-------
Depth
Meters Feet
0 -
LOG OF FORT YUKON WATER WELL (1954)
50
100
150
50 m —
200
250
300
100m —I
350
400
450
silty sand (late Pleistocene)
approximate
top of permafrost
sandy gravel (Pleistocene)
•»
(Plio-Pleistocene?)
"Blue silt" lacustrine beds
(Pliocene?)
base of
continuous permafrost
Grey silt
w/ sporadic lenses of permafrost ice
(probably lacustrine)
Pollen sample ( pollen assemblage suggests
ca. 6-8 Ma likely) late Miocene
"
...
\ silty sand
J shallow lacustrine?
silt (lacustrine?)
Fig. 4. Log of Fort Yukon, Alaska, water well drilled by the U.S.
Army Corps of Engineers in 1954 (Williams, 1962). A single
sample of sediment collected from a depth of ca. 390 feet
(119 m) was found to contain a fossil pollen assemblage that
suggests a probable late Miocene age (ca. 6-8 million yrs.
old) for that depth.
rn o
6 •-
C
-------
ALPINE DRILLING & ENTERPRISES
Permit Number; #SW.
Date Started: 8-18-07
Legal Description:
Date of Issue:
Date Com pleted: 8-18-07
2007 Test Well # 1 Fort Yukon ARS Site
Property Owner Name & Address: USAF - ARCTEC
Parcel Identification Number;,
Is well located at approved permit location? Kl Yes
No
Borehole Data:
Soil Type, Thickness & Water Strata
stick-up
Sandy Silt
silty sand
silty sandy gravel small amt H20
silty sandy gravel Frozen
Depth (ft)
From To
0
1
12
24
32
1
12
24
32
100
Method of Drilling £3 air rotary O cable tool
Casing type: steel
Wall Thickness: .025 inches
Diameter: 6 inches Depth: 60 feet
Liner Type:
Diameter: inches Depth: _
Casing stickup above ground: 1_ feet
feet
Static water level (from ground level): O.feet
Pumping level: feet after
hours pumping gpm
Recovery Rate: gpm
Method of Testing:
Well Intake Opening Type:
D Open End [X] Open Hole
n Screened Start feet Stopped.
O Perforations Start feet Stopped,
.feet
feet
Grout Type: bentonite granules Volume: 4
Depth: Start togs feet Stopped 20 feet
Pump: Intake Depth feet
Pump size hp Brand Name
Well Disinfected Upon Completion? D Yes D No
Method of Disinfection:
Comments: Well appears to be pema frost from the 32'
level. A well seal was installed but the USA/may want to
decommission this well in the future.
Well Driller: Alpine Drilling & Enterprises
P.O. Box 110496
Anchorage, AK 99511-0496
Attention: The well driller shall provide a well log to the property owner within 30 days of completion and the property
owner or the well driller shall provide a well log to the Development Services Department within 60 days of completion.
-------
APPENDIX A.v.
ALLAKAKET RARE SITE BACKGROUND INFORMATION
-------
R.A.R.E. Opportunity
Regional Applied Research Effort, U.S. Environmental Protection Agency
The EPA, Office of Research and Development and the EPA, Alaska Operations Office are
partnering to look at how contaminants in leachate from open dumps may harm the environment
especially drinking water sources. The EPA resources for the project are limited but we think this
can be a good start in looking at the relationship between dump site leachate and impacts to our
environment. There is the opportunity for EPA to partner with five villages on the project.
Five different types of dump site conditions are needed for the project: 1) a dump site in dug up
tundra; 2) a dump site mostly on top of the tundra; 3) a dump site in a tundra pond; 4) a dump site
in ground that is not tundra where there is a short distance (twenty-five feet or less) to ground
water; and 4) a dump site in ground that is not tundra where there is a longer distance (twenty-
five feet or more) to ground water.
If you think your village may be interested in participating in the project please complete this
form and return it to either Michelle Davis or Joe Sarcone of the EPA, Alaska Operations Office.
Our fax number is (907) 271-3424. Thanks.
Name of Village:
Allakaket
Contact Person:
Pamela Vent EPA Coordinator
Email address:
allakaketepa@yahoo .com
Telephone number:
907-968-2529
IGAP program: yes_X no
Owner/operator of dump site (for example: the city government):
City of Allakaket
Owner of the land the dump site is located on (for example: the corporation):
City of Allakaket
Age of the dump site:
The dump was built 1999
Distance of the dump site to the village:
The dump is around 2-3 miles away from any houses
Distance of the dump site to a drinking water source (this could be the source of water for your
watering point/washeteria or it could be a traditional water source such as river, tundra pond,
spring, or ice):
It is about 2 !/2 - 3 !/> miles away from the washeteria
Distance of dump from a source of subsistence (for example, a river or slough or a berry picking
area):
The dump is about 2 1A -3 !/> away from the Koyukuk River, there is berry picking areas
all around the tundra between the dump and Allakaket.
Page 1. of 2.
-------
Type of dump site condition, Please circle one:
1) dump site in dug up tundra;
2) dump site mostly on top of the tundra;
3) dump site in a tundra pond;
4) dump site in ground that is not tundra where there is a short distance (twenty-five feet or less)
to ground water;
5) dump site in ground that is not tundra where there is a longer distance (twenty-five feet or
more) to ground water.
6) other (please describe)
The dump is mostly on top of tundra and also on Permafrost
Additional information you would like for us to know:
The Tribal Council and Community are interested on learning what would happen
if the permafrost would melt and the affects it would have on our lands.
Page 2. of 2.
-------
Alaska Division of Community and Regional Affairs
Services Staff Directory
Commerce
• find
Alaska Community Database Community
Information Summaries (CIS)
State of Alaska > Commerce >DCRA Home Page
• Community Database Online > CIS > Results
Allakaket
(al-uh-KACK-ut); also see New Allakaket
For Photos of Allakaket click here
For a Map of Allakaket click here
Current Population: 103 (2011 Alaska Department of Labor Estimate)
Incorporation Type: 2nd Class City
Located In: Yukon-Koyukuk Census Area
Taxes: Sales: None, Property: None, Special: None
Location and Climate
Allakaket is on the south bank of the Koyukuk River, southwest of its junction with the Alatna
River, approximately 190 air miles northwest of Fairbanks and 57 miles upriver from Hughes. The
village of Alatna is located directly across the river. The community lies at approximately
66.562610° North Latitude and -152.647560° West Longitude. (Sec. 14, T020N, R024W,
Fairbanks Meridian.) Allakaket is located in the Fairbanks Recording District. The area
encompasses 3.6 sq. miles of land and 0.7 sq. miles of water.
The area experiences a cold, continental climate with extreme temperature differences. The
average high temperature during July is 70 °F. The average low temperature during January is
well below zero and extended periods of-40 °F are common. The highest temperature ever
recorded was 94 °F, and the lowest was -75 °F. Average annual precipitation is 13 inches, and
average annual snowfall is 72 inches. The Koyukuk River is ice-free from June through October.
History, Culture and Demographics
Several Native groups have lived in the area, including Koyukon Athabascans and Kobuk, Selawik, and Nunamiut
Eskimos from the north and northwest. The Koyukon lived in several camps throughout the year, moving as the
seasons changed, following the wild game and fish. The various bands established joint settlements after 1851. The
old site of Alatna was a traditional trading center for Athabascans and Eskimos. The first mission on the Koyukuk
River, St. John's-in-the-Wilderness Episcopal Mission, was established in 1906. A post office was opened in 1925. In
1938, the name of the community was changed to Allakaket (the old name for the mission), and the name Alatna was
assumed by the small Eskimo community across the river. The first public school was established in 1957. A flood
caused by ice jamming inundated 85% of the community in the Spring of 1964. In 1975, the community incorporated
as a city, including both settlements of Allakaket and Alatna. A clinic and airport were built in 1978. A new school and
community roads were built in 1979. In September 1994, flood waters destroyed and swept away nearly all of the
community's buildings, homes, and food caches for the winter. Residents rebuilt near the old city site, but some new
homes and facilities are now located outside of the incorporated city boundaries. New Allakaket and Alatna are
located outside of the city limits.
A federally-recognized tribe is located in the community — the Allakaket Village. Allakaket is mainly an Athabascan
community; Kobuk Eskimos live across the river in Alatna. Two separate village councils exist. Traditional potlatches,
Topographic
map of
Allakaket
area
http://commerce.alaska.gov/dca/commdb/CIS.cfmC4/20/2012 4:45:16 PM]
-------
Alaska Division of Community and Regional Affairs
dances and foot races attract visitors from area villages. Subsistence activities provide the majority of food sources.
The sale, importation, and possession of alcohol is banned in the village.
According to Census 2010, there were 58 housing units in the community and 44 were occupied. Its population was
95.2 percent American Indian or Alaska Native; 1 percent white; 3.8 percent of the local residents had multi-racial
backgrounds.
Facilities, Utilities, Schools and Health Care
Most public facilities were severely damaged in the 1994 Koyukuk River flood. Major components have been replaced
— a washeteria, well and treatment plant, 100,000-gal. water storage tank, sewage lagoon, and force main have been
completed. The lagoon is connected to the washeteria and school. Residents carry treated water and haul
honeybuckets or use pit privies; no households have plumbing. Electricity is provided by Alaska Power Company.
There is one school located in the community, attended by 41 students. Local hospitals or health clinics include
Allakaket Health Clinic. Allakaket Health Clinic is a Primary Health Care facility with river and air access.
Economy
Most cash jobs are part-time or seasonal. The primary year-round employers are the school, city, tribe, and village
corporation store. Construction and BLM emergency firefighting provide summer jobs. A few earn income from
trapping or selling traditional Native handicrafts. Subsistence is the focus of the local economy. Salmon, whitefish,
moose, bear, small game, and berries provide most food sources. Caribou are taken when available.
The 2006-2010 American Community Survey (ACS) estimated 201 residents as employed. The public sector
employed 30.0%1 of all workers. The local unemployment rate was 54.5%1. The percentage of workers not in labor
force was 18.5%1. The ACS surveys established that average median household income (in 2010 inflation-adjusted
dollars) was $19,250 (MOE +/-$5,250)1. The per capita income (in 2010 inflation-adjusted dollars) was $15,925 (MOE
+/-$5,965)1. About 49.2%1 of all residents had incomes below the poverty level.
All ACS statistics are published with their repective margin of error (MOE). Some of the statistics here are calculated from the original ACS data. The
MOE was unable to be carried through the calculations.
For additional ACS information please click here.
For current Local Labor Market Information please click here
Transportation
Allakaket has no road link, but winter trails connect it with Hughes, Settles, and Tanana. River transportation is
important in summer, but there is no commercial barge access due to shallow water. A state-owned 4,000' long by
100' wide gravel runway is accessible year-round. A $6 million airport improvement began construction in 1997.
Organizations with Local Offices
City- City of Allakaket
P.O. Box 30
Allakaket, AK 99720
Phone 907-968-2424
Fax 907-968-2241
E-mail cityofallakaket@gmail.com
Electric Utility - Alaska Power Company
P.O. Box 3222
Port Townsend, WA 98368
Phone 800-982-0136
Fax 360-385-5177
E-mail apt@aptalaska.com
Web http://www.aptalaska.com/
Tribe - federally recognized - Allakaket Village
P.O. Box 50
Allakaket, AK 99720
Phone 907-968-2241
Fax 907-968-2233
Regional Organizations
http://commerce.alaska.gov/dca/commdb/CIS.cfm[4/20/2012 4:45:16 PM]
-------
Alaska Division of Community and Regional Affairs
School District - Yukon-Koyukuk School District
4762 Old Airport Way
Fairbanks, AK 99709-4456
Phone 907-374-9400
Fax 907-374-9442
E-mail kboyd@yksd.com
Web http://www.yksd.com
Regional Native Corporation - Doyon, Limited
1 Doyon Place, Suite 300
Fairbanks, AK 99701-2941
Phone 907-459-2000
Fax 907-459-2060
E-mail info@doyon.com
Web http://www.doyon.com
Regional Native Health Corporation - Tanana Chiefs Conference
122 First Ave, Suite 600
Fairbanks, AK 99701
Phone 907-452-8251
Fax 907-459-3851
E-mail jerryisaac@tananachiefs.org
Web http://www.tananachiefs.org
Native Housing Authority - Allakaket Village
P.O. Box 50
Allakaket, AK 99720
Phone 907-968-2241
Fax 907-968-2233
Services Webmaster
http://commerce.alaska.gov/dca/commdb/CIS.cfmC4/20/2012 4:45:16 PM]
-------
Alaska Well Log Tracking System
AllakaketWell Logs
(Searched May 2012)
#
1
2
3
4
5
6
Driller
USBIA
USBIA
USBIA
USBIA
LCMF LTD
USPHS
Owner
US BIA, ALLAKAKET
US BIA, ALLAKAKET
US BIA, ALLAKAKET
US BIA, ALLAKAKET
ALLAKAKET, CITY OF
US PHS, ALLAKAKET
Property Description
ALLAKAKET AREA
ALLAKAKET AREA
ALLAKAKET AREA
ALLAKAKET AREA
ALLAKAKET AREA
ALLAKAKET, COMMUNITY
WELL
Key
2625
2626
2627
2647
23081
23838
http://www.navmaps.alaska.gov/welts/switchbox.asp
-------
J^K;
-------
LOCATION OF WELL
x*/r.
STATE OF ALASKA
DEPARTMENT OF NATURAL RESOURCES «
DIVISION OF MINING & WATER MGMT *£ */ K) £
WATER WELL RECORD
BOROUGH
LOT
BLOCK
SECTION QTW
SECTION
TOWNIH»
RANOC
MEMOIAN
WELL OWNER:
, .
t»T^ /A«4 f
DEPTHS MEASURED FROM:D casino top D ground surface
BOREHOLE DATA:
Material Type and Color
Depth
From To
WELL DEPTH:
Depth of hole:__
Depth of casing:_
ft
ft
DATE QF COMPLETION
» / 2.1 i 9f
DEPTH TO STATIC WATER LEVEL:
*t below D top of casino JB ground surface
I Zl t
Date:
METHOD OF DRILLING: £1 air rotary D
D other
W/STEX. P&OIA.
USE OF WELL: D domestic D !rrto,atto» D
fS public supply D other
SILT
CASING STICK-UP:
Casing type:.
jt. Pierre jg in. to ft
.to ft
WATAft
V7
49
WELL INTAKE OPENING TYPE: el open end O screened
D perforated D open
73
Depths of openirtfls:
SCREEN TYPE:
Slot/Mesh Size:
AtA,
Diemr
in.
ft
GRAVEL PACK TYPE:
Volume used:
GROUT TYPE:
Depth; from-frrfflff^iftt
DEVELOPMENT METHOD!
Duration? -4
(£
-SI-
PUMPWG LEVa AND YIELDr *^- •.'-"
ft after -« hr»otw»flto»
>
-------
WELL LOG
U.S. PUBLIC HEALTH SERVICE, DIVISION OF INDIAN HEALTH
LOCATION
£T
DATE STARTED
/
DATE COMPLETED
9/
/
DRILLER
WELI
TOTAL DEPTH OF WELL 3
GROUT
FT. CASING INSTALLED
DIAMETER
SCREEN SIZE
LENGTH
DATE
SPECIAL NOTES:
GJ^SV *4*^-
¥'
fv c
£XA/-I>^
Ctfb^l
DEPTH
FROM - TO
FORMATION
STATIC WATER LEVEL I $f HRS. PUJIPED 3O @ J-S* GPM. DRAOTOW Q FI
DRILLER
e*
-i
m
O
~H
-------
ANCHORAGE, ALASKA 99509
BUSINESS PARK BLVD.
ANALYTICAL REPORT
CUSTOMER Alaska Area Native Health Service SAMPLE LOCATION:
DATE COLLECTED 8-27-78 TIME COLLECTED:
SAMPLED BY Tom Bol
REMARKS Treatment
en SOURCE Community Well
: None. Preservation: None. Color: Clear.
Taste: Good. Smell: None.
[]Ag
[]A1
[]As
[]Au
[]B.
[]Ba
[]B1
[]Ca
[]Cd
[]Co
[]Cr
[]Cu
[]Fe
[]Hg
[]K.
[]Mg
[]Mn
[]Mo
[]Na
[]Ni
m
.Silver
.Aluminum
.Arsenic
.Gold
Boron
.Barium
.Bismuth
.Calcium
.Cadmium
.Cobalt
.Chromium
.Copper
.Iron
.Mercury
Potassium
.Magnesium
.Manganese
.Molybdenum
.Sodium
.Nickel
3/1 mg/1
<0.01 []P, Phosphorous
[JPb.Lead ^0.02
<^0.01 []Pt, Platinum
[]Sb, Antimony
[]Se, Selenium <0.01
<0.1 []Si, Silicon
[]Sn,Tin
59 []Sr, Strontium
<0.01 []T1, Titanium
[]W, Tungsten
< 0.01 []V, Vanadium
^0.01 []Zn,Zinc <0.01
0.02 []Zr, Zirconium
<0.002 [] Ammonia
Nitrogen-N
-<0.1 []Kjedahl
Nitrogen-N
9.9 []Nitrate-N 0.17
^0.01 []Nitrite-N
[]Phosphorus
(Ortho)-P
1.4 []Chloride 2
[]Fluoride
Allakaket, Alaska
FOR LAB USE ONLY
RECVD.BY SE LAB # 8605
DATE RECEIVED 8-30-78
DATE COMPLETED- 9-6-78
DATE REPORTED 9-7-78
SIGNED ^^xA_JL s*f M&S+-,
mg/1
[]Cyanide
[]Sulfate 25
[]Phenol
[]Total Dissolved 218
Solids
[]Total Volatile
Solids
[]Suspended
Solids
[]Volatile Sus-
pended Solids
[]Hardness as 188
CaCOo
[]Alkalinity as 166
CaCOs
n
n
n
******
[]mmhos Conductivity 310
[]pH Units 7.3
[]Turbidity NTU 3
[]Color Units ^
[]T.Coliform/100ml Sb
[] i.
-------
APPENDIX B
FIELD LOGS
-------
APPENDIX B.i.
EKWOK FIELD LOGS
-------
Shaw Alaska, Inc.
LOG OF EXPLORATORY BORING
OTHER
i
BOREHOLE /WELL/ |
w
^
S
s
<.&.
*\
^
PIEZOMETER DETAILS
^
^
»^-
a '
A
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^
£0
33V
^
SAMPLE NUMBER
-M--'
SAMPLE METHOD
\l-t\n*
e>R-c*
i**!*
U.C<
Qc^
BLOWS/ 6"
1
tf i,a/
lid
x &-£.
RECOVERY
A
ts>(>5
INTERVAL SAMPLED
CLIENT/PROJECT RARE - /\K T-U Li1 BORING NOfkWP^l
PERSONNEL VMxyt«. C^f . SuA 3c~ts, ^i'^^^: SHEET I OF \
DEPTH IN FEET
- Li -
^T
- (n -
- Jo .
SOIL GROUP
USCS SYMBOL
WATER LEVEL DATA
DEPTH A/^ 6 ' DATUM:
LITHOLOGIC DESCRIPTION
f-L^i C^.Wv^ Sai.mSjV
Sol.Vvf 4"|S"S
C.-^iv-l'- , ^'ll^j ^ie.-1-C.
a I. , c- <^\-> 1 £ ^ I" > "-^~
d-tL^^i. *-tt* St«*vHv.
150# HAMMER 300# HAMMER =1.5" ID SPLIT BARREL SAMPLER =3" ID SPLIT BARREL SAMPLER
-------
Shaw Alaska, Inc.
LOG OF EXPLORATORY BORING
OTHER
BOREHOLE /WELL/
PIEZOMETER DETAILS
W#
'
$\*>
§
V'W
ji
'. A
RJ
J
SAMPLE NUMBER
,«
^;
*^U
Of*
SAMPLE METHOD
JS
j/
BLOWS/ 6"
A
,4
RECOVERY
INTERVAL SAMPLED
CLIENT/PROJECT RA-Rt ~AK T^Ui if" BORING NO. EKWP2.<^2_
PERSONN
DEPTH IN FEET
- a.
7 _
5.
S_
L GROUP
CS SYMBOL
O / oi.vUitol: SHEET i OF /
WATER LEVEL DATA
3EPTH No i*AMH*f *— ' o "^5 bft£
DATE ^1
-------
LOG OF
OTHER
Shaw Alaska, Inc.
EXPLORATORY BORING
BOREHOLE / WELL /
PIEZOMETER DETAILS
*l
1
v&
w
-Vt*1
'
''
'
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m
it?T*
SAMPLE NUMBER
^V
*>uf
__sot
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SAMPLE METHOD
^A!)
W-
:;V
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BLOWS/ 6"
A
cW
RECOVERY
u^<-
INTERVAL SAMPLED
CLIENT/PROJECT ft A (VB - A k. T^:UJ L F- BORING NO^kWP^^S
PERSONN
H
UJ
UJ
LL
•z.
£
UJ
0
0_
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- >
3
4.
- t J
b
SOIL GROUP
USCS SYMBOL
ELW^^CopfXei/^'t-^^CJ:* W.-£u>ii SHEET 1 OF 1
WATER LEVEL DATA
DEPTH k}o icafe*/- Qfl-'S ' tfjS
DATE O'jOlO'l
TIME , iV.iO
BORING DEPTH ^/ GROUND ELEVATION
CASING DEPTH 5"' DATUM:
LITHOLOGIC DESCRIPTION
^t_ *-*-4-
C>1^CV"A'
\
^tW<,^ ^ S
REMARKS:
150# HAMMER 300# HAMMER =1.5" ID SPLIT BARREL SAMPLER =3" ID SPLIT BARREL SAMPLER
-------
EKWPZ01
EKWPZ02
-------
EKWPZ03
-------
APPENDIX B.ii.
EEK FIELD LOGS
-------
LOG OF
OTHER
Shaw Alaska, Inc.
EXPLORATORY BORING
BOREHOLE / WELL /
PIEZOMETER DETAILS
1
*"9*
1 —
V>
^J
w— '
]s
v>\
s
SAMPLE NUMBER
"~'V
-*y»
-^
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SAMPLE METHOD
:i V«
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BLOWS/ 6"
U^>
RECOVERY
"0
INTERVAL SAMPLED
CLIENT/PROJECT I^A^E" A K T^;L\ LP BORINGNO. £fcKP'20j_
PERSONNELVvW^_ C-opJ/^^klu^i ^H f SHEET i OF I
DEPTH IN FEET
1
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A
• \ ~
1_
A.
T
L GROUP
3S SYMBOL
O 00
CO 3
^ Of
\
WATER LEVEL DATA
DEPTH 2.'' Uji 'V.C'V OH*)
DATE t'iitG'j i-'-llllj'l
TIME , jS.ljffi1'*' 1S!M
BORING DEPTH 5"' s" GROUND ELEVATION
CASING DEPTH S" ' S'/ DATUM:
LITHOLOGIC DESCRIPTION
^ ' jjil i*/«J-«v
-------
Shaw Alaska, Inc.
LOG OF EXPLORATORY BORING
BOREHOLE /WELL/
PIEZOMETER DETAILS
SAMPLE NUMBER
SAMPLE METHOD
BLO
RECO
ERVAL SAMPLED
CLIENT/PROJECT
BORING NO..
SHEET i
OF 1
DEPTH
DEPTH
DATE
%g
op
^
=! O
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CO 3)
BORING DEPTH
WATER LEVEL DATA
IME
ASING DEPTH
il'.US"
ff',,
S.oJ ; (£>
•^tf* (V
5"'
GROUND ELEVATION,
DATUM:
LITHOLOGIC DESCRIPTION
-------
Shaw Alaska, Inc.
LOG OF EXPLORATORY BORING
OTHER
BOREHOLE /WELL/
PIEZOMETER DETAI
E NUMBER
SAMP
RECOVERY
ERVAL SAMPLED
CLIENT/PROJECT
LP
PERSONNEL^'cvy,
DEPTH
DATE
95°,
Oi
§£
=1 O
O CO
CO 3
TIME
BORING DEPTH
WATER LEVEL DATA
ASING DEPTH
1/tl/fc-i
'(,,. ,j
4" ' b:, c,
S'.i'otuJ
4 • t
Iltl/Qj
BORING N0._
SHEET I
OF \
GROUND ELEVATION^
DATUM:
LiTHooGic DESCRIPTION
1
dis"s
-Vcp
C3'
\ G>^V oU
" .'IX
\
0
I
\-\
REMARKS:
150# HAMMER
300# HAMMER
=1.5" ID SPLIT BARREL SAMPLER
=3" ID SPLIT BARREL SAMPLER
-------
LOG
OTHER
Shaw Alaska, Inc.
OF EXPLORATORY BORING
BOREHOLE / WELL /
V«
",A^
(
f
=
Cu
»x
PIEZOMETER DETAILS I
S
x-^"
^~"
j*i
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SAMPLE NUMBER
•11
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SAMPLE METHOD
V*^<
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^/v-"-/r
xcYS
\f+- \
BLOWS/ 6"
cV
RECOVERY
^
INTERVAL SAMPLED
CLIENT/PROJECT KA-&t-AK ^.'Ul LF BORING NO. ^k Pi0"4-
PERSONNELW;^^ C/sjd/SLck S*.*-*, ^ciK? SHEET \ OF |
H
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L GROUP
DS SYMBOL
O C/3
co Z)
WATER LEVEL DATA
DEPTH t* -L. ll t S ^ kf
DATE 'Uil(O*i l/VI/^j
TIME v lo : i>o j"f :?>X
BORING DEPTH ^/i' 4.?' GROUND ELEVATION
CASING DEPTH i 1 ' 3.5"' DATUM:
LITHOLOGIC DESCRIPTION
-«f w • -w, U,f^ pc> <^,->.^ . t.OO'
rv / /"' (^ 1 \ it 1 1 A ' 1")
'^v 0 £> -V vu'ixl-ty* •« \^, KM^i 1 t^'t* | *T . ^ •>» .
REMARKS:
150# HAMMER 300# HAMMER =1.5" ID SPLIT BARREL SAMPLER =3" ID SPLIT BARREL SAMPLER
-------
EEKPZ01
EEKPZ02
-------
EEKPZ03
EEKPZ04
-------
APPENDIX B.iii.
WHITE MOUNTAIN FIELD LOGS
-------
Shaw Alaska, Inc.
LOG OF EXPLORATORY BORING
DETAI
BOREHOLE
PIEZOMETE
BLO
RY
RECO
ERVA
CLIENT/PROJECT_
PERSONNEL & £
o 5
§1
=! o
O CO
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WATER LEVEL DATA
IME
ASING DEPTH
,<8 ir
GROUND ELEVATION,
DATUM:
TlTHOLOGIC
REMARKS:
150# HAMMER
300# HAMMER
=1.5" ID SPLIT BARREL SAMPLER
=3" ID SPLIT BARREL SAMPLER
-------
1."
Shaw" Alaska, Inc.
LOG OF EXPLORATORY BORING
OTHER
r
.''
BOREHOLE / WELL /
PIEZOMETER DETAILS
SAMPLE NUMBER
SAMPLE METHOD
CD
O
CD
RECOVERY
INTERVAL SAMPLED
CLIENT/PROJECT ! t?^"1 "^ &f>* BORING NO.WXT P'2-.<*^-
PERSONN
i-
LU
LU
U.
z
CL
LU
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SOIL GROUP
USCS SYMBOL
EL /3fU fail**' ^^^ Cv^r» SHEET ] OF >
WATER LEVEL DATA
DEPTH .-
DATE ^J ^[i'lfO'l
TIME/^^i-K i~>^> ^^.T^-^
Bo'RiiTc§'olpTH~~" % 3 GROUND ELEVATION C As<- }
CASING DEPTH i-3'K . DATUM:
t^3 ft,4i^ ¥* fit LITHOLOGIC DESCRIPTION
/(. / .; £ M r - / ^ "^ ^'^""-^
REMARKS:
150# HAMMER 300# HAMMER =1.5" ID SPLIT BARREL SAMPLER =3" ID SPLIT BARREL SAMPLER
-------
WMTPZ-01
I
WMTPZ02
-------
WMTSUMP01
-------
APPENDIX B.iv.
FORT YUKON FIELD LOGS
-------
1AA--
ShawK Alaska, Inc.
LOG OF EXPLORATORY BORING
CLIENT/PROJECT,
PERSONNEL J^T
r-,
\
-------
Shaw Alaska, Inc.
LOG OF EXPLORATORY BORING
OTHER
BOREHOLE /WELL/
PIEZOMETER DETAILS
NUMBER
SAM
METHOD
MP
RECO
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CLIENT/PROJECT
tu£r<
BORING NO.
PERSONNEL
DEPTH
DATE
TIME
=! O
O CO
co o
WATER LEVEL DATA
BORING DEPTH
ASING DEPTH
12-30
SHEET / OF
GROUND ELEVATION.
DATUM:
LITHOLOGIC DESCRIPTION
2*
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REMARKS:
150# HAMMER 300# HAMMER =1.5" ID SPLIT BARREL SAMPLER =3" ID SPLIT BARREL SAMPLER
-------
LOG
OTHER
V**
Shaw9" Alaska, Inc.
OF EXPLORATORY BORING
BOREHOLE /WELL/
PIEZOMETER DETAILS
.
S**'
tf
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^M^ BORING NO. /< v ^3"
PERSONNEL vj J ~ /X> SHEET. / OF /
DEPTH IN FEET
- J. -
X
L GROUP
3S SYMBOL
O <. w^.i_ u^i -X \u" cJ-co^
6 /^XMb „ u>-cll O^y
C/ 3^/10 - U^U ^>
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K&s^l @ 2^^
REMARKS:
_ s
150# HAMMER 300# HAMMER =1.5" ID SPLIT BARREL SAMPLER =3" ID SPLIT BARREL SAMPLER
-------
I.1!1.
\\
£,
- , t*
JP •
Shaw Alaska, Inc.
LOG OF EXPLORATORY BORING
OTHER
/*
)>
tj?
)
/
\^
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BOREHOLE / WELL /
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SAMPLE NUMBER
- l><
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INTERVAL SAMPLED
CLIENT/PROJECT K/V'Nt BORING NO. ' ^ ' ^
PERSONN
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UJ
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z
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3S SYMBOL
O L£--^J_
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£j j»* <5 ^ C—
t- v*% *" *"
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REMARKS:
150# HAMMER 300# HAMMER =1.5" ID SPLIT BARREL SAMPLER =3" ID SPLIT BARREL SAMPLER
-------
FYUPZ01
-------
FYUPZ03
FYUPZ04
.
•' i .&i '*
-------
APPENDIX B.v.
ALLAKAKET FIELD LOGS
-------
Shaw Alaska, Inc.
LOG OF EXPLORATORY BORING
OTHER
^
<;<•-**
BOREHOLE / WELL /
PIEZOMETER DETAILS
-
*
OJ
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1
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REMARKS:
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£4
-------
3/4-
LOG
OTHER
^^
IL-T ^
•"
/
Shaw Alaska, Inc.
OF EXPLORATORY BORING
BOREHOLE / WELL /
PIEZOMETER DETAILS
^
SAMPLE NUMBER
I ,oC
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f
SAMPLE METHOD
P^"
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RECOVERY
!»(,.«.
INTERVAL SAMPLED
wtfA-r-
CLIENT/PROJECT K/VR b BORING NO. A; ^T (P ^r2-
PERSONNEL "S3 j L^ft, P^^ V*^ SHEET I OF '
DEPTH IN FEET
"-
SOIL GROUP
uses SYMBOL
WATER LEVEL DATA
DEPTH
DATE 7/7/10
TIME
BORING DEPTH GROUND ELEVATION * I # (M-
CASING DEPTH DATUM:
LITHOLOGIC DESCRIPTION
Pny-^vCrvvV i 1. ^ - \. $5 ^f tg5
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I C* v>-C-/~ Si'VTA,*^- fe^yO ^^A IM.*/W\
-------
/LA!
-------
Shaw Alaska, Inc.
LOG OF EXPLORATORY BORING
OTHER
—
S"
BOREHOLE / WELL /
__-^ -
3
it
PIEZOMETER DETAILS
t :
1
*J t
SAMPLE NUMBER
t~N^
- Pc~
SAMPLE METHOD
£FVX\TZ-
-Cr«Si
BLOWS/ 6"
**j&
RECOVERY
INTERVAL SAMPLED
CLIENT/PROJECT I^™A/L fe BORING NO. 4 £T P* - <*'!,
PERSONNEL L^"2> j ^. P<*,^ -l/e^t" SHEET 1 OF '
H
UJ
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3S SYMBOL
O *V ^ ot 6' C.L 6*,s
p^-Lj, f;^ _i:l Z.P4- ^W^j^iS^^
^Uc\^ck ^fle Up U> 5>^^ <^l)t~-^e~~4 £^tx^v Ijo4o^^
7/e/^ ' G"> _,_U,U-
7/«Ho- 6-7" ^^ ^^^ (7/6/1"'-
/ i"~ti-y ie ^'^^^^
. , i i f-^v-^,1 ,'^«Jl>"Xc-Crx
7/ ft u«vs
-------
AETPZ01
AETPZ02
-------
AETPZ03
AETSUMP01
-------
AETSUMP02
-------
APPENDIX C
SGS ANALYTICAL REPORTS
-------
SGS North America Inc.
Alaska Division
Level II Laboratory Data Report
Project: RARE-AKTribal Landfill Sept.09
Client: Shaw Env & Infrastructure Inc.
SGS Work Order: 1094697
Released by:
Contents:
Cover Page
Case Narrative
Final Report Pages
Quality Control Summary Forms
Chain of Custody/Sample Receipt Forms
Note:
Unless otherwise noted, all quality assurance/quality control criteria is in compliance with the standards set forth by the proper regulatory authority, the
SGS Quality Assurance Program Plan, and the National Environmental Accreditation Conference.
-------
Case Narrative
Client SHAWENV
Workorder 1094697
Sample ID
Shaw Env & Infrastructure Inc.
RARE-AKTribal Landfill Sept.09
Client Sample ID
Printed Date/Time 9/30/2009 9:54
Refer to the sample receipt form for information on sample condition.
1094697001 PS 0909ERNOBPWG401
2320B - Alkalinity RPD was outside of QC criteria. The result for the sample and duplicate is less than the PQL.
922277 LCSD LCSD for HBN 219718 [XXX/21596
8270D- LCS/LCSD RPD for pyridine does not meet QC criteria. This analyte was not detected above the PQL in the
associated samples.
924651 DUP 0909ERNOBPWG401(1094697001DUP)
2320B - Alkalinity RPD was outside of QC criteria. The result for the sample and duplicate is less than the PQL.
-------
Laboratory Analysis Report
200 W. Potter Drive
Anchorage, AK 99518-1605
Tel: (907) 562-2343
Fax:(907)561-5301
Web: http://www.us.sgs.com
Wayne Coppel
Shaw Env & Infrastructure Inc.
2000 W.Int'l Airport, SteCl
Anchorage, AK 995 02
Work Order: 1094697
RARE-AKTribal Landfill Sept. 09 Released by:
Client: Shaw Env & Infrastructure Inc.
Report Date: September 30,2009
Enclosed are the analytical results associated with the above workorder.
As required by the state of Alaska and the USEPA, a formal Quality Assurance/Quality Control Program is maintained by SGS. A
copy of our Quality Assurance Plan (QAP), which outlines this program, is available at your request.
The laboratory certification numbers are AK971-05 (DW), UST-005 (CS) and AK00971 (Micro) for ADEC and AK100001 for
NELAP (RCRA methods: 1020A, 1311, 6010B, 7470A, 7471A, 9040B, 9045C, 9056, 9060, 9065, 8015B, 8021B, 8081A/8082,
8260B, 8270C).
Except as specifically noted, all statements and data in this report are in conformance to the provisions set forth by the SGS QAP,
the National Environmental Laboratory Accreditation Program and, when applicable, other regulatory authorities.
If you have any questions regarding this report or if we can be of any other assistance, please contact your SGS Project Manager at
907-562-2343. All work is being provided under SGS general terms and conditions
(http://www.sgs.com/terms_and_conditions.htm) unless other written agreements have been accepted by both parties.
PQL Practical Quantitation Limit (reporting limit).
U Indicates the analyte was analyzed for but not detected.
F Indicates value that is greater than or equal to the MDL.
J The quantitation is an estimation.
ND Indicates the analyte is not detected.
B Indicates the analyte is found in a blank associated with the sample.
* The analyte has exceeded allowable regulatory or control limits.
GT Greater Than
D The analyte concentration is the result of a dilution.
LT Less Than
! Surrogate out of control limits.
Q QC parameter out of acceptance range.
M A matrix effect was present.
JL The analyte was positively identified, but the quantitation is a low estimation.
E The analyte result is above the calibrated range.
R Rejected
Note: Sample summaries which include a result for "Total Solids" have already been adjusted for moisture content.
SGS North America Inc.
