&EPA
  United States
  Environmental Protection
  Agency
  Emerging Technologies
  for Wastewater Treatment and
  In-Plant Wet Weather Management


                 EPA 832-R-12-011 • March 2013

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Emerging Technologies
for Waste water Treatment and
In-Plant Wet Weather Management
Prepared for:
Office of Wastewater Management
U.S. Environmental Protection Agency
Washington, D.C.

EPA 832-R-12-011
Under Contract

EP-C-11-009
Prepared by:
Tetra Tech, Inc.
Fairfax, Virginia
SEPA
   United States
   Environmental Protection
   Agency
March 2013

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Emerging Technologies                                                               March 2013
Emerging  Technologies for Wastewater Treatment and In-Plant
Wet Weather Management
EPA832-R-12-011
March 2013
Produced under U.S. EPA Contract No. EP-C-11-009
U.S. EPA Project Manager/ Leader: Jacqueline Rose, Office of Wastewater Management
Prepared by the Tetra Tech Corporation, Fairfax, Virginia
Tetra Tech Project Managers:  Greg Mallon and Sean Scuras

Guidance was contributed by the following panel of EPA, academia, and industry experts:
Bob Bastian, Richard Field, Lauren Fillmore, April Gu, David Kinnear,  Nancy Love, Jim McQuarrie, Dan
Murray, Sudhir Murthy, Amit Pramanick, Eliot Sherman, David Stensel, Rao Surampalli, Anthony Tafuri,
Cindy Wallis-Lage, James Wheeler, and Phil Zahreddine.
Technical Review was provided by professionals with experience in wastewater treatment.  Technical
reviewers of this document were:
Charles Bott, Chief of Special Projects, Hampton Roads Sanitation District, Virginia Beach, Virginia
Glen Daigger, Chief Wastewater Process Engineer, CH2MHNI, Englewood, Colorado
Tyler Richards,  Deputy Director of Engineering and Technical Services, Gwinnnett County Water
Resources, Gwinnett County, Georgia
Electronic copies of this report can be downloaded from the
U.S. EPA Office of Wastewater Management web site at:
http://water.epa.gov/scitech/wastetech/publications.cfm
Cover photos, top to bottom:
Butler Drive Water Reclamation Facility, Peoria, AZ (Arizona Water Infrastructure Finance Authority)
Orange County Water District, Groundwater Replenishment, CA (Tetra Tech)
Ypsilanti Community Utilities Authority Biosolids Incineration System, Ml (Tetra Tech)
Richardson Treatment Plant, sampling influent water, Loma Linda, CA (Tetra Tech)
Background photo: James E. Anderson Reverse Osmosis Water Treatment Plant, Port St. Lucie, FL
(Tetra Tech)
ii                                           Wastewater Treatment and In-Plant Wet Weather Management

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March 2013                                                                 Emerging Technologies
                                   Preface
       The U.S. Environmental Protection Agency (U.S. EPA) is charged by Congress with protecting
       the nation's land, air, and water resources. Under a mandate of environmental laws, the
       Agency strives to formulate and implement actions leading to a balance between human
       activities and the ability of natural systems to support and sustain life. To meet this mandate,
       the Office of Wastewater Management (OWM) provides information and technical support to
       solve environmental problems today and to build a knowledge base necessary to protect public
       health and the environment in the future.

       This publication  has been produced, under contract to the U.S. EPA,  by the Tetra Tech
       Corporation, and it provides current state of development as of the publication date.  It is
       expected that this document will be  revised periodically to reflect advances in this rapidly
       evolving area. The original publication was published in February 2008 with document number
       EPA 832-R-06-006. This publication is the first update and has a new document number, EPA
       832-R-12-011, March 2013. Except as noted, information, interviews, and data development
       were conducted by the contractor. Some of the information, especially related to emerging
       technologies, was provided by the manufacturer or vendor of the equipment or technology, and
       could not be verified or supported by full scale case studies. In some  cases, cost data were
       based on estimated savings without actual field data. When evaluating technologies, estimated
       costs, and stated performance, efforts should be made to collect current and up to date
       information.

       The mention of trade names, specific vendors, or products does not represent an actual or
       presumed endorsement, preference, or acceptance by the U.S. EPA or Federal Government.
       Stated results, conclusions, usage,  or practices do not necessarily  represent the views or
       policies of the U.S. EPA.
Wastewater Treatment and In-Plant Wet Weather Management                                           iii

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Emerging Technologies                                                                      March 2013
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iv                                               Wastewater Treatment and In-Plant Wet Weather Management

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March 2013                                                             Emerging Technologies
                                Contents
Preface	iii
  List of Tables	vii
  List of Figures	vii
  List of Technologies	viii
Overview	O-1
Chapter 1. Introduction and Approach
  1.1 Introduction	1-1
  1.2 Approach	1-2
      1.2.1  Information Collection and New Process Identification	1-2
      1.2.2  Initial Screened Technologies	1-3
      1.2.3  Development of Technology Summary Sheets	1-5
      1.2.4  Evaluation of Technologies	1-21
  1.3 Reference  Document Format and Use	1 -22
  1.4 Chapter References	1-23
Chapter 2. Physical/Chemical Treatment Processes
  2.1 Introduction	2-1
  2.2 Technology Assessment	2-1
Chapter 3. Biological Treatment Processes
  3.1 I ntroduction	3-1
  3.2 Technology Assessment	3-1
Chapter 4. In-Plant Wet Weather Flows Management Processes
  4.1 I ntroduction	4-1
  4.2 Technology Assessment	4-1
Chapter 5. Process Monitoring Technologies
  5.1 I ntroduction	5-1
  5.2 Technology Assessment	5-1
Chapter 6. Energy Conservation Measures
  6.1 I ntroduction	6-1
  6.2 Technology Assessment	6-1

Wastewater Treatment and In-Plant Wet Weather Management                                          v

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Emerging Technologies
  6.3  Chapter References	6-21
Chapter 7. Research Needs
  7.1  I ntroduction	7-1
  7.2  Research Needs	7-1
       7.2.1  Upgrading WWTPs	7-1
       7.2.2 Removal of Nutrients	7-2
       7.2.3 Removal of Other Contaminants	7-3
       7.2.4 Security of Water Systems	7-3
       7.2.5 Energy Conservation and Renewable Energy Sources	7-3
       7.2.6 Wastewater and Solids Treatment Optimization	7-4
  7.3  Chapter References	7-4
Appendix A. Trade Associations	A-1
Appendix B.  List of Acronyms and Abbreviations	 B-1
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                                                                       Emerging Technologies

                                 List of Tables
Table 1.1—Summary of Treatment Technologies Chapter 2 - Physical/Chemical Treatment
          Processes	1-6
Table 1.2—Summary of Treatment Technologies Chapter 3 - Biological Treatment
          Processes	1-10
Table 1.3—Summary of Treatment Technologies Chapter 4 - In-Plant Wet Weather Flows
          Management Processes	1-16
Table 1.4—Summary of Treatment Technologies Chapter 5 - Process Monitoring
          Technologies	1-17
Table 1.5—Summary of Treatment Technologies Chapter 6 - Energy Conservation
          Measures	1-19
Table 1.6—Descriptive Evaluation Criteria	1-21
Table 2.1—Physical/Chemical Treatment Processes - State of Development	2-2
Table 3.1—Biological Treatment Processes - State of Development	3-2
Table 4.1—In-Plant Wet Weather Flows Management Processes - State of Development	4-2
Table 5.1—Process Monitoring Technologies -State of Development	5-2
Table 6.1—Energy Conservation Measures - State of Development	6-3
                                List of Figures
Figure 1.1—Flow Schematic for Document Development	1-2
Figure 2.1—Evaluation of Innovative Physical/Chemical Treatment Technologies	2-5
Figure 3.1—Evaluation of I nnovative Biological Treatment Technologies	3-6
Figure 4.1—Evaluation of Innovative In-Plant Wet Weather Flows Management
          Technologies	4-3
Figure 5.1—Evaluation of Innovative Process Monitoring Technologies	5-3
Wastewater Treatment and In-Plant Wet Weather Management                                          vii

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Emerging Technologies
                                          March 2013
List of Technologies
Process
Blue PRO™ Reactive Media Filtration
Phosphorus Recovery (Struvite or Calcium Phosphate Precipitation)
Compressible Media Filtration (CMF)
Magnetite Ballasted Sedimentation
Multi-stage Filtration
Nanofiltration (NF) and Reverse Osmosis (RO)
Microwave Ultraviolet (UV) Disinfection
Actiflo® Process
DensaDeg® Process
Alternative Disinfectants [Peracetic Acid (PAA) and BCDMH]
Ammonia Recovery
Blue CAT™
Salsnes Filter
Bioaugmentation














Deammonification (Sidestream and Mainstream Deammonification and
Mainstream Nitrite Shunt)
Nitritation and Denitritation (Sidestream)
Deep Shaft Activated Sludge/VERTREAT™
Cyclic Metabolic Environment
Magnetite Ballasted Activated Sludge




Biological-Chemical Phosphorus and Nitrogen Removal (BCFS) Process
Modified University of Cape Town (MUCT) Process
Westbank Process
Modified Anaerobic/Oxic (A/0) Process
Membrane Biofilm Reactor (MBfR)
Vacuum Rotation Membrane (VRM®) System
OpenCel Focused Pulse
Integrated Fixed-film Activated Sludge (IFAS) Systems with Biological
Multi-Stage Activated Biological Process (MSABP™)
Aerobic Granular Sludge Process (AGSP)
Anaerobic Migrating Blanket Reactor (AMBR)






Phosphorus Removal



Type
Innovative
Innovative
Innovative
Innovative
Innovative
Innovative
Adaptive Use
Adaptive Use
Adaptive Use
Emerging
Emerging
Emerging
Emerging
Innovative
Innovative
(Sidestream
Deammonification)
and
Emerging/Research
(Mainstream
Deammonification
and Mainstream
Nitrite Shunt
Innovative
Innovative
Innovative
Innovative
Adaptive Use
Adaptive Use
Adaptive Use
Adaptive Use
Emerging
Emerging
Emerging
Emerging
Emerging
Emerging
Research
Page
2-6
2-8
2-10
2-14
2-16
2-18
2-20
2-22
2-24
2-26
2-29
2-31
2-33
3-7
3-16
3-19
3-22
3-23
3-25
3-27
3-29
3-30
3-31
3-32
3-34
3-35
3-36
3-37
3-38
3-41

VIM
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March 2013
Emerging Technologies
Process
Anaerobic Membrane BioReactor (An-MBR)
Microbial Fuel Cell (MFC)
Compressible Media Filtration (CMF)
Continuous Deflection Separator (CDS)
TRASHMASTER™ Net Capture System
Treatment Shaft
HYDROSELF® Flip Gate Flusher
Tipping Flusher®
Alternative Disinfectants (PAA and BCDMH)
BioActiflo® Process
Fluorescence In Situ Hybridization (FISH) for Filamentous and Nitrifying Bacteria
Microtox®/0nline Microtox®
Nicotinamide Adenine Dinucleotide (NADH) Probes
Online Respirometry
Microwave Density Analyzer
Nutrient Analyzers, Probes, and Electrodes
Biological Micro-Electro-Mechanical Systems (BioMEMS)
Fluorescence In Situ Hybridization (FISH) for Phosphorus Accumulating Organisms (PAOs)
Handheld Advanced Nucleic Acid Analyzer (HANAA)
Immunosensors and Immunoassays
Photo-electro Chemical Oxygen Demand (PeCOD™)
Automated SRT/DO Control
Dual Impeller Aerator (mechanical mixing)
Integrated Air Flow Control
Single-stage Centrifugal Blowers with Inlet Guide Vanes and Variable Diffuser Vanes
Intermittent Mixing
Pulsed Large Bubble Mixing
Pump Control Optimization
Critical Oxygen Point Control
Membrane Air Scour Alternatives
Ultra-fine Bubble Diffusers
Automated Channel Routing for UV Disinfection
Low Pressure High Output Lamps for UV Disinfection
Solar Drying of Sewage Sludge
Type
Research
Research
Innovative
Innovative
Innovative
Innovative
Innovative
Innovative
Emerging
Adaptive Use
Innovative
Innovative
Innovative
Innovative
Innovative
Innovative
Emerging
Emerging
Emerging
Emerging
Emerging
Innovative
Innovative
Innovative
Innovative
Innovative
Innovative
Innovative
Emerging
Emerging
Emerging
Emerging
Emerging
Emerging
Page
3-43
3-45
4-4
4-8
4-10
4-11
4-13
4-15
4-16
4-19
5-4
5-5
5-6
5-7
5-8
5-9
5-12
5-13
5-14
5-15
5-16
6-4
6-5
6-6
6-8
6-10
6-11
6-12
6-13
6-14
6-16
6-18
6-19
6-20

Wastewater Treatment and In-Plant Wet Weather Management
                  IX

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March 2013                                                                 Emerging Technologies
                                  Overview
       In 2008, there were 14,780 municipal wastewater treatment plants operating in the United
       States. These plants ranged in size from a few hundred gallons per day (GPD) to more than
       1440 million gallons per day (MGD). Early efforts in water pollution control began in the late
       1800s with construction of facilities to prevent human waste from reaching drinking water
       supplies. Since the passage of the 1972 Amendments to the Federal Water Pollution Control
       Act (Clean Water Act [CWA]), municipal wastewater treatment facilities have been designed
       and built or upgraded to abate an ever-increasing volume and diversity of pollutants. With few
       exceptions, the CWA requires that municipal wastewater treatment plant discharges meet a
       minimum of secondary treatment. However, in 2008, nearly 37 percent of the municipal
       facilities produced and discharged effluent at higher levels of treatment than the  minimum
       federal standards for secondary treatment. In many cases, this is due to more stringent water
       quality based requirements.

       This document updates the original 2008 publication "Emerging Technologies for Wastewater
       Treatment and In-Plant Wet Weather Management" EPA 832-R-06-006 and provides
       information on four of the five  categories of development regarding emerging wastewater
       treatment and in-plant wet weather management technologies. Information in the form of
       technology fact sheets on established technologies is not included. The five categories are:

           1. Research - Technologies in the development stage and/or have been tested at a
           laboratory or bench scale only.

           2. Emerging - Technologies that have been tested at a pilot or demonstration scale, or
           have been implemented at full scale in 3 or fewer installations or for less than 1 year.

           3. Innovative - Technologies that have been implemented at full scale for less than five
           years, or have some degree of initial use (i.e., implemented in more than three but less
           than 1 percent [150]  of US treatment facilities).

           4. Established - Technologies that have been used at more than 1  percent (150) of US
           treatment facilities or have been available and widely implemented for more than five
           years. (Note: Fact sheets for established technologies are outside the scope of this
           document and, therefore  not included.)

           5. Adaptive Use - Some wastewater treatment processes have been established for
           years, but their use has not been static.  In some cases, an established technology may
           have been modified or adapted resulting in an emerging technology. In other cases, a
           process that was developed to achieve one treatment objective is now being applied in
           different ways or to achieve additional treatment objectives. During the operation of
           treatment systems using these established technologies, engineers, and operators have
           altered and improved their efficiency and performance. This document includes
           established technologies that have undergone recent modifications or are used in new
           applications.
Wastewater Treatment and In-Plant Wet Weather Management                                          O-1

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Emerging Technologies

       This document also provides information on each technology, except for "established", its
       objective, its description, its state of development, available cost information, associated
       contact names, and related data sources. For each technology, this document further
       evaluates technologies against various criteria, although it does not rank or recommend any
       one technology over another. In some cases, the only available information is from the vendor
       or researcher, and has not been independently verified. Research needs are also identified to
       guide development of innovative and emerging technologies and improve established ones.

       Knowledge about technologies tends to evolve. The information provides a snapshot at a point
       in time; what is understood at one point in time may change as more  information develops.
       This includes knowledge about operating mechanisms as well as the relative and absolute
       costs and features of a particular technology. Inquiries into the current state of knowledge are
       an important step when considering implementation of any technology.
O-2                                            Wastewater Treatment and In-Plant Wet Weather Management

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Chapter
 Introduction and Approach
   1.1  Introduction
        In 2008, there were 14,780 municipal wastewater treatment plants operating in the United
        States. These plants ranged in size from a few hundred gallons per day (GPD) to more than
        1440 million gallons per day (MGD). Early efforts in water pollution control began in the late
        1800s with construction of facilities to prevent human waste from reaching drinking water
        supplies. Since the passage of the 1972 Amendments to the Federal Water Pollution Control
        Act (known as the Clean Water Act [CWA]), municipal wastewater treatment facilities have
        been designed and built or upgraded to abate an ever-increasing volume and diversity of
        pollutants. The CWA requires that municipal wastewater treatment plant discharges meet a
        minimum of secondary treatment. However, in 2008, nearly 37 percent of the municipal
        facilities produced and discharged effluent at higher levels of treatment than the  minimum
        federal standards for secondary treatment.

        To meet the challenge of keeping progress in wastewater pollution abatement ahead of
        population growth, changes in industrial processes, and technological developments, EPA is
        providing this document to make information available on recent advances and innovative
        techniques. This document updates  the original 2008 publication "Emerging Technologies for
        Wastewater Treatment and In-Plant  Wet Weather Management" EPA 832-R-06-006.

        The goal of this document is straight forward—to provide a guide for persons seeking
        information on innovative and emerging wastewater treatment technologies. The guide lists
        new technologies, assesses their merits and costs, and provides sources for further
        technological investigation. This document is intended to serve as a tool for wastewater facility
        owners/utilities, operators, planners, and consultants.

        New technologies typically follow a development process that leads from laboratory and  bench-
        scale investigations to pilot studies, and to initiate use or "full-scale demonstrations" before the
        technology is considered established. Not all technologies survive the entire development
        process. Some fail in the laboratory or at pilot stages; others see limited application in the field,
        but poor performance, complications, or unexpected costs may cause them  to lose favor. Even
        technologies that become established may lose favor in time, as technological advances lead
        to obsolescence.  In short, technologies  are subject to the same evolutionary forces present in
        nature; those that cannot meet the demands of their environment fail, while those that adapt to
        changing technological, economic and regulatory climates can achieve long-standing success
        and survival in the market.

        Some wastewater treatment processes  have been established for many years, but that does
        not mean that they are static. During the operation of treatment systems using these
        established technologies, engineers and operators  have altered and improved efficiency  and
        performance. In other cases, established technologies applied to one aspect of treatment have
 Wastewater Treatment and In-Plant Wet Weather Management
1-1

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Emerging Technologies
                                      March 2013
        been modified so that they can perform different objectives. Often, better performance can be
        achieved by linking established processes in innovative ways. This document includes
        established technologies that have undergone recent modifications or are used in new
        applications (adaptive use). These technologies are evaluated in the chapters alongside the
        innovative, emerging, and research technologies.
  1.2 Approach
       To develop this reference document, the investigators sought information from a variety of
       sources, identified new technologies, prepared cost summaries, where information was
       available, for all technologies, and evaluated technologies deemed to be innovative. This
       method is described below and in Figure 1-1.
                    Collect Information
                     Identify Process
                                    Established
                                                        No Further Action
                           Innovative, Emerging or Research
                                                              Has Innovative
                                                              Modifications
                     Prepare Process
                     Summary Sheets
                                   Emerging or Research
                        Screen    >         	No Further Action
                            Innovative
                     Prepare Process
                     Evaluation Matrix
                                                                   74S043_WWT-01..ai
                   Figure 1.1—Flow Schematic for Document Development
1.2.1  Information Collection and New Process  Identification
        The collection of information and identification of new technology provided the foundation for
        subsequent work. To identify new treatment process technologies, investigators gathered
        information and focused on relevant Water Environment Federation (WEF) and American
1-2
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                                                                          Emerging Technologies

       Society of Civil Engineers (ASCE) conference proceedings, as well as monthly publications
       from these and other organizations such as International Water Association (IWA).

       "Gray" Literature - Vendor-supplied information, Internet research, and consultants'
       technical reports comprise the information collected in this category.

       Expert Panel - A panel of industry experts including those from technical associations,
       consulting practice, utilities,  and academia was organized to identify emerging wastewater
       treatment technologies.

       Technologies identified through search of the above sources were screened to determine their
       classification as described below.


1.2.2 Initial  Screened Technologies

       This project focuses on emerging technologies that appear to  be viable, but have not yet been
       accepted as established processes in the United States. Specific screening criteria used to
       define the state of development for processes are described in the following paragraphs. This
       screening resulted in:
           •   3 research technologies

           •   22 emerging technologies

           •   31 innovative technologies

           •   7 adaptive use technologies

       Research - These technologies are in the development stage and/or have been tested at
       laboratory or bench scale. New technologies that have reached the demonstration stage
       overseas, but cannot yet be considered to be established there, are also considered to be
       research technologies with respect to North American applications.

       Emerging - Technologies that have been tested  at a pilot or demonstration scale, or have
       been implemented at full scale in 3 or fewer installations or for less than 1 year.

       Innovative - Technologies that meet one of the following criteria were classified as
       innovative:
           •   They have been tested as a full-scale demonstration.

           •   They have been available and implemented in the United States for less than five
              years.
           •   They have some degree of initial use (i.e., implemented in less than 1 percent  of
              municipalities (150) throughout the  United States).

           •   They are established technologies from overseas.

       Established - In most cases, these processes are used at more than 1 percent of full-scale
       facilities (150) in North America; but there are some exceptions based upon specific
       considerations. The established category may include technologies that are widely used
       although introduced more recently in North America.  Due to the extensive number of
       established technologies and variations in each technology, established technologies  are only
       listed in this report. None are described in depth in this document and Technology Summary
       Sheets are not provided for established technologies.

Waste water Treatment and In-Plant Wet Weather Management                                           1-3

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Emerging Technologies

       Adaptive Use - In some cases, an established technology such as the UCT (University of
       Cape Town) process may have been modified or adapted, resulting in an emerging technology
       such as the Modified UCT. In other cases, a process like Actiflo® was developed to remove
       solids from wet weather flows but is now also being used to polish final effluent.

       The focus of this document is on Innovative Technologies along with preliminary information on
       Emerging and Research Technologies. Early in the development process (the laboratory stage
       or few full scale installations), data are usually insufficient to prove or disprove general
       technology viability at full scale. Available information on these Emerging or Research
       technologies is presented in this document. Technologies on the other end of the
       developmental scale, those defined  as Established in North America, are excluded from the
       detailed assessments on the assumption that they are proven,  although still relatively new.

       The differentiation between technologies established in Europe or Asia and those that have
       reached similar status in the United  States can be  critical since technologies that have been
       applied successfully in other countries have not always flourished here in the United States.
       Because the viability of imported technologies is not guaranteed, established processes from
       overseas are classified  as innovative technologies for this project, unless they are proven in
       North American applications.

       Some technologies fall  into a "gray area" between  the Research and Innovative categories.
       Technologies that fall into this category are incorporated into the Emerging category. The
       screening assessment is summarized by chapter in Tables  1.1  through 1.5.
           •   Table 1.1 summarizes the treatment technologies for Chapter 2 - Physical/Chemical
              Treatment Processes.

           •   Table 1.2 summarizes the treatment technologies for Chapter 3 - Biological Treatment
              Processes.

           •   Table 1.3 summarizes the treatment technologies for Chapter 4 - In-Plant Wet Weather
              Management Processes.
           •   Table 1.4 summarizes the treatment technologies for Chapter 5 - Process Monitoring
              Technologies.
           •   Table 1.5 summarizes the treatment technologies for Chapter 6 - Energy Conservation
              Measures.

       All the cost estimates provided in this document contain a certain degree of expert judgment or
       educated analysis concerning the various cost elements that comprise the estimates. This is
       true when cost estimates are based on limited or no information where in some  cases little
       more than process type, location, and plant capacity are known. Therefore, cost estimates are
       at best order-of-magnitude level  per American Association of Cost Engineers (AACE)
       International classification. However, numerous peripheral factors could also interfere with the
       accuracy of the order-of-magnitude  level cost estimates. Considering these facts, the reader
       should keep in mind that site-specific applications and local requirements should be considered
       to increase the accuracy of cost estimates provided in this document.

       Knowledge about technologies tends to evolve. The information provides a snapshot at a point
       in time; what is understood at one point in time may change as more information develops.
       This includes knowledge about operating mechanisms as well as the relative and absolute
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                                                                        Emerging Technologies

       costs and features of a particular technology. Inquiries into the current state of knowledge are
       an important step when considering implementation of any technology.


1.2.3 Development of Technology Summary  Sheets

       Technologies categorized as research, emerging, innovative, or adaptive use are each
       summarized on an individual Technology Summary sheet. Each process generally includes the
       following information:
       Objective - Description of the goal of the technology.

       State of Development - Where and how the technology has been applied (i.e., resulting in
       being  placed in the corresponding category: research; emerging; innovative; or adaptive use).

       Description - A brief overview of the technology.

       Comparison to Established Technologies - Advantages and disadvantages of
       innovative, emerging, and research technologies are compared to more commonly used
       technologies.

       Available Cost Information -Approximate range of capital and operations and
       maintenance costs, and assumptions made in developing them (when reliable information was
       available).

       Vendors  Name(s) - Name, address, telephone numbers, web address, and other contact
       information for equipment manufacturers and suppliers.

       Installation(s) - Name, address, telephone numbers, and other contact information for
       utilities and facilities where the technology has been used (full or pilot scale).

       Key Words for Internet Search - Because this document is not intended to provide a
       comprehensive list of vendors for these technologies, key words have been added to aid the
       reader in finding additional vendors and current  product information on the Internet.

       Data Sources - References used to compile  the technology summary. Specific citations to
       data sources are  provided as appropriate within the individual technology summary sheets that
       were prepared for this update (noted at the top of the sheet as "prepared 2012"). Data not cited
       should be assumed to be provided by the technology vendor. Technology summaries labeled
       as "updated 2012" or "prepared 2008" include data from the listed sources but it  may not be
       cited within the text.
Waste water Treatment and In-Plant Wet Weather Management                                          1-5

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Emerging Technologies
                                      March 2013
                     Table 1.1—Summary of Treatment Technologies
                       Chapter 2 - Physical/Chemical Treatment Processes
Established Technologies (technology summaries not included)
Adsorption
Activated Alumina Media
Granular-Activated Carbon (GAC)
Granular Iron Based Media
Powdered Activated Carbon (PAC)





•
•
•





•



•

•
•















Disinfection
Ozone
Chlorine/Chlorine Dioxide/Liquid
Chlorine/Dechlorination
Halogens (Bromine)
Ultraviolet (UV) Disinfection
























•
•
•
•








Flocculation
Nutrient Removal
Air Stripping
Chemically Enhanced Primary Treatment
Denitrification Filters
Ion-Exchange
Chemical Precipitation*
- Alum Addition
- Iron Salts Addition
- Zeolite
Solids Contact Clarifier for P Removal










•
•


•
•

•
•


•




•


•







•
•


•
•
•
•
•


•
































Oxidation
Chemical Oxidation
- Chlorine/Hypochlorite/Chlorine Dioxide
- Hydrogen Peroxide



























1-6
Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
Emerging Technologies
                     Table 1.1—Summary of Treatment Technologies
                 Chapter 2 - Physical/Chemical Treatment Processes (continued)
- Hydroxyl Radical
- Oxygen (Atomic and Molecular)
- Ozone
Advanced Oxidation Processes
- Catalytic Oxidation
- Fenton's Reagent (H202 + Ferrous Ion)
- Photo Catalysis (UV + Ti02)
- Supercritical Water Oxidation








































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Preliminary/Primary Treatment
Advanced Grit Removal System (AGRS)
- HEADCELL™
- GRITKINQTM
- PISTAGRITTM
- HYDROGRIT™
Grit Removal
- Traveling Bridge
Screening
- Fine Screening
- Micro Screening
- Rotary Screening
- Step Screening
- Microsieves
Solids Removal
Dissolved Air Flotation (DAF)
Treatment/Settling
Filtration through Media
- Automatic Backwash Filters (ABW®)
- Cloth Media
o Disc Filter (DF)































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Wastewater Treatment and In-Plant Wet Weather Management
               1-7

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Emerging Technologies
                                      March 2013
                     Table 1.1—Summary of Treatment Technologies
                 Chapter 2 - Physical/Chemical Treatment Processes (continued)
o Drum Filter
o Diamond-Shaped Filters
- Pulsed Bed Filter
- Silica Media (One- and Two-Stage)
o Conventional Downflow
o Deep- Bed Downflow Filters
o Deep-Bed Upflow Continuous
Backwash Filters
Filtration through Membranes
- Electrodialysis
- Microfiltration
- Ultrafiltration
Innovative Technologies
Summary
on page











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Nutrient Removal
Blue PRO™ Reactive Media
Filtration
Phosphorus Recovery (Struvite or
Calcium Phosphate Precipitation)
2-6
2-8


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Solids Removal
Compressible Media Filtration (CMF)
Magnetite Ballasted Sedimentation
Multi-stage Filtration
Nanofiltration and Reverse Osmosis
Adaptive Use Technologies
2-10
2-14
2-16
2-18
Summary
on Page
•



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Disinfection
Microwave Ultraviolet (UV)
Disinfection
2-20









Solids Removal
Ballasted High Rate Clarification










1-8
Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
Emerging Technologies
                     Table 1.1—Summary of Treatment Technologies
                 Chapter 2 - Physical/Chemical Treatment Processes (continued)
(BHRC) Processes
- Actiflo® Process
- Densadeg® Process
Emerging Technologies

2-22
2-24
Summary
on page




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Disinfection
Alternative Disinfectants
- PAA - Peracetic acid
- BCDMH
2-26





















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Nutrient Removal
Ammonia Recovery Analyzer
2-29





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Oxidation
Blue CAT™
2-31

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Preliminary/Primary Treatment
Salsnes Filter
2-33
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Research Technologies
None at this time










Wastewater Treatment and In-Plant Wet Weather Management
               1-9

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Emerging Technologies
                                       March 2013
                      Table 1.2—Summary of Treatment Technologies
                           Chapter 3 - Biological Treatment Processes
Established Technologies (technology summaries not included)
Anaerobic Processes
Anaerobic Attached Growth System
- Upflow Packed-Bed Attached Growth Reactor
- Upflow Attached Growth Anaerobic
- Expanded-Bed Reactor (Anaerobic Expanded
Bed Reactor [AEBR])
- Downflow Attached Growth Process
Anaerobic Contact Process
- Anaerobic Sequencing Batch Reactor (ASBR)
- Upflow Anaerobic Sludge Blanket (UASB)
- ANaerobic FLuidized Bed Reactor (ANFLOW)

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BOD Removal and Nitrification
Biolac-Aerated Lagoon
Complete Mix-Activated Sludge (CMAS) Process
Contact Stabilization
Conventional Extended Aeration
Countercurrent Aeration System (CCAS™)
Cyclic Activated Sludge System (CASS™)
Facultative and Aerated Lagoons
High-Purity Oxygen (HPO)
Intermittent Cycle Extended Aeration System (ICEAS™)
Kraus Process
Oxidation Ditch/Aerated Lagoons
Sequencing Batch Reactor (SBR)
Staged Activated-Sludge Process
Step Feed
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1-10
Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
Emerging Technologies
                      Table 1.2—Summary of Treatment Technologies
                      Chapter 3 - Biological Treatment Processes (continued)
Technology and Advancements § o i£E:cE~gS'E |j '£, '= "§
„ . . . . „ , i -E — o> a) a) o tl «5 a> •— -= ° •=
(Listed in process flow sequence) o o. ZQ:OQ:C/)C,I-Q: Q o. ^ CD
Biofilm Processes
Biological Aerated Filters (BAF)
- Biofor®
- Biostyr®
Fluidized Bed Bioreactor (FBBR)
Integrated fixed-Film Activated Sludge (IFAS)
- IFAS -Submerged Mobile Media
- IFAS -Submerged Fixed Media
Moving-Bed Bio Reactor (MBBR) Process
Rotating Biological Contactor (RBC)
Submerged Rotating Biological Contactor (SRBC)
Trickling Filter (TF)
Trickling Filter/Solids Contactor (TF/SC)

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Nitrogen Removal
Bardenpho® (Four Stage)
Biodenitro™
Denitrification Filter
Ludzack-Ettinger
Modified Ludzack-Ettinger (MLE)
Orbal™ Process
Schreiber™ Process
Simultaneous Nitrification denitrificatioN (SNdN)
Process
Step Feed (Alternating Anoxic and Aerobic)
Wuhrman
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Nitrogen and Phosphorus Removal
Anaerobic/Anoxic/Oxic (A2/0)
Bardenpho® (Five Stage)
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Wastewater Treatment and In-Plant Wet Weather Management
              1-11

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Emerging Technologies
                                       March 2013
                      Table 1.2—Summary of Treatment Technologies
                      Chapter 3 - Biological Treatment Processes (continued)
• a Q. °o'coWw"So •*= ° .8 _E:
Technology and Advancements § 8 £ E 'E E ^ 2 S> E -| '& = «
„ . . . . ,. , i -c — o> o> o> o tl «5 a> •— -= ° •=
(Listed in process flow sequence) o o. ZQ:OQ:C/)C,I-Q: Q Q.S CQ
Johannesburg Process
Step Feed BNR Process
University of Cape Town (UCT)
Virginia Initiative Plant (VIP)
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Phosphorus Removal
Phoredox (Anaerobic/Oxic [A/0])
Phostrip
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Membrane Processes
Membrane Bioreactor (MBR)
- Tubular
- Hollow-Fiber
- Spiral Wound
- Plate and Frame
- Pleated Cartridge Filters
Innovative Technologies
Summary
on page

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Bioaugmentation
Bioaugmentation
- External Bioaugmentation
- Seeding from Commercial Sources
of Nitrifiers
o In-Pipe Technology
o Trickling Filter and Pushed
Activated Sludge (TF/PAS)
Process
o Seeding from External
Dispensed Growth Reactors
Treating Reject Waters
(Chemostat Type)
o In-Nitri® Process
3-7







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1-12
Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
Emerging Technologies
                      Table 1.2—Summary of Treatment Technologies
                      Chapter 3 - Biological Treatment Processes (continued)
Technology and Advancements § o i£E:cE~gS'E |j '£, '= "§
„ . . . . „ , i -E — o> a) a) o tl «5 a> •— -= ° •=
(Listed in process flow sequence) o o. ZQ:OQ:C/)C,I-Q: Q o. ^ CD
o Immobilized Cell-Augmented
Activated Sludge (ICASS)
Process
o Seeding from Parallel
Processes
o Seeding from Downstream
Process
- In Situ Bioaugmentation
o DE-nitrification and Phosphate
accumulation in ANOXic
(DEPHANOX) Process
o Bio-Augmentation
Regeneration/Reaeration
(BAR) Process
o Bio-Augmentation Batch
Enhanced (BABE) Process
o Aeration Tank 3 (ATS) Process
o Main stream AUtotrophic
Recycle Enabling Enhanced
N-removal (MAUREEN)
Process
o Regeneration DeNitrification
(R-DN) Process
o Centrate and RAS Reaeration
Basin (CaRRB) Process











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Nitrogen Removal
Deammonification (Sidestream)
Nitritation and Denitritation (Sidestream)
3-16
3-19
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Deep-Shaft Activated Sludge/
VERTREAT™
3-22
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Wastewater Treatment and In-Plant Wet Weather Management
              1-13

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Emerging Technologies
                                       March 2013
                      Table 1.2—Summary of Treatment Technologies
                      Chapter 3 - Biological Treatment Processes (continued)
Solids Minimization
Cyclic Metabolic Environment
3-23
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Solids Settleability
Magnetite Ballasted Activated Sludge
Adaptive Use Technologies
Nitrogen and Phosphorus Removal
Biological-Chemical Phosphorus and
Nitrogen Removal (BCFS) Process
Modified University of Cape Town (MUCT)
Process
Westbank Process
3-25
Summary
on page

3-27
3-29
3-30
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Phosphorus Removal
Modified Anaerobic/Oxic (A/0) Process
Emerging Technologies
3-31
Summary
on page
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Membrane Processes
Membrane Biofilm Reactor (MBfR)
Vacuum Rotation Membrane (VRM®)
System
3-32
3-34
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OpenCel Focused Pulse
3-35



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Integrated Fixed-film Activated Sludge
(I FAS) with Biological Phosphorus
Removal
3-36
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Solids Minimization
Multi-Stage Activated Biological Process
(MSABP™)
3-37
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Aerobic Granular Sludge Process (AGSP)
3-38
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1-14
Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
                                            Emerging Technologies
                        Table 1.2—Summary of Treatment Technologies
                        Chapter 3 - Biological Treatment Processes (continued)
Research Technologies
Anaerobic Processes
    Anaerobic Migrating Blanket Reactor
    (AMBR®)
3-41
    Anaerobic Membrane BioReactor
    (An-MBR)
3-43
Electricity Generation
    Microbial Fuel Cell (MFC) Based
    Treatment System
3-45
Wastewater Treatment and In-Plant Wet Weather Management
                                                            1-15

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Emerging Technologies
                                      March 2013
                     Table 1.3—Summary of Treatment Technologies
                    Chapter 4 - In-Plant Wet Weather Management Processes
Established Technologies (technology summaries not included)
Treatment
Dispersed Air Flotation
Dissolved Air Flotation (DAF)
Enhanced Clarification/High Rate Clarification (HRC)
Ballasted Flocculation (Actiflo® and Microsep®)
Lamella Plate Settlers
Screening
Vortex Separation
Innovative Technologies
Summary
on page







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Treatment
Compressible Media Filtration (CMF)
Continuous Deflection Separator (CDS)
TRASHMASTER™ Net Capture System
Treatment Shaft
4-4
4-8
4-10
4-11




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Storage
HYDROSELF® Flushing Gate
Tipping Flusher®
4-13
4-15








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Adaptive Use Technologies
BioActiflo Process
Emerging Technologies
4-19
Summary
on page
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Treatment
Alternative Disinfectants (PAA; BCDMH)
Research Technologies
None at this time
4-16




















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1-16
Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
Emerging Technologies
                      Table 1.4—Summary of Treatment Technologies
                          Chapter 5 - Process Monitoring Technologies
Established Technologies (technology summaries not included)
Microbial Activity
Dissolved Oxygen Analyzer
Oxidation Reduction Potential (ORP) Probe
Solids Retention Time (SRT) Controller
























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Sludge Blanket Level Detector
Total Suspended Solids Analyzer














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Online Ck Residual
pH Probes
Innovative Technologies
Summary
on page














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Microbial Activity
Fluorescence In Situ Hybridization (FISH)
for Filamentous and Nitrifying Bacteria
Microtox®/0nline Microtox®
Nicotinamide Adenine Dinucleotide (NADH)
Probes
Online Respirometry
5-4
5-5
5-6
5-7
































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5-8







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Nutrient Analyzers, Probes, and Electrodes
5-9







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None at this time










Wastewater Treatment and In-Plant Wet Weather Management
              1-17

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Emerging Technologies
                                      March 2013
                       Table 1.4—Summary of Treatment Technologies
                      Chapter 5 - Process Monitoring Technologies (continued)
Emerging Technologies
Summary
on page

Microbial Activity
Biological Micro-Electro-Mechanical
Systems (BioMEMS)
FISH for Phosphorus Accumulating
Organisms (PAOs)
Handheld Advanced Nucleic Acid Analyzer
(HANAA)
Immunosensors and Immunoassays
5-12
5-13
5-14
5-15
































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Photo-electro Chemical Oxygen Demand
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Research Technologies
None at this time
5-16








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1-18
Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
Emerging Technologies
                     Table 1.5—Summary of Treatment Technologies
                           Chapter 6 - Energy Conservation Measures
Established Technologies (technology summaries not included)
Aeration
Adjustment of Submergence of Mechanical Aerators
Bioprocess Intelligent Optimization System (BIOS)
Cycling Mechanical Aerators On and Off
Fine-Pore Aeration Diffusers
High Speed (Gearless) Turbo Blowers





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Hyperbolic Mixers


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NEMA Premium® efficiency motors
Variable Frequency Drives (VFDs)
Other Processes
Incineration Heat Recovery [Applications: N/A]
Innovative Technologies
Summary
on page
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Aeration
Automated SRT/DO Control
Dual Impeller Aerator (mechanical mixing)
Integrated Air Flow Control
Single-stage Centrifugal Blowers with Inlet
Guide Vanes and Variable Diffuser Vanes
6-4
6-4
6-6
6-8




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Pulsed Large Bubble Mixing
6-10
6-11




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Pump Control Optimization
6-12
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Adaptive Use Technologies
None at this time










Wastewater Treatment and In-Plant Wet Weather Management
              1-19

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Emerging Technologies
                                                        March 2013
                         Table 1.5—Summary of Treatment Technologies
                         Chapter 6 - Energy Conservation Measures (continued)
Emerging Technologies
Aeration
    Critical Oxygen Point Control
6-13
    Membrane Air Scour Alternatives
6-14
    Ultra-fine Bubble Diffusers
6-16
Disinfection
    Automated Channel Routing for UV
    Disinfection
6-18
    Low Pressure High Output Lamps for UV
    Disinfection
6-19
Other Processes
    Solar Drying of Sewage Sludge
6-20
Research Technologies
    None at this time
1-20
             Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
Emerging Technologies
1.2.4 Evaluation of Technologies

       Technologies defined as innovative in the initial screening were subjected to a detailed
       evaluation. Each technology was evaluated with respect to the descriptive and comparative
       criteria described below. Descriptive criteria include:
           •   State of Development - Describes the stage of development for each technology,
              ranging from bench scale development to full-scale operations.

           •   Applicability - Qualitatively assesses in which market the technology is designed to
              be used.

           •   Effluent Reuse - Describes the reuse of treated effluent as specifically direct,
              indirect, potable and/or nonpotable.

           •   Benefits - Considers the potential benefits gained (e.g., capital or operational
              savings) from implementation of the technology.
       Designations for each  descriptive criterion are presented in Table 1.6.

                         Table  1.6—Descriptive Evaluation Criteria
Criterion Designation Description
State of Development
Applicability
Effluent Reuse
Potential Benefits
B
P
I
M
0
N
I
F
S
L
Dp
Dn
IP
In
C
I
0
S
W
E
Bench scale
Pilot scale
Full-scale industrial applications
Full-scale municipal applications
Full-scale operations overseas
Full-scale operations in North America
Industrywide
Few plants
Primarily small plants
Primarily large plants
Direct potable
Direct nonpotable
Indirect potable
Indirect nonpotable
Capital savings
Intense operational demand
Operational/Maintenance savings
Shock load capacity
Wet weather load capacity
Effluent quality
Wastewater Treatment and In-Plant Wet Weather Management
              1-21

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Emerging Technologies
                                     March 2013
       Comparative criteria include:
           •   Impact on Existing Facilities or Other Processes - Describes whether or not
              the technology requires the involvement of extensive design changes, and the degree
              to which the existing facilities will be disturbed.
           •   Complexity - Considers the installation, startup, and shutdown methods for the
              technology.

       Air/Odor Emissions - Considers if the process has impacts on air and odor emissions for
       the facility.

           •   Energy - Considers the amount of energy required to adequately maintain the process
              and if any energy saving is possible.
           •   Footprint - Considers how the footprint helps to identify the land needed to expand a
              facility for increased capacity.

           •   Retrofitting - Considers if the process can be used to modify old treatment plants
              without extensive reconstruction.

       The above criteria compared individual technologies with other technologies in the same
       category, and were scored positive, neutral/mixed, or negative.

       The criteria and ratings were applied to each innovative technology and the results are
       presented in matrix format. Where available information was insufficient to rate a technology for
       a criterion, no rating is given. The project team and reviewers assessed each technology based
       on the limited information gathered and their collective judgment, experience, and opinions.
       Results of the evaluation are presented in  subsequent chapters.
  1.3  Reference Document Format and Use
       The remainder of the reference document is divided into chapters based upon general
       technologies, one chapter is dedicated to each of the following categories:
           •   Chapter 2 - Physical/Chemical Treatment Processes

           •   Chapter 3 - Biological Treatment Processes

           •   Chapter 4 - In-Plant Wet Weather  Flows Management Processes

           •   Chapter 5 - Process Monitoring Technologies

           •   Chapter 6 - Energy Conservation Measures

           •   Chapter 7 - Research Needs

       Where appropriate to more than one category, a single technology may be included in more
       than one chapter; for example, the Alternative Disinfectants (PAA; BCDMH) technology fact
       sheet appears in both Chapter 2 and Chapter 4. Each chapter provides an overview of the
       appropriate technologies, discusses the state of development for each,  presents an evaluation
       matrix for innovative technologies, and concludes with a Technology Summary Sheet for each
       research, emerging, innovative, and adaptive use technology included in that chapter.

       The technology summaries and evaluation matrices are the cornerstones of each chapter,
       providing a broad overview of the innovative technologies. Neither the summaries nor the
1-22
Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
Emerging Technologies
       matrices should be considered definitive technology assessments. Rather, they should be
       considered stepping stones to more detailed investigations.

       Appendix A contains applicable trade associations.

       Appendix B contains a list of acronyms and abbreviations.

       This document will be updated from time to time. Technologies were reviewed in late 2011  to
       early 2012.
  1.4  Chapter References
  Hunter, P. and Lewis, S., Top Ten Biggest Wastewater Treatment Plants, Engineering News Record,
       April 2, 2012.

  U.S. EPA, Clean Watershed Needs Survey 2008 Report to Congress, EPA 832-R-10-002, Office of
       Water, 2010.
Wastewater Treatment and In-Plant Wet Weather Management
              1-23

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 Chapter
Physical/Chemical Treatment  Processes
  2.1  Introduction
       For the purpose of this report, physical and chemical treatment processes are defined as
       treatment technologies that do not include any biomass in the process to achieve the treatment
       objective. Physical processes remove solids from wastewater as it flows through screens or
       filter media, or solids are removed by gravity settling or air flotation. Particles entrapped with air
       float to the surface and can be removed. Chemicals are used in wastewater treatment to create
       changes in the pollutants that increase the ability to remove them. Changes may include
       forming floe or a heavier particle mass to improve removal by physical processes. As a result,
       chemical addition and physical processes are usually employed together to provide treatment.
       This chapter focuses on advances in basic physical and chemical treatment processes.
  2.2  Technology Assessment
       A summary of established, innovative, emerging, and adaptive use technologies (there are no
       research technologies in this chapter) for physical and/or chemical treatment processes is
       provided in Table 2.1. A comparative evaluation among innovative technologies is provided in
       Figure 2.1. Most of the physical chemical processes are established, and they are very
       essential unit processes that are widely used in various applications in wastewater treatment.

       Innovative development in physical and chemical technologies includes BluePRO™ reactive
       media filtration, phosphorus recovery (struvite or calcium phosphate precipitation),
       compressible media filtration, magnetite ballasted sedimentation, multi-stage filtration, and
       nanofiltration and reverse osmosis. These technologies focus on the separation of liquids and
       solids and phosphorus (which is removed as a solid). Advanced solids separation is critical as
       a preliminary process step and as an advanced treatment step to reduce suspended solids,
       plus nutrients and other compounds, in the effluent. The application of these technologies has
       promoted the reuse of wastewater by providing a very high-quality effluent.

