United States       Prevention, Pesticides     EPA712-C-95-244
          Environmental Protection    and Toxic Substances     August 1995
          Agency         (7101)
&EPA   Health Effects Test
          Guidelines
          OPPTS 870.7485
          Metabolism and
          Pharmacokinetics
                  'Public Draft"

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                           INTRODUCTION
     This guideline is one of a series of test guidelines that have been
developed by the Office of Prevention, Pesticides and Toxic Substances,
United States Environmental Protection Agency for use in the testing of
pesticides and toxic substances, and the development of test data that must
be submitted to the Agency for review under Federal regulations.

     The Office of Prevention,  Pesticides and Toxic Substances (OPPTS)
has  developed this guideline through a  process of  harmonization that
blended the testing  guidance and requirements that existed in the  Office
of Pollution Prevention and Toxics  (OPPT) and appeared in Title 40,
Chapter I,  Subchapter R of the Code of Federal Regulations  (CFR), the
Office of Pesticide Programs (OPP) which appeared in publications of the
National Technical  Information Service (NTIS) and the guidelines pub-
lished by the Organization for Economic Cooperation and Development
(OECD).

     The purpose of harmonizing these guidelines into a single  set of
OPPTS  guidelines is to minimize variations among the testing procedures
that must be performed to meet the data requirements of the U. S. Environ-
mental Protection Agency under the Toxic  Substances Control Act (15
U.S.C. 2601) and the Federal Insecticide,  Fungicide and Rodenticide Act
(7U.S.C. I36,etseq.).

     Public Draft Access Information: This draft guideline is part of a
series of related harmonized guidelines that  need to  be considered as a
unit. For copies: These guidelines are available electronically from the
EPA Public Access Gopher (gopher.epa.gov) under the heading "Environ-
mental  Test Methods and  Guidelines"  or  in paper by contacting the
OPP    Public   Docket   at   (703)   305-5805   or   by   e-mail:
guidelines@epamail.epa.gov.

     To Submit Comments:  Interested persons are invited to submit com-
ments. By mail: Public Docket and Freedom of Information Section,  Office
of Pesticide Programs, Field  Operations Division  (7506C), Environmental
Protection Agency,  401  M St.  SW.,  Washington, DC 20460. In person:
bring to: Rm. 1132, Crystal Mall #2, 1921 Jefferson Davis Highway, Ar-
lington, VA. Comments may also be submitted electronically by sending
electronic mail (e-mail) to: guidelines@epamail.epa.gov.

     Final  Guideline Release:  This document is available  from the U.S.
Government Printing Office,  Washington, DC 20402 on The Federal Bul-
letin Board. By modem dial 202-512-1387, telnet:  federal.bbs.gpo.gov
3001, or call 202-512-1530 for disks or  paper copies.  This  guideline is
available in ASCII and PDF (portable document format).

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OPPTS 870.7485   Metabolism and pharmacokinetics
     (a) Scope—(1) Applicability. This guideline is intended to meet test-
ing  requirements   of both  the  Federal  Insecticide,  Fungicide,   and
Rodenticide Act (FIFRA) (7 U.S.C. 136, et seq.) and the Toxic Substances
Control Act (TSCA) (15 U.S.C. 2601).

     (2) Background. The source material  used in developing this har-
monized OPPTS test  guideline are 40 CFR  798.7485,  OPP  guideline
85-1, and OECD Guideline 417.

     (b) Purpose. (1) Testing of the disposition of a test substance is de-
signed  to  obtain adequate  information on  its  absorption,  distribution,
biotransformation, and excretion and to aid in understanding the mecha-
nism of toxicity. Basic pharmacokinetic parameters determined from these
studies will also provide information on the potential  for accumulation of
the test substance in tissues and/or organs and the potential for induction
of biotransformation as a  result of exposure to the test substance. These
data can be used to  assess the adequacy and relevance of the extrapolation
of animal toxicity data (particularly chronic toxicity and/or carcinogenicity
data) to human risk assessment.

