Miami Ocean Dredged Material Disposal
Site 2010 PCB and Copper Study
Advanced Chemical Monitoring
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EPA-904-R-14-001
February 2014
Miami Ocean Dredged Material Disposal Site
2010 PCB and Copper Study
Advanced Chemical Monitoring
U.S. Environmental Protection Agency
Region 4
Water Protection Division
Coastal and Ocean Protection Section
Atlanta, GA
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1.0 Introduction 1
2.0 Methods 6
2.1 Sediment Sampling 6
2.2 Tissue Sampling 6
2.3 Sediment Chemistry Data Analysis 10
3.0 Results 11
3.1 Sediments 11
3.2 Tissues 17
4.0 Quality Control 17
5.0 Recommendations 18
6.0 References 19
Figure 1: Miami ODMDS Location Map 2
Figure 2: Total PCBs (NOAA Summation) at the Miami ODMDS from the 2007 Trend Assessment Survey 4
Figure 3: Copper Concentrations at the Miami ODMDS from the 2007 Trend Assessment Survey 5
Figure 4: Deep Ocean Van Veen 7
Figure 5: Otter Trawl 7
Figure 6: Examples of Taxa used for Tissue Sampling 8
Figure 7: Filleting Gulfstream Flounder 9
Figure 8: 2010 Copper Concentrations at the Miami ODMDS 12
Figure 9: 2010 PCBs (NOAA Summation) Concentration at the Miami ODMDS 13
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Figure 10: 2010 PCBs (Region 4 Total) Concentration at the Miami ODMDS 14
Figure 11: 2010 Total Organic Carbon Normalized Total PCBs (Region 4 Total) at the Miami ODMDS 15
Figure 12: 2010 Mean Sediment Quality Guideline Quotient at the Miami ODMDS 16
Table 1: Miami ODMDS 2007 Trend Assessment Sediment Chemistry Results 3
Table 2:Summary of Invertebrates and Fishes Sampled for Tissue Analysis 10
Table 3: Summary of Sediment Impacted by Elevated Copper and PCBs 11
Table 4: Summary of Tissue Chemistry Results 17
Table 5: Comparison of NBA and EPA Region 4 PCB Results (Total EPA Region 4 PCBs) 18
Table 6: Comparison of Field Split Results 18
Appendix A: Sediment Sample Locations and Descriptions
Appendix B: Analytes, Methods and Detection Limits
Appendix C: Trawl Locations
Appendix D: Sediment Chemistry Results
Appendix E: Tissue Chemistry Results
Appendix F: Hydrocarbon Contamination Investigation
Appendix G: EPA Region 4 Laboratory PCB Analysis Results
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It is the responsibility of the U.S. Environmental Protection Agency (EPA) and the U.S. Army Corps of
Engineers (USAGE) under the Marine Protection, Research, and Sanctuaries Act (MPRSA) of 1972 to
manage and monitor each of the Ocean Dredged Material Disposal Sites (ODMDSs) designated by the
EPA pursuant to Section 102 of MPRSA. MPRSA, the Water Resources Development Act (WRDA) of
1992, and a Memorandum of Agreement between EPA and USAGE require the joint development of site
management and monitoring plans (SMMP) to specifically address the disposal of dredged material at
ODMDSs. Additionally, the Memorandum of Understanding (MOU) between EPA Region 4 and the
USAGE South Atlantic Division specifies that it is in the best interest of the EPA and the USAGE to act in
partnership concerning the management and monitoring of all ODMDSs.
Management of ODMDSs involves regulating the times, the quantity, and the physical/chemical
characteristics of dredged material that is dumped at the site; establishing disposal controls, conditions,
and requirements to avoid and minimize potential impacts to the marine environment; and monitoring
the site environs to verify that unanticipated or significant adverse effects are not occurring from past or
continued use of the site and that permit terms are met.
The Miami ODMDS was designated by EPA in 1996. The center of the Miami ODMDS is located 4.7
nautical miles (nmi) offshore Miami Beach, Florida and is positioned over the upper continental slope
with water depths ranging from 127 to 235 meters. The ODMDS measures 1 nmi by 1 nmi (1.85 km x 1
.85 km) square and is centered at 25° 45.00' N latitude and 80° 03.37' W longitude (see Figure 1).
Dredged material has been disposed within the vicinity since 1957. Most recently, 4.4 million cubic
yards of dredged material was disposed at the ODMDS from the Miami Harbor Phase II Deepening
Project between 1995 and 2006. Material consisted of a mixture of sand, silt and crushed limestone.
A SMMP was developed and finalized by the EPA and USAGE for the Miami ODMDS in 1995 as part of
the designation process and reviewed and revised in 2008. The SMMP outlines strategies for monitoring
the ODMDS and thresholds for taking action based on the results of those efforts. One of the
monitoring goals is to periodically conduct trend assessment surveys of the ODMDS. The trend
assessment survey consists of an evaluation of the water and sediment quality and an analysis of the
benthic community. The results are reviewed for any progressive non-seasonal changes in water or
sediment quality or the absence from the site of pollution sensitive biota. If changes are observed,
additional monitoring and assessment is warranted.
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Biscayne Bay
x Key ,
\Biscayne/
(.
1 nmi
Figure 1: Miami ODMDS Location Map
Consistent with the Miami ODMDS SMMP, a trend assessment was conducted by EPA Region 4 in
October 2007 (EPA, 2012). Results of the study did not show a statistically significant change in the
benthic communities within the ODMDS. No changes were observed in the water quality at the site.
However, changes were observed in the chemical characteristics of the sediments. The sediments had
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elevated levels of copper, lead and PCBs. Concentrations were higher inside the site than out and higher
than concentrations observed in the dredged material when it was tested prior to disposal. In addition,
concentrations were in excess of NOAA sediment screening guidelines used to screen for substances
that may threaten natural resources (Buchman, 2008). Results are summarized in Table 1 below and in
Figures 2 and 3.
Table 1: Miami ODMDS 2007 Trend Assessment Sediment Chemistry Results
Contaminant
Copper
Lead
Total PCBs
Concentration
outside the
ODMDS (ppm)
Mean: 20.5
Range: 1.3-24
Mean: 3. 8
Range: 1.7-9
Mean: 5.0
Range: 0.8-
21.0
Concentration
within the
ODMDS (ppm)
Mean: 6.5
Range: 3.3-49
Mean: 17.5
Range: 2.7-34
Mean: 62.4
Range: 3.6-163
Screening Level*
(ppm)
TEL:18.7
ERL34.0
PEL108
ERM: 270
TEL:20.2
ERL46.7
PEL112
ERM: 218
TEL:21.6
ERL22.7
PEL189
ERM: 180
Probability of Effect from
Highest Observed
Concentration**
29%
26%
41%
*Effects Range-Low (ERL)/Threshold Effects Levels (TELs): Concentrations below which adverse effects rarely occur.
Effects Range-Median (ERM) / Probable Effects Level (PEL): Concentrations above which effects frequently occur.
** from NOAA, 1999.
The ERL/ERM screening levels values were originally calculated to provide a means for interpreting
monitoring data collected under the NOAA National Status and Trends Program. For copper, the percent
incidence of adverse effects for concentrations between the ERL and the ERM was 29%. For
concentrations above the ERM, the percent incidence of adverse effects is 84%. For PCBs, the percent
incidence of effects for concentrations between the ERL and the ERM was 41%. For concentrations
above the ERM, the percent incidence of effects is 51%. (NOAA, 1999)
TELs and PELs were originally developed for Florida coastal waters. For copper, the percent incidence of
adverse effects for concentrations between the PEL and the TEL was 22%. For concentrations above the
PEL, the percent incidence of adverse effects is 56%. For lead, the percent incidence of adverse effects
for concentrations between the PEL and the TEL was 26%. For PCBs, the percent incidence of effects for
concentrations between the PEL and the TEL was 37%. For concentrations above the TEL, the percent
incidence of effects is 55%. (MacDonald et. al, 1996)
Based on the elevated concentration of these contaminants and the moderate probability of adverse
biological effects, further studies were warranted to characterize the magnitude and distribution of the
contamination within and around the Miami ODMDS.
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528000
526000
524000
cr- 520000
0)
en
c
9
•
!«
KOOMCS CutwfctOCMDS Dnoo* M
Q C
522000 1 73
10.1
13.2
4.4
518000
516000 °'842
514000
512000
510000
3.68
69.8
42
68.6
26.9
164
1.21
3.17
PCB Concentration
(PPb)
y 0 to 22
22 to 50
50 to 100
| 100 to 150
I 150 to 180
960000 962000 964000 966000 968000 970000 972000
TEUERL = 22PPb Easting (feet)
PEL/ERM = 180
When concentration less than the ERL. % incidence of effects =18.5
When concentration greater than the ERL, but less than the ERM, % incidence of effect = 40.8%
When concentration greater than the ERM, % incidence of effect = 51
Figure 2: Total PCBs (NOAA Summation) at the Miami ODMDS from the 2007 Trend Assessment
Survey
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528000
526000
524000
522000
c- 520000
0)
D)
f 518000
z
516000
514000
512000
510000
T
I
4.8
•
651.4
3.4
1.9
3.4
1.3
•
•3 Q
o.o
23
49
21
22
24
3.6
Copper Concentration
(ppm)
0 to 18.7
18,7 to 25
25 to 34
34 to 40
40 to 50
960000 962000 964000 966000 968000 970000 972000
Easting (feet)
TEL=18.7 ppm; ERL=34.0 ppm; PEL = 108 ppm; ERM = 270 ppm
When concentration less than the ERL, % incidence of effects = 9.4
When concentration greater than the ERL. but less than the ERM, % incidence of effect = 29%
When concentration greater than the ERM, % incidence of effect = 84
Figure 3: Copper Concentrations at the Miami ODMDS from the 2007 Trend Assessment Survey
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2.0
In order to map the concentrations of PCBs and metals within the sediments at the Miami ODMDS,
sediment samples were collected from 30 stations within the ODMDS plus an additional 10 stations to
the north and east of the ODMDS within the extended impact zone (Germane, 2006) and where
elevated contaminant concentrations were observed (EPA, 2012). All samples were systematically
selected using the EPA/DOE program, Visual Sample Plan (PNNL, 2007), to maximize the likelihood of
delineating a contaminant footprint. Sediments were collected using a stainless steel Deep Ocean Van
Veen grab sampler from the EPA Ocean Survey Vessel (OSV) Bold (see figure 4). The Deep Ocean Van
Veen has a surface area of 0.18m2 and a sampling depth of 30cm. Sediments were collected from the
top 5-10 cm from the center of the grab sampler with a stainless steel spoon to minimize contact of the
sample with the grab sampler. The position of the sample was recorded when the grab reached the
seafloor utilizing Hypack software. Sampling was conducted from April 21, 2010 to April 22, 2010.
Samples were homogenized and placed in two 237-ml pre-cleaned glass jars with Teflon lid liners. The
jars of sediment were labeled and stored at approximately 4°C in a refrigerator on board the OSV Bold.
All samples were collected and processed on board the OSV Bold by ANAMAR Environmental Consulting,
a contractor to the USAGE Jacksonville District. Sample coordinates and descriptions are presented in
Appendix A.
At the end of the survey, sediment samples were shipped via FedEx to Northeast Analytical (NEA) for
analysis of total organic carbon (TOC), metals, and PCB congeners. Analytes and analytical methods are
presented in Appendix B.
A secondary objective of the sampling effort was to test the feasibility of collecting epibenthic organisms
for tissue analysis to examine the bioaccumulation of the PCBs in future monitoring efforts. Shellfish
and fishes were collected in a 7.3 m wide otter trawl having a stretch mesh size of 14 mm in the bag
end, supplied by the OSV Bold (see figure 5). Each sample consisted of 5 to 15 minute tows at a speed
over ground of between 1.7 knots and 1.8 knots. This provided a sampling area of approximately 11,110
m2. Spatial coordinates were recorded at the beginning and at the end of each tow, along with the
direction of travel, water depth, and tide sequence. Most tows were generally conducted against the
prevailing current (i.e., the Florida Current), from north to south, to maximize trawl performance and
ship maneuverability. Upon completion of each tow, specimens were carefully and thoroughly removed
from the trawl net and bag, taking care not to overlook any still contained in the net (to avoid cross-
contamination between samples). Individual organisms were taxonomically identified and sorted and
later verified at the lab using taxonomic keys along with the consultation of taxonomists (ANAMAR,
2010). Individuals identified for tissue analysis were retained on ice for later tissue extraction. Trawl
locations are provided in Appendix C.
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Figure 4: Deep Ocean Van Veen
Figure 5: Otter Trawl
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Taxa were selected for tissue analysis based on their known life history traits, availability, and degree of
site specificity. In order to represent localized bioaccumulation within the Miami ODMDS, selected
candidate taxa were non-migratory, thought to have relatively small home ranges, benthic to epibenthic
most of their lives, and regularly appeared in trawl catches. Taxa selected for tissue sampling during this
study consisted of Jonah crabs (Cancer spp.), spiny crabs (Rochinia sp.), Gulf Stream flounder
(Citharichthys arctifrons), and larger members of the scorpionfish family (Scorpaenidae). Photographs
of the selected taxa are presented in figure 6. Three additional taxa, the spider crab genus Nibilia, the
rosette skate (Leucoraja garmani), and the hake genus Urophycis were deemed suitable but were either
not collected (in the case of Nibilia sp.) or sufficient numbers were not available to facilitate tissue
sampling.
Gulf Stream Flounde
Figure 6: Examples of Taxa used for Tissue Sampling
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All taxonomic identification and tissue sample processing was coordinated by ANAMAR Environmental
Consulting. Cleaned and decontaminated stainless steel fillet knives and forceps were used to extract
muscle tissues during sample extraction while on the OSV Bold. Equipment contacting tissue samples
were first cleaned and decontaminated. Tissue sample methods and materials followed the guidance of
Pequegnat et al. (1990), but differed in terms of the mass needed for analysis and by the use of Teflon
material in partial replacement of aluminum foil. Efforts were made to extract as much muscle tissue as
possible from each sampled individual in an effort to allow for laboratory splitting of samples and/or
archiving of extra tissues for later use. The minimum amount required by Northeast Analytical, Inc. was
10 grams per sample, but the preferred amount was >25 grams. Muscle tissues from multiple
individuals of a given species and trawl attempts were often combined to allow adequate mass of tissue
for PCB and metal analysis (see Table 2). Upon extraction of tissues, each sample was wrapped in a
portion of pre-cleaned Teflon bag and then wrapped in clean aluminum foil. The wrapped sample was
then double-bagged in Ziploc* bags with attached labels and stored frozen onboard the ship. The
temperature within the freezer was monitored using a thermometer and recorded on a temperature
log. At the end of the survey, tissue samples were shipped via FedEx to NEAfor analysis of percent
lipids, metals, and PCB congeners. Analytes and analytical methods are presented in Appendix B.