       This chapter also discusses some of the adaptive uses or unique applications of already
       established technologies. For example, microwave ultraviolet disinfection is an adaptation of
       UV disinfection that can reduce energy consumption and increase lamp life. The Ballasted High
       Rate Clarification (BHRC) processes use a high-rate chemical/physical clarification process
       that involves the formation of suspended solids onto a ballast particle with the aid of a
       coagulant and polymer. The BHRC process includes the patented Actiflo® and  DensaDeg®
       processes. Emerging technologies include alternative disinfectants like peracetic acid (PAA),
       ammonia recovery processes including vacuum distillation, BlueCAT™ adsorption filtration
       which the vendor indicates can be used for removal of microconstituents, with advanced
       oxidation and the Salsnes filter for primary treatment. These technologies are discussed in the
       technology summaries in this chapter.
Wastewater Treatment and In-Plant Wet Weather Management
2-1

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Emerging Technologies
                                           March 2013
         Knowledge about technologies tends to evolve. The information provides a snapshot at a point
         in time; what is understood at one point in time may change as more information develops.
         This includes knowledge about operating mechanisms as well as the relative and absolute
         costs and features of a particular technology. Inquiries into the current state of knowledge are
         an important step when considering implementation of any technology.
                       Table 2.1—Physical/Chemical Treatment Processes
                                         State of Development
            Established Technologies (technology summaries not included)
            Adsorption
               Activated Alumina Media
               Granular-Activated Carbon (GAC)
               Granular Iron Based Media
               Powdered Activated Carbon (PAC)
            Disinfection
               Ozone
               Chlorine/Chlorine Dioxide/Liquid Chlorine/Dechlorination
               Halogens (Bromine)
               Ultraviolet (UV) Disinfection
            Flocculation
            Nutrient Removal
               Air Stripping
               Chemically Enhanced Primary Treatment
               Denitrification Filters
               Ion-Exchange
               Chemical Precipitation*
                   -   Alum Addition
                   -   Iron Salts Addition
                   -   Zeolite
               Solids Contact Clarifier for P Removal
            Oxidation
               Chemical Oxidation
                   -   Chlorine/Hypochlorite/Chlorine Dioxide
                   -   Hydrogen Peroxide
                   -   Hydroxyl Radical
                   -   Oxygen (Atomic and Molecular)
                   -   Ozone
               Advanced Oxidation Processes
                   -   Catalytic Oxidation
                   -   Fenton's Reagent (H202 + Ferrous Ion)
                   -   Photo Catalysis (UV + Ti02)
                   -   Supercritical Water Oxidation
2-2
Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
Emerging Technologies

Table 2.1 — Physical/Chemical Treatment Processes
State of Development
-
Established Technologies (technology summaries not included) (continued)
Preliminary/Primary Treatment
Advanced Grit Removal System (AGRS)
- HEADCELLTM
- GRITKING™
- PISTAGRIT™
- HYDROGRIT™
Grit Removal
- Traveling Bridge
Screening
- Fine Screening
- Micro Screening
- Rotary Screening
- Step Screening
- Microsieves
Solids Removal
Dissolved Air Flotation (DAF) Treatment/Settling
Filtration through Media
- Automatic Backwash Filters (ABW®)
- Cloth Media
o Disc Filter (DF)
o Drum Filter
o Diamond-Shaped Filters
- Pulsed Bed Filter
- Silica Media (One- and Two-Stage)
o Conventional Downflow
o Deep-Bed Downflow Filters
o Deep-Bed Upflow Continuous Backwash Filters
Filtration through Membranes
- Electodialysis
- Microfiltration
- Ultrafiltration
Innovative Technologies
Nutrient Removal
Blue PRO™ Reactive Media Filtration
Phosphorus Recovery (Struvite or Calcium Phosphate Precipitation)
Solids Removal
Compressible Media Filtration (CMF)
Magnetite Ballasted Sedimentation
Multi-stage Filtration
Nanofiltration and Reverse Osmosis

Summary on
page

2-6
2-8

2-10
2-14
2-16
2-18


Wastewater Treatment and In-Plant Wet Weather Management
                 2-3

-------
Emerging Technologies
                                     March 2013
                    Table 2.1—Physical/Chemical Treatment Processes -
                                    State of Development
Adaptive Use Technologies
Summary on
page
Disinfection
Microwave Ultraviolet (UV) Disinfection
2-20
Solids Removal
Ballasted High Rate Clarification (BHRC) Processes
- Actiflo® Process
- Densadeg® Process
Emerging Technologies

2-22
2-24
Summary on
page
Disinfection
Alternative Disinfectants (PAA and BCDMH)
2-26
Nutrient Removal
Ammonia Recovery
2-29
Oxidation
Blue CAT™
2-31
Preliminary/Primary Treatment
Salsnes Filter
Research Technologies
None at this time
2-33


2-4
Wastewater Treatment and In-Plant Wet Weather Management

-------
March 2013
                                                        Emerging Technologies
                                                    Nutrient Removal
  Blue PRO™ Reactive Media Filtration
I, M, N
                                  Ip, In
  Phosphorus Recovery (Struvite or
  Calcium Phosphate Precipitation)
I, M, N
                                 Ip, Dn
                                                     Solids Removal
  Compressible Media Filters
I,M, N
                                   Dn
  Magnetite Ballasted Sedimentation
I, M, N
C,W,E
                                                                                        Dn,
                                                                                       Ip, In
  Multi-stage Filtration
I, M, N
                                 Ip, Dn
  Nanofiltration and Reverse Osmosis
I,M, N
                                 Ip, Dp
  Key
B = Bench scale
I = Full-scale industrial applications
M = Full-scale municipal applications
0 = Full-scale operations overseas
P = Pilot
N = Full-scale operations
   in North America
                                            pplicability
                                        F = Few plants
                                         = Industrywide
                                        L = Primarily large plants
                                        S = Primarily small plants
                           Potential Benefits
                       C = Capital sav ngs
                       I = Intense operational demand
                       0 = Operational/maintenance savings
                       S = Shock load capacity
                       W = Wet weather load capacity
                       E = Effluent quality
                                      Dp = Direct potable
                                      Dn = Direct nonpotable
                                      lp= Indirect potable
                                      In = Indirect nonpotable
                                                                     A  Positive feature
                                                                     0  Neutral or mixed
                                                                     T  Negative feature
        Figure 2.1—Evaluation of Innovative Physical/Chemical Treatment Technologies
Wastewater Treatment and In-Plant Wet Weather Management
                                                                            2-5

-------
Emerging Technologies
                                                                                       March 2013
  Nutrient Removal
                                  updated 2012
                                                                    Technology Summary
  Blue PRO™ Reactive  Media Filtration
                                                  State of Development:
                                                  Innovative.
Objective:
Remove phosphorus from tertiary wastewater.
Description:
The patented Blue PRO™ reactive filtration system is used to remove phosphorus from wastewater. It
combines co-precipitation and adsorption to a reactive filter media in an upflow sand filter. The Blue PRO™
equipment includes continuous backwash moving-bed filtration technology preceded by chemical addition and
a proprietary pre-reactor zone. Reactive hydrous ferric oxide-coated sand media is created by using an iron
coagulant on the filter media and accomplishes phosphorus removal by adsorption and filtration. This process
does not require the media to be changed because it includes a continuous regeneration process. After
adsorption, the iron and phosphorus are abraded from the sand grains. The iron and phosphorus passes out
in a wastestream while the sand is retained in the system.

The Blue PRO™ system is most suitable for small to medium plants (less than 10 MGD), because of the
relatively small area of each filter unit. For a larger  plant, it would be difficult to operate and maintain because
of the sheer number of filters required for treatment. Blue PRO™ units can be configured to run in series to
achieve lower phosphorus removal. The wastestream (containing residual iron) can be recycled to the head of
the plant to accomplish chemically enhanced primary treatment. It has been demonstrated that the Blue
PRO™ process can achieve monthly average effluent total phosphorus  levels as low as 0.009 mg/L to
0.036 mg/L in certain plants (Leaf et al., 2007).  However further full scale data is needed to determine how
consistently these levels could be achieved and assess the ability of this and other competing technologies to
address fluctuations in influent phosphorus flow and loading due to diurnal or seasonal conditions. Concerns
regarding this process include the fact that large recycle streams have to be sent to the biological process
(Perri et al., 2012). Full-scale facilities are meeting  total phosphorus limits of 0.05 mg/L (Newcombe and Lopp,
2010).
Comparison to Established Technologies:
The Blue PRO™ process appears to be similar to other advanced filtration processes preceded by iron
addition but includes the reactive adsorption media and proprietary pre-reactor zone and regeneration
process. Research by Benisch et al. found that  Blue PRO™ provided better total phosphorus removal than
other continuous backwash filters and was similar to a multistage adsorption clarifier filter system. BlueWater
also provides the BlueCAT™ system,  which combines Blue PRO™ with an advanced oxidation  process.
Available Cost  Information:
Approximate Capital Cost: 1  MGD $178,300;  3 MGD $494,000 uninstalled (2008).
Approximate O&M Costs: 1 MGD $29,380; 3  MGD $84,000 annually (2008).
Vendor Name(s):                              Installation(s):
Blue Water Technologies, Inc.                      More than 10 installations in the United States at up
10450 North Airport Dr.                             to 4-MGD capacity:
Hayden, ID 83835                                  Broadway, VA
Telephone: 888-710-2583                           Coeurd'Alene, ID
Fax: 208-209-0396                                 Georgetown, CO
Website: http://www.blueH2O.net                    Hayden, ID
                                                 Marlborough, MA
                                                 Plummer, ID
                                                 Sheintech, LA
                                                 Westerly,  MA

Key Words for Internet Search:
Blue PRO, advanced phosphorus removal, phosphorus adsorption
2-6
                                               Wastewater Treatment and In-Plant Wet Weather Management

-------
March 2013
        Emerging Technologies
  Nutrient Removal
                                 updated 2012
Technology Summary
  Blue PRO™ Reactive Media Filtration (continued)
  Data Sources:
  Newcombe, R.L. and Lopp, M. "Advanced Treatment and Mercury Removal to Ultra-low Levels by Reactive
  Filtration: Project Results from Great Lakes Region Treatment Facilities", 39th Annual Technical Symposium
  and OPCEA Exhibition, Water Environment Association of Ontario, 2010.Newcombe, R.L., et al. "Phosphorus
  Removal from Municipal Wastewater by Hydrous Ferric Oxide Reactive Filtration and Coupled Chemically
  Enhanced Secondary Treatment: Part II - Mechanism," Water Environment Research, Vol. 80, No. 3, pp.
  248-256, 2008.

  Newcombe, R.L., et al. "Phosphorus Removal from Municipal Wastewater by Hydrous Ferric Oxide Reactive
  Filtration and Coupled Chemically Enhanced Secondary Treatment: Part I - Performance," Water
  Environment Research, Vol. 80, No. 3,  pp. 238-247, 2008.

  Benisch, M. et al., "Can Tertiary Phosphorus Removal Reliably Produce 10 ug/L? Pilot Results from Coeur
  D'Alene, ID," WEF Nutrient Removal Conference, 2007.

  Leaf, W., et al., "Total Phosphorus Removal to Low Levels through Tertiary Reactive Filtration," WEFTEC,
  2007.

  Perri, K., et al. "Technology Evaluation  and Membrane Pilot Study to Achieve Low-Level Phosphorus Limits
  for Barrie,  Ontario". WEFTEC, 2012.

  Blue PRO™, "Hydrous Ferric Oxide (HFO) Coated Sand. Adsorptive Media Technical Summary," 2006.

  CH2M Hill, Technical Memorandum, "Evaluation of Blue PRO Process at the Hayden Wastewater Research
  Facility - Final Summary Report," 2006.

  http://www.blueh2o.net
                                                 Blue Water's
                                                 Phosphorus Removal Operation
               Skid mount design for flows from 10.000 gpd to 1 MOD
                                                                      888.710.Blue
                                                                   www.blueh2o.net
                     Blue Water Blue Pro™ Phosphorus Removal System
                          (used with permission of Blue Water Technologies)
Wastewater Treatment and In-Plant Wet Weather Management
                        2-7

-------
Emerging Technologies
                                                                                        March 2013
  Nutrient Removal
                                   prepared 2012
                                                                      Technology Summary
  Phosphorus Recovery (Struvite or Calcium Phosphate Precipitation)
                                                   State of Development:
                                                   Innovative.
Objective:
Precipitation and recovery of phosphorus as a
usable product.
Description:
Phosphorus recovery has become desirable as the potential for worldwide phosphorus shortage has been
recognized  (Bufe, 2010). Because phosphorus can be removed from wastewater in solid form only, it must
either be a component of the sludge or recovered as a separate solid phase. Although several other
approaches have been proposed, precipitation with crystallization has been adopted at several full-scale
facilities. Effective phosphorus recovery is implemented in the high phosphorus return stream of sludge liquor
from dewatering or decanting rather than in the mainstream where the phosphorus concentration is much
lower. Although phosphorus recovery could be used with sludge liquor from treatment plants using metal
phosphate precipitation, the process is most practical when coupled with biological phosphorus  removal,
which transfers much of the mainstream phosphorus to the sludge but allows a larger portion of it to be
released particularly during anaerobic digestion.
Although there are several variations, the basic precipitation/crystallization process is similar. The sludge
liquor is  returned to an upflow fluidized bed reactor along with a chemical added to generate a precipitate. A
common additive is magnesium to generate a magnesium ammonium phosphate precipitate (MgNH4PO4).
Otherwise known as MAP or struvite, this precipitate occurs frequently in sludge handling systems even
without supplemental magnesium. Controlled addition of magnesium and manipulation of upflow rate causes
the precipitate to be efficiently formed  and suspended in the flow until it grows to the desired size, at which
point, it settles to the bottom of the reactor cone and is removed. The product is marketed as a fertilizer.
Because MAP includes 0.45 Ib N for every 1.0 Ib P, struvite precipitation will also remove and recover
nitrogen  but to a lesser degree than phosphorus. Up to 85% P recovery has been reported by Ostara.
The Crystalactor process, developed by DHV and marketed in the United States by Procorp, has been used
to precipitate calcium phosphate (generally impractical for domestic WWTP applications  because of
carbonate interference [IWA, 2012]) and is being applied to precipitate struvite. The product is heated dried,
bagged,  and is the property of the WWTP owner. Procorp will help with  marketing. The Ostara Pearl process
is controlled to produce pellets of 1 to 3.5 mm, which are marketed by Ostara as CrystalGreen fertilizer. The
Multiform Harvest process uses a smaller reactor with no recycle to produce a raw struvite precipitate that
Multiform Harvest markets after converting it to a saleable product through further off-site processing.
These phosphorus recovery processes can be combined with phosphorus release upstream of thickening
equipment and anaerobic digesters to decrease uncontrolled struvite formation. The approach involves
combining primary sludge with waste activated sludge from a biological phosphorus  removal process under
anaerobic conditions to induce phosphorus release. Ostara's WASSTRIP process is one example.
Comparison to Established Technologies:
The most common method for phosphorus removal from wastewater is  by precipitation/adsorption with waste
activated sludge. Biological phosphorus removal is also relatively  common. Both processes result in
phosphorus being transferred from the wastewater to the sludge. When the sludge is stabilized and the
biosolids are land applied, the phosphorus is essentially recovered as a soil/crop nutrient. However, when the
sludge is incinerated or otherwise disposed of, the phosphorus could be effectively lost, although some
consideration has been given to phosphorus recovery from ash. Phosphorus recovery methods  separate a
large portion of the phosphorus from the sludge so that the two can be managed independently. One
important benefit of phosphorus recovery technologies is that any metal ions in the sludge remain with the
sludge and  are not co-precipitated with the phosphorus.
Available Cost Information:
Approximate Capital Cost: Highly dependent on wastestream strength.
Approximate O&M Costs: Not available.
2-8
                                                Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
                            Emerging Technologies
  Nutrient Removal
                                 prepared 2012
                    Technology Summary
  Phosphorus Recovery (Struvite or Calcium Phosphate Precipitation) (cont.)
  Vendor Name(s):
  Procorp Enterprises (Crystalactor)
  10200 Innovation Drive, Suite 500
  Milwaukee, Wl 53226
  Telephone: 800-449-8777
  Telephone: 414-258-8777
  Fax:414-258-8066
  Email: eng@procorp.com
  Website: www.procorp.com
  Ostara Nutrient Recovery Technologies (Pearl)
  690 - 1199 West Render Street
  Vancouver, BC V6E 2R1
  Telephone: 604-408-6697
  Fax: 604-408-4442
Installation(s):
Crystalactor
Two U.S. struvite removal facilities in
design/construction/startup in 2012
  Multiform Harvest
  2033 Sixth Ave., Suite 253
  Seattle, WA 98121-2580
  Telephone: 206-725-3305
  Email:  info@multiformharvest.com
  Key Words for Internet Search:
  Phosphorus recovery, phosphorus precipitation, Ostara,
Pearl
Durham, OR
Suffolk, VA
York, PA
Clean Water Services
(Operating a facility with Struvite recovery since
May, 2009)
Portland, OR
(Hillsboro,  OR)
Madison, Wl (2013 startup anticipated)
Multiform  Harvest
Boise, ID
Yakima, ID
Multiform Harvest, Crystalactor
  Data Sources:
  Sartorius, C., et al., "Phosphorus Recovery from Wastewater - Expert Survey on Present Use and Future
  Potential," Water Environment Research, Vol. 84, No. 4, pp 313-321, 2012.
  Water Environment Research Foundation, "Nutrient Recovery: State of the Knowledge," September 2011.
  Bufe, M., "Enough to Go Around? Phosphorus Shortage Concerns Spur Nutrient Recovery Technologies and
  Educational Efforts," Water Engineering and Technology, Vol. 22, No. 9, pp 18-23, 2010.
  International Water Association, "International Conference on Nutrient Recovery From Wastewater Streams
  Vancouver, 2009," IWA Water Wiki
  (http://www.iwawaterwiki.org/xwiki/bin/view/Articles/NutrientRecoveryProceedings), 2012.
  Le Corre, K.S., et al. "Phosphorus Recovery from Wastewater by Struvite Crystallization: A Review," Critical
  Reviews in Environmental Science and Technology Vol. 39,  No. 6, pp 433-477, 2009.
  Britton, A., et al. "Pilot testing and economic evaluation  of struvite recovery from dewatering centrate at
  HRSD's Nansemond WWTP," International Conference on Nutrient Recovery from Wastewater Streams
  Vancouver, 2009
Wastewater Treatment and In-Plant Wet Weather Management
                                            2-9

-------
Emerging Technologies
                                                                                           March 2013
  Solids Removal
                                    prepared 2012
                                                                        Technology Summary
  Compressible Media  Filtration (CMF)
                                                     State of Development:
                                                     Innovative.
Objective:
Multifunction, passive, high-rate filtration for wet-
and dry-weather treatment applications.
Description:
The WWETCO FlexFilter™ and Bio-FlexFilter™ use a synthetic fiber media bed that is passively compressed
from the sides by the head of the incoming water. The lateral compression forms a cone-shaped porosity
gradient that allows the stratification and removal  of large and small particles from the top to the bottom of the
media bed. The porosity gradient through the media bed, with its ability to handle heavy solids loading, gives
the technology a wide range of uses. In one location at the WWTF, the filter can be used to
    1.  Produce a reuse quality effluent as a tertiary filter
    2.  Increase the organic removal capacity of the facility, and/or reduce its power consumption
    3.  Treat excess wet-weather flow including biological treatment, as appropriate
The first two functions are accomplished during dry weather by a portion of the filter matrix sized for their
specific dual-use (Figure 1). During dry weather, part of the filter matrix acts as a tertiary filter and the
remaining portion as a biofilter. The tertiary filter cells can effectively remove phosphate precipitates created
by addition of metal salts. The biotreatment portion of the filter matrix can be used during dry weather to treat
primary influent or primary effluent wastewater, removing both particulates and soluble BOD reducing
secondary loadings (one trial showed consistent 38 percent removal, [WWETCO, 2012]) while maintaining a
healthy biological population in the filter media bed for treatment of the wet-weather flow when it occurs.
The biofilter cell matrix is sized for the excess wet-weather flow and TSS conditions to generally meet
secondary treatment effluent criteria. In wet weather, valves are opened or closed to direct the excess flow
through a one or two-stage filter treatment train. A two-stage, wet-weather filter train is shown in Figure 2. In
this case the FlexFilter primarily provides solids separation and the Bio-FlexFilter provides soluble BOD
removal,  optimizing the capacity of each train component. Another operation option allows the FlexFilter or a
portion of it to be used in the tertiary filter mode during smaller, wet-weather events. Only during larger events
would the entire filter matrix be dedicated to wet-weather treatment. When biological treatment is not required,
for instance in the case of CSOs, the Bio-FlexFilter cells can be eliminated. In this case, the  FlexFilter would
still be applied in the same two modes shown in Figures 1 and 2 (the Bio-FlexFilter being excluded), with both
filter effluents going to disinfection.

A filter cell treating wet weather or primary type solids uses the neighboring filter effluent for backwash supply.
When treating a waste with low solids (primary or secondary effluent), the filter cell can use the influent water
as backwash supply.  Low head air scrubs the media and lifts the spent backwash into the backwash trough to
waste.  Backwash from the filter would normally be routed to the plant influent, backwash from the biofilter
would normally be sent to solids processing. Excess biological growth is controlled with  a dilute chlorine
(3 mg/L) solution added to the backwash.
2-10
                                                 Wastewater Treatment and In-Plant Wet Weather Management

-------
March 2013
        Emerging Technologies
 Solids Removal
                              prepared 2012
Technology Summary
 Compressible Media Filtration (CMF) (continued)
Dry Weather Treatment Train
Preliminary
Treatment
f
Primary
Clarifier
r^
Bo og'ca
Treatment
Secondary
Clarifier
r





Primary Influent 'pr Primary Effluent
FlexFilter Effluent \
Bio-Filter Effluerit
i
FlexFilter™
Secondary
Effluent
Metal Salts Option
for Phosphorous
Trimming

Reuse Quality
Filter Effluent
Backwash
1
""I ' j i w
CP Bio-Fl
Low Head
Pumping
!

Bio-FlexFilter
^ Effluent To
Solids
Processing
exFilter™

  Figure 1. Dry-Weather Flow Schematic. Either filter system can be operated individually.
Wet Weather Treatment Train
Preliminary Excess Wet Weather
Treatment Flow (WWF)

i Backwt
Primary (Optional) Backwash To Soli
Kh
ds
Clarlfier * Processing
\ t *l/
Biological /-~vi
Treatment FlexFilter™ (J^ Bit
'*' ' 1 A * '
High Performance j L_T '--.-'
Secondary Solids Separatidn i Low Head
Clarifier ' Pumping
I 1
i
Disinfection


*
f-F/exR/ter™

Bio-Filtration for
Soluble Organic
Removal

    Figure 2. Wet-Weather Flow Schematic. Shows a two-stage FlexFilter/Bio-FlexFilter
     process train. A single-stage FlexFilter could also be appropriate for wet-weather
                     CSO applications without biological treatment.
Wastewater Treatment and In-Plant Wet Weather Management
                    2-11

-------
Emerging Technologies
                                        March 2013
  Solids Removal
                                   prepared 2012
                      Technology Summary
  Compressible Media Filtration (CMF) (continued)
  The passively operated matrix of the FlexFilter cells works with simple flow and level logic controls, open-close
  valves, and a low-head blower for cleaning and pumping the spent backwash water to waste. The multifunction
  filter makes this technology very attractive for satisfying current and future regulatory mandates for phosphorous
  control, excess wet-weather treatment and as an intermediate wastewater treatment step to reduce overall plant
  energy consumption and/or increase plant organic treatment capacity. A trial in Atlanta (McKern, 2004), showed
  that the FlexFilter is suitable for removal of TSS from raw CSO flow (75% to 94%) and sedimentation basin
  effluent (35%). The Bio-FlexFilter is suitable for meeting secondary treatment effluent criteria for CBOD5 and
  TSS (effluent less than 30 mg/L each) for wet-weather flows (WWETCO 2012).

  Sizing of the filter matrix is  a function of hydraulic and solids loading and the available head. Peak hydraulic
  loading rates (HLRs) range from 10 to 20 gpm/sq ft, with the lower end for high-strength wastewaters like
  CSOs and primary influent  sewage. The higher HLR would apply to the more dilute solids concentrations such
  as from a tertiary filter or dilute wet weather. Chemically assisted phosphorous removal HLR is 5 to 10 gpm/sq ft,
  depending on the concentration of metal salt/soluble phosphorous precipitate required. For CSO or primary
  influent applications, the footprint of the concrete filter structure (10 MGD) including influent/effluent channels
  and operating and backwashing cell chambers would be less than 210 sq ft per MGD (WWETCO, 2012). A
  smaller footprint would be used for SSO or tertiary applications. The filter system footprint above 10 MGD
  decreases with  increasing flows. Also according to the manufacturer, the filter matrix footprint without the
  peripheral concrete channels and chambers can  be reduced by about one-third using influent and effluent
  piping. The depth of the typical high solids filter is about 14 feet. Steel tank tertiary filters are 10  feet tall.
  Existing filter basins at 6- and 7-foot depths can be retrofitted.
  Comparison to Established Technologies:
  According to Frank and Smith (2006) the WWETCO FlexFilter technology provided comparable  effluent TSS
  (49 mg/L to 52  mg/L) with the ballasted flocculation systems in side-by-side testing. However, ballasted
  flocculation requires flocculation chemicals and  ramp-up time (15 to 30 minutes) to achieve performance
  objectives. The WWETCO  FlexFilter can meet similar or better TSS removals, requires no chemicals, and
  immediately achieves performance objectives. The FlexFilter starts dry and ends dry without odor issues,
  without special  startup protocols,  and without special attention to mechanical equipment. Although the
  WWETCO filter footprint is generally somewhat larger than the footprint for ballasted sedimentation,  it is roughly
  half as deep. FlexFilter throughput for tertiary filtration is in the order of 98 percent (WWETCO, 2012). Average
  throughput for CSO is about 95 percent (< 5% backwash per McKern, 2004). The throughput for chemically
  assisted  phosphorous filtration and biofiltration is in the order of 85 to 90 percent (WWETCO, 2012).
  Available Cost Information:
  Approximate Capital Cost: Equipment includes the filter media bed (all internal structural metals, media,
  compression bladder, airdiffuser), complete controls, valves/gates and actuators and blower package with
  redundancy. Equipment costs vary with the scale of the facility. Smaller flows will result in greater redundancy
  because of the  minimum size of the equipment. Costs decrease with increasing flows above 10  MGD.
  Equipment costs for the 10-MGD filter matrix can be generalized as follows:
Application
Tertiary filter
SSO and primary effluent
CSO and influent
Estimated equipment cost ($ per gallon capacity)
Less than $0.06
Less than $0.07
Less than $0.09
  Approximate O&M Costs: Operation costs are summarized as follows (WWETCO, 2012):
     1.   Tertiary filtration - 10 kW per MGD treated (20 mg/L TSS influent)
     2.   SSO or primary effluent - 35 kW per MGD treated (100 mg/L TSS influent)
     3.   CSO or primary influent - 60 kW per MGD treated (200 mg/L TSS influent)
2-12
Wastewater Treatment and In-Plant Wet Weather Management

-------
March 2013
                           Emerging Technologies
  Solids Removal
                                 prepared 2012
                   Technology Summary
  Compressible Media Filtration (CMF) (continued)
  Vendor Name(s):
  WWETCO, LLC
  152 Hickory Springs Industrial Dr.
  Canton, GA30115
  Telephone: 404-307-5731
  Email: info@westech-inc.com
  Web site: http:/www.wwetco.com
Installation(s):
FlexFilter
Columbus, GA
Heard County Water Authority, Franklin, GA
Lamar, MO
Springfield, OH (2012)
Bio-FlexFilter
Manila, Philippines
  Key Words for Internet Search:
  Wet weather filtration, CSO, SSO, bio-filtration, enhanced primary filtration, intermediate wastewater
  treatment, roughing filter, HRT, phosphorus removal, tertiary filtration, compressed media filter
  Data Sources:
  Arnett, C.A., et al., "Bacteria TMDL Solution To Protect Public Health And Delisting Process in Columbus,
  GA," WEFTEC, 2006.
  Frank, D.A., and T.F. Smith III, "Side by Side by Side, The Evaluation of Three High Rate Process
  Technologies for Wet Weather Treatment," WEFTEC, 2006.
  McKern, R. et al., "Atlanta CSO Pilot Plant Performance Results," WEFTEC, 2004.
  WERF, Peer Review: Wet Weather Demonstration Project in Columbus, Georgia, Co-published: Water
  Environment Research Foundation, Alexandria, VA, and  IWA Publishing, London, U.K., 2003.
  WWETCO, Boner, M., personal communication, 2012.
Wastewater Treatment and In-Plant Wet Weather Management
                                         2-13

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Emerging Technologies
                                                                                       March 2013
  Solids Removal
                                  updated 2012
                                                                     Technology Summary
  Magnetite Ballasted Sedimentation
                                                   State of Development:
                                                   Innovative.
Objective:
Ballasted sedimentation process for enhanced
removal of suspended solids. Used for tertiary
treatment (including phosphorus solids removal) or
high-rate treatment of overflows.

Description:
The CoMag™ process uses conventional chemical coagulation and flocculation along with the addition of
finely ground magnetite as a ballasting agent. The dense magnetite significantly increases the weight and
settleability of chemical floes, resulting in high-rate sedimentation. Approximately 85 percent of the settled
sludge is recycled (similar to the solids contact process) to provide nucleation sites for floe development.
Excess sludge is passed through a shear mill followed by a magnetic recovery drum to recover the magnetite
before the  nearly magnetite-free sludge is further processed. The recovered magnetite is returned to the
process. BioMag™ is a similar process using magnetite addition directly to the activated sludge process to
improve biological floe settleability. For more information, see the BioMag™ technology description in Chapter
3, Biological Treatment Processes. The Sirofloc process is similar to CoMag™ but involves an initial
magnetite activation step and has been  used to treat raw wastewater overflows.

Comparison to Established Technologies:
Magnetite is denser than suspended solids and sand, and it generates heavy, dense floe that settles rapidly.
This allows otherwise ordinary clarifiers  to be loaded at higher than typical rates while maintaining high-quality
effluent. The footprint of clarifiers used with the CoMag™ process is correspondingly small (although an
additional small area is required to house the magnetite recovery drum and magnetite supply). The magnetite
seed is recovered from sludge using a magnet instead of gravity, so recovery efficiency is high, and magnetite
make-up requirements are low. As with other processes employed to chemically precipitate phosphorus,
precipitation performance is limited by kinetic and stoichiometric factors. However, the nucleation, solids
contact and ballast provided by the CoMag™ process combine to allow phosphorus precipitates to be
removed very effectively once they are formed.
  Available Cost Information:
  Approximate Capital Cost: Not disclosed by the vendor.
  Approximate O&M Costs: Not disclosed by the vendor.
  Vendor Name(s):
  CoMag™ -Siemens Industry, Inc.
  Water Technologies
  Telephone: 866-926-8420 or 724-772-1402
  Web: www.water.siemens.com
                                                 Installation(s):
                                                 CoMag™
                                                 Concord, MA
                                                 Billerica, MA
                                                 Maynard, MA
                                                 Charlton, MA
                                                 Sturbridge, MA

                                                 Sirofloc
                                                 Malabar STP, New South Wales, Australia
                                                 No installations are in the United States
  Sirofloc - CSIRO
  Locked Bag 10
  Clayton South VIC 3169
  Australia
  Telephone: +61-3-9545-2176
  Fax:+61-3-9545-2175
  Email: enquiries@csiro.au

  Key Words for Internet Search:
  Siemens CoMag, ballasted sedimentation,  ballasted clarification, Concord WWTP, Sirofloc
2-14
                                               Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
        Emerging Technologies
  Solids Removal
                                 updated 2012
Technology Summary
  Magnetite Ballasted Sedimentation  (continued)
  Data Sources:
  Siemens, www.water.siemens.com
  Ellis, E.P, and A.M. Cathcart, "Selection, Installation, Startup and Testing of the World's First Full-Scale
  CoMag Phosphorus Reduction Tertiary Treatment System," Proceedings WEFTEC 2008.
  Tozer, H.G., "Study of Five Phosphorus Removal Processes Select CoMag™ to Meet Concord,
  Massachusetts' Stringent New Limits," Proceedings WEF Nutrient Removal, 2007.
  Akyel, G., et al., "Rapid Sewage Clarification Using Magnetite Particles," Proceedings of the 15th Federal
  Convention of the Australian Water and Wastewater Association, 1993.
  Booker, N.A., et al., "Novel High Rate Processes for Sewer Overflow Treatment," Water Science and
  Technology," Vol. 34, No. 3-4, pp. 103-109, 1996.
                                                                                  745043_WWT-04.ai
                               CoMag™ Process Flow Diagram
Wastewater Treatment and In-Plant Wet Weather Management
                      2-15

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Emerging Technologies
                                                                                       March 2013
  Solids Removal
  Multi-stage Filtration
                                  prepared 2012
                                                                    Technology Summary
                                                  State of Development:
                                                  Innovative.
Objective:
Very efficient removal of solids that contain
phosphorus and nitrogen, allowing compliance with
stringent nutrient limits.
Description:
Very low limits on nutrients are difficult to meet without achieving very low effluent solids concentrations.
Biomass solids are typically 8 to 10 percent nitrogen and 1 to 2 percent phosphorus by mass (Grady et al,
2011). If enhanced biological phosphorus removal is performed, the phosphorus content of the biomass can
be increased to 6 to 8 percent (Grady et al, 2011). If chemical phosphorus removal is done, the metal
phosphate precipitate (some of it colloidal) will have a substantial total  phosphorus component. Therefore,
although the discharge permit might allow 10, 20, or 30 mg/L total suspended solids, significantly lower total
suspended solids  could be  required to meet the nutrient limits. Implementing filtration in series with a first-
stage filter or first-stage clarifier and chemical addition between stages allows the finer colloidal particles that
escape the first solids separation stage to be targeted. Some example  systems that have shown good
phosphorus removal performance are Trident HS, DynaSand D2, and BluePRO™. Trident HS uses a tube
clarifier first stage followed  by an adsorption clarifier and mixed media or upflow, moving-bed filter final stage.
The Trident HS has been shown to achieve  effluent total phosphorus of 0.02 mg/L (Liu, 2010). The DynaSand
D2 uses two continuous-backwash, upflow-sand filters with a lamella settler applied on the backwash. Using
chemical phosphorus removal, DyanSand D2 has achieved 0.01  mg/L  average total phosphorus (Liu, 2010).
The BluePRO™ is a continuous-backwash,  upflow-sand filter with adsorption media and can  be used in series
to achieve very low effluent solids levels. With two-stage BluePRO™, the WWTP at Hayden,  Idaho, achieves
total  phosphorus between 0.009 and 0.018 mg/L (Leaf, 2007).
Comparison to Established Technologies:
Multistage filtration provides effluent solids quality better than single-stage sedimentation or filtration and
approaching that provided by microfiltration  membrane systems.
Available Cost Information:
Approximate Capital Cost: Equipment cost vary with technology and  performance requirements
Approximate O&M Costs: Operating costs include pumping.
Vendor Name(s):                              Installation(s):
Parkson - DynaSand                              DyanSand D2
1401 West Cypress Creek Rd                        Manotick, ON
Fort Lauderdale, FL 33309-1969                      Stamford, NY
Telephone: 1-888-PARKSON                        Walton, NY
Fax:954-974-6182
Email: technology@parkson.com
Web site: www.parkson.com
  Blue Water Technologies, Inc.
  10450 North Airport Drive
  Hayden, ID 83835
  Telephone: 888-710-2583
  Fax: 208-209-0396
  Website: http://www.blueH2O.net

  Siemens Industry, Inc. - Trident HS
  Water Technologies
  Telephone: 866-926-8420 or 724-772-1402
  Web: www.water.siemens.com
                                                         ,TM
                                                 BluePRO
                                                 Hayden, ID
                                                 Trident HS
                                                 Couerd'Alene, ID
2-16
                                               Wastewater Treatment and In-Plant Wet Weather Management

-------
March 2013
        Emerging Technologies
  Solids Removal
                                 prepared 2012
Technology Summary
  Multi-stage Filtration (continued)
  Key Words for Internet Search:
  DyanSand, BluePro, Trident HS, wastewater filtration

  Data Sources:
  Grady, CPL Jr. et al., Biological Wastewater Treatment, IWA Publishing and CRC Press, Taylor and Francis
  Group, Boca Raton FL, 2011.

  WEF Nutrient Removal Task Force, Nutrient Removal, WEF Manual of Practice No. 34, WEF Press,
  Alexandria VA, 2010.

  Liu, I., et al., "Comparison of Phosphorus Fractionation in Effluents from Different Wastewater Treatment
  Processes," WEFTEC Proceedings, 2010.

  Benisch, M., et al., "Can Tertiary Phosphorus Removal Reliably Produce 10 ug/L?," WEF Nutrient Removal
  Conference Proceedings, 2007.

  Leaf, W., et al., "Total Phosphorus Removal to Low Levels Through Tertiary Reactive Filtration," WEFTEC
  Proceedings, 2007.
Wastewater Treatment and In-Plant Wet Weather Management
                      2-17

-------
Emerging Technologies
                                                                                      March 2013
  Solids Removal
                                  updated 2012
                                                                    Technology Summary
  Nanofiltration (NF) and Reverse Osmosis (RO)
                                                  State of Development:
                                                  Innovative.
Objective:
NF and RO are membrane processes that can be
used to remove recalcitrant compounds that
otherwise contribute organic carbon, nitrogen, and
phosphorus, to reduce total dissolved solids,  and to
remove viruses.
Description:
Tertiary membrane filtration for advanced treatment of secondary effluent can be accomplished using NF or
RO. Typical characteristics for each are
Characteristic
Pore size range
Molecular weight cutoff
Operating pressure
NF
0.001-0.01 micrometers
200-400 Daltons
70-120psig
RO
0.0001-0.001 micrometers
100-200 Daltons
1 25-300 psig
Example
Contaminants
in Secondary
Effluent
•njill-if.--: P-WJS
MWCO. Da
Nominal Pore
Size, urn
QBPs
i — n
SOCs
IDS
; norganic
ions)
GS3
Pesticides
PhACs
EDCs
nrtrrni
(IP
10- ; 10'
0.001 O.C

Vj>
SMPS
EPS MOM
ILJ]|[[J]|l|[jl
son
Viruses
S///////A
' Baden
Colls
I
i
V////////////////J(
v/$fc%yi:
. . ^_m^_
10* ; io!



02 0005 0.004 0.1 1
al

c
Cysts
•••
luUi'...:
I^H
I
amass Floe
i
1
1


Grarnjl8f-P^f>a FimaUon |

0 10
                        NF and RO Treatment Process Characteristics

  RO operates by high-pressure diffusion of solutes through the membrane; NF uses both diffusion and sieving
  action. NF removes many of the same organic compounds that would be targeted with RO but allows more of
  the inorganic material to remain. Both processes are used for removing priority organic pollutants, recalcitrant
  organics, bacteria, and viruses. Recently, NF and RO have been considered as technology to achieve low
  levels of total nitrogen.  However, recent research (Merlo et al. 2012) has determined that even RO does not
  consistently achieve total nitrogen levels less than 1.0 mg/L.  Both are useful for removing pesticides,
  Pharmaceuticals, hormones, and other micro-constituents.

  NF and RO are primarily used where water reuse is the treatment goal. Typically, microfiltration or
  ultrafiltration is used as a pretreatment process for water that is required to be treated through NF or RO. The
  membranes are typically made of cellulose acetate or aromatic polyamides and are spiral wound  and hollow
  fiber. NF is operated at lower pressures, so it uses less energy than RO. Both require membrane replacement
  as trans-membrane pressure increases from fouling.
2-18
                                               Wastewater Treatment and In-Plant Wet Weather Management

-------
March 2013
                           Emerging Technologies
  Solids Removal
                                 updated 2012
                   Technology Summary
  Nanofiltration (NF) and Reverse Osmosis (RO) (continued)
  Comparison to Established Technologies:
  Microfiltration and ultrafiltration membranes are used for membrane bioreactors where the membrane is in
  direct contact with the high solids mixed liquor. These membranes provide excellent removal of particulate
  and colloidal material but cannot remove dissolved constituents as can NF and RO. NF and RO remove total
  suspended solids, total dissolved solids, and other pathogens better than the ultrafiltration process.
  Available Cost Information:
  Approximate Capital Cost: Not available.
  Approximate O&M Costs: Not available.
  Vendor Name(s):
  Nitto Denko - Hydranautics
  401 Jones Rd
  Oceanside,  CA 92058
  Telephone:  760-901-2500
  Fax:760-901-2578
  Email: info@hydranautics.com
  GE Infrastructure Water and Process
  Technologies
  4636 Somerton Rd
  Trevose, PA 19053
  Telephone:  215-355-3300
  Web site: www.gewater.com
  Koch Membrane Systems, Inc.
  850 Main St
  Wilmington, MA 01887
  Telephone:  888-677-5624
  Email: info@kochmembrane.com
  Siemens Industry, Inc.
  Water Technologies
  Telephone: 866-926-8420 or 724-772-1402
  Web: www.water.siemens.com
Installation(s):
Full-scale U.S. installations:
   Carlsbad, CA
   Carson, CA
   Cerritos, CA
   Chandler, AZ
   Dublin/San Ramon, CA
   El Segundo, CA
   Eva Beach, HI
   Fountain Valley, CA
   Harlingen, TX
   Ky Colony Beach, FL
   Livermore, CA
   Long Beach, CA
   Los Angeles, CA
   Miami, FL
   Santa Maria, CA
   Scottsdale, AZ
   State College, PA
   Torrance, CA
  Key Words for Internet Search:
  Nanofiltration, NF, wastewater treatment, reverse osmosis, RO, membranes

  Data Sources:
  Merlo, R., et al., "Analysis of Organic Nitrogen Removal in Municipal Wastewater by Reverse Osmosis,"
  Water Environment Research, Vol. 84, No. 7, pp. 588-595, 2012.
  Reardon, R.D., et al., "Membrane Treatment of Secondary Effluent for Subsequent Use: Phase 2 - Pilot Plant
  Comparisons of MF and UF for Pretreatment of High Pressure Membranes," Water Environment Research
  Foundation Report No. 01-CTS-6a, 2007.
  Reardon, R.D., et al., "Membrane Treatment of Secondary Effluent for Subsequent Use," Water Environment
  Research Foundation Report No. 01-CTS-6, 2005.
  Metcalf and Eddy, Wastewater Engineering Treatment and Reuse, 4th ed., 2003.
Wastewater Treatment and In-Plant Wet Weather Management
                                         2-19

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Emerging Technologies
                                                                                        March 2013
  Disinfection
                                   updated 2012
                                                                     Technology Summary
  Microwave  Ultraviolet (UV) Disinfection
                                                   State of Development:
                                                   Adaptive Use.
Objective:
Precipitation and recovery of phosphorus as a
usable product.
Description:
UV disinfection transfers electromagnetic energy from a mercury arc lamp to wastewater. Electromagnetic
radiation, between the ranges of 100 to 400 nm (UV range), penetrates bacterial cells, and works as a
bactericide. Typical mercury vapor UV lamps contain electrodes that facilitate the generation of UV radiation
by striking an electric arc. These electrodes are delicate and their deterioration is the primary source of failure
in UV disinfection systems. Microwave UV disinfection technology eliminates the need for electrodes by using
microwave-powered, electrodeless, mercury UV lamps.  In this technology, microwave energy is generated by
magnetrons and directed through wave guides into quartz lamp sleeves containing argon gas. The directed
microwave energy excites the argon atoms, which in turn excite the mercury atoms to produce radiation as
they return from excited states to lower energy states, as is the case with other mercury UV lamps. Electrode-
less lamps operate at low pressure, which reduces safety risks and increases lamp life. Microwave UV lamps
allow greater flexibility for variations  in parameters such as lamp diameter, operating pressures, and fill
materials because of the absence of electrodes. This allows for greater optimization of radiation at specific
wavelength regions. The intensity of the radiation increases when the applied microwave power is increased.
Microwave UV disinfection systems are available in modular, open-channel, and closed-vessel designs.

Comparison to Established Technologies:
Microwave UV disinfection systems use low-pressure, high-output electrodeless lamps to optimize  UV output
at 254 nm (the same wavelength targeted by standard UV disinfection systems). The electrodeless lamps
warm up quickly and are capable of disinfection within 12 seconds compared to startup times of 20 seconds
to 3 minutes for electrode lamps. Eliminating the electrode from the lamp eliminates the primary deterioration
process associated with UV lamps, resulting in a lamp life approximately three times that of electrode lamps.
Lamp aging, the phenomenon  by which the output of UV lamps steadily decreases with lamp age is not a
factor with microwave UV lamps. The lamp has a very low residual radiation of energy, thus almost instant
shutoff capability, which prevents overheating heat-sensitive materials near the lamps. The improved warm up
and shutoff response capability provide additional opportunity for effective flow pacing control to match UV dose
to operating conditions in  real time. This reduces energy consumption without reducing lamp life. Radiation is
produced through the entire length of the lamp, and no energy loss occurs as is associated with electrodes. The
electrodeless lamp system has more components than the conventional electrode system, including the
magnetron, wave guides,  and cooling fans. Magnetron life is limited and requires replacement. Magnetrons
usually are warranted for up to 10,000 hours of operation. Lamps are typically warranted for 3 years.
Available Cost Information:
Approximate Capital Cost: Not disclosed by the vendor.
Approximate O&M Costs: Not disclosed by the vendor.
  Vendor Name(s):
  Severn Trent Services - Microdynamics
  3000 Advance Ln
  Colmar, PA18915
  Telephone: 215-997-4000
  Fax:215-997-4062
  Email: info@severntrentservices.com
  Web site: www.severntrentservices.com
                                                  Installation(s):
                                                  Blairsville WWTP, PA
                                                  Dow Chemicals, TX
                                                  Kent County, DE
                                                  Kingsport WWTP, TN
                                                  Leacock WWTP, PA
                                                  Mandeville WWTP, LA
                                                  Montevallo WWTP, AL
                                                  Mt. Signal WWTP, Seeley County, CA
2-20
                                                Wastewater Treatment and In-Plant Wet Weather Management

-------
March 2013
        Emerging Technologies
  Disinfection
                                 updated 2012
Technology Summary
  Microwave  Ultraviolet (UV) Disinfection (continued)
  Key Words for Internet Search:
  Microwave UV disinfection, electrodeless UV lamps
  Data Sources:
  Meera, V., et al., "Microwave UV Comes to Texas," WEFTEC Proceedings, 2010.
  Black and Veatch Corporation, "White's Handbook of Chlorination and Alternative Disinfectants," 5th ed.,
  Wiley, 2010.
  Newton, J., "Disinfection Utilizing an Innovative Microwave UV System," WEFTEC Proceedings, 2009.
  Gutierrez, R.L., et al., "Microwave UV-A NewWave of Tertiary Disinfection," WEFTEC Proceedings, 2006.
  Microwave UV Technology, a Presentation by MicroDynamics™, Severn Trent Services.
  Vendor-supplied information.
Wastewater Treatment and In-Plant Wet Weather Management
                      2-21

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Emerging Technologies
                                                                                         March 2013
  Solids Removal               prepared 2008
  Actiflo® Process
                                                                       Technology Summary
                                                    State of Development:
                                                    Adaptive Use.
Objective:
Treatment of primary and tertiary effluents.
Description:
The Actiflo® process is a high-rate chemical and physical clarification process that involves the formation of
suspended solids onto a ballast particle (microsand) followed by lamellar settling. It is considered an
established process for the treatment of wet weather flows, but is also being applied to primary and tertiary
effluents. The process starts with the addition of a coagulant to destabilize suspended solids. The flow enters
the coagulation tank for flash mixing to allow the coagulant to take effect then overflows into the injection tank
where microsand is added. The microsand serves as a "seed" for floe formation, providing a large surface
area for suspended solids to bond to and is the key to Actiflo®. It allows solids to settle out more quickly,
thereby requiring a smaller footprint than conventional clarification.
Polymers may either be added in the injection tank or at the next step, the maturation tank. Mixing is slower in
the maturation tank, allowing the  polymer to help bond the microsand to the destabilized suspended solids.
Finally, the settling tank effectively removes the floe with help from plate settlers allowing the tank size to be
further reduced. Clarified water exits the process by overflowing weirs above the plate settlers. The sand and
sludge mixture is collected at the bottom of the settling tank with a conventional scraper system and pumped
to a hydrocyclone, located above the injection tank. The hydrocyclone converts the pumping energy into
centrifugal forces to separate the higher density sand from the lower density sludge. The sludge is discharged
out of the top of the hydrocyclone while the sand is recycled back into the Actiflo® process for further use.
Screening is required  upstream of Actiflo® so that particles larger than 3 to 6 mm do not clog the
hydrocyclone.
Several startup modes may be used for a full scale Actiflo® system. If a wet weather event is expected within
7 days of a previous wet weather event, the units should be shut down, but not put on standby. Wastewater
would remain  in the tanks  and a wet startup would ensue at the time of the next wet weather event. In
summer months, when freezing is not possible, the intermittent flush standby mode could be used; and when
freezing is possible, the continuous flush standby mode should be used. These standby modes should results
in a successful wet  method, dry startup. (See also "BioActiflo®" process, Chapter 4.)

