SEPA
EPA/600/R-14/215 September 2014
United States
Environmental Protection
Agency
Sample Collection Information
Document for Chemical and
Radiochemical Analytes
Companion to Selected Analytical Methods for
Environmental Remediation and Recovery
(SAM)-2012
Office of Research and Development
National Homeland Security Research Center
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Sample Collection Information
Document for Chemical and
Radiochemical Analytes
Companion to Selected Analytical
Methods for Environmental Remediation
and Recovery (SAM) 2012
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Cincinnati, OH 45268
Office of Research and Development
National Homeland Security Research Center, Threat and Consequence Assessment Division
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SAM Companion -Sample Collection Information Document
Acknowledgements
This document was developed by the U.S. Environmental Protection Agency's (EPA) National Homeland
Security Research Center (NHSRC) within EPA's Office of Research and Development as a companion
to NHSRC's Selected Analytical Methods for Environmental Remediation and Recovery (SAM). We
wish to acknowledge the external peer reviews conducted by: Terry Smith and Scott Hudson of EPA's
Office of Emergency Management (OEM), John Griggs of EPA's National Analytical Radiation
Environmental Laboratory (NAREL), and Stuart Willison of EPA's NHSRC, whose thoughtful comments
contribute greatly to the quality of the information. The document was prepared by Computer Sciences
Corporation (CSC) under EPA Contract No. EP-C-10-060, Work Assignment 16.
Disclaimer
This document is undergoing review in accordance with EPA policy prior to publication. Note that
approval for publication does not signify that the contents necessarily reflect the views of the Agency.
Mention of trade names, products, or services does not convey EPA approval, endorsement, or
recommendation.
Questions concerning this document or its application should be addressed to:
Romy Campisano
National Homeland Security Research Center
Office of Research and Development (NG16)
U.S. Environmental Protection Agency
26 West Martin Luther King Drive
Cincinnati, OH 45268
(513)569-7016
campisano.romy@epa.gov
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Table of Contents
ACKNOWLEDGEMENTS M
LIST OF ATTACHMENTS Mi
ACRONYMS AND ABBREVIATIONS v
1.0 BACKGROUND 1
2.0 SCOPE AND APPLICATION 1
2.1 SAMPLE COLLECTION INFORMATION TABLES 2
2.2 DOCUMENT DEVELOPMENT 2
2.3 LIMITATIONS 3
3.0 HEALTH AND SAFETY CONSIDERATIONS 4
3.1 HEALTH AND SAFETY PLANS 4
3.2 PERSONAL PROTECTIVE EQUIPMENT 4
3.3 TRAINING 5
4.0 PREPARATION FOR SAMPLE COLLECTION 5
4.1 FIELD SAMPLING EQUIPMENT AND SUPPLIES 5
4.2 FIELD DATA DOCUMENTATION 5
5.0 PREPARATION OF SAMPLE CONTAINERS 6
5.1 SAMPLE CONTAINER LABELS 6
5.2 PREPARING SAMPLE CONTAINERS FOR PACKAGING 6
5.3 GENERAL SAMPLE SHIPMENT GUIDELINES 6
5.4 CHAIN-OF-CUSTODY FORMS 7
5.5 CUSTODY SEALS/TAMPER-EVIDENT BAGS 7
6.0 DEFINITIONS 8
7.0 REFERENCES 9
List of Attachments
Attachment A: Sample Collection Information for the Chemical Analytes and Methods Listed in
SAM 2012
Attachment B: Sample Collection Information for the Radiochemical Analytes and Methods Listed in
SAM 2012
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Acronyms and Abbreviations
AOAC Association of Official Analytical Chemists
ASTM American Society for Testing and Materials
CDC Centers for Disease Control and Prevention
CFR Code of Federal Regulations
Ch. Chapter
CLP Contract Laboratory Program
COC Chain of Custody
CSC Computer Sciences Corporation
CWA Chemical Warfare Agent
DGR Dangerous Goods Regulations
DHS U.S. Department of Homeland Security
DIMP Diisopropyl methylphosphonate
DNPH Dinitrophenylhydrazine
DOE U.S. Department of Energy
DOL U.S. Department of Labor
DOT U.S. Department of Transportation
EA2192 Diisopropylaminoethyl methyl thiolophosphonate
ED Ethyldichloroarsine
EDEA N-Ethyldiethanolamine
EMPA Ethylmethyl phosphonate
EMSL Environmental Monitoring and Support Laboratory
EPA U.S. Environmental Protection Agency
FDA U.S. Food and Drug Administration
FRMAC Federal Radiological Monitoring and Assessment Center
GC Gas chromatography
GPS Global positioning system
FฃASL Health and Safety Laboratory
HASP Health and Safety Plan
HMP Hydroxymethyl piperidine
HMX Octahydro-1,3,5,7- tetranitro-1,3,5,7- tetrazocine
HMTD Hexamethylenetriperoxidediamine
i.d. Inner diameter
IATA International Air Transportation Association
IMPA Isopropyl methylphosphonic acid
IO Inorganic
ISO International Organization for Standardization
LC/MS/MS Liquid chromatograph/tandem mass spectrometer
MARLAP Multi-Agency Radiological Laboratory Protocols
MDEA Methyldiethanolamine
MPA Methylphosphonic acid
N Normal
NBD chloride 7-chloro-4-nitrobenzo-2-oxa-l,3-diazole
NEMI National Environmental Methods Index
NHSRC National Homeland Security Research Center
NIOSH National Institute for Occupational Safety and Health
NIST National Institute of Standards and Technology
n.o.s. Not otherwise specified (as used in 49 CFR Part 172)
NRC U.S. Nuclear Regulatory Commission
o.d. Outer diameter
ORISE Oak Ridge Institute for Science and Education
OSHA Occupational Safety and Health Administration
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OSWER Office of Solid Waste and Emergency Response
OVS OSHA versatile sampler
OW Office of Water
PETN Pentaerythritol tetranitrate
PMPA Pinacolyl methyl phosphonic acid
PPE Personal protective equipment
PTFE Polytetrafluoroethylene (Teflonฎ)
PUF Polyurethene foam
PVC Polyvinylchloride
QC Quality control
qty Quantity
RDX Hexahydro-l,3,5-trinitro-l,3,5-triazine
RESL Radiological and Environmental Sciences Laboratory
SAM Selected Analytical Methods for Environmental Remediation and Recovery
SCID Sample Collection Information Document
SCP Sample Collection Plan
SM Standard Method
SRS Savannah River Site
SW Solid waste
TBD To be determined
TDG Thiodiglycol
TEA Triethanolamine
TNB Trinitrobenzene
TNT Trinitrotoluene
TO Toxic organic
UN United Nations
USGS United States Geological Survey
VCSB Voluntary Consensus Standards Body
VOA Volatile organic analyte
VOC Volatile organic compound
Vol. Volume
VTSR Validated Time of Sample Receipt
XAD Polymeric resin
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Sample Collection Information Document
[Companion to Selected Analytical Methods for Environmental Remediation
and Recovery (SAM) 2012]
1.0 Background
The U.S. Environmental Protection Agency's (EPA's) National Homeland Security Research
Center (NHSRC) has worked with experts from across EPA and its sister agencies since 2003 to
develop a compendium of analytical methods to be used when responding to intentional or
unintentional contamination incidents. Analytical methods have been selected for chemical,
radiochemical, pathogen and biotoxin analytes of concern for the types of environmental sample
matrices that are anticipated in such incidents. The results of these efforts have been published
in several revisions of EPA's Selected Analytical Methods for Environmental Remediation and
Recovery (SAM).1 NHSRC periodically reviews and updates the SAM document to address the
needs of homeland security, reflect improvements in analytical methods and new technologies,
and incorporate changes in target analytes.
During development of the SAM documents, EPA recognized the need for a companion
document to provide information regarding collection of samples for analysis by the methods
selected. This document is intended to address this need, in part, by providing information
regarding sample containers, preservation, size, packaging and sources for additional
information supporting collection of chemical and radiochemical samples to be analyzed using
the methods listed in SAM 2012. As with SAM, NHSRC plans to update the information in this
document periodically, to reflect changes to the analytes and/or methods listed in SAM.
The information contained in this document is intended to support and be used with the
methods listed in SAM 2012. The information will be reviewed and updated periodically,
along with the SAM document, to reflect advances in technologies, results of method
evaluation and validation studies, and additional analytes or matrices.
2.0 Scope and Application
This Sample Collection Information Document (SCID) provides general information for use by
EPA and its contractors when collecting samples during environmental remediation following a
contamination incident. The document is intended to be used with SAM, and to provide
information needed for collection of samples to be analyzed using the specific methods and
procedures listed in SAM 2012 (EPA/600/R-12/555). Where possible, the information provided
was obtained from the sample collection requirements and guidelines included in the SAM 2012
analytical methods. Where this information was not available, additional sources were used (see
Section 7.0).
The information in this document is intended to be used during site assessment, remediation and
clearance activities following a contamination incident; it assumes that samples will be collected
by personnel trained in collection of environmental samples containing the target analytes and in
dealing with the corresponding safety concerns. Information is included regarding containers,
1 Formerly Standardized Analytical Methods for Environmental Restoration Following Homeland Security Events
(SAM). SAM and its methods are available at: http://www.epa.gov/sam/.
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collection volume or weight, preservation, holding times, and packaging of samples representing
the sample types and analytes for chemical and radiochemical analytes listed in SAM 2012.
Collection, preservation, and shipment procedures and information for samples containing
chemical warfare agents (CWAs) listed in SAM are currently being evaluated by EPA and,
therefore, are not included in this document at this time. Sample collection information for
pathogens and biotoxins listed in SAM are being evaluated and developed, and also are not
included in this document. For information regarding collection of samples to be analyzed for
CWAs, pathogens or biotoxins, users of this document should contact the SAM technical leads at
http://www.epa.gov/sam/resources.htm.
NOTE: It is possible that some of the information in this document should be modified to address
site- or event-specific data needs; for example, additional sample volume may be needed for quality
control (QC) or in cases when a low concentration of analyte is suspected. Sample Collection Plans
(SCPs) should be in place and consulted for specific sample collection requirements prior to initiation
of sample collection activities. Site- or event-specific SCPs include information regarding laboratory
capacity, the extent of contamination, target analytes, data quality objectives, sample locations and the
number and type of samples needed.
2.1 Sample Collection Information Attachments
This document contains the following two attachments listing information for
collection of samples that will be analyzed for measurement of the analytes listed in
SAM 2012:
Attachment A: Sample Collection Information for the Chemical Analytes and
Methods Listed in SAM 2012
Attachment B: Sample Collection Information for the Radiochemical Analytes and
Methods Listed in SAM 2012
Each attachment provides the sample size that should be collected to support sample
analysis, the preservatives and/or temperature needed to maintain sample integrity prior
to analysis, the maximum amount of time that should elapse between sample collection
and the initiation of analytical procedures (e.g., sample analysis, digestion or extraction),
the appropriate type of container, the sample label and packaging procedures needed for
sample shipment, and the source(s) used to provide the information. The information in
each attachment is arranged by sample type (e.g., solid, particulate, water, wipes) and
corresponds to the sample types listed for each analyte in SAM.
2.2 Document Development
EPA developed a hierarchy of references to prioritize the documents and resources that
were used to identify the information that is included in this document. The first sources
consulted were the methods listed in SAM 2012. If those methods included sample
collection information, the information was evaluated and, if appropriate, included in the
sample collection information tables provided in Attachments A and B. The second
sources consulted were EPA procedures for collection of samples addressing the specific
analyte/matrix pairs. If there were no EPA procedures available, other federal agency or
Voluntary Consensus Standards Body (VCSB)2 methods were consulted. If no
2 EPA OMB Circular No. A-119, February 1998. VCSBs are domestic or international organizations which plan,
develop, establish, or coordinate voluntary consensus standards using agreed-upon procedures. Under the National
Technology Transfer and Advancement Act (NTTAA), participation of federal representatives in VCSBs is
encouraged to increase the likelihood that the standards they develop will meet both public and private sector needs.
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procedures were identified for collection of a particular analyte/matrix pair, methods for
that analyte in other sample types were considered, followed by procedures described and
supported by data in research literature, such as journal articles.
The following agencies, organizations, and publications were used:
U.S. EPA - United States Environmental Protection Agency
AOAC - AOAC International (formerly Association of Official Analytical Chemists)
ASTM - ASTM International (formerly American Society for Testing and Materials)
CFR - Code of Federal Regulations
U.S. DHS - United States Department of Homeland Security
U.S. DOE - United States Department of Energy
U.S. DOL - United States Department of Labor
U.S. DOT - United States Department of Transportation
U.S. FDA - United States Food and Drug Administration
USGS - United States Geological Survey
IATA - International Air Transport Association
ISO - International Organization for Standardization
NEMI - National Environmental Methods Index
NIOSH - National Institute for Occupational Safety and Health
Organisation for the Prohibition of Chemical Weapons
OSHA - Occupational Safety and Health Administration
Standard Methods for the Examination of Water and Wastewater
Washington State Department of Ecology
Journals: Analyst, Analytical Letters, Atmospheric Environment, Chromatographia,
Journal of Chromatography A, Journal of Chromatography B, Journal of Forensic
Sciences
Sample collection information was not identified for all the analyte/matrix pairs listed in
SAM. In some cases, "TBD" (to be determined) is used to identify gaps of information
that have yet to be determined. In other cases, a footnote is used to identify information
that is considered to be applicable to a given analyte/matrix pair because the information
is specific to a similar analyte or matrix.
2.3 Limitations
This document provides summary information only regarding collection of samples to be
analyzed for measurement of the chemical and radiochemical analytes listed in SAM
2012. Although at this time much of the information has not been tested for the
particular analytes (e.g., analytes not explicitly identified in the method) or sample types,
the information listed is considered to be the most appropriate currently available. For
example, research is needed to determine appropriate preservation and holding times for
many of the chemical agents. Many of the target analytes listed in this document have
only recently become an environmental concern, and EPA is actively pursuing
development and validation of appropriate sample collection procedures.
Sample collection plans must be consulted for site- or event-specific requirements,
including QC and reporting. The information sources cited in this document also should
be consulted for additional details regarding sample collection, including QC
requirements, sample handling, packaging, shipping and safety procedures. Sample
collectors should check with the incident commanders for special instructions regarding
evidentiary matters prior to sample collection.
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3.0 Health and Safety Considerations
This document assumes that a site- or event-specific Health and Safety Plan (HASP) is in place
that includes the safety concerns and requirements regarding the specific types of hazards that
should be considered during a sample collection event. This section provides general guidelines
regarding health and safety concerns. At a minimum, all sampling team members should be
trained in Occupational Safety and Health Administration (OSHA) requirements for hazardous
waste operations and emergency response at 29 CFR 1910.120 or 29 CFR 1926.65 and have
current medical screening.
3.1 Health and Safety Plans
Health and Safety Plans (HASPs) will vary depending on the site, the sampling phase
(site assessment, remediation or final status determination) and the responsible
organization. The purpose of these plans is to ensure maximum protection to workers,
the environment and surrounding communities, in a way that is consistent with
requirements needed to perform operational activities. Guidance on developing HASPs
is provided in the U.S. Department of Labor Occupational Safety and Health
Administration's template at: https://www.osha.gov/dep/anthrax/hasp/index.html. At a
minimum, HASPs should include instructions and guidelines regarding:
Names, positions, and contact information of key personnel and health and safety
personnel
Site- or event-specific risk assessment addressing sample collection activities
Training requirements
Personal protective equipment (PPE) on site and usage requirements
Medical screening requirements (maintain confidential documents properly and
securely)
Site or event control
Emergency response plan, containing off-site emergency contact information such as
local hazardous materials response teams or additional trained rescue personnel (29
CFR 1910.38)
Entry and egress procedures
Spill containment
Decontamination procedures
NOTE: Entry and decontamination procedures should address personnel monitoring and
decontamination during entry and egress.
3.2 Personal Protective Equipment and Monitoring
Each site or event also will dictate the level of PPE that will be required. Selection of
protective clothing is dependent on site conditions and sample collection requirements
included in the SCP. Specific guidance for selection of PPE is provided in 29 CFR
1910.120, Appendix B. Factors that should be considered during selection include:
contaminant identification, routes of exposure (i.e., inhalation, skin absorption, ingestion
and injection), performance of equipment in protecting against exposure, activity
duration, and stress induced by work requirements. Because the use of PPE can also
cause hazards to workers (e.g., heat stress, impaired vision and mobility), care should be
taken to provide a level of protection that is sufficient to prevent exposure yet is not too
high so as to create other unnecessary hazards.
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3.3 Training
Sample collectors must be trained in collection and handling of samples suspected of
containing the contaminants of concern (see Attachments A and B), must be up to date
regarding medical screening requirements, and must be approved for site entry.
Additionally, sample collectors and packers must be trained in and comply with the site
HASP and all site-specific training requirements, including the following:
Ability to select and work with the appropriate level of PPE
Ability to apply appropriate personnel monitoring
Decontamination procedures
Prevention of sample cross-contamination
Training frequency and documentation
4.0 Preparation for Sample Collection
It is highly recommended that sampling kits be used during sample collection, and that these kits
be properly equipped, maintained, and organized before deployment of sample collection
personnel. Sample collectors should consult with project managers and the SCP to determine
what equipment and materials should be assembled. Prior to sample collection, samplers should
also contact the laboratory that will be analyzing the samples to understand laboratory-specific
requirements. Sample kits should contain all sample containers, materials, supplies and forms
needed to perform sample collection, decontamination, documentation and field packaging
activities.
4.1 Field Sampling Equipment and Supplies
Before starting field sampling activities, all necessary equipment and supplies should be
identified and available. The following is a preliminary list of equipment that should be
specified and available:
Sampling devices (e.g., air filters, soil samplers, water samplers, air filter samplers)
Sample preservation equipment (e.g., acids, dechlorinating reagents)
Sample volumetric measuring devices and/or weighing devices
Sample containers and packaging equipment
PPE
Record keeping devices (e.g., logs, Chain-of-Custody [COC] forms, writing
instruments)
Site maps, global positioning system (GPS) recorders, etc.
Sample location markers
Pre-labeled and pre-weighed sampling containers
Shipping containers, shipping forms, and shipping labels
4.2 Field Data Documentation
All data collected in the field should be adequately documented. Documented
information should include (for example):
Names of field sampling personnel
Sample Collection Plan (SCP)
Sample location(s)
Sampling depth
Physical and meteorological conditions
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Date and time of sampling
Sample medium
Expected contaminants
Expected radionuclides (if applicable)
Sample identification number
Sample size (weight, volume), sample duration (air filters), air volume, etc.
Sample handling precautions
Radiological dose rate measurements of samples performed in the field should be
documented and transmitted to the laboratory along with the samples. Documentation
should include the type of instrument used, background count rates, and units.
5.0 Preparation of Sample Containers
5.1 Sample Container Labels
Each sample container has a label that provides information uniquely identifying and
describing the sample. A single, unique label is affixed to each individual sample
container, sample information is added in waterproof ink, and the label is covered with
clear tape. Alternatively, a pre-prepared label that uniquely identifies the sample, such as
a bar code that tracks the sample information, can be affixed to the container. Sample
container labels include information regarding the date and time of sample collection;
date, time and type of sample preservation; sample identification numbers; and the names
and signatures of sample collectors.
5.2 Preparing Sample Containers for Packaging
Once samples have been collected and preserved as specified, the containers are prepared
for shipment to the analytical laboratory. Sample containers should be labeled, sealed,
and cleaned or disinfected prior to packing into transport or shipping containers. For
samples containing radiochemical analytes, each sample container should have exposure
rate measurements taken and surface contamination surveys completed, and the results
recorded on a field sample tracking form (see EPA's Sample Collection Procedures for
Radiochemical Analytes in Environmental Matrices, July 2012). Summary procedures
for cleaning and sealing sample containers are provided in the tables included in
Attachments A and B. General information regarding packing samples into transport
containers outside the contaminated area is provided as a footnote to each table.
5.3 General Sample Shipment Guidelines
Samplers are responsible for ensuring compliance with DOT and IATA regulations
regarding the transfer of hazardous substances and environmental samples. These
regulations, 49 CFR 172 and 173 for DOT (organized by separate subparts as references
in Section 7.0) and the Dangerous Goods Regulations (DGR) for IATA, provide specific
details regarding proper marking, labeling, placarding, packaging and shipment of
hazardous materials, substances and wastes and regulatory exceptions; and must be
consulted prior to preparation of or planning for sample shipment. Summary information
regarding appropriate labeling and packaging of sample transport containers is provided
in the sample collection information tables included in Attachments A through C.
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5.4 Chain-of-Custody Forms
COC forms create a written record that can be used to trace the creation, possession, and
handling of the sample from the moment of its collection through analysis. A COC form
accompanies each sample or group of samples as custody of the sample(s) is transferred
from one custodian to another. One copy of the form is retained by the original sample
collector. If multiple laboratories are receiving a sample, individual COCs are provided
to each individual laboratory, each COC representing the contents of the sample
shipment. Sample collectors are responsible for the initial maintenance and completion
of COC forms. Although COC forms vary in style, format and detail, the forms should
contain the same minimal information required to identify the sample and to document
custody.
At a minimum, sample collectors are responsible for providing the following information
on the COC form:
General incident information (sample owners, contact information, site name)
Sample information (e.g., sample identification number, sample type [matrix],
whether grab or composite, number and type of sample containers, and date/time
sample was collected)
Date and time the sample was relinquished
Signature of persons transferring and receiving the samples
5.5 Custody Seals / Tamper-evident Bags
Custody seals are attached over the cap of each sample container to ensure the sample has
not been opened or tampered with after collection and packaging. A custody seal also
can be placed over the shipping or transport container, making it impossible to open the
container without ripping the seal. Typically, there is one seal per sample container and
two seals are placed on opposite sides of the shipping container. Custody seals contain
the signature of the person responsible for packing the container and the date sealed. The
seal must be sturdy to resist incidental contact but able to break when the cap or lid is
moved. Sample collectors should:
Sign and date the sample custody seal, usually a 1- by 3-inch white paper label with
black lettering and an adhesive backing. The custody seal is part of the COC process
and is used to prevent or identify tampering with samples.
Place the custody seal across the container lid so that the seal would be broken if a
container were to be opened. If a cooler is used, ensure that the water drainage point
is secure.
Alternatively, sample containers may be placed into a tamper-evident bag. Bags/seals
with a unique identifier must be associated with the person collecting the sample through
logbook entries, preservation of tear-off strips in the logbook, or similar means. When
using a tape-type tamper-evident seal, the initials of the person securing the container and
the date that it was secured must be recorded on the seal.
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6.0 Definitions
The following definitions are provided to describe the sample collection information listed in the
tables in Attachments A and B:
Analyte - The chemical compound, class of compound, radionuclide or radioactivity that
will be measured in the sample. The analytes in this document are intended to address the
analytes listed in SAM 2012.
Container - The type of container (e.g., bottle, bag) that must be used to hold the sample.
The container must be sufficient to maintain sample integrity and be composed of materials
that will remain inert when in contact with the sample.
Holding Time - The maximum amount of time allowable from sample collection until
sample analysis or extraction.
Packaging - Sample container packaging requirements for shipment of sample to the
laboratory.
Preservation - Conditions and/or chemicals used to maintain the integrity of a sample.
Some examples of common preservatives include nitric acid, hydrochloric acid, sodium
thiosulfate, and temperatures < 4ฐC.
Sample Size - The minimum amount of sample that should be collected to support analysis
of a single sample. Volume and weight requirements depend on the target analyte(s), the
analytical method that will be used, and the data requirements.
Shipping Label - U.S. DOT shipping label requirements under 49 CFR 172 and 173.
Source/SAM Method - The reference(s) supporting the information provided. Tiers are
provided for SAM chemistry methods, to indicate the level of analytical method usability
assigned by SAM workgroups for the specific analyte and sample type. SAM describes these
tiers as:
- Tier I: Analyte/sample type is a target of the method(s). Data are available for all aspects
of method performance and quality control measures supporting its use for a nalysis of
environmental samples following a contamination event. Evaluation and/or use of the
method(s) in multiple laboratories indicate that the method can be i mplemented with no
additional modifications for the analyte/sample type.
- Tier II: The analyte/sample type is a target of the method(s) and the method(s) has been
evaluated for the analyte/sample type by one or more laboratories, or (2) the a
nalyte/sample type is not a target of the method(s), but the method has been used by
laboratories to address the analyte/sample type. In either case, available data and/or
information indicate that modifications will likely be needed for use of the method(s) to
address the analyte/sample type.
- Tier III: The analyte/sample type is not a target of the method(s), and/or no reliable data
supporting the method's fitness for its intended use are available. Data from other
analytes or sample types, however, suggest that the method(s), with significant
modification, may be applicable.
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7.0 References
Analytical methods listed in Attachments A and B can be accessed through SAM at
http://www.epa.gov/sam/. In addition to these methods, the following resources were used to
prepare this document:
Crowson, A., Beardah, M. 2001. "Development of an LC/MS Method for the Trace Analysis
of Hexamethylenetriperoxidediamine (HMYD)" Analyst. 126:1689-1693.
Hamelin, E., Mawhinney, D., Parry, R., Kobelski, R. 2010. "Quantification of
Monofluoroacetate and Monochloroacetate in Human Urine by Isotope Dilution Liquid
Chromatography Tandem Mass Spectrometry." Journal ofChromatography B. 2010
878(15/16): 1045-1050.
Hamet, C., Asuncion, L. 2011. "Single-Laboratory Validation of a Method to Quantify
Bound 2-Chloropropane-l,3-diol and 3-Chloropropane-l,2-diol in Foodstuffs Using Acid
Catalysed Transesterification, HFBI Derivatisation and GC/MS Detection." European
Journal LipidScience and Technology. 113: 345-355.
Hiemstra, M. and de Kok, A. 2007. "Comprehensive Multi-residue Method for the Target
Analysis of Pesticides in Crops Using Liquid Chromatography-tandem Mass Spectrometry."
Journal of Chromatography A. 1154(1): 3-25.
Johnson, B.J., Emerson, D.W., Song, L., Floyd, J. and Tadepalli, B. 1999. "Determination of
Active Chlorine in Air by Bonded Phase Sorbent Collection and Spectrophotometric
Analysis." Analyst. 124(12): 1853-1857.
Kirchherr, H. 1993. "Determination of Hydrazine in Human Plasma by High-Performance
Liquid Chromatography." Journal ofChromatography B: Biomedical Sciences and
Applications. 617(1): 157-162.
Kruszyna, R., Smith, R.P. and Kruszyna, H. 1998. "Determining Sodium Azide
Concentration in the Blood by Ion Chromatography." Journal of Forensic Sciences. 43(1):
200-202.
Liu, F., Bischoff, G., Pestemer, W., Xu, W. and Kofoet, A. 2006. "Multi-residue Analysis of
Some Polar Pesticides in Water Samples with SPE and LC/MS/MS." Chromatographia.
63(5/6): 233-237.
Mathew, B., Anastasio, C. 2000. "Determination of Halogenated Mono-alcohols and Diols in
Water by Gas Chromatography with Electron-Capture Detection." Journal of
Chromatography A. 866: 65-77.
Noonan, G., Begley, T., Diachenko, G. 2007. "Rapid Quantitative and Qualitative
Confirmatory Method for the Determination of Monofluoroacetic Acid in Foods by Liquid
Chromatography-Mass Spectrometry." Journal ofChromatography A. 1139(2): 271-278.
Tomkins, B.A. 1994. "Screening Procedure for Sodium Fluoroacetate (Compound 1080) at
Sub-Microgram/Gram Concentrations in Soils." Analytical Letters. 27(14): 2703-2718.
U.S. Department of Energy. March 1979. "Radiochemical Analytical Procedures for Analysis
of Environmental Samples." Environmental Monitoring and Support Laboratory. EMSL-LV-
0539-17. http://www.health.state.mn.us/divs/phl/accreditation/docs/refmethodepa053917.pdf
(accessed June 2014).
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U.S. Department of Labor. 29 CFR 1910.120, "Hazardous Waste Operations and Emergency
Response," 29 CFR 1910.120, Appendix B, "General Description and Discussion of the
Levels of Protection and Protective Gear," and 1910.38 "Emergency Action Plans."
http://www.osha.gov/pls/oshaweb/owasrch.search form?p doc tvpe=STANDARDS&p toe
_level=1 &p_keyvalue= 1910 (accessed June 2014).
U.S. Department of Labor. 29 CFR 1926.65. "Hazardous Waste Operations and Emergency
Response."
http://www. osha.gov/pls/oshaweb/owadisp. show_document?p_table=STANDARDS&p_id=l
0651 (accessed June 2014).
U.S. Department of Transportation. 49 CFR 172.101. "Purpose and Use of Hazardous
Materials Table." http://ecfr.gpoaccess.gov/cgi/t/text/text-
idx?c=ecfr:sid=c28017b4dla5ccfa65c01bc527771253:rgn=div5;view=text:node=49%3A2.1.
1.3.8;idno=49;cc=ecfr (accessed June 2014).
U.S. Department of Transportation. 49 CFR 172.301. "General Marking Requirements for
Non-Bulk Packagings." http://ecfr.gpoaccess.gov/cgi/t/text/text-
idx?c=ecfr:sid=c28017b4dla5ccfa65c01bc527771253:rgn=div5:view=text:node=49%3A2.1
.1.3.8;idno=49;cc=ecfr (accessed June 2014).
U.S. Department of Transportation. 49 CFR 173. "Shippers - General Requirements for
Shipments and Packaging." http://ecfr.gpoaccess.gov/cgi/t/text/text-
idx?c=ecfr:rgn=div5:view=text:node=49%3A2.1.1.3.9;idno=49:sid=09c9fel3d2d28dae87elf
flfcfd94388;cc=ecfr (accessed June 2014).
- U.S. Department of Transportation. 49 CFR 173.132. "Class 6, Division 6.1-
Definitions." http://www.ecfr.gov/cgi-bin/text-
Jdx?SID=Oc46a55el5a8fcl66b592b9bcd9aelc4&node=49:2.1.1.3.9.4.25.Il&rgn=div8
(accessed June 2014).
- 49 CFR 173.150. "Exceptions for Class 3 (flammable and combustible liquids)."
http://ecfr.gpoaccess.gov/cgi/t/text/text-
idx?c=ecfr&sid=fcba55e480a66cbb555aa7cb35816b4d&rgn=div5&view=text&node=49:
2.1.1.3.9&idno=49#49:2.1.1.3.9.4.25.20 (accessed June 2014).
- 49 CFR 173.153. "Exceptions for Division 6.1 (poisonous materials)."
http://ecfr.gpoaccess.gov/cgi/t/text/text-
idx?c=ecfr:rgn=div5;view=text:node=49%3A2.1.1.3.9;idno=49;sid=09c9fe 13d2d28dae8
7elfflfcfd94388:cc=ecfr#49:2.1.1.3.9.4.25.23 (accessed June 2014).
- 49 CFR 173.154. "Exceptions for Class 8 (corrosive materials)."
http://ecfr.gpoaccess.gov/cgi/t/text/text-
idx?c=ecfr:rgn=div5:view=text:node=49%3A2.1.1.3.9:idno=49:sid=09c9fe 13d2d28dae8
7elfflfcfd94388:cc=ecfr#49:2.1.1.3.9.4.25.24 (accessed June 2014).
- 49 CFR 173.24 and 173.24a. "General Requirements for Packaging" and "Packages and
Additional General Requirements for Non-bulk Packaging and Packages."
http://ecfr.gpoaccess.gov/cgi/t/text/text-
idx?c=ecfr:rgn=div5:view=text:node=49%3A2.1.1.3.9:idno=49:sid=09c9fe 13d2d28dae8
7elfflfcfd94388:cc=ecfr#49:2.1.1.3.9.2.25.5 (accessed June 2014).
10 September 2014
-------
SAM Companion -Sample Collection Information Document
- 49 CFR 173.403. "Definitions." http://ecfr.gpoaccess.gov/cgi/t/text/text-
idx?c=ecfr:rgn=div5:view=text:node=49%3A2.1.1.3.9:idno=49:sid=09c9fe 13d2d28dae8
7elfflfcfd94388:cc=ecfr#49:2.1.1.3.9.9.25.2 (accessed June 2014).
- 49 CFR 173.453. "Fissile Materials - Exceptions."
http://ecfr.gpoaccess.gov/cgi/t/text/text-
idx?c=ecfr:rgn=div5:view=text:node=49%3A2.1.1.3.9:idno=49:sid=09c9fe 13d2d28dae8
7elfflfcfd94388;cc=ecfr#49:2.1.1.3.9.9.25.31 (accessed June 2014).
U.S. Environmental Protection Agency. 40 CFR 61, Appendix B. "Standards of Performance
for New Stationary Sources, Performance Specifications - Test Methods."
http: //www. ecfr. gov/cgi-bin/text-
idx?SID=4ac359277bd96162371110314291e70b&node=40:9.0.1.1.1.29.1.21.5&rgn=div9
(accessed June 2014).
U.S. Environmental Protection Agency. July 2012. "Sample Collection Procedures for
Radiochemical Analytes in Environmental Matrices." EPA/600/R-12/566, National
Homeland Security Research Center. Cincinnati, OH.
http://www.epa.gov/sam/Sample Collection Procedures for Radiochemical Analvtes .pdf
(accessed June 2014).
U.S. Environmental Protection Agency. July 2012. "Selected Analytical Methods for
Remediation and Recovery (SAM) - 2012." EPA/600/R-12/555, National Homeland Security
Research Center. Cincinnati, OH. http://www.epa.gov/sam/SAM_2012_07162012.pdf
(accessed June 2014).
U.S. Environmental Protection Agency. Office of Solid Waste and Emergency Response
(OSWER), SW-846 Methods on Line.
http://www.epa.gov/osw/hazard/testmethods/sw846/online/ (accessed June 2014).
U.S. Environmental Protection Agency Office of Management and Budget. February 1998.
Circular No. A-119 Federal Participation in the Development and Use of Voluntary
Consensus Standards and in Conformity Assessment Activities.
http://www.whitehouse.gov/omb/circulars al 19 (accessed June 2014).
Xie, Y. 2006. "Cyanogen Chloride and Cyanogen Bromide Analysis in Drinking Water."
Encyclopedia of Analytical Chemistry, 1-11.
http://onlinelibrarv.wilev.com/doi/10.1002/9780470027318.a0809/abstract (accessed June
2014).
Xu, X., Song, G., Zhu, Y., Zhang, J., Zhao, Y., Shen, H., Cai, Z., Han, J. and Ren, Y. 2008.
"Simultaneous Determination of Two Acute Poisoning Rodenticides Tetramine and
Fluoroacetamide With a Coupled Column in Poisoning Cases." Journal of Chromatography
B. 876(1): 103-108.
11 September 2014
-------
Attachment A
Sample Collection Information for the
Chemical Analytes and Methods
Listed in SAM 2012
-------
Attachment A: Sample Collection Information for the Chemical Analytes Listed in SAM 2012
Air Samples
Analyte
Acephate
Acrylamide
Acrylonitrile
Aldicarb (Temik)
Aldicarb sulfone
Aldicarb sulfoxide
Sample
Volume'11
TBD
1 20 L (flow rate
= 1 L/min)
1 20 L (flow rate
= 1 L/min)
240 - 480 L
240 - 480 L
240 - 480 L
Sample Container
250 mL PTFE
centrifuge tube
Filter/solid sorbent
tube (OVS-7 tube:
13mm quartz fiber
filter, XAD-7 [270
mg/140 mg])
Filter/solid sorbent
tube (OVS-7 tube:
13mm quartz fiber
filter, XAD-7 [270
mg/140 mg])
Filter/solid sorbent
tube (OVS-2 tube:
13mm quartz fiber
filter, XAD-2 [270
mg/140 mg])
Filter/ solid sorbent
tube (OVS-2 tube: 13
mm quartz filter, XAD-
2, [270mg/140mg])
Filter/solid sorbent
tube (OVS-2 tube: 13
mm quartz filter, XAD-
2, [270mg/140mg])
Holding Time
TBD
Stable at least 4 days
at temperatures up to
45ฐC.
Stable at least 4 days
at temperatures up to
45ฐC.
Stable at least 30
days at negative (-)
12ฐCoratleast7
days at 24ฐC.
TBD
TBD
Sample Preservation
or Preparation
TBD
None
None
Store refrigerated and tightly
sealed. Analyze at room
temperature.
Store refrigerated and tightly
sealed. Analyze at room
temperature.
Store refrigerated and tightly
sealed. Analyze at room
temperature.
Packaging Requirements
TBD
Place filter in protective covering. Wipe outside
of each sorbent tube clean using a damp, then
dry cloth. Cap both ends of the tube with
plastic caps. Place protected filter and/or tubes
in double plastic bags and wrap with bubble
wrap. Pack samples as described in Footnote
(4).
Place filter in protective covering. Wipe outside
of each sorbent tube clean using a damp, then
dry cloth. Cap both ends of the tube with
plastic caps. Place protected filter and/or tubes
in double plastic bags and wrap with bubble
wrap. Pack samples as described in Footnote
(4).
Place filter in protective covering. Wipe outside
of each sorbent tube clean using a damp, then
dry cloth. Cap both ends of the tube with
plastic caps. Place protected filter and/or tubes
in double plastic bags and wrap with bubble
wrap. Pack samples as described in Footnote
(4).
Place filter in protective covering. Wipe outside
of each sorbent tube clean using a damp, then
dry cloth. Cap both ends of the tube with
plastic caps. Place protected filter and/or tubes
in double plastic bags and wrap with bubble
wrap. Pack samples as described in Footnote
(4).
Place filter in protective covering. Wipe outside
of each sorbent tube clean using a damp, then
dry cloth. Cap both ends of the tube with
plastic caps. Place protected filter and/or tubes
in double plastic bags and wrap with bubble
wrap. Pack samples as described in Footnote
(4).
Shipping Label121
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Acrylamide, solid, 6.1 ,
Poison, UN2074
Standard carrier
shipping label AND
Acrylonitrile,
stabilized, 3,
Flammable liquid, 6.1 ,
Poison, UN1093
Standard carrier
shipping label AND
Carbamate
pesticides, solid,
toxic, 6.1, UN2757
Standard carrier
shipping label AND
Carbamate
pesticides, solid,
toxic, 6.1, UN2757
Standard carrier
shipping label AND
Carbamate
pesticides, solid,
toxic, 6.1, UN2757
Source/SAM
Method131
Adapted from
Journal of
Chroma tography
A, 1154(1): 3-25
[SAM Tier III]
PV2004
(OS HA)
[SAM Tier I]
PV2004
(OS HA)
[SAM Tier III]
5601
(NIOSH)
[SAM Tier I]
5601
(NIOSH)
[SAM Tier III]
5601
(NIOSH)
[SAM Tier III]
Sample Collection Information Document
A1 -1
September 2014
-------
Air Samples
Analyte
Allyl alcohol'51
4-Aminopyridine
Ammonia
Ammonium
metavanadate
(analyze as total
vanadium)
Arsenic, Total
Arsenic trioxide
(analyze as total
arsenic)
Arsine
Asbestos
Sample
Volume'11
One to four 1 L
or 6 L samples
(depending on
suspected
concentration)
each in a
separate
canister'6'
Sample Container
Specially prepared 1 L
or 6 L stainless steel
canister
For subatmospheric
pressure sampling, the
canister is evacuated
to 0.05 mm Hg; for
pressurized sampling,
the sample is collected
using a pump and flow
control arrangement to
achieve a typical 101 -
202 kPa(15-30psig)
Holding Time
Under conditions of
normal use, most
VOCs can be
recovered from
canisters near their
original
concentrations after
storage times of up to
30 days.
Sample Preservation
or Preparation
None
Packaging Requirements
Ship canister in container provided by
laboratory.
Shipping Label'2'
Standard carrier
shipping label AND
Allyl alcohol, 3,
Flammable liquid, 6.1,
Poison, UN1098.
Source/SAM
Method'3'
TO-15
(EPAORD)
[SAM Tier III]
Not of concern in this sample type
0.1 (at 50 ppm)
-96L
Up to 1700m3
Up to 1700m3
Up to 1700m3
0.1 L (at 0.05
ppm) - 1 0 L
500 - 5000 L
Solid sorbent tube
(sulfuric acid-treated
silica gel)
Filter (quartz, silica, or
cellulose fiber)
Filter (quartz, silica, or
cellulose fiber)
Filter (quartz, silica, or
cellulose fiber)
Solid sorbent tube
(coconut shell
charcoal [1 00 mg/50
mg])
Polycarbonate or
cellulose ester filter
1 day after
desorption.
6 months
6 months
6 months
6 days
None
After desorption, adjust pH of
the desorption solution to
between 5 - 6.5 with NaOH.
