&EPA United States Environmental Protection Agency Analytical Methods Recommended for Drinking Water Monitoring of Secondary Contaminants Analysis for the following contaminants may be conducted in accordance with the methods in the following table, or their equivalent as determined by EPA. Methods for copper, fluoride, and pH are listed in 40 CFR 141.23 and methods for the remaining contaminants are in 40 CFR 143.4. Additional methods are listed in Appendix A to Subpart C of Part 141. The recommended monitoring for these contaminants is specified in 40 CFR 143.4. The CFR is the legal reference for approved methods and takes precedent over this table. The table should accurately reflect the analytical methods information published in 40 CFR 141. If discrepancies are found, please notify the Safe Drinking Water Hotline (800-426-4791) so that EPA can correct the table. Contaminant Organization Method Number Aluminum EPA EPA EPA EPA Standard Methods Standard Methods Standard Methods 200.5, Rev. 4.2 200.7, Rev. 4.4 200.8, Rev. 5.4 200. 9, Rev. 2.2 3111D 3111D 3111D Reference Title Date EPA Publication Number Criteria for analyzing aluminum, copper, iron, manganese, silver, ar procedures are contained in Section IV of Technical Notes on Drink National Environmental Publications Internet Site (NEPIS) database Determination of Trace Elements in Drinking Water by Axially Viewed Inductively Coupled Plasma - Atomic Emission Spectrometry In Methods for the Determination of Metals in Environmental Samples, Supplement I In Methods for the Determination of Metals in Environmental Samples, Supplement I In Methods for the Determination of Metals in Environmental Samples, Supplement I Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition October 2003 May 1994 May 1994 May 1994 1992 1995 2005 EPA/600-R- 06/115 EPA/600/R- 94/111 EPA/600/R- 94/111 EPA/600/R- 94/111 Publication Order No. Source of Method id zinc samples with digestion or directly without digestion, and other recommended ing Water Methods (EPA/600/R-94/173) available through EPA's digital publications i (http://www.epa.gov/nscep/). PB95-125472 PB95-125472 PB95-125472 http://www.epa.gov/nerlcwww/ordmeth.htm https: //www.nemi. go v https: //www.nemi. go v https: //www.nemi. go v Standard Methods Standard Methods Standard Methods Office of Water (MS - 4606 M) EPA 815-B-14-005 January 2014 ------- Contaminant Organization Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Online Method Number 3111D 3113B 3113B 3113B 3113B 3120B 3120B 3120B 3120B 3120B 3111 D-99 Reference Title Standard Methods for the Examination of Water and Wastewater, 22nd Edition Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 20th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Date 2012 1992 1995 2005 2012 1992 1995 1998 2005 2012 EPA Publication Number Publication Order No. Source of Method Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods http://www.standardmethods.org ------- Contaminant Organization Standard Methods Online Standard Methods Online Standard Methods Online Method Number 3113B-04 3113 B-99 3 120 B-99 Chloride ASTM International ASTM International ASTM International ASTM International D4327-03 D4327-97 D512-04B D512-89B (Reapproved 1999) Reference Title Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Date EPA Publication Number Publication Order No. Source of Method http://www.standardmethods.org http://www.standardmethods.org http://www.standardmethods.org Annual Book of ASTM Standards, Vol. 11.01 Annual Book of ASTM Standards, Vol. 11.01 Annual Book of ASTM Standards, Vol. 11.01 Annual Book of ASTM Standards, Vol. 11.01 http://www.astm.org http://www.astm.org http://www.astm.org http://www.astm.org ------- Contaminant Organization EPA EPA Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Method Number 300.0, Rev. 2.1 300.1, Rev. 1.0 4110B 4110B 4110B 4110B 4110B 4500-Cr B 4500-Cr B 4500-Cr B 4500-Cr B 4500-Cr B 4500-Cr D 4500-Cr D 4500-Cr D Reference Title In Methods for the Determination of Inorganic Substances in Environmental Samples In Methods for the Determination of Organic and Inorganic Compounds in Drinking Water, Vol. 1 Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 20th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 20th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 20th Edition Date August 1993 August 2000 1992 1995 1998 2005 2012 1992 1995 1998 2005 2012 1992 1995 1998 EPA Publication Number EPA/600/R- 93/100 EPA815-R-00- 014 Publication Order No. PB94-120821 PB2000- 106981 Source of Method https: //www.nemi. go v http://water.epa.gov/scitech/drinkingwater/labcert/methods