SEPA United States Environmental Protection Agency Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Office of Water (4608T) EPA 817-B-12-002 September 2012 http://www.epa.gov/watersecurity ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Office of Water (4608T) EPA817-B-12-002 September 2012 http://www.epa.gov/watersecurity ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Disclaimer The Containment and Disposal of Large Amounts of Water: A Support Guide for Water Utilities is designed to provide recommendations that may be useful in preparing for contamination threats and events. While it may serve as a reference document for preparation and response to an actual contamination event when rapid decision mak- ing is needed, this guide does not address all facets of the decontamination phase of a response. It consists of broad recommendations that may be adaptable to a specific situation or incident. Use of this guide is voluntary. This guide is not a rule; it is not le- gally enforceable; and it does not confer legal rights or impose legal obligations upon any member of the public, water utilities, the U.S. Environmental Protection Agency (EPA), state and local governments, tribes, or any other agency. It includes references to statutes and regulations, but it does not change or substitute for any legal require- ments. While EPA has made every effort to ensure the accuracy of the discussion in this guide, the obligations of the regulated community are determined by the relevant statutes, regulations, or other legally binding requirements. In the event of a conflict between the discussion in this document and any statute or regulation, this document would not be controlling. The word "should" as used in this guide does not connote a requirement, but may indicate EPA's strongly preferred approach to ensure effective implementation of legal requirements. MI ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities This page has been left blank intentionally IV ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities List of Acronyms ACP Area Contingency Plan ADAMS Agency-wide Documents Access and Management System AEA Atomic Energy Act ALARA As Low as Reasonably Achievable ATSDR Agency for Toxic Substances and Disease Registry BSL Biosafety Level CBR Chemical, Biological, and Radiological CDC Centers for Disease Control CERCLA Comprehensive Environmental Response, Compensation, and Liability Act CFR Code of Federal Regulations CID EPA Criminal Investigation Division CRS Congressional Research Service CSO Combined Sewer Overflow CWA Clean Water Act CWT Centralized Waste Treatment DBP Disinfection Byproduct DDT Dichlorodiphenyltrichloroethane DHS U.S. Department of Homeland Security DOD U.S. Department of Defense DOE U.S. Department of Energy DOT U.S. Department of Transportation EDR Electrodialysis Reversal EMS Emergency Management Service EPA U.S. Environmental Protection Agency ERLN Environmental Response Laboratory Network ERP Emergency Response Plan FBI Federal Bureau of Investigation FEMA Federal Emergency Management Agency FIFRA Federal Insecticide, Fungicide, and Rodenticide Act FMCSA Federal Motor Carrier Safety Administration FOTW Federally Owned Treatment Works FR Federal Register GAC Granular Activated Charcoal HAA Haloacetic Acid ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities HASP Health and Safety Plan HAZMAT Hazardous Materials HLRW High-level Radioactive Waste HMR Hazardous Materials Regulation 1C Incident Commander ICS Incident Command System ID Identifier IND Improvised Nuclear Device JTTF Joint Terrorism Task Force LDR Land Disposal Restrictions LLMW Low-Level Mixed Waste LLRW Low-Level Radioactive Waste LLRWDF Low-Level Radioactive Waste Disposal Facility LQG Large Quantity Generators MARPOL Marine Pollution; more specifically, the designation for the International Convention for the Prevention of Pollution from Ships MCL Maximum Contaminant Level NCP National Oil and Hazardous Substances Pollution Contingency Plan NHMRR National HAZMAT (Hazardous Materials) Route Registry NPDES National Pollutant Discharge Elimination System NRC Nuclear Regulatory Commission NRT National Response Team OPA Oil Pollution Act OSC On-Scene Coordinator OSHA Occupational Safety and Health Administration PCB Polychlorinated Biphenyl PHMSA Pipeline and Hazardous Materials Safety Administration POTW Publicly Owned Treatment Works RAP Remediation Action Plan RCP Regional Contingency Plan RCRA Resource Conservation and Recovery Act ROD Radiological Dispersal Device RPTB Response Protocol Toolbox SAFESTAT Motor Carrier Safety Status Measurement System SAM Standardized Analytical Methods for Environmental Restoration following Homeland Security Events SDWA Safe Drinking Water Act VI ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities SEB Staphylococcal Enterotoxin B THM Trihalomethane IRAQIS Transportation Routing Analysis Geographic Information System TSCA Toxic Substances Control Act DIG Underground Injection Control USAGE U.S. Army Corps of Engineers USAPHC U.S. Army Public Health Command USC United States Code USCG U.S. Coast Guard USDW Underground Source of Drinking Water UST Underground Storage Tank UV Ultraviolet WCIT Water Contaminant Information Tool WLA Water Laboratory Alliance WSi CMP Water Security Initiative Interim Guidance on Developing Consequence Management Plans for Drinking Water Utilities WWTP Wastewater Treatment Plant VII ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Glossary The following terms are defined for purposes of this guidance document: Agency - A division of government with a specific function, or a non-governmental organization (e.g., private contractor, business, etc.) that offers a particular kind of assistance. In the incident command system (ICS), agencies are defined as jurisdictional (having a statutory role in incident mitigation) or assisting and/or coop- erating (providing resources and/or assistance). Agreement State - Any State with which the Nuclear Regulatory Commission or the Atomic Energy Com- mission has entered into an effective agreement under subsection 274b of the Atomic Energy Act of 1954, as amended in 68 Stat. 919 (Per 40 CFR 191.02(f)). All Hazards - An incident, natural or manmade, that warrants action to protect life, property, environment, and public health or safety, and to minimize disruptions of government, social, or economic activities. (From U.S. Department of Homeland Security, National Response Framework, FEMA Publication P-692, 2008) As Low as Reasonably Achievable (ALARA) - Making every reasonable effort to maintain exposures to radiation as far below the dose limits in this part as is practical consistent with the purpose for which the li- censed activity is undertaken, taking into account the state of technology, the economics of improvements in relation to the state of technology, the economics of improvements in relation to benefits to public health and safety, and other societal and socioeconomic considerations, and in relation to utilization of nuclear energy and licensed materials in the public interest (Per 10 CFR 20.1003). Before the Drinking Water Distribution System - Water is considered to be located before the drinking wa- ter distribution system after it has been withdrawn from the source water (e.g., surface water or ground water) and before it is released to the pipes in the drinking water distribution system. Therefore, for the purposes of this guide, this does not include source water, but does include water located within a drinking water treat- ment plant or reservoir that has not entered the distribution system. Biosafety Level - The level of precaution that must be taken to minimize the exposure of workers and the environment to infectious agents. The greater the threat of infection a contaminant poses, the greater the bio- safety level. (From Centers for Disease Control and Prevention, Biosafety in Microbiological and Biomedical Laboratories, 5th ed., HHS Publication (CDC) 21-1112, 2009) Brine - Treatment residual highly saturated with salt. Cancelled Pesticide - A pesticide for which the registration (i.e., license) has been cancelled through one of the following actions: Voluntary cancellation by the registrant Cancellation by EPA because required fees were not paid Cancellation by EPA because unacceptable risk existed that could not be reduced by other actions such as amendment to terminate one or more uses or amendment to change the terms and conditions of registration and labeling For more information, see 7 U.S.C. 136d Section 6(b) and EPA's Web page on regulating pesticides: http:// www.epa.gov/pesticides/regulating/restricted. htm#canceled. Catch Basins - Chambers or sumps, usually built at the curb line, which allow surface water runoff to enter the stormwater conveyance system. Centralized Waste Treatment (CWT) Facility - Any facility that treats (for disposal, recycling, or recovery of material) any hazardous or non-hazardous industrial wastes, hazardous or non-hazardous industrial waste- water, and/or used material received from off site. "CWT facility" includes both a facility that treats waste received exclusively from off site and a facility that treats wastes generated on site as well as waste received from off site. For example, an organic chemical manufacturing plant may, in certain circumstances, be a CWT VIM ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities facility if it treats industrial wastes received from off site as well as industrial waste generated at the organic chemical manufacturing plant. CWT facilities may also include re-refiners and may be owned by the federal government (Per 40 CFR 437.2). Code of Federal Regulations (CFR) - The CFR is the codification of the federal regulations published in the Federal Register by the executive departments and agencies of the federal government. Each volume of the CFR is updated once each calendar year and is issued on a quarterly basis. See http://www.gpoaccess.gov/ cfr/index.html. Combined Sewer System - Sewer system that is designed to collect stormwater runoff, domestic sewage, and commercial and industrial wastewater in a single pipe and transport it to a treatment plant, where it is treated and then discharged to a water body. Combined sewer systems generally include some combined sewer overflow (CSO) discharge points prior to reaching the treatment plant. For more information, see EPA's National Pollutant Discharge Elimination System (NPDES) Web page on combined sewer overflows: http:// cfpub.epa.gov/npdes/home.cfm?program_id=5. Containment - The temporary storing of water to prevent further contamination or harm to human health and the environment. Contaminated Water-Water contaminated with a biological, chemical, or radiological contaminant. Decontamination - The inactivation or reduction of contaminants from surfaces by physical, chemical or other methods to meet a cleanup goal. Decontamination does not include treatment of contaminated water or wastewater. Drinking Water Distribution System - System consisting of pipes, pumps, control valves and storage facili- ties designed to provide water for human consumption (e.g., to homes, businesses, hospitals, government facilities, etc.). For the purposes of this guide, this does not include the end point of the water (e.g., the home, business, etc.). Drinking Water Primacy Agency - The agency that has primary responsibility for administration and en- forcement of primary drinking water regulations and related requirements applicable to public water systems within a state (Per 40 CFR Part 142). Drinking water primacy for a particular state or tribe may reside in one of a variety of agencies, such as health departments, environmental quality departments, etc., or in the appli- cable EPA region. The drinking water primacy agency may also play the role of technical assistance provider to drinking water utilities. Drinking Water System-A utility, its components, personnel, and assets that are involved in providing drink- ing water to its customers. Emergency - Any incident, whether natural or manmade, that requires responsive action within hours to pro- tect life or property. As defined in the Stafford Act, any occasion or instance for which, in the determination of the President, federal assistance is needed to supplement state and local efforts and capabilities to save lives and to protect property and public health and safety, or to lessen or avert the threat of a catastrophe in any part of the United States (Per 42 U.S.C. 5122). Emergency Response Plan - A document that describes the actions that a drinking water or wastewater utility might take in response to various emergencies, disasters, and other unexpected incidents. (From EPA Emergency Response Plan Guidance for Small and Medium Community Water Systems to Comply with the Public Health Security and Bioterrorism Preparedness and Response Act of 2002, EPA 816-R-04-002, 2004) Federal Register (FR) - The Federal Register is the official daily publication for rules, proposed rules, and notices of federal agencies and organizations, as well as executive orders and other presidential documents. See http://www.gpo.gov/fdsys/browse/collection.action?collectionCode=FR. Force Main - Pipeline that conveys wastewater under pressure from the discharge side of a pump or pneu- matic ejector to a discharge point. Pumps or compressors located in a lift station provide the energy for wastewater conveyance in force mains. IX ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Hazardous Substance - Consistent with the definitions in the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) and the National Contingency Plan (see 40 CFR 300.5), this term generally includes (but is not limited to): Any of more than 400 hazardous substances designated under section 311 (b)(2)(A) of the Clean Wa- ter Act (CWA) or toxic pollutants listed under section 307(a) of the CWA Any substance designated pursuant to section 102 of CERCLA Any hazardous waste having the characteristics identified or listed under section 3001 of the Resource Conservation and Recovery Act (RCRA) Any of more than 200 hazardous air pollutants listed under section 112 of the Clean Air Act (CAA), as amended Any imminently hazardous chemical substance or mixture about which the EPA Administrator has "taken action pursuant to" section 7 of the Toxic Substances Control Act (TSCA) The term does not include petroleum, including crude oil or any fraction thereof that is not otherwise listed or designated above. The term does not include natural gas, natural gas liquids, liquefied natural gas, or synthetic gas usable for fuel (or mixtures of natural gas and such synthetic gas). High-Level Radioactive Waste (HLRW) - The highly radioactive materials produced as byproducts of fuel reprocessing or of the reactions that occur inside nuclear reactors. HLRW includes: (1) irradiated reactor fuel; (2) liquid wastes resulting from the operation of the first cycle solvent extraction system, or equivalent, and the concentrated wastes from subsequent extraction cycles, or equivalent, in a facility for reprocessing irradiated reactor fuel; and, (3) solids into which such liquid wastes have been converted (Per 10 CFR 60.2). Containment and disposal of this type of radioactive waste is not covered in this guide. Hydrophobic - Having a strong aversion for water. In Situ - In place. Incident Command System (ICS) - A standardized on-scene emergency management construct specifi- cally designed to provide for the adoption of an integrated organizational structure that reflects the complex- ity and demands of single or multiple incidents, without being hindered by jurisdictional boundaries. ICS is a management system designed to enable effective incident management by integrating a combination of facilities, equipment, personnel, procedures, and communications operating within a common organizational structure, designed to aid in the management of resources during incidents. It is used for all kinds of emergen- cies and is applicable to small as well as large and complex incidents. ICS is used by various jurisdictions and functional agencies, both public and private, to organize field-level incident management operations. (From U.S. Department of Homeland Security, National Response Framework, 2008, FEMA Publication P-692.) Individual Control Mechanism - Individual permit, order, or similar control mechanism. For example, this phrase is used in EPA's General Pretreatment regulations at 40 CFR 403.8(f)(1)(iii). Initial Response - Actions taken immediately following notification of a contamination incident or release. In addition to search and rescue, scene control, and law enforcement activities, initial response may include initial site containment, environmental sampling and analysis, and public health activities, such as treatment of potentially exposed persons. Injection Well - A "well" into which "fluids" are being injected. A well is defined as a bored, drilled, or driven shaft whose depth is greater than the largest surface dimension; or, a dug hole whose depth is greater than the largest surface dimension; or, an improved sinkhole; or, a subsurface fluid distribution system (Per 40 CFR 144.3.) For more information see http://water.epa.gov/type/groundwater/uic/basicinformation.cfm. Large Quantity Generators (LOG) - A facility that generates 1,000 kilograms per month or more of hazard- ous waste, more than 1 kilogram per month of acutely hazardous waste, or more than 100 kilograms per month of any residue, contaminated soil, waste or other debris from the cleanup of spills of acute hazardous waste (Per 40 CFR 261.5(e)(2) and 40 CFR 262). For more information on LQG, see http://www.epa.gov/osw/ hazard/generation/lqg.htm. ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Lift Station -A tank or chamber accompanied by a pump and related controls used to retain and periodically discharge effluent. Lined Evaporation Pond - Man-made pond having a large surface area for maximum exposure (e.g., expo- sure to sunlight or atmosphere). Local Limits - Limitations and requirements that an industrial user must meet before discharging into a publicly owned treatment works (POTW). Developed in accordance with 40 CFR 403.5(c), local limits are Pretreatment Standards for the purpose of CWA section 307(d) [per 40 CFR 403.5(d)]. Each POTW pretreat- ment program must develop, implement, and enforce technically based local limits. (From EPA Local Limits Development Guidance, EPA-833-R-0-4002A, July 2004) Low Level Mixed Waste (LLMW) - Material containing low-level radioactive waste and hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA). Low Level Radioactive Waste (LLRW) - Radioactive waste not classified as high-level radioactive waste, transuranic waste, spent nuclear fuel, or byproduct material as defined in section 11e (2), (3) or (4) of the definition of byproduct material set forth in 10 CFR 20.1003 (Per 10 CFR 61.2). LLRW may contain either high or low concentrations of radioactivity. Low Level Radioactive Waste Disposal Facility (LLRWDF) - Commercially operated sites licensed by the NRC or an Agreement State to dispose of solid LLRW. Maximum Contaminant Level (MCL) - The maximum permissible level of a contaminant in water which is delivered to any user of a public water system (Per 40 CFR 141.2). Under CERCLA, ground waters and surface waters that are current or potential drinking water sources are generally expected to be returned to beneficial reuse, which includes achieving MCLs. Mixed Waste - RCRA section 1004(41) defines mixed waste as waste that contains both hazardous waste and source, special nuclear, or by-product material subject to the Atomic Energy Act of 1954. National Oil and Hazardous Substances Pollution Contingency Plan (NCP) - Also called the National Contingency Plan, the NCP (40 CFR part 300) generally provides a blueprint for carrying out response ac- tions under CERCLA and section 311 of the CWA. The NCP is designed to provide for efficient, coordinated, and effective response to discharges of oil and releases of hazardous substances, pollutants, and contami- nants. The NCP describes the organizational structure and procedures for preparing for and responding to discharges of oil and releases of hazardous substances, pollutants, and contaminants. National Pollutant Discharge Elimination System (NPDES) -The national program for issuing, modifying, revoking and reissuing, terminating, monitoring and enforcing permits, and imposing and enforcing pretreat- ment requirements, under sections 307, 402, 318, and 405 of CWA (Per 40 CFR 122.2). This permit program controls water pollution by regulating point sources that discharge pollutants into waters of the United States. Oil - Consistent with the definition published in the NCP at 40 CFR 300.5, this term includes: Oil as defined by section 311 (a)(1) of the CWA, which means oil of any kind or in any form, including, but not limited to, petroleum, fuel oil, sludge, oil refuse, and oil mixed with wastes other than dredged spoil. Oil as defined by section 1001 of the Oil Pollution Act (OPA), which means oil of any kind or in any form, including, but not limited to, petroleum, fuel oil, sludge, oil refuse, and oil mixed with wastes other than dredged spoil, but does not include petroleum, including crude oil or any fraction thereof, which is specifically listed or designated as a hazardous substance under subparagraphs (A) through (F) of section 101(14) of CERCLA (42 U.S.C. 9601) and which is subject to the provisions of that Act. On-Scene Coordinator (OSC) - The federal official predesignated by EPA or the U.S. Coast Guard to co- ordinate and direct responses under subpart D, or the government official designated by the lead agency to coordinate and direct removal actions under subpart E of the NCP (Per 40 CFR 300.5). The specific duties of the OSC are provided in 40 CFR 300.120. XI ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Paint Filter Liquids Test - This method is used to determine the presence of free liquids in a representative sample of waste and compliance with 40 CFR 264.314 and 40 CFR 265.314 (disposal of bulk and container- ized liquids at hazardous waste landfills). See Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, Method 9095B, EPA Publication SW-846, November 2004, for more information. Potable Water - Water of sufficiently high quality that it can be consumed or used without risk of immediate or long-term harm. Public Health -The practice of preventing disease and promoting good health within groups of people, from small communities to entire countries. Public Water System - A system for the provision to the public of water for human consumption through pipes or, after August 5, 1998, other constructed conveyances, if such system has at least 15 service con- nections or regularly serves an average of at least 25 individuals daily at least 60 days out of the year. Such term includes: any collection, treatment, storage, and distribution facilities under control of the operator of such system and used primarily in connection with such system; and any collection or pretreatment storage facilities not under such control which are used primarily in connection with such system. Such term does not include any "special irrigation district." A public water system is either a "community water system" or a "noncommunity water system" (Per 40 CFR 141.2). Publicly Owned Treatment Works (POTW) - A treatment works as defined by section 212 of the CWA which is owned by a state or municipality (as defined by section 502(4) of the CWA). This definition includes any devices and systems used in the storage, treatment, recycling, and reclamation of municipal sewage or industrial wastes of a liquid nature. It also includes sewers, pipes and other conveyances only if they convey wastewater to a POTW plant. The term also means the municipality as defined in section 502(4) of the CWA, which has jurisdiction over the indirect discharges to and the discharges from such a treatment works (Per 40CFR403.3(q)). Publicly Owned Treatment Works (POTW) Pretreatment Program or Approved Pretreatment Program - A program administered by a POTW that meets the criteria established in 40 CFR 403.8 and 403.9 and that has been approved by a Regional Administrator or State Director in accordance with 40 CFR 403.11 (Per 40 CFR 403.3(d)). The program may include requirements for the reduction of the amount of contaminants, the elimination of contaminants, or the alteration of the nature of contaminant properties in wastewater prior to release into a POTW. Pump Station - Facility that consists of pumps and service equipment designed to pump flows from lower to higher elevations to allow continuous and cost-effective treatment. Radiological Dispersal Device (ROD) - Any device that causes the purposeful dissemination of radioactive material, across an area with the intent to cause harm, without a nuclear detonation occurring. Raw Water - Untreated water. Raw Water Main - Transmission, arterial, or distribution water main, but not a service line that transports raw water from source to the treatment plant. Receiving