     (2) Metabolism data can also be used to assist in determining whether
animal  toxicity studies have adequately addressed any toxicity concerns
arising from exposure to plant metabolites, and in the setting of tolerances,
if any, for those metabolites in raw agricultural commodities.

     (c) Definitions. The following definitions apply to this guideline:

     Metabolism (biotransformation)  is the sum of the processes by which
a foreign chemical  is subjected to chemical  change by living organisms.

     LOEL is the lowest observable effect level.

     NOEL is the no observable effect level.

     Pharmacokinetics is the quantitation and  determination of the  time
course   and   dose   dependency   of  the  absorption,   distribution,
biotransformation, and excretion of chemicals.

     (d) Good laboratory practice standards. The pharmacokinetics and
metabolism tests outlined in this guideline are to conform to the laboratory
practices stipulated in 40 CFR parts 160 and 792.

     (e) Test Procedures. Test procedures presented below utilize a tier
system  to  minimize the use of resources and  to  allow flexibility in the
conduct of metabolism studies.  The  proposed tier system will  consist of
a basic data set (Tier 1)  and additional studies (Tier 2) which may be
requested based upon the  existing  toxicology data base and/or  the results
of Tier  1 testing which are found to impact upon the risk assessment proc-
ess.  For Tier 1  testing, the oral route will typically be required; however,

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if the use pattern results in other types of exposure, other routes (dermal
and/or inhalation) may be required for initial testing of the disposition of
a chemical  substance. Complete descriptions of the test procedures for
these other  routes of exposure can be found under  paragraph (i) of this
guideline. Except in unusual circumstances, the tiered approach to metabo-
lism testing  should apply to  all listed routes of exposure.

     (1) Pilot studies. The  use of pilot studies is recommended and en-
couraged  for  the  selection   of  experimental   conditions  for  the
pharmacokinetics and metabolism studies (mass balance, analytical proce-
dures, dose-finding, excretion of CC>2, etc.).

     (2) Animal selection—(i) Species. The rat is normally used for test-
ing because it has been  used extensively for metabolic and toxicological
studies. The use of other or additional species may be required if critical
toxicology studies  demonstrate evidence of  significant toxicity  in these
species.

     (ii) Strain. Adult animals of the  strain chosen are to be  used for the
determination of adverse health effects associated with the test substance.

     (3) Material to be  tested—(i) Test  substance.  (A) A test substance
radiolabeled using  14C  should  be used for all material balance  and
metabolite identification aspects  of the study. Other radioactive isotopes
such as 35S, 36C1, and 113Sn or stable isotopes such  as 15N and 18O may
be used, particularly if the  element is responsible for  or is a part of the
toxic portion of the compound. If it can be demonstrated that the material
balance and  metabolite identification requirements can be met using
unlabeled test substance, radiolabeled compound need not be used. If pos-
sible, the  radiolabel should be located in a core  portion of the molecule
which is metabolically stable (it is not exchangeable,  is  not removed meta-
bolically as CCh,  and does not  become  part of the one-carbon pool of
the organism). Labeling of multiple sites of the molecule may be necessary
to follow the metabolic fate  of the compound.

     (B) The  label  should  follow  the test  compound and/or its  major
metabolites  until excreted. The radiopurity of the radioactive test substance
is to be the highest attainable for  a  particular test  substance (ideally  it
should be greater than 95 percent) and reasonable effort should be made
to identify impurities present at or above 2 percent. The purity, along with
the identity  of major impurities  which have been identified,  is to be re-
ported. For other segments of the study, nonradioactive test substance may
be used if it can be demonstrated  that the analytical specificity and sen-
sitivity of the method  used  with  nonradioactive test  substance is equal to
or greater than  that which  could be  obtained with  the radiolabeled  test
substance. The radioactive  and nonradioactive test  substances are to be
analyzed using an appropriate method to establish purity and identity. Ad-
ditional guidance will  be provided  in chemical specific test rules to assist

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in the definition and specifications of test substances composed of mixtures
and methods for determination of purity.