Comparison to Established Technologies:
Fundamentally, this process is very similar to conventional coagulation, flocculation, and sedimentation water
treatment technology. Both processes use coagulant for the destabilization and flocculent aid (polymer) for
the aggregation of suspended materials. These materials are then subsequently removed by settling for
disposal. The  primary technical advance made in the Actiflo® process is the addition of microsand as a "seed"
and ballast for the formation of high-density floes that have a relatively high-density microsand nucleus and
are easily removed  by settling. Chemical phosphorus removal is limited by kinetic factors as well as
stoichiometric factors  and  excessive inorganic precipitant requirements need to be reduced.
Available Cost Information:
Approximate Capital Cost: Not disclosed by vendor.
Approximate O&M Costs: Not disclosed by vendor.
Vendor Name(s):
Kruger USA
401 Harrison Oaks Blvd., Suite 100
Gary, NC 27513
Telephone: 919-677-8310
Fax:919-677-0082
Email: krugerincmarketing@veoliawater.com
Web site: http://www.krugerusa.com
                                                    Installation(s):
                                                    City of Greenfield, IN
                                                    Lincolnton, NC
                                                    Lawrence WWTP, IN
                                                    Williamette WTP, OR
                                                    Fort Worth, TX
2-22
                                                 Wastewater Treatment and In-Plant Wet Weather Management

-------
March 2013
          Emerging Technologies
  Solids Removal
                                 prepared 2008
 Technology Summary
 Actiflo® Process (continued)
  Key Words for Internet Search:
  Actiflo®, Ballasted High Rate Clarification, BHRC

  Data Sources:
  Web site owned by Kruger USA.
  Keller, John, et al., "Actiflo®: A Year's Worth of Operating Experience from the Largest SSO System in the
  U.S.," Water Environment Federation's Annual Technical Exhibition and Conference (WEFTEC), 2005.
  Ponist, Jeffrey B., David Scheiter, "Ballasted High Rate Clarification Process Removes City of Greenfield,
  Indiana as a CSO Community."
  Sigmund, Thomas, et al., "Operating Chemically Enhanced Clarification for Optimum Disinfection
  Performance," WEFTEC, 2006.
                                                  Microsand and Sludge to Hyrdocyclone
              Polymer
                               Microsand
                                          I
T
Clarified
 Water
                                                          o   o  o
       Coagulant
    Raw
    Water
ex
j
X3
^
IX
ex
>-a
~
ex
X3
Coagulation Injection Maturation
                                                                   \
                                                       Tube Settler
                                                       with Scraper
                                   Actiflo® Process Diagram
   O  O  O   O
                                                                                  74S041_WWT-07 .ai
Wastewater Treatment and In-Plant Wet Weather Management
                        2-23

-------
Emerging Technologies
                                        March 2013
  Solids Removal
                                   prepared 2008
                      Technology Summary
  DensaDeg® Process
  Objective:
  Treatment of primary and tertiary effluents and wet
  weather flows.
  State of Development:
  Adaptive Use.
  Description:
  The DensaDeg® process is a high-rate chemical and physical clarification process that combines sludge
  ballasted clarification and lamellar filtration, both established processes. The DensaDeg® process starts with
  the addition of a coagulant to destabilize suspended solids. The flow enters the rapid-mix tank for flash mixing
  to allow the coagulant to take effect then overflows into the reactor tank where sludge and polymer are added.
  A draft tube and mixer in the reactor allow for thorough mixing of the wastewater with the recirculated sludge
  and added chemicals. The sludge serves as a "seed" for floe formation providing a large surface area for
  suspended solids to bond to and is the key to DensaDeg®, allowing solids to settle out  more quickly, thereby
  requiring a smaller footprint than conventional clarification.
  Wastewater flows over a weir from the reactor tank through a transition zone before entering the clarifier. The
  clarifier effectively removes the flow with help from settling tubes, allowing the tank size to be further reduced.
  Clarified water exits the process  by overflowing weirs above the settling tubes. Sludge  is collected at the
  bottom of the clarifier with a conventional scraper system and recirculated back to the reactor tank.
  Periodically, a separate sludge pump energizes and wastes a small portion of the  sludge from the system.
  Scum is removed from the process at the top of the transition zone by a cylindrical collector that automatically
  rotates periodically.
  Several startup modes may be used for a full-scale DensaDeg®. If a wet weather event is expected within 6
  hours of a previous wet weather  event, the units should be shut down, but not drained. After 6 hours, the units
  may be drained except for three feet of depth in the clarifier. Both of these scenarios, which would include
  keeping the sludge collector running while the system  is idle, would maintain a sludge inventory and a wet
  startup would ensue at the time of the next wet weather event. After 12 hours the tanks should be completely
  drained to prepare for a dry startup.

  Comparison to Established Technologies:
  Fundamentally, this process is very similar to conventional coagulation, flocculation,  and sedimentation
  treatment technology. Both processes use coagulant for the destabilization  and flocculent aid (polymer) for
  the aggregation of suspended materials. These materials are then subsequently removed by settling for
  disposal. The primary technical advance made in the DensaDeg® process is the recirculated sludge as a
  "seed" for the formation of high-density floes for easy removal by settling. Chemical phosphorus removal  is
  limited by kinetic factors as well as stoichiometric factors, and excessive inorganic precipitant requirements
  need to be reduced.
  Available Cost Information:
  Approximate Capital Cost: Cost estimates are dependent upon local requirements and specific applications.
  Approximate O&M Costs: Cost savings are linked to the relative ease of installation, operational flexibility,
  and low-energy consumption.
  Vendor Name(s):                               Installation(s):
  Infilco Degremont Inc.                             Turlock, CA
  P.O. Box 71390                                   Gainsville, GA
  Richmond, VA 23255-1930                          Toledo, OH
  Telephone: 804-756-7600                           Halifax, Nova Scotia
  Website: http://www.infilcodegremont.com            Shreveport,  LA
                                                   Breckenridge, CO
2-24
Wastewater Treatment and In-Plant Wet Weather Management

-------
March 2013
        Emerging Technologies
  Solids Removal
                                prepared 2008
Technology Summary
DensaDeg® Process (continued)
Key Words for Internet Search:
DensaDeg®, High Rate Clarification, HRC
Data Sources:
Web site owned by Infilco Degremont.
http://www.infilcodegremont.com/separations_4.html
Sigmund, Thomas, et al., "Operating Chemically enhanced Clarification for Optimum Disinfection
Performance," WEFTEC, 2006.
Coagulation Flocculation Clarification
Coagulant
txi>-=

.
Polymer Floated Matter
•It r J
p 1 ^ MUM
X 1 o 1 1
^ ^
a
i/f 4X.
^ ' , ' '
I I x> o=nnr

V
i
vvvv M—.
\\\\\\\\ ~" rr

~m3=
// j
_
Sludge Recirculation Thickened Sludge
Extraction
745043_WWT-03.al
Process Diagram of the DensaDeg® High-Rate Clarifier and Thickener
Wastewater Treatment and In-Plant Wet Weather Management
                      2-25

-------
Emerging Technologies
                                                                                          March 2013
  Disinfection
                                   updated 2012
                                                                       Technology Summary
  Alternative Disinfectants [Peracetic Acid (PAA) and BCDMH]
                                                    State of Development:
                                                    Emerging.
Objective:
Alternatives to chlorine disinfection using disinfection
products such as peracetic acid (PAA, also known
as peroxyacetic acid [CH3CO3H]), or Bromo Chloro
Dimethylhydantoin (1 -Bromo-3-Chloro-5,5
Dimethylhydantoin [BCDMH]).
Description:
Alternative disinfectants are being applied to wet-weather flows because of their ability to act as high-rate
disinfectant. PAA is a stronger oxidant than hypochlorite or chlorine dioxide but not as strong as ozone. In
parts of Europe  and Canada where chlorine is not used because of the potential to form disinfection by-
products. PAA is an oxidizing agent used as a routine wastewater disinfectant. PAA does not affect effluent
toxicity, so need not be removed as with chlorine. Recently approved by EPA specifically as a wastewater
disinfectant (Proxitane WW-12), PAA is a clear, colorless liquid available at a concentration of 12 to 15
percent. With stabilizers to prevent degradation in storage it exhibits less than 1 percent decrease in activity
per year. At the  12 percent concentration, its freezing point is approximately-40 °C. Although it is explosive at
high concentrations, at 15 percent or less, PAA does not explode. The solution is acidic (pH 2) and requires
care in handling, transport, and storage. PAA has been used successfully in combination with UV disinfection,
allowing reductions in lamp intensity and less frequent lamp cleaning. It is available in totes or in bulk, should
be stored near the point of application, and should be well mixed where it is introduced. The dosage used for
disinfecting secondary effluent depends on the target organism, the water quality,  and the level of inactivation
required. For example, a dosage of 5 mg/L 15 percent PAA, with contact time of 20 minutes, can reduce fecal
and total coliform by 4 to 5 logs in secondary effluent (Morris 1993). Dosage of 1-2 mg/L PAA is typical for
secondary effluents. Note, however, that PAA is less effective for inactivation of spores, viruses, and protozoa
including Giardia and Cryptosporidium (Koivunen et al. 2005; Liberti and Notarnicola 1999).

BCDMH is a chemical disinfectant used to treat drinking water. It is a crystalline substance, insoluble in water,
but soluble in acetone.  It reacts slowly with water, releasing hypochlorous acid and hypobromous acid.
EBARA has devised a system to liquefy the BCDMH powder in a mixer with an injection device. The solution
is injected directly into the wastewater, and it relies on the turbulence of the process to mix into the
disinfection process.
Comparison to Established Technologies:
Compared to disinfection with chlorine compounds, PAA does not form harmful by-products after reacting with
wastewater when using dosages typical for secondary effluent. For example, during the trial at St. Augustine
(Keough and Tran 2011), an average PAA dose of 1.5 mg/L provided similar fecal coliform reduction as a
7 mg/L chlorine dose (both meeting the 200 cfu/00  mL limit), but the chlorine resulted in 170 ug/L total THM
compared to 0.6 ug/L TTHM for PAA. With tertiary treatment, PAA can meet limits of less than  10 cfu/mL but
achieving very low (less than 2 cfu/100 mL) fecal coliform limits required high PAA doses (Leong et al. 2008).
However, a residual of acetic acid could be present and might exert an oxygen demand or provide substrate
for bacterial regrowth. Dosages and  contact times are no more than required for disinfection with chlorine, so
existing contact tanks should be adequate for conversion to PAA.
BCDMH has a small footprint and is  easier to store than chlorine disinfection products. The feed stock is
BCDMH powder, which is liquefied as needed by feeding through a dissolution mixer with clean water to form
a solution that is injected into the wastewater. The BCDMH powder is reportedly highly stable, with a shelf life
of longer than one year, making it potentially attractive for use in  CSO applications that are characterized by
intermittent operation. BCDMH is an effective disinfectant that can achieving bacterial reductions comparable
to sodium hypochlorite, but it acts in a shorter amount of contact time (typically 3 minutes instead of 5 minutes
for sodium hypochlorite), thereby reducing the size of the contact chamber, which  might result in capital cost
savings. Similar to sodium hypochlorite, BCDMH also produces DBPs and disinfection residuals, potentially
requiring the use of a reducing agent.
2-26
                                                 Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
                            Emerging Technologies
  Disinfection
                                 updated 2012
                   Technology Summary
 Alternative Disinfectants [Peracetic Acid  (PAA) and  BCDMH] (continued)
 Available Cost Information:
 Approximate Capital Cost: Equipment required is similar to that used for hypochlorite systems.
 Approximate O&M Costs: The cost of PAA is approximately $1.00/lb.
  Vendor Name(s):
  Peracetic Acid
  FMC Corporation
  Minh Iran
  1735 Market St
  Philadelphia, PA 19103
  Telephone: 609-951-3180 or 267-357-1645
  Email: Minh.Tran@fmc.com
  Web site: http://www.microbialcontrol.fmc.com
  Solvay Chemicals NA/PERAGreen Solutions
  John Meakim
  2900 Hungary Rd
  Richmond, VA 23228
  Telephone: 804-501-0845x320
  Fax:804-501-0846
  Web site: www.peragreensolutions.com
  BCDMH
  EBARA Engineering Service Corporation
  Shinagawa, NSS-11 Building
  2-13-34 Konan, Minato-Ku, Tokyo, Japan
  Telephone: 81-3-5461-6111 (switchboard)
  Web site: http://www.ebara.co.jp/en/
  Key Words for Internet Search:
  Alternative disinfectant, CSO disinfection, peracetic acid, PAA, peroxyacetic acid, BCDMH
  Data Sources:
  Brian, K., and M. Tran, "Old City, New Ideas: Peracetic Acid in Wastewater Disinfection at St.Augustine,"
  Florida Water Resources Journal, April, 2011.
  Leong, et al., "Disinfection of Wastewater Effluent: Comparison of Alternative Technologies," Water
  Environment Research Foundation (WERF) Report 04-HHE-4, 2008.
  Meakim, J.T., et al., "Peroxyacetic Acid Restores Design Capacity for Fecal Coliform Compliance in an
  Underperforming UV Disinfection Wastewater System with No Capital Upgrade," Proceedings WEF Specialty
  Conference on Disinfection, 2009.
  Rossi, S., et al., "Peracetic Acid Disinfection: A Feasible Alternative to Wastewater Chlorination," Water
  Environment Research, Vol. 79, No. 4, pp. 341-350, 2007.
  Moffa, P.E., et al., "Alternative Disinfection Technology Demonstrates Advantages for Wet Weather
  Applications," Water Environment and Technology, January 2007.
Installation(s):
Peracetic Acid
Many applications are in Europe, including
   Milan/Taranto, Italy
   Kuopio, Finland

Canadian applications:
   Niagara Falls, Ontario
   Chateauguay, Quebec
   La Prarie, Quebec

U.S.  pilots:
   Hannibal, MO
   Stubenville, OH
   Jefferson City, MO
   St Augustine, FL
   Largo, FL
BCDMH
Columbus, GA
Akron, OH
Wastewater Treatment and In-Plant Wet Weather Management
                                          2-27

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Emerging Technologies
                                       March 2013
  Disinfection
                                  updated 2012
                     Technology Summary
  Alternative Disinfectants [Peracetic Acid (PAA) and BCDMH] (continued)
  Columbus Georgia Waterworks, CSO Technology Testing web site:
  http://www.cwwga.org/NationalPrograms/lndex.htm

  Combined Sewer Overflow Technology Fact Sheet Alternative Disinfection Methods web site:
  www.epa.gov/owmitnet/mtb/altdis.pdf

  Gehr, R., et al., "Disinfection Efficiency of Peracetic Acid, UV and Ozone after Enhanced Primary Treatment
  of Municipal Wastewater," Water Research, Vol. 37, No. 19, pp. 4573-4586, 2003.

  Morris, R., "Reduction of Microbial Levels in Sewage Effluents using Chlorine and Peracetic Acid
  Disinfectants," Water Science and Technology, Vol. 27, 1993.

  WERF, Wet Weather Demonstration Project in Columbus, Georgia, 98-WWR1P.

  Kitis, M., "Disinfection of Wastewater with Peracetic Acid: A Review," Environment International, Vol. 30,
  pp. 47-55, 2004.

  Koivunen, J., and H. Heinonen-Tanski, "Inactivation of Enteric Microorganisms with Chemical Disinfectants,
  UV Irradiation and Combined chemical/UV Treatments," Water Research, Vol. 39, No. 8, pp.1519-1526, 2005.

  Liberti, L, and M. Notarnicola, "Advanced Treatment and Disinfection for Municipal Wastewater Reuse in
  Agriculture," Water Science and  Technology, Vol. 40, No. 4-5, pp. 235-245, 1999.
2-28
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March 2013
                                                Emerging Technologies
  Nutrient Removal
                                  prepared 2012
                                        Technology Summary
  Ammonia  Recovery
  Objective:
  Removal and recovery of ammonia nitrogen.
                    State of Development:
                    Emerging.
  Description:
  Ammonia recovery from high-concentration sludge liquors such as centrate streams can be accomplished by
  vacuum distillation or by stripping with air or steam coupled with ammonia adsorption into sulfuric acid to
  produce ammonium sulfate. The Ammonia Recovery Process (ARP) has achieved ammonia removal from a
  centrate stream at approximately 1,000 mg/L ammonia -N to less than 100 mg/L ammonia -N (Orentlichter,
  2009), but it works well over a range of concentrations. The ammonia is recovered as ammonium sulfate
  solution that might be a marketable product. Because stripping ammonia requires that it be in the form of free
  ammonia rather than ammonium  ion, the centrate pH and temperature are elevated. Typical  municipal design
  is for pH 9.5 at a temperature of 140 °F, although other combinations of temperature and pH can achieve the
  similarly high free ammonia fraction required for effective stripping (see the graph below based on equilibrium
  and thermodynamic constants from Snoeyink and Jenkins, 1980). This requires addition of sodium hydroxide
  (caustic) or other base and heating of the centrate above the typical inlet range of 90 to 105 °F. To improve
  stripping efficiency, the ARP system lowers the pressure over the water to a vacuum of 26 to 29 inches in a
  batch operation lasting approximately 10 minutes (Orenlichter, 2009). This releases the dissolved ammonia
  gas from solution to be entrained in sulfuric acid, which generates the ammonium sulfate solution product. If
  desired, the solution  produced can be further concentrated using multiple stages of vacuum distillation.
  According to pilot-scale results with centrate and landfill leachate at various concentrations, the process is first
  order with respect to ammonia concentration so it can be expected to provide 90% removal over a wide range
  of influent ammonia concentrations (Orenlichter, 2009).
                100.00%

                 90.00%

                 80.00%

                 70.00%

                 60.00%
             _™

             |   50.00%
             E
             <   40.00%
             •
             £   30.00%
             se
                 20.00%

                 10.00%

                  0.00%
Water Temp, F
       -140


       -104


       -68
                                                      8.5
                                  9
9.5
10
                                                    PH
             Graph of free ammonia fraction as a function of temperature and pH
Wastewater Treatment and In-Plant Wet Weather Management
                                                               2-29

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Emerging Technologies
                                       March 2013
  Nutrient Removal
                                  prepared 2012
                     Technology Summary
  Ammonia Recovery (continued)
  Comparison to Established Technologies:
  Several technologies exist to remove ammonia including air and steam stripping as well as vacuum
  distillation. Any of these can be coupled with ammonia recovery as ammonium sulfate. Although the stripping
  technologies have been known since the  1960s they are rarely applied for ammonia recovery because the
  process is not economical. Struvite precipitation processes remove and recover ammonia along with the
  phosphorus target, but the ammonia removal is significantly less when compared to the 90% that is
  removed/recovered with vacuum distillation. Ammonia removal in municipal wastewaters is typically
  accomplished with biological processes that require oxygen, can require supplemental carbon,  and produce
  sludge. Vacuum distillation can be shut down and restarted efficiently, so it is more suited to seasonal
  operation than biological processes for ammonia removal. More concentrated ammonia streams such as
  encountered in some industrial applications use breakpoint chlorination or air- or steam-stripping. Because it
  uses significantly less gas volume and operates at a lower temperature, vacuum distillation systems have a
  much smaller footprint and power requirement than steam or hot air stripping.
  Available Cost Information:
  Approximate Capital Cost: Equipment for 1.2-MGD centrate, approximately $14,000,000 (ThermoEnergy
  Corp, 2012).
  Approximate O&M Costs:  Mainly depend on costs for sodium hydroxide and sulfuric acid consumed in the
  process.
  Vendor Name(s):                             Installation(s):
  ThermoEnergy Corporation (ARP)                  26th Ward WWTP (1.2 mgd centate), New York City,
  323 Center Street                                  NY (2012 startup)
  Little Rock, AK 72201                               Agricultural facility large-scale pilot, Netherlands
  Telephone: 508-854-1628, ext. 302
  Email: info@thermoenergy.com
  Web site: www.thermoenergy.com

  Key Words for Internet Search:
  Vacuum distillation, ammonia recovery, nitrogen recovery, ARP, CASTIon, RCAST

  Data Sources:
  Kemp, Simon, and Brown, United States Patent 7,270,796, September 18, 2007.
  Orentlicher, M. et al. "Centrate Ammonia Reduction with ARP®: Pilot Data with Synthetic and Actual
  Wastewaters," WEF/WERF  Nutrient Removal Specialty Conference, 2009.
  ThermoEnergy Corp, direct communication, 2012.
  Snoeyink, V. and Jenkins, D. Water Chemistry, John Wiley and Sons, New York, NY, 1980.
2-30
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March 2013
                                                                             Emerging Technologies
  Oxidation
                                  updated 2012
                                                                     Technology Summary
                                                   State of Development:
                                                   Emerging.
Objective:
Removal of micro-constituents such as endocrine
disrupters, hormones, Pharmaceuticals, and other
complex organics; disinfection, adsorption of macro-
contaminants such as phosphorus.
Description:
The Blue CAT™ process is a combination of the Blue PRO™ adsorption filter process with an Advanced
Oxidation Process (typically ferric with ozone) for tertiary removal of slowly biodegradable or non-
biodegradable micro-constituents that have passed through upstream treatment processes. The oxidation
process also provides highly effective disinfection without chlorine by-products. The Blue PRO process
provides adsorption of contaminants such as phosphorus in an upflow sand filter with hydrous ferric oxide-
coated media and a proprietary pre-reactor. According to the manufacturer, unpublished pilot studies of the
Blue CAT system have been conducted at 10 gpm. Results of those studies include total organic compound
reduction from 4 to 1.5 mg/L,  a high-percentage reduction of estrogenic compounds and pharmaceutical
surrogates monitored in the studies, color removal disinfection to less than 2 cfu/100 ml, turbidity reduction to
0.1 to 0.3 NTU, and 95 percent total phosphorus removal. The residual Blue CAT wastestream can be
recycled to the head of the plant for additional contaminant removals and other secondary process
enhancements. For increased contaminant-removal rates, destruction of organics, or disinfection, two passes
through Blue CAT can be combined in series.
Comparison to Established Technologies:
Some evidence shows that Blue CAT requires less power than other advanced oxidation processes because
of the system's catalytic configuration to maximize oxidative capability. The only metal salt chemical used is a
small amount of iron reagent (4-10 mg/L Fe) for the Blue  PRO process. No polymer is used. The
manufacturer claims that the process requires lower chemical dosing than typical chemical wastewater
treatment processes and, consequently, produces fewer solids. The iron-based reactive agent also provides
odor control.  Similar to the Blue PRO process, the Blue CAT system is suitable for plants at less than
10 MGD. Because the upflow filters are limited in size, it would be difficult to operate and maintain a facility
treating more than 10 MGD because of the sheer number of modules required for treatment.
Available Cost Information:
Approximate Capital and O&M Costs: Unavailable because no full-scale installation is in place.
Vendor Name(s):                              Installation(s):
Blue Water Technologies, Inc.                     No Blue CAT installations as of August 2012.
10450 North  Airport Dr.
Hayden, ID 83835
Telephone: 888-710-2583
Web site: www.blueh2o.net

Key Words for  Internet Search:
Blue CAT,  catalytic oxidation, ozone, advanced phosphorus removal, endocrine disrupters
Data Sources:
Blue PRO™, "Hydrous Ferric Oxide (HFO) Coated Sand, Adsorptive Media Technical Summary," 2006.
CH2M Hill, Technical Memorandum, "Evaluation of Blue PRO Process at the Hayden Wastewater Research
Facility - Final Summary Report," 2006.
Newcombe, R.L., et al., "Arsenic Removal from Drinking Water by Moving Bed Active Filtration," Journal of
Environmental Engineering, Vol. 132, No.1, pp. 5-12, 2006.
Wastewater Treatment and In-Plant Wet Weather Management
                                                                                            2-31

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Emerging Technologies
                                      March 2013
  Oxidation
                                 updated 2012
                     Technology Summary
  Blue CAT™ (continued)
  Newcombe, R.L., et al., "Phosphorus Removal from Municipal Wastewater by Hydrous Ferric Oxide Reactive
  Filtration and Coupled Chemically Enhanced Secondary Treatment: Part I. Performance," Water Environment
  Research, Vol. 80, No. 3, pp. 238-247, 2008.

  Newcombe, R.L., et al., "Phosphorus Removal from Municipal Wastewater by Hydrous Ferric Oxide Reactive
  Filtration and Coupled Chemically Enhanced Secondary Treatment: Part II. Mechanism," Water Environment
  Research, Vol. 80, No. 3, pp. 248-256, 2008.
2-32
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                                                                               Emerging Technologies

  Preliminary/Primary Treatment   prepared2012                          Technology Summary
   Salsnes Filter
   Objective:                                     State of Development:
   Removal of fine primary solids using a rotating belt     Emerging.
   screen.
   Description:
   The Salsnes filter uses a removable fine mesh screen attached to an inclined moving belt of wire cloth to
   sieve solids from wastewater simultaneously filtering the water and dewatering the solids. The belt rotates to
   an "air knife" for self-cleaning with compressed air to remove the solids to a sludge compartment. In one
   installation, the Salsnes filter has proven to reduce influent BOD and TSS by 40% and 65% respectively
   (McElroy, 2012). Performance depends on the size distribution of influent solids and the size of the mesh
   selected for the filter screen which typically ranges from 100 to 500 microns (Sutton  et al. 2008) although a
   1000 micron mesh screen was installed at the Daphne Utilities WWTF. The screen surface hydraulic loading
   rate is an important factor affecting screen performance. A pressure transmitter varies belt speed to maintain
   liquid level at near the overflow elevation to assure effective flow distribution. The belt is backwashed to
   remove fats, oils, and grease. Filters are available in sizes with capacities up to 2200 gpm for free standing
   units and 3500 gpm for units installed in a concrete channel. Multiple units may be installed in parallel to
   achieve the desired capacity. A dewatering screw press is available to transport the  solids, and when used
   can produce sludge at up to 27% solids (Sutton 2008).
   Comparison to Established Technologies:
   The Salsnes filter's BOD and solids removal performance is equal to or better than traditional primary
   clarifiers (McElroy, 2012 and Sutton, 2008). According to the manufacturer, land requirements are
   approximately 1/10th that of primary clarifiers. Solids  removed with the Salnes filter and screw press are
   significantly drier than for a primary clarifier, typically 27% and 4% respectively.

   Available Cost Information:
   Approximate Capital and O&M Costs: Capital cost is estimated at 30-50% less than for primary clarifiers
   Vendor Name(s):                             Installation(s):
   Salsnes Filter AS, Verftsgt. 11                      Daphne Utilities WWTF, Daphne AL
   7800 Namsos, Norway
   Telephone: +47 74 27 48 60
   Web site: www.salsnes.com
   Trojan Technologies
   (US Representative)
   3020 Gore Road
   London, Ontario Canada, N5V4T7
   Telephone: 1 8882206118 (US/CAN)
   Web site: www.trojanuv.com

   Key Words for Internet Search:
   Salsnes filter, primary treatment, fine screen,  rotating belt screen
   Data Sources:
   McElroy, R. et al., "Restoring Lost WWTP Capacity through Innovative Technologies", WEFTEC 2012.
   Sutton, P. et al. "Rotating Belt Screens: An Attractive Alternative for Primary Treatment of Municipal
   Wastewater" WEFTEC 2008.
Wastewater Treatment and In-Plant Wet Weather Management                                             2-33

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-------
 Chapter
Biological Treatment  Processes
  3.1  Introduction
       Biological treatment processes are systems that use microorganisms to degrade organic
       contaminants from wastewater.  In wastewater treatment, natural biodegradation processes
       have been contained and accelerated in systems to remove organic material and nutrients. The
       microorganisms metabolize nutrients, colloids, and dissolved organic matter, resulting in
       treated wastewater.  Excess microbial growth is removed from the treated wastewater by
       physical processes.

       Biological processes are the preferred way of treatment as they are cost effective in terms of
       energy consumption and chemical usage. For example, biological nutrient removal (BNR) has
       emerged as the preferred approach for nutrient removal. BNR processes involve modifications
       of biological treatment systems so that the microorganisms in these systems can more
       effectively convert nitrate nitrogen into inert nitrogen gas and trap phosphorus in solids that are
       removed from the effluent.  I FAS (Integrated Fixed-film Activated Sludge, MBBR (Moving Bed
       Bio-Reactor), and MBR (Membrane Bio-Reactor) processes have all become established
       technologies for situations where reactor volume is at a premium and are particularly well
       suited to BNR applications. In the last several years, nitritation/denitritation and
       deammonification processes have made the transition from Europe and are beginning to be
       implemented at large US utilities.
  3.2  Technology Assessment
       Table 3.1 presents a categorized list of established, innovative, emerging and research
       biological treatment process technologies. The list includes most established biological
       treatment processes and recent developments in cost-effective methods to retrofit older
       systems or result in systems with smaller footprints. Experience with operation of biological
       systems and the ongoing effort to maximize process performance have resulted in modification
       or development of several biological treatment processes that warrant discussion in this
       chapter on innovative, adaptive use, emerging, and research technologies. Generally,  the
       improvements in established biological treatment processes provide treatment of recycle
       streams, optimize recycle, and maximize nutrient-removal capabilities.

       Selecting and classifying technologies for inclusion in this report was a challenging task.
       Biological processes in particular are constantly evolving such that in many cases the same
       process configuration will be known under two or more names or the same name may be
       applied to slightly different process configurations. Rather than adopting a defined and named
       configuration, current practice is to use modern process modeling to develop a site specific
       process configuration. Consequently, skilled practitioners can apply the fundamentals of
       process engineering to develop an essentially infinite range of site specific process
Wastewater Treatment and In-Plant Wet Weather Management
3-1

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Emerging Technologies
                                     March 2013
       configurations beyond those presented in this report. Future updates to this report will no doubt
       rename, reclassify, or even remove some of the process configurations currently included as
       the report evolves to keep up with the technology developments and engineering  practice.

       An evaluation of the innovative technologies identified for biological treatment processes
       relative to their state of development, applicability, potential for effluent reuse and the potential
       benefits of the technology is presented in Figure 3.1. Summary sheets for each innovative,
       adaptive use, emerging, and research technology are provided at the end of the chapter. The
       innovative technologies are: Bioaugmentation, Deammonification, Nitritation/Denitritation,
       Deep-Shaft Activated Sludge/VERTREAT™, Cyclic Metabolic Environment and Magnetite
       Ballasted Activated Sludge processes. The adaptive use technologies are: the Biological-
       Chemical  Phosphorus and Nitrogen Removal (BCFS) Process, the Modified University of Cape
       Town (MUCT) Process, the Westbank Process, and the Modified Anaerobic/Oxic (A/O)
       Process. These processes have various configurations and modules to fit the specific needs of
       any individual treatment plant. Most of these technologies can be  easily retrofitted into existing
       treatment  systems that enable treatment processes to achieve better nutrient removal.

       Emerging  technologies included at the end of this chapter are: Membrane Biofilm Reactor
       (MBfR), Vacuum Rotation Membrane (VRM), OpenCel Focused Pulse, Integrated Fixed-film
       Activated Sludge (IFAS) Systems with Biological Phosphorus Removal, Multi-Stage Activated
       Biological  Process (MSABP™) and Aerobic Granular Sludge Process (AGSP). Three
       technologies in the research stage of development are included: Anaerobic Migrating Blanket
       Reactor (AMBR®), Anaerobic Membrane BioReactor (An-MBR), and Microbial Fuel Cell (MFC)
       Based Treatment System.
Kr
in
Th
cc
ar
lowledge about technologies tends to evolve. The information provides a snapshot at a point
time; what is understood at one point in time may change as more information develops.
lis includes knowledge about operating mechanisms as well as the relative and absolute
sts and features of a particular technology. Inquiries into the current state of knowledge are
i important step when considering implementation of any technology.
Table 3.1 — Biological Treatment Processes - State of Development
Established Technologies (technology summaries not included)
Anaerobic Processes
Anaerobic Attached Growth System
- Upflow Packed-Bed Attached Growth Reactor
- Upflow Attached Growth Anaerobic
- Expanded-Bed Reactor (Anaerobic Expanded Bed Reactor [AEBR])
- Downflow Attached Growth Process
Anaerobic Contact Process
Anaerobic Sequencing Batch Reactor (ASBR®)
Upflow Anaerobic Sludge Blanket (UASB)
ANFLOW (ANaerobic FLuidized Bed Reactor)
BOD Removal and Nitrification
Biolac-Aerated Lagoon
Complete Mix-Activated Sludge (CMAS) Process
Contact Stabilization
Conventional Extended Aeration

3-2
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March 2013
Emerging Technologies

Table 3.1 — Biological Treatment Processes - State of Development
Established Technologies (technology summaries not included) (continued)
Countercurrent Aeration System (CCAS™)
Cyclic Activated Sludge System (CASS™)
Facultative and Aerated Lagoons
High-Purity Oxygen (HPO)
Intermittent Cycle Extended Aeration System (ICEAS™)
Kraus Process
Oxidation Ditch/Aerated Lagoons
Sequencing Batch Reactor (SBR)
Staged Activated-Sludge Process
Step Feed
Biofilm Processes
Biological Aerated Filters (BAF)
- Biofor®
- Biostyr®
Fluidized Bed Bioreactor (FBBR)
Integrated fixed-Film Activated Sludge (IFAS)
- I FAS - Submerged Mobile Media
- I FAS -Submerged Fixed Media
Moving-Bed Bio Reactor (MBBR) Process
Rotating Biological Contactor (RBC)
Submerged Rotating Biological Contactor (SRBC)
Trickling Filter (TF)
Trickling Filter /Solids Contactor (TF/SC)
Nitrogen Removal
Bardenpho® (Four Stage)
BiodenitroTM
Denitrification Filter
Ludzack-Ettinger
Modified Ludzack-Ettinger (MLE)
OrbalTM Process
SchreiberTM Process
Simultaneous Nitrification denitrificatioN (SNdN) Process
Step Feed (Alternating Anoxic and Aerobic)
Wuhrman
Nitrogen and Phosphorus Removal
Anaerobic/Anoxic/Oxic (A2/0)
Bardenpho® (Five Stage)
Johannesburg Process
Step Feed BNR Process
University of Cape Town (UCT)
Virginia Initiative Plant (VIP)

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                 3-3

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Emerging Technologies
                                          March 2013

Table 3.1 — Biological Treatment Processes - State of Development
Established Technologies (technology summaries not included) (continued)
Phosphorus Removal
Phoredox (Anaerobic/Oxic [A/0])
Phostrip
Membrane Processes
Membrane Bioreactor (MBR)
- Tubular
- Hollow-Fiber
- Spiral Wound
- Plate and Frame
- Pleated Cartridge Filters
. .. T . . . Summary on
Innovative Technologies page
Bioaugmentation
Bioaugmentation 3-7
- External Bioaugmentation
- Seeding from Commercial Sources of Nitrifiers
o In-Pipe Technology
o Trickling Filter and Pushed Activated Sludge (TF/PAS) Process
o Seeding from External Dispensed Growth Reactors Treating
Reject Waters (Chemostat Type)
o In-Nitri® Process
o Immobilized Cell-Augmented Activated Sludge (ICASS) Process
o Seeding from Parallel Processes
o Seeding from Downstream Process
- In Situ Bioaugmentation
o DE-nitrification and Phosphate accumulation in ANOXic
(DEPHANOX) Process
o Bio-Augmentation Regeneration/Reaeration (BAR) Process
o Bio-Augmentation Batch Enhanced (BABE) Process
o Aeration Tank 3 (ATS) Process
o Main stream AUtotrophic Recycle Enabling Enhanced N-removal
(MAUREEN) Process
o Regeneration DeNitrification (R-DN) Process
o Centrate and RAS Reaeration Basin (CaRRB) Process
Nitrogen Removal
Deammonification (Sidestream and Mainstream Deammonification and Mainstream 3-16
Nitrite Shunt)
Nitritation and Denitritation (Sidestream) 3-19
Small Site
Deep-Shaft Activated Sludge/VERTREAT™ 3-22
Solids Minimization
Cyclic Metabolic Environment 3-23


3-4
Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
Emerging Technologies
             Table 3.1—Biological Treatment Processes - State of Development
Innovative Technologies (continued)
Summary on
page
Solids Settleability
Magnetite Ballasted Activated Sludge
Adaptive Use Technologies
3-25
Summary on
page
Nitrogen and Phosphorus Removal
Biological-Chemical Phosphorus and Nitrogen Removal (BCFS) Process
Modified University of Cape Town (MUCT) Process
Westbank Process
3-27
3-29
3-30
Phosphorus Removal
Modified Anaerobic/Oxic (A/0) Process
Emerging Technologies
3-31
Summary on
page
Membrane Processes
Membrane Biofilm Reactor (MBfR)
Vacuum Rotation Membrane (VRM®) System
3-32
3-34
Nitrogen Removal
OpenCel Focused Pulse
3-35
Nitrogen and Phosphorus Removal
Integrated Fixed-film Activated Sludge (IFAS) with Biological Phosphorus Removal
3-36
Solids Minimization
Multi-Stage Activated Biological Process (MSABP™)
3-37
Solids Settleability
Aerobic Granular Sludge Process (AGSP)
Research Technologies
3-38
Summary on
page
Anaerobic Processes
Anaerobic Migrating Blanket Reactor (AMBR®)
Anaerobic Membrane BioReactor (An-MBR)
3-41
3-43
Electricity Generation
Microbial Fuel Cell (MFC) Based Treatment System
3-45
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               3-5

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Emerging Technologies
                                                                    March 2013
                                                    Bioaugmentation
  Bioaugmentation
                                         N,0
                   C,0
                                        In
                                                   Nitrogen Removal
  Deammonification
                                         0,P
          F,L
       0,S
  Nitritation/Denitritation
                                         0, N
          F,L
       0,S
                                                       Small Site
  Deep-Shaft Activated
  Sludge/VERTREAT™
 M,N,
   0
       C,0
                                  In
e
                                                   Solids Minimization
  Cyclic Metabolic Environment
  M, N
       M, N
                                  In
                                                   Solids Settleability
  Magnetite Ballasted Activated Sludge
  M, N
I
C,l,0
  Key
         .ement of Development
     B = Bench scale
     I = Full-scale industrial applications
     M = Full-scale municipal applications
     0 = Full-scale operations overseas
     P = Pilot
     N = Full-scale operations
       in North America
F = Few plants
I = Industrywide
L = Primarily large plants
S = Primarily small plants
                           Potential Benefits
            C = Capital savings
            I = Intense operational demand
            0 = Operational/maintenance savings
            S = Shock load capacity
            W = Wet weather load capacity
            E = Effluent quality
                                              Effluent Reuse
                                     Dp = Direct potable
                                     Dn = Direct nonpotable
                                     Ip = Indirect potable
                                     In = Indirect nonpotable
                                                                  Comparative Criteria
                                                                    A Positive feature
                                                                    0 Neutral or mixed
                                                                    T Negative feature
             Figure 3.1—Evaluation of Innovative Biological Treatment Technologies
3-6
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March 2013
                                                                                Emerging Technologies
  Bioaugmentation
                                  updated 2012
Technology Summary
  Bioaugmentatio.
                                                    State of Development:
                                                    Innovative.
Objective:
To increase treatment capacity by adding bacteria to
the bioreactor or upstream of the treatment reactor.
Most frequently used to enhance nitrification, thereby
allowing more reactor volume to be used for
denitrification or phosphorus removal. Can also be
used to decrease influent loadings. Note: This fact
sheet addresses biological additives and does not
include chemical or enzymatic additives.
Description:
Providing active biomass to the influent of any activated sludge process provides a lower effluent substrate
(i.e., chemical oxygen demand [COD], ammonia-N) concentration for any particular solids retention time
(SRT). Such bioaugmentation also prevents the phenomenon known as washout because the reactor will
contain active biomass even if the wasting rate exceeds the growth rate. Consequently, bioaugmentation is
used to stabilize biological processes that would otherwise be unsustainable at the SRT allowed by the
available reactor volume. This is particularly true for nitrification processes that operate at relatively slow
growth rates and require long SRTs for stability. In nitrifying systems, the need for an aerobic SRT sufficient to
nitrify determines the aeration basin volume. By using bioaugmentation to reduce the required SRT, the
capacity of the aeration basin is increased or the aerobic volume can be reduced. Reducing aerobic volume
by converting a portion of the basin to anoxic or anaerobic operation can allow conversion to a biological
nutrient removal (BNR) process without additional reactor tankage. Two types of bioaugmentation schemes
can be used: (1) external bioaugmentation and (2) in situ bioaugmentation. External bioaugmentation  includes
adding external-source nitrifiers; in situ bioaugmentation provides internal process enhancements that
increase activity or enrich nitrifier population. The advantage of external bioaugmentation schemes is that the
promotion  of nitrification in the mainstream process can be decoupled from its aerobic SRT. The advantage of
in situ schemes is  that there is less concern  about the loss of activity of the seed nitrifiers when transferred to
the mainstream process because their conditions of growth (i.e., temperature, osmotic pressure) are similar to
those prevalent in  the mainstream process.

External Bioaugmentation
Examples  of external bioaugmentation include seeding from commercial sources of nitrifiers, Trickling Filter
and Pushed Activated Sludge (TF/PAS) process, seeding from  external dispersed growth reactors treating
reject waters, seeding from external activated sludge reactors treating reject waters, seeding from  parallel
processes, and seeding from downstream processes. Some facilities having both air-activated sludge
systems and high-purity oxygen systems have proven that nitrification in the high-purity oxygen can be
significantly enhanced by seeding with nitrification solids from the parallel aerated BNR system. This
procedure is not patented. External bioaugmentation is performed in Hagerstown, Maryland, Henrico County,
Virginia, and Hopewell, Virginia. Note, nitrification in high-purity oxygen plants is typically limited by pH
inhibition.
Seeding from  Commercial Sources of Microorganisms: Although early attempts at bioaugmentation with
commercial seed sources in waste water treatment plants (WWTPs) produced controversial  results,
bioaugmentation for nitrification has readily measurable success. Adding external nitrifiers' sources has
shown some success at both laboratory and field scale and allows operation at colder temperatures where
nitrifiers would  normally wash out, but required dosages of the nitrifiers were very high. Therefore,  most
investigators diverted to onsite production of seed organisms in the treatment plant. One exception is the
seeding microorganisms directly to the sewer system known as In-Pipe Technology.
Wastewater Treatment and In-Plant Wet Weather Management
                                                                                                 3-7

-------
Emerging Technologies
                                                        March 2013
  Bioaugmentation
updated 2012
Technology Summary
  Bioaugmentation (continued)
  In-Pipe Technology Process: This approach uses facultative microorganisms added to the sewer system
  upstream of the treatment facility with the goal of supplementing/modifying the biofilm on the walls of the
  sewer pipe. Using bioaugmentation in this way, the sewer is intended to become a part of the treatment
  process by reducing organic loading to the WWTP and transforming slowly degradable COD to readily
  degradable COD. Because sewer conditions generate relatively low sludge yield, waste activated sludge is
  decreased. Shearing of active biomass from the sewer walls provides indirect bioaugmentation to the
  downstream WWTP but would not include any significant nitrifier content.  However, reducing COD loading
  and waste activated sludge  production would result in an increased nitrifier fraction and an increased SRT for
  a given aerobic volume, thereby increasing nitrification capacity. In-Pipe Technology  uses dosing units
  installed  at strategic locations in the sewer system and resupplies them with concentrated microbial stock for
  a monthly fee per MGD treated.
  Trickling Filter and Pushed Activated Sludge (TF/PAS) Process: The  earliest example of external
  bioaugmentation with nitrifiers generated in the plant  from a wastewater source is likely that of the TF/PAS
  process, whereby the total organic loading on the trickling filter is adjusted to achieve about 50 percent
  nitrification, thus seeding nitrifiers to a downstream activated sludge step with a low SRT of 2 to 4 days. It
  appears that the enhanced nitrification rates achieved could be because of both the effect of seeding and
  removing toxicants in the wastewater by pretreatment of the trickling filter.
               Trickling Filter
                                          TF Partly Nitrifies, Seeding
                                          Nitrifiers to Activated Sludge Step
                                                                       Second C la rifier

              Process Flow Diagram for Trickling Filter/Pushed Activated Sludge
3-8
               Wastewater Treatment and In-Plant Wet Weather Management

-------
March 2013
                                             Emerging Technologies
  Bioaugmentation
updated 2012
Technology Summary
  Bioaugmentation (continued)
  Seeding from External Dispersed Growth Reactors Treating Reject Waters (Chemostat Type): Some
  success has been reported with chemostats seeding batzch reactors simulating mainstream processes.
  Nitrifiers grown in batch-fed, sidestream chemostats are more effective in stimulating the process efficiency in
  the simulated mainstream reactors than are those grown in continuously fed chemostats. It has been shown
  that the specific nitrifier types grown in the sidestream chemostats are able to replace the microbial population
  in the mainstream reactors, suggesting that population diversity leads to more robust mainstream reactors.

                                                                       Clarifier
Primary
Effluent

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                                   Return Activated Sludge
                                                                               Waste Sludge
                                          Equalized Ammonia Laden
                                          Filtrate From Dawaterirg
                Dbpersed Growth Reactor (e.g, SHARON Process}

             Process Flow Diagram for Seeding from External Dispersed Growth
Wastewater Treatment and In-Plant Wet Weather Management
                                                             3-9

-------
Emerging Technologies
                                                                       March 2013
  Bioaugmentation
              updated 2012
                        Technology Summary
  Bioaugmentation (continued)
  In-Nitri® Process: A patented process known as the Inexpensive Nitrification or In-Nitri® process uses a
  separate activated sludge process (aeration tank and clarifier) to treat the ammonia-rich sidestream from
  digester supernatant ordewatering. Compared to the mainstream, the sidestream has a much greater
  ammonia-N:COD ratio and usually a higher temperature, a nitrifying SRT can be maintained in a much
  smaller aeration basin. Further, the excess sludge from the sidestream system acts to augment the nitrifiers in
  the mainstream aeration tank. With the nitrifier bioaugmentation from the sidestream, the SRT required to
  achieve  nitrification in the mainstream reactor is reduced. The process  has the advantage of achieving year-
  round nitrification by  reducing the SRT by adding only a small aeration tank and clarifiers for growing nitrifiers.
          Raw
          Wastewater
  Primary
Sedimentation
   Tank
                     Primary Sludge
                      Thickening
Aeration
 Tank
                                        Thickened
                                        Primary
                                        Sludge
                                      Nitrified
                                      Dewatering
                                      Liquid
 Secondary
Sedimentation
   Tank
Treated
Ef-'Leit
                                Excess
                                Nitrification
                                Sludge
                         WAS
                       Thickening
                                                        Supernatant
                                                          Dewaterirg
                                                          Return
                                                          Stream
                                                    Sludge
                                                   De watering
                                                   "
                                                   Alkalinity
                                                   Sludge for
                                                    Disposal
                       Process Flow Diagram for Inexpensive Nitrification


  Immobilized Cell-Augmented Activated Sludge (ICAAS) Process: Immobilized cells are maintained for a
  specific treatment activity and are enriched in a reactor for bioaugmentation. The ICAAS process employs the
  immobilized cells that are activated and maintained for their specific treatment activity in an offline enricher
  reactor for bioaugmentation. The process  has been effectively used in bench-scale reactors for treating
  hazardous-compound shock loads, to achieve enhanced nitrate removal and to increase general performance
  of the treatment process.
  Seeding from Parallel Processes: Two schemes have been proposed to grow nitrifiers in a membrane
  bioreactor and seed a high-rate BNR process. However, results on pilot or full-scale trials have not yet been
  reported. Another approach included two parallel activated-sludge processes, tertiary nitrifying membrane
  bioreactor seeding paralleling a high-rate activated sludge process. Some process issues in this scheme are
  that membranes select for filtering,  not settling biomass; seeding effectiveness is likely affected by predation;
  and the process fits only some nutrient-removal flow diagrams.
3-10
                              Wastewater Treatment and In-Plant Wet Weather Management

-------
March 2013
                                                        Emerging Technologies
  Bioaugmentation
         updated 2012
                     Technology Summary
  Bioaugmentation (continued)
  Seeding from Downstream Process: This seeding process was developed for the main treatment plant in
  Vienna, Austria. The plant uses two stages of activated sludge in which the first stage is operated at a short
  (2-4 day) SRT and the second stage is operated at a long SRT for nitrification/denitrification. In this scheme,
  nitrifying mixed liquor is wasted from the second stage to the first stage, resulting in some nitrification in the
  first stage. Under normal circumstances'! 0 to 40 percent of the influent is bypassed to the second stage to
  provide carbon for denitrification. A similar process is operated at the Howard F Curren WWTP in Tampa
  Florida where the first stage operates as a high purity oxygen activated sludge process receiving WAS from
  the second stage nitrification process thereby providing some nitrification in the first stage.