Body - The body of water into which water and/or effluent is discharged from wastewater sys- tems, stormwater systems, and other point-source dischargers. Remediation - Remediation includes the processes of characterizing, decontaminating, and clearing a con- taminated site or items, including disposal of wastes. It is a synonym for cleanup. (From U.S. DHS/EPA, Draft Planning Guidance for Recovery Following Biological Incidents, May 2009) Reservoir - Any natural or artificial holding area used to store, regulate, or control water. Residual - Byproducts from the treatment of contaminated water, including water, water-soluble materials, and solids. Resource Conservation and Recovery Act (RCRA) Hazardous Waste - RCRA section 1004(5) defines a waste as hazardous if it is a solid waste that may cause an increase in mortality or serious illness or pose a XII ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities substantial present or potential hazard to human health or the environment when improperly treated, stored, transported, disposed or otherwise managed. See Solid Waste (below) for the statutory and regulatory defini- tion of a RCRA solid waste. RCRA hazardous wastes can be liquids, solids, gases, or sludges. The regulatory definition of hazardous waste is found in 40 CFR Part 261. A waste may be considered hazardous if it exhibits certain hazardous properties (characteristics) in 40 CFR 261.21 to 261.24 or if it is listed as hazardous waste in 40 CFR 261.31 to 261.33, Subpart D-Lists of Hazardous Wastes). They can be discarded commercial products, such as cleaning fluids or pesticides, or the byproducts of manufacturing processes. See RCRA 1004(5) and 40 CFR 261.3 for the complete definitions, and http://www.epa.gov/osw/hazard/index.htm for more information. Response - Includes immediate actions to save lives, protect property and the environment, and meet basic human needs. Response also includes the execution of emergency plans and actions to support short-term recovery. (From U.S. Department of Homeland Security, National Response Framework, FEMA Publication P-692, 2008) Service Reservoir - A water storage container that holds clean water after it has been treated in a water plant, and before it is piped to the end users. Solid - State of matter characterized by particles arranged such that their shape and volume are relatively stable. The constituents of a solid tend to be packed together much closer than the particles in a gas or liquid. Solid Waste - RCRA section 1004(27) defines a solid waste as any garbage, refuse or sludge from waste treatment, water supply treatment and air pollution control and other discarded materials from industrial, commercial, mining and agricultural operations and from community activities. The statutory definition also includes several exclusions. The RCRA regulatory definition of solid waste is any discarded material that is abandoned, recycled, inherently waste-like, or a military munition, subject to certain exclusions. See 40 CFR 261.2 for the complete definition and http://www.epa.gov/waste/hazard/dsw/index.htm. Soluble - Susceptible of being dissolved in or as if in a liquid, especially water. Source Water - Water in its natural state, prior to any treatment for drinking. Stabilization/Solidification - Waste stabilization means any physical or chemical process used to either reduce the mobility of hazardous constituents in a hazardous waste or eliminate free liquids as determined by Test Method 9095B (Paint Filter Liquids Test) in Test Methods for Evaluating Solid Waste, Physical/Chemi- cal Methods, EPA Publication SW-846, as incorporated by reference in 40 CFR 260.11. A waste stabilization process includes mixing the hazardous waste with binders or other materials, and curing the resulting haz- ardous waste and binder mixture. Other synonymous terms used to refer to this process are "waste fixation" or "waste solidification." This does not include the adding of absorbent materials to the surface of a waste, without mixing, agitation, or subsequent curing, to absorb free liquid (Per 40 CFR 265.1081). Storage - Long term containment of water. Stormwater System or Separate Storm Sewer System - A conveyance or system of conveyances (includ- ing roads with drainage systems and municipal streets) that is designed or used for collecting or conveying stormwater for discharge to waters of the United States. Surface Water - Water that is open to the atmosphere and subject to surface runoff, such as rivers and lakes. Suspended Pesticide - A pesticide for which the registration (i.e., license) has been suspended for one of the following reasons: If a registrant does not take appropriate steps to address an Agency-imposed requirement for the generation and submission of data that are necessary to support continued registration of a pesticide product or does not submit timely and acceptable data in response to such requirement If necessary to prevent an imminent hazard during the time required for cancellation or change of clas- sification proceedings For more information, see 7 U.S.C. 136d Section 6(c) and EPA's Web page on suspended pesticides at: http://www.epa.gov/opp00001/regulating/registering/. XIII ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Temporary Storage - Short-term containment of water in a storage area or container specifically designed to hold water (e.g., holding ponds and holding tanks). Transuranic Waste - Waste containing more than 100 nanocuries of alpha-emitting transuranic isotopes, with half-lives greater than twenty years, per gram of waste, except for: (1) High-level radioactive wastes; (2) wastes that the Department of Energy has determined, with the concurrence of the EPA Administrator, do not need the degree of isolation required by this part; or (3) wastes that the Nuclear Regulatory Commission (NRC) has approved for disposal on a case-by-case basis in accordance with 10 CFR Part 61 (Per 40 CFR 191.02(i)). Transuranic elements are artificially made radioactive elements, such as neptunium, plutonium, americium, and others that have atomic numbers higher than uranium in the periodic table of elements. Transuranic waste is primarily produced from recycling spent nuclear fuel or using plutonium to fabricate nuclear weapons. Treatment - The removal of contaminants from water or wastewater. Treatment is not the same as "decon- tamination." (See separate definition for this term.) Underground Source of Drinking Water -An aquifer or its portion: (a)(1) Which supplies any public water system; or (2) Which contains a sufficient quantity of ground water to supply a public water system; and (i) Currently supplies drinking water for human consumption; or (ii) Contains fewer than 10,000 mg/l total dis- solved solids; and (b) Which is not an exempted aquifer. Volume Reduction - A process used to decrease the quantity or amount of space the contaminated water occupies. Wastewater System - A utility, its components, personnel, and assets that are involved in the handling, col- lecting, and treating of wastewater. Wastewater Treatment Plant - A treatment system that may consist of physical, biological, chemical, and mechanical processes for the purpose of removing and/or reducing contaminants in the wastewater. Generic term that includes publicly owned treatment works (POTW), federally owned treatment works (FOTW), cen- tralized waste treatment (CWT) facilities, and other wastewater treatment plants. Water Contaminant - Any physical, chemical, biological, or radiological substance or matter in water (Per section 1401 (6) of the Safe Drinking Water Act (SDWA) and 40 CFR 141.2). For the purposes of this guide, this definition will be used for drinking water and wastewater. Water Profile - The characteristics of the water including but not limited to contaminant levels, temperature, pH, and turbidity. Water System - The water supply source, treatment plant infrastructure and processes, and the water dis- tribution system. Within the Drinking Water Distribution System -Water located within the pipe, pumps, control valves, and storage facilities of the distribution system which are designed to provide water for human consumption to homes, businesses, hospitals, government facilities, etc. This does not include water at the end point of the system (e.g., the home, business, etc.). XIV ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Table of Contents LIST OF ACRONYMS v GLOSSARY viii 1.0 INTRODUCTION 1 2.0 CONTAINMENT AND DISPOSAL AS PART OF REMEDIATION AND RECOVERY 5 2.1 Actions Prior to Containment 5 2.2 EPA Water Sector Response and Recovery Guidance 5 2.3 Statutes and Regulations 6 2.4 Potential Partners 7 3.0 CONTAINMENT AND TREATMENT OF WATER 9 3.1 Containment of Water In Situ 9 3.2 Containment of Water in Temporary Storage 12 3.3 Treatment of Water 14 4.0 DISPOSAL OF WATER 19 4.1 Direct Discharge of Water to Surface Water 25 4.2 Disposal of Water through a Wastewater Treatment Plant (WWTP) 26 4.3 Transfer of Water to a Hazardous or Medical/Infectious Waste Facility 30 4.4 Underground Injection of Water 30 4.5 Volume Reduction and Solidification of Water with Radiological Contaminants 31 5.0 STORAGE AND TRANSPORTATION 32 5.1 Storage of Water 32 5.2 Transportation of Water 33 APPENDIX A: RISK COMMUNICATION A-1 APPENDIX B: POTENTIAL TREATMENT METHODS B-1 APPENDIX C: SAMPLE DISPOSAL CHECKLIST C-1 APPENDIX D: RESOURCES D-1 APPENDIX E: SUMMARY OF APPLICABLE LAWS AND REGULATIONS E-1 APPENDIX F: REFERENCES.. .. F-1 XV ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities LIST OF TABLES Table 1-1: Classes of Contaminants Addressed in Guide 3 Table 2-1: Potentially Applicable Federal Statutes and Regulations for Containment, Treatment, and Disposal 7 Table 3-1: Potential Additional Considerations Related to Containment In Situ 12 Table 3-2: Additional Contaminant Specific Considerations for Temporary Storage 13 Table 3-3: Potential Treatment Methods for Water Contaminated with Chemicals 15 Table 3-4: Potential Treatment Methods for Water Contaminated with Biologicals 16 Table 3-5: Recommended Treatment Methods for Biotoxin Contaminated Water 17 Table 3-6: Potential Treatment Methods for Water Contaminated with Radiologicals 17 Table 4-1: Characteristics of Treated Water and Potential Disposal Requirements 20 Table 4-2: Information on Disposal by Direct Discharge to Surface Water (Chemical, Biological, Toxin, and Radiological) 25 Table 4-3: Some Key Additional Requirements and Considerations for WWTPs 27 Table 4-4: Information on Disposal by Transfer or Discharge to a WWTP 29 Table B-1: Description of Potential Treatment Methods for CBR Contaminants B-2 Table B-2: Potential Hydrolysis Products from Chemical Contaminants B-7 Table B-3: Potential Treatment Byproducts and Treatment Process Residuals B-8 Table D-1: General Resources D-1 Table D-2: Disposal Resources D-6 Table D-3: Storage Resources D-7 Table D-4: Transport Resources D-8 Table D-5: Information on Disposal of Solids D-9 Table E-1: Classes and Considerations for Underground Injection/Well Disposal E-6 Table E-2: Summary of Storage, Treatment, Transportation, and Disposal of Mixed Wastes, Final Rule, May 2001 E-8 LIST OF FIGURES Figure 1-1: Overview of Potential Options for Containment, Treatment, and Disposal of Large Amounts of Water from Drinking Water, Wastewater, and/or Stormwater Systems... 4 Figure 3-1: Recommended Decision-Making Framework for Containment and Treatment of Contaminated Water for Drinking Water Systems 10 Figure 3-2: Recommended Decision-Making Framework for Containment and Treatment of Contaminated Water for Wastewater and Stormwater Systems 11 Figure 4-1: Recommended Decision Tree for Evaluating Disposal of Treated Water for Drinking Water Systems 23 Figure 4-2: Recommended Decision Tree for Evaluating Disposal of Treated Water for Wastewater and Stormwater Systems 24 Figure A-1: Recommended Framework for Developing a Risk Communication Strategy for a Drinking Water Utility Following a Contamination Incident A-3 XVI ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities 1.0 Introduction In the event that a drinking water, wastewater, or stormwater system is contaminated with a chemical, biological (including toxins), or radiological (CBR) contaminant, the system may need to contain, treat, and/or dispose of large volumes of water as a part of the decontamination efforts to return to service. This guide is intended for events involving emergency response activities at water utilities. In these types of events, an Incident Command System (ICS) may be established to manage the response, including decontamination activities.1 This guide provides a summary of key information that may be useful in addressing containment, treatment, and disposal of water contaminated with a CBR agent within any part of a drinking water, wastewater, and/or stormwater sys- tem resulting from an "all hazards" contamination event.23 Who May Find this Guide Useful? The information and recommendations in this guide were developed primarily for drinking water, wastewater, and stormwater utility per- sonnel involved in response activities. Decision makers involved with emergency response planning, such as emergency management agencies, environmental agencies, public health agencies, law en- forcement, as well as other federal, state, local, and tribal agencies, may also find the information and recommendations in this guide useful as a reference source. What is the Scope of this Guide? This guide provides the following for water within drinking water, waste- water, and/or stormwater systems: An overview of the issues associated with containment, treatment, and disposal of water contaminated with CBR agents after a deci- sion to contain the water has been made, including: - Potential types of containment - Potential treatment methods - Potential disposal options and associated considerations - Information on some of the key relevant statutes and regulations that may be applicable for containment and disposal Recommended decision-making frameworks for containment, treat- ment, and disposal of water contaminated with CBR agents This guide is not intended to provide recommendations on: Initial response activities immediately following a confirmed contami- nation incident4 Source water, such as ground water or surface water that has not entered the drinking water, wastewater, or stormwater system Potential Locations of Large Amounts of Contaminated Water at the Utility Drinking Water System Raw water pipe (intake to treatment plant) Drinking water treatment plant Transmission mains Service reservoir Drinking water distribution network Pump stations Storage tanks Wastewater System Collection system Wastewater treatment plant Effluent pipes Lift stations Treatment lagoons Stormwater System Catch basins Collection system Force mains 1 For more information on the ICS and how ICS applies to water facilities, see http://water.epa.gov/infrastructure/watersecurity/emerplan/ index.cfm#pp5. 2 Potential treatment options are included in this guide because disposal options may be affected by the type of treatment employed. 3 For more information on how the U.S. manages an all-hazards response, see http://www.fema.gov/pdf/emergency/nrf/nrf-core.pdf. 4 Please note that water should not be released without regard to statutory and regulatory requirements. ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Development of clearance goals Decontamination of system infrastructure Decontamination of household infrastructure/equipment (e.g., hot water heaters, etc.) Disposal of solids including treatment residuals5 Disposal of source water or water residing at consumer locations Roles and responsibilities during decontamination and/or treatment activities and disposal Details of coordination activities among involved parties Wash water generated from decontamination activities that has not been discharged to a wastewater or stormwater system6 If the contamination event requires a criminal investigation, additional actions that are outside of the scope of this guide may be required to preserve and collect evidence. In this case, the responding agencies should co- ordinate evidence preservation/collection and treatment/disposal activities with applicable agencies, such as local law enforcement, U.S. Environmental Protection Agency (EPA) Criminal Investigation Division (CID), or the Federal Bureau of Investigation (FBI). How Should this Guide be Used? This guide is intended to be used as a preparedness tool and as a reference during emergency response-related containment, treat- ment, and disposal activities for large amounts of water. Informa- tion and recommendations presented in this guide are subject to change, and users are encouraged to consult current versions of the laws, regulations, resources, and references presented. In ad- dition to the methods, statutes, regulations, and issues discussed in this guide, it may be appropriate to consider other factors such as system size, available assets, and state and local regulations pertaining to the treatment, storage, and disposal of large amounts of contaminated water. This guide does not supersede any federal or state statutes or regulations. Please consult state authorities for guidance on ad- ditional requirements, as states may have laws or regulations that are more stringent than federal laws and regulations. Which Contaminants Are Included in this Guide? Chemical, biological, toxin, and radiological contaminants of con- cern to the Water Sector are included in this guide. Contaminant- specific information is identified through color-coding and the use of contaminant-specific icons. Table 1-1 presents the contaminant classes covered in each section of the guide. How is this Guide Organized? This guide is organized in the following sections: 1.0 Introduction 2.0 Containment, Treatment, and Disposal as Part of Response and Recovery 3.0 Containment and Treatment of Water 4.0 Disposal of Water 5.0 Storage and Transportation Appendix A: Risk Communication Appendix B: Potential Treatment Methods Appendix C: Sample Disposal Checklist Appendix D: Resources Appendix E: Summary of Potentially Applicable Laws and Regulations Appendix F: References 5 This document is not meant to provide guidance for the disposal of solids. However, under RCRA, solid waste includes solid, liquid, semisolid, or contained gaseous material. Liquids considered solid waste by RCRA are included in this guide. Please refer to the glossary for the definitions of both solid and solid waste. For information and resources on disposal of solids, refer to Appendix D, Table D-5. 6 While this document is not intended to provide recommendations for the disposal of wash water, some of the information in this guide may be applicable to wash water. ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Table 1-1: Classes of Contaminants Addressed in Guide Treatment Method * & CHEM nSn owLx' BIO n2n O^L^ TOXIN 4.4 RAD Method Description Chemical Warfare Agents Heavy Metals Hydrophobics Pesticides Bacteria Viruses Protozoa Plant Toxins Bacterial Toxins Algal Toxins Fungal Toxins Alpha Betaf Gamma* Representative Contaminants BZ Cyclosarin Lewisite Sarin Arsenic Cadmium Chromium Copper Chlordane Chlorinated solvent mixtures Coal Tars Diesel Gasoline Aldicarb Carbofuran Dichlorvos Dicrotophos Bacillus anthracis Brucellaspp. Burkholderia spp. Clostridium perfringens Coxiella burnetii Escherichia co//O157:H7 Caliciviruses Hepatitis A virus Cryptosporidium spp. Giardia spp. Digoxin Anatoxin A Botulinum Brevetoxin Microcystins Aflatoxin Sulfur Mustard Tabun VX Mercury Nickel Thallium Heating oil Industrial dyes and solvents Petroleum products (including oil and petroleum) PCBs Fenamiphos Mevinphos Phorate Francisella tularensis Salmonella Typhi Shigella dysenteriae Vibrio cholerae Yersinia pestis Rotavirus Variola major virus (Smallpox) Toxoplasma gondii Ricin Staphylococcal enterotoxin B (SEB) Saxitoxin T2 mycotoxin Americium-241 Cesium-137 Cobalt-60 Americium-241 Cesium-137 lridium-192 Strontium-90 Cobalt-60 lridium-192 * High-level radioactive waste (HLRW) is not covered in this document. t Of the four radioisotopes shown here, only Strontium-90 is predominantly a beta emitter; Cesium-137, Cobalt-60, and lridium-192 are predomi- nantly gamma emitters. t Americium-241 is predominantly an alpha emitter. ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Figure 1-1 presents a high-level overview of the recommended process for containment, treatment, and dis- posal of water contaminated with CBR contaminants for drinking water, wastewater, and stormwater systems. Flowcharts in Section 3.0 and Section 4.0 incorporate more detail on containment/treatment and disposal, respectively. The recommended processes for containment/treatment and disposal for drinking water systems and wastewater/stormwater systems differ, and, therefore, separate flowcharts are provided. Identification of Contamination Containment for Treatment Disposal of Water /' Contamination confirmed in \ | drinking water, wastewater : s and/or stormwater system / V Contain water Conta In situ tempor v Determine / ^ On site f treatment V Apply Deter treatment treatt v Assess water to confirm treatment and determine disposal method V Determine method of disposal ir v V /Direct discharge^ f***^ ^P°sal at a hazardou^X , through a or medical waste facility ^to surface wate^ ^ wwyTp J ^ (CHEM, BIO, TOX) 7 t t V n water in any storage ^-^ Transport off site 4-Off site-*' for treatment and/or disposal milS v TO trpat m \ Tn HiT-wv-o nent vix V V Underground^ AolHum^ducttioriN\ .... and solidification VnjeCtl0V V (RAD only) J t Figure 1-1: Overview of Potential Options for Containment, Treatment, and Disposal of Large Amounts of Water from Drinking Water, Wastewater, and/or Stormwater Systems 4 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities 2.0 Containment, Treatment, and Disposal as Part of Response and Recovery Containment, treatment, and disposal of large amounts of water associated with decontamination activities may be critical to response and recovery after a contamination event at a water utility. This section provides information that may be taken into consideration, including actions taken prior to containment, additional response and recovery guidance, statutes and regulations, and potential partners in disposal operations. 2.1 Actions Prior to Containment Response actions taken prior to containment may include confirmation of contamination and identification of contaminant type.7 Response and recovery actions that support containment, treatment, and disposal planning may include: Characterization of the CBR contaminant and utility system - After initial identification, further character- ization of the chemical, biological, and radiological (CBR) agent may provide critical information regarding contaminant concentrations and any potential health risks. Characterization of the affected utility may provide critical information concerning the location and status of the contaminant in the system (e.g., whether the agent is stable or prone to hydrolysis or natural attenuation). Determination of clearance goals - Prior to containment, treatment, and/or disposal, clearance goals may be established on a site-specific and incident-specific basis by the Incident Command (1C) in accordance with applicable statutory and regulatory requirements. Clearance goals may also specify measurable criteria, in accordance with any applicable laws and regulations, for determining the success of treatment. Development of the Remediation Action Plan - The drinking water, wastewater, and/or stormwater system may develop a site-specific and incident-specific Remediation Action Plan that describes actions to remove, reduce, or eliminate contaminates in or on a site. It includes a treatment and decontamination strategy in ac- cordance with any applicable laws and regulations. This plan may consider the capabilities and limitations of the system, the circumstances of the contamination incident, volume and location of contaminated water, and any applicable statutory and regulatory requirements. 2.2 EPA Water Sector Response and Recovery Guidance The following documents provide additional information regarding response and recovery and may be used in conjunction with this guide: Water Security Initiative: Interim Guidance on Developing Consequence Management Plans for Drink- ing Water Utilities, October 2008 (WSi CMP)8 -Assists drinking water utilities with the development of plans to guide the utility and partner agencies through the processes of validating, responding to, and recovering from a contamination incident in the distribution system. While the WSi CMP recommends proper disposal of wastewater, it does not provide specific guidance on the disposal of large amounts of water. However, it provides in-depth information concerning actions taken prior to containment, including characterization and development of a Remediation Action Plan, as described in Section 2.1 above. 7 Please note that the water also may be contained during the initial response. 8 See EPA 817-R-08-001, http://water.epa.gov/infrastructure/watersecurity/upload/2008_10_24_watersecurity_guide_interim_cmp_wsi.pdf. ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Response Protocol Toolbox: Planning for and Responding to Drinking Water Contamination Threats and Incidents, Interim Final, April 2004 (RPTB - Module 6)9 - Describes response and recovery activi- ties following a confirmed contamination incident; however, it provides only limited information on disposal options for water. A similar toolbox is currently under development for wastewater but is not yet available to the public. 2.3 Statutes and Regulations This section identifies statutory and regulatory requirements that may apply to planning and decision making for containment, treatment and disposal of large amounts of water con- taminated with CBR contaminants. Table 2-1 lists these statutes and regulations by con- taminant category. Summaries are available in Appendix E. The applicability of these stat- utes and regulations should be evaluated on a case-by-case and incident-specific basis. States may have EPA-approved programs for implementing certain requirements in the Resource Conservation and Recovery Act (RCRA), Clean Water Act (CWA), Safe Drink- ing Water Act (SDWA), or other federal en- vironmental statutes. States may also have additional, more stringent statutes or regu- lations as part of these programs. Please consult state authorities for guidance on ad- ditional requirements. Clean Water Act Sections 301 (f) and 311 (b) While a number of statutes and regulations may apply, two sections of CWA are particularly relevant to the contaminants included in this guide. Section 301 (f): "Not withstanding any other provisions of [the Clean Water] Act it shall be unlawful to discharge any radiological, chemical, or biological warfare agent, any high-level radioactive waste, or any medical waste, into the navigable waters." Section 311 (b): "The Congress hereby declares that it is the policy of the United States that there should be no discharges of oil or hazardous substances into or upon the navigable waters of the United States, adjoining shorelines, or into or upon the waters of the contiguous zone, or in connection with activities under the Outer Continental Shelf Lands Act or the Deepwater Port Act of 1974, or which may affect natural resources belonging to, appertaining to, or under the exclusive management authority of the United States (including resources under the Magnuson Stevens Fishery Conservation and Management Act of 1976)." 9 See EPA 817-D-03-006, http://water.epa.gov/infrastructure/watersecurity/upload/2004_05_19_watersecurity_guide_response_module6.pdf. ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Table 2-1: Potentially Applicable Federal Statutes and Regulations for Containment, Treatment, and Disposal Chemical Biological Toxin Radiological * 33 USC 1251 etseq. t 42 USC 9601 et seq. CERCLA may apply in incidents involving federal response or requiring federal assistance. This guide does not include all exemptions that may apply during incidents requiring federal assistance or federal response. See http://www.epa.gov/lawsregs/laws/cercla. html for more information. t 7 USC 136 etseq. H 49 CFR Parts 100-185. § 33 USC 40 2701-2720; applicable when dealing with a discharge of oil (may also apply for discharge of a mixture of oil and Clean Water Act section 311 hazardous substances). ** 42 USC 6901 et seq. ft 42 USC300f etseq. # 15 USC2601 etseq. HH 42 USC2011 etseq. §§ 42 USC 2021 bet seq. 2.4 Potential Partners The following entities may be involved in containment, treatment, and disposal operations, depending on site-specific and incident-specific characteristics of the contamination event: Drinking water utility Stormwater utility Wastewater utility Neighboring utilities (drinking water and/or wastewater) Local health department Local law enforcement ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Local government Local emergency planning committees and emergency management agencies Local fire, emergency medical service (EMS), and hazardous materials (HAZMAT) responders State government State environmental and/or public health laboratories State environment or health department State emergency responders State emergency management and homeland security agencies State law enforcement State drinking water and wastewater primacy agencies Mutual aid and assistance partners Media Centers for Disease Control and Prevention (CDC) EPA regional offices and/or laboratories EPA Criminal Investigation Division (CID) Joint Terrorism Task Force (JTTF) Federal Bureau of Investigation (FBI) National Guard National Response Center Nuclear Regulatory Commission (NRC) U.S. Army Corps of Engineers (USAGE) U.S. Department of Homeland Security, including Federal Emergency Management Agency (FEMA) and U.S. Coast Guard (USCG) ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities 3.0 Containment and Treatment of Water Contaminated water generally should be contained and treated either in situ or using temporary storage con- sistent with applicable regulatory requirements. Figure 3-1 and Figure 3-2 illustrate a recommended decision- making process for choosing whether to contain in situ or in temporary storage for drinking water systems and wastewater/stormwater systems, respectively. Numbers in the flowcharts indicate sections in this guide where the specific topics are discussed in more detail. A number of factors should be considered when evaluating containment and treatment methods, including: Risk to public health and the environment Worker health and safety Contaminant properties - Potential adherence to infrastructure and subsequent contamination of additional water - Formation of, or interaction with, biofilms - Potential formation of secondary contaminants through hydrolysis or other mechanisms - Aerosolization and/or vaporization potential Any isolation of water that may be needed during confirmation of contamination 3.1 Containment of Water In Situ Depending on the location of the contaminated water, containment and treatment in situ may be an option. A hydraulic map of the water system may assist in identifying potential locations of contamination. Water may be able to be contained: Before the Drinking Water Distribution System - Contaminated water that has not yet entered the drink- ing water distribution system (e.g., it is in storage tanks at the drinking water treatment facility) Within the Drinking Water Distribution System - Contaminated water that has entered the distribution system may be contained within the system by turning off valves and pumps and advising customer(s) to keep faucets closed10 Within the Wastewater or Stormwater System - Contaminated water that is contained in the wastewater system (e.g., in overflow tanks, sanitary sewer pipes) or stormwater system (e.g., in stormwater collection pipes) 10 When making the decision to contain contaminated water within a distribution system, it is important to consider any potential exposure risks to people served by the closed off portion of the system. ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities T .2 /Contamination confirmed in*' drinking water system Within Drinking Water Distribution System Before Drinking Water Distribution System X Identify and isolate contaminated water in pipe network (3.1) Yes Contain contaminated water in situ (3.1) Yes Transfer contaminated water to temporary storage on site (3.2) Contain to transport off site for treatment and/or disposal (5.2) Sample and evaluate residual contaminant concentration (3.3) Has water 'been treated to clearance" Assess water to determine disposal method (3.3) Determine method of disposal (4.0) /Direct discharge to\ (urface water (4.1)j /Disposal at a hazardous or/ medical waste facility (4.3-CHEM, BIO, TOX)^/ t . Undgr°"n, (4'4) /Volume reductior^ and solidification only) _ ! Figure 3-1: Recommended Decision-Making Framework for Containment and Treatment of Contaminated Water for Drinking Water Systems 10 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities "o c IR£ I O CO N i J.y E Is -2 IS § Contamination { confirmed in wastewater; '-.or stormwater system / ate eatmen -o cr CD CD c= i o O /-Can water be\^ contained i ' Yes Contain contaminated water in situ (3.1 ) :an water be" contained in 1 storage on site? Yes Transfer contaminated water to temporary storage on site (3.2) Determine treatment (3.3) Yes Can ^\ "water be treated in" temporary storage ^on site? (3.2)^- Yes Contain to transport off site for treatment and/or disposal (5.2) Apply treatment approach (3.3) Sample and evaluate residual contaminant concentration (3.3) Has' been treated to clearance" goals? i No Assess water to determine disposal method (3.3) ate a Determine method of disposal (4.0) .. , , , . Direct discharge to surface water (4.1 ^Disposal at a hazardous o7\ medical waste facility ^(4.3-CHEM, BIO,' ! . injection (4.4) volume reductiori gnd S0|idification (4.5.^0 on|y) Figure 3-2: Recommended Decision-Making Framework for Containment and Treatment of Contaminated Water for Wastewater and Stormwater Systems11 11 If it is decided that treatment will occur off site, it may be disposed of at a WWTR However, prior to considering disposal through a WWTP as an option, utilities should check with the proposed receiving WWTP to ensure that contaminated water can be safely treated and/or discharged according to the terms contained within the facility's discharge permit issued by EPA or an authorized state or tribe. WWTPs are not allowed to discharge contaminates above the thresholds established within their NPDES permits. 11 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Table 3-1 provides potential additional considerations for evaluating each of these containment options. Table 3-1: Potential Additional Considerations Related to Containment In Situ Storage Location Before the Drinking Water Distribution System Additional Considerations Feasibility of containing water and preventing it from entering the distribution system Health and safety of drinking water system personnel (e.g., will containment result in further exposure of workers to contaminants?) Within the Drinking Water Distribution System Feasibility of containing water within the system (e.g., construction, age, and design life of infrastructure as well as the ability to shut off valves and the timeline for these activities) Water within the drinking water distribution system posing a risk to those serviced by the closed-off portion of the system Notifying the public when contaminated water is contained within the distribution system (see Appendix A for more information on risk communication and public notification) Leaks, poorly sealed connections, corrosion, old breaks, etc., that may also allow release of vapors and water Contaminated water exacerbating corrosion of connections, pumps, etc. Within the Wastewater or Stormwater System Feasibility of containing water within the system; factors that may affect the ability to contain in situ, such as system capacity, intake flow rates, design life of infrastructure, and availability of shutoff valves Leaks, poorly sealed connections, corrosion, old breaks, etc., that may also allow release of vapors and water Contaminated water exacerbating corrosion of connections, pumps, etc. Health and safety of wastewater and/or stormwater system personnel (e.g., will containment result in further exposure of workers to contaminants?) Notifying the public when contaminated water is contained within the system and preventing sewage backups in homes (see Appendix A for more information on risk communication and public notification) Leaks within the system (e.g., collection and conveyance) that, depending on the severity, may require action (e.g., deploying HAZMAT teams) by the appropriate authority (e.g., fire department, health department) once they are identified 3.2 Containment of Water in Temporary Storage Temporary storage may be appropriate for containment of the contaminated water under a number of circum- stances including, but not limited to: Containment in situ is not feasible (e.g., stormwater or combined12 systems may not have the infrastructure or capacity to contain in situ or may result in leakage to ground water) Treatment in situ is not feasible Contaminant(s) may adhere to the walls of pipes or other system infrastructure and re-contaminate water later conveyed through the system 12 See NPDES CSO 9 Minimum Control Plan at http://cfpub.epa.gov/npdes/cso/ninecontrols.cfm?program_id=5 for more information. 12 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Potential considerations for all contaminant types when determining the type of temporary storage to use include: Quantity of water Feasibility of treatment within temporary storage Availability of tanks, containers, holding ponds, etc. Potential location of temporary storage and transportation requirements Structure and integrity of new or existing temporary storage area(s) Security of temporary storage location(s) Duration of storage Applicable regulations on construction of temporary storage area(s) Threat posed by temporary storage to the public, environment, and emer- gency responders Public health threat posed while transferring the water to storage Potential Types of Temporary Storage 55-gallon drums Single tank trucks hold 5,000 to 9,000 gallons Multiple truck tankers Use of railway tanks to hold in large facilities On-site or off-site holding tanks Empty water basins Table 3-2 provides additional contaminant-specific considerations that should be contemplated when evalu- ating options for containing water in temporary storage. Table 3-2: Additional Contaminant Specific Considerations for Temporary Storage Contaminant Type CHEM Contaminant-Specific Considerations Applicability of underground storage tank (UST) regulations (40 CFR Part 280)* Chemical properties of contaminant (e.g., toxicity, reactivity) Applicability of RCRA regulations1 State regulations regarding medical/infectious waste Labeling containers with appropriate Biosafety Level* BIO TOXIN State regulations regarding medical/infectious waste Applicability of UST regulations (40 CFR Part 280) Chemical properties of contaminant (e.g., toxicity, reactivity) Labeling containers with appropriate Biosafety Level Applicability of RCRA regulations RAD Nuclear Regulatory Commission (NRC) licenses (e.g., unless the NRC license require- ment is waived, one should apply for a license once the type of temporary storage has been chosen) Other NRC requirements RCRA requirements, if any, applicable to mixed waste * See http://www.epa.gov/swerust1/fedlaws/cfr.htm for an overview of regulations pertaining to underground storage tanks. t If temporary storage of a RCRA hazardous waste exceeds 90 days, RCRA regulations for treatment, storage and disposal facilities may apply. t See www.cdc.gov/od/ohs/biosfty/biosfty.htm for information on biosafety and the 5th edition of Biosafety in Microbiological and Biomedical Laboratories, http://www.cdc.gov/biosafety/publications/bmbl5/index.htm, for specific BSL definitions. H Contact the NRC or Agreement State for more information on NRC requirements. Also see http://www.nrc.gov/. 13 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities 3.3 Treatment of Water The following should be considered when determining which treatment methods to use: Clearance goals - Water should be treated until it meets the clearance goals in accordance with any ap- plicable laws and regulations. Sampling and analysis should be used to verify if the clearance goals have been met. Quality and characteristics of the water - Characteristics such as water alkalinity, hardness, and turbidity may influence the efficacy of treatment and the ability to accurately analyze water samples. CBR contaminant - Characteristics of the contaminant, such as solubility and specific gravity, concentra- tion of the contaminant, potential for aerosolization, possible toxicologically significant hydrolysis products (see Appendix B, Table B-2), and treatment byproducts and residuals (Table B-3) may dictate which treat- ment methods will successfully remove or inactivate the contaminant. Location of water - Whether the water is located within a water distribution system, wastewater convey- ance system, or other location can limit treatment options. System capabilities and limitations - The capabilities of the affected system may limit the system's op- tions for treatment. Health and safety considerations13 - During the treatment process, contaminants may become concen- trated. Safety precautions may include appropriate safety placards and labeling, use of personal protective equipment (PPE), and limiting periods of exposure. Extra safety precautions should be taken with residuals which may have high levels of radioactivity.14 FIFRA regulations - Chemicals, such as chlorine, chlorine dioxide, and chloramines, used to treat water contaminated with biological contaminants, are typically regulated as pesticides under the Federal Insec- ticide, Fungicide, and Rodenticide Act (FIFRA), in which case they may be used only in accordance with their label or labeling.15 A FIFRA exemption should be requested and obtained for off-label use of a regis- tered pesticide or use of an unregistered pesticide. Federal, state, and local laws and regulations - Applicable laws and regulations regarding treatment and other actions may affect the available range of treatment options. Tables 3-3, 3-4, 3-5, and 3-6 indicate candidate treatment methods for specific contaminants in each con- taminant class (see Appendix B for method descriptions and considerations, including the formation of toxic treatment byproducts).16 These tables summarize data available in EPA's online Water Contaminant Informa- tion Tool (WCIT).17 Users are encouraged to consult WCIT directly as needed since this tool is updated peri- odically as new information becomes available. Tables 3-3 through 3-6 reflect current WCIT data and should not be viewed as an exhaustive or critical review of the state of the science for treatment technologies listed. 13 See http://www.osha.gov/index.html. 14 See http://www.epa.gov/safewater/radionuclides/pdfs/webcast/presentations/worker_safety_loren_setlow.pdf. 15 See http://www.epa.gov/pesticides/regulating/laws.htm#fifra. 16 Tables 3.4, 3.5, and 3.6 do not address treatment residuals. 17 See http://www.epa.gov/wcit/for more information and updates on treatment methods. Registration is required. 14 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Table 3-3: Potential Treatment Methods for Water Contaminated with Chemicals CHEM BZ Cyclosarin Lewisite Sarin Sulfur mustard Tabun VX Arsenic Cadmium Chromium Copper Mercury Nickel Thallium Chlorinated solvent mixtures Chlordane Coal tars Diesel fuel Gasoline Heating oil Industrial dyes and solvents Petroleum products (e.g., oil and petroleum) PCBs Aldicarb Carbofuran Dichlorvos Dicrotophos Fenamiphos Mevinphos P ho rate * The term "sorbents" includes granular activated carbon and powdered activated carbon. 15 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Table 3-4: Potential Treatment Methods for Water Contaminated with Biologicals BIO Bacillus anthracis Brucella spp. Burkholderia spp. Clostridium perfringens Coxiella burnetii Escherichia coli O157:H7 Francisella tularensis Salmonella Typhi Shigella dysenteriae Vibrio choleras Yersinia pestis Caliciviruses Hepatitis A virus Rotavirus Variola major virus (Smallpox) Cryptosporidium spp. Giardia spp. Toxoplasma gone/// 16 ------- Containment and Disposal of Large Amounts of Water: A Support Guide for Water Utilities Table 3-5: Recommended Treatment Methods for Biotoxin Contaminated Water TOXIN tin >xin A inum lylococcal Enterotoxin B (SEB) ;toxin tcystins oxin jxin ycotoxin Table 3-6: Potential Treatment Methods for Water Contaminated with Radiologicals* RAD 5 Eg -E i 1 Americium-241 Cesium-137 Cobalt-60 lridium-192 Strontium-90 * See WCIT at http://www.epa.gov/wcit/ for more information and updates on treatment methods. Registration is required. In addition to WCIT, this table includes treatment methods investigated in other EPA preliminary scoping studies on existing methods. t EDR = Electrodialysis reversal. 17 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities The following methods and resources should be consulted in support of laboratory analyses before and after treatment: Water sampling and analysis methods - EPA's Sampling Guidance for Unknown Contaminants in Drinking Water, November 2008 (EPA-817-R-08-003), EPA's Standardized Analytical Methods for Environmental Restora- tion Following Homeland Security Events -2010 (Revision 6.0, EPA-600-R-10-122), or state-approved methods (EPA-817-R-08-003, EPA-600-R-10-122)18<19 Laboratory capabilities and capacities - Environmental Response Laboratory Network (ERLN) and the Water Laboratory Alliance (WLA)20 Analytical methods for response to contamination with CBR contaminants - WCIT21 Test procedure guidelines and methods - Guidelines Establishing Test Procedures for the Analysis of Pollutants (40 CFR Part 136) for certain CWA programs and methods included in the National Primary Drinking Water Regulations (40 CFR Part 141) Certified drinking water laboratories - Laboratories certified by EPA or the state to analyze drinking water samples for monitoring compliance with drinking water standards. Contact EPA's State Certification Program for a list of certified laboratories.22 18 See http://water.epa.gov/infrastructure/watersecurity/wla/upload/2008_12_31_watersecurity_pubs_guide_watersecurity_ samplingforunknown.pdf 19 See SAM at http://www.epa.gov/sam/SAM_2012_07162012.pdf; SAM is updated as new information becomes available; users should consult the most current version of this document. 20 Seewww.epa.gov/compendium/for ERLN and WLA (registration required). 21 See http://www.epa.gov/wcit/for more information on analytical methods (registration required). 22 See http://water.epa.gov/scitech/drinkingwater/labcert/for more information on the Drinking Water Laboratory Certification program. 