200 W. Potter Dr. Anchorage AK. 99518-1605 t (907) 562-2343 fY90T) 561-5301 www.us.sgs.com
-------
Detectable Results Summary
Print Date: 9/30/2009 9:54 am
Client Sample ID: 0909ERWHBPWG401
SGSRef. #: 1094697002
Waters Department
Parameter
TPH Silica Gel HEM
Total Organic Carbon
Result
5.53
3.77
Units
mg/L
mg/L
SGS North America Inc. Alaska D ivision 200 West Potter Drive Anchorage Alaska 995 1 8
MemberofSGS Group(Societe Gene rale de Surveillance)
-------
SGSRef.# 1094697001
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal
Landfill Sept,
.09
Client Sample ID 0909ERNOBP WG40 1
Matrix Water (Surface, Eff., Ground)
Location/Well ID ERNOBP
Sample Remarks:
2320B - Alkalinity RPD was outside
Parameter
Metals Department
Mercury
Waters Department
Alkalinity
Total Dissolved Solids
TPH Silica Gel HEM
Total Organic Carbon
Semivolatile Organic GC/MS
N-Nitrosodimethylamine
Aniline
Phenol
Bis(2-Chloroethyl)ether
2-Chlorophenol
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
Benzyl alcohol
1 ,2-Dichlorobenzene
2-Methylphenol (o-Cresol)
Bis(2chloro 1 methylethyl)Ether
3&4-Methylphenol (p&m-Cresol)
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
of QC criteria. The result for the
Results
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
PQL
0.200
10.0
10.0
4.44
0.500
0.0110
0.0549
0.0110
0.0110
0.0110
0.0110
0.0110
0.0110
0.0110
0.0110
0.0110
0.0220
0.0110
0.0110
0.0110
0.0110
0.0110
sample
Units
ug/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Printed Date/Time
Collected
Received
Date/Time
Date/Time
Technical Director
and duplicate is less than the
Method
Container ID
SW7470A/E245.1 A
SM20 2320B
SM20 2540C
EPA 1664A
SM5310B
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
C
C
D
B
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
09/30/2009
9:54
09/03/2009 16:00
09/04/2009 12:35
Stephen C. Ede
PQL.
Allowable Prep
Limits Date
09/10/09
09/17/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
Analysis
Date init
09/11/09 KAR
09/17/09 MPL
09/09/09 OLT
09/17/09 RTS
09/11/09 KAR
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
-------
SGSRef.# 1094697001
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal Landfill Sept.09
Client Sample ID 0909ERNOBP WG40 1
Matrix Water (Surface, Eff., Ground)
Location/Well ID ERNOBP
Parameter
Results
PQL
Units
Printed Date/Time
Collected Date/Time
Received Date/Time
Technical Director
09/30/2009 9:54
09/03/2009 16:00
09/04/2009 12:35
Stephen C. Ede
Allowable Prep Analysis
Method Container ID Limits Date Date m;t
Semivolatile Organic GC/MS
2,4-Dimethylphenol
Benzoic acid
Bis(2-Chloroethoxy)methane
1 ,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methyl phenol
2,4-Dichlorophenol
2-Methylnaphthalene
Hexachlorocyclopentadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethyl phthalate
Acenaphthylene
2,6-Dinitrotoluene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
2,4-Dinitrotoluene
Diethylphthalate
4-Chlorophenyl-phenylether
Fluorene
4-Nitroaniline
2-Methyl-4,6-dinitrophenol
N-Nitrosodiphenylamine
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.0110
0.0549
0.0110
0.0110
0.0110
0.0110
0.0110
0.0110
0.0110
0.0110
0.0330
0.0110
0.0110
0.0110
0.0110
0.0110
0.0110
0.0110
0.0110
0.0110
0.0549
0.0549
0.0110
0.0110
0.0110
0.0110
0.0110
0.0110
0.0549
0.0110
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
-------
SGSRef.# 1094697001
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal Landfill Sept.09
Client Sample ID 0909ERNOBP WG40 1
Matrix Water (Surface, Eff., Ground)
Location/Well ID ERNOBP
Parameter
Results
PQL
Units
Printed Date/Time 09/30/2009 9:54
Collected Date/Time 09/03/2009 16:00
Received Date/Time 09/04/2009 12:35
Technical Director Stephen C. Ede
Allowable Prep Analysis
Method Container ID Limits Date Date m;t
Semivolatile Organic GC/MS
4-Bromophenyl-phenylether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butylphthalate
Fluoranthene
Pyrene
Azobenzene
Butylbenzylphthalate
3,3-Dichlorobenzidine
Benzo(a)Anthracene
Chrysene
bis(2-Ethylhexyl)phthalate
di-n-Octylphthalate
Benzo[b]Fluoranthene
Benzo[k]fluoranthene
Benzo[a]pyrene
Indeno[l,2,3-c,d] pyrene
Dibenzo[a,h]anthracene
Benzo[g,h,i]perylene
Surrogates
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
Terphenyl-dl4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
63.4
68
68.9
74.9
81
101
0.0110
0.0110
0.0549
0.0110
0.0110
0.0110
0.0110
0.0110
0.0110
0.0110
0.0110
0.0110
0.0110
0.0110
0.0110
0.0110
0.0110
0.0110
0.0110
0.0110
0.0110
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
%
%
%
%
%
%
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F 21-88
F 28-97
F 41-110
F 50-110
F 45-124
F 52-135
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
-------
SGSRef.# 1094697002
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal
Landfill Sept.09
Client Sample ID 0909ERWHBP WG40 1
Matrix Water (Surface, Eff., Ground)
Location/Well ID ERWHBP
Printed Date/Time
Collected
Received
Date/Time
Date/Time
Technical Director
09/30/2009
9:54
09/03/2009 16:00
09/04/2009 12:35
Stephen C. Ede
Sample Remarks:
Parameter
Metals Department
Mercury
Waters Department
Alkalinity
Total Dissolved Solids
TPH Silica Gel HEM
Total Organic Carbon
Semivolatile Organic GC/MS
N-Nitrosodimethylamine
Aniline
Phenol
Bis(2-Chloroethyl)ether
2-Chlorophenol
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
Benzyl alcohol
1 ,2-Dichlorobenzene
2-Methylphenol (o-Cresol)
Bis(2chloro 1 methylethyl)Ether
3&4-Methylphenol (p&m-Cresol)
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
Results
ND
ND
ND
5.53
3.77
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
PQL
0.200
10.0
10.0
4.26
0.500
0.0109
0.0543
0.0109
0.0109
0.0109
0.0109
0.0109
0.0109
0.0109
0.0109
0.0109
0.0217
0.0109
0.0109
0.0109
0.0109
0.0109
Units
ug/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Method
Container ID
SW7470A/E245.1 A
SM20 2320B
SM20 2540C
EPA 1664A
SM5310B
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
C
C
E
B
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
Allowable Prep
Limits Date
09/10/09
09/17/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
Analysis
Date init
09/11/09 KAR
09/17/09 MPL
09/09/09 OLT
09/17/09 RTS
09/12/09 KAR
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
09/19/09 MCM
-------
SGSRef.# 1094697002
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal Landfill Sept.09
Client Sample ID 0909ERWHBP WG40 1
Matrix Water (Surface, Eff., Ground)
Location/Well ID ERWHBP
Parameter
Results
PQL
Units
Printed Date/Time
Collected Date/Time
Received Date/Time
Technical Director
09/30/2009 9:54
09/03/2009 16:00
09/04/2009 12:35
Stephen C. Ede
Allowable Prep Analysis
Method Container ID Limits Date Date m;t
Semivolatile Organic GC/MS
2,4-Dimethylphenol
Benzoic acid
Bis(2-Chloroethoxy)methane
1 ,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methyl phenol
2,4-Dichlorophenol
2-Methylnaphthalene
Hexachlorocyclopentadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethyl phthalate
Acenaphthylene
2,6-Dinitrotoluene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
2,4-Dinitrotoluene
Diethylphthalate
4-Chlorophenyl-phenylether
Fluorene
4-Nitroaniline
2-Methyl-4,6-dinitrophenol
N-Nitrosodiphenylamine
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.0109
0.0543
0.0109
0.0109
0.0109
0.0109
0.0109
0.0109
0.0109
0.0109
0.0326
0.0109
0.0109
0.0109
0.0109
0.0109
0.0109
0.0109
0.0109
0.0109
0.0543
0.0543
0.0109
0.0109
0.0109
0.0109
0.0109
0.0109
0.0543
0.0109
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
-------
SGSRef.# 1094697002
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal Landfill Sept.09
Client Sample ID 0909ERWHBP WG40 1
Matrix Water (Surface, Eff., Ground)
Location/Well ID ERWHBP
Parameter
Results
PQL
Units
Printed Date/Time 09/30/2009 9:54
Collected Date/Time 09/03/2009 16:00
Received Date/Time 09/04/2009 12:35
Technical Director Stephen C. Ede
Allowable Prep Analysis
Method Container ID Limits Date Date m;t
Semivolatile Organic GC/MS
4-Bromophenyl-phenylether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butylphthalate
Fluoranthene
Pyrene
Azobenzene
Butylbenzylphthalate
3,3-Dichlorobenzidine
Benzo(a)Anthracene
Chrysene
bis(2-Ethylhexyl)phthalate
di-n-Octylphthalate
Benzo[b]Fluoranthene
Benzo[k]fluoranthene
Benzo[a]pyrene
Indeno[l,2,3-c,d] pyrene
Dibenzo[a,h]anthracene
Benzo[g,h,i]perylene
Surrogates
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
Terphenyl-dl4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
53.8
59
65.6
76.3
90.9
87.7
0.0109
0.0109
0.0543
0.0109
0.0109
0.0109
0.0109
0.0109
0.0109
0.0109
0.0109
0.0109
0.0109
0.0109
0.0109
0.0109
0.0109
0.0109
0.0109
0.0109
0.0109
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
%
%
%
%
%
%
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F 21-88
F 28-97
F 41-110
F 50-110
F 45-124
F 52-135
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
-------
SGSRef.# 1094697003
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal
Landfill Sept.09
Client Sample ID 0909DIBLNK WG50 1
Matrix Water (Surface, Eff., Ground)
Location/Well ID DIBLNK
Printed Date/Time
Collected
Received
Date/Time
Date/Time
Technical Director
09/30/2009
9:54
09/03/2009 16:00
09/04/2009 12:35
Stephen C. Ede
Sample Remarks:
Parameter
Metals Department
Mercury
Waters Department
Alkalinity
Total Dissolved Solids
TPH Silica Gel HEM
Total Organic Carbon
Semivolatile Organic GC/MS
N-Nitrosodimethylamine
Aniline
Phenol
Bis(2-Chloroethyl)ether
2-Chlorophenol
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
Benzyl alcohol
1 ,2-Dichlorobenzene
2-Methylphenol (o-Cresol)
Bis(2chloro 1 methylethyl)Ether
3&4-Methylphenol (p&m-Cresol)
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
Results
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
PQL
0,
.200
10.0
10.0
4,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0
.55
.500
.0108
.0538
.0108
.0108
.0108
.0108
.0108
.0108
.0108
.0108
.0108
.0215
.0108
.0108
.0108
.0108
.0108
Units
ug/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Method
Container ID
SW7470A/E245.1 G
SM20 2320B
SM20 2540C
EPA 1664A
SM5310B
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
C
C
E
B
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
Allowable Prep
Limits Date
09/28/09
09/17/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
09/08/09
Analysis
Date
09/29/09
09/17/09
09/09/09
09/17/09
09/12/09
09/19/09
09/19/09
09/19/09
09/19/09
09/19/09
09/19/09
09/19/09
09/19/09
09/19/09
09/19/09
09/19/09
09/19/09
09/19/09
09/19/09
09/19/09
09/19/09
09/19/09
Init
KAR
MPL
OLT
RTS
KAR
MCM
MCM
MCM
MCM
MCM
MCM
MCM
MCM
MCM
MCM
MCM
MCM
MCM
MCM
MCM
MCM
MCM
-------
SGSRef.# 1094697003
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal Landfill Sept.09
Client Sample ID 0909DIBLNK WG50 1
Matrix Water (Surface, Eff., Ground)
Location/Well ID DIBLNK
Parameter
Results
PQL
Units
Printed Date/Time
Collected Date/Time
Received Date/Time
Technical Director
09/30/2009 9:54
09/03/2009 16:00
09/04/2009 12:35
Stephen C. Ede
Allowable Prep Analysis
Method Container ID Limits Date Date m;t
Semivolatile Organic GC/MS
2,4-Dimethylphenol
Benzoic acid
Bis(2-Chloroethoxy)methane
1 ,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methyl phenol
2,4-Dichlorophenol
2-Methylnaphthalene
Hexachlorocyclopentadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethyl phthalate
Acenaphthylene
2,6-Dinitrotoluene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
2,4-Dinitrotoluene
Diethylphthalate
4-Chlorophenyl-phenylether
Fluorene
4-Nitroaniline
2-Methyl-4,6-dinitrophenol
N-Nitrosodiphenylamine
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.0108
0.0538
0.0108
0.0108
0.0108
0.0108
0.0108
0.0108
0.0108
0.0108
0.0323
0.0108
0.0108
0.0108
0.0108
0.0108
0.0108
0.0108
0.0108
0.0108
0.0538
0.0538
0.0108
0.0108
0.0108
0.0108
0.0108
0.0108
0.0538
0.0108
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
-------
SGSRef.# 1094697003
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal Landfill Sept.09
Client Sample ID 0909DIBLNK WG50 1
Matrix Water (Surface, Eff., Ground)
Location/Well ID DIBLNK
Parameter
Results
PQL
Units
Printed Date/Time 09/30/2009 9:54
Collected Date/Time 09/03/2009 16:00
Received Date/Time 09/04/2009 12:35
Technical Director Stephen C. Ede
Allowable Prep Analysis
Method Container ID Limits Date Date m;t
Semivolatile Organic GC/MS
4-Bromophenyl-phenylether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butylphthalate
Fluoranthene
Pyrene
Azobenzene
Butylbenzylphthalate
3,3-Dichlorobenzidine
Benzo(a)Anthracene
Chrysene
bis(2-Ethylhexyl)phthalate
di-n-Octylphthalate
Benzo[b]Fluoranthene
Benzo[k]fluoranthene
Benzo[a]pyrene
Indeno[l,2,3-c,d] pyrene
Dibenzo[a,h]anthracene
Benzo[g,h,i]perylene
Surrogates
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
Terphenyl-dl4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
62.9
69.8
72.5
77.6
84.8
98.8
0.0108
0.0108
0.0538
0.0108
0.0108
0.0108
0.0108
0.0108
0.0108
0.0108
0.0108
0.0108
0.0108
0.0108
0.0108
0.0108
0.0108
0.0108
0.0108
0.0108
0.0108
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
%
%
%
%
%
%
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
SW8270D
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F
F 21-88
F 28-97
F 41-110
F 50-110
F 45-124
F 52-135
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
09/08/09 09/19/09 MCM
-------
SGS Ref.#
Client Name
Project Name/#
Client Sample ID
Matrix
Location/Well ID
1094697004
Shaw Env & Infrastructure Inc.
RARE-AKTnbal Landfill Sept.09
0909EEKPZ01WG001
Water (Surface, Eff., Ground)
PZ01
Printed Date/Time
Collected Date/Time
Received Date/Time
Technical Director
09/30/2009 9:54
09/11/2009 15:29
09/14/2009 13:40
Stephen C. Ede
Sample Remarks:
Parameter
Results PQL
Units Method
Container ID
Allowable Prep
Limits Date
Analysis
Date mit
Metals Department
Mercury
ND
0.200
ug/L
SW7470A/E245.1 A
09/23/09 09/23/09 KAR
-------
SGS Ref.#
Client Name
Project Name/#
Client Sample ID
Matrix
Location/Well ID
1094697005
Shaw Env & Infrastructure Inc.
RARE-AKTnbal Landfill Sept.09
0909EEKPZ02WG001
Water (Surface, Eff., Ground)
PZ02
Printed Date/Time
Collected Date/Time
Received Date/Time
Technical Director
09/30/2009 9:54
09/11/2009 15:55
09/14/2009 13:40
Stephen C. Ede
Sample Remarks:
Parameter
Results PQL
Units Method
Container ID
Allowable Prep
Limits Date
Analysis
Date mit
Metals Department
Mercury
ND
0.200
ug/L
SW7470A/E245.1 A
09/23/09 09/23/09 KAR
-------
SGSRef.# 1094697006
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTnbal Landfill Sept.09
Client Sample ID Blue Jug-Idaho
Matrix Water (Surface, Eff., Ground)
Printed Date/Time 09/30/2009 9:54
Collected Date/Time 08/24/2009 8:00
Received Date/Time 08/24/2009 8:30
Technical Director Stephen C. Ede
Sample Remarks:
Parameter
Metals by ICP/MS
Aluminum
Antimony
Arsenic
Barium
Beryllium
Boron
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Molybdenum
Nickel
Selenium
Silver
Sodium
Lhallium
Vanadium
Lin
Zinc
Bismuth
Potassium
Results
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
PQL
4.00
0.100
1.00
0.100
0.100
10.0
0.100
100
0.400
0.0400
0.200
40.0
0.200
40.0
0.100
0.100
0.400
2.00
0.0400
200
0.0400
2.00
0.400
2.00
0.100
100
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Allowable Prep Analysis
Method Container ID Limits Date Date
200. {
200. {
200. {
200. {
200. {
200. {
200. {
200. {
200. {
200. {
200. {
200. {
200. {
200. {
200. {
200. {
200. {
200. {
200. {
200. {
200. {
200. {
200. {
200. {
200. {
200. {
3 Low Level
I Low Level
I Low Level
3 Low Level
3 Low Level
I Low Level
I Low Level
3 Low Level
3 Low Level
I Low Level
I Low Level
3 Low Level
3 Low Level
I Low Level
I Low Level
3 Low Level
3 Low Level
I Low Level
I Low Level
3 Low Level
3 Low Level
I Low Level
I Low Level
3 Low Level
3 Low Level
I Low Level
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
A
08/27/09
08/27/09
08/27/09
08/27/09
08/27/09
08/27/09
08/27/09
08/27/09
08/27/09
08/27/09
08/27/09
08/27/09
08/27/09
08/27/09
08/27/09
08/27/09
08/27/09
08/27/09
08/27/09
08/27/09
08/27/09
08/27/09
08/27/09
08/27/09
08/27/09
08/27/09
Init
NRB
NRB
NRB
NRB
NRB
NRB
NRB
NRB
NRB
NRB
NRB
NRB
NRB
NRB
NRB
NRB
NRB
NRB
NRB
NRB
NRB
NRB
NRB
NRB
NRB
NRB
-------
SGS Ref.# 922275 Method Blank
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal Landfill Sept.09
Matrix Water (Surface, Eff , Ground)
Printed Date/Time
Prep Batch
Method
Date
09/30/2009 9:54
XXX21596
SW3520C
09/08/2009
QC results affect the following production samples:
1094697001, 1094697002, 1094697003
Parameter
Semi volatile Organic GC/MS
N-Nitrosodimethylamine
Aniline
Phenol
Bis(2-Chloroethyl)ether
2-Chlorophenol
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
Benzyl alcohol
1 ,2-Dichlorobenzene
2-Methylphenol (o-Cresol)
Bi s(2chloro 1 methyl ethy l)Ether
3&4-Methylphenol (p&m-Cresol)
N-Nitroso-di-n-propylamine
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Benzoic acid
Bis(2-Chloroethoxy)methane
1,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methylphenol
2,4-Dichlorophenol
2-Methylnaphthalene
Hexachlorocyclopentadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethylphthalate
Acenaphthylene
2,6-Dinitrotoluene
3-Nitroaniline
Results
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Reporting/Control
Limit
0.0100
0.0500
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0200
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0500
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0300
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
MDL
0.00310
0.0150
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00620
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.0250
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00940
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Analysis
Date
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
-------
SGS Ref.# 922275 Method Blank
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal Landfill Sept.09
Matrix Water (Surface, Eff , Ground)
Parameter
Semi volatile Organic GC/MS
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
2,4-Dinitrotoluene
Diethylphthalate
4-Chlorophenyl-phenyl ether
Fluorene
4-Nitroaniline
2-Methyl-4,6-dinitrophenol
N-Nitrosodiphenylamine
4-Bromophenyl-phenyl ether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butylphthalate
Fluoranthene
Pyrene
Azobenzene
Butylbenzylphthalate
3,3-Dichlorobenzidine
Benzo(a)Anthracene
Chrysene
bis(2-Ethylhexyl)phthalate
di-n-Octylphthalate
Benzo[b]Fluoranthene
Benzo[k]fluoranthene
Benzo[a]pyrene
Indeno[l,2,3-c,d] pyrene
Dibenzo[a,h]anthracene
Benzo[g,h,i]perylene
Surrogates
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
Results
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
61.2
68.4
70.8
76.9
89.6
Reporting/Control
Limit
0.0100
0.0500
0.0500
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0500
0.0100
0.0100
0.0100
0.0500
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
21-88
28-97
41-110
50-110
45-124
MDL
0.00310
0.0150
0.0150
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.0150
0.00310
0.00310
0.00310
0.0150
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
Printed Date/Time
Prep Batch
Method
Date
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
%
%
%
%
%
09/30/2009 9:54
XXX21596
SW3520C
09/08/2009
Analysis
Date
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
09/18/09
-------
SGS Ref.# 922275 Method Blank
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal Landfill Sept.09
Matrix Water (Surface, Eff, Ground)
Printed Date/Time
Prep Batch
Method
Date
09/30/2009 9:54
XXX21596
SW3520C
09/08/2009
Parameter
Results
Reporting/Control
T.imit
MDL
Units
Analysis
Date
Semivolatile Organic GC/MS
Terphenyl-dl4
Batch XMS5090
Method SW8270D
Instrument HP 5890 Series II MS4 SVPA
105
52-135
09/18/09
-------
SGS Ref.# 923028 Method Blank
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal Landfill Sept.09
Matrix Water (Surface, Eff, Ground)
Printed Date/Time
Prep Batch
Method
Date
09/30/2009 9:54
QC results affect the following production samples:
1094697001,1094697002, 1094697003
Parameter
Results
Reporting/Control
T.imit
MDL
Units
Analysis
Date
Waters Department
Total Dissolved Solids
Batch WAT7807
Method SM20 2540C
Instrument
ND
10.0
3.10
09/09/09
-------
SGSRef.# 923501 Method Blank
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal Landfill Sept.09
Matrix Water (Surface, Eff, Ground)
Printed Date/Time
Prep Batch
Method
Date
09/30/2009 9:54
QC results affect the following production samples:
1094697001
Parameter
Results
Reporting/Control
T.imit
MDL
Units
Analysis
Date
Waters Department
Total Organic Carbon
Batch WTC1931
Method SM5310B
Instrument TOC Analyzer
0.172J
0.500
0.150
09/11/09
-------
SGSRef.# 923515 Method Blank
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal Landfill Sept.09
Matrix Water (Surface, Eff, Ground)
Printed Date/Time
Prep Batch
Method
Date
09/30/2009 9:54
QC results affect the following production samples:
1094697001,1094697002, 1094697003
Parameter
Results
Reporting/Control
T.imit
MDL
Units
Analysis
Date
Waters Department
Total Organic Carbon
Batch WTC1931
Method SM5310B
Instrument TOC Analyzer
0.169J
0.500
0.150
09/12/09
-------
SGSRef.# 923521 Method Blank
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal Landfill Sept.09
Matrix Water (Surface, Eff , Ground)
Printed Date/Time 09/30/2009 9:54
Prep Batch MXX22208
Method METHOD
Date 09/10/2009
QC results affect the following production samples:
1094697001, 1094697002
Reporting/Control
Parameter Results Ljmjt MDL
Metals Department
Mercury ND 0.200 0.0620
Batch MCV4314
Method S W7470A/E245 . 1
Instrument PSA Millennium mercury AA
Analysis
Units Date
ug/L 09/11/09
-------
SGS Ref.# 924649 Method Blank
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal Landfill Sept.09
Matrix Water (Surface, Eff, Ground)
Printed Date/Time
Prep Batch
Method
Date
09/30/2009 9:54
QC results affect the following production samples:
1094697001,1094697002, 1094697003
Parameter
Results
Reporting/Control
T.imit
MDL
Units
Analysis
Date
Waters Department
Alkalinity
Batch
Method
Instrument
ND
10.0
3.10
09/17/09
WTI3186
SM20 2320B
-------
SGS Ref.# 924739 Method Blank
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal Landfill Sept.09
Matrix Water (Surface, Eff , Ground)
Printed Date/Time
Prep Batch
Method
Date
09/30/2009 9:54
TPHX1983
EXTJ664TP
09/17/2009
QC results affect the following production samples:
1094697001, 1094697002, 1094697003
Reporting/Control
Parameter Results Ljmjt MDL
Units
Analysis
Date
Waters Department
TPH Silica Gel HEM
Batch TPH2166
Method EPA 1664 A
Instrument
ND
4.00
1.20
09/17/09
-------
SGSRef.# 926319 Method Blank
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal Landfill Sept.09
Matrix Water (Surface, Eff , Ground)
Printed Date/Time 09/30/2009 9:54
Prep Batch MXX22266
Method METHOD
Date 09/23/2009
QC results affect the following production samples:
1094697004, 1094697005
Reporting/Control
Parameter Results Ljmjt MDL
Metals Department
Mercury ND 0.200 0.0620
Batch MCV4329
Method S W7470A/E245 . 1
Instrument PSA Millennium mercury AA
Analysis
Units Date
ug/L 09/23/09
-------
SGS Ref.#
Client Name
Project Name/#
Matrix
927678 Method Blank
Shaw Env & Infrastructure Inc.
RARE-AKTribal Landfill Sept.09
Water (Surface, Eff, Ground)
Printed Date/Time
Prep Batch
Method
Date
09/30/2009 9:54
MXX22299
METHOD
09/28/2009
QC results affect the following production samples:
1094697003
Parameter
Reporting/Control
Results T jrmt MDL
Units
Analysis
Date
Metals Department
Mercury
Batch MCV4342
Method S W7470A/E245.1
Instrument PSA Millennium mercury AA
ND
0.200
0.0620
ug/L
09/29/09
-------
SGS Ref.#
Client Name
Project Name/#
Matrix
927685 Method Blank
Shaw Env & Infrastructure Inc.
RARE-AKTribal Landfill Sept.09
Water (Surface, Eff, Ground)
Printed Date/Time
Prep Batch
Method
Date
09/30/2009 9:54
MXX22299
METHOD
09/28/2009
QC results affect the following production samples:
1094697003
Parameter
Reporting/Control
Results T jrmt MDL
Units
Analysis
Date
Metals Department
Mercury
Batch MCV4342
Method S W7470A/E245.1
Instrument PSA Millennium mercury AA
ND
0.200
0.0620
ug/L
09/29/09
-------
SGS Ref.# 923030 Duplicate
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal Landfill Sept.09
Original 1094697003
Matrix Water (Surface, Eff, Ground)
Printed Date/Time 09/30/2009 9:54
Prep Batch
Method
Date
QC results affect the following production samples:
1094697001, 1094697002, 1094697003
Original
Parameter Result
QC RPD Analysis
Result Umts RP0 Limits Date
Waters Department
Total Dissolved Solids
Batch WAT7807
Method SM20 2540C
Instrument
ND
ND mg/L
09/09/2009
-------
SGSRef.# 924651 Duplicate
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal Landfill Sept.09
Original 1094697001
Matrix Water (Surface, Eff, Ground)
Printed Date/Time 09/30/2009 9:54
Prep Batch
Method
Date
QC results affect the following production samples:
1094697001, 1094697002, 1094697003
Original
Parameter Result
QC RPD Analysis
Result Umts RP0 Limits Date
Waters Department
Alkalinity
Batch WTI3186
Method SM20 2320B
Instrument
ND
ND mg/L
09/17/2009
-------
SGS Ref.# 924652 Duplicate
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal Landfill Sept.09
Original 1094762001
Matrix Water (Surface, Eff, Ground)
Printed Date/Time 09/30/2009 9:54
Prep Batch
Method
Date
QC results affect the following production samples:
1094697002, 1094697003
Original
Parameter Result
QC RPD Analysis
Result Umts RP0 Limits Date
Waters Department
Alkalinity
Batch WTI3186
Method SM20 2320B
Instrument
100
100 mg/L
09/17/2009
-------
SGS Ref.# 922276 Lab Control Sample Printed Date/Time 09/30/2009
922277 Lab Control Sample Duplicate FreP Batch XXX21596
Client Name Shaw Env & Infrastructure Inc. Method SW3520C
Project Name/# RARE- AKTribal Landfill Sept.09 Date 09/08/2009
Matrix Water (Surface, Eff, Ground)
9:54
QC results affect the following production samples:
1094697001, 1094697002, 1094697003
Parameter
Semivolatile Organic GC/MS
N-Nitrosodimethylamine
Aniline
Phenol
Bis(2-Chloroethyl)ether
2-Chlorophenol
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
Benzyl alcohol
1 ,2-Dichlorobenzene
2-Methylphenol (o-Cresol)
Bis(2chlorolmethylethyl)Ether
3&4-Methylphenol (p&m-Cresol)
N-Nitroso-di-n-propylamine
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
QC
Results
0.0657
0.0638
0.0631
0.0532
0.0727
0.0667
0.0682
0.0653
0.0732
0.0713
0.0664
0.0659
0.0644
0.0659
0.0774
0.0732
0.0669
0.0667
0.0771
0.0740
0.0693
0.0692
0.114
0.108
0.0758
0.0738
Pet LCS/LCSD
Recov Limits RPD
66 (27-100)
64 3
63 (21-119)
53 17
73 ( 26-92 )
67 9
68 (37-100)
65 4
73 ( 37-97 )
71 3
66 ( 32-98 )
66 1
64 ( 32-97 )
66 2
77 (38-110)
73 6
67 ( 35-99 )
67 0
77 ( 38-99 )
74 4
69 (36-103)
69 0
81 (38-105)
77 5
76 (42-108)
74 3
RPD Spiked
Limits Amount
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.14
(<20) 0.14
0.1
(<20) 0.1
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Analysis
Date
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
-------
SGS Ref.# 922276 Lab Control Sample Printed Date/Time 09/30/2009
922277 Lab Control Sample Duplicate FreP Batch XXX21596
Client Name Shaw Env & Infrastructure Inc. Method SW3520C
Project Name/# RARE- AKTribal Landfill Sept.09 Date 09/08/2009
Matrix Water (Surface, Eff, Ground)
Parameter
QC
Results
Pet LCS/LCSD
Recov Limits RPD
RPD Spiked
Limits Amount
9:54
Analysis
Date
Semivolatile Organic GC/MS
Hexachloroethane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Benzoic acid
Bis(2-Chloroethoxy)methane
1 ,2,4-Trichlorobenzene
Naphthalene
4-Chloroaniline
Hexachlorobutadiene
4-Chloro-3-methylphenol
2,4-Dichlorophenol
2-Methylnaphthalene
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
0.0586
0.0578
0.0705
0.0700
0.0786
0.0758
0.0787
0.0777
0.0700
0.0701
0.0870
0.0825
0.0768
0.0736
0.0690
0.0693
0.0723
0.0718
0.0746
0.0652
0.0707
0.0696
0.0952
0.0903
0.0829
0.0798
0.0784
0.0774
59 ( 30-95 )
58 2
71 (45-105)
70 1
79 (50-110)
76 4
79 (40-109)
78 1
70 ( 32-86 )
70 0
62 (20-101)
59 5
77 (46-105)
74 4
69 (37-104)
69 0
72 (45-100)
72 1
75 (37-110)
65 13
71 (38-105)
70 2
95 (50-110)
90 5
83 (50-105)
80 4
78 (46-105)
77 1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.14
(<20) 0.14
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
-------
SGS Ref.# 922276 Lab Control Sample Printed Date/Time 09/30/2009
922277 Lab Control Sample Duplicate FreP Batch XXX21596
Client Name Shaw Env & Infrastructure Inc. Method SW3520C
Project Name/# RARE- AKTribal Landfill Sept.09 Date 09/08/2009
Matrix Water (Surface, Eff, Ground)
Parameter
QC
Results
Pet LCS/LCSD
Recov Limits RPD
RPD Spiked
Limits Amount
9:54
Analysis
Date
Semivolatile Organic GC/MS
Hexachlorocyclopentadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
2-Chloronaphthalene
2-Nitroaniline
Dimethylphthalate
Acenaphthylene
2,6-Dinitrotoluene
3-Nitroaniline
Acenaphthene
2,4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
2,4-Dinitrotoluene
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
0.0204
0.0235
0.0937
0.0894
0.0933
0.0884
0.0699
0.0675
0.0927
0.0870
0.0834
0.0792
0.0843
0.0815
0.0891
0.0865
0.0917
0.0863
0.0851
0.0834
0.0952
0.0971
0.130
0.115
0.0838
0.0819
0.0848
20 ( 10-58 )
24 14
94 (50-115)
89 5
93 (50-110)
88 5
70 (50-105)
68 4
93 (54-115)
87 6
83 (36-125)
79 5
84 (53-105)
82 3
89 (55-115)
87 3
92 (54-125)
86 6
85 (53-110)
83 2
53 (29-130)
54 2
93 (42-112)
82 13
84 (55-105)
82 2
85 (55-115)
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.18
(<20) 0.18
0.14
(<20) 0.14
0.1
(<20) 0.1
0.1
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
-------
SGS Ref.# 922276 Lab Control Sample Printed Date/Time 09/30/2009
922277 Lab Control Sample Duplicate FreP Batch XXX21596
Client Name Shaw Env & Infrastructure Inc. Method SW3520C
Project Name/# RARE- AKTribal Landfill Sept.09 Date 09/08/2009
Matrix Water (Surface, Eff, Ground)
Parameter
QC
Results
Pet LCS/LCSD
Recov Limits RPD
RPD Spiked
Limits Amount
9:54
Analysis
Date
Semivolatile Organic GC/MS
Diethylphthalate
4-Chlorophenyl-phenylether
Fluorene
4-Nitroaniline
2-Methyl-4,6-dinitrophenol
N-Nitrosodiphenylamine
4-Bromophenyl-phenylether
Hexachlorobenzene
Pentachlorophenol
Phenanthrene
Anthracene
Di-n-butylphthalate
Fluoranthene
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
0.0830
0.0821
0.0794
0.0804
0.0773
0.0874
0.0831
0.0923
0.0867
0.105
0.108
0.0855
0.0830
0.0758
0.0736
0.0867
0.0840
0.110
0.107
0.0909
0.0878
0.0909
0.0869
0.0827
0.0791
0.0890
0.0871
83 2
82 (51-120)
79 3
80 (50-110)
77 4
87 (56-110)
83 5
92 (52-120)
87 6
58 (43-130)
60 3
86 (53-110)
83 3
76 (52-110)
74 3
87 (54-110)
84 3
79 (51-115)
77 3
91 (58-115)
88 4
91 (59-110)
87 5
83 (55-115)
79 4
89 (59-115)
87 2
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.18
(<20) 0.18
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.14
(<20) 0.14
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
-------
SGS Ref.# 922276 Lab Control Sample Printed Date/Time 09/30/2009
922277 Lab Control Sample Duplicate FreP Batch XXX21596
Client Name Shaw Env & Infrastructure Inc. Method SW3520C
Project Name/# RARE- AKTribal Landfill Sept.09 Date 09/08/2009
Matrix Water (Surface, Eff, Ground)
Parameter
QC
Results
Pet LCS/LCSD
Recov Limits RPD
RPD Spiked
Limits Amount
9:54
Analysis
Date
Semivolatile Organic GC/MS
Pyrene
Azobenzene
Butylbenzylphthalate
3,3-Dichlorobenzidine
Benzo(a)Anthracene
Chrysene
bis(2-Ethylhexyl)phthalate
di-n-Octylphthalate
Benzo[b]Fluoranthene
Benzo[k]fluoranthene
Benzo[a]pyrene
Indeno[l,2,3-c,d] pyrene
Dibenzo[a,h]anthracene
Benzo [g,h,i] pery lene
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
0.0953
0.0922
0.0849
0.0824
0.0943
0.0905
0.0846
0.0786
0.0931
0.0883
0.0923
0.0892
0.0907
0.0862
0.0913
0.0879
0.0928
0.0905
0.106
0.105
0.109
0.107
0.0669
0.0644
0.0707
0.0684
0.0568
0.0543
95 (62-128)
92 3
85 (52-124)
82 3
94 (58-115)
91 4
85 (53-110)
79 8
93 (64-110)
88 5
92 (63-110)
89 4
91 (59-125)
86 5
91 (52-131)
88 4
93 (57-120)
91 3
106 (58-124)
105 0
109 (58-110)
107 2
67 (51-125)
64 4
71 (53-125)
68 3
57 (48-123)
54 4
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
-------
SGSRef.# 922276 Lab Control Sample Printed Date/Time 09/30/2009 9:54
922277 Lab Control Sample Duplicate FreP Batch XXX21596
Client Name Shaw Env & Infrastructure Inc. Method SW3520C
Project Name/# RARE- AKTribal Landfill Sept.09 Date 09/08/2009
Matrix Water (Surface, Eff, Ground)
Parameter
Semivolatile Organic GC/MS
Surrogates
2-Fluorophenol
Phenol-d6
Nitrobenzene-d5
2-Fluorobiphenyl
2,4,6-Tribromophenol
Terphenyl-dl4
QC
Results
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
Pet LCS/LCSD
Recov Limits RPD
60 (21-88)
59 2
70 ( 28-97 )
67 4
75 (41-110)
74 0
80 (50-110)
78 2
89 (45-124)
84 5
96 (52-135)
93 3
RPD Spiked Analysis
Limits Amount Date
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
09/19/2009
Batch XMS5090
Method SW8270D
Instrument HP 5890 Series II MS4 SVPA
-------
SGS Ref.# 923029 Lab Control Sample
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal Landfill Sept.09
Matrix Water (Surface, Eff, Ground)
Printed Date/Time 09/30/2009 9:54
Prep Batch
Method
Date
QC results affect the following production samples:
1094697001, 1094697002, 1094697003
QC Pet
Parameter Results Recov
Waters Department
Total Dissolved Solids LCS 405 98
Batch WAT7807
Method SM20 2540C
Instrument
LCS/LCSD RPD Spiked Analysis
Limits RPD Limits Amount Date
(75-125) 413 mg/L 09/09/2009
-------
SGS Ref.#
Client Name
Project Name/#
Matrix
923499 Lab Control Sample
Shaw Env & Infrastructure Inc.