Figure 7: Filleting Gulfstream Flounder
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Table 2: Summary of Invertebrates and Fishes Sampled for Tissue Analysis
Tissue
Sample
Number
MT10-01&07
MT10-02&05
MT10-03&04
MT10-06
Taxon Sampled
Citharichthys arctifrons
(Gulf Stream flounder)
Cancer borealis
(Jonah crab)
Rochiniacf. crassa
(spiny crab)
Helicolenus dactylopterus
(blackbelly rosefish)
Number of
Specimens Used in
Sample
29
2
8
1
Estimated Tissue
Wet Weight
(grams)
65
60
85
200
Tow Number
(Station Number)
M10-08-B
M10-22-A
M10-08-A
M10-22-A
M10-08-A
M10-22-A
M10-25-A
2.3 Sediment Chemistry Data Analysis
Total PCB concentration was calculated using two methods consistent with EPA Region 4 guidance (EPA,
2008). The first method included a summation of all 26 PCB congeners analyzed (see Appendix B). The
second method included a summation of 18 congeners identified by NOAA (1989) to approximate
aroclor mixtures. Estimated values (J-flag) were used in the summation, but non-detected congeners
were not in order to minimize the effect of the elevated detection limits. PCB concentrations were also
normalized to total organic carbon as the concentration of organic contaminants and the toxicity of
these contaminants in sediments have been observed to correlate well with the organic carbon content
of sediments (Michelsen, 1992).
Toxicity of sediments has been shown to increase coincidently with increases in both the number of
sediment quality guidelines exceeded and with the chemical concentrations of the mixtures of
substances in the bulk sediments. To account for the mixtures, mean ERM and mean PEL quotients can
be derived as the average of the ratios between the chemical concentrations in the sediments and the
respective ERM or PEL values (Long & MacDonald, 1998). Hyland et. al, (1999) proposed a combined
mean ERM/PEL quotient to include more analytes. This method was used in this analysis to show areas
with the greatest likelihood of adverse environmental effects.
Total PCBs, Copper and mean SQG quotient were analyzed, gridded and plotted with the Surfer grid
based graphics program utilizing kriging. Kriging is a geostatistical gridding method that makes
predictions based upon a weighted mean of sample values. The linear variogram model was used with
default parameters. A grid spacing of approximately 100 feet was used.
10
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3.0 Results
3.1 Sediments
Sediment chemistry results are provided in Appendix D. Copper concentrations ranged from less than 2
ppm to 56.8 ppm near the center of the ODMDS. Copper concentrations were also elevated west of the
ODMDS boundaries. The distribution of copper concentrations is shown in figure 8. Figures 9 and 10
show the Total PCBs concentration using the NOAA and EPA Region 4 summation techniques,
respectively. Yellow areas represent areas with concentrations greater than the TEL and ERL. Orange
areas represent areas with concentrations greater than the PEL and ERM. For the Region 4 summation,
the total area above the TEL/ERL is 890 acres (3.6 km2) or 51% of the survey area. The total area above
the PEL/ERM is 60 acres (0.24 km2) or 36% of the survey area. There does not appear to be any single
congener contributing to the elevated PCB concentrations. Organic carbon normalized PCB results are
presented in figure 11 showing where PCBs are most highly bioavailable. Results of the sediment quality
guideline quotient calculations are shown in figure 12. The total area above the level indicative of a high
risk of benthic impacts is 324 acres (1.3 km2) or 19% of the survey area.
Table 3: Summary of Sediment Impacted by Elevated Copper and PCBs.
Criteria
Above ERL for Copper
Above ERL for Total R4 PCBs
Above ERM for Total R4 PCBs
High Risk of benthic impacts
Moderate Probability of sediment toxicity
Total Area (acres/km2)
531/2.2
890/3.6
60/0.25
324/1.3
161/0.65
11
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Copper Concentration at the Miami ODMDS - 2010
i i i i i
524000-
522000-
520000
0)
O)
c
518000^
516000-
514000^
512000
Copper Concentration
(ppm)
5
c
2
18
t!
3
6 3
•
34 39 55
) W
52 43
A
37 40 48 47
^h. ^h.
C
37 50 42
6 45
+
_
3 5 6
V
57 43
6 10
• 0
8 10
*
50
964000
966000 968000
970000 972000
Easting (feet)
TEL=18.7 ppm: ERL=34.0 ppm; PEL = 108 ppm; ERM = 270 ppm
When concentration less than the ERL, % incidence of effects = 9.4
When concentration greater than the ERL, but less than the ERM, % incidence of effect = 29%
When concentration greater than the ERM, % incidence of effect = 84
Figure 8: 2010 Copper Concentrations at the Miami ODMDS
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524000-
522000-
520000J
CO
C
518000J
516000n
514000^
512000
PCS Concentration
(PPb)
20
0 to 22
22 to 100
100 to 180
180 to 500
500 lo 1000
S($ 1°1 95 I/
17
70 956 515
48
16 156
964000 966000 968000 970000 972000
Easting (feet)
TEUERL = 22 ppb
PEL/ERM = 180 ppb
When concentration less than the ERL, % incidence of effects = 18.5
When concentration greater than the ERL. but less than the ERM, % incidence of effect = 40.8%
When concentration greater than the ERM, % incidence of effect = 51%
Figure 9: 2010 PCBs (NOAA Summation) Concentration at the Miami ODMDS
13
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524000-
522000-
520000-
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524000-
522000-
520000n
-------
524000-
522000-
520000-
CD
0)
c
!c
•c
o
518000-
516000
514000-
512000
964000 966000 968000 970000 972000
Easting (feet)
Moderate probability of toxicity
High risk of benthic impacts
Moderate risk of benthic impacts
Figure 12: 2010 Mean Sediment Quality Guideline Quotient at the Miami ODMDS
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3.2 Tissues
Tissue chemistry results are presented in Appendix E. Copper ranged from below reporting limits to
7.83 mg/kg. PCB congeners were below reporting limits for all samples except for congener 153
(1.29u.g/kg ) in the Spiny Crab. Results are summarized in table 4.
Table 4: Summary of Tissue Chemistry Results
Tissue Sample
Number
MT10-01&07
MT10-02&05
MT10-03&04
MT10-06
Taxon Sampled
Citharichthys arctifrons
(Gulf Stream flounder)
Cancer borealis (Jonah crab)
Rochinia cf. crassa
(spiny crab)
Helicolenus dactylopterus
(blackbelly rosefish)
Copper Concentration
(mg/kg)
<0.93
7.83
4.94
<1.00
Total Region 4 PCB
Concentration (u.g/kg )
16.25*
16.02
16.16
16.29
*no PCB congeners detected. MDLs were used in the summation when a congener was not detected.
For comparison, EPA recently conducted tissue sampling at the Port Everglades ODMDS offshore Fort
Lauderdale, Florida (ANAMAR, 2012). Copper tissue levels at and near the Port Everglades Harbor
ODMDS were measured at 7.6 to 13.6 mg/kg for Jonah crab and 0.15 to 0.22 mg/kg for fish (spotted
hake). Copper results from the Miami ODMDS study are not significantly higher than those offshore Fort
Lauderdale, Florida. For PCBs, a comparison of PCB congener 153 shows higher concentrations at the
Miami ODMDS. Congener 153 was measured at below reporting limits to 0.17 u.g/kg in Jonah crab
offshore Fort Lauderdale, Florida, which is lower than the below reporting limits to 1.29 u.g/kg found in
this study. A direct comparison of total PCBs is difficult due to the high number of non detected
congeners and difference in reporting limits of the two studies.
Additionally, results for PCBs were compared to human health and wildlife criteria. Total PCBs were two
orders of magnitude less than the U.S. Food and Drug Administration's tolerance level of 2 ppm for
human seafood consumption (FDA, 1991) and one order of magnitude less than the 0.13 ppm criterion
for the protection of wildlife that are fish consumers (Newell, 1987).
4.0 Quality Control
All sediment samples were found to have a hydrocarbon matrix interference. As a result, the laboratory
reporting limits were elevated. Additionally, as a result of the matrix interference, the PCB Matrix Spike
Samples and Matrix Spike Duplicate Samples were outside the quality control acceptance limits. Further
investigation revealed that the sediment samples were likely contaminated by cable grease (DynaLube*)
on the OSV Bold cable. The DynaLube was analyzed by NEA and found to be the contaminant present in
the sediment samples (Appendix F). Three archived samples were also analyzed by the EPA Region 4
laboratory to confirm the matrix interference. The Region 4 laboratory found that the samples
contained a number of large unidentified peaks, which caused interference with some of the PCB
17
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congeners and raised the reporting limits (Appendix G). A comparison of the NBA and EPA Region 4
laboratory results are presented in table 5.
Table 5: Comparison of NEA and EPA Region 4 PCB Results (Total EPA Region 4 PCBs)
Sample
MT10-01
MT10-18
MT10-36
NEA
15.0
43.35
8.60
EPA Region 4 Laboratory
18.12
12.50
9.60
Two field splits were collected and analyzed. Results are compared in table 6.
Table 6: Comparison of Field S
jlit Results
Analysis
PCB Congener #180 (u.g/kg )
Total Region 4 PCBs (u.g/kg )
Copper
Total Organic Carbon
Percent Moisture
Split 1
M 10-23
3.37
71.0
55.1
31000
55.1
M 10-42
2.63
56.0
51.7
22000
51.7
Split 2
M 10-37
3.04
31.2
4.5
9500
40.6
M 10-41
<1.91
26.8
33.8
8800
37.3
5.0 Recommendations
The monitoring activities to date have followed the recommended actions in the Miami ODMDS 2008
SMMP. The 2007 Trend Assessment Study indicated a non-seasonal change in sediment quality at the
ODMDS thereby necessitating the need for additional chemical monitoring (this study). The chemical
monitoring has indicated that PCBs and Copper are elevated as defined in the SMMP. Therefore
additional monitoring is warranted. Pursuant to the SMMP, the site should be assessed to determine if it
is a source of adverse bioaccumulation or sublethal changes in benthic organisms, which may endanger
the marine environment. As a significant quantity of dredged material will be disposed at the ODMDS as
part of the Miami Harbor Phase III Deepening Project, resulting in a substantial change in the benthic
characteristics, it is recommended that that a follow-up chemical study be conducted following
completion of the deepening project. A Sediment Profile Imaging Study should also be conducted to
determine the footprint of the deepening project's disposal mound. This follow-up study should include
the ODMDS, the mound footprint and an expanded area to the north and east of the previous survey
area to attempt to further delineate the scope of the elevated copper and PCB levels. In the meantime,
a risk assessment will be conducted using the Bioaccumulation Risk Assessment Modeling System
(BRAMS). BRAMS is an executable program that can be used to calculate, with inputs provided by users,
potential human health and ecological risks due to bioaccumulation of sediment-associated
contaminants (ERDC, 2012). Due to the difficulties in collecting fish tissue samples, additional fish tissue
sampling is not recommended at this time.
18
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ANAMAR Environmental Consulting. 2010. Technical Report: Surveying Miami Ocean Dredged Material
Disposal Site for PCB and Metal Contaminants, Miami, Florida. Prepared for the U.S. Army Corps of
Engineers Jacksonville District. July 2010.
ANAMAR Environmental Consulting. 2012. Final Report Site Designation Study for the Port Everglades
Harbor Ocean Dredged Material Disposal Site Expansion: May 2011 Survey Results. Prepared for the U.S.
Army Corps of Engineers Jacksonville District. January 2012.
Environmental Protection Agency Region 4 (EPA). 2012. Miami, Florida Ocean Dredged Material Disposal
Site(ODMDS) October 2007 Trend Assessment Summary Report. U.S. Environmental Protection Agency
Region 4, Water Management Division. Atlanta, GA. January 2012.
Environmental Protection Agency Region 4 (EPA). 2008. Miami Ocean Dredged Material Disposal Site
(ODMDS) Site Management and Monitoring Plan. U.S. U.S. Environmental Protection Agency Region 4,
Water Management Division. Atlanta, GA. September 2008.
Food and Drug Administration (FDA). 1991. Tolerances of Polychlorinated Biphenyls (PCBs), 21 CFR Ch. 1,
April 1, 1991, Sect 109.30(a)(7), U.S. Food and Drug Administration. Health Human Services, Public
Health Service, Rockville, MD, pp. 96-98.
Germano and Associates. 2006. May 2006 Post-Disposal Sediment Profile Imaging Mapping at the Miami
ODMDS. Prepared for U.S. Environmental Protection Agency Region 4, Water Management Division.
Atlanta, GA. September 2006.
Hyland, J.L., Van Dolah, R.F., and Snoots, T.R. 1999. Predicting Stress in Benthic Communities of
Southeastern U.S. Estuaries in Relation to Chemical Contamination of Sediments. Environmental
Toxicology and Chemistry, Vol. 18, No. 11, pp. 2557-2564.
Long, E.R., Field, L.J., MacDonald, D.D. 1998. Predicting toxicity in marine sediments with numerical
sediment quality guidelines. Environmental Toxicology Chemistry 17:714-727.
MacDonald, D.D., Carr, R.S., Calder, F.D., Long, E.R., and Ingersoll, C.G. 1996. Development and
evaluation of sediment Quality Guidelines for Florida coastal waters. Ecotoxicology 5: 253-278.
Michelsen, T.C. 1992. Technical Information Memorandum: Organic Carbon Normalization of Sediment
Data. Washington Department of Ecology Sediment management Unit. Publication No. 05-09-050.
December 1992.
National Oceanic and Atmospheric Administration (NOAA). 1989. A summary of data on tissue
contamination from the first three years (1986-1988) of the Mussel Watch Program. NOAA Tech. Memo.
NOSOMA49, 154p.
19
-------
National Oceanic and Atmospheric Administration (NOAA). 1999. Sediment Quality Guidelines Developed
for the National Status and Trends Program. June 1999.
Newell, A.J., Johnson, D.W., Allen, L.K. 1987. Niagara River Biota Contamination Project: Fish Flesh
Criteria for Piscivorous Wildlife. Technical Report 87-3. New York State Department of Environmental
Conservation Division of Fish and Wildlife, Bureau of Environmental Protection, Albany, NY. July 1987.
Pacific Northwest National Laboratory 2007. Visual Sample Plan Version 5.0. Prepared for the U.S.
Department of Energy under Contract DE-AC05-76RL01830. PNNL-19693. September 2007.
Pequegnat, W.E., Gallaway, B.J. and Wright, T.D. 1990. Revised procedural guide for designation surveys
of ocean dredged material dumping sites. U.S. Army Corps of Engineers, Dredging Operations Technical
Support Program, Technical Report D-90-8.
U.S. Army Engineer Research and Development Center. 2012. Bioaccumulation Risk Assessment
Modeling System. Prepared for U.S. Army Corps of Engineers and U.S. Environmental Protection Agency.
May 2012.