18 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities 4.0 Disposal of Water After the contaminated water has been treated, the sampling and analyses have been completed, and the clear- ance goals for treatment have been met, the water should be assessed to determine suitable disposal options in accordance with applicable laws and regulations. For example, when water contains certain contaminants or exhibits certain characteristics, statutes such as RCRA, CWA, and FIFRA and their implementing regulations may have additional requirements for disposal. The following potential disposal methods are discussed in Sections 4.1- 4.5: Direct discharge to surface water Disposal through a wastewater treatment plant (WWTP) Transfer to a hazardous or medical/infectious waste facility Disposal in an underground injection well Volume reduction and solidification (radiological contaminants only) RCRA Hazardous Waste Permits and Manifests NRC Disposal Application CHEM TOXIN Disposal of water that is considered RCRA hazardous waste may require: An EPA identification number (EPA Form 8700- 12) A hazardous waste manifest for transport (EPA Form 8700-22) Permits for the disposal facility EPA RCRA forms can be obtained either online at http://www.epa.gov/osw/hazard/index.htm or by contacting the state waste and/or environmental office. Water utilities sending RCRA hazardous waste off site should ensure that the transporter and disposal facility are in compliance with all RCRA requirements. WWTPs that treat hazardous wastewater may qualify for a Permit-By-Rule exemption (40 CFR 270.60) whereby the facility's non-RCRA permit serves in place of a RCRA permit, provided that the facility is in compliance with its permit and other RCRA administrative requirements. Waste discharged under a Permit-By-Rule must meet all federal, state, and local pretreatment requirements. For information regarding state- specific RCRA requirements, state agencies should be contacted. RAD In some instances of radiological contamination, an NRC disposal application may be required. If required, an NRC disposal application should be submitted to obtain approval of the disposal method selected (authority provided to NRC under the AEA, as amended). The NRC or Agreement State should be contacted to determine if this approval is required. The NRC provides a list of provisions in 10 CFR 20.2002 for the approval of a disposal procedure not otherwise authorized by NRC regulations. If a disposal application is required, all the following information needs to be submitted in an NRC application before disposing of the water: A description of the waste, including the physical and chemical properties important to risk evaluation, and the proposed manner and conditions of disposal An analysis and evaluation of pertinent information on the nature of the environment/location of disposal The nature and location of other potentially affected licensed and unlicensed facilities Analyses and procedures used to ensure that doses are maintained as low as reasonably achievable (ALARA) and within the dose limits this part 19 ------- Table 4-1 provides a high-level overview of potential characteristics and corresponding disposal requirements which may be helpful when evaluat- ing the above options. The column titled "Potential Disposal Requirements" in particular highlights potential limiting factors to consider. Table 4-1: Characteristics of Treated Water and Potential Disposal Requirements Characteristic Contains chemical, biologi- cal, or radiological warfare agent Class CHEM Potential Disposal Requirements BIO TOXIN RAD The Clean Water Act Section 301 (f) pro- hibits the discharge of any radiological, chemical, or biological warfare agent, any high-level radioactive waste, or any medical waste into the navigable waters. Other Potential Considerations To Evaluate If the contaminant is a chemical warfare agent, the wa- ter also may be considered RCRA hazardous waste. If the contaminant is a biological warfare agent, the water also may be considered infectious/medical waste. If the contaminant is a radiological warfare agent, determine whether the contaminant is an alpha, beta, or gamma emitter. Contains harmful quantities pursuant to the Clean Water Act 311 (b) and the sheen rule (40 CFR 110.3) pro- mulgated thereunder. Rule prohibits a discharge that would: Cause a sheen or discol- oration on the surface of a body of water Violate applicable water qual- ity standards Cause a sludge or emulsion to be deposited beneath the surface of the water or on adjoining shorelines CHEM Oil that violates the sheen rule should not be discharged to navigable waters as out- lined in the Clean Water Act Section 311 (b) and 40 CFR Part 110. For disposal of water contaminated with oil, users should contact the appropriate EPA regional office or the state and local authorities (e.g., departments of environmental protection, fish & wildlife, etc.) for the applicable Area Contingency Plan (ACP). Please refer to Appendix E for more information on the ACR EPA reporting exemptions for releases include: - Discharges from properly functioning vessel engines - Research and development releases - National Pollutant Discharge Elimination System (NPDES)-permitted releases - Discharges permitted under International Convention for the Prevention of Pollution from Ships (MARPOL) See http://www.epa.gov/emergencies/content/ reporting/oilexem.htm for more information. NJ O ------- Characteristic Contains cancelled or sus- pended pesticide (7 USC 136d) See http://www.epa.gov/pes- ticides/regulating/registering/ suspensions.htm for a current list of suspended pesticides and http://www.epa.gov/pes- ticides/reg u lating/restricted. htm for more information on cancelled pesticides Class CHEM Potential Disposal Requirements EPA may have issued additional require- ments and/or procedures for those who dis- pose of the pesticide (varies by pesticide). The EPA regional or headquarters pesti- cides program office should be contacted to determine if there are additional require- ments and/or procedures for the cancelled or suspended pesticide and to determine if those requirements and/or procedures ap- ply to the contaminated water. Other Potential Considerations To Evaluate Additional requirements and/or procedures may include: - Labeling and disposal of the pesticide - Labeling and disposal of any container of a pesti- cide, any rinsate containing the pesticide, or any other material used to contain or collect excess or spilled quantities of the pesticide Contains PCBs or other TSCA-regulated chemicals Contact the EPA regional office to determine if the contaminant is regulated under TSCA CHEM Restrictions will depend on the contaminant. For example, PCB- contaminated waters are subject to specific requirements under 40 CFR Part 761. States may have additional regulations governing PCB disposal. State or local officials should be consulted for addi- tional considerations as they vary by state. Considered RCRA hazard- ous waste (40 CFR Part 261) The water is considered a RCRA hazardous listed waste* or The water exhibits hazardous waste characteristics of ignit- ability, corrosivity, toxicity, or reactivity CHEM TOXIN Subject to RCRA hazardous waste requirements for transportation, storage, and disposal including: - An EPA identification number - Hazardous waste manifest - Permits If the treated water is considered a RCRA hazard- ous waste and is shipped to a WWTP for disposal (or another WWTP if the contamination occurred at a wastewater treatment system), the receiving WWTP may be subject to additional RCRA regulations. Considered medical or infec- tious waste State or local officials should be consulted to determine if the water qualifies as medical or infectious waste BIO CWA Section 301 (f) prohibits discharge of medical waste to navigable waters as noted above. Some states require medical/infectious waste to be disposed of as RCRA hazard- ous waste while others enforce special medical/infectious waste requirements. State or local officials should be consulted for addi- tional considerations as requirements vary by state. ------- Characteristic Considered low-level radio- active waste (LLRW) Confirm that the water is considered LLRW (i.e., radio- active by coming in contact or co-existing with low levels of radioactive materials or neu- tron activation) Class V RAD Potential Disposal Requirements Maximum federal or state regulatory con- centrations for direct discharge to surface water and release into sewers may apply. Other Potential Considerations To Evaluate An NRC or Agreement State license may be required to handle and dispose of the water. Consider whether the contaminant is an alpha, beta, or gamma emitter. O o ff 3 3 CD a 03 3 Q q 55' a o M 03 1Q CD > O £ p* to s, o o a 03 3 5' 03 c? a I CD CO c 73 73 O 3- Q c ci CD Considered low-level mixed waste (LLMW) Confirm that the water is con- sidered LLMW (see above) Confirm the water is a RCRA hazardous waste (see above) V RAD Maximum federal or state regulatory con- centrations for direct discharge to surface water and release into sewers may apply for radioactivity. Subject to RCRA hazardous waste regu- lations for transportation, storage, and disposal unless an exemption is obtained (Appendix E, Table E-2). An NRC or Agreement State license may be required to handle and dispose of the water. Consider whether the contaminant is an alpha, beta, or gamma emitter. If the treated water is considered a RCRA hazard- ous waste and is shipped to a WWTP for disposal (or another WWTP if the contamination occurred at a wastewater treatment system), the receiving WWTP may be subject to additional RCRA regulations. * See http://www.epa.gov/osw/hazard/wastetypes/listed.htm. Figures 4-1 and 4-2 provide a suggested order for evaluating these disposal methods depending on the characteristics of the water and typical availability of the method. One may evaluate any of these methods, as long as the disposal is conducted in accordance with applicable statutory and regulatory requirements. Numbers in the flowcharts indicate sections in this guide where the topic is discussed in more detail. £ CD" CD' t/i NJ NJ ------- 1-1 I _ o 2 O a .!£ O Contamination confirmed in drinking water system Obtain NPDES \ permit and discharge ) ^tp surface water (4.1>' Obtain required i permits and discharge \water to WWTP (4.21 Obtain required i manifest and transport to hazardous waste facility (4.3) ^Obtain required permits ano\ 1 inject underground (4.4) j Solidify waste and refer to solid waste disposal guidance ^_ (4.5-RAD only) Figure 4-1: Recommended Decision Tree for Evaluating Disposal of Treated Water for Drinking Water Systems CD 10 ------- , .,, _ , ... ... Identification of Disposal/Storage Containment and Treatment of Water _ . . .. Contamination Contamination confirmed in wastewater and/or stormwater Contain water . /nstfu(3.1) T Determine treatment (3.3) * On-ste Contain water in emporary storage (3.2) A ( 1 C w Apply treatment (3.3) « Determine treatment (3.3) \t r Assess water to confirm treatment and determine disposal method (3.3) Stormwater System Consider direct water (4.1) /Do the\ /contaminants/ <^ meet discharge / No Requirements?/ Yes (^^ Wastewater System a / \, /Can water/ /be processed/^ / through POTVW / \FOTVWWWTP of/ /J4-2)/ Yes /Process through \ : POTW/FOTW/ i \ WWTP (4.2) , 1 Consider WWTP (4.2) 1 Transport off , ff-site ^for treatment ar disposal (5.C To treat f- / To dispose /Does watei/^ /meet requirements/ to d scharge to other N -, "/^ POTW/FOTW/CWT/ \private WWTP? / Yes A Has xOther WWTP agreedx /to accept the water and/_No /approved method &/ / discharge? / \ (4.2) / Yes / Obtain required permits and \ ^discharge water to WWTP (4.2)J ite d/or ) 1 Consider disposal at waste facility (4.3) /hazardous// / medical waste /y^ / facility accept / / waste? / // I Yes J /^Obtain required \ / manifest and transport X) I to hazardous waste } facility (4.3) ^/ Yes 4 Consider underground injection (4.4) x-appropriate\^ / class injection /^No /well available?/ /(4.4)/ Yes JL /Injection weiN> No /accept water?/ Yes 1 -WaHhe- Yes Consider volume / .. \ A\, / volume / ' reduction / \ / solidification \ NO /feasible? (4.5-/ /RAD only)/ Yes /''Solidify waste and/ / refer to solid waste \ \, disposal guidance Obtain required permits an^ V (4.5-RAD only) ^/ V inject underground (4.4) ^ .' Figure 4-2: Recommended Decision Tree for Evaluating Disposal of Treated Water for Wastewater and Stormwater Systems CD CD 10 *». ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities 4.1 Direct Discharge of Water to Surface Water Direct discharge to surface water may be an option for disposing of water from a drinking water system, storm- water system, or water contained and treated in temporary storage. Table 4-2 summarizes the process of ob- taining approval and discharging the water, along with any specific requirements or characteristics of the water that should be considered prior to discharge. Table 4-2: Information on Disposal by Direct Discharge to Surface Water (Chemical, Biological, Toxin, and Radiological) Contaminant Type CHEM BIO TOXIN RAD Contaminant-Specific Considerations 1. Locate an accessible and appropriate body of water. 2. Contact the state environmental office or EPA regional office to apply to obtain or modify an existing NPDES permit. Note that in some cir- cumstances, discharges in compliance with the instructions of an On-Scene Coordinator may not require an NPDES permit. For more information, see 40 CFR 122.3(d). 3.Test the water using methods in EPA's SAM or other appropriate methods to confirm that con- taminant levels are below the acceptable dis- charge levels listed on the NPDES permit. 4. Discharge to surface water following the specifi- cations listed in the NPDES permit. 5. Obtain a license or other approval from the NRC or Agreement State to discharge to the receiving body of water, if applicable. (Radiological only) Potential Discharge Specifications/ Requirements The following characteristics of the dis- charge should be considered: - Location of discharge - Method of discharge - Time of discharge - Volume of discharge - Flow rate of discharge - Water profile The Clean Water Act Section 301 (f) pro- hibits the discharge of any chemical, biological or radiological warfare agent, any high-level radioactive waste, or any medical waste into the navigable waters. Oil that meets the Sheen Rule should not be discharged to navigable waters as per CWA 311(b) and 40 CFR Part 110. (Chemical, Biological, and Toxin Only) NPDES Permits Discharge to surface water is regulated by the CWA, which prohibits discharge of pollutants to waters of the United States except as in compliance with specified provisions of the Act. To discharge to surface water, an NPDES permit should be obtained from the authorized state or EPA region (40 CFR Part 122 et seq.). An NPDES permit includes the following: Technology-based and water quality-based limitations on pollutant discharges to surface water Additional provisions such as monitoring and reporting requirements EPA's national recommended water quality criteria are available at http://water.epa.gov/scitech/swguidance/ standards/criteria/current/index.cfm. These criteria are published pursuant to Section 304(a) of the CWA and provide guidance for states and tribes to use in adopting water quality standards. For more information, please see: http://cfpub.epa.gov/npdes/home.cfm?program_id=45. 25 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities 4.2 Disposal of Water through a Wastewater Treatment Plant (WWTP) Water from all systems may be disposed through four types of WWTPs depending on a variety of factors includ- ing, but not limited to, the availability of the facility and characteristics of the water. These four types of WWTPs are the following: Publicly owned treatment works (POTW) Federally owned treatment works (FOTW) Centralized waste treatment facility (CWT) (chemical contaminants only) Privately owned WWTPs If the water from the incident was contained within the wastewater system, disposal may be appropriate through the WWTP of the system consistent with the NPDES permit requirements and any applicable permit. It should be determined if the water can be processed through the WWTP of the system without causing an untreated pass-through or interference or violating any applicable pretreatment requirements, or if the water should be transported to another WWTP Different types of WWTPs may have different requirements for accepting water.23 Table 4-3 lists requirements that may apply and other potential considerations pertaining to the type of WWTP Table 4-4 summarizes the recommended process a system may use to identify a receiving treatment works and provides additional infor- mation for the process of requesting a permit to discharge to a WWTP 23 Water discharged from a WWTP should be authorized by and consistent with a discharge permit issued by EPA or an authorized state or tribe. 26 ------- Table 4-3: Some Key Additional Requirements and Considerations for WWTPs* WWTP Type POTW Additional Requirements Water meets all the: - Federally prohibited discharge stan- dards - Federal categorical pretreatment re- quirements (which vary by industrial process category) - State laws and regulations - Local limits established by the POTW to prevent either: Pollutants in the treated water from passing through the POTW untreat- ed Interferences with the POTW (i.e., inhibition or disruption of POTW treatment process or operations or sludge process, use, or disposal) CHEM TOXIN V RAD BIO Contaminant-Specific Considerations Water considered a RCRA hazardous waste may be subject to additional disposal requirements described in the following documents: - EPA's Guidance Manual for the Control of Wastes Hauled to Publicly Owned Treatment Works, September, 1999, which explains how smaller POTWs without pretreatment programs (see box below) accept and control hauled wastewater* - EPA's Guidance Manual for the Identification of Hazardous Waste Delivered to POTWs by Truck, Rail or Dedicated Pipe, June 1987, which provides guidance on hazardous waste hauled to POTWs* Water classified as hazardous may also be subject to additional reporting require- ments, as listed in 40 CFR 403.12(p). If the treated water is considered a RCRA hazardous waste and is shipped to a WWTP for disposal (or another WWTP if the contamination occurred at a wastewater treatment system), the receiving WWTP may become a hazardous waste facility and may be subject to additional RCRA regulations. Maximum federal or state regulatory concentrations for direct discharge to surface water and release into sewers may apply for radioactivity. Some states require medical/infectious waste to be disposed of as RCRA hazardous waste while others enforce special medical/infectious waste requirements. O o I. 5' 3 CD p* D) Q. CO a o to Q> D) 1Q CD 3 o 3 e/T 2, I c? T3 73 O Q c OL CD * Please note that regardless of the type of facility, the discharge must be authorized and consistent with a discharge permit issued by EPA or an authorized state or tribe. t Publication No. EPA-833B-98-003; see http://water.epa.gov/aboutow/owm/upload/2005_07_14_hwfinal.pdf. t Publication No. EPA-833-B-87-100; see http://nepis.epa.gov/Exe/ZyPURL.cgi7Dockey=2000SWI9.txt. CD i c CD t/i 10 ------- WWTP Type FOTW OR OTHER WWTP Additional Requirements The discharge of the water should be covered by a permit as described below: The FOTW or WWTP addresses the specific discharge either in the FOTW/ WWTP's NPDES permit or The discharge is subject to a separate NPDES regulation pursuant to 40 CFR 122.44(m) or analogous state, territo- rial, or tribal NPDES regulation in areas where such government is authorized to administer the NPDES permitting program CHEM TOXIN V RAD Contaminant-Specific Considerations Discharges to an FOTW/WWTP that are not subject to and in compliance with require- ments such as federal prohibited discharge standards, federal categorical pretreatment standards, and local limits may be subject to requirements applicable to "solid waste" under RCRA as well as effluent guidelines and standards. Maximum federal or state regulatory concentrations for direct discharge to surface water and release into sewers may apply for water exhibiting radioactivity. o o ff 3 3 CD a 03 a. q 55' a o SL o 1Q CD > O £ p* to s, o o a 03 3 5' 03 c? a I CD CWT The CWT accepts wastewater from off site for treatment and/or recovery CWTs are subject to the Centralized Waste Treatment Rule (40 CFR Part 437), which may affect the CWT's con- ditions for acceptance of the water CHEM Different CWTs may be better suited to treat water contaminated with different contaminants (e.g., CWT for oily wastes if the contaminant is oil or another hydrophobic, or CWT for metal-bearing wastes if the contaminant is a heavy metal). The resulting wastewaters from the CWT may be discharged directly to waters of the U.S. or indirectly to a POTW consistent with any applicable statutory or regulatory requirements or permit conditions. CO c 73 73 O 3- O CD 31 £ CD" CD' t/i NJ 00 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Table 4-4: Information on Disposal by Transfer or Discharge to a WWTP Recommended Process for Identifying and Contacting a POTW, FOTW, CWT, or Other WWTP To transfer or discharge water to a POTW, FOTW, CWT, or other WWTP, one should: 1. Identify potential treatment facility. 2. Contact a POTW, FOTW, CWT, or other WWTP and request (in writing) formal permission to discharge to the treatment works. 3. In the written request, inquire about what requirements the WWTP has for accepting the treated water. 4. If the POTW agrees to accept the treated water, obtain an individual control mechanism from the POTW (e.g., permit, license, contract, etc.) and provide information for revising the NPDES permit if necessary. Alternatively, for discharges to an FOTW, CWT, or other WWTP provide information for revising the NPDES permit for the FOTW, CWT, or other WWTP enabling it to accept the water, if necessary. 5. Confirm that contaminant levels are compliant with the individual control mechanism issued by the POTW or with the requirements of the NPDES permit for the FOTW, CWT, or other WWTR If contaminant levels are not compliant, pursue alternate disposal options. 6. After an authorization to send the waters to the POTW, FOTW, CWT, or other WWTP is confirmed, discharge the water to the treatment works following the requirements and instructions listed on the individual control mechanism or the permit, as applicable. Common Specifications and/or Requirements The following characteristics of the discharge should be considered: - Method of discharge - Time of discharge - Location of discharge - Volume of discharge - Flow rate of discharge - Discharge standards The Clean Water Act Section 301 (f) prohibits the discharge of any chemical, biological, or radiological warfare agent, any high-level radioactive waste, or any medical waste into the navigable waters. Oil that meets the Sheen Rule should not be discharged to navigable waters as per CWA 311(b)and40CFRPart110. Pretreatment Programs An analysis of pretreatment requirements designed to prevent pass through, inhibition, and sludge contamination at a WWTP should be conducted prior to any transfer or discharge of hazardous waste to the facility. Section 307(b) of the CWA established the National Pretreatment Program which sets and/or enforces the following: Prohibited discharge standards - apply to pollutants that can never be discharged to a POTW (given below) Categorical pretreatment standards - national, technology-based limits on pollutant discharges that vary according to industrial sector Local limits - standards to prevent untreated pass-through at or interference with specific POTWs National Pretreatment Standards: Prohibited Discharges (40 CFR 403.5) The CWA prohibits the discharge of certain pollutants to a POTW, including chemical contaminant(s) and/or residuals from the treatment process. A POTW also may refuse to accept waste from a discharger. Potential applicable prohibitions include pollutants that may cause the following: A pass-through or interference with the treatment processes (including effects on the quality of sludge) Corrosive structural damage to the treatment works Acidification of the water to a pH lower than 5.0, unless the treatment works is designed to accommodate such a discharge Additionally, potentially prohibited pollutants include the following: Solid or viscous pollutants in amounts that will cause obstruction to the flow of the POTW Petroleum oil, non-biodegradable cutting oil, or products of mineral oil origin that will cause interference or pass-through 29 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities 4.3 Transfer of Water to a Hazardous or Medical/Infectious Waste Facility Transfer to a hazardous waste facility may be an option for disposal of water from drinking water, wastewater, and stormwater systems. The following considerations should be evaluated prior to disposal: Is the treated water considered a RCRA hazardous waste or a medical/infectious waste handled by the state as RCRA hazardous waste? Does the facility agree to accept the water? Does the treated water meet the conditions that the facility has for acceptance? Does the facility have the appropriate licenses and permits? Similarly, transfer to a medical/infectious waste facility may be an option for disposal of water from drinking water, wastewater, and stormwater systems. The following considerations should be evaluated prior to disposal: Is the treated water considered a medical/infectious waste? Does the facility agree to accept the water? Does the treated water meet the conditions that the facility has for acceptance? Does the facility have the appropriate licenses and permits? 4.4 Underground Injection of Water Underground injection may be a disposal option for treated water if: The injection activity is permitted or authorized by rule, and the injection well is constructed and operated so that underground sources of drinking water are not endangered. Owners/operators of wells are responsible for obtaining the necessary permits or authorizations. An appropriate class of injection well is available and willing to accept the water, or a new well is constructed, and use of the well for injection is consistent with the existing or new Underground Injection Control (UIC) permit/authorization. A new or revised permit may need to be obtained, or in the case of an injection well au- thorized by rule, one may be required to submit updated inventory information. Only specific types of wastes are allowed to be injected into a given well class. The disposer of the water contacts the well owner/operator and receives permission to transfer the water. The well owner/operator contacts the EPA regional UIC program office or the state if the state has UIC pri- macy. Table E-1 in Appendix E describes the different classes of injection wells, class uses, and considerations for us- ing each well class in further detail. More information on underground injection is available from the UIC program office in states with UIC primacy.24 For states that do not have UIC primacy, information is available from the EPA regional UIC program office.25 24 See EPA's Underground Injection Control Programs Web page on UIC Primacy at: http://water.epa.gov/type/groundwater/uic/Primacy.cfm 25 See EPA's Underground Injection Control Programs Web page on UIC Regional Contacts at: http://water.epa.gov/type/groundwater/uic/ whereyoulive.cfm . 30 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities 4.5 Volume Reduction and Solidification of Water with Radiological Contaminants For water considered LLRW or LLMW, solidification may allow for disposal at an LLRW disposal facility.26 In this scenario, the feasibility of volume re- duction and solidification should be determined. Smaller quantities of wa- ter may be solidified without volume reduction. For additional information on solidification of mixed waste, see http://nepis.epa.gov/Exe/ZyPURL. cgi?Dockey=P10094M5.txt. LLMW Requirements RAD Water considered LLMW may be subject to RCRA requirements. The EPA Regional RCRA or Authorized State RCRA program office should be contacted to determine applicable requirements or to determine if the water qualifies for an exemption if it is stored as LLRW (see Appendix E for a description of the exemption). 