.18
5.00E-01 9.63 1.00 3.18
5.00E-01 6.93 1.00 3.18
5.00E-01 9.26 1.00 3.18
5.00E-01 12.78 1.00 3.18
5.00E-01 11.72 1.00 3.18
5.00E-01 2.83 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.09E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.67E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/1/11 12:20 PM EPA Interlab L07 1315 SWA
3/1/11 2:17 PM EPA Interlab L07 1315 SWA
3/1/11 12:23 PM EPA Interlab L07 1315 SWA
3/1/11 12:25 PM EPA Interlab L07 1315 SWA
3/1/11 12:26 PM EPA Interlab L07 1315 SWA
3/1/11 12:28 PM EPA Interlab L07 1315 SWA
3/1/11 12:29 PM EPA Interlab L07 1315 SWA
3/1/11 12:31 PM EPA Interlab L07 1315 SWA
3/1/11 12:33 PM EPA Interlab L07 1315 SWA
3/1/11 12:34 PM EPA Interlab L07 1315 SWA
3/1/11 12:36 PM EPA Interlab L07 1315 SWA
3/1/11 12:38 PM EPA Interlab L07 1315 SWA
3/1/11 12:39 PM EPA Interlab L07 1315 SWA
3/1/11 12:41 PM EPA Interlab L07 1315 SWA
3/1/11 12:43 PM EPA Interlab L07 1315 SWA
3/1/11 12:44 PM EPA Interlab L07 1315 SWA
3/1/11 12:46 PM EPA Interlab L07 1315 SWA
3/1/11 12:48 PM EPA Interlab L07 1315 SWA
3/1/11 12:56 PM EPA Interlab L07 1315 SWA
3/1/11 12:57 PM EPA Interlab L07 1315 SWA
3/1/11 12:59 PM EPA Interlab L07 1315 SWA
3/1/11 1:01 PM EPA Interlab L07 1315 SWA
3/1/11 1:02 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :04 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :06 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :07 PM EPA Interlab L07 1315 SWA
3/1/1 1 1 :09 PM EPA Interlab L07 1315 SWA
3/1/11 12:00 PM EPA Interlab L07 1315 SWA
3/1/11 12:02 PM EPA Interlab L07 1315 SWA
3/1/11 2:15 PM EPA Interlab L07 1315 SWA
3/1/11 12:05 PM EPA Interlab L07 1315 SWA
3/1/11 4:06 PM EPA Interlab L07 1315 SWA
3/1/11 12:08 PM EPA Interlab L07 1315 SWA
3/1/11 12:10 PM EPA Interlab L07 1315 SWA
3/1/11 12:11 PM EPA Interlab L07 1315SWA
3/1/11 12:13 PM EPA Interlab L07 1315 SWA
1-612
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1315:
Dilut
Element Sample ID Fact
Al SWA-L09-1315-T01-A
Al SWA-L09-1315-T02-A
Al SWA-L09-1315-T03-A
Al SWA-L09-1315-T04-A
Al SWA-L09-1315-T05-A
Al SWA-L09-1315-T06-A
Al SWA-L09-1315-T07-A
Al SWA-L09-1315-T08-A
Al SWA-L09-1315-T09-A
Al SWA-L09-1315-T01-B
Al SWA-L09-1315-T02-B
Al SWA-L09-1315-T03-B
Al SWA-L09-1315-T04-B
Al SWA-L09-1315-T05-B
Al SWA-L09-1315-T06-B
Al SWA-L09-1315-T07-B
Al SWA-L09-1315-T08-B
Al SWA-L09-1315-T09-B
Al SWA-L09-1315-T01-C
Al SWA-L09-1315-T02-C
Al SWA-L09-1315-T03-C
Al SWA-L09-1315-T04-C
Al SWA-L09-1315-T05-C
Al SWA-L09-1315-T06-C
Al SWA-L09-1315-T07-C
Al SWA-L09-1315-T08-C
Al SWA-L09-1315-T09-C
Al SWA-L09-1315-M01-A
Al SWA-L09-1315-M02-A
Al SWA-L09-1315-M03-A
Al SWA-L09-1315-M04-A
Al SWA-L09-1315-M05-A
Al SWA-L09-1315-M06-A
Al SWA-L09-1315-M07-A
Al SWA-L09-1315-M08-A
Al SWA-L09-1315-M09-A
on Sample
or Cone. Quallf
ug/L
1 9.90E+02
1 2.52E+03
1 2.14E+03
1 3.75E+03
1 3.46E+03
1 4.30E+03
1 3.61 E+03
1 2.35E+03
1 3.08E+03
1 1.01 E+03
1 2.93E+03
1 1.67E+03
1 3.43E+03
1 3.43E+03
1 3.99E+03
1 3.47E+03
1 2.30E+03
1 2.95E+03
1 1.01 E+03
1 2.46E+03
1 1.90E+03
1 3.90E+03
1 3.44E+03
1 4.41 E+03
1 3.55E+03
1 2.33E+03
1 3.13E+03
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
er Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.90E+02 2.17 1.00 3.18
2.52E+03 1.38 1.00 3.18
2.14E+03 1.04 1.00 3.18 10000 1000
3.75E+03 2.11 1.00 3.18
3.46E+03 0.83 1.00 3.18
4.30E+03 1.81 1.00 3.18
3.61E+03 1.09 1.00 3.18
2.35E+03 0.60 1.00 3.18
3.08E+03 2.61 1.00 3.18
1.01 E+03 1.05 1.00 3.18
2.93E+03 0.82 1.00 3.18
1.67E+03 3.02 1.00 3.18 10000 1000
3.43E+03 0.79 1.00 3.18
3.43E+03 1.86 1.00 3.18
3.99E+03 3.09 1.00 3.18
3.47E+03 1.24 1.00 3.18
2.30E+03 0.78 1.00 3.18
2.95E+03 1.30 1.00 3.18
1.01 E+03 0.34 1.00 3.18
2.46E+03 0.90 1.00 3.18
1.90E+03 0.53 1.00 3.18 10000 1000
3.90E+03 1.96 1.00 3.18
3.44E+03 1.66 1.00 3.18
4.41E+03 1.19 1.00 3.18
3.55E+03 1.10 1.00 3.18
2.33E+03 1.23 1.00 3.18
3.13E+03 1.98 1.00 3.18
5.00E-01 2.25 1.00 3.18
5.00E-01 2.67 1.00 3.18
5.00E-01 1.23 1.00 3.18
5.00E-01 1.55 1.00 3.18
5.00E-01 3.86 1.00 3.18
5.00E-01 3.34 1.00 3.18
5.00E-01 8.71 1.00 3.18
5.00E-01 27.41 1.00 3.18
5.00E-01 1.23 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.15E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.64E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.81 E+03 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/11 4:59 PM EPA Interlab L09 1315 SWA
8/18/11 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/11 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/11 5:27 PM EPA Interlab L09 1315 SWA
8/18/11 5:28 PM EPA Interlab L09 1315 SWA
8/18/11 5:30 PM EPA Interlab L09 1315 SWA
8/18/11 5:32 PM EPA Interlab L09 1315 SWA
8/18/11 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/11 5:37 PM EPA Interlab L09 1315 SWA
8/18/11 5:38 PM EPA Interlab L09 1315 SWA
8/18/11 5:40 PM EPA Interlab L09 1315 SWA
8/18/11 5:42 PM EPA Interlab L09 1315 SWA
8/18/11 5:43 PM EPA Interlab L09 1315 SWA
8/18/11 5:45 PM EPA Interlab L09 1315 SWA
8/18/11 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/11 4:42 PM EPA Interlab L09 1315 SWA
8/18/11 4:44 PM EPA Interlab L09 1315 SWA
8/18/11 4:46 PM EPA Interlab L09 1315 SWA
8/18/11 4:47 PM EPA Interlab L09 1315 SWA
8/18/11 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/11 4:52 PM EPA Interlab L09 1315 SWA
1-613
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Sb SWA-L09-1315-T01-A 1 1.27E+02
Sb SWA-L09-1315-T02-A 1 2.49E+02
Sb SWA-L09-1315-T03-A 1 2.29E+02
Sb SWA-L09-1315-T04-A 1 3.87E+02
Sb SWA-L09-1315-T05-A 1 3.65E+02
Sb SWA-L09-1315-T06-A 1 4.39E+02
Sb SWA-L09-1315-T07-A 1 3.09E+02
Sb SWA-L09-1315-T08-A 1 2.16E+02
Sb SWA-L09-1315-T09-A 1 2.67E+02
Sb SWA-L09-1315-T01-B 1 1.30E+02
Sb SWA-L09-1315-T02-B 1 2.76E+02
Sb SWA-L09-1315-T03-B 1 1.42E+02
Sb SWA-L09-1315-T04-B 1 2.78E+02
Sb SWA-L09-1315-T05-B 1 2.90E+02
Sb SWA-L09-1315-T06-B 1 3.38E+02
Sb SWA-L09-1315-T07-B 1 2.84E+02
Sb SWA-L09-1315-T08-B 1 2.00E+02
Sb SWA-L09-1315-T09-B 1 2.48E+02
Sb SWA-L09-1315-T01-C 1 1.67E+02
Sb SWA-L09-1315-T02-C 1 3.24E+02
Sb SWA-L09-1315-T03-C 1 1.69E+02
Sb SWA-L09-1315-T04-C 1 3.29E+02
Sb SWA-L09-1315-T05-C 1 2.82E+02
Sb SWA-L09-1315-T06-C 1 3.86E+02
Sb SWA-L09-1315-T07-C 1 2.88E+02
Sb SWA-L09-1315-T08-C 1 2.21E+02
Sb SWA-L09-1315-T09-C 1 2.65E+02
Sb SWA-L09-1315-M01-A 1 3.75E+00 U1/2
Sb SWA-L09-1315-M02-A 1 3.75E+00 U1/2
Sb SWA-L09-1315-M03-A 1 3.75E+00 U1/2
Sb SWA-L09-1315-M04-A 1 3.75E+00 U1/2
Sb SWA-L09-1315-M05-A 1 3.75E+00 U1/2
Sb SWA-L09-1315-M06-A 1 3.75E+00 U1/2
Sb SWA-L09-1315-M07-A 1 3.75E+00 U1/2
Sb SWA-L09-1315-M08-A 1 3.75E+00 U1/2
Sb SWA-L09-1315-M09-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.27E+02 4.52 7.50 23.90
2.49E+02 4.92 7.50 23.90
2.29E+02 2.00 7.50 23.90 10000 1000
3.87E+02 1.75 7.50 23.90
3.65E+02 1.41 7.50 23.90
4.39E+02 3.47 7.50 23.90
3.09E+02 2.56 7.50 23.90
2.16E+02 1.00 7.50 23.90
2.67E+02 3.80 7.50 23.90
1.30E+02 1.49 7.50 23.90
2.76E+02 3.70 7.50 23.90
1.42E+02 3.41 7.50 23.90 10000 1000
2.78E+02 3.19 7.50 23.90
2.90E+02 5.20 7.50 23.90
3.38E+02 3.03 7.50 23.90
2.84E+02 2.68 7.50 23.90
2.00E+02 6.32 7.50 23.90
2.48E+02 2.49 7.50 23.90
1.67E+02 4.06 7.50 23.90
3.24E+02 2.65 7.50 23.90
1.69E+02 0.84 7.50 23.90 10000 1000
3.29E+02 2.96 7.50 23.90
2.82E+02 1.87 7.50 23.90
3.86E+02 2.07 7.50 23.90
2.88E+02 0.79 7.50 23.90
2.21E+02 0.76 7.50 23.90
2.65E+02 3.84 7.50 23.90
3.75E+00 28.95 7.50 23.90
3.75E+00 31.57 7.50 23.90
3.75E+00 3.60 7.50 23.90
3.75E+00 14.77 7.50 23.90
3.75E+00 12.70 7.50 23.90
3.75E+00 4.67 7.50 23.90
3.75E+00 35.90 7.50 23.90
3.75E+00 24.24 7.50 23.90
3.75E+00 35.88 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.30E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.22E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.29E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:59 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/11 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:27 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:28 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:30 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:32 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:37 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:38 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:40 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:43 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:45 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:44 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:46 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:47 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:52 PM EPA Interlab L09 1315 SWA
1-614
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
As SWA-L09-1315-T01-A 1 6.40E+01
As SWA-L09-1315-T02-A 1 1.61E+02
As SWA-L09-1315-T03-A 1 7.25E+01
As SWA-L09-1315-T04-A 1 2.95E+02
As SWA-L09-1315-T05-A 1 2.12E+02
As SWA-L09-1315-T06-A 1 2.16E+02
As SWA-L09-1315-T07-A 1 1.42E+02
As SWA-L09-1315-T08-A 1 8.87E+01
As SWA-L09-1315-T09-A 1 1.18E+02
As SWA-L09-1315-T01-B 1 7.08E+01
As SWA-L09-1315-T02-B 1 1.55E+02
As SWA-L09-1315-T03-B 1 6.01E+01
As SWA-L09-1315-T04-B 1 2.39E+02
As SWA-L09-1315-T05-B 1 1.26E+02
As SWA-L09-1315-T06-B 1 1.44E+02
As SWA-L09-1315-T07-B 1 1.09E+02
As SWA-L09-1315-T08-B 1 6.51E+01
As SWA-L09-1315-T09-B 1 8.71E+01
As SWA-L09-1315-T01-C 1 8.81E+01
As SWA-L09-1315-T02-C 1 2.18E+02
As SWA-L09-1315-T03-C 1 9.28E+01
As SWA-L09-1315-T04-C 1 2.27E+02
As SWA-L09-1315-T05-C 1 1.77E+02
As SWA-L09-1315-T06-C 1 1.99E+02
As SWA-L09-1315-T07-C 1 1.53E+02
As SWA-L09-1315-T08-C 1 8.36E+01
As SWA-L09-1315-T09-C 1 1.08E+02
As SWA-L09-1315-M01-A 1 5.50E+00 U1/2
As SWA-L09-1315-M02-A 1 5.50E+00 U1/2
As SWA-L09-1315-M03-A 1 5.50E+00 U1/2
As SWA-L09-1315-M04-A 1 5.50E+00 U1/2
As SWA-L09-1315-M05-A 1 5.50E+00 U1/2
As SWA-L09-1315-M06-A 1 5.50E+00 U1/2
As SWA-L09-1315-M07-A 1 5.50E+00 U1/2
As SWA-L09-1315-M08-A 1 5.50E+00 U1/2
As SWA-L09-1315-M09-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.40E+01 9.75 11.00 35.00
1.61E+02 3.89 11.00 35.00
7.25E+01 3.08 11.00 35.00 10000 1000
2.95E+02 5.26 11.00 35.00
2.12E+02 1.02 11.00 35.00
2.16E+02 1.65 11.00 35.00
1.42E+02 1.38 11.00 35.00
8.87E+01 7.49 11.00 35.00
1.18E+02 5.74 11.00 35.00
7.08E+01 6.82 11.00 35.00
1.55E+02 1.52 11.00 35.00
6.01E+01 0.76 11.00 35.00 10000 1000
2.39E+02 3.83 11.00 35.00
1.26E+02 8.04 11.00 35.00
1.44E+02 6.33 11.00 35.00
1.09E+02 4.88 11.00 35.00
6.51E+01 1.48 11.00 35.00
8.71E+01 4.67 11.00 35.00
8.81E+01 1.81 11.00 35.00
2.18E+02 1.27 11.00 35.00
9.28E+01 5.93 11.00 35.00 10000 1000
2.27E+02 1.91 11.00 35.00
1.77E+02 4.96 11.00 35.00
1.99E+02 2.88 11.00 35.00
1.53E+02 1.04 11.00 35.00
8.36E+01 6.05 11.00 35.00
1.08E+02 2.59 11.00 35.00
5.50E+00 20.59 11.00 35.00
5.50E+00 39.81 11.00 35.00
5.50E+00 23.65 11.00 35.00
5.50E+00 14.23 11.00 35.00
5.50E+00 61.60 11.00 35.00
5.50E+00 43.23 11.00 35.00
5.50E+00 45.74 11.00 35.00
5.50E+00 41.20 11.00 35.00
5.50E+00 39.07 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 . 1 6E+03 1 08% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:59 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/11 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:27 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:28 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:30 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:32 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:37 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:38 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:40 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:43 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:45 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:44 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:46 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:47 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:52 PM EPA Interlab L09 1315 SWA
1-615
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
B SWA-L09-1315-T01-A 1 1.97E+01
B SWA-L09-1315-T02-A 1 4.41E+01
B SWA-L09-1315-T03-A 1 4.56E+01
B SWA-L09-1315-T04-A 1 6.38E+01
B SWA-L09-1315-T05-A 1 5.85E+01
B SWA-L09-1315-T06-A 1 7.24E+01
B SWA-L09-1315-T07-A 1 5.03E+01
B SWA-L09-1315-T08-A 1 3.82E+01
B SWA-L09-1315-T09-A 1 4.81 E+01
B SWA-L09-1315-T01-B 1 2.22E+01
B SWA-L09-1315-T02-B 1 7.04E+01
B SWA-L09-1315-T03-B 1 3.59E+01
B SWA-L09-1315-T04-B 1 4.99E+01
B SWA-L09-1315-T05-B 1 5.06E+01
B SWA-L09-1315-T06-B 1 5.93E+01
B SWA-L09-1315-T07-B 1 5.32E+01
B SWA-L09-1315-T08-B 1 3.82E+01
B SWA-L09-1315-T09-B 1 5.02E+01
B SWA-L09-1315-T01-C 1 1.94E+01
B SWA-L09-1315-T02-C 1 5.50E+01
B SWA-L09-1315-T03-C 1 3.13E+01
B SWA-L09-1315-T04-C 1 4.70E+01
B SWA-L09-1315-T05-C 1 4.19E+01
B SWA-L09-1315-T06-C 1 5.71E+01
B SWA-L09-1315-T07-C 1 5.47E+01
B SWA-L09-1315-T08-C 1 4.44E+01
B SWA-L09-1315-T09-C 1 5.85E+01
B SWA-L09-1315-M01-A 1 5.00E-01 U1/2
B SWA-L09-1315-M02-A 1 5.00E-01 U1/2
B SWA-L09-1315-M03-A 1 5.00E-01 U1/2
B SWA-L09-1315-M04-A 1 5.00E-01 U1/2
B SWA-L09-1315-M05-A 1 5.00E-01 U1/2
B SWA-L09-1315-M06-A 1 5.00E-01 U1/2
B SWA-L09-1315-M07-A 1 5.00E-01 U1/2
B SWA-L09-1315-M08-A 1 5.00E-01 U1/2
B SWA-L09-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.97E+01 5.23 1.00 3.18
4.41E+01 1.92 1.00 3.18
4.56E+01 2.26 1.00 3.18 10000 1000
6.38E+01 4.14 1.00 3.18
5.85E+01 1.14 1.00 3.18
7.24E+01 1.45 1.00 3.18
5.03E+01 4.00 1.00 3.18
3.82E+01 4.64 1.00 3.18
4.81E+01 2.40 1.00 3.18
2.22E+01 3.82 1.00 3.18
7.04E+01 0.52 1.00 3.18
3.59E+01 6.78 1.00 3.18 10000 1000
4.99E+01 2.46 1.00 3.18
5.06E+01 4.27 1.00 3.18
5.93E+01 1.27 1.00 3.18
5.32E+01 3.09 1.00 3.18
3.82E+01 1.19 1.00 3.18
5.02E+01 3.56 1.00 3.18
1.94E+01 3.75 1.00 3.18
5.50E+01 1.76 1.00 3.18
3.13E+01 2.73 1.00 3.18 10000 1000
4.70E+01 2.79 1.00 3.18
4.19E+01 1.44 1.00 3.18
5.71E+01 0.81 1.00 3.18
5.47E+01 9.36 1.00 3.18
4.44E+01 4.68 1.00 3.18
5.85E+01 2.54 1.00 3.18
5.00E-01 7.70 1.00 3.18
5.00E-01 7.75 1.00 3.18
5.00E-01 2.10 1.00 3.18
5.00E-01 5.22 1.00 3.18
5.00E-01 1.79 1.00 3.18
5.00E-01 1.47 1.00 3.18
5.00E-01 9.44 1.00 3.18
5.00E-01 6.31 1.00 3.18
5.00E-01 1.11 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.09E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.46E+02 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:59 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/11 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:27 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:28 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:30 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:32 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:37 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:38 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:40 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:43 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:45 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:44 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:46 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:47 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:52 PM EPA Interlab L09 1315 SWA
1-616
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualil
ug/L
Ba SWA-L09-1315-T01-A 1 5.02E+01
Ba SWA-L09-1315-T02-A 1 1.48E+02
Ba SWA-L09-1315-T03-A 1 2.15E+02
Ba SWA-L09-1315-T04-A 1 3.31E+02
Ba SWA-L09-1315-T05-A 1 4.07E+02
Ba SWA-L09-1315-T06-A 1 4.78E+02
Ba SWA-L09-1315-T07-A 1 5.70E+02
Ba SWA-L09-1315-T08-A 1 5.34E+02
Ba SWA-L09-1315-T09-A 1 5.50E+02
Ba SWA-L09-1315-T01-B 1 5.00E+01
Ba SWA-L09-1315-T02-B 1 1.92E+02
Ba SWA-L09-1315-T03-B 1 2.06E+02
Ba SWA-L09-1315-T04-B 1 3.60E+02
Ba SWA-L09-1315-T05-B 1 4.76E+02
Ba SWA-L09-1315-T06-B 1 5.67E+02
Ba SWA-L09-1315-T07-B 1 6.07E+02
Ba SWA-L09-1315-T08-B 1 5.56E+02
Ba SWA-L09-1315-T09-B 1 5.87E+02
Ba SWA-L09-1315-T01-C 1 5.11E+01
Ba SWA-L09-1315-T02-C 1 1.75E+02
Ba SWA-L09-1315-T03-C 1 2.18E+02
Ba SWA-L09-1315-T04-C 1 3.91E+02
Ba SWA-L09-1315-T05-C 1 4.97E+02
Ba SWA-L09-1315-T06-C 1 5.81E+02
Ba SWA-L09-1315-T07-C 1 5.97E+02
Ba SWA-L09-1315-T08-C 1 5.22E+02
Ba SWA-L09-1315-T09-C 1 5.46E+02
Ba SWA-L09-1315-M01-A 1 5.00E-01 U1/2
Ba SWA-L09-1315-M02-A 1 5.00E-01 U1/2
Ba SWA-L09-1315-M03-A 1 5.00E-01 U1/2
Ba SWA-L09-1315-M04-A 1 5.00E-01 U1/2
Ba SWA-L09-1315-M05-A 1 5.00E-01 U1/2
Ba SWA-L09-1315-M06-A 1 5.00E-01 U1/2
Ba SWA-L09-1315-M07-A 1 5.00E-01 U1/2
Ba SWA-L09-1315-M08-A 1 5.00E-01 U1/2
Ba SWA-L09-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.02E+01 1.75 1.00 3.18
1.48E+02 2.01 1.00 3.18
2.15E+02 1.54 1.00 3.18 10000 1000
3.31E+02 2.51 1.00 3.18
4.07E+02 1.70 1.00 3.18
4.78E+02 1.64 1.00 3.18
5.70E+02 0.28 1.00 3.18
5.34E+02 1.78 1.00 3.18
5.50E+02 0.40 1.00 3.18
5.00E+01 1.45 1.00 3.18
1.92E+02 1.29 1.00 3.18
2.06E+02 2.02 1.00 3.18 10000 1000
3.60E+02 0.77 1.00 3.18
4.76E+02 1.76 1.00 3.18
5.67E+02 2.61 1.00 3.18
6.07E+02 1.31 1.00 3.18
5.56E+02 1.44 1.00 3.18
5.87E+02 0.74 1.00 3.18
5.11E+01 0.75 1.00 3.18
1.75E+02 1.06 1.00 3.18
2.18E+02 1.39 1.00 3.18 10000 1000
3.91E+02 3.12 1.00 3.18
4.97E+02 1.41 1.00 3.18
5.81E+02 1.10 1.00 3.18
5.97E+02 3.01 1.00 3.18
5.22E+02 0.81 1.00 3.18
5.46E+02 1.61 1.00 3.18
5.00E-01 22.78 1.00 3.18
5.00E-01 38.36 1.00 3.18
5.00E-01 12.35 1.00 3.18
5.00E-01 44.57 1.00 3.18
5.00E-01 22.49 1.00 3.18
5.00E-01 33.73 1.00 3.18
5.00E-01 29.33 1.00 3.18
5.00E-01 25.82 1.00 3.18
5.00E-01 6.32 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.10E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.13E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
1/25/12 12:54 PM EPA Interlab L09 1315 SWA
1/25/12 12:55 PM EPA Interlab L09 1315 SWA
1/25/12 12:57 PM EPA Interlab L09 1315 SWA
1/25/12 12:59 PM EPA Interlab L09 1315 SWA
1/25/12 1 :00 PM EPA Interlab L09 1315 SWA
1/25/12 1 :02 PM EPA Interlab L09 1315 SWA
1/25/12 1 :04 PM EPA Interlab L09 1315 SWA
1/25/12 1:05 PM EPA Interlab L09 1315 SWA
1/25/12 1:07 PM EPA Interlab L09 1315 SWA
1/25/12 1:12 PM EPA Interlab L09 1315 SWA
1/25/12 1:14 PM EPA Interlab L09 1315 SWA
1/25/12 1:15 PM EPA Interlab L09 1315 SWA
1/25/12 1:17 PM EPA Interlab L09 1315 SWA
1/25/12 1:19 PM EPA Interlab L09 1315 SWA
1/25/12 1:20 PM EPA Interlab L09 1315 SWA
1/25/12 1:22 PM EPA Interlab L09 1315 SWA
1/25/12 1:24 PM EPA Interlab L09 1315 SWA
1/25/12 1:25 PM EPA Interlab L09 1315 SWA
1/25/12 1:27 PM EPA Interlab L09 1315 SWA
1/25/12 1:29 PM EPA Interlab L09 1315 SWA
1/25/12 1:30 PM EPA Interlab L09 1315 SWA
1/25/12 1:32 PM EPA Interlab L09 1315 SWA
1/25/12 1:33 PM EPA Interlab L09 1315 SWA
1/25/12 1:35 PM EPA Interlab L09 1315 SWA
1/25/12 1:37 PM EPA Interlab L09 1315 SWA
1/25/12 1:38 PM EPA Interlab L09 1315 SWA
1/25/12 1:40 PM EPA Interlab L09 1315 SWA
1/25/12 12:39 PM EPA Interlab L09 1315 SWA
1/25/12 12:41 PM EPA Interlab L09 1315 SWA
1/25/12 12:42 PM EPA Interlab L09 1315 SWA
1/25/12 12:44 PM EPA Interlab L09 1315 SWA
1/25/12 12:46 PM EPA Interlab L09 1315 SWA
1/25/12 12:47 PM EPA Interlab L09 1315 SWA
1/25/12 12:49 PM EPA Interlab L09 1315 SWA
1/25/12 12:51 PM EPA Interlab L09 1315 SWA
1/25/12 12:52 PM EPA Interlab L09 1315 SWA
1-617
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Be SWA-L09-1315-T01-A 1 9.50E-01 U1/2
Be SWA-L09-1315-T02-A 1 9.50E-01 U1/2
Be SWA-L09-1315-T03-A 1 9.50E-01 U1/2
Be SWA-L09-1315-T04-A 1 9.50E-01 U1/2
Be SWA-L09-1315-T05-A 1 9.50E-01 U1/2
Be SWA-L09-1315-T06-A 1 9.50E-01 U1/2
Be SWA-L09-1315-T07-A 1 9.50E-01 U1/2
Be SWA-L09-1315-T08-A 1 9.50E-01 U1/2
Be SWA-L09-1315-T09-A 1 9.50E-01 U1/2
Be SWA-L09-1315-T01-B 1 9.50E-01 U1/2
Be SWA-L09-1315-T02-B 1 9.50E-01 U1/2
Be SWA-L09-1315-T03-B 1 9.50E-01 U1/2
Be SWA-L09-1315-T04-B 1 9.50E-01 U1/2
Be SWA-L09-1315-T05-B 1 9.50E-01 U1/2
Be SWA-L09-1315-T06-B 1 9.50E-01 U1/2
Be SWA-L09-1315-T07-B 1 9.50E-01 U1/2
Be SWA-L09-1315-T08-B 1 9.50E-01 U1/2
Be SWA-L09-1315-T09-B 1 9.50E-01 U1/2
Be SWA-L09-1315-T01-C 1 9.50E-01 U1/2
Be SWA-L09-1315-T02-C 1 9.50E-01 U1/2
Be SWA-L09-1315-T03-C 1 9.50E-01 U1/2
Be SWA-L09-1315-T04-C 1 9.50E-01 U1/2
Be SWA-L09-1315-T05-C 1 9.50E-01 U1/2
Be SWA-L09-1315-T06-C 1 9.50E-01 U1/2
Be SWA-L09-1315-T07-C 1 9.50E-01 U1/2
Be SWA-L09-1315-T08-C 1 9.50E-01 U1/2
Be SWA-L09-1315-T09-C 1 9.50E-01 U1/2
Be SWA-L09-1315-M01-A 1 9.50E-01 U1/2
Be SWA-L09-1315-M02-A 1 9.50E-01 U1/2
Be SWA-L09-1315-M03-A 1 9.50E-01 U1/2
Be SWA-L09-1315-M04-A 1 9.50E-01 U1/2
Be SWA-L09-1315-M05-A 1 9.50E-01 U1/2
Be SWA-L09-1315-M06-A 1 9.50E-01 U1/2
Be SWA-L09-1315-M07-A 1 9.50E-01 U1/2
Be SWA-L09-1315-M08-A 1 9.50E-01 U1/2
Be SWA-L09-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 26.03 1.90 6.00
9.50E-01 30.84 1.90 6.00
9.50E-01 42.97 1.90 6.00 10000 1000
9.50E-01 36.84 1.90 6.00
9.50E-01 67.36 1.90 6.00
9.50E-01 21.31 1.90 6.00
9.50E-01 44.32 1.90 6.00
9.50E-01 52.06 1.90 6.00
9.50E-01 31.97 1.90 6.00
9.50E-01 56.36 1.90 6.00
9.50E-01 15.66 1.90 6.00
9.50E-01 34.19 1.90 6.00 10000 1000
9.50E-01 38.11 1.90 6.00
9.50E-01 64.51 1.90 6.00
9.50E-01 37.83 1.90 6.00
9.50E-01 51.00 1.90 6.00
9.50E-01 34.59 1.90 6.00
9.50E-01 63.20 1.90 6.00
9.50E-01 19.70 1.90 6.00
9.50E-01 34.05 1.90 6.00
9.50E-01 58.63 1.90 6.00 10000 1000
9.50E-01 61.91 1.90 6.00
9.50E-01 34.97 1.90 6.00
9.50E-01 21.06 1.90 6.00
9.50E-01 31.34 1.90 6.00
9.50E-01 30.75 1.90 6.00
9.50E-01 31.95 1.90 6.00
9.50E-01 57.30 1.90 6.00
9.50E-01 29.75 1.90 6.00
9.50E-01 40.55 1.90 6.00
9.50E-01 47.80 1.90 6.00
9.50E-01 30.39 1.90 6.00
9.50E-01 26.63 1.90 6.00
9.50E-01 54.51 1.90 6.00
9.50E-01 41.06 1.90 6.00
9.50E-01 47.67 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 . 1 1 E+03 1 1 1 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.04E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/11 4:59 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/11 5:27 PM EPA Interlab L09 1315 SWA
8/18/11 5:28 PM EPA Interlab L09 1315 SWA
8/18/11 5:30 PM EPA Interlab L09 1315 SWA
8/18/11 5:32 PM EPA Interlab L09 1315 SWA
8/18/11 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/11 5:37 PM EPA Interlab L09 1315 SWA
8/18/11 5:38 PM EPA Interlab L09 1315 SWA
8/18/11 5:40 PM EPA Interlab L09 1315 SWA
8/18/11 5:42 PM EPA Interlab L09 1315 SWA
8/18/11 5:43 PM EPA Interlab L09 1315 SWA
8/18/11 5:45 PM EPA Interlab L09 1315 SWA
8/18/11 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/11 4:42 PM EPA Interlab L09 1315 SWA
8/18/11 4:44 PM EPA Interlab L09 1315 SWA
8/18/11 4:46 PM EPA Interlab L09 1315 SWA
8/18/11 4:47 PM EPA Interlab L09 1315 SWA
8/18/11 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/11 4:52 PM EPA Interlab L09 1315 SWA
1-618
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cd SWA-L09-1315-T01-A 1 1.10E+00 U1/2
Cd SWA-L09-1315-T02-A 1 1.10E+00 U1/2
Cd SWA-L09-1315-T03-A 1 1.10E+00 U1/2
Cd SWA-L09-1315-T04-A 1 1.10E+00 U1/2
Cd SWA-L09-1315-T05-A 1 1.10E+00 U1/2
Cd SWA-L09-1315-T06-A 1 1.10E+00 U1/2
Cd SWA-L09-1315-T07-A 1 1.10E+00 U1/2
Cd SWA-L09-1315-T08-A 1 1.10E+00 U1/2
Cd SWA-L09-1315-T09-A 1 1.10E+00 U1/2
Cd SWA-L09-1315-T01-B 1 1.10E+00 U1/2
Cd SWA-L09-1315-T02-B 1 1.10E+00 U1/2
Cd SWA-L09-1315-T03-B 1 1.10E+00 U1/2
Cd SWA-L09-1315-T04-B 1 1.10E+00 U1/2
Cd SWA-L09-1315-T05-B 1 1.10E+00 U1/2
Cd SWA-L09-1315-T06-B 1 1.10E+00 U1/2
Cd SWA-L09-1315-T07-B 1 1.10E+00 U1/2
Cd SWA-L09-1315-T08-B 1 1.10E+00 U1/2
Cd SWA-L09-1315-T09-B 1 1.10E+00 U1/2
Cd SWA-L09-1315-T01-C 1 1.10E+00 U1/2
Cd SWA-L09-1315-T02-C 1 1.10E+00 U1/2
Cd SWA-L09-1315-T03-C 1 1.10E+00 U1/2
Cd SWA-L09-1315-T04-C 1 1.10E+00 U1/2
Cd SWA-L09-1315-T05-C 1 1.10E+00 U1/2
Cd SWA-L09-1315-T06-C 1 1.10E+00 U1/2
Cd SWA-L09-1315-T07-C 1 1.10E+00 U1/2
Cd SWA-L09-1315-T08-C 1 1.10E+00 U1/2
Cd SWA-L09-1315-T09-C 1 1.10E+00 U1/2
Cd SWA-L09-1315-M01-A 1 1.10E+00 U1/2
Cd SWA-L09-1315-M02-A 1 1.10E+00 U1/2
Cd SWA-L09-1315-M03-A 1 1.10E+00 U1/2
Cd SWA-L09-1315-M04-A 1 1.10E+00 U1/2
Cd SWA-L09-1315-M05-A 1 1.10E+00 U1/2
Cd SWA-L09-1315-M06-A 1 1.10E+00 U1/2
Cd SWA-L09-1315-M07-A 1 1.10E+00 U1/2
Cd SWA-L09-1315-M08-A 1 1.10E+00 U1/2
Cd SWA-L09-1315-M09-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 9.01 2.20 7.00
1.10E+00 48.45 2.20 7.00
1.10E+00 25.28 2.20 7.00 10000 1000
1.10E+00 27.69 2.20 7.00
1.10E+00 54.14 2.20 7.00
1.10E+00 39.34 2.20 7.00
1.10E+00 18.45 2.20 7.00
1.10E+00 51.69 2.20 7.00
1.10E+00 63.80 2.20 7.00
1.10E+00 24.05 2.20 7.00
1.10E+00 11.34 2.20 7.00
1.10E+00 54.50 2.20 7.00 10000 1000
1.10E+00 25.66 2.20 7.00
1.10E+00 36.53 2.20 7.00
1.10E+00 14.40 2.20 7.00
1.10E+00 39.20 2.20 7.00
1.10E+00 59.23 2.20 7.00
1.10E+00 31.20 2.20 7.00
1.10E+00 31.85 2.20 7.00
1.10E+00 24.52 2.20 7.00
1.10E+00 27.78 2.20 7.00 10000 1000
1.10E+00 58.26 2.20 7.00
1.10E+00 30.37 2.20 7.00
1.10E+00 50.74 2.20 7.00
1.10E+00 34.54 2.20 7.00
1.10E+00 43.55 2.20 7.00
1.10E+00 53.51 2.20 7.00
1.10E+00 9.76 2.20 7.00
1.10E+00 25.70 2.20 7.00
1.10E+00 31.77 2.20 7.00
1.10E+00 16.19 2.20 7.00
1.10E+00 46.82 2.20 7.00
1.10E+00 20.60 2.20 7.00
1.10E+00 52.05 2.20 7.00
1.10E+00 50.89 2.20 7.00
1.10E+00 31.68 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.13E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.20E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/11 4:59 PM EPA Interlab L09 1315 SWA
8/18/11 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/11 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/11 5:27 PM EPA Interlab L09 1315 SWA
8/18/11 5:28 PM EPA Interlab L09 1315 SWA
8/18/11 5:30 PM EPA Interlab L09 1315 SWA
8/18/11 5:32 PM EPA Interlab L09 1315 SWA
8/18/11 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/11 5:37 PM EPA Interlab L09 1315 SWA
8/18/11 5:38 PM EPA Interlab L09 1315 SWA
8/18/11 5:40 PM EPA Interlab L09 1315 SWA
8/18/11 5:42 PM EPA Interlab L09 1315 SWA
8/18/11 5:43 PM EPA Interlab L09 1315 SWA
8/18/11 5:45 PM EPA Interlab L09 1315 SWA
8/18/11 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/11 4:42 PM EPA Interlab L09 1315 SWA
8/18/11 4:44 PM EPA Interlab L09 1315 SWA
8/18/11 4:46 PM EPA Interlab L09 1315 SWA
8/18/11 4:47 PM EPA Interlab L09 1315 SWA
8/18/11 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/11 4:52 PM EPA Interlab L09 1315 SWA
1-619
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Ca SWA-L09-1315-T01-A 1 2.22E+03
Ca SWA-L09-1315-T02-A 1 7.41E+03
Ca SWA-L09-1315-T03-A 1 9.96E+03
Ca SWA-L09-1315-T04-A 1 1.70E+04
Ca SWA-L09-1315-T05-A 1 1.95E+04
Ca SWA-L09-1315-T06-A 1 2.29E+04
Ca SWA-L09-1315-T07-A 1 2.33E+04
Ca SWA-L09-1315-T08-A 1 2.06E+04
Ca SWA-L09-1315-T09-A 1 2.28E+04
Ca SWA-L09-1315-T01-B 1 2.30E+03
Ca SWA-L09-1315-T02-B 1 8.41E+03
Ca SWA-L09-1315-T03-B 1 9.51E+03
Ca SWA-L09-1315-T04-B 1 1.88E+04
Ca SWA-L09-1315-T05-B 1 2.16E+04
Ca SWA-L09-1315-T06-B 1 2.48E+04
Ca SWA-L09-1315-T07-B 1 2.50E+04
Ca SWA-L09-1315-T08-B 1 2.15E+04
Ca SWA-L09-1315-T09-B 1 2.38E+04
Ca SWA-L09-1315-T01-C 1 2.42E+03
Ca SWA-L09-1315-T02-C 1 7.40E+03
Ca SWA-L09-1315-T03-C 1 8.99E+03
Ca SWA-L09-1315-T04-C 1 1.70E+04
Ca SWA-L09-1315-T05-C 1 1.92E+04
Ca SWA-L09-1315-T06-C 1 2.39E+04
Ca SWA-L09-1315-T07-C 1 2.28E+04
Ca SWA-L09-1315-T08-C 1 2.07E+04
Ca SWA-L09-1315-T09-C 1 2.35E+04
Ca SWA-L09-1315-M01-A 1 9.95E+01
Ca SWA-L09-1315-M02-A 1 2.00E+01
Ca SWA-L09-1315-M03-A 1 1.76E+02
Ca SWA-L09-1315-M04-A 1 1.74E+02
Ca SWA-L09-1315-M05-A 1 9.33E+01
Ca SWA-L09-1315-M06-A 1 7.60E+01
Ca SWA-L09-1315-M07-A 1 8.14E+01
Ca SWA-L09-1315-M08-A 1 1.15E+02
Ca SWA-L09-1315-M09-A 1 1.72E+02
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.22E+03 2.55 2.60 8.30
7.41 E+03 1.64 2.60 8.30
9.96E+03 2.15 2.60 8.30 10000 1000
1.70E+04 1.64 2.60 8.30
1.95E+04 1.17 2.60 8.30
2.29E+04 2.09 2.60 8.30
2.33E+04 1.36 2.60 8.30
2.06E+04 0.58 2.60 8.30
2.28E+04 2.53 2.60 8.30
2.30E+03 0.95 2.60 8.30
8.41 E+03 1.25 2.60 8.30
9.51E+03 2.26 2.60 8.30 10000 1000
1.88E+04 0.99 2.60 8.30
2.16E+04 1.75 2.60 8.30
2.48E+04 2.43 2.60 8.30
2.50E+04 1.60 2.60 8.30
2.15E+04 1.12 2.60 8.30
2.38E+04 1.32 2.60 8.30
2.42E+03 0.17 2.60 8.30
7.40E+03 1.71 2.60 8.30
8.99E+03 0.50 2.60 8.30 10000 1000
1.70E+04 1.22 2.60 8.30
1.92E+04 1.73 2.60 8.30
2.39E+04 0.11 2.60 8.30
2.28E+04 1.41 2.60 8.30
2.07E+04 0.94 2.60 8.30
2.35E+04 1.99 2.60 8.30
9.95E+01 1.83 2.60 8.30
2.00E+01 5.71 2.60 8.30
1.76E+02 5.66 2.60 8.30
1.74E+02 5.92 2.60 8.30
9.33E+01 0.52 2.60 8.30
7.60E+01 4.40 2.60 8.30
8.14E+01 3.53 2.60 8.30
1.15E+02 2.08 2.60 8.30
1.72E+02 0.94 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.08E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.84E+03 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/11 4:59 PM EPA Interlab L09 1315 SWA
8/18/11 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/11 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/11 5:27 PM EPA Interlab L09 1315 SWA
8/18/11 5:28 PM EPA Interlab L09 1315 SWA
8/18/11 5:30 PM EPA Interlab L09 1315 SWA
8/18/11 5:32 PM EPA Interlab L09 1315 SWA
8/18/11 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/11 5:37 PM EPA Interlab L09 1315 SWA
8/18/11 5:38 PM EPA Interlab L09 1315 SWA
8/18/11 5:40 PM EPA Interlab L09 1315 SWA
8/18/11 5:42 PM EPA Interlab L09 1315 SWA
8/18/11 5:43 PM EPA Interlab L09 1315 SWA
8/18/11 5:45 PM EPA Interlab L09 1315 SWA
8/18/11 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/11 4:42 PM EPA Interlab L09 1315 SWA
8/18/11 4:44 PM EPA Interlab L09 1315 SWA
8/18/11 4:46 PM EPA Interlab L09 1315 SWA
8/18/11 4:47 PM EPA Interlab L09 1315 SWA
8/18/11 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/11 4:52 PM EPA Interlab L09 1315 SWA
1-620
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Cr SWA-L09-1315-T01-A 1 3.03E+01
Cr SWA-L09-1315-T02-A 1 6.03E+01
Cr SWA-L09-1315-T03-A 1 2.42E+01
Cr SWA-L09-1315-T04-A 1 3.22E+01
Cr SWA-L09-1315-T05-A 1 2.93E+01
Cr SWA-L09-1315-T06-A 1 3.70E+01
Cr SWA-L09-1315-T07-A 1 3.72E+01
Cr SWA-L09-1315-T08-A 1 2.79E+01
Cr SWA-L09-1315-T09-A 1 3.42E+01
Cr SWA-L09-1315-T01-B 1 3.11E+01
Cr SWA-L09-1315-T02-B 1 6.49E+01
Cr SWA-L09-1315-T03-B 1 2.42E+01
Cr SWA-L09-1315-T04-B 1 4.57E+01
Cr SWA-L09-1315-T05-B 1 4.02E+01
Cr SWA-L09-1315-T06-B 1 4.29E+01
Cr SWA-L09-1315-T07-B 1 3.91E+01
Cr SWA-L09-1315-T08-B 1 2.90E+01
Cr SWA-L09-1315-T09-B 1 3.47E+01
Cr SWA-L09-1315-T01-C 1 4.95E+01
Cr SWA-L09-1315-T02-C 1 6.35E+01
Cr SWA-L09-1315-T03-C 1 2.38E+01
Cr SWA-L09-1315-T04-C 1 4.07E+01
Cr SWA-L09-1315-T05-C 1 3.25E+01
Cr SWA-L09-1315-T06-C 1 4.09E+01
Cr SWA-L09-1315-T07-C 1 3.87E+01
Cr SWA-L09-1315-T08-C 1 2.69E+01
Cr SWA-L09-1315-T09-C 1 3.26E+01
Cr SWA-L09-1315-M01-A 1 6.00E-01 U1/2
Cr SWA-L09-1315-M02-A 1 6.00E-01 U1/2
Cr SWA-L09-1315-M03-A 1 6.00E-01 U1/2
Cr SWA-L09-1315-M04-A 1 6.00E-01 U1/2
Cr SWA-L09-1315-M05-A 1 6.00E-01 U1/2
Cr SWA-L09-1315-M06-A 1 6.00E-01 U1/2
Cr SWA-L09-1315-M07-A 1 6.00E-01 U1/2
Cr SWA-L09-1315-M08-A 1 6.00E-01 U1/2
Cr SWA-L09-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.03E+01 2.35 1.20 3.82
6.03E+01 1.89 1.20 3.82
2.42E+01 1.64 1.20 3.82 10000 1000
3.22E+01 4.26 1.20 3.82
2.93E+01 0.93 1.20 3.82
3.70E+01 2.17 1.20 3.82
3.72E+01 1.34 1.20 3.82
2.79E+01 3.66 1.20 3.82
3.42E+01 1.95 1.20 3.82
3.11E+01 1.60 1.20 3.82
6.49E+01 1.66 1.20 3.82
2.42E+01 1.42 1.20 3.82 10000 1000
4.57E+01 1.59 1.20 3.82
4.02E+01 1.39 1.20 3.82
4.29E+01 2.51 1.20 3.82
3.91E+01 0.82 1.20 3.82
2.90E+01 0.53 1.20 3.82
3.47E+01 1.40 1.20 3.82
4.95E+01 0.93 1.20 3.82
6.35E+01 1.75 1.20 3.82
2.38E+01 2.42 1.20 3.82 10000 1000
4.07E+01 0.86 1.20 3.82
3.25E+01 1.21 1.20 3.82
4.09E+01 0.69 1.20 3.82
3.87E+01 1.08 1.20 3.82
2.69E+01 2.15 1.20 3.82
3.26E+01 2.40 1.20 3.82
6.00E-01 54.29 1.20 3.82
6.00E-01 41.69 1.20 3.82
6.00E-01 23.21 1.20 3.82
6.00E-01 5.71 1.20 3.82
6.00E-01 8.39 1.20 3.82
6.00E-01 57.16 1.20 3.82
6.00E-01 59.36 1.20 3.82
6.00E-01 26.58 1.20 3.82
6.00E-01 8.73 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 . 1 3E+03 111 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.98E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:59 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/11 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:27 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:28 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:30 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:32 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:37 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:38 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:40 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:43 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:45 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:44 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:46 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:47 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:52 PM EPA Interlab L09 1315 SWA
1-621
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Co SWA-L09-1315-T01-A 1 9.00E-01 U1/2
Co SWA-L09-1315-T02-A 1 9.00E-01 U1/2
Co SWA-L09-1315-T03-A 1 9.00E-01 U1/2
Co SWA-L09-1315-T04-A 1 9.00E-01 U1/2
Co SWA-L09-1315-T05-A 1 9.00E-01 U1/2
Co SWA-L09-1315-T06-A 1 9.00E-01 U1/2
Co SWA-L09-1315-T07-A 1 9.00E-01 U1/2
Co SWA-L09-1315-T08-A 1 9.00E-01 U1/2
Co SWA-L09-1315-T09-A 1 9.00E-01 U1/2
Co SWA-L09-1315-T01-B 1 9.00E-01 U1/2
Co SWA-L09-1315-T02-B 1 9.00E-01 U1/2
Co SWA-L09-1315-T03-B 1 9.00E-01 U1/2
Co SWA-L09-1315-T04-B 1 9.00E-01 U1/2
Co SWA-L09-1315-T05-B 1 9.00E-01 U1/2
Co SWA-L09-1315-T06-B 1 9.00E-01 U1/2
Co SWA-L09-1315-T07-B 1 9.00E-01 U1/2
Co SWA-L09-1315-T08-B 1 9.00E-01 U1/2
Co SWA-L09-1315-T09-B 1 9.00E-01 U1/2
Co SWA-L09-1315-T01-C 1 9.00E-01 U1/2
Co SWA-L09-1315-T02-C 1 9.00E-01 U1/2
Co SWA-L09-1315-T03-C 1 9.00E-01 U1/2
Co SWA-L09-1315-T04-C 1 9.00E-01 U1/2
Co SWA-L09-1315-T05-C 1 9.00E-01 U1/2
Co SWA-L09-1315-T06-C 1 9.00E-01 U1/2
Co SWA-L09-1315-T07-C 1 9.00E-01 U1/2
Co SWA-L09-1315-T08-C 1 9.00E-01 U1/2
Co SWA-L09-1315-T09-C 1 9.00E-01 U1/2
Co SWA-L09-1315-M01-A 1 9.00E-01 U1/2
Co SWA-L09-1315-M02-A 1 9.00E-01 U1/2
Co SWA-L09-1315-M03-A 1 9.00E-01 U1/2
Co SWA-L09-1315-M04-A 1 9.00E-01 U1/2
Co SWA-L09-1315-M05-A 1 9.00E-01 U1/2
Co SWA-L09-1315-M06-A 1 9.00E-01 U1/2
Co SWA-L09-1315-M07-A 1 9.00E-01 U1/2
Co SWA-L09-1315-M08-A 1 9.00E-01 U1/2
Co SWA-L09-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 39.84 1.80 5.72
9.00E-01 48.20 1.80 5.72
9.00E-01 25.09 1.80 5.72 10000 1000
9.00E-01 54.20 1.80 5.72
9.00E-01 6.95 1.80 5.72
9.00E-01 46.69 1.80 5.72
9.00E-01 25.60 1.80 5.72
9.00E-01 71.05 1.80 5.72
9.00E-01 59.10 1.80 5.72
9.00E-01 38.25 1.80 5.72
9.00E-01 69.50 1.80 5.72
9.00E-01 32.18 1.80 5.72 10000 1000
9.00E-01 27.60 1.80 5.72
9.00E-01 26.47 1.80 5.72
9.00E-01 22.34 1.80 5.72
9.00E-01 53.34 1.80 5.72
9.00E-01 66.42 1.80 5.72
9.00E-01 18.07 1.80 5.72
9.00E-01 69.75 1.80 5.72
9.00E-01 56.11 1.80 5.72
9.00E-01 61.24 1.80 5.72 10000 1000
9.00E-01 50.68 1.80 5.72
9.00E-01 31.13 1.80 5.72
9.00E-01 21.67 1.80 5.72
9.00E-01 40.13 1.80 5.72
9.00E-01 52.91 1.80 5.72
9.00E-01 48.48 1.80 5.72
9.00E-01 32.48 1.80 5.72
9.00E-01 29.19 1.80 5.72
9.00E-01 46.32 1.80 5.72
9.00E-01 90.82 1.80 5.72
9.00E-01 54.99 1.80 5.72
9.00E-01 26.39 1.80 5.72
9.00E-01 11.97 1.80 5.72
9.00E-01 12.30 1.80 5.72
9.00E-01 47.25 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.25E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.89E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/11 4:59 PM EPA Interlab L09 1315 SWA
8/18/11 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/11 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/11 5:27 PM EPA Interlab L09 1315 SWA
8/18/11 5:28 PM EPA Interlab L09 1315 SWA
8/18/11 5:30 PM EPA Interlab L09 1315 SWA
8/18/11 5:32 PM EPA Interlab L09 1315 SWA
8/18/11 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/11 5:37 PM EPA Interlab L09 1315 SWA
8/18/11 5:38 PM EPA Interlab L09 1315 SWA
8/18/11 5:40 PM EPA Interlab L09 1315 SWA
8/18/11 5:42 PM EPA Interlab L09 1315 SWA
8/18/11 5:43 PM EPA Interlab L09 1315 SWA
8/18/11 5:45 PM EPA Interlab L09 1315 SWA
8/18/11 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/11 4:42 PM EPA Interlab L09 1315 SWA
8/18/11 4:44 PM EPA Interlab L09 1315 SWA
8/18/11 4:46 PM EPA Interlab L09 1315 SWA
8/18/11 4:47 PM EPA Interlab L09 1315 SWA
8/18/11 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/11 4:52 PM EPA Interlab L09 1315 SWA
1-622
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cu SWA-L09-1315-T01-A 1 1.85E+00 U1/2
Cu SWA-L09-1315-T02-A 1 1.85E+00 U1/2
Cu SWA-L09-1315-T03-A 1 1.85E+00 U1/2
Cu SWA-L09-1315-T04-A 1 1.85E+00 U1/2
Cu SWA-L09-1315-T05-A 1 1.85E+00 U1/2
Cu SWA-L09-1315-T06-A 1 1.85E+00 U1/2
Cu SWA-L09-1315-T07-A 1 1.85E+00 U1/2
Cu SWA-L09-1315-T08-A 1 1.85E+00 U1/2
Cu SWA-L09-1315-T09-A 1 1.85E+00 U1/2
Cu SWA-L09-1315-T01-B 1 1.85E+00 U1/2
Cu SWA-L09-1315-T02-B 1 1.85E+00 U1/2
Cu SWA-L09-1315-T03-B 1 1.85E+00 U1/2
Cu SWA-L09-1315-T04-B 1 1.85E+00 U1/2
Cu SWA-L09-1315-T05-B 1 1.85E+00 U1/2
Cu SWA-L09-1315-T06-B 1 1.85E+00 U1/2
Cu SWA-L09-1315-T07-B 1 1.85E+00 U1/2
Cu SWA-L09-1315-T08-B 1 1.85E+00 U1/2
Cu SWA-L09-1315-T09-B 1 1.85E+00 U1/2
Cu SWA-L09-1315-T01-C 1 1.85E+00 U1/2
Cu SWA-L09-1315-T02-C 1 1.85E+00 U1/2
Cu SWA-L09-1315-T03-C 1 1.85E+00 U1/2
Cu SWA-L09-1315-T04-C 1 1.85E+00 U1/2
Cu SWA-L09-1315-T05-C 1 1.85E+00 U1/2
Cu SWA-L09-1315-T06-C 1 1.85E+00 U1/2
Cu SWA-L09-1315-T07-C 1 1.85E+00 U1/2
Cu SWA-L09-1315-T08-C 1 1.85E+00 U1/2
Cu SWA-L09-1315-T09-C 1 1.85E+00 U1/2
Cu SWA-L09-1315-M01-A 1 1.85E+00 U1/2
Cu SWA-L09-1315-M02-A 1 1.85E+00 U1/2
Cu SWA-L09-1315-M03-A 1 1.85E+00 U1/2
Cu SWA-L09-1315-M04-A 1 1.85E+00 U1/2
Cu SWA-L09-1315-M05-A 1 1.85E+00 U1/2
Cu SWA-L09-1315-M06-A 1 1.85E+00 U1/2
Cu SWA-L09-1315-M07-A 1 1.85E+00 U1/2
Cu SWA-L09-1315-M08-A 1 1.85E+00 U1/2
Cu SWA-L09-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 51.48 3.70 11.80
1.85E+00 54.27 3.70 11.80
1.85E+00 6.16 3.70 11.80 10000 1000
1.85E+00 21.34 3.70 11.80
1.85E+00 36.79 3.70 11.80
1.85E+00 25.02 3.70 11.80
1.85E+00 24.86 3.70 11.80
1.85E+00 13.84 3.70 11.80
1.85E+00 17.76 3.70 11.80
1.85E+00 46.46 3.70 11.80
1.85E+00 22.72 3.70 11.80
1.85E+00 72.16 3.70 11.80 10000 1000
1.85E+00 50.55 3.70 11.80
1.85E+00 12.25 3.70 11.80
1.85E+00 49.51 3.70 11.80
1.85E+00 47.60 3.70 11.80
1.85E+00 36.31 3.70 11.80
1.85E+00 27.83 3.70 11.80
1.85E+00 10.09 3.70 11.80
1.85E+00 33.73 3.70 11.80
1.85E+00 42.10 3.70 11.80 10000 1000
1.85E+00 9.73 3.70 11.80
1.85E+00 34.43 3.70 11.80
1.85E+00 36.30 3.70 11.80
1.85E+00 12.64 3.70 11.80
1.85E+00 10.84 3.70 11.80
1.85E+00 32.85 3.70 11.80
1.85E+00 60.76 3.70 11.80
1.85E+00 36.52 3.70 11.80
1.85E+00 50.74 3.70 11.80
1.85E+00 78.48 3.70 11.80
1.85E+00 66.74 3.70 11.80
1.85E+00 68.08 3.70 11.80
1.85E+00 15.15 3.70 11.80
1.85E+00 26.65 3.70 11.80
1.85E+00 21.71 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.19E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.89E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/11 4:59 PM EPA Interlab L09 1315 SWA
8/18/11 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/11 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/11 5:27 PM EPA Interlab L09 1315 SWA
8/18/11 5:28 PM EPA Interlab L09 1315 SWA
8/18/11 5:30 PM EPA Interlab L09 1315 SWA
8/18/11 5:32 PM EPA Interlab L09 1315 SWA
8/18/11 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/11 5:37 PM EPA Interlab L09 1315 SWA
8/18/11 5:38 PM EPA Interlab L09 1315 SWA
8/18/11 5:40 PM EPA Interlab L09 1315 SWA
8/18/11 5:42 PM EPA Interlab L09 1315 SWA
8/18/11 5:43 PM EPA Interlab L09 1315 SWA
8/18/11 5:45 PM EPA Interlab L09 1315 SWA
8/18/11 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/11 4:42 PM EPA Interlab L09 1315 SWA
8/18/11 4:44 PM EPA Interlab L09 1315 SWA
8/18/11 4:46 PM EPA Interlab L09 1315 SWA
8/18/11 4:47 PM EPA Interlab L09 1315 SWA
8/18/11 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/11 4:52 PM EPA Interlab L09 1315 SWA
1-623
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Fe SWA-L09-1315-T01-A 1 1.81E+01
Fe SWA-L09-1315-T02-A 1 1.64E+01
Fe SWA-L09-1315-T03-A 1 1.02E+01
Fe SWA-L09-1315-T04-A 1 1.03E+01
Fe SWA-L09-1315-T05-A 1 9.22E+00
Fe SWA-L09-1315-T06-A 1 6.54E+00
Fe SWA-L09-1315-T07-A 1 6.62E+00
Fe SWA-L09-1315-T08-A 1 8.05E+00
Fe SWA-L09-1315-T09-A 1 1.24E+01
Fe SWA-L09-1315-T01-B 1 1.61E+01
Fe SWA-L09-1315-T02-B 1 1.60E+01
Fe SWA-L09-1315-T03-B 1 7.94E+00
Fe SWA-L09-1315-T04-B 1 8.60E+00
Fe SWA-L09-1315-T05-B 1 6.47E+00
Fe SWA-L09-1315-T06-B 1 6.52E+00
Fe SWA-L09-1315-T07-B 1 6.91E+00
Fe SWA-L09-1315-T08-B 1 6.85E+00
Fe SWA-L09-1315-T09-B 1 1.07E+01
Fe SWA-L09-1315-T01-C 1 2.36E+01
Fe SWA-L09-1315-T02-C 1 2.27E+01
Fe SWA-L09-1315-T03-C 1 1.17E+01
Fe SWA-L09-1315-T04-C 1 1.22E+01
Fe SWA-L09-1315-T05-C 1 1.16E+01
Fe SWA-L09-1315-T06-C 1 7.28E+00
Fe SWA-L09-1315-T07-C 1 7.68E+00
Fe SWA-L09-1315-T08-C 1 7.43E+00
Fe SWA-L09-1315-T09-C 1 9.91E+00
Fe SWA-L09-1315-M01-A 1 1.00E+00 U1/2
Fe SWA-L09-1315-M02-A 1 1.00E+00 U1/2
Fe SWA-L09-1315-M03-A 1 1.00E+00 U1/2
Fe SWA-L09-1315-M04-A 1 1.00E+00 U1/2
Fe SWA-L09-1315-M05-A 1 1.00E+00 U1/2
Fe SWA-L09-1315-M06-A 1 1.00E+00 U1/2
Fe SWA-L09-1315-M07-A 1 1.00E+00 U1/2
Fe SWA-L09-1315-M08-A 1 1.00E+00 U1/2
Fe SWA-L09-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.81E+01 2.05 2.00 6.40
1.64E+01 3.13 2.00 6.40
1.02E+01 1.41 2.00 6.40 10000 1000
1.03E+01 6.05 2.00 6.40
9.22E+00 2.57 2.00 6.40
6.54E+00 8.22 2.00 6.40
6.62E+00 8.77 2.00 6.40
8.05E+00 4.41 2.00 6.40
1.24E+01 3.05 2.00 6.40
1.61E+01 2.72 2.00 6.40
1.60E+01 1.57 2.00 6.40
7.94E+00 5.78 2.00 6.40 10000 1000
8.60E+00 4.72 2.00 6.40
6.47E+00 3.17 2.00 6.40
6.52E+00 4.61 2.00 6.40
6.91E+00 5.09 2.00 6.40
6.85E+00 3.64 2.00 6.40
1.07E+01 10.69 2.00 6.40
2.36E+01 2.44 2.00 6.40
2.27E+01 1.11 2.00 6.40
1.17E+01 4.44 2.00 6.40 10000 1000
1.22E+01 1.36 2.00 6.40
1.16E+01 3.33 2.00 6.40
7.28E+00 5.92 2.00 6.40
7.68E+00 1.17 2.00 6.40
7.43E+00 4.03 2.00 6.40
9.91E+00 2.35 2.00 6.40
1.00E+00 5.74 2.00 6.40
1.00E+00 1.12 2.00 6.40
1.00E+00 7.81 2.00 6.40
1.00E+00 1.98 2.00 6.40
1.00E+00 4.02 2.00 6.40
1.00E+00 1.45 2.00 6.40
1.00E+00 12.25 2.00 6.40
1.00E+00 18.38 2.00 6.40
1.00E+00 0.30 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.14E+03 113% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.21E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:59 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/11 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:27 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:28 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:30 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:32 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:37 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:38 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:40 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:43 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:45 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:44 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:46 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:47 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:52 PM EPA Interlab L09 1315 SWA
1-624
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Pb SWA-L09-1315-T01-A 1 3.40E+00 U1/2
Pb SWA-L09-1315-T02-A 1 3.40E+00 U1/2
Pb SWA-L09-1315-T03-A 1 3.40E+00 U1/2
Pb SWA-L09-1315-T04-A 1 3.40E+00 U1/2
Pb SWA-L09-1315-T05-A 1 3.40E+00 U1/2
Pb SWA-L09-1315-T06-A 1 3.40E+00 U1/2
Pb SWA-L09-1315-T07-A 1 3.40E+00 U1/2
Pb SWA-L09-1315-T08-A 1 3.40E+00 U1/2
Pb SWA-L09-1315-T09-A 1 3.40E+00 U1/2
Pb SWA-L09-1315-T01-B 1 3.40E+00 U1/2
Pb SWA-L09-1315-T02-B 1 3.40E+00 U1/2
Pb SWA-L09-1315-T03-B 1 3.40E+00 U1/2
Pb SWA-L09-1315-T04-B 1 3.40E+00 U1/2
Pb SWA-L09-1315-T05-B 1 3.40E+00 U1/2
Pb SWA-L09-1315-T06-B 1 3.40E+00 U1/2
Pb SWA-L09-1315-T07-B 1 3.40E+00 U1/2
Pb SWA-L09-1315-T08-B 1 3.40E+00 U1/2
Pb SWA-L09-1315-T09-B 1 3.40E+00 U1/2
Pb SWA-L09-1315-T01-C 1 3.40E+00 U1/2
Pb SWA-L09-1315-T02-C 1 3.40E+00 U1/2
Pb SWA-L09-1315-T03-C 1 3.40E+00 U1/2
Pb SWA-L09-1315-T04-C 1 3.40E+00 U1/2
Pb SWA-L09-1315-T05-C 1 3.40E+00 U1/2
Pb SWA-L09-1315-T06-C 1 3.40E+00 U1/2
Pb SWA-L09-1315-T07-C 1 3.40E+00 U1/2
Pb SWA-L09-1315-T08-C 1 3.40E+00 U1/2
Pb SWA-L09-1315-T09-C 1 3.40E+00 U1/2
Pb SWA-L09-1315-M01-A 1 3.40E+00 U1/2
Pb SWA-L09-1315-M02-A 1 3.40E+00 U1/2
Pb SWA-L09-1315-M03-A 1 3.40E+00 U1/2
Pb SWA-L09-1315-M04-A 1 3.40E+00 U1/2
Pb SWA-L09-1315-M05-A 1 3.40E+00 U1/2
Pb SWA-L09-1315-M06-A 1 3.40E+00 U1/2
Pb SWA-L09-1315-M07-A 1 3.40E+00 U1/2
Pb SWA-L09-1315-M08-A 1 3.40E+00 U1/2
Pb SWA-L09-1315-M09-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 51.60 6.80 21.60
3.40E+00 17.05 6.80 21.60
3.40E+00 39.93 6.80 21.60 10000 1000
3.40E+00 62.54 6.80 21.60
3.40E+00 50.42 6.80 21.60
3.40E+00 23.72 6.80 21.60
3.40E+00 19.18 6.80 21.60
3.40E+00 46.85 6.80 21.60
3.40E+00 33.53 6.80 21.60
3.40E+00 18.32 6.80 21.60
3.40E+00 48.25 6.80 21.60
3.40E+00 24.86 6.80 21.60 10000 1000
3.40E+00 59.76 6.80 21.60
3.40E+00 21.16 6.80 21.60
3.40E+00 38.50 6.80 21.60
3.40E+00 25.56 6.80 21.60
3.40E+00 47.97 6.80 21.60
3.40E+00 29.16 6.80 21.60
3.40E+00 25.70 6.80 21.60
3.40E+00 58.60 6.80 21.60
3.40E+00 7.98 6.80 21.60 10000 1000
3.40E+00 23.98 6.80 21.60
3.40E+00 34.82 6.80 21.60
3.40E+00 41.83 6.80 21.60
3.40E+00 35.60 6.80 21.60
3.40E+00 40.56 6.80 21.60
3.40E+00 44.90 6.80 21.60
3.40E+00 32.04 6.80 21.60
3.40E+00 47.42 6.80 21.60
3.40E+00 38.95 6.80 21.60
3.40E+00 27.70 6.80 21.60
3.40E+00 45.86 6.80 21.60
3.40E+00 54.82 6.80 21.60
3.40E+00 45.30 6.80 21.60
3.40E+00 1.54 6.80 21.60
3.40E+00 76.92 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.08E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.20E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.86E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/11 4:59 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/11 5:27 PM EPA Interlab L09 1315 SWA
8/18/11 5:28 PM EPA Interlab L09 1315 SWA
8/18/11 5:30 PM EPA Interlab L09 1315 SWA
8/18/11 5:32 PM EPA Interlab L09 1315 SWA
8/18/11 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/11 5:37 PM EPA Interlab L09 1315 SWA
8/18/11 5:38 PM EPA Interlab L09 1315 SWA
8/18/11 5:40 PM EPA Interlab L09 1315 SWA
8/18/11 5:42 PM EPA Interlab L09 1315 SWA
8/18/11 5:43 PM EPA Interlab L09 1315 SWA
8/18/11 5:45 PM EPA Interlab L09 1315 SWA
8/18/11 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/11 4:42 PM EPA Interlab L09 1315 SWA
8/18/11 4:44 PM EPA Interlab L09 1315 SWA
8/18/11 4:46 PM EPA Interlab L09 1315 SWA
8/18/11 4:47 PM EPA Interlab L09 1315 SWA
8/18/11 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/11 4:52 PM EPA Interlab L09 1315 SWA
1-625
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Li SWA-L09-1315-T01-A 1 9.50E-01 U1/2
Li SWA-L09-1315-T02-A 1 9.50E-01 U1/2
Li SWA-L09-1315-T03-A 1 9.50E-01 U1/2
Li SWA-L09-1315-T04-A 1 9.50E-01 U1/2
Li SWA-L09-1315-T05-A 1 9.50E-01 U1/2
Li SWA-L09-1315-T06-A 1 9.50E-01 U1/2
Li SWA-L09-1315-T07-A 1 9.50E-01 U1/2
Li SWA-L09-1315-T08-A 1 9.50E-01 U1/2
Li SWA-L09-1315-T09-A 1 9.50E-01 U1/2
Li SWA-L09-1315-T01-B 1 9.50E-01 U1/2
Li SWA-L09-1315-T02-B 1 9.50E-01 U1/2
Li SWA-L09-1315-T03-B 1 9.50E-01 U1/2
Li SWA-L09-1315-T04-B 1 9.50E-01 U1/2
Li SWA-L09-1315-T05-B 1 9.50E-01 U1/2
Li SWA-L09-1315-T06-B 1 9.50E-01 U1/2
Li SWA-L09-1315-T07-B 1 9.50E-01 U1/2
Li SWA-L09-1315-T08-B 1 9.50E-01 U1/2
Li SWA-L09-1315-T09-B 1 9.50E-01 U1/2
Li SWA-L09-1315-T01-C 1 9.50E-01 U1/2
Li SWA-L09-1315-T02-C 1 9.50E-01 U1/2
Li SWA-L09-1315-T03-C 1 9.50E-01 U1/2
Li SWA-L09-1315-T04-C 1 9.50E-01 U1/2
Li SWA-L09-1315-T05-C 1 9.50E-01 U1/2
Li SWA-L09-1315-T06-C 1 9.50E-01 U1/2
Li SWA-L09-1315-T07-C 1 9.50E-01 U1/2
Li SWA-L09-1315-T08-C 1 9.50E-01 U1/2
Li SWA-L09-1315-T09-C 1 9.50E-01 U1/2
Li SWA-L09-1315-M01-A 1 9.50E-01 U1/2
Li SWA-L09-1315-M02-A 1 9.50E-01 U1/2
Li SWA-L09-1315-M03-A 1 9.50E-01 U1/2
Li SWA-L09-1315-M04-A 1 9.50E-01 U1/2
Li SWA-L09-1315-M05-A 1 9.50E-01 U1/2
Li SWA-L09-1315-M06-A 1 9.50E-01 U1/2
Li SWA-L09-1315-M07-A 1 9.50E-01 U1/2
Li SWA-L09-1315-M08-A 1 9.50E-01 U1/2
Li SWA-L09-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 6.33 1.90 6.00
9.50E-01 33.53 1.90 6.00
9.50E-01 37.45 1.90 6.00 10000 1000
9.50E-01 24.51 1.90 6.00
9.50E-01 10.80 1.90 6.00
9.50E-01 69.69 1.90 6.00
9.50E-01 30.32 1.90 6.00
9.50E-01 15.39 1.90 6.00
9.50E-01 37.48 1.90 6.00
9.50E-01 4.07 1.90 6.00
9.50E-01 59.32 1.90 6.00
9.50E-01 24.77 1.90 6.00 10000 1000
9.50E-01 81.81 1.90 6.00
9.50E-01 60.17 1.90 6.00
9.50E-01 53.06 1.90 6.00
9.50E-01 88.23 1.90 6.00
9.50E-01 11.20 1.90 6.00
9.50E-01 13.08 1.90 6.00
9.50E-01 53.44 1.90 6.00
9.50E-01 28.04 1.90 6.00
9.50E-01 35.21 1.90 6.00 10000 1000
9.50E-01 71.07 1.90 6.00
9.50E-01 10.64 1.90 6.00
9.50E-01 13.64 1.90 6.00
9.50E-01 34.29 1.90 6.00
9.50E-01 17.03 1.90 6.00
9.50E-01 72.47 1.90 6.00
9.50E-01 25.53 1.90 6.00
9.50E-01 12.02 1.90 6.00
9.50E-01 54.17 1.90 6.00
9.50E-01 35.70 1.90 6.00
9.50E-01 51.39 1.90 6.00
9.50E-01 22.08 1.90 6.00
9.50E-01 7.64 1.90 6.00
9.50E-01 66.55 1.90 6.00
9.50E-01 33.74 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.78E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.75E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.26E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/11 4:59 PM EPA Interlab L09 1315 SWA
8/18/11 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/11 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/11 5:27 PM EPA Interlab L09 1315 SWA
8/18/11 5:28 PM EPA Interlab L09 1315 SWA
8/18/11 5:30 PM EPA Interlab L09 1315 SWA
8/18/11 5:32 PM EPA Interlab L09 1315 SWA
8/18/11 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/11 5:37 PM EPA Interlab L09 1315 SWA
8/18/11 5:38 PM EPA Interlab L09 1315 SWA
8/18/11 5:40 PM EPA Interlab L09 1315 SWA
8/18/11 5:42 PM EPA Interlab L09 1315 SWA
8/18/11 5:43 PM EPA Interlab L09 1315 SWA
8/18/11 5:45 PM EPA Interlab L09 1315 SWA
8/18/11 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/11 4:42 PM EPA Interlab L09 1315 SWA
8/18/11 4:44 PM EPA Interlab L09 1315 SWA
8/18/11 4:46 PM EPA Interlab L09 1315 SWA
8/18/11 4:47 PM EPA Interlab L09 1315 SWA
8/18/11 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/11 4:52 PM EPA Interlab L09 1315 SWA
1-626
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Mn SWA-L09-1315-T01-A 1 1.00E+00 U1/2
Mn SWA-L09-1315-T02-A 1 1.00E+00 U1/2
Mn SWA-L09-1315-T03-A 1 1.00E+00 U1/2
Mn SWA-L09-1315-T04-A 1 1.00E+00 U1/2
Mn SWA-L09-1315-T05-A 1 1.00E+00 U1/2
Mn SWA-L09-1315-T06-A 1 1.00E+00 U1/2
Mn SWA-L09-1315-T07-A 1 1.00E+00 U1/2
Mn SWA-L09-1315-T08-A 1 1.00E+00 U1/2
Mn SWA-L09-1315-T09-A 1 1.00E+00 U1/2
Mn SWA-L09-1315-T01-B 1 1.00E+00 U1/2
Mn SWA-L09-1315-T02-B 1 1.00E+00 U1/2
Mn SWA-L09-1315-T03-B 1 1.00E+00 U1/2
Mn SWA-L09-1315-T04-B 1 1.00E+00 U1/2
Mn SWA-L09-1315-T05-B 1 1.00E+00 U1/2
Mn SWA-L09-1315-T06-B 1 1.00E+00 U1/2
Mn SWA-L09-1315-T07-B 1 1.00E+00 U1/2
Mn SWA-L09-1315-T08-B 1 1.00E+00 U1/2
Mn SWA-L09-1315-T09-B 1 1.00E+00 U1/2
Mn SWA-L09-1315-T01-C 1 1.00E+00 U1/2
Mn SWA-L09-1315-T02-C 1 1.00E+00 U1/2
Mn SWA-L09-1315-T03-C 1 1.00E+00 U1/2
Mn SWA-L09-1315-T04-C 1 1.00E+00 U1/2
Mn SWA-L09-1315-T05-C 1 1.00E+00 U1/2
Mn SWA-L09-1315-T06-C 1 1.00E+00 U1/2
Mn SWA-L09-1315-T07-C 1 1.00E+00 U1/2
Mn SWA-L09-1315-T08-C 1 1.00E+00 U1/2
Mn SWA-L09-1315-T09-C 1 1.00E+00 U1/2
Mn SWA-L09-1315-M01-A 1 1.00E+00 U1/2
Mn SWA-L09-1315-M02-A 1 1.00E+00 U1/2
Mn SWA-L09-1315-M03-A 1 1.00E+00 U1/2
Mn SWA-L09-1315-M04-A 1 1.00E+00 U1/2
Mn SWA-L09-1315-M05-A 1 1.00E+00 U1/2
Mn SWA-L09-1315-M06-A 1 1.00E+00 U1/2
Mn SWA-L09-1315-M07-A 1 1.00E+00 U1/2
Mn SWA-L09-1315-M08-A 1 1.00E+00 U1/2
Mn SWA-L09-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 3.46 2.00 6.40
1.00E+00 4.66 2.00 6.40
1.00E+00 12.22 2.00 6.40 10000 1000
1.00E+00 8.38 2.00 6.40
1.00E+00 6.24 2.00 6.40
1.00E+00 12.29 2.00 6.40
1.00E+00 5.96 2.00 6.40
1.00E+00 6.15 2.00 6.40
1.00E+00 3.09 2.00 6.40
1.00E+00 3.41 2.00 6.40
1.00E+00 0.65 2.00 6.40
1.00E+00 30.99 2.00 6.40 10000 1000
1.00E+00 15.60 2.00 6.40
1.00E+00 8.67 2.00 6.40
1.00E+00 17.01 2.00 6.40
1.00E+00 25.52 2.00 6.40
1.00E+00 2.16 2.00 6.40
1.00E+00 5.61 2.00 6.40
1.00E+00 6.81 2.00 6.40
1.00E+00 7.40 2.00 6.40
1.00E+00 13.25 2.00 6.40 10000 1000
1.00E+00 16.84 2.00 6.40
1.00E+00 8.97 2.00 6.40
1.00E+00 7.14 2.00 6.40
1.00E+00 4.13 2.00 6.40
1.00E+00 16.21 2.00 6.40
1.00E+00 9.68 2.00 6.40
1.00E+00 14.54 2.00 6.40
1.00E+00 13.70 2.00 6.40
1.00E+00 10.00 2.00 6.40
1.00E+00 4.43 2.00 6.40
1.00E+00 11.15 2.00 6.40
1.00E+00 19.40 2.00 6.40
1.00E+00 18.87 2.00 6.40
1.00E+00 26.95 2.00 6.40
1.00E+00 6.46 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.10E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.44E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/11 4:59 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/11 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/11 5:27 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:28 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:30 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:32 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:37 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:38 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:40 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:43 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:45 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:44 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:46 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:47 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:52 PM EPA Interlab L09 1315 SWA
1-627
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Mg SWA-L09-1315-T01-A 1 2.69E+01
Mg SWA-L09-1315-T02-A 1 3.64E+01
Mg SWA-L09-1315-T03-A 1 4.79E+01
Mg SWA-L09-1315-T04-A 1 3.56E+01
Mg SWA-L09-1315-T05-A 1 2.71E+01
Mg SWA-L09-1315-T06-A 1 3.21E+01
Mg SWA-L09-1315-T07-A 1 3.08E+01
Mg SWA-L09-1315-T08-A 1 6.34E+01
Mg SWA-L09-1315-T09-A 1 4.22E+01
Mg SWA-L09-1315-T01-B 1 2.96E+01
Mg SWA-L09-1315-T02-B 1 3.31 E+01
Mg SWA-L09-1315-T03-B 1 5.04E+01
Mg SWA-L09-1315-T04-B 1 4.74E+01
Mg SWA-L09-1315-T05-B 1 3.33E+01
Mg SWA-L09-1315-T06-B 1 2.47E+01
Mg SWA-L09-1315-T07-B 1 3.71E+01
Mg SWA-L09-1315-T08-B 1 6.37E+01
Mg SWA-L09-1315-T09-B 1 4.61E+01
Mg SWA-L09-1315-T01-C 1 4.17E+01
Mg SWA-L09-1315-T02-C 1 4.07E+01
Mg SWA-L09-1315-T03-C 1 5.52E+01
Mg SWA-L09-1315-T04-C 1 3.97E+01
Mg SWA-L09-1315-T05-C 1 3.55E+01
Mg SWA-L09-1315-T06-C 1 2.72E+01
Mg SWA-L09-1315-T07-C 1 3.83E+01
Mg SWA-L09-1315-T08-C 1 6.68E+01
Mg SWA-L09-1315-T09-C 1 4.55E+01
Mg SWA-L09-1315-M01-A 1 1.41E+01
Mg SWA-L09-1315-M02-A 1 1.34E+01
Mg SWA-L09-1315-M03-A 1 2.60E+01
Mg SWA-L09-1315-M04-A 1 1.74E+01
Mg SWA-L09-1315-M05-A 1 2.55E+01
Mg SWA-L09-1315-M06-A 1 2.38E+01
Mg SWA-L09-1315-M07-A 1 2.79E+01
Mg SWA-L09-1315-M08-A 1 2.56E+01
Mg SWA-L09-1315-M09-A 1 2.64E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.69E+01 4.42 1.00 3.18
3.64E+01 3.94 1.00 3.18
4.79E+01 9.23 1.00 3.18 10000 1000
3.56E+01 1.11 1.00 3.18
2.71E+01 3.19 1.00 3.18
3.21E+01 2.61 1.00 3.18
3.08E+01 6.95 1.00 3.18
6.34E+01 7.40 1.00 3.18
4.22E+01 1.85 1.00 3.18
2.96E+01 1.90 1.00 3.18
3.31E+01 2.31 1.00 3.18
5.04E+01 1.22 1.00 3.18 10000 1000
4.74E+01 2.03 1.00 3.18
3.33E+01 1.39 1.00 3.18
2.47E+01 9.78 1.00 3.18
3.71E+01 1.32 1.00 3.18
6.37E+01 9.92 1.00 3.18
4.61E+01 1.67 1.00 3.18
4.17E+01 4.89 1.00 3.18
4.07E+01 13.33 1.00 3.18
5.52E+01 1.32 1.00 3.18 10000 1000
3.97E+01 9.59 1.00 3.18
3.55E+01 3.14 1.00 3.18
2.72E+01 1.92 1.00 3.18
3.83E+01 4.81 1.00 3.18
6.68E+01 5.47 1.00 3.18
4.55E+01 1.09 1.00 3.18
1.41E+01 7.18 1.00 3.18
1.34E+01 23.81 1.00 3.18
2.60E+01 3.00 1.00 3.18
1.74E+01 9.14 1.00 3.18
2.55E+01 1.35 1.00 3.18
2.38E+01 5.47 1.00 3.18
2.79E+01 11.96 1.00 3.18
2.56E+01 1.38 1.00 3.18
2.64E+01 2.50 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.15E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.61 E+02 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:59 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/11 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:27 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:28 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:30 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:32 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:37 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:38 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:40 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:43 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:45 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:44 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:46 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:47 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:52 PM EPA Interlab L09 1315 SWA
1-628
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Mo SWA-L09-1315-T01-A 1 5.20E+00
Mo SWA-L09-1315-T02-A 1 5.55E+00
Mo SWA-L09-1315-T03-A 1 5.83E+00
Mo SWA-L09-1315-T04-A 1 9.51E+00
Mo SWA-L09-1315-T05-A 1 8.25E+00
Mo SWA-L09-1315-T06-A 1 9.67E+00
Mo SWA-L09-1315-T07-A 1 7.45E+00
Mo SWA-L09-1315-T08-A 1 5.47E+00
Mo SWA-L09-1315-T09-A 1 6.49E+00
Mo SWA-L09-1315-T01-B 1 5.81 E+00
Mo SWA-L09-1315-T02-B 1 6.21E+00
Mo SWA-L09-1315-T03-B 1 4.81E+00
Mo SWA-L09-1315-T04-B 1 7.84E+00
Mo SWA-L09-1315-T05-B 1 7.76E+00
Mo SWA-L09-1315-T06-B 1 9.39E+00
Mo SWA-L09-1315-T07-B 1 7.30E+00
Mo SWA-L09-1315-T08-B 1 3.92E+00
Mo SWA-L09-1315-T09-B 1 6.44E+00
Mo SWA-L09-1315-T01-C 1 5.29E+00
Mo SWA-L09-1315-T02-C 1 5.97E+00
Mo SWA-L09-1315-T03-C 1 5.16E+00
Mo SWA-L09-1315-T04-C 1 8.68E+00
Mo SWA-L09-1315-T05-C 1 8.61E+00
Mo SWA-L09-1315-T06-C 1 9.63E+00
Mo SWA-L09-1315-T07-C 1 7.61E+00
Mo SWA-L09-1315-T08-C 1 4.52E+00
Mo SWA-L09-1315-T09-C 1 5.66E+00
Mo SWA-L09-1315-M01-A 1 6.00E-01 U1/2
Mo SWA-L09-1315-M02-A 1 6.00E-01 U1/2
Mo SWA-L09-1315-M03-A 1 6.00E-01 U1/2
Mo SWA-L09-1315-M04-A 1 6.00E-01 U1/2
Mo SWA-L09-1315-M05-A 1 6.00E-01 U1/2
Mo SWA-L09-1315-M06-A 1 6.00E-01 U1/2
Mo SWA-L09-1315-M07-A 1 6.00E-01 U1/2
Mo SWA-L09-1315-M08-A 1 6.00E-01 U1/2
Mo SWA-L09-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.20E+00 1.75 1.20 3.82
5.55E+00 7.33 1.20 3.82
5.83E+00 1.35 1.20 3.82 10000 1000
9.51E+00 1.50 1.20 3.82
8.25E+00 1.53 1.20 3.82
9.67E+00 4.26 1.20 3.82
7.45E+00 1.14 1.20 3.82
5.47E+00 8.95 1.20 3.82
6.49E+00 7.32 1.20 3.82
5.81E+00 12.68 1.20 3.82
6.21E+00 6.66 1.20 3.82
4.81E+00 1.58 1.20 3.82 10000 1000
7.84E+00 1.50 1.20 3.82
7.76E+00 6.12 1.20 3.82
9.39E+00 1.28 1.20 3.82
7.30E+00 1.49 1.20 3.82
3.92E+00 2.67 1.20 3.82
6.44E+00 1.16 1.20 3.82
5.29E+00 3.52 1.20 3.82
5.97E+00 7.95 1.20 3.82
5.16E+00 1.23 1.20 3.82 10000 1000
8.68E+00 2.16 1.20 3.82
8.61E+00 7.19 1.20 3.82
9.63E+00 8.22 1.20 3.82
7.61E+00 2.28 1.20 3.82
4.52E+00 1.91 1.20 3.82
5.66E+00 1.45 1.20 3.82
6.00E-01 22.43 1.20 3.82
6.00E-01 45.10 1.20 3.82
6.00E-01 12.42 1.20 3.82
6.00E-01 25.51 1.20 3.82
6.00E-01 7.17 1.20 3.82
6.00E-01 34.72 1.20 3.82
6.00E-01 5.43 1.20 3.82
6.00E-01 11.56 1.20 3.82
6.00E-01 46.44 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.08E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.44E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:59 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/11 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:27 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:28 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:30 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:32 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:37 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:38 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:40 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:43 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:45 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:44 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:46 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:47 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:52 PM EPA Interlab L09 1315 SWA
1-629
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ni SWA-L09-1315-T01-A 1 9.00E-01 U1/2
Ni SWA-L09-1315-T02-A 1 9.00E-01 U1/2
Ni SWA-L09-1315-T03-A 1 9.00E-01 U1/2
Ni SWA-L09-1315-T04-A 1 9.00E-01 U1/2
Ni SWA-L09-1315-T05-A 1 9.00E-01 U1/2
Ni SWA-L09-1315-T06-A 1 9.00E-01 U1/2
Ni SWA-L09-1315-T07-A 1 9.00E-01 U1/2
Ni SWA-L09-1315-T08-A 1 9.00E-01 U1/2
Ni SWA-L09-1315-T09-A 1 9.00E-01 U1/2
Ni SWA-L09-1315-T01-B 1 9.00E-01 U1/2
Ni SWA-L09-1315-T02-B 1 9.00E-01 U1/2
Ni SWA-L09-1315-T03-B 1 9.00E-01 U1/2
Ni SWA-L09-1315-T04-B 1 9.00E-01 U1/2
Ni SWA-L09-1315-T05-B 1 9.00E-01 U1/2
Ni SWA-L09-1315-T06-B 1 9.00E-01 U1/2
Ni SWA-L09-1315-T07-B 1 9.00E-01 U1/2
Ni SWA-L09-1315-T08-B 1 9.00E-01 U1/2
Ni SWA-L09-1315-T09-B 1 9.00E-01 U1/2
Ni SWA-L09-1315-T01-C 1 9.00E-01 U1/2
Ni SWA-L09-1315-T02-C 1 9.00E-01 U1/2
Ni SWA-L09-1315-T03-C 1 9.00E-01 U1/2
Ni SWA-L09-1315-T04-C 1 9.00E-01 U1/2
Ni SWA-L09-1315-T05-C 1 9.00E-01 U1/2
Ni SWA-L09-1315-T06-C 1 9.00E-01 U1/2
Ni SWA-L09-1315-T07-C 1 9.00E-01 U1/2
Ni SWA-L09-1315-T08-C 1 9.00E-01 U1/2
Ni SWA-L09-1315-T09-C 1 9.00E-01 U1/2
Ni SWA-L09-1315-M01-A 1 9.00E-01 U1/2
Ni SWA-L09-1315-M02-A 1 9.00E-01 U1/2
Ni SWA-L09-1315-M03-A 1 9.00E-01 U1/2
Ni SWA-L09-1315-M04-A 1 9.00E-01 U1/2
Ni SWA-L09-1315-M05-A 1 9.00E-01 U1/2
Ni SWA-L09-1315-M06-A 1 9.00E-01 U1/2
Ni SWA-L09-1315-M07-A 1 9.00E-01 U1/2
Ni SWA-L09-1315-M08-A 1 9.00E-01 U1/2
Ni SWA-L09-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 29.02 1.80 5.70
9.00E-01 13.37 1.80 5.70
9.00E-01 51.91 1.80 5.70 10000 1000
9.00E-01 47.55 1.80 5.70
9.00E-01 65.91 1.80 5.70
9.00E-01 28.91 1.80 5.70
9.00E-01 31.31 1.80 5.70
9.00E-01 13.92 1.80 5.70
9.00E-01 22.79 1.80 5.70
9.00E-01 54.65 1.80 5.70
9.00E-01 34.26 1.80 5.70
9.00E-01 64.65 1.80 5.70 10000 1000
9.00E-01 44.30 1.80 5.70
9.00E-01 23.30 1.80 5.70
9.00E-01 41.71 1.80 5.70
9.00E-01 34.12 1.80 5.70
9.00E-01 74.22 1.80 5.70
9.00E-01 63.37 1.80 5.70
9.00E-01 26.72 1.80 5.70
9.00E-01 57.53 1.80 5.70
9.00E-01 12.64 1.80 5.70 10000 1000
9.00E-01 22.16 1.80 5.70
9.00E-01 43.74 1.80 5.70
9.00E-01 54.31 1.80 5.70
9.00E-01 38.02 1.80 5.70
9.00E-01 41.41 1.80 5.70
9.00E-01 25.12 1.80 5.70
9.00E-01 23.37 1.80 5.70
9.00E-01 33.98 1.80 5.70
9.00E-01 19.61 1.80 5.70
9.00E-01 29.82 1.80 5.70
9.00E-01 24.79 1.80 5.70
9.00E-01 46.32 1.80 5.70
9.00E-01 44.76 1.80 5.70
9.00E-01 34.01 1.80 5.70
9.00E-01 62.53 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.08E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.20E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.86E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/11 4:59 PM EPA Interlab L09 1315 SWA
8/18/11 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/11 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/11 5:27 PM EPA Interlab L09 1315 SWA
8/18/11 5:28 PM EPA Interlab L09 1315 SWA
8/18/11 5:30 PM EPA Interlab L09 1315 SWA
8/18/11 5:32 PM EPA Interlab L09 1315 SWA
8/18/11 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/11 5:37 PM EPA Interlab L09 1315 SWA
8/18/11 5:38 PM EPA Interlab L09 1315 SWA
8/18/11 5:40 PM EPA Interlab L09 1315 SWA
8/18/11 5:42 PM EPA Interlab L09 1315 SWA
8/18/11 5:43 PM EPA Interlab L09 1315 SWA
8/18/11 5:45 PM EPA Interlab L09 1315 SWA
8/18/11 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/11 4:42 PM EPA Interlab L09 1315 SWA
8/18/11 4:44 PM EPA Interlab L09 1315 SWA
8/18/11 4:46 PM EPA Interlab L09 1315 SWA
8/18/11 4:47 PM EPA Interlab L09 1315 SWA
8/18/11 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/11 4:52 PM EPA Interlab L09 1315 SWA
1-630
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
P SWA-L09-1315-T01-A 1 1.63E+01
P SWA-L09-1315-T02-A 1 7.99E+00 E
P SWA-L09-1315-T03-A 1 9.59E+00 E
P SWA-L09-1315-T04-A 1 7.09E+00 E
P SWA-L09-1315-T05-A 1 1.39E+01
P SWA-L09-1315-T06-A 1 8.76E+00 E
P SWA-L09-1315-T07-A 1 3.80E+00 E
P SWA-L09-1315-T08-A 1 1.85E+00 U1/2
P SWA-L09-1315-T09-A 1 1.85E+00 U1/2
P SWA-L09-1315-T01-B 1 1.46E+01
P SWA-L09-1315-T02-B 1 7.25E+00 E
P SWA-L09-1315-T03-B 1 9.43E+00 E
P SWA-L09-1315-T04-B 1 8.49E+00 E
P SWA-L09-1315-T05-B 1 1.31E+01
P SWA-L09-1315-T06-B 1 7.24E+00 E
P SWA-L09-1315-T07-B 1 6.64E+00 E
P SWA-L09-1315-T08-B 1 1.85E+00 U1/2
P SWA-L09-1315-T09-B 1 1.85E+00 U1/2
P SWA-L09-1315-T01-C 1 1.58E+01
P SWA-L09-1315-T02-C 1 8.51E+00 E
P SWA-L09-1315-T03-C 1 6.41E+00 E
P SWA-L09-1315-T04-C 1 5.71E+00 E
P SWA-L09-1315-T05-C 1 1.36E+01
P SWA-L09-1315-T06-C 1 8.86E+00 E
P SWA-L09-1315-T07-C 1 3.82E+00 E
P SWA-L09-1315-T08-C 1 1.85E+00 U1/2
P SWA-L09-1315-T09-C 1 1.85E+00 U1/2
P SWA-L09-1315-M01-A 1 1.85E+00 U1/2
P SWA-L09-1315-M02-A 1 1.85E+00 U1/2
P SWA-L09-1315-M03-A 1 1.85E+00 U1/2
P SWA-L09-1315-M04-A 1 1.85E+00 U1/2
P SWA-L09-1315-M05-A 1 1.85E+00 U1/2
P SWA-L09-1315-M06-A 1 1.85E+00 U1/2
P SWA-L09-1315-M07-A 1 1.85E+00 U1/2
P SWA-L09-1315-M08-A 1 1.85E+00 U1/2
P SWA-L09-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.63E+01 6.89 3.70 11.80
7.99E+00 3.73 3.70 11.80
9.59E+00 5.07 3.70 11.80 10000 1000
7.09E+00 2.27 3.70 11.80
1.39E+01 9.03 3.70 11.80
8.76E+00 4.23 3.70 11.80
3.80E+00 12.85 3.70 11.80
1.85E+00 11.31 3.70 11.80
1.85E+00 15.14 3.70 11.80
1.46E+01 10.70 3.70 11.80
7.25E+00 14.73 3.70 11.80
9.43E+00 5.36 3.70 11.80 10000 1000
8.49E+00 5.53 3.70 11.80
1.31E+01 1.81 3.70 11.80
7.24E+00 5.93 3.70 11.80
6.64E+00 4.58 3.70 11.80
1.85E+00 8.54 3.70 11.80
1.85E+00 15.26 3.70 11.80
1.58E+01 2.04 3.70 11.80
8.51 E+00 1.55 3.70 11.80
6.41E+00 12.76 3.70 11.80 10000 1000
5.71 E+00 14.45 3.70 11.80
1.36E+01 3.25 3.70 11.80
8.86E+00 2.04 3.70 11.80
3.82E+00 3.72 3.70 11.80
1.85E+00 3.64 3.70 11.80
1.85E+00 17.65 3.70 11.80
1.85E+00 19.19 3.70 11.80
1.85E+00 27.78 3.70 11.80
1.85E+00 33.45 3.70 11.80
1.85E+00 10.29 3.70 11.80
1.85E+00 7.48 3.70 11.80
1.85E+00 2.45 3.70 11.80
1.85E+00 8.99 3.70 11.80
1.85E+00 4.40 3.70 11.80
1.85E+00 1.81 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.13E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.33E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/11 4:59 PM EPA Interlab L09 1315 SWA
8/18/11 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/11 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/11 5:27 PM EPA Interlab L09 1315 SWA
8/18/11 5:28 PM EPA Interlab L09 1315 SWA
8/18/11 5:30 PM EPA Interlab L09 1315 SWA
8/18/11 5:32 PM EPA Interlab L09 1315 SWA
8/18/11 5:33 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:35 PM EPA Interlab L09 1315 SWA
8/18/11 5:37 PM EPA Interlab L09 1315 SWA
8/18/11 5:38 PM EPA Interlab L09 1315 SWA
8/18/11 5:40 PM EPA Interlab L09 1315 SWA
8/18/11 5:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:43 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:45 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/11 4:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:44 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:46 PM EPA Interlab L09 1315 SWA
8/18/11 4:47 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/11 4:52 PM EPA Interlab L09 1315 SWA
1-631
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
K SWA-L09-1315-T01-A 1 7.65E+03
K SWA-L09-1315-T02-A 1 1.47E+04
K SWA-L09-1315-T03-A 1 1.50E+04
K SWA-L09-1315-T04-A 1 3.38E+04
K SWA-L09-1315-T05-A 1 2.93E+04
K SWA-L09-1315-T06-A 1 3.63E+04
K SWA-L09-1315-T07-A 1 2.59E+04
K SWA-L09-1315-T08-A 1 1.12E+04
K SWA-L09-1315-T09-A 1 1.72E+04
K SWA-L09-1315-T01-B 1 7.72E+03
K SWA-L09-1315-T02-B 1 1.80E+04
K SWA-L09-1315-T03-B 1 9.49E+03
K SWA-L09-1315-T04-B 1 2.71E+04
K SWA-L09-1315-T05-B 1 2.61E+04
K SWA-L09-1315-T06-B 1 3.08E+04
K SWA-L09-1315-T07-B 1 2.25E+04
K SWA-L09-1315-T08-B 1 9.78E+03
K SWA-L09-1315-T09-B 1 1.48E+04
K SWA-L09-1315-T01-C 1 8.02E+03
K SWA-L09-1315-T02-C 1 1.62E+04
K SWA-L09-1315-T03-C 1 1.17E+04
K SWA-L09-1315-T04-C 1 3.25E+04
K SWA-L09-1315-T05-C 1 2.73E+04
K SWA-L09-1315-T06-C 1 3.69E+04
K SWA-L09-1315-T07-C 1 2.29E+04
K SWA-L09-1315-T08-C 1 1.10E+04
K SWA-L09-1315-T09-C 1 1.75E+04
K SWA-L09-1315-M01-A 1 7.65E+00
K SWA-L09-1315-M02-A 1 4.61E+00 E
K SWA-L09-1315-M03-A 1 1.84E+00 E
K SWA-L09-1315-M04-A 1 3.87E+00 E
K SWA-L09-1315-M05-A 1 2.41E+00 E
K SWA-L09-1315-M06-A 1 2.62E+00 E
K SWA-L09-1315-M07-A 1 1.83E+00 E
K SWA-L09-1315-M08-A 1 2.11E+OOE
K SWA-L09-1315-M09-A 1 4.17E+00 E
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.65E+03 1.66 1.60 5.09
1.47E+04 1.96 1.60 5.09
1.50E+04 1.46 1.60 5.09 10000 1000
3.38E+04 2.21 1.60 5.09
2.93E+04 1.03 1.60 5.09
3.63E+04 2.11 1.60 5.09
2.59E+04 0.85 1.60 5.09
1.12E+04 0.54 1.60 5.09
1.72E+04 2.95 1.60 5.09
7.72E+03 0.71 1.60 5.09
1.80E+04 1.27 1.60 5.09
9.49E+03 1.80 1.60 5.09 10000 1000
2.71E+04 0.99 1.60 5.09
2.61E+04 1.79 1.60 5.09
3.08E+04 2.57 1.60 5.09
2.25E+04 1.24 1.60 5.09
9.78E+03 1.20 1.60 5.09
1.48E+04 0.87 1.60 5.09
8.02E+03 0.60 1.60 5.09
1.62E+04 1.01 1.60 5.09
1.17E+04 0.74 1.60 5.09 10000 1000
3.25E+04 2.62 1.60 5.09
2.73E+04 1.67 1.60 5.09
3.69E+04 0.45 1.60 5.09
2.29E+04 5.41 1.60 5.09
1.10E+04 1.59 1.60 5.09
1.75E+04 1.93 1.60 5.09
7.65E+00 4.25 1.60 5.09
4.61E+00 4.21 1.60 5.09
1.84E+00 4.62 1.60 5.09
3.87E+00 4.37 1.60 5.09
2.41E+00 9.05 1.60 5.09
2.62E+00 3.12 1.60 5.09
1.83E+00 4.84 1.60 5.09
2.11E+00 3.03 1.60 5.09
4.17E+00 1.62 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.58E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.26E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:59 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/11 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:27 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:28 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:30 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:32 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:37 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:38 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:40 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:43 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:45 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:42 PM EPA Interlab L09 1315 SWA
8/18/11 4:44 PM EPA Interlab L09 1315 SWA
8/18/11 4:46 PM EPA Interlab L09 1315 SWA
8/18/11 4:47 PM EPA Interlab L09 1315 SWA
8/18/11 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/11 4:52 PM EPA Interlab L09 1315 SWA
1-632
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Se SWA-L09-1315-T01-A 1 1.04E+03
Se SWA-L09-1315-T02-A 1 1.70E+03
Se SWA-L09-1315-T03-A 1 1.32E+03
Se SWA-L09-1315-T04-A 1 4.19E+03
Se SWA-L09-1315-T05-A 1 3.32E+03
Se SWA-L09-1315-T06-A 1 3.97E+03
Se SWA-L09-1315-T07-A 1 2.59E+03
Se SWA-L09-1315-T08-A 1 1.04E+03
Se SWA-L09-1315-T09-A 1 1.74E+03
Se SWA-L09-1315-T01-B 1 1.08E+03
Se SWA-L09-1315-T02-B 1 2.02E+03
Se SWA-L09-1315-T03-B 1 9.91E+02
Se SWA-L09-1315-T04-B 1 2.90E+03
Se SWA-L09-1315-T05-B 1 2.77E+03
Se SWA-L09-1315-T06-B 1 3.31E+03
Se SWA-L09-1315-T07-B 1 2.20E+03
Se SWA-L09-1315-T08-B 1 8.98E+02
Se SWA-L09-1315-T09-B 1 1.49E+03
Se SWA-L09-1315-T01-C 1 1.21E+03
Se SWA-L09-1315-T02-C 1 1.96E+03
Se SWA-L09-1315-T03-C 1 1.27E+03
Se SWA-L09-1315-T04-C 1 3.95E+03
Se SWA-L09-1315-T05-C 1 3.00E+03
Se SWA-L09-1315-T06-C 1 4.22E+03
Se SWA-L09-1315-T07-C 1 2.34E+03
Se SWA-L09-1315-T08-C 1 9.83E+02
Se SWA-L09-1315-T09-C 1 1.72E+03
Se SWA-L09-1315-M01-A 1 7.50E+00 U1/2
Se SWA-L09-1315-M02-A 1 7.50E+00 U1/2
Se SWA-L09-1315-M03-A 1 7.50E+00 U1/2
Se SWA-L09-1315-M04-A 1 7.50E+00 U1/2
Se SWA-L09-1315-M05-A 1 7.50E+00 U1/2
Se SWA-L09-1315-M06-A 1 7.50E+00 U1/2
Se SWA-L09-1315-M07-A 1 7.50E+00 U1/2
Se SWA-L09-1315-M08-A 1 7.50E+00 U1/2
Se SWA-L09-1315-M09-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.04E+03 1.55 15.00 47.70
1.70E+03 3.24 15.00 47.70
1.32E+03 1.94 15.00 47.70 10000 1000
4.19E+03 2.01 15.00 47.70
3.32E+03 0.60 15.00 47.70
3.97E+03 2.37 15.00 47.70
2.59E+03 1.55 15.00 47.70
1.04E+03 1.34 15.00 47.70
1.74E+03 2.80 15.00 47.70
1.08E+03 0.84 15.00 47.70
2.02E+03 1.79 15.00 47.70
9.91E+02 2.23 15.00 47.70 10000 1000
2.90E+03 1.47 15.00 47.70
2.77E+03 2.08 15.00 47.70
3.31E+03 3.26 15.00 47.70
2.20E+03 1.11 15.00 47.70
8.98E+02 0.94 15.00 47.70
1.49E+03 1.29 15.00 47.70
1.21E+03 1.25 15.00 47.70
1.96E+03 0.68 15.00 47.70
1.27E+03 1.21 15.00 47.70 10000 1000
3.95E+03 1.99 15.00 47.70
3.00E+03 1.26 15.00 47.70
4.22E+03 0.63 15.00 47.70
2.34E+03 2.27 15.00 47.70
9.83E+02 0.81 15.00 47.70
1.72E+03 2.73 15.00 47.70
7.50E+00 56.62 15.00 47.70
7.50E+00 20.19 15.00 47.70
7.50E+00 75.85 15.00 47.70
7.50E+00 64.17 15.00 47.70
7.50E+00 44.93 15.00 47.70
7.50E+00 40.98 15.00 47.70
7.50E+00 7.25 15.00 47.70
7.50E+00 51.72 15.00 47.70
7.50E+00 27.12 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.26E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.91E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.18E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:59 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/11 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:27 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:28 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:30 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:32 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:37 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:38 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:40 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:43 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:45 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:44 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:46 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:47 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:52 PM EPA Interlab L09 1315 SWA
1-633
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Si SWA-L09-1315-T01-A 1 6.53E+02
Si SWA-L09-1315-T02-A 1 1.91E+03
Si SWA-L09-1315-T03-A 1 2.63E+03
Si SWA-L09-1315-T04-A 1 5.75E+03
Si SWA-L09-1315-T05-A 1 5.94E+03
Si SWA-L09-1315-T06-A 1 7.74E+03
Si SWA-L09-1315-T07-A 1 7.11E+03
Si SWA-L09-1315-T08-A 1 5.44E+03
Si SWA-L09-1315-T09-A 1 6.88E+03
Si SWA-L09-1315-T01-B 1 6.72E+02
Si SWA-L09-1315-T02-B 1 2.21E+03
Si SWA-L09-1315-T03-B 1 1.92E+03
Si SWA-L09-1315-T04-B 1 5.45E+03
Si SWA-L09-1315-T05-B 1 6.29E+03
Si SWA-L09-1315-T06-B 1 7.58E+03
Si SWA-L09-1315-T07-B 1 6.95E+03
Si SWA-L09-1315-T08-B 1 5.48E+03
Si SWA-L09-1315-T09-B 1 6.60E+03
Si SWA-L09-1315-T01-C 1 8.16E+02
Si SWA-L09-1315-T02-C 1 2.08E+03
Si SWA-L09-1315-T03-C 1 2.09E+03
Si SWA-L09-1315-T04-C 1 5.74E+03
Si SWA-L09-1315-T05-C 1 5.87E+03
Si SWA-L09-1315-T06-C 1 8.02E+03
Si SWA-L09-1315-T07-C 1 6.97E+03
Si SWA-L09-1315-T08-C 1 5.43E+03
Si SWA-L09-1315-T09-C 1 7.10E+03
Si SWA-L09-1315-M01-A 1 5.50E-01 U1/2
Si SWA-L09-1315-M02-A 1 5.50E-01 U1/2
Si SWA-L09-1315-M03-A 1 5.50E-01 U1/2
Si SWA-L09-1315-M04-A 1 5.50E-01 U1/2
Si SWA-L09-1315-M05-A 1 5.50E-01 U1/2
Si SWA-L09-1315-M06-A 1 5.50E-01 U1/2
Si SWA-L09-1315-M07-A 1 5.50E-01 U1/2
Si SWA-L09-1315-M08-A 1 5.50E-01 U1/2
Si SWA-L09-1315-M09-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.53E+02 2.55 1.10 3.50
1.91E+03 2.40 1.10 3.50
2.63E+03 1.83 1.10 3.50 10000 1000
5.75E+03 2.61 1.10 3.50
5.94E+03 1.13 1.10 3.50
7.74E+03 1.54 1.10 3.50
7.11E+03 0.59 1.10 3.50
5.44E+03 1.51 1.10 3.50
6.88E+03 0.64 1.10 3.50
6.72E+02 0.94 1.10 3.50
2.21E+03 1.50 1.10 3.50
1.92E+03 2.01 1.10 3.50 10000 1000
5.45E+03 1.01 1.10 3.50
6.29E+03 1.76 1.10 3.50
7.58E+03 2.75 1.10 3.50
6.95E+03 1.03 1.10 3.50
5.48E+03 1.77 1.10 3.50
6.60E+03 0.28 1.10 3.50
8.16E+02 0.55 1.10 3.50
2.08E+03 1.31 1.10 3.50
2.09E+03 0.28 1.10 3.50 10000 1000
5.74E+03 2.22 1.10 3.50
5.87E+03 1.51 1.10 3.50
8.02E+03 0.52 1.10 3.50
6.97E+03 10.17 1.10 3.50
5.43E+03 1.01 1.10 3.50
7.10E+03 1.76 1.10 3.50
5.50E-01 7.39 1.10 3.50
5.50E-01 15.43 1.10 3.50
5.50E-01 21.58 1.10 3.50
5.50E-01 10.32 1.10 3.50
5.50E-01 14.37 1.10 3.50
5.50E-01 13.96 1.10 3.50
5.50E-01 4.29 1.10 3.50
5.50E-01 5.50 1.10 3.50
5.50E-01 2.45 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.59E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.80E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.03E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/11 4:59 PM EPA Interlab L09 1315 SWA
8/18/11 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/11 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/11 5:27 PM EPA Interlab L09 1315 SWA
8/18/11 5:28 PM EPA Interlab L09 1315 SWA
8/18/11 5:30 PM EPA Interlab L09 1315 SWA
8/18/11 5:32 PM EPA Interlab L09 1315 SWA
8/18/11 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/11 5:37 PM EPA Interlab L09 1315 SWA
8/18/11 5:38 PM EPA Interlab L09 1315 SWA
8/18/11 5:40 PM EPA Interlab L09 1315 SWA
8/18/11 5:42 PM EPA Interlab L09 1315 SWA
8/18/11 5:43 PM EPA Interlab L09 1315 SWA
8/18/11 5:45 PM EPA Interlab L09 1315 SWA
8/18/11 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/11 4:42 PM EPA Interlab L09 1315 SWA
8/18/11 4:44 PM EPA Interlab L09 1315 SWA
8/18/11 4:46 PM EPA Interlab L09 1315 SWA
8/18/11 4:47 PM EPA Interlab L09 1315 SWA
8/18/11 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/11 4:52 PM EPA Interlab L09 1315 SWA
1-634
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Na SWA-L09-1315-T01-A 1 3.39E+04
Na SWA-L09-1315-T02-A 1 5.99E+04
Na SWA-L09-1315-T03-A 1 6.08E+04
Na SWA-L09-1315-T04-A 1 1.18E+05
Na SWA-L09-1315-T05-A 1 1.08E+05
Na SWA-L09-1315-T06-A 1 1.29E+05
Na SWA-L09-1315-T07-A 1 9.76E+04
Na SWA-L09-1315-T08-A 1 4.74E+04
Na SWA-L09-1315-T09-A 1 7.10E+04
Na SWA-L09-1315-T01-B 1 3.39E+04
Na SWA-L09-1315-T02-B 1 6.95E+04
Na SWA-L09-1315-T03-B 1 3.82E+04
Na SWA-L09-1315-T04-B 1 9.70E+04
Na SWA-L09-1315-T05-B 1 9.52E+04
Na SWA-L09-1315-T06-B 1 1.10E+05
Na SWA-L09-1315-T07-B 1 8.66E+04
Na SWA-L09-1315-T08-B 1 4.22E+04
Na SWA-L09-1315-T09-B 1 6.33E+04
Na SWA-L09-1315-T01-C 1 3.60E+04
Na SWA-L09-1315-T02-C 1 6.62E+04
Na SWA-L09-1315-T03-C 1 4.72E+04
Na SWA-L09-1315-T04-C 1 1.15E+05
Na SWA-L09-1315-T05-C 1 9.98E+04
Na SWA-L09-1315-T06-C 1 1.27E+05
Na SWA-L09-1315-T07-C 1 8.89E+04
Na SWA-L09-1315-T08-C 1 4.79E+04
Na SWA-L09-1315-T09-C 1 7.34E+04
Na SWA-L09-1315-M01-A 1 3.37E+01
Na SWA-L09-1315-M02-A 1 1.83E+01
Na SWA-L09-1315-M03-A 1 2.13E+01
Na SWA-L09-1315-M04-A 1 1.18E+01
Na SWA-L09-1315-M05-A 1 9.54E+00
Na SWA-L09-1315-M06-A 1 2.08E+01
Na SWA-L09-1315-M07-A 1 1.44E+01
Na SWA-L09-1315-M08-A 1 2.20E+01
Na SWA-L09-1315-M09-A 1 2.60E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.39E+04 0.59 2.50 8.00
5.99E+04 0.48 2.50 8.00
6.08E+04 0.68 2.50 8.00 10000 1000
1.18E+05 0.17 2.50 8.00
1.08E+05 0.69 2.50 8.00
1.29E+05 0.24 2.50 8.00
9.76E+04 0.27 2.50 8.00
4.74E+04 0.07 2.50 8.00
7.10E+04 1.11 2.50 8.00
3.39E+04 0.73 2.50 8.00
6.95E+04 0.51 2.50 8.00
3.82E+04 0.66 2.50 8.00 10000 1000
9.70E+04 0.29 2.50 8.00
9.52E+04 0.22 2.50 8.00
1.10E+05 0.39 2.50 8.00
8.66E+04 0.48 2.50 8.00
4.22E+04 0.44 2.50 8.00
6.33E+04 0.89 2.50 8.00
3.60E+04 0.90 2.50 8.00
6.62E+04 0.48 2.50 8.00
4.72E+04 0.24 2.50 8.00 10000 1000
1.15E+05 0.79 2.50 8.00
9.98E+04 0.11 2.50 8.00
1.27E+05 0.32 2.50 8.00
8.89E+04 1.25 2.50 8.00
4.79E+04 1.07 2.50 8.00
7.34E+04 0.87 2.50 8.00
3.37E+01 2.83 2.50 8.00
1.83E+01 2.24 2.50 8.00
2.13E+01 0.63 2.50 8.00
1.18E+01 1.26 2.50 8.00
9.54E+00 4.86 2.50 8.00
2.08E+01 0.88 2.50 8.00
1.44E+01 1.89 2.50 8.00
2.20E+01 1.15 2.50 8.00
2.60E+01 1.53 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.17E+04 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.90E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.81 E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/11 4:59 PM EPA Interlab L09 1315 SWA
8/18/11 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/11 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/11 5:27 PM EPA Interlab L09 1315 SWA
8/18/11 5:28 PM EPA Interlab L09 1315 SWA
8/18/11 5:30 PM EPA Interlab L09 1315 SWA
8/18/11 5:32 PM EPA Interlab L09 1315 SWA
8/18/11 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/11 5:37 PM EPA Interlab L09 1315 SWA
8/18/11 5:38 PM EPA Interlab L09 1315 SWA
8/18/11 5:40 PM EPA Interlab L09 1315 SWA
8/18/11 5:42 PM EPA Interlab L09 1315 SWA
8/18/11 5:43 PM EPA Interlab L09 1315 SWA
8/18/11 5:45 PM EPA Interlab L09 1315 SWA
8/18/11 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/11 4:42 PM EPA Interlab L09 1315 SWA
8/18/11 4:44 PM EPA Interlab L09 1315 SWA
8/18/11 4:46 PM EPA Interlab L09 1315 SWA
8/18/11 4:47 PM EPA Interlab L09 1315 SWA
8/18/11 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/11 4:52 PM EPA Interlab L09 1315 SWA
1-635
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Sr SWA-L09-1315-T01-A 1 2.17E+01
Sr SWA-L09-1315-T02-A 1 7.00E+01
Sr SWA-L09-1315-T03-A 1 8.75E+01
Sr SWA-L09-1315-T04-A 1 1.50E+02
Sr SWA-L09-1315-T05-A 1 1.67E+02
Sr SWA-L09-1315-T06-A 1 2.06E+02
Sr SWA-L09-1315-T07-A 1 2.13E+02
Sr SWA-L09-1315-T08-A 1 1.72E+02
Sr SWA-L09-1315-T09-A 1 2.00E+02
Sr SWA-L09-1315-T01-B 1 2.22E+01
Sr SWA-L09-1315-T02-B 1 8.43E+01
Sr SWA-L09-1315-T03-B 1 8.58E+01
Sr SWA-L09-1315-T04-B 1 1.69E+02
Sr SWA-L09-1315-T05-B 1 1.93E+02
Sr SWA-L09-1315-T06-B 1 2.28E+02
Sr SWA-L09-1315-T07-B 1 2.30E+02
Sr SWA-L09-1315-T08-B 1 1.79E+02
Sr SWA-L09-1315-T09-B 1 2.09E+02
Sr SWA-L09-1315-T01-C 1 2.69E+01
Sr SWA-L09-1315-T02-C 1 7.36E+01
Sr SWA-L09-1315-T03-C 1 8.02E+01
Sr SWA-L09-1315-T04-C 1 1.56E+02
Sr SWA-L09-1315-T05-C 1 1.69E+02
Sr SWA-L09-1315-T06-C 1 2.24E+02
Sr SWA-L09-1315-T07-C 1 2.05E+02
Sr SWA-L09-1315-T08-C 1 1.70E+02
Sr SWA-L09-1315-T09-C 1 2.05E+02
Sr SWA-L09-1315-M01-A 1 5.00E-01 U1/2
Sr SWA-L09-1315-M02-A 1 5.00E-01 U1/2
Sr SWA-L09-1315-M03-A 1 5.00E-01 U1/2
Sr SWA-L09-1315-M04-A 1 5.00E-01 U1/2
Sr SWA-L09-1315-M05-A 1 5.00E-01 U1/2
Sr SWA-L09-1315-M06-A 1 5.00E-01 U1/2
Sr SWA-L09-1315-M07-A 1 5.00E-01 U1/2
Sr SWA-L09-1315-M08-A 1 5.00E-01 U1/2
Sr SWA-L09-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.17E+01 2.57 1.00 3.18
7.00E+01 1.03 1.00 3.18
8.75E+01 1.28 1.00 3.18 10000 1000
1.50E+02 1.57 1.00 3.18
1.67E+02 0.16 1.00 3.18
2.06E+02 2.33 1.00 3.18
2.13E+02 1.55 1.00 3.18
1.72E+02 0.55 1.00 3.18
2.00E+02 2.82 1.00 3.18
2.22E+01 0.18 1.00 3.18
8.43E+01 0.72 1.00 3.18
8.58E+01 2.33 1.00 3.18 10000 1000
1.69E+02 1.54 1.00 3.18
1.93E+02 2.08 1.00 3.18
2.28E+02 2.51 1.00 3.18
2.30E+02 1.41 1.00 3.18
1.79E+02 1.44 1.00 3.18
2.09E+02 1.10 1.00 3.18
2.69E+01 1.49 1.00 3.18
7.36E+01 3.11 1.00 3.18
8.02E+01 0.99 1.00 3.18 10000 1000
1.56E+02 1.38 1.00 3.18
1.69E+02 1.73 1.00 3.18
2.24E+02 0.95 1.00 3.18
2.05E+02 5.40 1.00 3.18
1.70E+02 1.84 1.00 3.18
2.05E+02 1.22 1.00 3.18
5.00E-01 13.11 1.00 3.18
5.00E-01 17.45 1.00 3.18
5.00E-01 6.25 1.00 3.18
5.00E-01 39.66 1.00 3.18
5.00E-01 32.95 1.00 3.18
5.00E-01 26.94 1.00 3.18
5.00E-01 28.63 1.00 3.18
5.00E-01 15.61 1.00 3.18
5.00E-01 20.78 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 .20E+03 1 1 1 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:59 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/11 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:27 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:28 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:30 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:32 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:37 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:38 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:40 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:43 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:45 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:44 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:46 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:47 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:52 PM EPA Interlab L09 1315 SWA
1-636
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
S SWA-L09-1315-T01-A 1 3.55E+03
S SWA-L09-1315-T02-A 1 5.84E+03
S SWA-L09-1315-T03-A 1 4.06E+03
S SWA-L09-1315-T04-A 1 1.33E+04
S SWA-L09-1315-T05-A 1 1.02E+04
S SWA-L09-1315-T06-A 1 1.21E+04
S SWA-L09-1315-T07-A 1 7.56E+03
S SWA-L09-1315-T08-A 1 3.35E+03
S SWA-L09-1315-T09-A 1 5.20E+03
S SWA-L09-1315-T01-B 1 3.60E+03
S SWA-L09-1315-T02-B 1 6.60E+03
S SWA-L09-1315-T03-B 1 3.27E+03
S SWA-L09-1315-T04-B 1 8.99E+03
S SWA-L09-1315-T05-B 1 8.41E+03
S SWA-L09-1315-T06-B 1 1.02E+04
S SWA-L09-1315-T07-B 1 6.75E+03
S SWA-L09-1315-T08-B 1 2.97E+03
S SWA-L09-1315-T09-B 1 4.62E+03
S SWA-L09-1315-T01-C 1 3.95E+03
S SWA-L09-1315-T02-C 1 6.39E+03
S SWA-L09-1315-T03-C 1 4.20E+03
S SWA-L09-1315-T04-C 1 1.18E+04
S SWA-L09-1315-T05-C 1 8.99E+03
S SWA-L09-1315-T06-C 1 1.24E+04
S SWA-L09-1315-T07-C 1 6.83E+03
S SWA-L09-1315-T08-C 1 3.21E+03
S SWA-L09-1315-T09-C 1 5.30E+03
S SWA-L09-1315-M01-A 1 2.33E+01
S SWA-L09-1315-M02-A 1 2.58E+01
S SWA-L09-1315-M03-A 1 3.30E+01
S SWA-L09-1315-M04-A 1 3.07E+01
S SWA-L09-1315-M05-A 1 1.84E+01 E
S SWA-L09-1315-M06-A 1 2.11E+01 E
S SWA-L09-1315-M07-A 1 1.58E+01 E
S SWA-L09-1315-M08-A 1 3.17E+01
S SWA-L09-1315-M09-A 1 2.99E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.55E+03 2.40 6.80 21.60
5.84E+03 2.58 6.80 21.60
4.06E+03 1.42 6.80 21.60 10000 1000
1.33E+04 2.26 6.80 21.60
1.02E+04 0.86 6.80 21.60
1.21E+04 2.03 6.80 21.60
7.56E+03 1.13 6.80 21.60
3.35E+03 0.57 6.80 21.60
5.20E+03 2.34 6.80 21.60
3.60E+03 2.66 6.80 21.60
6.60E+03 1.62 6.80 21.60
3.27E+03 1.24 6.80 21.60 10000 1000
8.99E+03 1.63 6.80 21.60
8.41E+03 1.67 6.80 21.60
1.02E+04 3.80 6.80 21.60
6.75E+03 1.64 6.80 21.60
2.97E+03 0.79 6.80 21.60
4.62E+03 0.67 6.80 21.60
3.95E+03 1.29 6.80 21.60
6.39E+03 1.86 6.80 21.60
4.20E+03 0.78 6.80 21.60 10000 1000
1.18E+04 1.42 6.80 21.60
8.99E+03 1.98 6.80 21.60
1.24E+04 0.93 6.80 21.60
6.83E+03 1.30 6.80 21.60
3.21E+03 1.45 6.80 21.60
5.30E+03 1.49 6.80 21.60
2.33E+01 4.93 6.80 21.60
2.58E+01 1.30 6.80 21.60
3.30E+01 9.54 6.80 21.60
3.07E+01 7.91 6.80 21.60
1.84E+01 12.48 6.80 21.60
2.11E+01 1.83 6.80 21.60
1.58E+01 12.84 6.80 21.60
3.17E+01 8.17 6.80 21.60
2.99E+01 7.63 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.02E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.14E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.13E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:59 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/11 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:27 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:28 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:30 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:32 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:37 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:38 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:40 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:43 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:45 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:44 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:46 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:47 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:52 PM EPA Interlab L09 1315 SWA
1-637
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Tl SWA-L09-1315-T01-A 1 2.30E+00 U1/2
Tl SWA-L09-1315-T02-A 1 2.30E+00 U1/2
Tl SWA-L09-1315-T03-A 1 2.30E+00 U1/2
Tl SWA-L09-1315-T04-A 1 2.30E+00 U1/2
Tl SWA-L09-1315-T05-A 1 2.30E+00 U1/2
Tl SWA-L09-1315-T06-A 1 2.30E+00 U1/2
Tl SWA-L09-1315-T07-A 1 2.30E+00 U1/2
Tl SWA-L09-1315-T08-A 1 2.30E+00 U1/2
Tl SWA-L09-1315-T09-A 1 2.30E+00 U1/2
Tl SWA-L09-1315-T01-B 1 2.30E+00 U1/2
Tl SWA-L09-1315-T02-B 1 2.30E+00 U1/2
Tl SWA-L09-1315-T03-B 1 2.30E+00 U1/2
Tl SWA-L09-1315-T04-B 1 2.30E+00 U1/2
Tl SWA-L09-1315-T05-B 1 2.30E+00 U1/2
Tl SWA-L09-1315-T06-B 1 2.30E+00 U1/2
Tl SWA-L09-1315-T07-B 1 2.30E+00 U1/2
Tl SWA-L09-1315-T08-B 1 2.30E+00 U1/2
Tl SWA-L09-1315-T09-B 1 2.30E+00 U1/2
Tl SWA-L09-1315-T01-C 1 2.30E+00 U1/2
Tl SWA-L09-1315-T02-C 1 2.30E+00 U1/2
Tl SWA-L09-1315-T03-C 1 2.30E+00 U1/2
Tl SWA-L09-1315-T04-C 1 2.30E+00 U1/2
Tl SWA-L09-1315-T05-C 1 2.30E+00 U1/2
Tl SWA-L09-1315-T06-C 1 2.30E+00 U1/2
Tl SWA-L09-1315-T07-C 1 2.30E+00 U1/2
Tl SWA-L09-1315-T08-C 1 2.30E+00 U1/2
Tl SWA-L09-1315-T09-C 1 2.30E+00 U1/2
Tl SWA-L09-1315-M01-A 1 2.30E+00 U1/2
Tl SWA-L09-1315-M02-A 1 2.30E+00 U1/2
Tl SWA-L09-1315-M03-A 1 2.30E+00 U1/2
Tl SWA-L09-1315-M04-A 1 2.30E+00 U1/2
Tl SWA-L09-1315-M05-A 1 2.30E+00 U1/2
Tl SWA-L09-1315-M06-A 1 2.30E+00 U1/2
Tl SWA-L09-1315-M07-A 1 2.30E+00 U1/2
Tl SWA-L09-1315-M08-A 1 2.30E+00 U1/2
Tl SWA-L09-1315-M09-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 36.92 4.60 14.60
2.30E+00 31.79 4.60 14.60
2.30E+00 40.61 4.60 14.60 10000 1000
2.30E+00 25.97 4.60 14.60
2.30E+00 68.71 4.60 14.60
2.30E+00 23.55 4.60 14.60
2.30E+00 11.49 4.60 14.60
2.30E+00 41.38 4.60 14.60
2.30E+00 47.03 4.60 14.60
2.30E+00 8.57 4.60 14.60
2.30E+00 36.28 4.60 14.60
2.30E+00 59.32 4.60 14.60 10000 1000
2.30E+00 42.48 4.60 14.60
2.30E+00 85.65 4.60 14.60
2.30E+00 27.73 4.60 14.60
2.30E+00 65.67 4.60 14.60
2.30E+00 52.14 4.60 14.60
2.30E+00 12.76 4.60 14.60
2.30E+00 36.41 4.60 14.60
2.30E+00 52.34 4.60 14.60
2.30E+00 25.12 4.60 14.60 10000 1000
2.30E+00 55.66 4.60 14.60
2.30E+00 14.59 4.60 14.60
2.30E+00 26.28 4.60 14.60
2.30E+00 16.51 4.60 14.60
2.30E+00 43.55 4.60 14.60
2.30E+00 33.00 4.60 14.60
2.30E+00 26.23 4.60 14.60
2.30E+00 52.15 4.60 14.60
2.30E+00 40.61 4.60 14.60
2.30E+00 45.24 4.60 14.60
2.30E+00 29.40 4.60 14.60
2.30E+00 50.70 4.60 14.60
2.30E+00 37.50 4.60 14.60
2.30E+00 21.41 4.60 14.60
2.30E+00 63.01 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.08E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.28E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.89E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/11 4:59 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/11 5:27 PM EPA Interlab L09 1315 SWA
8/18/11 5:28 PM EPA Interlab L09 1315 SWA
8/18/11 5:30 PM EPA Interlab L09 1315 SWA
8/18/11 5:32 PM EPA Interlab L09 1315 SWA
8/18/11 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/11 5:37 PM EPA Interlab L09 1315 SWA
8/18/11 5:38 PM EPA Interlab L09 1315 SWA
8/18/11 5:40 PM EPA Interlab L09 1315 SWA
8/18/11 5:42 PM EPA Interlab L09 1315 SWA
8/18/11 5:43 PM EPA Interlab L09 1315 SWA
8/18/11 5:45 PM EPA Interlab L09 1315 SWA
8/18/11 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/11 4:42 PM EPA Interlab L09 1315 SWA
8/18/11 4:44 PM EPA Interlab L09 1315 SWA
8/18/11 4:46 PM EPA Interlab L09 1315 SWA
8/18/11 4:47 PM EPA Interlab L09 1315 SWA
8/18/11 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/11 4:52 PM EPA Interlab L09 1315 SWA
1-638
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Ti SWA-L09-1315-T01-A 1 1.00E+00 U1/2
Ti SWA-L09-1315-T02-A 1 1.00E+00 U1/2
Ti SWA-L09-1315-T03-A 1 1.00E+00 U1/2
Ti SWA-L09-1315-T04-A 1 1.00E+00 U1/2
Ti SWA-L09-1315-T05-A 1 1.00E+00 U1/2
Ti SWA-L09-1315-T06-A 1 1.00E+00 U1/2
Ti SWA-L09-1315-T07-A 1 1.00E+00 U1/2
Ti SWA-L09-1315-T08-A 1 1.00E+00 U1/2
Ti SWA-L09-1315-T09-A 1 1.00E+00 U1/2
Ti SWA-L09-1315-T01-B 1 1.00E+00 U1/2
Ti SWA-L09-1315-T02-B 1 1.00E+00 U1/2
Ti SWA-L09-1315-T03-B 1 1.00E+00 U1/2
Ti SWA-L09-1315-T04-B 1 1.00E+00 U1/2
Ti SWA-L09-1315-T05-B 1 1.00E+00 U1/2
Ti SWA-L09-1315-T06-B 1 1.00E+00 U1/2
Ti SWA-L09-1315-T07-B 1 1.00E+00 U1/2
Ti SWA-L09-1315-T08-B 1 1.00E+00 U1/2
Ti SWA-L09-1315-T09-B 1 1.00E+00 U1/2
Ti SWA-L09-1315-T01-C 1 1.00E+00 U1/2
Ti SWA-L09-1315-T02-C 1 1.00E+00 U1/2
Ti SWA-L09-1315-T03-C 1 1.00E+00 U1/2
Ti SWA-L09-1315-T04-C 1 1.00E+00 U1/2
Ti SWA-L09-1315-T05-C 1 1.00E+00 U1/2
Ti SWA-L09-1315-T06-C 1 1.00E+00 U1/2
Ti SWA-L09-1315-T07-C 1 1.00E+00 U1/2
Ti SWA-L09-1315-T08-C 1 1.00E+00 U1/2
Ti SWA-L09-1315-T09-C 1 1.00E+00 U1/2
Ti SWA-L09-1315-M01-A 1 1.00E+00 U1/2
Ti SWA-L09-1315-M02-A 1 1.00E+00 U1/2
Ti SWA-L09-1315-M03-A 1 1.00E+00 U1/2
Ti SWA-L09-1315-M04-A 1 1.00E+00 U1/2
Ti SWA-L09-1315-M05-A 1 1.00E+00 U1/2
Ti SWA-L09-1315-M06-A 1 1.00E+00 U1/2
Ti SWA-L09-1315-M07-A 1 1.00E+00 U1/2
Ti SWA-L09-1315-M08-A 1 1.00E+00 U1/2
Ti SWA-L09-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 24.32 2.00 6.40
1.00E+00 22.50 2.00 6.40
1.00E+00 20.44 2.00 6.40 10000 1000
1.00E+00 22.07 2.00 6.40
1.00E+00 16.04 2.00 6.40
1.00E+00 61.53 2.00 6.40
1.00E+00 12.45 2.00 6.40
1.00E+00 12.04 2.00 6.40
1.00E+00 5.54 2.00 6.40
1.00E+00 6.85 2.00 6.40
1.00E+00 18.38 2.00 6.40
1.00E+00 27.00 2.00 6.40 10000 1000
1.00E+00 19.11 2.00 6.40
1.00E+00 5.74 2.00 6.40
1.00E+00 8.48 2.00 6.40
1.00E+00 5.34 2.00 6.40
1.00E+00 22.79 2.00 6.40
1.00E+00 23.51 2.00 6.40
1.00E+00 1.41 2.00 6.40
1.00E+00 9.18 2.00 6.40
1.00E+00 7.00 2.00 6.40 10000 1000
1.00E+00 18.31 2.00 6.40
1.00E+00 14.22 2.00 6.40
1.00E+00 16.85 2.00 6.40
1.00E+00 35.34 2.00 6.40
1.00E+00 15.66 2.00 6.40
1.00E+00 13.90 2.00 6.40
1.00E+00 46.10 2.00 6.40
1.00E+00 24.10 2.00 6.40
1.00E+00 28.71 2.00 6.40
1.00E+00 71.36 2.00 6.40
1.00E+00 38.82 2.00 6.40
1.00E+00 20.09 2.00 6.40
1.00E+00 23.94 2.00 6.40
1.00E+00 30.54 2.00 6.40
1.00E+00 4.49 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.12E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.39E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/11 4:59 PM EPA Interlab L09 1315 SWA
8/18/11 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/11 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/11 5:27 PM EPA Interlab L09 1315 SWA
8/18/11 5:28 PM EPA Interlab L09 1315 SWA
8/18/11 5:30 PM EPA Interlab L09 1315 SWA
8/18/11 5:32 PM EPA Interlab L09 1315 SWA
8/18/11 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/11 5:37 PM EPA Interlab L09 1315 SWA
8/18/11 5:38 PM EPA Interlab L09 1315 SWA
8/18/11 5:40 PM EPA Interlab L09 1315 SWA
8/18/11 5:42 PM EPA Interlab L09 1315 SWA
8/18/11 5:43 PM EPA Interlab L09 1315 SWA
8/18/11 5:45 PM EPA Interlab L09 1315 SWA
8/18/11 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/11 4:42 PM EPA Interlab L09 1315 SWA
8/18/11 4:44 PM EPA Interlab L09 1315 SWA
8/18/11 4:46 PM EPA Interlab L09 1315 SWA
8/18/11 4:47 PM EPA Interlab L09 1315 SWA
8/18/11 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/11 4:52 PM EPA Interlab L09 1315 SWA
1-639
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
V SWA-L09-1315-T01-A 1 5.11E+00
V SWA-L09-1315-T02-A 1 1.20E+01
V SWA-L09-1315-T03-A 1 9.12E+00
V SWA-L09-1315-T04-A 1 1.67E+01
V SWA-L09-1315-T05-A 1 1.52E+01
V SWA-L09-1315-T06-A 1 1.78E+01
V SWA-L09-1315-T07-A 1 1.46E+01
V SWA-L09-1315-T08-A 1 1.00E+01
V SWA-L09-1315-T09-A 1 1.30E+01
V SWA-L09-1315-T01-B 1 5.40E+00
V SWA-L09-1315-T02-B 1 1.31E+01
V SWA-L09-1315-T03-B 1 5.97E+00
V SWA-L09-1315-T04-B 1 1.35E+01
V SWA-L09-1315-T05-B 1 1.34E+01
V SWA-L09-1315-T06-B 1 1.63E+01
V SWA-L09-1315-T07-B 1 1.37E+01
V SWA-L09-1315-T08-B 1 8.91E+00
V SWA-L09-1315-T09-B 1 1.16E+01
V SWA-L09-1315-T01-C 1 6.33E+00
V SWA-L09-1315-T02-C 1 1.53E+01
V SWA-L09-1315-T03-C 1 7.57E+00
V SWA-L09-1315-T04-C 1 1.70E+01
V SWA-L09-1315-T05-C 1 1.35E+01
V SWA-L09-1315-T06-C 1 1.78E+01
V SWA-L09-1315-T07-C 1 1.37E+01
V SWA-L09-1315-T08-C 1 8.77E+00
V SWA-L09-1315-T09-C 1 1.26E+01
V SWA-L09-1315-M01-A 1 7.50E-01 U1/2
V SWA-L09-1315-M02-A 1 7.50E-01 U1/2
V SWA-L09-1315-M03-A 1 7.50E-01 U1/2
V SWA-L09-1315-M04-A 1 7.50E-01 U1/2
V SWA-L09-1315-M05-A 1 7.50E-01 U1/2
V SWA-L09-1315-M06-A 1 7.50E-01 U1/2
V SWA-L09-1315-M07-A 1 7.50E-01 U1/2
V SWA-L09-1315-M08-A 1 7.50E-01 U1/2
V SWA-L09-1315-M09-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.11E+00 7.54 1.50 4.77
1.20E+01 3.43 1.50 4.77
9.12E+00 6.37 1.50 4.77 10000 1000
1.67E+01 3.36 1.50 4.77
1.52E+01 1.58 1.50 4.77
1.78E+01 5.30 1.50 4.77
1.46E+01 4.56 1.50 4.77
1.00E+01 3.60 1.50 4.77
1.30E+01 4.94 1.50 4.77
5.40E+00 2.87 1.50 4.77
1.31E+01 1.58 1.50 4.77
5.97E+00 7.40 1.50 4.77 10000 1000
1.35E+01 5.21 1.50 4.77
1.34E+01 3.75 1.50 4.77
1.63E+01 5.19 1.50 4.77
1.37E+01 3.32 1.50 4.77
8.91E+00 3.26 1.50 4.77
1.16E+01 2.66 1.50 4.77
6.33E+00 10.32 1.50 4.77
1.53E+01 6.30 1.50 4.77
7.57E+00 4.44 1.50 4.77 10000 1000
1.70E+01 3.52 1.50 4.77
1.35E+01 5.55 1.50 4.77
1.78E+01 6.01 1.50 4.77
1.37E+01 3.15 1.50 4.77
8.77E+00 5.12 1.50 4.77
1.26E+01 2.72 1.50 4.77
7.50E-01 44.00 1.50 4.77
7.50E-01 26.98 1.50 4.77
7.50E-01 77.03 1.50 4.77
7.50E-01 36.97 1.50 4.77
7.50E-01 12.56 1.50 4.77
7.50E-01 44.42 1.50 4.77
7.50E-01 51.35 1.50 4.77
7.50E-01 29.24 1.50 4.77
7.50E-01 73.88 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.09E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.36E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:59 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/11 5:04 PM EPA Interlab L09 1315 SWA
8/18/11 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/11 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:27 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:28 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:30 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:32 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:37 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:38 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:40 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:43 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:45 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:42 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:44 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:46 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:47 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/1 1 4:52 PM EPA Interlab L09 1315 SWA
1-640
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Zn SWA-L09-1315-T01-A 1 1.00E+00 E
Zn SWA-L09-1315-T02-A 1 5.00E-01 U1/2
Zn SWA-L09-1315-T03-A 1 5.00E-01 U1/2
Zn SWA-L09-1315-T04-A 1 5.00E-01 U1/2
Zn SWA-L09-1315-T05-A 1 5.00E-01 U1/2
Zn SWA-L09-1315-T06-A 1 5.00E-01 U1/2
Zn SWA-L09-1315-T07-A 1 5.00E-01 U1/2
Zn SWA-L09-1315-T08-A 1 5.00E-01 U1/2
Zn SWA-L09-1315-T09-A 1 5.00E-01 U1/2
Zn SWA-L09-1315-T01-B 1 1.18E+00 E
Zn SWA-L09-1315-T02-B 1 5.00E-01 U1/2
Zn SWA-L09-1315-T03-B 1 5.00E-01 U1/2
Zn SWA-L09-1315-T04-B 1 5.00E-01 U1/2
Zn SWA-L09-1315-T05-B 1 5.00E-01 U1/2
Zn SWA-L09-1315-T06-B 1 5.00E-01 U1/2
Zn SWA-L09-1315-T07-B 1 5.00E-01 U1/2
Zn SWA-L09-1315-T08-B 1 5.00E-01 U1/2
Zn SWA-L09-1315-T09-B 1 5.00E-01 U1/2
Zn SWA-L09-1315-T01-C 1 1.31E+00 E
Zn SWA-L09-1315-T02-C 1 5.00E-01 U1/2
Zn SWA-L09-1315-T03-C 1 5.00E-01 U1/2
Zn SWA-L09-1315-T04-C 1 5.00E-01 U1/2
Zn SWA-L09-1315-T05-C 1 5.00E-01 U1/2
Zn SWA-L09-1315-T06-C 1 5.00E-01 U1/2
Zn SWA-L09-1315-T07-C 1 5.00E-01 U1/2
Zn SWA-L09-1315-T08-C 1 5.00E-01 U1/2
Zn SWA-L09-1315-T09-C 1 5.00E-01 U1/2
Zn SWA-L09-1315-M01-A 1 5.00E-01 U1/2
Zn SWA-L09-1315-M02-A 1 5.00E-01 U1/2
Zn SWA-L09-1315-M03-A 1 5.00E-01 U1/2
Zn SWA-L09-1315-M04-A 1 5.00E-01 U1/2
Zn SWA-L09-1315-M05-A 1 5.00E-01 U1/2
Zn SWA-L09-1315-M06-A 1 5.00E-01 U1/2
Zn SWA-L09-1315-M07-A 1 5.00E-01 U1/2
Zn SWA-L09-1315-M08-A 1 5.00E-01 U1/2
Zn SWA-L09-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 4.22 1.00 3.18
5.00E-01 14.20 1.00 3.18
5.00E-01 17.85 1.00 3.18 10000 1000
5.00E-01 16.45 1.00 3.18
5.00E-01 7.44 1.00 3.18
5.00E-01 28.45 1.00 3.18
5.00E-01 11.83 1.00 3.18
5.00E-01 22.44 1.00 3.18
5.00E-01 25.64 1.00 3.18
1.18E+00 15.24 1.00 3.18
5.00E-01 11.29 1.00 3.18
5.00E-01 23.99 1.00 3.18 10000 1000
5.00E-01 14.77 1.00 3.18
5.00E-01 17.96 1.00 3.18
5.00E-01 17.68 1.00 3.18
5.00E-01 18.38 1.00 3.18
5.00E-01 20.25 1.00 3.18
5.00E-01 19.03 1.00 3.18
1.31E+00 3.30 1.00 3.18
5.00E-01 11.48 1.00 3.18
5.00E-01 9.78 1.00 3.18 10000 1000
5.00E-01 10.64 1.00 3.18
5.00E-01 15.99 1.00 3.18
5.00E-01 14.07 1.00 3.18
5.00E-01 21.71 1.00 3.18
5.00E-01 10.08 1.00 3.18
5.00E-01 7.35 1.00 3.18
5.00E-01 23.97 1.00 3.18
5.00E-01 7.86 1.00 3.18
5.00E-01 5.01 1.00 3.18
5.00E-01 8.80 1.00 3.18
5.00E-01 22.17 1.00 3.18
5.00E-01 8.40 1.00 3.18
5.00E-01 22.82 1.00 3.18
5.00E-01 8.10 1.00 3.18
5.00E-01 3.63 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.14E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.32E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/18/11 4:54 PM EPA Interlab L09 1315 SWA
8/18/11 4:55 PM EPA Interlab L09 1315 SWA
8/18/11 4:57 PM EPA Interlab L09 1315 SWA
8/18/11 4:59 PM EPA Interlab L09 1315 SWA
8/18/11 5:00 PM EPA Interlab L09 1315 SWA
8/18/11 5:02 PM EPA Interlab L09 1315 SWA
8/18/11 5:04 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:05 PM EPA Interlab L09 1315 SWA
8/18/11 5:07 PM EPA Interlab L09 1315 SWA
8/18/11 5:17 PM EPA Interlab L09 1315 SWA
8/18/11 5:19 PM EPA Interlab L09 1315 SWA
8/18/1 1 5:20 PM EPA Interlab L09 1315 SWA
8/18/11 5:22 PM EPA Interlab L09 1315 SWA
8/18/11 5:23 PM EPA Interlab L09 1315 SWA
8/18/11 5:25 PM EPA Interlab L09 1315 SWA
8/18/11 5:27 PM EPA Interlab L09 1315 SWA
8/18/11 5:28 PM EPA Interlab L09 1315 SWA
8/18/11 5:30 PM EPA Interlab L09 1315 SWA
8/18/11 5:32 PM EPA Interlab L09 1315 SWA
8/18/11 5:33 PM EPA Interlab L09 1315 SWA
8/18/11 5:35 PM EPA Interlab L09 1315 SWA
8/18/11 5:37 PM EPA Interlab L09 1315 SWA
8/18/11 5:38 PM EPA Interlab L09 1315 SWA
8/18/11 5:40 PM EPA Interlab L09 1315 SWA
8/18/11 5:42 PM EPA Interlab L09 1315 SWA
8/18/11 5:43 PM EPA Interlab L09 1315 SWA
8/18/11 5:45 PM EPA Interlab L09 1315 SWA
8/18/11 4:39 PM EPA Interlab L09 1315 SWA
8/18/11 4:41 PM EPA Interlab L09 1315 SWA
8/18/11 4:42 PM EPA Interlab L09 1315 SWA
8/18/11 4:44 PM EPA Interlab L09 1315 SWA
8/18/11 4:46 PM EPA Interlab L09 1315 SWA
8/18/11 4:47 PM EPA Interlab L09 1315 SWA
8/18/11 4:49 PM EPA Interlab L09 1315 SWA
8/18/11 4:51 PM EPA Interlab L09 1315 SWA
8/18/11 4:52 PM EPA Interlab L09 1315 SWA
1-641
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1315:
Element Sample ID
Al SWA-L10-1315-T01-A
Al SWA-L10-1315-T02-A
Al SWA-L10-1315-T03-A
Al SWA-L10-1315-T04-A
Al SWA-L10-1315-T05-A
Al SWA-L10-1315-T06-A
Al SWA-L10-1315-T07-A
Al SWA-L10-1315-T08-A
Al SWA-L10-1315-T09-A
Al SWA-L10-1315-T01-B
Al SWA-L10-1315-T02-B
Al SWA-L10-1315-T03-B
Al SWA-L10-1315-T04-B
Al SWA-L10-1315-T05-B
Al SWA-L10-1315-T06-B
Al SWA-L10-1315-T07-B
Al SWA-L10-1315-T08-B
Al SWA-L10-1315-T09-B
Al SWA-L10-1315-T01-C
Al SWA-L10-1315-T02-C
Al SWA-L10-1315-T03-C
Al SWA-L10-1315-T04-C
Al SWA-L10-1315-T05-C
Al SWA-L10-1315-T06-C
Al SWA-L10-1315-T07-C
Al SWA-L10-1315-T08-C
Al SWA-L10-1315-T09-C
Al SWA-L10-1315-M01-A
Al SWA-L10-1315-M02-A
Al SWA-L10-1315-M03-A
Al SWA-L10-1315-M04-A
Al SWA-L10-1315-M05-A
Al SWA-L10-1315-M06-A
Al SWA-L10-1315-M07-A
Al SWA-L10-1315-M08-A
Al SWA-L10-1315-M09-A
Dilution Sample
Factor Cone. Quallf
I Mg/L
1 1.51E+03
1 2.42E+03
1 2.69E+03
1 5.73E+03
1 4.84E+03
1 5.63E+03
1 4.91 E+03
1 3.10E+03
1 3.94E+03
1 1.58E+03
1 2.98E+03
1 3.12E+03
1 6.62E+03
1 5.54E+03
1 6.13E+03
1 5.30E+03
1 3.30E+03
1 4.08E+03
1 1.49E+03
1 2.67E+03
1 3.31 E+03
1 7. 11 E+03
1 5.87E+03
1 6.39E+03
1 5.44E+03
1 3.37E+03
1 4.42E+03
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
er Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.51 E+03 1.29 1.00 3.18
2.42E+03 0.27 1.00 3.18
2.69E+03 0.32 1.00 3.18 10000 1000
5.73E+03 0.83 1.00 3.18
4.84E+03 0.54 1.00 3.18
5.63E+03 4.31 1.00 3.18
4.91E+03 0.58 1.00 3.18
3.10E+03 0.88 1.00 3.18
3.94E+03 0.41 1.00 3.18
1.58E+03 0.60 1.00 3.18
2.98E+03 0.80 1.00 3.18
3.12E+03 1.32 1.00 3.18 10000 1000
6.62E+03 0.67 1.00 3.18
5.54E+03 0.25 1.00 3.18
6.13E+03 0.49 1.00 3.18
5.30E+03 1.14 1.00 3.18
3.30E+03 0.41 1.00 3.18
4.08E+03 0.59 1.00 3.18
1.49E+03 0.32 1.00 3.18
2.67E+03 0.64 1.00 3.18
3.31E+03 0.79 1.00 3.18 10000 1000
7.11E+03 0.47 1.00 3.18
5.87E+03 0.73 1.00 3.18
6.39E+03 0.32 1.00 3.18
5.44E+03 0.63 1.00 3.18
3.37E+03 0.20 1.00 3.18
4.42E+03 3.97 1.00 3.18
5.00E-01 10.07 1.00 3.18
5.00E-01 1.51 1.00 3.18
5.00E-01 2.70 1.00 3.18
5.00E-01 10.99 1.00 3.18
5.00E-01 5.93 1.00 3.18
5.00E-01 8.46 1.00 3.18
5.00E-01 3.60 1.00 3.18
5.00E-01 3.82 1.00 3.18
5.00E-01 4.52 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.60E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.99E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.24E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26 PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36 PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39 PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315 SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-642
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Sb SWA-L10-1315-T01-A 1 2.01E+02
Sb SWA-L10-1315-T02-A 1 2.44E+02
Sb SWA-L10-1315-T03-A 1 2.71E+02
Sb SWA-L10-1315-T04-A 1 4.25E+02
Sb SWA-L10-1315-T05-A 1 3.24E+02
Sb SWA-L10-1315-T06-A 1 3.69E+02
Sb SWA-L10-1315-T07-A 1 3.12E+02
Sb SWA-L10-1315-T08-A 1 2.24E+02
Sb SWA-L10-1315-T09-A 1 2.55E+02
Sb SWA-L10-1315-T01-B 1 2.23E+02
Sb SWA-L10-1315-T02-B 1 2.42E+02
Sb SWA-L10-1315-T03-B 1 2.36E+02
Sb SWA-L10-1315-T04-B 1 5.03E+02
Sb SWA-L10-1315-T05-B 1 3.96E+02
Sb SWA-L10-1315-T06-B 1 4.26E+02
Sb SWA-L10-1315-T07-B 1 3.48E+02
Sb SWA-L10-1315-T08-B 1 2.28E+02
Sb SWA-L10-1315-T09-B 1 2.68E+02
Sb SWA-L10-1315-T01-C 1 2.00E+02
Sb SWA-L10-1315-T02-C 1 2.57E+02
Sb SWA-L10-1315-T03-C 1 3.15E+02
Sb SWA-L10-1315-T04-C 1 6.51E+02
Sb SWA-L10-1315-T05-C 1 4.77E+02
Sb SWA-L10-1315-T06-C 1 4.89E+02
Sb SWA-L10-1315-T07-C 1 3.96E+02
Sb SWA-L10-1315-T08-C 1 2.62E+02
Sb SWA-L10-1315-T09-C 1 3.08E+02
Sb SWA-L10-1315-M01-A 1 3.75E+00 U1/2
Sb SWA-L10-1315-M02-A 1 3.75E+00 U1/2
Sb SWA-L10-1315-M03-A 1 3.75E+00 U1/2
Sb SWA-L10-1315-M04-A 1 3.75E+00 U1/2
Sb SWA-L10-1315-M05-A 1 3.75E+00 U1/2
Sb SWA-L10-1315-M06-A 1 3.75E+00 U1/2
Sb SWA-L10-1315-M07-A 1 3.75E+00 U1/2
Sb SWA-L10-1315-M08-A 1 3.75E+00 U1/2
Sb SWA-L10-1315-M09-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.01 E+02 4.45 7.50 23.90
2.44E+02 2.27 7.50 23.90
2.71E+02 5.55 7.50 23.90 10000 1000
4.25E+02 1.06 7.50 23.90
3.24E+02 3.27 7.50 23.90
3.69E+02 3.06 7.50 23.90
3.12E+02 0.85 7.50 23.90
2.24E+02 3.09 7.50 23.90
2.55E+02 2.22 7.50 23.90
2.23E+02 2.28 7.50 23.90
2.42E+02 0.67 7.50 23.90
2.36E+02 2.62 7.50 23.90 10000 1000
5.03E+02 1.12 7.50 23.90
3.96E+02 3.22 7.50 23.90
4.26E+02 2.57 7.50 23.90
3.48E+02 1.58 7.50 23.90
2.28E+02 4.51 7.50 23.90
2.68E+02 3.09 7.50 23.90
2.00E+02 4.73 7.50 23.90
2.57E+02 1.92 7.50 23.90
3.15E+02 5.78 7.50 23.90 10000 1000
6.51E+02 0.41 7.50 23.90
4.77E+02 3.84 7.50 23.90
4.89E+02 1.77 7.50 23.90
3.96E+02 1.69 7.50 23.90
2.62E+02 2.55 7.50 23.90
3.08E+02 3.35 7.50 23.90
3.75E+00 39.60 7.50 23.90
3.75E+00 16.52 7.50 23.90
3.75E+00 36.86 7.50 23.90
3.75E+00 10.80 7.50 23.90
3.75E+00 16.24 7.50 23.90
3.75E+00 53.31 7.50 23.90
3.75E+00 48.15 7.50 23.90
3.75E+00 13.79 7.50 23.90
3.75E+00 10.52 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.15E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36 PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315 SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-643
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
As SWA-L10-1315-T01-A 1 1.47E+02
As SWA-L10-1315-T02-A 1 9.54E+01
As SWA-L10-1315-T03-A 1 1.48E+02
As SWA-L10-1315-T04-A 1 2.88E+02
As SWA-L10-1315-T05-A 1 2.34E+02
As SWA-L10-1315-T06-A 1 1.94E+02
As SWA-L10-1315-T07-A 1 1.63E+02
As SWA-L10-1315-T08-A 1 1.05E+02
As SWA-L10-1315-T09-A 1 1.17E+02
As SWA-L10-1315-T01-B 1 1.90E+02
As SWA-L10-1315-T02-B 1 1.08E+02
As SWA-L10-1315-T03-B 1 1.30E+02
As SWA-L10-1315-T04-B 1 2.50E+02
As SWA-L10-1315-T05-B 1 1.95E+02
As SWA-L10-1315-T06-B 1 1.96E+02
As SWA-L10-1315-T07-B 1 1.60E+02
As SWA-L10-1315-T08-B 1 9.34E+01
As SWA-L10-1315-T09-B 1 1.22E+02
As SWA-L10-1315-T01-C 1 1.20E+02
As SWA-L10-1315-T02-C 1 1.54E+02
As SWA-L10-1315-T03-C 1 2.63E+02
As SWA-L10-1315-T04-C 1 4.13E+02
As SWA-L10-1315-T05-C 1 2.67E+02
As SWA-L10-1315-T06-C 1 2.46E+02
As SWA-L10-1315-T07-C 1 1.76E+02
As SWA-L10-1315-T08-C 1 1.06E+02
As SWA-L10-1315-T09-C 1 1.31E+02
As SWA-L10-1315-M01-A 1 5.50E+00 U1/2
As SWA-L10-1315-M02-A 1 5.50E+00 U1/2
As SWA-L10-1315-M03-A 1 5.50E+00 U1/2
As SWA-L10-1315-M04-A 1 5.50E+00 U1/2
As SWA-L10-1315-M05-A 1 5.50E+00 U1/2
As SWA-L10-1315-M06-A 1 5.50E+00 U1/2
As SWA-L10-1315-M07-A 1 5.50E+00 U1/2
As SWA-L10-1315-M08-A 1 5.50E+00 U1/2
As SWA-L10-1315-M09-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.47E+02 2.93 11.00 35.00
9.54E+01 6.20 11.00 35.00
1.48E+02 5.38 11.00 35.00 10000 1000
2.88E+02 2.19 11.00 35.00
2.34E+02 4.24 11.00 35.00
1.94E+02 4.37 11.00 35.00
1.63E+02 2.33 11.00 35.00
1.05E+02 10.76 11.00 35.00
1.17E+02 6.03 11.00 35.00
1.90E+02 1.74 11.00 35.00
1.08E+02 3.84 11.00 35.00
1.30E+02 8.57 11.00 35.00 10000 1000
2.50E+02 3.13 11.00 35.00
1.95E+02 4.43 11.00 35.00
1.96E+02 3.45 11.00 35.00
1.60E+02 4.33 11.00 35.00
9.34E+01 9.50 11.00 35.00
1.22E+02 4.00 11.00 35.00
1.20E+02 5.88 11.00 35.00
1.54E+02 4.91 11.00 35.00
2.63E+02 1.26 11.00 35.00 10000 1000
4.13E+02 0.59 11.00 35.00
2.67E+02 1.29 11.00 35.00
2.46E+02 1.69 11.00 35.00
1.76E+02 5.97 11.00 35.00
1.06E+02 7.75 11.00 35.00
1.31E+02 2.97 11.00 35.00
5.50E+00 35.10 11.00 35.00
5.50E+00 27.43 11.00 35.00
5.50E+00 79.07 11.00 35.00
5.50E+00 58.32 11.00 35.00
5.50E+00 83.20 11.00 35.00
5.50E+00 20.94 11.00 35.00
5.50E+00 47.64 11.00 35.00
5.50E+00 56.34 11.00 35.00
5.50E+00 15.41 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.77E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36 PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315 SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-644
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
B SWA-L10-1315-T01-A 1 3.52E+01
B SWA-L10-1315-T02-A 1 3.33E+01
B SWA-L10-1315-T03-A 1 4.30E+01
B SWA-L10-1315-T04-A 1 7.28E+01
B SWA-L10-1315-T05-A 1 6.10E+01
B SWA-L10-1315-T06-A 1 7.25E+01
B SWA-L10-1315-T07-A 1 6.86E+01
B SWA-L10-1315-T08-A 1 5.15E+01
B SWA-L10-1315-T09-A 1 5.54E+01
B SWA-L10-1315-T01-B 1 3.24E+01
B SWA-L10-1315-T02-B 1 3.95E+01
B SWA-L10-1315-T03-B 1 4.56E+01
B SWA-L10-1315-T04-B 1 9.28E+01
B SWA-L10-1315-T05-B 1 7.32E+01
B SWA-L10-1315-T06-B 1 8.89E+01
B SWA-L10-1315-T07-B 1 7.87E+01
B SWA-L10-1315-T08-B 1 5.57E+01
B SWA-L10-1315-T09-B 1 6.45E+01
B SWA-L10-1315-T01-C 1 3.05E+01
B SWA-L10-1315-T02-C 1 3.31E+01
B SWA-L10-1315-T03-C 1 4.28E+01
B SWA-L10-1315-T04-C 1 8.39E+01
B SWA-L10-1315-T05-C 1 6.74E+01
B SWA-L10-1315-T06-C 1 7.70E+01
B SWA-L10-1315-T07-C 1 6.98E+01
B SWA-L10-1315-T08-C 1 5.30E+01
B SWA-L10-1315-T09-C 1 6.10E+01
B SWA-L10-1315-M01-A 1 5.00E-01 U1/2
B SWA-L10-1315-M02-A 1 5.00E-01 U1/2
B SWA-L10-1315-M03-A 1 5.00E-01 U1/2
B SWA-L10-1315-M04-A 1 5.00E-01 U1/2
B SWA-L10-1315-M05-A 1 5.00E-01 U1/2
B SWA-L10-1315-M06-A 1 5.00E-01 U1/2
B SWA-L10-1315-M07-A 1 5.00E-01 U1/2
B SWA-L10-1315-M08-A 1 5.00E-01 U1/2
B SWA-L10-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.52E+01 6.58 1.00 3.18
3.33E+01 4.40 1.00 3.18
4.30E+01 0.86 1.00 3.18 10000 1000
7.28E+01 3.05 1.00 3.18
6.10E+01 1.14 1.00 3.18
7.25E+01 2.25 1.00 3.18
6.86E+01 2.14 1.00 3.18
5.15E+01 0.64 1.00 3.18
5.54E+01 4.12 1.00 3.18
3.24E+01 4.64 1.00 3.18
3.95E+01 4.02 1.00 3.18
4.56E+01 3.79 1.00 3.18 10000 1000
9.28E+01 0.30 1.00 3.18
7.32E+01 0.77 1.00 3.18
8.89E+01 3.00 1.00 3.18
7.87E+01 3.52 1.00 3.18
5.57E+01 2.57 1.00 3.18
6.45E+01 1.44 1.00 3.18
3.05E+01 7.33 1.00 3.18
3.31E+01 5.16 1.00 3.18
4.28E+01 5.03 1.00 3.18 10000 1000
8.39E+01 2.91 1.00 3.18
6.74E+01 5.09 1.00 3.18
7.70E+01 1.75 1.00 3.18
6.98E+01 0.44 1.00 3.18
5.30E+01 1.82 1.00 3.18
6.10E+01 3.70 1.00 3.18
5.00E-01 2.33 1.00 3.18
5.00E-01 4.25 1.00 3.18
5.00E-01 2.83 1.00 3.18
5.00E-01 2.24 1.00 3.18
5.00E-01 3.08 1.00 3.18
5.00E-01 2.50 1.00 3.18
5.00E-01 2.54 1.00 3.18
5.00E-01 2.16 1.00 3.18
5.00E-01 4.96 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.99E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.92E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.62E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36 PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39 PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315 SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-645
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ba SWA-L10-1315-T01-A 1 1.86E+01
Ba SWA-L10-1315-T02-A 1 8.61E+01
Ba SWA-L10-1315-T03-A 1 1.58E+02
Ba SWA-L10-1315-T04-A 1 3.13E+02
Ba SWA-L10-1315-T05-A 1 3.50E+02
Ba SWA-L10-1315-T06-A 1 3.78E+02
Ba SWA-L10-1315-T07-A 1 4.12E+02
Ba SWA-L10-1315-T08-A 1 3.67E+02
Ba SWA-L10-1315-T09-A 1 3.34E+02
Ba SWA-L10-1315-T01-B 1 2.30E+01
Ba SWA-L10-1315-T02-B 1 1.30E+02
Ba SWA-L10-1315-T03-B 1 1.73E+02
Ba SWA-L10-1315-T04-B 1 2.91E+02
Ba SWA-L10-1315-T05-B 1 3.26E+02
Ba SWA-L10-1315-T06-B 1 3.74E+02
Ba SWA-L10-1315-T07-B 1 4.26E+02
Ba SWA-L10-1315-T08-B 1 4.10E+02
Ba SWA-L10-1315-T09-B 1 3.90E+02
Ba SWA-L10-1315-T01-C 1 6.96E+01
Ba SWA-L10-1315-T02-C 1 3.18E+02
Ba SWA-L10-1315-T03-C 1 2.08E+02
Ba SWA-L10-1315-T04-C 1 2.97E+02
Ba SWA-L10-1315-T05-C 1 3.46E+02
Ba SWA-L10-1315-T06-C 1 3.99E+02
Ba SWA-L10-1315-T07-C 1 4.30E+02
Ba SWA-L10-1315-T08-C 1 4.21E+02
Ba SWA-L10-1315-T09-C 1 4.11E+02
Ba SWA-L10-1315-M01-A 1 5.00E-01 U1/2
Ba SWA-L10-1315-M02-A 1 5.00E-01 U1/2
Ba SWA-L10-1315-M03-A 1 5.00E-01 U1/2
Ba SWA-L10-1315-M04-A 1 5.00E-01 U1/2
Ba SWA-L10-1315-M05-A 1 5.00E-01 U1/2
Ba SWA-L10-1315-M06-A 1 5.00E-01 U1/2
Ba SWA-L10-1315-M07-A 1 5.00E-01 U1/2
Ba SWA-L10-1315-M08-A 1 5.00E-01 U1/2
Ba SWA-L10-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.86E+01 0.78 1.00 3.18
8.61E+01 0.40 1.00 3.18
1.58E+02 0.54 1.00 3.18 10000 1000
3.13E+02 0.50 1.00 3.18
3.50E+02 0.56 1.00 3.18
3.78E+02 3.94 1.00 3.18
4.12E+02 0.57 1.00 3.18
3.67E+02 0.39 1.00 3.18
3.34E+02 0.21 1.00 3.18
2.30E+01 0.53 1.00 3.18
1.30E+02 0.63 1.00 3.18
1.73E+02 0.68 1.00 3.18 10000 1000
2.91E+02 0.68 1.00 3.18
3.26E+02 0.11 1.00 3.18
3.74E+02 0.59 1.00 3.18
4.26E+02 1.53 1.00 3.18
4.10E+02 0.92 1.00 3.18
3.90E+02 0.14 1.00 3.18
6.96E+01 1.03 1.00 3.18
3.18E+02 1.08 1.00 3.18
2.08E+02 0.53 1.00 3.18 10000 1000
2.97E+02 0.86 1.00 3.18
3.46E+02 0.90 1.00 3.18
3.99E+02 0.51 1.00 3.18
4.30E+02 0.91 1.00 3.18
4.21E+02 1.77 1.00 3.18
4.11E+02 3.53 1.00 3.18
5.00E-01 2.37 1.00 3.18
5.00E-01 21.54 1.00 3.18
5.00E-01 19.28 1.00 3.18
5.00E-01 24.19 1.00 3.18
5.00E-01 31.45 1.00 3.18
5.00E-01 7.35 1.00 3.18
5.00E-01 1.41 1.00 3.18
5.00E-01 5.69 1.00 3.18
5.00E-01 2.38 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.07E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.23E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36 PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39 PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315 SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-646
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L I
Be SWA-L10-1315-T01-A 1 9.50E-01 U1/2
Be SWA-L10-1315-T02-A 1 9.50E-01 U1/2
Be SWA-L10-1315-T03-A 1 9.50E-01 U1/2
Be SWA-L10-1315-T04-A 1 9.50E-01 U1/2
Be SWA-L10-1315-T05-A 1 9.50E-01 U1/2
Be SWA-L10-1315-T06-A 1 9.50E-01 U1/2
Be SWA-L10-1315-T07-A 1 9.50E-01 U1/2
Be SWA-L10-1315-T08-A 1 9.50E-01 U1/2
Be SWA-L10-1315-T09-A 1 9.50E-01 U1/2
Be SWA-L10-1315-T01-B 1 9.50E-01 U1/2
Be SWA-L10-1315-T02-B 1 9.50E-01 U1/2
Be SWA-L10-1315-T03-B 1 9.50E-01 U1/2
Be SWA-L10-1315-T04-B 1 9.50E-01 U1/2
Be SWA-L10-1315-T05-B 1 9.50E-01 U1/2
Be SWA-L10-1315-T06-B 1 9.50E-01 U1/2
Be SWA-L10-1315-T07-B 1 9.50E-01 U1/2
Be SWA-L10-1315-T08-B 1 9.50E-01 U1/2
Be SWA-L10-1315-T09-B 1 9.50E-01 U1/2
Be SWA-L10-1315-T01-C 1 9.50E-01 U1/2
Be SWA-L10-1315-T02-C 1 9.50E-01 U1/2
Be SWA-L10-1315-T03-C 1 9.50E-01 U1/2
Be SWA-L10-1315-T04-C 1 9.50E-01 U1/2
Be SWA-L10-1315-T05-C 1 9.50E-01 U1/2
Be SWA-L10-1315-T06-C 1 9.50E-01 U1/2
Be SWA-L10-1315-T07-C 1 9.50E-01 U1/2
Be SWA-L10-1315-T08-C 1 9.50E-01 U1/2
Be SWA-L10-1315-T09-C 1 9.50E-01 U1/2
Be SWA-L10-1315-M01-A 1 9.50E-01 U1/2
Be SWA-L10-1315-M02-A 1 9.50E-01 U1/2
Be SWA-L10-1315-M03-A 1 9.50E-01 U1/2
Be SWA-L10-1315-M04-A 1 9.50E-01 U1/2
Be SWA-L10-1315-M05-A 1 9.50E-01 U1/2
Be SWA-L10-1315-M06-A 1 9.50E-01 U1/2
Be SWA-L10-1315-M07-A 1 9.50E-01 U1/2
Be SWA-L10-1315-M08-A 1 9.50E-01 U1/2
Be SWA-L10-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 27.07 1.90 6.00
9.50E-01 17.27 1.90 6.00
9.50E-01 22.62 1.90 6.00 10000 1000
9.50E-01 20.53 1.90 6.00
9.50E-01 82.18 1.90 6.00
9.50E-01 12.04 1.90 6.00
9.50E-01 50.08 1.90 6.00
9.50E-01 29.16 1.90 6.00
9.50E-01 19.35 1.90 6.00
9.50E-01 48.17 1.90 6.00
9.50E-01 35.52 1.90 6.00
9.50E-01 38.94 1.90 6.00 10000 1000
9.50E-01 14.76 1.90 6.00
9.50E-01 89.26 1.90 6.00
9.50E-01 38.71 1.90 6.00
9.50E-01 24.73 1.90 6.00
9.50E-01 22.65 1.90 6.00
9.50E-01 55.06 1.90 6.00
9.50E-01 20.33 1.90 6.00
9.50E-01 30.83 1.90 6.00
9.50E-01 13.59 1.90 6.00 10000 1000
9.50E-01 50.43 1.90 6.00
9.50E-01 21.54 1.90 6.00
9.50E-01 81.65 1.90 6.00
9.50E-01 69.46 1.90 6.00
9.50E-01 11.28 1.90 6.00
9.50E-01 22.30 1.90 6.00
9.50E-01 74.65 1.90 6.00
9.50E-01 45.57 1.90 6.00
9.50E-01 46.62 1.90 6.00
9.50E-01 11.02 1.90 6.00
9.50E-01 33.88 1.90 6.00
9.50E-01 32.42 1.90 6.00
9.50E-01 30.06 1.90 6.00
9.50E-01 72.24 1.90 6.00
9.50E-01 20.92 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.90E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.72E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.55E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26 PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39 PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315 SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-647
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L I
Cd SWA-L10-1315-T01-A 1 1.10E+00 U1/2
Cd SWA-L10-1315-T02-A 1 1.10E+00 U1/2
Cd SWA-L10-1315-T03-A 1 1.10E+00 U1/2
Cd SWA-L10-1315-T04-A 1 1.10E+00 U1/2
Cd SWA-L10-1315-T05-A 1 1.10E+00 U1/2
Cd SWA-L10-1315-T06-A 1 1.10E+00 U1/2
Cd SWA-L10-1315-T07-A 1 1.10E+00 U1/2
Cd SWA-L10-1315-T08-A 1 1.10E+00 U1/2
Cd SWA-L10-1315-T09-A 1 1.10E+00 U1/2
Cd SWA-L10-1315-T01-B 1 1.10E+00 U1/2
Cd SWA-L10-1315-T02-B 1 1.10E+00 U1/2
Cd SWA-L10-1315-T03-B 1 1.10E+00 U1/2
Cd SWA-L10-1315-T04-B 1 1.10E+00 U1/2
Cd SWA-L10-1315-T05-B 1 1.10E+00 U1/2
Cd SWA-L10-1315-T06-B 1 1.10E+00 U1/2
Cd SWA-L10-1315-T07-B 1 1.10E+00 U1/2
Cd SWA-L10-1315-T08-B 1 1.10E+00 U1/2
Cd SWA-L10-1315-T09-B 1 1.10E+00 U1/2
Cd SWA-L10-1315-T01-C 1 1.10E+00 U1/2
Cd SWA-L10-1315-T02-C 1 1.10E+00 U1/2
Cd SWA-L10-1315-T03-C 1 1.10E+00 U1/2
Cd SWA-L10-1315-T04-C 1 1.10E+00 U1/2
Cd SWA-L10-1315-T05-C 1 1.10E+00 U1/2
Cd SWA-L10-1315-T06-C 1 1.10E+00 U1/2
Cd SWA-L10-1315-T07-C 1 1.10E+00 U1/2
Cd SWA-L10-1315-T08-C 1 1.10E+00 U1/2
Cd SWA-L10-1315-T09-C 1 1.10E+00 U1/2
Cd SWA-L10-1315-M01-A 1 1.10E+00 U1/2
Cd SWA-L10-1315-M02-A 1 1.10E+00 U1/2
Cd SWA-L10-1315-M03-A 1 1.10E+00 U1/2
Cd SWA-L10-1315-M04-A 1 1.10E+00 U1/2
Cd SWA-L10-1315-M05-A 1 1.10E+00 U1/2
Cd SWA-L10-1315-M06-A 1 1.10E+00 U1/2
Cd SWA-L10-1315-M07-A 1 1.10E+00 U1/2
Cd SWA-L10-1315-M08-A 1 1.10E+00 U1/2
Cd SWA-L10-1315-M09-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 28.81 2.20 7.00
1.10E+00 80.43 2.20 7.00
1.10E+00 80.48 2.20 7.00 10000 1000
1.10E+00 12.11 2.20 7.00
1.10E+00 71.65 2.20 7.00
1.10E+00 29.75 2.20 7.00
1.10E+00 10.70 2.20 7.00
1.10E+00 29.85 2.20 7.00
1.10E+00 52.64 2.20 7.00
1.10E+00 31.16 2.20 7.00
1.10E+00 50.06 2.20 7.00
1.10E+00 30.12 2.20 7.00 10000 1000
1.10E+00 12.78 2.20 7.00
1.10E+00 19.88 2.20 7.00
1.10E+00 10.11 2.20 7.00
1.10E+00 32.35 2.20 7.00
1.10E+00 41.12 2.20 7.00
1.10E+00 14.26 2.20 7.00
1.10E+00 48.72 2.20 7.00
1.10E+00 21.70 2.20 7.00
1.10E+00 97.83 2.20 7.00 10000 1000
1.10E+00 25.85 2.20 7.00
1.10E+00 66.59 2.20 7.00
1.10E+00 18.96 2.20 7.00
1.10E+00 11.76 2.20 7.00
1.10E+00 22.39 2.20 7.00
1.10E+00 56.40 2.20 7.00
1.10E+00 51.86 2.20 7.00
1.10E+00 98.86 2.20 7.00
1.10E+00 86.74 2.20 7.00
1.10E+00 58.26 2.20 7.00
1.10E+00 76.29 2.20 7.00
1.10E+00 15.69 2.20 7.00
1.10E+00 36.71 2.20 7.00
1.10E+00 11.75 2.20 7.00
1.10E+00 41.87 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.17E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.89E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.83E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26 PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36 PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39 PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-648
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ca SWA-L10-1315-T01-A 1 1.94E+03
Ca SWA-L10-1315-T02-A 1 9.39E+03
Ca SWA-L10-1315-T03-A 1 1.41E+04
Ca SWA-L10-1315-T04-A 1 2.66E+04
Ca SWA-L10-1315-T05-A 1 2.72E+04
Ca SWA-L10-1315-T06-A 1 2.76E+04
Ca SWA-L10-1315-T07-A 1 2.69E+04
Ca SWA-L10-1315-T08-A 1 2.39E+04
Ca SWA-L10-1315-T09-A 1 2.13E+04
Ca SWA-L10-1315-T01-B 1 2.48E+03
Ca SWA-L10-1315-T02-B 1 1.19E+04
Ca SWA-L10-1315-T03-B 1 1.60E+04
Ca SWA-L10-1315-T04-B 1 2.73E+04
Ca SWA-L10-1315-T05-B 1 2.86E+04
Ca SWA-L10-1315-T06-B 1 2.99E+04
Ca SWA-L10-1315-T07-B 1 3.08E+04
Ca SWA-L10-1315-T08-B 1 2.74E+04
Ca SWA-L10-1315-T09-B 1 2.81E+04
Ca SWA-L10-1315-T01-C 1 1.87E+03
Ca SWA-L10-1315-T02-C 1 1.09E+04
Ca SWA-L10-1315-T03-C 1 1.49E+04
Ca SWA-L10-1315-T04-C 1 2.49E+04
Ca SWA-L10-1315-T05-C 1 2.66E+04
Ca SWA-L10-1315-T06-C 1 2.80E+04
Ca SWA-L10-1315-T07-C 1 2.86E+04
Ca SWA-L10-1315-T08-C 1 2.60E+04
Ca SWA-L10-1315-T09-C 1 2.65E+04
Ca SWA-L10-1315-M01-A 1 1.65E+01
Ca SWA-L10-1315-M02-A 1 1.39E+02
Ca SWA-L10-1315-M03-A 1 2.21E+01
Ca SWA-L10-1315-M04-A 1 1.48E+02
Ca SWA-L10-1315-M05-A 1 1.10E+02
Ca SWA-L10-1315-M06-A 1 1.32E+02
Ca SWA-L10-1315-M07-A 1 7.20E+01
Ca SWA-L10-1315-M08-A 1 2.55E+01
Ca SWA-L10-1315-M09-A 1 6.74E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.94E+03 0.48 2.60 8.30
9.39E+03 0.35 2.60 8.30
1.41E+04 0.49 2.60 8.30 10000 1000
2.66E+04 0.43 2.60 8.30
2.72E+04 0.58 2.60 8.30
2.76E+04 3.67 2.60 8.30
2.69E+04 0.13 2.60 8.30
2.39E+04 0.27 2.60 8.30
2.13E+04 0.36 2.60 8.30
2.48E+03 0.91 2.60 8.30
1.19E+04 0.77 2.60 8.30
1.60E+04 0.68 2.60 8.30 10000 1000
2.73E+04 0.58 2.60 8.30
2.86E+04 0.17 2.60 8.30
2.99E+04 0.61 2.60 8.30
3.08E+04 0.67 2.60 8.30
2.74E+04 0.80 2.60 8.30
2.81 E+04 0.61 2.60 8.30
1.87E+03 0.88 2.60 8.30
1.09E+04 0.76 2.60 8.30
1.49E+04 0.17 2.60 8.30 10000 1000
2.49E+04 0.49 2.60 8.30
2.66E+04 0.81 2.60 8.30
2.80E+04 0.18 2.60 8.30
2.86E+04 0.39 2.60 8.30
2.60E+04 0.31 2.60 8.30
2.65E+04 3.45 2.60 8.30
1.65E+01 1.99 2.60 8.30
1.39E+02 6.20 2.60 8.30
2.21 E+01 3.38 2.60 8.30
1.48E+02 6.24 2.60 8.30
1.10E+02 8.67 2.60 8.30
1.32E+02 1.96 2.60 8.30
7.20E+01 9.01 2.60 8.30
2.55E+01 6.18 2.60 8.30
6.74E+01 1.32 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.50E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.68E+04 82% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.59E+04 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26 PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36 PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39 PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-649
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cr SWA-L10-1315-T01-A 1 1.91E+01
Cr SWA-L10-1315-T02-A 1 2.59E+01
Cr SWA-L10-1315-T03-A 1 2.69E+01
Cr SWA-L10-1315-T04-A 1 5.27E+01
Cr SWA-L10-1315-T05-A 1 4.65E+01
Cr SWA-L10-1315-T06-A 1 5.49E+01
Cr SWA-L10-1315-T07-A 1 5.24E+01
Cr SWA-L10-1315-T08-A 1 3.41 E+01
Cr SWA-L10-1315-T09-A 1 4.60E+01
Cr SWA-L10-1315-T01-B 1 5.09E+01
Cr SWA-L10-1315-T02-B 1 4.35E+01
Cr SWA-L10-1315-T03-B 1 3.45E+01
Cr SWA-L10-1315-T04-B 1 6.47E+01
Cr SWA-L10-1315-T05-B 1 5.64E+01
Cr SWA-L10-1315-T06-B 1 6.13E+01
Cr SWA-L10-1315-T07-B 1 5.78E+01
Cr SWA-L10-1315-T08-B 1 3.92E+01
Cr SWA-L10-1315-T09-B 1 4.81E+01
Cr SWA-L10-1315-T01-C 1 1.81E+01
Cr SWA-L10-1315-T02-C 1 3.35E+01
Cr SWA-L10-1315-T03-C 1 2.92E+01
Cr SWA-L10-1315-T04-C 1 5.50E+01
Cr SWA-L10-1315-T05-C 1 4.76E+01
Cr SWA-L10-1315-T06-C 1 5.24E+01
Cr SWA-L10-1315-T07-C 1 4.90E+01
Cr SWA-L10-1315-T08-C 1 3.51E+01
Cr SWA-L10-1315-T09-C 1 4.48E+01
Cr SWA-L10-1315-M01-A 1 6.00E-01 U1/2
Cr SWA-L10-1315-M02-A 1 6.00E-01 U1/2
Cr SWA-L10-1315-M03-A 1 6.00E-01 U1/2
Cr SWA-L10-1315-M04-A 1 6.00E-01 U1/2
Cr SWA-L10-1315-M05-A 1 6.00E-01 U1/2
Cr SWA-L10-1315-M06-A 1 6.00E-01 U1/2
Cr SWA-L10-1315-M07-A 1 6.00E-01 U1/2
Cr SWA-L10-1315-M08-A 1 6.00E-01 U1/2
Cr SWA-L10-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.91 E+01 2.92 1.20 3.82
2.59E+01 0.91 1.20 3.82
2.69E+01 3.08 1.20 3.82 10000 1000
5.27E+01 1.19 1.20 3.82
4.65E+01 1.11 1.20 3.82
5.49E+01 3.10 1.20 3.82
5.24E+01 1.08 1.20 3.82
3.41E+01 2.05 1.20 3.82
4.60E+01 0.92 1.20 3.82
5.09E+01 0.13 1.20 3.82
4.35E+01 0.72 1.20 3.82
3.45E+01 1.29 1.20 3.82 10000 1000
6.47E+01 0.42 1.20 3.82
5.64E+01 0.81 1.20 3.82
6.13E+01 1.49 1.20 3.82
5.78E+01 1.40 1.20 3.82
3.92E+01 3.30 1.20 3.82
4.81E+01 0.60 1.20 3.82
1.81E+01 0.68 1.20 3.82
3.35E+01 0.61 1.20 3.82
2.92E+01 1.92 1.20 3.82 10000 1000
5.50E+01 1.00 1.20 3.82
4.76E+01 0.43 1.20 3.82
5.24E+01 0.68 1.20 3.82
4.90E+01 1.02 1.20 3.82
3.51E+01 1.69 1.20 3.82
4.48E+01 3.16 1.20 3.82
6.00E-01 25.73 1.20 3.82
6.00E-01 51.67 1.20 3.82
6.00E-01 16.19 1.20 3.82
6.00E-01 63.50 1.20 3.82
6.00E-01 35.63 1.20 3.82
6.00E-01 75.37 1.20 3.82
6.00E-01 50.35 1.20 3.82
6.00E-01 67.02 1.20 3.82
6.00E-01 6.01 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.13E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.18E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.90E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36 PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39 PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315 SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-650
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L I
Co SWA-L10-1315-T01-A 1 9.00E-01 U1/2
Co SWA-L10-1315-T02-A 1 9.00E-01 U1/2
Co SWA-L10-1315-T03-A 1 9.00E-01 U1/2
Co SWA-L10-1315-T04-A 1 9.00E-01 U1/2
Co SWA-L10-1315-T05-A 1 9.00E-01 U1/2
Co SWA-L10-1315-T06-A 1 9.00E-01 U1/2
Co SWA-L10-1315-T07-A 1 9.00E-01 U1/2
Co SWA-L10-1315-T08-A 1 9.00E-01 U1/2
Co SWA-L10-1315-T09-A 1 9.00E-01 U1/2
Co SWA-L10-1315-T01-B 1 9.00E-01 U1/2
Co SWA-L10-1315-T02-B 1 9.00E-01 U1/2
Co SWA-L10-1315-T03-B 1 9.00E-01 U1/2
Co SWA-L10-1315-T04-B 1 9.00E-01 U1/2
Co SWA-L10-1315-T05-B 1 9.00E-01 U1/2
Co SWA-L10-1315-T06-B 1 9.00E-01 U1/2
Co SWA-L10-1315-T07-B 1 9.00E-01 U1/2
Co SWA-L10-1315-T08-B 1 9.00E-01 U1/2
Co SWA-L10-1315-T09-B 1 9.00E-01 U1/2
Co SWA-L10-1315-T01-C 1 9.00E-01 U1/2
Co SWA-L10-1315-T02-C 1 9.00E-01 U1/2
Co SWA-L10-1315-T03-C 1 9.00E-01 U1/2
Co SWA-L10-1315-T04-C 1 9.00E-01 U1/2
Co SWA-L10-1315-T05-C 1 9.00E-01 U1/2
Co SWA-L10-1315-T06-C 1 9.00E-01 U1/2
Co SWA-L10-1315-T07-C 1 9.00E-01 U1/2
Co SWA-L10-1315-T08-C 1 9.00E-01 U1/2
Co SWA-L10-1315-T09-C 1 9.00E-01 U1/2
Co SWA-L10-1315-M01-A 1 9.00E-01 U1/2
Co SWA-L10-1315-M02-A 1 9.00E-01 U1/2
Co SWA-L10-1315-M03-A 1 9.00E-01 U1/2
Co SWA-L10-1315-M04-A 1 9.00E-01 U1/2
Co SWA-L10-1315-M05-A 1 9.00E-01 U1/2
Co SWA-L10-1315-M06-A 1 9.00E-01 U1/2
Co SWA-L10-1315-M07-A 1 9.00E-01 U1/2
Co SWA-L10-1315-M08-A 1 9.00E-01 U1/2
Co SWA-L10-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 10.22 1.80 5.72
9.00E-01 31.89 1.80 5.72
9.00E-01 45.65 1.80 5.72 10000 1000
9.00E-01 15.45 1.80 5.72
9.00E-01 36.04 1.80 5.72
9.00E-01 65.23 1.80 5.72
9.00E-01 24.00 1.80 5.72
9.00E-01 13.21 1.80 5.72
9.00E-01 29.94 1.80 5.72
9.00E-01 33.37 1.80 5.72
9.00E-01 32.34 1.80 5.72
9.00E-01 26.21 1.80 5.72 10000 1000
9.00E-01 11.61 1.80 5.72
9.00E-01 34.76 1.80 5.72
9.00E-01 18.59 1.80 5.72
9.00E-01 19.63 1.80 5.72
9.00E-01 89.33 1.80 5.72
9.00E-01 13.73 1.80 5.72
9.00E-01 17.32 1.80 5.72
9.00E-01 44.75 1.80 5.72
9.00E-01 35.58 1.80 5.72 10000 1000
9.00E-01 32.55 1.80 5.72
9.00E-01 11.05 1.80 5.72
9.00E-01 16.12 1.80 5.72
9.00E-01 14.72 1.80 5.72
9.00E-01 14.24 1.80 5.72
9.00E-01 66.10 1.80 5.72
9.00E-01 86.81 1.80 5.72
9.00E-01 54.79 1.80 5.72
9.00E-01 47.96 1.80 5.72
9.00E-01 34.78 1.80 5.72
9.00E-01 88.56 1.80 5.72
9.00E-01 26.62 1.80 5.72
9.00E-01 44.82 1.80 5.72
9.00E-01 67.94 1.80 5.72
9.00E-01 31.69 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.13E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.84E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.32E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26 PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36 PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39 PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-651
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L I
Cu SWA-L10-1315-T01-A 1 1.85E+00 U1/2
Cu SWA-L10-1315-T02-A 1 1.85E+00 U1/2
Cu SWA-L10-1315-T03-A 1 1.85E+00 U1/2
Cu SWA-L10-1315-T04-A 1 1.85E+00 U1/2
Cu SWA-L10-1315-T05-A 1 1.85E+00 U1/2
Cu SWA-L10-1315-T06-A 1 1.85E+00 U1/2
Cu SWA-L10-1315-T07-A 1 1.85E+00 U1/2
Cu SWA-L10-1315-T08-A 1 1.85E+00 U1/2
Cu SWA-L10-1315-T09-A 1 1.85E+00 U1/2
Cu SWA-L10-1315-T01-B 1 1.85E+00 U1/2
Cu SWA-L10-1315-T02-B 1 1.85E+00 U1/2
Cu SWA-L10-1315-T03-B 1 1.85E+00 U1/2
Cu SWA-L10-1315-T04-B 1 1.85E+00 U1/2
Cu SWA-L10-1315-T05-B 1 1.85E+00 U1/2
Cu SWA-L10-1315-T06-B 1 1.85E+00 U1/2
Cu SWA-L10-1315-T07-B 1 1.85E+00 U1/2
Cu SWA-L10-1315-T08-B 1 1.85E+00 U1/2
Cu SWA-L10-1315-T09-B 1 1.85E+00 U1/2
Cu SWA-L10-1315-T01-C 1 1.85E+00 U1/2
Cu SWA-L10-1315-T02-C 1 1.85E+00 U1/2
Cu SWA-L10-1315-T03-C 1 1.85E+00 U1/2
Cu SWA-L10-1315-T04-C 1 1.85E+00 U1/2
Cu SWA-L10-1315-T05-C 1 1.85E+00 U1/2
Cu SWA-L10-1315-T06-C 1 1.85E+00 U1/2
Cu SWA-L10-1315-T07-C 1 1.85E+00 U1/2
Cu SWA-L10-1315-T08-C 1 1.85E+00 U1/2
Cu SWA-L10-1315-T09-C 1 1.85E+00 U1/2
Cu SWA-L10-1315-M01-A 1 1.85E+00 U1/2
Cu SWA-L10-1315-M02-A 1 1.85E+00 U1/2
Cu SWA-L10-1315-M03-A 1 1.85E+00 U1/2
Cu SWA-L10-1315-M04-A 1 1.85E+00 U1/2
Cu SWA-L10-1315-M05-A 1 1.85E+00 U1/2
Cu SWA-L10-1315-M06-A 1 1.85E+00 U1/2
Cu SWA-L10-1315-M07-A 1 1.85E+00 U1/2
Cu SWA-L10-1315-M08-A 1 1.85E+00 U1/2
Cu SWA-L10-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 10.21 3.70 11.80
1.85E+00 61.21 3.70 11.80
1.85E+00 76.59 3.70 11.80 10000 1000
1.85E+00 46.67 3.70 11.80
1.85E+00 37.77 3.70 11.80
1.85E+00 19.55 3.70 11.80
1.85E+00 25.52 3.70 11.80
1.85E+00 25.67 3.70 11.80
1.85E+00 29.57 3.70 11.80
1.85E+00 48.77 3.70 11.80
1.85E+00 20.77 3.70 11.80
1.85E+00 47.30 3.70 11.80 10000 1000
1.85E+00 11.60 3.70 11.80
1.85E+00 59.73 3.70 11.80
1.85E+00 26.72 3.70 11.80
1.85E+00 89.67 3.70 11.80
1.85E+00 96.03 3.70 11.80
1.85E+00 49.87 3.70 11.80
1.85E+00 47.97 3.70 11.80
1.85E+00 21.23 3.70 11.80
1.85E+00 10.96 3.70 11.80 10000 1000
1.85E+00 26.11 3.70 11.80
1.85E+00 79.28 3.70 11.80
1.85E+00 20.87 3.70 11.80
1.85E+00 23.80 3.70 11.80
1.85E+00 24.62 3.70 11.80
1.85E+00 86.50 3.70 11.80
1.85E+00 77.11 3.70 11.80
1.85E+00 23.43 3.70 11.80
1.85E+00 27.07 3.70 11.80
1.85E+00 24.79 3.70 11.80
1.85E+00 66.61 3.70 11.80
1.85E+00 13.48 3.70 11.80
1.85E+00 17.88 3.70 11.80
1.85E+00 17.01 3.70 11.80
1.85E+00 10.90 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.87E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.60E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.26E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26 PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36 PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39 PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-652
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Fe SWA-L10-1315-T01-A 1 5.92E+00 E
Fe SWA-L10-1315-T02-A 1 5.93E+00 E
Fe SWA-L10-1315-T03-A 1 3.69E+00 E
Fe SWA-L10-1315-T04-A 1 3.87E+00 E
Fe SWA-L10-1315-T05-A 1 2.77E+00 E
Fe SWA-L10-1315-T06-A 1 2.53E+00 E
Fe SWA-L10-1315-T07-A 1 3.21E+00 E
Fe SWA-L10-1315-T08-A 1 4.00E+00 E
Fe SWA-L10-1315-T09-A 1 2.30E+00 E
Fe SWA-L10-1315-T01-B 1 8.70E+00
Fe SWA-L10-1315-T02-B 1 7.94E+00
Fe SWA-L10-1315-T03-B 1 5.73E+00 E
Fe SWA-L10-1315-T04-B 1 7.81E+00
Fe SWA-L10-1315-T05-B 1 1.38E+01
Fe SWA-L10-1315-T06-B 1 3.53E+00 E
Fe SWA-L10-1315-T07-B 1 2.94E+00 E
Fe SWA-L10-1315-T08-B 1 2.54E+00 E
Fe SWA-L10-1315-T09-B 1 2.14E+00 E
Fe SWA-L10-1315-T01-C 1 6.85E+00
Fe SWA-L10-1315-T02-C 1 4.84E+00 E
Fe SWA-L10-1315-T03-C 1 6.53E+00
Fe SWA-L10-1315-T04-C 1 6.21E+00 E
Fe SWA-L10-1315-T05-C 1 5.05E+00 E
Fe SWA-L10-1315-T06-C 1 3.31E+00 E
Fe SWA-L10-1315-T07-C 1 3.29E+00 E
Fe SWA-L10-1315-T08-C 1 2.90E+00 E
Fe SWA-L10-1315-T09-C 1 2.18E+00 E
Fe SWA-L10-1315-M01-A 1 1.00E+00 U1/2
Fe SWA-L10-1315-M02-A 1 1.00E+00 U1/2
Fe SWA-L10-1315-M03-A 1 1.00E+00 U1/2
Fe SWA-L10-1315-M04-A 1 1.00E+00 U1/2
Fe SWA-L10-1315-M05-A 1 1.00E+00 U1/2
Fe SWA-L10-1315-M06-A 1 1.00E+00 U1/2
Fe SWA-L10-1315-M07-A 1 1.00E+00 U1/2
Fe SWA-L10-1315-M08-A 1 1.00E+00 U1/2
Fe SWA-L10-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.92E+00 2.77 2.00 6.40
5.93E+00 2.20 2.00 6.40
3.69E+00 7.31 2.00 6.40 10000 1000
3.87E+00 1.54 2.00 6.40
2.77E+00 1.70 2.00 6.40
2.53E+00 10.33 2.00 6.40
3.21 E+00 2.23 2.00 6.40
4.00E+00 0.48 2.00 6.40
2.30E+00 2.87 2.00 6.40
8.70E+00 0.55 2.00 6.40
7.94E+00 7.02 2.00 6.40
5.73E+00 5.13 2.00 6.40 10000 1000
7.81 E+00 1.40 2.00 6.40
1.38E+01 1.48 2.00 6.40
3.53E+00 9.39 2.00 6.40
2.94E+00 9.42 2.00 6.40
2.54E+00 2.42 2.00 6.40
2.14E+00 4.37 2.00 6.40
6.85E+00 3.63 2.00 6.40
4.84E+00 6.40 2.00 6.40
6.53E+00 1.49 2.00 6.40 10000 1000
6.21 E+00 10.54 2.00 6.40
5.05E+00 2.35 2.00 6.40
3.31E+00 17.52 2.00 6.40
3.29E+00 9.20 2.00 6.40
2.90E+00 23.50 2.00 6.40
2.18E+00 2.37 2.00 6.40
1.00E+00 54.62 2.00 6.40
1.00E+00 31.20 2.00 6.40
1.00E+00 23.64 2.00 6.40
1.00E+00 18.75 2.00 6.40
1.00E+00 17.11 2.00 6.40
1.00E+00 60.02 2.00 6.40
1.00E+00 11.05 2.00 6.40
1.00E+00 65.98 2.00 6.40
1.00E+00 45.89 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.00E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.82E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.34E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26 PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36 PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39 PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315 SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L1 01 31 5 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-653
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L I
Pb SWA-L10-1315-T01-A 1 3.40E+00 U1/2
Pb SWA-L10-1315-T02-A 1 3.40E+00 U1/2
Pb SWA-L10-1315-T03-A 1 3.40E+00 U1/2
Pb SWA-L10-1315-T04-A 1 3.40E+00 U1/2
Pb SWA-L10-1315-T05-A 1 3.40E+00 U1/2
Pb SWA-L10-1315-T06-A 1 3.40E+00 U1/2
Pb SWA-L10-1315-T07-A 1 3.40E+00 U1/2
Pb SWA-L10-1315-T08-A 1 3.40E+00 U1/2
Pb SWA-L10-1315-T09-A 1 3.40E+00 U1/2
Pb SWA-L10-1315-T01-B 1 3.40E+00 U1/2
Pb SWA-L10-1315-T02-B 1 3.40E+00 U1/2
Pb SWA-L10-1315-T03-B 1 3.40E+00 U1/2
Pb SWA-L10-1315-T04-B 1 3.40E+00 U1/2
Pb SWA-L10-1315-T05-B 1 3.40E+00 U1/2
Pb SWA-L10-1315-T06-B 1 3.40E+00 U1/2
Pb SWA-L10-1315-T07-B 1 3.40E+00 U1/2
Pb SWA-L10-1315-T08-B 1 3.40E+00 U1/2
Pb SWA-L10-1315-T09-B 1 3.40E+00 U1/2
Pb SWA-L10-1315-T01-C 1 3.40E+00 U1/2
Pb SWA-L10-1315-T02-C 1 3.40E+00 U1/2
Pb SWA-L10-1315-T03-C 1 3.40E+00 U1/2
Pb SWA-L10-1315-T04-C 1 3.40E+00 U1/2
Pb SWA-L10-1315-T05-C 1 3.40E+00 U1/2
Pb SWA-L10-1315-T06-C 1 3.40E+00 U1/2
Pb SWA-L10-1315-T07-C 1 3.40E+00 U1/2
Pb SWA-L10-1315-T08-C 1 3.40E+00 U1/2
Pb SWA-L10-1315-T09-C 1 3.40E+00 U1/2
Pb SWA-L10-1315-M01-A 1 3.40E+00 U1/2
Pb SWA-L10-1315-M02-A 1 3.40E+00 U1/2
Pb SWA-L10-1315-M03-A 1 3.40E+00 U1/2
Pb SWA-L10-1315-M04-A 1 3.40E+00 U1/2
Pb SWA-L10-1315-M05-A 1 3.40E+00 U1/2
Pb SWA-L10-1315-M06-A 1 3.40E+00 U1/2
Pb SWA-L10-1315-M07-A 1 3.40E+00 U1/2
Pb SWA-L10-1315-M08-A 1 3.40E+00 U1/2
Pb SWA-L10-1315-M09-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 25.18 6.80 21.60
3.40E+00 12.34 6.80 21.60
3.40E+00 48.59 6.80 21.60 10000 1000
3.40E+00 19.79 6.80 21.60
3.40E+00 76.27 6.80 21.60
3.40E+00 46.88 6.80 21.60
3.40E+00 36.27 6.80 21.60
3.40E+00 49.03 6.80 21.60
3.40E+00 28.26 6.80 21.60
3.40E+00 26.92 6.80 21.60
3.40E+00 39.43 6.80 21.60
3.40E+00 94.30 6.80 21.60 10000 1000
3.40E+00 32.19 6.80 21.60
3.40E+00 58.31 6.80 21.60
3.40E+00 12.42 6.80 21.60
3.40E+00 23.99 6.80 21.60
3.40E+00 12.27 6.80 21.60
3.40E+00 13.89 6.80 21.60
3.40E+00 21.06 6.80 21.60
3.40E+00 74.54 6.80 21.60
3.40E+00 55.23 6.80 21.60 10000 1000
3.40E+00 39.25 6.80 21.60
3.40E+00 18.48 6.80 21.60
3.40E+00 26.85 6.80 21.60
3.40E+00 11.63 6.80 21.60
3.40E+00 43.47 6.80 21.60
3.40E+00 38.92 6.80 21.60
3.40E+00 14.60 6.80 21.60
3.40E+00 21.37 6.80 21.60
3.40E+00 48.40 6.80 21.60
3.40E+00 15.53 6.80 21.60
3.40E+00 13.38 6.80 21.60
3.40E+00 57.28 6.80 21.60
3.40E+00 70.68 6.80 21.60
3.40E+00 74.76 6.80 21.60
3.40E+00 43.78 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.10E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.77E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.19E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26 PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39 PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315 SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-654
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L I
Li SWA-L10-1315-T01-A 1 9.50E-01 U1/2
Li SWA-L10-1315-T02-A 1 9.50E-01 U1/2
Li SWA-L10-1315-T03-A 1 9.50E-01 U1/2
Li SWA-L10-1315-T04-A 1 9.50E-01 U1/2
Li SWA-L10-1315-T05-A 1 9.50E-01 U1/2
Li SWA-L10-1315-T06-A 1 9.50E-01 U1/2
Li SWA-L10-1315-T07-A 1 9.50E-01 U1/2
Li SWA-L10-1315-T08-A 1 9.50E-01 U1/2
Li SWA-L10-1315-T09-A 1 9.50E-01 U1/2
Li SWA-L10-1315-T01-B 1 9.50E-01 U1/2
Li SWA-L10-1315-T02-B 1 9.50E-01 U1/2
Li SWA-L10-1315-T03-B 1 9.50E-01 U1/2
Li SWA-L10-1315-T04-B 1 9.50E-01 U1/2
Li SWA-L10-1315-T05-B 1 9.50E-01 U1/2
Li SWA-L10-1315-T06-B 1 9.50E-01 U1/2
Li SWA-L10-1315-T07-B 1 9.50E-01 U1/2
Li SWA-L10-1315-T08-B 1 9.50E-01 U1/2
Li SWA-L10-1315-T09-B 1 9.50E-01 U1/2
Li SWA-L10-1315-T01-C 1 9.50E-01 U1/2
Li SWA-L10-1315-T02-C 1 9.50E-01 U1/2
Li SWA-L10-1315-T03-C 1 9.50E-01 U1/2
Li SWA-L10-1315-T04-C 1 9.50E-01 U1/2
Li SWA-L10-1315-T05-C 1 9.50E-01 U1/2
Li SWA-L10-1315-T06-C 1 9.50E-01 U1/2
Li SWA-L10-1315-T07-C 1 9.50E-01 U1/2
Li SWA-L10-1315-T08-C 1 9.50E-01 U1/2
Li SWA-L10-1315-T09-C 1 9.50E-01 U1/2
Li SWA-L10-1315-M01-A 1 9.50E-01 U1/2
Li SWA-L10-1315-M02-A 1 9.50E-01 U1/2
Li SWA-L10-1315-M03-A 1 9.50E-01 U1/2
Li SWA-L10-1315-M04-A 1 9.50E-01 U1/2
Li SWA-L10-1315-M05-A 1 9.50E-01 U1/2
Li SWA-L10-1315-M06-A 1 9.50E-01 U1/2
Li SWA-L10-1315-M07-A 1 9.50E-01 U1/2
Li SWA-L10-1315-M08-A 1 9.50E-01 U1/2
Li SWA-L10-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 36.75 1.90 6.00
9.50E-01 16.26 1.90 6.00
9.50E-01 17.25 1.90 6.00 10000 1000
9.50E-01 36.86 1.90 6.00
9.50E-01 38.91 1.90 6.00
9.50E-01 16.67 1.90 6.00
9.50E-01 10.61 1.90 6.00
9.50E-01 25.85 1.90 6.00
9.50E-01 26.06 1.90 6.00
9.50E-01 33.07 1.90 6.00
9.50E-01 41.23 1.90 6.00
9.50E-01 16.39 1.90 6.00 10000 1000
9.50E-01 30.93 1.90 6.00
9.50E-01 4.81 1.90 6.00
9.50E-01 20.66 1.90 6.00
9.50E-01 16.39 1.90 6.00
9.50E-01 1.03 1.90 6.00
9.50E-01 38.66 1.90 6.00
9.50E-01 28.70 1.90 6.00
9.50E-01 18.16 1.90 6.00
9.50E-01 22.14 1.90 6.00 10000 1000
9.50E-01 16.60 1.90 6.00
9.50E-01 30.67 1.90 6.00
9.50E-01 18.02 1.90 6.00
9.50E-01 26.16 1.90 6.00
9.50E-01 0.12 1.90 6.00
9.50E-01 26.31 1.90 6.00
9.50E-01 21.70 1.90 6.00
9.50E-01 25.99 1.90 6.00
9.50E-01 31.46 1.90 6.00
9.50E-01 2.63 1.90 6.00
9.50E-01 40.71 1.90 6.00
9.50E-01 24.27 1.90 6.00
9.50E-01 3.99 1.90 6.00
9.50E-01 20.61 1.90 6.00
9.50E-01 8.52 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.86E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.60E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.20E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26 PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36 PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39 PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-655
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Mn SWA-L10-1315-T01-A 1 1.00E+00 U1/2
Mn SWA-L10-1315-T02-A 1 1.00E+00 U1/2
Mn SWA-L10-1315-T03-A 1 1.00E+00 U1/2
Mn SWA-L10-1315-T04-A 1 1.00E+00 U1/2
Mn SWA-L10-1315-T05-A 1 1.00E+00 U1/2
Mn SWA-L10-1315-T06-A 1 1.00E+00 U1/2
Mn SWA-L10-1315-T07-A 1 1.00E+00 U1/2
Mn SWA-L10-1315-T08-A 1 1.00E+00 U1/2
Mn SWA-L10-1315-T09-A 1 1.00E+00 U1/2
Mn SWA-L10-1315-T01-B 1 1.00E+00 U1/2
Mn SWA-L10-1315-T02-B 1 1.00E+00 U1/2
Mn SWA-L10-1315-T03-B 1 1.00E+00 U1/2
Mn SWA-L10-1315-T04-B 1 1.00E+00 U1/2
Mn SWA-L10-1315-T05-B 1 1.00E+00 U1/2
Mn SWA-L10-1315-T06-B 1 1.00E+00 U1/2
Mn SWA-L10-1315-T07-B 1 1.00E+00 U1/2
Mn SWA-L10-1315-T08-B 1 1.00E+00 U1/2
Mn SWA-L10-1315-T09-B 1 1.00E+00 U1/2
Mn SWA-L10-1315-T01-C 1 1.00E+00 U1/2
Mn SWA-L10-1315-T02-C 1 1.00E+00 U1/2
Mn SWA-L10-1315-T03-C 1 1.00E+00 U1/2
Mn SWA-L10-1315-T04-C 1 1.00E+00 U1/2
Mn SWA-L10-1315-T05-C 1 1.00E+00 U1/2
Mn SWA-L10-1315-T06-C 1 1.00E+00 U1/2
Mn SWA-L10-1315-T07-C 1 1.00E+00 U1/2
Mn SWA-L10-1315-T08-C 1 1.00E+00 U1/2
Mn SWA-L10-1315-T09-C 1 1.00E+00 U1/2
Mn SWA-L10-1315-M01-A 1 1.00E+00 U1/2
Mn SWA-L10-1315-M02-A 1 1.00E+00 U1/2
Mn SWA-L10-1315-M03-A 1 1.00E+00 U1/2
Mn SWA-L10-1315-M04-A 1 1.00E+00 U1/2
Mn SWA-L10-1315-M05-A 1 1.00E+00 U1/2
Mn SWA-L10-1315-M06-A 1 1.00E+00 U1/2
Mn SWA-L10-1315-M07-A 1 1.00E+00 U1/2
Mn SWA-L10-1315-M08-A 1 1.00E+00 U1/2
Mn SWA-L10-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 47.68 2.00 6.40
1.00E+00 3.94 2.00 6.40
1.00E+00 39.04 2.00 6.40 10000 1000
1.00E+00 37.50 2.00 6.40
1.00E+00 67.61 2.00 6.40
1.00E+00 60.76 2.00 6.40
1.00E+00 14.48 2.00 6.40
1.00E+00 15.77 2.00 6.40
1.00E+00 11.85 2.00 6.40
1.00E+00 48.78 2.00 6.40
1.00E+00 33.19 2.00 6.40
1.00E+00 25.73 2.00 6.40 10000 1000
1.00E+00 18.95 2.00 6.40
1.00E+00 35.86 2.00 6.40
1.00E+00 30.60 2.00 6.40
1.00E+00 9.53 2.00 6.40
1.00E+00 4.86 2.00 6.40
1.00E+00 7.80 2.00 6.40
1.00E+00 12.16 2.00 6.40
1.00E+00 3.08 2.00 6.40
1.00E+00 20.30 2.00 6.40 10000 1000
1.00E+00 19.00 2.00 6.40
1.00E+00 22.28 2.00 6.40
1.00E+00 13.15 2.00 6.40
1.00E+00 19.19 2.00 6.40
1.00E+00 8.82 2.00 6.40
1.00E+00 11.69 2.00 6.40
1.00E+00 3.24 2.00 6.40
1.00E+00 2.69 2.00 6.40
1.00E+00 4.32 2.00 6.40
1.00E+00 30.93 2.00 6.40
1.00E+00 16.73 2.00 6.40
1.00E+00 19.45 2.00 6.40
1.00E+00 32.11 2.00 6.40
1.00E+00 21.15 2.00 6.40
1.00E+00 9.14 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.81 E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.72E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.32E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26 PM EPA Interlab L10 1315 SWA
2/17/11 12:27PM EPA Interlab L10 1315 SWA
2/17/11 12:36 PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39 PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315 SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-656