None
None
None
25ฐC
None
Wipe outside of each sorbent tube clean using
a damp, then dry cloth. Cap tubes with plastic
(not rubber) caps immediately after sampling.
Place tubes in double plastic bags and wrap
with bubble wrap. Pack samples as described
in Footnote (4).
Place filter in protective covering. Place
protected filter in double plastic bags, and wrap
with bubble wrap. Pack samples as described
in Footnote (4).
Place filter in protective covering. Place
protected filter in double plastic bags, and wrap
with bubble wrap. Pack samples as described
in Footnote (4).
Place filter in protective covering. Place
protected filter in double plastic bags, and wrap
with bubble wrap. Pack samples as described
in Footnote (4).
Wipe outside of each sorbent tube clean using
a damp, then dry cloth. Cap tubes with plastic
(not rubber) caps. Place tubes in double
plastic bags and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Place filter in protective covering. Place
protected filter in double plastic bags, and wrap
with bubble wrap. Pack samples as described
in Footnote (4).
Standard carrier
shipping label AND (if
greater than 10%
ammonia by volume)
Ammonia solution, 8,
Corrosive, UN2672
Standard carrier
shipping label AND
Ammonium
metavanadate, 6.1,
Poison, UN2859
Standard carrier
shipping label AND
Arsenic, 6.1, Poison,
UN1558
Standard carrier
shipping label AND
Aresnic trioxide, 6.1,
Poison, UN1561
Standard carrier
shipping label AND
Arsine, 2.3 (2.1),
Poisonous gas,
UN2190
Standard carrier
shipping label AND
Asbestos, 9, Class 9,
NA2212
6015
(NIOSH)
[SAM Tier I]
10-3.1 / IO-3.4 / 10-
3.5
(EPAORD)
[SAM Tier I]
IO-3.1 / IO-3.4 / IO-
3.5
(EPAORD)
[SAM Tier I]
IO-3.1 / IO-3.4 / IO-
3.5
(EPAORD)
[SAM Tier I]
6001
(NIOSH)
[SAM Tier I]
10312:1995
(ISO)
[SAM Tier I]
Sample Collection Information Document
A1 -2
September 2014
-------
Air Samples
Analyte
Boron trifluoride
Brodifacoum
Bromadiolone
Calcium arsenate
(analyze as total
arsenic)
Carbofuran (Furadan)
Carbon disulfide
Carfentanil
Chlorfenvinphos
Sample
Volume'11
Up to 480 L
Sample Container
Midget glass bubbler
containing 10-mLof
0.1 M NH4F; sample
solution transferred to
20 mL glass vial with
PTFE cap
Holding Time
TBD
Sample Preservation
or Preparation
TBD
Packaging Requirements
Wipe outside of each sorbent tube clean using
a damp, then dry cloth. Cap tubes with plastic
(not rubber) caps immediately after sampling.
Place tubes in double plastic bags and wrap
with bubble wrap. Pack samples as described
in Footnote (4).
Shipping Label'2'
Standard carrier
shipping label AND
Boron trifluoride, 2.3,
Poisonous gas,
UN1008
Source/SAM
Method'3'
ID216SG
(OS HA)
[SAM Tier I]
Not of concern in this sample type
Not of concern in this sample type
Up to 1700m3
240 - 480 L
One to four 1 L
or 6 L samples
(depending on
suspected
concentration)
each in a
separate
canister'6'
Filter (quartz, silica, or
cellulose fiber)
Filter/solid sorbent
tube (OVS-2 tube:
13mm quartz fiber
filter, XAD-2 [270
mg/140 mg])
Specially prepared 1-L
or 6-L stainless steel
canister
For subatmospheric
pressure sampling, the
canister is evacuated
to 0.05 mm Hg; for
pressurized sampling,
the sample is collected
using a pump and flow
control arrangement to
achieve a typical 101 -
202 kPa(15-30psig)
6 months
Stable at least 30
days at negative (-)
12ฐCoratleast7
days at 24ฐC.
Under conditions of
normal use, most
VOCs can be
recovered from
canisters near their
original
concentrations after
storage times of up to
30 days.
None
Store refrigerated and tightly
sealed. Analyze at room
temperature.
None
Place filter in protective covering. Place
protected filter in double plastic bags, and wrap
with bubble wrap. Pack samples as described
in Footnote (4).
Place filter in protective covering. Wipe outside
of each sorbent tube clean using a damp, then
dry cloth. Cap both ends of the tube with
plastic caps. Place protected filter and/or tubes
in double plastic bags, and wrap with bubble
wrap. Pack samples as described in Footnote
(4).
Ship canister in container provided by
laboratory.
Standard carrier
shipping label AND
Calcium arsenate,
6.1, Poison, UN1573
Standard carrier
shipping label AND
Carbamate
pesticides, solid,
toxic, 6.1, UN2757
Standard carrier
shipping label AND
Carbon disulfide, 3,
Flammable liquid,
UN1131
IO-3.1 / IO-3.4 / IO-
3.5
(EPAORD)
[SAM Tier I]
5601
(NIOSH)
[SAM Tier I]
TO-15
(EPAORD)
[SAM Tier I]
Not of concern in this sample type
240 - 7200 L
(flow rate = 1
5 L/min)
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Store at < 4ฐC.
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
TO-10A
(EPAORD)
[SAM Tier II]
Sample Collection Information Document
A1 -3
September 2014
-------
Air Samples
Analyte
Chlorine'51
2-Chloroethanol
3-Chloro-1,2-
propanediol'5'
Chloropicrin'5'
Chlorpyrifos
Chlorpyrifos oxon
Crimidine
Cyanide, Amenable to
chlorination
Cyanide, Total151
Sample
Volume'11
8 L (at 0.1 ppm)
-360L
2 (at 5 ppm) -
35 L (flow rate =
0.01 -0.2
L/min)
240 - 7200 L
(flow rate = 1
5 L/min)
5 L (flow rate =
0.2 L/min)
240 - 7200 L
(flow rate = 1
5 L/min)
240 - 7200 L
(flow rate = 1 -
5 L/min)
Sample Container
Prefilter and filter
(PTFE, 0.5|jmand
silver membrane, 25
mm, 0.45 |jm)
Solid sorbent tube
(petroleum charcoal
[100 mg/50 mg])
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Solid sorbent tube
(XAD-4 [100 mg/50
mg])
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Holding Time
Up to 30 days at
25ฐC.
TBD
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Minimize transport
and storage time. If
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Sample Preservation
or Preparation
Protect from light.
None
Store at<4ฐC.
Room temperature in the
dark.
Store at < 4ฐC.
Store at < 4ฐC.
Packaging Requirements
Place filter in protective covering. Place
protected filter in double plastic bags, and wrap
with bubble wrap. Pack samples as described
in Footnote (4).
Wipe outside of each sorbent tube clean using
a damp, then dry cloth. Cap tubes with plastic
(not rubber) caps. Place tubes in double
plastic bags and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Wipe outside of each sorbent tube clean using
a damp, then dry cloth. Cap tubes with plastic
(not rubber) caps. Place tubes in double
plastic bags and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Shipping Label'2'
Standard carrier
shipping label AND
Chlorine, 2.3,5.1,
Oxidizer, 8, Poison
gas, UN1017
Standard carrier
shipping label
Standard carrier
shipping label
Standard carrier
shipping label AND
Chloropicrin, 6.1,
Poison, UN 1580
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Source/SAM
Method'31
Adapted from
Analyst, 124(12):
1853-1857/4500-
Cl G (SM)
[SAM Tier II]
2513(NIOSH)
[SAM Tier I]
TO-10A
(EPAORD)
[SAM Tier III]
PV2103
(OS HA)
[SAM Tier I]
TO-10A
(EPAORD)
[SAM Tier I]
TO-10A
(EPAORD)
[SAM Tier III]
Not of concern in this sample type
Not of concern in this sample type
2 (at 5 ppm) -
90 L
Solid sorbent tube
(soda lime [600
mg/200 mg])
Stable at least 2
weeks at 25ฐC.
Store at 25ฐC.
Wipe outside of each sorbent tube clean using
a damp, then dry cloth. Cap tubes with plastic
(not rubber) caps. Place tubes in double
plastic bags and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Cyanides, inorganic,
solid, n.o.s, 6.1,
Poison, UN 1588
6010
(NIOSH)
[SAM Tier I]
Sample Collection Information Document
A1 -4
September 2014
-------
Air Samples
Analyte
Cyanogen chloride151
1,2-Dichloroethane
(degradation product of
HD)
Dichlorvos
Dicrotophos
Diesel Range Organics
Sample
Volume'11
One to four 1 L
or 6 L samples
(depending on
suspected
concentration)
each in a
separate
canister'6'
One to four 1 L
or 6 L samples
(depending on
suspected
concentration)
each in a
separate
canister'6'
240 - 7200 L
(flow rate = 1
5 L/min)
240 - 7200 L
(flow rate = 1
5 L/min)
Sample Container
Specially prepared 1 L
or 6 L stainless steel
canister. For
subatmospheric
pressure sampling, the
canister is evacuated
to 0.05 mm Hg; for
pressurized sampling,
the sample is collected
using a pump and flow
control arrangement to
achieve a typical 101 -
202kPa(15-30
psig).
Specially prepared 1 L
or 6 L stainless steel
canister
For subatmospheric
pressure sampling, the
canister is evacuated
to 0.05 mm Hg; for
pressurized sampling,
the sample is collected
using a pump and flow
control arrangement to
achieve a typical 101 -
202 kPa(15-30psig)
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Holding Time
Minimize transport
and storage time. If
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Under conditions of
normal use, most
VOCs can be
recovered from
canisters near their
original
concentrations after
storage times of up to
30 days.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Sample Preservation
or Preparation
None
None
Store at < 4ฐC.
Store at < 4ฐC.
Packaging Requirements
Ship canister in container provided by
laboratory.
Ship canister in container provided by
laboratory.
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Shipping Label'2'
Standard carrier
shipping label AND
Cyanogen chloride,
2.3, Poisonous gas,
UN1589
Standard carrier
shipping label AND
Ethylene dichloride, 6,
Poison, UN1184
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Source/SAM
Method'31
TO-15
(EPAORD)
[SAM Tier III]
TO-15
(EPAORD)
[SAM Tier I]
TO-10A
(EPAORD)
[SAM Tier I]
TO-10A
(EPAORD)
[SAM Tier I]
Not of concern in this sample type
Sample Collection Information Document
A1 -5
September 2014
-------
Air Samples
Analyte
Diisopropyl
methylphosphonate
(DIMP)
(degradation product of
GBf
Dimethylphosphite'51
Dimethyl
phosphoramidic acid
(degradation product of
GAf
Diphacinone
Disulfoton
Disulfoton sulfone oxon
Disulfoton sulfoxide
Sample
Volume'11
240 - 7200 L
(flow rate = 1 -
5 L/min)
240 - 7200 L
(flow rate = 1
5 L/min)
240 - 7200 L
(flow rate = 1
5 L/min)
Sample Container
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Holding Time
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Minimize transport
and storage time. If
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Sample Preservation
or Preparation
Store at<4ฐC.
Store at<4ฐC.
Store at<4ฐC.
Packaging Requirements
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Shipping Label12'
Standard carrier
shipping label
Standard carrier
shipping label AND
Organophosphorus
compound, toxic,
solid, n.o.s, 6.1,
Poison, UN3464
Standard carrier
shipping label AND
Organophosphorus
compound, toxic,
solid, n.o.s, 6.1,
Poison, UN3464
Source/SAM
Method'31
TO-10A
(EPAORD)
[SAM Tier III]
TO-10A
(EPAORD)
[SAM Tier II]
TO-10A
(EPAORD)
[SAM Tier III]
Not of concern in this sample type
12- 240 L
12- 240 L
12-240 L
Filter/solid sorbent
tube (OVS-2 tube: 13
mm quartz filter, XAD-
2, [270mg/140mg])
Filter/solid sorbent
tube (OVS-2 tube: 13
mm quartz filter, XAD-
2, [270mg/140mg])
Filter/solid sorbent
tube (OVS-2 tube: 13
mm quartz filter, XAD-
2, [270mg/140mg])
10 days at 25ฐC or
30 days at 0ฐC.
10 days at 25ฐC or 30
days at 0ฐC.
10 days at 25ฐC or
30 days at 0ฐC.
10 days at 25ฐC or
30 days at 0ฐC.
10 days at 25ฐC or
30 days at 0ฐC.
10 days at 25ฐC or
30 days at 0ฐC.
Place filter in protective covering. Wipe outside
of each sorbent tube clean using a damp, then
dry cloth. Cap both ends of the tube with
plastic caps. Place protected filter and/or tubes
in double plastic bags, and wrap with bubble
wrap. Pack samples as described in Footnote
(4).
Place filter in protective covering. Wipe outside
of each sorbent tube clean using a damp, then
dry cloth. Cap both ends of the tube with
plastic caps. Place protected filter and/or tubes
in double plastic bags, and wrap with bubble
wrap. Pack samples as described in Footnote
(4).
Place filter in protective covering. Wipe outside
of each sorbent tube clean using a damp, then
dry cloth. Cap both ends of the tube with
plastic caps. Place protected filter and/or tubes
in double plastic bags, and wrap with bubble
wrap. Pack samples as described in Footnote
(4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
5600
(NIOSH)
[SAM Tier I]
5600
(NIOSH)
[SAM Tier III]
5600
(NIOSH)
[SAM Tier III]
Sample Collection Information Document
A1 -6
September 2014
-------
Air Samples
Analyte
Disulfoton sulfoxide
oxon
1,4-Dithiane
(degradation product of
HD)
EA2192 [S-2-
(diisopropylamino)
ethyl methyl
phosphonothioic acid]
(hydrolysis product of
VX)<5>
Ethyl
methylphosphonic acid
(EMPA)
(degradation product of
VX)(5>
Ethyldichloroarsine
(ED)'5'
N-Ethyldiethanolamine
(EDEA) (degradation
product of HN-1)(S|
Sample
Volume'11
12- 240 L
Sample Container
Filter/solid sorbent
tube (OVS-2tube: 13
mm quartz filter, XAD-
2, [270mg/140mg])
Holding Time
10 days at 25ฐC or 30
days at 0ฐC.
Sample Preservation
or Preparation
10 days at 25ฐC or
30 days at 0ฐC.
Packaging Requirements
Place filter in protective covering. Wipe outside
of each sorbent tube clean using a damp, then
dry cloth. Cap both ends of the tube with
plastic caps. Place protected filter and/or tubes
in double plastic bags, and wrap with bubble
wrap. Pack samples as described in Footnote
(4).
Shipping Label12'
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Source/SAM
Method'31
5600
(NIOSH)
[SAM Tier III]
Not of concern in this sample type
240 - 7200 L
(flow rate = 1
5 L/min)
240 - 7200 L
(flow rate = 1
5 L/min)
One to four 1 L
or 6 L samples
(depending on
suspected
concentration)
each in a
separate
canister'6'
240 - 7200 L
(flow rate = 1 -
5 L/min)
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Specially prepared 1 L
or 6 L stainless steel
canister
For subatmospheric
pressure sampling, the
canister is evacuated
to 0.05 mm Hg; for
pressurized sampling,
the sample is collected
using a pump and flow
control arrangement to
achieve a typical 101 -
202 kPa(15-30psig)
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Minimize transport
and storage time. If
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Minimize transport
and storage time. If
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Minimize transport
and storage time. If
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Store at<4ฐC.
Store at<4ฐC.
None
Store at < 4ฐC.
TBD<7)
Air-tight container containing activated carbon.
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Ship canister in container provided by
laboratory.
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
TBD(7)
Standard carrier
shipping label AND
Organophosphorus
compound, toxic,
solid, n.o.s, 6.1,
Poison, UN3464
Standard carrier
shipping label AND
Ethyldichloroarsine,
6.1, Poison, UN1892
Standard carrier
shipping label
TO-10A
(EPA ORD)
[SAM Tier III]
TO-10A
(EPA ORD)/
Footnote (8)
[SAM Tier III]
TO-15
(EPA ORD)
[SAM Tier III]
TO-10A
(EPA ORD)
[SAM Tier III]
Sample Collection Information Document
A1 -7
September 2014
-------
Air Samples
Analyte
Ethylene oxide
Fenamiphos'5'
Fentanyl
Fluoride
Fluoroacetamide
Fluoroacetic acid and
fluoroacetate salts
(analyze as
fluoroacetate ion)'5'
2-Fluoroethanol
Sample
Volume'11
One to four 1 L
or 6 L samples
(depending on
suspected
concentration)
each in a
separate
canister'6'
240 - 7200 L
(flow rate = 1
5 L/min)
Sample Container
Specially prepared 1 L
or 6 L stainless steel
canister
For subatmospheric
pressure sampling, the
canister is evacuated
to 0.05 mm Hg; for
pressurized sampling,
the sample is collected
using a pump and flow
control arrangement to
achieve a typical 101 -
202 kPa(15-30psig)
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Holding Time
Under conditions of
normal use, most
VOCs can be
recovered from
canisters near their
original
concentrations after
storage times of up to
30 days.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Sample Preservation
or Preparation
None
Store at<4ฐC.
Packaging Requirements
Ship canister in container provided by
laboratory.
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Shipping Label'2'
Standard carrier
shipping label AND
Ethylene oxide
(concentration
dependent, refer to 40
CFR 172.101 for
more information)
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Source/SAM
Method'3'
TO-15
(EPAORD)
[SAM Tier I]
TO-10A
(EPAORD)
[SAM Tier II]
Not of concern in this sample type
Not of concern in this sample type
TBD
60 ML (300.1)-
480 L (at 1 .5 -
2.0 L/min)
(S301-1)
2 (at 5 ppm) -
35 L (flow rate =
0.01 -0.2
L/min)
TBD
Cellulose ester
membrane filter/
cleaned and rinsed
glass or plastic bottles
Solid sorbent tube
(petroleum charcoal
[100 mg/50 mg])
TBD
Analyze samples
within 7 days.
TBD
TBD
None
None
TBD
Place filter in protective covering. Place
protected filter in double plastic bags, and wrap
with bubble wrap. Pack samples as described
in Footnote (4).
Wipe outside of each sorbent tube clean using
a damp, then dry cloth. Cap tubes with plastic
(not rubber) caps. Place tubes in double
plastic bags and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label
Standard carrier
shipping label AND
Fluoroacetic acid, 6.1 ,
Poison, UN2642
Standard carrier
shipping label
Adapted from
Journal of
Chroma tography
6,876(1): 103-108
[SAM Tier III]
S301-1
(NIOSH)
[SAM Tier III]
2513
(NIOSH)
[SAM Tier III]
Sample Collection Information Document
A1 -8
September 2014
-------
Air Samples
Analyte
Formaldehyde
Gasoline Range
Organics
Hexahydro-1 ,3,5-trinitro-
1,3,5-triazine(RDX)
Hexamethylene
triperoxidediamine
Hydrogen bromide
Hydrogen chloride
Hydrogen cyanide
Hydrogen fluoride
Hydrogen sulfide
Sample
Volume'11
1 L (at 0.25
mg/mVl5 L
(at 2.5 mg/m3)
Sample Container
Dinitrophenylhydrazine
(DNPH)-coated silica
gel cartridge
Holding Time
At least 34 days at
5ฐC.
Sample Preservation
or Preparation
Store at 5ฐC.
Packaging Requirements
Place end caps onto the cartridge and seal
sampler in an envelope. Protect from heat.
Place cartridge in double plastic bags and wrap
with bubble wrap. Ship samples on ice. Pack
samples as described in Footnote (4).
Shipping Label12'
Standard carrier
shipping label AND
Formaldehyde
(concentration
dependent, refer to 40
CFR 172.101 for
more information).
Source/SAM
Method'31
2016
(NIOSH)
[SAM Tier I]
Not of concern in this sample type
Not of concern in this sample type
Not of concern in this sample type
3-100 L
3-100L
2 - 90 L (at 5
ppm)
3-100 L
1 .2 (at 1 0 ppm)
-40 L
Solid sorbent tube
(washed silica gel [400
mg/200 mg] with glass
fiber filter plug)
Solid sorbent tube
(washed silica gel [400
mg/200 mg] with glass
fiber filter plug)
Solid sorbent tube
(soda lime [600
mg/200 mg])
Solid sorbent tube
(washed silica gel [400
mg/200 mg] with glass
fiber filter plug)
Filter and solid sorbent
tube (Zefluor, 0.5 |jm;
coconut shell charcoal
[400 mg/200 mg])
At least 21 days at
25ฐC.
At least 21 days at
25ฐC.
At least 21 days at
25ฐC.
At least 21 days at
25ฐC.
At least 21 days at
25ฐC.
Store at 25ฐC.
Store at 25ฐC.
Store at 25ฐC.
Store at 25ฐC.
Store at 25ฐC.
Wipe outside of each sorbent tube clean using
a damp, then dry cloth. Cap tubes with plastic
(not rubber) caps. Place tubes in double
plastic bags and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Wipe outside of each sorbent tube clean using
a damp, then dry cloth. Cap tubes with plastic
(not rubber) caps. Place tubes in double
plastic bags and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Wipe outside of each sorbent tube clean using
a damp, then dry cloth. Cap tubes with plastic
(not rubber) caps. Place tubes in double
plastic bags and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Wipe outside of each sorbent tube clean using
a damp, then dry cloth. Cap tubes with plastic
(not rubber) caps. Place tubes in double
plastic bags and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Place filter or cleaned sorbent tube in double
plastic bags, and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Hydrogen bromide,
2.3, Poisonous gas,
UN1048
Standard carrier
shipping label AND
Hydrogen chloride,
2.3, Poisonous gas,
UN1050
Standard carrier
shipping label AND
Hydrogen cyanide,
2.3, Poisonous gas,
UN1956
Standard carrier
shipping label AND
Hydrogen fluoride,
2.3, Poisonous gas,
Corrosive, UN1052
Standard carrier
shipping label AND
Hydrogen sulfide, 2.3,
Poisonous gas,
Corrosive, UN1053
7903
(NIOSH)
[SAM Tier I]
7903
(NIOSH)
[SAM Tier I]
6010
(NIOSH)
[SAM Tier I]
7903
(NIOSH)
[SAM Tier I]
6013
(NIOSH)
[SAM Tier I]
Sample Collection Information Document
A1 -9
September 2014
-------
Air Samples
Analyte
Isopropyl
methylphosphonic acid
(IMPA) (degradation
product of GB)'51
Kerosene
Lead arsenate
(analyze as total
arsenic)
Lewisite oxide
(degradation product of
Lewisite)151
(analyze as total
arspnir^
Mercuric chloride
(analyze as total
mercurv)
Mercury, Total
Methamidophos
Methomyl
Sample
Volume'11
240 - 7200 L
(flow rate = 1 -
5 L/min)
Sample Container
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Holding Time
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Sample Preservation
or Preparation
Store at<4ฐC.
Packaging Requirements
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Shipping Label12'
Standard carrier
shipping label AND
Organophosphorus
compound, toxic,
solid, n.o.s, 6.1,
Poison, UN3464
Source/SAM
Method'31
TO-10A
(EPAORD)
[SAM Tier III]
Not of concern in this sample type
Up to 1700m3
Up to 1700m3
Filter (quartz, silica, or
cellulose fiber)
Filter (quartz, silica, or
cellulose fiber)
6 months
6 months
None
None
Place filter in protective covering. Place
protected filter in double plastic bags, and wrap
with bubble wrap. Pack samples as described
in Footnote (4).
Wipe outside of each container clean using a
damp, then dry cloth. Seal the container with
non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Lead arsenate, 6.1,
Poison, UN1617
Standard carrier
shipping label AND
Arsenic compounds,
solid, n.o.s, 6.1,
Poison, UN1557
IO-3.1 / IO-3.4 / Id-
3.5
(EPAORD)
[SAM Tier I]
10-3.1 / IO-3.4 / 10-
3.5
(EPAORD)/
Footnote (8)
[SAM Tier I]
Not of concern in this sample type
For vapor
phase Hg, the
volume of air
sampled is
determined
from the
average of the
flow rate
measurements
and the sample
duration.
Typical flow rate
is 30 L/min for
12-24 hours.
TBD
12-480 L
Sampling pumps
specially designed for
trace-level pollutant
sampling; vapor phase
Hg collected using two
gold traps in series;
the two traps are
attached to a PTFE
filter pack.
250 mL PTFE
centrifuge tube
Filter/solid sorbent
tube (OVS-2 tube:
13mm quartz fiber
filter, XAD-2
[270mg/140mg])
Vapor phase Hg
samples can be
stored up to 1 week
at 4ฐC.
Particle-phase Hg
filters can be stored
indefinitely in a
freezer at negative (-)
40ฐC.
Analyze immediately
or store at negative
(-) 18ฐC.
Stable 30 days at
negative (-) 1 2ฐC or
at least 7 days at
24ฐC.
Store vapor phase Hg
samples at 4ฐC.
Store particle-phase Hg
filters indefinitely at negative
(-) 40ฐC.
TBD
Store refrigerated and tightly
sealed. Analyze at room
temperature.
Wipe the outside of each trap clean, cap both
ends. Place trap in double plastic bags and
wrap with bubble wrap. Pack samples as
described in Footnote (4).
TBD
Place filter in protective covering. Wipe outside
of each sorbent tube clean using a damp, then
dry cloth. Cap both ends of the tube with
plastic caps. Place protected filter and/or
tubes in double plastic bags, and wrap with
bubble wrap. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND
Mercury, 8, Corrosive,
UN 2809
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Carbamate
pesticides, solid,
toxic, 6.1, UN2757
IO-5
(EPAORD)
[SAM Tier I]
Adapted from
Journal of
Chroma tography
A, 1154(1): 3-25
[SAM Tier III]
5601
(NIOSH)
[SAM Tier I]
Sample Collection Information Document
A1 -10
September 2014
-------
Air Samples
Analyte
Methoxyethyl
mercuric acetate
(analyze as total
mercury)151
Methyl acrylonitrile
Methyl fluoroacetate
(analyze as
fluoroacetate ion)151
Methyl hydrazine
Methyl isocyanate
Methyl paraoxon
Sample
Volume'11
For vapor
phase Hg, the
volume of air
sampled is
determined
from the
average of the
flow rate
measurements
and the sample
duration.
Typical flow rate
of 30 L/min for
12-24 hours.
1 20 L (flow rate
= 1 L/min)
Up to 480 L
(flow rate = 1 .5
- 2.0 L/min)
3 (at 0.2 ppm) -
20 L
15 L (flow rate =
0.05 L/min)
240 - 7200 L
(flow rate = 1 -
5 L/min)
Sample Container
Sampling pumps
specially designed for
trace-level pollutant
sampling; vapor phase
Hg collected using two
gold traps in series;
the two traps are
attached to a PTFE
filter pack.
Filter/solid sorbent
tube (OVS-7 tube:
13mm quartz fiber
filter, XAD-7 [270
mg/140 mg])
Cellulose ester
membrane
filter/cleaned and
rinsed glass or plastic
bottles
Bubbler (0.1 M
hydrochloric acid)
Solid sorbent tube
(XAD-7 tubes coated
with 0.03 mg of 1-(2-
pyridyl)piperazine [1-
2PP])
Sorbent cartridge
containing PUFor
PUF in combination
with other solid
sorbent
Holding Time
Vapor phase Hg
samples can be
stored up to 1 week
at 4ฐC.
Particle-phase Hg
filters can be stored
indefinitely in a
freezer at negative (-)
40ฐC.
Stable at least 4 days
at temperatures up to
45ฐC.
Analyze samples
within 7 days.
At least 5 days at
25ฐC.
Can be stored at
room temperature or
refrigerated for up to
18 days.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Sample Preservation
or Preparation
Store vapor phase Hg
samples at 4ฐC.
Store particle-phase Hg
filters indefinitely at negative
(-) 40ฐC.
None
None
Store at 25ฐC.
Store at reduced
temperature out of sunlight
until analysis.
Store at < 4ฐC.
Packaging Requirements
Wipe the outside of each trap clean, cap both
ends. Place trap in double plastic bags and
wrap with bubble wrap. Pack samples as
described in Footnote (4).
Place filter in protective covering. Wipe outside
of each sorbent tube clean using a damp, then
dry cloth. Cap both ends of the tube with
plastic caps. Place protected filter and/or
tubes in double plastic bags, and wrap with
bubble wrap. Pack samples as described in
Footnote (4).
Place filter in protective covering. Place
protected filter in double plastic bags, and wrap
with bubble wrap. Pack samples as described
in Footnote (4).
Wipe outside of each container clean using a
damp, then dry cloth. Seal the container with
non-reactive tape or film. Wrap each glass
container with bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean using a
damp, then dry cloth. Cap ends of tube and
wrap with OSHA seal. Seal the container with
non-reactive tape or film. Wrap each glass
container with bubble wrap. Pack samples as
described in Footnote (4).
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Shipping Label12'
Standard carrier
shipping label AND
Mercury compounds,
solid, n.o.s, 6.1,
Poison, UN2025
Standard carrier
shipping label AND
Methyl acryonitrile,
3.0, Flammable
Liquid, 6.1, Poison,
UN 3079
Standard carrier
shipping label AND
Fluoroacetic acid, 6.1 ,
Poison, UN2642
Standard carrier
shipping label AND
Methyl hydrazine, 6.1 ,
Poison, UN 1244
Standard carrier
shipping label AND
Methyl hydrazine, 6.1 ,
Poison, UN2480
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Source/SAM
Method'31
10-5
(EPAORD)
[SAM Tier 1]
PV2004
(OSHA)
[SAM Tier III]
S301-1
(NIOSH)
[SAM Tier III]
3510
(NIOSH)
[SAM Tier I]
OSHA 54
[SAM Tier I]
TO-10A
(EPAORD)
[SAM Tier III]
Sample Collection Information Document
A1 - 11
September 2014
-------
Air Samples
Analyte
Methyl parathion
Methylamine
N-Methyl
diethanolamine (MDEA)
(degradation product of
HN-2)'5'
Methylphosphonic acid
(MPA)
(degradation product of
VX, GB, & GD)'5'
Mevinphos
Monocrotophos
Nicotine compounds
(analyze as nicotine)
Octahydro-1,3,5,7-
tetranitro-1, 3,5,7-
tetrazocine (HMX)
Osmium tetraoxide
(analyze for total
osmium)151
Sample
Volume'11
240 - 7200 L
(flow rate = 1 -
5 L/min)
1 0 L (flow rate =
0.2 L/min)
240 - 7200 L
(flow rate = 1
5 L/min)
240 - 7200 L
(flow rate = 1
5 L/min)
240 - 7200 L
(at 1 - 5 L/min)
240 - 7200 L
(flow rate = 1 -
5 L/min)
Sample Container
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Solid sorbent tubes
containing XAD-7
resin coated with 10%
NBD chloride (7-
chloro-4-nitrobenzo-2-
oxa-1 ,3-diazole) by
weight
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Holding Time
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
TBD
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Sample Preservation
or Preparation
Store at<4ฐC.
TBD
Store at<4ฐC.
Store at<4ฐC.
Store at < 4ฐC.
Store at < 4ฐC.
Packaging Requirements
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Wipe outside of each container clean using a
damp, then dry cloth. Cap ends of tube and
wrap with OSHA seal. Seal the container with
non-reactive tape or film. Wrap each glass
container with bubble wrap. Pack samples as
described in Footnote (4).
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Shipping Label12'
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND,
Methylamine,
anhydrous, 2.1,
Flammable gas,
UN1061
Standard carrier
shipping label
Standard carrier
shipping label AND
Organophosphorus
compound, toxic,
solid, n.o.s, 6.1,
Poison, UN3464
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Source/SAM
Method'3'
TO-10A
(EPAORD)
[SAM Tier I]
OSHA 40
[SAM Tier I]
TO-10A
(EPAORD)
[SAM Tier III]
TO-10A
(EPAORD)
[SAM Tier III]
TO-10A
(EPAORD)
[SAM Tier II]
TO-10A
(EPAORD)
[SAM Tier III]
Not of concern in this sample type
Not of concern in this sample type
TBD
Filter (quartz, silica or
cellulose fiber)
TBD
TBD
Place filter in protective covering. Place
protected filter in double plastic bags, and wrap
with bubble wrap. Pack samples as described
in Footnote (4).
Standard carrier
shipping label AND
Osmium tetroxide,
6.1, Poison, UN2471
10-3.1 / IO-3.4
(EPAORD)
[SAM Tier II]
Sample Collection Information Document
A1 - 12
September 2014
-------
Air Samples
Analyte
Oxamyl
Paraoxon
Paraquat
Parathion
Pentaerythritol
tetranitrate (PETN)
Phencyclidine151
Phorate
Phorate sulfone
Sample
Volume'11
240 - 480 L
240 - 7200 L
(flow rate = 1
5 L/min)
Sample Container
Filter/solid sorbent
tube (OVS-2 tube:
13mm quartz fiber
filter, XAD-2
[270mg/140mg])
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Holding Time
Stable 30 days at
negative (-) 1 2ฐC or
at least 7 days at
24ฐC.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Sample Preservation
or Preparation
Store refrigerated and tightly
sealed. Analyze at room
temperature.
Store at < 4ฐC.
Packaging Requirements
Place filter in protective covering. Wipe outside
of each sorbent tube clean using a damp, then
dry cloth. Cap both ends of the tube with
plastic caps. Place protected filter and/or
tubes in double plastic bags, and wrap with
bubble wrap. Pack samples as described in
Footnote (4).
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Shipping Label12'
Standard carrier
shipping label AND
Carbamate
pesticides, solid,
toxic, 6.1, UN2757
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Source/SAM
Method'31
5601
(NIOSH)
[SAM Tier I]
TO-10A
(EPAORD)
[SAM Tier III]
Not of concern in this sample type
240 - 7200 L
(flow rate = 1 -
5 L/min)
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Store at < 4ฐC.
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
TO-10A
(EPAORD)
[SAM Tier III]
Not of concern in this sample type
240 - 7200 L
(flow rate = 1 -
5 L/min)
240 - 7200 L
(flow rate = 1 -
5 L/min)
240 - 7200 L
(flow rate = 1
5 L/min)
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Store at<4ฐC.
Store at < 4ฐC.
Store at < 4ฐC.
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Standard carrier
shipping label
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
TO-10A
(EPAORD)
[SAM Tier II]
TO-10A
(EPAORD)
[SAM Tier II]
TO-10A
(EPAORD)
[SAM Tier III]
Sample Collection Information Document
A1 -13
September 2014
-------
Air Samples
Analyte
Phorate sulfone oxon
Phorate sulfoxide
Phorate sulfoxide oxon
Phosgene
Phosphamidon
Phosphine
Phosphorus trichloride
Sample
Volume'11
240-7200 L
(flow rate = 1-5
L/min)
240 - 7200 L
(flow rate = 1 -
5 L/min)
240-7200 L
(flow rate = 1 -5
L/min)
240 L (flow rate
= 1 L/min)
240 - 7200 L
(flow rate = 1
5 L/min)
1 (at 0.3 ppm) -
16L
1 1 (at 0.5 ppm)
-100 L
Sample Container
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
4-mm i.d. x 6-mm o.d.
x 11 -cm long silane-
treated glass tubes
packed with 150
mg/75 mg of
pretreated XAD-2
adsorbent coated with
2-HMP(2-
[hydroxymethyl]
piperidine)
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Sorbent tube (Hg(CN)2
coated silica gel [300
mg/150 mg])
Bubbler (1 5 mLH2O)
Holding Time
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Can be stored at
ambient temperature
for up to 19 days.
Desorbed samples
remain stable for at
least 16 hours.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
7 days at 25ฐC.
TBD
Sample Preservation
or Preparation
Store at<4ฐC.
Store at < 4ฐC.
Store at<4ฐC.
Store at ambient
temperature.
Store at < 4ฐC.
Store at room temperature.
TBD
Packaging Requirements
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Wipe outside of each container clean using a
damp, then dry cloth. Seal the container with
non-reactive tape or film. Wrap each glass
container with bubble wrap. Pack samples as
described in Footnote (4). Air-tight container
containing activated carbon.
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Wipe outside of each sorbent tube clean using
a damp, then dry cloth. Cap tubes with plastic
(not rubber) caps. Place tubes in double
plastic bags and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Wipe outside of each container clean using a
damp, then dry cloth. Seal the container with
non-reactive tape or film. Wrap each glass
container with bubble wrap. Pack samples as
described in Footnote (4). Air-tight container
containing activated carbon.
Shipping Label12'
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Phosgene, 2.3,
Poisonous gas,
UN1076
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Phosphine, 2.3,
Poisonous gas,
UN2199
Standard carrier
shipping label AND
Phosphorus
trichloride, 6.1,
Poison, UN1809
Source/SAM
Method'31
TO-10A
(EPAORD)
[SAM Tier III]
TO-10A
(EPAORD)
[SAM Tier III]
TO-10A
(EPAORD)
[SAM Tier III]
OSHA61 /
Footnote (8)
[SAM Tier I]
TO-10A
(EPAORD)
[SAM Tier II]
6002
(NIOSH)
[SAM Tier I]
6402 (NIOSH)/
Footnote (8)
[SAM Tier I]
Sample Collection Information Document
A1 -14
September 2014
-------
Air Samples
Analyte
Pinacolyl methyl
phosphonic acid
(PMPA) (degradation
product of GD)'51
Propylene oxide151
Sodium arsenite
(analyze as total
arsenic)151
Sodium azide (analyze
as azide ion)
Strychnine
Tetraethyl
pyrophosphate151
(TEPP)
Tetramethylene-
disulfotetramine'5'
(TETS)
Thallium sulfate
(analyze as total
thallium)
Thiodiglycol (TDG)
(degradation product of
HD)'5'
Sample
Volume'11
240 - 7200 L
(flow rate = 1 -
5 L/min)
0.5 (at 100
ppm) - 5 L
Up to 1700m3
5 L (flow rate =
1 L/min)
Sample Container
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Solid sorbent tube
(coconut shell
charcoal [1 00 mg/50
mg])
Filter (quartz, silica, or
cellulose fiber)
Filter/ Sorbent tube
(PVC or quartz filter
with silica coated
sorbent [150 mg/75
mg])
Holding Time
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
TBD
6 months
Analyze samples
stored at room
temperature within 10
days.
Sample Preservation
or Preparation
Store at<4ฐC.
Refrigerate
None
Refrigerate when not in
transit.
Packaging Requirements
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Wipe outside of each sorbent tube clean using
a damp, then dry cloth. Cap tubes with plastic
(not rubber) caps. Place tubes in double
plastic bags and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Place filter in protective covering. Place
protected filter in double plastic bags, and wrap
with bubble wrap. Pack samples as described
in Footnote (4).
TBD
Shipping Label12'
Standard carrier
shipping label AND
Organophosphorus
compound, toxic,
solid, n.o.s, 6.1,
Poison, UN3464
Standard carrier
shipping label AND
Propylene oxide, 3,
Flammable, UN1280.
Standard carrier
shipping label AND
Sodium arsenite,
solid, 6.1, Poison,
UN2027
Standard carrier
shipping label AND
Sodium azide, 6.1,
Poison, UN 1687
Source/SAM
Method'31
TO-10A
(EPAORD)
[SAM Tier III]
1612
(NIOSH)
[SAM Tier I]
IO-3.1 / IO-3.4 / Id-
3.5
(EPAORD)
[SAM Tier I]
ID-211
(OS HA)
[SAM Tier I]
Not of concern in this sample type
240 - 7200 L
(flow rate = 1 -
5 L/min)
240 - 7200 L
(flow rate = 1
5 L/min)
Up to 1700m3
240 - 7200 L
(flow rate = 1 -
5 L/min)
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Filter (quartz, silica, or
cellulose fiber)
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
6 months
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Store at<4ฐC.
Store at < 4ฐC.
None
Store at<4ฐC.
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Place filter in protective covering. Place
protected filter in double plastic bags, and wrap
with bubble wrap. Pack samples as described
in Footnote (4).
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Pesticides, solid,
toxic, n.o.s, 6.1,
Poison, UN2588
Standard carrier
shipping label AND
Thallium compounds
n.o.s, 6.1 , Poison,
UN1707
Standard carrier
shipping label AND
Aviation regulated
solid, n.o.s, UN3335
TO-10A
(EPAORD)
[SAM Tier II]
TO-10A
(EPAORD)
[SAM Tier II]
IO-3.1 / IO-3.4 / IO-
3.5
(EPAORD)
[SAM Tier I]
TO-10A
(EPAORD)
[SAM Tier III]
Sample Collection Information Document
A1 -15
September 2014
-------
Air Samples
Analyte
Thiofanox
1,4-Thioxane
(degradation product of
HD)
Titanium tetrachloride
(analyze as total
Titanium)
Triethanolamine (TEA)
(degradation product of
HN-3)'5'
Trimethyl phosphite'5'
1,3,5-Trinitrobenzene
(1,3,5-TNB)
2,4,6-Trinitrotoluene
(2,4,6-TNT)
Vanadium pentoxide
(analyze as total
vanadium)
White phosphorus
Sample
Volume'11
12- 240 L (flow
rate = 0.1 -1.0
L/min)
Sample Container
Filter/ solid sorbent
tube (OVS-2tube: 13
mm quartz filter, XAD-
2, [270mg/140mg])
Holding Time
TBD
Sample Preservation
or Preparation
Store refrigerated and tightly
sealed. Analyze at room
temperature.
