United States
                  Environmental Protection
                  Agency
National Risk Management
Research Laboratory
Cincinnati, OH 45268
                  Research and Development
EPA/600/SR-97/112
November 1997
&EPA      Project  Summary

                  Field  Performance of
                  Woodburning  Stoves in  Colorado
                  During the  1995-96  Heating
                  Season

                  Robert Cornell, Dennis R. Jaasma, and Yagna Mukkamala
                    During the winter of 1995-96, the field
                  performance  of 13  EPA-certified
                  woodburning stoves in Crested  Butte
                  and Curecanti National Park, CO, was
                  evaluated. Measurements included par-
                  ticulate matter (PM), carbon monoxide
                  (CO), and weekly average  burn rates.
                  Six  non-catalytic Phase II  stoves, six
                  catalytic Phase II stoves, and one cata-
                  lytic Phase I stove were monitored. The
                  study adds to the existing database on
                  the field emissions of newer and older
                  certified stoves. Average non-catalytic
                  stove PM and CO emission factors of
                  the study were 9.8 and 93 g/kg, respec-
                  tively. For the catalytic stoves the fac-
                  tors were 22.8 and 112 g/kg, respec-
                  tively. The report compares these val-
                  ues with results from previous studies
                  and suggests reasons that field perfor-
                  mance  is poor relative to what might
                  be expected from certification test re-
                  sults.
                    This Project Summary was developed
                  by the National Risk Management Re-
                  search  Laboratory's Air Pollution Pre-
                  vention Control Division, Research Tri-
                  angle Park, NC, to announce key find-
                  ings of the research project that is fully
                  documented in a separate report of the
                  same title (see Project Report ordering
                  information at back).

                  Objective
                    The purpose of this project was to quan-
                  tify the field performance of EPA-certified
                  woodstoves, both when  stoves are rela-
                  tively new and after stoves have been in
                  service for an appreciable time. One-week
                  averages of PM and CO emissions were
                  measured for a variety of stoves, includ-
                  ing both catalytic and  non-catalytic EPA-
                  certified models. The Virginia Polytechnic
 Institute and State University (VPI) sam-
 pler was used for all measurements, and
 both  PM and CO emissions are reported
 as measured by the sampler.
  The report summarizes the measure-
 ment methods  and the measured emis-
 sion factors. The  emission factors of the
 current study are compared with earlier
 data for PM and CO emissions of certified
 and uncertified  (conventional) stoves.

 Introduction
  Personnel from VPI measured woodstove
 emissions in Crested Butte, CO, during the
 winters of 1988-89, 1989-90, and 1991-
 92. The  1988-89  and 1989-90 measure-
 ments were intended to determine the ef-
 fect of a town-wide changeover from con-
 ventional to EPA-certified (mostly Phase
 I) woodstoves.  The 1991-92 study was
 intended to focus exclusively on Phase II
 stoves, but a limited number of Phase II
 stoves in Crested Butte and reluctance of
 owners to  permit monitoring limited  the
 Phase II data obtained. Both PM  and CO
 emissions were measured  during these
 studies. A fourth  study, in the winter of
 1992-93, involved only CO and carbon
 dioxide (CO2) measurements of  catalytic
 stoves.
  The 1995-96 study obtained additional
 data on the performance of Phase  II stoves
 in  Crested Butte and in Curecanti Na-
 tional Park, located outside of Gunnison,
 CO. The intention was to monitor each
 stove for four weeks to average the ef-
 fects of weekly weather changes and other
 uncontrolled variables, but for some stoves
 fewer than four 1-week averages were
 obtained. Sampling in Crested Butte oc-
 curred from February  5 to March 4, 1996.
 Sampling in Curecanti National  Park oc-
 curred from March 8 to April 13, 1996,

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when warm weather ended the heating
season.
  Thirteen stoves were monitored: seven
catalytic and six non-catalytic. Household
profiles describing each site are  in the full
report. One of the  catalytic stoves was
Phase I certified and all other stoves were
Phase II certified. The full report  also con-
tains a spreadsheet showing all measured
values and calculated emissions data.
  The previous studies created a large
database of emissions from conventional
and Phase I stoves, giving baseline data
for comparison to Phase II  models.  Only
one of the 1995-96 stoves was monitored
in a  previous  study and can be directly
compared with previous  data. However,
over the years, three Crested Butte stoves
have been monitored for PM and CO dur-
ing more than  one season, and their data
can  be  examined  for long term perfor-
mance changes. The 1988-1996  Colorado
work also includes several catalytic stoves
which were monitored for  PM  and  CO
(using the VPI  sampler) during  one sea-
son  and also  had  short-term  (approxi-
mately an hour) monitoring  for  flue gas
temperature and CO and CO2 concentra-
tions under technician-controlled conditions
during the winter of 1992-93. The  1992-
93 CO,  CO2, and temperature  data can
give  a rough estimate of the PM and CO
data that would have been obtained with
the VPI sampler.