20
-------
APPENDIX A
Sediment Sample Locations and
Descriptions
-------
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-------
Sediment Sampling Stations and Sample Characteristics
Station
Number
M10-01
Ml 0-02
Ml 0-03
Ml 0-04
M10-05
Ml 0-06
Ml 0-07
M10-08
Ml 0-09
M10-10
M10-11
M10-12
M10-13
M10-14
M10-15
M10-16
M10-17
M10-18
M10-19
Ml 0-20
M10-21
Ml 0-22
Ml 0-23
Ml 0-24
Ml 0-25
Ml 0-26
M10-26R
Ml 0-27
Ml 0-28
Ml 0-29
M10-30
M10-31
M10-32
M10-33
M10-34
M10-35
M10-36
M10-37
M10-38
M10-39
Ml 0-40
Latitude
25 44.617' N
25 44.644' N
25 44.614' N
25 44.616' N
25 44.607' N
25 44.782' N
25 44.769' N
25 44.777' N
25 44.779' N
25 44.781' N
25 44.961' N
25 44.952' N
25 44.93' N
25 44.973' N
25 44.961' N
25 45. 093' N
25 45. 119' N
25 45. 113' N
25 45. 115' N
25 45.111'N
2545. 287' N
25 45. 282' N
25 45. 266' N
25 45. 242' N
25 45. 257' N
25 45. 423' N
25 45.44'N
25 45. 428' N
25 45. 462' N
25 45. 439' N
25 45.451' N
25 44.676' N
25 44.938' N
2545. 254' N
25 44.95' N
25 45.589' N
25 45. 594' N
25 45. 884' N
25 45.888' N
25 46. 199' N
25 46.201' N
Longitude
80 3.745' W
80 3.539'W
80 3.316' W
80 3.097' W
80 2.899' W
80 3.849' W
80 3.607' W
80 3.413' W
80 3.17'W
80 2.961' W
80 3.712' W
80 3.531'W
80 3.303' W
80 3.082' W
80 2.864' W
80 3.851'W
80 3.633' W
80 3.388' W
80 3.201' W
80 2.998' W
80 3.634' W
80 3.509'W
80 3.275' W
80 3.114'W
80 2.89' W
80 3.858'W
80 3.847' W
80 3.626' W
80 3.398' W
80 3.18'W
80 3.004' W
80 2.541' W
80 2.621' W
802.533' W
80 2.428' W
80 3.412' W
80 3.047' W
80 3.613' W
80 3.245' W
80 3.433' W
80 3.028' W
Depth (m)
135
153
179
205
226
130
150
169
198
222
141
158
183
208
230
131
149
165
193
218
152
164
186
212
232
130
134
150
174
200
222
245
243
246
248
175
218
156
198
179
225
Sediment
Texture
V. FINE SAND
V. FINE SAND
V. FINE SAND
SLIGHT CLAY
SILT/CLAY
FINE SAND
FINE SAND
V. FINE SAND
FINE SAND
V. FINE SAND
SILT/CLAY
SILT/CLAY
FINE SAND
SILT/CLAY
FINE SAND
SILT/CLAY
FINE SAND
FINE SAND
MED SAND
V. FINE SAND
FINE SAND
FINE SAND
V. FINE SAND
V. FINE SAND
V. FINE SAND
FINE SAND
MED. SAND
V. FINE SAND
FINE SAND
V FINE SAND
V. FINE SAND
V. FINE SAND
SILT/CLAY
V. FINE SAND
FINE SAND
FINE SAND
V. FINE SAND
V.FINE SAND
V. FINE SAND
V. FINE SAND
SILT/CLAY
Sediment Color (after
homogenization)
GREENISH GRAY
LIGHT GRAY
LIGHT GRAY
LIGHT GRAY
GREENISH GRAY
LIGHT GRAY
LIGHT GRAY
GREENISH GRAY
LIGHT GRAY
LIGHT GRAY
GREENISH GRAY
LIGHT GRAY
LIGHT GRAY
LIGHT GRAY
LIGHT GRAY
LIGHT GRAY
LIGHT GRAY
LIGHT GRAY
OLIVE GRAY
LIGHT GRAY
LIGHT GRAY
LIGHT GRAY
LIGHT GRAY
LIGHT GRAY
LIGHT GRAY
LIGHT GRAY
LIGHT GRAY
LIGHT GRAY
LIGHT GRAY
LIGHT GRAY
LIGHT GRAY
LIGHT GRAY
GREENISH GRAY
LIGHT GRAY
GREENISH GRAY
OLIVE GRAY
LIGHT GRAY
LIGHT GRAY
LIGHT GRAY
LIGHT GRAY
LIGHT GRAY
Further Notes
SOMEWHAT PLASTIC
STRONG H2s ODOR
SLIGHT ODOR
FIELD SPLIT:
Ml 0-42
RE-SAMPLED
NO ODOR, CHUNKS
OF LIMESTONE
TUBE WORMS AND
SMALL ROCKS
NO ODOR
MUNIDA SP., NO
ODOR
NO ODOR
FIELD SPLIT:
M10-41
-------
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-------
APPENDIX B
Analytes, Methods and Detection Limits
-------
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-------
Analvtes and Analytical Methods
PCB Congener
2.4' diCB
2,2',5 triCB
2,4,4' triCB
2,2'.3,5' tetraCB
2,2'.4',5 tetraCB
2,2'5,5' tetraCB
2,3',4,4' tetraCB
3,3',4,4' tetraCB
2,2',3,4,5'peutaCB
2,2',4,5,5' peutaCB
2,3,3'4,4' peutaCB
2,3'.4,4',5 peutaCB
3, 3 '.4,4', 5 peutaCB
2.3.3'.4.4' peutaCB
2,2'.3.4,4',5' hexaCB
2.2'.4.4',5,5' hexaCB
7,3.3',4.4',5 hexaCB
3,3'A4',5,5' hexaCB
2,2',3,3',4,4'5 heptaCB
2,2',3,4,4',5,5' heptaCB
2,2',3,4,4',5'.6 heptaCB
2,2',3.4,4',6,6' heptaCB
2,2',3,4',5,5'.6 heptaCB
2,2',3.3',4,4'.5.6 octaCB
2,2I,3,3',4.4',5.5I,6 uouaCB
2,2',3,3',4,4'.5,5',6,6' decaCB
Congener
Number
8
18
28
44
49
52
66
77
87
101
105
118
126
128
138
153
156
169
170
180
183
184
187
195
206
209
Matrix
Sediments/Tissue
Sediments/Tissue
Sedimeuts/Tissue
Sediments 'Tissue
Sedimeuts/Tissue
Sedimeuts/Tissue
Sediments Tissue
S ediuients/Tissue
Sediments Tissue
Sediments/Tissue
Sediments/Tissue
Sediments/Tissue
Sedimeuts/Tissue
Sedimeuts/Tissue
Sediments/Tissue
Sediments/Tissue
Sediments/Tissue
S ediuients/Tissue
Sediments/Tissue
S ediuieuts/Tissue
SediuientsTissue
Sediments/Tissue
Sediments/Tissue
Sediments/Tissue
SediuieutsTissue
Sedimeuts/Tissue
Method
SW-846 Method 8082
SW-846 Method 8082
SW-846 Method 8082
SW-846 Method 8082
SW-846 Method 8082
SW-846 Method 8082
SW-846 Method 8082
SW-846 Method 8082
SW-846 Method 8082
SW-846 Method 8082
SW-846 Method 8082
SW-846 Method 8082
SW-846 Method 8082
SW-846 Method 8082
SW-846 Method 8082
SW-846 Method 8082
SW-846 Method 8082
SW-846 Method 8082
SW-846 Method 8082
SW-846 Method 8082
SW-846 Method 8082
SW-846 Method 8082
SW-846 Method 8082
SW-846 Method 8082
SW-846 Method 8082
SW-846 Method 8082
Metal
Arsenic
Cadmium
Chromium
Copper
Lead
Nickel
Silver
Zinc
Matrix
Sediments/Tissue
Sedimeuts/Tissue
Sedimeuts/Tissue
Sedimeuts/Tissue
Sedimeuts/Tissue
6020
6020
6020
Method
SW-846 601 OB
SW-846 601 OB
SW-846 601 OB
SW-846 6010B
SW-846 601 OB
SW-846 601 OB
SW-846 601 OB
SW-846 601 OB
-------
Analysis
Total Organic Carbon
Percent Moisture
Lipids
Matrix
Sediments
Sediments
Tissue
Method
High-temperature Combustion
SW-846 3545 DRV. 7.2.1.
NEA SOP NEI1 58.05
-------
APPENDIX C
Trawl Locations
-------
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-------
Epibenthic Trawls
Eight epibenthic trawls were conducted of 5 to 15 minutes in duration at speeds of 1.7 to 1.8 knots over
ground. Two trawls resulted in no organisms collected due to net damage or net loss and two trawls did
not have either any taxa of interest or insufficient body mass for tissue collection. The four successful
trawls are shown in figure 1 below:
Figure C-1: Epibenthic Trawls
A summary of the trawls is provided in table C-1 and table C-2 presents a summary of the tissue samples
collected. Table C-3 provides a list of all taxa identified from the trawl catches.
Table C-1: Trawl Summary
Tow
Number
M10-08-A
M10-08-B
M10-20-A
M10-22-A
M10-22-B
M10-24-A
M10-25-A
M10-25-B
Start of Tow
Latitude
25 44.874 N
25 44.836 N
25 45.214 N
25 45. 730 N
25 45.571 N
25 45.423 N
25 45.338 N
25 45. 424 N
Longitude
80 3.475W
80 3.291 W
80 3.021 W
80 3.489W
80 3.488 W
80 3.087 W
80 2.937 W
80 2.917 W
End of Tow
Latitude
25 44.861 N
25 44.814 N
25 45.059 N
25 45. 254 N
25 45. 114 N
25 44.969 N
25 45. 197 N
25 45. 138 N
Longitude
80 3.295W
80 2.957 W
80 3.020W
80 3.480W
80 3.501 W
80 3.143W
80 2.935 W
80 2.915 W
Depth
Range
(m)
195-217
208-238
221-222
165-168
159-165
204-211
231-232
231-232
Bottom
Time
(minutes)
5
10
6
17
16
16
6
11
Notes
Bridle twisted, limestone rabble in net,
5 taxa caught
Only 2 taxa caught
Net damaged, tickler chain damaged, 4
taxa caught
Net damaged, portion of tow was
outside of ODMDS, 20 taxa caught
Net lost, otter doors badly damaged
but retrieved
Net badly damaged, no taxa caught
1 m diameter truck tire in net, 4 taxa
caught
Limestone rabble in net, 2 taxa caught
-------
Table C-2: Summary of Invertebrates and Fishes Sampled for Tissue Analysis
Tissue
Sample
Number
MT10-01
MT10-02
MT10-03
MT10-04
MT10-05
MT10-06
MT10-07
Taxon Sampled
Citharichthys arctifrons
(Gulf Stream flounder)
Cancer borealis
(Jonah crab)
Rochinia cf. crassa
(spiny crab)
Rochinia cf. crassa
(spiny crab)
Cancer borealis
(Jonah crab)
Helicolenus dactylopterus
(blackbelly rosefish)
Citharichthys arctifrons
(Gulf Stream flounder)
Number of
Specimens Used in
Sample
5
1
9
Approx. 6
1
1
Approx. 24
Estimated Tissue
Wet Weight
(grams)
15
30
35
50
30
200
50
Tow Number
(Station Number)
M10-08-B
(M10-08)
M10-08-A
(M10-08)
M10-08-A
(M10-08)
M10-22-A
(M10-22)
M10-22-A
(M10-22)
M10-25-A
(M10-25)
M10-22-A
(M10-22)
Table C-3: Taxa Identified from Trawl Catches
Taxon
Cerianthidae
Hexactinellida
Polychaeta
Polystira sp.
Scaphella dorni
Loliginidae
Penaeidae
Munida sp.
Bathynectes longispina
Cancer borealis
Rochinia cf. crassa
Leucoraja garmani
Lepophidium profundorum
Bregmaceros sp.
Urophycis cf. chesteri
Zalieutes mcgintys
Macroramphosus scolopax
Helicolenus dactylopterus
Pontinus longispinus
Peristedion miniatum
Anthias nicholsi
Foetorepus goodenbeani
Citharichthys arctifrons
Monolene sessilicauda
Symphurus cf. pusillus
Laemonema barbatulum
Common Name
Burrowing anemone
Glass sponge
Polychaete worm
Giant turris
Dohrn's volute
Squid
Penaeid shrimp
Squat lobster
Bathyal swimming crab
Jonah crab
Spiny crab
Rosette skate
Fawn cusk-eel
Codlet
Longfm hake
Tricorn batfish
Longspine snipefish
Blackbelly rosefish
Longspine scorpionfish
Armored searobin
Yellowfin bass
Palefm dragonet
Gulf Stream flounder
Deepwater flounder
Northern tonguefish
Shortbeard codling
Taxa identification by ANAMAR Environmental Consulting, Inc.