  In Situ Bioaugmentation
  Separate-stage nitrification processes,  in which carbon is removed in an initial biological stage and then
  followed by a separate-stage nitrification process, are the first examples of in situ bioaugmentation. A three-
  sludge system incorporating separate-stage nitrification was promoted as a preferred technology in 1970s.
  The main reason for this was that the separate steps of carbon removal, nitrification, and denitrification could
  each be optimized. Fixed-film systems  have also been used for separate stage nitrification. The purpose of
  these systems was threefold: (1) use of media with high-mass-transfer rates; (2) use of recirculation to
  improve media-wetting and gain maximum nitrifying biofilm coverage and minimization of influent solids to
  avoid competition for oxygen from heterotrophs; and (3) the control of predators with flooding and alkaline
  treatment.
  DE-nitrification and Phosphate accumulation in ANOXic (DEPHANOX) Process: This process includes a
  combination of suspended growth  and fixed-film systems in separate stages. DEPHANOX is based on the
  phenomenon of simultaneous denitrification and phosphate accumulation in the anoxic zone. The solids
  removed at the primary settling tank are combined with the nitrified wastewater to provide the carbon source
  required for denitrification. The nitrification stage is a biofilm  reactor in standard DEPHANOX applications. A
  modified approach is to use a suspended biomass reactor for nitrification but to follow it with a clarifier so that
  the nitrifying biomass is kept separate from the phosphorus accumulating and denitrifying biomass.
     Influent
/Primary \
  Settling
   Tank
                                       Nitrification
Oenitrification
                                               HAS
                                                                                  WAS
                         Process Flow Diagram for DEPHANOX Process

  Bio-Augmentation Regeneration/Reaeration (BAR) Process: In the Bio-Augmentation R Process, in the
  Czech Republic the R stands for regeneration zone, and in the United States the R stands for reaeration. The
  BAR process simply recycles the ammonia-laden filtrate or centrate from dewatering of aerobically digested
  sludge to a reaeration (regeneration) tank and receives the entire return activated sludge flow into an aeration
  tank. The high ammonia concentration and elevated temperature in that tank promote nitrification and develop
  a concentrated culture of nitrifiers. The mixed liquor from the reaeration (regeneration) zone flows to the
  aeration basin properly seeding it with nitrifiers. A key difference between the BAR process and In-Nitri  is that
  introduction of returned activated sludge (RAS) from the mainstream reactor allows the seed nitrifiers to be
  incorporated into already well-developed floes, thereby providing some protection against environmental
Wastewater Treatment and In-Plant Wet Weather Management
                                                                       3-11

-------
Emerging Technologies
                                                      March 2013
  Bioaugmentation
updated 2012
Technology Summary
  Bioaugmentation (continued)
  shock when they enter the main aeration basin. The lack of a clarifier or other means to concentrate the
  biomass concentration in the nitrifier seed reactor reduces the degree of control that is available using In-Nitri.
  The BAR process was independently developed in the United States and Czech Republic.
                         Primary Effluent
                                                                   Clanfier

                               Vat
                                         t
                                          °To»
V
•••. •«•• %
'? •sj: •-:
•? cr?
' "f
^
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p=^
Waste Sli
                ^—^^  Equalized Ammonia Laden
                         Filtrate From Dewatenng

                            Process Flow Diagram for BAR Process

  Bio-Augmentation Batch Enhanced (BABE) Process: The patented BABE process is composed of a
  sequencing batch reactor (SBR) that is fed with the reject water from the sludge dewatering process and a
  portion of the RAS from the treatment system. The BABE process is similar to the BAR process, but
  configuring the nitrifying seed reactor as an SBR provides a means to control the biomass concentration
  there. Longer sludge age can be achieved in the SBR tank, which helps the nitrifying bacteria to adapt and
  grow in the BABE reactor. The SBR follows the phases of the standard treatment cycle, i.e., fill and aerate,
  react, settle, and waste.

A '.




Activated
Sludge Tank
RAS
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>

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Secondary Efflue


                               Nitrifiers (NO3-N)
                                                                                  WAS
                                                                          Centrate (NH3-N)
                                Flow Diagram for BABE Process
3-12
               Wastewater Treatment and In-Plant Wet Weather Management

-------
March 2013
                                              Emerging Technologies
  Bioaugmentation
updated 2012
Technology Summary
  Bioaugmentation (continued)
  Aeration Tank 3 (ATS) Process: The ATS process is similar to BAR process but differs in sending a smaller
  fraction of the RAS to the reaeration tank, and it has a downstream anoxic zone. The process goal is to stop
  the nitrification process at the nitrite stage (nitritation) by control of dissolved oxygen and pH to reduce the
  consumption of carbon and oxygen for complete denitrification. Adding an external carbon source at the
  anoxic zone might be needed to accomplish denitrification.
  Mainstream AUtotropic Recycle Enabling Enhanced N-removal (MAUREEN) Process: The MAUREEN
  process includes a sidestream bioreactorto allow for nitrification and  denitrification of the centrate stream.
  The configuration is similar to the  ATS process but has biomass recycling at the sidestream reactor. This
  process was developed for the Blue Plains Advanced Wastewater Treatment Plan  (AWTP) and provides
  significant flexibility when applied  to the two-sludge system at the plant. The configuration includes
  preferential bioaugmentation of ammonia-oxidizing bacteria from the second to the first stage via the
  sidestream reactor and oxidation of ammonia in reject centrate to nitrite in the enrichment reactor, resulting in
  reduced power and chemical consumption. This process has the ability to fortify the second-stage system with
  a combination of primarily ammonia oxidizers and anoxic methanol-degrading bacteria produced in the
  sidestream reactor under conditions that would limit the presence of nitrite-oxidizing bacteria and
  heterotrophic bacteria. Supernatant from the sidestream process can be used for odor and corrosion control
  in the headworks or in process streams at the plant. Key to the success of the process is the physical
  configuration and selection of operating conditions of the sidestream  reactor.
                                                                 WAS
                                                                 Nitrifiers and Methanol
                                                                 Using Dentrifiers
                                                     Return Liquor (Centrate;
                                    Alkalinity I
                                  Methanol
                         Process Flow Diagram for MAUREEN Process
Wastewater Treatment and In-Plant Wet Weather Management
                                                             3-13

-------
Emerging Technologies
                                                      March 2013
  Bioaugmentation
updated 2012
Technology Summary
  Bioaugmentation (continued)
  Regeneration-DeNitrification (R-DN) Process: The R-DN process is identical to BAR process and involves
  filtrate or centrate bioaugmentation. It was independently developed in the Czech Republic and the United
  States.
  Centrate and RAS Reaeration Basin (CaRRB) Process: Another named process that is identical to the
  BAR and R-DN processes.
  Comparison to Established Technologies:
  Bioaugmentation processes can be used to reduce the bioreactor volume of many mainstream treatment
  processes. In general they reduce the loading to the mainstream plant by pretreating the high-strength recycle
  flow while providing the mainstream plant with seed organisms generated in the sidestream reactor.
  Depending on the needs of the mainstream process, the sidestream process can be configured to augment
  populations of both nitrifiers and denitrifiers. The biomass generated by the sidestream reactor allows the
  mainstream reactor to be smaller in volume while providing the required SRT. The reduction in required
  volume can allow a portion of the basin volume to be converted to provide denitrification or phosphorus
  removal. By pretreating the sidestream before blending into the mainstream process, loading and
  performance can be stabilized.
  Available Cost Information:
  Approximate Capital Cost: Cost information is not available from vendors. However, bioaugmentation
  processes save capital costs in the main treatment systems because of reduced reactor volumes via the
  augmentation of nitrifying bacteria.
  Approximate O&M Costs: The operating costs are mainly related to mixing and  aeration requirements and
  depend on local conditions and the available equipment. Bioaugmentation processes also save operating
  costs in the main treatment through the augmentation  of nitrifying bacteria. Actual costs were not disclosed.
  Vendor Name(s):
  In-Pipe Technology
  100 Bridge Street
  Wheaton, IL60187
  Telephone: 630-871-5844
  Email: jelliott@in-pipe.com
  Web site: www.in-pipe.com

  DHV Water BV, BABE Process
  P.O. Box 484
  3800 AL Amersfoort, The Netherlands
  Telephone: 0031-33-468-2200
  Email: info@wa.dhv.nl
  Web site: http://www.dhv.com/water/

  M2T (Mixing and Mass Transfer Technologies),
  In-Nitri  Process
  P.O. Box 315
  State College, PA 16804
  Telephone: 814-466-6994 or 888-715-9600
  Email: info@m2ttech.com
  Web site: http://m2ttech.com/index.asp
                Installation(s):
                In-Pipe Technology: 38 active applications as of
                2012 including Orange Park, FL; Missouri City, TX;
                Leesport, PA; Jackson, MS; Plymouth, MA; Ft
                Dodge, IA; Huntington, NY; Maricopa, AZ; Spring
                Valley, IL; Charles County, MD; Crown Point, IN;
                Suffolk County, NY

                TF/PAS  Process: Central Valley WRF Utah;
                Melrose, MN

                In-Nitri Process: Richmond, VA; Harrisburg, PA
                pilot, Tucson, AZ pilot

                BAR (R-DN, CaRRB) Process: Appleton WWTP,
                Wl; Theresa Street WWTP, Lincoln, NE; Hite
                WWTP, Denver, CO; Blue Lake WWTP, Shakopee,
                MN; Woodward Ave WWTP, Hamilton, Ontario,
                Canada; and 20 plants in the Czech Republic

                ATS Process: 26th Ward WWTP, Hunts  Point
                WWTP, Bowery Bay WWTP New York City, NY

                BABE Process: Hertozenbosch Netherlands,
                Garmerwolde Netherlands

                MAUREEN Process: Blue Plains AWTP,
                Washington, DC
3-14
              Wastewater Treatment and In-Plant Wet Weather Management

-------
March 2013
                                            Emerging Technologies
  Bioaugmentation
updated 2012
Technology Summary
  Bioaugmentation (continued)
  Key Words for Internet Search:
  Bioaugmentation, In-Pipe Technology, BABE process, InNitri
  Data Sources:
  Law, K. and Stinson, B., "Sidestream Treatment Overview," IWEA Watercon, 2012.
  Katehis, D., et al. "Nutrient Removal from Anaerobic Digester Side-Stream at the Blue Plains AWTP,"
  WEFTEC, 2006.
  Salem, S., et al. "Bio-augmentation by Nitrification with Return Sludge," Water Research, Vol. 37, pp. 1794-
  1804,2003.
  Constantine, T.A., et al., "New Nitrifier Bioaugmentation Process Configure to Achieve Year Round
  Nitrification at Low SRTs," Proceedings of WEFTEC, 2001.
  Daigger, G.T., et al., "Incorporation of Biological Nutrient Removal (BNR) into Membrane Bioreactors
  (MRBs)," Proceedings of the International Water Association (IWA) Specialized Conference on Nutrient
  Management in Wastewater Treatment Processes and Recycle Streams, Krakow, Poland.
  Katehis, D., et al., "Enhancement of Nitrogen Removal Thru Innovative Integration of Centrate Treatment,"
  WEFTEC, 2002.
  Parker, D.S., and J. Wanner, "Improving Nitrification through Bioaugmentation," WEF, Nutrient Removal
  Conference, 2007.
  Parker, D., Brown, and Caldwell, "Nutrient Removal, How low can we go and what is stopping us from going
  lower? Improving Nitrification through Bioaugmentation," WERF Presentation, 2007.
  Stensel, H.D, "Sidestream Treatment for Nitrogen Removal," 11th Annual Education Seminar Central States
  Water Environmental Association, 2006.
  http://m2ttech.com/index.asp
  http://www.dhv.com/water/
Wastewater Treatment and In-Plant Wet Weather Management
                                                           3-15

-------
Emerging Technologies
                                                                                       March 2013
  Nitrogen Removal
                                 prepared 2012
Technology Summary
  Deammonification (Sidestream and  Mainstream Deammonification and
  Mainstream Nitrite Shunt)
  Objective:
  Biological nitrogen removal from high-strength
  streams (e.g., sludge liquors, landfill leachate).
                                                 State of Development:
                                                 Innovative (Sidestream Deammonification) and
                                                 Emerging/Research (Mainstream Deammonification
                                                 and Mainstream Nitrite Shunt).
Description:
The deammonification process (Sidestream) involves removing ammonia in a two step process that
requires initial partial nitritation to convert approximately 50 percent of the ammonia to nitrite. Anaerobic
ammonia oxidation (Anammox) bacteria convert the nitrite and the remaining ammonia to nitrogen gas under
anoxic conditions. The process requires only partial nitritation, which theoretically reduces the energy demand
up to 63 percent compared to conventional nitrification and denitrification. The deammonification process is a
completely autotrophic process and does not require any supplemental carbon.
Mainstream deammonification and mainstream nitrite shunt are two emerging/research technologies that
offer much promise. Beyond the savings in aeration energy and supplemental carbon associated with
Nitrogen removal, is the dramatic energy benefit of redirecting wastewater carbon to anaerobic processes for
energy generation, as well as the BNR process volume benefit associated with keeping the carbon out of that
system and the additional aeration energy benefit of the same.
Example processes - DEMON®, SHARON-ANAMMOX, ANAMMOX® Paques, ANITA-Mox, DeAmmon
Where is it applied - The deammonification process has  been successfully implemented as a Sidestream
process for treating centrate and filtrate recycle streams from dewatering anaerobically digested biosolids,
with over 20 first generation municipal and industrial processes operational in Europe. The relatively high
temperature and high ammonia concentrations typically found in these recycle flows make them ideal
candidates for this process. Deammonification  has not yet been installed in the main liquid stream process at
full scale due to the difficulty in inhibiting nitrite  oxidizing bacteria (NOB) growth, the relatively lower tempera-
ture and ammonia concentration, and the need for selective retention of Anammox bacteria. However, a full-
scale full-plant deammonification demonstration has been  installed at the Strass WWTP in Austria where a
Sidestream deammonification process can provide seed for bioaugmentation in the full-plant testing. Pilot
scale testing of full-plant deammonification is also being implemented at plants in Washington DC  and
Virginia.
Process Controls - The main process controls are solids retention time (SRT), pH, dissolved oxygen,
temperature, and nitrite concentration. Aeration mode (continuous vs. intermittent) and whether to  use
innoculum of Anammox bacteria are also used  in process control as competition for oxygen  between
ammonia oxidizing bacteria (AOB) and NOB is  controlled by DO level and aeration time and regimen.
Monitoring the biomass is also used  for volatile suspended solids content as well microscopic analysis as
indicators of efficient operation. The  control of the deammonification process is similar to the nitritation and
denitritation process because NOB growth must be inhibited. In addition, the deammonification process must
have adequate SRT. The growth rate of anammox bacteria is extremely slow (approximately 13 times slower
than  nitrifying autotrophs), which requires special attention to SRTs in the deammonification reactors to
prevent anammox washout. Anammox bacteria tend to grow as relatively heavy granules, which allows for the
possibility of separating anammox bacteria from other ammonia oxidizing bacteria (AOB) and NOB. The use
of cyclone (such as in the DEMON®  process), or through the controlled granular size (such as in the
ANAMMOX® Paques process) allows for separate control of the anammox SRT (must be more than 30 days)
while maintaining optimal SRTs for AOB growth (typically between 2 to 3 days).
Configurations - Several process configurations are used for the deammonification process. Paques has
both  the two-step SHARON-ANAMMOX process as well as a one-step granular sludge process with both
AOB and anammox in the reactor at the same time. The SHARON-ANAMMOX process (ANAMMOX -
Paques) is a two-stage, suspended growth implementing a SHARON reactor, followed by an anoxic
anammox reactor. The SHARON reactor does  not have solids retention while the anammox reactor uses an
upflow solids granulation process to  generate biomass that will be retained in spite  of the slow growth rate.
3-16
                                                Wastewater Treatment and In-Plant Wet Weather Management

-------
March 2013
                                             Emerging Technologies
  Nitrogen Removal
prepared 2012
Technology Summary
  Deammonification (Sidestream and Mainstream Deammonification and
  Mainstream Nitrite Shunt) (continued)
  The second configuration (DEMON) involves a single SBR where the nitritation and anammox processes
  occur simultaneously and biomass is retained using a hydrocyclone process to promote sludge granulation.
  The DO is controlled at very low levels (< 0.3 mg/L) along with the pH to monitor nitritation. The third
  configuration (Anita-MOX, DeAmmon) uses carrier media similar to moving bed bioreactors as a means to
  retain the anammox organisms in the system. In these attached growth systems, nitritation takes place in the
  outer biofilm while the anammox bacteria are found in the inner biomass. Completely autotrophic nitrogen
  removal over nitrite (CANON) and oxygen-limited autotrophic nitrification denitrification (OLAND) are other
  terms used to identify the processes that are now generically described as deammonification.
  Comparison to Established  Technologies:
  The deammonification process can save up to 63 percent of the oxygen demand (energy) compared to
  conventional nitrification/denitrification with nearly 100 percent reduction in carbon demand, 80 percent
  reduction in biomass production and no additional alkalinity requirement. In comparison, the
  nitritation/denitritation process can achieve a 25 percent reduction in oxygen (energy) demand, 40 percent
  reduction in carbon demand, and 40 percent reduction in biomass production when compared to conventional
  nitrification/denitrification. The deammonification process is completely autotrophic and does not require
  supplemental carbon (another benefit of deammonification over nitritation/denitritation). Because
  supplemental carbon is not required for deammonification, biosolids production is very low by comparison to
  alternative processes. Based on reported data, the deammonification process can achieve up to 95 percent
  ammonia removal. Because the anammox organisms (planctomycetes) are extremely slow growing, the
  deammonification process is slow to start without seed organisms from an operating facility, and special care
  must be taken to retain the biomass to provide the long SRT required.
  Available Cost Information:
  Approximate Capital Cost: Not disclosed by the vendor.
  Approximate O&M Costs: Not disclosed by the vendor.
  Vendor Name(s):
  DEMON® - World Water Works, Inc.
  Chandler Johnson
  4000 SW 113th Street
  Oklahoma City, OK 73173
  Telephone: 855-466-2271
  Email: CJohnson@worldwaterworks.com
  Web site: http://www.worldwaterworks.com

  ANITA™ Mox - Veolia Water, Inc.
  Hong Zhao
  401  Harrison Oaks Blvd, Suite 100
  Gary, NC 27513
  Telephone: 919-677-8310
                Installation(s):
                Full-scale systems have been operated in Europe.
                The first U.S. installation DEMON) became
                operational at Hampton Roads Sanitation District in
                2012, the process is under construction at
                Alexandria Sanitation Authority and several other US
                projects are under design. The technology is
                available commercially.
                DEMON® - Nine full-scale side-stream installations
                are in Austria (Strass), Germany, Switzerland
                (Glarnerland), Netherlands (Apeldoorn), Finland, and
                Hungary. The first full-scale US installation has been
                operating at the HRSD York River WWTP since
                October 2012. Several installations are under
                construction in the United States (Alexandria, VA)
                and several are in the design phase.
                ANITA™ Mox/DeAmmon - Installations are in
                Sweden (Himmerfjarden, Vaxjo, and Malmo),
                Holbasck Denmark, Germany (Hattingen), and China
                (Dalien). No installations are in the United States,
                but this process is in the design phase for the HRSD
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Emerging Technologies
                                                    March 2013
  Nitrogen Removal
prepared 2012
Technology Summary
  Deammonification (Sidestream and  Mainstream Deammonification and
  Mainstream Nitrite Shunt) (continued)
  Email: hong.zhao@veoliawater.com
  Web site: http://www.veoliawatersystems.com
                James River WWTP, and a pilot test is underway at
                the Denver MWRD plant.
  DeAmmon - Purac
  Box 1146
  SE 221 05
  Lund, Sweden
  Telephone: 46-46-19-19-00
  Fax:46-46-19-19-19
  Email: pt@purac.se
  Web site: www.lackebywatergroup.com
  ANAMMOX® and SHARON ANAMMOX- Paques
  Aafko Sheringa
  T. de Boerstraat 24
  8561 EL Balk
  The Netherlands
  Telephone: 31-0-514-60-85-83
  Email: a.sheringa@paques.nl
  Website: http://en.paques.nl
  Key Words for Internet Search:
  Deammonification, anammox, sidestream treatment, DEMON process, ANITA-Mox, CANON process, OLAND
  process
  Data Sources:
  Joss, A., et al., "Combined Nitritation-Anammox: Advances in Understanding Process Stability,"
  Environmental Science and Technology, Vol. 45, No. 22, pp. 9735-9742, 2011.
  Rogalla, F., "Sustainable Solutions," Water and Waste Treatment, Vol. 54, No. 2, 2011.
  Daigger, G.T., et al., "Implementation of a Full-Scale Anammox-Based Facility to Treat and Anaerobic
  Digestion Sidestream at the Alexandria Sanitation Authority Water Resource Facility," Proceedings of the
  Nutrient Recovery and Management Conference 2011, Miami, FL, CD-ROM January 9-12, 2011.
  Gustavsson, D. J. I., "Biological Sludge Liquor Treatment at Municipal Wastewater Treatment Plants - A
  Review", VATTEN 66:179-192. Lund 2010.
  Wett, B., "Development and Implementation  of a Robust Deammonification Process," presentation at the
  Leading Edge Technologies Conference, Singapore, 2007.
  http://cyklar.ch/libraries.files/RobustDEMONProcess.pdf
  Wett, B., et al., "Key Parameters for Control of DEMON Deammonification Process," presentation at the
  Nutrient Removal Conference in Baltimore, MD, 2007.
  De Clippeleir, H., et al., "OLAND is feasible to treat sewage-like nitrogen concentrations at low hydraulic
  residence time," Proceedings of the Nutrient Recovery and Management Conference 201, Miami, FL,
  CD-ROM January 9-12, 2011.
  Veolia Water Solutions: http://www.veoliawater.com
  Phone conversations with World Waterworks staff, 2012.
  Vendor-supplied information
3-18
              Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
                                                                                 Emerging Technologies
  Nitrogen Removal
                                  prepared 2012
Technology Summary
  Nitritation and Denitritation (Sidestream)
                                                     State of Development:
                                                     Innovative.
Objective:
Biological ammonia removal from high-strength
streams (e.g., sludge liquors, landfill leachate).
Description:
This process involves the oxidation of ammonia to nitrite (nitritation) in an aerobic environment; however,
unlike nitrification, the nitritation process stops the oxidation at nitrite and does not proceed from nitrite to
nitrate (nitratation). To accomplish nitritation without nitratation, reactor environmental conditions are
controlled to promote the growth of ammonia-oxidizing bacteria (AOB), such as nitrosomonas, while inhibiting
the growth of nitrite-oxidizing bacteria (NOB), such as nitrobactor and nitrospira. The high temperature of the
sludge liquors favor NOB washout because the aerobic NOB grow faster than NOB at temperatures above 20
°C (Hellinga et al. 1998). Nitritation is desirable because it consumes approximately 25 percent less oxygen
than complete  nitrification. To provide complete nitrogen removal, nitritation is often coupled with denitritation.
Similar to the more common denitrification process for reducing nitrate, the process of denitritation involves
reducing nitrite to nitrogen gas by heterotrophic bacteria using carbon as an  electron donor in an anoxic
environment. The reactor is likely carbon limited requiring a supplemental carbon source. The denitritation
process requires 40 percent less carbon than the denitrification process. The nitritation-denitritation process
(the nitrite shunt) results in a  reduction in sludge production of approximately 30 to 40 percent compared to a
conventional nitrification-denitrification process.
The nitritation process is also used to produce nitrite as an electron acceptor for the deammonification
process (i.e., DEMON ), which uses specialized autotrophic microorganisms (ANAMMOX) to oxidize
ammonium and generate nitrogen gas (from ammonia and nitrate) without the carbon consumption of
denitrification or denitritation.
Example processes - Single-Reactor High-activity Ammonia Removal Over Nitrite (SHARON), which is a
chemostat process without biomass retention; and Strass Sequencing Batch Reactor (SBR), often with a high
solids retention time (SRT), which increases the internal carbon source for denitritation.
Where is it applied - The nitritation and denitritation process  has  been successfully implemented as a
sidestream process for treating centrate and filtrate recycle streams from dewatering anaerobically digested
biosolids. The relatively high temperature and high ammonia concentrations typically found in these recycle
flows make them ideal candidates for this process. Nitritation-denitritation is currently being tested in the main
liquid stream process—where temperature and ammonia concentration  is lower than sidestreams—to
investigate design and operational parameters, the difficulty in inhibiting NOB growth, the risk of poor mixed
liquor settling, and the increased risk of discharging highly toxic nitrite to the  receiving stream. Mainstream
nitritation/denitritation will be included in a future update of this report.
Process controls - The main process controls include the water temperature, SRT, pH, dissolved oxygen
concentration,  and the nitrite concentration. At temperatures  above 20 °C, AOB have a faster growth rate than
NOB. Operating at an SRT that is long enough to promote AOB growth but too short for NOB growth (i.e., 1
day) allows for proper control to stop the ammonia oxidation  process at  nitrite. The SHARON process
operates as a chemostat without solids recycle as a process  control but with a small volume to give a short
HRT and SRT. This prevents an NOB population from developing but also limits the mass of heterotrophs
and, therefore, the denitritation capacity. The Strass process includes solids retention control through the use
of an SBR and is operated to provide a longer SRT (i.e., 20 days) to allow good denitritation. NOB inhibition is
achieved through control of pH and nitrite concentration  in the SBR using cyclical aeration. During the
aeration interval, the pH drops because of acidification from the nitritation process. When the low pH setpoint
is achieved, aeration stops so that denitritation can occur, which adds alkalinity, resulting in an increase in  pH.
The pH operating band is relatively narrow but can be kept below the optimal growth range for NOB. In
addition,  a low dissolved oxygen concentration in conjunction with a high nitrite  concentration can be used
during the aeration cycle to inhibit NOB growth.
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Emerging Technologies
                                                      March 2013
  Nitrogen Removal
prepared 2012
Technology Summary
  Nitritation and Denitritation (Sidestream) (continued)
  Comparison to Established Technologies:
  The nitritation and denitritation process offers energy and carbon savings compared to conventional
  nitrification and denitrification processes. Up to 25 percent less oxygen and 40 percent less carbon are
  consumed compared to conventional nitrification and denitrification. Because less carbon is required, there is
  also less sludge production—as much  as 40 percent less. According to European data, the average nitrogen
  removal efficiency is in the range of 85 to 95 percent. On average 70 percent of the nitrogen load is converted
  via nitrite. The nitritation and denitritation process has the following advantages: low investment and low
  operational costs, no chemical by-products, insensitive to high influent suspended solids levels, and negligible
  odor emission. Compared to bioaugmentation processes for sidestream treatment, the tankage requirements
  for nitritation are smaller, and the process is somewhat simpler to operate. Because nitritation-denitritation is
  less resource efficient than deammonification, the nitritation process is more attractive as part of the
  deammonification process.
  Available Cost Information:
  Approximate Capital Cost: Not disclosed by vendor.
  Approximate O&M Costs: Not disclosed by vendor.
  Vendor Name(s):
  Grontmij UK (SHARON Process)
  Grove House, Mansion Gate Drive
  LS7 4DN Leeds,  United Kingdom
  Telephone:+44 113 262 0000 / +44 845 074 285
  Email: enquiries.uk@grontmij.co.uk

  Delft University of Technology
  (SHARON Process)
  Dr. Ir. Mark van Loosdrecht Department of
  Biotechnology
  Julianalaan 67
  2628 BC Delft
  The Netherlands
  Telephone: 31-15-278 1618
  Email: mark.vanLoosdrecht@tnw.tudelft.nl

  Cyklar-Stulz (Strass SBR Process)
  CH-8737 Gommiswald Rietwiesstrasse 39
  Switzerland
  Telephone: 41-55-290-11-41
  Fax:41-55-290-11-43
  Email: info@cyklar.ch
  Web site: http://www.cykar.ch
                Installation(s):
                SHARON Process
                One full-scale application is under construction in
                Wards Island, New York City, NY. Six facilities are in
                operation worldwide
                Wards Island, NY
                Geneva, Switzerland
                Paris, France
                MVPC Shell Green, Manchester, U.K.
                Whitlingham, Norwich, U.K.
                Garmerwolde, Netherlands
                Beverwijk, Netherlands
                Rotterdam, Netherlands
                Utrecht, Netherlands
                Strass SBR Process
                Strass, Austria (has now been converted to use the
                DEMON deammonification process)

                Salzburg, Austria
  Key Words for Internet Search:
  Nitritation, denitritation, SHARON process, sidestream process, SBR Nitritation-Denitritation process
3-20
               Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
                                            Emerging Technologies
  Nitrogen Removal
prepared 2012
Technology Summary
  Nitritation and  Denitritation (Sidestream) (continued)
  Data Sources:
  Ganigue, R., et al. "Impact of Influent Characteristics on a Partial Nitritation SBR Treating High Nitrogen
  Loaded Wastewater," Bioresource Technology, Vol. 111, pp. 62-69, 2012.
  Hellinga C., et al., "The Sharon process: An innovative method for nitrogen removal from ammonium-rich
  waste water." Water Science and Technology, Vol. 37, No. 9, pp. 135-142, 1998.
  Miot, A., and K.R. Pagilla, "Control of Partial Nitritation of Centrate in a Sequencing Batch Reactor," Water
  Environment Research, Vol. 82, No. 9, pp. 819-829, 2010.
  Dosta, J. et al., "Operation of the SHARON Denitrification  Process to Treat Sludge Reject Water Using
  Hydrolyzed Primary Sludge to Denitrify," Water Environment Research, Vol. 80, No. 3, pp. 197-204, 2008.
  WEF Nutrient Removal Task Force, Nutrient Removal: WEF Manual of Practice No. 34, WEF Press,
  Alexandria, VA, 2010.
  Wett,  B., etal., "pH Controlled Reject Water Treatment," Water Science Technology, 1998.
  Metcalf and Eddy, Wastewater Engineering Treatment and Reuse, 4th ed., 2003.
  Communication with Mixing and Mass Transfer Technologies, May 2012.
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Emerging Technologies
                                                                                    March 2013
  Small Site
                                 updated 2012
                                                                  Technology Summary
  Deep Shaft Activated  Sludge/VERTREAT
                                                 State of Development:
                                                 Innovative. Variations of this technology have been
                                                 applied worldwide for more than 3 decades but it has
                                                 not been widely adopted.
Objective:
Increased oxygen transfer in the activated sludge
process to decrease power requirements, saving
both capital and operating costs.
Description:
The Deep-Shaft Activated Sludge/VERTREAT™ process is a modification of the activated-sludge process.
VERTREAT™ essentially uses a vertical "tank" or shaft in place of the surface aeration basins used in a
conventional system. The result of this vertical configuration is a ten-fold increase in the dissolved oxygen
content of the mixed liquor, which increases the level of biological activity in the bioreactor. The process can
accommodate high-organic loading with lower aeration supply due to the enhanced oxygen transfer (a
function of both  increased pressure at depth and longer bubble-contact time).

Comparison to Established Technologies:
Reduced footprint requirements.
Lower power consumption and simple controls  resulting in reduced O&M.
Much higher-rate system due to increased oxygen transfer in process.
Available Cost Information:
Approximate Capital Cost: $3 to $5 per installed design gallon of flow.
Approximate O&M Costs: Dependent on power costs. Roughly half the aeration power requirement due to
increased oxygen-transfer efficiency. Lower maintenance costs as a result of having no pumps ordiffusers in
the core system.
Vendor Name(s):
NORAM Engineering and Constructors Ltd.
Suite 1800, 200 Granville Street
Vancouver, BC, Canada V6C 1S4
Telephone: 604-681-2030
Fax: 604-683-9164
  Web site: www.noram-eng.com
Installation(s):
City of Homer - Public Works Department
3575 Heath Street
Homer, AK, USA 99603
Telephone: 907-235-3174
Fax:907-235-3178
Email: jhobbs@ci.homer.ak.us
  Key Words for Internet Search:
  Deep shaft process, activated sludge, wastewater treatment, oxygen transfer, high rate, BOD, aerobic

  Data Sources:
  www.noram-eng.com
  www.vertreat.com
  Email communication with the vendor.
3-22
                                              Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
                             Emerging Technologies
  Solids Minimization
                                  updated 2012
                    Technology Summary
  Cyclic Metabolic Environment
  Objective:
  Biological treatment with decreased waste biosolids
  volume.
State of Development:
Innovative.
  Description:
  The Cannibal® process seeks to reduce solids production from biological wastewater treatment by adding an
  unaerated interchange tank to the process and cycling the biomass between the metabolic environments
  established in the interchange tank and the main bioreactor. A portion of sludge from the main treatment
  process is pumped to a sidestream interchange bioreactor where the mixed liquor is converted from an
  aerobic environment to a facultative environment. Some bacteria decay in the interchange reactor, while other
  bacteria break down and use the remains of the decaying organisms, their by-products, and anaerobically
  digestable organics. The bioreactor is periodically aerated to maintain dissolved oxygen at the transition
  between anoxic and anaerobic conditions. Mixed liquor from the bioreactor is recycled back to the main
  treatment process. There, other bacteria decay and are subsequently broken down. The process  continues
  use of the alternating environments of the aerobic treatment process and the interchange bioreactor. An
  important step is the removal of inorganic materials by a solid-separation module (fine drum
  screen/hydrocyclone) on  the return sludge line. All the return sludge is pumped through this module and
  recycled back to the main treatment process. Only a portion of this flow  is diverted to the sidestream
  bioreactor for the selection and destruction process. The decreased wasting limits biological phosphorous
  removal in this process, but physiochemical removal via chemical addition has been successful when sludge
  wasting is adjusted to compensate. The interchange tank is typically open and thus can create odor issues if
  aeration rate and ORP are not carefully controlled. Reductions of 60 to 70 percent or more in sludge
  production have been reported. However other installations have not been able to achieve similar
  performance. Initial research to determine the cause of the performance differences has focused  on the
  release of soluble chemical oxygen demand in the interchange tank, but the mechanism is still not well
  understood.
  Comparison  to  Established Technologies:
  Not similar to any established technology.
  Available Cost  Information:
  Approximate Capital Cost: Not disclosed by vendor.
  Approximate O&M Costs: Not disclosed by vendor.
  According to the vendor,  a 1.5-MGD WWTP could recognize an approximate net annual operating cost
  savings of $245,600 using the Cannibal process.
  Vendor Name(s):
  Siemens Industry, Inc. - Cannibal
  Water Technologies
  Telephone: 866-926-8420 or 724-772-1402
  Web: www.water.siemens.com
Installation(s):
Cannibal
Approximately 60 installations have been completed
since the inception of the process in 1998. Several
installations have shut down for various reasons
including odors. Current installations are being
monitored by the manufacturer to meet performance
guarantees.
Example municipal installations:
Columbia, SC
Gumming, GA
Peru, IN
Byron, IL
Lebanon, OR
Clovis, CA
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Emerging Technologies
                                       March 2013
  Solids Minimization
                                 updated 2012
                     Technology Summary
  Cyclic Metabolic Environment (continued)
                                                 Albany/Millersburg, OR
                                                 Healdsburg, CA
                                                 Oregon, IL
                                                 Emporia, VA
                                                 Macomb, MS
                                                 Big Bear, CA
                                                 Morongo, CA
                                                 Thomasville, NC

                                                 Example industrial installation:
                                                 Alpine Cheese Factory, Holmes County, OH

  Key Words for Internet Search:
  Cannibal process, biosolids, sludge, Catabol process, Khudenko Engineering, metabolic solids reduction,
  interchange tank
  Data Sources:
  Sandino, J., and D. Whitlock, "Evaluation of Processes to Reduce Activated Sludge Solids Generation and
  Disposal," Water Environment Research Foundation, WERF Report 05-CTS-3, 2010.

  Roxborough, R.  et al., "Sludge Minimization Technologies—Doing More to Get Less," WEFTEC Proceedings,
  2006.

  Novak, J.T., et al., "Biological Solids Reduction using the Cannibal Process," Water Environment Research,
  Vol. 79, No. 12, pp. 2380-2386, 2007.

  Sheridan, J., and B. Curtis, "Casebook: Revolutionary Technology Cuts Biosolids Production and Costs,"
  Pollution Engineering, Vol. 36, No. 5, 2004.

  Vendor-supplied information.
3-24
Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
                                                                                Emerging Technologies
  Solids Settleability
                                 prepared 2012
Technology Summary
  Magnetite Ballasted Activated Sludge
                                                    State of Development:
                                                    Innovative.
Objective:
Increase settling rates of activated sludge floes and
capacity of activated sludge processes without
expansion of reactor volume.
Description:
The mixed liquor suspended solids concentration of a typical activated sludge process is limited to 3,500 to
6,000 mg/L depending on the  loading rates and settleability characteristics of the biomass. Operating with
mixed liquor concentrations above this range tends to overload the secondary clarifiers with respect to solids
loading. Enhanced sedimentation activated sludge processes increase settling velocities and improve floe
formation, thereby allowing for greater solids loadings at the secondary clarifiers while maintaining effluent
quality. These improved settling characteristics allow for activated sludge systems to be operated at higher
mixed liquor concentrations than typical activated sludge systems, providing increased biomass to treat larger
loads or to maintain the  longer solids retention time necessary for stable nitrification. Facilities can take
advantage of this capability by reducing the required aerobic volume (because of the increased mixed liquor
concentration) and converting the previously aerobic volume to anoxic or anaerobic treatment stages to
provide  nutrient removal in the same reactor volume.
Example Process - BioMag™
BioMag™: The BioMag™ process adds magnetite to the mixed liquor as a ballast to enhance settling
characteristics. The magnetite is an inert  and fully oxidized form of iron ore (Fe3O4), which increases the
density of activated sludge floes to increase settling rates by as much as 30 times conventional settling rates.
The enhanced settling characteristics allow the activated sludge system to be operated at up to three times
the mixed liquor concentration of conventional systems. The magnetite is added to the mixed liquor in a
ballast mix tank. The majority  of the magnetite remains with the biomass and is returned with the RAS.  As
sludge is wasted from the system, the waste activated sludge passes through a shear mill to liberate the
magnetite before passing over a magnetic drum separator to recover the  magnetite before sludge wasting.
Approximately 95 to 99% of the  magnetite is recovered in the process. The BioMag™ process is suitable for
BOD, nitrogen, and biological  phosphorus removal. This process was developed from the CoMag enhanced
sedimentation process, which uses magnetite to improve settleability of raw wastewater for treating overflows
or for tertiary removal of effluent suspended solids (see the  process description in Chapter 2).
Comparison to Established Technologies:
Magnetite-ballasted activated  sludge competes with conventional activated sludge and with other process
enhancements that allow operation with increased biomass such as  Integrated fixed-Film Activated Sludge
and Membrane BioReactor. The main benefit of the magnetite-ballasted activated sludge process is its ability
to enhance the capacity and nutrient removal performance of activated sludge systems without adding capital-
intensive new tankage or energy-intensive operating costs.  The aerobic granular sludge process (AGSP, e.g.,
Nereda) is another approach to  increasing the density of biological solids.
Available Cost Information:
The primary applications for magnetite-ballasted active sludge are in upgrading municipal WWTPs and
treating  strong organic wastes from the food and beverage  industry.  Most of these applications involve
integrating BioMag™ in  an existing facility, thereby requiring custom solutions. As a result, prices are driven
by multiple factors. Nonetheless, early experience has shown that BioMag™ capital and operating costs are
comparable to or lower than competing solutions. For example, at the 5.5-MGD Easterly WWTP in
Marlborough, MA, the capital cost to implement BioMag™ was estimated at $12.1 million (including
structures), whereas implementing the tertiary ballasted sedimentation alternative was estimated at
$16 million. Annual operating  cost for BioMag™ was estimated at $740,000 versus $650,000 for the
alternative.
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Emerging Technologies
                                                                                  March 2013
  Solids Settleability
                               prepared 2012
Technology Summary
  Magnetite Ballasted Activated Sludge (continued)
  Vendor Name(s):
  Siemens Industry, Inc. - BioMag™
  Water Technologies
  Telephone: 866-926-8420 or 724-772-1402
  Web: www.water.siemens.com
                                              Installation(s):
                                              BioMag™
                                              Long Trail Brewing Company, Bridgewater Corners,
                                              VT
                                              Allenstown, NH
                                              Upper Gwynedd, PA
                                              Sturbridge, MA
                                              Easterly WWTP, Marlborough, MA
                                              Mystic, CT
                                              Taneytown, MD
                                              Marlay Taylor WWTP, St. Mary's County, MD
                                              Four SBR WWTP Upgrade, Berkeley County, WV
                                              East Norriton-Plymouth WWTP, PA
                                              Winebrenner, Cascade, MD
Key Words for Internet Search:
Magnetite Ballasted Activated Sludge, Siemens BioMag

Data Sources:
BioMag™

Siemens Water Technologies, www.water.siemens.com

Andryszak, R., et al., "Enhanced Nutrient Removal Upgrade of the Winebrenner Wastewater Treatment Plant
Using BioMag™ Technology," WEFTEC Proceedings, 2011.

McConnell, W.C., et al., "FullScale Demonstration at the Mystic WPCF and Establishing the Basis-of-Design
fora Permanent Installation," WEFTEC Proceedings, 2010.

Catlow, I., and S. Woodard, "Ballasted Biological Treatment Process Removes Nutrients and Doubles Plant
Capacity," Proceedings WEF Nutrient Removal, 2009.

Madden, J., COM, personal communication, 2010.
3-26
                                             Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
                                                                            Emerging Technologies
  Nitrogen and Phosphorus Removal
                                             prepared 2008
Technology Summary
  Biological-Chemical Phosphorus and Nitrogen Removal (BCFS) Process
                                                   State of Development:
                                                   Adaptive Use.
Objective:
Enhanced nutrient removal (nitrogen and phosphorus).
Description:
The BCFS process has been developed to achieve low-nutrient effluent concentrations at relatively low
Biochemical Oxygen Demand Ratio to Nitrogen (BOD/N) and Biochemical Oxygen Demand Ratio to
Phosphorus (BOD/P) ratios in the influent. The process design is based on the University of Cape Town
(UCT) process. In the process, the return sludge is introduced at the start of the anoxic zone to prevent the
presence of nitrate in the anaerobic zone. Mixed liquor is recirculated from the end of the anoxic zone to the
anaerobic zone. At the end of the anoxic zone, most of the nitrate is removed. In the anoxic zone, the
phosphorus is taken up by phosphate-accumulating bacteria in the activated sludge. The anoxic phosphorus
uptake results in a lower energy and BOD demand as well as lower sludge production.

Because of the  different microorganisms involved in phosphorus and  nitrogen removal, the retention times for
both removal processes are different. For maximum nitrification and availability of COD for denitrification a
long sludge-retention time is necessary. For biological phosphorus removal, usually shorter retention times
are advantageous. In the BCFS  process, long sludge-retention times  that are favorable for the removal of
nitrogen are preferred.
Comparison to  Established Technologies:
The BCFS process achieves removal rates for BOD, nutrients, and suspended solids similar to other process
designs based on the activated-sludge concept. With the BCFS process configuration, a stable and reliable
operation is possible. It has been demonstrated that the biological phosphorus removal capacity is usually
sufficient to comply with effluent standards. The settling characteristics of the activated sludge can be
enhanced by implementing the BCFS process design. The compartmentalization of the process allows low
and stable sludge volume index  (SVI) to be achieved. At the Molten WWTP, SVI is reduced from  150 to 80
mL/mg. Chemical phosphorus removal is limited by kinetic factors as  well as stoichiometric factors, and
excessive inorganic precipitant requirements need to be reduced.
Available Cost Information:
Approximate Capital Cost: The capital costs for the implementation of a BCFS process in case of upgrading
depend on the availability of existing tanks and equipment as well as  local requirements and specific
application. Actual costs are not disclosed.
Approximate O&M Costs: Not disclosed.
  Vendor Name(s):
  N/A

  Key Words for Internet Search:
  BCFS, nitrogen phosphorus nutrient removal
  Data Sources:
  Technical University of Delft, The Netherlands.