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Mg SWA-L10-1315-T01-A 1 1.44E+01
Mg SWA-L10-1315-T02-A 1 1.60E+01
Mg SWA-L10-1315-T03-A 1 3.86E+01
Mg SWA-L10-1315-T04-A 1 1.30E+01
Mg SWA-L10-1315-T05-A 1 1.59E+01
Mg SWA-L10-1315-T06-A 1 2.50E+01
Mg SWA-L10-1315-T07-A 1 2.63E+01
Mg SWA-L10-1315-T08-A 1 6.04E+01
Mg SWA-L10-1315-T09-A 1 4.15E+01
Mg SWA-L10-1315-T01-B 1 9.89E+00
Mg SWA-L10-1315-T02-B 1 4.97E+01
Mg SWA-L10-1315-T03-B 1 4.68E+01
Mg SWA-L10-1315-T04-B 1 2.78E+01
Mg SWA-L10-1315-T05-B 1 2.88E+01
Mg SWA-L10-1315-T06-B 1 1.17E+01
Mg SWA-L10-1315-T07-B 1 1.54E+01
Mg SWA-L10-1315-T08-B 1 4.61E+01
Mg SWA-L10-1315-T09-B 1 3.28E+01
Mg SWA-L10-1315-T01-C 1 7.22E+00
Mg SWA-L10-1315-T02-C 1 2.70E+01
Mg SWA-L10-1315-T03-C 1 4.52E+01
Mg SWA-L10-1315-T04-C 1 7.47E+00
Mg SWA-L10-1315-T05-C 1 6.46E+00
Mg SWA-L10-1315-T06-C 1 2.34E+01
Mg SWA-L10-1315-T07-C 1 1.58E+01
Mg SWA-L10-1315-T08-C 1 3.48E+01
Mg SWA-L10-1315-T09-C 1 3.69E+01
Mg SWA-L10-1315-M01-A 1 1.78E+01
Mg SWA-L10-1315-M02-A 1 2.46E+01
Mg SWA-L10-1315-M03-A 1 1.76E+01
Mg SWA-L10-1315-M04-A 1 2.53E+01
Mg SWA-L10-1315-M05-A 1 2.48E+01
Mg SWA-L10-1315-M06-A 1 2.79E+01
Mg SWA-L10-1315-M07-A 1 3.18E+01
Mg SWA-L10-1315-M08-A 1 1.97E+01
Mg SWA-L10-1315-M09-A 1 2.99E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.44E+01 5.75 1.00 3.18
1.60E+01 2.23 1.00 3.18
3.86E+01 3.19 1.00 3.18 10000 1000
1.30E+01 1.53 1.00 3.18
1.59E+01 7.16 1.00 3.18
2.50E+01 4.02 1.00 3.18
2.63E+01 3.61 1.00 3.18
6.04E+01 6.21 1.00 3.18
4.15E+01 2.50 1.00 3.18
9.89E+00 7.27 1.00 3.18
4.97E+01 5.29 1.00 3.18
4.68E+01 6.31 1.00 3.18 10000 1000
2.78E+01 6.26 1.00 3.18
2.88E+01 2.63 1.00 3.18
1.17E+01 8.53 1.00 3.18
1.54E+01 4.25 1.00 3.18
4.61E+01 11.40 1.00 3.18
3.28E+01 2.51 1.00 3.18
7.22E+00 4.98 1.00 3.18
2.70E+01 4.98 1.00 3.18
4.52E+01 3.19 1.00 3.18 10000 1000
7.47E+00 5.74 1.00 3.18
6.46E+00 7.48 1.00 3.18
2.34E+01 3.32 1.00 3.18
1.58E+01 10.81 1.00 3.18
3.48E+01 3.39 1.00 3.18
3.69E+01 4.83 1.00 3.18
1.78E+01 6.31 1.00 3.18
2.46E+01 2.62 1.00 3.18
1.76E+01 1.06 1.00 3.18
2.53E+01 3.94 1.00 3.18
2.48E+01 2.61 1.00 3.18
2.79E+01 9.33 1.00 3.18
3.18E+01 6.30 1.00 3.18
1.97E+01 11.13 1.00 3.18
2.99E+01 9.53 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.26E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9. 1 1 E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.95E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36 PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39 PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315 SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-657
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
Mo SWA-L10-1315-T01-A 1 5.26E+00
Mo SWA-L10-1315-T02-A 1 3.81E+00 E
Mo SWA-L10-1315-T03-A 1 4.07E+00
Mo SWA-L10-1315-T04-A 1 6.70E+00
Mo SWA-L10-1315-T05-A 1 5.42E+00
Mo SWA-L10-1315-T06-A 1 6.73E+00
Mo SWA-L10-1315-T07-A 1 5.17E+00
Mo SWA-L10-1315-T08-A 1 3.66E+00 E
Mo SWA-L10-1315-T09-A 1 4.60E+00
Mo SWA-L10-1315-T01-B 1 9.93E+00
Mo SWA-L10-1315-T02-B 1 5.45E+00
Mo SWA-L10-1315-T03-B 1 6.52E+00
Mo SWA-L10-1315-T04-B 1 1.15E+01
Mo SWA-L10-1315-T05-B 1 8.18E+00
Mo SWA-L10-1315-T06-B 1 8.68E+00
Mo SWA-L10-1315-T07-B 1 5.61E+00
Mo SWA-L10-1315-T08-B 1 3.12E+00 E
Mo SWA-L10-1315-T09-B 1 3.49E+00 E
Mo SWA-L10-1315-T01-C 1 4.10E+00
Mo SWA-L10-1315-T02-C 1 5.60E+00
Mo SWA-L10-1315-T03-C 1 5.66E+00
Mo SWA-L10-1315-T04-C 1 1.36E+01
Mo SWA-L10-1315-T05-C 1 1.03E+01
Mo SWA-L10-1315-T06-C 1 9.85E+00
Mo SWA-L10-1315-T07-C 1 7.26E+00
Mo SWA-L10-1315-T08-C 1 4.50E+00
Mo SWA-L10-1315-T09-C 1 5.07E+00
Mo SWA-L10-1315-M01-A 1 6.00E-01 U1/2
Mo SWA-L10-1315-M02-A 1 6.00E-01 U1/2
Mo SWA-L10-1315-M03-A 1 6.00E-01 U1/2
Mo SWA-L10-1315-M04-A 1 6.00E-01 U1/2
Mo SWA-L10-1315-M05-A 1 6.00E-01 U1/2
Mo SWA-L10-1315-M06-A 1 6.00E-01 U1/2
Mo SWA-L10-1315-M07-A 1 6.00E-01 U1/2
Mo SWA-L10-1315-M08-A 1 6.00E-01 U1/2
Mo SWA-L10-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.26E+00 2.50 1.20 3.82
3.81 E+00 3.96 1.20 3.82
4.07E+00 5.62 1.20 3.82 10000 1000
6.70E+00 1.79 1.20 3.82
5.42E+00 2.47 1.20 3.82
6.73E+00 6.18 1.20 3.82
5.17E+00 1.92 1.20 3.82
3.66E+00 9.17 1.20 3.82
4.60E+00 3.70 1.20 3.82
9.93E+00 7.65 1.20 3.82
5.45E+00 10.61 1.20 3.82
6.52E+00 7.82 1.20 3.82 10000 1000
1.15E+01 4.77 1.20 3.82
8.18E+00 1.73 1.20 3.82
8.68E+00 1.50 1.20 3.82
5.61E+00 6.86 1.20 3.82
3.12E+00 24.54 1.20 3.82
3.49E+00 30.45 1.20 3.82
4.10E+00 3.06 1.20 3.82
5.60E+00 1.23 1.20 3.82
5.66E+00 9.23 1.20 3.82 10000 1000
1.36E+01 5.20 1.20 3.82
1.03E+01 8.23 1.20 3.82
9.85E+00 5.51 1.20 3.82
7.26E+00 7.43 1.20 3.82
4.50E+00 16.27 1.20 3.82
5.07E+00 1.51 1.20 3.82
6.00E-01 9.60 1.20 3.82
6.00E-01 34.20 1.20 3.82
6.00E-01 24.25 1.20 3.82
6.00E-01 6.05 1.20 3.82
6.00E-01 23.59 1.20 3.82
6.00E-01 12.44 1.20 3.82
6.00E-01 8.81 1.20 3.82
6.00E-01 15.76 1.20 3.82
6.00E-01 23.36 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.03E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.86E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.32E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26 PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39 PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315 SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-658
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L I
Ni SWA-L10-1315-T01-A 1 9.00E-01 U1/2
Ni SWA-L10-1315-T02-A 1 9.00E-01 U1/2
Ni SWA-L10-1315-T03-A 1 9.00E-01 U1/2
Ni SWA-L10-1315-T04-A 1 9.00E-01 U1/2
Ni SWA-L10-1315-T05-A 1 9.00E-01 U1/2
Ni SWA-L10-1315-T06-A 1 9.00E-01 U1/2
Ni SWA-L10-1315-T07-A 1 9.00E-01 U1/2
Ni SWA-L10-1315-T08-A 1 9.00E-01 U1/2
Ni SWA-L10-1315-T09-A 1 9.00E-01 U1/2
Ni SWA-L10-1315-T01-B 1 9.00E-01 U1/2
Ni SWA-L10-1315-T02-B 1 9.00E-01 U1/2
Ni SWA-L10-1315-T03-B 1 9.00E-01 U1/2
Ni SWA-L10-1315-T04-B 1 9.00E-01 U1/2
Ni SWA-L10-1315-T05-B 1 9.00E-01 U1/2
Ni SWA-L10-1315-T06-B 1 9.00E-01 U1/2
Ni SWA-L10-1315-T07-B 1 9.00E-01 U1/2
Ni SWA-L10-1315-T08-B 1 9.00E-01 U1/2
Ni SWA-L10-1315-T09-B 1 9.00E-01 U1/2
Ni SWA-L10-1315-T01-C 1 9.00E-01 U1/2
Ni SWA-L10-1315-T02-C 1 9.00E-01 U1/2
Ni SWA-L10-1315-T03-C 1 9.00E-01 U1/2
Ni SWA-L10-1315-T04-C 1 9.00E-01 U1/2
Ni SWA-L10-1315-T05-C 1 9.00E-01 U1/2
Ni SWA-L10-1315-T06-C 1 9.00E-01 U1/2
Ni SWA-L10-1315-T07-C 1 9.00E-01 U1/2
Ni SWA-L10-1315-T08-C 1 9.00E-01 U1/2
Ni SWA-L10-1315-T09-C 1 9.00E-01 U1/2
Ni SWA-L10-1315-M01-A 1 9.00E-01 U1/2
Ni SWA-L10-1315-M02-A 1 9.00E-01 U1/2
Ni SWA-L10-1315-M03-A 1 9.00E-01 U1/2
Ni SWA-L10-1315-M04-A 1 9.00E-01 U1/2
Ni SWA-L10-1315-M05-A 1 9.00E-01 U1/2
Ni SWA-L10-1315-M06-A 1 9.00E-01 U1/2
Ni SWA-L10-1315-M07-A 1 9.00E-01 U1/2
Ni SWA-L10-1315-M08-A 1 9.00E-01 U1/2
Ni SWA-L10-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 41.54 1.80 5.70
9.00E-01 3.66 1.80 5.70
9.00E-01 64.79 1.80 5.70 10000 1000
9.00E-01 61.94 1.80 5.70
9.00E-01 11.73 1.80 5.70
9.00E-01 12.23 1.80 5.70
9.00E-01 58.50 1.80 5.70
9.00E-01 82.44 1.80 5.70
9.00E-01 83.79 1.80 5.70
9.00E-01 10.10 1.80 5.70
9.00E-01 45.25 1.80 5.70
9.00E-01 54.10 1.80 5.70 10000 1000
9.00E-01 65.49 1.80 5.70
9.00E-01 13.84 1.80 5.70
9.00E-01 14.99 1.80 5.70
9.00E-01 19.71 1.80 5.70
9.00E-01 16.93 1.80 5.70
9.00E-01 33.03 1.80 5.70
9.00E-01 37.58 1.80 5.70
9.00E-01 86.05 1.80 5.70
9.00E-01 62.10 1.80 5.70 10000 1000
9.00E-01 14.89 1.80 5.70
9.00E-01 83.66 1.80 5.70
9.00E-01 45.57 1.80 5.70
9.00E-01 16.68 1.80 5.70
9.00E-01 42.82 1.80 5.70
9.00E-01 17.64 1.80 5.70
9.00E-01 11.25 1.80 5.70
9.00E-01 49.90 1.80 5.70
9.00E-01 17.30 1.80 5.70
9.00E-01 13.19 1.80 5.70
9.00E-01 28.01 1.80 5.70
9.00E-01 39.06 1.80 5.70
9.00E-01 33.96 1.80 5.70
9.00E-01 44.17 1.80 5.70
9.00E-01 25.40 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.05E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.78E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.43E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26 PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36 PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39 PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-659
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L I
P SWA-L10-1315-T01-A 1 1.85E+00 U1/2
P SWA-L10-1315-T02-A 1 1.85E+00 U1/2
P SWA-L10-1315-T03-A 1 1.85E+00 U1/2
P SWA-L10-1315-T04-A 1 1.85E+00 U1/2
P SWA-L10-1315-T05-A 1 8.27E+00 E
P SWA-L10-1315-T06-A 1 1.85E+00 U1/2
P SWA-L10-1315-T07-A 1 1.85E+00 U1/2
P SWA-L10-1315-T08-A 1 1.85E+00 U1/2
P SWA-L10-1315-T09-A 1 1.85E+00 U1/2
P SWA-L10-1315-T01-B 1 1.36E+01
P SWA-L10-1315-T02-B 1 8.92E+00 E
P SWA-L10-1315-T03-B 1 1.42E+01
P SWA-L10-1315-T04-B 1 2.01 E+01
P SWA-L10-1315-T05-B 1 7.08E+00 E
P SWA-L10-1315-T06-B 1 1.85E+00 U1/2
P SWA-L10-1315-T07-B 1 6.15E+00 E
P SWA-L10-1315-T08-B 1 1.85E+00 U1/2
P SWA-L10-1315-T09-B 1 1.85E+00 U1/2
P SWA-L10-1315-T01-C 1 1.85E+00 U1/2
P SWA-L10-1315-T02-C 1 1.85E+00 U1/2
P SWA-L10-1315-T03-C 1 6.54E+00 E
P SWA-L10-1315-T04-C 1 3.30E+00 U1/2
P SWA-L10-1315-T05-C 1 1.85E+00 U1/2
P SWA-L10-1315-T06-C 1 1.85E+00 U1/2
P SWA-L10-1315-T07-C 1 7.21E+00 E
P SWA-L10-1315-T08-C 1 1.85E+00 U1/2
P SWA-L10-1315-T09-C 1 1.85E+00 U1/2
P SWA-L10-1315-M01-A 1 1.85E+00 U1/2
P SWA-L10-1315-M02-A 1 1.85E+00 U1/2
P SWA-L10-1315-M03-A 1 1.85E+00 U1/2
P SWA-L10-1315-M04-A 1 1.85E+00 U1/2
P SWA-L10-1315-M05-A 1 1.85E+00 U1/2
P SWA-L10-1315-M06-A 1 1.85E+00 U1/2
P SWA-L10-1315-M07-A 1 1.85E+00 U1/2
P SWA-L10-1315-M08-A 1 1.85E+00 U1/2
P SWA-L10-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 70.94 3.70 11.80
1.85E+00 40.34 3.70 11.80
1.85E+00 18.14 3.70 11.80 10000 1000
1.85E+00 58.31 3.70 11.80
8.27E+00 15.17 3.70 11.80
1.85E+00 40.20 3.70 11.80
1.85E+00 11.86 3.70 11.80
1.85E+00 36.28 3.70 11.80
1.85E+00 44.07 3.70 11.80
1.36E+01 4.45 3.70 11.80
8.92E+00 12.19 3.70 11.80
1.42E+01 7.72 3.70 11.80 10000 1000
2.01E+01 11.01 3.70 11.80
7.08E+00 37.79 3.70 11.80
1.85E+00 53.78 3.70 11.80
6.15E+00 29.20 3.70 11.80
1.85E+00 15.13 3.70 11.80
1.85E+00 57.16 3.70 11.80
1.85E+00 40.67 3.70 11.80
1.85E+00 48.77 3.70 11.80
6.54E+00 18.99 3.70 11.80 10000 1000
3.30E+00 80.13 3.70 11.80
1.85E+00 20.66 3.70 11.80
1.85E+00 24.89 3.70 11.80
7.21E+00 19.85 3.70 11.80
1.85E+00 67.49 3.70 11.80
1.85E+00 24.00 3.70 11.80
1.85E+00 62.52 3.70 11.80
1.85E+00 98.62 3.70 11.80
1.85E+00 26.01 3.70 11.80
1.85E+00 18.49 3.70 11.80
1.85E+00 13.26 3.70 11.80
1.85E+00 30.10 3.70 11.80
1.85E+00 73.06 3.70 11.80
1.85E+00 15.82 3.70 11.80
1.85E+00 92.37 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.91 E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.64E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.95E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26 PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39 PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315 SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-660
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
K SWA-L10-1315-T01-A 1 1.08E+04
K SWA-L10-1315-T02-A 1 1.16E+04
K SWA-L10-1315-T03-A 1 1.12E+04
K SWA-L10-1315-T04-A 1 3.31E+04
K SWA-L10-1315-T05-A 1 2.75E+04
K SWA-L10-1315-T06-A 1 3.61 E+04
K SWA-L10-1315-T07-A 1 2. 81 E+04
K SWA-L10-1315-T08-A 1 1.21E+04
K SWA-L10-1315-T09-A 1 1.83E+04
K SWA-L10-1315-T01-B 1 1.16E+04
K SWA-L10-1315-T02-B 1 1.54E+04
K SWA-L10-1315-T03-B 1 1.50E+04
K SWA-L10-1315-T04-B 1 4.49E+04
K SWA-L10-1315-T05-B 1 3.46E+04
K SWA-L10-1315-T06-B 1 4.09E+04
K SWA-L10-1315-T07-B 1 2.99E+04
K SWA-L10-1315-T08-B 1 1.21E+04
K SWA-L10-1315-T09-B 1 1.84E+04
K SWA-L10-1315-T01-C 1 1.07E+04
K SWA-L10-1315-T02-C 1 1.69E+04
K SWA-L10-1315-T03-C 1 2.22E+04
K SWA-L10-1315-T04-C 1 6.09E+04
K SWA-L10-1315-T05-C 1 4.52E+04
K SWA-L10-1315-T06-C 1 5.20E+04
K SWA-L10-1315-T07-C 1 3.80E+04
K SWA-L10-1315-T08-C 1 1.51E+04
K SWA-L10-1315-T09-C 1 2.26E+04
K SWA-L10-1315-M01-A 1 3.39E+01
K SWA-L10-1315-M02-A 1 2.74E+01
K SWA-L10-1315-M03-A 1 1.72E+01
K SWA-L10-1315-M04-A 1 2.36E+01
K SWA-L10-1315-M05-A 1 9.78E+00
K SWA-L10-1315-M06-A 1 1.59E+01
K SWA-L10-1315-M07-A 1 4.19E+00 E
K SWA-L10-1315-M08-A 1 6.85E+00
K SWA-L10-1315-M09-A 1 1.32E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.08E+04 0.60 1.60 5.09
1.16E+04 0.22 1.60 5.09
1.12E+04 0.49 1.60 5.09 10000 1000
3.31E+04 0.43 1.60 5.09
2.75E+04 1.24 1.60 5.09
3.61E+04 2.76 1.60 5.09
2.81E+04 0.54 1.60 5.09
1.21E+04 0.11 1.60 5.09
1.83E+04 0.24 1.60 5.09
1.16E+04 0.54 1.60 5.09
1.54E+04 0.72 1.60 5.09
1.50E+04 0.72 1.60 5.09 10000 1000
4.49E+04 0.43 1.60 5.09
3.46E+04 0.31 1.60 5.09
4.09E+04 0.94 1.60 5.09
2.99E+04 1.22 1.60 5.09
1.21E+04 0.83 1.60 5.09
1.84E+04 0.76 1.60 5.09
1.07E+04 0.88 1.60 5.09
1.69E+04 1.16 1.60 5.09
2.22E+04 0.86 1.60 5.09 10000 1000
6.09E+04 0.30 1.60 5.09
4.52E+04 0.32 1.60 5.09
5.20E+04 0.81 1.60 5.09
3.80E+04 0.32 1.60 5.09
1.51E+04 0.52 1.60 5.09
2.26E+04 3.06 1.60 5.09
3.39E+01 3.51 1.60 5.09
2.74E+01 1.84 1.60 5.09
1.72E+01 13.09 1.60 5.09
2.36E+01 9.79 1.60 5.09
9.78E+00 9.48 1.60 5.09
1.59E+01 3.21 1.60 5.09
4.19E+00 1.85 1.60 5.09
6.85E+00 7.39 1.60 5.09
1.32E+01 4.79 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.21 E+04 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.59E+04 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.31 E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36 PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39 PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315 SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-661
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Se SWA-L10-1315-T01-A 1 2.08E+03
Se SWA-L10-1315-T02-A 1 1.54E+03
Se SWA-L10-1315-T03-A 1 2.87E+03
Se SWA-L10-1315-T04-A 1 6.42E+03
Se SWA-L10-1315-T05-A 1 4.13E+03
Se SWA-L10-1315-T06-A 1 4.34E+03
Se SWA-L10-1315-T07-A 1 2.28E+03
Se SWA-L10-1315-T08-A 1 1.19E+03
Se SWA-L10-1315-T09-A 1 1.57E+03
Se SWA-L10-1315-T01-B 1 2.64E+03
Se SWA-L10-1315-T02-B 1 1.81E+03
Se SWA-L10-1315-T03-B 1 1.83E+03
Se SWA-L10-1315-T04-B 1 5.23E+03
Se SWA-L10-1315-T05-B 1 3.57E+03
Se SWA-L10-1315-T06-B 1 3.87E+03
Se SWA-L10-1315-T07-B 1 2.42E+03
Se SWA-L10-1315-T08-B 1 8.63E+02
Se SWA-L10-1315-T09-B 1 1.40E+03
Se SWA-L10-1315-T01-C 1 2.38E+03
Se SWA-L10-1315-T02-C 1 1.86E+03
Se SWA-L10-1315-T03-C 1 2.87E+03
Se SWA-L10-1315-T04-C 1 7.02E+03
Se SWA-L10-1315-T05-C 1 4.49E+03
Se SWA-L10-1315-T06-C 1 4.63E+03
Se SWA-L10-1315-T07-C 1 2.85E+03
Se SWA-L10-1315-T08-C 1 1.03E+03
Se SWA-L10-1315-T09-C 1 1.71E+03
Se SWA-L10-1315-M01-A 1 7.50E+00 U1/2
Se SWA-L10-1315-M02-A 1 7.50E+00 U1/2
Se SWA-L10-1315-M03-A 1 7.50E+00 U1/2
Se SWA-L10-1315-M04-A 1 7.50E+00 U1/2
Se SWA-L10-1315-M05-A 1 7.50E+00 U1/2
Se SWA-L10-1315-M06-A 1 7.50E+00 U1/2
Se SWA-L10-1315-M07-A 1 7.50E+00 U1/2
Se SWA-L10-1315-M08-A 1 7.50E+00 U1/2
Se SWA-L10-1315-M09-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.08E+03 0.39 15.00 47.70
1.54E+03 1.16 15.00 47.70
2.87E+03 0.50 15.00 47.70 10000 1000
6.42E+03 0.48 15.00 47.70
4.13E+03 1.36 15.00 47.70
4.34E+03 3.40 15.00 47.70
2.28E+03 1.84 15.00 47.70
1.19E+03 2.40 15.00 47.70
1.57E+03 0.74 15.00 47.70
2.64E+03 1.18 15.00 47.70
1.81E+03 1.45 15.00 47.70
1.83E+03 0.09 15.00 47.70 10000 1000
5.23E+03 0.58 15.00 47.70
3.57E+03 0.33 15.00 47.70
3.87E+03 1.05 15.00 47.70
2.42E+03 0.39 15.00 47.70
8.63E+02 2.92 15.00 47.70
1.40E+03 0.26 15.00 47.70
2.38E+03 2.56 15.00 47.70
1.86E+03 1.76 15.00 47.70
2.87E+03 0.05 15.00 47.70 10000 1000
7.02E+03 0.71 15.00 47.70
4.49E+03 0.76 15.00 47.70
4.63E+03 0.68 15.00 47.70
2.85E+03 1.08 15.00 47.70
1.03E+03 1.53 15.00 47.70
1.71E+03 4.63 15.00 47.70
7.50E+00 10.12 15.00 47.70
7.50E+00 19.84 15.00 47.70
7.50E+00 43.04 15.00 47.70
7.50E+00 64.84 15.00 47.70
7.50E+00 11.54 15.00 47.70
7.50E+00 18.27 15.00 47.70
7.50E+00 26.13 15.00 47.70
7.50E+00 49.27 15.00 47.70
7.50E+00 22.19 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.74E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.69E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.72E+03 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36 PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315 SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-662
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Si SWA-L10-1315-T01-A 1 7.21E+02
Si SWA-L10-1315-T02-A 1 1.50E+03
Si SWA-L10-1315-T03-A 1 2.64E+03
Si SWA-L10-1315-T04-A 1 7.13E+03
Si SWA-L10-1315-T05-A 1 7.12E+03
Si SWA-L10-1315-T06-A 1 8.63E+03
Si SWA-L10-1315-T07-A 1 8.19E+03
Si SWA-L10-1315-T08-A 1 6.17E+03
Si SWA-L10-1315-T09-A 1 7.98E+03
Si SWA-L10-1315-T01-B 1 9.84E+02
Si SWA-L10-1315-T02-B 1 2.18E+03
Si SWA-L10-1315-T03-B 1 3.24E+03
Si SWA-L10-1315-T04-B 1 7.62E+03
Si SWA-L10-1315-T05-B 1 7.39E+03
Si SWA-L10-1315-T06-B 1 8.36E+03
Si SWA-L10-1315-T07-B 1 7.98E+03
Si SWA-L10-1315-T08-B 1 5.96E+03
Si SWA-L10-1315-T09-B 1 7.49E+03
Si SWA-L10-1315-T01-C 1 8.62E+02
Si SWA-L10-1315-T02-C 1 2.09E+03
Si SWA-L10-1315-T03-C 1 3.39E+03
Si SWA-L10-1315-T04-C 1 8.18E+03
Si SWA-L10-1315-T05-C 1 7.74E+03
Si SWA-L10-1315-T06-C 1 8.69E+03
Si SWA-L10-1315-T07-C 1 8.12E+03
Si SWA-L10-1315-T08-C 1 6.08E+03
Si SWA-L10-1315-T09-C 1 7.86E+03
Si SWA-L10-1315-M01-A 1 5.50E-01 U1/2
Si SWA-L10-1315-M02-A 1 5.50E-01 U1/2
Si SWA-L10-1315-M03-A 1 5.50E-01 U1/2
Si SWA-L10-1315-M04-A 1 5.50E-01 U1/2
Si SWA-L10-1315-M05-A 1 5.50E-01 U1/2
Si SWA-L10-1315-M06-A 1 5.50E-01 U1/2
Si SWA-L10-1315-M07-A 1 5.50E-01 U1/2
Si SWA-L10-1315-M08-A 1 5.50E-01 U1/2
Si SWA-L10-1315-M09-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.21 E+02 0.31 1.10 3.50
1.50E+03 0.62 1.10 3.50
2.64E+03 0.30 1.10 3.50 10000 1000
7.13E+03 0.52 1.10 3.50
7.12E+03 2.28 1.10 3.50
8.63E+03 3.52 1.10 3.50
8.19E+03 1.03 1.10 3.50
6.17E+03 1.45 1.10 3.50
7.98E+03 0.87 1.10 3.50
9.84E+02 1.33 1.10 3.50
2.18E+03 0.82 1.10 3.50
3.24E+03 0.75 1.10 3.50 10000 1000
7.62E+03 1.08 1.10 3.50
7.39E+03 0.83 1.10 3.50
8.36E+03 0.76 1.10 3.50
7.98E+03 1.16 1.10 3.50
5.96E+03 0.83 1.10 3.50
7.49E+03 1.30 1.10 3.50
8.62E+02 1.95 1.10 3.50
2.09E+03 0.85 1.10 3.50
3.39E+03 0.48 1.10 3.50 10000 1000
8.18E+03 0.21 1.10 3.50
7.74E+03 0.52 1.10 3.50
8.69E+03 0.45 1.10 3.50
8.12E+03 1.00 1.10 3.50
6.08E+03 0.28 1.10 3.50
7.86E+03 3.71 1.10 3.50
5.50E-01 12.32 1.10 3.50
5.50E-01 8.79 1.10 3.50
5.50E-01 24.29 1.10 3.50
5.50E-01 16.81 1.10 3.50
5.50E-01 8.02 1.10 3.50
5.50E-01 29.76 1.10 3.50
5.50E-01 20.67 1.10 3.50
5.50E-01 36.35 1.10 3.50
5.50E-01 9.36 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.55E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.15E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.25E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26 PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36 PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39 PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-663
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
Na SWA-L10-1315-T01-A 1 4.75E+04
Na SWA-L10-1315-T02-A 1 4.72E+04
Na SWA-L10-1315-T03-A 1 4.83E+04
Na SWA-L10-1315-T04-A 1 1.08E+05
Na SWA-L10-1315-T05-A 1 9.59E+04
Na SWA-L10-1315-T06-A 1 1.17E+05
Na SWA-L10-1315-T07-A 1 9.75E+04
Na SWA-L10-1315-T08-A 1 5.27E+04
Na SWA-L10-1315-T09-A 1 7.50E+04
Na SWA-L10-1315-T01-B 1 5.07E+04
Na SWA-L10-1315-T02-B 1 6.15E+04
Na SWA-L10-1315-T03-B 1 6.11E+04
Na SWA-L10-1315-T04-B 1 1.33E+05
Na SWA-L10-1315-T05-B 1 1.12E+05
Na SWA-L10-1315-T06-B 1 1.27E+05
Na SWA-L10-1315-T07-B 1 1.02E+05
Na SWA-L10-1315-T08-B 1 5.19E+04
Na SWA-L10-1315-T09-B 1 7.32E+04
Na SWA-L10-1315-T01-C 1 4.71E+04
Na SWA-L10-1315-T02-C 1 6.63E+04
Na SWA-L10-1315-T03-C 1 8.03E+04
Na SWA-L10-1315-T04-C 1 1.60E+05
Na SWA-L10-1315-T05-C 1 1.34E+05
Na SWA-L10-1315-T06-C 1 1.48E+05
Na SWA-L10-1315-T07-C 1 1.18E+05
Na SWA-L10-1315-T08-C 1 6.17E+04
Na SWA-L10-1315-T09-C 1 8.36E+04
Na SWA-L10-1315-M01-A 1 3.23E+01
Na SWA-L10-1315-M02-A 1 4.06E+01
Na SWA-L10-1315-M03-A 1 3.09E+01
Na SWA-L10-1315-M04-A 1 3.36E+01
Na SWA-L10-1315-M05-A 1 2.44E+01
Na SWA-L10-1315-M06-A 1 2.37E+01
Na SWA-L10-1315-M07-A 1 2.84E+01
Na SWA-L10-1315-M08-A 1 2.23E+01
Na SWA-L10-1315-M09-A 1 2.34E+01
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.75E+04 0.79 2.50 8.00
4.72E+04 0.54 2.50 8.00
4.83E+04 0.09 2.50 8.00 10000 1000
1.08E+05 0.37 2.50 8.00
9.59E+04 0.60 2.50 8.00
1.17E+05 0.66 2.50 8.00
9.75E+04 0.75 2.50 8.00
5.27E+04 0.71 2.50 8.00
7.50E+04 0.34 2.50 8.00
5.07E+04 0.47 2.50 8.00
6.15E+04 0.35 2.50 8.00
6.11E+04 0.36 2.50 8.00 10000 1000
1.33E+05 0.23 2.50 8.00
1.12E+05 0.41 2.50 8.00
1.27E+05 0.20 2.50 8.00
1.02E+05 0.27 2.50 8.00
5.19E+04 0.11 2.50 8.00
7.32E+04 1.11 2.50 8.00
4.71 E+04 0.34 2.50 8.00
6.63E+04 0.85 2.50 8.00
8.03E+04 0.36 2.50 8.00 10000 1000
1.60E+05 0.58 2.50 8.00
1.34E+05 0.91 2.50 8.00
1.48E+05 0.21 2.50 8.00
1.18E+05 0.41 2.50 8.00
6.17E+04 0.27 2.50 8.00
8.36E+04 1.29 2.50 8.00
3.23E+01 5.88 2.50 8.00
4.06E+01 0.87 2.50 8.00
3.09E+01 3.08 2.50 8.00
3.36E+01 6.07 2.50 8.00
2.44E+01 3.86 2.50 8.00
2.37E+01 7.71 2.50 8.00
2.84E+01 5.13 2.50 8.00
2.23E+01 3.60 2.50 8.00
2.34E+01 10.47 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.92E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.20E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.12E+04 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26 PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36 PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39 PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-664
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
Sr SWA-L10-1315-T01-A 1 1.82E+01
Sr SWA-L10-1315-T02-A 1 8.25E+01
Sr SWA-L10-1315-T03-A 1 1.12E+02
Sr SWA-L10-1315-T04-A 1 2.26E+02
Sr SWA-L10-1315-T05-A 1 2.24E+02
Sr SWA-L10-1315-T06-A 1 2.42E+02
Sr SWA-L10-1315-T07-A 1 2.42E+02
Sr SWA-L10-1315-T08-A 1 1.90E+02
Sr SWA-L10-1315-T09-A 1 1.92E+02
Sr SWA-L10-1315-T01-B 1 2.46E+01
Sr SWA-L10-1315-T02-B 1 1.02E+02
Sr SWA-L10-1315-T03-B 1 1.25E+02
Sr SWA-L10-1315-T04-B 1 2.39E+02
Sr SWA-L10-1315-T05-B 1 2.43E+02
Sr SWA-L10-1315-T06-B 1 2.69E+02
Sr SWA-L10-1315-T07-B 1 2.76E+02
Sr SWA-L10-1315-T08-B 1 2.19E+02
Sr SWA-L10-1315-T09-B 1 2.29E+02
Sr SWA-L10-1315-T01-C 1 1.72E+01
Sr SWA-L10-1315-T02-C 1 9.31E+01
Sr SWA-L10-1315-T03-C 1 1.17E+02
Sr SWA-L10-1315-T04-C 1 2.20E+02
Sr SWA-L10-1315-T05-C 1 2.25E+02
Sr SWA-L10-1315-T06-C 1 2.55E+02
Sr SWA-L10-1315-T07-C 1 2.55E+02
Sr SWA-L10-1315-T08-C 1 2.08E+02
Sr SWA-L10-1315-T09-C 1 2.22E+02
Sr SWA-L10-1315-M01-A 1 5.00E-01 U1/2
Sr SWA-L10-1315-M02-A 1 5.00E-01 U1/2
Sr SWA-L10-1315-M03-A 1 5.00E-01 U1/2
Sr SWA-L10-1315-M04-A 1 5.00E-01 U1/2
Sr SWA-L10-1315-M05-A 1 5.00E-01 U1/2
Sr SWA-L10-1315-M06-A 1 5.00E-01 U1/2
Sr SWA-L10-1315-M07-A 1 5.00E-01 U1/2
Sr SWA-L10-1315-M08-A 1 5.00E-01 U1/2
Sr SWA-L10-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.82E+01 0.54 1.00 3.18
8.25E+01 1.17 1.00 3.18
1.12E+02 0.63 1.00 3.18 10000 1000
2.26E+02 1.07 1.00 3.18
2.24E+02 0.52 1.00 3.18
2.42E+02 3.53 1.00 3.18
2.42E+02 0.58 1.00 3.18
1.90E+02 0.41 1.00 3.18
1.92E+02 0.25 1.00 3.18
2.46E+01 2.50 1.00 3.18
1.02E+02 1.23 1.00 3.18
1.25E+02 1.58 1.00 3.18 10000 1000
2.39E+02 0.79 1.00 3.18
2.43E+02 0.60 1.00 3.18
2.69E+02 0.64 1.00 3.18
2.76E+02 0.76 1.00 3.18
2.19E+02 0.94 1.00 3.18
2.29E+02 0.65 1.00 3.18
1.72E+01 4.86 1.00 3.18
9.31E+01 1.54 1.00 3.18
1.17E+02 1.24 1.00 3.18 10000 1000
2.20E+02 0.75 1.00 3.18
2.25E+02 0.62 1.00 3.18
2.55E+02 0.62 1.00 3.18
2.55E+02 0.73 1.00 3.18
2.08E+02 0.37 1.00 3.18
2.22E+02 3.59 1.00 3.18
5.00E-01 13.49 1.00 3.18
5.00E-01 17.62 1.00 3.18
5.00E-01 29.30 1.00 3.18
5.00E-01 49.51 1.00 3.18
5.00E-01 52.48 1.00 3.18
5.00E-01 29.12 1.00 3.18
5.00E-01 44.28 1.00 3.18
5.00E-01 36.88 1.00 3.18
5.00E-01 11.87 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.71 E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.77E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36 PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39 PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315 SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-665
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
S SWA-L10-1315-T01-A 1 2.78E+03
S SWA-L10-1315-T02-A 1 5.62E+03
S SWA-L10-1315-T03-A 1 4.03E+03
S SWA-L10-1315-T04-A 1 1.20E+04
S SWA-L10-1315-T05-A 1 9.85E+03
S SWA-L10-1315-T06-A 1 1.21E+04
S SWA-L10-1315-T07-A 1 7.73E+03
S SWA-L10-1315-T08-A 1 2.52E+03
S SWA-L10-1315-T09-A 1 4.71E+03
S SWA-L10-1315-T01-B 1 2.11E+03
S SWA-L10-1315-T02-B 1 5.60E+03
S SWA-L10-1315-T03-B 1 8.26E+03
S SWA-L10-1315-T04-B 1 2.45E+04
S SWA-L10-1315-T05-B 1 1.71E+04
S SWA-L10-1315-T06-B 1 1.78E+04
S SWA-L10-1315-T07-B 1 9.38E+03
S SWA-L10-1315-T08-B 1 3.41E+03
S SWA-L10-1315-T09-B 1 5.92E+03
S SWA-L10-1315-T01-C 1 2.12E+03
S SWA-L10-1315-T02-C 1 5.46E+03
S SWA-L10-1315-T03-C 1 1.34E+04
S SWA-L10-1315-T04-C 1 2.84E+04
S SWA-L10-1315-T05-C 1 2.26E+04
S SWA-L10-1315-T06-C 1 2.13E+04
S SWA-L10-1315-T07-C 1 1.39E+04
S SWA-L10-1315-T08-C 1 4.13E+03
S SWA-L10-1315-T09-C 1 7.18E+03
S SWA-L10-1315-M01-A 1 3.40E+00 U1/2
S SWA-L10-1315-M02-A 1 3.40E+00 U1/2
S SWA-L10-1315-M03-A 1 3.40E+00 U1/2
S SWA-L10-1315-M04-A 1 3.40E+00 U1/2
S SWA-L10-1315-M05-A 1 3.40E+00 U1/2
S SWA-L10-1315-M06-A 1 3.40E+00 U1/2
S SWA-L10-1315-M07-A 1 3.40E+00 U1/2
S SWA-L10-1315-M08-A 1 3.40E+00 U1/2
S SWA-L10-1315-M09-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.78E+03 0.12 6.80 21.60
5.62E+03 2.05 6.80 21.60
4.03E+03 1.01 6.80 21.60 10000 1000
1.20E+04 1.25 6.80 21.60
9.85E+03 1.92 6.80 21.60
1.21E+04 3.60 6.80 21.60
7.73E+03 0.83 6.80 21.60
2.52E+03 1.67 6.80 21.60
4.71E+03 1.31 6.80 21.60
2.11E+03 0.53 6.80 21.60
5.60E+03 1.66 6.80 21.60
8.26E+03 1.30 6.80 21.60 10000 1000
2.45E+04 0.72 6.80 21.60
1.71E+04 0.71 6.80 21.60
1.78E+04 0.61 6.80 21.60
9.38E+03 1.25 6.80 21.60
3.41E+03 0.51 6.80 21.60
5.92E+03 0.27 6.80 21.60
2.12E+03 2.04 6.80 21.60
5.46E+03 2.01 6.80 21.60
1.34E+04 0.48 6.80 21.60 10000 1000
2.84E+04 0.55 6.80 21.60
2.26E+04 1.29 6.80 21.60
2.13E+04 0.81 6.80 21.60
1.39E+04 0.19 6.80 21.60
4.13E+03 0.47 6.80 21.60
7.18E+03 2.61 6.80 21.60
3.40E+00 2.19 6.80 21.60
3.40E+00 3.02 6.80 21.60
3.40E+00 3.21 6.80 21.60
3.40E+00 4.01 6.80 21.60
3.40E+00 2.89 6.80 21.60
3.40E+00 1.70 6.80 21.60
3.40E+00 3.10 6.80 21.60
3.40E+00 1.41 6.80 21.60
3.40E+00 1.77 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.98E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.15E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.43E+04 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36 PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315 SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-666
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Tl SWA-L10-1315-T01-A 1 2.30E+00 U1/2
Tl SWA-L10-1315-T02-A 1 2.30E+00 U1/2
Tl SWA-L10-1315-T03-A 1 2.30E+00 U1/2
Tl SWA-L10-1315-T04-A 1 2.30E+00 U1/2
Tl SWA-L10-1315-T05-A 1 2.30E+00 U1/2
Tl SWA-L10-1315-T06-A 1 2.30E+00 U1/2
Tl SWA-L10-1315-T07-A 1 2.30E+00 U1/2
Tl SWA-L10-1315-T08-A 1 2.30E+00 U1/2
Tl SWA-L10-1315-T09-A 1 2.30E+00 U1/2
Tl SWA-L10-1315-T01-B 1 2.30E+00 U1/2
Tl SWA-L10-1315-T02-B 1 2.30E+00 U1/2
Tl SWA-L10-1315-T03-B 1 2.30E+00 U1/2
Tl SWA-L10-1315-T04-B 1 2.30E+00 U1/2
Tl SWA-L10-1315-T05-B 1 2.30E+00 U1/2
Tl SWA-L10-1315-T06-B 1 2.30E+00 U1/2
Tl SWA-L10-1315-T07-B 1 2.30E+00 U1/2
Tl SWA-L10-1315-T08-B 1 2.30E+00 U1/2
Tl SWA-L10-1315-T09-B 1 2.30E+00 U1/2
Tl SWA-L10-1315-T01-C 1 2.30E+00 U1/2
Tl SWA-L10-1315-T02-C 1 2.30E+00 U1/2
Tl SWA-L10-1315-T03-C 1 2.30E+00 U1/2
Tl SWA-L10-1315-T04-C 1 2.30E+00 U1/2
Tl SWA-L10-1315-T05-C 1 2.30E+00 U1/2
Tl SWA-L10-1315-T06-C 1 2.30E+00 U1/2
Tl SWA-L10-1315-T07-C 1 2.30E+00 U1/2
Tl SWA-L10-1315-T08-C 1 2.30E+00 U1/2
Tl SWA-L10-1315-T09-C 1 2.30E+00 U1/2
Tl SWA-L10-1315-M01-A 1 2.30E+00 U1/2
Tl SWA-L10-1315-M02-A 1 2.30E+00 U1/2
Tl SWA-L10-1315-M03-A 1 2.30E+00 U1/2
Tl SWA-L10-1315-M04-A 1 2.30E+00 U1/2
Tl SWA-L10-1315-M05-A 1 2.30E+00 U1/2
Tl SWA-L10-1315-M06-A 1 2.30E+00 U1/2
Tl SWA-L10-1315-M07-A 1 2.30E+00 U1/2
Tl SWA-L10-1315-M08-A 1 2.30E+00 U1/2
Tl SWA-L10-1315-M09-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 35.46 4.60 14.60
2.30E+00 16.33 4.60 14.60
2.30E+00 6.63 4.60 14.60 10000 1000
2.30E+00 17.69 4.60 14.60
2.30E+00 28.93 4.60 14.60
2.30E+00 46.47 4.60 14.60
2.30E+00 13.11 4.60 14.60
2.30E+00 15.95 4.60 14.60
2.30E+00 26.58 4.60 14.60
2.30E+00 37.99 4.60 14.60
2.30E+00 10.17 4.60 14.60
2.30E+00 10.22 4.60 14.60 10000 1000
2.30E+00 82.15 4.60 14.60
2.30E+00 11.13 4.60 14.60
2.30E+00 8.61 4.60 14.60
2.30E+00 20.30 4.60 14.60
2.30E+00 8.67 4.60 14.60
2.30E+00 7.54 4.60 14.60
2.30E+00 6.16 4.60 14.60
2.30E+00 29.17 4.60 14.60
2.30E+00 23.98 4.60 14.60 10000 1000
2.30E+00 18.61 4.60 14.60
2.30E+00 29.25 4.60 14.60
2.30E+00 22.85 4.60 14.60
2.30E+00 16.22 4.60 14.60
2.30E+00 15.66 4.60 14.60
2.30E+00 46.52 4.60 14.60
2.30E+00 21.95 4.60 14.60
2.30E+00 66.89 4.60 14.60
2.30E+00 23.13 4.60 14.60
2.30E+00 12.59 4.60 14.60
2.30E+00 32.12 4.60 14.60
2.30E+00 15.74 4.60 14.60
2.30E+00 12.57 4.60 14.60
2.30E+00 41.90 4.60 14.60
2.30E+00 34.68 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.84E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.77E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.30E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26 PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39 PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315 SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-667
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Ti SWA-L10-1315-T01-A 1 1.00E+00 U1/2
Ti SWA-L10-1315-T02-A 1 1.00E+00 U1/2
Ti SWA-L10-1315-T03-A 1 1.00E+00 U1/2
Ti SWA-L10-1315-T04-A 1 1.00E+00 U1/2
Ti SWA-L10-1315-T05-A 1 1.00E+00 U1/2
Ti SWA-L10-1315-T06-A 1 1.00E+00 U1/2
Ti SWA-L10-1315-T07-A 1 1.00E+00 U1/2
Ti SWA-L10-1315-T08-A 1 1.00E+00 U1/2
Ti SWA-L10-1315-T09-A 1 1.00E+00 U1/2
Ti SWA-L10-1315-T01-B 1 1.00E+00 U1/2
Ti SWA-L10-1315-T02-B 1 1.00E+00 U1/2
Ti SWA-L10-1315-T03-B 1 1.00E+00 U1/2
Ti SWA-L10-1315-T04-B 1 1.00E+00 U1/2
Ti SWA-L10-1315-T05-B 1 1.00E+00 U1/2
Ti SWA-L10-1315-T06-B 1 1.00E+00 U1/2
Ti SWA-L10-1315-T07-B 1 1.00E+00 U1/2
Ti SWA-L10-1315-T08-B 1 1.00E+00 U1/2
Ti SWA-L10-1315-T09-B 1 1.00E+00 U1/2
Ti SWA-L10-1315-T01-C 1 1.00E+00 U1/2
Ti SWA-L10-1315-T02-C 1 1.00E+00 U1/2
Ti SWA-L10-1315-T03-C 1 1.00E+00 U1/2
Ti SWA-L10-1315-T04-C 1 1.00E+00 U1/2
Ti SWA-L10-1315-T05-C 1 1.00E+00 U1/2
Ti SWA-L10-1315-T06-C 1 1.00E+00 U1/2
Ti SWA-L10-1315-T07-C 1 1.00E+00 U1/2
Ti SWA-L10-1315-T08-C 1 1.00E+00 U1/2
Ti SWA-L10-1315-T09-C 1 1.00E+00 U1/2
Ti SWA-L10-1315-M01-A 1 1.00E+00 U1/2
Ti SWA-L10-1315-M02-A 1 1.00E+00 U1/2
Ti SWA-L10-1315-M03-A 1 1.00E+00 U1/2
Ti SWA-L10-1315-M04-A 1 1.00E+00 U1/2
Ti SWA-L10-1315-M05-A 1 1.00E+00 U1/2
Ti SWA-L10-1315-M06-A 1 1.00E+00 U1/2
Ti SWA-L10-1315-M07-A 1 1.00E+00 U1/2
Ti SWA-L10-1315-M08-A 1 1.00E+00 U1/2
Ti SWA-L10-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 10.83 2.00 6.40
1.00E+00 54.06 2.00 6.40
1.00E+00 51.61 2.00 6.40 10000 1000
1.00E+00 11.94 2.00 6.40
1.00E+00 83.62 2.00 6.40
1.00E+00 72.80 2.00 6.40
1.00E+00 11.53 2.00 6.40
1.00E+00 79.46 2.00 6.40
1.00E+00 48.41 2.00 6.40
1.00E+00 27.77 2.00 6.40
1.00E+00 89.59 2.00 6.40
1.00E+00 17.69 2.00 6.40 10000 1000
1.00E+00 33.30 2.00 6.40
1.00E+00 17.28 2.00 6.40
1.00E+00 20.00 2.00 6.40
1.00E+00 13.30 2.00 6.40
1.00E+00 31.92 2.00 6.40
1.00E+00 36.05 2.00 6.40
1.00E+00 34.38 2.00 6.40
1.00E+00 35.94 2.00 6.40
1.00E+00 61.58 2.00 6.40 10000 1000
1.00E+00 74.46 2.00 6.40
1.00E+00 81.69 2.00 6.40
1.00E+00 45.12 2.00 6.40
1.00E+00 11.46 2.00 6.40
1.00E+00 49.80 2.00 6.40
1.00E+00 95.27 2.00 6.40
1.00E+00 81.51 2.00 6.40
1.00E+00 73.37 2.00 6.40
1.00E+00 10.33 2.00 6.40
1.00E+00 33.21 2.00 6.40
1.00E+00 29.93 2.00 6.40
1.00E+00 16.74 2.00 6.40
1.00E+00 10.98 2.00 6.40
1.00E+00 37.23 2.00 6.40
1.00E+00 74.87 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.40E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.80E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.93E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26 PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36 PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39 PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-668
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L I
V SWA-L10-1315-T01-A 1 1.18E+01
V SWA-L10-1315-T02-A 1 8.88E+00
V SWA-L10-1315-T03-A 1 1.08E+01
V SWA-L10-1315-T04-A 1 2.07E+01
V SWA-L10-1315-T05-A 1 1.79E+01
V SWA-L10-1315-T06-A 1 2.10E+01
V SWA-L10-1315-T07-A 1 1.85E+01
V SWA-L10-1315-T08-A 1 1.31E+01
V SWA-L10-1315-T09-A 1 1.63E+01
V SWA-L10-1315-T01-B 1 1.47E+01
V SWA-L10-1315-T02-B 1 1.17E+01
V SWA-L10-1315-T03-B 1 1.36E+01
V SWA-L10-1315-T04-B 1 2.59E+01
V SWA-L10-1315-T05-B 1 2.15E+01
V SWA-L10-1315-T06-B 1 2.40E+01
V SWA-L10-1315-T07-B 1 2.09E+01
V SWA-L10-1315-T08-B 1 1.38E+01
V SWA-L10-1315-T09-B 1 1.72E+01
V SWA-L10-1315-T01-C 1 1.14E+01
V SWA-L10-1315-T02-C 1 1.16E+01
V SWA-L10-1315-T03-C 1 1.61E+01
V SWA-L10-1315-T04-C 1 3.03E+01
V SWA-L10-1315-T05-C 1 2.35E+01
V SWA-L10-1315-T06-C 1 2.49E+01
V SWA-L10-1315-T07-C 1 2.06E+01
V SWA-L10-1315-T08-C 1 1.38E+01
V SWA-L10-1315-T09-C 1 1.78E+01
V SWA-L10-1315-M01-A 1 7.50E-01 U1/2
V SWA-L10-1315-M02-A 1 7.50E-01 U1/2
V SWA-L10-1315-M03-A 1 7.50E-01 U1/2
V SWA-L10-1315-M04-A 1 7.50E-01 U1/2
V SWA-L10-1315-M05-A 1 7.50E-01 U1/2
V SWA-L10-1315-M06-A 1 7.50E-01 U1/2
V SWA-L10-1315-M07-A 1 7.50E-01 U1/2
V SWA-L10-1315-M08-A 1 7.50E-01 U1/2
V SWA-L10-1315-M09-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.18E+01 2.45 1.50 4.77
8.88E+00 4.46 1.50 4.77
1.08E+01 5.33 1.50 4.77 10000 1000
2.07E+01 2.64 1.50 4.77
1.79E+01 4.84 1.50 4.77
2.10E+01 7.55 1.50 4.77
1.85E+01 3.61 1.50 4.77
1.31E+01 3.05 1.50 4.77
1.63E+01 4.22 1.50 4.77
1.47E+01 7.67 1.50 4.77
1.17E+01 3.76 1.50 4.77
1.36E+01 2.84 1.50 4.77 10000 1000
2.59E+01 1.65 1.50 4.77
2.15E+01 5.36 1.50 4.77
2.40E+01 1.67 1.50 4.77
2.09E+01 4.46 1.50 4.77
1.38E+01 3.82 1.50 4.77
1.72E+01 4.88 1.50 4.77
1.14E+01 9.46 1.50 4.77
1.16E+01 4.42 1.50 4.77
1.61E+01 2.53 1.50 4.77 10000 1000
3.03E+01 2.82 1.50 4.77
2.35E+01 3.65 1.50 4.77
2.49E+01 0.86 1.50 4.77
2.06E+01 2.95 1.50 4.77
1.38E+01 4.65 1.50 4.77
1.78E+01 1.71 1.50 4.77
7.50E-01 10.47 1.50 4.77
7.50E-01 21.21 1.50 4.77
7.50E-01 10.67 1.50 4.77
7.50E-01 35.63 1.50 4.77
7.50E-01 27.99 1.50 4.77
7.50E-01 10.17 1.50 4.77
7.50E-01 10.91 1.50 4.77
7.50E-01 18.09 1.50 4.77
7.50E-01 12.34 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.79E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.71 E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.38E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36 PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39 PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315 SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-669
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
ug/L
Zn SWA-L10-1315-T01-A 1 4.03E+00
Zn SWA-L10-1315-T02-A 1 2.79E+00 E
Zn SWA-L10-1315-T03-A 1 1.21E+00 E
Zn SWA-L10-1315-T04-A 1 1.65E+00 E
Zn SWA-L10-1315-T05-A 1 1.89E+00 E
Zn SWA-L10-1315-T06-A 1 1.27E+00 E
Zn SWA-L10-1315-T07-A 1 2.86E+00 E
Zn SWA-L10-1315-T08-A 1 4.31E+00
Zn SWA-L10-1315-T09-A 1 3.65E+00
Zn SWA-L10-1315-T01-B 1 1.24E+00 E
Zn SWA-L10-1315-T02-B 1 4.05E+00
Zn SWA-L10-1315-T03-B 1 1.94E+00 E
Zn SWA-L10-1315-T04-B 1 1.18E+00 E
Zn SWA-L10-1315-T05-B 1 2.43E+00 E
Zn SWA-L10-1315-T06-B 1 2.70E+00 E
Zn SWA-L10-1315-T07-B 1 3.26E+00
Zn SWA-L10-1315-T08-B 1 1.75E+00 E
Zn SWA-L10-1315-T09-B 1 2.55E+00 E
Zn SWA-L10-1315-T01-C 1 2.23E+00 E
Zn SWA-L10-1315-T02-C 1 7.51E+00
Zn SWA-L10-1315-T03-C 1 1.72E+00 E
Zn SWA-L10-1315-T04-C 1 2.56E+00 E
Zn SWA-L10-1315-T05-C 1 4.23E+00
Zn SWA-L10-1315-T06-C 1 3.11E+OOE
Zn SWA-L10-1315-T07-C 1 2.90E+00 E
Zn SWA-L10-1315-T08-C 1 1.05E+00 E
Zn SWA-L10-1315-T09-C 1 1.69E+00 E
Zn SWA-L10-1315-M01-A 1 5.00E-01 U1/2
Zn SWA-L10-1315-M02-A 1 5.00E-01 U1/2
Zn SWA-L10-1315-M03-A 1 5.00E-01 U1/2
Zn SWA-L10-1315-M04-A 1 5.00E-01 U1/2
Zn SWA-L10-1315-M05-A 1 5.00E-01 U1/2
Zn SWA-L10-1315-M06-A 1 5.00E-01 U1/2
Zn SWA-L10-1315-M07-A 1 5.00E-01 U1/2
Zn SWA-L10-1315-M08-A 1 5.00E-01 U1/2
Zn SWA-L10-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.03E+00 1.15 1.00 3.18
2.79E+00 6.95 1.00 3.18
1.21E+00 26.38 1.00 3.18 10000 1000
1.65E+00 14.16 1.00 3.18
1.89E+00 3.16 1.00 3.18
1.27E+00 1.91 1.00 3.18
2.86E+00 6.12 1.00 3.18
4.31E+00 6.48 1.00 3.18
3.65E+00 1.05 1.00 3.18
1.24E+00 11.87 1.00 3.18
4.05E+00 4.82 1.00 3.18
1.94E+00 12.65 1.00 3.18 10000 1000
1.18E+00 25.70 1.00 3.18
2.43E+00 15.17 1.00 3.18
2.70E+00 1.91 1.00 3.18
3.26E+00 1.04 1.00 3.18
1.75E+00 28.59 1.00 3.18
2.55E+00 6.86 1.00 3.18
2.23E+00 8.47 1.00 3.18
7.51E+00 3.23 1.00 3.18
1.72E+00 5.72 1.00 3.18 10000 1000
2.56E+00 1.04 1.00 3.18
4.23E+00 7.39 1.00 3.18
3.11E+00 15.11 1.00 3.18
2.90E+00 2.59 1.00 3.18
1.05E+00 19.80 1.00 3.18
1.69E+00 2.82 1.00 3.18
5.00E-01 4.57 1.00 3.18
5.00E-01 3.03 1.00 3.18
5.00E-01 18.47 1.00 3.18
5.00E-01 5.36 1.00 3.18
5.00E-01 1.01 1.00 3.18
5.00E-01 5.16 1.00 3.18
5.00E-01 7.72 1.00 3.18
5.00E-01 6.05 1.00 3.18
5.00E-01 11.31 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.25E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.78E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.90E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
2/17/11 12:14 PM EPA Interlab L10 1315 SWA
2/17/11 12:16 PM EPA Interlab L10 1315 SWA
2/17/11 12:17 PM EPA Interlab L10 1315 SWA
2/17/11 12:19 PM EPA Interlab L10 1315 SWA
2/17/11 12:21 PM EPA Interlab L10 1315 SWA
2/17/11 12:22 PM EPA Interlab L10 1315 SWA
2/17/11 12:24 PM EPA Interlab L10 1315 SWA
2/17/11 12:26 PM EPA Interlab L10 1315 SWA
2/17/11 12:27 PM EPA Interlab L10 1315 SWA
2/17/11 12:36 PM EPA Interlab L10 1315 SWA
2/17/11 12:37 PM EPA Interlab L10 1315 SWA
2/17/11 12:39 PM EPA Interlab L10 1315 SWA
2/17/11 12:41 PM EPA Interlab L10 1315 SWA
2/17/11 12:42 PM EPA Interlab L10 1315 SWA
2/17/11 12:44 PM EPA Interlab L10 1315 SWA
2/17/11 12:45 PM EPA Interlab L10 1315 SWA
2/17/11 12:47 PM EPA Interlab L10 1315 SWA
2/17/11 12:49 PM EPA Interlab L10 1315 SWA
2/17/11 12:50 PM EPA Interlab L10 1315 SWA
2/17/11 12:52 PM EPA Interlab L10 1315 SWA
2/17/11 12:54 PM EPA Interlab L10 1315 SWA
2/17/11 12:55 PM EPA Interlab L10 1315 SWA
2/17/11 12:57 PM EPA Interlab L10 1315 SWA
2/17/11 12:59 PM EPA Interlab L10 1315 SWA
2/17/11 1:00 PM EPA Interlab L10 1315 SWA
2/17/11 1:02 PM EPA Interlab L10 1315 SWA
2/17/11 1:03 PM EPA Interlab L10 1315 SWA
2/17/11 11:59 AM EPA Interlab L10 1315 SWA
2/17/11 12:01 PM EPA Interlab L10 1315 SWA
2/17/11 12:02 PM EPA Interlab L10 1315 SWA
2/17/11 12:04 PM EPA Interlab L10 1315 SWA
2/17/11 12:06 PM EPA Interlab L10 1315 SWA
2/17/11 12:07 PM EPA Interlab L10 1315 SWA
2/17/11 12:09 PM EPA Interlab L10 1315 SWA
2/17/11 12:11 PM EPA Interlab L10 1315 SWA
2/17/11 12:12 PM EPA Interlab L10 1315 SWA
1-670
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1315:
Element Sample ID
Al SWA-L11-1315-T01-A
Al SWA-L11-1315-T02-A
Al SWA-L11-1315-T03-A
Al SWA-L11-1315-T04-A
Al SWA-L11-1315-T05-A
Al SWA-L11-1315-T06-A
Al SWA-L11-1315-T07-A
Al SWA-L11-1315-T08-A
Al SWA-L11-1315-T09-A
Al SWA-L11-1315-T01-B
Al SWA-L11-1315-T02-B
Al SWA-L11-1315-T03-B
Al SWA-L11-1315-T04-B
Al SWA-L11-1315-T05-B
Al SWA-L11-1315-T06-B
Al SWA-L11-1315-T07-B
Al SWA-L11-1315-T08-B
Al SWA-L11-1315-T09-B
Al SWA-L11-1315-T01-C
Al SWA-L11-1315-T02-C
Al SWA-L11-1315-T03-C
Al SWA-L11-1315-T04-C
Al SWA-L11-1315-T05-C
Al SWA-L11-1315-T06-C
Al SWA-L11-1315-T07-C
Al SWA-L11-1315-T08-C
Al SWA-L11-1315-T09-C
Al SWA-L11-1315-M01-A
Al SWA-L11-1315-M02-A
Al SWA-L11-1315-M03-A
Al SWA-L11-1315-M04-A
Al SWA-L11-1315-M05-A
Al SWA-L11-1315-M06-A
Al SWA-L11-1315-M07-A
Al SWA-L11-1315-M08-A
Al SWA-L11-1315-M09-A
Dilution Sample
Factor Cone. Qualifier
I ug/L I
1 2.06E+03
1 5.36E+03
1 3.04E+03
1 6.10E+03
1 5.16E+03
1 5.52E+03
1 4.61 E+03
1 2.85E+03
1 3.67E+03
1 1.29E+03
1 4.34E+03
1 2.52E+03
1 5.75E+03
1 5.03E+03
1 5.58E+03
1 4.31 E+03
1 2.60E+03
1 3.71 E+03
1 1.74E+03
1 4.67E+03
1 2.98E+03
1 6.27E+03
1 5. 11 E+03
1 5.82E+03
1 4.86E+03
1 2. 81 E+03
1 3.73E+03
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.06E+03 2.81 1.00 3.18
5.36E+03 0.70 1.00 3.18
3.04E+03 2.07 1.00 3.18 10000 1000
6.10E+03 1.86 1.00 3.18
5.16E+03 0.70 1.00 3.18
5.52E+03 1.66 1.00 3.18
4.61E+03 0.32 1.00 3.18
2.85E+03 3.21 1.00 3.18
3.67E+03 0.78 1.00 3.18
1.29E+03 1.59 1.00 3.18
4.34E+03 0.27 1.00 3.18
2.52E+03 2.59 1.00 3.18 10000 1000
5.75E+03 0.88 1.00 3.18
5.03E+03 0.42 1.00 3.18
5.58E+03 1.09 1.00 3.18
4.31E+03 2.60 1.00 3.18
2.60E+03 1.13 1.00 3.18
3.71E+03 0.74 1.00 3.18
1.74E+03 7.17 1.00 3.18
4.67E+03 0.66 1.00 3.18
2.98E+03 1.18 1.00 3.18 10000 1000
6.27E+03 1.15 1.00 3.18
5.11E+03 0.39 1.00 3.18
5.82E+03 0.43 1.00 3.18
4.86E+03 1.85 1.00 3.18
2.81E+03 2.26 1.00 3.18
3.73E+03 0.13 1.00 3.18
5.00E-01 3.88 1.00 3.18
5.00E-01 8.52 1.00 3.18
5.00E-01 5.93 1.00 3.18
5.00E-01 3.44 1.00 3.18
5.00E-01 9.33 1.00 3.18
5.00E-01 1.62 1.00 3.18
5.00E-01 9.01 1.00 3.18
5.00E-01 6.87 1.00 3.18
5.00E-01 8.16 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.02E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.57E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.97E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1:36 AM EPA Interlab L11 1315SWA
6/7/11 1 1 :38 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :40 AM EPA Interlab L1 1 1315SWA
6/7/11 11:41 AM EPA Interlab L11 1315SWA
6/7/11 1 1 :43 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :45 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :46 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :48 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :50 AM EPA Interlab L1 1 1315SWA
6/7/11 11:51 AM EPA Interlab L11 1315SWA
6/7/11 1 1 :53 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :55 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :56 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :58 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :59 AM EPA Interlab L1 1 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-671
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Sb SWA-L11-1315-T01-A 1 3.49E+02
Sb SWA-L11-1315-T02-A 1 6.14E+02
Sb SWA-L11-1315-T03-A 1 3.00E+02
Sb SWA-L11-1315-T04-A 1 5.87E+02
Sb SWA-L11-1315-T05-A 1 4.70E+02
Sb SWA-L11-1315-T06-A 1 4.87E+02
Sb SWA-L11-1315-T07-A 1 3.76E+02
Sb SWA-L11-1315-T08-A 1 2.35E+02
Sb SWA-L11-1315-T09-A 1 2.87E+02
Sb SWA-L11-1315-T01-B 1 2.62E+02
Sb SWA-L11-1315-T02-B 1 5.17E+02
Sb SWA-L11-1315-T03-B 1 2.57E+02
Sb SWA-L11-1315-T04-B 1 5.34E+02
Sb SWA-L11-1315-T05-B 1 4.28E+02
Sb SWA-L11-1315-T06-B 1 4.64E+02
Sb SWA-L11-1315-T07-B 1 3.53E+02
Sb SWA-L11-1315-T08-B 1 2.17E+02
Sb SWA-L11-1315-T09-B 1 2.90E+02
Sb SWA-L11-1315-T01-C 1 2.50E+02
Sb SWA-L11-1315-T02-C 1 4.38E+02
Sb SWA-L11-1315-T03-C 1 2.73E+02
Sb SWA-L11-1315-T04-C 1 5.64E+02
Sb SWA-L11-1315-T05-C 1 4.64E+02
Sb SWA-L11-1315-T06-C 1 5.02E+02
Sb SWA-L11-1315-T07-C 1 4.04E+02
Sb SWA-L11-1315-T08-C 1 2.45E+02
Sb SWA-L11-1315-T09-C 1 3.11E+02
Sb SWA-L11-1315-M01-A 1 3.75E+00 U1/2
Sb SWA-L11-1315-M02-A 1 3.75E+00 U1/2
Sb SWA-L11-1315-M03-A 1 3.75E+00 U1/2
Sb SWA-L11-1315-M04-A 1 3.75E+00 U1/2
Sb SWA-L11-1315-M05-A 1 3.75E+00 U1/2
Sb SWA-L11-1315-M06-A 1 3.75E+00 U1/2
Sb SWA-L11-1315-M07-A 1 3.75E+00 U1/2
Sb SWA-L11-1315-M08-A 1 3.75E+00 U1/2
Sb SWA-L11-1315-M09-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.49E+02 1.91 7.50 23.90
6.14E+02 1.61 7.50 23.90
300E+02 5.51 7.50 23.90 10000 1000
5.87E+02 1.73 7.50 23.90
4.70E+02 0.68 7.50 23.90
4.87E+02 2.59 7.50 23.90
376E+02 2.58 7.50 23.90
2.35E+02 6.48 7.50 23.90
2.87E+02 1.14 7.50 23.90
2.62E+02 2.41 7.50 23.90
5.17E+02 2.11 7.50 23.90
2.57E+02 1.59 7.50 23.90 10000 1000
5.34E+02 2.34 7.50 23.90
4.28E+02 1.87 7.50 23.90
4.64E+02 1.60 7.50 23.90
3.53E+02 3.15 7.50 23.90
2.17E+02 2.45 7.50 23.90
2.90E+02 2.98 7.50 23.90
2.50E+02 6.19 7.50 23.90
4.38E+02 2.42 7.50 23.90
2.73E+02 2.00 7.50 23.90 10000 1000
5.64E+02 2.04 7.50 23.90
4.64E+02 2.34 7.50 23.90
5.02E+02 1.58 7.50 23.90
4.04E+02 1.25 7.50 23.90
2.45E+02 3.35 7.50 23.90
3.11E+02 2.32 7.50 23.90
3.75E+00 5.89 7.50 23.90
3.75E+00 16.44 7.50 23.90
3.75E+00 21.84 7.50 23.90
3.75E+00 10.66 7.50 23.90
3.75E+00 13.37 7.50 23.90
3.75E+00 2.14 7.50 23.90
3.75E+00 15.26 7.50 23.90
3.75E+00 8.49 7.50 23.90
3.75E+00 10.25 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.38E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.30E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.26E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :36 AM EPA Interlab L1 1 1315SWA
6/7/11 11:38 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:40 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:41 AM EPA Interlab L11 1315 SWA
6/7/11 11:43 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:45 AM EPA Interlab L1 1 131 5 SWA
6/7/11 11:46 AM EPA Interlab L11 131 5 SWA
6/7/11 11:48 AM EPA Interlab L11 131 5 SWA
6/7/11 11:50 AM EPA Interlab L11 131 5 SWA
6/7/11 11:51 AM EPA Interlab L11 131 5 SWA
6/7/11 11:53 AM EPA Interlab L11 1315SWA
6/7/11 11:55 AM EPA Interlab L11 1315SWA
6/7/11 11:56 AM EPA Interlab L11 1315SWA
6/7/11 11:58 AM EPA Interlab L11 1315SWA
6/7/11 11:59 AM EPA Interlab L11 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-672
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
As SWA-L11-1315-T01-A 1 4.02E+02
As SWA-L11-1315-T02-A 1 2.74E+02
As SWA-L11-1315-T03-A 1 1.44E+02
As SWA-L11-1315-T04-A 1 2.86E+02
As SWA-L11-1315-T05-A 1 1.97E+02
As SWA-L11-1315-T06-A 1 1.87E+02
As SWA-L11-1315-T07-A 1 1.40E+02
As SWA-L11-1315-T08-A 1 7.93E+01
As SWA-L11-1315-T09-A 1 1.01E+02
As SWA-L11-1315-T01-B 1 2.78E+02
As SWA-L11-1315-T02-B 1 3.26E+02
As SWA-L11-1315-T03-B 1 1.46E+02
As SWA-L11-1315-T04-B 1 3.27E+02
As SWA-L11-1315-T05-B 1 2.13E+02
As SWA-L11-1315-T06-B 1 2.01E+02
As SWA-L11-1315-T07-B 1 1.40E+02
As SWA-L11-1315-T08-B 1 7.42E+01
As SWA-L11-1315-T09-B 1 1.16E+02
As SWA-L11-1315-T01-C 1 1.73E+02
As SWA-L11-1315-T02-C 1 4.22E+02
As SWA-L11-1315-T03-C 1 2.67E+02
As SWA-L11-1315-T04-C 1 5.42E+02
As SWA-L11-1315-T05-C 1 2.92E+02
As SWA-L11-1315-T06-C 1 2.52E+02
As SWA-L11-1315-T07-C 1 1.75E+02
As SWA-L11-1315-T08-C 1 9.51E+01
As SWA-L11-1315-T09-C 1 1.24E+02
As SWA-L11-1315-M01-A 1 5.50E+00 U1/2
As SWA-L11-1315-M02-A 1 5.50E+00 U1/2
As SWA-L11-1315-M03-A 1 5.50E+00 U1/2
As SWA-L11-1315-M04-A 1 5.50E+00 U1/2
As SWA-L11-1315-M05-A 1 5.50E+00 U1/2
As SWA-L11-1315-M06-A 1 5.50E+00 U1/2
As SWA-L11-1315-M07-A 1 5.50E+00 U1/2
As SWA-L11-1315-M08-A 1 5.50E+00 U1/2
As SWA-L11-1315-M09-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.02E+02 3.87 11.00 35.00
2.74E+02 3.28 11.00 35.00
1.44E+02 3.03 11.00 35.00 10000 1000
2.86E+02 1.74 11.00 35.00
1.97E+02 1.27 11.00 35.00
1.87E+02 4.48 11.00 35.00
1.40E+02 4.48 11.00 35.00
7.93E+01 11.79 11.00 35.00
1.01E+02 2.63 11.00 35.00
2.78E+02 2.62 11.00 35.00
326E+02 3.83 11.00 35.00
1.46E+02 1.07 11.00 35.00 10000 1000
3.27E+02 2.63 11.00 35.00
2.13E+02 0.99 11.00 35.00
2.01E+02 1.81 11.00 35.00
1.40E+02 5.27 11.00 35.00
7.42E+01 9.68 11.00 35.00
1.16E+02 3.77 11.00 35.00
1.73E+02 6.97 11.00 35.00
4.22E+02 1.43 11.00 35.00
2.67E+02 2.58 11.00 35.00 10000 1000
5.42E+02 3.03 11.00 35.00
2.92E+02 2.39 11.00 35.00
2.52E+02 5.37 11.00 35.00
1.75E+02 1.14 11.00 35.00
9.51E+01 2.21 11.00 35.00
1.24E+02 5.95 11.00 35.00
5.50E+00 31.42 11.00 35.00
5.50E+00 15.28 11.00 35.00
5.50E+00 28.90 11.00 35.00
5.50E+00 22.40 11.00 35.00
5.50E+00 68.93 11.00 35.00
5.50E+00 52.54 11.00 35.00
5.50E+00 23.73 11.00 35.00
5.50E+00 52.25 11.00 35.00
5.50E+00 43.78 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 . 1 9E+03 1 05% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.24E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.38E+03 111% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :36 AM EPA Interlab L1 1 1315SWA
6/7/11 11:38 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:40 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:41 AM EPA Interlab L11 1315 SWA
6/7/11 11:43 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:45 AM EPA Interlab L1 1 131 5 SWA
6/7/11 11:46 AM EPA Interlab L11 131 5 SWA
6/7/11 11:48 AM EPA Interlab L11 131 5 SWA
6/7/11 11:50 AM EPA Interlab L11 131 5 SWA
6/7/11 11:51 AM EPA Interlab L11 131 5 SWA
6/7/11 11:53 AM EPA Interlab L11 1315SWA
6/7/11 11:55 AM EPA Interlab L11 1315SWA
6/7/11 11:56 AM EPA Interlab L11 1315SWA
6/7/11 11:58 AM EPA Interlab L11 1315SWA
6/7/11 11:59 AM EPA Interlab L11 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-673
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
B SWA-L11-1315-T01-A 1 5.23E+01
B SWA-L11-1315-T02-A 1 9.55E+01
B SWA-L11-1315-T03-A 1 5.48E+01
B SWA-L11-1315-T04-A 1 9.34E+01
B SWA-L11-1315-T05-A 1 7.77E+01
B SWA-L11-1315-T06-A 1 8.76E+01
B SWA-L11-1315-T07-A 1 7.33E+01
B SWA-L11-1315-T08-A 1 5.01 E+01
B SWA-L11-1315-T09-A 1 6.38E+01
B SWA-L11-1315-T01-B 1 6.86E+01
B SWA-L11-1315-T02-B 1 1.00E+02
B SWA-L11-1315-T03-B 1 5.46E+01
B SWA-L11-1315-T04-B 1 8.88E+01
B SWA-L11-1315-T05-B 1 7.43E+01
B SWA-L11-1315-T06-B 1 8.63E+01
B SWA-L11-1315-T07-B 1 6.74E+01
B SWA-L11-1315-T08-B 1 4.72E+01
B SWA-L11-1315-T09-B 1 6.29E+01
B SWA-L11-1315-T01-C 1 3.24E+01
B SWA-L11-1315-T02-C 1 5.54E+01
B SWA-L11-1315-T03-C 1 4.18E+01
B SWA-L11-1315-T04-C 1 7.58E+01
B SWA-L11-1315-T05-C 1 6.45E+01
B SWA-L11-1315-T06-C 1 7.54E+01
B SWA-L11-1315-T07-C 1 6.75E+01
B SWA-L11-1315-T08-C 1 4.71E+01
B SWA-L11-1315-T09-C 1 5.50E+01
B SWA-L11-1315-M01-A 1 5.00E-01 U1/2
B SWA-L11-1315-M02-A 1 5.00E-01 U1/2
B SWA-L11-1315-M03-A 1 5.00E-01 U1/2
B SWA-L11-1315-M04-A 1 5.00E-01 U1/2
B SWA-L11-1315-M05-A 1 5.00E-01 U1/2
B SWA-L11-1315-M06-A 1 5.00E-01 U1/2
B SWA-L11-1315-M07-A 1 5.00E-01 U1/2
B SWA-L11-1315-M08-A 1 5.00E-01 U1/2
B SWA-L11-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.23E+01 2.67 1.00 3.18
9.55E+01 2.74 1.00 3.18
5.48E+01 2.91 1.00 3.18 10000 1000
9.34E+01 3.85 1.00 3.18
7.77E+01 4.06 1.00 3.18
8.76E+01 2.28 1.00 3.18
7.33E+01 1.46 1.00 3.18
5.01E+01 3.73 1.00 3.18
6.38E+01 0.59 1.00 3.18
6.86E+01 1.37 1.00 3.18
1.00E+02 1.17 1.00 3.18
5.46E+01 3.91 1.00 3.18 10000 1000
8.88E+01 0.28 1.00 3.18
7.43E+01 0.72 1.00 3.18
8.63E+01 1.24 1.00 3.18
6.74E+01 2.85 1.00 3.18
4.72E+01 1.23 1.00 3.18
6.29E+01 4.64 1.00 3.18
3.24E+01 13.92 1.00 3.18
5.54E+01 5.42 1.00 3.18
4.18E+01 1.03 1.00 3.18 10000 1000
7.58E+01 1.35 1.00 3.18
6.45E+01 2.23 1.00 3.18
7.54E+01 1.72 1.00 3.18
6.75E+01 1.45 1.00 3.18
4.71E+01 2.97 1.00 3.18
5.50E+01 4.31 1.00 3.18
5.00E-01 3.48 1.00 3.18
5.00E-01 2.02 1.00 3.18
5.00E-01 6.61 1.00 3.18
5.00E-01 2.80 1.00 3.18
5.00E-01 6.33 1.00 3.18
5.00E-01 8.63 1.00 3.18
5.00E-01 1.73 1.00 3.18
5.00E-01 8.97 1.00 3.18
5.00E-01 3.89 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.07E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :36 AM EPA Interlab L1 1 1315SWA
6/7/11 11:38 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:40 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:41 AM EPA Interlab L11 1315 SWA
6/7/11 11:43 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:45 AM EPA Interlab L1 1 131 5 SWA
6/7/11 11:46 AM EPA Interlab L11 131 5 SWA
6/7/11 11:48 AM EPA Interlab L11 131 5 SWA
6/7/11 11:50 AM EPA Interlab L11 131 5 SWA
6/7/11 11:51 AM EPA Interlab L11 131 5 SWA
6/7/11 11:53 AM EPA Interlab L11 1315SWA
6/7/11 11:55 AM EPA Interlab L11 1315SWA
6/7/11 11:56 AM EPA Interlab L11 1315SWA
6/7/11 11:58 AM EPA Interlab L11 1315SWA
6/7/11 11:59 AM EPA Interlab L11 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-674
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
ug/L
Ba SWA-L11-1315-T01-A 1 3.93E+01
Ba SWA-L11-1315-T02-A 1 3.30E+02
Ba SWA-L11-1315-T03-A 1 3.44E+02
Ba SWA-L11-1315-T04-A 1 6.10E+02
Ba SWA-L11-1315-T05-A 1 6.94E+02
Ba SWA-L11-1315-T06-A 1 7.78E+02
Ba SWA-L11-1315-T07-A 1 8.84E+02
Ba SWA-L11-1315-T08-A 1 8.34E+02
Ba SWA-L11-1315-T09-A 1 7.89E+02
Ba SWA-L11-1315-T01-B 1 4.38E+01
Ba SWA-L11-1315-T02-B 1 3.18E+02
Ba SWA-L11-1315-T03-B 1 2.72E+02
Ba SWA-L11-1315-T04-B 1 4.97E+02
Ba SWA-L11-1315-T05-B 1 6.00E+02
Ba SWA-L11-1315-T06-B 1 7.08E+02
Ba SWA-L11-1315-T07-B 1 7.47E+02
Ba SWA-L11-1315-T08-B 1 6.64E+02
Ba SWA-L11-1315-T09-B 1 7.49E+02
Ba SWA-L11-1315-T01-C 1 1.37E+02
Ba SWA-L11-1315-T02-C 1 4.69E+02
Ba SWA-L11-1315-T03-C 1 3.46E+02
Ba SWA-L11-1315-T04-C 1 5.77E+02
Ba SWA-L11-1315-T05-C 1 6.50E+02
Ba SWA-L11-1315-T06-C 1 7.95E+02
Ba SWA-L11-1315-T07-C 1 8.95E+02
Ba SWA-L11-1315-T08-C 1 7.46E+02
Ba SWA-L11-1315-T09-C 1 7.95E+02
Ba SWA-L11-1315-M01-A 1 5.00E-01 U1/2
Ba SWA-L11-1315-M02-A 1 5.00E-01 U1/2
Ba SWA-L11-1315-M03-A 1 5.00E-01 U1/2
Ba SWA-L11-1315-M04-A 1 5.00E-01 U1/2
Ba SWA-L11-1315-M05-A 1 5.00E-01 U1/2
Ba SWA-L11-1315-M06-A 1 5.00E-01 U1/2
Ba SWA-L11-1315-M07-A 1 5.00E-01 U1/2
Ba SWA-L11-1315-M08-A 1 5.00E-01 U1/2
Ba SWA-L11-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.93E+01 2.98 1.00 3.18
3.30E+02 1.70 1.00 3.18
344E+02 1.16 1.00 3.18 10000 1000
6.10E+02 1.40 1.00 3.18
6.94E+02 0.88 1.00 3.18
7.78E+02 1.27 1.00 3.18
8.84E+02 0.15 1.00 3.18
8.34E+02 2.77 1.00 3.18
7.89E+02 1.05 1.00 3.18
4.38E+01 1.11 1.00 3.18
318E+02 0.69 1.00 3.18
2.72E+02 2.28 1.00 3.18 10000 1000
4.97E+02 1.18 1.00 3.18
6.00E+02 0.32 1.00 3.18
7.08E+02 1.44 1.00 3.18
7.47E+02 1.63 1.00 3.18
6.64E+02 1.13 1.00 3.18
7.49E+02 1.28 1.00 3.18
1.37E+02 6.58 1.00 3.18
4.69E+02 0.89 1.00 3.18
3.46E+02 0.94 1.00 3.18 10000 1000
5.77E+02 1.14 1.00 3.18
6.50E+02 0.80 1.00 3.18
7.95E+02 0.77 1.00 3.18
8.95E+02 1.66 1.00 3.18
7.46E+02 1.72 1.00 3.18
7.95E+02 0.98 1.00 3.18
5.00E-01 26.93 1.00 3.18
5.00E-01 18.34 1.00 3.18
5.00E-01 4.44 1.00 3.18
5.00E-01 9.43 1.00 3.18
5.00E-01 6.21 1.00 3.18
5.00E-01 21.24 1.00 3.18
5.00E-01 2.73 1.00 3.18
5.00E-01 11.84 1.00 3.18
5.00E-01 21.98 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.29E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.38E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.38E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :36 AM EPA Interlab L1 1 1315SWA
6/7/11 11:38 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:40 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:41 AM EPA Interlab L11 1315 SWA
6/7/11 11:43 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:45 AM EPA Interlab L1 1 131 5 SWA
6/7/11 11:46 AM EPA Interlab L11 131 5 SWA
6/7/11 11:48 AM EPA Interlab L11 131 5 SWA
6/7/11 11:50 AM EPA Interlab L11 131 5 SWA
6/7/11 11:51 AM EPA Interlab L11 131 5 SWA
6/7/11 11:53 AM EPA Interlab L11 1315SWA
6/7/11 11:55 AM EPA Interlab L11 1315SWA
6/7/11 11:56 AM EPA Interlab L11 1315SWA
6/7/11 11:58 AM EPA Interlab L11 1315SWA
6/7/11 11:59 AM EPA Interlab L11 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-675
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Be SWA-L11-1315-T01-A 1 9.50E-01 U1/2
Be SWA-L11-1315-T02-A 1 9.50E-01 U1/2
Be SWA-L11-1315-T03-A 1 9.50E-01 U1/2
Be SWA-L11-1315-T04-A 1 9.50E-01 U1/2
Be SWA-L11-1315-T05-A 1 9.50E-01 U1/2
Be SWA-L11-1315-T06-A 1 9.50E-01 U1/2
Be SWA-L11-1315-T07-A 1 9.50E-01 U1/2
Be SWA-L11-1315-T08-A 1 9.50E-01 U1/2
Be SWA-L11-1315-T09-A 1 9.50E-01 U1/2
Be SWA-L11-1315-T01-B 1 9.50E-01 U1/2
Be SWA-L11-1315-T02-B 1 9.50E-01 U1/2
Be SWA-L11-1315-T03-B 1 9.50E-01 U1/2
Be SWA-L11-1315-T04-B 1 9.50E-01 U1/2
Be SWA-L11-1315-T05-B 1 9.50E-01 U1/2
Be SWA-L11-1315-T06-B 1 9.50E-01 U1/2
Be SWA-L11-1315-T07-B 1 9.50E-01 U1/2
Be SWA-L11-1315-T08-B 1 9.50E-01 U1/2
Be SWA-L11-1315-T09-B 1 9.50E-01 U1/2
Be SWA-L11-1315-T01-C 1 9.50E-01 U1/2
Be SWA-L11-1315-T02-C 1 9.50E-01 U1/2
Be SWA-L11-1315-T03-C 1 9.50E-01 U1/2
Be SWA-L11-1315-T04-C 1 9.50E-01 U1/2
Be SWA-L11-1315-T05-C 1 9.50E-01 U1/2
Be SWA-L11-1315-T06-C 1 9.50E-01 U1/2
Be SWA-L11-1315-T07-C 1 9.50E-01 U1/2
Be SWA-L11-1315-T08-C 1 9.50E-01 U1/2
Be SWA-L11-1315-T09-C 1 9.50E-01 U1/2
Be SWA-L11-1315-M01-A 1 9.50E-01 U1/2
Be SWA-L11-1315-M02-A 1 9.50E-01 U1/2
Be SWA-L11-1315-M03-A 1 9.50E-01 U1/2
Be SWA-L11-1315-M04-A 1 9.50E-01 U1/2
Be SWA-L11-1315-M05-A 1 9.50E-01 U1/2
Be SWA-L11-1315-M06-A 1 9.50E-01 U1/2
Be SWA-L11-1315-M07-A 1 9.50E-01 U1/2
Be SWA-L11-1315-M08-A 1 9.50E-01 U1/2
Be SWA-L11-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 35.39 1.90 6.00
9.50E-01 59.77 1.90 6.00
9.50E-01 11.16 1.90 6.00 10000 1000
9.50E-01 44.45 1.90 6.00
9.50E-01 10.23 1.90 6.00
9.50E-01 35.19 1.90 6.00
9.50E-01 33.28 1.90 6.00
9.50E-01 10.20 1.90 6.00
9.50E-01 18.93 1.90 6.00
9.50E-01 52.05 1.90 6.00
9.50E-01 48.08 1.90 6.00
9.50E-01 22.41 1.90 6.00 10000 1000
9.50E-01 78.76 1.90 6.00
9.50E-01 19.44 1.90 6.00
9.50E-01 15.72 1.90 6.00
9.50E-01 41.37 1.90 6.00
9.50E-01 41.32 1.90 6.00
9.50E-01 18.85 1.90 6.00
9.50E-01 39.19 1.90 6.00
9.50E-01 70.46 1.90 6.00
9.50E-01 19.70 1.90 6.00 10000 1000
9.50E-01 13.14 1.90 6.00
9.50E-01 16.37 1.90 6.00
9.50E-01 25.52 1.90 6.00
9.50E-01 21.05 1.90 6.00
9.50E-01 56.22 1.90 6.00
9.50E-01 39.67 1.90 6.00
9.50E-01 10.13 1.90 6.00
9.50E-01 16.79 1.90 6.00
9.50E-01 12.00 1.90 6.00
9.50E-01 13.28 1.90 6.00
9.50E-01 13.62 1.90 6.00
9.50E-01 10.84 1.90 6.00
9.50E-01 14.07 1.90 6.00
9.50E-01 13.32 1.90 6.00
9.50E-01 12.61 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.03E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :36 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :38 AM EPA Interlab L1 1 1315SWA
6/7/11 11:40 AM EPA Interlab L11 1315SWA
6/7/11 11:41 AM EPA Interlab L11 1315 SWA
6/7/11 11:43 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:45 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:46 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:48 AM EPA Interlab L1 1 131 5 SWA
6/7/11 11:50 AM EPA Interlab L11 131 5 SWA
6/7/11 11:51 AM EPA Interlab L11 1315 SWA
6/7/11 11:53 AM EPA Interlab L11 131 5 SWA
6/7/11 11:55 AM EPA Interlab L11 131 5 SWA
6/7/11 11:56 AM EPA Interlab L11 131 5 SWA
6/7/11 11:58 AM EPA Interlab L11 1315SWA
6/7/11 11:59 AM EPA Interlab L11 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-676
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cd SWA-L11-1315-T01-A 1 1.10E+00 U1/2
Cd SWA-L11-1315-T02-A 1 1.10E+00 U1/2
Cd SWA-L11-1315-T03-A 1 1.10E+00 U1/2
Cd SWA-L11-1315-T04-A 1 1.10E+00 U1/2
Cd SWA-L11-1315-T05-A 1 1.10E+00 U1/2
Cd SWA-L11-1315-T06-A 1 1.10E+00 U1/2
Cd SWA-L11-1315-T07-A 1 1.10E+00 U1/2
Cd SWA-L11-1315-T08-A 1 1.10E+00 U1/2
Cd SWA-L11-1315-T09-A 1 1.10E+00 U1/2
Cd SWA-L11-1315-T01-B 1 1.10E+00 U1/2
Cd SWA-L11-1315-T02-B 1 1.10E+00 U1/2
Cd SWA-L11-1315-T03-B 1 1.10E+00 U1/2
Cd SWA-L11-1315-T04-B 1 1.10E+00 U1/2
Cd SWA-L11-1315-T05-B 1 1.10E+00 U1/2
Cd SWA-L11-1315-T06-B 1 1.10E+00 U1/2
Cd SWA-L11-1315-T07-B 1 1.10E+00 U1/2
Cd SWA-L11-1315-T08-B 1 1.10E+00 U1/2
Cd SWA-L11-1315-T09-B 1 1.10E+00 U1/2
Cd SWA-L11-1315-T01-C 1 1.10E+00 U1/2
Cd SWA-L11-1315-T02-C 1 1.10E+00 U1/2
Cd SWA-L11-1315-T03-C 1 1.10E+00 U1/2
Cd SWA-L11-1315-T04-C 1 1.10E+00 U1/2
Cd SWA-L11-1315-T05-C 1 1.10E+00 U1/2
Cd SWA-L11-1315-T06-C 1 1.10E+00 U1/2
Cd SWA-L11-1315-T07-C 1 1.10E+00 U1/2
Cd SWA-L11-1315-T08-C 1 1.10E+00 U1/2
Cd SWA-L11-1315-T09-C 1 1.10E+00 U1/2
Cd SWA-L11-1315-M01-A 1 1.10E+00 U1/2
Cd SWA-L11-1315-M02-A 1 1.10E+00 U1/2
Cd SWA-L11-1315-M03-A 1 1.10E+00 U1/2
Cd SWA-L11-1315-M04-A 1 1.10E+00 U1/2
Cd SWA-L11-1315-M05-A 1 1.10E+00 U1/2
Cd SWA-L11-1315-M06-A 1 1.10E+00 U1/2
Cd SWA-L11-1315-M07-A 1 1.10E+00 U1/2
Cd SWA-L11-1315-M08-A 1 1.10E+00 U1/2
Cd SWA-L11-1315-M09-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00 10000 1000
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00 10000 1000
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00 10000 1000
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
1.10E+00 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 11:35 AM EPA Interlab L11 1315SWA
6/7/1 1 1 1 :36 AM EPA Interlab L1 1 1315 SWA
6/7/11 1 1:38 AM EPA Interlab L11 131 5 SWA
6/7/1 1 1 1 :40 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:41 AM EPA Interlab L11 131 5 SWA
6/7/1 1 1 1 :43 AM EPA Interlab L1 1 1315 SWA
6/7/1 1 1 1 :45 AM EPA Interlab L1 1 1315 SWA
6/7/1 1 1 1 :46 AM EPA Interlab L1 1 1315 SWA
6/7/1 1 1 1 :48 AM EPA Interlab L1 1 1315 SWA
6/7/1 1 1 1 :50 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:51 AM EPA Interlab L11 1315 SWA
6/7/1 1 1 1 :53 AM EPA Interlab L1 1 1315 SWA
6/7/1 1 1 1 :55 AM EPA Interlab L1 1 1315 SWA
6/7/1 1 1 1 :56 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:58 AM EPA Interlab L11 1315SWA
6/7/11 11:59 AM EPA Interlab L11 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315 SWA
6/7/11 12:08 PM EPA Interlab L11 1315 SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L1 1 1315 SWA
6/7/11 12:29 PM EPA Interlab L11 1315 SWA
6/7/11 12:31 PM EPA Interlab L11 1315 SWA
6/7/11 12:32 PM EPA Interlab L11 1315 SWA
6/7/11 12:34 PM EPA Interlab L11 1315 SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-677
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Ca SWA-L11-1315-T01-A 1 7.40E+02
Ca SWA-L11-1315-T02-A 1 8.70E+03
Ca SWA-L11-1315-T03-A 1 1.08E+04
Ca SWA-L11-1315-T04-A 1 2.11E+04
Ca SWA-L11-1315-T05-A 1 2.33E+04
Ca SWA-L11-1315-T06-A 1 2.61E+04
Ca SWA-L11-1315-T07-A 1 2.71E+04
Ca SWA-L11-1315-T08-A 1 2.33E+04
Ca SWA-L11-1315-T09-A 1 2.24E+04
Ca SWA-L11-1315-T01-B 1 8.64E+02
Ca SWA-L11-1315-T02-B 1 8.54E+03
Ca SWA-L11-1315-T03-B 1 9.09E+03
Ca SWA-L11-1315-T04-B 1 1.85E+04
Ca SWA-L11-1315-T05-B 1 2.04E+04
Ca SWA-L11-1315-T06-B 1 2.42E+04
Ca SWA-L11-1315-T07-B 1 2.34E+04
Ca SWA-L11-1315-T08-B 1 1.94E+04
Ca SWA-L11-1315-T09-B 1 2.33E+04
Ca SWA-L11-1315-T01-C 1 1.10E+03
Ca SWA-L11-1315-T02-C 1 9.44E+03
Ca SWA-L11-1315-T03-C 1 1.04E+04
Ca SWA-L11-1315-T04-C 1 1.97E+04
Ca SWA-L11-1315-T05-C 1 2.08E+04
Ca SWA-L11-1315-T06-C 1 2.50E+04
Ca SWA-L11-1315-T07-C 1 2.58E+04
Ca SWA-L11-1315-T08-C 1 2.08E+04
Ca SWA-L11-1315-T09-C 1 2.36E+04
Ca SWA-L11-1315-M01-A 1 1.59E+01
Ca SWA-L11-1315-M02-A 1 1.12E+01
Ca SWA-L11-1315-M03-A 1 2.37E+01
Ca SWA-L11-1315-M04-A 1 3.45E+01
Ca SWA-L11-1315-M05-A 1 5.12E+01
Ca SWA-L11-1315-M06-A 1 4.75E+01
Ca SWA-L11-1315-M07-A 1 6.41E+01
Ca SWA-L11-1315-M08-A 1 1.45E+01
Ca SWA-L11-1315-M09-A 1 4.27E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.40E+02 3.15 2.60 8.30
8.70E+03 1.52 2.60 8.30
1.08E+04 1.88 2.60 8.30 10000 1000
2.11E+04 1.66 2.60 8.30
2.33E+04 1.10 2.60 8.30
2.61 E+04 1.30 2.60 8.30
2.71E+04 0.68 2.60 8.30
2.33E+04 3.08 2.60 8.30
2.24E+04 1.37 2.60 8.30
8.64E+02 2.07 2.60 8.30
8.54E+03 0.64 2.60 8.30
9.09E+03 1.99 2.60 8.30 10000 1000
1.85E+04 0.67 2.60 8.30
2.04E+04 0.31 2.60 8.30
2.42E+04 1.33 2.60 8.30
2.34E+04 2.01 2.60 8.30
1.94E+04 1.38 2.60 8.30
2.33E+04 1.01 2.60 8.30
1.10E+03 6.35 2.60 8.30
9.44E+03 0.55 2.60 8.30
1.04E+04 1.11 2.60 8.30 10000 1000
1.97E+04 0.86 2.60 8.30
2.08E+04 0.94 2.60 8.30
2.50E+04 0.85 2.60 8.30
2.58E+04 1.20 2.60 8.30
2.08E+04 2.06 2.60 8.30
2.36E+04 1.00 2.60 8.30
1.59E+01 1.66 2.60 8.30
1.12E+01 2.69 2.60 8.30
2.37E+01 1.61 2.60 8.30
3.45E+01 1.16 2.60 8.30
5.12E+01 9.51 2.60 8.30
4.75E+01 1.33 2.60 8.30
6.41 E+01 1.77 2.60 8.30
1.45E+01 3.02 2.60 8.30
4.27E+01 2.11 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.17E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.93E+03 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.13E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1:36 AM EPA Interlab L11 131 5 SWA
6/7/11 1 1 :38 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :40 AM EPA Interlab L1 1 1315SWA
6/7/11 11:41 AM EPA Interlab L11 1315SWA
6/7/11 1 1 :43 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :45 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :46 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :48 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :50 AM EPA Interlab L1 1 1315SWA
6/7/11 11:51 AM EPA Interlab L11 131 5 SWA
6/7/11 1 1 :53 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :55 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :56 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :58 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :59 AM EPA Interlab L1 1 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-678
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Cr SWA-L11-1315-T01-A 1 4.27E+01
Cr SWA-L11-1315-T02-A 1 9.00E+01
Cr SWA-L11-1315-T03-A 1 2.92E+01
Cr SWA-L11-1315-T04-A 1 4.94E+01
Cr SWA-L11-1315-T05-A 1 4.19E+01
Cr SWA-L11-1315-T06-A 1 4.73E+01
Cr SWA-L11-1315-T07-A 1 4.38E+01
Cr SWA-L11-1315-T08-A 1 2.99E+01
Cr SWA-L11-1315-T09-A 1 3.79E+01
Cr SWA-L11-1315-T01-B 1 4.66E+01
Cr SWA-L11-1315-T02-B 1 8.70E+01
Cr SWA-L11-1315-T03-B 1 3.36E+01
Cr SWA-L11-1315-T04-B 1 6.25E+01
Cr SWA-L11-1315-T05-B 1 4.69E+01
Cr SWA-L11-1315-T06-B 1 4.65E+01
Cr SWA-L11-1315-T07-B 1 3.87E+01
Cr SWA-L11-1315-T08-B 1 2.39E+01
Cr SWA-L11-1315-T09-B 1 3.52E+01
Cr SWA-L11-1315-T01-C 1 4.29E+01
Cr SWA-L11-1315-T02-C 1 5.11E+01
Cr SWA-L11-1315-T03-C 1 2.36E+01
Cr SWA-L11-1315-T04-C 1 4.27E+01
Cr SWA-L11-1315-T05-C 1 4.06E+01
Cr SWA-L11-1315-T06-C 1 4.67E+01
Cr SWA-L11-1315-T07-C 1 4.53E+01
Cr SWA-L11-1315-T08-C 1 2.96E+01
Cr SWA-L11-1315-T09-C 1 3.92E+01
Cr SWA-L11-1315-M01-A 1 6.00E-01 U1/2
Cr SWA-L11-1315-M02-A 1 6.00E-01 U1/2
Cr SWA-L11-1315-M03-A 1 6.00E-01 U1/2
Cr SWA-L11-1315-M04-A 1 6.00E-01 U1/2
Cr SWA-L11-1315-M05-A 1 6.00E-01 U1/2
Cr SWA-L11-1315-M06-A 1 6.00E-01 U1/2
Cr SWA-L11-1315-M07-A 1 6.00E-01 U1/2
Cr SWA-L11-1315-M08-A 1 6.00E-01 U1/2
Cr SWA-L11-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.27E+01 3.22 1.20 3.82
9.00E+01 0.98 1.20 3.82
2.92E+01 0.86 1.20 3.82 10000 1000
4.94E+01 2.12 1.20 3.82
4.19E+01 1.25 1.20 3.82
4.73E+01 2.79 1.20 3.82
4.38E+01 2.14 1.20 3.82
2.99E+01 4.11 1.20 3.82
379E+01 0.79 1.20 3.82
4.66E+01 1.59 1.20 3.82
8.70E+01 0.94 1.20 3.82
336E+01 1.25 1.20 3.82 10000 1000
6.25E+01 1.40 1.20 3.82
4.69E+01 1.39 1.20 3.82
4.65E+01 1.84 1.20 3.82
3.87E+01 2.93 1.20 3.82
2.39E+01 3.80 1.20 3.82
3.52E+01 1.26 1.20 3.82
4.29E+01 7.97 1.20 3.82
5.11E+01 0.93 1.20 3.82
2.36E+01 2.83 1.20 3.82 10000 1000
4.27E+01 2.40 1.20 3.82
4.06E+01 2.45 1.20 3.82
4.67E+01 1.51 1.20 3.82
4.53E+01 1.58 1.20 3.82
2.96E+01 2.23 1.20 3.82
3.92E+01 1.00 1.20 3.82
6.00E-01 62.52 1.20 3.82
6.00E-01 28.92 1.20 3.82
6.00E-01 36.93 1.20 3.82
6.00E-01 69.21 1.20 3.82
6.00E-01 29.04 1.20 3.82
6.00E-01 12.91 1.20 3.82
6.00E-01 31.80 1.20 3.82
6.00E-01 42.82 1.20 3.82
6.00E-01 25.97 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.10E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 . 1 0E+03 1 06% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :36 AM EPA Interlab L1 1 1315SWA
6/7/11 11:38 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:40 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:41 AM EPA Interlab L11 1315 SWA
6/7/11 11:43 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:45 AM EPA Interlab L1 1 131 5 SWA
6/7/11 11:46 AM EPA Interlab L11 131 5 SWA
6/7/11 11:48 AM EPA Interlab L11 131 5 SWA
6/7/11 11:50 AM EPA Interlab L11 131 5 SWA
6/7/11 11:51 AM EPA Interlab L11 131 5 SWA
6/7/11 11:53 AM EPA Interlab L11 1315SWA
6/7/11 11:55 AM EPA Interlab L11 1315SWA
6/7/11 11:56 AM EPA Interlab L11 1315SWA
6/7/11 11:58 AM EPA Interlab L11 1315SWA
6/7/11 11:59 AM EPA Interlab L11 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-679
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Co SWA-L11-1315-T01-A 1 9.00E-01 U1/2
Co SWA-L11-1315-T02-A 1 9.00E-01 U1/2
Co SWA-L11-1315-T03-A 1 9.00E-01 U1/2
Co SWA-L11-1315-T04-A 1 9.00E-01 U1/2
Co SWA-L11-1315-T05-A 1 9.00E-01 U1/2
Co SWA-L11-1315-T06-A 1 9.00E-01 U1/2
Co SWA-L11-1315-T07-A 1 9.00E-01 U1/2
Co SWA-L11-1315-T08-A 1 9.00E-01 U1/2
Co SWA-L11-1315-T09-A 1 9.00E-01 U1/2
Co SWA-L11-1315-T01-B 1 9.00E-01 U1/2
Co SWA-L11-1315-T02-B 1 9.00E-01 U1/2
Co SWA-L11-1315-T03-B 1 9.00E-01 U1/2
Co SWA-L11-1315-T04-B 1 9.00E-01 U1/2
Co SWA-L11-1315-T05-B 1 9.00E-01 U1/2
Co SWA-L11-1315-T06-B 1 9.00E-01 U1/2
Co SWA-L11-1315-T07-B 1 9.00E-01 U1/2
Co SWA-L11-1315-T08-B 1 9.00E-01 U1/2
Co SWA-L11-1315-T09-B 1 9.00E-01 U1/2
Co SWA-L11-1315-T01-C 1 9.00E-01 U1/2
Co SWA-L11-1315-T02-C 1 9.00E-01 U1/2
Co SWA-L11-1315-T03-C 1 9.00E-01 U1/2
Co SWA-L11-1315-T04-C 1 9.00E-01 U1/2
Co SWA-L11-1315-T05-C 1 9.00E-01 U1/2
Co SWA-L11-1315-T06-C 1 9.00E-01 U1/2
Co SWA-L11-1315-T07-C 1 9.00E-01 U1/2
Co SWA-L11-1315-T08-C 1 9.00E-01 U1/2
Co SWA-L11-1315-T09-C 1 9.00E-01 U1/2
Co SWA-L11-1315-M01-A 1 9.00E-01 U1/2
Co SWA-L11-1315-M02-A 1 9.00E-01 U1/2
Co SWA-L11-1315-M03-A 1 9.00E-01 U1/2
Co SWA-L11-1315-M04-A 1 9.00E-01 U1/2
Co SWA-L11-1315-M05-A 1 9.00E-01 U1/2
Co SWA-L11-1315-M06-A 1 9.00E-01 U1/2
Co SWA-L11-1315-M07-A 1 9.00E-01 U1/2
Co SWA-L11-1315-M08-A 1 9.00E-01 U1/2
Co SWA-L11-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 44.06 1.80 5.72
9.00E-01 38.17 1.80 5.72
9.00E-01 37.70 1.80 5.72 10000 1000
9.00E-01 26.47 1.80 5.72
9.00E-01 52.27 1.80 5.72
9.00E-01 22.81 1.80 5.72
9.00E-01 54.19 1.80 5.72
9.00E-01 44.03 1.80 5.72
9.00E-01 33.63 1.80 5.72
9.00E-01 45.99 1.80 5.72
9.00E-01 21.32 1.80 5.72
9.00E-01 69.21 1.80 5.72 10000 1000
9.00E-01 43.94 1.80 5.72
9.00E-01 30.58 1.80 5.72
9.00E-01 25.09 1.80 5.72
9.00E-01 24.57 1.80 5.72
9.00E-01 32.39 1.80 5.72
9.00E-01 13.73 1.80 5.72
9.00E-01 62.62 1.80 5.72
9.00E-01 98.57 1.80 5.72
9.00E-01 76.94 1.80 5.72 10000 1000
9.00E-01 35.03 1.80 5.72
9.00E-01 43.58 1.80 5.72
9.00E-01 28.68 1.80 5.72
9.00E-01 15.16 1.80 5.72
9.00E-01 15.21 1.80 5.72
9.00E-01 44.62 1.80 5.72
9.00E-01 27.68 1.80 5.72
9.00E-01 14.81 1.80 5.72
9.00E-01 36.35 1.80 5.72
9.00E-01 14.69 1.80 5.72
9.00E-01 25.72 1.80 5.72
9.00E-01 29.48 1.80 5.72
9.00E-01 1.73 1.80 5.72
9.00E-01 37.04 1.80 5.72
9.00E-01 12.70 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1:36 AM EPA Interlab L11 131 5 SWA
6/7/11 1 1 :38 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :40 AM EPA Interlab L1 1 1315SWA
6/7/11 11:41 AM EPA Interlab L11 1315SWA
6/7/11 1 1 :43 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :45 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :46 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :48 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :50 AM EPA Interlab L1 1 1315SWA
6/7/11 11:51 AM EPA Interlab L11 131 5 SWA
6/7/11 1 1 :53 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :55 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :56 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :58 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :59 AM EPA Interlab L1 1 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-680
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cu SWA-L11-1315-T01-A 1 1.85E+00 U1/2
Cu SWA-L11-1315-T02-A 1 1.85E+00 U1/2
Cu SWA-L11-1315-T03-A 1 1.85E+00 U1/2
Cu SWA-L11-1315-T04-A 1 1.85E+00 U1/2
Cu SWA-L11-1315-T05-A 1 1.85E+00 U1/2
Cu SWA-L11-1315-T06-A 1 1.85E+00 U1/2
Cu SWA-L11-1315-T07-A 1 1.85E+00 U1/2
Cu SWA-L11-1315-T08-A 1 1.85E+00 U1/2
Cu SWA-L11-1315-T09-A 1 1.85E+00 U1/2
Cu SWA-L11-1315-T01-B 1 1.85E+00 U1/2
Cu SWA-L11-1315-T02-B 1 1.85E+00 U1/2
Cu SWA-L11-1315-T03-B 1 1.85E+00 U1/2
Cu SWA-L11-1315-T04-B 1 1.85E+00 U1/2
Cu SWA-L11-1315-T05-B 1 1.85E+00 U1/2
Cu SWA-L11-1315-T06-B 1 1.85E+00 U1/2
Cu SWA-L11-1315-T07-B 1 1.85E+00 U1/2
Cu SWA-L11-1315-T08-B 1 1.85E+00 U1/2
Cu SWA-L11-1315-T09-B 1 1.85E+00 U1/2
Cu SWA-L11-1315-T01-C 1 1.85E+00 U1/2
Cu SWA-L11-1315-T02-C 1 1.85E+00 U1/2
Cu SWA-L11-1315-T03-C 1 1.85E+00 U1/2
Cu SWA-L11-1315-T04-C 1 1.85E+00 U1/2
Cu SWA-L11-1315-T05-C 1 1.85E+00 U1/2
Cu SWA-L11-1315-T06-C 1 1.85E+00 U1/2
Cu SWA-L11-1315-T07-C 1 1.85E+00 U1/2
Cu SWA-L11-1315-T08-C 1 1.85E+00 U1/2
Cu SWA-L11-1315-T09-C 1 1.85E+00 U1/2
Cu SWA-L11-1315-M01-A 1 1.85E+00 U1/2
Cu SWA-L11-1315-M02-A 1 1.85E+00 U1/2
Cu SWA-L11-1315-M03-A 1 1.85E+00 U1/2
Cu SWA-L11-1315-M04-A 1 1.85E+00 U1/2
Cu SWA-L11-1315-M05-A 1 1.85E+00 U1/2
Cu SWA-L11-1315-M06-A 1 1.85E+00 U1/2
Cu SWA-L11-1315-M07-A 1 1.85E+00 U1/2
Cu SWA-L11-1315-M08-A 1 1.85E+00 U1/2
Cu SWA-L11-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 28.27 3.70 11.80
1.85E+00 11.23 3.70 11.80
1.85E+00 88.16 3.70 11.80 10000 1000
1.85E+00 44.76 3.70 11.80
1.85E+00 10.47 3.70 11.80
1.85E+00 64.48 3.70 11.80
1.85E+00 42.70 3.70 11.80
1.85E+00 31.66 3.70 11.80
1.85E+00 13.62 3.70 11.80
1.85E+00 55.29 3.70 11.80
1.85E+00 72.43 3.70 11.80
1.85E+00 77.31 3.70 11.80 10000 1000
1.85E+00 51.60 3.70 11.80
1.85E+00 20.91 3.70 11.80
1.85E+00 77.10 3.70 11.80
1.85E+00 63.01 3.70 11.80
1.85E+00 59.24 3.70 11.80
1.85E+00 19.14 3.70 11.80
1.85E+00 29.16 3.70 11.80
1.85E+00 13.77 3.70 11.80
1.85E+00 125.90 3.70 11.80 10000 1000
1.85E+00 16.67 3.70 11.80
1.85E+00 75.03 3.70 11.80
1.85E+00 33.40 3.70 11.80
1.85E+00 13.76 3.70 11.80
1.85E+00 80.64 3.70 11.80
1.85E+00 10.99 3.70 11.80
1.85E+00 18.97 3.70 11.80
1.85E+00 76.04 3.70 11.80
1.85E+00 30.14 3.70 11.80
1.85E+00 19.68 3.70 11.80
1.85E+00 54.31 3.70 11.80
1.85E+00 17.98 3.70 11.80
1.85E+00 54.95 3.70 11.80
1.85E+00 49.18 3.70 11.80
1.85E+00 15.33 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1:36 AM EPA Interlab L11 131 5 SWA
6/7/11 1 1 :38 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :40 AM EPA Interlab L1 1 1315SWA
6/7/11 11:41 AM EPA Interlab L11 1315SWA
6/7/11 1 1 :43 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :45 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :46 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :48 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :50 AM EPA Interlab L1 1 1315SWA
6/7/11 11:51 AM EPA Interlab L11 131 5 SWA
6/7/11 1 1 :53 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :55 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :56 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :58 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :59 AM EPA Interlab L1 1 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-681
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Fe SWA-L11-1315-T01-A 1 1.19E+01
Fe SWA-L11-1315-T02-A 1 8.88E+00
Fe SWA-L11-1315-T03-A 1 2.36E+00 E
Fe SWA-L11-1315-T04-A 1 3.94E+00 E
Fe SWA-L11-1315-T05-A 1 1.00E+00 U1/2
Fe SWA-L11-1315-T06-A 1 3.19E+00 E
Fe SWA-L11-1315-T07-A 1 1.00E+00 U1/2
Fe SWA-L11-1315-T08-A 1 1.00E+00 U1/2
Fe SWA-L11-1315-T09-A 1 1.00E+00 U1/2
Fe SWA-L11-1315-T01-B 1 9.51E+00
Fe SWA-L11-1315-T02-B 1 9.57E+00
Fe SWA-L11-1315-T03-B 1 3.01E+00 E
Fe SWA-L11-1315-T04-B 1 3.29E+00 E
Fe SWA-L11-1315-T05-B 1 4.88E+00 E
Fe SWA-L11-1315-T06-B 1 5.38E+00 E
Fe SWA-L11-1315-T07-B 1 1.00E+00 U1/2
Fe SWA-L11-1315-T08-B 1 1.00E+00 U1/2
Fe SWA-L11-1315-T09-B 1 1.00E+00 U1/2
Fe SWA-L11-1315-T01-C 1 1.11E+01
Fe SWA-L11-1315-T02-C 1 1.12E+01
Fe SWA-L11-1315-T03-C 1 5.09E+00 E
Fe SWA-L11-1315-T04-C 1 7.33E+00
Fe SWA-L11-1315-T05-C 1 2.62E+00 E
Fe SWA-L11-1315-T06-C 1 3.27E+00 E
Fe SWA-L11-1315-T07-C 1 1.00E+00 U1/2
Fe SWA-L11-1315-T08-C 1 1.00E+00 U1/2
Fe SWA-L11-1315-T09-C 1 1.00E+00 U1/2
Fe SWA-L11-1315-M01-A 1 1.00E+00 U1/2
Fe SWA-L11-1315-M02-A 1 1.00E+00 U1/2
Fe SWA-L11-1315-M03-A 1 1.00E+00 U1/2
Fe SWA-L11-1315-M04-A 1 1.00E+00 U1/2
Fe SWA-L11-1315-M05-A 1 1.00E+00 U1/2
Fe SWA-L11-1315-M06-A 1 1.00E+00 U1/2
Fe SWA-L11-1315-M07-A 1 1.00E+00 U1/2
Fe SWA-L11-1315-M08-A 1 1.00E+00 U1/2
Fe SWA-L11-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.19E+01 1.13 2.00 6.40
8.88E+00 4.35 2.00 6.40
2.36E+00 27.89 2.00 6.40 10000 1000
394E+00 11.10 2.00 6.40
1.00E+00 6.18 2.00 6.40
319E+00 3.32 2.00 6.40
1.00E+00 40.27 2.00 6.40
1.00E+00 51.28 2.00 6.40
1.00E+00 15.69 2.00 6.40
9.51 E+00 3.08 2.00 6.40
9.57E+00 2.15 2.00 6.40
301E+00 12.66 2.00 6.40 10000 1000
329E+00 6.80 2.00 6.40
4.88E+00 9.68 2.00 6.40
5.38E+00 6.61 2.00 6.40
1.00E+00 5.79 2.00 6.40
1.00E+00 7.26 2.00 6.40
1.00E+00 4.76 2.00 6.40
1.11E+01 3.91 2.00 6.40
1.12E+01 4.04 2.00 6.40
5.09E+00 2.43 2.00 6.40 10000 1000
7.33E+00 0.44 2.00 6.40
2.62E+00 21.95 2.00 6.40
327E+00 15.52 2.00 6.40
1.00E+00 7.46 2.00 6.40
1.00E+00 39.52 2.00 6.40
1.00E+00 11.51 2.00 6.40
1.00E+00 8.60 2.00 6.40
1.00E+00 0.77 2.00 6.40
1.00E+00 24.84 2.00 6.40
1.00E+00 11.56 2.00 6.40
1.00E+00 7.96 2.00 6.40
1.00E+00 3.09 2.00 6.40
1.00E+00 2.39 2.00 6.40
1.00E+00 15.47 2.00 6.40
1.00E+00 7.90 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 11:35 AM EPA Interlab L11 1315SWA
6/7/11 1 1 :36 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1:38 AM EPA Interlab L11 1315SWA
6/7/11 11:40 AM EPA Interlab L11 1315SWA
6/7/11 11:41 AM EPA Interlab L11 1315SWA
6/7/11 1 1:43 AM EPA Interlab L11 1315SWA
6/7/11 1 1:45 AM EPA Interlab L11 1315SWA
6/7/11 11:46 AM EPA Interlab L11 1315SWA
6/7/11 11:48 AM EPA Interlab L11 1315SWA
6/7/11 11:50 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:51 AM EPA Interlab L11 1315SWA
6/7/11 11:53 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:55 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:56 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:58 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:59 AM EPA Interlab L1 1 1315 SWA
6/7/11 12:01 PM EPA Interlab L11 1315 SWA
6/7/11 12:08 PM EPA Interlab L11 1315 SWA
6/7/11 12:09 PM EPA Interlab L11 1315 SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315 SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-682
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Pb SWA-L11-1315-T01-A 1 3.40E+00 U1/2
Pb SWA-L11-1315-T02-A 1 3.40E+00 U1/2
Pb SWA-L11-1315-T03-A 1 3.40E+00 U1/2
Pb SWA-L11-1315-T04-A 1 3.40E+00 U1/2
Pb SWA-L11-1315-T05-A 1 3.40E+00 U1/2
Pb SWA-L11-1315-T06-A 1 3.40E+00 U1/2
Pb SWA-L11-1315-T07-A 1 3.40E+00 U1/2
Pb SWA-L11-1315-T08-A 1 3.40E+00 U1/2
Pb SWA-L11-1315-T09-A 1 3.40E+00 U1/2
Pb SWA-L11-1315-T01-B 1 3.40E+00 U1/2
Pb SWA-L11-1315-T02-B 1 3.40E+00 U1/2
Pb SWA-L11-1315-T03-B 1 3.40E+00 U1/2
Pb SWA-L11-1315-T04-B 1 3.40E+00 U1/2
Pb SWA-L11-1315-T05-B 1 3.40E+00 U1/2
Pb SWA-L11-1315-T06-B 1 3.40E+00 U1/2
Pb SWA-L11-1315-T07-B 1 3.40E+00 U1/2
Pb SWA-L11-1315-T08-B 1 3.40E+00 U1/2
Pb SWA-L11-1315-T09-B 1 3.40E+00 U1/2
Pb SWA-L11-1315-T01-C 1 3.40E+00 U1/2
Pb SWA-L11-1315-T02-C 1 3.40E+00 U1/2
Pb SWA-L11-1315-T03-C 1 3.40E+00 U1/2
Pb SWA-L11-1315-T04-C 1 3.40E+00 U1/2
Pb SWA-L11-1315-T05-C 1 3.40E+00 U1/2
Pb SWA-L11-1315-T06-C 1 3.40E+00 U1/2
Pb SWA-L11-1315-T07-C 1 3.40E+00 U1/2
Pb SWA-L11-1315-T08-C 1 3.40E+00 U1/2
Pb SWA-L11-1315-T09-C 1 3.40E+00 U1/2
Pb SWA-L11-1315-M01-A 1 3.40E+00 U1/2
Pb SWA-L11-1315-M02-A 1 3.40E+00 U1/2
Pb SWA-L11-1315-M03-A 1 3.40E+00 U1/2
Pb SWA-L11-1315-M04-A 1 3.40E+00 U1/2
Pb SWA-L11-1315-M05-A 1 3.40E+00 U1/2
Pb SWA-L11-1315-M06-A 1 3.40E+00 U1/2
Pb SWA-L11-1315-M07-A 1 3.40E+00 U1/2
Pb SWA-L11-1315-M08-A 1 3.40E+00 U1/2
Pb SWA-L11-1315-M09-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 66.38 6.80 21.60
3.40E+00 57.68 6.80 21.60
340E+00 33.02 6.80 21.60 10000 1000
340E+00 52.59 6.80 21.60
340E+00 73.86 6.80 21.60
340E+00 53.22 6.80 21.60
340E+00 54.27 6.80 21.60
340E+00 48.68 6.80 21.60
340E+00 55.01 6.80 21.60
340E+00 15.36 6.80 21.60
340E+00 67.86 6.80 21.60
340E+00 54.66 6.80 21.60 10000 1000
340E+00 68.53 6.80 21.60
340E+00 47.60 6.80 21.60
3.40E+00 71.88 6.80 21.60
3.40E+00 44.23 6.80 21.60
3.40E+00 48.11 6.80 21.60
3.40E+00 56.01 6.80 21.60
3.40E+00 12.18 6.80 21.60
3.40E+00 15.30 6.80 21.60
3.40E+00 42.90 6.80 21.60 10000 1000
3.40E+00 39.91 6.80 21.60
3.40E+00 45.84 6.80 21.60
3.40E+00 77.04 6.80 21.60
3.40E+00 49.16 6.80 21.60
3.40E+00 65.65 6.80 21.60
3.40E+00 17.52 6.80 21.60
3.40E+00 12.46 6.80 21.60
3.40E+00 40.73 6.80 21.60
3.40E+00 34.98 6.80 21.60
3.40E+00 17.39 6.80 21.60
3.40E+00 59.47 6.80 21.60
3.40E+00 14.39 6.80 21.60
3.40E+00 33.36 6.80 21.60
3.40E+00 42.51 6.80 21.60
3.40E+00 44.89 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :36 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :38 AM EPA Interlab L1 1 1315SWA
6/7/11 11:40 AM EPA Interlab L11 1315SWA
6/7/11 11:41 AM EPA Interlab L11 1315 SWA
6/7/11 11:43 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:45 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:46 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:48 AM EPA Interlab L1 1 131 5 SWA
6/7/11 11:50 AM EPA Interlab L11 131 5 SWA
6/7/11 11:51 AM EPA Interlab L11 1315 SWA
6/7/11 11:53 AM EPA Interlab L11 131 5 SWA
6/7/11 11:55 AM EPA Interlab L11 131 5 SWA
6/7/11 11:56 AM EPA Interlab L11 131 5 SWA
6/7/11 11:58 AM EPA Interlab L11 1315SWA
6/7/11 11:59 AM EPA Interlab L11 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-683
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Li SWA-L11-1315-T01-A 1 9.50E-01 U1/2
Li SWA-L11-1315-T02-A 1 9.50E-01 U1/2
Li SWA-L11-1315-T03-A 1 9.50E-01 U1/2
Li SWA-L11-1315-T04-A 1 9.50E-01 U1/2
Li SWA-L11-1315-T05-A 1 9.50E-01 U1/2
Li SWA-L11-1315-T06-A 1 9.50E-01 U1/2
Li SWA-L11-1315-T07-A 1 9.50E-01 U1/2
Li SWA-L11-1315-T08-A 1 9.50E-01 U1/2
Li SWA-L11-1315-T09-A 1 9.50E-01 U1/2
Li SWA-L11-1315-T01-B 1 9.50E-01 U1/2
Li SWA-L11-1315-T02-B 1 9.50E-01 U1/2
Li SWA-L11-1315-T03-B 1 9.50E-01 U1/2
Li SWA-L11-1315-T04-B 1 9.50E-01 U1/2
Li SWA-L11-1315-T05-B 1 9.50E-01 U1/2
Li SWA-L11-1315-T06-B 1 9.50E-01 U1/2
Li SWA-L11-1315-T07-B 1 9.50E-01 U1/2
Li SWA-L11-1315-T08-B 1 9.50E-01 U1/2
Li SWA-L11-1315-T09-B 1 9.50E-01 U1/2
Li SWA-L11-1315-T01-C 1 9.50E-01 U1/2
Li SWA-L11-1315-T02-C 1 9.50E-01 U1/2
Li SWA-L11-1315-T03-C 1 9.50E-01 U1/2
Li SWA-L11-1315-T04-C 1 9.50E-01 U1/2
Li SWA-L11-1315-T05-C 1 9.50E-01 U1/2
Li SWA-L11-1315-T06-C 1 9.50E-01 U1/2
Li SWA-L11-1315-T07-C 1 9.50E-01 U1/2
Li SWA-L11-1315-T08-C 1 9.50E-01 U1/2
Li SWA-L11-1315-T09-C 1 9.50E-01 U1/2
Li SWA-L11-1315-M01-A 1 9.50E-01 U1/2
Li SWA-L11-1315-M02-A 1 9.50E-01 U1/2
Li SWA-L11-1315-M03-A 1 9.50E-01 U1/2
Li SWA-L11-1315-M04-A 1 9.50E-01 U1/2
Li SWA-L11-1315-M05-A 1 9.50E-01 U1/2
Li SWA-L11-1315-M06-A 1 9.50E-01 U1/2
Li SWA-L11-1315-M07-A 1 9.50E-01 U1/2
Li SWA-L11-1315-M08-A 1 9.50E-01 U1/2
Li SWA-L11-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 2.70 1.90 6.00
9.50E-01 1.22 1.90 6.00
9.50E-01 2.93 1.90 6.00 10000 1000
9.50E-01 0.88 1.90 6.00
9.50E-01 1.72 1.90 6.00
9.50E-01 4.51 1.90 6.00
9.50E-01 2.82 1.90 6.00
9.50E-01 3.05 1.90 6.00
9.50E-01 3.20 1.90 6.00
9.50E-01 11.66 1.90 6.00
9.50E-01 4.38 1.90 6.00
9.50E-01 1.11 1.90 6.00 10000 1000
9.50E-01 4.62 1.90 6.00
9.50E-01 5.97 1.90 6.00
9.50E-01 4.48 1.90 6.00
9.50E-01 2.54 1.90 6.00
9.50E-01 3.93 1.90 6.00
9.50E-01 8.42 1.90 6.00
9.50E-01 3.44 1.90 6.00
9.50E-01 9.87 1.90 6.00
9.50E-01 7.47 1.90 6.00 10000 1000
9.50E-01 5.06 1.90 6.00
9.50E-01 5.13 1.90 6.00
9.50E-01 5.13 1.90 6.00
9.50E-01 3.80 1.90 6.00
9.50E-01 3.78 1.90 6.00
9.50E-01 3.06 1.90 6.00
9.50E-01 4.02 1.90 6.00
9.50E-01 3.20 1.90 6.00
9.50E-01 7.82 1.90 6.00
9.50E-01 8.11 1.90 6.00
9.50E-01 1.03 1.90 6.00
9.50E-01 1.60 1.90 6.00
9.50E-01 10.99 1.90 6.00
9.50E-01 5.40 1.90 6.00
9.50E-01 7.04 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.92E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.95E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.19E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1:36 AM EPA Interlab L11 131 5 SWA
6/7/11 1 1 :38 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :40 AM EPA Interlab L1 1 1315SWA
6/7/11 11:41 AM EPA Interlab L11 1315SWA
6/7/11 1 1 :43 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :45 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :46 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :48 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :50 AM EPA Interlab L1 1 1315SWA
6/7/11 11:51 AM EPA Interlab L11 131 5 SWA
6/7/11 1 1 :53 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :55 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :56 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :58 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :59 AM EPA Interlab L1 1 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-684
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Mn SWA-L11-1315-T01-A 1 1.00E+00 U1/2
Mn SWA-L11-1315-T02-A 1 1.00E+00 U1/2
Mn SWA-L11-1315-T03-A 1 1.00E+00 U1/2
Mn SWA-L11-1315-T04-A 1 1.00E+00 U1/2
Mn SWA-L11-1315-T05-A 1 1.00E+00 U1/2
Mn SWA-L11-1315-T06-A 1 1.00E+00 U1/2
Mn SWA-L11-1315-T07-A 1 1.00E+00 U1/2
Mn SWA-L11-1315-T08-A 1 1.00E+00 U1/2
Mn SWA-L11-1315-T09-A 1 1.00E+00 U1/2
Mn SWA-L11-1315-T01-B 1 1.00E+00 U1/2
Mn SWA-L11-1315-T02-B 1 1.00E+00 U1/2
Mn SWA-L11-1315-T03-B 1 1.00E+00 U1/2
Mn SWA-L11-1315-T04-B 1 1.00E+00 U1/2
Mn SWA-L11-1315-T05-B 1 1.00E+00 U1/2
Mn SWA-L11-1315-T06-B 1 1.00E+00 U1/2
Mn SWA-L11-1315-T07-B 1 1.00E+00 U1/2
Mn SWA-L11-1315-T08-B 1 1.00E+00 U1/2
Mn SWA-L11-1315-T09-B 1 1.00E+00 U1/2
Mn SWA-L11-1315-T01-C 1 1.00E+00 U1/2
Mn SWA-L11-1315-T02-C 1 1.00E+00 U1/2
Mn SWA-L11-1315-T03-C 1 1.00E+00 U1/2
Mn SWA-L11-1315-T04-C 1 1.00E+00 U1/2
Mn SWA-L11-1315-T05-C 1 1.00E+00 U1/2
Mn SWA-L11-1315-T06-C 1 1.00E+00 U1/2
Mn SWA-L11-1315-T07-C 1 1.00E+00 U1/2
Mn SWA-L11-1315-T08-C 1 1.00E+00 U1/2
Mn SWA-L11-1315-T09-C 1 1.00E+00 U1/2
Mn SWA-L11-1315-M01-A 1 1.00E+00 U1/2
Mn SWA-L11-1315-M02-A 1 1.00E+00 U1/2
Mn SWA-L11-1315-M03-A 1 1.00E+00 U1/2
Mn SWA-L11-1315-M04-A 1 1.00E+00 U1/2
Mn SWA-L11-1315-M05-A 1 1.00E+00 U1/2
Mn SWA-L11-1315-M06-A 1 1.00E+00 U1/2
Mn SWA-L11-1315-M07-A 1 1.00E+00 U1/2
Mn SWA-L11-1315-M08-A 1 1.00E+00 U1/2
Mn SWA-L11-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 51.88 2.00 6.40
1.00E+00 62.58 2.00 6.40
1.00E+00 56.04 2.00 6.40 10000 1000
1.00E+00 2.93 2.00 6.40
1.00E+00 20.81 2.00 6.40
1.00E+00 3.99 2.00 6.40
1.00E+00 24.72 2.00 6.40
1.00E+00 52.36 2.00 6.40
1.00E+00 30.86 2.00 6.40
1.00E+00 83.17 2.00 6.40
1.00E+00 16.13 2.00 6.40
1.00E+00 17.46 2.00 6.40 10000 1000
1.00E+00 10.08 2.00 6.40
1.00E+00 58.69 2.00 6.40
1.00E+00 5.91 2.00 6.40
1.00E+00 32.32 2.00 6.40
1.00E+00 24.95 2.00 6.40
1.00E+00 48.84 2.00 6.40
1.00E+00 49.58 2.00 6.40
1.00E+00 20.24 2.00 6.40
1.00E+00 39.09 2.00 6.40 10000 1000
1.00E+00 8.76 2.00 6.40
1.00E+00 10.98 2.00 6.40
1.00E+00 11.53 2.00 6.40
1.00E+00 37.79 2.00 6.40
1.00E+00 28.22 2.00 6.40
1.00E+00 22.95 2.00 6.40
1.00E+00 69.96 2.00 6.40
1.00E+00 57.98 2.00 6.40
1.00E+00 49.76 2.00 6.40
1.00E+00 11.94 2.00 6.40
1.00E+00 34.08 2.00 6.40
1.00E+00 0.17 2.00 6.40
1.00E+00 38.32 2.00 6.40
1.00E+00 71.24 2.00 6.40
1.00E+00 28.32 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.82E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.72E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :36 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1:38 AM EPA Interlab L11 1315SWA
6/7/11 11:40 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:41 AM EPA Interlab L11 1315 SWA
6/7/11 11:43 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:45 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:46 AM EPA Interlab L1 1 131 5 SWA
6/7/11 11:48 AM EPA Interlab L11 131 5 SWA
6/7/11 11:50 AM EPA Interlab L11 131 5 SWA
6/7/11 11:51 AM EPA Interlab L11 131 5 SWA
6/7/11 11:53 AM EPA Interlab L11 131 5 SWA
6/7/11 11:55 AM EPA Interlab L11 1315SWA
6/7/11 11:56 AM EPA Interlab L11 1315SWA
6/7/11 11:58 AM EPA Interlab L11 1315SWA
6/7/11 11:59 AM EPA Interlab L11 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-685
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Mg SWA-L11-1315-T01-A 1 2.31E+00 E
Mg SWA-L11-1315-T02-A 1 8.28E+00
Mg SWA-L11-1315-T03-A 1 3.16E+01
Mg SWA-L11-1315-T04-A 1 8.93E+00
Mg SWA-L11-1315-T05-A 1 1.82E+01
Mg SWA-L11-1315-T06-A 1 3.15E+01
Mg SWA-L11-1315-T07-A 1 2.77E+01
Mg SWA-L11-1315-T08-A 1 3.98E+01
Mg SWA-L11-1315-T09-A 1 1.23E+01
Mg SWA-L11-1315-T01-B 1 3.45E+00
Mg SWA-L11-1315-T02-B 1 7.69E+00
Mg SWA-L11-1315-T03-B 1 2.79E+01
Mg SWA-L11-1315-T04-B 1 5.22E+00
Mg SWA-L11-1315-T05-B 1 1.19E+01
Mg SWA-L11-1315-T06-B 1 3.47E+01
Mg SWA-L11-1315-T07-B 1 3.05E+01
Mg SWA-L11-1315-T08-B 1 2.79E+01
Mg SWA-L11-1315-T09-B 1 7.13E+00
Mg SWA-L11-1315-T01-C 1 2.12E+00 E
Mg SWA-L11-1315-T02-C 1 7.71E+00
Mg SWA-L11-1315-T03-C 1 2.90E+01
Mg SWA-L11-1315-T04-C 1 8.49E+00
Mg SWA-L11-1315-T05-C 1 1.50E+01
Mg SWA-L11-1315-T06-C 1 3.26E+01
Mg SWA-L11-1315-T07-C 1 2.93E+01
Mg SWA-L11-1315-T08-C 1 3.44E+01
Mg SWA-L11-1315-T09-C 1 8.49E+00
Mg SWA-L11-1315-M01-A 1 5.00E-01 U1/2
Mg SWA-L11-1315-M02-A 1 5.00E-01 U1/2
Mg SWA-L11-1315-M03-A 1 5.00E-01 U1/2
Mg SWA-L11-1315-M04-A 1 5.00E-01 U1/2
Mg SWA-L11-1315-M05-A 1 5.00E-01 U1/2
Mg SWA-L11-1315-M06-A 1 5.00E-01 U1/2
Mg SWA-L11-1315-M07-A 1 5.00E-01 U1/2
Mg SWA-L11-1315-M08-A 1 5.00E-01 U1/2
Mg SWA-L11-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.31E+00 53.64 1.00 3.18
8.28E+00 10.38 1.00 3.18
3.16E+01 6.46 1.00 3.18 10000 1000
8.93E+00 7.63 1.00 3.18
1.82E+01 57.08 1.00 3.18
315E+01 14.51 1.00 3.18
2.77E+01 46.09 1.00 3.18
398E+01 3.59 1.00 3.18
1.23E+01 8.72 1.00 3.18
345E+00 44.07 1.00 3.18
7.69E+00 11.15 1.00 3.18
2.79E+01 8.22 1.00 3.18 10000 1000
5.22E+00 36.16 1.00 3.18
1.19E+01 6.40 1.00 3.18
3.47E+01 1.70 1.00 3.18
3.05E+01 32.11 1.00 3.18
2.79E+01 3.24 1.00 3.18
7.13E+00 6.43 1.00 3.18
2.12E+00 27.27 1.00 3.18
7.71E+00 34.11 1.00 3.18
2.90E+01 2.09 1.00 3.18 10000 1000
8.49E+00 49.22 1.00 3.18
1.50E+01 29.76 1.00 3.18
3.26E+01 2.70 1.00 3.18
2.93E+01 29.11 1.00 3.18
3.44E+01 7.31 1.00 3.18
8.49E+00 5.78 1.00 3.18
5.00E-01 11.10 1.00 3.18
5.00E-01 24.45 1.00 3.18
5.00E-01 46.64 1.00 3.18
5.00E-01 8.87 1.00 3.18
5.00E-01 2.81 1.00 3.18
5.00E-01 1.58 1.00 3.18
5.00E-01 13.15 1.00 3.18
5.00E-01 8.66 1.00 3.18
5.00E-01 10.69 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.06E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :36 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1:38 AM EPA Interlab L11 1315SWA
6/7/11 11:40 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:41 AM EPA Interlab L11 1315 SWA
6/7/11 11:43 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:45 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:46 AM EPA Interlab L1 1 131 5 SWA
6/7/11 11:48 AM EPA Interlab L11 131 5 SWA
6/7/11 11:50 AM EPA Interlab L11 131 5 SWA
6/7/11 11:51 AM EPA Interlab L11 131 5 SWA
6/7/11 11:53 AM EPA Interlab L11 131 5 SWA
6/7/11 11:55 AM EPA Interlab L11 1315SWA
6/7/11 11:56 AM EPA Interlab L11 1315SWA
6/7/11 11:58 AM EPA Interlab L11 1315SWA
6/7/11 11:59 AM EPA Interlab L11 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-686
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Mo SWA-L11-1315-T01-A 1 3.45E+00 E
Mo SWA-L11-1315-T02-A 1 6.12E+00
Mo SWA-L11-1315-T03-A 1 2.94E+00 E
Mo SWA-L11-1315-T04-A 1 1.02E+01
Mo SWA-L11-1315-T05-A 1 6.78E+00
Mo SWA-L11-1315-T06-A 1 6.62E+00
Mo SWA-L11-1315-T07-A 1 4.17E+00
Mo SWA-L11-1315-T08-A 1 1.75E+00 E
Mo SWA-L11-1315-T09-A 1 2.15E+00 E
Mo SWA-L11-1315-T01-B 1 2.21E+00 E
Mo SWA-L11-1315-T02-B 1 5.47E+00
Mo SWA-L11-1315-T03-B 1 1.89E+00 E
Mo SWA-L11-1315-T04-B 1 8.62E+00
Mo SWA-L11-1315-T05-B 1 4.97E+00
Mo SWA-L11-1315-T06-B 1 8.49E+00
Mo SWA-L11-1315-T07-B 1 3.89E+00
Mo SWA-L11-1315-T08-B 1 1.81E+00 E
Mo SWA-L11-1315-T09-B 1 2.49E+00 E
Mo SWA-L11-1315-T01-C 1 2.22E+00 E
Mo SWA-L11-1315-T02-C 1 7.03E+00
Mo SWA-L11-1315-T03-C 1 3.13E+00 E
Mo SWA-L11-1315-T04-C 1 1.30E+01
Mo SWA-L11-1315-T05-C 1 6.53E+00
Mo SWA-L11-1315-T06-C 1 9.17E+00
Mo SWA-L11-1315-T07-C 1 5.16E+00
Mo SWA-L11-1315-T08-C 1 2.05E+00 E
Mo SWA-L11-1315-T09-C 1 2.24E+00 E
Mo SWA-L11-1315-M01-A 1 6.00E-01 U1/2
Mo SWA-L11-1315-M02-A 1 6.00E-01 U1/2
Mo SWA-L11-1315-M03-A 1 6.00E-01 U1/2
Mo SWA-L11-1315-M04-A 1 6.00E-01 U1/2
Mo SWA-L11-1315-M05-A 1 6.00E-01 U1/2
Mo SWA-L11-1315-M06-A 1 6.00E-01 U1/2
Mo SWA-L11-1315-M07-A 1 6.00E-01 U1/2
Mo SWA-L11-1315-M08-A 1 6.00E-01 U1/2
Mo SWA-L11-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.45E+00 15.66 1.20 3.82
6.12E+00 2.61 1.20 3.82
2.94E+00 2.81 1.20 3.82 10000 1000
1.02E+01 1.55 1.20 3.82
6.78E+00 7.28 1.20 3.82
6.62E+00 2.14 1.20 3.82
4.17E+00 1.93 1.20 3.82
1.75E+00 33.95 1.20 3.82
2.15E+00 21.05 1.20 3.82
2.21E+00 4.34 1.20 3.82
5.47E+00 2.97 1.20 3.82
1.89E+00 31.38 1.20 3.82 10000 1000
8.62E+00 7.84 1.20 3.82
4.97E+00 1.50 1.20 3.82
8.49E+00 1.69 1.20 3.82
389E+00 18.66 1.20 3.82
1.81E+00 25.09 1.20 3.82
2.49E+00 12.49 1.20 3.82
2.22E+00 5.62 1.20 3.82
7.03E+00 7.40 1.20 3.82
313E+00 29.35 1.20 3.82 10000 1000
1.30E+01 2.84 1.20 3.82
6.53E+00 10.82 1.20 3.82
9.17E+00 8.09 1.20 3.82
5.16E+00 1.88 1.20 3.82
2.05E+00 7.50 1.20 3.82
2.24E+00 21.73 1.20 3.82
6.00E-01 67.42 1.20 3.82
6.00E-01 26.13 1.20 3.82
6.00E-01 19.50 1.20 3.82
6.00E-01 12.30 1.20 3.82
6.00E-01 59.03 1.20 3.82
6.00E-01 27.75 1.20 3.82
6.00E-01 42.28 1.20 3.82
6.00E-01 35.44 1.20 3.82
6.00E-01 15.43 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.05E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :36 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1:38 AM EPA Interlab L11 1315SWA
6/7/11 11:40 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:41 AM EPA Interlab L11 1315 SWA
6/7/11 11:43 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:45 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:46 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:48 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:50 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:51 AM EPA Interlab L11 1315 SWA
6/7/11 11:53 AM EPA Interlab L11 131 5 SWA
6/7/11 11:55 AM EPA Interlab L11 131 5 SWA
6/7/11 11:56 AM EPA Interlab L11 131 5 SWA
6/7/11 11:58 AM EPA Interlab L11 131 5 SWA
6/7/11 11:59 AM EPA Interlab L11 131 5 SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L1 1 1315 SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-687
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ni SWA-L11-1315-T01-A 1 9.00E-01 U1/2
Ni SWA-L11-1315-T02-A 1 9.00E-01 U1/2
Ni SWA-L11-1315-T03-A 1 9.00E-01 U1/2
Ni SWA-L11-1315-T04-A 1 9.00E-01 U1/2
Ni SWA-L11-1315-T05-A 1 9.00E-01 U1/2
Ni SWA-L11-1315-T06-A 1 9.00E-01 U1/2
Ni SWA-L11-1315-T07-A 1 9.00E-01 U1/2
Ni SWA-L11-1315-T08-A 1 9.00E-01 U1/2
Ni SWA-L11-1315-T09-A 1 9.00E-01 U1/2
Ni SWA-L11-1315-T01-B 1 9.00E-01 U1/2
Ni SWA-L11-1315-T02-B 1 9.00E-01 U1/2
Ni SWA-L11-1315-T03-B 1 9.00E-01 U1/2
Ni SWA-L11-1315-T04-B 1 9.00E-01 U1/2
Ni SWA-L11-1315-T05-B 1 9.00E-01 U1/2
Ni SWA-L11-1315-T06-B 1 9.00E-01 U1/2
Ni SWA-L11-1315-T07-B 1 9.00E-01 U1/2
Ni SWA-L11-1315-T08-B 1 9.00E-01 U1/2
Ni SWA-L11-1315-T09-B 1 9.00E-01 U1/2
Ni SWA-L11-1315-T01-C 1 9.00E-01 U1/2
Ni SWA-L11-1315-T02-C 1 9.00E-01 U1/2
Ni SWA-L11-1315-T03-C 1 9.00E-01 U1/2
Ni SWA-L11-1315-T04-C 1 9.00E-01 U1/2
Ni SWA-L11-1315-T05-C 1 9.00E-01 U1/2
Ni SWA-L11-1315-T06-C 1 9.00E-01 U1/2
Ni SWA-L11-1315-T07-C 1 9.00E-01 U1/2
Ni SWA-L11-1315-T08-C 1 9.00E-01 U1/2
Ni SWA-L11-1315-T09-C 1 9.00E-01 U1/2
Ni SWA-L11-1315-M01-A 1 9.00E-01 U1/2
Ni SWA-L11-1315-M02-A 1 9.00E-01 U1/2
Ni SWA-L11-1315-M03-A 1 9.00E-01 U1/2
Ni SWA-L11-1315-M04-A 1 9.00E-01 U1/2
Ni SWA-L11-1315-M05-A 1 9.00E-01 U1/2
Ni SWA-L11-1315-M06-A 1 9.00E-01 U1/2
Ni SWA-L11-1315-M07-A 1 9.00E-01 U1/2
Ni SWA-L11-1315-M08-A 1 9.00E-01 U1/2
Ni SWA-L11-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 77.22 1.80 5.70
9.00E-01 21.43 1.80 5.70
9.00E-01 28.80 1.80 5.70 10000 1000
9.00E-01 63.29 1.80 5.70
9.00E-01 10.78 1.80 5.70
9.00E-01 57.98 1.80 5.70
9.00E-01 30.23 1.80 5.70
9.00E-01 52.10 1.80 5.70
9.00E-01 23.54 1.80 5.70
9.00E-01 32.19 1.80 5.70
9.00E-01 18.97 1.80 5.70
9.00E-01 16.14 1.80 5.70 10000 1000
9.00E-01 22.43 1.80 5.70
9.00E-01 15.36 1.80 5.70
9.00E-01 36.04 1.80 5.70
9.00E-01 14.45 1.80 5.70
9.00E-01 32.22 1.80 5.70
9.00E-01 4.40 1.80 5.70
9.00E-01 12.28 1.80 5.70
9.00E-01 6.17 1.80 5.70
9.00E-01 11.42 1.80 5.70 10000 1000
9.00E-01 19.86 1.80 5.70
9.00E-01 16.57 1.80 5.70
9.00E-01 24.72 1.80 5.70
9.00E-01 8.38 1.80 5.70
9.00E-01 28.75 1.80 5.70
9.00E-01 1.68 1.80 5.70
9.00E-01 21.22 1.80 5.70
9.00E-01 19.11 1.80 5.70
9.00E-01 11.92 1.80 5.70
9.00E-01 13.46 1.80 5.70
9.00E-01 3.22 1.80 5.70
9.00E-01 8.10 1.80 5.70
9.00E-01 9.44 1.80 5.70
9.00E-01 30.88 1.80 5.70
9.00E-01 39.43 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1:36 AM EPA Interlab L11 131 5 SWA
6/7/11 1 1 :38 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :40 AM EPA Interlab L1 1 1315SWA
6/7/11 11:41 AM EPA Interlab L11 1315SWA
6/7/11 1 1 :43 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :45 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :46 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :48 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :50 AM EPA Interlab L1 1 1315SWA
6/7/11 11:51 AM EPA Interlab L11 131 5 SWA
6/7/11 1 1 :53 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :55 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :56 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :58 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :59 AM EPA Interlab L1 1 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-688
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
P SWA-L11-1315-T01-A 1 3.19E+01
P SWA-L11-1315-T02-A 1 1.39E+01
P SWA-L11-1315-T03-A 1 1.27E+01
P SWA-L11-1315-T04-A 1 1.39E+01
P SWA-L11-1315-T05-A 1 2.15E+01
P SWA-L11-1315-T06-A 1 9.26E+00 E
P SWA-L11-1315-T07-A 1 1.16E+01 E
P SWA-L11-1315-T08-A 1 1.85E+00 U1/2
P SWA-L11-1315-T09-A 1 6.69E+00 E
P SWA-L11-1315-T01-B 1 1.95E+01
P SWA-L11-1315-T02-B 1 1.53E+01
P SWA-L11-1315-T03-B 1 1.25E+01
P SWA-L11-1315-T04-B 1 1.21E+01
P SWA-L11-1315-T05-B 1 2.04E+01
P SWA-L11-1315-T06-B 1 1.76E+01
P SWA-L11-1315-T07-B 1 2.00E+01
P SWA-L11-1315-T08-B 1 1.31E+01
P SWA-L11-1315-T09-B 1 1.67E+01
P SWA-L11-1315-T01-C 1 8.91E+00 E
P SWA-L11-1315-T02-C 1 2.05E+01
P SWA-L11-1315-T03-C 1 1.69E+01
P SWA-L11-1315-T04-C 1 2.24E+01
P SWA-L11-1315-T05-C 1 1.61E+01
P SWA-L11-1315-T06-C 1 1.07E+01 E
P SWA-L11-1315-T07-C 1 4.30E+00 E
P SWA-L11-1315-T08-C 1 1.10E+01 E
P SWA-L11-1315-T09-C 1 1.28E+01
P SWA-L11-1315-M01-A 1 1.85E+00 U1/2
P SWA-L11-1315-M02-A 1 1.85E+00 U1/2
P SWA-L11-1315-M03-A 1 1.85E+00 U1/2
P SWA-L11-1315-M04-A 1 1.85E+00 U1/2
P SWA-L11-1315-M05-A 1 1.85E+00 U1/2
P SWA-L11-1315-M06-A 1 1.85E+00 U1/2
P SWA-L11-1315-M07-A 1 1.85E+00 U1/2
P SWA-L11-1315-M08-A 1 1.85E+00 U1/2
P SWA-L11-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.19E+01 1.85 3.70 11.80
1.39E+01 7.54 3.70 11.80
1.27E+01 14.35 3.70 11.80 10000 1000
1.39E+01 8.63 3.70 11.80
2.15E+01 3.83 3.70 11.80
9.26E+00 2.23 3.70 11.80
1.16E+01 16.00 3.70 11.80
1.85E+00 21.75 3.70 11.80
6.69E+00 7.05 3.70 11.80
1.95E+01 7.80 3.70 11.80
1.53E+01 5.93 3.70 11.80
1.25E+01 1.21 3.70 11.80 10000 1000
1.21E+01 9.70 3.70 11.80
2.04E+01 1.72 3.70 11.80
1.76E+01 4.15 3.70 11.80
2.00E+01 3.25 3.70 11.80
1.31E+01 2.09 3.70 11.80
1.67E+01 2.87 3.70 11.80
8.91E+00 16.68 3.70 11.80
2.05E+01 2.92 3.70 11.80
1.69E+01 2.46 3.70 11.80 10000 1000
2.24E+01 6.73 3.70 11.80
1.61E+01 7.59 3.70 11.80
1.07E+01 4.19 3.70 11.80
4.30E+00 29.63 3.70 11.80
1.10E+01 10.33 3.70 11.80
1.28E+01 5.77 3.70 11.80
1.85E+00 8.46 3.70 11.80
1.85E+00 28.15 3.70 11.80
1.85E+00 8.52 3.70 11.80
1.85E+00 15.00 3.70 11.80
1.85E+00 31.43 3.70 11.80
1.85E+00 25.22 3.70 11.80
1.85E+00 15.38 3.70 11.80
1.85E+00 4.45 3.70 11.80
1.85E+00 3.93 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :36 AM EPA Interlab L1 1 1315SWA
6/7/11 11:38 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:40 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:41 AM EPA Interlab L11 1315 SWA
6/7/11 11:43 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:45 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:46 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:48 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:50 AM EPA Interlab L1 1 131 5 SWA
6/7/11 11:51 AM EPA Interlab L11 1315 SWA
6/7/11 11:53 AM EPA Interlab L11 131 5 SWA
6/7/11 11:55 AM EPA Interlab L11 131 5 SWA
6/7/11 11:56 AM EPA Interlab L11 131 5 SWA
6/7/11 11:58 AM EPA Interlab L11 1315SWA
6/7/11 11:59 AM EPA Interlab L11 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-689
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
K SWA-L11-1315-T01-A 1 1.27E+04
K SWA-L11-1315-T02-A 1 3.21E+04
K SWA-L11-1315-T03-A 1 1.82E+04
K SWA-L11-1315-T04-A 1 4.84E+04
K SWA-L11-1315-T05-A 1 3.70E+04
K SWA-L11-1315-T06-A 1 4.25E+04
K SWA-L11-1315-T07-A 1 2.89E+04
K SWA-L11-1315-T08-A 1 1.22E+04
K SWA-L11-1315-T09-A 1 1.87E+04
K SWA-L11-1315-T01-B 1 9.88E+03
K SWA-L11-1315-T02-B 1 2.97E+04
K SWA-L11-1315-T03-B 1 1.57E+04
K SWA-L11-1315-T04-B 1 4.60E+04
K SWA-L11-1315-T05-B 1 3.66E+04
K SWA-L11-1315-T06-B 1 4.40E+04
K SWA-L11-1315-T07-B 1 2.87E+04
K SWA-L11-1315-T08-B 1 1.15E+04
K SWA-L11-1315-T09-B 1 2.04E+04
K SWA-L11-1315-T01-C 1 1.14E+04
K SWA-L11-1315-T02-C 1 3.93E+04
K SWA-L11-1315-T03-C 1 2.26E+04
K SWA-L11-1315-T04-C 1 6.00E+04
K SWA-L11-1315-T05-C 1 4.13E+04
K SWA-L11-1315-T06-C 1 4.89E+04
K SWA-L11-1315-T07-C 1 3.29E+04
K SWA-L11-1315-T08-C 1 1.28E+04
K SWA-L11-1315-T09-C 1 2.11E+04
K SWA-L11-1315-M01-A 1 1.17E+01
K SWA-L11-1315-M02-A 1 2.25E+01
K SWA-L11-1315-M03-A 1 4.45E+01
K SWA-L11-1315-M04-A 1 1.65E+01
K SWA-L11-1315-M05-A 1 3.12E+01
K SWA-L11-1315-M06-A 1 4.50E+01
K SWA-L11-1315-M07-A 1 1.51E+01
K SWA-L11-1315-M08-A 1 2.78E+01
K SWA-L11-1315-M09-A 1 1.42E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.27E+04 2.83 1.60 5.09
3.21 E+04 1.21 1.60 5.09
1.82E+04 1.59 1.60 5.09 10000 1000
4.84E+04 1.18 1.60 5.09
370E+04 1.42 1.60 5.09
4.25E+04 1.44 1.60 5.09
2.89E+04 0.45 1.60 5.09
1.22E+04 3.11 1.60 5.09
1.87E+04 1.34 1.60 5.09
9.88E+03 1.18 1.60 5.09
2.97E+04 0.89 1.60 5.09
1.57E+04 1.83 1.60 5.09 10000 1000
4.60E+04 0.72 1.60 5.09
3.66E+04 0.65 1.60 5.09
4.40E+04 1.10 1.60 5.09
2.87E+04 1.65 1.60 5.09
1.15E+04 1.37 1.60 5.09
2.04E+04 0.98 1.60 5.09
1.14E+04 6.37 1.60 5.09
3.93E+04 1.11 1.60 5.09
2.26E+04 1.11 1.60 5.09 10000 1000
6.00E+04 1.31 1.60 5.09
4.13E+04 1.27 1.60 5.09
4.89E+04 0.67 1.60 5.09
3.29E+04 1.64 1.60 5.09
1.28E+04 1.99 1.60 5.09
2.11E+04 0.87 1.60 5.09
1.17E+01 3.74 1.60 5.09
2.25E+01 1.99 1.60 5.09
4.45E+01 0.86 1.60 5.09
1.65E+01 4.15 1.60 5.09
3.12E+01 6.07 1.60 5.09
4.50E+01 0.73 1.60 5.09
1.51E+01 4.11 1.60 5.09
2.78E+01 7.50 1.60 5.09
1.42E+01 14.31 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.92E+04 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.68E+04 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.36E+04 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :36 AM EPA Interlab L1 1 1315SWA
6/7/11 11:38 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:40 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:41 AM EPA Interlab L11 1315 SWA
6/7/11 11:43 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:45 AM EPA Interlab L1 1 131 5 SWA
6/7/11 11:46 AM EPA Interlab L11 131 5 SWA
6/7/11 11:48 AM EPA Interlab L11 131 5 SWA
6/7/11 11:50 AM EPA Interlab L11 131 5 SWA
6/7/11 11:51 AM EPA Interlab L11 131 5 SWA
6/7/11 11:53 AM EPA Interlab L11 1315SWA
6/7/11 11:55 AM EPA Interlab L11 1315SWA
6/7/11 11:56 AM EPA Interlab L11 1315SWA
6/7/11 11:58 AM EPA Interlab L11 1315SWA
6/7/11 11:59 AM EPA Interlab L11 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-690
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Se SWA-L11-1315-T01-A 1 2.97E+03
Se SWA-L11-1315-T02-A 1 4.56E+03
Se SWA-L11-1315-T03-A 1 2.50E+03
Se SWA-L11-1315-T04-A 1 6.79E+03
Se SWA-L11-1315-T05-A 1 4.71E+03
Se SWA-L11-1315-T06-A 1 4.89E+03
Se SWA-L11-1315-T07-A 1 2.90E+03
Se SWA-L11-1315-T08-A 1 1.06E+03
Se SWA-L11-1315-T09-A 1 1.75E+03
Se SWA-L11-1315-T01-B 1 2.07E+03
Se SWA-L11-1315-T02-B 1 3.87E+03
Se SWA-L11-1315-T03-B 1 2.01E+03
Se SWA-L11-1315-T04-B 1 6.05E+03
Se SWA-L11-1315-T05-B 1 4.47E+03
Se SWA-L11-1315-T06-B 1 5.00E+03
Se SWA-L11-1315-T07-B 1 2.91E+03
Se SWA-L11-1315-T08-B 1 1.06E+03
Se SWA-L11-1315-T09-B 1 1.97E+03
Se SWA-L11-1315-T01-C 1 1.81E+03
Se SWA-L11-1315-T02-C 1 5.04E+03
Se SWA-L11-1315-T03-C 1 3.20E+03
Se SWA-L11-1315-T04-C 1 8.57E+03
Se SWA-L11-1315-T05-C 1 5.27E+03
Se SWA-L11-1315-T06-C 1 5.91E+03
Se SWA-L11-1315-T07-C 1 3.53E+03
Se SWA-L11-1315-T08-C 1 1.26E+03
Se SWA-L11-1315-T09-C 1 2.16E+03
Se SWA-L11-1315-M01-A 1 7.50E+00 U1/2
Se SWA-L11-1315-M02-A 1 7.50E+00 U1/2
Se SWA-L11-1315-M03-A 1 7.50E+00 U1/2
Se SWA-L11-1315-M04-A 1 7.50E+00 U1/2
Se SWA-L11-1315-M05-A 1 7.50E+00 U1/2
Se SWA-L11-1315-M06-A 1 7.50E+00 U1/2
Se SWA-L11-1315-M07-A 1 7.50E+00 U1/2
Se SWA-L11-1315-M08-A 1 7.50E+00 U1/2
Se SWA-L11-1315-M09-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.97E+03 2.32 15.00 47.70
4.56E+03 0.78 15.00 47.70
2.50E+03 1.40 15.00 47.70 10000 1000
6.79E+03 1.39 15.00 47.70
4.71E+03 0.49 15.00 47.70
4.89E+03 1.79 15.00 47.70
2.90E+03 1.72 15.00 47.70
1.06E+03 3.90 15.00 47.70
1.75E+03 2.15 15.00 47.70
2.07E+03 0.76 15.00 47.70
387E+03 0.95 15.00 47.70
2.01E+03 2.87 15.00 47.70 10000 1000
6.05E+03 1.19 15.00 47.70
4.47E+03 0.91 15.00 47.70
5.00E+03 0.96 15.00 47.70
2.91E+03 2.51 15.00 47.70
1.06E+03 1.13 15.00 47.70
1.97E+03 0.42 15.00 47.70
1.81E+03 6.43 15.00 47.70
5.04E+03 1.31 15.00 47.70
3.20E+03 0.91 15.00 47.70 10000 1000
8.57E+03 1.22 15.00 47.70
5.27E+03 0.96 15.00 47.70
5.91E+03 1.23 15.00 47.70
3.53E+03 1.62 15.00 47.70
1.26E+03 2.57 15.00 47.70
2.16E+03 2.11 15.00 47.70
7.50E+00 11.31 15.00 47.70
7.50E+00 30.57 15.00 47.70
7.50E+00 49.76 15.00 47.70
7.50E+00 13.43 15.00 47.70
7.50E+00 33.88 15.00 47.70
7.50E+00 14.67 15.00 47.70
7.50E+00 12.74 15.00 47.70
7.50E+00 27.52 15.00 47.70
7.50E+00 35.75 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.47E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.99E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.15E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :36 AM EPA Interlab L1 1 1315SWA
6/7/11 11:38 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:40 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:41 AM EPA Interlab L11 1315 SWA
6/7/11 11:43 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:45 AM EPA Interlab L1 1 131 5 SWA
6/7/11 11:46 AM EPA Interlab L11 131 5 SWA
6/7/11 11:48 AM EPA Interlab L11 131 5 SWA
6/7/11 11:50 AM EPA Interlab L11 131 5 SWA
6/7/11 11:51 AM EPA Interlab L11 131 5 SWA
6/7/11 11:53 AM EPA Interlab L11 1315SWA
6/7/11 11:55 AM EPA Interlab L11 1315SWA
6/7/11 11:56 AM EPA Interlab L11 1315SWA
6/7/11 11:58 AM EPA Interlab L11 1315SWA
6/7/11 11:59 AM EPA Interlab L11 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-691
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Si SWA-L11-1315-T01-A 1 1.18E+03
Si SWA-L11-1315-T02-A 1 5.38E+03
Si SWA-L11-1315-T03-A 1 3.99E+03
Si SWA-L11-1315-T04-A 1 8.91E+03
Si SWA-L11-1315-T05-A 1 8.56E+03
Si SWA-L11-1315-T06-A 1 9.06E+03
Si SWA-L11-1315-T07-A 1 8.24E+03
Si SWA-L11-1315-T08-A 1 5.92E+03
Si SWA-L11-1315-T09-A 1 7.50E+03
Si SWA-L11-1315-T01-B 1 8.20E+02
Si SWA-L11-1315-T02-B 1 4.31E+03
Si SWA-L11-1315-T03-B 1 3.04E+03
Si SWA-L11-1315-T04-B 1 7.96E+03
Si SWA-L11-1315-T05-B 1 7.92E+03
Si SWA-L11-1315-T06-B 1 9.07E+03
Si SWA-L11-1315-T07-B 1 7.94E+03
Si SWA-L11-1315-T08-B 1 5.46E+03
Si SWA-L11-1315-T09-B 1 7.82E+03
Si SWA-L11-1315-T01-C 1 9.99E+02
Si SWA-L11-1315-T02-C 1 4.20E+03
Si SWA-L11-1315-T03-C 1 3.11E+03
Si SWA-L11-1315-T04-C 1 7.51E+03
Si SWA-L11-1315-T05-C 1 7.16E+03
Si SWA-L11-1315-T06-C 1 8.37E+03
Si SWA-L11-1315-T07-C 1 7.79E+03
Si SWA-L11-1315-T08-C 1 5.45E+03
Si SWA-L11-1315-T09-C 1 7.10E+03
Si SWA-L11-1315-M01-A 1 5.50E-01 U1/2
Si SWA-L11-1315-M02-A 1 5.50E-01 U1/2
Si SWA-L11-1315-M03-A 1 5.50E-01 U1/2
Si SWA-L11-1315-M04-A 1 5.50E-01 U1/2
Si SWA-L11-1315-M05-A 1 5.50E-01 U1/2
Si SWA-L11-1315-M06-A 1 5.50E-01 U1/2
Si SWA-L11-1315-M07-A 1 5.50E-01 U1/2
Si SWA-L11-1315-M08-A 1 5.50E-01 U1/2
Si SWA-L11-1315-M09-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.18E+03 2.93 1.10 3.50
5.38E+03 1.85 1.10 3.50
3.99E+03 2.19 1.10 3.50 10000 1000
8.91 E+03 1.80 1.10 3.50
8.56E+03 2.17 1.10 3.50
9.06E+03 1.45 1.10 3.50
8.24E+03 0.46 1.10 3.50
5.92E+03 3.15 1.10 3.50
7.50E+03 2.00 1.10 3.50
8.20E+02 1.66 1.10 3.50
4.31 E+03 0.93 1.10 3.50
3.04E+03 2.73 1.10 3.50 10000 1000
7.96E+03 1.03 1.10 3.50
7.92E+03 0.78 1.10 3.50
9.07E+03 0.51 1.10 3.50
7.94E+03 1.93 1.10 3.50
5.46E+03 1.68 1.10 3.50
7.82E+03 1.53 1.10 3.50
9.99E+02 6.07 1.10 3.50
4.20E+03 1.41 1.10 3.50
3.11E+03 2.40 1.10 3.50 10000 1000
7.51 E+03 0.77 1.10 3.50
7.16E+03 0.98 1.10 3.50
8.37E+03 1.14 1.10 3.50
7.79E+03 1.16 1.10 3.50
5.45E+03 1.50 1.10 3.50
7.10E+03 0.68 1.10 3.50
5.50E-01 25.23 1.10 3.50
5.50E-01 40.76 1.10 3.50
5.50E-01 6.19 1.10 3.50
5.50E-01 26.77 1.10 3.50
5.50E-01 39.55 1.10 3.50
5.50E-01 12.86 1.10 3.50
5.50E-01 28.15 1.10 3.50
5.50E-01 47.04 1.10 3.50
5.50E-01 18.39 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.93E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.98E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4. 11 E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1:36 AM EPA Interlab L11 131 5 SWA
6/7/11 1 1 :38 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :40 AM EPA Interlab L1 1 1315SWA
6/7/11 11:41 AM EPA Interlab L11 1315SWA
6/7/11 1 1 :43 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :45 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :46 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :48 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :50 AM EPA Interlab L1 1 1315SWA
6/7/11 11:51 AM EPA Interlab L11 131 5 SWA
6/7/11 1 1 :53 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :55 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :56 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :58 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :59 AM EPA Interlab L1 1 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-692
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Na SWA-L11-1315-T01-A 1 5.66E+04
Na SWA-L11-1315-T02-A 1 1.05E+05
Na SWA-L11-1315-T03-A 1 6.58E+04
Na SWA-L11-1315-T04-A 1 1.37E+05
Na SWA-L11-1315-T05-A 1 1.12E+05
Na SWA-L11-1315-T06-A 1 1.27E+05
Na SWA-L11-1315-T07-A 1 9.84E+04
Na SWA-L11-1315-T08-A 1 4.88E+04
Na SWA-L11-1315-T09-A 1 7.28E+04
Na SWA-L11-1315-T01-B 1 4.47E+04
Na SWA-L11-1315-T02-B 1 1.03E+05
Na SWA-L11-1315-T03-B 1 6.11E+04
Na SWA-L11-1315-T04-B 1 1.36E+05
Na SWA-L11-1315-T05-B 1 1.12E+05
Na SWA-L11-1315-T06-B 1 1.30E+05
Na SWA-L11-1315-T07-B 1 9.97E+04
Na SWA-L11-1315-T08-B 1 4.78E+04
Na SWA-L11-1315-T09-B 1 7.76E+04
Na SWA-L11-1315-T01-C 1 4.65E+04
Na SWA-L11-1315-T02-C 1 1.20E+05
Na SWA-L11-1315-T03-C 1 8.16E+04
Na SWA-L11-1315-T04-C 1 1.62E+05
Na SWA-L11-1315-T05-C 1 1.24E+05
Na SWA-L11-1315-T06-C 1 1.41E+05
Na SWA-L11-1315-T07-C 1 1.05E+05
Na SWA-L11-1315-T08-C 1 5.22E+04
Na SWA-L11-1315-T09-C 1 8.06E+04
Na SWA-L11-1315-M01-A 1 3.48E+01
Na SWA-L11-1315-M02-A 1 4.52E+01
Na SWA-L11-1315-M03-A 1 4.20E+01
Na SWA-L11-1315-M04-A 1 3.48E+01
Na SWA-L11-1315-M05-A 1 3.62E+01
Na SWA-L11-1315-M06-A 1 3.46E+01
Na SWA-L11-1315-M07-A 1 2.60E+01
Na SWA-L11-1315-M08-A 1 2.67E+01
Na SWA-L11-1315-M09-A 1 2.85E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.66E+04 4.80 2.50 8.00
1.05E+05 3.24 2.50 8.00
6.58E+04 5.61 2.50 8.00 10000 1000
1.37E+05 2.74 2.50 8.00
1.12E+05 4.03 2.50 8.00
1.27E+05 1.38 2.50 8.00
9.84E+04 7.07 2.50 8.00
4.88E+04 3.24 2.50 8.00
7.28E+04 2.70 2.50 8.00
4.47E+04 0.18 2.50 8.00
1.03E+05 0.21 2.50 8.00
6.11E+04 0.74 2.50 8.00 10000 1000
1.36E+05 0.31 2.50 8.00
1.12E+05 0.68 2.50 8.00
1.30E+05 0.42 2.50 8.00
9.97E+04 0.51 2.50 8.00
4.78E+04 0.09 2.50 8.00
7.76E+04 0.43 2.50 8.00
4.65E+04 0.10 2.50 8.00
1.20E+05 0.95 2.50 8.00
8.16E+04 0.88 2.50 8.00 10000 1000
1.62E+05 0.30 2.50 8.00
1.24E+05 0.94 2.50 8.00
1.41E+05 0.73 2.50 8.00
1.05E+05 0.50 2.50 8.00
5.22E+04 0.41 2.50 8.00
8.06E+04 0.37 2.50 8.00
3.48E+01 1.53 2.50 8.00
4.52E+01 0.79 2.50 8.00
4.20E+01 0.84 2.50 8.00
3.48E+01 0.22 2.50 8.00
3.62E+01 0.22 2.50 8.00
3.46E+01 0.52 2.50 8.00
2.60E+01 0.54 2.50 8.00
2.67E+01 1.17 2.50 8.00
2.85E+01 0.40 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.67E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.20E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.25E+04 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1:36 AM EPA Interlab L11 131 5 SWA
6/7/11 1 1 :38 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :40 AM EPA Interlab L1 1 1315SWA
6/7/11 11:41 AM EPA Interlab L11 1315SWA
6/7/11 1 1 :43 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :45 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :46 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :48 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :50 AM EPA Interlab L1 1 1315SWA
6/7/11 11:51 AM EPA Interlab L11 131 5 SWA
6/7/11 1 1 :53 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :55 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :56 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :58 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :59 AM EPA Interlab L1 1 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-693
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Sr SWA-L11-1315-T01-A 1 4.03E+00
Sr SWA-L11-1315-T02-A 1 8.00E+01
Sr SWA-L11-1315-T03-A 1 9.32E+01
Sr SWA-L11-1315-T04-A 1 1.90E+02
Sr SWA-L11-1315-T05-A 1 2.07E+02
Sr SWA-L11-1315-T06-A 1 2.45E+02
Sr SWA-L11-1315-T07-A 1 2.46E+02
Sr SWA-L11-1315-T08-A 1 1.95E+02
Sr SWA-L11-1315-T09-A 1 2.02E+02
Sr SWA-L11-1315-T01-B 1 3.36E+00
Sr SWA-L11-1315-T02-B 1 7.56E+01
Sr SWA-L11-1315-T03-B 1 7.23E+01
Sr SWA-L11-1315-T04-B 1 1.58E+02
Sr SWA-L11-1315-T05-B 1 1.73E+02
Sr SWA-L11-1315-T06-B 1 2.14E+02
Sr SWA-L11-1315-T07-B 1 2.05E+02
Sr SWA-L11-1315-T08-B 1 1.53E+02
Sr SWA-L11-1315-T09-B 1 1.93E+02
Sr SWA-L11-1315-T01-C 1 6.64E+00
Sr SWA-L11-1315-T02-C 1 9.37E+01
Sr SWA-L11-1315-T03-C 1 8.86E+01
Sr SWA-L11-1315-T04-C 1 1.77E+02
Sr SWA-L11-1315-T05-C 1 1.83E+02
Sr SWA-L11-1315-T06-C 1 2.32E+02
Sr SWA-L11-1315-T07-C 1 2.37E+02
Sr SWA-L11-1315-T08-C 1 1.68E+02
Sr SWA-L11-1315-T09-C 1 2.01E+02
Sr SWA-L11-1315-M01-A 1 5.00E-01 U1/2
Sr SWA-L11-1315-M02-A 1 5.00E-01 U1/2
Sr SWA-L11-1315-M03-A 1 5.00E-01 U1/2
Sr SWA-L11-1315-M04-A 1 5.00E-01 U1/2
Sr SWA-L11-1315-M05-A 1 5.00E-01 U1/2
Sr SWA-L11-1315-M06-A 1 5.00E-01 U1/2
Sr SWA-L11-1315-M07-A 1 5.00E-01 U1/2
Sr SWA-L11-1315-M08-A 1 5.00E-01 U1/2
Sr SWA-L11-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.03E+00 50.65 1.00 3.18
8.00E+01 1.60 1.00 3.18
9.32E+01 0.85 1.00 3.18 10000 1000
1.90E+02 2.52 1.00 3.18
2.07E+02 1.42 1.00 3.18
2.45E+02 1.55 1.00 3.18
2.46E+02 1.19 1.00 3.18
1.95E+02 3.21 1.00 3.18
2.02E+02 1.08 1.00 3.18
336E+00 2.21 1.00 3.18
7.56E+01 1.25 1.00 3.18
7.23E+01 2.88 1.00 3.18 10000 1000
1.58E+02 1.08 1.00 3.18
1.73E+02 0.66 1.00 3.18
2.14E+02 1.22 1.00 3.18
2.05E+02 2.53 1.00 3.18
1.53E+02 1.42 1.00 3.18
1.93E+02 0.95 1.00 3.18
6.64E+00 12.72 1.00 3.18
9.37E+01 0.92 1.00 3.18
8.86E+01 1.53 1.00 3.18 10000 1000
1.77E+02 1.09 1.00 3.18
1.83E+02 1.16 1.00 3.18
2.32E+02 1.23 1.00 3.18
2.37E+02 1.20 1.00 3.18
1.68E+02 2.18 1.00 3.18
2.01E+02 0.40 1.00 3.18
5.00E-01 13.52 1.00 3.18
5.00E-01 6.68 1.00 3.18
5.00E-01 2.85 1.00 3.18
5.00E-01 11.50 1.00 3.18
5.00E-01 8.96 1.00 3.18
5.00E-01 5.97 1.00 3.18
5.00E-01 11.65 1.00 3.18
5.00E-01 7.38 1.00 3.18
5.00E-01 18.61 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 . 1 1 E+03 1 02% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 . 1 1 E+03 1 03% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :36 AM EPA Interlab L1 1 1315SWA
6/7/11 11:38 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:40 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:41 AM EPA Interlab L11 1315 SWA
6/7/11 11:43 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:45 AM EPA Interlab L1 1 131 5 SWA
6/7/11 11:46 AM EPA Interlab L11 131 5 SWA
6/7/11 11:48 AM EPA Interlab L11 131 5 SWA
6/7/11 11:50 AM EPA Interlab L11 131 5 SWA
6/7/11 11:51 AM EPA Interlab L11 131 5 SWA
6/7/11 11:53 AM EPA Interlab L11 1315SWA
6/7/11 11:55 AM EPA Interlab L11 1315SWA
6/7/11 11:56 AM EPA Interlab L11 1315SWA
6/7/11 11:58 AM EPA Interlab L11 1315SWA
6/7/11 11:59 AM EPA Interlab L11 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-694
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
S SWA-L11-1315-T01-A 1 1.55E+04
S SWA-L11-1315-T02-A 1 2.47E+04
S SWA-L11-1315-T03-A 1 1.22E+04
S SWA-L11-1315-T04-A 1 4.13E+04
S SWA-L11-1315-T05-A 1 2.50E+04
S SWA-L11-1315-T06-A 1 3.09E+04
S SWA-L11-1315-T07-A 1 1.48E+04
S SWA-L11-1315-T08-A 1 4.56E+03
S SWA-L11-1315-T09-A 1 8.33E+03
S SWA-L11-1315-T01-B 1 1.09E+04
S SWA-L11-1315-T02-B 1 2.26E+04
S SWA-L11-1315-T03-B 1 1.02E+04
S SWA-L11-1315-T04-B 1 3.77E+04
S SWA-L11-1315-T05-B 1 2.52E+04
S SWA-L11-1315-T06-B 1 3.34E+04
S SWA-L11-1315-T07-B 1 1.66E+04
S SWA-L11-1315-T08-B 1 4.67E+03
S SWA-L11-1315-T09-B 1 1.04E+04
S SWA-L11-1315-T01-C 1 8.55E+03
S SWA-L11-1315-T02-C 1 3.16E+04
S SWA-L11-1315-T03-C 1 1.83E+04
S SWA-L11-1315-T04-C 1 5.17E+04
S SWA-L11-1315-T05-C 1 3.16E+04
S SWA-L11-1315-T06-C 1 3.74E+04
S SWA-L11-1315-T07-C 1 1.89E+04
S SWA-L11-1315-T08-C 1 5.58E+03
S SWA-L11-1315-T09-C 1 1.04E+04
S SWA-L11-1315-M01-A 1 3.40E+00 U1/2
S SWA-L11-1315-M02-A 1 3.40E+00 U1/2
S SWA-L11-1315-M03-A 1 3.40E+00 U1/2
S SWA-L11-1315-M04-A 1 3.40E+00 U1/2
S SWA-L11-1315-M05-A 1 3.40E+00 U1/2
S SWA-L11-1315-M06-A 1 3.40E+00 U1/2
S SWA-L11-1315-M07-A 1 3.40E+00 U1/2
S SWA-L11-1315-M08-A 1 3.40E+00 U1/2
S SWA-L11-1315-M09-A 1 4.12E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.55E+04 3.67 6.80 21.60
2.47E+04 1.96 6.80 21.60
1.22E+04 0.71 6.80 21.60 10000 1000
4.13E+04 2.05 6.80 21.60
2.50E+04 1.67 6.80 21.60
309E+04 1.44 6.80 21.60
1.48E+04 0.26 6.80 21.60
4.56E+03 1.83 6.80 21.60
8.33E+03 2.09 6.80 21.60
1.09E+04 1.07 6.80 21.60
2.26E+04 1.28 6.80 21.60
1.02E+04 1.71 6.80 21.60 10000 1000
3.77E+04 0.65 6.80 21.60
2.52E+04 0.71 6.80 21.60
3.34E+04 0.62 6.80 21.60
1.66E+04 1.58 6.80 21.60
4.67E+03 1.37 6.80 21.60
1.04E+04 1.08 6.80 21.60
8.55E+03 6.70 6.80 21.60
3.16E+04 1.37 6.80 21.60
1.83E+04 0.93 6.80 21.60 10000 1000
5.17E+04 2.01 6.80 21.60
3.16E+04 2.18 6.80 21.60
3.74E+04 1.29 6.80 21.60
1.89E+04 1.12 6.80 21.60
5.58E+03 2.34 6.80 21.60
1.04E+04 1.12 6.80 21.60
3.40E+00 52.74 6.80 21.60
3.40E+00 26.09 6.80 21.60
3.40E+00 13.53 6.80 21.60
3.40E+00 6.06 6.80 21.60
3.40E+00 11.95 6.80 21.60
3.40E+00 10.41 6.80 21.60
3.40E+00 15.82 6.80 21.60
3.40E+00 8.34 6.80 21.60
4.12E+01 3.23 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.31E+04 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 . 1 1 E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.92E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :36 AM EPA Interlab L1 1 1315SWA
6/7/11 11:38 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:40 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:41 AM EPA Interlab L11 1315 SWA
6/7/11 11:43 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:45 AM EPA Interlab L1 1 131 5 SWA
6/7/11 11:46 AM EPA Interlab L11 131 5 SWA
6/7/11 11:48 AM EPA Interlab L11 131 5 SWA
6/7/11 11:50 AM EPA Interlab L11 131 5 SWA
6/7/11 11:51 AM EPA Interlab L11 131 5 SWA
6/7/11 11:53 AM EPA Interlab L11 1315SWA
6/7/11 11:55 AM EPA Interlab L11 1315SWA
6/7/11 11:56 AM EPA Interlab L11 1315SWA
6/7/11 11:58 AM EPA Interlab L11 1315SWA
6/7/11 11:59 AM EPA Interlab L11 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-695
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Tl SWA-L11-1315-T01-A 1 2.30E+00 U1/2
Tl SWA-L11-1315-T02-A 1 2.30E+00 U1/2
Tl SWA-L11-1315-T03-A 1 2.30E+00 U1/2
Tl SWA-L11-1315-T04-A 1 2.30E+00 U1/2
Tl SWA-L11-1315-T05-A 1 2.30E+00 U1/2
Tl SWA-L11-1315-T06-A 1 2.30E+00 U1/2
Tl SWA-L11-1315-T07-A 1 2.30E+00 U1/2
Tl SWA-L11-1315-T08-A 1 2.30E+00 U1/2
Tl SWA-L11-1315-T09-A 1 2.30E+00 U1/2
Tl SWA-L11-1315-T01-B 1 2.30E+00 U1/2
Tl SWA-L11-1315-T02-B 1 2.30E+00 U1/2
Tl SWA-L11-1315-T03-B 1 2.30E+00 U1/2
Tl SWA-L11-1315-T04-B 1 2.30E+00 U1/2
Tl SWA-L11-1315-T05-B 1 2.30E+00 U1/2
Tl SWA-L11-1315-T06-B 1 2.30E+00 U1/2
Tl SWA-L11-1315-T07-B 1 2.30E+00 U1/2
Tl SWA-L11-1315-T08-B 1 2.30E+00 U1/2
Tl SWA-L11-1315-T09-B 1 2.30E+00 U1/2
Tl SWA-L11-1315-T01-C 1 2.30E+00 U1/2
Tl SWA-L11-1315-T02-C 1 2.30E+00 U1/2
Tl SWA-L11-1315-T03-C 1 2.30E+00 U1/2
Tl SWA-L11-1315-T04-C 1 2.30E+00 U1/2
Tl SWA-L11-1315-T05-C 1 2.30E+00 U1/2
Tl SWA-L11-1315-T06-C 1 2.30E+00 U1/2
Tl SWA-L11-1315-T07-C 1 2.30E+00 U1/2
Tl SWA-L11-1315-T08-C 1 2.30E+00 U1/2
Tl SWA-L11-1315-T09-C 1 2.30E+00 U1/2
Tl SWA-L11-1315-M01-A 1 2.30E+00 U1/2
Tl SWA-L11-1315-M02-A 1 2.30E+00 U1/2
Tl SWA-L11-1315-M03-A 1 2.30E+00 U1/2
Tl SWA-L11-1315-M04-A 1 2.30E+00 U1/2
Tl SWA-L11-1315-M05-A 1 2.30E+00 U1/2
Tl SWA-L11-1315-M06-A 1 2.30E+00 U1/2
Tl SWA-L11-1315-M07-A 1 2.30E+00 U1/2
Tl SWA-L11-1315-M08-A 1 2.30E+00 U1/2
Tl SWA-L11-1315-M09-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 75.65 4.60 14.60
2.30E+00 26.46 4.60 14.60
2.30E+00 20.70 4.60 14.60 10000 1000
2.30E+00 37.57 4.60 14.60
2.30E+00 16.55 4.60 14.60
2.30E+00 2.77 4.60 14.60
2.30E+00 30.65 4.60 14.60
2.30E+00 9.10 4.60 14.60
2.30E+00 25.96 4.60 14.60
2.30E+00 15.68 4.60 14.60
2.30E+00 38.98 4.60 14.60
2.30E+00 11.33 4.60 14.60 10000 1000
2.30E+00 36.66 4.60 14.60
2.30E+00 25.88 4.60 14.60
2.30E+00 40.94 4.60 14.60
2.30E+00 35.03 4.60 14.60
2.30E+00 10.34 4.60 14.60
2.30E+00 33.78 4.60 14.60
2.30E+00 58.37 4.60 14.60
2.30E+00 4.89 4.60 14.60
2.30E+00 34.48 4.60 14.60 10000 1000
2.30E+00 65.71 4.60 14.60
2.30E+00 19.87 4.60 14.60
2.30E+00 35.43 4.60 14.60
2.30E+00 11.26 4.60 14.60
2.30E+00 75.77 4.60 14.60
2.30E+00 12.00 4.60 14.60
2.30E+00 55.11 4.60 14.60
2.30E+00 57.03 4.60 14.60
2.30E+00 74.02 4.60 14.60
2.30E+00 28.39 4.60 14.60
2.30E+00 21.87 4.60 14.60
2.30E+00 38.91 4.60 14.60
2.30E+00 28.97 4.60 14.60
2.30E+00 42.63 4.60 14.60
2.30E+00 21.31 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.99E+02 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :36 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :38 AM EPA Interlab L1 1 1315SWA
6/7/11 11:40 AM EPA Interlab L11 1315SWA
6/7/11 11:41 AM EPA Interlab L11 1315 SWA
6/7/11 11:43 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:45 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:46 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:48 AM EPA Interlab L1 1 131 5 SWA
6/7/11 11:50 AM EPA Interlab L11 131 5 SWA
6/7/11 11:51 AM EPA Interlab L11 1315 SWA
6/7/11 11:53 AM EPA Interlab L11 131 5 SWA
6/7/11 11:55 AM EPA Interlab L11 131 5 SWA
6/7/11 11:56 AM EPA Interlab L11 131 5 SWA
6/7/11 11:58 AM EPA Interlab L11 1315SWA
6/7/11 11:59 AM EPA Interlab L11 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-696
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Ti SWA-L11-1315-T01-A 1 1.00E+00 U1/2
Ti SWA-L11-1315-T02-A 1 1.00E+00 U1/2
Ti SWA-L11-1315-T03-A 1 1.00E+00 U1/2
Ti SWA-L11-1315-T04-A 1 1.00E+00 U1/2
Ti SWA-L11-1315-T05-A 1 1.00E+00 U1/2
Ti SWA-L11-1315-T06-A 1 1.00E+00 U1/2
Ti SWA-L11-1315-T07-A 1 1.00E+00 U1/2
Ti SWA-L11-1315-T08-A 1 1.00E+00 U1/2
Ti SWA-L11-1315-T09-A 1 1.00E+00 U1/2
Ti SWA-L11-1315-T01-B 1 1.00E+00 U1/2
Ti SWA-L11-1315-T02-B 1 1.00E+00 U1/2
Ti SWA-L11-1315-T03-B 1 1.00E+00 U1/2
Ti SWA-L11-1315-T04-B 1 1.00E+00 U1/2
Ti SWA-L11-1315-T05-B 1 1.00E+00 U1/2
Ti SWA-L11-1315-T06-B 1 1.00E+00 U1/2
Ti SWA-L11-1315-T07-B 1 1.00E+00 U1/2
Ti SWA-L11-1315-T08-B 1 1.00E+00 U1/2
Ti SWA-L11-1315-T09-B 1 1.00E+00 U1/2
Ti SWA-L11-1315-T01-C 1 1.00E+00 U1/2
Ti SWA-L11-1315-T02-C 1 1.00E+00 U1/2
Ti SWA-L11-1315-T03-C 1 1.00E+00 U1/2
Ti SWA-L11-1315-T04-C 1 1.00E+00 U1/2
Ti SWA-L11-1315-T05-C 1 1.00E+00 U1/2
Ti SWA-L11-1315-T06-C 1 1.00E+00 U1/2
Ti SWA-L11-1315-T07-C 1 1.00E+00 U1/2
Ti SWA-L11-1315-T08-C 1 1.00E+00 U1/2
Ti SWA-L11-1315-T09-C 1 1.00E+00 U1/2
Ti SWA-L11-1315-M01-A 1 1.00E+00 U1/2
Ti SWA-L11-1315-M02-A 1 1.00E+00 U1/2
Ti SWA-L11-1315-M03-A 1 1.00E+00 U1/2
Ti SWA-L11-1315-M04-A 1 1.00E+00 U1/2
Ti SWA-L11-1315-M05-A 1 1.00E+00 U1/2
Ti SWA-L11-1315-M06-A 1 1.00E+00 U1/2
Ti SWA-L11-1315-M07-A 1 1.00E+00 U1/2
Ti SWA-L11-1315-M08-A 1 1.00E+00 U1/2
Ti SWA-L11-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 17.03 2.00 6.40
1.00E+00 42.38 2.00 6.40
1.00E+00 25.55 2.00 6.40 10000 1000
1.00E+00 12.97 2.00 6.40
1.00E+00 32.30 2.00 6.40
1.00E+00 27.00 2.00 6.40
1.00E+00 86.64 2.00 6.40
1.00E+00 22.55 2.00 6.40
1.00E+00 12.68 2.00 6.40
1.00E+00 44.12 2.00 6.40
1.00E+00 18.87 2.00 6.40
1.00E+00 15.22 2.00 6.40 10000 1000
1.00E+00 44.88 2.00 6.40
1.00E+00 17.28 2.00 6.40
1.00E+00 60.81 2.00 6.40
1.00E+00 41.65 2.00 6.40
1.00E+00 23.73 2.00 6.40
1.00E+00 93.51 2.00 6.40
1.00E+00 57.47 2.00 6.40
1.00E+00 60.65 2.00 6.40
1.00E+00 16.94 2.00 6.40 10000 1000
1.00E+00 83.76 2.00 6.40
1.00E+00 24.59 2.00 6.40
1.00E+00 17.55 2.00 6.40
1.00E+00 35.34 2.00 6.40
1.00E+00 11.15 2.00 6.40
1.00E+00 45.66 2.00 6.40
1.00E+00 91.45 2.00 6.40
1.00E+00 31.41 2.00 6.40
1.00E+00 25.07 2.00 6.40
1.00E+00 72.26 2.00 6.40
1.00E+00 12.17 2.00 6.40
1.00E+00 54.75 2.00 6.40
1.00E+00 71.55 2.00 6.40
1.00E+00 13.11 2.00 6.40
1.00E+00 22.12 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1:36 AM EPA Interlab L11 1315SWA
6/7/11 1 1 :38 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :40 AM EPA Interlab L1 1 1315SWA
6/7/11 11:41 AM EPA Interlab L11 1315SWA
6/7/11 1 1 :43 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :45 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :46 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :48 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :50 AM EPA Interlab L1 1 1315SWA
6/7/11 11:51 AM EPA Interlab L11 1315SWA
6/7/11 1 1 :53 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :55 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :56 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :58 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :59 AM EPA Interlab L1 1 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-697
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
V SWA-L11-1315-T01-A 1 2.03E+01
V SWA-L11-1315-T02-A 1 2.37E+01
V SWA-L11-1315-T03-A 1 1.08E+01
V SWA-L11-1315-T04-A 1 2.31E+01
V SWA-L11-1315-T05-A 1 1.86E+01
V SWA-L11-1315-T06-A 1 1.94E+01
V SWA-L11-1315-T07-A 1 1.60E+01
V SWA-L11-1315-T08-A 1 8.34E+00
V SWA-L11-1315-T09-A 1 1.23E+01
V SWA-L11-1315-T01-B 1 1.40E+01
V SWA-L11-1315-T02-B 1 2.13E+01
V SWA-L11-1315-T03-B 1 9.04E+00
V SWA-L11-1315-T04-B 1 2.16E+01
V SWA-L11-1315-T05-B 1 1.71E+01
V SWA-L11-1315-T06-B 1 1.91E+01
V SWA-L11-1315-T07-B 1 1.42E+01
V SWA-L11-1315-T08-B 1 7.57E+00
V SWA-L11-1315-T09-B 1 1.28E+01
V SWA-L11-1315-T01-C 1 9.74E+00
V SWA-L11-1315-T02-C 1 2.02E+01
V SWA-L11-1315-T03-C 1 1.22E+01
V SWA-L11-1315-T04-C 1 2.88E+01
V SWA-L11-1315-T05-C 1 1.91E+01
V SWA-L11-1315-T06-C 1 2.23E+01
V SWA-L11-1315-T07-C 1 1.72E+01
V SWA-L11-1315-T08-C 1 1.00E+01
V SWA-L11-1315-T09-C 1 1.27E+01
V SWA-L11-1315-M01-A 1 7.50E-01 U1/2
V SWA-L11-1315-M02-A 1 7.50E-01 U1/2
V SWA-L11-1315-M03-A 1 7.50E-01 U1/2
V SWA-L11-1315-M04-A 1 7.50E-01 U1/2
V SWA-L11-1315-M05-A 1 7.50E-01 U1/2
V SWA-L11-1315-M06-A 1 7.50E-01 U1/2
V SWA-L11-1315-M07-A 1 7.50E-01 U1/2
V SWA-L11-1315-M08-A 1 7.50E-01 U1/2
V SWA-L11-1315-M09-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.03E+01 4.66 1.50 4.77
2.37E+01 2.39 1.50 4.77
1.08E+01 3.71 1.50 4.77 10000 1000
2.31E+01 1.28 1.50 4.77
1.86E+01 2.39 1.50 4.77
1.94E+01 8.90 1.50 4.77
1.60E+01 1.41 1.50 4.77
8.34E+00 8.85 1.50 4.77
1.23E+01 8.78 1.50 4.77
1.40E+01 3.04 1.50 4.77
2.13E+01 2.83 1.50 4.77
9.04E+00 5.20 1.50 4.77 10000 1000
2.16E+01 0.48 1.50 4.77
1.71E+01 5.26 1.50 4.77
1.91E+01 7.35 1.50 4.77
1.42E+01 2.91 1.50 4.77
7.57E+00 7.72 1.50 4.77
1.28E+01 5.08 1.50 4.77
9.74E+00 3.61 1.50 4.77
2.02E+01 0.98 1.50 4.77
1.22E+01 4.20 1.50 4.77 10000 1000
2.88E+01 3.73 1.50 4.77
1.91E+01 0.70 1.50 4.77
2.23E+01 2.42 1.50 4.77
1.72E+01 1.54 1.50 4.77
1.00E+01 2.51 1.50 4.77
1.27E+01 1.74 1.50 4.77
7.50E-01 46.52 1.50 4.77
7.50E-01 34.00 1.50 4.77
7.50E-01 15.08 1.50 4.77
7.50E-01 38.60 1.50 4.77
7.50E-01 40.53 1.50 4.77
7.50E-01 36.25 1.50 4.77
7.50E-01 40.12 1.50 4.77
7.50E-01 38.13 1.50 4.77
7.50E-01 46.15 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.05E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :36 AM EPA Interlab L1 1 1315SWA
6/7/11 11:38 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:40 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:41 AM EPA Interlab L11 1315 SWA
6/7/11 11:43 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:45 AM EPA Interlab L1 1 131 5 SWA
6/7/11 11:46 AM EPA Interlab L11 131 5 SWA
6/7/11 11:48 AM EPA Interlab L11 131 5 SWA
6/7/11 11:50 AM EPA Interlab L11 131 5 SWA
6/7/11 11:51 AM EPA Interlab L11 131 5 SWA
6/7/11 11:53 AM EPA Interlab L11 1315SWA
6/7/11 11:55 AM EPA Interlab L11 1315SWA
6/7/11 11:56 AM EPA Interlab L11 1315SWA
6/7/11 11:58 AM EPA Interlab L11 1315SWA
6/7/11 11:59 AM EPA Interlab L11 1315SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-698
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Zn SWA-L11-1315-T01-A 1 5.00E-01 U1/2
Zn SWA-L11-1315-T02-A 1 5.00E-01 U1/2
Zn SWA-L11-1315-T03-A 1 5.00E-01 U1/2
Zn SWA-L11-1315-T04-A 1 2.05E+00 E
Zn SWA-L11-1315-T05-A 1 5.00E-01 U1/2
Zn SWA-L11-1315-T06-A 1 5.00E-01 U1/2
Zn SWA-L11-1315-T07-A 1 5.00E-01 U1/2
Zn SWA-L11-1315-T08-A 1 5.00E-01 U1/2
Zn SWA-L11-1315-T09-A 1 1.73E+00 E
Zn SWA-L11-1315-T01-B 1 5.00E-01 U1/2
Zn SWA-L11-1315-T02-B 1 5.00E-01 U1/2
Zn SWA-L11-1315-T03-B 1 5.00E-01 U1/2
Zn SWA-L11-1315-T04-B 1 5.00E-01 U1/2
Zn SWA-L11-1315-T05-B 1 5.00E-01 U1/2
Zn SWA-L11-1315-T06-B 1 5.00E-01 U1/2
Zn SWA-L11-1315-T07-B 1 5.00E-01 U1/2
Zn SWA-L11-1315-T08-B 1 5.00E-01 U1/2
Zn SWA-L11-1315-T09-B 1 5.00E-01 U1/2
Zn SWA-L11-1315-T01-C 1 5.00E-01 U1/2
Zn SWA-L11-1315-T02-C 1 5.00E-01 U1/2
Zn SWA-L11-1315-T03-C 1 5.00E-01 U1/2
Zn SWA-L11-1315-T04-C 1 5.00E-01 U1/2
Zn SWA-L11-1315-T05-C 1 5.00E-01 U1/2
Zn SWA-L11-1315-T06-C 1 5.00E-01 U1/2
Zn SWA-L11-1315-T07-C 1 5.00E-01 U1/2
Zn SWA-L11-1315-T08-C 1 5.00E-01 U1/2
Zn SWA-L11-1315-T09-C 1 5.00E-01 U1/2
Zn SWA-L11-1315-M01-A 1 5.00E-01 U1/2
Zn SWA-L11-1315-M02-A 1 5.00E-01 U1/2
Zn SWA-L11-1315-M03-A 1 5.00E-01 U1/2
Zn SWA-L11-1315-M04-A 1 5.00E-01 U1/2
Zn SWA-L11-1315-M05-A 1 5.00E-01 U1/2
Zn SWA-L11-1315-M06-A 1 5.00E-01 U1/2
Zn SWA-L11-1315-M07-A 1 5.00E-01 U1/2
Zn SWA-L11-1315-M08-A 1 5.00E-01 U1/2
Zn SWA-L11-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.00E-01 9.11 1.00 3.18
5.00E-01 28.66 1.00 3.18
5.00E-01 10.82 1.00 3.18 10000 1000
2.05E+00 14.03 1.00 3.18
5.00E-01 51.63 1.00 3.18
5.00E-01 17.01 1.00 3.18
5.00E-01 49.95 1.00 3.18
5.00E-01 44.14 1.00 3.18
1.73E+00 21.67 1.00 3.18
5.00E-01 31.45 1.00 3.18
5.00E-01 26.17 1.00 3.18
5.00E-01 40.66 1.00 3.18 10000 1000
5.00E-01 42.35 1.00 3.18
5.00E-01 38.11 1.00 3.18
5.00E-01 17.55 1.00 3.18
5.00E-01 56.63 1.00 3.18
5.00E-01 59.91 1.00 3.18
5.00E-01 38.87 1.00 3.18
5.00E-01 10.39 1.00 3.18
5.00E-01 74.57 1.00 3.18
5.00E-01 67.17 1.00 3.18 10000 1000
5.00E-01 46.99 1.00 3.18
5.00E-01 78.29 1.00 3.18
5.00E-01 10.25 1.00 3.18
5.00E-01 11.21 1.00 3.18
5.00E-01 21.86 1.00 3.18
5.00E-01 32.95 1.00 3.18
5.00E-01 41.35 1.00 3.18
5.00E-01 49.29 1.00 3.18
5.00E-01 51.83 1.00 3.18
5.00E-01 11.37 1.00 3.18
5.00E-01 26.87 1.00 3.18
5.00E-01 37.50 1.00 3.18
5.00E-01 59.63 1.00 3.18
5.00E-01 8.46 1.00 3.18
5.00E-01 8.86 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.07E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/7/11 1 1 :33 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :35 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1:36 AM EPA Interlab L11 1315SWA
6/7/11 1 1 :38 AM EPA Interlab L1 1 1315SWA
6/7/11 1 1 :40 AM EPA Interlab L1 1 1315SWA
6/7/11 11:41 AM EPA Interlab L11 1315SWA
6/7/11 1 1:43 AM EPA Interlab L11 1315SWA
6/7/11 11:45 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:46 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:48 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:50 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:51 AM EPA Interlab L11 1315 SWA
6/7/11 11:53 AM EPA Interlab L1 1 1315 SWA
6/7/11 11:55 AM EPA Interlab L1 1 131 5 SWA
6/7/11 11:56 AM EPA Interlab L11 131 5 SWA
6/7/11 11:58 AM EPA Interlab L11 131 5 SWA
6/7/11 11:59 AM EPA Interlab L11 131 5 SWA
6/7/11 12:01 PM EPA Interlab L11 1315SWA
6/7/11 12:08 PM EPA Interlab L11 1315SWA
6/7/11 12:09 PM EPA Interlab L11 1315SWA
6/7/11 12:11 PM EPA Interlab L11 1315SWA
6/7/11 12:13 PM EPA Interlab L11 1315SWA
6/7/11 12:14 PM EPA Interlab L11 1315SWA
6/7/11 12:16 PM EPA Interlab L11 1315SWA
6/7/11 12:18 PM EPA Interlab L11 1315SWA
6/7/11 12:19 PM EPA Interlab L11 1315SWA
6/7/11 12:21 PM EPA Interlab L11 1315SWA
6/7/11 12:22 PM EPA Interlab L11 1315SWA
6/7/11 12:24 PM EPA Interlab L11 1315SWA
6/7/11 12:26 PM EPA Interlab L11 1315SWA
6/7/11 12:27 PM EPA Interlab L11 1315SWA
6/7/11 12:29 PM EPA Interlab L11 1315SWA
6/7/11 12:31 PM EPA Interlab L11 1315SWA
6/7/11 12:32 PM EPA Interlab L11 1315SWA
6/7/11 12:34 PM EPA Interlab L11 1315SWA
6/7/11 12:36 PM EPA Interlab L11 1315SWA
1-699
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1315:
Element Sample ID
Al SWA-LRef-1315-T01-A
Al SWA-LRef-1315-T02-A
Al SWA-LRef-1315-T03-A
Al SWA-LRef-1315-T04-A
Al SWA-LRef-1315-T05-A
Al SWA-LRef-1315-T06-A
Al SWA-LRef-1315-T07-A
Al SWA-LRef-1315-T08-A
Al SWA-LRef-1315-T09-A
Al SWA-LRef-1315-T01-B
Al SWA-LRef-1315-T02-B
Al SWA-LRef-1315-T03-B
Al SWA-LRef-1315-T04-B
Al SWA-LRef-1315-T05-B
Al SWA-LRef-1315-T06-B
Al SWA-LRef-1315-T07-B
Al SWA-LRef-1315-T08-B
Al SWA-LRef-1315-T09-B
Al SWA-LRef-1315-T01-C
Al SWA-LRef-1315-T02-C
Al SWA-LRef-1315-T03-C
Al SWA-LRef-1315-T04-C
Al SWA-LRef-1315-T05-C
Al SWA-LRef-1315-T06-C
Al SWA-LRef-1315-T07-C
Al SWA-LRef-1315-T08-C
Al SWA-LRef-1315-T09-C
Al SWA-LRef-1315-M01-A
Al SWA-LRef-1315-M02-A
Al SWA-LRef-1315-M03-A
Al SWA-LRef-1315-M04-A
Al SWA-LRef-1315-M05-A
Al SWA-LRef-1315-M06-A
Al SWA-LRef-1315-M07-A
Al SWA-LRef-1315-M08-A
Al SWA-LRef-1315-M09-A
Dilution Sample
Factor Cone. Qualifier
I ug/L I
1 1.08E+03
1 3.84E+03
1 2.60E+03
1 4.96E+03
1 4.53E+03
1 4.19E+03
1 3.72E+03
1 2.36E+03
1 2.50E+03
1 1.34E+03
1 3.87E+03
1 2.80E+03
1 4.91 E+03
1 4.29E+03
1 4.24E+03
1 3.58E+03
1 2.25E+03
1 2.92E+03
1 6.68E+02
1 3.80E+03
1 2.98E+03
1 5.12E+03
1 4.59E+03
1 4.30E+03
1 3.63E+03
1 2.25E+03
1 2. 91 E+03
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.08E+03 0.38 1.00 3.18
3.84E+03 1.07 1.00 3.18
2.60E+03 1.16 1.00 3.18 10000 1000
4.96E+03 0.32 1.00 3.18
4.53E+03 1.00 1.00 3.18
4.19E+03 0.32 1.00 3.18
3.72E+03 0.33 1.00 3.18
2.36E+03 0.24 1.00 3.18
2.50E+03 0.36 1.00 3.18
1.34E+03 0.41 1.00 3.18
3.87E+03 0.91 1.00 3.18
2.80E+03 0.70 1.00 3.18 10000 1000
4.91E+03 0.22 1.00 3.18
4.29E+03 0.45 1.00 3.18
4.24E+03 0.57 1.00 3.18
3.58E+03 0.59 1.00 3.18
2.25E+03 0.83 1.00 3.18
2.92E+03 0.26 1.00 3.18
6.68E+02 0.70 1.00 3.18
3.80E+03 0.54 1.00 3.18
2.98E+03 0.73 1.00 3.18 10000 1000
5.12E+03 0.30 1.00 3.18
4.59E+03 0.71 1.00 3.18
4.30E+03 0.81 1.00 3.18
3.63E+03 0.49 1.00 3.18
2.25E+03 0.50 1.00 3.18
2.91E+03 0.23 1.00 3.18
5.00E-01 46.33 1.00 3.18
5.00E-01 11.21 1.00 3.18
5.00E-01 29.33 1.00 3.18
5.00E-01 14.85 1.00 3.18
5.00E-01 0.58 1.00 3.18
5.00E-01 0.32 1.00 3.18
5.00E-01 14.41 1.00 3.18
5.00E-01 24.93 1.00 3.18
5.00E-01 26.78 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.60E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.80E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.92E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/14/11 4:17 PM EPA Interlab LRef 1315 SWA
3/14/11 4:19 PM EPA Interlab LRef 1315 SWA
3/14/11 4:20 PM EPA Interlab LRef 1315 SWA
3/14/11 4:22 PM EPA Interlab LRef 1315 SWA
3/14/11 4:24 PM EPA Interlab LRef 1315 SWA
3/14/11 4:25 PM EPA Interlab LRef 1315 SWA
3/14/11 4:27 PM EPA Interlab LRef 1315 SWA
3/14/11 4:28 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:30 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:32 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:33 PM EPA Interlab LRef 1315 SWA
3/14/11 4:35 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:37 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:38 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:40 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:42 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:43 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:45 PM EPA Interlab LRef 1315 SWA
3/15/11 10:28 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:30 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:32 AM EPA Interlab LRef 1315 SWA
3/15/11 10:33 AM EPA Interlab LRef 1315 SWA
3/15/11 10:35 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:37 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:38 AM EPA Interlab LRef 1315 SWA
3/15/11 10:40 AM EPA Interlab LRef 1315 SWA
3/15/11 10:41 AM EPA Interlab LRef 1315 SWA
3/14/11 2:57 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:30 PM EPA Interlab LRef 1315 SWA
3/14/11 2:58 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:00 PM EPA Interlab LRef 1315 SWA
3/14/11 3:01 PM EPA Interlab LRef 1315 SWA
3/14/11 3:24 PM EPA Interlab LRef 1315 SWA
3/14/11 3:25 PM EPA Interlab LRef 1315 SWA
3/14/11 3:27 PM EPA Interlab LRef 1315 SWA
3/14/11 3:29 PM EPA Interlab LRef 1315 SWA
1-700
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Sb SWA-LRef-1315-T01-A 1 1.07E+02
Sb SWA-LRef-1315-T02-A 1 4.62E+02
Sb SWA-LRef-1315-T03-A 1 2.80E+02
Sb SWA-LRef-1315-T04-A 1 4.45E+02
Sb SWA-LRef-1315-T05-A 1 4.14E+02
Sb SWA-LRef-1315-T06-A 1 4.86E+02
Sb SWA-LRef-1315-T07-A 1 2.80E+02
Sb SWA-LRef-1315-T08-A 1 2.60E+02
Sb SWA-LRef-1315-T09-A 1 2.59E+02
Sb SWA-LRef-1315-T01-B 1 1.16E+02
Sb SWA-LRef-1315-T02-B 1 4.64E+02
Sb SWA-LRef-1315-T03-B 1 2.96E+02
Sb SWA-LRef-1315-T04-B 1 4.59E+02
Sb SWA-LRef-1315-T05-B 1 4.79E+02
Sb SWA-LRef-1315-T06-B 1 5.03E+02
Sb SWA-LRef-1315-T07-B 1 3.73E+02
Sb SWA-LRef-1315-T08-B 1 2.75E+02
Sb SWA-LRef-1315-T09-B 1 2.24E+02
Sb SWA-LRef-1315-T01-C 1 6.34E+01
Sb SWA-LRef-1315-T02-C 1 4.63E+02
Sb SWA-LRef-1315-T03-C 1 2.96E+02
Sb SWA-LRef-1315-T04-C 1 4.52E+02
Sb SWA-LRef-1315-T05-C 1 4.42E+02
Sb SWA-LRef-1315-T06-C 1 5.06E+02
Sb SWA-LRef-1315-T07-C 1 3.53E+02
Sb SWA-LRef-1315-T08-C 1 2.82E+02
Sb SWA-LRef-1315-T09-C 1 2.31E+02
Sb SWA-LRef-1315-M01-A 1 3.75E+00 U1/2
Sb SWA-LRef-1315-M02-A 1 3.75E+00 U1/2
Sb SWA-LRef-1315-M03-A 1 3.75E+00 U1/2
Sb SWA-LRef-1315-M04-A 1 3.75E+00 U1/2
Sb SWA-LRef-1315-M05-A 1 3.75E+00 U1/2
Sb SWA-LRef-1315-M06-A 1 3.75E+00 U1/2
Sb SWA-LRef-1315-M07-A 1 3.75E+00 U1/2
Sb SWA-LRef-1315-M08-A 1 3.75E+00 U1/2
Sb SWA-LRef-1315-M09-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.07E+02 4.26 7.50 23.90
4.62E+02 5.49 7.50 23.90
2.80E+02 1.22 7.50 23.90 10000 1000
4.45E+02 2.34 7.50 23.90
4.14E+02 2.07 7.50 23.90
4.86E+02 2.08 7.50 23.90
2.80E+02 2.31 7.50 23.90
2.60E+02 5.14 7.50 23.90
2.59E+02 1.68 7.50 23.90
1.16E+02 2.15 7.50 23.90
4.64E+02 1.96 7.50 23.90
2.96E+02 1.75 7.50 23.90 10000 1000
4.59E+02 1.99 7.50 23.90
4.79E+02 2.60 7.50 23.90
5.03E+02 1.91 7.50 23.90
3.73E+02 2.48 7.50 23.90
2.75E+02 4.69 7.50 23.90
2.24E+02 2.08 7.50 23.90
6.34E+01 11.13 7.50 23.90
4.63E+02 2.01 7.50 23.90
2.96E+02 4.13 7.50 23.90 10000 1000
4.52E+02 3.87 7.50 23.90
4.42E+02 2.30 7.50 23.90
5.06E+02 1.90 7.50 23.90
3.53E+02 0.37 7.50 23.90
2.82E+02 3.07 7.50 23.90
2.31E+02 2.98 7.50 23.90
3.75E+00 27.07 7.50 23.90
3.75E+00 33.94 7.50 23.90
3.75E+00 20.85 7.50 23.90
3.75E+00 30.73 7.50 23.90
3.75E+00 28.22 7.50 23.90
3.75E+00 1.83 7.50 23.90
3.75E+00 41.09 7.50 23.90
3.75E+00 39.27 7.50 23.90
3.75E+00 38.16 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.27E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.26E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.21E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/3/11 1:12 PM EPA Interlab LRef 1315 SWA
11/3/11 1:14 PM EPA Interlab LRef 1315 SWA
11/3/11 1:15 PM EPA Interlab LRef 131 5 SWA
11/3/11 1:17 PM EPA Interlab LRef 131 5 SWA
11/3/11 1:19PM EPA Interlab LRef 131 5 SWA
11/3/11 1:20 PM EPA Interlab LRef 131 5 SWA
11/3/11 1:22 PM EPA Interlab LRef 1315 SWA
11/3/11 1:24PM EPA Interlab LRef 1315 SWA
11/3/11 1:25 PM EPA Interlab LRef 1315 SWA
11/3/11 1:27 PM EPA Interlab LRef 1315 SWA
11/3/11 1:29 PM EPA Interlab LRef 1315 SWA
11/3/11 1:30 PM EPA Interlab LRef 1315 SWA
11/3/11 1:32 PM EPA Interlab LRef 1315 SWA
11/3/11 1:34 PM EPA Interlab LRef 1315 SWA
11/3/11 1:35 PM EPA Interlab LRef 1315 SWA
11/3/11 1:37 PM EPA Interlab LRef 1315 SWA
11/3/11 1:39 PM EPA Interlab LRef 1315 SWA
11/3/11 1:40 PM EPA Interlab LRef 1315 SWA
11/3/11 1:46 PM EPA Interlab LRef 1315 SWA
11/3/11 1:48 PM EPA Interlab LRef 1315 SWA
11/3/11 1:49 PM EPA Interlab LRef 1315 SWA
11/3/11 1:51 PM EPA Interlab LRef 1315 SWA
11/3/11 1:53 PM EPA Interlab LRef 1315 SWA
11/3/11 1:54 PM EPA Interlab LRef 1315 SWA
11/3/11 1:56 PM EPA Interlab LRef 1315 SWA
11/3/11 1:58 PM EPA Interlab LRef 1315 SWA
11/3/11 1:59 PM EPA Interlab LRef 1315 SWA
11/3/11 12:57 PM EPA Interlab LRef 1315 SWA
11/3/11 12:59 PM EPA Interlab LRef 1315 SWA
11/3/11 1:00 PM EPA Interlab LRef 1315 SWA
11/3/11 1:02 PM EPA Interlab LRef 1315 SWA
11/3/11 1:04 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :05 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :07 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :09 PM EPA Interlab LRef 1315 SWA
11/3/11 1:10 PM EPA Interlab LRef 1315 SWA
1-701
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
As SWA-LRef-1315-T01-A 1 8.46E+01
As SWA-LRef-1315-T02-A 1 1.10E+02
As SWA-LRef-1315-T03-A 1 8.35E+01
As SWA-LRef-1315-T04-A 1 1.60E+02
As SWA-LRef-1315-T05-A 1 1.34E+02
As SWA-LRef-1315-T06-A 1 1.38E+02
As SWA-LRef-1315-T07-A 1 1.13E+02
As SWA-LRef-1315-T08-A 1 6.79E+01
As SWA-LRef-1315-T09-A 1 1.24E+02
As SWA-LRef-1315-T01-B 1 1.17E+02
As SWA-LRef-1315-T02-B 1 1.64E+02
As SWA-LRef-1315-T03-B 1 1.44E+02
As SWA-LRef-1315-T04-B 1 2.41E+02
As SWA-LRef-1315-T05-B 1 1.56E+02
As SWA-LRef-1315-T06-B 1 1.71E+02
As SWA-LRef-1315-T07-B 1 1.34E+02
As SWA-LRef-1315-T08-B 1 8.31E+01
As SWA-LRef-1315-T09-B 1 1.13E+02
As SWA-LRef-1315-T01-C 1 7.57E+01
As SWA-LRef-1315-T02-C 1 1.74E+02
As SWA-LRef-1315-T03-C 1 1.34E+02
As SWA-LRef-1315-T04-C 1 2.08E+02
As SWA-LRef-1315-T05-C 1 1.63E+02
As SWA-LRef-1315-T06-C 1 1.71E+02
As SWA-LRef-1315-T07-C 1 1.18E+02