-------
APPENDIX D
Sediment Chemistry Results
-------
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-------
Station M10-
ANALYTE
PCB Congener #008
PCB Congener #01 8
PCB Congener #028 20,45,51
PCB Congener #044 47,39,65
PCB Congener #049 36
PCB Congener #052
PCB Congener #066
PCB Congener #077 111,151
PCB Congener #087
PCB Congener #101 90,113,150
PCB Congener #105 146
PCB Congener #11 8
PCB Congener #126 182
PCB Congener #128 166
PCB Congener #138 129,163
PCB Congener #153 168
PCB Congener #156 157,197
PCB Congener #169
PCB Congener #170
PCB Congener #180 193
PCB Congener #183
PCB Congener #184 165
PCB Congener #187
PCB Congener #195
PCB Congener #206
PCB Congener #209
Nonachlorobiphenyl
Total Organic Carbon
% Moisture
Arsenic
Cadmium
Chromium
Copper
Lead
Nickel
Silver
Zinc
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/Kg
mg/kg
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
1
CONG
ND
ND
000104
0.000989
000101
000126
ND
0.000557
0.000649
000177
0.000985
000141
ND
0.000413
0 00234
000159
0 00048
ND
ND
0.000502
ND
ND
ND
ND
ND
ND
0.0699
11000
392
2.77
ND
7.34
3.38
1.7
2.7
ND
4.55
FLAG
U
U
J
J
J
J
U
J
J
J
J
J
U
J
J
J
U
U
J
U
U
U
U
U
U
U
U
PQL
0.00195
0.00195
0.00195
0.00195
0.00195
0.00195
0.00195
0.00195
0.00195
0.00195
0.00195
0.00195
0.00195
0.00195
0.00195
0.00195
0.00195
0.00195
0.00195
0.00195
0.00195
0.00195
0.00195
0.00195
0.00195
0.00195
320
0.0205
1.48
0.148
1.48
1.48
0.738
1.48
0.295
1.48
J-Denotes concentration result greater thant he MDL, but less than the PQL
U-Denotes analyte not observed at a concentration greater than the MDL
MDL
0.00039
0.00039
0.00039
0.00039
0.00039
0.00039
0.00039
0.00039
0.00039
0.00039
0.00039
0.00039
0.00039
0.00039
0.00039
0.00039
0.00039
0.00039
0.00039
0.00039
0.00039
0.00039
0.00039
0.00039
0.00039
0.00039
2
CONG
ND
ND
0.000979
0.00135
0.0013
0.00152
ND
ND
ND
0.000583
ND
ND
ND
ND
0.000892
0.000742
ND
ND
ND
0.000591
ND
ND
0.000438
ND
ND
0.000494
0.0737
10000
42.8
3.16
ND
8.53
4.7
3.28
2.81
0336
6.39
FLAG
U
U
J
J
J
J
U
U
U
J
U
U
U
U
J
J
U
U
U
J
U
U
J
U
U
J
U
PQL
0.00207
0.00207
0.00207
0.00207
0.00207
0.00207
0.00207
0.00207
0.00207
0.00207
0.00207
0.00207
0.00207
0.00207
0.00207
0.00207
0.00207
0.00207
0.00207
0.00207
0.00207
0.00207
0.00207
0.00207
0.00207
0.00207
340
00186
1.6
0.16
1.6
1.6
0.801
1.6
0.321
1.6
MDL
0000415
0000415
0000415
0000415
0000415
0000415
0000415
0000415
0000415
0000415
0000415
0000415
0000415
0000415
0000415
0000415
0000415
0000415
0000415
0000415
0000415
0000415
0000415
0000415
0000415
0000415
3
CONG
ND
ND
0.000829
000162
0.0012
0.000824
0.000351
0.000381
ND
000111
0.000655
0.000623
ND
ND
000126
000122
ND
ND
ND
0.000745
ND
ND
0.000496
ND
ND
ND
0.0592
7700
32.5
3.53
ND
7.68
5.97
5.64
1.9
0.395
8.69
FLAG
U
U
J
J
J
J
J
J
U
J
J
J
U
U
J
J
U
U
U
J
U
U
J
U
U
U
U
PQL
0.00174
0.00174
0.00174
0.00174
0.00174
0.00174
0.00174
0.00174
0.00174
0.00174
0.00174
0.00174
0.00174
0.00174
0.00174
0.00174
0.00174
0.00174
0.00174
0.00174
0.00174
0.00174
0.00174
0.00174
0.00174
0.00174
270
0.02
1.38
0.138
1.38
1.38
0.69
1.38
0.276
1.38
MDL
0.000348
0.000348
0.000348
0.000348
0.000348
0.000348
0.000348
0.000348
0.000348
0.000348
0.000348
0.000348
0.000348
0.000348
0.000348
0.000348
0.000348
0.000348
0.000348
0.000348
0.000348
0.000348
0.000348
0.000348
0.000348
0.000348
4
CONG
ND
ND
0.00124
0.00253
0.00189
0.00164
ND
ND
ND
0.000788
ND
0.000646
ND
ND
0.00132
0.00122
ND
ND
ND
0.000732
ND
ND
0.000519
ND
ND
ND
0.0833
13000
45.5
2.79
ND
10.5
7.58
5.08
3.81
ND
10.1
FLAG
U
U
J
J
J
U
U
U
J
U
J
U
U
J
J
U
U
U
J
U
U
J
U
U
U
U
U
PQL
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
370
00196
1.74
0.174
1.74
1.74
0.872
1.74
0.349
1.74
MDL
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
-------
Station M10-
ANALYTE
PCB Congener #008
PCB Congener #01 8
PCB Congener #028 20,45,51
PCB Congener #044 47,39,65
PCB Congener #049 36
PCB Congener #052
PCB Congener #066
PCB Congener #077 111,151
PCB Congener #087
PCB Congener #101 90,113,150
PCB Congener #105 146
PCB Congener #11 8
PCB Congener #126 182
PCB Congener #128 166
PCB Congener #138 129,163
PCB Congener #153 168
PCB Congener #156 157,197
PCB Congener #169
PCB Congener #170
PCB Congener #180 193
PCB Congener #183
PCB Congener #184 165
PCB Congener #187
PCB Congener #195
PCB Congener #206
PCB Congener #209
Nonachlorobiphenyl
Total Organic Carbon
% Moisture
Arsenic
Cadmium
Chromium
Copper
Lead
Nickel
Silver
Zinc
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/Kg
mg/kg
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
5
CONG
ND
ND
0.001
000132
0.0016
0.0016
ND
ND
ND
000107
0.000522
0.000563
ND
ND
000141
000151
ND
ND
ND
0.000798
ND
ND
0.000574
ND
ND
ND
0.0853
16000
48
3.41
ND
109
9.93
6.56
4.34
ND
11.6
J-Denotes concentration result greater thant he l\
U-Denotes analyte not observed at a concentrati
FLAG
U
U
J
J
J
J
U
U
U
J
J
J
U
U
J
J
U
U
U
J
U
U
J
U
U
U
U
U
PQL
0.00235
0.00235
0.00235
0.00235
0.00235
0.00235
0.00235
0.00235
0.00235
0.00235
0.00235
0.00235
0.00235
0.00235
0.00235
0.00235
0.00235
0.00235
0.00235
0.00235
0.00235
0.00235
0.00235
0.00235
0.00235
0.00235
390
0.0191
1.9
0.19
1.9
1.9
095
1.9
038
1.9
MDL
0.000469
0.000469
0.000469
0.000469
0.000469
0.000469
0.000469
0.000469
0.000469
0.000469
0.000469
0.000469
0.000469
0.000469
0.000469
0.000469
0.000469
0.000469
0.000469
0.000469
0.000469
0.000469
0.000469
0.000469
0.000469
0.000469
31
CONG
ND
ND
0.000898
0.000966
0.00154
0.00265
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.0843
15000
48.9
3.54
ND
10.1
5.53
3.62
4.97
0386
8.58
FLAG
U
U
J
J
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PQL
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
350
00198
1.83
0.183
1.83
1.83
0.913
1.83
0.365
1.83
MDL
0 000459
0 000459
0 000459
0 000459
0 000459
0 000459
0 000459
0 000459
0 000459
0 000459
0 000459
0 000459
0 000459
0 000459
0 000459
0 000459
0 000459
0 000459
0 000459
0 000459
0 000459
0 000459
0 000459
0 000459
0 000459
0 000459
10
CONG
ND
ND
000128
000165
0 00273
000315
0.000716
ND
ND
000176
0.000898
000134
ND
ND
000213
000192
0.000539
ND
0.000495
000107
ND
ND
0.000619
ND
ND
0 00055
0.0882
17000
49.4
3.74
ND
10.7
10
8.78
3.65
ND
13.2
FLAG
U
U
J
J
J
U
U
J
J
J
U
U
J
J
J
U
J
J
U
U
J
U
U
J
U
U
PQL
0.0024
0.0024
0.0024
0.0024
0.0024
0.0024
0.0024
0.0024
0.0024
0.0024
0.0024
0.0024
0.0024
0.0024
0.0024
0.0024
0.0024
0.0024
0.0024
0.0024
0.0024
0.0024
0.0024
0.0024
0.0024
0.0024
380
0.0197
1.75
0.175
1.75
1.75
0.877
1.75
0.351
1.75
MDL
0 00048
0 00048
0 00048
0 00048
0 00048
0 00048
0 00048
0 00048
0 00048
0 00048
0 00048
0 00048
0 00048
0 00048
0 00048
0 00048
0 00048
0 00048
0 00048
0 00048
0 00048
0 00048
0 00048
0 00048
0 00048
0 00048
9
CONG
0.00164
0.00107
0.0057
0.00404
0.00317
0.00388
0.00169
0.000415
ND
0.00124
0.000661
0.000945
ND
ND
0.00139
0.00114
ND
ND
ND
0.000705
ND
ND
0.000474
ND
ND
ND
0.0683
8600
37
3.39
ND
8
6.01
5.25
2.35
ND
8.46
FLAG
J
J
J
J
U
J
J
J
U
U
J
J
U
U
U
J
U
U
J
U
U
U
U
U
PQL
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
300
00179
1.44
0.144
1.44
1.44
0.718
1.44
0.287
1.44
MDL
0.000374
0.000374
0.000374
0.000374
0.000374
0.000374
0.000374
0.000374
0.000374
0.000374
0.000374
0.000374
0.000374
0.000374
0.000374
0.000374
0.000374
0.000374
0.000374
0.000374
0.000374
0.000374
0.000374
0.000374
0.000374
0.000374
-------
Station M10-
ANALYTE
PCB Congener #008
PCB Congener #01 8
PCB Congener #028 20,45,51
PCB Congener #044 47,39,65
PCB Congener #049 36
PCB Congener #052
PCB Congener #066
PCB Congener #077 111,151
PCB Congener #087
PCB Congener #101 90,113,150
PCB Congener #105 146
PCB Congener #11 8
PCB Congener #126 182
PCB Congener #128 166
PCB Congener #138 129,163
PCB Congener #153 168
PCB Congener #156 157,197
PCB Congener #169
PCB Congener #170
PCB Congener #180 193
PCB Congener #183
PCB Congener #184 165
PCB Congener #187
PCB Congener #195
PCB Congener #206
PCB Congener #209
Nonachlorobiphenyl
Total Organic Carbon
% Moisture
Arsenic
Cadmium
Chromium
Copper
Lead
Nickel
Silver
Zinc
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/Kg
mg/kg
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
8
CONG
ND
ND
000215
0 00492
0 00259
000217
0.000843
0.000737
0.000727
0 00255
0.0012
0.0017
ND
0 00047
0 00293
0 00274
ND
ND
0 00056
000143
ND
ND
000108
ND
ND
ND
0.0832
15000
46
2.93
ND
11.6
449
109
3.24
ND
15.4
J-Denotes concentration result greater thant he l\
U-Denotes analyte not observed at a concentrati
FLAG
U
U
J
J
J
J
J
J
J
U
J
U
U
J
J
U
U
J
U
U
U
U
U
PQL
0.00224
0.00224
0.00224
0.00224
0.00224
0.00224
0.00224
0.00224
0.00224
0.00224
0.00224
0.00224
0.00224
0.00224
0.00224
0.00224
0.00224
0.00224
0.00224
0.00224
0.00224
0.00224
0.00224
0.00224
0.00224
0.00224
360
0.0186
1.71
0.171
1.71
1.71
0.857
1.71
0.343
1.71
MDL
0.000448
0.000448
0.000448
0.000448
0.000448
0.000448
0.000448
0.000448
0.000448
0.000448
0.000448
0.000448
0.000448
0.000448
0.000448
0.000448
0.000448
0.000448
0.000448
0.000448
0.000448
0.000448
0.000448
0.000448
0.000448
0.000448
7
CONG
ND
ND
0.00142
0.00226
0.00196
0.00182
ND
ND
ND
0.000513
ND
ND
ND
ND
0.000685
0.000629
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.0896
13000
49.9
3.05
ND
9.74
5.67
3.61
3.72
ND
7.72
FLAG
U
U
J
J
J
J
U
U
U
J
U
U
U
U
J
J
U
U
U
U
U
U
U
U
U
U
U
U
PQL
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
370
00189
1.81
0.181
1.81
1.81
0.907
1.81
0.363
1.81
MDL
0 000484
0 000484
0 000484
0 000484
0 000484
0 000484
0 000484
0 000484
0 000484
0 000484
0 000484
0 000484
0 000484
0 000484
0 000484
0 000484
0 000484
0 000484
0 000484
0 000484
0 000484
0 000484
0 000484
0 000484
0 000484
0 000484
6
CONG
ND
ND
000109
0.000545
000121
000172
0.000422
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.0685
10000
36.9
2.3
ND
7.47
3.45
1.58
2.81
ND
4.52
FLAG
U
U
J
J
J
J
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PQL
0.00188
0.00188
0.00188
0.00188
0.00188
0.00188
0.00188
0.00188
0.00188
0.00188
0.00188
0.00188
0.00188
0.00188
0.00188
0.00188
0.00188
0.00188
0.00188
0.00188
0.00188
0.00188
0.00188
0.00188
0.00188
0.00188
310
0.0187
1.47
0.147
1.47
1.47
0.735
1.47
0.294
1.47
MDL
0.000376
0.000376
0.000376
0.000376
0.000376
0.000376
0.000376
0.000376
0.000376
0.000376
0.000376
0.000376
0.000376
0.000376
0.000376
0.000376
0.000376
0.000376
0.000376
0.000376
0.000376
0.000376
0.000376
0.000376
0.000376
0.000376
39
CONG
0.00241
0.0021
0.00631
0.00348
0.00304
0.00359
0.00195
0.000993
0.000488
0.00176
0.000775
0.000895
ND
ND
0.00217
0.00231
0.000431
ND
0.000657
0.00192
ND
ND
0.00106
ND
ND
ND
0.0681
11000
33.1
2.91
ND
6.99
4.43
3
1.89
ND
6.4
FLAG
J
J
J
J
J
U
U
J
U
J
U
U
J
U
U
U
U
U
PQL
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
290
00182
1.36
0.136
1.36
1.36
0.682
1.36
0.273
1.36
MDL
0.000369
0.000369
0.000369
0.000369
0.000369
0.000369
0.000369
0.000369
0.000369
0.000369
0.000369
0.000369
0.000369
0.000369
0.000369
0.000369
0.000369
0.000369
0.000369
0.000369
0.000369
0.000369
0.000369
0.000369
0.000369
0.000369
-------
Station M10-
ANALYTE
PCB Congener #008
PCB Congener #01 8
PCB Congener #028 20,45,51
PCB Congener #044 47,39,65
PCB Congener #049 36
PCB Congener #052
PCB Congener #066
PCB Congener #077 111,151
PCB Congener #087
PCB Congener #101 90,113,150
PCB Congener #105 146
PCB Congener #11 8
PCB Congener #126 182
PCB Congener #128 166
PCB Congener #138 129,163
PCB Congener #153 168
PCB Congener #156 157,197
PCB Congener #169
PCB Congener #170
PCB Congener #180 193
PCB Congener #183
PCB Congener #184 165
PCB Congener #187
PCB Congener #195
PCB Congener #206
PCB Congener #209
Nonachlorobiphenyl
Total Organic Carbon
% Moisture
Arsenic
Cadmium
Chromium
Copper
Lead
Nickel
Silver
Zinc
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/Kg
mg/kg
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
40
CONG
ND
ND
0 00254
000215
0 00238
0 00292
0.000771
ND
ND
0.000786
ND
0 00049
ND
ND
0.000575
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.0899
18000
493
4.25
ND
93
5.39
2.63
4.17
ND
7.37
J-Denotes concentration result greater thant he l\
U-Denotes analyte not observed at a concentrati
FLAG
U
U
J
J
J
U
U
J
U
J
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
PQL
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
380
0.0194
1 81
0.181
1 81
1 81