RARE-AKTribal Landfill Sept.09
Water (Surface, Eff., Ground)
Printed Date/Time 09/30/2009
Prep Batch
Method
Date
9:54
QC results affect the following production samples:
1094697001
Parameter
QC Pet
Results Recov
LCS/LCSD RPD Spiked
Limits RPD Limits Amount
Analysis
Date
Waters Department
Total Organic Carbon
LCS 75.3
100
(90-110)
75 mg/L 09/11/2009
Batch WTC1931
Method SM5310B
Instrument XOC Analyzer
-------
SGSRef.# 923514 Lab Control Sample
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal Landfill Sept.09
Matrix Water (Surface, Eff, Ground)
Printed Date/Time 09/30/2009 9:54
Prep Batch
Method
Date
QC results affect the following production samples:
1094697001, 1094697002, 1094697003
QC Pet
Parameter Results Recov
Waters Department
Total Organic Carbon LCS 79.2 106
Batch WTC1931
Method SM5310B
Instrument XOC Analyzer
LCS/LCSD RPD Spiked Analysis
Limits RPD Limits Amount Date
(90-110) 75 mg/L 09/12/2009
-------
SGS Ref.# 923522 Lab Control
Sample
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal Landfill Sept.09
Printed Date/Time 09/30/2009
Prep Batch MXX22208
Method METHOD
Date 09/10/2009
9:54
Matrix Water (Surface, Eff, Ground)
QC results affect the following production samples:
1094697001, 1094697002
Parameter
Metals Department
Mercury LCS
Batch MCV4314
Method SW7470A/E245.1
Instrument p<=A Millennium mercurv A
QC Pet
Results Recov
4.18 105
A
LCS/LCSD RPD Spiked
Limits RPD Limits Amount
(85-115) 4 ug/L
Analysis
Date
09/1 1/2009
-------
SGS Ref.# 924650 Lab Control Sample
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal Landfill Sept.09
Matrix Water (Surface, Eff, Ground)
Printed Date/Time 09/30/2009 9:54
Prep Batch
Method
Date
QC results affect the following production samples:
1094697001, 1094697002, 1094697003
QC Pet
Parameter Results Recov
Waters Department
Alkalinity LCS 253 101
Batch WTI3186
Method SM20 2320B
Instrument
LCS/LCSD RPD Spiked Analysis
Limits RPD Limits Amount Date
(90-110) 250 mg/L 09/17/2009
-------
SGS Ref.# 924740 Lab Control Sample
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal Landfill Sept.09
Matrix Water (Surface, Eff, Ground)
Printed Date/Time 09/30/2009
Prep Batch TPHX1983
Method EXTJ664TP
Date 09/17/2009
9:54
QC results affect the following production samples:
1094697001, 1094697002, 1094697003
QC Pet
Parameter Results Recov
Waters Department
TPH Silica Gel HEM LCS 18.6 93
Batch TPH2166
Method EPA 1664A
Instrument
LCS/LCSD RPD Spiked
Limits RPD Limits Amount
(64-132) 20 mg/L
Analysis
Date
09/17/2009
-------
SGS Ref.# 926320 Lab Control
Sample
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AKTribal Landfill Sept.09
Printed Date/Time 09/30/2009
Prep Batch MXX22266
Method METHOD
Date 09/23/2009
9:54
Matrix Water (Surface, Eff, Ground)
QC results affect the following production samples:
1094697004, 1094697005
Parameter
Metals Department
Mercury LCS
Batch MCV4329
Method SW7470A/E245.1
Instrument p<=A Millennium mercurv A
QC Pet
Results Recov
3.86 96
A
LCS/LCSD RPD Spiked
Limits RPD Limits Amount
(85-115) 4 ug/L
Analysis
Date
09/23/2009
-------
SGS Ref.#
Client Name
Project Name/#
Matrix
927679 Lab
Control Sample
Shaw Env & Infrastructure Inc.
RARE-AKTribal Landfill Sept.09
Water (Surface,
Eff., Ground)
Printed Date/Time 09/30/2009
Prep Batch MXX22299
Method METHOD
Date 09/28/2009
9:54
QC results affect the following production samples:
1094697003
Parameter
QC Pet
Results Recov
LCS/LCSD RPD Spiked
Limits RPD Limits Amount
Analysis
Date
Metals Department
Mercury
Batch
Method
Instrument
MCV4342
SW7470A/E245.1
PSA Millennium me
LCS 4.22 105
^rr.nrv A A
(85-115) 4 ug/L
09/29/2009
-------
SGS Ref.#
Client Name
Project Name/#
Matrix
927686 Lab Control
Sample
Shaw Env & Infrastructure Inc.
RARE-AKTribal Landfill Sept.09
Printed Date/Time 09/30/2009
Prep Batch MXX22299
Method METHOD
Date 09/28/2009
9:54
Water (Surface, Eff., Ground)
QC results affect the following production samples:
1094697003
Parameter
QC Pet
Results Recov
LCS/LCSD RPD Spiked
Limits RPD Limits Amount
Analysis
Date
Metals Department
Mercury
Batch
Method
Instrument
LCS
MCV4342
SW7470A/E245.1
PSA Millennium mercurv A
3.91 98
A
(85-115) 4 ug/L
09/29/2009
-------
SGS Ref.# 923502 Matrix Spike
923503 Matrix Spike Duplicate
Original 1094697001
Matrix Water (Surface, Eff., Ground)
Printed Date/Time
Prep Batch
Method
Date
09/30/2009 9:54
QC results affect the following production samples:
1094697001, 1094697002
Original QC Pet MS/MSD
Parameter Qualifiers Result Result Recov Limits
Waters Department
Total Organic Carbon MS ND 10.5 105 (75-125)
MSB 10.8 108
RPD
RPD Limits
3 (<25)
Spiked Analysis
Amount Date
10.0 mg/L 09/1 1/2009
10.0 mg/L 09/1 1/2009
Batch WTC1931
Method SM5310B
Instrument TOC Analyzer
-------
SGS Ref.# 923508 Matrix Spike
923509 Matrix Spike Duplicate
Original 1094697002
Matrix Water (Surface, Eff., Ground)
Printed Date/Time
Prep Batch
Method
Date
09/30/2009 9:54
QC results affect the following production samples:
1094697002, 1094697003
Original QC Pet MS/MSD
Parameter Qualifiers Result Result Recov Limits
Waters Department
Total Organic Carbon MS 3.77 12.8 91 (75-125)
MSB 12.7 89
RPD
RPD Limits
1 (<25)
Spiked Analysis
Amount Date
10.0 mg/L 09/12/2009
10.0 mg/L 09/12/2009
Batch WTC1931
Method SM5310B
Instrument TOC Analyzer
-------
SGS Ref.# 923523 Matrix Spike
Original 1094677002
Matrix Water (Surface, Eff, Ground)
Printed Date/Time 09/30/2009 9:54
Prep Batch MXX22208
Method Digestion Mercury (W)
Date 09/10/2009
QC results affect the following production samples:
1094697001, 1094697002
Original QC
Parameter Qualifiers Result Result
Metals Department
Mercury MS ND 8.42
Batch MCV4314
Method SW7470A/E245.1
Instrument PSA Millennium mercury AA
Pet MS/MSD RPD Spiked Analysis
Recov Limits RPD Limits Amount Date
105 (85-115) goo ug/L 09/1 1/2009
-------
SGSRef.# 923524 Matrix Spike Printed Date/Time
923525 Matrix Spike Duplicate FreP Batch
Method
Date
Original 1094455001
Matrix Water (Surface, Eff, Ground)
09/30/2009 9:54
MXX22208
Digestion Mercury (W)
09/10/2009
QC results affect the following production samples:
1094697001, 1094697002
Original QC Pet MS/MSD RPD
Parameter Qualifiers Result Result Recov Limits RPD Limits
Metals Department
Mercury MS ND 8.3 104 (85-115)
MSD 9.06 113 9 (< 15 )
Batch MCV4314
Method SW7470A/E245.1
Instrument PSA Millennium mercury AA
Spiked Analysis
Amount Date
8.00 ug/L 09/1 1/2009
8.00 ug/L 09/1 1/2009
-------
SGS Ref.# 924742 Matrix Spike
Original 924738
Matrix Water (Surface, Eff., Ground)
Printed Date/Time 09/30/2009 9:54
Prep Batch TPHX1983
Method Extraction for EPA 1 664 TPH S
Date 09/17/2009
QC results affect the following production samples:
1094697001, 1094697002, 1094697003
Original QC
Parameter Qualifiers Result Result
Waters Department
TPH Silica Gel HEM MS ND 18.4
Batch TPH2166
Method EPA 1664A
Pet MS/MSD RPD Spiked Analysis
Recov Limits RPD Limits Amount Date
87 (64-132) 21.3 mg/L 09/17/2009
Instrument
-------
SGS Ref.# 926321 Matrix Spike
Original 926315
Matrix Water (Surface, Eff., Ground)
Printed Date/Time
Prep Batch
Method
Date
09/30/2009 9:54
MXX22266
Digestion Mercury (W)
09/23/2009
QC results affect the following production samples:
1094697004, 1094697005
Original QC
Parameter Qualifiers Result Result
Pet MS/MSD RPD
Recov Limits RPD Limits
Spiked Analysis
Amount Date
Metals Department
Mercury MS 0.704
Batch MCV4329
Method SW7470A/E245.1
Instrument PSA Millennium mercury AA
6.65
74* (85-115)
8.00 ug/L 09/23/2009
-------
SGSRef.# 926322 Matrix Spike Printed Date/Time
926323 Matrix Spike Duplicate FreP Batch
Method
Date
Original 1094652001
Matrix Solid/Soil (Wet Weight)
09/30/2009 9:54
MXX22266
Digestion Mercury (W)
09/23/2009
QC results affect the following production samples:
1094697004, 1094697005
Original QC Pet MS/MSD RPD
Parameter Qualifiers Result Result Recov Limits RPD Limits
Metals Department
Mercury MS ND 77.4 97 (85-115)
MSB 78.9 99 2 (< 15 )
Batch MCV4329
Method SW7470A/E245.1
Instrument PSA Millennium mercury AA
Spiked Analysis
Amount Date
80.0 ug/L 09/23/2009
80.0 ug/L 09/23/2009
-------
SGS Ref.# 927681 Matrix Spike
927682 Matrix Spike Duplicate
Original 1095908001
Matrix Water (Surface, Eff, Ground)
Printed Date/Time
Prep Batch
Method
Date
09/30/2009 9:54
MXX22299
Digestion Mercury (W)
09/28/2009
QC results affect the following production samples:
1094697003
Original QC Pet MS/MSD
Parameter Qualifiers Result Result Recov Limits
Metals Department
Mercury MS ND 7.96 100 (85-115)
MSD 8.21 103
RPD
RPD Limits
3 (<15)
Spiked Analysis
Amount Date
8.00 ug/L 09/29/2009
8.00 ug/L 09/29/2009
Batch MCV4342
Method SW7470A/E245.1
Instrument PSA Millennium mercury AA
-------
SGS Ref.# 927689 Matrix Spike
927690 Matrix Spike Duplicate
Original 1095912001
Matrix Water (Surface, Eff., Ground)
Printed Date/Time
Prep Batch
Method
Date
09/30/2009 9:54
MXX22299
Digestion Mercury (W)
09/28/2009
QC results affect the following production samples:
1094697003
Original QC Pet MS/MSD
Parameter Qualifiers Result Result Recov Limits
Metals Department
Mercury MS ND 8.21 103 (85-115)
MSB 8.17 102
RPD
RPD Limits
0 (<15)
Spiked Analysis
Amount Date
8.00 ug/L 09/29/2009
8.00 ug/L 09/29/2009
Batch MCV4342
Method SW7470A/E245.1
Instrument PSA Millennium mercury AA
-------
Data Path
Data File
Acq On
Operator
Sample
Misc
ALS Vial
LSC Area Percent Report
Z:\GC\Public\Public\2009\09\SPA\Data\091809A\
1823A.D
19 Sep 2009 1:28 am
JDH
1094697001
[SPA]
21 Sample Multiplier: 1
Integration Parameters: INTP22.P
Integrator: RTE
Smoothing : ON
Sampling : 1
Start Thrs: 0.2
Stop Thrs : 0
Filtering: 5
Min Area: 3 % of largest Peak
Max Peaks: 100
Peak Location: TOP
If leading or trailing edge < 100 prefer < Baseline drop else tangent >
Peak separation: 5
Method : \\USFS700\ANK_INSTRUMENT_DATA\GC\PUBLIC\PUBLIC\2009\09\SPA\METHOD\SPA20090916.M
Title : SW-846 8270C / EPA 625
Signal : TIC
pea}
#
1
2
3
4
5
3
4
4
5
6
R.T. 1
min
.608
.377
.703
.221
.013
first
scan
161
267
315
381
491
max
scan
172
276
320
390
497
last
scan
195
291
334
398
529
PK
TY
rBV
rBV
rBV
rBV
rBV
peak
height
1692977
3778585
5764343
3137959
11405420
corr .
area
7599721
8529117
12885707
4420835
16269333
corr.
% max.
41.19%
46.23%
69.84%
23.96%
88.19%
to
5.
5.
8,
3.
11
of
tal
295%
942%
978%
080%
.335%
6 7.478 689 695 702 rBV 6171828
7 8.581 835 844 868 rBV 10017952
8 9.973 1022 1032 1046 rBV 4673836
9 11.290 1199 1210 1216 rBV2 8360842
10 14.465 1629 1639 1652 rBV2 5417622
11 16.493 1900 1913 1925 rVB 6276823
12 16.693 1933 1940 1953 rVB 962890
13 19.098 2251 2265 2275 rBV 4851655
7636174 41.39% 5.320%
18449065 100.00% 12.854%
7613774 41.27% 5.305%
18415251 99.82% 12.830%
9977134 54.08% 6.951%
17103118
1320887
13309256
92.70% 11.916%
7.16% 0.920%
72.14% 9.273%
Sum of corrected areas:
143529372
SPA20090916.M Mon Oct 05 12:03:35 2009
Page: 1
-------
LSC Report - Integrated Chromatogram
Data Path
Data File
Acq On
Operator
Sample
Misc
ALS Vial
Z:\GC\Public\Public\2009\09\SPA\Data\091809A\
1823A.D
19 Sep 2009 1:28 am
JDH
1094697001
[SPA]
21 Sample Multiplier: 1
Quant Method : \\USFS700\ANK_INSTRUMENT_DATA\GC\PUBLIC\PUBLIC\2009\09\SPA\METHOD\SPA20090916.
M
Quant Title : SW-846 8270C / EPA 625
TIC Library : \\USFS700\ANK_INSTRUMENT_DATA\GC\PUBLIC\MS__LIB\NIST02.L
TIC Integration Parameters: RTEINT.P
TIC: 1823A.D
01
8.58
4.70
7.48
Abundance
I 1e+07
; 8000000
! 6000000|
4000000
2000000
Tirne--> 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00^ 6.50 7,00 7.50 8.00 8.50 9.00 9.50
Abundance " ~ " "~ ~ ' TfC: 1823A.D
4.38
3.61
5.22
9.97
1e+07
8000000
6000000
4000000
2000000
11.29
16.49
14.47
16.69
Time-> 10.50 11.00 11.50 12.00 12.50 13.00 13.50 14.00 14.50 15.00 15.50 16.00 16.50 17.00 17.50
Abundance ffC:l823Al)
1e+07
8000000
6000000
4000000
2000000
Time--> 18.00 18.50 19.00 19.50 20.00 20.50 21.00 21.50 22.00 22.50.... 23.00 23.50 24.00 24.50 25.00
SPA20090916.M Mon Oct 05 12:03:36 2009 Page: 2
-------
Data Path
Data File
Acq On
Operator
Sample
Misc
ALS Vial
Quant Method
Quant Title
Tentatively Identified Compound (LSC) summary
Z:\GC\Public\Public\2009\09\SPA\Data\091809A\\
1823A.D
19 Sep 2009 1:28 am^
JDHH | ~
1094697001/"Ja**|
[SPA] ^ l°'
21 Sample Multiplier: 11
\\USFS700\ANK_INSTRUMENT_DATA\GC\PUBLIC\PUBLIC\2009\09\SPA\METHOD\SPA20090916,
MM
SW-846 8270C / EPA 6255
TIC Library : \\USFS700\ANK_INSTRUMENT_DATA\GC\PUBLIC\MS_LIB\NIST02.LL
TIC Integration Parameters: RTEINT.PP
TIC Top Hit name
--Internal Standard |
RT EstConc Units Response |# RT Resp Cone|
No Library Search Compounds Detected
SPA20090916 .M Mon Oct 05 12:03:37 2009
Page: 3
-------
LSC Area Percent Report
Data Path : Z:\GC\Public\Public\2009\09\SPA\Data\091809A\
Data File : 1824A.D
Acq On : 19 Sep 2009 2:01 am
Operator : JDH
Sample : 1094697002
Misc : [SPA]
ALS Vial : 22 Sample Multiplier: 1
Integration Parameters: INTP22.P
Integrator:
Smoothing :
Sampling :
Start Thrs:
Stop Thrs :
RTE
ON
1
0.2
0
Filtering: 5
Min Area: 3 %
Max Peaks: 100
Peak Location: TOP
of largest Peak
If leading or trailing edge < 100 prefer < Baseline drop else tangent >
Peak separation: 5
Method : \\USFS700\ANK_INSTRUMENT_DATA\GC\PUBLIC\PUBLIC\2009\09\SPA\METHOD\SPA20090916.M
Title : SW-846 8270C / EPA 625
Signal
TIC
pea)
#
1
2
3
4
5
c I
r
3
4,
4,
4,
4,
*.T. J
nin
.611
.270
.381
.706
.766
first
scan
160
253
271
314
326
max
scan
173
262
277
321
329
last
scan
196
271
295
326
340
PK
TY
rBV
rBV
rVB
rBV
rVB
peak
height
1652721
540135
3509457
6649536
3213393
corr .
area
7385960
1419673
8359218
14364321
5382016
CO3
% r
35
6,
40,
69,
25,
:r .
nax.
.55%
.83%
.23%
.13%
.90%
tc
3.
0,
4.
7.
2,
of
3tal
.899%
,749%
,412%
,582%
.841%
11
12
13
14
15
16
17
18
19
20
9.976
11.293
12.907
13.462
13.669
13.965
14.476
14.661
15.519
16.519
21 16.704
22 17.459
23 19.131
24 20.019
384
491
529
689
835
1023
1198
1422
1500
1528
1569
1631
1663
1778
1905
1939
2040
2258
2386
391
498
534
696
845
1033
1211
1429
1504
1532
1572
1641
1666
1782
1917
1942
2044
2270
2390
400
513
539
702
859
1047
1217
1433
1509
1536
1581
1648
1676
1788
1926
1950
2048
2274
2399
rBV
rBV
rBV
rBV
rBV
rBV
rBV2
rVB
rBV3
rBV3
rVB2
rBV2
rBV4
rVB
rVB
rVB
rBV2
rVB
rVB3
3387330
12534997
4071477
6585589
11125948
5111489
8154211
7097436
395870
603558
454589
4769616
319709
1960923
6381806
660793
931897
4744895
654376
4724428
17853384
4454937
8778869
20777872
8949915
20549069
11793006
849789
1094197
1060756
10654802
1047968
2549218
19347441
1058243
1723371
13961459
1313714
22.74%
85.92%
21.44%
42.25%
100.00%
43.07%
98.90%
56.76%
4.09%
5.27%
5.11%
51.28%
5.04%
12.27%
93.12%
5.09%
8.29%
67.19%
6.32%
4.724%
10.846%
6.225%
0.449%
0.578%
0.560%
5.624%
0.553%
1.346%
10.212%
0.559%
0.910%
7.369%
0.693%
Sum of corrected areas:
189453626
SPA20090916 .M Mon Oct 05 12:03:51 2009
Page: 1
-------
Data Path
Data File
Acq On
Operator
Sample
Misc
ALS Vial
Quant Method
Quant Title
LSC Report - Integrated Chromatogram
Z:\GC\Public\Public\2009\09\SPA\Data\091809A\
1824A.D
19 Sep 2009 2:01 am
JDH
1094697002
[SPA]
22 Sample Multiplier: 1
\\USFS700\ANK_INSTRUMENT_DATA\GC\PUBLIC\PUBLIC\2009\09\SPA\METHOD\SPA20090916.
M
SW-846 8270C / EPA 625
TIC Library : \\USFS700\ANK_INSTRUMENT_DATA\GC\PUBLIC\MS_LIB\NIST02.L
TIC Integration Parameters: RTEINT.P
Abundance
1.2e+07
: 1e+07
\ 8000000
6000000
4000000
2000000
! 0
rrime-->
~"x_
-r-p-i 1 1 1
2.50 3.
3.61
,
f r i i i | 'i l i !
00 3.50 4.
4
4.71
38
.77 5
, , , | i i > i i i
00 4.50 5.00
22
"H — i —
5.
TIC
6
): 1824A.D
02
7.48
6
28
1 1 1 1 T 1 I ' '1 1 j T 1 t T- -r~--1 1 T — 1 1 1 1 1 f
50 6.00 6.50 ___7.00 7.50 8.
8.58
9.9£
!
''~T "" T"?' *~T"""r " T - v i r i ; i i ; i i i i t <
00 8.50 9.00 9.50
Abundance . TIC: 1824A.D
\ 1.2e+07
; 1e+07
8000000
; 6000000
; 4000000
; 2000000
'. 0
Time-->
Abundance
: 1.2e+07
11
.29
12.91
Lj
^^A— JV-~— .-^--'••A— •*••
14
13-S!!K-J
p/i^jU'°"-^-w. yv""^
10.50 11.00 11.50 12.00 12.50 13.00 13.50 14.00 14
TIC:1824A.D
.48
ie
15.52
L^-A^^^AAAw^
.50 15.00 15.
50 16.00 16
.52
16.70 y6
50 17.00 17.50
19.13
1e+07
8000000
6000000
4000000
2000000
Time-> 18.00 18.50 laoo ...19.50 20^00 20.50 21.00 21.50 22.00 22.50 23.00 23.50 24,00 24.50 25.00 25.50
SPA20090916.M Mon Oct 05 12:03:53 2009 Page: 2
-------
Library Search Compound Report
Data Path
Data File
Acq On
Operator
Sample
Misc
ALS Vial
Quant Method
Quant Title
Z:\GC\Public\Public\2009\09\SPA\Data\091809A\
1824A.D
19 Sep 2009 2:01 am
JDH
1094697002
[SPA]
22 Sample Multiplier: 1
\\USFS700\ANK_INSTRUMENT_DATA\GC\PUBLIC\PUBLIC\2009\09\SPA\METHOD\SPA20090916
M
SW-846 8270C / EPA 625
TIC Library : \\USFS700\ANK_INSTRUMENT__DATA\GC\PUBLIC\MS_LIB\NIST02.L
TIC Integration Parameters: RTEINT.P
***************************************** + ***********-*••*•**************
Peak Number 1 1-Hexanol, 2-ethyl- Concentration Rank 2
R.T. EstConc Area Relative to ISTD R.T.
4.77 59.95 mg/L 5382020
Hit# of 5 Tentative ID
1,4-Dichlorobenzene-D4 4.71
MW MolForm CAS# Qual
1 1-Hexanol, 2-ethyl-
2 1-Hexanol, 2-ethyl-
3 dl-2-Ethylhexyl chloroformate
4 1-Hexanol, 2-ethyl-
5 1-Hexanol, 2-ethyl-
130 C8H180
130 C8H180
192 C9H17C102
130 C8H180
130 C8H180
Abundance
5000
Scan 329 (4.766 min): 1824A.D (-326) (-)
5|7
41
70 83
O.ii|itii ,.,,.1,111,.,.,,, iv,^.,.,iL|,.,V JJ^^.M™?.,,
;rn/z::> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150
Abundance
57
5000
0
41
29
70 83
15
98
112
r p-rrrr
rn/z:-> 10 20 .30_40 50 60 70 80 90 100110120 130140150
Abundance
57
5000
43
29
70 83
OWrr,V%
m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150
Abundance #50875: dl-2-Ethylhexyl chloroformate
I SJ
5000
70
41
29
83
15
m/z->
10 20 30 40 50 60 70 80 90 100 110 120 130 140 150
000104-76-7 78'
000104-76-7 78
024468-13-1 59
000104-76-7 56
000104-76-7 56
m/z 57.10 100.00%
4.40 4.60 4.80 5.00 5.20
"m7z~ 41.05 ~ 40.42%
4.40 4.60 4.80 5.00 5.20
m'/z" ~43~."00 32.01%
4.40 4.60 4.80 5,00 5.20
Wz" 55.00 25.30%
4.40 4.60 4.80 5.00 5.20
m/z 70.05 24.60%
4.40 4.60 4.80 5.00 5.20
SPA20090916.M Mon Oct 05 12:03:56 2009
Page: 3
-------
Library Search Compound Report
Data Path
Data File
Acg On
Operator
Sample
Misc
ALS Vial
Z:\GC\Public\Public\2009\09\SPA\Data\091809A\
1824A.D
19 Sep 2009 2:01 am
JDH
1094697002
[SPA]
22 Sample Multiplier: 1
Quant Method : \\USFS700\ANK_INSTRUMENT_DATA\GC\PUBLIC\PUBLIC\2009\09\SPA\METHOD\SPA20090916.
M
Quant Title : SW-846 8270C / EPA 625
TIC Library : \\USFS700\ANK_INSTRUMENT_DATA\GC\PUBLIC\MS_LIB\NIST02.L
TIC Integration Parameters: RTEINT.P
*********************************************************************
Peak Number 2 Disulfide, bis(1,1,3,3-tetr... Concentration Rank 3
R.T. EstConc Area Relative to ISTD R.T.
6.28 39.92 mg/L 4454940 Naphthalene-D8
Hit# of 5 Tentative ID MW MolForm
6.02
CAS#
Qual
1 Disulfide, bis(1,1,3,3-tetrameth..
2 Hexanal, 2,2-dimethyl-
3 Nonane, 2,2,4,4,6,8,8-heptamethyl-
4 Thiolane-3,4-dicarbonitrile, 2,5...
5 Isobutyl ether
290 C16H34S2
128 C8H160
226 C16H34
386 C16H20F6N2S
130 C8H180
Abundance
5000
57
Scan 534 (6.283 min): 1824A.D (-529) (-)
41
113
73 97
129146 178 206 240
hi/z::> 20 40 60 80 100 120 140 160 180 200 220 240 260 280
Abundance • _ , ." ' i,' '
57
i
5000
0
41
15
75
97
113
129 163
290
t-p-n
mlz-->_20 40 60 80 100J20 140 160 180 200 220 240 260 280
Abundance
57
5000
m/z->
Abundance
5000
41
73
99
129
TTjTT-i-rp rri ] I r rTyrTTTyTTTTp-rTT-p-rrrp-rrTpi n p-m j-rrrrp-myn , i | i i
20 40 60 80 100 120 140 160 180 200 220 240 260 280
#73995: Nonane, 2.2,4,4.6,8,8-heptamethyl-
O1,
41
99
m/z->
8? T i 127 155
20 40 60 80 100 120 140 160 180 200 220 240 260 280
-rt-J-T
029956-99-8 38x"
000996-12-3 25
004390-04-9 17
1000260-74-6 17
000628-55-7 12
m/z 57.10 100.00%
6.00 6.20 6.40 6.60
'm/z 41.05 25.97%
6.00 6.20 6.40 6.60
' m/z 113"7io" 20.52%'
6.00 6.20 6.40 6.60
m/z' 54.95 ~~ 8763%
6.00 6.20 6,40 6.60 :
m/z 106.95 8.35%i
6.00 6.20 6.40 6.60
SPA20090916.M Mon Oct 05 12:03:58 2009
Page: 4
-------
Data Path
Data File
Acq On
Operator
Sample
Misc
ALS Vial
Quant Method
Quant Title
Tentatively Identified Compound (LSC) summary
Z:\GC\Public\Public\2009\09\SPA\Data\091809A\
1824A.D
19 Sep 2009 2:01 am
JDH
1094697002
[SPA]
22 Sample Multiplier: 1
\\USFS700\ANK_INSTRUMENT_DATA\GC\PUBLIC\PUBLIC\2009\09\SPA\METHOD\SPA20090916,
M
SW-846 8270C / EPA 625
TIC Library : \\USFS700\ANK_INSTRUMENT_DATA\GC\PUBLIC\MS_LIB\NIST02.L
TIC Integration Parameters: RTEINT.P
TIC Top Hit name
RT EstConc Units Response
--Internal Standard
# RT Resp Cone
1-Hexanol, 2-ethyl-
Disulfide,
4.77 59.9 mg/L 5382020 1
6.28 39.9 mg/L 4454940 2
12.91 91.8 mg/L 11793000 4
•15.52 21.1 mg/L 2549220 5
4.71 14364300 160.0
6.02 17853400 160.0
11.29 20549100 160.0
16.52 19347400 160.0
SPA20090916.M Mon Oct 05 12:04:02 2009
Page: 7
-------
Kottsick, Jason L (Anchorage)
Page 1 of 3
1094697
From: Crupi, Steve [steve.crupi@shawgrp.com]
Sent: Tuesday, September 08, 2009 11:35 AM
To: Kottsick, Jason L (Anchorage)
Cc: Long, Alesha (Anchorage); James, Jack; James, Rachel
Subject: RE: 1094697_RARE0909_COC4Sep09
Jason,
For the two -401 samples you received, please conduct a SVOC 8270 TIC search (in addition to the 'regular'
analyte list) looking for and reporting ONLY the top ten TICs meeting the criteria for TIC identification (greater
than 10% the nearest IS, etc.). Do not do a TIC search for the -501 samples.
For all future field samples on this project (samples ending in '001'), please conduct an SVOC 8270 TIC search (in
addition to the 'regular' list) whenever SVOC 8270 is requested. I, and Jack, wiil try to remember to formally
request TICs on the COC.
Steve
Steven R. Crupi
Project Manager
Shaw Alaska, inc. ,->.!;
Shaw Environmental & Infrastructure .
2000 W. internat'l Airport Rd., C-1, Anchorage, AK 99502
(907) 249-6312 (direct)
(907) 243-6300 (general) :
Shaw™ a world of Solutions™
www.shawgrp.com
From: Kottsick, Jason L (Anchorage) [mailto:Jason.Kottsick@sgs.com]
Sent: Tuesday, September 08, 2009 10:37 AM
To: Crupi, Steve
Cc: Long, Alesha (Anchorage)
Subject: FW: 1094697_RARE0909_COC4Sep09
Jason Kottsick
Environmental Services
Project Manager
SGS - North America Inc.
200 West Potter Drive
US - 99518 - Anchorage, AK
Phone: (907) 562-2343
Fax:(907)561-5301
E-mail: jason.kottsick@sgs.com
Did you know SGS now offers TO-14, TO-15 ambient air volatiies analysis including NELAC
accreditation?
9/8/2009
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1094697
SAMPLE RECEIPT FORM SGS wo#:
Yes No NA
L/L Are samples RUSH, priority or w/in 72 hrs of hold time?
(x If yes, have you done e-mail ALERT notification?
L: Are samples within 24 hrs. of hold time or due date?
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Cooler IP
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. If this is for PWS, provide PWSID:
Payment received: $ by Check or Credit Card
. Will courier charges apply?
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Were
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UPS / FedEx / USPS / DHL/ Carlile
AkAir Goldstreak / NAC / ERA / PenAir
Other:
Additional Sample Remarks: (V if applicable)
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Multi-Incremental Samples?
Lab-filtered for dissolved
Ref Lab required for
Foreign Soil?
\ Qi3st_
Completed by (sign):
Login proof: Self-check completed
(print):
Peer-reviewer's initials.
Form # F004r20 revised 05/05/2009
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1094697
SAMPLE RECEIPT FORM SGS wo#:
Yes
No
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NA
Are samples RUSH, priority or w/in 72 hrs of hold time?
If yes, have you done e-mail ALERT notification?
Are samples within 24 hrs. of hold time or due date?
If yes, have you also spoken with supervisor?
Archiving bottles: Are lids marked w/ red "X"?
Were samples collected with proper preservative?
Any problems (ID, cond'n, HT, etc)? Explain:
TAT (circle one):
Received Date:
Received Time: _
Cooler ID
-or- Rush
Temperature
°C
°C
°C
°C
Measured w/
(Therm #)
If this is for PWS, provide PWSID:
Payment received: $ by Check or Credit Card
. Will courier charges apply?
Data package required? (Level: 1 / 2 / 3 / 4)
Notes:
Is this a DoD project? (USAGE, Navy, AFCEE)
Note: Temperature readings include thermometer correction factors
' method (circle all that apply):
'/ Alert Courier / Lynden / SGS
UPS / FedEx / USPS / DHL/ Carlile
AkAir Goldstreak / NAC / ERA / PenAir
Other:
This, section must be filled out for DoD projects (USACE, Navy, AFCEE):
Yes ; No ' ' - " - j| •
«•""' , ' ^ Is received temperature <6QC? • > *
_J/~, Were "containers ice-free? Notify PM immediately of any ice in samples.
If some cooler temperatures are non-compliant, see
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u. - : Was cooler sealed with custody seals & were theydntact?
. '#/where: f fattf'*' ftfc*> T9f* (>/#
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Was COC sealed in plastic bag & taped inside' lid of cooler,?
Was the COC filled out properly? Did labels correspond?.
Did the COC indicate USAGE / Navy / AFCEE project? •
Samples were packed to prevent breakage, with (circle one):
BEEhSLStep Vermiculite Other (specify); •
Were all samples sealed in separate plastic bags?
Were all VOCs free of headsjpace and/or HeOH preserved?
" Were correct container/ sample sizes' submitted? •
Was the PM notified of arrival so they cap send "
Sample Receipt Acknowledgement to client?
Cooler Temp °C ' Cooler ID Cooler Temp °C
Cooler Temp BC_J___ Cooler ED. Cooler Temp °C
Cooler, EL
Cooler tt>
Additional Sample Remarks: (V if applicable)
Extra Sample Volume?
Limited Sample Volume?
Multi-Incremental Samples?
Lab-filtered for dissolved
Ref Lab required for
Foreign Soil?
This section ntust be compteted if problems are noted.
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B-y (SGS PM): ^
Individual contacted: . ! .. >
Via: • Phone •/ Fax / E-mail (circle one)
Date/Time: __^ -
Reason for, contact: ;
Change Order Reauired? Yes / No
Notes:
Urr
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Completed by (sign):
Login proof:
(print):
Self-check completed
Peer-reviewer's Initials
Form # F004r22 revised 09/05/2009
-------
•-~--~--~---r- SAMPLE RECEIPT FORM - Bottle Tracking SGSWO#
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SGS North America Inc.
Alaska Division
Level II Laboratory Data Report
Project: RARE-AK Tribal LF-Ekwok
Client: Shaw Env & Infrastructure Inc.
SGS Work Order: 1103392
Released by:
Contents:
Cover Page
Case Narrative
Final Report Pages
Quality Control Summary Forms
Chain of Custody/Sample Receipt Forms
Note:
Unless otherwise noted, all quality assurance/quality control criteria is in compliance with the standards set forth by the proper regulatory authority, the
SGS Quality Assurance Program Plan, and the National Environmental Accreditation Conference.
-------
CASE NARRATIVE
Print Date: 7/21/2010
Client Name: Shaw Env & Infrastructure Inc.
Project Name: RARE-AK Tribal LF-Ekwok
Workorder No.: 1103392
Sample Comments
Refer to the sample receipt form for information on sample condition.
Lab Sample ID
974761
974762
974765
974766
Sample Type Client Sample ID
' MS 07031 OEX09BNW...(1103312004M
245.1 - Mercury- MS recovery for mercury was outside of acceptance criteria. Post digestion spike was unsuccessful.
Sample result was determined by MSA.
'BND
070310EX09BN...(1103312004BNC
245.1 - Mercury- MS recovery for mercury wasoutside of acceptance criteria. Post digestion spike was unsuccessful.
Sample result was determined by MSA..
'MS
60054108004(1103261002MS)
7470A - Mercury- MS/MSD recoveries for mercury were outside of acceptance criteria (biased low ). Post digestion spike
was successful.
'MSD
60054108004(1103261002MSD)
7470A - Mercury- MS/MSD recoveries for mercury were outside of acceptance criteria (biased low ). Post digestion spike
was successful.