As SWA-LRef-1315-T08-C 1 8.62E+01
As SWA-LRef-1315-T09-C 1 1.12E+02
As SWA-LRef-1315-M01-A 1 5.50E+00 U1/2
As SWA-LRef-1315-M02-A 1 5.50E+00 U1/2
As SWA-LRef-1315-M03-A 1 5.50E+00 U1/2
As SWA-LRef-1315-M04-A 1 5.50E+00 U1/2
As SWA-LRef-1315-M05-A 1 5.50E+00 U1/2
As SWA-LRef-1315-M06-A 1 5.50E+00 U1/2
As SWA-LRef-1315-M07-A 1 5.50E+00 U1/2
As SWA-LRef-1315-M08-A 1 5.50E+00 U1/2
As SWA-LRef-1315-M09-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.46E+01 2.49 11.00 35.00
1.10E+02 3.64 11.00 35.00
8.35E+01 3.18 11.00 35.00 10000 1000
1.60E+02 1.40 11.00 35.00
1.34E+02 3.88 11.00 35.00
1.38E+02 1.90 11.00 35.00
1.13E+02 3.59 11.00 35.00
6.79E+01 1.94 11.00 35.00
1.24E+02 5.20 11.00 35.00
1.17E+02 7.26 11.00 35.00
1.64E+02 3.48 11.00 35.00
1.44E+02 1.57 11.00 35.00 10000 1000
2.41E+02 0.94 11.00 35.00
1.56E+02 3.09 11.00 35.00
1.71E+02 4.26 11.00 35.00
1.34E+02 2.04 11.00 35.00
8.31E+01 7.65 11.00 35.00
1.13E+02 7.16 11.00 35.00
7.57E+01 8.48 11.00 35.00
1.74E+02 4.06 11.00 35.00
1.34E+02 1.00 11.00 35.00 10000 1000
2.08E+02 2.53 11.00 35.00
1.63E+02 1.84 11.00 35.00
1.71E+02 1.46 11.00 35.00
1.18E+02 0.89 11.00 35.00
8.62E+01 7.07 11.00 35.00
1.12E+02 7.47 11.00 35.00
5.50E+00 24.99 11.00 35.00
5.50E+00 33.87 11.00 35.00
5.50E+00 24.08 11.00 35.00
5.50E+00 46.30 11.00 35.00
5.50E+00 59.48 11.00 35.00
5.50E+00 4.13 11.00 35.00
5.50E+00 45.02 11.00 35.00
5.50E+00 33.92 11.00 35.00
5.50E+00 16.32 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.09E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 . 1 1 E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/14/11 4:17 PM EPA Interlab LRef 1315 SWA
3/14/11 4:19 PM EPA Interlab LRef 1315 SWA
3/14/11 4:20 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:22 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:24 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:25 PM EPA Interlab LRef 1315 SWA
3/14/11 4:27 PM EPA Interlab LRef 1315 SWA
3/14/11 4:28 PM EPA Interlab LRef 1315 SWA
3/14/11 4:30 PM EPA Interlab LRef 1315 SWA
3/14/11 4:32 PM EPA Interlab LRef 1315 SWA
3/14/11 4:33 PM EPA Interlab LRef 1315 SWA
3/14/11 4:35 PM EPA Interlab LRef 1315 SWA
3/14/11 4:37 PM EPA Interlab LRef 1315 SWA
3/14/11 4:38 PM EPA Interlab LRef 1315 SWA
3/14/11 4:40 PM EPA Interlab LRef 1315 SWA
3/14/11 4:42 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:43 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:45 PM EPA Interlab LRef 1315 SWA
3/15/11 10:28 AM EPA Interlab LRef 1315 SWA
3/15/11 10:30 AM EPA Interlab LRef 1315 SWA
3/15/11 10:32 AM EPA Interlab LRef 1315 SWA
3/15/11 10:33 AM EPA Interlab LRef 1315 SWA
3/15/11 10:35 AM EPA Interlab LRef 1315 SWA
3/15/11 10:37 AM EPA Interlab LRef 1315 SWA
3/15/11 10:38 AM EPA Interlab LRef 1315 SWA
3/15/11 10:40 AM EPA Interlab LRef 1315 SWA
3/15/11 10:41 AM EPA Interlab LRef 1315 SWA
3/14/11 2:57 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:30 PM EPA Interlab LRef 1315 SWA
3/14/11 2:58 PM EPA Interlab LRef 1315 SWA
3/14/11 3:00 PM EPA Interlab LRef 1315 SWA
3/14/11 3:01 PM EPA Interlab LRef 1315 SWA
3/14/11 3:24 PM EPA Interlab LRef 1315 SWA
3/14/11 3:25 PM EPA Interlab LRef 1315 SWA
3/14/11 3:27 PM EPA Interlab LRef 1315 SWA
3/14/11 3:29 PM EPA Interlab LRef 1315 SWA
1-702
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
B SWA-LRef-1315-T01-A 1 5.38E+01
B SWA-LRef-1315-T02-A 1 8.12E+01
B SWA-LRef-1315-T03-A 1 6.08E+01
B SWA-LRef-1315-T04-A 1 8.32E+01
B SWA-LRef-1315-T05-A 1 6.92E+01
B SWA-LRef-1315-T06-A 1 8.05E+01
B SWA-LRef-1315-T07-A 1 7.46E+01
B SWA-LRef-1315-T08-A 1 8.59E+01
B SWA-LRef-1315-T09-A 1 6.59E+01
B SWA-LRef-1315-T01-B 1 3.96E+01
B SWA-LRef-1315-T02-B 1 8.63E+01
B SWA-LRef-1315-T03-B 1 4.83E+01
B SWA-LRef-1315-T04-B 1 7.49E+01
B SWA-LRef-1315-T05-B 1 5.96E+01
B SWA-LRef-1315-T06-B 1 7.57E+01
B SWA-LRef-1315-T07-B 1 7.02E+01
B SWA-LRef-1315-T08-B 1 7.10E+01
B SWA-LRef-1315-T09-B 1 5.45E+01
B SWA-LRef-1315-T01-C 1 3.80E+01
B SWA-LRef-1315-T02-C 1 8.14E+01
B SWA-LRef-1315-T03-C 1 4.48E+01
B SWA-LRef-1315-T04-C 1 7.01E+01
B SWA-LRef-1315-T05-C 1 5.62E+01
B SWA-LRef-1315-T06-C 1 8.21E+01
B SWA-LRef-1315-T07-C 1 7.64E+01
B SWA-LRef-1315-T08-C 1 7.56E+01
B SWA-LRef-1315-T09-C 1 4.83E+01
B SWA-LRef-1315-M01-A 1 5.00E-01 U1/2
B SWA-LRef-1315-M02-A 1 5.00E-01 U1/2
B SWA-LRef-1315-M03-A 1 5.00E-01 U1/2
B SWA-LRef-1315-M04-A 1 5.00E-01 U1/2
B SWA-LRef-1315-M05-A 1 5.00E-01 U1/2
B SWA-LRef-1315-M06-A 1 5.00E-01 U1/2
B SWA-LRef-1315-M07-A 1 5.00E-01 U1/2
B SWA-LRef-1315-M08-A 1 5.00E-01 U1/2
B SWA-LRef-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.38E+01 0.53 1.00 3.18
8.12E+01 2.84 1.00 3.18
6.08E+01 1.37 1.00 3.18 10000 1000
8.32E+01 2.17 1.00 3.18
6.92E+01 2.73 1.00 3.18
8.05E+01 3.78 1.00 3.18
7.46E+01 1.15 1.00 3.18
8.59E+01 4.07 1.00 3.18
6.59E+01 1.64 1.00 3.18
3.96E+01 8.56 1.00 3.18
8.63E+01 2.47 1.00 3.18
4.83E+01 2.19 1.00 3.18 10000 1000
7.49E+01 2.68 1.00 3.18
5.96E+01 0.42 1.00 3.18
7.57E+01 3.31 1.00 3.18
7.02E+01 0.92 1.00 3.18
7.10E+01 3.72 1.00 3.18
5.45E+01 4.60 1.00 3.18
3.80E+01 9.62 1.00 3.18
8.14E+01 1.32 1.00 3.18
4.48E+01 2.98 1.00 3.18 10000 1000
7.01E+01 1.56 1.00 3.18
5.62E+01 4.23 1.00 3.18
8.21 E+01 0.65 1.00 3.18
7.64E+01 4.33 1.00 3.18
7.56E+01 3.13 1.00 3.18
4.83E+01 2.60 1.00 3.18
5.00E-01 1.07 1.00 3.18
5.00E-01 1.24 1.00 3.18
5.00E-01 1.81 1.00 3.18
5.00E-01 1.74 1.00 3.18
5.00E-01 1.37 1.00 3.18
5.00E-01 1.44 1.00 3.18
5.00E-01 1.41 1.00 3.18
5.00E-01 1.09 1.00 3.18
5.00E-01 0.65 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.73E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/3/11 1:12 PM EPA Interlab LRef 1315 SWA
11/3/11 1:14 PM EPA Interlab LRef 1315 SWA
11/3/11 1:15 PM EPA Interlab LRef 131 5 SWA
11/3/11 1:17 PM EPA Interlab LRef 131 5 SWA
11/3/11 1:19PM EPA Interlab LRef 131 5 SWA
11/3/11 1:20 PM EPA Interlab LRef 131 5 SWA
11/3/11 1:22 PM EPA Interlab LRef 1315 SWA
11/3/11 1:24PM EPA Interlab LRef 1315 SWA
11/3/11 1:25 PM EPA Interlab LRef 1315 SWA
11/3/11 1:27 PM EPA Interlab LRef 1315 SWA
11/3/11 1:29 PM EPA Interlab LRef 1315 SWA
11/3/11 1:30 PM EPA Interlab LRef 1315 SWA
11/3/11 1:32 PM EPA Interlab LRef 1315 SWA
11/3/11 1:34 PM EPA Interlab LRef 1315 SWA
11/3/11 1:35 PM EPA Interlab LRef 1315 SWA
11/3/11 1:37 PM EPA Interlab LRef 1315 SWA
11/3/11 1:39 PM EPA Interlab LRef 1315 SWA
11/3/11 1:40 PM EPA Interlab LRef 1315 SWA
11/3/11 1:46 PM EPA Interlab LRef 1315 SWA
11/3/11 1:48 PM EPA Interlab LRef 1315 SWA
11/3/11 1:49 PM EPA Interlab LRef 1315 SWA
11/3/11 1:51 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :53 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :54 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :56 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :58 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :59 PM EPA Interlab LRef 1315 SWA
11/3/11 12:57 PM EPA Interlab LRef 1315 SWA
11/3/11 12:59 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :00 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :02 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :04 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :05 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :07 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :09 PM EPA Interlab LRef 1315 SWA
11/3/11 1:10 PM EPA Interlab LRef 1315 SWA
1-703
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
Ba SWA-LRef-1315-T01-A 1 2.04E+01
Ba SWA-LRef-1315-T02-A 1 2.38E+02
Ba SWA-LRef-1315-T03-A 1 1.99E+02
Ba SWA-LRef-1315-T04-A 1 3.17E+02
Ba SWA-LRef-1315-T05-A 1 3.81E+02
Ba SWA-LRef-1315-T06-A 1 4.78E+02
Ba SWA-LRef-1315-T07-A 1 4.96E+02
Ba SWA-LRef-1315-T08-A 1 4.44E+02
Ba SWA-LRef-1315-T09-A 1 4.10E+02
Ba SWA-LRef-1315-T01-B 1 2.04E+01
Ba SWA-LRef-1315-T02-B 1 3.92E+02
Ba SWA-LRef-1315-T03-B 1 2.36E+02
Ba SWA-LRef-1315-T04-B 1 3.52E+02
Ba SWA-LRef-1315-T05-B 1 3.75E+02
Ba SWA-LRef-1315-T06-B 1 4.95E+02
Ba SWA-LRef-1315-T07-B 1 4.70E+02
Ba SWA-LRef-1315-T08-B 1 4.62E+02
Ba SWA-LRef-1315-T09-B 1 4.34E+02
Ba SWA-LRef-1315-T01-C 1 1.26E+01
Ba SWA-LRef-1315-T02-C 1 1.87E+02
Ba SWA-LRef-1315-T03-C 1 1.86E+02
Ba SWA-LRef-1315-T04-C 1 2.91E+02
Ba SWA-LRef-1315-T05-C 1 3.57E+02
Ba SWA-LRef-1315-T06-C 1 4.48E+02
Ba SWA-LRef-1315-T07-C 1 4.66E+02
Ba SWA-LRef-1315-T08-C 1 4.03E+02
Ba SWA-LRef-1315-T09-C 1 3.87E+02
Ba SWA-LRef-1315-M01-A 1 5.00E-01 U1/2
Ba SWA-LRef-1315-M02-A 1 5.00E-01 U1/2
Ba SWA-LRef-1315-M03-A 1 5.00E-01 U1/2
Ba SWA-LRef-1315-M04-A 1 5.00E-01 U1/2
Ba SWA-LRef-1315-M05-A 1 5.00E-01 U1/2
Ba SWA-LRef-1315-M06-A 1 5.00E-01 U1/2
Ba SWA-LRef-1315-M07-A 1 5.00E-01 U1/2
Ba SWA-LRef-1315-M08-A 1 5.00E-01 U1/2
Ba SWA-LRef-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.04E+01 1.00 1.00 3.18
2.38E+02 0.65 1.00 3.18
1.99E+02 0.75 1.00 3.18 10000 1000
3.17E+02 0.50 1.00 3.18
3.81E+02 2.29 1.00 3.18
4.78E+02 1.60 1.00 3.18
4.96E+02 0.77 1.00 3.18
4.44E+02 0.86 1.00 3.18
4.10E+02 0.49 1.00 3.18
2.04E+01 0.35 1.00 3.18
3.92E+02 1.39 1.00 3.18
2.36E+02 0.52 1.00 3.18 10000 1000
3.52E+02 0.33 1.00 3.18
3.75E+02 0.28 1.00 3.18
4.95E+02 1.25 1.00 3.18
4.70E+02 0.75 1.00 3.18
4.62E+02 0.40 1.00 3.18
4.34E+02 2.14 1.00 3.18
1.26E+01 1.11 1.00 3.18
1.87E+02 0.78 1.00 3.18
1.86E+02 1.34 1.00 3.18 10000 1000
2.91E+02 0.52 1.00 3.18
3.57E+02 1.17 1.00 3.18
4.48E+02 0.62 1.00 3.18
4.66E+02 1.28 1.00 3.18
4.03E+02 0.77 1.00 3.18
3.87E+02 0.49 1.00 3.18
5.00E-01 1.34 1.00 3.18
5.00E-01 1.03 1.00 3.18
5.00E-01 1.76 1.00 3.18
5.00E-01 1.26 1.00 3.18
5.00E-01 1.33 1.00 3.18
5.00E-01 0.66 1.00 3.18
5.00E-01 1.76 1.00 3.18
5.00E-01 21.61 1.00 3.18
5.00E-01 11.42 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.24E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.21E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/14/11 4:17 PM EPA Interlab LRef 1315 SWA
3/14/11 4:19 PM EPA Interlab LRef 1315 SWA
3/14/11 4:20 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:22 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:24 PM EPA Interlab LRef 1315 SWA
3/14/11 4:25 PM EPA Interlab LRef 1315 SWA
3/14/11 4:27 PM EPA Interlab LRef 1315 SWA
3/14/11 4:28 PM EPA Interlab LRef 1315 SWA
3/14/11 4:30 PM EPA Interlab LRef 1315 SWA
3/14/11 4:32 PM EPA Interlab LRef 1315 SWA
3/14/11 4:33 PM EPA Interlab LRef 1315 SWA
3/14/11 4:35 PM EPA Interlab LRef 1315 SWA
3/14/11 4:37 PM EPA Interlab LRef 1315 SWA
3/14/11 4:38 PM EPA Interlab LRef 1315 SWA
3/14/11 4:40 PM EPA Interlab LRef 1315 SWA
3/14/11 4:42 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:43 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:45 PM EPA Interlab LRef 1315 SWA
3/15/11 10:28 AM EPA Interlab LRef 1315 SWA
3/15/11 10:30 AM EPA Interlab LRef 1315 SWA
3/15/11 10:32 AM EPA Interlab LRef 1315 SWA
3/15/11 10:33 AM EPA Interlab LRef 1315 SWA
3/15/11 10:35 AM EPA Interlab LRef 1315 SWA
3/15/11 10:37 AM EPA Interlab LRef 1315 SWA
3/15/11 10:38 AM EPA Interlab LRef 1315 SWA
3/15/11 10:40 AM EPA Interlab LRef 1315 SWA
3/15/11 10:41 AM EPA Interlab LRef 1315 SWA
3/14/1 1 2:57 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:30 PM EPA Interlab LRef 1315 SWA
3/14/11 2:58 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:00 PM EPA Interlab LRef 1315 SWA
3/14/11 3:01 PM EPA Interlab LRef 1315 SWA
3/14/11 3:24 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:25 PM EPA Interlab LRef 1315 SWA
3/14/11 3:27 PM EPA Interlab LRef 1315 SWA
3/14/11 3:29 PM EPA Interlab LRef 1315 SWA
1-704
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Be SWA-LRef-1315-T01-A 1 9.50E-01 U1/2
Be SWA-LRef-1315-T02-A 1 9.50E-01 U1/2
Be SWA-LRef-1315-T03-A 1 9.50E-01 U1/2
Be SWA-LRef-1315-T04-A 1 9.50E-01 U1/2
Be SWA-LRef-1315-T05-A 1 9.50E-01 U1/2
Be SWA-LRef-1315-T06-A 1 9.50E-01 U1/2
Be SWA-LRef-1315-T07-A 1 9.50E-01 U1/2
Be SWA-LRef-1315-T08-A 1 9.50E-01 U1/2
Be SWA-LRef-1315-T09-A 1 9.50E-01 U1/2
Be SWA-LRef-1315-T01-B 1 9.50E-01 U1/2
Be SWA-LRef-1315-T02-B 1 9.50E-01 U1/2
Be SWA-LRef-1315-T03-B 1 9.50E-01 U1/2
Be SWA-LRef-1315-T04-B 1 9.50E-01 U1/2
Be SWA-LRef-1315-T05-B 1 9.50E-01 U1/2
Be SWA-LRef-1315-T06-B 1 9.50E-01 U1/2
Be SWA-LRef-1315-T07-B 1 9.50E-01 U1/2
Be SWA-LRef-1315-T08-B 1 9.50E-01 U1/2
Be SWA-LRef-1315-T09-B 1 9.50E-01 U1/2
Be SWA-LRef-1315-T01-C 1 9.50E-01 U1/2
Be SWA-LRef-1315-T02-C 1 9.50E-01 U1/2
Be SWA-LRef-1315-T03-C 1 9.50E-01 U1/2
Be SWA-LRef-1315-T04-C 1 9.50E-01 U1/2
Be SWA-LRef-1315-T05-C 1 9.50E-01 U1/2
Be SWA-LRef-1315-T06-C 1 9.50E-01 U1/2
Be SWA-LRef-1315-T07-C 1 9.50E-01 U1/2
Be SWA-LRef-1315-T08-C 1 9.50E-01 U1/2
Be SWA-LRef-1315-T09-C 1 9.50E-01 U1/2
Be SWA-LRef-1315-M01-A 1 9.50E-01 U1/2
Be SWA-LRef-1315-M02-A 1 9.50E-01 U1/2
Be SWA-LRef-1315-M03-A 1 9.50E-01 U1/2
Be SWA-LRef-1315-M04-A 1 9.50E-01 U1/2
Be SWA-LRef-1315-M05-A 1 9.50E-01 U1/2
Be SWA-LRef-1315-M06-A 1 9.50E-01 U1/2
Be SWA-LRef-1315-M07-A 1 9.50E-01 U1/2
Be SWA-LRef-1315-M08-A 1 9.50E-01 U1/2
Be SWA-LRef-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 48.61 1.90 6.00
9.50E-01 22.95 1.90 6.00
9.50E-01 49.03 1.90 6.00 10000 1000
9.50E-01 20.98 1.90 6.00
9.50E-01 68.12 1.90 6.00
9.50E-01 8.97 1.90 6.00
9.50E-01 38.28 1.90 6.00
9.50E-01 7.16 1.90 6.00
9.50E-01 8.59 1.90 6.00
9.50E-01 33.13 1.90 6.00
9.50E-01 11.72 1.90 6.00
9.50E-01 9.70 1.90 6.00 10000 1000
9.50E-01 102.25 1.90 6.00
9.50E-01 42.23 1.90 6.00
9.50E-01 29.38 1.90 6.00
9.50E-01 19.43 1.90 6.00
9.50E-01 50.08 1.90 6.00
9.50E-01 37.48 1.90 6.00
9.50E-01 23.72 1.90 6.00
9.50E-01 26.90 1.90 6.00
9.50E-01 67.19 1.90 6.00 10000 1000
9.50E-01 28.25 1.90 6.00
9.50E-01 25.49 1.90 6.00
9.50E-01 17.10 1.90 6.00
9.50E-01 59.87 1.90 6.00
9.50E-01 40.14 1.90 6.00
9.50E-01 6.61 1.90 6.00
9.50E-01 62.41 1.90 6.00
9.50E-01 38.07 1.90 6.00
9.50E-01 59.86 1.90 6.00
9.50E-01 22.20 1.90 6.00
9.50E-01 18.75 1.90 6.00
9.50E-01 19.42 1.90 6.00
9.50E-01 29.48 1.90 6.00
9.50E-01 46.18 1.90 6.00
9.50E-01 7.59 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.80E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/14/11 4:17 PM EPA Interlab LRef 1315 SWA
3/14/11 4:19 PM EPA Interlab LRef 1315 SWA
3/14/11 4:20 PM EPA Interlab LRef 1315 SWA
3/14/11 4:22 PM EPA Interlab LRef 1315 SWA
3/14/11 4:24 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:25 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:27 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:28 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:30 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:32 PM EPA Interlab LRef 1315 SWA
3/14/11 4:33 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:35 PM EPA Interlab LRef 1315 SWA
3/14/11 4:37 PM EPA Interlab LRef 1315 SWA
3/14/11 4:38 PM EPA Interlab LRef 1315 SWA
3/14/11 4:40 PM EPA Interlab LRef 1315 SWA
3/14/11 4:42 PM EPA Interlab LRef 1315 SWA
3/14/11 4:43 PM EPA Interlab LRef 1315 SWA
3/14/11 4:45 PM EPA Interlab LRef 1315 SWA
3/15/11 10:28 AM EPA Interlab LRef 1315 SWA
3/15/11 10:30 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:32 AM EPA Interlab LRef 1315 SWA
3/15/11 10:33 AM EPA Interlab LRef 1315 SWA
3/15/11 10:35 AM EPA Interlab LRef 1315 SWA
3/15/11 10:37 AM EPA Interlab LRef 1315 SWA
3/15/11 10:38 AM EPA Interlab LRef 1315 SWA
3/15/11 10:40 AM EPA Interlab LRef 1315 SWA
3/15/11 10:41 AM EPA Interlab LRef 1315 SWA
3/14/11 2:57 PM EPA Interlab LRef 1315 SWA
3/14/11 3:30 PM EPA Interlab LRef 1315 SWA
3/14/11 2:58 PM EPA Interlab LRef 1315 SWA
3/14/11 3:00 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:01 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:24 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:25 PM EPA Interlab LRef 1315 SWA
3/14/11 3:27 PM EPA Interlab LRef 1315 SWA
3/14/11 3:29 PM EPA Interlab LRef 1315 SWA
1-705
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cd SWA-LRef-1315-T01-A 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T02-A 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T03-A 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T04-A 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T05-A 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T06-A 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T07-A 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T08-A 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T09-A 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T01-B 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T02-B 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T03-B 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T04-B 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T05-B 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T06-B 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T07-B 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T08-B 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T09-B 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T01-C 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T02-C 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T03-C 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T04-C 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T05-C 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T06-C 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T07-C 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T08-C 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T09-C 1 1.10E+00 U1/2
Cd SWA-LRef-1315-M01-A 1 1.10E+00 U1/2
Cd SWA-LRef-1315-M02-A 1 1.10E+00 U1/2
Cd SWA-LRef-1315-M03-A 1 1.10E+00 U1/2
Cd SWA-LRef-1315-M04-A 1 1.10E+00 U1/2
Cd SWA-LRef-1315-M05-A 1 1.10E+00 U1/2
Cd SWA-LRef-1315-M06-A 1 1.10E+00 U1/2
Cd SWA-LRef-1315-M07-A 1 1.10E+00 U1/2
Cd SWA-LRef-1315-M08-A 1 1.10E+00 U1/2
Cd SWA-LRef-1315-M09-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 37.59 2.20 7.00
1.10E+00 68.01 2.20 7.00
1.10E+00 29.76 2.20 7.00 10000 1000
1.10E+00 9.06 2.20 7.00
1.10E+00 65.30 2.20 7.00
1.10E+00 58.93 2.20 7.00
1.10E+00 42.52 2.20 7.00
1.10E+00 70.84 2.20 7.00
1.10E+00 58.52 2.20 7.00
1.10E+00 29.98 2.20 7.00
1.10E+00 32.36 2.20 7.00
1.10E+00 36.15 2.20 7.00 10000 1000
1.10E+00 26.47 2.20 7.00
1.10E+00 11.97 2.20 7.00
1.10E+00 25.16 2.20 7.00
1.10E+00 52.92 2.20 7.00
1.10E+00 54.08 2.20 7.00
1.10E+00 43.76 2.20 7.00
1.10E+00 26.54 2.20 7.00
1.10E+00 31.41 2.20 7.00
1.10E+00 44.02 2.20 7.00 10000 1000
1.10E+00 33.41 2.20 7.00
1.10E+00 19.79 2.20 7.00
1.10E+00 25.33 2.20 7.00
1.10E+00 31.40 2.20 7.00
1.10E+00 22.31 2.20 7.00
1.10E+00 45.64 2.20 7.00
1.10E+00 37.04 2.20 7.00
1.10E+00 50.92 2.20 7.00
1.10E+00 41.51 2.20 7.00
1.10E+00 45.66 2.20 7.00
1.10E+00 82.33 2.20 7.00
1.10E+00 33.10 2.20 7.00
1.10E+00 29.32 2.20 7.00
1.10E+00 65.90 2.20 7.00
1.10E+00 21.15 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.99E+02 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.73E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/14/11 4:17 PM EPA Interlab LRef 1315 SWA
3/14/11 4:19 PM EPA Interlab LRef 1315 SWA
3/14/11 4:20 PM EPA Interlab LRef 1315 SWA
3/14/11 4:22 PM EPA Interlab LRef 1315 SWA
3/14/11 4:24 PM EPA Interlab LRef 1315 SWA
3/14/11 4:25 PM EPA Interlab LRef 1315 SWA
3/14/11 4:27 PM EPA Interlab LRef 1315 SWA
3/14/11 4:28 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:30 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:32 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:33 PM EPA Interlab LRef 1315 SWA
3/14/11 4:35 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:37 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:38 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:40 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:42 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:43 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:45 PM EPA Interlab LRef 1315 SWA
3/15/11 10:28 AM EPA Interlab LRef 1315 SWA
3/15/11 10:30 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:32 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:33 AM EPA Interlab LRef 1315 SWA
3/15/11 10:35 AM EPA Interlab LRef 1315 SWA
3/15/11 10:37 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:38 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:40 AM EPA Interlab LRef 1315 SWA
3/15/11 10:41 AM EPA Interlab LRef 1315 SWA
3/14/11 2:57 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:30 PM EPA Interlab LRef 1315 SWA
3/14/11 2:58 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:00 PM EPA Interlab LRef 1315 SWA
3/14/11 3:01 PM EPA Interlab LRef 1315 SWA
3/14/11 3:24 PM EPA Interlab LRef 1315 SWA
3/14/11 3:25 PM EPA Interlab LRef 1315 SWA
3/14/11 3:27 PM EPA Interlab LRef 1315 SWA
3/14/11 3:29 PM EPA Interlab LRef 1315 SWA
1-706
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Ca SWA-LRef-1315-T01-A 1 2.01E+03
Ca SWA-LRef-1315-T02-A 1 1.45E+04
Ca SWA-LRef-1315-T03-A 1 1.46E+04
Ca SWA-LRef-1315-T04-A 1 2.51E+04
Ca SWA-LRef-1315-T05-A 1 2.76E+04
Ca SWA-LRef-1315-T06-A 1 2.70E+04
Ca SWA-LRef-1315-T07-A 1 2.98E+04
Ca SWA-LRef-1315-T08-A 1 2.48E+04
Ca SWA-LRef-1315-T09-A 1 2.74E+04
Ca SWA-LRef-1315-T01-B 1 1.91E+03
Ca SWA-LRef-1315-T02-B 1 1.39E+04
Ca SWA-LRef-1315-T03-B 1 1.46E+04
Ca SWA-LRef-1315-T04-B 1 2.43E+04
Ca SWA-LRef-1315-T05-B 1 2.58E+04
Ca SWA-LRef-1315-T06-B 1 2.74E+04
Ca SWA-LRef-1315-T07-B 1 2.54E+04
Ca SWA-LRef-1315-T08-B 1 2.35E+04
Ca SWA-LRef-1315-T09-B 1 2.50E+04
Ca SWA-LRef-1315-T01-C 1 1.02E+03
Ca SWA-LRef-1315-T02-C 1 1.27E+04
Ca SWA-LRef-1315-T03-C 1 1.48E+04
Ca SWA-LRef-1315-T04-C 1 2.41 E+04
Ca SWA-LRef-1315-T05-C 1 2.68E+04
Ca SWA-LRef-1315-T06-C 1 2.74E+04
Ca SWA-LRef-1315-T07-C 1 2.64E+04
Ca SWA-LRef-1315-T08-C 1 2.33E+04
Ca SWA-LRef-1315-T09-C 1 2.43E+04
Ca SWA-LRef-1315-M01-A 1 1.09E+02
Ca SWA-LRef-1315-M02-A 1 7.26E+01
Ca SWA-LRef-1315-M03-A 1 1.30E+01
Ca SWA-LRef-1315-M04-A 1 9.01 E+01
Ca SWA-LRef-1315-M05-A 1 1.43E+02
Ca SWA-LRef-1315-M06-A 1 1.53E+02
Ca SWA-LRef-1315-M07-A 1 1.02E+02
Ca SWA-LRef-1315-M08-A 1 7.26E+01
Ca SWA-LRef-1315-M09-A 1 8.38E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.01 E+03 2.27 2.60 8.30
1.45E+04 1.00 2.60 8.30
1.46E+04 1.15 2.60 8.30 10000 1000
2. 51 E+04 0.49 2.60 8.30
2.76E+04 0.97 2.60 8.30
2.70E+04 0.51 2.60 8.30
2.98E+04 0.49 2.60 8.30
2.48E+04 0.55 2.60 8.30
2.74E+04 0.49 2.60 8.30
1.91E+03 1.14 2.60 8.30
1.39E+04 0.46 2.60 8.30
1.46E+04 0.54 2.60 8.30 10000 1000
2.43E+04 0.28 2.60 8.30
2.58E+04 0.26 2.60 8.30
2.74E+04 0.60 2.60 8.30
2.54E+04 0.52 2.60 8.30
2.35E+04 0.36 2.60 8.30
2.50E+04 0.67 2.60 8.30
1.02E+03 3.13 2.60 8.30
1.27E+04 0.15 2.60 8.30
1.48E+04 0.65 2.60 8.30 10000 1000
2.41 E+04 0.60 2.60 8.30
2.68E+04 1.37 2.60 8.30
2.74E+04 1.50 2.60 8.30
2.64E+04 0.82 2.60 8.30
2.33E+04 0.89 2.60 8.30
2.43E+04 0.42 2.60 8.30
1.09E+02 2.15 2.60 8.30
7.26E+01 4.31 2.60 8.30
1.30E+01 8.20 2.60 8.30
9.01 E+01 5.77 2.60 8.30
1.43E+02 2.07 2.60 8.30
1.53E+02 0.66 2.60 8.30
1.02E+02 7.31 2.60 8.30
7.26E+01 6.07 2.60 8.30
8.38E+01 3.32 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.55E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.55E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.57E+04 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/14/11 4:17 PM EPA Interlab LRef 1315 SWA
3/14/11 4:19 PM EPA Interlab LRef 1315 SWA
3/14/11 4:20 PM EPA Interlab LRef 1315 SWA
3/14/11 4:22 PM EPA Interlab LRef 1315 SWA
3/14/11 4:24 PM EPA Interlab LRef 1315 SWA
3/14/11 4:25 PM EPA Interlab LRef 1315 SWA
3/14/11 4:27 PM EPA Interlab LRef 1315 SWA
3/14/11 4:28 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:30 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:32 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:33 PM EPA Interlab LRef 1315 SWA
3/14/11 4:35 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:37 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:38 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:40 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:42 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:43 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:45 PM EPA Interlab LRef 1315 SWA
3/15/11 10:28 AM EPA Interlab LRef 1315 SWA
3/15/11 10:30 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:32 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:33 AM EPA Interlab LRef 1315 SWA
3/15/11 10:35 AM EPA Interlab LRef 1315 SWA
3/15/11 10:37 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:38 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:40 AM EPA Interlab LRef 1315 SWA
3/15/11 10:41 AM EPA Interlab LRef 1315 SWA
3/14/11 2:57 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:30 PM EPA Interlab LRef 1315 SWA
3/14/11 2:58 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:00 PM EPA Interlab LRef 1315 SWA
3/14/11 3:01 PM EPA Interlab LRef 1315 SWA
3/14/11 3:24 PM EPA Interlab LRef 1315 SWA
3/14/11 3:25 PM EPA Interlab LRef 1315 SWA
3/14/11 3:27 PM EPA Interlab LRef 1315 SWA
3/14/11 3:29 PM EPA Interlab LRef 1315 SWA
1-707
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Cr SWA-LRef-1315-T01-A 1 2.58E+01
Cr SWA-LRef-1315-T02-A 1 5.87E+01
Cr SWA-LRef-1315-T03-A 1 3.42E+01
Cr SWA-LRef-1315-T04-A 1 5.50E+01
Cr SWA-LRef-1315-T05-A 1 4.98E+01
Cr SWA-LRef-1315-T06-A 1 5.18E+01
Cr SWA-LRef-1315-T07-A 1 5.01E+01
Cr SWA-LRef-1315-T08-A 1 3.46E+01
Cr SWA-LRef-1315-T09-A 1 4.66E+01
Cr SWA-LRef-1315-T01-B 1 2.61E+01
Cr SWA-LRef-1315-T02-B 1 3.59E+01
Cr SWA-LRef-1315-T03-B 1 2.36E+01
Cr SWA-LRef-1315-T04-B 1 3.74E+01
Cr SWA-LRef-1315-T05-B 1 4.22E+01
Cr SWA-LRef-1315-T06-B 1 4.98E+01
Cr SWA-LRef-1315-T07-B 1 5.00E+01
Cr SWA-LRef-1315-T08-B 1 3.57E+01
Cr SWA-LRef-1315-T09-B 1 4.44E+01
Cr SWA-LRef-1315-T01-C 1 2.65E+01
Cr SWA-LRef-1315-T02-C 1 4.54E+01
Cr SWA-LRef-1315-T03-C 1 2.84E+01
Cr SWA-LRef-1315-T04-C 1 4.36E+01
Cr SWA-LRef-1315-T05-C 1 4.70E+01
Cr SWA-LRef-1315-T06-C 1 5.21E+01
Cr SWA-LRef-1315-T07-C 1 5.27E+01
Cr SWA-LRef-1315-T08-C 1 3.63E+01
Cr SWA-LRef-1315-T09-C 1 4.76E+01
Cr SWA-LRef-1315-M01-A 1 6.00E-01 U1/2
Cr SWA-LRef-1315-M02-A 1 6.00E-01 U1/2
Cr SWA-LRef-1315-M03-A 1 6.00E-01 U1/2
Cr SWA-LRef-1315-M04-A 1 6.00E-01 U1/2
Cr SWA-LRef-1315-M05-A 1 6.00E-01 U1/2
Cr SWA-LRef-1315-M06-A 1 6.00E-01 U1/2
Cr SWA-LRef-1315-M07-A 1 6.00E-01 U1/2
Cr SWA-LRef-1315-M08-A 1 6.00E-01 U1/2
Cr SWA-LRef-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.58E+01 1.39 1.20 3.82
5.87E+01 1.31 1.20 3.82
3.42E+01 0.86 1.20 3.82 10000 1000
5.50E+01 0.19 1.20 3.82
4.98E+01 0.81 1.20 3.82
5.18E+01 1.16 1.20 3.82
5.01E+01 1.44 1.20 3.82
3.46E+01 1.97 1.20 3.82
4.66E+01 0.87 1.20 3.82
2.61E+01 0.72 1.20 3.82
3.59E+01 0.73 1.20 3.82
2.36E+01 2.61 1.20 3.82 10000 1000
3.74E+01 1.09 1.20 3.82
4.22E+01 0.20 1.20 3.82
4.98E+01 0.95 1.20 3.82
5.00E+01 0.56 1.20 3.82
3.57E+01 0.62 1.20 3.82
4.44E+01 0.13 1.20 3.82
2.65E+01 1.18 1.20 3.82
4.54E+01 0.46 1.20 3.82
2.84E+01 2.27 1.20 3.82 10000 1000
4.36E+01 0.97 1.20 3.82
4.70E+01 1.01 1.20 3.82
5.21E+01 1.59 1.20 3.82
5.27E+01 1.41 1.20 3.82
3.63E+01 1.38 1.20 3.82
4.76E+01 1.09 1.20 3.82
6.00E-01 17.89 1.20 3.82
6.00E-01 20.84 1.20 3.82
6.00E-01 23.72 1.20 3.82
6.00E-01 39.16 1.20 3.82
6.00E-01 22.63 1.20 3.82
6.00E-01 2.61 1.20 3.82
6.00E-01 9.53 1.20 3.82
6.00E-01 14.26 1.20 3.82
6.00E-01 7.94 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.03E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/14/11 4:17 PM EPA Interlab LRef 1315 SWA
3/14/11 4:19 PM EPA Interlab LRef 1315 SWA
3/14/11 4:20 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:22 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:24 PM EPA Interlab LRef 1315 SWA
3/14/11 4:25 PM EPA Interlab LRef 1315 SWA
3/14/11 4:27 PM EPA Interlab LRef 1315 SWA
3/14/11 4:28 PM EPA Interlab LRef 1315 SWA
3/14/11 4:30 PM EPA Interlab LRef 1315 SWA
3/14/11 4:32 PM EPA Interlab LRef 1315 SWA
3/14/11 4:33 PM EPA Interlab LRef 1315 SWA
3/14/11 4:35 PM EPA Interlab LRef 1315 SWA
3/14/11 4:37 PM EPA Interlab LRef 1315 SWA
3/14/11 4:38 PM EPA Interlab LRef 1315 SWA
3/14/11 4:40 PM EPA Interlab LRef 1315 SWA
3/14/11 4:42 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:43 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:45 PM EPA Interlab LRef 1315 SWA
3/15/11 10:28 AM EPA Interlab LRef 1315 SWA
3/15/11 10:30 AM EPA Interlab LRef 1315 SWA
3/15/11 10:32 AM EPA Interlab LRef 1315 SWA
3/15/11 10:33 AM EPA Interlab LRef 1315 SWA
3/15/11 10:35 AM EPA Interlab LRef 1315 SWA
3/15/11 10:37 AM EPA Interlab LRef 1315 SWA
3/15/11 10:38 AM EPA Interlab LRef 1315 SWA
3/15/11 10:40 AM EPA Interlab LRef 1315 SWA
3/15/11 10:41 AM EPA Interlab LRef 1315 SWA
3/14/1 1 2:57 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:30 PM EPA Interlab LRef 1315 SWA
3/14/11 2:58 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:00 PM EPA Interlab LRef 1315 SWA
3/14/11 3:01 PM EPA Interlab LRef 1315 SWA
3/14/11 3:24 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:25 PM EPA Interlab LRef 1315 SWA
3/14/11 3:27 PM EPA Interlab LRef 1315 SWA
3/14/11 3:29 PM EPA Interlab LRef 1315 SWA
1-708
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Co SWA-LRef-1315-T01-A 1 9.00E-01 U1/2
Co SWA-LRef-1315-T02-A 1 9.00E-01 U1/2
Co SWA-LRef-1315-T03-A 1 9.00E-01 U1/2
Co SWA-LRef-1315-T04-A 1 9.00E-01 U1/2
Co SWA-LRef-1315-T05-A 1 9.00E-01 U1/2
Co SWA-LRef-1315-T06-A 1 9.00E-01 U1/2
Co SWA-LRef-1315-T07-A 1 9.00E-01 U1/2
Co SWA-LRef-1315-T08-A 1 9.00E-01 U1/2
Co SWA-LRef-1315-T09-A 1 9.00E-01 U1/2
Co SWA-LRef-1315-T01-B 1 9.00E-01 U1/2
Co SWA-LRef-1315-T02-B 1 9.00E-01 U1/2
Co SWA-LRef-1315-T03-B 1 9.00E-01 U1/2
Co SWA-LRef-1315-T04-B 1 9.00E-01 U1/2
Co SWA-LRef-1315-T05-B 1 9.00E-01 U1/2
Co SWA-LRef-1315-T06-B 1 9.00E-01 U1/2
Co SWA-LRef-1315-T07-B 1 9.00E-01 U1/2
Co SWA-LRef-1315-T08-B 1 9.00E-01 U1/2
Co SWA-LRef-1315-T09-B 1 9.00E-01 U1/2
Co SWA-LRef-1315-T01-C 1 9.00E-01 U1/2
Co SWA-LRef-1315-T02-C 1 9.00E-01 U1/2
Co SWA-LRef-1315-T03-C 1 9.00E-01 U1/2
Co SWA-LRef-1315-T04-C 1 9.00E-01 U1/2
Co SWA-LRef-1315-T05-C 1 9.00E-01 U1/2
Co SWA-LRef-1315-T06-C 1 9.00E-01 U1/2
Co SWA-LRef-1315-T07-C 1 9.00E-01 U1/2
Co SWA-LRef-1315-T08-C 1 9.00E-01 U1/2
Co SWA-LRef-1315-T09-C 1 9.00E-01 U1/2
Co SWA-LRef-1315-M01-A 1 9.00E-01 U1/2
Co SWA-LRef-1315-M02-A 1 9.00E-01 U1/2
Co SWA-LRef-1315-M03-A 1 9.00E-01 U1/2
Co SWA-LRef-1315-M04-A 1 9.00E-01 U1/2
Co SWA-LRef-1315-M05-A 1 9.00E-01 U1/2
Co SWA-LRef-1315-M06-A 1 9.00E-01 U1/2
Co SWA-LRef-1315-M07-A 1 9.00E-01 U1/2
Co SWA-LRef-1315-M08-A 1 9.00E-01 U1/2
Co SWA-LRef-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 30.27 1.80 5.72
9.00E-01 44.05 1.80 5.72
9.00E-01 33.88 1.80 5.72 10000 1000
9.00E-01 52.87 1.80 5.72
9.00E-01 33.03 1.80 5.72
9.00E-01 43.18 1.80 5.72
9.00E-01 73.49 1.80 5.72
9.00E-01 45.72 1.80 5.72
9.00E-01 2.05 1.80 5.72
9.00E-01 40.04 1.80 5.72
9.00E-01 63.44 1.80 5.72
9.00E-01 10.78 1.80 5.72 10000 1000
9.00E-01 10.15 1.80 5.72
9.00E-01 60.57 1.80 5.72
9.00E-01 42.75 1.80 5.72
9.00E-01 12.74 1.80 5.72
9.00E-01 28.37 1.80 5.72
9.00E-01 64.20 1.80 5.72
9.00E-01 43.39 1.80 5.72
9.00E-01 64.30 1.80 5.72
9.00E-01 25.08 1.80 5.72 10000 1000
9.00E-01 24.11 1.80 5.72
9.00E-01 19.53 1.80 5.72
9.00E-01 28.82 1.80 5.72
9.00E-01 74.24 1.80 5.72
9.00E-01 63.10 1.80 5.72
9.00E-01 14.92 1.80 5.72
9.00E-01 27.96 1.80 5.72
9.00E-01 44.27 1.80 5.72
9.00E-01 73.28 1.80 5.72
9.00E-01 25.93 1.80 5.72
9.00E-01 49.63 1.80 5.72
9.00E-01 24.40 1.80 5.72
9.00E-01 4.56 1.80 5.72
9.00E-01 42.93 1.80 5.72
9.00E-01 55.68 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.70E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.95E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.54E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/14/11 4:17 PM EPA Interlab LRef 1315 SWA
3/14/11 4:19 PM EPA Interlab LRef 1315 SWA
3/14/11 4:20 PM EPA Interlab LRef 1315 SWA
3/14/11 4:22 PM EPA Interlab LRef 1315 SWA
3/14/11 4:24 PM EPA Interlab LRef 1315 SWA
3/14/11 4:25 PM EPA Interlab LRef 1315 SWA
3/14/11 4:27 PM EPA Interlab LRef 1315 SWA
3/14/11 4:28 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:30 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:32 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:33 PM EPA Interlab LRef 1315 SWA
3/14/11 4:35 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:37 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:38 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:40 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:42 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:43 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:45 PM EPA Interlab LRef 1315 SWA
3/15/11 10:28 AM EPA Interlab LRef 1315 SWA
3/15/11 10:30 AM EPA Interlab LRef 1315 SWA
3/15/11 10:32 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:33 AM EPA Interlab LRef 1315 SWA
3/15/11 10:35 AM EPA Interlab LRef 1315 SWA
3/15/11 10:37 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:38 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:40 AM EPA Interlab LRef 1315 SWA
3/15/11 10:41 AM EPA Interlab LRef 1315 SWA
3/14/11 2:57 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:30 PM EPA Interlab LRef 1315 SWA
3/14/11 2:58 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:00 PM EPA Interlab LRef 1315 SWA
3/14/11 3:01 PM EPA Interlab LRef 1315 SWA
3/14/11 3:24 PM EPA Interlab LRef 1315 SWA
3/14/11 3:25 PM EPA Interlab LRef 1315 SWA
3/14/11 3:27 PM EPA Interlab LRef 1315 SWA
3/14/11 3:29 PM EPA Interlab LRef 1315 SWA
1-709
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cu SWA-LRef-1315-T01-A 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T02-A 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T03-A 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T04-A 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T05-A 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T06-A 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T07-A 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T08-A 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T09-A 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T01-B 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T02-B 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T03-B 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T04-B 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T05-B 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T06-B 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T07-B 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T08-B 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T09-B 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T01-C 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T02-C 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T03-C 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T04-C 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T05-C 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T06-C 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T07-C 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T08-C 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T09-C 1 1.85E+00 U1/2
Cu SWA-LRef-1315-M01-A 1 1.85E+00 U1/2
Cu SWA-LRef-1315-M02-A 1 1.85E+00 U1/2
Cu SWA-LRef-1315-M03-A 1 1.85E+00 U1/2
Cu SWA-LRef-1315-M04-A 1 1.85E+00 U1/2
Cu SWA-LRef-1315-M05-A 1 1.85E+00 U1/2
Cu SWA-LRef-1315-M06-A 1 1.85E+00 U1/2
Cu SWA-LRef-1315-M07-A 1 1.85E+00 U1/2
Cu SWA-LRef-1315-M08-A 1 1.85E+00 U1/2
Cu SWA-LRef-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 19.87 3.70 11.80
1.85E+00 37.22 3.70 11.80
1.85E+00 64.54 3.70 11.80 10000 1000
1.85E+00 9.18 3.70 11.80
1.85E+00 7.64 3.70 11.80
1.85E+00 20.04 3.70 11.80
1.85E+00 68.38 3.70 11.80
1.85E+00 2.58 3.70 11.80
1.85E+00 23.93 3.70 11.80
1.85E+00 46.07 3.70 11.80
1.85E+00 21.76 3.70 11.80
1.85E+00 23.34 3.70 11.80 10000 1000
1.85E+00 67.05 3.70 11.80
1.85E+00 36.49 3.70 11.80
1.85E+00 29.82 3.70 11.80
1.85E+00 51.21 3.70 11.80
1.85E+00 26.71 3.70 11.80
1.85E+00 15.57 3.70 11.80
1.85E+00 52.69 3.70 11.80
1.85E+00 20.87 3.70 11.80
1.85E+00 28.31 3.70 11.80 10000 1000
1.85E+00 26.82 3.70 11.80
1.85E+00 33.07 3.70 11.80
1.85E+00 33.25 3.70 11.80
1.85E+00 22.83 3.70 11.80
1.85E+00 86.04 3.70 11.80
1.85E+00 31.05 3.70 11.80
1.85E+00 41.63 3.70 11.80
1.85E+00 63.39 3.70 11.80
1.85E+00 42.19 3.70 11.80
1.85E+00 18.35 3.70 11.80
1.85E+00 49.57 3.70 11.80
1.85E+00 31.08 3.70 11.80
1.85E+00 24.14 3.70 11.80
1.85E+00 41.18 3.70 11.80
1.85E+00 46.07 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.80E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.51 E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/14/11 4:17 PM EPA Interlab LRef 1315 SWA
3/14/11 4:19 PM EPA Interlab LRef 1315 SWA
3/14/11 4:20 PM EPA Interlab LRef 1315 SWA
3/14/11 4:22 PM EPA Interlab LRef 1315 SWA
3/14/11 4:24 PM EPA Interlab LRef 1315 SWA
3/14/11 4:25 PM EPA Interlab LRef 1315 SWA
3/14/11 4:27 PM EPA Interlab LRef 1315 SWA
3/14/11 4:28 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:30 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:32 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:33 PM EPA Interlab LRef 1315 SWA
3/14/11 4:35 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:37 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:38 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:40 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:42 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:43 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:45 PM EPA Interlab LRef 1315 SWA
3/15/11 10:28 AM EPA Interlab LRef 1315 SWA
3/15/11 10:30 AM EPA Interlab LRef 1315 SWA
3/15/11 10:32 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:33 AM EPA Interlab LRef 1315 SWA
3/15/11 10:35 AM EPA Interlab LRef 1315 SWA
3/15/11 10:37 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:38 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:40 AM EPA Interlab LRef 1315 SWA
3/15/11 10:41 AM EPA Interlab LRef 1315 SWA
3/14/11 2:57 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:30 PM EPA Interlab LRef 1315 SWA
3/14/11 2:58 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:00 PM EPA Interlab LRef 1315 SWA
3/14/11 3:01 PM EPA Interlab LRef 1315 SWA
3/14/11 3:24 PM EPA Interlab LRef 1315 SWA
3/14/11 3:25 PM EPA Interlab LRef 1315 SWA
3/14/11 3:27 PM EPA Interlab LRef 1315 SWA
3/14/11 3:29 PM EPA Interlab LRef 1315 SWA
1-710
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Fe SWA-LRef-1315-T01-A 1 8.72E+00
Fe SWA-LRef-1315-T02-A 1 1.63E+01
Fe SWA-LRef-1315-T03-A 1 5.46E+00 E
Fe SWA-LRef-1315-T04-A 1 5.77E+00 E
Fe SWA-LRef-1315-T05-A 1 4.42E+00 E
Fe SWA-LRef-1315-T06-A 1 3.47E+00 E
Fe SWA-LRef-1315-T07-A 1 5.29E+00 E
Fe SWA-LRef-1315-T08-A 1 2.28E+00 E
Fe SWA-LRef-1315-T09-A 1 2.57E+00 E
Fe SWA-LRef-1315-T01-B 1 1.01E+01
Fe SWA-LRef-1315-T02-B 1 9.74E+00
Fe SWA-LRef-1315-T03-B 1 5.85E+00 E
Fe SWA-LRef-1315-T04-B 1 5.36E+00 E
Fe SWA-LRef-1315-T05-B 1 3.72E+00 E
Fe SWA-LRef-1315-T06-B 1 3.64E+00 E
Fe SWA-LRef-1315-T07-B 1 2.80E+00 E
Fe SWA-LRef-1315-T08-B 1 1.00E+00 U1/2
Fe SWA-LRef-1315-T09-B 1 2.20E+00 E
Fe SWA-LRef-1315-T01-C 1 5.95E+00 E
Fe SWA-LRef-1315-T02-C 1 1.08E+01
Fe SWA-LRef-1315-T03-C 1 5.87E+00 E
Fe SWA-LRef-1315-T04-C 1 5.59E+00 E
Fe SWA-LRef-1315-T05-C 1 1.14E+01
Fe SWA-LRef-1315-T06-C 1 3.81E+00 E
Fe SWA-LRef-1315-T07-C 1 2.58E+00 E
Fe SWA-LRef-1315-T08-C 1 2.14E+00 E
Fe SWA-LRef-1315-T09-C 1 1.00E+00 U1/2
Fe SWA-LRef-1315-M01-A 1 1.00E+00 U1/2
Fe SWA-LRef-1315-M02-A 1 1.00E+00 U1/2
Fe SWA-LRef-1315-M03-A 1 1.00E+00 U1/2
Fe SWA-LRef-1315-M04-A 1 1.00E+00 U1/2
Fe SWA-LRef-1315-M05-A 1 1.00E+00 U1/2
Fe SWA-LRef-1315-M06-A 1 1.00E+00 U1/2
Fe SWA-LRef-1315-M07-A 1 1.00E+00 U1/2
Fe SWA-LRef-1315-M08-A 1 1.00E+00 U1/2
Fe SWA-LRef-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.72E+00 1.94 2.00 6.40
1.63E+01 2.85 2.00 6.40
5.46E+00 8.85 2.00 6.40 10000 1000
5.77E+00 1.41 2.00 6.40
4.42E+00 10.27 2.00 6.40
3.47E+00 1.29 2.00 6.40
5.29E+00 5.48 2.00 6.40
2.28E+00 9.49 2.00 6.40
2.57E+00 0.90 2.00 6.40
1.01E+01 2.30 2.00 6.40
9.74E+00 2.20 2.00 6.40
5.85E+00 5.19 2.00 6.40 10000 1000
5.36E+00 3.14 2.00 6.40
3.72E+00 6.15 2.00 6.40
3.64E+00 7.39 2.00 6.40
2.80E+00 10.93 2.00 6.40
1.00E+00 11.05 2.00 6.40
2.20E+00 8.90 2.00 6.40
5.95E+00 2.10 2.00 6.40
1.08E+01 0.31 2.00 6.40
5.87E+00 5.23 2.00 6.40 10000 1000
5.59E+00 3.91 2.00 6.40
1.14E+01 5.53 2.00 6.40
3.81 E+00 10.36 2.00 6.40
2.58E+00 5.10 2.00 6.40
2.14E+00 2.44 2.00 6.40
1.00E+00 2.77 2.00 6.40
1.00E+00 1.21 2.00 6.40
1.00E+00 22.19 2.00 6.40
1.00E+00 15.18 2.00 6.40
1.00E+00 10.05 2.00 6.40
1.00E+00 0.28 2.00 6.40
1.00E+00 2.41 2.00 6.40
1.00E+00 34.08 2.00 6.40
1.00E+00 13.42 2.00 6.40
1.00E+00 13.85 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.87E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.71 E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/14/11 4:17 PM EPA Interlab LRef 1315 SWA
3/14/11 4:19 PM EPA Interlab LRef 1315 SWA
3/14/11 4:20 PM EPA Interlab LRef 1315 SWA
3/14/11 4:22 PM EPA Interlab LRef 1315 SWA
3/14/11 4:24 PM EPA Interlab LRef 1315 SWA
3/14/11 4:25 PM EPA Interlab LRef 1315 SWA
3/14/11 4:27 PM EPA Interlab LRef 1315 SWA
3/14/11 4:28 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:30 PM EPA Interlab LRef 1315 SWA
3/14/11 4:32 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:33 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:35 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:37 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:38 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:40 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:42 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:43 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:45 PM EPA Interlab LRef 1315 SWA
3/15/11 10:28 AM EPA Interlab LRef 1315 SWA
3/15/11 10:30 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:32 AM EPA Interlab LRef 1315 SWA
3/15/11 10:33 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:35 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:37 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:38 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:40 AM EPA Interlab LRef 1315 SWA
3/15/11 10:41 AM EPA Interlab LRef 1315 SWA
3/14/11 2:57 PM EPA Interlab LRef 1315 SWA
3/14/11 3:30 PM EPA Interlab LRef 1315 SWA
3/14/11 2:58 PM EPA Interlab LRef 1315 SWA
3/14/11 3:00 PM EPA Interlab LRef 1315 SWA
3/14/11 3:01 PM EPA Interlab LRef 1315 SWA
3/14/11 3:24 PM EPA Interlab LRef 1315 SWA
3/14/11 3:25 PM EPA Interlab LRef 1315 SWA
3/14/11 3:27 PM EPA Interlab LRef 1315 SWA
3/14/11 3:29 PM EPA Interlab LRef 1315 SWA
1-711
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Pb SWA-LRef-1315-T01-A 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T02-A 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T03-A 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T04-A 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T05-A 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T06-A 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T07-A 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T08-A 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T09-A 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T01-B 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T02-B 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T03-B 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T04-B 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T05-B 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T06-B 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T07-B 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T08-B 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T09-B 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T01-C 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T02-C 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T03-C 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T04-C 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T05-C 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T06-C 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T07-C 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T08-C 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T09-C 1 3.40E+00 U1/2
Pb SWA-LRef-1315-M01-A 1 3.40E+00 U1/2
Pb SWA-LRef-1315-M02-A 1 3.40E+00 U1/2
Pb SWA-LRef-1315-M03-A 1 3.40E+00 U1/2
Pb SWA-LRef-1315-M04-A 1 3.40E+00 U1/2
Pb SWA-LRef-1315-M05-A 1 3.40E+00 U1/2
Pb SWA-LRef-1315-M06-A 1 3.40E+00 U1/2
Pb SWA-LRef-1315-M07-A 1 3.40E+00 U1/2
Pb SWA-LRef-1315-M08-A 1 3.40E+00 U1/2
Pb SWA-LRef-1315-M09-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 52.75 6.80 21.60
3.40E+00 48.69 6.80 21.60
3.40E+00 60.53 6.80 21.60 10000 1000
3.40E+00 15.00 6.80 21.60
3.40E+00 54.77 6.80 21.60
3.40E+00 9.32 6.80 21.60
3.40E+00 37.38 6.80 21.60
3.40E+00 38.27 6.80 21.60
3.40E+00 6.86 6.80 21.60
3.40E+00 44.83 6.80 21.60
3.40E+00 37.38 6.80 21.60
3.40E+00 76.09 6.80 21.60 10000 1000
3.40E+00 38.40 6.80 21.60
3.40E+00 63.53 6.80 21.60
3.40E+00 37.30 6.80 21.60
3.40E+00 35.31 6.80 21.60
3.40E+00 25.44 6.80 21.60
3.40E+00 77.18 6.80 21.60
3.40E+00 57.53 6.80 21.60
3.40E+00 12.17 6.80 21.60
3.40E+00 34.28 6.80 21.60 10000 1000
3.40E+00 31.57 6.80 21.60
3.40E+00 22.14 6.80 21.60
3.40E+00 46.73 6.80 21.60
3.40E+00 37.64 6.80 21.60
3.40E+00 28.84 6.80 21.60
3.40E+00 14.45 6.80 21.60
3.40E+00 11.56 6.80 21.60
3.40E+00 13.28 6.80 21.60
3.40E+00 35.36 6.80 21.60
3.40E+00 24.72 6.80 21.60
3.40E+00 31.88 6.80 21.60
3.40E+00 6.21 6.80 21.60
3.40E+00 23.31 6.80 21.60
3.40E+00 4.47 6.80 21.60
3.40E+00 15.72 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.72E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.90E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.52E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/14/11 4:17 PM EPA Interlab LRef 1315 SWA
3/14/11 4:19 PM EPA Interlab LRef 1315 SWA
3/14/11 4:20 PM EPA Interlab LRef 1315 SWA
3/14/11 4:22 PM EPA Interlab LRef 1315 SWA
3/14/11 4:24 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:25 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:27 PM EPA Interlab LRef 1315 SWA
3/14/11 4:28 PM EPA Interlab LRef 1315 SWA
3/14/11 4:30 PM EPA Interlab LRef 1315 SWA
3/14/11 4:32 PM EPA Interlab LRef 1315 SWA
3/14/11 4:33 PM EPA Interlab LRef 1315 SWA
3/14/11 4:35 PM EPA Interlab LRef 1315 SWA
3/14/11 4:37 PM EPA Interlab LRef 1315 SWA
3/14/11 4:38 PM EPA Interlab LRef 1315 SWA
3/14/11 4:40 PM EPA Interlab LRef 1315 SWA
3/14/11 4:42 PM EPA Interlab LRef 1315 SWA
3/14/11 4:43 PM EPA Interlab LRef 1315 SWA
3/14/11 4:45 PM EPA Interlab LRef 1315 SWA
3/15/11 10:28 AM EPA Interlab LRef 1315 SWA
3/15/11 10:30 AM EPA Interlab LRef 1315 SWA
3/15/11 10:32 AM EPA Interlab LRef 1315 SWA
3/15/11 10:33 AM EPA Interlab LRef 1315 SWA
3/15/11 10:35 AM EPA Interlab LRef 1315 SWA
3/15/11 10:37 AM EPA Interlab LRef 1315 SWA
3/15/11 10:38 AM EPA Interlab LRef 1315 SWA
3/15/11 10:40 AM EPA Interlab LRef 1315 SWA
3/15/11 10:41 AM EPA Interlab LRef 1315 SWA
3/14/11 2:57 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:30 PM EPA Interlab LRef 1315 SWA
3/14/1 1 2:58 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:00 PM EPA Interlab LRef 1315 SWA
3/14/11 3:01 PM EPA Interlab LRef 1315 SWA
3/14/11 3:24 PM EPA Interlab LRef 1315 SWA
3/14/11 3:25 PM EPA Interlab LRef 1315 SWA
3/14/11 3:27 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:29 PM EPA Interlab LRef 1315 SWA
1-712
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Li SWA-LRef-1315-T01-A 1 9.50E-01 U1/2
Li SWA-LRef-1315-T02-A 1 9.50E-01 U1/2
Li SWA-LRef-1315-T03-A 1 9.50E-01 U1/2
Li SWA-LRef-1315-T04-A 1 9.50E-01 U1/2
Li SWA-LRef-1315-T05-A 1 9.50E-01 U1/2
Li SWA-LRef-1315-T06-A 1 9.50E-01 U1/2
Li SWA-LRef-1315-T07-A 1 9.50E-01 U1/2
Li SWA-LRef-1315-T08-A 1 9.50E-01 U1/2
Li SWA-LRef-1315-T09-A 1 9.50E-01 U1/2
Li SWA-LRef-1315-T01-B 1 9.50E-01 U1/2
Li SWA-LRef-1315-T02-B 1 9.50E-01 U1/2
Li SWA-LRef-1315-T03-B 1 9.50E-01 U1/2
Li SWA-LRef-1315-T04-B 1 9.50E-01 U1/2
Li SWA-LRef-1315-T05-B 1 9.50E-01 U1/2
Li SWA-LRef-1315-T06-B 1 9.50E-01 U1/2
Li SWA-LRef-1315-T07-B 1 9.50E-01 U1/2
Li SWA-LRef-1315-T08-B 1 9.50E-01 U1/2
Li SWA-LRef-1315-T09-B 1 9.50E-01 U1/2
Li SWA-LRef-1315-T01-C 1 9.50E-01 U1/2
Li SWA-LRef-1315-T02-C 1 9.50E-01 U1/2
Li SWA-LRef-1315-T03-C 1 9.50E-01 U1/2
Li SWA-LRef-1315-T04-C 1 9.50E-01 U1/2
Li SWA-LRef-1315-T05-C 1 9.50E-01 U1/2
Li SWA-LRef-1315-T06-C 1 9.50E-01 U1/2
Li SWA-LRef-1315-T07-C 1 9.50E-01 U1/2
Li SWA-LRef-1315-T08-C 1 9.50E-01 U1/2
Li SWA-LRef-1315-T09-C 1 9.50E-01 U1/2
Li SWA-LRef-1315-M01-A 1 9.50E-01 U1/2
Li SWA-LRef-1315-M02-A 1 9.50E-01 U1/2
Li SWA-LRef-1315-M03-A 1 9.50E-01 U1/2
Li SWA-LRef-1315-M04-A 1 9.50E-01 U1/2
Li SWA-LRef-1315-M05-A 1 9.50E-01 U1/2
Li SWA-LRef-1315-M06-A 1 9.50E-01 U1/2
Li SWA-LRef-1315-M07-A 1 9.50E-01 U1/2
Li SWA-LRef-1315-M08-A 1 9.50E-01 U1/2
Li SWA-LRef-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 10.60 1.90 6.00
9.50E-01 60.45 1.90 6.00
9.50E-01 91.26 1.90 6.00 10000 1000
9.50E-01 22.61 1.90 6.00
9.50E-01 34.34 1.90 6.00
9.50E-01 58.21 1.90 6.00
9.50E-01 10.40 1.90 6.00
9.50E-01 50.15 1.90 6.00
9.50E-01 32.59 1.90 6.00
9.50E-01 38.72 1.90 6.00
9.50E-01 10.47 1.90 6.00
9.50E-01 74.58 1.90 6.00 10000 1000
9.50E-01 14.11 1.90 6.00
9.50E-01 12.45 1.90 6.00
9.50E-01 18.28 1.90 6.00
9.50E-01 44.41 1.90 6.00
9.50E-01 22.25 1.90 6.00
9.50E-01 3.44 1.90 6.00
9.50E-01 38.16 1.90 6.00
9.50E-01 56.92 1.90 6.00
9.50E-01 21.14 1.90 6.00 10000 1000
9.50E-01 16.20 1.90 6.00
9.50E-01 10.24 1.90 6.00
9.50E-01 3.49 1.90 6.00
9.50E-01 64.04 1.90 6.00
9.50E-01 30.56 1.90 6.00
9.50E-01 42.36 1.90 6.00
9.50E-01 19.02 1.90 6.00
9.50E-01 52.30 1.90 6.00
9.50E-01 21.18 1.90 6.00
9.50E-01 67.20 1.90 6.00
9.50E-01 50.48 1.90 6.00
9.50E-01 33.18 1.90 6.00
9.50E-01 50.30 1.90 6.00
9.50E-01 24.81 1.90 6.00
9.50E-01 43.77 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.83E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.87E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.76E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/3/11 1:12 PM EPA Interlab LRef 1315 SWA
11/3/11 1:14 PM EPA Interlab LRef 1315 SWA
11/3/11 1:15 PM EPA Interlab LRef 131 5 SWA
11/3/11 1:17 PM EPA Interlab LRef 131 5 SWA
11/3/11 1:19PM EPA Interlab LRef 131 5 SWA
11/3/11 1:20 PM EPA Interlab LRef 131 5 SWA
11/3/11 1:22 PM EPA Interlab LRef 131 5 SWA
11/3/11 1:24PM EPA Interlab LRef 1315 SWA
11/3/11 1:25 PM EPA Interlab LRef 1315 SWA
11/3/11 1:27 PM EPA Interlab LRef 1315 SWA
11/3/11 1:29 PM EPA Interlab LRef 1315 SWA
11/3/11 1:30 PM EPA Interlab LRef 1315 SWA
11/3/11 1:32 PM EPA Interlab LRef 1315 SWA
11/3/11 1:34 PM EPA Interlab LRef 1315 SWA
11/3/11 1:35 PM EPA Interlab LRef 1315 SWA
11/3/11 1:37 PM EPA Interlab LRef 1315 SWA
11/3/11 1:39 PM EPA Interlab LRef 1315 SWA
11/3/11 1:40 PM EPA Interlab LRef 1315 SWA
11/3/11 1:46 PM EPA Interlab LRef 1315 SWA
11/3/11 1:48 PM EPA Interlab LRef 1315 SWA
11/3/11 1:49 PM EPA Interlab LRef 1315 SWA
11/3/11 1:51 PM EPA Interlab LRef 1315 SWA
11/3/11 1:53 PM EPA Interlab LRef 1315 SWA
11/3/11 1:54 PM EPA Interlab LRef 1315 SWA
11/3/11 1:56 PM EPA Interlab LRef 1315 SWA
11/3/11 1:58 PM EPA Interlab LRef 1315 SWA
11/3/11 1:59 PM EPA Interlab LRef 1315 SWA
11/3/11 12:57 PM EPA Interlab LRef 1315 SWA
11/3/11 12:59 PM EPA Interlab LRef 1315 SWA
11/3/11 1:00 PM EPA Interlab LRef 1315 SWA
11/3/11 1:02 PM EPA Interlab LRef 1315 SWA
11/3/11 1:04 PM EPA Interlab LRef 1315 SWA
11/3/11 1:05 PM EPA Interlab LRef 1315 SWA
11/3/11 1:07 PM EPA Interlab LRef 1315 SWA
11/3/11 1:09 PM EPA Interlab LRef 1315 SWA
11/3/11 1:10 PM EPA Interlab LRef 1315 SWA
1-713
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Mn SWA-LRef-1315-T01-A 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T02-A 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T03-A 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T04-A 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T05-A 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T06-A 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T07-A 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T08-A 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T09-A 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T01-B 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T02-B 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T03-B 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T04-B 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T05-B 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T06-B 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T07-B 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T08-B 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T09-B 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T01-C 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T02-C 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T03-C 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T04-C 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T05-C 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T06-C 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T07-C 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T08-C 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T09-C 1 1.00E+00 U1/2
Mn SWA-LRef-1315-M01-A 1 1.00E+00 U1/2
Mn SWA-LRef-1315-M02-A 1 1.00E+00 U1/2
Mn SWA-LRef-1315-M03-A 1 1.00E+00 U1/2
Mn SWA-LRef-1315-M04-A 1 1.00E+00 U1/2
Mn SWA-LRef-1315-M05-A 1 1.00E+00 U1/2
Mn SWA-LRef-1315-M06-A 1 1.00E+00 U1/2
Mn SWA-LRef-1315-M07-A 1 1.00E+00 U1/2
Mn SWA-LRef-1315-M08-A 1 1.00E+00 U1/2
Mn SWA-LRef-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 9.68 2.00 6.40
1.00E+00 7.89 2.00 6.40
1.00E+00 12.24 2.00 6.40 10000 1000
1.00E+00 5.86 2.00 6.40
1.00E+00 3.21 2.00 6.40
1.00E+00 15.66 2.00 6.40
1.00E+00 10.32 2.00 6.40
1.00E+00 13.21 2.00 6.40
1.00E+00 0.23 2.00 6.40
1.00E+00 10.18 2.00 6.40
1.00E+00 9.64 2.00 6.40
1.00E+00 3.45 2.00 6.40 10000 1000
1.00E+00 21.08 2.00 6.40
1.00E+00 2.30 2.00 6.40
1.00E+00 10.78 2.00 6.40
1.00E+00 27.18 2.00 6.40
1.00E+00 34.11 2.00 6.40
1.00E+00 4.65 2.00 6.40
1.00E+00 13.94 2.00 6.40
1.00E+00 4.51 2.00 6.40
1.00E+00 14.36 2.00 6.40 10000 1000
1.00E+00 12.73 2.00 6.40
1.00E+00 11.33 2.00 6.40
1.00E+00 18.28 2.00 6.40
1.00E+00 5.51 2.00 6.40
1.00E+00 13.26 2.00 6.40
1.00E+00 6.29 2.00 6.40
1.00E+00 9.58 2.00 6.40
1.00E+00 28.15 2.00 6.40
1.00E+00 16.14 2.00 6.40
1.00E+00 6.68 2.00 6.40
1.00E+00 3.55 2.00 6.40
1.00E+00 5.83 2.00 6.40
1.00E+00 10.13 2.00 6.40
1.00E+00 18.75 2.00 6.40
1.00E+00 14.84 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.85E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.95E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.56E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/14/11 4:17 PM EPA Interlab LRef 1315 SWA
3/14/11 4:19 PM EPA Interlab LRef 1315 SWA
3/14/11 4:20 PM EPA Interlab LRef 1315 SWA
3/14/11 4:22 PM EPA Interlab LRef 1315 SWA
3/14/11 4:24 PM EPA Interlab LRef 1315 SWA
3/14/11 4:25 PM EPA Interlab LRef 1315 SWA
3/14/11 4:27 PM EPA Interlab LRef 1315 SWA
3/14/11 4:28 PM EPA Interlab LRef 1315 SWA
3/14/11 4:30 PM EPA Interlab LRef 1315 SWA
3/14/11 4:32 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:33 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:35 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:37 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:38 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:40 PM EPA Interlab LRef 1315 SWA
3/14/11 4:42 PM EPA Interlab LRef 1315 SWA
3/14/11 4:43 PM EPA Interlab LRef 1315 SWA
3/14/11 4:45 PM EPA Interlab LRef 1315 SWA
3/15/11 10:28 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:30 AM EPA Interlab LRef 1315 SWA
3/15/11 10:32 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:33 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:35 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:37 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:38 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:40 AM EPA Interlab LRef 1315 SWA
3/15/11 10:41 AM EPA Interlab LRef 1315 SWA
3/14/11 2:57 PM EPA Interlab LRef 1315 SWA
3/14/11 3:30 PM EPA Interlab LRef 1315 SWA
3/14/11 2:58 PM EPA Interlab LRef 1315 SWA
3/14/11 3:00 PM EPA Interlab LRef 1315 SWA
3/14/11 3:01 PM EPA Interlab LRef 1315 SWA
3/14/11 3:24 PM EPA Interlab LRef 1315 SWA
3/14/11 3:25 PM EPA Interlab LRef 1315 SWA
3/14/11 3:27 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:29 PM EPA Interlab LRef 1315 SWA
1-714
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Mg SWA-LRef-1315-T01-A 1 4.59E+00
Mg SWA-LRef-1315-T02-A 1 2.37E+01
Mg SWA-LRef-1315-T03-A 1 2.65E+01
Mg SWA-LRef-1315-T04-A 1 2.09E+01
Mg SWA-LRef-1315-T05-A 1 2.26E+01
Mg SWA-LRef-1315-T06-A 1 1.71E+01
Mg SWA-LRef-1315-T07-A 1 9.08E+00
Mg SWA-LRef-1315-T08-A 1 5.32E+01
Mg SWA-LRef-1315-T09-A 1 2.81E+01
Mg SWA-LRef-1315-T01-B 1 3.77E+00
Mg SWA-LRef-1315-T02-B 1 1.78E+01
Mg SWA-LRef-1315-T03-B 1 3.46E+01
Mg SWA-LRef-1315-T04-B 1 2.42E+01
Mg SWA-LRef-1315-T05-B 1 2.41 E+01
Mg SWA-LRef-1315-T06-B 1 1.05E+01
Mg SWA-LRef-1315-T07-B 1 2.50E+01
Mg SWA-LRef-1315-T08-B 1 6.31E+01
Mg SWA-LRef-1315-T09-B 1 2.57E+01
Mg SWA-LRef-1315-T01-C 1 1.85E+00 E
Mg SWA-LRef-1315-T02-C 1 1.59E+01
Mg SWA-LRef-1315-T03-C 1 2.83E+01
Mg SWA-LRef-1315-T04-C 1 1.15E+01
Mg SWA-LRef-1315-T05-C 1 3.40E+01
Mg SWA-LRef-1315-T06-C 1 2.26E+01
Mg SWA-LRef-1315-T07-C 1 1.22E+01
Mg SWA-LRef-1315-T08-C 1 6.50E+01
Mg SWA-LRef-1315-T09-C 1 2.46E+01
Mg SWA-LRef-1315-M01-A 1 2.33E+00 E
Mg SWA-LRef-1315-M02-A 1 4.62E+00
Mg SWA-LRef-1315-M03-A 1 1.71E+00 E
Mg SWA-LRef-1315-M04-A 1 2.22E+00 E
Mg SWA-LRef-1315-M05-A 1 2.19E+00 E
Mg SWA-LRef-1315-M06-A 1 2.46E+00 E
Mg SWA-LRef-1315-M07-A 1 1.21E+00 E
Mg SWA-LRef-1315-M08-A 1 3.36E+00
Mg SWA-LRef-1315-M09-A 1 2.79E+00 E
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.59E+00 1.88 1.00 3.18
2.37E+01 4.09 1.00 3.18
2.65E+01 11.17 1.00 3.18 10000 1000
2.09E+01 1.99 1.00 3.18
2.26E+01 1.50 1.00 3.18
1.71E+01 8.70 1.00 3.18
9.08E+00 7.41 1.00 3.18
5.32E+01 1.02 1.00 3.18
2.81E+01 1.05 1.00 3.18
3.77E+00 9.93 1.00 3.18
1.78E+01 1.01 1.00 3.18
3.46E+01 2.32 1.00 3.18 10000 1000
2.42E+01 5.06 1.00 3.18
2.41E+01 5.53 1.00 3.18
1.05E+01 1.49 1.00 3.18
2.50E+01 8.67 1.00 3.18
6.31E+01 4.26 1.00 3.18
2.57E+01 1.47 1.00 3.18
1.85E+00 18.43 1.00 3.18
1.59E+01 3.62 1.00 3.18
2.83E+01 6.39 1.00 3.18 10000 1000
1.15E+01 9.60 1.00 3.18
3.40E+01 6.03 1.00 3.18
2.26E+01 8.76 1.00 3.18
1.22E+01 3.65 1.00 3.18
6.50E+01 7.69 1.00 3.18
2.46E+01 1.78 1.00 3.18
2.33E+00 3.49 1.00 3.18
4.62E+00 2.10 1.00 3.18
1.71E+00 4.14 1.00 3.18
2.22E+00 3.03 1.00 3.18
2.19E+00 3.15 1.00 3.18
2.46E+00 14.89 1.00 3.18
1.21E+00 3.68 1.00 3.18
3.36E+00 3.42 1.00 3.18
2.79E+00 3.90 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.74E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.62E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/14/11 4:17 PM EPA Interlab LRef 1315 SWA
3/14/11 4:19 PM EPA Interlab LRef 1315 SWA
3/14/11 4:20 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:22 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:24 PM EPA Interlab LRef 1315 SWA
3/14/11 4:25 PM EPA Interlab LRef 1315 SWA
3/14/11 4:27 PM EPA Interlab LRef 1315 SWA
3/14/11 4:28 PM EPA Interlab LRef 1315 SWA
3/14/11 4:30 PM EPA Interlab LRef 1315 SWA
3/14/11 4:32 PM EPA Interlab LRef 1315 SWA
3/14/11 4:33 PM EPA Interlab LRef 1315 SWA
3/14/11 4:35 PM EPA Interlab LRef 1315 SWA
3/14/11 4:37 PM EPA Interlab LRef 1315 SWA
3/14/11 4:38 PM EPA Interlab LRef 1315 SWA
3/14/11 4:40 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:42 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:43 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:45 PM EPA Interlab LRef 1315 SWA
3/15/11 10:28 AM EPA Interlab LRef 1315 SWA
3/15/11 10:30 AM EPA Interlab LRef 1315 SWA
3/15/11 10:32 AM EPA Interlab LRef 1315 SWA
3/15/11 10:33 AM EPA Interlab LRef 1315 SWA
3/15/11 10:35 AM EPA Interlab LRef 1315 SWA
3/15/11 10:37 AM EPA Interlab LRef 1315 SWA
3/15/11 10:38 AM EPA Interlab LRef 1315 SWA
3/15/11 10:40 AM EPA Interlab LRef 1315 SWA
3/15/11 10:41 AM EPA Interlab LRef 1315 SWA
3/14/1 1 2:57 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:30 PM EPA Interlab LRef 1315 SWA
3/14/1 1 2:58 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:00 PM EPA Interlab LRef 1315 SWA
3/14/11 3:01 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:24 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:25 PM EPA Interlab LRef 1315 SWA
3/14/11 3:27 PM EPA Interlab LRef 1315 SWA
3/14/11 3:29 PM EPA Interlab LRef 1315 SWA
1-715
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Mo SWA-LRef-1315-T01-A 1 3.80E+00 E
Mo SWA-LRef-1315-T02-A 1 4.59E+00
Mo SWA-LRef-1315-T03-A 1 3.69E+00 E
Mo SWA-LRef-1315-T04-A 1 6.79E+00
Mo SWA-LRef-1315-T05-A 1 4.52E+00
Mo SWA-LRef-1315-T06-A 1 7.77E+00
Mo SWA-LRef-1315-T07-A 1 6.10E+00
Mo SWA-LRef-1315-T08-A 1 3.16E+00 E
Mo SWA-LRef-1315-T09-A 1 5.36E+00
Mo SWA-LRef-1315-T01-B 1 2.90E+00 E
Mo SWA-LRef-1315-T02-B 1 4.46E+00
Mo SWA-LRef-1315-T03-B 1 3.85E+00
Mo SWA-LRef-1315-T04-B 1 6.89E+00
Mo SWA-LRef-1315-T05-B 1 4.01E+00
Mo SWA-LRef-1315-T06-B 1 8.82E+00
Mo SWA-LRef-1315-T07-B 1 5.04E+00
Mo SWA-LRef-1315-T08-B 1 3.01E+00 E
Mo SWA-LRef-1315-T09-B 1 5.30E+00
Mo SWA-LRef-1315-T01-C 1 1.55E+00 E
Mo SWA-LRef-1315-T02-C 1 4.91E+00
Mo SWA-LRef-1315-T03-C 1 3.52E+00 E
Mo SWA-LRef-1315-T04-C 1 6.45E+00
Mo SWA-LRef-1315-T05-C 1 5.02E+00
Mo SWA-LRef-1315-T06-C 1 8.94E+00
Mo SWA-LRef-1315-T07-C 1 6.26E+00
Mo SWA-LRef-1315-T08-C 1 3.03E+00 E
Mo SWA-LRef-1315-T09-C 1 4.33E+00
Mo SWA-LRef-1315-M01-A 1 6.00E-01 U1/2
Mo SWA-LRef-1315-M02-A 1 6.00E-01 U1/2
Mo SWA-LRef-1315-M03-A 1 6.00E-01 U1/2
Mo SWA-LRef-1315-M04-A 1 6.00E-01 U1/2
Mo SWA-LRef-1315-M05-A 1 6.00E-01 U1/2
Mo SWA-LRef-1315-M06-A 1 6.00E-01 U1/2
Mo SWA-LRef-1315-M07-A 1 6.00E-01 U1/2
Mo SWA-LRef-1315-M08-A 1 6.00E-01 U1/2
Mo SWA-LRef-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.80E+00 14.53 1.20 3.82
4.59E+00 3.35 1.20 3.82
3.69E+00 15.84 1.20 3.82 10000 1000
6.79E+00 5.53 1.20 3.82
4.52E+00 1.73 1.20 3.82
7.77E+00 1.35 1.20 3.82
6.10E+00 14.35 1.20 3.82
3.16E+00 22.13 1.20 3.82
5.36E+00 3.51 1.20 3.82
2.90E+00 12.81 1.20 3.82
4.46E+00 1.20 1.20 3.82
3.85E+00 3.50 1.20 3.82 10000 1000
6.89E+00 1.07 1.20 3.82
4.01E+00 1.31 1.20 3.82
8.82E+00 1.70 1.20 3.82
5.04E+00 2.29 1.20 3.82
3.01E+00 26.87 1.20 3.82
5.30E+00 12.30 1.20 3.82
1.55E+00 15.50 1.20 3.82
4.91E+00 9.67 1.20 3.82
3.52E+00 3.04 1.20 3.82 10000 1000
6.45E+00 2.28 1.20 3.82
5.02E+00 1.54 1.20 3.82
8.94E+00 6.71 1.20 3.82
6.26E+00 3.96 1.20 3.82
3.03E+00 2.04 1.20 3.82
4.33E+00 2.86 1.20 3.82
6.00E-01 29.59 1.20 3.82
6.00E-01 24.23 1.20 3.82
6.00E-01 47.46 1.20 3.82
6.00E-01 1.91 1.20 3.82
6.00E-01 6.03 1.20 3.82
6.00E-01 8.93 1.20 3.82
6.00E-01 15.56 1.20 3.82
6.00E-01 41.91 1.20 3.82
6.00E-01 5.47 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.77E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.56E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/14/11 4:17 PM EPA Interlab LRef 1315 SWA
3/14/11 4:19 PM EPA Interlab LRef 1315 SWA
3/14/11 4:20 PM EPA Interlab LRef 1315 SWA
3/14/11 4:22 PM EPA Interlab LRef 1315 SWA
3/14/11 4:24 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:25 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:27 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:28 PM EPA Interlab LRef 1315 SWA
3/14/11 4:30 PM EPA Interlab LRef 1315 SWA
3/14/11 4:32 PM EPA Interlab LRef 1315 SWA
3/14/11 4:33 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:35 PM EPA Interlab LRef 1315 SWA
3/14/11 4:37 PM EPA Interlab LRef 1315 SWA
3/14/11 4:38 PM EPA Interlab LRef 1315 SWA
3/14/11 4:40 PM EPA Interlab LRef 1315 SWA
3/14/11 4:42 PM EPA Interlab LRef 1315 SWA
3/14/11 4:43 PM EPA Interlab LRef 1315 SWA
3/14/11 4:45 PM EPA Interlab LRef 1315 SWA
3/15/11 10:28 AM EPA Interlab LRef 1315 SWA
3/15/11 10:30 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:32 AM EPA Interlab LRef 1315 SWA
3/15/11 10:33 AM EPA Interlab LRef 1315 SWA
3/15/11 10:35 AM EPA Interlab LRef 1315 SWA
3/15/11 10:37 AM EPA Interlab LRef 1315 SWA
3/15/11 10:38 AM EPA Interlab LRef 1315 SWA
3/15/11 10:40 AM EPA Interlab LRef 1315 SWA
3/15/11 10:41 AM EPA Interlab LRef 1315 SWA
3/14/11 2:57 PM EPA Interlab LRef 1315 SWA
3/14/11 3:30 PM EPA Interlab LRef 1315 SWA
3/14/11 2:58 PM EPA Interlab LRef 1315 SWA
3/14/11 3:00 PM EPA Interlab LRef 1315 SWA
3/14/11 3:01 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:24 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:25 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:27 PM EPA Interlab LRef 1315 SWA
3/14/11 3:29 PM EPA Interlab LRef 1315 SWA
1-716
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ni SWA-LRef-1315-T01-A 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T02-A 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T03-A 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T04-A 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T05-A 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T06-A 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T07-A 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T08-A 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T09-A 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T01-B 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T02-B 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T03-B 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T04-B 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T05-B 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T06-B 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T07-B 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T08-B 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T09-B 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T01-C 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T02-C 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T03-C 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T04-C 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T05-C 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T06-C 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T07-C 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T08-C 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T09-C 1 9.00E-01 U1/2
Ni SWA-LRef-1315-M01-A 1 9.00E-01 U1/2
Ni SWA-LRef-1315-M02-A 1 9.00E-01 U1/2
Ni SWA-LRef-1315-M03-A 1 9.00E-01 U1/2
Ni SWA-LRef-1315-M04-A 1 9.00E-01 U1/2
Ni SWA-LRef-1315-M05-A 1 9.00E-01 U1/2
Ni SWA-LRef-1315-M06-A 1 9.00E-01 U1/2
Ni SWA-LRef-1315-M07-A 1 9.00E-01 U1/2
Ni SWA-LRef-1315-M08-A 1 9.00E-01 U1/2
Ni SWA-LRef-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 69.60 1.80 5.70
9.00E-01 10.65 1.80 5.70
9.00E-01 50.56 1.80 5.70 10000 1000
9.00E-01 33.69 1.80 5.70
9.00E-01 71.48 1.80 5.70
9.00E-01 21.75 1.80 5.70
9.00E-01 57.43 1.80 5.70
9.00E-01 18.05 1.80 5.70
9.00E-01 12.55 1.80 5.70
9.00E-01 28.82 1.80 5.70
9.00E-01 37.36 1.80 5.70
9.00E-01 72.97 1.80 5.70 10000 1000
9.00E-01 53.94 1.80 5.70
9.00E-01 31.63 1.80 5.70
9.00E-01 36.71 1.80 5.70
9.00E-01 28.54 1.80 5.70
9.00E-01 33.03 1.80 5.70
9.00E-01 30.07 1.80 5.70
9.00E-01 48.64 1.80 5.70
9.00E-01 27.94 1.80 5.70
9.00E-01 11.48 1.80 5.70 10000 1000
9.00E-01 1.97 1.80 5.70
9.00E-01 40.17 1.80 5.70
9.00E-01 9.41 1.80 5.70
9.00E-01 24.85 1.80 5.70
9.00E-01 33.85 1.80 5.70
9.00E-01 60.20 1.80 5.70
9.00E-01 25.09 1.80 5.70
9.00E-01 27.34 1.80 5.70
9.00E-01 33.16 1.80 5.70
9.00E-01 27.22 1.80 5.70
9.00E-01 33.54 1.80 5.70
9.00E-01 10.68 1.80 5.70
9.00E-01 20.56 1.80 5.70
9.00E-01 8.17 1.80 5.70
9.00E-01 29.18 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.75E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.48E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/14/11 4:17 PM EPA Interlab LRef 1315 SWA
3/14/11 4:19 PM EPA Interlab LRef 1315 SWA
3/14/11 4:20 PM EPA Interlab LRef 1315 SWA
3/14/11 4:22 PM EPA Interlab LRef 1315 SWA
3/14/11 4:24 PM EPA Interlab LRef 1315 SWA
3/14/11 4:25 PM EPA Interlab LRef 1315 SWA
3/14/11 4:27 PM EPA Interlab LRef 1315 SWA
3/14/11 4:28 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:30 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:32 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:33 PM EPA Interlab LRef 1315 SWA
3/14/11 4:35 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:37 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:38 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:40 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:42 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:43 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:45 PM EPA Interlab LRef 1315 SWA
3/15/11 10:28 AM EPA Interlab LRef 1315 SWA
3/15/11 10:30 AM EPA Interlab LRef 1315 SWA
3/15/11 10:32 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:33 AM EPA Interlab LRef 1315 SWA
3/15/11 10:35 AM EPA Interlab LRef 1315 SWA
3/15/11 10:37 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:38 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:40 AM EPA Interlab LRef 1315 SWA
3/15/11 10:41 AM EPA Interlab LRef 1315 SWA
3/14/11 2:57 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:30 PM EPA Interlab LRef 1315 SWA
3/14/11 2:58 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:00 PM EPA Interlab LRef 1315 SWA
3/14/11 3:01 PM EPA Interlab LRef 1315 SWA
3/14/11 3:24 PM EPA Interlab LRef 1315 SWA
3/14/11 3:25 PM EPA Interlab LRef 1315 SWA
3/14/11 3:27 PM EPA Interlab LRef 1315 SWA
3/14/11 3:29 PM EPA Interlab LRef 1315 SWA
1-717
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
P SWA-LRef-1315-T01-A 1 1.85E+00 U1/2
P SWA-LRef-1315-T02-A 1 1.85E+00 U1/2
P SWA-LRef-1315-T03-A 1 1.85E+00 U1/2
P SWA-LRef-1315-T04-A 1 1.85E+00 U1/2
P SWA-LRef-1315-T05-A 1 1.85E+00 U1/2
P SWA-LRef-1315-T06-A 1 1.85E+00 U1/2
P SWA-LRef-1315-T07-A 1 1.85E+00 U1/2
P SWA-LRef-1315-T08-A 1 1.85E+00 U1/2
P SWA-LRef-1315-T09-A 1 1.85E+00 U1/2
P SWA-LRef-1315-T01-B 1 1.85E+00 U1/2
P SWA-LRef-1315-T02-B 1 1.85E+00 U1/2
P SWA-LRef-1315-T03-B 1 1.85E+00 U1/2
P SWA-LRef-1315-T04-B 1 1.85E+00 U1/2
P SWA-LRef-1315-T05-B 1 1.85E+00 U1/2
P SWA-LRef-1315-T06-B 1 1.85E+00 U1/2
P SWA-LRef-1315-T07-B 1 1.85E+00 U1/2
P SWA-LRef-1315-T08-B 1 1.85E+00 U1/2
P SWA-LRef-1315-T09-B 1 1.85E+00 U1/2
P SWA-LRef-1315-T01-C 1 1.85E+00 U1/2
P SWA-LRef-1315-T02-C 1 1.85E+00 U1/2
P SWA-LRef-1315-T03-C 1 1.85E+00 U1/2
P SWA-LRef-1315-T04-C 1 1.85E+00 U1/2
P SWA-LRef-1315-T05-C 1 1.85E+00 U1/2
P SWA-LRef-1315-T06-C 1 1.85E+00 U1/2
P SWA-LRef-1315-T07-C 1 1.85E+00 U1/2
P SWA-LRef-1315-T08-C 1 1.85E+00 U1/2
P SWA-LRef-1315-T09-C 1 1.85E+00 U1/2
P SWA-LRef-1315-M01-A 1 1.85E+00 U1/2
P SWA-LRef-1315-M02-A 1 1.85E+00 U1/2
P SWA-LRef-1315-M03-A 1 1.85E+00 U1/2
P SWA-LRef-1315-M04-A 1 1.85E+00 U1/2
P SWA-LRef-1315-M05-A 1 1.85E+00 U1/2
P SWA-LRef-1315-M06-A 1 1.85E+00 U1/2
P SWA-LRef-1315-M07-A 1 1.85E+00 U1/2
P SWA-LRef-1315-M08-A 1 1.85E+00 U1/2
P SWA-LRef-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 39.16 3.70 11.80
1.85E+00 13.67 3.70 11.80
1.85E+00 35.72 3.70 11.80 10000 1000
1.85E+00 11.79 3.70 11.80
1.85E+00 51.36 3.70 11.80
1.85E+00 50.69 3.70 11.80
1.85E+00 58.17 3.70 11.80
1.85E+00 16.22 3.70 11.80
1.85E+00 4.40 3.70 11.80
1.85E+00 30.44 3.70 11.80
1.85E+00 37.78 3.70 11.80
1.85E+00 26.17 3.70 11.80 10000 1000
1.85E+00 6.28 3.70 11.80
1.85E+00 22.97 3.70 11.80
1.85E+00 25.57 3.70 11.80
1.85E+00 32.72 3.70 11.80
1.85E+00 68.93 3.70 11.80
1.85E+00 38.18 3.70 11.80
1.85E+00 64.36 3.70 11.80
1.85E+00 16.19 3.70 11.80
1.85E+00 26.17 3.70 11.80 10000 1000
1.85E+00 11.41 3.70 11.80
1.85E+00 53.90 3.70 11.80
1.85E+00 38.13 3.70 11.80
1.85E+00 24.28 3.70 11.80
1.85E+00 28.16 3.70 11.80
1.85E+00 55.16 3.70 11.80
1.85E+00 24.13 3.70 11.80
1.85E+00 11.94 3.70 11.80
1.85E+00 15.26 3.70 11.80
1.85E+00 23.89 3.70 11.80
1.85E+00 36.01 3.70 11.80
1.85E+00 16.33 3.70 11.80
1.85E+00 18.07 3.70 11.80
1.85E+00 21.34 3.70 11.80
1.85E+00 86.31 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.81 E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/14/11 4:17 PM EPA Interlab LRef 1315 SWA
3/14/11 4:19 PM EPA Interlab LRef 1315 SWA
3/14/11 4:20 PM EPA Interlab LRef 1315 SWA
3/14/11 4:22 PM EPA Interlab LRef 1315 SWA
3/14/11 4:24 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:25 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:27 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:28 PM EPA Interlab LRef 1315 SWA
3/14/11 4:30 PM EPA Interlab LRef 1315 SWA
3/14/11 4:32 PM EPA Interlab LRef 1315 SWA
3/14/11 4:33 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:35 PM EPA Interlab LRef 1315 SWA
3/14/11 4:37 PM EPA Interlab LRef 1315 SWA
3/14/11 4:38 PM EPA Interlab LRef 1315 SWA
3/14/11 4:40 PM EPA Interlab LRef 1315 SWA
3/14/11 4:42 PM EPA Interlab LRef 1315 SWA
3/14/11 4:43 PM EPA Interlab LRef 1315 SWA
3/14/11 4:45 PM EPA Interlab LRef 1315 SWA
3/15/11 10:28 AM EPA Interlab LRef 1315 SWA
3/15/11 10:30 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:32 AM EPA Interlab LRef 1315 SWA
3/15/11 10:33 AM EPA Interlab LRef 1315 SWA
3/15/11 10:35 AM EPA Interlab LRef 1315 SWA
3/15/11 10:37 AM EPA Interlab LRef 1315 SWA
3/15/11 10:38 AM EPA Interlab LRef 1315 SWA
3/15/11 10:40 AM EPA Interlab LRef 1315 SWA
3/15/11 10:41 AM EPA Interlab LRef 1315 SWA
3/14/11 2:57 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:30 PM EPA Interlab LRef 1315 SWA
3/14/1 1 2:58 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:00 PM EPA Interlab LRef 1315 SWA
3/14/11 3:01 PM EPA Interlab LRef 1315 SWA
3/14/11 3:24 PM EPA Interlab LRef 1315 SWA
3/14/11 3:25 PM EPA Interlab LRef 1315 SWA
3/14/11 3:27 PM EPA Interlab LRef 1315 SWA
3/14/11 3:29 PM EPA Interlab LRef 1315 SWA
1-718
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
K SWA-LRef-1315-T01-A 1 8.45E+03
K SWA-LRef-1315-T02-A 1 2.56E+04
K SWA-LRef-1315-T03-A 1 1.52E+04
K SWA-LRef-1315-T04-A 1 3.86E+04
K SWA-LRef-1315-T05-A 1 2.99E+04
K SWA-LRef-1315-T06-A 1 3.38E+04
K SWA-LRef-1315-T07-A 1 2.30E+04
K SWA-LRef-1315-T08-A 1 8.97E+03
K SWA-LRef-1315-T09-A 1 1.48E+04
K SWA-LRef-1315-T01-B 1 8.00E+03
K SWA-LRef-1315-T02-B 1 2.42E+04
K SWA-LRef-1315-T03-B 1 1.66E+04
K SWA-LRef-1315-T04-B 1 3.89E+04
K SWA-LRef-1315-T05-B 1 2.86E+04
K SWA-LRef-1315-T06-B 1 3.30E+04
K SWA-LRef-1315-T07-B 1 2.25E+04
K SWA-LRef-1315-T08-B 1 8.95E+03
K SWA-LRef-1315-T09-B 1 1.44E+04
K SWA-LRef-1315-T01-C 1 6.40E+03
K SWA-LRef-1315-T02-C 1 2.51E+04
K SWA-LRef-1315-T03-C 1 1.70E+04
K SWA-LRef-1315-T04-C 1 3.80E+04
K SWA-LRef-1315-T05-C 1 2.93E+04
K SWA-LRef-1315-T06-C 1 3.23E+04
K SWA-LRef-1315-T07-C 1 2.19E+04
K SWA-LRef-1315-T08-C 1 8.77E+03
K SWA-LRef-1315-T09-C 1 1.36E+04
K SWA-LRef-1315-M01-A 1 5.73E+01
K SWA-LRef-1315-M02-A 1 3.95E+01
K SWA-LRef-1315-M03-A 1 4.62E+01
K SWA-LRef-1315-M04-A 1 4.40E+01
K SWA-LRef-1315-M05-A 1 4.79E+01
K SWA-LRef-1315-M06-A 1 3.25E+01
K SWA-LRef-1315-M07-A 1 2.18E+01
K SWA-LRef-1315-M08-A 1 4.39E+01
K SWA-LRef-1315-M09-A 1 4.76E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.45E+03 0.69 1.60 5.09
2.56E+04 0.69 1.60 5.09
1.52E+04 0.64 1.60 5.09 10000 1000
3.86E+04 0.79 1.60 5.09
2.99E+04 1.55 1.60 5.09
3.38E+04 0.34 1.60 5.09
2.30E+04 0.25 1.60 5.09
8.97E+03 0.51 1.60 5.09
1.48E+04 0.39 1.60 5.09
8.00E+03 0.39 1.60 5.09
2.42E+04 0.53 1.60 5.09
1.66E+04 0.69 1.60 5.09 10000 1000
3.89E+04 0.29 1.60 5.09
2.86E+04 0.85 1.60 5.09
3.30E+04 0.80 1.60 5.09
2.25E+04 0.25 1.60 5.09
8.95E+03 0.45 1.60 5.09
1.44E+04 0.87 1.60 5.09
6.40E+03 0.62 1.60 5.09
2.51E+04 0.78 1.60 5.09
1.70E+04 0.87 1.60 5.09 10000 1000
3.80E+04 0.57 1.60 5.09
2.93E+04 1.11 1.60 5.09
3.23E+04 0.83 1.60 5.09
2.19E+04 1.06 1.60 5.09
8.77E+03 0.79 1.60 5.09
1.36E+04 0.50 1.60 5.09
5.73E+01 5.14 1.60 5.09
3.95E+01 1.23 1.60 5.09
4.62E+01 0.85 1.60 5.09
4.40E+01 3.09 1.60 5.09
4.79E+01 5.87 1.60 5.09
3.25E+01 0.67 1.60 5.09
2.18E+01 1.31 1.60 5.09
4.39E+01 9.11 1.60 5.09
4.76E+01 3.98 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.61E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.76E+04 91 % VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.80E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/14/11 4:17 PM EPA Interlab LRef 1315 SWA
3/14/11 4:19 PM EPA Interlab LRef 1315 SWA
3/14/11 4:20 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:22 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:24 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:25 PM EPA Interlab LRef 1315 SWA
3/14/11 4:27 PM EPA Interlab LRef 1315 SWA
3/14/11 4:28 PM EPA Interlab LRef 1315 SWA
3/14/11 4:30 PM EPA Interlab LRef 1315 SWA
3/14/11 4:32 PM EPA Interlab LRef 1315 SWA
3/14/11 4:33 PM EPA Interlab LRef 1315 SWA
3/14/11 4:35 PM EPA Interlab LRef 1315 SWA
3/14/11 4:37 PM EPA Interlab LRef 1315 SWA
3/14/11 4:38 PM EPA Interlab LRef 1315 SWA
3/14/11 4:40 PM EPA Interlab LRef 1315 SWA
3/14/11 4:42 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:43 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:45 PM EPA Interlab LRef 1315 SWA
3/15/11 10:28 AM EPA Interlab LRef 1315 SWA
3/15/11 10:30 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:32 AM EPA Interlab LRef 1315 SWA
3/15/11 10:33 AM EPA Interlab LRef 1315 SWA
3/15/11 10:35 AM EPA Interlab LRef 1315 SWA
3/15/11 10:37 AM EPA Interlab LRef 1315 SWA
3/15/11 10:38 AM EPA Interlab LRef 1315 SWA
3/15/11 10:40 AM EPA Interlab LRef 1315 SWA
3/15/11 10:41 AM EPA Interlab LRef 1315 SWA
3/14/11 2:57 PM EPA Interlab LRef 1315 SWA
3/14/11 3:30 PM EPA Interlab LRef 1315 SWA
3/14/11 2:58 PM EPA Interlab LRef 1315 SWA
3/14/11 3:00 PM EPA Interlab LRef 1315 SWA
3/14/11 3:01 PM EPA Interlab LRef 1315 SWA
3/14/11 3:24 PM EPA Interlab LRef 1315 SWA
3/14/11 3:25 PM EPA Interlab LRef 1315 SWA
3/14/11 3:27 PM EPA Interlab LRef 1315 SWA
3/14/11 3:29 PM EPA Interlab LRef 1315 SWA
1-719
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Se SWA-LRef-1315-T01-A 1 1.55E+03
Se SWA-LRef-1315-T02-A 1 5.05E+03
Se SWA-LRef-1315-T03-A 1 2.58E+03
Se SWA-LRef-1315-T04-A 1 5.28E+03
Se SWA-LRef-1315-T05-A 1 3.24E+03
Se SWA-LRef-1315-T06-A 1 3.39E+03
Se SWA-LRef-1315-T07-A 1 1.96E+03
Se SWA-LRef-1315-T08-A 1 7.50E+02
Se SWA-LRef-1315-T09-A 1 1.14E+03
Se SWA-LRef-1315-T01-B 1 1.60E+03
Se SWA-LRef-1315-T02-B 1 5.12E+03
Se SWA-LRef-1315-T03-B 1 2.55E+03
Se SWA-LRef-1315-T04-B 1 5.22E+03
Se SWA-LRef-1315-T05-B 1 3.03E+03
Se SWA-LRef-1315-T06-B 1 3.62E+03
Se SWA-LRef-1315-T07-B 1 1.96E+03
Se SWA-LRef-1315-T08-B 1 7.54E+02
Se SWA-LRef-1315-T09-B 1 1.28E+03
Se SWA-LRef-1315-T01-C 1 1.43E+03
Se SWA-LRef-1315-T02-C 1 5.31E+03
Se SWA-LRef-1315-T03-C 1 2.51E+03
Se SWA-LRef-1315-T04-C 1 5.57E+03
Se SWA-LRef-1315-T05-C 1 3.14E+03
Se SWA-LRef-1315-T06-C 1 3.71E+03
Se SWA-LRef-1315-T07-C 1 2.05E+03
Se SWA-LRef-1315-T08-C 1 7.58E+02
Se SWA-LRef-1315-T09-C 1 1.21E+03
Se SWA-LRef-1315-M01-A 1 7.50E+00 U1/2
Se SWA-LRef-1315-M02-A 1 7.50E+00 U1/2
Se SWA-LRef-1315-M03-A 1 7.50E+00 U1/2
Se SWA-LRef-1315-M04-A 1 7.50E+00 U1/2
Se SWA-LRef-1315-M05-A 1 7.50E+00 U1/2
Se SWA-LRef-1315-M06-A 1 7.50E+00 U1/2
Se SWA-LRef-1315-M07-A 1 7.50E+00 U1/2
Se SWA-LRef-1315-M08-A 1 7.50E+00 U1/2
Se SWA-LRef-1315-M09-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.55E+03 0.77 15.00 47.70
5.05E+03 1.26 15.00 47.70
2.58E+03 0.62 15.00 47.70 10000 1000
5.28E+03 0.69 15.00 47.70
3.24E+03 0.26 15.00 47.70
3.39E+03 0.17 15.00 47.70
1.96E+03 1.62 15.00 47.70
7.50E+02 0.55 15.00 47.70
1.14E+03 0.87 15.00 47.70
1.60E+03 1.90 15.00 47.70
5.12E+03 0.69 15.00 47.70
2.55E+03 1.81 15.00 47.70 10000 1000
5.22E+03 0.48 15.00 47.70
3.03E+03 1.54 15.00 47.70
3.62E+03 1.35 15.00 47.70
1.96E+03 0.28 15.00 47.70
7.54E+02 4.20 15.00 47.70
1.28E+03 1.32 15.00 47.70
1.43E+03 3.03 15.00 47.70
5.31E+03 1.47 15.00 47.70
2.51E+03 2.33 15.00 47.70 10000 1000
5.57E+03 0.66 15.00 47.70
3.14E+03 1.98 15.00 47.70
3.71E+03 1.24 15.00 47.70
2.05E+03 1.15 15.00 47.70
7.58E+02 3.21 15.00 47.70
1.21E+03 0.05 15.00 47.70
7.50E+00 15.83 15.00 47.70
7.50E+00 44.04 15.00 47.70
7.50E+00 69.56 15.00 47.70
7.50E+00 48.12 15.00 47.70
7.50E+00 41.83 15.00 47.70
7.50E+00 1.44 15.00 47.70
7.50E+00 39.94 15.00 47.70
7.50E+00 23.10 15.00 47.70
7.50E+00 2.73 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.53E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.47E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.54E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/3/11 1:12 PM EPA Interlab LRef 1315 SWA
11/3/11 1:14 PM EPA Interlab LRef 1315 SWA
11/3/11 1:15 PM EPA Interlab LRef 131 5 SWA
11/3/11 1:17 PM EPA Interlab LRef 131 5 SWA
11/3/11 1:19PM EPA Interlab LRef 131 5 SWA
11/3/11 1:20 PM EPA Interlab LRef 131 5 SWA
11/3/11 1:22 PM EPA Interlab LRef 1315 SWA
11/3/11 1:24PM EPA Interlab LRef 1315 SWA
11/3/11 1:25 PM EPA Interlab LRef 1315 SWA
11/3/11 1:27 PM EPA Interlab LRef 1315 SWA
11/3/11 1:29 PM EPA Interlab LRef 1315 SWA
11/3/11 1:30 PM EPA Interlab LRef 1315 SWA
11/3/11 1:32 PM EPA Interlab LRef 1315 SWA
11/3/11 1:34 PM EPA Interlab LRef 1315 SWA
11/3/11 1:35 PM EPA Interlab LRef 1315 SWA
11/3/11 1:37 PM EPA Interlab LRef 1315 SWA
11/3/11 1:39 PM EPA Interlab LRef 1315 SWA
11/3/11 1:40 PM EPA Interlab LRef 1315 SWA
11/3/11 1:46 PM EPA Interlab LRef 1315 SWA
11/3/11 1:48 PM EPA Interlab LRef 1315 SWA
11/3/11 1:49 PM EPA Interlab LRef 1315 SWA
11/3/11 1:51 PM EPA Interlab LRef 1315 SWA
11/3/11 1:53 PM EPA Interlab LRef 1315 SWA
11/3/11 1:54 PM EPA Interlab LRef 1315 SWA
11/3/11 1:56 PM EPA Interlab LRef 1315 SWA
11/3/11 1:58 PM EPA Interlab LRef 1315 SWA
11/3/11 1:59 PM EPA Interlab LRef 1315 SWA
11/3/11 12:57 PM EPA Interlab LRef 1315 SWA
11/3/11 12:59 PM EPA Interlab LRef 1315 SWA
11/3/11 1:00 PM EPA Interlab LRef 1315 SWA
11/3/11 1:02 PM EPA Interlab LRef 1315 SWA
11/3/11 1:04 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :05 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :07 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :09 PM EPA Interlab LRef 1315 SWA
11/3/11 1:10 PM EPA Interlab LRef 1315 SWA
1-720
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Si SWA-LRef-1315-T01-A 1 7.10E+02
Si SWA-LRef-1315-T02-A 1 4.17E+03
Si SWA-LRef-1315-T03-A 1 3.19E+03
Si SWA-LRef-1315-T04-A 1 8.00E+03
Si SWA-LRef-1315-T05-A 1 7.52E+03
Si SWA-LRef-1315-T06-A 1 8.08E+03
Si SWA-LRef-1315-T07-A 1 7.30E+03
Si SWA-LRef-1315-T08-A 1 5.10E+03
Si SWA-LRef-1315-T09-A 1 6.73E+03
Si SWA-LRef-1315-T01-B 1 7.03E+02
Si SWA-LRef-1315-T02-B 1 4.40E+03
Si SWA-LRef-1315-T03-B 1 3.09E+03
Si SWA-LRef-1315-T04-B 1 7.99E+03
Si SWA-LRef-1315-T05-B 1 7.70E+03
Si SWA-LRef-1315-T06-B 1 8.13E+03
Si SWA-LRef-1315-T07-B 1 7.18E+03
Si SWA-LRef-1315-T08-B 1 5.21E+03
Si SWA-LRef-1315-T09-B 1 6.93E+03
Si SWA-LRef-1315-T01-C 1 7.13E+02
Si SWA-LRef-1315-T02-C 1 3.13E+03
Si SWA-LRef-1315-T03-C 1 2.89E+03
Si SWA-LRef-1315-T04-C 1 7.98E+03
Si SWA-LRef-1315-T05-C 1 7.98E+03
Si SWA-LRef-1315-T06-C 1 8.17E+03
Si SWA-LRef-1315-T07-C 1 7.06E+03
Si SWA-LRef-1315-T08-C 1 5.24E+03
Si SWA-LRef-1315-T09-C 1 7.10E+03
Si SWA-LRef-1315-M01-A 1 5.50E-01 U1/2
Si SWA-LRef-1315-M02-A 1 5.50E-01 U1/2
Si SWA-LRef-1315-M03-A 1 5.50E-01 U1/2
Si SWA-LRef-1315-M04-A 1 5.50E-01 U1/2
Si SWA-LRef-1315-M05-A 1 5.50E-01 U1/2
Si SWA-LRef-1315-M06-A 1 5.50E-01 U1/2
Si SWA-LRef-1315-M07-A 1 5.50E-01 U1/2
Si SWA-LRef-1315-M08-A 1 5.50E-01 U1/2
Si SWA-LRef-1315-M09-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.10E+02 0.48 1.10 3.50
4.17E+03 1.40 1.10 3.50
3.19E+03 0.36 1.10 3.50 10000 1000
8.00E+03 0.91 1.10 3.50
7.52E+03 1.67 1.10 3.50
8.08E+03 0.83 1.10 3.50
7.30E+03 1.13 1.10 3.50
5.10E+03 0.67 1.10 3.50
6.73E+03 0.50 1.10 3.50
7.03E+02 0.76 1.10 3.50
4.40E+03 0.48 1.10 3.50
3.09E+03 0.52 1.10 3.50 10000 1000
7.99E+03 1.34 1.10 3.50
7.70E+03 0.57 1.10 3.50
8.13E+03 1.10 1.10 3.50
7.18E+03 0.83 1.10 3.50
5.21E+03 1.39 1.10 3.50
6.93E+03 1.08 1.10 3.50
7.13E+02 0.99 1.10 3.50
3.13E+03 1.61 1.10 3.50
2.89E+03 0.47 1.10 3.50 10000 1000
7.98E+03 0.51 1.10 3.50
7.98E+03 1.25 1.10 3.50
8.17E+03 0.74 1.10 3.50
7.06E+03 0.60 1.10 3.50
5.24E+03 1.14 1.10 3.50
7.10E+03 0.44 1.10 3.50
5.50E-01 2.78 1.10 3.50
5.50E-01 2.99 1.10 3.50
5.50E-01 5.22 1.10 3.50
5.50E-01 7.41 1.10 3.50
5.50E-01 6.21 1.10 3.50
5.50E-01 1.02 1.10 3.50
5.50E-01 6.40 1.10 3.50
5.50E-01 4.16 1.10 3.50
5.50E-01 12.40 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.15E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.03E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.81 E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/3/11 1:12 PM EPA Interlab LRef 1315 SWA
11/3/11 1:14 PM EPA Interlab LRef 1315 SWA
11/3/11 1:15 PM EPA Interlab LRef 131 5 SWA
11/3/11 1:17 PM EPA Interlab LRef 131 5 SWA
11/3/11 1:19PM EPA Interlab LRef 131 5 SWA
11/3/11 1:20 PM EPA Interlab LRef 131 5 SWA
11/3/11 1:22 PM EPA Interlab LRef 1315 SWA
11/3/11 1:24PM EPA Interlab LRef 1315 SWA
11/3/11 1:25 PM EPA Interlab LRef 1315 SWA
11/3/11 1:27 PM EPA Interlab LRef 1315 SWA
11/3/11 1:29 PM EPA Interlab LRef 1315 SWA
11/3/11 1:30 PM EPA Interlab LRef 1315 SWA
11/3/11 1:32 PM EPA Interlab LRef 1315 SWA
11/3/11 1:34 PM EPA Interlab LRef 1315 SWA
11/3/11 1:35 PM EPA Interlab LRef 1315 SWA
11/3/11 1:37 PM EPA Interlab LRef 1315 SWA
11/3/11 1:39 PM EPA Interlab LRef 1315 SWA
11/3/11 1:40 PM EPA Interlab LRef 1315 SWA
11/3/11 1:46 PM EPA Interlab LRef 1315 SWA
11/3/11 1:48 PM EPA Interlab LRef 1315 SWA
11/3/11 1:49 PM EPA Interlab LRef 1315 SWA
11/3/11 1:51 PM EPA Interlab LRef 1315 SWA
11/3/11 1:53 PM EPA Interlab LRef 1315 SWA
11/3/11 1:54 PM EPA Interlab LRef 1315 SWA
11/3/11 1:56 PM EPA Interlab LRef 1315 SWA
11/3/11 1:58 PM EPA Interlab LRef 1315 SWA
11/3/11 1:59 PM EPA Interlab LRef 1315 SWA
11/3/11 12:57 PM EPA Interlab LRef 1315 SWA
11/3/11 12:59 PM EPA Interlab LRef 1315 SWA
11/3/11 1:00 PM EPA Interlab LRef 1315 SWA
11/3/11 1:02 PM EPA Interlab LRef 1315 SWA
11/3/11 1:04 PM EPA Interlab LRef 1315 SWA
11/3/11 1:05 PM EPA Interlab LRef 1315 SWA
11/3/11 1:07 PM EPA Interlab LRef 1315 SWA
11/3/11 1:09 PM EPA Interlab LRef 1315 SWA
11/3/11 1:10 PM EPA Interlab LRef 1315 SWA
1-721
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Na SWA-LRef-1315-T01-A 1 3.96E+04
Na SWA-LRef-1315-T02-A 1 1.18E+05
Na SWA-LRef-1315-T03-A 1 6.92E+04
Na SWA-LRef-1315-T04-A 1 1.79E+05
Na SWA-LRef-1315-T05-A 1 1.44E+05
Na SWA-LRef-1315-T06-A 1 1.02E+05
Na SWA-LRef-1315-T07-A 1 8.22E+04
Na SWA-LRef-1315-T08-A 1 3.84E+04
Na SWA-LRef-1315-T09-A 1 5.90E+04
Na SWA-LRef-1315-T01-B 1 3.89E+04
Na SWA-LRef-1315-T02-B 1 1.14E+05
Na SWA-LRef-1315-T03-B 1 8.10E+04
Na SWA-LRef-1315-T04-B 1 1.86E+05
Na SWA-LRef-1315-T05-B 1 1.39E+05
Na SWA-LRef-1315-T06-B 1 1.02E+05
Na SWA-LRef-1315-T07-B 1 8.16E+04
Na SWA-LRef-1315-T08-B 1 3.86E+04
Na SWA-LRef-1315-T09-B 1 5.80E+04
Na SWA-LRef-1315-T01-C 1 2.88E+04
Na SWA-LRef-1315-T02-C 1 1.19E+05
Na SWA-LRef-1315-T03-C 1 8.28E+04
Na SWA-LRef-1315-T04-C 1 1.81E+05
Na SWA-LRef-1315-T05-C 1 1.43E+05
Na SWA-LRef-1315-T06-C 1 1.01E+05
Na SWA-LRef-1315-T07-C 1 8.02E+04
Na SWA-LRef-1315-T08-C 1 3.84E+04
Na SWA-LRef-1315-T09-C 1 5.64E+04
Na SWA-LRef-1315-M01-A 1 2.32E+01
Na SWA-LRef-1315-M02-A 1 1.71E+01
Na SWA-LRef-1315-M03-A 1 1.85E+01
Na SWA-LRef-1315-M04-A 1 1.44E+01
Na SWA-LRef-1315-M05-A 1 1.02E+01
Na SWA-LRef-1315-M06-A 1 7.15E+00 E
Na SWA-LRef-1315-M07-A 1 9.65E+00
Na SWA-LRef-1315-M08-A 1 4.61 E+00 E
Na SWA-LRef-1315-M09-A 1 4.91 E+00 E
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.96E+04 0.51 2.50 8.00
1.18E+05 0.95 2.50 8.00
6.92E+04 0.38 2.50 8.00 10000 1000
1.79E+05 0.36 2.50 8.00
1.44E+05 0.37 2.50 8.00
1.02E+05 0.38 2.50 8.00
8.22E+04 0.51 2.50 8.00
3.84E+04 0.33 2.50 8.00
5.90E+04 0.49 2.50 8.00
3.89E+04 0.43 2.50 8.00
1.14E+05 0.66 2.50 8.00
8.10E+04 0.45 2.50 8.00 10000 1000
1.86E+05 0.15 2.50 8.00
1.39E+05 0.43 2.50 8.00
1.02E+05 0.06 2.50 8.00
8.16E+04 0.33 2.50 8.00
3.86E+04 0.23 2.50 8.00
5.80E+04 0.53 2.50 8.00
2.88E+04 0.46 2.50 8.00
1.19E+05 0.15 2.50 8.00
8.28E+04 1.28 2.50 8.00 10000 1000
1.81E+05 0.75 2.50 8.00
1.43E+05 0.53 2.50 8.00
1.01E+05 0.34 2.50 8.00
8.02E+04 1.20 2.50 8.00
3.84E+04 0.47 2.50 8.00
5.64E+04 0.13 2.50 8.00
2.32E+01 4.27 2.50 8.00
1.71E+01 2.72 2.50 8.00
1.85E+01 8.84 2.50 8.00
1.44E+01 4.56 2.50 8.00
1.02E+01 6.39 2.50 8.00
7.15E+00 0.22 2.50 8.00
9.65E+00 2.03 2.50 8.00
4.61 E+00 0.63 2.50 8.00
4.91 E+00 2.07 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
7.01E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.19E+04 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.36E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/14/11 4:17 PM EPA Interlab LRef 1315 SWA
3/14/11 4:19 PM EPA Interlab LRef 1315 SWA
3/14/11 4:20 PM EPA Interlab LRef 1315 SWA
3/14/11 4:22 PM EPA Interlab LRef 1315 SWA
3/14/11 4:24 PM EPA Interlab LRef 1315 SWA
3/14/11 4:25 PM EPA Interlab LRef 1315 SWA
3/14/11 4:27 PM EPA Interlab LRef 1315 SWA
3/14/11 4:28 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:30 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:32 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:33 PM EPA Interlab LRef 1315 SWA
3/14/11 4:35 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:37 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:38 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:40 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:42 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:43 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:45 PM EPA Interlab LRef 1315 SWA
3/15/11 10:28 AM EPA Interlab LRef 1315 SWA
3/15/11 10:30 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:32 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:33 AM EPA Interlab LRef 1315 SWA
3/15/11 10:35 AM EPA Interlab LRef 1315 SWA
3/15/11 10:37 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:38 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:40 AM EPA Interlab LRef 1315 SWA
3/15/11 10:41 AM EPA Interlab LRef 1315 SWA
3/14/11 2:57 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:30 PM EPA Interlab LRef 1315 SWA
3/14/11 2:58 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:00 PM EPA Interlab LRef 1315 SWA
3/14/11 3:01 PM EPA Interlab LRef 1315 SWA
3/14/11 3:24 PM EPA Interlab LRef 1315 SWA
3/14/11 3:25 PM EPA Interlab LRef 1315 SWA
3/14/11 3:27 PM EPA Interlab LRef 1315 SWA
3/14/11 3:29 PM EPA Interlab LRef 1315 SWA
1-722
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Sr SWA-LRef-1315-T01-A 1 7.81E+00
Sr SWA-LRef-1315-T02-A 1 1.18E+02
Sr SWA-LRef-1315-T03-A 1 1.05E+02
Sr SWA-LRef-1315-T04-A 1 1.95E+02
Sr SWA-LRef-1315-T05-A 1 2.15E+02
Sr SWA-LRef-1315-T06-A 1 2.36E+02
Sr SWA-LRef-1315-T07-A 1 2.59E+02
Sr SWA-LRef-1315-T08-A 1 2.37E+02
Sr SWA-LRef-1315-T09-A 1 2.68E+02
Sr SWA-LRef-1315-T01-B 1 7.70E+00
Sr SWA-LRef-1315-T02-B 1 1.14E+02
Sr SWA-LRef-1315-T03-B 1 9.43E+01
Sr SWA-LRef-1315-T04-B 1 1.96E+02
Sr SWA-LRef-1315-T05-B 1 2.13E+02
Sr SWA-LRef-1315-T06-B 1 2.38E+02
Sr SWA-LRef-1315-T07-B 1 2.46E+02
Sr SWA-LRef-1315-T08-B 1 2.33E+02
Sr SWA-LRef-1315-T09-B 1 2.52E+02
Sr SWA-LRef-1315-T01-C 1 8.13E+00
Sr SWA-LRef-1315-T02-C 1 1.11E+02
Sr SWA-LRef-1315-T03-C 1 1.04E+02
Sr SWA-LRef-1315-T04-C 1 1.79E+02
Sr SWA-LRef-1315-T05-C 1 2.17E+02
Sr SWA-LRef-1315-T06-C 1 2.26E+02
Sr SWA-LRef-1315-T07-C 1 2.54E+02
Sr SWA-LRef-1315-T08-C 1 2.25E+02
Sr SWA-LRef-1315-T09-C 1 2.43E+02
Sr SWA-LRef-1315-M01-A 1 5.00E-01 U1/2
Sr SWA-LRef-1315-M02-A 1 5.00E-01 U1/2
Sr SWA-LRef-1315-M03-A 1 5.00E-01 U1/2
Sr SWA-LRef-1315-M04-A 1 5.00E-01 U1/2
Sr SWA-LRef-1315-M05-A 1 5.00E-01 U1/2
Sr SWA-LRef-1315-M06-A 1 5.00E-01 U1/2
Sr SWA-LRef-1315-M07-A 1 5.00E-01 U1/2
Sr SWA-LRef-1315-M08-A 1 5.00E-01 U1/2
Sr SWA-LRef-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.81E+00 4.65 1.00 3.18
1.18E+02 1.01 1.00 3.18
1.05E+02 0.36 1.00 3.18 10000 1000
1.95E+02 0.73 1.00 3.18
2.15E+02 1.22 1.00 3.18
2.36E+02 0.64 1.00 3.18
2.59E+02 0.64 1.00 3.18
2.37E+02 1.36 1.00 3.18
2.68E+02 0.71 1.00 3.18
7.70E+00 3.59 1.00 3.18
1.14E+02 0.57 1.00 3.18
9.43E+01 1.02 1.00 3.18 10000 1000
1.96E+02 0.82 1.00 3.18
2.13E+02 1.46 1.00 3.18
2.38E+02 0.90 1.00 3.18
2.46E+02 0.28 1.00 3.18
2.33E+02 0.92 1.00 3.18
2.52E+02 0.22 1.00 3.18
8.13E+00 4.89 1.00 3.18
1.11E+02 0.55 1.00 3.18
1.04E+02 0.86 1.00 3.18 10000 1000
1.79E+02 0.18 1.00 3.18
2.17E+02 1.62 1.00 3.18
2.26E+02 1.57 1.00 3.18
2.54E+02 0.81 1.00 3.18
2.25E+02 1.09 1.00 3.18
2.43E+02 0.48 1.00 3.18
5.00E-01 16.71 1.00 3.18
5.00E-01 18.41 1.00 3.18
5.00E-01 55.52 1.00 3.18
5.00E-01 57.84 1.00 3.18
5.00E-01 16.02 1.00 3.18
5.00E-01 0.20 1.00 3.18
5.00E-01 39.50 1.00 3.18
5.00E-01 33.39 1.00 3.18
5.00E-01 13.68 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.20E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/3/11 1:12 PM EPA Interlab LRef 1315 SWA
11/3/11 1:14 PM EPA Interlab LRef 1315 SWA
11/3/11 1:15 PM EPA Interlab LRef 131 5 SWA
11/3/11 1:17 PM EPA Interlab LRef 131 5 SWA
11/3/11 1:19PM EPA Interlab LRef 131 5 SWA
11/3/11 1:20 PM EPA Interlab LRef 131 5 SWA
11/3/11 1:22 PM EPA Interlab LRef 1315 SWA
11/3/11 1:24PM EPA Interlab LRef 1315 SWA
11/3/11 1:25 PM EPA Interlab LRef 1315 SWA
11/3/11 1:27 PM EPA Interlab LRef 1315 SWA
11/3/11 1:29 PM EPA Interlab LRef 1315 SWA
11/3/11 1:30 PM EPA Interlab LRef 1315 SWA
11/3/11 1:32 PM EPA Interlab LRef 1315 SWA
11/3/11 1:34 PM EPA Interlab LRef 1315 SWA
11/3/11 1:35 PM EPA Interlab LRef 1315 SWA
11/3/11 1:37 PM EPA Interlab LRef 1315 SWA
11/3/11 1:39 PM EPA Interlab LRef 1315 SWA
11/3/11 1:40 PM EPA Interlab LRef 1315 SWA
11/3/11 1:46 PM EPA Interlab LRef 1315 SWA
11/3/11 1:48 PM EPA Interlab LRef 1315 SWA
11/3/11 1:49 PM EPA Interlab LRef 1315 SWA
11/3/11 1:51 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :53 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :54 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :56 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :58 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :59 PM EPA Interlab LRef 1315 SWA
11/3/11 12:57 PM EPA Interlab LRef 1315 SWA
11/3/11 12:59 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :00 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :02 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :04 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :05 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :07 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :09 PM EPA Interlab LRef 1315 SWA
11/3/11 1:10 PM EPA Interlab LRef 131 5 SWA
1-723
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
S SWA-LRef-1315-T01-A 1 4.04E+03
S SWA-LRef-1315-T02-A 1 1.42E+04
S SWA-LRef-1315-T03-A 1 6.98E+03
S SWA-LRef-1315-T04-A 1 2.27E+04
S SWA-LRef-1315-T05-A 1 1.07E+04
S SWA-LRef-1315-T06-A 1 1.24E+04
S SWA-LRef-1315-T07-A 1 6.93E+03
S SWA-LRef-1315-T08-A 1 1.72E+03
S SWA-LRef-1315-T09-A 1 3.88E+03
S SWA-LRef-1315-T01-B 1 4.37E+03
S SWA-LRef-1315-T02-B 1 1.21E+04
S SWA-LRef-1315-T03-B 1 7.85E+03
S SWA-LRef-1315-T04-B 1 1.87E+04
S SWA-LRef-1315-T05-B 1 9.43E+03
S SWA-LRef-1315-T06-B 1 8.68E+03
S SWA-LRef-1315-T07-B 1 5.35E+03
S SWA-LRef-1315-T08-B 1 1.64E+03
S SWA-LRef-1315-T09-B 1 3.47E+03
S SWA-LRef-1315-T01-C 1 2.45E+03
S SWA-LRef-1315-T02-C 1 1.43E+04
S SWA-LRef-1315-T03-C 1 7.96E+03
S SWA-LRef-1315-T04-C 1 1.86E+04
S SWA-LRef-1315-T05-C 1 9.74E+03
S SWA-LRef-1315-T06-C 1 9.69E+03
S SWA-LRef-1315-T07-C 1 5.33E+03
S SWA-LRef-1315-T08-C 1 1.66E+03
S SWA-LRef-1315-T09-C 1 3.51E+03
S SWA-LRef-1315-M01-A 1 3.40E+00 U1/2
S SWA-LRef-1315-M02-A 1 3.40E+00 U1/2
S SWA-LRef-1315-M03-A 1 3.40E+00 U1/2
S SWA-LRef-1315-M04-A 1 3.40E+00 U1/2
S SWA-LRef-1315-M05-A 1 3.40E+00 U1/2
S SWA-LRef-1315-M06-A 1 3.40E+00 U1/2
S SWA-LRef-1315-M07-A 1 3.40E+00 U1/2
S SWA-LRef-1315-M08-A 1 3.40E+00 U1/2
S SWA-LRef-1315-M09-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.04E+03 0.97 6.80 21.60
1.42E+04 1.04 6.80 21.60
6.98E+03 1.37 6.80 21.60 10000 1000
2.27E+04 0.61 6.80 21.60
1.07E+04 0.97 6.80 21.60
1.24E+04 0.88 6.80 21.60
6.93E+03 0.75 6.80 21.60
1.72E+03 0.57 6.80 21.60
3.88E+03 1.38 6.80 21.60
4.37E+03 1.58 6.80 21.60
1.21E+04 0.63 6.80 21.60
7.85E+03 0.70 6.80 21.60 10000 1000
1.87E+04 0.40 6.80 21.60
9.43E+03 0.86 6.80 21.60
8.68E+03 0.57 6.80 21.60
5.35E+03 0.18 6.80 21.60
1.64E+03 1.03 6.80 21.60
3.47E+03 0.93 6.80 21.60
2.45E+03 0.58 6.80 21.60
1.43E+04 0.63 6.80 21.60
7.96E+03 2.12 6.80 21.60 10000 1000
1.86E+04 0.42 6.80 21.60
9.74E+03 2.72 6.80 21.60
9.69E+03 1.47 6.80 21.60
5.33E+03 1.40 6.80 21.60
1.66E+03 2.03 6.80 21.60
3.51 E+03 0.30 6.80 21.60
3.40E+00 0.40 6.80 21.60
3.40E+00 2.14 6.80 21.60
3.40E+00 1.63 6.80 21.60
3.40E+00 13.34 6.80 21.60
3.40E+00 4.56 6.80 21.60
3.40E+00 1.25 6.80 21.60
3.40E+00 1.97 6.80 21.60
3.40E+00 18.09 6.80 21.60
3.40E+00 8.78 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
7.83E+03 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.74E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.79E+03 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/14/11 4:17 PM EPA Interlab LRef 1315 SWA
3/14/11 4:19 PM EPA Interlab LRef 1315 SWA
3/14/11 4:20 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:22 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:24 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:25 PM EPA Interlab LRef 1315 SWA
3/14/11 4:27 PM EPA Interlab LRef 1315 SWA
3/14/11 4:28 PM EPA Interlab LRef 1315 SWA
3/14/11 4:30 PM EPA Interlab LRef 1315 SWA
3/14/11 4:32 PM EPA Interlab LRef 1315 SWA
3/14/11 4:33 PM EPA Interlab LRef 1315 SWA
3/14/11 4:35 PM EPA Interlab LRef 1315 SWA
3/14/11 4:37 PM EPA Interlab LRef 1315 SWA
3/14/11 4:38 PM EPA Interlab LRef 1315 SWA
3/14/11 4:40 PM EPA Interlab LRef 1315 SWA
3/14/11 4:42 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:43 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:45 PM EPA Interlab LRef 1315 SWA
3/15/11 10:28 AM EPA Interlab LRef 1315 SWA
3/15/11 10:30 AM EPA Interlab LRef 1315 SWA
3/15/11 10:32 AM EPA Interlab LRef 1315 SWA
3/15/11 10:33 AM EPA Interlab LRef 1315 SWA
3/15/11 10:35 AM EPA Interlab LRef 1315 SWA
3/15/11 10:37 AM EPA Interlab LRef 1315 SWA
3/15/11 10:38 AM EPA Interlab LRef 1315 SWA
3/15/11 10:40 AM EPA Interlab LRef 1315 SWA
3/15/11 10:41 AM EPA Interlab LRef 1315 SWA
3/14/11 2:57 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:30 PM EPA Interlab LRef 1315 SWA
3/14/11 2:58 PM EPA Interlab LRef 1315 SWA
3/14/11 3:00 PM EPA Interlab LRef 1315 SWA
3/14/11 3:01 PM EPA Interlab LRef 1315 SWA
3/14/11 3:24 PM EPA Interlab LRef 1315 SWA
3/14/11 3:25 PM EPA Interlab LRef 1315 SWA
3/14/11 3:27 PM EPA Interlab LRef 1315 SWA
3/14/11 3:29 PM EPA Interlab LRef 1315 SWA
1-724
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Tl SWA-LRef-1315-T01-A 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T02-A 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T03-A 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T04-A 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T05-A 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T06-A 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T07-A 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T08-A 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T09-A 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T01-B 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T02-B 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T03-B 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T04-B 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T05-B 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T06-B 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T07-B 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T08-B 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T09-B 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T01-C 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T02-C 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T03-C 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T04-C 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T05-C 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T06-C 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T07-C 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T08-C 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T09-C 1 2.30E+00 U1/2
Tl SWA-LRef-1315-M01-A 1 2.30E+00 U1/2
Tl SWA-LRef-1315-M02-A 1 2.30E+00 U1/2
Tl SWA-LRef-1315-M03-A 1 2.30E+00 U1/2
Tl SWA-LRef-1315-M04-A 1 2.30E+00 U1/2
Tl SWA-LRef-1315-M05-A 1 2.30E+00 U1/2
Tl SWA-LRef-1315-M06-A 1 2.30E+00 U1/2
Tl SWA-LRef-1315-M07-A 1 2.30E+00 U1/2
Tl SWA-LRef-1315-M08-A 1 2.30E+00 U1/2
Tl SWA-LRef-1315-M09-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 90.75 4.60 14.60
2.30E+00 27.02 4.60 14.60
2.30E+00 22.83 4.60 14.60 10000 1000
2.30E+00 31.87 4.60 14.60
2.30E+00 79.39 4.60 14.60
2.30E+00 41.08 4.60 14.60
2.30E+00 29.80 4.60 14.60
2.30E+00 25.45 4.60 14.60
2.30E+00 28.87 4.60 14.60
2.30E+00 41.67 4.60 14.60
2.30E+00 42.25 4.60 14.60
2.30E+00 91.17 4.60 14.60 10000 1000
2.30E+00 17.23 4.60 14.60
2.30E+00 55.09 4.60 14.60
2.30E+00 61.73 4.60 14.60
2.30E+00 38.40 4.60 14.60
2.30E+00 21.80 4.60 14.60
2.30E+00 24.92 4.60 14.60
2.30E+00 29.76 4.60 14.60
2.30E+00 24.97 4.60 14.60
2.30E+00 13.08 4.60 14.60 10000 1000
2.30E+00 49.20 4.60 14.60
2.30E+00 22.22 4.60 14.60
2.30E+00 45.68 4.60 14.60
2.30E+00 55.77 4.60 14.60
2.30E+00 33.73 4.60 14.60
2.30E+00 23.86 4.60 14.60
2.30E+00 36.43 4.60 14.60
2.30E+00 38.38 4.60 14.60
2.30E+00 31.40 4.60 14.60
2.30E+00 58.58 4.60 14.60
2.30E+00 41.50 4.60 14.60
2.30E+00 4.53 4.60 14.60
2.30E+00 21.63 4.60 14.60
2.30E+00 5.89 4.60 14.60
2.30E+00 24.51 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.72E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.50E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/14/11 4:17 PM EPA Interlab LRef 1315 SWA
3/14/11 4:19 PM EPA Interlab LRef 1315 SWA
3/14/11 4:20 PM EPA Interlab LRef 1315 SWA
3/14/11 4:22 PM EPA Interlab LRef 1315 SWA
3/14/11 4:24 PM EPA Interlab LRef 1315 SWA
3/14/11 4:25 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:27 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:28 PM EPA Interlab LRef 1315 SWA
3/14/11 4:30 PM EPA Interlab LRef 1315 SWA
3/14/11 4:32 PM EPA Interlab LRef 1315 SWA
3/14/11 4:33 PM EPA Interlab LRef 1315 SWA
3/14/11 4:35 PM EPA Interlab LRef 1315 SWA
3/14/11 4:37 PM EPA Interlab LRef 1315 SWA
3/14/11 4:38 PM EPA Interlab LRef 1315 SWA
3/14/11 4:40 PM EPA Interlab LRef 1315 SWA
3/14/11 4:42 PM EPA Interlab LRef 1315 SWA
3/14/11 4:43 PM EPA Interlab LRef 1315 SWA
3/14/11 4:45 PM EPA Interlab LRef 1315 SWA
3/15/11 10:28 AM EPA Interlab LRef 1315 SWA
3/15/11 10:30 AM EPA Interlab LRef 1315 SWA
3/15/11 10:32 AM EPA Interlab LRef 1315 SWA
3/15/11 10:33 AM EPA Interlab LRef 1315 SWA
3/15/11 10:35 AM EPA Interlab LRef 1315 SWA
3/15/11 10:37 AM EPA Interlab LRef 1315 SWA
3/15/11 10:38 AM EPA Interlab LRef 1315 SWA
3/15/11 10:40 AM EPA Interlab LRef 1315 SWA
3/15/11 10:41 AM EPA Interlab LRef 1315 SWA
3/14/1 1 2:57 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:30 PM EPA Interlab LRef 1315 SWA
3/14/11 2:58 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:00 PM EPA Interlab LRef 1315 SWA
3/14/11 3:01 PM EPA Interlab LRef 1315 SWA
3/14/11 3:24 PM EPA Interlab LRef 1315 SWA
3/14/11 3:25 PM EPA Interlab LRef 1315 SWA
3/14/11 3:27 PM EPA Interlab LRef 1315 SWA
3/14/11 3:29 PM EPA Interlab LRef 1315 SWA
1-725
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Ti SWA-LRef-1315-T01-A 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T02-A 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T03-A 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T04-A 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T05-A 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T06-A 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T07-A 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T08-A 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T09-A 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T01-B 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T02-B 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T03-B 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T04-B 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T05-B 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T06-B 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T07-B 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T08-B 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T09-B 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T01-C 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T02-C 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T03-C 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T04-C 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T05-C 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T06-C 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T07-C 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T08-C 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T09-C 1 1.00E+00 U1/2
Ti SWA-LRef-1315-M01-A 1 1.00E+00 U1/2
Ti SWA-LRef-1315-M02-A 1 1.00E+00 U1/2
Ti SWA-LRef-1315-M03-A 1 1.00E+00 U1/2
Ti SWA-LRef-1315-M04-A 1 1.00E+00 U1/2
Ti SWA-LRef-1315-M05-A 1 1.00E+00 U1/2
Ti SWA-LRef-1315-M06-A 1 1.00E+00 U1/2
Ti SWA-LRef-1315-M07-A 1 1.00E+00 U1/2
Ti SWA-LRef-1315-M08-A 1 1.00E+00 U1/2
Ti SWA-LRef-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 41.73 2.00 6.40
1.00E+00 77.53 2.00 6.40
1.00E+00 53.20 2.00 6.40 10000 1000
1.00E+00 17.02 2.00 6.40
1.00E+00 44.15 2.00 6.40
1.00E+00 15.46 2.00 6.40
1.00E+00 16.78 2.00 6.40
1.00E+00 67.87 2.00 6.40
1.00E+00 1.41 2.00 6.40
1.00E+00 21.78 2.00 6.40
1.00E+00 19.37 2.00 6.40
1.00E+00 63.64 2.00 6.40 10000 1000
1.00E+00 43.56 2.00 6.40
1.00E+00 63.14 2.00 6.40
1.00E+00 22.82 2.00 6.40
1.00E+00 12.29 2.00 6.40
1.00E+00 60.37 2.00 6.40
1.00E+00 59.54 2.00 6.40
1.00E+00 14.67 2.00 6.40
1.00E+00 22.18 2.00 6.40
1.00E+00 62.73 2.00 6.40 10000 1000
1.00E+00 26.85 2.00 6.40
1.00E+00 25.20 2.00 6.40
1.00E+00 62.66 2.00 6.40
1.00E+00 29.29 2.00 6.40
1.00E+00 14.27 2.00 6.40
1.00E+00 16.94 2.00 6.40
1.00E+00 11.01 2.00 6.40
1.00E+00 22.84 2.00 6.40
1.00E+00 46.07 2.00 6.40
1.00E+00 43.04 2.00 6.40
1.00E+00 20.94 2.00 6.40
1.00E+00 62.48 2.00 6.40
1.00E+00 35.16 2.00 6.40
1.00E+00 22.64 2.00 6.40
1.00E+00 11.17 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.73E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.73E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.42E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/14/11 4:17 PM EPA Interlab LRef 1315 SWA
3/14/11 4:19 PM EPA Interlab LRef 1315 SWA
3/14/11 4:20 PM EPA Interlab LRef 1315 SWA
3/14/11 4:22 PM EPA Interlab LRef 1315 SWA
3/14/11 4:24 PM EPA Interlab LRef 1315 SWA
3/14/11 4:25 PM EPA Interlab LRef 1315 SWA
3/14/11 4:27 PM EPA Interlab LRef 1315 SWA
3/14/11 4:28 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:30 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:32 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:33 PM EPA Interlab LRef 1315 SWA
3/14/11 4:35 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:37 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:38 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:40 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:42 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:43 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:45 PM EPA Interlab LRef 1315 SWA
3/15/11 10:28 AM EPA Interlab LRef 1315 SWA
3/15/11 10:30 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:32 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:33 AM EPA Interlab LRef 1315 SWA
3/15/11 10:35 AM EPA Interlab LRef 1315 SWA
3/15/11 10:37 AM EPA Interlab LRef 1315 SWA
3/15/11 10:38 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:40 AM EPA Interlab LRef 1315 SWA
3/15/11 10:41 AM EPA Interlab LRef 1315 SWA
3/14/11 2:57 PM EPA Interlab LRef 1315 SWA
3/14/11 3:30 PM EPA Interlab LRef 1315 SWA
3/14/11 2:58 PM EPA Interlab LRef 1315 SWA
3/14/11 3:00 PM EPA Interlab LRef 1315 SWA
3/14/11 3:01 PM EPA Interlab LRef 1315 SWA
3/14/11 3:24 PM EPA Interlab LRef 1315 SWA
3/14/11 3:25 PM EPA Interlab LRef 1315 SWA
3/14/11 3:27 PM EPA Interlab LRef 1315 SWA
3/14/11 3:29 PM EPA Interlab LRef 1315 SWA
1-726
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
V SWA-LRef-1315-T01-A 1 1.08E+01
V SWA-LRef-1315-T02-A 1 1.79E+01
V SWA-LRef-1315-T03-A 1 1.09E+01
V SWA-LRef-1315-T04-A 1 1.89E+01
V SWA-LRef-1315-T05-A 1 2.25E+01
V SWA-LRef-1315-T06-A 1 1.98E+01
V SWA-LRef-1315-T07-A 1 1.74E+01
V SWA-LRef-1315-T08-A 1 1.32E+01
V SWA-LRef-1315-T09-A 1 1.79E+01
V SWA-LRef-1315-T01-B 1 1.24E+01
V SWA-LRef-1315-T02-B 1 1.82E+01
V SWA-LRef-1315-T03-B 1 1.12E+01
V SWA-LRef-1315-T04-B 1 1.97E+01
V SWA-LRef-1315-T05-B 1 1.61E+01
V SWA-LRef-1315-T06-B 1 1.88E+01
V SWA-LRef-1315-T07-B 1 1.68E+01
V SWA-LRef-1315-T08-B 1 1.21E+01
V SWA-LRef-1315-T09-B 1 1.55E+01
V SWA-LRef-1315-T01-C 1 1.18E+01
V SWA-LRef-1315-T02-C 1 1.88E+01
V SWA-LRef-1315-T03-C 1 1.19E+01
V SWA-LRef-1315-T04-C 1 2.09E+01
V SWA-LRef-1315-T05-C 1 1.83E+01
V SWA-LRef-1315-T06-C 1 2.03E+01
V SWA-LRef-1315-T07-C 1 1.52E+01
V SWA-LRef-1315-T08-C 1 1.28E+01
V SWA-LRef-1315-T09-C 1 1.60E+01
V SWA-LRef-1315-M01-A 1 7.50E-01 U1/2
V SWA-LRef-1315-M02-A 1 7.50E-01 U1/2
V SWA-LRef-1315-M03-A 1 7.50E-01 U1/2
V SWA-LRef-1315-M04-A 1 7.50E-01 U1/2
V SWA-LRef-1315-M05-A 1 7.50E-01 U1/2
V SWA-LRef-1315-M06-A 1 7.50E-01 U1/2
V SWA-LRef-1315-M07-A 1 7.50E-01 U1/2
V SWA-LRef-1315-M08-A 1 7.50E-01 U1/2
V SWA-LRef-1315-M09-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.08E+01 4.56 1.50 4.77
1.79E+01 2.04 1.50 4.77
1.09E+01 11.32 1.50 4.77 10000 1000
1.89E+01 4.85 1.50 4.77
2.25E+01 2.80 1.50 4.77
1.98E+01 4.14 1.50 4.77
1.74E+01 0.85 1.50 4.77
1.32E+01 2.79 1.50 4.77
1.79E+01 3.08 1.50 4.77
1.24E+01 1.88 1.50 4.77
1.82E+01 1.38 1.50 4.77
1.12E+01 4.79 1.50 4.77 10000 1000
1.97E+01 2.05 1.50 4.77
1.61E+01 0.99 1.50 4.77
1.88E+01 3.90 1.50 4.77
1.68E+01 6.16 1.50 4.77
1.21E+01 8.54 1.50 4.77
1.55E+01 3.11 1.50 4.77
1.18E+01 5.46 1.50 4.77
1.88E+01 7.27 1.50 4.77
1.19E+01 5.33 1.50 4.77 10000 1000
2.09E+01 3.12 1.50 4.77
1.83E+01 6.13 1.50 4.77
2.03E+01 5.34 1.50 4.77
1.52E+01 3.46 1.50 4.77
1.28E+01 8.09 1.50 4.77
1.60E+01 6.29 1.50 4.77
7.50E-01 42.75 1.50 4.77
7.50E-01 38.27 1.50 4.77
7.50E-01 29.48 1.50 4.77
7.50E-01 55.38 1.50 4.77
7.50E-01 13.38 1.50 4.77
7.50E-01 6.34 1.50 4.77
7.50E-01 40.73 1.50 4.77
7.50E-01 33.12 1.50 4.77
7.50E-01 19.20 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.80E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/3/11 1:12 PM EPA Interlab LRef 1315 SWA
11/3/11 1:14 PM EPA Interlab LRef 1315 SWA
11/3/11 1:15 PM EPA Interlab LRef 131 5 SWA
11/3/11 1:17 PM EPA Interlab LRef 131 5 SWA
11/3/11 1:19PM EPA Interlab LRef 131 5 SWA
11/3/11 1:20 PM EPA Interlab LRef 131 5 SWA
11/3/11 1:22 PM EPA Interlab LRef 1315 SWA
11/3/11 1:24PM EPA Interlab LRef 1315 SWA
11/3/11 1:25 PM EPA Interlab LRef 1315 SWA
11/3/11 1:27 PM EPA Interlab LRef 1315 SWA
11/3/11 1:29 PM EPA Interlab LRef 1315 SWA
11/3/11 1:30 PM EPA Interlab LRef 1315 SWA
11/3/11 1:32 PM EPA Interlab LRef 1315 SWA
11/3/11 1:34 PM EPA Interlab LRef 1315 SWA
11/3/11 1:35 PM EPA Interlab LRef 1315 SWA
11/3/11 1:37 PM EPA Interlab LRef 1315 SWA
11/3/11 1:39 PM EPA Interlab LRef 1315 SWA
11/3/11 1:40 PM EPA Interlab LRef 1315 SWA
11/3/11 1:46 PM EPA Interlab LRef 1315 SWA
11/3/11 1:48 PM EPA Interlab LRef 1315 SWA
11/3/11 1:49 PM EPA Interlab LRef 1315 SWA
11/3/11 1:51 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :53 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :54 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :56 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :58 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :59 PM EPA Interlab LRef 1315 SWA
11/3/11 12:57 PM EPA Interlab LRef 1315 SWA
11/3/11 12:59 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :00 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :02 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :04 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :05 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :07 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 1 :09 PM EPA Interlab LRef 1315 SWA
11/3/11 1:10 PM EPA Interlab LRef 131 5 SWA
1-727
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Zn SWA-LRef-1315-T01-A 1 2.11E+OOE
Zn SWA-LRef-1315-T02-A 1 1.91E+01
Zn SWA-LRef-1315-T03-A 1 1.50E+01
Zn SWA-LRef-1315-T04-A 1 1.45E+01
Zn SWA-LRef-1315-T05-A 1 1.33E+01
Zn SWA-LRef-1315-T06-A 1 1.45E+01
Zn SWA-LRef-1315-T07-A 1 1.77E+00 E
Zn SWA-LRef-1315-T08-A 1 2.06E+00 E
Zn SWA-LRef-1315-T09-A 1 1.86E+01
Zn SWA-LRef-1315-T01-B 1 1.65E+00 E
Zn SWA-LRef-1315-T02-B 1 3.51E+00
Zn SWA-LRef-1315-T03-B 1 1.47E+01
Zn SWA-LRef-1315-T04-B 1 1.45E+01
Zn SWA-LRef-1315-T05-B 1 1.23E+01
Zn SWA-LRef-1315-T06-B 1 1.47E+01
Zn SWA-LRef-1315-T07-B 1 5.00E-01 U1/2
Zn SWA-LRef-1315-T08-B 1 5.00E-01 U1/2
Zn SWA-LRef-1315-T09-B 1 1.37E+01
Zn SWA-LRef-1315-T01-C 1 5.00E-01 U1/2
Zn SWA-LRef-1315-T02-C 1 2.62E+00 E
Zn SWA-LRef-1315-T03-C 1 1.45E+01
Zn SWA-LRef-1315-T04-C 1 1.46E+01
Zn SWA-LRef-1315-T05-C 1 1.40E+01
Zn SWA-LRef-1315-T06-C 1 1.41E+01
Zn SWA-LRef-1315-T07-C 1 1.75E+00 E
Zn SWA-LRef-1315-T08-C 1 2.07E+00 E
Zn SWA-LRef-1315-T09-C 1 1.06E+01
Zn SWA-LRef-1315-M01-A 1 5.00E-01 U1/2
Zn SWA-LRef-1315-M02-A 1 5.00E-01 U1/2
Zn SWA-LRef-1315-M03-A 1 5.00E-01 U1/2
Zn SWA-LRef-1315-M04-A 1 5.00E-01 U1/2
Zn SWA-LRef-1315-M05-A 1 5.00E-01 U1/2
Zn SWA-LRef-1315-M06-A 1 5.00E-01 U1/2
Zn SWA-LRef-1315-M07-A 1 5.00E-01 U1/2
Zn SWA-LRef-1315-M08-A 1 5.00E-01 U1/2
Zn SWA-LRef-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.11E+00 1.67 1.00 3.18
1.91E+01 0.91 1.00 3.18
1.50E+01 0.27 1.00 3.18 10000 1000
1.45E+01 0.24 1.00 3.18
1.33E+01 4.00 1.00 3.18
1.45E+01 0.62 1.00 3.18
1.77E+00 3.74 1.00 3.18
2.06E+00 7.06 1.00 3.18
1.86E+01 0.46 1.00 3.18
1.65E+00 13.83 1.00 3.18
3.51E+00 0.69 1.00 3.18
1.47E+01 0.80 1.00 3.18 10000 1000
1.45E+01 0.76 1.00 3.18
1.23E+01 2.61 1.00 3.18
1.47E+01 1.84 1.00 3.18
5.00E-01 11.61 1.00 3.18
5.00E-01 7.90 1.00 3.18
1.37E+01 3.55 1.00 3.18
5.00E-01 12.42 1.00 3.18
2.62E+00 1.28 1.00 3.18
1.45E+01 1.08 1.00 3.18 10000 1000
1.46E+01 1.29 1.00 3.18
1.40E+01 1.40 1.00 3.18
1.41E+01 1.65 1.00 3.18
1.75E+00 11.37 1.00 3.18
2.07E+00 7.43 1.00 3.18
1.06E+01 1.09 1.00 3.18
5.00E-01 0.26 1.00 3.18
5.00E-01 20.82 1.00 3.18
5.00E-01 0.57 1.00 3.18
5.00E-01 1.28 1.00 3.18
5.00E-01 0.31 1.00 3.18
5.00E-01 2.65 1.00 3.18
5.00E-01 12.79 1.00 3.18
5.00E-01 23.77 1.00 3.18
5.00E-01 4.36 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.72E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.48E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/14/11 4:17 PM EPA Interlab LRef 1315 SWA
3/14/11 4:19 PM EPA Interlab LRef 1315 SWA
3/14/11 4:20 PM EPA Interlab LRef 1315 SWA
3/14/11 4:22 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:24 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:25 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:27 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:28 PM EPA Interlab LRef 1315 SWA
3/14/11 4:30 PM EPA Interlab LRef 1315 SWA
3/14/11 4:32 PM EPA Interlab LRef 1315 SWA
3/14/11 4:33 PM EPA Interlab LRef 1315 SWA
3/14/1 1 4:35 PM EPA Interlab LRef 1315 SWA
3/14/11 4:37 PM EPA Interlab LRef 1315 SWA
3/14/11 4:38 PM EPA Interlab LRef 1315 SWA
3/14/11 4:40 PM EPA Interlab LRef 1315 SWA
3/14/11 4:42 PM EPA Interlab LRef 1315 SWA
3/14/11 4:43 PM EPA Interlab LRef 1315 SWA
3/14/11 4:45 PM EPA Interlab LRef 1315 SWA
3/15/11 10:28 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:30 AM EPA Interlab LRef 1315 SWA
3/15/11 10:32 AM EPA Interlab LRef 1315 SWA
3/15/11 10:33 AM EPA Interlab LRef 1315 SWA
3/15/11 10:35 AM EPA Interlab LRef 1315 SWA
3/15/11 10:37 AM EPA Interlab LRef 1315 SWA
3/15/11 10:38 AM EPA Interlab LRef 1315 SWA
3/15/11 10:40 AM EPA Interlab LRef 1315 SWA
3/15/11 10:41 AM EPA Interlab LRef 1315 SWA
3/14/1 1 2:57 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:30 PM EPA Interlab LRef 1315 SWA
3/14/11 2:58 PM EPA Interlab LRef 1315 SWA
3/14/1 1 3:00 PM EPA Interlab LRef 1315 SWA
3/14/11 3:01 PM EPA Interlab LRef 1315 SWA
3/14/11 3:24 PM EPA Interlab LRef 1315 SWA
3/14/11 3:25 PM EPA Interlab LRef 1315 SWA
3/14/11 3:27 PM EPA Interlab LRef 1315 SWA
3/14/11 3:29 PM EPA Interlab LRef 1315 SWA
1-728
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1315:
Dilut
Element Sample ID Fact
Al SWA-LRef-1315-T01-D
Al SWA-LRef-1315-T02-D
Al SWA-LRef-1315-T03-D
Al SWA-LRef-1315-T04-D
Al SWA-LRef-1315-T05-D
Al SWA-LRef-1315-T06-D
Al SWA-LRef-1315-T07-D
Al SWA-LRef-1315-T08-D
Al SWA-LRef-1315-T09-D
Al SWA-LRef-1315-T01-E
Al SWA-LRef-1315-T02-E
Al SWA-LRef-1315-T03-E
Al SWA-LRef-1315-T04-E
Al SWA-LRef-1315-T05-E
Al SWA-LRef-1315-T06-E
Al SWA-LRef-1315-T07-E
Al SWA-LRef-1315-T08-E
Al SWA-LRef-1315-T09-E
Al SWA-LRef-1315-T01-F
Al SWA-LRef-1315-T02-F
Al SWA-LRef-1315-T03-F
Al SWA-LRef-1315-T04-F
Al SWA-LRef-1315-T05-F
Al SWA-LRef-1315-T06-F
Al SWA-LRef-1315-T07-F
Al SWA-LRef-1315-T08-F
Al SWA-LRef-1315-T09-F
on Sample
or Cone. Quallf
ug/L
1 1.49E+03
1 3.92E+03
1 2.88E+03
1 4.59E+03
1 5.64E+03
1 4.44E+03
1 3.81 E+03
1 2.21 E+03
1 2.78E+03
1 1.27E+03
1 3.87E+03
1 2.81 E+03
1 5.90E+03
1 4.74E+03
1 4.58E+03
1 3.49E+03
1 2.36E+03
1 3.17E+03
1 7.53E+02
1 3.63E+03
1 2.54E+03
1 4.61 E+03
1 4.21 E+03
1 4.39E+03
1 3.30E+03
1 2.17E+03
1 2. 81 E+03
ICP-OES Spike Sol'n
er Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.49E+03 3.52 1.00 3.18
3.92E+03 2.46 1.00 3.18
2.88E+03 0.24 1.00 3.18 10000 1000
4.59E+03 2.26 1.00 3.18
5.64E+03 2.14 1.00 3.18
4.44E+03 1.11 1.00 3.18
3.81E+03 2.30 1.00 3.18
2.21E+03 1.43 1.00 3.18
2.78E+03 1.57 1.00 3.18
1.27E+03 14.88 1.00 3.18
3.87E+03 1.71 1.00 3.18
2.81E+03 2.02 1.00 3.18 10000 1000
5.90E+03 3.04 1.00 3.18
4.74E+03 1.88 1.00 3.18
4.58E+03 3.72 1.00 3.18
3.49E+03 1.09 1.00 3.18
2.36E+03 4.78 1.00 3.18
3.17E+03 2.69 1.00 3.18
7.53E+02 12.48 1.00 3.18
3.63E+03 2.13 1.00 3.18
2.54E+03 2.62 1.00 3.18 10000 1000
4.61E+03 1.71 1.00 3.18
4.21E+03 2.23 1.00 3.18
4.39E+03 2.52 1.00 3.18
3.30E+03 6.25 1.00 3.18
2.17E+03 5.94 1.00 3.18
2.81E+03 3.56 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.83E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.73E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.58E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/15/1 1 10:43 AM EPA Interlab LRef 1315 SWA
3/15/11 10:45 AM EPA Interlab LRef 1315 SWA
3/15/11 10:46 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:48 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:50 AM EPA Interlab LRef 1315 SWA
3/15/11 10:51 AM EPA Interlab LRef 1315 SWA
3/15/11 10:53 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:55 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:56 AM EPA Interlab LRef 1315 SWA
3/15/11 11:01 AM EPA Interlab LRef 1315 SWA
3/15/11 11:03 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :05 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :06 AM EPA Interlab LRef 1315 SWA
3/15/11 11:08 AM EPA Interlab LRef 1315 SWA
3/15/11 11:10 AM EPA Interlab LRef 1315 SWA
3/15/1111:11 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:13 AM EPA Interlab LRef 1315 SWA
3/15/11 11:15 AM EPA Interlab LRef 1315 SWA
3/15/11 11:16 AM EPA Interlab LRef 1315 SWA
3/15/11 11:18 AM EPA Interlab LRef 1315 SWA
3/15/11 11:19 AM EPA Interlab LRef 1315 SWA
3/15/11 11:21 AM EPA Interlab LRef 1315 SWA
3/15/11 11:23 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :24 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :26 AM EPA Interlab LRef 1315 SWA
3/15/11 11:28 AM EPA Interlab LRef 1315 SWA
3/15/11 11:29 AM EPA Interlab LRef 1315 SWA
1-729
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Sb SWA-LRef-1315-T01-D 1 1.27E+02
Sb SWA-LRef-1315-T02-D 1 4.41 E+02
Sb SWA-LRef-1315-T03-D 1 3.04E+02
Sb SWA-LRef-1315-T04-D 1 4.45E+02
Sb SWA-LRef-1315-T05-D 1 4.41 E+02
Sb SWA-LRef-1315-T06-D 1 4.53E+02
Sb SWA-LRef-1315-T07-D 1 3.63E+02
Sb SWA-LRef-1315-T08-D 1 2.67E+02
Sb SWA-LRef-1315-T09-D 1 2.41 E+02
Sb SWA-LRef-1315-T01-E 1 1.23E+02
Sb SWA-LRef-1315-T02-E 1 4.27E+02
Sb SWA-LRef-1315-T03-E 1 2.82E+02
Sb SWA-LRef-1315-T04-E 1 4.57E+02
Sb SWA-LRef-1315-T05-E 1 4.52E+02
Sb SWA-LRef-1315-T06-E 1 4.82E+02
Sb SWA-LRef-1315-T07-E 1 3.70E+02
Sb SWA-LRef-1315-T08-E 1 3.00E+02
Sb SWA-LRef-1315-T09-E 1 2.42E+02
Sb SWA-LRef-1315-T01-F 1 7.22E+01
Sb SWA-LRef-1315-T02-F 1 4.46E+02
Sb SWA-LRef-1315-T03-F 1 2.66E+02
Sb SWA-LRef-1315-T04-F 1 4.57E+02
Sb SWA-LRef-1315-T05-F 1 4.38E+02
Sb SWA-LRef-1315-T06-F 1 5.11E+02
Sb SWA-LRef-1315-T07-F 1 3.41 E+02
Sb SWA-LRef-1315-T08-F 1 2.63E+02
Sb SWA-LRef-1315-T09-F 1 2.24E+02
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.27E+02 3.52 7.50 23.90
4.41 E+02 2.46 7.50 23.90
3.04E+02 0.24 7.50 23.90 10000 1000
4.45E+02 2.26 7.50 23.90
4.41E+02 2.14 7.50 23.90
4.53E+02 1.11 7.50 23.90
3.63E+02 2.30 7.50 23.90
2.67E+02 1.43 7.50 23.90
2.41 E+02 1.57 7.50 23.90
1.23E+02 14.88 7.50 23.90
4.27E+02 1.71 7.50 23.90
2.82E+02 2.02 7.50 23.90 10000 1000
4.57E+02 3.04 7.50 23.90
4.52E+02 1.88 7.50 23.90
4.82E+02 3.72 7.50 23.90
3.70E+02 1.09 7.50 23.90
3.00E+02 4.78 7.50 23.90
2.42E+02 2.69 7.50 23.90
7.22E+01 12.48 7.50 23.90
4.46E+02 2.13 7.50 23.90
2.66E+02 2.62 7.50 23.90 10000 1000
4.57E+02 1.71 7.50 23.90
4.38E+02 2.23 7.50 23.90
5.11E+02 2.52 7.50 23.90
3.41E+02 6.25 7.50 23.90
2.63E+02 5.94 7.50 23.90
2.24E+02 3.56 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.34E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.23E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.22E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/3/11 2:01 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:02 PM EPA Interlab LRef 1315 SWA
11/3/11 2:04 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:06 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:07 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:09 PM EPA Interlab LRef 1315 SWA
11/3/11 2:11 PM EPA Interlab LRef 131 5 SWA
11/3/11 2:12 PM EPA Interlab LRef 131 5 SWA
11/3/11 2:14 PM EPA Interlab LRef 1315 SWA
11/3/11 2:19 PM EPA Interlab LRef 1315 SWA
11/3/11 2:21 PM EPA Interlab LRef 131 5 SWA
11/3/11 2:22 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:24 PM EPA Interlab LRef 1315 SWA
11/3/11 2:26 PM EPA Interlab LRef 1315 SWA
11/3/11 2:27 PM EPA Interlab LRef 1315 SWA
11/3/11 2:29 PM EPA Interlab LRef 1315 SWA
11/3/11 2:31 PM EPA Interlab LRef 1315 SWA
11/3/11 2:32 PM EPA Interlab LRef 1315 SWA
11/3/11 2:34 PM EPA Interlab LRef 1315 SWA
11/3/11 2:36 PM EPA Interlab LRef 1315 SWA
11/3/11 2:37 PM EPA Interlab LRef 1315 SWA
11/3/11 2:39 PM EPA Interlab LRef 1315 SWA
11/3/11 2:41 PM EPA Interlab LRef 1315 SWA
11/3/11 2:42 PM EPA Interlab LRef 1315 SWA
11/3/11 2:44 PM EPA Interlab LRef 1315 SWA
11/3/11 2:46 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:47 PM EPA Interlab LRef 1315 SWA
1-730
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
As SWA-LRef-1315-T01-D 1 1.20E+02
As SWA-LRef-1315-T02-D 1 1.55E+02
As SWA-LRef-1315-T03-D 1 1.64E+02
As SWA-LRef-1315-T04-D 1 1.98E+02
As SWA-LRef-1315-T05-D 1 2.11E+02
As SWA-LRef-1315-T06-D 1 1.64E+02
As SWA-LRef-1315-T07-D 1 1.57E+02
As SWA-LRef-1315-T08-D 1 7.92E+01
As SWA-LRef-1315-T09-D 1 1.20E+02
As SWA-LRef-1315-T01-E 1 1.07E+02
As SWA-LRef-1315-T02-E 1 2.69E+02
As SWA-LRef-1315-T03-E 1 2.00E+02
As SWA-LRef-1315-T04-E 1 4.23E+02
As SWA-LRef-1315-T05-E 1 2.24E+02
As SWA-LRef-1315-T06-E 1 1.74E+02
As SWA-LRef-1315-T07-E 1 1.36E+02
As SWA-LRef-1315-T08-E 1 9.74E+01
As SWA-LRef-1315-T09-E 1 1.14E+02
As SWA-LRef-1315-T01-F 1 8.45E+01
As SWA-LRef-1315-T02-F 1 1.51E+02
As SWA-LRef-1315-T03-F 1 1.32E+02
As SWA-LRef-1315-T04-F 1 2.09E+02
As SWA-LRef-1315-T05-F 1 1.62E+02
As SWA-LRef-1315-T06-F 1 1.66E+02
As SWA-LRef-1315-T07-F 1 1.23E+02
As SWA-LRef-1315-T08-F 1 8.09E+01
As SWA-LRef-1315-T09-F 1 1.13E+02
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.20E+02 4.81 11.00 35.00
1.55E+02 2.80 11.00 35.00
1.64E+02 6.21 11.00 35.00 10000 1000
1.98E+02 2.49 11.00 35.00
2.11E+02 1.92 11.00 35.00
1.64E+02 0.86 11.00 35.00
1.57E+02 0.27 11.00 35.00
7.92E+01 12.37 11.00 35.00
1.20E+02 5.78 11.00 35.00
1.07E+02 6.35 11.00 35.00
2.69E+02 2.04 11.00 35.00
2.00E+02 1.67 11.00 35.00 10000 1000
4.23E+02 3.53 11.00 35.00
2.24E+02 2.79 11.00 35.00
1.74E+02 3.59 11.00 35.00
1.36E+02 2.57 11.00 35.00
9.74E+01 6.80 11.00 35.00
1.14E+02 8.15 11.00 35.00
8.45E+01 2.55 11.00 35.00
1.51E+02 4.83 11.00 35.00
1.32E+02 2.68 11.00 35.00 10000 1000
2.09E+02 2.26 11.00 35.00
1.62E+02 2.99 11.00 35.00
1.66E+02 3.96 11.00 35.00
1.23E+02 4.28 11.00 35.00
8.09E+01 6.81 11.00 35.00
1.13E+02 5.66 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 . 1 9E+03 1 03% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/15/1 1 10:43 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:45 AM EPA Interlab LRef 1315 SWA
3/15/11 10:46 AM EPA Interlab LRef 1315 SWA
3/15/11 10:48 AM EPA Interlab LRef 1315 SWA
3/15/11 10:50 AM EPA Interlab LRef 1315 SWA
3/15/11 10:51 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:53 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:55 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:56 AM EPA Interlab LRef 1315 SWA
3/15/11 11:01 AM EPA Interlab LRef 1315 SWA
3/15/11 11:03 AM EPA Interlab LRef 1315 SWA
3/15/11 11:05 AM EPA Interlab LRef 1315 SWA
3/15/11 11:06 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :08 AM EPA Interlab LRef 1315 SWA
3/15/11 11:10 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :1 1 AM EPA Interlab LRef 1315 SWA
3/15/11 11:13 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :15 AM EPA Interlab LRef 1315 SWA
3/15/11 11:16 AM EPA Interlab LRef 1315 SWA
3/15/11 11:18 AM EPA Interlab LRef 1315 SWA
3/15/11 11:19 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :21 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :23 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :24 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :26 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :28 AM EPA Interlab LRef 1315 SWA
3/15/11 11:29 AM EPA Interlab LRef 1315 SWA
1-731
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
B SWA-LRef-1315-T01-D 1 5.29E+01
B SWA-LRef-1315-T02-D 1 9.03E+01
B SWA-LRef-1315-T03-D 1 4.40E+01
B SWA-LRef-1315-T04-D 1 6.22E+01
B SWA-LRef-1315-T05-D 1 6.81E+01
B SWA-LRef-1315-T06-D 1 7.82E+01
B SWA-LRef-1315-T07-D 1 8.38E+01
B SWA-LRef-1315-T08-D 1 7.48E+01
B SWA-LRef-1315-T09-D 1 4.68E+01
B SWA-LRef-1315-T01-E 1 4.39E+01
B SWA-LRef-1315-T02-E 1 9.20E+01
B SWA-LRef-1315-T03-E 1 4.78E+01
B SWA-LRef-1315-T04-E 1 6.12E+01
B SWA-LRef-1315-T05-E 1 5.37E+01
B SWA-LRef-1315-T06-E 1 8.16E+01
B SWA-LRef-1315-T07-E 1 7.28E+01
B SWA-LRef-1315-T08-E 1 6.84E+01
B SWA-LRef-1315-T09-E 1 4.59E+01
B SWA-LRef-1315-T01-F 1 3.95E+01
B SWA-LRef-1315-T02-F 1 9.24E+01
B SWA-LRef-1315-T03-F 1 4.37E+01
B SWA-LRef-1315-T04-F 1 7.17E+01
B SWA-LRef-1315-T05-F 1 5.65E+01
B SWA-LRef-1315-T06-F 1 8.24E+01
B SWA-LRef-1315-T07-F 1 7.54E+01
B SWA-LRef-1315-T08-F 1 7.37E+01
B SWA-LRef-1315-T09-F 1 4.79E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.29E+01 2.66 1.00 3.18
9.03E+01 11.48 1.00 3.18
4.40E+01 0.38 1.00 3.18 10000 1000
6.22E+01 2.96 1.00 3.18
6.81E+01 1.30 1.00 3.18
7.82E+01 4.61 1.00 3.18
8.38E+01 3.68 1.00 3.18
7.48E+01 3.38 1.00 3.18
4.68E+01 3.09 1.00 3.18
4.39E+01 4.81 1.00 3.18
9.20E+01 3.00 1.00 3.18
4.78E+01 1.48 1.00 3.18 10000 1000
6.12E+01 1.86 1.00 3.18
5.37E+01 3.79 1.00 3.18
8.16E+01 2.40 1.00 3.18
7.28E+01 1.78 1.00 3.18
6.84E+01 1.48 1.00 3.18
4.59E+01 1.82 1.00 3.18
3.95E+01 1.94 1.00 3.18
9.24E+01 1.84 1.00 3.18
4.37E+01 4.53 1.00 3.18 10000 1000
7.17E+01 3.92 1.00 3.18
5.65E+01 1.35 1.00 3.18
8.24E+01 2.07 1.00 3.18
7.54E+01 0.83 1.00 3.18
7.37E+01 2.83 1.00 3.18
4.79E+01 2.38 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.05E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.69E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/3/11 2:01 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:02 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:04 PM EPA Interlab LRef 1315 SWA
11/3/11 2:06 PM EPA Interlab LRef 1315 SWA
11/3/11 2:07 PM EPA Interlab LRef 1315 SWA
11/3/11 2:09 PM EPA Interlab LRef 1315 SWA
11/3/11 2:11 PM EPA Interlab LRef 1315 SWA
11/3/11 2:12 PM EPA Interlab LRef 1315 SWA
11/3/11 2:14 PM EPA Interlab LRef 1315 SWA
11/3/11 2:19 PM EPA Interlab LRef 1315 SWA
11/3/11 2:21 PM EPA Interlab LRef 1315 SWA
11/3/11 2:22 PM EPA Interlab LRef 1315 SWA
11/3/11 2:24 PM EPA Interlab LRef 1315 SWA
11/3/11 2:26 PM EPA Interlab LRef 1315 SWA
11/3/11 2:27 PM EPA Interlab LRef 1315 SWA
11/3/11 2:29 PM EPA Interlab LRef 1315 SWA
11/3/11 2:31 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:32 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:34 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:36 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:37 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:39 PM EPA Interlab LRef 1315 SWA
11/3/11 2:41 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:42 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:44 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:46 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:47 PM EPA Interlab LRef 1315 SWA
1-732
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
Ba SWA-LRef-1315-T01-D 1 1.86E+01
Ba SWA-LRef-1315-T02-D 1 2.01 E+02
Ba SWA-LRef-1315-T03-D 1 2.66E+02
Ba SWA-LRef-1315-T04-D 1 4.22E+02
Ba SWA-LRef-1315-T05-D 1 3.52E+02
Ba SWA-LRef-1315-T06-D 1 4.71E+02
Ba SWA-LRef-1315-T07-D 1 3.85E+02
Ba SWA-LRef-1315-T08-D 1 4.21E+02
Ba SWA-LRef-1315-T09-D 1 3.44E+02
Ba SWA-LRef-1315-T01-E 1 1.70E+01
Ba SWA-LRef-1315-T02-E 1 4.03E+02
Ba SWA-LRef-1315-T03-E 1 1.99E+02
Ba SWA-LRef-1315-T04-E 1 2.93E+02
Ba SWA-LRef-1315-T05-E 1 3.17E+02
Ba SWA-LRef-1315-T06-E 1 5.05E+02
Ba SWA-LRef-1315-T07-E 1 4.45E+02
Ba SWA-LRef-1315-T08-E 1 4.06E+02
Ba SWA-LRef-1315-T09-E 1 4.18E+02
Ba SWA-LRef-1315-T01-F 1 1.54E+01
Ba SWA-LRef-1315-T02-F 1 1.91 E+02
Ba SWA-LRef-1315-T03-F 1 1.93E+02
Ba SWA-LRef-1315-T04-F 1 3.38E+02
Ba SWA-LRef-1315-T05-F 1 4.03E+02
Ba SWA-LRef-1315-T06-F 1 5.68E+02
Ba SWA-LRef-1315-T07-F 1 5.35E+02
Ba SWA-LRef-1315-T08-F 1 4.84E+02
Ba SWA-LRef-1315-T09-F 1 4.35E+02
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.86E+01 0.07 1.00 3.18
2.01E+02 1.68 1.00 3.18
2.66E+02 0.72 1.00 3.18 10000 1000
4.22E+02 0.50 1.00 3.18
3.52E+02 0.24 1.00 3.18
4.71E+02 0.41 1.00 3.18
3.85E+02 0.56 1.00 3.18
4.21E+02 1.41 1.00 3.18
3.44E+02 0.53 1.00 3.18
1.70E+01 0.42 1.00 3.18
4.03E+02 0.91 1.00 3.18
1.99E+02 0.55 1.00 3.18 10000 1000
2.93E+02 0.75 1.00 3.18
3.17E+02 0.24 1.00 3.18
5.05E+02 1.88 1.00 3.18
4.45E+02 1.25 1.00 3.18
4.06E+02 1.37 1.00 3.18
4.18E+02 0.59 1.00 3.18
1.54E+01 0.22 1.00 3.18
1.91E+02 0.42 1.00 3.18
1.93E+02 0.23 1.00 3.18 10000 1000
3.38E+02 0.99 1.00 3.18
4.03E+02 1.64 1.00 3.18
5.68E+02 6.89 1.00 3.18
5.35E+02 0.78 1.00 3.18
4.84E+02 0.61 1.00 3.18
4.35E+02 0.46 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.29E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.27E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/15/1 1 10:43 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:45 AM EPA Interlab LRef 1315 SWA
3/15/11 10:46 AM EPA Interlab LRef 1315 SWA
3/15/11 10:48 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:50 AM EPA Interlab LRef 1315 SWA
3/15/11 10:51 AM EPA Interlab LRef 1315 SWA
3/15/11 10:53 AM EPA Interlab LRef 1315 SWA
3/15/11 10:55 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:56 AM EPA Interlab LRef 1315 SWA
3/15/11 11:01 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:03 AM EPA Interlab LRef 1315 SWA
3/15/11 11:05 AM EPA Interlab LRef 1315 SWA
3/15/11 11:06 AM EPA Interlab LRef 1315 SWA
3/15/11 11:08 AM EPA Interlab LRef 1315 SWA
3/15/11 11:10 AM EPA Interlab LRef 1315 SWA
3/15/11 11:11 AM EPA Interlab LRef 1315 SWA
3/15/11 11:13 AM EPA Interlab LRef 1315 SWA
3/15/11 11:15 AM EPA Interlab LRef 1315 SWA
3/15/11 11:16AM EPA Interlab LRef 1315 SWA
3/15/11 11:18AM EPA Interlab LRef 1315 SWA
3/15/11 11:19 AM EPA Interlab LRef 1315 SWA
3/15/11 11:21 AM EPA Interlab LRef 1315 SWA
3/15/11 11:23 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :24 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :26 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :28 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :29 AM EPA Interlab LRef 1315 SWA
1-733
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Be SWA-LRef-1315-T01-D 1 9.50E-01 U1/2
Be SWA-LRef-1315-T02-D 1 9.50E-01 U1/2
Be SWA-LRef-1315-T03-D 1 9.50E-01 U1/2
Be SWA-LRef-1315-T04-D 1 9.50E-01 U1/2
Be SWA-LRef-1315-T05-D 1 9.50E-01 U1/2
Be SWA-LRef-1315-T06-D 1 9.50E-01 U1/2
Be SWA-LRef-1315-T07-D 1 9.50E-01 U1/2
Be SWA-LRef-1315-T08-D 1 9.50E-01 U1/2
Be SWA-LRef-1315-T09-D 1 9.50E-01 U1/2
Be SWA-LRef-1315-T01-E 1 9.50E-01 U1/2
Be SWA-LRef-1315-T02-E 1 9.50E-01 U1/2
Be SWA-LRef-1315-T03-E 1 9.50E-01 U1/2
Be SWA-LRef-1315-T04-E 1 9.50E-01 U1/2
Be SWA-LRef-1315-T05-E 1 9.50E-01 U1/2
Be SWA-LRef-1315-T06-E 1 9.50E-01 U1/2
Be SWA-LRef-1315-T07-E 1 9.50E-01 U1/2
Be SWA-LRef-1315-T08-E 1 9.50E-01 U1/2
Be SWA-LRef-1315-T09-E 1 9.50E-01 U1/2
Be SWA-LRef-1315-T01-F 1 9.50E-01 U1/2
Be SWA-LRef-1315-T02-F 1 9.50E-01 U1/2
Be SWA-LRef-1315-T03-F 1 9.50E-01 U1/2
Be SWA-LRef-1315-T04-F 1 9.50E-01 U1/2
Be SWA-LRef-1315-T05-F 1 9.50E-01 U1/2
Be SWA-LRef-1315-T06-F 1 9.50E-01 U1/2
Be SWA-LRef-1315-T07-F 1 9.50E-01 U1/2
Be SWA-LRef-1315-T08-F 1 9.50E-01 U1/2
Be SWA-LRef-1315-T09-F 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 58.07 1.90 6.00
9.50E-01 24.43 1.90 6.00
9.50E-01 48.99 1.90 6.00 10000 1000
9.50E-01 24.16 1.90 6.00
9.50E-01 15.51 1.90 6.00
9.50E-01 43.06 1.90 6.00
9.50E-01 42.51 1.90 6.00
9.50E-01 73.41 1.90 6.00
9.50E-01 36.07 1.90 6.00
9.50E-01 3.75 1.90 6.00
9.50E-01 19.72 1.90 6.00
9.50E-01 14.60 1.90 6.00 10000 1000
9.50E-01 11.44 1.90 6.00
9.50E-01 31.82 1.90 6.00
9.50E-01 62.56 1.90 6.00
9.50E-01 77.94 1.90 6.00
9.50E-01 32.41 1.90 6.00
9.50E-01 41.01 1.90 6.00
9.50E-01 43.54 1.90 6.00
9.50E-01 12.31 1.90 6.00
9.50E-01 38.82 1.90 6.00 10000 1000
9.50E-01 55.97 1.90 6.00
9.50E-01 44.26 1.90 6.00
9.50E-01 62.09 1.90 6.00
9.50E-01 36.30 1.90 6.00
9.50E-01 40.77 1.90 6.00
9.50E-01 72.36 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.84E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/15/1 1 10:43 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:45 AM EPA Interlab LRef 1315 SWA
3/15/11 10:46 AM EPA Interlab LRef 1315 SWA
3/15/11 10:48 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:50 AM EPA Interlab LRef 1315 SWA
3/15/11 10:51 AM EPA Interlab LRef 1315 SWA
3/15/11 10:53 AM EPA Interlab LRef 1315 SWA
3/15/11 10:55 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:56 AM EPA Interlab LRef 1315 SWA
3/15/11 11:01 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:03 AM EPA Interlab LRef 1315 SWA
3/15/11 11:05 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :06 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :08 AM EPA Interlab LRef 1315 SWA
3/15/11 11:10 AM EPA Interlab LRef 1315 SWA
3/15/11 11:11 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:13AM EPA Interlab LRef 1315 SWA
3/15/11 11:15 AM EPA Interlab LRef 1315 SWA
3/15/11 11:16 AM EPA Interlab LRef 1315 SWA
3/15/11 11:18 AM EPA Interlab LRef 1315 SWA
3/15/11 11:19 AM EPA Interlab LRef 1315 SWA
3/15/11 11:21 AM EPA Interlab LRef 1315 SWA
3/15/11 11:23 AM EPA Interlab LRef 1315 SWA
3/15/11 11:24 AM EPA Interlab LRef 1315 SWA
3/15/11 11:26 AM EPA Interlab LRef 1315 SWA
3/15/11 11:28 AM EPA Interlab LRef 1315 SWA
3/15/11 11:29 AM EPA Interlab LRef 1315 SWA
1-734
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cd SWA-LRef-1315-T01-D 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T02-D 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T03-D 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T04-D 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T05-D 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T06-D 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T07-D 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T08-D 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T09-D 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T01-E 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T02-E 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T03-E 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T04-E 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T05-E 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T06-E 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T07-E 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T08-E 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T09-E 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T01-F 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T02-F 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T03-F 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T04-F 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T05-F 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T06-F 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T07-F 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T08-F 1 1.10E+00 U1/2
Cd SWA-LRef-1315-T09-F 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+00 47.87 2.20 7.00
1.10E+00 29.44 2.20 7.00
1.10E+00 47.76 2.20 7.00 10000 1000
1.10E+00 29.45 2.20 7.00
1.10E+00 61.03 2.20 7.00
1.10E+00 41.15 2.20 7.00
1.10E+00 37.77 2.20 7.00
1.10E+00 40.60 2.20 7.00
1.10E+00 30.33 2.20 7.00
1.10E+00 51.20 2.20 7.00
1.10E+00 51.43 2.20 7.00
1.10E+00 30.23 2.20 7.00 10000 1000
1.10E+00 23.64 2.20 7.00
1.10E+00 29.12 2.20 7.00
1.10E+00 55.79 2.20 7.00
1.10E+00 29.19 2.20 7.00
1.10E+00 65.52 2.20 7.00
1.10E+00 92.90 2.20 7.00
1.10E+00 53.11 2.20 7.00
1.10E+00 48.01 2.20 7.00
1.10E+00 47.08 2.20 7.00 10000 1000
1.10E+00 66.52 2.20 7.00
1.10E+00 32.91 2.20 7.00
1.10E+00 63.83 2.20 7.00
1.10E+00 73.97 2.20 7.00
1.10E+00 9.08 2.20 7.00
1.10E+00 35.68 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.05E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.71E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/15/1 1 10:43 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:45 AM EPA Interlab LRef 1315 SWA
3/15/11 10:46 AM EPA Interlab LRef 1315 SWA
3/15/11 10:48 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:50 AM EPA Interlab LRef 1315 SWA
3/15/11 10:51 AM EPA Interlab LRef 1315 SWA
3/15/11 10:53 AM EPA Interlab LRef 1315 SWA
3/15/11 10:55 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:56 AM EPA Interlab LRef 1315 SWA
3/15/11 11:01 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:03 AM EPA Interlab LRef 1315 SWA
3/15/11 11:05 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :06 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :08 AM EPA Interlab LRef 1315 SWA
3/15/11 11:10 AM EPA Interlab LRef 1315 SWA
3/15/11 11:11 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:13 AM EPA Interlab LRef 1315 SWA
3/15/11 11:15 AM EPA Interlab LRef 1315 SWA
3/15/11 11:16 AM EPA Interlab LRef 1315 SWA
3/15/11 11:18 AM EPA Interlab LRef 1315 SWA
3/15/11 11:19 AM EPA Interlab LRef 1315 SWA
3/15/11 11:21 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:23 AM EPA Interlab LRef 1315 SWA
3/15/11 11:24 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :26 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :28 AM EPA Interlab LRef 1315 SWA
3/15/11 11:29 AM EPA Interlab LRef 1315 SWA
1-735
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Ca SWA-LRef-1315-T01-D 1 2.33E+03
Ca SWA-LRef-1315-T02-D 1 1.45E+04
Ca SWA-LRef-1315-T03-D 1 1.47E+04
Ca SWA-LRef-1315-T04-D 1 2.36E+04
Ca SWA-LRef-1315-T05-D 1 3.08E+04
Ca SWA-LRef-1315-T06-D 1 2.78E+04
Ca SWA-LRef-1315-T07-D 1 2.14E+04
Ca SWA-LRef-1315-T08-D 1 2.33E+04
Ca SWA-LRef-1315-T09-D 1 2.07E+04
Ca SWA-LRef-1315-T01-E 1 2.11E+03
Ca SWA-LRef-1315-T02-E 1 1.21E+04
Ca SWA-LRef-1315-T03-E 1 1.32E+04
Ca SWA-LRef-1315-T04-E 1 3.01 E+04
Ca SWA-LRef-1315-T05-E 1 2.49E+04
Ca SWA-LRef-1315-T06-E 1 2.84E+04
Ca SWA-LRef-1315-T07-E 1 2.68E+04
Ca SWA-LRef-1315-T08-E 1 2.23E+04
Ca SWA-LRef-1315-T09-E 1 2.39E+04
Ca SWA-LRef-1315-T01-F 1 1.19E+03
Ca SWA-LRef-1315-T02-F 1 1.40E+04
Ca SWA-LRef-1315-T03-F 1 1.45E+04
Ca SWA-LRef-1315-T04-F 1 2.45E+04
Ca SWA-LRef-1315-T05-F 1 2.61E+04
Ca SWA-LRef-1315-T06-F 1 2.96E+04
Ca SWA-LRef-1315-T07-F 1 2.77E+04
Ca SWA-LRef-1315-T08-F 1 2.35E+04
Ca SWA-LRef-1315-T09-F 1 2.35E+04
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.33E+03 0.81 2.60 8.30
1.45E+04 7.28 2.60 8.30
1.47E+04 0.45 2.60 8.30 10000 1000
2.36E+04 0.52 2.60 8.30
3.08E+04 0.08 2.60 8.30
2.78E+04 0.84 2.60 8.30
2.14E+04 0.57 2.60 8.30
2.33E+04 1.26 2.60 8.30
2.07E+04 1.01 2.60 8.30
2.11E+03 0.64 2.60 8.30
1.21 E+04 0.33 2.60 8.30
1.32E+04 0.43 2.60 8.30 10000 1000
3.01 E+04 0.72 2.60 8.30
2.49E+04 0.38 2.60 8.30
2.84E+04 0.80 2.60 8.30
2.68E+04 0.28 2.60 8.30
2.23E+04 1.61 2.60 8.30
2.39E+04 0.83 2.60 8.30
1.19E+03 1.34 2.60 8.30
1.40E+04 0.42 2.60 8.30
1.45E+04 0.37 2.60 8.30 10000 1000
2.45E+04 1.04 2.60 8.30
2.61 E+04 1.65 2.60 8.30
2.96E+04 0.96 2.60 8.30
2.77E+04 0.49 2.60 8.30
2.35E+04 0.42 2.60 8.30
2.35E+04 0.36 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.56E+04 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.41 E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.55E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/15/1 1 10:43 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:45 AM EPA Interlab LRef 1315 SWA