Packaging Requirements
Place filter in protective covering. Wipe outside
of each sorbent tube clean using a damp, then
dry cloth. Cap both ends of the tube with
plastic caps. Place protected filter and/or
tubes in double plastic bags, and wrap with
bubble wrap. Pack samples as described in
Footnote (4).
Shipping Label'2'
Standard carrier
shipping label AND
Carbamate
pesticides, solid,
toxic, 6.1, UN2757
Source/SAM
Method'3'
5601
(NIOSH)
[SAM Tier III]
Not of concern in this sample type
Not of concern in this sample type
240 - 7200 L
(flow rate = 1 -
5 L/min)
240 - 7200 L
(flow rate = 1 -
5 L/min)
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Sorbent cartridge
containing PUF or
PUF in combination
with other solid
sorbent
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Store at<4ฐC.
Store at<4ฐC.
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Remove PUF cartridge from sampler, wrap with
aluminum foil used to store cartridge, and place
in a sealed container. Place container in
double plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote (4).
Standard carrier
shipping label AND
Ethanolamine
solutions, 8,
Corrosive, UN2491
Standard carrier
shipping label AND
Trimethyl phosphite,
3, Flammable,
UN2329
TO-10A
(EPAORD)
[SAM Tier III]
TO-10A
(EPAORD)
[SAM Tier III]
Not of concern in this sample type
Not of concern in this sample type
Up to 1700m3
5 L (at 0.1
mg/m^-lOO L
Filter (quartz, silica, or
cellulose fiber)
Solid sorbent tube
(TenaxGC[100
mg/50 mg])
6 months
7 days at 25ฐC.
None
None
Place filter in protective covering. Place
protected filter in double plastic bags, and wrap
with bubble wrap. Pack samples as described
in Footnote (4).
Wipe outside of each sorbent tube clean using
a damp, then dry cloth. Cap tubes with plastic
(not rubber) caps. Place tubes in double
plastic bags and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Vanadium pentoxide,
6.1, Poison, UN2862
Standard carrier
shipping label AND
Phosphorus, white
(dry or wetted), 4.2,
Spontaneously
combustible, 6.1 ,
Poison, UN 1381
IO-3.1 / IO-3.4 / Id-
3.5
(EPAORD)
[SAM Tier I]
7905
(NIOSH)
[SAM Tier I]
Sample Collection Information Document
A1 -16
September 2014
-------
Aqueous/Liquid Samples
Analyte
Acephate
Acrylamide
Acrylonitrile
Aldicarb (Temik)
Aldicarb sulfone
Aldicarb sulfoxide
Sample
Volume'11
1 -4L
1 -4L
40 -160 ml
25 ml
>25mL
>25mL
Sample Container
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Screw cap vials
equipped with a PTFE-
lined silicone septum
Pre-cleaned amber
glass bottles with
PTFE-lined caps
demonstrated to be
free of interferences
Pre-cleaned amber
glass bottles with
PTFE-lined caps
demonstrated to be
free of interferences.
All samples are
acidified with glacial
acetic acid to pH a 3.8
upon collection.
Pre-cleaned amber
glass bottles with
PTFE-lined caps
demonstrated to be
free of interferences.
All samples are
acidified with glacial
acetic acid to pH a 3.8
upon collection.
Holding Time
Analyze samples
within 7 days of
collection.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Analyze samples
within 14 days of
collection.
Analyze samples
within 14 days of
collection.
Analyze samples
within 14 days of
collection.
Analyze samples
within 14 days of
collection.
Sample Preservation or
Preparation
Store at 4 (ฑ2)ฐC.
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Store samples at ฃ 4ฐC until
analysis. The sample storage
area must be free of organic
solvent vapors and direct or
intense light.
Store between 0ฐC and 6ฐC.
Store between 0ฐC and 6ฐC .
Store between 0ฐC and 6ฐC.
Packaging Requirements
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
The use of the methyl silicone coated
packing is recommended, but not
mandatory.
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label'21
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label AND
Acrylamide solution,
6.1, Poison, UN3426
Standard carrier
shipping label AND
Acrylonitrile, stabilized,
3, Flammable liquid,
6.1, Poison, UN1093
Standard carrier
shipping label AND
Carbamate pesticides,
liquid, toxic, 6.1,
Poison, UN2992
Standard carrier
shipping label AND
Carbamate pesticides,
liquid, toxic, 6.1,
Poison, UN2992
Standard carrier
shipping label AND
Carbamate pesticides,
liquid, toxic, 6.1,
Poison, UN2992
Source/SAM
Method'31
Adapted from
Chromatographia,
63(5/6): 223-237
[SAM Tier II]
Ch.4/8316
(EPASW-846)
[SAM Tier 1 1]
524.2
(EPAOW)
[SAM Tier 1 1]
D7645-10
(ASTM)
[II]
D7645-10
(ASTM)
[SAM Tier 1 1]
D7645-10
(ASTM)
[SAM Tier 1 1]
Sample Collection Information Document
A2-1
September 2014
-------
Aqueous/Liquid Samples
Analyte
Allyl alcohol
4-Aminopyridine
Ammonia
Ammonium
metavanadate
(analyze as total
vanadium)
Arsenic, Total
Arsenic trioxide
(analyze as total
arsenic)
Sample
Volume'11
40 -160 ml
(one to four
VOA vials)
1 -4L
0.5 -2 L
120 -480 ml
120 -480 ml
120 -480 ml
Sample Container
40 ml VOA glass
screw-cap vials with
PTFE septa
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Polyethylene or glass
container
Plastic or glass
(special cleaning
needed)(11)
Plastic or glass
(special cleaning
needed)(11)
Plastic or glass
(special cleaning
needed)(11)
Holding Time
1 4 days
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Analyze within 28
days. Analyze
immediately if not
preserved.
Preserve with acid
within 2 weeks of
collection; can be held
6 months with
acidification. If not
acid preserved,
analyze immediately.
Preserve with acid
within 2 weeks of
collection; can be held
6 months with
acidification. If not
acid preserved,
analyze immediately.
Preserve with acid
within 2 weeks of
collection; can be held
6 months with
acidification. If not
acid preserved,
analyze immediately.
Sample Preservation or
Preparation
Cool to 4ฐC and adjust to pH <
2 with H2SO4, HCI, or solid
NaHSO4. Store samples in
capped vials, with no
headspace in an area free of
solvent fumes. Add sodium
thiosulfate to remove residual
chlorine from treated
wastewater samples.'9'
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Acidify to pH < 2 with H2SO4
and refrigerate.
Acidify to pH < 2 with nitric acid
and store at 4ฐC. If arsenic
species are to be determined,
remove unpreserved aliquot
prior to sample preservation.'12'
Acidify to pH < 2 with nitric acid
and store at 4ฐC. If arsenic
species are to be determined,
remove unpreserved aliquot
prior to sample preservation.'12'
Acidify to pH < 2 with nitric acid
and store at 4ฐC. If arsenic
species are to be determined,
remove unpreserved aliquot
prior to sample preservation.'12'
Packaging Requirements
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label121
Standard carrier
shipping label AND Allyl
alcohol, 3, Flammable
liquid, 6.1, Poison,
UN1098. See Footnote
(10) when bisulfate is
used.
Standard carrier
shipping label AND
Aminopyridines, 6.1,
Poison, UN2671
Standard carrier
shipping label AND (if
greater than 10%
ammonia by volume)
Ammonia solution, 8,
Corrosive, UN2672
Standard carrier
shipping label AND
Ammonium
metavanadate, 6.1,
Poison, UN2859
Standard carrier
shipping label AND
Arsenic, 6.1, Poison,
UN1558
Standard carrier
shipping label AND
Arsenic trioxide, 6.1,
Poison, UN1561
Source/SAM
Method'31
Ch. 4 / 5030C /
8260C
(EPASW-846)
[SAM Tier II]
Ch.4 / 3535A /
8330B
(EPASW-846)
[SAM Tier III]
4500- NH3B/ 4500
NH3G(SM)
[SAM Tier 1]
200.7 / 200.8
(EPA OW)
[SAM Tier 1]
200.7 / 200.8
(EPAOW)
[SAM Tier 1]
200.7 / 200.8
(EPAOW)
[SAM Tier 1]
Sample Collection Information Document
A2-2
September 2014
-------
Aqueous/Liquid Samples
Analyte
Arsine'51
(analyze as total
arsenic in non-air
sample)
Asbestos
Boron trifluoride
Brodifacoum
Bromadiolone151
Calcium arsenate
(analyze as total
arsenic)
Carbofuran (Furadan)
Sample
Volume'11
120 -480 ml
Sample Container
Plastic or glass
(special cleaning
needed)'11'
Holding Time
Minimize transport
and storage time; if
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Sample Preservation or
Preparation
Acidify to pH < 2 with nitric acid
and store at 4ฐC. If arsenic
species are to be determined,
remove unpreserved aliquot
prior to sample preservation.'12'
Packaging Requirements
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label121
Standard carrier
shipping label AND
Arsine, 2.3(2.1),
Poisonous gas,
UN2189
Source/SAM
Method'31
200.7 / 200.8
(EPAOW)
[SAM Tier 1]
Not of concern in this sample type
Not of concern in this sample type
40 ml
40 ml
120 -480 ml
1 -4L
Pre-cleaned amber
glass vials with PTFE-
lined caps
demonstrated
to be free of
interferences
Pre-cleaned amber
glass vials with PTFE-
lined caps
demonstrated
to be free of
interferences
Plastic or glass
(special cleaning
needed)'11'
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Analyze samples
within 14 days of
collection.
Analyze samples
within 14 days of
collection.
Preserve with acid
within 2 weeks of
collection; can be held
6 months with
acidification. If not
acid preserved,
analyze immediately.
Analyze samples
within 14 days of
collection.
Water samples are collected
unpreserved, and stored
between 0ฐC and 6ฐC.
Chlorinated water samples are
dechlorinated with ascorbic
acid; 10 mg of ascorbic acid is
added to each 40 ml vial prior
to water collection.
Water samples are collected
unpreserved, and stored
between 0ฐC and 6ฐC.
Chlorinated water samples are
dechlorinated with ascorbic
acid; 10 mg of ascorbic acid is
added to each 40 ml vial prior
to water collection.
Acidify to pH < 2 with nitric acid
and store at 4ฐC. If arsenic
species are to be determined,
remove unpreserved aliquot
prior to sample preservation.'12'
Store between 0ฐC and 6ฐC.
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Coumarin derivative
pesticides, liquid, toxic,
6.1, Poison, UN3023
Standard carrier
shipping label AND
Coumarin derivative
pesticides, liquid, toxic,
6.1, Poison, UN3023
Standard carrier
shipping label AND
Calcium arsenate, 6.1,
Poison, UN1573
Standard carrier
shipping label AND
Carbamate pesticides,
liquid, toxic, 6.1,
Poison, UN2992
D7644-10
(ASTM)
[SAM Tier 1 1]
D7644-10
(ASTM)
[SAM Tier 1 1]
200.7 / 200.8
(EPAOW)
[SAM Tier I]
D7645-10
(ASTM)
[SAM Tier 1 1]
Sample Collection Information Document
A2-3
September 2014
-------
Aqueous/Liquid Samples
Analyte
Carbon disulfide
Carfentanil
Chlorfenvinphos
Chlorine
2-Chloroethanol
3-Chloro-1,2-
propanediol151
Sample
Volume'11
40 -160 ml
(One to four
VOA vials)
1 -4L
1 -4L
0.5 -2 L
40 -160 ml
(one to four
VOA vials)
5 ml
Sample Container
40 ml VOA glass
screw-cap vials with
PTFE septa
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass bottle
40 ml VOA glass
screw-cap vials with
PTFE septa
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Holding Time
1 4 days
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Analyze immediately.
1 4 days
Samples can be
stored for 0-15 days
as long as the pH is
adjusted to <8.
Sample Preservation or
Preparation
Cool to 4ฐC and adjust to pH <
2 with H2SO4, HCI, or solid
NaHSO4. Store samples in
capped vials, with no
headspace in an area free of
solvent fumes. Add sodium
thiosulfate to remove residual
chlorine from treated
wastewater samples.'9'
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Avoid excessive light and
agitation. Do not store
samples.
Cool to 4ฐC and adjust to pH <
2 with H2SO4, HCI, or solid
NaHSO4. Store samples in
capped vials, with no
headspace in an area free of
solvent fumes. Add sodium
thiosulfate to remove residual
chlorine from treated
wastewater samples.'9'
TBD
Packaging Requirements
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each vial clean using a
damp, then dry cloth. Seal the vial with
non-reactive tape or film. Wrap glass
vials with bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label121
Standard carrier
shipping label AND
Carbon disulfide, 3,
Flammable liquid,
UN1 131. See Footnote
(10) when bisulfate is
used.
Standard carrier
shipping label
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label AND
Chlorine, 2.3, 5.1,
Oxidizer, 8, Poison gas,
UN1017
Standard carrier
shipping label. See
Footnote (10) when
bisulfate is used.
Standard carrier
shipping label
Source/SAM
Method'31
Ch. 4 / 5030C /
8260C
(EPASW-846)
[SAM Tier 1]
Ch. 4 / 3520C /
3535A/8321B
(EPASW-846)
[SAM Tier III]
Ch. 4 / 3520C /
3535A / 8270D
(EPASW-846)
[SAM Tier I]
4500-CI G
(SM)
[SAM Tier I]
Ch. 4 / 5030C /
8260C
(EPASW-846)
[SAM Tier 1 1]
Journal of
Chromatography A
866(2000) 65-77
[SAM Tier 1 1]
Sample Collection Information Document
A2-4
September 2014
-------
Aqueous/Liquid Samples
Analyte
Chloropicrin151
Chlorpyrifos
Chlorpyrifos oxon
Crimidine151
Cyanide, Amenable to
chlorination
Cyanide, Total
Sample
Volume'11
120 -240 ml
40 -160 ml
(One to four
VOA vials)
1 -4L
40 -160 ml
(One to four
VOA vials)
1 -4L
0.5 -2 L
Sample Container
60 ml screw cap glass
vials with PTFE-lined
septum or lid
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Glass or polyethylene
bottle (1 L size)
Glass or polyethylene
bottle
Holding Time
Extract all samples
within 14 days of
collection and analyze
within 14 days
following extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
1 4 days
12 days from
Validated Time of
Sample Receipt
(VTSR).
Sample Preservation or
Preparation
Cool to 4ฐC and store extracts
at < negative (-) 10ฐC until
analysis.
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Add NaOH until pH > 12 at time
of collection; cool to 4ฐC.
Protect from light and cool to 4
(ฑ2)ฐC from time of receipt until
60 days after delivery of a
complete, reconciled data
package. Add 0.6 g of asorbic
acid for each liter of sample
volume.
Packaging Requirements
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack
samples as described in Footnote (4).
(Air-tight container containing activated
carbon)
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label'21
Standard carrier
shipping label AND
Chloropicrin, 6.1,
Poison, UN1580
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label
Standard carrier
shipping label AND
Cyanide solutions n.o.s,
6.1, Poison, UN1935
Standard carrier
shipping label AND
Cyanide solutions n.o.s,
6.1, Poison, UN1580
Source/SAM
Method'31
551.1
(EPAOW)
[SAM Tier I]
Ch.4/ 3511 /
8270D
(EPASW-846)
[SAM Tier 1 1]
Ch.4 / 3520C /
3535A / 8270D
(EPASW-846)
[SAM Tier III]
Ch.4/ 3511 /
8270D
(EPASW-846)
[SAM Tier 1 1]
3135.21
(EPA Regional
Lab)
[SAM Tier 1]
ISM 01. 3 CN
(EPA CLP)
[SAM Tier I]
Sample Collection Information Document
A2-5
September 2014
-------
Aqueous/Liquid Samples
Analyte
Cyanogen chloride151
1,2-Dichloroethane
(degradation product of
HD)
Dichlorvos
Dicrotophos
Diesel Range Organics
Sample
Volume'11
80 -120 ml
Collect in
duplicate or
triplicate in
nominal 40 ml
vials
40 -160 ml
(one to four
VOA vials)
1 -4L
1 -4L
1 -4L
Sample Container
40 ml VOA glass
screw-cap vials with
PTFE septa and
threaded polypyrene
caps
40 ml VOA glass
screw-cap vials with
PTFE septa
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Holding Time
Samples may be
analyzed within 2
weeks. Analyze as
soon as possible after
collection.
1 4 days
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Sample Preservation or
Preparation
Cool to 4ฐC and adjust to pH <
2 with H2SO4, HCI, or solid
NaHSO4. Store samples in
capped vials, with no
headspace in an area free of
solvent fumes. Add sodium
thiosulfate to remove residual
chlorine from treated
wastewater samples.'9'
Cool to 4ฐC and adjust to pH <
2 with H2SO4, HCI, or solid
NaHSO4. Store samples in
capped vials, with no
headspace in an area free of
solvent fumes. Add sodium
thiosulfate to remove residual
chlorine from treated
wastewater samples.'9'
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Packaging Requirements
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack
samples as described in Footnote (4).
(Air-tight container containing activated
carbon)
Wipe outside of each vial clean using a
damp, then dry cloth. Seal the vial with
non-reactive tape or film. Wrap glass vials
with bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label121
Standard carrier
shipping label AND
Cyanogen chloride, 2.3,
Poisonous gas,
UN1589. See Footnote
(10) when bisulfate is
used.
Standard carrier
shipping label AND
Ethylene dichloride. 3,
Flammable liquid, 6,
Poison, UN1184. See
Footnote (10) when
bisulfate is used.
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label
Source/SAM
Method'31
Encyclopedia of
Anal. Chem. 2006
00:10.1002/97804
70027 31 8.a0809
[SAM Tier 1 1]
Ch. 4 / 5030C /
8260C
(EPASW-846)
[SAM Tier I]
Ch. 4/3535A/
8270D
(EPASW-846)
[SAM Tier I]
Ch. 4/3535A/
8270D
(EPASW-846)
[SAM Tier I]
Ch. 4 / 3520C /
3535A/8015C
(EPASW-846)
[SAM Tier I]
Sample Collection Information Document
A2-6
September 2014
-------
Aqueous/Liquid Samples
Analyte
Diisopropyl
methylphosphonate
(DIMP)
(degradation product of
GB)<51
Dimethvlphosphite151
Dimethylphosphor
amidic acid
(degradation product
GA)'5'
Diphacinone
Disulfoton
Disulfoton sulfone oxon
Sample
Volume'11
25 ml
Sample Container
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Holding Time
Analyze samples
within 1 day of
collection.
Sample Preservation or
Preparation
Store between 0ฐC and ฐC.
Packaging Requirements
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label121
Standard carrier
shipping label
Source/SAM
Method'31
D7597-09
(ASTM)
[SAM Tier II]
Not of concern in this sample type
1 -4L
40 ml
1 -4L
1 -4L
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Pre-cleaned amber
glass vials with PTFE-
lined caps
demonstrated
to be free of
interferences
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Analyze samples
within 14 days of
collection.
Extract immediately
after collection and
preservation and
store at 4 C. Analyze
extracts within 30
days.
Extract immediately
after collection and
preservation and
store at 4ฐC. Analyze
extracts within 30
days.
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Water samples are collected
unpreserved, and stored
between 0ฐC and 6ฐC.
Chlorinated
water samples are
dechlorinated with ascorbic
acid; 10 mg of ascorbic acid is
added to each 40 ml vial prior
to water collection.
Cool to 4ฐC. Add sodium
sulfite to remove residual
chlorine from treated
wastewater samples and then
adicify to pH < 2 with 6N HCI.<9)
Cool to 4ฐC. Add sodium
sulfite to remove residual
chlorine from treated
wastewater samples and then
adicify to pH < 2 with 6N HCI.(9)
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, liquid,
n.o.s, 6.1, Poison,
UN3278
Standard carrier
shipping label AND
Coumarin derivative
pesticides, liquid, toxic,
6.1, Poison, UN3023
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Ch. 4/3535A/
832 1B
(EPASW-846)
[SAM Tier III]
D7644-10
(ASTM)
[SAM Tier 1 1]
525.2
(EPAOW)
[SAM Tier 1 1]
525.2
(EPAOW)
[SAM Tier III]
Sample Collection Information Document
A2-7
September 2014
-------
Aqueous/Liquid Samples
Analyte
Disulfoton sulfoxide
Disulfoton sulfoxide
oxon
1,4-Dithiane
(degradation product of
HD)<51
EA2192 [S-2-
(diisopropylamino)
ethylmethylphosphonot
hioic acid]
(hydrolysis product of
VX)'5'
Ethyl
methylphosphonic acid
(EMPA)
(degradation product of
VX)'51
Sample
Volume'11
1 -4L
1 -4L
40 -160 ml
(One to four
VOA vials)
1 -4L
25 ml
Sample Container
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Holding Time
Extract immediately
after collection and
preservation and
store at 4ฐC. Analyze
extracts within 30
days.
Extract immediately
after collection and
preservation and
store at 4ฐC. Analyze
extracts within 30
days.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Minimize transport
and storage time; if
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Analyze samples
within 1 day of
collection.
Sample Preservation or
Preparation
Cool to 4ฐC. Add sodium
sulfite to remove residual
chlorine from treated
wastewater samples and then
adicify to pH < 2 with 6N HCI.(9)
Cool to 4ฐC. Add sodium
sulfite to remove residual
chlorine from treated
wastewater samples and then
adicify to pH < 2 with 6N HCI.(9)
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Store between 0ฐC and 6 ฐC.
Packaging Requirements
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
TBD. Air-tight container containing
activated carbon.
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label'21
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label
TBD'7'
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, liquid,
n.o.s, 6.1, Poison,
UN3278
Source/SAM
Method'31
525.2
(EPAOW)
[SAM Tier II]
525.2
(EPAOW)
[SAM Tier III]
Ch. 4/3535A/
351 1 / 8270D
(EPASW-846)
[SAM Tier 1 1]
Ch. 4/3535A/
832 1B
(EPASW-846)/
Footnote (8)
[SAM Tier III]
D7597-09
(ASTM)
[SAM Tier 1 1]
Sample Collection Information Document
A2-8
September 2014
-------
Aqueous/Liquid Samples
Analyte
Ethyldichloroarsine
(ED)'51
N-Ethyldiethanolamine
(EDEA) (degradation
product of HN-1)'51
Ethylene oxide
Fenamiphos151
Fentanyl
Fluoride
Sample
Volume'11
1 -4L
25 ml
40 -160 ml
(one to four
VOA vials)
1 -4L
1 -4L
40 ml (one
VOA vial)
Sample Container
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
40 ml VOA glass
screw-cap vials with
PTFE septa
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
40 ml VOA vial
Holding Time
Minimize transport
and storage time; if
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Analyze samples
within 7 days of
collection.
1 4 days
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
28 days
Sample Preservation or
Preparation
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Store between 0ฐC and 6ฐC.
Cool to 4ฐC and adjust to pH <
2 with H2SO4, HCI, or solid
NaHSO4. Store samples in
capped vials, with no
headspace in an area free of
solvent fumes. Add sodium
thiosulfate to remove residual
chlorine from treated
wastewater samples.'9'
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
None
Packaging Requirements
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples as
described in Footnote (4).
Shipping Label'21
Standard carrier
shipping label AND
Ethyldichloroarsine, 6.1,
Poison, UN1892
Standard carrier
shipping label
Standard carrier
shipping label AND
Ethylene oxide
(concentration
dependent, refer to 40
CFR 172.101 for more
information). See
Footnote (10) when
bisulfate is used.
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label
Standard carrier
shipping label
Source/SAM
Method'31
Ch. 4/3535A/
8270D
(EPASW-846)
[SAM Tier III]
D7599-09
(ASTM)
[SAM Tier II]
Ch. 4 / 5030C /
8260C
(EPASW-846)
[SAM Tier II]
Ch. 4 / 3520C /
3535A / 8270D
(EPASW-846)
[SAM Tier II]
Ch. 4 / 3520C /
3535A/8321B
(EPASW-846)
[SAM Tier 1 1]
300.1, Rev 1.0
(EPAOW)
[SAM Tier I]
Sample Collection Information Document
A2-9
September 2014
-------
Aqueous/Liquid Samples
Analyte
Fluoroacetamide
Fluoroacetic acid and
fluoroacetate salts
(analyze as
fluoroacetate ion)151
2-Fluoroethanol
Formaldehyde
Gasoline Range
Organics
Hexahydro-1,3,5-trinitro-
1,3,5-triazine(RDX)
Sample
Volume'11
TBD
25 ml
100 -400 ml
100 -400 ml
40 -160 ml
(One to four
VOA vials)
1 -4L
Sample Container
TBD
Pre-cleaned amber
glass bottle with PTFE-
lined caps
demonstrated to be
free of interferences
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
40 ml VOA glass
screw-cap vials with
PTFE septa
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Holding Time
TBD
TBD
1 4 days
Derivatized and
extracted within 3
days of collection.
1 4 days
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Sample Preservation or
Preparation
TBD
TBD
Cool to 4ฐC and adjust to pH <
2 with H2SO4, HCI, or solid
NaHSO4. Store samples in
capped vials, with no
headspace in an area free of
solvent fumes. Add sodium
thiosulfate to remove residual
chlorine from treated
wastewater samples.'9'
Refrigerate at 4ฐC. Preserve to
pH 5.0 to minimize the
formation of artifact
formaldehyde.
Cool to 4ฐC and adjust to pH <
2 with H2SO4, HCI, or solid
NaHSO4. Store samples in
capped vials, with no
headspace in an area free of
solvent fumes. Add sodium
thiosulfate to remove residual
chlorine from treated
wastewater samples.'9'
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Packaging Requirements
TBD
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label'21
Standard carrier
shipping label
Standard carrier
shipping label AND
Fluoroacetic acid, 6.1,
Poison, UN2642
Standard carrier
shipping label
Standard carrier
shipping label AND
Formaldehyde
(concentration
dependent, refer to 40
CFR 172.101 for more
information).
Standard carrier AND
Gasoline identification
set, 2.3, Poison gas,
NA9035 shipping label.
See Footnote (1 0) when
bisulfate is used.
Standard carrier
shipping label AND
RDX, 1.1, Explosive,
UN0483
Source/SAM
Method'31
Adapted from
Journal of
Chromatography B,
876(1): 103-108
[SAM Tier 1 1]
Adapted from J.
Chrom B. 2010
(878)1045-1050
[SAM Tier III]
Ch. 4 / 5030C /
8260C
(SW-846)
[SAM Tier III]
Ch. 4/831 5A
(EPA SW-846)
[SAM Tier I]
Ch. 4 / 5030C /
801 5C
(EPA SW-846)
[SAM Tier I]
Ch. 4/3535A/
8330B
(EPA SW-846)
[SAM Tier I]
Sample Collection Information Document
A2-10
September 2014
-------
Aqueous/Liquid Samples
Analyte
Hexamethylenetriper
oxidediamine (HMTD)'51
Hydrogen bromide
Hydrogen chloride
Hydrogen cyanide15'
Hydrogen fluoride
Hydrogen sulfide
Isopropyl
methylphosphonic acid
(IMPA) (degradation
product of GB)'51
Kerosene151
Lead arsenate
(analyze as total
arsenic)
Lewisite oxide
(degradation product of
Lewisite)'51
(analyze as total
arsenic)
Sample
Volume'11
1 -4L
Sample Container
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Holding Time
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Sample Preservation or
Preparation
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Packaging Requirements
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label'21
Forbidden
Source/SAM
Method'31
Ch. 4/3535A/
8330B
(EPASW-846)/
Analyst (2001)
126:1689-1693
[SAM Tier 1 1]
Not of concern in this sample type
Not of concern in this sample type
Not of concern in this sample type
Not of concern in this sample type
Not of concern in this sample type
25 ml
1 -4L
120 -480 ml
120 -480 ml
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Plastic or glass
(special cleaning
needed)(11)
Plastic or glass
(special cleaning
needed)(11)
Analyze samples
within 1 day of
collection.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Preserve with acid
within 2 weeks of
collection; can be held
6 months with
acidification. If not
acid preserved,
analyze immediately.
Samples should be
preserved with acid
within 2 weeks of
collection, and can be
held 6 months with
acidification. If not
acid preserved,
analyze immediately.
Store between 0ฐC and 6 ฐC.
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Acidify to pH < 2 with nitric acid
and store at 4ฐC. If arsenic
species are to be determined,
remove unpreserved aliquot
prior to sample preservation.'12'
Acidify to pH < 2 with nitric acid
and store at 4ฐC. If arsenic
species are to be determined,
remove unpreserved aliquot
prior to sample preservation.'12'
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, liquid,
n.o.s, 6.1, Poison,
UN3278
Standard carrier
shipping label AND
Kerosene, 3,
Flammable, UN1223.
See Footnote (1 0) when
bisulfate is used.
Standard carrier
shipping label AND
Lead arsenate, 6.1,
Poison, UN1617
Standard carrier
shipping label AND
Arsenic compounds,
liquid, n.o.s, 6.1,
Poison, UN1556
D7597-09
(ASTM)
[SAM Tier 1 1]
Ch. 4 / 5030C /
801 5C
(EPASW-846)
[SAM Tier I]
200.7 / 200.8
(EPAOW)
[SAM Tier I]
200.7 / 200.8
(EPAOW)/
Footnote (8)
[SAM Tier I]
Sample Collection Information Document
A2-11
September 2014
-------
Aqueous/Liquid Samples
Analyte
Mercuric chloride
(analyze as total
mercury)
Mercury, Total
Methamidophos
Methomyl
Methoxyethylmercuric
acetate (analyze for
total mercury)151
Methyl acrylonitrile
Methyl fluoroacetate
(analyze for
fluoroacetate ion)151
Methyl hydrazine151
Methyl isocyanate
Sample
Volume'11
400 ml
400 ml
TBD
25 ml
400 ml
1 -4L
25 ml
1 -4L
Sample Container
PTFE, plastic or glass
PTFE, plastic or glass
TBD
Pre-cleaned amber
glass bottles with
PTFE-lined caps
demonstrated to be
free of interferences
PTFE, plastic or glass
40 ml to 120 ml
screw cap vials each
equipped with a PTFE
faced silicone septum
Pre-cleaned amber
glass bottle with PTFE-
lined caps
demonstrated to be
free of interferences
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Holding Time
28 days
28 days
TBD
Analyze samples
within 14 days of
collection.
28 days
Analyze samples
within 14 days of
collection.
TBD
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Sample Preservation or
Preparation
Acidify to pH < 2 with nitric
acid. [Normally, 3 ml of (1+1)
acid per liter of sample is
sufficient for most ambient
and drinking water samples.]
Acidify to pH < 2 with nitric
acid. [Normally, 3 ml of (1+1)
acid per liter of sample is
sufficient for most ambient
and drinking water samples.]
TBD
Store between 0ฐC and 6ฐC.
Acidify to pH < 2 with nitric
acid. [Normally, 3 ml of (1+1)
acid per liter of sample is
sufficient for most ambient
and drinking water samples.]
Store samples at ฃ 4ฐC until
analysis. The sample storage
area must be free of organic
solvent vapors and direct or
intense light.
TBD
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Packaging Requirements
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
TBD
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the vial with
non-reactive tape or film. Wrap glass
vials with bubble wrap. Pack samples as
described in Footnote (4). The use of the
methyl silicone coated packing is
recommended, but not mandatory.
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label'21
Standard carrier
shipping label AND
Mercuric chloride, 6.1,
Poison, UN1624
Standard carrier
shipping label AND
Mercury, 8, Corrosive,
UN2809
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label AND
Carbamate pesticides,
liquid, toxic, 6.1,
Poison, UN2992
Standard carrier
shipping label AND
Mercury compounds,
liquid, n.o.s, 6.1,
Poison, UN2024
Standard carrier
shipping label AND
Methyl acryonitrile, 3.0,
Flammable Liquid, 6.1,
Poison, UN3079
Standard carrier
shipping label
Standard carrier
shipping label AND
Methyl hydrazine, 6.1,
Poison, UN1244
Source/SAM
Method'31
245.1
(EPAOW)
[SAM Tier I]
245.1
(EPAOW)
[SAM Tier I]
Adapted from
Chromatographia,
63(5/6): 233-237
[SAM Tier 1 1]
D7645-10
(ASTM)
[SAM Tier 1 1]
245.1
(EPAOW)
[SAM Tier I]
524.2
(EPAOW)
[SAM Tier 1 1]
J. Chrom B. 2010
(878)1045-1050
[SAM Tier III]
J. Chrom. 1993
(617), 157-162
[SAM Tier 1 1]
Not of concern in this sample type
Sample Collection Information Document
A2-12
September 2014
-------
Aqueous/Liquid Samples
Analyte
Methyl paraoxon
Methyl parathion
Methylamine
N-
Methyldiethanolamine
(MDEA) (degradation
product of HN-2)'51
Methylphosphonic acid
(MPA)
(degradation product of
VX, GB, & GD)'51
Mevinphos
Sample
Volume'11
1 -4L
1 -4L
Sample Container
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Holding Time
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Sample Preservation or
Preparation
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Packaging Requirements
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label'21
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Source/SAM
Method'31
Ch. 4/3535A/
8270D
(EPASW-846)
[SAM Tier III]
Ch. 4/3535A/
8270D
(EPASW-846)
[SAM Tier 1]
Not of concern in this sample type
25 ml
25 ml
1 -4L
ฃ25 ml pre-cleaned
amber glass bottles
with PTFE-lined caps
demonstrated to be
free of interferences
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Analyze samples
within 7 days of
collection.
Analyze samples
within 1 day of
collection.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Store between 0ฐC and 6ฐC.
Store between 0ฐC and 6ฐC.
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, liquid,
n.o.s, 6.1, Poison,
UN3278
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
D7599-09
(ASTM)
[SAM Tier II]
D7597-09
(ASTM)
[SAM Tier II]
Ch. 4/3535A/
8270D
(EPASW-846)
[SAM Tier 1]
Sample Collection Information Document
A2-13
September 2014
-------
Aqueous/Liquid Samples
Analyte
Monocrotophos
Nicotine compounds
(analyze as nicotine)
Octahydro-1, 3,5,7-
tetranitro-1, 3,5,7-
tetrazocine (HMX)
Osmium tetraoxide
(analyze as total
osmium)151
Oxamyl
Paraoxon
Sample
Volume'11
1 -4L
1 -4L
1 -4L
20 - 80 ml
25 ml
1 -4L
Sample Container
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Glass (special cleaning
needed)(11)
Pre-cleaned amber
glass bottles with
PTFE-lined caps
demonstrated to be
free of interferences
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Holding Time
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Analyze or digest
samples as soon as
possible upon receipt.
Digested samples can
be held up to 6
months prior to
analysis.
Analyze samples
within 14 days of
collection.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Sample Preservation or
Preparation
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Cool to < 6ฐC and store in the
dark. Add sodium thiosulfate to
remove residual chlorine from
wastewater samples.'9'
1% Ammonium hydroxide.'12'
Store between 0ฐC and 6ฐC.
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Packaging Requirements
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label121
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label AND
Nicotine compounds,
liquid, n.o.s, 6.1,
Poison, UN3144
Standard carrier
shipping label
Standard carrier
shipping label AND
Osmium tetroxide, 6.1,
Poison, UN2471
Standard carrier
shipping label AND
Carbamate pesticides,
liquid, toxic, 6.1,
Poison, UN2992
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Source/SAM
Method'31
Ch. 4/3535A/
8270D
(EPASW-846)
[SAM Tier 1]
Ch. 4/3535A/
8270D
(EPASW-846)
[SAM Tier II]
Ch. 4/3535A/
8330B
(EPASW-846)
[SAM Tier 1]
200.7 / 200.8
(EPAOW)
[SAM Tier II]
D7645-10
(ASTM)
[SAM Tier 1 1]
Ch. 4 / 3520C /
3535A / 8270D
(SW-846)
[SAM Tier III]
Sample Collection Information Document
A2-14
September 2014
-------
Aqueous/Liquid Samples
Analyte
Paraquat
Parathion
Pentaerythritol
tetranitrate (PETN)
Phencyclidine
Phorate
Phorate sulfone
Sample
Volume'11
250 -1000 ml
1 -4L
1 -4L
40 -160 ml
(One to four
VOA vials)
1 -4L
1 -4L
Sample Container
Polyvinylchloride
(PVC) high-density or
silanized amber glass
bottle fitted with screw
caps
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Holding Time
Extract samples
within 7 days of
collection; analyze
within 21 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Sample Preservation or
Preparation
Refrigerate at 4ฐC from time of
collection until extraction. Add
100 mg/L sodium thiosulfate to
samples containing residual
chlorine. Keep protected from
light.
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Cool to < 6ฐC and store in the
dark. Add sodium thiosulfate to
remove residual chlorine from
wastewater samples.'9'
Cool to < 6ฐC and store in the
dark. Add sodium thiosulfate to
remove residual chlorine from
wastewater samples.'9'
Cool to < 6ฐC and store in the
dark. Add sodium thiosulfate to
remove residual chlorine from
wastewater samples.'9'
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Packaging Requirements
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label121
Standard carrier
shipping label AND
Bipyridilium pesticides,
liquid, 6.1, Toxic,
UN3016
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Forbidden
Standard carrier
shipping label
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Source/SAM
Method'31
549.2
(EPAOW)
[SAM Tier 1]
Ch. 4 / 3520C /
3535A / 8270D
(SW-846)
[SAM Tier 1]
Ch. 4/3535A/
8330B
(EPA SW-846)
[SAM Tier 1]
351 1 / 8270D
(EPA SW-846)
[SAM Tier 1 1]
Ch. 4/3535A/
8270D
(EPA SW-846)
[SAM Tier I]
Ch. 4/3535A/
8270D
(EPA SW-846)
[SAM Tier III]
Sample Collection Information Document
A2-15
September 2014
-------
Aqueous/Liquid Samples
Analyte
Phorate sulfone oxon
Phorate sulfoxide
Phorate sulfoxide oxon
Phosgene
Phosphamidon
Phosphine
Phosphorus trichloride
Pinacolyl methyl
phosphonic acid
(PMPA) (degradation
product of GD)'51
Sample
Volume'11
1 -4L
1 -4L
1 -4L
Sample Container
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Holding Time
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Sample Preservation or
Preparation
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Packaging Requirements
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label121
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Source/SAM
Method'31
Ch. 4/3535A/
8270D
(EPASW-846)
[SAM Tier III]
Ch. 4/3535A/
8270D
(EPASW-846)
[SAM Tier III]
Ch. 4/3535A/
8270D
(EPASW-846)
[SAM Tier III]
Not of concern in this sample type
1 -4L
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Ch. 4 / 3520C /
3535A / 8270D
(EPASW-846)
[SAM Tier 1]
Not of concern in this sample type
Not of concern in this sample type
25 ml
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Analyze samples
within 1 day of
collection.
Store between 0ฐC and 6ฐC.
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, liquid,
n.o.s, 6.1, Poison,
UN3278
D7597-09
(ASTM)
[SAM Tier II]
Sample Collection Information Document
A2-16
September 2014
-------
Aqueous/Liquid Samples
Analyte
Propylene oxide151
Sodium arsenite
(analyze as total
arsenic)'51
Sodium azide (analyze
as azide ion)
Strychnine
Tetraethyl
pyrophosphate151
(TEPP)
Sample
Volume'11
40 -160 ml
(one to four
VOA vials)
120 -480 ml
40 ml (one
VOA vial)
1 -4L
1 -4L
Sample Container
40 ml VOA glass
screw-cap vials with
PTFE septa
Plastic or glass
(special cleaning
needed)'11'
40 ml VOA vial
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Holding Time
1 4 days
Samples should be
preserved with acid
within 2 weeks of
collection, and can be
held 6 months with
acidification. If not
acid preserved,
analyze immediately.