     (ii) Administration of test substance. Test substance should be dis-
solved homogeneously in  a  known vehicle which  does  not  significantly
alter (positively or negatively) the  absorption of test material.  The cus-
tomary method of administration will be by oral gavage; however, admin-
istration by gelatin capsule or as  a  dietary mixture may  be advantageous
in specific situations. Verification of the actual dose administered to each
animal should be provided.

     (4) Tier testing, (i) The multiplicity of metabolic parameters that im-
pact the outcome of toxicological evaluations preclude the use of a univer-
sal  study  design for routine  toxicological  evaluation of  a  test substance.
The  usefulness of a particular study design depends upon the biological
activity of a compound and circumstances  of exposure. For these reasons,
a tiered system is proposed for evaluation  of the metabolism/kinetic prop-
erties of a test substance.

     (ii) The first tier data set is a definitive study by the appropriate route
of exposure conducted in  male rats to determine  the routes and rate of
excretion and to identify excreted metabolites. First tier data will also pro-
vide basic information for additional testing (Tier 2) if such testing is con-
sidered necessary. In the majority of cases, Tier 1  data are expected to
satisfy regulatory requirements for biotransformation and pharmacokinetic
data on test chemicals.

     (iii) Second tier testing  describes a variety of metabolism/kinetic ex-
periments which address specific questions based on the existing  toxi-
cology data base and/or those results  of Tier  1 testing impacting signifi-
cantly on the risk assessment process. For conduct of these studies,  indi-
vidualized protocols may be necessary. These can be developed as a coop-
erative effort between Agency and industry scientists.

     (f) Tier 1  data requirements (minimum data set). At this initial
level of testing, biotransformation and pharmacokinetic data from a single
low  dose  group will be required. This study will determine  the  rate and
routes of excretion and the type of metabolites generated.

     (1) Number  and sex of animals. A minimum of four male young
adult animals  will be  required for Tier  1  testing.  The use of both sexes
may be required in cases  where  there is  evidence  to support significant
sex-related differences in toxicity.

     (2) Dose selection, (i) A single low  dose is required for each route
of exposure. The low dose should be  nontoxic, but high enough  to allow
for metabolite identification in excreta. If no other toxicity data are avail-
able for selection  of the low dose,  a  dose identified as a  fraction of the
LD50 (as determined from acute toxicity studies) may be used. The mag-

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nitude of the low  dose used and any other dose  levels used  in  Tier  1
studies should be justified in the final report.

     (ii)  For test  substances  of  low  toxicity  a  maximum  dose  of
1,000 mg/kg should be used; chemical-specific considerations may neces-
sitate a higher maximum dose and will be addressed in specific test rules.

     (3)  Measurements—(i)  Excretion.  (A)  Data  obtained  under this
paragraph (percent recovery of administered dose from urine, feces, and
expired air)  will be used  to  determine the rate and extent of excretion
of test chemical, to assist  in establishing mass balance, and will be used
in conjunction with pharmacokinetic parameters to determine the extent
of absorption. The quantities of radioactivity eliminated in the urine, feces,
and expired air  are to be determined separately at appropriate time inter-
vals.

     (B)  If a pilot  study has  shown that no  significant amount of radio-
activity is  excreted in expired  air, expired air need not be collected in
the definitive study.

     (C)  Each animal is to be placed in a separate metabolic unit for col-
lection of excreta (urine, feces and expired air). At the end of each  collec-
tion  period, the  metabolic  units are to be rinsed with appropriate solvent
to ensure maximum recovery of radiolabel. Excreta collection is to  be ter-
minated  at 7 days, or after at least 90 percent of the  administered dose
has been recovered, whichever  occurs first. The total quantities of radio-
activity in urine are to be determined at  6,  12, and 24 h  on day 1  of
collection, and daily thereafter until study termination, unless pilot  studies
suggest alternate or additional time points for  collection. The total quan-
tities of radioactivity in feces should be determined on a daily basis begin-
ning at 24 h post-dose, and daily thereafter  until study termination. The
collection of CCh and other volatile materials may be discontinued when
less  than 1 percent of the administered dose  is found  in the exhaled air
during a  24-h collection period.