0.905
1 81
0.362
1 81
MDL
0.000485
0.000485
0.000485
0.000485
0.000485
0.000485
0.000485
0.000485
0.000485
0.000485
0.000485
0.000485
0.000485
0.000485
0.000485
0.000485
0.000485
0.000485
0.000485
0.000485
0.000485
0.000485
0.000485
0.000485
0.000485
0.000485
38
CONG
0.0186
0.0296
0.0403
0.0194
0.0126
0.0147
0.0118
0.000825
0.00193
0.00339
0.0017
0.00296
ND
ND
0.00147
0.00109
ND
ND
ND
0.000485
ND
ND
ND
ND
ND
ND
0.0718
9900
39.9
2.58
ND
8.02
5.09
3.2
2.57
ND
6.47
FLAG
J
J
J
U
U
J
J
U
U
U
J
U
U
U
U
U
U
U
U
PQL
0.002
0.002
0.002
0.002
0.002
0.002
0.002
0.002
0.002
0.002
0.002
0.002
0.002
0.002
0.002
0.002
0.002
0.002
0.002
0.002
0.002
0.002
0.002
0.002
0.002
0.002
300
00175
1.55
0.155
1.55
1.55
0.777
1.55
0.311
1.55
MDL
0.0004
0.0004
0.0004
0.0004
0.0004
0.0004
0.0004
0.0004
0.0004
0.0004
0.0004
0.0004
0.0004
0.0004
0.0004
0.0004
0.0004
0.0004
0.0004
0.0004
0.0004
0.0004
0.0004
0.0004
0.0004
0.0004
37
CONG
ND
ND
000173
0.000923
000189
0 00295
0.000497
0.000661
ND
0.000452
ND
ND
ND
ND
000151
000196
0.000421
ND
000101
0 00304
0.000608
ND
000167
ND
ND
0.000422
0.0744
9500
40.6
3.78
ND
7.54
4.5
9.44
2.34
ND
5.36
FLAG
U
U
J
J
J
J
J
U
J
U
U
U
U
J
J
J
U
J
J
U
J
U
U
J
U
U
PQL
0.00209
0.00209
0.00209
0.00209
0.00209
0.00209
0.00209
0.00209
0.00209
0.00209
0.00209
0.00209
0.00209
0.00209
0.00209
0.00209
0.00209
0.00209
0.00209
0.00209
0.00209
0.00209
0.00209
0.00209
0.00209
0.00209
330
0.0199
1.64
0.164
1.64
1.64
0.819
1.64
0.328
1.64
MDL
0.000417
0.000417
0.000417
0.000417
0.000417
0.000417
0.000417
0.000417
0.000417
0.000417
0.000417
0.000417
0.000417
0.000417
0.000417
0.000417
0.000417
0.000417
0.000417
0.000417
0.000417
0.000417
0.000417
0.000417
0.000417
0.000417
36
CONG
ND
ND
0.000913
0.00199
0.00169
0.00191
ND
ND
ND
0.000524
ND
ND
ND
ND
0.00051
0.00061
ND
ND
ND
0.000449
ND
ND
ND
ND
ND
ND
0.0777
13000
44.4
ND
ND
8.66
4.66
2.63
3.88
ND
6.02
FLAG
U
U
J
J
J
J
U
U
U
J
U
U
U
U
J
J
U
U
U
J
U
U
U
U
U
U
U
U
U
PQL
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
330
00191
1.63
0.163
1.63
1.63
0.816
1.63
0.326
1.63
MDL
0.000439
0.000439
0.000439
0.000439
0.000439
0.000439
0.000439
0.000439
0.000439
0.000439
0.000439
0.000439
0.000439
0.000439
0.000439
0.000439
0.000439
0.000439
0.000439
0.000439
0.000439
0.000439
0.000439
0.000439
0.000439
0.000439
-------
Station M10-
ANALYTE
PCB Congener #008
PCB Congener #01 8
PCB Congener #028 20,45,51
PCB Congener #044 47,39,65
PCB Congener #049 36
PCB Congener #052
PCB Congener #066
PCB Congener #077 111,151
PCB Congener #087
PCB Congener #101 90,113,150
PCB Congener #105 146
PCB Congener #11 8
PCB Congener #126 182
PCB Congener #128 166
PCB Congener #138 129,163
PCB Congener #153 168
PCB Congener #156 157,197
PCB Congener #169
PCB Congener #170
PCB Congener #180 193
PCB Congener #183
PCB Congener #184 165
PCB Congener #187
PCB Congener #195
PCB Congener #206
PCB Congener #209
Nonachlorobiphenyl
Total Organic Carbon
% Moisture
Arsenic
Cadmium
Chromium
Copper
Lead
Nickel
Silver
Zinc
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/Kg
mg/kg
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
30
CONG
0.000531
ND
000165
0 00301
0.003
000316
0.000447
0.000456
ND
0.000602
ND
ND
ND
ND
000101
000119
ND
ND
0.000469
000135
ND
ND
0.0008
ND
ND
ND
0.0825
16000
44
ND
ND
8.55
4.61
1 8
3.81
ND
8.34
J-Denotes concentration result greater thant he l\
U-Denotes analyte not observed at a concentrati
FLAG
J
U
J
J
J
U
J
U
U
U
U
J
J
U
U
J
J
U
U
J
U
U
U
U
U
U
PQL
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
330
0.0204
1.67
0.167
1.67
1.67
0.835
1.67
0.334
1.67
MDL
0.000426
0.000426
0.000426
0.000426
0.000426
0.000426
0.000426
0.000426
0.000426
0.000426
0.000426
0.000426
0.000426
0.000426
0.000426
0.000426
0.000426
0.000426
0.000426
0.000426
0.000426
0.000426
0.000426
0.000426
0.000426
0.000426
29
CONG
ND
ND
0.000916
0.00297
0.00259
0.00376
ND
ND
ND
0.000709
ND
ND
ND
ND
0.000787
0.00079
ND
ND
ND
0.000771
ND
ND
0.000602
ND
ND
ND
0.0634
9400
35
2.13
ND
6.52
3.46
1.4
1.98
ND
4.3
FLAG
U
U
J
U
U
U
J
U
U
U
U
J
J
U
U
U
J
U
U
J
U
U
U
U
U
PQL
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
0.00187
280
0.019
1.47
0.147
1.47
1.47
0.737
1.47
0.295
1.47
MDL
0 000375
0 000375
0 000375
0 000375
0 000375
0 000375
0 000375
0 000375
0 000375
0 000375
0 000375
0 000375
0 000375
0 000375
0 000375
0 000375
0 000375
0 000375
0 000375
0 000375
0 000375
0 000375
0 000375
0 000375
0 000375
0 000375
28
CONG
ND
ND
0 00293
0 00534
0 00543
0 00492
0.000869
000107
0.000805
0 00291
000113
0 00205
ND
0.000869
0 00372
0 00333
0.000602
ND
0.000662
000215
0.000445
ND
000161
ND
0.000376
ND
0.0721
13000
34.4
4.16
ND
9.07
36.2
10.6
2.11
ND
17
FLAG
U
U
J
J
J
J
U
J
J
U
J
J
U
J
U
J
U
U
U
PQL
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
0.00185
300
0.0189
1.49
0.149
1.49
1.49
0.745
1.49
0.298
1.49
MDL
0 00037
0 00037
0 00037
0 00037
0 00037
0 00037
0 00037
0 00037
0 00037
0 00037
0 00037
0 00037
0 00037
0 00037
0 00037
0 00037
0 00037
0 00037
0 00037
0 00037
0 00037
0 00037
0 00037
0 00037
0 00037
0 00037
27
CONG
ND
ND
0.00204
0.00358
0.00305
0.00254
ND
ND
ND
0.000854
ND
ND
ND
ND
0.00131
0.0012
ND
ND
ND
0.000782
ND
ND
0.000856
ND
ND
0.000528
0.0833
22000
47.1
2.06
ND
9.96
6.41
4.31
3.46
ND
7.71
FLAG
U
U
J
U
U
U
J
U
U
U
U
J
J
U
U
U
J
U
U
J
U
U
J
U
U
PQL
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
350
00186
1.7
0.17
1.7
1.7
0.85
1.7
0.34
1.7
MDL
0.000461
0.000461
0.000461
0.000461
0.000461
0.000461
0.000461
0.000461
0.000461
0.000461
0.000461
0.000461
0.000461
0.000461
0.000461
0.000461
0.000461
0.000461
0.000461
0.000461
0.000461
0.000461
0.000461
0.000461
0.000461
0.000461
-------
Station M10-
ANALYTE
PCB Congener #008
PCB Congener #01 8
PCB Congener #028 20,45,51
PCB Congener #044 47,39,65
PCB Congener #049 36
PCB Congener #052
PCB Congener #066
PCB Congener #077 111,151
PCB Congener #087
PCB Congener #101 90,113,150
PCB Congener #105 146
PCB Congener #11 8
PCB Congener #126 182
PCB Congener #128 166
PCB Congener #138 129,163
PCB Congener #153 168
PCB Congener #156 157,197
PCB Congener #169
PCB Congener #170
PCB Congener #180 193
PCB Congener #183
PCB Congener #184 165
PCB Congener #187
PCB Congener #195
PCB Congener #206
PCB Congener #209
Nonachlorobiphenyl
Total Organic Carbon
% Moisture
Arsenic
Cadmium
Chromium
Copper
Lead
Nickel
Silver
Zinc
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/Kg
mg/kg
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
26R
CONG
ND
ND
0 00229
0.000842
0 00462
0 00908
ND
ND
ND
ND
ND
ND
ND
ND
0.000473
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.0679
11000
343
1.99
ND
6.32
2.36
ND
2.27
ND
3.14
J-Denotes concentration result greater thant he l\
U-Denotes analyte not observed at a concentrati
FLAG
U
U
J
U
U
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PQL
0.00182
0.00182
0.00182
0.00182
0.00182
0.00182
0.00182
0.00182
0.00182
0.00182
0.00182
0.00182
0.00182
0.00182
0.00182
0.00182
0.00182
0.00182
0.00182
0.00182
0.00182
0.00182
0.00182
0.00182
0.00182
0.00182
270
0.019
1.42
0.142
1.42
1.42
0.711
1.42
0.284
1.42
MDL
0.000365
0.000365
0.000365
0.000365
0.000365
0.000365
0.000365
0.000365
0.000365
0.000365
0.000365
0.000365
0.000365
0.000365
0.000365
0.000365
0.000365
0.000365
0.000365
0.000365
0.000365
0.000365
0.000365
0.000365
0.000365
0.000365
32
CONG
ND
ND
0.00167
0.000793
0.00288
0.00449
0.000633
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.000532
0.0843
16000
47.3
2.02
0.2
9.94
49.8
2.54
4.99
ND
6.63
FLAG
U
U
J
J
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
U
PQL
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
370
00202
1.87
0.187
1.87
1.87
0.935
1.87
0.374
1.87
MDL
0 000452
0 000452
0 000452
0 000452
0 000452
0 000452
0 000452
0 000452
0 000452
0 000452
0 000452
0 000452
0 000452
0 000452
0 000452
0 000452
0 000452
0 000452
0 000452
0 000452
0 000452
0 000452
0 000452
0 000452
0 000452
0 000452
34
CONG
ND
ND
0 00392
0 00226
0 00267
000414
000153
000117
0 00227
0 00321
0 00642
0 00687
ND
0 00623
0.0161
0 00537
0 00701
ND
000815
0 00942
0.000925
ND
000165
000119
0.001
0.000459
0.0763
19000
44.2
3.29
ND
9.09
48.3
ND
4.72
ND
6.16
FLAG
U
U
J
J
U
U
J
U
J
J
J
J
U
U
U
PQL
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
0.00213
330
0.019
1.73
0.173
1.73
1.73
0.865
1.73
0.346
1.73
MDL
0.000427
0.000427
0.000427
0.000427
0.000427
0.000427
0.000427
0.000427
0.000427
0.000427
0.000427
0.000427
0.000427
0.000427
0.000427
0.000427
0.000427
0.000427
0.000427
0.000427
0.000427
0.000427
0.000427
0.000427
0.000427
0.000427
25
CONG
ND
ND
0.000994
0.00196
0.00185
0.00249
ND
ND
ND
0.000491
ND
ND
ND
ND
0.000679
0.000672
ND
ND
ND
0.000603
ND
ND
ND
ND
ND
0.000453
0.0835
15000
46.7
3.62
ND
10
42.6
3.64
4.29
ND
7.37
FLAG
U
U
J
J
J
U
U
U
J
U
U
U
U
J
J
U
U
U
J
U
U
U
U
U
J
U
U
PQL
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
0.00226
360
00205
1.84
0.184
1.84
1.84
0.918
1.84
0.367
1.84
MDL
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
0.000452
-------
Station M10-
ANALYTE
PCB Congener #008
PCB Congener #01 8
PCB Congener #028 20,45,51
PCB Congener #044 47,39,65
PCB Congener #049 36
PCB Congener #052
PCB Congener #066
PCB Congener #077 111,151
PCB Congener #087
PCB Congener #101 90,113,150
PCB Congener #105 146
PCB Congener #11 8
PCB Congener #126 182
PCB Congener #128 166
PCB Congener #138 129,163
PCB Congener #153 168
PCB Congener #156 157,197
PCB Congener #169
PCB Congener #170
PCB Congener #180 193
PCB Congener #183
PCB Congener #184 165
PCB Congener #187
PCB Congener #195
PCB Congener #206
PCB Congener #209
Nonachlorobiphenyl
Total Organic Carbon
% Moisture
Arsenic
Cadmium
Chromium
Copper
Lead
Nickel
Silver
Zinc
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/Kg
mg/kg
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
20
CONG
0.000599
ND
0 00609
0.0114
0.01
0 00729
000125
0.0126
0 00063
0 00665
0 00551
0 00273
ND
000138
0.0253
0.0377
0.0028
ND
0.0245
0.0744
0.016
ND
0.0386
0 00842
000512
0.000674
0.0768
22000
44.7
5.22
ND
12.7
473
16.4
3.04
0.456
23.7
J-Denotes concentration result greater thant he l\
U-Denotes analyte not observed at a concentrati
FLAG
J
U
J
J
U
J
U
U
J
U
PQL
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
0.00219
350
0.0186
1.79
0.179
1.79
1.79
0.894
1.79
0.358
1.79
MDL
0.000437
0.000437
0.000437
0.000437
0.000437
0.000437
0.000437
0.000437
0.000437
0.000437
0.000437
0.000437
0.000437
0.000437
0.000437
0.000437
0.000437
0.000437
0.000437
0.000437
0.000437
0.000437
0.000437
0.000437
0.000437
0.000437
15
CONG
ND
ND
0.00195
0.00261
0.00423
0.00392
0.000652
0.000849
ND
0.00205
0.00119
0.00161
ND
ND
0.00293
0.0026
0.000588
ND
0.000672
0.00198
0.000567
ND
0.00128
ND
ND
0.000453
0.0821
21000
43.8
3.41
ND
11
42.6
10.5
3.66
ND
15.7
FLAG
U
U
J
J
J
U
J
J
J
U
U
J
U
J
J
J
U
J
U
U
J
U
U
PQL
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
330
00193
1.67
0.167
1.67
1.67
0.837
1.67
0.335
1.67
MDL
0 000445
0 000445
0 000445
0 000445
0 000445
0 000445
0 000445
0 000445
0 000445
0 000445
0 000445
0 000445
0 000445
0 000445
0 000445
0 000445
0 000445
0 000445
0 000445
0 000445
0 000445
0 000445
0 000445
0 000445
0 000445
0 000445
14
CONG
0.000833
ND
0 00785
0 00557
0.0129
0.0147
000213
0 00339
0 00503
0.0128
0 00672
0.0107
ND
0 00328
0.0159
0.0111
0 00252
ND
0 00261
0 00521
000166
ND
000319
0.000534
0.000492
0.000776
0.0851
28000
49.7
6.07
0.196
16.5
56.8
26.3
3.67
0.382
37.3
FLAG
J
U
J
U
U
J
U
J
J
J
PQL
0.00238
0.00238
0.00238
0.00238
0.00238
0.00238
0.00238
0.00238
0.00238
0.00238
0.00238
0.00238
0.00238
0.00238
0.00238
0.00238
0.00238
0.00238
0.00238
0.00238
0.00238
0.00238
0.00238
0.00238
0.00238
0.00238
390
0.0179
1.86
0.186
1.86
1.86
0.929
1.86
0.371
1.86
MDL
0.000476
0.000476
0.000476
0.000476
0.000476
0.000476
0.000476
0.000476
0.000476
0.000476
0.000476
0.000476
0.000476
0.000476
0.000476
0.000476
0.000476
0.000476
0.000476
0.000476
0.000476
0.000476
0.000476
0.000476
0.000476
0.000476
19
CONG
ND
ND
0.00527
0.00921
0.00634
0.00574
0.00172
0.0439
0.00338
0.0314
0.0127
0.00534
ND
0.00451
0.0772
0.0874
0.00594
ND
0.0399
0.122
0.0276
ND
0.058
0.011
0.00597
0.00059
0.064
14000
35.1
3.75
ND
9.96
47.5
16
2.9
ND
21.2
FLAG
U
U
J
U
U
U
J
U
U
PQL
0.00179
0.00179
0.00179
0.00179
0.00179
0.00179
0.00179
0.00179
0.00179
0.00179
0.00179