  Waterboard Groot Salland, The Netherlands.
                                                Installation(s):
                                                Molten WWTP, The Netherlands
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Emerging Technologies
                                 March 2013
 Nitrogen and Phosphorus Removal
prepared 2008
Technology Summary
 Biological-Chemical Phosphorus and Nitrogen Removal (BCFS) Process
 (continued)
                               Internal Recycle
Influent



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-------
March 2013
                               Emerging Technologies
  Nitrogen and Phosphorus Removal
prepared 2008
Technology Summary
  Modified University of Cape Town (MUCT) Process
  Objective:
  Enhanced removal of phosphorus and nitrogen from
  wastewater.
     State of Development:
     Adaptive Use.
  Description:
  The Modified University of Cape Town (MUCT) process provides efficient nitrogen removal by sending the
  RAS to the anoxic zone. The anaerobic reactor, is located upstream of two anoxic reactors. RAS is subjected
  to the first anoxic reactor stage. There is an internal recycle from the first anoxic reactor to the anaerobic
  reactor, and another internal recycle from the oxic reactor to the second anoxic reactor.
  Comparison to Established Technologies:
  The MUCT process is different from the UCT process. MUCT includes two anoxic stages in series. Influent
  wastewater is fed to the anaerobic reactor, which is located upstream of the anoxic reactors. Returned
  activated sludge (RAS) is returned to the first anoxic reactor. There is an internal recirculation from the first
  anoxic reactor to the anaerobic reactor. Removal of nitrogen in the aeration basin may vary from 40 to 100
  percent and the effluent nitrate should be sufficiently low so as not to interfere with the anaerobic contact
  zone. Plug flow configuration of the aeration basin allows the anoxic zones in the first section of the plant to
  be low, while the endogenous oxygen demand at the end of the aeration basin and the DO level will increase
  to allow for the  required nitrification and phosphate uptake. Nitrates not removed in the aeration basin will be
  recycled to the  anoxic zone. Therefore, efficient overall nitrogen removal is achieved more economically.
  Available Cost Information:
  Approximate Capital and O&M Costs: Cost estimates are dependent upon local requirements and specific
  application and economy of scale applies. For example, uniform annual cost of a 100,000 GPD plant is
  estimated to be about $272,075 based on an interest rate of 6 percent for a 20-year period.
  Vendor Name(s):                              Installation(s):
  N/A                                             King County South AWTP, WA
  Key Words  for Internet Search:
  Modified UCT process, RAS anaerobic reactor
  Data Sources:
  "Design and Retrofit of Wastewater Treatment Plants for Biological Nutrient Removal," Water Quality
  Management Library, Volume 5, Second Edition, 1998.
  Principles and Practice of Nutrient Removal from Municipal Wastewater, Lewis Publishers, Second Edition,
  1991.
Influent

Internal Recycle
rn
Anaerobic
U
X
o
z
i

Internal Recycle
1
u
'x
o
<
Oxic


Returned Activated Slue
Cla
\ ^
ifier
Y- / Effluent
y '
ge
                                                                   \
                                                                      Waste
                                                                      Sludge
                                                                        745043_WWT-lB.ai
                       Process Flow Diagram for Modified UCT Process
Wastewater Treatment and In-Plant Wet Weather Management
                                             3-29

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Emerging Technologies
                                                    March 2013
  Nitrogen and Phosphorus Removal
            updated 2008
Technology Summary
  Westbank Process
  Objective:
  Enhanced removal of phosphorus and nitrogen from
  wastewater.
               State of Development:
               Adaptive Use.
  Description:
  The Westbank Process is a version of the Three-Stage Bardenpho® but includes Returned Activated Sludge
  (RAS) denitrification to provide efficient phosphate and nitrogen removal. First, RAS is subjected to an anoxic
  stage to remove nitrates. While a fraction of the influent wastewater is sent to the anoxic reactor, the
  remaining portion is fed to the anaerobic reactor directly. There is also an internal recycle from the oxic
  reactor to the second-stage anoxic reactor.
  Comparison to Established Technologies:
  In the basic Three-Stage Bardenpho® process, the oxic reactor is in tandem with the anaerobic and anoxic
  reactors. RAS is returned to the anaerobic reactor and there is an internal recirculation from the oxic reactor
  to the anoxic reactor. The Westbank Process includes the anaerobic reactor sandwiched between the two
  anoxic reactors, with the oxic reactor downstream of the three stages.
  Available Cost Information:
  Approximate Capital and O&M Costs: Cost estimates are dependent upon  local requirements and specific
  application and economy of scale applies. For example, uniform annual cost of a 100,000 GPD plant is
  estimated about $272,075 based on an interest rate of 6% fora 20-year period.
  Vendor Name(s):
  N/A
               Installation(s):
               Used in Kelowna WWTP, British Columbia, Canada
  Key Words for Internet Search:
  Westbank process, BNR, biological nutrient removal

  Data Sources:
  "Design and Retrofit of Wastewater Treatment Plants for Biological Nutrient Removal," Water Quality
  Management Library, Volume 5, Second Edition, 1998.
  Principles and Practice of Nutrient Removal from Municipal Wastewater, Lewis Publishers, Second Edition,
  1991.
          Influent
                        -Q
                         O
Internal Recycle
                                           Oxic
                                                                     Clarifier
                                                                              Effluent
                                   Returned Activated Sludge
                                Y
                                                                          Waste
                                                                          Sludge
                                                                             745043_WWT-16.a
                       Process Flow Diagram for the Westbank Process
3-30
             Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
                                                                           Emerging Technologies
  Phosphorus Removal
                                prepared 2008
Technology Summary
  Modified Anaerobic/Oxic  (A/O) Process
  Objective:
  Enhanced removal of phosphorus and nitrogen from
  wastewater.
                                               State of Development:
                                               Adaptive Use.
  Description:
  The modified A/O process provides phosphate and nitrogen removal. If nitrification is not required and the
  temperatures are not high, the simple two-stage, high-rate A/O process may be sufficient. However, with
  higher temperatures some nitrate formation cannot be avoided. Therefore, returned activated sludge (RAS)
  should be subjected to an anoxic stage to remove nitrates before mixing it with the influent wastewater.
  Comparison to Established Technologies:
  The simple high-rate A/O process uses an anaerobic reactor upstream of the oxic reactor. RAS is returned to
  the anaerobic reactor. The modified A/O process, however, includes an anoxic reactor downstream of the
  anaerobic reactor where only RAS is recycled. Influent wastewater is directly sent to the anaerobic reactor for
  phosphorus removal. There is an internal recirculation from the anoxic reactor to the anaerobic reactor.
  Available Cost Information:
  Approximate Capital Cost: Cost estimates are dependent upon local requirements and specific application
  and economy of scale applies. For example, uniform annual cost of a 100,000 GPD plant is estimated about
  $244,000 based on an interest rate of 6 percent for a 20-year period.
  Approximate O&M Costs: Unknown
  Vendor Name(s):
  N/A
                                                Installation(s):
                                                Fayetteville AWTP, AR
Key Words for Internet Search:
High-rate A/O with RAS denitrification
Data Sources:
"Design and Retrofit of Wastewater Treatment Plants for Biological Nutrient Removal," Water Quality
Management Library, Volume 5, Second Edition, 1998.
Principles and Practice of Nutrient Removal from Municipal Wastewater, Lewis Publishers,
Second Edition, 1991.
                Influent    Internal Recycle
                                                                       Effluent
11
Anaerobic

u
g
c

Oxic
Clar
\
1
Returned Activated Sludge
                                                                \
                                                                  Waste
                                                                  Sludge
                                                                       /4M>H_WWI-19.ai
              Process Flow Diagram for Modified Anaerobic/Oxic (A/O) Process
Wastewater Treatment and In-Plant Wet Weather Management
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Emerging Technologies
                                                                                        March 2013
  Membrane Processes
                                   prepared 2012
                                                                     Technology Summary
  Membrane Biofilm Reactor (MBfR)
                                                   State of Development:
                                                   Emerging.
Objective:
Use of hollow membrane fibers to deliver gas
(oxygen or hydrogen) to a surface biofilm for efficient
removal of pollutant compounds (either reduced or
oxidized).
Description:
The MBfR process reactor uses a bundle of hollow-fiber, composite membranes sealed on one end and
submerged in the water to  be treated. A gas is introduced inside the fibers and diffuses through to a biofilm
that develops on the outside surface of the membrane. Because the gas permeates the membrane in the
opposite direction than the water-based compounds, counter-gradients are established for the concentration
of each, thus improving the efficiency of the gas use. MBfR membranes are hydrophobicso that the pores
remain dry and use gas diffusion to prevent formation of gas bubbles. The gas pressure to the hollow fibers is
an important and easily adjusted control mechanism. Only gas, not water,  permeates the membranes. This
significantly decreases the potential for membrane plugging. However, prevention of excessive biofilm growth
on the outer membrane surface remains a concern.
MBfRs have  been studied at the bench scale and tested at the pilot scale for a variety of drinking water and
wastewater applications (Martin et al. 2011). Oxygen- or air-based reactors have successfully conducted
concurrent nitrification and denitrification, high  strength chemical demand oxidation, and decomposition of
Pharmaceuticals (Brindle et al. 1999; Downing  and Nerenberg 2008;  Kim et al. 2010; Semmens et al. 2003;
Syron and Casey 2008). Alternatively, Hydrogen-based reactors safely treat oxidized contaminants including
nitrate, perchlorate, bromate, selenate, and chlorinated solvents such as trichloroethylene (Chung et al. 2008;
Nerenberg and Rittmann 2004; Terada et al. 2006).
When hydrogen gas is supplied—a technology also known as HFMBfR (Hydrogen-based hollow-Fiber
Membrane Biofilm Reactor)—an autotrophic biofilm develops and uses hydrogen as its electron donor to
reduce one or several oxidized contaminants acting as electron acceptor. This approach can be used for
treating wastewater, groundwater, or drinking water. The process is effective in treating water with oxidized
contaminants such as nitrate, perchlorate, chlorinated solvents, selenate, bromate, chromate, and
radionuclides. When oxygen is supplied—a technology also known as MABR (Membrane Aerated
Bioreactor)—a nitrifying biofilm can develop for ammonia removal. Systems with a blend of oxygen-supplied
fiber bundles for nitrification and hydrogen-supplied fiber bundles for denitrification have been successfully
operated in trials.  Another approach to nitrogen removal uses an oxygen-supplied MBfR for nitrification with a
suspended phase biomass for heterotrophic denitrification using the carbon in the wastewater or with an
oxygen limitation so that the outer perimeter of the biofilm is anoxic and provides denitrification.
The technology involves bundles of membrane tubes at 50-330 urn diameter and up to nearly 1 meter long.
For total nitrogen removal with air, TKN loading is up to 103 mg/m2/day. With hydrogen supplied as the
electron donor, nitrate-N can be removed at up to 1,300 mg/m2/day. Details of MBfR design and operation are
fully described in Martin and Nerenburg (2012).
Comparison to Established Technologies:
Although they sound somewhat similar, MBfRs differ from membrane bioreactors (MBRs) in that the
membrane is used for gas  delivery and biofilm  support and does not  act as a filter mechanism.
Available Cost Information:
Approximate Capital Cost: Too few installations to provide generalized cost estimate.
Approximate O&M Costs: Too few installations to provide generalized cost  estimate.
Vendor Name(s):                              Installation(s):
APTWater                                        No full installations are in the United States
3333 Vincent Road, Suite 222                       Cucamonga Valley Water District, Rancho
3-32
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March 2013
                             Emerging Technologies
  Membrane Processes
                                  prepared 2012
                    Technology Summary
  Membrane Biofilm Reactor (MBfR) (continued)
  Pleasant Hill, CA 94523
  Telephone: 925-977-1811 or 1-888-307-2749
  Fax:925-977-1818
  Email: info@aptwater.com
  Web site: http://www.aptwater.com/
Cucamonga, CA, hydrogen gas used for nitrate
removal (2012 startup)
Ojai Valley Sanitation District, Ojai, CA, a 29,000-
gpd pilot facility was operated with hydrogen for
nitrate removal in 2010
                                                   La Puenta, CA, pilot system

  Key Words for Internet Search:
  MBfr, HFMBfR, H-2 hydrogen based membrane biofilm reactor, MABR, membrane aerated bioreactor

  Data Sources:
  Martin, K.J., et al., "Multidimensional Modeling of the Hollow-Fiber Membrane Biofilm Reactor." Proceedings
  WEFTEC 2011, 3256-3271, 2011.
  Brindle, K., et al., "Pilot-Plant Treatment of a High-Strength Brewery Wastewater Using a Membrane-Aeration
  Bioreactor." Water Environment Research, Vol. 71, No. 6, pp. 1197-1203, 1999.
  Downing, L.S., and R. Nerenberg, "Total nitrogen removal in a hybrid, membrane aerated activated sludge
  process." Water Research, Vol. 42,  No. 14, pp. 3697-3708, 2008.
  Kim, J., et al., "Decompostion of Pharmaceuticals (sulfamethazine and sulfathiazole) using oxygen-based
  membrane biofilm reactor." Desalination, Vol. 250, No. 2, pp. 751-756, 2010.
  Semmens, M.J., et al., "COD and nitrogen removal by  biofilms growing on gas permeable membranes." Water
  Research, Vol. 37, No. 18, pp. 4343-4350, 2003.
  Syron, E., and E. Casey, "Membrane-Aerated  Biofilms for High Rate Biotreatment: Performance Appraisal,
  Engineering Principles, Scale-up, and  Development Requirements." Environmental Science & Technology,
  Vol. 42, No. 6, pp. 1833-1844, 2008
  Chung, J., et al., "Bioreduction of Trichloroethene Using a Hydrogen-Based Membrane Biofilm Reactor."
  Environmental Science & Technology, Vol. 42, pp. 477-483, 2008.
  Nerenberg, R., and B.E. Rittmann, "Hydrogen-based, hollow-fiber membrane biofilm reactor for reduction of
  perchlorate and other oxidized contaminants." Water Science and Technology,  Vol. 49, No. 11-12, pp. 223-
  230,2004.
  Terada, A., et al., "Rapid autohydrogenotrophic denitrification by a membrane biofilm reactor equipped with a
  fibrous support around a gas-permeable membrane." Biochemical Engineering  Journal, Vol. 31, No. 1, pp. 84-
  91,2006.
  Martin, K.J., and R. Nerenberg, "The membrane biofilm reactor (MBfR) for water and wastewater treatment:
  Principles, applications,  and recent developments." Bioresource Technology, Vol. 122, pp. 83-94,
  http://dx.doi.0rg/10.1016/j.biortech.2012.02.110, 2012.
  Robert Nerenberg, "Membrane Biofilm Reactors for Water and Wastewater Treatment," Proceedings
  Borchardt Conference: A Seminar on Advances in Water and Wastewater Treatment, 2005.
  Hwang, J.H. et al., "Achieving biofilm control in a membrane  biofilm reactor removing total nitrogen," Water
  Research, Vol. 44, No. 7, pp. 2283-2291, 2010.
  Sahu, A.K., et al., "Onsite Wastewater Denitrification Using a Hydrogenotrophic Hollow-Fiber Membrane
  Bioreactor" Water Environment Research, Vol. 81, No. 7, pp. 680-686, 2009.
  Syron, E., and E. Casey, "Membrane-Aerated  Biofilms for High Rate Biotreatment: Performance Appraisal,
  Engineering Principles, Scale-up, and  Development Requirements," Environmental Science & Technology,
  Vol. 42, No. 6, pp. 1833-1844, 2008.
  Water Environment Research Foundation, WERF Report, Treatment Processes - Membrane Technology:
  Pilot Studies of Membrane-Aerated  Bioreactors, Final Report, 2005. http://www.aptwater.com
  http://www.uspto.gov/
Wastewater Treatment and In-Plant Wet Weather Management
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Emerging Technologies
                                                                                      March 2013
  Membrane Processes
                                  updated 2012
                                                                    Technology Summary
  Vacuum Rotation Membrane (VRM®) System
  Objective:
  Ultrafiltration of biomass for high-quality effluent with
  a smaller footprint than activated sludge and a
  unique approach to cleaning of the membrane
  surface.
                                                State of Development:
                                                Emerging.
  Description:
  This membrane system employs flat-sheet, ultrafiltration-membrane segments configured into disks rotating
  on a horizontal shaft. The hydrophilic membrane has a pore size of approximately 38 nm. Sequential cleaning
  of the rotating membranes is achieved with scouring air introduced next to the shaft at about half the water
  depth, providing high-intensity scouring of 1/6 to 1/8 of the disk near the 12 o'clock position. The membranes
  rotate through the scouring section several times per minute. Operating results show that neither back-pulsing
  nor regular cleaning is required. Average flux is typically 8-12 gal/ft2/day with a suction head of less than 10
  feet. (Shear forces introduced  by the rotational movement together with the high-intensity air scour remove
  solids buildup on the membranes to decrease membrane fouling. Chemical cleaning once or twice a year has
  shown to be sufficient for operating VRM plants.
  Comparison to Established Technologies:
  The VRM technology provides similar advantages as other MBR processes using Ultrafiltration membranes.
  The unique feature of VRM is that the membranes are configured into disks rather than tubes or plates and
  that the disks are rotated for cleaning and to introduce shear forces for fouling control.
  Available Cost Information:
  Approximate Capital Cost: No U.S. applications from which to obtain cost information.
  Approximate O&M Costs: No U.S. applications from which to obtain cost information.
  Vendor Name(s):
  Huber Technology, Inc.
  9735 North Cross Center Ct, Suite A
  Huntersville, NC 28078
  Telephone: 704-949-1010
  Email: filtration-reuse@hhusa.net
  Web site: http://www.huber-technology.com
                                                Installation(s):
                                                The process is primarily marketed toward
                                                international industrial applications. There are 30
                                                installations internationally, but none are in the
                                                United States.

                                                Hans Kupfer & Sohn GmbH & Co.KG, Heilsbronn,
                                                Bavaria, Germany (meat processing)

                                                Anheuser-Busch InBev, Lb'wen, Belgium (brewing)

                                                GZM  Extraktionswerk AG, Lyss, Switzerland
                                                (slaughtering by-products)

                                                La Santa WWTP, Lanzarote, Spain
Key Words for Internet Search:
VRM, membrane bioreactor, wastewater, vacuum, rotation
Data Sources:
Schuler, S. "Operating Experience with Rotating Membrane Bioreactors", Water World, March 2009.

http://www.huber-technology.com
3-34
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March 2013
                                                                              Emerging Technologies
                                 prepared 2012
                                                                     Technology Summary
                                                 State of Development:
                                                 Emerging.
Nitrogen Removal
  OpenCel Focused Pulse
Objective:
Waste activated sludge (WAS) reduction and
generation of carbon source fordenitrification.
Description:
OpenCel uses electrical pulses to disrupt WAS cell structure causing the cells to lyse. OpenCel focused pulse
(FP) technology uses high-frequency micro-pulses of between 20 and 60 kV for no more than 0.1 second to
cause the cell membrane to swell and rupture. Once ruptured, the WAS is more readily degradable by the
active microorganisms. Bench scale research (Lee et al. 2010) shows that the semi-soluble COD of WAS
increased by more than 26 times after OpenCel treatment compared with untreated WAS. If the WAS treated
with OpenCel is fed to a digester, it degrades more completely, giving higher volatile solids destruction
(therefore less biosolids yield) and generating more digester gas (if anaerobic). If fed to an anoxic zone, the
ruptured cells become a source of readily biodegradable carbon fordenitrification. The denitrification rate
using OpenCel  treated WAS has been shown to be approximately equal to the rate when using methanol as
carbon source but does not include the dangers of methanol handling. Other research  (Rittman et al. 2008)
shows that full FP pretreatment should increase biogas production and biosolids removal by 60 and 40
percent, respectively. Note that WAS is approximately 6 to 10 percent nitrogen and 1 to 2 percent phosphorus
(more if biological phosphorus removal is practiced). Much of that nitrogen and phosphorus is returned  to the
process when cells are ruptured.
Comparison to Established Technologies:
Other approaches to generating carbon for denitrification from biomass are based on the use of endogenous
respiration and require increased  solids retention time and, therefore, tank volume. External sources of carbon
purchased specifically for denitrification will generally have no or little nitrogen. Cell lysis by OpenCel or
endogenous respiration provides carbon but with about 8 percent nitrogen (proportional to the typical
composition of bacteria). Other cell lysis technologies including sonication, MicroSludge, and Cambi are used to
improve digestion  of sludge but have not been applied to generate carbon within the activated sludge process.
Available Cost Information:
No cost information is available because of the lack of full-scale installations.
                                                 Installation(s):
                                                 Lancaster, OH - pilot
                                                 Mesa, AZ - full-scale demonstration
Vendor Name(s):
OpenCEL, LLC
900 Circle 75 Parkway, Suite 1330
Atlanta, GA 30339
Telephone:  847-835-7418
Fax: 847-835-7423
Email: info@opencel.com
Key Words for Internet Search:
Focused pulse, OpenCel, carbon source
Data Sources:
Sandino, J., and D. Whitlock, "Evaluation of Processes to Reduce Activated Sludge Solids Generation and
Disposal," Water Environment Research Foundation (WERF) Report No. 05-CTS-3, 2010.
Lee, Il-Su, et al. "Feasibility of Focused-Pulsed Treated Waste Activated Sludge as a Supplemental Electron
Donor for Denitrification," Water Environment Research Vol. 82, No. 12, pp 2316-2324, 2010.
Salerno, M.B. et al. "Using a Pulsed Electric Field as a Pretreatment for Improved Biosolids Digestion and
Methanogenisis," Water Environment Research Vol. 81, No. 8,  pp 831-839, 2009.
Rittman, B.E., H. Lee, J. Alder, J.E. Banaszak, and R. Lopez. .2008. Full-Scale Application of Focused-Pulsed
Pretreatment for Improving Biosolids Digestion and Conversion to Methane. Water Science and Technology
Vol. 58, No. 10, pp 1895-1901.
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Emerging Technologies
                                                                                       March 2013
  Nitrogen and Phosphorus Removal
                                              prepared 2012
Technology Summary
  Integrated Fixed-film Activated Sludge (IFAS) Systems with Biological
  Phosphorus Removal
                                                  State of Development:
                                                  Emerging.
Objective:
This treatment process aims at increasing the
biomass in a biological phosphorus removal process
without increasing the suspended solids
concentration or solids loading to the clarifier.
Description:
The IFAS hybrid processes include any activated sludge system that has some type of fixed/film media in a
suspended growth reactor to increase the amount of biomass available for treatment. The IFAS media can be
retrofitted into existing activated sludge systems and lagoons. There are two major types of IFAS: (1)
Submerged Mobile Media IFAS  and (2) Submerged Fixed Media IFAS. The media material varies but is
usually a plastic carrier, sponge carrier, or knitted matrix. Mobile media is retained by screened baffle walls
and can be allowed to migrate over the entire basin volume or can be retained in specific zones by multiple
baffle walls.
An important feature of the IFAS process is that it provides the capability to decouple the solids retention time
(SRT) of the suspended biomass from the SRT of the biomass attached to the IFAS media. This feature is
especially useful with processes that must nitrify and perform enhanced biological phosphorus removal
(EBPR) because the optimal SRT for EBPR is short (< 5 days) while the optimal SRT for nitrification is
generally longer (> 8 days) depending on wastewater temperature. Research (Onnis-Hayden et al. 2011) has
shown that the majority (> 90%) of the EBPR capability is associated with the suspended biomass, but most
of the nitrifying capability (> 70%) is associated with the biomass attached to the IFAS media. This
segregation of EBPR and nitrifying organisms allows the suspended phase to be controlled to a short SRT
without concern that the nitrifying capability of the system will decline or that  nitrifier washout will occur. It also
retains the bulk of the nitrifier population in the aerobic zone(s) thereby reducing the nitrifier fraction in the
anaerobic and anoxic zones where the nitrifiers are ineffective.
Comparison to Established Technologies:
The advantage of IFAS over a conventional activated-sludge plant is that IFAS could allow significant
expansion without additional aeration  basins by increasing biomass without increasing suspended solids
concentration. This is a particular benefit when biological nutrient removal is  required and allows some basin
volume to be converted to anoxic (for denitrification) and/or anaerobic (for EBPR) conditions without a
proportional reduction in the quantity of biomass under aeration. Using IFAS with EBPR provides phosphorus
removal that would otherwise be attained with metal salt addition and precipitation or some other non-
biological process
Key Words for Internet Search:
IFAS, EBPR, fixed film, BNR
Data Sources:
Onnis-Hayden, A., N. Majed, A.  Schramm, and A.Z. Gu. "Process Optimization by Decoupled Control of Key
Microbial Populations: Distribution of Activity and Abundance of Polyphosphate-Accumulating Organisms and
Nitrifying Populations in a Full-Scale IFAS-EBPR Plant," Water Research Vol. 45, No. 13, pp 3845-3854, 2011
3-36
                                               Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
                                                                            Emerging Technologies
  Solids Minimization
                                  prepared 2008
                                                                    Technology Summary
  Multi-Stage Activated  Biological Process (MSABP™)
                                                  State of Development:
                                                  Emerging.
Objective:
Carbon oxidation, nitrification, and denitrification.
Description:
The Multi-Stage Activated Biological Process (MSABPTM) is a method of domestic and industrial wastewater
treatment based upon spatial succession of microorganisms by trophic level. The spatial segregation provides
conditions at which bacteria are used as food source sequentially by first primary and then higher level
microorganisms in the food chain. Apparently, the spatial microorganism succession provides treatment by
aerobic and anaerobic microorganisms maintained at different stages of the biological reactor.
There are eight compartments in the biological reactor. The influent wastewater enters the first compartment
and travels through the each compartment circulating via the flow pattern created by airdiffusers located at
the bottom of the tank. Wastewater flow is in a looping pattern so that short circuiting is reduced. Removal of
organics and nitrification take place in the first four compartments. Fifth and sixth compartments  are anoxic
and denitrification occurs in these compartments. Usually 80 percent of the BOD is reduced in these
compartments leaving about 20 percent available for nitrification and denitrification processes. The seventh
and eighth compartments operate in endogenous phase and digest remaining volatile solids.
Comparison to Established Technologies:
The vendor claims that no waste-activated sludge is generated in this system. Total number of compartments
and size are based on the influent wastewater characteristics and treatment goals.
Available Cost Information:
Approximate Capital Cost: Dependent upon local requirements and specific application.
Approximate O&M Costs: Not disclosed by vendor.
  Vendor Name(s):
  Aquarius Technologies, Inc.
  1103 Mineral Springs Drive, Suite 300
  Port Washington, Wl 53074
  Telephone: 262-268-1500
  Fax:262-268-1515
  Email: info@aquariustechnologies.com
  BioScape Technologies, Inc.
  Tim Bossard, Jack Akin
  816 Bennett Avenue
  Medford, OR 97504
  Telephone: 541-858-5774
  Fax:541-858-2771
  Email: info@bioscapetechnologies.com
  Key Words for Internet Search:
  Multi-Stage Activated Biological Process, MAB, MSABP™
  Data Sources:
  http://www.aquariustechnologies.com/
  http://www.bioscapetechnologies.com/index.html
                                                Installation(s):
                                                Beijing Eizen Lubao Oil Co., China
                                                Johnson and Johnson Ltd., China
                                                Salatey Shamir Foods, Israel
                                                Pigs grow farm, Spain
                                                Marugan WWTP, Spain
                                                Delta Textile Factory, Israel
                                                Shtrauss  Dairy Foods, Israel
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Emerging Technologies
                                                                                           March 2013
  Solids Settleability
                                  prepared 2012
Technology Summary
  Aerobic Granular Sludge Process (AGSP)
                                                     State of Development:
                                                     Emerging.
Objective:
Aerobic biological treatment process that generates
dense sludge pellets, thereby providing highly
efficient sold-liquid separation.
Description:
It has been demonstrated that granular sludge has improved settling characteristics, facilitating highly efficient
solid-liquid separation. Compact structured and biologically efficient aerobic sludge granules with wide diverse
microbial species have been developed and shown to exhibit excellent settleability, high biomass retention,
and tolerance to toxicity (Adav et.  al., 2008). With high biomass retention and biological activity, a granular
sludge  reactor can be operated  at higher biomass concentrations, allowing higher loading rates while
maintaining the  longer solids retention time necessary for stable nitrification and providing anoxic and
anaerobic micro-environments in the sludge granules if desired for nutrient removal. To achieve granulation
under aerobic process conditions, short settling times are used to introduce a strong selective advantage for
well-settling sludge granules. Poor-settling biomass is washed out under these conditions. Granular sludge
process research and application  has primarily used a sequencing batch reactor (SBR) configuration. Similar
to conventional  applications of the SBR concept, one treatment cycle in the AGSP reactor has four well-
defined phases. These are filling,  mixing/aerating, settling, and decanting. Batch feeding of the reactor
induces a high-substrate concentration at the beginning of a treatment cycle. Because of a high concentration
gradient, substrate can diffuse deeply into the granules preventing starvation of bacteria in the granules. With
insufficient feeding (diffusion gradient), the bacteria at the center of the granules will be starved and
weakened,  which eventually leads to the granules' disintegration. In general, the size of the granules
increases until the formation of stable granules is limited by substrate diffusion. Less stable granules are
susceptible to shear forces and  shrink or disintegrate.  Weakened biomass in the granule center also
decreases the granule density and inhibits settling processes, causing washout. Thus, a dynamic equilibrium
eventually is reached between substrate concentration and the average diameter of granules. It has been
observed that high-shear forces under turbulent flow conditions give  selective advantage to the formation of
stable granules. Research has shown that nitrogen removal rates of  more than 80 percent seem feasible
(Tsuneda et al., 2006). While nitrification takes place in the outer, aerobic layer of the granules, denitrification
occurs  in the anoxic core of the  granules with the necessary carbon source being supplied by substrate
diffused into the granules.
The first pilot research project using aerobic granular technology was performed in the Netherlands using the
Granular Sequencing Batch Reactor in  a system called Nereda™ (de Bruin et al., 2005). The project designed
for simultaneous BOD, nitrogen and phosphorus removal was successful and exhibited an SVI of 55 mL/g
VSS, well below typical values of 100-200 mL/g VSS. The first full scale Nereda™ installation began operating
in Epe  Netherlands in May 2012 and will be the first opportunity to gain experience with the effect of
hydrodynamic conditions at full scale  on granule formation and stability.
Example Process - Nereda™

Comparison to  Established Technologies:
Because they operate at higher biomass concentrations, settle at a high rate, and do not require separate
clarifiers, Nereda process applications require only about one-quarter of the space required by conventional
activated sludge installations. Granular sludge was initially developed under anaerobic operating conditions
because granules do not develop  readily under aerobic conditions. To form aerobic granules, the AGSP is
most often configured and operated as  an SBR. This allows the high initial loading to develop adequate
driving  force for diffusion of substrate into the granules and the control of settling and decanting times that is
necessary to select for the microorganisms that will develop granules under aerobic conditions. Further
development of the aerobic granular-sludge technology can result in  the application of enrichment reactors to
generate the desired granular biomass.
3-38
                                                 Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
                                                                             Emerging Technologies
  Solids Settleability
                                prepared 2012
Technology Summary
  Aerobic Granular Sludge Process (AGSP) (continued)
                                                  applications to allow reliable cost generalization.
                                                  Installation(s):
                                                  Nereda™
                                                  The first full-scale municipal Nereda process was
                                                  commissioned at Epe, Netherlands in May 2012.
                                                  Four others facilities are being designed or
                                                  constructed for sites in the Netherlands, South
                                                  Africa, and Poland. No installations are in the United
                                                  States
Available Cost Information:
There is too little experience with Nereda or other AGSP
Vendor Name(s):
Nereda™ - DHV Water BV
P.O. Box 1132
3800 AL Amersfoort
The Netherlands
Telephone:  0031-33-468-22 00
Fax:0031-33-468-2801
Email: andreas.giesen@dhv.nl
Website: http://www.dhv.com
AGSP - Delft University of Technology
Department of Biotechnology
Environmental Biotechnology Group
Delft, The Netherlands
Telephone:  31-15-278-1551
Email: m.dekreuk@tnw.tudelft.nl
Web site: www.bt.tudelft.nl
Key Words for Internet Search:
Nereda, aerobic granular sludge process
Data Sources:
http://www.neredannop.nl/english/
DHV Web site, http://www.dhv.com
Lopez-Palau, S., J. Dosta,  and J. Mata-Alvarez J. "Start-up of an aerobic granular sequencing batch reactor
for the treatment of winery wastewater." Water Science and Technology, Vol. 60, No. 4, pp. 1049-1054, 2009
AdavS.S., Lee D., Show, K., Tay J., Aerobic Granular Sludge: Recent Advances. Biotechnology Advances,
Vol. 26 pp. 411-423, 2008.  Tsuneda, S., Ogiwara M., Ejiri Y., and A. Hirata. "High-rate nitrification using
aerobic granular sludge." Water Science and Technology Vol. 53, No. 3, pp. 147-154, 2006.
Cassidy D.P. and E. Bella.  "Nitrogen and phosphorus removal from an abattoir wastewater in a SBR with
aerobic granular sludge." Water Research Vol. 39, No. 19,  pp. 4817-4823, 2005.
De Bruin, L. M. M., van der Roest, H.F.R., de Kreuk, M., van Loosdrecht, M.C.M., Promising Results Pilot
Research Aerobic Granular Sludge Technology at WWTP Ede, in Aerobic Granular Sludge, IWA Publishing,
London, U.K., pp 135-142,  2005.
Qin, L., Y. Liu, and J-H Tay. "Effect of settling time on aerobic granulation in sequencing batch reactor."
Biochemical Engineering Journal, Vol. 21, No. 1, pp. 47-52, 2004.
de Bruin, L.M.M., M.K. de Kreuk, H.F.R. van der Roest, C.  Uijterlinde, and M.C.M. van Loosdrecht. Aerobic
granular sludge technology: An alternative to activated sludge. Water Science and Technology, Vol. 49, Nos.
11-12, pp. 1-7,2004.
Arrojo, B., A. Mosquera-Corral, J.M. Garrido, and R. Mendez. "Aerobic granulation with industrial wastewater
in sequencing batch reactors." Water Research, Vol. 38, Nos. 14-15, pp. 3389-3399, 2004.
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Emerging Technologies
                                                      March 2013
  Solids Settleability
prepared 2012
Technology Summary
  Aerobic Granular Sludge Process (AGSP) (continued)
  De Kreuk, M.K. and M.C.M. Van Loosdrecht. "Selection of Slow Growing Organisms as a Means for
  Improving Aerobic Granular Sludge Stability," Water Science Technology, 49, pp. 11-12 and 9-19, 2004.
  Tay, J.-H., Q.-S. Liu, and Y. Liu. The effects of shear force on the formation, structure and metabolism of
  aerobic granules. Applied Microbiology and Biotechnology, Vol. 57, Nos. 1-2, pp. 227-233, 2001.
  Etterer, T. and P. A. Wilderer. "Generation and Properties of Aerobic Granular Sludge," Water Science
  Technology,pp. 3-43, 2001.
  Beun, J.J., A. Hendriks, M.C.M. Van Loosdrecht, E. Morgenroth, P.A. Wilderer, and J.J. Heijnen. "Aerobic
  granulation in a sequencing batch reactor." Water Research, Vol. 33, No. 10, pp. 2283-2290, 1999.
  Morgenroth, E., T. Sherden, M.C.M. Van Loosdrecht, J.J. Heijnen, and P.A. Wilderer. "Aerobic Granular
  Sludge in a Sequencing Batch Reactor," Water Resources, Vol. 31, No. 12, 1997.
3-40
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March 2013
                                                                              Emerging Technologies
  Anaerobic Processes
                                   updated 2012
                                                                      Technology Summary
  Anaerobic Migrating  Blanket Reactor (AMBR)
                                                   State of Development:
                                                   Research (for municipal applications).
Objective:
Improve wastewater treatment efficiency.
Description:
AMBR is an anaerobic process that uses a blanket of granular biomass and produces biogas. The granular
biomass allows for operation at very long solids retention times so the AMBR process can be operated at
ambient temperatures that would require heating for non-granular, anaerobic processes at shorter solids
retention times. AMBRs use multiple tanks in series (a minimum of three) with gentle mixing in each to enhance
transport of substrate into the granules. No recycle is required. The serial configuration causes the biomass to
migrate toward the final tank, which, because it has the lowest concentration of substrate, produces little biogas,
thereby allowing it to act as  an internal clarifier with settling of the granular biomass. Because the final tank
allows the less dense biomass to escape while retaining granular biomass, it effectively selects for biomass that
is granular. To prevent excessive accumulation of biomass in the final tank,  the flow of wastewater is reversed
periodically by alternating the influent feed and effluent withdrawal points, thereby redistributing biomass toward
the other end of the reactor. The simple design, lack of heating, and the low biomass production typical of
anaerobic processes combine to make AMBR highly efficient operationally. Bench-scale testing has shown
the AMBR process to achieve 59 percent removal of COD from nonfat dry milk at 15 °C, with improved
removal of 80 to 95 percent at 20 °C (Angenet, 2001). Therefore, although the AMBR process could be a
viable process for pretreating industrial wastewater, at domestic wastewater treatment facilities it would likely
need to be combined with a downstream aerobic process for effluent polishing.
The AMBR process has  been applied at a full-scale installation for remediation of dairy wastes and in trials for
remediation of perchloroethylene (PCE), p-Nitrophenol, and other groundwater contaminants.  Research has
been performed to simulate treatment of domestic wastewater using AMBR (Angenent et al., 2001); however,
no full scale installations are now in place.
Comparison to Established Technologies:
AMBR is an anaerobic process using a  blanket of granular biomass similar to that developed in upflow
anaerobic sludge blanket (UASB) reactors. Unlike the UASB process, AMBRs do not require the use of
elaborate gas-solids separators and feed distribution systems. Flow reversal is sufficient to contain the
granular biomass in the bioreactorso the use of packing  or external settlers for solids capture  is not required.
Like other anaerobic processes, the AMBR process produces biogas, but  unlike most other anaerobic
processes, it requires no heating. Because it also does not require aeration, the AMBR process is  more
energy efficient than aerobic processes. It also produces less waste sludge than aerobic processes. However,
effluent quality is  marginal compared to aerobic processes and might require the use of a smaller aerobic
process downstream of the AMBR  process to meet discharge limits. Nutrient removal is minimal.
Available Cost Information:
Approximate Capital Cost: Unavailable because no full-scale facility is in place.
Approximate O&M Costs: Unavailable because no full-scale facility is in  place.
Vendor Name(s):                              Installation(s):
Developer                                        Full-scale industrial application in Costa Rica was
Largus (Lars) Angenent                              snut down. No full-scale installation is in place.
Cornell University
Dept of Biological and Environmental Engineering
214Riley-RobbHall
Ithaca, NY 14853
Telephone: 607-255-2480
Fax: 607-255-4080
Email: Ia249@cornell.edu
Web site: http://angenent.bee.cornell.edu
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Emerging Technologies
                                       March 2013
  Anaerobic Processes
                                  updated 2012
                     Technology Summary
  Anaerobic Migrating Blanket Reactor (AMBR) (continued)
  Patent holder
  Iowa State University Research Foundation, Inc.
  Ames, IA

  Key Words for Internet Search:
  AMBR, anaerobic migrating blanket reactor, anaerobic sludge blanket
  Data Sources:
  Kuscu, O. S., and D.T. Sponza, "Application of Box-Wilson experimental design method for 2,4-dinitrotoluene
  treatment in a sequential anaerobic migrating blanket reactor (AMBR)/aerobic completely stirred tank reactor
  (CSTR) system," Journal of Hazardous Materials, Vol. 187, No. 1 -3, pp. 222-234, 2011.

  Kuscu, O.S., and D.T. Sponza, "Effect of increasing nitrobenzene loading rates on the performance of
  anaerobic migrating blanket reactor and sequential anaerobic migrating blanket reactor/completely stirred
  tank reactor system," Journal of Hazardous Materials, Vol. 168, No. 1, pp. 390-399, 2009.

  Angenent, L.T., and S. Sung, "Development of Anaerobic Migrating Blanket Reactor (AMBR), A Novel
  Anaerobic Treatment System," Water Research, Vol.  35, No. 7, pp. 1,739-1,747, 2001.

  Angenent, L.T., et al., "Anaerobic Migrating Blanket Reactor Treatment of Low-Strength  Wastewater at Low
  Temperatures," Water Environment Research, Vol. 73, No. 5 pp. 567-574, 2001.

  Metcalf and Eddy, Wastewater Engineering Treatment and Reuse 4th ed., pp 1017-1018, 2003.

  Telephone conversation with  Lars Angenent, August 2004.

  Correspondence with Lars Angenent, August 2012.
3-42
Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
                                                                              Emerging Technologies
 Anaerobic Processes
                                  updated 2012
                                                                     Technology Summary
  Anaerobic  Membrane BioReactor (An-MBR)
                                                   State of Development:
                                                   Research (for municipal applications).
Objective:
Anaerobic treatment combined with membrane
filtration of biomass to improve effluent quality.
Description:
The An-MBR process is a promising process with the potential for energy-efficient treatment of municipal and
industrial wastewaters. It couples an anaerobic biological process with a membrane for liquid/solids
separation. The anaerobic process removes organic material [Chemical Oxygen Demand (COD)] without
aeration by converting it to methane gas and a small amount of new biomass. The membrane is usually of
pore size classified as microfiltration (retains particles > 0.1 urn, or ultrafiltration (retains particles > 0.01 urn)
so does not allow even individual microbial cells to pass through with the permeate. The process is energy
efficient and minimizes sludge management requirements. Consequently, it is particularly desirable for
treating high-strength wastes that can be costly when treated aerobically. Although anaerobic processes are
most often operated at warm temperatures to increase rate, An-MBRs have recently been shown to perform
adequately at 15°C (Raskin  et al. 2012). This is because the membrane allows for operation at high solids
concentrations and therefore high solids retention times to compensate for the low growth rate. The
membrane also retains the poorly settleable solids typical of traditional anaerobic processes thereby
improving effluent quality. One recent study (Raskin et al. 2012) found an average permeate COD
concentration of 36 mg/L and Biological Oxygen Demand after 5 days (BODS) below 30 mg/L. Although some
amount of membrane fouling improves organic removal, excessive fouling can be controlled by back flushing
and biogas sparging. Membrane fouling has been shown to be controlled if membranes are placed directly in
contact with granular activated carbon (GAG) in a fluidized bed MBR and a high quality effluent (5 mg/l BOD
and zero TSS) could be produced (Kim  et al. 2011). This research was done at a small scale, in a warm
climate and  it did not address long-term membrane fouling problems. Nevertheless, it estimated a significant
decrease in secondary process energy use in addition to significant methane production. Recent An-MBR
research was also done at the University of Michigan  (WERF 2012) on both synthetic wastewater and
municipal wastewater at temperatures down to 15 degrees C and using biogas sparging to minimize
membrane fouling. Effluent BOD of less than 30 mg/l was achieved for extended periods of time. Further
research is needed on optimizing process performance at low temperatures and demonstrating performance
at pilot and full scale.

An-MBRs are operated at elevated temperatures to pretreat high-strength wastes before additional aerobic
treatment but also show real potential for complete treatment of domestic wastewater COD. Nutrient removal
is minimal.
A significant proportion of the methane produced is dissolved in the effluent. This will typically be stripped out
of the effluent and emitted to the atmosphere to reduce the concentration of methane in the effluent. Because
methane is a significant greenhouse gas, the emissions from this should be considered.

Comparison to Established Technologies:
The An-MBR process is similar to an aerobic MBR facility except that the biological process is anaerobic.
Therefore the An-MBR requires less energy, generates biogas, and produces less waste biomass than an
aerobic MBR. Although most anaerobic processes are operated at > 25°C, including a membrane allows the
An-MBR process to be operated at temperatures more typical of domestic wastewater without heating
(< 20°C). Much like in an MBR, the membranes in the An-MBR are back flushed with permeate but rather
than also being sparged with air as in the MBR, the An-MBR membranes are sparged with the biogas
produced in the process. As is typical with the MBR, the membranes have a limited life in that mineral
deposits, cell material, and other compounds will progressively foul the membrane irreversibly until adequate
flux can no longer be recovered. Unlike  aerobic processes (including MBRs) anaerobic processes are not
effective for transformation of ammonia  or for nutrient removal.
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Emerging Technologies
                                             March 2013
  Anaerobic Processes
                                 updated 2012
                           Technology Summary
  Anaerobic Membrane  BioReactor (An-MBR) (continued)
  Available Cost Information:
  Approximate Capital Cost: Highly dependent
  Approximate O&M Costs: Not available.
  Vendor Name(s):
  Veolia Water Solutions and Technologies
  Biothane Americas
  2500 Broadway
  Camden, NJ08104
  Telephone:  856-541-3500
  Fax:856-541-3366
  Email: sales@biothane.com
  ADI Systems Inc.
  P.O. Box 397
  7 Pointe Sewall Road
  Wolfeboro, NH 03894
  Telephone:  603-569-0955
  Fax: 603-569-0957
  Email: systems@adi.ca
  Web site: www.adisystemsinc.com
  Key Words for Internet Search:
  Anaerobic Membrane Bioreactor, An-MBR
on waste stream flow.
        Installation(s):
        Industrial:
        More than a dozen industrial installations worldwide
        Food industry:
        Ken's Foods, Marlborough, MA
        Valley Queen Cheese, Milbank SD
        Daisy Brand, Garland Texas
        Holmes Cheese, Millersburg, OH (2012 start-up)
        Undisclosed food processor, Kentucky
        (2012 start-up)
        Biofuel industry:
        Komers International, Goszyn, Poland
        Undisclosed US biodiesel facility (2012 start-up)
        Domestic:
        No known full-scale An-MBR systems are in
        operation to treat municipal wastewater.
  Data Sources:
  Raskin, L, et al., "Anaerobic Membrane Bioreactors for Sustainable Wastewater Treatment," (WERF Project
  U4R08), WERF, 2012.
  J. Kim et al., "Anaerobic Fluidized Bed Membrane Bioreactor for Wastewater Treatment," Environmental
  Science and Technology Vol. 45, pp. 576-581, 2011.
  Ahlem Saddoud, Mariem Ellouze, Abdelhafidh Dhouib, Sami Sayadi, "Anaerobic membrane bioreactor
  treatment of domestic wastewater in Tunisia," Desalination, Vol. 207, pp. 205-215, 2007.
  Membrane Bioreactors for Anaerobic Treatment of Wastewaters, WERF Project 02-CTS-4 Phase 1 Report,
  2004.
  Membrane Bioreactors for Anaerobic Treatment of Wastewaters, WERF, Phase 2 Report, 2004.
  Preliminary Investigation of an Anaerobic Membrane Separation Process for Treatment of Low Strength
  Wastewaters, WERF, 2004
  Fuchs, W., H. Binder, G. Mavrias, and R. Braun. "Anaerobic treatment of wastewater with high organic
  content using a stirred tank reactor coupled with a membrane filtration unit", Water Research Vol, 37, pp.
  902-908, 2003.
3-44
       Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
                                                                              Emerging Technologies
  Electricity Generation
                                 prepared 2012
Technology Summary
  Microbial Fuel  Cell (MFC) Based Treatment System
                                                   State of Development:
                                                   Research.
Objective:
Use bacteria to generate electricity while providing
biological wastewater treatment.
Description:
An MFC is a device that generates electricity from bacterial metabolism of organic matter (which is measured
as chemical oxygen demand in wastewater). During the final stage of bacterial metabolism, electrons are
passed along the cell membrane and deposited onto a terminal electron acceptor, usually oxygen. Under
anaerobic conditions, bacteria must use an alternative electron acceptor like sulfate, nitrate, or—as is the
case with an MFC—an electrode. In an MFC, bacteria are grown under anaerobic conditions and they transfer
their electrons externally to an anode. Electrons flow from the anode to a positively charged cathode through
an external circuit; this flow of electrons represents an electrical current. The cathode is exposed to oxygen
and protons (H+) that chemically react with the incoming electrons to form water. MFC research is focused on
the design of the fuel cell including the number of chambers and their layout; electrode size (surface area),
spacing, materials, and quantity; alternatives to and composition of proton exchange membranes; and
affordable cathode catalysts. Biological research is being done to identify  bacterial species that optimize the
process and to better understand how they transfer electrons externally. A modified MFC that generates pure
hydrogen gas for use with hydrogen fuel cells is also being studied.  In this approach, no oxygen is supplied at
the cathode. Instead, a small amount of voltage is added  to the circuit to facilitate the chemical formation of
hydrogen gas (instead of water). Recent advances in MFC research have achieved substantial increases in
MFC power production compared to previous designs. While still an emerging technology that is being studied
at the laboratory-level, some day MFCs might be capable of producing enough electricity to operate a
wastewater treatment plant and perhaps even an excess  that could  be sold back to the grid.
Comparison to Established Technologies:
Not comparable to any established wastewater treatment technology.
Available Cost Information:
Approximate Capital Cost: Not disclosed by the vendor.
Approximate O&M Costs:  Not disclosed by the vendor.
Vendor Name(s):                               Installation(s):
Research projects at  universities:                     No installations are in the United States.
Dr. Bruce Logan
Pennsylvania State University
Hydrogen Energy Center
231 QSackett Building
University Park, PA 16802
Telephone: 814-863-7908
Email: blogan@psu.edu
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Emerging Technologies
                                                       March 2013
  Electricity Generation
prepared 2012
Technology Summary
  Microbial Fuel Cell  (MFC) Based Treatment System (continued)
  Dr. Lars Angenent
  Cornell University
  Department of Biological and Environmental
  Engineering
  214Riley-RobbHall
  Ithaca, NY 14853
  Telephone: 607-255-2480
  Email: Ia249@cornell.edu

  Key Words for Internet Search: It is time to close out the grant (it expired at the end of 2012).
  Anaerobic Membrane Bioreactor, An-MBR

  Data Sources:
  Yanzhen, F., et al., "Improved performance of CEA microbial fuel cells with increased reactor size," Energy &
  Environmental Science, Vol. 5, No. 8, pp. 8273-8280, 2012.

  Logan, B.E., and K. Rabaey. "Conversion of wastes into bioelectricity and chemicals using microbial
  electrochemical technologies," Science, 337:686-690, 2012.
  Cusick, R.D., et al. "Performance of a pilot-scale continuous flow microbial electrolysis cell fed winery
  wastewater," Applied Microbiolical Biotechnolofy, Vol. 89, No. 6, pp. 2053-2063, 2011.
  Fornero, J., et al., "Electric power generation from municipal, food, and animal wastewaters using microbial
  fuel cells," Electroanalysis, Vol. 22, pp. 832, 2010.
  Ahn, Y., and B.E. Logan. "Domestic wastewater treatment using microbial fuel cells and electrical energy
  production," Bioresource Technolofy, Vol. 101, No. 2, pp. 469-475, 2009.
  Fornero, J.J., et al. "Microbial fuel cell performance with a pressurized cathode," Environmental Science and
  Technology, Vol. 42, p. 8578, 2008.
  Logan, B.E., Microbial Fuel Cells, John Wiley & Sons, New York, 2008.
  Logan, B.E., "Extracting Hydrogen and Electricity from Renewable Resources," Environmental Science and
  Technology, Vol. 38, pp. 160A-167A, 2004.
  Logan, B.E., et al., "Microbial Fuel Cells: Methodology and Technology," Environmental Science  and
  Technology, Vol. 40 No. 7, pp.  5181-5192, 2006.
  Liu, H., et al., "Production of electricity during wastewater treatment using a  single chamber microbial fuel
  cell," Environmental Science and Technology, Vol. 38, pp. 2281-2285.
  Logan, B.E., and J.M. Regan. "Electricity-producing bacterial communities in microbial fuel cells," Trends in
  Microbiology Vol. 14, No. 12, pp. 512-518, 2006
  Li, X. et al. "Manganese dioxide as a new cathode catalyst in microbial fuel cells," Journal of Power Sources,
  Vol. 195, pp. 2586-2591, 2010
  Jiang, D., and B. Li. "Granular activated carbon single-chamber microbial fuel cells (GAC-SCMFCs): A design
  suitable for large-scale wastewater treatment processes," Biochemical Engineering Journal, Vol.  47, pp. 31-
  37,2009

  Dekker, A. et al. "Analysis and  Improvement of a Scaled-Dp and Stacked Microbial Fuel Cell." Environmental
  Science and Technology, Vol. 43,  No. 23, pp. 9038-9042, 2009.
  Kato, S., et al., "Microbial interspecies electron transfer via electric currents through conductive materials,"
  Proceedings of the National Academy of Sciences Volume 109, 2012.
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               Wastewater Treatment and In-Plant Wet Weather Management

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Chapter
 In-Plant Wet  Weather Flows Management
   4.1  Introduction
        Chapter 4 in-plant wet weather flows management processes include the storage and
        treatment of wastewater with infiltration/inflow entering a WWTP or storm-related flows in
        combined sewer systems entering a WWTP. This chapter focuses on storage and treatment
        technologies that can be used to manage the volume of wastewater during wet weather events.
        It does not address use of green infrastructure, which is being used in numerous cases in lieu
        of gray infrastructure.
   4.2  Technology Assessment
        Table 4.1 includes a categorized list of established, innovative, emerging, and adaptive use
        technologies for wet weather management. The innovative wet weather management
        technologies are: Compressible Media Filtration (CMF), Continuous Deflection Separator
        (CDS), TRASHMASTER™ Net Capture System, Treatment Shaft, HYDROSELF® Flip Gate
        Flusher, and Tipping Flusher® technology. Alternative Disinfectants (PAA and BCDMH) is an
        Emerging in-plant wet weather management technology, and BioActiflo® is an Adaptive Use
        Technology.

        Wet weather flows can be better managed if the conveyance systems to a facility are well
        maintained and separated from the storm sewer system. However, new technologies are
        needed to overcome the wet weather issues more efficiently. Emerging technologies used to
        rehabilitate conveyance systems to reduce wet weather flows are described in the U.S. EPA
        document "Emerging Technologies for Conveyance Systems - New Installations and
        Rehabilitation Methods" (EPA 832-R-06-004, July 2006). An evaluation of the innovative
        technologies identified for in-plant wet weather management processes is presented in
        Figure 4.1.