     (ii)  Tissue  distribution. At the termination of the Tier 1 study, the
following tissues should be collected and stored frozen: Liver, fat, kidney,
spleen, whole blood, and residual carcass. If it is determined that a signifi-
cant amount of the administered  dose is unaccounted for in the excreta,
data on the percent of the  dose in these tissues as well as residual carcass
will be requested. Additional tissues are to be included if there is evidence
of target organ  toxicity from subchronic  or chronic  toxicity studies. For
other routes  of  exposure,  specific tissues may also be required, such as
lungs in  inhalation studies and skin in dermal  studies. Certain techniques
currently at various stages of development, e.g. quantitative whole-body
autoradiography, may  prove useful in determining if a test substance con-
centrates in certain organs  or in determining a specific pattern of distribu-
tion  within a given tissue.  The use of such techniques is encouraged,  but

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not required, and may be employed to limit the number of tissues collected
to those shown to contain a measurable amount of radioactivity.

     (iii) Metabolism. Excreta  are to be  collected for identification and
quantitation  of unchanged  test substance  and metabolites as described
under paragraph (f)(3)(i) of this guideline. Pooling of excreta to facilitate
metabolite identification within a given dose group is acceptable. Profiling
of metabolites  from each time period is recommended. However, if lack
of sample  and/or radioactivity precludes this, pooling of urine  as well as
pooling of feces across several time points  is acceptable. Appropriate qual-
itative and quantitative  methods are to be  used to  assay urine,  feces, and
expired air from treated animals. Reasonable efforts should be made to
identify all metabolites and to  provide a metabolic scheme for the test
chemical. Compounds which have been characterized in excreta  as com-
prising 5 percent or greater of the administered dose should be identified.
If identification  at this  level is not possible,  a justification/explanation
should be  provided in the final report. Identification of metabolites rep-
resenting less than 5 percent of the administered dose might be requested
if such data are needed for risk assessment of the test chemical. Structural
confirmation should be provided whenever possible. Validation  of the
methods used in metabolite identification should be included.

     (g) Tier 2 data requirements. Studies at the Tier 2 level are designed
to answer  questions about the disposition  of test chemicals based  on the
existing toxicology data base and/or results of Tier  1  testing which may
have  a  significant impact on the risk assessment for the test chemical.
Such studies may address questions regarding absorption,  persistence, or
distribution of the test chemical, or a definitive alteration in the metabolic
profile occurring with dose which may be  of toxicological concern. Flexi-
bility will  be allowed in the design of specific experiments as warranted
by technological advances in this field.

     (1) Absorption, (i) In cases where the extent of absorption has not
been  established from Tier  1 studies,  or  where greater than 20 percent
of the administered dose is present  in feces and  has been identified as
parent chemical, a study to determine the  extent of absorption will be re-
quired. This can be accomplished either through intravenous administration
of test material and measurement of radioactivity in excreta or after oral
administration  of test material and measurement of radioactivity in bile.

     (ii) For the intravenous study, a single low dose of test chemical using
an  appropriate vehicle  will  be  administered in a  suitable volume (e.g.
1 mL/kg) at a suitable site to at least three male  rats (both sexes might
be used if warranted). The disposition of the test chemical should be mon-
itored for oral  dosing as outlined in paragraph (f)(3)(i) of this guideline.
Metabolite identification will not be required for this study.

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     (iii) If a biliary excretion study is chosen the oral route of administra-
tion will be requested. In this study,  the bile ducts  of at least three rats
(or of both sexes,  if warranted) should be  appropriately cannulated and
a single low dose  of the  test chemical should  be administered  to  these
rats. Following administration of the test chemical, excretion of radioactiv-
ity  in  bile should be  monitored as long as  necessary to determine if a
significant percentage  of the administered dose is excreted via this route.