3/15/11 10:46 AM EPA Interlab LRef 1315 SWA
3/15/11 10:48 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:50 AM EPA Interlab LRef 1315 SWA
3/15/11 10:51 AM EPA Interlab LRef 1315 SWA
3/15/11 10:53 AM EPA Interlab LRef 1315 SWA
3/15/11 10:55 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:56 AM EPA Interlab LRef 1315 SWA
3/15/11 11:01 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:03 AM EPA Interlab LRef 1315 SWA
3/15/11 11:05 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :06 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :08 AM EPA Interlab LRef 1315 SWA
3/15/11 11:10 AM EPA Interlab LRef 1315 SWA
3/15/11 11:11 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:13 AM EPA Interlab LRef 1315 SWA
3/15/11 11:15 AM EPA Interlab LRef 1315 SWA
3/15/11 11:16 AM EPA Interlab LRef 1315 SWA
3/15/11 11:18 AM EPA Interlab LRef 1315 SWA
3/15/11 11:19 AM EPA Interlab LRef 1315 SWA
3/15/11 11:21 AM EPA Interlab LRef 1315 SWA
3/15/11 11:23 AM EPA Interlab LRef 1315 SWA
3/15/11 11:24 AM EPA Interlab LRef 1315 SWA
3/15/11 11:26 AM EPA Interlab LRef 1315 SWA
3/15/11 11:28 AM EPA Interlab LRef 1315 SWA
3/15/11 11:29 AM EPA Interlab LRef 1315 SWA
1-736
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Cr SWA-LRef-1315-T01-D 1 2.33E+01
Cr SWA-LRef-1315-T02-D 1 4.80E+01
Cr SWA-LRef-1315-T03-D 1 2.43E+01
Cr SWA-LRef-1315-T04-D 1 3.79E+01
Cr SWA-LRef-1315-T05-D 1 6.39E+01
Cr SWA-LRef-1315-T06-D 1 5.73E+01
Cr SWA-LRef-1315-T07-D 1 5.03E+01
Cr SWA-LRef-1315-T08-D 1 3.52E+01
Cr SWA-LRef-1315-T09-D 1 4.59E+01
Cr SWA-LRef-1315-T01-E 1 3.38E+01
Cr SWA-LRef-1315-T02-E 1 5.25E+01
Cr SWA-LRef-1315-T03-E 1 2.56E+01
Cr SWA-LRef-1315-T04-E 1 3.83E+01
Cr SWA-LRef-1315-T05-E 1 4.83E+01
Cr SWA-LRef-1315-T06-E 1 5.61E+01
Cr SWA-LRef-1315-T07-E 1 4.72E+01
Cr SWA-LRef-1315-T08-E 1 3.68E+01
Cr SWA-LRef-1315-T09-E 1 4.70E+01
Cr SWA-LRef-1315-T01-F 1 1.75E+01
Cr SWA-LRef-1315-T02-F 1 4.57E+01
Cr SWA-LRef-1315-T03-F 1 2.82E+01
Cr SWA-LRef-1315-T04-F 1 4.26E+01
Cr SWA-LRef-1315-T05-F 1 4.10E+01
Cr SWA-LRef-1315-T06-F 1 4.09E+01
Cr SWA-LRef-1315-T07-F 1 4.43E+01
Cr SWA-LRef-1315-T08-F 1 3.28E+01
Cr SWA-LRef-1315-T09-F 1 4.44E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.33E+01 2.07 1.20 3.82
4.80E+01 8.37 1.20 3.82
2.43E+01 2.09 1.20 3.82 10000 1000
3.79E+01 1.82 1.20 3.82
6.39E+01 1.24 1.20 3.82
5.73E+01 0.39 1.20 3.82
5.03E+01 1.01 1.20 3.82
3.52E+01 0.19 1.20 3.82
4.59E+01 0.80 1.20 3.82
3.38E+01 1.11 1.20 3.82
5.25E+01 0.84 1.20 3.82
2.56E+01 3.00 1.20 3.82 10000 1000
3.83E+01 2.11 1.20 3.82
4.83E+01 0.50 1.20 3.82
5.61E+01 0.52 1.20 3.82
4.72E+01 0.79 1.20 3.82
3.68E+01 1.21 1.20 3.82
4.70E+01 2.20 1.20 3.82
1.75E+01 3.02 1.20 3.82
4.57E+01 1.63 1.20 3.82
2.82E+01 0.98 1.20 3.82 10000 1000
4.26E+01 0.97 1.20 3.82
4.10E+01 0.26 1.20 3.82
4.09E+01 3.33 1.20 3.82
4.43E+01 0.53 1.20 3.82
3.28E+01 2.60 1.20 3.82
4.44E+01 1.50 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.06E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.96E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/15/1 1 10:43 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:45 AM EPA Interlab LRef 1315 SWA
3/15/11 10:46 AM EPA Interlab LRef 1315 SWA
3/15/11 10:48 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:50 AM EPA Interlab LRef 1315 SWA
3/15/11 10:51 AM EPA Interlab LRef 1315 SWA
3/15/11 10:53 AM EPA Interlab LRef 1315 SWA
3/15/11 10:55 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:56 AM EPA Interlab LRef 1315 SWA
3/15/11 11:01 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:03 AM EPA Interlab LRef 1315 SWA
3/15/11 11:05 AM EPA Interlab LRef 1315 SWA
3/15/11 11:06 AM EPA Interlab LRef 1315 SWA
3/15/11 11:08 AM EPA Interlab LRef 1315 SWA
3/15/11 11:10 AM EPA Interlab LRef 1315 SWA
3/15/11 11:11 AM EPA Interlab LRef 1315 SWA
3/15/11 11:13 AM EPA Interlab LRef 1315 SWA
3/15/11 11:15 AM EPA Interlab LRef 1315 SWA
3/15/11 11:16AM EPA Interlab LRef 1315 SWA
3/15/11 11:18AM EPA Interlab LRef 1315 SWA
3/15/11 11:19 AM EPA Interlab LRef 1315 SWA
3/15/11 11:21 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :23 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :24 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :26 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :28 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :29 AM EPA Interlab LRef 1315 SWA
1-737
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Co SWA-LRef-1315-T01-D 1 9.00E-01 U1/2
Co SWA-LRef-1315-T02-D 1 9.00E-01 U1/2
Co SWA-LRef-1315-T03-D 1 9.00E-01 U1/2
Co SWA-LRef-1315-T04-D 1 9.00E-01 U1/2
Co SWA-LRef-1315-T05-D 1 9.00E-01 U1/2
Co SWA-LRef-1315-T06-D 1 9.00E-01 U1/2
Co SWA-LRef-1315-T07-D 1 9.00E-01 U1/2
Co SWA-LRef-1315-T08-D 1 9.00E-01 U1/2
Co SWA-LRef-1315-T09-D 1 9.00E-01 U1/2
Co SWA-LRef-1315-T01-E 1 9.00E-01 U1/2
Co SWA-LRef-1315-T02-E 1 9.00E-01 U1/2
Co SWA-LRef-1315-T03-E 1 9.00E-01 U1/2
Co SWA-LRef-1315-T04-E 1 9.00E-01 U1/2
Co SWA-LRef-1315-T05-E 1 9.00E-01 U1/2
Co SWA-LRef-1315-T06-E 1 9.00E-01 U1/2
Co SWA-LRef-1315-T07-E 1 9.00E-01 U1/2
Co SWA-LRef-1315-T08-E 1 9.00E-01 U1/2
Co SWA-LRef-1315-T09-E 1 9.00E-01 U1/2
Co SWA-LRef-1315-T01-F 1 9.00E-01 U1/2
Co SWA-LRef-1315-T02-F 1 9.00E-01 U1/2
Co SWA-LRef-1315-T03-F 1 9.00E-01 U1/2
Co SWA-LRef-1315-T04-F 1 9.00E-01 U1/2
Co SWA-LRef-1315-T05-F 1 9.00E-01 U1/2
Co SWA-LRef-1315-T06-F 1 9.00E-01 U1/2
Co SWA-LRef-1315-T07-F 1 9.00E-01 U1/2
Co SWA-LRef-1315-T08-F 1 9.00E-01 U1/2
Co SWA-LRef-1315-T09-F 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 59.85 1.80 5.72
9.00E-01 29.07 1.80 5.72
9.00E-01 25.56 1.80 5.72 10000 1000
9.00E-01 41.54 1.80 5.72
9.00E-01 26.21 1.80 5.72
9.00E-01 29.55 1.80 5.72
9.00E-01 62.04 1.80 5.72
9.00E-01 49.82 1.80 5.72
9.00E-01 12.46 1.80 5.72
9.00E-01 51.68 1.80 5.72
9.00E-01 66.76 1.80 5.72
9.00E-01 64.62 1.80 5.72 10000 1000
9.00E-01 27.83 1.80 5.72
9.00E-01 22.92 1.80 5.72
9.00E-01 15.39 1.80 5.72
9.00E-01 43.47 1.80 5.72
9.00E-01 46.95 1.80 5.72
9.00E-01 46.90 1.80 5.72
9.00E-01 40.28 1.80 5.72
9.00E-01 48.02 1.80 5.72
9.00E-01 27.86 1.80 5.72 10000 1000
9.00E-01 84.34 1.80 5.72
9.00E-01 72.26 1.80 5.72
9.00E-01 1.06 1.80 5.72
9.00E-01 24.39 1.80 5.72
9.00E-01 13.12 1.80 5.72
9.00E-01 42.12 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.33E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/15/1 1 10:43 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:45 AM EPA Interlab LRef 1315 SWA
3/15/11 10:46 AM EPA Interlab LRef 1315 SWA
3/15/11 10:48 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:50 AM EPA Interlab LRef 1315 SWA
3/15/11 10:51 AM EPA Interlab LRef 1315 SWA
3/15/11 10:53 AM EPA Interlab LRef 1315 SWA
3/15/11 10:55 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:56 AM EPA Interlab LRef 1315 SWA
3/15/11 11:01 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:03 AM EPA Interlab LRef 1315 SWA
3/15/11 11:05 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :06 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :08 AM EPA Interlab LRef 1315 SWA
3/15/11 11:10 AM EPA Interlab LRef 1315 SWA
3/15/11 11:11 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:13 AM EPA Interlab LRef 1315 SWA
3/15/11 11:15 AM EPA Interlab LRef 1315 SWA
3/15/11 11:16 AM EPA Interlab LRef 1315 SWA
3/15/11 11:18 AM EPA Interlab LRef 1315 SWA
3/15/11 11:19 AM EPA Interlab LRef 1315 SWA
3/15/11 11:21 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:23 AM EPA Interlab LRef 1315 SWA
3/15/11 11:24 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :26 AM EPA Interlab LRef 1315 SWA
3/15/11 11:28 AM EPA Interlab LRef 1315 SWA
3/15/11 11:29 AM EPA Interlab LRef 1315 SWA
1-738
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Cu SWA-LRef-1315-T01-D 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T02-D 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T03-D 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T04-D 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T05-D 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T06-D 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T07-D 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T08-D 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T09-D 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T01-E 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T02-E 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T03-E 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T04-E 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T05-E 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T06-E 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T07-E 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T08-E 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T09-E 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T01-F 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T02-F 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T03-F 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T04-F 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T05-F 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T06-F 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T07-F 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T08-F 1 1.85E+00 U1/2
Cu SWA-LRef-1315-T09-F 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 60.13 3.70 11.80
1.85E+00 99.04 3.70 11.80
1.85E+00 51.65 3.70 11.80 10000 1000
1.85E+00 16.88 3.70 11.80
1.85E+00 23.16 3.70 11.80
1.85E+00 25.50 3.70 11.80
1.85E+00 55.06 3.70 11.80
1.85E+00 47.18 3.70 11.80
1.85E+00 34.12 3.70 11.80
1.85E+00 28.45 3.70 11.80
1.85E+00 11.93 3.70 11.80
1.85E+00 28.78 3.70 11.80 10000 1000
1.85E+00 25.43 3.70 11.80
1.85E+00 9.22 3.70 11.80
1.85E+00 16.77 3.70 11.80
1.85E+00 10.07 3.70 11.80
1.85E+00 33.11 3.70 11.80
1.85E+00 44.94 3.70 11.80
1.85E+00 5.24 3.70 11.80
1.85E+00 9.34 3.70 11.80
1.85E+00 15.80 3.70 11.80 10000 1000
1.85E+00 23.42 3.70 11.80
1.85E+00 51.70 3.70 11.80
1.85E+00 36.79 3.70 11.80
1.85E+00 12.80 3.70 11.80
1.85E+00 23.49 3.70 11.80
1.85E+00 28.22 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.43E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/15/1 1 10:43 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:45 AM EPA Interlab LRef 1315 SWA
3/15/11 10:46 AM EPA Interlab LRef 1315 SWA
3/15/11 10:48 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:50 AM EPA Interlab LRef 1315 SWA
3/15/11 10:51 AM EPA Interlab LRef 1315 SWA
3/15/11 10:53 AM EPA Interlab LRef 1315 SWA
3/15/11 10:55 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:56 AM EPA Interlab LRef 1315 SWA
3/15/11 11:01 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:03 AM EPA Interlab LRef 1315 SWA
3/15/11 11:05 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :06 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :08 AM EPA Interlab LRef 1315 SWA
3/15/11 11:10 AM EPA Interlab LRef 1315 SWA
3/15/11 11:11 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:13 AM EPA Interlab LRef 1315 SWA
3/15/11 11:15 AM EPA Interlab LRef 1315 SWA
3/15/11 11:16 AM EPA Interlab LRef 1315 SWA
3/15/11 11:18 AM EPA Interlab LRef 1315 SWA
3/15/11 11:19 AM EPA Interlab LRef 1315 SWA
3/15/11 11:21 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:23 AM EPA Interlab LRef 1315 SWA
3/15/11 11:24 AM EPA Interlab LRef 1315 SWA
3/15/11 11:26 AM EPA Interlab LRef 1315 SWA
3/15/11 11:28 AM EPA Interlab LRef 1315 SWA
3/15/11 11:29 AM EPA Interlab LRef 1315 SWA
1-739
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Fe SWA-LRef-1315-T01-D 1 1.51E+01
Fe SWA-LRef-1315-T02-D 1 7.40E+00
Fe SWA-LRef-1315-T03-D 1 6.24E+00 E
Fe SWA-LRef-1315-T04-D 1 6.93E+00
Fe SWA-LRef-1315-T05-D 1 7.32E+00
Fe SWA-LRef-1315-T06-D 1 7.59E+00
Fe SWA-LRef-1315-T07-D 1 3.05E+00 E
Fe SWA-LRef-1315-T08-D 1 6.90E+00
Fe SWA-LRef-1315-T09-D 1 1.00E+00 U1/2
Fe SWA-LRef-1315-T01-E 1 1.29E+01
Fe SWA-LRef-1315-T02-E 1 1.23E+01
Fe SWA-LRef-1315-T03-E 1 7.04E+00
Fe SWA-LRef-1315-T04-E 1 1.61E+01
Fe SWA-LRef-1315-T05-E 1 4.87E+00 E
Fe SWA-LRef-1315-T06-E 1 3.67E+00 E
Fe SWA-LRef-1315-T07-E 1 2.49E+00 E
Fe SWA-LRef-1315-T08-E 1 2.43E+00 E
Fe SWA-LRef-1315-T09-E 1 1.00E+00 U1/2
Fe SWA-LRef-1315-T01-F 1 6.22E+00 E
Fe SWA-LRef-1315-T02-F 1 8.97E+00
Fe SWA-LRef-1315-T03-F 1 5.25E+00 E
Fe SWA-LRef-1315-T04-F 1 4.65E+00 E
Fe SWA-LRef-1315-T05-F 1 4.19E+00 E
Fe SWA-LRef-1315-T06-F 1 1.00E+00 U1/2
Fe SWA-LRef-1315-T07-F 1 2.22E+00 E
Fe SWA-LRef-1315-T08-F 1 1.00E+00 U1/2
Fe SWA-LRef-1315-T09-F 1 2.87E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.51E+01 2.01 2.00 6.40
7.40E+00 9.78 2.00 6.40
6.24E+00 5.75 2.00 6.40 10000 1000
6.93E+00 3.63 2.00 6.40
7.32E+00 0.69 2.00 6.40
7.59E+00 0.72 2.00 6.40
3.05E+00 13.92 2.00 6.40
6.90E+00 3.56 2.00 6.40
1.00E+00 10.07 2.00 6.40
1.29E+01 2.75 2.00 6.40
1.23E+01 1.98 2.00 6.40
7.04E+00 2.57 2.00 6.40 10000 1000
1.61E+01 2.04 2.00 6.40
4.87E+00 0.43 2.00 6.40
3.67E+00 4.11 2.00 6.40
2.49E+00 4.51 2.00 6.40
2.43E+00 3.83 2.00 6.40
1.00E+00 4.31 2.00 6.40
6.22E+00 3.92 2.00 6.40
8.97E+00 2.91 2.00 6.40
5.25E+00 6.21 2.00 6.40 10000 1000
4.65E+00 4.77 2.00 6.40
4.19E+00 6.37 2.00 6.40
1.00E+00 33.82 2.00 6.40
2.22E+00 15.96 2.00 6.40
1.00E+00 5.18 2.00 6.40
2.87E+00 4.68 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.45E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/15/1 1 10:43 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:45 AM EPA Interlab LRef 1315 SWA
3/15/11 10:46 AM EPA Interlab LRef 1315 SWA
3/15/11 10:48 AM EPA Interlab LRef 1315 SWA
3/15/11 10:50 AM EPA Interlab LRef 1315 SWA
3/15/11 10:51 AM EPA Interlab LRef 1315 SWA
3/15/11 10:53 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:55 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:56 AM EPA Interlab LRef 1315 SWA
3/15/11 11:01 AM EPA Interlab LRef 1315 SWA
3/15/11 11:03 AM EPA Interlab LRef 1315 SWA
3/15/11 11:05 AM EPA Interlab LRef 1315 SWA
3/15/11 11:06 AM EPA Interlab LRef 1315 SWA
3/15/11 11:08 AM EPA Interlab LRef 1315 SWA
3/15/11 11:10AM EPA Interlab LRef 1315 SWA
3/15/11 11:11 AM EPA Interlab LRef 1315 SWA
3/15/11 11:13AM EPA Interlab LRef 1315 SWA
3/15/11 11:15AM EPA Interlab LRef 1315 SWA
3/15/11 11:16AM EPA Interlab LRef 1315 SWA
3/15/11 11:18AM EPA Interlab LRef 1315 SWA
3/15/11 11:19 AM EPA Interlab LRef 1315 SWA
3/15/11 11:21 AM EPA Interlab LRef 1315 SWA
3/15/11 11:23 AM EPA Interlab LRef 1315 SWA
3/15/11 11:24AM EPA Interlab LRef 1315 SWA
3/15/11 11:26 AM EPA Interlab LRef 1315 SWA
3/15/11 11:28 AM EPA Interlab LRef 1315 SWA
3/15/11 11:29 AM EPA Interlab LRef 1315 SWA
1-740
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Pb SWA-LRef-1315-T01-D 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T02-D 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T03-D 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T04-D 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T05-D 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T06-D 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T07-D 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T08-D 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T09-D 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T01-E 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T02-E 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T03-E 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T04-E 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T05-E 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T06-E 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T07-E 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T08-E 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T09-E 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T01-F 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T02-F 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T03-F 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T04-F 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T05-F 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T06-F 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T07-F 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T08-F 1 3.40E+00 U1/2
Pb SWA-LRef-1315-T09-F 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.40E+00 23.33 6.80 21.60
3.40E+00 39.80 6.80 21.60
3.40E+00 21.88 6.80 21.60 10000 1000
3.40E+00 55.17 6.80 21.60
3.40E+00 11.53 6.80 21.60
3.40E+00 20.85 6.80 21.60
3.40E+00 19.77 6.80 21.60
3.40E+00 38.27 6.80 21.60
3.40E+00 23.80 6.80 21.60
3.40E+00 46.44 6.80 21.60
3.40E+00 51.14 6.80 21.60
3.40E+00 33.40 6.80 21.60 10000 1000
3.40E+00 6.83 6.80 21.60
3.40E+00 55.13 6.80 21.60
3.40E+00 21.53 6.80 21.60
3.40E+00 46.65 6.80 21.60
3.40E+00 26.17 6.80 21.60
3.40E+00 15.85 6.80 21.60
3.40E+00 38.94 6.80 21.60
3.40E+00 27.91 6.80 21.60
3.40E+00 14.35 6.80 21.60 10000 1000
3.40E+00 16.90 6.80 21.60
3.40E+00 21.57 6.80 21.60
3.40E+00 40.89 6.80 21.60
3.40E+00 16.24 6.80 21.60
3.40E+00 20.13 6.80 21.60
3.40E+00 59.58 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.99E+02 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.35E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/15/1 1 10:43 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:45 AM EPA Interlab LRef 1315 SWA
3/15/11 10:46 AM EPA Interlab LRef 1315 SWA
3/15/11 10:48 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:50 AM EPA Interlab LRef 1315 SWA
3/15/11 10:51 AM EPA Interlab LRef 1315 SWA
3/15/11 10:53 AM EPA Interlab LRef 1315 SWA
3/15/11 10:55 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:56 AM EPA Interlab LRef 1315 SWA
3/15/11 11:01 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:03 AM EPA Interlab LRef 1315 SWA
3/15/11 11:05 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :06 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :08 AM EPA Interlab LRef 1315 SWA
3/15/11 11:10AM EPA Interlab LRef 1315 SWA
3/15/11 11:11 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:13 AM EPA Interlab LRef 1315 SWA
3/15/11 11:15 AM EPA Interlab LRef 1315 SWA
3/15/11 11:16 AM EPA Interlab LRef 1315 SWA
3/15/11 11:18 AM EPA Interlab LRef 1315 SWA
3/15/11 11:19 AM EPA Interlab LRef 1315 SWA
3/15/11 11:21 AM EPA Interlab LRef 1315 SWA
3/15/11 11:23 AM EPA Interlab LRef 1315 SWA
3/15/11 11:24 AM EPA Interlab LRef 1315 SWA
3/15/11 11:26 AM EPA Interlab LRef 1315 SWA
3/15/11 11:28 AM EPA Interlab LRef 1315 SWA
3/15/11 11:29 AM EPA Interlab LRef 1315 SWA
1-741
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Li SWA-LRef-1315-T01-D 1 9.50E-01 U1/2
Li SWA-LRef-1315-T02-D 1 9.50E-01 U1/2
Li SWA-LRef-1315-T03-D 1 9.50E-01 U1/2
Li SWA-LRef-1315-T04-D 1 9.50E-01 U1/2
Li SWA-LRef-1315-T05-D 1 9.50E-01 U1/2
Li SWA-LRef-1315-T06-D 1 9.50E-01 U1/2
Li SWA-LRef-1315-T07-D 1 9.50E-01 U1/2
Li SWA-LRef-1315-T08-D 1 9.50E-01 U1/2
Li SWA-LRef-1315-T09-D 1 9.50E-01 U1/2
Li SWA-LRef-1315-T01-E 1 9.50E-01 U1/2
Li SWA-LRef-1315-T02-E 1 9.50E-01 U1/2
Li SWA-LRef-1315-T03-E 1 9.50E-01 U1/2
Li SWA-LRef-1315-T04-E 1 9.50E-01 U1/2
Li SWA-LRef-1315-T05-E 1 9.50E-01 U1/2
Li SWA-LRef-1315-T06-E 1 9.50E-01 U1/2
Li SWA-LRef-1315-T07-E 1 9.50E-01 U1/2
Li SWA-LRef-1315-T08-E 1 9.50E-01 U1/2
Li SWA-LRef-1315-T09-E 1 9.50E-01 U1/2
Li SWA-LRef-1315-T01-F 1 9.50E-01 U1/2
Li SWA-LRef-1315-T02-F 1 9.50E-01 U1/2
Li SWA-LRef-1315-T03-F 1 9.50E-01 U1/2
Li SWA-LRef-1315-T04-F 1 9.50E-01 U1/2
Li SWA-LRef-1315-T05-F 1 9.50E-01 U1/2
Li SWA-LRef-1315-T06-F 1 9.50E-01 U1/2
Li SWA-LRef-1315-T07-F 1 9.50E-01 U1/2
Li SWA-LRef-1315-T08-F 1 9.50E-01 U1/2
Li SWA-LRef-1315-T09-F 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 21.64 1.90 6.00
9.50E-01 65.58 1.90 6.00
9.50E-01 34.94 1.90 6.00 10000 1000
9.50E-01 69.62 1.90 6.00
9.50E-01 11.43 1.90 6.00
9.50E-01 11.46 1.90 6.00
9.50E-01 47.42 1.90 6.00
9.50E-01 21.98 1.90 6.00
9.50E-01 29.34 1.90 6.00
9.50E-01 13.24 1.90 6.00
9.50E-01 37.00 1.90 6.00
9.50E-01 12.98 1.90 6.00 10000 1000
9.50E-01 10.86 1.90 6.00
9.50E-01 71.48 1.90 6.00
9.50E-01 80.19 1.90 6.00
9.50E-01 86.45 1.90 6.00
9.50E-01 31.28 1.90 6.00
9.50E-01 57.97 1.90 6.00
9.50E-01 85.13 1.90 6.00
9.50E-01 8.26 1.90 6.00
9.50E-01 11.28 1.90 6.00 10000 1000
9.50E-01 29.29 1.90 6.00
9.50E-01 17.72 1.90 6.00
9.50E-01 9.99 1.90 6.00
9.50E-01 28.09 1.90 6.00
9.50E-01 12.93 1.90 6.00
9.50E-01 1679.25 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.24E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.92E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.15E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/3/11 2:01 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:02 PM EPA Interlab LRef 1315 SWA
11/3/11 2:04 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:06 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:07 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:09 PM EPA Interlab LRef 1315 SWA
11/3/11 2:11 PM EPA Interlab LRef 131 5 SWA
11/3/11 2:12 PM EPA Interlab LRef 131 5 SWA
11/3/11 2:14 PM EPA Interlab LRef 1315 SWA
11/3/11 2:19 PM EPA Interlab LRef 1315 SWA
11/3/11 2:21 PM EPA Interlab LRef 131 5 SWA
11/3/11 2:22 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:24 PM EPA Interlab LRef 1315 SWA
11/3/11 2:26 PM EPA Interlab LRef 1315 SWA
11/3/11 2:27 PM EPA Interlab LRef 1315 SWA
11/3/11 2:29 PM EPA Interlab LRef 1315 SWA
11/3/11 2:31 PM EPA Interlab LRef 1315 SWA
11/3/11 2:32 PM EPA Interlab LRef 1315 SWA
11/3/11 2:34 PM EPA Interlab LRef 1315 SWA
11/3/11 2:36 PM EPA Interlab LRef 1315 SWA
11/3/11 2:37 PM EPA Interlab LRef 1315 SWA
11/3/11 2:39 PM EPA Interlab LRef 1315 SWA
11/3/11 2:41 PM EPA Interlab LRef 1315 SWA
11/3/11 2:42 PM EPA Interlab LRef 1315 SWA
11/3/11 2:44 PM EPA Interlab LRef 1315 SWA
11/3/11 2:46 PM EPA Interlab LRef 1315 SWA
11/3/11 2:47 PM EPA Interlab LRef 1315 SWA
1-742
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
Mn SWA-LRef-1315-T01-D 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T02-D 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T03-D 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T04-D 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T05-D 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T06-D 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T07-D 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T08-D 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T09-D 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T01-E 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T02-E 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T03-E 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T04-E 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T05-E 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T06-E 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T07-E 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T08-E 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T09-E 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T01-F 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T02-F 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T03-F 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T04-F 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T05-F 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T06-F 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T07-F 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T08-F 1 1.00E+00 U1/2
Mn SWA-LRef-1315-T09-F 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 17.28 2.00 6.40
1.00E+00 6.94 2.00 6.40
1.00E+00 9.73 2.00 6.40 10000 1000
1.00E+00 18.99 2.00 6.40
1.00E+00 0.44 2.00 6.40
1.00E+00 1.29 2.00 6.40
1.00E+00 16.28 2.00 6.40
1.00E+00 10.29 2.00 6.40
1.00E+00 17.59 2.00 6.40
1.00E+00 11.76 2.00 6.40
1.00E+00 9.18 2.00 6.40
1.00E+00 19.63 2.00 6.40 10000 1000
1.00E+00 1.43 2.00 6.40
1.00E+00 4.54 2.00 6.40
1.00E+00 13.49 2.00 6.40
1.00E+00 14.69 2.00 6.40
1.00E+00 6.66 2.00 6.40
1.00E+00 17.58 2.00 6.40
1.00E+00 5.39 2.00 6.40
1.00E+00 2.20 2.00 6.40
1.00E+00 12.25 2.00 6.40 10000 1000
1.00E+00 15.08 2.00 6.40
1.00E+00 7.88 2.00 6.40
1.00E+00 11.71 2.00 6.40
1.00E+00 13.12 2.00 6.40
1.00E+00 7.98 2.00 6.40
1.00E+00 17.92 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.59E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/15/1 1 10:43 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:45 AM EPA Interlab LRef 1315 SWA
3/15/11 10:46 AM EPA Interlab LRef 1315 SWA
3/15/11 10:48 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:50 AM EPA Interlab LRef 1315 SWA
3/15/11 10:51 AM EPA Interlab LRef 1315 SWA
3/15/11 10:53 AM EPA Interlab LRef 1315 SWA
3/15/11 10:55 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:56 AM EPA Interlab LRef 1315 SWA
3/15/11 11:01 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:03 AM EPA Interlab LRef 1315 SWA
3/15/11 11:05 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :06 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :08 AM EPA Interlab LRef 1315 SWA
3/15/11 11:10 AM EPA Interlab LRef 1315 SWA
3/15/11 11:11 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:13 AM EPA Interlab LRef 1315 SWA
3/15/11 11:15 AM EPA Interlab LRef 1315 SWA
3/15/11 11:16AM EPA Interlab LRef 1315 SWA
3/15/11 11:18AM EPA Interlab LRef 1315 SWA
3/15/11 11:19 AM EPA Interlab LRef 1315 SWA
3/15/11 11:21 AM EPA Interlab LRef 1315 SWA
3/15/11 11:23 AM EPA Interlab LRef 1315 SWA
3/15/11 11:24 AM EPA Interlab LRef 1315 SWA
3/15/11 11:26 AM EPA Interlab LRef 1315 SWA
3/15/11 11:28 AM EPA Interlab LRef 1315 SWA
3/15/11 11:29 AM EPA Interlab LRef 1315 SWA
1-743
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Mg SWA-LRef-1315-T01-D 1 2.03E+00 E
Mg SWA-LRef-1315-T02-D 1 8.36E+00
Mg SWA-LRef-1315-T03-D 1 2.95E+01
Mg SWA-LRef-1315-T04-D 1 2.05E+01
Mg SWA-LRef-1315-T05-D 1 2.31 E+01
Mg SWA-LRef-1315-T06-D 1 1.09E+01
Mg SWA-LRef-1315-T07-D 1 1.29E+01
Mg SWA-LRef-1315-T08-D 1 6.43E+01
Mg SWA-LRef-1315-T09-D 1 5.06E+01
Mg SWA-LRef-1315-T01-E 1 5.29E+00
Mg SWA-LRef-1315-T02-E 1 1.46E+01
Mg SWA-LRef-1315-T03-E 1 2.53E+01
Mg SWA-LRef-1315-T04-E 1 3.77E+01
Mg SWA-LRef-1315-T05-E 1 1.06E+01
Mg SWA-LRef-1315-T06-E 1 8.65E+00
Mg SWA-LRef-1315-T07-E 1 8.27E+00
Mg SWA-LRef-1315-T08-E 1 6.18E+01
Mg SWA-LRef-1315-T09-E 1 1.57E+01
Mg SWA-LRef-1315-T01-F 1 3.26E+00
Mg SWA-LRef-1315-T02-F 1 2.21E+01
Mg SWA-LRef-1315-T03-F 1 3.82E+01
Mg SWA-LRef-1315-T04-F 1 2.63E+01
Mg SWA-LRef-1315-T05-F 1 1.31 E+01
Mg SWA-LRef-1315-T06-F 1 1.83E+01
Mg SWA-LRef-1315-T07-F 1 2.35E+01
Mg SWA-LRef-1315-T08-F 1 7.46E+01
Mg SWA-LRef-1315-T09-F 1 2.71E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.03E+00 4.74 1.00 3.18
8.36E+00 3.00 1.00 3.18
2.95E+01 1.70 1.00 3.18 10000 1000
2.05E+01 1.19 1.00 3.18
2.31E+01 1.20 1.00 3.18
1.09E+01 1.43 1.00 3.18
1.29E+01 13.41 1.00 3.18
6.43E+01 6.77 1.00 3.18
5.06E+01 5.55 1.00 3.18
5.29E+00 7.16 1.00 3.18
1.46E+01 3.14 1.00 3.18
2.53E+01 2.49 1.00 3.18 10000 1000
3.77E+01 0.46 1.00 3.18
1.06E+01 2.28 1.00 3.18
8.65E+00 6.01 1.00 3.18
8.27E+00 6.01 1.00 3.18
6.18E+01 7.72 1.00 3.18
1.57E+01 3.74 1.00 3.18
3.26E+00 2.56 1.00 3.18
2.21E+01 5.90 1.00 3.18
3.82E+01 7.04 1.00 3.18 10000 1000
2.63E+01 6.62 1.00 3.18
1.31E+01 1.14 1.00 3.18
1.83E+01 4.00 1.00 3.18
2.35E+01 1.40 1.00 3.18
7.46E+01 6.73 1.00 3.18
2.71E+01 5.57 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.50E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/15/1 1 10:43 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:45 AM EPA Interlab LRef 1315 SWA
3/15/11 10:46 AM EPA Interlab LRef 1315 SWA
3/15/11 10:48 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:50 AM EPA Interlab LRef 1315 SWA
3/15/11 10:51 AM EPA Interlab LRef 1315 SWA
3/15/11 10:53 AM EPA Interlab LRef 1315 SWA
3/15/11 10:55 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:56 AM EPA Interlab LRef 1315 SWA
3/15/11 11:01 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:03 AM EPA Interlab LRef 1315 SWA
3/15/11 11:05 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :06 AM EPA Interlab LRef 1315 SWA
3/15/11 11:08 AM EPA Interlab LRef 1315 SWA
3/15/11 11:10AM EPA Interlab LRef 1315 SWA
3/15/11 11:11 AM EPA Interlab LRef 1 31 5 SWA
3/15/11 11:13 AM EPA Interlab LRef 1315 SWA
3/15/11 11:15 AM EPA Interlab LRef 1315 SWA
3/15/11 11:16 AM EPA Interlab LRef 1315 SWA
3/15/11 11:18AM EPA Interlab LRef 1315 SWA
3/15/11 11:19 AM EPA Interlab LRef 1315 SWA
3/15/11 11:21 AM EPA Interlab LRef 1315 SWA
3/15/11 11:23 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :24 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :26 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :28 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :29 AM EPA Interlab LRef 1315 SWA
1-744
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
ug/L
Mo SWA-LRef-1315-T01-D 1 2.56E+00 E
Mo SWA-LRef-1315-T02-D 1 3.01 E+00 E
Mo SWA-LRef-1315-T03-D 1 3.89E+00
Mo SWA-LRef-1315-T04-D 1 6.24E+00
Mo SWA-LRef-1315-T05-D 1 5.63E+00
Mo SWA-LRef-1315-T06-D 1 8.44E+00
Mo SWA-LRef-1315-T07-D 1 6.60E+00
Mo SWA-LRef-1315-T08-D 1 4.41 E+00
Mo SWA-LRef-1315-T09-D 1 4.71E+00
Mo SWA-LRef-1315-T01-E 1 1.98E+00 E
Mo SWA-LRef-1315-T02-E 1 5.15E+00
Mo SWA-LRef-1315-T03-E 1 4.77E+00
Mo SWA-LRef-1315-T04-E 1 9.14E+00
Mo SWA-LRef-1315-T05-E 1 5.32E+00
Mo SWA-LRef-1315-T06-E 1 1.02E+01
Mo SWA-LRef-1315-T07-E 1 6.40E+00
Mo SWA-LRef-1315-T08-E 1 4.18E+00
Mo SWA-LRef-1315-T09-E 1 5.21E+00
Mo SWA-LRef-1315-T01-F 1 2.06E+00 E
Mo SWA-LRef-1315-T02-F 1 3.06E+00 E
Mo SWA-LRef-1315-T03-F 1 2.54E+00 E
Mo SWA-LRef-1315-T04-F 1 5.11E+00
Mo SWA-LRef-1315-T05-F 1 4.31E+00
Mo SWA-LRef-1315-T06-F 1 9.31E+00
Mo SWA-LRef-1315-T07-F 1 4.66E+00
Mo SWA-LRef-1315-T08-F 1 4.35E+00
Mo SWA-LRef-1315-T09-F 1 3.97E+00
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.56E+00 10.86 1.20 3.82
3.01 E+00 5.26 1.20 3.82
3.89E+00 1.21 1.20 3.82 10000 1000
6.24E+00 3.34 1.20 3.82
5.63E+00 9.32 1.20 3.82
8.44E+00 1.57 1.20 3.82
6.60E+00 1.22 1.20 3.82
4.41 E+00 2.33 1.20 3.82
4.71 E+00 4.77 1.20 3.82
1.98E+00 18.45 1.20 3.82
5.15E+00 14.15 1.20 3.82
4.77E+00 1.52 1.20 3.82 10000 1000
9.14E+00 6.12 1.20 3.82
5.32E+00 12.46 1.20 3.82
1.02E+01 1.48 1.20 3.82
6.40E+00 1.64 1.20 3.82
4.18E+00 2.23 1.20 3.82
5.21E+00 1.66 1.20 3.82
2.06E+00 3.55 1.20 3.82
3.06E+00 13.31 1.20 3.82
2.54E+00 18.87 1.20 3.82 10000 1000
5.11E+00 4.43 1.20 3.82
4.31E+00 7.10 1.20 3.82
9.31E+00 2.05 1.20 3.82
4.66E+00 2.12 1.20 3.82
4.35E+00 4.70 1.20 3.82
3.97E+00 2.92 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.46E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/15/1 1 10:43 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:45 AM EPA Interlab LRef 1315 SWA
3/15/11 10:46 AM EPA Interlab LRef 1315 SWA
3/15/11 10:48 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:50 AM EPA Interlab LRef 1315 SWA
3/15/11 10:51 AM EPA Interlab LRef 1315 SWA
3/15/11 10:53 AM EPA Interlab LRef 1315 SWA
3/15/11 10:55 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:56 AM EPA Interlab LRef 1315 SWA
3/15/11 11:01 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:03 AM EPA Interlab LRef 1315 SWA
3/15/11 11:05 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :06 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :08 AM EPA Interlab LRef 1315 SWA
3/15/11 11:10 AM EPA Interlab LRef 1315 SWA
3/15/11 11:11 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:13AM EPA Interlab LRef 1315 SWA
3/15/11 11:15 AM EPA Interlab LRef 1315 SWA
3/15/11 11:16 AM EPA Interlab LRef 1315 SWA
3/15/11 11:18 AM EPA Interlab LRef 1315 SWA
3/15/11 11:19 AM EPA Interlab LRef 1315 SWA
3/15/11 11:21 AM EPA Interlab LRef 1315 SWA
3/15/11 11:23 AM EPA Interlab LRef 1315 SWA
3/15/11 11:24 AM EPA Interlab LRef 1315 SWA
3/15/11 11:26 AM EPA Interlab LRef 1315 SWA
3/15/11 11:28 AM EPA Interlab LRef 1315 SWA
3/15/11 11:29 AM EPA Interlab LRef 1315 SWA
1-745
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ni SWA-LRef-1315-T01-D 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T02-D 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T03-D 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T04-D 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T05-D 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T06-D 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T07-D 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T08-D 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T09-D 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T01-E 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T02-E 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T03-E 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T04-E 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T05-E 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T06-E 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T07-E 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T08-E 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T09-E 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T01-F 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T02-F 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T03-F 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T04-F 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T05-F 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T06-F 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T07-F 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T08-F 1 9.00E-01 U1/2
Ni SWA-LRef-1315-T09-F 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 63.52 1.80 5.70
9.00E-01 23.68 1.80 5.70
9.00E-01 49.36 1.80 5.70 10000 1000
9.00E-01 34.36 1.80 5.70
9.00E-01 15.93 1.80 5.70
9.00E-01 23.49 1.80 5.70
9.00E-01 67.42 1.80 5.70
9.00E-01 32.98 1.80 5.70
9.00E-01 31.06 1.80 5.70
9.00E-01 81.24 1.80 5.70
9.00E-01 49.24 1.80 5.70
9.00E-01 56.29 1.80 5.70 10000 1000
9.00E-01 11.58 1.80 5.70
9.00E-01 17.92 1.80 5.70
9.00E-01 35.89 1.80 5.70
9.00E-01 12.31 1.80 5.70
9.00E-01 45.99 1.80 5.70
9.00E-01 30.67 1.80 5.70
9.00E-01 47.97 1.80 5.70
9.00E-01 49.32 1.80 5.70
9.00E-01 88.11 1.80 5.70 10000 1000
9.00E-01 61.86 1.80 5.70
9.00E-01 41.01 1.80 5.70
9.00E-01 7.83 1.80 5.70
9.00E-01 46.31 1.80 5.70
9.00E-01 29.98 1.80 5.70
9.00E-01 9.96 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.03E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.46E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/15/1 1 10:43 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:45 AM EPA Interlab LRef 1315 SWA
3/15/11 10:46 AM EPA Interlab LRef 1315 SWA
3/15/11 10:48 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:50 AM EPA Interlab LRef 1315 SWA
3/15/11 10:51 AM EPA Interlab LRef 1315 SWA
3/15/11 10:53 AM EPA Interlab LRef 1315 SWA
3/15/11 10:55 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:56 AM EPA Interlab LRef 1315 SWA
3/15/11 11:01 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:03 AM EPA Interlab LRef 1315 SWA
3/15/11 11:05 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :06 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :08 AM EPA Interlab LRef 1315 SWA
3/15/11 11:10 AM EPA Interlab LRef 1315 SWA
3/15/11 11:11 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:13 AM EPA Interlab LRef 1315 SWA
3/15/11 11:15 AM EPA Interlab LRef 1315 SWA
3/15/11 11:16 AM EPA Interlab LRef 1315 SWA
3/15/11 11:18 AM EPA Interlab LRef 1315 SWA
3/15/11 11:19 AM EPA Interlab LRef 1315 SWA
3/15/11 11:21 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:23 AM EPA Interlab LRef 1315 SWA
3/15/11 11:24 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :26 AM EPA Interlab LRef 1315 SWA
3/15/11 11:28 AM EPA Interlab LRef 1315 SWA
3/15/11 11:29 AM EPA Interlab LRef 1315 SWA
1-746
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
P SWA-LRef-1315-T01-D 1 1.85E+00 U1/2
P SWA-LRef-1315-T02-D 1 1.85E+00 U1/2
P SWA-LRef-1315-T03-D 1 1.85E+00 U1/2
P SWA-LRef-1315-T04-D 1 1.85E+00 U1/2
P SWA-LRef-1315-T05-D 1 1.85E+00 U1/2
P SWA-LRef-1315-T06-D 1 1.85E+00 U1/2
P SWA-LRef-1315-T07-D 1 1.85E+00 U1/2
P SWA-LRef-1315-T08-D 1 1.85E+00 U1/2
P SWA-LRef-1315-T09-D 1 1.85E+00 U1/2
P SWA-LRef-1315-T01-E 1 1.85E+00 U1/2
P SWA-LRef-1315-T02-E 1 1.85E+00 U1/2
P SWA-LRef-1315-T03-E 1 1.85E+00 U1/2
P SWA-LRef-1315-T04-E 1 1.85E+00 U1/2
P SWA-LRef-1315-T05-E 1 1.85E+00 U1/2
P SWA-LRef-1315-T06-E 1 1.85E+00 U1/2
P SWA-LRef-1315-T07-E 1 1.85E+00 U1/2
P SWA-LRef-1315-T08-E 1 1.85E+00 U1/2
P SWA-LRef-1315-T09-E 1 1.85E+00 U1/2
P SWA-LRef-1315-T01-F 1 1.85E+00 U1/2
P SWA-LRef-1315-T02-F 1 1.85E+00 U1/2
P SWA-LRef-1315-T03-F 1 1.85E+00 U1/2
P SWA-LRef-1315-T04-F 1 1.85E+00 U1/2
P SWA-LRef-1315-T05-F 1 1.85E+00 U1/2
P SWA-LRef-1315-T06-F 1 1.85E+00 U1/2
P SWA-LRef-1315-T07-F 1 1.85E+00 U1/2
P SWA-LRef-1315-T08-F 1 1.85E+00 U1/2
P SWA-LRef-1315-T09-F 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 25.91 3.70 11.80
1.85E+00 15.29 3.70 11.80
1.85E+00 26.95 3.70 11.80 10000 1000
1.85E+00 11.54 3.70 11.80
1.85E+00 4.30 3.70 11.80
1.85E+00 10.43 3.70 11.80
1.85E+00 42.79 3.70 11.80
1.85E+00 28.30 3.70 11.80
1.85E+00 38.00 3.70 11.80
1.85E+00 9.78 3.70 11.80
1.85E+00 88.44 3.70 11.80
1.85E+00 17.64 3.70 11.80 10000 1000
1.85E+00 12.70 3.70 11.80
1.85E+00 23.95 3.70 11.80
1.85E+00 56.70 3.70 11.80
1.85E+00 37.02 3.70 11.80
1.85E+00 10.67 3.70 11.80
1.85E+00 24.46 3.70 11.80
1.85E+00 14.60 3.70 11.80
1.85E+00 50.91 3.70 11.80
1.85E+00 45.86 3.70 11.80 10000 1000
1.85E+00 88.21 3.70 11.80
1.85E+00 50.64 3.70 11.80
1.85E+00 28.51 3.70 11.80
1.85E+00 16.66 3.70 11.80
1.85E+00 9.07 3.70 11.80
1.85E+00 10.08 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.03E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.86E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/15/1 1 10:43 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:45 AM EPA Interlab LRef 1315 SWA
3/15/11 10:46 AM EPA Interlab LRef 1315 SWA
3/15/11 10:48 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:50 AM EPA Interlab LRef 1315 SWA
3/15/11 10:51 AM EPA Interlab LRef 1315 SWA
3/15/11 10:53 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:55 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:56 AM EPA Interlab LRef 1315 SWA
3/15/11 11:01 AM EPA Interlab LRef 1315 SWA
3/15/11 11:03 AM EPA Interlab LRef 1315 SWA
3/15/11 11:05 AM EPA Interlab LRef 1315 SWA
3/15/11 11:06 AM EPA Interlab LRef 1315 SWA
3/15/11 11:08 AM EPA Interlab LRef 1315 SWA
3/15/11 11:10AM EPA Interlab LRef 1315 SWA
3/15/11 11:11 AM EPA Interlab LRef 1315 SWA
3/15/11 11:13 AM EPA Interlab LRef 1315 SWA
3/15/11 11:15 AM EPA Interlab LRef 1315 SWA
3/15/11 11:16 AM EPA Interlab LRef 1315 SWA
3/15/11 11:18 AM EPA Interlab LRef 1315 SWA
3/15/11 11:19AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :21 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :23 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :24 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :26 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :28 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :29 AM EPA Interlab LRef 1315 SWA
1-747
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
K SWA-LRef-1315-T01-D 1 8.50E+03
K SWA-LRef-1315-T02-D 1 2.03E+04
K SWA-LRef-1315-T03-D 1 1.76E+04
K SWA-LRef-1315-T04-D 1 3.55E+04
K SWA-LRef-1315-T05-D 1 2.61E+04
K SWA-LRef-1315-T06-D 1 3.16E+04
K SWA-LRef-1315-T07-D 1 2.60E+04
K SWA-LRef-1315-T08-D 1 8.57E+03
K SWA-LRef-1315-T09-D 1 1.39E+04
K SWA-LRef-1315-T01-E 1 8.94E+03
K SWA-LRef-1315-T02-E 1 3.07E+04
K SWA-LRef-1315-T03-E 1 2.03E+04
K SWA-LRef-1315-T04-E 1 5.00E+04
K SWA-LRef-1315-T05-E 1 3.47E+04
K SWA-LRef-1315-T06-E 1 3.93E+04
K SWA-LRef-1315-T07-E 1 2.20E+04
K SWA-LRef-1315-T08-E 1 1.06E+04
K SWA-LRef-1315-T09-E 1 1.73E+04
K SWA-LRef-1315-T01-F 1 5.61E+03
K SWA-LRef-1315-T02-F 1 2.19E+04
K SWA-LRef-1315-T03-F 1 1.45E+04
K SWA-LRef-1315-T04-F 1 3.47E+04
K SWA-LRef-1315-T05-F 1 2.79E+04
K SWA-LRef-1315-T06-F 1 3.48E+04
K SWA-LRef-1315-T07-F 1 2.13E+04
K SWA-LRef-1315-T08-F 1 8.60E+03
K SWA-LRef-1315-T09-F 1 1.41E+04
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.50E+03 0.28 1.60 5.09
2.03E+04 1.25 1.60 5.09
1.76E+04 0.65 1.60 5.09 10000 1000
3.55E+04 0.37 1.60 5.09
2.61E+04 0.22 1.60 5.09
3.16E+04 1.41 1.60 5.09
2.60E+04 0.29 1.60 5.09
8.57E+03 1.04 1.60 5.09
1.39E+04 0.53 1.60 5.09
8.94E+03 0.72 1.60 5.09
3.07E+04 0.73 1.60 5.09
2.03E+04 0.18 1.60 5.09 10000 1000
5.00E+04 0.52 1.60 5.09
3.47E+04 0.79 1.60 5.09
3.93E+04 0.23 1.60 5.09
2.20E+04 0.59 1.60 5.09
1.06E+04 1.20 1.60 5.09
1.73E+04 0.71 1.60 5.09
5.61 E+03 0.28 1.60 5.09
2.19E+04 0.24 1.60 5.09
1.45E+04 0.46 1.60 5.09 10000 1000
3.47E+04 1.21 1.60 5.09
2.79E+04 1.44 1.60 5.09
3.48E+04 3.64 1.60 5.09
2.13E+04 0.90 1.60 5.09
8.60E+03 0.18 1.60 5.09
1.41E+04 0.46 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.85E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.11E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.54E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/15/1 1 10:43 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:45 AM EPA Interlab LRef 1315 SWA
3/15/11 10:46 AM EPA Interlab LRef 1315 SWA
3/15/11 10:48 AM EPA Interlab LRef 1315 SWA
3/15/11 10:50 AM EPA Interlab LRef 1315 SWA
3/15/11 10:51 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:53 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:55 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:56 AM EPA Interlab LRef 1315 SWA
3/15/11 11:01 AM EPA Interlab LRef 1315 SWA
3/15/11 11:03 AM EPA Interlab LRef 1315 SWA
3/15/11 11:05 AM EPA Interlab LRef 1315 SWA
3/15/11 11:06 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :08 AM EPA Interlab LRef 1315 SWA
3/15/11 11:10 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :1 1 AM EPA Interlab LRef 1315 SWA
3/15/11 11:13 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :15 AM EPA Interlab LRef 1315 SWA
3/15/11 11:16 AM EPA Interlab LRef 1315 SWA
3/15/11 11:18 AM EPA Interlab LRef 1315 SWA
3/15/11 11:19 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :21 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :23 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :24 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :26 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :28 AM EPA Interlab LRef 1315 SWA
3/15/11 11:29 AM EPA Interlab LRef 1315 SWA
1-748
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
Se SWA-LRef-1315-T01-D 1 1.67E+03
Se SWA-LRef-1315-T02-D 1 4.83E+03
Se SWA-LRef-1315-T03-D 1 2.67E+03
Se SWA-LRef-1315-T04-D 1 5.49E+03
Se SWA-LRef-1315-T05-D 1 3.07E+03
Se SWA-LRef-1315-T06-D 1 3.69E+03
Se SWA-LRef-1315-T07-D 1 1.97E+03
Se SWA-LRef-1315-T08-D 1 7.60E+02
Se SWA-LRef-1315-T09-D 1 1.12E+03
Se SWA-LRef-1315-T01-E 1 1.56E+03
Se SWA-LRef-1315-T02-E 1 5.22E+03
Se SWA-LRef-1315-T03-E 1 2.67E+03
Se SWA-LRef-1315-T04-E 1 5.35E+03
Se SWA-LRef-1315-T05-E 1 3.37E+03
Se SWA-LRef-1315-T06-E 1 3.61E+03
Se SWA-LRef-1315-T07-E 1 2.00E+03
Se SWA-LRef-1315-T08-E 1 7.39E+02
Se SWA-LRef-1315-T09-E 1 1.11E+03
Se SWA-LRef-1315-T01-F 1 1.53E+03
Se SWA-LRef-1315-T02-F 1 4.85E+03
Se SWA-LRef-1315-T03-F 1 2.72E+03
Se SWA-LRef-1315-T04-F 1 5.26E+03
Se SWA-LRef-1315-T05-F 1 3.00E+03
Se SWA-LRef-1315-T06-F 1 3.76E+03
Se SWA-LRef-1315-T07-F 1 2.13E+03
Se SWA-LRef-1315-T08-F 1 7.11E+02
Se SWA-LRef-1315-T09-F 1 1.22E+03
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.67E+03 1.47 15.00 47.70
4.83E+03 18.25 15.00 47.70
2.67E+03 1.64 15.00 47.70 10000 1000
5.49E+03 1.06 15.00 47.70
3.07E+03 0.86 15.00 47.70
3.69E+03 1.38 15.00 47.70
1.97E+03 0.34 15.00 47.70
7.60E+02 3.29 15.00 47.70
1.12E+03 2.41 15.00 47.70
1.56E+03 1.03 15.00 47.70
5.22E+03 0.59 15.00 47.70
2.67E+03 1.16 15.00 47.70 10000 1000
5.35E+03 0.97 15.00 47.70
3.37E+03 0.86 15.00 47.70
3.61E+03 0.70 15.00 47.70
2.00E+03 0.45 15.00 47.70
7.39E+02 1.78 15.00 47.70
1.11E+03 0.65 15.00 47.70
1.53E+03 1.88 15.00 47.70
4.85E+03 1.84 15.00 47.70
2.72E+03 0.77 15.00 47.70 10000 1000
5.26E+03 0.79 15.00 47.70
3.00E+03 1.10 15.00 47.70
3.76E+03 0.55 15.00 47.70
2.13E+03 1.85 15.00 47.70
7.11E+02 0.23 15.00 47.70
1.22E+03 0.86 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.60E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.55E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.66E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/3/11 2:01 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:02 PM EPA Interlab LRef 1315 SWA
11/3/11 2:04 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:06 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:07 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:09 PM EPA Interlab LRef 1315 SWA
11/3/11 2:11 PM EPA Interlab LRef 131 5 SWA
11/3/11 2:12 PM EPA Interlab LRef 131 5 SWA
11/3/11 2:14 PM EPA Interlab LRef 1315 SWA
11/3/11 2:19 PM EPA Interlab LRef 1315 SWA
11/3/11 2:21 PM EPA Interlab LRef 131 5 SWA
11/3/11 2:22 PM EPA Interlab LRef 1315 SWA
11/3/11 2:24PM EPA Interlab LRef 1315 SWA
11/3/11 2:26 PM EPA Interlab LRef 1315 SWA
11/3/11 2:27 PM EPA Interlab LRef 1315 SWA
11/3/11 2:29 PM EPA Interlab LRef 1315 SWA
11/3/11 2:31 PM EPA Interlab LRef 1315 SWA
11/3/11 2:32 PM EPA Interlab LRef 1315 SWA
11/3/11 2:34 PM EPA Interlab LRef 1315 SWA
11/3/11 2:36 PM EPA Interlab LRef 1315 SWA
11/3/11 2:37 PM EPA Interlab LRef 1315 SWA
11/3/11 2:39 PM EPA Interlab LRef 1315 SWA
11/3/11 2:41 PM EPA Interlab LRef 1315 SWA
11/3/11 2:42 PM EPA Interlab LRef 1315 SWA
11/3/11 2:44 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:46 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:47 PM EPA Interlab LRef 1315 SWA
1-749
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Si SWA-LRef-1315-T01-D 1 7.72E+02
Si SWA-LRef-1315-T02-D 1 4.12E+03
Si SWA-LRef-1315-T03-D 1 3.06E+03
Si SWA-LRef-1315-T04-D 1 8.19E+03
Si SWA-LRef-1315-T05-D 1 7.69E+03
Si SWA-LRef-1315-T06-D 1 8.16E+03
Si SWA-LRef-1315-T07-D 1 7.16E+03
Si SWA-LRef-1315-T08-D 1 5.32E+03
Si SWA-LRef-1315-T09-D 1 6.76E+03
Si SWA-LRef-1315-T01-E 1 7.48E+02
Si SWA-LRef-1315-T02-E 1 4.21E+03
Si SWA-LRef-1315-T03-E 1 3.20E+03
Si SWA-LRef-1315-T04-E 1 8.11E+03
Si SWA-LRef-1315-T05-E 1 7.81E+03
Si SWA-LRef-1315-T06-E 1 8.10E+03
Si SWA-LRef-1315-T07-E 1 7.16E+03
Si SWA-LRef-1315-T08-E 1 5.24E+03
Si SWA-LRef-1315-T09-E 1 6.73E+03
Si SWA-LRef-1315-T01-F 1 7.35E+02
Si SWA-LRef-1315-T02-F 1 4.12E+03
Si SWA-LRef-1315-T03-F 1 3.21E+03
Si SWA-LRef-1315-T04-F 1 8.01E+03
Si SWA-LRef-1315-T05-F 1 7.73E+03
Si SWA-LRef-1315-T06-F 1 8.18E+03
Si SWA-LRef-1315-T07-F 1 7.09E+03
Si SWA-LRef-1315-T08-F 1 5.24E+03
Si SWA-LRef-1315-T09-F 1 7.09E+03
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.72E+02 0.78 1.10 3.50
4.12E+03 6.42 1.10 3.50
3.06E+03 0.86 1.10 3.50 10000 1000
8.19E+03 0.94 1.10 3.50
7.69E+03 0.94 1.10 3.50
8.16E+03 1.24 1.10 3.50
7.16E+03 0.29 1.10 3.50
5.32E+03 0.57 1.10 3.50
6.76E+03 0.17 1.10 3.50
7.48E+02 1.03 1.10 3.50
4.21E+03 2.19 1.10 3.50
3.20E+03 1.58 1.10 3.50 10000 1000
8.11E+03 1.18 1.10 3.50
7.81E+03 0.53 1.10 3.50
8.10E+03 1.84 1.10 3.50
7.16E+03 1.23 1.10 3.50
5.24E+03 1.55 1.10 3.50
6.73E+03 2.03 1.10 3.50
7.35E+02 1.27 1.10 3.50
4.12E+03 1.05 1.10 3.50
3.21E+03 1.00 1.10 3.50 10000 1000
8.01E+03 2.06 1.10 3.50
7.73E+03 2.22 1.10 3.50
8.18E+03 12.18 1.10 3.50
7.09E+03 0.25 1.10 3.50
5.24E+03 1.20 1.10 3.50
7.09E+03 0.72 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.06E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.17E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.22E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/3/11 2:01 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:02 PM EPA Interlab LRef 1315 SWA
11/3/11 2:04 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:06 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:07 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:09 PM EPA Interlab LRef 1315 SWA
11/3/11 2:11 PM EPA Interlab LRef 131 5 SWA
11/3/11 2:12 PM EPA Interlab LRef 131 5 SWA
11/3/11 2:14 PM EPA Interlab LRef 1315 SWA
11/3/11 2:19 PM EPA Interlab LRef 1315 SWA
11/3/11 2:21 PM EPA Interlab LRef 131 5 SWA
11/3/11 2:22 PM EPA Interlab LRef 1315 SWA
11/3/11 2:24PM EPA Interlab LRef 1315 SWA
11/3/11 2:26 PM EPA Interlab LRef 1315 SWA
11/3/11 2:27 PM EPA Interlab LRef 1315 SWA
11/3/11 2:29 PM EPA Interlab LRef 1315 SWA
11/3/11 2:31 PM EPA Interlab LRef 1315 SWA
11/3/11 2:32 PM EPA Interlab LRef 1315 SWA
11/3/11 2:34 PM EPA Interlab LRef 1315 SWA
11/3/11 2:36 PM EPA Interlab LRef 1315 SWA
11/3/11 2:37 PM EPA Interlab LRef 1315 SWA
11/3/11 2:39 PM EPA Interlab LRef 1315 SWA
11/3/11 2:41 PM EPA Interlab LRef 1315 SWA
11/3/11 2:42 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:44 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:46 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:47 PM EPA Interlab LRef 1315 SWA
1-750
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Na SWA-LRef-1315-T01-D 1 4.18E+04
Na SWA-LRef-1315-T02-D 1 1.51E+05
Na SWA-LRef-1315-T03-D 1 8.53E+04
Na SWA-LRef-1315-T04-D 1 1.69E+05
Na SWA-LRef-1315-T05-D 1 1.30E+05
Na SWA-LRef-1315-T06-D 1 9.89E+04
Na SWA-LRef-1315-T07-D 1 8.97E+04
Na SWA-LRef-1315-T08-D 1 3.76E+04
Na SWA-LRef-1315-T09-D 1 5.68E+04
Na SWA-LRef-1315-T01-E 1 4.26E+04
Na SWA-LRef-1315-T02-E 1 1.44E+05
Na SWA-LRef-1315-T03-E 1 9.53E+04
Na SWA-LRef-1315-T04-E 1 2.30E+05
Na SWA-LRef-1315-T05-E 1 1.64E+05
Na SWA-LRef-1315-T06-E 1 1.12E+05
Na SWA-LRef-1315-T07-E 1 8.01 E+04
Na SWA-LRef-1315-T08-E 1 4.36E+04
Na SWA-LRef-1315-T09-E 1 6.55E+04
Na SWA-LRef-1315-T01-F 1 2.63E+04
Na SWA-LRef-1315-T02-F 1 1.02E+05
Na SWA-LRef-1315-T03-F 1 6.79E+04
Na SWA-LRef-1315-T04-F 1 1.64E+05
Na SWA-LRef-1315-T05-F 1 1.36E+05
Na SWA-LRef-1315-T06-F 1 9.34E+04
Na SWA-LRef-1315-T07-F 1 7.69E+04
Na SWA-LRef-1315-T08-F 1 3.65E+04
Na SWA-LRef-1315-T09-F 1 5.66E+04
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.18E+04 0.70 2.50 8.00
1.51E+05 0.40 2.50 8.00
8.53E+04 0.43 2.50 8.00 10000 1000
1.69E+05 1.33 2.50 8.00
1.30E+05 1.62 2.50 8.00
9.89E+04 0.38 2.50 8.00
8.97E+04 0.53 2.50 8.00
3.76E+04 0.45 2.50 8.00
5.68E+04 0.52 2.50 8.00
4.26E+04 0.46 2.50 8.00
1.44E+05 0.69 2.50 8.00
9.53E+04 0.32 2.50 8.00 10000 1000
2.30E+05 2.25 2.50 8.00
1.64E+05 0.20 2.50 8.00
1.12E+05 0.39 2.50 8.00
8.01 E+04 0.89 2.50 8.00
4.36E+04 0.44 2.50 8.00
6.55E+04 0.80 2.50 8.00
2.63E+04 0.86 2.50 8.00
1.02E+05 0.99 2.50 8.00
6.79E+04 0.45 2.50 8.00 10000 1000
1.64E+05 0.18 2.50 8.00
1.36E+05 0.19 2.50 8.00
9.34E+04 0.83 2.50 8.00
7.69E+04 1.32 2.50 8.00
3.65E+04 0.64 2.50 8.00
5.66E+04 0.20 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.62E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.61 E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.88E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/15/1 1 10:43 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:45 AM EPA Interlab LRef 1315 SWA
3/15/11 10:46 AM EPA Interlab LRef 1315 SWA
3/15/11 10:48 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:50 AM EPA Interlab LRef 1315 SWA
3/15/11 10:51 AM EPA Interlab LRef 1315 SWA
3/15/11 10:53 AM EPA Interlab LRef 1315 SWA
3/15/11 10:55 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:56 AM EPA Interlab LRef 1315 SWA
3/15/11 11:01 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:03 AM EPA Interlab LRef 1315 SWA
3/15/11 11:05 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :06 AM EPA Interlab LRef 1315 SWA
3/15/1 1 11 :08 AM EPA Interlab LRef 1315 SWA
3/15/11 11:10 AM EPA Interlab LRef 1315 SWA
3/15/11 11:11 AM EPA Interlab LRef 131 5 SWA
3/15/11 11:13 AM EPA Interlab LRef 1315 SWA
3/15/11 11:15 AM EPA Interlab LRef 1315 SWA
3/15/11 11:16 AM EPA Interlab LRef 1315 SWA
3/15/11 11:18 AM EPA Interlab LRef 1315 SWA
3/15/11 11:19 AM EPA Interlab LRef 1315 SWA
3/15/11 11:21 AM EPA Interlab LRef 1315 SWA
3/15/11 11:23 AM EPA Interlab LRef 1315 SWA
3/15/11 11:24 AM EPA Interlab LRef 1315 SWA
3/15/11 11:26 AM EPA Interlab LRef 1315 SWA
3/15/11 11:28 AM EPA Interlab LRef 1315 SWA
3/15/11 11:29 AM EPA Interlab LRef 1315 SWA
1-751
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Sr SWA-LRef-1315-T01-D 1 7.23E+00
Sr SWA-LRef-1315-T02-D 1 1.13E+02
Sr SWA-LRef-1315-T03-D 1 9.97E+01
Sr SWA-LRef-1315-T04-D 1 1.87E+02
Sr SWA-LRef-1315-T05-D 1 2.15E+02
Sr SWA-LRef-1315-T06-D 1 2.68E+02
Sr SWA-LRef-1315-T07-D 1 2.55E+02
Sr SWA-LRef-1315-T08-D 1 2.40E+02
Sr SWA-LRef-1315-T09-D 1 2.65E+02
Sr SWA-LRef-1315-T01-E 1 8.43E+00
Sr SWA-LRef-1315-T02-E 1 1.09E+02
Sr SWA-LRef-1315-T03-E 1 9.64E+01
Sr SWA-LRef-1315-T04-E 1 1.87E+02
Sr SWA-LRef-1315-T05-E 1 2.07E+02
Sr SWA-LRef-1315-T06-E 1 2.41E+02
Sr SWA-LRef-1315-T07-E 1 2.52E+02
Sr SWA-LRef-1315-T08-E 1 2.37E+02
Sr SWA-LRef-1315-T09-E 1 2.61E+02
Sr SWA-LRef-1315-T01-F 1 7.11E+00
Sr SWA-LRef-1315-T02-F 1 1.15E+02
Sr SWA-LRef-1315-T03-F 1 9.42E+01
Sr SWA-LRef-1315-T04-F 1 1.70E+02
Sr SWA-LRef-1315-T05-F 1 2.27E+02
Sr SWA-LRef-1315-T06-F 1 2.26E+02
Sr SWA-LRef-1315-T07-F 1 2.45E+02
Sr SWA-LRef-1315-T08-F 1 2.20E+02
Sr SWA-LRef-1315-T09-F 1 2.56E+02
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.23E+00 3.40 1.00 3.18
1.13E+02 6.08 1.00 3.18
9.97E+01 1.16 1.00 3.18 10000 1000
1.87E+02 0.37 1.00 3.18
2.15E+02 0.25 1.00 3.18
2.68E+02 0.82 1.00 3.18
2.55E+02 0.54 1.00 3.18
2.40E+02 0.82 1.00 3.18
2.65E+02 1.73 1.00 3.18
8.43E+00 2.42 1.00 3.18
1.09E+02 1.10 1.00 3.18
9.64E+01 0.87 1.00 3.18 10000 1000
1.87E+02 0.99 1.00 3.18
2.07E+02 0.43 1.00 3.18
2.41E+02 1.00 1.00 3.18
2.52E+02 0.10 1.00 3.18
2.37E+02 1.27 1.00 3.18
2.61E+02 1.04 1.00 3.18
7.11E+00 4.19 1.00 3.18
1.15E+02 1.08 1.00 3.18
9.42E+01 1.19 1.00 3.18 10000 1000
1.70E+02 1.84 1.00 3.18
2.27E+02 1.26 1.00 3.18
2.26E+02 1.71 1.00 3.18
2.45E+02 0.20 1.00 3.18
2.20E+02 0.94 1.00 3.18
2.56E+02 1.63 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 . 1 5E+03 1 05% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 . 1 1 E+03 1 02% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/3/11 2:01 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:02 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:04 PM EPA Interlab LRef 1315 SWA
11/3/11 2:06 PM EPA Interlab LRef 1315 SWA
11/3/11 2:07 PM EPA Interlab LRef 1315 SWA
11/3/11 2:09 PM EPA Interlab LRef 1315 SWA
11/3/11 2:11 PM EPA Interlab LRef 1315 SWA
11/3/11 2:12 PM EPA Interlab LRef 1315 SWA
11/3/11 2:14 PM EPA Interlab LRef 1315 SWA
11/3/11 2:19 PM EPA Interlab LRef 1315 SWA
11/3/11 2:21 PM EPA Interlab LRef 1315 SWA
11/3/11 2:22 PM EPA Interlab LRef 1315 SWA
11/3/11 2:24 PM EPA Interlab LRef 1315 SWA
11/3/11 2:26 PM EPA Interlab LRef 1315 SWA
11/3/11 2:27 PM EPA Interlab LRef 1315 SWA
11/3/11 2:29 PM EPA Interlab LRef 1315 SWA
11/3/11 2:31 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:32 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:34 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:36 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:37 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:39 PM EPA Interlab LRef 1315 SWA
11/3/11 2:41 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:42 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:44 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:46 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:47 PM EPA Interlab LRef 1315 SWA
1-752
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
S SWA-LRef-1315-T01-D 1 5.19E+03
S SWA-LRef-1315-T02-D 1 2.78E+04
S SWA-LRef-1315-T03-D 1 9.27E+03
S SWA-LRef-1315-T04-D 1 1.82E+04
S SWA-LRef-1315-T05-D 1 9.05E+03
S SWA-LRef-1315-T06-D 1 9.76E+03
S SWA-LRef-1315-T07-D 1 8.31E+03
S SWA-LRef-1315-T08-D 1 1.65E+03
S SWA-LRef-1315-T09-D 1 3.42E+03
S SWA-LRef-1315-T01-E 1 4.78E+03
S SWA-LRef-1315-T02-E 1 2.36E+04
S SWA-LRef-1315-T03-E 1 1.35E+04
S SWA-LRef-1315-T04-E 1 1.72E+04
S SWA-LRef-1315-T05-E 1 1.35E+04
S SWA-LRef-1315-T06-E 1 1.43E+04
S SWA-LRef-1315-T07-E 1 5.66E+03
S SWA-LRef-1315-T08-E 1 2.39E+03
S SWA-LRef-1315-T09-E 1 4.50E+03
S SWA-LRef-1315-T01-F 1 2.37E+03
S SWA-LRef-1315-T02-F 1 1.09E+04
S SWA-LRef-1315-T03-F 1 6.67E+03
S SWA-LRef-1315-T04-F 1 1.59E+04
S SWA-LRef-1315-T05-F 1 9.11E+03
S SWA-LRef-1315-T06-F 1 8.19E+03
S SWA-LRef-1315-T07-F 1 4.78E+03
S SWA-LRef-1315-T08-F 1 1.52E+03
S SWA-LRef-1315-T09-F 1 3.17E+03
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.19E+03 1.05 6.80 21.60
2.78E+04 12.32 6.80 21.60
9.27E+03 1.42 6.80 21.60 10000 1000
1.82E+04 0.72 6.80 21.60
9.05E+03 0.91 6.80 21.60
9.76E+03 0.66 6.80 21.60
8.31 E+03 0.40 6.80 21.60
1.65E+03 0.33 6.80 21.60
3.42E+03 0.62 6.80 21.60
4.78E+03 0.89 6.80 21.60
2.36E+04 0.21 6.80 21.60
1.35E+04 0.28 6.80 21.60 10000 1000
1.72E+04 0.30 6.80 21.60
1.35E+04 0.84 6.80 21.60
1.43E+04 0.63 6.80 21.60
5.66E+03 1.18 6.80 21.60
2.39E+03 2.71 6.80 21.60
4.50E+03 1.22 6.80 21.60
2.37E+03 1.25 6.80 21.60
1.09E+04 0.68 6.80 21.60
6.67E+03 0.60 6.80 21.60 10000 1000
1.59E+04 0.88 6.80 21.60
9.11E+03 1.44 6.80 21.60
8.19E+03 1.04 6.80 21.60
4.78E+03 1.02 6.80 21.60
1.52E+03 0.98 6.80 21.60
3.17E+03 0.99 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.43E+04 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.57E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/15/1 1 10:43 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:45 AM EPA Interlab LRef 1315 SWA
3/15/11 10:46 AM EPA Interlab LRef 1315 SWA
3/15/11 10:48 AM EPA Interlab LRef 1315 SWA
3/15/11 10:50 AM EPA Interlab LRef 1315 SWA
3/15/11 10:51 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:53 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:55 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:56 AM EPA Interlab LRef 1315 SWA
3/15/11 11:01 AM EPA Interlab LRef 1315 SWA
3/15/11 11:03 AM EPA Interlab LRef 1315 SWA
3/15/11 11:05 AM EPA Interlab LRef 1315 SWA
3/15/11 11:06 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :08 AM EPA Interlab LRef 1315 SWA
3/15/11 11:10 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :1 1 AM EPA Interlab LRef 1315 SWA
3/15/11 11:13 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :15 AM EPA Interlab LRef 1315 SWA
3/15/11 11:16 AM EPA Interlab LRef 1315 SWA
3/15/11 11:18 AM EPA Interlab LRef 1315 SWA
3/15/11 11:19 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :21 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :23 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :24 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :26 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :28 AM EPA Interlab LRef 1315 SWA
3/15/11 11:29 AM EPA Interlab LRef 1315 SWA
1-753
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Tl SWA-LRef-1315-T01-D 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T02-D 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T03-D 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T04-D 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T05-D 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T06-D 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T07-D 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T08-D 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T09-D 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T01-E 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T02-E 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T03-E 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T04-E 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T05-E 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T06-E 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T07-E 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T08-E 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T09-E 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T01-F 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T02-F 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T03-F 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T04-F 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T05-F 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T06-F 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T07-F 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T08-F 1 2.30E+00 U1/2
Tl SWA-LRef-1315-T09-F 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.30E+00 38.57 4.60 14.60
2.30E+00 26.40 4.60 14.60
2.30E+00 39.68 4.60 14.60 10000 1000
2.30E+00 27.15 4.60 14.60
2.30E+00 44.05 4.60 14.60
2.30E+00 57.25 4.60 14.60
2.30E+00 44.16 4.60 14.60
2.30E+00 38.84 4.60 14.60
2.30E+00 22.50 4.60 14.60
2.30E+00 20.38 4.60 14.60
2.30E+00 11.10 4.60 14.60
2.30E+00 18.96 4.60 14.60 10000 1000
2.30E+00 28.42 4.60 14.60
2.30E+00 50.46 4.60 14.60
2.30E+00 37.27 4.60 14.60
2.30E+00 30.39 4.60 14.60
2.30E+00 46.75 4.60 14.60
2.30E+00 57.64 4.60 14.60
2.30E+00 24.84 4.60 14.60
2.30E+00 25.13 4.60 14.60
2.30E+00 48.88 4.60 14.60 10000 1000
2.30E+00 35.29 4.60 14.60
2.30E+00 45.54 4.60 14.60
2.30E+00 37.71 4.60 14.60
2.30E+00 58.12 4.60 14.60
2.30E+00 60.72 4.60 14.60
2.30E+00 67.07 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.37E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/15/1 1 10:43 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:45 AM EPA Interlab LRef 1315 SWA
3/15/11 10:46 AM EPA Interlab LRef 1315 SWA
3/15/11 10:48 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:50 AM EPA Interlab LRef 1315 SWA
3/15/11 10:51 AM EPA Interlab LRef 1315 SWA
3/15/11 10:53 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:55 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:56 AM EPA Interlab LRef 1315 SWA
3/15/11 11:01 AM EPA Interlab LRef 1315 SWA
3/15/11 11:03 AM EPA Interlab LRef 1315 SWA
3/15/11 11:05 AM EPA Interlab LRef 1315 SWA
3/15/11 11:06 AM EPA Interlab LRef 1315 SWA
3/15/11 11:08 AM EPA Interlab LRef 1315 SWA
3/15/11 11:10AM EPA Interlab LRef 1315 SWA
3/15/11 11:11 AM EPA Interlab LRef 1315 SWA
3/15/11 11:13 AM EPA Interlab LRef 1315 SWA
3/15/11 11:15 AM EPA Interlab LRef 1315 SWA
3/15/11 11:16 AM EPA Interlab LRef 1315 SWA
3/15/11 11:18 AM EPA Interlab LRef 1315 SWA
3/15/11 11:19 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :21 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :23 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :24 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :26 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :28 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :29 AM EPA Interlab LRef 1315 SWA
1-754
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ti SWA-LRef-1315-T01-D 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T02-D 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T03-D 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T04-D 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T05-D 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T06-D 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T07-D 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T08-D 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T09-D 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T01-E 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T02-E 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T03-E 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T04-E 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T05-E 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T06-E 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T07-E 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T08-E 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T09-E 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T01-F 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T02-F 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T03-F 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T04-F 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T05-F 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T06-F 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T07-F 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T08-F 1 1.00E+00 U1/2
Ti SWA-LRef-1315-T09-F 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 24.44 2.00 6.40
1.00E+00 70.90 2.00 6.40
1.00E+00 33.72 2.00 6.40 10000 1000
1.00E+00 1.51 2.00 6.40
1.00E+00 0.99 2.00 6.40
1.00E+00 10.54 2.00 6.40
1.00E+00 46.53 2.00 6.40
1.00E+00 12.28 2.00 6.40
1.00E+00 75.08 2.00 6.40
1.00E+00 29.29 2.00 6.40
1.00E+00 36.97 2.00 6.40
1.00E+00 70.73 2.00 6.40 10000 1000
1.00E+00 1.33 2.00 6.40
1.00E+00 2.75 2.00 6.40
1.00E+00 16.98 2.00 6.40
1.00E+00 65.73 2.00 6.40
1.00E+00 11.10 2.00 6.40
1.00E+00 111.18 2.00 6.40
1.00E+00 41.57 2.00 6.40
1.00E+00 23.74 2.00 6.40
1.00E+00 32.78 2.00 6.40 10000 1000
1.00E+00 49.00 2.00 6.40
1.00E+00 14.65 2.00 6.40
1.00E+00 71.86 2.00 6.40
1.00E+00 49.34 2.00 6.40
1.00E+00 56.08 2.00 6.40
1.00E+00 54.79 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.87E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.48E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/15/1 1 10:43 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:45 AM EPA Interlab LRef 1315 SWA
3/15/11 10:46 AM EPA Interlab LRef 1315 SWA
3/15/11 10:48 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:50 AM EPA Interlab LRef 1315 SWA
3/15/11 10:51 AM EPA Interlab LRef 1315 SWA
3/15/11 10:53 AM EPA Interlab LRef 1315 SWA
3/15/11 10:55 AM EPA Interlab LRef 1315 SWA
3/15/11 10:56 AM EPA Interlab LRef 1315 SWA
3/15/11 11:01 AM EPA Interlab LRef 1315 SWA
3/15/11 11:03 AM EPA Interlab LRef 1315 SWA
3/15/11 11:05 AM EPA Interlab LRef 1315 SWA
3/15/11 11:06 AM EPA Interlab LRef 1315 SWA
3/15/11 11:08 AM EPA Interlab LRef 1315 SWA
3/15/11 11:10 AM EPA Interlab LRef 1315 SWA
3/15/11 11:11 AM EPA Interlab LRef 1 31 5 SWA
3/15/11 11:13 AM EPA Interlab LRef 1315 SWA
3/15/11 11:15 AM EPA Interlab LRef 1315 SWA
3/15/11 11:16 AM EPA Interlab LRef 1315 SWA
3/15/11 11:18 AM EPA Interlab LRef 1315 SWA
3/15/11 11:19 AM EPA Interlab LRef 1315 SWA
3/15/11 11:21 AM EPA Interlab LRef 1315 SWA
3/15/11 11:23 AM EPA Interlab LRef 1315 SWA
3/15/11 11:24 AM EPA Interlab LRef 1315 SWA
3/15/11 11:26 AM EPA Interlab LRef 1315 SWA
3/15/11 11:28 AM EPA Interlab LRef 1315 SWA
3/15/11 11:29 AM EPA Interlab LRef 1315 SWA
1-755
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
V SWA-LRef-1315-T01-D 1 1.12E+01
V SWA-LRef-1315-T02-D 1 1.79E+01
V SWA-LRef-1315-T03-D 1 1.21E+01
V SWA-LRef-1315-T04-D 1 1.76E+01
V SWA-LRef-1315-T05-D 1 2.08E+01
V SWA-LRef-1315-T06-D 1 2.06E+01
V SWA-LRef-1315-T07-D 1 1.89E+01
V SWA-LRef-1315-T08-D 1 1.17E+01
V SWA-LRef-1315-T09-D 1 1.60E+01
V SWA-LRef-1315-T01-E 1 1.14E+01
V SWA-LRef-1315-T02-E 1 1.91E+01
V SWA-LRef-1315-T03-E 1 1.24E+01
V SWA-LRef-1315-T04-E 1 2.11E+01
V SWA-LRef-1315-T05-E 1 1.92E+01
V SWA-LRef-1315-T06-E 1 1.98E+01
V SWA-LRef-1315-T07-E 1 1.69E+01
V SWA-LRef-1315-T08-E 1 1.18E+01
V SWA-LRef-1315-T09-E 1 1.64E+01
V SWA-LRef-1315-T01-F 1 1.19E+01
V SWA-LRef-1315-T02-F 1 1.75E+01
V SWA-LRef-1315-T03-F 1 9.93E+00
V SWA-LRef-1315-T04-F 1 2.09E+01
V SWA-LRef-1315-T05-F 1 1.71E+01
V SWA-LRef-1315-T06-F 1 2.00E+01
V SWA-LRef-1315-T07-F 1 1.61E+01
V SWA-LRef-1315-T08-F 1 1.16E+01
V SWA-LRef-1315-T09-F 1 1.52E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.12E+01 10.93 1.50 4.77
1.79E+01 3.95 1.50 4.77
1.21E+01 3.49 1.50 4.77 10000 1000
1.76E+01 3.93 1.50 4.77
2.08E+01 0.11 1.50 4.77
2.06E+01 6.04 1.50 4.77
1.89E+01 2.86 1.50 4.77
1.17E+01 8.67 1.50 4.77
1.60E+01 4.82 1.50 4.77
1.14E+01 5.50 1.50 4.77
1.91E+01 10.64 1.50 4.77
1.24E+01 8.33 1.50 4.77 10000 1000
2.11E+01 0.99 1.50 4.77
1.92E+01 1.82 1.50 4.77
1.98E+01 1.18 1.50 4.77
1.69E+01 1.43 1.50 4.77
1.18E+01 3.84 1.50 4.77
1.64E+01 2.26 1.50 4.77
1.19E+01 5.55 1.50 4.77
1.75E+01 6.95 1.50 4.77
9.93E+00 9.87 1.50 4.77 10000 1000
2.09E+01 4.97 1.50 4.77
1.71E+01 7.41 1.50 4.77
2.00E+01 2.28 1.50 4.77
1.61E+01 6.46 1.50 4.77
1.16E+01 5.42 1.50 4.77
1.52E+01 0.54 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.71 E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
11/3/11 2:01 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:02 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:04 PM EPA Interlab LRef 1315 SWA
11/3/11 2:06 PM EPA Interlab LRef 1315 SWA
11/3/11 2:07 PM EPA Interlab LRef 1315 SWA
11/3/11 2:09 PM EPA Interlab LRef 1315 SWA
11/3/11 2:11 PM EPA Interlab LRef 1315 SWA
11/3/11 2:12 PM EPA Interlab LRef 1315 SWA
11/3/11 2:14 PM EPA Interlab LRef 1315 SWA
11/3/11 2:19 PM EPA Interlab LRef 1315 SWA
11/3/11 2:21 PM EPA Interlab LRef 1315 SWA
11/3/11 2:22 PM EPA Interlab LRef 1315 SWA
11/3/11 2:24 PM EPA Interlab LRef 1315 SWA
11/3/11 2:26 PM EPA Interlab LRef 1315 SWA
11/3/11 2:27 PM EPA Interlab LRef 1315 SWA
11/3/11 2:29 PM EPA Interlab LRef 1315 SWA
11/3/11 2:31 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:32 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:34 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:36 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:37 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:39 PM EPA Interlab LRef 1315 SWA
11/3/11 2:41 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:42 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:44 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:46 PM EPA Interlab LRef 1315 SWA
1 1/3/1 1 2:47 PM EPA Interlab LRef 1315 SWA
1-756
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
Zn SWA-LRef-1315-T01-D 1 1.46E+00 E
Zn SWA-LRef-1315-T02-D 1 2.57E+00 E
Zn SWA-LRef-1315-T03-D 1 1.50E+01
Zn SWA-LRef-1315-T04-D 1 1.47E+01
Zn SWA-LRef-1315-T05-D 1 1.49E+01
Zn SWA-LRef-1315-T06-D 1 1.47E+01
Zn SWA-LRef-1315-T07-D 1 5.00E-01 U1/2
Zn SWA-LRef-1315-T08-D 1 5.00E-01 U1/2
Zn SWA-LRef-1315-T09-D 1 1.43E+01
Zn SWA-LRef-1315-T01-E 1 7.35E+00
Zn SWA-LRef-1315-T02-E 1 2.57E+00 E
Zn SWA-LRef-1315-T03-E 1 1.50E+01
Zn SWA-LRef-1315-T04-E 1 2.70E+01
Zn SWA-LRef-1315-T05-E 1 1.39E+01
Zn SWA-LRef-1315-T06-E 1 1.44E+01
Zn SWA-LRef-1315-T07-E 1 1.21E+00 E
Zn SWA-LRef-1315-T08-E 1 1.53E+00 E
Zn SWA-LRef-1315-T09-E 1 1.47E+01
Zn SWA-LRef-1315-T01-F 1 6.77E+00
Zn SWA-LRef-1315-T02-F 1 2.51E+00 E
Zn SWA-LRef-1315-T03-F 1 1.55E+01
Zn SWA-LRef-1315-T04-F 1 1.45E+01
Zn SWA-LRef-1315-T05-F 1 1.38E+01
Zn SWA-LRef-1315-T06-F 1 1.41E+01
Zn SWA-LRef-1315-T07-F 1 2.09E+00 E
Zn SWA-LRef-1315-T08-F 1 5.00E-01 U1/2
Zn SWA-LRef-1315-T09-F 1 1.41E+01
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.46E+00 0.34 1.00 3.18
2.57E+00 2.13 1.00 3.18
1.50E+01 0.21 1.00 3.18 10000 1000
1.47E+01 2.11 1.00 3.18
1.49E+01 3.12 1.00 3.18
1.47E+01 1.86 1.00 3.18
5.00E-01 5.95 1.00 3.18
5.00E-01 9.78 1.00 3.18
1.43E+01 2.06 1.00 3.18
7.35E+00 0.70 1.00 3.18
2.57E+00 5.43 1.00 3.18
1.50E+01 1.80 1.00 3.18 10000 1000
2.70E+01 2.30 1.00 3.18
1.39E+01 1.79 1.00 3.18
1.44E+01 3.12 1.00 3.18
1.21E+00 6.54 1.00 3.18
1.53E+00 8.54 1.00 3.18
1.47E+01 1.22 1.00 3.18
6.77E+00 1.85 1.00 3.18
2.51E+00 6.52 1.00 3.18
1.55E+01 1.98 1.00 3.18 10000 1000
1.45E+01 1.58 1.00 3.18
1.38E+01 1.00 1.00 3.18
1.41E+01 3.10 1.00 3.18
2.09E+00 7.41 1.00 3.18
5.00E-01 17.67 1.00 3.18
1.41E+01 1.20 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.36E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
3/15/1 1 10:43 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:45 AM EPA Interlab LRef 1315 SWA
3/15/11 10:46 AM EPA Interlab LRef 1315 SWA
3/15/11 10:48 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:50 AM EPA Interlab LRef 1315 SWA
3/15/11 10:51 AM EPA Interlab LRef 1315 SWA
3/15/11 10:53 AM EPA Interlab LRef 1315 SWA
3/15/11 10:55 AM EPA Interlab LRef 1315 SWA
3/15/1 1 10:56 AM EPA Interlab LRef 1315 SWA
3/15/11 11:01 AM EPA Interlab LRef 1315 SWA
3/15/11 11:03 AM EPA Interlab LRef 1315 SWA
3/15/11 11:05 AM EPA Interlab LRef 1315 SWA
3/15/11 11:06 AM EPA Interlab LRef 1315 SWA
3/15/11 11:08 AM EPA Interlab LRef 1315 SWA
3/15/11 11:10AM EPA Interlab LRef 1315 SWA
3/15/11 11:11 AM EPA Interlab LRef 1315 SWA
3/15/11 11:13AM EPA Interlab LRef 1315 SWA
3/15/11 11:15 AM EPA Interlab LRef 1315 SWA
3/15/11 11:16 AM EPA Interlab LRef 1315 SWA
3/15/11 11:18 AM EPA Interlab LRef 1315 SWA
3/15/11 11:19AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :21 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :23 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :24 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :26 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :28 AM EPA Interlab LRef 1315 SWA
3/15/1 1 1 1 :29 AM EPA Interlab LRef 1315 SWA
1-757
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1315:
Element Sample ID
Al CFS-L01-1315-T01-A
Al CFS-L01-1315-T02-A
Al CFS-L01-1315-T03-A
Al CFS-L01-1315-T04-A
Al CFS-L01-1315-T05-A
Al CFS-L01-1315-T06-A
Al CFS-L01-1315-T07-A
Al CFS-L01-1315-T08-A
Al CFS-L01-1315-T09-A
Al CFS-L01-1315-T01-B
Al CFS-L01-1315-T02-B
Al CFS-L01-1315-T03-B
Al CFS-L01-1315-T04-B
Al CFS-L01-1315-T05-B
Al CFS-L01-1315-T06-B
Al CFS-L01-1315-T07-B
Al CFS-L01-1315-T08-B
Al CFS-L01-1315-T09-B
Al CFS-L01-1315-T01-C
Al CFS-L01-1315-T02-C
Al CFS-L01-1315-T03-C
Al CFS-L01-1315-T04-C
Al CFS-L01-1315-T05-C
Al CFS-L01-1315-T06-C
Al CFS-L01-1315-T07-C
Al CFS-L01-1315-T08-C
Al CFS-L01-1315-T09-C
Al CFS-L01-1315-M01-A
Al CFS-L01-1315-M02-A
Al CFS-L01-1315-M03-A
Al CFS-L01-1315-M04-A
Al CFS-L01-1315-M05-A
Al CFS-L01-1315-M06-A
Al CFS-L01-1315-M07-A
Al CFS-L01-1315-M08-A
Al CFS-L01-1315-M09-A
Dilution Sample
Factor Cone. Qualifier
I ug/L I
1 1.26E+01
1 2.14E+01
1 1.33E+01
1 3.05E+01
1 3.28E+01
1 3.95E+01
1 4.74E+01
1 4.41 E+01
1 4.38E+01
1 1.37E+01
1 1.88E+01
1 1.95E+01
1 3.93E+01
1 2.58E+01
1 4.82E+01
1 6.09E+01
1 4.76E+01
1 5.18E+01
1 1.14E+01
1 1.23E+01
1 1.22E+01
1 2.80E+01
1 3.24E+01
1 4.93E+01
1 3.87E+01
1 5.02E+01
1 4.07E+01
1 1.30E+OOE
1 1.25E+OOE
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.26E+01 11.13 1.00 3.18
2.14E+01 0.61 1.00 3.18
1.33E+01 1.72 1.00 3.18 10000 1000
3.05E+01 7.85 1.00 3.18
3.28E+01 4.92 1.00 3.18
3.95E+01 7.88 1.00 3.18
4.74E+01 0.93 1.00 3.18
4.41E+01 5.08 1.00 3.18
4.38E+01 3.63 1.00 3.18
1.37E+01 2.09 1.00 3.18
1.88E+01 4.97 1.00 3.18
1.95E+01 8.76 1.00 3.18 10000 1000
3.93E+01 1.18 1.00 3.18
2.58E+01 5.19 1.00 3.18
4.82E+01 1.58 1.00 3.18
6.09E+01 1.66 1.00 3.18
4.76E+01 4.43 1.00 3.18
5.18E+01 9.24 1.00 3.18
1.14E+01 8.42 1.00 3.18
1.23E+01 9.54 1.00 3.18
1.22E+01 5.00 1.00 3.18 10000 1000
2.80E+01 1.98 1.00 3.18
3.24E+01 7.41 1.00 3.18
4.93E+01 2.94 1.00 3.18
3.87E+01 2.34 1.00 3.18
5.02E+01 1.31 1.00 3.18
4.07E+01 5.45 1.00 3.18
1.30E+00 6.66 1.00 3.18
1.25E+00 11.33 1.00 3.18
5.00E-01 9.18 1.00 3.18
5.00E-01 12.17 1.00 3.18
5.00E-01 3.86 1.00 3.18
5.00E-01 2.48 1.00 3.18
5.00E-01 9.82 1.00 3.18
5.00E-01 5.91 1.00 3.18
5.00E-01 13.29 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.80E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.30E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.38E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-758
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Sb CFS-L01-1315-T01-A 1 9.09E+00 E
Sb CFS-L01-1315-T02-A 1 1.01E+01 E
Sb CFS-L01-1315-T03-A 1 1.04E+01 E
Sb CFS-L01-1315-T04-A 1 1.45E+01 E
Sb CFS-L01-1315-T05-A 1 1.08E+01 E
Sb CFS-L01-1315-T06-A 1 1.32E+01 E
Sb CFS-L01-1315-T07-A 1 1.27E+01 E
Sb CFS-L01-1315-T08-A 1 1.08E+01 E
Sb CFS-L01-1315-T09-A 1 9.23E+00 E
Sb CFS-L01-1315-T01-B 1 1.28E+01 E
Sb CFS-L01-1315-T02-B 1 9.63E+00 E
Sb CFS-L01-1315-T03-B 1 1.28E+01 E
Sb CFS-L01-1315-T04-B 1 1.08E+01 E
Sb CFS-L01-1315-T05-B 1 8.42E+00 E
Sb CFS-L01-1315-T06-B 1 1.39E+01 E
Sb CFS-L01-1315-T07-B 1 1.40E+01 E
Sb CFS-L01-1315-T08-B 1 1.13E+01 E
Sb CFS-L01-1315-T09-B 1 8.43E+00 E
Sb CFS-L01-1315-T01-C 1 7.95E+00 E
Sb CFS-L01-1315-T02-C 1 1.26E+01 E
Sb CFS-L01-1315-T03-C 1 1.14E+01 E
Sb CFS-L01-1315-T04-C 1 1.16E+01 E
Sb CFS-L01-1315-T05-C 1 1.29E+01 E
Sb CFS-L01-1315-T06-C 1 1.41E+01 E
Sb CFS-L01-1315-T07-C 1 1.44E+01 E
Sb CFS-L01-1315-T08-C 1 1.25E+01 E
Sb CFS-L01-1315-T09-C 1 1.03E+01 E
Sb CFS-L01-1315-M01-A 1 3.75E+00 U1/2
Sb CFS-L01-1315-M02-A 1 3.75E+00 U1/2
Sb CFS-L01-1315-M03-A 1 3.75E+00 U1/2
Sb CFS-L01-1315-M04-A 1 3.75E+00 U1/2
Sb CFS-L01-1315-M05-A 1 3.75E+00 U1/2
Sb CFS-L01-1315-M06-A 1 3.75E+00 U1/2
Sb CFS-L01-1315-M07-A 1 3.75E+00 U1/2
Sb CFS-L01-1315-M08-A 1 3.75E+00 U1/2
Sb CFS-L01-1315-M09-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.09E+00 17.82 7.50 23.90
1.01E+01 6.42 7.50 23.90
1.04E+01 4.32 7.50 23.90 10000 1000
1.45E+01 14.00 7.50 23.90
1.08E+01 10.71 7.50 23.90
1.32E+01 9.61 7.50 23.90
1.27E+01 4.08 7.50 23.90
1.08E+01 4.64 7.50 23.90
9.23E+00 15.68 7.50 23.90
1.28E+01 10.05 7.50 23.90
9.63E+00 14.23 7.50 23.90
1.28E+01 11.92 7.50 23.90 10000 1000
1.08E+01 9.57 7.50 23.90
8.42E+00 5.61 7.50 23.90
1.39E+01 6.33 7.50 23.90
1.40E+01 5.96 7.50 23.90
1.13E+01 12.64 7.50 23.90
8.43E+00 6.42 7.50 23.90
7.95E+00 7.73 7.50 23.90
1.26E+01 19.92 7.50 23.90
1.14E+01 25.01 7.50 23.90 10000 1000
1.16E+01 21.04 7.50 23.90
1.29E+01 9.40 7.50 23.90
1.41E+01 17.43 7.50 23.90
1.44E+01 9.78 7.50 23.90
1.25E+01 6.61 7.50 23.90
1.03E+01 9.50 7.50 23.90
3.75E+00 37.17 7.50 23.90
3.75E+00 28.62 7.50 23.90
3.75E+00 31.90 7.50 23.90
3.75E+00 29.24 7.50 23.90
3.75E+00 30.41 7.50 23.90
3.75E+00 37.07 7.50 23.90
3.75E+00 27.54 7.50 23.90
3.75E+00 23.98 7.50 23.90
3.75E+00 16.98 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.90E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.35E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.46E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-759
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
As CFS-L01-1315-T01-A 1 5.50E+00 U1/2
As CFS-L01-1315-T02-A 1 1.30E+01 E
As CFS-L01-1315-T03-A 1 1.67E+01 E
As CFS-L01-1315-T04-A 1 1.29E+01 E
As CFS-L01-1315-T05-A 1 1.53E+01 E
As CFS-L01-1315-T06-A 1 1.18E+01 E
As CFS-L01-1315-T07-A 1 5.50E+00 U1/2
As CFS-L01-1315-T08-A 1 5.50E+00 U1/2
As CFS-L01-1315-T09-A 1 5.50E+00 U1/2
As CFS-L01-1315-T01-B 1 5.50E+00 U1/2
As CFS-L01-1315-T02-B 1 1.18E+01 E
As CFS-L01-1315-T03-B 1 1.20E+01 E
As CFS-L01-1315-T04-B 1 1.47E+01 E
As CFS-L01-1315-T05-B 1 1.73E+01 E
As CFS-L01-1315-T06-B 1 1.54E+01 E
As CFS-L01-1315-T07-B 1 5.50E+00 U1/2
As CFS-L01-1315-T08-B 1 5.50E+00 U1/2
As CFS-L01-1315-T09-B 1 5.50E+00 U1/2
As CFS-L01-1315-T01-C 1 5.50E+00 U1/2
As CFS-L01-1315-T02-C 1 1.24E+01 E
As CFS-L01-1315-T03-C 1 1.25E+01 E
As CFS-L01-1315-T04-C 1 1.34E+01 E
As CFS-L01-1315-T05-C 1 1.80E+01 E
As CFS-L01-1315-T06-C 1 1.50E+01 E
As CFS-L01-1315-T07-C 1 5.50E+00 U1/2
As CFS-L01-1315-T08-C 1 5.50E+00 U1/2
As CFS-L01-1315-T09-C 1 5.50E+00 U1/2
As CFS-L01-1315-M01-A 1 5.50E+00 U1/2
As CFS-L01-1315-M02-A 1 5.50E+00 U1/2
As CFS-L01-1315-M03-A 1 5.50E+00 U1/2
As CFS-L01-1315-M04-A 1 5.50E+00 U1/2
As CFS-L01-1315-M05-A 1 5.50E+00 U1/2
As CFS-L01-1315-M06-A 1 5.50E+00 U1/2
As CFS-L01-1315-M07-A 1 5.50E+00 U1/2
As CFS-L01-1315-M08-A 1 5.50E+00 U1/2
As CFS-L01-1315-M09-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.50E+00 5.23 11.00 35.00
1.30E+01 11.79 11.00 35.00
1.67E+01 4.01 11.00 35.00 10000 1000
1.29E+01 24.84 11.00 35.00
1.53E+01 8.12 11.00 35.00
1.18E+01 29.85 11.00 35.00
5.50E+00 63.37 11.00 35.00
5.50E+00 23.44 11.00 35.00
5.50E+00 38.70 11.00 35.00
5.50E+00 48.32 11.00 35.00
1.18E+01 25.60 11.00 35.00
1.20E+01 12.43 11.00 35.00 10000 1000
1.47E+01 19.95 11.00 35.00
1.73E+01 7.88 11.00 35.00
1.54E+01 22.54 11.00 35.00
5.50E+00 36.59 11.00 35.00
5.50E+00 13.79 11.00 35.00
5.50E+00 9.66 11.00 35.00
5.50E+00 16.08 11.00 35.00
1.24E+01 27.86 11.00 35.00
1.25E+01 36.19 11.00 35.00 10000 1000
1.34E+01 12.14 11.00 35.00
1.80E+01 27.56 11.00 35.00
1.50E+01 34.49 11.00 35.00
5.50E+00 7.03 11.00 35.00
5.50E+00 37.58 11.00 35.00
5.50E+00 21.89 11.00 35.00
5.50E+00 114.42 11.00 35.00
5.50E+00 48.99 11.00 35.00
5.50E+00 16.52 11.00 35.00
5.50E+00 42.37 11.00 35.00
5.50E+00 62.76 11.00 35.00
5.50E+00 64.22 11.00 35.00
5.50E+00 10.67 11.00 35.00
5.50E+00 53.77 11.00 35.00
5.50E+00 80.82 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.69E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.35E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.26E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-760
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
B CFS-L01-1315-T01-A 1 4.68E+00
B CFS-L01-1315-T02-A 1 3.26E+01
B CFS-L01-1315-T03-A 1 1.92E+01
B CFS-L01-1315-T04-A 1 8.94E+01
B CFS-L01-1315-T05-A 1 8.90E+01
B CFS-L01-1315-T06-A 1 1.32E+02
B CFS-L01-1315-T07-A 1 1.17E+02
B CFS-L01-1315-T08-A 1 6.37E+01
B CFS-L01-1315-T09-A 1 9.88E+01
B CFS-L01-1315-T01-B 1 7.14E+00
B CFS-L01-1315-T02-B 1 2.60E+01
B CFS-L01-1315-T03-B 1 2.23E+01
B CFS-L01-1315-T04-B 1 8.11E+01
B CFS-L01-1315-T05-B 1 9.36E+01
B CFS-L01-1315-T06-B 1 1.39E+02
B CFS-L01-1315-T07-B 1 1.19E+02
B CFS-L01-1315-T08-B 1 6.36E+01
B CFS-L01-1315-T09-B 1 1.06E+02
B CFS-L01-1315-T01-C 1 6.07E+00
B CFS-L01-1315-T02-C 1 2.31E+01
B CFS-L01-1315-T03-C 1 2.27E+01
B CFS-L01-1315-T04-C 1 8.51 E+01
B CFS-L01-1315-T05-C 1 9.57E+01
B CFS-L01-1315-T06-C 1 1.44E+02
B CFS-L01-1315-T07-C 1 1.27E+02
B CFS-L01-1315-T08-C 1 6.67E+01
B CFS-L01-1315-T09-C 1 1.09E+02
B CFS-L01-1315-M01-A 1 5.00E-01 U1/2
B CFS-L01-1315-M02-A 1 5.00E-01 U1/2
B CFS-L01-1315-M03-A 1 5.00E-01 U1/2
B CFS-L01-1315-M04-A 1 5.00E-01 U1/2
B CFS-L01-1315-M05-A 1 5.00E-01 U1/2
B CFS-L01-1315-M06-A 1 5.00E-01 U1/2
B CFS-L01-1315-M07-A 1 5.00E-01 U1/2
B CFS-L01-1315-M08-A 1 5.00E-01 U1/2
B CFS-L01-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.68E+00 6.83 1.00 3.18
3.26E+01 3.39 1.00 3.18
1.92E+01 4.80 1.00 3.18 10000 1000
8.94E+01 5.15 1.00 3.18
8.90E+01 1.50 1.00 3.18
1.32E+02 3.07 1.00 3.18
1.17E+02 0.91 1.00 3.18
6.37E+01 2.31 1.00 3.18
9.88E+01 1.61 1.00 3.18
7.14E+00 1.55 1.00 3.18
2.60E+01 3.66 1.00 3.18
2.23E+01 2.79 1.00 3.18 10000 1000
8. 11 E+01 1.05 1.00 3.18
9.36E+01 0.44 1.00 3.18
1.39E+02 1.21 1.00 3.18
1.19E+02 0.56 1.00 3.18
6.36E+01 0.96 1.00 3.18
1.06E+02 2.10 1.00 3.18
6.07E+00 1.90 1.00 3.18
2.31E+01 3.61 1.00 3.18
2.27E+01 1.49 1.00 3.18 10000 1000
8.51E+01 1.80 1.00 3.18
9.57E+01 1.40 1.00 3.18
1.44E+02 2.47 1.00 3.18
1.27E+02 2.05 1.00 3.18
6.67E+01 1.67 1.00 3.18
1.09E+02 1.38 1.00 3.18
5.00E-01 5.82 1.00 3.18
5.00E-01 7.72 1.00 3.18
5.00E-01 8.95 1.00 3.18
5.00E-01 8.18 1.00 3.18
5.00E-01 5.23 1.00 3.18
5.00E-01 0.92 1.00 3.18
5.00E-01 4.66 1.00 3.18
5.00E-01 7.27 1.00 3.18
5.00E-01 5.96 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.69E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.85E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.76E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-761
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Ba CFS-L01-1315-T01-A 1 2.20E+01
Ba CFS-L01-1315-T02-A 1 2.58E+01
Ba CFS-L01-1315-T03-A 1 2.86E+01
Ba CFS-L01-1315-T04-A 1 3.08E+01
Ba CFS-L01-1315-T05-A 1 3.11E+01
Ba CFS-L01-1315-T06-A 1 3.78E+01
Ba CFS-L01-1315-T07-A 1 3.44E+01
Ba CFS-L01-1315-T08-A 1 2.73E+01
Ba CFS-L01-1315-T09-A 1 3.01 E+01
Ba CFS-L01-1315-T01-B 1 2.45E+01
Ba CFS-L01-1315-T02-B 1 2.88E+01
Ba CFS-L01-1315-T03-B 1 2.93E+01
Ba CFS-L01-1315-T04-B 1 3.32E+01
Ba CFS-L01-1315-T05-B 1 3.42E+01
Ba CFS-L01-1315-T06-B 1 3.88E+01
Ba CFS-L01-1315-T07-B 1 3.57E+01
Ba CFS-L01-1315-T08-B 1 2.65E+01
Ba CFS-L01-1315-T09-B 1 2.99E+01
Ba CFS-L01-1315-T01-C 1 2.13E+01
Ba CFS-L01-1315-T02-C 1 2.46E+01
Ba CFS-L01-1315-T03-C 1 2.68E+01
Ba CFS-L01-1315-T04-C 1 3.12E+01
Ba CFS-L01-1315-T05-C 1 3.23E+01
Ba CFS-L01-1315-T06-C 1 3.74E+01
Ba CFS-L01-1315-T07-C 1 3.56E+01
Ba CFS-L01-1315-T08-C 1 2.87E+01
Ba CFS-L01-1315-T09-C 1 3.24E+01
Ba CFS-L01-1315-M01-A 1 5.00E-01 U1/2
Ba CFS-L01-1315-M02-A 1 5.00E-01 U1/2
Ba CFS-L01-1315-M03-A 1 5.00E-01 U1/2
Ba CFS-L01-1315-M04-A 1 5.00E-01 U1/2
Ba CFS-L01-1315-M05-A 1 5.00E-01 U1/2
Ba CFS-L01-1315-M06-A 1 5.00E-01 U1/2
Ba CFS-L01-1315-M07-A 1 5.00E-01 U1/2
Ba CFS-L01-1315-M08-A 1 5.00E-01 U1/2
Ba CFS-L01-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.20E+01 2.30 1.00 3.18
2.58E+01 0.81 1.00 3.18
2.86E+01 2.60 1.00 3.18 10000 1000
3.08E+01 4.72 1.00 3.18
3. 11 E+01 1.44 1.00 3.18
3.78E+01 2.28 1.00 3.18
3.44E+01 1.14 1.00 3.18
2.73E+01 2.11 1.00 3.18
3.01E+01 0.73 1.00 3.18
2.45E+01 5.85 1.00 3.18
2.88E+01 1.93 1.00 3.18
2.93E+01 1.33 1.00 3.18 10000 1000
3.32E+01 0.72 1.00 3.18
3.42E+01 0.68 1.00 3.18
3.88E+01 0.79 1.00 3.18
3.57E+01 3.18 1.00 3.18
2.65E+01 1.97 1.00 3.18
2.99E+01 4.05 1.00 3.18
2.13E+01 2.10 1.00 3.18
2.46E+01 1.79 1.00 3.18
2.68E+01 1.51 1.00 3.18 10000 1000
3.12E+01 0.17 1.00 3.18
3.23E+01 1.54 1.00 3.18
3.74E+01 1.60 1.00 3.18
3.56E+01 0.90 1.00 3.18
2.87E+01 1.55 1.00 3.18
3.24E+01 1.17 1.00 3.18
5.00E-01 21.99 1.00 3.18
5.00E-01 15.27 1.00 3.18
5.00E-01 7.70 1.00 3.18
5.00E-01 13.14 1.00 3.18
5.00E-01 10.12 1.00 3.18
5.00E-01 7.34 1.00 3.18
5.00E-01 14.36 1.00 3.18
5.00E-01 6.80 1.00 3.18
5.00E-01 10.71 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.74E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.46E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.51 E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-762
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Be CFS-L01-1315-T01-A 1 9.50E-01 U1/2
Be CFS-L01-1315-T02-A 1 9.50E-01 U1/2
Be CFS-L01-1315-T03-A 1 9.50E-01 U1/2
Be CFS-L01-1315-T04-A 1 9.50E-01 U1/2
Be CFS-L01-1315-T05-A 1 9.50E-01 U1/2
Be CFS-L01-1315-T06-A 1 9.50E-01 U1/2
Be CFS-L01-1315-T07-A 1 9.50E-01 U1/2
Be CFS-L01-1315-T08-A 1 9.50E-01 U1/2
Be CFS-L01-1315-T09-A 1 9.50E-01 U1/2
Be CFS-L01-1315-T01-B 1 9.50E-01 U1/2
Be CFS-L01-1315-T02-B 1 9.50E-01 U1/2
Be CFS-L01-1315-T03-B 1 9.50E-01 U1/2
Be CFS-L01-1315-T04-B 1 9.50E-01 U1/2
Be CFS-L01-1315-T05-B 1 9.50E-01 U1/2
Be CFS-L01-1315-T06-B 1 9.50E-01 U1/2
Be CFS-L01-1315-T07-B 1 9.50E-01 U1/2
Be CFS-L01-1315-T08-B 1 9.50E-01 U1/2
Be CFS-L01-1315-T09-B 1 9.50E-01 U1/2
Be CFS-L01-1315-T01-C 1 9.50E-01 U1/2
Be CFS-L01-1315-T02-C 1 9.50E-01 U1/2
Be CFS-L01-1315-T03-C 1 9.50E-01 U1/2
Be CFS-L01-1315-T04-C 1 9.50E-01 U1/2
Be CFS-L01-1315-T05-C 1 9.50E-01 U1/2
Be CFS-L01-1315-T06-C 1 9.50E-01 U1/2
Be CFS-L01-1315-T07-C 1 9.50E-01 U1/2
Be CFS-L01-1315-T08-C 1 9.50E-01 U1/2
Be CFS-L01-1315-T09-C 1 9.50E-01 U1/2
Be CFS-L01-1315-M01-A 1 9.50E-01 U1/2
Be CFS-L01-1315-M02-A 1 9.50E-01 U1/2
Be CFS-L01-1315-M03-A 1 9.50E-01 U1/2
Be CFS-L01-1315-M04-A 1 9.50E-01 U1/2
Be CFS-L01-1315-M05-A 1 9.50E-01 U1/2
Be CFS-L01-1315-M06-A 1 9.50E-01 U1/2
Be CFS-L01-1315-M07-A 1 9.50E-01 U1/2
Be CFS-L01-1315-M08-A 1 9.50E-01 U1/2
Be CFS-L01-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 52.24 1.90 6.00
9.50E-01 13.92 1.90 6.00
9.50E-01 25.33 1.90 6.00 10000 1000
9.50E-01 76.66 1.90 6.00
9.50E-01 68.06 1.90 6.00
9.50E-01 50.98 1.90 6.00
9.50E-01 51.06 1.90 6.00
9.50E-01 48.95 1.90 6.00
9.50E-01 32.82 1.90 6.00
9.50E-01 29.80 1.90 6.00
9.50E-01 9.18 1.90 6.00
9.50E-01 98.39 1.90 6.00 10000 1000
9.50E-01 11.87 1.90 6.00
9.50E-01 16.56 1.90 6.00
9.50E-01 36.92 1.90 6.00
9.50E-01 45.39 1.90 6.00
9.50E-01 88.42 1.90 6.00
9.50E-01 36.97 1.90 6.00
9.50E-01 2.12 1.90 6.00
9.50E-01 31.31 1.90 6.00
9.50E-01 38.93 1.90 6.00 10000 1000
9.50E-01 46.23 1.90 6.00
9.50E-01 11.79 1.90 6.00
9.50E-01 10.54 1.90 6.00
9.50E-01 85.93 1.90 6.00
9.50E-01 22.70 1.90 6.00
9.50E-01 66.59 1.90 6.00
9.50E-01 24.53 1.90 6.00
9.50E-01 29.88 1.90 6.00
9.50E-01 32.84 1.90 6.00
9.50E-01 8.66 1.90 6.00
9.50E-01 66.60 1.90 6.00
9.50E-01 4.67 1.90 6.00
9.50E-01 59.96 1.90 6.00
9.50E-01 22.14 1.90 6.00
9.50E-01 61.87 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.94E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.25E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.46E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-763
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Cd CFS-L01-1315-T01-A 1 8.94E+01
Cd CFS-L01-1315-T02-A 1 2.84E+02
Cd CFS-L01-1315-T03-A 1 2.25E+02
Cd CFS-L01-1315-T04-A 1 7.82E+02
Cd CFS-L01-1315-T05-A 1 8.46E+02
Cd CFS-L01-1315-T06-A 1 1.24E+03
Cd CFS-L01-1315-T07-A 1 1.12E+03
Cd CFS-L01-1315-T08-A 1 6.10E+02
Cd CFS-L01-1315-T09-A 1 9.76E+02
Cd CFS-L01-1315-T01-B 1 9.42E+01
Cd CFS-L01-1315-T02-B 1 3.12E+02
Cd CFS-L01-1315-T03-B 1 2.69E+02
Cd CFS-L01-1315-T04-B 1 7.25E+02
Cd CFS-L01-1315-T05-B 1 8.79E+02
Cd CFS-L01-1315-T06-B 1 1.27E+03
Cd CFS-L01-1315-T07-B 1 1.10E+03
Cd CFS-L01-1315-T08-B 1 6.16E+02
Cd CFS-L01-1315-T09-B 1 1.02E+03
Cd CFS-L01-1315-T01-C 1 9.71E+01
Cd CFS-L01-1315-T02-C 1 2.59E+02
Cd CFS-L01-1315-T03-C 1 2.78E+02
Cd CFS-L01-1315-T04-C 1 7.96E+02
Cd CFS-L01-1315-T05-C 1 9.32E+02
Cd CFS-L01-1315-T06-C 1 1.40E+03
Cd CFS-L01-1315-T07-C 1 1.23E+03
Cd CFS-L01-1315-T08-C 1 6.90E+02
Cd CFS-L01-1315-T09-C 1 1.10E+03
Cd CFS-L01-1315-M01-A 1 1.10E+00 U1/2
Cd CFS-L01-1315-M02-A 1 1.10E+00 U1/2
Cd CFS-L01-1315-M03-A 1 1.10E+00 U1/2
Cd CFS-L01-1315-M04-A 1 1.10E+00 U1/2
Cd CFS-L01-1315-M05-A 1 1.10E+00 U1/2
Cd CFS-L01-1315-M06-A 1 1.10E+00 U1/2
Cd CFS-L01-1315-M07-A 1 1.10E+00 U1/2
Cd CFS-L01-1315-M08-A 1 1.10E+00 U1/2
Cd CFS-L01-1315-M09-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.94E+01 0.93 2.20 7.00
2.84E+02 0.84 2.20 7.00
2.25E+02 1.61 2.20 7.00 10000 1000
7.82E+02 5.87 2.20 7.00
8.46E+02 1.70 2.20 7.00
1.24E+03 2.05 2.20 7.00
1.12E+03 0.63 2.20 7.00
6.10E+02 0.55 2.20 7.00
9.76E+02 0.80 2.20 7.00
9.42E+01 4.36 2.20 7.00
3.12E+02 1.37 2.20 7.00
2.69E+02 1.62 2.20 7.00 10000 1000
7.25E+02 0.25 2.20 7.00
8.79E+02 1.19 2.20 7.00
1.27E+03 0.70 2.20 7.00
1.10E+03 1.90 2.20 7.00
6.16E+02 1.65 2.20 7.00
1.02E+03 2.89 2.20 7.00
9.71 E+01 2.05 2.20 7.00
2.59E+02 0.95 2.20 7.00
2.78E+02 1.14 2.20 7.00 10000 1000
7.96E+02 1.27 2.20 7.00
9.32E+02 2.08 2.20 7.00
1.40E+03 0.56 2.20 7.00
1.23E+03 0.43 2.20 7.00
6.90E+02 0.58 2.20 7.00
1.10E+03 0.82 2.20 7.00
1.10E+00 21.87 2.20 7.00
1.10E+00 11.08 2.20 7.00
1.10E+00 26.16 2.20 7.00
1.10E+00 22.29 2.20 7.00
1.10E+00 19.30 2.20 7.00
1.10E+00 20.29 2.20 7.00
1.10E+00 17.98 2.20 7.00
1.10E+00 24.28 2.20 7.00
1.10E+00 25.88 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.13E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.31E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.29E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-764
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Ca CFS-L01-1315-T01-A 1 1.82E+04
Ca CFS-L01-1315-T02-A 1 3.48E+04
Ca CFS-L01-1315-T03-A 1 2.26E+04
Ca CFS-L01-1315-T04-A 1 6.45E+04
Ca CFS-L01-1315-T05-A 1 7.01 E+04
Ca CFS-L01-1315-T06-A 1 1.07E+05
Ca CFS-L01-1315-T07-A 1 1.05E+05
Ca CFS-L01-1315-T08-A 1 5.95E+04
Ca CFS-L01-1315-T09-A 1 9.82E+04
Ca CFS-L01-1315-T01-B 1 1.79E+04
Ca CFS-L01-1315-T02-B 1 4.00E+04
Ca CFS-L01-1315-T03-B 1 3.09E+04
Ca CFS-L01-1315-T04-B 1 6.36E+04
Ca CFS-L01-1315-T05-B 1 7.66E+04
Ca CFS-L01-1315-T06-B 1 1.12E+05
Ca CFS-L01-1315-T07-B 1 1.05E+05
Ca CFS-L01-1315-T08-B 1 6.13E+04
Ca CFS-L01-1315-T09-B 1 1.05E+05
Ca CFS-L01-1315-T01-C 1 1.91 E+04
Ca CFS-L01-1315-T02-C 1 3.01 E+04
Ca CFS-L01-1315-T03-C 1 3.02E+04
Ca CFS-L01-1315-T04-C 1 6.88E+04
Ca CFS-L01-1315-T05-C 1 7.83E+04
Ca CFS-L01-1315-T06-C 1 1.20E+05
Ca CFS-L01-1315-T07-C 1 1.11E+05
Ca CFS-L01-1315-T08-C 1 6.57E+04
Ca CFS-L01-1315-T09-C 1 1.08E+05
Ca CFS-L01-1315-M01-A 1 6.80E+01
Ca CFS-L01-1315-M02-A 1 5.96E+01
Ca CFS-L01-1315-M03-A 1 4.41E+01
Ca CFS-L01-1315-M04-A 1 5.92E+01
Ca CFS-L01-1315-M05-A 1 3.69E+01
Ca CFS-L01-1315-M06-A 1 4.46E+01
Ca CFS-L01-1315-M07-A 1 4.30E+01
Ca CFS-L01-1315-M08-A 1 3.24E+01
Ca CFS-L01-1315-M09-A 1 1.61E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.82E+04 0.73 2.60 8.30
3.48E+04 0.52 2.60 8.30
2.26E+04 0.89 2.60 8.30 10000 1000
6.45E+04 6.17 2.60 8.30
7.01 E+04 1.74 2.60 8.30
1.07E+05 2.13 2.60 8.30
1.05E+05 0.60 2.60 8.30
5.95E+04 0.86 2.60 8.30
9.82E+04 1.00 2.60 8.30
1.79E+04 4.36 2.60 8.30
4.00E+04 1.33 2.60 8.30
3.09E+04 2.02 2.60 8.30 10000 1000
6.36E+04 0.48 2.60 8.30
7.66E+04 1.11 2.60 8.30
1.12E+05 0.70 2.60 8.30
1.05E+05 1.89 2.60 8.30
6.13E+04 1.87 2.60 8.30
1.05E+05 2.77 2.60 8.30
1.91 E+04 1.52 2.60 8.30
3.01 E+04 0.98 2.60 8.30
3.02E+04 1.53 2.60 8.30 10000 1000
6.88E+04 1.51 2.60 8.30
7.83E+04 2.18 2.60 8.30
1.20E+05 1.11 2.60 8.30
1.11E+05 0.52 2.60 8.30
6.57E+04 0.44 2.60 8.30
1.08E+05 1.24 2.60 8.30
6.80E+01 8.21 2.60 8.30
5.96E+01 8.59 2.60 8.30
4.41E+01 2.35 2.60 8.30
5.92E+01 4.86 2.60 8.30
3.69E+01 5.67 2.60 8.30
4.46E+01 15.99 2.60 8.30
4.30E+01 8.22 2.60 8.30
3.24E+01 12.99 2.60 8.30
1.61E+01 8.31 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.36E+04 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.18E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3. 11 E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315CFS
8/10/11 1:24 PM EPA Interlab L01 1315CFS
8/10/11 1:26 PM EPA Interlab L01 1315CFS
8/10/11 1:27 PM EPA Interlab L01 1315CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315CFS
1-765
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Cr CFS-L01-1315-T01-A 1 6.00E-01 U1/2
Cr CFS-L01-1315-T02-A 1 6.00E-01 U1/2
Cr CFS-L01-1315-T03-A 1 6.00E-01 U1/2
Cr CFS-L01-1315-T04-A 1 6.00E-01 U1/2
Cr CFS-L01-1315-T05-A 1 6.00E-01 U1/2
Cr CFS-L01-1315-T06-A 1 6.00E-01 U1/2
Cr CFS-L01-1315-T07-A 1 6.00E-01 U1/2
Cr CFS-L01-1315-T08-A 1 6.00E-01 U1/2
Cr CFS-L01-1315-T09-A 1 6.00E-01 U1/2
Cr CFS-L01-1315-T01-B 1 6.00E-01 U1/2
Cr CFS-L01-1315-T02-B 1 6.00E-01 U1/2
Cr CFS-L01-1315-T03-B 1 6.00E-01 U1/2
Cr CFS-L01-1315-T04-B 1 6.00E-01 U1/2
Cr CFS-L01-1315-T05-B 1 6.00E-01 U1/2
Cr CFS-L01-1315-T06-B 1 6.00E-01 U1/2
Cr CFS-L01-1315-T07-B 1 6.00E-01 U1/2
Cr CFS-L01-1315-T08-B 1 6.00E-01 U1/2
Cr CFS-L01-1315-T09-B 1 6.00E-01 U1/2
Cr CFS-L01-1315-T01-C 1 6.00E-01 U1/2
Cr CFS-L01-1315-T02-C 1 6.00E-01 U1/2
Cr CFS-L01-1315-T03-C 1 6.00E-01 U1/2
Cr CFS-L01-1315-T04-C 1 6.00E-01 U1/2
Cr CFS-L01-1315-T05-C 1 6.00E-01 U1/2
Cr CFS-L01-1315-T06-C 1 6.00E-01 U1/2
Cr CFS-L01-1315-T07-C 1 6.00E-01 U1/2
Cr CFS-L01-1315-T08-C 1 6.00E-01 U1/2
Cr CFS-L01-1315-T09-C 1 6.00E-01 U1/2
Cr CFS-L01-1315-M01-A 1 6.00E-01 U1/2
Cr CFS-L01-1315-M02-A 1 6.00E-01 U1/2
Cr CFS-L01-1315-M03-A 1 6.00E-01 U1/2
Cr CFS-L01-1315-M04-A 1 6.00E-01 U1/2
Cr CFS-L01-1315-M05-A 1 6.00E-01 U1/2
Cr CFS-L01-1315-M06-A 1 6.00E-01 U1/2
Cr CFS-L01-1315-M07-A 1 6.00E-01 U1/2
Cr CFS-L01-1315-M08-A 1 6.00E-01 U1/2
Cr CFS-L01-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 67.45 1.20 3.82
6.00E-01 55.60 1.20 3.82
6.00E-01 40.52 1.20 3.82 10000 1000
6.00E-01 21.03 1.20 3.82
6.00E-01 9.69 1.20 3.82
6.00E-01 45.07 1.20 3.82
6.00E-01 25.86 1.20 3.82
6.00E-01 11.91 1.20 3.82
6.00E-01 59.38 1.20 3.82
6.00E-01 75.30 1.20 3.82
6.00E-01 43.62 1.20 3.82
6.00E-01 36.47 1.20 3.82 10000 1000
6.00E-01 18.11 1.20 3.82
6.00E-01 73.18 1.20 3.82
6.00E-01 10.45 1.20 3.82
6.00E-01 59.32 1.20 3.82
6.00E-01 68.78 1.20 3.82
6.00E-01 31.61 1.20 3.82
6.00E-01 37.71 1.20 3.82
6.00E-01 7.43 1.20 3.82
6.00E-01 18.19 1.20 3.82 10000 1000
6.00E-01 77.40 1.20 3.82
6.00E-01 28.10 1.20 3.82
6.00E-01 11.35 1.20 3.82
6.00E-01 98.71 1.20 3.82
6.00E-01 79.90 1.20 3.82
6.00E-01 15.61 1.20 3.82
6.00E-01 59.55 1.20 3.82
6.00E-01 34.10 1.20 3.82
6.00E-01 47.29 1.20 3.82
6.00E-01 52.60 1.20 3.82
6.00E-01 24.90 1.20 3.82
6.00E-01 75.27 1.20 3.82
6.00E-01 57.38 1.20 3.82
6.00E-01 15.33 1.20 3.82
6.00E-01 49.43 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.73E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.06E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.22E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-766
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Co CFS-L01-1315-T01-A 1 9.00E-01 U1/2
Co CFS-L01-1315-T02-A 1 6.15E+00
Co CFS-L01-1315-T03-A 1 4.89E+00 E
Co CFS-L01-1315-T04-A 1 2.28E+01
Co CFS-L01-1315-T05-A 1 2.62E+01
Co CFS-L01-1315-T06-A 1 4.00E+01
Co CFS-L01-1315-T07-A 1 3.77E+01
Co CFS-L01-1315-T08-A 1 1.92E+01
Co CFS-L01-1315-T09-A 1 3.28E+01
Co CFS-L01-1315-T01-B 1 9.00E-01 U1/2
Co CFS-L01-1315-T02-B 1 5.94E+00
Co CFS-L01-1315-T03-B 1 6.75E+00
Co CFS-L01-1315-T04-B 1 2.02E+01
Co CFS-L01-1315-T05-B 1 2.62E+01
Co CFS-L01-1315-T06-B 1 4.03E+01
Co CFS-L01-1315-T07-B 1 3.58E+01
Co CFS-L01-1315-T08-B 1 1.96E+01
Co CFS-L01-1315-T09-B 1 3.38E+01
Co CFS-L01-1315-T01-C 1 9.00E-01 U1/2
Co CFS-L01-1315-T02-C 1 5.44E+00 E
Co CFS-L01-1315-T03-C 1 6.64E+00
Co CFS-L01-1315-T04-C 1 2.17E+01
Co CFS-L01-1315-T05-C 1 2.80E+01
Co CFS-L01-1315-T06-C 1 4.36E+01
Co CFS-L01-1315-T07-C 1 3.98E+01
Co CFS-L01-1315-T08-C 1 2.23E+01
Co CFS-L01-1315-T09-C 1 3.51 E+01
Co CFS-L01-1315-M01-A 1 9.00E-01 U1/2
Co CFS-L01-1315-M02-A 1 9.00E-01 U1/2
Co CFS-L01-1315-M03-A 1 9.00E-01 U1/2
Co CFS-L01-1315-M04-A 1 9.00E-01 U1/2
Co CFS-L01-1315-M05-A 1 9.00E-01 U1/2
Co CFS-L01-1315-M06-A 1 9.00E-01 U1/2
Co CFS-L01-1315-M07-A 1 9.00E-01 U1/2
Co CFS-L01-1315-M08-A 1 9.00E-01 U1/2
Co CFS-L01-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 32.51 1.80 5.72
6.15E+00 11.14 1.80 5.72
4.89E+00 9.21 1.80 5.72 10000 1000
2.28E+01 7.42 1.80 5.72
2.62E+01 2.18 1.80 5.72
4.00E+01 1.41 1.80 5.72
3.77E+01 1.18 1.80 5.72
1.92E+01 3.34 1.80 5.72
3.28E+01 1.44 1.80 5.72
9.00E-01 41.98 1.80 5.72
5.94E+00 10.92 1.80 5.72
6.75E+00 8.67 1.80 5.72 10000 1000
2.02E+01 6.42 1.80 5.72
2.62E+01 1.80 1.80 5.72
4.03E+01 0.95 1.80 5.72
3.58E+01 1.65 1.80 5.72
1.96E+01 3.23 1.80 5.72
3.38E+01 3.03 1.80 5.72
9.00E-01 9.73 1.80 5.72
5.44E+00 16.27 1.80 5.72
6.64E+00 5.44 1.80 5.72 10000 1000
2.17E+01 4.50 1.80 5.72
2.80E+01 0.37 1.80 5.72
4.36E+01 2.37 1.80 5.72
3.98E+01 2.12 1.80 5.72
2.23E+01 3.63 1.80 5.72
3.51E+01 2.93 1.80 5.72
9.00E-01 36.02 1.80 5.72
9.00E-01 4.60 1.80 5.72
9.00E-01 17.66 1.80 5.72
9.00E-01 34.89 1.80 5.72
9.00E-01 45.05 1.80 5.72
9.00E-01 23.68 1.80 5.72
9.00E-01 22.37 1.80 5.72
9.00E-01 16.96 1.80 5.72
9.00E-01 38.83 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.98E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.42E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.53E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-767
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Cu CFS-L01-1315-T01-A 1 7.33E+01
Cu CFS-L01-1315-T02-A 1 1.96E+02
Cu CFS-L01-1315-T03-A 1 1.75E+02
Cu CFS-L01-1315-T04-A 1 3.10E+02
Cu CFS-L01-1315-T05-A 1 3.28E+02
Cu CFS-L01-1315-T06-A 1 4.84E+02
Cu CFS-L01-1315-T07-A 1 5.50E+02
Cu CFS-L01-1315-T08-A 1 3.87E+02
Cu CFS-L01-1315-T09-A 1 5.59E+02
Cu CFS-L01-1315-T01-B 1 1.07E+02
Cu CFS-L01-1315-T02-B 1 1.90E+02
Cu CFS-L01-1315-T03-B 1 1.74E+02
Cu CFS-L01-1315-T04-B 1 2.68E+02
Cu CFS-L01-1315-T05-B 1 3.73E+02
Cu CFS-L01-1315-T06-B 1 4.93E+02
Cu CFS-L01-1315-T07-B 1 4.99E+02
Cu CFS-L01-1315-T08-B 1 3.72E+02
Cu CFS-L01-1315-T09-B 1 5.49E+02
Cu CFS-L01-1315-T01-C 1 9.80E+01
Cu CFS-L01-1315-T02-C 1 1.69E+02
Cu CFS-L01-1315-T03-C 1 1.78E+02
Cu CFS-L01-1315-T04-C 1 3.57E+02
Cu CFS-L01-1315-T05-C 1 3.69E+02
Cu CFS-L01-1315-T06-C 1 5.96E+02
Cu CFS-L01-1315-T07-C 1 5.74E+02
Cu CFS-L01-1315-T08-C 1 4.02E+02
Cu CFS-L01-1315-T09-C 1 6.38E+02
Cu CFS-L01-1315-M01-A 1 1.85E+00 U1/2
Cu CFS-L01-1315-M02-A 1 1.85E+00 U1/2
Cu CFS-L01-1315-M03-A 1 1.85E+00 U1/2
Cu CFS-L01-1315-M04-A 1 1.85E+00 U1/2
Cu CFS-L01-1315-M05-A 1 1.85E+00 U1/2
Cu CFS-L01-1315-M06-A 1 1.85E+00 U1/2
Cu CFS-L01-1315-M07-A 1 1.85E+00 U1/2
Cu CFS-L01-1315-M08-A 1 1.85E+00 U1/2
Cu CFS-L01-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.33E+01 1.56 3.70 11.80
1.96E+02 1.17 3.70 11.80
1.75E+02 1.76 3.70 11.80 10000 1000
3.10E+02 4.38 3.70 11.80
3.28E+02 2.59 3.70 11.80
4.84E+02 1.36 3.70 11.80
5.50E+02 1.49 3.70 11.80
3.87E+02 1.00 3.70 11.80
5.59E+02 0.55 3.70 11.80
1.07E+02 4.43 3.70 11.80
1.90E+02 3.47 3.70 11.80
1.74E+02 1.30 3.70 11.80 10000 1000
2.68E+02 1.22 3.70 11.80
3.73E+02 0.24 3.70 11.80
4.93E+02 0.87 3.70 11.80
4.99E+02 2.30 3.70 11.80
3.72E+02 1.86 3.70 11.80
5.49E+02 2.83 3.70 11.80
9.80E+01 1.50 3.70 11.80
1.69E+02 0.24 3.70 11.80
1.78E+02 2.54 3.70 11.80 10000 1000
3.57E+02 1.64 3.70 11.80
3.69E+02 2.36 3.70 11.80
5.96E+02 1.46 3.70 11.80
5.74E+02 1.16 3.70 11.80
4.02E+02 0.55 3.70 11.80
6.38E+02 0.70 3.70 11.80
1.85E+00 6.26 3.70 11.80
1.85E+00 10.55 3.70 11.80
1.85E+00 8.55 3.70 11.80
1.85E+00 4.16 3.70 11.80
1.85E+00 5.88 3.70 11.80
1.85E+00 0.86 3.70 11.80
1.85E+00 13.54 3.70 11.80
1.85E+00 32.54 3.70 11.80
1.85E+00 0.35 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.15E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.13E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.19E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315CFS
8/10/11 1:42 PM EPA Interlab L01 1315CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-768
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Fe CFS-L01-1315-T01-A 1 1.00E+00 U1/2
Fe CFS-L01-1315-T02-A 1 1.00E+00 U1/2
Fe CFS-L01-1315-T03-A 1 1.00E+00 U1/2
Fe CFS-L01-1315-T04-A 1 1.00E+00 U1/2
Fe CFS-L01-1315-T05-A 1 1.00E+00 U1/2
Fe CFS-L01-1315-T06-A 1 1.00E+00 U1/2
Fe CFS-L01-1315-T07-A 1 1.00E+00 U1/2
Fe CFS-L01-1315-T08-A 1 1.00E+00 U1/2
Fe CFS-L01-1315-T09-A 1 1.00E+00 U1/2
Fe CFS-L01-1315-T01-B 1 1.00E+00 U1/2
Fe CFS-L01-1315-T02-B 1 1.00E+00 U1/2
Fe CFS-L01-1315-T03-B 1 1.00E+00 U1/2
Fe CFS-L01-1315-T04-B 1 1.00E+00 U1/2
Fe CFS-L01-1315-T05-B 1 1.00E+00 U1/2
Fe CFS-L01-1315-T06-B 1 1.00E+00 U1/2
Fe CFS-L01-1315-T07-B 1 1.00E+00 U1/2
Fe CFS-L01-1315-T08-B 1 1.00E+00 U1/2
Fe CFS-L01-1315-T09-B 1 1.00E+00 U1/2
Fe CFS-L01-1315-T01-C 1 1.00E+00 U1/2
Fe CFS-L01-1315-T02-C 1 1.00E+00 U1/2
Fe CFS-L01-1315-T03-C 1 1.00E+00 U1/2
Fe CFS-L01-1315-T04-C 1 1.00E+00 U1/2
Fe CFS-L01-1315-T05-C 1 1.00E+00 U1/2
Fe CFS-L01-1315-T06-C 1 1.00E+00 U1/2
Fe CFS-L01-1315-T07-C 1 1.00E+00 U1/2
Fe CFS-L01-1315-T08-C 1 1.00E+00 U1/2
Fe CFS-L01-1315-T09-C 1 1.00E+00 U1/2
Fe CFS-L01-1315-M01-A 1 1.00E+00 U1/2
Fe CFS-L01-1315-M02-A 1 1.00E+00 U1/2
Fe CFS-L01-1315-M03-A 1 1.00E+00 U1/2
Fe CFS-L01-1315-M04-A 1 1.00E+00 U1/2
Fe CFS-L01-1315-M05-A 1 1.00E+00 U1/2
Fe CFS-L01-1315-M06-A 1 1.00E+00 U1/2
Fe CFS-L01-1315-M07-A 1 1.00E+00 U1/2
Fe CFS-L01-1315-M08-A 1 1.00E+00 U1/2
Fe CFS-L01-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 3.40 2.00 6.40
1.00E+00 10.14 2.00 6.40
1.00E+00 4.50 2.00 6.40 10000 1000
1.00E+00 7.71 2.00 6.40
1.00E+00 1.65 2.00 6.40
1.00E+00 5.48 2.00 6.40
1.00E+00 4.15 2.00 6.40
1.00E+00 14.07 2.00 6.40
1.00E+00 1.21 2.00 6.40
1.00E+00 17.67 2.00 6.40
1.00E+00 4.49 2.00 6.40
1.00E+00 3.78 2.00 6.40 10000 1000
1.00E+00 1.63 2.00 6.40
1.00E+00 6.78 2.00 6.40
1.00E+00 6.29 2.00 6.40
1.00E+00 1.34 2.00 6.40
1.00E+00 1.91 2.00 6.40
1.00E+00 3.80 2.00 6.40
1.00E+00 2.92 2.00 6.40
1.00E+00 6.27 2.00 6.40
1.00E+00 7.23 2.00 6.40 10000 1000
1.00E+00 0.95 2.00 6.40
1.00E+00 5.70 2.00 6.40
1.00E+00 3.99 2.00 6.40
1.00E+00 1.97 2.00 6.40
1.00E+00 1.98 2.00 6.40
1.00E+00 0.31 2.00 6.40
1.00E+00 2.35 2.00 6.40
1.00E+00 2.46 2.00 6.40
1.00E+00 9.02 2.00 6.40
1.00E+00 2.74 2.00 6.40
1.00E+00 2.87 2.00 6.40
1.00E+00 8.70 2.00 6.40
1.00E+00 4.52 2.00 6.40
1.00E+00 3.06 2.00 6.40
1.00E+00 3.79 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.93E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.38E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.38E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-769
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Pb CFS-L01-1315-T01-A 1 6.28E+01
Pb CFS-L01-1315-T02-A 1 1.59E+02
Pb CFS-L01-1315-T03-A 1 7.61E+01
Pb CFS-L01-1315-T04-A 1 2.28E+02
Pb CFS-L01-1315-T05-A 1 2.14E+02
Pb CFS-L01-1315-T06-A 1 3.15E+02
Pb CFS-L01-1315-T07-A 1 3.85E+02
Pb CFS-L01-1315-T08-A 1 2.07E+02
Pb CFS-L01-1315-T09-A 1 3.80E+02
Pb CFS-L01-1315-T01-B 1 6.30E+01
Pb CFS-L01-1315-T02-B 1 2.14E+02
Pb CFS-L01-1315-T03-B 1 1.22E+02
Pb CFS-L01-1315-T04-B 1 1.89E+02
Pb CFS-L01-1315-T05-B 1 2.94E+02
Pb CFS-L01-1315-T06-B 1 3.38E+02
Pb CFS-L01-1315-T07-B 1 3.44E+02
Pb CFS-L01-1315-T08-B 1 1.92E+02
Pb CFS-L01-1315-T09-B 1 3.78E+02
Pb CFS-L01-1315-T01-C 1 6.77E+01
Pb CFS-L01-1315-T02-C 1 1.54E+02
Pb CFS-L01-1315-T03-C 1 1.08E+02
Pb CFS-L01-1315-T04-C 1 2.80E+02
Pb CFS-L01-1315-T05-C 1 2.68E+02
Pb CFS-L01-1315-T06-C 1 4.73E+02
Pb CFS-L01-1315-T07-C 1 3.93E+02
Pb CFS-L01-1315-T08-C 1 2.13E+02
Pb CFS-L01-1315-T09-C 1 4.61 E+02
Pb CFS-L01-1315-M01-A 1 3.40E+00 U1/2
Pb CFS-L01-1315-M02-A 1 3.40E+00 U1/2
Pb CFS-L01-1315-M03-A 1 3.40E+00 U1/2
Pb CFS-L01-1315-M04-A 1 3.40E+00 U1/2
Pb CFS-L01-1315-M05-A 1 3.40E+00 U1/2
Pb CFS-L01-1315-M06-A 1 3.40E+00 U1/2
Pb CFS-L01-1315-M07-A 1 3.40E+00 U1/2
Pb CFS-L01-1315-M08-A 1 3.40E+00 U1/2
Pb CFS-L01-1315-M09-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.28E+01 4.36 6.80 21.60
1.59E+02 0.89 6.80 21.60
7.61E+01 3.83 6.80 21.60 10000 1000
2.28E+02 6.39 6.80 21.60
2.14E+02 0.80 6.80 21.60
3.15E+02 3.16 6.80 21.60
3.85E+02 0.46 6.80 21.60
2.07E+02 0.69 6.80 21.60
3.80E+02 1.25 6.80 21.60
6.30E+01 4.91 6.80 21.60
2.14E+02 0.98 6.80 21.60
1.22E+02 1.87 6.80 21.60 10000 1000
1.89E+02 2.10 6.80 21.60
2.94E+02 2.27 6.80 21.60
3.38E+02 1.24 6.80 21.60
3.44E+02 2.45 6.80 21.60
1.92E+02 0.84 6.80 21.60
3.78E+02 3.75 6.80 21.60
6.77E+01 4.15 6.80 21.60
1.54E+02 2.46 6.80 21.60
1.08E+02 1.47 6.80 21.60 10000 1000
2.80E+02 1.17 6.80 21.60
2.68E+02 3.20 6.80 21.60
4.73E+02 1.94 6.80 21.60
3.93E+02 0.67 6.80 21.60
2.13E+02 1.22 6.80 21.60
4.61 E+02 3.07 6.80 21.60
3.40E+00 16.66 6.80 21.60
3.40E+00 6.75 6.80 21.60
3.40E+00 7.00 6.80 21.60
3.40E+00 22.19 6.80 21.60
3.40E+00 2.22 6.80 21.60
3.40E+00 16.49 6.80 21.60
3.40E+00 22.83 6.80 21.60
3.40E+00 9.13 6.80 21.60
3.40E+00 2.29 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-770
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Li CFS-L01-1315-T01-A 1 2.08E+00 E
Li CFS-L01-1315-T02-A 1 4.80E+00 E
Li CFS-L01-1315-T03-A 1 4.94E+00 E
Li CFS-L01-1315-T04-A 1 5.39E+00 E
Li CFS-L01-1315-T05-A 1 5.08E+00 E
Li CFS-L01-1315-T06-A 1 7.06E+00
Li CFS-L01-1315-T07-A 1 6.60E+00
Li CFS-L01-1315-T08-A 1 6.67E+00
Li CFS-L01-1315-T09-A 1 6.23E+00
Li CFS-L01-1315-T01-B 1 2.34E+00 E
Li CFS-L01-1315-T02-B 1 4.95E+00 E
Li CFS-L01-1315-T03-B 1 5.10E+00 E
Li CFS-L01-1315-T04-B 1 5.75E+00 E
Li CFS-L01-1315-T05-B 1 5.76E+00 E
Li CFS-L01-1315-T06-B 1 5.97E+00 E
Li CFS-L01-1315-T07-B 1 6.83E+00
Li CFS-L01-1315-T08-B 1 6.70E+00
Li CFS-L01-1315-T09-B 1 8.40E+00
Li CFS-L01-1315-T01-C 1 2.68E+00 E
Li CFS-L01-1315-T02-C 1 4.41 E+00 E
Li CFS-L01-1315-T03-C 1 5.46E+00 E
Li CFS-L01-1315-T04-C 1 6.99E+00
Li CFS-L01-1315-T05-C 1 6.12E+00
Li CFS-L01-1315-T06-C 1 4.98E+00 E
Li CFS-L01-1315-T07-C 1 6.68E+00
Li CFS-L01-1315-T08-C 1 5.51 E+00 E
Li CFS-L01-1315-T09-C 1 7. 41 E+00
Li CFS-L01-1315-M01-A 1 9.50E-01 U1/2
Li CFS-L01-1315-M02-A 1 9.50E-01 U1/2
Li CFS-L01-1315-M03-A 1 9.50E-01 U1/2
Li CFS-L01-1315-M04-A 1 9.50E-01 U1/2
Li CFS-L01-1315-M05-A 1 9.50E-01 U1/2
Li CFS-L01-1315-M06-A 1 9.50E-01 U1/2
Li CFS-L01-1315-M07-A 1 9.50E-01 U1/2
Li CFS-L01-1315-M08-A 1 9.50E-01 U1/2
Li CFS-L01-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.08E+00 8.59 1.90 6.00
4.80E+00 27.67 1.90 6.00
4.94E+00 44.81 1.90 6.00 10000 1000
5.39E+00 25.31 1.90 6.00
5.08E+00 19.59 1.90 6.00
7.06E+00 9.14 1.90 6.00
6.60E+00 1.38 1.90 6.00
6.67E+00 4.75 1.90 6.00
6.23E+00 16.62 1.90 6.00
2.34E+00 5.45 1.90 6.00
4.95E+00 24.48 1.90 6.00
5.10E+00 15.44 1.90 6.00 10000 1000
5.75E+00 38.46 1.90 6.00
5.76E+00 33.16 1.90 6.00
5.97E+00 17.52 1.90 6.00
6.83E+00 1.08 1.90 6.00
6.70E+00 2.24 1.90 6.00
8.40E+00 10.35 1.90 6.00
2.68E+00 9.75 1.90 6.00
4.41E+00 18.82 1.90 6.00
5.46E+00 18.06 1.90 6.00 10000 1000
6.99E+00 2.03 1.90 6.00
6.12E+00 1.50 1.90 6.00
4.98E+00 17.81 1.90 6.00
6.68E+00 1.53 1.90 6.00
5.51E+00 1.91 1.90 6.00
7.41E+00 5.49 1.90 6.00
9.50E-01 15.73 1.90 6.00
9.50E-01 37.66 1.90 6.00
9.50E-01 31.66 1.90 6.00
9.50E-01 9.95 1.90 6.00
9.50E-01 37.35 1.90 6.00
9.50E-01 25.80 1.90 6.00
9.50E-01 3.82 1.90 6.00
9.50E-01 5.31 1.90 6.00
9.50E-01 30.10 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.99E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.73E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.54E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabL01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-771
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
Mn CFS-L01-1315-T01-A 1 3.04E+01
Mn CFS-L01-1315-T02-A 1 1.86E+02
Mn CFS-L01-1315-T03-A 1 1.53E+02
Mn CFS-L01-1315-T04-A 1 5.95E+02
Mn CFS-L01-1315-T05-A 1 6.83E+02
Mn CFS-L01-1315-T06-A 1 1.11E+03
Mn CFS-L01-1315-T07-A 1 1.08E+03
Mn CFS-L01-1315-T08-A 1 5.87E+02
Mn CFS-L01-1315-T09-A 1 1.03E+03
Mn CFS-L01-1315-T01-B 1 4.50E+01
Mn CFS-L01-1315-T02-B 1 1.85E+02
Mn CFS-L01-1315-T03-B 1 1.67E+02
Mn CFS-L01-1315-T04-B 1 5.43E+02
Mn CFS-L01-1315-T05-B 1 6.76E+02
Mn CFS-L01-1315-T06-B 1 1.10E+03
Mn CFS-L01-1315-T07-B 1 1.05E+03
Mn CFS-L01-1315-T08-B 1 5.88E+02
Mn CFS-L01-1315-T09-B 1 1.05E+03
Mn CFS-L01-1315-T01-C 1 4.43E+01
Mn CFS-L01-1315-T02-C 1 1.62E+02
Mn CFS-L01-1315-T03-C 1 1.80E+02
Mn CFS-L01-1315-T04-C 1 5.73E+02
Mn CFS-L01-1315-T05-C 1 7.22E+02
Mn CFS-L01-1315-T06-C 1 1.20E+03
Mn CFS-L01-1315-T07-C 1 1.16E+03
Mn CFS-L01-1315-T08-C 1 6.65E+02
Mn CFS-L01-1315-T09-C 1 1.07E+03
Mn CFS-L01-1315-M01-A 1 1.00E+00 U1/2
Mn CFS-L01-1315-M02-A 1 1.00E+00 U1/2
Mn CFS-L01-1315-M03-A 1 1.00E+00 U1/2
Mn CFS-L01-1315-M04-A 1 1.00E+00 U1/2
Mn CFS-L01-1315-M05-A 1 1.00E+00 U1/2
Mn CFS-L01-1315-M06-A 1 1.00E+00 U1/2
Mn CFS-L01-1315-M07-A 1 1.00E+00 U1/2
Mn CFS-L01-1315-M08-A 1 1.00E+00 U1/2
Mn CFS-L01-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.04E+01 0.83 2.00 6.40
1.86E+02 1.71 2.00 6.40
1.53E+02 1.41 2.00 6.40 10000 1000
5.95E+02 5.27 2.00 6.40
6.83E+02 1.86 2.00 6.40
1.11E+03 1.31 2.00 6.40
1.08E+03 1.77 2.00 6.40
5.87E+02 0.93 2.00 6.40
1.03E+03 1.31 2.00 6.40
4.50E+01 2.78 2.00 6.40
1.85E+02 1.06 2.00 6.40
1.67E+02 2.20 2.00 6.40 10000 1000
5.43E+02 1.08 2.00 6.40
6.76E+02 1.47 2.00 6.40
1.10E+03 0.59 2.00 6.40
1.05E+03 1.22 2.00 6.40
5.88E+02 2.34 2.00 6.40
1.05E+03 6.27 2.00 6.40
4.43E+01 1.59 2.00 6.40
1.62E+02 0.83 2.00 6.40
1.80E+02 0.63 2.00 6.40 10000 1000
5.73E+02 0.59 2.00 6.40
7.22E+02 0.58 2.00 6.40
1.20E+03 2.17 2.00 6.40
1.16E+03 0.71 2.00 6.40
6.65E+02 1.95 2.00 6.40
1.07E+03 0.70 2.00 6.40
1.00E+00 1.37 2.00 6.40
1.00E+00 1.06 2.00 6.40
1.00E+00 1.66 2.00 6.40
1.00E+00 0.91 2.00 6.40
1.00E+00 1.18 2.00 6.40
1.00E+00 2.05 2.00 6.40
1.00E+00 4.61 2.00 6.40
1.00E+00 3.16 2.00 6.40
1.00E+00 4.19 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.05E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.20E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-772
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Mg CFS-L01-1315-T01-A 1 1.85E+03
Mg CFS-L01-1315-T02-A 1 1.10E+04
Mg CFS-L01-1315-T03-A 1 9.24E+03
Mg CFS-L01-1315-T04-A 1 4.18E+04
Mg CFS-L01-1315-T05-A 1 4.89E+04
Mg CFS-L01-1315-T06-A 1 7.68E+04
Mg CFS-L01-1315-T07-A 1 6.76E+04
Mg CFS-L01-1315-T08-A 1 3.38E+04
Mg CFS-L01-1315-T09-A 1 5.42E+04
Mg CFS-L01-1315-T01-B 1 2.51E+03
Mg CFS-L01-1315-T02-B 1 1.06E+04
Mg CFS-L01-1315-T03-B 1 9.69E+03
Mg CFS-L01-1315-T04-B 1 3.70E+04
Mg CFS-L01-1315-T05-B 1 5.05E+04
Mg CFS-L01-1315-T06-B 1 8.11E+04
Mg CFS-L01-1315-T07-B 1 7.17E+04
Mg CFS-L01-1315-T08-B 1 3.64E+04
Mg CFS-L01-1315-T09-B 1 5.93E+04
Mg CFS-L01-1315-T01-C 1 2.37E+03
Mg CFS-L01-1315-T02-C 1 8.94E+03
Mg CFS-L01-1315-T03-C 1 1.04E+04
Mg CFS-L01-1315-T04-C 1 3.87E+04
Mg CFS-L01-1315-T05-C 1 5.18E+04
Mg CFS-L01-1315-T06-C 1 8.18E+04
Mg CFS-L01-1315-T07-C 1 7.12E+04
Mg CFS-L01-1315-T08-C 1 3.63E+04
Mg CFS-L01-1315-T09-C 1 5.51 E+04
Mg CFS-L01-1315-M01-A 1 1.52E+01
Mg CFS-L01-1315-M02-A 1 2.05E+01
Mg CFS-L01-1315-M03-A 1 5.00E-01 U1/2
Mg CFS-L01-1315-M04-A 1 5.00E-01 U1/2
Mg CFS-L01-1315-M05-A 1 5.00E-01 U1/2
Mg CFS-L01-1315-M06-A 1 5.00E-01 U1/2
Mg CFS-L01-1315-M07-A 1 5.00E-01 U1/2
Mg CFS-L01-1315-M08-A 1 5.00E-01 U1/2
Mg CFS-L01-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+03 0.62 1.00 3.18
1.10E+04 0.64 1.00 3.18
9.24E+03 1.78 1.00 3.18 10000 1000
4.18E+04 8.09 1.00 3.18
4.89E+04 1.75 1.00 3.18
7.68E+04 1.48 1.00 3.18
6.76E+04 0.77 1.00 3.18
3.38E+04 0.79 1.00 3.18
5.42E+04 0.99 1.00 3.18
2.51E+03 5.14 1.00 3.18
1.06E+04 2.00 1.00 3.18
9.69E+03 2.30 1.00 3.18 10000 1000
3.70E+04 1.13 1.00 3.18
5.05E+04 1.22 1.00 3.18
8.11E+04 0.38 1.00 3.18
7.17E+04 1.53 1.00 3.18
3.64E+04 2.68 1.00 3.18
5.93E+04 3.37 1.00 3.18
2.37E+03 2.92 1.00 3.18
8.94E+03 0.70 1.00 3.18
1.04E+04 2.23 1.00 3.18 10000 1000
3.87E+04 0.70 1.00 3.18
5.18E+04 1.72 1.00 3.18
8.18E+04 1.06 1.00 3.18
7.12E+04 1.19 1.00 3.18
3.63E+04 0.72 1.00 3.18
5.51E+04 2.26 1.00 3.18
1.52E+01 4.03 1.00 3.18
2.05E+01 9.43 1.00 3.18
5.00E-01 27.10 1.00 3.18
5.00E-01 23.09 1.00 3.18
5.00E-01 12.66 1.00 3.18
5.00E-01 2.28 1.00 3.18
5.00E-01 39.10 1.00 3.18
5.00E-01 24.70 1.00 3.18
5.00E-01 5.15 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+04 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+04 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-773
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Mo CFS-L01-1315-T01-A 1 1.63E+00 E
Mo CFS-L01-1315-T02-A 1 1.67E+00 E
Mo CFS-L01-1315-T03-A 1 2.24E+00 E
Mo CFS-L01-1315-T04-A 1 2.58E+00 E
Mo CFS-L01-1315-T05-A 1 2.61E+00 E
Mo CFS-L01-1315-T06-A 1 2.35E+00 E
Mo CFS-L01-1315-T07-A 1 2.80E+00 E
Mo CFS-L01-1315-T08-A 1 2.34E+00 E
Mo CFS-L01-1315-T09-A 1 2.10E+00 E
Mo CFS-L01-1315-T01-B 1 1.53E+00 E
Mo CFS-L01-1315-T02-B 1 1.93E+00 E
Mo CFS-L01-1315-T03-B 1 2.50E+00 E
Mo CFS-L01-1315-T04-B 1 2.47E+00 E
Mo CFS-L01-1315-T05-B 1 2.29E+00 E
Mo CFS-L01-1315-T06-B 1 2.78E+00 E
Mo CFS-L01-1315-T07-B 1 2.31E+00 E
Mo CFS-L01-1315-T08-B 1 1.81E+00 E
Mo CFS-L01-1315-T09-B 1 2.15E+00 E
Mo CFS-L01-1315-T01-C 1 1.87E+00 E
Mo CFS-L01-1315-T02-C 1 1.85E+00 E
Mo CFS-L01-1315-T03-C 1 2.74E+00 E
Mo CFS-L01-1315-T04-C 1 2.82E+00 E
Mo CFS-L01-1315-T05-C 1 2.62E+00 E
Mo CFS-L01-1315-T06-C 1 2.82E+00 E
Mo CFS-L01-1315-T07-C 1 2.10E+00 E
Mo CFS-L01-1315-T08-C 1 1.56E+00 E
Mo CFS-L01-1315-T09-C 1 1.89E+00 E
Mo CFS-L01-1315-M01-A 1 6.00E-01 U1/2
Mo CFS-L01-1315-M02-A 1 6.00E-01 U1/2
Mo CFS-L01-1315-M03-A 1 6.00E-01 U1/2
Mo CFS-L01-1315-M04-A 1 6.00E-01 U1/2
Mo CFS-L01-1315-M05-A 1 6.00E-01 U1/2
Mo CFS-L01-1315-M06-A 1 6.00E-01 U1/2
Mo CFS-L01-1315-M07-A 1 6.00E-01 U1/2
Mo CFS-L01-1315-M08-A 1 6.00E-01 U1/2
Mo CFS-L01-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.63E+00 35.56 1.20 3.82
1.67E+00 20.36 1.20 3.82
2.24E+00 35.72 1.20 3.82 10000 1000
2.58E+00 36.15 1.20 3.82
2.61 E+00 6.85 1.20 3.82
2.35E+00 7.17 1.20 3.82
2.80E+00 34.13 1.20 3.82
2.34E+00 21.10 1.20 3.82
2.10E+00 14.80 1.20 3.82
1.53E+00 24.53 1.20 3.82
1.93E+00 16.38 1.20 3.82
2.50E+00 26.81 1.20 3.82 10000 1000
2.47E+00 18.79 1.20 3.82
2.29E+00 27.85 1.20 3.82
2.78E+00 52.53 1.20 3.82
2.31E+00 19.06 1.20 3.82
1.81 E+00 24.32 1.20 3.82
2.15E+00 6.63 1.20 3.82
1.87E+00 35.68 1.20 3.82
1.85E+00 15.80 1.20 3.82
2.74E+00 4.03 1.20 3.82 10000 1000
2.82E+00 20.90 1.20 3.82
2.62E+00 15.82 1.20 3.82
2.82E+00 30.70 1.20 3.82
2.10E+00 35.83 1.20 3.82
1.56E+00 22.11 1.20 3.82
1.89E+00 24.32 1.20 3.82
6.00E-01 32.16 1.20 3.82
6.00E-01 15.50 1.20 3.82
6.00E-01 46.06 1.20 3.82
6.00E-01 34.04 1.20 3.82
6.00E-01 11.10 1.20 3.82
6.00E-01 52.89 1.20 3.82
6.00E-01 33.61 1.20 3.82
6.00E-01 12.23 1.20 3.82
6.00E-01 41.61 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.77E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.27E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.44E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-774
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ni CFS-L01-1315-T01-A 1 9.00E-01 U1/2
Ni CFS-L01-1315-T02-A 1 1.07E+01
Ni CFS-L01-1315-T03-A 1 1.14E+01
Ni CFS-L01-1315-T04-A 1 3.85E+01
Ni CFS-L01-1315-T05-A 1 4.41E+01
Ni CFS-L01-1315-T06-A 1 6.76E+01
Ni CFS-L01-1315-T07-A 1 5.85E+01
Ni CFS-L01-1315-T08-A 1 3.20E+01
Ni CFS-L01-1315-T09-A 1 5.04E+01
Ni CFS-L01-1315-T01-B 1 9.00E-01 U1/2
Ni CFS-L01-1315-T02-B 1 1.38E+01
Ni CFS-L01-1315-T03-B 1 1.37E+01
Ni CFS-L01-1315-T04-B 1 3.80E+01
Ni CFS-L01-1315-T05-B 1 4.66E+01
Ni CFS-L01-1315-T06-B 1 6.65E+01
Ni CFS-L01-1315-T07-B 1 5.92E+01
Ni CFS-L01-1315-T08-B 1 3.10E+01
Ni CFS-L01-1315-T09-B 1 5.44E+01
Ni CFS-L01-1315-T01-C 1 9.00E-01 U1/2
Ni CFS-L01-1315-T02-C 1 1.05E+01
Ni CFS-L01-1315-T03-C 1 1.35E+01
Ni CFS-L01-1315-T04-C 1 4.04E+01
Ni CFS-L01-1315-T05-C 1 4.94E+01
Ni CFS-L01-1315-T06-C 1 7.46E+01
Ni CFS-L01-1315-T07-C 1 6.42E+01
Ni CFS-L01-1315-T08-C 1 3.53E+01
Ni CFS-L01-1315-T09-C 1 5.81 E+01
Ni CFS-L01-1315-M01-A 1 9.00E-01 U1/2
Ni CFS-L01-1315-M02-A 1 9.00E-01 U1/2
Ni CFS-L01-1315-M03-A 1 9.00E-01 U1/2
Ni CFS-L01-1315-M04-A 1 9.00E-01 U1/2
Ni CFS-L01-1315-M05-A 1 9.00E-01 U1/2
Ni CFS-L01-1315-M06-A 1 9.00E-01 U1/2
Ni CFS-L01-1315-M07-A 1 9.00E-01 U1/2
Ni CFS-L01-1315-M08-A 1 9.00E-01 U1/2
Ni CFS-L01-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 19.18 1.80 5.70
1.07E+01 5.10 1.80 5.70
1.14E+01 16.96 1.80 5.70 10000 1000
3.85E+01 2.06 1.80 5.70
4.41 E+01 0.77 1.80 5.70
6.76E+01 2.35 1.80 5.70
5.85E+01 2.12 1.80 5.70
3.20E+01 1.49 1.80 5.70
5.04E+01 3.05 1.80 5.70
9.00E-01 13.83 1.80 5.70
1.38E+01 9.12 1.80 5.70
1.37E+01 8.37 1.80 5.70 10000 1000
3.80E+01 3.82 1.80 5.70
4.66E+01 1.31 1.80 5.70
6.65E+01 1.55 1.80 5.70
5.92E+01 3.04 1.80 5.70
3.10E+01 4.20 1.80 5.70
5.44E+01 2.93 1.80 5.70
9.00E-01 14.82 1.80 5.70
1.05E+01 4.86 1.80 5.70
1.35E+01 4.14 1.80 5.70 10000 1000
4.04E+01 4.27 1.80 5.70
4.94E+01 2.30 1.80 5.70
7.46E+01 1.93 1.80 5.70
6.42E+01 1.85 1.80 5.70
3.53E+01 2.89 1.80 5.70
5.81E+01 3.71 1.80 5.70
9.00E-01 18.47 1.80 5.70
9.00E-01 3.95 1.80 5.70
9.00E-01 24.11 1.80 5.70
9.00E-01 17.71 1.80 5.70
9.00E-01 40.07 1.80 5.70
9.00E-01 35.11 1.80 5.70
9.00E-01 10.23 1.80 5.70
9.00E-01 49.38 1.80 5.70
9.00E-01 10.43 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.77E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.47E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.52E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-775
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L
P CFS-L01-1315-T01-A 1 6.79E+00 E
P CFS-L01-1315-T02-A 1 1.39E+01
P CFS-L01-1315-T03-A 1 1.32E+01
P CFS-L01-1315-T04-A 1 1.81E+01
P CFS-L01-1315-T05-A 1 1.26E+01
P CFS-L01-1315-T06-A 1 1.05E+01 E
P CFS-L01-1315-T07-A 1 1.28E+01
P CFS-L01-1315-T08-A 1 9.28E+00 E
P CFS-L01-1315-T09-A 1 5.08E+00 E
P CFS-L01-1315-T01-B 1 7.76E+00 E
P CFS-L01-1315-T02-B 1 1.26E+01
P CFS-L01-1315-T03-B 1 1.24E+01
P CFS-L01-1315-T04-B 1 1.58E+01
P CFS-L01-1315-T05-B 1 1.02E+01 E
P CFS-L01-1315-T06-B 1 1.18E+01
P CFS-L01-1315-T07-B 1 1.03E+01 E
P CFS-L01-1315-T08-B 1 9.73E+00 E
P CFS-L01-1315-T09-B 1 6.61E+00 E
P CFS-L01-1315-T01-C 1 7.59E+00 E
P CFS-L01-1315-T02-C 1 1.10E+01 E
P CFS-L01-1315-T03-C 1 1.43E+01
P CFS-L01-1315-T04-C 1 1.73E+01
P CFS-L01-1315-T05-C 1 1.59E+01
P CFS-L01-1315-T06-C 1 1.31E+01
P CFS-L01-1315-T07-C 1 9.97E+00 E
P CFS-L01-1315-T08-C 1 8.27E+00 E
P CFS-L01-1315-T09-C 1 8.34E+00 E
P CFS-L01-1315-M01-A 1 1.85E+00 U1/2
P CFS-L01-1315-M02-A 1 1.85E+00 U1/2
P CFS-L01-1315-M03-A 1 1.85E+00 U1/2
P CFS-L01-1315-M04-A 1 1.85E+00 U1/2
P CFS-L01-1315-M05-A 1 1.85E+00 U1/2
P CFS-L01-1315-M06-A 1 1.85E+00 U1/2
P CFS-L01-1315-M07-A 1 1.85E+00 U1/2
P CFS-L01-1315-M08-A 1 1.85E+00 U1/2
P CFS-L01-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.79E+00 2.78 3.70 11.80
1.39E+01 1.46 3.70 11.80
1.32E+01 10.04 3.70 11.80 10000 1000
1.81E+01 2.05 3.70 11.80
1.26E+01 8.46 3.70 11.80
1.05E+01 6.36 3.70 11.80
1.28E+01 1.36 3.70 11.80
9.28E+00 6.22 3.70 11.80
5.08E+00 28.63 3.70 11.80
7.76E+00 3.77 3.70 11.80
1.26E+01 1.64 3.70 11.80
1.24E+01 3.41 3.70 11.80 10000 1000
1.58E+01 1.99 3.70 11.80
1.02E+01 7.34 3.70 11.80
1.18E+01 2.69 3.70 11.80
1.03E+01 19.17 3.70 11.80
9.73E+00 37.31 3.70 11.80
6.61 E+00 20.00 3.70 11.80
7.59E+00 13.71 3.70 11.80
1.10E+01 7.49 3.70 11.80
1.43E+01 2.92 3.70 11.80 10000 1000
1.73E+01 4.91 3.70 11.80
1.59E+01 6.86 3.70 11.80
1.31E+01 3.94 3.70 11.80
9.97E+00 7.58 3.70 11.80
8.27E+00 10.97 3.70 11.80
8.34E+00 14.33 3.70 11.80
1.85E+00 2.03 3.70 11.80
1.85E+00 4.90 3.70 11.80
1.85E+00 4.43 3.70 11.80
1.85E+00 6.15 3.70 11.80
1.85E+00 12.39 3.70 11.80
1.85E+00 5.55 3.70 11.80
1.85E+00 8.13 3.70 11.80
1.85E+00 8.04 3.70 11.80
1.85E+00 16.38 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.96E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.96E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.53E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-776
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
K CFS-L01-1315-T01-A 1 2.06E+02
K CFS-L01-1315-T02-A 1 1.51E+03
K CFS-L01-1315-T03-A 1 1.17E+03
K CFS-L01-1315-T04-A 1 5.06E+03
K CFS-L01-1315-T05-A 1 5.25E+03
K CFS-L01-1315-T06-A 1 7.74E+03
K CFS-L01-1315-T07-A 1 6.30E+03
K CFS-L01-1315-T08-A 1 2.97E+03
K CFS-L01-1315-T09-A 1 4.64E+03
K CFS-L01-1315-T01-B 1 2.96E+02
K CFS-L01-1315-T02-B 1 1.48E+03
K CFS-L01-1315-T03-B 1 1.27E+03
K CFS-L01-1315-T04-B 1 4.75E+03
K CFS-L01-1315-T05-B 1 5.52E+03
K CFS-L01-1315-T06-B 1 8.12E+03
K CFS-L01-1315-T07-B 1 6.41 E+03
K CFS-L01-1315-T08-B 1 3.03E+03
K CFS-L01-1315-T09-B 1 4.82E+03
K CFS-L01-1315-T01-C 1 2.77E+02
K CFS-L01-1315-T02-C 1 1.34E+03
K CFS-L01-1315-T03-C 1 1.38E+03
K CFS-L01-1315-T04-C 1 5.19E+03
K CFS-L01-1315-T05-C 1 5.73E+03
K CFS-L01-1315-T06-C 1 8.35E+03
K CFS-L01-1315-T07-C 1 6.64E+03
K CFS-L01-1315-T08-C 1 3.15E+03
K CFS-L01-1315-T09-C 1 4.78E+03
K CFS-L01-1315-M01-A 1 1.95E+01
K CFS-L01-1315-M02-A 1 1.46E+01
K CFS-L01-1315-M03-A 1 7.89E+00
K CFS-L01-1315-M04-A 1 2.31E+01
K CFS-L01-1315-M05-A 1 1.56E+01
K CFS-L01-1315-M06-A 1 8.18E+00
K CFS-L01-1315-M07-A 1 1.03E+01
K CFS-L01-1315-M08-A 1 1.08E+01
K CFS-L01-1315-M09-A 1 1.66E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.06E+02 0.09 1.60 5.09
1.51 E+03 0.55 1.60 5.09
1.17E+03 0.94 1.60 5.09 10000 1000
5.06E+03 6.15 1.60 5.09
5.25E+03 1.38 1.60 5.09
7.74E+03 1.96 1.60 5.09
6.30E+03 0.82 1.60 5.09
2.97E+03 0.95 1.60 5.09
4.64E+03 0.63 1.60 5.09
2.96E+02 3.91 1.60 5.09
1.48E+03 1.14 1.60 5.09
1.27E+03 1.70 1.60 5.09 10000 1000
4.75E+03 0.43 1.60 5.09
5.52E+03 1.31 1.60 5.09
8.12E+03 0.79 1.60 5.09
6.41 E+03 1.50 1.60 5.09
3.03E+03 1.80 1.60 5.09
4.82E+03 2.67 1.60 5.09
2.77E+02 2.57 1.60 5.09
1.34E+03 0.78 1.60 5.09
1.38E+03 1.39 1.60 5.09 10000 1000
5.19E+03 1.37 1.60 5.09
5.73E+03 2.34 1.60 5.09
8.35E+03 0.84 1.60 5.09
6.64E+03 0.33 1.60 5.09
3.15E+03 0.50 1.60 5.09
4.78E+03 1.06 1.60 5.09
1.95E+01 0.97 1.60 5.09
1.46E+01 2.57 1.60 5.09
7.89E+00 6.52 1.60 5.09
2.31E+01 5.74 1.60 5.09
1.56E+01 1.08 1.60 5.09
8.18E+00 4.43 1.60 5.09
1.03E+01 13.56 1.60 5.09
1.08E+01 3.48 1.60 5.09
1.66E+01 10.19 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.15E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.25E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.53E+03 115% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-777
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L
Se CFS-L01-1315-T01-A 1 2.26E+01 E
Se CFS-L01-1315-T02-A 1 2.64E+01 E
Se CFS-L01-1315-T03-A 1 2.94E+01 E
Se CFS-L01-1315-T04-A 1 7.41E+01
Se CFS-L01-1315-T05-A 1 5.76E+01
Se CFS-L01-1315-T06-A 1 8.63E+01
Se CFS-L01-1315-T07-A 1 6.57E+01
Se CFS-L01-1315-T08-A 1 3.71E+01 E
Se CFS-L01-1315-T09-A 1 3.99E+01 E
Se CFS-L01-1315-T01-B 1 2.38E+01 E
Se CFS-L01-1315-T02-B 1 2.72E+01 E
Se CFS-L01-1315-T03-B 1 1.82E+01 E
Se CFS-L01-1315-T04-B 1 5.18E+01
Se CFS-L01-1315-T05-B 1 6.75E+01
Se CFS-L01-1315-T06-B 1 8.78E+01
Se CFS-L01-1315-T07-B 1 8.32E+01
Se CFS-L01-1315-T08-B 1 3.82E+01 E
Se CFS-L01-1315-T09-B 1 3.31 E+01 E
Se CFS-L01-1315-T01-C 1 2.28E+01 E
Se CFS-L01-1315-T02-C 1 2.72E+01 E
Se CFS-L01-1315-T03-C 1 2.04E+01 E
Se CFS-L01-1315-T04-C 1 5.09E+01
Se CFS-L01-1315-T05-C 1 7.68E+01
Se CFS-L01-1315-T06-C 1 1.01E+02
Se CFS-L01-1315-T07-C 1 6.17E+01
Se CFS-L01-1315-T08-C 1 3.57E+01 E
Se CFS-L01-1315-T09-C 1 2.93E+01 E
Se CFS-L01-1315-M01-A 1 7.50E+00 U1/2
Se CFS-L01-1315-M02-A 1 7.50E+00 U1/2
Se CFS-L01-1315-M03-A 1 7.50E+00 U1/2
Se CFS-L01-1315-M04-A 1 7.50E+00 U1/2
Se CFS-L01-1315-M05-A 1 7.50E+00 U1/2
Se CFS-L01-1315-M06-A 1 7.50E+00 U1/2
Se CFS-L01-1315-M07-A 1 7.50E+00 U1/2
Se CFS-L01-1315-M08-A 1 7.50E+00 U1/2
Se CFS-L01-1315-M09-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.26E+01 6.71 15.00 47.70
2.64E+01 14.80 15.00 47.70
2.94E+01 2.78 15.00 47.70 10000 1000
7.41E+01 2.12 15.00 47.70
5.76E+01 12.99 15.00 47.70
8.63E+01 1.29 15.00 47.70
6.57E+01 7.64 15.00 47.70
3.71E+01 23.79 15.00 47.70
3.99E+01 15.59 15.00 47.70
2.38E+01 15.79 15.00 47.70
2.72E+01 9.55 15.00 47.70
1.82E+01 7.49 15.00 47.70 10000 1000
5.18E+01 11.92 15.00 47.70
6.75E+01 1.23 15.00 47.70
8.78E+01 1.66 15.00 47.70
8.32E+01 1.83 15.00 47.70
3.82E+01 7.86 15.00 47.70
3.31E+01 14.73 15.00 47.70
2.28E+01 7.14 15.00 47.70
2.72E+01 17.90 15.00 47.70
2.04E+01 7.66 15.00 47.70 10000 1000
5.09E+01 7.16 15.00 47.70
7.68E+01 9.13 15.00 47.70
1.01E+02 7.71 15.00 47.70
6.17E+01 1.19 15.00 47.70
3.57E+01 5.66 15.00 47.70
2.93E+01 5.55 15.00 47.70
7.50E+00 11.01 15.00 47.70
7.50E+00 26.40 15.00 47.70
7.50E+00 26.65 15.00 47.70
7.50E+00 10.18 15.00 47.70
7.50E+00 26.39 15.00 47.70
7.50E+00 29.28 15.00 47.70
7.50E+00 34.63 15.00 47.70
7.50E+00 13.17 15.00 47.70
7.50E+00 19.90 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.02E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.90E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.61 E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-778
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Si CFS-L01-1315-T01-A 1 5.37E+01
Si CFS-L01-1315-T02-A 1 2.34E+02
Si CFS-L01-1315-T03-A 1 2.04E+02
Si CFS-L01-1315-T04-A 1 7.33E+02
Si CFS-L01-1315-T05-A 1 8.12E+02
Si CFS-L01-1315-T06-A 1 1.25E+03
Si CFS-L01-1315-T07-A 1 1.26E+03
Si CFS-L01-1315-T08-A 1 7.29E+02
Si CFS-L01-1315-T09-A 1 1.22E+03
Si CFS-L01-1315-T01-B 1 6.42E+01
Si CFS-L01-1315-T02-B 1 2.50E+02
Si CFS-L01-1315-T03-B 1 2.40E+02
Si CFS-L01-1315-T04-B 1 6.67E+02
Si CFS-L01-1315-T05-B 1 8.17E+02
Si CFS-L01-1315-T06-B 1 1.26E+03
Si CFS-L01-1315-T07-B 1 1.22E+03
Si CFS-L01-1315-T08-B 1 7.56E+02
Si CFS-L01-1315-T09-B 1 1.24E+03
Si CFS-L01-1315-T01-C 1 6.31E+01
Si CFS-L01-1315-T02-C 1 2.19E+02
Si CFS-L01-1315-T03-C 1 2.33E+02
Si CFS-L01-1315-T04-C 1 6.95E+02
Si CFS-L01-1315-T05-C 1 8.41 E+02
Si CFS-L01-1315-T06-C 1 1.35E+03
Si CFS-L01-1315-T07-C 1 1.29E+03
Si CFS-L01-1315-T08-C 1 7.85E+02
Si CFS-L01-1315-T09-C 1 1.26E+03
Si CFS-L01-1315-M01-A 1 3.56E+00
Si CFS-L01-1315-M02-A 1 5.50E-01 U1/2
Si CFS-L01-1315-M03-A 1 5.50E-01 U1/2
Si CFS-L01-1315-M04-A 1 5.50E-01 U1/2
Si CFS-L01-1315-M05-A 1 5.50E-01 U1/2
Si CFS-L01-1315-M06-A 1 5.50E-01 U1/2
Si CFS-L01-1315-M07-A 1 5.50E-01 U1/2
Si CFS-L01-1315-M08-A 1 5.50E-01 U1/2
Si CFS-L01-1315-M09-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.37E+01 8.89 1.10 3.50
2.34E+02 2.00 1.10 3.50
2.04E+02 1.45 1.10 3.50 10000 1000
7.33E+02 6.07 1.10 3.50
8.12E+02 1.24 1.10 3.50
1.25E+03 1.80 1.10 3.50
1.26E+03 0.27 1.10 3.50
7.29E+02 2.05 1.10 3.50
1.22E+03 0.71 1.10 3.50
6.42E+01 5.52 1.10 3.50
2.50E+02 1.43 1.10 3.50
2.40E+02 3.33 1.10 3.50 10000 1000
6.67E+02 0.71 1.10 3.50
8.17E+02 1.09 1.10 3.50
1.26E+03 0.92 1.10 3.50
1.22E+03 1.49 1.10 3.50
7.56E+02 2.44 1.10 3.50
1.24E+03 2.29 1.10 3.50
6.31 E+01 4.52 1.10 3.50
2.19E+02 1.73 1.10 3.50
2.33E+02 1.62 1.10 3.50 10000 1000
6.95E+02 1.66 1.10 3.50
8.41 E+02 2.41 1.10 3.50
1.35E+03 0.99 1.10 3.50
1.29E+03 0.26 1.10 3.50
7.85E+02 0.84 1.10 3.50
1.26E+03 0.89 1.10 3.50
3.56E+00 8.06 1.10 3.50
5.50E-01 3.13 1.10 3.50
5.50E-01 1.43 1.10 3.50
5.50E-01 4.74 1.10 3.50
5.50E-01 8.39 1.10 3.50
5.50E-01 1.35 1.10 3.50
5.50E-01 7.29 1.10 3.50
5.50E-01 6.10 1.10 3.50
5.50E-01 1.92 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.10E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.20E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-779
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Na CFS-L01-1315-T01-A 1 9.34E+02
Na CFS-L01-1315-T02-A 1 5.52E+03
Na CFS-L01-1315-T03-A 1 4.54E+03
Na CFS-L01-1315-T04-A 1 1.89E+04
Na CFS-L01-1315-T05-A 1 2.04E+04
Na CFS-L01-1315-T06-A 1 2.79E+04
Na CFS-L01-1315-T07-A 1 2.02E+04
Na CFS-L01-1315-T08-A 1 8.50E+03
Na CFS-L01-1315-T09-A 1 1.17E+04
Na CFS-L01-1315-T01-B 1 1.03E+03
Na CFS-L01-1315-T02-B 1 5.16E+03
Na CFS-L01-1315-T03-B 1 4.72E+03
Na CFS-L01-1315-T04-B 1 1.83E+04
Na CFS-L01-1315-T05-B 1 2.08E+04
Na CFS-L01-1315-T06-B 1 2.91E+04
Na CFS-L01-1315-T07-B 1 2.02E+04
Na CFS-L01-1315-T08-B 1 8.37E+03
Na CFS-L01-1315-T09-B 1 1.16E+04
Na CFS-L01-1315-T01-C 1 9.24E+02
Na CFS-L01-1315-T02-C 1 4.66E+03
Na CFS-L01-1315-T03-C 1 5.12E+03
Na CFS-L01-1315-T04-C 1 1.93E+04
Na CFS-L01-1315-T05-C 1 2.17E+04
Na CFS-L01-1315-T06-C 1 2.93E+04
Na CFS-L01-1315-T07-C 1 2.04E+04
Na CFS-L01-1315-T08-C 1 8.40E+03
Na CFS-L01-1315-T09-C 1 1.13E+04
Na CFS-L01-1315-M01-A 1 2.73E+01
Na CFS-L01-1315-M02-A 1 1.69E+01
Na CFS-L01-1315-M03-A 1 1.33E+01
Na CFS-L01-1315-M04-A 1 1.62E+01
Na CFS-L01-1315-M05-A 1 1.37E+01
Na CFS-L01-1315-M06-A 1 3.08E+00 E
Na CFS-L01-1315-M07-A 1 4.11E+OOE
Na CFS-L01-1315-M08-A 1 2.80E+00 E
Na CFS-L01-1315-M09-A 1 1.58E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.34E+02 0.56 2.50 8.00
5.52E+03 0.29 2.50 8.00
4.54E+03 0.21 2.50 8.00 10000 1000
1.89E+04 2.24 2.50 8.00
2.04E+04 0.75 2.50 8.00
2.79E+04 0.66 2.50 8.00
2.02E+04 0.44 2.50 8.00
8.50E+03 0.51 2.50 8.00
1.17E+04 0.73 2.50 8.00
1.03E+03 1.29 2.50 8.00
5.16E+03 0.80 2.50 8.00
4.72E+03 0.63 2.50 8.00 10000 1000
1.83E+04 0.93 2.50 8.00
2.08E+04 0.29 2.50 8.00
2.91E+04 0.50 2.50 8.00
2.02E+04 1.03 2.50 8.00
8.37E+03 0.71 2.50 8.00
1.16E+04 0.26 2.50 8.00
9.24E+02 1.22 2.50 8.00
4.66E+03 0.24 2.50 8.00
5.12E+03 0.29 2.50 8.00 10000 1000
1.93E+04 0.29 2.50 8.00
2.17E+04 0.45 2.50 8.00
2.93E+04 1.02 2.50 8.00
2.04E+04 0.70 2.50 8.00
8.40E+03 0.13 2.50 8.00
1.13E+04 0.41 2.50 8.00
2.73E+01 5.13 2.50 8.00
1.69E+01 2.99 2.50 8.00
1.33E+01 2.46 2.50 8.00
1.62E+01 1.54 2.50 8.00
1.37E+01 3.86 2.50 8.00
3.08E+00 2.87 2.50 8.00
4.11E+00 4.01 2.50 8.00
2.80E+00 2.35 2.50 8.00
1.58E+01 4.11 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.42E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.62E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.08E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315CFS
8/10/11 1:24 PM EPA Interlab L01 1315CFS
8/10/11 1:26 PM EPA Interlab L01 1315CFS
8/10/11 1:27 PM EPA Interlab L01 1315CFS
8/10/11 1:29 PM EPA Interlab L01 1315CFS
8/10/11 1:30 PM EPA Interlab L01 1315CFS
8/10/11 1:32 PM EPA Interlab L01 1315CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-780
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Sr CFS-L01-1315-T01-A 1 4.18E+01
Sr CFS-L01-1315-T02-A 1 1.31E+02
Sr CFS-L01-1315-T03-A 1 1.00E+02
Sr CFS-L01-1315-T04-A 1 3.56E+02
Sr CFS-L01-1315-T05-A 1 3.97E+02
Sr CFS-L01-1315-T06-A 1 6.35E+02
Sr CFS-L01-1315-T07-A 1 6.26E+02
Sr CFS-L01-1315-T08-A 1 3.47E+02
Sr CFS-L01-1315-T09-A 1 5.77E+02
Sr CFS-L01-1315-T01-B 1 4.48E+01
Sr CFS-L01-1315-T02-B 1 1.49E+02
Sr CFS-L01-1315-T03-B 1 1.23E+02
Sr CFS-L01-1315-T04-B 1 3.35E+02
Sr CFS-L01-1315-T05-B 1 4.32E+02
Sr CFS-L01-1315-T06-B 1 6.96E+02
Sr CFS-L01-1315-T07-B 1 6.69E+02
Sr CFS-L01-1315-T08-B 1 3.82E+02
Sr CFS-L01-1315-T09-B 1 6.62E+02
Sr CFS-L01-1315-T01-C 1 4.60E+01
Sr CFS-L01-1315-T02-C 1 1.23E+02
Sr CFS-L01-1315-T03-C 1 1.28E+02
Sr CFS-L01-1315-T04-C 1 3.71E+02
Sr CFS-L01-1315-T05-C 1 4.43E+02
Sr CFS-L01-1315-T06-C 1 7.01E+02
Sr CFS-L01-1315-T07-C 1 6.71E+02
Sr CFS-L01-1315-T08-C 1 3.79E+02
Sr CFS-L01-1315-T09-C 1 6.21E+02
Sr CFS-L01-1315-M01-A 1 5.00E-01 U1/2
Sr CFS-L01-1315-M02-A 1 5.00E-01 U1/2
Sr CFS-L01-1315-M03-A 1 5.00E-01 U1/2
Sr CFS-L01-1315-M04-A 1 5.00E-01 U1/2
Sr CFS-L01-1315-M05-A 1 5.00E-01 U1/2
Sr CFS-L01-1315-M06-A 1 5.00E-01 U1/2
Sr CFS-L01-1315-M07-A 1 5.00E-01 U1/2
Sr CFS-L01-1315-M08-A 1 5.00E-01 U1/2
Sr CFS-L01-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.18E+01 3.38 1.00 3.18
1.31E+02 0.86 1.00 3.18
1.00E+02 0.54 1.00 3.18 10000 1000
3.56E+02 6.24 1.00 3.18
3.97E+02 1.48 1.00 3.18
6.35E+02 2.20 1.00 3.18
6.26E+02 0.58 1.00 3.18
3.47E+02 0.79 1.00 3.18
5.77E+02 0.62 1.00 3.18
4.48E+01 4.34 1.00 3.18
1.49E+02 1.13 1.00 3.18
1.23E+02 1.85 1.00 3.18 10000 1000
3.35E+02 0.72 1.00 3.18
4.32E+02 0.67 1.00 3.18
6.96E+02 0.65 1.00 3.18
6.69E+02 3.30 1.00 3.18
3.82E+02 2.05 1.00 3.18
6.62E+02 4.03 1.00 3.18
4.60E+01 3.00 1.00 3.18
1.23E+02 1.11 1.00 3.18
1.28E+02 2.39 1.00 3.18 10000 1000
3.71E+02 1.21 1.00 3.18
4.43E+02 2.20 1.00 3.18
7.01E+02 1.47 1.00 3.18
6.71E+02 1.28 1.00 3.18
3.79E+02 0.50 1.00 3.18
6.21E+02 1.23 1.00 3.18
5.00E-01 19.63 1.00 3.18
5.00E-01 30.88 1.00 3.18
5.00E-01 12.02 1.00 3.18
5.00E-01 22.91 1.00 3.18
5.00E-01 15.74 1.00 3.18
5.00E-01 5.48 1.00 3.18
5.00E-01 22.08 1.00 3.18
5.00E-01 22.81 1.00 3.18
5.00E-01 15.45 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 . 1 4E+03 1 04% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.21E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-781
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
S CFS-L01-1315-T01-A 1 1.90E+04
S CFS-L01-1315-T02-A 1 4.45E+04
S CFS-L01-1315-T03-A 1 3.13E+04
S CFS-L01-1315-T04-A 1 1.14E+05
S CFS-L01-1315-T05-A 1 1.29E+05
S CFS-L01-1315-T06-A 1 2.01 E+05
S CFS-L01-1315-T07-A 1 1.87E+05
S CFS-L01-1315-T08-A 1 9.81 E+04
S CFS-L01-1315-T09-A 1 1.60E+05
S CFS-L01-1315-T01-B 1 1.77E+04
S CFS-L01-1315-T02-B 1 4.75E+04
S CFS-L01-1315-T03-B 1 3.87E+04
S CFS-L01-1315-T04-B 1 1.07E+05
S CFS-L01-1315-T05-B 1 1.37E+05
S CFS-L01-1315-T06-B 1 2.12E+05
S CFS-L01-1315-T07-B 1 1.92E+05
S CFS-L01-1315-T08-B 1 1.03E+05
S CFS-L01-1315-T09-B 1 1.72E+05
S CFS-L01-1315-T01-C 1 1.83E+04
S CFS-L01-1315-T02-C 1 3.71E+04
S CFS-L01-1315-T03-C 1 3.95E+04
S CFS-L01-1315-T04-C 1 1.13E+05
S CFS-L01-1315-T05-C 1 1.41 E+05
S CFS-L01-1315-T06-C 1 2.21E+05
S CFS-L01-1315-T07-C 1 1.97E+05
S CFS-L01-1315-T08-C 1 1.07E+05
S CFS-L01-1315-T09-C 1 1.69E+05
S CFS-L01-1315-M01-A 1 1.06E+01 E
S CFS-L01-1315-M02-A 1 1.16E+01 E
S CFS-L01-1315-M03-A 1 1.61E+01 E
S CFS-L01-1315-M04-A 1 1.78E+01 E
S CFS-L01-1315-M05-A 1 1.59E+01 E
S CFS-L01-1315-M06-A 1 1.62E+01 E
S CFS-L01-1315-M07-A 1 1.70E+01 E
S CFS-L01-1315-M08-A 1 1.83E+01 E
S CFS-L01-1315-M09-A 1 1.07E+01 E
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.90E+04 0.66 6.80 21.60
4.45E+04 0.93 6.80 21.60
3.13E+04 1.18 6.80 21.60 10000 1000
1.14E+05 6.15 6.80 21.60
1.29E+05 1.27 6.80 21.60
2.01 E+05 2.00 6.80 21.60
1.87E+05 0.58 6.80 21.60
9.81 E+04 0.81 6.80 21.60
1.60E+05 0.89 6.80 21.60
1.77E+04 3.66 6.80 21.60
4.75E+04 1.41 6.80 21.60
3.87E+04 1.69 6.80 21.60 10000 1000
1.07E+05 0.72 6.80 21.60
1.37E+05 1.04 6.80 21.60
2.12E+05 0.61 6.80 21.60
1.92E+05 1.81 6.80 21.60
1.03E+05 1.75 6.80 21.60
1.72E+05 2.53 6.80 21.60
1.83E+04 2.11 6.80 21.60
3.71E+04 1.19 6.80 21.60
3.95E+04 1.88 6.80 21.60 10000 1000
1.13E+05 1.70 6.80 21.60
1.41 E+05 2.41 6.80 21.60
2. 21 E+05 0.78 6.80 21.60
1.97E+05 0.31 6.80 21.60
1.07E+05 0.54 6.80 21.60
1.69E+05 1.60 6.80 21.60
1.06E+01 6.67 6.80 21.60
1.16E+01 2.19 6.80 21.60
1.61E+01 1.17 6.80 21.60
1.78E+01 6.97 6.80 21.60
1.59E+01 4.31 6.80 21.60
1.62E+01 3.07 6.80 21.60
1.70E+01 6.05 6.80 21.60
1.83E+01 9.45 6.80 21.60
1.07E+01 1.58 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.22E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.96E+04 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.04E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-782
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Tl CFS-L01-1315-T01-A 1 9.55E+00 E
Tl CFS-L01-1315-T02-A 1 4.70E+01
Tl CFS-L01-1315-T03-A 1 3.88E+01
Tl CFS-L01-1315-T04-A 1 1.63E+02
Tl CFS-L01-1315-T05-A 1 1.76E+02
Tl CFS-L01-1315-T06-A 1 2.51 E+02
Tl CFS-L01-1315-T07-A 1 2.18E+02
Tl CFS-L01-1315-T08-A 1 1.17E+02
Tl CFS-L01-1315-T09-A 1 1.82E+02
Tl CFS-L01-1315-T01-B 1 1.37E+01 E
Tl CFS-L01-1315-T02-B 1 4.82E+01
Tl CFS-L01-1315-T03-B 1 4.77E+01
Tl CFS-L01-1315-T04-B 1 1.49E+02
Tl CFS-L01-1315-T05-B 1 1.80E+02
Tl CFS-L01-1315-T06-B 1 2.53E+02
Tl CFS-L01-1315-T07-B 1 2.19E+02
Tl CFS-L01-1315-T08-B 1 1.16E+02
Tl CFS-L01-1315-T09-B 1 1.78E+02
Tl CFS-L01-1315-T01-C 1 6.76E+00 E
Tl CFS-L01-1315-T02-C 1 4.13E+01
Tl CFS-L01-1315-T03-C 1 4.93E+01
Tl CFS-L01-1315-T04-C 1 1.60E+02
Tl CFS-L01-1315-T05-C 1 1.88E+02
Tl CFS-L01-1315-T06-C 1 2.67E+02
Tl CFS-L01-1315-T07-C 1 2.30E+02
Tl CFS-L01-1315-T08-C 1 1.27E+02
Tl CFS-L01-1315-T09-C 1 1.88E+02
Tl CFS-L01-1315-M01-A 1 2.30E+00 U1/2
Tl CFS-L01-1315-M02-A 1 2.30E+00 U1/2
Tl CFS-L01-1315-M03-A 1 2.30E+00 U1/2
Tl CFS-L01-1315-M04-A 1 2.30E+00 U1/2
Tl CFS-L01-1315-M05-A 1 2.30E+00 U1/2
Tl CFS-L01-1315-M06-A 1 2.30E+00 U1/2
Tl CFS-L01-1315-M07-A 1 2.30E+00 U1/2
Tl CFS-L01-1315-M08-A 1 2.30E+00 U1/2
Tl CFS-L01-1315-M09-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.55E+00 26.01 4.60 14.60
4.70E+01 5.13 4.60 14.60
3.88E+01 3.21 4.60 14.60 10000 1000
1.63E+02 5.81 4.60 14.60
1.76E+02 3.73 4.60 14.60
2.51E+02 3.62 4.60 14.60
2.18E+02 2.34 4.60 14.60
1.17E+02 4.47 4.60 14.60
1.82E+02 2.35 4.60 14.60
1.37E+01 9.51 4.60 14.60
4.82E+01 4.82 4.60 14.60
4.77E+01 2.19 4.60 14.60 10000 1000
1.49E+02 1.35 4.60 14.60
1.80E+02 3.06 4.60 14.60
2.53E+02 1.49 4.60 14.60
2.19E+02 2.18 4.60 14.60
1.16E+02 2.47 4.60 14.60
1.78E+02 3.31 4.60 14.60
6.76E+00 15.58 4.60 14.60
4.13E+01 7.20 4.60 14.60
4.93E+01 7.25 4.60 14.60 10000 1000
1.60E+02 4.23 4.60 14.60
1.88E+02 2.06 4.60 14.60
2.67E+02 2.67 4.60 14.60
2.30E+02 0.58 4.60 14.60
1.27E+02 1.18 4.60 14.60
1.88E+02 1.13 4.60 14.60
2.30E+00 24.97 4.60 14.60
2.30E+00 34.28 4.60 14.60
2.30E+00 44.01 4.60 14.60
2.30E+00 11.17 4.60 14.60
2.30E+00 34.36 4.60 14.60
2.30E+00 21.03 4.60 14.60
2.30E+00 1.37 4.60 14.60
2.30E+00 37.01 4.60 14.60
2.30E+00 27.87 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.34E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.93E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.52E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-783
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ti CFS-L01-1315-T01-A 1 1.00E+00 U1/2
Ti CFS-L01-1315-T02-A 1 1.00E+00 U1/2
Ti CFS-L01-1315-T03-A 1 1.00E+00 U1/2
Ti CFS-L01-1315-T04-A 1 1.00E+00 U1/2
Ti CFS-L01-1315-T05-A 1 1.00E+00 U1/2
Ti CFS-L01-1315-T06-A 1 1.00E+00 U1/2
Ti CFS-L01-1315-T07-A 1 1.00E+00 U1/2
Ti CFS-L01-1315-T08-A 1 1.00E+00 U1/2
Ti CFS-L01-1315-T09-A 1 1.00E+00 U1/2
Ti CFS-L01-1315-T01-B 1 1.00E+00 U1/2
Ti CFS-L01-1315-T02-B 1 1.00E+00 U1/2
Ti CFS-L01-1315-T03-B 1 1.00E+00 U1/2
Ti CFS-L01-1315-T04-B 1 1.00E+00 U1/2
Ti CFS-L01-1315-T05-B 1 1.00E+00 U1/2
Ti CFS-L01-1315-T06-B 1 1.00E+00 U1/2
Ti CFS-L01-1315-T07-B 1 1.00E+00 U1/2
Ti CFS-L01-1315-T08-B 1 1.00E+00 U1/2
Ti CFS-L01-1315-T09-B 1 1.00E+00 U1/2
Ti CFS-L01-1315-T01-C 1 1.00E+00 U1/2
Ti CFS-L01-1315-T02-C 1 1.00E+00 U1/2
Ti CFS-L01-1315-T03-C 1 1.00E+00 U1/2
Ti CFS-L01-1315-T04-C 1 1.00E+00 U1/2
Ti CFS-L01-1315-T05-C 1 1.00E+00 U1/2
Ti CFS-L01-1315-T06-C 1 1.00E+00 U1/2
Ti CFS-L01-1315-T07-C 1 1.00E+00 U1/2
Ti CFS-L01-1315-T08-C 1 1.00E+00 U1/2
Ti CFS-L01-1315-T09-C 1 1.00E+00 U1/2
Ti CFS-L01-1315-M01-A 1 1.00E+00 U1/2
Ti CFS-L01-1315-M02-A 1 1.00E+00 U1/2
Ti CFS-L01-1315-M03-A 1 1.00E+00 U1/2
Ti CFS-L01-1315-M04-A 1 1.00E+00 U1/2
Ti CFS-L01-1315-M05-A 1 1.00E+00 U1/2
Ti CFS-L01-1315-M06-A 1 1.00E+00 U1/2
Ti CFS-L01-1315-M07-A 1 1.00E+00 U1/2
Ti CFS-L01-1315-M08-A 1 1.00E+00 U1/2
Ti CFS-L01-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 42.22 2.00 6.40
1.00E+00 18.20 2.00 6.40
1.00E+00 67.25 2.00 6.40 10000 1000
1.00E+00 3.72 2.00 6.40
1.00E+00 20.24 2.00 6.40
1.00E+00 10.93 2.00 6.40
1.00E+00 5.12 2.00 6.40
1.00E+00 56.62 2.00 6.40
1.00E+00 3.33 2.00 6.40
1.00E+00 25.90 2.00 6.40
1.00E+00 24.93 2.00 6.40
1.00E+00 31.91 2.00 6.40 10000 1000
1.00E+00 14.56 2.00 6.40
1.00E+00 45.41 2.00 6.40
1.00E+00 6.37 2.00 6.40
1.00E+00 5.17 2.00 6.40
1.00E+00 9.63 2.00 6.40
1.00E+00 17.32 2.00 6.40
1.00E+00 24.89 2.00 6.40
1.00E+00 55.89 2.00 6.40
1.00E+00 24.80 2.00 6.40 10000 1000
1.00E+00 0.69 2.00 6.40
1.00E+00 44.42 2.00 6.40
1.00E+00 12.70 2.00 6.40
1.00E+00 30.25 2.00 6.40
1.00E+00 13.51 2.00 6.40
1.00E+00 32.24 2.00 6.40
1.00E+00 2.43 2.00 6.40
1.00E+00 20.31 2.00 6.40
1.00E+00 0.23 2.00 6.40
1.00E+00 9.42 2.00 6.40
1.00E+00 5.81 2.00 6.40
1.00E+00 39.85 2.00 6.40
1.00E+00 42.23 2.00 6.40
1.00E+00 2.18 2.00 6.40
1.00E+00 15.30 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.54E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.80E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.06E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-784
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
V CFS-L01-1315-T01-A 1 2.02E+00 E
V CFS-L01-1315-T02-A 1 3.53E+00 E
V CFS-L01-1315-T03-A 1 2.91E+00 E
V CFS-L01-1315-T04-A 1 4.67E+00 E
V CFS-L01-1315-T05-A 1 4.86E+00
V CFS-L01-1315-T06-A 1 6.48E+00
V CFS-L01-1315-T07-A 1 6.87E+00
V CFS-L01-1315-T08-A 1 4.48E+00 E
V CFS-L01-1315-T09-A 1 6.76E+00
V CFS-L01-1315-T01-B 1 2.61E+00 E
V CFS-L01-1315-T02-B 1 3.62E+00 E
V CFS-L01-1315-T03-B 1 3.21E+00 E
V CFS-L01-1315-T04-B 1 5.39E+00
V CFS-L01-1315-T05-B 1 6.24E+00
V CFS-L01-1315-T06-B 1 7.65E+00
V CFS-L01-1315-T07-B 1 7.02E+00
V CFS-L01-1315-T08-B 1 5.62E+00
V CFS-L01-1315-T09-B 1 7.58E+00
V CFS-L01-1315-T01-C 1 2.09E+00 E
V CFS-L01-1315-T02-C 1 2.73E+00 E
V CFS-L01-1315-T03-C 1 3.26E+00 E
V CFS-L01-1315-T04-C 1 5.22E+00
V CFS-L01-1315-T05-C 1 6.19E+00
V CFS-L01-1315-T06-C 1 8.18E+00
V CFS-L01-1315-T07-C 1 7.43E+00
V CFS-L01-1315-T08-C 1 4.53E+00 E
V CFS-L01-1315-T09-C 1 6.43E+00
V CFS-L01-1315-M01-A 1 7.50E-01 U1/2
V CFS-L01-1315-M02-A 1 7.50E-01 U1/2
V CFS-L01-1315-M03-A 1 7.50E-01 U1/2
V CFS-L01-1315-M04-A 1 7.50E-01 U1/2
V CFS-L01-1315-M05-A 1 7.50E-01 U1/2
V CFS-L01-1315-M06-A 1 7.50E-01 U1/2
V CFS-L01-1315-M07-A 1 7.50E-01 U1/2
V CFS-L01-1315-M08-A 1 7.50E-01 U1/2
V CFS-L01-1315-M09-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.02E+00 15.98 1.50 4.77
3.53E+00 9.59 1.50 4.77
2.91E+00 8.76 1.50 4.77 10000 1000
4.67E+00 10.93 1.50 4.77
4.86E+00 15.95 1.50 4.77
6.48E+00 4.65 1.50 4.77
6.87E+00 1.02 1.50 4.77
4.48E+00 17.38 1.50 4.77
6.76E+00 5.55 1.50 4.77
2.61 E+00 23.78 1.50 4.77
3.62E+00 16.11 1.50 4.77
3.21 E+00 9.30 1.50 4.77 10000 1000
5.39E+00 3.68 1.50 4.77
6.24E+00 1.78 1.50 4.77
7.65E+00 1.15 1.50 4.77
7.02E+00 3.09 1.50 4.77
5.62E+00 6.42 1.50 4.77
7.58E+00 8.92 1.50 4.77
2.09E+00 15.48 1.50 4.77