        Knowledge about technologies tends to evolve. The information provides a snapshot at a point
        in time; what is understood at one point in time may change as more information develops.
        This includes knowledge about operating mechanisms as well as the relative and absolute
        costs and features of a particular technology. Inquiries into the current state of knowledge are
        an important step when considering implementation of any technology.
 Wastewater Treatment and In-Plant Wet Weather Management
4-1

-------
Emerging Technologies
                                     March 2013
              Table 4.1—In-Plant Wet Weather Flows Management Processes -
                                    State of Development
Established Technologies (technology summaries not included)
Treatment
Dispersed Air Flotation
Dissolved Air Flotation (DAF)
Enhanced Clarification/High Rate Clarification (HRC)
Ballasted Flocculation (Actiflo® and Microsep®)
Lamella Plate Settlers
Screening
Vortex Separation
Innovative Technologies
Summary on
page
Treatment
Compressible Media Filtration (CMF)
Continuous Deflection Separator (CDS)
TRASHMASTER™ Net Capture System
Treatment Shaft
4-4
4-8
4-10
4-11
Storage
HYDROSELF® Flip Gate Flusher
Tipping Flusher®
Adaptive Use Technologies
BioActiflo®
Emerging Technologies
4-13
4-15
Summary on
page
4-19
Summary on
page
Disinfection
Alternative Disinfectants(PAA and BCDMH)
4-16
Research Technologies
None at this time
NA
4-2
Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
                                                       Emerging Technologies
                                                      Treatment
  Compressible Media Filtration (CMF)
  P,N
S,F
W
Dn
  Continuous Deflection Separator (CDS)
  P,N
S,F
W
Dn
  TRASHMASTER™ Net Capture System
  M, N
S,F
W
Dn
  Treatment Shaft
  M, N
S,F
W
Dn
                                                       Storage
  HYDROSELF® Flip Gate Flusher
  M, N
S,F
W
Dn
  Tipping Flusher®
  M, N
S,F
W
Dn
  Key
      Statement of Development
    B = Bench scale
    I = Full-scale industrial applications
    M = Full-scale municipal applications
    0 = Full-scale operations overseas
    P = Pilot
    N = Full-scale operations
       in North America
  Applicability
F = Few plants
I = Industrywide
L = Primarily large plants
S = Primarily small plants
                  "otential Benefits
             C = Capital savings
             I = Intense operational demand
             0 = Operational/maintenance savings
             S = Shock load capacity
             W = Wet weather load capacity
             E = Effluent quality
                                      Effluent Reuse
                                   Dp = Direct potable
                                   Dn = Direct nonpotable
                                   Ip = Indirect potable
                                   In = Indirect nonpotable
                                                                  omparative Criteria
                                                                   A Positive feature
                                                                   0 Neutral or mixed
                                                                   T Negative feature
         Figure 4.1— Evaluation of Innovative In-Plant Wet Weather Flows Management
                                                  Technologies
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Emerging Technologies
                                                                                           March 2013
  Treatment
                                    prepared 2012
                                                                        Technology Summary
  Compressible Media  Filtration  (CMF)
                                                     State of Development:
                                                     Innovative.
Objective:
Multifunction, passive, high-rate filtration for wet-
and dry-weather treatment applications.
Description:
The WWETCO FlexFilter™ and Bio-FlexFilter™ use a synthetic fiber media bed that is passively compressed
from the sides by the head of the incoming water. The lateral compression forms a cone-shaped porosity
gradient that allows the stratification and removal of large and small particles from the top to the bottom of the
media bed. The porosity gradient through the media bed, with its ability to handle heavy solids loading, gives
the technology a wide range of uses. In one location at the WWTF, the filter can be used to
    1.  Produce a reuse quality effluent as a tertiary filter
    2.  Increase the organic removal capacity of the facility, and/or reduce its power consumption
    3.  Treat excess wet-weather flow including biological treatment, as appropriate
The first two functions are accomplished during dry weather by a portion of the filter matrix sized for their
specific dual-use (Figure 1). During dry weather, part of the filter matrix acts as a tertiary filter and the
remaining portion as a biofilter. The tertiary filter cells can effectively remove phosphate precipitates created
by addition of metal salts. The biotreatment portion of the filter matrix can be used during dry weather to  treat
primary influent or primary effluent wastewater, removing both particulates and soluble BOD reducing
secondary loadings (one trial showed consistent 38 percent removal, [WWETCO, 2012]) while maintaining a
healthy biological population in the filter media bed for treatment of the wet-weather flow when it occurs.
The biofilter cell matrix is sized for the excess wet-weather flow and TSS conditions to generally meet
secondary treatment effluent criteria. In wet weather, valves are opened or closed to direct the excess flow
through a one or two-stage filter treatment train. A two-stage, wet-weather filter train is shown in Figure 2. In
this case the FlexFilter primarily provides solids separation and the Bio-FlexFilter provides soluble BOD
removal,  optimizing the capacity of each train component. Another operation option allows the FlexFilter or a
portion of it to be used in the tertiary filter mode during smaller, wet-weather events. Only during larger events
would the entire filter matrix be dedicated to wet-weather treatment. When biological treatment is not required,
the Bio-FlexFilter cells can be eliminated. In this case, the FlexFilter would still be applied in the same  two
modes shown in Figures 1 and 2 (the Bio-FlexFilter being excluded), with both filter effluents going to
disinfection.

A filter cell treating wet weather or primary type solids uses the neighboring filter effluent for backwash supply.
When treating a waste with low solids (primary or secondary effluent), the filter cell can use the influent water
as backwash supply.  Low head air scrubs the media  and lifts the spent backwash into the backwash trough to
waste. Backwash from the filter would normally be routed to the plant influent, backwash from the biofilter
would normally be sent to solids processing. Excess biological growth is controlled with  a dilute chlorine
(3 mg/L) solution added to the backwash.
4-4
                                                  Wastewater Treatment and In-Plant Wet Weather Management

-------
March 2013
        Emerging Technologies
  Treatment
                                prepared 2012
Technology Summary
Compressible Media Filtration (CMF) (continued)
Figure 1. Dry
Figure 2. \
process 1

Dry Weather Treatment Train
Preliminary
Treatment
Primary
Clarifier
_£*
Bo og'ca
Treatment
Secondary
Clarifier
r

Disinfection



Primary Influent 'pr Primary Effluent
FlexFilter Effluent \ Backwash
Bio-Filter Effluerit 1

i 1!: i
FlexFilter™ CP Bit
Secondary
Effluent
^ . t ^
Low Head

Bio-FlexFilter
^ Effluent To
Solids
- . Processing
>-F!exFilter™

Metal Salts Option Pumping
for Phosphorous
Trimming


i
Reuse Quality
Filter Effluent

r-Weather Flow Schematic. Either filter system can be operated individually.
Wet Weather Treatment Train
Preliminary t
Treatment f
Primary
Clarifier

Biological
Treatment
4.
Secondary
Clarifier
v
Disinfection
1 "

xcess Wet Weather
:iow (WWF)
(Optional)


Backwash
1
V !| ^
FlexFilter™ (T1 Bit
A A * '
High Performance
Solids Separation Low Head
Pumping




; Backwash
To Solids
Processing
i
3-FlexFilter™
Bio-Filtration for
Soluble Organic
Removal


Wet-Weather Flow Schematic. Shows a two-stage FlexFilter/Bio-FlexFilter
train. A single-stage FlexFilter could also be appropriate for wet-weather
CSO applications without biological treatment.
Wastewater Treatment and In-Plant Wet Weather Management

-------
Emerging Technologies
                                        March 2013
  Treatment
                                   prepared 2012
                      Technology Summary
  Compressible Media Filtration (CMF) (continued)
  The passively operated matrix of the FlexFilter cells works with simple flow and level logic controls, open-
  close valves, and a low-head blower for cleaning and pumping the spent backwash water to waste. The
  multifunction filter makes this technology very attractive for satisfying current and future regulatory mandates
  for phosphorous control, excess wet-weather treatment and as an intermediate wastewater treatment step to
  reduce overall plant energy consumption and/or increase plant organic treatment capacity. A trial in Atlanta
  (McKern, 2004), showed that the FlexFilter is suitable for removal of TSS from raw CSO flow (75% to 94%)
  and sedimentation basin effluent (35%).
  Sizing of the filter matrix is a function of hydraulic and solids loading and the available head. Peak hydraulic
  loading rates (HLRs) range from 10 to 20 gpm/sq ft, with the lower end for high-strength wastewaters like
  CSOs and primary influent sewage. The higher HLR would apply to the more dilute solids concentrations such
  as from a tertiary filter or dilute wet weather. Chemically assisted phosphorous removal HLR is 5 to 10 gpm/sq ft,
  depending on the concentration of metal salt/soluble phosphorous precipitate required. For CSO or primary
  influent applications, the footprint of the concrete filter structure (10 MGD) including influent/effluent channels
  and operating and backwashing cell chambers would be less than 210 sq ft per MGD (WWETCO, 2012). A
  smaller footprint would be used for SSO or tertiatry applications. The filter system footprint above 10 MGD
  decreases with increasing flows. Also according to the manufacturer, the filter matrix footprint without the
  peripheral concrete channels and chambers can  be reduced by about one-third using influent and effluent
  piping. The depth of the typical high solids filter is about 14 feet. Steel tank tertiary filters are 10 feet tall.
  Existing filter basins at 6- and 7-foot depths can be retrofitted.

  Comparison to Established Technologies:
  According to Frank and Smith (2006) the WWETCO FlexFilter technology provided comparable effluent TSS
  (49 mg/L to  52 mg/L) with the ballasted flocculation systems in side-by-side testing. However, ballasted
  flocculation  require flocculation chemicals and  ramp-up time (15 to 30 minutes) to achieve performance
  objectives. The WWETCO FlexFilter can meet similar or better TSS removals, requires no chemicals, and
  immediately achieves performance objectives. The FlexFilter starts dry and ends dry without odor issues,
  without special startup protocols, and without special attention to mechanical equipment. Although the
  WWETCO filter footprint is generally somewhat larger than the footprint for ballasted sedimentation, it is roughly
  half as deep. FlexFilter throughput for tertiary filtration is in the order of 98 percent (WWETCO, 2012). Average
  throughput for CSO is about 95 percent (< 5%  backwash per McKern, 2004). The throughput for chemically
  assisted phosphorous filtration and biofiltration is in the order of 85 to 90 percent (WWETCO, 2012).

  Available Cost Information:
  Approximate Capital Cost:  Equipment includes the filter media  bed (all internal structural metals, media,
  compression bladder, airdiffuser), complete controls, valves/gates and actuators and blower package with
  redundancy. Equipment costs vary with the scale of the facility. Smaller flows will result in greater redundancy
  because of the minimum size of the equipment. Costs decrease with increasing flows above 10 MGD.
  Equipment costs for the 10-MGD filter matrix can be generalized  as follows:
Application
Tertiary filter
SSO and primary effluent
CSO and influent
Estimated equipment cost ($ per gallon capacity)
Less than $0.06
Less than $0.07
Less than $0.09
  Approximate O&M Costs: Operation costs are summarized as follows (WWETCO, 2012):
     1.  Tertiary filtration - 10 kW per MGD treated (20 mg/L TSS influent)
     2.  SSO or primary effluent - 35 kW per MGD treated (100 mg/L TSS influent)
     3.  CSO or primary influent - 60 kW per MGD treated (200 mg/L TSS influent)
4-6
Wastewater Treatment and In-Plant Wet Weather Management

-------
March 2013
                                                                           Emerging Technologies
  Treatment
                                 prepared 2012
                                                                  Technology Summary
  Compressible Media Filtration (CMF) (continued)
                                                 Installation(s):
                                                 FlexFilter
                                                 Columbus, GA
                                                 Heard County Water Authority, Franklin,GA
                                                 Lamar, MO
                                                 Springfield, OH (2012)
Vendor Name(s):
WWETCO, LLC
152 Hickory Springs Industrial Dr.
Canton, GA30115
Telephone: 404-307-5731
Email: info@westech-inc.com
Web site: http:/www.wwetco.com
                                               Bio-FlexFilter
                                               Manila, Philippines
Key Words for Internet Search:
Wet weather filtration, CSO, SSO, bio-filtration, enhanced primary filtration, intermediate wastewater
treatment, roughing filter, HRT, phosphorus removal, tertiary filtration, compressed media filter
Data Sources:
Arnett, C.A., et al., "Bacteria TMDL Solution To Protect Public Health And Delisting Process in Columbus,
GA," WEFTEC, 2006.
Frank, D.A., and T.F. Smith III, "Side by Side by Side, The Evaluation of Three High Rate Process
Technologies for Wet Weather Treatment," WEFTEC, 2006.
McKern, R. et al., "Atlanta CSO Pilot Plant Performance Results," WEFTEC, 2004.
WERF, Peer Review: Wet Weather Demonstration Project in Columbus, Georgia, Co-published: Water
Environment Research Foundation, Alexandria, VA, and IWA Publishing, London, U.K., 2003.
WWETCO, Boner, M., personal communication, 2012.
Wastewater Treatment and In-Plant Wet Weather Management
                                                                                          4-7

-------
Emerging Technologies
                                       March 2013
  Treatment
                                  updated 2008
                     Technology Summary
  Continuous Deflection Separator (CDS)
  Objective:
  Separates debris, sediments, oil, and grease from
  stormwater runoff.
  State of Development:
  Innovative.
  Description:
  The CDS is a hydrodynamic separator similar to a vortex separator, but the CDS has a filtration mechanism
  for solid separation. With the circular flow and particle sedimentation, the filtration mechanism increases
  removal rates during high flows. The screen is arranged so that the flow provides a scouring action intended
  to prevent plugging. Sediment trapping efficiency is a function of screen  size. During flow events, the
  diversion weir bypasses the separation chamber to avoid washing trapped solids into the effluent flow. CDS
  units are available either precast or cast-in-place, and offline units can treat flows from 1 to 300 cubic feet per
  minute (cfm). The inline units treat up to 6 cfm and internally bypass flows in excess of 50 cfm. Floating
  sorbents have been used to improve removal of oil and grease.
               Slorm Drain
                                                 Storm Bypass Weir
                     Storm Drain
                  Inlet
                  Separation
                  Screen
                                                            Catch men I Sump Wilh
                                                            <  U ;ui;.nl Basket
                                         CDS Diagram

  Comparison to Established Technologies:
  CDS operation is independent of flow for wide treatment ranges.
  Available Cost Information:
  Approximate Capital Cost: Site specific and ranges from $5,000 to $50,000.
  Approximate O&M Costs: Depend on flow and frequency of application.
  Vendor Name(s):
  CONTECH® Construction Products, Inc.
  9025 Centre Pointe Dr., Suite 400
  West Chester, OH 45069
  Telephone: 800-338-1122 or 513-645-7000
  Web site:
  http://www.conteches.com/Products/Stormwater-
  Management/Treatment/CDS.aspx
  Installation(s):
  Bayside Bridge, Pinellas County, FL
  Bovina, NY
  Cincinnati, OH
  Harrisonburg, VA
  Lansing, IL
  Ontario Mills, Ontario, CA
4-8
Wastewater Treatment and In-Plant Wet Weather Management

-------
March 2013
        Emerging Technologies
  Treatment
                                 updated 2008
Technology Summary
  Continuous Deflection Separator (CDS) (continued)
                                                 Pacific Grove, CA
                                                 Redmond, WA
                                                 Redondo Beach, CA
                                                 Stanford University, Stanford, CA
                                                 Weehawken, NJ

  Key Words for Internet Search:
  CONTECH, Continuous Deflection Separation, CDS

  Data Sources:
  Vendor web site: http://www.contech-cpi.com/
  http://www.state.nj.us/dep/dsr/bscit/cds_verification.pdf, "NJCAT Technology Verification Addendum Report:
  High Efficiency Continuous Deflective Separators," CDS Technologies, Inc., 2004.
  Cook, T.J.F., et al., "The effectiveness of Continuous Deflective Separation (CDS) pollutant traps in reducing
  geochemical input into urban wetlands: A comparative study of two contrasting stormwater catchments, Perth,
  WA." 2003. Advances in Regolith, Proceedings of the CRC LEME Regional Regolith Symposia, Roach I.e.,
  ed., pp. 80-81,2003.
  Schwarz, T., and S. Wells, "Storm Water Particle Removal using Cross-Flow Filtration and Sedimentation,"
  Advances in  Filtration and Separation Technology, Vol. 12, W. Leung, ed., American Filtrations and
  Separations Society, pp. 219-226, 1999.
  United States patent (Patent Number: 5,788,848) - Apparatus and Methods for Separating Solids from
  Flowing Liquids or Gases, August 4,  1998.
Wastewater Treatment and In-Plant Wet Weather Management
                        4-9

-------
Emerging Technologies
                                                                                    March 2013
  Treatment
                                 updated 2012
                                                                  Technology Summary
  TRASHMASTER™ Net Capture System
                                                 State of Development:
                                                 Innovative.
Objective:
Wet-weather management of trash and debris
removal from combined sewer overflows and
stormwater systems.
Description:
The TRASHMASTER Net Capture System is a molded structure with nets that removes accumulated trash,
sediments, and debris in a combined sewer overflow or stormwater collection system. The operating principle
of the system is to capture trash, debris, and sediment in special removable nets as the water flows through
the unit. No electrical connections are required. It is used only in low-flow applications (5 cubic feet per
second [cfs] or less) and inserts in-line on the existing piping. It is a lightweight, roto-molded, fiberglass unit
that is easy to install on pipes that are 24 inches or smaller in diameter by using on-site equipment. No special
construction is  necessary. The unit can be installed in two days or less to depths of 10 feet. The unit can also
accommodate special chemical feed systems to treat waterborne impurities.
Comparison to Established Technologies:
The TRASHMASTER Net Capture System is a unique solution to remove trash and debris in low flowing
water. The vendor, Fresh Creek Technologies, produces similar, established technologies (e.g., Netting
TrashTrap® System). Other established technologies require extensive engineering, special installation
equipment, a more expensive product, and a week or longer to install.

Available Cost Information:
Approximate Capital Cost: Approximately $40,000.
Approximate O&M Costs: Approximately $110  per event.
  Vendor Name(s):
  Fresh Creek Technologies, Inc.
  1384 Pompton Ave., Suite 2
  Cedar Grove,  NJ 07009
  Telephone: 973-237-9099
  Fax: 973-237-0744
  Web site: www.freshcreek.com
                                                Installation(s):
                                                Elizabeth Township, PA
                                                Kingston, Ontario, Canada
                                                Signal Hill, CA
                                                Somerville, NJ
  Key Words for Internet Search:
  TRASHMASTER Net Capture System, netting systems, Fresh Creek Technologies
  Data Sources:
  Email and telephone conversations with vendor.

  http://www.freshcreek.com
4-10
                                              Wastewater Treatment and In-Plant Wet Weather Management

-------
March 2013
                                                                               Emerging Technologies
  Treatment
                                   prepared 2012
                                                                      Technology Summary
  Treatment Shaft
                                                    State of Development:
                                                    Innovative.
Objective:
Automated capture and treatment of large combined
sewer overflows in a compact structure. Minimal
head loss, primary settling, skimming, fine screening,
and disinfection in a unit.
Description:
The Treatment Shaft is a deep, in-ground, vertical shaft to provide disinfection and detention for wet-weather
flows with low head loss. Treatment Shaft technology provides disinfection contact time, vessel flushing, air
venting, odor control, surge control, skimming, settling, and fine screening in a compact structure suited for
urban sites. During wet-weather conditions, water rises over an upstream interceptor weir and falls into the
Treatment Shaft.  For storms that exceed the shaft capacity, chlorine is automatically injected before the
upstream weir via chemical mixers. The shaft fills and floatables are trapped on the upstream side of the
shaft's  baffle wall. Solids settle in the shaft because of the low upward velocity in the shaft. After the shaft fills,
raked bar screens activate and trap screenings of mostly neutrally buoyant materials while allowing treated
water to overflow to discharge. As the storm event subsides, dewatering pumps activate and screenings and
floatables are  drawn down to around the 10-foot level. A flushing mode begins with a high-pressure nozzle
system to keep in suspension any materials that would normally settle. The dewatering chopper pumps
continue until the shaft is emptied. The shaft can then  be injected with an odor-neutralizing solution.
                                                          Ground Sjlace
                                                                  WSter Flaws Dottier
                                                                 - 'flflenreslment
                        w-rte Wrier - No Morns

                      J [.. Fatal h) HK>::. C-.' wlwts finding.
                         Process Flow Diagram for the Treatment Shaft

  Comparison to Established Technologies:
  Compared to traditional surface storage systems, the Treatment Shaft occupies approximately 15 percent of
  the surface area of a basin of the same volume (Gilberson, 2011). It has 30 to 50 percent lower capital cost
  than comparably sized tunnels or basins (Giulberson 2011). Simple shaft geometry minimizes head loss,
  allowing gravity operation and eliminating the need for booster pump stations. The Treatment Shaft system
  eliminates tunnel and associated drop shafts, riser shafts, construction shafts, ventilation structures, surge
  control tanks, and screening buildings. It also eliminates water infiltration and associated treatment costs,  and
  manual disposal of screenings.
  Available Cost Information:
  Approximate Capital Cost: Example is  $36.8 million for peak design flow of 1,206 MGD and storage capture
  volume of 6.8 MG (NIH  Consultants, 2008)
  Approximate O&M Costs: Compared to tunnels or basins, the Treatment Shaft has automated operation
  and lower O&M requirements.	
Wastewater Treatment and In-Plant Wet Weather Management
                                                                                              4-11

-------
Emerging Technologies
                                                                                   March 2013
  Treatment
                                 prepared 2012
                                                                 Technology Summary
                                                Installation(s):
                                                Dearborn, Ml
  Treatment Shaft (continued)
Vendor Name(s):
Applied Engineering Technologies
2626 Packard Rd.
Ann Arbor, Ml 48104
Telephone: 734-922-5066
Process Wastewater Technologies LLC
(PWTech)
James Heist
9003 Yellow Brick Rd., Suite 5
Baltimore, MD21237
Telephone: 410-238-7977
Fax:410-238-7559
Email: jheist@pwtech.us

Key Words for Internet Search:
Treatment Shaft, combined sewer overflow, CSO, PWTech, AE Technology

Data Sources:
Gilberson, K. "New CSO Treatment Shaft Technology Replaces Cancelled Tunnel Project", Environmental
Science and Engineering Magazine, September 2011.
NIH Consultants LTD, Final Report on Interim Construction Progress: East Dearborn CSO Control Project
Contract No. 6, September 2008.
Wright,  S.J., et al., "Treatment shaft for combined sewer overflow detention," Water Environmental Research,
Vol. 82, No. 5, pp. 434-439, 2010.
AET (www.ae-technologies.net)
PWTech (www.PWTech.us)
http://www.wwdmag.com/channel/casestudies/city-save-120-million-using-innovative-combined-sewer-
o ve rf low-tre atm e nt-s h aft- p
4-12
                                             Wastewater Treatment and In-Plant Wet Weather Management

-------
March 2013
                                                                           Emerging Technologies
  Storage
                                prepared 2008
Technology Summary
  HYDROSELF® Flip Gate Flusher
                                                 State of Development:
                                                 Innovative.
Objective:
Wet-weather management, cleaning of combined
sewer overflows and storage tanks.
Description:
The Hydroself flushing gate system is a method of removal of accumulated sediments and debris in the
combined sewer retention systems, stormwater runoff, and balancing tank. The operating principle for the
Hydroself flushing system is that the flush water is held in reserve and as it is released, there is a high-energy
wave. The wave removes the accumulated debris from the retention chamber and interceptors along the
flushway lengths.
Comparison to Established Technologies:
The Hydroself flushing gate system is not similar to established wastewater technology but is similar to other
innovative technologies that restore the capacity of collection systems. Removing accumulated sediment can
be done manually. The system lessens labor requirements and improves employee safety over manual
cleaning.
Available Cost Information:
Approximate Capital Cost: Approximately $91.44 per square yard of gate area (1995).
Approximate O&M Costs: Approximately $0.07 per square yard of gate area.
  Vendor Name(s):
  Process Wastewater Technologies, Inc.
  9003 Yellow Brick Rd, Suite S
  Baltimore, MD21237
  Telephone:  410-238-7977
  Fax:410-238-7559
  Web site:
  http://www.pwtech.us/HTML/tipping_bucket.html
  Steinhardt  GmbH Wassertechnik
  (Hydroself  Tipping Bucket)
  Roderweg 6-10
  D-65232
  Taunusstein, Germany
  Telephone:  49-6128-9165-0
  Email: info@steinhardt.de
  Web site:
  http://steinhardtgmbh.com/flushing/hydroself-tipping-
  bucket/
  Gabriel Novae and Associates, Inc. (Autoflush)
  3532 Ashby
  Montreal, Quebec H4R 2C1, Canada
  Telephone:  514-336-5454
  Email: gnacso@gnacso.com
  Website: gnacso.com
  Key Words for Internet Search:
  Sewer, tank, flushing, tipping flusher, wet weather management, wet well
                                                Installation(s):
                                                More than 600 units applied in Europe for cleaning
                                                CSO storage tanks
                                                Clough Creek CSO Treatment Facility,
                                                Cincinnati, OH
                                                Cheboygan, Ml
                                                Sarnia, Ontario, Canada
Wastewater Treatment and In-Plant Wet Weather Management
                                                                                         4-13

-------
Emerging Technologies
                                                    March 2013
  Storage
prepared 2008
Technology Summary
  HYDROSELF® Flip Gate  Flusher (continued)
  Data Sources:
  WERF Manual, "Best Practices for Wet Weather Wastewater Flows," 2002.
  Fan, C.Y., et al., "Sewer and Tank Flushing for Corrosion and Pollution Control," EPA/600/J-01/120, USEPA,
  2001.
  EPA, "Combined Sewer Overflow Technology Fact Sheet," EPA 832-F-99-042, 1999.
  Field, R., and T.P. O'Connor, "Control and Treatment of Combined Sewer Overflows." Control and Treatment
  of Combined Sewer Overflows, P. Moffa, ed., Van Nostrand Reinhold, New York, NY, 1997.
  Parente, M., et al., "Evaluation of the New Technology in the Flushing of Detention Facilities," WEFTEC
  Proceedings, 1995.
  Novae, G., and N. Grande, "Cost Analysis of Different Methods of Cleaning CSO and Wastewater
  Equalization Tanks," WEFTEC Proceedings, 1992.
  http://www.epa.gov/ednnrmrl/repository
  http://www.steinhardt.de/htm_en/fset_e.html
4-14
              Wastewater Treatment and In-Plant Wet Weather Management

-------
                                                                              Emerging Technologies

  Storage                        PrePared2oo8                         Technology Summary
 Tipping Flusher
  Objective:                                     State of Development:
  Wet-weather management, cleaning of combined       Innovative.
  sewer overflows, and storage tanks.
  Description:
  The system generally includes filling pipes and valves, a pumping system, and wet well (where restricted by
  the site conditions), and the tipping flusher vessels. The tipping flusher is a cylindrical stainless steel vessel
  suspended above the maximum water level on the back wall of the storage tank. Just before water overtops
  the vessel, the unit's center of gravity shifts and causes it to rotate and discharge its contents down the back
  wall of the tank. A curved fillet at the intersection of the wall and tank floor redirects the flushwater (with
  minimum energy loss) horizontally across the floor of the tank. The fillet size depends on the size of the
  flusher. The flushing force removes the sediment debris from the tank floor and transports it to a collection
  sump at the opposite end of the tank.
  Comparison to Established Technologies:
  The Tipping Flusher is not similar to established wastewater technology, but it is similar to other innovative
  technologies that restore the capacity of collection  systems. Removing accumulated sediment can be done
  manually. The system lessens labor requirements, and  it improves employee safety over manual cleaning.
  Available Cost Information:
  Approximate Capital Cost: Approximately $15/cubic yard of storage, $137/square yard (1998).
  Approximate O&M Costs: $0.10/square yard (1998).
  Vendor Name(s):                                     Installation(s):
  Process Wastewater Technologies, Inc.                    Many European installations, more than
  9003 Yellow Brick Rd, Suite S                              25 installations in the United States
  Baltimore, MD 21237                                      including Saginaw, Ml
  Telephone: 410-238-7977
  Fax:410-238-7559
  Web site: http://www.pwtech.us/HTML/tipping_bucket.html
  Steinhardt GmbH Wassertechnik
  (Hydroself Tipping Bucket)
  Roderweg 6-10
  D-65232
  Taunusstein, Germany
  Telephone: 49-6128-9165-0
  Email: info@steinhardt.de
  Web site: http://steinhardtgmbh.com/flushing/hydroself-
  tipping-bucket/
  Key Words for Internet Search:
  Sewer, tank, flushing, tipping  flusher,  wet weather  management, wet well
  Data Sources:
  WERF Manual, "Best Practices for Wet Weather Wastewater Flows," 2002.
  EPA, "Combined Sewer Overflow Technology Fact Sheet," EPA 832-F-99-042, 1999.
  Field, R., and T.P. O'Connor, "Control and Treatment of Combined Sewer Overflows," Control and Treatment
  of Combined Sewer Overflows, P. Moffa, ed., Van  Nostrand Reinhold, New York, NY. 1997.
  Parente, M., et al., "Evaluation of the New Technology in the Flushing of Detention Facilities," WEFTEC
  Proceedings,  1995.	
Waste water Treatment and In-Plant Wet Weather Management                                            4-15

-------
Emerging Technologies
                                                                                          March 2013
  Disinfection
                                   updated 2012
                                                                       Technology Summary
  Alternative Disinfectants (PAA and BCDMH)
                                                    State of Development:
                                                    Emerging.
Objective:
Alternative to chlorine disinfection using disinfection
products such as peracetic acid (PAA), or Bromo
Chloro Dimethylhydantoin (1-Bromo-3-Chloro-5,5
Dimethylhydantoin [BCDMH]).
Description:
Alternative disinfectants are being applied to wet-weather flows because of their ability to act as high-rate
disinfectant.  PAA is a stronger oxidant than hypochlorite or chlorine dioxide but not as strong as ozone. In
parts of Europe and Canada chlorine is not used because of the potential to form disinfection by-products.
PAA (aka peroxyacetic acid) [CH3CO3H] is an oxidizing agent used as a routine wastewater disinfectant.
Recently approved by EPA specifically as a wastewater disinfectant (Proxitane WW-12), PAA is a clear,
colorless liquid available at a concentration of 12 to 15 percent. With stabilizers to prevent degradation in
storage it exhibits less than 1 "percent decrease in activity per year. At the 12 percent concentration, its
freezing point is approximately -40°C. Although it  is explosive at high concentrations, at 15 percent or less,
PAA does not explode. The solution is acidic (pH 2) and requires care in handling, transport, and storage.
PAA has been used successfully in combination with UV disinfection, allowing reductions in lamp intensity
and less frequent lamp cleaning. It is available in totes or in bulk, should be stored near the point of
application, and should be well mixed where it is introduced. The dosage used for disinfecting secondary
effluent depends on the target organism, the water quality, and the level of inactivation required. For example,
a dosage of 5 mg/L 15 percent PAA, with contact time of 20 minutes, can reduce fecal and total coliform by 4
to 5 logs in secondary effluent (Morris 1993). Dosage of 1-2 mg/L PAA is typical for secondary effluents.
Note,  however, that PAA is less effective for inactivation of spores, viruses, protozoa, and protozoa including
Giardia and Cryptosporidium (Koivunen  et al. 2005; Liberti and Notarnicola 1999).
BCDMH is a chemical disinfectant used  to treat drinking water. It is a crystalline substance, insoluble in water,
but soluble in acetone. It reacts slowly with water,  releasing hypochlorous acid and hypobromous acid.
EBARA Engineering Service Corporation has devised a system to liquefy the BCDMH powder in a mixer with
an injection device. The solution is injected directly into the wastewater, and it relies on the turbulence of the
process to mix into the disinfection process.
Comparison to Established Technologies:
Compared to disinfection with chlorine compounds, PAA does not form harmful by-products after reacting with
wastewater when using dosages typical for secondary effluent. For example, during the trial at St. Augustine
(Keough and Tran 2011), an average PAA dose of 1.5 mg/L provided similar fecal coliform reduction  as a
7 mg/L chlorine dose (both meeting the 200 cfu/00 mL limit), but the chlorine resulted in 170 ug/L total THM
compared to 0.6 ug/L TTHM for PAA. With tertiary treatment, PAA can meet limits of less than 10 cfu/mL but
achieving very low (less than 2 cfu/100 mL) fecal coliform limits required  high PAA doses (Leong et al. 2008).
However, a residual of acetic acid could be present and might exert an oxygen demand or provide  substrate
for bacterial regrowth. Dosages and contact times are no more than required for disinfection with chlorine, so
existing contact tanks should be adequate for conversion to PAA.
BCDMH has a small footprint and is easier to store than chlorine disinfection products. The feed stock is
BCDMH powder, which is liquefied as needed  by feeding through a dissolution mixer with clean water to form
a solution that is injected into the wastewater. The BCDMH powder is reportedly highly stable, with a shelf  life
of longer than one year, making it potentially attractive for use in CSO applications that are characterized by
intermittent operation. BCDMH is an effective disinfectant that can achieve bacterial reductions comparable to
sodium hypochlorite, but it acts in a shorter amount of contact time (typically 3 minutes instead of 5 minutes
for sodium hypochlorite), thereby reducing the size of the contact chamber, which might result in capital cost
savings. Similar to sodium hypochlorite, BCDMH also produces DBPs and disinfection residuals, potentially
requiring the use of a reducing agent.
4-16
                                                 Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
                            Emerging Technologies
  Disinfection
                                  prepared 2008
                   Technology Summary
 Alternative Disinfectants (PAA and BCDMH) (continued)
 Available Cost Information:
 Approximate Capital Cost: Equipment required is similar to that used for hypochlorite systems.
 Approximate O&M Costs: The cost of PAA is approximately $1.00/lb.
  Vendor Name(s):
  Peracetic Acid
  FMC Corporation
  Minh Iran
  1735 Market St
  Philadelphia, PA 19103
  Telephone: 609-951-3180 or 267-357-1645
  Email: Minh.Tran@fmc.com
  Web site: http://www.microbialcontrol.fmc.com
  Solvay Chemicals NA/PERAGreen Solutions
  John Meakim
  2900 Hungary Rd
  Richmond, VA 23228
  Telephone: 804-501-0845x320
  Fax:804-501-0846
  Web site: www.peragreensolutions.com
  BCDMH
  EBARA Engineering Service Corporation
  Shinagawa, NSS-11 Building
  2-13-34 Konan, Minato-Ku, Tokyo, Japan
  Telephone: 81-3-5461-6111 (switchboard)
  Web site: http://www.ebara.co.jp/en/
  Key Words for Internet Search:
  Alternative disinfectant, CSO disinfection, peracetic acid, PAA, peroxyacetic acid, BCDMH
  Data Sources:
  Brian, K., and M. Tran, "Old City, New Ideas: Peracetic Acid in Wastewater Disinfection at St.Augustine,"
  Florida Water Resources Journal, April, 2011.
  Leong, et al., "Disinfection of Wastewater Effluent: Comparison of Alternative Technologies," Water
  Environment Research Foundation (WERF) Report 04-HHE-4, 2008.
  Meakim, J.T., et al., "Peroxyacetic Acid Restores Design Capacity for Fecal Coliform Compliance in an
  Underperforming UV Disinfection Wastewater System with No Capital Upgrade," Proceedings WEF Specialty
  Conference on on  Disinfection, 2009.
  Rossi, S., et al., "Peracetic Acid Disinfection: A Feasible Alternative to Wastewater Chlorination," Water
  Environment Research, Vol. 79, No. 4, pp. 341-350, 2007.
  Moffa, P.E., et al.,  "Alternative Disinfection Technology Demonstrates Advantages for Wet Weather
  Applications," Water Environment and Technology, January 2007.
Installation(s):
Peracetic Acid
Many applications are in Europe, including
    Milan/Taranto, Italy
    Kuopio, Finland
Canadian applications:
    Niagara Falls, Ontario
    Chateauguay, Quebec
    La Prarie, Quebec
U.S. pilots:
    Hannibal, MO
    Steubenville, OH
    Jefferson City, MO
    St Augustine, FL
    Largo, FL
BCDMH
Columbus, GA
Akron, OH
Wastewater Treatment and In-Plant Wet Weather Management
                                          4-17

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Emerging Technologies
                                       March 2013
  Disinfection
                                  prepared 2008
                     Technology Summary
  Alternative  Disinfectants (PAA and BCDMH) (continued)
  Columbus Georgia Waterworks, CSO Technology Testing web site:
  http://www.cwwga.org/NationalPrograms/lndex.htm

  Combined Sewer Overflow Technology Fact Sheet Alternative Disinfection Methods web site:
  www.epa.gov/owmitnet/mtb/altdis.pdf

  Gehr, R., et al., "Disinfection Efficiency of Peracetic Acid, UV and Ozone after Enhanced Primary Treatment
  of Municipal Wastewater," Water Research, Vol. 37, No. 19, pp. 4573-4586, 2003.

  Morris, R., "Reduction of Microbial Levels in Sewage Effluents using Chlorine and Peracetic Acid
  Disinfectants," Water Science and Technology, Vol. 27, 1993.

  WERF, Wet Weather Demonstration  Project in Columbus, Georgia, 98-WWR1P.

  Kitis, M., "Disinfection of Wastewater with Peracetic Acid: A Review," Environment International, Vol. 30,
  pp. 47-55, 2004.

  Koivunen, J.,  and H. Heinonen-Tanski, "Inactivation of Enteric Microorganisms with Chemical Disinfectants,
  UV Irradiation and Combined chemical/UV Treatments," Water Research, Vol. 39, No. 8, pp.1519-1526, 2005.

  Liberti, L, and M. Notarnicola, "Advanced Treatment and Disinfection for Municipal Wastewater Reuse in
  Agriculture," Water Science and Technology, Vol. 40,  No. 4-5, pp. 235-245, 1999.
4-18
Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
                                                                                Emerging Technologies
  Treatment
                                   updated 2012
                                                                       Technology Summary
  BioActiflo® Process
                                                    State of Development:
                                                    Adaptive Use.
Objective:
Biological treatment with high-rate clarification of wet
weather flows.
Description:
The BioActiflo® process is a high-rate process that combines biological treatment with the Actiflo® ballasted
flocculation high-rate clarification process (see separate fact sheet for the Actiflo® process). Biological
treatment is provided by a solids contact basin which is used ahead of the Actiflo high rate clarification. This
basin has a shorter hydraulic retention time and a lower mixed liquor suspended solids (MLSS) concentration
than conventional aeration basins. Biological solids in the return activated sludge (RAS) are used to uptake
soluble biochemical oxygen demand (BOD) and use it as a substrate. Testing to date has shown that the
uptake rate is a function of the return activated sludge (RAS)/wastewater contact time and the amount of
biological solids in contact with the primary wastewater. The target concentration of MLSS in the contact basin
is maintained by using  a portion of the RAS stream in addition to concentrated sludge from the Actiflo high -
rate clarification process. The MLSS is aerated for rapid BOD uptake by the biomass and then flows from the
solids contact tank to the Actiflo® high-rate clarification process which uses coagulation, injection of
microsand and polymer, settling and sand recirculation as described in the Actiflo Technology Summary in
Chapter 2 of this document. The result is a process that provides high removal efficiency of BOD, as well as
suspended solids, thereby achieving biological treatment of excess flows while preserving the integrity of plant
processes and washout of biomass.
Pilot testing of the BioActiflo® process was conducted in Fort Smith, AR in 2004 to 2006, Port Orchard, WA in
2007, and Knoxville, TN in 2010. Bench scale testing was conducted at the Wilson Creek Regional
Wastewater Treatment Plant in Lucas, Texas. The first BioActiflo installation was commissioned in 2012 in
Akron OH and pilot testing is in progress. This testing is focusing on BioActiflo performance for BOD and total
suspended solids (TSS), as well as looking at pathogen removal. While pilot testing to date has shown that
the process is capable  of achieving total BOD removal exceeding 85% and TSS removal of 90% or higher,
current additional testing will provide additional information on process reliability in achieving TBOD and TSS
removal targets.
                                                                                          Effluent To
                                                                                          Outfall
                                                      • ACTIFLO® Ballasted Clarification
I
—
c

Maturation

7 \
Settling
w
                                                  Coag    Polymer
      Diagram of BioActiflo® Configuration (in green) at a Wastewater Treatment Plant
Wastewater Treatment and In-Plant Wet Weather Management
                                                                                               4-19

-------
Emerging Technologies
                                        March 2013
  Treatment
                                  updated 2012
                     Technology Summary
  BioActiflo® Process (continued)
  Comparison to Established Technologies:
  Compared to conventional biological treatment systems, the BioActiflo® provides treatment to all flows
  entering a plant. It also has a relatively small footprint due to its short hydraulic retention time and high
  surface loading rates. While the coagulation and flocculation tanks ahead of the Actiflo unit add to the system
  footprint, this is still a much smaller footprint option than a conventional secondary clarifier (Fitzpatrick et al,
  2012). The clarification part of the BioActiflo® process also allows dual use operations for wet weather peak
  flow treatment and dry weather primary or tertiary treatment if desired. Compared to primary or chemically
  enhanced primary treatment processes, the BioActiflo® process is not as limited by existing clarifier capacity.
  By combining proven treatment technologies such as high-rate contact-stabilization and  ballasted
  sedimentation, site constraints can be ameliorated at significant capital and operating cost savings (Katehis
  et. al, 2011). It should be noted that BioActiflo®testing to date has been based on site specific conditions. As
  such, more data is needed to determine if BioActiFlo could be utilized in lieu of conventional treatment.
  Available Cost Information:
  Approximate Capital Cost: Not disclosed by vendor.
  Approximate O&M Costs: Not disclosed by vendor.
  Vendor Name(s):
  Kruger USA
  401 Harrison Oaks Blvd., Suite 100
  Gary, NC27513
  Telephone: 919-677-8310
  Fax:919-677-0082
  Email: krugerincmarketing@veoliawater.com
  Web site: http://www.krugerusa.com
  Installation(s):
  Fort Smith, AR
  Port Orchard, WA
  Knoxville, TN (Kuwahee and Forth Creek WWTPs)
  Wilson Creek RWWTP, TX (Bench-scale testing)
  Akron, OH
  Key Words for Internet Search:
  BioActiflo®, Ballasted High Rate Clarification, Solids Contact Basin, BHRC

  Data Sources:
  Web site owned by Kruger USA.
  J. D. Fitzpatrick, J.D., et al., "Preparing for a Rainy Day - Overview of Treatment Technology Options for Wet-
  Weather Flow Management", Water Environment Federation's Annual Technical Exhibition and Conference
  (WEFTEC) proceedings, 2012.
  Katehis, Dimitrios, et al., "Maximizing Wet Weather treatment Capacity of Nutrient Removal Facilities", Water
  Environment Federation's Annual Technical Exhibition and Conference (WEFTEC) proceedings, 2011.
  Keller, John, et al., "Actiflo®: A Year's Worth of Operating Experience from the Largest SSO System in the
  U.S.," Water Environment Federation's Annual Technical Exhibition and Conference (WEFTEC) proceedings ,
  2005.
  Sigmund, Thomas, et al., "Operating Chemically Enhanced Clarification for Optimum Disinfection
  Performance," Water Environment Federation's Annual Technical Exhibition and Conference (WEFTEC)
  proceedings, 2006.
4-20
Wastewater Treatment and In-Plant Wet Weather Management

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 Chapter
Process Monitoring  Technologies
  5.1  Introduction
       Process monitoring technologies are a critical component in the improvement of wastewater
       treatment. Process monitoring technologies, can help prevent upsets in treatment systems,
       maintain compliance with discharge limits, and save energy and chemicals used by maximizing
       process efficiency. (They are included for process monitoring only and are not expected to be
       used for compliance monitoring reporting, as described in CFR Part 136. However, they are not
       dispositive for any internal monitoring required by EPA or a State.)
  5.2  Technology Assessment
       The innovative technologies listed in this chapter are focused on online monitoring in
       wastewater treatment systems. These monitoring technologies usually are probes or sensors
       that can detect change in physical, chemical and biological activity, and they can be installed at
       critical points throughout the plant. They can save energy and reduce operation and
       maintenance cost. The innovative process monitoring technologies addressed in this chapter
       are: Fluorescence In Situ Hybridization (FISH) for Filamentous and Nitrifying Bacteria,
       Microtox®/Online Microtox®, Nicotinamide Adenine Dinucleotide (NADH) Probes, Online
       Respirometry, Microwave Density Analyzer, and Nutrient Analyzers, Probes & Electrodes. The
       emerging process monitoring technologies addressed in this chapter are: Biological Micro-
       Electro-Mechanical Systems (BioMEMS), FISH for Phosphorus Accumulating Organisms
       (PAOs), Handheld Advanced Nucleic Acid Analyzer (HANAA), Immunosensors and
       Immunoassays, and Photo-electro Chemical Oxygen Demand (PeCOD™). Quantitative PCR
       (qPCR) technology for quantification of microorganisms based on their DNA is now being
       applied for wastewater treatment research and for rapid detection of pathogens and will be
       included in a future update of this report.

       Table 5.1 includes a listing of established, innovative, and emerging technologies for process
       monitoring. An evaluation of the innovative technologies identified for process monitoring is
       presented in Figure 5.1. Summary sheets for each innovative technology and for each
       emerging technology are  provided at the end of this chapter.

       Knowledge about technologies tends to evolve. The information provides a snapshot at a point
       in time; what is understood at one point in time may change as more information develops.
       This includes knowledge about operating mechanisms as well as the relative and absolute
       costs and features of a particular technology. Inquiries into the current state of knowledge are
       an important step when considering implementation of any technology.
Wastewater Treatment and In-Plant Wet Weather Management
5-1

-------
Emerging Technologies
                                          March 2013

Table 5.1 — Process Monitoring Technologies - State of Development
Established Technologies (technology summaries not included)
Microbial Activity
Dissolved Oxygen Analyzer
Oxidation Reduction Potential (ORP) Probe
Solids Retention Time (SRT) Controller
Solids
Sludge Blanket Level Detector
Total Suspended Solids Analyzer
Water Quality
Online Cb Residual
pH Probes
Innovative Technologies
Summary on
page
Microbial Activity
Fluorescence In Situ Hybridization (FISH) for Filamentous and Nitrifying Bacteria
Microtox®/0nline Microtox®
Nicotinamide Adenine Dinucleotide (NADH) Probes
Online Respirometry
5-4
5-5
5-6
5-7
Solids
Microwave Density Analyzer
5-8
Water Quality
Nutrient Analyzers, Probes, and Electrodes
5-9
Adaptive Use Technologies
None at this time
Emerging Technologies
NA
Summary on
page
Microbial Activity
Biological Micro-Electro-Mechanical Systems (BioMEMS)
FISH for Phosphorus Accumulating Organisms (PAOs)
Handheld Advanced Nucleic Acid Analyzer (HANAA)
Immunosensors and Immunoassays
5-12
5-13
5-14
5-15
Water Quality
Photo-electro Chemical Oxygen Demand (PeCOD™)
5-16
Research Technologies
None at this time.