     (2) Tissue distribution time course, (i) The correlation of levels of
metabolites or parent chemical in target tissues with toxicity is often useful
in determining the mechanisms of toxicity,  especially when evidence of
target  organ toxicity or extended half-life is apparent. For this reason, a
time course of tissue distribution in selected tissues will be requested to
aid in  the determination of possible mechanisms of toxicity. The selection
of tissues for this  type of study  will be based upon available evidence
of target organ toxicity and/or carcinogenicity,  and the number of time
points  required will be based upon pharmacokinetic  information obtained
from Tier 1 data.  Flexibility will be allowed in the selection of time points
to be used in the study.

     (ii) For this  type  of study, three rats per time point will be adminis-
tered an appropriate oral  dose  of test chemical, and the time course of
distribution monitored in selected tissues. Only one sex may be required,
unless  target organ toxicity is observed in sex-specific organs. Assessment
of tissue distribution will be made using appropriate techniques for assess-
ment of total amount distributed to tissue and for assessment of metabolite
distribution.

     (3) Plasma kinetics. The purpose of this experiment is to obtain esti-
mates  of basic pharmacokinetic parameters (half-life, volume  of distribu-
tion, absorption rate constant) for the test substance. In addition, kinetic
data can also  be  used to substantiate  questions  about bioavailability and
whether clearance is saturated in a dose-dependent fashion. For this experi-
ment a minimum of three rats is required. At least two doses will be re-
quired, usually the NOEL and LOEL from  the  critical toxicology study.
Following administration of test  substance,  samples should be obtained
from each animal at 30 min and again at 2, 4, 8, and 24 h using appropriate
sampling  methodology.  Different time  points may  be utilized if found
more suitable  for obtaining pharmacokinetic estimates. Total radioactivity
present (or total amount of chemical, for nonradioactive materials) should
be analyzed in whole blood and plasma using appropriate  methods, and
the blood/plasma  ratio  should be calculated.

     (4) Induction, (i) Studies addressing the possible induction of metab-
olizing enzymes will be requested if:

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     (A) Available evidence shows a relationship between metabolism of
the test chemical and toxicity (in the form of target organ toxicity and/
or carcinogenicity).

     (B) There is a nonlinear relationship between  dose and metabolism.

     (C) The results of tissue distribution studies show identification of
a potentially toxic metabolite.

     (D) Induction can plausibly be invoked as a factor in such effects.

     (ii) Several in vivo and in vitro methods are available for assessment
of enzyme induction, and the experiments which best address  the issue
at hand can be determined between Agency and industry scientists. If in-
duction is demonstrated, the relationship  of this phenomenon to toxicity
observed from  subchronic and/or chronic  toxicity studies will need to be
addressed (mechanism of toxicity will need to be established).

     (iii) If toxicologically significant alterations in the metabolic profile
of the test chemical are observed through either in vitro or in vivo experi-
ments, characterization of the enzymes involved (for example, Phase I en-
zymes  such  as isozymes  of the  Cytochrome  P450-dependent  mono-
oxygenase system, Phase II enzymes  such as isozymes of sulfotransferase
or uridine diphosphate glucuronosyl transferase, or any other relevant en-
zymes)  will be requested.  This information will help establish the  rel-
evance of the involved enzymes  to human risk, as it is known that certain
isozymes  are present in animal species which are not present in humans,
and vice versa.

     (5) Physiologically-based modeling. Traditional methods  of model-
ing have been used to determine kinetic parameters associated with drug
and xenobiotic disposition, but have assumed a purely mathematical con-
struct of mammalian organisms in their operation. On the other hand, more
recent models which take into account the physiological processes of the
animal have been used with success in defining biological determinants
of chemical disposition as well as the relationship between tissue dose
and  tissue response. These  so-called physiologically-based models, also
allow for cross-species extrapolation which is often necessary in the risk-
assessment process. The use of physiologically-based modeling  as an ex-
perimental tool for addressing specific issues related to biotransformation
and  pharmacokinetics of a test  substance is encouraged.  Information as
derived from physiologically-based modeling experiments may aid in the
comparison of biotransformation and pharmacokinetics of a test  substance
between animal species and humans, and  in the assessment of risk under
specific exposure conditions.

