United States Environmental Protection Agency National Risk Management Research Laboratory Cincinnati, OH 45268 Research and Development EPA/600/SR-97/112 November 1997 &EPA Project Summary Field Performance of Woodburning Stoves in Colorado During the 1995-96 Heating Season Robert Cornell, Dennis R. Jaasma, and Yagna Mukkamala During the winter of 1995-96, the field performance of 13 EPA-certified woodburning stoves in Crested Butte and Curecanti National Park, CO, was evaluated. Measurements included par- ticulate matter (PM), carbon monoxide (CO), and weekly average burn rates. Six non-catalytic Phase II stoves, six catalytic Phase II stoves, and one cata- lytic Phase I stove were monitored. The study adds to the existing database on the field emissions of newer and older certified stoves. Average non-catalytic stove PM and CO emission factors of the study were 9.8 and 93 g/kg, respec- tively. For the catalytic stoves the fac- tors were 22.8 and 112 g/kg, respec- tively. The report compares these val- ues with results from previous studies and suggests reasons that field perfor- mance is poor relative to what might be expected from certification test re- sults. This Project Summary was developed by the National Risk Management Re- search Laboratory's Air Pollution Pre- vention Control Division, Research Tri- angle Park, NC, to announce key find- ings of the research project that is fully documented in a separate report of the same title (see Project Report ordering information at back). Objective The purpose of this project was to quan- tify the field performance of EPA-certified woodstoves, both when stoves are rela- tively new and after stoves have been in service for an appreciable time. One-week averages of PM and CO emissions were measured for a variety of stoves, includ- ing both catalytic and non-catalytic EPA- certified models. The Virginia Polytechnic Institute and State University (VPI) sam- pler was used for all measurements, and both PM and CO emissions are reported as measured by the sampler. The report summarizes the measure- ment methods and the measured emis- sion factors. The emission factors of the current study are compared with earlier data for PM and CO emissions of certified and uncertified (conventional) stoves. Introduction Personnel from VPI measured woodstove emissions in Crested Butte, CO, during the winters of 1988-89, 1989-90, and 1991- 92. The 1988-89 and 1989-90 measure- ments were intended to determine the ef- fect of a town-wide changeover from con- ventional to EPA-certified (mostly Phase I) woodstoves. The 1991-92 study was intended to focus exclusively on Phase II stoves, but a limited number of Phase II stoves in Crested Butte and reluctance of owners to permit monitoring limited the Phase II data obtained. Both PM and CO emissions were measured during these studies. A fourth study, in the winter of 1992-93, involved only CO and carbon dioxide (CO2) measurements of catalytic stoves. The 1995-96 study obtained additional data on the performance of Phase II stoves in Crested Butte and in Curecanti Na- tional Park, located outside of Gunnison, CO. The intention was to monitor each stove for four weeks to average the ef- fects of weekly weather changes and other uncontrolled variables, but for some stoves fewer than four 1-week averages were obtained. Sampling in Crested Butte oc- curred from February 5 to March 4, 1996. Sampling in Curecanti National Park oc- curred from March 8 to April 13, 1996, ------- when warm weather ended the heating season. Thirteen stoves were monitored: seven catalytic and six non-catalytic. Household profiles describing each site are in the full report. One of the catalytic stoves was Phase I certified and all other stoves were Phase II certified. The full report also con- tains a spreadsheet showing all measured values and calculated emissions data. The previous studies created a large database of emissions from conventional and Phase I stoves, giving baseline data for comparison to Phase II models. Only one of the 1995-96 stoves was monitored in a previous study and can be directly compared with previous data. However, over the years, three Crested Butte stoves have been monitored for PM and CO dur- ing more than one season, and their data can be examined for long term perfor- mance changes. The 1988-1996 Colorado work also includes several catalytic stoves which were monitored for PM and CO (using the VPI sampler) during one sea- son and also had short-term (approxi- mately an hour) monitoring for flue gas temperature and CO and CO2 concentra- tions under technician-controlled conditions during the winter of 