' QC comments may be associated with the field samples found in this report. When applicable, comments will be applied to
associated field samples.
SOS North America Inc.
Environmental Division 200 West Potter D rive Anchorage A K 995 18 t(907 )562.2343 f(907)561 .5301
www.us.sgs.com
M em ber of S G S Group
-------
Laboratory Analytical Report
Client: Shaw Env & Infrastructure Inc.
2000 W. Int'l Airport, Ste C1
Anchorage, AK 99502
Project:
Workorder No.:
Attn: Jack James
T: F:
jack.james@shawgrp.com
RARE-AK Tribal LF-Ekwok
1103392
Certification:
This data package is in compliance with the terms and conditions of the contract, both
technically and for completeness, unless otherwise noted on the sample data sheet(s) and/or
case narrative. This certification applies only to the tested parameters and the specific
sample(s) received at the laboratory. If you have any questions regarding this report, or if we
can be of further assistance, please contact your SGS Project Manager.
Steve Crupi
steven.crupi@sgs.com
Project Manager
Contents (Bookmarked in PDF):
Cover Page
Glossary
Sample Summary Forms
Case Narrative
Sample Results Forms
Batch Summary Forms (by method)
Quality Control Summary Forms (by method)
Chain of Custody/Sample Receipt Forms
Attachments (if applicable)
SGSNorth America Inc.
EnvironmentalDivision 200 We stPotter Drive Anchorage AK 99518 t(907 )562.2343 f( 907)561 .5301
www.us.sgs.com
Member of SGS Group
-------
Print Date: 7/21/2010
Enclosed are the analytical results associated with the above work order. All results are intended to be used in their entirety and SGS is not
responsible for use of less than the complete report. If you have any questions regarding this report, or if we can be of any other assistance, please
contact your SGS Project Manager at 907-562-2343. All work is provided under SGS general terms and conditions
(), unless other written agreements have been accepted by both parties.
SGS maintains a formal Quality Assurance/Quality Control (QA/QC) program. A copy of our Quality Assurance Plan (QAP), which outlines this
program, is available at your request. The laboratory certification numbers are AK00971 (DW Chemistry & Microbiology) & UST-005 (CS) for
ADEC and AK100001 forNELAP (RCRA methods: 1020A, 1311, 3010A, 3050B, 3520C, 3550C, 5030B, 5035B, 6010B, 6020, 7470A, 7471B,
8021B, 8081B, 8082A, 8260B, 8270D, 8270D-SIM, 9040B, 9045C, 9056A, 9060A, AK101 and AK102/103). Except as specifically noted, all
statements and data in this report are in conformance to the provisions set forth by the SGS QAP and, when applicable, the National Environmental
Laboratory Accreditation Program and other regulatory authorities. The following descriptors or qualifiers may be found in your report:
* The analyte has exceeded allowable regulatory or control limits.
! Surrogate out of control limits.
B Indicates the analyte is found in a blank associated with the sample.
CCV Continuing Calibration Verification
CL Control Limit
D The analyte concentration is the result of a dilution.
DF Dilution Factor
DL Detection Limit (i.e., maximum method detection limit)
E The analyte result is above the calibrated range.
F Indicates value that is greater than or equal to the DL
GT Greater Than
ICV Initial Calibration Verification
J The quantitation is an estimation.
JL The analyte was positively identified, but the quantitation is a low estimation.
LCS(D) Laboratory Control Spike (Duplicate)
LOD Limit of Detection (i.e., 2xDL)
LOQ Limit of Quantitation (i.e., reporting or practical quantitation limit)
LT Less Than
M A matrix effect was present.
MB Method Blank
MS(D) Matrix Spike (Duplicate)
ND Indicates the analyte is not detected.
Q QC parameter out of acceptance range.
R Rejected
RL Reporting Limit
RPD Relative Percent Difference
U Indicates the analyte was analyzed for but not detected.
Note: Sample summaries which include a result for "Total Solids" have already been adjusted for moisture content.
All DRO/RRO analyses are integrated per SOP.
SGSNorth America Inc. Environm entalDivision 200 WestPotter D rive Anchorage AK 9951 8 t(907 )562.2343 f( 907)561 .5301
www.us.sgs.com M ember of SGS Group
-------
SAMPLE SUMMARY Print Date: 7/21/2010 9:07 am
Client Name: Shaw Env & Infrastructure Inc.
Project Name: RARE-AK Tribal LF-Ekwok
Workorder No.: 1103392
Analytical Methods
Method Description Analytical Method
Mercury 7470 SW7470A/E245.1
Sample ID Cross Reference
Lab Sample ID Client Sample ID
1103392001 07081OEKWPZ02WG001
SGSNorth America Inc.
EnvironmentalDivision 200 WestPotter D rive Anchorage AK 99518 t(907 )562.2343 f( 907)561 .5301
www.us.sgs.com MemberofSGS Group
-------
Shaw Env & Infrastructure Inc.
Print Date: 7/21/2010 9:07 am
Client Sample ID: 07081OEKWPZ02WG001
SGSRef. #: 1103392001
Project ID: RARE-AK Tribal LF-Ekwok
Matrix: Water (Surface, Eff., Ground)
Collection Date/Time: 07/08/10 13:18
Receipt Date/Time: 07/12/10 13:46
Location: PZ02
Metals Department
Parameter
Mercury
Batch Information
Analytical Batch: MCV4581
Analytical Method: SW7470A/E245.1
Analysis Date/Time: 07/20/10 13:19
Dilution Factor: 1
Result LOQ/CL
0.200 U 0.200
Analytical Prep
Units DF Batch Batch Qualifiers
ug/L 1 MCV4581 MXX23253
Prep Batch: MXX23253
Prep Method: METHOD
Prep Date/Time: 07/19/10 17:10
Initial PrepWt.A/ol.: 25 ml
Prep Extract Vol.: 50 ml
Container 10:1103392001-A
Analyst: KAR
SGSNorth America Inc.
EnvironmentalDivision 200 WestPotter D rive Anchorage AK 9951 8 t(907 )562.2343 f( 907)561 .5301
w ww.us.sgs.com
M ember of SG S Group
-------
SGS Ref.# 974759 Method Blank
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Tribal LF-Ekwok
Matrix Water (Surface, Eff , Ground)
Printed Date/Time 07/21/2010 9:07
Prep Batch MXX23253
Method METHOD
Date 07/19/2010
QC results affect the following production samples:
1103392001
Parameter Results LOQ/CL
Metals Department
Mercury 0.124U 0.200
Batch MCV4581
Method S W7470A/E245 . 1
Instrument PSA Millennium mercury AA
Analysis
DL Units Date
0.0620 ug/L 07/20/10
-------
SGS Ref.#
Client Name
Project Name/#
Matrix
974760 Lab Control Sample
Shaw Env & Infrastructure Inc.
RARE-AK Tribal LF-Ekwok
Water (Surface, Eff., Ground)
Printed Date/Time 07/21/2010
Prep Batch MXX23253
Method METHOD
Date 07/19/2010
9:07
QC results affect the following production samples:
1103392001
Parameter
QC Pet
Results Recov
LCS/LCSD RPD Spiked
Limits RPD Limits Amount
Analysis
Date
Metals Department
Mercury
Batch
Method
Instrument
LCS 3.51 88
MCV4581
SW7470A/E245.1
PSA Millennium merr.nrv A A
(85-115) 4 ug/L
07/20/2010
-------
SGS Ref.# 974761 Matrix Spike
Original 1103312004
Matrix Water (Surface, Eff., Ground)
Printed Date/Time
Prep Batch
Method
Date
07/21/2010 9:07
MXX23253
Digestion Mercury (W)
07/19/2010
QC results affect the following production samples:
1103392001
Original QC
Parameter Qualifiers Result Result
Pet MS/MSD RPD
Recov Limits RPD Limits
Spiked Analysis
Amount Date
Metals Department
Mercury MS (0.200) U .428
Batch MCV4581
Method SW7470A/E245.1
Instrument PSA Millennium mercury AA
5* (85-115)
8.00 ug/L 07/20/2010
-------
SGS Ref.# 974762 Bench Spike DIGESTED
Original 1103312004
Matrix Water (Surface, Eff., Ground)
Printed Date/Time
Prep Batch
Method
Date
07/21/2010 9:07
MXX23253
Digestion Mercury
07/19/2010
(W)
QC results affect the following production samples:
1103392001
Original QC Pet
Parameter Qualifiers Result Result Recov
MS/MSD RPD
Limits RPD Limits
Spiked Analysis
Amount Date
Metals Department
Mercury END (0.200) U 11.9
Batch MCV4581
Method SW7470A/E245.1
Instrument PSA Millennium mercury AA
119* (85-115)
10.0 ug/L 07/20/2010
-------
SGS Ref.# 974765 Matrix Spike
974766 Matrix Spike Duplicate
Original 1103261002
Matrix Water (Surface, Eff, Ground)
Printed Date/Time
Prep Batch
Method
Date
07/21/2010 9:07
MXX23253
Digestion Mercury (W)
07/19/2010
QC results affect the following production samples:
1103392001
Original QC Pet MS/MSD
Parameter Qualifiers Result Result Recov Limits
Metals Department
Mercury MS (0.124)U 6.54 82* (85-115)
MSD 6.27 78*
RPD
RPD Limits
4 (<15)
Spiked Analysis
Amount Date
8.00 ug/L 07/20/2010
8.00 ug/L 07/20/2010
Batch MCV4581
Method SW7470A/E245.1
Instrument PSA Millennium mercury AA
-------
SGS Ref.# 974767 Bench Spike DIGESTED
Original 1103261002
Matrix Water (Surface, Eff., Ground)
Printed Date/Time
Prep Batch
Method
Date
07/21/2010 9:07
MXX23253
Digestion Mercury
07/19/2010
(W)
QC results affect the following production samples:
1103392001
Original QC Pet
Parameter Qualifiers Result Result Recov
MS/MSD RPD
Limits RPD Limits
Spiked Analysis
Amount Date
Metals Department
Mercury END (0.124)U 7.25
Batch MCV4581
Method SW7470A/E245.1
Instrument PSA Millennium mercury AA
91 (85-115)
8.00 ug/L 07/20/2010
-------
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on«H 1 ' °3392 1
^^Ji»^^ lillili illll Illll Itlil HIII tiifi
SAMPLE RECEIPT FORM 'Hllillll
i
Review Criteria:
Were custody seals intact?
Note # & location if applicable.
COC accompanied samples?
Temperature blank compliant (i.e., 0-6°C after correction factor)?
Cooler ID: &Ho ' ®G 1 @, &>3°C w/ Therm.ID: 3Le?$L
Cooler ID: @ w/ Therm.ID:
Cooler ID: @ w/ Therm.ID:
Cooler ID: @ w/ Therm.ID:
Cooler ID: (Sj w/ Therm.ID:
Note: If non-compliant, use form FS-0029 to document affected samples/analyses.
If samples are received without a temperature blank, the "cooler
temperature" will be documented in lieu of the temperature blank &
"COOLER TEMP" will be noted to the right. In cases where neither a
temp blank nor cooler temp can be obtained, note "ambient" or "chilled."
If temperature(s) <0°C, were all containers ice free?
Deljyery^rnethod (specify all that apply):
^CGgat^ USPS Alert Courier RoadRunner
AKAir Lynden Carlile ERA
FedEx UPS NAC PenAir
Other:
Condition:
<^es) No N/A
fYesT) No N/A
(f?es) No N/A
Yes No
SRF Completed by: C$
Bottle Sheet by: M-
V~*4^X'
Peer Reviewed byCSS^J
PM = N/A
Additional notes (if applicable):
F004r24^SampleReceiptFormj-evised JD5222010
-------
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SAMPLE ID
1103392
001 001
A A
X
*-f
(0
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£ O
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Q. —
TYPE CONTAINERS
1 Water
HNO3 (pH <2)
l
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PRINT LABELS I Notes:
Q i ANOMALIES -
O
H
LU
ANALYSIS
W_Metals_Total/Diss.
e.g., preservative added
or SPECIAL HANDLING -
e.g., Multi-Incremental (Ml),
Field Filter (FF), Lab Filter (LF),
use "same jar as" (SJA) for QC,
2xMeOH, bubbles, etc.
Type comments below:
1103392
Page: 1 ; Printed: 7/12/2010
F066_SRF-BottleTracking(electronic)_rev03-05212010
-------
SGS North America Inc.
Alaska Division
Level II Laboratory Data Report
Project: RARE-AK Ft. Yukon Tribal LF
Client: Shaw Env & Infrastructure Inc.
SGS Work Order: 1103076
Released by:
Contents:
Cover Page
Case Narrative
Final Report Pages
Quality Control Summary Forms
Chain of Custody/Sample Receipt Forms
Note:
Unless otherwise noted, all quality assurance/quality control criteria is in compliance with the standards set forth by the proper regulatory authority, the
SGS Quality Assurance Program Plan, and the National Environmental Accreditation Conference.
-------
CASE NARRATIVE
Print Date: 7/12/2010
Client Name: Shaw Env & Infrastructure Inc.
Project Name: RARE-AK Ft. Yukon Tribal LF
Workorder No.: 1103076
Sample Comments
Refer to the sample receipt form for information on sample condition.
Lab Sample ID Sample Type Client Sample ID
970377 * LCS LCS for HBN 470580 [XXX/22939]
8270D - LCS recoveries for multiple analytes do not meet QC criteria (biased high). These analytes were not detected
above the LOG in the associated samples.
970378 * LCSD LCSD for HBN 470580 [XXX/22939
8270D - LCS/LCSD RPDs for multiple analytes do not meet QC criteria. These analytes were not detected above the LOQ in
the associated samples.
970856 *MB MB for HBN 478180 [WTC/1995]
531 OB - TOC was detected in the MB greater than half of the LOQ however less than the LOQ.
971520 * CCV CCV for HBN 489680 (XMS/5500)
8270D - CCV recovery for 4-nitrophenol does not meet QC criteria (biased high). This analyte was not detected above the
LOQ in the associated samples.
* QC comments may be associated with the field samples found in this report. When applicable, comments will be applied to
associated field samples.
SGSNorth America Inc. EnvironmentalDivision 200 WestPotter D rive Anchorage AK 9951 8 1(907)562.2343 f(907)S61 .5301
1 www.us.sgs.com M ember of SG S Group
-------
Laboratory Analytical Report
Client: Shaw Env & Infrastructure Inc.
2000 W. Int'l Airport, Ste C1
Anchorage, AK 99502
Attn: Jack James
T: F:
jack.james@shawgrp.com
Project: RARE-AK Ft. Yukon Tribal LF
Workorder No.: 1103076
Certification:
This data package is in compliance with the terms and conditions of the contract, both
technically and for completeness, unless otherwise noted on the sample data sheet(s) and/or
case narrative. This certification applies only to the tested parameters and the specific
sample(s) received at the laboratory. If you have any questions regarding this report, or if we
can be of further assistance, please contact your SGS Project Manager.
Steve Crupi
steven.crupi@sgs.com
Project Manager
Contents (Bookmarked in PDF):
Cover Page
Glossary
Sample Summary Forms
Case Narrative
Sample Results Forms
Batch Summary Forms (by method)
Quality Control Summary Forms (by method)
Chain of Custody/Sample Receipt Forms
Attachments (if applicable)
SGSNorth America Inc. Environmental Division 200 We stPotter Drive Anchorage AK 9951 8t(907 )562.2343 f(907)561 .5301
www.us.sgs.com Member of SGS Group
-------
Print Date: 7/12/2010
Enclosed are the analytical results associated with the above work order. All results are intended to be used in their entirety and SGS is not
responsible for use of less than the complete report. If you have any questions regarding this report, or if we can be of any other assistance, please
contact your SGS Project Manager at 907-562-2343. All work is provided under SGS general terms and conditions
(), unless other written agreements have been accepted by both parties.
SGS maintains a formal Quality Assurance/Quality Control (QA/QC) program. A copy of our Quality Assurance Plan (QAP), which outlines this
program, is available at your request. The laboratory certification numbers are AK00971 (DW Chemistry & Microbiology) & UST-005 (CS) for
ADEC and AK100001 for NELAP (RCRA methods: 1020A, 1311, 3010A, 3050B, 3520C, 3550C, 5030B, 5035B, 6010B, 6020, 7470A, 7471B,
8021B, 8081B, 8082A, 8260B, 8270D, 8270D-SIM, 9040B, 9045C, 9056A, 9060A, AK101 and AK102/103). Except as specifically noted, all
statements and data in this report are in conformance to the provisions set forth by the SGS QAP and, when applicable, the National Environmental
Laboratory Accreditation Program and other regulatory authorities. The following descriptors or qualifiers may be found in your report:
* The analyte has exceeded allowable regulatory or control limits.
! Surrogate out of control limits.
B Indicates the analyte is found in a blank associated with the sample.
CCV Continuing Calibration Verification
CL Control Limit
D The analyte concentration is the result of a dilution.
DF Dilution Factor
DL Detection Limit (i.e., maximum method detection limit)
E The analyte result is above the calibrated range.
F Indicates value that is greater than or equal to the DL
GT Greater Than
ICV Initial Calibration Verification
J The quantitation is an estimation.
JL The analyte was positively identified, but the quantitation is a low estimation.
LCS(D) Laboratory Control Spike (Duplicate)
LOD Limit of Detection (i.e., 2xDL)
LOQ Limit of Quantitation (i.e., reporting or practical quantitation limit)
LT Less Than
M A matrix effect was present.
MB Method Blank
MS(D) Matrix Spike (Duplicate)
ND Indicates the analyte is not detected.
Q QC parameter out of acceptance range.
R Rejected
RL Reporting Limit
RPD Relative Percent Difference
U Indicates the analyte was analyzed for but not detected.
Note: Sample summaries which include a result for "Total Solids" have already been adjusted for moisture content.
All DRO/RRO analyses are integrated per SOP.
SGSNorth America Inc.
Environmental Division 200 West Potter D rive Anchorage AK 99518 t(907 )562.2343 f( 907)5 61 .5301
w ww.us.sgs .com M ember of SG S Group
-------
SAMPLE SUMMARY
Print Date: 7/12/2010 3:23 pm
Client Name: Shaw Env & Infrastructure Inc.
Project Name: RARE-AK Ft. Yukon Tribal LF
Workorder No.: 1103076
Analytical Methods
Method Description
Alkalinity as CaCOS QC
Mercury 7470
SW846-8270 SVOC by GC/MS (W) Liq/Liq ext
Total Dissolved Solids SM18 2540C
Total Organic Carbon
TPH by EPA 1664
Analytical Method
SM20 2320B
SW7470A/E245.1
SW8270D
SM20 2540C
SM5310B
EPA1664A
Sample ID Cross Reference
Lab Sample ID
1103076001
1103076002
Client Sample ID
06231OFYUPZ04WG001
06231OFYUSP01WS001
SGSNorth America Inc. Environm entalDivision 200 We stPotter D rive Anchorage AK 9951 8 1(907)562.2343 f( 907)561 .5301
www.us.sgs.com M ember of SGS Group
-------
Detectable Results Summary
Print Date: 7/12/2010 3:23 pm
Client Sample ID: 06231OFYUPZ04WG001
SGSRef. #: 1103076001
Waters Department
Parameter
Alkalinity
Total Dissolved Solids
Total Organic Carbon
Result
399
676
59.4
Units
mg/L
mg/L
mg/L
Client Sample ID: 06231OFYUSP01WS001
SGSRef. #: 1103076002
Waters Department
Parameter
Alkalinity
Total Dissolved Solids
Total Organic Carbon
Result
318
2330
22.2
Units
mg/L
mg/L
mg/L
SGSNorth America Inc.
Environmental Division 200 We stPotter D rive Anchorage AK 9951 8 t(907 )562
www.us.sgs.com
2343 f(907)561 .5301
M ember of SGS Group
-------
Shaw Env & Infrastructure Inc.
Print Date: 7/12/2010 3:23 pm
Client Sample ID: 06231OFYUPZ04WG001
SGSRef. #: 1103076001
Project ID: RARE-AK Ft. Yukon Tribal LF
Matrix: Water (Surface, Eff., Ground)
Collection Date/Time: 06/23/10 15:00
Receipt Date/Time: 06/25/10 15:30
Location: PZ04
Metals Department
Parameter
Mercury
Batch Information
Analytical Batch: MCV4567
Analytical Method: SW7470A/E245.1
Analysis Date/Time: 07/07/10 15:35
Dilution Factor: 1
Result
LOQ/CL
Units
DF
Analytical Prep
Batch Batch
Qualifiers
0.200 U 0.200 ug/L
Prep Batch: MXX23182
Prep Method: METHOD
Prep Date/Time: 07/06/10 11:30
MCV4567 MXX23182
Initial PrepWt.A/ol.: 25 ml
Prep Extract Vol.: 50 ml
Container 10:1103076001-A
Analyst: RTS
SGSNorth America Inc
EnvronmentalDivision 200 WestPotter D rive Anchorage AK 9951 8 t(907 )562.2343 f( 907)561 .5301
w ww.us.sgs.com
M ember of SG S Group
-------
Shaw Env & Infrastructure Inc.
Print Date: 7/12/2010 3:23 pm
Client Sample ID: 06231OFYUPZ04WG001
SGSRef. #: 1103076001
Project ID: RARE-AK Ft. Yukon Tribal LF
Matrix: Water (Surface, Eff., Ground)
Collection Date/Time: 06/23/10 15:00
Receipt Date/Time: 06/25/10 15:30
Location: PZ04
Waters Department
Parameter
Result
LOQ/CL
Units
DF
Analytical
Batch
Prep
Batch
Qualifiers
Alkalinity
Total Dissolved Solids
Total Organic Carbon
TPH Silica Gel HEM
Batch Information
Analytical Batch: TPH2194
Analytical Method: EPA 1664A
Analysis Date/Time: 07/01/10 12:30
Dilution Factor: 1
399
676
59.4
32.0 U
10.0
10.0
0.500
32.0
Prep Batch: TPHX2011
Prep Method: EXTJ664TP
Prep Date/Time: 07/01/10 12:30
mg/L 1 WTI3351
mg/L 1 WAT8246
mg/L 1 WTC1995
mg/L 1 TPH2194 TPHX2011
Initial Prep Wt./Vol.: 125 mL
Prep Extract Vol.: 50 mL
Container ID: 1103076001-C
Analyst: RTS
Analytical Batch: WAT8246
Analytical Method: SM20 2540C
Analysis Date/Time: 06/29/10 12:00
Dilution Factor: 1
Initial Prep Wt./Vol.: 50 mL
Container ID:1103076001-E
Analyst: JJR
Analytical Batch: WTC1995
Analytical Method: SM 531 OB
Analysis Date/Time: 07/01/10 11:28
Dilution Factor: 1
Initial Prep Wt./Vol.: 30 mL
Container 10:1103076001-6
Analyst: SHA
Analytical Batch: WTI3351
Analytical Method: SM20 2320B
Analysis Date/Time: 06/25/10 19:19
Dilution Factor: 1
Initial Prep Wt./Vol.: 50 mL
Container 10:1103076001-0
Analyst: LP
SGSNorth America Inc
EnvronmentalDivision 200 WestPotter D rive Anchorage AK 9951 8 t(907 )562.2343 f( 907)561 .5301
w ww.us.sgs.com
M ember of SG S Group
-------
Shaw Env & Infrastructure Inc.
Print Date: 7/12/2010 3:23 pm
Client Sample ID: 06231 OFYUPZ04WG001
SGSRef. #: 11 03076001
Project ID: RARE-AK Ft. Yukon Tribal LF
Matrix: Water (Surface, Eff., Ground)
Semivolatile Organic GC/MS
Parameter
1 ,2,4-Trichlorobenzene
1 ,2-Dichlorobenzene
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methyl-4,6-dinitrophenol
2-Methylnaphthalene
2-Methylphenol (o-Cresol)
2-Nitroaniline
2-Nitrophenol
3&4-Methylphenol (p&m-Cresol)
3,3-Dichlorobenzidine
3-Nitroaniline
4-Bromophenyl-phenylether
4-Chloro-3-methylphenol
4-Chloroaniline
4-Chlorophenyl-phenylether
4-Nitroaniline
4-Nitrophenol
Acenaphthene
Acenaphthylene
Aniline
Anthracene
Azobenzene
Benzo(a)Anthracene
Benzo[a]pyrene
Benzo[b]Fluoranthene
Benzo[g,h,i]perylene
SGSNorth America Inc.
Result
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.385 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.385 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.154 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.385 U
0.0769 U
0.0769 U
0.385 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
Envir onm ental Div
w ww.us.sgs. com
LOQ/CL
0.0769
0.0769
0.0769
0.0769
0.0769
0.0769
0.0769
0.0769
0.385
0.0769
0.0769
0.0769
0.0769
0.385
0.0769
0.0769
0.0769
0.0769
0.154
0.0769
0.0769
0.0769
0.0769
0.0769
0.0769
0.0769
0.385
0.0769
0.0769
0.385
0.0769
0.0769
0.0769
0.0769
0.0769
0.0769
ision 200 WestPottei
Collection Date/Time: 06/23/10 15:00
Receipt Date/Time: 06/25/10 15:30
Location: PZ04
Units DF
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
Analytical
Batch
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
Prep
Batch Qualifiers
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
Drive Anchorage AK 99518 1(907)562.2343 f( 907)561 5301
M ember of SG S Group
-------
Shaw Env & Infrastructure Inc.
Print Date: 7/12/2010 3:23 pm
Client Sample ID: 06231 OFYUPZ04WG001
SGSRef. #: 11 03076001
Project ID: RARE-AK Ft. Yukon Tribal LF
Matrix: Water (Surface, Eff., Ground)
Semivolatile Organic GC/MS
Parameter
Benzo[k]fluoranthene
Benzole acid
Benzyl alcohol
Bis(2chloro1 methylethyl)Ether
Bis(2-Chloroethoxy)methane
Bis(2-Chloroethyl)ether
bis(2-Ethylhexyl)phthalate
Butylbenzylphthalate
Chrysene
Dibenzo[a,h]anthracene
Dibenzofuran
Diethylphthalate
Dimethylphthalate
Di-n-butylphthalate
di-n-Octylphthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
lndeno[1,2,3-c,d] pyrene
Isophorone
Naphthalene
Nitrobenzene
N-Nitrosodimethylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
2,4,6-Tribromophenol
2-Fluorobiphenyl
2-Fluorophenol
Nitrobenzene-d5
Phenol-d6
SGSNorth America Inc.
Result
0.0769 U
0.385 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.231 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.0769 U
0.385 U
0.0769 U
0.0769 U
0.0769 U
81.1
68.3
58.7
55.3
58.9
Envir onm ental Div
w ww.us.sgs. com
LOQ/CL
0.0769
0.385
0.0769
0.0769
0.0769
0.0769
0.0769
0.0769
0.0769
0.0769
0.0769
0.0769
0.0769
0.0769
0.0769
0.0769
0.0769
0.0769
0.0769
0.231
0.0769
0.0769
0.0769
0.0769
0.0769
0.0769
0.0769
0.0769
0.385
0.0769
0.0769
0.0769
45-124
50-110
21-88
41-110
28-97
ision 200 WestPottei
Collection Date/Time: 06/23/10 15:00
Receipt Date/Time: 06/25/10 15:30
Location: PZ04
Units DF
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
% 1
% 1
% 1
% 1
% 1
Analytical
Batch
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
Prep
Batch Qualifiers
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
Drive Anchorage AK 99518 1(907)562.2343 f( 907)561 5301
M ember of SG S Group
-------
Shaw Env & Infrastructure Inc.
Print Date: 7/12/2010 3:23 pm
Client Sample ID: 06231OFYUPZ04WG001
SGSRef. #: 1103076001
Project ID: RARE-AK Ft. Yukon Tribal LF
Matrix: Water (Surface, Eff., Ground)
Collection Date/Time: 06/23/10 15:00
Receipt Date/Time: 06/25/10 15:30
Location: PZ04
Semivolatile Organic GC/MS
Parameter
Terphenyl-d14
Batch Information
Analytical Batch: XMS5496
Analytical Method: SW8270D
Analysis Date/Time: 07/02/10 00:54
Dilution Factor: 1
Result
96.1
LOQ/CL
52-135
Analytical Prep
Units DF Batch Batch Qualifiers
% 1 XMS5496 XXX22939
Prep Batch: XXX22939
Prep Method: SW3520C
Prep Date/Time: 06/30/10 11:30
Initial PrepWt.A/ol.: 130 ml
Prep Extract Vol.: 1 ml
Container ID:1103076001-F
Analyst: JDH
SGSNorth America Inc
EnvronmentalDivision 200 WestPotter D rive Anchorage AK 9951 8 t(907 )562.2343 f( 907)561 .5301
w ww.us.sgs.com
M ember of SG S Group
-------
Shaw Env & Infrastructure Inc.
Print Date: 7/12/2010 3:23 pm
Client Sample ID: 06231OFYUSP01WS001
SGSRef. #: 1103076002
Project ID: RARE-AK Ft. Yukon Tribal LF
Matrix: Water (Surface, Eff., Ground)
Collection Date/Time: 06/23/10 12:45
Receipt Date/Time: 06/25/10 15:30
Location: SP01
Metals Department
Parameter
Mercury
Batch Information
Analytical Batch: MCV4567
Analytical Method: SW7470A/E245.1
Analysis Date/Time: 07/07/10 15:38
Dilution Factor: 1
Result
LOQ/CL
Units
DF
Analytical Prep
Batch Batch
Qualifiers
0.200 U 0.200 ug/L
Prep Batch: MXX23182
Prep Method: METHOD
Prep Date/Time: 07/06/10 11:30
MCV4567 MXX23182
Initial PrepWt.A/ol.: 25 ml
Prep Extract Vol.: 50 ml
Container ID:1103076002-A
Analyst: RTS
SGSNorth America Inc
EnvronmentalDivision 200 WestPotter D rive Anchorage AK 9951 8 t(907 )562.2343 f( 907)561 .5301
w ww.us.sgs.com
M ember of SG S Group
-------
Shaw Env & Infrastructure Inc.
Print Date: 7/12/2010 3:23 pm
Client Sample ID: 06231OFYUSP01WS001
SGSRef. #: 1103076002
Project ID: RARE-AK Ft. Yukon Tribal LF
Matrix: Water (Surface, Eff., Ground)
Collection Date/Time: 06/23/10 12:45
Receipt Date/Time: 06/25/10 15:30
Location: SP01
Waters Department
Parameter
Result
LOQ/CL
Units
DF
Analytical
Batch
Prep
Batch
Qualifiers
Alkalinity
Total Dissolved Solids
Total Organic Carbon
TPH Silica Gel HEM
Batch Information
Analytical Batch: TPH2194
Analytical Method: EPA 1664A
Analysis Date/Time: 07/01/10 12:30
Dilution Factor: 1
318
2330
22.2
32.0 U
10.0
10.0
0.500
32.0
Prep Batch: TPHX2011
Prep Method: EXTJ664TP
Prep Date/Time: 07/01/10 12:30
mg/L 1 WTI3351
mg/L 1 WAT8246
mg/L 1 WTC1995
mg/L 1 TPH2194 TPHX2011
Initial Prep Wt./Vol.: 125 mL
Prep Extract Vol.: 50 mL
Container ID:1103076002-C
Analyst: RTS
Analytical Batch: WAT8246
Analytical Method: SM20 2540C
Analysis Date/Time: 06/29/10 12:00
Dilution Factor: 1
Initial Prep Wt./Vol.: 100 mL
Container ID: 1103076002-E
Analyst: JJR
Analytical Batch: WTC1995
Analytical Method: SM 531 OB
Analysis Date/Time: 07/01/10 11:42
Dilution Factor: 1
Initial Prep Wt./Vol.: 30 mL
Container 10:1103076002-6
Analyst: SHA
Analytical Batch: WTI3351
Analytical Method: SM20 2320B
Analysis Date/Time: 06/25/10 19:31
Dilution Factor: 1
Initial Prep Wt./Vol.: 50 mL
Container 10:1103076002-0
Analyst: LP
SGSNorth America Inc
EnvronmentalDivision 200 WestPotter D rive Anchorage AK 9951 8 t(907 )562.2343 f( 907)561 .5301
w ww.us.sgs.com
M ember of SG S Group
-------
Shaw Env & Infrastructure Inc.
Print Date: 7/12/2010 3:23 pm
Client Sample ID: 06231 OFYUSP01WS001
SGSRef. #: 11 03076002
Project ID: RARE-AK Ft. Yukon Tribal LF
Matrix: Water (Surface, Eff., Ground)
Semivolatile Organic GC/MS
Parameter
1 ,2,4-Trichlorobenzene
1 ,2-Dichlorobenzene
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methyl-4,6-dinitrophenol
2-Methylnaphthalene
2-Methylphenol (o-Cresol)
2-Nitroaniline
2-Nitrophenol
3&4-Methylphenol (p&m-Cresol)
3,3-Dichlorobenzidine
3-Nitroaniline
4-Bromophenyl-phenylether
4-Chloro-3-methylphenol
4-Chloroaniline
4-Chlorophenyl-phenylether
4-Nitroaniline
4-Nitrophenol
Acenaphthene
Acenaphthylene
Aniline
Anthracene
Azobenzene
Benzo(a)Anthracene
Benzo[a]pyrene
Benzo[b]Fluoranthene
Benzo[g,h,i]perylene
SGSNorth America Inc.
Result
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.400 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.400 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.160 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.400 U
0.0800 U
0.0800 U
0.400 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
Envir onm ental Div
w ww.us.sgs. com
LOQ/CL
0.0800
0.0800
0.0800
0.0800
0.0800
0.0800
0.0800
0.0800
0.400
0.0800
0.0800
0.0800
0.0800
0.400
0.0800
0.0800
0.0800
0.0800
0.160
0.0800
0.0800
0.0800
0.0800
0.0800
0.0800
0.0800
0.400
0.0800
0.0800
0.400
0.0800
0.0800
0.0800
0.0800
0.0800
0.0800
ision 200 WestPottei
Collection Date/Time: 06/23/10 12:45
Receipt Date/Time: 06/25/10 15:30
Location: SP01
Units DF
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
Analytical
Batch
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
Prep
Batch Qualifiers
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
Drive Anchorage AK 99518 1(907)562.2343 f( 907)561 5301
M ember of SG S Group
-------
Shaw Env & Infrastructure Inc.
Print Date: 7/12/2010 3:23 pm
Client Sample ID: 06231 OFYUSP01WS001
SGSRef. #: 11 03076002
Project ID: RARE-AK Ft. Yukon Tribal LF
Matrix: Water (Surface, Eff., Ground)
Semivolatile Organic GC/MS
Parameter
Benzo[k]fluoranthene
Benzole acid
Benzyl alcohol
Bis(2chloro1 methylethyl)Ether
Bis(2-Chloroethoxy)methane
Bis(2-Chloroethyl)ether
bis(2-Ethylhexyl)phthalate
Butylbenzylphthalate
Chrysene
Dibenzo[a,h]anthracene
Dibenzofuran
Diethylphthalate
Dimethylphthalate
Di-n-butylphthalate
di-n-Octylphthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
lndeno[1,2,3-c,d] pyrene
Isophorone
Naphthalene
Nitrobenzene
N-Nitrosodimethylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
2,4,6-Tribromophenol
2-Fluorobiphenyl
2-Fluorophenol
Nitrobenzene-d5
Phenol-d6
SGSNorth America Inc.
Result
0.0800 U
0.400 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.240 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.0800 U
0.400 U
0.0800 U
0.0800 U
0.0800 U
98.9
88.4
73.1
76.1
73.8
Envir onm ental Div
w ww.us.sgs. com
LOQ/CL
0.0800
0.400
0.0800
0.0800
0.0800
0.0800
0.0800
0.0800
0.0800
0.0800
0.0800
0.0800
0.0800
0.0800
0.0800
0.0800
0.0800
0.0800
0.0800
0.240
0.0800
0.0800
0.0800
0.0800
0.0800
0.0800
0.0800
0.0800
0.400
0.0800
0.0800
0.0800
45-124
50-110
21-88
41-110
28-97
ision 200 WestPottei
Collection Date/Time: 06/23/10 12:45
Receipt Date/Time: 06/25/10 15:30
Location: SP01
Units DF
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
mg/L 1
% 1
% 1
% 1
% 1
% 1
Analytical
Batch
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
XMS5496
Prep
Batch Qualifiers
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
XXX22939
Drive Anchorage AK 99518 1(907)562.2343 f( 907)561 5301
M ember of SG S Group
-------
Shaw Env & Infrastructure Inc.