     (h) Reporting  of study results. In addition to the reporting require-
ments specified in 40 CFR part  792,  subpart J, the  completed study (Tier
1 or Tier 2) should be presented in the following format:

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     (1) Title/Cover Page. Title page and additional requirements (require-
ments  for data submission, good laboratory  practice,  statements of data
confidentiality claims and quality assurance) if relevant to the study report,
should precede the content of the study formatted below. These require-
ments  are to be found in 40  CFR parts  158 and  160 or parts 790, 792,
and 799.

     (2) Table  of Contents. A concise listing is to precede the  body of
the report, containing all essential elements of the study and the page and
table number where the element is located in  the final report of the  study.
Essential elements of the Table  of Contents should include a summary,
an introduction, the materials and methods section, results, discussion/ con-
clusions, references,  tables, figures, appendices, and key subsections as
deemed appropriate. The Table of Contents should include the page num-
ber of each of these elements.

     (3) Body of the report. The body  of the report must include informa-
tion  required under 40 CFR  158.85(a)  or this guideline, organized into
sections and paragraphs as follows:

     (i) Summary.  This section of the study report is to contain a summary
and  analysis  of the test results and  a  statement of the conclusions drawn
from the analysis. This section should highlight the nature and magnitude
of metabolites,  tissue residue,  rate of clearance, bioaccumulation potential,
sex differences, etc. The summary should be  presented in sufficient detail
to permit independent evaluation of the findings.

     (ii) Introduction. This section of the report should include the objec-
tives of the study, guideline references, regulatory history,  if any,  and a
rationale.

     (iii) Materials and methods. This section of the  report is to include
detailed descriptions of all elements including:

     (A) Test substance. (7) This section should include identification of
the test substance—chemical name, molecular structure, qualitative  and
quantitative determination of its chemical composition,  and type and quan-
tities of any impurities whenever possible.

     (2) This section should  also include information on physical prop-
erties including physical state, color, gross solubility and/or partition coef-
ficient, and stability.

     (3)  The type or description  of any  vehicle, diluents,  suspending
agents, and emulsifiers or other  materials used in administering the test
substance should be stated.

     (4) If the test substance is radiolabeled, information on the following
should be included: The type of radionuclide, position of label, specific
activity, and radiopurity.

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     (B) Test animals.  This section should include information on the test
animals,  including:  Species,  strain,  age  at  study  initiation,  sex,  body
weight, health status, and animal husbandry.

     (C) Methods. This subsection should include details of the study de-
sign and methodology used. It should include a description of:

     (1) How the dosing  solution was prepared and the type of solvent
used.

     (2) Number of treatment groups  and number of animals per group.

     (3) Dosage levels and volume.

     (4) Route of administration.

     (5) Frequency of dosing.

     (6) Fasting period (if used).

     (7) Total radioactivity per animal.

     (8) Animal handling.

     (9) Sample collection.

     (10) Sample handling.

     (11) Analytical methods used for separation.

     (12) Quantitation and identification of metabolites.

     (13) Other experimental measurements and procedures employed (in-
cluding validation of test methods for metabolite analysis).

     (D) Statistical analysis. If statistical analysis is used to analyze the
study findings, sufficient  information  on the method of analysis  and the
computer  program employed  should be included so that an independent
reviewer/statistician  can reevaluate and reconstruct the  analysis.  Presen-
tation of models should include a full description of the model to  allow
independent reconstruction and validation of the model.

     (iv) Results. All data  should be summarized and tabulated with appro-
priate statistical evaluation  and  placed in the text of this section. Radio-
activity counting data should be summarized and presented as appropriate
for the study,  typically as  disintegrations per minute and  microgram  or
milligram equivalents,  although  other units may be used. Graphic  illustra-
tions of the findings, reproduction of representative chromatographic and
spectrometric data, and proposed metabolic pathways and molecular  struc-
ture of metabolites should be included in this section. In addition the fol-
lowing information is to be included in this section if applicable:

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     (A) Justification for modification of exposure conditions, if applica-
ble.

     (B) Justification for selection of dose levels for pharmacokinetic and
metabolism studies.