1992-93. The 1992- 93 CO, CO2, and temperature data can give a rough estimate of the PM and CO data that would have been obtained with the VPI sampler. Measurement Procedures The hardware used for the measure- ments is known as the "VPI sampler." It has been compared to the EPA reference method for woodstove PM and to the dilu- tion tunnel method for CO measurement and has been found to be accurate. The methods for sampler preparation and workup are documented in earlier reports and are not repeated here. Participants used their normal wood sup- ply. Field personnel weighed a large part of the participant's woodpile at sampler deployment, marked the weighed part by replacing the wood on top of a bright red ribbon, and weighed any unused wood from the pre-weighed supply at sampler retrieval. Fuel moisture was measured gravimetrically, using chips generated by low speed drilling of representative logs. Results Forty-seven deployments resulted in useful data on stove emissions. Eight blanks were also run and were used to correct the measured results and give an idea of the uncertainties of this season's measurements. Blanks were split equally between Crested Butte and the Curecanti National Recreation Area. Table 1 compares the PM and CO fac- tors for the current study with those of previous studies. The listed values repre- sent the average factors for all datapoints for each type of stove in each study. The average PM catch of the study was 30.5 mg, and the highest level of uncertainty was 1.6 mg; thus, the average gravimetric uncertainty is 1.6/30.5, or 5%. As in previ- ous studies the uncertainty in CO emis- sions is estimated to be +/- 10% of re- ported value. The average PM emission factor for the Phase II catalytic stoves in the 1995-96 study was 22.8 g/kg, approximately equiva- lent to that of conventional stoves and 133% greater than the average PM factor of Phase II non-catalytic stoves. The CO emission factors for catalytic stoves were 20% greater than for the non-catalytic stoves and effectively the same as for conventional stoves. The average PM emission factors for catalytic stoves in- creased by 30% from the 1991-92 study. The corresponding CO factors gained 45%. The non-catalytic stoves, on average, show no definitive evidence of performance degradation over the course of the study. A strong dependence of emission factors on burn rate has been noted for non- catalytic stoves, and this dependence prob- ably is the cause of the observed year-to- year fluctuations in average performance of these stoves. Significant physical degradation has been noted in catalytic stove models over the course of this study. In some cases the cause of poor catalytic stove perfor- mance has been identified as mechanical failures. In other cases one can only as- sume that factors such as operator be- havior or fuel variability are involved. In non-catalytic models, the operation, fuel- ing and design of the stoves (as opposed to mechanical degradation) appear to be the most likely determiners of emission performance. Table 1. Conventional and EPA Certified Woodstove Results Year of Study 1988-89 1989-90 1991-92 1995-96 PM Factors, g/kg Com CAT NCAT 22.1 5.5 — 22.2 11.1 9.9 — 17.6 14.9 — 22.8 9.8 CO Factors, g/kg Com CAT NCAT 115 40 — 111 52 76 — 77 107 — 112 93 Avg. Burn Rate, kg/hr Com CAT NCAT 1.35 0.86 — 1.64 0.93 1.10 — 0.85 0.82 — 0.77 0.98 #Stoves/# datapoints Com CAT1 NCAT* 11/37 2/9 — 7/27 72/72 5/29 — 9/31 2/7 — 7/27 6/20 Notes: * 1988-1990 catalytic models were all Phase I certified. 1991-92 included 7 Phase I and 2 Phase II catalytics. 1995-96 included 1 Phase I and 6 Phase II catalytics. "All non-catalytic models tested were Phase II Certified. ------- R. Correll, D.R. Jaasma, and Y. Mukkamala are with Virginia Polytechnic Institute and State University, Blacksburg, VA 24061-0238. Robert C. McCrillis is the EPA Project Officer (see below). The complete report, entitled "Field Performance of Woodburning Stoves in Colo- rado During the 1995-96 Heating Season," (Order No. PB98-106487; Cost: $21.50, subject to change) will be available only from: National Technical Information Service 5285 Port Royal Road Springfield, VA 22161 Telephone: 703-487-4650 The EPA Project Officer can be contacted at: Air Pollution Prevention and Control Division National Risk Management Research Laboratory U. S. Environmental Protection Agency Research Triangle Park, NC 27711 United States Environmental Protection Agency Center for Environmental Research Information Cincinnati, OH 45268 Official Business Penalty for Private Use $300 BULK RATE POSTAGE & FEES PAID EPA PERMIT No. G-35 EPA/600/SR-97/112 ------- |