28 days
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Sample Preservation or
Preparation
Cool to 4ฐC and adjust to pH <
2 with H2SO4, HCI, or solid
NaHSO4. Store samples in
capped vials, with no
headspace in an area free of
solvent fumes. Add sodium
thiosulfate to remove residual
chlorine from treated
wastewater samples.'9'
Acidify to pH < 2 with nitric acid
and store at 4ฐC. If arsenic
species are to be determined,
remove unpreserved aliquot
prior to sample preservation.'12'
None
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Packaging Requirements
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label'21
Standard carrier
shipping label AND
Propylene oxide, 3,
Flammable liquid,
UN1280. See Footnote
(10) when bisulfate is
used.
Standard carrier
shipping label AND
Sodium arsenite,
aqueous solutions, 6.1,
Poison, UN1686
Standard carrier
shipping label AND
Sodium azide, 6.1,
Poison, UN1687
Standard carrier
shipping label AND
Strychnine, 6.1, Poison,
UN1692
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Source/SAM
Method'31
Ch. 4 / 5030C /
8260C
(EPASW-846)
[SAM Tier II]
200.7 / 200.8
(EPAOW)
[SAM Tier 1]
Adapted from J. of
Forensic Sciences,
43(1): 200-202 /
300.1, Rev 1.0
(EPAOW)
[SAM Tier 1 1]
Ch. 4/3535A/
8270D
(EPASW-846)
[SAM Tier I]
Ch. 4/3511 /
8270D
(EPASW-846)
[SAM Tier 1 1]
Sample Collection Information Document
A2-17
September 2014
-------
Aqueous/Liquid Samples
Analyte
Tetramethylene-
disulfotetramine151
(TETS)
Thallium sulfate
(analyze as total
thallium)
Thiodiglycol (TDG)
(degradation product of
HD)<51
Thiofanox
1,4-Thioxane
(degradation product of
HD)'5'
Titanium tetrachloride
(analyze as total
titanium)
Sample
Volume'11
1 -4L
120 -480 ml
1 -4L
>25mL
40 -160 ml
(One to four
VOA vials)
Sample Container
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Plastic or glass
(special cleaning
needed)'11'
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Pre-cleaned amber
glass bottles with
PTFE-lined caps
demonstrated to be
free of interferences.
All samples are
acidified with glacial
acetic acid to pH > 3.8
upon collection.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Holding Time
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Samples should be
preserved with acid
within 2 weeks of
collection, and can be
held 6 months with
acidification. If not
acid preserved,
analyze immediately.
Analyze samples
within 7 days of
collection.
Analyze samples
within 14 days of
collection.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Sample Preservation or
Preparation
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Acidify to pH < 2 with nitric acid
and store at 4ฐC. If arsenic
species are to be determined,
remove unpreserved aliquot
prior to sample preservation.'12'
Store at 4 (ฑ2)ฐC.
Store between 0ฐC and 6ฐC.
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Packaging Requirements
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label121
Standard carrier
shipping label AND
Pesticides, liquid, toxic,
n.o.s, 6.1, Poison,
UN2902
Standard carrier
shipping label AND
Thallium compounds
n.o.s, 6.1, Poison,
UN1707
Standard carrier
shipping label AND
Aviation regulated
liquid, n.o.s, UN3334
Standard carrier
shipping label AND
Carbamate pesticides,
liquid, toxic, 6.1,
Poison, UN2992
Standard carrier
shipping label AND
Flammable Liquids,
n.o.s, 3, Flammable,
UN1993
Source/SAM
Method'31
Ch. 4/3511 /
8270D
(EPASW-846)
[SAM Tier 1 1]
200.7 / 200.8
(EPAOW)
[SAM Tier I]
D7598-09
(ASTM)
[SAM Tier 1 1]
D7645-10
(ASTM)
[SAM Tier 1 1]
[SAM Tier 1 1]
Not of concern in this sample type
Sample Collection Information Document
A2-18
September 2014
-------
Aqueous/Liquid Samples
Analyte
Triethanolamine (TEA)
(degradation product of
HN-3)'51
Trimethyl phosphite151
1 ,3,5-Trin itrobenzene
(1,3,5-TNB)
2,4,6-Trinitrotoluene
(2,4,6-TNT)
Vanadium pentoxide
(analyze as total
vanadium)
White phosphorus
Sample
Volume'11
25 ml
Sample Container
ฃ25 ml pre-cleaned
amber glass bottles
with PTFE-lined caps
demonstrated to be
free of interferences
Holding Time
Analyze samples
within 7 days of
collection.
Sample Preservation or
Preparation
Store between 0ฐC and 6ฐC.
Packaging Requirements
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label121
Standard carrier
shipping label AND
Ethanolamine solutions,
8, Corrosive, UN2491
Source/SAM
Method'31
D7599-09
(ASTM)
[SAM Tier II]
Not of concern in this sample type
1 -4L
1 -4L
120 -480 ml
0.5 -2 L
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined
septa or lids are not
available, solvent-
rinsed aluminum foil
may be used as a
liner.
Plastic or glass
(special cleaning
needed)'11'
Wide-mouth glass or
PTFE container with
PTFE-lined septum or
lid; fill to overflowing to
eliminate headspace
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Extract samples
within 7 days of
collection; analyze
within 40 days of
extraction.
Samples should be
preserved with acid
within 2 weeks of
collection, and can be
held 6 months with
acidification. If not
acid preserved,
analyze immediately.
Extracts with
isooctane should be
analyzed within 30
days.
Cool to < 6ฐC and store in the
dark. Add sodium thiosulfate to
remove residual chlorine from
wastewater samples.'9'
Cool to < 6ฐC and store in the
dark. Add sodium thiosulfate to
remove residual chlorine from
wastewater samples.'9'
Acidify to pH < 2 with nitric acid
and store at 4ฐC. If arsenic
species are to be determined,
remove unpreserved aliquot
prior to sample preservation.'12'
Cool to 4ฐC and store in the
dark.
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Trinitrobenzene and
trinitrotoluene mixtures,
1.1, Explosive, UN0388
Standard carrier
shipping label AND
Trinitrobenzene and
trinitrotoluene mixtures,
1.1, Explosive, UN0388
Standard carrier
shipping label AND
Vanadium pentoxide,
6.1, Poison, UN2862
Standard carrier
shipping label AND
Phosphorus, white (dry
or wetted), 4.2,
Spontaneously
combustible, 6.1,
Poison, UN1381
Ch. 4/3535A/
8330B
(EPASW-846)
[SAM Tier 1]
Ch. 4/3535A/
8330B
(EPASW-846)
[SAM Tier 1]
200.7 / 200.8
(EPAOW)
[SAM Tier 1]
7580
(EPASW-846)
[SAM Tier 1]
Sample Collection Information Document
A2-19
September 2014
-------
Drinking Water Samples
Analyte
Acephate
Acrylamide
Acrylonitrile
Aldicarb (Temik)
Aldicarb sulfone
Sample
Volume'11
40 ml
1 -4L
25 -100 ml
1 -4L
1 -4L
Sample Container
Amber glass bottles (40 ml or
larger) fitted with PTFE-lined
screw caps
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
40-mL to 120-mL screw cap vials
each equipped with a PTFE-lined
silicone septum (Special cleaning
required). (13) Fill sample bottles to
overflowing.
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Holding Time
Analyze samples
within 14 days of
collection.
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
1 4 days
28 days
28 days
Sample Preservation or
Preparation
Add 400 uL of ammonium
acetate concentrated stock and
80 uL of concentrated sodium
omadine stock. Samples must
not exceed 10 ฐC during the first
48 hours after collection. Store
at or below 6 ฐC (but not frozen)
until analysis.
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. <9)
If residual chlorine is present,
add ~25 mg of ascorbic acid per
40 ml of sample to the sample
bottle before filling. Adjust to
pH < 2 at time of collection, but
after dechlorination, with 2
drops of 1:1 HCI for each 40 ml
of sample. Store samples at ฃ
4ฐC until analysis. The sample
storage area must be free of
organic solvent vapors and
direct or intense light.
Preserve with potassium
dihydrogen citrate and sodium
thiosulfate (if residual chlorine is
present)'9'. After collecting the
sample, cap carefully, and
agitate for 1 minute. Store at <
6ฐC and protect from light until
analysis. Do not freeze.
Preserve with potassium
dihydrogen citrate and sodium
thiosulfate (if residual chlorine is
present)'9'. After collecting the
sample, cap carefully, and
agitate for 1 minute. Store at <
6ฐC and protect from light until
analysis. Do not freeze.
Packaging Requirements
Wipe outside of each bottle clean
using a damp, then dry cloth. Seal
the bottle with non-reactive tape or
film. Wrap glass bottles with bubble
wrap. Pack samples as described in
Footnote (4).
Wipe outside of each bottle clean
using a damp, then dry cloth. Seal
the bottle with non-reactive tape or
film. Wrap glass bottles with bubble
wrap. Pack samples as described in
Footnote (4).
Wipe outside of each vial clean
using a damp, then dry cloth. Seal
the vial with non-reactive tape or
film. Wrap glass vials with bubble
wrap. Pack samples as described in
Footnote (4).
Wipe outside of each bottle clean
using a damp, then dry cloth. Seal
the bottle with non-reactive tape or
film. Wrap glass bottles with bubble
wrap. Pack samples as described in
Footnote (4).
Wipe outside of each bottle clean
using a damp, then dry cloth. Seal
the bottle with non-reactive tape or
film. Wrap glass bottles with bubble
wrap. Pack samples as described in
Footnote (4).
Shipping Label'21
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label AND
Acrylamide solution,
6.1, Poison, UN3426
Standard carrier
shipping label AND
Carbon disulfide, 3,
Flammable liquid,
UN1131.See
Footnote (10) when
bisulfate is used.
Standard carrier
shipping label AND
Carbamate
pesticides, liquid,
toxic, 6.1, Poison,
UN2992
Standard carrier
shipping label AND
Carbamate
pesticides, liquid,
toxic, 6.1, Poison,
UN2992
Source/SAM
Method'31
538
(EPA OW)
[SAM Tier 1]
Ch. 4/8316
(EPA SW-846)
[SAM Tier 1 1]
524.2
(EPA OW)
[SAM Tier 1 1]
531.2
(EPA OW)
[SAM Tier I]
531.2
(EPA OW)
[SAM Tier I]
Sample Collection Information Document
A3-1
September 2014
-------
Drinking Water Samples
Analyte
Aldicarb sulfoxide
Allyl alcohol
4-Aminopyridine
Ammonia
Ammonium metavanadate
(analyze as total vanadium)
Sample
Volume'11
1 -4L
40 -160 ml
(one to four
VOA vials)
1 -4L
400-1600
ml
120-480
ml
Sample Container
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
40 ml VOA glass screw-cap vials
with PTFE septa
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Plastic or glass bottles
Plastic or glass (special cleaning
needed)(11)
Holding Time
28 days
1 4 days
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
28 days
Preserve with
acid within 2
weeks of
collection; can
be held 6
months with
acidification. If
not acid
preserved,
analyze
immediately.
Sample Preservation or
Preparation
Preserve with potassium
dihydrogen citrate and sodium
thiosulfate (if residual chlorine is
present)'9'. After collecting the
sample, cap carefully, and
agitate for 1 minute. Store at <
6ฐC and protect from light until
analysis. Do not freeze.
Cool to 4ฐC and adjust to pH < 2
with H2SO4, HCI, or solid
NaHSO4. Store samples in
capped vials, with no
headspace in an area free of
solvent fumes. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples.'9'
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples.'9'
Cool to 4ฐC and adjust to pH < 2
with H2SO4. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples.'9'
Acidify to pH < 2 with nitric acid
and store at 4ฐC. If arsenic
species are to be determined,
remove unpreserved aliquot
prior to sample preservation.'12'
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each vial clean
using a damp, then dry cloth. Seal
the vial with non-reactive tape or
film. Wrap glass vials with bubble
wrap. Pack samples as described in
Footnote (4).
Wipe outside of each bottle clean
using a damp, then dry cloth. Seal
the bottle with non-reactive tape or
film. Wrap glass bottles with bubble
wrap. Pack samples as described in
Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Shipping Label121
Standard carrier
shipping label AND
Carbamate
pesticides, liquid,
toxic, 6.1, Poison,
UN2992
Standard carrier
shipping label AND
Allyl alcohol, 3,
Flammable liquid,
6.1, Poison, UN1098.
See Footnote (1 0)
when bisulfate is
used.
Standard carrier
shipping label AND
Aminopyridines, 6.1,
Poison, UN2671
Standard carrier
shipping label AND (if
greater than 10%
ammonia by volume)
Ammonia solution, 8,
Corrosive, UN2672
Standard carrier
shipping label AND
Ammonium
metavanadate, 6.1,
Poison, UN2859
Source/SAM
Method'31
531.2
(EPA OW)
[SAM Tier I]
Ch. 4/5030C/
8260C
(EPA SW-846)
[SAM Tier 1 1]
Ch. 4/3535A/
8330B
(EPA SW-846)
[SAM Tier 1 1 1]
350.1
(EPA OW)
[SAM Tier I]
200.7/200.8
(EPA OW)
[SAM Tier I]
Sample Collection Information Document
A3-2
September 2014
-------
Drinking Water Samples
Analyte
Arsenic, Total
Arsenic trioxide
(analyze as total arsenic)
Arsine'51
(analyze as total arsenic in
non-air samples)
Asbestos
Boron trifluoride
Brodifacoum
Sample
Volume'11
120-480
ml
120-480
ml
120-480
ml
Sample Container
Plastic or glass (special cleaning
needed)'11'
Plastic or glass (special cleaning
needed)'1 1)
Plastic or glass (special cleaning
needed)'1 1)
Holding Time
Preserve with
acid within 2
weeks of
collection.
Samples can be
held 6 months
with acidification;
if not acid
preserved,
analyze
immediately.
Preserve with
acid within 2
weeks of
collection; can
be held 6
months with
acidification. If
not acid
preserved,
analyze
immediately.
Minimize
transport and
storage time; if
feasible, analyze
or extract
immediately
upon receipt at
the laboratory.
Sample Preservation or
Preparation
Acidify to pH < 2 with nitric acid
and store at 4ฐC. If arsenic
species are to be determined,
remove unpreserved aliquot
prior to sample preservation.'12'
Acidify to pH < 2 with nitric acid
and store at 4ฐC. If arsenic
species are to be determined,
remove unpreserved aliquot
prior to sample preservation.'12'
Acidify to pH < 2 with nitric acid
and store at 4ฐC. If arsenic
species are to be determined,
remove unpreserved aliquot
prior to sample preservation.'12'
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Shipping Label121
Standard carrier
shipping label AND
Arsenic, 6.1, Poison,
UN1558
Standard carrier
shipping label AND
Arsenic trioxide, 6.1,
Poison, UN1561
Standard carrier
shipping label AND
Arsine, 2.3(2.1),
Poisonous gas,
UN2189
Source/SAM
Method'31
200.7/200.8
(EPA OW)
[SAM Tier 1]
200.7/200.8
(EPA OW)
[SAM Tier 1]
200.7/200.8
(EPA OW)
[SAM Tier 1]
Not of concern in this sample type
Not of concern in this sam
40 ml with a
50 ml final
volume
Pre-cleaned amber glass vials
with PTFE-lined caps
demonstrated to be free of
interferences
Analyze the
sample
within 14 days of
collection.
Store in laboratory between 0ฐC
and 6ฐC. Chlorinated drinking
water samples are dechlorinated
with ascorbic acid; 10 mg of
ascorbic acid is added to each
40 ml vial prior to water
collection.
pie type
Wipe outside of each bottle clean
using a damp, then dry cloth. Seal
the bottle with non-reactive tape or
film. Wrap glass bottles with bubble
wrap. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND
Coumarin derivative
pesticides, liquid,
toxic, 6.1, Poison,
UN3023
D7644-10
(ASTM)
[SAM Tier 1 1]
Sample Collection Information Document
A3-3
September 2014
-------
Drinking Water Samples
Analyte
Bromadiolone151
Calcium arsenate
(analyze as total arsenic)
Carbofuran (Furadan)
Carbon disulfide
Carfentanil
Sample
Volume'11
40 ml with a
50 ml final
volume
120-480
ml
25 -100 ml
25 -100 ml
1 -4L
Sample Container
Pre-cleaned amber glass vials
with PTFE-lined caps
demonstrated
to be free of interferences
Plastic or glass (special cleaning
needed)'11'
Amber 40- or 60-mL glass bottles
with PTFE-lined screw caps.
Preservative should be added to
bottle before sample collection.
40 ml to 120 ml screw cap vials
each equipped with a PTFE-lined
silicone septum (Special cleaning
required). <13) Fill sample bottles to
overflowing.
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Holding Time
Analyze the
sample
within 14 days of
collection.
Preserve with
acid within 2
weeks of
collection; can
be held 6
months with
acidification. If
not acid
preserved,
analyze
immediately.
28 days
1 4 days
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Sample Preservation or
Preparation
Store in laboratory between 0ฐC
and 6ฐC. Chlorinated drinking
water samples are dechlorinated
with ascorbic acid; 10 mg of
ascorbic acid is added to each
40 ml vial prior to water
collection.
Acidify to pH < 2 with nitric acid
and store at 4ฐC. If arsenic
species are to be determined,
remove unpreserved aliquot
prior to sample preservation. <12)
Preserve with potassium
dihydrogen citrate and sodium
thiosulfate (if residual chlorine is
present)'9'. After collecting the
sample, cap carefully, and
agitate for 1 minute. Store at <
6ฐC and protect from light until
analysis. Do not freeze.
If residual chlorine is present,
add ~25 mg of ascorbic acid per
40 ml of sample to the sample
bottle before filling. Adjust to
pH < 2 at time of collection, but
after dechlorination, with 2
drops of 1:1 HCI for each 40 ml
of sample. Store samples at ฃ
4ฐC until analysis. The sample
storage area must be free of
organic solvent vapors and
direct or intense light.
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. <9)
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each vial clean
using a damp, then dry cloth. Seal
the vial with non-reactive tape or
film. Wrap glass vials with bubble
wrap. Pack samples as described in
Footnote (4).
Wipe outside of each bottle clean
using a damp, then dry cloth. Seal
the bottle with non-reactive tape or
film. Wrap glass bottles with bubble
wrap. Pack samples as described in
Footnote (4).
Shipping Label121
Standard carrier
shipping label AND
Coumarin derivative
pesticides, liquid,
toxic, 6.1, Poison,
UN3023
Standard carrier
shipping label AND
Calcium arsenate,
6.1, Poison, UN1573
Standard carrier
shipping label AND
Carbamate
pesticides, liquid,
toxic, 6.1, Poison,
UN2992
Standard carrier
shipping label AND
Carbon disulfide, 3,
Flammable liquid,
UN1131.See
Footnote (10) when
bisulfate is used.
Standard carrier
shipping label
Source/SAM
Method'31
D7644-10
(ASTM)
[SAM Tier 1 1]
200.7/200.8
(EPA OW)
[SAM Tier I]
531.2
(EPA OW)
[SAM Tier I]
524.2
(EPA OW)
[SAM Tier I]
Ch. 4/3520C/
3535A/8321B
(EPA SW-846)
[SAM Tier 1 1 1]
Sample Collection Information Document
A3-4
September 2014
-------
Drinking Water Samples
Analyte
Chlorfenvinphos
Chlorine
2-Chloroethanol
3-Chloro-1,2-propanediol|51
Chloropicrin151
Chlorpyrifos
Sample
Volume'11
1 -4L
0.5 -2 L
40 -160 ml
(one to four
VOA vials)
5mL
120-240
ml
40 -160 ml
(One to four
VOA vials)
Sample Container
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Amber glass bottle
40 ml VOA glass screw-cap vials
with PTFE septa
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
60 ml screw cap glass vials with
PTFE-lined septum or lid.
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Holding Time
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Analyze
immediately.
14 days
Samples can be
stored for at
least for 0-1 5
days as long as
the pH is
adjusted to <8
Extract all
samples within
14 days of
collection and
analyze within
1 4 days
following
extraction.
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Sample Preservation or
Preparation
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. <9)
Avoid excessive light and
agitation.
Cool to 4ฐC and adjust to pH < 2
with H2SO4, HCI, or solid
NaHSO4. Store samples in
capped vials, with no
headspace in an area free of
solvent fumes. Add sodium
thiosulfate to remove residual
chlorine from treated
wastewater samples.'9'
TBD
Cool to 4ฐC and store extracts
at < negative (-) 10ฐC until
analysis.
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples.'9'
Packaging Requirements
Wipe outside of each bottle clean
using a damp, then dry cloth. Seal
the bottle with non-reactive tape or
film. Wrap glass bottles with bubble
wrap. Pack samples as described in
Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each vial clean
using a damp, then dry cloth. Seal
the vial with non-reactive tape or
film. Wrap glass vials with bubble
wrap. Pack samples as described in
Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4). (Air-tight
container containing activated
carbon.)
Wipe outside of each bottle clean
using a damp, then dry cloth. Seal
the bottle with non-reactive tape or
film. Wrap glass bottles with bubble
wrap. Pack samples as described in
Footnote (4).
Shipping Label'21
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label AND
Chlorine, 2.3, 5.1,
Oxidizer, 8, Poison
gas, UN1017
Standard carrier
shipping label. See
Footnote (10) when
bisulfate is used.
Standard carrier
shipping label
Standard carrier
shipping label AND
Chloropicrin, 6.1,
Poison, UN1580
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Source/SAM
Method'31
Ch. 4/3520C/
3535A/8270D
(EPA SW-846)
[SAM Tier 1]
4500-CI G
(SM)
[SAM Tierl]
Ch. 4/5030C/
8260C
(EPA SW-846)
[SAM Tier II]
Journal of Chrom. A
866(2000) 65-77
[SAM Tier II]
551.1
(EPA OW)
[SAM Tier I]
3511 /8270D
(EPA SW-846)
[SAM Tier 1 1]
Sample Collection Information Document
A3-5
September 2014
-------
Drinking Water Samples
Analyte
Chlorpyrifos oxon
Crimidine151
Cyanide, Amenable to
chlorination
Cyanide, Total
Cyanogen chloride151
1,2-Dichloroethane
(degradation product of HD)
Sample
Volume'11
1 -4L
40 -160 ml
(One to four
VOA vials)
1 -4L
50 -200 ml
80 -120 ml
Collect in
duplicate or
triplicate in
nominal
40mL vials
25 -100 ml
Sample Container
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Glass or polyethylene bottle (1 L
size)
Plastic or glass
40 ml VOA glass screw-cap vials
with PTFE septa and threaded
polypyrene caps
40 ml to 120 ml screw cap vials
each equipped with a PTFE-lined
silicone septum (special cleaning
required). <13) Fill sample bottles to
overflowing.
Holding Time
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
1 4 days
14 days
Samples may be
analyzed within
2 weeks.
Recommended
to analyze as
soon as possible
after collection.
1 4 days
Sample Preservation or
Preparation
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. <9)
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. <9)
Add NaOH until pH > 12 at time
of collection; cool to 4ฐC.
Adjust to pH a 12 with sodium
hydroxide; cool to 4ฐC at time of
collection. If feasible, analyze
samples immediately upon
receipt at laboratory.
Cool to 4ฐC and adjust to pH < 2
with H2SO4, HCI, or solid
NaHSO4. Store samples in
capped vials, with no
headspace in an area free of
solvent fumes. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. (9)
If residual chlorine is present
add ~25 mg of ascorbic acid per
40 ml of sample to the sample
bottle before filling. Adjust to
pH < 2 at time of collection, but
after dechlorination, with 2
drops of 1:1 HCI for each 40 ml
of sample. Seal the sample
bottle.
Packaging Requirements
Wipe outside of each bottle clean
using a damp, then dry cloth. Seal
the bottle with non-reactive tape or
film. Wrap glass bottles with bubble
wrap. Pack samples as described in
Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each vial clean
using a damp, then dry cloth. Seal
the vial with non-reactive tape or
film. Wrap glass vials with bubble
wrap. Pack samples as described in
Footnote (4). (Air-tight container
containing activated carbon)
Wipe outside of each vial clean
using a damp, then dry cloth. Seal
the vial with non-reactive tape or
film. Wrap glass vials with bubble
wrap. Pack samples as described in
Footnote (4).
Shipping Label121
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label
Standard carrier
shipping label AND
Cyanide solutions
n.o.s, 6.1, Poison,
UN1935
Standard carrier
shipping label AND
Cyanide solutions
n.o.s, 6.1, Poison,
UN1580
Standard carrier
shipping label AND
Cyanogen chloride,
2.3, Poisonous gas,
UN1589. See
Footnote (10) when
bisulfate is used.
Standard carrier
shipping label AND
Ethylene dichloride.
3, Flammable liquid,
6, Poison, UN1184.
See Footnote (1 0)
when bisulfate is
used.
Source/SAM
Method'31
Ch.4 /3520C/
3535A/8270D
(EPA SW-846)
[SAM Tier III]
Ch. 4/3511 /
8270D
(EPA SW-846)
[SAM Tier 1 1]
3135.21
(EPA Regional Lab)
[SAM Tier 1]
335.4
(EPA OW)
[SAM Tier 1]
Encyclopedia of
Anal. Chem. 2006
DOI:10/1002/97804
70027 31 8.a0809
[SAM Tier 1 1]
524.2
(EPA OW)
[SAM Tier I]
Sample Collection Information Document
A3-6
September 2014
-------
Drinking Water Samples
Analyte
Dichlorvos
Dicrotophos
Diesel Range Organics
Diisopropyl
methylphosphonate (DIMP)
(degradation product of
GB)<51
Dimethvlphosphite151
Dimethylphosphoramidic
acid (degradation product of
GA)'5'
Diphacinone
Sample
Volume'11
1 -4L
1 -4L
1 -4L
40 ml
Sample Container
1 Lor 1-quart amber glass bottles
fitted with PTFE-lined screw caps
(amber bottles are preferred)
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Amber glass bottles (40 ml or
larger) fitted with PTFE-lined
screw caps
Holding Time
Extract samples
within 14 days of
collection;
analyze within
30 days of
extraction.
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Analyze samples
within 14 days of
collection.
Sample Preservation or
Preparation
Cool to 4ฐC. Add sodium sulfite
to remove residual chlorine from
treated water samples and then
adicify to pH < 2 with 6N HCI.(9)
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated water
samples.'9'
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples.'9'
Add 400 uL of ammonium
acetate concentrated stock and
80 uL of concentrated sodium
omadine stock. Samples must
not exceed 10 ฐC during the first
48 hours after collection. Store
at or below 6 ฐC (but not frozen)
until analysis.
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Shipping Label'21
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label
Standard carrier
shipping label
Source/SAM
Method'31
525.2
(EPA OW)
[SAM Tier 1]
Ch. 4/3535A/
8270D
(EPA SW-846)
[SAM Tier 1]
Ch. 4/3520C/
3535A/8015C
(EPA SW-846)
[SAM Tier I]
538
(EPA OW)
[SAM Tier I]
Not of concern in this sample type
1 -4L
40 ml with a
50 ml final
volume
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Pre-cleaned amber glass vials
with PTFE-lined caps
demonstrated
to be free of interferences
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Analyze the
sample
within 14 days of
collection.
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples.'9'
Store in laboratory between 0ฐC
and 6ฐC. Chlorinated drinking
water samples are dechlorinated
with ascorbic acid; 10 mg of
ascorbic acid is added to each
40 ml vial prior to water
collection.
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic,
liquid, n.o.s, 6.1,
Poison, UN3278
Standard carrier
shipping label AND
Coumarin derivative
pesticides, liquid,
toxic, 6.1, Poison,
UN3023
Ch. 4/3535A/
8321 B
(EPA SW-846)
[SAM Tier 1 1 1]
D7644-10
(ASTM)
[SAM Tier 1 1]
Sample Collection Information Document
A3-7
September 2014
-------
Drinking Water Samples
Analyte
Disulfoton
Disulfoton sulfone oxon
Disulfoton sulfoxide
Disulfoton sulfoxide oxon
1,4-Dithiane
(degradation product of
HD)'5'
EA2192 [S-2-
(diisopropylamino)ethyl
methylphosphonothioic
acid]
(hydrolysis product of VX)'51
Sample
Volume'11
1 -4L
1 -4L
1 -4L
1 -4L
40 -160 ml
(One to four
VOA vials)
1 -4L
Sample Container
1-L or 1 -quart amber glass bottles
fitted with PTFE-lined screw caps
(amber bottles are preferred)
1-L or 1-quart amber glass bottles
fitted with PTFE-lined screw caps
(amber bottles are preferred)
1-L or 1-quart amber glass bottles
fitted with PTFE-lined screw caps
(amber bottles are preferred)
1-L or 1-quart amber glass bottles
fitted with PTFE-lined screw caps
(amber bottles are preferred)
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Holding Time
Extract samples
within 14 days of
collection;
analyze within
30 days of
extraction.
Extract samples
within 14 days of
collection;
analyze within
30 days of
extraction.
Extract samples
within 14 days of
collection;
analyze within
30 days of
extraction.
Extract samples
within 14 days of
collection;
analyze within
30 days of
extraction.
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Minimize
transport and
storage time; if
feasible, analyze
or extract
immediately
upon receipt at
the laboratory.
Sample Preservation or
Preparation
Cool to 4ฐC. Add sodium sulfite
to remove residual chlorine from
treated water samples and then
adicify to pH < 2 with 6N HCI.(9)
Cool to 4ฐC. Add sodium sulfite
to remove residual chlorine from
treated water samples and then
adicify to pH < 2 with 6N HCI.(9)
Cool to 4ฐC. Add sodium sulfite
to remove residual chlorine from
treated water samples and then
adicify to pH < 2 with 6N HCI.(9)
Cool to 4ฐC. Add sodium sulfite
to remove residual chlorine from
treated water samples and then
adicify to pH < 2 with 6N HCI.(9)
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. <9)
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. <9)
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
TBD(7)
Air-tight container containing
activated carbon
Shipping Label121
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label
TBD(7)
Source/SAM
Method'31
525.2
(EPA OW)
[SAM Tier II]
525.2
(EPA OW)
[SAM Tier III]
525.2
(EPA OW)
[SAM Tier II]
525.2
(EPA OW)
[SAM Tier III]
3511 /8270D
(EPA SW-846)
[SAM Tier 1 1]
Ch. 4/3535A/
8321 B
(EPA SW-846) /
Footnote (8)
[SAM Tier 1 1 1]
Sample Collection Information Document
A3-8
September 2014
-------
Drinking Water Samples
Analyte
Ethyl methyl phosphonic
acid (EMPA)
(degradation product of
VX)'5'
Ethyldichloroarsine (ED)'51
N-Ethyldiethanolamine
(EDEA) (degradation product
of HN-1)'51
Ethylene oxide
Fenamiphos
Sample
Volume'11
25 ml
1 -4L
25 ml
40 -160 ml
(one to four
VOA vials)
1 -4L
Sample Container
Pre-cleaned amber class bottles
with PTFE-lined caps
demonstrated to be free of
interferences.
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
40 ml VOA glass screw-cap vials
with PTFE septa
Amber glass bottles fitted with
PTFE-lined screw caps
Holding Time
Minimize
transport and
storage time; if
feasible, analyze
or extract
immediately
upon receipt at
the laboratory.
TBD. Minimize
transport and
storage time; if
feasible, analyze
or extract
immediately
upon receipt at
the laboratory.
TBD
1 4 days
Extract
immediately;
extracts may be
stored for up to
30 days after
sample
extraction.
Sample Preservation or
Preparation
Store between 0ฐC and 6ฐC.
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. <9)
Store between 0ฐC and 6ฐC.
Cool to 4ฐC and adjust to pH < 2
with H2SO4, HCI, or solid
NaHSO4. Store samples in
capped vials, with no
headspace in an area free of
solvent fumes. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. (9)
Cool to 4ฐC. Add sodium sulfite
to remove residual chlorine from
treated water samples and then
adicify to pH < 2 with 6N HCI.(9)
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4). (Air-tight
container containing activated
carbon)
Wipe outside of each vial clean
using a damp, then dry cloth. Seal
the vial with non-reactive tape or
film. Wrap glass vials with bubble
wrap. Pack samples as described in
Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Shipping Label121
Standard carrier
shipping label AND
Organophosphorus
compound, toxic,
liquid, n.o.s, 6.1,
Poison, UN3278
Standard carrier
shipping label AND
Ethyldichloroarsine,
6.1, Poison, UN1892
Standard carrier
shipping label
Standard carrier
shipping label AND
Ethylene oxide
(concentration
dependent, refer to
40CFR172.101 for
more information).
See Footnote (1 0)
when bisulfate is
used.
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Source/SAM
Method'31
D7597-09
(ASTM)
[SAM Tier III]
Ch. 4/3535A/
8270D
(EPA SW-846)
[SAM Tier III]
D7599-09
(ASTM)
[SAM Tier III]
Ch. 4/5030C/
8260C
(EPA SW-846)
[SAM Tier II]
525.2
(EPA OW)
[SAM Tier 1]
Sample Collection Information Document
A3-9
September 2014
-------
Drinking Water Samples
Analyte
Fentanyl
Fluoride
Fluoroacetamide
Fluoroacetic acid and
fluoroacetate salts (analyze
as fluoroacetate ion)151
2-Fluoroethanol
Formaldehyde
Sample
Volume'11
1 -4L
40 ml (one
VOAvial)
TBD
25 ml
40 -160 ml
(One to four
VOA vials)
30-120
(One to four
30 ml
amber
bottles)
Sample Container
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
40 ml VOA vial
TBD
Pre-cleaned amber glass bottles
with PTFE-lined caps
demonstrated to be free of
interferences
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
30 ml amber glass, screw cap
bottles and caps equipped with
PTFE-faced silicon septa. Screw
caps should be polypropylene.
Holding Time
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
28 days
TBD
TBD
1 4 days
Samples must
be extracted
within 7 days of
sampling.
Extracts must be
analyzed
within 14 days of
extraction.
Sample Preservation or
Preparation
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. <9)
None
TBD
TBD
Cool to 4ฐC and adjust to pH < 2
with H2SO4, HCI, or solid
NaHSO4. Store samples in
capped vials, with no
headspace in an area free of
solvent fumes. Add sodium
thiosulfate to remove residual
chlorine from treated water
samples.'9'
Samples must be iced or
refrigerated at 4 ฑ 2 C and
maintained at these
conditions away from light until
extraction.
Packaging Requirements
Wipe outside of each bottle clean
using a damp, then dry cloth. Seal
the bottle with non-reactive tape or
film. Wrap glass bottles with bubble
wrap. Pack samples as described in
Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
TBD
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Shipping Label'21
Standard carrier
shipping label
Standard carrier
shipping label
Standard carrier
shipping label
Standard carrier
shipping label
Standard carrier
shipping label
Standard carrier
shipping label AND
Formaldehyde
(concentration
dependent, refer to
40CFR172.101 for
more information).
Source/SAM
Method'31
Ch. 4/3520C/
3535A/8321B
(EPA SW-846)
[SAM Tier 1 1]
300.1, Rev 1.0
(EPA OW)
[SAM Tier I]
Adapted from
Journal of
Chromatography B,
876(1):103-108
[SAM Tier 1 1]
Journal of
Chromatography B.
2010,878:1045-
1050
[SAM Tier 1 1 1]
Ch. 4/5030C/
8260C
(EPA SW-846)
[SAM Tier 1 1 1]
556.1
(EPA OW)
[SAM Tier I]
Sample Collection Information Document
A3-10
September 2014
-------
Drinking Water Samples
Analyte
Gasoline Range Organics
Hexahydro-1,3,5-trinitro-1,3,5
triazine (RDX)
Hexamethylenetriperoxide-
diamine (HMTD)'51
Hydrogen bromide
Hydrogen chloride
Hydrogen cyanide15'
Hydrogen fluoride
Hydrogen sulfide
Isopropyl methylphosphonic
acid (IMPA) (degradation
product of GB)'51
Kerosene151
Sample
Volume'11
40 -160 ml
(One to four
VOA vials)
1 -4L
1 -4L
Sample Container
40 ml VOA glass screw-cap vials
with PTFE septa
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Holding Time
1 4 days
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Sample Preservation or
Preparation
Cool to 4ฐC and adjust to pH < 2
with H2SO4, HCI, or solid
NaHSO4. Store samples in
capped vials, with no
headspace in an area free of
solvent fumes. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. (9)
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. (9)
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. <9)
Packaging Requirements
Wipe outside of each vial clean
using a damp, then dry cloth. Seal
the vial with non-reactive tape or
film. Wrap glass vials with bubble
wrap. Pack samples as described in
Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Shipping Label121
Standard carrier AND
Gasoline
identification set, 2.3,
Poison gas, NA9035.
See Footnote (1 0)
when bisulfate is
used.
Standard carrier
shipping label AND
RDX, 1.1, Explosive,
UN0483
Forbidden
Source/SAM
Method'31
Ch. 4/5030C/
801 5C
(EPA SW-846)
[SAM Tier I]
Ch. 4/3535A/
8330B
(EPA SW-846)
[SAM Tier I]
Ch. 4/3535A/
8330B
(EPA SW-846) /
Analyst (2001)
126:1689-1693
[SAM Tier 1 1]
Not of concern in this sample type
Not of concern in this sample type
Not of concern in this sample type
Not of concern in this sample type
Not of concern in this sam
1 -4L
1 -4L
Pre-cleaned amber glass bottles
with PTFE-lined caps
demonstrated to be free of
interferences
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Minimize
transport and
storage time; if
feasible, analyze
or extract
immediately
upon receipt at
the laboratory.
1 4 days
Store between 0ฐC and 6ฐC.
Cool to 4ฐC and adjust to pH < 2
with H2SO4, HCI, or solid
NaHSO4. Store samples in
capped vials, with no
headspace in an area free of
solvent fumes. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. (9)
pie type
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each vial clean
using a damp, then dry cloth. Seal
the vial with non-reactive tape or
film. Wrap glass vials with bubble
wrap. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic,
liquid, n.o.s, 6.1,
Poison, UN3278
Standard carrier
shipping label AND
Kerosene, 3,
Flammable, UN1223.
See Footnote (1 0)
when bisulfate is
used.
D7597-09
[SAM Tier 1 1 1]
Ch. 4/5030C/
801 5C
(EPA SW-846)
[SAM Tier I]
Sample Collection Information Document
A3-11
September 2014
-------
Drinking Water Samples
Analyte
Lead arsenate
(analyze as total arsenic)
Lewisite oxide
(degradation product of
Lewisite)'51
(analyze as total arsenic)
Mercuric chloride (analyze
as total mercury)
Mercury, Total
Methamidophos
Sample
Volume'11
120-480
ml
120-480
ml
100-400
ml
100-400
ml
40 ml
Sample Container
Plastic or glass (special cleaning
needed)'11'
Plastic or glass (special cleaning
needed)'1 1)
BOD bottle or ground glass
stoppered flask
BOD bottle or ground glass
stoppered flask
Amber glass bottles (40 ml or
larger) fitted with PTFE-lined
screw caps
Holding Time
Preserve with
acid within 2
weeks of
collection; can
be held 6
months with
acidification. If
not acid
preserved,
analyze
immediately.
Preserve with
acid within 2
weeks of
collection.
Samples can be
held 6 months
with acidification;
if not acid
preserved,
analyze
immediately.
28 days
28 days
Analyze samples
within 14 days of
collection.
Sample Preservation or
Preparation
Acidify to pH < 2 with nitric acid
and store at 4ฐC. If arsenic
species are to be determined,
remove unpreserved aliquot
prior to sample preservation.'12'
Acidify to pH < 2 with nitric acid
and store at 4ฐC. If arsenic
species are to be determined,
remove unpreserved aliquot
prior to sample preservation.'12'
Preserve samples to pH < 2
with nitric acid upon collection
and hold for 16 hours before
analyzing. If dissolved mercury
is to be determined, filter the
sample prior to preservation.'12'
Preserve samples to pH < 2
with nitric acid upon collection
and hold for 16 hours before
analyzing. If dissolved mercury
is to be determined, filter the
sample prior to preservation.'12'
Add 400 uL of ammonium
acetate concentrated stock and
80 uL of concentrated sodium
omadine stock. Samples must
not exceed 10 ฐC during the first
48 hours after collection. Store
at or below 6 ฐC (but not frozen)
until analysis.
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each bottle clean
using a damp, then dry cloth. Seal
the bottle with non-reactive tape or
film. Wrap glass bottles with bubble
wrap. Pack samples as described in
Footnote (4).