     (C) Description of pilot studies used in the experimental design of
the pharmacokinetic and metabolism studies, if applicable.

     (D) Quantity and percent recovery  of radioactivity in urine,  feces,
and expired air, as appropriate. For dermal studies, include recovery data
for treated skin,  skin washes, and residual radioactivity in the covering
apparatus and metabolic unit as well as  results  of the  dermal washing
study.

     (E) Tissue distribution reported as percent of administered dose and
microgram equivalents per gram of tissue.

     (F) Material balance developed from each study involving the assay
of body tissues and excreta.

     (G) Plasma  levels and pharmacokinetic parameters after  administra-
tion by the relevant routes of exposure.

     (H) Rate and extent of absorption of the test substance after adminis-
tration by the relevant routes of exposure.

     (I)  Quantities of the test substance and metabolites (reported as per-
cent of the administered dose) collected in excreta.

     (J) Individual animal data.

     (v) Discussion and conclusions. (A) In this section the authors should:

     (7) Provide a plausible  explanation of the metabolic pathway for the
test chemical.

     (2) Emphasize species and sex differences whenever possible.
        Discuss the nature and magnitude of metabolites, rates of clear-
ance, bioaccumulation potential, and level of tissue residues as appropriate.

     (B) The authors should be able to derive  a concise conclusion that
can be supported by the findings of the study.

     (vi) Optional sections. The authors  may include additional  sections
such as appendices, bibliography, tables, etc.

     (i) Alternate routes of exposure for Tier 1 testing — (1) Dermal —
(i) Dermal treatment.  One or more dose levels of the test substance are
to be used in the dermal portion of the study. The low dose level should
be selected in accordance with paragraph (f)(2) of this guideline. The der-

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mal doses are to be dissolved, if necessary, in a suitable vehicle and ap-
plied in volumes adequate to deliver the doses. Shortly before testing, fur
is  to be clipped from the dorsal  area  of the trunk of  the test  animals.
Shaving may be employed, but it should be carried out approximately 24
h before the test. When clipping or shaving the fur, care should be taken
to  avoid abrading the  skin, which could alter  its permeability. Approxi-
mately 10 percent of the body surface  should be cleared for application
of the  test substance—a minimum of 6 cm2 is to be used. With highly
toxic substances, the surface area covered may be less  than approximately
10 percent,  but as much of the  area as  possible is to  be  covered with
a thin  and uniform film. The same nominal treatment surface area is to
be used for all  dermal test groups. The dosed areas are to be protected
with a suitable  covering which is secured in place.  The animals  are to
be housed separately.

    (ii) Dermal washing study.  (A) A washing experiment is to be con-
ducted to assess the removal of the applied low dose of the  test substance
by washing the treated skin area with  a mild soap and water. A  single
dose is to be applied to two animals in accordance with paragraph (f)(2)
of this guideline. After application (2 to 5 min) the treated areas  of the
animals are to  be washed  with a mild  soap and water.  The  amounts of
test substance recovered in the washes are to be determined to assess the
effectiveness of removal by washing.

    (B)  Unless precluded by  corrosiveness, the test  substance  is to  be
applied and kept on the skin for a minimum of 6 h. At the time of removal
of the  covering, the  treated area is to be washed following  the procedure
as  outlined in the dermal washing study. Both the covering and the washes
are to  be analyzed for residual test substance. At the termination  of the
studies, each animal is to be sacrificed  and the treated skin removed. An
appropriate section of treated skin is to  be analyzed to determine residual
radioactivity.

    (2) Inhalation. One or more concentrations of test substance  are to
be used in this portion of the  study.  The low concentration  should  be se-
lected  in accordance with paragraph (f)(2) of this guideline. Inhalation
treatments are to be conducted using a "nose-cone" or  "head-only" appa-
ratus to prevent absorption by alternate routes of exposure. If other inhala-
tion exposure conditions are proposed for use in a chemical-specific test
rule, justification for the modification must be documented. A single expo-
sure over a defined period is to be used for each group—a typical exposure
is 4-6 h.
                                 11

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