26 See Glossary for definition of stabilization/solidification. 31 ------- Containment and Disposal of Large Amounts of Water: A Support Guide for Water Utilities 5.0 Storage and Transportation of Water As part of the response and recovery process, water may need to be stored or transported before, during, or after treatment and prior to disposal. The following subsections provide information on potential require- ments for storage and transportation of water. 5.1 Storage of Water Section 3.2 of this document discusses containment of water in temporary storage prior to disposal. If the contaminated water cannot be disposed, the water should be stored above ground until further treatment or disposal options become available. Long-term storage should be in a secure location, and detailed records should be maintained. Additional sampling and analyses may be necessary to monitor the characteristics, quality, and/or contaminant levels of the water over time. Several statutes and regulations may apply to the storage of water depending on the contaminants in the water, the characteristics of the water, and other fac- tors specific to the event. State and local jurisdictions may have additional regulations regarding long-term storage of water contaminated with chemical, biological, and radiological (CBR) agents; users should con- tact state and local authorities. EPA Requirements CHEM BIO TOXIN These statutes and regulations include: RCRA - In cases where the water is considered RCRA hazardous waste, RCRA storage regulations (40 CFR Part 264 and 265) may apply. - Storage of RCRA hazardous waste may require an EPA identification number and permits that may be required by state and local environmental and/or waste offices. Refer to Section 4.0 for information on these permits. - RCRA hazardous waste may be exempt from permitting regulations if specific requirements are met. Appendix E provides a list of exemptions from RCRA permitting regulations regarding storage. - Underground storage - UST systems that are used to store hazardous substances and/or petroleum > products are regulated under RCRA, Subtitle I. USTs containing hazardous wastes are regulated under Subtitle C of RCRA. See 40 CFR 302.4 for the regulated list of hazardous substances. FIFRA - If the water or water system was intentionally treated with a pesticide (e.g., to control bacteria), the pesticide label or labeling may impose requirements affecting storage and/or disposal. - If the contaminant in the water is a pesticide that was canceled or suspended under FIFRA, EPA may have issued, pursuant to FIFRA section 19, additional requirements and/or procedures for storage and/or disposal of the contaminated water. - The regional EPA office should be contacted to determine if there are additional requirements and/ or procedures for the canceled or suspended pesticide and to determine if those requirements and/or procedures apply to the contaminated water. 32 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities NRC Requirements RAD For water containing radiological contaminants, the NRC or Agreement State should be contacted to identify storage or labeling requirements specific to the type and amount of radioactivity at hand (Per 10 CFR 61.55 - 57). For descriptions of potential storage requirements and considerations, refer to the NRC Regulatory Issue Summary 2008 12, Considerations for Extended Interim Storage of Low Level Radioactive Waste by Fuel Cell and Materials License and/or Extended Storage of Low Level Radioactive Waste: Potential Problem Areas, BNL-NUREG-36149. (See Appendices D and F for links to these documents.) 5.2 Transportation of Water In some instances, the water may need to be transported from the contaminated site for treatment, storage, or disposal. The U.S. Department of Transportation (DOT) Hazardous Materials Regulations (HMR; 49 CFR Parts 100 - 185) provide requirements for the packaging, labeling, permitting, and transporting of hazardous materials, including chemical contaminants. For information about transportation requirements for hazard- ous materials, contact the DOT Hazardous Materials Information Line at 800-467-4922 or contact the state transportation department. States may have additional regulations, and state transportation agencies should be contacted for information regarding state-specific requirements. EPA Requirements CHEM TOXIN In addition to DOT regulations and requirements, EPA may have additional requirements for those transporting waste under: RCRA - EPA provides regulatory requirements for transporters of RCRA hazardous waste (pursuant to RCRA, 40 CFR Part 263) such as requiring an EPA identification number, hazardous waste manifest, and permits that may be required by state and local environmental and/or waste offices. FIFRA- EPA may have labeling requirements and/or procedures for transporting canceled or suspended pesticides, any container of a pesticide, any rinsate containing the pesticide, or any other material used to contain or collect excess or spilled quantities of the pesticide, which may also apply to water contaminated with a canceled or suspended pesticide. (Per FIFRA, 7USCl36q) NRC Requirements RAD The NRC works with DOT for the transportation and packaging of radioactive waste under the Hazardous Materials Regulations (HMR; 49 CFR Parts 100-185). These regulations establish requirements for the permitting, packaging, labeling, and shipping of contaminated materials. 33 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities This page has been left blank intentionally 34 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Appendix A: Risk Communication Figure A-1 describes an example framework that can be used to develop a risk communication strategy for decontamination efforts related to containment, treatment, and disposal of large amounts of water from a drinking water, wastewater, or stormwater system.27 The left-hand column depicts communication and coor- dination with federal, state, local and/or tribal agencies to notify them of the Remediation Action Plan and to coordinate the development of a public risk communication strategy. The third column illustrates aspects of the implementation of the public notification and risk communication strategy. As part of pre-incident plan- ning, it is recommended that a communication strategy be developed and contact information for federal, state, local and/or tribal agencies, health agencies, emergency responders, and public officials be collected and compiled. Resources on risk communication include: Revised Public Notification Handbook, March 2010 (EPA-816-R-09-013) - This handbook provides guid- ance to states, public water systems, and the general public regarding how EPA interprets public noti- fication regulations. This handbook also provides example "boil water" alerts and "problem corrected" notices. See EPA's public notification Web page for more details and access to the handbook: http://wat.er. epa.gov/lawsregs/rulesregs/sdwa/publicnotification/upload/PNrevisedPNHandbookMarch2010.pdf. 40 CFR 141.201, National Primary Drinking Water Regulations Subpart Q - Public Notification of Drinking Water Violations - 40 CFR 141.201 describes general public notification requirements including Tier 1 re- quirements. Water Security Initiative: Consequence Management Plan Guidance, October 2008 (EPA-817-R-08-001) This guidance document includes an example of how public information activities might be planned during each response phase of a contamination incident. See http://water.epa.gov/infrastructure/watersecurity/ upload/2008_10_24_watersecurity_guide_interim_cmp_wsi.pdf. Risk Communication in Action: The Risk Communication Workbook, August 2007 (EPA-625-R-05-003) This workbook provides a better understanding of the elements of successful risk communication to public health officials, local environmental managers and community decision makers. It describes concepts of risk communication based on perceptions, value differences, persuasion, and presentation of data in new ways. See http://nepis.epa.gov/Exe/ZyPURL.cgi?Dockey=60000l2U.txt. Risk Communication in Action: The Tools of Message Mapping, August 2007 (EPA-625-R-06-012) - This workbook provides an explanation of how to create and use message maps, which are science-based risk communication tools that enable members of the emergency response and environmental protection communities to quickly and concisely deliver the most pertinent information about an emergency. See http://nepis.epa.gov/Exe/ZyPURL.cgi?Dockey=60000IOS.txt. Effective Risk and Crisis Communication during Water Security Emergencies: Summary Report of EPA Sponsored Message Mapping Workshops, March 2007 (EPA-600-R-07-027) - This report sum- marizes results from three water security risk communication message mapping workshops. It provides information about effective message development and delivery that could be useful to Water Sector organi- zations as they develop their respective risk communication plans. See http://nepis.epa.gov/Exe/ZyPURL. cgi?Dockey=60000GH1 .txt. Summary Report of the National Water Security Risk Communication Symposium, November 2005 (EPA-600-C-05-006) - This document summarizes a two-day symposium hosted by EPA about communi- cating risks to drinking water and wastewater systems on May 20 - 21, 2004, in San Francisco, California. The Symposium provided an opportunity to inform key water security stakeholder groups about crisis risk 27 Please note that this figure illustrates an example of a drinking water communications strategy and would need to be modified appropriately for decontamination efforts at a wastewater or stormwater utility. A-1 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities communication; a forum to share effective risk communication strategies, best practices, tools, and exist- ing projects; and an opportunity to gather information and advice to support activities in developing and implementing successful risk communication strategies, tools, and plans. Sessions included risk com- munication during and following a crisis and risk communication in preparation for a potential crisis. See http://nepis. epa.gov/Exe/ZyPURL. cgi?Dockey=P100049M.txt. Response Protocol Toolbox: Planning for and Responding to Drinking Water Contamination Threats and Incidents, April 2004 (EPA 817-D-03-005 and EPA 817-D-03-006) - These modules provide emergency response planning tools that are designed to help the water sector to effectively and appropriately respond to intentional contamination threats and incidents. Module 5 introduces the concept of a comprehensive communications strategy of providing information to the public and details the message, audience, poten- tial vehicles, resources needed and feedback mechanisms. Module 6 discusses each of these elements in more detail. See http://water.epa.gov/infrastructure/watersecurity/upload/2004_05_19_watersecurity_ guide_response_module5.pdf and http://water.epa.gov/infrastructure/watersecurity/upload/2004_05_19_ watersecurity_guide_response_module6.pdf. A-2 ------- Verification of Decontamination Approach Before Public Communication c Coordinate with federal, state, local, and/or tribal agencies to verify approach before communicating with public Communications Started Priorto Decontamination Notify all applicable agencies (federal, state, local, and/or tribal, including health agencies), first responders, and public authorities Determine public health and environmental risk with state and local health departments Coordinate with WWTP(s) and other disposal options Obtain applicable permits specific to treatment Coordinate on federal, state, and local level to arrange transport Obtain permits for disposal option Coordinate with local WWTP(s) to determine feasibility of discharging to WWTP Determine feasibility of disposal to underground injection wells T Coordinate on federal, state, and local level to arrange transport, if applicable f Determine feasibility of disposal to hazardous or medical waste facility ^ Phase of Incident Response Presented in Disposal Guide B Contain ination is Confirmed * Contain and Treat In situ Temporary storage n 1 ^^P I I Discharge to surface ' | water 1 Transfer to hazardous | facility 1 Underground injection 1 Implementation of Public Notification and Risk Communication Strategy After coordinating with involved agencies and public officials to implement public notification and risk communication Communications Started Prior to Decon tarn ination Initiate public notification of contamination and Provide information on short/long term alternate water supply as appropriate Provide information on water use and safety, including "curb to faucet" f Recurring Public Com munications N Provide information on the nature of incident and treatment goals and objectives Regularly update on treatment activities Incorporate community feedback and adapt After system is restored, notify public that incident is mitigated 1 Provide follow-up information and reports to public Contact Information State Health Department Contact: Phone: Email: Local Health Department Contact: Phone: Email: Other Agencies Agency Name: Phone ' Email: Agency Name: Contact' Phone: Email: Agency Name: Contact: Phone: Email: Other Contacts (e.g., public officials and first responders) Contact: Phone: Email: Contact: Org/Title: Phone: Email: Figure A-1 : Recommended Framework for Developing a Risk Communication Strategy for a Drinking Water Utility Following a Contamination Incident 0 0 p* ainment and g a 0 o >f Large Amounts of Contarr 5 Q. I CD 73 73 O 3- O cL CD 31 i CD" CD' t/i ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Appendix B: Risk Communication In some situations, the contaminant may degrade over time in the water, resulting in natural attenuation. The likelihood of natural attenuation depends on the characteristics of the contaminant, such as tendency to hy- drolyze; water quality aspects including acidity/alkalinity, temperature, presence of other contaminants; and exposure of contaminated water to environmental stressors such as sunlight, wind, and freeze-thaw cycles. Natural attenuation may require extended holding times and may result in byproducts of toxicological sig- nificance, for example from hydrolysis (see Table B-2) or other natural processes. Water that has undergone natural attenuation should be treated and/or disposed in accordance with applicable statutory and regula- tory requirements. The likelihood of a contaminant to naturally attenuate should also be considered when choosing and implementing a treatment method. Tables B1 - B3 provide information on potential treatment methods. These tables can be used to help identify which treatment methods may be appropriate in different circumstances. Table B-1 provides method descriptions and specific considerations for potential treatment options identified in Tables 3-3 through 3-6 that may be used to treat water contaminated with chemical, biological, or radiologi- cal (CBR) agents. This table does not address disposal of treatment residuals. Table B-2 lists some of the potential hydrolysis products that may result from the representative contami- nants listed in this guide. These products vary in toxicological significance. For example, hydrolysis products of lewisite and VX can have similar, high acute toxicity as the parent compounds. Hydrolysis products with much lower acute toxicity may be present as well; however, all need to be considered in order to protect hu- man health and ensure effective treatment. Many of the example hydrolysis products identified in Table B-2 may have non-lethal human health effects, depending on dose and duration of exposure. Table B-2 is not an exhaustive list. Rather, the entries in the table are designed to illustrate that hydrolysis products may be of concern in certain circumstances, and should be considered when devising a treatment plan. Consult the Water Contaminant Information Tool (WCIT) for more information on other potential hydrolysis products. EPA Cumulative Risk Assessments also provide information on toxicologically significant hydrolysis products for several classes of pesticides (http://www.epa.gov/oppsrrd1/cumulative/). Table B-3 provides information on byproducts resulting from several potential treatment methods, along with some treatment process residuals (e.g., treatment chemicals added in excess). The considerations listed in Table B-1 indicate the formation of these byproducts for various treatment processes. Table B-3 provides some specific, illustrative examples for several chemicals. Table B-3 is not an exhaustive list, but is primarily intended to raise awareness of specific types of treatment byproducts beyond what is well known in the water industry regarding regulated "disinfection byproducts" such as trihalomethanes and haloacetic acids. Users are encouraged to obtain updated and more detailed information from EPA's WCIT. EPA Cumulative Risk As- sessments also provide information on toxicologically significant treatment byproducts for several classes of pesticides (http://www.epa.gov/oppsrrd1/cumulative/). While many natural attenuation, hydrolysis, and treatment products may be treated the same way as the par- ent contaminant, additional treatment technology may be required to remove such byproducts, as illustrated in Table B-3. B-1 ------- Table B-1: Description of Potential Treatment Methods for CBR Contaminants Treatment Method Activated alumina Method Description 1 Adsorption of contaminant is facilitated by the porous nature of activated alumina. Considerations and Notes 1 Residuals may include backwash water, caustic regenerant solution, neutralization water, and rinse water containing high levels of the con- taminant. o o ff 3 3 CD a 03 3 Q q 55' a o M 03 1Q CD > O £ p* to s, o o a 03 3 5' D) C? Q. I CD CO c 73 73 O 3- Q c ci CD Activated sludge 1 Microorganisms and air (oxygen) are added to the water to consume organic material. 1 Radionuclides are consumed with organic material. 1 Resulting sludge is settled or filtered out of the water. Residuals may include contaminated sludge. Biosorption Metal ions and/or organic compounds are removed by microorganisms. Microorganisms settle or are filtered out. Residuals may include contaminated sludge. Booms 1 Floating oil is concentrated in thicker sur- face layers, making recovery easier. Recommended for use in holding tanks/storage areas, not within pipes. Recommended for use in conjunction with additional removal process- es. Chloramination 1 Chlorine (or hypochlorite) and ammonia are combined in water to form monochloramine, which inactivates microorganisms in the water and may also affect some chemical contaminants. 1 Treatment chemical mixture may be considered a pesticide and may require special handling. 1 Disinfection byproducts or liquid residuals may be produced; these byproducts or residuals may result in negative human health effects. 1 Residuals include chloraminated water. 1 If off-label use of a registered pesticide, or use of an unregistered pes- ticide, is contemplated, an exemption from FIFRA (Sec. 18) must be obtained. £ CD" CD' t/i 00 NJ ------- Treatment Method Chlorination Method Description 1 Chlorine or hypochlorite is added to water to obtain desired concentration and contact time. 1 The free chlorine interacts with the contaminant(s) for treatment. Considerations and Notes 1 Residuals include chlorinated water. 1 Method may result in the production of disinfection byproducts or liquid residuals, such as trihalomethanes (THMs) and haloacetic acids (HAAs), which may themselves result in negative human health effects. 1 Most vegetative bacteria are susceptible to free chlorine. 1 Some spore-forming bacteria, such as B. anthracis, and many proto- zoa, may be more resistant to chlorine. However, it may be possible to use high doses of chlorine (compared to normal treatment) to inacti- vate resistant organisms. 1 When using chlorine, increased concentrations and/or contact times may be required for the treatment of chlorine-resistant organisms. 1 Treatment chemical mixture may be considered a pesticide and may require special handling. 1 If off-label use of a registered pesticide, or use of an unregistered pesticide, is contemplated, an exemption from FIFRA (Sec.18) must be obtained. Microorganisms are inactivated through oxidation (by chlorine dioxide or sodium chlorite). Chlorine dioxide 1 Chlorite and chlorate ions may be formed, which may require addi- tional processing to mitigate them prior to disposal; however, formation of these ions will be minimized by proper use of chlorine dioxide. 1 If off-label use of a registered pesticide, or use of an unregistered pesticide, is contemplated, an exemption from FIFRA (Sec.18) must be obtained. 1 Disinfection byproducts or liquid residuals may be produced; these byproducts and residuals may result in negative human health effects. Coagulants or flocculants (e.g., alum coagulation) 1A coagulant is added to the water, causing particles to clump together. 1 Repulsion forces between contaminant molecules are neutralized, allowing forma- tion of complexes that can be more readily removed from water. Method is often used as an initial treatment, prior to filtration or sorbent methods. Co-precipitation with barium sulfate 1 Radioactive strontium is adsorbed on barium sulfate precipitate, and has been used for modeling of the decontamination process in continuous and semi-continuous stirred tank reactors. 1 Through simulations, it has been found that the critical parameter is the mean residence time, and the semi-bath stirred tank reactor is the best configuration. oo CO ------- Treatment Method Electrodialysis/ reversal (EDR) Method Description Ions of elements are extracted by a mercury cathode, creating a mercury mixture that causes a separation of contaminated mate- rials from the waste volume. Considerations and Notes ^H Additional processing is required for mercury mixture. 1 Water is passed through a filter and the con- taminant particles become trapped on one side of the filter. Filtration 1 Residuals include sand beds and other spent filters with high concen- trations of contaminants. 1 Filter should be chosen based on physical and chemical properties of the contaminant. 1 Filters may be fouled quickly, depending on the surface area of the filter and extent of the contamination. 1 Speed of treatment may be dictated by type of filter employed. 1 Large-scale filtration may be problematic, in terms of time and cost, for some contaminants. Hydrogen peroxide 1 Hydrogen peroxide is added to water to ob- tain desired concentration and contact time in order to treat the contaminant. 1 The pH of the water may be decreased by treatment. 1 Disinfection byproducts or liquid residuals may be produced; these byproducts or residuals may result in negative human health effects. Hydrous manganese oxide 1 The contamination becomes surrounded by oxygen atoms and is removed through an ion exchange. Intraparticle diffusion is the rate-limiting step in the sorption of contami- nant to microporous oxides. Ion exchange (e.g., greensand) 1 Water is passed through a resin containing exchangeable ions (cations, anions, or a mixture of the two). 1 The ions on the resin are replaced by con- taminants since they form stronger bonds. 1 Stronger bonds must be formed between the contaminant and resin than the exchangeable ion. 1 Effectiveness of treatment can be limited by other ions, such as sulfate, calcium and magnesium. 1 Residuals may include brine, backwash, rinse water, and aged/ineffec- tive resins. 1 Hydrated lime or quicklime is added to the water to precipitate the contaminant. Lime softening 1 Residuals may include backwash, sludge, and aged media. 1 Corrosivity of the water may be altered by the treatment, and a corro- sion-inhibiting material may need to be added to the water. 1 Disinfection byproducts or liquid residuals may be produced; these byproducts and residuals may themselves result in negative human health effects. 1 Contaminants' hydrolysis rates can be altered by lime softening (see Appendix B, Table B-3). CD ------- Treatment Method Magnetic polyamine epichlorhydrin resin Method Description 1 Magnetic polymer composition is placed in water in the presence of an external mag- netic field. Considerations and Notes Residuals may include spent, contaminated resins. Oil-water separators 1 Water is pumped through a separation tank; hydrophobic contaminants rise to the top or settle to the bottom of the water column, al- lowing removal of the contaminant from the water. 1 Method works well when the contaminant rises to the top or settles to the bottom of the water column. May not be effective if the contaminant is dispersed throughout the water column. 1 Oil is effectively removed from heavily contaminated waters; may not reduce the oil level to an adequate level for discharge. Ozone Ozone is infused into water via ozone gen- erators. 1 Disinfection byproducts or liquid residuals may be produced; these byproducts and residuals may result in negative human health effects. 