Shipping Label'21
Standard carrier
shipping label AND
Lead arsenate, 6.1,
Poison, UN1617
Standard carrier
shipping label AND
Arsenic compounds,
liquid, n.o.s, 6.1,
Poison, UN1556
Standard carrier
shipping label AND
Mercuric chloride,
6.1, Poison, UN1624
Standard carrier
shipping label AND
Mercury, 8,
Corrosive, UN2809
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Source/SAM
Method'31
200.7/200.8
(EPA OW)
[SAM Tier 1]
200.7/200.8
(EPA OW) /
Footnote (8)
[SAM Tier 1]
245.1
(EPA OW) / 40 CFR
136.3
[SAM Tier I]
245.1
(EPA OW) /
40 CFR 136.3
[SAM Tier I]
538
(EPA OW)
[SAM Tier I]
Sample Collection Information Document
A3-12
September 2014
-------
Drinking Water Samples
Analyte
Methomyl
Methoxyethylmercuric
acetate (analyze as total
mercury)151
Methyl acrylonitrile
Methyl fluoroacetate
(analyze as fluoroacetate
ion)'51
Methyl hydrazine151
Methyl isocyanate
Methyl paraoxon
Sample
Volume'11
25 -100 ml
100-400
ml
25 -100 ml
25mL
1 -4L
Sample Container
Amber 40- or 60-mL glass bottles
with PTFE-lined screw caps.
Preservative should be added to
bottle before sample collection.
PTFE or glass
Amber glass or PTFE container
with PTFE-lined septum or lid.
40-mL to 120-mL screw cap vials
each equipped with a PTFE-lined
silicone septum (special cleaning
required).'13' FiN samp|e bottles
to overflowing.
Pre-cleaned amber glass bottles
with PTFE-lined caps
demonstrated to be free of
interferences
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Holding Time
28 days
28 days
1 4 days
TBD
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Sample Preservation or
Preparation
Preserve with potassium
dihydrogen citrate and sodium
thiosulfate (if residual chlorine is
present)'9'. After collecting the
sample, cap carefully, and
agitate for 1 minute. Store at <
6ฐC and protect from light until
analysis. Do not freeze.
Preserve samples to pH < 2
with nitric acid upon collection.
If mercury species are to be
determined, remove a sample
aliquot prior to preservation.'12'
If residual chlorine is present
add ~25 mg of ascorbic acid per
40 ml of sample to the sample
bottle before filling. Adjust to
pH < 2 at time of collection, but
after dechlorination, with 2
drops of 1:1 HCI for each 40 ml
of sample. Seal the sample
bottle.
TBD
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples.'9'
Not of concern in this sam
1 -4L
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples.'9'
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each vial clean
using a damp, then dry cloth. Seal
the vial with non-reactive tape or
film. Wrap glass vials with bubble
wrap. Pack samples as described in
Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Shipping Label'21
Standard carrier
shipping label AND
Carbamate
pesticides, liquid,
toxic, 6.1, Poison,
UN2992
Standard carrier
shipping label AND
Mercury compounds,
liquid, n.o.s, 6.1,
Poison, UN2024
Standard carrier
shipping label AND
Ethylene dichloride.
3, Flammable liquid,
6, Poison, UN1184.
See Footnote (1 0)
when bisulfate is
used.
Standard carrier
shipping label
Standard carrier
shipping label AND
Methyl hydrazine,
6.1, Poison, UN1244
Source/SAM
Method'31
531.2
(EPA OW)
[SAM Tier I]
245.1
(EPA OW) /
40CFR 136.3
[SAM Tier I]
524.2
(EPA OW)
[SAM Tier 1 1]
Journal of
Chromatography B,
2010.878:1045-
1050
[SAM Tier 1 1 1]
J. Chrom. 1993
(617), 157-162
[SAM Tier 1 1]
pie type
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Ch. 4/3535A/
8270D
(EPA SW-846)
[SAM Tier 1 1 1]
Sample Collection Information Document
A3-13
September 2014
-------
Drinking Water Samples
Analyte
Methyl parathion
Methylamine
N-Methyldiethanolamine
(MDEA) (degradation
product of HN-2)'51
Methylphosphonic acid
(MPA)
(degradation product of VX,
GB, & GD)'51
Mevinphos
Monocrotophos
Nicotine compounds
(analyze as nicotine)
Sample
Volume'11
1 -4L
Sample Container
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Holding Time
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Sample Preservation or
Preparation
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. <9)
Not of concern in this sam
25 ml
25 ml
1 -4L
1 -4L
1 -4L
Pre-cleaned amber glass bottles
with PTFE-lined caps
demonstrated to be free on
interferences
Pre-cleaned amber glass bottles
with PTFE-lined caps
demonstrated to be free on
interferences
Amber glass bottles fitted with
PTFE-lined screw caps
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
TBD. Extract
samples within 7
days of
collection;
analyze within
40 days of
extraction.
TBD. Extract
samples within 7
days of
collection;
analyze within
40 days of
extraction.
Extract samples
within 14 days of
collection;
analyze within
30 days of
extraction.
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Store between 0ฐC and 6ฐC.
Store between 0ฐC and 6ฐC.
Cool to 4ฐC. Add sodium sulfite
to remove residual chlorine from
treated water samples and then
adicify to pH < 2 with 6N HCI.(9)
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. <9)
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. <9)
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Shipping Label121
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Source/SAM
Method'31
Ch. 4/3535A/
8270D
(EPA SW-846)
[SAM Tier 1]
pie type
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label
Standard carrier
shipping label AND
Organophosphorus
compound, toxic,
liquid, n.o.s, 6.1,
Poison, UN3278
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label AND
Nicotine compounds,
liquid, n.o.s, 6.1,
Poison, UN3144
D7597-09
(ASTM)
[SAM Tier III]
D7597-09
(ASTM)
[SAM Tier III]
525.2
(EPA OW)
[SAM Tier 1]
Ch. 4/3535A/
8270D
(EPA SW-846)
[SAM Tier 1]
Ch. 4/3535A/
8270D
(EPA SW-846)
[SAM Tier II]
Sample Collection Information Document
A3-14
September 2014
-------
Drinking Water Samples
Analyte
Octahydro-1,3,5,7-tetranitro-
1,3,5,7-tetrazocine(HMX)
Osmium tetraoxide (analyze
as total osmium)151
Oxamyl
Paraoxon
Paraquat
Parathion
Sample
Volume'11
1 -4L
1 -4L
25 -100 ml
1 -4L
1 -4L
1 -4L
Sample Container
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Glass (special cleaning
needed)(11)
Amber 40- or 60-mL glass bottles
with PTFE-lined screw caps.
Preservative should be added to
bottle before sample collection.
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
High density PVC or silanized
amber glass bottle (1-L) fitted
with screw cap.
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Holding Time
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Analyze or
digest samples
as soon as
possible upon
receipt. Digested
samples can be
held up to 6
months prior to
analysis.
28 days
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Extract samples
within 7 days of
collection;
analyze within
21 days of
extraction.
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Sample Preservation or
Preparation
Cool to < 6ฐC and store in the
dark. Add sodium thiosulfate to
remove residual chlorine from
treated drinking water
samples. (9)
1% Ammonium hydroxide. <12)
Preserve with potassium
dihydrogen citrate and sodium
thiosulfate (if residual chlorine is
present)'9'. After collecting the
sample, cap carefully, and
agitate for 1 minute. Store at <
6ฐC and protect from light until
analysis. Do not freeze.
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Refrigerate at 4ฐC from time of
collection until extraction. Add
100 mg/L sodium thiosulfate to
samples containing residual
chlorine. Keep protected from
light.
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each bottle clean
using a damp, then dry cloth. Seal
the bottle with non-reactive tape or
film. Wrap glass bottles with bubble
wrap. Pack samples as described in
Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each bottle clean
using a damp, then dry cloth. Seal
the bottle with non-reactive tape or
film. Wrap glass bottles with bubble
wrap. Pack samples as described in
Footnote (4).
Shipping Label'21
Standard carrier
shipping label
Standard carrier
shipping label AND
Osmium tetroxide,
6.1, Poison, UN2471
Standard carrier
shipping label AND
Carbamate
pesticides, liquid,
toxic, 6.1, Poison,
UN2992
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label AND
Bipyridilium
pesticides, liquid, 6.1,
Toxic, UN3016
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Source/SAM
Method'31
Ch. 4/3535A/
8330B
(EPA SW-846)
[SAM Tier 1]
200.7/200.8 (EPA
OW)
[SAM Tier II]
531.2
(EPA OW)
[SAM Tier I]
Ch. 4/3520C/
3535A/8270D
(EPA SW-846)
[SAM Tier 1 1 1]
549.2
(EPA OW)
[SAM Tier I]
Ch. 4/3520C/
3535A/8270D
(EPA SW-846)
[SAM Tier I]
Sample Collection Information Document
A3-15
September 2014
-------
Drinking Water Samples
Analyte
Pentaerythritol tetranitrate
(PETN)
Phencyclidine
Phorate
Phorate sulfone
Phorate sulfone oxon
Phorate sulfoxide
Sample
Volume'11
1 -4L
40 -160 ml
(One to four
VOA vials)
1 -4L
1 -4L
1 -4L
1 -4L
Sample Container
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Holding Time
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Sample Preservation or
Preparation
Cool to < 6ฐC and store in the
dark. Add sodium thiosulfate to
remove residual chlorine from
treated drinking water
samples. (9)
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. <9)
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. <9)
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. <9)
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. (9)
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. <9)
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Shipping Label121
Forbidden
Standard carrier
shipping label
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Source/SAM
Method'31
Ch. 4/3535A/
8330B
(EPA SW-846)
[SAM Tier 1]
3511 /8270D
(EPA SW-846)
[SAM Tier 1 1]
Ch. 4/3535A/
8270D
(EPA SW-846)
[SAM Tier I]
Ch. 4/3535A/
8270D
(EPA SW-846)
[SAM Tier 1 1 1]
Ch. 4/3535A/
8270D
(EPA SW-846)
[SAM Tier 1 1 1]
Ch. 4/3535A/
8270D
(EPA SW-846)
[SAM Tier 1 1 1]
Sample Collection Information Document
A3-16
September 2014
-------
Drinking Water Samples
Analyte
Phorate sulfoxide oxon
Phosgene
Phosphamidon
Phosphine
Phosphorus trichloride
Pinacolyl methyl phosphonic
acid (PMPA) (degradation
product of GD)'51
Propylene oxide151
Sodium arsenite (analyze as
total arsenic)'51
Sample
Volume'11
1 -4L
Sample Container
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Holding Time
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Sample Preservation or
Preparation
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. <9)
Not of concern in this sam
1 -4L
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from wastewater
samples.'9'
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Shipping Label'21
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Source/SAM
Method'31
Ch. 4/3535A/
8270D
(EPA SW-846)
[SAM Tier III]
pie type
Wipe outside of each bottle clean
using a damp, then dry cloth. Seal
the bottle with non-reactive tape or
film. Wrap glass bottles with bubble
wrap. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Ch. 4/3520C/
3535A/8270D
(EPA SW-846)
[SAM Tier 1]
Not of concern in this sample type
Not of concern in this sam
25 ml
40 -160 ml
(One to four
VOA vials)
120-480
ml
Pre-cleaned amber glass bottles
with PTFE-lined caps
demonstrated to be free of
interferences
40 ml VOA glass screw-cap vials
with PTFE septa
Plastic or glass (special cleaning
needed)'11'
TBD. Minimize
transport and
storage time; if
feasible, analyze
or extract
immediately
upon receipt at
the laboratory.
1 4 days
Preserve with acid
within 2 weeks of
collection.
Samples can be
held 6 months
if not acid
preserved,
analyze
immediately.
Store between 0ฐC and 6ฐC.
Cool to 4ฐC and adjust to pH < 2
with H2SO4, HCI, or solid
NaHSO4. Store samples in
capped vials, with no
headspace in an area free of
solvent fumes. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples.'9'
Acidify to pH < 2 with nitric acid
and store at 4ฐC. If arsenic
species are to be determined,
remove unpreserved aliquot
prior to sample preservation.'12'
pie type
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each vial clean
using a damp, then dry cloth. Seal
the vial with non-reactive tape or
film. Wrap glass vials with bubble
wrap. Pack samples as described in
Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic,
liquid, n.o.s, 6.1,
Poison, UN3278
Standard carrier
shipping label AND
Propylene oxide, 3,
Flammable liquid,
UN1280. See
Footnote (10) when
bisulfate is used.
Standard carrier
shipping label AND
Sodium arsenite,
aqueous solutions,
6.1, Poison, UN1686
D7597-09
(ASTM)
[SAM Tier III]
Ch. 4/5030C/
8260C
(EPA SW-846)
[SAM Tier II]
200.7/200.8
(EPA OW)
[SAM Tier 1]
Sample Collection Information Document
A3-17
September 2014
-------
Drinking Water Samples
Analyte
Sodium azide (analyze as
azide ion)
Strychnine
Tetraethyl pyrophosphate151
(TEPP)
Tetramethylene-
disulfotetramine151
(TETS)
Thallium sulfate (analyze as
total thallium)
Sample
Volume'11
40 ml (one
VOAvial)
1 -4L
40 -160 ml
(One to four
VOA vials)
50 -200 ml
120-480
ml
Sample Container
40 ml VOA vial
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
50 ml polypropylene vessel fitted
with a flat-top polyethylene screw-
cap
Plastic or glass (special cleaning
needed)'11'
Holding Time
28 days
Extract samples
within 7 days
and analyze
extracts within
40 days of
extraction.
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
28 days
Samples should
be preserved
with acid within 2
weeks of
collection, and
can be held 6
months with
acidification. If
not acid
preserved,
analyze
immediately.
Sample Preservation or
Preparation
None
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. (9)
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. <9)
Cool to 4ฐC. Add preservatives
descrived in Table 9-2 of the
method.
Acidify to pH < 2 with nitric acid
and store at 4ฐC. If arsenic
species are to be determined,
remove unpreserved aliquot
prior to sample preservation. <12)
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Shipping Label121
Standard carrier
shipping label AND
Sodium azide, 6.1,
Poison, UN1687
Standard carrier
shipping label AND
Strychnine, 6.1,
Poison, UN1692
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
Standard carrier
shipping label AND
Pesticides, liquid,
toxic, n.o.s, 6.1,
Poison, UN2902
Standard carrier
shipping label AND
Thallium compounds
n.o.s, 6.1, Poison,
UN1707
Source/SAM
Method'31
Adapted from J. of
Forensic Sciences,
43(1): 200-202 /
300.1, Rev 1.0
(EPA OW)
[SAM Tier 1 1]
Ch. 4/3535A/
8270D
(EPA SW-846)
[SAM Tier I]
3511 /8270D
(EPA SW-846)
[SAM Tier 1 1]
EPA 600/R-1 1/091
(EPA/CDC)
[SAM Tier 1 1]
200.7/200.8
(EPA OW)
[SAM Tier I]
Sample Collection Information Document
A3-18
September 2014
-------
Drinking Water Samples
Analyte
Thiodiglycol (TDG)
(degradation product of
HD)<51
Thiofanox
1,4-Thioxane
(degradation product of
HD)'5'
Titanium tetrachloride
(analyze as total titanium)
Triethanolamine (TEA)
(degradation product of HN-
3)(5>
Trimethyl phosphite151
1 ,3,5-Trin itrobenzene
(1,3,5-TNB)
Sample
Volume'11
1 -4L
40 ml
40 -160 ml
(One to four
VOA vials)
Sample Container
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Amber glass bottles (40 ml or
larger) fitted with PTFE-lined
screw caps
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Holding Time
Minimize
transport and
storage time; if
feasible, analyze
or extract
immediately
upon receipt at
the laboratory.
Analyze samples
within 14 days of
collection.
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Sample Preservation or
Preparation
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. <9)
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine.
Add 400 uL of ammonium
acetate concentrated stock and
80 uL of concentrated sodium
omadine stock. Samples ust not
exceed 10 ฐC during the first 48
hours after collection. Store at
or below 6 ฐC (but above
freezing) until analysis.
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. <9)
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4). (Air-tight
container containing activated
carbon)
Wipe outside of each bottle clean
using a damp, then dry cloth. Seal
the bottle with non-reactive tape or
film. Wrap glass bottles with bubble
wrap. Pack samples as described in
Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Shipping Label'21
Standard carrier
shipping label AND
Aviation regulated
liquid, n.o.s, UN3334
Standard carrier
shipping label AND
Carbamate
pesticides, liquid,
toxic, 6.1, Poison,
UN2992
Standard carrier
shipping label AND
Flammable Liquids,
n.o.s, 3, Flammable,
UN1993
Source/SAM
Method'31
Ch. 4/3535A/
8321 B
(EPA SW-846) /
Footnote (8)
[SAM Tier 1 1 1]
538
(EPA OW)
[SAM Tier I]
3511 /8270D
(EPA SW-846)
[SAM Tier 1 1]
Not of concern in this sample type
1 -4L
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Cool to < 6ฐC. Add sodium
thiosulfate to remove residual
chlorine from treated drinking
water samples. <9)
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Ethanolamine
solutions, 8,
Corrosive, UN2491
3520C/3535A/
8321 B
(EPA SW-846)
[SAM Tier 1 1 1]
Not of concern in this sample type
1 -4L
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Cool to < 6ฐC and store in the
dark. Add sodium thiosulfate to
remove residual chlorine from
treated drinking water
samples.'9'
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Trinitrobenzene and
trinitrotoluene
mixtures, 1.1,
Explosive, UN0388
Ch. 4/3535A/
8330B
(EPA SW-846)
[SAM Tier I]
Sample Collection Information Document
A3-19
September 2014
-------
Drinking Water Samples
Analyte
2,4,6-Trinitrotoluene
(2,4,6-TNT)
Vanadium pentoxide
(analyze as total vanadium)
White phosphorus
Sample
Volume'11
1 -4L
120-480
ml
0.5 -2 L
Sample Container
Amber glass or PTFE container
with PTFE-lined septum or lid.
When PTFE-lined septa or lids
are not available, solvent rinsed
aluminum foil may be used as a
liner.
Plastic or glass (special cleaning
needed)'11'
Wide-mouth glass or PTFE
container with PTFE-lined septum
or lid. Fill to overflowing to
eliminate headspace.
Holding Time
Extract samples
within 7 days of
collection;
analyze within
40 days of
extraction.
Samples should
be preserved
with acid within 2
weeks of
collection, and
can be held 6
months with
acidification. If
not acid
preserved,
analyze
immediately.
Extracts with
isooctane should
be analyzed
within 30 days.
Sample Preservation or
Preparation
Cool to < 6ฐC and store in the
dark. Add sodium thiosulfate to
remove residual chlorine from
treated drinking water
samples. (9)
Acidify to pH < 2 with nitric acid
and store at 4ฐC. If arsenic
species are to be determined,
remove unpreserved aliquot
prior to sample preservation. <12)
Cool to 4ฐC and store in the
dark.
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal
the container with non-reactive tape
or film. Wrap glass containers with
bubble wrap. Pack samples as
described in Footnote (4).
Shipping Label121
Standard carrier
shipping label AND
Trinitrobenzene and
trinitrotoluene
mixtures, 1.1,
Explosive, UN0388
Standard carrier
shipping label AND
Vanadium pentoxide,
6.1, Poison, UN2862
Standard carrier
shipping label AND
Phosphorus, white
(dry or wetted), 4.2,
Spontaneously
combustible, 6.1,
Poison, UN1381
Source/SAM
Method'31
Ch. 4/3535A/
8330B
(EPA SW-846)
[SAM Tier 1]
200.7/200.8
(EPA OW)
[SAM Tier 1]
7580
(EPA SW-846)
[SAM Tier 1]
Sample Collection Information Document
A3-20
September 2014
-------
Solid Samples
Analyte
Acephate
Acrylamide
Acrylonitrile
Aldicarb (Temik)
Aldicarb sulfone
Aldicarb sulfoxide
Allyl alcohol
Sample Size111
TBD
20 - 80 g
5-20g
When collected
without
preservative,
fill the
container,
leaving no
headspace.
20 - 80 g
20 - 80 g
20 - 80 g
5-20g
When collected
without
preservative,
fill the
container,
leaving no
headspace.
Sample Container
250 ml PTFE
centrifuge tube
250 ml wide-mouth
glass container with
PTFE-lined septa or lid
40 ml VOA vial (with
septum) and magnetic
stirring bar
Clear, wide-mouth glass
jar with PTFE-lined lid
250 ml wide-mouth
glass container with
PTFE-lined septa or lid
250 ml wide-mouth
glass container with
PTFE-lined septa or lid
40 ml VOA vial (with
septum) and magnetic
stirring bar
Holding Time
Analyze immediately
or store at negative
(-)18ฐC.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
7 days of collection;
analyze within 40 days
of extraction.
Extract samples within
7 days of collection;
analyze within 40 days
of extraction.
Extract samples within
7 days of collection;
analyze within 40 days
of extraction.
1 4 days
Sample Preservation or
Preparation
Cool to < 6ฐC.
Cool to < 6ฐC.
Preserve to pH ฃ 2 with
NaHSO4 (low analyte
concentrations) or methanol
(high analyte concentrations)
and cool to 4ฐC. Freeze
unpreserved samples at
negative (-) 7ฐC. (Frozen vials
should be placed on their
side.)
Store at 4 (ฑ2)ฐC and out of
direct sunlight.
Store at 4 (ฑ2)ฐC and out of
direct sunlight. Acidify to pH 4
- 5 with 0.1 N chloroacetic acid
immediately after collection.
Store at 4 (ฑ2)ฐC and out of
direct sunlight. Acidify to pH 4
- 5 with 0.1 N chloroacetic acid
immediately after collection.
Preserve to pH ฃ 2 with
NaHSO4 (low analyte
concentrations) or methanol
(high analyte concentrations)
and cool to 4ฐC. Freeze
unpreserved samples at
negative (-) 7ฐC. (Frozen vials
should be placed on their
side.)
Packaging Requirements
TBD
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
bottle with non-reactive tape or film.
Wrap glass bottles with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
bottle with non-reactive tape or film.
Wrap glass bottles with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each vial clean using a
damp, then dry cloth. Seal the vial with
non-reactive tape or film. Wrap glass
vials with bubble wrap. Pack samples as
described in Footnote (4).
Shipping Label121
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Acrylamide, solid, 6.1,
Poison, UN2074
Standard carrier
shipping label AND
Acrylonitrile, stabilized,
3, Flammable liquid,
6.1, Poison, UN1093
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757
Standard carrier
shipping label AND
Allyl alcohol, 3,
Flammable liquid, 6.1,
Poison, UN1098. See
Footnote (2) when
adding liquid
preservatives such as
methanol or bisulfate.
Source/SAM
Method'31
Adapted from
Journal of
Chromatography A,
1154(1): 3-25
[SAM Tier 1 1]
Water Extraction
8316
(EPASW-846)
[SAM Tier III]
Ch. 4/5035A/
8260C
(EPASW-846)
[SAM Tier 1 1]
Ch. 4/831 8A
(EPASW-846)
[SAM Tier 1 1]
Ch. 4/831 8A
(EPASW-846)
[SAM Tier 1 1]
Ch. 4/831 8A
(EPASW-846)
[SAM Tier III]
Ch. 4/5035A/
8260C
(EPASW-846)
[SAM Tier 1 1]
Sample Collection Information Document
A4-1
September 2014
-------
Solid Samples
Analyte
4-Aminopyridine
Ammonia
Ammonium
metavanadate
(analyze as total
vanadium)
Arsenic, Total
Arsenic trioxide
(analyze as total
arsenic)
Arsine'51
(analyze as total arsenic
in non-air samples)
Asbestos
Boron trifluoride
Sample Size111
10-40g
Sample Container
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined septa
or lids are not available,
solvent rinsed
aluminum foil may be
used as a liner.
Holding Time
Extract samples within
7 days of collection;
analyze within 40 days
of extraction.
Sample Preservation or
Preparation
Store samples and extracts at
< 4ฐC in the dark. After air
drying, soil and solid samples
can be stored at room
temperature.
Packaging Requirements
Wipe outside of each bottle clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film. Wrap glass
bottles with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label121
Standard carrier
shipping label AND
Aminopyridines, 6.1,
Poison, UN2671
Source/SAM
Method'31
Ch. 4 / 8330B
(EPASW-846)
[SAM Tier III]
Not of concern in this sample type
200 g
200 g
200 g
1 - 8 g (wet
weight) or 1 - 4
g (dry weight)
200 ml for soft
surfaces; wipe
for hard
surfaces
PTFE, plastic or glass.
If using 6020A, only
PTFE or fluorocarbon
containers are
recommended, (special
cleaning needed). <11)
PTFE, plastic or glass.
If using 6020A, only
PTFE or fluorocarbon
containers are
recommended, (special
cleaning needed). <11)
PTFE, plastic or glass.
If using 6020A, only
PTFE or fluorocarbon
containers are
recommended, (special
cleaning needed). <11)
Plastic or glass (special
cleaning needed)'11'
Wipe (hard surfaces);
25 or 37 mm air
sampling cassette
transferred to aqueous
suspension of 200 ml
(soft surfaces)
Digest samples as
soon as possible after
arrival; analyze within
180 days of digestion.
Digest samples as
soon as possible after
arrival; analyze within
180 days of digestion.
Digest samples as
soon as possible after
arrival; analyze within
180 days of digestion.
Minimize transport and
storage time; if
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
None
None
None
None
None
None
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Standard carrier
shipping label AND
Ammonium
metavanadate, 6.1,
Poison, UN2859
Standard carrier
shipping label AND
Arsenic, 6.1, Poison,
UN1558
Standard carrier
shipping label AND
Arsenic trioxide, 6.1,
Poison, UN1561
Standard carrier
shipping label AND
Arsine, 2.3(2.1),
Poisonous gas,
UN2188
Standard carrier
shipping label
3050B/6010C/
6020A
(EPASW-846)
[SAM Tier I]
Ch. 3 / 3050B /
6010C/6020A
(EPASW-846)
[SAM Tier I]
3050B/6010C/
6020A
(EPASW-846)
[SAM Tier I]
Ch. 3 / 3050B /
7010
(EPASW-846)
[SAM Tier I]
D5755-03 (soft
surfaces-micro vac)
(ASTM)
[SAM Tier III]
Not of concern in this sample type
Sample Collection Information Document
A4-2
September 2014
-------
Solid Samples
Analyte
Brodifacoum
Bromadiolone15'
Calcium arsenate
(analyze as total
arsenic)
Carbofuran (Furadan)
Carbon disulfide
Carfentanil
Sample Size111
50 - 200 g
50 - 200 g
200 g
20 - 80 g
5-20g
When collected
without
preservative,
fill the
container,
leaving no
headspace.
50 - 200 g
Sample Container
250 ml wide-mouth
glass container with
PTFE-lined septa or lid
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
PTFE, plastic or glass.
If using 6020A, only
PTFE or fluorocarbon
containers are
recommended, (special
cleaning needed). <11)
Clear, wide mouth glass
jar with PTFE-lined lid
40 ml VOA vial (with
septum) and magnetic
stirring bar
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Holding Time
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Digest samples as
soon as possible after
arrival; analyze within
180 days of digestion.
Extract within 7 days
of collection; analyze
within 40 days of
extraction.
1 4 days
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Sample Preservation or
Preparation
Cool to < 6ฐC.
Cool to < 6ฐC.
None
Store at 4 (ฑ2)ฐC and out of
direct sunlight.
Preserve to pH ฃ 2 with
NaHSO4(lowanalyte
concentrations) or methanol
(high analyte concentrations)
and cool to 4ฐC. Freeze
unpreserved samples at
negative (-) 7ฐC. (Frozen vials
should be placed on their
side.)
Cool to < 6ฐC.
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each vial clean using a
damp, then dry cloth. Seal the vial with
non-reactive tape or film. Wrap glass
vials with bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Shipping Label121
Standard carrier
shipping label AND
Coumarin derivative
pesticides, solid, toxic,
6.1, Poison, UN3026
Standard carrier
shipping label AND
Coumarin derivative
pesticides, solid, toxic,
6.1, Poison, UN3026
Standard carrier
shipping label AND
Calcium arsenate, 6.1 ,
Poison, UN1573
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757
Standard carrier
shipping label AND
Carbon disulfide, 3,
Flammable liquid,
UN1131.See
Footnote (11) when
methanol or bisulfate
is used.
Standard carrier
shipping label
Source/SAM
Method'31
Ch. 4 / 3541 /
3545A/8321B
(EPASW-846)
[SAM Tier III]
Ch. 4 / 3541 /
3545A/8321B
(EPASW-846)
[SAM Tier III]
Ch. 3 / 3050B /
6010C/6020A
(EPASW-846)
[SAM Tier I]
831 8A
(EPASW-846)
[SAM Tier 1 1]
Ch. 4/5035A/
8260C
(EPASW-846)
[SAM Tier I]
Ch. 4 / 3541 /
3545A/8321B
(EPASW-846)
[SAM Tier III]
Sample Collection Information Document
A4-3
September 2014
-------
Solid Samples
Analyte
Chlorfenvinphos
Chlorine
2-Chloroethanol
3-Chloro-1,2-
propanediol151
Chloropicrin151
Chlorpyrifos
Sample Size111
1-4g
Sample Container
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Holding Time
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Sample Preservation or
Preparation
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Shipping Label121
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Source/SAM
Method'31
Ch. 4 / 3541 /
3545A / 8270D
(EPASW-846)
[SAM Tier I]
Not of concern in this sample type
5-20g
When collected
without
preservative,
fill the
container,
leaving no
headspace.
30- 120 g
30- 120 g
30- 120 g
40 ml VOA vial (with
septum) and magnetic
stirring bar
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
1 4 days
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Preserve to pH ฃ 2 with
NaHSO4(lowanalyte
concentrations) or methanol
(high analyte concentrations)
and cool to 4ฐC. Freeze
unpreserved samples at
negative (-) 7ฐC. (Frozen vials
should be placed on their
side.)
Cool to < 6ฐC.
Cool to < 6ฐC.
Cool to < 6ฐC.
Wipe outside of each vial clean using a
damp, then dry cloth. Seal the vial with
non-reactive tape or film. Wrap glass
vials with bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4). (Air-tight container containing
activated carbon.)
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Standard carrier
shipping label. See
Footnote (2) when
adding liquid
preservatives such as
methanol or bisulfate
Standard carrier
shipping label
Standard carrier
shipping label AND
Chloropicrin, 6.1,
Poison, UN1580
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Ch. 4/5035A/
8260C
(EPASW-846)
[SAM Tier 1 1]
European Journal
Lipid Sci.
Technology 2011,
113345-355
[SAM Tier 1 1]
Ch. 4/3570A/
8270D
(EPASW-846)
[SAM Tier 1 1]
Ch. 4/3570A/
8270D
(EPASW-846)
[SAM Tier 1 1]
Sample Collection Information Document
A4-4
September 2014
-------
Solid Samples
Analyte
Chlorpyrifos oxon
Crimidine151
Cyanide, Amenable to
chlorination
Cyanide, Total
Cyanogen chloride151
Sample Size111
30- 120 g
30- 120 g
30- 120 g
1-5g
5-20g
When collected
without
preservative,
fill the
container,
leaving no
headspace.
Sample Container
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Glass or polyethylene
bottle (1 L size)
Glass or polyethylene
bottles
40 ml VOA vial (with
septum) and magnetic
stirring bar
Holding Time
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
1 4 days
12 days after sample
receipt
Minimize transport and
storage time; if
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Sample Preservation or
Preparation
Cool to < 6ฐC.
Cool to < 6ฐC.
Add NaOH until pH> 12 at
time of collection; cool to 4ฐC.
Protect from light and ice or
refrigerate at 4 (ฑ2)ฐC from
collection until digestion.
Preserve to pH ฃ 2 with
NaHSO4(lowanalyte
concentrations) or methanol
(high analyte concentrations)
and cool to 4ฐC. Freeze
unpreserved samples at
negative (-) 7ฐC. (Frozen vials
should be placed on their
side.)
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4). (Air-tight container containing
activated carbon.)
Wipe outside of each vial clean using a
damp, then dry cloth. Seal the vial with
non-reactive tape or film. Wrap glass
vials with bubble wrap. Pack samples as
described in Footnote (4). (Air-tight
container containing activated carbon.)
Shipping Label121
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label
Standard carrier
shipping label AND
Cyanide inorganic
solid n.o.s, 6.1,
Poison, UN1588
Standard carrier
shipping label AND
Cyanides, inorganic,
solid, n.o.s, 6.1,
Poison, UN1588
Standard carrier
shipping label AND
Cyanogen chloride,
2.3, Poisonous gas,
UN1589. See
Footnote (11) when
methanol or bisulfate
is used.
Source/SAM
Method'31
Ch. 4 / 3541 /
3545A / 8270D
(EPASW-846)
[SAM Tier III]
Ch. 4 / 3570 /
8270D
(EPASW-846)
[SAM Tier 1 1]
3135.21
(EPA Regional Lab)
[SAM Tier 1]
ISM 01. 3 CN
(EPA CLP)
[SAM Tier I]
Encyclopedia of
Anal. Chem. 2006
DOI:
10.1002/978047002
7318.a0809
[SAM Tier 1 1]
Sample Collection Information Document
A4-5
September 2014
-------
Solid Samples
Analyte
1,2-Dichloroethane
(degradation product of
HD)
Dichlorvos
Dicrotophos
Diesel Range Organics
Diisopropyl
methylphosphonate
(DIMP)
(degradation product of
GB)(5>
Sample Size111
5-20g
When collected
without
preservative,
fill the
container,
leaving no
headspace.
30- 120 g
30- 120 g
30- 120 g
10 -40 ml
Sample Container
40 ml VOA vial (with
septum) and magnetic
stirring bar
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Holding Time
1 4 days
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract and analyze
samples within 7 days
of collection.
Sample Preservation or
Preparation
Preserve to pH ฃ 2 with
NaHSO4(lowanalyte
concentrations) or methanol
(high analyte concentrations)
and cool to 4ฐC. Freeze
unpreserved samples at
negative (-) 7ฐC. (Frozen vials
should be placed on their
side.)
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Cool to < 6ฐC.
Store between 0ฐC and 6ฐC.
Packaging Requirements
Wipe outside of each vial clean using a
damp, then dry cloth. Seal the vial with
non-reactive tape or film. Wrap glass
vials with bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Shipping Label121
Standard carrier
shipping label AND
Ethylene dichloride, 6,
Poison, UN1184. See
Footnote (2) when
adding liquid
preservatives such as
methanol or bisulfate.
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label
Standard carrier
shipping label
Source/SAM
Method'31
Ch. 4/5035A/
8260C
(EPASW-846)
[SAM Tier 1]
Ch. 4/3545A/
3541 / 8270D
(EPASW-846)
[SAM Tier I]
Ch. 4/3545A/
3541 / 8270D
(EPASW-846)
[SAM Tier I]
Ch. 4 / 3541 /
3545A/8015C
(EPASW-846)
[SAM Tier I]
E2866-12 (ASTM)
[SAM Tier 1 1]
Sample Collection Information Document
A4-6
September 2014
-------
Solid Samples
Analyte
Dimethylphosphite151
Dimethylphosphoramidi
c acid (degradation
product GA)(S|
Diphacinone
Disulfoton
Disulfoton sulfone oxon
Sample Size111
30- 120 g
30- 120 g
30- 120 g
30- 120 g
30- 120 g
Sample Container
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Holding Time
Minimize transport and
storage time; if
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Sample Preservation or
Preparation
Cool to < 6ฐC.
Cool to 4ฐC.
Cool to < 6ฐC.
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Cool samples to ฃ 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4). (Air-tight container containing
activated carbon.)
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Shipping Label121
Standard carrier
shipping label AND
Organophosphorus
compound, toxic,
solid, n.o.s, 6.1,
Poison, UN3464
Standard carrier
shipping label AND
Organophosphorus
compound, toxic,
solid, n.o.s, 6.1,
Poison, UN3464
Standard carrier
shipping label AND
Coumarin derivative
pesticides, solid, toxic,
6.1, Poison, UN3026
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Source/SAM
Method'31
Ch. 4 / 3570 /
8270D
(EPASW-846)/
Footnote (8)
[SAM Tier II]
Ch. 4 / 3541 /
3545A/8321B
(EPASW-846)
[ISAM Tier II]
Ch. 4 / 3541 /
3545A/8321B
(EPASW-846)
[SAM Tier III]
Ch. 4 / 3570 /
8270D
(EPASW-846)
[SAM Tier 1 1]
Ch. 4 / 3541 /
3545A / 8270D
(EPASW-846)
[SAM Tier III]
Sample Collection Information Document
A4-7
September 2014
-------
Solid Samples
Analyte
Disulfoton sulfoxide
Disulfoton sulfoxide
oxon
1,4-Dithiane
(degradation product of
HD)'5'
EA2192 [S-2-
(diisopropylamino) ethyl
methylphosphonothioic
acid]
(hydrolysis product of
VX)'5'
Ethyl methyl
phosphonic acid
(EMPA)
(degradation product of
VX)'51
Sample Size111
30- 120 g
30- 120 g
30- 120 g
30- 120 g
10-100g
Sample Container
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Glass jars with PTFE-
lined caps
demonstrated to be free
of interferences
Holding Time
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Minimize transport and
storage time; if
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Analyze samples
within 7 days of
collection.
Sample Preservation or
Preparation
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Cool samples to ฃ 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Cool to < 6ฐC.
Store between 0ฐC and 6ฐC.
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
TBD(7)
Air-tight container containing activated
carbon
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Shipping Label121
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label. See
Footnote (2) when
adding liquid
preservatives such as
methanol or bisulfate
TBD(7)
Standard carrier
shipping label AND
Organophosphorus
compound, toxic,
solid, n.o.s, 6.1,
Poison, UN3464
Source/SAM
Method'31
Ch. 4 / 3541 /
3545A / 8270D
(EPASW-846)
[SAM Tier III]
Ch. 4 / 3541 /
3545A / 8270D
(EPASW-846)
[SAM Tier III]
Ch. 4 / 3570 /
8270D
(EPASW-846)
[SAM Tier 1 1]
Ch. 4 / 3541 /
3545A/8321B
(EPASW-846)/
Footnote (8)
[SAM Tier III]
E2866-12
(ASTM)
[SAM Tier 1 1]
Sample Collection Information Document
A4-8
September 2014
-------
Solid Samples
Analyte
Ethyldichloroarsine
(ED)151
N-Ethyldiethanolamine
(EDEA) (degradation
product of HN-1)(S|
Ethylene oxide
Fenamiphos151
Fentanyl
Fluoride
Sample Size111
30- 120 g
30- 120 g
5-20g
When collected
without
preservative,
fill the
container,
leaving no
headspace.
30- 120 g
30- 120 g
Sample Container
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
40 ml VOA vial (with
septum) and magnetic
stirring bar
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Holding Time
Minimize transport and
storage time; if
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
1 4 days
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Sample Preservation or
Preparation
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Cool to < 6ฐC.
Preserve to pH ฃ 2 with
NaHSO4(lowanalyte
concentrations) or methanol
(high analyte concentrations)
and cool to 4ฐC. Freeze
unpreserved samples at
negative (-) 7ฐC. (Frozen vials
should be placed on their
side.)
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Cool to < 6ฐC.
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4). (Air-tight container containing
activated carbon)
Wipe outside of each vial clean using a
damp, then dry cloth. Seal the vial with
non-reactive tape or film. Wrap glass
vials with bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Shipping Label121
Standard carrier
shipping label AND
Ethyldichloroarsine,
6.1, Poison, UN1892
Standard carrier
shipping label
Standard carrier
shipping label AND
Ethylene oxide
(concentration
dependent, refer to 40
CFR 172.101 for more
information). See
Footnote (2) when
adding liquid
preservatives such as
methanol or bisulfate.
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label
Source/SAM
Method'31
Ch. 4 / 3541 /
3545A / 8270D
(EPASW-846)
[SAM Tier III]
Ch. 4 / 3541 /
3545A/8321B
(EPASW-846)/
Footnote (8)
[SAM Tier III]
Ch. 4/5035A/
8260C
(EPASW-846)
[ISAM Tier I]
Ch. 4 / 3570 /
8270D
(EPASW-846)
[SAM Tier 1 1]
Ch. 4 / 3541 /
3545A/8321B
(EPASW-846)
[SAM Tier III]
Not of concern in this sample type
Sample Collection Information Document
A4-9
September 2014
-------
Solid Samples
Analyte
Fluoroacetamide
Fluoroacetic acid and
fluoroacetate salts
(analyze as
fluoroacetate ion)151
2-Fluoroethanol
Formaldehyde
Gasoline Range
Organ ics
Sample Size111
TBD
30- 120 g
5-20g
When collected
without
preservative,
fill the
container,
leaving no
headspace.
25- 100 g
5-20g
When collected
without
preservative,
fill the
container,
leaving no
headspace.
Sample Container
TBD
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
40 ml VOA vial (with
septum) and magnetic
stirring bar.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
40 ml VOA vial (with
septum) and magnetic
stirring bar
Holding Time
TBD
Analyze samples
within 7 days.
1 4 days
Extract and analyze
within 30 days of
collection. All
derivatized sample
extracts should be
analyzed within 3 days
after preparation.