index.cfm Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods ------- Contaminant Organization Standard Methods Standard Methods Standard Methods Online Standard Methods Online Standard Methods Online Waters Corporation Method Number 4500-Cr D 4500-Cr D 4110B-00 4500-Cr B-97 4500-Cr D-97 Method D6508, Revision 2 Reference Title Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Test Method for Determination of Dissolved Inorganic Anions in Aqueous Matrices Using Capillary Ion Electrophoresis and Chromate Electrolyte Date 2005 2012 EPA Publication Number Publication Order No. Source of Method Standard Methods Standard Methods http://www.standardmethods.org http://www.standardmethods.org http://www.standardmethods.org Water Corporation ------- Contaminant Organization Method Number Color Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Online 2120 B 2120 B 2120 B 2120 B 2120 B 2120 B-01 Copper ASTM International ASTM International ASTM International ASTM International ASTM International ASTM International D1688-07A D1688-02A D1688-95A D1688-90A D1688-07C D1688-02 C Reference Title Date EPA Publication Number Publication Order No. Source of Method Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 20th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. 1992 1995 1998 2005 2012 Criteria for analyzing aluminum, copper, iron, manganese, silver, ar procedures are contained in Section IV of Technical Notes on Drink National Environmental Publications Internet Site (NEPIS) database Annual Book of ASTM Standards, Vol. 11.01 Annual Book of ASTM Standards, Vol. 11.01 Annual Book of ASTM Standards, Vol. 11.01 Annual Book of ASTM Standards, Vol. 11.01 Annual Book of ASTM Standards, Vol. 11.01 Annual Book of ASTM Standards, Vol. 11.01 Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods http://www.standardmethods.org id zinc samples with digestion or directly without digestion, and other recommended ing Water Methods (EPA/600/R-94/173) available through EPA's digital publications i (http://www.epa.gov/nscep/). http://www.astm.org http://www.astm.org http://www.astm.org ASTM International (ASTM) http://www.astm.org http://www.astm.org ------- Contaminant Organization ASTM International ASTM International EPA EPA EPA EPA Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Method Number D1688-95 C D1688-90 C 200. 5, Rev. 4.2 200.7, Rev. 4.4 200. 8, Rev. 5.4 200. 9, Rev. 2.2 3111B 3111B 3111B 3111B 3113B 3113B 3113B 3113B Reference Title Annual Book of ASTM Standards, Vol. 11.01 Annual Book of ASTM Standards, Vol. 11.01 Determination of Trace Elements in Drinking Water by Axially Viewed Inductively Coupled Plasma - Atomic Emission Spectrometry In Methods for the Determination of Metals in Environmental Samples, Supplement I In Methods for the Determination of Metals in Environmental Samples, Supplement I In Methods for the Determination of Metals in Environmental Samples, Supplement I Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Date October 2003 May 1994 May 1994 May 1994 1992 1995 2005 2012 1992 1995 2005 2012 EPA Publication Number EPA/600-R- 06/115 EPA/600/R- 94/111 EPA/600/R- 94/111 EPA/600/R- 94/111 Publication Order No. PB95-125472 PB95-125472 PB95-125472 Source of Method http://www.astm.org ASTM International (ASTM) http://www.epa.gov/nerlcwww/ordmeth.htm https: //www.nemi. go v https: //www.nemi. go v https: //www.nemi. go v Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods ------- Contaminant Organization Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Online Standard Methods Online Method Number 3120B 3120B 3120B 3120B 3120B 3111 B-99 3113B-04 Reference Title Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 20th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Date 1992 1995 1998 2005 2012 EPA Publication Number Publication Order No. Source of Method Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods http://www.standardmethods.org http://www.standardmethods.org ------- Contaminant Organization Standard Methods Online Standard Methods Online Method Number 3113 B-99 3120 B-99 Fluoride ASTM International ASTM International ASTM International ASTM International ASTM International ASTM International Bran + Luebbe Bran + Luebbe EPA Dl 179-10 B Dl 179-04 B Dl 179-99 B Dl 179-93 B D4327-03 D4327-97 129-71 W 380-75 WE 300.0, Rev. 2.1 Reference Title Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Date EPA Publication Number Publication Order No. Source of Method http://www.standardmethods.org http://www.standardmethods.org Annual Book of ASTM Standards, Vol. 11.01 Annual Book of ASTM Standards, Vol. 11.01 Annual Book of ASTM Standards, Vol. 11.01 Annual Book of ASTM Standards, Vol. 11.01 Annual Book of ASTM Standards, Vol. 11.01 Annual Book of ASTM Standards, Vol. 11.01 Fluoride in Water and Wastewater Fluoride in Water and Wastewater In Methods for the Determination of Inorganic Substances in Environmental Samples December 1972 February 1976 August 1993 EPA/600/R- 93/100 PB94-120821 http://www.astm.org http://www.astm.org http://www.astm.org ASTM International (ASTM) http://www.astm.org http://www.astm.org Bran + Luebbe Bran + Luebbe https: //www.nemi. go v ------- Contaminant Organization EPA Hach Co. Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Method Number 300.1, Rev. 1.0 10225 4110B 4110B 4110B 4110B 4110B 4500-F' B 4500-F- B 4500-F- B 4500-F' B 4500-F' B 4500-F" C 4500-F- C Reference Title In Methods for the Determination of Organic and Inorganic Compounds in Drinking Water, Vol. 1 Hach Company SPADNS 2 (Arsenic-free) Fluoride Method 10225 - Spectrophotometric Measurement of Fluoride in Water and Wastewater Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 20th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 20th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Date August 2000 January 2011 1992 1995 1998 2005 2012 1992 1995 1998 2005 2012 1992 1995 EPA Publication Number EPA815-R-00- 014 Publication Order No. PB2000- 106981 Source of Method http://water.epa.gov/scitech/drinkingwater/labcert/methods index.cfm http://www.hach.com Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods ------- Contaminant Organization Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Method Number 4500-F- C 4500-F" C 4500-F" C 4500-F- D 4500-F- D 4500-F" D 4500-F' D 4500-F- D 4500-F- E 4500-F' E 4500-F' E 4500-F" E 4500-F- E Reference Title Standard Methods for the Examination of Water and Wastewater, 20th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 20th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 20th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Date 1998 2005 2012 1992 1995 1998 2005 2012 1992 1995 1998 2005 2012 EPA Publication Number Publication Order No. Source of Method Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods ------- Contaminant Organization Standard Methods Online Standard Methods Online Standard Methods Online Standard Methods Online Method Number 4110B-00 4500-F B-97 4500-F C-97 4500-F D-97 Reference Title Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Date EPA Publication Number Publication Order No. Source of Method http://www.standardmethods.org http://www.standardmethods.org http://www.standardmethods.org http://www.standardmethods.org ------- Contaminant Organization Standard Methods Online Waters Corporation Method Number 4500-F- E-97 Method D6508, Rev. 2 Foaming Agent Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Online 5540 C 5540 C 5540 C 5540 C 5540 C 5540 C-00 Reference Title Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Test Method for Determination of Dissolved Inorganic Anions in Aqueous Matrices Using Capillary Ion Electrophoresis and Chromate Electrolyte Date EPA Publication Number Publication Order No. Source of Method http://www.standardmethods.org Waters Corporation Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 20th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. 1992 1995 1998 2005 2012 Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods http://www.standardmethods.org ------- Contaminant Organization Method Number Iron EPA EPA EPA Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods 200. 5, Rev. 4.2 200.7, Rev. 4.4 200. 9, Rev. 2.2 3111B 3111B 3111B 3111B 3113B 3113B 3113B 3113B 3120B Reference Title Date EPA Publication Number Criteria for analyzing aluminum, copper, iron, manganese, silver, ar procedures are contained in Section IV of Technical Notes on Drink National Environmental Publications Internet Site (NEPIS) database Determination of Trace Elements in Drinking Water by Axially Viewed Inductively Coupled Plasma - Atomic Emission Spectrometry In Methods for the Determination of Metals in Environmental Samples, Supplement I In Methods for the Determination of Metals in Environmental Samples, Supplement I Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Standard Methods for the Examination of Water and Wastewater, 18th Edition October 2003 May 1994 May 1994 1992 1995 2005 2012 1992 1995 2005 2012 1992 EPA/600-R- 06/115 EPA/600/R- 94/111 EPA/600/R- 94/111 Publication Order No. Source of Method id zinc samples with digestion or directly without digestion, and other recommended ing Water Methods (EPA/600/R-94/173) available through EPA's digital publications : (http://www.epa.gov/nscep/). PB95-125472 PB95-125472 http://www.epa.gov/nerlcwww/ordmeth.htm https: //www.nemi. go v https: //www.nemi. go v Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods ------- Contaminant Organization Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Online Standard Methods Online Standard Methods Online Method Number 3120B 3120B 3120B 3120B 3111 B-99 3113B-04 3113 B-99 Reference Title Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 20th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Date 1995 1998 2005 2012 EPA Publication Number Publication Order No. Source of Method Standard Methods Standard Methods Standard Methods Standard Methods http://www.standardmethods.org http://www.standardmethods.org http://www.standardmethods.org ------- Contaminant Organization Standard Methods Online Method Number 3120B-99 Manganese EPA EPA EPA EPA Standard Methods Standard Methods Standard Methods Standard Methods 200.5, Rev. 4.2 200.7, Rev. 4.4 200.8, Rev. 5.4 200. 9, Rev. 2.2 3111B 3111B 3111B 3111B Reference Title Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Date EPA Publication Number Criteria for analyzing aluminum, copper, iron, manganese, silver, ar procedures are contained in Section IV of Technical Notes on Drink National Environmental Publications Internet Site (NEPIS) database Determination of Trace Elements in Drinking Water by Axially Viewed Inductively Coupled Plasma - Atomic Emission Spectrometry In Methods for the Determination of Metals in Environmental Samples, Supplement I In Methods for the Determination of Metals in Environmental Samples, Supplement I In Methods for the Determination of Metals in Environmental Samples, Supplement I Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition October 2003 May 1994 May 1994 May 1994 1992 1995 2005 2012 EPA/600-R- 06/115 EPA/600/R- 94/111 EPA/600/R- 94/111 EPA/600/R- 94/111 Publication Order No. Source of Method http://www.standardmethods.org id zinc samples with digestion or directly without digestion, and other recommended ing Water Methods (EPA/600/R-94/173) available through EPA's digital publications : (http://www.epa.gov/nscep/). PB95-125472 PB95-125472 PB95-125472 http://www.epa.gov/nerlcwww/ordmeth.htm https: //www.nemi. go v https: //www.nemi. go v https: //www.nemi. go v Standard Methods Standard Methods Standard Methods Standard Methods ------- Contaminant Organization Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Online Method Number 3113B 3113B 3113B 3113B 3120B 3120B 3120B 3120B 3120B 3111 B-99 Reference Title Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 20th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Date 1992 1995 2005 2012 1992 1995 1998 2005 2012 EPA Publication Number Publication Order No. Source of Method Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods http://www.standardmethods.org ------- Contaminant Organization Standard Methods Online Standard Methods Online Standard Methods Online Method Number 3113B-04 3113 B-99 3 120 B-99 Odor Standard Methods Standard Methods Standard Methods 2150 B 2150 B 2150 B Reference Title Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Date EPA Publication Number Publication Order No. Source of Method http://www.standardmethods.org http://www.standardmethods.org http://www.standardmethods.org Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 20th Edition 1992 1995 1998 Standard Methods Standard Methods Standard Methods ------- Contaminant Organization Standard Methods Standard Methods Standard Methods Online Method Number 2150 B 2150 B 2150 B-97 pH ASTM International ASTM International ASTM International ASTM International EPA EPA Standard Methods Standard Methods Standard Methods Standard Methods D1293-12 D1293-99 D1293-95 D1293-84 150.1 150.2 4500-H+ B 4500-H+ B 4500-H+ B 4500-H+ B Reference Title Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Date 2005 2012 EPA Publication Number Publication Order No. Source of Method Standard Methods Standard Methods http://www.standardmethods.org Annual Book of ASTM Standards, Vol. 11.01 Annual Book of ASTM Standards, Vol. 11.01 Annual Book of ASTM Standards, Vol. 11.01 Annual Book of ASTM Standards, Vol. 11.01 In Methods for Chemical Analysis of Water and Wastes In Methods for Chemical Analysis of Water and Wastes Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 20th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition March 1983 March 1983 1992 1995 1998 2005 EPA/600/4- 79/020 EPA/600/4- 79/020 PB84-128677 PB84-128677 http://www.astm.org http://www.astm.org ASTM International (ASTM) ASTM International (ASTM) https: //www.nemi. go v https: //www.nemi. go v Standard Methods Standard Methods Standard Methods Standard Methods ------- Contaminant Organization Standard Methods Standard Methods Online Method Number 4500-H+ B 4500-H+ B-00 Silver EPA EPA EPA EPA Standard Methods Standard Methods Standard Methods 200. 