Print Date: 7/12/2010 3:23 pm
Client Sample ID: 06231OFYUSP01WS001
SGSRef. #: 1103076002
Project ID: RARE-AK Ft. Yukon Tribal LF
Matrix: Water (Surface, Eff., Ground)
Collection Date/Time: 06/23/10 12:45
Receipt Date/Time: 06/25/10 15:30
Location: SP01
Semivolatile Organic GC/MS
Parameter
Terphenyl-d14
Batch Information
Analytical Batch: XMS5496
Analytical Method: SW8270D
Analysis Date/Time: 07/01/10 19:00
Dilution Factor: 1
Result
99.2
LOQ/CL
52-135
Analytical Prep
Units DF Batch Batch Qualifiers
% 1 XMS5496 XXX22939
Prep Batch: XXX22939
Prep Method: SW3520C
Prep Date/Time: 06/30/10 11:30
Initial PrepWt.A/ol.: 125 ml
Prep Extract Vol.: 1 ml
Container ID: 1103076002-F
Analyst: JDH
SGSNorth America Inc
EnvronmentalDivision 200 WestPotter D rive Anchorage AK 9951 8 t(907 )562.2343 f( 907)561 .5301
w ww.us.sgs.com
M ember of SG S Group
-------
SGS Ref.# 969795 Method Blank
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Ft. Yukon Tribal LF
Matrix Water (Surface, Eff , Ground)
Printed Date/Time 07/12/2010 15:23
Prep Batch
Method
Date
QC results affect the following production samples:
1103076001,1103076002
Parameter Results LOQ/CL DL
Analysis
Units Date
Waters Department
Alkalinity
Batch
Method
Instrument
6.20 U
10.0
3.10
06/25/10
WTI3351
SM20 2320B
Titration
-------
SGS Ref.# 970376 Method Blank
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Ft. Yukon Tribal LF
Matrix Water (Surface, Eff , Ground)
Printed Date/Time
Prep Batch
Method
Date
07/12/2010 15:23
XXX22939
SW3520C
06/30/2010
QC results affect the following production samples:
1103076001,1103076002
Parameter Results LOQ/CL DL
Units
Analysis
Date
Semivolatile Organic GC/MS
-------
SGS Ref.# 970376 Method Blank
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Ft. Yukon Tribal LF
Matrix Water (Surface, Eff , Ground)
Parameter
Semi volatile Organic GC/MS
1,2,4-Trichlorobenzene
1 ,2-Dichlorobenzene
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methyl-4,6-dinitrophenol
2-Methylnaphthalene
2-Methylphenol (o-Cresol)
2-Nitroaniline
2-Nitrophenol
3&4-Methylphenol (p&m-Cresol)
3,3-Dichlorobenzidine
3-Nitroaniline
4-Bromophenyl-phenyl ether
4-Chloro-3-methylphenol
4-Chloroaniline
4-Chlorophenyl-phenyl ether
4-Nitroaniline
4-Nitrophenol
Acenaphthene
Acenaphthylene
Aniline
Anthracene
Azobenzene
Benzo(a)Anthracene
Benzo[a]pyrene
Benzo[b]Fluoranthene
Benzo[g,h,i]perylene
Benzo[k]fluoranthene
Benzoic acid
Benzyl alcohol
Results
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.0300 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.0300 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.0124 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.0300 U
0.00620 U
0.00620 U
0.0300 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.0500 U
0.00620 U
LOQ/CL
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0500
0.0100
0.0100
0.0100
0.0100
0.0500
0.0100
0.0100
0.0100
0.0100
0.0200
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0500
0.0100
0.0100
0.0500
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0500
0.0100
DL
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.0150
0.00310
0.00310
0.00310
0.00310
0.0150
0.00310
0.00310
0.00310
0.00310
0.00620
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.0150
0.00310
0.00310
0.0150
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.0250
0.00310
Printed Date/Time
Prep Batch
Method
Date
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
07/12/2010 15:23
XXX22939
SW3520C
06/30/2010
Analysis
Date
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
-------
SGS Ref.# 970376 Method Blank
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Ft. Yukon Tribal LF
Matrix Water (Surface, Eff , Ground)
Parameter
Semi volatile Organic GC/MS
Bi s(2chloro 1 methyl ethy l)Ether
Bis(2-Chloroethoxy)methane
Bis(2-Chloroethyl)ether
bis(2-Ethylhexyl)phthalate
Butylbenzylphthalate
Chrysene
Dibenzo[a,h]anthracene
Dibenzofuran
Diethylphthalate
Dimethylphthalate
Di-n-butylphthalate
di-n-Octylphthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno[l,2,3-c,d] pyrene
Isophorone
Naphthalene
Nitrobenzene
N-Nitrosodimethylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
Surrogates
2,4,6-Tribromophenol
2-Fluorobiphenyl
2-Fluorophenol
Nitrobenzene-d5
Phenol-d6
Terphenyl-dl4
Results
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.0188 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.00620 U
0.0300 U
0.00620 U
0.00620 U
0.00620 U
73.4
71.9
58.8
63
62.4
91.5
LOQ/CL
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0300
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0100
0.0500
0.0100
0.0100
0.0100
45-124
50-110
21-88
41-110
28-97
52-135
DL
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00940
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.00310
0.0150
0.00310
0.00310
0.00310
Printed Date/Time
Prep Batch
Method
Date
Units
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
%
%
%
%
%
%
07/12/2010 15:23
XXX22939
SW3520C
06/30/2010
Analysis
Date
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
07/01/10
-------
SGS Ref.#
Client Name
Project Name/#
Matrix
Parameter
Semi volatile
Batch
Method
Instrument
970376 Method Blank
Shaw Env & Infrastructure Inc.
RARE-AK Ft. Yukon Tribal LF
Water (Surface, Eff, Ground)
Results LOQ/CL DL
Organic GC/MS
XMS5496
SW8270D
HP 6890/5973 SSA
Printed Date/Time 07/12/2010 15:23
Prep Batch XXX22939
Method SW3520C
Date 06/30/2010
Analysis
Units Date
-------
SGS Ref.#
Client Name
Project Name/#
Matrix
970482 Method Blank
Shaw Env & Infrastructure Inc.
RARE-AK Ft. Yukon Tribal LF
Water (Surface, Eff, Ground)
Printed Date/Time
Prep Batch
Method
Date
07/12/2010 15:23
QC results affect the following production samples:
1103076001,1103076002
Parameter
Results
LOQ/CL
DL
Units
Analysis
Date
Waters Department
Total Dissolved Solids
Batch WAT8246
Method SM20 2540C
Instrument
6.20 U
10.0
3.10
06/29/10
-------
SGS Ref.# 970856 Method Blank
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Ft. Yukon Tribal LF
Matrix Water (Surface, Eff , Ground)
Printed Date/Time 07/12/2010 15:23
Prep Batch
Method
Date
QC results affect the following production samples:
1103076001,1103076002
Parameter Results LOQ/CL DL
Analysis
Units Date
Waters Department
Total Organic Carbon
Batch WTC1995
Method SM5310B
Instrument TOC Analyzer
0.418J
0.500
0.150
07/01/10
-------
SGS Ref.# 970959 Method Blank
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Ft. Yukon Tribal LF
Matrix Water (Surface, Eff , Ground)
Printed Date/Time
Prep Batch
Method
Date
07/12/2010 15:23
TPHX2011
EXTJ664TP
07/01/2010
QC results affect the following production samples:
1103076001,1103076002
Parameter Results LOQ/CL DL
Units
Analysis
Date
Waters Department
TPH Silica Gel HEM
Batch TPH2194
Method EPA 1664 A
Instrument
2.40 U
4.00
1.20
07/01/10
-------
SGSRef.# 971763 Method Blank
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Ft. Yukon Tribal LF
Matrix Water (Surface, Eff , Ground)
Printed Date/Time 07/12/2010 15:23
Prep Batch MXX23182
Method METHOD
Date 07/06/2010
QC results affect the following production samples:
1103076001,1103076002
Parameter Results LOQ/CL
Metals Department
Mercury 0.124U 0.200
Batch MCV4567
Method S W7470A/E245 . 1
Instrument PSA Millennium mercury AA
Analysis
DL Units Date
0.0620 ug/L 07/07/10
-------
SGS Ref.# 969797 Duplicate
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Ft. Yukon Tribal LF
Original 1103067001
Matrix Water (Surface, Eff, Ground)
Printed Date/Time 07/12/2010 15:23
Prep Batch
Method
Date
QC results affect the following production samples:
1103076001,1103076002
Original
Parameter Result
QC RPD Analysis
Result Umts RP0 Limits Date
Waters Department
Alkalinity
Batch
Method
Instrument
187
WTI3351
SM20 2320B
Titration
188 mg/L
06/25/2010
-------
SGS Ref.# 970484 Duplicate
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Ft. Yukon Tribal LF
Original 1102845008
Matrix Water (Surface, Eff, Ground)
Printed Date/Time 07/12/2010 15:23
Prep Batch
Method
Date
QC results affect the following production samples:
1103076001,1103076002
Original
Parameter Result
QC RPD Analysis
Result Umts RP0 Limits Date
Waters Department
Total Dissolved Solids
Batch WAT8246
Method SM20 2540C
Instrument
108
87.0 mg/L
22
06/29/2010
-------
SGS Ref.# 970485 Duplicate
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Ft. Yukon Tribal LF
Original 1103098001
Matrix Water (Surface, Eff, Ground)
Printed Date/Time 07/12/2010 15:23
Prep Batch
Method
Date
QC results affect the following production samples:
1103076001,1103076002
Original
Parameter Result
QC RPD Analysis
Result Umts RP0 Limits Date
Waters Department
Total Dissolved Solids
Batch WAT8246
Method SM20 2540C
Instrument
202
193
mg/L
06/29/2010
-------
SGS Ref.#
Client Name
Project Name/#
Original
Matrix
971768 Duplicate
Shaw Env & Infrastructure Inc.
RARE-AK Ft. Yukon Tribal LF
1102849022
Water (Surface, Eff., Ground)
Printed Date/Time 07/12/2010
Prep Batch MXX23182
Method METHOD
Date 7/6/2010 11
15:23
:30:OOAM
QC results affect the following production samples:
1103076001,1103076002
Parameter
Original
Result
QC RPD
Result Umts RP0 Limits
Analysis
Date
Metals Department
Mercury
Batch
Method
Instrument
MCV4567
SW7470A/E245.1
PSA Millennium mercury AA
0.124U
0.124U ug/L
07/07/2010
-------
SGS Ref.#
Client Name
Project Name/#
Original
Matrix
971770 Duplicate
Shaw Env & Infrastructure Inc.
RARE-AK Ft. Yukon Tribal LF
1102849057
Water (Surface, Eff., Ground)
Printed Date/Time 07/12/2010
Prep Batch MXX23182
Method METHOD
Date 7/6/2010 11
15:23
:30:OOAM
QC results affect the following production samples:
1103076001,1103076002
Parameter
Original
Result
QC RPD
Result Umts RP0 Limits
Analysis
Date
Metals Department
Mercury
Batch
Method
Instrument
MCV4567
SW7470A/E245.1
PSA Millennium mercury AA
0.124U
0.124U ug/L
07/07/2010
-------
SGS Ref.# 969796 Lab Control Sample
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Ft. Yukon Tribal LF
Matrix Water (Surface, Eff, Ground)
QC results affect the following production samples:
1103076001,1103076002
QC Pet
Parameter Results Recov
Waters Department
Alkalinity LCS 245 98
Batch WTI3351
Method SM20 2320B
Instrument fitration
Printed Date/Time 07/12/2010 15:23
Prep Batch
Method
Date
LCS/LCSD RPD Spiked Analysis
Limits RPD Limits Amount Date
(85-115) 250 mg/L 06/25/2010
-------
SGS Ref.# 970377 Lab Control Sample
970378 Lab Control Sample Duplicate
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Ft. Yukon Tribal LF
Matrix Water (Surface, Eff, Ground)
Printed Date/Time
Prep Batch
Method
Date
07/12/2010
XXX22939
SW3520C
06/30/2010
15:23
QC results affect the following production samples:
1103076001,1103076002
QC Pet LCS/LCSD
Parameter Results Recov Limits
RPD
RPD Limits
Spiked
Amount
Analysis
Date
Semivolatile Organic GC/MS
-------
SGS Ref.# 970377 Lab Control Sample Printed Date/Time
970378 Lab Control Sample Duplicate FreP Batch
Client Name Shaw Env & Infrastructure Inc. Method
Project Name/# RARE-AK Ft. Yukon Tribal LF Date
Matrix Water (Surface, Eff, Ground)
Parameter
QC
Results
Pet LCS/LCSD RPD
Recov Limits RPD Limits
07/12/2010
XXX22939
SW3520C
06/30/2010
Spiked
Amount
15:23
Analysis
Date
Semivolatile Organic GC/MS
1 ,2,4-Trichlorobenzene
1 ,2-Dichlorobenzene
1 ,3-Dichlorobenzene
1 ,4-Dichlorobenzene
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methyl-4,6-dinitrophenol
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
0.0828
0.0849
0.0819
0.0869
0.0790
0.0854
0.0783
0.0836
0.113
0.111
0.110
0.109
0.0929
0.0970
0.0724
0.0694
0.205
0.109
0.116
0.119
0.108
0.107
0.0834
0.0830
0.0903
0.0947
0.234
0.133
83 (37-104)
85 3 (< 20 )
82 ( 35-99 )
87 6 (< 20 )
79 ( 32-98 )
85 8 (<20)
78 ( 32-97 )
84 7 (< 20 )
113 * (50-110)
111 * 2 (<20)
110 (50-115)
109 2 (<20)
93 (50-105)
97 4 (< 20 )
72 ( 32-86 )
69 4 (<20)
114 (29-130)
60 61 * (<20)
116 * (55-115)
119 * 3 (<20)
108 (55-115)
107 2 (<20)
83 (50-105)
83 0 (< 20 )
90 ( 37-97 )
95 5 (< 20 )
130 (43-130)
74 55 * (<20)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.18
0.18
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.18
0.18
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
-------
SGS Ref.# 970377 Lab Control Sample Printed Date/Time
970378 Lab Control Sample Duplicate FreP Batch
Client Name Shaw Env & Infrastructure Inc. Method
Project Name/# RARE-AK Ft. Yukon Tribal LF Date
Matrix Water (Surface, Eff, Ground)
Parameter
QC
Results
Pet LCS/LCSD RPD
Recov Limits RPD Limits
07/12/2010
XXX22939
SW3520C
06/30/2010
Spiked
Amount
15:23
Analysis
Date
Semivolatile Organic GC/MS
2-Methylnaphthalene
2-Methylphenol (o-Cresol)
2-Nitroaniline
2-Nitrophenol
3&4-Methylphenol (p&m-Cresol)
3,3-Dichlorobenzidine
3-Nitroaniline
4-Bromophenyl-phenylether
4-Chloro-3-methylphenol
4-Chloroaniline
4-Chlorophenyl-phenylether
4-Nitroaniline
4-Nitrophenol
Acenaphthene
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
0.0933
0.0932
0.0907
0.0698
0.111
0.108
0.0969
0.0926
0.135
0.142
0.116
0.0927
0.114
0.109
0.0914
0.0856
0.109
0.109
0.0853
0.0841
0.0977
0.0950
0.125
0.120
0.149
0.151
0.0974
93 (46-105)
93 0 (< 20 )
91 (38-99)
70 26 * (<20)
111 (54-115)
108 2 (<20)
97 (40-109)
93 5 (< 20 )
96 (38-105)
101 5 (<20)
116 * (53-110)
93 22 * (<20)
114 (54-125)
109 5 (<20)
91 (52-110)
86 7 (< 20 )
109 (50-110)
109 0 (<20)
85 (37-110)
84 2 (< 20 )
98 (50-110)
95 3 (< 20 )
125 * (52-120)
120 5 (< 20 )
106 (42-112)
108 1 (<20)
97 (53-110)
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.14
0.14
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.1
0.14
0.14
0.1
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
-------
SGSRef.# 970377 Lab Control Sample Printed Date/Time 07/12/2010
970378 Lab Control Sample Duplicate FreP Batch XXX22939
Client Name Shaw Env & Infrastructure Inc. Method SW3520C
Project Name/# RARE- AK Ft. Yukon Tribal LF Date 06/30/2010
Matrix Water (Surface, Eff, Ground)
Parameter
QC
Results
Pet LCS/LCSD
Recov Limits RPD
RPD Spiked
Limits Amount
15:23
Analysis
Date
Semivolatile Organic GC/MS
Acenaphthylene
Aniline
Anthracene
Azobenzene
Benzo(a)Anthracene
Benzo[a]pyrene
Benzo[b]Fluoranthene
Benzo [g,h,i] pery lene
Benzo[k]fluoranthene
Benzoic acid
Benzyl alcohol
Bis(2chlorolmethylethyl)Ether
Bis(2-Chloroethoxy)methane
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
0.0926
0.0997
0.0967
0.0719
0.0693
0.111
0.107
0.105
0.0966
0.113
0.114
0.113
0.110
0.105
0.100
0.122
0.115
0.103
0.109
0.133
0.135
0.0932
0.0986
0.0848
0.0866
0.0902
0.0893
93 5
100 (53-105)
97 3
72 (21-119)
69 4
111 * (59-110)
107 4
105 (52-124)
97 8
113 * (64-110)
114 * 0
113 * (58-110)
110 3
105 (57-120)
100 4
122 (48-123)
115 6
103 (58-124)
109 6
95 (20-101)
97 2
93 (38-110)
99 6
85 (36-103)
87 2
90 (46-105)
89 1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.14
(<20) 0.14
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
-------
SGSRef.# 970377 Lab Control Sample Printed Date/Time 07/12/2010
970378 Lab Control Sample Duplicate FreP Batch XXX22939
Client Name Shaw Env & Infrastructure Inc. Method SW3520C
Project Name/# RARE- AK Ft. Yukon Tribal LF Date 06/30/2010
Matrix Water (Surface, Eff, Ground)
Parameter
QC
Results
Pet LCS/LCSD
Recov Limits RPD
RPD Spiked
Limits Amount
15:23
Analysis
Date
Semivolatile Organic GC/MS
Bis(2-Chloroethyl)ether
bis(2-Ethylhexyl)phthalate
Butylbenzylphthalate
Chrysene
Dibenzo[a,h]anthracene
Dibenzofuran
Diethylphthalate
Dimethylphthalate
Di-n-butylphthalate
di-n-Octylphthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
0.0831
0.0850
0.118
0.121
0.117
0.122
0.107
0.105
0.118
0.115
0.103
0.100
0.111
0.110
0.106
0.103
0.112
0.109
0.117
0.122
0.113
0.113
0.0892
0.0891
0.110
0.105
0.0882
0.0915
83 (37-100)
85 2
118 (59-125)
121 3
117 * (58-115)
122 * 4
107 (63-110)
105 2
118 (53-125)
115 3
103 (55-105)
100 3
111 (51-120)
110 1
106 (36-125)
103 2
112 (55-115)
109 3
117 (52-131)
122 4
113 (59-115)
113 1
89 (56-110)
89 0
110 (54-110)
105 4
88 (38-105)
92 4
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
0.1
(<20) 0.1
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
-------
SGS Ref.# 970377 Lab Control Sample
970378 Lab Control Sample Duplicate
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Ft. Yukon Tribal LF
Matrix Water (Surface, Eff, Ground)
Parameter
QC
Results
Pet
Recov
Printed Date/Time 07/12/2010
Prep Batch XXX22939
Method SW3520C
Date 06/30/2010
LCS/LCSD RPD Spiked
Limits RPD Limits Amount
15:23
Analysis
Date
Semivolatile Organic GC/MS
Hexachlorocyclopentadiene
Hexachloroethane
Indeno[l,2,3-c,d] pyrene
Isophorone
Naphthalene
Nitrobenzene
N-Nitrosodimethylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
0.0373
0.0265
0.0785
0.0832
0.117
0.112
0.0937
0.0890
0.0878
0.0833
0.0899
0.0886
0.0843
0.0898
0.0881
0.0848
0.0895
0.0829
0.181
0.160
0.110
0.108
0.0889
0.0914
0.111
0.112
37
27
79
83
117
112
94
89
88
83
90
89
84
90
88
85
90
83
129 *
114
110
108
89
91
111
112
(10-58) 0.1
34 * (<20) 0.1
(30-95) 0.1
6 (<20) 0.1
(51-125) 0.1
4 (<20) 0.1
(50-110) 0.1
5 (<20) 0.1
(45-100) 0.1
5 (<20) 0.1
(45-105) 0.1
2 (<20) 0.1
(27-100) 0.1
6 (<20) 0.1
(42-108) 0.1
4 (<20) 0.1
(53-110) 0.1
8 (<20) 0.1
(51-115) 0.14
12 (<20) 0.14
(58-115) 0.1
3 (<20) 0.1
(26-92) 0.1
3 (<20) 0.1
(62-128) 0.1
1 (<20) 0.1
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/06/2010
07/01/2010
07/01/2010
Surrogates
-------
SGSRef.# 970377 Lab Control Sample Printed Date/Time 07/12/2010 15:23
970378 Lab Control Sample Duplicate FreP Batch XXX22939
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Ft.
Matrix Water (Surface
Parameter
Semivolatile Organic GC/MS
2,4,6-Tribromophenol
2-Fluorobiphenyl
2-Fluorophenol
Nitrobenzene-d5
Phenol-d6
Terphenyl-dl4
Yukon Tribal LF
, Eff, Ground)
QC
Results
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
LCS
LCSD
Pet LCS/LCSD
Recov Limits RPD
106 (45-124)
100 6
86 (50-110)
84 2
71 (21-88)
81 13
85 (41-110)
85 0
81 (28-97)
88 8
102 (52-135)
107 5
Method SW3520C
Date 06/30/2010
RPD Spiked Analysis
Limits Amount Date
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
07/01/2010
Batch XMS5496
Method SW8270D
Instrument HP 6890/5973 SSA
-------
SGS Ref.# 970483 Lab Control Sample
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Ft. Yukon Tribal LF
Matrix Water (Surface, Eff, Ground)
Printed Date/Time 07/12/2010 15:23
Prep Batch
Method
Date
QC results affect the following production samples:
1103076001,1103076002
QC Pet
Parameter Results Recov
Waters Department
Total Dissolved Solids LCS 312 95
Batch WAT8246
Method SM20 2540C
Instrument
LCS/LCSD RPD Spiked Analysis
Limits RPD Limits Amount Date
(75-125) 330 mg/L 06/29/2010
-------
SGS Ref.#
Client Name
Project Name/#
Matrix
970854 Lab Control Sample
Shaw Env & Infrastructure Inc.
RARE-AK Ft. Yukon Tribal LF
Water (Surface, Eff, Ground)
Printed Date/Time
Prep Batch
Method
Date
07/12/2010 15:23
QC results affect the following production samples:
1103076001,1103076002
Parameter
QC
Results
Pet
Recov
LCS/LCSD
Limits
RPD
RPD
Limits
Spiked
Amount
Analysis
Date
Waters Department
Total Organic Carbon
LCS
77.1
103
(80-120)
75 mg/L 07/01/2010
Batch WTC1995
Method SM5310B
Instrument XOC Analyzer
-------
SGS Ref.# 970960 Lab Control Sample
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Ft. Yukon Tribal LF
Matrix Water (Surface, Eff, Ground)
Printed Date/Time 07/12/2010
Prep Batch TPHX2011
Method EXTJ664TP
Date 07/01/2010
15:23
QC results affect the following production samples:
1103076001,1103076002
QC Pet
Parameter Results Recov
Waters Department
TPH Silica Gel HEM LCS 17.5 88
Batch TPH2194
Method EPA 1664A
Instrument
LCS/LCSD RPD Spiked
Limits RPD Limits Amount
(64-132) 20 mg/L
Analysis
Date
07/01/2010
-------
SGSRef.# 971764 Lab Control Sample
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Ft. Yukon Tribal LF
Matrix Water (Surface, Eff, Ground)
QC results affect the following production samples:
1103076001,1103076002
QC Pet
Parameter Results Recov
Metals Department
Mercury LCS 3.50 88
Batch MCV4567
Method SW7470A/E245.1
Instrument p<=A Millennium mercurv AA
Printed Date/Time 07/12/2010
Prep Batch MXX23182
Method METHOD
Date 07/06/2010
LCS/LCSD RPD Spiked
Limits RPD Limits Amount
(85-115) 4 ug/L
15:23
Analysis
Date
07/07/2010
-------
SGS Ref.# 970857
970858
Original 1103120003
Matrix Drinking Water
Matrix Spike
Matrix Spike Duplicate
Printed Date/Time
Prep Batch
Method
Date
07/12/2010 15:23
QC results affect the following production samples:
1103076001,1103076002
Parameter Qualifiers
Waters Department
Total Organic Carbon MS
MSB
Original QC Pet MS/MSD
Result Result Recov Limits
4.49 14.8 103 (75-125)
14.8 103
RPD
RPD Limits
0 (<25)
Spiked Analysis
Amount Date
10.0 mg/L 07/01/2010
10.0 mg/L 07/01/2010
Batch WTC1995
Method SM5310B
Instrument TOC Analyzer
-------
SGS Ref.# 970962 Matrix Spike
Original 970958
Matrix Water (Surface, Eff., Ground)
Printed Date/Time 07/12/2010 15:23
Prep Batch TPHX2011
Method Extraction for EPA 1 664 TPH S
Date 07/01/2010
QC results affect the following production samples:
1103076001,1103076002
Original QC
Parameter Qualifiers Result Result
Waters Department
TPH Silica Gel HEM MS 2.08J 17.4
Batch TPH2194
Method EPA 1664A
Instrument
Pet MS/MSD RPD Spiked Analysis
Recov Limits RPD Limits Amount Date
74 ( 64-132 ) 20.6 mg/L 07/01/2010
-------
SGSRef.# 971765 Matrix Spike
971766 Matrix Spike Duplicate
Original 1102849005
Matrix Water (Surface, Eff., Ground)
Printed Date/Time
Prep Batch
Method
Date
07/12/2010 15:23
MXX23182
Digestion Mercury (W)
07/06/2010
QC results affect the following production samples:
1103076001,1103076002
Original QC Pet MS/MSD
Parameter Qualifiers Result Result Recov Limits
Metals Department
Mercury MS (0.124)U 8.27 103 (85-115)
MSB 7.46 93
RPD
RPD Limits
10 (<15)
Spiked Analysis
Amount Date
8.00 ug/L 07/07/2010
8.00 ug/L 07/07/2010
Batch MCV4567
Method SW7470A/E245.1
Instrument PSA Millennium mercury AA
-------
SGSRef.# 971767 Matrix Spike
Original 1102849022
Matrix Water (Surface, Eff., Ground)
Printed Date/Time
Prep Batch
Method
Date
07/12/2010 15:23
MXX23182
Digestion Mercury (W)
07/06/2010
QC results affect the following production samples:
1103076001,1103076002
Original QC
Parameter Qualifiers Result Result
Pet MS/MSD RPD
Recov Limits RPD Limits
Spiked Analysis
Amount Date
Metals Department
Mercury MS (0.124)U 8
Batch MCV4567
Method SW7470A/E245.1
Instrument PSA Millennium mercury AA
100 (85-115)
8.00 ug/L 07/07/2010
-------
SGSRef.# 971769 Matrix Spike
Original 1102849057
Matrix Water (Surface, Eff., Ground)
Printed Date/Time
Prep Batch
Method
Date
07/12/2010 15:23
MXX23182
Digestion Mercury (W)
07/06/2010
QC results affect the following production samples:
1103076001,1103076002
Original QC
Parameter Qualifiers Result Result
Pet MS/MSD RPD
Recov Limits RPD Limits
Spiked Analysis
Amount Date
Metals Department
Mercury MS (0.124)U 8.96
Batch MCV4567
Method SW7470A/E245.1
Instrument PSA Millennium mercury AA
112 (85-115)
8.00 ug/L 07/07/2010
-------
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SAMPLE RECEIPT FORM
Review Criteria:
Condition:
1103076
Comments/Action Taken:
Were custody seals intact?
Note # & location if applicable.
COC accompanied samples?
No N/A
No N/A
Temperature blank compliant (i.e., 0-6°C after correction factor)?
No N/A
Cooler ID:
Cooler ID:
Cooler ID:
Cooler ID:
Cooler ID:
I
@.
w/ Therm. ID:
w/ Therm.ID:
w/ Therm.ID:
w/ Therm.ID:
w/ Therm.ID:
: If non-compliant, use form FS-0029 to document affected samples/analyses,
If samples are received without a temperature blank, the "cooler
temperature" will be documented in lieu of the temperature blank &
"COOLER TEMF' will be noted to the right. In cases where neither a
temp blank nor cooler temp can be obtained, note "ambient" or "chilled."
If temperature(s) <0°C, were all containers ice free?
Yes No
DeliKerjynethod,(specify all that apply):
CQjenlx USPS " Alert Courier Road Runner
AKAir Lynden Carlile ERA
FedEx UPS NAC PenAir
Other:
Note airbill/tracking #
See Attached
or N/A
* For samples received with payment, note amount ($ ) and cash / check / CC (circle one),
* For samples received in FBKS, ANCH staff will verify all criteria are reviewed.
SRF Initiated by:
Do samples match COC (i.e., sample IDs, dates/times collected)?
Are analyses requested unambiguous?
N/A
N/A
Were samples in good condition (no leaks/cracks/breakage)?
Packkigjnaterial used (specify all that apply):
^
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001 002
001 002
001 002
001 002
001 002
001 002
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Container I
Container I
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B B
C C
D D
E E
F F
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1 Water
1 Water
1 Water
1 Water
1 Water
0
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CONTAINERS
HNO3 (pH <2)
HCI (pH <2)
HCI (pH <2)
N/A
N/A
N/A
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W_Metals_Total/Diss.
W_TOC/DOC
W_Oil&Grease/TPH1664
W_Waters_Dept
W_Waters_Dept
W_SVOC
,BELS Notes:
ANOMALIES -
e.g., preservative added
or SPECIAL HANDLING -
e.g., Multi-Incremental (Ml),
Field Filter (FF), Lab Filter (LF),
use "same jar as" (SJA) for QC,
2xMeOH, bubbles, etc.
Type comments below:
&£nv*£M '\ferCto**4.. ltA*»?~f1\^_
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Page: 1 ; Printed: 6/25/2010
F066_SR F-BottleTracking (electron ic)_rev03-05212010
-------
Shaw Custody Seal
~
Signed
Shaw Custody Seal
fa
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\
Signed.
1103076
-------
SGS North America Inc.
Alaska Division
Level II Laboratory Data Report
Project: RARE-AK Tribal LanfillsAug2010
Client: Shaw Env & Infrastructure Inc.
SGS Work Order: 1104166
Released by:
Contents:
Cover Page
Case Narrative
Final Report Pages
Quality Control Summary Forms
Chain of Custody/Sample Receipt Forms
Note:
Unless otherwise noted, all quality assurance/quality control criteria is in compliance with the standards set forth by the proper regulatory authority, the
SGS Quality Assurance Program Plan, and the National Environmental Accreditation Conference.
-------
CASE NARRATIVE Print Date: 8/23/2010
Client Name: Shaw Env & Infrastructure Inc.
Project Name: RARE-AK Tribal LanfillsAug2010
Workorder No.: 1104166
Sample Comments
Refer to the sample receipt form for information on sample condition.
Lab Sample ID Sample Type Client Sample ID
There were no analytical anomalies associated with the data reported herein.
* QC comments may be associated with the field samples found in this report. When applicable, comments will be applied to
associated field samples.
SGSNorth America Inc. EnvironmentalDivision 200 WestPotter D rive Anchorage AK 9951 8 1(907)562.2343 f(907)S61 .5301
1 www.us.sgs.com M ember of SG S Group
-------
Laboratory Analytical Report
Client: Shaw Env & Infrastructure Inc.
2000 W. Int'l Airport, Ste C1
Anchorage, AK 99502
Attn: Jack James
T: F:
jack.james@shawgrp.com
Project: RARE-AK Tribal LanfillsAug2010
Workorder No.: 1104166
Certification:
This data package is in compliance with the terms and conditions of the contract, both
technically and for completeness, unless otherwise noted on the sample data sheet(s) and/or
case narrative. This certification applies only to the tested parameters and the specific
sample(s) received at the laboratory. If you have any questions regarding this report, or if we
can be of further assistance, please contact your SGS Project Manager.
Steve Crupi
steven.crupi@sgs.com
Project Manager
Contents (Bookmarked in PDF):
Cover Page
Glossary
Sample Summary Forms
Case Narrative
Sample Results Forms
Batch Summary Forms (by method)
Quality Control Summary Forms (by method)
Chain of Custody/Sample Receipt Forms
Attachments (if applicable)
SGSNorth America Inc. Environmental Division 200 We stPotter Drive Anchorage AK 9951 8t(907 )562.2343 f(907)561 .5301
www.us.sgs.com Member of SGS Group
-------
Print Date: 8/23/2010
Enclosed are the analytical results associated with the above work order. All results are intended to be used in their entirety and SGS is not
responsible for use of less than the complete report. If you have any questions regarding this report, or if we can be of any other assistance, please
contact your SGS Project Manager at 907-562-2343. All work is provided under SGS general terms and conditions
(), unless other written agreements have been accepted by both parties.
SGS maintains a formal Quality Assurance/Quality Control (QA/QC) program. A copy of our Quality Assurance Plan (QAP), which outlines this
program, is available at your request. The laboratory certification numbers are AK00971 (DW Chemistry & Microbiology) & UST-005 (CS) for
ADEC and AK100001 for NELAP (RCRA methods: 1020A, 1311, 3010A, 3050B, 3520C, 3550C, 5030B, 5035B, 6010B, 6020, 7470A, 7471B,
8021B, 8081B, 8082A, 8260B, 8270D, 8270D-SIM, 9040B, 9045C, 9056A, 9060A, AK101 and AK102/103). Except as specifically noted, all
statements and data in this report are in conformance to the provisions set forth by the SGS QAP and, when applicable, the National Environmental
Laboratory Accreditation Program and other regulatory authorities. The following descriptors or qualifiers may be found in your report:
* The analyte has exceeded allowable regulatory or control limits.
! Surrogate out of control limits.
B Indicates the analyte is found in a blank associated with the sample.
CCV Continuing Calibration Verification
CL Control Limit
D The analyte concentration is the result of a dilution.
DF Dilution Factor
DL Detection Limit (i.e., maximum method detection limit)
E The analyte result is above the calibrated range.
F Indicates value that is greater than or equal to the DL
GT Greater Than
ICV Initial Calibration Verification
J The quantitation is an estimation.
JL The analyte was positively identified, but the quantitation is a low estimation.
LCS(D) Laboratory Control Spike (Duplicate)
LOD Limit of Detection (i.e., 2xDL)
LOQ Limit of Quantitation (i.e., reporting or practical quantitation limit)
LT Less Than
M A matrix effect was present.
MB Method Blank
MS(D) Matrix Spike (Duplicate)
ND Indicates the analyte is not detected.
Q QC parameter out of acceptance range.
R Rejected
RL Reporting Limit
RPD Relative Percent Difference
U Indicates the analyte was analyzed for but not detected.
Note: Sample summaries which include a result for "Total Solids" have already been adjusted for moisture content.
All DRO/RRO analyses are integrated per SOP.
SGSNorth America Inc.
Environmental Division 200 West Potter D rive Anchorage AK 99518 t(907 )562.2343 f( 907)5 61 .5301
w ww.us.sgs .com M ember of SG S Group
-------
SAMPLE SUMMARY
Print Date: 8/23/2010 11:07 am
Client Name: Shaw Env & Infrastructure Inc.
Project Name: RARE-AK Tribal LanfillsAug2010
Workorder No.: 1104166
Analytical Methods
Method Description
Alkalinity as CaCOS QC
Total Dissolved Solids SM18 2540C
Total Organic Carbon
TPH by EPA 1664
Analytical Method
SM20 2320B
SM20 2540C
SM5310B
EPA1664A
Sample ID Cross Reference
Lab Sample ID
1104166001
1104166002
Client Sample ID
081110EKWPZ02WG001
081110EKWPZ03WG001
SGSNorth America Inc. Environm entalDivision 200 We stPotter D rive Anchorage AK 9951 8 1(907)562.2343 f( 907)561 .5301
www.us.sgs.com M ember of SGS Group
-------
Detectable Results Summary
Print Date: 8/23/2010 11:07 am
Client Sample ID: 081110EKWPZ02WG001
SGSRef. #: 1104166001
Waters Department
Parameter
Alkalinity
Total Dissolved Solids
Result
13.1
24.0
Units
mg/L
mg/L
Client Sample ID: 081110EKWPZ03WG001
SGSRef. #: 1104166002
Waters Department
Parameter
TPH Silica Gel HEM
Total Organic Carbon
Result
13.8
23.3
Units
mg/L
mg/L
SGSNorth America Inc.
Environmental Division 200 We stPotter D rive Anchorage AK 9951 8 t(907 )562
www.us.sgs.com
2343 f(907)561 .5301
M ember of SGS Group
-------
Shaw Env & Infrastructure Inc.
Print Date: 8/23/2010 11:07 am
Client Sample ID: 081110EKWPZ02WG001
SGSRef. #: 1104166001
Project ID: RARE-AK Tribal LanfillsAug2010
Matrix: Water (Surface, Eff., Ground)
Collection Date/Time: 08/11/10 12:06
Receipt Date/Time: 08/12/10 16:52
Location: PZ02
Waters Department
Parameter
Result
LOQ/CL
Units
DF
Analytical Prep
Batch Batch
Qualifiers
Alkalinity
Total Dissolved Solids
Batch Information
Analytical Batch: WAT8315
Analytical Method: SM20 2540C
Analysis Date/Time: 08/13/10 14:00
Dilution Factor: 1
13.1
24.0
10.0
10.0
mg/L
mg/L
1 WTI3389
1 WAT8315
Initial PrepWt.A/ol.: 100mL
Container 10:1104166001-A
Analyst: JJR
Analytical Batch: WTI3389
Analytical Method: SM20 2320B
Analysis Date/Time: 08/13/10 22:44
Dilution Factor: 1
Initial PrepWt.A/ol.: 50 ml
Container 10:1104166001-6
Analyst: LP
SGSNorth America Inc
EnvronmentalDivision 200 WestPotter D rive Anchorage AK 9951 8 t(907 )562.2343 f( 907)561 .5301
w ww.us.sgs.com
M ember of SG S Group
-------
Shaw Env & Infrastructure Inc.