0.00179
0.00179
0.00179
0.00179
0.00179
0.00179
0.00179
0.00179
0.003576
0.00179
0.00179
0.00179
0.00179
0.00179
0.00179
290
0.02
1.39
0.139
1.39
1.39
0.697
1.39
0.279
1.39
MDL
0.000358
0.000358
0.000358
0.000358
0.000358
0.000358
0.000358
0.000358
0.000358
0.000358
0.000358
0.000358
0.000358
0.000358
0.000358
0.000358
0.000358
0.000358
0.000358
0.000715
0.000358
0.000358
0.000358
0.000358
0.000358
0.000358
-------
Station M10-
ANALYTE
PCB Congener #008
PCB Congener #01 8
PCB Congener #028 20,45,51
PCB Congener #044 47,39,65
PCB Congener #049 36
PCB Congener #052
PCB Congener #066
PCB Congener #077 111,151
PCB Congener #087
PCB Congener #101 90,113,150
PCB Congener #105 146
PCB Congener #11 8
PCB Congener #126 182
PCB Congener #128 166
PCB Congener #138 129,163
PCB Congener #153 168
PCB Congener #156 157,197
PCB Congener #169
PCB Congener #170
PCB Congener #180 193
PCB Congener #183
PCB Congener #184 165
PCB Congener #187
PCB Congener #195
PCB Congener #206
PCB Congener #209
Nonachlorobiphenyl
Total Organic Carbon
% Moisture
Arsenic
Cadmium
Chromium
Copper
Lead
Nickel
Silver
Zinc
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/Kg
mg/kg
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
24
CONG
ND
ND
0 00552
0 00652
0.0103
0 00896
000146
000119
0.000856
0 00381
000173
0 00293
ND
0 00068
0 00496
0 00477
0.000917
ND
000106
0 00264
0.000932
ND
0 00201
ND
ND
0.000573
0.087
52000
502
6.12
0.249
148
522
178
4
0.462
27
J-Denotes concentration result greater thant he l\
U-Denotes analyte not observed at a concentrati
FLAG
U
U
J
J
J
J
U
J
J
U
J
J
U
J
U
U
J
PQL
0.00244
0.00244
0.00244
0.00244
0.00244
0.00244
0.00244
0.00244
0.00244
0.00244
0.00244
0.00244
0.00244
0.00244
0.00244
0.00244
0.00244
0.00244
0.00244
0.00244
0.00244
0.00244
0.00244
0.00244
0.00244
0.00244
350
0.0181
1 98
0.198
1 98
1 98
099
1 98
0.396
1 98
MDL
0.000489
0.000489
0.000489
0.000489
0.000489
0.000489
0.000489
0.000489
0.000489
0.000489
0.000489
0.000489
0.000489
0.000489
0.000489
0.000489
0.000489
0.000489
0.000489
0.000489
0.000489
0.000489
0.000489
0.000489
0.000489
0.000489
23
CONG
ND
ND
0.00411
0.00362
0.00779
0.00888
0.00168
0.00166
0.00103
0.00468
0.00257
0.00364
ND
0.00118
0.00637
0.00565
0.000923
ND
0.0014
0.00337
0.000843
ND
0.00237
ND
ND
0.000757
0.0913
31000
51.3
5.91
0233
15.5
55.1
22.6
3.61
ND
34.3
FLAG
U
U
J
J
J
U
J
J
U
J
J
U
J
U
U
J
U
PQL
0.00253
0.00253
0.00253
0.00253
0.00253
0.00253
0.00253
0.00253
0.00253
0.00253
0.00253
0.00253
0.00253
0.00253
0.00253
0.00253
0.00253
0.00253
0.00253
0.00253
0.00253
0.00253
0.00253
0.00253
0.00253
0.00253
370
0.018
1.86
0.186
1.86
1.86
0.929
1.86
0.372
1.86
MDL
0 000506
0 000506
0 000506
0 000506
0 000506
0 000506
0 000506
0 000506
0 000506
0 000506
0 000506
0 000506
0 000506
0 000506
0 000506
0 000506
0 000506
0 000506
0 000506
0 000506
0 000506
0 000506
0 000506
0 000506
0 000506
0 000506
18
CONG
ND
ND
000189
0 00296
0 00475
0 00539
000114
000132
000103
0 00384
000212
0.0031
ND
0.000869
0 00474
000419
0.000686
ND
0.000884
0 00228
0.000591
ND
000157
ND
ND
ND
0.0609
16000
34.8
4.99
0.157
12.1
40.2
18.4
2.5
0.403
22.2
FLAG
U
U
J
J
J
U
J
J
U
J
J
U
J
U
U
U
PQL
0.00186
0.00186
0.00186
0.00186
0.00186
0.00186
0.00186
0.00186
0.00186
0.00186
0.00186
0.00186
0.00186
0.00186
0.00186
0.00186
0.00186
0.00186
0.00186
0.00186
0.00186
0.00186
0.00186
0.00186
0.00186
0.00186
290
0.0189
1.46
0.146
1.46
1.46
0.732
1.46
0.293
1.46
MDL
0.000372
0.000372
0.000372
0.000372
0.000372
0.000372
0.000372
0.000372
0.000372
0.000372
0.000372
0.000372
0.000372
0.000372
0.000372
0.000372
0.000372
0.000372
0.000372
0.000372
0.000372
0.000372
0.000372
0.000372
0.000372
0.000372
13
CONG
ND
ND
0.00296
0.00265
0.0049
0.00471
0.00119
0.00134
0.000934
0.00355
0.00223
0.0031
ND
0.00102
0.00507
0.00433
0.000892
ND
0.00108
0.00237
0.000806
ND
0.00175
ND
ND
0.000436
0.0753
21000
43.7
4.79
0.22
12.2
42.3
16.5
3.1
ND
25.1
FLAG
U
U
J
J
J
U
J
J
U
J
J
U
J
U
U
J
U
PQL
0.00211
0.00211
0.00211
0.00211
0.00211
0.00211
0.00211
0.00211
0.00211
0.00211
0.00211
0.00211
0.00211
0.00211
0.00211
0.00211
0.00211
0.00211
0.00211
0.00211
0.00211
0.00211
0.00211
0.00211
0.00211
0.00211
330
00191
1.7
0.17
1.7
1.7
0.85
1.7
0.34
1.7
MDL
0.000422
0.000422
0.000422
0.000422
0.000422
0.000422
0.000422
0.000422
0.000422
0.000422
0.000422
0.000422
0.000422
0.000422
0.000422
0.000422
0.000422
0.000422
0.000422
0.000422
0.000422
0.000422
0.000422
0.000422
0.000422
0.000422
-------
Station M10-
ANALYTE
PCB Congener #008
PCB Congener #01 8
PCB Congener #028 20,45,51
PCB Congener #044 47,39,65
PCB Congener #049 36
PCB Congener #052
PCB Congener #066
PCB Congener #077 111,151
PCB Congener #087
PCB Congener #101 90,113,150
PCB Congener #105 146
PCB Congener #11 8
PCB Congener #126 182
PCB Congener #128 166
PCB Congener #138 129,163
PCB Congener #153 168
PCB Congener #156 157,197
PCB Congener #169
PCB Congener #170
PCB Congener #180 193
PCB Congener #183
PCB Congener #184 165
PCB Congener #187
PCB Congener #195
PCB Congener #206
PCB Congener #209
Nonachlorobiphenyl
Total Organic Carbon
% Moisture
Arsenic
Cadmium
Chromium
Copper
Lead
Nickel
Silver
Zinc
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/Kg
mg/kg
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
12
CONG
ND
ND
0 00355
000513
0 00572
0 00427
000107
0.0024
0.000837
000417
0 00272
0 00289
ND
000108
000914
0 00943
000138
ND
0 00354
0 00833
0 00202
ND
0 00354
0.000563
ND
ND
0.0873
24000
51 3
5.09
ND
14.4
503
13.7
4.45
ND
23
J-Denotes concentration result greater thant he l\
U-Denotes analyte not observed at a concentrati
FLAG
U
U
J
J
J
U
J
J
U
J
U
J
U
U
U
U
PQL
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
390
002
1 96
0.196
1 96
1 96
0.982
1 96
0.393
1 96
MDL
0.000491
0.000491
0.000491
0.000491
0.000491
0.000491
0.000491
0.000491
0.000491
0.000491
0.000491
0.000491
0.000491
0.000491
0.000491
0.000491
0.000491
0.000491
0.000491
0.000491
0.000491
0.000491
0.000491
0.000491
0.000491
0.000491
17
CONG
ND
ND
0.00148
0.00151
0.0021
0.00203
ND
ND
ND
0.000597
ND
ND
ND
ND
0.000966
0.000899
ND
ND
ND
0.000465
ND
ND
0.000525
ND
ND
ND
0.0727
21000
40.4
3.29
ND
9.95
37.3
3.85
3.17
ND
8.72
FLAG
U
U
J
J
J
U
U
U
J
U
U
U
U
J
J
U
U
U
J
U
U
J
U
U
U
U
U
PQL
0.00204
0.00204
0.00204
0.00204
0.00204
0.00204
0.00204
0.00204
0.00204
0.00204
0.00204
0.00204
0.00204
0.00204
0.00204
0.00204
0.00204
0.00204
0.00204
0.00204
0.00204
0.00204
0.00204
0.00204
0.00204
0.00204
310
00188
1.57
0.157
1.57
1.57
0.783
1.57
0.313
1.57
MDL
0 000409
0 000409
0 000409
0 000409
0 000409
0 000409
0 000409
0 000409
0 000409
0 000409
0 000409
0 000409
0 000409
0 000409
0 000409
0 000409
0 000409
0 000409
0 000409
0 000409
0 000409
0 000409
0 000409
0 000409
0 000409
0 000409
22
CONG
ND
ND
0.0038
0.0103
0 00588
0 00328
0.000676
000136
0.000418
0 00281
000127
0.0016
ND
0.000527
0 00408
0 00463
0.000531
ND
000151
0.0044
0.000867
ND
0 00269
0.000421
ND
0.000441
0.0709
18000
41.1
3.54
ND
11.2
39
9.81
2.93
ND
15.9
FLAG
U
U
J
J
J
J
J
U
J
J
U
J
J
U
J
U
J
U
U
PQL
0.00203
0.00203
0.00203
0.00203
0.00203
0.00203
0.00203
0.00203
0.00203
0.00203
0.00203
0.00203
0.00203
0.00203
0.00203
0.00203
0.00203
0.00203
0.00203
0.00203
0.00203
0.00203
0.00203
0.00203
0.00203
0.00203
320
0.0207
1.55
0.155
1.55
1.55
0.773
1.55
0.309
1.55
MDL
0.000405
0.000405
0.000405
0.000405
0.000405
0.000405
0.000405
0.000405
0.000405
0.000405
0.000405
0.000405
0.000405
0.000405
0.000405
0.000405
0.000405
0.000405
0.000405
0.000405
0.000405
0.000405
0.000405
0.000405
0.000405
0.000405
42
CONG
ND
ND
0.0023
0.00373
0.00426
0.0048
0.00107
0.00131
0.00114
0.00417
0.00245
0.00334
ND
0.00103
0.0051
0.00505
0.000793
ND
0.000982
0.00263
0.000702
ND
0.00205
ND
ND
0.000613
0.0859
22000
50.1
5.32
0.199
15.3
51.7
24.7
3.31
0.386
31.5
FLAG
U
U
J
J
J
J
U
J
J
U
J
J
U
J
U
U
J
PQL
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
0.00242
360
00177
1.83
0.183
1.83
1.83
0.916
1.83
0.366
1.83
MDL
0.000484
0.000484
0.000484
0.000484
0.000484
0.000484
0.000484
0.000484
0.000484
0.000484
0.000484
0.000484
0.000484
0.000484
0.000484
0.000484
0.000484
0.000484
0.000484
0.000484
0.000484
0.000484
0.000484
0.000484
0.000484
0.000484
-------
Station M10-
ANALYTE
PCB Congener #008
PCB Congener #01 8
PCB Congener #028 20,45,51
PCB Congener #044 47,39,65
PCB Congener #049 36
PCB Congener #052
PCB Congener #066
PCB Congener #077 111,151
PCB Congener #087
PCB Congener #101 90,113,150
PCB Congener #105 146
PCB Congener #11 8
PCB Congener #126 182
PCB Congener #128 166
PCB Congener #138 129,163
PCB Congener #153 168
PCB Congener #156 157,197
PCB Congener #169
PCB Congener #170
PCB Congener #180 193
PCB Congener #183
PCB Congener #184 165
PCB Congener #187
PCB Congener #195
PCB Congener #206
PCB Congener #209
Nonachlorobiphenyl
Total Organic Carbon
% Moisture
Arsenic
Cadmium
Chromium
Copper
Lead
Nickel
Silver
Zinc
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/Kg
mg/kg
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
41
CONG
ND
ND
000104
0.000939
000167
000214
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.0693
8800
373
1.67
ND
7.92
338
2.54
2.76
ND
5
J-Denotes concentration result greater thant he l\
U-Denotes analyte not observed at a concentrati
FLAG
U
U
J
J
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PQL
0.00191
0.00191
0.00191
0.00191
0.00191
0.00191
0.00191
0.00191
0.00191
0.00191
0.00191
0.00191
0.00191
0.00191
0.00191
0.00191
0.00191
0.00191
0.00191
0.00191
0.00191
0.00191
0.00191
0.00191
0.00191
0.00191
300
0.0177
1 52
0.152
1 52
1 52
0.761
1 52
0.304
1 52
MDL
0.000383
0.000383
0.000383
0.000383
0.000383
0.000383
0.000383
0.000383
0.000383
0.000383
0.000383
0.000383
0.000383
0.000383
0.000383
0.000383
0.000383
0.000383
0.000383
0.000383
0.000383
0.000383
0.000383
0.000383
0.000383
0.000383
33
CONG
ND
ND
0.00131
0.00152
0.00265
0.00355
ND
ND
ND
0.000446
ND
ND
ND
ND
0.000698
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.000706
0.000486
0.0776
12000
45.5
1.92
ND
9.37
51.1
ND
4.61
ND
6.56
FLAG
U
U
J
J
U
U
U
J
U
U
U
U
J
U
U
U
U
U
U
U
U
U
J
J
U
U
U
PQL
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
0.00222
350
00196
1.72
0.172
1.72
1.72
0.861
1.72
0.345
1.72
MDL
0 000443
0 000443
0 000443
0 000443
0 000443
0 000443
0 000443
0 000443
0 000443
0 000443
0 000443
0 000443
0 000443
0 000443
0 000443
0 000443
0 000443
0 000443
0 000443
0 000443
0 000443
0 000443
0 000443
0 000443
0 000443
0 000443
16
CONG
ND
ND
0.0023
000138
0 00367
0 00422
0.000515
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.0932
14000
50.2
2.76
ND
10.2
48.3
2.41
4.2
ND
6.42
FLAG
U
U
J
J
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PQL
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
0.00246
370
0.018
1.92
0.192
1.92
1.92
0.96
1.92
0.384
1.92
MDL
0.000493
0.000493
0.000493
0.000493
0.000493
0.000493
0.000493
0.000493
0.000493
0.000493
0.000493
0.000493
0.000493
0.000493
0.000493
0.000493
0.000493
0.000493
0.000493
0.000493
0.000493
0.000493
0.000493
0.000493
0.000493
0.000493
11
CONG
ND
ND
0.00179
0.00133
0.0028
0.00236
ND
ND
ND
0.000473
ND
ND
ND
ND
0.000699
0.000521
ND
ND
ND
ND
ND
ND
0.000461
ND
ND
ND
0.0826
13000
46.9
2.85
ND
9.24
36.5
2.23
3.6
ND
6.33
FLAG
U
U
J
J
U
U
U
J
U
U
U
U
J
J
U
U
U
U
U
U
J
U
U
U
U
U
PQL
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
00023
330
00182
1.84
0.184
1.84
1.84
0.922
1.84
0.369
1.84
MDL
0.000459
0.000459
0.000459
0.000459
0.000459
0.000459
0.000459
0.000459
0.000459
0.000459
0.000459
0.000459
0.000459
0.000459
0.000459
0.000459
0.000459
0.000459
0.000459
0.000459
0.000459
0.000459
0.000459
0.000459
0.000459
0.000459
-------
Station M10-
ANALYTE
PCB Congener #008
PCB Congener #01 8
PCB Congener #028 20,45,51
PCB Congener #044 47,39,65
PCB Congener #049 36
PCB Congener #052
PCB Congener #066
PCB Congener #077 111,151
PCB Congener #087
PCB Congener #101 90,113,150
PCB Congener #105 146
PCB Congener #11 8
PCB Congener #126 182
PCB Congener #128 166
PCB Congener #138 129,163
PCB Congener #153 168
PCB Congener #156 157,197
PCB Congener #169
PCB Congener #170
PCB Congener #180 193
PCB Congener #183
PCB Congener #184 165
PCB Congener #187
PCB Congener #195
PCB Congener #206
PCB Congener #209
Nonachlorobiphenyl
Total Organic Carbon
% Moisture
Arsenic
Cadmium