5-2
Wastewater Treatment and In-Plant Wet Weather Management

-------
March 2013
                                                        Emerging Technologies
                                                    Microbial Activity
  Fluorescence In Situ Hybridization
  (FISH) for Filamentous and Nitrifying
  Bacteria
 I, M, N
C,0,S
 NA
  Microtox®/0nline Microtox®
 I, M, N
C,0,S
 NA
e
  Nicotinamide Adenine Dinucleotide
  (NADH) Probes
 I,M, N
 c,o
 NA
  Online Respirometry
 I,M, N     F      C,0,S    A      A      G      NA      A      0     A
                                                         Solids
  Microwave Density Analyzer
 I, M, N
C,0,S
 NA
                                                      Water Quality
  Nutrient Analyzers, Probes, and
  Electrodes
 I, M, N
C,0,S
Dn.ln
  Key
      Statement of Development
     B = Bench scale
     I = Full-scale industrial applications
     M = Full-scale municipal applications
     0 = Full-scale operations overseas
     P = Pilot
     N = Full-scale operations
       in North America
F = Few plants
I = Industrywide
L = Primarily large plants
S = Primarily small plants
      C = Capital savings
      I = Intense operational demand
      0 = Operational/maintenance savings
      S = Shock load capacity
      W = Wet weather load capacity
      E = Effluent quality
                                                            "luent Reuse
     Dp = Direct potable
     Dn = Direct nonpotable
     lp= Indirect potable
     In = Indirect nonpotable
                                                                  Comparative Criteria
                                                                    A  Positive feature
                                                                    0  Neutral or mixed
                                                                    T  Negative feature
              Figure 5.1— Evaluation of Innovative Process Monitoring Technologies
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                                                                            5-3

-------
Emerging Technologies
                                                       March 2013
  Microbial Activity
prepared 2008
Technology Summary
  Fluorescence In Situ Hybridization  (FISH) for Filamentous and  Nitrifying
  Bacteria
  Objective:
  Identify and quantify specific microorganisms in
  wastewater.
                State of Development:
                Innovative.
  Description:
  Bacteria in activated sludge contains DMA as unique genetic material. DMA sequences unique to individual
  groups of microorganisms can be used to identify specific microorganisms in a sample containing a mixture of
  many different types of microorganisms. The process of identifying specific microorganisms is part of the full-
  cycle 16S Ribosomal Ribonucleic Acid (rRNA) approach by using FISH. Fluorescently labeled 16S rRNA
  probes are hybridized, stained, and observed under an epifluorescent microscope. This document discusses
  the on-line version, not the field test kit. FISH was developed in the 1990s and routinely is used in medical
  fields. More recently it has been applied to the wastewater treatment field, as well as at wetlands. Also, it has
  potential applicability for monitoring efforts such as tracking fecal organisms ("microbial source tracking").
  Comparison to Established Technologies:
  The microbial detection process is able to positively identify specific microorganisms in a  mixed culture.
  Previously, microbiological tests performed in a laboratory were necessary to  identify and enumerate bacteria.
  This process provides real-time feedback, over laboratory tests that take hours or even days for results.
  Another advantage of using FISH is that it does not have to be performed on cells that are actively dividing,
  which makes it a more versatile test. Use of FISH is now fairly common.
  Available Cost Information:
  Approximate Capital Cost: Unknown.
  Approximate O&M Costs: Unknown.
  Vendor Name(s):
  Department of Civil and Environmental Engineering
  at the following universities:
  University of Illinois, Urbana-Champaign
  University of Cincinnati
  North Carolina State University
                 Installation(s):
                 Littleton/Englewood Wastewater Treatment Plant
                 Englewood, Colorado 80110
                 (Profile data were collected monthly since July 1996
                 during this NSF grant period.)
  Key Words for Internet Search:
  Fluorescence In Situ Hybridization, FISH, 16S rRNA, full-cycle 16S rRNA approach, phylogeny
  Data Sources:
  Department of Civil and Environmental Engineering, University of Illinois, Urbana-Champaign, University of
  Cincinnati, and North Carolina State University.
  Sidney Biesterfeld, Linda Figueroa, Mark Hernandez, and Phil Russell, Colorado School of Mines,
  Littleton/Englewood Wastewater Treatment Plant, Englewood, Colorado, and University of Colorado, Boulder,
  80309: Use of Fluorescent Oligonucleotide Probes to Characterize Vertical Population Distributions of
  Nitrifying Bacteria in a Full-Scale Nitrifying Trickling Filter, 1998.
5-4
               Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
                                                                           Emerging Technologies
  Microbial Activity
                                prepared 2008
Technology Summary
  Microtox®/Online Microtox®
                                                   State of Development:
                                                   Innovative.
Objective:
Acute toxicity analysis for wastewater, water, soil, and
other hazardous waste applications.
Description:
The toxicity test is based on indigenous bioluminescence of a marine bacterium (Photobacterium
phosphoreum to Vibrio fischeri strain, NRRL B-11177). The aqueous samples are incubated for controlled
time and luminators are used to compare the reduction in light of the sample with a control culture of the
bacterium. The proportional reduction in bioluminescence is indicative of toxicity of the sample. The Microtox®
instrumentation  systems are available for online and offline toxicity analysis.
Comparison to Established Technologies:
Microtox® monitoring is a biosensor based on a toxicity measurement system. The Microtox® process can
provide near real-time monitoring of water and wastewater and is much faster than other laboratory based
analysis.
Available Cost Information:
Approximate Capital Cost: $17,895.
Approximate O&M Costs: Costs: $2.50 to $7 per test. Cost information includes the cost for the software for
the unit. The O&M cost varies depending on the dilution range of toxicity tests.
                                                   Installation(s):
                                                   Petersburg, VA
Vendor Name(s):
Modern Water (current owner of this technology)
15 Read's Way, Suite 100
Newcastle, DE 19720
Telephone: +001 302-669-6900 or +1(0) 302 669 6900
Email: info@modernwater.com
Email UK: info@modernwater.co.uk
Web site: http://www.modernwater.co.uk
Strategic Diagnostics, Inc.
(former owner of this technology)
111 Pencader Drive
Newark, DE 19702
Telephone: 302-456-6789 or 800-544-8881
Email: sales@sdix.com
Web site: http://www.sdix.com
Key Words for Internet Search:
Microtox®, toxicity test, wastewater, online
Data Sources:
WERF Report, Collection and Treatment - A Review and Needs Survey of Upset Early Warning Devices,
Final Report, 2000.
Web site sources are as follows:
http://www.modernwater.co.uk
http://www.sdix.com
http://www.azurenv.com
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Emerging Technologies
                                                      March 2013
  Microbial Activity
updated 2012
Technology Summary
  Nicotinamide Adenine Dinucleotide (NADH) Probes
  Objective:
  NADH process probes can be used for aeration control
  to maintain simultaneous nitrification and denitrification
  conditions.
                  State of Development:
                  Innovative. (Not currently licensed for sale in the
                  United States as of 2012.)
  Description:
  Nicotinamide adenine dinucleotide (NAD) is an intermediate compound in biological reactions that functions to
  transport electrons from a reduced substrate (i.e., chemical oxygen demand) to the biosynthetic pathways. In
  its reduced form, it exists as NADH or NADPH and is commonly referred to as reducing power. When light at
  340 nm strikes NADH, it fluoresces and emits light at 460 nm. NADH probes emitting 340 nm and detecting
  460 nm can be used to monitor the level of reducing power by measuring fluorescence, which indicates the
  concentration of NADH. The measurement is done using immersed probes with no sampling or subsequent
  analysis. The SymBio process has applied NADH measurement (along with measurement of the dissolved
  oxygen level) to control aeration as needed to optimize Simultaneous Nitrification and deNitrification (SNdN)
  in the same basin. When properly controlled the SNdN process provides denitrifying anoxic
  microenvironments  inside the activated sludge floe at the same time as aerobic nitrifying conditions are
  provided at the floe  surface and in the bulk water.
  Comparison to Established  Technologies:
  Other technologies  that monitor the oxidation/reduction level of the bioreactor are dissolved oxygen probes
  and oxidation reduction potential (ORP) probes. Both are inferior to NADH as measures of biomass reducing
  power. ORP measurements include the reducing power contributed by reduced substrates whether the
  biomass is able to act on them. Dissolved oxygen probes provide information on only a single oxidizing
  compound (oxygen) and provide no information on the state of the reactor environment when it contains no
  dissolved oxygen as in anoxic or anaerobic conditions.
  Available Cost Information:
  Approximate Capital Cost: 2005 cost for SymBio was approximately $100,000 for one sensor with a
  process control package. The SymBio process and NADH probe technology are no longer licensed for sale in
  the United States. For possible site-specific licensing,  contact former licensee Ovivo Water (Enviroquip).
  Approximate O&M Costs: No additional costs for O&M are incurred.
  Vendor Name(s):                               Installation(s):
  Ovivo Water (Enviroquip)                            More than 40 municipal applications are in the
  Formerly licensed to sell SymBio in the United States      United States including:
  2404 Rutland Dr, Suite 200
  Austin, TX 78758
  Telephone: 512-834-6029
  Email: chintan.parikh@ovivowater.com
                  Bend OR, Big Bear CA, Lake Elsinore CA,
                  New Philadelphia OH, Perris CA,
                  Pflugerville TX, Rochelle IL, Stonington CT
  Key Words for Internet Search:
  SymBio, NADH, Simultaneous nitrification denitrification, SNdN
  Data Sources:
  Trivedi, H., and N. Heinen, "Simultaneous Nitrification/Denitrification by Monitoring NADH Fluorescence in
  Activated Sludge," WEFTEC 2000.

  Chintan Parik, Ovivo Water, June 7, 2012.
5-6
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March 2013
                                                                            Emerging Technologies
  Microbial Activity
                                prepared 2008
Technology Summary
  Online Respirometry
                                                   State of Development:
                                                   Innovative.
Objective:
Measures cellular respiration or oxygen uptake rate.
Description:
Respirometry devices are used for biotreatment process control. The device can be set up and operated in
different modes. For oxygen uptake-based respirometers, oxygen is measured either in closed headspace
gas or liquid phases. The respirometry rate measurement can also determine the shock-load measurement
and toxicity in a system when the baseline respirometry rate has been set for a system.
Respirometer's sensors can also be calibrated to measure other gases of concern like carbon monoxide,
hydrogen sulfide, and methane.
Comparison to Established Technologies:
Traditionally, respirometric studies or kinetic parameters for wastewater treatment have been performed in
laboratories with use of dissolved oxygen probes. During the stabilization of probes in the laboratory, sensitive
information was lost, which was critical for measuring oxygen uptake rates and dissolved oxygen rates. The
real-time feedback using the probes provides more reliable information on oxygen uptake.
Available Cost Information:
Approximate Capital Cost: 1 unit of the respirometer Respicond V for about $60,000 U.S.
Approximate O&M Costs: Unknown.
Cost based on the published cost for the Respicond V on  the web site of A. Nordgren Innovations AB, Sweden.
Vendor Name(s):                               Installation(s):
A. Nordgren Innovations AB                         There are no known installations.
Djakneboda 99
SE915 97 Bygdea, Sweden
Telephone: 46-934-31260
Email: a.nordgren@respicond.com
Web site: http://www.respicond.com
Columbus Instruments
950 N. Hague Avenue
Columbus, OH 43204
Telephone: 614-276-0861 or 800-669-5011
Email: sales@colinst.com
Web site: http://www.colinst.com
Respirometry Plus, LLC
P.O. Box 1236, Fond du Lac, Wl 54935-1236
Telephone: 800-328-7518
Email: operations@respirometryplus.com
Web site: http://www.respirometryplus.com
Key Words for Internet Search:
Cellular respiration, online respirometry, biotreatment process control, oxygen respirometer
Data Sources:
WERF web site and publications.
Research journals and publications.
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Emerging Technologies
                                       March 2013
  Solids
                                  prepared 2008
                     Technology Summary
  Microwave Density Analyzer
  Objective:
  Solids measurement.
  State of Development:
  Innovative.
  Description:
  The microwave sludge density transmitter uses microwave-phase difference measurements to determine the
  density of solids flowing through pipes. This method exploits the way that fluid density affects the propagation
  of microwaves when they pass through it. The Microwave Density Analyzer allows reliable measurement of
  the sludge density and monitors the difference in microwave phase between the original wave and one wave
  that passed through the measured fluid. Unlike the method of monitoring the attenuation of a transmitted
  wave, measuring flow density by observing a wave's phase difference is not affected by flow velocity and is
  resistant to the effects of contamination, scaling, fouling, and gas bubbles. It uses no moving mechanical
  parts or mechanism that is often used in other measuring methods for cleaning, sampling, or defoaming. It
  permits continuous measurement. The density meter measures density in electric current, which is suitable for
  an application in a process for monitoring and controlling.
  Comparison to Established Technologies:
  This density meter has adapted a new measuring method called "phase difference method by microwaves."
  When microwaves go through a substance and come out of it, This density measures the phase lag of the
  waves and obtains a certain physical property of the substance that is proportional to the density.
  Available Cost Information:
  Approximate Capital Cost: 8-inch density meter is about $75,000 to $100,000 depending upon the specific
  application.
  Approximate O&M Costs: Not disclosed.
  Vendor Name(s):                             Installation(s):
  Toshiba International Corporation                  Blue Plains AWTP, Washington, D.C.
  Industrial Division
  Houston, TX
  Telephone: 713-466-0277
  FAX: 713-896-5225
  Email: 800-231-1412

  Key Words for Internet Search:
  Microwave Density Analyzer, LQ500, LQ300, LQ510
  Data Sources:
  Engineering Program Management Consultancy Services,  CH2M HILL, Parsons, "Evaluation of the Test
  Results for the Microwave Sludge Density Meter at the Gravity Sludge Thickener (GST) No. 7," Blue Plains
  AWTP, Interoffice Memorandum, 2006.
  Toshiba web site: http://www.toshiba.com/ind/product_display
5-8
Wastewater Treatment and In-Plant Wet Weather Management

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                                                                                 Emerging Technologies

  Water Quality                  Updated2oi2                           Technology Summary
  Nutrient Analyzers, Probes, and  Electrodes
  Objective:                                       State of Development:
  In situ, real-time measurement of ammonia, nitrate,      Innovative.
  orthophosphate, and total phosphorus concentration
  for process monitoring and control of nitrification,
  denitrification, and phosphorus removal.
  Description:
  Analyzers
  Analyzers pump a small amount of sample to a device where reagents are involved usually to produce a
  color-generating reaction that is then measured for intensity to determine concentration. These devices are
  available for ammonia, phosphate, and total phosphorus.
  Metrohm-Applikon Alert: This colorimetric analyzer uses differential absorbance colorimetry to determine
  ammonia, nitrate, nitrite, or phosphorus. The Alert colorimeter takes as color measurement using long life
  LEDS, first to establish the initial color and after reagent addition to determine the developed color. The
  differential technique compensates for fouling of the cell and for initial sample color.
  WTW Trescon: This is an analyzer for orthophosphate or total phosphorus. The orthophosphate analyzer
  uses the vanadate/molybdate method to color the sample yellow. The color intensity is measured
  photometrically and  reported as phosphorus content. Ranges are 0.05 to 3.00 mg P/L, 0.1 to 10 mg P/L,  or
  0.1 to 25 mg P/L. For total phosphorus analysis, a digestion unit  is required to provide a chemical-thermal
  digestion that will convert all phosphorus in the sample to phosphate. The phosphate is measured using the
  molybdenum blue method. Ranges are 0.01 to 3.00 mg P/L, and 0.3 to 100 mg  P/L.
  ChemScan UV Series: This consists of an online single  or multiple parameter analyzers using full-spectrum
  UV-visible detection with chemometric analysis of spectral data. Multiple sample lines allow sampling from
  several locations to the same analyzer. The analyzer is script driven and can perform rapid sequential
  analysis with or without the assistance of chemical reagents. Nitrate analysis or a separate analysis (or both)
  of nitrite are performed according to  the direct analysis of spectra from the sample. Ammonia analysis is
  reagent-assisted using bleach and hydroxide  reagents. The analyzer contains an internal manifold to provide
  automatic zeroing, cleaning, and managing multiple sample lines. A variety of accessories are available,
  including sample pumps, filters, and  external controllers.
  Hach AMTAX: This consists of an ammonia sampler with gas-sensitive electrode, low range 0.5 mg/L to
  20 mg NH3-N/L at 3 percent accuracy. It samples at an adjustable frequency of 5 to  120 minutes, mixes the
  sample with sodium hydroxide to convert all ammonium to free ammonia,  expels ammonia gas from sample,
  redissolves it in the indicator reagent and measures color with a colorimeter. It then pumps the sample to the
  analyzer which is mounted out of process. The analyzer requires a consumable reagent.
  Hach PHOSPHAX:  This is a continuous flow  analyzer for ortho-Phosphate using the photometric methods
  with vanado-molydan. It has a five minute cycle time for each measurement and allows for adjustable
  intervals from 5 minutes to 120 minutes. Measurement range is 0.05 -15 mg/L PO4-P. Accuracy at the low
  range is 2% ± 0.05 mg/L. The unit features daily automatic  cleaning and calibration.
  UV/Vis Probes
  WTW NitraVis®: This consists of in situ, real-time spectral measurement (UV and Visibility [VIS] range of 200
  to 750 nm) of nitrate concentration without filtering. Interferences, such as those caused by turbidity, are
  detected and compensated for.  The  process operates  in media at temperatures of at least 32°F, with a pH
  between 4 and 9, and contains less than 5,000 mg/L chloride. Automatic cleaning occurs with compressed air
  before each measurement. The measuring range is 0.1 to 100 mg/L NO3-N with accuracy of ±3 percent.
  Hach Evita: This nitrate probe uses  UV absorption to measure nitrate concentration. The probe is immersed
  in wastewater and the ion-specific membrane allows the appropriate ions to be transferred to the carrier
  solution so no sample preparation is necessary and interference  from bacteria and particles is virtually
Wastewater Treatment and In-Plant Wet Weather Management                                               5-9

-------
Emerging Technologies
                                                      March 2013
  Water Quality
updated 2012
Technology Summary
  Nutrient Analyzers, Probes, and Electrodes (continued)
  eliminated. It uses deionized water that needs to be refilled every 10 weeks. The measuring range is 2 to
  50 mg/L NO3-N with accuracy of ±10 percent. It can take readings about every 13 minutes.
  Hach NITRATAX: This probe is based on UV light absorption. The photometer measures the primary UV 210
  beam, and a second beam at 350 nm provides a reference standard. Measuring range is 0.1 to 100 mg/L
  NO3-N at 5 percent accuracy. It includes a self-cleaning wiper system.
  Ion Selective Electrodes
  WTW ISE: Direct immersion ion selective electrodes (ISEs) are available in combination ammonium/nitrate
  (VARiON), ammonium with  potassium compensation, and nitrate with chloride compensation. These all
  provide continuous measurement of process concentrations. Ranges are 0.1 to 100 mg/L or 1 to 1,000 mg/L
  as nitrogen for either parameter.
  Biochem/Myratek Sentry C-2: This electrode is based on ISE technology. A sample is isolated in the
  measuring chamber and ammonia and the nitrate values established. Calibration using the standard addition
  method is performed automatically at user-set intervals. Installation takes less than 1 hour; maintenance less
  than 15 minutes per week.
  Hach NH4D Ammonium Probe: This consists of direct immersion ISE for measuring ammonium  from 0.2 to
  1,000 mg/L NH4-N with 5 percent accuracy. Potassium interference is compensated by including a potassium
  ISE. Provides continuous measurement. Can be provided with optional air cleaning system to reduce
  maintenance frequency.
  Endress + Mauser ISEMax: The ISEMax unit uses a single probe to measure both ammonium and nitrate
  continuously using ISE technology. The range is 0 to 1,000 mg/L ammonium-N, 0.1 to 1,000 mg/L nitrate-N.
  Up to three electrodes can be included in a single probe.

  Comparison to Established Technologies:
  Monitoring used to be done by taking samples and analyzing them for various parameters in laboratories. Lab
  analyses take time, and one cannot resolve a problem until the results are gathered. These  monitoring
  technologies provide real-time or near real-time conditions in the treatment system through continuous
  monitoring. Immediate feedback helps operators immediately take corrective action if a shock or toxic load
  occurs. It can also allow for timely process adjustments that can  reduce energy consumption and  chemical
  usage where applicable.
  ISEs are generally the lowest cost to purchase and maintain. Ammonia ISE probes can be purchased for
  $6,500 to $15,000. Analyzers are most costly and maintenance intensive but could be useful for compounds
  for which ISE probes are not available.
  Available Cost Information:
  Approximate Capital Cost: Equipment costs vary from approximately $6,000 to $25,000 depending on
  capabilities and features.
  Approximate O&M Costs: Costs vary with frequency of calibration requirements, cleaning, and analyzer
  reagents. Analyzers have greatest operation and maintenance followed by UV/VIS. ISEs are least costly to
  maintain.
  Vendor Name(s):
  Metrohm-Applikon
  De Brauwweg 13
  PO Box 149
  3100 AC Scheidam
  The Netherlands
  Telephone: +31 10 298 35 55
  Email: analyzers@metrohm-applikon.com
                Installation(s):
                Many installations are throughout the US:
                Metrohm-Applikon
                Hampton Roads Sanitation District
                Norfolk, VA

                Hach AMTAX
                Messerly WWTP
                Augusta,  GA
5-10
               Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
                                                                         Emerging Technologies
  Water Quality
                               updated 2012
Technology Summary
  Nutrient Analyzers, Probes, and Electrodes (continued)
                                                Chemscan
                                                Curren WWTP
                                                Tampa, FL
                                                Biochem Sentry C-2
                                                23rd Avenue WWTP
                                                Phoenix, AZ
                                                South Cross Bayou WRF
                                                St. Petersburg, FL
                                                Wastewater Treatment Plant
                                                Enfield, CT
                                                Wastewater Treatment Plant
                                                Abington, PA
ASA/ChemScan
2325 Parklawn Drive, Suite I
Waukesha, WI53186
Telephone: 262-717-9500
Email: info@chemscan.com
Website: http://www.chemscan.com
Myratek, Inc. - BioChem Technology, Inc.
3620 Horizon Drive, Suite 200
King of Prussia, PA 19406
Telephone: 610-768-9360
Email: sales@biochemtech.com
Web site: http://www.biochemtech.com
WTW, Inc.
P.O. Box9010
151 Graham Road
College Station, TX 77842
Telephone: 979-690-5561
Fax: 979-690-0440
Email: info@wtw-inc.com
Web site: http://www.wtw.com
Hach Company
P.O. Box 389
Loveland, CO 80539-0389
Telephone: 800-227-4224
Web site: www.hach.com
Key Words for  Internet Search:
Water monitoring, wastewater, ammonia, nitrates, probe, online analysis, ion selective electrode

Data Sources:
Misiti, John Hach, "UV Spectrum Based NOx Monitors," paper.
Web site sources:
http://www.chemscan.com
http://biochemtech.com
http://www.hach.com
http://www.wtw.com
http://www.roycetechnologies.com
Vendor-supplied information.
Wastewater Treatment and In-Plant Wet Weather Management
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Emerging Technologies
                                                                                   March 2013
  Microbial Activity
                               prepared 2008
Technology Summary
  Biological  Micro-Electro-Mechanical Systems (BioMEMS)
                                                  State of Development:
                                                  Emerging.
Objective:
Biological Micro-Electro-Mechanical Systems
(BioMEMS) are aimed at rapid testing of biomolecules
that are indicative of an upset process.
Description:
BioMEMS are being developed for the faster detection of upset signs in a bioprocess by using microchips or
integrated circuits that can detect and quantify the biomolecules that cause process upsets. The systems aim
at detecting the changes in the microbial activities that are caused by a shock load ortoxicity. BioMEMS can
be a very useful in predicting operational problems before they occur, such as bulking, foaming, and
detecting, which cause operational problems because of changes to microbial population.
Comparison to Established Technologies:
Not similar to any established technology.
Available Cost Information:
Approximate Capital Cost: Unknown.
Approximate O&MCosts: Unknown.
Vendor Name(s):
University of Cincinnati
Water Quality Biotechnology Program
Room 765, Baldwin Hall, Box 210071
Cincinnati, OH 45221-0071
Telephone: 513-556-3670
Email: daniel.oerther@uc.edu orchong.ahn@uc.edu
Websites: www.wqb.uc.edu orwww.biomems.uc.edu
Key Words for Internet Search:
BioMEMS, wastewater, biomechanics, biological micro-electro-mechanical systems
Data Sources:
Web site sources are as follows:
www.biomems.uc.edu
www.memsnet.org
                                                  Installation(s):
                                                  There are no installations in the United States at
                                                  this time.
5-12
                                             Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
                                                                            Emerging Technologies
  Microbial Activity
                                prepared 2008
Technology Summary
  Fluorescence In  Situ Hybridization (FISH) for Phosphorus Accumulating
  Organisms (PAOs)
                                                    State of Development:
                                                    Emerging.
Objective:
Identify specific microorganisms in wastewater.
Description:
Bacteria in activated sludge contain DMA as unique genetic material. DMA sequences unique to individual
groups of microorganisms can be used to identify specific microorganisms in samples that contain a mixture
of many different types of microorganisms. The process of identifying specific PAOs is part of the full-cycle
16S rRNA approach using FISH. Fluorescently labeled 16S rRNA probes are hybridized, stained, and
observed under an epifluorescent microscope. This document discusses the on-line version, not the field test
kit.
Comparison to Established Technologies:
The FISH for PAOs microbial detection process is able to positively identify specific microorganisms in a
mixed culture. Previously, microbiological tests performed in a laboratory were necessary to identify and
enumerate bacteria. This process provides real-time feedback, over laboratory tests that take hours or even
days for results.
Available Cost Information:
Approximate Capital Cost: Unknown.
Approximate O&M Costs: Unknown.
Vendor Name(s):                               Installation(s):
Department of Civil and Environmental Engineering       There are no known installations.
at the following universities:
University of Illinois at Urbana-Champaign
University of Cincinnati
North Carolina State University

Key Words for Internet Search:
Fluorescence In Situ Hybridization (FISH),  16S rRNA, full-cycle 16S rRNA approach, phylogeny
Data Sources:
Amann,  R. I., L. Krumholz, and D. A. Stahl, "Fluorescent-Oligonucleotide Probing of Whole Cells for
Determinative, Phylogenetic, and Environmental Studies in Microbiology," Department of Veterinary
Pathobiology, University of Illinois, Urbana, IL 61801, Journal of Bacteriology, 172(2), pp. 762-770, February
1990.
Amann,  Rudolf, "Monitoring the Community Structure of Wastewater Treatment Plants: A Comparison of Old
and New Techniques," Max-Planck Institut fur Marine Mikrobiologie, Arbeitsgruppe Molekulare Okologie,
Celsiusstr. 1, D-28359 Bremen,  Germany, FEMS Microbiology Ecology, Volume 25, Issue 3, p. 205, March
1998.
Daims, Holger, Niels B.  Ramsing, Karl-Heinz Schleifer, and Michael Wagner, "Cultivation-Independent,
Semiautomatic Determination of Absolute Bacterial Cell Numbers in Environmental Samples by Fluorescence
In Situ Hybridization," Lehrstuhl fur Mikrobiologie, Technische Universitat Munchen, 85350 Freising,
Germany, and Department of Microbial Ecology, Institute of Biological Sciences, University of Aarhus, 8000
Aarhus,  Denmark, Applied and Environmental  Microbiology, pp. 5,810-5,818, Vol. 67, No. 12, December
2001.
Wastewater Treatment and In-Plant Wet Weather Management
                                                                                           5-13

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Emerging Technologies
                                                    March 2013
  Microbial Activity
prepared 2008
Technology Summary
  Handheld Advanced Nucleic Acid Analyzer (HANAA)
  Objective:
  Real-time detection of pathogens in water and
  wastewater.
                 State of Development:
                 Emerging.
  Description:
  HANAA uses the genetic material of microorganisms in wastewater by performing a Polymerase Chain
  Reaction (PCR) to detect pathogens. PCR is a technique for enzymatically replicating DMA without using a
  living organism, such as E. coli or yeast. Like amplification using living organisms, this technique allows for a
  small amount of DMA to be amplified exponentially. The HANAA is a miniature thermal cycler, which can
  perform PCR in real time.
  Commercially these products are available as Bio-Seeq™ and RAZOR®, although they are mostly being used
  for bioterrorism monitoring purposes.
  Comparison to Established Technologies:
  HANAA can be compared to a thermal cycler that is used in laboratories performing extensive molecular
  biology work. HANAA is a portable version of the thermal cycler and therefore, has the benefit of being used
  in field where monitoring needs to be performed, without extensive sampling and laboratory analysis time.
  Available Cost Information:
  Approximate Capital Cost: Unknown.
  Approximate O&M Costs:  Unknown.
  Vendor Name(s):                              Installation(s):
  Smiths  Detection                                  Information not available about the installations.
  Telephone: 1-908-222-9100
  Web site: www.smithsdetection.com
  Idaho Technology Inc.
  390 Wakara Way
  Salt  Lake City, UT84108
  Telephone: 801-736-6354 or 800-735-6544
  Fax:801-588-0507
  Email: it@idahotech.com
  Web site: www.idahotech.com

  Key Words for Internet Search:
  Bio-Seeq™, Smiths Detection, Handheld Advanced Nuclei Acid Analyzer, HANNA
  Data Sources:
  Higgins, James, "Handheld Advanced Nucleic Acid Analyzer (HANAA) for Waterborne Pathogen Detection,"
  WERF publication,  USDA, 2001.
  www.smithsdetection.com
  Telephone conversation with the vendor.
5-14
              Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
                                                                          Emerging Technologies
  Microbial Activity
                               prepared 2008
Technology Summary
  Immunosensors and Immunoassays
                                                  State of Development:
                                                  Emerging.
Objective:
Use antigen- antibody interaction to identify the
presence of toxins in wastewater.
Description:
Immunosensors and immunoassays involve antibodies that bind to a specific antigen noncovalently. Sensors
and assays are designed to detect these interactions through a range of transducer options. The most popular
immunoassay system  in use is the Enzyme-Linked ImmunoSorbent Assay (ELISA). Environmental application
includes analyzing selected contaminants such as pesticides and polyaromatic hydrocarbons. ELISAs include
an antibody or antigen bound on a titer plate and an unbound reagent labeled with an enzyme that produces a
signal in the presence of a specified substrate.
Comparison to Established Technologies:
This is not similar to any established technology.
Available Cost Information:
Approximate Capital Cost: Unknown.
Approximate O&M Costs: Unknown.
Vendor Name(s):                             Installation(s):
Not available commercially for wastewater             There are no known installations.
applications.
Key Words for Internet Search:
ELISA,  antibody-antigen, immunosensors, and immunoassays
Data Sources:
Love, Nancy and Charles Bott, "A Review and Needs Survey of Upset Early Warning Devices," WERF
publication, 2000.
Wastewater Treatment and In-Plant Wet Weather Management
                                                                                        5-15

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Emerging Technologies
                                                                                     March 2013
  Water Quality
                                prepared 2008
Technology Summary
  Photo-electro Chemical Oxygen Demand (PeCOD™)
                                                   State of Development:
                                                   Emerging.
                                           •JIVK
Objective:
Determine Chemical Oxygen Demand (COD) of
wastewater without extensive laboratory process.
Description:
Photo-electro Chemical Oxygen Demand (PeCOD1™) technology can measure photo-current charge
originating from the oxidization  of soluble organic species contained in a sample. The PeCOD™ technology is
able to photo-electrochemically generate an electrical signal that directly correlates, via mass balance, with
the soluble oxidizable organic species contained in wastewater samples. The core of the technology is the
ability of the UV-activated nano-particulate photocatalyst semi-conductive electrode to create a high-oxidation
potential that ensures complete oxidation of all soluble oxidizable organic species. This technology has the
ability to capture and measure the resultant photo-current. The PeCOD™ online analyzer has been used to
monitor soluble COD in municipal wastewater treatment plants. Real-time soluble COD event-monitoring
enables efficient secondary treatment and reduces operational and discharge costs in  regional plants
vulnerable to COD surges from industrial sources.
Comparison to Established Technologies:
The photoelectric COD sensor has short analysis time, is  simple to use, has low impact to the environment,
and has a long sensor life. It  provides real-time results in as low as 30 seconds to overcome the problems of
time delay encountered by chemical oxidation methods. High sensitivity and wide linear range is obtained by
direct signal acquisition. Measures soluble COD only.
Available Cost Information:
Approximate Capital Cost:  Not available.
Approximate O&M Costs: Not available.
Vendor Name(s):                               Installation(s):
Aqua Diagnostic Pty Ltd.                            There are no installations.
Level 1, 159 Dorcas Street
South Melbourne, Victoria 3205
Australia
Telephone: 61 3 8606 3424
Fax: 61 3  9686 9866
Email: info@aquadiagnostic.com
Web site:  http://www.aquadiagnostic.com

East China  Normal University
Litong Jin
Department  of Chemistry
Shanghai  200062
People's Republic of China.

Key Words for Internet Search:
Photo-electro Chemical Oxygen Demand, PeCOD™, Aqua Diagnostic
Data Sources:
Aqua Diagnostic, "PeCOD™  COD Analyzer Delivers Rapid, Reliable and Accurate On-Line COD Monitoring,
Technology." Journal Abstract,  "Ti/TiO2 Electrode Preparation Using Laser Anneal and its' Application to
Determination of Chemical Oxygen Demand," Electroanalysis, Volume 18, Issue 10, pp. 1,014-1,018.
5-16
                                              Wastewater Treatment and In-Plant Wet Weather Management

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 Chapter
Energy Conservation  Measures
  6.1  Introduction
       Energy consumption for municipal wastewater treatment accounts for 15% to 30% of the
       operating cost at large treatment facilities and 30% to 40% at small facilities (WEF, 2009).
       Energy is required throughout the wastewater treatment process and facilities, with aeration,
       pumping and solids management operations typically accounting for the greatest share of a
       utility's energy use. The demand and cost of this energy to a wastewater utility continues to rise
       due to a  number of factors including:
          •  Implementation of increasingly stringent discharge requirements.

          •  Enhanced treatment of biosolids, including drying and pelletizing.

          •  Higher pumping and treatment requirements and costs associated with increased
             infiltration and inflow from aging wastewater collection systems.

          •  Increasing electricity rates associated with the cost of fossil fuels used for energy
             production and with construction of new electric power generating and distribution
             infrastructure to meet increasing demand.

       As a consequence of rising energy demand and costs, many wastewater facilities have
       developed energy management strategies and implemented energy conservation measures
       (ECMs) to reduce their energy consumption and costs as well as reduce their carbon footprint
       and associated greenhouse gas emissions. ECMs are herein defined as energy efficient
       equipment retrofits, operational modifications, and process control enhancements whose
       implementation leads to reduced energy consumption and costs and often, improved treatment
       efficiency. This chapter focuses on the advances in ECMs  used at wastewater facilities,
       particularly those that have been developed and implemented since 2008. Other ECMs and
       energy conservation approaches are discussed in "Evaluation of Energy Conservation
       Measures for Wastewater Treatment Facilities" (EPA 832-R-10-005).
  6.2  Technology Assessment
       A summary of several innovative, emerging and established ECMs is provided in Table 6.1.
       Individual technology summary sheets with performance and cost/savings* information are
       included for several innovative and emerging ECMs documented in the literature. (* Capital
       costs shown in this chapter may include other needed facilities and/or ancillary equipment
       needed to implement the ECM and may have been derived from the total cost of a larger
       project. In some cases, installation costs may not be available and not be included. Capital and
       O&M costs as well as energy savings are site specific and equipment specific and can vary
       significantly. For details on the basis of some of the reported costs, please consult the EPA
Wastewater Treatment and In-Plant Wet Weather Management
6-1

-------
Emerging Technologies

       document referenced (in section 6.1 above) in this chapter which is available at
       http://water.epa.gov/scitech/wastetech/upload/Evaluation-of-Energy-Conservation-Measures-
       for- Waste water- Treatment-Facilities, pdf.)

       Many energy conservation measures are established and essential measures relating to
       efficient pumping systems including pumps, drives and motors. In addition, established ECMs
       include fine bubble diffuser systems that increase the oxygen transfer efficiency, thereby
       decreasing energy demand. Established aeration equipment includes highly efficient turbo
       blowers which use friction-free bearing designs coupled with the use of high efficiency motors
       and integral speed control to achieve high energy efficiency. Established reactor mixing
       systems include hyperbolic mixers which  use a stirrer located close to the bottom of a tank to
       promote complete mixing.

       Innovative development in energy conservation measures mainly focus on aeration system
       control or efficient equipment. Aeration control ECMs includes the Integrated Air Flow Control
       system which eliminates the pressure control loop common in many automatic DO control
       systems leading to more efficient blower operation and reduced energy consumption. Also
       included is the Automated SRT/DO Control ECM which uses  algorithms to optimize DO and
       SRT set points and reduce energy consumption while maintaining process performance. A
       pulsed large bubble mixing system is included which achieves mixing requirements and
       reduced energy consumption by using short bursts of compressed air instead of mechanical
       mixers. Control of aeration for nitrification processes based on ammonia concentration is  also
       being applied and will be  included in a future version of this report.

       Knowledge about technologies tends to evolve. The information provides a snapshot at a point
       in time; what  is understood at one point in time may change as more information develops.
       This includes knowledge about operating mechanisms as well as the relative and absolute
       costs and features of a particular technology. Inquiries into the current state of knowledge are
       an important  step when considering implementation of any technology.
6-2                                            Wastewater Treatment and In-Plant Wet Weather Management

-------
March 2013
  Emerging Technologies
                Table 6.1—Energy Conservation Measures - State of Development
            Established Technologies (technology summaries not included)
            Aeration
                Adjustment of Submergence of Mechanical Aerators
                Bioprocess Intelligent Optimization System (BIOS)
                Cycling Mechanical Aerators On and Off
                Fine-Pore Aeration Diffusers
                High Speed (Gearless) Turbo Blowers
            Mixing
                Hyperbolic Mixers
            Pumping
                NEMA Premium® efficiency motors
                Variable Frequency Drives (VFDs)
            Other Processes
                Incineration Heat Recovery
            Innovative Technologies
Summary on
   page
            Aeration
                Automated SRT/DO Control
    6-4
                Dual Impeller Aerator (mechanical mixing)
    6-5
                Integrated Air Flow Control
    6-6
                Single-stage Centrifugal Blowers with Inlet Guide Vanes and Variable Diffuser Vanes
    6-8
            Mixing
                Intermittent Mixing
    6-10
                Pulsed Large Bubble Mixing
    6-11
            Pumping
                Pump Control Optimization
    6-12
            Adaptive Use Technologies
                None at this time
     NA
            Emerging Technologies
Summary on
   page
            Aeration
                Critical Oxygen Point Control
    6-13
                Membrane Air Scour Alternatives
    6-14
                Ultra-fine Bubble Diffusers
    6-16
            Disinfection
                Automated Channel Routing for UV Disinfection
    6-18
                Low Pressure High Output Lamps for UV Disinfection
    6-19
            Other Processes
                Solar Drying of Sewage Sludge
    6-20
            Research Technologies
                None at this time
Wastewater Treatment and In-Plant Wet Weather Management
                     6-3

-------
Emerging Technologies
                                                                                      March 2013
  Aeration
                                  prepared 2012
                                                                    Technology Summary
  Automated SRT/DO Control
  Objective:
  Optimization and automatic control of dissolved oxygen
  (DO) and sludge age (SRT) in aeration systems to
  optimize DO and SRT set points and reduce energy
  consumption while maintaining process performance.
                                                   State of Development:
                                                   Innovative. The OPTIMaster™ algorithm is
                                                   approaching an established process while
                                                   SRTMaster™ has been implemented for over
                                                   12 years and DOmaster™ was implemented over
                                                   8 years.
Description:
Proprietary algorithms (OPTIMaster™), (DOmaster™) and (SRTMaster™) which provide set point
optimization, based on actual data and process variables: sludge modeling, plant historical data, and
statistical process control. The software utilizes a biological process model based control algorithms for
sludge age and DO and automates control of these parameters (through automatic sludge wasting and blower
output adjustment) to optimize aeration. OPTIMaster™, DOmaster™ and SRTMaster™  could be used
separately or together.
Comparison to  Established Technologies:
This technology represents an improvement to conventional technology as follows:
SRTMaster™ allows the automatic control of SRT and  equalization of mass solids loading on thickening
facility, improving activated sludge process stability and reducing energy usage and chemicals use for sludge
thickening. DOmaster™ is an improvement over traditional DO control because it provides more robust
control by using activated sludge modeling and data mining instead of traditional PID control. OPTIMaster™
allows automatic selection of DO and SRT set points. The criteria for selection are reduction of energy usage
while maintaining low effluent suspended  solids concentration and absence of foam.
All software modules have artificial intelligence features used for alerting operators about meter problems
(TSS, DO, Flow) as well as changes in process BOD loadings or migration of solids to the clarifiers.
Available Cost  Information:
Project Cost of $135,000 for a 22.4 MGD  plant (average daily flow) with average energy savings of $26,980/yr
and a simple payback period of 5 years.
Vendor Name(s):                             Installation(s):
Ekster and Associates Inc.                        Oxnard Wastewater Treatment Plant
1904 Lockwood Ave.                              6001 Perkins Road
Fremont, CA 94539                                Oxnard, CA 93033-9047
Telephone:  510-657-7066                          Telephone: 805-488-3517
Email: info@srtcontrol.com                         Email: Mark.Moise@ci.oxnard.ca.us

Key Words for Internet Search:
DO control algorithm, SRT control algorithm, OPTIMaster™, SRTMaster™, DOmaster™, wastewater
treatment, Ekster
Data Sources:
Oxnard Wastewater Treatment Plant
Mark Moise, Alex Ekster, Operation of a Solids Contact Tank at Low Dissolved Oxygen and Low Total
Suspended  Solids Concentrations, Proceedings of WEFTEC, Conference and Exposition, San Diego, 2007.

USEPA (2010)  Evaluation of Energy Conservation Measures for Wastewater  Treatment Facilities. Office of
Water. EPA 832-R-10- 005 September 2010.
http://water.epa.gov/scitech/wastetech/upload/Evaluation-of-Energy-Conservation-Measures-for-Wastewater-
Treatment-Facilities.pdf.
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                                               Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
                                                                           Emerging Technologies
 Aeration
                                 prepared 2012
                                                                  Technology Summary
  Dual Impeller Aerator (mechanical mixing)
                                                 State of Development:
                                                 Innovative.
Objective:
Provide additional mixing energy near the floor of an
aeration basin, permitting greater power turndown
when a VFD is used and an associated energy
savings.
Description:
A dual impeller aerator by Ovivo (formerly Eimco Water Technologies) includes a lower impeller near the
bottom of the basin  floor to augment the surface impeller. This provides additional mixing energy near the
floor of the basin, permitting greater power turndown when a VFD is used and an associated energy savings.
Comparison to Established Technologies:
Improved energy efficiency compared to single impeller mechanical aerators which are limited in their turn
down due to the need to keep the contents of the basin from settling.
Available Cost Information:
Not available.
                                                 Installation(s):
                                                 Information not available.
Vendor Name(s):
Ovivo USA
(Formerly Eimco Water Technologies LLC)
2404 Rutland Drive
Austin, TX 78758
Telephone: 512-834-6000
Fax:512-834-6039
Email: info.US@ovivowater.com

Key Words for Internet Search:
Dual impeller, turn down, basin floor mixing, energy efficient mixing

Data Sources:
USEPA (2010) Evaluation of Energy Conservation Measures for Wastewater Treatment Facilities. Office of
Water. EPA 832-R-10- 005 September 2010.
http://water.epa.gov/scitech/wastetech/upload/Evaluation-of-Energy-Conservation-Measures-for-Wastewater-
Treatment-Facilities.pdf
Wastewater Treatment and In-Plant Wet Weather Management
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Emerging Technologies
                                                                                         March 2013
  Aeration
                                   prepared 2012
                                                                      Technology Summary
  Integrated Air Flow Control
                                                    State of Development:
                                                    Innovative. This technology is being used in the US
                                                    and is approaching an established process.
Objective:
Integrated Air Flow Control is a proprietary aeration
control system which can result in better stability and
simplified tuning of the aeration system process
leading to more efficient blower operation and
reduced energy consumption.
Description:
This technology uses modern control capabilities to integrate basin and blower air control into a coherent
strategy that eliminates the pressure control loop common in many automatic DO control systems. Traditional
automatic dissolved oxygen (DO) control systems usually include four control loops: DO Control at the
aeration basins, air flow control at the aeration basins, pressure control at the common air header, and air
flow control at each blower. The discharge pressure control  loop in traditional systems is used to stabilize air
flow to individual aeration tanks and is often specified as part of the blower controls to adjust the air flow
based on changes in DO. Since the relationship between actual oxygen transfer efficiency and air flow rate is
non-linear and dependent on a number of changing factors,  it is not possible to properly define a specific air
rate that should be associated with a specific change in DO  concentration. This coupled with the long process
response time associated with DO control can cause instability in the operation of the blowers and control
valves (cyclic oscillation, or hunting) as the control system attempts to adjust air flow and pressure in
response to changes in the process and ambient air conditions
The Integrated Air Flow Control System eliminates the pressure control loop. Air valves  at individual tanks are
used to distribute total air flow from the blowers proportionally to total demand. Blowers  are controlled to
provide the total system air flow required to meet total process demand. System pressure, which is the result
of changing airflow and changing system restriction, is allowed to rise and fall as the friction losses change.
The result is better stability, simplified tuning, and more efficient blower operation. In addition, a unique most
open valve (MOV) logic is used to minimize system restriction and optimize header pressure by maintaining
one valve — the MOV valve — at maximum position at all times. This further reduces the wasted energy
resulting from constant pressure control.
Comparison to Established Technologies:
This technology represents an improvement to previous automated control systems that use cascaded control
strategy that includes a pressure control loop's output as a setpoint for blower air control. Energy savings on
the  order of 10% have been reported from implementing this technology.
Available Cost Information:
Project Cost of $200,000 (2007 Dollars) for a 23.7  MGD plant (average daily flow) with average energy
savings of $135,786/yr and a simple payback period of 1.5 years.
Vendor Name(s):                              Installation(s):
Dresser Roots                                     Bucklin Point WWTF/United Water
2135 Hwy6 South                                  102 Campbell Avenue
Houston, TX 77077                                 East Providence, Rl 02916
281-496-8100
www.rootsblowers.com
                                                    Brent Herring, Superintendent
                                                    401-434-6350 X-182
  Key Words for Internet Search:
  Do control, blower control, wastewater treatment, Dresser
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                                                Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
                       Emerging Technologies
 Aeration
                              prepared 2012
               Technology Summary
  Integrated Air Flow Control (continued)
  Data Sources:
  Bucklin Point WWTF/United Water

  USEPA (2010) Evaluation of Energy Conservation Measures for Wastewater Treatment Facilities. Office of
  Water. EPA 832-R-10- 005 September 2010.

  http://water.epa.gov/scitech/wastetech/upload/Evaluation-of-Energy-Conservation-Measures-for-Wastewater-
  Treatment-Facilities.pdf
           BLOWER AIR FLOW
                                BLOWER FLOW
                                CONTROL
                                                           TOTAL FLOW SETPOINT
                                                          TOTAL FLOW REQ.
                INLET BFV
                CONTROL
                                      FLOW SETPOINT

                                  AIR FLOW
        System with
         Direct Flow
           Control
FLOW
CONTROL
                                                FLOW SETPOINT
                                               DO
                                               CONTROL
                                                   TANK1
                  FLOW SETPOINT
                               .AIR FLOW
             FLOW
             CONTROL
                                                    DO
        H
              FLOW SETPOINT
I                                                            DO
                                                            CONTROL
                                                TANK 2
Wastewater Treatment and In-Plant Wet Weather Management
                                     6-7

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Emerging Technologies
                                                                                      March 2013
  Aeration
                                  prepared 2012
                                                                    Technology Summary
  Single-stage Centrifugal Blowers with Inlet Guide Vanes and Variable
  Diffuser Vanes
                                                  State of Development:
                                                  Innovative (some, but not all turbocompressors, are
                                                  innovative).
Objective:
Utilizing inlet guide vanes and variable outlet vane
diffusers on a single stage centrifugal blower makes
it possible to operate the blower at its highest
efficiency point.
Description:
Single-stage centrifugal blowers equipped with inlet guide vanes pre-rotate the intake air before it enters the
high speed blower impellers. This reduces flow more efficiently than throttling. Blowers that are also equipped
with variable outlet vane diffusers have improved control of the output air volume. Utilizing inlet guide vane
and discharge diffusers on a single-stage centrifugal blower makes it possible to operate the blower at its
highest efficiency point, not only at the design condition but also within a greater range outside of the design
condition. A programmable logic controller (PLC control) can be used to optimize inlet guide vane operation
(i.e., positioning) based on ambient temperature, differential pressure, and machine capacity. Automated DO
and variable header pressure control can increase efficiency.
Comparison to Established Technologies:
Increased energy efficiency compared to positive displacement blowers. Can be less maintenance intensive,
and can result in lower monitoring/operational costs if properly automated.
Available Cost Information:
Project Cost of $901,000 for an 11.8 MGD plant (average daily flow) with average energy savings of
$63,889/yr and a simple payback period of 14 years.
  Vendor Name(s):
  Siemens Industry, Inc.
  Water Technologies
  Telephone: 866-926-8420 or 724-772-1402
  Web: www.water.siemens.com
                                                 Installation(s):
                                                 Sheboygan Regional Wastewater Treatment Plant
                                                 3333 Lakeshore Drive
                                                 Sheboygan,Wl 53081
                                                 Dale Doer
                                                 Wastewater Superintendent
                                                 Telephone: 920-459-3464
                                                 Single Stage,
                                                 Email: Dale.doerr@sheboyganwwtp.com

Key Words for Internet Search:
Single Stage Blower, Inlet Guide Vanes, Variable diffuser Vane
Data Sources:
USEPA (2010) Evaluation of Energy Conservation Measures for Wastewater Treatment Facilities. Office of
Water. EPA 832-R-10- 005 September 2010.
http://water.epa.gov/scitech/wastetech/upload/Evaluation-of-Energy-Conservation-Measures-for-Wastewater-
Treatment-Facilities.pdf
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March 2013
       Emerging Technologies
 Aeration
                             prepared 2012
Technology Summary
 Single-stage Centrifugal Blowers with Inlet Guide Vanes and Variable
 Diffuser Vanes (continued)
       Single-Stage Centrifugal Blower with Inlet Guide Vanes and Variable Diffuser
         Vanes by Turblex® (now part of Siemens Energy). Used with permission.
Wastewater Treatment and In-Plant Wet Weather Management