Print Date: 8/23/2010 11:07 am
Client Sample ID: 081110EKWPZ03WG001
SGSRef. #: 1104166002
Project ID: RARE-AK Tribal LanfillsAug2010
Matrix: Water (Surface, Eff., Ground)
Collection Date/Time: 08/11/10 11:21
Receipt Date/Time: 08/12/10 16:52
Location: PZ03
Waters Department
Parameter
Result
LOQ/CL
Units
DF
Analytical Prep
Batch Batch
Qualifiers
Total Organic Carbon
TPH Silica Gel HEM
Batch Information
Analytical Batch: TPH2199
Analytical Method: EPA 1664A
Analysis Date/Time: 08/19/10 09:00
Dilution Factor: 1
23.3
13.8
0.500
5.41
Prep Batch: TPHX2016
Prep Method: EXTJ664TP
Prep Date/Time: 08/19/10 09:00
mg/L 1 WTC1999
mg/L 1 TPH2199 TPHX2016
Initial Prep Wt./Vol.: 740 ml
Prep Extract Vol.: 50 ml
Container 10:1104166002-6
Analyst: RTS
Analytical Batch: WTC1999
Analytical Method: SM 531 OB
Analysis Date/Time: 08/16/10 12:21
Dilution Factor: 1
Initial Prep Wt./Vol.: 30 ml
Container ID:1104166002-A
Analyst: KAR
SGSNorth America Inc
EnvronmentalDivision 200 WestPotter D rive Anchorage AK 9951 8 t(907 )562.2343 f( 907)561 .5301
w ww.us.sgs.com
M ember of SG S Group
-------
SGSRef.# 981266 Method Blank
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Tribal LanfillsAug2010
Matrix Water (Surface, Eff , Ground)
Printed Date/Time 08/23/2010 11:07
Prep Batch
Method
Date
QC results affect the following production samples:
1104166001
Parameter Results LOQ/CL DL
Analysis
Units Date
Waters Department
Alkalinity
Batch
Method
Instrument
6.20 U
10.0
3.10
8/13/10
WTI3389
SM20 2320B
Titration
-------
SGSRef.# 981352 Method Blank
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Tribal LanfillsAug2010
Matrix Water (Surface, Eff , Ground)
Printed Date/Time 08/23/2010 11:07
Prep Batch
Method
Date
QC results affect the following production samples:
1104166001
Parameter Results LOQ/CL DL
Analysis
Units Date
Waters Department
Total Dissolved Solids
Batch WAT8315
Method SM20 2540C
Instrument
6.20 U
10.0
3.10
8/13/10
-------
SGSRef.# 981623 Method Blank
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Tribal LanfillsAug2010
Matrix Water (Surface, Eff , Ground)
Printed Date/Time 08/23/2010 11:07
Prep Batch
Method
Date
QC results affect the following production samples:
1104166002
Parameter Results LOQ/CL DL
Analysis
Units Date
Waters Department
Total Organic Carbon
Batch WTC1999
Method SM5310B
Instrument TOC Analyzer
0.300 U
0.500
0.150
08/16/10
-------
SGS Ref.#
Client Name
Project Name/#
Matrix
982798 Method Blank
Shaw Env & Infrastructure Inc.
RARE-AK Tribal LanfillsAug2010
Water (Surface, Eff, Ground)
Printed Date/Time
Prep Batch
Method
Date
08/23/2010 11:07
TPHX2016
EXTJ664TP
08/19/2010
QC results affect the following production samples:
1104166002
Parameter
Results LOQ/CL DL
Units
Analysis
Date
Waters Department
TPH Silica Gel HEM
Batch TPH2199
Method EPA 1664 A
Instrument
2.40 U
4.00
1.20
08/19/10
-------
SGS Ref.# 981268 Duplicate
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Tribal LanfillsAug20 1 0
Original 1104170001
Matrix Water (Surface, Eff, Ground)
QC results affect the following production samples:
1104166001
Original
Parameter Result
Waters Department
Alkalinity 92.0
Batch WTI3389
Method SM20 2320B
Instrument Titration
Printed Date/Time 08/23/2010 11:07
Prep Batch
Method
Date
QC RPD Analysis
Result Umts RP0 Limits Date
91.9 mg/L 0 (<25) 08/13/2010
-------
SGSRef.# 981354 Duplicate
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Tribal LanfillsAug20 1 0
Original 1104134001
Matrix Water (Surface, Eff, Ground)
Printed Date/Time 08/23/2010 11:07
Prep Batch
Method
Date
QC results affect the following production samples:
1104166001
Original
Parameter Result
QC RPD Analysis
Result Umts RP0 Limits Date
Waters Department
Total Dissolved Solids
Batch WAT8315
Method SM20 2540C
Instrument
461
464 mg/L
08/13/2010
-------
SGSRef.# 981355 Duplicate
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Tribal LanfillsAug20 1 0
Original 1104166001
Matrix Water (Surface, Eff, Ground)
Printed Date/Time 08/23/2010 11:07
Prep Batch
Method
Date
QC results affect the following production samples:
1104166001
Original
Parameter Result
QC RPD Analysis
Result Umts RP0 Limits Date
Waters Department
Total Dissolved Solids
Batch WAT8315
Method SM20 2540C
Instrument
24.0
23.0 mg/L
08/13/2010
-------
SGS Ref.# 981267 Lab Control Sample
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Tribal LanfillsAug2010
Matrix Water (Surface, Eff, Ground)
Printed Date/Time
Prep Batch
Method
Date
08/23/2010 11:07
QC results affect the following production samples:
1104166001
Parameter
QC
Results
Pet
Recov
LCS/LCSD
Limits
RPD
RPD
Limits
Spiked
Amount
Analysis
Date
Waters Department
Alkalinity
Batch WTI3389
Method SM20 2320B
Instrument fitration
LCS
263
105
(85-115)
250 mg/L 08/13/2010
-------
SGSRef.# 981353 Lab Control Sample
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Tribal LanfillsAug2010
Matrix Water (Surface, Eff, Ground)
Printed Date/Time
Prep Batch
Method
Date
08/23/2010 11:07
QC results affect the following production samples:
1104166001
Parameter
QC
Results
Pet
Recov
LCS/LCSD
Limits
RPD
RPD
Limits
Spiked
Amount
Analysis
Date
Waters Department
Total Dissolved Solids
Batch WAT8315
Method SM20 2540C
Instrument
LCS
316
96
(75-125)
330 mg/L 08/13/2010
-------
SGS Ref.#
Client Name
Project Name/#
Matrix
981621 Lab Control Sample
Shaw Env & Infrastructure Inc.
RARE-AK Tribal LanfillsAug2010
Water (Surface, Eff., Ground)
Printed Date/Time 08/23/2010
Prep Batch
Method
Date
11:07
QC results affect the following production samples:
1104166002
Parameter
QC Pet
Results Recov
LCS/LCSD RPD Spiked
Limits RPD Limits Amount
Analysis
Date
Waters Department
Total Organic Carbon
Batch WTC1999
Method SM5310B
Instrument TOC Analyzer
LCS
85.2
114
(80-120)
75 mg/L 08/16/2010
-------
SGS Ref.# 982799 Lab Control Sample
Client Name Shaw Env & Infrastructure Inc.
Project Name/# RARE-AK Tribal LanfillsAug20 1 0
Matrix Water (Surface, Eff, Ground)
Printed Date/Time
Prep Batch
Method
Date
08/23/2010
TPHX2016
EXTJ664TP
08/19/2010
11:07
QC results affect the following production samples:
1104166002
QC Pet LCS/LCSD
Parameter Results Recov Limits
RPD
RPD Limits
Spiked
Amount
Analysis
Date
Waters Department
TPH Silica Gel HEM
Batch TPH2199
Method EPA 1664A
Instrument
LCS
16.5
83
(64-132)
20 mg/L 08/19/2010
-------
SGSRef.# 981626 Matrix Spike
981627 Matrix Spike Duplicate
Original 1104166002
Matrix Water (Surface, Eff, Ground)
Printed Date/Time
Prep Batch
Method
Date
08/23/2010 11:07
QC results affect the following production samples:
1104166002
Original QC Pet MS/MSD
Parameter Qualifiers Result Result Recov Limits
Waters Department
Total Organic Carbon MS 23.3 34.1 107 (75-125)
MSB 32.8 94
RPD
RPD Limits
4 (<25)
Spiked Analysis
Amount Date
10.0 mg/L 08/16/2010
10.0 mg/L 08/16/2010
Batch WTC1999
Method SM5310B
Instrument TOC Analyzer
-------
SGS Ref.# 982801 Matrix Spike
Original 982795
Matrix Water (Surface, Eff., Ground)
Printed Date/Time 08/23/2010 11:07
Prep Batch TPHX2016
Method Extraction for EPA 1 664 TPH S
Date 08/19/2010
QC results affect the following production samples:
1104166002
Original QC
Parameter Qualifiers Result Result
Waters Department
TPH Silica Gel HEM MS (2.52) U 17.4
Batch TPH2199
Method EPA 1664A
Instrument
Pet MS/MSD RPD Spiked Analysis
Recov Limits RPD Limits Amount Date
84 ( 64-132 ) 20.7 mg/L 08/19/2010
-------
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SGSL
SAMPLE RECEIPT FORM
Review Criteria:
Were custody seals intact? Note # & location, if applicable.
COC accompanied samples?
Temperature blank compliant* (i.e., 0-6°C after correction factor)?
* Note: Exemption permitted for chilled samples collected less than 8 hours ago,
Cooler ID: ( @ Uk°l w/Therm.ID: Ql'ft
Cooler ID: @ w/ ThermJD:
Cooler ID: @, w/ Therm.ID:
Cooler ID: (% w/ Therm.ID:
Cooler ID: @ w/ Therm.ID:
Note: If non-compliant, use form FS-0029 to document affected samples/analyses.
If samples are received without a temperature blank, the "cooler
temperature" will be documented in lieu of the temperature blank &
"COOLER TEMP" will be noted to the right. In cases where neither a
temp blank nor cooler temp can be obtained, note "ambient" or "chilled."
If temperature(s) <0°C, were all sample containers ice free?
Delivery method (specify all that apply): ^fiepJ
USPS Alert Courier RoadRunner AKAir
Lynden Carlile ERA PenAir
FedEx UPS NAC Other:
^^Condition:
(£e£> No N/A
(TeF> No N/A
(?es) No N/A
Yes No ^/^
Note airbill/tracking #
See Attached
6®
I I Ut I For samples received with payment, note amount ($ ) and cash / check / CC (circle one). /^1£5>
-> For samples received in FBKS, ANCH staff will verify all criteria are reviewed. SRF Initiated by: Vi&!A~*
Do samples match COC* (i.e., sample IDs, dates/times collected)?
* Note: Exemption permitted if collection times differ by less than an hour;
in which case, the times on the COC will be used.
Are analyses requested unambiguous?
Were samples in good condition (no leaks/cracks/bfgakaje)?
Packing material used (specify all that apply): (gubWe^rap
Separate plastic bags Vermiculite Other:
Were all VOA vials free of headspace (i.e., bubbles <6 mm)?
Were all soil VOAs field extracted with MeOH+BFB?
Were the bottles provided by SGS? (Note apparent exceptions.)
Were proper containers (type/mass/volume/preservative*) used?
* Note: Exemption permitted for waters to be analyzed for metals.
Were Trip Blanks (i.e., VOAs, LL-Hg) in cooler with samples?
For preserved waters (other than VOA vials, LL-Mercury or
microbiological analyses), was pH verified and compliant?
If pH was adjusted, were bottles flagged (i.e., stickers)?
Refer to attached bottle sheet (form F066) for documentation.
For RUSH or SHORT HOLD TIME samples, were the COC &
this SRF flagged, bottles flagged (e.g., stickers) and lab notified?
For client requested, site-specific QC (e.g., MS/MSD/DUP), were
bottles flagged (e.g., stickers) and numbered accordingly?
J£QE£gecial handling (e.g., "MI" or foreign soils, lab filter, limited
No N/A
dSs* No N/A
(^P) No N/A
Yes No ^^\
Yes No oE?
Yes (^> N/A
Yes No $/>?)
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Yes No (^^>
Yes No (£$/£)
Yes No (M^J)
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(Yes) No N/A
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Additional notes (if applicable):
F004r25_SampleReceiptForm_revised_07302010
-------
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Container ID
Container ID
SAMPLE ID
1104166
1104166
1104166
1104166
001 001
001 001
002 002
002 002
A
B
A
B
A
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A
B
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(CHECKED)
TYPE CONTAINERS
1 Water
1 Water
1 Water
1 Water
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N/A
N/A
HCI (pH <2)
HCI (pH <2)
•
PRINT LABELS Notes:
Q ANOMALIES-
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ANALYSIS
W_Waters_Dept
W_Waters_Dept
W_TOC/DOC
W_Oil&Grease/TPH1 664
e.g., preservative added
or SPECIAL HANDLING -
e.g., Multi-Incremental (Ml),
Field Filter (FF), Lab Filter (LF),
use "same jar as" (SJA) forQC,
2xMeOH, bubbles, etc.
Type comments below:
.
extra volume
\ • «i\nit\\\\\\\\\\\\
Page: 1 ; Printed: 8/12/2010
F066_SRF-BottleTracking(electronic)_rev03-05212010
-------
APPENDIX D
CDC AND ASTDR CHEMICAL HEALTH EFFECTS INDEX
-------
ATSDR
AGENCY FOR TOXIC SUBSTANCES
AND DISEASE REGISTRY
ALUMINUM
CAS # 7429-90-5
Division of Toxicology and Environmental Medicine ToxFAQs1
September 2008
This fact sheet answers the most frequently asked health questions (FAQs) about aluminum. For more
information, call the ATSDR Information Center at 1-800-232-4636. This fact sheet is one in a series
of summaries about hazardous substances and their health effects. It is important you understand this
information because this substance may harm you. The effects of exposure to any hazardous substance
depend on the dose, the duration, how you are exposed, personal traits and habits, and whether other
chemicals are present.
HIGHLIGHTS: Everyone is exposed to low levels of aluminum from food, air,
water, and soil. Exposure to high levels of aluminum may result in respiratory and
neurological problems. Aluminum (in compounds combined with other elements)
has been found in at least 596 of the 1,699 National Priority List (NPL) sites identified
by the Environmental Protection Agency (EPA).
What is aluminum?
Aluminum is the most abundant metal in the earth's crust. It is
always found combined with other elements such as oxygen,
silicon, and fluorine. Aluminum as the metal is obtained from
aluminum-containing minerals. Small amounts of aluminum can
be found dissolved in water.
Aluminum metal is light in weight and silvery-white in appearance.
Aluminum is used for beverage cans, pots and pans, airplanes,
siding and roofing, and foil. Aluminum is often mixed with small
amounts of other metals to form aluminum alloys, which are
stronger and harder.
Aluminum compounds have many different uses, for example,
as alums in water-treatment and alumina in abrasives and furnace
linings. They are also found in consumer products such as
antacids, astringents, buffered aspirin, food additives, cosmetics,
and antiperspirants.
What happens to aluminum when it enters the
environment?
Q Aluminum cannot be destroyed in the environment, it can
only change its form.
Q In the air, aluminum binds to small particles, which can
stay suspended for many days.
Q Under most conditions, a small amount of aluminum will
dissolve in lakes, streams, and rivers.
Q It can be taken up by some plants from soil.
Q Aluminum is not accumulated to a significant extent in
most plants or animals.
How might I be exposed to aluminum?
Q Virtually all food, water, air, and soil contain some
aluminum.
Q The average adult in the U.S. eats about 7-9 mg
aluminum per day in their food.
Q Breathing higher levels of aluminum dust in workplace air.
Q Living in areas where the air is dusty, where aluminum is
mined or processed into aluminum metal, near certain
hazardous waste sites, or where aluminum is naturally high.
Q Eating substances containing high levels of aluminum
(such as antacids) especially when eating or drinking citrus
products at the same time.
Q Children and adults may be exposed to small amounts of
aluminum from vaccinations.
Q Very little enters your body from aluminum cooking
utensils.
How can aluminum affect my health?
Only very small amounts of aluminum that you may inhale, ingest,
or have skin contact with will enter the bloodstream.
Exposure to aluminum is usually not harmful, but exposure to
high levels can affect your health. Workers who breathe large
amounts of aluminum dusts can have lung problems, such as
coughing or abnormal chest X-rays. Some workers who breathe
aluminum dusts or aluminum fumes have decreased performance
in some tests that measure functions of the nervous system.
Some people with kidney disease store a lot of aluminum in their
bodies and sometimes develop bone or brain diseases which
U.S. DEPARTMENT OF HEALTH AND HUMAN SERVICES, Public Health Service
Agency for Toxic Substances and Disease Registry
-------
Page 2
ALUMINUM
CAS # 7429-90-5
ToxFAQs™ Internet address is http://www.atsdr.cdc.gov/toxfaq.html
may be caused by the excess aluminum. Some studies show that
people exposed to high levels of aluminum may develop
Alzheimer's disease, but other studies have not found this to be
true. We do not know for certain whether aluminum causes
Alzheimer's disease.
Studies in animals show that the nervous system is a sensitive
target of aluminum toxicity. Obvious signs of damage were not
seen in animals after high oral doses of aluminum. However, the
animals did not perform as well in tests that measured the strength
of their grip or how much they moved around.
We do not know if aluminum will affect reproduction in people.
Aluminum does not appear to affect fertility in animals.
How likely is aluminum to cause cancer?
The Department of Health and Human Services (DHHS) and the
EPA have not evaluated the carcinogenic potential of aluminum
in humans. Aluminum has not been shown to cause cancer in
animals.
How can aluminum affect children?
Children with kidney problems who were given aluminum in their
medical treatments developed bone diseases. It does not appear
that children are more sensitive to aluminum than adults.
We do not know if aluminum will cause birth defects in people.
Birth defects have not been seen in animals. Aluminum in large
amounts has been shown to be harmful to unborn and developing
animals because it can cause delays in skeletal and neurological
development.
Aluminum is found in breast milk, but only a small amount of this
aluminum will enter the infant's body through breastfeeding.
How can families reduce the risks of exposure to
aluminum?
Q Since aluminum is so common and widespread in the
environment, families cannot avoid exposure to aluminum.
Q Avoid taking large quantities of aluminum-containing
antacids and buffered aspirin and take these medications as
directed.
Q Make sure all medications have child-proof caps so
children will not accidentally eat them.
Is there a medical test to determine whether I have
been exposed to aluminum?
All people have small amounts of aluminum in their bodies.
Aluminum can be measured in blood, bones, feces, or urine.
Urine and blood aluminum measurements can tell you
whether you have been exposed to larger-than-normal
amounts of aluminum. Measuring bone aluminum can also
indicate exposure to high levels, but this requires a bone
biopsy.
Has the federal government made recommendations
to protect human health?
The EPA has recommended a Secondary Maximum
Contaminant Level (SMCL) of 0.05-0.2 milligrams per liter
(mg/L) for aluminum in drinking water. The SMCL is not
based on levels that will affect humans or animals. It is
based on taste, smell, or color.
The Occupational Health and Safety Administration (OSHA)
has limited workers' exposure to aluminum in dusts to
15 milligrams per cubic meter (mg/m3) (total dust) and
5 mg/m3 (respirable fraction) of air for an 8-hour workday,
40-hour workweek.
The Food and Drug Administration (FDA) has determined that
aluminum used as food additives and medicinals such as antacids
are generally safe.
References
Agency for Toxic Substances and Disease Registry
(ATSDR). 2008. Toxicological Profile for Aluminum. Atlanta,
GA: U.S. Department of Health and Human Services, Public
Health Service.
Where Can I get more information? For more information, contact the Agency for Toxic Substances and Disease
Registry, Division of Toxicology and Environmental Medicine, 1600 Clifton Road NE, Mailstop F-32, Atlanta, GA 30333. Phone:
1-800-232-4636, FAX: 770-488-4178. ToxFAQs Internet address via WWW is http://www.atsdr.cdc.gov/toxfaq.html. ATSDR
can tell you where to find occupational and environmental health clinics. Their specialists can recognize, evaluate, and treat
illnesses resulting from exposure to hazardous substances. You can also contact your community or state health or environmental
quality department if you have any more questions or concerns.
Federal Recycling Program
Printed on Recycled Paper
-------
CDC - Arsenic and Drinking Water from Private Wells - Wells - Private Water Systems -... Page 1 of 2
Centers for Disease Control and Prevention
CDC 2d/7: Saving Uves. Protecting People. Saving Money through Prevention.
Arsenic and Drinking Water from Private Wells
What is arsenic?
Arsenic is an element that occurs naturally in rocks and soil and is used for a variety of
purposes within industry and agriculture. It is also a byproduct of copper smelting, mining,
and coal burning. Arsenic can combine with other elements to make chemicals used to
preserve wood and to kill insects on cotton and other agricultural crops.
For more information about arsenic illnesses and treatment, please visit CDC-ATSDR's arsenic
(http://www.atsdr.cdc.gov/tfacts2.html) page.
(#) OTOP
Where and how does arsenic get into drinking water?
Arsenic can enter the water supply from natural deposits in the earth or from industrial and
agricultural pollution. It is widely believed that naturally occurring arsenic dissolves out of
certain rock formations when ground water levels drop significantly. Some industries in the
United States release thousands of pounds of arsenic into the environment every year. Once
released, arsenic remains in the environment for a long time. Arsenic is removed from the air
by rain, snow, and gradual settling. Once on the ground or in surface water, arsenic can slowly
enter ground water. High arsenic levels in private wells may come from certain arsenic
containing fertilizers used in the past or industrial waste. It may also indicate improper well
construction or overuse of chemical fertilizers or herbicides in the past.
£#} OTOP
How can I find out whether there is arsenic in my drinking water?
If you suspect a problem and your drinking water comes from a private well, you may contact
your state certification officer (http://www.epa.gov/ogwdw/labs/index.html) &
(http://www.cdc.gov/Other/disclaimer.html) for a list of laboratories in your area that will perform
tests on drinking water for a fee.
(#)
How do I remove arsenic from my drinking water?
Heating or boiling your water will not remove arsenic. Because some of the water evaporates
during the boiling process, the arsenic concentrations can actually increase slightly as the
water is boiled. Additionally, chlorine (bleach) disinfection will not remove arsenic.
http://www.cdc.gov/healthywater/drinking/private/wells/disease/arsemc.html 5/7/2012
-------
CDC - Arsenic and Drinking Water from Private Wells - Wells - Private Water Systems -... Page 2 of 2
You may wish to consider water treatment methods such as reverse osmosis, ultra-filtration,
distillation, or ion exchange. Typically these methods are used to treat water at only one faucet.
Contact your local health department for recommended procedures. If you want to know more
about these and other treatment options, please contact NSF International
(http://nsf.org/certified/consumer/listings advanced.asp?
companyname=&productname=&programcode=WATER FILTER&) &
(http://www.cdc.gov/Other/disclaimer.html). an organization that focuses on public health and
safety through standards development, product certification, education, and risk management.
Remember to have your well water tested regularly
(/healthywater/drinking/private/wells/testing.html). at least once a year, to make sure the problem
is controlled.
(#)
Page last reviewed: May 3, 2010
Page last updated: May 3, 2010
Content source: Centers for Disease Control and Prevention
Centers for Disease Control and Prevention 1600 Clifton Rd. Atlanta, GA 30333, USA
800-CDC-INFO (800-232-4636) TTY: (888) 232-6348, New Hours of Operation 8am-8pm ET/Monday-Friday
Closed Holidays - cdcinfo(5)cdc.gov
http://www.cdc.gov/healthywater/drinking/private/wells/disease/arsenic.html 5/7/2012
-------
ATSDR
AGENCY FOR TOXIC SUBSTANCES
AND DISEASE REGISTRY
ARSENIC
CAS # 7440-38-2
Division of Toxicology and Environmental Medicine ToxFAQs1
August 2007
This fact sheet answers the most frequently asked health questions (FAQs) about arsenic. For more
information, call the ATSDR Information Center at 1-800-232-4636. This fact sheet is one in a series
of summaries about hazardous substances and their health effects. It is important you understand this
information because this substance may harm you. The effects of exposure to any hazardous substance
depend on the dose, the duration, how you are exposed, personal traits and habits, and whether other
chemicals are present.
HIGHLIGHTS: Exposure to higher than average levels of arsenic occur mostly in
the workplace, near hazardous waste sites, or in areas with high natural levels. At
high levels, inorganic arsenic can cause death. Exposure to lower levels for a long
time can cause a discoloration of the skin and the appearance of small corns or
warts. Arsenic has been found in at least 1,149 of the 1,684 National Priority List
sites identified by the Environmental Protection Agency (EPA).
What is arsenic?
Arsenic is a naturally occurring element widely distributed in
the earth's crust. In the environment, arsenic is combined
with oxygen, chlorine, and sulfur to form inorganic arsenic
compounds. Arsenic in animals and plants combines with
carbon and hydrogen to form organic arsenic compounds.
Inorganic arsenic compounds are mainly used to preserve
wood. Copper chromated arsenate (CCA) is used to make
"pressure-treated" lumber. CCA is no longer used in the
U.S. for residential uses; it is still used in industrial
applications. Organic arsenic compounds are used as
pesticides, primarily on cotton fields and orchards.
What happens to arsenic when it enters the
environment?
Q Arsenic occurs naturally in soil and minerals and may
enter the air, water, and land from wind-blown dust and may
get into water from runoff and leaching.
Q Arsenic cannot be destroyed in the environment. It can
only change its form.
Q Rain and snow remove arsenic dust particles from the air.
Q Many common arsenic compounds can dissolve in water.
Most of the arsenic in water will ultimately end up in soil or
sediment.
Q Fish and shellfish can accumulate arsenic; most of this
arsenic is in an organic form called arsenobetaine that is
much less harmful.
How might I be exposed to arsenic?
Q Ingesting small amounts present in your food and water
or breathing air containing arsenic.
Q Breathing sawdust or burning smoke from wood treated
with arsenic.
Q Living in areas with unusually high natural levels of
arsenic in rock.
Q Working in a job that involves arsenic production or use,
such as copper or lead smelting, wood treating, or pesticide
application.
How can arsenic affect my health?
Breathing high levels of inorganic arsenic can give you a
sore throat or irritated lungs.
Ingesting very high levels of arsenic can result in death.
Exposure to lower levels can cause nausea and vomiting,
decreased production of red and white blood cells, abnormal
heart rhythm, damage to blood vessels, and a sensation of
"pins and needles" in hands and feet.
Ingesting or breathing low levels of inorganic arsenic for a
long time can cause a darkening of the skin and the
appearance of small "corns" or "warts" on the palms, soles,
and torso.
Skin contact with inorganic arsenic may cause redness and
swelling.
U.S. DEPARTMENT OF HEALTH AND HUMAN SERVICES, Public Health Service
Agency for Toxic Substances and Disease Registry
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ARSENIC
CAS # 7440-38-2
ToxFAQs™ Internet address is http://www.atsdr.cdc.gov/toxfaq.html
Almost nothing is known regarding health effects of organic
arsenic compounds in humans. Studies in animals show that
some simple organic arsenic compounds are less toxic than
inorganic forms. Ingestion of methyl and dimethyl
compounds can cause diarrhea and damage to the kidneys
How likely is arsenic to cause cancer?
Several studies have shown that ingestion of inorganic
arsenic can increase the risk of skin cancer and cancer in the
liver, bladder, and lungs. Inhalation of inorganic arsenic can
cause increased risk of lung cancer. The Department of
Health and Human Services (DHHS) and the EPA have
determined that inorganic arsenic is a known human
carcinogen. The International Agency for Research on
Cancer (IARC) has determined that inorganic arsenic is
carcinogenic to humans.
How can arsenic affect children?
There is some evidence that long-term exposure to arsenic in
children may result in lower IQ scores. There is also some
evidence that exposure to arsenic in the womb and early
childhood may increase mortality in young adults.
There is some evidence that inhaled or ingested arsenic can
injure pregnant women or their unborn babies, although the
studies are not definitive. Studies in animals show that large
doses of arsenic that cause illness in pregnant females, can
also cause low birth weight, fetal malformations, and even
fetal death. Arsenic can cross the placenta and has been
found in fetal tissues. Arsenic is found at low levels in
breast milk.
How can families reduce the risks of exposure to
arsenic?
Q If you use arsenic-treated wood in home projects, you
should wear dust masks, gloves, and protective clothing to
decrease exposure to sawdust.
Q If you live in an area with high levels of arsenic in water
or soil, you should use cleaner sources of water and limit
contact with soil.
Q If you work in a job that may expose you to arsenic, be aware
that you may carry arsenic home on your clothing, skin, hair, or
tools. Be sure to shower and change clothes before going home.
Is there a medical test to determine whether I've
been exposed to arsenic?
There are tests available to measure arsenic in your blood, urine,
hair, and fingernails. The urine test is the most reliable test for
arsenic exposure within the last few days. Tests on hair and
fingernails can measure exposure to high levels of arsenic over
the past 6-12 months. These tests can determine if you have
been exposed to above-average levels of arsenic. They cannot
predict whether the arsenic levels in your body will affect your
health.
Has the federal government made recommendations
to protect human health?
The EPA has set limits on the amount of arsenic that
industrial sources can release to the environment and has
restricted or cancelled many of the uses of arsenic in
pesticides. EPA has set a limit of 0.01 parts per million (ppm)
for arsenic in drinking water.
The Occupational Safety and Health Administration (OSHA)
has set a permissible exposure limit (PEL) of 10 micrograms
of arsenic per cubic meter of workplace air (10 ug/m3) for 8
hour shifts and 40 hour work weeks.
References
Agency for Toxic Substances and Disease Registry (ATSDR).
2007. Toxicological Profile for Arsenic (Update). Atlanta, GA:
U.S. Department of Public Health and Human Services, Public
Health Service.
Where Can I get more information? For more information, contact the Agency for Toxic Substances and Disease
Registry, Division of Toxicology and Environmental Medicine, 1600 Clifton Road NE, Mailstop F-32, Atlanta, GA 30333. Phone:
1-800-232-4636, FAX: 770-488-4178. ToxFAQs Internet address via WWW is http://www.atsdr.cdc.gov/toxfaq.html. ATSDR
can tell you where to find occupational and environmental health clinics. Their specialists can recognize, evaluate, and treat
illnesses resulting from exposure to hazardous substances. You can also contact your community or state health or environmental
quality department if you have any more questions or concerns.
Federal Recycling Program
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ATSDR
AGENCY FOR TOXIC SUBSTANCES
AND DISEASE REGISTRY
BERYLLIUM
CAS #7440-41-7
Division of Toxicology ToxFAQs1
September 2002
This fact sheet answers the most frequently asked health questions (FAQs) about beryllium. For more
information, call the ATSDR Information Center at 1-888-422-8737. This fact sheet is one in a series
of summaries about hazardous substances and their health effects. It is important you understand this
information because this substance may harm you. The effects of exposure to any hazardous substance
depend on the dose, the duration, how you are exposed, personal traits and habits, and whether other
chemicals are present.
HIGHLIGHTS: People working or living near beryllium industries have the
greatest potential for exposure to beryllium. Lung damage has been observed
in people exposed to high levels of beryllium in the air. About 1-15% of all
people occupationally-exposed to beryllium in air become sensitive to beryllium
and may develop chronic beryllium disease (CBD), an irreversible and
sometimes fatal scarring of the lungs. CBD may be completely asymptomatic or
begin with coughing, chest pain, shortness of breath, weakness, and/or fatigue.
Beryllium has been found in at least 535 of the 1,613 National Priorities List
sites identified by the Environmental Protection Agency (EPA).
What is beryllium?
Beryllium is a hard, grayish metal naturally found in mineral
rocks, coal, soil, and volcanic dust. Beryllium ore is mined,
and the beryllium is purified for use in nuclear weapons and
reactors, aircraft and space vehicle structures, instruments, x-
ray machines, and mirrors. Beryllium oxide is used to make
speciality ceramics for electrical and high-technology
applications. Beryllium alloys are used in automobiles,
computers, sports equipment (golf clubs), and dental
bridges.
What happens to beryllium when it enters the
environment?
Q Beryllium dust enters the air from burning coal and oil.
This beryllium dust will eventually settle over the land and
water.
Q It enters water from erosion of rocks and soil, and from
industrial waste. Some beryllium compounds will dissolve in
water, but most stick to particles and settle to the bottom.
Q Most beryllium in soil does not dissolve in water and
remains bound to soil.
Q Beryllium does not accumulate in the food chain.
How might I be exposed to beryllium?
Q The general population is normally exposed to low levels
of beryllium in air, food, and water.
Q People working in industries where beryllium is mined,
processed, machined, or converted into metal, alloys, and
other chemicals may be exposed to high levels of beryllium.
People living near these industries may also be exposed to
higher than normal levels of beryllium in air.
Q People living near uncontrolled hazardous waste sites may
be exposed to higher than normal levels of beryllium.
How can beryllium affect my health?
Beryllium can be harmful if you breathe it. The effects
depend on how much you are exposed to, for how long, and
individual susceptibility. If beryllium air levels are high
enough (greater than 1000 ug/m3), an acute condition can
result. This condition resembles pneumonia and is called
acute beryllium disease Occupational and community air
standards are effective in preventing acute lung damage.
Some exposed workers (1-15%) become sensitive to
beryllium. These individuals may develop an inflammatory
reaction in the respiratory system. This condition is called
chronic beryllium disease (CBD), and can occur years after
exposure to higher than normal levels of beryllium (greater
than 0.2 ug/m3). This disease can make you feel weak and
tired, and can cause difficulty in breathing. It can also result
in anorexia, weight loss, and may also lead to right side heart
U.S. DEPARTMENT OF HEALTH AND HUMAN SERVICES, Public Health Service
Agency for Toxic Substances and Disease Registry
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BERYLLIUM
CAS #7440-41-7
ToxFAQs™ Internet address is http://www.atsdr.cdc.gov/toxfaq.html
enlargement and heart disease in advanced cases. Some
people who are sensitized to beryllium may not have any
symptoms. The general population is unlikely to develop
chronic beryllium disease because ambient air levels of
beryllium are normally very low (0.00003-0.0002 ug/m3).
Swallowing beryllium has not been reported to cause effects
in humans because very little beryllium is absorbed from the
stomach and intestines. Ulcers have been seen in dogs
ingesting beryllium in the diet. Beryllium contact with skin
that has been scraped or cut may cause rashes or ulcers.
How likely is beryllium to cause cancer?
Long term exposure to beryllium can increase the risk of
developing lung cancer in people.
The Department of Health and Human Services (DHHS) and
the International Agency for Research on Cancer (IARC)
have determined that beryllium is a human carcinogen. The
EPA has determined that beryllium is a probable human
carcinogen. EPA has estimated that lifetime exposure to
0.04 ug/m3 beryllium can result in a one in a thousand chance
of developing cancer.
How can beryllium affect children?
It is likely that the health effects seen in children exposed to
beryllium will be similar to the effects seen in adults. We do
not know whether children differ from adults in their
susceptibility to beryllium.
We do not know if exposure to beryllium will result in birth
defects or other developmental effects in people. The
studies on developmental effects in animals are not
conclusive.
How can families reduce the risk of exposure to
beryllium?
Q Individuals working at facilities that use beryllium should
make sure that contaminated clothing and objects are not
brought home.
Q Children should avoid playing in soils near uncontrolled
hazardous waste sites where beryllium may have been
discarded.
Is there a medical test to show whether I've been
exposed to beryllium?
Beryllium can be measured in samples from your blood,
urine, skin, or lungs. These tests are rarely done because
they are not reliable measures of your exposure over time.
Also, these tests do not show if you have become sensitized
to beryllium.
Another test, the beryllium lymphocyte proliferation test
(BeLPT), can help your doctor decide if you are sensitized to
beryllium. This test is only done in a few specialized
laboratories, but doctors familiar with the test can collect
blood samples and send them for testing by overnight
carrier. The BeLPT is most often done for people who work
with beryllium. It is also useful for separating chronic
beryllium disease from diagnoses that resemble it (for
example, sarcoidosis). Depending on your exposure history,
clinical findings, and test results, your doctor may also
recommend additional specialized testing.
Has the federal government made
recommendations to protect human health?
The EPA restricts the amount of beryllium that industries
may release into the air to 0.01 ug/m3, averaged over a 30-
day period.
The Occupational Safety and Health Administration (OSHA)
sets a limit of 2 ug/m3 for an 8-hour work shift measured as a
personal sample.
References
Agency for Toxic Substances and Disease Registry
(ATSDR). 2002. Toxicological Profile for Beryllium Atlanta,
GA: U.S. Department of Health and Human Services, Public
Health Service.