2.73E+00 24.02 1.50 4.77
3.26E+00 8.04 1.50 4.77 10000 1000
5.22E+00 6.63 1.50 4.77
6.19E+00 5.21 1.50 4.77
8.18E+00 4.31 1.50 4.77
7.43E+00 4.86 1.50 4.77
4.53E+00 15.29 1.50 4.77
6.43E+00 1.19 1.50 4.77
7.50E-01 21.60 1.50 4.77
7.50E-01 37.47 1.50 4.77
7.50E-01 7.41 1.50 4.77
7.50E-01 48.66 1.50 4.77
7.50E-01 28.37 1.50 4.77
7.50E-01 30.77 1.50 4.77
7.50E-01 12.84 1.50 4.77
7.50E-01 27.11 1.50 4.77
7.50E-01 35.59 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.74E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.15E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.32E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-785
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Zn CFS-L01-1315-T01-A 1 2.88E+02
Zn CFS-L01-1315-T02-A 1 1.53E+03
Zn CFS-L01-1315-T03-A 1 1.26E+03
Zn CFS-L01-1315-T04-A 1 4.18E+03
Zn CFS-L01-1315-T05-A 1 4.70E+03
Zn CFS-L01-1315-T06-A 1 7.04E+03
Zn CFS-L01-1315-T07-A 1 6.47E+03
Zn CFS-L01-1315-T08-A 1 3.52E+03
Zn CFS-L01-1315-T09-A 1 5.63E+03
Zn CFS-L01-1315-T01-B 1 5.19E+02
Zn CFS-L01-1315-T02-B 1 1.63E+03
Zn CFS-L01-1315-T03-B 1 1.46E+03
Zn CFS-L01-1315-T04-B 1 4.00E+03
Zn CFS-L01-1315-T05-B 1 4.84E+03
Zn CFS-L01-1315-T06-B 1 6.97E+03
Zn CFS-L01-1315-T07-B 1 6.32E+03
Zn CFS-L01-1315-T08-B 1 3.47E+03
Zn CFS-L01-1315-T09-B 1 5.70E+03
Zn CFS-L01-1315-T01-C 1 5.06E+02
Zn CFS-L01-1315-T02-C 1 1.35E+03
Zn CFS-L01-1315-T03-C 1 1.47E+03
Zn CFS-L01-1315-T04-C 1 4.24E+03
Zn CFS-L01-1315-T05-C 1 5.02E+03
Zn CFS-L01-1315-T06-C 1 7.83E+03
Zn CFS-L01-1315-T07-C 1 7.03E+03
Zn CFS-L01-1315-T08-C 1 3.85E+03
Zn CFS-L01-1315-T09-C 1 6.09E+03
Zn CFS-L01-1315-M01-A 1 5.00E-01 U1/2
Zn CFS-L01-1315-M02-A 1 5.00E-01 U1/2
Zn CFS-L01-1315-M03-A 1 5.00E-01 U1/2
Zn CFS-L01-1315-M04-A 1 5.00E-01 U1/2
Zn CFS-L01-1315-M05-A 1 5.00E-01 U1/2
Zn CFS-L01-1315-M06-A 1 5.00E-01 U1/2
Zn CFS-L01-1315-M07-A 1 5.00E-01 U1/2
Zn CFS-L01-1315-M08-A 1 5.00E-01 U1/2
Zn CFS-L01-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.88E+02 0.71 1.00 3.18
1.53E+03 1.68 1.00 3.18
1.26E+03 1.56 1.00 3.18 10000 1000
4.18E+03 4.88 1.00 3.18
4.70E+03 1.45 1.00 3.18
7.04E+03 3.01 1.00 3.18
6.47E+03 1.83 1.00 3.18
3.52E+03 0.91 1.00 3.18
5.63E+03 1.21 1.00 3.18
5.19E+02 2.88 1.00 3.18
1.63E+03 1.25 1.00 3.18
1.46E+03 1.61 1.00 3.18 10000 1000
4.00E+03 2.53 1.00 3.18
4.84E+03 0.58 1.00 3.18
6.97E+03 2.70 1.00 3.18
6.32E+03 0.68 1.00 3.18
3.47E+03 2.62 1.00 3.18
5.70E+03 6.02 1.00 3.18
5.06E+02 1.32 1.00 3.18
1.35E+03 0.41 1.00 3.18
1.47E+03 0.42 1.00 3.18 10000 1000
4.24E+03 2.74 1.00 3.18
5.02E+03 1.34 1.00 3.18
7.83E+03 1.99 1.00 3.18
7.03E+03 0.88 1.00 3.18
3.85E+03 1.72 1.00 3.18
6.09E+03 2.49 1.00 3.18
5.00E-01 1.05 1.00 3.18
5.00E-01 2.74 1.00 3.18
5.00E-01 2.84 1.00 3.18
5.00E-01 2.68 1.00 3.18
5.00E-01 2.58 1.00 3.18
5.00E-01 2.68 1.00 3.18
5.00E-01 5.06 1.00 3.18
5.00E-01 10.48 1.00 3.18
5.00E-01 3.26 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.13E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.37E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.40E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/10/11 1:35PMEPAInterlabl_01 1315 CFS
8/10/11 3:17 PM EPA Interlab L01 1315 CFS
8/10/11 1:45 PM EPA Interlab L01 1315 CFS
8/10/11 1:55 PM EPA Interlab L01 1315 CFS
8/10/11 2:00 PM EPA Interlab L01 1315 CFS
8/10/11 2:05 PM EPA Interlab L01 1315 CFS
8/10/11 2:10 PM EPA Interlab L01 1315 CFS
8/10/11 2:15 PM EPA Interlab L01 1315 CFS
8/10/11 2:20 PM EPA Interlab L01 1315 CFS
8/10/11 1:37 PM EPA Interlab L01 1315 CFS
8/10/11 1:42 PM EPA Interlab L01 1315 CFS
8/10/11 1:47 PM EPA Interlab L01 1315 CFS
8/10/11 1:57 PM EPA Interlab L01 1315 CFS
8/10/11 2:02 PM EPA Interlab L01 1315 CFS
8/10/11 2:07 PM EPA Interlab L01 1315 CFS
8/10/11 2:12 PM EPA Interlab L01 1315 CFS
8/10/11 2:17 PM EPA Interlab L01 1315 CFS
8/10/11 2:21 PM EPA Interlab L01 1315 CFS
8/10/11 1:39 PM EPA Interlab L01 1315 CFS
8/10/11 1:44 PM EPA Interlab L01 1315 CFS
8/10/11 1:49 PM EPA Interlab L01 1315 CFS
8/10/11 1:58 PM EPA Interlab L01 1315 CFS
8/10/11 2:03 PM EPA Interlab L01 1315 CFS
8/10/11 2:08 PM EPA Interlab L01 1315 CFS
8/10/11 2:13 PM EPA Interlab L01 1315 CFS
8/10/11 2:18 PM EPA Interlab L01 1315 CFS
8/10/11 2:23 PM EPA Interlab L01 1315 CFS
8/10/11 3:15 PM EPA Interlab L01 1315 CFS
8/10/11 1:22 PM EPA Interlab L01 1315 CFS
8/10/11 1:24 PM EPA Interlab L01 1315 CFS
8/10/11 1:26 PM EPA Interlab L01 1315 CFS
8/10/11 1:27 PM EPA Interlab L01 1315 CFS
8/10/11 1:29 PM EPA Interlab L01 1315 CFS
8/10/11 1:30 PM EPA Interlab L01 1315 CFS
8/10/11 1:32 PM EPA Interlab L01 1315 CFS
8/10/11 1:34 PM EPA Interlab L01 1315 CFS
1-786
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1315:
Element Sample ID
Al CFS-L04-1315-T01-A
Al CFS-L04-1315-T02-A
Al CFS-L04-1315-T03-A
Al CFS-L04-1315-T04-A
Al CFS-L04-1315-T05-A
Al CFS-L04-1315-T06-A
Al CFS-L04-1315-T07-A
Al CFS-L04-1315-T08-A
Al CFS-L04-1315-T09-A
Al CFS-L04-1315-T01-B
Al CFS-L04-1315-T02-B
Al CFS-L04-1315-T03-B
Al CFS-L04-1315-T04-B
Al CFS-L04-1315-T05-B
Al CFS-L04-1315-T06-B
Al CFS-L04-1315-T07-B
Al CFS-L04-1315-T08-B
Al CFS-L04-1315-T09-B
Al CFS-L04-1315-T01-C
Al CFS-L04-1315-T02-C
Al CFS-L04-1315-T03-C
Al CFS-L04-1315-T04-C
Al CFS-L04-1315-T05-C
Al CFS-L04-1315-T06-C
Al CFS-L04-1315-T07-C
Al CFS-L04-1315-T08-C
Al CFS-L04-1315-T09-C
Al CFS-L04-1315-M01-A
Al CFS-L04-1315-M02-A
Al CFS-L04-1315-M03-A
Al CFS-L04-1315-M04-A
Al CFS-L04-1315-M05-A
Al CFS-L04-1315-M06-A
Al CFS-L04-1315-M07-A
Al CFS-L04-1315-M08-A
Al CFS-L04-1315-M09-A
Dilution Sample
Factor Cone. Qualifier
I ug/L I
1 1.25E+01
1 2.54E+01
1 3.10E+01
1 3.76E+01
1 4.05E+01
1 4.81 E+01
1 3.52E+01
1 3.49E+01
1 4.01 E+01
1 9.84E+00
1 2.83E+01
1 3.03E+01
1 3.77E+01
1 4.26E+01
1 4.55E+01
1 3.74E+01
1 3.61 E+01
1 3.70E+01
1 1.27E+01
1 2.64E+01
1 3.38E+01
1 3.98E+01
1 4.65E+01
1 4.66E+01
1 3.69E+01
1 3.90E+01
1 3.70E+01
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.25E+01 5.92 1.00 3.18
2.54E+01 6.13 1.00 3.18
3.10E+01 2.54 1.00 3.18 10000 1000
3.76E+01 3.07 1.00 3.18
4.05E+01 4.81 1.00 3.18
4.81E+01 7.44 1.00 3.18
3.52E+01 4.07 1.00 3.18
3.49E+01 3.49 1.00 3.18
4.01E+01 7.10 1.00 3.18
9.84E+00 1.53 1.00 3.18
2.83E+01 0.30 1.00 3.18
3.03E+01 6.49 1.00 3.18 10000 1000
3.77E+01 13.80 1.00 3.18
4.26E+01 7.00 1.00 3.18
4.55E+01 6.84 1.00 3.18
3.74E+01 4.45 1.00 3.18
3.61E+01 4.92 1.00 3.18
3.70E+01 3.46 1.00 3.18
1.27E+01 4.81 1.00 3.18
2.64E+01 1.73 1.00 3.18
3.38E+01 1.36 1.00 3.18 10000 1000
3.98E+01 4.62 1.00 3.18
4.65E+01 1.96 1.00 3.18
4.66E+01 0.67 1.00 3.18
3.69E+01 1.43 1.00 3.18
3.90E+01 3.64 1.00 3.18
3.70E+01 8.47 1.00 3.18
5.00E-01 28.38 1.00 3.18
5.00E-01 31.61 1.00 3.18
5.00E-01 16.23 1.00 3.18
5.00E-01 28.54 1.00 3.18
5.00E-01 11.72 1.00 3.18
5.00E-01 24.99 1.00 3.18
5.00E-01 14.39 1.00 3.18
5.00E-01 37.13 1.00 3.18
5.00E-01 23.36 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.94E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-787
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Sb CFS-L04-1315-T01-A 1 9.37E+00 E
Sb CFS-L04-1315-T02-A 1 9.58E+00 E
Sb CFS-L04-1315-T03-A 1 1.03E+01 E
Sb CFS-L04-1315-T04-A 1 9.92E+00 E
Sb CFS-L04-1315-T05-A 1 1.09E+01 E
Sb CFS-L04-1315-T06-A 1 1.14E+01 E
Sb CFS-L04-1315-T07-A 1 1.12E+01 E
Sb CFS-L04-1315-T08-A 1 8.39E+00 E
Sb CFS-L04-1315-T09-A 1 8.42E+00 E
Sb CFS-L04-1315-T01-B 1 9.03E+00 E
Sb CFS-L04-1315-T02-B 1 9.65E+00 E
Sb CFS-L04-1315-T03-B 1 1.14E+01 E
Sb CFS-L04-1315-T04-B 1 8.97E+00 E
Sb CFS-L04-1315-T05-B 1 1.04E+01 E
Sb CFS-L04-1315-T06-B 1 1.24E+01 E
Sb CFS-L04-1315-T07-B 1 1.19E+01 E
Sb CFS-L04-1315-T08-B 1 8.37E+00 E
Sb CFS-L04-1315-T09-B 1 9.17E+00 E
Sb CFS-L04-1315-T01-C 1 8.99E+00 E
Sb CFS-L04-1315-T02-C 1 9.49E+00 E
Sb CFS-L04-1315-T03-C 1 1.04E+01 E
Sb CFS-L04-1315-T04-C 1 8.23E+00 E
Sb CFS-L04-1315-T05-C 1 1.10E+01 E
Sb CFS-L04-1315-T06-C 1 1.46E+01 E
Sb CFS-L04-1315-T07-C 1 1.15E+01 E
Sb CFS-L04-1315-T08-C 1 8.05E+00 E
Sb CFS-L04-1315-T09-C 1 8.56E+00 E
Sb CFS-L04-1315-M01-A 1 3.75E+00 U1/2
Sb CFS-L04-1315-M02-A 1 3.75E+00 U1/2
Sb CFS-L04-1315-M03-A 1 3.75E+00 U1/2
Sb CFS-L04-1315-M04-A 1 3.75E+00 U1/2
Sb CFS-L04-1315-M05-A 1 3.75E+00 U1/2
Sb CFS-L04-1315-M06-A 1 3.75E+00 U1/2
Sb CFS-L04-1315-M07-A 1 3.75E+00 U1/2
Sb CFS-L04-1315-M08-A 1 3.75E+00 U1/2
Sb CFS-L04-1315-M09-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.37E+00 7.38 7.50 23.90
9.58E+00 12.12 7.50 23.90
1.03E+01 2.00 7.50 23.90 10000 1000
9.92E+00 11.40 7.50 23.90
1.09E+01 29.31 7.50 23.90
1.14E+01 9.48 7.50 23.90
1.12E+01 19.99 7.50 23.90
8.39E+00 27.91 7.50 23.90
8.42E+00 22.58 7.50 23.90
9.03E+00 9.42 7.50 23.90
9.65E+00 6.14 7.50 23.90
1.14E+01 18.60 7.50 23.90 10000 1000
8.97E+00 9.54 7.50 23.90
1.04E+01 16.63 7.50 23.90
1.24E+01 25.49 7.50 23.90
1.19E+01 5.51 7.50 23.90
8.37E+00 3.91 7.50 23.90
9.17E+00 22.55 7.50 23.90
8.99E+00 4.10 7.50 23.90
9.49E+00 1.91 7.50 23.90
1.04E+01 13.90 7.50 23.90 10000 1000
8.23E+00 12.71 7.50 23.90
1.10E+01 3.52 7.50 23.90
1.46E+01 9.26 7.50 23.90
1.15E+01 9.11 7.50 23.90
8.05E+00 6.41 7.50 23.90
8.56E+00 18.35 7.50 23.90
3.75E+00 38.35 7.50 23.90
3.75E+00 20.18 7.50 23.90
3.75E+00 31.20 7.50 23.90
3.75E+00 41.00 7.50 23.90
3.75E+00 39.54 7.50 23.90
3.75E+00 11.30 7.50 23.90
3.75E+00 11.79 7.50 23.90
3.75E+00 22.81 7.50 23.90
3.75E+00 12.63 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-788
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
As CFS-L04-1315-T01-A 1 5.50E+00 U1/2
As CFS-L04-1315-T02-A 1 5.50E+00 U1/2
As CFS-L04-1315-T03-A 1 1.30E+01 E
As CFS-L04-1315-T04-A 1 1.33E+01 E
As CFS-L04-1315-T05-A 1 1.58E+01 E
As CFS-L04-1315-T06-A 1 1.61E+01 E
As CFS-L04-1315-T07-A 1 1.17E+01 E
As CFS-L04-1315-T08-A 1 5.50E+00 U1/2
As CFS-L04-1315-T09-A 1 5.50E+00 U1/2
As CFS-L04-1315-T01-B 1 5.50E+00 U1/2
As CFS-L04-1315-T02-B 1 1.14E+01 E
As CFS-L04-1315-T03-B 1 1.69E+01 E
As CFS-L04-1315-T04-B 1 1.60E+01 E
As CFS-L04-1315-T05-B 1 1.20E+01 E
As CFS-L04-1315-T06-B 1 1.59E+01 E
As CFS-L04-1315-T07-B 1 1.23E+01 E
As CFS-L04-1315-T08-B 1 5.50E+00 U1/2
As CFS-L04-1315-T09-B 1 5.50E+00 U1/2
As CFS-L04-1315-T01-C 1 5.50E+00 U1/2
As CFS-L04-1315-T02-C 1 5.50E+00 U1/2
As CFS-L04-1315-T03-C 1 1.49E+01 E
As CFS-L04-1315-T04-C 1 1.49E+01 E
As CFS-L04-1315-T05-C 1 1.43E+01 E
As CFS-L04-1315-T06-C 1 1.95E+01 E
As CFS-L04-1315-T07-C 1 1.47E+01 E
As CFS-L04-1315-T08-C 1 5.50E+00 U1/2
As CFS-L04-1315-T09-C 1 5.50E+00 U1/2
As CFS-L04-1315-M01-A 1 5.50E+00 U1/2
As CFS-L04-1315-M02-A 1 5.50E+00 U1/2
As CFS-L04-1315-M03-A 1 5.50E+00 U1/2
As CFS-L04-1315-M04-A 1 5.50E+00 U1/2
As CFS-L04-1315-M05-A 1 5.50E+00 U1/2
As CFS-L04-1315-M06-A 1 5.50E+00 U1/2
As CFS-L04-1315-M07-A 1 5.50E+00 U1/2
As CFS-L04-1315-M08-A 1 5.50E+00 U1/2
As CFS-L04-1315-M09-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.50E+00 31.60 11.00 35.00
5.50E+00 39.88 11.00 35.00
1.30E+01 2.40 11.00 35.00 10000 1000
1.33E+01 10.95 11.00 35.00
1.58E+01 21.46 11.00 35.00
1.61E+01 15.03 11.00 35.00
1.17E+01 35.83 11.00 35.00
5.50E+00 25.32 11.00 35.00
5.50E+00 56.98 11.00 35.00
5.50E+00 46.04 11.00 35.00
1.14E+01 11.80 11.00 35.00
1.69E+01 38.46 11.00 35.00 10000 1000
1.60E+01 22.12 11.00 35.00
1.20E+01 10.12 11.00 35.00
1.59E+01 29.95 11.00 35.00
1.23E+01 21.01 11.00 35.00
5.50E+00 45.42 11.00 35.00
5.50E+00 39.08 11.00 35.00
5.50E+00 41.30 11.00 35.00
5.50E+00 21.47 11.00 35.00
1.49E+01 33.76 11.00 35.00 10000 1000
1.49E+01 27.71 11.00 35.00
1.43E+01 33.97 11.00 35.00
1.95E+01 19.15 11.00 35.00
1.47E+01 23.90 11.00 35.00
5.50E+00 41.84 11.00 35.00
5.50E+00 32.19 11.00 35.00
5.50E+00 6.31 11.00 35.00
5.50E+00 34.85 11.00 35.00
5.50E+00 22.51 11.00 35.00
5.50E+00 22.14 11.00 35.00
5.50E+00 44.28 11.00 35.00
5.50E+00 9.68 11.00 35.00
5.50E+00 29.99 11.00 35.00
5.50E+00 32.78 11.00 35.00
5.50E+00 15.02 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-789
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
B CFS-L04-1315-T01-A 1 1.78E+01
B CFS-L04-1315-T02-A 1 3.82E+01
B CFS-L04-1315-T03-A 1 3.88E+01
B CFS-L04-1315-T04-A 1 8.50E+01
B CFS-L04-1315-T05-A 1 1.09E+02
B CFS-L04-1315-T06-A 1 1.70E+02
B CFS-L04-1315-T07-A 1 1.39E+02
B CFS-L04-1315-T08-A 1 7.10E+01
B CFS-L04-1315-T09-A 1 1.44E+02
B CFS-L04-1315-T01-B 1 1.12E+01
B CFS-L04-1315-T02-B 1 3.86E+01
B CFS-L04-1315-T03-B 1 4.20E+01
B CFS-L04-1315-T04-B 1 8.62E+01
B CFS-L04-1315-T05-B 1 1.14E+02
B CFS-L04-1315-T06-B 1 1.71E+02
B CFS-L04-1315-T07-B 1 1.44E+02
B CFS-L04-1315-T08-B 1 6.84E+01
B CFS-L04-1315-T09-B 1 1.38E+02
B CFS-L04-1315-T01-C 1 1.25E+01
B CFS-L04-1315-T02-C 1 4.14E+01
B CFS-L04-1315-T03-C 1 4.14E+01
B CFS-L04-1315-T04-C 1 9.19E+01
B CFS-L04-1315-T05-C 1 1.11E+02
B CFS-L04-1315-T06-C 1 1.73E+02
B CFS-L04-1315-T07-C 1 1.43E+02
B CFS-L04-1315-T08-C 1 6.92E+01
B CFS-L04-1315-T09-C 1 1.54E+02
B CFS-L04-1315-M01-A 1 5.00E-01 U1/2
B CFS-L04-1315-M02-A 1 5.00E-01 U1/2
B CFS-L04-1315-M03-A 1 5.00E-01 U1/2
B CFS-L04-1315-M04-A 1 5.00E-01 U1/2
B CFS-L04-1315-M05-A 1 5.00E-01 U1/2
B CFS-L04-1315-M06-A 1 5.00E-01 U1/2
B CFS-L04-1315-M07-A 1 5.00E-01 U1/2
B CFS-L04-1315-M08-A 1 5.00E-01 U1/2
B CFS-L04-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.78E+01 3.17 1.00 3.18
3.82E+01 1.56 1.00 3.18
3.88E+01 0.89 1.00 3.18 10000 1000
8.50E+01 2.05 1.00 3.18
1.09E+02 1.27 1.00 3.18
1.70E+02 2.46 1.00 3.18
1.39E+02 1.79 1.00 3.18
7.10E+01 2.01 1.00 3.18
1.44E+02 2.52 1.00 3.18
1.12E+01 7.36 1.00 3.18
3.86E+01 0.84 1.00 3.18
4.20E+01 0.43 1.00 3.18 10000 1000
8.62E+01 5.65 1.00 3.18
1.14E+02 1.91 1.00 3.18
1.71E+02 1.02 1.00 3.18
1.44E+02 4.72 1.00 3.18
6.84E+01 1.70 1.00 3.18
1.38E+02 2.39 1.00 3.18
1.25E+01 1.48 1.00 3.18
4.14E+01 2.09 1.00 3.18
4.14E+01 4.68 1.00 3.18 10000 1000
9.19E+01 0.68 1.00 3.18
1.11E+02 1.15 1.00 3.18
1.73E+02 1.07 1.00 3.18
1.43E+02 2.70 1.00 3.18
6.92E+01 0.79 1.00 3.18
1.54E+02 2.57 1.00 3.18
5.00E-01 3.39 1.00 3.18
5.00E-01 3.87 1.00 3.18
5.00E-01 10.65 1.00 3.18
5.00E-01 4.39 1.00 3.18
5.00E-01 6.17 1.00 3.18
5.00E-01 7.67 1.00 3.18
5.00E-01 3.93 1.00 3.18
5.00E-01 9.66 1.00 3.18
5.00E-01 7.67 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+03 114% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+03 112% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-790
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Ba CFS-L04-1315-T01-A 1 2.61E+01
Ba CFS-L04-1315-T02-A 1 2.51 E+01
Ba CFS-L04-1315-T03-A 1 3.18E+01
Ba CFS-L04-1315-T04-A 1 2.60E+01
Ba CFS-L04-1315-T05-A 1 2.83E+01
Ba CFS-L04-1315-T06-A 1 3. 11 E+01
Ba CFS-L04-1315-T07-A 1 4.02E+01
Ba CFS-L04-1315-T08-A 1 3.60E+01
Ba CFS-L04-1315-T09-A 1 3.50E+01
Ba CFS-L04-1315-T01-B 1 2.04E+01
Ba CFS-L04-1315-T02-B 1 2.49E+01
Ba CFS-L04-1315-T03-B 1 2.89E+01
Ba CFS-L04-1315-T04-B 1 2.63E+01
Ba CFS-L04-1315-T05-B 1 3.52E+01
Ba CFS-L04-1315-T06-B 1 3.64E+01
Ba CFS-L04-1315-T07-B 1 4.48E+01
Ba CFS-L04-1315-T08-B 1 3.70E+01
Ba CFS-L04-1315-T09-B 1 3.94E+01
Ba CFS-L04-1315-T01-C 1 1.66E+01
Ba CFS-L04-1315-T02-C 1 2.35E+01
Ba CFS-L04-1315-T03-C 1 2.57E+01
Ba CFS-L04-1315-T04-C 1 2.67E+01
Ba CFS-L04-1315-T05-C 1 3.05E+01
Ba CFS-L04-1315-T06-C 1 3.29E+01
Ba CFS-L04-1315-T07-C 1 4. 11 E+01
Ba CFS-L04-1315-T08-C 1 3.96E+01
Ba CFS-L04-1315-T09-C 1 3.46E+01
Ba CFS-L04-1315-M01-A 1 5.00E-01 U1/2
Ba CFS-L04-1315-M02-A 1 5.00E-01 U1/2
Ba CFS-L04-1315-M03-A 1 5.00E-01 U1/2
Ba CFS-L04-1315-M04-A 1 5.00E-01 U1/2
Ba CFS-L04-1315-M05-A 1 5.00E-01 U1/2
Ba CFS-L04-1315-M06-A 1 5.00E-01 U1/2
Ba CFS-L04-1315-M07-A 1 5.00E-01 U1/2
Ba CFS-L04-1315-M08-A 1 5.00E-01 U1/2
Ba CFS-L04-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.61E+01 1.21 1.00 3.18
2.51E+01 2.76 1.00 3.18
3.18E+01 1.76 1.00 3.18 10000 1000
2.60E+01 2.88 1.00 3.18
2.83E+01 1.44 1.00 3.18
3. 11 E+01 2.84 1.00 3.18
4.02E+01 0.68 1.00 3.18
3.60E+01 2.01 1.00 3.18
3.50E+01 1.36 1.00 3.18
2.04E+01 1.94 1.00 3.18
2.49E+01 1.21 1.00 3.18
2.89E+01 1.14 1.00 3.18 10000 1000
2.63E+01 0.56 1.00 3.18
3.52E+01 0.12 1.00 3.18
3.64E+01 0.42 1.00 3.18
4.48E+01 2.78 1.00 3.18
3.70E+01 1.33 1.00 3.18
3.94E+01 1.05 1.00 3.18
1.66E+01 2.05 1.00 3.18
2.35E+01 1.74 1.00 3.18
2.57E+01 1.37 1.00 3.18 10000 1000
2.67E+01 0.62 1.00 3.18
3.05E+01 0.44 1.00 3.18
3.29E+01 0.51 1.00 3.18
4. 11 E+01 0.59 1.00 3.18
3.96E+01 2.07 1.00 3.18
3.46E+01 1.97 1.00 3.18
5.00E-01 25.70 1.00 3.18
5.00E-01 7.50 1.00 3.18
5.00E-01 4.09 1.00 3.18
5.00E-01 0.58 1.00 3.18
5.00E-01 5.14 1.00 3.18
5.00E-01 29.43 1.00 3.18
5.00E-01 16.11 1.00 3.18
5.00E-01 8.38 1.00 3.18
5.00E-01 12.93 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-791
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Be CFS-L04-1315-T01-A 1 9.50E-01 U1/2
Be CFS-L04-1315-T02-A 1 9.50E-01 U1/2
Be CFS-L04-1315-T03-A 1 9.50E-01 U1/2
Be CFS-L04-1315-T04-A 1 9.50E-01 U1/2
Be CFS-L04-1315-T05-A 1 9.50E-01 U1/2
Be CFS-L04-1315-T06-A 1 9.50E-01 U1/2
Be CFS-L04-1315-T07-A 1 9.50E-01 U1/2
Be CFS-L04-1315-T08-A 1 9.50E-01 U1/2
Be CFS-L04-1315-T09-A 1 9.50E-01 U1/2
Be CFS-L04-1315-T01-B 1 9.50E-01 U1/2
Be CFS-L04-1315-T02-B 1 9.50E-01 U1/2
Be CFS-L04-1315-T03-B 1 9.50E-01 U1/2
Be CFS-L04-1315-T04-B 1 9.50E-01 U1/2
Be CFS-L04-1315-T05-B 1 9.50E-01 U1/2
Be CFS-L04-1315-T06-B 1 9.50E-01 U1/2
Be CFS-L04-1315-T07-B 1 9.50E-01 U1/2
Be CFS-L04-1315-T08-B 1 9.50E-01 U1/2
Be CFS-L04-1315-T09-B 1 9.50E-01 U1/2
Be CFS-L04-1315-T01-C 1 9.50E-01 U1/2
Be CFS-L04-1315-T02-C 1 9.50E-01 U1/2
Be CFS-L04-1315-T03-C 1 9.50E-01 U1/2
Be CFS-L04-1315-T04-C 1 9.50E-01 U1/2
Be CFS-L04-1315-T05-C 1 9.50E-01 U1/2
Be CFS-L04-1315-T06-C 1 9.50E-01 U1/2
Be CFS-L04-1315-T07-C 1 9.50E-01 U1/2
Be CFS-L04-1315-T08-C 1 9.50E-01 U1/2
Be CFS-L04-1315-T09-C 1 9.50E-01 U1/2
Be CFS-L04-1315-M01-A 1 9.50E-01 U1/2
Be CFS-L04-1315-M02-A 1 9.50E-01 U1/2
Be CFS-L04-1315-M03-A 1 9.50E-01 U1/2
Be CFS-L04-1315-M04-A 1 9.50E-01 U1/2
Be CFS-L04-1315-M05-A 1 9.50E-01 U1/2
Be CFS-L04-1315-M06-A 1 9.50E-01 U1/2
Be CFS-L04-1315-M07-A 1 9.50E-01 U1/2
Be CFS-L04-1315-M08-A 1 9.50E-01 U1/2
Be CFS-L04-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 68.94 1.90 6.00
9.50E-01 21.86 1.90 6.00
9.50E-01 2.57 1.90 6.00 10000 1000
9.50E-01 13.30 1.90 6.00
9.50E-01 38.91 1.90 6.00
9.50E-01 16.75 1.90 6.00
9.50E-01 55.22 1.90 6.00
9.50E-01 80.49 1.90 6.00
9.50E-01 42.14 1.90 6.00
9.50E-01 29.64 1.90 6.00
9.50E-01 20.10 1.90 6.00
9.50E-01 35.96 1.90 6.00 10000 1000
9.50E-01 1.54 1.90 6.00
9.50E-01 18.05 1.90 6.00
9.50E-01 51.19 1.90 6.00
9.50E-01 22.64 1.90 6.00
9.50E-01 40.05 1.90 6.00
9.50E-01 50.20 1.90 6.00
9.50E-01 47.57 1.90 6.00
9.50E-01 1.26 1.90 6.00
9.50E-01 30.30 1.90 6.00 10000 1000
9.50E-01 38.24 1.90 6.00
9.50E-01 5.47 1.90 6.00
9.50E-01 40.92 1.90 6.00
9.50E-01 69.34 1.90 6.00
9.50E-01 31.28 1.90 6.00
9.50E-01 9.18 1.90 6.00
9.50E-01 25.51 1.90 6.00
9.50E-01 37.64 1.90 6.00
9.50E-01 16.84 1.90 6.00
9.50E-01 28.90 1.90 6.00
9.50E-01 43.05 1.90 6.00
9.50E-01 29.97 1.90 6.00
9.50E-01 39.62 1.90 6.00
9.50E-01 9.29 1.90 6.00
9.50E-01 44.01 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-792
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Cd CFS-L04-1315-T01-A 1 1.27E+02
Cd CFS-L04-1315-T02-A 1 3.65E+02
Cd CFS-L04-1315-T03-A 1 4.13E+02
Cd CFS-L04-1315-T04-A 1 8.22E+02
Cd CFS-L04-1315-T05-A 1 1.08E+03
Cd CFS-L04-1315-T06-A 1 1.64E+03
Cd CFS-L04-1315-T07-A 1 1.56E+03
Cd CFS-L04-1315-T08-A 1 8.49E+02
Cd CFS-L04-1315-T09-A 1 1.65E+03
Cd CFS-L04-1315-T01-B 1 1.16E+02
Cd CFS-L04-1315-T02-B 1 3.33E+02
Cd CFS-L04-1315-T03-B 1 3.69E+02
Cd CFS-L04-1315-T04-B 1 8.34E+02
Cd CFS-L04-1315-T05-B 1 1.14E+03
Cd CFS-L04-1315-T06-B 1 1.65E+03
Cd CFS-L04-1315-T07-B 1 1.52E+03
Cd CFS-L04-1315-T08-B 1 8.29E+02
Cd CFS-L04-1315-T09-B 1 1.54E+03
Cd CFS-L04-1315-T01-C 1 1.04E+02
Cd CFS-L04-1315-T02-C 1 3.41 E+02
Cd CFS-L04-1315-T03-C 1 3.53E+02
Cd CFS-L04-1315-T04-C 1 9.27E+02
Cd CFS-L04-1315-T05-C 1 1.04E+03
Cd CFS-L04-1315-T06-C 1 1.68E+03
Cd CFS-L04-1315-T07-C 1 1.56E+03
Cd CFS-L04-1315-T08-C 1 9.21E+02
Cd CFS-L04-1315-T09-C 1 1.73E+03
Cd CFS-L04-1315-M01-A 1 1.10E+00 U1/2
Cd CFS-L04-1315-M02-A 1 1.10E+00 U1/2
Cd CFS-L04-1315-M03-A 1 1.10E+00 U1/2
Cd CFS-L04-1315-M04-A 1 1.10E+00 U1/2
Cd CFS-L04-1315-M05-A 1 1.10E+00 U1/2
Cd CFS-L04-1315-M06-A 1 1.10E+00 U1/2
Cd CFS-L04-1315-M07-A 1 1.10E+00 U1/2
Cd CFS-L04-1315-M08-A 1 1.10E+00 U1/2
Cd CFS-L04-1315-M09-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.27E+02 1.39 2.20 7.00
3.65E+02 2.62 2.20 7.00
4.13E+02 1.92 2.20 7.00 10000 1000
8.22E+02 2.84 2.20 7.00
1.08E+03 1.55 2.20 7.00
1.64E+03 2.38 2.20 7.00
1.56E+03 0.87 2.20 7.00
8.49E+02 2.15 2.20 7.00
1.65E+03 1.81 2.20 7.00
1.16E+02 2.27 2.20 7.00
3.33E+02 1.48 2.20 7.00
3.69E+02 1.30 2.20 7.00 10000 1000
8.34E+02 0.85 2.20 7.00
1.14E+03 0.28 2.20 7.00
1.65E+03 0.35 2.20 7.00
1.52E+03 2.93 2.20 7.00
8.29E+02 1.24 2.20 7.00
1.54E+03 1.01 2.20 7.00
1.04E+02 1.90 2.20 7.00
3.41 E+02 1.08 2.20 7.00
3.53E+02 1.61 2.20 7.00 10000 1000
9.27E+02 0.58 2.20 7.00
1.04E+03 0.41 2.20 7.00
1.68E+03 0.36 2.20 7.00
1.56E+03 0.67 2.20 7.00
9.21 E+02 2.04 2.20 7.00
1.73E+03 2.28 2.20 7.00
1.10E+00 13.61 2.20 7.00
1.10E+00 16.17 2.20 7.00
1.10E+00 23.94 2.20 7.00
1.10E+00 3.80 2.20 7.00
1.10E+00 13.40 2.20 7.00
1.10E+00 9.04 2.20 7.00
1.10E+00 6.05 2.20 7.00
1.10E+00 9.52 2.20 7.00
1.10E+00 13.41 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.34E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.46E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.34E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-793
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Ca CFS-L04-1315-T01-A 1 1.84E+04
Ca CFS-L04-1315-T02-A 1 4.10E+04
Ca CFS-L04-1315-T03-A 1 5.14E+04
Ca CFS-L04-1315-T04-A 1 8.97E+04
Ca CFS-L04-1315-T05-A 1 1.02E+05
Ca CFS-L04-1315-T06-A 1 1.36E+05
Ca CFS-L04-1315-T07-A 1 1.42E+05
Ca CFS-L04-1315-T08-A 1 7.82E+04
Ca CFS-L04-1315-T09-A 1 1.58E+05
Ca CFS-L04-1315-T01-B 1 2.53E+04
Ca CFS-L04-1315-T02-B 1 4.26E+04
Ca CFS-L04-1315-T03-B 1 5.27E+04
Ca CFS-L04-1315-T04-B 1 9.10E+04
Ca CFS-L04-1315-T05-B 1 1.17E+05
Ca CFS-L04-1315-T06-B 1 1.46E+05
Ca CFS-L04-1315-T07-B 1 1.43E+05
Ca CFS-L04-1315-T08-B 1 8.06E+04
Ca CFS-L04-1315-T09-B 1 1.49E+05
Ca CFS-L04-1315-T01-C 1 2.00E+04
Ca CFS-L04-1315-T02-C 1 3.95E+04
Ca CFS-L04-1315-T03-C 1 4.18E+04
Ca CFS-L04-1315-T04-C 1 9.27E+04
Ca CFS-L04-1315-T05-C 1 1.05E+05
Ca CFS-L04-1315-T06-C 1 1.40E+05
Ca CFS-L04-1315-T07-C 1 1.45E+05
Ca CFS-L04-1315-T08-C 1 8.80E+04
Ca CFS-L04-1315-T09-C 1 1.69E+05
Ca CFS-L04-1315-M01-A 1 2.32E+01
Ca CFS-L04-1315-M02-A 1 2.21E+01
Ca CFS-L04-1315-M03-A 1 1.79E+01
Ca CFS-L04-1315-M04-A 1 1.68E+01
Ca CFS-L04-1315-M05-A 1 1.77E+01
Ca CFS-L04-1315-M06-A 1 1.94E+01
Ca CFS-L04-1315-M07-A 1 9.81E+00
Ca CFS-L04-1315-M08-A 1 1.36E+01
Ca CFS-L04-1315-M09-A 1 3.75E+00 E
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.84E+04 0.83 2.60 8.30
4.10E+04 1.36 2.60 8.30
5.14E+04 1.14 2.60 8.30 10000 1000
8.97E+04 1.04 2.60 8.30
1.02E+05 1.36 2.60 8.30
1.36E+05 2.14 2.60 8.30
1.42E+05 0.83 2.60 8.30
7.82E+04 2.06 2.60 8.30
1.58E+05 1.93 2.60 8.30
2.53E+04 2.07 2.60 8.30
4.26E+04 0.69 2.60 8.30
5.27E+04 1.11 2.60 8.30 10000 1000
9.10E+04 0.87 2.60 8.30
1.17E+05 0.25 2.60 8.30
1.46E+05 0.25 2.60 8.30
1.43E+05 2.65 2.60 8.30
8.06E+04 1.32 2.60 8.30
1.49E+05 1.05 2.60 8.30
2.00E+04 1.98 2.60 8.30
3.95E+04 0.34 2.60 8.30
4.18E+04 1.84 2.60 8.30 10000 1000
9.27E+04 0.79 2.60 8.30
1.05E+05 0.18 2.60 8.30
1.40E+05 0.44 2.60 8.30
1.45E+05 0.79 2.60 8.30
8.80E+04 1.85 2.60 8.30
1.69E+05 2.01 2.60 8.30
2.32E+01 1.00 2.60 8.30
2.21E+01 5.81 2.60 8.30
1.79E+01 6.10 2.60 8.30
1.68E+01 1.01 2.60 8.30
1.77E+01 4.20 2.60 8.30
1.94E+01 3.14 2.60 8.30
9.81E+00 1.40 2.60 8.30
1.36E+01 2.18 2.60 8.30
3.75E+00 12.72 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.23E+04 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.36E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.27E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
1 0/1 0/1 1 3:28 PM EPA Interlab L04 1 31 5 CFS
1 0/1 0/1 1 3:29 PM EPA Interlab L04 1 31 5 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-794
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Cr CFS-L04-1315-T01-A 1 6.00E-01 U1/2
Cr CFS-L04-1315-T02-A 1 6.00E-01 U1/2
Cr CFS-L04-1315-T03-A 1 6.00E-01 U1/2
Cr CFS-L04-1315-T04-A 1 6.00E-01 U1/2
Cr CFS-L04-1315-T05-A 1 6.00E-01 U1/2
Cr CFS-L04-1315-T06-A 1 6.00E-01 U1/2
Cr CFS-L04-1315-T07-A 1 6.00E-01 U1/2
Cr CFS-L04-1315-T08-A 1 6.00E-01 U1/2
Cr CFS-L04-1315-T09-A 1 6.00E-01 U1/2
Cr CFS-L04-1315-T01-B 1 6.00E-01 U1/2
Cr CFS-L04-1315-T02-B 1 6.00E-01 U1/2
Cr CFS-L04-1315-T03-B 1 6.00E-01 U1/2
Cr CFS-L04-1315-T04-B 1 6.00E-01 U1/2
Cr CFS-L04-1315-T05-B 1 6.00E-01 U1/2
Cr CFS-L04-1315-T06-B 1 6.00E-01 U1/2
Cr CFS-L04-1315-T07-B 1 6.00E-01 U1/2
Cr CFS-L04-1315-T08-B 1 6.00E-01 U1/2
Cr CFS-L04-1315-T09-B 1 6.00E-01 U1/2
Cr CFS-L04-1315-T01-C 1 6.00E-01 U1/2
Cr CFS-L04-1315-T02-C 1 6.00E-01 U1/2
Cr CFS-L04-1315-T03-C 1 6.00E-01 U1/2
Cr CFS-L04-1315-T04-C 1 6.00E-01 U1/2
Cr CFS-L04-1315-T05-C 1 6.00E-01 U1/2
Cr CFS-L04-1315-T06-C 1 6.00E-01 U1/2
Cr CFS-L04-1315-T07-C 1 6.00E-01 U1/2
Cr CFS-L04-1315-T08-C 1 6.00E-01 U1/2
Cr CFS-L04-1315-T09-C 1 6.00E-01 U1/2
Cr CFS-L04-1315-M01-A 1 6.00E-01 U1/2
Cr CFS-L04-1315-M02-A 1 6.00E-01 U1/2
Cr CFS-L04-1315-M03-A 1 6.00E-01 U1/2
Cr CFS-L04-1315-M04-A 1 6.00E-01 U1/2
Cr CFS-L04-1315-M05-A 1 6.00E-01 U1/2
Cr CFS-L04-1315-M06-A 1 6.00E-01 U1/2
Cr CFS-L04-1315-M07-A 1 6.00E-01 U1/2
Cr CFS-L04-1315-M08-A 1 6.00E-01 U1/2
Cr CFS-L04-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 17.20 1.20 3.82
6.00E-01 24.78 1.20 3.82
6.00E-01 1.10 1.20 3.82 10000 1000
6.00E-01 23.20 1.20 3.82
6.00E-01 11.95 1.20 3.82
6.00E-01 15.28 1.20 3.82
6.00E-01 14.77 1.20 3.82
6.00E-01 52.44 1.20 3.82
6.00E-01 43.43 1.20 3.82
6.00E-01 18.81 1.20 3.82
6.00E-01 33.69 1.20 3.82
6.00E-01 21.32 1.20 3.82 10000 1000
6.00E-01 20.50 1.20 3.82
6.00E-01 83.79 1.20 3.82
6.00E-01 41.89 1.20 3.82
6.00E-01 48.28 1.20 3.82
6.00E-01 63.45 1.20 3.82
6.00E-01 42.61 1.20 3.82
6.00E-01 9.57 1.20 3.82
6.00E-01 2.33 1.20 3.82
6.00E-01 55.24 1.20 3.82 10000 1000
6.00E-01 62.93 1.20 3.82
6.00E-01 287.11 1.20 3.82
6.00E-01 56.88 1.20 3.82
6.00E-01 16.22 1.20 3.82
6.00E-01 37.25 1.20 3.82
6.00E-01 8.89 1.20 3.82
6.00E-01 10.47 1.20 3.82
6.00E-01 17.47 1.20 3.82
6.00E-01 10.08 1.20 3.82
6.00E-01 13.71 1.20 3.82
6.00E-01 67.10 1.20 3.82
6.00E-01 56.46 1.20 3.82
6.00E-01 70.37 1.20 3.82
6.00E-01 27.78 1.20 3.82
6.00E-01 66.19 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.99E+02 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-795
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Co CFS-L04-1315-T01-A 1 9.00E-01 U1/2
Co CFS-L04-1315-T02-A 1 8.12E+00
Co CFS-L04-1315-T03-A 1 7.82E+00
Co CFS-L04-1315-T04-A 1 2.11E+01
Co CFS-L04-1315-T05-A 1 2.82E+01
Co CFS-L04-1315-T06-A 1 4.67E+01
Co CFS-L04-1315-T07-A 1 4.33E+01
Co CFS-L04-1315-T08-A 1 2.37E+01
Co CFS-L04-1315-T09-A 1 4.94E+01
Co CFS-L04-1315-T01-B 1 9.00E-01 U1/2
Co CFS-L04-1315-T02-B 1 7.40E+00
Co CFS-L04-1315-T03-B 1 8.13E+00
Co CFS-L04-1315-T04-B 1 2.14E+01
Co CFS-L04-1315-T05-B 1 2.82E+01
Co CFS-L04-1315-T06-B 1 4.61 E+01
Co CFS-L04-1315-T07-B 1 4.34E+01
Co CFS-L04-1315-T08-B 1 2.29E+01
Co CFS-L04-1315-T09-B 1 4.46E+01
Co CFS-L04-1315-T01-C 1 9.00E-01 U1/2
Co CFS-L04-1315-T02-C 1 7.67E+00
Co CFS-L04-1315-T03-C 1 7.53E+00
Co CFS-L04-1315-T04-C 1 2.32E+01
Co CFS-L04-1315-T05-C 1 2.86E+01
Co CFS-L04-1315-T06-C 1 4.81 E+01
Co CFS-L04-1315-T07-C 1 4.55E+01
Co CFS-L04-1315-T08-C 1 2.54E+01
Co CFS-L04-1315-T09-C 1 5.14E+01
Co CFS-L04-1315-M01-A 1 9.00E-01 U1/2
Co CFS-L04-1315-M02-A 1 9.00E-01 U1/2
Co CFS-L04-1315-M03-A 1 9.00E-01 U1/2
Co CFS-L04-1315-M04-A 1 9.00E-01 U1/2
Co CFS-L04-1315-M05-A 1 9.00E-01 U1/2
Co CFS-L04-1315-M06-A 1 9.00E-01 U1/2
Co CFS-L04-1315-M07-A 1 9.00E-01 U1/2
Co CFS-L04-1315-M08-A 1 9.00E-01 U1/2
Co CFS-L04-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 8.51 1.80 5.72
8.12E+00 4.04 1.80 5.72
7.82E+00 1.53 1.80 5.72 10000 1000
2. 11 E+01 2.28 1.80 5.72
2.82E+01 1.46 1.80 5.72
4.67E+01 2.44 1.80 5.72
4.33E+01 1.92 1.80 5.72
2.37E+01 3.14 1.80 5.72
4.94E+01 2.59 1.80 5.72
9.00E-01 31.78 1.80 5.72
7.40E+00 3.50 1.80 5.72
8.13E+00 6.29 1.80 5.72 10000 1000
2.14E+01 3.67 1.80 5.72
2.82E+01 2.03 1.80 5.72
4.61 E+01 2.49 1.80 5.72
4.34E+01 3.71 1.80 5.72
2.29E+01 2.33 1.80 5.72
4.46E+01 2.76 1.80 5.72
9.00E-01 24.14 1.80 5.72
7.67E+00 2.39 1.80 5.72
7.53E+00 7.91 1.80 5.72 10000 1000
2.32E+01 0.38 1.80 5.72
2.86E+01 1.33 1.80 5.72
4.81E+01 1.07 1.80 5.72
4.55E+01 0.57 1.80 5.72
2.54E+01 3.63 1.80 5.72
5.14E+01 0.98 1.80 5.72
9.00E-01 86.84 1.80 5.72
9.00E-01 40.73 1.80 5.72
9.00E-01 27.18 1.80 5.72
9.00E-01 50.93 1.80 5.72
9.00E-01 36.86 1.80 5.72
9.00E-01 12.49 1.80 5.72
9.00E-01 54.65 1.80 5.72
9.00E-01 21.27 1.80 5.72
9.00E-01 40.36 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-796
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Cu CFS-L04-1315-T01-A 1 8.25E+01
Cu CFS-L04-1315-T02-A 1 1.65E+02
Cu CFS-L04-1315-T03-A 1 1.58E+02
Cu CFS-L04-1315-T04-A 1 3.41 E+02
Cu CFS-L04-1315-T05-A 1 4.13E+02
Cu CFS-L04-1315-T06-A 1 7.09E+02
Cu CFS-L04-1315-T07-A 1 7.72E+02
Cu CFS-L04-1315-T08-A 1 6.05E+02
Cu CFS-L04-1315-T09-A 1 8.64E+02
Cu CFS-L04-1315-T01-B 1 8.32E+01
Cu CFS-L04-1315-T02-B 1 1.93E+02
Cu CFS-L04-1315-T03-B 1 1.86E+02
Cu CFS-L04-1315-T04-B 1 3.45E+02
Cu CFS-L04-1315-T05-B 1 3.95E+02
Cu CFS-L04-1315-T06-B 1 6.92E+02
Cu CFS-L04-1315-T07-B 1 7.50E+02
Cu CFS-L04-1315-T08-B 1 5.65E+02
Cu CFS-L04-1315-T09-B 1 8.65E+02
Cu CFS-L04-1315-T01-C 1 8.49E+01
Cu CFS-L04-1315-T02-C 1 1.89E+02
Cu CFS-L04-1315-T03-C 1 1.55E+02
Cu CFS-L04-1315-T04-C 1 3.08E+02
Cu CFS-L04-1315-T05-C 1 4.00E+02
Cu CFS-L04-1315-T06-C 1 6.98E+02
Cu CFS-L04-1315-T07-C 1 7.94E+02
Cu CFS-L04-1315-T08-C 1 5.73E+02
Cu CFS-L04-1315-T09-C 1 8.50E+02
Cu CFS-L04-1315-M01-A 1 1.85E+00 U1/2
Cu CFS-L04-1315-M02-A 1 1.85E+00 U1/2
Cu CFS-L04-1315-M03-A 1 1.85E+00 U1/2
Cu CFS-L04-1315-M04-A 1 1.85E+00 U1/2
Cu CFS-L04-1315-M05-A 1 1.85E+00 U1/2
Cu CFS-L04-1315-M06-A 1 1.85E+00 U1/2
Cu CFS-L04-1315-M07-A 1 1.85E+00 U1/2
Cu CFS-L04-1315-M08-A 1 1.85E+00 U1/2
Cu CFS-L04-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.25E+01 1.58 3.70 11.80
1.65E+02 1.60 3.70 11.80
1.58E+02 1.41 3.70 11.80 10000 1000
3.41 E+02 3.02 3.70 11.80
4.13E+02 1.32 3.70 11.80
7.09E+02 2.00 3.70 11.80
7.72E+02 0.64 3.70 11.80
6.05E+02 2.50 3.70 11.80
8.64E+02 1.18 3.70 11.80
8.32E+01 3.10 3.70 11.80
1.93E+02 3.42 3.70 11.80
1.86E+02 1.28 3.70 11.80 10000 1000
3.45E+02 1.74 3.70 11.80
3.95E+02 1.15 3.70 11.80
6.92E+02 1.45 3.70 11.80
7.50E+02 2.54 3.70 11.80
5.65E+02 1.68 3.70 11.80
8.65E+02 0.45 3.70 11.80
8.49E+01 1.78 3.70 11.80
1.89E+02 1.35 3.70 11.80
1.55E+02 1.39 3.70 11.80 10000 1000
3.08E+02 1.10 3.70 11.80
4.00E+02 1.25 3.70 11.80
6.98E+02 0.49 3.70 11.80
7.94E+02 0.28 3.70 11.80
5.73E+02 2.62 3.70 11.80
8.50E+02 1.84 3.70 11.80
1.85E+00 39.83 3.70 11.80
1.85E+00 21.77 3.70 11.80
1.85E+00 28.49 3.70 11.80
1.85E+00 36.32 3.70 11.80
1.85E+00 21.66 3.70 11.80
1.85E+00 9.07 3.70 11.80
1.85E+00 30.99 3.70 11.80
1.85E+00 13.69 3.70 11.80
1.85E+00 23.89 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.14E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.20E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315 CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
1 0/1 0/1 1 1 : 1 4 PM EPA Interlab L04 1 31 5 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-797
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Fe CFS-L04-1315-T01-A 1 1.00E+00 U1/2
Fe CFS-L04-1315-T02-A 1 1.00E+00 U1/2
Fe CFS-L04-1315-T03-A 1 1.00E+00 U1/2
Fe CFS-L04-1315-T04-A 1 1.00E+00 U1/2
Fe CFS-L04-1315-T05-A 1 1.00E+00 U1/2
Fe CFS-L04-1315-T06-A 1 1.00E+00 U1/2
Fe CFS-L04-1315-T07-A 1 1.00E+00 U1/2
Fe CFS-L04-1315-T08-A 1 1.00E+00 U1/2
Fe CFS-L04-1315-T09-A 1 1.00E+00 U1/2
Fe CFS-L04-1315-T01-B 1 1.00E+00 U1/2
Fe CFS-L04-1315-T02-B 1 1.00E+00 U1/2
Fe CFS-L04-1315-T03-B 1 1.00E+00 U1/2
Fe CFS-L04-1315-T04-B 1 1.00E+00 U1/2
Fe CFS-L04-1315-T05-B 1 1.00E+00 U1/2
Fe CFS-L04-1315-T06-B 1 1.00E+00 U1/2
Fe CFS-L04-1315-T07-B 1 1.00E+00 U1/2
Fe CFS-L04-1315-T08-B 1 1.00E+00 U1/2
Fe CFS-L04-1315-T09-B 1 1.00E+00 U1/2
Fe CFS-L04-1315-T01-C 1 1.00E+00 U1/2
Fe CFS-L04-1315-T02-C 1 1.00E+00 U1/2
Fe CFS-L04-1315-T03-C 1 1.00E+00 U1/2
Fe CFS-L04-1315-T04-C 1 1.00E+00 U1/2
Fe CFS-L04-1315-T05-C 1 1.00E+00 U1/2
Fe CFS-L04-1315-T06-C 1 1.00E+00 U1/2
Fe CFS-L04-1315-T07-C 1 1.00E+00 U1/2
Fe CFS-L04-1315-T08-C 1 1.00E+00 U1/2
Fe CFS-L04-1315-T09-C 1 1.00E+00 U1/2
Fe CFS-L04-1315-M01-A 1 1.00E+00 U1/2
Fe CFS-L04-1315-M02-A 1 1.00E+00 U1/2
Fe CFS-L04-1315-M03-A 1 1.00E+00 U1/2
Fe CFS-L04-1315-M04-A 1 1.00E+00 U1/2
Fe CFS-L04-1315-M05-A 1 1.00E+00 U1/2
Fe CFS-L04-1315-M06-A 1 1.00E+00 U1/2
Fe CFS-L04-1315-M07-A 1 1.00E+00 U1/2
Fe CFS-L04-1315-M08-A 1 1.00E+00 U1/2
Fe CFS-L04-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 8.47 2.00 6.40
1.00E+00 21.41 2.00 6.40
1.00E+00 1.65 2.00 6.40 10000 1000
1.00E+00 17.73 2.00 6.40
1.00E+00 29.26 2.00 6.40
1.00E+00 8.92 2.00 6.40
1.00E+00 29.27 2.00 6.40
1.00E+00 8.53 2.00 6.40
1.00E+00 2.88 2.00 6.40
1.00E+00 5.97 2.00 6.40
1.00E+00 1.00 2.00 6.40
1.00E+00 23.25 2.00 6.40 10000 1000
1.00E+00 39.66 2.00 6.40
1.00E+00 19.63 2.00 6.40
1.00E+00 21.14 2.00 6.40
1.00E+00 10.41 2.00 6.40
1.00E+00 8.33 2.00 6.40
1.00E+00 6.72 2.00 6.40
1.00E+00 2.31 2.00 6.40
1.00E+00 2.11 2.00 6.40
1.00E+00 11.34 2.00 6.40 10000 1000
1.00E+00 3.99 2.00 6.40
1.00E+00 21.75 2.00 6.40
1.00E+00 16.16 2.00 6.40
1.00E+00 27.06 2.00 6.40
1.00E+00 6.71 2.00 6.40
1.00E+00 27.15 2.00 6.40
1.00E+00 12.19 2.00 6.40
1.00E+00 17.59 2.00 6.40
1.00E+00 10.89 2.00 6.40
1.00E+00 14.35 2.00 6.40
1.00E+00 20.15 2.00 6.40
1.00E+00 31.89 2.00 6.40
1.00E+00 28.72 2.00 6.40
1.00E+00 1.77 2.00 6.40
1.00E+00 5.18 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.66E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.84E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-798
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Pb CFS-L04-1315-T01-A 1 1.25E+02
Pb CFS-L04-1315-T02-A 1 2.84E+02
Pb CFS-L04-1315-T03-A 1 3.12E+02
Pb CFS-L04-1315-T04-A 1 4.82E+02
Pb CFS-L04-1315-T05-A 1 5.69E+02
Pb CFS-L04-1315-T06-A 1 7.77E+02
Pb CFS-L04-1315-T07-A 1 7.90E+02
Pb CFS-L04-1315-T08-A 1 6.89E+02
Pb CFS-L04-1315-T09-A 1 8.69E+02
Pb CFS-L04-1315-T01-B 1 1.47E+02
Pb CFS-L04-1315-T02-B 1 2.73E+02
Pb CFS-L04-1315-T03-B 1 3.00E+02
Pb CFS-L04-1315-T04-B 1 4.89E+02
Pb CFS-L04-1315-T05-B 1 5.63E+02
Pb CFS-L04-1315-T06-B 1 7.52E+02
Pb CFS-L04-1315-T07-B 1 8.20E+02
Pb CFS-L04-1315-T08-B 1 6.60E+02
Pb CFS-L04-1315-T09-B 1 8.31 E+02
Pb CFS-L04-1315-T01-C 1 1.25E+02
Pb CFS-L04-1315-T02-C 1 2.34E+02
Pb CFS-L04-1315-T03-C 1 3.07E+02
Pb CFS-L04-1315-T04-C 1 4.84E+02
Pb CFS-L04-1315-T05-C 1 5.87E+02
Pb CFS-L04-1315-T06-C 1 7.97E+02
Pb CFS-L04-1315-T07-C 1 8.32E+02
Pb CFS-L04-1315-T08-C 1 6.92E+02
Pb CFS-L04-1315-T09-C 1 8.13E+02
Pb CFS-L04-1315-M01-A 1 3.40E+00 U1/2
Pb CFS-L04-1315-M02-A 1 3.40E+00 U1/2
Pb CFS-L04-1315-M03-A 1 3.40E+00 U1/2
Pb CFS-L04-1315-M04-A 1 3.40E+00 U1/2
Pb CFS-L04-1315-M05-A 1 3.40E+00 U1/2
Pb CFS-L04-1315-M06-A 1 3.40E+00 U1/2
Pb CFS-L04-1315-M07-A 1 3.40E+00 U1/2
Pb CFS-L04-1315-M08-A 1 3.40E+00 U1/2
Pb CFS-L04-1315-M09-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.25E+02 3.68 6.80 21.60
2.84E+02 1.48 6.80 21.60
3.12E+02 2.31 6.80 21.60 10000 1000
4.82E+02 2.24 6.80 21.60
5.69E+02 1.26 6.80 21.60
7.77E+02 3.03 6.80 21.60
7.90E+02 0.94 6.80 21.60
6.89E+02 1.29 6.80 21.60
8.69E+02 2.47 6.80 21.60
1.47E+02 3.00 6.80 21.60
2.73E+02 15.70 6.80 21.60
3.00E+02 0.97 6.80 21.60 10000 1000
4.89E+02 1.05 6.80 21.60
5.63E+02 0.59 6.80 21.60
7.52E+02 0.45 6.80 21.60
8.20E+02 4.30 6.80 21.60
6.60E+02 1.01 6.80 21.60
8.31 E+02 1.75 6.80 21.60
1.25E+02 3.20 6.80 21.60
2.34E+02 0.86 6.80 21.60
3.07E+02 1.55 6.80 21.60 10000 1000
4.84E+02 0.77 6.80 21.60
5.87E+02 0.56 6.80 21.60
7.97E+02 0.64 6.80 21.60
8.32E+02 0.56 6.80 21.60
6.92E+02 1.53 6.80 21.60
8.13E+02 2.41 6.80 21.60
3.40E+00 13.88 6.80 21.60
3.40E+00 22.76 6.80 21.60
3.40E+00 45.10 6.80 21.60
3.40E+00 39.72 6.80 21.60
3.40E+00 49.79 6.80 21.60
3.40E+00 38.85 6.80 21.60
3.40E+00 22.14 6.80 21.60
3.40E+00 34.40 6.80 21.60
3.40E+00 10.54 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.23E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.33E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.32E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-799
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Li CFS-L04-1315-T01-A 1 4.30E+00 E
Li CFS-L04-1315-T02-A 1 6.68E+00
Li CFS-L04-1315-T03-A 1 7.80E+00
Li CFS-L04-1315-T04-A 1 7.87E+00
Li CFS-L04-1315-T05-A 1 8.02E+00
Li CFS-L04-1315-T06-A 1 8.47E+00
Li CFS-L04-1315-T07-A 1 6.50E+00
Li CFS-L04-1315-T08-A 1 6.42E+00
Li CFS-L04-1315-T09-A 1 7.23E+00
Li CFS-L04-1315-T01-B 1 3.69E+00 E
Li CFS-L04-1315-T02-B 1 5.23E+00 E
Li CFS-L04-1315-T03-B 1 7.31E+00
Li CFS-L04-1315-T04-B 1 8.30E+00
Li CFS-L04-1315-T05-B 1 7.94E+00
Li CFS-L04-1315-T06-B 1 8.30E+00
Li CFS-L04-1315-T07-B 1 5.70E+00 E
Li CFS-L04-1315-T08-B 1 5.96E+00 E
Li CFS-L04-1315-T09-B 1 6.85E+00
Li CFS-L04-1315-T01-C 1 3.88E+00 E
Li CFS-L04-1315-T02-C 1 6.02E+00
Li CFS-L04-1315-T03-C 1 7.33E+00
Li CFS-L04-1315-T04-C 1 7.93E+00
Li CFS-L04-1315-T05-C 1 8.14E+00
Li CFS-L04-1315-T06-C 1 8.68E+00
Li CFS-L04-1315-T07-C 1 6.93E+00
Li CFS-L04-1315-T08-C 1 7.02E+00
Li CFS-L04-1315-T09-C 1 6.67E+00
Li CFS-L04-1315-M01-A 1 9.50E-01 U1/2
Li CFS-L04-1315-M02-A 1 9.50E-01 U1/2
Li CFS-L04-1315-M03-A 1 9.50E-01 U1/2
Li CFS-L04-1315-M04-A 1 9.50E-01 U1/2
Li CFS-L04-1315-M05-A 1 9.50E-01 U1/2
Li CFS-L04-1315-M06-A 1 9.50E-01 U1/2
Li CFS-L04-1315-M07-A 1 9.50E-01 U1/2
Li CFS-L04-1315-M08-A 1 9.50E-01 U1/2
Li CFS-L04-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.30E+00 9.19 1.90 6.00
6.68E+00 6.73 1.90 6.00
7.80E+00 1.89 1.90 6.00 10000 1000
7.87E+00 4.21 1.90 6.00
8.02E+00 2.29 1.90 6.00
8.47E+00 2.28 1.90 6.00
6.50E+00 3.26 1.90 6.00
6.42E+00 1.67 1.90 6.00
7.23E+00 13.35 1.90 6.00
3.69E+00 14.61 1.90 6.00
5.23E+00 0.57 1.90 6.00
7.31E+00 1.86 1.90 6.00 10000 1000
8.30E+00 5.90 1.90 6.00
7.94E+00 5.72 1.90 6.00
8.30E+00 1.83 1.90 6.00
5.70E+00 9.42 1.90 6.00
5.96E+00 15.54 1.90 6.00
6.85E+00 12.98 1.90 6.00
3.88E+00 7.06 1.90 6.00
6.02E+00 1.09 1.90 6.00
7.33E+00 7.58 1.90 6.00 10000 1000
7.93E+00 2.66 1.90 6.00
8.14E+00 4.94 1.90 6.00
8.68E+00 2.61 1.90 6.00
6.93E+00 6.67 1.90 6.00
7.02E+00 2.35 1.90 6.00
6.67E+00 2.04 1.90 6.00
9.50E-01 31.48 1.90 6.00
9.50E-01 13.29 1.90 6.00
9.50E-01 33.50 1.90 6.00
9.50E-01 23.70 1.90 6.00
9.50E-01 24.60 1.90 6.00
9.50E-01 45.19 1.90 6.00
9.50E-01 32.04 1.90 6.00
9.50E-01 36.71 1.90 6.00
9.50E-01 42.18 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.54E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.44E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-800
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
Mn CFS-L04-1315-T01-A 1 5.44E+01
Mn CFS-L04-1315-T02-A 1 2.18E+02
Mn CFS-L04-1315-T03-A 1 1.95E+02
Mn CFS-L04-1315-T04-A 1 5.44E+02
Mn CFS-L04-1315-T05-A 1 7.15E+02
Mn CFS-L04-1315-T06-A 1 1.25E+03
Mn CFS-L04-1315-T07-A 1 1.19E+03
Mn CFS-L04-1315-T08-A 1 6.57E+02
Mn CFS-L04-1315-T09-A 1 1.39E+03
Mn CFS-L04-1315-T01-B 1 5.53E+01
Mn CFS-L04-1315-T02-B 1 1.97E+02
Mn CFS-L04-1315-T03-B 1 1.89E+02
Mn CFS-L04-1315-T04-B 1 5.52E+02
Mn CFS-L04-1315-T05-B 1 7.50E+02
Mn CFS-L04-1315-T06-B 1 1.28E+03
Mn CFS-L04-1315-T07-B 1 1.17E+03
Mn CFS-L04-1315-T08-B 1 6.25E+02
Mn CFS-L04-1315-T09-B 1 1.33E+03
Mn CFS-L04-1315-T01-C 1 5.69E+01
Mn CFS-L04-1315-T02-C 1 2.16E+02
Mn CFS-L04-1315-T03-C 1 2.07E+02
Mn CFS-L04-1315-T04-C 1 6.11E+02
Mn CFS-L04-1315-T05-C 1 7.35E+02
Mn CFS-L04-1315-T06-C 1 1.30E+03
Mn CFS-L04-1315-T07-C 1 1.26E+03
Mn CFS-L04-1315-T08-C 1 6.87E+02
Mn CFS-L04-1315-T09-C 1 1.45E+03
Mn CFS-L04-1315-M01-A 1 1.00E+00 U1/2
Mn CFS-L04-1315-M02-A 1 1.00E+00 U1/2
Mn CFS-L04-1315-M03-A 1 1.00E+00 U1/2
Mn CFS-L04-1315-M04-A 1 1.00E+00 U1/2
Mn CFS-L04-1315-M05-A 1 1.00E+00 U1/2
Mn CFS-L04-1315-M06-A 1 1.00E+00 U1/2
Mn CFS-L04-1315-M07-A 1 1.00E+00 U1/2
Mn CFS-L04-1315-M08-A 1 1.00E+00 U1/2
Mn CFS-L04-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.44E+01 1.24 2.00 6.40
2.18E+02 9.41 2.00 6.40
1.95E+02 2.11 2.00 6.40 10000 1000
5.44E+02 2.00 6.40
7.15E+02 0.75 2.00 6.40
1.25E+03 1.51 2.00 6.40
1.19E+03 1.37 2.00 6.40
6.57E+02 0.75 2.00 6.40
1.39E+03 0.91 2.00 6.40
5.53E+01 2.17 2.00 6.40
1.97E+02 6.47 2.00 6.40
1.89E+02 1.25 2.00 6.40 10000 1000
5.52E+02 0.71 2.00 6.40
7.50E+02 1.04 2.00 6.40
1.28E+03 0.65 2.00 6.40
1.17E+03 1.42 2.00 6.40
6.25E+02 1.30 2.00 6.40
1.33E+03 1.70 2.00 6.40
5.69E+01 2.14 2.00 6.40
2.16E+02 0.69 2.00 6.40
2.07E+02 2.15 2.00 6.40 10000 1000
6.11E+02 1.08 2.00 6.40
7.35E+02 0.86 2.00 6.40
1.30E+03 0.42 2.00 6.40
1.26E+03 1.38 2.00 6.40
6.87E+02 1.61 2.00 6.40
1.45E+03 1.36 2.00 6.40
1.00E+00 7.34 2.00 6.40
1.00E+00 0.88 2.00 6.40
1.00E+00 10.36 2.00 6.40
1.00E+00 4.59 2.00 6.40
1.00E+00 10.84 2.00 6.40
1.00E+00 5.66 2.00 6.40
1.00E+00 1.94 2.00 6.40
1.00E+00 6.72 2.00 6.40
1.00E+00 13.89 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.22E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-801
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Mg CFS-L04-1315-T01-A 1 3.42E+03
Mg CFS-L04-1315-T02-A 1 1.16E+04
Mg CFS-L04-1315-T03-A 1 1.12E+04
Mg CFS-L04-1315-T04-A 1 4.28E+04
Mg CFS-L04-1315-T05-A 1 5.57E+04
Mg CFS-L04-1315-T06-A 1 9.21E+04
Mg CFS-L04-1315-T07-A 1 7.54E+04
Mg CFS-L04-1315-T08-A 1 3.13E+04
Mg CFS-L04-1315-T09-A 1 7.63E+04
Mg CFS-L04-1315-T01-B 1 3.44E+03
Mg CFS-L04-1315-T02-B 1 1.32E+04
Mg CFS-L04-1315-T03-B 1 1.20E+04
Mg CFS-L04-1315-T04-B 1 4.34E+04
Mg CFS-L04-1315-T05-B 1 6.03E+04
Mg CFS-L04-1315-T06-B 1 9.51 E+04
Mg CFS-L04-1315-T07-B 1 7. 51 E+04
Mg CFS-L04-1315-T08-B 1 3.13E+04
Mg CFS-L04-1315-T09-B 1 7.38E+04
Mg CFS-L04-1315-T01-C 1 3.63E+03
Mg CFS-L04-1315-T02-C 1 1.43E+04
Mg CFS-L04-1315-T03-C 1 1.36E+04
Mg CFS-L04-1315-T04-C 1 4.55E+04
Mg CFS-L04-1315-T05-C 1 5.52E+04
Mg CFS-L04-1315-T06-C 1 9.08E+04
Mg CFS-L04-1315-T07-C 1 7.55E+04
Mg CFS-L04-1315-T08-C 1 3.15E+04
Mg CFS-L04-1315-T09-C 1 7.55E+04
Mg CFS-L04-1315-M01-A 1 5.00E-01 U1/2
Mg CFS-L04-1315-M02-A 1 5.00E-01 U1/2
Mg CFS-L04-1315-M03-A 1 5.00E-01 U1/2
Mg CFS-L04-1315-M04-A 1 5.00E-01 U1/2
Mg CFS-L04-1315-M05-A 1 5.00E-01 U1/2
Mg CFS-L04-1315-M06-A 1 5.00E-01 U1/2
Mg CFS-L04-1315-M07-A 1 5.00E-01 U1/2
Mg CFS-L04-1315-M08-A 1 5.00E-01 U1/2
Mg CFS-L04-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.42E+03 0.98 1.00 3.18
1.16E+04 1.61 1.00 3.18
1.12E+04 2.88 1.00 3.18 10000 1000
4.28E+04 1.33 1.00 3.18
5.57E+04 0.63 1.00 3.18
9.21E+04 2.02 1.00 3.18
7.54E+04 1.14 1.00 3.18
3.13E+04 2.08 1.00 3.18
7.63E+04 1.98 1.00 3.18
3.44E+03 2.58 1.00 3.18
1.32E+04 0.45 1.00 3.18
1.20E+04 1.01 1.00 3.18 10000 1000
4.34E+04 0.44 1.00 3.18
6.03E+04 0.72 1.00 3.18
9.51E+04 0.91 1.00 3.18
7.51E+04 1.10 1.00 3.18
3.13E+04 1.40 1.00 3.18
7.38E+04 1.90 1.00 3.18
3.63E+03 2.75 1.00 3.18
1.43E+04 0.68 1.00 3.18
1.36E+04 1.51 1.00 3.18 10000 1000
4.55E+04 1.14 1.00 3.18
5.52E+04 0.60 1.00 3.18
9.08E+04 0.96 1.00 3.18
7.55E+04 0.63 1.00 3.18
3.15E+04 2.64 1.00 3.18
7.55E+04 1.75 1.00 3.18
5.00E-01 20.41 1.00 3.18
5.00E-01 12.11 1.00 3.18
5.00E-01 25.51 1.00 3.18
5.00E-01 18.03 1.00 3.18
5.00E-01 3.00 1.00 3.18
5.00E-01 18.66 1.00 3.18
5.00E-01 36.13 1.00 3.18
5.00E-01 16.99 1.00 3.18
5.00E-01 26.70 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.21E+04 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.29E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.45E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-802
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Mo CFS-L04-1315-T01-A 1 2.44E+00 E
Mo CFS-L04-1315-T02-A 1 2.40E+00 E
Mo CFS-L04-1315-T03-A 1 2.44E+00 E
Mo CFS-L04-1315-T04-A 1 2.97E+00 E
Mo CFS-L04-1315-T05-A 1 3.61E+00 E
Mo CFS-L04-1315-T06-A 1 3.97E+00
Mo CFS-L04-1315-T07-A 1 3.04E+00 E
Mo CFS-L04-1315-T08-A 1 3.57E+00 E
Mo CFS-L04-1315-T09-A 1 3.89E+00
Mo CFS-L04-1315-T01-B 1 2.35E+00 E
Mo CFS-L04-1315-T02-B 1 2.57E+00 E
Mo CFS-L04-1315-T03-B 1 3.87E+00
Mo CFS-L04-1315-T04-B 1 3.01 E+00 E
Mo CFS-L04-1315-T05-B 1 3.56E+00 E
Mo CFS-L04-1315-T06-B 1 3.14E+00 E
Mo CFS-L04-1315-T07-B 1 4.96E+00
Mo CFS-L04-1315-T08-B 1 2.71E+00 E
Mo CFS-L04-1315-T09-B 1 4.22E+00
Mo CFS-L04-1315-T01-C 1 2.48E+00 E
Mo CFS-L04-1315-T02-C 1 3.11E+OOE
Mo CFS-L04-1315-T03-C 1 3.31E+00 E
Mo CFS-L04-1315-T04-C 1 3.76E+00 E
Mo CFS-L04-1315-T05-C 1 2.99E+00 E
Mo CFS-L04-1315-T06-C 1 4.28E+00
Mo CFS-L04-1315-T07-C 1 2.34E+00 E
Mo CFS-L04-1315-T08-C 1 2.96E+00 E
Mo CFS-L04-1315-T09-C 1 4.42E+00
Mo CFS-L04-1315-M01-A 1 6.00E-01 U1/2
Mo CFS-L04-1315-M02-A 1 6.00E-01 U1/2
Mo CFS-L04-1315-M03-A 1 6.00E-01 U1/2
Mo CFS-L04-1315-M04-A 1 6.00E-01 U1/2
Mo CFS-L04-1315-M05-A 1 6.00E-01 U1/2
Mo CFS-L04-1315-M06-A 1 6.00E-01 U1/2
Mo CFS-L04-1315-M07-A 1 6.00E-01 U1/2
Mo CFS-L04-1315-M08-A 1 6.00E-01 U1/2
Mo CFS-L04-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.44E+00 25.52 1.20 3.82
2.40E+00 31.19 1.20 3.82
2.44E+00 2.30 1.20 3.82 10000 1000
2.97E+00 16.30 1.20 3.82
3.61E+00 20.14 1.20 3.82
3.97E+00 3.60 1.20 3.82
3.04E+00 1.90 1.20 3.82
3.57E+00 12.33 1.20 3.82
3.89E+00 1.96 1.20 3.82
2.35E+00 20.90 1.20 3.82
2.57E+00 16.50 1.20 3.82
3.87E+00 9.16 1.20 3.82 10000 1000
3.01 E+00 2.70 1.20 3.82
3.56E+00 17.48 1.20 3.82
3.14E+00 5.93 1.20 3.82
4.96E+00 8.06 1.20 3.82
2.71E+00 19.35 1.20 3.82
4.22E+00 5.55 1.20 3.82
2.48E+00 8.34 1.20 3.82
3. 11 E+00 1.05 1.20 3.82
3.31 E+00 32.13 1.20 3.82 10000 1000
3.76E+00 27.99 1.20 3.82
2.99E+00 8.45 1.20 3.82
4.28E+00 2.33 1.20 3.82
2.34E+00 2.35 1.20 3.82
2.96E+00 17.58 1.20 3.82
4.42E+00 2.04 1.20 3.82
6.00E-01 10.37 1.20 3.82
6.00E-01 19.40 1.20 3.82
6.00E-01 22.58 1.20 3.82
6.00E-01 11.52 1.20 3.82
6.00E-01 23.45 1.20 3.82
6.00E-01 54.68 1.20 3.82
6.00E-01 7.67 1.20 3.82
6.00E-01 53.53 1.20 3.82
6.00E-01 53.65 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 131 5 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 131 5 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 131 5 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-803
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Ni CFS-L04-1315-T01-A 1 4.18E+00 E
Ni CFS-L04-1315-T02-A 1 1.49E+01
Ni CFS-L04-1315-T03-A 1 1.48E+01
Ni CFS-L04-1315-T04-A 1 3.79E+01
Ni CFS-L04-1315-T05-A 1 5.05E+01
Ni CFS-L04-1315-T06-A 1 8.16E+01
Ni CFS-L04-1315-T07-A 1 7.63E+01
Ni CFS-L04-1315-T08-A 1 3.76E+01
Ni CFS-L04-1315-T09-A 1 8.00E+01
Ni CFS-L04-1315-T01-B 1 4.00E+00 E
Ni CFS-L04-1315-T02-B 1 1.40E+01
Ni CFS-L04-1315-T03-B 1 1.48E+01
Ni CFS-L04-1315-T04-B 1 3.84E+01
Ni CFS-L04-1315-T05-B 1 5.17E+01
Ni CFS-L04-1315-T06-B 1 7.99E+01
Ni CFS-L04-1315-T07-B 1 7.15E+01
Ni CFS-L04-1315-T08-B 1 3.65E+01
Ni CFS-L04-1315-T09-B 1 7.33E+01
Ni CFS-L04-1315-T01-C 1 4.30E+00 E
Ni CFS-L04-1315-T02-C 1 1.47E+01
Ni CFS-L04-1315-T03-C 1 1.48E+01
Ni CFS-L04-1315-T04-C 1 4.41 E+01
Ni CFS-L04-1315-T05-C 1 5.07E+01
Ni CFS-L04-1315-T06-C 1 8.45E+01
Ni CFS-L04-1315-T07-C 1 7.63E+01
Ni CFS-L04-1315-T08-C 1 4.05E+01
Ni CFS-L04-1315-T09-C 1 8.16E+01
Ni CFS-L04-1315-M01-A 1 9.00E-01 U1/2
Ni CFS-L04-1315-M02-A 1 9.00E-01 U1/2
Ni CFS-L04-1315-M03-A 1 9.00E-01 U1/2
Ni CFS-L04-1315-M04-A 1 9.00E-01 U1/2
Ni CFS-L04-1315-M05-A 1 9.00E-01 U1/2
Ni CFS-L04-1315-M06-A 1 9.00E-01 U1/2
Ni CFS-L04-1315-M07-A 1 9.00E-01 U1/2
Ni CFS-L04-1315-M08-A 1 9.00E-01 U1/2
Ni CFS-L04-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.18E+00 7.07 1.80 5.70
1.49E+01 4.29 1.80 5.70
1.48E+01 1.94 1.80 5.70 10000 1000
3.79E+01 3.42 1.80 5.70
5.05E+01 1.32 1.80 5.70
8.16E+01 1.42 1.80 5.70
7.63E+01 1.50 1.80 5.70
3.76E+01 5.32 1.80 5.70
8.00E+01 1.54 1.80 5.70
4.00E+00 20.35 1.80 5.70
1.40E+01 2.60 1.80 5.70
1.48E+01 5.53 1.80 5.70 10000 1000
3.84E+01 1.72 1.80 5.70
5.17E+01 0.30 1.80 5.70
7.99E+01 2.98 1.80 5.70
7.15E+01 6.36 1.80 5.70
3.65E+01 2.20 1.80 5.70
7.33E+01 7.30 1.80 5.70
4.30E+00 3.47 1.80 5.70
1.47E+01 1.37 1.80 5.70
1.48E+01 2.41 1.80 5.70 10000 1000
4.41 E+01 0.92 1.80 5.70
5.07E+01 1.73 1.80 5.70
8.45E+01 0.61 1.80 5.70
7.63E+01 4.23 1.80 5.70
4.05E+01 3.23 1.80 5.70
8.16E+01 2.22 1.80 5.70
9.00E-01 4.68 1.80 5.70
9.00E-01 54.22 1.80 5.70
9.00E-01 38.82 1.80 5.70
9.00E-01 37.57 1.80 5.70
9.00E-01 19.35 1.80 5.70
9.00E-01 27.65 1.80 5.70
9.00E-01 56.71 1.80 5.70
9.00E-01 50.05 1.80 5.70
9.00E-01 28.02 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-804
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
P CFS-L04-1315-T01-A 1 1.85E+00 U1/2
P CFS-L04-1315-T02-A 1 8.42E+00 E
P CFS-L04-1315-T03-A 1 9.53E+00 E
P CFS-L04-1315-T04-A 1 5.54E+00 E
P CFS-L04-1315-T05-A 1 1.41E+01
P CFS-L04-1315-T06-A 1 9.94E+00 E
P CFS-L04-1315-T07-A 1 1.26E+01
P CFS-L04-1315-T08-A 1 1.31E+01
P CFS-L04-1315-T09-A 1 1.24E+01
P CFS-L04-1315-T01-B 1 1.85E+00 U1/2
P CFS-L04-1315-T02-B 1 8.82E+00 E
P CFS-L04-1315-T03-B 1 1.05E+01 E
P CFS-L04-1315-T04-B 1 5.60E+00 E
P CFS-L04-1315-T05-B 1 1.70E+01
P CFS-L04-1315-T06-B 1 1.29E+01
P CFS-L04-1315-T07-B 1 1.35E+01
P CFS-L04-1315-T08-B 1 1.30E+01
P CFS-L04-1315-T09-B 1 1.07E+01 E
P CFS-L04-1315-T01-C 1 1.85E+00 U1/2
P CFS-L04-1315-T02-C 1 8.53E+00 E
P CFS-L04-1315-T03-C 1 9.59E+00 E
P CFS-L04-1315-T04-C 1 6.02E+00 E
P CFS-L04-1315-T05-C 1 7.94E+00 E
P CFS-L04-1315-T06-C 1 1.12E+01 E
P CFS-L04-1315-T07-C 1 1.04E+01 E
P CFS-L04-1315-T08-C 1 1.17E+01 E
P CFS-L04-1315-T09-C 1 1.30E+01
P CFS-L04-1315-M01-A 1 1.85E+00 U1/2
P CFS-L04-1315-M02-A 1 1.85E+00 U1/2
P CFS-L04-1315-M03-A 1 1.85E+00 U1/2
P CFS-L04-1315-M04-A 1 1.85E+00 U1/2
P CFS-L04-1315-M05-A 1 1.85E+00 U1/2
P CFS-L04-1315-M06-A 1 1.85E+00 U1/2
P CFS-L04-1315-M07-A 1 1.85E+00 U1/2
P CFS-L04-1315-M08-A 1 1.85E+00 U1/2
P CFS-L04-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 35.70 3.70 11.80
8.42E+00 7.78 3.70 11.80
9.53E+00 2.79 3.70 11.80 10000 1000
5.54E+00 26.10 3.70 11.80
1.41E+01 5.93 3.70 11.80
9.94E+00 5.67 3.70 11.80
1.26E+01 2.22 3.70 11.80
1.31E+01 2.98 3.70 11.80
1.24E+01 9.99 3.70 11.80
1.85E+00 11.26 3.70 11.80
8.82E+00 0.36 3.70 11.80
1.05E+01 24.75 3.70 11.80 10000 1000
5.60E+00 13.46 3.70 11.80
1.70E+01 2.55 3.70 11.80
1.29E+01 18.73 3.70 11.80
1.35E+01 9.99 3.70 11.80
1.30E+01 5.14 3.70 11.80
1.07E+01 6.24 3.70 11.80
1.85E+00 38.07 3.70 11.80
8.53E+00 1.97 3.70 11.80
9.59E+00 22.34 3.70 11.80 10000 1000
6.02E+00 30.27 3.70 11.80
7.94E+00 12.22 3.70 11.80
1.12E+01 18.26 3.70 11.80
1.04E+01 32.35 3.70 11.80
1.17E+01 25.69 3.70 11.80
1.30E+01 14.81 3.70 11.80
1.85E+00 59.83 3.70 11.80
1.85E+00 23.08 3.70 11.80
1.85E+00 14.50 3.70 11.80
1.85E+00 7.13 3.70 11.80
1.85E+00 35.50 3.70 11.80
1.85E+00 25.57 3.70 11.80
1.85E+00 33.73 3.70 11.80
1.85E+00 41.26 3.70 11.80
1.85E+00 39.75 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 131 5 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 131 5 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 131 5 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-805
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
K CFS-L04-1315-T01-A 1 4.48E+02
K CFS-L04-1315-T02-A 1 1.83E+03
K CFS-L04-1315-T03-A 1 1.61E+03
K CFS-L04-1315-T04-A 1 5.31 E+03
K CFS-L04-1315-T05-A 1 6.52E+03
K CFS-L04-1315-T06-A 1 9.58E+03
K CFS-L04-1315-T07-A 1 7.18E+03
K CFS-L04-1315-T08-A 1 2.59E+03
K CFS-L04-1315-T09-A 1 6.68E+03
K CFS-L04-1315-T01-B 1 4.47E+02
K CFS-L04-1315-T02-B 1 1.85E+03
K CFS-L04-1315-T03-B 1 1.61 E+03
K CFS-L04-1315-T04-B 1 5.38E+03
K CFS-L04-1315-T05-B 1 6.79E+03
K CFS-L04-1315-T06-B 1 9.78E+03
K CFS-L04-1315-T07-B 1 7.36E+03
K CFS-L04-1315-T08-B 1 2.65E+03
K CFS-L04-1315-T09-B 1 6.57E+03
K CFS-L04-1315-T01-C 1 4.80E+02
K CFS-L04-1315-T02-C 1 1.94E+03
K CFS-L04-1315-T03-C 1 1.62E+03
K CFS-L04-1315-T04-C 1 5.66E+03
K CFS-L04-1315-T05-C 1 6.31 E+03
K CFS-L04-1315-T06-C 1 9.57E+03
K CFS-L04-1315-T07-C 1 7.21E+03
K CFS-L04-1315-T08-C 1 2.71E+03
K CFS-L04-1315-T09-C 1 6.84E+03
K CFS-L04-1315-M01-A 1 3.81 E+01
K CFS-L04-1315-M02-A 1 3.62E+01
K CFS-L04-1315-M03-A 1 2.70E+01
K CFS-L04-1315-M04-A 1 3.19E+01
K CFS-L04-1315-M05-A 1 2.63E+01
K CFS-L04-1315-M06-A 1 2.50E+01
K CFS-L04-1315-M07-A 1 2.37E+01
K CFS-L04-1315-M08-A 1 2.25E+01
K CFS-L04-1315-M09-A 1 2.12E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.48E+02 1.09 1.60 5.09
1.83E+03 5.64 1.60 5.09
1.61 E+03 1.90 1.60 5.09 10000 1000
5.31 E+03 2.93 1.60 5.09
6.52E+03 1.56 1.60 5.09
9.58E+03 2.47 1.60 5.09
7.18E+03 0.79 1.60 5.09
2.59E+03 2.11 1.60 5.09
6.68E+03 1.99 1.60 5.09
4.47E+02 2.59 1.60 5.09
1.85E+03 0.69 1.60 5.09
1.61 E+03 1.07 1.60 5.09 10000 1000
5.38E+03 1.98 1.60 5.09
6.79E+03 0.20 1.60 5.09
9.78E+03 0.17 1.60 5.09
7.36E+03 2.86 1.60 5.09
2.65E+03 1.36 1.60 5.09
6.57E+03 1.25 1.60 5.09
4.80E+02 2.05 1.60 5.09
1.94E+03 0.13 1.60 5.09
1.62E+03 1.54 1.60 5.09 10000 1000
5.66E+03 0.67 1.60 5.09
6.31 E+03 0.28 1.60 5.09
9.57E+03 0.44 1.60 5.09
7.21 E+03 0.38 1.60 5.09
2.71 E+03 1.85 1.60 5.09
6.84E+03 2.04 1.60 5.09
3.81 E+01 7.24 1.60 5.09
3.62E+01 4.69 1.60 5.09
2.70E+01 6.94 1.60 5.09
3.19E+01 8.58 1.60 5.09
2.63E+01 9.72 1.60 5.09
2.50E+01 11.64 1.60 5.09
2.37E+01 5.65 1.60 5.09
2.25E+01 4.83 1.60 5.09
2.12E+01 6.79 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.54E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.60E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.59E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-806
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Se CFS-L04-1315-T01-A 1 1.81E+01 E
Se CFS-L04-1315-T02-A 1 2.31 E+01 E
Se CFS-L04-1315-T03-A 1 2.93E+01 E
Se CFS-L04-1315-T04-A 1 4.95E+01
Se CFS-L04-1315-T05-A 1 7.10E+01
Se CFS-L04-1315-T06-A 1 9.33E+01
Se CFS-L04-1315-T07-A 1 7.89E+01
Se CFS-L04-1315-T08-A 1 3.13E+01 E
Se CFS-L04-1315-T09-A 1 4.95E+01
Se CFS-L04-1315-T01-B 1 1.88E+01 E
Se CFS-L04-1315-T02-B 1 2.68E+01 E
Se CFS-L04-1315-T03-B 1 2.37E+01 E
Se CFS-L04-1315-T04-B 1 5.02E+01
Se CFS-L04-1315-T05-B 1 8.00E+01
Se CFS-L04-1315-T06-B 1 9.71E+01
Se CFS-L04-1315-T07-B 1 6.98E+01
Se CFS-L04-1315-T08-B 1 2.56E+01 E
Se CFS-L04-1315-T09-B 1 4.82E+01
Se CFS-L04-1315-T01-C 1 1.96E+01 E
Se CFS-L04-1315-T02-C 1 2.52E+01 E
Se CFS-L04-1315-T03-C 1 3.42E+01 E
Se CFS-L04-1315-T04-C 1 6.13E+01
Se CFS-L04-1315-T05-C 1 6.92E+01
Se CFS-L04-1315-T06-C 1 1.10E+02
Se CFS-L04-1315-T07-C 1 7.20E+01
Se CFS-L04-1315-T08-C 1 2.90E+01 E
Se CFS-L04-1315-T09-C 1 3.89E+01 E
Se CFS-L04-1315-M01-A 1 7.50E+00 U1/2
Se CFS-L04-1315-M02-A 1 7.50E+00 U1/2
Se CFS-L04-1315-M03-A 1 7.50E+00 U1/2
Se CFS-L04-1315-M04-A 1 7.50E+00 U1/2
Se CFS-L04-1315-M05-A 1 7.50E+00 U1/2
Se CFS-L04-1315-M06-A 1 7.50E+00 U1/2
Se CFS-L04-1315-M07-A 1 7.50E+00 U1/2
Se CFS-L04-1315-M08-A 1 7.50E+00 U1/2
Se CFS-L04-1315-M09-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.81E+01 31.29 15.00 47.70
2.31E+01 17.30 15.00 47.70
2.93E+01 4.40 15.00 47.70 10000 1000
4.95E+01 0.88 15.00 47.70
7.10E+01 1.31 15.00 47.70
9.33E+01 1.62 15.00 47.70
7.89E+01 1.61 15.00 47.70
3.13E+01 14.77 15.00 47.70
4.95E+01 3.35 15.00 47.70
1.88E+01 17.88 15.00 47.70
2.68E+01 7.99 15.00 47.70
2.37E+01 14.85 15.00 47.70 10000 1000
5.02E+01 5.26 15.00 47.70
8.00E+01 7.45 15.00 47.70
9.71E+01 6.72 15.00 47.70
6.98E+01 10.38 15.00 47.70
2.56E+01 18.85 15.00 47.70
4.82E+01 2.96 15.00 47.70
1.96E+01 3.38 15.00 47.70
2.52E+01 0.25 15.00 47.70
3.42E+01 9.77 15.00 47.70 10000 1000
6.13E+01 1.45 15.00 47.70
6.92E+01 2.92 15.00 47.70
1.10E+02 12.31 15.00 47.70
7.20E+01 1.97 15.00 47.70
2.90E+01 17.09 15.00 47.70
3.89E+01 9.82 15.00 47.70
7.50E+00 37.22 15.00 47.70
7.50E+00 41.64 15.00 47.70
7.50E+00 33.53 15.00 47.70
7.50E+00 47.83 15.00 47.70
7.50E+00 40.88 15.00 47.70
7.50E+00 15.18 15.00 47.70
7.50E+00 22.15 15.00 47.70
7.50E+00 36.28 15.00 47.70
7.50E+00 31.71 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-807
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Si CFS-L04-1315-T01-A 1 6.16E+01
Si CFS-L04-1315-T02-A 1 2.53E+02
Si CFS-L04-1315-T03-A 1 3.09E+02
Si CFS-L04-1315-T04-A 1 6.70E+02
Si CFS-L04-1315-T05-A 1 9.41 E+02
Si CFS-L04-1315-T06-A 1 1.52E+03
Si CFS-L04-1315-T07-A 1 1.53E+03
Si CFS-L04-1315-T08-A 1 8.71E+02
Si CFS-L04-1315-T09-A 1 1.69E+03
Si CFS-L04-1315-T01-B 1 6.74E+01
Si CFS-L04-1315-T02-B 1 2.70E+02
Si CFS-L04-1315-T03-B 1 2.75E+02
Si CFS-L04-1315-T04-B 1 6.80E+02
Si CFS-L04-1315-T05-B 1 9.68E+02
Si CFS-L04-1315-T06-B 1 1.55E+03
Si CFS-L04-1315-T07-B 1 1.54E+03
Si CFS-L04-1315-T08-B 1 8.67E+02
Si CFS-L04-1315-T09-B 1 1.64E+03
Si CFS-L04-1315-T01-C 1 6.17E+01
Si CFS-L04-1315-T02-C 1 2.70E+02
Si CFS-L04-1315-T03-C 1 2.57E+02
Si CFS-L04-1315-T04-C 1 7.03E+02
Si CFS-L04-1315-T05-C 1 8.59E+02
Si CFS-L04-1315-T06-C 1 1.54E+03
Si CFS-L04-1315-T07-C 1 1.55E+03
Si CFS-L04-1315-T08-C 1 9.41 E+02
Si CFS-L04-1315-T09-C 1 1.75E+03
Si CFS-L04-1315-M01-A 1 5.50E-01 U1/2
Si CFS-L04-1315-M02-A 1 5.50E-01 U1/2
Si CFS-L04-1315-M03-A 1 5.50E-01 U1/2
Si CFS-L04-1315-M04-A 1 5.50E-01 U1/2
Si CFS-L04-1315-M05-A 1 5.50E-01 U1/2
Si CFS-L04-1315-M06-A 1 5.50E-01 U1/2
Si CFS-L04-1315-M07-A 1 5.50E-01 U1/2
Si CFS-L04-1315-M08-A 1 5.50E-01 U1/2
Si CFS-L04-1315-M09-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.16E+01 1.23 1.10 3.50
2.53E+02 1.13 1.10 3.50
3.09E+02 1.69 1.10 3.50 10000 1000
6.70E+02 2.33 1.10 3.50
9.41 E+02 1.37 1.10 3.50
1.52E+03 2.72 1.10 3.50
1.53E+03 1.30 1.10 3.50
8.71 E+02 2.03 1.10 3.50
1.69E+03 1.57 1.10 3.50
6.74E+01 2.98 1.10 3.50
2.70E+02 0.92 1.10 3.50
2.75E+02 3.00 1.10 3.50 10000 1000
6.80E+02 5.55 1.10 3.50
9.68E+02 0.37 1.10 3.50
1.55E+03 0.22 1.10 3.50
1.54E+03 2.98 1.10 3.50
8.67E+02 2.28 1.10 3.50
1.64E+03 1.34 1.10 3.50
6.17E+01 1.75 1.10 3.50
2.70E+02 0.76 1.10 3.50
2.57E+02 2.69 1.10 3.50 10000 1000
7.03E+02 0.84 1.10 3.50
8.59E+02 0.39 1.10 3.50
1.54E+03 0.87 1.10 3.50
1.55E+03 1.08 1.10 3.50
9.41 E+02 1.81 1.10 3.50
1.75E+03 2.13 1.10 3.50
5.50E-01 4.63 1.10 3.50
5.50E-01 3.39 1.10 3.50
5.50E-01 5.25 1.10 3.50
5.50E-01 9.57 1.10 3.50
5.50E-01 7.29 1.10 3.50
5.50E-01 7.08 1.10 3.50
5.50E-01 5.70 1.10 3.50
5.50E-01 9.79 1.10 3.50
5.50E-01 1.55 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.27E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.30E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.30E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-808
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Na CFS-L04-1315-T01-A 1 1.50E+03
Na CFS-L04-1315-T02-A 1 5.82E+03
Na CFS-L04-1315-T03-A 1 5.61 E+03
Na CFS-L04-1315-T04-A 1 2.12E+04
Na CFS-L04-1315-T05-A 1 2.33E+04
Na CFS-L04-1315-T06-A 1 3.09E+04
Na CFS-L04-1315-T07-A 1 1.94E+04
Na CFS-L04-1315-T08-A 1 4.88E+03
Na CFS-L04-1315-T09-A 1 1.50E+04
Na CFS-L04-1315-T01-B 1 1.37E+03
Na CFS-L04-1315-T02-B 1 6.58E+03
Na CFS-L04-1315-T03-B 1 5.59E+03
Na CFS-L04-1315-T04-B 1 2.15E+04
Na CFS-L04-1315-T05-B 1 2.39E+04
Na CFS-L04-1315-T06-B 1 3.13E+04
Na CFS-L04-1315-T07-B 1 1.99E+04
Na CFS-L04-1315-T08-B 1 5.07E+03
Na CFS-L04-1315-T09-B 1 1.52E+04
Na CFS-L04-1315-T01-C 1 1.64E+03
Na CFS-L04-1315-T02-C 1 7.19E+03
Na CFS-L04-1315-T03-C 1 6.09E+03
Na CFS-L04-1315-T04-C 1 2.08E+04
Na CFS-L04-1315-T05-C 1 2.23E+04
Na CFS-L04-1315-T06-C 1 3.01 E+04
Na CFS-L04-1315-T07-C 1 2.00E+04
Na CFS-L04-1315-T08-C 1 5.38E+03
Na CFS-L04-1315-T09-C 1 1.63E+04
Na CFS-L04-1315-M01-A 1 1.32E+01
Na CFS-L04-1315-M02-A 1 4.63E+00 E
Na CFS-L04-1315-M03-A 1 6.37E+00 E
Na CFS-L04-1315-M04-A 1 5.83E+00 E
Na CFS-L04-1315-M05-A 1 1.21E+01
Na CFS-L04-1315-M06-A 1 1.47E+01
Na CFS-L04-1315-M07-A 1 1.19E+01
Na CFS-L04-1315-M08-A 1 1.26E+01
Na CFS-L04-1315-M09-A 1 6.85E+00 E
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.50E+03 0.13 2.50 8.00
5.82E+03 2.08 2.50 8.00
5.61E+03 1.43 2.50 8.00 10000 1000
2.12E+04 1.13 2.50 8.00
2.33E+04 0.10 2.50 8.00
3.09E+04 0.84 2.50 8.00
1.94E+04 0.52 2.50 8.00
4.88E+03 0.77 2.50 8.00
1.50E+04 0.49 2.50 8.00
1.37E+03 0.33 2.50 8.00
6.58E+03 0.41 2.50 8.00
5.59E+03 0.24 2.50 8.00 10000 1000
2.15E+04 0.88 2.50 8.00
2.39E+04 1.25 2.50 8.00
3.13E+04 0.47 2.50 8.00
1.99E+04 0.11 2.50 8.00
5.07E+03 0.38 2.50 8.00
1.52E+04 0.55 2.50 8.00
1.64E+03 0.81 2.50 8.00
7.19E+03 0.63 2.50 8.00
6.09E+03 0.21 2.50 8.00 10000 1000
2.08E+04 0.19 2.50 8.00
2.23E+04 0.73 2.50 8.00
3.01 E+04 0.40 2.50 8.00
2.00E+04 0.41 2.50 8.00
5.38E+03 0.09 2.50 8.00
1.63E+04 0.70 2.50 8.00
1.32E+01 0.63 2.50 8.00
4.63E+00 2.15 2.50 8.00
6.37E+00 1.48 2.50 8.00
5.83E+00 1.84 2.50 8.00
1.21E+01 3.00 2.50 8.00
1.47E+01 0.73 2.50 8.00
1.19E+01 1.97 2.50 8.00
1.26E+01 1.67 2.50 8.00
6.85E+00 1.35 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.52E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.52E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.02E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 131 5 CFS
1 0/1 0/1 1 3:33 PM EPA Interlab L04 1 31 5 CFS
1 0/1 0/1 1 3:34 PM EPA Interlab L04 1 31 5 CFS
1 0/1 0/1 1 3:36 PM EPA Interlab L04 1 31 5 CFS
1-809
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
Sr CFS-L04-1315-T01-A 1 5.03E+01
Sr CFS-L04-1315-T02-A 1 1.47E+02
Sr CFS-L04-1315-T03-A 1 1.67E+02
Sr CFS-L04-1315-T04-A 1 3.53E+02
Sr CFS-L04-1315-T05-A 1 4.19E+02
Sr CFS-L04-1315-T06-A 1 6.48E+02
Sr CFS-L04-1315-T07-A 1 6.30E+02
Sr CFS-L04-1315-T08-A 1 3.66E+02
Sr CFS-L04-1315-T09-A 1 7.18E+02
Sr CFS-L04-1315-T01-B 1 5.39E+01
Sr CFS-L04-1315-T02-B 1 1.44E+02
Sr CFS-L04-1315-T03-B 1 1.50E+02
Sr CFS-L04-1315-T04-B 1 3.58E+02
Sr CFS-L04-1315-T05-B 1 4.63E+02
Sr CFS-L04-1315-T06-B 1 6.86E+02
Sr CFS-L04-1315-T07-B 1 6.56E+02
Sr CFS-L04-1315-T08-B 1 3.73E+02
Sr CFS-L04-1315-T09-B 1 7.10E+02
Sr CFS-L04-1315-T01-C 1 4.49E+01
Sr CFS-L04-1315-T02-C 1 1.37E+02
Sr CFS-L04-1315-T03-C 1 1.37E+02
Sr CFS-L04-1315-T04-C 1 3.61 E+02
Sr CFS-L04-1315-T05-C 1 3.87E+02
Sr CFS-L04-1315-T06-C 1 6.57E+02
Sr CFS-L04-1315-T07-C 1 6.49E+02
Sr CFS-L04-1315-T08-C 1 3.90E+02
Sr CFS-L04-1315-T09-C 1 7.39E+02
Sr CFS-L04-1315-M01-A 1 5.00E-01 U1/2
Sr CFS-L04-1315-M02-A 1 5.00E-01 U1/2
Sr CFS-L04-1315-M03-A 1 5.00E-01 U1/2
Sr CFS-L04-1315-M04-A 1 5.00E-01 U1/2
Sr CFS-L04-1315-M05-A 1 5.00E-01 U1/2
Sr CFS-L04-1315-M06-A 1 5.00E-01 U1/2
Sr CFS-L04-1315-M07-A 1 5.00E-01 U1/2
Sr CFS-L04-1315-M08-A 1 5.00E-01 U1/2
Sr CFS-L04-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.03E+01 1.76 1.00 3.18
1.47E+02 3.86 1.00 3.18
1.67E+02 1.40 1.00 3.18 10000 1000
3.53E+02 2.72 1.00 3.18
4.19E+02 1.19 1.00 3.18
6.48E+02 1.02 1.00 3.18
6.30E+02 1.22 1.00 3.18
3.66E+02 2.28 1.00 3.18
7.18E+02 2.24 1.00 3.18
5.39E+01 2.30 1.00 3.18
1.44E+02 0.76 1.00 3.18
1.50E+02 1.41 1.00 3.18 10000 1000
3.58E+02 1.72 1.00 3.18
4.63E+02 1.00 1.00 3.18
6.86E+02 1.07 1.00 3.18
6.56E+02 2.91 1.00 3.18
3.73E+02 1.33 1.00 3.18
7.10E+02 1.37 1.00 3.18
4.49E+01 1.92 1.00 3.18
1.37E+02 1.75 1.00 3.18
1.37E+02 3.16 1.00 3.18 10000 1000
3.61E+02 1.17 1.00 3.18
3.87E+02 1.68 1.00 3.18
6.57E+02 1.63 1.00 3.18
6.49E+02 1.14 1.00 3.18
3.90E+02 1.58 1.00 3.18
7.39E+02 2.26 1.00 3.18
5.00E-01 44.66 1.00 3.18
5.00E-01 16.13 1.00 3.18
5.00E-01 37.45 1.00 3.18
5.00E-01 58.62 1.00 3.18
5.00E-01 20.64 1.00 3.18
5.00E-01 27.64 1.00 3.18
5.00E-01 32.58 1.00 3.18
5.00E-01 41.64 1.00 3.18
5.00E-01 12.08 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.14E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-810
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
S CFS-L04-1315-T01-A 1 1.97E+04
S CFS-L04-1315-T02-A 1 5.02E+04
S CFS-L04-1315-T03-A 1 5.90E+04
S CFS-L04-1315-T04-A 1 1.23E+05
S CFS-L04-1315-T05-A 1 1.50E+05
S CFS-L04-1315-T06-A 1 2.22E+05
S CFS-L04-1315-T07-A 1 2.05E+05
S CFS-L04-1315-T08-A 1 9.80E+04
S CFS-L04-1315-T09-A 1 2.15E+05
S CFS-L04-1315-T01-B 1 2.25E+04
S CFS-L04-1315-T02-B 1 4.77E+04
S CFS-L04-1315-T03-B 1 5.34E+04
S CFS-L04-1315-T04-B 1 1.25E+05
S CFS-L04-1315-T05-B 1 1.66E+05
S CFS-L04-1315-T06-B 1 2.33E+05
S CFS-L04-1315-T07-B 1 2.07E+05
S CFS-L04-1315-T08-B 1 1.00E+05
S CFS-L04-1315-T09-B 1 2.05E+05
S CFS-L04-1315-T01-C 1 1.87E+04
S CFS-L04-1315-T02-C 1 4.70E+04
S CFS-L04-1315-T03-C 1 4.74E+04
S CFS-L04-1315-T04-C 1 1.28E+05
S CFS-L04-1315-T05-C 1 1.35E+05
S CFS-L04-1315-T06-C 1 2.25E+05
S CFS-L04-1315-T07-C 1 2.07E+05
S CFS-L04-1315-T08-C 1 1.06E+05
S CFS-L04-1315-T09-C 1 2.29E+05
S CFS-L04-1315-M01-A 1 1.16E+01 E
S CFS-L04-1315-M02-A 1 9.24E+00 E
S CFS-L04-1315-M03-A 1 8.27E+00 E
S CFS-L04-1315-M04-A 1 8.38E+00 E
S CFS-L04-1315-M05-A 1 1.06E+01 E
S CFS-L04-1315-M06-A 1 8.07E+00 E
S CFS-L04-1315-M07-A 1 1.22E+01 E
S CFS-L04-1315-M08-A 1 8.92E+00 E
S CFS-L04-1315-M09-A 1 1.43E+01 E
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.97E+04 1.06 6.80 21.60
5.02E+04 3.84 6.80 21.60
5.90E+04 1.79 6.80 21.60 10000 1000
1.23E+05 6.80 21.60
1.50E+05 1.59 6.80 21.60
2.22E+05 2.41 6.80 21.60
2.05E+05 0.76 6.80 21.60
9.80E+04 2.47 6.80 21.60
2.15E+05 1.84 6.80 21.60
2.25E+04 2.22 6.80 21.60
4.77E+04 0.63 6.80 21.60
5.34E+04 1.10 6.80 21.60 10000 1000
1.25E+05 0.60 6.80 21.60
1.66E+05 0.21 6.80 21.60
2.33E+05 0.11 6.80 21.60
2.07E+05 2.90 6.80 21.60
1.00E+05 1.19 6.80 21.60
2.05E+05 1.38 6.80 21.60
1.87E+04 2.23 6.80 21.60
4.70E+04 0.18 6.80 21.60
4.74E+04 1.25 6.80 21.60 10000 1000
1.28E+05 0.56 6.80 21.60
1.35E+05 0.45 6.80 21.60
2.25E+05 0.54 6.80 21.60
2.07E+05 0.69 6.80 21.60
1.06E+05 2.17 6.80 21.60
2.29E+05 2.35 6.80 21.60
1.16E+01 1.75 6.80 21.60
9.24E+00 1.21 6.80 21.60
8.27E+00 8.56 6.80 21.60
8.38E+00 9.08 6.80 21.60
1.06E+01 1.36 6.80 21.60
8.07E+00 6.32 6.80 21.60
1.22E+01 4.27 6.80 21.60
8.92E+00 2.03 6.80 21.60
1.43E+01 4.74 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.98E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.43E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.83E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-811
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Tl CFS-L04-1315-T01-A 1 1.78E+01
Tl CFS-L04-1315-T02-A 1 7.30E+01
Tl CFS-L04-1315-T03-A 1 6.77E+01
Tl CFS-L04-1315-T04-A 1 1.71E+02
Tl CFS-L04-1315-T05-A 1 2.11E+02
Tl CFS-L04-1315-T06-A 1 2.96E+02
Tl CFS-L04-1315-T07-A 1 2.45E+02
Tl CFS-L04-1315-T08-A 1 1.12E+02
Tl CFS-L04-1315-T09-A 1 2.28E+02
Tl CFS-L04-1315-T01-B 1 1.62E+01
Tl CFS-L04-1315-T02-B 1 6.64E+01
Tl CFS-L04-1315-T03-B 1 6.10E+01
Tl CFS-L04-1315-T04-B 1 1.73E+02
Tl CFS-L04-1315-T05-B 1 2.19E+02
Tl CFS-L04-1315-T06-B 1 3.01 E+02
Tl CFS-L04-1315-T07-B 1 2.47E+02
Tl CFS-L04-1315-T08-B 1 1.12E+02
Tl CFS-L04-1315-T09-B 1 2.25E+02
Tl CFS-L04-1315-T01-C 1 1.52E+01
Tl CFS-L04-1315-T02-C 1 7.04E+01
Tl CFS-L04-1315-T03-C 1 6.37E+01
Tl CFS-L04-1315-T04-C 1 1.74E+02
Tl CFS-L04-1315-T05-C 1 2.04E+02
Tl CFS-L04-1315-T06-C 1 3.00E+02
Tl CFS-L04-1315-T07-C 1 2.48E+02
Tl CFS-L04-1315-T08-C 1 1.21E+02
Tl CFS-L04-1315-T09-C 1 2.38E+02
Tl CFS-L04-1315-M01-A 1 2.30E+00 U1/2
Tl CFS-L04-1315-M02-A 1 2.30E+00 U1/2
Tl CFS-L04-1315-M03-A 1 2.30E+00 U1/2
Tl CFS-L04-1315-M04-A 1 2.30E+00 U1/2
Tl CFS-L04-1315-M05-A 1 2.30E+00 U1/2
Tl CFS-L04-1315-M06-A 1 2.30E+00 U1/2
Tl CFS-L04-1315-M07-A 1 2.30E+00 U1/2
Tl CFS-L04-1315-M08-A 1 2.30E+00 U1/2
Tl CFS-L04-1315-M09-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.78E+01 4.42 4.60 14.60
7.30E+01 2.12 4.60 14.60
6.77E+01 2.58 4.60 14.60 10000 1000
1.71E+02 1.49 4.60 14.60
2.11E+02 2.18 4.60 14.60
2.96E+02 1.97 4.60 14.60
2.45E+02 3.70 4.60 14.60
1.12E+02 1.09 4.60 14.60
2.28E+02 4.74 4.60 14.60
1.62E+01 0.97 4.60 14.60
6.64E+01 7.40 4.60 14.60
6.10E+01 14.24 4.60 14.60 10000 1000
1.73E+02 6.02 4.60 14.60
2.19E+02 1.87 4.60 14.60
3.01E+02 0.14 4.60 14.60
2.47E+02 4.51 4.60 14.60
1.12E+02 2.45 4.60 14.60
2.25E+02 2.70 4.60 14.60
1.52E+01 3.87 4.60 14.60
7.04E+01 1.46 4.60 14.60
6.37E+01 2.24 4.60 14.60 10000 1000
1.74E+02 0.37 4.60 14.60
2.04E+02 0.72 4.60 14.60
3.00E+02 2.36 4.60 14.60
2.48E+02 1.69 4.60 14.60
1.21E+02 2.43 4.60 14.60
2.38E+02 4.23 4.60 14.60
2.30E+00 7.62 4.60 14.60
2.30E+00 43.90 4.60 14.60
2.30E+00 101.86 4.60 14.60
2.30E+00 44.63 4.60 14.60
2.30E+00 33.14 4.60 14.60
2.30E+00 38.01 4.60 14.60
2.30E+00 27.42 4.60 14.60
2.30E+00 17.87 4.60 14.60
2.30E+00 19.10 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.07E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-812
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ti CFS-L04-1315-T01-A 1 1.00E+00 U1/2
Ti CFS-L04-1315-T02-A 1 1.00E+00 U1/2
Ti CFS-L04-1315-T03-A 1 1.00E+00 U1/2
Ti CFS-L04-1315-T04-A 1 1.00E+00 U1/2
Ti CFS-L04-1315-T05-A 1 1.00E+00 U1/2
Ti CFS-L04-1315-T06-A 1 1.00E+00 U1/2
Ti CFS-L04-1315-T07-A 1 1.00E+00 U1/2
Ti CFS-L04-1315-T08-A 1 1.00E+00 U1/2
Ti CFS-L04-1315-T09-A 1 1.00E+00 U1/2
Ti CFS-L04-1315-T01-B 1 1.00E+00 U1/2
Ti CFS-L04-1315-T02-B 1 1.00E+00 U1/2
Ti CFS-L04-1315-T03-B 1 1.00E+00 U1/2
Ti CFS-L04-1315-T04-B 1 1.00E+00 U1/2
Ti CFS-L04-1315-T05-B 1 1.00E+00 U1/2
Ti CFS-L04-1315-T06-B 1 1.00E+00 U1/2
Ti CFS-L04-1315-T07-B 1 1.00E+00 U1/2
Ti CFS-L04-1315-T08-B 1 1.00E+00 U1/2
Ti CFS-L04-1315-T09-B 1 1.00E+00 U1/2
Ti CFS-L04-1315-T01-C 1 1.00E+00 U1/2
Ti CFS-L04-1315-T02-C 1 1.00E+00 U1/2
Ti CFS-L04-1315-T03-C 1 1.00E+00 U1/2
Ti CFS-L04-1315-T04-C 1 1.00E+00 U1/2
Ti CFS-L04-1315-T05-C 1 1.00E+00 U1/2
Ti CFS-L04-1315-T06-C 1 1.00E+00 U1/2
Ti CFS-L04-1315-T07-C 1 1.00E+00 U1/2
Ti CFS-L04-1315-T08-C 1 1.00E+00 U1/2
Ti CFS-L04-1315-T09-C 1 1.00E+00 U1/2
Ti CFS-L04-1315-M01-A 1 1.00E+00 U1/2
Ti CFS-L04-1315-M02-A 1 1.00E+00 U1/2
Ti CFS-L04-1315-M03-A 1 1.00E+00 U1/2
Ti CFS-L04-1315-M04-A 1 1.00E+00 U1/2
Ti CFS-L04-1315-M05-A 1 1.00E+00 U1/2
Ti CFS-L04-1315-M06-A 1 1.00E+00 U1/2
Ti CFS-L04-1315-M07-A 1 1.00E+00 U1/2
Ti CFS-L04-1315-M08-A 1 1.00E+00 U1/2
Ti CFS-L04-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 13.00 2.00 6.40
1.00E+00 55.58 2.00 6.40
1.00E+00 2.45 2.00 6.40 10000 1000
1.00E+00 23.12 2.00 6.40
1.00E+00 15.73 2.00 6.40
1.00E+00 45.57 2.00 6.40
1.00E+00 38.81 2.00 6.40
1.00E+00 45.05 2.00 6.40
1.00E+00 15.99 2.00 6.40
1.00E+00 59.70 2.00 6.40
1.00E+00 0.96 2.00 6.40
1.00E+00 32.61 2.00 6.40 10000 1000
1.00E+00 18.36 2.00 6.40
1.00E+00 48.60 2.00 6.40
1.00E+00 51.82 2.00 6.40
1.00E+00 22.57 2.00 6.40
1.00E+00 16.86 2.00 6.40
1.00E+00 9.99 2.00 6.40
1.00E+00 6.16 2.00 6.40
1.00E+00 1.14 2.00 6.40
1.00E+00 23.54 2.00 6.40 10000 1000
1.00E+00 40.87 2.00 6.40
1.00E+00 30.02 2.00 6.40
1.00E+00 48.11 2.00 6.40
1.00E+00 53.38 2.00 6.40
1.00E+00 25.90 2.00 6.40
1.00E+00 28.01 2.00 6.40
1.00E+00 12.59 2.00 6.40
1.00E+00 51.81 2.00 6.40
1.00E+00 67.81 2.00 6.40
1.00E+00 38.87 2.00 6.40
1.00E+00 67.48 2.00 6.40
1.00E+00 12.14 2.00 6.40
1.00E+00 39.72 2.00 6.40
1.00E+00 11.96 2.00 6.40
1.00E+00 9.48 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.44E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.48E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-813
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
V CFS-L04-1315-T01-A 1 2.13E+00 E
V CFS-L04-1315-T02-A 1 3.35E+00 E
V CFS-L04-1315-T03-A 1 4.33E+00 E
V CFS-L04-1315-T04-A 1 5.83E+00
V CFS-L04-1315-T05-A 1 5.76E+00
V CFS-L04-1315-T06-A 1 8.25E+00
V CFS-L04-1315-T07-A 1 8.00E+00
V CFS-L04-1315-T08-A 1 4.84E+00
V CFS-L04-1315-T09-A 1 9.58E+00
V CFS-L04-1315-T01-B 1 1.84E+00 E
V CFS-L04-1315-T02-B 1 2.64E+00 E
V CFS-L04-1315-T03-B 1 4.17E+00 E
V CFS-L04-1315-T04-B 1 5.91E+00
V CFS-L04-1315-T05-B 1 6.75E+00
V CFS-L04-1315-T06-B 1 8.16E+00
V CFS-L04-1315-T07-B 1 7.89E+00
V CFS-L04-1315-T08-B 1 5.02E+00
V CFS-L04-1315-T09-B 1 8.53E+00
V CFS-L04-1315-T01-C 1 1.77E+00 E
V CFS-L04-1315-T02-C 1 3.13E+00 E
V CFS-L04-1315-T03-C 1 3.87E+00 E
V CFS-L04-1315-T04-C 1 5.28E+00
V CFS-L04-1315-T05-C 1 5.86E+00
V CFS-L04-1315-T06-C 1 7.34E+00
V CFS-L04-1315-T07-C 1 7.81E+00
V CFS-L04-1315-T08-C 1 5.30E+00
V CFS-L04-1315-T09-C 1 9.58E+00
V CFS-L04-1315-M01-A 1 7.50E-01 U1/2
V CFS-L04-1315-M02-A 1 7.50E-01 U1/2
V CFS-L04-1315-M03-A 1 7.50E-01 U1/2
V CFS-L04-1315-M04-A 1 7.50E-01 U1/2
V CFS-L04-1315-M05-A 1 7.50E-01 U1/2
V CFS-L04-1315-M06-A 1 7.50E-01 U1/2
V CFS-L04-1315-M07-A 1 7.50E-01 U1/2
V CFS-L04-1315-M08-A 1 7.50E-01 U1/2
V CFS-L04-1315-M09-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.13E+00 10.72 1.50 4.77
3.35E+00 14.44 1.50 4.77
4.33E+00 1.93 1.50 4.77 10000 1000
5.83E+00 4.43 1.50 4.77
5.76E+00 6.29 1.50 4.77
8.25E+00 7.76 1.50 4.77
8.00E+00 5.69 1.50 4.77
4.84E+00 2.35 1.50 4.77
9.58E+00 1.52 1.50 4.77
1.84E+00 20.88 1.50 4.77
2.64E+00 14.17 1.50 4.77
4.17E+00 9.41 1.50 4.77 10000 1000
5.91E+00 3.19 1.50 4.77
6.75E+00 1.72 1.50 4.77
8.16E+00 3.11 1.50 4.77
7.89E+00 1.19 1.50 4.77
5.02E+00 10.45 1.50 4.77
8.53E+00 8.75 1.50 4.77
1.77E+00 4.14 1.50 4.77
3.13E+00 1.26 1.50 4.77
3.87E+00 4.00 1.50 4.77 10000 1000
5.28E+00 3.31 1.50 4.77
5.86E+00 1.41 1.50 4.77
7.34E+00 7.15 1.50 4.77
7.81 E+00 4.29 1.50 4.77
5.30E+00 7.37 1.50 4.77
9.58E+00 9.06 1.50 4.77
7.50E-01 43.24 1.50 4.77
7.50E-01 22.20 1.50 4.77
7.50E-01 25.70 1.50 4.77
7.50E-01 18.45 1.50 4.77
7.50E-01 30.56 1.50 4.77
7.50E-01 20.31 1.50 4.77
7.50E-01 9.95 1.50 4.77
7.50E-01 24.04 1.50 4.77
7.50E-01 7.95 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315 CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 131 5 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 131 5 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 131 5 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-814
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Zn CFS-L04-1315-T01-A 1 4.61E+02
Zn CFS-L04-1315-T02-A 1 1.40E+03
Zn CFS-L04-1315-T03-A 1 1.74E+03
Zn CFS-L04-1315-T04-A 1 3.64E+03
Zn CFS-L04-1315-T05-A 1 4.84E+03
Zn CFS-L04-1315-T06-A 1 7.96E+03
Zn CFS-L04-1315-T07-A 1 7.88E+03
Zn CFS-L04-1315-T08-A 1 4.40E+03
Zn CFS-L04-1315-T09-A 1 8.60E+03
Zn CFS-L04-1315-T01-B 1 4.62E+02
Zn CFS-L04-1315-T02-B 1 1.39E+03
Zn CFS-L04-1315-T03-B 1 1.56E+03
Zn CFS-L04-1315-T04-B 1 3.70E+03
Zn CFS-L04-1315-T05-B 1 4.90E+03
Zn CFS-L04-1315-T06-B 1 7.83E+03
Zn CFS-L04-1315-T07-B 1 7.62E+03
Zn CFS-L04-1315-T08-B 1 4.12E+03
Zn CFS-L04-1315-T09-B 1 8.11E+03
Zn CFS-L04-1315-T01-C 1 4.26E+02
Zn CFS-L04-1315-T02-C 1 1.43E+03
Zn CFS-L04-1315-T03-C 1 1.52E+03
Zn CFS-L04-1315-T04-C 1 3.97E+03
Zn CFS-L04-1315-T05-C 1 4.63E+03
Zn CFS-L04-1315-T06-C 1 7.93E+03
Zn CFS-L04-1315-T07-C 1 8.00E+03
Zn CFS-L04-1315-T08-C 1 4.65E+03
Zn CFS-L04-1315-T09-C 1 8.87E+03
Zn CFS-L04-1315-M01-A 1 5.00E-01 U1/2
Zn CFS-L04-1315-M02-A 1 5.00E-01 U1/2
Zn CFS-L04-1315-M03-A 1 5.00E-01 U1/2
Zn CFS-L04-1315-M04-A 1 5.00E-01 U1/2
Zn CFS-L04-1315-M05-A 1 5.00E-01 U1/2
Zn CFS-L04-1315-M06-A 1 5.00E-01 U1/2
Zn CFS-L04-1315-M07-A 1 5.00E-01 U1/2
Zn CFS-L04-1315-M08-A 1 5.00E-01 U1/2
Zn CFS-L04-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.61E+02 1.58 1.00 3.18
1.40E+03 15.29 1.00 3.18
1.74E+03 1.29 1.00 3.18 10000 1000
3.64E+03 0.93 1.00 3.18
4.84E+03 0.85 1.00 3.18
7.96E+03 2.26 1.00 3.18
7.88E+03 1.21 1.00 3.18
4.40E+03 0.83 1.00 3.18
8.60E+03 1.63 1.00 3.18
4.62E+02 1.85 1.00 3.18
1.39E+03 1.27 1.00 3.18
1.56E+03 1.71 1.00 3.18 10000 1000
3.70E+03 0.34 1.00 3.18
4.90E+03 1.19 1.00 3.18
7.83E+03 1.36 1.00 3.18
7.62E+03 0.87 1.00 3.18
4.12E+03 1.13 1.00 3.18
8.11E+03 1.15 1.00 3.18
4.26E+02 1.09 1.00 3.18
1.43E+03 0.51 1.00 3.18
1.52E+03 2.11 1.00 3.18 10000 1000
3.97E+03 0.88 1.00 3.18
4.63E+03 1.30 1.00 3.18
7.93E+03 1.30 1.00 3.18
8.00E+03 1.57 1.00 3.18
4.65E+03 1.67 1.00 3.18
8.87E+03 1.95 1.00 3.18
5.00E-01 3.63 1.00 3.18
5.00E-01 3.48 1.00 3.18
5.00E-01 11.85 1.00 3.18
5.00E-01 4.17 1.00 3.18
5.00E-01 1.30 1.00 3.18
5.00E-01 11.53 1.00 3.18
5.00E-01 4.54 1.00 3.18
5.00E-01 5.15 1.00 3.18
5.00E-01 7.97 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.66E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.49E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.49E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
10/10/11 3:38 PM EPA Interlab L04 1315 CFS
10/10/11 3:43 PM EPA Interlab L04 1315 CFS
10/10/11 3:47 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 1:12 PM EPA Interlab L04 1315CFS
10/10/11 2:55 PM EPA Interlab L04 1315 CFS
10/10/11 3:00 PM EPA Interlab L04 1315 CFS
10/10/11 3:05 PM EPA Interlab L04 1315 CFS
10/10/11 3:25 PM EPA Interlab L04 1315 CFS
10/10/11 3:39 PM EPA Interlab L04 1315 CFS
10/10/11 3:44 PM EPA Interlab L04 1315 CFS
10/10/11 3:49 PM EPA Interlab L04 1315 CFS
10/10/11 3:59 PM EPA Interlab L04 1315 CFS
10/10/11 1:14 PM EPA Interlab L04 1315 CFS
10/10/11 2:56 PM EPA Interlab L04 1315 CFS
10/10/11 3:01 PM EPA Interlab L04 1315 CFS
10/10/11 3:06 PM EPA Interlab L04 1315 CFS
10/10/11 3:27 PM EPA Interlab L04 1315 CFS
10/10/11 3:41 PM EPA Interlab L04 1315 CFS
10/10/11 3:46 PM EPA Interlab L04 1315 CFS
10/10/11 3:51 PM EPA Interlab L04 1315 CFS
10/10/11 1:10 PM EPA Interlab L04 1315 CFS
10/10/11 1:15 PM EPA Interlab L04 1315 CFS
10/10/11 2:58 PM EPA Interlab L04 1315 CFS
10/10/11 3:03 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:23 PM EPA Interlab L04 1315 CFS
10/10/11 3:24 PM EPA Interlab L04 1315 CFS
10/10/11 3:26 PM EPA Interlab L04 1315 CFS
10/10/11 3:28 PM EPA Interlab L04 1315 CFS
10/10/11 3:29 PM EPA Interlab L04 1315 CFS
10/10/11 3:31 PM EPA Interlab L04 1315 CFS
10/10/11 3:33 PM EPA Interlab L04 1315 CFS
10/10/11 3:34 PM EPA Interlab L04 1315 CFS
10/10/11 3:36 PM EPA Interlab L04 1315 CFS
1-815
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1315:
Element Sample ID
Al CFS-L06-1315-T01-A
Al CFS-L06-1315-T02-A
Al CFS-L06-1315-T03-A
Al CFS-L06-1315-T04-A
Al CFS-L06-1315-T05-A
Al CFS-L06-1315-T06-A
Al CFS-L06-1315-T07-A
Al CFS-L06-1315-T08-A
Al CFS-L06-1315-T09-A
Al CFS-L06-1315-T01-B
Al CFS-L06-1315-T02-B
Al CFS-L06-1315-T03-B
Al CFS-L06-1315-T04-B
Al CFS-L06-1315-T05-B
Al CFS-L06-1315-T06-B
Al CFS-L06-1315-T07-B
Al CFS-L06-1315-T08-B
Al CFS-L06-1315-T09-B
Al CFS-L06-1315-T01-C
Al CFS-L06-1315-T02-C
Al CFS-L06-1315-T03-C
Al CFS-L06-1315-T04-C
Al CFS-L06-1315-T05-C
Al CFS-L06-1315-T06-C
Al CFS-L06-1315-T07-C
Al CFS-L06-1315-T08-C
Al CFS-L06-1315-T09-C
Al CFS-L06-1315-M01-A
Al CFS-L06-1315-M02-A
Al CFS-L06-1315-M03-A
Al CFS-L06-1315-M04-A
Al CFS-L06-1315-M05-A
Al CFS-L06-1315-M06-A
Al CFS-L06-1315-M07-A
Al CFS-L06-1315-M08-A
Al CFS-L06-1315-M09-A
Dilution Sample
Factor Cone. Qualifier
I ug/L I
1 8.36E+00
1 1.70E+01
1 2.29E+01
1 3.00E+01
1 3.56E+01
1 4.24E+01
1 4.79E+01
1 2.98E+01
1 4.08E+01
1 1.01E+01
1 1.71E+01
1 1.93E+01
1 3.09E+01
1 3.66E+01
1 4.31 E+01
1 4.27E+01
1 3.27E+01
1 4.17E+01
1 1.00E+01
1 1.79E+01
1 2.12E+01
1 3.29E+01
1 3.83E+01
1 4.24E+01
1 4.13E+01
1 3.26E+01
1 4.27E+01
1 1.94E+OOE
1 1.21E+OOE
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.36E+00 4.51 1.00 3.18
1.70E+01 9.10 1.00 3.18
2.29E+01 7.15 1.00 3.18 10000 1000
3.00E+01 7.79 1.00 3.18
3.56E+01 5.72 1.00 3.18
4.24E+01 4.92 1.00 3.18
4.79E+01 2.53 1.00 3.18
2.98E+01 4.88 1.00 3.18
4.08E+01 4.45 1.00 3.18
1.01E+01 4.99 1.00 3.18
1.71E+01 7.61 1.00 3.18
1.93E+01 11.92 1.00 3.18 10000 1000
3.09E+01 6.18 1.00 3.18
3.66E+01 4.80 1.00 3.18
4.31E+01 5.12 1.00 3.18
4.27E+01 2.04 1.00 3.18
3.27E+01 6.30 1.00 3.18
4.17E+01 6.07 1.00 3.18
1.00E+01 6.20 1.00 3.18
1.79E+01 7.11 1.00 3.18
2.12E+01 1.86 1.00 3.18 10000 1000
3.29E+01 6.51 1.00 3.18
3.83E+01 1.06 1.00 3.18
4.24E+01 7.55 1.00 3.18
4.13E+01 10.22 1.00 3.18
3.26E+01 9.39 1.00 3.18
4.27E+01 7.13 1.00 3.18
1.94E+00 14.53 1.00 3.18
1.21E+00 27.10 1.00 3.18
5.00E-01 7.69 1.00 3.18
5.00E-01 9.45 1.00 3.18
5.00E-01 11.89 1.00 3.18
5.00E-01 25.54 1.00 3.18
5.00E-01 9.24 1.00 3.18
5.00E-01 13.12 1.00 3.18
5.00E-01 3.02 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-816
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Sb CFS-L06-1315-T01-A 1 8.64E+00 E
Sb CFS-L06-1315-T02-A 1 9.15E+00 E
Sb CFS-L06-1315-T03-A 1 9.53E+00 E
Sb CFS-L06-1315-T04-A 1 1.25E+01 E
Sb CFS-L06-1315-T05-A 1 1.61E+01 E
Sb CFS-L06-1315-T06-A 1 1.23E+01 E
Sb CFS-L06-1315-T07-A 1 9.41E+00 E
Sb CFS-L06-1315-T08-A 1 8.33E+00 E
Sb CFS-L06-1315-T09-A 1 7.69E+00 E
Sb CFS-L06-1315-T01-B 1 8.81E+00 E
Sb CFS-L06-1315-T02-B 1 9.28E+00 E
Sb CFS-L06-1315-T03-B 1 9.71E+00 E
Sb CFS-L06-1315-T04-B 1 1.01E+01 E
Sb CFS-L06-1315-T05-B 1 1.05E+01 E
Sb CFS-L06-1315-T06-B 1 1.41E+01 E
Sb CFS-L06-1315-T07-B 1 7.63E+00 E
Sb CFS-L06-1315-T08-B 1 1.51E+01 E
Sb CFS-L06-1315-T09-B 1 1.04E+01 E
Sb CFS-L06-1315-T01-C 1 7.96E+00 E
Sb CFS-L06-1315-T02-C 1 8.88E+00 E
Sb CFS-L06-1315-T03-C 1 9.15E+00 E
Sb CFS-L06-1315-T04-C 1 9.41E+00 E
Sb CFS-L06-1315-T05-C 1 1.05E+01 E
Sb CFS-L06-1315-T06-C 1 1.16E+01 E
Sb CFS-L06-1315-T07-C 1 8.62E+00 E
Sb CFS-L06-1315-T08-C 1 9.50E+00 E
Sb CFS-L06-1315-T09-C 1 8.28E+00 E
Sb CFS-L06-1315-M01-A 1 3.75E+00 U1/2
Sb CFS-L06-1315-M02-A 1 3.75E+00 U1/2
Sb CFS-L06-1315-M03-A 1 3.75E+00 U1/2
Sb CFS-L06-1315-M04-A 1 3.75E+00 U1/2
Sb CFS-L06-1315-M05-A 1 3.75E+00 U1/2
Sb CFS-L06-1315-M06-A 1 3.75E+00 U1/2
Sb CFS-L06-1315-M07-A 1 3.75E+00 U1/2
Sb CFS-L06-1315-M08-A 1 3.75E+00 U1/2
Sb CFS-L06-1315-M09-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.64E+00 26.57 7.50 23.90
9.15E+00 20.36 7.50 23.90
9.53E+00 6.22 7.50 23.90 10000 1000
1.25E+01 5.85 7.50 23.90
1.61E+01 16.05 7.50 23.90
1.23E+01 7.53 7.50 23.90
9.41E+00 9.15 7.50 23.90
8.33E+00 9.79 7.50 23.90
7.69E+00 13.16 7.50 23.90
8.81 E+00 25.48 7.50 23.90
9.28E+00 7.73 7.50 23.90
9.71E+00 16.49 7.50 23.90 10000 1000
1.01E+01 17.97 7.50 23.90
1.05E+01 5.74 7.50 23.90
1.41E+01 7.84 7.50 23.90
7.63E+00 5.60 7.50 23.90
1.51E+01 26.64 7.50 23.90
1.04E+01 13.07 7.50 23.90
7.96E+00 14.62 7.50 23.90
8.88E+00 4.81 7.50 23.90
9.15E+00 14.61 7.50 23.90 10000 1000
9.41 E+00 5.03 7.50 23.90
1.05E+01 3.66 7.50 23.90
1.16E+01 4.27 7.50 23.90
8.62E+00 14.05 7.50 23.90
9.50E+00 25.11 7.50 23.90
8.28E+00 11.39 7.50 23.90
3.75E+00 44.47 7.50 23.90
3.75E+00 26.00 7.50 23.90
3.75E+00 37.37 7.50 23.90
3.75E+00 21.61 7.50 23.90
3.75E+00 40.66 7.50 23.90
3.75E+00 25.70 7.50 23.90
3.75E+00 8.33 7.50 23.90
3.75E+00 8.26 7.50 23.90
3.75E+00 11.71 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.98E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.64E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-817
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
As CFS-L06-1315-T01-A 1 5.50E+00 U1/2
As CFS-L06-1315-T02-A 1 5.50E+00 U1/2
As CFS-L06-1315-T03-A 1 1.24E+01 E
As CFS-L06-1315-T04-A 1 1.23E+01 E
As CFS-L06-1315-T05-A 1 1.41E+01 E
As CFS-L06-1315-T06-A 1 1.39E+01 E
As CFS-L06-1315-T07-A 1 1.25E+01 E
As CFS-L06-1315-T08-A 1 5.50E+00 U1/2
As CFS-L06-1315-T09-A 1 5.50E+00 U1/2
As CFS-L06-1315-T01-B 1 5.50E+00 U1/2
As CFS-L06-1315-T02-B 1 5.50E+00 U1/2
As CFS-L06-1315-T03-B 1 1.33E+01 E
As CFS-L06-1315-T04-B 1 1.31E+01 E
As CFS-L06-1315-T05-B 1 1.68E+01 E
As CFS-L06-1315-T06-B 1 1.15E+01 E
As CFS-L06-1315-T07-B 1 1.28E+01 E
As CFS-L06-1315-T08-B 1 5.50E+00 U1/2
As CFS-L06-1315-T09-B 1 5.50E+00 U1/2
As CFS-L06-1315-T01-C 1 5.50E+00 U1/2
As CFS-L06-1315-T02-C 1 5.50E+00 U1/2
As CFS-L06-1315-T03-C 1 1.23E+01 E
As CFS-L06-1315-T04-C 1 1.25E+01 E
As CFS-L06-1315-T05-C 1 1.48E+01 E
As CFS-L06-1315-T06-C 1 1.52E+01 E
As CFS-L06-1315-T07-C 1 1.30E+01 E
As CFS-L06-1315-T08-C 1 5.50E+00 U1/2
As CFS-L06-1315-T09-C 1 5.50E+00 U1/2
As CFS-L06-1315-M01-A 1 5.50E+00 U1/2
As CFS-L06-1315-M02-A 1 5.50E+00 U1/2
As CFS-L06-1315-M03-A 1 5.50E+00 U1/2
As CFS-L06-1315-M04-A 1 5.50E+00 U1/2
As CFS-L06-1315-M05-A 1 5.50E+00 U1/2
As CFS-L06-1315-M06-A 1 5.50E+00 U1/2
As CFS-L06-1315-M07-A 1 5.50E+00 U1/2
As CFS-L06-1315-M08-A 1 5.50E+00 U1/2
As CFS-L06-1315-M09-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.50E+00 31.99 11.00 35.00
5.50E+00 48.26 11.00 35.00
1.24E+01 9.74 11.00 35.00 10000 1000
1.23E+01 10.11 11.00 35.00
1.41E+01 27.96 11.00 35.00
1.39E+01 23.99 11.00 35.00
1.25E+01 24.41 11.00 35.00
5.50E+00 35.17 11.00 35.00
5.50E+00 9.92 11.00 35.00
5.50E+00 29.25 11.00 35.00
5.50E+00 20.16 11.00 35.00
1.33E+01 25.73 11.00 35.00 10000 1000
1.31E+01 16.94 11.00 35.00
1.68E+01 11.46 11.00 35.00
1.15E+01 14.52 11.00 35.00
1.28E+01 12.77 11.00 35.00
5.50E+00 31.18 11.00 35.00
5.50E+00 13.50 11.00 35.00
5.50E+00 17.39 11.00 35.00
5.50E+00 36.01 11.00 35.00
1.23E+01 39.06 11.00 35.00 10000 1000
1.25E+01 24.93 11.00 35.00
1.48E+01 32.43 11.00 35.00
1.52E+01 20.06 11.00 35.00
1.30E+01 13.21 11.00 35.00
5.50E+00 32.03 11.00 35.00
5.50E+00 16.04 11.00 35.00
5.50E+00 24.18 11.00 35.00
5.50E+00 38.48 11.00 35.00
5.50E+00 34.20 11.00 35.00
5.50E+00 18.27 11.00 35.00
5.50E+00 20.97 11.00 35.00
5.50E+00 17.01 11.00 35.00
5.50E+00 7.67 11.00 35.00
5.50E+00 33.69 11.00 35.00
5.50E+00 24.25 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.87E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.52E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-818
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
B CFS-L06-1315-T01-A 1 9.89E+00
B CFS-L06-1315-T02-A 1 3.20E+01
B CFS-L06-1315-T03-A 1 3.08E+01
B CFS-L06-1315-T04-A 1 9.08E+01
B CFS-L06-1315-T05-A 1 1.15E+02
B CFS-L06-1315-T06-A 1 1.59E+02
B CFS-L06-1315-T07-A 1 1.30E+02
B CFS-L06-1315-T08-A 1 6.19E+01
B CFS-L06-1315-T09-A 1 1.03E+02
B CFS-L06-1315-T01-B 1 1.26E+01
B CFS-L06-1315-T02-B 1 2.36E+01
B CFS-L06-1315-T03-B 1 2.21E+01
B CFS-L06-1315-T04-B 1 7.80E+01
B CFS-L06-1315-T05-B 1 1.02E+02
B CFS-L06-1315-T06-B 1 1.49E+02
B CFS-L06-1315-T07-B 1 1.27E+02
B CFS-L06-1315-T08-B 1 6.21E+01
B CFS-L06-1315-T09-B 1 9.86E+01
B CFS-L06-1315-T01-C 1 1.15E+01
B CFS-L06-1315-T02-C 1 2.41E+01
B CFS-L06-1315-T03-C 1 1.86E+01
B CFS-L06-1315-T04-C 1 7.42E+01
B CFS-L06-1315-T05-C 1 9.35E+01
B CFS-L06-1315-T06-C 1 1.43E+02
B CFS-L06-1315-T07-C 1 1.19E+02
B CFS-L06-1315-T08-C 1 5.50E+01
B CFS-L06-1315-T09-C 1 9.03E+01
B CFS-L06-1315-M01-A 1 5.00E-01 U1/2
B CFS-L06-1315-M02-A 1 5.00E-01 U1/2
B CFS-L06-1315-M03-A 1 5.00E-01 U1/2
B CFS-L06-1315-M04-A 1 5.00E-01 U1/2
B CFS-L06-1315-M05-A 1 5.00E-01 U1/2
B CFS-L06-1315-M06-A 1 5.00E-01 U1/2
B CFS-L06-1315-M07-A 1 5.00E-01 U1/2
B CFS-L06-1315-M08-A 1 5.00E-01 U1/2
B CFS-L06-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.89E+00 3.40 1.00 3.18
3.20E+01 1.27 1.00 3.18
3.08E+01 3.08 1.00 3.18 10000 1000
9.08E+01 1.22 1.00 3.18
1.15E+02 1.73 1.00 3.18
1.59E+02 1.51 1.00 3.18
1.30E+02 2.89 1.00 3.18
6.19E+01 1.82 1.00 3.18
1.03E+02 0.70 1.00 3.18
1.26E+01 3.89 1.00 3.18
2.36E+01 2.29 1.00 3.18
2.21E+01 3.20 1.00 3.18 10000 1000
7.80E+01 2.77 1.00 3.18
1.02E+02 1.63 1.00 3.18
1.49E+02 1.09 1.00 3.18
1.27E+02 1.31 1.00 3.18
6.21E+01 0.98 1.00 3.18
9.86E+01 0.93 1.00 3.18
1.15E+01 4.17 1.00 3.18
2.41E+01 2.30 1.00 3.18
1.86E+01 6.08 1.00 3.18 10000 1000
7.42E+01 0.62 1.00 3.18
9.35E+01 1.17 1.00 3.18
1.43E+02 2.74 1.00 3.18
1.19E+02 2.28 1.00 3.18
5.50E+01 0.88 1.00 3.18
9.03E+01 1.01 1.00 3.18
5.00E-01 5.31 1.00 3.18
5.00E-01 1.83 1.00 3.18
5.00E-01 6.30 1.00 3.18
5.00E-01 0.38 1.00 3.18
5.00E-01 2.84 1.00 3.18
5.00E-01 1.56 1.00 3.18
5.00E-01 8.30 1.00 3.18
5.00E-01 2.92 1.00 3.18
5.00E-01 2.66 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.61 E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.50E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.92E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-819
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Ba CFS-L06-1315-T01-A 1 2.07E+01
Ba CFS-L06-1315-T02-A 1 2.38E+01
Ba CFS-L06-1315-T03-A 1 2.63E+01
Ba CFS-L06-1315-T04-A 1 2.92E+01
Ba CFS-L06-1315-T05-A 1 3.10E+01
Ba CFS-L06-1315-T06-A 1 3.69E+01
Ba CFS-L06-1315-T07-A 1 3.33E+01
Ba CFS-L06-1315-T08-A 1 2.89E+01
Ba CFS-L06-1315-T09-A 1 3.40E+01
Ba CFS-L06-1315-T01-B 1 1.99E+01
Ba CFS-L06-1315-T02-B 1 2.22E+01
Ba CFS-L06-1315-T03-B 1 2.83E+01
Ba CFS-L06-1315-T04-B 1 3.01 E+01
Ba CFS-L06-1315-T05-B 1 3.02E+01
Ba CFS-L06-1315-T06-B 1 3.43E+01
Ba CFS-L06-1315-T07-B 1 3.43E+01
Ba CFS-L06-1315-T08-B 1 2.94E+01
Ba CFS-L06-1315-T09-B 1 3.45E+01
Ba CFS-L06-1315-T01-C 1 1.73E+01
Ba CFS-L06-1315-T02-C 1 2.20E+01
Ba CFS-L06-1315-T03-C 1 2.56E+01
Ba CFS-L06-1315-T04-C 1 2.90E+01
Ba CFS-L06-1315-T05-C 1 3.29E+01
Ba CFS-L06-1315-T06-C 1 3.41 E+01
Ba CFS-L06-1315-T07-C 1 3.47E+01
Ba CFS-L06-1315-T08-C 1 3.01 E+01
Ba CFS-L06-1315-T09-C 1 3.55E+01
Ba CFS-L06-1315-M01-A 1 5.00E-01 U1/2
Ba CFS-L06-1315-M02-A 1 5.00E-01 U1/2
Ba CFS-L06-1315-M03-A 1 5.00E-01 U1/2
Ba CFS-L06-1315-M04-A 1 5.00E-01 U1/2
Ba CFS-L06-1315-M05-A 1 5.00E-01 U1/2
Ba CFS-L06-1315-M06-A 1 5.00E-01 U1/2
Ba CFS-L06-1315-M07-A 1 5.00E-01 U1/2
Ba CFS-L06-1315-M08-A 1 5.00E-01 U1/2
Ba CFS-L06-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.07E+01 2.91 1.00 3.18
2.38E+01 3.37 1.00 3.18
2.63E+01 4.68 1.00 3.18 10000 1000
2.92E+01 4.18 1.00 3.18
3.10E+01 1.73 1.00 3.18
3.69E+01 3.00 1.00 3.18
3.33E+01 1.26 1.00 3.18
2.89E+01 2.75 1.00 3.18
3.40E+01 0.45 1.00 3.18
1.99E+01 4.43 1.00 3.18
2.22E+01 4.92 1.00 3.18
2.83E+01 1.64 1.00 3.18 10000 1000
3.01E+01 2.49 1.00 3.18
3.02E+01 0.99 1.00 3.18
3.43E+01 1.11 1.00 3.18
3.43E+01 1.72 1.00 3.18
2.94E+01 1.02 1.00 3.18
3.45E+01 0.29 1.00 3.18
1.73E+01 2.57 1.00 3.18
2.20E+01 2.44 1.00 3.18
2.56E+01 4.93 1.00 3.18 10000 1000
2.90E+01 1.51 1.00 3.18
3.29E+01 1.44 1.00 3.18
3.41E+01 1.90 1.00 3.18
3.47E+01 4.79 1.00 3.18
3.01E+01 2.32 1.00 3.18
3.55E+01 0.11 1.00 3.18
5.00E-01 4.37 1.00 3.18
5.00E-01 5.31 1.00 3.18
5.00E-01 33.04 1.00 3.18
5.00E-01 8.20 1.00 3.18
5.00E-01 25.34 1.00 3.18
5.00E-01 15.64 1.00 3.18
5.00E-01 4.54 1.00 3.18
5.00E-01 15.40 1.00 3.18
5.00E-01 15.01 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.94E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.47E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.93E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-820
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Be CFS-L06-1315-T01-A 1 9.50E-01 U1/2
Be CFS-L06-1315-T02-A 1 9.50E-01 U1/2
Be CFS-L06-1315-T03-A 1 9.50E-01 U1/2
Be CFS-L06-1315-T04-A 1 9.50E-01 U1/2
Be CFS-L06-1315-T05-A 1 9.50E-01 U1/2
Be CFS-L06-1315-T06-A 1 9.50E-01 U1/2
Be CFS-L06-1315-T07-A 1 9.50E-01 U1/2
Be CFS-L06-1315-T08-A 1 9.50E-01 U1/2
Be CFS-L06-1315-T09-A 1 9.50E-01 U1/2
Be CFS-L06-1315-T01-B 1 9.50E-01 U1/2
Be CFS-L06-1315-T02-B 1 9.50E-01 U1/2
Be CFS-L06-1315-T03-B 1 9.50E-01 U1/2
Be CFS-L06-1315-T04-B 1 9.50E-01 U1/2
Be CFS-L06-1315-T05-B 1 9.50E-01 U1/2
Be CFS-L06-1315-T06-B 1 9.50E-01 U1/2
Be CFS-L06-1315-T07-B 1 9.50E-01 U1/2
Be CFS-L06-1315-T08-B 1 9.50E-01 U1/2
Be CFS-L06-1315-T09-B 1 9.50E-01 U1/2
Be CFS-L06-1315-T01-C 1 9.50E-01 U1/2
Be CFS-L06-1315-T02-C 1 9.50E-01 U1/2
Be CFS-L06-1315-T03-C 1 9.50E-01 U1/2
Be CFS-L06-1315-T04-C 1 9.50E-01 U1/2
Be CFS-L06-1315-T05-C 1 9.50E-01 U1/2
Be CFS-L06-1315-T06-C 1 9.50E-01 U1/2
Be CFS-L06-1315-T07-C 1 9.50E-01 U1/2
Be CFS-L06-1315-T08-C 1 9.50E-01 U1/2
Be CFS-L06-1315-T09-C 1 9.50E-01 U1/2
Be CFS-L06-1315-M01-A 1 9.50E-01 U1/2
Be CFS-L06-1315-M02-A 1 9.50E-01 U1/2
Be CFS-L06-1315-M03-A 1 9.50E-01 U1/2
Be CFS-L06-1315-M04-A 1 9.50E-01 U1/2
Be CFS-L06-1315-M05-A 1 9.50E-01 U1/2
Be CFS-L06-1315-M06-A 1 9.50E-01 U1/2
Be CFS-L06-1315-M07-A 1 9.50E-01 U1/2
Be CFS-L06-1315-M08-A 1 9.50E-01 U1/2
Be CFS-L06-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 43.23 1.90 6.00
9.50E-01 26.53 1.90 6.00
9.50E-01 23.88 1.90 6.00 10000 1000
9.50E-01 28.60 1.90 6.00
9.50E-01 18.55 1.90 6.00
9.50E-01 13.99 1.90 6.00
9.50E-01 15.18 1.90 6.00
9.50E-01 43.14 1.90 6.00
9.50E-01 65.00 1.90 6.00
9.50E-01 44.66 1.90 6.00
9.50E-01 41.01 1.90 6.00
9.50E-01 36.32 1.90 6.00 10000 1000
9.50E-01 28.11 1.90 6.00
9.50E-01 50.20 1.90 6.00
9.50E-01 35.80 1.90 6.00
9.50E-01 42.01 1.90 6.00
9.50E-01 26.15 1.90 6.00
9.50E-01 25.40 1.90 6.00
9.50E-01 28.39 1.90 6.00
9.50E-01 11.30 1.90 6.00
9.50E-01 7.86 1.90 6.00 10000 1000
9.50E-01 12.83 1.90 6.00
9.50E-01 23.91 1.90 6.00
9.50E-01 6.45 1.90 6.00
9.50E-01 15.04 1.90 6.00
9.50E-01 8.01 1.90 6.00
9.50E-01 11.17 1.90 6.00
9.50E-01 28.77 1.90 6.00
9.50E-01 20.00 1.90 6.00
9.50E-01 18.27 1.90 6.00
9.50E-01 44.47 1.90 6.00
9.50E-01 16.34 1.90 6.00
9.50E-01 8.37 1.90 6.00
9.50E-01 31.55 1.90 6.00
9.50E-01 32.17 1.90 6.00
9.50E-01 13.16 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.99E+02 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.57E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-821
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Cd CFS-L06-1315-T01-A 1 5.32E+01
Cd CFS-L06-1315-T02-A 1 2.69E+02
Cd CFS-L06-1315-T03-A 1 3.03E+02
Cd CFS-L06-1315-T04-A 1 8.16E+02
Cd CFS-L06-1315-T05-A 1 9.97E+02
Cd CFS-L06-1315-T06-A 1 1.43E+03
Cd CFS-L06-1315-T07-A 1 1.22E+03
Cd CFS-L06-1315-T08-A 1 6.26E+02
Cd CFS-L06-1315-T09-A 1 1.04E+03
Cd CFS-L06-1315-T01-B 1 3.71E+01
Cd CFS-L06-1315-T02-B 1 2.63E+02
Cd CFS-L06-1315-T03-B 1 2.81E+02
Cd CFS-L06-1315-T04-B 1 8.08E+02
Cd CFS-L06-1315-T05-B 1 9.99E+02
Cd CFS-L06-1315-T06-B 1 1.42E+03
Cd CFS-L06-1315-T07-B 1 1.27E+03
Cd CFS-L06-1315-T08-B 1 6.81 E+02
Cd CFS-L06-1315-T09-B 1 1.07E+03
Cd CFS-L06-1315-T01-C 1 4.39E+01
Cd CFS-L06-1315-T02-C 1 3.26E+02
Cd CFS-L06-1315-T03-C 1 3.18E+02
Cd CFS-L06-1315-T04-C 1 8.86E+02
Cd CFS-L06-1315-T05-C 1 1.08E+03
Cd CFS-L06-1315-T06-C 1 1.57E+03
Cd CFS-L06-1315-T07-C 1 1.40E+03
Cd CFS-L06-1315-T08-C 1 7.55E+02
Cd CFS-L06-1315-T09-C 1 1.18E+03
Cd CFS-L06-1315-M01-A 1 1.10E+00 U1/2
Cd CFS-L06-1315-M02-A 1 1.10E+00 U1/2
Cd CFS-L06-1315-M03-A 1 1.10E+00 U1/2
Cd CFS-L06-1315-M04-A 1 1.10E+00 U1/2
Cd CFS-L06-1315-M05-A 1 1.10E+00 U1/2
Cd CFS-L06-1315-M06-A 1 1.10E+00 U1/2
Cd CFS-L06-1315-M07-A 1 1.10E+00 U1/2
Cd CFS-L06-1315-M08-A 1 1.10E+00 U1/2
Cd CFS-L06-1315-M09-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.32E+01 1.32 2.20 7.00
2.69E+02 1.90 2.20 7.00
3.03E+02 2.28 2.20 7.00 10000 1000
8.16E+02 2.27 2.20 7.00
9.97E+02 1.25 2.20 7.00
1.43E+03 0.88 2.20 7.00
1.22E+03 1.55 2.20 7.00
6.26E+02 1.07 2.20 7.00
1.04E+03 0.99 2.20 7.00
3.71E+01 1.71 2.20 7.00
2.63E+02 1.12 2.20 7.00
2.81E+02 2.32 2.20 7.00 10000 1000
8.08E+02 2.30 2.20 7.00
9.99E+02 0.66 2.20 7.00
1.42E+03 1.43 2.20 7.00
1.27E+03 0.85 2.20 7.00
6.81E+02 1.10 2.20 7.00
1.07E+03 1.04 2.20 7.00
4.39E+01 0.91 2.20 7.00
3.26E+02 0.73 2.20 7.00
3.18E+02 6.83 2.20 7.00 10000 1000
8.86E+02 0.94 2.20 7.00
1.08E+03 0.57 2.20 7.00
1.57E+03 1.88 2.20 7.00
1.40E+03 3.91 2.20 7.00
7.55E+02 1.91 2.20 7.00
1.18E+03 0.30 2.20 7.00
1.10E+00 28.26 2.20 7.00
1.10E+00 5.59 2.20 7.00
1.10E+00 15.66 2.20 7.00
1.10E+00 11.03 2.20 7.00
1.10E+00 3.03 2.20 7.00
1.10E+00 3.87 2.20 7.00
1.10E+00 5.25 2.20 7.00
1.10E+00 24.57 2.20 7.00
1.10E+00 22.72 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.31E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.37E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.30E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-822
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 ug/L
Ca CFS-L06-1315-T01-A 1 1.54E+04
Ca CFS-L06-1315-T02-A 1 2.93E+04
Ca CFS-L06-1315-T03-A 1 2.16E+04
Ca CFS-L06-1315-T04-A 1 5.96E+04
Ca CFS-L06-1315-T05-A 1 7.81 E+04
Ca CFS-L06-1315-T06-A 1 1.19E+05
Ca CFS-L06-1315-T07-A 1 1.12E+05
Ca CFS-L06-1315-T08-A 1 6.20E+04
Ca CFS-L06-1315-T09-A 1 1.06E+05
Ca CFS-L06-1315-T01-B 1 1.43E+04
Ca CFS-L06-1315-T02-B 1 2.54E+04
Ca CFS-L06-1315-T03-B 1 2.18E+04
Ca CFS-L06-1315-T04-B 1 6.31 E+04
Ca CFS-L06-1315-T05-B 1 8.35E+04
Ca CFS-L06-1315-T06-B 1 1.25E+05
Ca CFS-L06-1315-T07-B 1 1.21E+05
Ca CFS-L06-1315-T08-B 1 6.95E+04
Ca CFS-L06-1315-T09-B 1 1.11E+05
Ca CFS-L06-1315-T01-C 1 1.45E+04
Ca CFS-L06-1315-T02-C 1 2.89E+04
Ca CFS-L06-1315-T03-C 1 2.38E+04
Ca CFS-L06-1315-T04-C 1 6.54E+04
Ca CFS-L06-1315-T05-C 1 8.46E+04
Ca CFS-L06-1315-T06-C 1 1.27E+05
Ca CFS-L06-1315-T07-C 1 1.22E+05
Ca CFS-L06-1315-T08-C 1 7.12E+04
Ca CFS-L06-1315-T09-C 1 1.15E+05
Ca CFS-L06-1315-M01-A 1 2.71E+01
Ca CFS-L06-1315-M02-A 1 2.35E+01
Ca CFS-L06-1315-M03-A 1 2.73E+01
Ca CFS-L06-1315-M04-A 1 1.53E+01
Ca CFS-L06-1315-M05-A 1 2.30E+01
Ca CFS-L06-1315-M06-A 1 2.61E+01
Ca CFS-L06-1315-M07-A 1 2.59E+01
Ca CFS-L06-1315-M08-A 1 4.38E+00 E
Ca CFS-L06-1315-M09-A 1 4.20E+00 E
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.54E+04 1.00 2.60 8.30
2.93E+04 1.48 2.60 8.30
2.16E+04 1.74 2.60 8.30 10000 1000
5.96E+04 1.88 2.60 8.30
7.81 E+04 1.25 2.60 8.30
1.19E+05 0.79 2.60 8.30
1.12E+05 1.57 2.60 8.30
6.20E+04 0.98 2.60 8.30
1.06E+05 1.42 2.60 8.30
1.43E+04 1.01 2.60 8.30
2.54E+04 1.48 2.60 8.30
2.18E+04 2.40 2.60 8.30 10000 1000
6.31 E+04 2.25 2.60 8.30
8.35E+04 0.42 2.60 8.30
1.25E+05 1.31 2.60 8.30
1.21E+05 0.75 2.60 8.30
6.95E+04 1.21 2.60 8.30
1.11E+05 0.92 2.60 8.30
1.45E+04 0.35 2.60 8.30
2.89E+04 0.60 2.60 8.30
2.38E+04 6.39 2.60 8.30 10000 1000
6.54E+04 0.98 2.60 8.30
8.46E+04 0.86 2.60 8.30
1.27E+05 1.90 2.60 8.30
1.22E+05 3.57 2.60 8.30
7.12E+04 1.55 2.60 8.30
1.15E+05 0.23 2.60 8.30
2.71E+01 3.11 2.60 8.30
2.35E+01 2.40 2.60 8.30
2.73E+01 5.28 2.60 8.30
1.53E+01 2.16 2.60 8.30
2.30E+01 1.76 2.60 8.30
2.61E+01 1.03 2.60 8.30
2.59E+01 5.40 2.60 8.30
4.38E+00 2.96 2.60 8.30
4.20E+00 15.56 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.25E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.27E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.46E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-823
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Cr CFS-L06-1315-T01-A 1 6.00E-01 U1/2
Cr CFS-L06-1315-T02-A 1 6.00E-01 U1/2
Cr CFS-L06-1315-T03-A 1 6.00E-01 U1/2
Cr CFS-L06-1315-T04-A 1 6.00E-01 U1/2
Cr CFS-L06-1315-T05-A 1 6.00E-01 U1/2
Cr CFS-L06-1315-T06-A 1 6.00E-01 U1/2
Cr CFS-L06-1315-T07-A 1 6.00E-01 U1/2
Cr CFS-L06-1315-T08-A 1 6.00E-01 U1/2
Cr CFS-L06-1315-T09-A 1 6.00E-01 U1/2
Cr CFS-L06-1315-T01-B 1 6.00E-01 U1/2
Cr CFS-L06-1315-T02-B 1 6.00E-01 U1/2
Cr CFS-L06-1315-T03-B 1 6.00E-01 U1/2
Cr CFS-L06-1315-T04-B 1 6.00E-01 U1/2
Cr CFS-L06-1315-T05-B 1 6.00E-01 U1/2
Cr CFS-L06-1315-T06-B 1 6.00E-01 U1/2
Cr CFS-L06-1315-T07-B 1 6.00E-01 U1/2
Cr CFS-L06-1315-T08-B 1 6.00E-01 U1/2
Cr CFS-L06-1315-T09-B 1 6.00E-01 U1/2
Cr CFS-L06-1315-T01-C 1 6.00E-01 U1/2
Cr CFS-L06-1315-T02-C 1 6.00E-01 U1/2
Cr CFS-L06-1315-T03-C 1 6.00E-01 U1/2
Cr CFS-L06-1315-T04-C 1 6.00E-01 U1/2
Cr CFS-L06-1315-T05-C 1 6.00E-01 U1/2
Cr CFS-L06-1315-T06-C 1 6.00E-01 U1/2
Cr CFS-L06-1315-T07-C 1 6.00E-01 U1/2
Cr CFS-L06-1315-T08-C 1 6.00E-01 U1/2
Cr CFS-L06-1315-T09-C 1 6.00E-01 U1/2
Cr CFS-L06-1315-M01-A 1 6.00E-01 U1/2
Cr CFS-L06-1315-M02-A 1 6.00E-01 U1/2
Cr CFS-L06-1315-M03-A 1 6.00E-01 U1/2
Cr CFS-L06-1315-M04-A 1 6.00E-01 U1/2
Cr CFS-L06-1315-M05-A 1 6.00E-01 U1/2
Cr CFS-L06-1315-M06-A 1 6.00E-01 U1/2
Cr CFS-L06-1315-M07-A 1 6.00E-01 U1/2
Cr CFS-L06-1315-M08-A 1 6.00E-01 U1/2
Cr CFS-L06-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 37.77 1.20 3.82
6.00E-01 59.66 1.20 3.82
6.00E-01 23.89 1.20 3.82 10000 1000
6.00E-01 34.90 1.20 3.82
6.00E-01 10.91 1.20 3.82
6.00E-01 13.88 1.20 3.82
6.00E-01 10.90 1.20 3.82
6.00E-01 61.66 1.20 3.82
6.00E-01 42.07 1.20 3.82
6.00E-01 6.72 1.20 3.82
6.00E-01 35.02 1.20 3.82
6.00E-01 47.51 1.20 3.82 10000 1000
6.00E-01 8.38 1.20 3.82
6.00E-01 40.23 1.20 3.82
6.00E-01 12.05 1.20 3.82
6.00E-01 17.40 1.20 3.82
6.00E-01 35.65 1.20 3.82
6.00E-01 42.82 1.20 3.82
6.00E-01 32.06 1.20 3.82
6.00E-01 40.97 1.20 3.82
6.00E-01 32.71 1.20 3.82 10000 1000
6.00E-01 19.15 1.20 3.82
6.00E-01 21.69 1.20 3.82
6.00E-01 23.50 1.20 3.82
6.00E-01 25.02 1.20 3.82
6.00E-01 62.19 1.20 3.82
6.00E-01 20.39 1.20 3.82
6.00E-01 40.52 1.20 3.82
6.00E-01 41.34 1.20 3.82
6.00E-01 31.41 1.20 3.82
6.00E-01 14.96 1.20 3.82
6.00E-01 11.49 1.20 3.82
6.00E-01 35.51 1.20 3.82
6.00E-01 40.81 1.20 3.82
6.00E-01 70.87 1.20 3.82
6.00E-01 39.82 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.99E+02 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.63E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-824
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Co CFS-L06-1315-T01-A 1 9.00E-01 U1/2
Co CFS-L06-1315-T02-A 1 4.49E+00 E
Co CFS-L06-1315-T03-A 1 5.38E+00 E
Co CFS-L06-1315-T04-A 1 2.16E+01
Co CFS-L06-1315-T05-A 1 2.77E+01
Co CFS-L06-1315-T06-A 1 4.42E+01
Co CFS-L06-1315-T07-A 1 3.89E+01
Co CFS-L06-1315-T08-A 1 1.68E+01
Co CFS-L06-1315-T09-A 1 3.37E+01
Co CFS-L06-1315-T01-B 1 9.00E-01 U1/2
Co CFS-L06-1315-T02-B 1 4.05E+00 E
Co CFS-L06-1315-T03-B 1 4.28E+00 E
Co CFS-L06-1315-T04-B 1 2.17E+01
Co CFS-L06-1315-T05-B 1 2.78E+01
Co CFS-L06-1315-T06-B 1 4.30E+01
Co CFS-L06-1315-T07-B 1 3.96E+01
Co CFS-L06-1315-T08-B 1 1.98E+01
Co CFS-L06-1315-T09-B 1 3.34E+01
Co CFS-L06-1315-T01-C 1 9.00E-01 U1/2
Co CFS-L06-1315-T02-C 1 6.22E+00
Co CFS-L06-1315-T03-C 1 5.55E+00 E
Co CFS-L06-1315-T04-C 1 2.53E+01
Co CFS-L06-1315-T05-C 1 3.14E+01
Co CFS-L06-1315-T06-C 1 4.95E+01
Co CFS-L06-1315-T07-C 1 4.69E+01
Co CFS-L06-1315-T08-C 1 2.33E+01
Co CFS-L06-1315-T09-C 1 3.91 E+01
Co CFS-L06-1315-M01-A 1 9.00E-01 U1/2
Co CFS-L06-1315-M02-A 1 9.00E-01 U1/2
Co CFS-L06-1315-M03-A 1 9.00E-01 U1/2
Co CFS-L06-1315-M04-A 1 9.00E-01 U1/2
Co CFS-L06-1315-M05-A 1 9.00E-01 U1/2
Co CFS-L06-1315-M06-A 1 9.00E-01 U1/2
Co CFS-L06-1315-M07-A 1 9.00E-01 U1/2
Co CFS-L06-1315-M08-A 1 9.00E-01 U1/2
Co CFS-L06-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 36.37 1.80 5.72
4.49E+00 5.26 1.80 5.72
5.38E+00 6.24 1.80 5.72 10000 1000
2.16E+01 2.81 1.80 5.72
2.77E+01 2.97 1.80 5.72
4.42E+01 1.46 1.80 5.72
3.89E+01 3.15 1.80 5.72
1.68E+01 6.81 1.80 5.72
3.37E+01 3.72 1.80 5.72
9.00E-01 11.68 1.80 5.72
4.05E+00 7.04 1.80 5.72
4.28E+00 7.57 1.80 5.72 10000 1000
2.17E+01 3.12 1.80 5.72
2.78E+01 0.55 1.80 5.72
4.30E+01 2.30 1.80 5.72
3.96E+01 2.52 1.80 5.72
1.98E+01 3.76 1.80 5.72
3.34E+01 3.03 1.80 5.72
9.00E-01 21.98 1.80 5.72
6.22E+00 1.09 1.80 5.72
5.55E+00 7.81 1.80 5.72 10000 1000
2.53E+01 5.61 1.80 5.72
3.14E+01 2.81 1.80 5.72
4.95E+01 3.45 1.80 5.72
4.69E+01 4.12 1.80 5.72
2.33E+01 5.41 1.80 5.72
3.91E+01 1.48 1.80 5.72
9.00E-01 49.55 1.80 5.72
9.00E-01 42.04 1.80 5.72
9.00E-01 69.23 1.80 5.72
9.00E-01 19.21 1.80 5.72
9.00E-01 14.62 1.80 5.72
9.00E-01 63.54 1.80 5.72
9.00E-01 54.12 1.80 5.72
9.00E-01 43.15 1.80 5.72
9.00E-01 59.06 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.78E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.58E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-825
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Cu CFS-L06-1315-T01-A 1 6.79E+01
Cu CFS-L06-1315-T02-A 1 1.44E+02
Cu CFS-L06-1315-T03-A 1 2.06E+02
Cu CFS-L06-1315-T04-A 1 3.19E+02
Cu CFS-L06-1315-T05-A 1 4.02E+02
Cu CFS-L06-1315-T06-A 1 5.80E+02
Cu CFS-L06-1315-T07-A 1 8.35E+02
Cu CFS-L06-1315-T08-A 1 3.66E+02
Cu CFS-L06-1315-T09-A 1 5.80E+02
Cu CFS-L06-1315-T01-B 1 5.59E+01
Cu CFS-L06-1315-T02-B 1 1.23E+02
Cu CFS-L06-1315-T03-B 1 1.47E+02
Cu CFS-L06-1315-T04-B 1 2.71E+02
Cu CFS-L06-1315-T05-B 1 3.48E+02
Cu CFS-L06-1315-T06-B 1 5.27E+02
Cu CFS-L06-1315-T07-B 1 5.52E+02
Cu CFS-L06-1315-T08-B 1 3.71E+02
Cu CFS-L06-1315-T09-B 1 5.84E+02
Cu CFS-L06-1315-T01-C 1 4.96E+01
Cu CFS-L06-1315-T02-C 1 1.40E+02
Cu CFS-L06-1315-T03-C 1 1.66E+02
Cu CFS-L06-1315-T04-C 1 3.15E+02
Cu CFS-L06-1315-T05-C 1 3.94E+02
Cu CFS-L06-1315-T06-C 1 6.09E+02
Cu CFS-L06-1315-T07-C 1 6.61E+02
Cu CFS-L06-1315-T08-C 1 4.36E+02
Cu CFS-L06-1315-T09-C 1 6.84E+02
Cu CFS-L06-1315-M01-A 1 1.85E+00 U1/2
Cu CFS-L06-1315-M02-A 1 1.85E+00 U1/2
Cu CFS-L06-1315-M03-A 1 1.85E+00 U1/2
Cu CFS-L06-1315-M04-A 1 1.85E+00 U1/2
Cu CFS-L06-1315-M05-A 1 1.85E+00 U1/2
Cu CFS-L06-1315-M06-A 1 1.85E+00 U1/2
Cu CFS-L06-1315-M07-A 1 1.85E+00 U1/2
Cu CFS-L06-1315-M08-A 1 1.85E+00 U1/2
Cu CFS-L06-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.79E+01 1.61 3.70 11.80
1.44E+02 0.67 3.70 11.80
2.06E+02 2.92 3.70 11.80 10000 1000
3.19E+02 1.76 3.70 11.80
4.02E+02 2.61 3.70 11.80
5.80E+02 1.25 3.70 11.80
8.35E+02 1.03 3.70 11.80
3.66E+02 1.31 3.70 11.80
5.80E+02 0.65 3.70 11.80
5.59E+01 2.50 3.70 11.80
1.23E+02 1.53 3.70 11.80
1.47E+02 1.87 3.70 11.80 10000 1000
2.71E+02 2.33 3.70 11.80
3.48E+02 0.65 3.70 11.80
5.27E+02 2.27 3.70 11.80
5.52E+02 1.27 3.70 11.80
3.71E+02 1.12 3.70 11.80
5.84E+02 0.90 3.70 11.80
4.96E+01 1.80 3.70 11.80
1.40E+02 1.00 3.70 11.80
1.66E+02 8.94 3.70 11.80 10000 1000
3.15E+02 0.61 3.70 11.80
3.94E+02 0.04 3.70 11.80
6.09E+02 1.78 3.70 11.80
6.61E+02 4.73 3.70 11.80
4.36E+02 1.45 3.70 11.80
6.84E+02 0.40 3.70 11.80
1.85E+00 2.46 3.70 11.80
1.85E+00 6.97 3.70 11.80
1.85E+00 7.31 3.70 11.80
1.85E+00 16.44 3.70 11.80
1.85E+00 10.81 3.70 11.80
1.85E+00 3.54 3.70 11.80
1.85E+00 6.58 3.70 11.80
1.85E+00 3.72 3.70 11.80
1.85E+00 4.49 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.13E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-826
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Fe CFS-L06-1315-T01-A 1 1.00E+00 U1/2
Fe CFS-L06-1315-T02-A 1 1.00E+00 U1/2
Fe CFS-L06-1315-T03-A 1 1.00E+00 U1/2
Fe CFS-L06-1315-T04-A 1 1.00E+00 U1/2
Fe CFS-L06-1315-T05-A 1 1.00E+00 U1/2
Fe CFS-L06-1315-T06-A 1 1.00E+00 U1/2
Fe CFS-L06-1315-T07-A 1 1.00E+00 U1/2
Fe CFS-L06-1315-T08-A 1 1.00E+00 U1/2
Fe CFS-L06-1315-T09-A 1 1.00E+00 U1/2
Fe CFS-L06-1315-T01-B 1 1.00E+00 U1/2
Fe CFS-L06-1315-T02-B 1 1.00E+00 U1/2
Fe CFS-L06-1315-T03-B 1 1.00E+00 U1/2
Fe CFS-L06-1315-T04-B 1 1.00E+00 U1/2
Fe CFS-L06-1315-T05-B 1 1.00E+00 U1/2
Fe CFS-L06-1315-T06-B 1 1.00E+00 U1/2
Fe CFS-L06-1315-T07-B 1 1.00E+00 U1/2
Fe CFS-L06-1315-T08-B 1 1.00E+00 U1/2
Fe CFS-L06-1315-T09-B 1 1.00E+00 U1/2
Fe CFS-L06-1315-T01-C 1 1.00E+00 U1/2
Fe CFS-L06-1315-T02-C 1 1.00E+00 U1/2
Fe CFS-L06-1315-T03-C 1 1.00E+00 U1/2
Fe CFS-L06-1315-T04-C 1 1.00E+00 U1/2
Fe CFS-L06-1315-T05-C 1 1.00E+00 U1/2
Fe CFS-L06-1315-T06-C 1 1.00E+00 U1/2
Fe CFS-L06-1315-T07-C 1 1.00E+00 U1/2
Fe CFS-L06-1315-T08-C 1 1.00E+00 U1/2
Fe CFS-L06-1315-T09-C 1 1.00E+00 U1/2
Fe CFS-L06-1315-M01-A 1 1.00E+00 U1/2
Fe CFS-L06-1315-M02-A 1 1.00E+00 U1/2
Fe CFS-L06-1315-M03-A 1 1.00E+00 U1/2
Fe CFS-L06-1315-M04-A 1 1.00E+00 U1/2
Fe CFS-L06-1315-M05-A 1 1.00E+00 U1/2
Fe CFS-L06-1315-M06-A 1 1.00E+00 U1/2
Fe CFS-L06-1315-M07-A 1 1.00E+00 U1/2
Fe CFS-L06-1315-M08-A 1 1.00E+00 U1/2
Fe CFS-L06-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 4.42 2.00 6.40
1.00E+00 11.63 2.00 6.40
1.00E+00 10.20 2.00 6.40 10000 1000
1.00E+00 21.26 2.00 6.40
1.00E+00 9.38 2.00 6.40
1.00E+00 7.53 2.00 6.40
1.00E+00 34.36 2.00 6.40
1.00E+00 12.06 2.00 6.40
1.00E+00 19.50 2.00 6.40
1.00E+00 0.82 2.00 6.40
1.00E+00 32.96 2.00 6.40
1.00E+00 4.92 2.00 6.40 10000 1000
1.00E+00 11.95 2.00 6.40
1.00E+00 15.70 2.00 6.40
1.00E+00 10.33 2.00 6.40
1.00E+00 19.14 2.00 6.40
1.00E+00 16.10 2.00 6.40
1.00E+00 9.67 2.00 6.40
1.00E+00 20.08 2.00 6.40
1.00E+00 29.14 2.00 6.40
1.00E+00 15.93 2.00 6.40 10000 1000
1.00E+00 11.94 2.00 6.40
1.00E+00 13.30 2.00 6.40
1.00E+00 8.96 2.00 6.40
1.00E+00 11.76 2.00 6.40
1.00E+00 31.25 2.00 6.40
1.00E+00 8.83 2.00 6.40
1.00E+00 10.04 2.00 6.40
1.00E+00 3.79 2.00 6.40
1.00E+00 22.88 2.00 6.40
1.00E+00 24.63 2.00 6.40
1.00E+00 27.71 2.00 6.40
1.00E+00 13.70 2.00 6.40
1.00E+00 29.66 2.00 6.40
1.00E+00 11.01 2.00 6.40
1.00E+00 16.20 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.71E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-827
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Pb CFS-L06-1315-T01-A 1 3.81E+01
Pb CFS-L06-1315-T02-A 1 7.05E+01
Pb CFS-L06-1315-T03-A 1 1.13E+02
Pb CFS-L06-1315-T04-A 1 2.45E+02
Pb CFS-L06-1315-T05-A 1 3.07E+02
Pb CFS-L06-1315-T06-A 1 3.95E+02
Pb CFS-L06-1315-T07-A 1 4.59E+02
Pb CFS-L06-1315-T08-A 1 2.20E+02
Pb CFS-L06-1315-T09-A 1 3.49E+02
Pb CFS-L06-1315-T01-B 1 3.55E+01
Pb CFS-L06-1315-T02-B 1 8.13E+01
Pb CFS-L06-1315-T03-B 1 1.18E+02
Pb CFS-L06-1315-T04-B 1 1.97E+02
Pb CFS-L06-1315-T05-B 1 2.67E+02
Pb CFS-L06-1315-T06-B 1 3.82E+02
Pb CFS-L06-1315-T07-B 1 3.85E+02
Pb CFS-L06-1315-T08-B 1 2.52E+02
Pb CFS-L06-1315-T09-B 1 3.83E+02
Pb CFS-L06-1315-T01-C 1 3.63E+01
Pb CFS-L06-1315-T02-C 1 8.33E+01
Pb CFS-L06-1315-T03-C 1 1.25E+02
Pb CFS-L06-1315-T04-C 1 2.21E+02
Pb CFS-L06-1315-T05-C 1 2.99E+02
Pb CFS-L06-1315-T06-C 1 4.19E+02
Pb CFS-L06-1315-T07-C 1 4.19E+02
Pb CFS-L06-1315-T08-C 1 2.82E+02
Pb CFS-L06-1315-T09-C 1 4.11E+02
Pb CFS-L06-1315-M01-A 1 3.40E+00 U1/2
Pb CFS-L06-1315-M02-A 1 3.40E+00 U1/2
Pb CFS-L06-1315-M03-A 1 3.40E+00 U1/2
Pb CFS-L06-1315-M04-A 1 3.40E+00 U1/2
Pb CFS-L06-1315-M05-A 1 3.40E+00 U1/2
Pb CFS-L06-1315-M06-A 1 3.40E+00 U1/2
Pb CFS-L06-1315-M07-A 1 3.40E+00 U1/2
Pb CFS-L06-1315-M08-A 1 3.40E+00 U1/2
Pb CFS-L06-1315-M09-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.81 E+01 2.52 6.80 21.60
7.05E+01 8.73 6.80 21.60
1.13E+02 0.20 6.80 21.60 10000 1000
2.45E+02 2.93 6.80 21.60
3.07E+02 2.31 6.80 21.60
3.95E+02 1.28 6.80 21.60
4.59E+02 1.96 6.80 21.60
2.20E+02 0.72 6.80 21.60
3.49E+02 2.68 6.80 21.60
3.55E+01 11.11 6.80 21.60
8.13E+01 3.56 6.80 21.60
1.18E+02 4.58 6.80 21.60 10000 1000
1.97E+02 4.33 6.80 21.60
2.67E+02 1.77 6.80 21.60
3.82E+02 1.03 6.80 21.60
3.85E+02 0.42 6.80 21.60
2.52E+02 1.63 6.80 21.60
3.83E+02 1.11 6.80 21.60
3.63E+01 4.39 6.80 21.60
8.33E+01 5.90 6.80 21.60
1.25E+02 5.93 6.80 21.60 10000 1000
2.21E+02 3.16 6.80 21.60
2.99E+02 1.17 6.80 21.60
4.19E+02 0.54 6.80 21.60
4.19E+02 2.06 6.80 21.60
2.82E+02 1.18 6.80 21.60
4.11E+02 1.49 6.80 21.60
3.40E+00 7.89 6.80 21.60
3.40E+00 17.86 6.80 21.60
3.40E+00 9.40 6.80 21.60
3.40E+00 16.27 6.80 21.60
3.40E+00 7.25 6.80 21.60
3.40E+00 13.40 6.80 21.60
3.40E+00 5.77 6.80 21.60
3.40E+00 18.78 6.80 21.60
3.40E+00 24.05 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.03E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-828
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Li CFS-L06-1315-T01-A 1 2.06E+00 E
Li CFS-L06-1315-T02-A 1 2.42E+00 E
Li CFS-L06-1315-T03-A 1 2.49E+00 E
Li CFS-L06-1315-T04-A 1 5.29E+00 E
Li CFS-L06-1315-T05-A 1 5.54E+00 E
Li CFS-L06-1315-T06-A 1 6.18E+00
Li CFS-L06-1315-T07-A 1 6.04E+00
Li CFS-L06-1315-T08-A 1 4.90E+00 E
Li CFS-L06-1315-T09-A 1 6.29E+00
Li CFS-L06-1315-T01-B 1 2.06E+00 E
Li CFS-L06-1315-T02-B 1 2.15E+00 E
Li CFS-L06-1315-T03-B 1 3.22E+00 E
Li CFS-L06-1315-T04-B 1 4.87E+00 E
Li CFS-L06-1315-T05-B 1 5.39E+00 E
Li CFS-L06-1315-T06-B 1 6.29E+00
Li CFS-L06-1315-T07-B 1 5.72E+00 E
Li CFS-L06-1315-T08-B 1 6.15E+00
Li CFS-L06-1315-T09-B 1 6.12E+00
Li CFS-L06-1315-T01-C 1 2.97E+00 E
Li CFS-L06-1315-T02-C 1 2.45E+00 E
Li CFS-L06-1315-T03-C 1 2.25E+00 E
Li CFS-L06-1315-T04-C 1 5.49E+00 E
Li CFS-L06-1315-T05-C 1 4.92E+00 E
Li CFS-L06-1315-T06-C 1 5.46E+00 E
Li CFS-L06-1315-T07-C 1 5.52E+00 E
Li CFS-L06-1315-T08-C 1 4.18E+00 E
Li CFS-L06-1315-T09-C 1 5.96E+00 E
Li CFS-L06-1315-M01-A 1 9.50E-01 U1/2
Li CFS-L06-1315-M02-A 1 9.50E-01 U1/2
Li CFS-L06-1315-M03-A 1 9.50E-01 U1/2
Li CFS-L06-1315-M04-A 1 9.50E-01 U1/2
Li CFS-L06-1315-M05-A 1 9.50E-01 U1/2
Li CFS-L06-1315-M06-A 1 9.50E-01 U1/2
Li CFS-L06-1315-M07-A 1 9.50E-01 U1/2
Li CFS-L06-1315-M08-A 1 9.50E-01 U1/2
Li CFS-L06-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.06E+00 41.97 1.90 6.00
2.42E+00 15.48 1.90 6.00
2.49E+00 8.48 1.90 6.00 10000 1000
5.29E+00 44.82 1.90 6.00
5.54E+00 16.60 1.90 6.00
6.18E+00 3.10 1.90 6.00
6.04E+00 4.22 1.90 6.00
4.90E+00 6.70 1.90 6.00
6.29E+00 3.51 1.90 6.00
2.06E+00 11.68 1.90 6.00
2.15E+00 26.35 1.90 6.00
3.22E+00 29.11 1.90 6.00 10000 1000
4.87E+00 52.13 1.90 6.00
5.39E+00 35.64 1.90 6.00
6.29E+00 5.58 1.90 6.00
5.72E+00 13.86 1.90 6.00
6.15E+00 10.16 1.90 6.00
6.12E+00 1.66 1.90 6.00
2.97E+00 4.13 1.90 6.00
2.45E+00 25.98 1.90 6.00
2.25E+00 24.47 1.90 6.00 10000 1000
5.49E+00 35.19 1.90 6.00
4.92E+00 34.05 1.90 6.00
5.46E+00 13.73 1.90 6.00
5.52E+00 18.09 1.90 6.00
4.18E+00 20.55 1.90 6.00
5.96E+00 35.80 1.90 6.00
9.50E-01 28.99 1.90 6.00
9.50E-01 42.99 1.90 6.00
9.50E-01 48.26 1.90 6.00
9.50E-01 34.21 1.90 6.00
9.50E-01 56.72 1.90 6.00
9.50E-01 23.56 1.90 6.00
9.50E-01 14.17 1.90 6.00
9.50E-01 15.40 1.90 6.00
9.50E-01 38.10 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.19E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.19E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.72E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-829
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
ug/L
Mn CFS-L06-1315-T01-A 1 4.22E+01
Mn CFS-L06-1315-T02-A 1 2.09E+02
Mn CFS-L06-1315-T03-A 1 2.30E+02
Mn CFS-L06-1315-T04-A 1 6.49E+02
Mn CFS-L06-1315-T05-A 1 7.89E+02
Mn CFS-L06-1315-T06-A 1 1.28E+03
Mn CFS-L06-1315-T07-A 1 1.20E+03
Mn CFS-L06-1315-T08-A 1 6.25E+02
Mn CFS-L06-1315-T09-A 1 1.08E+03
Mn CFS-L06-1315-T01-B 1 2.73E+01
Mn CFS-L06-1315-T02-B 1 2.00E+02
Mn CFS-L06-1315-T03-B 1 2.08E+02
Mn CFS-L06-1315-T04-B 1 6.19E+02
Mn CFS-L06-1315-T05-B 1 7.72E+02
Mn CFS-L06-1315-T06-B 1 1.24E+03
Mn CFS-L06-1315-T07-B 1 1.20E+03
Mn CFS-L06-1315-T08-B 1 6.58E+02
Mn CFS-L06-1315-T09-B 1 1.10E+03
Mn CFS-L06-1315-T01-C 1 3.68E+01
Mn CFS-L06-1315-T02-C 1 2.61E+02
Mn CFS-L06-1315-T03-C 1 2.34E+02
Mn CFS-L06-1315-T04-C 1 6.91E+02
Mn CFS-L06-1315-T05-C 1 8.59E+02
Mn CFS-L06-1315-T06-C 1 1.40E+03
Mn CFS-L06-1315-T07-C 1 1.36E+03
Mn CFS-L06-1315-T08-C 1 7.36E+02
Mn CFS-L06-1315-T09-C 1 1.25E+03
Mn CFS-L06-1315-M01-A 1 1.00E+00 U1/2
Mn CFS-L06-1315-M02-A 1 1.00E+00 U1/2
Mn CFS-L06-1315-M03-A 1 1.00E+00 U1/2
Mn CFS-L06-1315-M04-A 1 1.00E+00 U1/2
Mn CFS-L06-1315-M05-A 1 1.00E+00 U1/2
Mn CFS-L06-1315-M06-A 1 1.00E+00 U1/2
Mn CFS-L06-1315-M07-A 1 1.00E+00 U1/2
Mn CFS-L06-1315-M08-A 1 1.00E+00 U1/2
Mn CFS-L06-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.22E+01 1.56 2.00 6.40
2.09E+02 0.75 2.00 6.40
2.30E+02 1.63 2.00 6.40 10000 1000
6.49E+02 0.96 2.00 6.40
7.89E+02 0.52 2.00 6.40
1.28E+03 0.27 2.00 6.40
1.20E+03 0.73 2.00 6.40
6.25E+02 1.15 2.00 6.40
1.08E+03 0.19 2.00 6.40
2.73E+01 1.39 2.00 6.40
2.00E+02 2.37 2.00 6.40
2.08E+02 2.21 2.00 6.40 10000 1000
6.19E+02 0.73 2.00 6.40
7.72E+02 0.35 2.00 6.40
1.24E+03 1.34 2.00 6.40
1.20E+03 1.13 2.00 6.40
6.58E+02 1.29 2.00 6.40
1.10E+03 1.11 2.00 6.40
3.68E+01 0.13 2.00 6.40
2.61E+02 1.72 2.00 6.40
2.34E+02 10.48 2.00 6.40 10000 1000
6.91 E+02 0.31 2.00 6.40
8.59E+02 0.64 2.00 6.40
1.40E+03 0.82 2.00 6.40
1.36E+03 2.06 2.00 6.40
7.36E+02 1.63 2.00 6.40
1.25E+03 0.55 2.00 6.40
1.00E+00 6.62 2.00 6.40
1.00E+00 14.17 2.00 6.40
1.00E+00 15.70 2.00 6.40
1.00E+00 5.64 2.00 6.40
1.00E+00 6.67 2.00 6.40
1.00E+00 3.56 2.00 6.40
1.00E+00 36.79 2.00 6.40
1.00E+00 23.82 2.00 6.40
1.00E+00 13.59 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.20E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.20E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.20E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-830
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Mg CFS-L06-1315-T01-A 1 3.65E+03
Mg CFS-L06-1315-T02-A 1 1.78E+04
Mg CFS-L06-1315-T03-A 1 1.89E+04
Mg CFS-L06-1315-T04-A 1 5.44E+04
Mg CFS-L06-1315-T05-A 1 6.34E+04
Mg CFS-L06-1315-T06-A 1 9.50E+04
Mg CFS-L06-1315-T07-A 1 8.10E+04
Mg CFS-L06-1315-T08-A 1 3.92E+04
Mg CFS-L06-1315-T09-A 1 6.51 E+04
Mg CFS-L06-1315-T01-B 1 2.20E+03
Mg CFS-L06-1315-T02-B 1 1.59E+04
Mg CFS-L06-1315-T03-B 1 1.67E+04
Mg CFS-L06-1315-T04-B 1 5.02E+04
Mg CFS-L06-1315-T05-B 1 6.03E+04
Mg CFS-L06-1315-T06-B 1 9.01 E+04
Mg CFS-L06-1315-T07-B 1 7.83E+04
Mg CFS-L06-1315-T08-B 1 4.04E+04
Mg CFS-L06-1315-T09-B 1 6.29E+04
Mg CFS-L06-1315-T01-C 1 2.55E+03
Mg CFS-L06-1315-T02-C 1 1.75E+04
Mg CFS-L06-1315-T03-C 1 1.57E+04
Mg CFS-L06-1315-T04-C 1 4.67E+04
Mg CFS-L06-1315-T05-C 1 5.54E+04
Mg CFS-L06-1315-T06-C 1 8.55E+04
Mg CFS-L06-1315-T07-C 1 7.53E+04
Mg CFS-L06-1315-T08-C 1 3.84E+04
Mg CFS-L06-1315-T09-C 1 6.07E+04
Mg CFS-L06-1315-M01-A 1 5.38E+00
Mg CFS-L06-1315-M02-A 1 1.26E+00 E
Mg CFS-L06-1315-M03-A 1 5.00E-01 U1/2
Mg CFS-L06-1315-M04-A 1 5.00E-01 U1/2
Mg CFS-L06-1315-M05-A 1 5.00E-01 U1/2
Mg CFS-L06-1315-M06-A 1 5.00E-01 U1/2
Mg CFS-L06-1315-M07-A 1 5.00E-01 U1/2
Mg CFS-L06-1315-M08-A 1 5.00E-01 U1/2
Mg CFS-L06-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.65E+03 1.30 1.00 3.18
1.78E+04 1.47 1.00 3.18
1.89E+04 2.52 1.00 3.18 10000 1000
5.44E+04 1.22 1.00 3.18
6.34E+04 1.04 1.00 3.18
9.50E+04 1.00 1.00 3.18
8.10E+04 0.79 1.00 3.18
3.92E+04 1.47 1.00 3.18
6.51E+04 1.82 1.00 3.18
2.20E+03 0.99 1.00 3.18
1.59E+04 0.82 1.00 3.18
1.67E+04 2.31 1.00 3.18 10000 1000
5.02E+04 2.59 1.00 3.18
6.03E+04 1.17 1.00 3.18
9.01E+04 1.33 1.00 3.18
7.83E+04 1.02 1.00 3.18
4.04E+04 1.42 1.00 3.18
6.29E+04 0.59 1.00 3.18
2.55E+03 0.39 1.00 3.18
1.75E+04 0.47 1.00 3.18
1.57E+04 5.83 1.00 3.18 10000 1000
4.67E+04 0.65 1.00 3.18
5.54E+04 0.26 1.00 3.18
8.55E+04 0.57 1.00 3.18
7.53E+04 2.22 1.00 3.18
3.84E+04 1.74 1.00 3.18
6.07E+04 0.14 1.00 3.18
5.38E+00 9.33 1.00 3.18
1.26E+00 7.68 1.00 3.18
5.00E-01 40.75 1.00 3.18
5.00E-01 15.69 1.00 3.18
5.00E-01 2.47 1.00 3.18
5.00E-01 8.98 1.00 3.18
5.00E-01 46.62 1.00 3.18
5.00E-01 8.73 1.00 3.18
5.00E-01 40.02 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.98E+04 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.76E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.67E+04 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-831
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Mo CFS-L06-1315-T01-A 1 1.49E+00 E
Mo CFS-L06-1315-T02-A 1 2.56E+00 E
Mo CFS-L06-1315-T03-A 1 2.49E+00 E
Mo CFS-L06-1315-T04-A 1 1.91E+00 E
Mo CFS-L06-1315-T05-A 1 1.94E+00 E
Mo CFS-L06-1315-T06-A 1 3.46E+00 E
Mo CFS-L06-1315-T07-A 1 2.13E+00 E
Mo CFS-L06-1315-T08-A 1 2.62E+00 E
Mo CFS-L06-1315-T09-A 1 2.39E+00 E
Mo CFS-L06-1315-T01-B 1 3.08E+00 E
Mo CFS-L06-1315-T02-B 1 2.20E+00 E
Mo CFS-L06-1315-T03-B 1 2.84E+00 E
Mo CFS-L06-1315-T04-B 1 2.33E+00 E
Mo CFS-L06-1315-T05-B 1 3.09E+00 E
Mo CFS-L06-1315-T06-B 1 3.78E+00 E
Mo CFS-L06-1315-T07-B 1 3.16E+00 E
Mo CFS-L06-1315-T08-B 1 3.06E+00 E
Mo CFS-L06-1315-T09-B 1 2.83E+00 E
Mo CFS-L06-1315-T01-C 1 1.51E+00 E
Mo CFS-L06-1315-T02-C 1 2.59E+00 E
Mo CFS-L06-1315-T03-C 1 2.56E+00 E
Mo CFS-L06-1315-T04-C 1 2.27E+00 E
Mo CFS-L06-1315-T05-C 1 2.25E+00 E
Mo CFS-L06-1315-T06-C 1 2.37E+00 E
Mo CFS-L06-1315-T07-C 1 3.06E+00 E
Mo CFS-L06-1315-T08-C 1 1.86E+00 E
Mo CFS-L06-1315-T09-C 1 2.95E+00 E
Mo CFS-L06-1315-M01-A 1 6.00E-01 U1/2
Mo CFS-L06-1315-M02-A 1 6.00E-01 U1/2
Mo CFS-L06-1315-M03-A 1 6.00E-01 U1/2
Mo CFS-L06-1315-M04-A 1 6.00E-01 U1/2
Mo CFS-L06-1315-M05-A 1 6.00E-01 U1/2
Mo CFS-L06-1315-M06-A 1 6.00E-01 U1/2
Mo CFS-L06-1315-M07-A 1 6.00E-01 U1/2
Mo CFS-L06-1315-M08-A 1 6.00E-01 U1/2
Mo CFS-L06-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.49E+00 1.81 1.20 3.82
2.56E+00 10.03 1.20 3.82
2.49E+00 36.53 1.20 3.82 10000 1000
1.91E+00 24.62 1.20 3.82
1.94E+00 28.26 1.20 3.82
3.46E+00 25.46 1.20 3.82
2.13E+00 18.74 1.20 3.82
2.62E+00 10.81 1.20 3.82
2.39E+00 11.49 1.20 3.82
3.08E+00 1.82 1.20 3.82
2.20E+00 17.67 1.20 3.82
2.84E+00 16.89 1.20 3.82 10000 1000
2.33E+00 9.66 1.20 3.82
3.09E+00 23.95 1.20 3.82
3.78E+00 32.46 1.20 3.82
3.16E+00 24.83 1.20 3.82
3.06E+00 23.61 1.20 3.82
2.83E+00 7.57 1.20 3.82
1.51E+00 18.42 1.20 3.82
2.59E+00 33.48 1.20 3.82
2.56E+00 17.05 1.20 3.82 10000 1000
2.27E+00 9.48 1.20 3.82
2.25E+00 6.32 1.20 3.82
2.37E+00 29.93 1.20 3.82
3.06E+00 28.20 1.20 3.82
1.86E+00 34.09 1.20 3.82
2.95E+00 19.83 1.20 3.82
6.00E-01 23.03 1.20 3.82
6.00E-01 51.08 1.20 3.82
6.00E-01 32.12 1.20 3.82
6.00E-01 34.10 1.20 3.82
6.00E-01 44.33 1.20 3.82
6.00E-01 20.21 1.20 3.82
6.00E-01 56.68 1.20 3.82
6.00E-01 34.93 1.20 3.82
6.00E-01 15.70 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.92E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.60E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 131 5 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-832
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Ni CFS-L06-1315-T01-A 1 9.00E-01 U1/2
Ni CFS-L06-1315-T02-A 1 9.47E+00
Ni CFS-L06-1315-T03-A 1 1.25E+01
Ni CFS-L06-1315-T04-A 1 4.25E+01
Ni CFS-L06-1315-T05-A 1 5.22E+01
Ni CFS-L06-1315-T06-A 1 7.88E+01
Ni CFS-L06-1315-T07-A 1 6.95E+01
Ni CFS-L06-1315-T08-A 1 3.16E+01
Ni CFS-L06-1315-T09-A 1 5.30E+01
Ni CFS-L06-1315-T01-B 1 9.00E-01 U1/2
Ni CFS-L06-1315-T02-B 1 8.01E+00
Ni CFS-L06-1315-T03-B 1 9.64E+00
Ni CFS-L06-1315-T04-B 1 4.02E+01
Ni CFS-L06-1315-T05-B 1 5.14E+01
Ni CFS-L06-1315-T06-B 1 7.60E+01
Ni CFS-L06-1315-T07-B 1 6.76E+01
Ni CFS-L06-1315-T08-B 1 3.29E+01
Ni CFS-L06-1315-T09-B 1 5.32E+01
Ni CFS-L06-1315-T01-C 1 9.00E-01 U1/2
Ni CFS-L06-1315-T02-C 1 1.22E+01
Ni CFS-L06-1315-T03-C 1 1.29E+01
Ni CFS-L06-1315-T04-C 1 4.48E+01
Ni CFS-L06-1315-T05-C 1 5.72E+01
Ni CFS-L06-1315-T06-C 1 8.82E+01
Ni CFS-L06-1315-T07-C 1 7.78E+01
Ni CFS-L06-1315-T08-C 1 3.96E+01
Ni CFS-L06-1315-T09-C 1 6.38E+01
Ni CFS-L06-1315-M01-A 1 9.00E-01 U1/2
Ni CFS-L06-1315-M02-A 1 9.00E-01 U1/2
Ni CFS-L06-1315-M03-A 1 9.00E-01 U1/2
Ni CFS-L06-1315-M04-A 1 9.00E-01 U1/2
Ni CFS-L06-1315-M05-A 1 9.00E-01 U1/2
Ni CFS-L06-1315-M06-A 1 9.00E-01 U1/2
Ni CFS-L06-1315-M07-A 1 9.00E-01 U1/2
Ni CFS-L06-1315-M08-A 1 9.00E-01 U1/2
Ni CFS-L06-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 11.90 1.80 5.70
9.47E+00 3.78 1.80 5.70
1.25E+01 2.73 1.80 5.70 10000 1000
4.25E+01 2.56 1.80 5.70
5.22E+01 0.97 1.80 5.70
7.88E+01 4.11 1.80 5.70
6.95E+01 1.55 1.80 5.70
3.16E+01 2.73 1.80 5.70
5.30E+01 5.36 1.80 5.70
9.00E-01 23.33 1.80 5.70
8.01 E+00 5.38 1.80 5.70
9.64E+00 6.92 1.80 5.70 10000 1000
4.02E+01 5.90 1.80 5.70
5.14E+01 2.49 1.80 5.70
7.60E+01 2.81 1.80 5.70
6.76E+01 2.31 1.80 5.70
3.29E+01 2.71 1.80 5.70
5.32E+01 1.10 1.80 5.70
9.00E-01 5.18 1.80 5.70
1.22E+01 1.14 1.80 5.70
1.29E+01 2.23 1.80 5.70 10000 1000
4.48E+01 0.48 1.80 5.70
5.72E+01 1.05 1.80 5.70
8.82E+01 2.43 1.80 5.70
7.78E+01 5.18 1.80 5.70
3.96E+01 3.17 1.80 5.70
6.38E+01 0.98 1.80 5.70
9.00E-01 17.89 1.80 5.70
9.00E-01 31.97 1.80 5.70
9.00E-01 31.26 1.80 5.70
9.00E-01 12.58 1.80 5.70
9.00E-01 24.55 1.80 5.70
9.00E-01 15.70 1.80 5.70
9.00E-01 11.87 1.80 5.70
9.00E-01 35.47 1.80 5.70
9.00E-01 28.42 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.68E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-833
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 ug/L
P CFS-L06-1315-T01-A 1 4.23E+00 E
P CFS-L06-1315-T02-A 1 8.99E+00 E
P CFS-L06-1315-T03-A 1 6.76E+00 E
P CFS-L06-1315-T04-A 1 9.36E+00 E
P CFS-L06-1315-T05-A 1 8.42E+00 E
P CFS-L06-1315-T06-A 1 4.10E+00 E
P CFS-L06-1315-T07-A 1 1.07E+01 E
P CFS-L06-1315-T08-A 1 8.34E+00 E
P CFS-L06-1315-T09-A 1 9.87E+00 E
P CFS-L06-1315-T01-B 1 3.87E+00 E
P CFS-L06-1315-T02-B 1 8.85E+00 E
P CFS-L06-1315-T03-B 1 1.23E+01
P CFS-L06-1315-T04-B 1 1.36E+01
P CFS-L06-1315-T05-B 1 1.03E+01 E
P CFS-L06-1315-T06-B 1 7.36E+00 E
P CFS-L06-1315-T07-B 1 5.78E+00 E
P CFS-L06-1315-T08-B 1 4.22E+00 E
P CFS-L06-1315-T09-B 1 7.20E+00 E
P CFS-L06-1315-T01-C 1 5.44E+00 E
P CFS-L06-1315-T02-C 1 1.07E+01 E
P CFS-L06-1315-T03-C 1 1.02E+01 E
P CFS-L06-1315-T04-C 1 7.02E+00 E
P CFS-L06-1315-T05-C 1 5.38E+00 E
P CFS-L06-1315-T06-C 1 7.73E+00 E
P CFS-L06-1315-T07-C 1 8.10E+00 E
P CFS-L06-1315-T08-C 1 6.43E+00 E
P CFS-L06-1315-T09-C 1 7.24E+00 E
P CFS-L06-1315-M01-A 1 1.85E+00 U1/2
P CFS-L06-1315-M02-A 1 1.85E+00 U1/2
P CFS-L06-1315-M03-A 1 1.85E+00 U1/2
P CFS-L06-1315-M04-A 1 1.85E+00 U1/2
P CFS-L06-1315-M05-A 1 1.85E+00 U1/2
P CFS-L06-1315-M06-A 1 1.85E+00 U1/2
P CFS-L06-1315-M07-A 1 1.85E+00 U1/2
P CFS-L06-1315-M08-A 1 1.85E+00 U1/2
P CFS-L06-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.23E+00 9.42 3.70 11.80
8.99E+00 37.39 3.70 11.80
6.76E+00 17.10 3.70 11.80 10000 1000
9.36E+00 28.78 3.70 11.80
8.42E+00 10.64 3.70 11.80
4.10E+00 32.05 3.70 11.80
1.07E+01 6.32 3.70 11.80
8.34E+00 18.73 3.70 11.80
9.87E+00 12.90 3.70 11.80
3.87E+00 35.00 3.70 11.80
8.85E+00 28.53 3.70 11.80
1.23E+01 3.40 3.70 11.80 10000 1000
1.36E+01 2.85 3.70 11.80
1.03E+01 11.97 3.70 11.80
7.36E+00 12.06 3.70 11.80
5.78E+00 5.40 3.70 11.80
4.22E+00 39.45 3.70 11.80
7.20E+00 22.17 3.70 11.80
5.44E+00 13.03 3.70 11.80
1.07E+01 4.30 3.70 11.80
1.02E+01 8.71 3.70 11.80 10000 1000
7.02E+00 28.18 3.70 11.80
5.38E+00 5.26 3.70 11.80
7.73E+00 31.68 3.70 11.80
8.10E+00 32.25 3.70 11.80
6.43E+00 17.05 3.70 11.80
7.24E+00 25.29 3.70 11.80
1.85E+00 53.11 3.70 11.80
1.85E+00 45.76 3.70 11.80
1.85E+00 21.26 3.70 11.80
1.85E+00 10.61 3.70 11.80
1.85E+00 10.27 3.70 11.80
1.85E+00 31.86 3.70 11.80
1.85E+00 42.50 3.70 11.80
1.85E+00 28.71 3.70 11.80
1.85E+00 22.84 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.88E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.93E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.55E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 131 5 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-834
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
ug/L
K CFS-L06-1315-T01-A 1 4.28E+02
K CFS-L06-1315-T02-A 1 2.07E+03
K CFS-L06-1315-T03-A 1 1.90E+03
K CFS-L06-1315-T04-A 1 5.57E+03
K CFS-L06-1315-T05-A 1 6.38E+03
K CFS-L06-1315-T06-A 1 9.06E+03
K CFS-L06-1315-T07-A 1 7.28E+03
K CFS-L06-1315-T08-A 1 3.33E+03
K CFS-L06-1315-T09-A 1 5.50E+03
K CFS-L06-1315-T01-B 1 2.87E+02
K CFS-L06-1315-T02-B 1 1.98E+03
K CFS-L06-1315-T03-B 1 1.80E+03
K CFS-L06-1315-T04-B 1 5.44E+03
K CFS-L06-1315-T05-B 1 6.32E+03
K CFS-L06-1315-T06-B 1 9.01 E+03
K CFS-L06-1315-T07-B 1 7.47E+03
K CFS-L06-1315-T08-B 1 3.50E+03
K CFS-L06-1315-T09-B 1 5.48E+03
K CFS-L06-1315-T01-C 1 2.82E+02
K CFS-L06-1315-T02-C 1 2.02E+03
K CFS-L06-1315-T03-C 1 1.70E+03
K CFS-L06-1315-T04-C 1 5.10E+03
K CFS-L06-1315-T05-C 1 5.99E+03
K CFS-L06-1315-T06-C 1 8.72E+03
K CFS-L06-1315-T07-C 1 7.06E+03
K CFS-L06-1315-T08-C 1 3.39E+03
K CFS-L06-1315-T09-C 1 5.35E+03
K CFS-L06-1315-M01-A 1 4.22E+01
K CFS-L06-1315-M02-A 1 4.61 E+01
K CFS-L06-1315-M03-A 1 2.48E+01
K CFS-L06-1315-M04-A 1 3.23E+01
K CFS-L06-1315-M05-A 1 4.38E+01
K CFS-L06-1315-M06-A 1 4.90E+01
K CFS-L06-1315-M07-A 1 2.72E+01
K CFS-L06-1315-M08-A 1 2.69E+01
K CFS-L06-1315-M09-A 1 1.80E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.28E+02 0.68 1.60 5.09
2.07E+03 1.58 1.60 5.09
1.90E+03 2.22 1.60 5.09 10000 1000
5.57E+03 2.04 1.60 5.09
6.38E+03 1.22 1.60 5.09
9.06E+03 0.90 1.60 5.09
7.28E+03 1.44 1.60 5.09
3.33E+03 1.07 1.60 5.09
5.50E+03 1.22 1.60 5.09
2.87E+02 1.18 1.60 5.09
1.98E+03 1.50 1.60 5.09
1.80E+03 2.11 1.60 5.09 10000 1000
5.44E+03 2.49 1.60 5.09
6.32E+03 0.97 1.60 5.09
9.01E+03 1.12 1.60 5.09
7.47E+03 0.67 1.60 5.09
3.50E+03 1.35 1.60 5.09
5.48E+03 1.05 1.60 5.09
2.82E+02 1.46 1.60 5.09
2.02E+03 1.06 1.60 5.09
1.70E+03 6.61 1.60 5.09 10000 1000
5.10E+03 0.94 1.60 5.09
5.99E+03 0.92 1.60 5.09
8.72E+03 1.62 1.60 5.09
7.06E+03 3.68 1.60 5.09
3.39E+03 1.69 1.60 5.09
5.35E+03 0.34 1.60 5.09
4.22E+01 4.93 1.60 5.09
4.61 E+01 4.59 1.60 5.09
2.48E+01 4.92 1.60 5.09
3.23E+01 2.22 1.60 5.09
4.38E+01 2.27 1.60 5.09
4.90E+01 3.17 1.60 5.09
2.72E+01 4.31 1.60 5.09
2.69E+01 6.06 1.60 5.09
1.80E+01 9.65 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.85E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.86E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.64E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-835
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L
Se CFS-L06-1315-T01-A 1 1.93E+01 E
Se CFS-L06-1315-T02-A 1 2.54E+01 E
Se CFS-L06-1315-T03-A 1 3.28E+01 E
Se CFS-L06-1315-T04-A 1 5.21E+01
Se CFS-L06-1315-T05-A 1 5.32E+01
Se CFS-L06-1315-T06-A 1 7.63E+01
Se CFS-L06-1315-T07-A 1 6.23E+01
Se CFS-L06-1315-T08-A 1 2.86E+01 E
Se CFS-L06-1315-T09-A 1 3.18E+01 E
Se CFS-L06-1315-T01-B 1 1.84E+01 E
Se CFS-L06-1315-T02-B 1 2.35E+01 E
Se CFS-L06-1315-T03-B 1 3.07E+01 E
Se CFS-L06-1315-T04-B 1 4.11E+01 E
Se CFS-L06-1315-T05-B 1 5.21E+01
Se CFS-L06-1315-T06-B 1 7.74E+01
Se CFS-L06-1315-T07-B 1 5.30E+01
Se CFS-L06-1315-T08-B 1 2.43E+01 E
Se CFS-L06-1315-T09-B 1 2.38E+01 E
Se CFS-L06-1315-T01-C 1 1.85E+01 E
Se CFS-L06-1315-T02-C 1 2.38E+01 E
Se CFS-L06-1315-T03-C 1 3.03E+01 E
Se CFS-L06-1315-T04-C 1 4.12E+01 E
Se CFS-L06-1315-T05-C 1 4.83E+01
Se CFS-L06-1315-T06-C 1 7.41E+01
Se CFS-L06-1315-T07-C 1 7.42E+01
Se CFS-L06-1315-T08-C 1 1.65E+01 E
Se CFS-L06-1315-T09-C 1 3.43E+01 E
Se CFS-L06-1315-M01-A 1 7.50E+00 U1/2
Se CFS-L06-1315-M02-A 1 7.50E+00 U1/2
Se CFS-L06-1315-M03-A 1 7.50E+00 U1/2
Se CFS-L06-1315-M04-A 1 7.50E+00 U1/2
Se CFS-L06-1315-M05-A 1 7.50E+00 U1/2
Se CFS-L06-1315-M06-A 1 7.50E+00 U1/2
Se CFS-L06-1315-M07-A 1 7.50E+00 U1/2
Se CFS-L06-1315-M08-A 1 7.50E+00 U1/2
Se CFS-L06-1315-M09-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.93E+01 10.36 15.00 47.70
2.54E+01 7.51 15.00 47.70
3.28E+01 6.70 15.00 47.70 10000 1000
5.21E+01 1.32 15.00 47.70
5.32E+01 3.62 15.00 47.70
7.63E+01 6.27 15.00 47.70
6.23E+01 14.27 15.00 47.70
2.86E+01 19.76 15.00 47.70
3.18E+01 11.70 15.00 47.70
1.84E+01 5.20 15.00 47.70
2.35E+01 18.88 15.00 47.70
3.07E+01 8.97 15.00 47.70 10000 1000
4.11E+01 10.51 15.00 47.70
5.21E+01 1.36 15.00 47.70
7.74E+01 1.24 15.00 47.70
5.30E+01 9.03 15.00 47.70
2.43E+01 14.66 15.00 47.70
2.38E+01 23.11 15.00 47.70
1.85E+01 22.16 15.00 47.70
2.38E+01 15.62 15.00 47.70
3.03E+01 3.14 15.00 47.70 10000 1000
4.12E+01 8.24 15.00 47.70
4.83E+01 1.76 15.00 47.70
7.41E+01 5.11 15.00 47.70
7.42E+01 6.10 15.00 47.70
1.65E+01 19.33 15.00 47.70
3.43E+01 9.50 15.00 47.70
7.50E+00 26.56 15.00 47.70
7.50E+00 60.40 15.00 47.70
7.50E+00 6.15 15.00 47.70
7.50E+00 57.16 15.00 47.70
7.50E+00 15.77 15.00 47.70
7.50E+00 29.82 15.00 47.70
7.50E+00 20.88 15.00 47.70
7.50E+00 74.85 15.00 47.70
7.50E+00 70.62 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.32E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.98E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.41 E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-836
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
Si CFS-L06-1315-T01-A 1 8.73E+01
Si CFS-L06-1315-T02-A 1 3.65E+02
Si CFS-L06-1315-T03-A 1 4.01 E+02
Si CFS-L06-1315-T04-A 1 7.47E+02
Si CFS-L06-1315-T05-A 1 9.98E+02
Si CFS-L06-1315-T06-A 1 1.47E+03
Si CFS-L06-1315-T07-A 1 1.37E+03
Si CFS-L06-1315-T08-A 1 7.19E+02
Si CFS-L06-1315-T09-A 1 1.22E+03
Si CFS-L06-1315-T01-B 1 7.51E+01
Si CFS-L06-1315-T02-B 1 3.07E+02
Si CFS-L06-1315-T03-B 1 3.17E+02
Si CFS-L06-1315-T04-B 1 7.62E+02
Si CFS-L06-1315-T05-B 1 1.03E+03
Si CFS-L06-1315-T06-B 1 1.52E+03
Si CFS-L06-1315-T07-B 1 1.42E+03
Si CFS-L06-1315-T08-B 1 7.82E+02
Si CFS-L06-1315-T09-B 1 1.27E+03
Si CFS-L06-1315-T01-C 1 7.98E+01
Si CFS-L06-1315-T02-C 1 3.37E+02
Si CFS-L06-1315-T03-C 1 2.73E+02
Si CFS-L06-1315-T04-C 1 8.55E+02
Si CFS-L06-1315-T05-C 1 1.06E+03
Si CFS-L06-1315-T06-C 1 1.62E+03
Si CFS-L06-1315-T07-C 1 1.50E+03
Si CFS-L06-1315-T08-C 1 8.40E+02
Si CFS-L06-1315-T09-C 1 1.36E+03
Si CFS-L06-1315-M01-A 1 3.08E+01
Si CFS-L06-1315-M02-A 1 4.40E+01
Si CFS-L06-1315-M03-A 1 3.58E+01
Si CFS-L06-1315-M04-A 1 3.22E+01
Si CFS-L06-1315-M05-A 1 2.79E+01
Si CFS-L06-1315-M06-A 1 3.91 E+01
Si CFS-L06-1315-M07-A 1 2.48E+01
Si CFS-L06-1315-M08-A 1 2.21E+01
Si CFS-L06-1315-M09-A 1 1.76E+01
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.73E+01 2.71 1.10 3.50
3.65E+02 1.53 1.10 3.50
4.01E+02 2.25 1.10 3.50 10000 1000
7.47E+02 1.97 1.10 3.50
9.98E+02 0.54 1.10 3.50
1.47E+03 1.31 1.10 3.50
1.37E+03 2.16 1.10 3.50
7.19E+02 1.51 1.10 3.50
1.22E+03 1.82 1.10 3.50
7.51 E+01 4.83 1.10 3.50
3.07E+02 1.00 1.10 3.50
3.17E+02 2.89 1.10 3.50 10000 1000
7.62E+02 2.19 1.10 3.50
1.03E+03 0.18 1.10 3.50
1.52E+03 1.45 1.10 3.50
1.42E+03 0.66 1.10 3.50
7.82E+02 2.30 1.10 3.50
1.27E+03 1.10 1.10 3.50
7.98E+01 2.92 1.10 3.50
3.37E+02 1.42 1.10 3.50
2.73E+02 6.51 1.10 3.50 10000 1000
8.55E+02 1.00 1.10 3.50
1.06E+03 0.99 1.10 3.50
1.62E+03 1.85 1.10 3.50
1.50E+03 4.28 1.10 3.50
8.40E+02 1.74 1.10 3.50
1.36E+03 0.45 1.10 3.50
3.08E+01 4.34 1.10 3.50
4.40E+01 2.58 1.10 3.50
3.58E+01 1.73 1.10 3.50
3.22E+01 1.36 1.10 3.50
2.79E+01 2.29 1.10 3.50
3.91 E+01 1.40 1.10 3.50
2.48E+01 3.87 1.10 3.50
2.21E+01 9.18 1.10 3.50
1.76E+01 1.08 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.34E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.31E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.27E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-837
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Na CFS-L06-1315-T01-A 1 2.20E+03
Na CFS-L06-1315-T02-A 1 8.74E+03
Na CFS-L06-1315-T03-A 1 7.95E+03
Na CFS-L06-1315-T04-A 1 2.19E+04
Na CFS-L06-1315-T05-A 1 2.29E+04
Na CFS-L06-1315-T06-A 1 3.09E+04
Na CFS-L06-1315-T07-A 1 2.35E+04
Na CFS-L06-1315-T08-A 1 1.01E+04
Na CFS-L06-1315-T09-A 1 1.59E+04
Na CFS-L06-1315-T01-B 1 1.58E+03
Na CFS-L06-1315-T02-B 1 8.38E+03
Na CFS-L06-1315-T03-B 1 7.56E+03
Na CFS-L06-1315-T04-B 1 2.17E+04
Na CFS-L06-1315-T05-B 1 2.31 E+04
Na CFS-L06-1315-T06-B 1 3.20E+04
Na CFS-L06-1315-T07-B 1 2. 51 E+04
Na CFS-L06-1315-T08-B 1 1.11 E+04
Na CFS-L06-1315-T09-B 1 1.67E+04
Na CFS-L06-1315-T01-C 1 1.74E+03
Na CFS-L06-1315-T02-C 1 8.76E+03
Na CFS-L06-1315-T03-C 1 7.05E+03
Na CFS-L06-1315-T04-C 1 2.05E+04
Na CFS-L06-1315-T05-C 1 2.21E+04
Na CFS-L06-1315-T06-C 1 3.10E+04
Na CFS-L06-1315-T07-C 1 2.43E+04
Na CFS-L06-1315-T08-C 1 1.09E+04
Na CFS-L06-1315-T09-C 1 1.68E+04
Na CFS-L06-1315-M01-A 1 3.64E+01
Na CFS-L06-1315-M02-A 1 1.99E+01
Na CFS-L06-1315-M03-A 1 1.04E+01
Na CFS-L06-1315-M04-A 1 2.64E+01
Na CFS-L06-1315-M05-A 1 3.28E+01
Na CFS-L06-1315-M06-A 1 3.54E+01
Na CFS-L06-1315-M07-A 1 1.10E+01
Na CFS-L06-1315-M08-A 1 1.51E+01
Na CFS-L06-1315-M09-A 1 9.39E+00
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.20E+03 0.15 2.50 8.00
8.74E+03 0.10 2.50 8.00
7.95E+03 0.56 2.50 8.00 10000 1000
2.19E+04 1.48 2.50 8.00
2.29E+04 0.40 2.50 8.00
3.09E+04 0.21 2.50 8.00
2.35E+04 0.49 2.50 8.00
1.01 E+04 0.51 2.50 8.00
1.59E+04 0.59 2.50 8.00
1.58E+03 0.83 2.50 8.00
8.38E+03 0.41 2.50 8.00
7.56E+03 0.21 2.50 8.00 10000 1000
2.17E+04 0.16 2.50 8.00
2.31E+04 0.18 2.50 8.00
3.20E+04 0.69 2.50 8.00
2. 51 E+04 0.67 2.50 8.00
1.11 E+04 0.37 2.50 8.00
1.67E+04 1.08 2.50 8.00
1.74E+03 0.62 2.50 8.00
8.76E+03 0.33 2.50 8.00
7.05E+03 3.58 2.50 8.00 10000 1000
2.05E+04 0.52 2.50 8.00
2.21 E+04 0.64 2.50 8.00
3.10E+04 0.46 2.50 8.00
2.43E+04 0.80 2.50 8.00
1.09E+04 0.49 2.50 8.00
1.68E+04 1.05 2.50 8.00
3.64E+01 0.94 2.50 8.00
1.99E+01 1.77 2.50 8.00
1.04E+01 1.80 2.50 8.00
2.64E+01 3.56 2.50 8.00
3.28E+01 1.92 2.50 8.00
3.54E+01 2.28 2.50 8.00
1.10E+01 1.57 2.50 8.00
1.51E+01 0.97 2.50 8.00
9.39E+00 0.92 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.83E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.46E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.97E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-838
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Sr CFS-L06-1315-T01-A 1 1.93E+01
Sr CFS-L06-1315-T02-A 1 8.96E+01
Sr CFS-L06-1315-T03-A 1 9.81 E+01
Sr CFS-L06-1315-T04-A 1 2.90E+02
Sr CFS-L06-1315-T05-A 1 3.81 E+02
Sr CFS-L06-1315-T06-A 1 6.25E+02
Sr CFS-L06-1315-T07-A 1 6.08E+02
Sr CFS-L06-1315-T08-A 1 3.28E+02
Sr CFS-L06-1315-T09-A 1 5.70E+02
Sr CFS-L06-1315-T01-B 1 1.40E+01
Sr CFS-L06-1315-T02-B 1 9.20E+01
Sr CFS-L06-1315-T03-B 1 9.75E+01
Sr CFS-L06-1315-T04-B 1 3.06E+02
Sr CFS-L06-1315-T05-B 1 4.08E+02
Sr CFS-L06-1315-T06-B 1 6.54E+02
Sr CFS-L06-1315-T07-B 1 6.49E+02
Sr CFS-L06-1315-T08-B 1 3.60E+02
Sr CFS-L06-1315-T09-B 1 5.79E+02
Sr CFS-L06-1315-T01-C 1 1.53E+01
Sr CFS-L06-1315-T02-C 1 1.02E+02
Sr CFS-L06-1315-T03-C 1 9.56E+01
Sr CFS-L06-1315-T04-C 1 2.87E+02
Sr CFS-L06-1315-T05-C 1 3.73E+02
Sr CFS-L06-1315-T06-C 1 6.04E+02
Sr CFS-L06-1315-T07-C 1 5.97E+02
Sr CFS-L06-1315-T08-C 1 3.40E+02
Sr CFS-L06-1315-T09-C 1 5.48E+02
Sr CFS-L06-1315-M01-A 1 5.00E-01 U1/2
Sr CFS-L06-1315-M02-A 1 5.00E-01 U1/2
Sr CFS-L06-1315-M03-A 1 5.00E-01 U1/2
Sr CFS-L06-1315-M04-A 1 5.00E-01 U1/2
Sr CFS-L06-1315-M05-A 1 5.00E-01 U1/2
Sr CFS-L06-1315-M06-A 1 5.00E-01 U1/2
Sr CFS-L06-1315-M07-A 1 5.00E-01 U1/2
Sr CFS-L06-1315-M08-A 1 5.00E-01 U1/2
Sr CFS-L06-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.93E+01 4.27 1.00 3.18
8.96E+01 1.39 1.00 3.18
9.81E+01 2.05 1.00 3.18 10000 1000
2.90E+02 2.50 1.00 3.18
3.81E+02 0.79 1.00 3.18
6.25E+02 1.24 1.00 3.18
6.08E+02 1.26 1.00 3.18
3.28E+02 0.88 1.00 3.18
5.70E+02 0.74 1.00 3.18
1.40E+01 4.36 1.00 3.18
9.20E+01 2.43 1.00 3.18
9.75E+01 1.86 1.00 3.18 10000 1000
3.06E+02 2.68 1.00 3.18
4.08E+02 0.58 1.00 3.18
6.54E+02 1.72 1.00 3.18
6.49E+02 1.49 1.00 3.18
3.60E+02 0.98 1.00 3.18
5.79E+02 0.76 1.00 3.18
1.53E+01 4.58 1.00 3.18
1.02E+02 0.45 1.00 3.18
9.56E+01 6.06 1.00 3.18 10000 1000
2.87E+02 1.13 1.00 3.18
3.73E+02 0.73 1.00 3.18
6.04E+02 2.22 1.00 3.18
5.97E+02 4.24 1.00 3.18
3.40E+02 2.16 1.00 3.18
5.48E+02 0.20 1.00 3.18
5.00E-01 12.31 1.00 3.18
5.00E-01 11.99 1.00 3.18
5.00E-01 24.07 1.00 3.18
5.00E-01 36.27 1.00 3.18
5.00E-01 24.53 1.00 3.18
5.00E-01 30.05 1.00 3.18
5.00E-01 1.67 1.00 3.18
5.00E-01 27.47 1.00 3.18
5.00E-01 12.38 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.09E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-839
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
S CFS-L06-1315-T01-A 1 8.36E+03
S CFS-L06-1315-T02-A 1 3.67E+04
S CFS-L06-1315-T03-A 1 3.98E+04
S CFS-L06-1315-T04-A 1 1.15E+05
S CFS-L06-1315-T05-A 1 1.40E+05
S CFS-L06-1315-T06-A 1 2.09E+05
S CFS-L06-1315-T07-A 1 1.85E+05
S CFS-L06-1315-T08-A 1 9.56E+04
S CFS-L06-1315-T09-A 1 1.63E+05
S CFS-L06-1315-T01-B 1 5.72E+03
S CFS-L06-1315-T02-B 1 3.52E+04
S CFS-L06-1315-T03-B 1 3.71E+04
S CFS-L06-1315-T04-B 1 1.12E+05
S CFS-L06-1315-T05-B 1 1.40E+05
S CFS-L06-1315-T06-B 1 2.09E+05
S CFS-L06-1315-T07-B 1 1.92E+05
S CFS-L06-1315-T08-B 1 1.03E+05
S CFS-L06-1315-T09-B 1 1.64E+05
S CFS-L06-1315-T01-C 1 6.60E+03
S CFS-L06-1315-T02-C 1 4.02E+04
S CFS-L06-1315-T03-C 1 3.75E+04
S CFS-L06-1315-T04-C 1 1.09E+05
S CFS-L06-1315-T05-C 1 1.35E+05
S CFS-L06-1315-T06-C 1 2.04E+05
S CFS-L06-1315-T07-C 1 1.87E+05
S CFS-L06-1315-T08-C 1 1.02E+05
S CFS-L06-1315-T09-C 1 1.64E+05
S CFS-L06-1315-M01-A 1 3.40E+00 U1/2
S CFS-L06-1315-M02-A 1 3.40E+00 U1/2
S CFS-L06-1315-M03-A 1 3.40E+00 U1/2
S CFS-L06-1315-M04-A 1 3.40E+00 U1/2
S CFS-L06-1315-M05-A 1 3.40E+00 U1/2
S CFS-L06-1315-M06-A 1 3.40E+00 U1/2
S CFS-L06-1315-M07-A 1 3.40E+00 U1/2
S CFS-L06-1315-M08-A 1 3.40E+00 U1/2
S CFS-L06-1315-M09-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.36E+03 1.76 6.80 21.60
3.67E+04 1.82 6.80 21.60
3.98E+04 2.02 6.80 21.60 10000 1000
1.15E+05 2.04 6.80 21.60
1.40E+05 1.34 6.80 21.60
2.09E+05 1.09 6.80 21.60
1.85E+05 1.46 6.80 21.60
9.56E+04 1.13 6.80 21.60
1.63E+05 1.39 6.80 21.60
5.72E+03 1.22 6.80 21.60
3.52E+04 1.00 6.80 21.60
3.71E+04 2.31 6.80 21.60 10000 1000
1.12E+05 2.44 6.80 21.60
1.40E+05 0.86 6.80 21.60
2.09E+05 1.32 6.80 21.60
1.92E+05 0.89 6.80 21.60
1.03E+05 1.06 6.80 21.60
1.64E+05 0.84 6.80 21.60
6.60E+03 0.47 6.80 21.60
4.02E+04 0.58 6.80 21.60
3.75E+04 6.25 6.80 21.60 10000 1000
1.09E+05 1.11 6.80 21.60
1.35E+05 0.94 6.80 21.60
2.04E+05 2.02 6.80 21.60
1.87E+05 3.91 6.80 21.60
1.02E+05 1.66 6.80 21.60
1.64E+05 0.38 6.80 21.60
3.40E+00 8.65 6.80 21.60
3.40E+00 4.57 6.80 21.60
3.40E+00 3.51 6.80 21.60
3.40E+00 2.55 6.80 21.60
3.40E+00 12.93 6.80 21.60
3.40E+00 1.62 6.80 21.60
3.40E+00 2.08 6.80 21.60
3.40E+00 7.64 6.80 21.60
3.40E+00 2.43 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.06E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.80E+04 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.84E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-840
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Tl CFS-L06-1315-T01-A 1 4.94E+00 E
Tl CFS-L06-1315-T02-A 1 5.51 E+01
Tl CFS-L06-1315-T03-A 1 6.19E+01
Tl CFS-L06-1315-T04-A 1 1.72E+02
Tl CFS-L06-1315-T05-A 1 2.13E+02
Tl CFS-L06-1315-T06-A 1 2.81 E+02
Tl CFS-L06-1315-T07-A 1 2. 41 E+02
Tl CFS-L06-1315-T08-A 1 1.26E+02
Tl CFS-L06-1315-T09-A 1 1.97E+02
Tl CFS-L06-1315-T01-B 1 4.72E+00 E
Tl CFS-L06-1315-T02-B 1 5.38E+01
Tl CFS-L06-1315-T03-B 1 5.84E+01
Tl CFS-L06-1315-T04-B 1 1.60E+02
Tl CFS-L06-1315-T05-B 1 2.03E+02
Tl CFS-L06-1315-T06-B 1 2.76E+02
Tl CFS-L06-1315-T07-B 1 2.40E+02
Tl CFS-L06-1315-T08-B 1 1.28E+02
Tl CFS-L06-1315-T09-B 1 1.93E+02
Tl CFS-L06-1315-T01-C 1 5.01E+00 E
Tl CFS-L06-1315-T02-C 1 5.64E+01
Tl CFS-L06-1315-T03-C 1 5.29E+01
Tl CFS-L06-1315-T04-C 1 1.57E+02
Tl CFS-L06-1315-T05-C 1 1.92E+02
Tl CFS-L06-1315-T06-C 1 2.77E+02
Tl CFS-L06-1315-T07-C 1 2.37E+02
Tl CFS-L06-1315-T08-C 1 1.27E+02
Tl CFS-L06-1315-T09-C 1 1.92E+02
Tl CFS-L06-1315-M01-A 1 2.30E+00 U1/2
Tl CFS-L06-1315-M02-A 1 2.30E+00 U1/2
Tl CFS-L06-1315-M03-A 1 2.30E+00 U1/2
Tl CFS-L06-1315-M04-A 1 2.30E+00 U1/2
Tl CFS-L06-1315-M05-A 1 2.30E+00 U1/2
Tl CFS-L06-1315-M06-A 1 2.30E+00 U1/2
Tl CFS-L06-1315-M07-A 1 2.30E+00 U1/2
Tl CFS-L06-1315-M08-A 1 2.30E+00 U1/2
Tl CFS-L06-1315-M09-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.94E+00 17.23 4.60 14.60
5.51E+01 1.79 4.60 14.60
6.19E+01 9.36 4.60 14.60 10000 1000
1.72E+02 4.03 4.60 14.60
2.13E+02 2.12 4.60 14.60
2.81E+02 3.07 4.60 14.60
2.41E+02 3.22 4.60 14.60
1.26E+02 1.58 4.60 14.60
1.97E+02 0.37 4.60 14.60
4.72E+00 24.03 4.60 14.60
5.38E+01 8.00 4.60 14.60
5.84E+01 6.93 4.60 14.60 10000 1000
1.60E+02 2.54 4.60 14.60
2.03E+02 1.42 4.60 14.60
2.76E+02 1.51 4.60 14.60
2.40E+02 1.35 4.60 14.60
1.28E+02 1.90 4.60 14.60
1.93E+02 0.16 4.60 14.60
5.01E+00 27.85 4.60 14.60
5.64E+01 5.80 4.60 14.60
5.29E+01 5.81 4.60 14.60 10000 1000
1.57E+02 2.75 4.60 14.60
1.92E+02 1.43 4.60 14.60
2.77E+02 3.51 4.60 14.60
2.37E+02 3.31 4.60 14.60
1.27E+02 3.77 4.60 14.60
1.92E+02 1.82 4.60 14.60
2.30E+00 41.97 4.60 14.60
2.30E+00 22.96 4.60 14.60
2.30E+00 28.72 4.60 14.60
2.30E+00 18.24 4.60 14.60
2.30E+00 17.16 4.60 14.60
2.30E+00 32.04 4.60 14.60
2.30E+00 41.67 4.60 14.60
2.30E+00 14.25 4.60 14.60
2.30E+00 11.94 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.07E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-841
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ti CFS-L06-1315-T01-A 1 1.00E+00 U1/2
Ti CFS-L06-1315-T02-A 1 1.00E+00 U1/2
Ti CFS-L06-1315-T03-A 1 1.00E+00 U1/2
Ti CFS-L06-1315-T04-A 1 1.00E+00 U1/2
Ti CFS-L06-1315-T05-A 1 1.00E+00 U1/2
Ti CFS-L06-1315-T06-A 1 1.00E+00 U1/2
Ti CFS-L06-1315-T07-A 1 1.00E+00 U1/2
Ti CFS-L06-1315-T08-A 1 1.00E+00 U1/2
Ti CFS-L06-1315-T09-A 1 1.00E+00 U1/2
Ti CFS-L06-1315-T01-B 1 1.00E+00 U1/2
Ti CFS-L06-1315-T02-B 1 1.00E+00 U1/2
Ti CFS-L06-1315-T03-B 1 1.00E+00 U1/2
Ti CFS-L06-1315-T04-B 1 1.00E+00 U1/2
Ti CFS-L06-1315-T05-B 1 1.00E+00 U1/2
Ti CFS-L06-1315-T06-B 1 1.00E+00 U1/2
Ti CFS-L06-1315-T07-B 1 1.00E+00 U1/2
Ti CFS-L06-1315-T08-B 1 1.00E+00 U1/2
Ti CFS-L06-1315-T09-B 1 1.00E+00 U1/2
Ti CFS-L06-1315-T01-C 1 1.00E+00 U1/2
Ti CFS-L06-1315-T02-C 1 1.00E+00 U1/2
Ti CFS-L06-1315-T03-C 1 1.00E+00 U1/2
Ti CFS-L06-1315-T04-C 1 1.00E+00 U1/2
Ti CFS-L06-1315-T05-C 1 1.00E+00 U1/2
Ti CFS-L06-1315-T06-C 1 1.00E+00 U1/2