5, Rev. 4.2 200.7, Rev. 4.4 200.8, Rev. 5.4 200. 9, Rev. 2.2 3111B 3111B 3111B Reference Title Standard Methods for the Examination of Water and Wastewater, 22nd Edition Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Date 2012 EPA Publication Number Criteria for analyzing aluminum, copper, iron, manganese, silver, ar procedures are contained in Section IV of Technical Notes on Drink National Environmental Publications Internet Site (NEPIS) database Determination of Trace Elements in Drinking Water by Axially Viewed Inductively Coupled Plasma - Atomic Emission Spectrometry In Methods for the Determination of Metals in Environmental Samples, Supplement I In Methods for the Determination of Metals in Environmental Samples, Supplement I In Methods for the Determination of Metals in Environmental Samples, Supplement I Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition October 2003 May 1994 May 1994 May 1994 1992 1995 2005 EPA/600-R- 06/115 EPA/600/R- 94/111 EPA/600/R- 94/111 EPA/600/R- 94/111 Publication Order No. Source of Method Standard Methods http://www.standardmethods.org id zinc samples with digestion or directly without digestion, and other recommended ing Water Methods (EPA/600/R-94/173) available through EPA's digital publications i (http://www.epa.gov/nscep/). PB95-125472 PB95-125472 PB95-125472 http://www.epa.gov/nerlcwww/ordmeth.htm https: //www.nemi. go v https: //www.nemi. go v https: //www.nemi. go v (i.e., no sample digestion) will be higher. Standard Methods Standard Methods Standard Methods ------- Contaminant Organization Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Online Method Number 3111B 3113B 3113B 3113B 3113B 3120B 3120B 3120B 3120B 3120B 3111 B-99 Reference Title Standard Methods for the Examination of Water and Wastewater, 22nd Edition Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 20th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Date 2012 1992 1995 2005 2012 1992 1995 1998 2005 2012 EPA Publication Number Publication Order No. Source of Method Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods http://www.standardmethods.org ------- Contaminant Organization Standard Methods Online Standard Methods Online Standard Methods Online U.S. Geological Survey Method Number 3113B-04 3113 B-99 3120B-99 1-3720-85 Sulfate Reference Title Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. In Methods for Determination of Inorganic Substances in Water and Fluvial Sediments, USGS Series: Techniques of Water- Resource Investigation Report; edited by Fishman, M.J. & Friedman, L.C. Date 1989 EPA Publication Number Publication Order No. 05-Al Source of Method http://www.standardmethods.org http://www.standardmethods.org http://www.standardmethods.org http://pubs.er.usgs.gov/ ------- Contaminant Organization ASTM International ASTM International ASTM International ASTM International ASTM International ASTM International EPA EPA EPA Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Method Number D4327-03 D4327-97 D516-11 D5 16-07 D5 16-02 D5 16-90 300.0, Rev. 2.1 300.1, Rev. 1.0 375.2, Rev. 2.0 4110B 4110B 4110B 4110B 4110B 4500-SO42- C 4500-SO42- C Reference Title Annual Book of ASTM Standards, Vol. 11.01 Annual Book of ASTM Standards, Vol. 11.01 Annual Book of ASTM Standards, Vol. 11.01 Annual Book of ASTM Standards, Vol. 11.01 Annual Book of ASTM Standards, Vol. 11.01 Annual Book of ASTM Standards, Vol. 11.01 In Methods for the Determination of Inorganic Substances in Environmental Samples In Methods for the Determination of Organic and Inorganic Compounds in Drinking Water, Vol. 1 In Methods for the Determination of Inorganic Substances in Environmental Samples Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 20th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Date August 1993 August 2000 August 1993 1992 1995 1998 2005 2012 1992 1995 EPA Publication Number EPA/600/R- 93/100 EPA815-R-00- 014 EPA/600/R- 93/100 Publication Order No. PB94-120821 PB2000- 106981 PB94-120821 Source of Method http://www.astm.org http://www.astm.org http://www.astm.org http://www.astm.org http://www.astm.org ASTM International (ASTM) https: //www.nemi. go v http://water.epa.gov/scitech/drinkingwater/labcert/methods index.cfm https: //www.nemi. go v Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods ------- Contaminant