1 Bromate is a regulated byproduct of the ozonation reaction, and is formed regardless of contaminant concentration if the water contains bromide. 1 Flow should be monitored carefully to ensure sufficient contact time. Particle separation and Magnetic separation Metal ions and radionuclides are selectively bound on the surface of magnetic and non- magnetic particles. Particles are filtered or applied to a mag- netic field. Residuals may include contaminated particles and filters. Photocatalytic oxidation 1 Organic contaminants are mineralized, con- verting them into carbon dioxide, water, and the oxidized inorganic anions of any hetero- atoms present. Disinfection byproducts or liquid residuals may be produced; these byproducts and residuals may result in negative human health effects. Precipitation 1 Water flow is reduced and/or chemicals are introduced so that contaminants can precipitate. 1 Precipitant is settled out of the water or is filtered out. Residuals may include contaminated precipitants. CD' t/1 CD A. ------- Treatment Method Reverse osmosis Method Description Water is forced through a membrane with small pores, achieving a pressure-driven membrane separation process. The contaminant is unable to pass through the pores, separating it from the water. Considerations and Notes 1 Membrane fouling or scaling can be caused by hard water. 1 Treated water may have decreased pH. 1 Residuals may include spent/used membranes, and liquid residuals with high concentrations of the contaminant. Skimmers Floating oil is removed from water by physi- cal separation, suction or absorptive materi- als. Recommended for use in holding tanks/storage areas, not within pipes. Sorbents (e.g., granular activated carbon [GAC]) 1 Insoluble materials or mixtures of materials are used to recover liquids through absorp- tion, adsorption (adherence), or both. 1 Hydrophobic contaminants are bound to GAC, enabling physical removal from the water. 1 Method is often used to remove final traces of oil from water. 1 Characteristics of sorbent and contaminant should be considered to optimize treatment. 1 GAC is identified as the best available technology in the National Primary Drinking Water implementation regulation (40 CFR 142.62) for treatment of many synthetic organics, including chlordane and various pesticides. 1 Residual GAC may be a RCRA hazardous waste or CERCLA hazard- ous substance. Supercritical water oxidation 1 Temperature and pressure of the water are raised to be above critical point in order for oxidation to occur. 1 Additional treatment methods may be necessary for precipitates formed during supercritical water oxidation. 1 Disinfection byproducts or liquid residuals may be produced; these byproducts and residuals may result in negative human health effects. 1 Water is passed through UV stream, inacti- vating microorganisms. UV 1 Photochemical transformation by this process has been observed. 1 Disinfection byproducts or liquid residuals may be produced; these byproducts and residuals may result in negative human health effects. 1 Flow should be monitored carefully to ensure sufficient contact time. 1 Efficacy of treatment may decrease for water with high turbidity or high suspended solids. CD' t/1 CD ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Table B-2: Potential Hydrolysis Products from Chemical Contaminants4 Benzyilic acid 3-quinuclidinol Carbofuran phenol Dichloroacetaldehyde Dichloroacetic acid Dichloroethanol Dimethyl phosphate Dimethyl phosphoric acid O-desmethyldicrotophos N,N-dimethylacetoacetamide Monocrotophos 2-Chlorovinyl arsonous acid Lewisite oxide Dnsopropyl methylphosphonic acid Hydrogen fluoride Isopropyl methylphosphonic acid Methylphosphonic acid Methylphosphonic acid mono(1 -methylethyl) ester (IMPA) Methylphosphonofluondic acid Cyanide compounds Dimethylamine Dimethylphosphamide Dimethylphosphoramidic acid D-ethyldimethylamide phosphoric acid Ethyl phosphoric acid Ethylphosphoryl cyanidate Phosphoric acid Dnsopropyl ethyl mercaptoamme Ethyl methylphosphonic acid Methylphosphonic acid * Note that this table does not contain all potential hydrolysis products. Consult WCIT for more infor- mation on other potential hydrolysis products. EPA Cumulative Risk Assessment provides informa- tion on toxicologically significant hydrolysis products for several classes of pesticides (http://www. epa.gov/oppsrrd1/cumulative/). B-7 ------- Table B-3: Potential Treatment Byproducts and Treatment Process Residuals* Treatment Method Free chlorine Byproducts Oxons, sulfoxides, sulfones Regulated disinfection byproducts (DBPs) Byproduct Notes Examples include aldicarb sulfoxide, aldicarb sulfone, methyl paraoxon, phorate sulfoxide, etc. Include trihalomethanes and haloacetic acids Treatment Process Residual Free Chlorine Treatment process for byproducts and residual Byproducts - activated carbon, filtration, ozonation, etc. Residuals - dechlorination agents, reducing agents, etc. Regulated DBFs - formation control, reverse osmosis o o I. 5' 3 CD p* D) Q. CO a o to Q> D) 1Q CD 3 o 3 e/T 2, I c? T3 73 O Q c OL CD Ozone Oxons, sulfoxides, sulfones Regulated DBPs Examples similar to free chlorine. All oxidative process may form these byproducts to varying degrees. Bromate will be formed if the water contains bromide Byproducts - activated carbon, filtration, ozonation, etc. Regulated DBPs - formation control, reverse osmosis Reverse Osmosis Hydrolysis products pH change from process may affect hydrolysis mechanisms and corresponding products; e.g. for organophosphates Residuals may include spent/used membranes, and liquid residuals with high concentrations of the contaminant. High concentration of contaminants may cause waste to be subject to additional regulations and/or more difficult to deal with. * Note that this table does not contain all potential treatment byproducts or residuals. Additionally, while many byproducts may be treated as described in Table B-1, the treatment technology for the residuals may be different than the technique needed to treat the original contaminant. EPA Cumulative Risk Assessments provide information on toxicologically significant treatment byproducts for several classes of pesticides (http://www.epa.gov/oppsrrd1/cumulative/). CD i c CD t/i CD oo ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Appendix C: Sample Disposal Checklist Disclaimer: This sample checklist addresses potential actions to contain, treat, and/or dispose of contaminated water resulting from a CBR incident in a drinking water, wastewater, and/or stormwater system and some of the potentially applicable statutory and regulatory requirements. Utilities, state agencies, and first responders may elect to create a site-specific checklist to ensure all actions are documented and performed appropriately. Contamination Incident and Site Background Information General Information: Name(s) of utility or entity affected (if known): Responsible Party (if known): Date and Time of the Incident: Type of Incident (e.g., explosion, vehicle accident, pipeline, intentional): Systems affected (check all that apply): Contamination of drinking water distribution system Contamination of wastewater system Contamination of stormwater collection system Other Contamination Location: _Public notification has been implemented or addressed (e.g., radio broadcast, safety zone broadcast to mariners, road closure, etc.) Contaminant Information: Type: Biological contaminant(s): Toxin contaminant(s): _Chemical contaminant(s): _Radiological contaminant(s): Other: C-1 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Details (if applicable): Contaminant Name Viscosity: Solubility: Volatility: Percent Evaporation in: 24 Hours - Other details: 48 Hours - gals Estimated volume of contaminated water: Release status: Instantaneous Continuous Intermittent bbls If continuous or intermittent, specify rate of release: Estimated surface area covered (if applicable): _gals/bbls per hour acres/sq ft Contact Information Name Organization Phone Number C-2 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Step 1: Evaluating the Potential to Contain Contaminated Water for Treatment Where is the water contained? (Please note: A hydraulic map of the contaminated water system may facilitate identifying potential locations of contamination within the system to aid containment.) _Before the drinking water system _Within the drinking water system _Within the wastewater system _Temporary storage _Within the stormwater system If stored in temporary storage, what types of container(s) are used (check all that apply)? _Drums (size: number: ) Holding tanks (size: Truck tankers (size: Railway tanks (size: Holding ponds (size: Other ( number: } number: } number: } number: } ) (size: number: Step 2: Treatment of Water Operations Prior to Treatment: Water profile evaluation completed Notes on water profile: Turbidity Alkalinity Laboratory used (if applicable) Other Temperature Hardness _Clearance goals established _ Remediation Action Plan developed _Clearance sampling and analysis plan developed C-3 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Notes on clearance goals and sampling and analysis plan: Treatment method(s) selected Have samples been collected and monitored for natural attenuation or hydrolysis (if applicable)? Yes No Operations after Treatment: Treatment confirmed (i.e., water meets clearance goals) Notes on analysis after treatment: Analysis method used Laboratory used (if applicable) If treatment is not confirmed, conduct additional treatment (list methods above). Step 3: Assessment of Water after Treatment Does the water contain any of the following (check all that apply): Warfare agent(s) RCRA hazardous waste _TSCA regulated substance _Radioactivity (LLRW) _Cancelled or suspended pesticide _Mixed waste (LLMW) In addition to the requirements under the Clean Water Act and the Safe Drinking Water Act, there may be ad- ditional requirements that are applicable to the disposal of water with the following characteristics to surface waters or underground injection control wells, depending on the particular characteristics of the contami- nated water (check those that apply in this situation): C-4 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Characteristic Warfare agent(s) Requirements _Clean Water Act Section 301 (f) prohibits discharge of warfare agents to navigable waters TSCA regulated substance _TSCA disposal requirements Contaminant specific requirements Radioactivity (LLRW) _NRC requirements for storage _NRC requirements for disposal RCRA hazardous waste _RCRA hazardous waste requirements for transportation _RCRA hazardous waste requirements for storage _RCRA hazardous waste requirements for disposal Cancelled or suspended pesticide _FIFRA storage requirements or procedures _FIFRA labeling requirements or procedures _FIFRA disposal requirements or procedures Contaminant specific requirements Mixed waste (LLMW) _NRC requirements for storage _NRC requirements for disposal _RCRA hazardous waste requirements for transportation _RCRA hazardous waste requirements for storage _RCRA hazardous waste requirements for disposal Oil _Clean Water Act Section 311 (b) and 40 CFR Part 110 prohibit discharge of oil to navigable waters Step 4: Disposal of Water28 Direct Discharge to Surface Water: Check once completed/verified. Location of discharge identified 28 May also apply to the disposal of liquid residuals. C-5 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities _NPDES and other appropriate permits for discharge obtained _Water does not contain any biological, chemical, or radiological warfare agents, High Level Radioactive Waste (HLRW), medical waste, or oil Disposal of Water through a WWTP (POTW, FOTW, CWT, or Other): Check once completed/verified. Water meets federal, state, and local pretreatment program standards (if applicable) No pollutants in the water will pass through the WWTP untreated Water will not cause interferences with WWTP (i.e., inhibition or disruption of WWTP treatment process or operations or sludge process, use, or disposal) WWTP has agreed to accept the water WWTP has issued/revised a permit for the discharge Underground Injection: Check once completed/verified. Underground injection disposal located Well owner(s)/well operator(s) have the appropriate permit(s) and will accept the water Injection meets federal and state UIC requirements including the prohibition of movement of fluid con- taining any contaminant into underground sources of drinking water (40 CFR 144.12) Volume Reduction and Solidification (radiological contaminants only): Check all that apply. Feasible to solidify the water (at current amount) Feasible to reduce volume of water Disposal at a Hazardous or Medical/Infectious Waste Facility (chemical, biological, and toxin contaminants): Check all that apply. Water qualifies for disposal at a hazardous or medical/infectious waste facility Hazardous or medical/infectious waste facility agrees to accept water Public Notifications: Press releases, other communication strategies and/or other public notification requirements have been employed to notify affected public of any public health risks associated with disposal C-6 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Step 5: Storage of Water Regulatory Requirements Check all that apply. Water is considered a RCRA hazardous waste Does storage of water qualify for an exemption from RCRA permitting requirement? (If no, obtain per- mit; if yes, contact state or regional EPA hazardous waste office to identify actions necessary to maintain the exemption.) Storage Parameters: Check once completed. Storage area and/or containers approved by the authorities such as NRC or EPA (if applicable) Storage containers and facilities labeled appropriately Proper security measures implemented around storage area Public Notifications: Press releases or other communication strategies employed to notify affected public of any public health risks Step 6: Transportation of Water Operational Controls: Check once completed. Receiving entity (e.g., hazardous waste facility) agreed to accept waste and approved method of transport All required tracking forms, manifests, etc., obtained and filled out _AII federal, state, and local transportation authorities have approved the method and route of transport Public Notifications: Public notification implemented or addressed to facilitate safe transportation of water (e.g., safety zone broadcast to mariners, road closure, and other DOT requirements) C-7 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Appendix D: Resources Resources for treatment, storage, transportation, and disposal are presented in the following tables: Table D-1: General Resources Table D-2: Disposal Resources Table D-3: Storage Resources Table D-4: Transport Resources Table D-5: Information on Disposal of Solids Table D-1: General Resources Agency-wide Documents Access and Management System (ADAMS) This database provides access to all public documents published by the NRC since November 1, 1999, as well as bibliographic records for public documents published by the NRC before November 1999. ADAMS is both Web-based and Citrix-based. ADAMS permits full-text searching and enables users to view document images as well as download and print files. See http://www.nrc.gov/reading-rm/adams. html to access the tool. Agency for Toxic Substances and Disease Registry (ATSDR) ATSDR provides useful information for substances not found in the EPA WCIT. See http://www.atsdr.cdc.gov/. Biosafety in Microbiological and Biomedical Laboratories 5th edition, December 2009 This manual explains biosafety procedures for laboratories and provides biosafety level (BSL) definitions. See HHS Publication No. (CDC) 21-1112, http://www.cdc.gov/biosafety/publications/bmbl5/ index.htm. CERCLA/Superfund Orientation Manual, October 1992 This document describes the Superfund program. See EPA publication EPA-542-R-92-005, http://nepis.epa.gov/Exe/ZyPURL. cgi?Dockey=10002WV5.txt. Communicating Radiation Risks, September 2007 The guide has been designed as a resource for emergency responders and federal, state, and local officials communicating with the public and the media during a radiological crisis. See EPA-402-F-07-008. See http://nepis.epa.gov/Exe/ZyPURL. cgi?Dockey=500025HA.txt. Criminal and Epidemiological Investigation Handbook, 2006 This handbook explains the steps of a criminal investigation following an attack with a biological contaminant (DOJ, FBI, and U.S. Army Soldier Biological Chemical Command). D-1 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Effective Risk and Crisis Communication during Water Security Emergencies: Sum- mary Report of EPA Sponsored Message Mapping Workshops, March 2007 This report summarizes results from three water security risk communication message mapping workshops. It provides information about effective message development and delivery that could be useful to Water Sector organizations as they develop their respective risk communication plans. See EPA publication EPA-600-R-07-027, http://nepis.epa.gov/Exe/ZyPURL.cgi?Dockey=60000GH1.txt. Guidance on PCBs This website provides a list of guidance documents related to PCB response, removal, and other regulations. See http://www.epa.gov/ wastes/h azard/tsd/pcbs/p u bs/g u id an ce. htm. Health and Safety Plans (HASPs) An electronic expert software system (developed by EPA and OSHA) is available at: http://www.osha.gov/dep/etools/ehasp/index.html. Incident Waste Decision Support Tool A decision support tool that organizes large amounts of information related to managing waste resulting from incidents of national significance (e.g., contaminated buildings and natural disasters). The tool can be used by individuals (i.e., emergency response authorities and property owners; tribal, state, and local permitting agencies; treatment and disposal managers; and/or planners) responsible for making disposal decisions. See http://www2.ergweb.com/bdrtool (registration required). Joint NRC/EPA Guidance on Testing Requirements for Mixed Radioactive and Hazardous Waste, November 1997 NRC and EPA's joint final guidance on the testing requirements for mixed waste. See Federal Register Notice (62 FR 224. November 20, 1997), https://www.federalregister.gov/articles/1997/11 /20/97-30528/ joint-nrcepa-guidance-on-testing-requirements-for-mixed-radioactive- and-hazardous-waste. National Primary Drinking Water Regulations SDWA regulations (40 CFR Part 141) set mandatory water quality standards for drinking water contaminants. More information is available at: http://water.epa.gov/drink/drink/contaminants/index.cfm. A list of the standards can be found at http://water.epa.gov/drink/ standardriskmanagement.cfm. Oil Spill Response Techniques This website provides information on oil spill response techniques including booms, skimmers, and sorbents. See http://www.epa.gov/ OEM/content/learni ng/oi Itech. htm. Planning for Decontamination Wastewater: A Guide for Utilities, 2005 This guide informs wastewater utility personnel of the pre-planning necessary to prevent, detect, respond to and/or recover from the impacts of decontamination wastewater containing CBR substances. See http://www.michigan.gov/documents/deq/deq-wb-wws- 2005WWDeconGuide_271352_7.pdf. Radionuclides Compliance Help This document describes the treatment and non-treatment options for radionuclides in water as well as discusses disposal issues. See http:// www.epa.gov/ogwdw/radionuclides/pdfs/learn.pdf. RCRA Online The RCRA Online database is designed to enable users to locate documents, including publications and other outreach materials, which cover a wide range of RCRA issues and topics. See http://www. epa.gov/waste/inforesources/online/index.htm. D-2 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Response Protocol Tool box (RPTB): Planning for and Responding to Drinking Water Contamination Threats and Incidents, April 2004 The RPTB is composed of six interrelated modules that focus on different aspects of planning a response to contamination threats and incidents. Remediation and Recovery Guide - Module 6. See EPA publication EPA-817-D-03-006, http://water.epa.gov/infrastructure/ watersecurity/upload/2004_05_19_watersecurity_guide_response_ module6.pdf. Response Protocol Toolbox: Response Guidelines, August 2004 An action-oriented document to assist drinking water utilities, laboratories, emergency responders, state drinking water programs, technical assistance providers, and public health and law enforcement officials during the management of an ongoing contamination threat or incident. See EPA publication EPA 817-D-04-001, http://water.epa. gov/infrastructure/watersecurity/upload/2004_11_24_rptb_response_ guidelines.pdf. Revised Public Notification Handbook, March 2010 This handbook provides guidance to states, public water systems, and the general public regarding how EPA interprets public notification regulations. See EPA's public notification Web page for more details and access to the handbook: http://water.epa.gov/lawsregs/rulesregs/ sdwa/publicnotification/upload/PNrevisedPNHandbookMarch2010. pdf; (EPA publication EPA-816-R-09-013). Risk Communication in Action: The Risk Communication Workbook, August 2007 This workbook provides a better understanding of the elements of successful risk communication to public health officials, local environmental managers, and community decision makers. It describes concepts of risk communication based on perceptions, value differences, persuasion and presentation of data in new ways. See EPA publication EPA-625-R-05-003, http://nepis.epa.gov/Exe/ ZyPURL.cgi?Dockey=60000l2U.txt Risk Communication in Action: The Tools of Message Mapping, August 2007 This workbook provides an explanation of how to create and use message maps, which are science-based risk communication tools that enable members of the emergency response and environmental protection communities to quickly and concisely deliver the most pertinent information about an emergency. See EPA publication EPA-625-R-06-012, http://nepis.epa.gov/Exe/ZyPURL. eg i?Dockey=60000I OS .txt. Safe Drinking Water Hotline The Safe Drinking Water Hotline provides the general public, regulators, medical and water professionals, academia, and media, with information about drinking water and ground water programs authorized under the Safe Drinking Water Act. Call 1-800-426-4791 for a point of contact for drinking water information. Also see http://wat.er. epa.gov/drink/hotline/index.cfm for more information about the hotline. D-3 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Sampling Guidance for Unknown Contaminants in Drinking Water, November 2008 This document provides comprehensive guidance that integrates recommendations for pathogen, toxin, chemical, and radiochemical sample collection, preservation, and transport procedures to support multiple analytical approaches for the detection and identification of potential contaminants in drinking water. This guidance document can be used to supplement a drinking water utility's emergency response plan by providing detailed recommended sampling procedures for use by utility personnel in response to a potential contamination event. See EPA publication EPA-817-R-08-003, http://water.epa.gov/ infrastructure/watersecurity/wla/upload/2008_12_31_watersecurity_ pubs_guide_watersecurity_samplingforunknown.pdf. Standardized Analyti- cal Methods for Envi- ronmental Restoration Following Homeland Security Events (SAM) This resource identifies analytical methods to be used by laboratories tasked with performing analyses of environmental samples following a homeland security event. See http://www.epa.gov/sam/ sam2010_9302010.pdf. Companion documents that discuss related issues (e.g., sampling) can be found at http://www.epa.gov/sam/ samcomp.htm. Storage, Treatment, Transportation, and Disposal of Mixed Waste; Final Rule (40 CFR Part 266) This final rule provides guidance on a conditional exemption for LLMW. See http://www.gpo.gov/fdsys/pkg/FR-2001 -05-16/pdf/01 -11408.pdf. Summary Report of the National Water Security Risk Communication Symposium, November 2005 This document summarizes a 2-day symposium hosted by EPA about communicating risks to drinking and wastewater systems on May 20 21, 2004, in San Francisco, California. The Symposium provided an opportunity to inform key water security stakeholder groups about crisis risk communication; a forum to share effective risk communication strategies, best practices, tools, and existing projects; and an opportunity to gather information and advice to support activities in developing and implementing successful risk communication strategies, tools, and plans. Sessions included risk communication during and following a crisis and risk communication in preparation for a potential crisis. See EPA publication EPA-600-C-05-006, http://nepis.epa.gov/Exe/ZyPURL. cgi?Dockey=P100049M.txt. Technical Guide 188: U.S. Army Food and Water Vulnerability Assessment Guide, July 2008 Technical guide for conducting a water vulnerability assessment (U.S. Army Public Health Command [USAPHC]). The July 2008 revision is available for official