Chromium
Copper
Lead
Nickel
Silver
Zinc
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/Kg
mg/kg
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
21
CONG
ND
ND
000211
0 00245
0 00353
0 00351
0.000605
ND
ND
0.000823
ND
ND
ND
ND
0.000749
0.000771
ND
ND
ND
0.000695
ND
ND
0.000473
ND
0.000426
0.000449
0.0744
11000
41.1
2.71
ND
9.24
343
3.36
2.97
ND
6.98
J-Denotes concentration result greater thant he l\
U-Denotes analyte not observed at a concentrati
FLAG
U
U
J
U
U
J
U
U
U
U
J
J
U
U
U
J
U
U
J
U
J
J
U
U
PQL
0.00206
0.00206
0.00206
0.00206
0.00206
0.00206
0.00206
0.00206
0.00206
0.00206
0.00206
0.00206
0.00206
0.00206
0.00206
0.00206
0.00206
0.00206
0.00206
0.00206
0.00206
0.00206
0.00206
0.00206
0.00206
0.00206
300
002
1.69
0.169
1.69
1.69
0.843
1.69
0.337
1.69
MDL
0.000412
0.000412
0.000412
0.000412
0.000412
0.000412
0.000412
0.000412
0.000412
0.000412
0.000412
0.000412
0.000412
0.000412
0.000412
0.000412
0.000412
0.000412
0.000412
0.000412
0.000412
0.000412
0.000412
0.000412
0.000412
0.000412
35
CONG
ND
ND
0.0022
0.00189
0.00461
0.00596
0.00106
0.000484
ND
0.00109
0.000597
0.000775
ND
ND
0.0014
0.00144
0.000597
ND
0.000358
0.000844
0.000429
ND
0.000553
ND
ND
ND
0.0615
6900
31.3
ND
ND
7.28
28.1
4.66
ND
ND
9.72
FLAG
U
U
J
J
U
J
J
J
U
U
J
J
J
U
J
J
J
U
J
U
U
U
U
U
U
U
PQL
0.00176
0.00176
0.00176
0.00176
0.00176
0.00176
0.00176
0.00176
0.00176
0.00176
0.00176
0.00176
0.00176
0.00176
0.00176
0.00176
0.00176
0.00176
0.00176
0.00176
0.00176
0.00176
0.00176
0.00176
0.00176
0.00176
260
00206
1.42
0.142
1.42
1.42
0.712
1.42
0.285
1.42
MDL
0 000352
0 000352
0 000352
0 000352
0 000352
0 000352
0 000352
0 000352
0 000352
0 000352
0 000352
0 000352
0 000352
0 000352
0 000352
0 000352
0 000352
0 000352
0 000352
0 000352
0 000352
0 000352
0 000352
0 000352
0 000352
0 000352
-------
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-------
APPENDIX E
Tissue Chemistry Results
-------
This page intentionally left blank
-------
Analyte
PCB Congener #008
PCB Congener #018
PCB Congener #028 20,45,51
PCB Congener #044 47,39,65
PCB Congener #049 36
PCB Congener #052
PCB Congener #066
PCB Congener #077 111,151
PCB Congener #087
PCB Congener #101 90,113,150
PCB Congener #105 146
PCB Congener #118
PCB Congener #126 182
PCB Congener #128 166
PCB Congener #138 129,163
PCB Congener #153 168
PCB Congener #1 56 1 57, 1 97
PCB Congener #169
PCB Congener #170
PCB Congener #180 193
PCB Congener #183
PCB Congener #184 165
PCB Congener #187
PCB Congener #195
PCB Congener #206
PCB Congener #209
NCAA PCB
Total R4 PCB
Lipids
Arsenic
Cadmium
Chromium
Copper
Lead
Nickel
Silver
Zinc
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
ug/kg
ug/kg
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
MT10-1 & MT10-7
CONC
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
9
6.5
0.226
23.3
ND
ND
ND
ND
ND
ND
2.78
FLAG
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PQL
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.01
0.928
0.0928
0.928
0.928
0.464
0.928
0.186
0.928
J-Denotes concentration result greater thant he MDL, but less than the PQL
U-Denotes analvte not observed at a concentration greater than the MDL
MDL
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
MT10-2&MT10-5
CONC
ND
ND
ND
0.000999
ND
ND
ND
ND
ND
0.000364
ND
ND
ND
ND
0.000539
0.000371
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
11.546
7.773
0.361
144
ND
ND
7.83
ND
ND
0.47
61.7
FLAG
U
U
U
J
U
U
U
U
U
J
U
U
U
U
J
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PQL
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.01
0.959
0.0959
0.959
0.959
0.479
0.959
0.192
0.959
MDL
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
MT10-03 & MT10-04
CONC
ND
ND
0.000344
0.000315
ND
ND
0.000257
ND
ND
0.000563
0.000616
0.000843
ND
ND
0.00112
0.00129
ND
ND
ND
0.000464
ND
ND
0.000351
ND
ND
ND
16.326
10.163
0.47
190
ND
ND
4.94
ND
ND
0.239
50.2
FLAG
U
U
J
J
U
U
J
U
U
J
J
J
U
U
J
U
U
U
J
U
U
J
U
U
U
U
U
U
U
PQL
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.01
0.912
0.0912
0.912
0.912
0.456
0.912
0.182
0.912
MDL
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
MT10-06
CONC
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.000587
0.000703
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
10.58
7.29
0.843
2.59
ND
ND
ND
ND
ND
ND
2.78
FLAG
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J
J
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
PQL
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.00125
0.01
0.995
0.0995
0.995
0.995
0.498
0.995
0.199
0.995
MDL
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
0.00025
-------
This page intentionally left blank
-------
APPENDIX F
Hydrocarbon Contamination
Investigation
-------
This page intentionally left blank
-------
SAMPLE DATA SUMMARY PACKAGE FOR:
USEPA REGION 4
MAIL DROP 3707 AP 22 RTP-FC
MAIL CODE: D-143-02
DURHAM, NC 27711
CONTACT: CHRIS MCARTHUR
HYDROCARBON CONTAMINATION INVESTIGATION
NYS-DOH 310-14 Petroleum Identification by NBA SOP NE136-04
Confirmation by GC/MS 8270C TICS by NBA SOP NE045-07
-------
Case Narrative
Northeast Analytical, Inc. LRF 10070245 Page 1 of 26
-------
September 14, 2010
CASE NARRATIVE
History & Overview
The USEPA Region 4 sediment samples for the Analysis of Marine Sediment and Tissue project were found to have
a contamination pattern. The contamination was hydrocarbon based. The GC/MS analysis of the sediment extracts
showed an elevated baseline and a library search of the sediment extract was made for the purpose of tentative
identification (TICS). Based on the Ions found we identified Docosane, Eicosane and Undecane as Tentivtely
Identified Compounds (TICS). All of these compounds are typical components used in greases and lubricants.
NEA was requested by the USEPA Region 4 to look at cable grease (DynaLube) that was used on the sampler cable
and a bolt that was on sampler during the time of sampling. We extracted the bolt and the cable grease for
Petroleum Identification. These analyses compare it the contamination pattern we had found in sediment samples
submitted for PCB analysis to the product used in the field.
Dyna-Blue® Cable Pulling Lubricant was a light blue paste like grease. According to the literature DynaLube is an
environmentally friendly product and is a clean, slow-drying, easy-to-apply gel lubricant.
The bolt was covered in a black/gray paste like grease. The grease that was present on the bolt was removed with a
cotton gauze pad. The pad was extracted with the grease. The other sample of the DynaLube product was sub
sampled from the 8oz received into a lOg sample for extraction.
This data package (NEA SDG ID: 10070245) consists of two samples, a bolt and ajar of DynaLube.
Sample Delivery and Receipt Conditions
(1.) DynaLube sample was delivered to the laboratory via FEDEX delivery service on 07/07/2010. In that delivery a
jar marked bolt was present but no bolt was in the jar. Sample was held until the bolt arrived and both samples
were logged in.
(2.) The Bolt sample was delivered to the laboratory via FEDEX delivery service on 07/27/2010.
(3.) All samples were received at the laboratory intact and within holding times.
(4.) The following temperatures were recorded at sample receipt: 24, 26.4 degrees Celsius.
NYS-DOH 310-14 Petroleum Identification by NEA SOP NE136-04
Analysis for PET ID (NEA SOP NE136_04). Samples were extracted by Solvent Extraction Method (EPA -
Method 3580). The following technical and administrative items were noted for the analysis:
(1.) The bolt was wiped and the 0.524g of the grease was obtained for extraction.
(2.) DynaLube sub sample was weight at lOg for extraction.
(3.) The samples were extracted withHexane.
(4.) Both samples were confirmed as lubricate based on standards and library match for presents of a lubricant.
a. MOTOR OIL COMPOSITE STANDARD
b. HYDRAULIC OIL STANDARD
(5.) All quality assurance parameters were met for the analysis.
Confirmation bv GC/MS 8270C TICS by NEA SOP NE045-07
Northeast Analytical, Inc. LRF 10070245 Page 2 of 26
-------
Analysis for Confirmation/Comparison by GC/MS 8270C TICS (NBA SOP NE045-07). Both Sample extracts were
analyzed by GC/MS SIM.
(1.) All quality assurance parameters were met for the analysis.
(2.) The overlay of the sediment chromatogram and the DynaLube and the bolt was not a complete match. It is our
opinion that the match is sufficient to say that the DynaLube was the contaminate present in the sediment
samples.
(3.) The pure product DynaLube matched the sediment in the 14 to 26 minute and again we identified Docosane,
Eicosane and Undecane as Tentivtely Identified Compounds (TICS).
(4.) The overlay of the 3 samples shows a shift of baseline response this is most likely due to product weathering
and dilution of the product into water and sediment.
Qualifier Summary
(1.) B-Denotes analyte observed in associated method blank at a concentration exceeding the MDL.
(2.) J-Denotes concentration result greater than the MDL but less than the PQL.
(3.) U-Denotes analyte not observed at a concentration greater than the MDL.
Respectfully submitted,
Ann C. Casey
Client Services
Northeast Analytical, Inc. LRF 10070245 Page 3 of 26
-------
Sample Chain Of Custody
Northeast Analytical, Inc. LRF 10070245 Page 4 of 26
-------
CHAIN OF CUSTODY RECORD
NORTHEAST ANALYTICAL, INC.
2190 Technology Drive, Schenectady, NY 12308
Telephone (518) 346-4592 Fax (518) 381-6055
www.nealab.com information @nealab.com
PAGE
OF
<10070245P1>
LRF#
100702451
DISPOSAL REQUIREMENTS: (To be filled in by Client)
RETURN TO CLIENT
DISPOSAL BY NORTHEAST ANALYTICAL
ARCHIVAL BY NORTHEAST ANALYTICAL
Additional charges incurred for disposal (if hazardous) or archival. Call for details.
CLIENT (REPORTS TO BE SENT TO):
PROJECTS/PROJECT NAME:
ENTER ANALYSIS AND METHOD NUMBER REQUESTED
PRESERVATIVE KEY
0-NONE
1 -HCL
2 -HN03
3 -H2SO4
4 - NaOH
5 - Zn. Acetate
6 - MeOH
7 -NaHSO4
8-Other
PROJECT MANAGER:
PROJECT LOCATION (CITYYSTATE) ADDRESS:
SAMPLED BY: (Please Print)
REQUIRED TURN AROUND TIME:
SAMPLING FIRM:
NAME OF COURIER (IF USED):
LECTRONIC RESULTS FORMAT:
PDF LV EXCEL (.CSV) D
FAXED RESULTS
n
SAMPLE ID
Data Report: B6LP* D Certificates Only
E-MAIL ADDRESS:
FAX*
DATE
TIME
MATRIX
GRAB/
COMP
LAB
SAMPLE ID
(NEA USE ONLY)
DR CHILLED:
SEIVED BROKEN OR LEAKING:
COC DISCREPANCIES:
RELINQUISHED BY
RELINQUISHED BY
RECEIVED BY
SIGNATURE
PRINTED NAME
PRINTED NAME
LRF 10070245
Page 5 of 26
LOGIN COC FORM 01 070105 REV01 01
-------
NEA
NEA SAMPLE RECEIPT REPORT
CLIENT: USEPA REGION 4
PROJECT: EP104000082/ MIAMI ODMDS PCB STUDY
NEALRF: 10070245
REPORT: CERTIFICATES & DATA PACKAGE
EDD: YES
TAT: 2 WEEK
RECEIVED DATE: 07/29/2010 10:25
SHIPPED VIA: FEDEX
SHIPPING ID: 862927500130
NUMBER OF COOLERS: 0
CUSTODY SEAL INTACT: NA
TEMPERATURE(S): 264°C
COMMENTS:
SAMPLE SEALS INTACT: NA
SAMPLES PROPERLY PRESERVED: NA
SAMPLES REC'D IN HOLDTIME: NO
DISPOSAL: HOLD SAMPLES
COC DISCREPANCY: NO
DATE-TIME
TEST
QC
CLIENT ID (NEA ID)
DYNALUBE (AN10002)
BOLT (AN1 0003)
SAMPLED
07/06/2010
07/21/2010
MATRIX
Solid
Solid
METHOD
NYS-DOH 310-14
NYS-DOH 310-14
DESCRIPTION
Petroleum Identification
Petroleum Identification
REQUESTED
This report may not be reproduced except in full, without the written approval of Northeast Analytical, Inc. Page 1 of 1
2190 Technology Drive Schenectady, NY 12308 Phone 518.346.4592 Fax 518.381.6055 Email : information@nealab.com
Northeast Analytical, Inc. LRF 10070245 Page 6 of 26
-------
Internal Sample Tracking Record
Northeast Analytical, Inc. LRF 10070245 Page 7 of 26
-------
EXTRACTION LOG
weAnalytical
Prep Date: 07/30/10
1
2
3
Prep
ID
109411
109409
109410
NEA
Sample ID
DBLK-36
10070245-01
1 0070245-02
Alt
Sample ID
ANI0002B
AN 10002
AN 1 0003
Batch ID: 11479
Matrix
Solid
Solid
Solid
PH
Analysis
Required
E PETID S
E PETID S
E PETID S
Extract
Type / Unit
SHAKE
SHAKE
SHAKE
Percent
Total
Solids
N/A
100
100
Sample
Amount
(g or mL)
10000
0524
10000
Extract
Time
On-1
NA
NA
NA
Extract
Time
Off-1
NA
NA
NA
Extract
Time
On -2
NA
NA
NA
Extract
Time
Off -2
NA
NA
NA
Initial for required Clean U
Date
Acid
Cleaned
MM/DO)
NA
NA
NA
Date
TEA
Cleaned
(MM/DD)
NA
NA
NA
Date
Florisil
Shake
(MM/DD)
NA
NA
NA
3 Steps
Date
Hg
Shake
MM/DD)
NA
NA
NA
Final
Ext.