Organization Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Method Number 4500-SO42- C 4500-SO42- C 4500-S042- C 4500-SO42- D 4500-SO42- D 4500-SO42- D 4500-S042- D 4500-SO42- D 4500-SO42- E 4500-SO42- E 4500-SO42- E 4500-SO42- E 4500-SO42- E 4500-SO42- F 4500-SO42' F Reference Title Standard Methods for the Examination of Water and Wastewater, 20th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 20th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 20th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Date 1998 2005 2012 1992 1995 1998 2005 2012 1992 1995 1998 2005 2012 1992 1995 EPA Publication Number Publication Order No. Source of Method Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods ------- Contaminant Organization Standard Methods Standard Methods Standard Methods Standard Methods Online Standard Methods Online Standard Methods Online Method Number 4500-SO42' F 4500-SO42' F 4500-SO42' F 4110B-00 4500-SO42' C- 97 4500-SO42' D- 97 Reference Title Standard Methods for the Examination of Water and Wastewater, 20th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Date 1998 2005 2012 EPA Publication Number Publication Order No. Source of Method Standard Methods Standard Methods Standard Methods http://www.standardmethods.org http://www.standardmethods.org http://www.standardmethods.org ------- Contaminant Organization Standard Methods Online Standard Methods Online Waters Corporation Method Number 4500-SO42- E- 97 4500-SO42- F- 97 Method D6508, Revision 2 TDS Standard Methods Standard Methods Standard Methods Standard Methods 2540 C 2540 C 2540 C 2540 C Reference Title Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Test Method for Determination of Dissolved Inorganic Anions in Aqueous Matrices Using Capillary Ion Electrophoresis and Chromate Electrolyte Date EPA Publication Number Publication Order No. Source of Method http://www.standardmethods.org http://www.standardmethods.org Waters Corporation Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 20th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition 1992 1995 1998 2005 Standard Methods Standard Methods Standard Methods Standard Methods ------- Contaminant Organization Standard Methods Standard Methods Online Method Number 2540 C 2540 C-97 Zinc EPA EPA EPA Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods 200. 5, Rev. 4.2 200.7, Rev. 4.4 200. 8, Rev. 5.4 3111B 3111B 3111B 3111B 3120B Reference Title Standard Methods for the Examination of Water and Wastewater, 22nd Edition Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Date 2012 EPA Publication Number Criteria for analyzing aluminum, copper, iron, manganese, silver, ar procedures are contained in Section IV of Technical Notes on Drink National Environmental Publications Internet Site (NEPIS) database Determination of Trace Elements in Drinking Water by Axially Viewed Inductively Coupled Plasma - Atomic Emission Spectrometry In Methods for the Determination of Metals in Environmental Samples, Supplement I In Methods for the Determination of Metals in Environmental Samples, Supplement I Standard Methods for the Examination of Water and Wastewater, 18th Edition Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Standard Methods for the Examination of Water and Wastewater, 18th Edition October 2003 May 1994 May 1994 1992 1995 2005 2012 1992 EPA/600-R- 06/115 EPA/600/R- 94/111 EPA/600/R- 94/111 Publication Order No. Source of Method Standard Methods http://www.standardmethods.org id zinc samples with digestion or directly without digestion, and other recommended ing Water Methods (EPA/600/R-94/173) available through EPA's digital publications : (http://www.epa.gov/nscep/). PB95-125472 PB95-125472 http://www.epa.gov/nerlcwww/ordmeth.htm https: //www.nemi. go v https: //www.nemi. go v Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods ------- Contaminant Organization Standard Methods Standard Methods Standard Methods Standard Methods Standard Methods Online Standard Methods Online Method Number 3120B 3120B 3120B 3120B 3111 B-99 3 120 B-99 Reference Title Standard Methods for the Examination of Water and Wastewater, 19th Edition Standard Methods for the Examination of Water and Wastewater, 20th Edition Standard Methods for the Examination of Water and Wastewater, 21st Edition Standard Methods for the Examination of Water and Wastewater, 22nd Edition Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. Date 1995 1998 2005 2012 EPA Publication Number Publication Order No. Source of Method Standard Methods Standard Methods Standard Methods Standard Methods http://www.standardmethods.org http://www.standardmethods.org ------- |