use by contacting USAPHC at http://www.med. navy.mil/sites/nepmu2/Documents/environmental_health/TG%20 188%20Food%20and%20Water%20Vulnerability%20Assessment%20 Guide.pdf. Water Contaminant Information Tool (WCIT) A secure, online database that provides information on chemical, biological, and radiological contaminants of concern for water security. Also can be used as a resource for contaminant-specific detailed information on the effectiveness of treatment methods for drinking water and wastewater. WCIT was updated in 2010 to include analytical methods data from the National Environmental Methods Index for Chemical, Biological, and Radiological Methods. See http://www.epa. gov/wcit/ (registration required). D-4 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Resource I Fri n < Description 0 F oc Water Laboratory Alliance Worker Safety Radionuclides Web Cast, 2004 The Water Laboratory Alliance (WLA) provides the drinking water sector with an integrated nationwide network of laboratories with the analytical capability and capacity to respond to intentional and unintentional drinking water contamination events involving chemical, biological, and radiochemical contaminants. See http://water.epa.gov/ infrastructure/watersecurity/wla/index.cfm. EPA's Office of Ground Water and Drinking Water conducted five on-site Radionuclides Implementation Workshops in the spring of 2007 (http://water.epa.gov/lawsregs/rulesregs/sdwa/radionuclides/ training. cfm). The training sessions were intended for state drinking water program and radiation program personnel, but were also open to technical assistance providers and system operators. Although rule requirements were reviewed, the focus of the workshops was on treatment technologies and residual disposal options and regulations. At the training, a presentation (dated 2004) was used, see http://www. epa.gov/safewater/radionuclides/pdfs/webcast/presentations/worker_ safety_loren_setlow.pdf. D-5 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Table D-2: Disposal Resources Guidance Manual for the Control of Wastes Hauled to Publicly Owned Treatment Works, September 1999 Provides information for smaller POTWs, generally those without pretreatment programs, on how to develop and implement hauled waste controls. See EPA publication EPA-833-B-98-003, http://water.epa.gov/aboutow/owm/ upload/2005_07_14_hwfinal.pdf. Guidance Manual for the Identification of Hazardous Waste Delivered to POTWs by Truck, Rail or Dedicated Pipe, June 1987 Guidance to EPA regions and states on how to identify POTWs that receive hazardous wastes by truck, rail, or dedicated pipe, and what requirements to impose on those POTWs. See http:// www.epa.gov/npdes/pubs/owm0190.pdf. Guide to Discharging CERCLA Aqueous Wastes to Publicly Owned Treatment Works, March 1991 Describes the process and regulations for discharging CERCLA wastes to POTWs in greater detail. See EPA publication 9330.2- 13FS, http://www.epa.gov/superfund/policy/remedy/pdfs/93- 30213fs-s.pdf. National Pollutant Discharge Elimination System (NPDES) Program Information about the EPA discharge permit program can be found at http://cfpub.epa.gov/npdes/home.cfm?program_ id=45. Radioactive Waste Streams: Waste Classification for Disposal, Congressional Research Service (CRS) Report to Congress, December 2006 Information on the classification of LLRW is found at http://www. fas.org/sgp/crs/misc/RL32163.pdf, (CRS Order Code RL32163). Stabilization/ Solidification Processes for Mixed Waste, June 1996 The document explains how to solidify mixed waste. See EPA publication EPA 402-R-96-014, http://nepis.epa.gov/Exe/ ZyPURL.cgi?Dockey=P10094M5.txt. A System's Guide to the Identification and Disposal of Hazardous and Non-Hazardous Water Treatment Plant Residuals, August 2006 RCRA hazardous waste regulations are summarized in this document. See EPA publication EPA 816-F-06-011, http://wat.er. epa.gov/drink/info/arsenic/upload/2006_09_14_arsenic_guide_ arsenic_disposalhazardous-nonhazardous.pdf. Underground Injection Control (UIC) Program EPA established regulations for UIC pursuant to Section 1421 of SDWA. Those regulations are at 40 CFR Parts 144-148. States may have more stringent requirements. See http://water.epa. gov/type/groundwater/uic/index.cfm for more information about EPA's UIC program. D-6 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Table D-3: Storage Resources Considerations for Extended Interim Storage of Low-Level Radioactive Waste by Fuel Cycle and Materials Licensees, May 2008 EPA training module: Introduction to Containers, September 2005 EPA training module: Introduction to Land Disposal Restrictions, September 2005 Large Quantity Generators (LQG) The NRC issued this regulatory issue summary (NRC Regulatory Issue Summary 2008-12) to address considerations related to extended interim storage of low-level radioactive waste. See http://www.nrc.gov/reading-rm/doc-collections/gen- comm/reg-issues/2008/ris-08-1 2.pdf. Provides basic requirements that pertain to the management of hazardous waste containers and regulations governing residues of hazardous waste in empty containers. See EPA publication EPA-530-K-05-01 0, http://nepis.epa.gov/Exe/ZyPURL. cgi?Dockey=P1 008KG6.txt. Provides an overview of the requirements for RCRA land disposal restrictions. See EPA publication EPA-530-K-05-01 4, http://nepis. epa.gov/Exe/ZyPURL. cgi?Dockey= P1009IJ2.txt. Those generating more than 2,200 Ibs hazardous waste or 2.2 Ibs acute hazardous waste per calendar month are subject to additional RCRA regulations. To determine if you are a large quantity generator, refer to the EPA chart at: http://www.epa. gov/solidwaste/hazard/generation/summary.htm. D-7 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Table D-4: Transport Resources Department of Energy (DOE) Transportation Routing Analysis Geographic Information System (IRAQIS) The Transportation Routing Analysis Geographic Information System (TRAGIS) model is used to calculate highway, rail, or waterway routes within the U.S. and therefore helps identify a transportation mode and route. Department of Transportation (DOT) Hazardous Materials Information Line For answers to questions regarding transportation of hazardous materials, call 800-467-4922. Hazardous Waste Manifest System To obtain EPA Uniform Hazardous Waste Manifest Form 8700- 22 visit http://www.epa.gov/wastes/hazard/transportation/ manifest/pdf/newform.pdf or contact the state hazardous waste office. See http://www.epa.gov/waste/hazard/transportation/ manifest/index.htm for more information about the program. National HAZMAT (Hazardous Materials) Route Registry (NHMRR) The NHMRR provides access to a national repository of both hazardous materials routes that are either designated for HAZMAT transportation or restricted from use by HAZMAT carriers. See http://www.fmcsa.dot.gov/safety-security/hazmat/ national-hazmat-Route.aspx. Nuclear Regulatory Commission (NRC) Transportation Requirements The following website provides access to NRC regulatory guides including those with transportation requirements: http://www.nrc.gov/reading-rm/doc-collections/reg-guides/ transportation/rg/. Pipeline and Hazardous Materials Safety Administration (PHMSA) PHMSA works to protect the American public and the environment by ensuring the safe and secure movement of hazardous materials to industry and consumers by all transportation modes, including the nation's pipelines. Call 202-366-4535 or see http://phmsa.dot.gov/hazmat/regs/sp-a/ special-permits. SafeStat (short for Motor Carrier Safety Status Measurement System) SafeStat is an automated, data driven analysis system designed by the Federal Motor Carrier Safety Administration (FMCSA). Combines current and historical carrier-based safety performance information to measure the relative (peer-to- peer) safety fitness of interstate commercial motor carriers and intrastate commercial motor carriers that transport hazardous materials. See http://ai.fmcsa.dot.gov/SMS/. State Manifest Requirements This EPA website provides links to the state program websites or contacts for the state hazardous waste manifest program. See http://www.epa.gov/epawaste/hazard/transportation/states. htm. D-8 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Table D-5: Information on Disposal of Solids Resource Land Disposal Restrictions: Summary of Requirements, August 2001 Paint Filter Liquid Test (SAM Method 9095B), September 2004 Resource Conservation Recovery Act Orientation Manual, 2011 Stabilization/Solidification Processes for Mixed Waste, June 1996 A System's Guide to the Identification and Disposal of Hazardous and Non-Hazardous Water Treatment Plant Residuals, August 2006 T =; % < Description o m R = This document summarizes the requirements of the Land Disposal Restrictions (LDR) program. This document is organized in a question-answer format to provide information about LDR regulations. See EPA publication EPA 530-R-01 -007, http://nepis.epa.gov/Exe/ZyPURL.cgi7Dockey = P1004UMF.txt. This is a method that is used to determine the presence of free liquids in a representative sample of waste. See EPA publication SW-846, http://www.epa.gov/wastes/hazard/testmethods/ sw846/pdfs/9095b.pdf for the method description. This manual addresses the management of solid or hazardous waste such as contaminated soils, water, debris, and sludges. See http://www.epa.gov/osw/inforesources/pubs/orientat/. The document explains how to solidify mixed waste. See EPA publication EPA 402-R-96-01 4, http://nepis.epa.gov/Exe/ ZyPURL.cgi?Dockey= P10094M5.txt. This document summarizes the RCRA hazardous waste regulations. See EPA publication EPA 81 6-F-06-01 1 , http:// water.epa.gov/drink/info/arsenic/upload/2006_09_14_arsenic_ guide_arsenic_disposalhazardous-nonhazardous.pdf. D-9 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Appendix E: Summary of Potentially Applicable Laws and Regulations This appendix provides a summary of the federal laws and regulations potentially applicable to the contain- ment and disposal of large amounts of water contaminated with chemical, biological, or radiological (CBR) contaminants. The full text of all the regulations cited below can be found at the Federal Register website (https://www.federalregister.gov/) or the Code of Federal Regulations (CFR) website (http://www.gpoaccess. gov/cfr/index.html). State and local governments and other federal agencies may have additional regulations for containment and disposal. Those regulations are not summarized in this document. Contact your state or local government for information and guidance. EPA Environmental Requirements Clean Water Act (CWA; 33 USC 1251 et seq.) Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA; 42 USC 9601 et seq.) Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA; 7 USC 136 etseq.) National Oil and Hazardous Substances Pollution Contingency Plan (NCP; 40 CFR Part 300) Oil Pollution Act (OPA; 33 USC 2701 et seq.) Resource Conservation and Recovery Act (RCRA; 42 USC 6901 et seq.) Safe Drinking Water Act (SDWA; 42 USC 300f et seq.) Storage, Treatment, Transportation, and Disposal of Mixed Wastes, Final Rule, May 2001 (66 FR 95. May 16, 2001) Toxic Substance Control Act (TSCA; 15 USC 2601 et seq.) Other Federal Requirements Transportation Requirements Hazardous Materials Regulations (HMR; 49 CFR Parts 100-185) Atomic Energy Act Atomic Energy Act of 1954, as Amended (AEA; 42 USC 2011 et seq.) Disposal Requirements, Non-EPA Low Level Radioactive Waste Policy Act (Pub. L. 96-573) Safety Requirements Occupational Safety and Health Act (OSH Act; 29 USC 651 et seq.) Federal Emergency Assistance The Robert T Stafford Disaster Relief and Emergency Assistance Act (Stafford Act; 42 USC 5212-52076) E-1 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Environmental Requirements Clean Water Act (CWA; 33 USC 1251 et seq.) The Clean Water Act establishes the basic structure for regulating discharges of pollutants into the waters of the United States and regulating quality standards for surface waters. The Clean Water Act section 301 (f) pro- hibits the discharge to waters of the United States of any radiological, chemical, or biological warfare agent, as well as any high-level radioactive waste or medical waste. For more information, see http://www.epa.gov/ lawsregs/laws/cwa.html. Under the CWA, EPA has implemented pollution control programs and regulates: Direct discharges of liquid waste to surface waters (rivers, lakes, etc.) generally through National Pollutant Discharge Elimination System (NPDES) permits (which are in many cases administered on the state level) (40 CFR Part 122) Discharges to publicly owned treatment works (POTW) through the National Pretreatment Standards (40 CFR Part 403) Discharges of oil to navigable water under 40 CFR Parts 110 and 112 EPA's CWA regulations prohibit the discharge of certain pollutants to a POTW through the National Pretreat- ment Standards: Prohibited Discharges (40 CFR 403.5). CBR contaminants can be considered pollutants. Prohibitions include pollutants that may: Cause a pass-through or interference with the POTW treatment processes (including the quality of sludge) Cause corrosive structural damage to the POTW Have a pH lower than 5.0 (i.e., are acidic), unless the POTW is designed to handle such a discharge Create a fire or explosion hazard Obstruct the flow in the POTW Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA; 42 USC 9601 et seq.) The Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA or Superfund) pro- vides broad response authority for cleaning up releases of hazardous substances, pollutants or contami- nants, establishes potential liability of persons responsible for releases of hazardous substances at these sites, and established a trust fund to provide for cleanup (e.g., when no responsible party could be identified). CERCLA authorizes both short-term removals (e.g., to address releases or threatened releases in need of prompt response), and long-term remedial response actions (e.g., to address releases or threats of releases of hazardous substances for sites listed on EPA's National Priorities List). CERCLA provides broad federal response authority that EPA (and consistent with Executive Order 12580, other federal agencies) can use for cleanup. EPA may enter into a cooperative agreement with state and local governments to assist in the cleanup where CERCLA section 104 authority is used to respond to a release of CBR contaminants. CERCLA cleanups are carried out consistent with the NCP and existing Superfund program guidance. See http://www.epa.gov/lawsregs/laws/cercla.html for more information. Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA; 7 USC 136 et seq.) Products used to treat water contaminated with biological contaminants, such as chlorine, chlorine dioxide, and chloramines may be registered as pesticides under the Federal Insecticide, Fungicide, and Rodenticide E-2 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Act (FIFRA), in which case they may used only in accordance with the label or labeling approved by EPA. Under FIFRA, no one may sell or distribute a pesticide unless it is registered by the EPA, or is otherwise ex- empted from the registration requirement. Registration includes approval by the EPA of the pesticide's label, which must give detailed instructions for its safe and effective use and disposal. Different kinds of exemptions are issued by EPA, depending on the situation and whether the criteria for granting such exemptions are met. For example, EPA issued numerous exemptions permitting the use of registered and unregistered antimicro- bial pesticides for inactivating Bacillus anthracis spores after EPA reviewed those products to ensure that they would be effective and not present unreasonable adverse effects to humans or the environment. For more information, see http://www.epa.gov/pesticides/factsheets/health_fs.htm. A chemical contaminant that is a FIFRA cancelled or suspended pesticide, rinsate containing the pesticide, or any other material used to collect excess or spilled quantities of the pesticide may be subject to additional regulations and/or requirements issued by EPA regarding labeling, transportation, storage, and disposal. Requirements vary depending on the pesticide, and, therefore, the regional EPA office should be contacted to determine if there are additional requirements and/or procedures for a cancelled or suspended pesticide and to determine if those requirements and/or procedures apply to the contaminated water. For more infor- mation on pesticides, please see http://www.epa.gov/pesticides/. For more information about FIFRA and cancellation/suspension of pesticides, please see http://www.epa.gov/oecaagct/lfra.html. National Oil and Hazardous Substances Pollution Contingency Plan (NCP; 40 CFR Part 300) The National Oil and Hazardous Substances Pollution Contingency Plan (NCP) provides a blueprint for pre- paring for and responding to discharges of oil and releases or threats of release of hazardous substances (or of pollutants and contaminants which may present an imminent and substantial endangerment to the public health and welfare). The NCP establishes the National Response Team (NRT), which consists of 16 federal agencies that are responsible for national response and preparedness planning. The NCP also establishes 13 Regional Response Teams (RRTs).2930 Details regarding planning and preparedness are found in 40 CFR 300.200 to 300.220. In this portion of the NCR the objective, authority, and scopes of the NCR Regional Contingency Plans (RCPs), and Area Contin- gency Plans (ACPs) are defined. The NCR RCR and ACP may be consulted during the response to a spill for guidance on cleanup and disposal. The description and breakdown of responsibilities of a response are found in 40 CFR 300.100 to 300.185. This part of the NCP describes the actions and responsibilities of the On-Scene Coordinator (OSC) and fed- eral agencies, as well as establishes the unified command structure. Regulations specific to oil spill response are found in 40 CFR 300.300 to 300.335 and regulations for re- sponses to hazardous substances releases are found in 40 CFR 300.400 to 300.525. Oil Pollution Act (OPA; 33 USC 2701 et seq.) The OPA establishes provisions that expand the federal government's ability, and provides the money and resources necessary, to respond to oil spills. The OPA provides new requirements for contingency planning both by government and industry. The National Oil and Hazardous Substances Pollution Contingency Plan (NCP) has been expanded in a three-tiered approach: the federal government is required to direct all public and private response efforts for certain types of spill events; Area Committees- composed of federal, state, 29 See http://www.nrt.org/ for more information on the NRT. 30 See http://www.nrt.org/Production/NRT/RRTHome.nsf/AIIPages/othr_rrt.htm?OpenDocument for information the RRT responsible for your E-3 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities and local government officials - must develop detailed, location-specific Area Contingency Plans; and own- ers or operators of vessels and certain facilities that pose a serious threat to the environment must prepare their own Facility Response Plans. For more information, see http://www.epa.gov/oem/content/lawsregs/ opaover.htm. Resource Conservation and Recovery Act (RCRA; 42 USC 6901 et seq.) The Resource Conservation and Recovery Act gives EPA the authority to control hazardous waste from "the cradle to the grave." This includes the generation, transportation, treatment, storage, and disposal of hazard- ous waste. RCRA also sets forth a framework for the management of non-hazardous solid wastes. For more information, see http://www.epa.gov/lawsregs/laws/rcra.html. Hazardous waste is defined in 40 CFR 261.3, Definitions of Hazardous Waste. A waste may be considered hazardous if it exhibits certain hazardous properties (characteristics) in 40 CFR 261.21 to 261.24 or if it is listed as a hazardous waste in 40 CFR 261.31 to 261.33, Subpart D - Lists of Hazardous Wastes. Waste streams that are not listed specifically as hazardous wastes may exhibit hazardous characteristics and thus be a RCRA hazardous waste. RCRA identifies four hazardous waste characteristic properties: ignitability, cor- rosivity, reactivity, or toxicity. Methods used to determine if a waste qualifies as hazardous waste are found in Test Methods for Evaluating Solid Waste, Physical/Chemical Methods (SW-846).31 Water produced during treatment that meets the definition of "Hazardous Waste" as described above may be subject to RCRA regu- lation (Subtitle C, 40 CFR Parts 260 to 299). Under RCRA, EPA has promulgated regulations for generators of hazardous waste (40 CFR Part 262), haz- ardous waste treatment facilities (40 CFR Parts 264 and 265), hazardous waste storage facilities (40 CFR Parts 264, 265, and 270), hazardous waste transporters (40 CFR Part 263), and state hazardous waste man- agement plans (40 CFR Part 271). As described in 40 CFR 264.1(g)(8)(i), RCRA Part 264 regulations do not apply to a person containing or treating waste during immediate response to the following except as provided in paragraph (g)(8)(ii) of the same section: A discharge of a hazardous waste32 An imminent and substantial threat of a discharge of hazardous waste A discharge of a material that, when discharged, becomes a hazardous waste An immediate threat to human health, public safety, property, or the environment, from the known or sus- pected presence of military munitions, other explosive material, or an explosive device, as determined by an explosive or munitions emergency response specialist as defined in 40 CFR 260.10 Safe Drinking Water Act (SDWA; 42 USC 300f et seq.) The Safe Drinking Water Act was established to protect the quality of drinking water in the U.S. This law focuses on all waters actually or potentially designed for drinking use, whether from above ground or under- ground sources. The Act authorizes EPA to establish national primary drinking water regulations for water for human consumption and requires all owners or operators of public water systems to comply with these standards. For more information, see http://www.epa.gov/lawsregs/laws/sdwa.html or http://water.epa.gov/ lawsregs/rulesregs/sdwa/index.cfm. EPA's regulations are at 40 CFR Part 141. More information about the standards is available at http://water.epa.gov/drink/standardsriskmanagement.cfm. A list of the standards can be found at http://water.epa.gov/drink/contaminants/index.cfm. The National Secondary Drinking Water 31 See http://www.epa.gov/osw/hazard/testmethods/sw846/online/index.htm. 32 Discharge is defined as the accidental or intentional spilling, leaking, pumping, pouring, emitting, emptying, or dumping of hazardous waste into or on any land or water (40 CFR 260.10, Definitions). E-4 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Regulations are listed in Part 143 of the SDWA. These regulations control contaminants that primarily affect the aesthetic qualities relating the public acceptance of drinking water. At considerably higher concentra- tions of these contaminants, health implications may also exist. The secondary regulations are not federally enforceable but are intended as guidelines for states. There are secondary regulations for 15 contaminants. For more information see http://water.epa.gov/drink/contaminants/secondarystandards.cfm. The SDWA also required EPA to establish regulations for the UIC Program to prevent endangerment of under- ground sources of drinking water (USDWs). The UIC regulations are at 40 CFR Parts 144-148. UIC programs are administered by EPA or states with primary enforcement responsibility for the program. States may have more stringent requirements. There are six classes of injection wells: Hazardous, Radioactive, Industrial & Municipal Waste Disposal Wells (Class I), Waste disposal wells for oil and gas production (Class II), Solution Mining Wells (Class III), Shallow Hazardous and Radioactive Injection Wells (Class IV; banned in 1984), injec- tion wells not included in Class I, II, III, IV, or VI (Class V), and Geological Sequestration of Carbon Dioxide (Class VI). Table E-1 describes the different classes of injection wells and considerations specific to each well class. Refer to EPA's Technical Program Overview: Underground Injection Control Regulations for further guidance on the regulations of UIC wells.33 33 See http://water.epa.gov/type/groundwater/uic/upload/2004_5_3_uicv_techguide_uic_tech_overview_uic_regs.pdf. E-5 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Table E-1: Classes and Considerations for Underground Injection/Well Disposal34 Class Includes deep injection wells used for hazardous waste, radioactive waste and other industrial material As defined in 40 CFR 144.3, radioac- tive waste includes any waste which contains radioactive material in concentrations which exceed those listed in 10 CFR 20, Appendix B, Table 2, Column 2 There are approximately 650 Class I injection wells nationwide, of those only about 113 are used for the injec- tion of hazardous waste. Only 10 states have wells that accept hazardous waste Considerations 1 Class I hazardous or mixed radioactive waste disposal wells have the most stringent USDW protective require- ments 1 As with all well classes under the UIC program may not conduct any injection activity in a manner that allows the movement of fluid containing any contaminant into USDWs, if the presence of that contaminant may cause a violation of any primary drinking water standard under 40 CFR 142 or may otherwise adversely affect public health (40 CFR 144.12) 1 Very few Class I facilities are able to accept hazardous waste generated off site 1 Fluids must be injected below the lowermost formation containing a USDW 1 Class I wells can be expensive to construct because they are technically complex 1 No radioactive waste disposal wells are currently in operation Includes injection wells used for dis- posal of fluid brought to the surface in connection with oil and natural gas production, or for enhanced recovery of oil or natural gas, or liquid hydrocarbon storage Not an option Wells which inject to extract minerals Not an option IV Shallow wells used to inject hazardous or radioactive waste into or above an underground source of drinking water (USDW) Class IV wells were banned in 1984 with the exception of wells used to inject contaminated ground water that has been treated and is being reinjected into the same forma- tion from which it was drawn, if such injection is approved by EPA, or a State, pursuant to provisions for a cleanup of releases under CERCLA or RCRA V Injection wells not included in Class- es I - IV, or VI Class V wells are located in every state 1 As with all well classes under the UIC program may not conduct any injection activity in a manner that allows the movement of fluid containing any contaminant into USDWs, if the presence of that contaminant may cause a violation of any primary drinking water standard under 40 CFR 142 or may otherwise adversely affect public health (40 CFR 144.12) VI Wells that are used for geologic sequestration of carbon dioxide be- neath the lowermost USDW Not an option 34 For more information on UIC and well disposal classes, please visit http://water.epa.gov/type/groundwater/uic/index.cfm. E-6 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Storage, Treatment, Transportation, and Disposal of Mixed Wastes, Final Rule, May 2001 (66 Federal Register 95 (16 May 2001), pp. 27217-27266) Following the Storage, Treatment, Transportation, and Disposal of Mixed Wastes, Final Rule, low-level mixed waste (LLMW) may be conditionally exempt from RCRA storage, treatment, transportation, and disposal regulations if the waste meets several conditions.35 Conditionally exempt LLMW is then stored, treated, trans- ported, and disposed as low-level radioactive waste (LLRW). This exemption is applicable only in RCRA-authorized states that have adopted the exemption provisions. States may also have additional conditions for the exemption. If waste does not qualify for the exemption it is subject to both NRC and RCRA requirements. Table E-2 provides a summary of the provisions for the conditional exemption. 