Measurement Procedures
  The hardware used  for the measure-
ments is known as  the  "VPI sampler."  It
has been compared to the EPA reference
method for woodstove PM and to the dilu-
tion tunnel method for CO measurement
and has been found to be accurate. The
methods  for sampler preparation and
workup are documented in earlier reports
and are not repeated here.
  Participants used their normal wood sup-
ply. Field personnel weighed a large part
of the  participant's  woodpile  at sampler
deployment, marked  the weighed part  by
replacing the wood on top of a bright red
ribbon, and  weighed any unused  wood
from the pre-weighed supply  at sampler
retrieval. Fuel  moisture  was measured
gravimetrically,  using chips generated  by
low speed drilling of representative logs.

Results
  Forty-seven  deployments resulted  in
useful  data on  stove emissions.  Eight
blanks were also run and were used  to
correct the measured results and give  an
idea of the uncertainties of this  season's
measurements. Blanks were split equally
between Crested Butte and the Curecanti
National Recreation Area.
  Table 1 compares the PM and CO fac-
tors for the  current  study with  those  of
previous studies. The listed values repre-
sent the average factors for all datapoints
for each type of stove in each study. The
average PM catch  of the study was 30.5
mg, and  the  highest level of uncertainty
was 1.6 mg; thus, the average gravimetric
uncertainty is 1.6/30.5, or 5%. As in previ-
ous studies the uncertainty in CO  emis-
sions is estimated to be +/-  10% of re-
ported value.
  The average PM emission factor for the
Phase II catalytic stoves in the 1995-96
study was 22.8 g/kg, approximately equiva-
lent  to that of conventional stoves and
133% greater than the average PM factor
of Phase II non-catalytic stoves. The CO
emission factors for catalytic stoves were
20%  greater than for the non-catalytic
stoves and  effectively the same  as for
conventional  stoves.  The  average  PM
emission factors  for  catalytic stoves in-
creased by 30% from the 1991-92 study.
The  corresponding  CO  factors gained
45%.
  The non-catalytic stoves, on  average,
show no definitive evidence of performance
degradation over the  course of the study.
A strong dependence of emission factors
on burn  rate  has been  noted  for  non-
catalytic stoves, and this dependence prob-
ably  is the cause of the observed year-to-
year fluctuations in average performance
of these stoves.
  Significant physical degradation has
been noted in catalytic stove models over
the course of this study. In some cases
the cause of poor catalytic stove  perfor-
mance has been identified as  mechanical
failures. In  other cases one can only as-
sume that  factors such as operator be-
havior or fuel  variability are involved. In
non-catalytic models, the operation,  fuel-
ing and  design of the stoves (as opposed
to  mechanical  degradation) appear to be
the most  likely determiners  of  emission
performance.
Table 1. Conventional and EPA Certified Woodstove Results
Year of
Study
1988-89
1989-90
1991-92
1995-96
PM Factors, g/kg
Com CAT NCAT
22.1 5.5 —
22.2 11.1 9.9
— 17.6 14.9
— 22.8 9.8
CO Factors, g/kg
Com CAT NCAT
115 40 —
111 52 76
— 77 107
— 112 93
Avg. Burn Rate,
kg/hr
Com CAT NCAT
1.35 0.86 —
1.64 0.93 1.10
— 0.85 0.82
— 0.77 0.98
#Stoves/#
datapoints
Com CAT1 NCAT*
11/37 2/9 —
7/27 72/72 5/29
— 9/31 2/7
— 7/27 6/20
Notes: * 1988-1990 catalytic models were all Phase I certified.
1991-92 included 7 Phase I and 2 Phase II catalytics.
        1995-96 included 1 Phase I and 6 Phase II catalytics.
                 "All non-catalytic models tested were Phase II Certified.

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   R. Correll, D.R. Jaasma, and Y. Mukkamala are with Virginia Polytechnic Institute
     and State University, Blacksburg, VA 24061-0238.
   Robert C. McCrillis is the EPA Project Officer (see below).
   The complete report, entitled "Field Performance of Woodburning Stoves in Colo-
     rado During  the 1995-96 Heating  Season," (Order No. PB98-106487; Cost:
     $21.50, subject to change) will be available only from:
           National Technical Information Service
           5285 Port Royal Road
           Springfield, VA 22161
           Telephone: 703-487-4650
   The EPA Project Officer can be contacted at:
           Air Pollution Prevention and Control Division
           National Risk Management Research Laboratory
           U. S. Environmental Protection Agency
           Research Triangle Park, NC 27711
United States
Environmental Protection Agency
Center for Environmental Research Information
Cincinnati, OH 45268

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EPA/600/SR-97/112

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