Ti CFS-L06-1315-T07-C 1 1.00E+00 U1/2
Ti CFS-L06-1315-T08-C 1 1.00E+00 U1/2
Ti CFS-L06-1315-T09-C 1 1.00E+00 U1/2
Ti CFS-L06-1315-M01-A 1 1.00E+00 U1/2
Ti CFS-L06-1315-M02-A 1 1.00E+00 U1/2
Ti CFS-L06-1315-M03-A 1 1.00E+00 U1/2
Ti CFS-L06-1315-M04-A 1 1.00E+00 U1/2
Ti CFS-L06-1315-M05-A 1 1.00E+00 U1/2
Ti CFS-L06-1315-M06-A 1 1.00E+00 U1/2
Ti CFS-L06-1315-M07-A 1 1.00E+00 U1/2
Ti CFS-L06-1315-M08-A 1 1.00E+00 U1/2
Ti CFS-L06-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 15.10 2.00 6.40
1.00E+00 32.87 2.00 6.40
1.00E+00 66.60 2.00 6.40 10000 1000
1.00E+00 56.03 2.00 6.40
1.00E+00 29.65 2.00 6.40
1.00E+00 56.54 2.00 6.40
1.00E+00 30.07 2.00 6.40
1.00E+00 14.66 2.00 6.40
1.00E+00 62.25 2.00 6.40
1.00E+00 27.44 2.00 6.40
1.00E+00 27.00 2.00 6.40
1.00E+00 11.33 2.00 6.40 10000 1000
1.00E+00 66.82 2.00 6.40
1.00E+00 40.00 2.00 6.40
1.00E+00 16.93 2.00 6.40
1.00E+00 32.94 2.00 6.40
1.00E+00 17.71 2.00 6.40
1.00E+00 40.63 2.00 6.40
1.00E+00 8.18 2.00 6.40
1.00E+00 44.15 2.00 6.40
1.00E+00 30.81 2.00 6.40 10000 1000
1.00E+00 50.47 2.00 6.40
1.00E+00 21.04 2.00 6.40
1.00E+00 56.99 2.00 6.40
1.00E+00 40.56 2.00 6.40
1.00E+00 22.91 2.00 6.40
1.00E+00 14.91 2.00 6.40
1.00E+00 11.22 2.00 6.40
1.00E+00 20.88 2.00 6.40
1.00E+00 5.30 2.00 6.40
1.00E+00 15.56 2.00 6.40
1.00E+00 45.70 2.00 6.40
1.00E+00 18.73 2.00 6.40
1.00E+00 9.19 2.00 6.40
1.00E+00 11.68 2.00 6.40
1.00E+00 3.88 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.96E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.50E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-842
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
V CFS-L06-1315-T01-A 1 2.17E+00 E
V CFS-L06-1315-T02-A 1 2.41 E+00 E
V CFS-L06-1315-T03-A 1 3.25E+00 E
V CFS-L06-1315-T04-A 1 3.63E+00 E
V CFS-L06-1315-T05-A 1 4.41E+00 E
V CFS-L06-1315-T06-A 1 8.15E+00
V CFS-L06-1315-T07-A 1 6.87E+00
V CFS-L06-1315-T08-A 1 3.57E+00 E
V CFS-L06-1315-T09-A 1 5.70E+00
V CFS-L06-1315-T01-B 1 1.94E+00 E
V CFS-L06-1315-T02-B 1 2.65E+00 E
V CFS-L06-1315-T03-B 1 3.39E+00 E
V CFS-L06-1315-T04-B 1 3.89E+00 E
V CFS-L06-1315-T05-B 1 5.43E+00
V CFS-L06-1315-T06-B 1 7.32E+00
V CFS-L06-1315-T07-B 1 6.52E+00
V CFS-L06-1315-T08-B 1 4.08E+00 E
V CFS-L06-1315-T09-B 1 5.75E+00
V CFS-L06-1315-T01-C 1 2.02E+00 E
V CFS-L06-1315-T02-C 1 2.55E+00 E
V CFS-L06-1315-T03-C 1 3.79E+00 E
V CFS-L06-1315-T04-C 1 4.10E+00 E
V CFS-L06-1315-T05-C 1 5.39E+00
V CFS-L06-1315-T06-C 1 6.69E+00
V CFS-L06-1315-T07-C 1 6.96E+00
V CFS-L06-1315-T08-C 1 5.12E+00
V CFS-L06-1315-T09-C 1 6.23E+00
V CFS-L06-1315-M01-A 1 7.50E-01 U1/2
V CFS-L06-1315-M02-A 1 7.50E-01 U1/2
V CFS-L06-1315-M03-A 1 7.50E-01 U1/2
V CFS-L06-1315-M04-A 1 7.50E-01 U1/2
V CFS-L06-1315-M05-A 1 7.50E-01 U1/2
V CFS-L06-1315-M06-A 1 7.50E-01 U1/2
V CFS-L06-1315-M07-A 1 7.50E-01 U1/2
V CFS-L06-1315-M08-A 1 7.50E-01 U1/2
V CFS-L06-1315-M09-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.17E+00 27.13 1.50 4.77
2.41 E+00 6.21 1.50 4.77
3.25E+00 12.08 1.50 4.77 10000 1000
3.63E+00 25.48 1.50 4.77
4.41E+00 18.36 1.50 4.77
8.15E+00 10.61 1.50 4.77
6.87E+00 4.12 1.50 4.77
3.57E+00 5.49 1.50 4.77
5.70E+00 9.96 1.50 4.77
1.94E+00 27.22 1.50 4.77
2.65E+00 22.65 1.50 4.77
3.39E+00 16.43 1.50 4.77 10000 1000
3.89E+00 4.35 1.50 4.77
5.43E+00 6.45 1.50 4.77
7.32E+00 7.95 1.50 4.77
6.52E+00 1.25 1.50 4.77
4.08E+00 22.60 1.50 4.77
5.75E+00 2.54 1.50 4.77
2.02E+00 8.64 1.50 4.77
2.55E+00 9.26 1.50 4.77
3.79E+00 13.87 1.50 4.77 10000 1000
4.10E+00 11.72 1.50 4.77
5.39E+00 2.14 1.50 4.77
6.69E+00 7.42 1.50 4.77
6.96E+00 4.24 1.50 4.77
5.12E+00 5.11 1.50 4.77
6.23E+00 4.65 1.50 4.77
7.50E-01 40.04 1.50 4.77
7.50E-01 23.76 1.50 4.77
7.50E-01 41.11 1.50 4.77
7.50E-01 18.96 1.50 4.77
7.50E-01 36.32 1.50 4.77
7.50E-01 22.32 1.50 4.77
7.50E-01 17.18 1.50 4.77
7.50E-01 27.00 1.50 4.77
7.50E-01 31.93 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.13E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.72E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.04E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-843
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Zn CFS-L06-1315-T01-A 1 2.27E+02
Zn CFS-L06-1315-T02-A 1 1.23E+03
Zn CFS-L06-1315-T03-A 1 1.49E+03
Zn CFS-L06-1315-T04-A 1 4.17E+03
Zn CFS-L06-1315-T05-A 1 5.07E+03
Zn CFS-L06-1315-T06-A 1 7.58E+03
Zn CFS-L06-1315-T07-A 1 6.70E+03
Zn CFS-L06-1315-T08-A 1 3.43E+03
Zn CFS-L06-1315-T09-A 1 5.53E+03
Zn CFS-L06-1315-T01-B 1 1.68E+02
Zn CFS-L06-1315-T02-B 1 1.17E+03
Zn CFS-L06-1315-T03-B 1 1.31E+03
Zn CFS-L06-1315-T04-B 1 3.93E+03
Zn CFS-L06-1315-T05-B 1 4.94E+03
Zn CFS-L06-1315-T06-B 1 7.35E+03
Zn CFS-L06-1315-T07-B 1 6.67E+03
Zn CFS-L06-1315-T08-B 1 3.63E+03
Zn CFS-L06-1315-T09-B 1 5.80E+03
Zn CFS-L06-1315-T01-C 1 1.95E+02
Zn CFS-L06-1315-T02-C 1 1.47E+03
Zn CFS-L06-1315-T03-C 1 1.51E+03
Zn CFS-L06-1315-T04-C 1 4.57E+03
Zn CFS-L06-1315-T05-C 1 5.76E+03
Zn CFS-L06-1315-T06-C 1 8.67E+03
Zn CFS-L06-1315-T07-C 1 7.92E+03
Zn CFS-L06-1315-T08-C 1 4.26E+03
Zn CFS-L06-1315-T09-C 1 6.81 E+03
Zn CFS-L06-1315-M01-A 1 5.00E-01 U1/2
Zn CFS-L06-1315-M02-A 1 5.00E-01 U1/2
Zn CFS-L06-1315-M03-A 1 5.00E-01 U1/2
Zn CFS-L06-1315-M04-A 1 5.00E-01 U1/2
Zn CFS-L06-1315-M05-A 1 5.00E-01 U1/2
Zn CFS-L06-1315-M06-A 1 5.00E-01 U1/2
Zn CFS-L06-1315-M07-A 1 5.00E-01 U1/2
Zn CFS-L06-1315-M08-A 1 5.00E-01 U1/2
Zn CFS-L06-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.27E+02 1.21 1.00 3.18
1.23E+03 1.67 1.00 3.18
1.49E+03 1.95 1.00 3.18 10000 1000
4.17E+03 0.79 1.00 3.18
5.07E+03 1.04 1.00 3.18
7.58E+03 0.66 1.00 3.18
6.70E+03 1.61 1.00 3.18
3.43E+03 1.59 1.00 3.18
5.53E+03 16.62 1.00 3.18
1.68E+02 1.61 1.00 3.18
1.17E+03 1.66 1.00 3.18
1.31E+03 2.86 1.00 3.18 10000 1000
3.93E+03 0.87 1.00 3.18
4.94E+03 0.77 1.00 3.18
7.35E+03 1.38 1.00 3.18
6.67E+03 1.84 1.00 3.18
3.63E+03 0.80 1.00 3.18
5.80E+03 2.02 1.00 3.18
1.95E+02 0.66 1.00 3.18
1.47E+03 1.55 1.00 3.18
1.51E+03 1.10 1.00 3.18 10000 1000
4.57E+03 0.21 1.00 3.18
5.76E+03 0.33 1.00 3.18
8.67E+03 0.78 1.00 3.18
7.92E+03 3.06 1.00 3.18
4.26E+03 2.42 1.00 3.18
6.81E+03 0.61 1.00 3.18
5.00E-01 6.39 1.00 3.18
5.00E-01 2.51 1.00 3.18
5.00E-01 8.10 1.00 3.18
5.00E-01 1.80 1.00 3.18
5.00E-01 2.17 1.00 3.18
5.00E-01 2.59 1.00 3.18
5.00E-01 11.75 1.00 3.18
5.00E-01 1.64 1.00 3.18
5.00E-01 4.50 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.40E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.21E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.44E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 3:35 PM EPA Interlab L06 1315 CFS
9/12/11 3:36 PM EPA Interlab L06 1315 CFS
9/12/11 3:38 PM EPA Interlab L06 1315 CFS
9/12/11 3:39 PM EPA Interlab L06 1315 CFS
9/12/11 3:41 PM EPA Interlab L06 1315 CFS
9/12/11 3:43 PM EPA Interlab L06 1315 CFS
9/12/11 3:44 PM EPA Interlab L06 1315 CFS
9/12/11 3:46 PM EPA Interlab L06 1315 CFS
9/12/11 3:48 PM EPA Interlab L06 1315 CFS
9/12/11 3:54 PM EPA Interlab L06 1315 CFS
9/12/11 3:56 PM EPA Interlab L06 1315 CFS
9/12/11 3:58 PM EPA Interlab L06 1315 CFS
9/12/11 3:59 PM EPA Interlab L06 1315 CFS
9/12/11 4:01 PM EPA Interlab L06 1315 CFS
9/12/11 4:03 PM EPA Interlab L06 1315 CFS
9/12/11 4:04 PM EPA Interlab L06 1315 CFS
9/12/11 4:06 PM EPA Interlab L06 1315 CFS
9/12/11 4:07 PM EPA Interlab L06 1315 CFS
9/12/11 4:09 PM EPA Interlab L06 1315 CFS
9/12/11 4:11 PM EPA Interlab L06 1315 CFS
9/12/11 4:12 PM EPA Interlab L06 1315 CFS
9/12/11 4:14 PM EPA Interlab L06 1315 CFS
9/12/11 4:16 PM EPA Interlab L06 1315 CFS
9/12/11 4:17 PM EPA Interlab L06 1315 CFS
9/12/11 4:19 PM EPA Interlab L06 1315 CFS
9/12/11 4:21 PM EPA Interlab L06 1315 CFS
9/12/11 4:22 PM EPA Interlab L06 1315 CFS
9/12/11 3:20 PM EPA Interlab L06 1315 CFS
9/12/11 3:21 PM EPA Interlab L06 1315 CFS
9/12/11 3:23 PM EPA Interlab L06 1315 CFS
9/12/11 3:25 PM EPA Interlab L06 1315 CFS
9/12/11 3:26 PM EPA Interlab L06 1315 CFS
9/12/11 3:28 PM EPA Interlab L06 1315 CFS
9/12/11 3:30 PM EPA Interlab L06 1315 CFS
9/12/11 3:31 PM EPA Interlab L06 1315 CFS
9/12/11 3:33 PM EPA Interlab L06 1315 CFS
1-844
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1315:
Element Sample ID
Al CFS-L07-1315-T01-A
Al CFS-L07-1315-T02-A
Al CFS-L07-1315-T03-A
Al CFS-L07-1315-T04-A
Al CFS-L07-1315-T05-A
Al CFS-L07-1315-T06-A
Al CFS-L07-1315-T07-A
Al CFS-L07-1315-T08-A
Al CFS-L07-1315-T09-A
Al CFS-L07-1315-T01-B
Al CFS-L07-1315-T02-B
Al CFS-L07-1315-T03-B
Al CFS-L07-1315-T04-B
Al CFS-L07-1315-T05-B
Al CFS-L07-1315-T06-B
Al CFS-L07-1315-T07-B
Al CFS-L07-1315-T08-B
Al CFS-L07-1315-T09-B
Al CFS-L07-1315-T01-C
Al CFS-L07-1315-T02-C
Al CFS-L07-1315-T03-C
Al CFS-L07-1315-T04-C
Al CFS-L07-1315-T05-C
Al CFS-L07-1315-T06-C
Al CFS-L07-1315-T07-C
Al CFS-L07-1315-T08-C
Al CFS-L07-1315-T09-C
Al CFS-L07-1315-M01-A
Al CFS-L07-1315-M02-A
Al CFS-L07-1315-M03-A
Al CFS-L07-1315-M04-A
Al CFS-L07-1315-M05-A
Al CFS-L07-1315-M06-A
Al CFS-L07-1315-M07-A
Al CFS-L07-1315-M08-A
Al CFS-L07-1315-M09-A
Dilution Sample
Factor Cone. Qualifier
I ug/L I
1 7.06E+00
1 2.75E+01
1 2.61E+01
1 3.63E+01
1 4.09E+01
1 4.86E+01
1 4.76E+01
1 4.02E+01
1 4.43E+01
1 1.58E+01
1 2.15E+01
1 2.19E+01
1 3.73E+01
1 4.07E+01
1 5.02E+01
1 4.59E+01
1 3.47E+01
1 4.60E+01
1 9.17E+00
1 2.78E+01
1 2.26E+01
1 4.94E+01
1 4.73E+01
1 5.03E+01
1 4.65E+01
1 3.62E+01
1 4.42E+01
1 1.30E+OOE
1 1.13E+OOE
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 1.42E+OOE
1 1.38E+OOE
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.06E+00 1.54 1.00 3.18
2.75E+01 4.22 1.00 3.18
2.61E+01 2.49 1.00 3.18 10000 1000
3.63E+01 0.89 1.00 3.18
4.09E+01 1.74 1.00 3.18
4.86E+01 6.96 1.00 3.18
4.76E+01 5.15 1.00 3.18
4.02E+01 1.63 1.00 3.18
4.43E+01 1.19 1.00 3.18
1.58E+01 2.72 1.00 3.18
2.15E+01 6.23 1.00 3.18
2.19E+01 10.59 1.00 3.18 10000 1000
3.73E+01 6.89 1.00 3.18
4.07E+01 6.38 1.00 3.18
5.02E+01 2.13 1.00 3.18
4.59E+01 1.17 1.00 3.18
3.47E+01 1.37 1.00 3.18
4.60E+01 6.38 1.00 3.18
9.17E+00 10.02 1.00 3.18
2.78E+01 6.30 1.00 3.18
2.26E+01 7.51 1.00 3.18 10000 1000
4.94E+01 3.15 1.00 3.18
4.73E+01 1.20 1.00 3.18
5.03E+01 3.48 1.00 3.18
4.65E+01 2.72 1.00 3.18
3.62E+01 6.77 1.00 3.18
4.42E+01 2.86 1.00 3.18
1.30E+00 22.36 1.00 3.18
1.13E+00 8.21 1.00 3.18
5.00E-01 16.57 1.00 3.18
5.00E-01 24.02 1.00 3.18
5.00E-01 5.73 1.00 3.18
5.00E-01 4.61 1.00 3.18
5.00E-01 12.74 1.00 3.18
1.42E+00 21.38 1.00 3.18
1.38E+00 17.06 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.89E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.94E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.63E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-845
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Sb CFS-L07-1315-T01-A 1 9.46E+00 E
Sb CFS-L07-1315-T02-A 1 1.17E+01 E
Sb CFS-L07-1315-T03-A 1 1.05E+01 E
Sb CFS-L07-1315-T04-A 1 9.52E+00 E
Sb CFS-L07-1315-T05-A 1 1.14E+01 E
Sb CFS-L07-1315-T06-A 1 1.17E+01 E
Sb CFS-L07-1315-T07-A 1 1.31E+01 E
Sb CFS-L07-1315-T08-A 1 1.17E+01 E
Sb CFS-L07-1315-T09-A 1 1.58E+01 E
Sb CFS-L07-1315-T01-B 1 9.84E+00 E
Sb CFS-L07-1315-T02-B 1 1.23E+01 E
Sb CFS-L07-1315-T03-B 1 1.15E+01 E
Sb CFS-L07-1315-T04-B 1 1.76E+01 E
Sb CFS-L07-1315-T05-B 1 1.55E+01 E
Sb CFS-L07-1315-T06-B 1 1.28E+01 E
Sb CFS-L07-1315-T07-B 1 1.71E+01 E
Sb CFS-L07-1315-T08-B 1 1.36E+01 E
Sb CFS-L07-1315-T09-B 1 1.57E+01 E
Sb CFS-L07-1315-T01-C 1 9.07E+00 E
Sb CFS-L07-1315-T02-C 1 7.69E+00 E
Sb CFS-L07-1315-T03-C 1 7.86E+00 E
Sb CFS-L07-1315-T04-C 1 1.68E+01 E
Sb CFS-L07-1315-T05-C 1 1.19E+01 E
Sb CFS-L07-1315-T06-C 1 1.40E+01 E
Sb CFS-L07-1315-T07-C 1 1.57E+01 E
Sb CFS-L07-1315-T08-C 1 1.09E+01 E
Sb CFS-L07-1315-T09-C 1 1.29E+01 E
Sb CFS-L07-1315-M01-A 1 3.75E+00 U1/2
Sb CFS-L07-1315-M02-A 1 3.75E+00 U1/2
Sb CFS-L07-1315-M03-A 1 3.75E+00 U1/2
Sb CFS-L07-1315-M04-A 1 3.75E+00 U1/2
Sb CFS-L07-1315-M05-A 1 3.75E+00 U1/2
Sb CFS-L07-1315-M06-A 1 3.75E+00 U1/2
Sb CFS-L07-1315-M07-A 1 3.75E+00 U1/2
Sb CFS-L07-1315-M08-A 1 3.75E+00 U1/2
Sb CFS-L07-1315-M09-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.46E+00 5.84 7.50 23.90
1.17E+01 19.61 7.50 23.90
1.05E+01 7.29 7.50 23.90 10000 1000
9.52E+00 7.73 7.50 23.90
1.14E+01 10.38 7.50 23.90
1.17E+01 19.35 7.50 23.90
1.31E+01 13.56 7.50 23.90
1.17E+01 25.67 7.50 23.90
1.58E+01 17.38 7.50 23.90
9.84E+00 16.83 7.50 23.90
1.23E+01 17.41 7.50 23.90
1.15E+01 7.62 7.50 23.90 10000 1000
1.76E+01 5.54 7.50 23.90
1.55E+01 6.53 7.50 23.90
1.28E+01 3.86 7.50 23.90
1.71E+01 24.14 7.50 23.90
1.36E+01 23.63 7.50 23.90
1.57E+01 19.73 7.50 23.90
9.07E+00 11.37 7.50 23.90
7.69E+00 4.62 7.50 23.90
7.86E+00 8.66 7.50 23.90 10000 1000
1.68E+01 4.89 7.50 23.90
1.19E+01 13.39 7.50 23.90
1.40E+01 23.36 7.50 23.90
1.57E+01 7.73 7.50 23.90
1.09E+01 4.32 7.50 23.90
1.29E+01 8.30 7.50 23.90
3.75E+00 37.06 7.50 23.90
3.75E+00 25.81 7.50 23.90
3.75E+00 18.89 7.50 23.90
3.75E+00 17.55 7.50 23.90
3.75E+00 23.89 7.50 23.90
3.75E+00 7.53 7.50 23.90
3.75E+00 5.94 7.50 23.90
3.75E+00 13.61 7.50 23.90
3.75E+00 11.51 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.88E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.62E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.71E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-846
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
As CFS-L07-1315-T01-A 1 5.50E+00 U1/2
As CFS-L07-1315-T02-A 1 1.43E+01 E
As CFS-L07-1315-T03-A 1 1.54E+01 E
As CFS-L07-1315-T04-A 1 1.18E+01 E
As CFS-L07-1315-T05-A 1 1.64E+01 E
As CFS-L07-1315-T06-A 1 1.25E+01 E
As CFS-L07-1315-T07-A 1 5.50E+00 U1/2
As CFS-L07-1315-T08-A 1 5.50E+00 U1/2
As CFS-L07-1315-T09-A 1 5.50E+00 U1/2
As CFS-L07-1315-T01-B 1 5.50E+00 U1/2
As CFS-L07-1315-T02-B 1 1.21E+01 E
As CFS-L07-1315-T03-B 1 1.32E+01 E
As CFS-L07-1315-T04-B 1 1.49E+01 E
As CFS-L07-1315-T05-B 1 1.34E+01 E
As CFS-L07-1315-T06-B 1 1.12E+01 E
As CFS-L07-1315-T07-B 1 5.50E+00 U1/2
As CFS-L07-1315-T08-B 1 5.50E+00 U1/2
As CFS-L07-1315-T09-B 1 5.50E+00 U1/2
As CFS-L07-1315-T01-C 1 5.50E+00 U1/2
As CFS-L07-1315-T02-C 1 1.36E+01 E
As CFS-L07-1315-T03-C 1 1.46E+01 E
As CFS-L07-1315-T04-C 1 1.36E+01 E
As CFS-L07-1315-T05-C 1 1.27E+01 E
As CFS-L07-1315-T06-C 1 1.16E+01 E
As CFS-L07-1315-T07-C 1 5.50E+00 U1/2
As CFS-L07-1315-T08-C 1 5.50E+00 U1/2
As CFS-L07-1315-T09-C 1 5.50E+00 U1/2
As CFS-L07-1315-M01-A 1 5.50E+00 U1/2
As CFS-L07-1315-M02-A 1 5.50E+00 U1/2
As CFS-L07-1315-M03-A 1 5.50E+00 U1/2
As CFS-L07-1315-M04-A 1 5.50E+00 U1/2
As CFS-L07-1315-M05-A 1 5.50E+00 U1/2
As CFS-L07-1315-M06-A 1 5.50E+00 U1/2
As CFS-L07-1315-M07-A 1 5.50E+00 U1/2
As CFS-L07-1315-M08-A 1 5.50E+00 U1/2
As CFS-L07-1315-M09-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.50E+00 7.84 11.00 35.00
1.43E+01 13.03 11.00 35.00
1.54E+01 24.93 11.00 35.00 10000 1000
1.18E+01 19.39 11.00 35.00
1.64E+01 12.41 11.00 35.00
1.25E+01 10.96 11.00 35.00
5.50E+00 41.23 11.00 35.00
5.50E+00 34.16 11.00 35.00
5.50E+00 39.42 11.00 35.00
5.50E+00 8.00 11.00 35.00
1.21E+01 11.91 11.00 35.00
1.32E+01 21.89 11.00 35.00 10000 1000
1.49E+01 11.06 11.00 35.00
1.34E+01 25.97 11.00 35.00
1.12E+01 25.06 11.00 35.00
5.50E+00 30.08 11.00 35.00
5.50E+00 33.71 11.00 35.00
5.50E+00 24.56 11.00 35.00
5.50E+00 32.01 11.00 35.00
1.36E+01 39.56 11.00 35.00
1.46E+01 23.11 11.00 35.00 10000 1000
1.36E+01 15.20 11.00 35.00
1.27E+01 38.73 11.00 35.00
1.16E+01 20.91 11.00 35.00
5.50E+00 36.48 11.00 35.00
5.50E+00 27.01 11.00 35.00
5.50E+00 22.87 11.00 35.00
5.50E+00 20.80 11.00 35.00
5.50E+00 58.00 11.00 35.00
5.50E+00 70.90 11.00 35.00
5.50E+00 45.12 11.00 35.00
5.50E+00 52.76 11.00 35.00
5.50E+00 41.84 11.00 35.00
5.50E+00 34.71 11.00 35.00
5.50E+00 63.52 11.00 35.00
5.50E+00 9.28 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.98E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.23E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.29E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-847
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
B CFS-L07-1315-T01-A 1 1.75E+01
B CFS-L07-1315-T02-A 1 3.33E+01
B CFS-L07-1315-T03-A 1 3.96E+01
B CFS-L07-1315-T04-A 1 9.87E+01
B CFS-L07-1315-T05-A 1 1.21E+02
B CFS-L07-1315-T06-A 1 1.95E+02
B CFS-L07-1315-T07-A 1 1.59E+02
B CFS-L07-1315-T08-A 1 7.49E+01
B CFS-L07-1315-T09-A 1 1.19E+02
B CFS-L07-1315-T01-B 1 1.83E+01
B CFS-L07-1315-T02-B 1 3.53E+01
B CFS-L07-1315-T03-B 1 4.02E+01
B CFS-L07-1315-T04-B 1 9.75E+01
B CFS-L07-1315-T05-B 1 1.20E+02
B CFS-L07-1315-T06-B 1 1.92E+02
B CFS-L07-1315-T07-B 1 1.56E+02
B CFS-L07-1315-T08-B 1 7.33E+01
B CFS-L07-1315-T09-B 1 1.20E+02
B CFS-L07-1315-T01-C 1 1.82E+01
B CFS-L07-1315-T02-C 1 3.45E+01
B CFS-L07-1315-T03-C 1 3.85E+01
B CFS-L07-1315-T04-C 1 9.44E+01
B CFS-L07-1315-T05-C 1 1.16E+02
B CFS-L07-1315-T06-C 1 1.92E+02
B CFS-L07-1315-T07-C 1 1.55E+02
B CFS-L07-1315-T08-C 1 7.09E+01
B CFS-L07-1315-T09-C 1 1.17E+02
B CFS-L07-1315-M01-A 1 5.00E-01 U1/2
B CFS-L07-1315-M02-A 1 5.00E-01 U1/2
B CFS-L07-1315-M03-A 1 5.00E-01 U1/2
B CFS-L07-1315-M04-A 1 5.00E-01 U1/2
B CFS-L07-1315-M05-A 1 5.00E-01 U1/2
B CFS-L07-1315-M06-A 1 5.00E-01 U1/2
B CFS-L07-1315-M07-A 1 5.00E-01 U1/2
B CFS-L07-1315-M08-A 1 5.00E-01 U1/2
B CFS-L07-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.75E+01 3.44 1.00 3.18
3.33E+01 0.88 1.00 3.18
3.96E+01 3.16 1.00 3.18 10000 1000
9.87E+01 1.53 1.00 3.18
1.21E+02 0.37 1.00 3.18
1.95E+02 1.36 1.00 3.18
1.59E+02 1.64 1.00 3.18
7.49E+01 0.98 1.00 3.18
1.19E+02 1.25 1.00 3.18
1.83E+01 4.50 1.00 3.18
3.53E+01 2.43 1.00 3.18
4.02E+01 2.22 1.00 3.18 10000 1000
9.75E+01 0.68 1.00 3.18
1.20E+02 0.40 1.00 3.18
1.92E+02 0.61 1.00 3.18
1.56E+02 1.39 1.00 3.18
7.33E+01 2.90 1.00 3.18
1.20E+02 1.71 1.00 3.18
1.82E+01 4.51 1.00 3.18
3.45E+01 2.35 1.00 3.18
3.85E+01 2.32 1.00 3.18 10000 1000
9.44E+01 5.41 1.00 3.18
1.16E+02 0.98 1.00 3.18
1.92E+02 1.10 1.00 3.18
1.55E+02 1.33 1.00 3.18
7.09E+01 0.35 1.00 3.18
1.17E+02 1.82 1.00 3.18
5.00E-01 2.56 1.00 3.18
5.00E-01 1.43 1.00 3.18
5.00E-01 3.92 1.00 3.18
5.00E-01 3.85 1.00 3.18
5.00E-01 3.46 1.00 3.18
5.00E-01 3.06 1.00 3.18
5.00E-01 9.49 1.00 3.18
5.00E-01 2.35 1.00 3.18
5.00E-01 1.77 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.29E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.38E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.68E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-848
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Ba CFS-L07-1315-T01-A 1 1.51E+01
Ba CFS-L07-1315-T02-A 1 2.70E+01
Ba CFS-L07-1315-T03-A 1 2.95E+01
Ba CFS-L07-1315-T04-A 1 3.53E+01
Ba CFS-L07-1315-T05-A 1 3.38E+01
Ba CFS-L07-1315-T06-A 1 3.36E+01
Ba CFS-L07-1315-T07-A 1 2.89E+01
Ba CFS-L07-1315-T08-A 1 3.78E+01
Ba CFS-L07-1315-T09-A 1 3.75E+01
Ba CFS-L07-1315-T01-B 1 1.77E+01
Ba CFS-L07-1315-T02-B 1 2.98E+01
Ba CFS-L07-1315-T03-B 1 2.60E+01
Ba CFS-L07-1315-T04-B 1 2.92E+01
Ba CFS-L07-1315-T05-B 1 2.93E+01
Ba CFS-L07-1315-T06-B 1 3.11E+01
Ba CFS-L07-1315-T07-B 1 2.91E+01
Ba CFS-L07-1315-T08-B 1 3.15E+01
Ba CFS-L07-1315-T09-B 1 3.50E+01
Ba CFS-L07-1315-T01-C 1 1.80E+01
Ba CFS-L07-1315-T02-C 1 2.59E+01
Ba CFS-L07-1315-T03-C 1 2.06E+01
Ba CFS-L07-1315-T04-C 1 2.84E+01
Ba CFS-L07-1315-T05-C 1 2.51E+01
Ba CFS-L07-1315-T06-C 1 3.63E+01
Ba CFS-L07-1315-T07-C 1 2.92E+01
Ba CFS-L07-1315-T08-C 1 2.96E+01
Ba CFS-L07-1315-T09-C 1 2.95E+01
Ba CFS-L07-1315-M01-A 1 5.00E-01 U1/2
Ba CFS-L07-1315-M02-A 1 5.00E-01 U1/2
Ba CFS-L07-1315-M03-A 1 5.00E-01 U1/2
Ba CFS-L07-1315-M04-A 1 5.00E-01 U1/2
Ba CFS-L07-1315-M05-A 1 5.00E-01 U1/2
Ba CFS-L07-1315-M06-A 1 5.00E-01 U1/2
Ba CFS-L07-1315-M07-A 1 5.00E-01 U1/2
Ba CFS-L07-1315-M08-A 1 5.00E-01 U1/2
Ba CFS-L07-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.51E+01 1.50 1.00 3.18
2.70E+01 0.98 1.00 3.18
2.95E+01 0.59 1.00 3.18 10000 1000
3.53E+01 0.51 1.00 3.18
3.38E+01 0.77 1.00 3.18
3.36E+01 1.85 1.00 3.18
2.89E+01 0.37 1.00 3.18
3.78E+01 1.36 1.00 3.18
3.75E+01 0.43 1.00 3.18
1.77E+01 5.61 1.00 3.18
2.98E+01 0.68 1.00 3.18
2.60E+01 2.16 1.00 3.18 10000 1000
2.92E+01 1.30 1.00 3.18
2.93E+01 0.31 1.00 3.18
3.11E+01 0.38 1.00 3.18
2.91E+01 1.43 1.00 3.18
3.15E+01 2.67 1.00 3.18
3.50E+01 2.04 1.00 3.18
1.80E+01 3.69 1.00 3.18
2.59E+01 1.04 1.00 3.18
2.06E+01 1.91 1.00 3.18 10000 1000
2.84E+01 4.71 1.00 3.18
2.51E+01 1.35 1.00 3.18
3.63E+01 1.11 1.00 3.18
2.92E+01 1.76 1.00 3.18
2.96E+01 1.30 1.00 3.18
2.95E+01 2.15 1.00 3.18
5.00E-01 5.42 1.00 3.18
5.00E-01 17.66 1.00 3.18
5.00E-01 17.78 1.00 3.18
5.00E-01 9.06 1.00 3.18
5.00E-01 2.37 1.00 3.18
5.00E-01 3.46 1.00 3.18
5.00E-01 22.03 1.00 3.18
5.00E-01 18.24 1.00 3.18
5.00E-01 13.37 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.53E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.80E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.70E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-849
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Be CFS-L07-1315-T01-A 1 9.50E-01 U1/2
Be CFS-L07-1315-T02-A 1 9.50E-01 U1/2
Be CFS-L07-1315-T03-A 1 9.50E-01 U1/2
Be CFS-L07-1315-T04-A 1 9.50E-01 U1/2
Be CFS-L07-1315-T05-A 1 9.50E-01 U1/2
Be CFS-L07-1315-T06-A 1 9.50E-01 U1/2
Be CFS-L07-1315-T07-A 1 9.50E-01 U1/2
Be CFS-L07-1315-T08-A 1 9.50E-01 U1/2
Be CFS-L07-1315-T09-A 1 9.50E-01 U1/2
Be CFS-L07-1315-T01-B 1 9.50E-01 U1/2
Be CFS-L07-1315-T02-B 1 9.50E-01 U1/2
Be CFS-L07-1315-T03-B 1 9.50E-01 U1/2
Be CFS-L07-1315-T04-B 1 9.50E-01 U1/2
Be CFS-L07-1315-T05-B 1 9.50E-01 U1/2
Be CFS-L07-1315-T06-B 1 9.50E-01 U1/2
Be CFS-L07-1315-T07-B 1 9.50E-01 U1/2
Be CFS-L07-1315-T08-B 1 9.50E-01 U1/2
Be CFS-L07-1315-T09-B 1 9.50E-01 U1/2
Be CFS-L07-1315-T01-C 1 9.50E-01 U1/2
Be CFS-L07-1315-T02-C 1 9.50E-01 U1/2
Be CFS-L07-1315-T03-C 1 9.50E-01 U1/2
Be CFS-L07-1315-T04-C 1 9.50E-01 U1/2
Be CFS-L07-1315-T05-C 1 9.50E-01 U1/2
Be CFS-L07-1315-T06-C 1 9.50E-01 U1/2
Be CFS-L07-1315-T07-C 1 9.50E-01 U1/2
Be CFS-L07-1315-T08-C 1 9.50E-01 U1/2
Be CFS-L07-1315-T09-C 1 9.50E-01 U1/2
Be CFS-L07-1315-M01-A 1 9.50E-01 U1/2
Be CFS-L07-1315-M02-A 1 9.50E-01 U1/2
Be CFS-L07-1315-M03-A 1 9.50E-01 U1/2
Be CFS-L07-1315-M04-A 1 9.50E-01 U1/2
Be CFS-L07-1315-M05-A 1 9.50E-01 U1/2
Be CFS-L07-1315-M06-A 1 9.50E-01 U1/2
Be CFS-L07-1315-M07-A 1 9.50E-01 U1/2
Be CFS-L07-1315-M08-A 1 9.50E-01 U1/2
Be CFS-L07-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 67.44 1.90 6.00
9.50E-01 15.66 1.90 6.00
9.50E-01 66.64 1.90 6.00 10000 1000
9.50E-01 67.12 1.90 6.00
9.50E-01 42.12 1.90 6.00
9.50E-01 22.65 1.90 6.00
9.50E-01 13.36 1.90 6.00
9.50E-01 50.59 1.90 6.00
9.50E-01 29.87 1.90 6.00
9.50E-01 26.00 1.90 6.00
9.50E-01 24.81 1.90 6.00
9.50E-01 40.94 1.90 6.00 10000 1000
9.50E-01 5.98 1.90 6.00
9.50E-01 35.84 1.90 6.00
9.50E-01 59.12 1.90 6.00
9.50E-01 81.36 1.90 6.00
9.50E-01 35.93 1.90 6.00
9.50E-01 68.81 1.90 6.00
9.50E-01 26.42 1.90 6.00
9.50E-01 53.35 1.90 6.00
9.50E-01 81.34 1.90 6.00 10000 1000
9.50E-01 28.80 1.90 6.00
9.50E-01 71.84 1.90 6.00
9.50E-01 50.16 1.90 6.00
9.50E-01 46.79 1.90 6.00
9.50E-01 44.09 1.90 6.00
9.50E-01 52.33 1.90 6.00
9.50E-01 59.40 1.90 6.00
9.50E-01 62.64 1.90 6.00
9.50E-01 24.39 1.90 6.00
9.50E-01 30.65 1.90 6.00
9.50E-01 19.59 1.90 6.00
9.50E-01 55.74 1.90 6.00
9.50E-01 13.04 1.90 6.00
9.50E-01 39.81 1.90 6.00
9.50E-01 7.56 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.39E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.42E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.63E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-850
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Cd CFS-L07-1315-T01-A 1 9.24E+01
Cd CFS-L07-1315-T02-A 1 3.64E+02
Cd CFS-L07-1315-T03-A 1 4.41 E+02
Cd CFS-L07-1315-T04-A 1 1.16E+03
Cd CFS-L07-1315-T05-A 1 1.33E+03
Cd CFS-L07-1315-T06-A 1 1.96E+03
Cd CFS-L07-1315-T07-A 1 1.65E+03
Cd CFS-L07-1315-T08-A 1 9.55E+02
Cd CFS-L07-1315-T09-A 1 1.43E+03
Cd CFS-L07-1315-T01-B 1 9.94E+01
Cd CFS-L07-1315-T02-B 1 4.12E+02
Cd CFS-L07-1315-T03-B 1 4.23E+02
Cd CFS-L07-1315-T04-B 1 1.13E+03
Cd CFS-L07-1315-T05-B 1 1.35E+03
Cd CFS-L07-1315-T06-B 1 1.92E+03
Cd CFS-L07-1315-T07-B 1 1.66E+03
Cd CFS-L07-1315-T08-B 1 9.32E+02
Cd CFS-L07-1315-T09-B 1 1.42E+03
Cd CFS-L07-1315-T01-C 1 7.55E+01
Cd CFS-L07-1315-T02-C 1 3.97E+02
Cd CFS-L07-1315-T03-C 1 3.83E+02
Cd CFS-L07-1315-T04-C 1 1.09E+03
Cd CFS-L07-1315-T05-C 1 1.29E+03
Cd CFS-L07-1315-T06-C 1 1.87E+03
Cd CFS-L07-1315-T07-C 1 1.54E+03
Cd CFS-L07-1315-T08-C 1 8.58E+02
Cd CFS-L07-1315-T09-C 1 1.29E+03
Cd CFS-L07-1315-M01-A 1 1.10E+00 U1/2
Cd CFS-L07-1315-M02-A 1 1.10E+00 U1/2
Cd CFS-L07-1315-M03-A 1 1.10E+00 U1/2
Cd CFS-L07-1315-M04-A 1 1.10E+00 U1/2
Cd CFS-L07-1315-M05-A 1 1.10E+00 U1/2
Cd CFS-L07-1315-M06-A 1 1.10E+00 U1/2
Cd CFS-L07-1315-M07-A 1 1.10E+00 U1/2
Cd CFS-L07-1315-M08-A 1 1.10E+00 U1/2
Cd CFS-L07-1315-M09-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.24E+01 1.01 2.20 7.00
3.64E+02 0.59 2.20 7.00
4.41E+02 0.90 2.20 7.00 10000 1000
1.16E+03 0.37 2.20 7.00
1.33E+03 0.29 2.20 7.00
1.96E+03 1.22 2.20 7.00
1.65E+03 0.68 2.20 7.00
9.55E+02 0.88 2.20 7.00
1.43E+03 0.95 2.20 7.00
9.94E+01 5.79 2.20 7.00
4.12E+02 0.47 2.20 7.00
4.23E+02 1.19 2.20 7.00 10000 1000
1.13E+03 1.85 2.20 7.00
1.35E+03 0.43 2.20 7.00
1.92E+03 0.37 2.20 7.00
1.66E+03 0.90 2.20 7.00
9.32E+02 2.45 2.20 7.00
1.42E+03 2.75 2.20 7.00
7.55E+01 3.70 2.20 7.00
3.97E+02 0.95 2.20 7.00
3.83E+02 1.21 2.20 7.00 10000 1000
1.09E+03 4.12 2.20 7.00
1.29E+03 1.43 2.20 7.00
1.87E+03 1.26 2.20 7.00
1.54E+03 1.87 2.20 7.00
8.58E+02 0.87 2.20 7.00
1.29E+03 2.05 2.20 7.00
1.10E+00 6.56 2.20 7.00
1.10E+00 21.65 2.20 7.00
1.10E+00 23.13 2.20 7.00
1.10E+00 16.61 2.20 7.00
1.10E+00 31.03 2.20 7.00
1.10E+00 9.40 2.20 7.00
1.10E+00 7.83 2.20 7.00
1.10E+00 16.80 2.20 7.00
1.10E+00 23.56 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.40E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.33E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.32E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-851
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Ca CFS-L07-1315-T01-A 1 1.11E+04
Ca CFS-L07-1315-T02-A 1 4.34E+04
Ca CFS-L07-1315-T03-A 1 4.82E+04
Ca CFS-L07-1315-T04-A 1 1.02E+05
Ca CFS-L07-1315-T05-A 1 1.13E+05
Ca CFS-L07-1315-T06-A 1 1.67E+05
Ca CFS-L07-1315-T07-A 1 1.47E+05
Ca CFS-L07-1315-T08-A 1 8.64E+04
Ca CFS-L07-1315-T09-A 1 1.36E+05
Ca CFS-L07-1315-T01-B 1 1.13E+04
Ca CFS-L07-1315-T02-B 1 4.47E+04
Ca CFS-L07-1315-T03-B 1 4.24E+04
Ca CFS-L07-1315-T04-B 1 9.34E+04
Ca CFS-L07-1315-T05-B 1 1.08E+05
Ca CFS-L07-1315-T06-B 1 1.58E+05
Ca CFS-L07-1315-T07-B 1 1.45E+05
Ca CFS-L07-1315-T08-B 1 8.46E+04
Ca CFS-L07-1315-T09-B 1 1.37E+05
Ca CFS-L07-1315-T01-C 1 1.10E+04
Ca CFS-L07-1315-T02-C 1 4.41 E+04
Ca CFS-L07-1315-T03-C 1 3.74E+04
Ca CFS-L07-1315-T04-C 1 9.10E+04
Ca CFS-L07-1315-T05-C 1 1.06E+05
Ca CFS-L07-1315-T06-C 1 1.63E+05
Ca CFS-L07-1315-T07-C 1 1.41E+05
Ca CFS-L07-1315-T08-C 1 8.18E+04
Ca CFS-L07-1315-T09-C 1 1.31E+05
Ca CFS-L07-1315-M01-A 1 3.99E+01
Ca CFS-L07-1315-M02-A 1 2.07E+01
Ca CFS-L07-1315-M03-A 1 2.25E+01
Ca CFS-L07-1315-M04-A 1 3.62E+01
Ca CFS-L07-1315-M05-A 1 2.94E+01
Ca CFS-L07-1315-M06-A 1 1.89E+01
Ca CFS-L07-1315-M07-A 1 1.01E+01
Ca CFS-L07-1315-M08-A 1 1.54E+01
Ca CFS-L07-1315-M09-A 1 2.12E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.11 E+04 1.67 2.60 8.30
4.34E+04 0.29 2.60 8.30
4.82E+04 0.90 2.60 8.30 10000 1000
1.02E+05 0.57 2.60 8.30
1.13E+05 0.41 2.60 8.30
1.67E+05 1.14 2.60 8.30
1.47E+05 0.91 2.60 8.30
8.64E+04 0.75 2.60 8.30
1.36E+05 1.03 2.60 8.30
1.13E+04 6.04 2.60 8.30
4.47E+04 0.48 2.60 8.30
4.24E+04 0.97 2.60 8.30 10000 1000
9.34E+04 2.01 2.60 8.30
1.08E+05 0.57 2.60 8.30
1.58E+05 0.83 2.60 8.30
1.45E+05 0.89 2.60 8.30
8.46E+04 2.33 2.60 8.30
1.37E+05 2.77 2.60 8.30
1.10E+04 3.43 2.60 8.30
4.41 E+04 0.77 2.60 8.30
3.74E+04 1.42 2.60 8.30 10000 1000
9.10E+04 4.05 2.60 8.30
1.06E+05 1.50 2.60 8.30
1.63E+05 1.34 2.60 8.30
1.41E+05 2.03 2.60 8.30
8.18E+04 0.54 2.60 8.30
1.31E+05 2.25 2.60 8.30
3.99E+01 0.71 2.60 8.30
2.07E+01 1.44 2.60 8.30
2.25E+01 1.12 2.60 8.30
3.62E+01 4.10 2.60 8.30
2.94E+01 3.14 2.60 8.30
1.89E+01 1.09 2.60 8.30
1.01E+01 8.78 2.60 8.30
1.54E+01 4.50 2.60 8.30
2.12E+01 2.58 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.91 E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.32E+04 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.83E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-852
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Cr CFS-L07-1315-T01-A 1 6.00E-01 U1/2
Cr CFS-L07-1315-T02-A 1 6.00E-01 U1/2
Cr CFS-L07-1315-T03-A 1 6.00E-01 U1/2
Cr CFS-L07-1315-T04-A 1 6.00E-01 U1/2
Cr CFS-L07-1315-T05-A 1 6.00E-01 U1/2
Cr CFS-L07-1315-T06-A 1 6.00E-01 U1/2
Cr CFS-L07-1315-T07-A 1 6.00E-01 U1/2
Cr CFS-L07-1315-T08-A 1 6.00E-01 U1/2
Cr CFS-L07-1315-T09-A 1 6.00E-01 U1/2
Cr CFS-L07-1315-T01-B 1 6.00E-01 U1/2
Cr CFS-L07-1315-T02-B 1 6.00E-01 U1/2
Cr CFS-L07-1315-T03-B 1 6.00E-01 U1/2
Cr CFS-L07-1315-T04-B 1 6.00E-01 U1/2
Cr CFS-L07-1315-T05-B 1 6.00E-01 U1/2
Cr CFS-L07-1315-T06-B 1 6.00E-01 U1/2
Cr CFS-L07-1315-T07-B 1 6.00E-01 U1/2
Cr CFS-L07-1315-T08-B 1 6.00E-01 U1/2
Cr CFS-L07-1315-T09-B 1 6.00E-01 U1/2
Cr CFS-L07-1315-T01-C 1 6.00E-01 U1/2
Cr CFS-L07-1315-T02-C 1 6.00E-01 U1/2
Cr CFS-L07-1315-T03-C 1 6.00E-01 U1/2
Cr CFS-L07-1315-T04-C 1 6.00E-01 U1/2
Cr CFS-L07-1315-T05-C 1 6.00E-01 U1/2
Cr CFS-L07-1315-T06-C 1 6.00E-01 U1/2
Cr CFS-L07-1315-T07-C 1 6.00E-01 U1/2
Cr CFS-L07-1315-T08-C 1 6.00E-01 U1/2
Cr CFS-L07-1315-T09-C 1 6.00E-01 U1/2
Cr CFS-L07-1315-M01-A 1 6.00E-01 U1/2
Cr CFS-L07-1315-M02-A 1 6.00E-01 U1/2
Cr CFS-L07-1315-M03-A 1 6.00E-01 U1/2
Cr CFS-L07-1315-M04-A 1 6.00E-01 U1/2
Cr CFS-L07-1315-M05-A 1 6.00E-01 U1/2
Cr CFS-L07-1315-M06-A 1 6.00E-01 U1/2
Cr CFS-L07-1315-M07-A 1 6.00E-01 U1/2
Cr CFS-L07-1315-M08-A 1 6.00E-01 U1/2
Cr CFS-L07-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 21.94 1.20 3.82
6.00E-01 34.12 1.20 3.82
6.00E-01 80.30 1.20 3.82 10000 1000
6.00E-01 56.75 1.20 3.82
6.00E-01 37.32 1.20 3.82
6.00E-01 79.17 1.20 3.82
6.00E-01 64.75 1.20 3.82
6.00E-01 85.28 1.20 3.82
6.00E-01 37.06 1.20 3.82
6.00E-01 11.20 1.20 3.82
6.00E-01 41.30 1.20 3.82
6.00E-01 65.42 1.20 3.82 10000 1000
6.00E-01 47.08 1.20 3.82
6.00E-01 50.04 1.20 3.82
6.00E-01 56.90 1.20 3.82
6.00E-01 46.36 1.20 3.82
6.00E-01 75.82 1.20 3.82
6.00E-01 39.30 1.20 3.82
6.00E-01 19.59 1.20 3.82
6.00E-01 57.50 1.20 3.82
6.00E-01 13.98 1.20 3.82 10000 1000
6.00E-01 26.23 1.20 3.82
6.00E-01 73.31 1.20 3.82
6.00E-01 83.55 1.20 3.82
6.00E-01 80.52 1.20 3.82
6.00E-01 26.79 1.20 3.82
6.00E-01 35.48 1.20 3.82
6.00E-01 50.22 1.20 3.82
6.00E-01 36.87 1.20 3.82
6.00E-01 61.75 1.20 3.82
6.00E-01 20.95 1.20 3.82
6.00E-01 56.28 1.20 3.82
6.00E-01 74.97 1.20 3.82
6.00E-01 27.64 1.20 3.82
6.00E-01 63.81 1.20 3.82
6.00E-01 39.64 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.22E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.45E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.43E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-853
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Co CFS-L07-1315-T01-A 1 9.00E-01 U1/2
Co CFS-L07-1315-T02-A 1 7.47E+00
Co CFS-L07-1315-T03-A 1 7.56E+00
Co CFS-L07-1315-T04-A 1 3.06E+01
Co CFS-L07-1315-T05-A 1 3.84E+01
Co CFS-L07-1315-T06-A 1 6.31 E+01
Co CFS-L07-1315-T07-A 1 5.54E+01
Co CFS-L07-1315-T08-A 1 2.98E+01
Co CFS-L07-1315-T09-A 1 4.80E+01
Co CFS-L07-1315-T01-B 1 9.00E-01 U1/2
Co CFS-L07-1315-T02-B 1 6.66E+00
Co CFS-L07-1315-T03-B 1 6.18E+00
Co CFS-L07-1315-T04-B 1 3. 11 E+01
Co CFS-L07-1315-T05-B 1 4.07E+01
Co CFS-L07-1315-T06-B 1 6.23E+01
Co CFS-L07-1315-T07-B 1 5.70E+01
Co CFS-L07-1315-T08-B 1 2.83E+01
Co CFS-L07-1315-T09-B 1 4.87E+01
Co CFS-L07-1315-T01-C 1 9.00E-01 U1/2
Co CFS-L07-1315-T02-C 1 6.25E+00
Co CFS-L07-1315-T03-C 1 6.18E+00
Co CFS-L07-1315-T04-C 1 2.85E+01
Co CFS-L07-1315-T05-C 1 3.78E+01
Co CFS-L07-1315-T06-C 1 5.99E+01
Co CFS-L07-1315-T07-C 1 5.18E+01
Co CFS-L07-1315-T08-C 1 2.66E+01
Co CFS-L07-1315-T09-C 1 4.44E+01
Co CFS-L07-1315-M01-A 1 9.00E-01 U1/2
Co CFS-L07-1315-M02-A 1 9.00E-01 U1/2
Co CFS-L07-1315-M03-A 1 9.00E-01 U1/2
Co CFS-L07-1315-M04-A 1 9.00E-01 U1/2
Co CFS-L07-1315-M05-A 1 9.00E-01 U1/2
Co CFS-L07-1315-M06-A 1 9.00E-01 U1/2
Co CFS-L07-1315-M07-A 1 9.00E-01 U1/2
Co CFS-L07-1315-M08-A 1 9.00E-01 U1/2
Co CFS-L07-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 3.48 1.80 5.72
7.47E+00 3.07 1.80 5.72
7.56E+00 3.91 1.80 5.72 10000 1000
3.06E+01 1.14 1.80 5.72
3.84E+01 1.38 1.80 5.72
6.31E+01 0.12 1.80 5.72
5.54E+01 1.56 1.80 5.72
2.98E+01 1.33 1.80 5.72
4.80E+01 0.82 1.80 5.72
9.00E-01 21.24 1.80 5.72
6.66E+00 11.85 1.80 5.72
6.18E+00 1.59 1.80 5.72 10000 1000
3. 11 E+01 3.10 1.80 5.72
4.07E+01 1.28 1.80 5.72
6.23E+01 3.00 1.80 5.72
5.70E+01 0.88 1.80 5.72
2.83E+01 3.65 1.80 5.72
4.87E+01 4.24 1.80 5.72
9.00E-01 26.33 1.80 5.72
6.25E+00 3.90 1.80 5.72
6.18E+00 1.47 1.80 5.72 10000 1000
2.85E+01 3.87 1.80 5.72
3.78E+01 0.36 1.80 5.72
5.99E+01 3.65 1.80 5.72
5.18E+01 4.77 1.80 5.72
2.66E+01 3.82 1.80 5.72
4.44E+01 3.84 1.80 5.72
9.00E-01 72.53 1.80 5.72
9.00E-01 69.06 1.80 5.72
9.00E-01 14.19 1.80 5.72
9.00E-01 39.29 1.80 5.72
9.00E-01 17.64 1.80 5.72
9.00E-01 81.24 1.80 5.72
9.00E-01 60.59 1.80 5.72
9.00E-01 27.52 1.80 5.72
9.00E-01 81.11 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.17E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.39E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.40E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-854
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Cu CFS-L07-1315-T01-A 1 7.47E+01
Cu CFS-L07-1315-T02-A 1 2.59E+02
Cu CFS-L07-1315-T03-A 1 2.68E+02
Cu CFS-L07-1315-T04-A 1 4.61 E+02
Cu CFS-L07-1315-T05-A 1 5.78E+02
Cu CFS-L07-1315-T06-A 1 8.25E+02
Cu CFS-L07-1315-T07-A 1 8.23E+02
Cu CFS-L07-1315-T08-A 1 8.65E+02
Cu CFS-L07-1315-T09-A 1 9.62E+02
Cu CFS-L07-1315-T01-B 1 6.58E+01
Cu CFS-L07-1315-T02-B 1 2.93E+02
Cu CFS-L07-1315-T03-B 1 2.35E+02
Cu CFS-L07-1315-T04-B 1 4.50E+02
Cu CFS-L07-1315-T05-B 1 5.74E+02
Cu CFS-L07-1315-T06-B 1 7.99E+02
Cu CFS-L07-1315-T07-B 1 8.08E+02
Cu CFS-L07-1315-T08-B 1 6.65E+02
Cu CFS-L07-1315-T09-B 1 8.93E+02
Cu CFS-L07-1315-T01-C 1 9.57E+01
Cu CFS-L07-1315-T02-C 1 2.49E+02
Cu CFS-L07-1315-T03-C 1 2.38E+02
Cu CFS-L07-1315-T04-C 1 4.53E+02
Cu CFS-L07-1315-T05-C 1 5.56E+02
Cu CFS-L07-1315-T06-C 1 8.46E+02
Cu CFS-L07-1315-T07-C 1 8.03E+02
Cu CFS-L07-1315-T08-C 1 6.60E+02
Cu CFS-L07-1315-T09-C 1 9.08E+02
Cu CFS-L07-1315-M01-A 1 1.85E+00 U1/2
Cu CFS-L07-1315-M02-A 1 1.85E+00 U1/2
Cu CFS-L07-1315-M03-A 1 1.85E+00 U1/2
Cu CFS-L07-1315-M04-A 1 1.85E+00 U1/2
Cu CFS-L07-1315-M05-A 1 1.85E+00 U1/2
Cu CFS-L07-1315-M06-A 1 1.85E+00 U1/2
Cu CFS-L07-1315-M07-A 1 1.85E+00 U1/2
Cu CFS-L07-1315-M08-A 1 1.85E+00 U1/2
Cu CFS-L07-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.47E+01 1.13 3.70 11.80
2.59E+02 1.37 3.70 11.80
2.68E+02 2.42 3.70 11.80 10000 1000
4.61 E+02 0.97 3.70 11.80
5.78E+02 0.96 3.70 11.80
8.25E+02 1.33 3.70 11.80
8.23E+02 0.45 3.70 11.80
8.65E+02 1.16 3.70 11.80
9.62E+02 1.15 3.70 11.80
6.58E+01 7.17 3.70 11.80
2.93E+02 0.53 3.70 11.80
2.35E+02 1.13 3.70 11.80 10000 1000
4.50E+02 1.88 3.70 11.80
5.74E+02 0.55 3.70 11.80
7.99E+02 0.44 3.70 11.80
8.08E+02 1.21 3.70 11.80
6.65E+02 2.42 3.70 11.80
8.93E+02 2.07 3.70 11.80
9.57E+01 3.63 3.70 11.80
2.49E+02 1.57 3.70 11.80
2.38E+02 0.93 3.70 11.80 10000 1000
4.53E+02 4.12 3.70 11.80
5.56E+02 0.41 3.70 11.80
8.46E+02 1.36 3.70 11.80
8.03E+02 1.20 3.70 11.80
6.60E+02 1.43 3.70 11.80
9.08E+02 2.12 3.70 11.80
1.85E+00 24.68 3.70 11.80
1.85E+00 6.24 3.70 11.80
1.85E+00 8.42 3.70 11.80
1.85E+00 14.79 3.70 11.80
1.85E+00 6.03 3.70 11.80
1.85E+00 3.76 3.70 11.80
1.85E+00 15.17 3.70 11.80
1.85E+00 17.91 3.70 11.80
1.85E+00 10.58 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.17E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.19E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-855
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Fe CFS-L07-1315-T01-A 1 1.00E+00 U1/2
Fe CFS-L07-1315-T02-A 1 1.00E+00 U1/2
Fe CFS-L07-1315-T03-A 1 1.00E+00 U1/2
Fe CFS-L07-1315-T04-A 1 1.00E+00 U1/2
Fe CFS-L07-1315-T05-A 1 1.00E+00 U1/2
Fe CFS-L07-1315-T06-A 1 1.00E+00 U1/2
Fe CFS-L07-1315-T07-A 1 1.00E+00 U1/2
Fe CFS-L07-1315-T08-A 1 1.00E+00 U1/2
Fe CFS-L07-1315-T09-A 1 1.00E+00 U1/2
Fe CFS-L07-1315-T01-B 1 1.00E+00 U1/2
Fe CFS-L07-1315-T02-B 1 1.00E+00 U1/2
Fe CFS-L07-1315-T03-B 1 1.00E+00 U1/2
Fe CFS-L07-1315-T04-B 1 1.00E+00 U1/2
Fe CFS-L07-1315-T05-B 1 1.00E+00 U1/2
Fe CFS-L07-1315-T06-B 1 1.00E+00 U1/2
Fe CFS-L07-1315-T07-B 1 1.00E+00 U1/2
Fe CFS-L07-1315-T08-B 1 1.00E+00 U1/2
Fe CFS-L07-1315-T09-B 1 1.00E+00 U1/2
Fe CFS-L07-1315-T01-C 1 1.00E+00 U1/2
Fe CFS-L07-1315-T02-C 1 1.00E+00 U1/2
Fe CFS-L07-1315-T03-C 1 1.00E+00 U1/2
Fe CFS-L07-1315-T04-C 1 1.00E+00 U1/2
Fe CFS-L07-1315-T05-C 1 1.00E+00 U1/2
Fe CFS-L07-1315-T06-C 1 1.00E+00 U1/2
Fe CFS-L07-1315-T07-C 1 1.00E+00 U1/2
Fe CFS-L07-1315-T08-C 1 1.00E+00 U1/2
Fe CFS-L07-1315-T09-C 1 1.00E+00 U1/2
Fe CFS-L07-1315-M01-A 1 1.00E+00 U1/2
Fe CFS-L07-1315-M02-A 1 1.00E+00 U1/2
Fe CFS-L07-1315-M03-A 1 1.00E+00 U1/2
Fe CFS-L07-1315-M04-A 1 1.00E+00 U1/2
Fe CFS-L07-1315-M05-A 1 1.00E+00 U1/2
Fe CFS-L07-1315-M06-A 1 1.00E+00 U1/2
Fe CFS-L07-1315-M07-A 1 1.00E+00 U1/2
Fe CFS-L07-1315-M08-A 1 1.00E+00 U1/2
Fe CFS-L07-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 1.38 2.00 6.40
1.00E+00 4.05 2.00 6.40
1.00E+00 12.57 2.00 6.40 10000 1000
1.00E+00 3.18 2.00 6.40
1.00E+00 15.04 2.00 6.40
1.00E+00 13.64 2.00 6.40
1.00E+00 10.22 2.00 6.40
1.00E+00 1.88 2.00 6.40
1.00E+00 11.23 2.00 6.40
1.00E+00 10.36 2.00 6.40
1.00E+00 19.22 2.00 6.40
1.00E+00 1.43 2.00 6.40 10000 1000
1.00E+00 15.04 2.00 6.40
1.00E+00 26.46 2.00 6.40
1.00E+00 28.25 2.00 6.40
1.00E+00 11.96 2.00 6.40
1.00E+00 6.23 2.00 6.40
1.00E+00 6.91 2.00 6.40
1.00E+00 2.47 2.00 6.40
1.00E+00 2.75 2.00 6.40
1.00E+00 5.10 2.00 6.40 10000 1000
1.00E+00 2.80 2.00 6.40
1.00E+00 12.54 2.00 6.40
1.00E+00 4.78 2.00 6.40
1.00E+00 9.38 2.00 6.40
1.00E+00 10.77 2.00 6.40
1.00E+00 22.71 2.00 6.40
1.00E+00 25.83 2.00 6.40
1.00E+00 12.44 2.00 6.40
1.00E+00 19.11 2.00 6.40
1.00E+00 1.61 2.00 6.40
1.00E+00 0.48 2.00 6.40
1.00E+00 7.55 2.00 6.40
1.00E+00 15.93 2.00 6.40
1.00E+00 2.37 2.00 6.40
1.00E+00 3.56 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.31 E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.54E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.54E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-856
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Pb CFS-L07-1315-T01-A 1 1.46E+02
Pb CFS-L07-1315-T02-A 1 2.31 E+02
Pb CFS-L07-1315-T03-A 1 3.09E+02
Pb CFS-L07-1315-T04-A 1 5.31 E+02
Pb CFS-L07-1315-T05-A 1 6.19E+02
Pb CFS-L07-1315-T06-A 1 7.66E+02
Pb CFS-L07-1315-T07-A 1 6.68E+02
Pb CFS-L07-1315-T08-A 1 7.19E+02
Pb CFS-L07-1315-T09-A 1 8.03E+02
Pb CFS-L07-1315-T01-B 1 1.58E+02
Pb CFS-L07-1315-T02-B 1 3.26E+02
Pb CFS-L07-1315-T03-B 1 2.84E+02
Pb CFS-L07-1315-T04-B 1 4.88E+02
Pb CFS-L07-1315-T05-B 1 5.95E+02
Pb CFS-L07-1315-T06-B 1 7.38E+02
Pb CFS-L07-1315-T07-B 1 6.93E+02
Pb CFS-L07-1315-T08-B 1 5.68E+02
Pb CFS-L07-1315-T09-B 1 7.23E+02
Pb CFS-L07-1315-T01-C 1 1.22E+02
Pb CFS-L07-1315-T02-C 1 3.02E+02
Pb CFS-L07-1315-T03-C 1 2.86E+02
Pb CFS-L07-1315-T04-C 1 5.21E+02
Pb CFS-L07-1315-T05-C 1 5.62E+02
Pb CFS-L07-1315-T06-C 1 7.88E+02
Pb CFS-L07-1315-T07-C 1 6.69E+02
Pb CFS-L07-1315-T08-C 1 5.44E+02
Pb CFS-L07-1315-T09-C 1 7.00E+02
Pb CFS-L07-1315-M01-A 1 3.40E+00 U1/2
Pb CFS-L07-1315-M02-A 1 3.40E+00 U1/2
Pb CFS-L07-1315-M03-A 1 3.40E+00 U1/2
Pb CFS-L07-1315-M04-A 1 3.40E+00 U1/2
Pb CFS-L07-1315-M05-A 1 3.40E+00 U1/2
Pb CFS-L07-1315-M06-A 1 3.40E+00 U1/2
Pb CFS-L07-1315-M07-A 1 3.40E+00 U1/2
Pb CFS-L07-1315-M08-A 1 3.40E+00 U1/2
Pb CFS-L07-1315-M09-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.46E+02 0.94 6.80 21.60
2.31 E+02 0.90 6.80 21.60
3.09E+02 1.73 6.80 21.60 10000 1000
5.31E+02 1.10 6.80 21.60
6.19E+02 0.40 6.80 21.60
7.66E+02 1.30 6.80 21.60
6.68E+02 0.89 6.80 21.60
7.19E+02 1.29 6.80 21.60
8.03E+02 0.44 6.80 21.60
1.58E+02 5.16 6.80 21.60
3.26E+02 0.21 6.80 21.60
2.84E+02 1.87 6.80 21.60 10000 1000
4.88E+02 1.53 6.80 21.60
5.95E+02 0.63 6.80 21.60
7.38E+02 0.96 6.80 21.60
6.93E+02 0.32 6.80 21.60
5.68E+02 2.13 6.80 21.60
7.23E+02 3.65 6.80 21.60
1.22E+02 3.84 6.80 21.60
3.02E+02 2.35 6.80 21.60
2.86E+02 2.19 6.80 21.60 10000 1000
5.21 E+02 4.36 6.80 21.60
5.62E+02 1.59 6.80 21.60
7.88E+02 2.54 6.80 21.60
6.69E+02 1.70 6.80 21.60
5.44E+02 0.48 6.80 21.60
7.00E+02 2.36 6.80 21.60
3.40E+00 5.13 6.80 21.60
3.40E+00 17.16 6.80 21.60
3.40E+00 15.76 6.80 21.60
3.40E+00 11.50 6.80 21.60
3.40E+00 4.26 6.80 21.60
3.40E+00 6.70 6.80 21.60
3.40E+00 10.10 6.80 21.60
3.40E+00 14.06 6.80 21.60
3.40E+00 28.04 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.36E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.26E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.28E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-857
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Li CFS-L07-1315-T01-A 1 2.62E+00 E
Li CFS-L07-1315-T02-A 1 3.72E+00 E
Li CFS-L07-1315-T03-A 1 5.33E+00 E
Li CFS-L07-1315-T04-A 1 4.94E+00 E
Li CFS-L07-1315-T05-A 1 5.02E+00 E
Li CFS-L07-1315-T06-A 1 6.25E+00
Li CFS-L07-1315-T07-A 1 4.42E+00 E
Li CFS-L07-1315-T08-A 1 5.21E+00 E
Li CFS-L07-1315-T09-A 1 5.19E+00 E
Li CFS-L07-1315-T01-B 1 2.10E+00 E
Li CFS-L07-1315-T02-B 1 3.71E+00 E
Li CFS-L07-1315-T03-B 1 4.44E+00 E
Li CFS-L07-1315-T04-B 1 5.99E+00 E
Li CFS-L07-1315-T05-B 1 3.84E+00 E
Li CFS-L07-1315-T06-B 1 4.74E+00 E
Li CFS-L07-1315-T07-B 1 5.30E+00 E
Li CFS-L07-1315-T08-B 1 5.51E+00 E
Li CFS-L07-1315-T09-B 1 5.30E+00 E
Li CFS-L07-1315-T01-C 1 2.37E+00 E
Li CFS-L07-1315-T02-C 1 4.99E+00 E
Li CFS-L07-1315-T03-C 1 2.87E+00 E
Li CFS-L07-1315-T04-C 1 5.71E+00 E
Li CFS-L07-1315-T05-C 1 5.37E+00 E
Li CFS-L07-1315-T06-C 1 4.37E+00 E
Li CFS-L07-1315-T07-C 1 3.97E+00 E
Li CFS-L07-1315-T08-C 1 6.61 E+00
Li CFS-L07-1315-T09-C 1 6.00E+00 E
Li CFS-L07-1315-M01-A 1 9.50E-01 U1/2
Li CFS-L07-1315-M02-A 1 9.50E-01 U1/2
Li CFS-L07-1315-M03-A 1 9.50E-01 U1/2
Li CFS-L07-1315-M04-A 1 9.50E-01 U1/2
Li CFS-L07-1315-M05-A 1 9.50E-01 U1/2
Li CFS-L07-1315-M06-A 1 9.50E-01 U1/2
Li CFS-L07-1315-M07-A 1 9.50E-01 U1/2
Li CFS-L07-1315-M08-A 1 9.50E-01 U1/2
Li CFS-L07-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.62E+00 14.04 1.90 6.00
3.72E+00 20.02 1.90 6.00
5.33E+00 36.25 1.90 6.00 10000 1000
4.94E+00 3.81 1.90 6.00
5.02E+00 16.39 1.90 6.00
6.25E+00 14.34 1.90 6.00
4.42E+00 27.46 1.90 6.00
5.21 E+00 5.78 1.90 6.00
5.19E+00 11.69 1.90 6.00
2.10E+00 4.59 1.90 6.00
3.71E+00 5.11 1.90 6.00
4.44E+00 22.82 1.90 6.00 10000 1000
5.99E+00 22.13 1.90 6.00
3.84E+00 18.79 1.90 6.00
4.74E+00 40.35 1.90 6.00
5.30E+00 31.90 1.90 6.00
5.51E+00 10.66 1.90 6.00
5.30E+00 33.11 1.90 6.00
2.37E+00 19.42 1.90 6.00
4.99E+00 22.29 1.90 6.00
2.87E+00 27.16 1.90 6.00 10000 1000
5.71E+00 12.09 1.90 6.00
5.37E+00 31.79 1.90 6.00
4.37E+00 29.91 1.90 6.00
3.97E+00 3.69 1.90 6.00
6.61 E+00 3.21 1.90 6.00
6.00E+00 31.37 1.90 6.00
9.50E-01 16.49 1.90 6.00
9.50E-01 3.94 1.90 6.00
9.50E-01 28.22 1.90 6.00
9.50E-01 40.79 1.90 6.00
9.50E-01 59.39 1.90 6.00
9.50E-01 39.46 1.90 6.00
9.50E-01 56.81 1.90 6.00
9.50E-01 5.31 1.90 6.00
9.50E-01 37.85 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.89E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.95E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.55E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-858
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
Mn CFS-L07-1315-T01-A 1 3.76E+01
Mn CFS-L07-1315-T02-A 1 2.34E+02
Mn CFS-L07-1315-T03-A 1 2.54E+02
Mn CFS-L07-1315-T04-A 1 8.19E+02
Mn CFS-L07-1315-T05-A 1 1.00E+03
Mn CFS-L07-1315-T06-A 1 1.72E+03
Mn CFS-L07-1315-T07-A 1 1.62E+03
Mn CFS-L07-1315-T08-A 1 9.04E+02
Mn CFS-L07-1315-T09-A 1 1.47E+03
Mn CFS-L07-1315-T01-B 1 3.91E+01
Mn CFS-L07-1315-T02-B 1 2.35E+02
Mn CFS-L07-1315-T03-B 1 2.62E+02
Mn CFS-L07-1315-T04-B 1 8.43E+02
Mn CFS-L07-1315-T05-B 1 1.08E+03
Mn CFS-L07-1315-T06-B 1 1.79E+03
Mn CFS-L07-1315-T07-B 1 1.71E+03
Mn CFS-L07-1315-T08-B 1 9.28E+02
Mn CFS-L07-1315-T09-B 1 1.51E+03
Mn CFS-L07-1315-T01-C 1 3.16E+01
Mn CFS-L07-1315-T02-C 1 2.22E+02
Mn CFS-L07-1315-T03-C 1 2.34E+02
Mn CFS-L07-1315-T04-C 1 7.76E+02
Mn CFS-L07-1315-T05-C 1 9.94E+02
Mn CFS-L07-1315-T06-C 1 1.64E+03
Mn CFS-L07-1315-T07-C 1 1.55E+03
Mn CFS-L07-1315-T08-C 1 8.44E+02
Mn CFS-L07-1315-T09-C 1 1.42E+03
Mn CFS-L07-1315-M01-A 1 1.00E+00 U1/2
Mn CFS-L07-1315-M02-A 1 1.00E+00 U1/2
Mn CFS-L07-1315-M03-A 1 1.00E+00 U1/2
Mn CFS-L07-1315-M04-A 1 1.00E+00 U1/2
Mn CFS-L07-1315-M05-A 1 1.00E+00 U1/2
Mn CFS-L07-1315-M06-A 1 1.00E+00 U1/2
Mn CFS-L07-1315-M07-A 1 1.00E+00 U1/2
Mn CFS-L07-1315-M08-A 1 1.00E+00 U1/2
Mn CFS-L07-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.76E+01 0.70 2.00 6.40
2.34E+02 0.75 2.00 6.40
2.54E+02 0.55 2.00 6.40 10000 1000
8.19E+02 0.22 2.00 6.40
1.00E+03 0.82 2.00 6.40
1.72E+03 0.11 2.00 6.40
1.62E+03 0.97 2.00 6.40
9.04E+02 1.29 2.00 6.40
1.47E+03 0.42 2.00 6.40
3.91E+01 7.10 2.00 6.40
2.35E+02 1.67 2.00 6.40
2.62E+02 0.49 2.00 6.40 10000 1000
8.43E+02 0.55 2.00 6.40
1.08E+03 0.56 2.00 6.40
1.79E+03 0.53 2.00 6.40
1.71E+03 0.18 2.00 6.40
9.28E+02 1.65 2.00 6.40
1.51E+03 1.54 2.00 6.40
3.16E+01 3.90 2.00 6.40
2.22E+02 1.23 2.00 6.40
2.34E+02 1.00 2.00 6.40 10000 1000
7.76E+02 3.19 2.00 6.40
9.94E+02 2.01 2.00 6.40
1.64E+03 1.36 2.00 6.40
1.55E+03 0.69 2.00 6.40
8.44E+02 0.34 2.00 6.40
1.42E+03 1.25 2.00 6.40
1.00E+00 20.41 2.00 6.40
1.00E+00 11.96 2.00 6.40
1.00E+00 39.36 2.00 6.40
1.00E+00 36.33 2.00 6.40
1.00E+00 5.14 2.00 6.40
1.00E+00 11.21 2.00 6.40
1.00E+00 5.14 2.00 6.40
1.00E+00 4.54 2.00 6.40
1.00E+00 5.46 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.17E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.20E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-859
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Mg CFS-L07-1315-T01-A 1 2.37E+03
Mg CFS-L07-1315-T02-A 1 1.47E+04
Mg CFS-L07-1315-T03-A 1 1.76E+04
Mg CFS-L07-1315-T04-A 1 6.17E+04
Mg CFS-L07-1315-T05-A 1 7.33E+04
Mg CFS-L07-1315-T06-A 1 1.14E+05
Mg CFS-L07-1315-T07-A 1 9.59E+04
Mg CFS-L07-1315-T08-A 1 4.83E+04
Mg CFS-L07-1315-T09-A 1 7.40E+04
Mg CFS-L07-1315-T01-B 1 2.52E+03
Mg CFS-L07-1315-T02-B 1 1.51E+04
Mg CFS-L07-1315-T03-B 1 1.78E+04
Mg CFS-L07-1315-T04-B 1 6.15E+04
Mg CFS-L07-1315-T05-B 1 7.66E+04
Mg CFS-L07-1315-T06-B 1 1.17E+05
Mg CFS-L07-1315-T07-B 1 9.95E+04
Mg CFS-L07-1315-T08-B 1 4.90E+04
Mg CFS-L07-1315-T09-B 1 7.53E+04
Mg CFS-L07-1315-T01-C 1 2.23E+03
Mg CFS-L07-1315-T02-C 1 1.47E+04
Mg CFS-L07-1315-T03-C 1 1.69E+04
Mg CFS-L07-1315-T04-C 1 6.01 E+04
Mg CFS-L07-1315-T05-C 1 7.62E+04
Mg CFS-L07-1315-T06-C 1 1.19E+05
Mg CFS-L07-1315-T07-C 1 9.92E+04
Mg CFS-L07-1315-T08-C 1 4.93E+04
Mg CFS-L07-1315-T09-C 1 7.75E+04
Mg CFS-L07-1315-M01-A 1 5.00E-01 U1/2
Mg CFS-L07-1315-M02-A 1 5.00E-01 U1/2
Mg CFS-L07-1315-M03-A 1 5.00E-01 U1/2
Mg CFS-L07-1315-M04-A 1 5.00E-01 U1/2
Mg CFS-L07-1315-M05-A 1 5.00E-01 U1/2
Mg CFS-L07-1315-M06-A 1 5.00E-01 U1/2
Mg CFS-L07-1315-M07-A 1 5.00E-01 U1/2
Mg CFS-L07-1315-M08-A 1 5.00E-01 U1/2
Mg CFS-L07-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.37E+03 0.84 1.00 3.18
1.47E+04 0.14 1.00 3.18
1.76E+04 1.05 1.00 3.18 10000 1000
6.17E+04 0.76 1.00 3.18
7.33E+04 0.39 1.00 3.18
1.14E+05 1.14 1.00 3.18
9.59E+04 0.21 1.00 3.18
4.83E+04 0.39 1.00 3.18
7.40E+04 1.45 1.00 3.18
2.52E+03 5.01 1.00 3.18
1.51 E+04 0.49 1.00 3.18
1.78E+04 0.56 1.00 3.18 10000 1000
6.15E+04 1.43 1.00 3.18
7.66E+04 0.81 1.00 3.18
1.17E+05 0.52 1.00 3.18
9.95E+04 0.55 1.00 3.18
4.90E+04 2.36 1.00 3.18
7.53E+04 1.60 1.00 3.18
2.23E+03 3.62 1.00 3.18
1.47E+04 1.06 1.00 3.18
1.69E+04 1.99 1.00 3.18 10000 1000
6.01E+04 2.15 1.00 3.18
7.62E+04 1.75 1.00 3.18
1.19E+05 1.50 1.00 3.18
9.92E+04 0.93 1.00 3.18
4.93E+04 1.07 1.00 3.18
7.75E+04 2.42 1.00 3.18
5.00E-01 32.42 1.00 3.18
5.00E-01 7.34 1.00 3.18
5.00E-01 24.34 1.00 3.18
5.00E-01 18.09 1.00 3.18
5.00E-01 10.79 1.00 3.18
5.00E-01 21.24 1.00 3.18
5.00E-01 32.41 1.00 3.18
5.00E-01 59.12 1.00 3.18
5.00E-01 25.71 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.85E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.87E+04 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.78E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-860
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Mo CFS-L07-1315-T01-A 1 1.37E+00 E
Mo CFS-L07-1315-T02-A 1 2.02E+00 E
Mo CFS-L07-1315-T03-A 1 2.28E+00 E
Mo CFS-L07-1315-T04-A 1 3.63E+00 E
Mo CFS-L07-1315-T05-A 1 2.88E+00 E
Mo CFS-L07-1315-T06-A 1 4.37E+00
Mo CFS-L07-1315-T07-A 1 2.61E+00 E
Mo CFS-L07-1315-T08-A 1 1.96E+00 E
Mo CFS-L07-1315-T09-A 1 3.22E+00 E
Mo CFS-L07-1315-T01-B 1 3.72E+00 E
Mo CFS-L07-1315-T02-B 1 3.14E+00 E
Mo CFS-L07-1315-T03-B 1 2.95E+00 E
Mo CFS-L07-1315-T04-B 1 3.95E+00
Mo CFS-L07-1315-T05-B 1 4.55E+00
Mo CFS-L07-1315-T06-B 1 4.44E+00
Mo CFS-L07-1315-T07-B 1 5.19E+00
Mo CFS-L07-1315-T08-B 1 3.49E+00 E
Mo CFS-L07-1315-T09-B 1 3.47E+00 E
Mo CFS-L07-1315-T01-C 1 1.90E+00 E
Mo CFS-L07-1315-T02-C 1 1.72E+00 E
Mo CFS-L07-1315-T03-C 1 1.83E+00 E
Mo CFS-L07-1315-T04-C 1 1.72E+00 E
Mo CFS-L07-1315-T05-C 1 2.44E+00 E
Mo CFS-L07-1315-T06-C 1 3.67E+00 E
Mo CFS-L07-1315-T07-C 1 4.00E+00
Mo CFS-L07-1315-T08-C 1 3.59E+00 E
Mo CFS-L07-1315-T09-C 1 2.57E+00 E
Mo CFS-L07-1315-M01-A 1 6.00E-01 U1/2
Mo CFS-L07-1315-M02-A 1 6.00E-01 U1/2
Mo CFS-L07-1315-M03-A 1 6.00E-01 U1/2
Mo CFS-L07-1315-M04-A 1 6.00E-01 U1/2
Mo CFS-L07-1315-M05-A 1 6.00E-01 U1/2
Mo CFS-L07-1315-M06-A 1 6.00E-01 U1/2
Mo CFS-L07-1315-M07-A 1 6.00E-01 U1/2
Mo CFS-L07-1315-M08-A 1 6.00E-01 U1/2
Mo CFS-L07-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.37E+00 30.61 1.20 3.82
2.02E+00 35.43 1.20 3.82
2.28E+00 21.94 1.20 3.82 10000 1000
3.63E+00 37.29 1.20 3.82
2.88E+00 23.50 1.20 3.82
4.37E+00 4.46 1.20 3.82
2.61E+00 6.90 1.20 3.82
1.96E+00 22.60 1.20 3.82
3.22E+00 30.26 1.20 3.82
3.72E+00 21.58 1.20 3.82
3.14E+00 30.07 1.20 3.82
2.95E+00 23.69 1.20 3.82 10000 1000
3.95E+00 21.11 1.20 3.82
4.55E+00 5.34 1.20 3.82
4.44E+00 1.99 1.20 3.82
5.19E+00 2.07 1.20 3.82
3.49E+00 21.90 1.20 3.82
3.47E+00 19.08 1.20 3.82
1.90E+00 59.03 1.20 3.82
1.72E+00 16.53 1.20 3.82
1.83E+00 20.15 1.20 3.82 10000 1000
1.72E+00 35.10 1.20 3.82
2.44E+00 7.05 1.20 3.82
3.67E+00 7.79 1.20 3.82
4.00E+00 2.46 1.20 3.82
3.59E+00 15.79 1.20 3.82
2.57E+00 21.68 1.20 3.82
6.00E-01 4.27 1.20 3.82
6.00E-01 4.37 1.20 3.82
6.00E-01 28.46 1.20 3.82
6.00E-01 22.74 1.20 3.82
6.00E-01 34.82 1.20 3.82
6.00E-01 31.38 1.20 3.82
6.00E-01 4.58 1.20 3.82
6.00E-01 5.68 1.20 3.82
6.00E-01 15.13 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.21E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.38E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.30E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-861
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Ni CFS-L07-1315-T01-A 1 9.00E-01 U1/2
Ni CFS-L07-1315-T02-A 1 1.77E+01
Ni CFS-L07-1315-T03-A 1 1.65E+01
Ni CFS-L07-1315-T04-A 1 5.63E+01
Ni CFS-L07-1315-T05-A 1 7.01E+01
Ni CFS-L07-1315-T06-A 1 1.07E+02
Ni CFS-L07-1315-T07-A 1 9.05E+01
Ni CFS-L07-1315-T08-A 1 4.95E+01
Ni CFS-L07-1315-T09-A 1 7.37E+01
Ni CFS-L07-1315-T01-B 1 9.00E-01 U1/2
Ni CFS-L07-1315-T02-B 1 1.52E+01
Ni CFS-L07-1315-T03-B 1 1.65E+01
Ni CFS-L07-1315-T04-B 1 5.88E+01
Ni CFS-L07-1315-T05-B 1 7.28E+01
Ni CFS-L07-1315-T06-B 1 1.07E+02
Ni CFS-L07-1315-T07-B 1 9.12E+01
Ni CFS-L07-1315-T08-B 1 5.16E+01
Ni CFS-L07-1315-T09-B 1 7.39E+01
Ni CFS-L07-1315-T01-C 1 9.00E-01 U1/2
Ni CFS-L07-1315-T02-C 1 1.54E+01
Ni CFS-L07-1315-T03-C 1 1.45E+01
Ni CFS-L07-1315-T04-C 1 5.37E+01
Ni CFS-L07-1315-T05-C 1 6.79E+01
Ni CFS-L07-1315-T06-C 1 1.04E+02
Ni CFS-L07-1315-T07-C 1 8.49E+01
Ni CFS-L07-1315-T08-C 1 4.94E+01
Ni CFS-L07-1315-T09-C 1 7.04E+01
Ni CFS-L07-1315-M01-A 1 9.00E-01 U1/2
Ni CFS-L07-1315-M02-A 1 9.00E-01 U1/2
Ni CFS-L07-1315-M03-A 1 9.00E-01 U1/2
Ni CFS-L07-1315-M04-A 1 9.00E-01 U1/2
Ni CFS-L07-1315-M05-A 1 9.00E-01 U1/2
Ni CFS-L07-1315-M06-A 1 9.00E-01 U1/2
Ni CFS-L07-1315-M07-A 1 9.00E-01 U1/2
Ni CFS-L07-1315-M08-A 1 9.00E-01 U1/2
Ni CFS-L07-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.00E-01 9.17 1.80 5.70
1.77E+01 5.23 1.80 5.70
1.65E+01 5.21 1.80 5.70 10000 1000
5.63E+01 1.27 1.80 5.70
7.01 E+01 3.83 1.80 5.70
1.07E+02 1.60 1.80 5.70
9.05E+01 3.95 1.80 5.70
4.95E+01 1.33 1.80 5.70
7.37E+01 3.22 1.80 5.70
9.00E-01 6.16 1.80 5.70
1.52E+01 3.35 1.80 5.70
1.65E+01 5.50 1.80 5.70 10000 1000
5.88E+01 3.66 1.80 5.70
7.28E+01 1.58 1.80 5.70
1.07E+02 1.94 1.80 5.70
9.12E+01 2.20 1.80 5.70
5.16E+01 2.70 1.80 5.70
7.39E+01 4.43 1.80 5.70
9.00E-01 7.70 1.80 5.70
1.54E+01 6.27 1.80 5.70
1.45E+01 8.94 1.80 5.70 10000 1000
5.37E+01 6.12 1.80 5.70
6.79E+01 1.82 1.80 5.70
1.04E+02 0.92 1.80 5.70
8.49E+01 2.78 1.80 5.70
4.94E+01 0.26 1.80 5.70
7.04E+01 3.31 1.80 5.70
9.00E-01 34.94 1.80 5.70
9.00E-01 31.88 1.80 5.70
9.00E-01 5.54 1.80 5.70
9.00E-01 27.71 1.80 5.70
9.00E-01 42.37 1.80 5.70
9.00E-01 33.88 1.80 5.70
9.00E-01 19.20 1.80 5.70
9.00E-01 30.77 1.80 5.70
9.00E-01 38.29 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.36E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.64E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.50E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-862
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
P CFS-L07-1315-T01-A 1 6.81E+00 E
P CFS-L07-1315-T02-A 1 9.89E+00 E
P CFS-L07-1315-T03-A 1 8.40E+00 E
P CFS-L07-1315-T04-A 1 1.57E+01
P CFS-L07-1315-T05-A 1 1.92E+01
P CFS-L07-1315-T06-A 1 1.22E+01
P CFS-L07-1315-T07-A 1 7.11E+OOE
P CFS-L07-1315-T08-A 1 6.59E+00 E
P CFS-L07-1315-T09-A 1 5.33E+00 E
P CFS-L07-1315-T01-B 1 5.26E+00 E
P CFS-L07-1315-T02-B 1 7.51E+00 E
P CFS-L07-1315-T03-B 1 1.41E+01
P CFS-L07-1315-T04-B 1 1.65E+01
P CFS-L07-1315-T05-B 1 2.05E+01
P CFS-L07-1315-T06-B 1 1.54E+01
P CFS-L07-1315-T07-B 1 8.37E+00 E
P CFS-L07-1315-T08-B 1 4.50E+00 E
P CFS-L07-1315-T09-B 1 5.18E+00 E
P CFS-L07-1315-T01-C 1 4.69E+00 E
P CFS-L07-1315-T02-C 1 1.08E+01 E
P CFS-L07-1315-T03-C 1 1.04E+01 E
P CFS-L07-1315-T04-C 1 1.91E+01
P CFS-L07-1315-T05-C 1 2.24E+01
P CFS-L07-1315-T06-C 1 1.47E+01
P CFS-L07-1315-T07-C 1 9.67E+00 E
P CFS-L07-1315-T08-C 1 5.05E+00 E
P CFS-L07-1315-T09-C 1 6.20E+00 E
P CFS-L07-1315-M01-A 1 1.85E+00 U1/2
P CFS-L07-1315-M02-A 1 1.85E+00 U1/2
P CFS-L07-1315-M03-A 1 1.85E+00 U1/2
P CFS-L07-1315-M04-A 1 1.85E+00 U1/2
P CFS-L07-1315-M05-A 1 1.85E+00 U1/2
P CFS-L07-1315-M06-A 1 1.85E+00 U1/2
P CFS-L07-1315-M07-A 1 1.85E+00 U1/2
P CFS-L07-1315-M08-A 1 1.85E+00 U1/2
P CFS-L07-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.81 E+00 27.74 3.70 11.80
9.89E+00 23.45 3.70 11.80
8.40E+00 17.80 3.70 11.80 10000 1000
1.57E+01 4.67 3.70 11.80
1.92E+01 4.48 3.70 11.80
1.22E+01 8.34 3.70 11.80
7. 11 E+00 6.50 3.70 11.80
6.59E+00 28.99 3.70 11.80
5.33E+00 19.30 3.70 11.80
5.26E+00 14.19 3.70 11.80
7. 51 E+00 37.45 3.70 11.80
1.41E+01 3.14 3.70 11.80 10000 1000
1.65E+01 5.69 3.70 11.80
2.05E+01 9.01 3.70 11.80
1.54E+01 16.98 3.70 11.80
8.37E+00 17.26 3.70 11.80
4.50E+00 10.72 3.70 11.80
5.18E+00 31.70 3.70 11.80
4.69E+00 28.99 3.70 11.80
1.08E+01 17.48 3.70 11.80
1.04E+01 27.75 3.70 11.80 10000 1000
1.91E+01 1.67 3.70 11.80
2.24E+01 11.68 3.70 11.80
1.47E+01 7.79 3.70 11.80
9.67E+00 9.12 3.70 11.80
5.05E+00 12.92 3.70 11.80
6.20E+00 17.84 3.70 11.80
1.85E+00 13.23 3.70 11.80
1.85E+00 42.26 3.70 11.80
1.85E+00 23.27 3.70 11.80
1.85E+00 46.73 3.70 11.80
1.85E+00 28.29 3.70 11.80
1.85E+00 37.16 3.70 11.80
1.85E+00 7.51 3.70 11.80
1.85E+00 11.05 3.70 11.80
1.85E+00 13.79 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.36E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.41E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.30E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-863
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
K CFS-L07-1315-T01-A 1 3.21E+02
K CFS-L07-1315-T02-A 1 2.43E+03
K CFS-L07-1315-T03-A 1 2.23E+03
K CFS-L07-1315-T04-A 1 7.32E+03
K CFS-L07-1315-T05-A 1 8.08E+03
K CFS-L07-1315-T06-A 1 1.20E+04
K CFS-L07-1315-T07-A 1 9.27E+03
K CFS-L07-1315-T08-A 1 4.38E+03
K CFS-L07-1315-T09-A 1 6.39E+03
K CFS-L07-1315-T01-B 1 3.40E+02
K CFS-L07-1315-T02-B 1 2.31E+03
K CFS-L07-1315-T03-B 1 2.22E+03
K CFS-L07-1315-T04-B 1 7.41 E+03
K CFS-L07-1315-T05-B 1 8.33E+03
K CFS-L07-1315-T06-B 1 1.20E+04
K CFS-L07-1315-T07-B 1 9.46E+03
K CFS-L07-1315-T08-B 1 4.44E+03
K CFS-L07-1315-T09-B 1 6.51 E+03
K CFS-L07-1315-T01-C 1 3.07E+02
K CFS-L07-1315-T02-C 1 2.23E+03
K CFS-L07-1315-T03-C 1 2.07E+03
K CFS-L07-1315-T04-C 1 7.14E+03
K CFS-L07-1315-T05-C 1 8.12E+03
K CFS-L07-1315-T06-C 1 1.21E+04
K CFS-L07-1315-T07-C 1 9.32E+03
K CFS-L07-1315-T08-C 1 4.41 E+03
K CFS-L07-1315-T09-C 1 6.49E+03
K CFS-L07-1315-M01-A 1 2.50E+01
K CFS-L07-1315-M02-A 1 2.90E+01
K CFS-L07-1315-M03-A 1 2.46E+01
K CFS-L07-1315-M04-A 1 3.06E+01
K CFS-L07-1315-M05-A 1 2.80E+01
K CFS-L07-1315-M06-A 1 2.55E+01
K CFS-L07-1315-M07-A 1 3.12E+01
K CFS-L07-1315-M08-A 1 1.61E+01
K CFS-L07-1315-M09-A 1 1.77E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.21 E+02 1.44 1.60 5.09
2.43E+03 0.35 1.60 5.09
2.23E+03 0.95 1.60 5.09 10000 1000
7.32E+03 0.55 1.60 5.09
8.08E+03 0.55 1.60 5.09
1.20E+04 1.43 1.60 5.09
9.27E+03 0.98 1.60 5.09
4.38E+03 0.69 1.60 5.09
6.39E+03 0.97 1.60 5.09
3.40E+02 5.33 1.60 5.09
2. 31 E+03 0.36 1.60 5.09
2.22E+03 1.27 1.60 5.09 10000 1000
7.41 E+03 1.96 1.60 5.09
8.33E+03 0.48 1.60 5.09
1.20E+04 0.58 1.60 5.09
9.46E+03 0.60 1.60 5.09
4.44E+03 2.26 1.60 5.09
6.51 E+03 2.77 1.60 5.09
3.07E+02 3.43 1.60 5.09
2.23E+03 0.76 1.60 5.09
2.07E+03 1.46 1.60 5.09 10000 1000
7.14E+03 4.11 1.60 5.09
8.12E+03 1.27 1.60 5.09
1.21E+04 1.27 1.60 5.09
9.32E+03 1.76 1.60 5.09
4.41 E+03 0.88 1.60 5.09
6.49E+03 2.14 1.60 5.09
2.50E+01 3.56 1.60 5.09
2.90E+01 8.00 1.60 5.09
2.46E+01 5.08 1.60 5.09
3.06E+01 1.47 1.60 5.09
2.80E+01 0.81 1.60 5.09
2.55E+01 5.81 1.60 5.09
3.12E+01 9.70 1.60 5.09
1.61E+01 8.91 1.60 5.09
1.77E+01 6.27 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.12E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.10E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.92E+03 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-864
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L
Se CFS-L07-1315-T01-A 1 1.53E+01 E
Se CFS-L07-1315-T02-A 1 1.76E+01 E
Se CFS-L07-1315-T03-A 1 2.65E+01 E
Se CFS-L07-1315-T04-A 1 5.49E+01
Se CFS-L07-1315-T05-A 1 6.44E+01
Se CFS-L07-1315-T06-A 1 8.87E+01
Se CFS-L07-1315-T07-A 1 5.83E+01
Se CFS-L07-1315-T08-A 1 2.83E+01 E
Se CFS-L07-1315-T09-A 1 2.42E+01 E
Se CFS-L07-1315-T01-B 1 1.69E+01 E
Se CFS-L07-1315-T02-B 1 2.23E+01 E
Se CFS-L07-1315-T03-B 1 2.83E+01 E
Se CFS-L07-1315-T04-B 1 5.16E+01
Se CFS-L07-1315-T05-B 1 6.00E+01
Se CFS-L07-1315-T06-B 1 1.03E+02
Se CFS-L07-1315-T07-B 1 6.50E+01
Se CFS-L07-1315-T08-B 1 2.32E+01 E
Se CFS-L07-1315-T09-B 1 2.42E+01 E
Se CFS-L07-1315-T01-C 1 1.55E+01 E
Se CFS-L07-1315-T02-C 1 2.02E+01 E
Se CFS-L07-1315-T03-C 1 2.74E+01 E
Se CFS-L07-1315-T04-C 1 5.54E+01
Se CFS-L07-1315-T05-C 1 6.26E+01
Se CFS-L07-1315-T06-C 1 1.02E+02
Se CFS-L07-1315-T07-C 1 6.20E+01
Se CFS-L07-1315-T08-C 1 3.44E+01 E
Se CFS-L07-1315-T09-C 1 2.04E+01 E
Se CFS-L07-1315-M01-A 1 7.50E+00 U1/2
Se CFS-L07-1315-M02-A 1 7.50E+00 U1/2
Se CFS-L07-1315-M03-A 1 7.50E+00 U1/2
Se CFS-L07-1315-M04-A 1 7.50E+00 U1/2
Se CFS-L07-1315-M05-A 1 7.50E+00 U1/2
Se CFS-L07-1315-M06-A 1 7.50E+00 U1/2
Se CFS-L07-1315-M07-A 1 7.50E+00 U1/2
Se CFS-L07-1315-M08-A 1 7.50E+00 U1/2
Se CFS-L07-1315-M09-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.53E+01 4.18 15.00 47.70
1.76E+01 16.32 15.00 47.70
2.65E+01 14.61 15.00 47.70 10000 1000
5.49E+01 9.16 15.00 47.70
6.44E+01 7.42 15.00 47.70
8.87E+01 1.30 15.00 47.70
5.83E+01 3.62 15.00 47.70
2.83E+01 9.08 15.00 47.70
2.42E+01 7.54 15.00 47.70
1.69E+01 8.31 15.00 47.70
2.23E+01 11.67 15.00 47.70
2.83E+01 6.98 15.00 47.70 10000 1000
5.16E+01 13.20 15.00 47.70
6.00E+01 7.70 15.00 47.70
1.03E+02 6.41 15.00 47.70
6.50E+01 1.66 15.00 47.70
2.32E+01 13.33 15.00 47.70
2.42E+01 11.64 15.00 47.70
1.55E+01 4.12 15.00 47.70
2.02E+01 7.23 15.00 47.70
2.74E+01 10.55 15.00 47.70 10000 1000
5.54E+01 5.72 15.00 47.70
6.26E+01 9.23 15.00 47.70
1.02E+02 5.33 15.00 47.70
6.20E+01 5.18 15.00 47.70
3.44E+01 19.28 15.00 47.70
2.04E+01 8.75 15.00 47.70
7.50E+00 16.52 15.00 47.70
7.50E+00 7.49 15.00 47.70
7.50E+00 12.78 15.00 47.70
7.50E+00 13.42 15.00 47.70
7.50E+00 25.63 15.00 47.70
7.50E+00 3.18 15.00 47.70
7.50E+00 14.40 15.00 47.70
7.50E+00 29.25 15.00 47.70
7.50E+00 9.95 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.25E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.55E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.46E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/1 1 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/1 1 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/1 1 4:39 PM EPA Interlab L07 1315 CFS
9/12/1 1 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-865
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Si CFS-L07-1315-T01-A 1 5.34E+01
Si CFS-L07-1315-T02-A 1 3.08E+02
Si CFS-L07-1315-T03-A 1 3.16E+02
Si CFS-L07-1315-T04-A 1 9.16E+02
Si CFS-L07-1315-T05-A 1 1.14E+03
Si CFS-L07-1315-T06-A 1 1.87E+03
Si CFS-L07-1315-T07-A 1 1.68E+03
Si CFS-L07-1315-T08-A 1 9.92E+02
Si CFS-L07-1315-T09-A 1 1.54E+03
Si CFS-L07-1315-T01-B 1 6.47E+01
Si CFS-L07-1315-T02-B 1 3.07E+02
Si CFS-L07-1315-T03-B 1 3.03E+02
Si CFS-L07-1315-T04-B 1 8.88E+02
Si CFS-L07-1315-T05-B 1 1.13E+03
Si CFS-L07-1315-T06-B 1 1.82E+03
Si CFS-L07-1315-T07-B 1 1.68E+03
Si CFS-L07-1315-T08-B 1 9.59E+02
Si CFS-L07-1315-T09-B 1 1.52E+03
Si CFS-L07-1315-T01-C 1 5.10E+01
Si CFS-L07-1315-T02-C 1 3.01 E+02
Si CFS-L07-1315-T03-C 1 2.84E+02
Si CFS-L07-1315-T04-C 1 8.84E+02
Si CFS-L07-1315-T05-C 1 1.12E+03
Si CFS-L07-1315-T06-C 1 1.85E+03
Si CFS-L07-1315-T07-C 1 1.62E+03
Si CFS-L07-1315-T08-C 1 9.26E+02
Si CFS-L07-1315-T09-C 1 1.45E+03
Si CFS-L07-1315-M01-A 1 5.50E-01 U1/2
Si CFS-L07-1315-M02-A 1 5.50E-01 U1/2
Si CFS-L07-1315-M03-A 1 5.50E-01 U1/2
Si CFS-L07-1315-M04-A 1 5.50E-01 U1/2
Si CFS-L07-1315-M05-A 1 5.50E-01 U1/2
Si CFS-L07-1315-M06-A 1 5.50E-01 U1/2
Si CFS-L07-1315-M07-A 1 5.50E-01 U1/2
Si CFS-L07-1315-M08-A 1 5.50E-01 U1/2
Si CFS-L07-1315-M09-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.34E+01 2.71 1.10 3.50
3.08E+02 1.65 1.10 3.50
3.16E+02 1.55 1.10 3.50 10000 1000
9.16E+02 0.71 1.10 3.50
1.14E+03 0.87 1.10 3.50
1.87E+03 1.13 1.10 3.50
1.68E+03 1.21 1.10 3.50
9.92E+02 0.80 1.10 3.50
1.54E+03 0.39 1.10 3.50
6.47E+01 6.54 1.10 3.50
3.07E+02 0.89 1.10 3.50
3.03E+02 0.11 1.10 3.50 10000 1000
8.88E+02 2.18 1.10 3.50
1.13E+03 0.62 1.10 3.50
1.82E+03 0.91 1.10 3.50
1.68E+03 1.38 1.10 3.50
9.59E+02 2.13 1.10 3.50
1.52E+03 2.60 1.10 3.50
5.10E+01 4.44 1.10 3.50
3.01 E+02 0.64 1.10 3.50
2.84E+02 1.35 1.10 3.50 10000 1000
8.84E+02 4.06 1.10 3.50
1.12E+03 1.86 1.10 3.50
1.85E+03 1.98 1.10 3.50
1.62E+03 2.23 1.10 3.50
9.26E+02 1.12 1.10 3.50
1.45E+03 2.28 1.10 3.50
5.50E-01 6.67 1.10 3.50
5.50E-01 9.75 1.10 3.50
5.50E-01 13.86 1.10 3.50
5.50E-01 5.78 1.10 3.50
5.50E-01 3.79 1.10 3.50
5.50E-01 11.96 1.10 3.50
5.50E-01 10.90 1.10 3.50
5.50E-01 22.20 1.10 3.50
5.50E-01 4.24 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.26E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.24E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-866
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Na CFS-L07-1315-T01-A 1 1.40E+03
Na CFS-L07-1315-T02-A 1 8.81 E+03
Na CFS-L07-1315-T03-A 1 8.94E+03
Na CFS-L07-1315-T04-A 1 2.84E+04
Na CFS-L07-1315-T05-A 1 2.97E+04
Na CFS-L07-1315-T06-A 1 3.99E+04
Na CFS-L07-1315-T07-A 1 2.86E+04
Na CFS-L07-1315-T08-A 1 1.19E+04
Na CFS-L07-1315-T09-A 1 1.61E+04
Na CFS-L07-1315-T01-B 1 1.49E+03
Na CFS-L07-1315-T02-B 1 8.83E+03
Na CFS-L07-1315-T03-B 1 9.21E+03
Na CFS-L07-1315-T04-B 1 2.93E+04
Na CFS-L07-1315-T05-B 1 3.09E+04
Na CFS-L07-1315-T06-B 1 4.09E+04
Na CFS-L07-1315-T07-B 1 2.96E+04
Na CFS-L07-1315-T08-B 1 1.24E+04
Na CFS-L07-1315-T09-B 1 1.65E+04
Na CFS-L07-1315-T01-C 1 1.39E+03
Na CFS-L07-1315-T02-C 1 8.45E+03
Na CFS-L07-1315-T03-C 1 8.51 E+03
Na CFS-L07-1315-T04-C 1 2.82E+04
Na CFS-L07-1315-T05-C 1 3.04E+04
Na CFS-L07-1315-T06-C 1 4.04E+04
Na CFS-L07-1315-T07-C 1 2.87E+04
Na CFS-L07-1315-T08-C 1 1.22E+04
Na CFS-L07-1315-T09-C 1 1.67E+04
Na CFS-L07-1315-M01-A 1 4.30E+01
Na CFS-L07-1315-M02-A 1 4.23E+01
Na CFS-L07-1315-M03-A 1 3.99E+01
Na CFS-L07-1315-M04-A 1 3.90E+01
Na CFS-L07-1315-M05-A 1 3.24E+01
Na CFS-L07-1315-M06-A 1 4.55E+01
Na CFS-L07-1315-M07-A 1 3.90E+01
Na CFS-L07-1315-M08-A 1 3.28E+01
Na CFS-L07-1315-M09-A 1 3.60E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.40E+03 0.39 2.50 8.00
8.81 E+03 0.80 2.50 8.00
8.94E+03 0.35 2.50 8.00 10000 1000
2.84E+04 0.65 2.50 8.00
2.97E+04 0.28 2.50 8.00
3.99E+04 0.19 2.50 8.00
2.86E+04 0.50 2.50 8.00
1.19E+04 0.11 2.50 8.00
1.61E+04 0.60 2.50 8.00
1.49E+03 0.60 2.50 8.00
8.83E+03 0.52 2.50 8.00
9.21E+03 0.46 2.50 8.00 10000 1000
2.93E+04 0.89 2.50 8.00
3.09E+04 0.07 2.50 8.00
4.09E+04 0.10 2.50 8.00
2.96E+04 0.55 2.50 8.00
1.24E+04 0.94 2.50 8.00
1.65E+04 1.49 2.50 8.00
1.39E+03 0.44 2.50 8.00
8.45E+03 0.60 2.50 8.00
8.51E+03 0.42 2.50 8.00 10000 1000
2.82E+04 0.58 2.50 8.00
3.04E+04 0.55 2.50 8.00
4.04E+04 0.13 2.50 8.00
2.87E+04 0.20 2.50 8.00
1.22E+04 0.79 2.50 8.00
1.67E+04 0.35 2.50 8.00
4.30E+01 9.57 2.50 8.00
4.23E+01 3.98 2.50 8.00
3.99E+01 1.88 2.50 8.00
3.90E+01 1.19 2.50 8.00
3.24E+01 2.89 2.50 8.00
4.55E+01 2.09 2.50 8.00
3.90E+01 1.79 2.50 8.00
3.28E+01 0.33 2.50 8.00
3.60E+01 1.86 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.83E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+04 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.49E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-867
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
Sr CFS-L07-1315-T01-A 1 2.88E+01
Sr CFS-L07-1315-T02-A 1 1.42E+02
Sr CFS-L07-1315-T03-A 1 1.55E+02
Sr CFS-L07-1315-T04-A 1 4.28E+02
Sr CFS-L07-1315-T05-A 1 5.22E+02
Sr CFS-L07-1315-T06-A 1 8.50E+02
Sr CFS-L07-1315-T07-A 1 7.98E+02
Sr CFS-L07-1315-T08-A 1 4.61 E+02
Sr CFS-L07-1315-T09-A 1 7.24E+02
Sr CFS-L07-1315-T01-B 1 2.92E+01
Sr CFS-L07-1315-T02-B 1 1.47E+02
Sr CFS-L07-1315-T03-B 1 1.49E+02
Sr CFS-L07-1315-T04-B 1 4.09E+02
Sr CFS-L07-1315-T05-B 1 5.18E+02
Sr CFS-L07-1315-T06-B 1 8.32E+02
Sr CFS-L07-1315-T07-B 1 7.93E+02
Sr CFS-L07-1315-T08-B 1 4.50E+02
Sr CFS-L07-1315-T09-B 1 7.30E+02
Sr CFS-L07-1315-T01-C 1 2.74E+01
Sr CFS-L07-1315-T02-C 1 1.44E+02
Sr CFS-L07-1315-T03-C 1 1.35E+02
Sr CFS-L07-1315-T04-C 1 4.00E+02
Sr CFS-L07-1315-T05-C 1 5.12E+02
Sr CFS-L07-1315-T06-C 1 8.60E+02
Sr CFS-L07-1315-T07-C 1 8.06E+02
Sr CFS-L07-1315-T08-C 1 4.58E+02
Sr CFS-L07-1315-T09-C 1 7.38E+02
Sr CFS-L07-1315-M01-A 1 5.00E-01 U1/2
Sr CFS-L07-1315-M02-A 1 5.00E-01 U1/2
Sr CFS-L07-1315-M03-A 1 5.00E-01 U1/2
Sr CFS-L07-1315-M04-A 1 5.00E-01 U1/2
Sr CFS-L07-1315-M05-A 1 5.00E-01 U1/2
Sr CFS-L07-1315-M06-A 1 5.00E-01 U1/2
Sr CFS-L07-1315-M07-A 1 5.00E-01 U1/2
Sr CFS-L07-1315-M08-A 1 5.00E-01 U1/2
Sr CFS-L07-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.88E+01 1.74 1.00 3.18
1.42E+02 0.57 1.00 3.18
1.55E+02 0.94 1.00 3.18 10000 1000
4.28E+02 0.81 1.00 3.18
5.22E+02 0.49 1.00 3.18
8.50E+02 1.12 1.00 3.18
7.98E+02 0.69 1.00 3.18
4.61E+02 0.61 1.00 3.18
7.24E+02 1.13 1.00 3.18
2.92E+01 8.73 1.00 3.18
1.47E+02 0.71 1.00 3.18
1.49E+02 0.94 1.00 3.18 10000 1000
4.09E+02 1.80 1.00 3.18
5.18E+02 0.59 1.00 3.18
8.32E+02 0.80 1.00 3.18
7.93E+02 1.49 1.00 3.18
4.50E+02 2.04 1.00 3.18
7.30E+02 3.73 1.00 3.18
2.74E+01 3.96 1.00 3.18
1.44E+02 0.96 1.00 3.18
1.35E+02 1.49 1.00 3.18 10000 1000
4.00E+02 4.60 1.00 3.18
5.12E+02 1.49 1.00 3.18
8.60E+02 1.21 1.00 3.18
8.06E+02 2.38 1.00 3.18
4.58E+02 1.37 1.00 3.18
7.38E+02 1.68 1.00 3.18
5.00E-01 60.83 1.00 3.18
5.00E-01 53.18 1.00 3.18
5.00E-01 70.10 1.00 3.18
5.00E-01 59.39 1.00 3.18
5.00E-01 42.68 1.00 3.18
5.00E-01 30.74 1.00 3.18
5.00E-01 7.80 1.00 3.18
5.00E-01 69.24 1.00 3.18
5.00E-01 49.67 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1 . 1 9E+03 1 03% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.20E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-868
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
S CFS-L07-1315-T01-A 1 1.20E+04
S CFS-L07-1315-T02-A 1 5.18E+04
S CFS-L07-1315-T03-A 1 5.83E+04
S CFS-L07-1315-T04-A 1 1.56E+05
S CFS-L07-1315-T05-A 1 1.80E+05
S CFS-L07-1315-T06-A 1 2.74E+05
S CFS-L07-1315-T07-A 1 2.36E+05
S CFS-L07-1315-T08-A 1 1.27E+05
S CFS-L07-1315-T09-A 1 1.98E+05
S CFS-L07-1315-T01-B 1 1.11E+04
S CFS-L07-1315-T02-B 1 5.23E+04
S CFS-L07-1315-T03-B 1 5.40E+04
S CFS-L07-1315-T04-B 1 1.50E+05
S CFS-L07-1315-T05-B 1 1.79E+05
S CFS-L07-1315-T06-B 1 2.70E+05
S CFS-L07-1315-T07-B 1 2.38E+05
S CFS-L07-1315-T08-B 1 1.27E+05
S CFS-L07-1315-T09-B 1 2.02E+05
S CFS-L07-1315-T01-C 1 1.07E+04
S CFS-L07-1315-T02-C 1 5.18E+04
S CFS-L07-1315-T03-C 1 4.93E+04
S CFS-L07-1315-T04-C 1 1.46E+05
S CFS-L07-1315-T05-C 1 1.78E+05
S CFS-L07-1315-T06-C 1 2.74E+05
S CFS-L07-1315-T07-C 1 2.34E+05
S CFS-L07-1315-T08-C 1 1.24E+05
S CFS-L07-1315-T09-C 1 1.96E+05
S CFS-L07-1315-M01-A 1 9.36E+01
S CFS-L07-1315-M02-A 1 8.44E+01
S CFS-L07-1315-M03-A 1 8.69E+01
S CFS-L07-1315-M04-A 1 6.35E+01
S CFS-L07-1315-M05-A 1 1.22E+02
S CFS-L07-1315-M06-A 1 1.77E+02
S CFS-L07-1315-M07-A 1 1.75E+02
S CFS-L07-1315-M08-A 1 1.37E+02
S CFS-L07-1315-M09-A 1 1.55E+02
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.20E+04 1.23 6.80 21.60
5.18E+04 0.32 6.80 21.60
5.83E+04 1.05 6.80 21.60 10000 1000
1.56E+05 0.42 6.80 21.60
1.80E+05 0.49 6.80 21.60
2.74E+05 1.58 6.80 21.60
2.36E+05 0.83 6.80 21.60
1.27E+05 0.77 6.80 21.60
1.98E+05 0.95 6.80 21.60
1.11E+04 6.00 6.80 21.60
5.23E+04 0.25 6.80 21.60
5.40E+04 1.54 6.80 21.60 10000 1000
1.50E+05 1.88 6.80 21.60
1.79E+05 0.35 6.80 21.60
2.70E+05 0.73 6.80 21.60
2.38E+05 0.74 6.80 21.60
1.27E+05 2.16 6.80 21.60
2.02E+05 2.88 6.80 21.60
1.07E+04 4.38 6.80 21.60
5.18E+04 0.44 6.80 21.60
4.93E+04 1.31 6.80 21.60 10000 1000
1.46E+05 4.43 6.80 21.60
1.78E+05 1.35 6.80 21.60
2.74E+05 1.48 6.80 21.60
2.34E+05 1.82 6.80 21.60
1.24E+05 1.01 6.80 21.60
1.96E+05 2.05 6.80 21.60
9.36E+01 5.24 6.80 21.60
8.44E+01 2.27 6.80 21.60
8.69E+01 11.57 6.80 21.60
6.35E+01 9.55 6.80 21.60
1.22E+02 9.03 6.80 21.60
1.77E+02 8.14 6.80 21.60
1.75E+02 5.04 6.80 21.60
1.37E+02 1.15 6.80 21.60
1.55E+02 4.46 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.92E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.49E+04 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.02E+04 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-869
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Tl CFS-L07-1315-T01-A 1 7.98E+00 E
Tl CFS-L07-1315-T02-A 1 7.03E+01
Tl CFS-L07-1315-T03-A 1 7.80E+01
Tl CFS-L07-1315-T04-A 1 2.17E+02
Tl CFS-L07-1315-T05-A 1 2.48E+02
Tl CFS-L07-1315-T06-A 1 3.55E+02
Tl CFS-L07-1315-T07-A 1 2.89E+02
Tl CFS-L07-1315-T08-A 1 1.61E+02
Tl CFS-L07-1315-T09-A 1 2.19E+02
Tl CFS-L07-1315-T01-B 1 7.50E+00 E
Tl CFS-L07-1315-T02-B 1 6.99E+01
Tl CFS-L07-1315-T03-B 1 7.47E+01
Tl CFS-L07-1315-T04-B 1 2.16E+02
Tl CFS-L07-1315-T05-B 1 2.48E+02
Tl CFS-L07-1315-T06-B 1 3.53E+02
Tl CFS-L07-1315-T07-B 1 2.92E+02
Tl CFS-L07-1315-T08-B 1 1.57E+02
Tl CFS-L07-1315-T09-B 1 2.24E+02
Tl CFS-L07-1315-T01-C 1 5.92E+00 E
Tl CFS-L07-1315-T02-C 1 7.27E+01
Tl CFS-L07-1315-T03-C 1 6.76E+01
Tl CFS-L07-1315-T04-C 1 2.09E+02
Tl CFS-L07-1315-T05-C 1 2.45E+02
Tl CFS-L07-1315-T06-C 1 3.42E+02
Tl CFS-L07-1315-T07-C 1 2.87E+02
Tl CFS-L07-1315-T08-C 1 1.63E+02
Tl CFS-L07-1315-T09-C 1 2.28E+02
Tl CFS-L07-1315-M01-A 1 2.30E+00 U1/2
Tl CFS-L07-1315-M02-A 1 2.30E+00 U1/2
Tl CFS-L07-1315-M03-A 1 2.30E+00 U1/2
Tl CFS-L07-1315-M04-A 1 2.30E+00 U1/2
Tl CFS-L07-1315-M05-A 1 2.30E+00 U1/2
Tl CFS-L07-1315-M06-A 1 2.30E+00 U1/2
Tl CFS-L07-1315-M07-A 1 2.30E+00 U1/2
Tl CFS-L07-1315-M08-A 1 2.30E+00 U1/2
Tl CFS-L07-1315-M09-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.98E+00 13.64 4.60 14.60
7.03E+01 0.78 4.60 14.60
7.80E+01 5.34 4.60 14.60 10000 1000
2.17E+02 0.49 4.60 14.60
2.48E+02 1.69 4.60 14.60
3.55E+02 2.17 4.60 14.60
2.89E+02 1.97 4.60 14.60
1.61E+02 0.58 4.60 14.60
2.19E+02 3.22 4.60 14.60
7.50E+00 27.51 4.60 14.60
6.99E+01 2.91 4.60 14.60
7.47E+01 6.01 4.60 14.60 10000 1000
2.16E+02 0.80 4.60 14.60
2.48E+02 0.88 4.60 14.60
3.53E+02 2.00 4.60 14.60
2.92E+02 1.78 4.60 14.60
1.57E+02 3.83 4.60 14.60
2.24E+02 4.40 4.60 14.60
5.92E+00 6.88 4.60 14.60
7.27E+01 3.26 4.60 14.60
6.76E+01 8.81 4.60 14.60 10000 1000
2.09E+02 3.25 4.60 14.60
2.45E+02 4.49 4.60 14.60
3.42E+02 0.90 4.60 14.60
2.87E+02 2.31 4.60 14.60
1.63E+02 2.73 4.60 14.60
2.28E+02 1.76 4.60 14.60
2.30E+00 16.56 4.60 14.60
2.30E+00 7.52 4.60 14.60
2.30E+00 28.90 4.60 14.60
2.30E+00 18.96 4.60 14.60
2.30E+00 34.62 4.60 14.60
2.30E+00 35.96 4.60 14.60
2.30E+00 38.15 4.60 14.60
2.30E+00 4.60 4.60 14.60
2.30E+00 9.62 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.52E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.91E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.83E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-870
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ti CFS-L07-1315-T01-A 1 1.00E+00 U1/2
Ti CFS-L07-1315-T02-A 1 1.00E+00 U1/2
Ti CFS-L07-1315-T03-A 1 1.00E+00 U1/2
Ti CFS-L07-1315-T04-A 1 1.00E+00 U1/2
Ti CFS-L07-1315-T05-A 1 1.00E+00 U1/2
Ti CFS-L07-1315-T06-A 1 1.00E+00 U1/2
Ti CFS-L07-1315-T07-A 1 1.00E+00 U1/2
Ti CFS-L07-1315-T08-A 1 1.00E+00 U1/2
Ti CFS-L07-1315-T09-A 1 1.00E+00 U1/2
Ti CFS-L07-1315-T01-B 1 1.00E+00 U1/2
Ti CFS-L07-1315-T02-B 1 1.00E+00 U1/2
Ti CFS-L07-1315-T03-B 1 1.00E+00 U1/2
Ti CFS-L07-1315-T04-B 1 1.00E+00 U1/2
Ti CFS-L07-1315-T05-B 1 1.00E+00 U1/2
Ti CFS-L07-1315-T06-B 1 1.00E+00 U1/2
Ti CFS-L07-1315-T07-B 1 1.00E+00 U1/2
Ti CFS-L07-1315-T08-B 1 1.00E+00 U1/2
Ti CFS-L07-1315-T09-B 1 1.00E+00 U1/2
Ti CFS-L07-1315-T01-C 1 1.00E+00 U1/2
Ti CFS-L07-1315-T02-C 1 1.00E+00 U1/2
Ti CFS-L07-1315-T03-C 1 1.00E+00 U1/2
Ti CFS-L07-1315-T04-C 1 1.00E+00 U1/2
Ti CFS-L07-1315-T05-C 1 1.00E+00 U1/2
Ti CFS-L07-1315-T06-C 1 1.00E+00 U1/2
Ti CFS-L07-1315-T07-C 1 1.00E+00 U1/2
Ti CFS-L07-1315-T08-C 1 1.00E+00 U1/2
Ti CFS-L07-1315-T09-C 1 1.00E+00 U1/2
Ti CFS-L07-1315-M01-A 1 1.00E+00 U1/2
Ti CFS-L07-1315-M02-A 1 1.00E+00 U1/2
Ti CFS-L07-1315-M03-A 1 1.00E+00 U1/2
Ti CFS-L07-1315-M04-A 1 1.00E+00 U1/2
Ti CFS-L07-1315-M05-A 1 1.00E+00 U1/2
Ti CFS-L07-1315-M06-A 1 1.00E+00 U1/2
Ti CFS-L07-1315-M07-A 1 1.00E+00 U1/2
Ti CFS-L07-1315-M08-A 1 1.00E+00 U1/2
Ti CFS-L07-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 2.75 2.00 6.40
1.00E+00 38.19 2.00 6.40
1.00E+00 42.98 2.00 6.40 10000 1000
1.00E+00 18.98 2.00 6.40
1.00E+00 10.46 2.00 6.40
1.00E+00 58.34 2.00 6.40
1.00E+00 30.34 2.00 6.40
1.00E+00 58.75 2.00 6.40
1.00E+00 74.09 2.00 6.40
1.00E+00 7.09 2.00 6.40
1.00E+00 29.79 2.00 6.40
1.00E+00 10.92 2.00 6.40 10000 1000
1.00E+00 41.13 2.00 6.40
1.00E+00 44.91 2.00 6.40
1.00E+00 48.65 2.00 6.40
1.00E+00 63.34 2.00 6.40
1.00E+00 16.49 2.00 6.40
1.00E+00 35.52 2.00 6.40
1.00E+00 17.99 2.00 6.40
1.00E+00 37.93 2.00 6.40
1.00E+00 15.57 2.00 6.40 10000 1000
1.00E+00 11.46 2.00 6.40
1.00E+00 56.90 2.00 6.40
1.00E+00 27.50 2.00 6.40
1.00E+00 28.44 2.00 6.40
1.00E+00 47.45 2.00 6.40
1.00E+00 40.98 2.00 6.40
1.00E+00 22.67 2.00 6.40
1.00E+00 24.25 2.00 6.40
1.00E+00 25.26 2.00 6.40
1.00E+00 18.60 2.00 6.40
1.00E+00 33.82 2.00 6.40
1.00E+00 40.44 2.00 6.40
1.00E+00 16.51 2.00 6.40
1.00E+00 28.37 2.00 6.40
1.00E+00 63.80 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.18E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.46E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.29E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-871
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
V CFS-L07-1315-T01-A 1 1.97E+00 E
V CFS-L07-1315-T02-A 1 2.82E+00 E
V CFS-L07-1315-T03-A 1 2.71E+00 E
V CFS-L07-1315-T04-A 1 5.71E+00
V CFS-L07-1315-T05-A 1 6.87E+00
V CFS-L07-1315-T06-A 1 8.85E+00
V CFS-L07-1315-T07-A 1 9.62E+00
V CFS-L07-1315-T08-A 1 4.72E+00 E
V CFS-L07-1315-T09-A 1 7.94E+00
V CFS-L07-1315-T01-B 1 2.14E+00 E
V CFS-L07-1315-T02-B 1 3.03E+00 E
V CFS-L07-1315-T03-B 1 3.14E+00 E
V CFS-L07-1315-T04-B 1 5.35E+00
V CFS-L07-1315-T05-B 1 5.77E+00
V CFS-L07-1315-T06-B 1 8.68E+00
V CFS-L07-1315-T07-B 1 9.12E+00
V CFS-L07-1315-T08-B 1 4.07E+00 E
V CFS-L07-1315-T09-B 1 8.14E+00
V CFS-L07-1315-T01-C 1 1.57E+00 E
V CFS-L07-1315-T02-C 1 2.74E+00 E
V CFS-L07-1315-T03-C 1 1.96E+00 E
V CFS-L07-1315-T04-C 1 5.25E+00
V CFS-L07-1315-T05-C 1 6.58E+00
V CFS-L07-1315-T06-C 1 9.37E+00
V CFS-L07-1315-T07-C 1 9.15E+00
V CFS-L07-1315-T08-C 1 5.77E+00
V CFS-L07-1315-T09-C 1 7.77E+00
V CFS-L07-1315-M01-A 1 7.50E-01 U1/2
V CFS-L07-1315-M02-A 1 7.50E-01 U1/2
V CFS-L07-1315-M03-A 1 7.50E-01 U1/2
V CFS-L07-1315-M04-A 1 7.50E-01 U1/2
V CFS-L07-1315-M05-A 1 7.50E-01 U1/2
V CFS-L07-1315-M06-A 1 7.50E-01 U1/2
V CFS-L07-1315-M07-A 1 7.50E-01 U1/2
V CFS-L07-1315-M08-A 1 7.50E-01 U1/2
V CFS-L07-1315-M09-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.97E+00 37.09 1.50 4.77
2.82E+00 9.31 1.50 4.77
2.71E+00 11.71 1.50 4.77 10000 1000
5.71 E+00 2.49 1.50 4.77
6.87E+00 7.93 1.50 4.77
8.85E+00 5.16 1.50 4.77
9.62E+00 3.84 1.50 4.77
4.72E+00 1.95 1.50 4.77
7.94E+00 8.94 1.50 4.77
2.14E+00 15.84 1.50 4.77
3.03E+00 16.54 1.50 4.77
3.14E+00 17.80 1.50 4.77 10000 1000
5.35E+00 6.23 1.50 4.77
5.77E+00 2.28 1.50 4.77
8.68E+00 5.67 1.50 4.77
9.12E+00 2.67 1.50 4.77
4.07E+00 20.74 1.50 4.77
8.14E+00 7.34 1.50 4.77
1.57E+00 35.01 1.50 4.77
2.74E+00 26.59 1.50 4.77
1.96E+00 22.14 1.50 4.77 10000 1000
5.25E+00 18.09 1.50 4.77
6.58E+00 4.12 1.50 4.77
9.37E+00 6.17 1.50 4.77
9.15E+00 3.94 1.50 4.77
5.77E+00 2.11 1.50 4.77
7.77E+00 7.35 1.50 4.77
7.50E-01 38.72 1.50 4.77
7.50E-01 1.99 1.50 4.77
7.50E-01 6.45 1.50 4.77
7.50E-01 33.00 1.50 4.77
7.50E-01 23.98 1.50 4.77
7.50E-01 20.35 1.50 4.77
7.50E-01 19.92 1.50 4.77
7.50E-01 6.55 1.50 4.77
7.50E-01 16.59 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.67E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.43E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.33E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-872
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Zn CFS-L07-1315-T01-A 1 2.37E+02
Zn CFS-L07-1315-T02-A 1 2.23E+03
Zn CFS-L07-1315-T03-A 1 2.25E+03
Zn CFS-L07-1315-T04-A 1 6.08E+03
Zn CFS-L07-1315-T05-A 1 7.07E+03
Zn CFS-L07-1315-T06-A 1 1.05E+04
Zn CFS-L07-1315-T07-A 1 9.17E+03
Zn CFS-L07-1315-T08-A 1 5.45E+03
Zn CFS-L07-1315-T09-A 1 8.02E+03
Zn CFS-L07-1315-T01-B 1 2.80E+02
Zn CFS-L07-1315-T02-B 1 2.08E+03
Zn CFS-L07-1315-T03-B 1 2.12E+03
Zn CFS-L07-1315-T04-B 1 5.73E+03
Zn CFS-L07-1315-T05-B 1 7.08E+03
Zn CFS-L07-1315-T06-B 1 1.04E+04
Zn CFS-L07-1315-T07-B 1 9.19E+03
Zn CFS-L07-1315-T08-B 1 5.21E+03
Zn CFS-L07-1315-T09-B 1 7.93E+03
Zn CFS-L07-1315-T01-C 1 3.77E+02
Zn CFS-L07-1315-T02-C 1 2.02E+03
Zn CFS-L07-1315-T03-C 1 1.96E+03
Zn CFS-L07-1315-T04-C 1 5.63E+03
Zn CFS-L07-1315-T05-C 1 6.86E+03
Zn CFS-L07-1315-T06-C 1 9.94E+03
Zn CFS-L07-1315-T07-C 1 8.47E+03
Zn CFS-L07-1315-T08-C 1 4.82E+03
Zn CFS-L07-1315-T09-C 1 7.33E+03
Zn CFS-L07-1315-M01-A 1 5.00E-01 U1/2
Zn CFS-L07-1315-M02-A 1 5.00E-01 U1/2
Zn CFS-L07-1315-M03-A 1 5.00E-01 U1/2
Zn CFS-L07-1315-M04-A 1 5.00E-01 U1/2
Zn CFS-L07-1315-M05-A 1 5.00E-01 U1/2
Zn CFS-L07-1315-M06-A 1 5.00E-01 U1/2
Zn CFS-L07-1315-M07-A 1 5.00E-01 U1/2
Zn CFS-L07-1315-M08-A 1 5.00E-01 U1/2
Zn CFS-L07-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.37E+02 0.31 1.00 3.18
2.23E+03 0.31 1.00 3.18
2.25E+03 0.55 1.00 3.18 10000 1000
6.08E+03 0.84 1.00 3.18
7.07E+03 0.58 1.00 3.18
1.05E+04 0.62 1.00 3.18
9.17E+03 0.54 1.00 3.18
5.45E+03 1.39 1.00 3.18
8.02E+03 1.02 1.00 3.18
2.80E+02 7.11 1.00 3.18
2.08E+03 1.35 1.00 3.18
2.12E+03 0.50 1.00 3.18 10000 1000
5.73E+03 1.57 1.00 3.18
7.08E+03 0.52 1.00 3.18
1.04E+04 1.17 1.00 3.18
9.19E+03 1.39 1.00 3.18
5.21E+03 2.11 1.00 3.18
7.93E+03 2.14 1.00 3.18
3.77E+02 4.30 1.00 3.18
2.02E+03 1.16 1.00 3.18
1.96E+03 0.86 1.00 3.18 10000 1000
5.63E+03 2.15 1.00 3.18
6.86E+03 2.27 1.00 3.18
9.94E+03 0.76 1.00 3.18
8.47E+03 1.88 1.00 3.18
4.82E+03 1.00 1.00 3.18
7.33E+03 1.52 1.00 3.18
5.00E-01 14.66 1.00 3.18
5.00E-01 0.84 1.00 3.18
5.00E-01 3.65 1.00 3.18
5.00E-01 1.24 1.00 3.18
5.00E-01 1.93 1.00 3.18
5.00E-01 5.39 1.00 3.18
5.00E-01 8.52 1.00 3.18
5.00E-01 1.37 1.00 3.18
5.00E-01 4.93 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
3.19E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.07E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.96E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/12/11 4:45 PM EPA Interlab L07 1315 CFS
9/12/11 4:47 PM EPA Interlab L07 1315 CFS
9/12/11 4:49 PM EPA Interlab L07 1315 CFS
9/12/11 4:50 PM EPA Interlab L07 1315 CFS
9/12/11 4:52 PM EPA Interlab L07 1315 CFS
9/12/11 4:54 PM EPA Interlab L07 1315 CFS
9/12/11 4:55 PM EPA Interlab L07 1315 CFS
9/12/11 4:57 PM EPA Interlab L07 1315 CFS
9/12/11 4:59 PM EPA Interlab L07 1315 CFS
9/12/11 5:05 PM EPA Interlab L07 1315 CFS
9/12/11 5:07 PM EPA Interlab L07 1315 CFS
9/12/11 5:08 PM EPA Interlab L07 1315 CFS
9/12/11 5:10 PM EPA Interlab L07 1315 CFS
9/12/11 5:12 PM EPA Interlab L07 1315 CFS
9/12/11 5:13 PM EPA Interlab L07 1315 CFS
9/12/11 5:15 PM EPA Interlab L07 1315 CFS
9/12/11 5:17 PM EPA Interlab L07 1315 CFS
9/12/11 5:18 PM EPA Interlab L07 1315 CFS
9/12/11 5:20 PM EPA Interlab L07 1315 CFS
9/12/11 5:22 PM EPA Interlab L07 1315 CFS
9/12/11 5:23 PM EPA Interlab L07 1315 CFS
9/12/11 5:25 PM EPA Interlab L07 1315 CFS
9/12/11 5:27 PM EPA Interlab L07 1315 CFS
9/12/11 5:28 PM EPA Interlab L07 1315 CFS
9/12/11 5:30 PM EPA Interlab L07 1315 CFS
9/12/11 5:32 PM EPA Interlab L07 1315 CFS
9/12/11 5:33 PM EPA Interlab L07 1315 CFS
9/12/11 4:30 PM EPA Interlab L07 1315 CFS
9/12/11 4:32 PM EPA Interlab L07 1315 CFS
9/12/11 4:34 PM EPA Interlab L07 1315 CFS
9/12/11 4:35 PM EPA Interlab L07 1315 CFS
9/12/11 4:37 PM EPA Interlab L07 1315 CFS
9/12/11 4:39 PM EPA Interlab L07 1315 CFS
9/12/11 4:40 PM EPA Interlab L07 1315 CFS
9/12/11 4:42 PM EPA Interlab L07 1315 CFS
9/12/11 4:44 PM EPA Interlab L07 1315 CFS
1-873
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1315:
Element Sample ID
Al CFS-L10-1315-T01-A
Al CFS-L10-1315-T02-A
Al CFS-L10-1315-T03-A
Al CFS-L10-1315-T04-A
Al CFS-L10-1315-T05-A
Al CFS-L10-1315-T06-A
Al CFS-L10-1315-T07-A
Al CFS-L10-1315-T08-A
Al CFS-L10-1315-T09-A
Al CFS-L10-1315-T01-B
Al CFS-L10-1315-T02-B
Al CFS-L10-1315-T03-B
Al CFS-L10-1315-T04-B
Al CFS-L10-1315-T05-B
Al CFS-L10-1315-T06-B
Al CFS-L10-1315-T07-B
Al CFS-L10-1315-T08-B
Al CFS-L10-1315-T09-B
Al CFS-L10-1315-T01-C
Al CFS-L10-1315-T02-C
Al CFS-L10-1315-T03-C
Al CFS-L10-1315-T04-C
Al CFS-L10-1315-T05-C
Al CFS-L10-1315-T06-C
Al CFS-L10-1315-T07-C
Al CFS-L10-1315-T08-C
Al CFS-L10-1315-T09-C
Al CFS-L10-1315-M01-A
Al CFS-L10-1315-M02-A
Al CFS-L10-1315-M03-A
Al CFS-L10-1315-M04-A
Al CFS-L10-1315-M05-A
Al CFS-L10-1315-M06-A
Al CFS-L10-1315-M07-A
Al CFS-L10-1315-M08-A
Al CFS-L10-1315-M09-A
Dilution Sample
Factor Cone. Qualifier
I ug/L I
1 1.03E+01
1 2.24E+01
1 2.18E+01
1 3.72E+01
1 4.12E+01
1 4.32E+01
1 4.15E+01
1 3.68E+01
1 4.93E+01
1 7.61E+00
1 2.24E+01
1 1.91E+01
1 3.47E+01
1 3.96E+01
1 4.82E+01
1 4.17E+01
1 3.79E+01
1 3.56E+01
1 8.70E+00
1 2.40E+01
1 1.89E+01
1 3.67E+01
1 3.95E+01
1 4.47E+01
1 5.49E+01
1 3.67E+01
1 3.45E+01
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 1.39E+OOE
1 1.30E+OOE
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.03E+01 2.07 1.00 3.18
2.24E+01 14.84 1.00 3.18
2.18E+01 6.38 1.00 3.18 10000 1000
3.72E+01 3.12 1.00 3.18
4.12E+01 4.14 1.00 3.18
4.32E+01 3.12 1.00 3.18
4.15E+01 7.53 1.00 3.18
3.68E+01 1.52 1.00 3.18
4.93E+01 5.97 1.00 3.18
7.61E+00 9.46 1.00 3.18
2.24E+01 9.00 1.00 3.18
1.91E+01 11.08 1.00 3.18 10000 1000
3.47E+01 5.63 1.00 3.18
3.96E+01 4.61 1.00 3.18
4.82E+01 2.04 1.00 3.18
4.17E+01 2.07 1.00 3.18
3.79E+01 5.38 1.00 3.18
3.56E+01 7.79 1.00 3.18
8.70E+00 1.39 1.00 3.18
2.40E+01 0.23 1.00 3.18
1.89E+01 5.77 1.00 3.18 10000 1000
3.67E+01 6.97 1.00 3.18
3.95E+01 9.65 1.00 3.18
4.47E+01 3.20 1.00 3.18
5.49E+01 2.92 1.00 3.18
3.67E+01 5.86 1.00 3.18
3.45E+01 5.27 1.00 3.18
5.00E-01 7.41 1.00 3.18
5.00E-01 7.33 1.00 3.18
5.00E-01 16.92 1.00 3.18
5.00E-01 21.82 1.00 3.18
5.00E-01 4.77 1.00 3.18
5.00E-01 10.53 1.00 3.18
1.39E+00 4.23 1.00 3.18
1.30E+00 5.16 1.00 3.18
5.00E-01 15.04 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.08E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.68E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.10E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-874
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L
Sb CFS-L10-1315-T01-A 1 1.10E+01 E
Sb CFS-L10-1315-T02-A 1 9.33E+00 E
Sb CFS-L10-1315-T03-A 1 1.04E+01 E
Sb CFS-L10-1315-T04-A 1 1.20E+01 E
Sb CFS-L10-1315-T05-A 1 1.15E+01 E
Sb CFS-L10-1315-T06-A 1 1.18E+01 E
Sb CFS-L10-1315-T07-A 1 9.85E+00 E
Sb CFS-L10-1315-T08-A 1 1.90E+01 E
Sb CFS-L10-1315-T09-A 1 1.27E+01 E
Sb CFS-L10-1315-T01-B 1 9.68E+00 E
Sb CFS-L10-1315-T02-B 1 8.50E+00 E
Sb CFS-L10-1315-T03-B 1 9.34E+00 E
Sb CFS-L10-1315-T04-B 1 8.99E+00 E
Sb CFS-L10-1315-T05-B 1 1.29E+01 E
Sb CFS-L10-1315-T06-B 1 1.25E+01 E
Sb CFS-L10-1315-T07-B 1 1.11E+01 E
Sb CFS-L10-1315-T08-B 1 1.52E+01 E
Sb CFS-L10-1315-T09-B 1 9.63E+00 E
Sb CFS-L10-1315-T01-C 1 1.16E+01 E
Sb CFS-L10-1315-T02-C 1 8.12E+00 E
Sb CFS-L10-1315-T03-C 1 9.53E+00 E
Sb CFS-L10-1315-T04-C 1 8.62E+00 E
Sb CFS-L10-1315-T05-C 1 1.25E+01 E
Sb CFS-L10-1315-T06-C 1 1.50E+01 E
Sb CFS-L10-1315-T07-C 1 1.32E+01 E
Sb CFS-L10-1315-T08-C 1 1.44E+01 E
Sb CFS-L10-1315-T09-C 1 1.31E+01 E
Sb CFS-L10-1315-M01-A 1 3.75E+00 U1/2
Sb CFS-L10-1315-M02-A 1 3.75E+00 U1/2
Sb CFS-L10-1315-M03-A 1 3.75E+00 U1/2
Sb CFS-L10-1315-M04-A 1 3.75E+00 U1/2
Sb CFS-L10-1315-M05-A 1 3.75E+00 U1/2
Sb CFS-L10-1315-M06-A 1 3.75E+00 U1/2
Sb CFS-L10-1315-M07-A 1 3.75E+00 U1/2
Sb CFS-L10-1315-M08-A 1 3.75E+00 U1/2
Sb CFS-L10-1315-M09-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.10E+01 30.05 7.50 23.90
9.33E+00 23.18 7.50 23.90
1.04E+01 14.14 7.50 23.90 10000 1000
1.20E+01 6.13 7.50 23.90
1.15E+01 1.48 7.50 23.90
1.18E+01 4.73 7.50 23.90
9.85E+00 12.05 7.50 23.90
1.90E+01 15.97 7.50 23.90
1.27E+01 17.74 7.50 23.90
9.68E+00 7.60 7.50 23.90
8.50E+00 28.47 7.50 23.90
9.34E+00 12.83 7.50 23.90 10000 1000
8.99E+00 16.62 7.50 23.90
1.29E+01 14.87 7.50 23.90
1.25E+01 9.25 7.50 23.90
1.11E+01 7.74 7.50 23.90
1.52E+01 3.74 7.50 23.90
9.63E+00 12.66 7.50 23.90
1.16E+01 9.42 7.50 23.90
8.12E+00 21.24 7.50 23.90
9.53E+00 19.21 7.50 23.90 10000 1000
8.62E+00 20.76 7.50 23.90
1.25E+01 8.20 7.50 23.90
1.50E+01 4.54 7.50 23.90
1.32E+01 5.71 7.50 23.90
1.44E+01 17.17 7.50 23.90
1.31E+01 12.57 7.50 23.90
3.75E+00 22.50 7.50 23.90
3.75E+00 36.32 7.50 23.90
3.75E+00 35.48 7.50 23.90
3.75E+00 35.33 7.50 23.90
3.75E+00 13.19 7.50 23.90
3.75E+00 5.53 7.50 23.90
3.75E+00 8.43 7.50 23.90
3.75E+00 12.37 7.50 23.90
3.75E+00 26.39 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.76E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.49E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.92E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-875
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
As CFS-L10-1315-T01-A 1 5.50E+00 U1/2
As CFS-L10-1315-T02-A 1 5.50E+00 U1/2
As CFS-L10-1315-T03-A 1 1.14E+01 E
As CFS-L10-1315-T04-A 1 1.40E+01 E
As CFS-L10-1315-T05-A 1 1.78E+01 E
As CFS-L10-1315-T06-A 1 1.27E+01 E
As CFS-L10-1315-T07-A 1 1.14E+01 E
As CFS-L10-1315-T08-A 1 5.50E+00 U1/2
As CFS-L10-1315-T09-A 1 5.50E+00 U1/2
As CFS-L10-1315-T01-B 1 5.50E+00 U1/2
As CFS-L10-1315-T02-B 1 5.50E+00 U1/2
As CFS-L10-1315-T03-B 1 1.36E+01 E
As CFS-L10-1315-T04-B 1 1.18E+01 E
As CFS-L10-1315-T05-B 1 2.15E+01 E
As CFS-L10-1315-T06-B 1 1.34E+01 E
As CFS-L10-1315-T07-B 1 1.14E+01 E
As CFS-L10-1315-T08-B 1 5.50E+00 U1/2
As CFS-L10-1315-T09-B 1 5.50E+00 U1/2
As CFS-L10-1315-T01-C 1 5.50E+00 U1/2
As CFS-L10-1315-T02-C 1 5.50E+00 U1/2
As CFS-L10-1315-T03-C 1 1.46E+01 E
As CFS-L10-1315-T04-C 1 1.85E+01 E
As CFS-L10-1315-T05-C 1 1.94E+01 E
As CFS-L10-1315-T06-C 1 1.51E+01 E
As CFS-L10-1315-T07-C 1 1.15E+01 E
As CFS-L10-1315-T08-C 1 5.50E+00 U1/2
As CFS-L10-1315-T09-C 1 5.50E+00 U1/2
As CFS-L10-1315-M01-A 1 5.50E+00 U1/2
As CFS-L10-1315-M02-A 1 5.50E+00 U1/2
As CFS-L10-1315-M03-A 1 5.50E+00 U1/2
As CFS-L10-1315-M04-A 1 5.50E+00 U1/2
As CFS-L10-1315-M05-A 1 5.50E+00 U1/2
As CFS-L10-1315-M06-A 1 5.50E+00 U1/2
As CFS-L10-1315-M07-A 1 5.50E+00 U1/2
As CFS-L10-1315-M08-A 1 5.50E+00 U1/2
As CFS-L10-1315-M09-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.50E+00 45.24 11.00 35.00
5.50E+00 50.48 11.00 35.00
1.14E+01 13.65 11.00 35.00 10000 1000
1.40E+01 3.38 11.00 35.00
1.78E+01 22.46 11.00 35.00
1.27E+01 11.74 11.00 35.00
1.14E+01 3.87 11.00 35.00
5.50E+00 17.78 11.00 35.00
5.50E+00 8.72 11.00 35.00
5.50E+00 3.17 11.00 35.00
5.50E+00 39.72 11.00 35.00
1.36E+01 10.69 11.00 35.00 10000 1000
1.18E+01 2.59 11.00 35.00
2.15E+01 8.30 11.00 35.00
1.34E+01 15.13 11.00 35.00
1.14E+01 9.96 11.00 35.00
5.50E+00 23.31 11.00 35.00
5.50E+00 42.87 11.00 35.00
5.50E+00 35.02 11.00 35.00
5.50E+00 34.69 11.00 35.00
1.46E+01 10.12 11.00 35.00 10000 1000
1.85E+01 12.82 11.00 35.00
1.94E+01 6.17 11.00 35.00
1.51E+01 25.57 11.00 35.00
1.15E+01 7.60 11.00 35.00
5.50E+00 11.26 11.00 35.00
5.50E+00 37.06 11.00 35.00
5.50E+00 22.71 11.00 35.00
5.50E+00 25.32 11.00 35.00
5.50E+00 38.81 11.00 35.00
5.50E+00 38.15 11.00 35.00
5.50E+00 20.17 11.00 35.00
5.50E+00 67.08 11.00 35.00
5.50E+00 38.79 11.00 35.00
5.50E+00 27.88 11.00 35.00
5.50E+00 13.01 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.96E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.69E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.27E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-876
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
B CFS-L10-1315-T01-A 1 7.72E+00
B CFS-L10-1315-T02-A 1 2.49E+01
B CFS-L10-1315-T03-A 1 2.48E+01
B CFS-L10-1315-T04-A 1 8.53E+01
B CFS-L10-1315-T05-A 1 1.05E+02
B CFS-L10-1315-T06-A 1 1.76E+02
B CFS-L10-1315-T07-A 1 1.19E+02
B CFS-L10-1315-T08-A 1 9.84E+01
B CFS-L10-1315-T09-A 1 8.26E+01
B CFS-L10-1315-T01-B 1 1.94E+01
B CFS-L10-1315-T02-B 1 3.47E+01
B CFS-L10-1315-T03-B 1 2.89E+01
B CFS-L10-1315-T04-B 1 9.56E+01
B CFS-L10-1315-T05-B 1 1.13E+02
B CFS-L10-1315-T06-B 1 1.83E+02
B CFS-L10-1315-T07-B 1 1.28E+02
B CFS-L10-1315-T08-B 1 1.04E+02
B CFS-L10-1315-T09-B 1 9.01E+01
B CFS-L10-1315-T01-C 1 8.37E+00
B CFS-L10-1315-T02-C 1 2.97E+01
B CFS-L10-1315-T03-C 1 2.85E+01
B CFS-L10-1315-T04-C 1 9.35E+01
B CFS-L10-1315-T05-C 1 1.17E+02
B CFS-L10-1315-T06-C 1 1.92E+02
B CFS-L10-1315-T07-C 1 1.38E+02
B CFS-L10-1315-T08-C 1 1.10E+02
B CFS-L10-1315-T09-C 1 9.14E+01
B CFS-L10-1315-M01-A 1 5.00E-01 U1/2
B CFS-L10-1315-M02-A 1 5.00E-01 U1/2
B CFS-L10-1315-M03-A 1 5.00E-01 U1/2
B CFS-L10-1315-M04-A 1 5.00E-01 U1/2
B CFS-L10-1315-M05-A 1 5.00E-01 U1/2
B CFS-L10-1315-M06-A 1 5.00E-01 U1/2
B CFS-L10-1315-M07-A 1 5.00E-01 U1/2
B CFS-L10-1315-M08-A 1 5.00E-01 U1/2
B CFS-L10-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.72E+00 3.14 1.00 3.18
2.49E+01 4.07 1.00 3.18
2.48E+01 4.61 1.00 3.18 10000 1000
8.53E+01 4.84 1.00 3.18
1.05E+02 1.66 1.00 3.18
1.76E+02 1.34 1.00 3.18
1.19E+02 2.17 1.00 3.18
9.84E+01 0.92 1.00 3.18
8.26E+01 1.12 1.00 3.18
1.94E+01 4.67 1.00 3.18
3.47E+01 5.24 1.00 3.18
2.89E+01 4.71 1.00 3.18 10000 1000
9.56E+01 2.63 1.00 3.18
1.13E+02 2.70 1.00 3.18
1.83E+02 0.61 1.00 3.18
1.28E+02 1.87 1.00 3.18
1.04E+02 1.78 1.00 3.18
9.01E+01 2.49 1.00 3.18
8.37E+00 8.22 1.00 3.18
2.97E+01 0.80 1.00 3.18
2.85E+01 4.49 1.00 3.18 10000 1000
9.35E+01 4.92 1.00 3.18
1.17E+02 0.83 1.00 3.18
1.92E+02 2.19 1.00 3.18
1.38E+02 2.16 1.00 3.18
1.10E+02 1.08 1.00 3.18
9.14E+01 0.11 1.00 3.18
5.00E-01 11.99 1.00 3.18
5.00E-01 9.06 1.00 3.18
5.00E-01 13.20 1.00 3.18
5.00E-01 9.02 1.00 3.18
5.00E-01 4.44 1.00 3.18
5.00E-01 7.24 1.00 3.18
5.00E-01 9.36 1.00 3.18
5.00E-01 1.74 1.00 3.18
5.00E-01 14.36 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.78E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.96E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-877
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Ba CFS-L10-1315-T01-A 1 2.64E+01
Ba CFS-L10-1315-T02-A 1 2.39E+01
Ba CFS-L10-1315-T03-A 1 2.59E+01
Ba CFS-L10-1315-T04-A 1 2.91E+01
Ba CFS-L10-1315-T05-A 1 3.35E+01
Ba CFS-L10-1315-T06-A 1 3.51E+01
Ba CFS-L10-1315-T07-A 1 3.31E+01
Ba CFS-L10-1315-T08-A 1 2.74E+01
Ba CFS-L10-1315-T09-A 1 2.91E+01
Ba CFS-L10-1315-T01-B 1 2.37E+01
Ba CFS-L10-1315-T02-B 1 2.21E+01
Ba CFS-L10-1315-T03-B 1 2.56E+01
Ba CFS-L10-1315-T04-B 1 3.18E+01
Ba CFS-L10-1315-T05-B 1 3.35E+01
Ba CFS-L10-1315-T06-B 1 3.66E+01
Ba CFS-L10-1315-T07-B 1 3.27E+01
Ba CFS-L10-1315-T08-B 1 2.81E+01
Ba CFS-L10-1315-T09-B 1 3.09E+01
Ba CFS-L10-1315-T01-C 1 2.43E+01
Ba CFS-L10-1315-T02-C 1 2.13E+01
Ba CFS-L10-1315-T03-C 1 2.68E+01
Ba CFS-L10-1315-T04-C 1 2.98E+01
Ba CFS-L10-1315-T05-C 1 3.03E+01
Ba CFS-L10-1315-T06-C 1 3.63E+01
Ba CFS-L10-1315-T07-C 1 3.31E+01
Ba CFS-L10-1315-T08-C 1 2.66E+01
Ba CFS-L10-1315-T09-C 1 3.19E+01
Ba CFS-L10-1315-M01-A 1 5.00E-01 U1/2
Ba CFS-L10-1315-M02-A 1 5.00E-01 U1/2
Ba CFS-L10-1315-M03-A 1 5.00E-01 U1/2
Ba CFS-L10-1315-M04-A 1 5.00E-01 U1/2
Ba CFS-L10-1315-M05-A 1 5.00E-01 U1/2
Ba CFS-L10-1315-M06-A 1 5.00E-01 U1/2
Ba CFS-L10-1315-M07-A 1 5.00E-01 U1/2
Ba CFS-L10-1315-M08-A 1 5.00E-01 U1/2
Ba CFS-L10-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.64E+01 1.58 1.00 3.18
2.39E+01 0.71 1.00 3.18
2.59E+01 2.93 1.00 3.18 10000 1000
2.91E+01 3.50 1.00 3.18
3.35E+01 0.52 1.00 3.18
3.51E+01 1.70 1.00 3.18
3.31E+01 2.59 1.00 3.18
2.74E+01 0.43 1.00 3.18
2.91E+01 1.76 1.00 3.18
2.37E+01 1.11 1.00 3.18
2.21E+01 5.40 1.00 3.18
2.56E+01 1.50 1.00 3.18 10000 1000
3.18E+01 2.22 1.00 3.18
3.35E+01 1.69 1.00 3.18
3.66E+01 2.17 1.00 3.18
3.27E+01 1.92 1.00 3.18
2.81E+01 2.38 1.00 3.18
3.09E+01 3.09 1.00 3.18
2.43E+01 2.87 1.00 3.18
2.13E+01 3.13 1.00 3.18
2.68E+01 1.64 1.00 3.18 10000 1000
2.98E+01 1.08 1.00 3.18
3.03E+01 0.56 1.00 3.18
3.63E+01 1.58 1.00 3.18
3.31E+01 2.21 1.00 3.18
2.66E+01 1.14 1.00 3.18
3.19E+01 1.19 1.00 3.18
5.00E-01 21.56 1.00 3.18
5.00E-01 37.80 1.00 3.18
5.00E-01 33.52 1.00 3.18
5.00E-01 11.12 1.00 3.18
5.00E-01 6.54 1.00 3.18
5.00E-01 13.91 1.00 3.18
5.00E-01 22.58 1.00 3.18
5.00E-01 2.51 1.00 3.18
5.00E-01 4.32 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.93E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.34E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.86E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-878
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Be CFS-L10-1315-T01-A 1 9.50E-01 U1/2
Be CFS-L10-1315-T02-A 1 9.50E-01 U1/2
Be CFS-L10-1315-T03-A 1 9.50E-01 U1/2
Be CFS-L10-1315-T04-A 1 9.50E-01 U1/2
Be CFS-L10-1315-T05-A 1 9.50E-01 U1/2
Be CFS-L10-1315-T06-A 1 9.50E-01 U1/2
Be CFS-L10-1315-T07-A 1 9.50E-01 U1/2
Be CFS-L10-1315-T08-A 1 9.50E-01 U1/2
Be CFS-L10-1315-T09-A 1 9.50E-01 U1/2
Be CFS-L10-1315-T01-B 1 9.50E-01 U1/2
Be CFS-L10-1315-T02-B 1 9.50E-01 U1/2
Be CFS-L10-1315-T03-B 1 9.50E-01 U1/2
Be CFS-L10-1315-T04-B 1 9.50E-01 U1/2
Be CFS-L10-1315-T05-B 1 9.50E-01 U1/2
Be CFS-L10-1315-T06-B 1 9.50E-01 U1/2
Be CFS-L10-1315-T07-B 1 9.50E-01 U1/2
Be CFS-L10-1315-T08-B 1 9.50E-01 U1/2
Be CFS-L10-1315-T09-B 1 9.50E-01 U1/2
Be CFS-L10-1315-T01-C 1 9.50E-01 U1/2
Be CFS-L10-1315-T02-C 1 9.50E-01 U1/2
Be CFS-L10-1315-T03-C 1 9.50E-01 U1/2
Be CFS-L10-1315-T04-C 1 9.50E-01 U1/2
Be CFS-L10-1315-T05-C 1 9.50E-01 U1/2
Be CFS-L10-1315-T06-C 1 9.50E-01 U1/2
Be CFS-L10-1315-T07-C 1 9.50E-01 U1/2
Be CFS-L10-1315-T08-C 1 9.50E-01 U1/2
Be CFS-L10-1315-T09-C 1 9.50E-01 U1/2
Be CFS-L10-1315-M01-A 1 9.50E-01 U1/2
Be CFS-L10-1315-M02-A 1 9.50E-01 U1/2
Be CFS-L10-1315-M03-A 1 9.50E-01 U1/2
Be CFS-L10-1315-M04-A 1 9.50E-01 U1/2
Be CFS-L10-1315-M05-A 1 9.50E-01 U1/2
Be CFS-L10-1315-M06-A 1 9.50E-01 U1/2
Be CFS-L10-1315-M07-A 1 9.50E-01 U1/2
Be CFS-L10-1315-M08-A 1 9.50E-01 U1/2
Be CFS-L10-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 37.10 1.90 6.00
9.50E-01 63.13 1.90 6.00
9.50E-01 37.28 1.90 6.00 10000 1000
9.50E-01 45.21 1.90 6.00
9.50E-01 29.16 1.90 6.00
9.50E-01 7.44 1.90 6.00
9.50E-01 12.75 1.90 6.00
9.50E-01 17.15 1.90 6.00
9.50E-01 8.63 1.90 6.00
9.50E-01 32.43 1.90 6.00
9.50E-01 23.10 1.90 6.00
9.50E-01 24.36 1.90 6.00 10000 1000
9.50E-01 47.20 1.90 6.00
9.50E-01 11.23 1.90 6.00
9.50E-01 10.65 1.90 6.00
9.50E-01 65.31 1.90 6.00
9.50E-01 36.65 1.90 6.00
9.50E-01 54.35 1.90 6.00
9.50E-01 25.91 1.90 6.00
9.50E-01 51.78 1.90 6.00
9.50E-01 57.84 1.90 6.00 10000 1000
9.50E-01 69.47 1.90 6.00
9.50E-01 10.08 1.90 6.00
9.50E-01 38.96 1.90 6.00
9.50E-01 36.95 1.90 6.00
9.50E-01 50.01 1.90 6.00
9.50E-01 19.72 1.90 6.00
9.50E-01 48.00 1.90 6.00
9.50E-01 12.53 1.90 6.00
9.50E-01 12.32 1.90 6.00
9.50E-01 55.14 1.90 6.00
9.50E-01 55.03 1.90 6.00
9.50E-01 38.31 1.90 6.00
9.50E-01 31.07 1.90 6.00
9.50E-01 60.53 1.90 6.00
9.50E-01 29.57 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.99E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.44E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.89E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-879
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
Cd CFS-L10-1315-T01-A 1 7.86E+01
Cd CFS-L10-1315-T02-A 1 3.65E+02
Cd CFS-L10-1315-T03-A 1 3.37E+02
Cd CFS-L10-1315-T04-A 1 1.10E+03
Cd CFS-L10-1315-T05-A 1 1.31E+03
Cd CFS-L10-1315-T06-A 1 1.91E+03
Cd CFS-L10-1315-T07-A 1 1.49E+03
Cd CFS-L10-1315-T08-A 1 1.08E+03
Cd CFS-L10-1315-T09-A 1 9.51E+02
Cd CFS-L10-1315-T01-B 1 6.84E+01
Cd CFS-L10-1315-T02-B 1 3.26E+02
Cd CFS-L10-1315-T03-B 1 3.07E+02
Cd CFS-L10-1315-T04-B 1 1.06E+03
Cd CFS-L10-1315-T05-B 1 1.23E+03
Cd CFS-L10-1315-T06-B 1 1.90E+03
Cd CFS-L10-1315-T07-B 1 1.53E+03
Cd CFS-L10-1315-T08-B 1 1.13E+03
Cd CFS-L10-1315-T09-B 1 1.01E+03
Cd CFS-L10-1315-T01-C 1 6.40E+01
Cd CFS-L10-1315-T02-C 1 3.57E+02
Cd CFS-L10-1315-T03-C 1 3.52E+02
Cd CFS-L10-1315-T04-C 1 1.12E+03
Cd CFS-L10-1315-T05-C 1 1.32E+03
Cd CFS-L10-1315-T06-C 1 2.03E+03
Cd CFS-L10-1315-T07-C 1 1.64E+03
Cd CFS-L10-1315-T08-C 1 1.13E+03
Cd CFS-L10-1315-T09-C 1 1.01E+03
Cd CFS-L10-1315-M01-A 1 1.10E+00 U1/2
Cd CFS-L10-1315-M02-A 1 1.10E+00 U1/2
Cd CFS-L10-1315-M03-A 1 1.10E+00 U1/2
Cd CFS-L10-1315-M04-A 1 1.10E+00 U1/2
Cd CFS-L10-1315-M05-A 1 1.10E+00 U1/2
Cd CFS-L10-1315-M06-A 1 1.10E+00 U1/2
Cd CFS-L10-1315-M07-A 1 1.10E+00 U1/2
Cd CFS-L10-1315-M08-A 1 1.10E+00 U1/2
Cd CFS-L10-1315-M09-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.86E+01 0.97 2.20 7.00
3.65E+02 0.78 2.20 7.00
3.37E+02 1.62 2.20 7.00 10000 1000
1.10E+03 1.90 2.20 7.00
1.31E+03 0.87 2.20 7.00
1.91E+03 1.48 2.20 7.00
1.49E+03 1.75 2.20 7.00
1.08E+03 0.66 2.20 7.00
9.51 E+02 0.33 2.20 7.00
6.84E+01 2.34 2.20 7.00
3.26E+02 5.76 2.20 7.00
3.07E+02 0.80 2.20 7.00 10000 1000
1.06E+03 1.91 2.20 7.00
1.23E+03 2.01 2.20 7.00
1.90E+03 1.10 2.20 7.00
1.53E+03 1.07 2.20 7.00
1.13E+03 2.36 2.20 7.00
1.01E+03 2.71 2.20 7.00
6.40E+01 1.81 2.20 7.00
3.57E+02 1.79 2.20 7.00
3.52E+02 0.24 2.20 7.00 10000 1000
1.12E+03 2.19 2.20 7.00
1.32E+03 1.43 2.20 7.00
2.03E+03 1.52 2.20 7.00
1.64E+03 2.20 2.20 7.00
1.13E+03 1.19 2.20 7.00
1.01E+03 1.43 2.20 7.00
1.10E+00 10.39 2.20 7.00
1.10E+00 7.17 2.20 7.00
1.10E+00 7.35 2.20 7.00
1.10E+00 10.37 2.20 7.00
1.10E+00 17.14 2.20 7.00
1.10E+00 15.76 2.20 7.00
1.10E+00 6.05 2.20 7.00
1.10E+00 2.28 2.20 7.00
1.10E+00 26.52 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.24E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.21E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.27E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-880
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Ca CFS-L10-1315-T01-A 1 1.59E+04
Ca CFS-L10-1315-T02-A 1 5.57E+04
Ca CFS-L10-1315-T03-A 1 4.61E+04
Ca CFS-L10-1315-T04-A 1 1.15E+05
Ca CFS-L10-1315-T05-A 1 1.24E+05
Ca CFS-L10-1315-T06-A 1 1.69E+05
Ca CFS-L10-1315-T07-A 1 1.38E+05
Ca CFS-L10-1315-T08-A 1 9.93E+04
Ca CFS-L10-1315-T09-A 1 8.82E+04
Ca CFS-L10-1315-T01-B 1 1.36E+04
Ca CFS-L10-1315-T02-B 1 4.56E+04
Ca CFS-L10-1315-T03-B 1 3.85E+04
Ca CFS-L10-1315-T04-B 1 1.07E+05
Ca CFS-L10-1315-T05-B 1 1.16E+05
Ca CFS-L10-1315-T06-B 1 1.67E+05
Ca CFS-L10-1315-T07-B 1 1.38E+05
Ca CFS-L10-1315-T08-B 1 1.03E+05
Ca CFS-L10-1315-T09-B 1 9.51E+04
Ca CFS-L10-1315-T01-C 1 1.21E+04
Ca CFS-L10-1315-T02-C 1 4.92E+04
Ca CFS-L10-1315-T03-C 1 4.37E+04
Ca CFS-L10-1315-T04-C 1 1.10E+05
Ca CFS-L10-1315-T05-C 1 1.20E+05
Ca CFS-L10-1315-T06-C 1 1.74E+05
Ca CFS-L10-1315-T07-C 1 1.47E+05
Ca CFS-L10-1315-T08-C 1 1.00E+05
Ca CFS-L10-1315-T09-C 1 9.16E+04
Ca CFS-L10-1315-M01-A 1 4.11E+01
Ca CFS-L10-1315-M02-A 1 3.44E+01
Ca CFS-L10-1315-M03-A 1 1.55E+01
Ca CFS-L10-1315-M04-A 1 2.23E+01
Ca CFS-L10-1315-M05-A 1 1.01E+01
Ca CFS-L10-1315-M06-A 1 1.90E+01
Ca CFS-L10-1315-M07-A 1 1.21E+01
Ca CFS-L10-1315-M08-A 1 9.26E+00
Ca CFS-L10-1315-M09-A 1 9.88E+00
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.59E+04 0.43 2.60 8.30
5.57E+04 0.76 2.60 8.30
4.61E+04 2.06 2.60 8.30 10000 1000
1.15E+05 2.16 2.60 8.30
1.24E+05 0.90 2.60 8.30
1.69E+05 1.09 2.60 8.30
1.38E+05 1.72 2.60 8.30
9.93E+04 0.32 2.60 8.30
8.82E+04 0.20 2.60 8.30
1.36E+04 1.71 2.60 8.30
4.56E+04 5.70 2.60 8.30
3.85E+04 0.61 2.60 8.30 10000 1000
1.07E+05 1.89 2.60 8.30
1.16E+05 1.41 2.60 8.30
1.67E+05 1.46 2.60 8.30
1.38E+05 0.89 2.60 8.30
1.03E+05 2.41 2.60 8.30
9.51 E+04 2.63 2.60 8.30
1.21E+04 1.47 2.60 8.30
4.92E+04 2.04 2.60 8.30
4.37E+04 0.25 2.60 8.30 10000 1000
1.10E+05 2.47 2.60 8.30
1.20E+05 1.65 2.60 8.30
1.74E+05 1.32 2.60 8.30
1.47E+05 2.05 2.60 8.30
1.00E+05 0.95 2.60 8.30
9.16E+04 1.40 2.60 8.30
4.11E+01 6.73 2.60 8.30
3.44E+01 2.15 2.60 8.30
1.55E+01 21.36 2.60 8.30
2.23E+01 2.61 2.60 8.30
1.01E+01 26.65 2.60 8.30
1.90E+01 1.26 2.60 8.30
1.21E+01 4.48 2.60 8.30
9.26E+00 2.23 2.60 8.30
9.88E+00 10.65 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.69E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
3.94E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.45E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-881
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Cr CFS-L10-1315-T01-A 1 6.00E-01 U1/2
Cr CFS-L10-1315-T02-A 1 6.00E-01 U1/2
Cr CFS-L10-1315-T03-A 1 6.00E-01 U1/2
Cr CFS-L10-1315-T04-A 1 6.00E-01 U1/2
Cr CFS-L10-1315-T05-A 1 6.00E-01 U1/2
Cr CFS-L10-1315-T06-A 1 6.00E-01 U1/2
Cr CFS-L10-1315-T07-A 1 6.00E-01 U1/2
Cr CFS-L10-1315-T08-A 1 6.00E-01 U1/2
Cr CFS-L10-1315-T09-A 1 6.00E-01 U1/2
Cr CFS-L10-1315-T01-B 1 6.00E-01 U1/2
Cr CFS-L10-1315-T02-B 1 6.00E-01 U1/2
Cr CFS-L10-1315-T03-B 1 6.00E-01 U1/2
Cr CFS-L10-1315-T04-B 1 6.00E-01 U1/2
Cr CFS-L10-1315-T05-B 1 6.00E-01 U1/2
Cr CFS-L10-1315-T06-B 1 6.00E-01 U1/2
Cr CFS-L10-1315-T07-B 1 6.00E-01 U1/2
Cr CFS-L10-1315-T08-B 1 6.00E-01 U1/2
Cr CFS-L10-1315-T09-B 1 6.00E-01 U1/2
Cr CFS-L10-1315-T01-C 1 6.00E-01 U1/2
Cr CFS-L10-1315-T02-C 1 6.00E-01 U1/2
Cr CFS-L10-1315-T03-C 1 6.00E-01 U1/2
Cr CFS-L10-1315-T04-C 1 6.00E-01 U1/2
Cr CFS-L10-1315-T05-C 1 6.00E-01 U1/2
Cr CFS-L10-1315-T06-C 1 6.00E-01 U1/2
Cr CFS-L10-1315-T07-C 1 6.00E-01 U1/2
Cr CFS-L10-1315-T08-C 1 6.00E-01 U1/2
Cr CFS-L10-1315-T09-C 1 6.00E-01 U1/2
Cr CFS-L10-1315-M01-A 1 6.00E-01 U1/2
Cr CFS-L10-1315-M02-A 1 6.00E-01 U1/2
Cr CFS-L10-1315-M03-A 1 6.00E-01 U1/2
Cr CFS-L10-1315-M04-A 1 6.00E-01 U1/2
Cr CFS-L10-1315-M05-A 1 6.00E-01 U1/2
Cr CFS-L10-1315-M06-A 1 6.00E-01 U1/2
Cr CFS-L10-1315-M07-A 1 6.00E-01 U1/2
Cr CFS-L10-1315-M08-A 1 6.00E-01 U1/2
Cr CFS-L10-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 58.24 1.20 3.82
6.00E-01 33.30 1.20 3.82
6.00E-01 5.29 1.20 3.82 10000 1000
6.00E-01 14.68 1.20 3.82
6.00E-01 26.01 1.20 3.82
6.00E-01 34.87 1.20 3.82
6.00E-01 10.16 1.20 3.82
6.00E-01 9.79 1.20 3.82
6.00E-01 39.94 1.20 3.82
6.00E-01 41.68 1.20 3.82
6.00E-01 19.37 1.20 3.82
6.00E-01 39.65 1.20 3.82 10000 1000
6.00E-01 27.05 1.20 3.82
6.00E-01 45.60 1.20 3.82
6.00E-01 16.85 1.20 3.82
6.00E-01 58.23 1.20 3.82
6.00E-01 23.36 1.20 3.82
6.00E-01 14.58 1.20 3.82
6.00E-01 35.99 1.20 3.82
6.00E-01 54.79 1.20 3.82
6.00E-01 75.66 1.20 3.82 10000 1000
6.00E-01 11.84 1.20 3.82
6.00E-01 7.94 1.20 3.82
6.00E-01 21.03 1.20 3.82
6.00E-01 9.99 1.20 3.82
6.00E-01 43.75 1.20 3.82
6.00E-01 41.31 1.20 3.82
6.00E-01 14.71 1.20 3.82
6.00E-01 63.18 1.20 3.82
6.00E-01 34.46 1.20 3.82
6.00E-01 16.61 1.20 3.82
6.00E-01 11.44 1.20 3.82
6.00E-01 16.38 1.20 3.82
6.00E-01 64.75 1.20 3.82
6.00E-01 70.14 1.20 3.82
6.00E-01 22.54 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.74E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.25E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.59E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-882
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L
Co CFS-L10-1315-T01-A 1 1.80E+00 E
Co CFS-L10-1315-T02-A 1 7.45E+00
Co CFS-L10-1315-T03-A 1 8.36E+00
Co CFS-L10-1315-T04-A 1 2.73E+01
Co CFS-L10-1315-T05-A 1 3.47E+01
Co CFS-L10-1315-T06-A 1 5.32E+01
Co CFS-L10-1315-T07-A 1 4.41E+01
Co CFS-L10-1315-T08-A 1 3.02E+01
Co CFS-L10-1315-T09-A 1 2.69E+01
Co CFS-L10-1315-T01-B 1 9.00E-01 U1/2
Co CFS-L10-1315-T02-B 1 7.96E+00
Co CFS-L10-1315-T03-B 1 6.37E+00
Co CFS-L10-1315-T04-B 1 2.66E+01
Co CFS-L10-1315-T05-B 1 3.33E+01
Co CFS-L10-1315-T06-B 1 5.36E+01
Co CFS-L10-1315-T07-B 1 4.60E+01
Co CFS-L10-1315-T08-B 1 3.16E+01
Co CFS-L10-1315-T09-B 1 2.98E+01
Co CFS-L10-1315-T01-C 1 9.00E-01 U1/2
Co CFS-L10-1315-T02-C 1 9.06E+00
Co CFS-L10-1315-T03-C 1 7.87E+00
Co CFS-L10-1315-T04-C 1 2.87E+01
Co CFS-L10-1315-T05-C 1 3.58E+01
Co CFS-L10-1315-T06-C 1 5.85E+01
Co CFS-L10-1315-T07-C 1 4.86E+01
Co CFS-L10-1315-T08-C 1 3.26E+01
Co CFS-L10-1315-T09-C 1 2.93E+01
Co CFS-L10-1315-M01-A 1 9.00E-01 U1/2
Co CFS-L10-1315-M02-A 1 9.00E-01 U1/2
Co CFS-L10-1315-M03-A 1 9.00E-01 U1/2
Co CFS-L10-1315-M04-A 1 9.00E-01 U1/2
Co CFS-L10-1315-M05-A 1 9.00E-01 U1/2
Co CFS-L10-1315-M06-A 1 9.00E-01 U1/2
Co CFS-L10-1315-M07-A 1 9.00E-01 U1/2
Co CFS-L10-1315-M08-A 1 9.00E-01 U1/2
Co CFS-L10-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.80E+00 7.18 1.80 5.72
7.45E+00 2.73 1.80 5.72
8.36E+00 1.34 1.80 5.72 10000 1000
2.73E+01 3.70 1.80 5.72
3.47E+01 4.35 1.80 5.72
5.32E+01 2.65 1.80 5.72
4.41 E+01 1.29 1.80 5.72
3.02E+01 1.31 1.80 5.72
2.69E+01 6.20 1.80 5.72
9.00E-01 35.76 1.80 5.72
7.96E+00 14.14 1.80 5.72
6.37E+00 1.16 1.80 5.72 10000 1000
2.66E+01 5.19 1.80 5.72
3.33E+01 4.04 1.80 5.72
5.36E+01 1.58 1.80 5.72
4.60E+01 1.08 1.80 5.72
3.16E+01 3.93 1.80 5.72
2.98E+01 2.91 1.80 5.72
9.00E-01 13.26 1.80 5.72
9.06E+00 1.33 1.80 5.72
7.87E+00 9.57 1.80 5.72 10000 1000
2.87E+01 5.82 1.80 5.72
3.58E+01 2.37 1.80 5.72
5.85E+01 4.10 1.80 5.72
4.86E+01 3.70 1.80 5.72
3.26E+01 4.64 1.80 5.72
2.93E+01 2.66 1.80 5.72
9.00E-01 23.10 1.80 5.72
9.00E-01 44.52 1.80 5.72
9.00E-01 48.57 1.80 5.72
9.00E-01 14.29 1.80 5.72
9.00E-01 23.53 1.80 5.72
9.00E-01 27.66 1.80 5.72
9.00E-01 37.28 1.80 5.72
9.00E-01 4.45 1.80 5.72
9.00E-01 35.03 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.81 E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.41 E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.85E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-883
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Cu CFS-L10-1315-T01-A 1 8.27E+01
Cu CFS-L10-1315-T02-A 1 1.72E+02
Cu CFS-L10-1315-T03-A 1 1.54E+02
Cu CFS-L10-1315-T04-A 1 3.41E+02
Cu CFS-L10-1315-T05-A 1 4.35E+02
Cu CFS-L10-1315-T06-A 1 6.68E+02
Cu CFS-L10-1315-T07-A 1 6.61E+02
Cu CFS-L10-1315-T08-A 1 5.83E+02
Cu CFS-L10-1315-T09-A 1 6.83E+02
Cu CFS-L10-1315-T01-B 1 7.29E+01
Cu CFS-L10-1315-T02-B 1 1.76E+02
Cu CFS-L10-1315-T03-B 1 1.44E+02
Cu CFS-L10-1315-T04-B 1 3.13E+02
Cu CFS-L10-1315-T05-B 1 4.02E+02
Cu CFS-L10-1315-T06-B 1 6.28E+02
Cu CFS-L10-1315-T07-B 1 6.39E+02
Cu CFS-L10-1315-T08-B 1 6.33E+02
Cu CFS-L10-1315-T09-B 1 5.87E+02
Cu CFS-L10-1315-T01-C 1 6.97E+01
Cu CFS-L10-1315-T02-C 1 1.41E+02
Cu CFS-L10-1315-T03-C 1 1.35E+02
Cu CFS-L10-1315-T04-C 1 3.10E+02
Cu CFS-L10-1315-T05-C 1 3.97E+02
Cu CFS-L10-1315-T06-C 1 7.12E+02
Cu CFS-L10-1315-T07-C 1 7.21E+02
Cu CFS-L10-1315-T08-C 1 6.06E+02
Cu CFS-L10-1315-T09-C 1 6.75E+02
Cu CFS-L10-1315-M01-A 1 1.85E+00 U1/2
Cu CFS-L10-1315-M02-A 1 1.85E+00 U1/2
Cu CFS-L10-1315-M03-A 1 1.85E+00 U1/2
Cu CFS-L10-1315-M04-A 1 1.85E+00 U1/2
Cu CFS-L10-1315-M05-A 1 1.85E+00 U1/2
Cu CFS-L10-1315-M06-A 1 1.85E+00 U1/2
Cu CFS-L10-1315-M07-A 1 1.85E+00 U1/2
Cu CFS-L10-1315-M08-A 1 1.85E+00 U1/2
Cu CFS-L10-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.27E+01 2.31 3.70 11.80
1.72E+02 3.04 3.70 11.80
1.54E+02 2.22 3.70 11.80 10000 1000
3.41 E+02 2.44 3.70 11.80
4.35E+02 0.56 3.70 11.80
6.68E+02 1.06 3.70 11.80
6.61 E+02 1.96 3.70 11.80
5.83E+02 0.73 3.70 11.80
6.83E+02 1.29 3.70 11.80
7.29E+01 2.14 3.70 11.80
1.76E+02 4.19 3.70 11.80
1.44E+02 2.03 3.70 11.80 10000 1000
3.13E+02 1.29 3.70 11.80
4.02E+02 1.93 3.70 11.80
6.28E+02 1.68 3.70 11.80
6.39E+02 1.03 3.70 11.80
6.33E+02 2.07 3.70 11.80
5.87E+02 1.98 3.70 11.80
6.97E+01 1.84 3.70 11.80
1.41E+02 2.16 3.70 11.80
1.35E+02 1.13 3.70 11.80 10000 1000
3.10E+02 2.77 3.70 11.80
3.97E+02 1.49 3.70 11.80
7.12E+02 1.35 3.70 11.80
7.21E+02 2.68 3.70 11.80
6.06E+02 0.66 3.70 11.80
6.75E+02 0.40 3.70 11.80
1.85E+00 68.31 3.70 11.80
1.85E+00 35.47 3.70 11.80
1.85E+00 60.43 3.70 11.80
1.85E+00 55.70 3.70 11.80
1.85E+00 56.39 3.70 11.80
1.85E+00 24.43 3.70 11.80
1.85E+00 72.73 3.70 11.80
1.85E+00 34.24 3.70 11.80
1.85E+00 75.10 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.09E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-884
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Fe CFS-L10-1315-T01-A 1 1.00E+00 U1/2
Fe CFS-L10-1315-T02-A 1 1.00E+00 U1/2
Fe CFS-L10-1315-T03-A 1 1.00E+00 U1/2
Fe CFS-L10-1315-T04-A 1 1.00E+00 U1/2
Fe CFS-L10-1315-T05-A 1 1.00E+00 U1/2
Fe CFS-L10-1315-T06-A 1 1.00E+00 U1/2
Fe CFS-L10-1315-T07-A 1 1.00E+00 U1/2
Fe CFS-L10-1315-T08-A 1 1.00E+00 U1/2
Fe CFS-L10-1315-T09-A 1 1.00E+00 U1/2
Fe CFS-L10-1315-T01-B 1 1.00E+00 U1/2
Fe CFS-L10-1315-T02-B 1 1.00E+00 U1/2
Fe CFS-L10-1315-T03-B 1 1.00E+00 U1/2
Fe CFS-L10-1315-T04-B 1 1.00E+00 U1/2
Fe CFS-L10-1315-T05-B 1 1.00E+00 U1/2
Fe CFS-L10-1315-T06-B 1 1.00E+00 U1/2
Fe CFS-L10-1315-T07-B 1 1.00E+00 U1/2
Fe CFS-L10-1315-T08-B 1 1.00E+00 U1/2
Fe CFS-L10-1315-T09-B 1 1.00E+00 U1/2
Fe CFS-L10-1315-T01-C 1 1.00E+00 U1/2
Fe CFS-L10-1315-T02-C 1 1.00E+00 U1/2
Fe CFS-L10-1315-T03-C 1 1.00E+00 U1/2
Fe CFS-L10-1315-T04-C 1 1.00E+00 U1/2
Fe CFS-L10-1315-T05-C 1 1.00E+00 U1/2
Fe CFS-L10-1315-T06-C 1 1.00E+00 U1/2
Fe CFS-L10-1315-T07-C 1 1.00E+00 U1/2
Fe CFS-L10-1315-T08-C 1 1.00E+00 U1/2
Fe CFS-L10-1315-T09-C 1 1.00E+00 U1/2
Fe CFS-L10-1315-M01-A 1 1.00E+00 U1/2
Fe CFS-L10-1315-M02-A 1 1.00E+00 U1/2
Fe CFS-L10-1315-M03-A 1 1.00E+00 U1/2
Fe CFS-L10-1315-M04-A 1 1.00E+00 U1/2
Fe CFS-L10-1315-M05-A 1 1.00E+00 U1/2
Fe CFS-L10-1315-M06-A 1 1.00E+00 U1/2
Fe CFS-L10-1315-M07-A 1 1.00E+00 U1/2
Fe CFS-L10-1315-M08-A 1 1.00E+00 U1/2
Fe CFS-L10-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 12.68 2.00 6.40
1.00E+00 19.30 2.00 6.40
1.00E+00 28.57 2.00 6.40 10000 1000
1.00E+00 30.13 2.00 6.40
1.00E+00 39.61 2.00 6.40
1.00E+00 24.33 2.00 6.40
1.00E+00 22.66 2.00 6.40
1.00E+00 1.34 2.00 6.40
1.00E+00 26.11 2.00 6.40
1.00E+00 6.39 2.00 6.40
1.00E+00 5.08 2.00 6.40
1.00E+00 11.67 2.00 6.40 10000 1000
1.00E+00 12.91 2.00 6.40
1.00E+00 0.94 2.00 6.40
1.00E+00 17.35 2.00 6.40
1.00E+00 27.16 2.00 6.40
1.00E+00 3.49 2.00 6.40
1.00E+00 38.88 2.00 6.40
1.00E+00 22.27 2.00 6.40
1.00E+00 28.50 2.00 6.40
1.00E+00 39.36 2.00 6.40 10000 1000
1.00E+00 8.86 2.00 6.40
1.00E+00 16.95 2.00 6.40
1.00E+00 3.19 2.00 6.40
1.00E+00 17.89 2.00 6.40
1.00E+00 16.09 2.00 6.40
1.00E+00 5.52 2.00 6.40
1.00E+00 35.60 2.00 6.40
1.00E+00 15.13 2.00 6.40
1.00E+00 14.58 2.00 6.40
1.00E+00 13.79 2.00 6.40
1.00E+00 26.79 2.00 6.40
1.00E+00 27.82 2.00 6.40
1.00E+00 3.53 2.00 6.40
1.00E+00 7.86 2.00 6.40
1.00E+00 2.80 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.26E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.82E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.05E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-885
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Pb CFS-L10-1315-T01-A 1 6.35E+01
Pb CFS-L10-1315-T02-A 1 1.43E+02
Pb CFS-L10-1315-T03-A 1 1.24E+02
Pb CFS-L10-1315-T04-A 1 3.42E+02
Pb CFS-L10-1315-T05-A 1 4.38E+02
Pb CFS-L10-1315-T06-A 1 6.78E+02
Pb CFS-L10-1315-T07-A 1 5.98E+02
Pb CFS-L10-1315-T08-A 1 5.28E+02
Pb CFS-L10-1315-T09-A 1 5.04E+02
Pb CFS-L10-1315-T01-B 1 6.60E+01
Pb CFS-L10-1315-T02-B 1 1.56E+02
Pb CFS-L10-1315-T03-B 1 1.23E+02
Pb CFS-L10-1315-T04-B 1 3.18E+02
Pb CFS-L10-1315-T05-B 1 4.10E+02
Pb CFS-L10-1315-T06-B 1 6.08E+02
Pb CFS-L10-1315-T07-B 1 5.24E+02
Pb CFS-L10-1315-T08-B 1 5.67E+02
Pb CFS-L10-1315-T09-B 1 4.46E+02
Pb CFS-L10-1315-T01-C 1 3.94E+01
Pb CFS-L10-1315-T02-C 1 1.23E+02
Pb CFS-L10-1315-T03-C 1 1.12E+02
Pb CFS-L10-1315-T04-C 1 3.14E+02
Pb CFS-L10-1315-T05-C 1 3.78E+02
Pb CFS-L10-1315-T06-C 1 6.91E+02
Pb CFS-L10-1315-T07-C 1 6.03E+02
Pb CFS-L10-1315-T08-C 1 5.03E+02
Pb CFS-L10-1315-T09-C 1 5.04E+02
Pb CFS-L10-1315-M01-A 1 3.40E+00 U1/2
Pb CFS-L10-1315-M02-A 1 3.40E+00 U1/2
Pb CFS-L10-1315-M03-A 1 3.40E+00 U1/2
Pb CFS-L10-1315-M04-A 1 3.40E+00 U1/2
Pb CFS-L10-1315-M05-A 1 3.40E+00 U1/2
Pb CFS-L10-1315-M06-A 1 3.40E+00 U1/2
Pb CFS-L10-1315-M07-A 1 3.40E+00 U1/2
Pb CFS-L10-1315-M08-A 1 3.40E+00 U1/2
Pb CFS-L10-1315-M09-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.35E+01 4.91 6.80 21.60
1.43E+02 3.03 6.80 21.60
1.24E+02 3.25 6.80 21.60 10000 1000
3.42E+02 0.82 6.80 21.60
4.38E+02 1.11 6.80 21.60
6.78E+02 0.81 6.80 21.60
5.98E+02 1.43 6.80 21.60
5.28E+02 0.92 6.80 21.60
5.04E+02 0.79 6.80 21.60
6.60E+01 5.71 6.80 21.60
1.56E+02 6.61 6.80 21.60
1.23E+02 4.05 6.80 21.60 10000 1000
3.18E+02 1.73 6.80 21.60
4.10E+02 1.00 6.80 21.60
6.08E+02 1.59 6.80 21.60
5.24E+02 0.55 6.80 21.60
5.67E+02 1.59 6.80 21.60
4.46E+02 3.91 6.80 21.60
3.94E+01 1.14 6.80 21.60
1.23E+02 2.66 6.80 21.60
1.12E+02 3.24 6.80 21.60 10000 1000
3.14E+02 2.58 6.80 21.60
3.78E+02 1.93 6.80 21.60
6.91 E+02 1.31 6.80 21.60
6.03E+02 3.73 6.80 21.60
5.03E+02 2.65 6.80 21.60
5.04E+02 0.51 6.80 21.60
3.40E+00 7.77 6.80 21.60
3.40E+00 6.40 6.80 21.60
3.40E+00 14.27 6.80 21.60
3.40E+00 13.34 6.80 21.60
3.40E+00 5.66 6.80 21.60
3.40E+00 10.71 6.80 21.60
3.40E+00 7.87 6.80 21.60
3.40E+00 2.17 6.80 21.60
3.40E+00 3.56 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.21E+03 108% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-886
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Li CFS-L10-1315-T01-A 1 5.18E+00 E
Li CFS-L10-1315-T02-A 1 6.04E+00
Li CFS-L10-1315-T03-A 1 7.32E+00
Li CFS-L10-1315-T04-A 1 8.29E+00
Li CFS-L10-1315-T05-A 1 8.09E+00
Li CFS-L10-1315-T06-A 1 8.95E+00
Li CFS-L10-1315-T07-A 1 4.39E+00 E
Li CFS-L10-1315-T08-A 1 4.59E+00 E
Li CFS-L10-1315-T09-A 1 7.30E+00
Li CFS-L10-1315-T01-B 1 4.15E+00 E
Li CFS-L10-1315-T02-B 1 7.00E+00
Li CFS-L10-1315-T03-B 1 5.31E+00 E
Li CFS-L10-1315-T04-B 1 8.50E+00
Li CFS-L10-1315-T05-B 1 7.07E+00
Li CFS-L10-1315-T06-B 1 9.13E+00
Li CFS-L10-1315-T07-B 1 7.50E+00
Li CFS-L10-1315-T08-B 1 5.20E+00 E
Li CFS-L10-1315-T09-B 1 8.53E+00
Li CFS-L10-1315-T01-C 1 2.95E+00 E
Li CFS-L10-1315-T02-C 1 6.84E+00
Li CFS-L10-1315-T03-C 1 7.36E+00
Li CFS-L10-1315-T04-C 1 7.19E+00
Li CFS-L10-1315-T05-C 1 6.69E+00
Li CFS-L10-1315-T06-C 1 6.90E+00
Li CFS-L10-1315-T07-C 1 5.86E+00 E
Li CFS-L10-1315-T08-C 1 7.49E+00
Li CFS-L10-1315-T09-C 1 8.43E+00
Li CFS-L10-1315-M01-A 1 9.50E-01 U1/2
Li CFS-L10-1315-M02-A 1 9.50E-01 U1/2
Li CFS-L10-1315-M03-A 1 9.50E-01 U1/2
Li CFS-L10-1315-M04-A 1 9.50E-01 U1/2
Li CFS-L10-1315-M05-A 1 9.50E-01 U1/2
Li CFS-L10-1315-M06-A 1 9.50E-01 U1/2
Li CFS-L10-1315-M07-A 1 9.50E-01 U1/2
Li CFS-L10-1315-M08-A 1 9.50E-01 U1/2
Li CFS-L10-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.18E+00 19.95 1.90 6.00
6.04E+00 2.21 1.90 6.00
7.32E+00 3.44 1.90 6.00 10000 1000
8.29E+00 3.99 1.90 6.00
8.09E+00 12.35 1.90 6.00
8.95E+00 8.24 1.90 6.00
4.39E+00 30.79 1.90 6.00
4.59E+00 4.45 1.90 6.00
7.30E+00 8.51 1.90 6.00
4.15E+00 23.91 1.90 6.00
7.00E+00 1.98 1.90 6.00
5.31E+00 6.35 1.90 6.00 10000 1000
8.50E+00 3.30 1.90 6.00
7.07E+00 1.91 1.90 6.00
9.13E+00 9.60 1.90 6.00
7.50E+00 1.98 1.90 6.00
5.20E+00 12.92 1.90 6.00
8.53E+00 2.37 1.90 6.00
2.95E+00 12.79 1.90 6.00
6.84E+00 2.09 1.90 6.00
7.36E+00 3.48 1.90 6.00 10000 1000
7.19E+00 1.11 1.90 6.00
6.69E+00 5.54 1.90 6.00
6.90E+00 3.62 1.90 6.00
5.86E+00 23.30 1.90 6.00
7.49E+00 2.19 1.90 6.00
8.43E+00 10.04 1.90 6.00
9.50E-01 43.36 1.90 6.00
9.50E-01 9.57 1.90 6.00
9.50E-01 41.29 1.90 6.00
9.50E-01 33.10 1.90 6.00
9.50E-01 11.15 1.90 6.00
9.50E-01 23.71 1.90 6.00
9.50E-01 22.33 1.90 6.00
9.50E-01 42.78 1.90 6.00
9.50E-01 38.14 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.68E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.90E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.93E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-887
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Mn CFS-L10-1315-T01-A 1 1.67E+03
Mn CFS-L10-1315-T02-A 1 9.55E+03
Mn CFS-L10-1315-T03-A 1 9.56E+03
Mn CFS-L10-1315-T04-A 1 2.80E+04
Mn CFS-L10-1315-T05-A 1 4.53E+04
Mn CFS-L10-1315-T06-A 1 8.62E+04
Mn CFS-L10-1315-T07-A 1 7.41E+04
Mn CFS-L10-1315-T08-A 1 4.95E+04
Mn CFS-L10-1315-T09-A 1 4.22E+04
Mn CFS-L10-1315-T01-B 1 1.71E+03
Mn CFS-L10-1315-T02-B 1 9.51E+03
Mn CFS-L10-1315-T03-B 1 1.02E+04
Mn CFS-L10-1315-T04-B 1 3.74E+04
Mn CFS-L10-1315-T05-B 1 5.26E+04
Mn CFS-L10-1315-T06-B 1 9.36E+04
Mn CFS-L10-1315-T07-B 1 7.73E+04
Mn CFS-L10-1315-T08-B 1 5.03E+04
Mn CFS-L10-1315-T09-B 1 4.38E+04
Mn CFS-L10-1315-T01-C 1 1.93E+03
Mn CFS-L10-1315-T02-C 1 9.77E+03
Mn CFS-L10-1315-T03-C 1 9.90E+03
Mn CFS-L10-1315-T04-C 1 3.13E+04
Mn CFS-L10-1315-T05-C 1 4.82E+04
Mn CFS-L10-1315-T06-C 1 9.11E+04
Mn CFS-L10-1315-T07-C 1 7.95E+04
Mn CFS-L10-1315-T08-C 1 5.10E+04
Mn CFS-L10-1315-T09-C 1 4.39E+04
Mn CFS-L10-1315-M01-A 1 1.00E+00 U1/2
Mn CFS-L10-1315-M02-A 1 1.00E+00 U1/2
Mn CFS-L10-1315-M03-A 1 1.00E+00 U1/2
Mn CFS-L10-1315-M04-A 1 1.00E+00 U1/2
Mn CFS-L10-1315-M05-A 1 1.00E+00 U1/2
Mn CFS-L10-1315-M06-A 1 1.00E+00 U1/2
Mn CFS-L10-1315-M07-A 1 1.00E+00 U1/2
Mn CFS-L10-1315-M08-A 1 1.00E+00 U1/2
Mn CFS-L10-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.67E+03 0.70 2.00 6.40
9.55E+03 2.14 2.00 6.40
9.56E+03 2.07 2.00 6.40 10000 1000
2.80E+04 0.82 2.00 6.40
4.53E+04 1.49 2.00 6.40
8.62E+04 0.60 2.00 6.40
7.41E+04 2.82 2.00 6.40
4.95E+04 0.77 2.00 6.40
4.22E+04 0.38 2.00 6.40
1.71E+03 1.91 2.00 6.40
9.51 E+03 5.34 2.00 6.40
1.02E+04 0.36 2.00 6.40 10000 1000
3.74E+04 1.01 2.00 6.40
5.26E+04 1.99 2.00 6.40
9.36E+04 0.90 2.00 6.40
7.73E+04 0.93 2.00 6.40
5.03E+04 0.76 2.00 6.40
4.38E+04 1.25 2.00 6.40
1.93E+03 1.54 2.00 6.40
9.77E+03 0.96 2.00 6.40
9.90E+03 1.10 2.00 6.40 10000 1000
3.13E+04 0.78 2.00 6.40
4.82E+04 2.17 2.00 6.40
9.11E+04 0.46 2.00 6.40
7.95E+04 1.70 2.00 6.40
5.10E+04 0.63 2.00 6.40
4.39E+04 0.53 2.00 6.40
1.00E+00 33.40 2.00 6.40
1.00E+00 15.91 2.00 6.40
1.00E+00 23.20 2.00 6.40
1.00E+00 14.42 2.00 6.40
1.00E+00 32.02 2.00 6.40
1.00E+00 6.65 2.00 6.40
1.00E+00 5.65 2.00 6.40
1.00E+00 1.38 2.00 6.40
1.00E+00 15.23 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.11E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+04 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
I-
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Mg CFS-L10-1315-T01-A 1 1.67E+03
Mg CFS-L10-1315-T02-A 1 9.55E+03
Mg CFS-L10-1315-T03-A 1 9.56E+03
Mg CFS-L10-1315-T04-A 1 2.80E+04
Mg CFS-L10-1315-T05-A 1 4.53E+04
Mg CFS-L10-1315-T06-A 1 8.62E+04
Mg CFS-L10-1315-T07-A 1 7.41E+04
Mg CFS-L10-1315-T08-A 1 4.95E+04
Mg CFS-L10-1315-T09-A 1 4.22E+04
Mg CFS-L10-1315-T01-B 1 1.71E+03
Mg CFS-L10-1315-T02-B 1 9.51E+03
Mg CFS-L10-1315-T03-B 1 1.02E+04
Mg CFS-L10-1315-T04-B 1 3.74E+04
Mg CFS-L10-1315-T05-B 1 5.26E+04
Mg CFS-L10-1315-T06-B 1 9.36E+04
Mg CFS-L10-1315-T07-B 1 7.73E+04
Mg CFS-L10-1315-T08-B 1 5.03E+04
Mg CFS-L10-1315-T09-B 1 4.38E+04
Mg CFS-L10-1315-T01-C 1 1.93E+03
Mg CFS-L10-1315-T02-C 1 9.77E+03
Mg CFS-L10-1315-T03-C 1 9.90E+03
Mg CFS-L10-1315-T04-C 1 3.13E+04
Mg CFS-L10-1315-T05-C 1 4.82E+04
Mg CFS-L10-1315-T06-C 1 9.11E+04
Mg CFS-L10-1315-T07-C 1 7.95E+04
Mg CFS-L10-1315-T08-C 1 5.10E+04
Mg CFS-L10-1315-T09-C 1 4.39E+04
Mg CFS-L10-1315-M01-A 1 5.00E-01 U1/2
Mg CFS-L10-1315-M02-A 1 5.00E-01 U1/2
Mg CFS-L10-1315-M03-A 1 5.00E-01 U1/2
Mg CFS-L10-1315-M04-A 1 5.00E-01 U1/2
Mg CFS-L10-1315-M05-A 1 5.00E-01 U1/2
Mg CFS-L10-1315-M06-A 1 5.00E-01 U1/2
Mg CFS-L10-1315-M07-A 1 5.00E-01 U1/2
Mg CFS-L10-1315-M08-A 1 5.00E-01 U1/2
Mg CFS-L10-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.67E+03 2.16 1.00 3.18
9.55E+03 1.89 1.00 3.18
9.56E+03 2.11 1.00 3.18 10000 1000
2.80E+04 1.18 1.00 3.18
4.53E+04 0.95 1.00 3.18
8.62E+04 0.98 1.00 3.18
7.41E+04 0.98 1.00 3.18
4.95E+04 0.64 1.00 3.18
4.22E+04 0.63 1.00 3.18
1.71E+03 3.22 1.00 3.18
9.51E+03 5.00 1.00 3.18
1.02E+04 0.79 1.00 3.18 10000 1000
3.74E+04 0.77 1.00 3.18
5.26E+04 1.37 1.00 3.18
9.36E+04 0.51 1.00 3.18
7.73E+04 0.40 1.00 3.18
5.03E+04 2.77 1.00 3.18
4.38E+04 2.70 1.00 3.18
1.93E+03 1.62 1.00 3.18
9.77E+03 1.39 1.00 3.18
9.90E+03 1.24 1.00 3.18 10000 1000
3.13E+04 1.94 1.00 3.18
4.82E+04 1.62 1.00 3.18
9.11E+04 0.91 1.00 3.18
7.95E+04 1.62 1.00 3.18
5.10E+04 1.45 1.00 3.18
4.39E+04 1.20 1.00 3.18
5.00E-01 3.06 1.00 3.18
5.00E-01 6.03 1.00 3.18
5.00E-01 34.16 1.00 3.18
5.00E-01 2.99 1.00 3.18
5.00E-01 38.29 1.00 3.18
5.00E-01 27.97 1.00 3.18
5.00E-01 2.93 1.00 3.18
5.00E-01 1.52 1.00 3.18
5.00E-01 5.44 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.05E+04 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.11E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-889
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Mo CFS-L10-1315-T01-A 1 1.26E+00 E
Mo CFS-L10-1315-T02-A 1 1.26E+00 E
Mo CFS-L10-1315-T03-A 1 1.25E+00 E
Mo CFS-L10-1315-T04-A 1 1.46E+00 E
Mo CFS-L10-1315-T05-A 1 2.09E+00 E
Mo CFS-L10-1315-T06-A 1 3.41E+00 E
Mo CFS-L10-1315-T07-A 1 2.52E+00 E
Mo CFS-L10-1315-T08-A 1 1.67E+00 E
Mo CFS-L10-1315-T09-A 1 1.50E+00 E
Mo CFS-L10-1315-T01-B 1 1.22E+00 E
Mo CFS-L10-1315-T02-B 1 2.88E+00 E
Mo CFS-L10-1315-T03-B 1 2.15E+00 E
Mo CFS-L10-1315-T04-B 1 2.28E+00 E
Mo CFS-L10-1315-T05-B 1 1.53E+00 E
Mo CFS-L10-1315-T06-B 1 2.31E+00 E
Mo CFS-L10-1315-T07-B 1 3.56E+00 E
Mo CFS-L10-1315-T08-B 1 2.23E+00 E
Mo CFS-L10-1315-T09-B 1 1.31E+00 E
Mo CFS-L10-1315-T01-C 1 1.49E+00 E
Mo CFS-L10-1315-T02-C 1 1.83E+00 E
Mo CFS-L10-1315-T03-C 1 1.96E+00 E
Mo CFS-L10-1315-T04-C 1 1.83E+00 E
Mo CFS-L10-1315-T05-C 1 1.59E+00 E
Mo CFS-L10-1315-T06-C 1 2.17E+00 E
Mo CFS-L10-1315-T07-C 1 2.57E+00 E
Mo CFS-L10-1315-T08-C 1 1.92E+00 E
Mo CFS-L10-1315-T09-C 1 1.47E+00 E
Mo CFS-L10-1315-M01-A 1 6.00E-01 U1/2
Mo CFS-L10-1315-M02-A 1 6.00E-01 U1/2
Mo CFS-L10-1315-M03-A 1 6.00E-01 U1/2
Mo CFS-L10-1315-M04-A 1 6.00E-01 U1/2
Mo CFS-L10-1315-M05-A 1 6.00E-01 U1/2
Mo CFS-L10-1315-M06-A 1 6.00E-01 U1/2
Mo CFS-L10-1315-M07-A 1 6.00E-01 U1/2
Mo CFS-L10-1315-M08-A 1 6.00E-01 U1/2
Mo CFS-L10-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.26E+00 20.75 1.20 3.82
1.26E+00 5.41 1.20 3.82
1.25E+00 2.10 1.20 3.82 10000 1000
1.46E+00 14.04 1.20 3.82
2.09E+00 22.18 1.20 3.82
3.41E+00 18.57 1.20 3.82
2.52E+00 28.33 1.20 3.82
1.67E+00 24.43 1.20 3.82
1.50E+00 30.79 1.20 3.82
1.22E+00 13.25 1.20 3.82
2.88E+00 6.38 1.20 3.82
2.15E+00 5.27 1.20 3.82 10000 1000
2.28E+00 32.36 1.20 3.82
1.53E+00 23.79 1.20 3.82
2.31E+00 18.14 1.20 3.82
3.56E+00 12.19 1.20 3.82
2.23E+00 32.53 1.20 3.82
1.31E+00 31.61 1.20 3.82
1.49E+00 8.31 1.20 3.82
1.83E+00 0.87 1.20 3.82
1.96E+00 27.90 1.20 3.82 10000 1000
1.83E+00 14.56 1.20 3.82
1.59E+00 31.14 1.20 3.82
2.17E+00 24.17 1.20 3.82
2.57E+00 11.16 1.20 3.82
1.92E+00 37.81 1.20 3.82
1.47E+00 5.12 1.20 3.82
6.00E-01 31.57 1.20 3.82
6.00E-01 33.40 1.20 3.82
6.00E-01 5.58 1.20 3.82
6.00E-01 61.46 1.20 3.82
6.00E-01 29.95 1.20 3.82
6.00E-01 43.81 1.20 3.82
6.00E-01 15.17 1.20 3.82
6.00E-01 5.65 1.20 3.82
6.00E-01 35.93 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.68E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.29E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.72E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L1 01 31 5 CFS
1-890
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Ni CFS-L10-1315-T01-A 1 4.06E+00 E
Ni CFS-L10-1315-T02-A 1 1.62E+01
Ni CFS-L10-1315-T03-A 1 1.57E+01
Ni CFS-L10-1315-T04-A 1 5.20E+01
Ni CFS-L10-1315-T05-A 1 6.54E+01
Ni CFS-L10-1315-T06-A 1 9.72E+01
Ni CFS-L10-1315-T07-A 1 7.85E+01
Ni CFS-L10-1315-T08-A 1 5.37E+01
Ni CFS-L10-1315-T09-A 1 4.60E+01
Ni CFS-L10-1315-T01-B 1 3.01E+00 E
Ni CFS-L10-1315-T02-B 1 1.41E+01
Ni CFS-L10-1315-T03-B 1 1.29E+01
Ni CFS-L10-1315-T04-B 1 4.99E+01
Ni CFS-L10-1315-T05-B 1 6.04E+01
Ni CFS-L10-1315-T06-B 1 9.57E+01
Ni CFS-L10-1315-T07-B 1 7.89E+01
Ni CFS-L10-1315-T08-B 1 5.41E+01
Ni CFS-L10-1315-T09-B 1 4.83E+01
Ni CFS-L10-1315-T01-C 1 2.38E+00 E
Ni CFS-L10-1315-T02-C 1 1.58E+01
Ni CFS-L10-1315-T03-C 1 1.54E+01
Ni CFS-L10-1315-T04-C 1 5.23E+01
Ni CFS-L10-1315-T05-C 1 6.72E+01
Ni CFS-L10-1315-T06-C 1 1.04E+02
Ni CFS-L10-1315-T07-C 1 8.69E+01
Ni CFS-L10-1315-T08-C 1 5.66E+01
Ni CFS-L10-1315-T09-C 1 4.74E+01
Ni CFS-L10-1315-M01-A 1 9.00E-01 U1/2
Ni CFS-L10-1315-M02-A 1 9.00E-01 U1/2
Ni CFS-L10-1315-M03-A 1 9.00E-01 U1/2
Ni CFS-L10-1315-M04-A 1 9.00E-01 U1/2
Ni CFS-L10-1315-M05-A 1 9.00E-01 U1/2
Ni CFS-L10-1315-M06-A 1 9.00E-01 U1/2
Ni CFS-L10-1315-M07-A 1 9.00E-01 U1/2
Ni CFS-L10-1315-M08-A 1 9.00E-01 U1/2
Ni CFS-L10-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.06E+00 26.14 1.80 5.70
1.62E+01 7.35 1.80 5.70
1.57E+01 8.74 1.80 5.70 10000 1000
5.20E+01 4.78 1.80 5.70
6.54E+01 1.06 1.80 5.70
9.72E+01 4.08 1.80 5.70
7.85E+01 4.66 1.80 5.70
5.37E+01 1.21 1.80 5.70
4.60E+01 2.54 1.80 5.70
3.01E+00 18.00 1.80 5.70
1.41E+01 2.70 1.80 5.70
1.29E+01 13.84 1.80 5.70 10000 1000
4.99E+01 1.70 1.80 5.70
6.04E+01 3.55 1.80 5.70
9.57E+01 1.61 1.80 5.70
7.89E+01 1.70 1.80 5.70
5.41 E+01 0.74 1.80 5.70
4.83E+01 2.87 1.80 5.70
2.38E+00 23.49 1.80 5.70
1.58E+01 1.95 1.80 5.70
1.54E+01 8.04 1.80 5.70 10000 1000
5.23E+01 6.71 1.80 5.70
6.72E+01 1.78 1.80 5.70
1.04E+02 3.62 1.80 5.70
8.69E+01 2.87 1.80 5.70
5.66E+01 2.00 1.80 5.70
4.74E+01 3.30 1.80 5.70
9.00E-01 51.86 1.80 5.70
9.00E-01 28.94 1.80 5.70
9.00E-01 22.94 1.80 5.70
9.00E-01 15.05 1.80 5.70
9.00E-01 44.02 1.80 5.70
9.00E-01 19.84 1.80 5.70
9.00E-01 40.64 1.80 5.70
9.00E-01 2.11 1.80 5.70
9.00E-01 62.93 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.85E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.59E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.16E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-891
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
P CFS-L10-1315-T01-A 1 1.85E+00 U1/2
P CFS-L10-1315-T02-A 1 4.68E+00 E
P CFS-L10-1315-T03-A 1 7.56E+00 E
P CFS-L10-1315-T04-A 1 5.41E+00 E
P CFS-L10-1315-T05-A 1 5.43E+00 E
P CFS-L10-1315-T06-A 1 7.61E+00 E
P CFS-L10-1315-T07-A 1 6.38E+00 E
P CFS-L10-1315-T08-A 1 6.28E+00 E
P CFS-L10-1315-T09-A 1 9.43E+00 E
P CFS-L10-1315-T01-B 1 1.85E+00 U1/2
P CFS-L10-1315-T02-B 1 3.99E+00 E
P CFS-L10-1315-T03-B 1 5.44E+00 E
P CFS-L10-1315-T04-B 1 5.12E+00 E
P CFS-L10-1315-T05-B 1 6.43E+00 E
P CFS-L10-1315-T06-B 1 7.12E+00 E
P CFS-L10-1315-T07-B 1 8.18E+00 E
P CFS-L10-1315-T08-B 1 7.75E+00 E
P CFS-L10-1315-T09-B 1 4.69E+00 E
P CFS-L10-1315-T01-C 1 1.85E+00 U1/2
P CFS-L10-1315-T02-C 1 4.06E+00 E
P CFS-L10-1315-T03-C 1 6.36E+00 E
P CFS-L10-1315-T04-C 1 5.20E+00 E
P CFS-L10-1315-T05-C 1 7.04E+00 E
P CFS-L10-1315-T06-C 1 7.55E+00 E
P CFS-L10-1315-T07-C 1 9.51E+00 E
P CFS-L10-1315-T08-C 1 8.66E+00 E
P CFS-L10-1315-T09-C 1 5.07E+00 E
P CFS-L10-1315-M01-A 1 1.85E+00 U1/2
P CFS-L10-1315-M02-A 1 1.85E+00 U1/2
P CFS-L10-1315-M03-A 1 1.85E+00 U1/2
P CFS-L10-1315-M04-A 1 1.85E+00 U1/2
P CFS-L10-1315-M05-A 1 1.85E+00 U1/2
P CFS-L10-1315-M06-A 1 1.85E+00 U1/2
P CFS-L10-1315-M07-A 1 1.85E+00 U1/2
P CFS-L10-1315-M08-A 1 1.85E+00 U1/2
P CFS-L10-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.85E+00 63.22 3.70 11.80
4.68E+00 15.12 3.70 11.80
7.56E+00 28.02 3.70 11.80 10000 1000
5.41 E+00 37.29 3.70 11.80
5.43E+00 26.14 3.70 11.80
7.61E+00 12.10 3.70 11.80
6.38E+00 17.75 3.70 11.80
6.28E+00 11.30 3.70 11.80
9.43E+00 55.99 3.70 11.80
1.85E+00 28.87 3.70 11.80
3.99E+00 31.58 3.70 11.80
5.44E+00 23.89 3.70 11.80 10000 1000
5.12E+00 38.61 3.70 11.80
6.43E+00 33.57 3.70 11.80
7.12E+00 25.32 3.70 11.80
8.18E+00 47.82 3.70 11.80
7.75E+00 43.18 3.70 11.80
4.69E+00 36.52 3.70 11.80
1.85E+00 59.73 3.70 11.80
4.06E+00 29.64 3.70 11.80
6.36E+00 12.17 3.70 11.80 10000 1000
5.20E+00 34.93 3.70 11.80
7.04E+00 39.26 3.70 11.80
7.55E+00 22.47 3.70 11.80
9.51E+00 17.31 3.70 11.80
8.66E+00 26.32 3.70 11.80
5.07E+00 14.92 3.70 11.80
1.85E+00 32.76 3.70 11.80
1.85E+00 21.33 3.70 11.80
1.85E+00 54.72 3.70 11.80
1.85E+00 18.61 3.70 11.80
1.85E+00 6.09 3.70 11.80
1.85E+00 8.57 3.70 11.80
1.85E+00 35.41 3.70 11.80
1.85E+00 57.88 3.70 11.80
1.85E+00 43.36 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.87E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.45E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.21E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-892
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
K CFS-L10-1315-T01-A 1 2.35E+02
K CFS-L10-1315-T02-A 1 1.21E+03
K CFS-L10-1315-T03-A 1 1.12E+03
K CFS-L10-1315-T04-A 1 7.58E+03
K CFS-L10-1315-T05-A 1 6.39E+03
K CFS-L10-1315-T06-A 1 1.03E+04
K CFS-L10-1315-T07-A 1 7.52E+03
K CFS-L10-1315-T08-A 1 5.02E+03
K CFS-L10-1315-T09-A 1 3.99E+03
K CFS-L10-1315-T01-B 1 1.63E+02
K CFS-L10-1315-T02-B 1 1.31E+03
K CFS-L10-1315-T03-B 1 1.25E+03
K CFS-L10-1315-T04-B 1 6.68E+03
K CFS-L10-1315-T05-B 1 6.60E+03
K CFS-L10-1315-T06-B 1 1.06E+04
K CFS-L10-1315-T07-B 1 7.57E+03
K CFS-L10-1315-T08-B 1 4.99E+03
K CFS-L10-1315-T09-B 1 4.16E+03
K CFS-L10-1315-T01-C 1 1.71E+02
K CFS-L10-1315-T02-C 1 1.23E+03
K CFS-L10-1315-T03-C 1 1.20E+03
K CFS-L10-1315-T04-C 1 7.11E+03
K CFS-L10-1315-T05-C 1 6.38E+03
K CFS-L10-1315-T06-C 1 1.07E+04
K CFS-L10-1315-T07-C 1 7.72E+03
K CFS-L10-1315-T08-C 1 4.94E+03
K CFS-L10-1315-T09-C 1 4.07E+03
K CFS-L10-1315-M01-A 1 1.94E+01
K CFS-L10-1315-M02-A 1 1.99E+01
K CFS-L10-1315-M03-A 1 2.56E+01
K CFS-L10-1315-M04-A 1 1.47E+01
K CFS-L10-1315-M05-A 1 1.42E+01
K CFS-L10-1315-M06-A 1 2.12E+01
K CFS-L10-1315-M07-A 1 2.76E+01
K CFS-L10-1315-M08-A 1 2.31E+01
K CFS-L10-1315-M09-A 1 2.67E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.35E+02 1.99 1.60 5.09
1.21E+03 0.48 1.60 5.09
1.12E+03 1.78 1.60 5.09 10000 1000
7.58E+03 2.08 1.60 5.09
6.39E+03 0.81 1.60 5.09
1.03E+04 1.33 1.60 5.09
7.52E+03 1.85 1.60 5.09
5.02E+03 0.25 1.60 5.09
3.99E+03 0.33 1.60 5.09
1.63E+02 2.41 1.60 5.09
1.31E+03 5.46 1.60 5.09
1.25E+03 0.34 1.60 5.09 10000 1000
6.68E+03 1.90 1.60 5.09
6.60E+03 1.89 1.60 5.09
1.06E+04 0.92 1.60 5.09
7.57E+03 0.99 1.60 5.09
4.99E+03 2.41 1.60 5.09
4.16E+03 2.50 1.60 5.09
1.71E+02 0.33 1.60 5.09
1.23E+03 1.71 1.60 5.09
1.20E+03 0.51 1.60 5.09 10000 1000
7.11E+03 2.52 1.60 5.09
6.38E+03 1.30 1.60 5.09
1.07E+04 1.56 1.60 5.09
7.72E+03 2.20 1.60 5.09
4.94E+03 1.12 1.60 5.09
4.07E+03 1.29 1.60 5.09
1.94E+01 0.78 1.60 5.09
1.99E+01 5.77 1.60 5.09
2.56E+01 8.14 1.60 5.09
1.47E+01 1.10 1.60 5.09
1.42E+01 2.05 1.60 5.09
2.12E+01 6.61 1.60 5.09
2.76E+01 6.31 1.60 5.09
2.31E+01 2.33 1.60 5.09
2.67E+01 9.56 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.00E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.20E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.13E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-893
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Se CFS-L10-1315-T01-A 1 1.63E+01 E
Se CFS-L10-1315-T02-A 1 1.94E+01 E
Se CFS-L10-1315-T03-A 1 2.46E+01 E
Se CFS-L10-1315-T04-A 1 3.49E+01 E
Se CFS-L10-1315-T05-A 1 5.64E+01
Se CFS-L10-1315-T06-A 1 8.62E+01
Se CFS-L10-1315-T07-A 1 6.06E+01
Se CFS-L10-1315-T08-A 1 4.52E+01 E
Se CFS-L10-1315-T09-A 1 2.21E+01 E
Se CFS-L10-1315-T01-B 1 1.68E+01 E
Se CFS-L10-1315-T02-B 1 2.06E+01 E
Se CFS-L10-1315-T03-B 1 2.50E+01 E
Se CFS-L10-1315-T04-B 1 3.69E+01 E
Se CFS-L10-1315-T05-B 1 5.07E+01
Se CFS-L10-1315-T06-B 1 7.76E+01
Se CFS-L10-1315-T07-B 1 6.37E+01
Se CFS-L10-1315-T08-B 1 3.36E+01 E
Se CFS-L10-1315-T09-B 1 1.74E+01 E
Se CFS-L10-1315-T01-C 1 1.71E+01 E
Se CFS-L10-1315-T02-C 1 2.09E+01 E
Se CFS-L10-1315-T03-C 1 2.55E+01 E
Se CFS-L10-1315-T04-C 1 3.80E+01 E
Se CFS-L10-1315-T05-C 1 4.79E+01
Se CFS-L10-1315-T06-C 1 7.66E+01
Se CFS-L10-1315-T07-C 1 6.93E+01
Se CFS-L10-1315-T08-C 1 3.15E+01 E
Se CFS-L10-1315-T09-C 1 1.67E+01 E
Se CFS-L10-1315-M01-A 1 7.50E+00 U1/2
Se CFS-L10-1315-M02-A 1 7.50E+00 U1/2
Se CFS-L10-1315-M03-A 1 7.50E+00 U1/2
Se CFS-L10-1315-M04-A 1 7.50E+00 U1/2
Se CFS-L10-1315-M05-A 1 7.50E+00 U1/2
Se CFS-L10-1315-M06-A 1 7.50E+00 U1/2
Se CFS-L10-1315-M07-A 1 7.50E+00 U1/2
Se CFS-L10-1315-M08-A 1 7.50E+00 U1/2
Se CFS-L10-1315-M09-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.63E+01 21.30 15.00 47.70
1.94E+01 15.02 15.00 47.70
2.46E+01 15.30 15.00 47.70 10000 1000
3.49E+01 5.62 15.00 47.70
5.64E+01 4.60 15.00 47.70
8.62E+01 10.90 15.00 47.70
6.06E+01 6.60 15.00 47.70
4.52E+01 24.47 15.00 47.70
2.21E+01 18.07 15.00 47.70
1.68E+01 27.92 15.00 47.70
2.06E+01 15.72 15.00 47.70
2.50E+01 11.26 15.00 47.70 10000 1000
3.69E+01 6.90 15.00 47.70
5.07E+01 6.95 15.00 47.70
7.76E+01 8.93 15.00 47.70
6.37E+01 6.92 15.00 47.70
3.36E+01 17.26 15.00 47.70
1.74E+01 19.01 15.00 47.70
1.71E+01 15.21 15.00 47.70
2.09E+01 4.86 15.00 47.70
2.55E+01 9.57 15.00 47.70 10000 1000
3.80E+01 9.34 15.00 47.70
4.79E+01 1.96 15.00 47.70
7.66E+01 3.93 15.00 47.70
6.93E+01 7.69 15.00 47.70
3.15E+01 15.64 15.00 47.70
1.67E+01 22.17 15.00 47.70
7.50E+00 11.36 15.00 47.70
7.50E+00 43.42 15.00 47.70
7.50E+00 46.13 15.00 47.70
7.50E+00 32.90 15.00 47.70
7.50E+00 43.35 15.00 47.70
7.50E+00 27.89 15.00 47.70
7.50E+00 17.34 15.00 47.70
7.50E+00 5.26 15.00 47.70
7.50E+00 9.73 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.79E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.76E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.44E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-894
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Si CFS-L10-1315-T01-A 1 4.77E+01
Si CFS-L10-1315-T02-A 1 3.16E+02
Si CFS-L10-1315-T03-A 1 2.92E+02
Si CFS-L10-1315-T04-A 1 9.44E+02
Si CFS-L10-1315-T05-A 1 1.17E+03
Si CFS-L10-1315-T06-A 1 1.89E+03
Si CFS-L10-1315-T07-A 1 1.45E+03
Si CFS-L10-1315-T08-A 1 1.31E+03
Si CFS-L10-1315-T09-A 1 1.15E+03
Si CFS-L10-1315-T01-B 1 3.67E+01
Si CFS-L10-1315-T02-B 1 2.70E+02
Si CFS-L10-1315-T03-B 1 2.48E+02
Si CFS-L10-1315-T04-B 1 8.96E+02
Si CFS-L10-1315-T05-B 1 1.09E+03
Si CFS-L10-1315-T06-B 1 1.84E+03
Si CFS-L10-1315-T07-B 1 1.44E+03
Si CFS-L10-1315-T08-B 1 1.31E+03
Si CFS-L10-1315-T09-B 1 1.19E+03
Si CFS-L10-1315-T01-C 1 3.29E+01
Si CFS-L10-1315-T02-C 1 3.01E+02
Si CFS-L10-1315-T03-C 1 2.88E+02
Si CFS-L10-1315-T04-C 1 9.45E+02
Si CFS-L10-1315-T05-C 1 1.15E+03
Si CFS-L10-1315-T06-C 1 1.95E+03
Si CFS-L10-1315-T07-C 1 1.54E+03
Si CFS-L10-1315-T08-C 1 1.30E+03
Si CFS-L10-1315-T09-C 1 1.18E+03
Si CFS-L10-1315-M01-A 1 5.50E-01 U1/2
Si CFS-L10-1315-M02-A 1 5.50E-01 U1/2
Si CFS-L10-1315-M03-A 1 5.50E-01 U1/2
Si CFS-L10-1315-M04-A 1 5.50E-01 U1/2
Si CFS-L10-1315-M05-A 1 5.50E-01 U1/2
Si CFS-L10-1315-M06-A 1 5.50E-01 U1/2
Si CFS-L10-1315-M07-A 1 5.50E-01 U1/2
Si CFS-L10-1315-M08-A 1 5.50E-01 U1/2
Si CFS-L10-1315-M09-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.77E+01 4.73 1.10 3.50
3.16E+02 1.34 1.10 3.50
2.92E+02 1.77 1.10 3.50 10000 1000
9.44E+02 2.10 1.10 3.50
1.17E+03 0.51 1.10 3.50
1.89E+03 1.15 1.10 3.50
1.45E+03 1.88 1.10 3.50
1.31E+03 0.73 1.10 3.50
1.15E+03 0.59 1.10 3.50
3.67E+01 2.27 1.10 3.50
2.70E+02 5.56 1.10 3.50
2.48E+02 1.15 1.10 3.50 10000 1000
8.96E+02 2.07 1.10 3.50
1.09E+03 1.58 1.10 3.50
1.84E+03 0.87 1.10 3.50
1.44E+03 1.47 1.10 3.50
1.31E+03 1.96 1.10 3.50
1.19E+03 2.57 1.10 3.50
3.29E+01 3.68 1.10 3.50
3.01 E+02 1.27 1.10 3.50
2.88E+02 1.15 1.10 3.50 10000 1000
9.45E+02 2.79 1.10 3.50
1.15E+03 1.73 1.10 3.50
1.95E+03 1.41 1.10 3.50
1.54E+03 2.03 1.10 3.50
1.30E+03 1.58 1.10 3.50
1.18E+03 1.34 1.10 3.50
5.50E-01 17.85 1.10 3.50
5.50E-01 12.72 1.10 3.50
5.50E-01 21.27 1.10 3.50
5.50E-01 20.41 1.10 3.50
5.50E-01 8.89 1.10 3.50
5.50E-01 20.81 1.10 3.50
5.50E-01 12.36 1.10 3.50
5.50E-01 2.44 1.10 3.50
5.50E-01 21.43 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.18E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.18E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-895
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Na CFS-L10-1315-T01-A 1 8.62E+02
Na CFS-L10-1315-T02-A 1 5.45E+03
Na CFS-L10-1315-T03-A 1 5.66E+03
Na CFS-L10-1315-T04-A 1 1.58E+04
Na CFS-L10-1315-T05-A 1 2.25E+04
Na CFS-L10-1315-T06-A 1 3.71E+04
Na CFS-L10-1315-T07-A 1 2.80E+04
Na CFS-L10-1315-T08-A 1 1.61E+04
Na CFS-L10-1315-T09-A 1 1.27E+04
Na CFS-L10-1315-T01-B 1 9.67E+02
Na CFS-L10-1315-T02-B 1 5.70E+03
Na CFS-L10-1315-T03-B 1 5.94E+03
Na CFS-L10-1315-T04-B 1 2.04E+04
Na CFS-L10-1315-T05-B 1 2.46E+04
Na CFS-L10-1315-T06-B 1 3.82E+04
Na CFS-L10-1315-T07-B 1 2.78E+04
Na CFS-L10-1315-T08-B 1 1.57E+04
Na CFS-L10-1315-T09-B 1 1.29E+04
Na CFS-L10-1315-T01-C 1 9.33E+02
Na CFS-L10-1315-T02-C 1 6.00E+03
Na CFS-L10-1315-T03-C 1 6.38E+03
Na CFS-L10-1315-T04-C 1 1.72E+04
Na CFS-L10-1315-T05-C 1 2.35E+04
Na CFS-L10-1315-T06-C 1 3.85E+04
Na CFS-L10-1315-T07-C 1 2.83E+04
Na CFS-L10-1315-T08-C 1 1.59E+04
Na CFS-L10-1315-T09-C 1 1.28E+04
Na CFS-L10-1315-M01-A 1 5.77E+01
Na CFS-L10-1315-M02-A 1 7.47E+01
Na CFS-L10-1315-M03-A 1 6.59E+01
Na CFS-L10-1315-M04-A 1 5.41E+01
Na CFS-L10-1315-M05-A 1 6.55E+01
Na CFS-L10-1315-M06-A 1 3.86E+01
Na CFS-L10-1315-M07-A 1 5.03E+01
Na CFS-L10-1315-M08-A 1 4.36E+01
Na CFS-L10-1315-M09-A 1 6.18E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.62E+02 0.10 2.50 8.00
5.45E+03 0.61 2.50 8.00
5.66E+03 0.23 2.50 8.00 10000 1000
1.58E+04 1.19 2.50 8.00
2.25E+04 0.65 2.50 8.00
3.71 E+04 0.47 2.50 8.00
2.80E+04 0.48 2.50 8.00
1.61 E+04 1.07 2.50 8.00
1.27E+04 0.50 2.50 8.00
9.67E+02 1.01 2.50 8.00
5.70E+03 1.90 2.50 8.00
5.94E+03 0.17 2.50 8.00 10000 1000
2.04E+04 0.73 2.50 8.00
2.46E+04 0.62 2.50 8.00
3.82E+04 1.05 2.50 8.00
2.78E+04 0.55 2.50 8.00
1.57E+04 0.55 2.50 8.00
1.29E+04 0.58 2.50 8.00
9.33E+02 0.49 2.50 8.00
6.00E+03 0.35 2.50 8.00
6.38E+03 0.27 2.50 8.00 10000 1000
1.72E+04 1.09 2.50 8.00
2.35E+04 0.48 2.50 8.00
3.85E+04 0.46 2.50 8.00
2.83E+04 0.79 2.50 8.00
1.59E+04 0.97 2.50 8.00
1.28E+04 1.37 2.50 8.00
5.77E+01 1.55 2.50 8.00
7.47E+01 2.54 2.50 8.00
6.59E+01 0.40 2.50 8.00
5.41E+01 1.21 2.50 8.00
6.55E+01 0.31 2.50 8.00
3.86E+01 1.65 2.50 8.00
5.03E+01 1.36 2.50 8.00
4.36E+01 0.41 2.50 8.00
6.18E+01 1.39 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
6.56E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
6.90E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
7.27E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-896
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualil
1 1 ug/L
Sr CFS-L10-1315-T01-A 1 3.69E+01
Sr CFS-L10-1315-T02-A 1 1.64E+02
Sr CFS-L10-1315-T03-A 1 1.45E+02
Sr CFS-L10-1315-T04-A 1 4.60E+02
Sr CFS-L10-1315-T05-A 1 5.62E+02
Sr CFS-L10-1315-T06-A 1 8.96E+02
Sr CFS-L10-1315-T07-A 1 7.64E+02
Sr CFS-L10-1315-T08-A 1 5.56E+02
Sr CFS-L10-1315-T09-A 1 4.92E+02
Sr CFS-L10-1315-T01-B 1 3.30E+01
Sr CFS-L10-1315-T02-B 1 1.56E+02
Sr CFS-L10-1315-T03-B 1 1.35E+02
Sr CFS-L10-1315-T04-B 1 4.81E+02
Sr CFS-L10-1315-T05-B 1 5.63E+02
Sr CFS-L10-1315-T06-B 1 8.94E+02
Sr CFS-L10-1315-T07-B 1 7.68E+02
Sr CFS-L10-1315-T08-B 1 5.54E+02
Sr CFS-L10-1315-T09-B 1 5.03E+02
Sr CFS-L10-1315-T01-C 1 2.97E+01
Sr CFS-L10-1315-T02-C 1 1.59E+02
Sr CFS-L10-1315-T03-C 1 1.46E+02
Sr CFS-L10-1315-T04-C 1 4.57E+02
Sr CFS-L10-1315-T05-C 1 5.50E+02
Sr CFS-L10-1315-T06-C 1 9.16E+02
Sr CFS-L10-1315-T07-C 1 7.88E+02
Sr CFS-L10-1315-T08-C 1 5.37E+02
Sr CFS-L10-1315-T09-C 1 4.90E+02
Sr CFS-L10-1315-M01-A 1 5.00E-01 U1/2
Sr CFS-L10-1315-M02-A 1 5.00E-01 U1/2
Sr CFS-L10-1315-M03-A 1 5.00E-01 U1/2
Sr CFS-L10-1315-M04-A 1 5.00E-01 U1/2
Sr CFS-L10-1315-M05-A 1 5.00E-01 U1/2
Sr CFS-L10-1315-M06-A 1 5.00E-01 U1/2
Sr CFS-L10-1315-M07-A 1 5.00E-01 U1/2
Sr CFS-L10-1315-M08-A 1 5.00E-01 U1/2
Sr CFS-L10-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.69E+01 4.92 1.00 3.18
1.64E+02 0.48 1.00 3.18
1.45E+02 1.57 1.00 3.18 10000 1000
4.60E+02 1.39 1.00 3.18
5.62E+02 1.08 1.00 3.18
8.96E+02 0.91 1.00 3.18
7.64E+02 2.50 1.00 3.18
5.56E+02 0.45 1.00 3.18
4.92E+02 0.33 1.00 3.18
3.30E+01 3.50 1.00 3.18
1.56E+02 6.38 1.00 3.18
1.35E+02 0.96 1.00 3.18 10000 1000
4.81E+02 1.37 1.00 3.18
5.63E+02 2.36 1.00 3.18
8.94E+02 1.61 1.00 3.18
7.68E+02 0.39 1.00 3.18
5.54E+02 2.47 1.00 3.18
5.03E+02 2.85 1.00 3.18
2.97E+01 2.95 1.00 3.18
1.59E+02 1.54 1.00 3.18
1.46E+02 0.70 1.00 3.18 10000 1000
4.57E+02 1.97 1.00 3.18
5.50E+02 0.77 1.00 3.18
9.16E+02 2.31 1.00 3.18
7.88E+02 2.71 1.00 3.18
5.37E+02 0.83 1.00 3.18
4.90E+02 1.59 1.00 3.18
5.00E-01 57.03 1.00 3.18
5.00E-01 39.04 1.00 3.18
5.00E-01 51.06 1.00 3.18
5.00E-01 53.53 1.00 3.18
5.00E-01 4.30 1.00 3.18
5.00E-01 52.60 1.00 3.18
5.00E-01 47.68 1.00 3.18
5.00E-01 2.34 1.00 3.18
5.00E-01 16.43 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.17E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 . 1 9E+03 1 05% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-897
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
S CFS-L10-1315-T01-A 1 1.42E+04
S CFS-L10-1315-T02-A 1 5.42E+04
S CFS-L10-1315-T03-A 1 4.60E+04
S CFS-L10-1315-T04-A 1 1.39E+05