Where can I get more information? For more information, contact the Agency for Toxic Substances and
Disease Registry, Division of Toxicology, 1600 Clifton Road NE, MailstopF-32, Atlanta, GA30333. Phone: 1-888-422-
8737, FAX: 770-488-4178. ToxFAQs Internet address via WWW is http://www.atsdr.cdc.gov/toxfaq.html. ATSDR can
tell you where to find occupational and environmental health clinics. Their specialists can recognize, evaluate, and
treat illnesses resulting from exposure to hazardous substances. You can also contact your community or state health
or environmental quality department if you have any more questions or concerns.
Federal Recycling Program
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ATSDR
AGENCY FOR TOXIC SUBSTANCES
AND DISEASE REGISTRY
CADMIUM
CAS # 7440-43-9
Division of Toxicology and Environmental Medicine ToxFAQs1
September 2008
This fact sheet answers the most frequently asked health questions (FAQs) about cadmium. For more
information, call the ATSDR Information Center at 1-800-232-4636. This fact sheet is one in a series
of summaries about hazardous substances and their health effects. It is important you understand this
information because this substance may harm you. The effects of exposure to any hazardous substance
depend on the dose, the duration, how you are exposed, personal traits and habits, and whether other
chemicals are present.
HIGHLIGHTS: Exposure to cadmium happens mostly in the workplace where
cadmium products are made. The general population is exposed from breathing
cigarette smoke or eating cadmium contaminated foods. Cadmium damages the
kidneys, lungs, and bones. Cadmium has been found in at least 1,014 of the 1,669
National Priorities List sites identified by the Environmental Protection Agency
(EPA).
What is cadmium?
Cadmium is a natural element in the earth's crust. It is usually
found as a mineral combined with other elements such as
oxygen (cadmium oxide), chlorine (cadmium chloride), or
sulfur (cadmium sulfate, cadmium sulfide).
All soils and rocks, including coal and mineral fertilizers,
contain some cadmium. Most cadmium used in the United
States is extracted during the production of other metals like
zinc, lead, and copper. Cadmium does not corrode easily
and has many uses, including batteries, pigments, metal
coatings, and plastics.
What happens to cadmium when it enters the
environment?
Q Cadmium enters soil, water, and air from mining, industry,
and burning coal and household wastes.
Q Cadmium does not break down in the environment, but
can change forms.
Q Cadmium particles in air can travel long distances before
falling to the ground or water.
Q Some forms of cadmium dissolve in water.
Q Cadmium binds strongly to soil particles.
Q Fish, plants, and animals take up cadmium from the
environment.
How might I be exposed to cadmium?
Q Eating foods containing cadmium; low levels are found
in all foods (highest levels are found in shellfish, liver, and
kidney meats).
Q Smoking cigarettes or breathing cigarette smoke.
Q Breathing contaminated workplace air.
Q Drinking contaminated water.
Q Living near industrial facilities which release cadmium
into the air.
How can cadmium affect my health?
Breathing high levels of cadmium can severely damage
the lungs. Eating food or drinking water with very high
levels severely irritates the stomach, leading to vomiting
and diarrhea.
Long-term exposure to lower levels of cadmium in air, food,
or water leads to a buildup of cadmium in the kidneys and
possible kidney disease. Other long-term effects are lung
damage and fragile bones.
How likely is cadmium to cause cancer?
The Department of Health and Human Services (DHHS)
has determined that cadmium and cadmium compounds
are known human carcinogens.
U.S. DEPARTMENT OF HEALTH AND HUMAN SERVICES, Public Health Service
Agency for Toxic Substances and Disease Registry
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CADMIUM
CAS # 7440-43-9
ToxFAQs™ Internet address is http://www.atsdr.cdc.gov/toxfaq.html
How can cadmium affect children?
The health effects in children are expected to be similar
to the effects seen in adults (kidney, lung, and bone
damage depending on the route of exposure).
A few studies in animals indicate that younger animals
absorb more cadmium than adults. Animal studies also
indicate that the young are more susceptible than adults
to a loss of bone and decreased bone strength from
exposure to cadmium.
We don't know if cadmium causes birth defects in people.
The babies of animals exposed to high levels of cadmium
during pregnancy had changes in behavior and learning ability.
There is also some information from animal studies that high
enough exposures to cadmium before birth can reduce body
weights and affect the skeleton in the developing young.
How can families reduce the risks of exposure to
cadmium?
Q In the home, store substances that contain cadmium safely,
and keep nickel-cadmium batteries out of reach of young
children.
Q Cadmium is a component of tobacco smoke. Avoid
smoking in enclosed spaces like inside the home or car in
order to limit exposure to children and other family members.
Q If you work with cadmium, use all safety precautions to
avoid carrying cadmium-containing dust home from work
on your clothing, skin, hair, or tools.
Q A balanced diet can reduce the amount of cadmium
taken into the body from food and drink.
Is there a medical test to determine whether I've
been exposed to cadmium?
Cadmium can be measured in blood, urine, hair, or nails.
Urinary cadmium has been shown to accurately reflect
the amount of cadmium in the body.
The amount of cadmium in your blood shows your recent
exposure to cadmium. The amount of cadmium in your
urine shows both your recent and your past exposure.
Has the federal government made recommendations
to protect human health?
The EPA has determined that exposure to cadmium in
drinking water at concentrations of 0.04 ppm for up to
10 days is not expected to cause any adverse effects in a
child.
The EPA has determined that lifetime exposure to
0.005 ppm cadmium is not expected to cause any
adverse effects.
The FDA has determined that the cadmium concentration
in bottled drinking water should not exceed 0.005 ppm.
The Occupational Health and Safety Administration
(OSHA) has limited workers' exposure to an average of
5 |J,g/m3 for an 8-hour workday, 40-hour workweek.
References
Agency for Toxic Substances and Disease Registry (ATSDR).
2008. Toxicological Profile for Cadmium (Draft for Public
Comment). Atlanta, GA: U.S. Department of Public Health
and Human Services, Public Health Service.
Where Can I get more information? For more information, contact the Agency for Toxic Substances and Disease
Registry, Division of Toxicology and Environmental Medicine, 1600 Clifton Road NE, Mailstop F-32, Atlanta, GA 30333. Phone:
1-800-232-4636, FAX: 770-488-4178. ToxFAQs Internet address via WWW is http://www.atsdr.cdc.gov/toxfaq.html. ATSDR
can tell you where to find occupational and environmental health clinics. Their specialists can recognize, evaluate, and treat
illnesses resulting from exposure to hazardous substances. You can also contact your community or state health or environmental
quality department if you have any more questions or concerns.
Federal Recycling Program
Printed on Recycled Paper
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ATSDR
AGENCY FOR TOXIC SUBSTANCES
AND DISEASE REGISTRY
CHROMIUM
CAS # 7440-47-3
Division of Toxicology and Environmental Medicine ToxFAQs1
September 2008
This fact sheet answers the most frequently asked health questions (FAQs) about chromium. For more
information, call the ATSDR Information Center at 1-800-232-4636. This fact sheet is one in a series
of summaries about hazardous substances and their health effects. It is important you understand this
information because this substance may harm you. The effects of exposure to any hazardous substance
depend on the dose, the duration, how you are exposed, personal traits and habits, and whether other
chemicals are present.
HIGHLIGHTS: Exposure to chromium occurs from ingesting contaminated food
or drinking water or breathing contaminated workplace air. Chromium(VI) at high
levels can damage the nose and cause cancer. Ingesting high levels of chromium(VI)
may result in anemia or damage to the stomach or intestines. Chromium(III) is an
essential nutrient. Chromium has been found in at least 1,127 of the 1,669 National
Priorities List sites identified by the Environmental Protection Agency (EPA).
What is chromium?
Chromium is a naturally occurring element found in rocks,
animals, plants, and soil. It can exist in several different
forms. Depending on the form it takes, it can be a liquid,
solid, or gas. The most common forms are chromium(O),
chromium(III), and chromium(VI). No taste or odor is
associated with chromium compounds.
The metal chromium, which is the chromium(O) form, is
used for making steel. Chromium(VI) and chromium(III)
are used for chrome plating, dyes and pigments, leather
tanning, and wood preserving.
What happens to chromium when it enters the
environment?
Q Chromium can be found in air soil, and water after release
from the manufacture, use, and disposal of chromium-based
products, and during the manufacturing process.
Q Chromium does not usually remain in the atmosphere,
but is deposited into the soil and water .
Q Chromium can easily change from one form to another
in water and soil, depending on the conditions present.
Q Fish do not accumulate much chromium in their bodies
from water.
How might I be exposed to chromium?
Q Eating food containing chromium(III).
Q Breathing contaminated workplace air or skin contact
during use in the workplace.
Q Drinking contaminated well water.
Q Living near uncontrolled hazardous waste sites containing
chromium or industries that use chromium.
How can chromium affect my health?
Chromium(III) is an essential nutrient that helps the body
use sugar, protein, and fat.
Breathing high levels of chromium(VI) can cause
irritation to the lining of the nose, nose ulcers, runny
nose, and breathing problems, such as asthma, cough,
shortness of breath, or wheezing. The concentrations of
chromium in air that can cause these effects may be
different for different types of chromium compounds,
with effects occurring at much lower concentrations for
chromium(VI) compared to chromium(III).
The main health problems seen in animals following
ingestion of chromium(VI) compounds are irritation and
ulcers in the stomach and small intestine and anemia.
Chromium (III) compounds are much less toxic and do
not appear to cause these problems.
Sperm damage and damage to the male reproductive
system have also been seen in laboratory animals exposed
to chromium (VI).
U.S. DEPARTMENT OF HEALTH AND HUMAN SERVICES, Public Health Service
Agency for Toxic Substances and Disease Registry
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CHROMIUM
CAS # 7440-47-3
ToxFAQs™ Internet address is http://www.atsdr.cdc.gov/toxfaq.html
Skin contact with certain chromium(VI) compounds can
cause skin ulcers. Some people are extremely sensitive
to chromium(VI) or chromium(III). Allergic reactions
consisting of severe redness and swelling of the skin
have been noted.
How likely is chromium to cause cancer?
The Department of Health and Human Services (DHHS),
the International Agency for Reseach on Cancer (IARC),
and the EPA have determined that chromium(VI)
compounds are known human carcinogens. In workers,
inhalation of chromium (VI) has been shown to cause
lung cancer. Chromium(VI) also causes lung cancer in
animals. An increase in stomach tumors was observed in
humans and animals exposed to chromium(VI) in drinking
water.
How can chromium affect children?
It is likely that health effects seen in children exposed to
high amounts of chromium will be similar to the effects
seen in adults.
We do not know if exposure to chromium will result in
birth defects or other developmental effects in people.
Some developmental effects have been observed in
animals exposed to chromium(VI).
How can families reduce the risks of exposure to
chromium?
Q Children should avoid playing in soils near uncontrolled
hazardous waste sites where chromium may have been
discarded.
Q Chromium is a component of tobacco smoke. Avoid
smoking in enclosed spaces like inside the home or car in
order to limit exposure to children and other family members.
Q Although chromium(III) is an essential nutrient, you should
avoid excessive use of dietary supplements containing
chromium.
Is there a medical test to determine whether I've
been exposed to chromium?
Since chromium (III) is an essential element and naturally
occurs in food, there will always be some level of
chromium in your body. Chromium can be measured in
hair, urine, and blood.
Higher than normal levels of chromium in blood or urine
may indicate that a person has been exposed to
chromium. However, increases in blood and urine
chromium levels cannot be used to predict the kind of
health effects that might develop from that exposure.
Has the federal government made recommendations
to protect human health?
The EPA has determined that exposure to chromium in
drinking water at concentrations of 1 mg/L for up to
10 days is not expected to cause any adverse effects in a
child.
The FDA has determined that the chromium
concentration in bottled drinking water should not exceed
Img/L.
The Occupational Health and Safety Administration
(OSHA) has limited workers' exposure to an average of
0.005 mg/m3 chromium(VI), 0.5 mg/m 3 chromium(III),
and 1.0 mg/m 3 chromium(O) for an 8-hour workday,
40-hour workweek.
References
Agency for Toxic Substances and Disease Registry (/TSDR).
2008. Toxicological Profile for Chromium (Draft for Public
Comment). Atlanta, GA: U.S. Department of Public Health
and Human Services, Public Health Service.
Where Can I get more information? For more information, contact the Agency for Toxic Substances and Disease
Registry, Division of Toxicology and Environmental Medicine, 1600 Clifton Road NE, Mailstop F-32, Atlanta, GA 30333. Phone:
1-800-232-4636, FAX: 770-488-4178. ToxFAQs Internet address via WWW is http://www.atsdr.cdc.gov/toxfaq.html. ATSDR
can tell you where to find occupational and environmental health clinics. Their specialists can recognize, evaluate, and treat
illnesses resulting from exposure to hazardous substances. You can also contact your community or state health or environmenta 1
quality department if you have any more questions or concerns.
Federal Recycling Program
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Private Well Water and Fluoride - Engineering Fact Sheet- Community Water Fluoridatio... Page 1 of 3
Private Well Water and Fluoride
This fact sheet addresses questions that consumers may have on fluoride levels in groundwater from
private wells.
How do I know if my water is from a public water system or a private well?
The U.S. Environmental Protection Agency defines a Public Water System as a system that serves 25
or more people per day. If you have water service from a well that has a limited delivery, such as to
your house but not to your neighbor's house, then you likely have a private well.
What are the governmental regulations for private wells?
Although most U.S. households are connected to a public water system, the U.S. Geological Survey
report "Estimated Use of Water in the United States in 2005" estimates that 14% of United States
residents rely on private wells that are not regulated by the EPA Safe Drinking Water Act. In most
states, private wells are not regulated by governmental regulatory entities. Therefore, it is the
responsibility of the homeowner to know and understand the quality of the water from their well. The
U.S. Environmental Protection Agency suggests that all wells be tested for quality once every three
years since influences to well water quality can change over time. Contact your public health office
for their advice on testing of private wells in your state or area. Additional information on testing
well water quality in private wells serving homes can be found on the U.S. Environmental
Protection Agency Web site.
My home gets its water from a private well. What do I need to know about fluoride and
groundwater from a well?
Fluoride is present in virtually all waters at some level, and it is important to know the fluoride
content of your water, particularly if you have children. A 2008 U.S. Geological Survey study found
that 4% of sampled wells had natural fluoride levels above the EPA Secondary Maximum
Contaminant Level (SMCL) of 2 mg/L. A smaller set of 1.2% of all wells exceeded the Maximum
Contaminant Level (MCL) of 4 mg/L. If you have a home well, the EPA recommends having a
sample of your water analyzed by a laboratory at least once every three years. Check with your
dentist, physician, or public health department to learn how to have your home well water tested.
What should I do if the water from my well has less fluoride than the recommended level of 0.7
mg/L? Can I add fluoride?
The recommended fluoride level in drinking water for good oral health is 0.7 mg/L (milligrams per
liter). If fluoride levels in your drinking water are lower than 0.7 mg/L, your child's dentist or
pediatrician should evaluate whether your child could benefit from daily fluoride supplements. (The
prescription dosage of fluoride supplements should be consistent with the schedule* 18 (PDF-43 IK)
established by the American Dental Association (ADA) Council on Scientific Affairs.) Their
recommendation will depend on your child's risk of developing tooth decay, as well as exposure to
other sources of fluoride, such as drinking water at school or day care, and fluoride toothpaste. It is
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not feasible to add fluoride to an individual residence's well.
What should I do if the water from my well has fluoride levels that are higher than the
recommended level of 0.7 mg/L?
In some regions in the United States, community drinking water and private wells can contain levels
of naturally occurring fluoride that are greater than the level recommended by the CDC for
preventing tooth decay. Consuming water with fluoride between 0.6 and 2.0 mg/L results in reduced
tooth decay, but consumption of water with fluoride exceeding 2.0 mg/L may increase the potential
for dental fluorosis.
The U.S. Environmental Protection Agency (EPA) currently has a non-enforceable recommended
guideline for fluoride of 2.0 mg/L to protect against dental fluorosis. If your home is served by a
private well that has fluoride levels exceeding this recommended guideline, but lower than 4.0 mg/L,
then it is best to provide children under 8 years of age with an alternative water source, such as
bottled water with a low fluoride content.
Continue to test your well water's quality every three years as recommended by EPA.
What should I do if my well water was measured as having too much fluoride (level greater
than 4 mg/L)?
It is unusual to have the fluoride content of water exceed 4 mg/L. If a laboratory report indicates that
you have such excessive fluoride content, it is recommended that the water be retested. At least four
samples should be collected, a minimum of one week apart, and the results compared. If one sample
is above 4 mg/L and the other samples are less than 4 mg/L, then the high value may have been an
erroneous measurement. If all samples register excessive levels greater than 4 mg/L, then you may
want to consider investigating alternate sources of water for drinking and cooking, or installing a
device to remove the fluoride from your home water source. Physical contact with high fluoride
content water, such as bathing or dishwashing, is safe since fluoride does not pass through the skin.
Back to Top
What are the health risks of consuming water with fluoride levels greater than 4 mg/L?
Children aged 8 years and younger have an increased chance of developing severe tooth dental
fluorosis. Consumption over a lifetime may increase the likelihood of bone fractures, and may result
in skeletal fluorosis, a painful or even crippling disease. The U.S. Environmental Protection Agency
has determined that safe exposure of fluoride is below 4 mg/L in drinking water to avoid those
effects.
Will using a home water filtration system take the fluoride out of my home's water?
Removal of fluoride from water is difficult. Most home point-of-use treatment systems that are
installed at single faucets use activated carbon filtration, which does not remove the fluoride. Reverse
osmosis point-of-use devices can effectively remove fluoride, although the amount may vary given
individual circumstances. For a home point-of-use device to claim a reduction in fluoride, it must
meet National Sanitation Foundation (NSF) Standard 58 criteria for fluoride removal. Standard 58
requires that a device must achieve a 1.5 milligrams per liter (mg/L) concentration in the product
water if the original concentration was 8.0 mg/L, or approximately 80 percent removal. This
percentage removal may not be consistent at lower concentrations of fluoride. Check with the
manufacturer of the individual product for specific product information.
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Fluoride is not released from water when it is boiled or frozen. One exception would be a water
distillation system. These systems heat water to the boiling point and then collect water vapor as it
evaporates. Water distillation systems are typically used in laboratories. For home use, these systems
can be expensive and may present safety and maintenance concerns.
Can I use water with fluoride for preparing infant formula?
Yes, you can use well water for preparing infant formula. It is important, however, to ensure that the
well water has been recently tested to verify safety. EPA suggests that well water should be tested a
minimum of once every three years for micro-organisms and other substances. In addition, parents of
young children should also have their well water tested for fluoride content.
For more information on private well testing, contact your local health department or visit the EPA
Web site. Parents and caregivers should speak with their pediatrician to review the results of the
private well testing and to determine if the well water should be boiled prior to mixing the formula. If
you are advised to boil the water, be sure to boil the water only one time so that you don't
concentrate substances by the boiling process itself.
If your child is exclusively consuming infant formula reconstituted with well water, and if that water
contains fluoride, there is an increased chance for dental fluorosis. To lessen this chance, parents can
use low-fluoride bottled water some of the time to mix infant formula; these bottled water are labeled
as de-ionized, purified, demineralized, or distilled. For more information, see Overview: Infant
Formula and Fluorosis.
Back to Top
IB One or more documents on this Web page is available in Portable Document Format (PDF). You
will need Acrobat Reader to view and print these documents.
Page last reviewed: February 1, 2012
Page last modified: February 1, 2012
Content source: Division of Oral Health, National Center for Chronic Disease Prevention and
Health Promotion.
Page Located on the Web at http://www.cdc.gov/fluoridation/fact_sheets/wellwater.htm
DEPARTMENT OF HEALTH AND HUMAN SERVICES
CENTERS FOR DISEASE CONTROL AND PREVENTION
SAFER-HEALTHIER. PEOPLE'"
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ATSDR
AGENCY FOR TOXIC SUBSTANCES
AND DISEASE REGISTRY
FLUORIDES, HYDROGEN FLUORIDE, AND FLUORINE
CAS # 7681-49-4, 7664-39-3, 7782-41-4
Division of Toxicology ToxFAQs1
September 2003
This fact sheet answers the most frequently asked health questions (FAQs) about fluorides, hydrogen
fluoride, and fluorine. For more information, call the ATSDR Information Center at 1-888-422-8737.
This fact sheet is one in a series of summaries about hazardous substances and their health effects. It
is important you understand this information because these substances may harm you. The effects of
exposure to any hazardous substance depend on the dose, the duration, how you are exposed, personal
traits and habits, and whether other chemicals are present.
HIGHLIGHTS: Fluorides are naturally occurring compounds. Low levels of
fluorides can help prevent dental cavities. At high levels, fluorides can result in
tooth and bone damage. Hydrogen fluoride and fluorine are naturally-occurring
gases that are very irritating to the skin, eyes, and respiratory tract. These
substances have been found in at least 188 of the 1,636 National Priorities List sites
identified by the Environmental Protection Agency (EPA).
What are fluorides, hydrogen fluoride, and
fluorine?
Fluorides, hydrogen fluoride, and fluorine are chemically
related. Fluorine is a naturally-occurring, pale yellow-green
gas with a sharp odor. It combines with metals to make
fluorides such as sodium fluoride and calcium fluoride, both
white solids. Sodium fluoride dissolves easily in water, but
calcium fluoride does not. Fluorine also combines with
hydrogen to make hydrogen fluoride, a colorless gas.
Hydrogen fluoride dissolves in water to form hydrofluoric
acid.
Fluorine and hydrogen fluoride are used to make certain
chemical compounds. Hydrofluoric acid is used for etching
glass. Other fluoride compounds are used in making steel,
chemicals, ceramics, lubricants, dyes, plastics, and pesticides.
Fluorides are often added to drinking water supplies and to
a variety of dental products, including toothpaste and mouth
rinses, to prevent dental cavities.
What happens to fluorides, hydrogen fluoride, and
fluorine when they enter the environment?
QFluorine cannot be destroyed in the environment; it can
only change its form. Fluorine forms salts with minerals in
soil.
QHydrogen fluoride gas will be absorbed by rain and into
clouds and fog to form hydrofluoric acid, which will fall to
the ground.
QFluorides released to the air from volcanoes and industry
are carried by wind and rain to nearby water, soil, and food
sources.
QFluorides in water and soil will form strong associations
with sediment or soil particles.
QFluorides will accumulate in plants and animals. In
animals, the fluoride accumulates primarily in the bones or
shell rather than in soft tissues.
How might I be exposed to fluorides, hydrogen
fluoride, and fluorine?
QThe general population can be exposed to fluorides in
contaminated air, food, drinking water and soil.
QPeople living in communities with fluoridated water or high
levels of naturally-occurring fluoride may be exposed to
higher levels.
QPeople who work or live near industries where fluoride-
containing substances are used may be exposed to higher
levels.
How can fluorides, hydrogen fluoride, and fluorine
affect my health?
Small amounts of fluoride help prevent tooth cavities, but
high levels can harm your health. In adults, exposure to
high levels of fluoride can result in denser bones. However,
if exposure is high enough, these bones may be more fragile
and brittle and there may be a greater risk of breaking the
bone. In animals, exposure to extremely high doses of
fluoride can result in decreased fertility and sperm and testes
damage.
U.S. DEPARTMENT OF HEALTH AND HUMAN SERVICES, Public Health Service
Agency for Toxic Substances and Disease Registry
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Page 2
FLUORIDES, HYDROGEN FLUORIDE, AND FLUORINE
CAS # 7681-49-4, 7664-39-3, 7782-41-4
ToxFAQs™ Internet address is http://www.atsdr.cdc.gov/toxfaq.html
Fluorine and hydrogen fluoride are very irritating to the skin,
eyes, and respiratory tract. At high levels, such as may
occur through exposure from an industrial accident,
hydrogen fluoride may also damage the heart.
How likely are fluorides, hydrogen fluoride, and
fluorine to cause cancer?
Most of the studies of people living in areas with fluoridated
water or naturally high levels of fluoride in drinking water did
not find an association between fluoride and cancer risk.
Two animal cancer studies were inconclusive. The
international Agency for Research on Cancer (IARC) has
determined that the carcinogenicity of fluoride to humans is
not classifiable.
How can fluorides, hydrogen fluoride, and fluorine
affect children?
When used appropriately, fluoride is both safe and effective
in preventing and controlling cavities. Drinking or eating
excessive fluoride during the time teeth are being formed
(before 8 years of age) can cause visible changes in teeth.
This condition is called dental fluorosis. At very high
concentrations of fluoride, the teeth can become more fragile
and sometimes can break.
No studies have addressed whether low levels of fluoride will
cause birth defects in humans. Birth defects have not been
found in most studies of animals.
How can families reduce the risk of exposure to
fluorides, hydrogen fluoride, and fluorine?
In the home, children may be exposed to high levels of
fluorides if they swallow dental products containing
fluoridated toothpaste, gels, or rinses. Parents should
supervise brushing and place at most, a small pea size dab of
toothpaste on the brush and teach children not to swallow
dental products. People who live in areas with high levels of
naturally-occurring fluoride in the water should use
alternative sources of dinking water, such as bottled water.
Is there a medical test to show whether I've been
exposed to fluoride, hydrogen fluoride, and
fluorine?
Tests are available to measure fluoride levels in urine; these
tests can determine if you have been exposed to higher-than-
normal levels of fluorides. The urine test must be performed
soon after exposure because fluoride that is not stored in
bones leaves the body within a few days. The test cannot
be performed in the doctor's office, but can be done at most
laboratories that test for chemical exposure. The urine
fluoride test cannot be used to predict the nature or severity
of toxic effects. Bone sampling can be done in special cases
to measure long-term exposure to fluorides.
Has the federal government made
recommendations to protect human health?
The EPA has set a maximum amount of fluoride allowable in
drinking water of 4.0 milligrams per liter of water (4.0 mg/L).
For the prevention of dental decay, the Public Health Service
(PHS) has, since 1962, recommended that public water
supplies contain between 0.7 and 1.2 milligrams of fluoride
per liter of drinking water.
The Occupational Safety and Health Administration (OSHA)
has set limits of 0.2 milligrams per cubic meter (0.2 mg/m3) for
fluorine, 2.0 mg/m3 for hydrogen fluoride, and 2.5 mg/m3 for
fluoride in workroom air to protect workers during an 8-hour
shift over a 40-hour work week.
Source of Information
Agency for Toxic Substances and Disease Registry
(ATSDR). 2003. Toxicological Profile for Fluorides,
Hydrogen Fluoride, and Fluorine. Atlanta, GA: U.S.
Department of Health and Human Services, Public Health
Service
Where can I get more information? For more information, contact the Agency for Toxic Substances and
Disease Registry, Division of Toxicology, 1600 Clifton Road NE,MailstopF-32, Atlanta, GA30333. Phone: 1-888-422-
8737, FAX: 770-488-4178. ToxFAQs Internet address via WWW is http://www.atsdr.cdc.gov/toxfaq.html. ATSDR can
tell you where to find occupational and environmental health clinics. Their specialists can recognize, evaluate, and
treat illnesses resulting from exposure to hazardous substances. You can also contact your community or state health
or environmental quality department if you have any more questions or concerns.
Federal Recycling Program
Printed on Recycled Paper
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CDC - Lead and Drinking Water from Private Wells - Wells - Private Water Systems - Dr... Page 1 of 2
Centers for Disease Control and Prevention
11 iffw jP j^jjk iQi^p
r.'DC 2&I7: Saving Lives. Protecting People. Saving Money through Prevention.
Lead and Drinking Water from Private Wells
What is lead?
Lead is a naturally occurring bluish-gray metal found in small amounts on the earth's outer
layer. Lead can be found in all parts of our environment. Much of it comes from human
activities including burning fossil fuels, mining, and manufacturing.
Lead is found in many different materials. It can still be found in lead-based paint, batteries,
ammunition, metal products such as solder and pipes, and devices to shield X-rays. Because of
health concerns, the amount of lead found in gasoline, paints and ceramic products, caulking,
and pipe solder has been reduced in recent years. As a result, the amount of lead in our blood
now is much less than it was 30 years ago.
For more information about lead illnesses and treatment, please visit CDC-ATSDR's lead
(http://www.atsdr.cdc.gov/tfactsi3.html) page.
(#) OTOP
Where and how does lead get into drinking water?
Lead rarely occurs naturally in water; it usually gets into the water from the delivery system.
Lead pipes are the main contributor to high lead levels in tap water. Other sources include
parts of the water delivery system such as lead solder used to join copper pipes, brass in
faucets, coolers, and valves. Although brass usually contains low lead levels, the lead can still
dissolve into the water, especially when the fixtures are new. Private wells more than 20 years
old may contain lead in the "packer" element that is used to help seal the well above the well
screen. Some brands of older submersible pumps used in wells may also contain leaded-brass
components. Corrosion of pipes and fixture parts can cause the lead to get into tap water.
(#) OTOP
How can I find out whether there is lead in my drinking water?
If you suspect a problem and your drinking water comes from a private well, you may contact
your state certification officer (http://www.epa.gov/ogwdw/labs/index.html) &
(http://www.cdc.gov/Other/disclaimer.html) for a list of laboratories in your area that will perform
tests on drinking water for a fee.
(#) OTOP
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CDC - Lead and Drinking Water from Private Wells - Wells - Private Water Systems - Dr... Page 2 of 2
How do I remove lead from my drinking water?
First, try to identify and remove the lead source. If you have a private well, check both the well
and the pump for potential lead sources. A licensed well water contractor can help you
determine if any of the well components are a source of lead.
Heating or boiling your water will not remove lead. Because some of the water evaporates
during the boiling process, the lead concentration of the water can actually increase slightly as
the water is boiled.
If it is not possible or cost-effective to remove the lead source, flushing the water system before
using the water for drinking or cooking may be an option. Any time a particular faucet has not
been used for several hours (approximately 6 or more), you can flush the system by running
the water for about 1-2 minutes or until the water becomes as cold as it will get. Flush each
faucet individually before using the water for drinking or cooking. You can use the water
flushed from the tap to water plants, wash dishes or clothing, or clean. Avoid cooking with or
drinking hot tap water because hot water dissolves lead more readily than cold water does. Do
not use hot tap water to make cereals, drinks or mix baby formula. You may draw cold water
after flushing the tap and then heat it if needed.
You may also wish to consider water treatment methods such as reverse osmosis, distillation,
and carbon filters specially designed to remove lead. Typically these methods are used to treat
water at only one faucet. Contact your local health department for recommended procedures. If
you want to know more about these filters, please contact NSF International
(http://nsf.org/certified/consumer/listings advanced.asp?
companyname=&productname=&programcode=WATER FILTER&f) &
fhttp://www.cdc.gov/Other/disclaimer.html). an organization for public health and safety through
standards development, product certification, education, and risk management. Remember to
have your well water tested regularly f/healthywater/drinking/private/wells/testing.html). at least
once a year, to make sure the problem is controlled.
{#)
Page last reviewed: December 14, 2009
Page last updated: May 3, 2010
Content source: Centers for Disease Control and Prevention
Centers for Disease Control and Prevention 1600 Clifton Rd. Atlanta, GA 30333, USA
800-CDC-INFO (800-232-4636) TTY: (888) 232-6348, New Hours of Operation 8am-8pm ET/Monday-Friday
Closed Holidays - cdcinfo(5)cdc.gov
http://www.cdc.gov/healthywater/drinking/private/wells/disease/lead.html 5/7/2012
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ATSDR
AGENCY FOR TOXIC SUBSTANCES
AND DISEASE REGISTRY
LEAD
CAS # 7439-92-1
Division of Toxicology and Environmental Medicine ToxFAQs1
August 2007
This fact sheet answers the most frequently asked health questions (FAQs) about lead. For more
information, call the ATSDR Information Center at 1-800-232-4636. This fact sheet is one in a series
of summaries about hazardous substances and their health effects. It is important you understand this
information because this substance may harm you. The effects of exposure to any hazardous substance
depend on the dose, the duration, how you are exposed, personal traits and habits, and whether other
chemicals are present.
HIGHLIGHTS: Exposure to lead can happen from breathing workplace air or
dust, eating contaminated foods, or drinking contaminated water. Children can be
exposed from eating lead-based paint chips or playing in contaminated soil. Lead
can damage the nervous system, kidneys, and reproductive system. Lead has been
found in at least 1,272 of the 1,684 National Priority List sites identified by the
Environmental Protection Agency (EPA).
What is lead?
Lead is a naturally occurring bluish-gray metal found in
small amounts in the earth's crust. Lead can be found in all
parts of our environment. Much of it comes from human
activities including burning fossil fuels, mining, and
manufacturing.
Lead has many different uses. It is used in the production of
batteries, ammunition, metal products (solder and pipes), and
devices to shield X-rays. Because of health concerns, lead
from paints and ceramic products, caulking, and pipe solder
has been dramatically reduced in recent years. The use of
lead as an additive to gasoline was banned in 1996 in the
United States.
What happens to lead when it enters the
environment?
Q Lead itself does not break down, but lead compounds are
changed by sunlight, air, and water.
Q When lead is released to the air, it may travel long
distances before settling to the ground.
Q Once lead falls onto soil, it usually sticks to soil
particles.
Q Movement of lead from soil into groundwater will depend
on the type of lead compound and the characteristics of the
soil.
How might I be exposed to lead?
Q Eating food or drinking water that contains lead. Water
pipes in some older homes may contain lead solder. Lead
can leach out into the water.
Q Spending time in areas where lead-based paints have
been used and are deteriorating. Deteriorating lead paint can
contribute to lead dust.
Q Working in a job where lead is used or engaging in
certain hobbies in which lead is used, such as making
stained glass.
Q Using health-care products or folk remedies that contain
lead.
How can lead affect my health?
The effects of lead are the same whether it enters the body
through breathing or swallowing. Lead can affect almost
every organ and system in your body. The main target for
lead toxicity is the nervous system, both in adults and
children. Long-term exposure of adults can result in
decreased performance in some tests that measure functions
of the nervous system. It may also cause weakness in
fingers, wrists, or ankles. Lead exposure also causes small
increases in blood pressure, particularly in middle-aged and
older people and can cause anemia. Exposure to high lead
levels can severely damage the brain and kidneys in adults
or children and ultimately cause death. In pregnant women,
high levels of exposure to lead may cause miscarriage. High-
level exposure in men can damage the organs responsible for
sperm production.
How likely is lead to cause cancer?
We have no conclusive proof that lead causes cancer in
humans. Kidney tumors have developed in rats and mice
that had been given large doses of some kind of lead
compounds. The Department of Health and Human Services
U.S. DEPARTMENT OF HEALTH AND HUMAN SERVICES, Public Health Service
Agency for Toxic Substances and Disease Registry
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Page 2
LEAD
CAS # 7439-92-1
ToxFAQs™ Internet address is http://www.atsdr.cdc.gov/toxfaq.html
(DHHS) has determined that lead and lead compounds are
reasonably anticipated to be human carcinogens and the EPA
has determined that lead is a probable human carcinogen.
The International Agency for Research on Cancer (IARC) has
determined that inorganic lead is probably carcinogenic to
humans and that there is insufficient information to determine
whether organic lead compounds will cause cancer in
humans.
How can lead affect children?
Small children can be exposed by eating lead-based paint
chips, chewing on objects painted with lead-based paint, or
swallowing house dust or soil that contains lead.
Children are more vulnerable to lead poisoning than adults. A
child who swallows large amounts of lead may develop blood
anemia, severe stomachache, muscle weakness, and brain
damage. If a child swallows smaller amounts of lead, much
less severe effects on blood and brain function may occur.
Even at much lower levels of exposure, lead can affect a
child's mental and physical growth.
Exposure to lead is more dangerous for young and unborn
children. Unborn children can be exposed to lead through
their mothers. Harmful effects include premature births,
smaller babies, decreased mental ability in the infant, learning
difficulties, and reduced growth in young children. These
effects are more common if the mother or baby was exposed
to high levels of lead. Some of these effects may persist
beyond childhood.
How can families reduce the risks of exposure to
lead?
Q Avoid exposure to sources of lead.
Q Do not allow children to chew or mouth surfaces that
may have been painted with lead-based paint.
Q If you have a water lead problem, run or flush water that
has been standing overnight before drinking or cooking with
it.
Q Some types of paints and pigments that are used as
make-up or hair coloring contain lead. Keep these kinds of
products away from children
Q If your home contains lead-based paint or you live in an
area contaminated with lead, wash children's hands and faces
often to remove lead dusts and soil, and regularly clean the
house of dust and tracked in soil.
Is there a medical test to determine whether I've
been exposed to lead?
A blood test is available to measure the amount of lead in
your blood and to estimate the amount of your recent
exposure to lead. Blood tests are commonly used to screen
children for lead poisoning. Lead in teeth or bones can be
measured by X-ray techniques, but these methods are not
widely available. Exposure to lead also can be evaluated by
measuring erythrocyte protoporphyrin (EP) in blood samples.
EP is a part of red blood cells known to increase when the
amount of lead in the blood is high. However, the EP level is
not sensitive enough to identify children with elevated blood
lead levels below about 25 micrograms per deciliter (ug/dL).
These tests usually require special analytical equipment that
is not available in a doctor's office. However, your doctor
can draw blood samples and send them to appropriate
laboratories for analysis.
Has the federal government made recommendations
to protect human health?
The Centers for Disease Control and Prevention (CDC)
recommends that states test children at ages 1 and 2 years.