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Emerging Technologies
                                                                                       March 2013
  Mixing
  Intermittent Mixing
                                prepared 2012
Technology Summary
                                                     State of Development:
                                                     Innovative. This technology is being used in the
                                                     US and was implemented at a US plant in 2008.
Objective:
Reduce energy usage for maintaining solids in
suspension in biological nutrient removal reactors and
mixed liquor channels.
Description:
An optimization algorithm is used to convert mixing in the anoxic/anaerobic zones of BNR reactors and mixed
liquor channels from continuous to intermittent (On/Off). This patent pending method of maintaining solids in
suspension allows reduced energy usage without compromising effluent quality and process reliability. A
special programming routine is used to avoid aeration control system oscillation. The routine sequences the
tanks rather than simultaneously providing air to all the tanks to re-suspend solids. Aeration system
modifications are often required including installation of new valves, actuators,  pneumatic lines, and electrical
systems, in addition to control system programming.
Comparison to Established Technologies:
As shown below, the  intermittent mixing provides significant energy savings compared to the continuous
mixing method.
Available  Cost Information:
Project Cost of $181,592 for a 167MGD plant (average daily flow) at the San Jose/Santa Clara Water
Pollution Control Plant, with average energy savings of $757,614 and a simple payback period of 3 months.
This corresponds  to reduction in associated aeration energy in the range of 23% and 38%. Another study
showed pulse aeration of anaerobic and anoxic zones resulted in  13%  less aeration demand with an annual
energy saving potential close to $430,000.
Vendor Name(s):                              Installation(s):
Ekster and Associates Inc.                         San Jose/ Santa Clara Water Pollution Control Plant
1904 Lockwood Ave.                               (SJ/SC WPCP)
Fremont, CA 94539                                700 Los  Esters Rd.,
Telephone: 510-657-7066                           San Jose, CA 95134
Email: info@srtcontrol.com                          Bhavani.Yerrapotu, Division Manager
                                                 Telephone: 408-945-5300
                                                 Email: Bhavani.Yerrapotu @sanjoseca.gov

Key Words for Internet Search:
Pump stations, Pumping, Pumps Scheduling, Ekster
Data Sources:
San Jose/ Santa Clara Water Pollution Control Plant
Issayas T.  Lemma, Steve Colby, Tom Herrington. Pulse Aeration of Secondary Aeration Tanks Holds Energy
Saving Potential without Compromising Effluent Quality Proceedings of 82nd WEFTEC, Conference and
Exposition, Orlando, 2009.
USEPA (2010) Evaluation of Energy Conservation Measures for Wastewater Treatment Facilities. Office  of
Water.  EPA 832-R-10- 005 September 2010.
http://water.epa.gov/scitech/wastetech/upload/Evaluation-of-Energy-Conservation-Measures-for-Wastewater-
Treatment-Facilities.pdf.
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March 2013
                                                                            Emerging Technologies
  Mixing
                                prepared 2012
Technology Summary
  Pulsed Large Bubble Mixing
                                                  State of Development:
                                                  Innovative.
Objective:
An innovative mixing technology by Enviromix called
BioMx® reduces energy required for anoxic or
anaerobic zone mixing by firing short bursts of
compressed air into the zone instead of
mechanically mixing it.
Description:
Uniquely designed nozzles produce a mass of large air bubbles, ranging from marble to softball size, which
mix the water as they rise to the surface. The large air bubbles, much larger than those made by coarse
bubble diffusers, are designed to  minimize oxygen transfer and maintain anoxic or anaerobic conditions. The
system includes a PLC to manage the timing of the air control valve firing, which gives the operator flexibility
to respond to different conditions  within the tank.
Comparison to Established Technologies:
Testing at the F. Wayne Hill Water Resources Center in Gwinnett County, Georgia showed that energy (in
kW) required to mix one anaerobic cell using the BioMx® system was 45 percent less than the energy
required by a submersible mixer.  Also, when operated in three cells using the same compressor, 60 percent
less energy was required. The manufacturer reports that the system has non-clogging, self cleaning in-tank
components that require no maintenance.
Available Cost Information:
Not available.
                                                  Installation(s):
                                                  Testing done at the F. Wayne Hill Water Resources
                                                  Center in Gwinnett County, Georgia in 2009-2010
                                                  and at the ReWa Mauldin Road WWTP in
                                                  Greenville SC in 2011. Installed at the Hopewell
                                                  Regional Treatment Facility, Hopewell, VA and the
                                                  Center Street WWTP Mt Pleasant SC.
Vendor Name(s):
EnviroMix
180 East Bay Suite 200
Charleston, SC 29401
Telephone: 843-573-7510
Fax: 843-573-7531
Email: sales@enviro-mix.com

Key Words for Internet Search:
Coarse bubble, Pulse mixing

Data Sources:
Randall, C.W. and W. O. Randall. 2010. Comparative Analysis of a Biomix System and a Submersible
Propeller Mixer: Mixing in Anaerobic Zones at the F. Wayne Hill Water Resources Center, Buford, Georgia.
(Report provided in an e-mail from Clifford W. Randall on May 4, 2010).
USEPA (2010) Evaluation of Energy Conservation Measures for Wastewater Treatment Facilities. Office of
Water. EPA 832-R-10- 005 September 2010.
http://water.epa.gov/scitech/wastetech/upload/Evaluation-of-Energy-Conservation-Measures-for-Wastewater-
Treatment-Facilities.pdf
Wastewater Treatment and In-Plant Wet Weather Management
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Emerging Technologies
                                                                                     March 2013
  Pumping
                                prepared 2012
Technology Summary
  Pump Control Optimization
                                                 State of Development:
                                                 Innovative. This technology is being used in the U.S.
                                                 and has been implemented at a US plant in 2008.
Objective:
Optimization of pump station operation by selecting
the optimum combination of pumps in operation for
each flow to maintain peak efficiency for each pump
and, as a result, reduce energy use and pump
maintenance. This selection is automated using
proprietary software.
Description:
The optimization program utilizes field data such as pump station flows, pump discharge pressures, wet well
levels, and pump power usage to select the combination of pumps and pump speed at each flow rate. The
software program utilizes two optimization algorithms in tandem (genetic and gradient reduction algorithms)
rather than a single algorithm. The vendor reports that this methodology guarantees that the selected pumps
and speed  combination for each flow regime results in the consumption of less energy compared to any other
possible combination. Pump station energy reduction in the range of 17% and 23.5% has been reported at the
San Jose/Santa Clara Water Pollution Control Plant.
Comparison to Established Technologies:
This software program allows optimization of combinations of pumps equipped with constant speed and
variable speed motors.
Available Cost Information:
Project Cost of $43,768 fora 167 MGD plant (average daily flow) with average annual energy savings of $
244,858 and a simple payback period of 2.1  month.
  Vendor Name(s):
  Eksterand Associates Inc.
  1904 Lockwood Ave.
  Fremont, CA 94539
  Telephone: 510-657-7066
  Email: info@srtcontrol.com
                                                Installation(s):
                                                San Jose/ Santa Clara Water Pollution Control Plant
                                                (SJ/SC WPCP)
                                                700 Los Esteros Rd.,
                                                San Jose, CA95134
                                                Bhavani Yerrapotu, Deputy Director
                                                Telephone: 408-945-5300
                                                Email: Bhavani.Yerrapotu @sanjoseca.gov
  Key Words for Internet Search:
  Pump stations, Pumping, Pumps Scheduling, Ekster

  Data Sources:
  San Jose/ Santa Clara Water Pollution Control Plant
  USEPA (2010) Evaluation of Energy Conservation Measures for Wastewater Treatment Facilities. Office of
  Water. EPA 832-R-10- 005 September 2010.
  http://water.epa.gov/scitech/wastetech/upload/Evaluation-of-Energy-Conservation-Measures-for-Wastewater-
  Treatment-Facilities.pdf
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March 2013
                                                                              Emerging Technologies
  Aeration
                                   prepared 2012
                                                                      Technology Summary
  Critical Oxygen Point Control
                                                   State of Development:
                                                   Emerging.
Objective:
Improve aeration efficiency by controlling the
optimum delivery of oxygen in the aeration basins.
This is done by determining the critical oxygen point
of the wastewater under aeration and utilizing this
data to change the DO setpoint.
Description:
Critical oxygen point control is a control method based on respirometric measurements. Bacteria respire by
diffusion of oxygen across their cell wall. Oxygen diffuses from a high concentration external to the bacterial
cell wall  to the low concentration internal to the bacterial cell. Diffusion will only take place once the oxygen
concentration differential across the cell wall is sufficient to drive the oxygen through it. The minimum
concentration at which this occurs is called the critical oxygen point. Below the critical oxygen  point, the
biodegradation rate will rapidly decrease. At the critical oxygen point, the biodegradation rate will be at a
maximum for the available food source (i.e., organic compounds and ammonia in the wastewater being
treated). Accurately knowing the critical oxygen point for the active  biomass allows the optimal DO setpoint to
be determined.
Strathkelvin Instruments (Scotland, UK) has developed a proprietary software upgrade to their Strathtox line
of respirometers that,  in real time, determines the critical  oxygen point of the wastewater under aeration and
utilizes this data to change the DO setpoint to control the optimum delivery of oxygen in the aeration basins.
Comparison to Established Technologies:
The vendor claims substantial savings in reducing aeration cycles while increasing utilization of available
capacity and reducing energy costs.
Available Cost Information:
Not available.
                                                   Installation(s):
                                                   See website which reports on a plant in the UK that
                                                   reduced plant capacity by 25% resulting in CO2 and
                                                   energy reduction while maintaining compliance.
                                                   http://pdfs.findtheneedle.co.uk/107710-1483.pdf
Vendor Name(s):
Strathkelvin Instruments Limited
Rowantree Avenue
North Lanarkshire
ML1  5RX
Scotland, UK
Telephone: 01698  730400
Fax:  01698 730401
Email: info@strathkelvin.com
Key Words for Internet Search:
Aeration efficiency, Critical Oxygen Point, respirometric measurements, optimal DO setpoint
Data Sources:
USEPA (2010) Evaluation of Energy Conservation Measures for Wastewater Treatment Facilities. Office of
Water. EPA 832-R-10- 005 September 2010.
http://water.epa.gov/scitech/wastetech/upload/Evaluation-of-Energy-Conservation-Measures-for-Wastewater-
Treatment-Facilities.pdf
http://www.strathkelvin.com/waste_water/applications.asp
Wastewater Treatment and In-Plant Wet Weather Management
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Emerging Technologies
                                                                                       March 2013
  Aeration
                                  prepared 2012
                                                                     Technology Summary
  Membrane Air Scour Alternatives
                                                   State of Development:
                                                   Emerging.
Objective:
Reduce membrane fouling by providing energy
efficient air scour fouling control and operational
strategies.
Description:
Several membrane manufacturers have modified operational strategies to reduce air scour fouling control
requirements (Wallis-Lage and Levesque 2009), particularly for MBR systems.
For example, Kubota varies the volume of air used for aeration based on the flux (e.g., lower air scour rates
are used for lower flux values). The manufacturer of the Huber system claims reduced energy consumption
for air scour due to a centrally positioned air intake and low pressure. Siemens uses a combination of air and
water to scour the membrane (Wallis-Lage and Levesque 2009). General Electric (GE) implemented "cyclic"
air scour whereby aeration would turned on and off in 10 second intervals. A newer innovation is their 10/30
Eco-aeration where the membrane is scoured for 10 seconds on, 30 second off during non-peak flow
conditions. GE claims that the 10/30 Eco-aeration can reduce energy consumption by up to 50 percent
compared to the standard 10/10 aeration protocol (Ginzburg et al. 2008).
Comparison to Established Technologies:
The literature includes pilot- and full-scale  test data for a membrane fouling controller and algorithm used to
clean the GE ZENON ZeeWeed MBR.  The system uses real-time analysis of the membrane's filtration
operating conditions to determine the fouling mechanism present in the MBR system. The information
obtained from the algorithm dictates the implementation of specific control actions to respond to the particular
fouling mechanism (e.g., membrane aeration, backwash, chemical cleaning -the biggest impact on energy
consumption being membrane aeration). When aeration is identified as the control action, the fouling
controller/algorithm provides the MBR Programmable Logic Controller (PLC) system the information to select
between the traditional 10/10 (air scour On/Off) protocol and a 10/30  Eco Aeration energy saving  protocol.
The algorithm was piloted and later full-scale tested at a 3 million gallon per day (mgd) plant in Pooler,
Georgia (Ginsburg et al. 2008). Ginzburg (2008) concluded that additional research is required to further
develop the on-line fouling controller to include additional control parameters such as  membrane aeration flow
rate, backwash flow rate, and backwash duration.
Available Cost Information:
Information not available.
Vendor Name(s):
Enviroquip (a division of Ovivo, formerly Eimco) -
partnership with Kubota Corporation, Japan)
2404 Rutland Drive
Austin, TX 78758
Telephone: 512-834-6000
Fax:512-834-6039
Email: info@enviroquip.com
HUBER SE
Industriepark Erasbach A1
D-92334 Berching
Germany
Telephone: +49-8462-201-0
Fax:+49-8462-201-810
Email: info@huber.de
                                                   Installation(s):
                                                   Pilot and full scale testing was conducted at a
                                                   wastewater treatment plant in Pooler, Georgia.
                                                   See data reference below.
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                                               Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
        Emerging Technologies
 Aeration
                                 prepared 2012
Technology Summary
  Membrane Air Scour Alternatives (continued)
 ZENON Membrane Solutions (GE)
 Oakville, Ontario, Canada
 Telephone: 905-465-3030
 Email: www.gewater.com
 Siemens Industry, Inc.
 Water Technologies
 Telephone: 866-926-8420 or 724-772-1402
 Web: www.water.siemens.com
 (select Contact at top of page)
 Key Words for Internet Search:
 Membrane Air Scour, membrane cleaning, membrane fouling, MBR efficiency
 Data  Sources:
 Wallis-Lage, C.L. and S. D. Levesque. 2009. Cost Effective & Energy Efficient MBR Systems. Presented at
 the Singapore International Water Week. June 22 - 26, 2009. Suntec Singapore International Convention and
 Exhibition Center.
 Ginzburg, B., J. Peeters, and J. Pawloski. 2008. On-line Fouling Control for Energy Reduction in Membrane
 Bioreactors. Presented at Membrane Technology 2008. Atlanta, GA. WEF.
 USEPA (2010) Evaluation of Energy Conservation Measures for Wastewater Treatment Facilities. Office of
 Water.  EPA 832-R-10- 005 September 2010.
 http://water.epa.gov/scitech/wastetech/upload/Evaluation-of-Energy-Conservation-Measures-for-Wastewater-
 Treatment-Facilities.pdf
Wastewater Treatment and In-Plant Wet Weather Management
                       6-15

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Emerging Technologies

  Aeration                        PrePared2oi2                           Technology Summary
  Ultra-fine Bubble  Diffusers
  Objective:                                      State of Development:
  Use of advanced diffuser technology in aerobic         Emerging.
  biological treatment processes to achieve enhanced
  energy reduction over fine bubble diffusers.
  Description:
  Recent advances in membrane materials have led to ultra-fine bubble diffusers, which generate bubbles with
  an average diameter  between 0.2 and 1.0 mm. The primary appeal of ultra-fine bubble diffusion is improved
  oxygen transfer efficiency (OTE). Additionally, some composite materials used in the manufacture of ultra-fine
  bubble diffusers are claimed to be more resistant to fouling, which serves to maintain the OTE and reduce the
  frequency of cleaning. Concerns about ultra-fine bubble diffusion include slow rise rates and the potential for
  inadequate mixing. Two proprietary ultra-fine bubble diffuser designs, panel diffusers by Parkson and
  Aerostrip® diffusers by the Aerostrip Corporation, are discussed below. Messner developed the original ultra-
  fine bubble diffuser which is marketed in Europe by Trevi Environmental Solutions.
  Comparison  to Established Technologies:
  Ultra-fine Bubble Diffusers are reported to achieve enhanced energy reduction over fine bubble diffusers. The
  advantages  of panel diffusers include the increased OTE and the even distribution of aeration. Disadvantages
  can include a higher capital cost, a higher head loss across the diffuser, increased air filtration requirements,
  and a tendency to tear when  over-pressurized.
  Panel diffusers by Parkson are membrane type diffusers built onto a rectangular panel. They are designed to
  cover large areas of the basin floor and lay close to the floor. Panel diffusers are constructed of polyurethane
  and generate a bubble with a diameter of about one mm.
  AeroStrip® is a proprietary diffuser design manufactured in Austria by Aquaconsult. The device is a long strip
  diffuser with a large aspect ratio. According to the manufacturer, it is a  homogenous thermoplastic membrane
  held in place by a stainless steel plate. The AeroStrip® diffuser provides many of the same advantages and
  disadvantages as panel diffusers; however, it appears  to be less prone to tearing. Also, the smaller strips
  allow tapering of the diffuser placement to match oxygen demand across the basin. AeroStrips may be
  mounted at floor level or on supports above the floor.
  Manufacturer's claims regarding the strip membrane diffuser include:
  •   Energy efficiencies between 10 percent and 20 percent greater than the traditional ceramic and
     elastomeric membrane diffuser configurations.

  •   Uniform bubble release across the membrane surface.
  •   Bubbles resist coalescing.
  •   Membrane not prone to clogging.
  •   Diffusers are self-cleaning, although Aerostrip panels have been reported to be susceptible to frequent
     fouling requiring bumping and flexing of the membrane to dislodge.

  Available Cost Information:
  Not available.
  Vendor Name(s):                              Installation(s):
  Parkson Corporation - HiOx Panels                Information not available.
  Telephone: 1-888-PARKSON
  Fax:954-974-6182
  technology@parkson.com
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March 2013
        Emerging Technologies
 Aeration
                                 prepared 2012
Technology Summary
  Ultra-fine Bubble Diffusers (continued)
  Trevi Environmental Solutions - Messner Panels
  Dulle-Grietlaan 17/1
  9050 Gentbrugge, Belgium
  Telephone: +32 9 220 05 77
  Email: info@trevi-env.com
  AQUACONSULT - Aerostrip Panels
  Anlagenbau Ges.m.b.H
  Wassergasse 22-26/9
  A-2500 Baden
  Austria
  Telephone: +43-2252 41 481
  Fax: +43-2252 41 480
  Email: office@aquaconsult.at
  Key Words for Internet Search:
  Fine bubble diffuser, panel diffuser, strip diffuser, thermoplastic membrane
  Data Sources:
  http://www.parkson.com/files/Brochures/HiOx_UltraFlex_Aeration_System.pdf
  http://www.aquaconsult.at/indexe.php
  USEPA (2010) Evaluation of Energy Conservation Measures for Wastewater Treatment Facilities. Office of
  Water. EPA 832-R-10- 005 September 2010.
  http://water.epa.gov/scitech/wastetech/upload/Evaluation-of-Energy-Conservation-Measures-for-Wastewater-
  Treatment-Facilities.pdf
Wastewater Treatment and In-Plant Wet Weather Management
                       6-17

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Emerging Technologies
                                                                                      March 2013
  Disinfection
                                  prepared 2012
                                                                    Technology Summary
  Automated Channel Routing for UV Disinfection
                                                  State of Development:
                                                  Emerging.
Objective:
Reduce energy use and extend UV lamp life for UV
disinfection systems.
Description:
Automation can reduce the number of lamps and/or channels operating based on real-time flow and
wastewater characteristic data. Controls can be designed to turn off lamps or divert flow to a few operating
channels depending on the UV system design. Control is most commonly flow-paced control or dose-paced
control. Flow-paced is the simplest with number of lamps/channels in service based strictly on influent flow
rate. Dose-paced control is based on the calculated dose, which is derived from flow rate, UV transmittance
(UVT) and lamp power (including lamp age and on-line intensity output) data (Leong et al. 2008). During
periods of high solids removal, UVT will increase and UV output can be decreased to achieve the same dose.
During wet weather events or other periods of low effluent quality, lamp output can be increased in response
to reduced UVT.
Comparison to Established  Technologies:
At the University of California, Davis Wastewater Treatment Plant,  process controls were implemented to
divert flow automatically to one of two channels during low flow conditions (Phillips and Fan 2005). This
change provided the flexibility to operate at 33, 50, 67 and 100 percent of maximum power. The original
design limited operation to 67 and 100 percent of maximum power. The annual energy use at the UC Davis
WWTP is expected to decrease by 25 percent once the  process changes are fully implemented in the fall of
2010.
Available  Cost Information:
Information not available.
  Vendor Name(s):
  Information not available.
                                                Installation(s):
                                                University of California, Davis Wastewater
                                                Treatment Plant
                                                Mike Fan, Superintendent Waste Water Treatment
                                                and Solid Waste
                                                Telephone: 530-752-7553
                                                Email: mmfan@ucdavis.edu
Key Words for Internet Search:
UV disinfection, automated channel routing, energy efficient UV control.
Data Sources:
Leong, L.Y.C., J. Kuo, and C Tang. 2008. Disinfection of Wastewater Effluent— Comparison of Alternative
Technologies. Water Environment Research Foundation (WERF), Alexandria, VA.
Phillips, D. L. and M. M. Fan. 2005. Automated Channel Routing to Reduce Energy Use in Wastewater UV
Disinfection Systems. University of California, Davis. Davis, California.
USEPA (2010) Evaluation of Energy Conservation Measures for Wastewater Treatment Facilities. Office of
Water. EPA 832-R-10- 005 September 2010.
http://water.epa.gov/scitech/wastetech/upload/Evaluation-of-Energy-Conservation-Measures-for-Wastewater-
Treatment-Facilities.pdf
6-18
                                               Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
                                                                            Emerging Technologies
  Disinfection
                                  prepared 2012
                                                                    Technology Summary
  Low Pressure High Output Lamps for UV Disinfection
                                                  State of Development:
                                                  Emerging.
Objective:
Reduce energy consumption for UV disinfection by
replacing medium pressure lamps with low pressure
low output lamps.
Description:
Low-pressure high-output lamps are similar to low-pressure low-intensity lamps except that a mercury
amalgam is used instead of mercury gas.
Comparison to Established Technologies:
In some cases, WWTPs can save on energy costs by specifying low-pressure low intensity lamps. The power
draw can be significantly lower than medium-pressure lamps. Tradeoffs are (1) a larger footprint for the same
disinfection level, which can be significant because as many as 20 low-pressure low-intensity lamps are
needed to produce the same disinfecting power as one medium-pressure lamp, and (2) higher operating costs
for maintenance and change out of additional lamps.
Leong et al. (2008) reported that the energy demand for low-pressure high-output systems is similar to that of
low-pressure low-intensity systems. Thus, low-pressure high-output lamps may be a good option for reducing
the number of lamps and footprint while keeping the energy requirements low. Salveson et al. (2009)
presented results of a pilot test at the Stockton,  CA WWTP comparing design conditions and operation of
medium pressure and low-pressure high-output lamps. The power draw for the low-pressure high-output
lamps was between 20 and 30 percent of the power draw for the medium pressure lamps, reducing annual
O&M costs significantly. These results are similar to information reported from one manufacturer for a 30 mgd
plant treating secondary effluent.
Available  Cost Information:
Information not available.
                                                  Installation(s):
                                                  Results of a pilot test at the Stockton, CA WWTP
                                                  were reported in the report referenced below by
                                                  Salveson et al. (2009).
Vendor Name(s):
Calgon Carbon Corporation
P.O. Box 717
Pittsburgh, PA 15230
Telephone: 800-4CARBON or 412-787-6700
Fax:412-787-6676
info@calgoncarbon-us.com

Key Words for Internet Search:
UV disinfection, low-pressure low intensity lamps, low-pressure high-output lamps.
Data Sources:
Salveson, A., T. Wade, K. Bircher, and B. Sotirakos. 2009. High Energy Efficiency and Small Footprint with
High-Wattage Low Pressure UV Disinfection for Water Reuse. Presented at the International Ultraviolet
Association (IUVA)/ International Ozone Association (IOA) North American Conference. May 5, 2009. Boston,
MA.

Leong, L.Y.C., J. Kuo, and C Tang. 2008. Disinfection of Wastewater Effluent— Comparison of Alternative
Technologies. Water Environment Research Foundation (WERF), Alexandria, VA.

USEPA (2010) Evaluation of Energy Conservation Measures for Wastewater Treatment Facilities. Office of
Water. EPA 832-R-10-005 September 2010.

http://water.epa.gov/scitech/wastetech/upload/Evaluation-of-Energy-Conservation-Measures-for-Wastewater-
Treatment-Facilities.pdf
Wastewater Treatment and In-Plant Wet Weather Management
                                                                                           6-19

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Emerging Technologies
                                                                                       March 2013
  Other Processes
                                  prepared 2012
                                                                     Technology Summary
  Solar Drying of Sewage Sludge
                                                  State of Development:
                                                  Emerging.
Objective:
Use of solar heat to evaporate residual water from
sludge, reduce thermal energy requirements and
sludge utilization/disposal costs.
Description:
Thermal drying is the use of heat to evaporate residual water from sludge. It typically follows dewatering and
can increase the dry solids content from between 18 and 30 percent to more than 90 percent (WEF 2009).
The thermal drying process reduces the mass and volume of dewatered solids and results in a product with a
high nutrient and organic content that can be used as a low-grade fertilizer. WEF and ASCE (2010) report on
growing  use in Europe and the United States of an emerging ECM for thermal drying called solar drying. First
developed by researchers in Germany, solar drying uses solar energy and convective air drying methods to
produce solids containing no more than 10 percent moisture. Solar dryers consist of a wide concrete pad with
low walls enclosed in a "greenhouse" type structure. Sludge is pumped onto the pad and arranged in a
relatively thin layer or in windrows. A microprocessor monitors temperature and humidity and adjusts fans and
louvers to provide sufficient ventilation for drying. Auxiliary heat may be used to enhance drying performance.
Comparison  to Established Technologies:
The Parkson Corporation reports that approximately 95 percent of energy used for drying is provided by solar
panels. They cite 100 installations in a variety of climates and for WWTP sizes ranging from 0.2 to 40 mgd.
Solar drying is considered an emerging ECM because of its capacity to significantly reduce fuel requirements
compared to conventional dryers.  Disadvantages of the technology are its large footprint, the need for
sufficient days with adequate solar heating, and potential for odor problems. If odors are present, appropriate
control technologies is available and can be provided.
Available  Cost Information:
Information not available.
  Vendor Name(s):
  Parkson Corporation
  Telephone: 1-888-PARKSON
  Fax:954-974-6182
  technology@parkson.com
                                                 Installation(s):
                                                 As of 2008, WEF and ASCE (2010) report that 10
                                                 solar drying facilities are being built or operated in
                                                 the U.S., mainly at small plants.
  Key Words for Internet Search:
  Solar drying, sludge drying, thermal drying
  Data Sources:
  WEF. 2009. MOP No. 32: Energy Conservation in Water and Wastewater Facilities. Prepared by the Energy
  Conservation in Water and Wastewater Treatment Facilities Task Force of the Water Environment Federation.
  McGraw Hill, New York.
  WEF and ASCE. 2010. Design of Municipal Wastewater Treatment Plants - WEF Manual of Practice 8 and
  ASCE Manuals and Reports on Engineering Practice No. 76, 5th Ed. Water Environment Federation,
  Alexandria, VA, and American  Society of Civil Engineers Environment & Water Resources Institute, Reston, Va.
  USEPA (2010) Evaluation of Energy Conservation Measures for Wastewater Treatment Facilities. Office of
  Water. EPA 832-R-10- 005 September 2010.
  http://water.epa.gov/scitech/wastetech/upload/Evaluation-of-Energy-Conservation-Measures-for-Wastewater-
  Treatment-Facilities.pdf
6-20
                                               Wastewater Treatment and In-Plant Wet Weather Management

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March 2013                                                                 Emerging Technologies
  6.3  Chapter References
  Gass, J.V. (2009) Scoping the Energy Savings Opportunities in Municipal Wastewater Treatment.
       Presented at the Consortium for Energy Efficiency Partner's Meeting, September 2009.

  Gidugu, S., S. Oton, and K. Ramalingam. 2010. Thorough Mixing Versus Energy Consumption. New
       England Water Environment Association Journal,  Spring 2010.

  Ginzburg, B., J. Peeters, and J.  Pawloski. 2008. On-line Fouling Control for Energy Reduction in
       Membrane Bioreactors. Presented at Membrane Technology 2008. Atlanta, GA. WEF.

  Gray & Osborne, Inc. 2008. Wastewater Treatment Plant Capacity Study and Engineering Report.
       March, 2008.

  Jones, T., Burgess, J. (2009) Municipal Water-Wastewater Breakout Session: High Speed Turbo
       Blowers. Presented at the Consortium for Energy  Efficiency Program Meeting, June 3, 2009.

  Lemma, I., Steve Colby, Herrington, T., Pulse Aeration of Secondary Aeration Tanks Holds Energy
       Saving Potential without Compromising Effluent Quality Proceedings of 82nd WEFTEC,
       Conference and Exposition, Orlando, 2009.

  Leong, L.Y.C., J. Kuo, and C Tang. 2008. Disinfection of Wastewater Effluent— Comparison of
       Alternative Technologies. Water Environment Research Foundation (WERF), Alexandria, VA.

  Moise, M., Ekster, A., Operation of a Solids Contact Tank at Low Dissolved Oxygen and Low Total
       Suspended Solids Concentrations, Proceedings of WEFTEC, Conference and Exposition, San
       Diego, 2007.

  Randall, C.W. and W. O. Randall.  2010. Comparative Analysis of a Biomix System and a
       Submersible Propeller Mixer: Mixing in Anaerobic Zones at the F. Wayne Hill Water Resources
       Center, Buford, Georgia. (Report provided in an e-mail from Clifford W. Randall on May 4,
       2010).

  Salveson, A., T. Wade, K. Bircher, and B. Sotirakos. 2009. High Energy Efficiency and Small
       Footprint with High-Wattage Low Pressure UV Disinfection for Water Reuse. Presented at the
       International Ultraviolet Association (IUVA)/  International Ozone Association (IOA) North
       American Conference. May 5, 2009. Boston, MA.

  USEPA (2010) Evaluation of Energy Conservation Measures for Wastewater Treatment Facilities.
       Office of Water. EPA 832-R-10-005 September 2010.

  Water Environment Federation Manual of Practice (MOP) No. 32: Energy Conservation in Water and
       Wastewater Facilities. Prepared by the Water and WastewaterTreatment FacilitiesTask Force
       of the Water Environment Federation. McGraw Hill, New York, 2009.

  Wallis-Lage, C.L. and S.  D. Levesque. 2009. Cost Effective & Energy Efficient MBR Systems.
       Presented at the Singapore International Water Week. June 22 - 26, 2009. Suntec Singapore
       International Convention and Exhibition Center.

  WEF and ASCE. 2010. Design of Municipal Wastewater Treatment Plants - WEF Manual of Practice
       8 and ASCE Manuals and Reports on Engineering Practice No. 76, 5th Ed. Water Environment
       Federation, Alexandria, VA, and American Society of Civil Engineers Environment & Water
       Resources Institute, Reston, Va.
Wastewater Treatment and In-Plant Wet Weather Management                                         6-21

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 Chapte
Research  Needs
  7.1  Introduction
       Science and research are critical to advancing EPA's mission to protect human health and the
       environment. This chapter focuses on the relevant research needs in the areas of specific
       technologies that may have a significant impact on wastewater treatment and wet weather flow
       management, such as achieving higher levels of pollutant removal while minimizing operation
       and maintenance costs of the treatment system, thereby improving the contributions of the
       industry to sustainability.

       Sustainability is based on a simple principle: Everything that we need for our survival and well-
       being depends, either directly or indirectly, on our natural environment. The goal of
       sustainability is to create and maintain the conditions under which humans and nature can
       coexist in productive harmony, for both present and future generations. Setting a goal of
       sustainability is important to achieve having, and continuing to have, the water, materials, and
       resources, to protect human health and our environment.**

       This chapter looks into some of the important technology areas and discusses associated
       research needs of interest in the wastewater treatment industry.
  7.2  Research Needs
       The application of new concepts and technologies to enhance the long-term sustainability of
       wastewater management can be expedited by promoting research needed to develop and
       demonstrate these concepts and technologies.

       At this time, research and technical issues can be grouped into the following areas:
       (1) upgrading older WWTPs; (2) nutrient removal and recovery (or, "the recovery of resources
       including energy and nutrients"); (3) removal of other contaminants; (4) security of water
       systems; (5) energy conservation and renewable energy sources; and (6) wastewater and
       solids treatment optimization.


7.2.1 Upgrading WWTPs

       Most of the treatment plants in the United States were constructed more than two decades
       ago. Many of these treatment facilities need to be upgraded to improve capacity and treatment
       efficiency. The upgraded treatment processes that can best fit the existing technologies at
       Publicly  Owned Treatment Works (POTWs) are chosen based upon wastewater discharge
       (NPDES) permit requirements and their cost-effectiveness to achieve water quality objectives
       and protect public health. Such upgrades are often opportunities to employ emerging
       technologies or established technologies in newer and better ways.
Wastewater Treatment and In-Plant Wet Weather Management
7-1

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Emerging Technologies

       Some of the areas of current and future interest are as follows:
           •   Innovative wastewater collection system designs that provide real-time condition
              assessment data for asset management decision-making.

           •   Determination of the long-term performance and life-cycle cost effectiveness of
              emerging system rehabilitation techniques, including new and existing materials.

           •   Advanced sewer system designs that minimize energy consumption and greenhouse
              gas emissions.


7.2.2 Removal of Nutrients (or, "Recovery of Resources including
       Energy and Nutrients")

       Nutrients in wastewater effluent can stimulate excessive algae growth, and ammonia is toxic to
       aquatic life. Increasingly more stringent nutrient discharge limits  are prompting research into
       technologies that are capable of improved nutrient removal.

       'Low energy alternatives to activated sludge' could also be considered a category or subsection
       that is an important research objective of this chapter. Some of the processes relevant to
       resource recovery could be listed under such a subsection as areas in which research could be
       beneficial, including Anaerobic MBR, Mainstream Deammonification, MBfR improved aeration,
       AnMBR, microbial fuel cells, and enhanced anaerobic processes. Fact sheets for these
       technologies are found in other chapters in this document.

       Some of the areas of current and future research interest are as follows:
           •   Advanced sustainable nutrient removal technologies capable of reducing nutrients to
              concentrations below current limit of technology while minimizing the costs, energy
              consumption and chemical consumption. Optimization of anaerobic wastewater
              treatment processes (including nutrient removal) for improved performance, particularly
              in cold climates.
           •   Continued development of full-scale anaerobic MBRs to reliably meet secondary and
              advanced treatment requirements under various operating conditions and climates and
              to meet stringent reclaimed water standards with subsequent disinfection.

           •   Optimized nitritation-denitritation and evaluating operating conditions and/or improved
              processes to promote nitrite oxidizing bacteria (NOB) suppression and washout.
           •   Application of deammonification and nitritation/denitritation processes (currently used
              for high temperature sidestreams) to treat low temperature mainstream flows.
           •   Use of MBfR technology to  improve energy efficiency of aerobic processes or to provide
              hydrogen as an alternative electron acceptor for denitrification or oxidation of other
              reduced contaminants.
           •   Improved understanding of the active fraction of denitrifier performance and kinetics
              leading to improved design  and operation.
           •   Improved understanding of the portion of organic nitrogen in the final effluent produced
              within a wastewater treatment plant (WWTP) and development of new processes or
              improved operational control strategies to minimize its production (i.e., non-reactive
              nitrogen in the plant that could theoretically become reactive when discharged).
7-2                                           Wastewater Treatment and In-Plant Wet Weather Management

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                                                                         Emerging Technologies

          •   Improve analytical methods for measuring very low levels of phosphorus.

          •   Improved understanding of performance and operational factors for full plant flow
              deammonification. Refinement of key process parameters leading to development of
              effective process designs and development of an optimized operational strategy.

          •   Innovative technologies for resource recovery (Nutrients, Carbon, H2O) from
              wastewater including recovery at source (grey water, black water, urine diversion), and
              enhanced anaerobic digestion and other solids conversion processes.


7.2.3 Removal of Other Contaminants

       Compounds that can alter the endocrine system of animals are known as Endocrine Disrupting
       Compounds (EDCs) and have been linked to a variety of adverse effects in both humans and
       wildlife. Pharmaceutical compounds and their metabolites have been detected as
       Pharmaceutically Active Compounds (PhACs). Some PhACs are highly persistent and can
       function as EDCs.
          •   Evaluate new technologies for cost-effective removal of EDCs, PhACs, PBDEs, Prions,
              PPCPs, etc.

          •   Improved and sustainable disinfection technologies for control of pathogens of concern
              (Cryptosporidium, Giardia, e-Co//-0157, etc.) and other bacteria, viruses and protozoa
              without disinfection byproduct issues.

          •   Innovative technologies or existing technology upgrades to remove  emerging
              contaminants with minimal costs and energy footprint.

          •   Alternative approaches to prevent or lessen the quantity of EDCs, PhACs,  PBDEs,
              Prions, PPCPs, etc., introduced into  wastewater.

7.2.4 Security of Water Systems

       While research for security of wastewater systems has been completed within the last decade,
       continuing needs include the following:
          •   Emergency preparedness of WWTPs to deal with pandemics, new strains of viruses
              and bacteria, or spill incidents.

          •   Mitigation strategies for treatment plants after natural calamities.

          •   Prevention and preparedness for bioterrorism.


7.2.5 Energy Conservation and Renewable  Energy Sources

       As the cost of energy rises, many wastewater facilities are searching for more energy efficient
       technologies,  processes, and operating techniques. In addition, in their effort to become energy
       self-sufficient, many wastewater facilities are looking for cost effective renewable energy
       sources.
          •   Enhanced production of digester gas.

          •   Effective use of digester gas for the onsite generation of heat and electric power.
Wastewater Treatment and In-Plant Wet Weather Management                                          7-3

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Emerging Technologies
                                    March 2013
          •   Cost effective renewable energy source, including, fuel cells, solar cells, wind turbines,
              hydropower, and heat extraction from wastewater.

          •   Use of biosolids for producing biofuels (pyrolysis,  gasification, etc.)

          •   Export of clean biogas for offsite commercial uses.


7.2.6 Wastewater and  Solids Treatment Optimization

       Optimizing the way facilities treat both wastewater and solids can result in cost savings in
       energy, maintenance, manpower, and other plant operating costs.
          •   Develop strategies, methods,  processes,  and tools for cost effective management of
              energy used in wastewater treatment.

          •   Develop cost effective methods to minimize the volume and quantity of wastewater
              treatment solids generation, without sacrificing produce value or quality.

          •   Identify new resource recovery opportunities for wastewater and biosolids, including
              heat extraction, nutrient mining and recovery (ammonia, nitrogen, phosphate, etc.), and
              wastewater and biosolids reuse.
  7.3  Chapter References
  **USEPA, Sustainability Web page, accessed November 2012.

  Institute of Environment and Resources - Wastewater Technology University of Denmark;
       web site: http://www.er.dtu.dk/English/

  Water Environment Research Foundation (WERF), 2002;
       web site: www.werf.org/funding/researchplan.cfm

  Water Environment Research Foundation (WERF), 2012; 11/29/2012 email from Lauren Filmore,
       WERF, to  James Wheeler, EPA.

  Parker, D.S., "Introduction of New Process Technology into the Wastewater Treatment Sector,"
       WEFTEC2010.

  Daigger,  G.T.,  "New Approaches and Technologies for Wastewater Management," The Bridge,
       National Academy of Engineering, Volume 38, Number 3, Fall 2008.
7-4
Wastewater Treatment and In-Plant Wet Weather Management

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Append!
Trade  Associations
 A.1  Introduction
       This chapter lists professional and trade associations that may have significant information.
       These professional and trade associations may provide relevant research assistance on
       wastewater treatment and in-plant wet weather management technologies within their
       respective areas of expertise.
 A.2  Trade Associations
       American Society of Civil Engineers (ASCE)
       1801 Alexander Bell Drive Reston, VA 20191-4400
       Telephone: 800-548-2723
       Web site: http://www.asce.org

       National Association of Clean Water Agencies (NACWA)
       1816 Jefferson Place, NW, Washington D.C. 20036
       Telephone: 202-833-2672
       Web site: http://www.nacwa.org/

       Water and Wastewater Equipment Manufacturers Association (WWEMA)
       P.O. Box 17402, Washington, D.C.  20041
       Telephone: 703-444-1777
       Web site: http://www.wwema.org

       Water Environment Federation (WEF)
       601 Wythe Street, Alexandria, VA 22314-1994
       Telephone: 800-666-0206
       Web site: http://www.wef.org

       Water Environment Research Foundation (WERF)
       635 Slaters Lane, Suite G-110, Alexandria, VA 22314
       Telephone: 571-384-2100
       Web site: http://www.werf.org
Wastewater Treatment and In-Plant Wet Weather Management
A-1

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Append!
List of Acronyms  and Abbreviations
Acronym/Abbreviation    Definition
A/O
A2/O
AACE
ABW®
AEBR
AGAR®
AGRS
AGSP
AIZ
AMBR®
AN FLOW
AN-MBR
AOB
AOP
ASBR®
ASCE
ATS
atm
AWTP
AWWA
BABE
BAF
BAR
BCDMH
BCFS
Anaerobic/Oxic (Phoredox)
Anaerobic/Anoxic/Oxic
American Association of Cost Engineers International
Automatic Backwash Filters
Anaerobic Expanded Bed Reactor
Attached Growth Airlift Reactor
Advanced Grit Removal System
Aerobic Granular Sludge Process
Air Intercept Zone
Anaerobic Migrating Blanket Reactor
Anaerobic Fluidized Bed Reactor
Anaerobic Membrane BioReactor
Ammonia oxidizing bacteria
Advanced Oxidation Process
Anaerobic Sequencing Batch Reactor
American Society of Civil Engineers
Aeration Tank 3
Atmosphere
Advanced Wastewater Treatment Plant
American Water Works Association
Bio-Augmentation Batch Enhanced
Biological Aerated Filters
Bio Augmentation Regeneration and/or Reaeration
1-Bromo-3 Chloro-5,5 DiMethylHydantoin
Biological-Chemical Phosphorus and Nitrogen Removal
Wastewater Treatment and In-Plant Wet Weather Management
                                                       B-1

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Emerging Technologies
                                                      March 2013
Acronym/Abbreviation     Definition
BHRC
BioMEMS
BIOS
BNR
BOD
BOD/N
BOD/P
BODS
CANON
CASS™
CCAS™
CDS
cfm
Cfu
CMAS
CMF®
CMOM
COD
CSO
CSS
CWA
DAF
DEMON
DEPHANOX
DF
DO
EBPR
ECM
EDC
ELISA
EMS
FBBR
Ballasted High Rate Clarification
Biological Micro-Electro Mechanical Systems
Bioprocess Intelligent Optimization System
Biological Nutrient Removal
Biological/Biochemical Oxygen Demand
Biochemical Oxygen Demand Ratio to Nitrogen
Biochemical Oxygen Demand Ratio to Phosphorus
Biological oxygen demand after 5 days
Completely autotrophic nitrogen removal over nitrite
Cyclic Activated Sludge System
CounterCurrent Aeration System
Continuous Deflection Separator
Cubic feet per minute
Colony forming unit
Complete Mix-Activated Sludge
Compressed Media Filter (WWETCO CMF®)
Capacity, Management, Operations, and Maintenance
Chemical Oxygen Demand
Combined Sewer Overflow
Combined Sewer System
Clean Water Act
Dissolved Air Flotation
DEamMONification
DE-nitrification and Phosphate accumulation in ANOXic
Disc Filter
Dissolved Oxygen
Enhanced Biological Phosphorus Removal
Energy conservation measure
Endocrine Disrupting Compound
Enzyme-Linked ImmunoSorbent Assay
Environmental Management Systems
Fluidized Bed BioReactor
B-2
                   Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
                                               Emerging Technologies
Acronym/Abbreviation     Definition
FISH
FP
GAC
GPD
gpm/ft2
GST
HANAA
HFMBfR
HFO
HLR
HPO
HRC
HRT
ICAAS
ICEAS™
I FAS
NT
ISE
IUVA
IWA
LOT
MAB
MABR
MAUREEN
MBBR
MBfR
MBR
MFC
mg/L
MGD
MISS
MLE
Fluorescence In Situ Hybridization
Focused pulse
Granular-Activated Carbon
Gallons per day
Gallons per minute per square foot
Gravity sludge thickener
Handheld Advanced Nucleic Acid Analyzer
Hydrogen-based hollow-Fiber Membrane Biofilm Reactor
Hydrous Ferric  Oxide
Hydraulic loading rate
High-Purity Oxygen
High-Rate Clarification
Hydraulic Retention Time
Immobilized Cell-Augmented Activated Sludge
Intermittent Cycle Extended Aeration System
Integrated Fixed-film Activated Sludge
Illinois Institute  of Technology
Ion Selective Electrode
International Ultraviolet Association
International Water Association
Limit Of Technology
Multi-stage Activated Biological
Membrane-Activated BioReactor
Main-stream AUtotrophic Recycle Enabling Enhanced N-removal
Moving Bed Bio Reactor
Membrane biofilm reactor
Membrane BioReactor
Microbial  Fuel Cell
Milligram  per Liter
Million Gallons  per Day
Moderate Isotope Separation System
Modified Ludzack-Ettinger
Wastewater Treatment and In-Plant Wet Weather Management
                                                              B-3

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Emerging Technologies
                                                       March 2013
Acronym/Abbreviation    Definition
MLSS
MOV
mph
MSABP™
MUCT
NACWA
NADH
NF
NOB
ntu
O&M
ORP
OTE
OWM
PAA
PAC
PAO
PBDE
PCE
PCR
PeCOD™
PhACs
PLC
POTW
PPCP
ppm
psig
PVC
qPCR
RAS
RBC
R-DN
Mixed Liquor Suspended Solids
Most open valve
Miles per hour
Multi-Stage Activated Biological Process
Modified University of Cape Town
National Association of Clean Water Agencies
Nicotinamide Adenine  Dinucleotide
NanoFiltration
Nitrite Oxidizing Bacteria
Nephelometric turbidity unit
Operation and Maintenance
Oxidation Reduction Potential
Oxygen transfer efficiency
Office of Wastewater Management (U.S. EPA)
Peracetic acid
Powdered Activated Carbon
Phosphorus Accumulating Organisms
PolyBrominated Diphenyl Ether
Perchloroethylene
Polymerase Chain Reaction
Photo-electro Chemical Oxygen Demand
Pharmaceutically Active Compounds
Programmable logic controller
Publicly Owned Treatment Works
Pharmaceutical and Personal Care Products
Parts per million
Pounds per square inch (gauge)
PolyVinyl Chloride
Quantitative PCR
Returned Activated Sludge
Rotating Biological Contactor
Regeneration DeNitrification
B-4
                   Wastewater Treatment and In-Plant Wet Weather Management

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March 2013
                                               Emerging Technologies
Acronym/Abbreviation     Definition
rDON
RO
rRNA
SBR
SCFM
SHARON
SHARON-ANAMMOX

SNdN
SRBC
SRT
SSO
STRASS
SVI
TDH
IDS
TF
TF/PAS
TF/SC
IMP
TOC
TSS
U.S. EPA
UASB
UCT
UV
UVT
VFD
VIP
VIS
VMI
VRM®
Refractory Dissolved Organic Nitrogen
Reverse osmosis
Ribosomal ribonucleic acid
Sequencing Batch Reactor
Standard Cubic Feet per Minute
Single reactor High-activity Ammonia Removal Over Nitrite
Single reactor High-activity Ammonia Removal Over Nitrite -
ANaerobic AMMonia OXidation
Simultaneous Nitrification deNitrification
Submerged Rotating Biological Contactor
Sludge Retention Time; Solids Retention Time
Sanitary Sewer Overflow
Similar to SHARON named after Strass, Austria
Sludge Volume Index
Total Dynamic Head
Total Dissolved Solids
Trickling Filter
Trickling Filter and Pushed Activated Sludge
Trickling Filter and Solid Contactor
Trans Membrane Pressure
Total Organic Carbon
Total Suspended Solids
United States Environmental Protection Agency
Upflow Anaerobic Sludge Blanket
University of Cape Town
Ultraviolet
UV transmittance
Variable frequency drive
Virginia Initiative Plant
Visibility
Virginia Military Institute
Vacuum Rotation Membrane
Wastewater Treatment and In-Plant Wet Weather Management
                                                             B-5

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Emerging Technologies
                                                       March 2013
Acronym/Abbreviation    Definition
WAS
WASA
WEF
WEFTEC

WERF
WRAP
WPCF
WRF
WWEMA
WWPF
WWTF
WWTP
Waste Activated Sludge
Water and Sewer Authority
Water Environment Federation
Water Environment Federation's Annual Technical Exhibition
and Conference
Water Environment Research Foundation
Water Pollution Abatement Program
Water Pollution Control Facility
Water Reuse Facility
Water and Wastewater Equipment Manufacturers Association
WasteWater Production Flow
WasteWater Treatment Facility
WasteWater Treatment Plant
B-6
                   Wastewater Treatment and In-Plant Wet Weather Management

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