1 4 days
Sample Preservation or
Preparation
TBD
Cool to 4*C.
Preserve to pH ฃ 2 with
NaHSO4(lowanalyte
concentrations) or methanol
(high analyte concentrations)
and cool to 4ฐC. Freeze
unpreserved samples at
negative (-) 7ฐC. (Frozen vials
should be placed on their
side.)
Refrigerate at 4ฐC (solid
extracts should be buffered to
pH 5.0 to minimize the
formation of artifact
formaldehyde).
Preserve to pH ฃ 2 with
NaHSO4 (low analyte
concentrations) or methanol
(high analyte concentrations)
and cool to 4ฐC. Freeze
unpreserved samples at
negative (-) 7ฐC. (Frozen vials
should be placed on their
side.)
Packaging Requirements
TBD
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each vial clean using a
damp, then dry cloth. Seal the vial with
non-reactive tape or film. Wrap glass
vials with bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each vial clean using a
damp, then dry cloth. Seal the vial with
non-reactive tape or film. Wrap glass
vials with bubble wrap. Pack samples as
described in Footnote (4).
Shipping Label121
Standard carrier
shipping label
Standard carrier
shipping label
Standard carrier
shipping label
Standard carrier
shipping label AND
Formaldehyde
(concentration
dependent, refer to 40
CFR172.101 for more
information)
Standard carrier AND
Gasoline identification
set, 2.3, Poison gas,
NA9035. See Footnote
(2) when adding liquid
preservatives such as
methanol or bisulfate.
Source/SAM
Method'31
Adapted from
Journal of
Chromatography B,
876(1): 103-1 08
[SAM Tier 1 1]
J.ChromA1139
(2007)271-278
[SAM Tier III]
Ch. 4/5035A/
8260C
(EPASW-846)
[SAM Tier III]
Ch. 4/831 5A
(EPASW-846)
[SAM Tier I]
Ch. 4/5035A/
801 5C
(EPASW-846)
[SAM Tier I]
Sample Collection Information Document
A4-10
September 2014
-------
Solid Samples
Analyte
Hexahydro-1,3,5-trinitro-
1,3,5-triazine(RDX)
Hexamethylenetriperoxi
dediamine (HMTD)(S|
Hydrogen bromide
Hydrogen chloride
Hydrogen cyanide
Hydrogen fluoride
Hydrogen sulfide
Isopropyl
methylphosphonic acid
(IMPA) (degradation
product of GB)(S|
Kerosene151
Lead arsenate
(analyze as total
arsenic)
Sample Size111
10-40g
10-40g
Sample Container
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Holding Time
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Sample Preservation or
Preparation
Store samples and extracts at
< 4ฐC in the dark. After air
drying, soil and solid samples
can be stored at room
temperature.
Store samples and extracts at
< 4ฐC in the dark. After air
drying, soil and solid samples
can be stored at room
temperature.
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Shipping Label121
Standard carrier
shipping label AND
RDX, 1.1, Explosive,
UN0483
Forbidden
Source/SAM
Method'31
Ch. 4 / 8330B
(EPASW-846)
[SAM Tier 1]
Ch. 4 / 8330B
(EPASW-846)/
Analyst 2001
126:1689-1693
[SAM Tier 1 1]
Not of concern in this sample type
Not of concern in this sample type
Not of concern in this sample type
Not of concern in this sample type
Not of concern in this sample type
10-100g
5-20g
When collected
without
preservative,
fill the
container,
leaving no
headspace.
200 g
Glass jars with PTFE-
lined caps
demonstrated to be free
of interferences
40 ml VOA vial (with
septum) and magnetic
stirring bar
PTFE, plastic or glass.
If using 6020A, only
PTFE or fluorocarbon
containers are
recommended, (special
cleaning needed). (11)
The samples are to be
extracted, filtered
and analyzed by
LC/MS/MS within 7
days of collection.
1 4 days
Digest samples as
soon as possible after
arrival; analyze within
180 days of digestion.
Cool between 0ฐC and 6ฐC.
Preserve to pH ฃ 2 with
NaHSO4(lowanalyte
concentrations) or methanol
(high analyte concentrations)
and cool to 4ฐC. Freeze
unpreserved samples at
negative (-) 7ฐC. (Frozen vials
should be placed on their
side.)
None
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each vial clean using a
damp, then dry cloth. Seal the vial with
non-reactive tape or film. Wrap glass
vials with bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic,
solid, n.o.s, 6.1,
Poison, UN3464
Standard carrier
shipping label AND
Kerosene, 3,
Flammable, UN1223.
See Footnote (2) when
adding liquid
preservatives such as
methanol or bisulfate.
Standard carrier
shipping label AND
Lead arsenate, 6.1,
Poison, UN1617
E2866-12
(ASTM)
[SAM Tier 1 1]
Ch. 4/5035A/
801 5C
(EPASW-846)
[SAM Tier I]
Ch. 3 / 3050B /
6010C/6020A
(EPASW-846)
[SAM Tier I]
Sample Collection Information Document
A4-11
September 2014
-------
Solid Samples
Analyte
Lewisite oxide
(degradation product of
Lewisite)'51
(analyze as total
arsenic)
Mercuric chloride
(analyze as total
mercury)
Mercury, Total
Methamidophos
Methomyl
Methoxyethylmercuric
acetate (analyze as total
mercury)151
Methyl acrylonitrile
Sample Size111
200 g
200 g
200 g
TBD
20 - 80 g
200 g
20 - 80 g
Sample Container
PTFE, plastic or glass.
If using 6020A, only
PTFE or fluorocarbon
containers are
recommended, (special
cleaning needed). <11)
PTFE, plastic or glass
PTFE, plastic or glass
250 ml PTFE
centrifuge tube
Clear, wide mouth glass
jar with PTFE-lined lid
PTFE, plastic or glass
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Holding Time
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
28 days
28 days
Analyze immediately
or store at negative (-)
18ฐC.
Extract samples within
7 days of collection;
analyze within 40 days
of extraction.
28 days
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Sample Preservation or
Preparation
None
Acidify to pH < 2 with nitric
acid.
Acidify to pH < 2 with nitric
acid.
Cool to < 6ฐC.
Store at 4 (ฑ2)ฐC and out of
direct sunlight.
Acidify to pH < 2 with nitric
acid.
Cool to < 6ฐC.
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
TBD
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
bottle with non-reactive tape or film.
Wrap glass bottles with bubble wrap.
Pack samples as described in Footnote
(4).
Shipping Label121
Standard carrier
shipping label AND
Arsenic compounds,
solid, n.o.s, 6.1,
Poison, UN1557
Standard carrier
shipping label AND
Mercuric chloride, 6.1,
Poison, UN1624
Standard carrier
shipping label AND
Mercury, 8, Corrosive,
UN2809
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757
Standard carrier
shipping label AND
Mercury compounds,
solid, n.o.s, 6.1,
Poison, UN2025
Standard carrier
shipping label AND
Methyl acryonitrile,
3.0, Flammable Liquid,
6.1, Poison, UN3079
Source/SAM
Method'31
Ch. 3 / 3050B /
6010C/6020A
(EPASW-846)/
Footnote (8)
[SAM Tier I]
Ch. 3 / 7473
(EPASW-846)
[SAM Tier I]
Ch. 3 / 7473
(EPASW-846)
[SAM Tier I]
Adapted from
Journal of
Chromatography A,
1154(1): 3-25
[SAM Tier 1 1]
831 8A
(EPASW-846)
[SAM Tier 1 1]
Ch. 3 / 7473
(EPASW-846)
[SAM Tier I]
5035A / 8260C
(EPASW-846)
[SAM Tier 1 1]
Sample Collection Information Document
A4-12
September 2014
-------
Solid Samples
Analyte
Methyl fluoroacetate
(analyze as
fluoroacetate ion) |s|
Methyl hydrazine'51
Methyl isocyanate
Methyl paraoxon
Methyl parathion
Methylamine
N-Methyldiethanolamine
(MDEA) (degradation
product of HN-2)(S|
Sample Size111
30- 120 g
30- 120 g
Sample Container
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Holding Time
Analyze samples
within 7 days.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Sample Preservation or
Preparation
Cool to 4ฐC.
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Shipping Label121
Standard carrier
shipping label
Standard carrier
shipping label AND
Methyl hydrazine, 6.1,
Poison, UN1244
Source/SAM
Method'31
J.ChromA1139
(2007)271-278
[SAM Tier III]
J.Chrom. 1993617
157-162
[SAM Tier III]
Not of concern in this sample type
30- 120 g
30- 120 g
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Extract sample within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
3541 / 3545A /
8270D
(EPASW-846)
[III]
Ch. 4 / 3541 /
3545A / 8270D
(EPASW-846)
[SAM Tier I]
Not of concern in this sample type
30- 120 g
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Cool to < 6ฐC.
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Standard carrier
shipping label
Ch. 4 / 3541 /
3545A/8321B
(EPASW-846)
[SAM Tier III]
Sample Collection Information Document
A4-13
September 2014
-------
Solid Samples
Analyte
Methylphosphonic acid
(MPA)
(degradation product of
VX, GB, & GD)(S|
Mevinphos
Monocrotophos
Nicotine compounds
(analyze as nicotine)
Octahyd ro-1, 3,5,7-
tetranitro-1 ,3,5,7-
tetrazocine (HMX)
Sample Size111
10-100g
30- 120 g
30- 120 g
30- 120 g
10-40g
Sample Container
Glass jars with PTFE-
lined caps
demonstrated to be free
of interferences
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Holding Time
Analyze samples
within 7 days of
collection.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Sample Preservation or
Preparation
Store between 0ฐC and 6ฐC.
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Store samples and extracts at
< 4ฐC in the dark. After air
drying, soil and solid samples
can be stored at room
temperature.
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Shipping Label121
Standard carrier
shipping label AND
Organophosphorus
compound, toxic,
solid, n.o.s, 6.1,
Poison, UN3464
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Nicotine compounds,
solid, n.o.s, 6.1,
Poison, UN1655
Standard carrier
shipping label
Source/SAM
Method'31
E2866-12 (ASTM)
[SAM Tier 1 1]
Ch. 4 / 3541 /
3545A / 8270D
(EPASW-846)
[SAM Tier I]
Ch. 4 / 3541 /
3545A / 8270D
(EPASW-846)
[SAM Tier I]
Ch. 4 / 3545A /
8270D
(EPASW-846)
[SAM Tier 1 1]
Ch. 4 / 8330B
(EPASW-846)
[SAM Tier I]
Sample Collection Information Document
A4-14
September 2014
-------
Solid Samples
Analyte
Osmium tetraoxide
(analyze as total
osmium)151
Oxamyl
Paraoxon
Paraquat
Parathion
Pentaerythritol
tetranitrate (PETN)
Sample Size111
200 g
20 - 80 g
30- 120 g
5-20g
30- 120 g
10-40g
Sample Container
PTFE, plastic or glass.
If using 6020A, only
PTFE or fluorocarbon
containers are
recommended, (special
cleaning needed). <11)
Clear, wide mouth glass
jar with PTFE-lined lid
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Clear, wide mouth glass
jar with PTFE-lined lid
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Holding Time
Digest samples as
soon as possible after
arrival; analyze within
180 days of digestion.
Extract samples within
7 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Analyze samples
within 7 days.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Sample Preservation or
Preparation
None
Store at 4 (ฑ2)ฐC and out of
direct sunlight.
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Cool to 4ฐC.
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Store samples and extracts at
< 4ฐC in the dark. After air
drying, soil and solid samples
can be stored at room
temperature.
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Place filter in protective covering. Place
protected filter in double plastic bags,
and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Shipping Label121
Standard carrier
shipping label AND
Osmium tetroxide, 6.1 ,
Poison, UN2471
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Fluoroacetic acid, 6.1 ,
Poison, UN2642
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Forbidden
Source/SAM
Method'31
Ch. 3 / 3050B /
601 OC
(EPASW-846)
[SAM Tier 1 1]
Ch. 4/831 8A
(EPASW-846)
[SAM Tier 1 1]
Ch. 4 / 3541 /
3545A / 8270D
(EPASW-846)
[SAM Tier III]
J. Chrom A, 1139
(2007)271-278
[SAM Tier 1 1]
Ch. 4 / 3541 /
3545A / 8270D
(EPASW-846)
[SAM Tier I]
Ch. 4 / 8330B
(EPASW-846)
[SAM Tier I]
Sample Collection Information Document
A4-15
September 2014
-------
Solid Samples
Analyte
Phencyclidine
Phorate
Phorate sulfone
Phorate sulfone oxon
Phorate sulfoxide
Sample Size111
30- 120 g
30- 120 g
30- 120 g
30- 120 g
30- 120 g
Sample Container
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Holding Time
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Sample Preservation or
Preparation
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Cool samples to ฃ 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Shipping Label121
Standard carrier
shipping label
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Source/SAM
Method'31
Ch. 4 / 3570
(EPASW-846)
[SAM Tier II]
Ch. 4/3545A/
8270D
(EPASW-846)
[SAM Tier 1]
Ch. 4 / 3541 /
3545A / 8270D
(EPASW-846)
[SAM Tier III]
Ch. 4 / 3541 /
3545A / 8270D
(EPASW-846)
[SAM Tier III]
Ch. 4 / 3545A /
8270D
(EPASW-846)
[SAM Tier III]
Sample Collection Information Document
A4-16
September 2014
-------
Solid Samples
Analyte
Phorate sulfoxide oxon
Phosgene
Phosphamidon
Phosphine
Phosphorus trichloride
Pinacolyl methyl
phosphonic acid
(PMPA) (degradation
product of GD)(S|
Propylene oxide151
Sodium arsenite
(analyze as total
arsenic)151
Sample Size111
30- 120 g
Sample Container
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Holding Time
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Sample Preservation or
Preparation
Cool samples to ฃ 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Shipping Label121
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Source/SAM
Method'31
Ch. 4 / 3541 /
3545A / 8270D
(EPASW-846)
[SAM Tier III]
Not of concern in this sample type
30- 120 g
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
3541 / 3545A /
8270D
(EPASW-846)
[SAM Tier I]
Not of concern in this sample type
Not of concern in this sample type
10-100g
5-20g
When collected
without
preservative,
fill the
container,
leaving no
headspace.
200 g
Glass jars with PTFE-
lined caps
demonstrated to be free
of interferences
40 ml VOA vial (with
septum) and magnetic
stirring bar.
PTFE, plastic or glass.
If using 6020A, only
PTFE or fluorocarbon
containers are
recommended, (special
cleaning needed). <11)
The samples are to be
extracted filtered and
analyzed within 7 days
of collection.
Stable for 7 days on
ice and 14 days with
chemical
preservatives. Analyze
as soon as practical.
Digest samples as
soon as possible after
arrival; analyze within
180 days of digestion.
Store between 0ฐC and 6ฐC.
Preserve to pH ฃ 2 with
NaHSO4(lowanalyte
concentrations) or methanol
(high analyte concentrations)
and cool to 4ฐC. Freeze
unpreserved samples at
negative (-) 7ฐC. (Frozen vials
should be placed on their
side.)
None
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each vial clean using a
damp, then dry cloth. Seal the vial with
non-reactive tape or film. Wrap glass
vials with bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic,
solid, n.o.s, 6.1,
Poison, UN3464
Standard carrier
shipping label AND
Propylene oxide, 3,
Flammable, UN1280.
See Footnote (2) when
adding liquid
preservatives such as
methanol or bisulfate.
Standard carrier
shipping label AND
Sodium arsenite, solid,
6.1, Poison, UN2027
E2866-12
(ASTM)
[SAM Tier 1 1]
Ch. 4/5035A/
8260C
(EPASW-846)
[SAM Tier 1 1]
Ch. 3 / 3050B /
6010C/6020A
(EPASW-846)
[SAM Tier I]
Sample Collection Information Document
A4-17
September 2014
-------
Solid Samples
Analyte
Sodium azide (analyze
as azide ion)
Strychnine
Tetraethyl
pyrophosphate151
(TEPP)
Tetramethylene-
disulfotetramine151
(TETS)
Thallium sulfate
(analyze as total
thallium)
Sample Size111
30- 120 g
30- 120 g
30- 120 g
30- 120 g
200 g
Sample Container
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
PTFE, plastic or glass.
If using 6020A, only
PTFE or fluorocarbon
containers are
recommended, (special
cleaning needed). <11)
Holding Time
Analyze samples
within 28 days.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Digest samples as
soon as possible after
arrival; analyze within
180 days of digestion.
Sample Preservation or
Preparation
Cool to 4ฐC.
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
None
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Shipping Label121
Standard carrier
shipping label AND
Sodium azide, 6.1,
Poison, UN1687
Standard carrier
shipping label AND
Strychnine, 6.1,
Poison, UN1692
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Pesticides, solid, toxic,
n.o.s, 6.1, Poison,
UN2588
Standard carrier
shipping label AND
Thallium compounds
n.o.s, 6.1, Poison,
UN1707
Source/SAM
Method'31
Adapted from J. of
Forensic Sciences,
43(1): 200-202 /
300.1, Rev 1.0
(EPAOW)
[SAM Tier 1 1]
3541 / 3545A /
8270D
(EPASW-846)
[SAM Tier I]
Ch. 4 / 3570 /
8270D
(EPASW-846)
[SAM Tier 1 1]
Ch. 4 / 3541 /
3545A / 8270D
(EPASW-846)
[SAM Tier 1 1]
Ch. 3 / 3050B /
6010C/6020A
(EPASW-846)
[SAM Tier I]
Sample Collection Information Document
A4-18
September 2014
-------
Solid Samples
Analyte
Thiodiglycol (TDG)
(degradation product of
HD)(5>
Thiofanox
1,4-Thioxane
(degradation product of
HD)'5'
Titanium tetrachloride
(analyze as total
titanium)'51
Triethanolamine (TEA)
(degradation product of
HN-3)(S|
Sample Size111
10-100g
30- 120 g
30- 120 g
200 g
30- 120 g
Sample Container
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
PTFE, plastic or glass.
If using 6020A, only
PTFE or fluorocarbon
containers are
recommended, (special
cleaning needed). <11)
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Holding Time
Extract and analyze
within 7 days of
sample collection.
Minimize transport and
storage time; if
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Digest samples as
soon as possible after
arrival; analyze within
180 days of digestion.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Sample Preservation or
Preparation
Cool between 0ฐC and 6ฐC.
Cool to < 6ฐC.
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
None
Cool to < 6ฐC.
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4). (Air-tight container containing
activated carbon.)
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4). (Air-tight container containing
activated carbon)
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Shipping Label121
Standard carrier
shipping label AND
Aviation regulated
solid, n.o.s, UN3335
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757
Standard carrier
shipping label AND
Flammable Liquids,
n.o.s, 3, Flammable,
UN1993
Standard carrier
shipping label AND
Titanium tetrachloride,
8, Corrosive, UN1838
Standard carrier
shipping label AND
Ethanolamine
solutions, 8,
Corrosive, UN2491
Source/SAM
Method'31
E2787-11
(ASTM)
[SAM Tier 1 1]
Ch. 4 / 3541 /
3545A/8321B
(EPASW-846)
[SAM Tier III]
Ch. 4/3545A/
8270D
(EPASW-846)
[SAM Tier 1 1]
Ch. 3 / 3050B /
6010C/6020A
(EPASW-846)
[SAM Tier I]
Ch. 4 / 3541 /
3545A/8321B
(EPASW-846)
[SAM Tier III]
Sample Collection Information Document
A4-19
September 2014
-------
Solid Samples
Analyte
Trimethyl phosphite151
1,3,5-Trinitrobenzene
(1,3,5-TNB)
2,4,6-Trinitrotoluene
(2,4,6-TNT)
Vanadium pentoxide
(analyze as total
vanadium)
White phosphorus
Sample Size111
30- 120 g
10-40g
10-40g
200 g
40- 160 g
Sample Container
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
PTFE, plastic or glass.
If using 6020A, only
PTFE or fluorocarbon
containers are
recommended, (special
cleaning needed). <11)
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent
rinsed aluminum foil
may be used as a liner.
Holding Time
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Digest samples as
soon as possible after
arrival; analyze within
180 days of digestion.
Soil / sediment
samples can be held
indefinitely if sealed
tightly to eliminate
moisture loss. Extracts
with isooctane should
be analyzed within 30
days.
Sample Preservation or
Preparation
Cool samples to < 6ฐC and
store extracts at negative (-)
10ฐCinthedark.
Store samples and extracts at
< 4ฐC in the dark. After air
drying, soil and solid samples
can be stored at room
temperature.
Store samples and extracts at
< 4ฐC in the dark. After air
drying, soil and solid samples
can be stored at room
temperature.
None
Cool to 4ฐC and store in the
dark.
Packaging Requirements
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Wipe outside of each container clean
using a damp, then dry cloth. Seal the
container with non-reactive tape or film.
Wrap glass containers with bubble wrap.
Pack samples as described in Footnote
(4).
Shipping Label121
Standard carrier
shipping label AND
Trimethyl phosphite, 3,
Flammable, UN2329
Standard carrier
shipping label AND
Trinitrobenzene and
trinitrotoluene
mixtures, 1.1,
Explosive, UN0388
Standard carrier
shipping label AND
Trinitrobenzene and
trinitrotoluene
mixtures, 1.1,
Explosive, UN0388
Standard carrier
shipping label AND
Vanadium pentoxide,
6.1, Poison, UN2862
Standard carrier
shipping label AND
Phosphorus, white
(dry or wetted), 4.2,
Spontaneously
combustible, 6.1,
Poison, UN1381
Source/SAM
Method'31
Ch. 4 / 3541 /
3545A / 8270D
(EPASW-846)
[SAM Tier III]
Ch. 4 / 8330B
(EPASW-846)
[SAM Tier I]
Ch. 4 / 8330B
(EPASW-846)
[SAM Tier I]
3050B/6010C/
6020A
(EPASW-846)
[SAM Tier I]
7580
(EPASW-846)
[SAM Tier I]
Sample Collection Information Document
A4-20
September 2014
-------
Wipe Samples
Analyte
Acephate
Acrylamide
Acrylonitrile
Aldicarb (Temik)
Aldicarb sulfone
Aldicarb sulfoxide
Ally] alcohol
4-Aminopyridine
Ammonia
Ammonium
metavanadate
(analyze as total
vanadium)
Sample Size111
TBD
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
Sample Container
250 mL PTFE centrifuge
tube
250 mL wide-mouth
glass container with
PTFE-lined septa or lid
250 mL wide-mouth
glass container with
PTFE-lined septa or lid
Clear, wide mouth glass
jar with PTFE-lined lid
Clear, wide mouth glass
jar with PTFE-lined lid
Clear, wide mouth glass
jar with PTFE-lined lid
Holding Time
Analyze immediately or
store at negative (-)
18ฐC.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within 7
days of collection;
analyze within 40 days
of extraction.
Extract samples within 7
days of collection;
analyze within 40 days
of extraction.
Extract samples within 7
days of collection;
analyze within 40 days
of extraction.
Sample Preservation or
Preparation
Cool to < 6ฐC.
Cool to < 6ฐC.
Cool to < 6ฐC.
Store at 4 (ฑ2)ฐC and out of
direct sunlight.
Store at 4 (ฑ2)ฐC and out of
direct sunlight.
Store at 4 (ฑ2)ฐC and out of
direct sunlight.
Packaging Requirements
TBD
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label121
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Acrylamide, solid, 6.1,
Poison, UN2074
Standard carrier
shipping label AND
Acrylonitrile, stabilized,
3, Flammable liquid, 6.1,
Poison, UN1093
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1, UN2757
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1, UN2757
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1, UN2757
Source/SAM
Method'31
Adapted from Journal
of Chromatography A,
11 54(1): 3-25
[SAM Tier III]
Ch. 4/3570 /8290A
Appendix A/ 831 6
(EPA SW-846)
[SAM Tier III]
Ch. 4/3570 /8290A
Appendix A / 8260C
(EPA SW-846)
[SAM Tier III]
Ch. 4/3570 /8290A
Appendix A/ 831 8A
(EPA SW-846)
[SAM Tier III]
Ch. 4/3570 /8290A
Appendix A/ 831 8A
(EPA SW-846)
[SAM Tier III]
Ch. 4/3570 /8290A
Appendix A/ 831 8A
(EPA SW-846)
[SAM Tier III]
Not of concern in this sample type
1 wipe/1 00cm2
or
1 wipe/ft2
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined septa
or lids are not available,
solvent rinsed aluminum
foil may be used as a
liner.
Extract samples within 7
days of collection;
analyze within 40 days
of extraction.
Store samples and extracts at <
4ฐC in the dark. After air drying,
soil and solid samples can be
stored at room tem/ature.
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Aminopyridines, 6.1,
Poison, UN2671
Ch. 4/3570 /8290A
Appendix A / 8330B
(EPA SW-846)
[SAM Tier III]
Not of concern in this sample type
TBD
PTFE, plastic or glass. If
using 6020A, only PTFE
orfluorocarbon
containers are
recommended, (special
cleaning needed).'11'
Digest samples as soon
as possible after arrival;
analyze within 180 days
of digestion.
None
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Ammonium
metavanadate, 6.1 ,
Poison, UN2859
Ch. 3/9102(NIOSH)
/ 6010C/6020A
(EPA SW-846)
[SAM Tier I]
Sample Collection Information Document
A5- 1
September 2014
-------
Wipe Samples
Analyte
Arsenic, Total
Arsenic trioxide
(analyze as total
arsenic)
Arsine'51
(analyze as total
arsenic in non-air
samples)
Asbestos
Boron trifluoride
Brodifacoum
Bromadiolone151
Calcium arsenate
(analyze as total
arsenic)
Carbofuran
(Furadan)
Carbon disulfide
Sample Size111
TBD
TBD
TBD
1 particle-free
wipe/1 00 cm2
Sample Container
PTFE, plastic or glass. If
using 6020A only PTFE
or fluorocarbon
containers are
recommended, (special
cleaning needed).'11'
PTFE, plastic or glass. If
using 6020A only PTFE
or fluorocarbon
containers are
recommended, (special
cleaning needed).'11'
PTFE, plastic or glass. If
using 6020A only PTFE
or fluorocarbon
containers are
recommended, (special
cleaning needed).'11'
Clean, sealable
container
Holding Time
Digest samples as soon
as possible after arrival;
analyze within 180 days
of digestion.
Digest samples as soon
as possible after arrival;
analyze within 180 days
of digestion.
Digest samples as soon
as possible after arrival;
analyze within 180 days
of digestion.
None
Sample Preservation or
Preparation
None
None
None
None
Packaging Requirements
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label121
Standard carrier
shipping label AND
Arsenic, 6.1, Poison,
UN1558
Standard carrier
shipping label AND
Arsenic trioxide, 6.1,
Poison, UN1561
Standard carrier
shipping label AND
Arsine, 2.3(2.1),
Poisonous gas, UN2188
Standard carrier
shipping label
Source/SAM
Method'31
9102(NIOSH)/Ch. 3
/6010C/6020A
(EPA SW-846)
[SAM Tier I]
9102(NIOSH)/Ch. 3
/6010C/6020A
(EPA SW-846)
[SAM Tier I]
9102(NIOSH)/6010C
/ 6020A
(EPA SW-846)
[SAM Tier I]
D6480-05 (hard
surfaces-wipes)
(ASTM)
[SAM Tier I]
Not of concern in this sample type
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
TBD
1 wipe/1 00cm2
or
1 wipe/ft2
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
PTFE, plastic or glass. If
using 6020A only PTFE
or fluorocarbon
containers are
recommended, (special
cleaning needed).'11'
Clear, wide mouth glass
jar with PTFE-lined lid
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Digest samples as soon
as possible after arrival;
analyze within 180 days
of digestion.
Extract samples within 7
days of collection;
analyze within 40 days
of extraction.
Cool to < 6ฐC.
Cool to < 6ฐC.
None
Store at 4 (ฑ2)ฐC and out of
direct sunlight.
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Coumarin derivative
pesticides, solid, toxic,
6.1, Poison, UN3026
Standard carrier
shipping label AND
Coumarin derivative
pesticides, solid, toxic,
6.1, Poison, UN3026
Standard carrier
shipping label AND
Calcium arsenate, 6.1,
Poison, UN1573
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1, UN2757
Ch. 4/3570 /8290A
Appendix A
(EPA SW-846)
[SAM Tier III]
Ch. 4/3570 /8290A
Appendix A/ 8321 B
(EPA SW-846)
[SAM Tier III]
9102(NIOSH)/Ch. 3
/6010C/6020A
(EPA SW-846)
[SAM Tier I]
Ch. 4/3570 /8290A
Appendix A/ 831 8A
(EPA SW-846)
[SAM Tier III]
Not of concern in this sample type
Sample Collection Information Document
A5-2
September 2014
-------
Wipe Samples
Analyte
Car fen tan il
Chlorfenvinphos
Chlorine
2-Chloroethanol
3-Chloro-1,2-
propanediol151
Chloropicrin'5'
Chlorpyrifos
Chlorpyrifos oxon
Sample Size111
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
Sample Container
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Holding Time
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Sample Preservation or
Preparation
Cool to < 6ฐC.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Packaging Requirements
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label121
Standard carrier
shipping label
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Source/SAM
Method'31
Ch. 4/3570 /8290A
Appendix A/ 8321 B
(EPA SW-846)
[SAM Tier III]
Ch. 4/3570 /8290A
Appendix A / 8270D
(EPA SW-846)
[SAM Tier 1 1]
Not of concern in this sample type
Not of concern in this sample type
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4). (Air-tight
container containing activated carbon)
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label
Standard carrier
shipping label AND
Chloropicrin, 6.1,
Poison, UN1580
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Eur. J. Lipid Sci.
Technol. 2011, 113-
345-355
[SAM Tier III]
Ch. 4/3570 /8290A
Appendix A / 8270D
(EPA SW-846)
[SAM Tier 1 1]
Ch. 4/3570 /8290A
Appendix A / 8270D
(EPA SW-846)
[SAM Tier 1 1]
Ch. 4/3570 /8290A
Appendix A / 8270D
(EPA SW-846)
[SAM Tier III]
Sample Collection Information Document
A5-3
September 2014
-------
Wipe Samples
Analyte
Crimidine151
Cyanide, Amenable
to chlorination
Cyanide, Total
Cyanogen chloride151
1,2-Dichloroethane
(degradation product
ofHD)
Dichlorvos
Dicrotophos
Diesel Range
Organics
Sample Size111
1 wipe/1 00cm2
or
1 wipe/ft2
TBD
TBD
Sample Container
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Glass or polyethylene
bottle (1 L size)
Glass or polyethylene
bottles
Holding Time
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
1 4 days
12 days after sample
receipt.
Sample Preservation or
Preparation
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Cool to 4ฐC.
Protect from light and ice or
refrigerate at 4 (ฑ2)ฐC from
collection until digestion. Add
0.6 g of asorbic acid for each liter
of sample volume.
Packaging Requirements
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4). (Air-tight
container containing activated carbon)
Shipping Label121
Standard carrier
shipping label
Standard carrier
shipping label AND
Cyanide inorganic solid
n.o.s, 6.1, Poison,
UN1588
Standard carrier
shipping label AND
Cyanides, inorganic,
solid, n.o.s, 6.1, Poison,
UN1588
Source/SAM
Method'31
Ch. 4/3570 /8290A
Appendix A / 8270D
(EPA SW-846)
[SAM Tier II]
3135.21
(EPA Regional Lab)
[SAM Tier III]
ISM 01. 3 CN
(EPA CLP)
[SAM Tier III]
Not of concern in this sample type
Not of concern in this sample type
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Cool to < 6ฐC.
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label
Ch. 4/3570 /8290A
Appendix A / 8270D
(EPA SW-846)
[SAM Tier 1 1]
Ch. 4/3570 /8290A
Appendix A / 8270D
(EPA SW-846)
[SAM Tier 1 1]
Ch. 4/3570 /8290A
Appendix A/ 801 5C
(EPA SW-846)
[SAM Tier I]
Sample Collection Information Document
A5-4
September 2014
-------
Wipe Samples
Analyte
Diisopropyl methyl-
phosphonate (DIMP)
(degradation product
ofGB)(51
Dimethyl-phosphite151
Dimethyl-
phosphoramidic acid
(degradation product
ofGAf1
Diphacinone
Disulfoton
Disulfoton sulfone
oxon
Sample Size111
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
Sample Container
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Holding Time
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Sample Preservation or
Preparation
Cool to < 6ฐC.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Cool to < 6ฐC.
Cool to < 6ฐC.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Packaging Requirements
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4). (Air-tight
container containing activated carbon)
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label121
Standard carrier
shipping label
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, solid,
n.o.s, 6.1, Poison,
UN3464
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, solid,
n.o.s, 6.1, Poison,
UN3464
Standard carrier
shipping label AND
Coumarin derivative
pesticides, solid, toxic,
6.1, Poison, UN3026
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Source/SAM
Method'31
Ch. 4/3570 /8290A
Appendix A/ 8321 B
(EPA SW-846)
[SAM Tier 1 1]
Ch. 4/3570 /8290A
Appendix A / 8270D
(EPA SW-846)
[SAM Tier 1 1]
Ch. 4/3570 /8290A
Appendix A/ 8321 B
(EPA SW-846)
[SAM Tier III]
Ch. 4/3570 /8290A
Appendix A/ 8321 B
(EPA SW-846)
[SAM Tier III]
Ch. 4/3570 /8290A
Appendix A / 8270D
(EPA SW-846)
[SAM Tier 1 1]
Ch. 4/3570 /8290A
Appendix A / 8270D
(EPA SW-846)
[SAM Tier III]
Sample Collection Information Document
A5-5
September 2014
-------
Wipe Samples
Analyte
Disulfoton sulfoxide
Disulfoton sulfoxide
oxon
1,4-Dithiane
(degradation product
of HD)(S|
EA2192
[S-2-(diisopropyl
amino) ethylmethyl
phosphonothioic
acid] (hydrolysis
product of VX)(S|
Ethyl methyl
phosphonic acid
(EMPA)
(degradation product
Ethyl-
dichloroarsine (ED)(S|
N-Ethyldiethanol-
amine (EDEA)
(degradation product
of HN-1 f}
Sample Size111
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
TBD
2 wipes/1 00 cm2
Sample Container
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
125 mL polypropylene
straight-side jar with a
polypropylene screw cap
Holding Time
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Samples should be
extracted and analyzed
within 48 hours of
collection or as soon as
possible.
Sample Preservation or
Preparation
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Cool to < 6ฐC.
Cool to < 6ฐC.
Cool to < 6ฐC.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Cool to < 6ฐC.
Packaging Requirements
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
TBD(7)
Air-tight container containing activated
carbon
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label121
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label. See
Footnote (2) when
adding liquid
preservatives such as
methanol or bisulfate
TBD(7)
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, solid,
n.o.s, 6.1, Poison,
UN3464
Standard carrier
shipping label AND
Ethyldichloroarsine, 6.1,
Poison, UN1892
Standard carrier
shipping label
Source/SAM
Method'31
Ch. 4/3570 /8290A
Appendix A / 8270D
(EPA SW-846)
[SAM Tier III]
Ch. 4/3570 /8290A
Appendix A / 8270D
(EPA SW-846)
[SAM Tier III]
Ch. 4/3570 /8290A
Appendix A / 8270D
(EPA SW-846)
[SAM Tier II]
Ch. 4/3570 /8290A
Appendix A/ 8321 B
(EPA SW-846)
[SAM Tier III]
Ch. 4/3570 /8290A
Appendix A/ 8321 B
(EPA SW-846)
[SAM Tier 1 1]
9102(NIOSH)/Ch. 4
/ 8270D
(EPA SW-846)
[SAM Tier III]
EPA 600/R-1 1/145
(EPA/NIOSH)
[SAM Tier 1 1]
Sample Collection Information Document
A5-6
September 2014
-------
Wipe Samples
Analyte
Ethylene oxide
Fenamiphos'5'
Fentanyl
Fluoride
Fluoroacetamide
Fluoroacetic acid
and fluoroacetate
salts (analyze as
fluoroacetate ion)'5'
2-Fluoroethanol
Formaldehyde
Gasoline Range
Organics
Sample Size111
Sample Container
Holding Time
Sample Preservation or
Preparation
Packaging Requirements
Shipping Label121
Source/SAM
Method'31
Not of concern in this sample type
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Cool to < 6ฐC.
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label
Ch. 4/3570 /8290A
Appendix A / 8270D
(EPA SW-846)
[SAM Tier II]
Ch. 4/3570 /8290A
Appendix A/ 8321 B
(EPA SW-846)
[SAM Tier III]
Not of concern in this sample type
TBD
1 wipe/1 00cm2
or
1 wipe/ft2
TBD
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
TBD
Analyze samples within
7 days.
TBD
Cool to 4ฐC.
TBD
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label
Standard carrier
shipping label
Adapted from Journal
of Chromatography B,
876(1):103-108
[SAM Tier III]
J. Chrom. A, 1139
(2007)271-278
[SAM Tier III]
Not of concern in this sample type
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
40 mL VOA vial (with
septum) and magnetic
stirring bar
Extract and analyze
within 30 days of
collection. All derivatized
sample extracts should
be analyzed within 3
days after preparation.
1 4 days
Cool to 4ฐC.
Cool to 4ฐC.
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Formaldehyde
(concentration
dependent, refer to 40
CFR172.101 for more
information).
Standard carrier AND
Gasoline identification
set, 2.3, Poison gas,
NA9035. See Footnote
(2) when adding liquid
preservatives such as
methanol or bisulfate.
Ch. 4/3570 /8290A
Appendix A/ 831 5A
(EPA SW-846)
[SAM Tier III]
Ch. 4/3570 /8290A
Appendix A/ 801 5C
(EPA SW-846)
[SAM Tier I]
Sample Collection Information Document
A5-7
September 2014
-------
Wipe Samples
Analyte
Hexahydro-1,3,5-
trinitro-1 ,3,5-triazine
(RDX)
Hexamethylene-
triperoxidediamine
(HMTD)'51
Hydrogen bromide
Hydrogen chloride
Hydrogen cyanide
Hydrogen fluoride
Hydrogen sulfide
Isopropyl methyl-
phosphonic acid
(IMPA) (degradation
product of GB)'51
Kerosene'51
Lead arsenate
(analyze as total
arsenic)
Lewisite oxide
(degradation product
of Lewisite)'51
(analyze as total
arsenic)
Sample Size'11
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
Sample Container
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Holding Time
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Sample Preservation or
Preparation
Store samples and extracts at <
4ฐC in the dark. After air drying,
soil and solid samples can be
stored at room tem/ature.
Store samples and extracts at <
4ฐC in the dark. After air drying,
soil and solid samples can be
stored at room tem/ature.
Packaging Requirements
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label'21
Standard carrier
shipping label AND
RDX, 1.1, Explosive,
UN0483
Forbidden
Source/SAM
Method'31
Ch. 4/3570 /8290A
Appendix A / 8330B
(EPA SW-846)
[SAM Tier 1]
Ch.4/3570/8290A
Appendix A / 8330B
(EPA SW-846) /
Adapted from Analyst
(2001)
126:1689-1693
[SAM Tier III]
Not of concern in this sample type
Not of concern in this sample type
Not of concern in this sample type
Not of concern in this sample type
Not of concern in this sample type
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
TBD
TBD
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
40-mL VOA vial (with
septum) and magnetic
stirring bar
PTFE, plastic or glass. If
using 6020A, only PTFE
orfluorocarbon
containers are
recommended, (special
cleaning needed).'11'
PTFE, plastic or glass. If
using 6020A, only PTFE
orfluorocarbon
containers are
recommended, (special
cleaning needed).'11'
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
1 4 days
Digest samples as soon
as possible after arrival;
analyze within 180 days
of digestion.
Minimize transport and
storage time; if feasible,
analyze or extract
immediately upon receipt
at the laboratory.
Cool to < 6ฐC.
Cool to 4ฐC.
None
None
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, solid,
n.o.s, 6.1, Poison,
UN3464
Standard carrier
shipping label AND
Kerosene, 3,
Flammable, UN1 223.
See Footnote (2) when
adding liquid
preservatives such as
methanol or bisulfate.