35 Refer to http://www.gpo.gov/fdsys/pkg/FR-2001 -05-16/pdf/01 -11408.pdf for the full text of the final rule. E-7 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Table E-2: Summary of Storage, Treatment, Transportation, and Disposal of Mixed Wastes, Final Rule, May 2001 Action Conditions for Exemption 1 Waste is generated under a single NRC or Agreement State license 1 Waste is stored in a tank or container 1 Waste is treated in a tank or container 1 Waste must be treated to levels that are as low as reasonably achievable (ALARA) 1 Waste cannot be transported if one wishes to maintain the LLMW exemption 1 Comply with NRC or Agreement State regulations and manifest requirements 1 Waste must be treated to levels that are ALARA 1 Solid waste must be treated to land disposal restrictions (LDR) treatment standard 1 Liquids cannot be disposed of at LLRW disposal facilities 1 Solid waste must be treated to LDR treatment standards and disposed of in containers meeting NRC requirements Notifications 1 Notify RCRA regulatory authority in writing by certified delivery claiming a conditional exemption for the LLMW - Notify within 90 days of when a storage unit is first used to store conditionally exempt LLMW -Includeyour name, address, RCRA identification number, NRC or NRC Agreement State license number, the waste code(s) and storage unit(s), and a statement that you meet the conditions of this subpart - Check to make sure the notification is signed by the authorized representative. Provide notice to the RCRA regulatory authority claiming the transportation conditional exemption prior to shipment (notice must include the facility name, address, phone number, RCRA ID, and be sent by certified delivery) Notify those receiving the exempted waste before shipment. Notification includes: -A statement that you have claimed the waste exemption -A statement that the waste meets LDR treatment standards -Facility's name, address, and RCRA ID number -A statement that the waste must be placed in a container according to 40 CFR 266.340 prior to disposal -The manifest number of the shipment that will contain the exempt waste -A certification that all the information provided is true, complete and accurate Recordkeeping 1 Keep the following: -Records required by NRC or NRC Agreement State license -Initial notification records - Return receipts - Reports of failures to meet the exemption conditions -All records supporting any reclaim of an exemption - Certification that facility personnel who manage stored mixed waste are trained in safe management of LLMW - Emergency plan as specified in 40 CFR 266.230(b) Keep all records for as long as the exemption is claimed and for 3 years thereaft E-8 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Toxic Substance Control Act (TSCA; 15 USC 2601 et seq.) The Toxic Substance Control Act (TSCA) provides EPA with authority to require reporting, record-keeping and testing requirements, and restrictions relating to chemical substances and/or mixtures. TSCA also addresses chemicals specifically including polychlorinated biphenyls (PCBs), asbestos, radon and lead-based paint. For additional information, see http://www.epa.gov/lawsregs/laws/tsca.html. Under TSCA authority, EPA has promulgated regulations to implement pre-market review of any new chemical substance before it is intro- duced into commerce. Under TSCA, EPA developed regulations for disposal of liquids and solids contami- nated with PCBs. Transportation Requirements Hazardous Materials Regulations (HMR; 49 CFR Parts 100-185) For information on the Hazardous Materials Regulations and other Department of Transportation (DOT) trans- port requirements see: http://www.phmsa.dot.gov/hazmat/regs/. Safety Requirements Occupational Safety and Health Act (OSH Act; 29 USC 651 et seq.) For information about the Occupational Safety and Health Act and worker health and safety guidance refer to: http://www.osha.gov/. Federal Emergency Assistance The Robert T. Stafford Disaster Relief and Emergency Assistance Act (Stafford Act; 42 USC 5121 etseq.) If state and local resources are overwhelmed during an emergency or major disaster, the Stafford Act pro- vides guidance on how the state can request federal assistance. For information about the Stafford Act and the process for receiving federal assistance during an emergency or major disaster, refer to: https://www.fema. gov/library/viewRecord.do?fromSearch=fromsearch&id=3564. E-9 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities Appendix F: References General References Bazan, EB, 2005. Robert T. Stafford Disaster Relief and Emergency Assistance Act: Legal Requirements for Federal and State Roles in Declarations of an Emergency or Major Disaster. CRS Report for Congress. September 2005. http://fpc.state.gov/documents/organization/53688.pdf National Association of Clean Water Agencies (NACWA), 2005. Planning for Decontamination Wastewater: A Guide for Utilities, http://www.michigan.gov/documents/deq/deq-wb-wws- 2005WWDeconGuide_271352_7.pdf U.S. Department of Energy, 2006. Transportation Routing Analysis Geographic Information System. September 2006. U.S. Department of Health and Human Services Centers for Disease Control and Prevention and National Institutes of Health, 2007. Biosafety in Microbiological and Biomedical Laboratories (BMBL) 5th Edition. http://www.cdc.gov/biosafety/publications/bmbl5/index.htm U.S. Department of Health and Human Services, Office of Inspector General, 2005. Possession, Use, and Transfer of Select Agents and Toxins; Final Rule. Federal Register Volume 70, Number 52, March 18, 2005. http://www.gpo.gov/fdsys/pkg/FR-2005-03-18/pdf/05-5216.pdf U.S. Department of Homeland Security and U.S. Environmental Protection Agency, 2009. Planning Guidance for Recovery Following Biological Incidents. May 2009 Draft. U.S. Department of Homeland Security, 2008. National Response Framework. FEMA Publication P-692, January 2008. http://www.fema.gov/pdf/emergency/nrf/nrf-core.pdf U.S. Department of Homeland Security, 2003a. Homeland Security Presidential Directive - 7: Critical Infrastructure Identification, Prioritization, and Protection. December 17, 2003. http://www.dhs.gov/xabout/ laws/gc_1214597989952.shtm U.S. Department of Homeland Security, 2003b. Presidential Policy Directive - 8: National Preparedness. December 17, 2003. http://www.dhs.gov/xabout/laws/gc_1215444247124.shtm U.S. Department of Homeland Security, 2003c. Homeland Security Presidential Directive - 10: Biodefense for the 21st Century. December 17, 2003. https://www.hsdl.org/?view&did=446666 U.S. Department of Labor, 2006. OSHA e-HASP Software. Occupational Safety and Health Administration, March 2006. http://www.osha.gov/dep/etools/ehasp/index.html U.S. Department of Transportation, 2008. The National Hazardous Materials Route Registry. Federal Motor Carriers Safety Administration. http://www.fmcsa.dot.gov/safety-security/hazmat/national-hazmat-Route.aspx U.S. Department of Transportation, 2005. Special Permits. Pipeline and Hazardous Materials Safety Administration, http://phmsa.dot.gov/hazmat/regs/sp-a/special-permits U.S. Environmental Protection Agency, 2008. Resource Conservation Recovery Act Orientation Manual. Office of Solid Waste, http://www.epa.gov/osw/inforesources/pubs/orientat/ U.S. Environmental Protection Agency, 2012. Incident Waste Decision Support Tool. Office of Research and Development, National Homeland Security Research Center, April 2012. http://www2.ergweb.com/bdrtool/ login.asp F-1 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities U.S. Environmental Protection Agency, 2007. Technical Brief: Water Systems Materials Disposal Decision Support Tool. Office of Research and Development, National Homeland Security Research Center, September 2007. U.S. Environmental Protection Agency, 2007. Risk Communication in Action: The Risk Communication Workbook. Publication No. EPA/625/R-05/003, Office of Research and Development, August 2007. http://nepis. epa.gov/Exe/ZyPURL. cgi?Dockey=60000!2U.txt U.S. Environmental Protection Agency, 2007. Risk Communication in Action: The Tools of Message Mapping. Publication No. EPA/625/R-06/012, Office of Research and Development, August 2007. http://nepis. epa.gov/Exe/ZyPURL. cgi?Dockey=60000IOS.txt U.S. Environmental Protection Agency, 2007. Effective Risk and Crisis Communication during Water Security Emergencies: Summary Report of EPA Sponsored Message Mapping Workshops. Publication No. EPA/600/R-07/027. Office of Research and Development, March 2007. http://nepis.epa.gov/Exe/ZyPURL. cgi?Dockey=60000GH1 .txt U.S. Environmental Protection Agency, 2010. Revised Public Health Notification Handbook. Publication No. EPA/816/R-07/03. Office of Water, March 2010. http://water.epa.gov/lawsregs/rulesregs/sdwa/ publicnotification/upload/PNrevisedPNHandbookMarch2010.pdf U.S. Environmental Protection Agency, 2005. Introduction to Containers (Training Module). Publication No. 530-K-05-010. Office of Solid Waste and Emergency Response, September 2005. http://nepis.epa.gov/Exe/ ZyPURL.cgi?Dockey=P1008KG6.txt U.S. Environmental Protection Agency, 2005. Introduction to Tanks (Training Module). Publication No. 530- K-05-018. Office of Solid Waste and Emergency Response, September 2005. http://www.epa.gov/wastes/ inforesources/pubs/training/tanks05.pdf U.S. Environmental Protection Agency, 2005. Introduction to Land Disposal Units (Training Module). Publication No. 530-K-05-014. Office of Solid Waste and Emergency Response, September 2005. http://nepis. epa.gov/Exe/ZyPURL. cgi?Dockey=P1009IJ2.txt U.S. Environmental Protection Agency, 2004. Method 9095B: Paint Filter Liquids Test. Office of Solid Waste and Emergency Response, November 2004. http://www.epa.gov/wastes/hazard/testmethods/sw846/ pdfs/9095b.pdf U.S. Environmental Protection Agency, 2004. Response Protocol Toolbox: Planning for and Responding to Drinking Water Contamination Threats and Incidents, Response Guidelines. Office of Water, Interim Final, August 2004. http://water.epa.gov/infrastructure/watersecurity/upload/2004_11_24_rptb_response_ guidelines.pdf U.S. Environmental Protection Agency, 2004. Response Protocol Toolbox: Planning for and Responding to Drinking Water Contamination Threats and Incidents, Module 6: Remediation and Recovery Guide. Office of Water, Interim Final, April 2004. http://water.epa.gov/infrastructure/watersecurity/upload/2004_05_19_ watersecurity_guide_response_module6.pdf U.S. Environmental Protection Agency, 2004. Summary Report of the National Water Security Risk Communication Symposium. Publication No. EPA/600/C-05/006. Office of Research and Development, May 2004. http://nepis.epa.gov/Exe/ZyPURL.cgi?Dockey=P100049M.txt U.S. Environmental Protection Agency, 2004 Local Limits Development Guidance, EPA833-R-0-4002A, July 2004. http://www.epa.gov/npdes/pubs/final_local_limits_guidance.pdf F-2 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities U.S. Environmental Protection Agency, 2001. Land Disposal Restrictions: Summary of Requirements, EPA530-R-01-007, Offices of Solid Waste and Emergency Response and Enforcement and Compliance Assurance, August 2001. http://nepis.epa.gov/Exe/ZyPURL.cgi?Dockey=P1004UMF.txt U.S. Environmental Protection Agency, 2001. Technical Program Overview: Underground Injection Control Regulations, EPA 816-R-02-025, Office of Water, July 2001. http://water.epa.gov/type/groundwater/uic/ upload/2004_5_3_uicv_techguide_uic_tech_overview_uic_regs.pdf U.S. Environmental Protection Agency, 1999. Guidance Manual for the Control of Wastes Hauled to Publicly Owned Treatment Works, Publication No. EPA-833-B-98-003. Office of Wastewater Management, September 1999. http://water.epa.gov/aboutow/owm/upload/2005_07_14_hwfinal.pdf U.S. Environmental Protection Agency, 1996. Hazardous Waste Requirements for Large Quantity Generators, Publication No. 530-F-96-032. Office of Solid Waste, June 1996. http://www.epa.gov/osw/ hazard/downloads/lqgpdf.pdf U.S. Environmental Protection Agency, 2012. Hazardous Waste Manifest System, Office of Solid Waste and Emergency Response, http://www.epa.gov/waste/hazard/transportation/manifest/index.htm U.S. Environmental Protection Agency, 2011. National Oil and Hazardous Substances Pollution Contingency Plan (also known as the National Contingency Plan [NCP]) Overview. Office of Emergency Management, http://www.epa.gov/osweroe1/content/lawsregs/ncpover.htm U.S. Environmental Protection Agency, 2012. Off-Site Rule Fact Sheet. Office of Solid Waste and Emergency Response, http://www.epa.gov/waste/hazard/wastetypes/wasteid/offsite/os-facts.htm U.S. Environmental Protection Agency, 2012. State Manifest Requirements, Office of Solid Waste and Emergency Response, http://www.epa.gov/epawaste/hazard/transportation/states.htm U.S. Environmental Protection Agency, 2010. Standardized Analytical Methods for Environmental Restoration following Homeland Security Events, Revision 6, EPA/600/R-10/122. Office of Research and Development, http://www.epa.gov/sam/sam2010_9302010.pdf U.S. Environmental Protection Agency, 2010. Water Contaminant Information Tool (WCIT). Office of Water. http://www.epa.gov/wcit/ U.S. Nuclear Regulatory Commission, 2012. NRC Regulatory Guides - Transportation (Division 7). http:// www.nrc.gov/reading-rm/doc-collections/reg-guides/transportation/rg/ Water UK, 2003. Protocol for the Disposal of Contaminated Water, Version 2.1, September 2003. http://www. water.org.uk/home/policy/publications/archive/industry-guidance/disposal-of-contaminated-water/2003- protocol-contamwater.pdf?s1=protocol&s2=for&s3=the&s4=disposal&s5=of&s6=contaminated&s7=water Chemical References Agency for Toxic Substances and Disease Registry, http://www.atsdr.cdc.gov/ Federal Motor Carrier Safety Administration, 2010. SafeStat Module, August 2010. http://ai.fmcsa.dot.gov/SMS/ U.S. Environmental Protection Agency, 2010. Hazardous Waste Generator Regulations, Version 5, August 2011. http://www.epa.gov/solidwaste/hazard/downloads/tool.pdf U.S. Environmental Protection Agency, 2009. Booms, March 2009. http://www.epa.gov/emergencies/ content/learning/booms.htm F-3 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities U.S. Environmental Protection Agency, 2009. Drinking Water Contaminants, Technical Factsheet on: Cadmium.(archived document) http://water.epa.gov/drink/contaminants/basicinformation/historical/upload/ Archived-Technical-Fact-Sheet-on-Cadmium.pdf. For current information, see http://water.epa.gov/drink/ contaminants/basicinformation/cadmium.cfm. U.S. Environmental Protection Agency, 2009. Drinking Water Contaminants, Technical Factsheet on: Chromium, (archived document) http://water.epa.gov/drink/contaminants/basicinformation/historical/ upload/Archived-Technical-Fact-Sheet-on-Chromium.pdf U.S. Environmental Protection Agency, 2009. Drinking Water Contaminants, Technical Factsheet on: Copper, (archived document) http://water.epa.gov/drink/contaminants/basicinformation/historical/upload/ Archived-Technical-Fact-Sheet-on-Copper.pdf U.S. Environmental Protection Agency, 2009. Drinking Water Contaminants, Technical Factsheet on: Mercury, (archived document) http://water.epa.gov/drink/contaminants/basicinformation/historical/upload/ Archived-Technical-Fact-Sheet-on-Mercury.pdf U.S. Environmental Protection Agency, 2009. Drinking Water Contaminants, Technical Factsheet on: Nickel. (archived document) http://water.epa.gov/drink/contaminants/basicinformation/historical/upload/Archived- Technical-Fact-Sheet-on-Nickel.pdf U.S. Environmental Protection Agency, 2009. Drinking Water Contaminants, Technical Factsheet on: Thallium, (archived document) http://water.epa.gov/drink/contaminants/basicinformation/historical/upload/ Archived-Technical-Fact-Sheet-on-Thallium.pdf U.S. Environmental Protection Agency, 2009. Emergency Management: Skimmers, March 2009. http://www.epa.gov/emergencies/content/learning/skimmers.htm U.S. Environmental Protection Agency, 2009. Emergency Management: Sorbents, March 2009. http://www.epa.gov/emergencies/content/learning/sorbents.htm U.S. Environmental Protection Agency, 2009. National Biennial RCRA Hazardous Waste Report: Documents and Data. July 2009. http://www.epa.gov/solidwaste/inforesources/data/biennialreport/index.htm U.S. Environmental Protection Agency, 2009. NRT Quick Reference Guide: Cyclosarin (GF), National Response Team. 2000. http://www.nrt.org/production/NRT/NRTWeb.nsf/AIIAttachmentsByTitle/A- 1043WMDGF(Cyclosarin)QRG/$File/GF_QRG_Final_(07-28-11).pdf?OpenElement U.S. Environmental Protection Agency, 2009. NPDES Permit Program Basics. Office of Water, April 2009. http://cfpub.epa.gov/npdes/home.cfm7programjd = 45 U.S. Environmental Protection Agency, 2009. Underground Injection Control Program. July 2009. http://water.epa.gov/type/groundwater/uic/index.cfm U.S. Environmental Protection Agency, 2008. Generator Summary Chart. November 2008. http://www.epa.gov/solidwaste/hazard/generation/summary.htm U.S. Environmental Protection Agency, 2008. Sampling Guidance for Unknown Contaminants in Drinking Water, Publication No. 817-R-08-003, November 2008. http://water.epa.gov/infrastructure/watersecurity/wla/ upload/2008_12_31_watersecurity_pubs_guide_watersecurity_samplingforunknown.pdf U.S. Environmental Protection Agency, 2008. NRT Quick Reference Guide: Lewisite (L), National Response Team. 2008. http://www.nrt.org/production/NRT/NRTWeb.nsf/AIIAttachmentsByTitle/A- 1009WMDQRGLewisite/$File/120216_Lewisite_QRG_Final.pdf?OpenElement F-4 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities U.S. Environmental Protection Agency, 2005. Treatment Technologies for Arsenic Removal. National Risk Management Research Laboratory, Publication No. EPA/600/S-05/006, November 2005. http://nepis.epa. gov/Exe/ZyPURL.cgi?Dockey=20017IDW.txt U.S. Environmental Protection Agency, 2000. Technologies and Costs for Removal of Arsenic from Drinking Water. Office of Water, Publication No. EPA 815-R-00-028, December 2000. http://water.epa.gov/drink/info/ arsenic/upload/2005_11_10_arsenic_treatments_and_costs.pdf U.S. Environmental Protection Agency, 1992. CERCLA/SUPERFUND Orientation Manual. Office of Solid Waste and Emergency Response. Publication No. EPA 542-R-92-005, October 1992. http://nepis.epa.gov/ Exe/ZyPURL.cgi?Dockey= 10002WV5.txt U.S. Environmental Protection Agency, 1991. Guide to Discharging CERCLA Aqueous Wastes to Publicly Owned Treatment Works (POTWs). Office of Solid Waste and Emergency Response, March 1991. http:// www.epa.gov/superfund/policy/remedy/pdfs/93-30213fs-s.pdf U.S. Environmental Protection Agency, 1987. Guidance Manual for the Identification of Hazardous Waste Delivered to POTWs by Truck, Rail or Dedicated Pipe. Office of Water Enforcement and Permits, June 1987. http://www.epa.gov/npdes/pubs/owm0190.pdf Biological References Burleson, G.R., T.M. Murray, and M. Pollard, 1975. Inactivation of Viruses and Bacteria by Ozone, with and without Sonication. Journal of Applied Microbiology. 29(3): 340-344. Centers for Disease Control and Prevention, Office of Inspector General, Department of Health Human Services (HHS), 2005. Possession, Use, and Transfer of Select Agents and Toxins; Final Rule, 2005. Federal Register Volume 70, Number 52, March 18, 2005. http://www.gpo.gov/fdsys/pkg/FR-2005-03-18/pdf/05- 5216.pdf Chang, J.C., S.F. Ossoff, D.C. Lobe, M.H. Dorfman, C.M. Dumais, R.G. Quails, and J.D. Johnson, 1985. UV inactivation of pathogenic and indicator microorganisms. Applied and Environmental Microbiology. 49(6): 1361-1365. Chauret, C., T Miller, I. Auvray, R. Hofmann, C. Durance, R.C. Andrews, and H. Baribeau, 2003. Inactivation by Chlorine and Monochloramine of Environmental and Culture Collection Strains of E. coli O157:H7 and Selected Heterotrophic Bacteria. American Water Works Association. Decamp, O., and A. Warren, 2000. Investigation of Escherichia coli Removal in Various Designs of Subsurface Flow Wetlands Used for Wastewater Treatment. Ecological Engineering. 14: 293-299. Fujioka, R.S., et al., 1986. Comparative Disinfection of Indicator Bacteria and Poliovirus by Chlorine Dioxide. 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April 2012. http://water.epa.gov/action/advisories/drinking/upload/dwstandards2012.pdf. F-6 ------- Containment and Disposal of Large Amounts of Contaminated Water: A Support Guide for Water Utilities U.S. Environmental Protection Agency, 2006. A System's Guide to the Identification and Disposal of Hazardous and Non-Hazardous Water Treatment Plant Residuals, Publication No. 816-F-06-011. Office of Water, August 2006. http://water.epa.gov/drink/info/arsenic/upload/2006_09_14_arsenic_guide_arsenic_ disposalhazardous-nonhazardous.pdf Toxin References Agency for Toxic Substances and Disease Registry, http://www.atsdr.cdc.gov/ Centers for Disease Control and Prevention, Office of Inspector General, Department of Health Human Services (HHS), 2005. Possession, Use, and Transfer of Select Agents and Toxins; Final Rule, 2005. Federal Register Volume 70, Number 52, March 18, 2005. http://www.gpo.gov/fdsys/pkg/FR-2005-03-18/pdf/05- 5216.pdf Lowe, H.N., and D.C. Lindsten, 1957. 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Implementation Guidance for Radionuclides, Publication No. 816-F-00-002. Office of Water, March 2002. http://nepis.epa.gov/Exe/ZyPURL.cgi?Dockey=P1009DJN.txt U.S. Environmental Protection Agency, 2001. Storage, Treatment, Transportation, and Disposal of Mixed Waste; Final Rule. Federal Register Volume 66, Number 95, May 16, 2001. http://www.gpo.gov/fdsys/pkg/ FR-2001 -05-16/pdf/01 -11408.pdf U.S. Environmental Protection Agency, 2001. Radionuclides Rule: A Quick Reference Guide, Publication No. 816-F-01-003. Office of Water, June 2001. http://water.epa.gov/lawsregs/rulesregs/sdwa/radionuclides/ upload/2009_04_16_radionuclides_qrg_radionuclides.pdf U.S. Environmental Protection Agency, 2000. National Primary Drinking Water Regulations; Radionuclides; Final Rule. Federal Register Volume 65, Number 236, December 7, 2000. http://www.gpo.gov/fdsys/pkg/FR- 2000-12-07/pdf/00-30421 .pdf U.S. Environmental Protection Agency, 1996. 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