S CFS-L10-1315-T05-A 1 1.71E+05
S CFS-L10-1315-T06-A 1 2.72E+05
S CFS-L10-1315-T07-A 1 2.27E+05
S CFS-L10-1315-T08-A 1 1.56E+05
S CFS-L10-1315-T09-A 1 1.36E+05
S CFS-L10-1315-T01-B 1 1.25E+04
S CFS-L10-1315-T02-B 1 4.74E+04
S CFS-L10-1315-T03-B 1 4.23E+04
S CFS-L10-1315-T04-B 1 1.47E+05
S CFS-L10-1315-T05-B 1 1.76E+05
S CFS-L10-1315-T06-B 1 2.81E+05
S CFS-L10-1315-T07-B 1 2.33E+05
S CFS-L10-1315-T08-B 1 1.60E+05
S CFS-L10-1315-T09-B 1 1.45E+05
S CFS-L10-1315-T01-C 1 1.16E+04
S CFS-L10-1315-T02-C 1 5.04E+04
S CFS-L10-1315-T03-C 1 4.67E+04
S CFS-L10-1315-T04-C 1 1.42E+05
S CFS-L10-1315-T05-C 1 1.75E+05
S CFS-L10-1315-T06-C 1 2.89E+05
S CFS-L10-1315-T07-C 1 2.45E+05
S CFS-L10-1315-T08-C 1 1.60E+05
S CFS-L10-1315-T09-C 1 1.43E+05
S CFS-L10-1315-M01-A 1 3.40E+00 U1/2
S CFS-L10-1315-M02-A 1 3.40E+00 U1/2
S CFS-L10-1315-M03-A 1 2.25E+01
S CFS-L10-1315-M04-A 1 1.44E+01 E
S CFS-L10-1315-M05-A 1 2.49E+01
S CFS-L10-1315-M06-A 1 1.89E+01 E
S CFS-L10-1315-M07-A 1 6.80E+00 E
S CFS-L10-1315-M08-A 1 8.63E+00 E
S CFS-L10-1315-M09-A 1 2.06E+01 E
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.42E+04 0.41 6.80 21.60
5.42E+04 1.19 6.80 21.60
4.60E+04 2.14 6.80 21.60 10000 1000
1.39E+05 2.15 6.80 21.60
1.71E+05 0.52 6.80 21.60
2.72E+05 1.05 6.80 21.60
2.27E+05 1.83 6.80 21.60
1.56E+05 0.34 6.80 21.60
1.36E+05 0.40 6.80 21.60
1.25E+04 2.75 6.80 21.60
4.74E+04 5.70 6.80 21.60
4.23E+04 0.74 6.80 21.60 10000 1000
1.47E+05 1.37 6.80 21.60
1.76E+05 1.70 6.80 21.60
2.81E+05 1.22 6.80 21.60
2.33E+05 1.13 6.80 21.60
1.60E+05 2.26 6.80 21.60
1.45E+05 2.45 6.80 21.60
1.16E+04 1.82 6.80 21.60
5.04E+04 1.95 6.80 21.60
4.67E+04 0.39 6.80 21.60 10000 1000
1.42E+05 2.81 6.80 21.60
1.75E+05 1.44 6.80 21.60
2.89E+05 1.46 6.80 21.60
2.45E+05 2.35 6.80 21.60
1.60E+05 1.21 6.80 21.60
1.43E+05 1.24 6.80 21.60
3.40E+00 25.37 6.80 21.60
3.40E+00 8.54 6.80 21.60
2.25E+01 1.76 6.80 21.60
1.44E+01 2.48 6.80 21.60
2.49E+01 3.45 6.80 21.60
1.89E+01 12.47 6.80 21.60
6.80E+00 10.18 6.80 21.60
8.63E+00 1.91 6.80 21.60
2.06E+01 1.73 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.69E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.32E+04 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.76E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-898
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Tl CFS-L10-1315-T01-A 1 9.10E+00 E
Tl CFS-L10-1315-T02-A 1 5.13E+01
Tl CFS-L10-1315-T03-A 1 4.81E+01
Tl CFS-L10-1315-T04-A 1 1.83E+02
Tl CFS-L10-1315-T05-A 1 2.24E+02
Tl CFS-L10-1315-T06-A 1 3.48E+02
Tl CFS-L10-1315-T07-A 1 2.53E+02
Tl CFS-L10-1315-T08-A 1 2.05E+02
Tl CFS-L10-1315-T09-A 1 1.60E+02
Tl CFS-L10-1315-T01-B 1 5.36E+00 E
Tl CFS-L10-1315-T02-B 1 5.65E+01
Tl CFS-L10-1315-T03-B 1 4.91E+01
Tl CFS-L10-1315-T04-B 1 1.91E+02
Tl CFS-L10-1315-T05-B 1 2.19E+02
Tl CFS-L10-1315-T06-B 1 3.48E+02
Tl CFS-L10-1315-T07-B 1 2.54E+02
Tl CFS-L10-1315-T08-B 1 2.07E+02
Tl CFS-L10-1315-T09-B 1 1.71E+02
Tl CFS-L10-1315-T01-C 1 5.86E+00 E
Tl CFS-L10-1315-T02-C 1 5.14E+01
Tl CFS-L10-1315-T03-C 1 5.27E+01
Tl CFS-L10-1315-T04-C 1 1.89E+02
Tl CFS-L10-1315-T05-C 1 2.26E+02
Tl CFS-L10-1315-T06-C 1 3.55E+02
Tl CFS-L10-1315-T07-C 1 2.68E+02
Tl CFS-L10-1315-T08-C 1 2.03E+02
Tl CFS-L10-1315-T09-C 1 1.80E+02
Tl CFS-L10-1315-M01-A 1 2.30E+00 U1/2
Tl CFS-L10-1315-M02-A 1 2.30E+00 U1/2
Tl CFS-L10-1315-M03-A 1 2.30E+00 U1/2
Tl CFS-L10-1315-M04-A 1 2.30E+00 U1/2
Tl CFS-L10-1315-M05-A 1 2.30E+00 U1/2
Tl CFS-L10-1315-M06-A 1 2.30E+00 U1/2
Tl CFS-L10-1315-M07-A 1 2.30E+00 U1/2
Tl CFS-L10-1315-M08-A 1 2.30E+00 U1/2
Tl CFS-L10-1315-M09-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.10E+00 10.89 4.60 14.60
5.13E+01 2.60 4.60 14.60
4.81E+01 1.59 4.60 14.60 10000 1000
1.83E+02 3.80 4.60 14.60
2.24E+02 1.27 4.60 14.60
3.48E+02 1.34 4.60 14.60
2.53E+02 2.55 4.60 14.60
2.05E+02 4.63 4.60 14.60
1.60E+02 1.98 4.60 14.60
5.36E+00 4.90 4.60 14.60
5.65E+01 2.69 4.60 14.60
4.91E+01 4.00 4.60 14.60 10000 1000
1.91E+02 1.19 4.60 14.60
2.19E+02 2.69 4.60 14.60
3.48E+02 2.08 4.60 14.60
2.54E+02 3.74 4.60 14.60
2.07E+02 2.42 4.60 14.60
1.71E+02 4.02 4.60 14.60
5.86E+00 11.65 4.60 14.60
5.14E+01 5.57 4.60 14.60
5.27E+01 4.25 4.60 14.60 10000 1000
1.89E+02 1.25 4.60 14.60
2.26E+02 1.87 4.60 14.60
3.55E+02 2.44 4.60 14.60
2.68E+02 2.17 4.60 14.60
2.03E+02 0.43 4.60 14.60
1.80E+02 3.03 4.60 14.60
2.30E+00 31.71 4.60 14.60
2.30E+00 20.91 4.60 14.60
2.30E+00 61.87 4.60 14.60
2.30E+00 44.22 4.60 14.60
2.30E+00 74.07 4.60 14.60
2.30E+00 35.08 4.60 14.60
2.30E+00 48.95 4.60 14.60
2.30E+00 4.05 4.60 14.60
2.30E+00 22.78 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.82E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-899
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ti CFS-L10-1315-T01-A 1 1.00E+00 U1/2
Ti CFS-L10-1315-T02-A 1 1.00E+00 U1/2
Ti CFS-L10-1315-T03-A 1 1.00E+00 U1/2
Ti CFS-L10-1315-T04-A 1 1.00E+00 U1/2
Ti CFS-L10-1315-T05-A 1 1.00E+00 U1/2
Ti CFS-L10-1315-T06-A 1 1.00E+00 U1/2
Ti CFS-L10-1315-T07-A 1 1.00E+00 U1/2
Ti CFS-L10-1315-T08-A 1 1.00E+00 U1/2
Ti CFS-L10-1315-T09-A 1 1.00E+00 U1/2
Ti CFS-L10-1315-T01-B 1 1.00E+00 U1/2
Ti CFS-L10-1315-T02-B 1 1.00E+00 U1/2
Ti CFS-L10-1315-T03-B 1 1.00E+00 U1/2
Ti CFS-L10-1315-T04-B 1 1.00E+00 U1/2
Ti CFS-L10-1315-T05-B 1 1.00E+00 U1/2
Ti CFS-L10-1315-T06-B 1 1.00E+00 U1/2
Ti CFS-L10-1315-T07-B 1 1.00E+00 U1/2
Ti CFS-L10-1315-T08-B 1 1.00E+00 U1/2
Ti CFS-L10-1315-T09-B 1 1.00E+00 U1/2
Ti CFS-L10-1315-T01-C 1 1.00E+00 U1/2
Ti CFS-L10-1315-T02-C 1 1.00E+00 U1/2
Ti CFS-L10-1315-T03-C 1 1.00E+00 U1/2
Ti CFS-L10-1315-T04-C 1 1.00E+00 U1/2
Ti CFS-L10-1315-T05-C 1 1.00E+00 U1/2
Ti CFS-L10-1315-T06-C 1 1.00E+00 U1/2
Ti CFS-L10-1315-T07-C 1 1.00E+00 U1/2
Ti CFS-L10-1315-T08-C 1 1.00E+00 U1/2
Ti CFS-L10-1315-T09-C 1 1.00E+00 U1/2
Ti CFS-L10-1315-M01-A 1 1.00E+00 U1/2
Ti CFS-L10-1315-M02-A 1 1.00E+00 U1/2
Ti CFS-L10-1315-M03-A 1 1.00E+00 U1/2
Ti CFS-L10-1315-M04-A 1 1.00E+00 U1/2
Ti CFS-L10-1315-M05-A 1 1.00E+00 U1/2
Ti CFS-L10-1315-M06-A 1 1.00E+00 U1/2
Ti CFS-L10-1315-M07-A 1 1.00E+00 U1/2
Ti CFS-L10-1315-M08-A 1 1.00E+00 U1/2
Ti CFS-L10-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 19.99 2.00 6.40
1.00E+00 29.44 2.00 6.40
1.00E+00 53.57 2.00 6.40 10000 1000
1.00E+00 53.69 2.00 6.40
1.00E+00 27.48 2.00 6.40
1.00E+00 16.76 2.00 6.40
1.00E+00 15.19 2.00 6.40
1.00E+00 31.58 2.00 6.40
1.00E+00 40.40 2.00 6.40
1.00E+00 62.86 2.00 6.40
1.00E+00 79.31 2.00 6.40
1.00E+00 23.21 2.00 6.40 10000 1000
1.00E+00 52.97 2.00 6.40
1.00E+00 33.55 2.00 6.40
1.00E+00 40.23 2.00 6.40
1.00E+00 29.63 2.00 6.40
1.00E+00 32.56 2.00 6.40
1.00E+00 47.33 2.00 6.40
1.00E+00 30.64 2.00 6.40
1.00E+00 49.11 2.00 6.40
1.00E+00 51.59 2.00 6.40 10000 1000
1.00E+00 15.97 2.00 6.40
1.00E+00 48.66 2.00 6.40
1.00E+00 51.82 2.00 6.40
1.00E+00 20.20 2.00 6.40
1.00E+00 47.61 2.00 6.40
1.00E+00 71.33 2.00 6.40
1.00E+00 7.32 2.00 6.40
1.00E+00 20.39 2.00 6.40
1.00E+00 8.13 2.00 6.40
1.00E+00 34.41 2.00 6.40
1.00E+00 16.13 2.00 6.40
1.00E+00 25.35 2.00 6.40
1.00E+00 23.49 2.00 6.40
1.00E+00 27.68 2.00 6.40
1.00E+00 44.21 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.00E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.54E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.86E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-900
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
V CFS-L10-1315-T01-A 1 2.09E+00 E
V CFS-L10-1315-T02-A 1 3.14E+00 E
V CFS-L10-1315-T03-A 1 3.16E+00 E
V CFS-L10-1315-T04-A 1 7.38E+00
V CFS-L10-1315-T05-A 1 7.26E+00
V CFS-L10-1315-T06-A 1 1.12E+01
V CFS-L10-1315-T07-A 1 9.18E+00
V CFS-L10-1315-T08-A 1 6.15E+00
V CFS-L10-1315-T09-A 1 5.13E+00
V CFS-L10-1315-T01-B 1 1.67E+00 E
V CFS-L10-1315-T02-B 1 3.33E+00 E
V CFS-L10-1315-T03-B 1 2.68E+00 E
V CFS-L10-1315-T04-B 1 6.25E+00
V CFS-L10-1315-T05-B 1 6.47E+00
V CFS-L10-1315-T06-B 1 9.54E+00
V CFS-L10-1315-T07-B 1 8.05E+00
V CFS-L10-1315-T08-B 1 6.94E+00
V CFS-L10-1315-T09-B 1 6.10E+00
V CFS-L10-1315-T01-C 1 1.85E+00 E
V CFS-L10-1315-T02-C 1 3.88E+00 E
V CFS-L10-1315-T03-C 1 3.43E+00 E
V CFS-L10-1315-T04-C 1 6.72E+00
V CFS-L10-1315-T05-C 1 7.86E+00
V CFS-L10-1315-T06-C 1 1.08E+01
V CFS-L10-1315-T07-C 1 8.87E+00
V CFS-L10-1315-T08-C 1 7.25E+00
V CFS-L10-1315-T09-C 1 6.38E+00
V CFS-L10-1315-M01-A 1 7.50E-01 U1/2
V CFS-L10-1315-M02-A 1 7.50E-01 U1/2
V CFS-L10-1315-M03-A 1 7.50E-01 U1/2
V CFS-L10-1315-M04-A 1 7.50E-01 U1/2
V CFS-L10-1315-M05-A 1 7.50E-01 U1/2
V CFS-L10-1315-M06-A 1 7.50E-01 U1/2
V CFS-L10-1315-M07-A 1 7.50E-01 U1/2
V CFS-L10-1315-M08-A 1 7.50E-01 U1/2
V CFS-L10-1315-M09-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.09E+00 21.76 1.50 4.77
3.14E+00 12.37 1.50 4.77
3.16E+00 24.10 1.50 4.77 10000 1000
7.38E+00 5.32 1.50 4.77
7.26E+00 4.89 1.50 4.77
1.12E+01 4.07 1.50 4.77
9.18E+00 2.69 1.50 4.77
6.15E+00 1.57 1.50 4.77
5.13E+00 7.33 1.50 4.77
1.67E+00 6.71 1.50 4.77
3.33E+00 12.51 1.50 4.77
2.68E+00 15.26 1.50 4.77 10000 1000
6.25E+00 8.77 1.50 4.77
6.47E+00 1.98 1.50 4.77
9.54E+00 3.52 1.50 4.77
8.05E+00 8.95 1.50 4.77
6.94E+00 1.86 1.50 4.77
6.10E+00 2.35 1.50 4.77
1.85E+00 8.35 1.50 4.77
3.88E+00 13.84 1.50 4.77
3.43E+00 19.49 1.50 4.77 10000 1000
6.72E+00 7.81 1.50 4.77
7.86E+00 1.29 1.50 4.77
1.08E+01 8.88 1.50 4.77
8.87E+00 1.55 1.50 4.77
7.25E+00 7.14 1.50 4.77
6.38E+00 11.93 1.50 4.77
7.50E-01 28.67 1.50 4.77
7.50E-01 31.35 1.50 4.77
7.50E-01 21.88 1.50 4.77
7.50E-01 42.07 1.50 4.77
7.50E-01 21.73 1.50 4.77
7.50E-01 39.86 1.50 4.77
7.50E-01 25.09 1.50 4.77
7.50E-01 15.34 1.50 4.77
7.50E-01 176.10 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.67E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.21E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.64E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L1 01 31 5 CFS
1-901
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Zn CFS-L10-1315-T01-A 1 3.97E+02
Zn CFS-L10-1315-T02-A 1 1.76E+03
Zn CFS-L10-1315-T03-A 1 1.69E+03
Zn CFS-L10-1315-T04-A 1 5.68E+03
Zn CFS-L10-1315-T05-A 1 6.99E+03
Zn CFS-L10-1315-T06-A 1 1.02E+04
Zn CFS-L10-1315-T07-A 1 8.59E+03
Zn CFS-L10-1315-T08-A 1 5.85E+03
Zn CFS-L10-1315-T09-A 1 5.45E+03
Zn CFS-L10-1315-T01-B 1 3.16E+02
Zn CFS-L10-1315-T02-B 1 1.44E+03
Zn CFS-L10-1315-T03-B 1 1.45E+03
Zn CFS-L10-1315-T04-B 1 5.04E+03
Zn CFS-L10-1315-T05-B 1 6.09E+03
Zn CFS-L10-1315-T06-B 1 9.54E+03
Zn CFS-L10-1315-T07-B 1 8.29E+03
Zn CFS-L10-1315-T08-B 1 5.88E+03
Zn CFS-L10-1315-T09-B 1 5.56E+03
Zn CFS-L10-1315-T01-C 1 3.07E+02
Zn CFS-L10-1315-T02-C 1 1.66E+03
Zn CFS-L10-1315-T03-C 1 1.74E+03
Zn CFS-L10-1315-T04-C 1 5.75E+03
Zn CFS-L10-1315-T05-C 1 6.97E+03
Zn CFS-L10-1315-T06-C 1 1.06E+04
Zn CFS-L10-1315-T07-C 1 9.10E+03
Zn CFS-L10-1315-T08-C 1 5.97E+03
Zn CFS-L10-1315-T09-C 1 5.57E+03
Zn CFS-L10-1315-M01-A 1 5.00E-01 U1/2
Zn CFS-L10-1315-M02-A 1 5.00E-01 U1/2
Zn CFS-L10-1315-M03-A 1 5.00E-01 U1/2
Zn CFS-L10-1315-M04-A 1 5.00E-01 U1/2
Zn CFS-L10-1315-M05-A 1 5.00E-01 U1/2
Zn CFS-L10-1315-M06-A 1 5.00E-01 U1/2
Zn CFS-L10-1315-M07-A 1 5.00E-01 U1/2
Zn CFS-L10-1315-M08-A 1 5.00E-01 U1/2
Zn CFS-L10-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.97E+02 1.02 1.00 3.18
1.76E+03 1.58 1.00 3.18
1.69E+03 2.32 1.00 3.18 10000 1000
5.68E+03 1.20 1.00 3.18
6.99E+03 1.63 1.00 3.18
1.02E+04 2.15 1.00 3.18
8.59E+03 1.52 1.00 3.18
5.85E+03 0.94 1.00 3.18
5.45E+03 0.75 1.00 3.18
3.16E+02 1.95 1.00 3.18
1.44E+03 4.81 1.00 3.18
1.45E+03 0.25 1.00 3.18 10000 1000
5.04E+03 0.77 1.00 3.18
6.09E+03 3.06 1.00 3.18
9.54E+03 0.61 1.00 3.18
8.29E+03 0.13 1.00 3.18
5.88E+03 1.53 1.00 3.18
5.56E+03 1.45 1.00 3.18
3.07E+02 1.68 1.00 3.18
1.66E+03 1.60 1.00 3.18
1.74E+03 1.49 1.00 3.18 10000 1000
5.75E+03 1.60 1.00 3.18
6.97E+03 1.76 1.00 3.18
1.06E+04 2.25 1.00 3.18
9.10E+03 1.71 1.00 3.18
5.97E+03 0.82 1.00 3.18
5.57E+03 0.57 1.00 3.18
5.00E-01 4.96 1.00 3.18
5.00E-01 4.89 1.00 3.18
5.00E-01 3.56 1.00 3.18
5.00E-01 5.87 1.00 3.18
5.00E-01 1.01 1.00 3.18
5.00E-01 6.51 1.00 3.18
5.00E-01 2.23 1.00 3.18
5.00E-01 2.42 1.00 3.18
5.00E-01 3.53 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.61E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.41E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.68E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
8/19/11 3:12 PM EPA Interlab L10 1315 CFS
8/19/11 3:14 PM EPA Interlab L10 1315 CFS
8/19/11 3:16 PM EPA Interlab L10 1315 CFS
8/19/11 3:17 PM EPA Interlab L10 1315 CFS
8/19/11 3:19 PM EPA Interlab L10 1315 CFS
8/19/11 3:21 PM EPA Interlab L10 1315 CFS
8/19/11 3:22 PM EPA Interlab L10 1315 CFS
8/19/11 3:24 PM EPA Interlab L10 1315 CFS
8/19/11 3:26 PM EPA Interlab L10 1315 CFS
8/19/11 3:36 PM EPA Interlab L10 1315 CFS
8/19/11 3:37 PM EPA Interlab L10 1315 CFS
8/19/11 3:39 PM EPA Interlab L10 1315 CFS
8/19/11 3:41 PM EPA Interlab L10 1315 CFS
8/19/11 3:42 PM EPA Interlab L10 1315 CFS
8/19/11 3:44 PM EPA Interlab L10 1315 CFS
8/19/11 3:46 PM EPA Interlab L10 1315 CFS
8/19/11 3:47 PM EPA Interlab L10 1315 CFS
8/19/11 3:49 PM EPA Interlab L10 1315 CFS
8/19/11 3:50 PM EPA Interlab L10 1315 CFS
8/19/11 3:52 PM EPA Interlab L10 1315 CFS
8/19/11 3:54 PM EPA Interlab L10 1315 CFS
8/19/11 3:55 PM EPA Interlab L10 1315 CFS
8/19/11 3:57 PM EPA Interlab L10 1315 CFS
8/19/11 3:59 PM EPA Interlab L10 1315 CFS
8/19/11 4:00 PM EPA Interlab L10 1315 CFS
8/19/11 4:02 PM EPA Interlab L10 1315 CFS
8/19/11 4:04 PM EPA Interlab L10 1315 CFS
8/19/11 2:58 PM EPA Interlab L10 1315 CFS
8/19/11 2:59 PM EPA Interlab L10 1315 CFS
8/19/11 3:01 PM EPA Interlab L10 1315 CFS
8/19/11 3:03 PM EPA Interlab L10 1315 CFS
8/19/11 3:04 PM EPA Interlab L10 1315 CFS
8/19/11 3:06 PM EPA Interlab L10 1315 CFS
8/19/11 3:08 PM EPA Interlab L10 1315 CFS
8/19/11 3:09 PM EPA Interlab L10 1315 CFS
8/19/11 3:11 PM EPA Interlab L10 1315 CFS
1-902
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1315:
Element Sample ID
Al CFS-L11-1315-T01-A
Al CFS-L11-1315-T02-A
Al CFS-L11-1315-T03-A
Al CFS-L11-1315-T04-A
Al CFS-L11-1315-T05-A
Al CFS-L11-1315-T06-A
Al CFS-L11-1315-T07-A
Al CFS-L11-1315-T08-A
Al CFS-L11-1315-T09-A
Al CFS-L11-1315-T01-B
Al CFS-L11-1315-T02-B
Al CFS-L11-1315-T03-B
Al CFS-L11-1315-T04-B
Al CFS-L11-1315-T05-B
Al CFS-L11-1315-T06-B
Al CFS-L11-1315-T07-B
Al CFS-L11-1315-T08-B
Al CFS-L11-1315-T09-B
Al CFS-L11-1315-T01-C
Al CFS-L11-1315-T02-C
Al CFS-L11-1315-T03-C
Al CFS-L11-1315-T04-C
Al CFS-L11-1315-T05-C
Al CFS-L11-1315-T06-C
Al CFS-L11-1315-T07-C
Al CFS-L11-1315-T08-C
Al CFS-L11-1315-T09-C
Al CFS-L11-1315-M01-A
Al CFS-L11-1315-M02-A
Al CFS-L11-1315-M03-A
Al CFS-L11-1315-M04-A
Al CFS-L11-1315-M05-A
Al CFS-L11-1315-M06-A
Al CFS-L11-1315-M07-A
Al CFS-L11-1315-M08-A
Al CFS-L11-1315-M09-A
Dilution Sample
Factor Cone. Qualifier
I ug/L I
1 1.76E+01
1 2.60E+01
1 3.84E+01
1 5.44E+01
1 4.40E+01
1 4.18E+01
1 2.76E+01
1 4.13E+01
1 3.71 E+01
1 1.55E+01
1 2. 41 E+01
1 3.71 E+01
1 4.75E+01
1 4.42E+01
1 4.57E+01
1 4.52E+01
1 2.96E+01
1 3.96E+01
1 1.62E+01
1 2.31 E+01
1 2.91 E+01
1 3.42E+01
1 4.34E+01
1 3.84E+01
1 4.52E+01
1 2.83E+01
1 4.16E+01
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.76E+01 1.24 1.00 3.18
2.60E+01 1.60 1.00 3.18
3.84E+01 1.61 1.00 3.18 10000 1000
5.44E+01 2.35 1.00 3.18
4.40E+01 1.77 1.00 3.18
4.18E+01 7.35 1.00 3.18
2.76E+01 10.96 1.00 3.18
4.13E+01 5.43 1.00 3.18
3.71E+01 5.55 1.00 3.18
1.55E+01 3.24 1.00 3.18
2.41E+01 2.81 1.00 3.18
3.71E+01 1.56 1.00 3.18 10000 1000
4.75E+01 1.48 1.00 3.18
4.42E+01 4.39 1.00 3.18
4.57E+01 6.30 1.00 3.18
4.52E+01 6.18 1.00 3.18
2.96E+01 3.08 1.00 3.18
3.96E+01 2.11 1.00 3.18
1.62E+01 9.72 1.00 3.18
2.31E+01 1.70 1.00 3.18
2.91E+01 8.85 1.00 3.18 10000 1000
3.42E+01 3.01 1.00 3.18
4.34E+01 6.22 1.00 3.18
3.84E+01 0.84 1.00 3.18
4.52E+01 4.73 1.00 3.18
2.83E+01 6.84 1.00 3.18
4.16E+01 6.66 1.00 3.18
5.00E-01 11.60 1.00 3.18
5.00E-01 1.68 1.00 3.18
5.00E-01 7.69 1.00 3.18
5.00E-01 5.24 1.00 3.18
5.00E-01 2.57 1.00 3.18
5.00E-01 4.76 1.00 3.18
5.00E-01 6.03 1.00 3.18
5.00E-01 10.13 1.00 3.18
5.00E-01 9.39 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.76E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.47E+02 91 %VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.65E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA Interlab L1 1 1315CFS
9/16/11 1 1:30 AM EPA Interlab L11 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 1 1:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 11:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 1 1:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 11:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 1 1:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 11:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 1 1:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315 CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L11 1315 CFS
9/16/11 12:11 PM EPA Interlab L11 1315CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12 AM EPA Interlab L11 1315CFS
9/16/11 11:13 AM EPA Interlab L11 1315CFS
9/16/11 11:15 AM EPA Interlab L11 1315CFS
9/16/11 11:17 AM EPA Interlab L11 1315CFS
9/16/11 11:18 AM EPA Interlab L11 1315CFS
9/16/11 11:20 AM EPA Interlab L11 1315CFS
9/16/11 1 1:22 AM EPA Interlab L11 1315CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315CFS
9/16/11 11:25 AM EPA Interlab L11 1315CFS
1-903
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Sb CFS-L11-1315-T01-A 1 8.40E+00 E
Sb CFS-L11-1315-T02-A 1 9.30E+00 E
Sb CFS-L11-1315-T03-A 1 9.45E+00 E
Sb CFS-L11-1315-T04-A 1 1.10E+01 E
Sb CFS-L11-1315-T05-A 1 1.27E+01 E
Sb CFS-L11-1315-T06-A 1 1.11E+01 E
Sb CFS-L11-1315-T07-A 1 8.68E+00 E
Sb CFS-L11-1315-T08-A 1 7.94E+00 E
Sb CFS-L11-1315-T09-A 1 7.85E+00 E
Sb CFS-L11-1315-T01-B 1 9.23E+00 E
Sb CFS-L11-1315-T02-B 1 9.43E+00 E
Sb CFS-L11-1315-T03-B 1 1.08E+01 E
Sb CFS-L11-1315-T04-B 1 1.30E+01 E
Sb CFS-L11-1315-T05-B 1 1.24E+01 E
Sb CFS-L11-1315-T06-B 1 1.01E+01 E
Sb CFS-L11-1315-T07-B 1 8.35E+00 E
Sb CFS-L11-1315-T08-B 1 8.53E+00 E
Sb CFS-L11-1315-T09-B 1 7.73E+00 E
Sb CFS-L11-1315-T01-C 1 9.16E+00 E
Sb CFS-L11-1315-T02-C 1 9.46E+00 E
Sb CFS-L11-1315-T03-C 1 1.04E+01 E
Sb CFS-L11-1315-T04-C 1 1.15E+01 E
Sb CFS-L11-1315-T05-C 1 1.21E+01 E
Sb CFS-L11-1315-T06-C 1 1.50E+01 E
Sb CFS-L11-1315-T07-C 1 1.40E+01 E
Sb CFS-L11-1315-T08-C 1 8.76E+00 E
Sb CFS-L11-1315-T09-C 1 8.47E+00 E
Sb CFS-L11-1315-M01-A 1 3.75E+00 U1/2
Sb CFS-L11-1315-M02-A 1 3.75E+00 U1/2
Sb CFS-L11-1315-M03-A 1 3.75E+00 U1/2
Sb CFS-L11-1315-M04-A 1 3.75E+00 U1/2
Sb CFS-L11-1315-M05-A 1 3.75E+00 U1/2
Sb CFS-L11-1315-M06-A 1 3.75E+00 U1/2
Sb CFS-L11-1315-M07-A 1 3.75E+00 U1/2
Sb CFS-L11-1315-M08-A 1 3.75E+00 U1/2
Sb CFS-L11-1315-M09-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.40E+00 8.49 7.50 23.90
9.30E+00 18.65 7.50 23.90
9.45E+00 20.08 7.50 23.90 10000 1000
1.10E+01 26.72 7.50 23.90
1.27E+01 14.49 7.50 23.90
1.11E+01 5.34 7.50 23.90
8.68E+00 3.31 7.50 23.90
7.94E+00 2.84 7.50 23.90
7.85E+00 13.03 7.50 23.90
9.23E+00 16.50 7.50 23.90
9.43E+00 28.01 7.50 23.90
1.08E+01 9.40 7.50 23.90 10000 1000
1.30E+01 5.36 7.50 23.90
1.24E+01 7.97 7.50 23.90
1.01E+01 11.76 7.50 23.90
8.35E+00 14.24 7.50 23.90
8.53E+00 19.33 7.50 23.90
7.73E+00 2.55 7.50 23.90
9.16E+00 9.58 7.50 23.90
9.46E+00 6.49 7.50 23.90
1.04E+01 10.65 7.50 23.90 10000 1000
1.15E+01 4.56 7.50 23.90
1.21E+01 10.34 7.50 23.90
1.50E+01 16.25 7.50 23.90
1.40E+01 20.26 7.50 23.90
8.76E+00 6.14 7.50 23.90
8.47E+00 11.91 7.50 23.90
3.75E+00 32.71 7.50 23.90
3.75E+00 30.32 7.50 23.90
3.75E+00 8.74 7.50 23.90
3.75E+00 9.51 7.50 23.90
3.75E+00 23.42 7.50 23.90
3.75E+00 18.87 7.50 23.90
3.75E+00 5.98 7.50 23.90
3.75E+00 24.42 7.50 23.90
3.75E+00 10.89 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.09E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.43E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.52E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L11 1315 CFS
9/16/11 12:11 PM EPA Interlab L11 1315 CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12 AM EPA Interlab L11 1315CFS
9/16/11 11:13 AM EPA Interlab L11 1315CFS
9/16/11 11:15 AM EPA Interlab L11 1315CFS
9/16/11 11:17 AM EPA Interlab L11 1315CFS
9/16/11 11:18 AM EPA Interlab L11 1315CFS
9/16/11 11:20 AM EPA Interlab L11 1315CFS
9/16/11 11:22 AM EPA Interlab L11 1315CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315CFS
1-904
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
As CFS-L11-1315-T01-A 1 5.50E+00 U1/2
As CFS-L11-1315-T02-A 1 1.15E+01 E
As CFS-L11-1315-T03-A 1 1.25E+01 E
As CFS-L11-1315-T04-A 1 1.61E+01 E
As CFS-L11-1315-T05-A 1 1.53E+01 E
As CFS-L11-1315-T06-A 1 1.27E+01 E
As CFS-L11-1315-T07-A 1 1.48E+01 E
As CFS-L11-1315-T08-A 1 1.15E+01 E
As CFS-L11-1315-T09-A 1 5.50E+00 U1/2
As CFS-L11-1315-T01-B 1 5.50E+00 U1/2
As CFS-L11-1315-T02-B 1 1.18E+01 E
As CFS-L11-1315-T03-B 1 1.13E+01 E
As CFS-L11-1315-T04-B 1 1.42E+01 E
As CFS-L11-1315-T05-B 1 1.44E+01 E
As CFS-L11-1315-T06-B 1 1.78E+01 E
As CFS-L11-1315-T07-B 1 1.55E+01 E
As CFS-L11-1315-T08-B 1 1.44E+01 E
As CFS-L11-1315-T09-B 1 5.50E+00 U1/2
As CFS-L11-1315-T01-C 1 5.50E+00 U1/2
As CFS-L11-1315-T02-C 1 1.24E+01 E
As CFS-L11-1315-T03-C 1 1.37E+01 E
As CFS-L11-1315-T04-C 1 1.41E+01 E
As CFS-L11-1315-T05-C 1 1.11E+01 E
As CFS-L11-1315-T06-C 1 1.25E+01 E
As CFS-L11-1315-T07-C 1 1.54E+01 E
As CFS-L11-1315-T08-C 1 1.31E+01 E
As CFS-L11-1315-T09-C 1 5.50E+00 U1/2
As CFS-L11-1315-M01-A 1 5.50E+00 U1/2
As CFS-L11-1315-M02-A 1 5.50E+00 U1/2
As CFS-L11-1315-M03-A 1 5.50E+00 U1/2
As CFS-L11-1315-M04-A 1 5.50E+00 U1/2
As CFS-L11-1315-M05-A 1 5.50E+00 U1/2
As CFS-L11-1315-M06-A 1 5.50E+00 U1/2
As CFS-L11-1315-M07-A 1 5.50E+00 U1/2
As CFS-L11-1315-M08-A 1 5.50E+00 U1/2
As CFS-L11-1315-M09-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.50E+00 51.92 11.00 35.00
1.15E+01 38.08 11.00 35.00
1.25E+01 17.75 11.00 35.00 10000 1000
1.61E+01 14.74 11.00 35.00
1.53E+01 31.94 11.00 35.00
1.27E+01 14.08 11.00 35.00
1.48E+01 10.80 11.00 35.00
1.15E+01 20.74 11.00 35.00
5.50E+00 14.63 11.00 35.00
5.50E+00 53.18 11.00 35.00
1.18E+01 21.10 11.00 35.00
1.13E+01 32.61 11.00 35.00 10000 1000
1.42E+01 2.58 11.00 35.00
1.44E+01 27.85 11.00 35.00
1.78E+01 14.11 11.00 35.00
1.55E+01 28.58 11.00 35.00
1.44E+01 35.63 11.00 35.00
5.50E+00 30.17 11.00 35.00
5.50E+00 32.52 11.00 35.00
1.24E+01 29.25 11.00 35.00
1.37E+01 33.01 11.00 35.00 10000 1000
1.41E+01 35.68 11.00 35.00
1.11E+01 20.94 11.00 35.00
1.25E+01 27.06 11.00 35.00
1.54E+01 33.22 11.00 35.00
1.31E+01 13.76 11.00 35.00
5.50E+00 8.88 11.00 35.00
5.50E+00 21.22 11.00 35.00
5.50E+00 27.49 11.00 35.00
5.50E+00 44.02 11.00 35.00
5.50E+00 19.61 11.00 35.00
5.50E+00 15.22 11.00 35.00
5.50E+00 31.46 11.00 35.00
5.50E+00 21.49 11.00 35.00
5.50E+00 56.35 11.00 35.00
5.50E+00 32.73 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.68E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.58E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.31 E+02 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315 CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L11 1315 CFS
9/16/11 12:11 PM EPA Interlab L11 1315 CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12 AM EPA Interlab L11 1315CFS
9/16/11 11:13 AM EPA Interlab L11 1315CFS
9/16/11 11:15 AM EPA Interlab L11 1315CFS
9/16/11 11:17 AM EPA Interlab L11 1315CFS
9/16/11 11:18 AM EPA Interlab L11 1315CFS
9/16/11 11:20 AM EPA Interlab L11 1315CFS
9/16/11 11:22 AM EPA Interlab L11 1315CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315CFS
1-905
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
B CFS-L11-1315-T01-A 1 1.84E+01
B CFS-L11-1315-T02-A 1 4.48E+01
B CFS-L11-1315-T03-A 1 3.57E+01
B CFS-L11-1315-T04-A 1 1.08E+02
B CFS-L11-1315-T05-A 1 1.15E+02
B CFS-L11-1315-T06-A 1 1.20E+02
B CFS-L11-1315-T07-A 1 1.73E+02
B CFS-L11-1315-T08-A 1 1.05E+02
B CFS-L11-1315-T09-A 1 1.13E+02
B CFS-L11-1315-T01-B 1 1.48E+01
B CFS-L11-1315-T02-B 1 4.41 E+01
B CFS-L11-1315-T03-B 1 3.46E+01
B CFS-L11-1315-T04-B 1 1.00E+02
B CFS-L11-1315-T05-B 1 1.17E+02
B CFS-L11-1315-T06-B 1 1.20E+02
B CFS-L11-1315-T07-B 1 1.91E+02
B CFS-L11-1315-T08-B 1 9.81 E+01
B CFS-L11-1315-T09-B 1 1.09E+02
B CFS-L11-1315-T01-C 1 1.74E+01
B CFS-L11-1315-T02-C 1 3.64E+01
B CFS-L11-1315-T03-C 1 3.63E+01
B CFS-L11-1315-T04-C 1 1.04E+02
B CFS-L11-1315-T05-C 1 1.18E+02
B CFS-L11-1315-T06-C 1 1.28E+02
B CFS-L11-1315-T07-C 1 1.74E+02
B CFS-L11-1315-T08-C 1 9.69E+01
B CFS-L11-1315-T09-C 1 1.05E+02
B CFS-L11-1315-M01-A 1 5.00E-01 U1/2
B CFS-L11-1315-M02-A 1 5.00E-01 U1/2
B CFS-L11-1315-M03-A 1 5.00E-01 U1/2
B CFS-L11-1315-M04-A 1 5.00E-01 U1/2
B CFS-L11-1315-M05-A 1 5.00E-01 U1/2
B CFS-L11-1315-M06-A 1 5.00E-01 U1/2
B CFS-L11-1315-M07-A 1 5.00E-01 U1/2
B CFS-L11-1315-M08-A 1 5.00E-01 U1/2
B CFS-L11-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.84E+01 4.16 1.00 3.18
4.48E+01 1.32 1.00 3.18
3.57E+01 2.14 1.00 3.18 10000 1000
1.08E+02 2.39 1.00 3.18
1.15E+02 1.59 1.00 3.18
1.20E+02 3.98 1.00 3.18
1.73E+02 1.55 1.00 3.18
1.05E+02 4.33 1.00 3.18
1.13E+02 1.32 1.00 3.18
1.48E+01 1.77 1.00 3.18
4.41E+01 1.97 1.00 3.18
3.46E+01 1.35 1.00 3.18 10000 1000
1.00E+02 2.97 1.00 3.18
1.17E+02 3.98 1.00 3.18
1.20E+02 1.28 1.00 3.18
1.91E+02 2.20 1.00 3.18
9.81E+01 3.21 1.00 3.18
1.09E+02 2.64 1.00 3.18
1.74E+01 1.49 1.00 3.18
3.64E+01 2.22 1.00 3.18
3.63E+01 0.33 1.00 3.18 10000 1000
1.04E+02 3.15 1.00 3.18
1.18E+02 5.35 1.00 3.18
1.28E+02 3.89 1.00 3.18
1.74E+02 1.46 1.00 3.18
9.69E+01 0.61 1.00 3.18
1.05E+02 1.58 1.00 3.18
5.00E-01 2.13 1.00 3.18
5.00E-01 2.30 1.00 3.18
5.00E-01 2.21 1.00 3.18
5.00E-01 1.88 1.00 3.18
5.00E-01 1.23 1.00 3.18
5.00E-01 4.20 1.00 3.18
5.00E-01 0.35 1.00 3.18
5.00E-01 1.11 1.00 3.18
5.00E-01 0.58 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.65E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.76E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.39E+02 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315 CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L11 1315 CFS
9/16/11 12:11 PM EPA Interlab L11 1315CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12 AM EPA Interlab L11 1315CFS
9/16/11 11:13 AM EPA Interlab L11 1315CFS
9/16/11 11:15 AM EPA Interlab L11 1315CFS
9/16/11 11:17 AM EPA Interlab L11 1315CFS
9/16/11 11:18 AM EPA Interlab L11 1315CFS
9/16/11 11:20 AM EPA Interlab L11 1315CFS
9/16/11 11:22 AM EPA Interlab L11 1315CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315CFS
1-906
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Ba CFS-L11-1315-T01-A 1 1.70E+01
Ba CFS-L11-1315-T02-A 1 1.60E+01
Ba CFS-L11-1315-T03-A 1 2.45E+01
Ba CFS-L11-1315-T04-A 1 3.02E+01
Ba CFS-L11-1315-T05-A 1 3.24E+01
Ba CFS-L11-1315-T06-A 1 3.17E+01
Ba CFS-L11-1315-T07-A 1 2.97E+01
Ba CFS-L11-1315-T08-A 1 2.24E+01
Ba CFS-L11-1315-T09-A 1 3.17E+01
Ba CFS-L11-1315-T01-B 1 1.75E+01
Ba CFS-L11-1315-T02-B 1 1.79E+01
Ba CFS-L11-1315-T03-B 1 2.44E+01
Ba CFS-L11-1315-T04-B 1 3.27E+01
Ba CFS-L11-1315-T05-B 1 2.92E+01
Ba CFS-L11-1315-T06-B 1 3.08E+01
Ba CFS-L11-1315-T07-B 1 2.60E+01
Ba CFS-L11-1315-T08-B 1 2.27E+01
Ba CFS-L11-1315-T09-B 1 2.92E+01
Ba CFS-L11-1315-T01-C 1 1.76E+01
Ba CFS-L11-1315-T02-C 1 2.09E+01
Ba CFS-L11-1315-T03-C 1 2.44E+01
Ba CFS-L11-1315-T04-C 1 2.81 E+01
Ba CFS-L11-1315-T05-C 1 3.17E+01
Ba CFS-L11-1315-T06-C 1 2.93E+01
Ba CFS-L11-1315-T07-C 1 2.61 E+01
Ba CFS-L11-1315-T08-C 1 2.35E+01
Ba CFS-L11-1315-T09-C 1 3.17E+01
Ba CFS-L11-1315-M01-A 1 5.00E-01 U1/2
Ba CFS-L11-1315-M02-A 1 5.00E-01 U1/2
Ba CFS-L11-1315-M03-A 1 5.00E-01 U1/2
Ba CFS-L11-1315-M04-A 1 5.00E-01 U1/2
Ba CFS-L11-1315-M05-A 1 5.00E-01 U1/2
Ba CFS-L11-1315-M06-A 1 5.00E-01 U1/2
Ba CFS-L11-1315-M07-A 1 5.00E-01 U1/2
Ba CFS-L11-1315-M08-A 1 5.00E-01 U1/2
Ba CFS-L11-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.70E+01 2.46 1.00 3.18
1.60E+01 2.32 1.00 3.18
2.45E+01 1.14 1.00 3.18 10000 1000
3.02E+01 13.95 1.00 3.18
3.24E+01 8.59 1.00 3.18
3.17E+01 3.98 1.00 3.18
2.97E+01 1.55 1.00 3.18
2.24E+01 4.33 1.00 3.18
3.17E+01 1.32 1.00 3.18
1.75E+01 1.77 1.00 3.18
1.79E+01 1.97 1.00 3.18
2.44E+01 1.35 1.00 3.18 10000 1000
3.27E+01 2.97 1.00 3.18
2.92E+01 3.98 1.00 3.18
3.08E+01 1.28 1.00 3.18
2.60E+01 2.20 1.00 3.18
2.27E+01 3.21 1.00 3.18
2.92E+01 2.64 1.00 3.18
1.76E+01 1.49 1.00 3.18
2.09E+01 2.22 1.00 3.18
2.44E+01 0.33 1.00 3.18 10000 1000
2.81E+01 3.15 1.00 3.18
3.17E+01 5.35 1.00 3.18
2.93E+01 3.89 1.00 3.18
2.61E+01 1.46 1.00 3.18
2.35E+01 0.61 1.00 3.18
3.17E+01 1.58 1.00 3.18
5.00E-01 2.13 1.00 3.18
5.00E-01 2.30 1.00 3.18
5.00E-01 2.21 1.00 3.18
5.00E-01 1.88 1.00 3.18
5.00E-01 1.23 1.00 3.18
5.00E-01 4.20 1.00 3.18
5.00E-01 0.35 1.00 3.18
5.00E-01 1.11 1.00 3.18
5.00E-01 0.58 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.34E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.63E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.67E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315 CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L11 1315 CFS
9/16/11 12:11 PM EPA Interlab L11 1315CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12 AM EPA Interlab L11 1315CFS
9/16/11 11:13 AM EPA Interlab L11 1315CFS
9/16/11 11:15 AM EPA Interlab L11 1315CFS
9/16/11 11:17 AM EPA Interlab L11 1315CFS
9/16/11 11:18 AM EPA Interlab L11 1315CFS
9/16/11 11:20 AM EPA Interlab L11 1315CFS
9/16/11 11:22 AM EPA Interlab L11 1315CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315CFS
1-907
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Be CFS-L11-1315-T01-A 1 9.50E-01 U1/2
Be CFS-L11-1315-T02-A 1 9.50E-01 U1/2
Be CFS-L11-1315-T03-A 1 9.50E-01 U1/2
Be CFS-L11-1315-T04-A 1 9.50E-01 U1/2
Be CFS-L11-1315-T05-A 1 9.50E-01 U1/2
Be CFS-L11-1315-T06-A 1 9.50E-01 U1/2
Be CFS-L11-1315-T07-A 1 9.50E-01 U1/2
Be CFS-L11-1315-T08-A 1 9.50E-01 U1/2
Be CFS-L11-1315-T09-A 1 9.50E-01 U1/2
Be CFS-L11-1315-T01-B 1 9.50E-01 U1/2
Be CFS-L11-1315-T02-B 1 9.50E-01 U1/2
Be CFS-L11-1315-T03-B 1 9.50E-01 U1/2
Be CFS-L11-1315-T04-B 1 9.50E-01 U1/2
Be CFS-L11-1315-T05-B 1 9.50E-01 U1/2
Be CFS-L11-1315-T06-B 1 9.50E-01 U1/2
Be CFS-L11-1315-T07-B 1 9.50E-01 U1/2
Be CFS-L11-1315-T08-B 1 9.50E-01 U1/2
Be CFS-L11-1315-T09-B 1 9.50E-01 U1/2
Be CFS-L11-1315-T01-C 1 9.50E-01 U1/2
Be CFS-L11-1315-T02-C 1 9.50E-01 U1/2
Be CFS-L11-1315-T03-C 1 9.50E-01 U1/2
Be CFS-L11-1315-T04-C 1 9.50E-01 U1/2
Be CFS-L11-1315-T05-C 1 9.50E-01 U1/2
Be CFS-L11-1315-T06-C 1 9.50E-01 U1/2
Be CFS-L11-1315-T07-C 1 9.50E-01 U1/2
Be CFS-L11-1315-T08-C 1 9.50E-01 U1/2
Be CFS-L11-1315-T09-C 1 9.50E-01 U1/2
Be CFS-L11-1315-M01-A 1 9.50E-01 U1/2
Be CFS-L11-1315-M02-A 1 9.50E-01 U1/2
Be CFS-L11-1315-M03-A 1 9.50E-01 U1/2
Be CFS-L11-1315-M04-A 1 9.50E-01 U1/2
Be CFS-L11-1315-M05-A 1 9.50E-01 U1/2
Be CFS-L11-1315-M06-A 1 9.50E-01 U1/2
Be CFS-L11-1315-M07-A 1 9.50E-01 U1/2
Be CFS-L11-1315-M08-A 1 9.50E-01 U1/2
Be CFS-L11-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 9.24 1.90 6.00
9.50E-01 54.52 1.90 6.00
9.50E-01 33.33 1.90 6.00 10000 1000
9.50E-01 11.90 1.90 6.00
9.50E-01 51.00 1.90 6.00
9.50E-01 37.12 1.90 6.00
9.50E-01 16.23 1.90 6.00
9.50E-01 5.96 1.90 6.00
9.50E-01 24.23 1.90 6.00
9.50E-01 42.07 1.90 6.00
9.50E-01 12.11 1.90 6.00
9.50E-01 23.50 1.90 6.00 10000 1000
9.50E-01 13.01 1.90 6.00
9.50E-01 47.85 1.90 6.00
9.50E-01 24.69 1.90 6.00
9.50E-01 36.02 1.90 6.00
9.50E-01 55.72 1.90 6.00
9.50E-01 2.79 1.90 6.00
9.50E-01 7.91 1.90 6.00
9.50E-01 19.33 1.90 6.00
9.50E-01 74.01 1.90 6.00 10000 1000
9.50E-01 33.43 1.90 6.00
9.50E-01 29.83 1.90 6.00
9.50E-01 44.14 1.90 6.00
9.50E-01 38.26 1.90 6.00
9.50E-01 34.35 1.90 6.00
9.50E-01 61.64 1.90 6.00
9.50E-01 36.56 1.90 6.00
9.50E-01 28.55 1.90 6.00
9.50E-01 43.19 1.90 6.00
9.50E-01 69.72 1.90 6.00
9.50E-01 55.25 1.90 6.00
9.50E-01 30.29 1.90 6.00
9.50E-01 18.62 1.90 6.00
9.50E-01 10.37 1.90 6.00
9.50E-01 23.97 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.74E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.73E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.40E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L11 1315 CFS
9/16/11 12:11 PM EPA Interlab L11 1315 CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12 AM EPA Interlab L11 1315CFS
9/16/11 11:13 AM EPA Interlab L11 1315CFS
9/16/11 11:15 AM EPA Interlab L11 1315CFS
9/16/11 11:17 AM EPA Interlab L11 1315CFS
9/16/11 11:18 AM EPA Interlab L11 1315CFS
9/16/11 11:20 AM EPA Interlab L11 1315CFS
9/16/11 11:22 AM EPA Interlab L11 1315CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315CFS
1-908
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualil
1 1 ug/L
Cd CFS-L11-1315-T01-A 1 5.32E+01
Cd CFS-L11-1315-T02-A 1 2.58E+02
Cd CFS-L11-1315-T03-A 1 2.29E+02
Cd CFS-L11-1315-T04-A 1 9.80E+02
Cd CFS-L11-1315-T05-A 1 8.82E+02
Cd CFS-L11-1315-T06-A 1 8.17E+02
Cd CFS-L11-1315-T07-A 1 1.69E+03
Cd CFS-L11-1315-T08-A 1 1.05E+03
Cd CFS-L11-1315-T09-A 1 1.01E+03
Cd CFS-L11-1315-T01-B 1 5.19E+01
Cd CFS-L11-1315-T02-B 1 2.61E+02
Cd CFS-L11-1315-T03-B 1 2.87E+02
Cd CFS-L11-1315-T04-B 1 9.07E+02
Cd CFS-L11-1315-T05-B 1 1.08E+03
Cd CFS-L11-1315-T06-B 1 9.11E+02
Cd CFS-L11-1315-T07-B 1 1.73E+03
Cd CFS-L11-1315-T08-B 1 6.82E+02
Cd CFS-L11-1315-T09-B 1 1.07E+03
Cd CFS-L11-1315-T01-C 1 3.28E+01
Cd CFS-L11-1315-T02-C 1 2.04E+02
Cd CFS-L11-1315-T03-C 1 2.36E+02
Cd CFS-L11-1315-T04-C 1 7.68E+02
Cd CFS-L11-1315-T05-C 1 8.71E+02
Cd CFS-L11-1315-T06-C 1 7.77E+02
Cd CFS-L11-1315-T07-C 1 1.59E+03
Cd CFS-L11-1315-T08-C 1 6.46E+02
Cd CFS-L11-1315-T09-C 1 9.47E+02
Cd CFS-L11-1315-M01-A 1 1.10E+00 U1/2
Cd CFS-L11-1315-M02-A 1 1.10E+00 U1/2
Cd CFS-L11-1315-M03-A 1 1.10E+00 U1/2
Cd CFS-L11-1315-M04-A 1 1.10E+00 U1/2
Cd CFS-L11-1315-M05-A 1 1.10E+00 U1/2
Cd CFS-L11-1315-M06-A 1 1.10E+00 U1/2
Cd CFS-L11-1315-M07-A 1 1.10E+00 U1/2
Cd CFS-L11-1315-M08-A 1 1.10E+00 U1/2
Cd CFS-L11-1315-M09-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
ier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.32E+01 1.64 2.20 7.00
2.58E+02 2.35 2.20 7.00
2.29E+02 1.64 2.20 7.00 10000 1000
9.80E+02 1.56 2.20 7.00
8.82E+02 2.54 2.20 7.00
8.17E+02 2.61 2.20 7.00
1.69E+03 1.27 2.20 7.00
1.05E+03 0.94 2.20 7.00
1.01E+03 0.53 2.20 7.00
5.19E+01 0.10 2.20 7.00
2.61E+02 0.41 2.20 7.00
2.87E+02 2.46 2.20 7.00 10000 1000
9.07E+02 0.69 2.20 7.00
1.08E+03 1.43 2.20 7.00
9.11E+02 1.41 2.20 7.00
1.73E+03 0.98 2.20 7.00
6.82E+02 1.04 2.20 7.00
1.07E+03 2.24 2.20 7.00
3.28E+01 0.36 2.20 7.00
2.04E+02 0.44 2.20 7.00
2.36E+02 0.97 2.20 7.00 10000 1000
7.68E+02 0.53 2.20 7.00
8.71 E+02 0.80 2.20 7.00
7.77E+02 1.34 2.20 7.00
1.59E+03 1.37 2.20 7.00
6.46E+02 0.57 2.20 7.00
9.47E+02 1.33 2.20 7.00
1.10E+00 0.53 2.20 7.00
1.10E+00 0.84 2.20 7.00
1.10E+00 0.81 2.20 7.00
1.10E+00 1.47 2.20 7.00
1.10E+00 0.87 2.20 7.00
1.10E+00 0.77 2.20 7.00
1.10E+00 0.81 2.20 7.00
1.10E+00 1.24 2.20 7.00
1.10E+00 0.41 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.25E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.29E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.26E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315 CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L1 1 1315 CFS
9/16/11 12:11 PM EPA Interlab L1 1 1315 CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12 AM EPA Interlab L11 1315 CFS
9/16/11 11:13 AM EPA Interlab L1 1 1315 CFS
9/16/11 11:15 AM EPA Interlab L1 1 1315 CFS
9/16/11 11:17 AM EPA Interlab L11 1315 CFS
9/16/11 11:18 AM EPA Interlab L1 1 1315 CFS
9/16/11 1 1:20 AM EPA Interlab L11 1315 CFS
9/16/11 1 1:22 AM EPA Interlab L11 1315 CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315 CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315 CFS
1-909
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Ca CFS-L11-1315-T01-A 1 9.87E+03
Ca CFS-L11-1315-T02-A 1 3.64E+04
Ca CFS-L11-1315-T03-A 1 4.24E+04
Ca CFS-L11-1315-T04-A 1 8.55E+04
Ca CFS-L11-1315-T05-A 1 8.13E+04
Ca CFS-L11-1315-T06-A 1 7.61 E+04
Ca CFS-L11-1315-T07-A 1 1.50E+05
Ca CFS-L11-1315-T08-A 1 6.51 E+04
Ca CFS-L11-1315-T09-A 1 1.03E+05
Ca CFS-L11-1315-T01-B 1 9.89E+03
Ca CFS-L11-1315-T02-B 1 3.35E+04
Ca CFS-L11-1315-T03-B 1 4.25E+04
Ca CFS-L11-1315-T04-B 1 7.44E+04
Ca CFS-L11-1315-T05-B 1 8.03E+04
Ca CFS-L11-1315-T06-B 1 7.60E+04
Ca CFS-L11-1315-T07-B 1 1.48E+05
Ca CFS-L11-1315-T08-B 1 6.45E+04
Ca CFS-L11-1315-T09-B 1 1.04E+05
Ca CFS-L11-1315-T01-C 1 9.19E+03
Ca CFS-L11-1315-T02-C 1 3.39E+04
Ca CFS-L11-1315-T03-C 1 4.35E+04
Ca CFS-L11-1315-T04-C 1 7.06E+04
Ca CFS-L11-1315-T05-C 1 8.18E+04
Ca CFS-L11-1315-T06-C 1 7.71E+04
Ca CFS-L11-1315-T07-C 1 1.57E+05
Ca CFS-L11-1315-T08-C 1 6.82E+04
Ca CFS-L11-1315-T09-C 1 1.04E+05
Ca CFS-L11-1315-M01-A 1 3.11E+01
Ca CFS-L11-1315-M02-A 1 4.26E+01
Ca CFS-L11-1315-M03-A 1 4.58E+01
Ca CFS-L11-1315-M04-A 1 4.09E+01
Ca CFS-L11-1315-M05-A 1 2.34E+01
Ca CFS-L11-1315-M06-A 1 3.05E+01
Ca CFS-L11-1315-M07-A 1 2.88E+01
Ca CFS-L11-1315-M08-A 1 1.15E+01
Ca CFS-L11-1315-M09-A 1 1.64E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.87E+03 3.14 2.60 8.30
3.64E+04 3.11 2.60 8.30
4.24E+04 1.72 2.60 8.30 10000 1000
8.55E+04 2.29 2.60 8.30
8.13E+04 4.12 2.60 8.30
7.61 E+04 0.81 2.60 8.30
1.50E+05 1.56 2.60 8.30
6.51 E+04 0.74 2.60 8.30
1.03E+05 0.79 2.60 8.30
9.89E+03 0.22 2.60 8.30
3.35E+04 0.19 2.60 8.30
4.25E+04 2.28 2.60 8.30 10000 1000
7.44E+04 0.81 2.60 8.30
8.03E+04 1.71 2.60 8.30
7.60E+04 1.32 2.60 8.30
1.48E+05 1.20 2.60 8.30
6.45E+04 1.26 2.60 8.30
1.04E+05 2.83 2.60 8.30
9.19E+03 0.21 2.60 8.30
3.39E+04 0.66 2.60 8.30
4.35E+04 1.03 2.60 8.30 10000 1000
7.06E+04 0.33 2.60 8.30
8.18E+04 1.06 2.60 8.30
7.71 E+04 1.29 2.60 8.30
1.57E+05 1.51 2.60 8.30
6.82E+04 0.60 2.60 8.30
1.04E+05 1.48 2.60 8.30
311E+01 0.39 2.60 8.30
4.26E+01 0.83 2.60 8.30
4.58E+01 0.90 2.60 8.30
4.09E+01 1.62 2.60 8.30
2.34E+01 0.78 2.60 8.30
3.05E+01 0.79 2.60 8.30
2.88E+01 0.92 2.60 8.30
1.15E+01 1.20 2.60 8.30
1.64E+01 0.54 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.33E+04 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.35E+04 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.44E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315 CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L1 1 1315 CFS
9/16/11 12:11 PM EPA Interlab L1 1 1315 CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12 AM EPA Interlab L11 1315CFS
9/16/11 11:13 AM EPA Interlab L11 1315CFS
9/16/11 1 1:15 AM EPA Interlab L11 131 5 CFS
9/16/11 11:17 AM EPA Interlab L1 1 1315 CFS
9/16/11 1 1:18 AM EPA Interlab L11 131 5 CFS
9/16/11 1 1:20 AM EPA Interlab L11 1315CFS
9/16/11 1 1:22 AM EPA Interlab L11 1315CFS
9/16/11 11:23 AM EPA Interlab L11 1315CFS
9/16/11 11:25 AM EPA Interlab L11 1315CFS
1-910
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Cr CFS-L11-1315-T01-A 1 6.00E-01 U1/2
Cr CFS-L11-1315-T02-A 1 6.00E-01 U1/2
Cr CFS-L11-1315-T03-A 1 6.00E-01 U1/2
Cr CFS-L11-1315-T04-A 1 6.00E-01 U1/2
Cr CFS-L11-1315-T05-A 1 6.00E-01 U1/2
Cr CFS-L11-1315-T06-A 1 6.00E-01 U1/2
Cr CFS-L11-1315-T07-A 1 6.00E-01 U1/2
Cr CFS-L11-1315-T08-A 1 6.00E-01 U1/2
Cr CFS-L11-1315-T09-A 1 6.00E-01 U1/2
Cr CFS-L11-1315-T01-B 1 6.00E-01 U1/2
Cr CFS-L11-1315-T02-B 1 6.00E-01 U1/2
Cr CFS-L11-1315-T03-B 1 6.00E-01 U1/2
Cr CFS-L11-1315-T04-B 1 6.00E-01 U1/2
Cr CFS-L11-1315-T05-B 1 6.00E-01 U1/2
Cr CFS-L11-1315-T06-B 1 6.00E-01 U1/2
Cr CFS-L11-1315-T07-B 1 6.00E-01 U1/2
Cr CFS-L11-1315-T08-B 1 6.00E-01 U1/2
Cr CFS-L11-1315-T09-B 1 6.00E-01 U1/2
Cr CFS-L11-1315-T01-C 1 6.00E-01 U1/2
Cr CFS-L11-1315-T02-C 1 6.00E-01 U1/2
Cr CFS-L11-1315-T03-C 1 6.00E-01 U1/2
Cr CFS-L11-1315-T04-C 1 6.00E-01 U1/2
Cr CFS-L11-1315-T05-C 1 6.00E-01 U1/2
Cr CFS-L11-1315-T06-C 1 6.00E-01 U1/2
Cr CFS-L11-1315-T07-C 1 6.00E-01 U1/2
Cr CFS-L11-1315-T08-C 1 6.00E-01 U1/2
Cr CFS-L11-1315-T09-C 1 6.00E-01 U1/2
Cr CFS-L11-1315-M01-A 1 6.00E-01 U1/2
Cr CFS-L11-1315-M02-A 1 6.00E-01 U1/2
Cr CFS-L11-1315-M03-A 1 6.00E-01 U1/2
Cr CFS-L11-1315-M04-A 1 6.00E-01 U1/2
Cr CFS-L11-1315-M05-A 1 6.00E-01 U1/2
Cr CFS-L11-1315-M06-A 1 6.00E-01 U1/2
Cr CFS-L11-1315-M07-A 1 6.00E-01 U1/2
Cr CFS-L11-1315-M08-A 1 6.00E-01 U1/2
Cr CFS-L11-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 49.51 1.20 3.82
6.00E-01 78.57 1.20 3.82
6.00E-01 34.26 1.20 3.82 10000 1000
6.00E-01 25.22 1.20 3.82
6.00E-01 34.19 1.20 3.82
6.00E-01 55.11 1.20 3.82
6.00E-01 62.58 1.20 3.82
6.00E-01 64.07 1.20 3.82
6.00E-01 29.55 1.20 3.82
6.00E-01 15.43 1.20 3.82
6.00E-01 31.79 1.20 3.82
6.00E-01 23.63 1.20 3.82 10000 1000
6.00E-01 32.82 1.20 3.82
6.00E-01 33.34 1.20 3.82
6.00E-01 28.59 1.20 3.82
6.00E-01 33.27 1.20 3.82
6.00E-01 35.50 1.20 3.82
6.00E-01 3.46 1.20 3.82
6.00E-01 17.14 1.20 3.82
6.00E-01 24.58 1.20 3.82
6.00E-01 22.24 1.20 3.82 10000 1000
6.00E-01 43.89 1.20 3.82
6.00E-01 51.83 1.20 3.82
6.00E-01 29.19 1.20 3.82
6.00E-01 16.53 1.20 3.82
6.00E-01 73.21 1.20 3.82
6.00E-01 25.17 1.20 3.82
6.00E-01 12.23 1.20 3.82
6.00E-01 40.77 1.20 3.82
6.00E-01 33.32 1.20 3.82
6.00E-01 39.51 1.20 3.82
6.00E-01 89.13 1.20 3.82
6.00E-01 52.30 1.20 3.82
6.00E-01 75.58 1.20 3.82
6.00E-01 47.45 1.20 3.82
6.00E-01 48.73 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.81E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.67E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.43E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L11 1315 CFS
9/16/11 12:11 PM EPA Interlab L11 1315 CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12 AM EPA Interlab L11 1315CFS
9/16/11 11:13 AM EPA Interlab L11 1315CFS
9/16/11 11:15 AM EPA Interlab L11 1315CFS
9/16/11 11:17 AM EPA Interlab L11 1315CFS
9/16/11 11:18 AM EPA Interlab L11 1315CFS
9/16/11 11:20 AM EPA Interlab L11 1315CFS
9/16/11 11:22 AM EPA Interlab L11 1315CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315CFS
1-911
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Co CFS-L11-1315-T01-A 1 2.25E+00 E
Co CFS-L11-1315-T02-A 1 7.17E+00
Co CFS-L11-1315-T03-A 1 8.91 E+00
Co CFS-L11-1315-T04-A 1 3.01 E+01
Co CFS-L11-1315-T05-A 1 2.69E+01
Co CFS-L11-1315-T06-A 1 2.66E+01
Co CFS-L11-1315-T07-A 1 5.32E+01
Co CFS-L11-1315-T08-A 1 3.51 E+01
Co CFS-L11-1315-T09-A 1 3.34E+01
Co CFS-L11-1315-T01-B 1 2.58E+00 E
Co CFS-L11-1315-T02-B 1 7. 61 E+00
Co CFS-L11-1315-T03-B 1 8.66E+00
Co CFS-L11-1315-T04-B 1 3.01 E+01
Co CFS-L11-1315-T05-B 1 3.66E+01
Co CFS-L11-1315-T06-B 1 3.21E+01
Co CFS-L11-1315-T07-B 1 6.37E+01
Co CFS-L11-1315-T08-B 1 2.53E+01
Co CFS-L11-1315-T09-B 1 3.88E+01
Co CFS-L11-1315-T01-C 1 2.06E+00 E
Co CFS-L11-1315-T02-C 1 5.03E+00 E
Co CFS-L11-1315-T03-C 1 6.15E+00
Co CFS-L11-1315-T04-C 1 2.18E+01
Co CFS-L11-1315-T05-C 1 2. 51 E+01
Co CFS-L11-1315-T06-C 1 2.26E+01
Co CFS-L11-1315-T07-C 1 5.00E+01
Co CFS-L11-1315-T08-C 1 2. 11 E+01
Co CFS-L11-1315-T09-C 1 3.17E+01
Co CFS-L11-1315-M01-A 1 9.00E-01 U1/2
Co CFS-L11-1315-M02-A 1 9.00E-01 U1/2
Co CFS-L11-1315-M03-A 1 9.00E-01 U1/2
Co CFS-L11-1315-M04-A 1 9.00E-01 U1/2
Co CFS-L11-1315-M05-A 1 9.00E-01 U1/2
Co CFS-L11-1315-M06-A 1 9.00E-01 U1/2
Co CFS-L11-1315-M07-A 1 9.00E-01 U1/2
Co CFS-L11-1315-M08-A 1 9.00E-01 U1/2
Co CFS-L11-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.25E+00 4.70 1.80 5.72
7.17E+00 3.86 1.80 5.72
8.91E+00 2.62 1.80 5.72 10000 1000
3.01 E+01 4.35 1.80 5.72
2.69E+01 9.20 1.80 5.72
2.66E+01 3.95 1.80 5.72
5.32E+01 13.58 1.80 5.72
3.51 E+01 4.84 1.80 5.72
3.34E+01 2.30 1.80 5.72
2.58E+00 6.41 1.80 5.72
7. 61 E+00 9.98 1.80 5.72
8.66E+00 3.44 1.80 5.72 10000 1000
3.01 E+01 2.91 1.80 5.72
3.66E+01 4.13 1.80 5.72
3.21 E+01 0.25 1.80 5.72
6.37E+01 4.55 1.80 5.72
2.53E+01 2.35 1.80 5.72
3.88E+01 3.42 1.80 5.72
2.06E+00 29.32 1.80 5.72
5.03E+00 9.64 1.80 5.72
6.15E+00 2.74 1.80 5.72 10000 1000
2.18E+01 1.84 1.80 5.72
2. 51 E+01 2.29 1.80 5.72
2.26E+01 2.39 1.80 5.72
5.00E+01 3.30 1.80 5.72
2. 11 E+01 1.88 1.80 5.72
317E+01 4.63 1.80 5.72
9.00E-01 37.67 1.80 5.72
9.00E-01 5.45 1.80 5.72
9.00E-01 14.35 1.80 5.72
9.00E-01 5.66 1.80 5.72
9.00E-01 1.09 1.80 5.72
9.00E-01 2.79 1.80 5.72
9.00E-01 1.48 1.80 5.72
9.00E-01 3.10 1.80 5.72
9.00E-01 3.38 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.84E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.74E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.47E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315 CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L11 1315 CFS
9/16/11 12:11 PM EPA Interlab L11 1315CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12 AM EPA Interlab L1 1 1315 CFS
9/16/11 11:13 AM EPA Interlab L11 1315 CFS
9/16/11 11:15 AM EPA Interlab L11 1315 CFS
9/16/11 11:17 AM EPA Interlab L1 1 1315 CFS
9/16/11 11:18 AM EPA Interlab L11 1315 CFS
9/16/11 1 1:20 AM EPA Interlab L11 1315 CFS
9/16/11 1 1:22 AM EPA Interlab L11 1315 CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315 CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315 CFS
1-912
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Cu CFS-L11-1315-T01-A 1 1.72E+02
Cu CFS-L11-1315-T02-A 1 1.65E+02
Cu CFS-L11-1315-T03-A 1 1.50E+02
Cu CFS-L11-1315-T04-A 1 3.33E+02
Cu CFS-L11-1315-T05-A 1 3.56E+02
Cu CFS-L11-1315-T06-A 1 4.96E+02
Cu CFS-L11-1315-T07-A 1 8.55E+02
Cu CFS-L11-1315-T08-A 1 3.27E+02
Cu CFS-L11-1315-T09-A 1 5.75E+02
Cu CFS-L11-1315-T01-B 1 1.28E+02
Cu CFS-L11-1315-T02-B 1 1.85E+02
Cu CFS-L11-1315-T03-B 1 1.46E+02
Cu CFS-L11-1315-T04-B 1 3.02E+02
Cu CFS-L11-1315-T05-B 1 3.71E+02
Cu CFS-L11-1315-T06-B 1 4.87E+02
Cu CFS-L11-1315-T07-B 1 8.68E+02
Cu CFS-L11-1315-T08-B 1 3.27E+02
Cu CFS-L11-1315-T09-B 1 5.62E+02
Cu CFS-L11-1315-T01-C 1 1.16E+02
Cu CFS-L11-1315-T02-C 1 1.54E+02
Cu CFS-L11-1315-T03-C 1 1.28E+02
Cu CFS-L11-1315-T04-C 1 3.21E+02
Cu CFS-L11-1315-T05-C 1 3.85E+02
Cu CFS-L11-1315-T06-C 1 4.84E+02
Cu CFS-L11-1315-T07-C 1 8.72E+02
Cu CFS-L11-1315-T08-C 1 3.20E+02
Cu CFS-L11-1315-T09-C 1 5.39E+02
Cu CFS-L11-1315-M01-A 1 1.85E+00 U1/2
Cu CFS-L11-1315-M02-A 1 1.85E+00 U1/2
Cu CFS-L11-1315-M03-A 1 1.85E+00 U1/2
Cu CFS-L11-1315-M04-A 1 1.85E+00 U1/2
Cu CFS-L11-1315-M05-A 1 1.85E+00 U1/2
Cu CFS-L11-1315-M06-A 1 1.85E+00 U1/2
Cu CFS-L11-1315-M07-A 1 1.85E+00 U1/2
Cu CFS-L11-1315-M08-A 1 1.85E+00 U1/2
Cu CFS-L11-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.72E+02 4.54 3.70 11.80
1.65E+02 3.86 3.70 11.80
1.50E+02 5.15 3.70 11.80 10000 1000
3.33E+02 2.47 3.70 11.80
356E+02 4.97 3.70 11.80
4.96E+02 1.40 3.70 11.80
8.55E+02 2.27 3.70 11.80
327E+02 5.58 3.70 11.80
5.75E+02 0.86 3.70 11.80
1.28E+02 2.85 3.70 11.80
1.85E+02 1.98 3.70 11.80
1.46E+02 2.25 3.70 11.80 10000 1000
302E+02 0.97 3.70 11.80
371E+02 1.48 3.70 11.80
4.87E+02 1.56 3.70 11.80
8.68E+02 0.83 3.70 11.80
3.27E+02 1.07 3.70 11.80
5.62E+02 14.72 3.70 11.80
1.16E+02 0.39 3.70 11.80
1.54E+02 1.46 3.70 11.80
1.28E+02 1.65 3.70 11.80 10000 1000
3.21E+02 1.12 3.70 11.80
3.85E+02 1.39 3.70 11.80
4.84E+02 1.20 3.70 11.80
8.72E+02 1.15 3.70 11.80
3.20E+02 0.85 3.70 11.80
5.39E+02 1.82 3.70 11.80
1.85E+00 1.21 3.70 11.80
1.85E+00 0.65 3.70 11.80
1.85E+00 0.94 3.70 11.80
1.85E+00 1.79 3.70 11.80
1.85E+00 0.64 3.70 11.80
1.85E+00 0.88 3.70 11.80
1.85E+00 0.73 3.70 11.80
1.85E+00 0.56 3.70 11.80
1.85E+00 1.60 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.03E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L1 1 1315 CFS
9/16/11 11:36 AM EPA Interlab L1 1 1315 CFS
9/16/11 11:38 AM EPA Interlab L1 1 1315 CFS
9/16/11 11:40 AM EPA Interlab L1 1 1315 CFS
9/16/11 11:46 AM EPA Interlab L1 1 131 5 CFS
9/16/11 11:48 AM EPA Interlab L11 131 5 CFS
9/16/11 11:50 AM EPA Interlab L1 1 1315 CFS
9/16/11 11:51 AM EPA Interlab L11 131 5 CFS
9/16/11 11:53 AM EPA Interlab L11 131 5 CFS
9/16/11 11:54 AM EPA Interlab L11 131 5 CFS
9/16/11 11:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315CFS
9/16/11 12:03 PM EPA Interlab L11 1315CFS
9/16/11 12:04 PM EPA Interlab L11 1315CFS
9/16/11 1:03 PM EPA Interlab L11 1315CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L11 1315 CFS
9/16/11 12:11 PM EPA Interlab L11 1315 CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 1 1:12 AM EPA Interlab L11 1315 CFS
9/16/11 11:13 AM EPA Interlab L11 1315 CFS
9/16/11 11:15 AM EPA Interlab L11 1315 CFS
9/16/11 1 1:17 AM EPA Interlab L11 1315 CFS
9/16/11 1 1:18 AM EPA Interlab L11 1315 CFS
9/16/11 11:20 AM EPA Interlab L11 1315 CFS
9/16/11 11:22 AM EPA Interlab L11 1315 CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315 CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315 CFS
1-913
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Fe CFS-L11-1315-T01-A 1 1.00E+00 U1/2
Fe CFS-L11-1315-T02-A 1 1.00E+00 U1/2
Fe CFS-L11-1315-T03-A 1 1.00E+00 U1/2
Fe CFS-L11-1315-T04-A 1 1.00E+00 U1/2
Fe CFS-L11-1315-T05-A 1 1.00E+00 U1/2
Fe CFS-L11-1315-T06-A 1 1.00E+00 U1/2
Fe CFS-L11-1315-T07-A 1 1.00E+00 U1/2
Fe CFS-L11-1315-T08-A 1 1.00E+00 U1/2
Fe CFS-L11-1315-T09-A 1 1.00E+00 U1/2
Fe CFS-L11-1315-T01-B 1 1.00E+00 U1/2
Fe CFS-L11-1315-T02-B 1 1.00E+00 U1/2
Fe CFS-L11-1315-T03-B 1 1.00E+00 U1/2
Fe CFS-L11-1315-T04-B 1 1.00E+00 U1/2
Fe CFS-L11-1315-T05-B 1 1.00E+00 U1/2
Fe CFS-L11-1315-T06-B 1 1.00E+00 U1/2
Fe CFS-L11-1315-T07-B 1 1.00E+00 U1/2
Fe CFS-L11-1315-T08-B 1 1.00E+00 U1/2
Fe CFS-L11-1315-T09-B 1 1.00E+00 U1/2
Fe CFS-L11-1315-T01-C 1 1.00E+00 U1/2
Fe CFS-L11-1315-T02-C 1 1.00E+00 U1/2
Fe CFS-L11-1315-T03-C 1 1.00E+00 U1/2
Fe CFS-L11-1315-T04-C 1 1.00E+00 U1/2
Fe CFS-L11-1315-T05-C 1 1.00E+00 U1/2
Fe CFS-L11-1315-T06-C 1 1.00E+00 U1/2
Fe CFS-L11-1315-T07-C 1 1.00E+00 U1/2
Fe CFS-L11-1315-T08-C 1 1.00E+00 U1/2
Fe CFS-L11-1315-T09-C 1 1.00E+00 U1/2
Fe CFS-L11-1315-M01-A 1 1.00E+00 U1/2
Fe CFS-L11-1315-M02-A 1 1.00E+00 U1/2
Fe CFS-L11-1315-M03-A 1 1.00E+00 U1/2
Fe CFS-L11-1315-M04-A 1 1.00E+00 U1/2
Fe CFS-L11-1315-M05-A 1 1.00E+00 U1/2
Fe CFS-L11-1315-M06-A 1 1.00E+00 U1/2
Fe CFS-L11-1315-M07-A 1 1.00E+00 U1/2
Fe CFS-L11-1315-M08-A 1 1.00E+00 U1/2
Fe CFS-L11-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 2.78 2.00 6.40
1.00E+00 30.28 2.00 6.40
1.00E+00 18.50 2.00 6.40 10000 1000
1.00E+00 11.33 2.00 6.40
1.00E+00 5.56 2.00 6.40
1.00E+00 11.11 2.00 6.40
1.00E+00 10.22 2.00 6.40
1.00E+00 17.39 2.00 6.40
1.00E+00 3.87 2.00 6.40
1.00E+00 1.41 2.00 6.40
1.00E+00 11.02 2.00 6.40
1.00E+00 1.02 2.00 6.40 10000 1000
1.00E+00 25.14 2.00 6.40
1.00E+00 11.16 2.00 6.40
1.00E+00 6.50 2.00 6.40
1.00E+00 2.78 2.00 6.40
1.00E+00 17.78 2.00 6.40
1.00E+00 3.28 2.00 6.40
1.00E+00 11.98 2.00 6.40
1.00E+00 12.95 2.00 6.40
1.00E+00 19.96 2.00 6.40 10000 1000
1.00E+00 13.08 2.00 6.40
1.00E+00 9.17 2.00 6.40
1.00E+00 5.63 2.00 6.40
1.00E+00 5.79 2.00 6.40
1.00E+00 18.63 2.00 6.40
1.00E+00 15.87 2.00 6.40
1.00E+00 28.26 2.00 6.40
1.00E+00 18.17 2.00 6.40
1.00E+00 8.76 2.00 6.40
1.00E+00 33.63 2.00 6.40
1.00E+00 5.35 2.00 6.40
1.00E+00 11.13 2.00 6.40
1.00E+00 18.82 2.00 6.40
1.00E+00 10.77 2.00 6.40
1.00E+00 22.84 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.14E+02 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.89E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.71E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315 CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L11 1315 CFS
9/16/11 12:11 PM EPA Interlab L11 1315 CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12 AM EPA Interlab L11 1315CFS
9/16/11 11:13 AM EPA Interlab L11 1315CFS
9/16/11 11:15 AM EPA Interlab L11 1315CFS
9/16/11 11:17 AM EPA Interlab L11 1315CFS
9/16/11 11:18 AM EPA Interlab L11 1315CFS
9/16/11 11:20 AM EPA Interlab L11 1315CFS
9/16/11 11:22 AM EPA Interlab L11 1315CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315CFS
1-914
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 Mg/L
Pb CFS-L11-1315-T01-A 1 4.94E+01
Pb CFS-L11-1315-T02-A 1 8.61 E+01
Pb CFS-L11-1315-T03-A 1 1.14E+02
Pb CFS-L11-1315-T04-A 1 2.69E+02
Pb CFS-L11-1315-T05-A 1 2.68E+02
Pb CFS-L11-1315-T06-A 1 3.53E+02
Pb CFS-L11-1315-T07-A 1 4.48E+02
Pb CFS-L11-1315-T08-A 1 2.37E+02
Pb CFS-L11-1315-T09-A 1 3.31 E+02
Pb CFS-L11-1315-T01-B 1 5.56E+01
Pb CFS-L11-1315-T02-B 1 8.76E+01
Pb CFS-L11-1315-T03-B 1 1.03E+02
Pb CFS-L11-1315-T04-B 1 2.57E+02
Pb CFS-L11-1315-T05-B 1 2.60E+02
Pb CFS-L11-1315-T06-B 1 3.42E+02
Pb CFS-L11-1315-T07-B 1 4.34E+02
Pb CFS-L11-1315-T08-B 1 2.14E+02
Pb CFS-L11-1315-T09-B 1 3.22E+02
Pb CFS-L11-1315-T01-C 1 5.48E+01
Pb CFS-L11-1315-T02-C 1 8.73E+01
Pb CFS-L11-1315-T03-C 1 1.13E+02
Pb CFS-L11-1315-T04-C 1 2.39E+02
Pb CFS-L11-1315-T05-C 1 2.70E+02
Pb CFS-L11-1315-T06-C 1 3.36E+02
Pb CFS-L11-1315-T07-C 1 4.37E+02
Pb CFS-L11-1315-T08-C 1 2.33E+02
Pb CFS-L11-1315-T09-C 1 3.19E+02
Pb CFS-L11-1315-M01-A 1 3.40E+00 U1/2
Pb CFS-L11-1315-M02-A 1 3.40E+00 U1/2
Pb CFS-L11-1315-M03-A 1 3.40E+00 U1/2
Pb CFS-L11-1315-M04-A 1 3.40E+00 U1/2
Pb CFS-L11-1315-M05-A 1 3.40E+00 U1/2
Pb CFS-L11-1315-M06-A 1 3.40E+00 U1/2
Pb CFS-L11-1315-M07-A 1 3.40E+00 U1/2
Pb CFS-L11-1315-M08-A 1 3.40E+00 U1/2
Pb CFS-L11-1315-M09-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.94E+01 1.24 6.80 21.60
8.61 E+01 3.38 6.80 21.60
1.14E+02 5.42 6.80 21.60 10000 1000
2.69E+02 1.85 6.80 21.60
2.68E+02 1.35 6.80 21.60
3.53E+02 2.63 6.80 21.60
4.48E+02 6.58 6.80 21.60
2.37E+02 2.31 6.80 21.60
3.31 E+02 2.54 6.80 21.60
5.56E+01 2.29 6.80 21.60
8.76E+01 2.74 6.80 21.60
1.03E+02 3.54 6.80 21.60 10000 1000
2.57E+02 1.35 6.80 21.60
2.60E+02 1.26 6.80 21.60
3.42E+02 2.48 6.80 21.60
4.34E+02 1.37 6.80 21.60
2.14E+02 1.24 6.80 21.60
3.22E+02 2.02 6.80 21.60
5.48E+01 1.67 6.80 21.60
8.73E+01 1.68 6.80 21.60
1.13E+02 0.92 6.80 21.60 10000 1000
2.39E+02 1.20 6.80 21.60
2.70E+02 3.24 6.80 21.60
336E+02 1.25 6.80 21.60
4.37E+02 1.78 6.80 21.60
2.33E+02 0.80 6.80 21.60
319E+02 1.21 6.80 21.60
340E+00 2.12 6.80 21.60
340E+00 3.35 6.80 21.60
340E+00 4.95 6.80 21.60
340E+00 3.08 6.80 21.60
340E+00 1.92 6.80 21.60
340E+00 1.68 6.80 21.60
340E+00 0.20 6.80 21.60
340E+00 1.62 6.80 21.60
340E+00 0.78 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.07E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315 CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L1 1 1315 CFS
9/16/11 12:11 PM EPA Interlab L1 1 1315 CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12 AM EPA Interlab L11 1315 CFS
9/16/11 11:13 AM EPA Interlab L1 1 1315 CFS
9/16/11 11:15 AM EPA Interlab L1 1 1315 CFS
9/16/11 11:17 AM EPA Interlab L11 1315 CFS
9/16/11 11:18 AM EPA Interlab L1 1 1315 CFS
9/16/11 1 1:20 AM EPA Interlab L11 1315 CFS
9/16/11 1 1:22 AM EPA Interlab L11 1315 CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315 CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315 CFS
1-915
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Li CFS-L11-1315-T01-A 1 3.38E+00 E
Li CFS-L11-1315-T02-A 1 2.17E+00 E
Li CFS-L11-1315-T03-A 1 3.32E+00 E
Li CFS-L11-1315-T04-A 1 4.44E+00 E
Li CFS-L11-1315-T05-A 1 6.25E+00
Li CFS-L11-1315-T06-A 1 5.72E+00 E
Li CFS-L11-1315-T07-A 1 5.45E+00 E
Li CFS-L11-1315-T08-A 1 6.47E+00
Li CFS-L11-1315-T09-A 1 7.97E+00
Li CFS-L11-1315-T01-B 1 1.98E+00 E
Li CFS-L11-1315-T02-B 1 2.17E+00 E
Li CFS-L11-1315-T03-B 1 2.35E+00 E
Li CFS-L11-1315-T04-B 1 4.25E+00 E
Li CFS-L11-1315-T05-B 1 5.36E+00 E
Li CFS-L11-1315-T06-B 1 6.65E+00
Li CFS-L11-1315-T07-B 1 4.24E+00 E
Li CFS-L11-1315-T08-B 1 5.09E+00 E
Li CFS-L11-1315-T09-B 1 7.13E+00
Li CFS-L11-1315-T01-C 1 2.23E+00 E
Li CFS-L11-1315-T02-C 1 2.54E+00 E
Li CFS-L11-1315-T03-C 1 3.82E+00 E
Li CFS-L11-1315-T04-C 1 4.94E+00 E
Li CFS-L11-1315-T05-C 1 5.00E+00 E
Li CFS-L11-1315-T06-C 1 5.42E+00 E
Li CFS-L11-1315-T07-C 1 5.14E+00 E
Li CFS-L11-1315-T08-C 1 6.20E+00
Li CFS-L11-1315-T09-C 1 6.21E+00
Li CFS-L11-1315-M01-A 1 9.50E-01 U1/2
Li CFS-L11-1315-M02-A 1 9.50E-01 U1/2
Li CFS-L11-1315-M03-A 1 9.50E-01 U1/2
Li CFS-L11-1315-M04-A 1 9.50E-01 U1/2
Li CFS-L11-1315-M05-A 1 9.50E-01 U1/2
Li CFS-L11-1315-M06-A 1 9.50E-01 U1/2
Li CFS-L11-1315-M07-A 1 9.50E-01 U1/2
Li CFS-L11-1315-M08-A 1 9.50E-01 U1/2
Li CFS-L11-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.38E+00 13.34 1.90 6.00
2.17E+00 17.00 1.90 6.00
3.32E+00 12.52 1.90 6.00 10000 1000
4.44E+00 31.53 1.90 6.00
6.25E+00 1.52 1.90 6.00
5.72E+00 14.16 1.90 6.00
5.45E+00 17.32 1.90 6.00
6.47E+00 5.81 1.90 6.00
7.97E+00 98.51 1.90 6.00
1.98E+00 36.02 1.90 6.00
2.17E+00 29.14 1.90 6.00
2.35E+00 12.83 1.90 6.00 10000 1000
4.25E+00 16.31 1.90 6.00
5.36E+00 19.27 1.90 6.00
6.65E+00 17.54 1.90 6.00
4.24E+00 18.58 1.90 6.00
5.09E+00 16.86 1.90 6.00
7.13E+00 3.43 1.90 6.00
2.23E+00 24.09 1.90 6.00
2.54E+00 63.92 1.90 6.00
3.82E+00 28.88 1.90 6.00 10000 1000
4.94E+00 19.76 1.90 6.00
5.00E+00 32.09 1.90 6.00
5.42E+00 34.58 1.90 6.00
5.14E+00 37.31 1.90 6.00
6.20E+00 12.28 1.90 6.00
6.21 E+00 3.45 1.90 6.00
9.50E-01 10.98 1.90 6.00
9.50E-01 24.40 1.90 6.00
9.50E-01 47.15 1.90 6.00
9.50E-01 32.15 1.90 6.00
9.50E-01 18.70 1.90 6.00
9.50E-01 31.38 1.90 6.00
9.50E-01 36.90 1.90 6.00
9.50E-01 16.34 1.90 6.00
9.50E-01 28.57 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.82E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.79E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.39E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315 CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L11 1315 CFS
9/16/11 12:11 PM EPA Interlab L11 1315 CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12 AM EPA Interlab L11 1315CFS
9/16/11 11:13 AM EPA Interlab L11 1315CFS
9/16/11 11:15 AM EPA Interlab L11 1315CFS
9/16/11 11:17 AM EPA Interlab L11 1315CFS
9/16/11 11:18 AM EPA Interlab L11 1315CFS
9/16/11 11:20 AM EPA Interlab L11 1315CFS
9/16/11 11:22 AM EPA Interlab L11 1315CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315CFS
1-916
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualil
1 1 1 M9/L
Mn CFS-L11-1315-T01-A 1 4.34E+01
Mn CFS-L11-1315-T02-A 1 1.96E+02
Mn CFS-L11-1315-T03-A 1 2.18E+02
Mn CFS-L11-1315-T04-A 1 6.50E+02
Mn CFS-L11-1315-T05-A 1 8.07E+02
Mn CFS-L11-1315-T06-A 1 1.18E+03
Mn CFS-L11-1315-T07-A 1 1.57E+03
Mn CFS-L11-1315-T08-A 1 9.15E+02
Mn CFS-L11-1315-T09-A 1 1.32E+03
Mn CFS-L11-1315-T01-B 1 4.34E+01
Mn CFS-L11-1315-T02-B 1 1.96E+02
Mn CFS-L11-1315-T03-B 1 2.18E+02
Mn CFS-L11-1315-T04-B 1 6.51E+02
Mn CFS-L11-1315-T05-B 1 8.22E+02
Mn CFS-L11-1315-T06-B 1 1.22E+03
Mn CFS-L11-1315-T07-B 1 1.57E+03
Mn CFS-L11-1315-T08-B 1 9.36E+02
Mn CFS-L11-1315-T09-B 1 1.21E+03
Mn CFS-L11-1315-T01-C 1 4.19E+01
Mn CFS-L11-1315-T02-C 1 2.08E+02
Mn CFS-L11-1315-T03-C 1 2.32E+02
Mn CFS-L11-1315-T04-C 1 6.55E+02
Mn CFS-L11-1315-T05-C 1 8.27E+02
Mn CFS-L11-1315-T06-C 1 1.12E+03
Mn CFS-L11-1315-T07-C 1 1.46E+03
Mn CFS-L11-1315-T08-C 1 9.27E+02
Mn CFS-L11-1315-T09-C 1 1.31E+03
Mn CFS-L11-1315-M01-A 1 1.00E+00 U1/2
Mn CFS-L11-1315-M02-A 1 1.00E+00 U1/2
Mn CFS-L11-1315-M03-A 1 1.00E+00 U1/2
Mn CFS-L11-1315-M04-A 1 1.00E+00 U1/2
Mn CFS-L11-1315-M05-A 1 1.00E+00 U1/2
Mn CFS-L11-1315-M06-A 1 1.00E+00 U1/2
Mn CFS-L11-1315-M07-A 1 1.00E+00 U1/2
Mn CFS-L11-1315-M08-A 1 1.00E+00 U1/2
Mn CFS-L11-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
ier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.34E+01 1.46 2.00 6.40
1.96E+02 3.18 2.00 6.40
2.18E+02 7.25 2.00 6.40 10000 1000
6.50E+02 1.16 2.00 6.40
8.07E+02 4.53 2.00 6.40
1.18E+03 4.36 2.00 6.40
1.57E+03 1.16 2.00 6.40
9.15E+02 7.70 2.00 6.40
1.32E+03 0.52 2.00 6.40
4.34E+01 0.48 2.00 6.40
1.96E+02 1.07 2.00 6.40
2.18E+02 0.82 2.00 6.40 10000 1000
6.51 E+02 0.84 2.00 6.40
8.22E+02 0.99 2.00 6.40
1.22E+03 0.62 2.00 6.40
1.57E+03 1.05 2.00 6.40
9.36E+02 0.96 2.00 6.40
1.21E+03 2.55 2.00 6.40
4.19E+01 0.25 2.00 6.40
2.08E+02 1.55 2.00 6.40
2.32E+02 0.79 2.00 6.40 10000 1000
6.55E+02 1.31 2.00 6.40
8.27E+02 0.86 2.00 6.40
1.12E+03 1.04 2.00 6.40
1.46E+03 1.12 2.00 6.40
9.27E+02 0.88 2.00 6.40
1.31E+03 1.54 2.00 6.40
1.00E+00 0.87 2.00 6.40
1.00E+00 0.59 2.00 6.40
1.00E+00 1.65 2.00 6.40
1.00E+00 0.39 2.00 6.40
1.00E+00 1.08 2.00 6.40
1.00E+00 0.82 2.00 6.40
1.00E+00 1.16 2.00 6.40
1.00E+00 1.08 2.00 6.40
1.00E+00 0.35 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.10E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.19E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315 CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L11 1315 CFS
9/16/11 12:11 PM EPA Interlab L11 1315CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12 AM EPA Interlab L11 1315CFS
9/16/11 11:13 AM EPA Interlab L11 1315CFS
9/16/11 11:15 AM EPA Interlab L11 1315CFS
9/16/11 11:17 AM EPA Interlab L11 1315CFS
9/16/11 11:18 AM EPA Interlab L11 1315CFS
9/16/11 11:20 AM EPA Interlab L11 1315CFS
9/16/11 11:22 AM EPA Interlab L11 1315CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315CFS
1-917
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Mg CFS-L11-1315-T01-A 1 3.89E+03
Mg CFS-L11-1315-T02-A 1 1.65E+04
Mg CFS-L11-1315-T03-A 1 1.91E+04
Mg CFS-L11-1315-T04-A 1 5.16E+04
Mg CFS-L11-1315-T05-A 1 6.69E+04
Mg CFS-L11-1315-T06-A 1 9.22E+04
Mg CFS-L11-1315-T07-A 1 1.04E+05
Mg CFS-L11-1315-T08-A 1 5.76E+04
Mg CFS-L11-1315-T09-A 1 5.86E+04
Mg CFS-L11-1315-T01-B 1 3.34E+03
Mg CFS-L11-1315-T02-B 1 1.46E+04
Mg CFS-L11-1315-T03-B 1 2.23E+04
Mg CFS-L11-1315-T04-B 1 5.44E+04
Mg CFS-L11-1315-T05-B 1 6.91 E+04
Mg CFS-L11-1315-T06-B 1 9.15E+04
Mg CFS-L11-1315-T07-B 1 1.12E+05
Mg CFS-L11-1315-T08-B 1 5.20E+04
Mg CFS-L11-1315-T09-B 1 6.21E+04
Mg CFS-L11-1315-T01-C 1 3.85E+03
Mg CFS-L11-1315-T02-C 1 1.75E+04
Mg CFS-L11-1315-T03-C 1 2.02E+04
Mg CFS-L11-1315-T04-C 1 5.01 E+04
Mg CFS-L11-1315-T05-C 1 7.05E+04
Mg CFS-L11-1315-T06-C 1 9.54E+04
Mg CFS-L11-1315-T07-C 1 1.03E+05
Mg CFS-L11-1315-T08-C 1 4.90E+04
Mg CFS-L11-1315-T09-C 1 5.64E+04
Mg CFS-L11-1315-M01-A 1 2.58E+00 E
Mg CFS-L11-1315-M02-A 1 5.00E-01 U1/2
Mg CFS-L11-1315-M03-A 1 5.00E-01 U1/2
Mg CFS-L11-1315-M04-A 1 5.00E-01 U1/2
Mg CFS-L11-1315-M05-A 1 5.00E-01 U1/2
Mg CFS-L11-1315-M06-A 1 5.00E-01 U1/2
Mg CFS-L11-1315-M07-A 1 5.00E-01 U1/2
Mg CFS-L11-1315-M08-A 1 5.00E-01 U1/2
Mg CFS-L11-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.89E+03 2.95 1.00 3.18
1.65E+04 2.05 1.00 3.18
1.91 E+04 3.69 1.00 3.18 10000 1000
5.16E+04 2.30 1.00 3.18
6.69E+04 2.28 1.00 3.18
9.22E+04 8.00 1.00 3.18
1.04E+05 1.15 1.00 3.18
5.76E+04 4.79 1.00 3.18
5.86E+04 1.03 1.00 3.18
3.34E+03 0.11 1.00 3.18
1.46E+04 0.40 1.00 3.18
2.23E+04 2.11 1.00 3.18 10000 1000
5.44E+04 1.06 1.00 3.18
6.91E+04 1.41 1.00 3.18
9.15E+04 1.50 1.00 3.18
1.12E+05 1.56 1.00 3.18
5.20E+04 0.86 1.00 3.18
6.21E+04 2.17 1.00 3.18
3.85E+03 1.33 1.00 3.18
1.75E+04 1.30 1.00 3.18
2.02E+04 1.36 1.00 3.18 10000 1000
5.01E+04 0.56 1.00 3.18
7.05E+04 1.14 1.00 3.18
9.54E+04 0.97 1.00 3.18
1.03E+05 0.92 1.00 3.18
4.90E+04 1.22 1.00 3.18
5.64E+04 0.84 1.00 3.18
2.58E+00 0.40 1.00 3.18
5.00E-01 0.79 1.00 3.18
5.00E-01 0.85 1.00 3.18
5.00E-01 1.45 1.00 3.18
5.00E-01 0.62 1.00 3.18
5.00E-01 1.01 1.00 3.18
5.00E-01 1.04 1.00 3.18
5.00E-01 1.16 1.00 3.18
5.00E-01 0.12 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.00E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.32E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2. 11 E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315 CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L11 1315 CFS
9/16/11 12:11 PM EPA Interlab L11 1315CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12 AM EPA Interlab L11 1315CFS
9/16/11 11:13 AM EPA Interlab L11 1315CFS
9/16/11 11:15 AM EPA Interlab L11 1315CFS
9/16/11 11:17 AM EPA Interlab L11 1315CFS
9/16/11 11:18 AM EPA Interlab L11 1315CFS
9/16/11 11:20 AM EPA Interlab L11 1315CFS
9/16/11 11:22 AM EPA Interlab L11 1315CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315CFS
1-918
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Mo CFS-L11-1315-T01-A 1 1.93E+00 E
Mo CFS-L11-1315-T02-A 1 1.73E+00 E
Mo CFS-L11-1315-T03-A 1 1.88E+00 E
Mo CFS-L11-1315-T04-A 1 2.43E+00 E
Mo CFS-L11-1315-T05-A 1 2.55E+00 E
Mo CFS-L11-1315-T06-A 1 3.42E+00 E
Mo CFS-L11-1315-T07-A 1 1.93E+00 E
Mo CFS-L11-1315-T08-A 1 2.43E+00 E
Mo CFS-L11-1315-T09-A 1 1.79E+00 E
Mo CFS-L11-1315-T01-B 1 2.43E+00 E
Mo CFS-L11-1315-T02-B 1 2.43E+00 E
Mo CFS-L11-1315-T03-B 1 1.90E+00 E
Mo CFS-L11-1315-T04-B 1 3.08E+00 E
Mo CFS-L11-1315-T05-B 1 2.88E+00 E
Mo CFS-L11-1315-T06-B 1 3.45E+00 E
Mo CFS-L11-1315-T07-B 1 1.71E+00 E
Mo CFS-L11-1315-T08-B 1 1.63E+00 E
Mo CFS-L11-1315-T09-B 1 1.98E+00 E
Mo CFS-L11-1315-T01-C 1 1.54E+00 E
Mo CFS-L11-1315-T02-C 1 1.29E+00 E
Mo CFS-L11-1315-T03-C 1 1.99E+00 E
Mo CFS-L11-1315-T04-C 1 2.26E+00 E
Mo CFS-L11-1315-T05-C 1 1.86E+00 E
Mo CFS-L11-1315-T06-C 1 3.85E+00
Mo CFS-L11-1315-T07-C 1 1.88E+00 E
Mo CFS-L11-1315-T08-C 1 2.43E+00 E
Mo CFS-L11-1315-T09-C 1 1.76E+00 E
Mo CFS-L11-1315-M01-A 1 6.00E-01 U1/2
Mo CFS-L11-1315-M02-A 1 6.00E-01 U1/2
Mo CFS-L11-1315-M03-A 1 6.00E-01 U1/2
Mo CFS-L11-1315-M04-A 1 6.00E-01 U1/2
Mo CFS-L11-1315-M05-A 1 6.00E-01 U1/2
Mo CFS-L11-1315-M06-A 1 6.00E-01 U1/2
Mo CFS-L11-1315-M07-A 1 6.00E-01 U1/2
Mo CFS-L11-1315-M08-A 1 6.00E-01 U1/2
Mo CFS-L11-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.93E+00 36.67 1.20 3.82
1.73E+00 16.09 1.20 3.82
1.88E+00 39.76 1.20 3.82 10000 1000
2.43E+00 25.93 1.20 3.82
2.55E+00 13.62 1.20 3.82
3.42E+00 14.80 1.20 3.82
1.93E+00 21.85 1.20 3.82
2.43E+00 30.27 1.20 3.82
1.79E+00 22.34 1.20 3.82
2.43E+00 29.70 1.20 3.82
2.43E+00 15.24 1.20 3.82
1.90E+00 31.63 1.20 3.82 10000 1000
3.08E+00 22.55 1.20 3.82
2.88E+00 27.18 1.20 3.82
3.45E+00 12.21 1.20 3.82
1.71E+00 20.86 1.20 3.82
1.63E+00 18.54 1.20 3.82
1.98E+00 2.22 1.20 3.82
1.54E+00 29.71 1.20 3.82
1.29E+00 4.44 1.20 3.82
1.99E+00 17.13 1.20 3.82 10000 1000
2.26E+00 26.25 1.20 3.82
1.86E+00 8.14 1.20 3.82
3.85E+00 3.54 1.20 3.82
1.88E+00 10.53 1.20 3.82
2.43E+00 18.80 1.20 3.82
1.76E+00 26.61 1.20 3.82
6.00E-01 40.91 1.20 3.82
6.00E-01 50.69 1.20 3.82
6.00E-01 66.23 1.20 3.82
6.00E-01 38.92 1.20 3.82
6.00E-01 24.01 1.20 3.82
6.00E-01 44.70 1.20 3.82
6.00E-01 19.50 1.20 3.82
6.00E-01 31.88 1.20 3.82
6.00E-01 25.50 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.76E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.54E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.38E+02 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L11 1315 CFS
9/16/11 12:11 PM EPA Interlab L11 1315 CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12AM EPA Interlab L1 1 1315CFS
9/16/11 11:13 AM EPA Interlab L11 1315CFS
9/16/11 11:15 AM EPA Interlab L11 1315CFS
9/16/11 11:17 AM EPA Interlab L1 1 1315CFS
9/16/11 11:18 AM EPA Interlab L11 1315CFS
9/16/11 11:20 AM EPA Interlab L11 1315CFS
9/16/11 11:22 AM EPA Interlab L11 1315CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315CFS
1-919
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Ni CFS-L11-1315-T01-A 1 5.82E+00
Ni CFS-L11-1315-T02-A 1 1.28E+01
Ni CFS-L11-1315-T03-A 1 1.43E+01
Ni CFS-L11-1315-T04-A 1 5.39E+01
Ni CFS-L11-1315-T05-A 1 4.83E+01
Ni CFS-L11-1315-T06-A 1 4.63E+01
Ni CFS-L11-1315-T07-A 1 8.86E+01
Ni CFS-L11-1315-T08-A 1 5.74E+01
Ni CFS-L11-1315-T09-A 1 5.06E+01
Ni CFS-L11-1315-T01-B 1 5.58E+00 E
Ni CFS-L11-1315-T02-B 1 1.52E+01
Ni CFS-L11-1315-T03-B 1 1.67E+01
Ni CFS-L11-1315-T04-B 1 5.41E+01
Ni CFS-L11-1315-T05-B 1 6.71E+01
Ni CFS-L11-1315-T06-B 1 5.80E+01
Ni CFS-L11-1315-T07-B 1 8.86E+01
Ni CFS-L11-1315-T08-B 1 4.21E+01
Ni CFS-L11-1315-T09-B 1 6.32E+01
Ni CFS-L11-1315-T01-C 1 3.89E+00 E
Ni CFS-L11-1315-T02-C 1 1.03E+01
Ni CFS-L11-1315-T03-C 1 1.35E+01
Ni CFS-L11-1315-T04-C 1 3.74E+01
Ni CFS-L11-1315-T05-C 1 4.61 E+01
Ni CFS-L11-1315-T06-C 1 4.09E+01
Ni CFS-L11-1315-T07-C 1 8.73E+01
Ni CFS-L11-1315-T08-C 1 3.28E+01
Ni CFS-L11-1315-T09-C 1 4.98E+01
Ni CFS-L11-1315-M01-A 1 9.00E-01 U1/2
Ni CFS-L11-1315-M02-A 1 9.00E-01 U1/2
Ni CFS-L11-1315-M03-A 1 9.00E-01 U1/2
Ni CFS-L11-1315-M04-A 1 9.00E-01 U1/2
Ni CFS-L11-1315-M05-A 1 9.00E-01 U1/2
Ni CFS-L11-1315-M06-A 1 9.00E-01 U1/2
Ni CFS-L11-1315-M07-A 1 9.00E-01 U1/2
Ni CFS-L11-1315-M08-A 1 9.00E-01 U1/2
Ni CFS-L11-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.82E+00 4.93 1.80 5.70
1.28E+01 4.21 1.80 5.70
1.43E+01 4.83 1.80 5.70 10000 1000
5.39E+01 10.87 1.80 5.70
4.83E+01 3.04 1.80 5.70
4.63E+01 3.24 1.80 5.70
8.86E+01 3.76 1.80 5.70
5.74E+01 1.30 1.80 5.70
5.06E+01 2.13 1.80 5.70
5.58E+00 9.41 1.80 5.70
1.52E+01 1.95 1.80 5.70
1.67E+01 1.27 1.80 5.70 10000 1000
5.41 E+01 4.64 1.80 5.70
6.71 E+01 5.31 1.80 5.70
5.80E+01 1.37 1.80 5.70
8.86E+01 1.12 1.80 5.70
4.21 E+01 2.68 1.80 5.70
6.32E+01 2.00 1.80 5.70
3.89E+00 7.68 1.80 5.70
1.03E+01 11.65 1.80 5.70
1.35E+01 3.61 1.80 5.70 10000 1000
3.74E+01 2.68 1.80 5.70
4.61 E+01 2.62 1.80 5.70
4.09E+01 1.89 1.80 5.70
8.73E+01 1.90 1.80 5.70
328E+01 2.78 1.80 5.70
4.98E+01 3.08 1.80 5.70
9.00E-01 5.62 1.80 5.70
9.00E-01 13.03 1.80 5.70
9.00E-01 4.74 1.80 5.70
9.00E-01 2.76 1.80 5.70
9.00E-01 4.97 1.80 5.70
9.00E-01 2.35 1.80 5.70
9.00E-01 1.20 1.80 5.70
9.00E-01 3.88 1.80 5.70
9.00E-01 0.48 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.76E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.69E+02 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.44E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315 CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L11 1315 CFS
9/16/11 12:11 PM EPA Interlab L1 1 1315 CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12 AM EPA Interlab L11 1315 CFS
9/16/11 11:13 AM EPA Interlab L1 1 1315 CFS
9/16/11 11:15 AM EPA Interlab L1 1 1315 CFS
9/16/11 11:17 AM EPA Interlab L11 1315 CFS
9/16/11 11:18 AM EPA Interlab L1 1 1315 CFS
9/16/11 1 1:20 AM EPA Interlab L11 1315 CFS
9/16/11 1 1:22 AM EPA Interlab L11 1315 CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315 CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315 CFS
1-920
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
P CFS-L11-1315-T01-A 1 5.62E+00 E
P CFS-L11-1315-T02-A 1 1.09E+01 E
P CFS-L11-1315-T03-A 1 1.25E+01
P CFS-L11-1315-T04-A 1 1.13E+01 E
P CFS-L11-1315-T05-A 1 1.04E+01 E
P CFS-L11-1315-T06-A 1 1.04E+01 E
P CFS-L11-1315-T07-A 1 5.12E+00 E
P CFS-L11-1315-T08-A 1 4.62E+00 E
P CFS-L11-1315-T09-A 1 4.45E+00 E
P CFS-L11-1315-T01-B 1 6.90E+00 E
P CFS-L11-1315-T02-B 1 9.81E+00 E
P CFS-L11-1315-T03-B 1 8.98E+00 E
P CFS-L11-1315-T04-B 1 1.16E+01 E
P CFS-L11-1315-T05-B 1 1.22E+01
P CFS-L11-1315-T06-B 1 8.98E+00 E
P CFS-L11-1315-T07-B 1 8.62E+00 E
P CFS-L11-1315-T08-B 1 7.97E+00 E
P CFS-L11-1315-T09-B 1 4.50E+00 E
P CFS-L11-1315-T01-C 1 5.08E+00 E
P CFS-L11-1315-T02-C 1 9.47E+00 E
P CFS-L11-1315-T03-C 1 1.07E+01 E
P CFS-L11-1315-T04-C 1 1.03E+01 E
P CFS-L11-1315-T05-C 1 1.14E+01 E
P CFS-L11-1315-T06-C 1 1.08E+01 E
P CFS-L11-1315-T07-C 1 9.38E+00 E
P CFS-L11-1315-T08-C 1 7.14E+00 E
P CFS-L11-1315-T09-C 1 4.20E+00 E
P CFS-L11-1315-M01-A 1 1.85E+00 U1/2
P CFS-L11-1315-M02-A 1 1.85E+00 U1/2
P CFS-L11-1315-M03-A 1 1.85E+00 U1/2
P CFS-L11-1315-M04-A 1 1.85E+00 U1/2
P CFS-L11-1315-M05-A 1 1.85E+00 U1/2
P CFS-L11-1315-M06-A 1 1.85E+00 U1/2
P CFS-L11-1315-M07-A 1 1.85E+00 U1/2
P CFS-L11-1315-M08-A 1 1.85E+00 U1/2
P CFS-L11-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.62E+00 6.39 3.70 11.80
1.09E+01 3.72 3.70 11.80
1.25E+01 9.19 3.70 11.80 10000 1000
1.13E+01 12.71 3.70 11.80
1.04E+01 21.94 3.70 11.80
1.04E+01 2.29 3.70 11.80
5.12E+00 32.85 3.70 11.80
4.62E+00 18.43 3.70 11.80
4.45E+00 4.78 3.70 11.80
6.90E+00 12.91 3.70 11.80
9.81E+00 31.17 3.70 11.80
8.98E+00 31.64 3.70 11.80 10000 1000
1.16E+01 3.03 3.70 11.80
1.22E+01 4.37 3.70 11.80
8.98E+00 14.84 3.70 11.80
8.62E+00 10.29 3.70 11.80
7.97E+00 16.31 3.70 11.80
4.50E+00 3.55 3.70 11.80
5.08E+00 28.38 3.70 11.80
9.47E+00 12.82 3.70 11.80
1.07E+01 21.74 3.70 11.80 10000 1000
1.03E+01 33.67 3.70 11.80
1.14E+01 29.69 3.70 11.80
1.08E+01 9.85 3.70 11.80
9.38E+00 22.55 3.70 11.80
7.14E+00 14.91 3.70 11.80
4.20E+00 18.38 3.70 11.80
1.85E+00 13.52 3.70 11.80
1.85E+00 10.97 3.70 11.80
1.85E+00 7.13 3.70 11.80
1.85E+00 18.77 3.70 11.80
1.85E+00 6.12 3.70 11.80
1.85E+00 27.23 3.70 11.80
1.85E+00 29.66 3.70 11.80
1.85E+00 11.24 3.70 11.80
1.85E+00 28.34 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.54E+02 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.39E+02 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.04E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315CFS
9/16/11 12:03 PM EPA Interlab L11 1315CFS
9/16/11 12:04 PM EPA Interlab L11 1315CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315CFS
9/16/11 12:09 PM EPA Interlab L11 1315CFS
9/16/11 12:11 PM EPA Interlab L11 1315CFS
9/16/11 12:13 PM EPA Interlab L11 1315CFS
9/16/11 12:14 PM EPA Interlab L11 1315CFS
9/16/11 11:12AM EPA Interlab L1 1 1315CFS
9/16/11 11:13 AM EPA Interlab L11 1315CFS
9/16/11 11:15 AM EPA Interlab L11 1315CFS
9/16/11 11:17 AM EPA Interlab L1 1 1315CFS
9/16/11 11:18 AM EPA Interlab L11 1315CFS
9/16/11 11:20 AM EPA Interlab L11 131 5 CFS
9/16/11 11:22 AM EPA Interlab L11 131 5 CFS
9/16/11 1 1:23 AM EPA Interlab L11 131 5 CFS
9/16/11 1 1:25 AM EPA Interlab L11 131 5 CFS
1-921
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
K CFS-L11-1315-T01-A 1 4.31E+02
K CFS-L11-1315-T02-A 1 2.05E+03
K CFS-L11-1315-T03-A 1 1.98E+03
K CFS-L11-1315-T04-A 1 5.88E+03
K CFS-L11-1315-T05-A 1 6.41 E+03
K CFS-L11-1315-T06-A 1 8.95E+03
K CFS-L11-1315-T07-A 1 6.15E+03
K CFS-L11-1315-T08-A 1 3.89E+03
K CFS-L11-1315-T09-A 1 5.23E+03
K CFS-L11-1315-T01-B 1 4.31E+02
K CFS-L11-1315-T02-B 1 1.99E+03
K CFS-L11-1315-T03-B 1 2.03E+03
K CFS-L11-1315-T04-B 1 5.66E+03
K CFS-L11-1315-T05-B 1 6.42E+03
K CFS-L11-1315-T06-B 1 8.90E+03
K CFS-L11-1315-T07-B 1 6.20E+03
K CFS-L11-1315-T08-B 1 3.36E+03
K CFS-L11-1315-T09-B 1 5.01 E+03
K CFS-L11-1315-T01-C 1 4.20E+02
K CFS-L11-1315-T02-C 1 1.86E+03
K CFS-L11-1315-T03-C 1 1.95E+03
K CFS-L11-1315-T04-C 1 5.77E+03
K CFS-L11-1315-T05-C 1 6.66E+03
K CFS-L11-1315-T06-C 1 8.92E+03
K CFS-L11-1315-T07-C 1 6.01 E+03
K CFS-L11-1315-T08-C 1 3.54E+03
K CFS-L11-1315-T09-C 1 4.83E+03
K CFS-L11-1315-M01-A 1 2.48E+01
K CFS-L11-1315-M02-A 1 1.96E+01
K CFS-L11-1315-M03-A 1 2.03E+01
K CFS-L11-1315-M04-A 1 1.89E+01
K CFS-L11-1315-M05-A 1 1.32E+01
K CFS-L11-1315-M06-A 1 1.52E+01
K CFS-L11-1315-M07-A 1 2.14E+01
K CFS-L11-1315-M08-A 1 2.13E+01
K CFS-L11-1315-M09-A 1 2.66E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.31E+02 1.11 1.60 5.09
2.05E+03 1.55 1.60 5.09
1.98E+03 6.06 1.60 5.09 10000 1000
5.88E+03 1.26 1.60 5.09
6.41E+03 1.11 1.60 5.09
8.95E+03 4.37 1.60 5.09
6.15E+03 1.66 1.60 5.09
3.89E+03 5.69 1.60 5.09
5.23E+03 1.48 1.60 5.09
4.31 E+02 0.35 1.60 5.09
1.99E+03 0.22 1.60 5.09
2.03E+03 2.40 1.60 5.09 10000 1000
5.66E+03 0.69 1.60 5.09
6.42E+03 1.17 1.60 5.09
8.90E+03 1.37 1.60 5.09
6.20E+03 1.02 1.60 5.09
3.36E+03 1.03 1.60 5.09
5.01 E+03 1.56 1.60 5.09
4.20E+02 1.56 1.60 5.09
1.86E+03 0.25 1.60 5.09
1.95E+03 1.00 1.60 5.09 10000 1000
5.77E+03 0.34 1.60 5.09
6.66E+03 0.91 1.60 5.09
8.92E+03 1.27 1.60 5.09
6.01E+03 1.14 1.60 5.09
3.54E+03 0.75 1.60 5.09
4.83E+03 1.19 1.60 5.09
2.48E+01 0.61 1.60 5.09
1.96E+01 0.76 1.60 5.09
2.03E+01 1.15 1.60 5.09
1.89E+01 1.65 1.60 5.09
1.32E+01 0.63 1.60 5.09
1.52E+01 0.91 1.60 5.09
2.14E+01 0.96 1.60 5.09
2.13E+01 1.27 1.60 5.09
2.66E+01 0.68 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.85E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.94E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.87E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315 CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L11 1315 CFS
9/16/11 12:11 PM EPA Interlab L11 1315CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12 AM EPA Interlab L11 1315CFS
9/16/11 11:13 AM EPA Interlab L11 1315CFS
9/16/11 11:15 AM EPA Interlab L11 1315CFS
9/16/11 11:17 AM EPA Interlab L11 1315CFS
9/16/11 11:18 AM EPA Interlab L11 1315CFS
9/16/11 11:20 AM EPA Interlab L11 1315CFS
9/16/11 11:22 AM EPA Interlab L11 1315CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315CFS
1-922
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L
Se CFS-L11-1315-T01-A 1 2.10E+01 E
Se CFS-L11-1315-T02-A 1 2.39E+01 E
Se CFS-L11-1315-T03-A 1 2.51E+01 E
Se CFS-L11-1315-T04-A 1 5.34E+01
Se CFS-L11-1315-T05-A 1 6.15E+01
Se CFS-L11-1315-T06-A 1 4.90E+01
Se CFS-L11-1315-T07-A 1 9.71E+01
Se CFS-L11-1315-T08-A 1 4.48E+01 E
Se CFS-L11-1315-T09-A 1 3.71E+01 E
Se CFS-L11-1315-T01-B 1 1.84E+01 E
Se CFS-L11-1315-T02-B 1 2.66E+01 E
Se CFS-L11-1315-T03-B 1 2.83E+01 E
Se CFS-L11-1315-T04-B 1 5.28E+01
Se CFS-L11-1315-T05-B 1 6.53E+01
Se CFS-L11-1315-T06-B 1 4.95E+01
Se CFS-L11-1315-T07-B 1 9.64E+01
Se CFS-L11-1315-T08-B 1 4.09E+01 E
Se CFS-L11-1315-T09-B 1 3.34E+01 E
Se CFS-L11-1315-T01-C 1 2.52E+01 E
Se CFS-L11-1315-T02-C 1 2.44E+01 E
Se CFS-L11-1315-T03-C 1 2.46E+01 E
Se CFS-L11-1315-T04-C 1 5.27E+01
Se CFS-L11-1315-T05-C 1 5.74E+01
Se CFS-L11-1315-T06-C 1 4.72E+01 E
Se CFS-L11-1315-T07-C 1 9.86E+01
Se CFS-L11-1315-T08-C 1 3.91 E+01 E
Se CFS-L11-1315-T09-C 1 5.00E+01
Se CFS-L11-1315-M01-A 1 7.50E+00 U1/2
Se CFS-L11-1315-M02-A 1 7.50E+00 U1/2
Se CFS-L11-1315-M03-A 1 7.50E+00 U1/2
Se CFS-L11-1315-M04-A 1 7.50E+00 U1/2
Se CFS-L11-1315-M05-A 1 7.50E+00 U1/2
Se CFS-L11-1315-M06-A 1 7.50E+00 U1/2
Se CFS-L11-1315-M07-A 1 7.50E+00 U1/2
Se CFS-L11-1315-M08-A 1 7.50E+00 U1/2
Se CFS-L11-1315-M09-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.10E+01 21.30 15.00 47.70
2.39E+01 33.31 15.00 47.70
2.51E+01 14.11 15.00 47.70 10000 1000
5.34E+01 6.26 15.00 47.70
6.15E+01 3.92 15.00 47.70
4.90E+01 4.64 15.00 47.70
9.71E+01 8.52 15.00 47.70
4.48E+01 11.48 15.00 47.70
3.71E+01 18.53 15.00 47.70
1.84E+01 29.47 15.00 47.70
2.66E+01 4.98 15.00 47.70
2.83E+01 2.20 15.00 47.70 10000 1000
5.28E+01 2.58 15.00 47.70
6.53E+01 6.38 15.00 47.70
4.95E+01 14.94 15.00 47.70
9.64E+01 2.43 15.00 47.70
4.09E+01 22.64 15.00 47.70
3.34E+01 1.10 15.00 47.70
2.52E+01 9.39 15.00 47.70
2.44E+01 16.53 15.00 47.70
2.46E+01 23.59 15.00 47.70 10000 1000
5.27E+01 6.33 15.00 47.70
5.74E+01 5.74 15.00 47.70
4.72E+01 9.26 15.00 47.70
9.86E+01 9.40 15.00 47.70
391E+01 20.46 15.00 47.70
5.00E+01 8.02 15.00 47.70
7.50E+00 42.52 15.00 47.70
7.50E+00 34.62 15.00 47.70
7.50E+00 17.76 15.00 47.70
7.50E+00 7.73 15.00 47.70
7.50E+00 11.03 15.00 47.70
7.50E+00 8.40 15.00 47.70
7.50E+00 14.83 15.00 47.70
7.50E+00 10.25 15.00 47.70
7.50E+00 24.06 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.77E+02 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.58E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.84E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315 CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L11 1315 CFS
9/16/11 12:11 PM EPA Interlab L11 1315CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12 AM EPA Interlab L1 1 1315CFS
9/16/11 11:13 AM EPA Interlab L11 1315CFS
9/16/11 11:15 AM EPA Interlab L11 1315CFS
9/16/11 11:17 AM EPA Interlab L1 1 1315CFS
9/16/11 11:18 AM EPA Interlab L11 1315CFS
9/16/11 11:20 AM EPA Interlab L11 1315CFS
9/16/11 11:22 AM EPA Interlab L11 1315CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315CFS
1-923
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Si CFS-L11-1315-T01-A 1 7.22E+01
Si CFS-L11-1315-T02-A 1 3.42E+02
Si CFS-L11-1315-T03-A 1 4.14E+02
Si CFS-L11-1315-T04-A 1 8.64E+02
Si CFS-L11-1315-T05-A 1 9.28E+02
Si CFS-L11-1315-T06-A 1 1.23E+03
Si CFS-L11-1315-T07-A 1 1.75E+03
Si CFS-L11-1315-T08-A 1 1.16E+03
Si CFS-L11-1315-T09-A 1 1.23E+03
Si CFS-L11-1315-T01-B 1 6.34E+01
Si CFS-L11-1315-T02-B 1 3.33E+02
Si CFS-L11-1315-T03-B 1 4.22E+02
Si CFS-L11-1315-T04-B 1 8.42E+02
Si CFS-L11-1315-T05-B 1 9.41 E+02
Si CFS-L11-1315-T06-B 1 1.28E+03
Si CFS-L11-1315-T07-B 1 1.75E+03
Si CFS-L11-1315-T08-B 1 1.15E+03
Si CFS-L11-1315-T09-B 1 1.28E+03
Si CFS-L11-1315-T01-C 1 6.79E+01
Si CFS-L11-1315-T02-C 1 3.41 E+02
Si CFS-L11-1315-T03-C 1 4.06E+02
Si CFS-L11-1315-T04-C 1 8.79E+02
Si CFS-L11-1315-T05-C 1 9.46E+02
Si CFS-L11-1315-T06-C 1 1.29E+03
Si CFS-L11-1315-T07-C 1 1.68E+03
Si CFS-L11-1315-T08-C 1 1.02E+03
Si CFS-L11-1315-T09-C 1 1.18E+03
Si CFS-L11-1315-M01-A 1 5.50E-01 U1/2
Si CFS-L11-1315-M02-A 1 5.50E-01 U1/2
Si CFS-L11-1315-M03-A 1 5.50E-01 U1/2
Si CFS-L11-1315-M04-A 1 5.50E-01 U1/2
Si CFS-L11-1315-M05-A 1 5.50E-01 U1/2
Si CFS-L11-1315-M06-A 1 5.50E-01 U1/2
Si CFS-L11-1315-M07-A 1 5.50E-01 U1/2
Si CFS-L11-1315-M08-A 1 5.50E-01 U1/2
Si CFS-L11-1315-M09-A 1 5.50E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.22E+01 1.23 1.10 3.50
3.42E+02 1.48 1.10 3.50
4.14E+02 5.43 1.10 3.50 10000 1000
8.64E+02 1.15 1.10 3.50
9.28E+02 1.44 1.10 3.50
1.23E+03 5.93 1.10 3.50
1.75E+03 5.61 1.10 3.50
1.16E+03 1.12 1.10 3.50
1.23E+03 1.46 1.10 3.50
6.34E+01 0.99 1.10 3.50
3.33E+02 1.23 1.10 3.50
4.22E+02 2.63 1.10 3.50 10000 1000
8.42E+02 0.86 1.10 3.50
9.41 E+02 0.98 1.10 3.50
1.28E+03 1.55 1.10 3.50
1.75E+03 1.25 1.10 3.50
1.15E+03 0.91 1.10 3.50
1.28E+03 1.86 1.10 3.50
6.79E+01 4.70 1.10 3.50
3.41 E+02 0.55 1.10 3.50
4.06E+02 1.61 1.10 3.50 10000 1000
8.79E+02 0.73 1.10 3.50
9.46E+02 0.51 1.10 3.50
1.29E+03 1.29 1.10 3.50
1.68E+03 1.46 1.10 3.50
1.02E+03 0.18 1.10 3.50
1.18E+03 1.15 1.10 3.50
5.50E-01 0.55 1.10 3.50
5.50E-01 0.78 1.10 3.50
5.50E-01 0.17 1.10 3.50
5.50E-01 1.37 1.10 3.50
5.50E-01 1.43 1.10 3.50
5.50E-01 1.53 1.10 3.50
5.50E-01 1.06 1.10 3.50
5.50E-01 0.91 1.10 3.50
5.50E-01 0.78 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.30E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.32E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.34E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315 CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L11 1315 CFS
9/16/11 12:11 PM EPA Interlab L11 1315CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12 AM EPA Interlab L11 1315CFS
9/16/11 11:13 AM EPA Interlab L11 1315CFS
9/16/11 11:15 AM EPA Interlab L11 1315CFS
9/16/11 11:17 AM EPA Interlab L11 1315CFS
9/16/11 11:18 AM EPA Interlab L11 1315CFS
9/16/11 11:20 AM EPA Interlab L11 1315CFS
9/16/11 11:22 AM EPA Interlab L11 1315CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315CFS
1-924
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Na CFS-L11-1315-T01-A 1 1.88E+03
Na CFS-L11-1315-T02-A 1 8.22E+03
Na CFS-L11-1315-T03-A 1 8.06E+03
Na CFS-L11-1315-T04-A 1 2.35E+04
Na CFS-L11-1315-T05-A 1 2.27E+04
Na CFS-L11-1315-T06-A 1 2.77E+04
Na CFS-L11-1315-T07-A 1 3.59E+04
Na CFS-L11-1315-T08-A 1 1.40E+04
Na CFS-L11-1315-T09-A 1 1.53E+04
Na CFS-L11-1315-T01-B 1 1.93E+03
Na CFS-L11-1315-T02-B 1 8.59E+03
Na CFS-L11-1315-T03-B 1 8.13E+03
Na CFS-L11-1315-T04-B 1 2.14E+04
Na CFS-L11-1315-T05-B 1 2.40E+04
Na CFS-L11-1315-T06-B 1 2.86E+04
Na CFS-L11-1315-T07-B 1 3.50E+04
Na CFS-L11-1315-T08-B 1 1.39E+04
Na CFS-L11-1315-T09-B 1 1.51E+04
Na CFS-L11-1315-T01-C 1 1.89E+03
Na CFS-L11-1315-T02-C 1 8.18E+03
Na CFS-L11-1315-T03-C 1 8.69E+03
Na CFS-L11-1315-T04-C 1 2.05E+04
Na CFS-L11-1315-T05-C 1 2.29E+04
Na CFS-L11-1315-T06-C 1 2.78E+04
Na CFS-L11-1315-T07-C 1 3.61 E+04
Na CFS-L11-1315-T08-C 1 1.32E+04
Na CFS-L11-1315-T09-C 1 1.51 E+04
Na CFS-L11-1315-M01-A 1 1.21E+01
Na CFS-L11-1315-M02-A 1 1.69E+01
Na CFS-L11-1315-M03-A 1 1.71E+01
Na CFS-L11-1315-M04-A 1 8.92E+00
Na CFS-L11-1315-M05-A 1 1.51E+01
Na CFS-L11-1315-M06-A 1 1.80E+01
Na CFS-L11-1315-M07-A 1 2.15E+01
Na CFS-L11-1315-M08-A 1 5.85E+00 E
Na CFS-L11-1315-M09-A 1 5.40E+00 E
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.88E+03 2.62 2.50 8.00
8.22E+03 1.31 2.50 8.00
8.06E+03 3.54 2.50 8.00 10000 1000
2.35E+04 0.94 2.50 8.00
2.27E+04 1.07 2.50 8.00
2.77E+04 0.98 2.50 8.00
3.59E+04 0.91 2.50 8.00
1.40E+04 4.68 2.50 8.00
1.53E+04 0.06 2.50 8.00
1.93E+03 0.32 2.50 8.00
8.59E+03 0.15 2.50 8.00
8.13E+03 0.48 2.50 8.00 10000 1000
2.14E+04 0.50 2.50 8.00
2.40E+04 0.83 2.50 8.00
2.86E+04 0.88 2.50 8.00
3.50E+04 0.55 2.50 8.00
1.39E+04 0.67 2.50 8.00
1.51 E+04 1.55 2.50 8.00
1.89E+03 0.56 2.50 8.00
8.18E+03 0.38 2.50 8.00
8.69E+03 0.19 2.50 8.00 10000 1000
2.05E+04 0.65 2.50 8.00
2.29E+04 0.18 2.50 8.00
2.78E+04 0.49 2.50 8.00
361E+04 0.18 2.50 8.00
1.32E+04 0.77 2.50 8.00
1.51 E+04 0.77 2.50 8.00
1.21E+01 0.91 2.50 8.00
1.69E+01 0.80 2.50 8.00
1.71E+01 0.36 2.50 8.00
8.92E+00 0.39 2.50 8.00
1.51E+01 0.60 2.50 8.00
1.80E+01 0.95 2.50 8.00
2.15E+01 0.12 2.50 8.00
5.85E+00 1.08 2.50 8.00
5.40E+00 0.58 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.92E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.02E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.61 E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315 CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L1 1 1315 CFS
9/16/11 12:11 PM EPA Interlab L1 1 1315 CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12 AM EPA Interlab L11 1315CFS
9/16/11 11:13 AM EPA Interlab L11 1315CFS
9/16/11 1 1:15 AM EPA Interlab L11 131 5 CFS
9/16/11 11:17 AM EPA Interlab L1 1 1315 CFS
9/16/11 1 1:18 AM EPA Interlab L11 131 5 CFS
9/16/11 1 1:20 AM EPA Interlab L11 1315CFS
9/16/11 1 1:22 AM EPA Interlab L11 1315CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315CFS
1-925
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Sr CFS-L11-1315-T01-A 1 1.46E+01
Sr CFS-L11-1315-T02-A 1 1.01E+02
Sr CFS-L11-1315-T03-A 1 8.61 E+01
Sr CFS-L11-1315-T04-A 1 3.90E+02
Sr CFS-L11-1315-T05-A 1 3.69E+02
Sr CFS-L11-1315-T06-A 1 8.51 E+02
Sr CFS-L11-1315-T07-A 1 5.61 E+02
Sr CFS-L11-1315-T08-A 1 3.88E+02
Sr CFS-L11-1315-T09-A 1 5.42E+02
Sr CFS-L11-1315-T01-B 1 1.93E+01
Sr CFS-L11-1315-T02-B 1 7.94E+01
Sr CFS-L11-1315-T03-B 1 8.42E+01
Sr CFS-L11-1315-T04-B 1 2.71E+02
Sr CFS-L11-1315-T05-B 1 3.57E+02
Sr CFS-L11-1315-T06-B 1 8.42E+02
Sr CFS-L11-1315-T07-B 1 5.49E+02
Sr CFS-L11-1315-T08-B 1 3.48E+02
Sr CFS-L11-1315-T09-B 1 5.60E+02
Sr CFS-L11-1315-T01-C 1 1.34E+01
Sr CFS-L11-1315-T02-C 1 8.37E+01
Sr CFS-L11-1315-T03-C 1 9.39E+01
Sr CFS-L11-1315-T04-C 1 3.22E+02
Sr CFS-L11-1315-T05-C 1 3.93E+02
Sr CFS-L11-1315-T06-C 1 8.45E+02
Sr CFS-L11-1315-T07-C 1 5.70E+02
Sr CFS-L11-1315-T08-C 1 3.62E+02
Sr CFS-L11-1315-T09-C 1 5.48E+02
Sr CFS-L11-1315-M01-A 1 5.00E-01 U1/2
Sr CFS-L11-1315-M02-A 1 5.00E-01 U1/2
Sr CFS-L11-1315-M03-A 1 5.00E-01 U1/2
Sr CFS-L11-1315-M04-A 1 5.00E-01 U1/2
Sr CFS-L11-1315-M05-A 1 5.00E-01 U1/2
Sr CFS-L11-1315-M06-A 1 5.00E-01 U1/2
Sr CFS-L11-1315-M07-A 1 5.00E-01 U1/2
Sr CFS-L11-1315-M08-A 1 5.00E-01 U1/2
Sr CFS-L11-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.46E+01 4.49 1.00 3.18
1.01 E+02 1.77 1.00 3.18
8.61E+01 2.02 1.00 3.18 10000 1000
3.90E+02 1.84 1.00 3.18
3.69E+02 2.66 1.00 3.18
8.51E+02 2.93 1.00 3.18
5.61E+02 0.90 1.00 3.18
3.88E+02 4.52 1.00 3.18
5.42E+02 3.72 1.00 3.18
1.93E+01 0.76 1.00 3.18
7.94E+01 1.09 1.00 3.18
8.42E+01 2.44 1.00 3.18 10000 1000
2.71E+02 0.62 1.00 3.18
3.57E+02 1.79 1.00 3.18
8.42E+02 1.73 1.00 3.18
5.49E+02 1.06 1.00 3.18
3.48E+02 2.05 1.00 3.18
5.60E+02 3.32 1.00 3.18
1.34E+01 2.60 1.00 3.18
8.37E+01 1.34 1.00 3.18
9.39E+01 1.72 1.00 3.18 10000 1000
3.22E+02 0.46 1.00 3.18
3.93E+02 0.93 1.00 3.18
8.45E+02 1.51 1.00 3.18
5.70E+02 1.00 1.00 3.18
3.62E+02 0.62 1.00 3.18
5.48E+02 1.49 1.00 3.18
5.00E-01 3.39 1.00 3.18
5.00E-01 1.39 1.00 3.18
5.00E-01 2.02 1.00 3.18
5.00E-01 1.38 1.00 3.18
5.00E-01 0.56 1.00 3.18
5.00E-01 1.28 1.00 3.18
5.00E-01 0.71 1.00 3.18
5.00E-01 1.04 1.00 3.18
5.00E-01 1.97 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.56E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315 CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L11 1315 CFS
9/16/11 12:11 PM EPA Interlab L11 1315CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12 AM EPA Interlab L11 1315CFS
9/16/11 11:13 AM EPA Interlab L11 1315CFS
9/16/11 11:15 AM EPA Interlab L11 1315CFS
9/16/11 11:17 AM EPA Interlab L11 1315CFS
9/16/11 11:18 AM EPA Interlab L11 1315CFS
9/16/11 11:20 AM EPA Interlab L11 1315CFS
9/16/11 11:22 AM EPA Interlab L11 1315CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315CFS
1-926
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
S CFS-L11-1315-T01-A 1 8.26E+03
S CFS-L11-1315-T02-A 1 3.75E+04
S CFS-L11-1315-T03-A 1 4.02E+04
S CFS-L11-1315-T04-A 1 1.13E+05
S CFS-L11-1315-T05-A 1 1.33E+05
S CFS-L11-1315-T06-A 1 1.96E+05
S CFS-L11-1315-T07-A 1 2.02E+05
S CFS-L11-1315-T08-A 1 1.08E+05
S CFS-L11-1315-T09-A 1 1.59E+05
S CFS-L11-1315-T01-B 1 7.51E+03
S CFS-L11-1315-T02-B 1 3.99E+04
S CFS-L11-1315-T03-B 1 4.26E+04
S CFS-L11-1315-T04-B 1 1.07E+05
S CFS-L11-1315-T05-B 1 1.38E+05
S CFS-L11-1315-T06-B 1 1.95E+05
S CFS-L11-1315-T07-B 1 2.09E+05
S CFS-L11-1315-T08-B 1 1.02E+05
S CFS-L11-1315-T09-B 1 1.60E+05
S CFS-L11-1315-T01-C 1 7.85E+03
S CFS-L11-1315-T02-C 1 3.74E+04
S CFS-L11-1315-T03-C 1 4.05E+04
S CFS-L11-1315-T04-C 1 1.04E+05
S CFS-L11-1315-T05-C 1 1.27E+05
S CFS-L11-1315-T06-C 1 1.96E+05
S CFS-L11-1315-T07-C 1 2.03E+05
S CFS-L11-1315-T08-C 1 1.01E+05
S CFS-L11-1315-T09-C 1 1.51E+05
S CFS-L11-1315-M01-A 1 2.94E+01
S CFS-L11-1315-M02-A 1 2.20E+01
S CFS-L11-1315-M03-A 1 1.82E+01 E
S CFS-L11-1315-M04-A 1 2.13E+01 E
S CFS-L11-1315-M05-A 1 1.32E+01 E
S CFS-L11-1315-M06-A 1 1.01E+01 E
S CFS-L11-1315-M07-A 1 2.03E+01 E
S CFS-L11-1315-M08-A 1 1.60E+01 E
S CFS-L11-1315-M09-A 1 1.34E+01 E
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.26E+03 2.62 6.80 21.60
3.75E+04 1.21 6.80 21.60
4.02E+04 8.74 6.80 21.60 10000 1000
1.13E+05 2.52 6.80 21.60
1.33E+05 1.65 6.80 21.60
1.96E+05 3.56 6.80 21.60
2.02E+05 3.03 6.80 21.60
1.08E+05 1.05 6.80 21.60
1.59E+05 0.97 6.80 21.60
7.51 E+03 0.41 6.80 21.60
3.99E+04 0.38 6.80 21.60
4.26E+04 2.24 6.80 21.60 10000 1000
1.07E+05 0.81 6.80 21.60
1.38E+05 1.58 6.80 21.60
1.95E+05 1.44 6.80 21.60
2.09E+05 1.11 6.80 21.60
1.02E+05 1.32 6.80 21.60
1.60E+05 3.98 6.80 21.60
7.85E+03 0.29 6.80 21.60
3.74E+04 0.39 6.80 21.60
4.05E+04 0.64 6.80 21.60 10000 1000
1.04E+05 0.56 6.80 21.60
1.27E+05 0.75 6.80 21.60
1.96E+05 1.65 6.80 21.60
2.03E+05 1.06 6.80 21.60
1.01E+05 0.58 6.80 21.60
1.51E+05 1.49 6.80 21.60
2.94E+01 0.75 6.80 21.60
2.20E+01 0.99 6.80 21.60
1.82E+01 0.41 6.80 21.60
2.13E+01 1.78 6.80 21.60
1.32E+01 0.59 6.80 21.60
1.01E+01 1.00 6.80 21.60
2.03E+01 1.06 6.80 21.60
1.60E+01 1.50 6.80 21.60
1.34E+01 0.58 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.1 1E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.35E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.14E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L11 1315 CFS
9/16/11 12:11 PM EPA Interlab L11 1315CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12 AM EPA Interlab L11 1315CFS
9/16/11 11:13 AM EPA Interlab L11 1315CFS
9/16/11 11:15 AM EPA Interlab L11 1315CFS
9/16/11 11:17 AM EPA Interlab L11 1315CFS
9/16/11 11:18 AM EPA Interlab L11 1315CFS
9/16/11 11:20 AM EPA Interlab L11 1315CFS
9/16/11 11:22 AM EPA Interlab L11 1315CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315CFS
1-927
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Tl CFS-L11-1315-T01-A 1 4.86E+00 E
Tl CFS-L11-1315-T02-A 1 5.14E+01
Tl CFS-L11-1315-T03-A 1 4.76E+01
Tl CFS-L11-1315-T04-A 1 1.89E+02
Tl CFS-L11-1315-T05-A 1 1.94E+02
Tl CFS-L11-1315-T06-A 1 3.18E+02
Tl CFS-L11-1315-T07-A 1 2.97E+02
Tl CFS-L11-1315-T08-A 1 1.31E+02
Tl CFS-L11-1315-T09-A 1 1.83E+02
Tl CFS-L11-1315-T01-B 1 5.52E+00 E
Tl CFS-L11-1315-T02-B 1 5.22E+01
Tl CFS-L11-1315-T03-B 1 5.18E+01
Tl CFS-L11-1315-T04-B 1 1.63E+02
Tl CFS-L11-1315-T05-B 1 1.92E+02
Tl CFS-L11-1315-T06-B 1 3.10E+02
Tl CFS-L11-1315-T07-B 1 2.98E+02
Tl CFS-L11-1315-T08-B 1 1.28E+02
Tl CFS-L11-1315-T09-B 1 1.79E+02
Tl CFS-L11-1315-T01-C 1 5.02E+00 E
Tl CFS-L11-1315-T02-C 1 4.37E+01
Tl CFS-L11-1315-T03-C 1 5.03E+01
Tl CFS-L11-1315-T04-C 1 1.59E+02
Tl CFS-L11-1315-T05-C 1 1.84E+02
Tl CFS-L11-1315-T06-C 1 3.01 E+02
Tl CFS-L11-1315-T07-C 1 2.92E+02
Tl CFS-L11-1315-T08-C 1 1.21E+02
Tl CFS-L11-1315-T09-C 1 1.69E+02
Tl CFS-L11-1315-M01-A 1 2.30E+00 U1/2
Tl CFS-L11-1315-M02-A 1 2.30E+00 U1/2
Tl CFS-L11-1315-M03-A 1 2.30E+00 U1/2
Tl CFS-L11-1315-M04-A 1 2.30E+00 U1/2
Tl CFS-L11-1315-M05-A 1 2.30E+00 U1/2
Tl CFS-L11-1315-M06-A 1 2.30E+00 U1/2
Tl CFS-L11-1315-M07-A 1 2.30E+00 U1/2
Tl CFS-L11-1315-M08-A 1 2.30E+00 U1/2
Tl CFS-L11-1315-M09-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.86E+00 15.23 4.60 14.60
5.14E+01 3.98 4.60 14.60
4.76E+01 2.00 4.60 14.60 10000 1000
1.89E+02 3.30 4.60 14.60
1.94E+02 3.45 4.60 14.60
3.18E+02 1.46 4.60 14.60
2.97E+02 2.13 4.60 14.60
1.31E+02 6.14 4.60 14.60
1.83E+02 1.75 4.60 14.60
5.52E+00 5.40 4.60 14.60
5.22E+01 3.22 4.60 14.60
5.18E+01 2.06 4.60 14.60 10000 1000
1.63E+02 2.28 4.60 14.60
1.92E+02 4.59 4.60 14.60
3.10E+02 1.44 4.60 14.60
2.98E+02 6.01 4.60 14.60
1.28E+02 2.94 4.60 14.60
1.79E+02 2.58 4.60 14.60
5.02E+00 16.84 4.60 14.60
4.37E+01 5.35 4.60 14.60
5.03E+01 6.81 4.60 14.60 10000 1000
1.59E+02 2.26 4.60 14.60
1.84E+02 4.51 4.60 14.60
3.01E+02 1.23 4.60 14.60
2.92E+02 2.10 4.60 14.60
1.21E+02 3.06 4.60 14.60
1.69E+02 1.12 4.60 14.60
2.30E+00 23.62 4.60 14.60
2.30E+00 5.86 4.60 14.60
2.30E+00 3.29 4.60 14.60
2.30E+00 4.24 4.60 14.60
2.30E+00 2.79 4.60 14.60
2.30E+00 2.84 4.60 14.60
2.30E+00 2.79 4.60 14.60
2.30E+00 0.94 4.60 14.60
2.30E+00 3.12 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.40E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.31E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L11 1315 CFS
9/16/11 12:11 PM EPA Interlab L11 1315 CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12AM EPA Interlab L1 1 1315CFS
9/16/11 11:13 AM EPA Interlab L11 1315CFS
9/16/11 11:15 AM EPA Interlab L11 1315CFS
9/16/11 11:17AM EPA Interlab L1 1 1315CFS
9/16/11 11:18 AM EPA Interlab L11 1315CFS
9/16/11 11:20 AM EPA Interlab L11 1315CFS
9/16/11 11:22 AM EPA Interlab L11 1315CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315CFS
1-928
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ti CFS-L11-1315-T01-A 1 1.00E+00 U1/2
Ti CFS-L11-1315-T02-A 1 1.00E+00 U1/2
Ti CFS-L11-1315-T03-A 1 1.00E+00 U1/2
Ti CFS-L11-1315-T04-A 1 1.00E+00 U1/2
Ti CFS-L11-1315-T05-A 1 1.00E+00 U1/2
Ti CFS-L11-1315-T06-A 1 1.00E+00 U1/2
Ti CFS-L11-1315-T07-A 1 1.00E+00 U1/2
Ti CFS-L11-1315-T08-A 1 1.00E+00 U1/2
Ti CFS-L11-1315-T09-A 1 1.00E+00 U1/2
Ti CFS-L11-1315-T01-B 1 1.00E+00 U1/2
Ti CFS-L11-1315-T02-B 1 1.00E+00 U1/2
Ti CFS-L11-1315-T03-B 1 1.00E+00 U1/2
Ti CFS-L11-1315-T04-B 1 1.00E+00 U1/2
Ti CFS-L11-1315-T05-B 1 1.00E+00 U1/2
Ti CFS-L11-1315-T06-B 1 1.00E+00 U1/2
Ti CFS-L11-1315-T07-B 1 1.00E+00 U1/2
Ti CFS-L11-1315-T08-B 1 1.00E+00 U1/2
Ti CFS-L11-1315-T09-B 1 1.00E+00 U1/2
Ti CFS-L11-1315-T01-C 1 1.00E+00 U1/2
Ti CFS-L11-1315-T02-C 1 1.00E+00 U1/2
Ti CFS-L11-1315-T03-C 1 1.00E+00 U1/2
Ti CFS-L11-1315-T04-C 1 1.00E+00 U1/2
Ti CFS-L11-1315-T05-C 1 1.00E+00 U1/2
Ti CFS-L11-1315-T06-C 1 1.00E+00 U1/2
Ti CFS-L11-1315-T07-C 1 1.00E+00 U1/2
Ti CFS-L11-1315-T08-C 1 1.00E+00 U1/2
Ti CFS-L11-1315-T09-C 1 1.00E+00 U1/2
Ti CFS-L11-1315-M01-A 1 1.00E+00 U1/2
Ti CFS-L11-1315-M02-A 1 1.00E+00 U1/2
Ti CFS-L11-1315-M03-A 1 1.00E+00 U1/2
Ti CFS-L11-1315-M04-A 1 1.00E+00 U1/2
Ti CFS-L11-1315-M05-A 1 1.00E+00 U1/2
Ti CFS-L11-1315-M06-A 1 1.00E+00 U1/2
Ti CFS-L11-1315-M07-A 1 1.00E+00 U1/2
Ti CFS-L11-1315-M08-A 1 1.00E+00 U1/2
Ti CFS-L11-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 52.10 2.00 6.40
1.00E+00 13.80 2.00 6.40
1.00E+00 26.43 2.00 6.40 10000 1000
1.00E+00 32.06 2.00 6.40
1.00E+00 24.76 2.00 6.40
1.00E+00 15.97 2.00 6.40
1.00E+00 43.18 2.00 6.40
1.00E+00 15.48 2.00 6.40
1.00E+00 37.45 2.00 6.40
1.00E+00 37.03 2.00 6.40
1.00E+00 61.95 2.00 6.40
1.00E+00 48.06 2.00 6.40 10000 1000
1.00E+00 28.51 2.00 6.40
1.00E+00 24.21 2.00 6.40
1.00E+00 23.49 2.00 6.40
1.00E+00 25.70 2.00 6.40
1.00E+00 52.52 2.00 6.40
1.00E+00 3.28 2.00 6.40
1.00E+00 23.76 2.00 6.40
1.00E+00 41.17 2.00 6.40
1.00E+00 5.92 2.00 6.40 10000 1000
1.00E+00 24.89 2.00 6.40
1.00E+00 42.01 2.00 6.40
1.00E+00 43.45 2.00 6.40
1.00E+00 20.15 2.00 6.40
1.00E+00 16.12 2.00 6.40
1.00E+00 32.47 2.00 6.40
1.00E+00 41.14 2.00 6.40
1.00E+00 7.53 2.00 6.40
1.00E+00 66.17 2.00 6.40
1.00E+00 39.86 2.00 6.40
1.00E+00 10.88 2.00 6.40
1.00E+00 76.29 2.00 6.40
1.00E+00 81.60 2.00 6.40
1.00E+00 17.59 2.00 6.40
1.00E+00 59.40 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.69E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.59E+02 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.34E+02 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315 CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L11 1315 CFS
9/16/11 12:11 PM EPA Interlab L11 1315 CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12 AM EPA Interlab L11 1315CFS
9/16/11 11:13 AM EPA Interlab L11 1315CFS
9/16/11 11:15 AM EPA Interlab L11 1315CFS
9/16/11 11:17 AM EPA Interlab L11 1315CFS
9/16/11 11:18 AM EPA Interlab L11 1315CFS
9/16/11 11:20 AM EPA Interlab L11 1315CFS
9/16/11 11:22 AM EPA Interlab L11 1315CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315CFS
1-929
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
V CFS-L11-1315-T01-A 1 1.75E+00 E
V CFS-L11-1315-T02-A 1 1.90E+00 E
V CFS-L11-1315-T03-A 1 3.15E+00 E
V CFS-L11-1315-T04-A 1 3.72E+00 E
V CFS-L11-1315-T05-A 1 3.49E+00 E
V CFS-L11-1315-T06-A 1 3.34E+00 E
V CFS-L11-1315-T07-A 1 8.26E+00
V CFS-L11-1315-T08-A 1 5.61E+00
V CFS-L11-1315-T09-A 1 5.36E+00
V CFS-L11-1315-T01-B 1 1.74E+00 E
V CFS-L11-1315-T02-B 1 1.75E+00 E
V CFS-L11-1315-T03-B 1 3.16E+00 E
V CFS-L11-1315-T04-B 1 3.45E+00 E
V CFS-L11-1315-T05-B 1 4.35E+00 E
V CFS-L11-1315-T06-B 1 4.03E+00 E
V CFS-L11-1315-T07-B 1 7.80E+00
V CFS-L11-1315-T08-B 1 3.69E+00 E
V CFS-L11-1315-T09-B 1 4.98E+00
V CFS-L11-1315-T01-C 1 1.61E+00 E
V CFS-L11-1315-T02-C 1 1.65E+00 E
V CFS-L11-1315-T03-C 1 2.69E+00 E
V CFS-L11-1315-T04-C 1 4.28E+00 E
V CFS-L11-1315-T05-C 1 4.05E+00 E
V CFS-L11-1315-T06-C 1 4.17E+00 E
V CFS-L11-1315-T07-C 1 8.10E+00
V CFS-L11-1315-T08-C 1 3.86E+00 E
V CFS-L11-1315-T09-C 1 5.37E+00
V CFS-L11-1315-M01-A 1 7.50E-01 U1/2
V CFS-L11-1315-M02-A 1 7.50E-01 U1/2
V CFS-L11-1315-M03-A 1 7.50E-01 U1/2
V CFS-L11-1315-M04-A 1 7.50E-01 U1/2
V CFS-L11-1315-M05-A 1 7.50E-01 U1/2
V CFS-L11-1315-M06-A 1 7.50E-01 U1/2
V CFS-L11-1315-M07-A 1 7.50E-01 U1/2
V CFS-L11-1315-M08-A 1 7.50E-01 U1/2
V CFS-L11-1315-M09-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.75E+00 26.68 1.50 4.77
1.90E+00 19.25 1.50 4.77
3.15E+00 7.85 1.50 4.77 10000 1000
3.72E+00 12.55 1.50 4.77
3.49E+00 8.22 1.50 4.77
3.34E+00 5.24 1.50 4.77
8.26E+00 7.56 1.50 4.77
5.61 E+00 3.89 1.50 4.77
5.36E+00 2.22 1.50 4.77
1.74E+00 12.53 1.50 4.77
1.75E+00 28.35 1.50 4.77
3.16E+00 14.17 1.50 4.77 10000 1000
3.45E+00 6.31 1.50 4.77
4.35E+00 19.21 1.50 4.77
4.03E+00 5.95 1.50 4.77
7.80E+00 6.89 1.50 4.77
3.69E+00 16.56 1.50 4.77
4.98E+00 2.46 1.50 4.77
1.61 E+00 15.36 1.50 4.77
1.65E+00 9.35 1.50 4.77
2.69E+00 5.26 1.50 4.77 10000 1000
4.28E+00 18.48 1.50 4.77
4.05E+00 6.60 1.50 4.77
4.17E+00 17.29 1.50 4.77
8.10E+00 5.09 1.50 4.77
3.86E+00 4.60 1.50 4.77
5.37E+00 1.22 1.50 4.77
7.50E-01 58.28 1.50 4.77
7.50E-01 12.60 1.50 4.77
7.50E-01 31.56 1.50 4.77
7.50E-01 9.07 1.50 4.77
7.50E-01 14.62 1.50 4.77
7.50E-01 21.66 1.50 4.77
7.50E-01 2.30 1.50 4.77
7.50E-01 20.13 1.50 4.77
7.50E-01 8.43 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.67E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.85E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.73E+02 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1 :50 AM EPA Interlab L1 1 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1 :54 AM EPA Interlab L1 1 1315CFS
9/16/11 1 1 :56 AM EPA Interlab L1 1 1315CFS
9/16/11 1 1 :58 AM EPA Interlab L1 1 1315CFS
9/16/11 1 1 :59 AM EPA Interlab L1 1 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315CFS
9/16/11 12:03 PM EPA Interlab L11 1315CFS
9/16/11 12:04 PM EPA Interlab L11 1315 CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315CFS
9/16/11 12:09 PM EPA Interlab L11 1315 CFS
9/16/11 12:11 PM EPA Interlab L11 1315CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 1 1:12 AM EPA Interlab L11 1315 CFS
9/16/11 11:13 AM EPA Interlab L11 1315 CFS
9/16/11 11:15 AM EPA Interlab L11 1315 CFS
9/16/11 1 1:17 AM EPA Interlab L11 1315 CFS
9/16/11 1 1:18 AM EPA Interlab L11 1315 CFS
9/16/11 11:20 AM EPA Interlab L11 1315 CFS
9/16/11 11:22 AM EPA Interlab L11 1315 CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315 CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315 CFS
1-930
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Zn CFS-L11-1315-T01-A 1 2.23E+02
Zn CFS-L11-1315-T02-A 1 1.24E+03
Zn CFS-L11-1315-T03-A 1 1.51E+03
Zn CFS-L11-1315-T04-A 1 4.97E+03
Zn CFS-L11-1315-T05-A 1 4.58E+03
Zn CFS-L11-1315-T06-A 1 4.29E+03
Zn CFS-L11-1315-T07-A 1 9.82E+03
Zn CFS-L11-1315-T08-A 1 5.98E+03
Zn CFS-L11-1315-T09-A 1 5.83E+03
Zn CFS-L11-1315-T01-B 1 2.02E+02
Zn CFS-L11-1315-T02-B 1 1.46E+03
Zn CFS-L11-1315-T03-B 1 1.63E+03
Zn CFS-L11-1315-T04-B 1 5.23E+03
Zn CFS-L11-1315-T05-B 1 6.37E+03
Zn CFS-L11-1315-T06-B 1 5.32E+03
Zn CFS-L11-1315-T07-B 1 1.05E+04
Zn CFS-L11-1315-T08-B 1 4.11E+03
Zn CFS-L11-1315-T09-B 1 6.32E+03
Zn CFS-L11-1315-T01-C 1 1.85E+02
Zn CFS-L11-1315-T02-C 1 9.47E+02
Zn CFS-L11-1315-T03-C 1 1.62E+03
Zn CFS-L11-1315-T04-C 1 3.67E+03
Zn CFS-L11-1315-T05-C 1 4.28E+03
Zn CFS-L11-1315-T06-C 1 3.89E+03
Zn CFS-L11-1315-T07-C 1 8.22E+03
Zn CFS-L11-1315-T08-C 1 3.38E+03
Zn CFS-L11-1315-T09-C 1 5.05E+03
Zn CFS-L11-1315-M01-A 1 5.00E-01 U1/2
Zn CFS-L11-1315-M02-A 1 5.00E-01 U1/2
Zn CFS-L11-1315-M03-A 1 5.00E-01 U1/2
Zn CFS-L11-1315-M04-A 1 5.00E-01 U1/2
Zn CFS-L11-1315-M05-A 1 5.00E-01 U1/2
Zn CFS-L11-1315-M06-A 1 5.00E-01 U1/2
Zn CFS-L11-1315-M07-A 1 5.00E-01 U1/2
Zn CFS-L11-1315-M08-A 1 5.00E-01 U1/2
Zn CFS-L11-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.23E+02 1.02 1.00 3.18
1.24E+03 1.80 1.00 3.18
1.51E+03 2.79 1.00 3.18 10000 1000
4.97E+03 4.70 1.00 3.18
4.58E+03 1.59 1.00 3.18
4.29E+03 2.11 1.00 3.18
9.82E+03 6.85 1.00 3.18
5.98E+03 6.65 1.00 3.18
5.83E+03 0.93 1.00 3.18
2.02E+02 0.16 1.00 3.18
1.46E+03 1.79 1.00 3.18
1.63E+03 1.95 1.00 3.18 10000 1000
5.23E+03 0.51 1.00 3.18
6.37E+03 0.52 1.00 3.18
5.32E+03 1.29 1.00 3.18
1.05E+04 2.15 1.00 3.18
4.11E+03 2.32 1.00 3.18
6.32E+03 3.13 1.00 3.18
1.85E+02 0.45 1.00 3.18
9.47E+02 1.29 1.00 3.18
1.62E+03 1.29 1.00 3.18 10000 1000
3.67E+03 1.54 1.00 3.18
4.28E+03 2.44 1.00 3.18
3.89E+03 0.84 1.00 3.18
8.22E+03 1.49 1.00 3.18
3.38E+03 0.83 1.00 3.18
5.05E+03 1.45 1.00 3.18
5.00E-01 0.37 1.00 3.18
5.00E-01 0.60 1.00 3.18
5.00E-01 1.91 1.00 3.18
5.00E-01 0.16 1.00 3.18
5.00E-01 0.10 1.00 3.18
5.00E-01 0.04 1.00 3.18
5.00E-01 1.34 1.00 3.18
5.00E-01 1.03 1.00 3.18
5.00E-01 1.24 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.41E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.54E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.59E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
9/16/11 11:26 AM EPA InterlabLH 1315CFS
9/16/11 11:28 AM EPA InterlabLH 1315CFS
9/16/11 11:30 AM EPA Interlab L1 1 1315CFS
9/16/11 11:31 AM EPA Interlab L11 1315CFS
9/16/11 11:33 AM EPA Interlab L11 1315CFS
9/16/11 11:35 AM EPA Interlab L11 1315CFS
9/16/11 1 1:36 AM EPA Interlab L11 1315CFS
9/16/11 1 1:38 AM EPA Interlab L11 1315CFS
9/16/11 11:40 AM EPA Interlab L11 1315CFS
9/16/11 11:46 AM EPA Interlab L11 1315CFS
9/16/11 1 1:48 AM EPA Interlab L11 1315CFS
9/16/11 1 1:50 AM EPA Interlab L11 1315CFS
9/16/11 11:51 AM EPA Interlab L11 1315CFS
9/16/11 11:53 AM EPA Interlab L11 1315CFS
9/16/11 1 1:54 AM EPA Interlab L11 1315CFS
9/16/11 1 1:56 AM EPA Interlab L11 1315CFS
9/16/11 11:58 AM EPA Interlab L11 1315CFS
9/16/11 11:59 AM EPA Interlab L11 1315CFS
9/16/11 12:01 PM EPA Interlab L11 1315 CFS
9/16/11 12:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:04 PM EPA Interlab L11 1315 CFS
9/16/11 1:03 PM EPA Interlab L11 1315 CFS
9/16/11 12:08 PM EPA Interlab L11 1315 CFS
9/16/11 12:09 PM EPA Interlab L11 1315 CFS
9/16/11 12:11 PM EPA Interlab L11 1315CFS
9/16/11 12:13 PM EPA Interlab L11 1315 CFS
9/16/11 12:14 PM EPA Interlab L11 1315 CFS
9/16/11 11:12 AM EPA Interlab L11 1315CFS
9/16/11 11:13 AM EPA Interlab L11 1315CFS
9/16/11 11:15 AM EPA Interlab L11 1315CFS
9/16/11 11:17 AM EPA Interlab L11 1315CFS
9/16/11 11:18 AM EPA Interlab L11 1315CFS
9/16/11 11:20 AM EPA Interlab L11 1315CFS
9/16/11 11:22 AM EPA Interlab L11 1315CFS
9/16/11 1 1:23 AM EPA Interlab L11 1315CFS
9/16/11 1 1:25 AM EPA Interlab L11 1315CFS
1-931
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1315:
Element
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Sample ID
CFS-LRef-1315-T01-A
CFS-LRef-1315-T02-A
CFS-LRef-1315-T03-A
CFS-LRef-1315-T04-A
CFS-LRef-1315-T05-A
CFS-LRef-1315-T06-A
CFS-LRef-1315-T07-A
CFS-LRef-1315-T08-A
CFS-LRef-1315-T09-A
CFS-LRef-1315-T01-B
CFS-LRef-1315-T02-B
CFS-LRef-1315-T03-B
CFS-LRef-1315-T04-B
CFS-LRef-1315-T05-B
CFS-LRef-1315-T06-B
CFS-LRef-1315-T07-B
CFS-LRef-1315-T08-B
CFS-LRef-1315-T09-B
CFS-LRef-1315-T01-C
CFS-LRef-1315-T02-C
CFS-LRef-1315-T03-C
CFS-LRef-1315-T04-C
CFS-LRef-1315-T05-C
CFS-LRef-1315-T06-C
CFS-LRef-1315-T07-C
CFS-LRef-1315-T08-C
CFS-LRef-1315-T09-C
CFS-LRef-1315-M01-A
CFS-LRef-1315-M02-A
CFS-LRef-1315-M03-A
CFS-LRef-1315-M04-A
CFS-LRef-1315-M05-A
CFS-LRef-1315-M06-A
CFS-LRef-1315-M07-A
CFS-LRef-1315-M08-A
CFS-LRef-1315-M09-A
Dilution Sample
Factor Cone. Qualifier
I ug/L I
1 8.02E+00
1 2.06E+01
1 1.85E+01
1 4.37E+01
1 3.99E+01
1 4.82E+01
1 4.66E+01
1 2.56E+01
1 5.30E+01
1 8.74E+00
1 2.28E+01
1 1.95E+01
1 3.44E+01
1 3.72E+01
1 4.69E+01
1 4.27E+01
1 2.75E+01
1 4.52E+01
1 7.06E+00
1 2.28E+01
1 2.05E+01
1 5.03E+01
1 4.29E+01
1 4.55E+01
1 4.85E+01
1 3.38E+01
1 4.37E+01
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
1 5.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.02E+00 8.45 1.00 3.18
2.06E+01 2.61 1.00 3.18
1.85E+01 9.80 1.00 3.18 10000 1000
4.37E+01 5.12 1.00 3.18
3.99E+01 2.27 1.00 3.18
4.82E+01 2.74 1.00 3.18
4.66E+01 5.35 1.00 3.18
2.56E+01 8.49 1.00 3.18
5.30E+01 7.78 1.00 3.18
8.74E+00 1.78 1.00 3.18
2.28E+01 4.11 1.00 3.18
1.95E+01 1.52 1.00 3.18 10000 1000
3.44E+01 3.23 1.00 3.18
3.72E+01 4.48 1.00 3.18
4.69E+01 3.58 1.00 3.18
4.27E+01 1.53 1.00 3.18
2.75E+01 5.37 1.00 3.18
4.52E+01 8.11 1.00 3.18
7.06E+00 10.97 1.00 3.18
2.28E+01 7.62 1.00 3.18
2.05E+01 6.64 1.00 3.18 10000 1000
5.03E+01 4.04 1.00 3.18
4.29E+01 4.78 1.00 3.18
4.55E+01 5.68 1.00 3.18
4.85E+01 0.71 1.00 3.18
3.38E+01 4.28 1.00 3.18
4.37E+01 5.15 1.00 3.18
5.00E-01 23.71 1.00 3.18
5.00E-01 13.90 1.00 3.18
5.00E-01 8.99 1.00 3.18
5.00E-01 13.60 1.00 3.18
5.00E-01 5.85 1.00 3.18
5.00E-01 5.67 1.00 3.18
5.00E-01 20.76 1.00 3.18
5.00E-01 7.29 1.00 3.18
5.00E-01 26.85 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.07E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/11 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:23 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:46 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:56 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:06 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:22 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:32 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:42 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:48 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:08 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:24 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:34 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:44 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:26 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:49 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:59 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:00 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:02 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:41 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:43 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:44 PM EPA Interlab LRef 1315 CFS
1-932
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Sb CFS-LRef-1315-T01-A 1 9.38E+00 E
Sb CFS-LRef-1315-T02-A 1 9.58E+00 E
Sb CFS-LRef-1315-T03-A 1 1.03E+01 E
Sb CFS-LRef-1315-T04-A 1 1.07E+01 E
Sb CFS-LRef-1315-T05-A 1 1.10E+01 E
Sb CFS-LRef-1315-T06-A 1 1.02E+01 E
Sb CFS-LRef-1315-T07-A 1 9.16E+00 E
Sb CFS-LRef-1315-T08-A 1 9.49E+00 E
Sb CFS-LRef-1315-T09-A 1 1.11E+01 E
Sb CFS-LRef-1315-T01-B 1 9.05E+00 E
Sb CFS-LRef-1315-T02-B 1 9.33E+00 E
Sb CFS-LRef-1315-T03-B 1 1.05E+01 E
Sb CFS-LRef-1315-T04-B 1 1.06E+01 E
Sb CFS-LRef-1315-T05-B 1 9.93E+00 E
Sb CFS-LRef-1315-T06-B 1 1.06E+01 E
Sb CFS-LRef-1315-T07-B 1 1.25E+01 E
Sb CFS-LRef-1315-T08-B 1 1.15E+01 E
Sb CFS-LRef-1315-T09-B 1 1.24E+01 E
Sb CFS-LRef-1315-T01-C 1 9.35E+00 E
Sb CFS-LRef-1315-T02-C 1 9.59E+00 E
Sb CFS-LRef-1315-T03-C 1 1.03E+01 E
Sb CFS-LRef-1315-T04-C 1 1.06E+01 E
Sb CFS-LRef-1315-T05-C 1 1.08E+01 E
Sb CFS-LRef-1315-T06-C 1 1.13E+01 E
Sb CFS-LRef-1315-T07-C 1 1.37E+01 E
Sb CFS-LRef-1315-T08-C 1 1.17E+01 E
Sb CFS-LRef-1315-T09-C 1 1.24E+01 E
Sb CFS-LRef-1315-M01-A 1 3.75E+00 U1/2
Sb CFS-LRef-1315-M02-A 1 3.75E+00 U1/2
Sb CFS-LRef-1315-M03-A 1 3.75E+00 U1/2
Sb CFS-LRef-1315-M04-A 1 3.75E+00 U1/2
Sb CFS-LRef-1315-M05-A 1 3.75E+00 U1/2
Sb CFS-LRef-1315-M06-A 1 3.75E+00 U1/2
Sb CFS-LRef-1315-M07-A 1 3.75E+00 U1/2
Sb CFS-LRef-1315-M08-A 1 3.75E+00 U1/2
Sb CFS-LRef-1315-M09-A 1 3.75E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.38E+00 8.26 7.50 23.90
9.58E+00 17.99 7.50 23.90
1.03E+01 19.99 7.50 23.90 10000 1000
1.07E+01 9.73 7.50 23.90
1.10E+01 8.58 7.50 23.90
1.02E+01 6.36 7.50 23.90
9.16E+00 9.19 7.50 23.90
9.49E+00 10.31 7.50 23.90
1.11E+01 22.04 7.50 23.90
9.05E+00 28.33 7.50 23.90
9.33E+00 5.61 7.50 23.90
1.05E+01 11.51 7.50 23.90 10000 1000
1.06E+01 12.54 7.50 23.90
9.93E+00 6.42 7.50 23.90
1.06E+01 8.31 7.50 23.90
1.25E+01 14.14 7.50 23.90
1.15E+01 26.98 7.50 23.90
1.24E+01 14.72 7.50 23.90
9.35E+00 22.31 7.50 23.90
9.59E+00 23.08 7.50 23.90
1.03E+01 10.64 7.50 23.90 10000 1000
1.06E+01 9.48 7.50 23.90
1.08E+01 9.61 7.50 23.90
1.13E+01 5.99 7.50 23.90
1.37E+01 10.21 7.50 23.90
1.17E+01 5.24 7.50 23.90
1.24E+01 1.04 7.50 23.90
3.75E+00 12.10 7.50 23.90
3.75E+00 25.37 7.50 23.90
3.75E+00 36.23 7.50 23.90
3.75E+00 28.40 7.50 23.90
3.75E+00 31.36 7.50 23.90
3.75E+00 33.46 7.50 23.90
3.75E+00 28.93 7.50 23.90
3.75E+00 39.28 7.50 23.90
3.75E+00 40.60 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:23 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:46 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:56 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:06 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:22 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:32 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:42 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:48 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:08 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:24 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:34 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:44 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:26 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:49 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:59 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:00 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:02 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:41 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:43 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:44 PM EPA Interlab LRef 1315 CFS
1-933
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
As CFS-LRef-1315-T01-A 1 5.50E+00 U1/2
As CFS-LRef-1315-T02-A 1 5.50E+00 U1/2
As CFS-LRef-1315-T03-A 1 1.17E+01 E
As CFS-LRef-1315-T04-A 1 1.54E+01 E
As CFS-LRef-1315-T05-A 1 1.77E+01 E
As CFS-LRef-1315-T06-A 1 1.55E+01 E
As CFS-LRef-1315-T07-A 1 1.27E+01 E
As CFS-LRef-1315-T08-A 1 1.13E+01 E
As CFS-LRef-1315-T09-A 1 5.50E+00 U1/2
As CFS-LRef-1315-T01-B 1 5.50E+00 U1/2
As CFS-LRef-1315-T02-B 1 5.50E+00 U1/2
As CFS-LRef-1315-T03-B 1 1.18E+01 E
As CFS-LRef-1315-T04-B 1 1.48E+01 E
As CFS-LRef-1315-T05-B 1 1.71E+01 E
As CFS-LRef-1315-T06-B 1 1.56E+01 E
As CFS-LRef-1315-T07-B 1 1.12E+01 E
As CFS-LRef-1315-T08-B 1 5.50E+00 U1/2
As CFS-LRef-1315-T09-B 1 5.50E+00 U1/2
As CFS-LRef-1315-T01-C 1 5.50E+00 U1/2
As CFS-LRef-1315-T02-C 1 5.50E+00 U1/2
As CFS-LRef-1315-T03-C 1 1.24E+01 E
As CFS-LRef-1315-T04-C 1 1.53E+01 E
As CFS-LRef-1315-T05-C 1 1.63E+01 E
As CFS-LRef-1315-T06-C 1 1.48E+01 E
As CFS-LRef-1315-T07-C 1 1.35E+01 E
As CFS-LRef-1315-T08-C 1 5.50E+00 U1/2
As CFS-LRef-1315-T09-C 1 5.50E+00 U1/2
As CFS-LRef-1315-M01-A 1 5.50E+00 U1/2
As CFS-LRef-1315-M02-A 1 5.50E+00 U1/2
As CFS-LRef-1315-M03-A 1 5.50E+00 U1/2
As CFS-LRef-1315-M04-A 1 5.50E+00 U1/2
As CFS-LRef-1315-M05-A 1 5.50E+00 U1/2
As CFS-LRef-1315-M06-A 1 5.50E+00 U1/2
As CFS-LRef-1315-M07-A 1 5.50E+00 U1/2
As CFS-LRef-1315-M08-A 1 5.50E+00 U1/2
As CFS-LRef-1315-M09-A 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.50E+00 4.04 11.00 35.00
5.50E+00 45.49 11.00 35.00
1.17E+01 29.83 11.00 35.00 10000 1000
1.54E+01 18.50 11.00 35.00
1.77E+01 20.97 11.00 35.00
1.55E+01 26.28 11.00 35.00
1.27E+01 7.78 11.00 35.00
1.13E+01 31.06 11.00 35.00
5.50E+00 34.95 11.00 35.00
5.50E+00 29.91 11.00 35.00
5.50E+00 32.80 11.00 35.00
1.18E+01 22.08 11.00 35.00 10000 1000
1.48E+01 25.97 11.00 35.00
1.71E+01 26.44 11.00 35.00
1.56E+01 1.66 11.00 35.00
1.12E+01 11.61 11.00 35.00
5.50E+00 11.88 11.00 35.00
5.50E+00 4.03 11.00 35.00
5.50E+00 58.22 11.00 35.00
5.50E+00 10.91 11.00 35.00
1.24E+01 28.85 11.00 35.00 10000 1000
1.53E+01 13.99 11.00 35.00
1.63E+01 11.81 11.00 35.00
1.48E+01 37.50 11.00 35.00
1.35E+01 28.14 11.00 35.00
5.50E+00 32.87 11.00 35.00
5.50E+00 33.09 11.00 35.00
5.50E+00 79.80 11.00 35.00
5.50E+00 40.99 11.00 35.00
5.50E+00 13.84 11.00 35.00
5.50E+00 31.33 11.00 35.00
5.50E+00 37.28 11.00 35.00
5.50E+00 105.84 11.00 35.00
5.50E+00 31.54 11.00 35.00
5.50E+00 40.21 11.00 35.00
5.50E+00 20.08 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.94E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.90E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/11 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:23 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:46 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:56 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:06 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:22 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:32 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:42 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:48 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:58 PM EPA Interlab LRef 1315 CFS
6/20/11 5:08 PM EPA Interlab LRef 1315 CFS
6/20/11 3:24 PM EPA Interlab LRef 1315 CFS
6/20/11 3:34 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:44 PM EPA Interlab LRef 1315 CFS
6/20/11 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/11 4:26 PM EPA Interlab LRef 1315 CFS
6/20/11 4:49 PM EPA Interlab LRef 1315 CFS
6/20/11 4:59 PM EPA Interlab LRef 1315 CFS
6/20/11 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/11 3:58 PM EPA Interlab LRef 1315 CFS
6/20/11 4:00 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:02 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:41 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:43 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:44 PM EPA Interlab LRef 1315 CFS
1-934
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
B CFS-LRef-1315-T01-A 1 1.73E+01
B CFS-LRef-1315-T02-A 1 5.62E+01
B CFS-LRef-1315-T03-A 1 4.16E+01
B CFS-LRef-1315-T04-A 1 1.19E+02
B CFS-LRef-1315-T05-A 1 1.26E+02
B CFS-LRef-1315-T06-A 1 1.81E+02
B CFS-LRef-1315-T07-A 1 1.53E+02
B CFS-LRef-1315-T08-A 1 7.52E+01
B CFS-LRef-1315-T09-A 1 1.41E+02
B CFS-LRef-1315-T01-B 1 2.04E+01
B CFS-LRef-1315-T02-B 1 5.37E+01
B CFS-LRef-1315-T03-B 1 4.04E+01
B CFS-LRef-1315-T04-B 1 1.17E+02
B CFS-LRef-1315-T05-B 1 1.22E+02
B CFS-LRef-1315-T06-B 1 1.79E+02
B CFS-LRef-1315-T07-B 1 1.57E+02
B CFS-LRef-1315-T08-B 1 7.91E+01
B CFS-LRef-1315-T09-B 1 1.25E+02
B CFS-LRef-1315-T01-C 1 1.70E+01
B CFS-LRef-1315-T02-C 1 5.54E+01
B CFS-LRef-1315-T03-C 1 4.03E+01
B CFS-LRef-1315-T04-C 1 1.15E+02
B CFS-LRef-1315-T05-C 1 1.19E+02
B CFS-LRef-1315-T06-C 1 1.83E+02
B CFS-LRef-1315-T07-C 1 1.54E+02
B CFS-LRef-1315-T08-C 1 8.16E+01
B CFS-LRef-1315-T09-C 1 1.21E+02
B CFS-LRef-1315-M01-A 1 5.00E-01 U1/2
B CFS-LRef-1315-M02-A 1 5.00E-01 U1/2
B CFS-LRef-1315-M03-A 1 5.00E-01 U1/2
B CFS-LRef-1315-M04-A 1 5.00E-01 U1/2
B CFS-LRef-1315-M05-A 1 5.00E-01 U1/2
B CFS-LRef-1315-M06-A 1 5.00E-01 U1/2
B CFS-LRef-1315-M07-A 1 5.00E-01 U1/2
B CFS-LRef-1315-M08-A 1 5.00E-01 U1/2
B CFS-LRef-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.73E+01 1.47 1.00 3.18
5.62E+01 6.57 1.00 3.18
4.16E+01 3.65 1.00 3.18 10000 1000
1.19E+02 3.64 1.00 3.18
1.26E+02 1.54 1.00 3.18
1.81E+02 1.15 1.00 3.18
1.53E+02 1.61 1.00 3.18
7.52E+01 13.32 1.00 3.18
1.41E+02 2.00 1.00 3.18
2.04E+01 5.19 1.00 3.18
5.37E+01 1.59 1.00 3.18
4.04E+01 1.04 1.00 3.18 10000 1000
1.17E+02 1.57 1.00 3.18
1.22E+02 0.73 1.00 3.18
1.79E+02 2.35 1.00 3.18
1.57E+02 1.52 1.00 3.18
7.91E+01 2.03 1.00 3.18
1.25E+02 1.89 1.00 3.18
1.70E+01 1.62 1.00 3.18
5.54E+01 2.84 1.00 3.18
4.03E+01 3.34 1.00 3.18 10000 1000
1.15E+02 1.30 1.00 3.18
1.19E+02 1.41 1.00 3.18
1.83E+02 2.85 1.00 3.18
1.54E+02 1.19 1.00 3.18
8.16E+01 1.81 1.00 3.18
1.21E+02 5.02 1.00 3.18
5.00E-01 9.69 1.00 3.18
5.00E-01 8.63 1.00 3.18
5.00E-01 2.49 1.00 3.18
5.00E-01 8.23 1.00 3.18
5.00E-01 2.18 1.00 3.18
5.00E-01 3.02 1.00 3.18
5.00E-01 1.82 1.00 3.18
5.00E-01 3.79 1.00 3.18
5.00E-01 2.83 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.98E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/11 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/11 4:23 PM EPA Interlab LRef 1315 CFS
6/20/11 4:46 PM EPA Interlab LRef 1315 CFS
6/20/11 4:56 PM EPA Interlab LRef 1315 CFS
6/20/11 5:06 PM EPA Interlab LRef 1315 CFS
6/20/11 3:22 PM EPA Interlab LRef 1315 CFS
6/20/11 3:32 PM EPA Interlab LRef 1315 CFS
6/20/11 3:42 PM EPA Interlab LRef 1315 CFS
6/20/11 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/11 4:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:48 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:08 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:24 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:34 PM EPA Interlab LRef 1315 CFS
6/20/11 3:44 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:26 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:49 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:59 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:00 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:02 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:41 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:43 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:44 PM EPA Interlab LRef 1315 CFS
1-935
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Ba CFS-LRef-1315-T01-A 1 1.83E+01
Ba CFS-LRef-1315-T02-A 1 1.91E+01
Ba CFS-LRef-1315-T03-A 1 2.36E+01
Ba CFS-LRef-1315-T04-A 1 2.91E+01
Ba CFS-LRef-1315-T05-A 1 3.35E+01
Ba CFS-LRef-1315-T06-A 1 3.73E+01
Ba CFS-LRef-1315-T07-A 1 3.15E+01
Ba CFS-LRef-1315-T08-A 1 2.49E+01
Ba CFS-LRef-1315-T09-A 1 3.36E+01
Ba CFS-LRef-1315-T01-B 1 1.73E+01
Ba CFS-LRef-1315-T02-B 1 1.98E+01
Ba CFS-LRef-1315-T03-B 1 2.38E+01
Ba CFS-LRef-1315-T04-B 1 2.76E+01
Ba CFS-LRef-1315-T05-B 1 3.42E+01
Ba CFS-LRef-1315-T06-B 1 3.80E+01
Ba CFS-LRef-1315-T07-B 1 3.09E+01
Ba CFS-LRef-1315-T08-B 1 2.29E+01
Ba CFS-LRef-1315-T09-B 1 2.86E+01
Ba CFS-LRef-1315-T01-C 1 1.70E+01
Ba CFS-LRef-1315-T02-C 1 1.92E+01
Ba CFS-LRef-1315-T03-C 1 2.34E+01
Ba CFS-LRef-1315-T04-C 1 2.60E+01
Ba CFS-LRef-1315-T05-C 1 3.33E+01
Ba CFS-LRef-1315-T06-C 1 3.73E+01
Ba CFS-LRef-1315-T07-C 1 3.27E+01
Ba CFS-LRef-1315-T08-C 1 2.55E+01
Ba CFS-LRef-1315-T09-C 1 2.97E+01
Ba CFS-LRef-1315-M01-A 1 5.00E-01 U1/2
Ba CFS-LRef-1315-M02-A 1 5.00E-01 U1/2
Ba CFS-LRef-1315-M03-A 1 5.00E-01 U1/2
Ba CFS-LRef-1315-M04-A 1 5.00E-01 U1/2
Ba CFS-LRef-1315-M05-A 1 5.00E-01 U1/2
Ba CFS-LRef-1315-M06-A 1 5.00E-01 U1/2
Ba CFS-LRef-1315-M07-A 1 5.00E-01 U1/2
Ba CFS-LRef-1315-M08-A 1 5.00E-01 U1/2
Ba CFS-LRef-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.83E+01 2.14 1.00 3.18
1.91E+01 1.41 1.00 3.18
2.36E+01 1.26 1.00 3.18 10000 1000
2.91E+01 1.92 1.00 3.18
3.35E+01 1.19 1.00 3.18
3.73E+01 0.70 1.00 3.18
3.15E+01 2.20 1.00 3.18
2.49E+01 2.64 1.00 3.18
3.36E+01 2.53 1.00 3.18
1.73E+01 1.56 1.00 3.18
1.98E+01 0.84 1.00 3.18
2.38E+01 0.71 1.00 3.18 10000 1000
2.76E+01 0.39 1.00 3.18
3.42E+01 2.75 1.00 3.18
3.80E+01 1.52 1.00 3.18
3.09E+01 5.75 1.00 3.18
2.29E+01 2.09 1.00 3.18
2.86E+01 1.34 1.00 3.18
1.70E+01 1.44 1.00 3.18
1.92E+01 1.31 1.00 3.18
2.34E+01 0.72 1.00 3.18 10000 1000
2.60E+01 1.83 1.00 3.18
3.33E+01 2.05 1.00 3.18
3.73E+01 0.19 1.00 3.18
3.27E+01 2.07 1.00 3.18
2.55E+01 0.95 1.00 3.18
2.97E+01 6.55 1.00 3.18
5.00E-01 2.68 1.00 3.18
5.00E-01 1.60 1.00 3.18
5.00E-01 1.18 1.00 3.18
5.00E-01 1.63 1.00 3.18
5.00E-01 6.27 1.00 3.18
5.00E-01 13.77 1.00 3.18
5.00E-01 9.39 1.00 3.18
5.00E-01 18.50 1.00 3.18
5.00E-01 7.66 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.12E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 . 1 1 E+03 1 09% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.09E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/11 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:23 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:46 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:56 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:06 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:22 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:32 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:42 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:48 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:08 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:24 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:34 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:44 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:26 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:49 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:59 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:00 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:02 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:41 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:43 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:44 PM EPA Interlab LRef 1315 CFS
1-936
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Be CFS-LRef-1315-T01-A 1 9.50E-01 U1/2
Be CFS-LRef-1315-T02-A 1 9.50E-01 U1/2
Be CFS-LRef-1315-T03-A 1 9.50E-01 U1/2
Be CFS-LRef-1315-T04-A 1 9.50E-01 U1/2
Be CFS-LRef-1315-T05-A 1 9.50E-01 U1/2
Be CFS-LRef-1315-T06-A 1 9.50E-01 U1/2
Be CFS-LRef-1315-T07-A 1 9.50E-01 U1/2
Be CFS-LRef-1315-T08-A 1 9.50E-01 U1/2
Be CFS-LRef-1315-T09-A 1 9.50E-01 U1/2
Be CFS-LRef-1315-T01-B 1 9.50E-01 U1/2
Be CFS-LRef-1315-T02-B 1 9.50E-01 U1/2
Be CFS-LRef-1315-T03-B 1 9.50E-01 U1/2
Be CFS-LRef-1315-T04-B 1 9.50E-01 U1/2
Be CFS-LRef-1315-T05-B 1 9.50E-01 U1/2
Be CFS-LRef-1315-T06-B 1 9.50E-01 U1/2
Be CFS-LRef-1315-T07-B 1 9.50E-01 U1/2
Be CFS-LRef-1315-T08-B 1 9.50E-01 U1/2
Be CFS-LRef-1315-T09-B 1 9.50E-01 U1/2
Be CFS-LRef-1315-T01-C 1 9.50E-01 U1/2
Be CFS-LRef-1315-T02-C 1 9.50E-01 U1/2
Be CFS-LRef-1315-T03-C 1 9.50E-01 U1/2
Be CFS-LRef-1315-T04-C 1 9.50E-01 U1/2
Be CFS-LRef-1315-T05-C 1 9.50E-01 U1/2
Be CFS-LRef-1315-T06-C 1 9.50E-01 U1/2
Be CFS-LRef-1315-T07-C 1 9.50E-01 U1/2
Be CFS-LRef-1315-T08-C 1 9.50E-01 U1/2
Be CFS-LRef-1315-T09-C 1 9.50E-01 U1/2
Be CFS-LRef-1315-M01-A 1 9.50E-01 U1/2
Be CFS-LRef-1315-M02-A 1 9.50E-01 U1/2
Be CFS-LRef-1315-M03-A 1 9.50E-01 U1/2
Be CFS-LRef-1315-M04-A 1 9.50E-01 U1/2
Be CFS-LRef-1315-M05-A 1 9.50E-01 U1/2
Be CFS-LRef-1315-M06-A 1 9.50E-01 U1/2
Be CFS-LRef-1315-M07-A 1 9.50E-01 U1/2
Be CFS-LRef-1315-M08-A 1 9.50E-01 U1/2
Be CFS-LRef-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 11.23 1.90 6.00
9.50E-01 25.39 1.90 6.00
9.50E-01 37.80 1.90 6.00 10000 1000
9.50E-01 72.30 1.90 6.00
9.50E-01 23.92 1.90 6.00
9.50E-01 47.97 1.90 6.00
9.50E-01 53.08 1.90 6.00
9.50E-01 44.49 1.90 6.00
9.50E-01 47.34 1.90 6.00
9.50E-01 26.14 1.90 6.00
9.50E-01 9.92 1.90 6.00
9.50E-01 8.49 1.90 6.00 10000 1000
9.50E-01 62.75 1.90 6.00
9.50E-01 56.03 1.90 6.00
9.50E-01 48.39 1.90 6.00
9.50E-01 17.52 1.90 6.00
9.50E-01 56.83 1.90 6.00
9.50E-01 49.63 1.90 6.00
9.50E-01 30.73 1.90 6.00
9.50E-01 18.55 1.90 6.00
9.50E-01 56.68 1.90 6.00 10000 1000
9.50E-01 54.11 1.90 6.00
9.50E-01 31.12 1.90 6.00
9.50E-01 16.84 1.90 6.00
9.50E-01 39.55 1.90 6.00
9.50E-01 50.41 1.90 6.00
9.50E-01 30.74 1.90 6.00
9.50E-01 33.81 1.90 6.00
9.50E-01 74.16 1.90 6.00
9.50E-01 49.73 1.90 6.00
9.50E-01 27.26 1.90 6.00
9.50E-01 66.69 1.90 6.00
9.50E-01 17.78 1.90 6.00
9.50E-01 43.92 1.90 6.00
9.50E-01 2.47 1.90 6.00
9.50E-01 31.29 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.03E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:23 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:46 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:56 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:06 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:22 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:32 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:42 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:48 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:08 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:24 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:34 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:44 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:26 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:49 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:59 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:00 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:02 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:41 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:43 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:44 PM EPA Interlab LRef 1315 CFS
1-937
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Cd CFS-LRef-1315-T01-A 1 7.02E+01
Cd CFS-LRef-1315-T02-A 1 4.26E+02
Cd CFS-LRef-1315-T03-A 1 3.74E+02
Cd CFS-LRef-1315-T04-A 1 1.20E+03
Cd CFS-LRef-1315-T05-A 1 1.31E+03
Cd CFS-LRef-1315-T06-A 1 1.81E+03
Cd CFS-LRef-1315-T07-A 1 1.58E+03
Cd CFS-LRef-1315-T08-A 1 8.40E+02
Cd CFS-LRef-1315-T09-A 1 1.52E+03
Cd CFS-LRef-1315-T01-B 1 8.41E+01
Cd CFS-LRef-1315-T02-B 1 4.10E+02
Cd CFS-LRef-1315-T03-B 1 3.77E+02
Cd CFS-LRef-1315-T04-B 1 1.15E+03
Cd CFS-LRef-1315-T05-B 1 1.26E+03
Cd CFS-LRef-1315-T06-B 1 1.79E+03
Cd CFS-LRef-1315-T07-B 1 1.54E+03
Cd CFS-LRef-1315-T08-B 1 8.08E+02
Cd CFS-LRef-1315-T09-B 1 1.34E+03
Cd CFS-LRef-1315-T01-C 1 7.30E+01
Cd CFS-LRef-1315-T02-C 1 4.40E+02
Cd CFS-LRef-1315-T03-C 1 3.60E+02
Cd CFS-LRef-1315-T04-C 1 1.11E+03
Cd CFS-LRef-1315-T05-C 1 1.23E+03
Cd CFS-LRef-1315-T06-C 1 1.88E+03
Cd CFS-LRef-1315-T07-C 1 1.63E+03
Cd CFS-LRef-1315-T08-C 1 8.84E+02
Cd CFS-LRef-1315-T09-C 1 1.31E+03
Cd CFS-LRef-1315-M01-A 1 1.10E+00 U1/2
Cd CFS-LRef-1315-M02-A 1 1.10E+00 U1/2
Cd CFS-LRef-1315-M03-A 1 1.10E+00 U1/2
Cd CFS-LRef-1315-M04-A 1 1.10E+00 U1/2
Cd CFS-LRef-1315-M05-A 1 1.10E+00 U1/2
Cd CFS-LRef-1315-M06-A 1 1.10E+00 U1/2
Cd CFS-LRef-1315-M07-A 1 1.10E+00 U1/2
Cd CFS-LRef-1315-M08-A 1 1.10E+00 U1/2
Cd CFS-LRef-1315-M09-A 1 1.10E+00 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.02E+01 2.60 2.20 7.00
4.26E+02 0.97 2.20 7.00
3.74E+02 1.72 2.20 7.00 10000 1000
1.20E+03 1.88 2.20 7.00
1.31E+03 2.09 2.20 7.00
1.81E+03 0.72 2.20 7.00
1.58E+03 1.50 2.20 7.00
8.40E+02 1.77 2.20 7.00
1.52E+03 2.54 2.20 7.00
8.41 E+01 1.93 2.20 7.00
4.10E+02 1.32 2.20 7.00
3.77E+02 0.89 2.20 7.00 10000 1000
1.15E+03 0.69 2.20 7.00
1.26E+03 1.63 2.20 7.00
1.79E+03 1.69 2.20 7.00
1.54E+03 1.36 2.20 7.00
8.08E+02 0.25 2.20 7.00
1.34E+03 1.03 2.20 7.00
7.30E+01 1.43 2.20 7.00
4.40E+02 1.26 2.20 7.00
3.60E+02 0.77 2.20 7.00 10000 1000
1.11E+03 1.54 2.20 7.00
1.23E+03 1.99 2.20 7.00
1.88E+03 1.25 2.20 7.00
1.63E+03 2.00 2.20 7.00
8.84E+02 1.17 2.20 7.00
1.31E+03 5.88 2.20 7.00
1.10E+00 13.44 2.20 7.00
1.10E+00 4.56 2.20 7.00
1.10E+00 24.61 2.20 7.00
1.10E+00 8.19 2.20 7.00
1.10E+00 20.04 2.20 7.00
1.10E+00 18.72 2.20 7.00
1.10E+00 13.02 2.20 7.00
1.10E+00 23.98 2.20 7.00
1.10E+00 36.76 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.39E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.41E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.34E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/11 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:23 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:46 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:56 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:06 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:22 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:32 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:42 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:48 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:08 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:24 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:34 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:44 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:26 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:49 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:59 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:00 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:02 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:41 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:43 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:44 PM EPA Interlab LRef 1315 CFS
1-938
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Ca CFS-LRef-1315-T01-A 1 1.06E+04
Ca CFS-LRef-1315-T02-A 1 3.88E+04
Ca CFS-LRef-1315-T03-A 1 4.68E+04
Ca CFS-LRef-1315-T04-A 1 8.73E+04
Ca CFS-LRef-1315-T05-A 1 1.02E+05
Ca CFS-LRef-1315-T06-A 1 1.46E+05
Ca CFS-LRef-1315-T07-A 1 1.38E+05
Ca CFS-LRef-1315-T08-A 1 7.77E+04
Ca CFS-LRef-1315-T09-A 1 1.42E+05
Ca CFS-LRef-1315-T01-B 1 9.53E+03
Ca CFS-LRef-1315-T02-B 1 3.69E+04
Ca CFS-LRef-1315-T03-B 1 4.64E+04
Ca CFS-LRef-1315-T04-B 1 8.31E+04
Ca CFS-LRef-1315-T05-B 1 9.86E+04
Ca CFS-LRef-1315-T06-B 1 1.48E+05
Ca CFS-LRef-1315-T07-B 1 1.34E+05
Ca CFS-LRef-1315-T08-B 1 7.43E+04
Ca CFS-LRef-1315-T09-B 1 1.28E+05
Ca CFS-LRef-1315-T01-C 1 9.66E+03
Ca CFS-LRef-1315-T02-C 1 3.58E+04
Ca CFS-LRef-1315-T03-C 1 4.38E+04
Ca CFS-LRef-1315-T04-C 1 7.81E+04
Ca CFS-LRef-1315-T05-C 1 9.46E+04
Ca CFS-LRef-1315-T06-C 1 1.53E+05
Ca CFS-LRef-1315-T07-C 1 1.44E+05
Ca CFS-LRef-1315-T08-C 1 8.16E+04
Ca CFS-LRef-1315-T09-C 1 1.25E+05
Ca CFS-LRef-1315-M01-A 1 6.78E+01
Ca CFS-LRef-1315-M02-A 1 5.38E+01
Ca CFS-LRef-1315-M03-A 1 2.54E+01
Ca CFS-LRef-1315-M04-A 1 3.41E+01
Ca CFS-LRef-1315-M05-A 1 3.70E+01
Ca CFS-LRef-1315-M06-A 1 5.74E+00 E
Ca CFS-LRef-1315-M07-A 1 5.49E+00 E
Ca CFS-LRef-1315-M08-A 1 1.21E+01
Ca CFS-LRef-1315-M09-A 1 2.78E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.06E+04 1.57 2.60 8.30
3.88E+04 0.22 2.60 8.30
4.68E+04 1.43 2.60 8.30 10000 1000
8.73E+04 1.54 2.60 8.30
1.02E+05 2.21 2.60 8.30
1.46E+05 0.97 2.60 8.30
1.38E+05 1.31 2.60 8.30
7.77E+04 1.70 2.60 8.30
1.42E+05 3.02 2.60 8.30
9.53E+03 1.86 2.60 8.30
3.69E+04 1.29 2.60 8.30
4.64E+04 0.77 2.60 8.30 10000 1000
8.31 E+04 0.49 2.60 8.30
9.86E+04 1.52 2.60 8.30
1.48E+05 1.64 2.60 8.30
1.34E+05 2.30 2.60 8.30
7.43E+04 0.29 2.60 8.30
1.28E+05 0.97 2.60 8.30
9.66E+03 2.06 2.60 8.30
3.58E+04 1.79 2.60 8.30
4.38E+04 0.79 2.60 8.30 10000 1000
7.81 E+04 1.79 2.60 8.30
9.46E+04 2.19 2.60 8.30
1.53E+05 1.39 2.60 8.30
1.44E+05 1.85 2.60 8.30
8.16E+04 1.22 2.60 8.30
1.25E+05 5.79 2.60 8.30
6.78E+01 2.06 2.60 8.30
5.38E+01 6.68 2.60 8.30
2.54E+01 1.55 2.60 8.30
3.41 E+01 4.97 2.60 8.30
3.70E+01 1.17 2.60 8.30
5.74E+00 14.44 2.60 8.30
5.49E+00 17.62 2.60 8.30
1.21 E+01 1.48 2.60 8.30
2.78E+01 7.97 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.76E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.72E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.47E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/11 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:23 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:46 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:56 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:06 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:22 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:32 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:42 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:48 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:08 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:24 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:34 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:44 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:26 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:49 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:59 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:00 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:02 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:41 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:43 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:44 PM EPA Interlab LRef 1315 CFS
1-939
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Cr CFS-LRef-1315-T01-A 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T02-A 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T03-A 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T04-A 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T05-A 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T06-A 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T07-A 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T08-A 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T09-A 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T01-B 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T02-B 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T03-B 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T04-B 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T05-B 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T06-B 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T07-B 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T08-B 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T09-B 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T01-C 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T02-C 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T03-C 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T04-C 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T05-C 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T06-C 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T07-C 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T08-C 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T09-C 1 6.00E-01 U1/2
Cr CFS-LRef-1315-M01-A 1 6.00E-01 U1/2
Cr CFS-LRef-1315-M02-A 1 6.00E-01 U1/2
Cr CFS-LRef-1315-M03-A 1 6.00E-01 U1/2
Cr CFS-LRef-1315-M04-A 1 6.00E-01 U1/2
Cr CFS-LRef-1315-M05-A 1 6.00E-01 U1/2
Cr CFS-LRef-1315-M06-A 1 6.00E-01 U1/2
Cr CFS-LRef-1315-M07-A 1 6.00E-01 U1/2
Cr CFS-LRef-1315-M08-A 1 6.00E-01 U1/2
Cr CFS-LRef-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 40.24 1.20 3.82
6.00E-01 75.06 1.20 3.82
6.00E-01 29.99 1.20 3.82 10000 1000
6.00E-01 87.49 1.20 3.82
6.00E-01 69.84 1.20 3.82
6.00E-01 42.88 1.20 3.82
6.00E-01 49.24 1.20 3.82
6.00E-01 64.41 1.20 3.82
6.00E-01 31.18 1.20 3.82
6.00E-01 85.22 1.20 3.82
6.00E-01 10.77 1.20 3.82
6.00E-01 27.35 1.20 3.82 10000 1000
6.00E-01 38.23 1.20 3.82
6.00E-01 42.79 1.20 3.82
6.00E-01 21.10 1.20 3.82
6.00E-01 43.60 1.20 3.82
6.00E-01 47.46 1.20 3.82
6.00E-01 20.15 1.20 3.82
6.00E-01 15.85 1.20 3.82
6.00E-01 59.33 1.20 3.82
6.00E-01 40.71 1.20 3.82 10000 1000
6.00E-01 59.38 1.20 3.82
6.00E-01 12.77 1.20 3.82
6.00E-01 68.24 1.20 3.82
6.00E-01 79.81 1.20 3.82
6.00E-01 124.95 1.20 3.82
6.00E-01 15.11 1.20 3.82
6.00E-01 33.19 1.20 3.82
6.00E-01 83.14 1.20 3.82
6.00E-01 6.01 1.20 3.82
6.00E-01 57.76 1.20 3.82
6.00E-01 27.15 1.20 3.82
6.00E-01 31.87 1.20 3.82
6.00E-01 33.88 1.20 3.82
6.00E-01 48.56 1.20 3.82
6.00E-01 28.70 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.03E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:23 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:46 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:56 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:06 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:22 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:32 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:42 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:48 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:08 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:24 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:34 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:44 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:26 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:49 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:59 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:00 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:02 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:41 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:43 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:44 PM EPA Interlab LRef 1315 CFS
1-940
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L
Co CFS-LRef-1315-T01-A 1 2.39E+00 E
Co CFS-LRef-1315-T02-A 1 1.36E+01
Co CFS-LRef-1315-T03-A 1 1.29E+01
Co CFS-LRef-1315-T04-A 1 3.96E+01
Co CFS-LRef-1315-T05-A 1 4.50E+01
Co CFS-LRef-1315-T06-A 1 6.42E+01
Co CFS-LRef-1315-T07-A 1 5.67E+01
Co CFS-LRef-1315-T08-A 1 3.16E+01
Co CFS-LRef-1315-T09-A 1 5.81E+01
Co CFS-LRef-1315-T01-B 1 2.75E+00 E
Co CFS-LRef-1315-T02-B 1 1.37E+01
Co CFS-LRef-1315-T03-B 1 1.14E+01
Co CFS-LRef-1315-T04-B 1 3.85E+01
Co CFS-LRef-1315-T05-B 1 4.44E+01
Co CFS-LRef-1315-T06-B 1 6.36E+01
Co CFS-LRef-1315-T07-B 1 6.02E+01
Co CFS-LRef-1315-T08-B 1 3.03E+01
Co CFS-LRef-1315-T09-B 1 5.02E+01
Co CFS-LRef-1315-T01-C 1 2.95E+00 E
Co CFS-LRef-1315-T02-C 1 1.59E+01
Co CFS-LRef-1315-T03-C 1 1.33E+01
Co CFS-LRef-1315-T04-C 1 3.95E+01
Co CFS-LRef-1315-T05-C 1 4.37E+01
Co CFS-LRef-1315-T06-C 1 6.95E+01
Co CFS-LRef-1315-T07-C 1 6.31E+01
Co CFS-LRef-1315-T08-C 1 3.40E+01
Co CFS-LRef-1315-T09-C 1 5.16E+01
Co CFS-LRef-1315-M01-A 1 9.00E-01 U1/2
Co CFS-LRef-1315-M02-A 1 9.00E-01 U1/2
Co CFS-LRef-1315-M03-A 1 9.00E-01 U1/2
Co CFS-LRef-1315-M04-A 1 9.00E-01 U1/2
Co CFS-LRef-1315-M05-A 1 9.00E-01 U1/2
Co CFS-LRef-1315-M06-A 1 9.00E-01 U1/2
Co CFS-LRef-1315-M07-A 1 9.00E-01 U1/2
Co CFS-LRef-1315-M08-A 1 9.00E-01 U1/2
Co CFS-LRef-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.39E+00 21.60 1.80 5.72
1.36E+01 9.17 1.80 5.72
1.29E+01 9.75 1.80 5.72 10000 1000
3.96E+01 3.02 1.80 5.72
4.50E+01 1.22 1.80 5.72
6.42E+01 0.80 1.80 5.72
5.67E+01 1.93 1.80 5.72
3.16E+01 3.60 1.80 5.72
5.81 E+01 2.83 1.80 5.72
2.75E+00 15.96 1.80 5.72
1.37E+01 5.42 1.80 5.72
1.14E+01 12.07 1.80 5.72 10000 1000
3.85E+01 1.48 1.80 5.72
4.44E+01 2.75 1.80 5.72
6.36E+01 1.33 1.80 5.72
6.02E+01 5.79 1.80 5.72
3.03E+01 3.13 1.80 5.72
5.02E+01 4.05 1.80 5.72
2.95E+00 12.35 1.80 5.72
1.59E+01 7.23 1.80 5.72
1.33E+01 3.25 1.80 5.72 10000 1000
3.95E+01 1.21 1.80 5.72
4.37E+01 2.29 1.80 5.72
6.95E+01 2.37 1.80 5.72
6.31E+01 3.18 1.80 5.72
3.40E+01 3.10 1.80 5.72
5.16E+01 4.60 1.80 5.72
9.00E-01 21.97 1.80 5.72
9.00E-01 58.51 1.80 5.72
9.00E-01 37.62 1.80 5.72
9.00E-01 19.63 1.80 5.72
9.00E-01 60.77 1.80 5.72
9.00E-01 33.42 1.80 5.72
9.00E-01 13.02 1.80 5.72
9.00E-01 31.55 1.80 5.72
9.00E-01 45.30 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:23 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:46 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:56 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:06 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:22 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:32 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:42 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:48 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:08 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:24 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:34 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:44 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:26 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:49 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:59 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:00 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:02 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:41 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:43 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:44 PM EPA Interlab LRef 1315 CFS
1-941
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Cu CFS-LRef-1315-T01-A 1 1.83E+02
Cu CFS-LRef-1315-T02-A 1 2.70E+02
Cu CFS-LRef-1315-T03-A 1 2.96E+02
Cu CFS-LRef-1315-T04-A 1 5.29E+02
Cu CFS-LRef-1315-T05-A 1 5.16E+02
Cu CFS-LRef-1315-T06-A 1 7.11E+02
Cu CFS-LRef-1315-T07-A 1 7.33E+02
Cu CFS-LRef-1315-T08-A 1 4.88E+02
Cu CFS-LRef-1315-T09-A 1 8.88E+02
Cu CFS-LRef-1315-T01-B 1 1.85E+02
Cu CFS-LRef-1315-T02-B 1 2.75E+02
Cu CFS-LRef-1315-T03-B 1 3.12E+02
Cu CFS-LRef-1315-T04-B 1 4.33E+02
Cu CFS-LRef-1315-T05-B 1 5.01E+02
Cu CFS-LRef-1315-T06-B 1 6.50E+02
Cu CFS-LRef-1315-T07-B 1 7.21E+02
Cu CFS-LRef-1315-T08-B 1 4.84E+02
Cu CFS-LRef-1315-T09-B 1 7.81E+02
Cu CFS-LRef-1315-T01-C 1 1.65E+02
Cu CFS-LRef-1315-T02-C 1 2.28E+02
Cu CFS-LRef-1315-T03-C 1 2.88E+02
Cu CFS-LRef-1315-T04-C 1 4.07E+02
Cu CFS-LRef-1315-T05-C 1 4.61E+02
Cu CFS-LRef-1315-T06-C 1 6.27E+02
Cu CFS-LRef-1315-T07-C 1 6.98E+02
Cu CFS-LRef-1315-T08-C 1 4.89E+02
Cu CFS-LRef-1315-T09-C 1 7.21E+02
Cu CFS-LRef-1315-M01-A 1 1.85E+00 U1/2
Cu CFS-LRef-1315-M02-A 1 1.85E+00 U1/2
Cu CFS-LRef-1315-M03-A 1 1.85E+00 U1/2
Cu CFS-LRef-1315-M04-A 1 1.85E+00 U1/2
Cu CFS-LRef-1315-M05-A 1 1.85E+00 U1/2
Cu CFS-LRef-1315-M06-A 1 1.85E+00 U1/2
Cu CFS-LRef-1315-M07-A 1 1.85E+00 U1/2
Cu CFS-LRef-1315-M08-A 1 1.85E+00 U1/2