Standard carrier
shipping label AND
Lead arsenate, 6.1,
Poison, UN1617
Standard carrier
shipping label AND
Arsenic compounds,
solid, n.o.s, 6.1, Poison,
UN1557
Ch. 4/3570 /8290A
Appendix A/ 8321 B
(EPA SW-846)
[SAM Tier 1 1]
Ch. 4/3570 /8290A
Appendix A/ 801 5C
(EPA SW-846)
[SAM Tier I]
9102(NIOSH)/Ch. 3
/6010C/6020A
(EPA SW-846)
[SAM Tier I]
9102(NIOSH)/Ch. 3
/6010C/6020A
(EPA SW-846)
[SAM Tier I]
Sample Collection Information Document
A5-8
September 2014
-------
Wipe Samples
Analyte
Mercuric chloride
(analyze as total
mercury)
Mercury, Total
Methamidophos
Methomyl
Methoxyethyl-
mercuric acetate
(analyze as total
mercury)151
Methyl acrylonitrile
Methyl fluoroacetate
(analyze as
fluoroacetate ion)'5'
Methyl hydrazine151
Methyl isocyanate
Sample Size111
TBD
TBD
TBD
1 wipe/1 00cm2
or
1 wipe/ft2
TBD
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
Sample Container
PTFE, plastic or glass
PTFE, plastic or glass
250 mL PTFE centrifuge
tube
Clear, wide mouth glass
jar with PTFE-lined lid
PTFE, plastic or glass
250 mL wide-mouth
glass container with
PTFE-lined septa or lid
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Holding Time
28 days
28 days
Analyze immediately or
store at negative (-) 18 C
Extract samples within 7
days of collection;
analyze within 40 days
of extraction.
28 days
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Analyze samples within
7 days.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Sample Preservation or
Preparation
None
None
TBD
Store at 4 (ฑ2)ฐC and out of
direct sunlight.
None
Cool to < 6ฐC.
Cool to 4ฐC.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Packaging Requirements
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
TBD
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label121
Standard carrier
shipping label AND
Mercuric chloride, 6.1,
Poison, UN1624
Standard carrier
shipping label AND
Mercury, 8, Corrosive,
UN2809
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1, UN2757
Standard carrier
shipping label AND
Mercury compounds,
solid, n.o.s, 6.1, Poison,
UN2025
Standard carrier
shipping label AND
Methyl acryonitrile, 3.0,
Flammable Liquid, 6.1,
Poison, UN3079
Standard carrier
shipping label
Standard carrier
shipping label AND
Methyl hydrazine, 6.1 ,
Poison, UN1244
Source/SAM
Method'31
Ch. 3/9102(NIOSH)
/7473
(EPA SW-846)
[SAM Tier I]
Ch.3/9102(NIOSH)
/7473
(EPA SW-846)
[SAM Tier I]
Adapted from Journal
of Chromatography A,
11 54(1): 3-25
[SAM Tier III]
Ch. 4/3570/8290
Appendix A/ 831 8A
(EPA SW-846)
[SAM Tier III]
Ch. 3/9102(NIOSH)
/7473
(EPA SW-846)
[SAM Tier I]
Ch. 4/3570/8290
Appendix A / 8260C
(EPA SW-846)
[III]
Adapted from J.
ChromA, 1139(2007)
271-278
[SAM Tier III]
Ch. 4/3570/8290
Appendix A / 8270D
(EPA SW-846) /
J. Chrom. 1993(617),
157-162
[SAM Tier III]
Not of concern in this sample type
Sample Collection Information Document
A5-9
September 2014
-------
Wipe Samples
Analyte
Methyl paraoxon
Methyl parathion
Methylamine
N-Methyl-
diethanolamine
(MDEA) (degradation
product of HN-2)(S|
Methyl -
phosphonic acid
(MPA)
(degradation product
ofVX, GB, &GD)(S|
Mevinphos
Monocrotophos
Sample Size111
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
Sample Container
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Holding Time
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Sample Preservation or
Preparation
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Packaging Requirements
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label121
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Source/SAM
Method'31
Ch. 4/3570/8290
Appendix A / 8270D
(EPA SW-846)
[SAM Tier III]
Ch. 4/3570/8290
Appendix A / 8270D
(EPA SW-846)
[SAM Tier II]
Not of concern in this sample type
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
125 mL polypropylene
straight-side jar with a
polypropylene screw cap
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Samples should be
extracted and analyzed
within 48 hours of
collection or as soon as
possible.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Cool to < 6ฐC.
Cool to < 6ฐC.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, solid,
n.o.s, 6.1, Poison,
UN3464
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
EPA600/R-11/114
(EPA/NIOSH)
[SAM Tier 1 1]
Ch. 4/3570/8290
Appendix A/ 8321 B
(EPA SW-846)
[SAM Tier 1 1]
Ch. 4/3570/8290
Appendix A / 8270D
(EPA SW-846)
[SAM Tier 1 1]
Ch. 4/3570/8290
Appendix A / 8270D
(EPA SW-846)
[SAM Tier III]
Sample Collection Information Document
A5-10
September 2014
-------
Wipe Samples
Analyte
Nicotine compounds
(analyze as nicotine)
Octahydro-1, 3,5,7-
tetranitro-1, 3,5,7-
tetrazocine (HMX)
Osmium tetraoxide
(analyze as total
osmium)151
Oxamyl
Paraoxon
Paraquat
Parathion
Sample Size111
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
TBD
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
Sample Container
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
PTFE, plastic or glass. If
using 6020A, only PTFE
orfluorocarbon
containers are
recommended, (special
cleaning needed).'11'
Clear, wide mouth glass
jar with PTFE-lined lid
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Clear, wide mouth glass
jar with PTFE-lined lid
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Holding Time
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Digest samples as soon
as possible after arrival;
analyze within 180 days
of digestion.
Extract samples within 7
days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Analyze samples within
7 days.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Sample Preservation or
Preparation
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Store samples and extracts at <
4ฐC in the dark. After air drying,
soil and solid samples can be
stored at room tem/ature.
None
Store at 4 (ฑ2)ฐC and out of
direct sunlight.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Cool to 4ฐC.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Packaging Requirements
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Place filter in protective covering. Place
protected filter in double plastic bags, and
wrap with bubble wrap. Pack samples as
described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label121
Standard carrier
shipping label AND
Nicotine compounds,
solid, n.o.s, 6.1, Poison,
UN1655
Standard carrier
shipping label
Standard carrier
shipping label AND
Osmium tetroxide, 6.1 ,
Poison, UN2471
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1, UN2757
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Fluoroacetic acid, 6.1 ,
Poison, UN2642
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Source/SAM
Method'31
Ch. 4/3570/8290
Appendix A / 8270D
(EPA SW-846)
[SAM Tier II]
Ch. 4/3570/8290
Appendix A / 8330B
(EPA SW-846)
[SAM Tier 1]
9102(NIOSH)/Ch. 3
/6010C
(EPA SW-846)
[SAM Tier III]
Ch. 4/3570/8290
Appendix A/ 831 8A
(EPA SW-846)
[SAM Tier III]
Ch. 4/3570/8290
Appendix A / 8270D
(EPA SW-846)
[SAM Tier III]
J. Chrom A, 1139
(2007)271-278
[SAM Tier III]
Ch. 4/3570/8290
Appendix A / 8270D
(EPA SW-846)
[SAM Tier 1 1]
Sample Collection Information Document
A5-11
September 2014
-------
Wipe Samples
Analyte
Pentaerythritol
tetranitrate (PETN)
Phencyclidine
Phorate
Phorate sulfone
Phorate sulfone
oxon
Phorate sulfoxide
Sample Size111
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
Sample Container
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined septa
or lids are not available,
solvent rinsed aluminum
foil may be used as a
liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Holding Time
Extract samples within 7
days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Sample Preservation or
Preparation
Store samples and extracts at <
4ฐC in the dark. After air drying,
soil and solid samples can be
stored at room tem/ature.
Cool to < 6ฐC.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Packaging Requirements
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label121
Forbidden
Standard carrier
shipping label
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Source/SAM
Method'31
Ch. 4/3570/8290
Appendix A / 8330B
(EPA SW-846)
[SAM Tier 1]
Ch. 4/3570/8290
Appendix A / 8270D
(EPA SW-846)
[SAM Tier II]
Ch. 4/3570/8290
Appendix A / 8270D
(EPA SW-846)
[SAM Tier II]
Ch. 4/3570/8290
Appendix A / 8270D
(EPA SW-846)
[SAM Tier III]
Ch. 4/3570/8290
Appendix A / 8270D
(EPA SW-846)
[SAM Tier III]
Ch. 4/3570/8290
Appendix A / 8270D
(EPA SW-846)
[SAM Tier III]
Sample Collection Information Document
A5-12
September 2014
-------
Wipe Samples
Analyte
Phorate sulfoxide
oxon
Phosgene
Phosphamidon
Phosphine
Phosphorus
trichloride
Pinacolyl methyl
phosphonic acid
(PMPA) (degradation
product of GD)'51
Propylene oxide151
Sodium arsenite
(analyze as total
arsenic)'51
Sodium azide
(analyze as azide ion)
Strychnine
Sample Size111
1 wipe/1 00cm2
or
1 wipe/ft2
Sample Container
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Holding Time
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Sample Preservation or
Preparation
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Packaging Requirements
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label'21
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Source/SAM
Method'31
Ch. 4/3570/8290
Appendix A / 8270D
(EPA SW-846)
[SAM Tier III]
Not of concern in this sample type
1 wipe/1 00cm2
or
1 wipe/ft2
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Ch. 4/3570/8290
Appendix A / 8270D
(EPA SW-846)
[SAM Tier II]
Not of concern in this sample type
Not of concern in this sample type
1 wipe/1 00cm2
or
1 wipe/ft2
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Cool to < 6ฐC.
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, solid,
n.o.s, 6.1, Poison,
UN3464
Ch. 4/3570/8290
Appendix A/ 8321 B
(EPA SW-846)
[SAM Tier 1 1]
Not of concern in this sample type
TBD
TBD
1 wipe/1 00cm2
or
1 wipe/ft2
PTFE, plastic or glass. If
using 6020A, only PTFE
orfluorocarbon
containers are
recommended, (special
cleaning needed).'11'
Filter / Sorbent tube
(PVC or quartz filter with
silica coated sorbent
[150mg/75mg])
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Digest samples as soon
as possible after arrival;
analyze within 180 days
of digestion.
Analyze samples stored
at room tem/ature within
10 days.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
None
Refrigerate when not in transit.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
TBD
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Sodium arsenite, solid,
6.1, Poison, UN2027
Standard carrier
shipping label AND
Sodium azide, 6.1,
Poison, UN1687
Standard carrier
shipping label AND
Strychnine, 6.1, Poison,
UN1692
9102(NIOSH)/Ch. 3
/6010C/6020A
(EPA SW-846)
[SAM Tier I]
ID-211
(OSHA)
[SAM Tier I]
Ch. 4/3570/8290
Appendix A / 8270D
(EPA SW-846)
[SAM Tier 1 1]
Sample Collection Information Document
A5- 13
September 2014
-------
Wipe Samples
Analyte
Tetraethyl
pyrophosphate'5'
(TEPP)
Tetramethylene
disulfotetramine
(5)
(TETS)
Thallium sulfate
(analyze as total
thallium)
Thiodiglycol (TDG)
(degradation product
of HD)'51
Thiofanox
1,4-Thioxane
(degradation product
of HD)'51
Titanium
tetrachloride
(analyze as total
titanium)151
Sample Size111
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
TBD
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
TBD
Sample Container
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
PTFE, plastic or glass. If
using 6020A, only PTFE
orfluorocarbon
containers are
recommended, (special
cleaning needed).'11'
70 mL VOA vial with
PTFE-lined cap
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
PTFE, plastic or glass. If
using 6020A, only PTFE
orfluorocarbon
containers are
recommended, (special
cleaning needed).'11'
Holding Time
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Digest samples as soon
as possible after arrival;
analyze within 180 days
of digestion.
Extract and analyze
within 7 days of sample
collection.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Digest samples as soon
as possible after arrival;
analyze within 180 days
of digestion.
Sample Preservation or
Preparation
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
None
Cool between 0ฐC and 6ฐC. .
Cool to < 6ฐC.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
None
Packaging Requirements
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4). (Air-tight
container containing activated carbon)
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4). (Air-tight
container containing activated carbon)
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label121
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Standard carrier
shipping label AND
Pesticides, solid, toxic,
n.o.s, 6.1, Poison,
UN2588
Standard carrier
shipping label AND
Thallium compounds
n.o.s, 6.1, Poison,
UN1707
Standard carrier
shipping label AND
Aviation regulated solid,
n.o.s, UN3335
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1, UN2757
Standard carrier
shipping label AND
Flammable Liquids,
n.o.s, 3, Flammable,
UN1993
Standard carrier
shipping label AND
Titanium tetrachloride,
8, Corrosive, UN1838
Source/SAM
Method'31
Ch. 4/3570/8290
Appendix A / 8270D
(EPA SW-846)
[SAM Tier II]
Ch. 4/3570/8290
Appendix A / 8270D
(EPA SW-846)
[SAM Tier II]
9102(NIOSH)/Ch. 3
/6010C/6020A
(EPA SW-846)
[SAM Tier I]
Ch. 4/3570/8290
Appendix A/ 8321 B
(EPA SW-846)
[SAM Tier 1 1]
Ch. 4/3570/8290
Appendix A/ 8321 B
(EPA SW-846)
[III]
Ch. 4/3570/8290
Appendix A / 8270D
(EPA SW-846)
[SAM Tier 1 1]
9102(NIOSH)/Ch. 3
/6010C/6020A
(EPA SW-846)
[SAM Tier III]
Sample Collection Information Document
A5-14
September 2014
-------
Wipe Samples
Analyte
Triethanolamine
(TEA) (degradation
product of HN-3)'51
Trimethyl
phosphite'51
1 ,3,5-Trinitrobenzene
(1,3,5-TNB)
2,4,6-Trinitrotoluene
(2,4,6-TNT)
Vanadium pentoxide
(analyze as total
vanadium)
White phosphorus
Sample Size111
2 wipes/1 00 cm2
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
1 wipe/1 00cm2
or
1 wipe/ft2
TBD
1 wipe/1 00cm2
or
1 wipe/ft2
Sample Container
125 mL polypropylene
straight-side jar with a
polypropylene screw cap
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined septa
or lids are not available,
solvent rinsed aluminum
foil may be used as a
liner.
Amber glass or PTFE
container with PTFE-
lined septum or lid.
When PTFE-lined septa
or lids are not available,
solvent rinsed aluminum
foil may be used as a
liner.
PTFE, plastic or glass. If
using 6020A, only PTFE
orfluorocarbon
containers are
recommended, (special
cleaning needed).'11'
Wide mouth glass or
PTFE container with
PTFE-lined septum or
lid. When PTFE-lined
septa or lids are not
available, solvent rinsed
aluminum foil may be
used as a liner.
Holding Time
Samples should be
extracted and analyzed
within 48 hours of
collection or as soon as
possible.
Extract samples within
14 days of collection;
analyze within 40 days
of extraction.
Extract samples within 7
days of collection;
analyze within 40 days
of extraction.
Extract samples within 7
days of collection;
analyze within 40 days
of extraction.
Digest samples as soon
as possible after arrival;
analyze within 180 days
of digestion.
Soil / sediment samples
can be held indefinitely if
sealed tightly to
eliminate moisture loss.
Extracts with isooctane
should be analyzed
within 30 days.
Sample Preservation or
Preparation
Cool to < 6ฐC.
Cool samples to < 6ฐC and store
extracts at negative (-) 10ฐC in
the dark.
Store samples and extracts at <
4ฐC in the dark. After air drying,
soil and solid samples can be
stored at room tem/ature.
Store samples and extracts at <
4ฐC in the dark. After air drying,
soil and solid samples can be
stored at room tem/ature.
None
Cool to 4ฐC and store in the
dark.
Packaging Requirements
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Wipe outside of each container clean using
a damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Shipping Label'21
Standard carrier
shipping label AND
Ethanolamine solutions,
8, Corrosive, UN2491
Standard carrier
shipping label AND
Trimethyl phosphite, 3,
Flammable, UN2329
Standard carrier
shipping label AND
Trinitrobenzene and
trinitrotoluene mixtures,
1.1, Explosive, UN0388
Standard carrier
shipping label AND
Trinitrobenzene and
trinitrotoluene mixtures,
1.1, Explosive, UN0388
Standard carrier
shipping label AND
Vanadium pentoxide,
6.1, Poison, UN2862
Standard carrier
shipping label AND
Phosphorus, white (dry
or wetted), 4.2,
Spontaneously
combustible, 6.1,
Poison, UN1381
Source/SAM
Method'31
EPA600/R-11/114
(EPA/NIOSH)
[SAM Tier 1 1]
Ch. 4/3570/8290
Appendix A / 8270D
(EPA SW-846)
[SAM Tier III]
Ch. 4/3570/8290
Appendix A / 8330B
(EPA SW-846)
[SAM Tier I]
Ch. 4/3570/8290
Appendix A / 8330B
(EPA SW-846)
[SAM Tier I]
9102(NIOSH)/Ch. 3
/6010C/6020A
(EPA SW-846)
[SAM Tier I]
Ch. 4/3570/8290
Appendix A / 7580
(EPA SW-846)
[SAM Tier III]
Sample Collection Information Document
A5-15
September 2014
-------
Footnotes:
(1) Sample sizes are based on a range covering the minimum amount needed for analysis of a single sample up to additional sample amounts that may be requested or needed for laboratory quality control
analyses (e.g., duplicates, matrix spikes) or for measurement of low analyte concentrations. It is also recommended that additional samples be collected in case of the need for reanalysis due to sample
spillage or unforseen analytical difficulties. Where possible, sample sizes are based on specifications included in the SAM analytical methods. Wipe sample areas are based on U.S. Office of Research and
Development, "A Literature Review of Wipe Sampling Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
(2) Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping
carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301),
appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase
"Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 2.1 or Division 2.3. Exception quantities include:
Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
Exception for Class 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 Ibs) of solid (49 CFR 173.153)
Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 Ibs) of solid (49 CFR 173.154)
Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to
contain >12% of energetic material residues, ship and label according to DOT requirements for secondary explosive materials.
(3) SAM methods listed in this column can be located using U.S. Environmental Protection Agency, National Homeland Security Research Center (NHSRC), Selected Analytical Methods for Environmental
Remediation and Recovery (SAM), 2012.
(4) Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample
preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed
preservation requirements. If the target analytes are unknown, samples should be maintained atฃ 4ฐC, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid
leakage, and the bags placed around, among, and on top of the sample containers.
(5) Currently, no information is available for this analyte in this matrix. Until such time that analyte-specific information is available, collection procedures described for a similar analyte are considered to be
appropriate.
(6) This method applies to ambient concentrations of VOCs above 0.5 ppbv and typically requires VOC enrichment by concentrating up to 1 L of sample volume; however, when using current technologies,
quantifications of approximately 100 pptv have been achieved with 0.5-L sample volumes.
(7) DOT regulations currently do not address labeling, packaging, and shipping of chemical warfare agents (CWAs) or this degradation product. Shipment of samples suspected of containing these compounds
should be determined by the overseeing regulatory authority and must be in compliance with U.S. Department of Defense and/or Department of Homeland Security regulations. Under current U.S. Army
regulations (AR 50-6, AR 385-61 and DA PAM 385-61), samples are analyzed and decontaminated on site, and are not removed until CWAs are no longer detected.
(8) In addition to the SAM method listed, the "Organisation for the Prohibition of Chemical Weapons, Quality System Documents" was also used as a source of information.
(9) Sodium thiosulfate or sodium sulfite should be added to treated drinking water or wastewater samples containing residual chlorine. For sodium thiosulfate, an amount equivalent to the following is
recommended: 3 mL of a 10% sodium thiosulfate solution per gallon of sample (or 0.008%). For sodium sulfite, an amount equivalent to the following is recommended: to 1-L sample, add 40 - 50 mg of solid
sodium sulfite with stiring or shaking. This solution can be added to the sample container prior to collection or after collection and prior to sample preservation.
(10) When samples are preserved with methanol or sodium bisulfate, quantity limitations apply. To avoid samples to be considered DOT hazardous material, ensure each container holds less than a net of 1 L (0.3
gal) of methanol or aqueous bisulfate. If these volumes are exceeded, the outer container must be marked as: "Methanol, 3, UN1230, Ltd Qty." In addition, a DOT label marked "Flammable Liquid, Class 3"
should be affixed to the outer container. In the case of sodium bisulfate preservative, the outer container also should be marked "Bisulfate, aqueous solution, 8, UN2837, Ltd Qty" and a DOT label marked
"Corrosive material, Class 8" is required.
(11) Use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1 hydrochloric acid:tap water, and reagent water.
(12) If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples
must be held for at least 24 hours prior to analysis.
(13) Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105ฐC oven for 1 hr, then remove and allow to cool in
an area known to be free of organics.
(14) An organic solid sample is a solid that completely dissolves in an organic solvent and leaves no solid residue.
Sample Collection Information Document A-Footnotes September 2014
-------
Attachment B
Sample Collection Information for the
Radiochemical Analytes and Methods
Listed in SAM 2012
-------
Attachment B: Sample Collection Information for the Radiochemical Analytes and Methods Listed in SAM 2012
Air Filters
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reative tape or film. Determine the radiation-specific activity of the sample(s) and
pack samples outside the contaminated area as described in Footnote (4).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote
(5).
Analyte
Gross Alpha
Gross Beta
Gamma
Select Mixed Fission
Products
Total Activity
Screening
Sample Size111
1 filter (limited to
counting geometry
size)
1 filter (limited to
counting geometry
size)
1 filter (limited to
counting geometry
size)
1 filter
Sample Container'2'
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Holding Time121
Maximum 6 months.
Maximum 170 days based on half-life
of
lr-192of 173 days.
Maximum 65 hours based on half-life
of Mo-99 of 65.94 hours.
Maximum 6 months.
Sample Preservative or Preparation!2'
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required.
Source/SAM Method13'
FRMAC, Vol. 2, pg. 33
(DOE)
FRMAC, Vol. 2, pg. 33
(DOE)
Ga-01-R
(HASL-300)
Preparation of Samples for
Total Activity Screening (Y-1 2)
Air Filters Qualitative Determination
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reative tape or film. Determine the radiation-specific activity of the sample(s) and
pack samples outside the contaminated area as described in Footnote (4).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote
(5).
Analyte
Americium-241
(alpha)
Plutonium-238
Plutonium-239
Radium-226
Uranium-238
Uranium-234
Uranium-235
Californium-252
Curium-244
Americium-241
(gamma)
Cesium-137
Cobalt-60
Europium-154
Ruthenium-103
Ruthenium-106
Sample Size111
1 filter
1 filter
1 filter
Sample Container121
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Holding Time'21
Maximum 6 months.
Maximum 6 months.
Maximum 6 months.
Sample Preservative or Preparation12'
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
Source/SAM Method'3'
Rapid Methods for Acid or
Fusion Digestion
(EPA)
D3084-05
(ASTM)
Ga-01-R
(HASL-300)
Sample Collection Information Document
B1 -1
September 2014
-------
Analyte
lodine-125
lodine-131
lridium-192
Molybdenum-99
Phosphorus-32
Polonium-210
Selenium-75
Strontium-89
Strontium-90
Technetium-99
Tritium
(Hydrogen-3)
Sample Size111
1 charcoal cartridge
Charcoal or silver
zeolite cartridge
1 filter
1 filter
1 filter
1 filter
1 filter
1 filter
1 filter
1 filter
Sample Container121
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Holding Time'21
Maximum 59 days based on half-life
of 1-1 25 of 59.4 days.
Maximum 8 days based on half-life of
-131 of 8.03 days.
Maximum 170 days based on half-life
of
lr-192of 173 days.
Maximum 65 hours based on half-life
of Mo-99 of 65.94 hours.
Maximum 14 days based on half-life
of P-32 of 14.26 days.
Maximum 6 months.
Maximum 120 days based on half-life
of
Se-75of 120 days.
Maximum 50 days based on half-life
of Sr-89 of 50.53 days.
Maximum 6 months.
Maximum 6 months.
Sample Preservative or Preparation!21
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
Source/SAM Method'31
Procedure #9(6)
(ORISE)
Ga-01-R(6)
(HASL-300)
Ga-01-R
(HASL-300)
Ga-01-R
(HASL-300)
RESL P-2
(DOE)
Method 1 1 1
(EPA)
Ga-01-R
(HASL-300)
Strontium in Food and
Bioenvironmental Samples
(EPA)
Rapid Methods for Acid or
Fusion Digestion
(EPA)
APS
(ORISE)
Not of concern in this sample type
Air Filters Confirmatory
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reative tape or film. Determine the radiation-specific activity of the sample(s) and
pack samples outside the contaminated area as described in Footnote (4).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote
(5).
Analyte
Americium-241
(alpha)
Californium-252
Curium-244
Sample Size111
1 filter
Sample Container121
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Holding Time'21
Maximum 6 months.
Sample Preservative or Preparation!2'
No preservation required. Analyze as is
without preparation.
Source/SAM Method'31
Am-04-RC
(HASL-300)
Sample Collection Information Document
B1 -2
September 2014
-------
Analyte
Americium-241
(gamma)
Cesium-137
Cobalt-60
Europium-154
Ruthenium-103
Ruthenium-106
lodine-125
lodine-131
lridium-192
Molybdenum-99
Phosphorus-32
Plutonium-238
Plutonium-239
Uranium-238
Uranium-234
Uranium-235
Polonium-210
Radium-226
Selenium-75
Strontium-89
Strontium-90
Technetium-99
Tritium
(Hydrogen-3)
Sample Size111
1 filter
1 charcoal cartridge
1 charcoal or silver
zeolite cartridge
1 filter
1 filter
1 filter
1 filter
1 filter
1 filter
1 filter
1 filter
1 filter
1 filter
Sample Container121
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Holding Time'21
Maximum 6 months.
Maximum 59 days based on half-life
of 1-1 25 of 59.4 days.
Maximum 8 days based on half-life of
1-131 of 8.03 days.
Maximum 170 days based on half-life
of lr-1 92 of 173 days.
Maximum 65 hours based on half-life
of Mo-99 of 65.94 hours.
Maximum 14 days based on half-life
of P-32 of 14.26 days.
Maximum 6 months.
Maximum 6 months.
Maximum 6 months.
Maximum 120 days based on half-life
ofSe-75of 120 days.
Maximum 50 days based on half-life
of Sr-89of 50. 53 days.
Maximum 6 months.
Maximum 6 months.
Sample Preservative or Preparation!21
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
Source/SAM Method'31
Ga-01-R
(HASL-300)
Procedure #9(6)(ORISE)
Ga-01-R(6)
(HASL-300)
Ga-01-R
(HASL-300)
Ga-01-R
(HASL-300)
RESL P-2
(DOE)
EMSL-33
(EPA)
Method 1 1 1
(EPA)
EMSL-19
(EPA)
Ga-01-R
(HASL-300)
Strontium in Food and
Bioenvironmental Samples
(EPA)
Sr-03-RC
(HASL-300)
APS
(ORISE)
Not applicable
Sample Collection Information Document
B1 -3
September 2014
-------
Analyte
Americium-241
(gamma)
Cesium-137
Cobalt-60
Europium-154
Ruthenium-103
Ruthenium-106
lodine-125
lodine-131
lridium-192
Molybdenum-99
Phosphorus-32
Plutonium-238
Plutonium-239
Uranium-238
Uranium-234
Uranium-235
Polonium-210
Radium-226
Selenium-75
Strontium-89
Strontium-90
Technetium-99
Tritium
(Hydrogen-3)
Sample Size111
1 filter
1 charcoal cartridge
1 charcoal or silver
zeolite cartridge
1 filter
1 filter
1 filter
1 filter
1 filter
1 filter
1 filter
1 filter
1 filter
1 filter
Sample Container121
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag
Holding Time'21
Maximum 6 months.
Maximum 59 days based on half-life
of 1-1 25 of 59.4 days.
Maximum 8 days based on half-life of
1-131 of 8.03 days.
Maximum 170 days based on half-life
of lr-1 92 of 173 days.
Maximum 65 hours based on half-life
of Mo-99 of 65.94 hours.
Maximum 14 days based on half-life
of P-32 of 14.26 days.
Maximum 6 months.
Maximum 6 months.
Maximum 6 months.
Maximum 120 days based on half-life
ofSe-75of 120 days.
Maximum 50 days based on half-life
of Sr-89of 50. 53 days.
Maximum 6 months.
Maximum 6 months.
Sample Preservative or Preparation!21
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
Source/SAM Method'31
Ga-01-R
(HASL-300)
Procedure #9(6)(ORISE)
Ga-01-R(6)
(HASL-300)
Ga-01-R
(HASL-300)
Ga-01-R
(HASL-300)
RESL P-2
(DOE)
EMSL-33
(EPA)
Method 1 1 1
(EPA)
EMSL-19
(EPA)
Ga-01-R
(HASL-300)
Strontium in Food and
Bioenvironmental Samples
(EPA)
Sr-03-RC
(HASL-300)
APS
(ORISE)
Not applicable
Sample Collection Information Document
B1 -3
September 2014
-------
Aqueous & Liquid Phase Samples
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reative tape or film. Wrap glass containers with bubble wrap. Determine
the radiation-specific activity of the sample(s) and pack samples outside the contaminated area as described in Footnote (4).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in
Footnote (5).
Analyte
Gross Alpha
Gross Beta
Gamma
Select Mixed Fission
Products
Total Activity
Screening
Sample Size111
1 L (solids limited)
1 L (solids limited)
Volume or mass equivalent to
calibration standard, approx. 0.5
-4L
2mL
Sample Container'2'
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Holding Time121
Maximum 6 months.
Maximum 170 days based
on half-life of
lr-192of 173 days.
Maximum 65 hours based
on half-life of
Mo-99 of 65.94 hours.
Maximum 6 months.
Sample Preservative or Preparation!2'
Preserve sample with nitric or hydrochloric acid to pH
* 2- Samples arriving unpreserved should be
allowed to rest for 1 6 hours with preservative prior to
sample preparation, time permitting.
Preserve sample with nitric or hydrochloric acid to pH
* 2- Samples arriving unpreserved should be
allowed to rest for 1 6 hours with preservative prior to
sample preparation, time permitting.
Preserve sample with nitric or hydrochloric acid to pH
* 2- Samples arriving unpreserved should be
allowed to rest for 1 6 hours with preservative prior to
sample preparation, time permitting.
No preservation required. Analyze as is without
preparation.
Source/SAM
Method13'
7110B
(SM)
7110B
(SM)
Ga-01-R
(HASL-300)
Preparation of
Samples for Total
Activity Screening
(Y-12)
Aqueous & Liquid Phase Qualitative Determination
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reative tape or film. Wrap glass containers with bubble wrap. Determine
the radiation-specific activity of the sample(s) and pack samples outside the contaminated area as described in Footnote (4).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in
Footnote (5).
Analyte
Americium-241 (alpha)
Californium-252
Curium-244
Plutonium-238
Plutonium-239
Americium-241
(gamma)
Cesium-137
Cobalt-60
Europium-154
Ruthenium-103
Ruthenium-106
Sample Size111
1 L
Volume or mass equivalent to
calibration standard, approx. 0.5
-4L
Sample Container121
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Holding Time'21
Maximum 6 months.
Maximum 6 months.
Sample Preservative or Preparation!2'
Preserve sample with nitric or hydrochloric acid to pH
< 2- Samples arriving unpreserved should be
allowed to rest for 1 6 hours with preservative prior to
sample preparation, time permitting.
Preserve sample with nitric or hydrochloric acid to pH
* 2- Samples arriving unpreserved should be
allowed to rest for 1 6 hours with preservative prior to
sample preparation, time permitting.
Source/SAM
Method13'
D3084-05
(ASTM)
7120
(SM)
Sample Collection Information Document
B2- 1
September 2014
-------
Analyte
lodine-125
lodine-131
lridium-192
Molybdenum-99
Phosphorus-32
Polonium-210
Radium-226
Selenium-75
Strontium-89
Strontium-90
Technetium-99
Sample Size111
0.1 L
Volume or mass equivalent to
calibration standard, approx. 0.5
-4 L
Volume or mass equivalent to
calibration standard, approx. 0.5
-4L
Volume or mass equivalent to
calibration standard, approx.
0.5-4 L
0.2-1 L
2.5 L
1 L
Volume or mass equivalent to
calibration standard, approx.
0.5-4 L
0.5L-4L
1 L
1 L (See method Note 2 for
additional sample size
considerations)
Sample Container121
Borosilicate glass small-mouth
bottle
Borosilicate glass small-mouth
bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Holding Time'21
Maximum 59 days based
on half-life of
1-1 25 of 59.4 days.
Maximum 8 days based on
half-life of 1-131 of 8.03
days.
Maximum 170 days based
on half-life of
lr-192of 173 days.
Maximum 65 hours based
on half-life of
Mo-99 of 65.94 hours.
Maximum 14 days based
on half-life of
P-32 of 14.26 days.
Maximum 6 months.
Maximum 6 months.
Maximum 120 days based
on half-life of
Se-75of 120 days.
Maximum 50 days based
on half-life of
Sr-89 of 50.53 days.
Maximum 6 months.
Maximum 6 months.
Sample Preservative or Preparation!21
No preservation required.
No preservation required. Analyze as is without
preparation.
Preserve sample with nitric or hydrochloric acid to pH
< 2- Samples arriving unpreserved should be
allowed to rest for 1 6 hours with preservative prior to
sample preparation, time permitting.
Preserve sample with nitric or hydrochloric acid to pH
* 2- Samples arriving unpreserved should be
allowed to rest for 1 6 hours with preservative prior to
sample preparation, time permitting.
Preserve sample with nitric or hydrochloric acid to pH
< 2- Samples arriving unpreserved should be
allowed to rest for 1 6 hours with preservative prior to
sample preparation, time permitting.
Preserve sample with nitric or hydrochloric acid to pH
* 2- Samples arriving unpreserved should be
allowed to rest for 1 6 hours with preservative prior to
sample preparation, time permitting.
Preserve sample with nitric acid to pH < 2.'7' Samples
arriving unpreserved should be allowed to rest for 16
hours with preservative prior to sample preparation,
time permitting.
Preserve sample with nitric acid to pH < 2.<7) Samples
arriving unpreserved should be allowed to rest for 16
hours with preservative prior to sample preparation,
time permitting.
Preserve sample with nitric or hydrochloric acid to pH
* 2- Samples arriving unpreserved should be
allowed to rest for 1 6 hours with preservative prior to
sample preparation, time permitting.
Preserve sample with nitric or hydrochloric acid to pH
< 2- Samples arriving unpreserved should be
allowed to rest for 1 6 hours with preservative prior to
sample preparation, time permitting.
No preservation required.
Source/SAM
Method131
Procedure #9
(ORISE)
Ga-01-R
(HASL-300)
7120
(SM)
Ga-01-R
(HASL-300)
R4-73-014
(EPA)
Po-02-RC
(HASL-300)
7500- Ra B
(SM)
7120
(SM)
905.0
(EPA)
D5811-08
(ASTM)
D71 68-05
(ASTM)
Sample Collection Information Document
B2-2
September 2014
-------
Analyte
Tritium (Hydrogen-3)
Uranium-238
Uranium-234
Uranium-235
Sample Size111
1 L
1 L
Sample Container121
Borosilicate glass small-mouth
bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Holding Time'21
Maximum 6 months.
Maximum 6 months.
Sample Preservative or Preparation!21
No preservation required.
Preserve sample with nitric or hydrochloric acid to pH
< 2- Samples arriving unpreserved should be
allowed to rest for 1 6 hours with preservative prior to
sample preparation, time permitting.
Source/SAM
Method131
906.0
(EPA)
7500- U B
(SM)
Aqueous & Liquid Phase Confirmatory
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reative tape or film. Wrap glass containers with bubble wrap. Determine
the radiation-specific activity of the sample(s) and pack samples outside the contaminated area as described in Footnote (4).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in
Footnote (5).
Americium-241 (alpha)
Californium-252
Curium-244
Americium-241
(gamma)
Cesium-137
Cobalt-60
Europium-154
Ruthenium-103
Ruthenium-106
lodine-125
lodine-131
lridium-192
Molybdenum-99
Phosphorus-32
0.1 -1 L
Volume or mass equivalent to
calibration standard, approx. 0.5
-4 L
0.1 L
Volume or mass equivalent to
calibration standard, approx. 0.5
-4L
Volume or mass equivalent to
calibration standard, approx. 0.5
-4 L
Volume or mass equivalent to
calibration standard, approx. 0.5
-4L
0.2-1 L
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Borosilicate glass small-mouth
bottle
Borosilicate glass small-mouth
bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Maximum 6 months.
Maximum 6 months.
Maximum 59 days based
on half-life of 1-1 25 of 59.4
days.
Maximum 8 days based on
half-life of 1-131 of 8.03
days.
Maximum 170 days based
on half-life of
lr-192of 173 days.
Maximum 65 hours based
on half-life of
Mo-99 of 65.94 hours.
Maximum 14 days based
on half-life of P-32 of 14.26
days.
Preserve sample with nitric or hydrochloric acid to pH
< 2- Samples arriving unpreserved should be
allowed to rest for 1 6 hours with preservative prior to
sample preparation, time permitting.
Preserve sample with nitric or hydrochloric acid to pH
* 2- Samples arriving unpreserved should be
allowed to rest for 1 6 hours with preservative prior to
sample preparation, time permitting.
No preservation required.
No preservation required. Analyze as is without
preparation.
Preserve sample with nitric or hydrochloric acid to pH
* 2- Samples arriving unpreserved should be
allowed to rest for 1 6 hours with preservative prior to
sample preparation, time permitting.
Preserve sample with nitric or hydrochloric acid to pH
< 2- Samples arriving unpreserved should be
allowed to rest for 1 6 hours with preservative prior to
sample preparation, time permitting.
Preserve sample with nitric or hydrochloric acid to pH
* 2- Samples arriving unpreserved should be
allowed to rest for 1 6 hours with preservative prior to
sample preparation, time permitting.
Am-04-RC
(HASL-300)
7120
(SM)
Procedure #9
(ORISE)
Ga-01-R
(HASL-300)
7120
(SM)
Ga-01-R
(HASL-300)
R4-73-01 4
(EPA)
Sample Collection Information Document
B2-3
September 2014
-------
Analyte
Plutonium-238
Plutonium-239
Polonium-210
Radium-226
Selenium-75
Strontium-89
Strontium-90
Technetium-99
Tritium (Hydrogen-3)
Uranium-238
Uranium-234
Uranium-235
Sample Size111
1 L
2.5 L
0.5L-4L
Volume or mass equivalent to
calibration standard, approx.
0.5-4 L
0.5L-4L
1 L
1 L (See method Note 2 for
additional sample size
considerations)
1 L
1 L
Sample Container121
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Borosilicate glass small-mouth
bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Holding Time'21
Maximum 6 months.
Maximum 6 months.
Maximum 6 months.
Maximum 120 days based
on half-life of
Se-75of 120 days.
Maximum 50 days based
on half-life of Sr-89 of
50.53 days.
Maximum 6 months.
Maximum 6 months.
Maximum 6 months.
Maximum 6 months.
Sample Preservative or Preparation!21
Preserve sample with nitric or hydrochloric acid to pH
< 2- Samples arriving unpreserved should be
allowed to rest for 1 6 hours with preservative prior to
sample preparation, time permitting.
Preserve sample with nitric or hydrochloric acid to pH
< 2- Samples arriving unpreserved should be
allowed to rest for 1 6 hours with preservative prior to
sample preparation, time permitting.
Preserve sample with nitric or hydrochloric acid to pH
* 2- Samples arriving unpreserved should be
allowed to rest for 1 6 hours with preservative prior to
sample preparation, time permitting.
Preserve sample with nitric acid to pH < 2.(7) Samples
arriving unpreserved should be allowed to rest for 16
hours with preservative prior to sample preparation,
time permitting.
Preserve sample with nitric or hydrochloric acid to pH
< 2- Samples arriving unpreserved should be
allowed to rest for 1 6 hours with preservative prior to
sample preparation, time permitting.
Preserve sample with nitric or hydrochloric acid to pH
< 2- Samples arriving unpreserved should be
allowed to rest for 1 6 hours with preservative prior to
sample preparation, time permitting.
No preservation required.
No preservation required.
Preserve sample with nitric or hydrochloric acid to pH
* 2- Samples arriving unpreserved should be
allowed to rest for 1 6 hours with preservative prior to
sample preparation, time permitting.
Source/SAM
Method131
EMSL-33
(EPA)
Po-02-RC
(HASL-300)
7500- Ra C
(SM)
7120
(SM)
905.0
(EPA)
D5811-08
(ASTM)
D71 68-05
(ASTM)
906.0
(EPA)
7500- U C
(SM)
Sample Collection Information Document
B2-4
September 2014
-------
Drinking Water Samples
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reative tape or film. Wrap glass containers with bubble wrap. Determine the
radiation-specific activity of the sample(s) and pack samples outside the contaminated area as described in Footnote (4).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote
(5).