Children should be tested at ages 3-6 years if they have
never been tested for lead, if they receive services from
public assistance programs for the poor such as Medicaid or
the Supplemental Food Program for Women, Infants, and
Children, if they live in a building or frequently visit a house
built before 1950; if they visit a home (house or apartment)
built before 1978 that has been recently remodeled; and/or if
they have a brother, sister, or playmate who has had lead
poisoning. CDC considers a blood lead level of 10 ug/dL to
be a level of concern for children.
EPA limits lead in drinking water to 15 ug per liter.
References
Agency for Toxic Substances and Disease Registry (ATSDR).
2007. Toxicological Profile for lead (Update). Atlanta, GA: U.S.
Department of Public Health and Human Services, Public Health
Service.
Where Can I get more information? For more information, contact the Agency for Toxic Substances and Disease
Registry, Division of Toxicology and Environmental Medicine, 1600 Clifton Road NE, Mailstop F-32, Atlanta, GA 30333. Phone:
1-800-232-4636, FAX: 770-488-4178. ToxFAQs Internet address via WWW is http://www.atsdr.cdc.gov/toxfaq.html. ATSDR
can tell you where to find occupational and environmental health clinics. Their specialists can recognize, evaluate, and treat
illnesses resulting from exposure to hazardous substances. You can also contact your community or state health or environmental
quality department if you have any more questions or concerns.
Federal Recycling Program
Printed on Recycled Paper
-------
ATSDR
AGENCY FOR TOXIC SUBSTANCES
AND DISEASE REGISTRY
MANGANESE
CAS # 7439-96-5
Division of Toxicology and Environmental Medicine ToxFAQs1
September 2008
This fact sheet answers the most frequently asked health questions (FAQs) about manganese. For
more information, call the ATSDR Information Center at 1-800-232-4636. This fact sheet is one in a
series of summaries about hazardous substances and their health effects. It is important you
understand this information because this substance may harm you. The effects of exposure to any
hazardous substance depend on the dose, the duration, how you are exposed, personal traits and
habits, and whether other chemicals are present.
HIGHLIGHTS: Manganese is a trace element and eating a small amount from food
or water is needed to stay healthy. Exposure to excess levels of manganese may
occur from breathing air, particularly where manganese is used in manufacturing,
and from drinking water and eating food. At high levels, it can cause damage to
the brain. Manganese has been found in at least 869 of the 1,669 National Priorities
List sites identified by the Environmental Protection Agency (EPA).
What is manganese?
Manganese is a naturally occurring metal that is found in
many types of rocks. Pure manganese is silver-colored, but
does not occur naturally. It combines with other substances
such as oxygen, sulfur, or chlorine. Manganese occurs
naturally in most foods and may be added to some foods.
Manganese is used principally in steel production to improve
hardness, stiffness, and strength. It may also be used as an
additive in gasoline to improve the octane rating of the gas.
What happens to manganese when it enters the
environment?
Q Manganese can be released to the air, soil, and water
from the manufacture, use, and disposal of manganese-based
products.
Q Manganese cannot break down in the environment. It
can only change its form or become attached to or separated
from particles.
Q In water, manganese tends to attach to particles in the
water or settle into the sediment.
Q The chemical state of manganese and the type of soil
determine how fast it moves through the soil and how much
is retained in the soil.
Q The manganese-containing gasoline additive may degrade
in the environment quickly when exposed to sunlight,
releasing manganese.
How might I be exposed to manganese?
Q The primary way you can be exposed to manganese is
by eating food or manganese-containing nutritional
supplements. Vegetarians who consume foods rich in
manganese such as grains, beans and nuts, as well as heavy
tea drinkers, may have a higher intake of manganese than
the average person.
Q Certain occupations like welding or working in a factory
where steel is made may increase your chances of being
exposed to high levels of manganese.
Q Manganese is routinely contained in groundwater, drinking
water, and soil at low levels. Drinking water containing
manganese or swimming or bathing in water containing
manganese may expose you to low levels of this chemical.
How can manganese affect my health?
Manganese is an essential nutrient, and eating a small
amount of it each day is important to stay healthy.
The most common health problems in workers exposed
to high levels of manganese involve the nervous system.
These health effects include behavioral changes and other
nervous system effects, which include movements that
may become slow and clumsy. This combination of
symptoms when sufficiently severe is referred to as
"manganism". Other less severe nervous system effects
such as slowed hand movements have been observed in
U.S. DEPARTMENT OF HEALTH AND HUMAN SERVICES, Public Health Service
Agency for Toxic Substances and Disease Registry
-------
Page 2
MANGANESE
CAS # 7439-96-5
ToxFAQs™ Internet address is http://www.atsdr.cdc.gov/toxfaq.html
some workers exposed to lower concentrations in the
work place.
Nervous system and reproductive effects have been
observed in animals after high oral doses of manganese.
How likely is manganese to cause cancer?
The EPA concluded that existing scientific information
cannot determine whether or not excess manganese can
cause cancer.
How can manganese affect children?
Studies in children have suggested that extremely high
levels of manganese exposure may produce undesirable
effects on brain development, including changes in
behavior and decreases in the ability to learn and
remember. We do not know for certain that these
changes were caused by manganese alone. We do not
know if these changes are temporary or permanent. We
do not know whether children are more sensitive than
adults to the effects of manganese, but there is some
indication from experiments in laboratory animals that
they may be.
Studies of manganese workers have not found increases
in birth defects or low birth weight in their offspring.
No birth defects were observed in animals exposed to
manganese.
How can families reduce the risks of exposure to
manganese?
Q Children are not likely to be exposed to harmful amounts
of manganese in the diet. However, higher-than-usual
amounts of manganese may be absorbed if their diet is low
in iron. It is important to provide your child with a well-
balanced diet.
Q Workers exposed to high levels of airborne manganese in
certain occupational settings may accumulate manganese dust
on their work clothes. Manganese-contaminated work
clothing should be removed before getting into your car or
entering your home to help reduce the exposure hazard for
yourself and your family.
Is there a medical test to determine whether I've
been exposed to manganese?
Several tests are available to measure manganese in
blood, urine, hair, or feces. Because manganese is
normally present in our body, some is always found in
tissues or fluids.
Because excess manganese is usually removed from the
body within a few days, past exposures are difficult to
measure with common laboratory tests.
Has the federal government made recommendations
to protect human health?
The EPA has determined that exposure to manganese in
drinking water at concentrations of 1 mg/L for up to
10 days is not expected to cause any adverse effects in a
child.
The EPA has established that lifetime exposure to 0.3 mg/L
manganese is not expected to cause any adverse effects.
The FDA has determined that the manganese concentration
in bottled drinking water should not exceed 0.05 mg/L.
The Occupational Health and Safety Administration (OSHA)
has established a ceiling limit (concentration that should not
be exceeded at any time during exposure) of 5 mg/m3 for
manganese in workplace air.
References
Agency for Toxic Substances and Disease Registry (ATSDR).
2008. Toxicological Profile for Manganese (Draft for Public
Comment). Atlanta, GA: U.S. Department of Public Health
and Human Services, Public Health Service.
Where Can I get more information? For more information, contact the Agency for Toxic Substances and Disease
Registry, Division of Toxicology and Environmental Medicine, 1600 Clifton Road NE, Mailstop F-32, Atlanta, GA 30333. Phone:
1-800-232-4636, FAX: 770-488-4178. ToxFAQs Internet address via WWW is http://www.atsdr.cdc.gov/toxfaq.html. ATSDR
can tell you where to find occupational and environmental health clinics. Their specialists can recognize, evaluate, and treat
illnesses resulting from exposure to hazardous substances. You can also contact your community or state health or environmental
quality department if you have any more questions or concerns.
Federal Recycling Program
Printed on Recycled Paper
-------
CDC - Nitrate and Drinking Water from Private Wells - Wells - Private Water Systems -... Page 1 of 2
Centers for Disease Control and Prevention
|t ffl ^A^BBp
gp rjDC iW/7: Saving Lives, Protecting People. Saving Money Through Prevention.
Nitrate and Drinking Water from Private Wells
What is nitrate?
Nitrate is a compound that is formed naturally when nitrogen combines with oxygen or ozone.
Nitrogen is essential for all living things, but high levels of nitrate in drinking water can be
dangerous to health, especially for infants and pregnant women. Nitrates are also made in
large amounts by plants and animals, and are released in smoke and industrial or automotive
exhaust.
For more information about nitrate illness and treatment, please visit EPA's nitrate
(http://www.epa.gov/safewater/contaminants/dw contamfs/nitrates.html) g
fhttp://www.cdc.gov/Other/ disclaimer.html) page.
C1TOP-
Where and how does nitrate get into drinking water?
Nitrate can occur naturally in surface and groundwater at a level that does not generally cause
health problems. High levels of nitrate in well water often result from improper well
construction, well location, overuse of chemical fertilizers, or improper disposal of human and
animal waste. Sources of nitrate that can enter your well include fertilizers, septic systems,
animal feedlots, industrial waste, and food processing waste. Wells maybe more vulnerable to
such contamination after flooding, particularly if the wells are shallow, have been dug or bored,
or have been submerged by floodwater for long periods of time.
How can I find out whether there is nitrate in my drinking water?
If you suspect a problem and your drinking water comes from a private well, you may contact
your state certification officer fhttp://www.epa.gov/ogwdw/labs/index.html) S
fhttp://www.cdc.gov/Other/ disclaimer.html) for a list of laboratories in your area that will perform
tests on drinking water for a fee.
(#) ClTOP
How do I remove nitrate from my drinking water?
Nitrate may be successfully removed from water using treatment processes such as ion
exchange, distillation, and reverse osmosis. Contact your local health department for
recommended procedures.
http://www.cdc.gov/healthywater/drinking/private/wells/disease/nitrate.html 5/7/2012
-------
CDC - Nitrate and Drinking Water from Private Wells - Wells - Private Water Systems -... Page 2 of 2
Heating or boiling your water will not remove nitrate. Because some of the water will evaporate
during the boiling process, the nitrate levels of water can actually increase slightly in
concentration if the water is boiled. Mechanical filters or chemical disinfection, such as
chlorination, DO NOT remove nitrate from water.
Remember to have your well water tested regularly
(/healthywater/drinking/private/wells/testing.html). at least once a year, after installing a
treatment system to make sure the problem is controlled.
(#)
Page last reviewed: December 2, 2009
Page last updated: December 2, 2009
Content source: Centers for Disease Control and Prevention
Centers for Disease Control and Prevention 1600 Clifton Rd. Atlanta, GA 30333, USA
800-CDC-INFO (800-232-4636) TTY: (888) 232-6348, New Hours of Operation 8am-8pm ET/Monday-Friday
Closed Holidays - cdcinfo(5)cdc.gov
http://www.cdc.gov/healthywater/drinking/private/wells/disease/nitrate.html 5/7/2012
-------
ATSDR
AGENCY FOR TOXIC SUBSTANCES
AND DISEASE REGISTRY
NITRATES AND NITRITES
CAS # 84145-82-4,14797-65-0
Division of Toxicology and Environmental Medicine ToxFAQs1
January 2011
This fact sheet answers the most frequently asked health questions (FAQs) about nitrates and nitrites.
For more information, call the ATSDR Information Center at 1-800-232-4636. This fact sheet is one in
a series of summaries about hazardous substances and their health effects. It is important you
understand this information because these substances may harm you. The effects of exposure to any
hazardous substance depend on the dose, the duration, how you are exposed, personal traits and
habits, and whether other chemicals are present.
HIGHLIGHTS: Nitrates and nitrites occur in soil, in water, and in some foods. They are
naturally occurring inorganic nitrogen ions. Nitrates are a natural part of the human diet.
When drinking water or eating food from areas containing nitrogen-based fertilizers, people
could be exposed to high nitrate and nitrite levels. The most serious health condition
caused by high nitrate or nitrite exposure is acute acquired methemoglobinemia. Infants
younger than 4 months of age exposed to high levels of nitrates/nitrites are especially prone
to acute acquired methemoglobinemia, which is described more fully in this fact sheet in
the section entitled "How can nitrates and nitrites affect my health?"
What are nitrates and nitrites?
Nitrate (NO 3") and nitrite (NO2 ") are inorganic ions that occur
naturally and are part of the nitrogen cycle. Nitrates (e.g.,
potassium nitrate and ammonium nitrate) are common
ingredients of fertilizer that contains nitrogen.
What happens to nitrates and nitrites when they
enter the environment?
Q Nitrite oxidizes easily into nitrate. Nitrate thus more
frequently occurs in groundwater and surface water.
Q Nitrate-containing compounds in the soil are generally
soluble, which means they dissolve easily in water. Nitrates
thus flow easily into groundwater.
Q Nitrates and nitrites both occur in soil and water.
Microbes break down animal and human organic wastes in
soil and water. This breakdown process converts wastes
into ammonia, which then oxidizes into nitrite and nitrate.
How might I be exposed to nitrates and nitrites?
Q You might be exposed to nitrates and nitrites as normal
parts of a human diet. Vegetables such as cauliflower,
spinach, collard greens, broccoli, beets, and root vegetables
have naturally greater nitrate content than do other plant
foods.
Q You may be exposed to high amounts of nitrates/nitrites
from soil and water contaminated by runoff from nitrogen-
containing fertilizers (e.g., potassium nitrate and ammonium
nitrate).
Q You may be exposed to nitrates/nitrites from contaminated
foodstuffs, from certain medications, and from certain
inhalants that give off nitrite fumes.
U.S. DEPARTMENT OF HEALTH AND HUMAN SERVICES, Public Health Service
Agency for Toxic Substances and Disease Registry
How can nitrates and nitrites affect my health?
Excessive nitrate or nitrite exposure can result in acute
acquired methemoglobinemia, a serious health
condition.
Hemoglobin in blood carries oxygen from the lungs to tissues
and helps carry carbon dioxide back to the lungs.
Hemoglobin in blood contains iron normally found in the
Fe2+ (ferrous) state. But excessive nitrates or nitrites can
alter the iron in hemoglobin to the Fe3+ (ferric) state. This
forms methemoglobin, an abnormal form of hemoglobin. As
methemoglobin forms, the blood loses its ability to carry oxygen
to tissues (anoxia).
Methemoglobinemia is actually an excess of methemoglobin in
the blood. Methemoglobinemia can cause cyanosis (blue skin)
of limbs/trunk, weakness, and rapid heart rate. If
methemoglobinemia progresses in severity, central nervous
system depression can occur, as can headache, dizziness,
fatigue, difficulty in breathing, and nausea. Finally, severe
methemoglobinemia can cause lethargy, brief loss of
consciousness, irregular heartbeat, shock, convulsions,
coma, and even death. In fact, methemoglobin levels greater
than 50% are potentially fatal (Nathan et al. 1977).
Nitrate and nitrite medications may cause hypotension (low
blood pressure). But ingestion of nitrates and nitrites in
food and water does not commonly result in hypotension.
Maternal exposure to environmental nitrates and nitrites may
increase the risk of pregnancy complications such as anemia,
abortion, premature labor, or preeclampsia.
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Page 2
NITRATES AND NITRITES
CAS # 84145-82-4,14797-65-0
ToxFAQs™ Internet address is http://www.atsdr.cdc.gov/toxfaq.html
Methemoglobinemia can also occur from other causes.
Exposure to oxidizing drugs or chemicals, systemic acidosis
(a generalized, abnormal increase in body fluid acidity),
diarrhea, or some genetic disorders such as infant cyanosis
(bluish discoloration of skin and mucus membranes) shortly
after birth can all result in methemoglobinemia.
How likely are nitrates and nitrites to cause cancer?
The Department of Health and Human Services (DHHS), the
International Agency for Research on Cancer (IARC), and
the Environmental Protection Agency (EPA) have not
classified nitrates and nitrites as to their human
carcinogenicity.
Still, a metabolic pathway is available for nitrites to react with
molecules in organisms to form N-nitroso compounds, some
of which may cause cancer.
How can nitrates and nitrites affect children?
In some infants, fetal methemoglobinemia can be a significant
problem. An infant's highly alkaline gastrointestinal system
favors the growth of nitrate-reducing bacteria, particularly in
the stomach and especially after ingestion of contaminated
water. This can lead to conversion of nitrates into high levels
of nitrites. These can change the hemoglobin in blood to
methemoglobin. An adult stomach, however, is typically
too acidic to allow for significant bacterial growth that
would convert nitrates to nitrites.
Infants younger than 4 months of age are prone to nitrite
exposure, especially infants who ingest formula diluted with
water from nitrate-contaminated rural domestic wells. A
portion of hemoglobin in young infants is still in the form of
fetal hemoglobin. Nitrites can more readily generate met-
hemoglobin from oxidized fetal hemoglobin than from adult
hemoglobin. Thus, infants less than 4 months of age, and
especially premature infants, are particularly susceptible to
such exposure.
At or near the 30th week of pregnancy, an expectant mother
and her fetus might be more sensitive to toxicity from nitrites
or nitrates.
How can families reduce the risk of exposure to
nitrates and nitrites?
Q You should avoid exposure to water, soil, or food
contaminated with high levels of nitrates and nitrites.
Q If you have well water that comes from areas that contain
large amounts of nitrogen-containing fertilizers, you should
monitor the water closely.
Is there a medical test to determine whether I've
been exposed to nitrates and nitrites?
No routine medical tests are available to determine nitrate
and nitrite levels.
Routine blood tests are available to detect
methemoglobinemia. But these tests cannot tell whether the
high methemoglobin levels were caused by nitrates or nitrites.
Has the federal government made recommendations
to protect human health?
The U.S. EPA has set an enforceable standard called a
maximum contaminant level (MCL) for nitrates at
10 ppm and for nitrites at 1 ppm in drinking water. Public
water supplies meeting certain criteria must follow these
regulations.
The U.S. EPA has set a reference dose (RfD) for nitrate of
1.6 mg nitrate nitrogen/kg body weight per day (equivalent
to about 7.0 mg nitrate ion/kg body weight per day).
The U.S. EPA has set an RfD of 0.1 mg nitrite
nitrogen/kg body weight per day (equivalent to 0.33 mg
nitrite ion/kg body weight per day).
References
Agency for Toxic Substances and Disease Registry
(ATSDR). 2007. Case Studies in Environmental Medicine,
Nitrate/Nitrite Toxicity. Atlanta, GA: U.S. Department of
Public Health and Human Services, Public Health Service.
Agency for Toxic Substances and Disease Registry
(ATSDR). 2004. Interaction Profile for: cyanide, fluoride,
nitrate, and uranium. Atlanta, GA: U.S. Department of Public
Health and Human Services, Public Health Service.
Nathan DM; Siegel AJ, BunnHF. 1977. Acute
methemoglobinemia and hemolytic anemia with
phenazopyridine. Arch Intern Med: 137(11): 1636-1638.
Where Can I get more information? For more information, contact the Agency for Toxic Substances and Disease
Registry, Division of Toxicology and Environmental Medicine, 1600 Clifton Road NE, Mailstop F-62, Atlanta, GA 30333. Phone:
1-800-232-4636, FAX: 770-488-4178. ToxFAQs Internet address via WWW is http://www.atsdr.cdc.gov/toxfaq.html. ATSDR
can tell you where to find occupational and environmental health clinics. Their specialists can recognize, evaluate, and treat
illnesses resulting from exposure to hazardous substances. You can also contact your community or state health or environmental
quality department if you have any more questions or concerns.
Federal Recycling Pr ogram
Printed on Recycled Paper
-------
ATSDR
AGENCY FOR TOXIC SUBSTANCES
AND DISEASE REGISTRY
ZINC
CAS # 7440-66-6
Division of Toxicology ToxFAQs1
This fact sheet answers the most frequently asked health questions (FAQs) about zinc. For more
information, call the ATSDR Information Center at 1-888-422-8737. This fact sheet is one in a series
of summaries about hazardous substances and their health effects. It is important you understand this
information because this substance may harm you. The effects of exposure to any hazardous substance
depend on the dose, the duration, how you are exposed, personal traits and habits, and whether other
chemicals are present.
HIGHLIGHTS: Zinc is a naturally occurring element. Exposure to high levels
of zinc occurs mostly from eating food, drinking water, or breathing workplace
air that is contaminated. Low levels of zinc are essential for maintaining good
health. Exposure to large amounts of zinc can be harmful. It can cause
stomach cramps, anemia, and changes in cholesterol levels. Zinc has been
found in at least 985 of the 1,662 National Priority List sites identified by the
Environmental Protection Agency (EPA).
What is zinc?
Zinc is one of the most common elements in the earth's
crust. It is found in air, soil, and water, and is present in all
foods. Pure zinc is a bluish-white shiny metal.
Zinc has many commercial uses as coatings to prevent rust,
in dry cell batteries, and mixed with other metals to make
alloys like brass, and bronze. A zinc and copper alloy is
used to make pennies in the United States.
Zinc combines with other elements to form zinc compounds.
Common zinc compounds found at hazardous waste sites
include zinc chloride, zinc oxide, zinc sulfate, and zinc
sulfide. Zinc compounds are widely used in industry to
make paint, rubber, dyes, wood preservatives, and ointments.
What happens to zinc when it enters the
environment?
Q Some is released into the environment by natural
processes, but most comes from human activities like mining,
steel production, coal burning, and burning of waste.
Q It attaches to soil, sediments, and dust particles in the
air.
Q Rain and snow remove zinc dust particles from the air.
Q Depending on the type of soil, some zinc compounds can
move into the groundwater and into lakes, streams, and
rivers.
Q Most of the zinc in soil stays bound to soil particles and
does not dissolve in water.
Q It builds up in fish and other organisms, but it does not
build up in plants.
How might I be exposed to zinc?
Q Ingesting small amounts present in your food and water.
Q Drinking contaminated water or a beverage that has been
stored in metal containers or flows through pipes that have
been coated with zinc to resist rust.
Q Eating too many dietary supplements that contain zinc.
Q Working on any of the following jobs: construction,
painting, automobile mechanics, mining, smelting, and
welding; manufacture of brass, bronze, or other zinc-
containing alloys; manufacture of galvanized metals; and
manufacture of machine parts, rubber, paint, linoleum,
oilcloths, batteries, some kind of glass, ceramics, and dyes.
How can zinc affect my health?
Zinc is an essential element in our diet. Too little zinc can
cause problems, but too much zinc is also harmful.
Harmful effects generally begin at levels 10-15 times higher
than the amount needed for good health. Large doses taken
by mouth even for a short time can cause stomach cramps,
nausea, and vomiting. Taken longer, it can cause anemia and
decrease the levels of your good cholesterol. We do not
know if high levels of zinc affect reproduction in humans.
Rats that were fed large amounts of zinc became infertile.
U.S. DEPARTMENT OF HEALTH AND HUMAN SERVICES, Public Health Service
Agency for Toxic Substances and Disease Registry
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Page 2
ZINC
CAS # 7440-66-6
ToxFAQs™ Internet address is http://www.atsdr.cdc.gov/toxfaq.html
Inhaling large amounts of zinc (as dusts or fumes) can cause
a specific short-term disease called metal fume fever. We do
not know the long-term effects of breathing high levels of
zinc.
Putting low levels of zinc acetate and zinc chloride on the
skin of rabbits, guinea pigs, and mice caused skin irritation.
Skin irritation will probably occur in people.
How likely is zinc to cause cancer?
The Department of Health and Human Services (DHHS) and
the International Agency for Research on Cancer (IARC)
have not classified zinc for carcinogenicity. Based on
incomplete information from human and animal studies, the
EPA has determined that zinc is not classifiable as to its
human carcinogenicity.
How can zinc affect children?
Zinc is essential for proper growth and development of
young children. It is likely that children exposed to very
high levels of zinc will have similar effects as adults. We do
not know whether children are more susceptible to the
effects of excessive intake of zinc than the adults.
We do not know if excess zinc can cause developmental
effects in humans. Animal studies have found decreased
weight in the offspring of animals that ingested very high
amounts of zinc.
How can families reduce the risks of exposure to
zinc?
Q Children living near waste sites that contain zinc may be
exposed to higher levels of zinc through breathing
contaminated air, drinking contaminated drinking water,
touching or eating contaminated soil.
Q Discourage your children from eating soil or putting their
hands in their mouths and teach them to wash their hands
frequently and before eating.
Q If you use medicines or vitamin supplements containing
zinc, make sure you use them appropriately and keep them
out of the reach of children.
Is there a medical test to determine whether I've
been exposed to zinc?
There are tests available to measure zinc in your blood,
urine, hair, saliva, and feces. These tests are not usually
done in the doctor's office because they require special
equipment. High levels of zinc in the feces can mean high
recent zinc exposure. High levels of zinc in the blood can
mean high zinc consumption and/or high exposure. Tests to
measure zinc in hair may provide information on long-term
zinc exposure; however, the relationship between levels in
your hair and the amount of zinc you were exposed to is not
clear.
Has the federal government made
recommendations to protect human health?
The EPA recommends that drinking water should contain no
more than 5 milligrams per liter of water (5 mg/L) because of
taste. The EPA requires that any release of 1,000 pounds (or
in some cases 5,000 pounds) into the environment be
reported to the agency.
To protect workers, the Occupational Safety and Health
Administration (OSHA) has set an average limit of 1 mg/m3
for zinc chloride fumes and 5 mg/m3 for zinc oxide (dusts and
fumes) in workplace air during an 8-hour workday, 40-hour
workweek.
Similarly, the National Institute for Occupational Safety and
Health (NIOSH) has set the same standards for up to a
10-hour workday over a 40-hour workweek.
References
Agency for Toxic Substances and Disease Registry
(ATSDR). 2005. Toxicological Profile for Zinc (Update).
Atlanta, GA: U.S. Department of Public Health and Human
Services, Public Health Service.
Where can I get more information? For more information, contact the Agency for Toxic Substances and
Disease Registry, Division of Toxicology, 1600 Clifton Road NE,MailstopF-32, Atlanta, GA30333. Phone: 1-888-422-
8737, FAX: 770-488-4178. ToxFAQs Internet address via WWW is http://www.atsdr.cdc.gov/toxfaq.html. ATSDR can
tell you where to find occupational and environmental health clinics. Their specialists can recognize, evaluate, and
treat illnesses resulting from exposure to hazardous substances. You can also contact your community or state health
or environmental quality department if you have any more questions or concerns.
Federal Recycling Program
Printed on Recycled Paper
-------
APPENDIX E
MICROBIAL REFERENCE TABLES
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Table 1: EPA's section 304(a) ambient water quality criteria for bacteria. (1) Freshwaters:
A
Indicator*1
E. coli e
Enterococci6
B
Geometric
mean
126/1 00 mil"
33/100mlc
C
Single sample maximum (per 100 ml)
Cl
Designated bathing
beach
(75% confidence level)
"235
"61
C2
Moderate use costal
recreation waters
(82% confidence level)
"298
"78
C3
Light use coastal
recreation waters
(90% confidence level)
"409
"107
C4
Infrequent use coastal
recreation waters
(95% confidence level)
"575
"151
Footnotes to table in paragraph (c)(l):
a. This value is for use with analytical methods 1103.1, 1603, or 1604 or any equivalent method that
measures viable bacteria.
b. Calculated using the following: single sample maximum = geometric mean * 10A(confidence level factor
* log standard deviation), where the confidence level factor is: 75%: 0.68; 82%: 0.94; 90%: 1.28; 95%:
1.65. The log standard deviation from EPA's epidemiological studies is 0.4.
c. This value is for use with analytical methods 1106.1 or 1600 or any equivalent method that measures
viable bacteria.
d. The State may determine which of these indicators applies to its freshwater coastal recreation waters.
Until a State makes that determination, E. coli will be the applicable indicator.
e. These values apply to E. coli or enterococci regardless of origin unless a sanitary survey shows that
sources of the indicator bacteria are non-human and an epidemiological study shows that the indicator
densities are not indicative of a human health risk.
Table 2: Alaska Water Quality Standards for Designated Uses
POLLUTANT & WATER USE
CRITERIA
(2) FECAL COLIFORM
BACTERIA (FC), FOR FRESH
WATER USES (See note 1)
(A) Water Supply
(i) drinking, culinary, and food
processing
(A) Water Supply
(ii) agriculture, including irrigation and
stock watering
(B) Water Recreation
(i) contact recreation
(B) Water Recreation
(ii) secondary recreation
CRITERIA
In a 30-day period, the geometric mean may not exceed 20 FC/100 ml,
and not more than 10% of the samples may exceed 40 FC/100 ml. For
groundwater, the FC concentration must be less than 1 FC/100 ml, using
the fecal coliform Membrane Filter Technique, or less than
3 FC/100 ml, using the fecal coliform most probable number (MPN)
technique
The geometric mean of samples taken in a 30-day period may not
exceed 200 FC/100 ml, and not more than 10% of the samples may
exceed 400 FC/100 ml.
For products not normally cooked and for dairy sanitation of
unpasteurized products, the criteria for drinking water supply, (2)(A)(i),
apply.
In a 30-day period, the geometric mean of samples may not exceed 100
FC/100 ml, and not more than one sample, or more than 10% of the
samples if there are more than 10 samples, may exceed 200 FC/100 ml.
In a 30-day period, the geometric mean of samples may not exceed 200
FC/100 ml, and not more than 10% of the total samples may exceed 400
FC/100 ml.
http://dec.alaska.gov/water/wqsar/wqs/pdfs/18 AAC 70 as Amended Through May 26 2011.pdf
-------
APPENDIX F
MICROBIAL FIGURES AND TABLES
-------
APPENDIX F.i.
EKWOK MICROBIAL FIGURES AND TABLES
-------
Ekwok
Figure 4: Cumulative E.coli (Spring A and Fall B) and Enterococcus sp. (Spring C and Fall D) microbial
indicator organism density detected in landfill impacted and control surface water samples.
4.0
_, 3.5
E
§ 3.0
• 2.5
2.0
01.5
0.5
0.0
Downgradient <50m
Dump
Subsurface
Downgradient <5000m
Control
Cumulative E.coli Microbial Load
4.0
_, 3.5
§3.0
3.4
Dump
Downgradient <50m
Control
Cumulative E.coli Microbial Load
4.0
_, 3.5
E
§ 3.0
T 2'5
2.0
>
O 1.5
I'0
0.5
0.0
2.7 T • Downgradient <50m
4.0
Cumulative Enterococcus sp. Microbial Load
Cumualive Microbial Enterococcus sp. Load
Table 1: List of Ekwok tested microbial samples, which are exceeded the EPA recommended bacteria
geometric mean for water quality criteria.
Location
Dump Impacted Water Spring 2010
<50m downgradient Spring 2010
Subsurface Water Spring 2010
Dump Impacted Water Fall 2010
<50m downgradient Fall 2010
Dump Impacted Water Spring 2011
<50m downgradient Spring 201 1
Dump Impacted Water Fall 201 1
Total Number
Indicator
E. coll
Recommended geometric mean
126/100 ml
631/lOOmL
1585/lOOmL
2512/lOOmL
2512/lOOmL
398/lOOmL
1585/lOOmL
2512/lOOmL
7
Enterococci
Recommended geometric mean
33/100 ml
794/lOOmL
126/lOOmL
2512/lOOmL
2512/lOOmL
316/lOOmL
2512/lOOmL
2512/lOOmL
2512/lOOmL
8
-------
APPENDIX F.ii.
EEK MICROBIAL FIGURES AND TABLES
-------
Eek
Figure 1: Cumulative E.coli {Fall 2009-11 (A), Spring 2010-11(C)} and Enterococcus sp.{Fall 2009-11
(B), Spring 2010-11 (D)} microbial indicator organism load detected in impacted dump and control surface
waters.
3.0
E 2.5
§
£i 2.0
Z
Q.
Z 1.5
0.5
0.0
I Dump
I Downgradient <50m
Downgradient <5000m
Control
0.4 0.4
II
Cumualive Microbial E.coli Load
3.5
- 3.0
§«
i2.0
•0.5
0.0
Dump
Downgradient <50m
Downgradient <5000m
Control
Cumulative Microbial Enterococcus sp. Load
3.5
| 3.0
32,
E2.0
I1'5
cl.O
0.0
D
Dump
Downgradient <50m
Downgradient <5000m
Control
Cumualtive Microbial E.coli Load
4.0
| 3.5
O 3.0
§2.5
a.
^ 2.0
$1.5
S 1-0
01
^ 0.5
0.0
I Dump
I Downgradient <50m
Downgradient <5000m
Control
Cumulative Microbial Enterococcus sp. Load
Tab lei: List of Eek tested microbial samples that exceeded the EPA recommended bacteria geometric
mean for water quality criteria.
Location
Dump Impacted Water Fall 2009
Dump Impacted Water Spring 2010
Dump Impacted Water Fall 2010
Dump Impacted Water Spring 2011
Dump Impacted Water Fall 201 1
Total Number
Indicator
E. coll
Recommended geometric mean
126/100 ml
501/lOOmL
126/lOOmL
215/lOOmL
3
Enterococcl
Recommended geometric mean
33/100 ml
200/lOOmL
2512/lOOmL
126/lOOmL
371/lOOmL
63/100mL
5
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APPENDIX F.iii.
WHITE MOUNTAIN MICROBIAL FIGURES AND TABLES
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White Mountain
Figure 1: E.coli (A) and Enterococcus sp. (B) microbial indicator organism load detected in impacted
dump and control surface water samples
4.5
4.0
_i3.5
03.0
I"
±2.0
3 i.o
raO.5
01
2 o.o
Microbaial E.coli Load
3.1 3.0
Dump 2010 I A
• Downgradient <50m
• Downgradient <5000m
• Control 2010
• Dump 2011
Downgradient <50m
• Downgradient <5000m
• Subsurface 2011
Control 2011
Spring 2010
Spring 2011
4.0
3.5
- 3.0
§2.5
3.4 >3.4
Dump 2010
I Downgradient <50m
Downgradient <5000m
I Control 2010
I Dump 2011
Downgradient <50m
I Downgradient <5000m
Subsurface 2011
Control 2011
Spring 2010
Spring 2011
Table 1: List of White Mountain tested microbial samples, which are exceeded the EPA recommended
bacteria geometric mean for water quality criteria.
Location
Dump Impacted Water Spring 2010
<50m downgradient Spring 2010
Dump Impacted Water Spring 2011
<50m downgradient Spring 201 1
Total Number
Indicator
E. coli
Recommended geometric mean
126/100 ml
1000/lOOmL
251/lOOmL
1259/lOOmL
1000/lOOmL
4
Enterococci
Recommended geometric mean
33/100 ml
631/lOOmL
398/lOOmL
2512/lOOmL
2512/lOOmL
4
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APPENDIX F.iv.
FORT YUKON MICROBIAL FIGURES AND TABLES
-------
Fort Yukon
Figure 1: E.coli (A) and Enterococcus sp. (B) microbial indicator organism load detected in impacted
dump and control surface water samples on June 22, 2010, May 23, 2011, and August 19, 2011.
4.0
O 3.0
^ 2.0
u>
° 1.5
| 1.0
^0.5
0.0
Microbail E.coli Load
>3.4
I Downgradient <50m
I Downgradient <5000m
• Control Su 2010
» Downgradient <50m
I Downgradient <5000m
I Control Sp. 2011
I Downgradient <50m
. Downgradient <5000m
.Control Fall 2011
Jo,
Summer
Spring
Microbail Enterococcus sp. Load
2.9
>3.4
Downgradient <50m
Downgradient <5000m
Control Su 2010
Downgradient <50m
Downgradient <5000m
Control Sp. 2011
Downgradient <50m
Downgradient <5000m
Subsurface
Control Fall 2011
Summer
Spring
Table 1: List of Fort Yukon tested microbial samples, which exceeded EPA recommended geometric mean
for water quality criteria.
Location
<50m downgradient Spring 201 1
<50m downgradient Fall 201 1
Total Number
Indicator
E. coll
Recommended geometric mean
126/100 ml
2512/lOOmL
1
Enterococcl
Recommended geometric mean
33/100 ml
794/lOOmL
2512/lOOmL
2
-------
APPENDIX F.v.
ALLAKAKET MICROBIAL FIGURES AND TABLES
-------
Allakaket
Figure 1: E.coli (A) and Enterococcus (B) microbial indicators detected in impacted dump and control
surface water samples on July 7, 2010 and August 17, 2011.
Microbail E.coli Load
3.0
_,2-5
O 2.0
fl,
bfl
o i.o
c
5 0.5
0.0
Dump 2010
Downgradient <50m
Downgradient <5000m
Control 2010
Dump 2011
Downgradient <50m
Downgradient <5000m
Subsurface
Control 2011
Summer 2010
Fall 2011
Microbail Enterococcus sp. Load
Dump2010
Downgradient <50m
Downgradient <5000m
Control 2010
Dump 2011
Downgradient <50m
Subsurface
Downgradient <5000m
Control 2011
B
Summer 2010
Fall 2011
Table 1: List of Allakaket tested microbial samples exceeding EPA recommended bacterial geometric mean
for water quality criteria 1986.
Location
Dump Impacted Water 2010
<50m Downgradient 2010
Dump Impacted Water 201 1
Subsurface Water 20 11
Total Number
Indicator
E. coli
Recommended geometric mean
126/100 ml
126/lOmL
1
Enterococci
Recommended geometric mean
33/100 ml
2512/lOOmL
1995/lOOmL
125/lOOmL
316/lOOmL
4
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