Cu CFS-LRef-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.83E+02 2.92 3.70 11.80
2.70E+02 0.69 3.70 11.80
2.96E+02 2.15 3.70 11.80 10000 1000
5.29E+02 1.68 3.70 11.80
5.16E+02 1.17 3.70 11.80
7.11E+02 0.41 3.70 11.80
7.33E+02 0.98 3.70 11.80
4.88E+02 1.26 3.70 11.80
8.88E+02 3.10 3.70 11.80
1.85E+02 3.56 3.70 11.80
2.75E+02 1.62 3.70 11.80
3.12E+02 0.31 3.70 11.80 10000 1000
4.33E+02 1.18 3.70 11.80
5.01 E+02 2.35 3.70 11.80
6.50E+02 1.74 3.70 11.80
7. 21 E+02 1.55 3.70 11.80
4.84E+02 1.79 3.70 11.80
7.81 E+02 0.64 3.70 11.80
1.65E+02 1.23 3.70 11.80
2.28E+02 0.93 3.70 11.80
2.88E+02 0.70 3.70 11.80 10000 1000
4.07E+02 0.55 3.70 11.80
4.61 E+02 1.47 3.70 11.80
6.27E+02 0.82 3.70 11.80
6.98E+02 1.84 3.70 11.80
4.89E+02 1.20 3.70 11.80
7.21 E+02 7.82 3.70 11.80
1.85E+00 1.43 3.70 11.80
1.85E+00 8.62 3.70 11.80
1.85E+00 10.22 3.70 11.80
1.85E+00 11.80 3.70 11.80
1.85E+00 20.50 3.70 11.80
1.85E+00 21.35 3.70 11.80
1.85E+00 43.58 3.70 11.80
1.85E+00 29.22 3.70 11.80
1.85E+00 18.20 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.18E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.25E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.26E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/11 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:23 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:46 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:56 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:06 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:22 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:32 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:42 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:48 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:08 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:24 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:34 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:44 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:26 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:49 PM EPA Interlab LRef 1315 CFS
6/20/11 4:59 PM EPA Interlab LRef 1315 CFS
6/20/11 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/11 3:58 PM EPA Interlab LRef 1315 CFS
6/20/11 4:00 PM EPA Interlab LRef 1315 CFS
6/20/11 4:02 PM EPA Interlab LRef 1315 CFS
6/20/11 4:41 PM EPA Interlab LRef 1315 CFS
6/20/11 4:43 PM EPA Interlab LRef 1315 CFS
6/20/11 4:44 PM EPA Interlab LRef 1315 CFS
1-942
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Fe CFS-LRef-1315-T01-A 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T02-A 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T03-A 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T04-A 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T05-A 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T06-A 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T07-A 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T08-A 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T09-A 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T01-B 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T02-B 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T03-B 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T04-B 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T05-B 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T06-B 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T07-B 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T08-B 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T09-B 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T01-C 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T02-C 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T03-C 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T04-C 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T05-C 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T06-C 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T07-C 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T08-C 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T09-C 1 1.00E+00 U1/2
Fe CFS-LRef-1315-M01-A 1 1.00E+00 U1/2
Fe CFS-LRef-1315-M02-A 1 1.00E+00 U1/2
Fe CFS-LRef-1315-M03-A 1 1.00E+00 U1/2
Fe CFS-LRef-1315-M04-A 1 1.00E+00 U1/2
Fe CFS-LRef-1315-M05-A 1 1.00E+00 U1/2
Fe CFS-LRef-1315-M06-A 1 1.00E+00 U1/2
Fe CFS-LRef-1315-M07-A 1 1.00E+00 U1/2
Fe CFS-LRef-1315-M08-A 1 1.00E+00 U1/2
Fe CFS-LRef-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 19.47 2.00 6.40
1.00E+00 30.34 2.00 6.40
1.00E+00 10.79 2.00 6.40 10000 1000
1.00E+00 1.48 2.00 6.40
1.00E+00 40.67 2.00 6.40
1.00E+00 3.07 2.00 6.40
1.00E+00 10.11 2.00 6.40
1.00E+00 11.77 2.00 6.40
1.00E+00 6.59 2.00 6.40
1.00E+00 8.00 2.00 6.40
1.00E+00 8.17 2.00 6.40
1.00E+00 21.09 2.00 6.40 10000 1000
1.00E+00 11.24 2.00 6.40
1.00E+00 4.06 2.00 6.40
1.00E+00 46.72 2.00 6.40
1.00E+00 9.96 2.00 6.40
1.00E+00 11.76 2.00 6.40
1.00E+00 7.54 2.00 6.40
1.00E+00 26.11 2.00 6.40
1.00E+00 20.13 2.00 6.40
1.00E+00 3.90 2.00 6.40 10000 1000
1.00E+00 13.97 2.00 6.40
1.00E+00 22.29 2.00 6.40
1.00E+00 21.59 2.00 6.40
1.00E+00 16.90 2.00 6.40
1.00E+00 1.75 2.00 6.40
1.00E+00 18.66 2.00 6.40
1.00E+00 16.18 2.00 6.40
1.00E+00 13.71 2.00 6.40
1.00E+00 37.05 2.00 6.40
1.00E+00 11.88 2.00 6.40
1.00E+00 21.97 2.00 6.40
1.00E+00 14.80 2.00 6.40
1.00E+00 18.54 2.00 6.40
1.00E+00 24.75 2.00 6.40
1.00E+00 46.57 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/11 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:23 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:46 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:56 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:06 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:22 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:32 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:42 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/11 4:25 PM EPA Interlab LRef 1315 CFS
6/20/11 4:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:58 PM EPA Interlab LRef 1315 CFS
6/20/11 5:08 PM EPA Interlab LRef 1315 CFS
6/20/11 3:24 PM EPA Interlab LRef 1315 CFS
6/20/11 3:34 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:44 PM EPA Interlab LRef 1315 CFS
6/20/11 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/11 4:26 PM EPA Interlab LRef 1315 CFS
6/20/11 4:49 PM EPA Interlab LRef 1315 CFS
6/20/11 4:59 PM EPA Interlab LRef 1315 CFS
6/20/11 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/11 3:58 PM EPA Interlab LRef 1315 CFS
6/20/11 4:00 PM EPA Interlab LRef 1315 CFS
6/20/11 4:02 PM EPA Interlab LRef 1315 CFS
6/20/11 4:41 PM EPA Interlab LRef 1315 CFS
6/20/11 4:43 PM EPA Interlab LRef 1315 CFS
6/20/11 4:44 PM EPA Interlab LRef 1315 CFS
1-943
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Pb CFS-LRef-1315-T01-A 1 1.26E+02
Pb CFS-LRef-1315-T02-A 1 1.91E+02
Pb CFS-LRef-1315-T03-A 1 2.20E+02
Pb CFS-LRef-1315-T04-A 1 4.69E+02
Pb CFS-LRef-1315-T05-A 1 3.83E+02
Pb CFS-LRef-1315-T06-A 1 5.40E+02
Pb CFS-LRef-1315-T07-A 1 5.11E+02
Pb CFS-LRef-1315-T08-A 1 3.89E+02
Pb CFS-LRef-1315-T09-A 1 6.92E+02
Pb CFS-LRef-1315-T01-B 1 1.14E+02
Pb CFS-LRef-1315-T02-B 1 2.21E+02
Pb CFS-LRef-1315-T03-B 1 2.40E+02
Pb CFS-LRef-1315-T04-B 1 4.03E+02
Pb CFS-LRef-1315-T05-B 1 3.65E+02
Pb CFS-LRef-1315-T06-B 1 4.97E+02
Pb CFS-LRef-1315-T07-B 1 5.25E+02
Pb CFS-LRef-1315-T08-B 1 3.73E+02
Pb CFS-LRef-1315-T09-B 1 5.57E+02
Pb CFS-LRef-1315-T01-C 1 1.04E+02
Pb CFS-LRef-1315-T02-C 1 2.03E+02
Pb CFS-LRef-1315-T03-C 1 2.45E+02
Pb CFS-LRef-1315-T04-C 1 4.03E+02
Pb CFS-LRef-1315-T05-C 1 3.70E+02
Pb CFS-LRef-1315-T06-C 1 5.50E+02
Pb CFS-LRef-1315-T07-C 1 5.42E+02
Pb CFS-LRef-1315-T08-C 1 3.80E+02
Pb CFS-LRef-1315-T09-C 1 5.09E+02
Pb CFS-LRef-1315-M01-A 1 3.40E+00 U1/2
Pb CFS-LRef-1315-M02-A 1 3.40E+00 U1/2
Pb CFS-LRef-1315-M03-A 1 3.40E+00 U1/2
Pb CFS-LRef-1315-M04-A 1 3.40E+00 U1/2
Pb CFS-LRef-1315-M05-A 1 3.40E+00 U1/2
Pb CFS-LRef-1315-M06-A 1 3.40E+00 U1/2
Pb CFS-LRef-1315-M07-A 1 3.40E+00 U1/2
Pb CFS-LRef-1315-M08-A 1 3.40E+00 U1/2
Pb CFS-LRef-1315-M09-A 1 3.40E+00 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.26E+02 1.40 6.80 21.60
1.91E+02 2.97 6.80 21.60
2.20E+02 2.76 6.80 21.60 10000 1000
4.69E+02 0.94 6.80 21.60
3.83E+02 3.51 6.80 21.60
5.40E+02 1.69 6.80 21.60
5.11E+02 2.19 6.80 21.60
3.89E+02 1.55 6.80 21.60
6.92E+02 2.56 6.80 21.60
1.14E+02 0.38 6.80 21.60
2.21E+02 2.87 6.80 21.60
2.40E+02 1.99 6.80 21.60 10000 1000
4.03E+02 0.38 6.80 21.60
3.65E+02 1.77 6.80 21.60
4.97E+02 2.00 6.80 21.60
5.25E+02 5.95 6.80 21.60
3.73E+02 1.14 6.80 21.60
5.57E+02 2.68 6.80 21.60
1.04E+02 2.73 6.80 21.60
2.03E+02 1.22 6.80 21.60
2.45E+02 2.50 6.80 21.60 10000 1000
4.03E+02 1.45 6.80 21.60
3.70E+02 1.62 6.80 21.60
5.50E+02 1.17 6.80 21.60
5.42E+02 1.16 6.80 21.60
3.80E+02 1.31 6.80 21.60
5.09E+02 5.46 6.80 21.60
3.40E+00 18.61 6.80 21.60
3.40E+00 19.42 6.80 21.60
3.40E+00 16.20 6.80 21.60
3.40E+00 7.55 6.80 21.60
3.40E+00 7.40 6.80 21.60
3.40E+00 10.62 6.80 21.60
3.40E+00 8.37 6.80 21.60
3.40E+00 12.84 6.80 21.60
3.40E+00 21.75 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.14E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.19E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.21E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/11 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:23 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:46 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:56 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:06 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:22 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:32 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:42 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:48 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:08 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:24 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:34 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:44 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:26 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:49 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:59 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:00 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:02 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:41 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:43 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:44 PM EPA Interlab LRef 1315 CFS
1-944
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Li CFS-LRef-1315-T01-A 1 2.09E+00 E
Li CFS-LRef-1315-T02-A 1 3.56E+00 E
Li CFS-LRef-1315-T03-A 1 3.28E+00 E
Li CFS-LRef-1315-T04-A 1 7.58E+00
Li CFS-LRef-1315-T05-A 1 7.22E+00
Li CFS-LRef-1315-T06-A 1 8.96E+00
Li CFS-LRef-1315-T07-A 1 7.98E+00
Li CFS-LRef-1315-T08-A 1 6.66E+00
Li CFS-LRef-1315-T09-A 1 1.03E+01
Li CFS-LRef-1315-T01-B 1 2.17E+00 E
Li CFS-LRef-1315-T02-B 1 3.13E+00 E
Li CFS-LRef-1315-T03-B 1 3.14E+00 E
Li CFS-LRef-1315-T04-B 1 7.51E+00
Li CFS-LRef-1315-T05-B 1 8.56E+00
Li CFS-LRef-1315-T06-B 1 7.65E+00
Li CFS-LRef-1315-T07-B 1 7.63E+00
Li CFS-LRef-1315-T08-B 1 7.17E+00
Li CFS-LRef-1315-T09-B 1 8.95E+00
Li CFS-LRef-1315-T01-C 1 2.08E+00 E
Li CFS-LRef-1315-T02-C 1 2.59E+00 E
Li CFS-LRef-1315-T03-C 1 3.37E+00 E
Li CFS-LRef-1315-T04-C 1 6.75E+00
Li CFS-LRef-1315-T05-C 1 8.71E+00
Li CFS-LRef-1315-T06-C 1 7.19E+00
Li CFS-LRef-1315-T07-C 1 7.74E+00
Li CFS-LRef-1315-T08-C 1 7.86E+00
Li CFS-LRef-1315-T09-C 1 8.19E+00
Li CFS-LRef-1315-M01-A 1 9.50E-01 U1/2
Li CFS-LRef-1315-M02-A 1 9.50E-01 U1/2
Li CFS-LRef-1315-M03-A 1 9.50E-01 U1/2
Li CFS-LRef-1315-M04-A 1 9.50E-01 U1/2
Li CFS-LRef-1315-M05-A 1 9.50E-01 U1/2
Li CFS-LRef-1315-M06-A 1 9.50E-01 U1/2
Li CFS-LRef-1315-M07-A 1 9.50E-01 U1/2
Li CFS-LRef-1315-M08-A 1 9.50E-01 U1/2
Li CFS-LRef-1315-M09-A 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.09E+00 15.98 1.90 6.00
3.56E+00 24.52 1.90 6.00
3.28E+00 16.41 1.90 6.00 10000 1000
7.58E+00 2.49 1.90 6.00
7.22E+00 4.94 1.90 6.00
8.96E+00 2.91 1.90 6.00
7.98E+00 5.46 1.90 6.00
6.66E+00 1.97 1.90 6.00
1.03E+01 3.27 1.90 6.00
2.17E+00 4.53 1.90 6.00
3.13E+00 26.42 1.90 6.00
3.14E+00 39.82 1.90 6.00 10000 1000
7.51 E+00 4.98 1.90 6.00
8.56E+00 4.12 1.90 6.00
7.65E+00 3.80 1.90 6.00
7.63E+00 13.41 1.90 6.00
7.17E+00 9.01 1.90 6.00
8.95E+00 4.65 1.90 6.00
2.08E+00 19.14 1.90 6.00
2.59E+00 29.81 1.90 6.00
3.37E+00 16.53 1.90 6.00 10000 1000
6.75E+00 2.63 1.90 6.00
8.71 E+00 3.02 1.90 6.00
7.19E+00 3.34 1.90 6.00
7.74E+00 4.64 1.90 6.00
7.86E+00 3.11 1.90 6.00
8.19E+00 3.82 1.90 6.00
9.50E-01 8.10 1.90 6.00
9.50E-01 10.74 1.90 6.00
9.50E-01 42.77 1.90 6.00
9.50E-01 37.64 1.90 6.00
9.50E-01 21.52 1.90 6.00
9.50E-01 14.67 1.90 6.00
9.50E-01 35.70 1.90 6.00
9.50E-01 41.46 1.90 6.00
9.50E-01 10.58 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.91 E+02 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.85E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.70E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:23 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:46 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:56 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:06 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:22 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:32 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:42 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:48 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:08 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:24 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:34 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:44 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:26 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:49 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:59 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:00 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:02 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:41 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:43 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:44 PM EPA Interlab LRef 1315 CFS
1-945
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualil
1 1 1 M9/L
Mn CFS-LRef-1315-T01-A 1 4.06E+01
Mn CFS-LRef-1315-T02-A 1 3.15E+02
Mn CFS-LRef-1315-T03-A 1 2.67E+02
Mn CFS-LRef-1315-T04-A 1 9.26E+02
Mn CFS-LRef-1315-T05-A 1 1.06E+03
Mn CFS-LRef-1315-T06-A 1 1.67E+03
Mn CFS-LRef-1315-T07-A 1 1.58E+03
Mn CFS-LRef-1315-T08-A 1 8.59E+02
Mn CFS-LRef-1315-T09-A 1 1.66E+03
Mn CFS-LRef-1315-T01-B 1 5.88E+01
Mn CFS-LRef-1315-T02-B 1 3.14E+02
Mn CFS-LRef-1315-T03-B 1 2.77E+02
Mn CFS-LRef-1315-T04-B 1 9.20E+02
Mn CFS-LRef-1315-T05-B 1 1.05E+03
Mn CFS-LRef-1315-T06-B 1 1.70E+03
Mn CFS-LRef-1315-T07-B 1 1.63E+03
Mn CFS-LRef-1315-T08-B 1 8.13E+02
Mn CFS-LRef-1315-T09-B 1 1.46E+03
Mn CFS-LRef-1315-T01-C 1 4.89E+01
Mn CFS-LRef-1315-T02-C 1 3.78E+02
Mn CFS-LRef-1315-T03-C 1 3.04E+02
Mn CFS-LRef-1315-T04-C 1 1.01E+03
Mn CFS-LRef-1315-T05-C 1 1.20E+03
Mn CFS-LRef-1315-T06-C 1 1.95E+03
Mn CFS-LRef-1315-T07-C 1 1.86E+03
Mn CFS-LRef-1315-T08-C 1 9.97E+02
Mn CFS-LRef-1315-T09-C 1 1.59E+03
Mn CFS-LRef-1315-M01-A 1 1.00E+00 U1/2
Mn CFS-LRef-1315-M02-A 1 1.00E+00 U1/2
Mn CFS-LRef-1315-M03-A 1 1.00E+00 U1/2
Mn CFS-LRef-1315-M04-A 1 1.00E+00 U1/2
Mn CFS-LRef-1315-M05-A 1 1.00E+00 U1/2
Mn CFS-LRef-1315-M06-A 1 1.00E+00 U1/2
Mn CFS-LRef-1315-M07-A 1 1.00E+00 U1/2
Mn CFS-LRef-1315-M08-A 1 1.00E+00 U1/2
Mn CFS-LRef-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
ier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.06E+01 2.25 2.00 6.40
3.15E+02 1.05 2.00 6.40
2.67E+02 1.31 2.00 6.40 10000 1000
9.26E+02 1.30 2.00 6.40
1.06E+03 0.19 2.00 6.40
1.67E+03 1.21 2.00 6.40
1.58E+03 0.80 2.00 6.40
8.59E+02 0.49 2.00 6.40
1.66E+03 0.73 2.00 6.40
5.88E+01 1.95 2.00 6.40
3.14E+02 1.30 2.00 6.40
2.77E+02 0.53 2.00 6.40 10000 1000
9.20E+02 0.46 2.00 6.40
1.05E+03 0.70 2.00 6.40
1.70E+03 1.52 2.00 6.40
1.63E+03 1.50 2.00 6.40
8.13E+02 1.61 2.00 6.40
1.46E+03 1.37 2.00 6.40
4.89E+01 1.33 2.00 6.40
3.78E+02 1.19 2.00 6.40
3.04E+02 2.30 2.00 6.40 10000 1000
1.01E+03 2.26 2.00 6.40
1.20E+03 2.47 2.00 6.40
1.95E+03 0.45 2.00 6.40
1.86E+03 2.03 2.00 6.40
9.97E+02 0.82 2.00 6.40
1.59E+03 12.19 2.00 6.40
1.00E+00 0.64 2.00 6.40
1.00E+00 1.84 2.00 6.40
1.00E+00 1.73 2.00 6.40
1.00E+00 13.62 2.00 6.40
1.00E+00 8.92 2.00 6.40
1.00E+00 3.83 2.00 6.40
1.00E+00 23.81 2.00 6.40
1.00E+00 14.43 2.00 6.40
1.00E+00 20.42 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.20E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.32E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.26E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/11 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:23 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:46 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:56 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:06 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:22 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:32 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:42 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:48 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:08 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:24 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:34 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:44 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:26 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:49 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:59 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:00 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:02 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:41 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:43 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:44 PM EPA Interlab LRef 1315 CFS
1-946
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Mg CFS-LRef-1315-T01-A 1 2.78E+03
Mg CFS-LRef-1315-T02-A 1 2.11E+04
Mg CFS-LRef-1315-T03-A 1 1.70E+04
Mg CFS-LRef-1315-T04-A 1 6.01E+04
Mg CFS-LRef-1315-T05-A 1 6.51E+04
Mg CFS-LRef-1315-T06-A 1 9.51E+04
Mg CFS-LRef-1315-T07-A 1 8.36E+04
Mg CFS-LRef-1315-T08-A 1 4.13E+04
Mg CFS-LRef-1315-T09-A 1 7.29E+04
Mg CFS-LRef-1315-T01-B 1 4.22E+03
Mg CFS-LRef-1315-T02-B 1 2.06E+04
Mg CFS-LRef-1315-T03-B 1 1.73E+04
Mg CFS-LRef-1315-T04-B 1 5.83E+04
Mg CFS-LRef-1315-T05-B 1 6.38E+04
Mg CFS-LRef-1315-T06-B 1 9.31E+04
Mg CFS-LRef-1315-T07-B 1 8.15E+04
Mg CFS-LRef-1315-T08-B 1 3.99E+04
Mg CFS-LRef-1315-T09-B 1 6.69E+04
Mg CFS-LRef-1315-T01-C 1 3.43E+03
Mg CFS-LRef-1315-T02-C 1 2.51E+04
Mg CFS-LRef-1315-T03-C 1 1.81E+04
Mg CFS-LRef-1315-T04-C 1 5.86E+04
Mg CFS-LRef-1315-T05-C 1 6.34E+04
Mg CFS-LRef-1315-T06-C 1 9.43E+04
Mg CFS-LRef-1315-T07-C 1 8.20E+04
Mg CFS-LRef-1315-T08-C 1 4.11E+04
Mg CFS-LRef-1315-T09-C 1 6.18E+04
Mg CFS-LRef-1315-M01-A 1 1.53E+01
Mg CFS-LRef-1315-M02-A 1 1.05E+01
Mg CFS-LRef-1315-M03-A 1 5.00E-01 U1/2
Mg CFS-LRef-1315-M04-A 1 5.00E-01 U1/2
Mg CFS-LRef-1315-M05-A 1 5.00E-01 U1/2
Mg CFS-LRef-1315-M06-A 1 5.00E-01 U1/2
Mg CFS-LRef-1315-M07-A 1 5.00E-01 U1/2
Mg CFS-LRef-1315-M08-A 1 5.00E-01 U1/2
Mg CFS-LRef-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.78E+03 2.03 1.00 3.18
2.11E+04 0.68 1.00 3.18
1.70E+04 1.65 1.00 3.18 10000 1000
6.01E+04 1.67 1.00 3.18
6.51E+04 2.85 1.00 3.18
9.51E+04 1.23 1.00 3.18
8.36E+04 1.62 1.00 3.18
4.13E+04 0.83 1.00 3.18
7.29E+04 2.22 1.00 3.18
4.22E+03 2.05 1.00 3.18
2.06E+04 2.00 1.00 3.18
1.73E+04 0.49 1.00 3.18 10000 1000
5.83E+04 0.62 1.00 3.18
6.38E+04 1.44 1.00 3.18
9.31E+04 0.72 1.00 3.18
8.15E+04 1.52 1.00 3.18
3.99E+04 0.62 1.00 3.18
6.69E+04 0.62 1.00 3.18
3.43E+03 1.51 1.00 3.18
2.51E+04 2.33 1.00 3.18
1.81E+04 1.18 1.00 3.18 10000 1000
5.86E+04 1.69 1.00 3.18
6.34E+04 2.60 1.00 3.18
9.43E+04 0.56 1.00 3.18
8.20E+04 0.54 1.00 3.18
4.11E+04 0.78 1.00 3.18
6.18E+04 5.20 1.00 3.18
1.53E+01 2.88 1.00 3.18
1.05E+01 1.34 1.00 3.18
5.00E-01 1.44 1.00 3.18
5.00E-01 2.20 1.00 3.18
5.00E-01 4.86 1.00 3.18
5.00E-01 15.66 1.00 3.18
5.00E-01 32.28 1.00 3.18
5.00E-01 4.00 1.00 3.18
5.00E-01 2.15 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.78E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.83E+04 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.89E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/11 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:23 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:46 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:56 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:06 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:22 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:32 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:42 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:48 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:08 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:24 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:34 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:44 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:26 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:49 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:59 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:00 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:02 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:41 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:43 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:44 PM EPA Interlab LRef 1315 CFS
1-947
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Mo CFS-LRef-1315-T01-A 1 1.54E+00 E
Mo CFS-LRef-1315-T02-A 1 2.49E+00 E
Mo CFS-LRef-1315-T03-A 1 2.24E+00 E
Mo CFS-LRef-1315-T04-A 1 2.83E+00 E
Mo CFS-LRef-1315-T05-A 1 3.22E+00 E
Mo CFS-LRef-1315-T06-A 1 2.81E+00 E
Mo CFS-LRef-1315-T07-A 1 2.22E+00 E
Mo CFS-LRef-1315-T08-A 1 2.24E+00 E
Mo CFS-LRef-1315-T09-A 1 2.01 E+00 E
Mo CFS-LRef-1315-T01-B 1 1.23E+00 E
Mo CFS-LRef-1315-T02-B 1 2.41E+00 E
Mo CFS-LRef-1315-T03-B 1 1.90E+00 E
Mo CFS-LRef-1315-T04-B 1 2.79E+00 E
Mo CFS-LRef-1315-T05-B 1 3.19E+00 E
Mo CFS-LRef-1315-T06-B 1 3.07E+00 E
Mo CFS-LRef-1315-T07-B 1 2.86E+00 E
Mo CFS-LRef-1315-T08-B 1 2.48E+00 E
Mo CFS-LRef-1315-T09-B 1 2.16E+00 E
Mo CFS-LRef-1315-T01-C 1 1.60E+00 E
Mo CFS-LRef-1315-T02-C 1 1.88E+00 E
Mo CFS-LRef-1315-T03-C 1 2.54E+00 E
Mo CFS-LRef-1315-T04-C 1 3.04E+00 E
Mo CFS-LRef-1315-T05-C 1 3.25E+00 E
Mo CFS-LRef-1315-T06-C 1 2.80E+00 E
Mo CFS-LRef-1315-T07-C 1 2.37E+00 E
Mo CFS-LRef-1315-T08-C 1 2.09E+00 E
Mo CFS-LRef-1315-T09-C 1 1.87E+00 E
Mo CFS-LRef-1315-M01-A 1 6.00E-01 U1/2
Mo CFS-LRef-1315-M02-A 1 6.00E-01 U1/2
Mo CFS-LRef-1315-M03-A 1 6.00E-01 U1/2
Mo CFS-LRef-1315-M04-A 1 6.00E-01 U1/2
Mo CFS-LRef-1315-M05-A 1 6.00E-01 U1/2
Mo CFS-LRef-1315-M06-A 1 6.00E-01 U1/2
Mo CFS-LRef-1315-M07-A 1 6.00E-01 U1/2
Mo CFS-LRef-1315-M08-A 1 6.00E-01 U1/2
Mo CFS-LRef-1315-M09-A 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.54E+00 2.96 1.20 3.82
2.49E+00 27.15 1.20 3.82
2.24E+00 9.87 1.20 3.82 10000 1000
2.83E+00 12.24 1.20 3.82
3.22E+00 33.18 1.20 3.82
2.81 E+00 7.82 1.20 3.82
2.22E+00 29.42 1.20 3.82
2.24E+00 7.83 1.20 3.82
2.01 E+00 2.59 1.20 3.82
1.23E+00 39.06 1.20 3.82
2. 41 E+00 25.77 1.20 3.82
1.90E+00 13.75 1.20 3.82 10000 1000
2.79E+00 15.19 1.20 3.82
3.19E+00 11.13 1.20 3.82
3.07E+00 10.05 1.20 3.82
2.86E+00 9.54 1.20 3.82
2.48E+00 30.22 1.20 3.82
2.16E+00 18.54 1.20 3.82
1.60E+00 102.33 1.20 3.82
1.88E+00 16.03 1.20 3.82
2.54E+00 27.26 1.20 3.82 10000 1000
3.04E+00 4.41 1.20 3.82
3.25E+00 31.03 1.20 3.82
2.80E+00 17.93 1.20 3.82
2.37E+00 13.83 1.20 3.82
2.09E+00 2.63 1.20 3.82
1.87E+00 4.34 1.20 3.82
6.00E-01 113.95 1.20 3.82
6.00E-01 32.47 1.20 3.82
6.00E-01 32.78 1.20 3.82
6.00E-01 28.16 1.20 3.82
6.00E-01 52.16 1.20 3.82
6.00E-01 22.64 1.20 3.82
6.00E-01 18.21 1.20 3.82
6.00E-01 46.71 1.20 3.82
6.00E-01 57.82 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.88E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.92E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:23 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:46 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:56 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:06 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:22 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:32 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:42 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:48 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:08 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:24 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:34 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:44 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:26 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:49 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:59 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:00 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:02 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:41 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:43 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:44 PM EPA Interlab LRef 1315 CFS
1-948
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Ni CFS-LRef-1315-T01-A 1 5.54E+00 E
Ni CFS-LRef-1315-T02-A 1 2.38E+01
Ni CFS-LRef-1315-T03-A 1 2.00E+01
Ni CFS-LRef-1315-T04-A 1 6.76E+01
Ni CFS-LRef-1315-T05-A 1 7.56E+01
Ni CFS-LRef-1315-T06-A 1 1.05E+02
Ni CFS-LRef-1315-T07-A 1 9.24E+01
Ni CFS-LRef-1315-T08-A 1 4.26E+01
Ni CFS-LRef-1315-T09-A 1 8.10E+01
Ni CFS-LRef-1315-T01-B 1 6.55E+00
Ni CFS-LRef-1315-T02-B 1 2.34E+01
Ni CFS-LRef-1315-T03-B 1 2.12E+01
Ni CFS-LRef-1315-T04-B 1 6.76E+01
Ni CFS-LRef-1315-T05-B 1 7.20E+01
Ni CFS-LRef-1315-T06-B 1 1.02E+02
Ni CFS-LRef-1315-T07-B 1 8.42E+01
Ni CFS-LRef-1315-T08-B 1 4.43E+01
Ni CFS-LRef-1315-T09-B 1 7.17E+01
Ni CFS-LRef-1315-T01-C 1 5.26E+00 E
Ni CFS-LRef-1315-T02-C 1 2.53E+01
Ni CFS-LRef-1315-T03-C 1 1.97E+01
Ni CFS-LRef-1315-T04-C 1 6.30E+01
Ni CFS-LRef-1315-T05-C 1 6.80E+01
Ni CFS-LRef-1315-T06-C 1 1.02E+02
Ni CFS-LRef-1315-T07-C 1 8.80E+01
Ni CFS-LRef-1315-T08-C 1 4.74E+01
Ni CFS-LRef-1315-T09-C 1 6.78E+01
Ni CFS-LRef-1315-M01-A 1 9.00E-01 U1/2
Ni CFS-LRef-1315-M02-A 1 9.00E-01 U1/2
Ni CFS-LRef-1315-M03-A 1 9.00E-01 U1/2
Ni CFS-LRef-1315-M04-A 1 9.00E-01 U1/2
Ni CFS-LRef-1315-M05-A 1 9.00E-01 U1/2
Ni CFS-LRef-1315-M06-A 1 9.00E-01 U1/2
Ni CFS-LRef-1315-M07-A 1 9.00E-01 U1/2
Ni CFS-LRef-1315-M08-A 1 9.00E-01 U1/2
Ni CFS-LRef-1315-M09-A 1 9.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.54E+00 12.79 1.80 5.70
2.38E+01 3.71 1.80 5.70
2.00E+01 8.65 1.80 5.70 10000 1000
6.76E+01 1.75 1.80 5.70
7.56E+01 3.30 1.80 5.70
1.05E+02 1.55 1.80 5.70
9.24E+01 3.38 1.80 5.70
4.26E+01 5.23 1.80 5.70
8.10E+01 4.77 1.80 5.70
6.55E+00 6.60 1.80 5.70
2.34E+01 3.35 1.80 5.70
2.12E+01 3.82 1.80 5.70 10000 1000
6.76E+01 4.08 1.80 5.70
7.20E+01 3.99 1.80 5.70
1.02E+02 2.31 1.80 5.70
8.42E+01 1.51 1.80 5.70
4.43E+01 0.43 1.80 5.70
7.17E+01 1.27 1.80 5.70
5.26E+00 18.89 1.80 5.70
2.53E+01 7.09 1.80 5.70
1.97E+01 12.67 1.80 5.70 10000 1000
6.30E+01 0.88 1.80 5.70
6.80E+01 0.41 1.80 5.70
1.02E+02 1.84 1.80 5.70
8.80E+01 1.27 1.80 5.70
4.74E+01 8.83 1.80 5.70
6.78E+01 6.80 1.80 5.70
9.00E-01 27.54 1.80 5.70
9.00E-01 7.09 1.80 5.70
9.00E-01 5.12 1.80 5.70
9.00E-01 40.69 1.80 5.70
9.00E-01 16.31 1.80 5.70
9.00E-01 5.88 1.80 5.70
9.00E-01 37.94 1.80 5.70
9.00E-01 28.59 1.80 5.70
9.00E-01 7.82 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:23 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:46 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:56 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:06 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:22 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:32 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:42 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:48 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:08 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:24 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:34 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:44 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:26 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:49 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:59 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:00 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:02 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:41 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:43 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:44 PM EPA Interlab LRef 1315 CFS
1-949
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
P CFS-LRef-1315-T01-A 1 4.21E+00 E
P CFS-LRef-1315-T02-A 1 1.05E+01 E
P CFS-LRef-1315-T03-A 1 1.06E+01 E
P CFS-LRef-1315-T04-A 1 1.14E+01 E
P CFS-LRef-1315-T05-A 1 9.01E+00 E
P CFS-LRef-1315-T06-A 1 9.00E+00 E
P CFS-LRef-1315-T07-A 1 8.35E+00 E
P CFS-LRef-1315-T08-A 1 6.80E+00 E
P CFS-LRef-1315-T09-A 1 5.36E+00 E
P CFS-LRef-1315-T01-B 1 5.70E+00 E
P CFS-LRef-1315-T02-B 1 1.52E+01
P CFS-LRef-1315-T03-B 1 1.52E+01
P CFS-LRef-1315-T04-B 1 1.23E+01
P CFS-LRef-1315-T05-B 1 9.22E+00 E
P CFS-LRef-1315-T06-B 1 8.55E+00 E
P CFS-LRef-1315-T07-B 1 8.17E+00 E
P CFS-LRef-1315-T08-B 1 6.13E+00 E
P CFS-LRef-1315-T09-B 1 5.81E+00 E
P CFS-LRef-1315-T01-C 1 5.62E+00 E
P CFS-LRef-1315-T02-C 1 1.08E+01 E
P CFS-LRef-1315-T03-C 1 1.14E+01 E
P CFS-LRef-1315-T04-C 1 1.06E+01 E
P CFS-LRef-1315-T05-C 1 9.10E+00 E
P CFS-LRef-1315-T06-C 1 8.13E+00 E
P CFS-LRef-1315-T07-C 1 8.15E+00 E
P CFS-LRef-1315-T08-C 1 6.45E+00 E
P CFS-LRef-1315-T09-C 1 6.71E+00 E
P CFS-LRef-1315-M01-A 1 1.85E+00 U1/2
P CFS-LRef-1315-M02-A 1 1.85E+00 U1/2
P CFS-LRef-1315-M03-A 1 1.85E+00 U1/2
P CFS-LRef-1315-M04-A 1 1.85E+00 U1/2
P CFS-LRef-1315-M05-A 1 1.85E+00 U1/2
P CFS-LRef-1315-M06-A 1 1.85E+00 U1/2
P CFS-LRef-1315-M07-A 1 1.85E+00 U1/2
P CFS-LRef-1315-M08-A 1 1.85E+00 U1/2
P CFS-LRef-1315-M09-A 1 1.85E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.21 E+00 27.30 3.70 11.80
1.05E+01 10.20 3.70 11.80
1.06E+01 29.92 3.70 11.80 10000 1000
1.14E+01 33.12 3.70 11.80
9.01 E+00 11.42 3.70 11.80
9.00E+00 12.18 3.70 11.80
8.35E+00 9.83 3.70 11.80
6.80E+00 24.35 3.70 11.80
5.36E+00 39.03 3.70 11.80
5.70E+00 2.27 3.70 11.80
1.52E+01 1.71 3.70 11.80
1.52E+01 3.25 3.70 11.80 10000 1000
1.23E+01 3.81 3.70 11.80
9.22E+00 5.04 3.70 11.80
8.55E+00 14.36 3.70 11.80
8.17E+00 5.85 3.70 11.80
6.13E+00 26.74 3.70 11.80
5.81 E+00 21.68 3.70 11.80
5.62E+00 11.62 3.70 11.80
1.08E+01 16.02 3.70 11.80
1.14E+01 34.98 3.70 11.80 10000 1000
1.06E+01 6.72 3.70 11.80
9.10E+00 7.51 3.70 11.80
8.13E+00 31.21 3.70 11.80
8.15E+00 31.30 3.70 11.80
6.45E+00 31.00 3.70 11.80
6.71E+00 27.14 3.70 11.80
1.85E+00 56.53 3.70 11.80
1.85E+00 27.31 3.70 11.80
1.85E+00 54.33 3.70 11.80
1.85E+00 25.10 3.70 11.80
1.85E+00 16.89 3.70 11.80
1.85E+00 40.74 3.70 11.80
1.85E+00 33.23 3.70 11.80
1.85E+00 72.19 3.70 11.80
1.85E+00 39.50 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.67E+02 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.89E+02 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/11 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:23 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:46 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:56 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:06 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:22 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:32 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:42 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:48 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:08 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:24 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:34 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:44 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:26 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:49 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:59 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:00 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:02 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:41 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:43 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:44 PM EPA Interlab LRef 1315 CFS
1-950
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
K CFS-LRef-1315-T01-A 1 2.77E+02
K CFS-LRef-1315-T02-A 1 2.66E+03
K CFS-LRef-1315-T03-A 1 1.78E+03
K CFS-LRef-1315-T04-A 1 6.41E+03
K CFS-LRef-1315-T05-A 1 6.60E+03
K CFS-LRef-1315-T06-A 1 9.50E+03
K CFS-LRef-1315-T07-A 1 7.96E+03
K CFS-LRef-1315-T08-A 1 3.69E+03
K CFS-LRef-1315-T09-A 1 6.85E+03
K CFS-LRef-1315-T01-B 1 3.65E+02
K CFS-LRef-1315-T02-B 1 2.65E+03
K CFS-LRef-1315-T03-B 1 1.82E+03
K CFS-LRef-1315-T04-B 1 6.39E+03
K CFS-LRef-1315-T05-B 1 6.59E+03
K CFS-LRef-1315-T06-B 1 9.52E+03
K CFS-LRef-1315-T07-B 1 8.11E+03
K CFS-LRef-1315-T08-B 1 3.58E+03
K CFS-LRef-1315-T09-B 1 6.00E+03
K CFS-LRef-1315-T01-C 1 3.21E+02
K CFS-LRef-1315-T02-C 1 2.85E+03
K CFS-LRef-1315-T03-C 1 1.80E+03
K CFS-LRef-1315-T04-C 1 6.47E+03
K CFS-LRef-1315-T05-C 1 6.47E+03
K CFS-LRef-1315-T06-C 1 9.93E+03
K CFS-LRef-1315-T07-C 1 8.10E+03
K CFS-LRef-1315-T08-C 1 3.90E+03
K CFS-LRef-1315-T09-C 1 5.79E+03
K CFS-LRef-1315-M01-A 1 3.74E+01
K CFS-LRef-1315-M02-A 1 2.57E+01
K CFS-LRef-1315-M03-A 1 2.69E+01
K CFS-LRef-1315-M04-A 1 2.07E+01
K CFS-LRef-1315-M05-A 1 2.43E+01
K CFS-LRef-1315-M06-A 1 1.36E+01
K CFS-LRef-1315-M07-A 1 1.79E+01
K CFS-LRef-1315-M08-A 1 1.02E+01
K CFS-LRef-1315-M09-A 1 1.30E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.77E+02 3.31 1.60 5.09
2.66E+03 0.66 1.60 5.09
1.78E+03 1.83 1.60 5.09 10000 1000
6.41E+03 1.62 1.60 5.09
6.60E+03 2.07 1.60 5.09
9.50E+03 0.84 1.60 5.09
7.96E+03 1.83 1.60 5.09
3.69E+03 1.72 1.60 5.09
6.85E+03 2.98 1.60 5.09
3.65E+02 1.60 1.60 5.09
2.65E+03 1.29 1.60 5.09
1.82E+03 0.60 1.60 5.09 10000 1000
6.39E+03 0.39 1.60 5.09
6.59E+03 1.60 1.60 5.09
9.52E+03 1.43 1.60 5.09
8.11E+03 1.91 1.60 5.09
3.58E+03 0.49 1.60 5.09
6.00E+03 0.89 1.60 5.09
3.21E+02 0.19 1.60 5.09
2.85E+03 1.35 1.60 5.09
1.80E+03 0.89 1.60 5.09 10000 1000
6.47E+03 1.90 1.60 5.09
6.47E+03 2.00 1.60 5.09
9.93E+03 1.27 1.60 5.09
8.10E+03 2.08 1.60 5.09
3.90E+03 1.59 1.60 5.09
5.79E+03 6.07 1.60 5.09
3.74E+01 3.43 1.60 5.09
2.57E+01 4.66 1.60 5.09
2.69E+01 4.92 1.60 5.09
2.07E+01 2.02 1.60 5.09
2.43E+01 2.30 1.60 5.09
1.36E+01 3.24 1.60 5.09
1.79E+01 4.22 1.60 5.09
1.02E+01 6.83 1.60 5.09
1.30E+01 1.12 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.65E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.76E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.75E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/11 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/11 4:23 PM EPA Interlab LRef 1315 CFS
6/20/11 4:46 PM EPA Interlab LRef 1315 CFS
6/20/11 4:56 PM EPA Interlab LRef 1315 CFS
6/20/11 5:06 PM EPA Interlab LRef 1315 CFS
6/20/11 3:22 PM EPA Interlab LRef 1315 CFS
6/20/11 3:32 PM EPA Interlab LRef 1315 CFS
6/20/11 3:42 PM EPA Interlab LRef 1315 CFS
6/20/11 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/11 4:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:48 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:08 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:24 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:34 PM EPA Interlab LRef 1315 CFS
6/20/11 3:44 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:26 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:49 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:59 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:00 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:02 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:41 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:43 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:44 PM EPA Interlab LRef 1315 CFS
1-951
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Se CFS-LRef-1315-T01-A 1 1.59E+01 E
Se CFS-LRef-1315-T02-A 1 2.12E+01 E
Se CFS-LRef-1315-T03-A 1 3.30E+01 E
Se CFS-LRef-1315-T04-A 1 7.17E+01
Se CFS-LRef-1315-T05-A 1 7.04E+01
Se CFS-LRef-1315-T06-A 1 1.04E+02
Se CFS-LRef-1315-T07-A 1 8.68E+01
Se CFS-LRef-1315-T08-A 1 3.97E+01 E
Se CFS-LRef-1315-T09-A 1 4.06E+01 E
Se CFS-LRef-1315-T01-B 1 1.55E+01 E
Se CFS-LRef-1315-T02-B 1 1.74E+01 E
Se CFS-LRef-1315-T03-B 1 2.65E+01 E
Se CFS-LRef-1315-T04-B 1 6.83E+01
Se CFS-LRef-1315-T05-B 1 6.75E+01
Se CFS-LRef-1315-T06-B 1 9.33E+01
Se CFS-LRef-1315-T07-B 1 7.24E+01
Se CFS-LRef-1315-T08-B 1 4.59E+01 E
Se CFS-LRef-1315-T09-B 1 4.51E+01 E
Se CFS-LRef-1315-T01-C 1 1.60E+01 E
Se CFS-LRef-1315-T02-C 1 1.67E+01 E
Se CFS-LRef-1315-T03-C 1 3.18E+01 E
Se CFS-LRef-1315-T04-C 1 6.45E+01
Se CFS-LRef-1315-T05-C 1 5.97E+01
Se CFS-LRef-1315-T06-C 1 9.52E+01
Se CFS-LRef-1315-T07-C 1 6.79E+01
Se CFS-LRef-1315-T08-C 1 3.69E+01 E
Se CFS-LRef-1315-T09-C 1 4.81E+01
Se CFS-LRef-1315-M01-A 1 7.50E+00 U1/2
Se CFS-LRef-1315-M02-A 1 7.50E+00 U1/2
Se CFS-LRef-1315-M03-A 1 7.50E+00 U1/2
Se CFS-LRef-1315-M04-A 1 7.50E+00 U1/2
Se CFS-LRef-1315-M05-A 1 7.50E+00 U1/2
Se CFS-LRef-1315-M06-A 1 7.50E+00 U1/2
Se CFS-LRef-1315-M07-A 1 7.50E+00 U1/2
Se CFS-LRef-1315-M08-A 1 7.50E+00 U1/2
Se CFS-LRef-1315-M09-A 1 7.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.59E+01 18.57 15.00 47.70
2.12E+01 28.77 15.00 47.70
3.30E+01 16.84 15.00 47.70 10000 1000
7.17E+01 4.11 15.00 47.70
7.04E+01 9.51 15.00 47.70
1.04E+02 5.56 15.00 47.70
8.68E+01 4.37 15.00 47.70
3.97E+01 10.21 15.00 47.70
4.06E+01 25.67 15.00 47.70
1.55E+01 19.82 15.00 47.70
1.74E+01 8.70 15.00 47.70
2.65E+01 15.77 15.00 47.70 10000 1000
6.83E+01 4.00 15.00 47.70
6.75E+01 1.47 15.00 47.70
9.33E+01 5.01 15.00 47.70
7.24E+01 8.50 15.00 47.70
4.59E+01 23.42 15.00 47.70
4.51E+01 17.81 15.00 47.70
1.60E+01 6.35 15.00 47.70
1.67E+01 9.58 15.00 47.70
3.18E+01 11.61 15.00 47.70 10000 1000
6.45E+01 7.76 15.00 47.70
5.97E+01 2.89 15.00 47.70
9.52E+01 10.72 15.00 47.70
6.79E+01 9.62 15.00 47.70
3.69E+01 10.51 15.00 47.70
4.81E+01 2.54 15.00 47.70
7.50E+00 25.56 15.00 47.70
7.50E+00 19.12 15.00 47.70
7.50E+00 32.06 15.00 47.70
7.50E+00 11.07 15.00 47.70
7.50E+00 6.42 15.00 47.70
7.50E+00 9.20 15.00 47.70
7.50E+00 17.13 15.00 47.70
7.50E+00 10.96 15.00 47.70
7.50E+00 8.59 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:23 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:46 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:56 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:06 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:22 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:32 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:42 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:48 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:08 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:24 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:34 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:44 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:26 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:49 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:59 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:00 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:02 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:41 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:43 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:44 PM EPA Interlab LRef 1315 CFS
1-952
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Si CFS-LRef-1315-T01-A 1 5.52E+01
Si CFS-LRef-1315-T02-A 1 3.06E+02
Si CFS-LRef-1315-T03-A 1 3.35E+02
Si CFS-LRef-1315-T04-A 1 9.42E+02
Si CFS-LRef-1315-T05-A 1 1.08E+03
Si CFS-LRef-1315-T06-A 1 1.58E+03
Si CFS-LRef-1315-T07-A 1 1.51E+03
Si CFS-LRef-1315-T08-A 1 8.39E+02
Si CFS-LRef-1315-T09-A 1 1.58E+03
Si CFS-LRef-1315-T01-B 1 6.70E+01
Si CFS-LRef-1315-T02-B 1 2.90E+02
Si CFS-LRef-1315-T03-B 1 3.39E+02
Si CFS-LRef-1315-T04-B 1 8.88E+02
Si CFS-LRef-1315-T05-B 1 1.04E+03
Si CFS-LRef-1315-T06-B 1 1.55E+03
Si CFS-LRef-1315-T07-B 1 1.54E+03
Si CFS-LRef-1315-T08-B 1 8.18E+02
Si CFS-LRef-1315-T09-B 1 1.41E+03
Si CFS-LRef-1315-T01-C 1 6.64E+01
Si CFS-LRef-1315-T02-C 1 2.94E+02
Si CFS-LRef-1315-T03-C 1 3.24E+02
Si CFS-LRef-1315-T04-C 1 8.45E+02
Si CFS-LRef-1315-T05-C 1 9.71E+02
Si CFS-LRef-1315-T06-C 1 1.53E+03
Si CFS-LRef-1315-T07-C 1 1.46E+03
Si CFS-LRef-1315-T08-C 1 8.50E+02
Si CFS-LRef-1315-T09-C 1 1.30E+03
Si CFS-LRef-1315-M01-A 1 8.31E+01
Si CFS-LRef-1315-M02-A 1 7.13E+01
Si CFS-LRef-1315-M03-A 1 5.67E+01
Si CFS-LRef-1315-M04-A 1 6.21E+01
Si CFS-LRef-1315-M05-A 1 4.53E+01
Si CFS-LRef-1315-M06-A 1 2.72E+01
Si CFS-LRef-1315-M07-A 1 3.88E+01
Si CFS-LRef-1315-M08-A 1 2.55E+01
Si CFS-LRef-1315-M09-A 1 1.89E+01
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.52E+01 1.75 1.10 3.50
3.06E+02 0.33 1.10 3.50
3.35E+02 2.31 1.10 3.50 10000 1000
9.42E+02 2.55 1.10 3.50
1.08E+03 2.12 1.10 3.50
1.58E+03 1.22 1.10 3.50
1.51E+03 1.25 1.10 3.50
8.39E+02 1.89 1.10 3.50
1.58E+03 2.41 1.10 3.50
6.70E+01 2.68 1.10 3.50
2.90E+02 0.90 1.10 3.50
3.39E+02 0.90 1.10 3.50 10000 1000
8.88E+02 0.57 1.10 3.50
1.04E+03 0.92 1.10 3.50
1.55E+03 1.67 1.10 3.50
1.54E+03 1.54 1.10 3.50
8.18E+02 0.76 1.10 3.50
1.41E+03 1.12 1.10 3.50
6.64E+01 1.95 1.10 3.50
2.94E+02 1.70 1.10 3.50
3.24E+02 1.53 1.10 3.50 10000 1000
8.45E+02 1.38 1.10 3.50
9.71E+02 1.15 1.10 3.50
1.53E+03 1.70 1.10 3.50
1.46E+03 2.31 1.10 3.50
8.50E+02 0.84 1.10 3.50
1.30E+03 6.47 1.10 3.50
8.31 E+01 3.28 1.10 3.50
7.13E+01 2.08 1.10 3.50
5.67E+01 0.77 1.10 3.50
6.21 E+01 1.90 1.10 3.50
4.53E+01 7.16 1.10 3.50
2.72E+01 14.60 1.10 3.50
3.88E+01 15.06 1.10 3.50
2.55E+01 18.03 1.10 3.50
1.89E+01 15.56 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.32E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.34E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.37E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/11 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:23 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:46 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:56 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:06 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:22 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:32 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:42 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:48 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:08 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:24 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:34 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:44 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:26 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:49 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:59 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:00 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:02 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:41 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:43 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:44 PM EPA Interlab LRef 1315 CFS
1-953
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Na CFS-LRef-1315-T01-A 1 1.27E+03
Na CFS-LRef-1315-T02-A 1 1.11E+04
Na CFS-LRef-1315-T03-A 1 7.54E+03
Na CFS-LRef-1315-T04-A 1 2.60E+04
Na CFS-LRef-1315-T05-A 1 2.50E+04
Na CFS-LRef-1315-T06-A 1 3.46E+04
Na CFS-LRef-1315-T07-A 1 2.72E+04
Na CFS-LRef-1315-T08-A 1 1.24E+04
Na CFS-LRef-1315-T09-A 1 2.10E+04
Na CFS-LRef-1315-T01-B 1 1.83E+03
Na CFS-LRef-1315-T02-B 1 1.09E+04
Na CFS-LRef-1315-T03-B 1 7.60E+03
Na CFS-LRef-1315-T04-B 1 2.56E+04
Na CFS-LRef-1315-T05-B 1 2.47E+04
Na CFS-LRef-1315-T06-B 1 3.46E+04
Na CFS-LRef-1315-T07-B 1 2.61E+04
Na CFS-LRef-1315-T08-B 1 1.20E+04
Na CFS-LRef-1315-T09-B 1 1.86E+04
Na CFS-LRef-1315-T01-C 1 1.54E+03
Na CFS-LRef-1315-T02-C 1 1.23E+04
Na CFS-LRef-1315-T03-C 1 7.49E+03
Na CFS-LRef-1315-T04-C 1 2.51E+04
Na CFS-LRef-1315-T05-C 1 2.46E+04
Na CFS-LRef-1315-T06-C 1 3.50E+04
Na CFS-LRef-1315-T07-C 1 2.68E+04
Na CFS-LRef-1315-T08-C 1 1.23E+04
Na CFS-LRef-1315-T09-C 1 1.77E+04
Na CFS-LRef-1315-M01-A 1 4.03E+01
Na CFS-LRef-1315-M02-A 1 3.45E+01
Na CFS-LRef-1315-M03-A 1 1.85E+01
Na CFS-LRef-1315-M04-A 1 2.66E+01
Na CFS-LRef-1315-M05-A 1 3.67E+01
Na CFS-LRef-1315-M06-A 1 1.79E+01
Na CFS-LRef-1315-M07-A 1 1.73E+01
Na CFS-LRef-1315-M08-A 1 1.54E+01
Na CFS-LRef-1315-M09-A 1 3.22E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.27E+03 1.45 2.50 8.00
1.11E+04 0.41 2.50 8.00
7.54E+03 0.61 2.50 8.00 10000 1000
2.60E+04 0.74 2.50 8.00
2.50E+04 0.82 2.50 8.00
3.46E+04 0.67 2.50 8.00
2.72E+04 0.26 2.50 8.00
1.24E+04 1.13 2.50 8.00
2.10E+04 0.70 2.50 8.00
1.83E+03 1.19 2.50 8.00
1.09E+04 0.61 2.50 8.00
7.60E+03 0.16 2.50 8.00 10000 1000
2.56E+04 0.64 2.50 8.00
2.47E+04 0.39 2.50 8.00
3.46E+04 0.24 2.50 8.00
2.61E+04 1.00 2.50 8.00
1.20E+04 0.90 2.50 8.00
1.86E+04 0.87 2.50 8.00
1.54E+03 0.47 2.50 8.00
1.23E+04 0.81 2.50 8.00
7.49E+03 0.39 2.50 8.00 10000 1000
2.51E+04 1.10 2.50 8.00
2.46E+04 0.60 2.50 8.00
3.50E+04 0.86 2.50 8.00
2.68E+04 0.94 2.50 8.00
1.23E+04 0.89 2.50 8.00
1.77E+04 2.74 2.50 8.00
4.03E+01 1.52 2.50 8.00
3.45E+01 0.64 2.50 8.00
1.85E+01 3.39 2.50 8.00
2.66E+01 2.64 2.50 8.00
3.67E+01 0.73 2.50 8.00
1.79E+01 1.42 2.50 8.00
1.73E+01 1.00 2.50 8.00
1.54E+01 2.20 2.50 8.00
3.22E+01 3.33 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.47E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.46E+03 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.37E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/11 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:23 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:46 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:56 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:06 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:22 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:32 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:42 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:48 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:08 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:24 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:34 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:44 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:26 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:49 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:59 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:00 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:02 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:41 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:43 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:44 PM EPA Interlab LRef 1315 CFS
1-954
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Sr CFS-LRef-1315-T01-A 1 2.87E+01
Sr CFS-LRef-1315-T02-A 1 1.37E+02
Sr CFS-LRef-1315-T03-A 1 1.21E+02
Sr CFS-LRef-1315-T04-A 1 4.03E+02
Sr CFS-LRef-1315-T05-A 1 4.79E+02
Sr CFS-LRef-1315-T06-A 1 7.60E+02
Sr CFS-LRef-1315-T07-A 1 7.49E+02
Sr CFS-LRef-1315-T08-A 1 5.26E+02
Sr CFS-LRef-1315-T09-A 1 7.49E+02
Sr CFS-LRef-1315-T01-B 1 3.66E+01
Sr CFS-LRef-1315-T02-B 1 1.36E+02
Sr CFS-LRef-1315-T03-B 1 1.25E+02
Sr CFS-LRef-1315-T04-B 1 3.93E+02
Sr CFS-LRef-1315-T05-B 1 4.67E+02
Sr CFS-LRef-1315-T06-B 1 7.57E+02
Sr CFS-LRef-1315-T07-B 1 7.15E+02
Sr CFS-LRef-1315-T08-B 1 3.93E+02
Sr CFS-LRef-1315-T09-B 1 6.83E+02
Sr CFS-LRef-1315-T01-C 1 3.06E+01
Sr CFS-LRef-1315-T02-C 1 1.48E+02
Sr CFS-LRef-1315-T03-C 1 1.24E+02
Sr CFS-LRef-1315-T04-C 1 3.91E+02
Sr CFS-LRef-1315-T05-C 1 4.63E+02
Sr CFS-LRef-1315-T06-C 1 7.68E+02
Sr CFS-LRef-1315-T07-C 1 7.30E+02
Sr CFS-LRef-1315-T08-C 1 4.03E+02
Sr CFS-LRef-1315-T09-C 1 6.23E+02
Sr CFS-LRef-1315-M01-A 1 5.00E-01 U1/2
Sr CFS-LRef-1315-M02-A 1 5.00E-01 U1/2
Sr CFS-LRef-1315-M03-A 1 5.00E-01 U1/2
Sr CFS-LRef-1315-M04-A 1 5.00E-01 U1/2
Sr CFS-LRef-1315-M05-A 1 5.00E-01 U1/2
Sr CFS-LRef-1315-M06-A 1 5.00E-01 U1/2
Sr CFS-LRef-1315-M07-A 1 5.00E-01 U1/2
Sr CFS-LRef-1315-M08-A 1 5.00E-01 U1/2
Sr CFS-LRef-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.87E+01 1.56 1.00 3.18
1.37E+02 0.31 1.00 3.18
1.21E+02 0.96 1.00 3.18 10000 1000
4.03E+02 1.45 1.00 3.18
4.79E+02 2.10 1.00 3.18
7.60E+02 0.26 1.00 3.18
7.49E+02 2.01 1.00 3.18
5.26E+02 1.84 1.00 3.18
7.49E+02 1.39 1.00 3.18
3.66E+01 1.48 1.00 3.18
1.36E+02 1.41 1.00 3.18
1.25E+02 0.76 1.00 3.18 10000 1000
3.93E+02 0.14 1.00 3.18
4.67E+02 1.16 1.00 3.18
7.57E+02 2.39 1.00 3.18
7.15E+02 5.16 1.00 3.18
3.93E+02 0.59 1.00 3.18
6.83E+02 0.95 1.00 3.18
3.06E+01 1.51 1.00 3.18
1.48E+02 1.59 1.00 3.18
1.24E+02 1.05 1.00 3.18 10000 1000
3.91E+02 1.97 1.00 3.18
4.63E+02 2.34 1.00 3.18
7.68E+02 2.43 1.00 3.18
7.30E+02 2.61 1.00 3.18
4.03E+02 1.43 1.00 3.18
6.23E+02 5.88 1.00 3.18
5.00E-01 9.49 1.00 3.18
5.00E-01 1.35 1.00 3.18
5.00E-01 2.89 1.00 3.18
5.00E-01 8.00 1.00 3.18
5.00E-01 38.51 1.00 3.18
5.00E-01 35.36 1.00 3.18
5.00E-01 30.19 1.00 3.18
5.00E-01 18.78 1.00 3.18
5.00E-01 168.97 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.08E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.17E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.15E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/11 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/11 4:23 PM EPA Interlab LRef 1315 CFS
6/20/11 4:46 PM EPA Interlab LRef 1315 CFS
6/20/11 4:56 PM EPA Interlab LRef 1315 CFS
6/20/11 5:06 PM EPA Interlab LRef 1315 CFS
6/20/11 3:22 PM EPA Interlab LRef 1315 CFS
6/20/11 3:32 PM EPA Interlab LRef 1315 CFS
6/20/11 3:42 PM EPA Interlab LRef 1315 CFS
6/20/11 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/11 4:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:48 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:08 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:24 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:34 PM EPA Interlab LRef 1315 CFS
6/20/11 3:44 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:26 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:49 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:59 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:00 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:02 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:41 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:43 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:44 PM EPA Interlab LRef 1315 CFS
1-955
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
S CFS-LRef-1315-T01-A 1 7.76E+03
S CFS-LRef-1315-T02-A 1 5.18E+04
S CFS-LRef-1315-T03-A 1 4.38E+04
S CFS-LRef-1315-T04-A 1 1.54E+05
S CFS-LRef-1315-T05-A 1 1.71E+05
S CFS-LRef-1315-T06-A 1 2.49E+05
S CFS-LRef-1315-T07-A 1 2.27E+05
S CFS-LRef-1315-T08-A 1 1.13E+05
S CFS-LRef-1315-T09-A 1 2.15E+05
S CFS-LRef-1315-T01-B 1 1.11E+04
S CFS-LRef-1315-T02-B 1 4.97E+04
S CFS-LRef-1315-T03-B 1 4.42E+04
S CFS-LRef-1315-T04-B 1 1.48E+05
S CFS-LRef-1315-T05-B 1 1.67E+05
S CFS-LRef-1315-T06-B 1 2.49E+05
S CFS-LRef-1315-T07-B 1 2.29E+05
S CFS-LRef-1315-T08-B 1 1.14E+05
S CFS-LRef-1315-T09-B 1 1.96E+05
S CFS-LRef-1315-T01-C 1 8.62E+03
S CFS-LRef-1315-T02-C 1 5.51E+04
S CFS-LRef-1315-T03-C 1 4.28E+04
S CFS-LRef-1315-T04-C 1 1.44E+05
S CFS-LRef-1315-T05-C 1 1.62E+05
S CFS-LRef-1315-T06-C 1 2.57E+05
S CFS-LRef-1315-T07-C 1 2.29E+05
S CFS-LRef-1315-T08-C 1 1.22E+05
S CFS-LRef-1315-T09-C 1 1.87E+05
S CFS-LRef-1315-M01-A 1 2.69E+01
S CFS-LRef-1315-M02-A 1 1.74E+01 E
S CFS-LRef-1315-M03-A 1 2.19E+01
S CFS-LRef-1315-M04-A 1 8.40E+00 E
S CFS-LRef-1315-M05-A 1 8.09E+00 E
S CFS-LRef-1315-M06-A 1 1.39E+01 E
S CFS-LRef-1315-M07-A 1 1.89E+01 E
S CFS-LRef-1315-M08-A 1 9.49E+00 E
S CFS-LRef-1315-M09-A 1 1.15E+01 E
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
7.76E+03 1.85 6.80 21.60
5.18E+04 0.84 6.80 21.60
4.38E+04 1.88 6.80 21.60 10000 1000
1.54E+05 1.33 6.80 21.60
1.71E+05 2.42 6.80 21.60
2.49E+05 0.94 6.80 21.60
2.27E+05 1.62 6.80 21.60
1.13E+05 1.96 6.80 21.60
2.15E+05 2.57 6.80 21.60
1.11E+04 2.00 6.80 21.60
4.97E+04 1.50 6.80 21.60
4.42E+04 0.67 6.80 21.60 10000 1000
1.48E+05 0.81 6.80 21.60
1.67E+05 1.70 6.80 21.60
2.49E+05 1.82 6.80 21.60
2.29E+05 2.13 6.80 21.60
1.14E+05 0.51 6.80 21.60
1.96E+05 1.00 6.80 21.60
8.62E+03 2.19 6.80 21.60
5.51E+04 1.59 6.80 21.60
4.28E+04 0.73 6.80 21.60 10000 1000
1.44E+05 1.84 6.80 21.60
1.62E+05 2.21 6.80 21.60
2.57E+05 1.32 6.80 21.60
2.29E+05 1.68 6.80 21.60
1.22E+05 0.86 6.80 21.60
1.87E+05 5.92 6.80 21.60
2.69E+01 0.54 6.80 21.60
1.74E+01 4.28 6.80 21.60
2.19E+01 18.12 6.80 21.60
8.40E+00 6.92 6.80 21.60
8.09E+00 6.25 6.80 21.60
1.39E+01 6.50 6.80 21.60
1.89E+01 5.96 6.80 21.60
9.49E+00 1.07 6.80 21.60
1.15E+01 4.63 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
4.47E+04 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.51 E+04 85% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.36E+04 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/11 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/11 4:23 PM EPA Interlab LRef 1315 CFS
6/20/11 4:46 PM EPA Interlab LRef 1315 CFS
6/20/11 4:56 PM EPA Interlab LRef 1315 CFS
6/20/11 5:06 PM EPA Interlab LRef 1315 CFS
6/20/11 3:22 PM EPA Interlab LRef 1315 CFS
6/20/11 3:32 PM EPA Interlab LRef 1315 CFS
6/20/11 3:42 PM EPA Interlab LRef 1315 CFS
6/20/11 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/11 4:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:48 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:08 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:24 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:34 PM EPA Interlab LRef 1315 CFS
6/20/11 3:44 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:26 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:49 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:59 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:58 PM EPA Interlab LRef 1315 CFS
6/20/11 4:00 PM EPA Interlab LRef 1315 CFS
6/20/11 4:02 PM EPA Interlab LRef 1315 CFS
6/20/11 4:41 PM EPA Interlab LRef 1315 CFS
6/20/11 4:43 PM EPA Interlab LRef 1315 CFS
6/20/11 4:44 PM EPA Interlab LRef 1315 CFS
1-956
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L
Tl CFS-LRef-1315-T01-A 1 6.09E+00 E
Tl CFS-LRef-1315-T02-A 1 9.41E+01
Tl CFS-LRef-1315-T03-A 1 6.56E+01
Tl CFS-LRef-1315-T04-A 1 2.15E+02
Tl CFS-LRef-1315-T05-A 1 2.27E+02
Tl CFS-LRef-1315-T06-A 1 3.19E+02
Tl CFS-LRef-1315-T07-A 1 2.81E+02
Tl CFS-LRef-1315-T08-A 1 1.75E+02
Tl CFS-LRef-1315-T09-A 1 2.56E+02
Tl CFS-LRef-1315-T01-B 1 8.64E+00 E
Tl CFS-LRef-1315-T02-B 1 8.72E+01
Tl CFS-LRef-1315-T03-B 1 7.13E+01
Tl CFS-LRef-1315-T04-B 1 2.17E+02
Tl CFS-LRef-1315-T05-B 1 2.31 E+02
Tl CFS-LRef-1315-T06-B 1 3.22E+02
Tl CFS-LRef-1315-T07-B 1 2.82E+02
Tl CFS-LRef-1315-T08-B 1 1.51 E+02
Tl CFS-LRef-1315-T09-B 1 2.33E+02
Tl CFS-LRef-1315-T01-C 1 7.39E+00 E
Tl CFS-LRef-1315-T02-C 1 8.96E+01
Tl CFS-LRef-1315-T03-C 1 6.09E+01
Tl CFS-LRef-1315-T04-C 1 2.09E+02
Tl CFS-LRef-1315-T05-C 1 2.20E+02
Tl CFS-LRef-1315-T06-C 1 3.24E+02
Tl CFS-LRef-1315-T07-C 1 2.77E+02
Tl CFS-LRef-1315-T08-C 1 1.59E+02
Tl CFS-LRef-1315-T09-C 1 2.24E+02
Tl CFS-LRef-1315-M01-A 1 2.30E+00 U1/2
Tl CFS-LRef-1315-M02-A 1 2.30E+00 U1/2
Tl CFS-LRef-1315-M03-A 1 2.30E+00 U1/2
Tl CFS-LRef-1315-M04-A 1 2.30E+00 U1/2
Tl CFS-LRef-1315-M05-A 1 2.30E+00 U1/2
Tl CFS-LRef-1315-M06-A 1 2.30E+00 U1/2
Tl CFS-LRef-1315-M07-A 1 2.30E+00 U1/2
Tl CFS-LRef-1315-M08-A 1 2.30E+00 U1/2
Tl CFS-LRef-1315-M09-A 1 2.30E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.09E+00 19.46 4.60 14.60
9.41E+01 1.81 4.60 14.60
6.56E+01 5.61 4.60 14.60 10000 1000
2.15E+02 3.03 4.60 14.60
2.27E+02 5.64 4.60 14.60
3.19E+02 2.24 4.60 14.60
2.81 E+02 2.78 4.60 14.60
1.75E+02 1.72 4.60 14.60
2.56E+02 5.20 4.60 14.60
8.64E+00 20.15 4.60 14.60
8.72E+01 2.39 4.60 14.60
7.13E+01 3.08 4.60 14.60 10000 1000
2.17E+02 2.42 4.60 14.60
2.31E+02 2.95 4.60 14.60
3.22E+02 1.94 4.60 14.60
2.82E+02 3.30 4.60 14.60
1.51E+02 1.74 4.60 14.60
2.33E+02 1.48 4.60 14.60
7.39E+00 14.28 4.60 14.60
8.96E+01 5.59 4.60 14.60
6.09E+01 3.04 4.60 14.60 10000 1000
2.09E+02 4.36 4.60 14.60
2.20E+02 4.66 4.60 14.60
3.24E+02 0.58 4.60 14.60
2.77E+02 3.46 4.60 14.60
1.59E+02 0.59 4.60 14.60
2.24E+02 8.42 4.60 14.60
2.30E+00 23.01 4.60 14.60
2.30E+00 49.69 4.60 14.60
2.30E+00 28.24 4.60 14.60
2.30E+00 15.28 4.60 14.60
2.30E+00 64.33 4.60 14.60
2.30E+00 60.98 4.60 14.60
2.30E+00 37.70 4.60 14.60
2.30E+00 8.94 4.60 14.60
2.30E+00 87.41 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.05E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 . 1 1 E+03 1 04% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:23 PM EPA Interlab LRef 1315 CFS
6/20/11 4:46 PM EPA Interlab LRef 1315 CFS
6/20/11 4:56 PM EPA Interlab LRef 1315 CFS
6/20/11 5:06 PM EPA Interlab LRef 1315 CFS
6/20/11 3:22 PM EPA Interlab LRef 1315 CFS
6/20/11 3:32 PM EPA Interlab LRef 1315 CFS
6/20/11 3:42 PM EPA Interlab LRef 1315 CFS
6/20/11 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/11 4:25 PM EPA Interlab LRef 1315 CFS
6/20/11 4:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:08 PM EPA Interlab LRef 1315 CFS
6/20/11 3:24 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:34 PM EPA Interlab LRef 1315 CFS
6/20/11 3:44 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:26 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:49 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:59 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/11 3:58 PM EPA Interlab LRef 1315 CFS
6/20/11 4:00 PM EPA Interlab LRef 1315 CFS
6/20/11 4:02 PM EPA Interlab LRef 1315 CFS
6/20/11 4:41 PM EPA Interlab LRef 1315 CFS
6/20/11 4:43 PM EPA Interlab LRef 1315 CFS
6/20/11 4:44 PM EPA Interlab LRef 1315 CFS
1-957
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ti CFS-LRef-1315-T01-A 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T02-A 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T03-A 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T04-A 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T05-A 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T06-A 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T07-A 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T08-A 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T09-A 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T01-B 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T02-B 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T03-B 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T04-B 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T05-B 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T06-B 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T07-B 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T08-B 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T09-B 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T01-C 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T02-C 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T03-C 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T04-C 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T05-C 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T06-C 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T07-C 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T08-C 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T09-C 1 1.00E+00 U1/2
Ti CFS-LRef-1315-M01-A 1 1.00E+00 U1/2
Ti CFS-LRef-1315-M02-A 1 1.00E+00 U1/2
Ti CFS-LRef-1315-M03-A 1 1.00E+00 U1/2
Ti CFS-LRef-1315-M04-A 1 1.00E+00 U1/2
Ti CFS-LRef-1315-M05-A 1 1.00E+00 U1/2
Ti CFS-LRef-1315-M06-A 1 1.00E+00 U1/2
Ti CFS-LRef-1315-M07-A 1 1.00E+00 U1/2
Ti CFS-LRef-1315-M08-A 1 1.00E+00 U1/2
Ti CFS-LRef-1315-M09-A 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 66.05 2.00 6.40
1.00E+00 56.18 2.00 6.40
1.00E+00 21.47 2.00 6.40 10000 1000
1.00E+00 16.75 2.00 6.40
1.00E+00 29.71 2.00 6.40
1.00E+00 64.08 2.00 6.40
1.00E+00 15.75 2.00 6.40
1.00E+00 48.30 2.00 6.40
1.00E+00 39.83 2.00 6.40
1.00E+00 57.47 2.00 6.40
1.00E+00 108.38 2.00 6.40
1.00E+00 62.32 2.00 6.40 10000 1000
1.00E+00 52.64 2.00 6.40
1.00E+00 38.31 2.00 6.40
1.00E+00 27.14 2.00 6.40
1.00E+00 27.71 2.00 6.40
1.00E+00 50.99 2.00 6.40
1.00E+00 42.94 2.00 6.40
1.00E+00 9.47 2.00 6.40
1.00E+00 16.18 2.00 6.40
1.00E+00 14.45 2.00 6.40 10000 1000
1.00E+00 7.68 2.00 6.40
1.00E+00 21.80 2.00 6.40
1.00E+00 40.68 2.00 6.40
1.00E+00 40.61 2.00 6.40
1.00E+00 24.87 2.00 6.40
1.00E+00 50.68 2.00 6.40
1.00E+00 37.97 2.00 6.40
1.00E+00 22.03 2.00 6.40
1.00E+00 63.21 2.00 6.40
1.00E+00 14.69 2.00 6.40
1.00E+00 8.82 2.00 6.40
1.00E+00 52.07 2.00 6.40
1.00E+00 41.04 2.00 6.40
1.00E+00 13.65 2.00 6.40
1.00E+00 32.81 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:23 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:46 PM EPA Interlab LRef 1315 CFS
6/20/11 4:56 PM EPA Interlab LRef 1315 CFS
6/20/11 5:06 PM EPA Interlab LRef 1315 CFS
6/20/11 3:22 PM EPA Interlab LRef 1315 CFS
6/20/11 3:32 PM EPA Interlab LRef 1315 CFS
6/20/11 3:42 PM EPA Interlab LRef 1315 CFS
6/20/11 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/11 4:25 PM EPA Interlab LRef 1315 CFS
6/20/11 4:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:58 PM EPA Interlab LRef 1315 CFS
6/20/11 5:08 PM EPA Interlab LRef 1315 CFS
6/20/11 3:24 PM EPA Interlab LRef 1315 CFS
6/20/11 3:34 PM EPA Interlab LRef 1315 CFS
6/20/11 3:44 PM EPA Interlab LRef 1315 CFS
6/20/11 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/11 4:26 PM EPA Interlab LRef 1315 CFS
6/20/11 4:49 PM EPA Interlab LRef 1315 CFS
6/20/11 4:59 PM EPA Interlab LRef 1315 CFS
6/20/11 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/11 3:58 PM EPA Interlab LRef 1315 CFS
6/20/11 4:00 PM EPA Interlab LRef 1315 CFS
6/20/11 4:02 PM EPA Interlab LRef 1315 CFS
6/20/11 4:41 PM EPA Interlab LRef 1315 CFS
6/20/11 4:43 PM EPA Interlab LRef 1315 CFS
6/20/11 4:44 PM EPA Interlab LRef 1315 CFS
1-958
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
V CFS-LRef-1315-T01-A 1 1.71E+00 E
V CFS-LRef-1315-T02-A 1 1.84E+00 E
V CFS-LRef-1315-T03-A 1 2.41E+00 E
V CFS-LRef-1315-T04-A 1 7.21E+00
V CFS-LRef-1315-T05-A 1 6.38E+00
V CFS-LRef-1315-T06-A 1 8.69E+00
V CFS-LRef-1315-T07-A 1 8.85E+00
V CFS-LRef-1315-T08-A 1 6.97E+00
V CFS-LRef-1315-T09-A 1 8.47E+00
V CFS-LRef-1315-T01-B 1 1.84E+00 E
V CFS-LRef-1315-T02-B 1 2.34E+00 E
V CFS-LRef-1315-T03-B 1 2.59E+00 E
V CFS-LRef-1315-T04-B 1 5.83E+00
V CFS-LRef-1315-T05-B 1 6.71E+00
V CFS-LRef-1315-T06-B 1 8.95E+00
V CFS-LRef-1315-T07-B 1 8.50E+00
V CFS-LRef-1315-T08-B 1 4.76E+00 E
V CFS-LRef-1315-T09-B 1 8.67E+00
V CFS-LRef-1315-T01-C 1 1.52E+00 E
V CFS-LRef-1315-T02-C 1 2.63E+00 E
V CFS-LRef-1315-T03-C 1 2.18E+00 E
V CFS-LRef-1315-T04-C 1 5.29E+00
V CFS-LRef-1315-T05-C 1 5.78E+00
V CFS-LRef-1315-T06-C 1 1.01E+01
V CFS-LRef-1315-T07-C 1 8.73E+00
V CFS-LRef-1315-T08-C 1 6.44E+00
V CFS-LRef-1315-T09-C 1 8.09E+00
V CFS-LRef-1315-M01-A 1 7.50E-01 U1/2
V CFS-LRef-1315-M02-A 1 7.50E-01 U1/2
V CFS-LRef-1315-M03-A 1 7.50E-01 U1/2
V CFS-LRef-1315-M04-A 1 7.50E-01 U1/2
V CFS-LRef-1315-M05-A 1 7.50E-01 U1/2
V CFS-LRef-1315-M06-A 1 7.50E-01 U1/2
V CFS-LRef-1315-M07-A 1 7.50E-01 U1/2
V CFS-LRef-1315-M08-A 1 7.50E-01 U1/2
V CFS-LRef-1315-M09-A 1 7.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.71E+00 20.72 1.50 4.77
1.84E+00 18.80 1.50 4.77
2.41E+00 9.72 1.50 4.77 10000 1000
7.21E+00 8.13 1.50 4.77
6.38E+00 1.38 1.50 4.77
8.69E+00 4.64 1.50 4.77
8.85E+00 7.18 1.50 4.77
6.97E+00 3.88 1.50 4.77
8.47E+00 12.14 1.50 4.77
1.84E+00 17.29 1.50 4.77
2.34E+00 26.48 1.50 4.77
2.59E+00 34.43 1.50 4.77 10000 1000
5.83E+00 8.46 1.50 4.77
6.71E+00 2.50 1.50 4.77
8.95E+00 6.91 1.50 4.77
8.50E+00 4.94 1.50 4.77
4.76E+00 11.18 1.50 4.77
8.67E+00 1.37 1.50 4.77
1.52E+00 8.23 1.50 4.77
2.63E+00 6.54 1.50 4.77
2.18E+00 16.85 1.50 4.77 10000 1000
5.29E+00 14.51 1.50 4.77
5.78E+00 2.35 1.50 4.77
1.01E+01 1.08 1.50 4.77
8.73E+00 1.41 1.50 4.77
6.44E+00 1.79 1.50 4.77
8.09E+00 2.40 1.50 4.77
7.50E-01 13.98 1.50 4.77
7.50E-01 26.66 1.50 4.77
7.50E-01 24.42 1.50 4.77
7.50E-01 23.02 1.50 4.77
7.50E-01 3.18 1.50 4.77
7.50E-01 7.78 1.50 4.77
7.50E-01 7.34 1.50 4.77
7.50E-01 18.48 1.50 4.77
7.50E-01 8.88 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.89E+02 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:23 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:46 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:56 PM EPA Interlab LRef 1315 CFS
6/20/11 5:06 PM EPA Interlab LRef 1315 CFS
6/20/11 3:22 PM EPA Interlab LRef 1315 CFS
6/20/11 3:32 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:42 PM EPA Interlab LRef 1315 CFS
6/20/11 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/11 4:25 PM EPA Interlab LRef 1315 CFS
6/20/11 4:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:58 PM EPA Interlab LRef 1315 CFS
6/20/11 5:08 PM EPA Interlab LRef 1315 CFS
6/20/11 3:24 PM EPA Interlab LRef 1315 CFS
6/20/11 3:34 PM EPA Interlab LRef 1315 CFS
6/20/11 3:44 PM EPA Interlab LRef 1315 CFS
6/20/11 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/11 4:26 PM EPA Interlab LRef 1315 CFS
6/20/11 4:49 PM EPA Interlab LRef 1315 CFS
6/20/11 4:59 PM EPA Interlab LRef 1315 CFS
6/20/11 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/11 3:58 PM EPA Interlab LRef 1315 CFS
6/20/11 4:00 PM EPA Interlab LRef 1315 CFS
6/20/11 4:02 PM EPA Interlab LRef 1315 CFS
6/20/11 4:41 PM EPA Interlab LRef 1315 CFS
6/20/11 4:43 PM EPA Interlab LRef 1315 CFS
6/20/11 4:44 PM EPA Interlab LRef 1315 CFS
1-959
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Zn CFS-LRef-1315-T01-A 1 4.32E+02
Zn CFS-LRef-1315-T02-A 1 2.18E+03
Zn CFS-LRef-1315-T03-A 1 1.99E+03
Zn CFS-LRef-1315-T04-A 1 6.39E+03
Zn CFS-LRef-1315-T05-A 1 6.95E+03
Zn CFS-LRef-1315-T06-A 1 9.89E+03
Zn CFS-LRef-1315-T07-A 1 8.72E+03
Zn CFS-LRef-1315-T08-A 1 4.78E+03
Zn CFS-LRef-1315-T09-A 1 8.39E+03
Zn CFS-LRef-1315-T01-B 1 5.22E+02
Zn CFS-LRef-1315-T02-B 1 2.21E+03
Zn CFS-LRef-1315-T03-B 1 1.98E+03
Zn CFS-LRef-1315-T04-B 1 5.96E+03
Zn CFS-LRef-1315-T05-B 1 6.70E+03
Zn CFS-LRef-1315-T06-B 1 9.72E+03
Zn CFS-LRef-1315-T07-B 1 8.25E+03
Zn CFS-LRef-1315-T08-B 1 4.46E+03
Zn CFS-LRef-1315-T09-B 1 7.47E+03
Zn CFS-LRef-1315-T01-C 1 4.50E+02
Zn CFS-LRef-1315-T02-C 1 2.34E+03
Zn CFS-LRef-1315-T03-C 1 1.89E+03
Zn CFS-LRef-1315-T04-C 1 5.62E+03
Zn CFS-LRef-1315-T05-C 1 6.40E+03
Zn CFS-LRef-1315-T06-C 1 9.62E+03
Zn CFS-LRef-1315-T07-C 1 8.85E+03
Zn CFS-LRef-1315-T08-C 1 4.72E+03
Zn CFS-LRef-1315-T09-C 1 7.12E+03
Zn CFS-LRef-1315-M01-A 1 5.00E-01 U1/2
Zn CFS-LRef-1315-M02-A 1 5.00E-01 U1/2
Zn CFS-LRef-1315-M03-A 1 5.00E-01 U1/2
Zn CFS-LRef-1315-M04-A 1 5.00E-01 U1/2
Zn CFS-LRef-1315-M05-A 1 5.00E-01 U1/2
Zn CFS-LRef-1315-M06-A 1 5.00E-01 U1/2
Zn CFS-LRef-1315-M07-A 1 5.00E-01 U1/2
Zn CFS-LRef-1315-M08-A 1 5.00E-01 U1/2
Zn CFS-LRef-1315-M09-A 1 5.00E-01 U1/2
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.32E+02 2.98 1.00 3.18
2.18E+03 1.19 1.00 3.18
1.99E+03 1.72 1.00 3.18 10000 1000
6.39E+03 1.17 1.00 3.18
6.95E+03 1.07 1.00 3.18
9.89E+03 1.43 1.00 3.18
8.72E+03 1.83 1.00 3.18
4.78E+03 0.51 1.00 3.18
8.39E+03 0.93 1.00 3.18
5.22E+02 2.24 1.00 3.18
2.21E+03 1.55 1.00 3.18
1.98E+03 0.52 1.00 3.18 10000 1000
5.96E+03 1.14 1.00 3.18
6.70E+03 1.28 1.00 3.18
9.72E+03 1.87 1.00 3.18
8.25E+03 1.31 1.00 3.18
4.46E+03 0.61 1.00 3.18
7.47E+03 1.73 1.00 3.18
4.50E+02 1.49 1.00 3.18
2.34E+03 2.53 1.00 3.18
1.89E+03 2.29 1.00 3.18 10000 1000
5.62E+03 2.25 1.00 3.18
6.40E+03 2.23 1.00 3.18
9.62E+03 1.07 1.00 3.18
8.85E+03 2.33 1.00 3.18
4.72E+03 0.51 1.00 3.18
7.12E+03 11.86 1.00 3.18
5.00E-01 3.30 1.00 3.18
5.00E-01 1.94 1.00 3.18
5.00E-01 2.72 1.00 3.18
5.00E-01 2.05 1.00 3.18
5.00E-01 3.41 1.00 3.18
5.00E-01 9.68 1.00 3.18
5.00E-01 6.98 1.00 3.18
5.00E-01 2.39 1.00 3.18
5.00E-01 4.73 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.93E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.97E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.79E+03 90% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/11 3:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:40 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:03 PM EPA Interlab LRef 1315 CFS
6/20/11 4:13 PM EPA Interlab LRef 1315 CFS
6/20/11 4:23 PM EPA Interlab LRef 1315 CFS
6/20/11 4:46 PM EPA Interlab LRef 1315 CFS
6/20/11 4:56 PM EPA Interlab LRef 1315 CFS
6/20/11 5:06 PM EPA Interlab LRef 1315 CFS
6/20/11 3:22 PM EPA Interlab LRef 1315 CFS
6/20/11 3:32 PM EPA Interlab LRef 1315 CFS
6/20/11 3:42 PM EPA Interlab LRef 1315 CFS
6/20/11 4:05 PM EPA Interlab LRef 1315 CFS
6/20/11 4:15 PM EPA Interlab LRef 1315 CFS
6/20/11 4:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:48 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:08 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:24 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:34 PM EPA Interlab LRef 1315 CFS
6/20/11 3:44 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:07 PM EPA Interlab LRef 1315 CFS
6/20/11 4:16 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:26 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:49 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:59 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:09 PM EPA Interlab LRef 1315 CFS
6/20/11 3:16 PM EPA Interlab LRef 1315 CFS
6/20/11 3:17 PM EPA Interlab LRef 1315 CFS
6/20/11 3:19 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:58 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:00 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:02 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:41 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:43 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:44 PM EPA Interlab LRef 1315 CFS
1-960
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
QA-QC Spreadsheet 1315:
Element
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Al
Sample ID
CFS-LRef-1315-T01-D
CFS-LRef-1315-T02-D
CFS-LRef-1315-T03-D
CFS-LRef-1315-T04-D
CFS-LRef-1315-T05-D
CFS-LRef-1315-T06-D
CFS-LRef-1315-T07-D
CFS-LRef-1315-T08-D
CFS-LRef-1315-T09-D
CFS-LRef-1315-T01-E
CFS-LRef-1315-T02-E
CFS-LRef-1315-T03-E
CFS-LRef-1315-T04-E
CFS-LRef-1315-T05-E
CFS-LRef-1315-T06-E
CFS-LRef-1315-T07-E
CFS-LRef-1315-T08-E
CFS-LRef-1315-T09-E
CFS-LRef-1315-T01-F
CFS-LRef-1315-T02-F
CFS-LRef-1315-T03-F
CFS-LRef-1315-T04-F
CFS-LRef-1315-T05-F
CFS-LRef-1315-T06-F
CFS-LRef-1315-T07-F
CFS-LRef-1315-T08-F
CFS-LRef-1315-T09-F
Dilution Sample
Factor Cone. Quallf
I Mg/L
1 9.01 E+00
1 2.05E+01
1 1.85E+01
1 4.52E+01
1 4.20E+01
1 4.74E+01
1 4.95E+01
1 4.90E+01
1 4.74E+01
1 9.35E+00
1 2.12E+01
1 2.00E+01
1 3.05E+01
1 3.39E+01
1 4.67E+01
1 4.74E+01
1 2.97E+01
1 4.33E+01
1 9.42E+00
1 2.34E+01
1 3.28E+01
1 3.34E+01
1 3.51 E+01
1 4.71 E+01
1 4.51 E+01
1 3.23E+01
1 4.57E+01
ICP-OES Spike Sol'n
er Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.01E+00 3.86 1.00 3.18
2.05E+01 1.59 1.00 3.18
1.85E+01 4.91 1.00 3.18 10000 1000
4.52E+01 6.41 1.00 3.18
4.20E+01 7.74 1.00 3.18
4.74E+01 3.51 1.00 3.18
4.95E+01 1.91 1.00 3.18
4.90E+01 10.90 1.00 3.18
4.74E+01 0.84 1.00 3.18
9.35E+00 9.29 1.00 3.18
2.12E+01 8.32 1.00 3.18
2.00E+01 3.11 1.00 3.18 10000 1000
3.05E+01 7.73 1.00 3.18
3.39E+01 7.09 1.00 3.18
4.67E+01 4.09 1.00 3.18
4.74E+01 2.59 1.00 3.18
2.97E+01 3.70 1.00 3.18
4.33E+01 9.41 1.00 3.18
9.42E+00 5.42 1.00 3.18
2.34E+01 1.76 1.00 3.18
3.28E+01 8.14 1.00 3.18 10000 1000
3.34E+01 5.68 1.00 3.18
3.51E+01 10.55 1.00 3.18
4.71E+01 1.29 1.00 3.18
4.51E+01 7.79 1.00 3.18
3.23E+01 2.20 1.00 3.18
4.57E+01 1.69 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.09E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/11 5:11 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:53 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:29 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:39 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/11 4:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:31 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:54 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-961
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Sb CFS-LRef-1315-T01-D 1 8.75E+00 E
Sb CFS-LRef-1315-T02-D 1 9.03E+00 E
Sb CFS-LRef-1315-T03-D 1 9.95E+00 E
Sb CFS-LRef-1315-T04-D 1 1.01E+01 E
Sb CFS-LRef-1315-T05-D 1 1.16E+01 E
Sb CFS-LRef-1315-T06-D 1 1.25E+01 E
Sb CFS-LRef-1315-T07-D 1 1.03E+01 E
Sb CFS-LRef-1315-T08-D 1 9.28E+00 E
Sb CFS-LRef-1315-T09-D 1 9.64E+00 E
Sb CFS-LRef-1315-T01-E 1 9.04E+00 E
Sb CFS-LRef-1315-T02-E 1 9.47E+00 E
Sb CFS-LRef-1315-T03-E 1 1.03E+01 E
Sb CFS-LRef-1315-T04-E 1 1.19E+01 E
Sb CFS-LRef-1315-T05-E 1 1.17E+01 E
Sb CFS-LRef-1315-T06-E 1 1.01E+01 E
Sb CFS-LRef-1315-T07-E 1 9.94E+00 E
Sb CFS-LRef-1315-T08-E 1 9.26E+00 E
Sb CFS-LRef-1315-T09-E 1 8.84E+00 E
Sb CFS-LRef-1315-T01-F 1 9.17E+00 E
Sb CFS-LRef-1315-T02-F 1 9.34E+00 E
Sb CFS-LRef-1315-T03-F 1 1.12E+01 E
Sb CFS-LRef-1315-T04-F 1 1.56E+01 E
Sb CFS-LRef-1315-T05-F 1 1.15E+01 E
Sb CFS-LRef-1315-T06-F 1 1.18E+01 E
Sb CFS-LRef-1315-T07-F 1 1.05E+01 E
Sb CFS-LRef-1315-T08-F 1 9.83E+00 E
Sb CFS-LRef-1315-T09-F 1 9.30E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.75E+00 7.24 7.50 23.90
9.03E+00 11.73 7.50 23.90
9.95E+00 23.70 7.50 23.90 10000 1000
1.01E+01 27.52 7.50 23.90
1.16E+01 12.25 7.50 23.90
1.25E+01 10.97 7.50 23.90
1.03E+01 6.44 7.50 23.90
9.28E+00 10.30 7.50 23.90
9.64E+00 7.82 7.50 23.90
9.04E+00 9.48 7.50 23.90
9.47E+00 10.07 7.50 23.90
1.03E+01 23.76 7.50 23.90 10000 1000
1.19E+01 28.53 7.50 23.90
1.17E+01 13.06 7.50 23.90
1.01E+01 19.98 7.50 23.90
9.94E+00 10.88 7.50 23.90
9.26E+00 7.53 7.50 23.90
8.84E+00 3.76 7.50 23.90
9.17E+00 6.69 7.50 23.90
9.34E+00 13.44 7.50 23.90
1.12E+01 8.12 7.50 23.90 10000 1000
1.56E+01 25.08 7.50 23.90
1.15E+01 18.19 7.50 23.90
1.18E+01 22.53 7.50 23.90
1.05E+01 11.37 7.50 23.90
9.83E+00 6.26 7.50 23.90
9.30E+00 5.41 7.50 23.90
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:1 1 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:53 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:29 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:39 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/11 4:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:31 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:54 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-962
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
As CFS-LRef-1315-T01-D 1 5.50E+00 U1/2
As CFS-LRef-1315-T02-D 1 5.50E+00 U1/2
As CFS-LRef-1315-T03-D 1 1.14E+01 E
As CFS-LRef-1315-T04-D 1 1.44E+01 E
As CFS-LRef-1315-T05-D 1 1.69E+01 E
As CFS-LRef-1315-T06-D 1 1.42E+01 E
As CFS-LRef-1315-T07-D 1 1.27E+01 E
As CFS-LRef-1315-T08-D 1 5.50E+00 U1/2
As CFS-LRef-1315-T09-D 1 5.50E+00 U1/2
As CFS-LRef-1315-T01-E 1 5.50E+00 U1/2
As CFS-LRef-1315-T02-E 1 5.50E+00 U1/2
As CFS-LRef-1315-T03-E 1 1.21E+01 E
As CFS-LRef-1315-T04-E 1 1.57E+01 E
As CFS-LRef-1315-T05-E 1 1.76E+01 E
As CFS-LRef-1315-T06-E 1 1.25E+01 E
As CFS-LRef-1315-T07-E 1 1.33E+01 E
As CFS-LRef-1315-T08-E 1 1.25E+01 E
As CFS-LRef-1315-T09-E 1 5.50E+00 U1/2
As CFS-LRef-1315-T01-F 1 5.50E+00 U1/2
As CFS-LRef-1315-T02-F 1 5.50E+00 U1/2
As CFS-LRef-1315-T03-F 1 1.17E+01 E
As CFS-LRef-1315-T04-F 1 1.54E+01 E
As CFS-LRef-1315-T05-F 1 1.73E+01 E
As CFS-LRef-1315-T06-F 1 1.23E+01 E
As CFS-LRef-1315-T07-F 1 1.16E+01 E
As CFS-LRef-1315-T08-F 1 1.13E+01 E
As CFS-LRef-1315-T09-F 1 5.50E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.50E+00 19.96 11.00 35.00
5.50E+00 24.35 11.00 35.00
1.14E+01 20.73 11.00 35.00 10000 1000
1.44E+01 24.81 11.00 35.00
1.69E+01 29.66 11.00 35.00
1.42E+01 32.87 11.00 35.00
1.27E+01 37.86 11.00 35.00
5.50E+00 21.16 11.00 35.00
5.50E+00 9.43 11.00 35.00
5.50E+00 49.22 11.00 35.00
5.50E+00 35.46 11.00 35.00
1.21E+01 55.43 11.00 35.00 10000 1000
1.57E+01 26.36 11.00 35.00
1.76E+01 35.51 11.00 35.00
1.25E+01 14.84 11.00 35.00
1.33E+01 24.32 11.00 35.00
1.25E+01 34.44 11.00 35.00
5.50E+00 24.09 11.00 35.00
5.50E+00 24.56 11.00 35.00
5.50E+00 9.88 11.00 35.00
1.17E+01 18.71 11.00 35.00 10000 1000
1.54E+01 10.53 11.00 35.00
1.73E+01 25.34 11.00 35.00
1.23E+01 16.39 11.00 35.00
1.16E+01 27.58 11.00 35.00
1.13E+01 28.30 11.00 35.00
5.50E+00 33.36 11.00 35.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:1 1 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:53 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:29 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:39 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:31 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:54 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-963
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
B CFS-LRef-1315-T01-D 1 1.90E+01
B CFS-LRef-1315-T02-D 1 5.04E+01
B CFS-LRef-1315-T03-D 1 4.45E+01
B CFS-LRef-1315-T04-D 1 1.23E+02
B CFS-LRef-1315-T05-D 1 1.23E+02
B CFS-LRef-1315-T06-D 1 1.80E+02
B CFS-LRef-1315-T07-D 1 1.61E+02
B CFS-LRef-1315-T08-D 1 7.38E+01
B CFS-LRef-1315-T09-D 1 1.30E+02
B CFS-LRef-1315-T01-E 1 1.60E+01
B CFS-LRef-1315-T02-E 1 5.60E+01
B CFS-LRef-1315-T03-E 1 4.37E+01
B CFS-LRef-1315-T04-E 1 1.08E+02
B CFS-LRef-1315-T05-E 1 1.21E+02
B CFS-LRef-1315-T06-E 1 1.77E+02
B CFS-LRef-1315-T07-E 1 1.60E+02
B CFS-LRef-1315-T08-E 1 6.85E+01
B CFS-LRef-1315-T09-E 1 1.23E+02
B CFS-LRef-1315-T01-F 1 1.57E+01
B CFS-LRef-1315-T02-F 1 4.43E+01
B CFS-LRef-1315-T03-F 1 4.22E+01
B CFS-LRef-1315-T04-F 1 1.14E+02
B CFS-LRef-1315-T05-F 1 1.19E+02
B CFS-LRef-1315-T06-F 1 1.83E+02
B CFS-LRef-1315-T07-F 1 1.62E+02
B CFS-LRef-1315-T08-F 1 7.34E+01
B CFS-LRef-1315-T09-F 1 1.24E+02
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.90E+01 7.20 1.00 3.18
5.04E+01 4.00 1.00 3.18
4.45E+01 2.52 1.00 3.18 10000 1000
1.23E+02 2.91 1.00 3.18
1.23E+02 0.75 1.00 3.18
1.80E+02 1.28 1.00 3.18
1.61E+02 0.56 1.00 3.18
7.38E+01 2.49 1.00 3.18
1.30E+02 3.51 1.00 3.18
1.60E+01 1.16 1.00 3.18
5.60E+01 3.55 1.00 3.18
4.37E+01 2.47 1.00 3.18 10000 1000
1.08E+02 1.50 1.00 3.18
1.21E+02 0.91 1.00 3.18
1.77E+02 1.35 1.00 3.18
1.60E+02 1.48 1.00 3.18
6.85E+01 5.68 1.00 3.18
1.23E+02 4.67 1.00 3.18
1.57E+01 6.72 1.00 3.18
4.43E+01 4.24 1.00 3.18
4.22E+01 1.10 1.00 3.18 10000 1000
1.14E+02 1.12 1.00 3.18
1.19E+02 5.05 1.00 3.18
1.83E+02 0.90 1.00 3.18
1.62E+02 1.50 1.00 3.18
7.34E+01 4.17 1.00 3.18
1.24E+02 1.09 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.12E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 . 1 4E+03 1 09% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.14E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:1 1 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/11 4:30 PM EPA Interlab LRef 1315 CFS
6/20/11 4:53 PM EPA Interlab LRef 1315 CFS
6/20/11 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/11 3:29 PM EPA Interlab LRef 1315 CFS
6/20/11 3:39 PM EPA Interlab LRef 1315 CFS
6/20/11 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/11 4:21 PM EPA Interlab LRef 1315 CFS
6/20/11 4:31 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:54 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-964
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Ba CFS-LRef-1315-T01-D 1 2.08E+01
Ba CFS-LRef-1315-T02-D 1 2.33E+01
Ba CFS-LRef-1315-T03-D 1 2.81E+01
Ba CFS-LRef-1315-T04-D 1 2.94E+01
Ba CFS-LRef-1315-T05-D 1 3.48E+01
Ba CFS-LRef-1315-T06-D 1 3.87E+01
Ba CFS-LRef-1315-T07-D 1 3.64E+01
Ba CFS-LRef-1315-T08-D 1 2.36E+01
Ba CFS-LRef-1315-T09-D 1 3.22E+01
Ba CFS-LRef-1315-T01-E 1 1.97E+01
Ba CFS-LRef-1315-T02-E 1 2.00E+01
Ba CFS-LRef-1315-T03-E 1 2.54E+01
Ba CFS-LRef-1315-T04-E 1 2.68E+01
Ba CFS-LRef-1315-T05-E 1 3.60E+01
Ba CFS-LRef-1315-T06-E 1 3.97E+01
Ba CFS-LRef-1315-T07-E 1 3.90E+01
Ba CFS-LRef-1315-T08-E 1 2.46E+01
Ba CFS-LRef-1315-T09-E 1 3.22E+01
Ba CFS-LRef-1315-T01-F 1 1.92E+01
Ba CFS-LRef-1315-T02-F 1 2.15E+01
Ba CFS-LRef-1315-T03-F 1 2.72E+01
Ba CFS-LRef-1315-T04-F 1 3.05E+01
Ba CFS-LRef-1315-T05-F 1 3.59E+01
Ba CFS-LRef-1315-T06-F 1 3.88E+01
Ba CFS-LRef-1315-T07-F 1 3.78E+01
Ba CFS-LRef-1315-T08-F 1 2.53E+01
Ba CFS-LRef-1315-T09-F 1 3.16E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.08E+01 2.00 1.00 3.18
2.33E+01 0.93 1.00 3.18
2.81E+01 0.87 1.00 3.18 10000 1000
2.94E+01 0.79 1.00 3.18
3.48E+01 1.04 1.00 3.18
3.87E+01 0.44 1.00 3.18
3.64E+01 1.05 1.00 3.18
2.36E+01 9.49 1.00 3.18
3.22E+01 2.64 1.00 3.18
1.97E+01 0.64 1.00 3.18
2.00E+01 1.05 1.00 3.18
2.54E+01 1.89 1.00 3.18 10000 1000
2.68E+01 1.80 1.00 3.18
3.60E+01 2.70 1.00 3.18
3.97E+01 1.21 1.00 3.18
3.90E+01 0.95 1.00 3.18
2.46E+01 3.05 1.00 3.18
3.22E+01 3.26 1.00 3.18
1.92E+01 2.17 1.00 3.18
2.15E+01 2.44 1.00 3.18
2.72E+01 2.60 1.00 3.18 10000 1000
3.05E+01 2.31 1.00 3.18
3.59E+01 3.57 1.00 3.18
3.88E+01 1.63 1.00 3.18
3.78E+01 0.73 1.00 3.18
2.53E+01 1.10 1.00 3.18
3.16E+01 1.17 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.08E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:1 1 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:53 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:29 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:39 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:21 PM EPA Interlab LRef 1315 CFS
6/20/11 4:31 PM EPA Interlab LRef 1315 CFS
6/20/11 4:54 PM EPA Interlab LRef 1315 CFS
6/20/11 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-965
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Be CFS-LRef-1315-T01-D 1 9.50E-01 U1/2
Be CFS-LRef-1315-T02-D 1 9.50E-01 U1/2
Be CFS-LRef-1315-T03-D 1 9.50E-01 U1/2
Be CFS-LRef-1315-T04-D 1 9.50E-01 U1/2
Be CFS-LRef-1315-T05-D 1 9.50E-01 U1/2
Be CFS-LRef-1315-T06-D 1 9.50E-01 U1/2
Be CFS-LRef-1315-T07-D 1 9.50E-01 U1/2
Be CFS-LRef-1315-T08-D 1 9.50E-01 U1/2
Be CFS-LRef-1315-T09-D 1 9.50E-01 U1/2
Be CFS-LRef-1315-T01-E 1 9.50E-01 U1/2
Be CFS-LRef-1315-T02-E 1 9.50E-01 U1/2
Be CFS-LRef-1315-T03-E 1 9.50E-01 U1/2
Be CFS-LRef-1315-T04-E 1 9.50E-01 U1/2
Be CFS-LRef-1315-T05-E 1 9.50E-01 U1/2
Be CFS-LRef-1315-T06-E 1 9.50E-01 U1/2
Be CFS-LRef-1315-T07-E 1 9.50E-01 U1/2
Be CFS-LRef-1315-T08-E 1 9.50E-01 U1/2
Be CFS-LRef-1315-T09-E 1 9.50E-01 U1/2
Be CFS-LRef-1315-T01-F 1 9.50E-01 U1/2
Be CFS-LRef-1315-T02-F 1 9.50E-01 U1/2
Be CFS-LRef-1315-T03-F 1 9.50E-01 U1/2
Be CFS-LRef-1315-T04-F 1 9.50E-01 U1/2
Be CFS-LRef-1315-T05-F 1 9.50E-01 U1/2
Be CFS-LRef-1315-T06-F 1 9.50E-01 U1/2
Be CFS-LRef-1315-T07-F 1 9.50E-01 U1/2
Be CFS-LRef-1315-T08-F 1 9.50E-01 U1/2
Be CFS-LRef-1315-T09-F 1 9.50E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
9.50E-01 9.25 1.90 6.00
9.50E-01 32.32 1.90 6.00
9.50E-01 17.09 1.90 6.00 10000 1000
9.50E-01 48.43 1.90 6.00
9.50E-01 40.98 1.90 6.00
9.50E-01 23.75 1.90 6.00
9.50E-01 15.88 1.90 6.00
9.50E-01 35.17 1.90 6.00
9.50E-01 29.55 1.90 6.00
9.50E-01 13.06 1.90 6.00
9.50E-01 16.24 1.90 6.00
9.50E-01 113.88 1.90 6.00 10000 1000
9.50E-01 10.71 1.90 6.00
9.50E-01 47.23 1.90 6.00
9.50E-01 67.43 1.90 6.00
9.50E-01 10.77 1.90 6.00
9.50E-01 66.30 1.90 6.00
9.50E-01 43.13 1.90 6.00
9.50E-01 36.49 1.90 6.00
9.50E-01 26.17 1.90 6.00
9.50E-01 52.76 1.90 6.00 10000 1000
9.50E-01 53.19 1.90 6.00
9.50E-01 16.02 1.90 6.00
9.50E-01 18.75 1.90 6.00
9.50E-01 34.73 1.90 6.00
9.50E-01 87.53 1.90 6.00
9.50E-01 63.17 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.04E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:1 1 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:53 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:29 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:39 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/11 4:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:31 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:54 PM EPA Interlab LRef 1315 CFS
6/20/11 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-966
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualil
1 1 ug/L
Cd CFS-LRef-1315-T01-D 1 8.59E+01
Cd CFS-LRef-1315-T02-D 1 4.07E+02
Cd CFS-LRef-1315-T03-D 1 4.15E+02
Cd CFS-LRef-1315-T04-D 1 1.22E+03
Cd CFS-LRef-1315-T05-D 1 1.21E+03
Cd CFS-LRef-1315-T06-D 1 1.74E+03
Cd CFS-LRef-1315-T07-D 1 1.63E+03
Cd CFS-LRef-1315-T08-D 1 7.91E+02
Cd CFS-LRef-1315-T09-D 1 1.43E+03
Cd CFS-LRef-1315-T01-E 1 7.42E+01
Cd CFS-LRef-1315-T02-E 1 4.67E+02
Cd CFS-LRef-1315-T03-E 1 3.72E+02
Cd CFS-LRef-1315-T04-E 1 1.05E+03
Cd CFS-LRef-1315-T05-E 1 1.18E+03
Cd CFS-LRef-1315-T06-E 1 1.75E+03
Cd CFS-LRef-1315-T07-E 1 1.64E+03
Cd CFS-LRef-1315-T08-E 1 7.41E+02
Cd CFS-LRef-1315-T09-E 1 1.27E+03
Cd CFS-LRef-1315-T01-F 1 6.60E+01
Cd CFS-LRef-1315-T02-F 1 3.47E+02
Cd CFS-LRef-1315-T03-F 1 3.60E+02
Cd CFS-LRef-1315-T04-F 1 1.08E+03
Cd CFS-LRef-1315-T05-F 1 1.17E+03
Cd CFS-LRef-1315-T06-F 1 1.76E+03
Cd CFS-LRef-1315-T07-F 1 1.60E+03
Cd CFS-LRef-1315-T08-F 1 7.24E+02
Cd CFS-LRef-1315-T09-F 1 1.31E+03
ICP-OES Spike Sol'n
ier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
8.59E+01 2.71 2.20 7.00
4.07E+02 0.13 2.20 7.00
4.15E+02 0.92 2.20 7.00 10000 1000
1.22E+03 1.37 2.20 7.00
1.21E+03 0.65 2.20 7.00
1.74E+03 0.65 2.20 7.00
1.63E+03 0.45 2.20 7.00
7.91E+02 1.84 2.20 7.00
1.43E+03 1.34 2.20 7.00
7.42E+01 1.32 2.20 7.00
4.67E+02 1.44 2.20 7.00
3.72E+02 1.38 2.20 7.00 10000 1000
1.05E+03 1.75 2.20 7.00
1.18E+03 0.73 2.20 7.00
1.75E+03 1.49 2.20 7.00
1.64E+03 1.48 2.20 7.00
7.41 E+02 1.06 2.20 7.00
1.27E+03 2.69 2.20 7.00
6.60E+01 2.68 2.20 7.00
3.47E+02 2.30 2.20 7.00
3.60E+02 3.53 2.20 7.00 10000 1000
1.08E+03 1.71 2.20 7.00
1.17E+03 1.74 2.20 7.00
1.76E+03 0.64 2.20 7.00
1.60E+03 0.98 2.20 7.00
7.24E+02 1.00 2.20 7.00
1.31E+03 1.73 2.20 7.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.36E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.40E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.35E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/11 5:11 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:53 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:29 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:39 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/11 4:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:31 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:54 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-967
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Ca CFS-LRef-1315-T01-D 1 1.01E+04
Ca CFS-LRef-1315-T02-D 1 4.14E+04
Ca CFS-LRef-1315-T03-D 1 5.29E+04
Ca CFS-LRef-1315-T04-D 1 9.92E+04
Ca CFS-LRef-1315-T05-D 1 1.05E+05
Ca CFS-LRef-1315-T06-D 1 1.53E+05
Ca CFS-LRef-1315-T07-D 1 1.54E+05
Ca CFS-LRef-1315-T08-D 1 7.73E+04
Ca CFS-LRef-1315-T09-D 1 1.48E+05
Ca CFS-LRef-1315-T01-E 1 1.05E+04
Ca CFS-LRef-1315-T02-E 1 4.18E+04
Ca CFS-LRef-1315-T03-E 1 5.78E+04
Ca CFS-LRef-1315-T04-E 1 8.77E+04
Ca CFS-LRef-1315-T05-E 1 9.37E+04
Ca CFS-LRef-1315-T06-E 1 1.43E+05
Ca CFS-LRef-1315-T07-E 1 1.43E+05
Ca CFS-LRef-1315-T08-E 1 6.84E+04
Ca CFS-LRef-1315-T09-E 1 1.24E+05
Ca CFS-LRef-1315-T01-F 1 1.00E+04
Ca CFS-LRef-1315-T02-F 1 3.60E+04
Ca CFS-LRef-1315-T03-F 1 5.69E+04
Ca CFS-LRef-1315-T04-F 1 8.89E+04
Ca CFS-LRef-1315-T05-F 1 9.24E+04
Ca CFS-LRef-1315-T06-F 1 1.45E+05
Ca CFS-LRef-1315-T07-F 1 1.40E+05
Ca CFS-LRef-1315-T08-F 1 6.75E+04
Ca CFS-LRef-1315-T09-F 1 1.26E+05
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.01E+04 2.43 2.60 8.30
4.14E+04 0.13 2.60 8.30
5.29E+04 1.01 2.60 8.30 10000 1000
9.92E+04 1.00 2.60 8.30
1.05E+05 0.06 2.60 8.30
1.53E+05 0.68 2.60 8.30
1.54E+05 0.38 2.60 8.30
7.73E+04 0.74 2.60 8.30
1.48E+05 1.45 2.60 8.30
1.05E+04 1.51 2.60 8.30
4.18E+04 1.51 2.60 8.30
5.78E+04 1.53 2.60 8.30 10000 1000
8.77E+04 1.50 2.60 8.30
9.37E+04 1.16 2.60 8.30
1.43E+05 1.48 2.60 8.30
1.43E+05 1.60 2.60 8.30
6.84E+04 1.06 2.60 8.30
1.24E+05 2.23 2.60 8.30
1.00E+04 1.59 2.60 8.30
3.60E+04 2.54 2.60 8.30
5.69E+04 3.83 2.60 8.30 10000 1000
8.89E+04 1.75 2.60 8.30
9.24E+04 1.86 2.60 8.30
1.45E+05 0.59 2.60 8.30
1.40E+05 0.94 2.60 8.30
6.75E+04 0.75 2.60 8.30
1.26E+05 1.94 2.60 8.30
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.38E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.87E+04 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
5.77E+04 83% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/11 5:11 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:53 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:29 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:39 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/11 4:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:31 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:54 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-968
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Cr CFS-LRef-1315-T01-D 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T02-D 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T03-D 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T04-D 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T05-D 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T06-D 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T07-D 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T08-D 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T09-D 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T01-E 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T02-E 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T03-E 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T04-E 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T05-E 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T06-E 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T07-E 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T08-E 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T09-E 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T01-F 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T02-F 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T03-F 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T04-F 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T05-F 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T06-F 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T07-F 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T08-F 1 6.00E-01 U1/2
Cr CFS-LRef-1315-T09-F 1 6.00E-01 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.00E-01 70.11 1.20 3.82
6.00E-01 6.65 1.20 3.82
6.00E-01 10.07 1.20 3.82 10000 1000
6.00E-01 31.76 1.20 3.82
6.00E-01 12.69 1.20 3.82
6.00E-01 30.52 1.20 3.82
6.00E-01 13.29 1.20 3.82
6.00E-01 45.14 1.20 3.82
6.00E-01 77.03 1.20 3.82
6.00E-01 18.45 1.20 3.82
6.00E-01 59.69 1.20 3.82
6.00E-01 43.90 1.20 3.82 10000 1000
6.00E-01 22.31 1.20 3.82
6.00E-01 57.49 1.20 3.82
6.00E-01 12.45 1.20 3.82
6.00E-01 42.51 1.20 3.82
6.00E-01 23.09 1.20 3.82
6.00E-01 61.35 1.20 3.82
6.00E-01 22.85 1.20 3.82
6.00E-01 6.11 1.20 3.82
6.00E-01 9.73 1.20 3.82 10000 1000
6.00E-01 39.68 1.20 3.82
6.00E-01 46.34 1.20 3.82
6.00E-01 218.47 1.20 3.82
6.00E-01 11.79 1.20 3.82
6.00E-01 11.69 1.20 3.82
6.00E-01 6.50 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.03E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:1 1 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:53 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:29 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:39 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/11 4:21 PM EPA Interlab LRef 1315 CFS
6/20/11 4:31 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:54 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-969
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 Mg/L
Co CFS-LRef-1315-T01-D 1 3.65E+00 E
Co CFS-LRef-1315-T02-D 1 1.25E+01
Co CFS-LRef-1315-T03-D 1 1.43E+01
Co CFS-LRef-1315-T04-D 1 3.91E+01
Co CFS-LRef-1315-T05-D 1 4.16E+01
Co CFS-LRef-1315-T06-D 1 6.03E+01
Co CFS-LRef-1315-T07-D 1 5.89E+01
Co CFS-LRef-1315-T08-D 1 2.80E+01
Co CFS-LRef-1315-T09-D 1 5.17E+01
Co CFS-LRef-1315-T01-E 1 3.91E+00 E
Co CFS-LRef-1315-T02-E 1 1.68E+01
Co CFS-LRef-1315-T03-E 1 1.25E+01
Co CFS-LRef-1315-T04-E 1 3.83E+01
Co CFS-LRef-1315-T05-E 1 4.10E+01
Co CFS-LRef-1315-T06-E 1 6.83E+01
Co CFS-LRef-1315-T07-E 1 6.60E+01
Co CFS-LRef-1315-T08-E 1 3.06E+01
Co CFS-LRef-1315-T09-E 1 4.94E+01
Co CFS-LRef-1315-T01-F 1 2.53E+00 E
Co CFS-LRef-1315-T02-F 1 1.18E+01
Co CFS-LRef-1315-T03-F 1 1.24E+01
Co CFS-LRef-1315-T04-F 1 3.63E+01
Co CFS-LRef-1315-T05-F 1 4.59E+01
Co CFS-LRef-1315-T06-F 1 6.22E+01
Co CFS-LRef-1315-T07-F 1 5.90E+01
Co CFS-LRef-1315-T08-F 1 2.69E+01
Co CFS-LRef-1315-T09-F 1 5.34E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.65E+00 23.83 1.80 5.72
1.25E+01 3.61 1.80 5.72
1.43E+01 2.25 1.80 5.72 10000 1000
3.91 E+01 2.82 1.80 5.72
4.16E+01 2.65 1.80 5.72
6.03E+01 1.39 1.80 5.72
5.89E+01 1.31 1.80 5.72
2.80E+01 8.68 1.80 5.72
5.17E+01 0.91 1.80 5.72
3.91 E+00 11.75 1.80 5.72
1.68E+01 4.86 1.80 5.72
1.25E+01 6.95 1.80 5.72 10000 1000
3.83E+01 5.85 1.80 5.72
4.10E+01 3.57 1.80 5.72
6.83E+01 2.02 1.80 5.72
6.60E+01 1.50 1.80 5.72
3.06E+01 2.61 1.80 5.72
4.94E+01 5.05 1.80 5.72
2.53E+00 26.68 1.80 5.72
1.18E+01 10.01 1.80 5.72
1.24E+01 5.67 1.80 5.72 10000 1000
3.63E+01 4.11 1.80 5.72
4.59E+01 5.17 1.80 5.72
6.22E+01 1.86 1.80 5.72
5.90E+01 2.13 1.80 5.72
2.69E+01 6.62 1.80 5.72
5.34E+01 2.22 1.80 5.72
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.05E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.05E+03 103% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/11 5:11 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:53 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:29 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:39 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:31 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:54 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-970
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Cu CFS-LRef-1315-T01-D 1 1.56E+02
Cu CFS-LRef-1315-T02-D 1 2.71E+02
Cu CFS-LRef-1315-T03-D 1 2.23E+02
Cu CFS-LRef-1315-T04-D 1 4.30E+02
Cu CFS-LRef-1315-T05-D 1 4.71E+02
Cu CFS-LRef-1315-T06-D 1 6.24E+02
Cu CFS-LRef-1315-T07-D 1 7.32E+02
Cu CFS-LRef-1315-T08-D 1 4.95E+02
Cu CFS-LRef-1315-T09-D 1 7.75E+02
Cu CFS-LRef-1315-T01-E 1 1.33E+02
Cu CFS-LRef-1315-T02-E 1 2.52E+02
Cu CFS-LRef-1315-T03-E 1 2.09E+02
Cu CFS-LRef-1315-T04-E 1 3.57E+02
Cu CFS-LRef-1315-T05-E 1 4.27E+02
Cu CFS-LRef-1315-T06-E 1 5.55E+02
Cu CFS-LRef-1315-T07-E 1 6.64E+02
Cu CFS-LRef-1315-T08-E 1 4.15E+02
Cu CFS-LRef-1315-T09-E 1 6.27E+02
Cu CFS-LRef-1315-T01-F 1 9.07E+01
Cu CFS-LRef-1315-T02-F 1 2.90E+02
Cu CFS-LRef-1315-T03-F 1 2.02E+02
Cu CFS-LRef-1315-T04-F 1 3.65E+02
Cu CFS-LRef-1315-T05-F 1 4.56E+02
Cu CFS-LRef-1315-T06-F 1 6.32E+02
Cu CFS-LRef-1315-T07-F 1 6.99E+02
Cu CFS-LRef-1315-T08-F 1 4.01 E+02
Cu CFS-LRef-1315-T09-F 1 6.65E+02
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.56E+02 1.77 3.70 11.80
2.71 E+02 0.89 3.70 11.80
2.23E+02 0.72 3.70 11.80 10000 1000
4.30E+02 0.76 3.70 11.80
4.71E+02 0.17 3.70 11.80
6.24E+02 0.92 3.70 11.80
7.32E+02 0.78 3.70 11.80
4.95E+02 12.98 3.70 11.80
7.75E+02 1.50 3.70 11.80
1.33E+02 1.05 3.70 11.80
2.52E+02 1.98 3.70 11.80
2.09E+02 2.21 3.70 11.80 10000 1000
3.57E+02 2.13 3.70 11.80
4.27E+02 0.77 3.70 11.80
5.55E+02 1.59 3.70 11.80
6.64E+02 3.05 3.70 11.80
4.15E+02 0.89 3.70 11.80
6.27E+02 2.74 3.70 11.80
9.07E+01 3.61 3.70 11.80
2.90E+02 3.08 3.70 11.80
2.02E+02 3.91 3.70 11.80 10000 1000
3.65E+02 1.93 3.70 11.80
4.56E+02 2.00 3.70 11.80
6.32E+02 1.48 3.70 11.80
6.99E+02 1.55 3.70 11.80
4.01 E+02 1.06 3.70 11.80
6.65E+02 2.20 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.19E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.16E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/11 5:01 PM EPA Interlab LRef 1315 CFS
6/20/11 5:11 PM EPA Interlab LRef 1315 CFS
6/20/11 3:27 PM EPA Interlab LRef 1315 CFS
6/20/11 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/11 4:20 PM EPA Interlab LRef 1315 CFS
6/20/11 4:30 PM EPA Interlab LRef 1315 CFS
6/20/11 4:53 PM EPA Interlab LRef 1315 CFS
6/20/11 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/11 3:29 PM EPA Interlab LRef 1315 CFS
6/20/11 3:39 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/11 4:21 PM EPA Interlab LRef 1315 CFS
6/20/11 4:31 PM EPA Interlab LRef 1315 CFS
6/20/11 4:54 PM EPA Interlab LRef 1315 CFS
6/20/11 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-971
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Fe CFS-LRef-1315-T01-D 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T02-D 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T03-D 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T04-D 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T05-D 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T06-D 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T07-D 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T08-D 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T09-D 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T01-E 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T02-E 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T03-E 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T04-E 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T05-E 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T06-E 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T07-E 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T08-E 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T09-E 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T01-F 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T02-F 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T03-F 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T04-F 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T05-F 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T06-F 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T07-F 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T08-F 1 1.00E+00 U1/2
Fe CFS-LRef-1315-T09-F 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 21.44 2.00 6.40
1.00E+00 49.28 2.00 6.40
1.00E+00 33.65 2.00 6.40 10000 1000
1.00E+00 42.17 2.00 6.40
1.00E+00 35.77 2.00 6.40
1.00E+00 26.72 2.00 6.40
1.00E+00 20.53 2.00 6.40
1.00E+00 15.31 2.00 6.40
1.00E+00 20.42 2.00 6.40
1.00E+00 32.40 2.00 6.40
1.00E+00 7.02 2.00 6.40
1.00E+00 16.66 2.00 6.40 10000 1000
1.00E+00 17.20 2.00 6.40
1.00E+00 31.47 2.00 6.40
1.00E+00 15.50 2.00 6.40
1.00E+00 72.97 2.00 6.40
1.00E+00 23.15 2.00 6.40
1.00E+00 44.18 2.00 6.40
1.00E+00 17.09 2.00 6.40
1.00E+00 11.88 2.00 6.40
1.00E+00 18.63 2.00 6.40 10000 1000
1.00E+00 15.00 2.00 6.40
1.00E+00 29.04 2.00 6.40
1.00E+00 18.38 2.00 6.40
1.00E+00 62.33 2.00 6.40
1.00E+00 35.31 2.00 6.40
1.00E+00 22.51 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.10E+03 110% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.04E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:1 1 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:53 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/11 3:29 PM EPA Interlab LRef 1315 CFS
6/20/11 3:39 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/11 4:21 PM EPA Interlab LRef 1315 CFS
6/20/11 4:31 PM EPA Interlab LRef 1315 CFS
6/20/11 4:54 PM EPA Interlab LRef 1315 CFS
6/20/11 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-972
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Pb CFS-LRef-1315-T01-D 1 1.06E+02
Pb CFS-LRef-1315-T02-D 1 2.20E+02
Pb CFS-LRef-1315-T03-D 1 2.37E+02
Pb CFS-LRef-1315-T04-D 1 4.64E+02
Pb CFS-LRef-1315-T05-D 1 3.99E+02
Pb CFS-LRef-1315-T06-D 1 5.42E+02
Pb CFS-LRef-1315-T07-D 1 6.07E+02
Pb CFS-LRef-1315-T08-D 1 4.28E+02
Pb CFS-LRef-1315-T09-D 1 6.63E+02
Pb CFS-LRef-1315-T01-E 1 9.74E+01
Pb CFS-LRef-1315-T02-E 1 2.08E+02
Pb CFS-LRef-1315-T03-E 1 1.92E+02
Pb CFS-LRef-1315-T04-E 1 3.39E+02
Pb CFS-LRef-1315-T05-E 1 3.46E+02
Pb CFS-LRef-1315-T06-E 1 5.05E+02
Pb CFS-LRef-1315-T07-E 1 5.32E+02
Pb CFS-LRef-1315-T08-E 1 3.26E+02
Pb CFS-LRef-1315-T09-E 1 4.52E+02
Pb CFS-LRef-1315-T01-F 1 6.69E+01
Pb CFS-LRef-1315-T02-F 1 1.77E+02
Pb CFS-LRef-1315-T03-F 1 1.75E+02
Pb CFS-LRef-1315-T04-F 1 3.14E+02
Pb CFS-LRef-1315-T05-F 1 3.88E+02
Pb CFS-LRef-1315-T06-F 1 4.86E+02
Pb CFS-LRef-1315-T07-F 1 4.84E+02
Pb CFS-LRef-1315-T08-F 1 2.82E+02
Pb CFS-LRef-1315-T09-F 1 5.11E+02
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.06E+02 9.00 6.80 21.60
2.20E+02 1.97 6.80 21.60
2.37E+02 3.36 6.80 21.60 10000 1000
4.64E+02 2.01 6.80 21.60
3.99E+02 1.62 6.80 21.60
5.42E+02 0.31 6.80 21.60
6.07E+02 1.36 6.80 21.60
4.28E+02 1.23 6.80 21.60
6.63E+02 1.88 6.80 21.60
9.74E+01 4.54 6.80 21.60
2.08E+02 1.42 6.80 21.60
1.92E+02 4.00 6.80 21.60 10000 1000
3.39E+02 1.52 6.80 21.60
3.46E+02 1.12 6.80 21.60
5.05E+02 0.93 6.80 21.60
5.32E+02 0.68 6.80 21.60
3.26E+02 1.50 6.80 21.60
4.52E+02 2.71 6.80 21.60
6.69E+01 3.94 6.80 21.60
1.77E+02 3.05 6.80 21.60
1.75E+02 3.63 6.80 21.60 10000 1000
3.14E+02 0.92 6.80 21.60
3.88E+02 0.58 6.80 21.60
4.86E+02 1.02 6.80 21.60
4.84E+02 1.65 6.80 21.60
2.82E+02 0.90 6.80 21.60
5.11E+02 1.81 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.24E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.24E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.20E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:1 1 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:53 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:29 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:39 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:21 PM EPA Interlab LRef 1315 CFS
6/20/11 4:31 PM EPA Interlab LRef 1315 CFS
6/20/11 4:54 PM EPA Interlab LRef 1315 CFS
6/20/11 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-973
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Li CFS-LRef-1315-T01-D 1 2.82E+00 E
Li CFS-LRef-1315-T02-D 1 3.31E+00 E
Li CFS-LRef-1315-T03-D 1 5.68E+00 E
Li CFS-LRef-1315-T04-D 1 6.71E+00
Li CFS-LRef-1315-T05-D 1 7.49E+00
Li CFS-LRef-1315-T06-D 1 7.96E+00
Li CFS-LRef-1315-T07-D 1 9.13E+00
Li CFS-LRef-1315-T08-D 1 7.67E+00
Li CFS-LRef-1315-T09-D 1 8.44E+00
Li CFS-LRef-1315-T01-E 1 2.06E+00 E
Li CFS-LRef-1315-T02-E 1 2.87E+00 E
Li CFS-LRef-1315-T03-E 1 5.35E+00 E
Li CFS-LRef-1315-T04-E 1 5.75E+00 E
Li CFS-LRef-1315-T05-E 1 7.37E+00
Li CFS-LRef-1315-T06-E 1 7.31E+00
Li CFS-LRef-1315-T07-E 1 7.59E+00
Li CFS-LRef-1315-T08-E 1 6.46E+00
Li CFS-LRef-1315-T09-E 1 8.15E+00
Li CFS-LRef-1315-T01-F 1 2.62E+00 E
Li CFS-LRef-1315-T02-F 1 3.79E+00 E
Li CFS-LRef-1315-T03-F 1 3.62E+00 E
Li CFS-LRef-1315-T04-F 1 6.27E+00
Li CFS-LRef-1315-T05-F 1 8.38E+00
Li CFS-LRef-1315-T06-F 1 7.94E+00
Li CFS-LRef-1315-T07-F 1 7.82E+00
Li CFS-LRef-1315-T08-F 1 8.00E+00
Li CFS-LRef-1315-T09-F 1 8.45E+00
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.82E+00 15.15 1.90 6.00
3.31E+00 32.14 1.90 6.00
5.68E+00 6.65 1.90 6.00 10000 1000
6.71 E+00 1.92 1.90 6.00
7.49E+00 1.15 1.90 6.00
7.96E+00 2.62 1.90 6.00
9.13E+00 2.71 1.90 6.00
7.67E+00 11.05 1.90 6.00
8.44E+00 9.77 1.90 6.00
2.06E+00 9.29 1.90 6.00
2.87E+00 72.30 1.90 6.00
5.35E+00 11.61 1.90 6.00 10000 1000
5.75E+00 19.49 1.90 6.00
7.37E+00 2.79 1.90 6.00
7. 31 E+00 9.55 1.90 6.00
7.59E+00 3.13 1.90 6.00
6.46E+00 1.78 1.90 6.00
8.15E+00 16.44 1.90 6.00
2.62E+00 38.60 1.90 6.00
3.79E+00 28.12 1.90 6.00
3.62E+00 18.28 1.90 6.00 10000 1000
6.27E+00 6.29 1.90 6.00
8.38E+00 1.25 1.90 6.00
7.94E+00 3.48 1.90 6.00
7.82E+00 5.14 1.90 6.00
8.00E+00 1.96 1.90 6.00
8.45E+00 2.73 1.90 6.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
8.80E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.73E+02 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.82E+02 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/11 5:11 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:53 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:29 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:39 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/11 4:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:31 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:54 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-974
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Mn CFS-LRef-1315-T01-D 1 5.55E+01
Mn CFS-LRef-1315-T02-D 1 3.06E+02
Mn CFS-LRef-1315-T03-D 1 3.12E+02
Mn CFS-LRef-1315-T04-D 1 9.71E+02
Mn CFS-LRef-1315-T05-D 1 1.03E+03
Mn CFS-LRef-1315-T06-D 1 1.68E+03
Mn CFS-LRef-1315-T07-D 1 1.70E+03
Mn CFS-LRef-1315-T08-D 1 7.80E+02
Mn CFS-LRef-1315-T09-D 1 1.53E+03
Mn CFS-LRef-1315-T01-E 1 5.86E+01
Mn CFS-LRef-1315-T02-E 1 4.49E+02
Mn CFS-LRef-1315-T03-E 1 3.51E+02
Mn CFS-LRef-1315-T04-E 1 1.10E+03
Mn CFS-LRef-1315-T05-E 1 1.04E+03
Mn CFS-LRef-1315-T06-E 1 2.06E+03
Mn CFS-LRef-1315-T07-E 1 2.08E+03
Mn CFS-LRef-1315-T08-E 1 9.30E+02
Mn CFS-LRef-1315-T09-E 1 1.45E+03
Mn CFS-LRef-1315-T01-F 1 4.37E+01
Mn CFS-LRef-1315-T02-F 1 2.68E+02
Mn CFS-LRef-1315-T03-F 1 2.80E+02
Mn CFS-LRef-1315-T04-F 1 9.05E+02
Mn CFS-LRef-1315-T05-F 1 1.28E+03
Mn CFS-LRef-1315-T06-F 1 1.68E+03
Mn CFS-LRef-1315-T07-F 1 1.68E+03
Mn CFS-LRef-1315-T08-F 1 7.74E+02
Mn CFS-LRef-1315-T09-F 1 1.74E+03
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
5.55E+01 1.26 2.00 6.40
3.06E+02 1.37 2.00 6.40
3.12E+02 1.55 2.00 6.40 10000 1000
9.71 E+02 0.39 2.00 6.40
1.03E+03 0.40 2.00 6.40
1.68E+03 0.87 2.00 6.40
1.70E+03 1.17 2.00 6.40
7.80E+02 8.38 2.00 6.40
1.53E+03 2.64 2.00 6.40
5.86E+01 2.27 2.00 6.40
4.49E+02 2.30 2.00 6.40
3.51E+02 1.92 2.00 6.40 10000 1000
1.10E+03 0.60 2.00 6.40
1.04E+03 2.07 2.00 6.40
2.06E+03 2.11 2.00 6.40
2.08E+03 0.90 2.00 6.40
9.30E+02 0.71 2.00 6.40
1.45E+03 0.43 2.00 6.40
4.37E+01 1.77 2.00 6.40
2.68E+02 2.39 2.00 6.40
2.80E+02 2.85 2.00 6.40 10000 1000
9.05E+02 1.06 2.00 6.40
1.28E+03 1.88 2.00 6.40
1.68E+03 0.89 2.00 6.40
1.68E+03 1.30 2.00 6.40
7.74E+02 0.75 2.00 6.40
1.74E+03 1.63 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.27E+03 96% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.27E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.22E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:1 1 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:53 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:29 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:39 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:21 PM EPA Interlab LRef 1315 CFS
6/20/11 4:31 PM EPA Interlab LRef 1315 CFS
6/20/11 4:54 PM EPA Interlab LRef 1315 CFS
6/20/11 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-975
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Mg CFS-LRef-1315-T01-D 1 3.96E+03
Mg CFS-LRef-1315-T02-D 1 2.12E+04
Mg CFS-LRef-1315-T03-D 1 2.06E+04
Mg CFS-LRef-1315-T04-D 1 6.43E+04
Mg CFS-LRef-1315-T05-D 1 6.45E+04
Mg CFS-LRef-1315-T06-D 1 9.57E+04
Mg CFS-LRef-1315-T07-D 1 8.83E+04
Mg CFS-LRef-1315-T08-D 1 3.77E+04
Mg CFS-LRef-1315-T09-D 1 6.77E+04
Mg CFS-LRef-1315-T01-E 1 4.08E+03
Mg CFS-LRef-1315-T02-E 1 2.77E+04
Mg CFS-LRef-1315-T03-E 1 1.94E+04
Mg CFS-LRef-1315-T04-E 1 5.79E+04
Mg CFS-LRef-1315-T05-E 1 6.27E+04
Mg CFS-LRef-1315-T06-E 1 9.35E+04
Mg CFS-LRef-1315-T07-E 1 8.73E+04
Mg CFS-LRef-1315-T08-E 1 3.59E+04
Mg CFS-LRef-1315-T09-E 1 6.51E+04
Mg CFS-LRef-1315-T01-F 1 2.92E+03
Mg CFS-LRef-1315-T02-F 1 1.78E+04
Mg CFS-LRef-1315-T03-F 1 1.82E+04
Mg CFS-LRef-1315-T04-F 1 5.82E+04
Mg CFS-LRef-1315-T05-F 1 6.23E+04
Mg CFS-LRef-1315-T06-F 1 9.57E+04
Mg CFS-LRef-1315-T07-F 1 8.61 E+04
Mg CFS-LRef-1315-T08-F 1 3.67E+04
Mg CFS-LRef-1315-T09-F 1 6.58E+04
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.96E+03 1.83 1.00 3.18
2.12E+04 0.62 1.00 3.18
2.06E+04 1.97 1.00 3.18 10000 1000
6.43E+04 1.44 1.00 3.18
6.45E+04 0.35 1.00 3.18
9.57E+04 0.73 1.00 3.18
8.83E+04 1.55 1.00 3.18
3.77E+04 9.26 1.00 3.18
6.77E+04 1.21 1.00 3.18
4.08E+03 1.20 1.00 3.18
2.77E+04 2.16 1.00 3.18
1.94E+04 1.90 1.00 3.18 10000 1000
5.79E+04 1.61 1.00 3.18
6.27E+04 1.19 1.00 3.18
9.35E+04 1.73 1.00 3.18
8.73E+04 1.95 1.00 3.18
3.59E+04 1.77 1.00 3.18
6.51E+04 2.36 1.00 3.18
2.92E+03 2.03 1.00 3.18
1.78E+04 2.09 1.00 3.18
1.82E+04 3.65 1.00 3.18 10000 1000
5.82E+04 1.64 1.00 3.18
6.23E+04 1.41 1.00 3.18
9.57E+04 1.15 1.00 3.18
8.61E+04 1.38 1.00 3.18
3.67E+04 1.09 1.00 3.18
6.58E+04 1.16 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.14E+04 86% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.03E+04 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.92E+04 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:1 1 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:53 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:29 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:39 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:21 PM EPA Interlab LRef 1315 CFS
6/20/11 4:31 PM EPA Interlab LRef 1315 CFS
6/20/11 4:54 PM EPA Interlab LRef 1315 CFS
6/20/11 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-976
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
Mo CFS-LRef-1315-T01-D 1 1.33E+00 E
Mo CFS-LRef-1315-T02-D 1 2.16E+00 E
Mo CFS-LRef-1315-T03-D 1 2.03E+00 E
Mo CFS-LRef-1315-T04-D 1 2.94E+00 E
Mo CFS-LRef-1315-T05-D 1 3.28E+00 E
Mo CFS-LRef-1315-T06-D 1 3.19E+00 E
Mo CFS-LRef-1315-T07-D 1 2.22E+00 E
Mo CFS-LRef-1315-T08-D 1 2.18E+00 E
Mo CFS-LRef-1315-T09-D 1 1.59E+00 E
Mo CFS-LRef-1315-T01-E 1 1.35E+00 E
Mo CFS-LRef-1315-T02-E 1 1.71E+00 E
Mo CFS-LRef-1315-T03-E 1 2.45E+00 E
Mo CFS-LRef-1315-T04-E 1 2.96E+00 E
Mo CFS-LRef-1315-T05-E 1 3.29E+00 E
Mo CFS-LRef-1315-T06-E 1 2.72E+00 E
Mo CFS-LRef-1315-T07-E 1 3.04E+00 E
Mo CFS-LRef-1315-T08-E 1 2.49E+00 E
Mo CFS-LRef-1315-T09-E 1 1.95E+00 E
Mo CFS-LRef-1315-T01-F 1 1.74E+00 E
Mo CFS-LRef-1315-T02-F 1 2.43E+00 E
Mo CFS-LRef-1315-T03-F 1 2.89E+00 E
Mo CFS-LRef-1315-T04-F 1 2.70E+00 E
Mo CFS-LRef-1315-T05-F 1 2.92E+00 E
Mo CFS-LRef-1315-T06-F 1 3.27E+00 E
Mo CFS-LRef-1315-T07-F 1 2.75E+00 E
Mo CFS-LRef-1315-T08-F 1 2.12E+00 E
Mo CFS-LRef-1315-T09-F 1 2.31E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.33E+00 24.99 1.20 3.82
2.16E+00 5.49 1.20 3.82
2.03E+00 7.82 1.20 3.82 10000 1000
2.94E+00 15.79 1.20 3.82
3.28E+00 33.00 1.20 3.82
3.19E+00 10.96 1.20 3.82
2.22E+00 19.10 1.20 3.82
2.18E+00 5.62 1.20 3.82
1.59E+00 14.30 1.20 3.82
1.35E+00 34.03 1.20 3.82
1.71E+00 15.68 1.20 3.82
2.45E+00 27.46 1.20 3.82 10000 1000
2.96E+00 30.97 1.20 3.82
3.29E+00 28.84 1.20 3.82
2.72E+00 15.64 1.20 3.82
3.04E+00 5.75 1.20 3.82
2.49E+00 23.79 1.20 3.82
1.95E+00 14.24 1.20 3.82
1.74E+00 5.72 1.20 3.82
2.43E+00 33.59 1.20 3.82
2.89E+00 37.10 1.20 3.82 10000 1000
2.70E+00 22.61 1.20 3.82
2.92E+00 14.67 1.20 3.82
3.27E+00 20.97 1.20 3.82
2.75E+00 7.97 1.20 3.82
2.12E+00 9.69 1.20 3.82
2.31E+00 32.11 1.20 3.82
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.01E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/11 5:11 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:53 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:29 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:39 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:31 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:54 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-977
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Ni CFS-LRef-1315-T01-D 1 4.85E+00 E
Ni CFS-LRef-1315-T02-D 1 2.31E+01
Ni CFS-LRef-1315-T03-D 1 2.03E+01
Ni CFS-LRef-1315-T04-D 1 6.57E+01
Ni CFS-LRef-1315-T05-D 1 6.82E+01
Ni CFS-LRef-1315-T06-D 1 9.65E+01
Ni CFS-LRef-1315-T07-D 1 8.72E+01
Ni CFS-LRef-1315-T08-D 1 4.07E+01
Ni CFS-LRef-1315-T09-D 1 7.14E+01
Ni CFS-LRef-1315-T01-E 1 4.04E+00 E
Ni CFS-LRef-1315-T02-E 1 2.64E+01
Ni CFS-LRef-1315-T03-E 1 2.05E+01
Ni CFS-LRef-1315-T04-E 1 5.71E+01
Ni CFS-LRef-1315-T05-E 1 6.45E+01
Ni CFS-LRef-1315-T06-E 1 9.34E+01
Ni CFS-LRef-1315-T07-E 1 8.40E+01
Ni CFS-LRef-1315-T08-E 1 3.61E+01
Ni CFS-LRef-1315-T09-E 1 6.73E+01
Ni CFS-LRef-1315-T01-F 1 4.83E+00 E
Ni CFS-LRef-1315-T02-F 1 1.94E+01
Ni CFS-LRef-1315-T03-F 1 1.77E+01
Ni CFS-LRef-1315-T04-F 1 5.95E+01
Ni CFS-LRef-1315-T05-F 1 6.40E+01
Ni CFS-LRef-1315-T06-F 1 9.77E+01
Ni CFS-LRef-1315-T07-F 1 8.71E+01
Ni CFS-LRef-1315-T08-F 1 3.86E+01
Ni CFS-LRef-1315-T09-F 1 6.53E+01
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.85E+00 7.31 1.80 5.70
2.31 E+01 6.80 1.80 5.70
2.03E+01 7.27 1.80 5.70 10000 1000
6.57E+01 10.79 1.80 5.70
6.82E+01 2.19 1.80 5.70
9.65E+01 2.43 1.80 5.70
8.72E+01 0.68 1.80 5.70
4.07E+01 6.51 1.80 5.70
7.14E+01 3.46 1.80 5.70
4.04E+00 13.48 1.80 5.70
2.64E+01 1.33 1.80 5.70
2.05E+01 1.12 1.80 5.70 10000 1000
5.71 E+01 3.95 1.80 5.70
6.45E+01 2.43 1.80 5.70
9.34E+01 3.51 1.80 5.70
8.40E+01 2.88 1.80 5.70
3.61 E+01 5.22 1.80 5.70
6.73E+01 2.58 1.80 5.70
4.83E+00 18.09 1.80 5.70
1.94E+01 5.46 1.80 5.70
1.77E+01 2.99 1.80 5.70 10000 1000
5.95E+01 2.00 1.80 5.70
6.40E+01 0.67 1.80 5.70
9.77E+01 0.32 1.80 5.70
8.71 E+01 2.63 1.80 5.70
3.86E+01 9.78 1.80 5.70
6.53E+01 1.98 1.80 5.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.08E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 105% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.11E+03 109% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/11 5:11 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:53 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:29 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:39 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:31 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:54 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-978
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L 1
P CFS-LRef-1315-T01-D 1 3.95E+00 E
P CFS-LRef-1315-T02-D 1 1.08E+01 E
P CFS-LRef-1315-T03-D 1 1.16E+01 E
P CFS-LRef-1315-T04-D 1 1.08E+01 E
P CFS-LRef-1315-T05-D 1 9.31E+00 E
P CFS-LRef-1315-T06-D 1 8.89E+00 E
P CFS-LRef-1315-T07-D 1 6.97E+00 E
P CFS-LRef-1315-T08-D 1 5.33E+00 E
P CFS-LRef-1315-T09-D 1 4.33E+00 E
P CFS-LRef-1315-T01-E 1 3.85E+00 E
P CFS-LRef-1315-T02-E 1 1.09E+01 E
P CFS-LRef-1315-T03-E 1 1.08E+01 E
P CFS-LRef-1315-T04-E 1 9.32E+00 E
P CFS-LRef-1315-T05-E 1 8.75E+00 E
P CFS-LRef-1315-T06-E 1 8.94E+00 E
P CFS-LRef-1315-T07-E 1 6.57E+00 E
P CFS-LRef-1315-T08-E 1 6.48E+00 E
P CFS-LRef-1315-T09-E 1 4.87E+00 E
P CFS-LRef-1315-T01-F 1 5.53E+00 E
P CFS-LRef-1315-T02-F 1 1.19E+01
P CFS-LRef-1315-T03-F 1 1.16E+01 E
P CFS-LRef-1315-T04-F 1 9.85E+00 E
P CFS-LRef-1315-T05-F 1 8.99E+00 E
P CFS-LRef-1315-T06-F 1 7.74E+00 E
P CFS-LRef-1315-T07-F 1 5.42E+00 E
P CFS-LRef-1315-T08-F 1 5.68E+00 E
P CFS-LRef-1315-T09-F 1 6.06E+00 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.95E+00 38.98 3.70 11.80
1.08E+01 26.96 3.70 11.80
1.16E+01 10.81 3.70 11.80 10000 1000
1.08E+01 25.42 3.70 11.80
9.31E+00 16.55 3.70 11.80
8.89E+00 39.29 3.70 11.80
6.97E+00 15.86 3.70 11.80
5.33E+00 12.63 3.70 11.80
4.33E+00 40.66 3.70 11.80
3.85E+00 29.38 3.70 11.80
1.09E+01 25.40 3.70 11.80
1.08E+01 16.23 3.70 11.80 10000 1000
9.32E+00 1.24 3.70 11.80
8.75E+00 26.18 3.70 11.80
8.94E+00 11.31 3.70 11.80
6.57E+00 67.71 3.70 11.80
6.48E+00 45.63 3.70 11.80
4.87E+00 30.79 3.70 11.80
5.53E+00 13.81 3.70 11.80
1.19E+01 18.84 3.70 11.80
1.16E+01 27.97 3.70 11.80 10000 1000
9.85E+00 40.00 3.70 11.80
8.99E+00 4.95 3.70 11.80
7.74E+00 31.54 3.70 11.80
5.42E+00 20.17 3.70 11.80
5.68E+00 14.71 3.70 11.80
6.06E+00 9.86 3.70 11.80
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 99% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.03E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:1 1 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:53 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:29 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:39 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/11 4:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:31 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:54 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-979
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
K CFS-LRef-1315-T01-D 1 4.00E+02
K CFS-LRef-1315-T02-D 1 2.45E+03
K CFS-LRef-1315-T03-D 1 2.09E+03
K CFS-LRef-1315-T04-D 1 6.71E+03
K CFS-LRef-1315-T05-D 1 6.57E+03
K CFS-LRef-1315-T06-D 1 9.66E+03
K CFS-LRef-1315-T07-D 1 8.44E+03
K CFS-LRef-1315-T08-D 1 3.40E+03
K CFS-LRef-1315-T09-D 1 6.18E+03
K CFS-LRef-1315-T01-E 1 4.23E+02
K CFS-LRef-1315-T02-E 1 2.77E+03
K CFS-LRef-1315-T03-E 1 2.02E+03
K CFS-LRef-1315-T04-E 1 6.20E+03
K CFS-LRef-1315-T05-E 1 6.51E+03
K CFS-LRef-1315-T06-E 1 9.82E+03
K CFS-LRef-1315-T07-E 1 8.70E+03
K CFS-LRef-1315-T08-E 1 3.39E+03
K CFS-LRef-1315-T09-E 1 5.89E+03
K CFS-LRef-1315-T01-F 1 3.31E+02
K CFS-LRef-1315-T02-F 1 2.18E+03
K CFS-LRef-1315-T03-F 1 1.94E+03
K CFS-LRef-1315-T04-F 1 6.29E+03
K CFS-LRef-1315-T05-F 1 6.56E+03
K CFS-LRef-1315-T06-F 1 9.76E+03
K CFS-LRef-1315-T07-F 1 8.43E+03
K CFS-LRef-1315-T08-F 1 3.33E+03
K CFS-LRef-1315-T09-F 1 6.11E+03
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.00E+02 2.13 1.60 5.09
2.45E+03 0.09 1.60 5.09
2.09E+03 0.93 1.60 5.09 10000 1000
6.71 E+03 1.45 1.60 5.09
6.57E+03 0.98 1.60 5.09
9.66E+03 0.54 1.60 5.09
8.44E+03 0.18 1.60 5.09
3.40E+03 1.69 1.60 5.09
6.18E+03 1.30 1.60 5.09
4.23E+02 1.65 1.60 5.09
2.77E+03 1.53 1.60 5.09
2.02E+03 1.78 1.60 5.09 10000 1000
6.20E+03 2.14 1.60 5.09
6.51E+03 1.05 1.60 5.09
9.82E+03 1.58 1.60 5.09
8.70E+03 1.27 1.60 5.09
3.39E+03 1.40 1.60 5.09
5.89E+03 2.60 1.60 5.09
3.31E+02 2.15 1.60 5.09
2.18E+03 2.13 1.60 5.09
1.94E+03 3.30 1.60 5.09 10000 1000
6.29E+03 1.77 1.60 5.09
6.56E+03 1.86 1.60 5.09
9.76E+03 0.71 1.60 5.09
8.43E+03 1.05 1.60 5.09
3.33E+03 0.98 1.60 5.09
6.11E+03 1.69 1.60 5.09
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.97E+03 88% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.95E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.89E+03 95% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:1 1 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/11 4:30 PM EPA Interlab LRef 1315 CFS
6/20/11 4:53 PM EPA Interlab LRef 1315 CFS
6/20/11 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/11 3:29 PM EPA Interlab LRef 1315 CFS
6/20/11 3:39 PM EPA Interlab LRef 1315 CFS
6/20/11 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/11 4:21 PM EPA Interlab LRef 1315 CFS
6/20/11 4:31 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:54 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-980
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 1 M9/L
Se CFS-LRef-1315-T01-D 1 1.89E+01 E
Se CFS-LRef-1315-T02-D 1 2.13E+01 E
Se CFS-LRef-1315-T03-D 1 2.70E+01 E
Se CFS-LRef-1315-T04-D 1 7.19E+01
Se CFS-LRef-1315-T05-D 1 7.07E+01
Se CFS-LRef-1315-T06-D 1 1.02E+02
Se CFS-LRef-1315-T07-D 1 8.09E+01
Se CFS-LRef-1315-T08-D 1 2.87E+01 E
Se CFS-LRef-1315-T09-D 1 4.56E+01 E
Se CFS-LRef-1315-T01-E 1 1.73E+01 E
Se CFS-LRef-1315-T02-E 1 2.14E+01 E
Se CFS-LRef-1315-T03-E 1 2.45E+01 E
Se CFS-LRef-1315-T04-E 1 6.40E+01
Se CFS-LRef-1315-T05-E 1 6.62E+01
Se CFS-LRef-1315-T06-E 1 9.25E+01
Se CFS-LRef-1315-T07-E 1 7.79E+01
Se CFS-LRef-1315-T08-E 1 4.30E+01 E
Se CFS-LRef-1315-T09-E 1 4.88E+01
Se CFS-LRef-1315-T01-F 1 1.65E+01 E
Se CFS-LRef-1315-T02-F 1 2.23E+01 E
Se CFS-LRef-1315-T03-F 1 2.99E+01 E
Se CFS-LRef-1315-T04-F 1 5.90E+01
Se CFS-LRef-1315-T05-F 1 5.12E+01
Se CFS-LRef-1315-T06-F 1 8.69E+01
Se CFS-LRef-1315-T07-F 1 8.80E+01
Se CFS-LRef-1315-T08-F 1 3.48E+01 E
Se CFS-LRef-1315-T09-F 1 4.27E+01 E
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.89E+01 4.29 15.00 47.70
2.13E+01 12.85 15.00 47.70
2.70E+01 13.45 15.00 47.70 10000 1000
7.19E+01 2.60 15.00 47.70
7.07E+01 9.53 15.00 47.70
1.02E+02 15.42 15.00 47.70
8.09E+01 2.57 15.00 47.70
2.87E+01 17.09 15.00 47.70
4.56E+01 25.25 15.00 47.70
1.73E+01 6.94 15.00 47.70
2.14E+01 16.58 15.00 47.70
2.45E+01 6.84 15.00 47.70 10000 1000
6.40E+01 1.72 15.00 47.70
6.62E+01 4.52 15.00 47.70
9.25E+01 2.61 15.00 47.70
7.79E+01 1.32 15.00 47.70
4.30E+01 3.28 15.00 47.70
4.88E+01 2.90 15.00 47.70
1.65E+01 2.34 15.00 47.70
2.23E+01 8.76 15.00 47.70
2.99E+01 11.00 15.00 47.70 10000 1000
5.90E+01 3.56 15.00 47.70
5.12E+01 12.61 15.00 47.70
8.69E+01 1.61 15.00 47.70
8.80E+01 3.26 15.00 47.70
3.48E+01 16.25 15.00 47.70
4.27E+01 9.33 15.00 47.70
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.08E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.06E+03 104% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.10E+03 107% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:1 1 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:53 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:29 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:39 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/11 4:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:31 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:54 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-981
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 ug/L
Si CFS-LRef-1315-T01-D 1 6.20E+01
Si CFS-LRef-1315-T02-D 1 2.72E+02
Si CFS-LRef-1315-T03-D 1 3.57E+02
Si CFS-LRef-1315-T04-D 1 9.45E+02
Si CFS-LRef-1315-T05-D 1 1.03E+03
Si CFS-LRef-1315-T06-D 1 1.54E+03
Si CFS-LRef-1315-T07-D 1 1.55E+03
Si CFS-LRef-1315-T08-D 1 8.16E+02
Si CFS-LRef-1315-T09-D 1 1.48E+03
Si CFS-LRef-1315-T01-E 1 5.86E+01
Si CFS-LRef-1315-T02-E 1 2.85E+02
Si CFS-LRef-1315-T03-E 1 3.29E+02
Si CFS-LRef-1315-T04-E 1 7.99E+02
Si CFS-LRef-1315-T05-E 1 9.84E+02
Si CFS-LRef-1315-T06-E 1 1.43E+03
Si CFS-LRef-1315-T07-E 1 1.46E+03
Si CFS-LRef-1315-T08-E 1 7.11E+02
Si CFS-LRef-1315-T09-E 1 1.30E+03
Si CFS-LRef-1315-T01-F 1 6.42E+01
Si CFS-LRef-1315-T02-F 1 2.83E+02
Si CFS-LRef-1315-T03-F 1 3.30E+02
Si CFS-LRef-1315-T04-F 1 8.36E+02
Si CFS-LRef-1315-T05-F 1 9.51E+02
Si CFS-LRef-1315-T06-F 1 1.51E+03
Si CFS-LRef-1315-T07-F 1 1.48E+03
Si CFS-LRef-1315-T08-F 1 7.35E+02
Si CFS-LRef-1315-T09-F 1 1.30E+03
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
6.20E+01 1.81 1.10 3.50
2.72E+02 0.67 1.10 3.50
3.57E+02 2.76 1.10 3.50 10000 1000
9.45E+02 2.54 1.10 3.50
1.03E+03 0.44 1.10 3.50
1.54E+03 0.95 1.10 3.50
1.55E+03 0.34 1.10 3.50
8.16E+02 9.92 1.10 3.50
1.48E+03 1.69 1.10 3.50
5.86E+01 1.04 1.10 3.50
2.85E+02 2.16 1.10 3.50
3.29E+02 1.15 1.10 3.50 10000 1000
7.99E+02 1.66 1.10 3.50
9.84E+02 0.74 1.10 3.50
1.43E+03 1.73 1.10 3.50
1.46E+03 1.76 1.10 3.50
7.11E+02 1.69 1.10 3.50
1.30E+03 3.22 1.10 3.50
6.42E+01 2.29 1.10 3.50
2.83E+02 1.20 1.10 3.50
3.30E+02 3.36 1.10 3.50 10000 1000
8.36E+02 1.58 1.10 3.50
9.51E+02 2.20 1.10 3.50
1.51E+03 0.67 1.10 3.50
1.48E+03 1.61 1.10 3.50
7.35E+02 0.72 1.10 3.50
1.30E+03 1.62 1.10 3.50
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.30E+03 94% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.39E+03 106% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.34E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:1 1 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:53 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:29 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:39 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:21 PM EPA Interlab LRef 1315 CFS
6/20/11 4:31 PM EPA Interlab LRef 1315 CFS
6/20/11 4:54 PM EPA Interlab LRef 1315 CFS
6/20/11 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-982
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
Na CFS-LRef-1315-T01-D 1 1.80E+03
Na CFS-LRef-1315-T02-D 1 1.03E+04
Na CFS-LRef-1315-T03-D 1 8.81E+03
Na CFS-LRef-1315-T04-D 1 2.59E+04
Na CFS-LRef-1315-T05-D 1 2.43E+04
Na CFS-LRef-1315-T06-D 1 3.45E+04
Na CFS-LRef-1315-T07-D 1 2.81E+04
Na CFS-LRef-1315-T08-D 1 1.06E+04
Na CFS-LRef-1315-T09-D 1 1.82E+04
Na CFS-LRef-1315-T01-E 1 1.83E+03
Na CFS-LRef-1315-T02-E 1 1.22E+04
Na CFS-LRef-1315-T03-E 1 8.11E+03
Na CFS-LRef-1315-T04-E 1 2.39E+04
Na CFS-LRef-1315-T05-E 1 2.43E+04
Na CFS-LRef-1315-T06-E 1 3.38E+04
Na CFS-LRef-1315-T07-E 1 2.80E+04
Na CFS-LRef-1315-T08-E 1 1.03E+04
Na CFS-LRef-1315-T09-E 1 1.77E+04
Na CFS-LRef-1315-T01-F 1 1.41E+03
Na CFS-LRef-1315-T02-F 1 8.85E+03
Na CFS-LRef-1315-T03-F 1 7.97E+03
Na CFS-LRef-1315-T04-F 1 2.46E+04
Na CFS-LRef-1315-T05-F 1 2.42E+04
Na CFS-LRef-1315-T06-F 1 3.41E+04
Na CFS-LRef-1315-T07-F 1 2.81E+04
Na CFS-LRef-1315-T08-F 1 1.04E+04
Na CFS-LRef-1315-T09-F 1 1.77E+04
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.80E+03 0.54 2.50 8.00
1.03E+04 0.65 2.50 8.00
8.81E+03 0.48 2.50 8.00 10000 1000
2.59E+04 0.79 2.50 8.00
2.43E+04 0.71 2.50 8.00
3.45E+04 1.32 2.50 8.00
2.81E+04 0.58 2.50 8.00
1.06E+04 5.27 2.50 8.00
1.82E+04 0.51 2.50 8.00
1.83E+03 1.13 2.50 8.00
1.22E+04 0.56 2.50 8.00
8.11E+03 1.52 2.50 8.00 10000 1000
2.39E+04 1.20 2.50 8.00
2.43E+04 0.28 2.50 8.00
3.38E+04 0.73 2.50 8.00
2.80E+04 0.16 2.50 8.00
1.03E+04 1.63 2.50 8.00
1.77E+04 1.23 2.50 8.00
1.41E+03 1.37 2.50 8.00
8.85E+03 0.79 2.50 8.00
7.97E+03 0.27 2.50 8.00 10000 1000
2.46E+04 0.48 2.50 8.00
2.42E+04 1.39 2.50 8.00
3.41 E+04 0.53 2.50 8.00
2.81 E+04 0.31 2.50 8.00
1.04E+04 0.36 2.50 8.00
1.77E+04 0.88 2.50 8.00
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
9.72E+03 91% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
9.03E+03 92% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
8.90E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/11 5:11 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:53 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:29 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:39 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/11 4:21 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:31 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:54 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-983
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qual
1 1 1 M9/L
Sr CFS-LRef-1315-T01-D 1 3.62E+01
Sr CFS-LRef-1315-T02-D 1 1.46E+02
Sr CFS-LRef-1315-T03-D 1 1.47E+02
Sr CFS-LRef-1315-T04-D 1 4.59E+02
Sr CFS-LRef-1315-T05-D 1 4.99E+02
Sr CFS-LRef-1315-T06-D 1 7.97E+02
Sr CFS-LRef-1315-T07-D 1 8.18E+02
Sr CFS-LRef-1315-T08-D 1 3.99E+02
Sr CFS-LRef-1315-T09-D 1 7.39E+02
Sr CFS-LRef-1315-T01-E 1 3.50E+01
Sr CFS-LRef-1315-T02-E 1 1.74E+02
Sr CFS-LRef-1315-T03-E 1 1.34E+02
Sr CFS-LRef-1315-T04-E 1 4.02E+02
Sr CFS-LRef-1315-T05-E 1 4.72E+02
Sr CFS-LRef-1315-T06-E 1 7.65E+02
Sr CFS-LRef-1315-T07-E 1 7.81E+02
Sr CFS-LRef-1315-T08-E 1 3.57E+02
Sr CFS-LRef-1315-T09-E 1 6.53E+02
Sr CFS-LRef-1315-T01-F 1 3.20E+01
Sr CFS-LRef-1315-T02-F 1 1.28E+02
Sr CFS-LRef-1315-T03-F 1 1.37E+02
Sr CFS-LRef-1315-T04-F 1 3.99E+02
Sr CFS-LRef-1315-T05-F 1 4.76E+02
Sr CFS-LRef-1315-T06-F 1 7.72E+02
Sr CFS-LRef-1315-T07-F 1 7.64E+02
Sr CFS-LRef-1315-T08-F 1 3.58E+02
Sr CFS-LRef-1315-T09-F 1 6.61E+02
ICP-OES Spike Sol'n
fier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
3.62E+01 1.89 1.00 3.18
1.46E+02 0.40 1.00 3.18
1.47E+02 1.11 1.00 3.18 10000 1000
4.59E+02 1.68 1.00 3.18
4.99E+02 0.31 1.00 3.18
7.97E+02 0.97 1.00 3.18
8.18E+02 1.72 1.00 3.18
3.99E+02 9.75 1.00 3.18
7.39E+02 1.00 1.00 3.18
3.50E+01 2.98 1.00 3.18
1.74E+02 2.01 1.00 3.18
1.34E+02 1.37 1.00 3.18 10000 1000
4.02E+02 1.91 1.00 3.18
4.72E+02 0.95 1.00 3.18
7.65E+02 2.46 1.00 3.18
7.81E+02 2.02 1.00 3.18
3.57E+02 1.42 1.00 3.18
6.53E+02 2.49 1.00 3.18
3.20E+01 1.64 1.00 3.18
1.28E+02 2.96 1.00 3.18
1.37E+02 3.23 1.00 3.18 10000 1000
3.99E+02 1.32 1.00 3.18
4.76E+02 2.25 1.00 3.18
7.72E+02 1.71 1.00 3.18
7.64E+02 1.63 1.00 3.18
3.58E+02 1.67 1.00 3.18
6.61E+02 1.58 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.11E+03 97% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.07E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.12E+03 98% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:1 1 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/11 4:30 PM EPA Interlab LRef 1315 CFS
6/20/11 4:53 PM EPA Interlab LRef 1315 CFS
6/20/11 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/11 3:29 PM EPA Interlab LRef 1315 CFS
6/20/11 3:39 PM EPA Interlab LRef 1315 CFS
6/20/11 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/11 4:21 PM EPA Interlab LRef 1315 CFS
6/20/11 4:31 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:54 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-984
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 M9/L
S CFS-LRef-1315-T01-D 1 1.05E+04
S CFS-LRef-1315-T02-D 1 5.38E+04
S CFS-LRef-1315-T03-D 1 5.39E+04
S CFS-LRef-1315-T04-D 1 1.69E+05
S CFS-LRef-1315-T05-D 1 1.72E+05
S CFS-LRef-1315-T06-D 1 2.57E+05
S CFS-LRef-1315-T07-D 1 2.45E+05
S CFS-LRef-1315-T08-D 1 1.13E+05
S CFS-LRef-1315-T09-D 1 2.13E+05
S CFS-LRef-1315-T01-E 1 1.01E+04
S CFS-LRef-1315-T02-E 1 6.38E+04
S CFS-LRef-1315-T03-E 1 4.83E+04
S CFS-LRef-1315-T04-E 1 1.41E+05
S CFS-LRef-1315-T05-E 1 1.61E+05
S CFS-LRef-1315-T06-E 1 2.46E+05
S CFS-LRef-1315-T07-E 1 2.37E+05
S CFS-LRef-1315-T08-E 1 1.03E+05
S CFS-LRef-1315-T09-E 1 1.88E+05
S CFS-LRef-1315-T01-F 1 8.29E+03
S CFS-LRef-1315-T02-F 1 4.47E+04
S CFS-LRef-1315-T03-F 1 4.58E+04
S CFS-LRef-1315-T04-F 1 1.44E+05
S CFS-LRef-1315-T05-F 1 1.60E+05
S CFS-LRef-1315-T06-F 1 2.49E+05
S CFS-LRef-1315-T07-F 1 2.33E+05
S CFS-LRef-1315-T08-F 1 1.04E+05
S CFS-LRef-1315-T09-F 1 1.92E+05
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.05E+04 2.09 6.80 21.60
5.38E+04 0.36 6.80 21.60
5.39E+04 1.10 6.80 21.60 10000 1000
1.69E+05 1.41 6.80 21.60
1.72E+05 0.37 6.80 21.60
2.57E+05 0.57 6.80 21.60
2.45E+05 0.68 6.80 21.60
1.13E+05 10.57 6.80 21.60
2.13E+05 1.46 6.80 21.60
1.01E+04 1.78 6.80 21.60
6.38E+04 1.70 6.80 21.60
4.83E+04 1.92 6.80 21.60 10000 1000
1.41E+05 1.57 6.80 21.60
1.61E+05 1.03 6.80 21.60
2.46E+05 1.79 6.80 21.60
2.37E+05 1.40 6.80 21.60
1.03E+05 1.43 6.80 21.60
1.88E+05 2.55 6.80 21.60
8.29E+03 2.28 6.80 21.60
4.47E+04 2.37 6.80 21.60
4.58E+04 3.72 6.80 21.60 10000 1000
1.44E+05 1.54 6.80 21.60
1.60E+05 2.43 6.80 21.60
2.49E+05 0.83 6.80 21.60
2.33E+05 1.19 6.80 21.60
1.04E+05 0.94 6.80 21.60
1.92E+05 1.86 6.80 21.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
5.47E+04 84% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.92E+04 87% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
4.66E+04 82% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:1 1 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/11 4:30 PM EPA Interlab LRef 1315 CFS
6/20/11 4:53 PM EPA Interlab LRef 1315 CFS
6/20/11 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/11 3:29 PM EPA Interlab LRef 1315 CFS
6/20/11 3:39 PM EPA Interlab LRef 1315 CFS
6/20/11 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/11 4:21 PM EPA Interlab LRef 1315 CFS
6/20/11 4:31 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:54 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-985
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 1 Mg/L
Tl CFS-LRef-1315-T01-D 1 1.54E+01
Tl CFS-LRef-1315-T02-D 1 8.04E+01
Tl CFS-LRef-1315-T03-D 1 8.00E+01
Tl CFS-LRef-1315-T04-D 1 2.13E+02
Tl CFS-LRef-1315-T05-D 1 2.22E+02
Tl CFS-LRef-1315-T06-D 1 3.16E+02
Tl CFS-LRef-1315-T07-D 1 2.97E+02
Tl CFS-LRef-1315-T08-D 1 1.40E+02
Tl CFS-LRef-1315-T09-D 1 2.30E+02
Tl CFS-LRef-1315-T01-E 1 1.01E+01 E
Tl CFS-LRef-1315-T02-E 1 8.19E+01
Tl CFS-LRef-1315-T03-E 1 7.26E+01
Tl CFS-LRef-1315-T04-E 1 1.98E+02
Tl CFS-LRef-1315-T05-E 1 2.19E+02
Tl CFS-LRef-1315-T06-E 1 3.17E+02
Tl CFS-LRef-1315-T07-E 1 2.94E+02
Tl CFS-LRef-1315-T08-E 1 1.35E+02
Tl CFS-LRef-1315-T09-E 1 2.25E+02
Tl CFS-LRef-1315-T01-F 1 1.41E+01 E
Tl CFS-LRef-1315-T02-F 1 7.27E+01
Tl CFS-LRef-1315-T03-F 1 6.77E+01
Tl CFS-LRef-1315-T04-F 1 2.02E+02
Tl CFS-LRef-1315-T05-F 1 2.17E+02
Tl CFS-LRef-1315-T06-F 1 3.17E+02
Tl CFS-LRef-1315-T07-F 1 2.90E+02
Tl CFS-LRef-1315-T08-F 1 1.40E+02
Tl CFS-LRef-1315-T09-F 1 2.31E+02
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.54E+01 6.13 4.60 14.60
8.04E+01 3.32 4.60 14.60
8.00E+01 2.11 4.60 14.60 10000 1000
2.13E+02 1.06 4.60 14.60
2.22E+02 2.22 4.60 14.60
3.16E+02 1.04 4.60 14.60
2.97E+02 2.19 4.60 14.60
1.40E+02 6.69 4.60 14.60
2.30E+02 2.46 4.60 14.60
1.01E+01 8.81 4.60 14.60
8.19E+01 8.61 4.60 14.60
7.26E+01 7.09 4.60 14.60 10000 1000
1.98E+02 0.09 4.60 14.60
2.19E+02 4.20 4.60 14.60
3.17E+02 3.32 4.60 14.60
2.94E+02 2.49 4.60 14.60
1.35E+02 3.17 4.60 14.60
2.25E+02 4.19 4.60 14.60
1.41E+01 9.22 4.60 14.60
7.27E+01 6.47 4.60 14.60
6.77E+01 3.57 4.60 14.60 10000 1000
2.02E+02 1.45 4.60 14.60
2.17E+02 1.29 4.60 14.60
3.17E+02 1.94 4.60 14.60
2.90E+02 1.80 4.60 14.60
1.40E+02 3.47 4.60 14.60
2.31E+02 2.10 4.60 14.60
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.10E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1 . 1 0E+03 1 03% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.08E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:1 1 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:30 PM EPA Interlab LRef 1315 CFS
6/20/11 4:53 PM EPA Interlab LRef 1315 CFS
6/20/11 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/11 3:29 PM EPA Interlab LRef 1315 CFS
6/20/11 3:39 PM EPA Interlab LRef 1315 CFS
6/20/11 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/11 4:21 PM EPA Interlab LRef 1315 CFS
6/20/11 4:31 PM EPA Interlab LRef 1315 CFS
6/20/11 4:54 PM EPA Interlab LRef 1315 CFS
6/20/11 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-986
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualifier
1 1 ug/L
Ti CFS-LRef-1315-T01-D 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T02-D 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T03-D 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T04-D 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T05-D 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T06-D 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T07-D 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T08-D 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T09-D 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T01-E 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T02-E 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T03-E 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T04-E 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T05-E 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T06-E 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T07-E 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T08-E 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T09-E 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T01-F 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T02-F 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T03-F 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T04-F 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T05-F 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T06-F 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T07-F 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T08-F 1 1.00E+00 U1/2
Ti CFS-LRef-1315-T09-F 1 1.00E+00 U1/2
ICP-OES Spike Sol'n
Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
1.00E+00 31.59 2.00 6.40
1.00E+00 41.87 2.00 6.40
1.00E+00 70.65 2.00 6.40 10000 1000
1.00E+00 21.30 2.00 6.40
1.00E+00 54.28 2.00 6.40
1.00E+00 19.56 2.00 6.40
1.00E+00 31.23 2.00 6.40
1.00E+00 47.00 2.00 6.40
1.00E+00 64.03 2.00 6.40
1.00E+00 13.89 2.00 6.40
1.00E+00 46.90 2.00 6.40
1.00E+00 44.82 2.00 6.40 10000 1000
1.00E+00 29.11 2.00 6.40
1.00E+00 9.07 2.00 6.40
1.00E+00 30.68 2.00 6.40
1.00E+00 50.35 2.00 6.40
1.00E+00 69.98 2.00 6.40
1.00E+00 55.10 2.00 6.40
1.00E+00 71.39 2.00 6.40
1.00E+00 46.33 2.00 6.40
1.00E+00 59.44 2.00 6.40 10000 1000
1.00E+00 29.02 2.00 6.40
1.00E+00 55.63 2.00 6.40
1.00E+00 40.81 2.00 6.40
1.00E+00 40.57 2.00 6.40
1.00E+00 44.90 2.00 6.40
1.00E+00 38.39 2.00 6.40
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 102% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:1 1 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:53 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/11 3:29 PM EPA Interlab LRef 1315 CFS
6/20/11 3:39 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/11 4:21 PM EPA Interlab LRef 1315 CFS
6/20/11 4:31 PM EPA Interlab LRef 1315 CFS
6/20/11 4:54 PM EPA Interlab LRef 1315 CFS
6/20/11 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-987
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qualil
1 1 1 M9/L
V CFS-LRef-1315-T01-D 1 2.02E+00 E
V CFS-LRef-1315-T02-D 1 3.10E+00 E
V CFS-LRef-1315-T03-D 1 2.84E+00 E
V CFS-LRef-1315-T04-D 1 7.61E+00
V CFS-LRef-1315-T05-D 1 7.35E+00
V CFS-LRef-1315-T06-D 1 9.13E+00
V CFS-LRef-1315-T07-D 1 9.97E+00
V CFS-LRef-1315-T08-D 1 5.35E+00
V CFS-LRef-1315-T09-D 1 7.93E+00
V CFS-LRef-1315-T01-E 1 1.88E+00 E
V CFS-LRef-1315-T02-E 1 2.71E+00 E
V CFS-LRef-1315-T03-E 1 1.99E+00 E
V CFS-LRef-1315-T04-E 1 5.46E+00
V CFS-LRef-1315-T05-E 1 6.44E+00
V CFS-LRef-1315-T06-E 1 8.54E+00
V CFS-LRef-1315-T07-E 1 9.44E+00
V CFS-LRef-1315-T08-E 1 4.72E+00 E
V CFS-LRef-1315-T09-E 1 7.95E+00
V CFS-LRef-1315-T01-F 1 1.65E+00 E
V CFS-LRef-1315-T02-F 1 1.99E+00 E
V CFS-LRef-1315-T03-F 1 3.19E+00 E
V CFS-LRef-1315-T04-F 1 5.61E+00
V CFS-LRef-1315-T05-F 1 6.48E+00
V CFS-LRef-1315-T06-F 1 9.54E+00
V CFS-LRef-1315-T07-F 1 9.56E+00
V CFS-LRef-1315-T08-F 1 3.98E+00 E
V CFS-LRef-1315-T09-F 1 8.52E+00
ICP-OES Spike Sol'n
ier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
2.02E+00 25.98 1.50 4.77
3.10E+00 11.13 1.50 4.77
2.84E+00 12.41 1.50 4.77 10000 1000
7.61E+00 7.68 1.50 4.77
7.35E+00 7.49 1.50 4.77
9.13E+00 1.84 1.50 4.77
9.97E+00 6.22 1.50 4.77
5.35E+00 7.67 1.50 4.77
7.93E+00 1.36 1.50 4.77
1.88E+00 15.71 1.50 4.77
2.71E+00 15.04 1.50 4.77
1.99E+00 8.30 1.50 4.77 10000 1000
5.46E+00 4.60 1.50 4.77
6.44E+00 5.66 1.50 4.77
8.54E+00 9.36 1.50 4.77
9.44E+00 9.16 1.50 4.77
4.72E+00 9.92 1.50 4.77
7.95E+00 8.11 1.50 4.77
1.65E+00 18.49 1.50 4.77
1.99E+00 22.92 1.50 4.77
3.19E+00 20.85 1.50 4.77 10000 1000
5.61E+00 6.52 1.50 4.77
6.48E+00 2.39 1.50 4.77
9.54E+00 6.84 1.50 4.77
9.56E+00 1.49 1.50 4.77
3.98E+00 12.12 1.50 4.77
8.52E+00 7.85 1.50 4.77
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
1.01E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.00E+03 100% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
1.02E+03 101% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/11 5:11 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:30 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:53 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:29 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:39 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:21 PM EPA Interlab LRef 1315 CFS
6/20/11 4:31 PM EPA Interlab LRef 1315 CFS
6/20/11 4:54 PM EPA Interlab LRef 1315 CFS
6/20/11 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-988
-------
Intel-laboratory Validation of LEAF Method 1314 and Method 1315
Dilution Sample
Element Sample ID Factor Cone. Qua
1 ug/L
Zn CFS-LRef-1315-T01-D 1 4.56E+02
Zn CFS-LRef-1315-T02-D 1 1.98E+03
Zn CFS-LRef-1315-T03-D 1 2.04E+03
Zn CFS-LRef-1315-T04-D 1 6.06E+03
Zn CFS-LRef-1315-T05-D 1 6.14E+03
Zn CFS-LRef-1315-T06-D 1 8.96E+03
Zn CFS-LRef-1315-T07-D 1 8.44E+03
Zn CFS-LRef-1315-T08-D 1 4.10E+03
Zn CFS-LRef-1315-T09-D 1 7.56E+03
Zn CFS-LRef-1315-T01-E 1 4.21E+02
Zn CFS-LRef-1315-T02-E 1 2.31E+03
Zn CFS-LRef-1315-T03-E 1 1.84E+03
Zn CFS-LRef-1315-T04-E 1 5.29E+03
Zn CFS-LRef-1315-T05-E 1 6.04E+03
Zn CFS-LRef-1315-T06-E 1 8.77E+03
Zn CFS-LRef-1315-T07-E 1 8.58E+03
Zn CFS-LRef-1315-T08-E 1 3.91 E+03
Zn CFS-LRef-1315-T09-E 1 6.77E+03
Zn CFS-LRef-1315-T01-F 1 3.82E+02
Zn CFS-LRef-1315-T02-F 1 1.87E+03
Zn CFS-LRef-1315-T03-F 1 1.79E+03
Zn CFS-LRef-1315-T04-F 1 5.41 E+03
Zn CFS-LRef-1315-T05-F 1 5.88E+03
Zn CFS-LRef-1315-T06-F 1 9.05E+03
Zn CFS-LRef-1315-T07-F 1 8.55E+03
Zn CFS-LRef-1315-T08-F 1 3.90E+03
Zn CFS-LRef-1315-T09-F 1 7.00E+03
ICP-OES Spike Sol'n
ifier Cone. RSD MDL ML Cone. Volume
ug/L % ug/L ug/L ug/L uL
4.56E+02 1.35 1.00 3.18
1.98E+03 1.19 1.00 3.18
2.04E+03 1.53 1.00 3.18 10000 1000
6.06E+03 0.40 1.00 3.18
6.14E+03 1.01 1.00 3.18
8.96E+03 1.15 1.00 3.18
8.44E+03 1.67 1.00 3.18
4.10E+03 12.70 1.00 3.18
7.56E+03 3.94 1.00 3.18
4.21E+02 2.16 1.00 3.18
2.31E+03 2.17 1.00 3.18
1.84E+03 1.76 1.00 3.18 10000 1000
5.29E+03 1.27 1.00 3.18
6.04E+03 2.79 1.00 3.18
8.77E+03 2.92 1.00 3.18
8.58E+03 0.23 1.00 3.18
3.91E+03 1.70 1.00 3.18
6.77E+03 1.96 1.00 3.18
3.82E+02 2.33 1.00 3.18
1.87E+03 2.22 1.00 3.18
1.79E+03 3.08 1.00 3.18 10000 1000
5.41 E+03 1.48 1.00 3.18
5.88E+03 2.49 1.00 3.18
9.05E+03 2.38 1.00 3.18
8.55E+03 0.81 1.00 3.18
3.90E+03 0.50 1.00 3.18
7.00E+03 1.66 1.00 3.18
Spike Spike
Cone. Recovery Instrument
ug/L %
VU ICP-OES
VU ICP-OES
2.93E+03 89% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.77E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
2.72E+03 93% VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
VU ICP-OES
Date/Time Filename
6/20/1 1 3:25 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:35 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:45 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:08 PM EPA Interlab LRef 1315 CFS
6/20/11 4:18 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:28 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:51 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:01 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:1 1 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:27 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:37 PM EPA Interlab LRef 1315 CFS
6/20/1 1 3:47 PM EPA Interlab LRef 1315 CFS
6/20/11 4:10 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:20 PM EPA Interlab LRef 1315 CFS
6/20/11 4:30 PM EPA Interlab LRef 1315 CFS
6/20/11 4:53 PM EPA Interlab LRef 1315 CFS
6/20/11 5:03 PM EPA Interlab LRef 1315 CFS
6/20/11 5:13 PM EPA Interlab LRef 1315 CFS
6/20/11 3:29 PM EPA Interlab LRef 1315 CFS
6/20/11 3:39 PM EPA Interlab LRef 1315 CFS
6/20/11 3:48 PM EPA Interlab LRef 1315 CFS
6/20/11 4:12 PM EPA Interlab LRef 1315 CFS
6/20/11 4:21 PM EPA Interlab LRef 1315 CFS
6/20/11 4:31 PM EPA Interlab LRef 1315 CFS
6/20/1 1 4:54 PM EPA Interlab LRef 1315 CFS
6/20/1 1 5:04 PM EPA Interlab LRef 1315 CFS
6/20/11 5:14 PM EPA Interlab LRef 1315 CFS
1-989
------- |