Analyte
Gross Alpha
Gross Beta
Gamma
Select Mixed Fission
Products
Total Activity
Screening
Sample Size111
1 L (solids limited)
1 L (solids limited)
Volume equivalent to
calibration standard, approx.
0.5-4 L
0.2 L per analyte group or a
minimum of 0.8 L for all
analytes listed
Sample Container'2'
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Holding Time121
Maximum 6 months.
Maximum 170 days based on
half-life of lr-192of 173 days.
Maximum 65 hours based on
half-life of
Mo-99 of 65.94 hours.
Maximum 6 months.
Sample Preservative or Preparation'2'
Preserve sample with nitric or hydrochloric acid to pH <
> (7)
' Samples arriving unpreserved should be allowed to
rest for 16 hours with preservative prior to sample
preparation, time permitting.
Preserve sample with nitric or hydrochloric acid to pH <
1 (7)
' Samples arriving unpreserved should be allowed to
rest for 16 hours with preservative prior to sample
preparation, time permitting.
Preserve sample with nitric or hydrochloric acid to pH <
9 (7)
* Samples arriving unpreserved should be allowed to
rest for 16 hours with preservative prior to sample
preparation, time permitting.
No preservation required. Analyze as is without
preparation.
Source/SAM
Method'3'
900.0
(EPA)
900.0
(EPA)
901.1
(EPA)
Preparation of
Samples for Total
Activity Screening
(Y-12)
Drinking Water Qualitative Determination
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reative tape or film. Wrap glass containers with bubble wrap. Determine the
radiation-specific activity of the sample(s) and pack samples outside the contaminated area as described in Footnote (4).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote
(5).
Californium-252
Curium-244
Americium-241 (alpha)
Plutonium-238
Plutonium-239
Radium-226
Uranium-234
Uranium-235
Uranium-238
Amercium-241
(gamma)
Cesium-137
Cobalt-60
Europium-154
Ruthenium-103
Ruthenium-106
1 L
0.2 L per analyte group
(americium, plutonium,
radium, uranium) or a
minimum of 0.8 L for all
analytes listed
Volume or mass equivalent
to calibration standard,
approx. 0.5-4 L
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Maximum 6 months.
Maximum 6 months.
Maximum 6 months.
Preserve sample with nitric or hydrochloric acid to pH <
2- Samples arriving unpreserved should be allowed to
rest for 16 hours with preservative prior to sample
preparation, time permitting.
No sample preservation is required if sample is delivered
to the laboratory within 3 days of collection.
If the sample is to be held for more than 3 days, add
concentrated HNO3to achieve a pH<2.
Preserve sample with nitric or hydrochloric acid to pH <
2- Samples arriving unpreserved should be allowed to
rest for 16 hours with preservative prior to sample
preparation, time permitting.
D3084-05
(ASTM)
Rapid Radiochemical
Methods
(EPA)
901.1
(EPA)
Sample Collection Information Document
B3- 1
September 2014
-------
Analyte
lodine-125
lodine-131
lridium-192
Molybdenum-99
Phosphorus-32
Polonium-210
Selenium-75
Strontium-89
Strontium-90
Technetium-99
Sample Size111
0.1 L
Volume or mass equivalent
to calibration standard,
approx. 0.5 - 4 L
Volume or mass equivalent
to calibration standard,
approx. 0.5 - 4 L
Volume or mass equivalent
to calibration standard,
approx. 0.5-4 L
1 L
2.5 L
Volume or mass equivalent
to calibration standard,
approx. 0.5 - 4 L
0.5 L -4 L
0.5 L
1 L
Sample Container121
Borosilicate glass small-mouth
bottle
Borosilicate glass small-mouth
bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Samples should be collected in 1
L plastic containers
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Holding Time'21
Maximum 59 days based on
half-life of 1-1 25 of 59.4 days.
Maximum 8 days based on half-
life of 1-131 of 8.03 days.
Maximum 170 days based on
half-life of lr-192of 173 days.
Maximum 65 hours based on
half-life of Mo-99 of 65.94
hours.
Maximum 14 days based on
half-life of P-32 of 14.26 days.
Maximum 6 months.
Maximum 120 days based on
half-life of
Se-75of 120 days.
Maximum 50 days based on
half-life of
Sr-89of 50. 53 days.
Maximum 6 months.
Maximum 6 months.
Sample Preservative or Preparation121
No preservation required.
No preservation required. Analyze as is without
preparation.
Preserve sample with nitric or hydrochloric acid to pH <
1 (7)
' Samples arriving unpreserved should be allowed to
rest for 16 hours with preservative prior to sample
preparation, time permitting.
Preserve sample with nitric or hydrochloric acid to pH <
2- Samples arriving unpreserved should be allowed to
rest for 16 hours with preservative prior to sample
preparation, time permitting.
No sample preservation is required if sample is delivered
to the laboratory within 3 days of sampling date/time. If
the sample is to be held for more than 3 days, add
concentrated HNO3 to achieve a pH < 2.
Preserve sample with nitric or hydrochloric acid to pH <
2- Samples arriving unpreserved should be allowed to
rest for 16 hours with preservative prior to sample
preparation, time permitting.
Preserve sample with nitric acid to pH < 2.'7' Samples
arriving unpreserved should be allowed to rest for 16
hours with preservative prior to sample preparation, time
permitting.
Preserve sample with nitric or hydrochloric acid to pH <
2- Samples arriving unpreserved should be allowed to
rest for 16 hours with preservative prior to sample
preparation, time permitting.
No sample preservation is required if sample is delivered
to the laboratory within 3 days of sampling date/time. If
the sample is to be held for more than 3 days, add
concentrated HNO3 to achieve a pH <2.
Preserve sample with nitric or hydrochloric acid to pH <
> (7)
' Samples arriving unpreserved should be allowed to
rest for 16 hours with preservative prior to sample
preparation, time permitting.
Source/SAM
Method131
Procedure #9
(ORISE)
901.1
(EPA)
901.1
(EPA)
901.1
(EPA)
Rapid Radiochemical
Method for P-32 in
Water
(EPA)
Po-02-RC
(HASL-300)
901.1
(EPA)
905.0
(EPA)
Rapid Radiochemical
Methods
(EPA)
Tc-02-RC
(HASL-300)
Sample Collection Information Document
B3-2
September 2014
-------
Analyte
Tritium (Hydrogen-3)
Sample Size111
1 L
Sample Container121
Borosilicate glass small-mouth
bottle
Holding Time'21
Maximum 6 months.
Sample Preservative or Preparation121
No preservation required.
Source/SAM
Method'3'
906.0
(EPA)
Drinking Water Confirmatory
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reative tape or film. Wrap glass containers with bubble wrap. Determine the
radiation-specific activity of the sample(s) and pack samples outside the contaminated area as described in Footnote (4).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote
(5).
Analyte
Americium-241 (alpha)
Californium-252
Curium-244
Americium-241
(gamma)
Cesium-137
Cobalt-60
Europium-154
Ruthenium-103
Ruthenium-106
lodine-125
lodine-131
lridium-192
Molybdenum-99
Phosphorus-32
Plutonium-238
Plutonium-239
Sample Size111
0.1 -1 L
Volume or mass equivalent
to calibration standard,
approx. 0.5-4 L
0.1 L
Volume or mass equivalent
to calibration standard,
approx. 0.5-4 L
Volume or mass equivalent
to calibration standard,
approx. 0.5-4 L
Volume or mass equivalent
to calibration standard,
approx. 0.5-4 L
0.2-1 L
1 L
Sample Container'2'
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Borosilicate glass small-mouth
bottle
Borosilicate glass small-mouth
bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Holding Time'21
Maximum 6 months.
Maximum 6 months.
Maximum 59 days based on
half-life of 1-1 25 of 59.4 days.
Maximum 8 days based on half-
life of 1-131 of 8.03 days.
Maximum 170 days based on
half-life of lr-192of 173 days.
Maximum 65 hours based on
half-life of Mo-99 of 65.94
hours.
Maximum 14 days based on
half-life of P-32 of 14.26 days.
Maximum 6 months.
Sample Preservative or Preparation'2'
Preserve sample with nitric or hydrochloric acid to pH <
> (7)
' Samples arriving unpreserved should be allowed to
rest for 16 hours with preservative prior to sample
preparation, time permitting.
Preserve sample with nitric or hydrochloric acid to pH <
2- Samples arriving unpreserved should be allowed to
rest for 16 hours with preservative prior to sample
preparation, time permitting.
No preservation required.
No preservation required. Analyze as is without
preparation.
Preserve sample with nitric or hydrochloric acid to pH <
> (7)
' Samples arriving unpreserved should be allowed to
rest for 16 hours with preservative prior to sample
preparation, time permitting.
Preserve sample with nitric or hydrochloric acid to pH <
> (7)
' Samples arriving unpreserved should be allowed to
rest for 16 hours with preservative prior to sample
preparation, time permitting.
Preserve sample with nitric or hydrochloric acid to pH <
2- Samples arriving unpreserved should be allowed to
rest for 16 hours with preservative prior to sample
preparation, time permitting.
Preserve sample with nitric or hydrochloric acid to pH <
2- Samples arriving unpreserved should be allowed to
rest for 16 hours with preservative prior to sample
preparation, time permitting.
Source/SAM
Method'3'
Am-04-RC
(HASL-300)
901.1
(EPA)
Procedure #9
(ORISE)
901.1
(EPA)
901.1
(EPA)
901.1
(EPA)
R4-73-014
(EPA)
EMSL-33
(EPA)
Sample Collection Information Document
B3-3
September 2014
-------
Analyte
Polonium-210
Radium-226
Selenium-75
Strontium-89
Strontium-90
Technetium-99
Tritium (Hydrogen-3)
Uranium-238
Uranium-234
Uranium-235
Sample Size111
2.5 L
1 L
Volume or mass equivalent
to calibration standard,
approx. 0.5-4 L
0.5 L -4 L
1 L
1 L
1 L
Sample Container121
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Borosilicate glass small-mouth
bottle
Plastic (polypropylene or
polyethylene) or borosilicate
glass small-mouth bottle
Holding Time'21
Maximum 6 months.
Maximum 6 months.
Maximum 120 days based on
half-life of
Se-75of 120 days.
Maximum 50 days based on
half-life of
Sr-89of 50. 53 days.
Maximum 6 months.
Maximum 6 months.
Maximum 6 months.
Sample Preservative or Preparation121
Preserve sample with nitric or hydrochloric acid to pH <
1 (7)
' Samples arriving unpreserved should be allowed to
rest for 16 hours with preservative prior to sample
preparation, time permitting.
Preserve sample with nitric or hydrochloric acid to pH <
1 (7)
' Samples arriving unpreserved should be allowed to
rest for 16 hours with preservative prior to sample
preparation, time permitting.
Preserve sample with nitric acid to pH < 2.'7' Samples
arriving unpreserved should be allowed to rest for 16
hours with preservative prior to sample preparation, time
permitting.
Preserve sample with nitric or hydrochloric acid to pH <
2- Samples arriving unpreserved should be allowed to
rest for 16 hours with preservative prior to sample
preparation, time permitting.
Preserve sample with nitric or hydrochloric acid to pH <
1 (7)
' Samples arriving unpreserved should be allowed to
rest for 16 hours with preservative prior to sample
preparation, time permitting.
No preservation required.
Preserve sample with nitric or hydrochloric acid to pH <
1 (7)
' Samples arriving unpreserved should be allowed to
rest for 16 hours with preservative prior to sample
preparation, time permitting.
Source/SAM
Method131
Po-02-RC
(HASL-300)
903.1
(EPA)
901.1
(EPA)
905.0
(EPA)
Tc-02-RC
(HASL-300)
906.0
(EPA)
D3972-02
(ASTM)
Sample Collection Information Document
B3-4
September 2014
-------
Soil & Sediment Samples
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reative tape or film. Wrap glass containers with bubble wrap. Determine the
radiation-specific activity of the sample(s) and pack samples outside the contaminated area as described in Footnote (4).
Shipping Label: Shipping labels per requirements of 49CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in
Footnote (5).
Analyte
Gross Alpha
Gross Beta
Gamma
Select Mixed Fission
Products
Total Activity
Screening
Sample Size111
0.1 g
0.1 g
Volume or mass equivalent to
calibration standard, approx. 0.5
-4 L
19
Sample Container'2'
Plastic (polypropylene or polyethylene) large-mouth
bottle, jar, or plastic bag. Borosilicate glass wide
mouth jar may also be used.
Plastic (polypropylene or polyethylene) large-mouth
bottle, jar, or plastic bag. Borosilicate glass wide
mouth jar may also be used.
Plastic (polypropylene or polyethylene) large-mouth
bottle, jar, or plastic bag. Borosilicate glass wide
mouth jar may also be used.
Plastic (polypropylene or polyethylene) large-mouth
bottle, jar, or plastic bag. Borosilicate glass wide
mouth jar may also be used.
Holding Time121
Maximum 6 months.
Maximum 170 days based
on half-life of
lr-192of 173 days.
Maximum 65 hours based on
half-life of
Mo-99 of 65.94 hours.
Maximum 6 months.
Sample Preservative or
Preparation121
Homogenize sample at collection.
No preservation required.
Homogenize sample at collection.
No preservation required.
Homogenize sample at collection.
No preservation required.
No preservation required. If Tc-99
is to be assessed, a separate
sample will be necessary.
Source/SAM
Method131
AP1
(ORISE)
AP1
(ORISE)
Ga-01-R
(HASL-300)
Preparation of
Samples for Total
Activity Screening
(Y-12)
Soil & Sediment Qualitative Determination
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reative tape or film. Wrap glass containers with bubble wrap. Determine the
radiation-specific activity of the sample(s) and pack samples outside the contaminated area as described in Footnote (4).
Shipping Label: Shipping labels per requirements of 49CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in
Footnote (5).
Americium-241 (alpha)
Plutonium-238
Plutonium-239
Strontium-90
Uranium-234
Uranium-235
Uranium-238
Californium-252
Curium-244
Radium-226
Americium-241
(gamma)
Cesium-137
Cobalt-60
Europium-154
Ruthenium-103
Ruthenium-106
1-2g
1 kg
Volume or mass equivalent to
calibration standard, approx. 0.5
-4 L
Plastic (polypropylene or polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or polyethylene) large-mouth
bottle, jar, or plastic bag. Borosilicate glass wide
mouth jar may also be used.
Plastic (polypropylene or polyethylene) large-mouth
bottle, jar, or plastic bag. Borosilicate glass wide
mouth jar may also be used.
Maximum 6 months.
Maximum 6 months.
Maximum 6 months.
Homogenize sample at collection.
No preservation required. Analyze
as is without preparation.
Homogenize sample at collection.
No preservation required. Analyze
as is without preparation.
Homogenize sample at collection.
No preservation required. Analyze
as is without preparation.
Actinides and
Sr-89/90 in Soil
Samples
(DOE SRS)
D3084-05
(ASTM)
Ga-01-R
(HASL-300)
Sample Collection Information Document
B4-1
September 2014
-------
Analyte
lodine-125
lodine-131
lridium-192
Molybdenum-99
Phosphorus-32
Polonium-210
Selenium-75
Strontium-89
Technetium-99
Tritium (Hydrogen-3)
Sample Size111
10g
Volume or mass equivalent to
calibration standard, approx. 0.5
-4 L
Volume or mass equivalent to
calibration standard, approx. 0.5
-4L
Volume or mass equivalent to
calibration standard, approx. 0.5
-4L
50- 100 g
1-5g
Volume or mass equivalent to
calibration standard, approx. 0.5
-4L
1-2g
10g
50 g
Sample Container121
Borosilicate glass wide mouth jar
Borosilicate glass wide mouth jar
Plastic (polypropylene or polyethylene) large-mouth
bottle, jar, or plastic bag. Borosilicate glass wide
mouth jar may also be used.
Plastic (polypropylene or polyethylene) large-mouth
bottle, jar, or plastic bag. Borosilicate glass wide
mouth jar may also be used.
Plastic (polypropylene or polyethylene) large-mouth
bottle, jar, or plastic bag. Borosilicate glass wide
mouth jar may also be used.
Plastic (polypropylene or polyethylene) large-mouth
bottle, jar, or plastic bag. Borosilicate glass wide
mouth jar may also be used.
Plastic (polypropylene or polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or polyethylene) large-mouth
bottle, jar, or plastic bag. Borosilicate glass wide
mouth jar may also be used.
Borosilicate glass wide mouth jar
Holding Time'21
Maximum 59 days based on
half-life of
1-1 25 of 59.4 days.
Maximum 8 days based on
half-life of
1-131 of 8.03 days.
Maximum 170 days based
on half-life of
lr-192of 173 days.
Maximum 65 hours based on
half-life of
Mo-99 of 65.94 hours.
Maximum 14 days based on
half-life of
P-32of 14. 26 days.
Maximum 6 months.
Maximum 120 days based
on half-life of
Se-75 of 1 20 days.
Maximum 50 days based on
half-life of
50.53 days.
Maximum 6 months.
Maximum 6 months.
Sample Preservative or
Preparation121
Homogenize sample at collection.
Analyze as is without preparation. 1-
125 will volatilize with heat; do not
dry sample prior to analysis.
Homogenize sample at collection. I-
131 will volatilize with heat; do not
dry sample prior to analysis.
Homogenize sample at collection.
No preservation required. Analyze
as is without preparation.
Homogenize sample at collection.
No preservation required. Analyze
as is without preparation.
Homogenize sample at collection.
No preservation required.
Homogenize sample at collection.
No preservation required. Analyze
as is without preparation.
Homogenize sample at collection.
No preservation required. Analyze
as is without preparation.
Homogenize sample at collection.
No preservation required. Sample
is dried, sieved, and homogenized
prior to analysis.
Homogenize sample at collection.
No preservation required. Analyze
as is without preparation.
No preservation required.
Homogenize sample at collection.
Tritium will volatilize with heat; do
not dry sample.
Source/SAM
Method131
Procedure #9
(ORISE)
Ga-01-R
(HASL-300)
Ga-01-R
(HASL-300)
Ga-01-R
(HASL-300)
RESL P-2
(DOE)
Po-02-RC
(HASL-300)
Ga-01-R
(HASL-300)
Actinides and
Sr-89/90 in Soil
Samples
(DOE SRS)
APS
(ORISE)
AP2
(ORISE)
Sample Collection Information Document
B4-2
September 2014
-------
Analyte
Sample Size111
Sample Container121
Holding Time'21
Sample Preservative or
Preparation121
Source/SAM
Method131
Soil & Sediment Confirmatory
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reative tape or film. Wrap glass containers with bubble wrap. Determine the
radiation-specific activity of the sample(s) and pack samples outside the contaminated area as described in Footnote (4).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in
Footnote (5).
Analyte
Americium-241 (alpha)
Californium-252
Curium-244
Americium-241
(gamma)
Cesium-137
Cobalt-60
Europium-154
Ruthenium-103
Ruthenium-106
lodine-125
lodine-131
lridium-192
Molybdenum-99
Phosphorus-32
Plutonium-238
Plutonium-239
Sample Size111
1 kg
Volume or mass equivalent to
calibration standard, approx. 0.5
-4L
10g
Volume or mass equivalent to
calibration standard, approx. 0.5
-4L
Volume or mass equivalent to
calibration standard, approx. 0.5
-4 L
Volume or mass equivalent to
calibration standard, approx. 0.5
-4L
50- 100 g
1 kg
Sample Container121
Plastic (polypropylene or polyethylene) large-mouth
bottle, jar, or plastic bag. Borosilicate glass wide
mouth jar may also be used.
Plastic (polypropylene or polyethylene) large-mouth
bottle, jar, or plastic bag. Borosilicate glass wide
mouth jar may also be used.
Borosilicate glass wide mouth jar
Borosilicate glass wide mouth jar
Plastic (polypropylene or polyethylene) large-mouth
bottle, jar, or plastic bag. Borosilicate glass wide
mouth jar may also be used.
Plastic (polypropylene or polyethylene) large-mouth
bottle, jar, or plastic bag. Borosilicate glass wide
mouth jar may also be used.
Plastic (polypropylene or polyethylene) large-mouth
bottle, jar, or plastic bag. Borosilicate glass wide
mouth jar may also be used.
Plastic (polypropylene or polyethylene) large-mouth
bottle, jar, or plastic bag. Borosilicate glass wide
mouth jar may also be used.
Holding Time'21
Maximum 6 months.
Maximum 6 months.
Maximum 59 days based on
half-life of
1-1 25 of 59.4 days.
Maximum 8 days based on
half-life of
1-131 of 8.03 days.
Maximum 170 days based
on half-life of
lr-192of 173 days.
Maximum 65 hours based on
half-life of
Mo-99 of 65.94 hours.
Maximum 14 days based on
half-life of
P-32of 14. 26 days.
Maximum 6 months.
Sample Preservative or
Preparation121
Homogenize sample at collection.
No preservation required.
Homogenize sample at collection.
No preservation required. Analyze
as is without preparation.
Homogenize sample at collection.
Analyze as is without preparation. 1-
125 will volatilize with heat; do not
dry sample prior analysis.
Homogenize sample at collection.
No preservation required. 1-131 will
volatilize with heat; do not dry
sample prior to analysis. Analyze
as is without preparation.
Homogenize sample at collection.
No preservation required. Analyze
as is without preparation.
Homogenize sample at collection.
No preservation required. Analyze
as is without preparation.
Homogenize sample at collection.
No preservation required.
Homogenize sample at collection.
No preservation required.
Source/SAM
Method'31
Am-01-RC
(HASL-300)
Ga-01-R
(HASL-300)
Procedure #9
(ORISE)
Ga-01-R
(HASL-300)
Ga-01-R
(HASL-300)
Ga-01-R
(HASL-300)
RESL P-2
(DOE)
EMSL-33
(EPA)
Sample Collection Information Document
B4-3
September 2014
-------
Analyte
Polonium-210
Radium-226
Selenium-75
Strontium-89
Strontium-90
Technetium-99
Tritium (Hydrogen-3)
Uranium-238
Uranium-234
Uranium-235
Sample Size111
1-5g
19
Volume or mass equivalent to
calibration standard, approx. 0.5
-4 L
2-10g
Based on gross beta analysis,
weigh out sufficient sample to
obtain 10- 100 times
background activity
10g
50 g
1 L
Sample Container121
Plastic (polypropylene or polyethylene) large-mouth
bottle, jar, or plastic bag. Borosilicate glass wide
mouth jar may also be used.
Plastic (polypropylene or polyethylene) large-mouth
bottle, jar, or plastic bag. Borosilicate glass wide
mouth jar may also be used.
Plastic (polypropylene or polyethylene) or borosilicate
glass small-mouth bottle
Plastic (polypropylene or polyethylene) large-mouth
bottle, jar, or plastic bag. Borosilicate glass wide
mouth jar may also be used.
Plastic (polypropylene or polyethylene) large-mouth
bottle, jar, or plastic bag. Borosilicate glass wide
mouth jar may also be used.
Plastic (polypropylene or polyethylene) large-mouth
bottle, jar, or plastic bag. Borosilicate glass wide
mouth jar may also be used.
Borosilicate glass wide mouth jar
Plastic (polypropylene or polyethylene) large-mouth
bottle, jar, or plastic bag. Borosilicate glass wide
mouth jar may also be used.
Holding Time'21
Maximum 6 months.
Maximum 6 months.
Maximum 120 days based
on half-life of
Se-75 of 1 20 days.
Maximum 50 days based on
half-life of
Sr-89 of 50.53 days.
Maximum 6 months.
Maximum 6 months.
Maximum 6 months.
Maximum 6 months.
Sample Preservative or
Preparation121
Homogenize sample at collection.
No preservation required. Analyze
as is without preparation.
Homogenize sample at collection.
No preservation required.
Homogenize sample at collection.
No preservation required. Analyze
as is without preparation.
No preservation required.
Homogenize sample at collection.
No preservation required. Analyze
as is without preparation.
Homogenize sample at collection.
No preservation required. Analyze
as is without preparation.
Homogenize sample at collection.
No preservation required. Tritium
will volatilize with heat; do not dry
sample before analysis.
Homogenize sample at collection.
No preservation required.
Source/SAM
Method131
Po-02-RC
(HASL-300)
EMSL-19
(EPA)
Ga-01-R
(HASL-300)
Strontium in Food and
Bioenvironmental
Samples
(EPA)
Sr-03-RC
(HASL-300)
APS
(ORISE)
AP2
(ORISE)
EMSL-33
(EPA)
Sample Collection Information Document
B4-4
September 2014
-------
Surface Wipes
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reative tape or film. Wrap glass containers with bubble wrap. Determine
the radiation-specific activity of the sample(s) and pack samples outside the contaminated area as described in Footnote (4).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in
Footnote (5).
Analyte
Gross Alpha
Gross Beta
Gamma
Select Mixed Fission
Products
Total Activity
Screening
Sample Size111
1 wipe (limited to
counting geometry
size)
1 wipe (limited to
counting geometry
size)
1 wipe (limited to
counting geometry
size)
1 wipe
Sample Container'2'
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Holding Time121
Maximum 6 months.
Maximum 170 days based on half-
life of lr-1 92 of 173 days.
Maximum 65 hours based on half-
life of Mo-99 of 65.94 hours
Maximum 6 months
Sample Preservative or Preparation'2'
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. If Tc-99 is to
be assessed, a separate sample will be
needed.
Source/SAM Method'3'
FRMAC, Vol. 2, pg. 33
(DOE)
FRMAC, Vol. 2, pg. 33
(DOE)
Ga-01-R
(HASL-300)
Preparation of Samples for
Total Activity Screening
(Y-12)
Surface Wipes Qualitative Determination
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reative tape or film. Wrap glass containers with bubble wrap. Determine
the radiation-specific activity of the sample(s) and pack samples outside the contaminated area as described in Footnote (4).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in
Footnote (5).
Americium-241 (alpha)
Plutonium-238
Plutonium-239
Radium-226
Uranium-238
Uranium-234
Uranium-235
Californium-252
Curium-244
Americium-241
(gamma)
Cesium-137
Cobalt-60
Europium-154
Ruthenium-103
Ruthenium-106
lodine-125
1 wipe
1 wipe
1 wipe
1 wipe
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Maximum 6 months
Maximum 6 months
Maximum 6 months
Maximum 59 days based on half-
life of 1-125 of 59.4 days
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
Rapid Methods for Acid or
Fusion Digestion
(EPA)
D3084-05
(ASTM)
Ga-01-R
(HASL-300)
Procedure #9
(ORISE)
Sample Collection Information Document
B5-1
September 2014
-------
Analyte
lodine-131
lridium-192
Molybdenum-99
Phosphorus-32
Polonium-210
Selenium-75
Strontium-89
Strontium-90
Technetium-99
Tritium (Hydrogen-3)
Sample Size111
1 wipe
1 wipe
1 wipe
1 wipe
1 wipe
1 wipe
1 wipe
1 wipe
1 wipe
1 wipe
Sample Container121
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Holding Time'21
Maximum 8 days based on half-
life of 1-131 of 8.03 days
Maximum 170 days based on half-
life of lr-1 92 of 173 days
Maximum 65 hours based on half-
life of Mo-99 of 65.94 hours
Maximum 14 days based on half-
life of P-32 of 14.26 days
Maximum 6 months
Maximum 120 days based on half-
life of Se-75 of 120 days
Maximum 50 days based on half-
life of Sr-89 of 50.53 days
Maximum 6 months
Maximum 6 months
Maximum 6 months
Sample Preservative or Preparation121
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Tritium will
volatilize with heat; do not dry sample
before analysis. Analyze as is without
preparation.
Source/SAM Method'31
Ga-01-R
(HASL-300)
Ga-01-R
(HASL-300)
Ga-01-R
(HASL-300)
RESL P-2
(DOE)
Method 1 1 1
(EPA)
Ga-01-R
(HASL-300)
Strontium in Food and
Bioenvironmental Samples
(ฃpA\
Rapid Methods for acid or
Fusion Digestion
AT^
(ORISE)
AP2
(ORISE)
Surface Wipes Confirmatory
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reative tape or film. Wrap glass containers with bubble wrap. Determine
the radiation-specific activity of the sample(s) and pack samples outside the contaminated area as described in Footnote (4).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in
Footnote (5).
Analyte
Americium-241 (alpha)
Californium-252
Curium-244
Americium-241
(gamma)
Cesium-137
Cobalt-60
Europium-154
Ruthenium-103
Ruthenium-106
Sample Size111
1 wipe
1 wipe
Sample Container121
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Holding Time'21
Maximum 6 months
Maximum 6 months
Sample Preservative or Preparation121
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
Source/SAM Method'31
Am-04-RC
(HASL-300)
Ga-01-R
(HASL-300)
Sample Collection Information Document
B5-2
September 2014
-------
Analyte
lodine-125
lodine-131
lridium-192
Molybdenum-99
Phosphorus-32
Plutonium-238
Plutonium-239
Uranium-238
Uranium-234
Uranium-235
Polonium-210
Radium-226
Selenium-75
Strontium-89
Strontium-90
Technetium-99
Tritium (Hydrogen-3)
Sample Size111
1 wipe
1 wipe
1 wipe
1 wipe
1 wipe
1 wipe
1 wipe
1 wipe
1 wipe
1 wipe
1 wipe
1 wipe
1 wipe
Sample Container121
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Glassine envelope, polyacrylic plastic Petri
dish, or polyethylene plastic bag.
Holding Time'21
Maximum 59 days based on half-
life of 1-125 of 59.4 days
Maximum 8 days based on half-
life of
1-131 of 8.03 days
Maximum 170 days based on half-
life of
lr-192of 173 days
Maximum 65 hours based on half-
life of Mo-99 of 65.94 hours
Maximum 14 days based on half-
life of P-32 of 14.26 days
Maximum 6 months
Maximum 6 months
Maximum 6 months
Maximum 120 days based on half-
life of Se-75 of 120 days
Maximum 50 days based on half-
life of Sr-89 of 50.53 days
Maximum 6 months
Maximum 6 months
Maximum 6 months
Sample Preservative or Preparation121
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Analyze as is
without preparation.
No preservation required. Tritium will
volatilize with heat; do not dry sample
prior to analysis.
Source/SAM Method'31
Procedure #9
(ORISE)
Ga-01-R
(HASL-300)
Ga-01-R
(HASL-300)
Ga-01-R
(HASL-300)
RESL P-2
(DOE)
EMSL-33
(EPA)
Method 1 1 1
(EPA)
EMSL-19
(EPA)
Ga-01-R
(HASL-300)
Strontium in Food and
Bioenvironmental Samples
fppai
Sr-03-RC
(HASL-300)
APS
(ORISE)
AP2
(ORISE)
Sample Collection Information Document
B5-3
September 2014
-------
Vegatation
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reative tape or film. Wrap glass containers with bubble wrap. Determine the
radiation- specific activity of the sample(s) and pack samples outside the contaminated area as described in Footnote (4).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (5).
Analyte
Gross Alpha
Gross Beta
Gamma
Select Mixed Fission
Products
Total Activity Screening
Sample Size111
0.1 g
Volume or mass equivalent
to calibration standard,
approx. 0.5-4 L
19
Sample Container121
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag. Borosilicate
glass wide mouth jar may also be used.
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag. Borosilicate
glass wide mouth jar may also be used.
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag. Borosilicate
glass wide mouth jar may also be used.
Holding Time'21
Maximum 6 months
Maximum 65 hours based on
half-life of
Mo-99 of 65.94 hours
Maximum 6 months
Sample Preservative or
Preparation121
No preservation required.
No preservation required.
No preservation required. If Tc-99 is to
be assessed, a separate sample will
be necessary.
Source/SAM Method'31
AP1
(ORISE)
Ga-01-R
(HASL-300)
Preparation of Samples for
Total Activity Screening
(Y-12)
Vegetation Qualitative Determination
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reative tape or film. Wrap glass containers with bubble wrap. Determine the
radiation-specific activity of the sample(s) and pack samples outside the contaminated area as described in Footnote (4).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (5).
Analyte
Americium-241 (alpha)
Plutonium-238
Plutonium-239
Strontium-90
Uranium-234
Uranium-235
Uranium-238
Californium-252
Curium-244
Americium-241
(gamma)
Cesium-137
Cobalt-60
Europium-154
Ruthenium-103
Ruthenium-106
lodine-125
Sample Size111
5g
10g
Volume or mass equivalent
to calibration standard,
approx. 0.5-4 L
3-5g
Sample Container'2'
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Holding Time'21
Maximum 6 months
Maximum 6 months
Maximum 6 months
Maximum 59 days based on half-
life of 1-125 of 59.4 days
Sample Preservative or
Preparation121
No preservation required.
No preservation required.
No preservation required.
No preservation required. 1-125 will
volatilize with heat; do not dry sample
prior to analysis.
Source/SAM Method'31
Actinides and
Sr-89/90 in Vegetation
(DOE SRS)
D3084-05
(ASTM)
Ga-01-R
(HASL-300)
Procedure #9
(ORISE)
Sample Collection Information Document
B6-1
September 2014
-------
Analyte
lodine-131
lridium-192
Molybdenum-99
Phosphorus-32
Polonium-210
Radium-226
Selenium-75
Strontium-89
Technetium-99
Tritium (Hydrogen-3)
Sample Size111
Volume or mass equivalent
to calibration standard,
approx. 0.5-4 L
Volume or mass equivalent
to calibration standard,
approx. 0.5 - 4 L
Volume or mass equivalent
to calibration standard,
approx. 0.5 - 4 L
100 g
100 g
2.3 kg to yield 10 g ash
sample
Volume or mass equivalent
to calibration standard,
approx. 0.5- 4 L
5g
10g
50 g
Sample Container121
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Plastic (polypropylene or polyethylene) or
borosilicate glass small-mouth bottle.
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Borosilicate glass wide mouth jar.
Holding Time'21
Maximum 8 days based on half-
life of 1-131 of 8.03 days
Maximum 170 days based on
half-life of lr-192of 173 days
Maximum 65 hours based on
half-life of Mo-99 of 65.94 hours
Maximum 14 days based on half-
life of P-32 of 1 4.26 days
Maximum 138 days based on
half-life of Po-21 Oof 138 days
Maximum 6 months
Maximum 120 days based on
half-life of Se-75 of 120 days
Maximum 50 days based on half-
life of Sr-89 of 50.53 days
Maximum 6 months
Maximum 6 months
Sample Preservative or
Preparation121
No preservation required. 1-131 will
volatilize with heat; do not dry sample
prior to analysis.
No preservation required.
No preservation required.
No preservation required.
No preservation required.
No preservation required.
No preservation required.
No preservation required.
No preservation required.
No preservation required. Tritium will
volatilize with heat; do not dry sample
prior to analysis.
Source/SAM Method'31
Ga-01-R
(HASL-300)
Ga-01-R
(HASL-300)
Ga-01-R
(HASL-300)
RESL P-2
(DOE)
Po-02-RC
(HASL-300)
Ra-03-RC
(HASL-300)
Ga-01-R
(HASL-300)
Actinides and
Sr-89/90 in Vegetation
(DOE SRS)
APS
(ORISE)
AP2
(ORISE)
Vegetation Confirmatory
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reative tape or film. Wrap glass containers with bubble wrap. Determine the
radiation-specific activity of the sample(s) and pack samples outside the contaminated area as described in Footnote (4).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (5).
Analyte
Americium-241 (alpha)
Californium-252
Curium-244
Plutonium-238
Plutonium-239
Sample Size111
1 00 - 300 g
Sample Container'2'
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Holding Time'21
Maximum 6 months
Sample Preservative or
Preparation121
No preservation required.
Source/SAM Method'31
Am-06-RC
(HASL-300)
Sample Collection Information Document
B6-2
September 2014
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Analyte
Americium-241
(gamma)
Cesium-137
Cobalt-60
Europium-154
Ruthenium-103
Ruthenium-106
lodine-125
lodine-131
lridium-192
Molybdenum-99
Phosphorus-32
Polonium-210
Radium-226
Selenium-75
Strontium-89
Strontium-90
Technetium-99
Tritium (Hydrogen-3)
Uranium-238
Uranium-234
Uranium-235
Sample Size111
Volume or mass equivalent
to calibration standard,
approx. 0.5-4 L
3-5g
Volume or mass equivalent
to calibration standard,
approx. 0.5 - 4 L
Volume or mass equivalent
to calibration standard,
approx. 0.5 - 4 L
Volume or mass equivalent
to calibration standard,
approx. 0.5-4 L
100 g
100 g
2.3 kg to yield 10 g ash
sample
Volume or mass equivalent
to calibration standard,
approx. 0.5 - 4 L
2-5g
1 00 - 300 g
5-20g
50 g
2.3 kg to yield 10 g ash
sample
Sample Container121
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Borosilicate glass wide mouth jar.
Plastic (polypropylene or polyethylene) large-
mouth bottle, jar, or plastic bag.
Holding Time'21
Maximum 6 months
Maximum 59 days based on half-
life of 1-125 of 59.4 days
Maximum 8 days based on half-
life of 1-131 of 8.03 days
Maximum 170 days based on
half-life of lr-192of 173 days
Maximum 65 hours based on
half-life of Mo-99 of 65.94 hours
Maximum 14 days based on half-
life of P-32 of 1 4.26 days
Maximum 138 days based on
half-life of Po-21 Oof 138 days
Maximum 6 months
Maximum 120 days based on
half-life of Se-75 of 120 days
Maximum 50 days based on half-
life of Sr-89 of 50.53 days
Maximum 6 months
Maximum 6 months
Maximum 6 months
Maximum 6 months
Sample Preservative or
Preparation121
No preservation required.
No preservation required. 1-125 will
volatilize with heat; do not dry sample
prior to analysis.
No preservation required. 1-131 will
volatilize with heat; do not dry sample
prior to analysis.
No preservation required.
No preservation required.
No preservation required.
No preservation required.
No preservation required.
No preservation required.
No preservation required.
No preservation required.
No preservation required.
No preservation required. Tritium will
volatilize with heat; do not dry sample
prior to analysis.
No preservation required.
Source/SAM Method'31
Ga-01-R
(HASL-300)
Procedure #9
(ORISE)
Ga-01-R
(HASL-300)
Ga-01-R
(HASL-300)
Ga-01-R
(HASL-300)
RESL P-2
(DOE)
Po-02-RC
(HASL-300)
Ra-03-RC
(HASL-300)
Ga-01-R
(HASL-300)
Strontium in Food and
Bioenvironmental Samples
/CD A\
Sr-03-RC
(HASL-300)
Tc-01-RC
(HASL-300)
AP2
(ORISE)
U-02-RC
(HASL-300)
Sample Collection Information Document
B6-3
September 2014
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Footnotes:
(1) The sample sizes listed are based on the amount needed for analysis of a single sample. If requested by the laboratory, additional samples(s) must be collected for
laboratory quality control analyses (e.g., duplicates, matrix spikes). It is also recommended that additional sample(s) be collected in case of the need for reanalysis due to
sample spillage or unforseen analytical difficulties.
(2) Sample container, holding times, preservation, and sample preparation information has been derived from requirements stated in the analytical methods or documents
cited under "SAM/Source Method" or in Section 7.0 of this document.
(3) SAM methods listed in this column can be located using U.S. Environmental Protection Agency, National Homeland Security Research Center's (NHSRC) Selected
Analytical Methods for Environmental Remediation and Recovery (SAM), 2012 (www.epa.gov/sam/). SAM is intended to be used concurrently with this Sample Collection
Information Document. Full citations for references not cited and/or accessed through the SAM Website are provided in Section 7.0 of this document.
(4) Sample transport containers are packed outside the contaminated area. Samples must be packed in a manner that protects the integrity of the sample containers.
Samples should be surrounded by shock absorbing and liquid absorbent packing materials (49CFR 173.24 and 173.453). Check the radiation-specific activity from the
packaged samples (49 CFR 173.403).
(5) Although the package required for transporting radioactive material is based on the activity INSIDE the package, the label required on the transport package is based
on the radiation hazard OUTSIDE the package. Radioactive material is the only hazardous material that has three possible labels, depending on the relative radiation
levels external to the package. Labels for radioactive material also require a Tl number which indicates the highest radiation level measured at 1 meter from the surface
of the package. The three possible labels are commonly called White 1, Yellow 2, and Yellow 3, referring to the color of the label and the number prominently displayed.
A specific label is required if the surface radiation limit and the limit at 1 meter satisfy the requirements of 49 CFR 172.403.
(6) This procedure should be used only for filters specifically designed for iodine.
(7) If dissolved components are to be determined, samples requiring preservation must be filtered prior to preservation.
Sample Collection Information Document September 2014
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r/EPA
United States
Environmental Protection
Agency
PRESORTED STANDARD
POSTAGE & FEES PAID
EPA
PERMIT NO. G-35
Office of Research and Development
National Homeland Security Research Center
Cincinnati, OH 45268
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