Vol
(mL)
10
10
10
Date
Cone
(MM/DO)
07/30
07/30
07/30
Comments
Solvent, Surrogate, Spike, and Acid Information
Item ; Lot Number
Hexane | DA239
Amount (uL) 1 Cone (ug/mL)
|
B
E
L
n
LD
D
S
0
D
D
M
n
K
n
Analyst Review:
Peer Review:
Print Dale: 1217/2010
Ure Version 5051
Paqeflof26
-------
Sample Analysis Data
Northeast Analytical, Inc. LRF 10070245 Page 9 of 26
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NEA
CERTIFICATE OF ANALYSIS
08/11/2010
USEPA REGION 4
MAIL DROP 3707 AP 22 RTP-FC
MAIL CODE: D-143-02
DURHAM, NC 27711
CONTACT: CHRIS MCARTHUR
CUSTOMERID:
MATRIX:
DATE RECEIVED:
SAMPLED BY:
CUSTOMERPO:
DYNALUBE
SOLID
07/27/2010 TIME: 10:25
M.LOWE
EP104000082
NEAID: AN10002 NEALRF: 10070245-01
DATE SAMPLED: 07/06/2010 TIME: N/A
PROJECT: EP104000082/ MIAMI ODMDS PCB STUDY
LOCATION:
LABELAP#: 11078
PARAMETERPERFORMED
RESULTS
RL
UNITS
DATE
ANALYZED
FLAGS
Petroleum ID Scan by NYS-DOH 310-14
Diesel Fuel Not Present 0.00
Fuel Oil (#2) Not Present 0.00
Fuel Oil (#4) Not Present 0.00
Fuel Oil (#5) Not Present 0.00
Fuel Oil (#6) Not Present 0.00
Gasoline Not Present 0.00
Kerosene Not Present 0.00
Lubricating Oil Present 0.00
Notes: ND (Not Detected) Denotes analyte not detected at a concentration greater than the RL
RL: Denotes the reporting limit for the sample
Note: Chromatographic pattern most closely resembles Lubricating Oil.
AUTHORIZED SIGNATURE:
08/05/2010
08/05/2010
08/05/2010
08/05/2010
08/05/2010
08/05/2010
08/05/2010
08/05/2010
William A Kotas
Sr Laboratory Representative
Robert E Wagner
Laboratory Director
This report may not be reproduced except in full, without the written approval of Northeast Analytical, Inc. Page 1 of 1
2190 Technology Drive Schenectady, NY 12308 Phone 518.346.4592 Fax 518.381.6055 Email : information@neala%.com
-------
NEA
CERTIFICATE OF ANALYSIS
08/11/2010
USEPA REGION 4
MAIL DROP 3707 AP 22 RTP-FC
MAIL CODE: D-143-02
DURHAM, NC 27711
CONTACT: CHRIS MCARTHUR
CUSTOMERID: BOLT
MATRIX: SOLID
DATE RECEIVED: 07/27/2010 TIME: 10:25
SAMPLED BY: M. LOWE
CUSTOMERPO: EP104000082
PARAMETERPERFORMED RESULTS
Petroleum ID Scan by NYS-DOH 310-14
Diesel Fuel Not Present
Fuel Oil (#2) Not Present
Fuel Oil (#4) Not Present
Fuel Oil (#5) Not Present
Fuel Oil (#6) Not Present
Gasoline Not Present
Kerosene Not Present
Lubricating Oil Present
Notes: ND (Not Detected) Denotes analyte not detected at a concentration gre;
RL: Denotes the reporting limit for the sample
Note: Chromatographic pattern most closely resembles Lubricating Oil.
AUTHORIZED SIGNATURE:
NEA ID: AN10003 NEALRF:
DATE SAMPLED: 07/21/2010
10070245-02
TIME: N/A
PROJECT: EP104000082/ MIAMI ODMDS PCB STUDY
RL
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
iter than the RL
LOCATION:
LABELAP#: 11078
DATE
UNITS ANALYZED
08/05/2010
08/05/2010
08/05/2010
08/05/2010
08/05/2010
08/05/2010
08/05/2010
08/05/2010
FLAGS
William A Kotas
Sr Laboratory Representative
Robert E Wagner
Laboratory Director
This report may not be reproduced except in full, without the written approval of Northeast Analytical, Inc. Page 1 of 1
2190 Technology Drive Schenectady, NY 12308 Phone 518.346.4592 Fax 518.381.6055 Email : information@neala%.com
-------
The PETID of the bolt and DynaLube did indeed confirm that both samples were lubricating oil.
The best match was hydraulic oil standard and the motor oil composite standard as seen in the
following chromatograms. This confirmed that the product of interest was a petroleum
lubricating. The bolt and Dyna Lube were match to each other and then to the standards. All of
the normal standard chromatograms have been included for review and reference.
Northeast Analytical, Inc. LRF 10070245 Page 12 of 26
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AN10002 - DYNALUBE PETID Chromatogram
1.50-
1.00-
0.50-
0.00-
-0.50-
-1.00-
-1.50-
5.00
10.00
15.00
20.00
25.00
Minutes
30.00
35.00
40.00
45.00
AN10003 - BOLT PETID Chromatogram
-0.90-
-1.00-
-1.10-
-1.20-
-1.30-
-1.40-
-J
-1.50-
5.00
10.00
15.00
20.00
25.00
Minutes
30.00
35.00
40.00
45.00
Northeast Analytical, Inc.
LRF 10070245
Page 13 of 26
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MOTOR OIL COMPOSITE STANDARD PETID Chromatogram
30.00 35.00 40.00 45.00 50.00 55.00 60.00
Minutes
HYDRAULIC OIL STANDARD PETID Chromatogram
-0.7CT-
-o.acr1
-t.BCr1
-1.7O1
5.00 10 00 15.00 20 00 25.00 30.00 35.00 40.00 45 00 50.00 55.00 60.00
Minutes
Northeast Analytical, Inc.
LRF 10070245
Page 14 of 26
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FUEL OIL #2 (HOME HEATING OIL) STANDARD PETID Chromatogram
45.00-
40.00^
35.00^
30.00^
25.00^
20.00^
15.00^
> :
E 10.00^
5.00^
-S.OO^
-10.00^
-15.00^
-20.00^
-25.00^
0.00 2.00 4.00 6.00 8.00 10.00 12.00 14.00 16 00 18.00 20.00 22.00 24.00 26.00 28.00 30 00 32.00 34.00 36.00 38.00 40.00
Minutes
DIESEL FUEL STANDARD PETID Chromatogram
2.00 4.00 600 8.00 10.00 12.00 14.00 16.00 18.00 20.00 22.00 2400 26.00 2800 30.00 32.00 34.00 36.00 38.00 40.00
Northeast Analytical, Inc.
LRF 10070245
Page 15 of 26
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UNLEADED GASOLINE STANDARD PETID Chromatogram
5.00 10.00 15.00 20.00 25.00 30.00 35.00 40.00 45.00 50.00 55.00 60 00
Minutes
COMPOSITE KEROSENE STANDARD PETID Chromatogram
500 10.00 15.00 20.00 25.00 30.00 35.00 40.00 45.00 5000 55.00 60.00
Minutes
Northeast Analytical, Inc.
LRF 10070245
Page 16 of 26
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MINERAL SPIRITS PETID Chromatogram
30.00
Minutes
JET FUEL A PETID Chromatogram
4.50-
4.00^
3.50-
3.00-
2.50^
2.00^
> 1.50^
1.00^
0.50^
o.ooH
-0 50^
-1 00^
-1 50-
30.00
Minutes
Northeast Analytical, Inc.
LRF 10070245
Page 17 of 26
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FUEL OIL #4 PETID Chromatogram
20 00 25 00 30 00 35 00
Minutes
FUEL OIL #5 PETID Chromatogram
20 00 25 00 30 00 35 00
Minutes
Northeast Analytical, Inc.
LRF 10070245
Page 18 of 26
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FUEL OIL #6 PETID Chromatogram
30 00
Minutes
Northeast Analytical, Inc.
LRF 10070245
Page 19 of 26
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The PETE) of the bolt compared to one of the sediment sample (GC/ECD) analysis. Show a very nice pattern
match to the 35minuets. The interferences from the DynaLube made it very difficult to measure the PCB
congeners of interest in the sediment samples.
AN10003 - BOLT PETID Chromatogram
-090-
-100-
-1.10-
-120-
-130-
-1.40-
-150-
1000
15.00
2000
2500
Mnutes
30.00
3500
40.00
45.00
Sediment M10-35 GC/ECD Chromatogram
The Chrornatograms of the GC/MS TICS analysis was more difficult to overlay. This is due to
dilution/weathering of the bolt and sediment samples verses the pure product. The shift of the 3 samples does not
Northeast Analytical, Inc.
LRF 10070245
Page 20 of 26
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overlay as well but the main components Docosane, Eicosane and Undecane as Tentivtely Identified Compounds
(TICS) match across all 3 samples.
Northeast Analytical, Inc. LRF 10070245 Page 21 of 26
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Data File: \\ftTOLLO\GCMS\TP10\GCMS03\Oa0410.b\M3051901.d/M3051901.MS
Injection Date; 19-MAV-2010 15:59
Instrument: GCHS03.1
Client Sample ID: EPP4 TEST
ITS MS M3051901.MS: 0.000 to 44.981 Mln
7.6-
7.0-;
6.B-
6.6-:
6.4-:
5.6-
5.6-.
5.4-1
5.2^
5.0-:
4.2-:
S 4.0-
° 3.8-:
x
3.2-:
3.0^
2.6^
2.frj
2.4-j
2.2^
2.0-:
l.fr:
1.6-
1.4^
1.2^
1.0-i
0.4-
0.2-;
0.0—
Northeast Analytical, Inc.
LRF 10070245
Page 22 of 26
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Data F i le • \\APOLLO\GCM5\TP10\GCM503\060410.b\M3080406.d/M3080406.MS
Injection Date: 04-AUG-2010 17:23
Instrument: GCMS03.i
Client Sample ID: ON10003
1.0-
0.9-
0.8-
0.7-
0.6-
x 0.5-
>
0.4-
0.3-
0.2-
0.1-
ITS MS M3080406.MS: 0.000 to 44.983 Mln
2 4
32 34 36 36 40 42 44
Northeast Analytical, Inc.
LRF 10070245
Page 23 of 26
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Data File; \\ftPOLLO\GCMS\TP10\GCMS03\080410.b\M30804Q5.d/M3080405.MS
Injection Date: 04-OUG-2010 16:36
Instrument: GCMS03.1
Client Sample ID: AN10002
ITS MS M3080405.MS: 0.000 to 44.996 Mln
Northeast Analytical, Inc.
LRF 10070245
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File: ITS MS M3051901.MS
File: ITS MS M3000405.MS
File: ITS MS M30B0406.M5
Inj. Date: 19-MAY-2010 15:59
Inj, Date: 04-ft(JG-2010 16:36
Inj. Date: 04-ftUG-2010 17;25
5.6
5.4
5.2
5.0
4.8-
4.6-
4.4:
4.2-'
4.0-
3.8
3.6-
3.4-|
3.2-
3.0:
o 2.8-
tr4
X
2.6-
2.4
2.2-
2.0:
i.a-
1.6-
1.4:
1.2-
1.0-
O.B
C.6-
f .4-
o.o
Northeast Analytical, Inc.
LRF 10070245
Page 25 of 26
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FORM 1
PCS ORGANICS ANALYSIS DATA SHEET
TENTATIVELY IDENTIFIED COMPOUNDS
CLIENT SAMPLE NO.
Lab Name: NORTHEAST ANALYTICAL
Lab Code: 11078 Case No.:
Matrix: (soil/water) WATER
Sample wt/vol: 1000 (g/mL) ML
Level: (low/raed) LOW
% Moisture: decanted: (Y/N)
Contract:
SAS No. :
EPA4 TEST
Concentrated Extract Volume: 1000(uL)
Injection Volume: 2.0(uL)
GPC Cleanup: (Y/N) N pH:
Number TICs found: 17
SDG No.: 0519.B
Lab Sample ID: EPA4 TEST
Lab File ID: M3051901
Date Received:
Date Extracted:
Date Analyzed: 05/19/10
Dilution Factor: 1.0
CONCENTRATION UNITS:
(ug/L or ug/Kg) ug/L
CAS
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
NUMBER
629-03-8
102-82-9
504-44-9
1120-21-4
56862-62-5
112-95-8
629-97-0
62238-13-5
630-07-9
609-26-7
3746-39-2
2885-00-9
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
COMPOUND NAME
HEXANE, 1,6-DIBROMO-
TRIBUTYLAMINE
UNKNOWN
UNKNOWN
UNKNOWN
HEXADECANE, 2, 6, 11, 15-TETRAM
UNDECANE
10 -METHYLNONADECANE
EICOSANE
DOCOSANE
UNKNOWN
DECANE, 2,3,7-TRIMETHYL-
PENTATRIACONTANE
PENTANE, 3-ETHYL-2-METHYL-
N-DODECYLTHIOGLYCOLATE
UNKNOWN
1 -OCTADECANETHIOL
RT
5.74
5.77
5.82
5.88
5.94
6.23
9.74
11.53
13.69
18.69
24.04
26.68
29.29
29.40
30.05
31.81
34.98
EST. CONC.
0.547
1.21
0.821
0.734
0.636
0.797
1.15
1.63
2.79
1.26
0.546
0.962
0.810
0.538
0.517
0.549
0.604
Q
NJ
NJ
J
J
J
NJ
NJ
NJ
NJ
NJ
J
NJ
NJ
NJ
NJ
J
NJ
FORM I PCB-TIC
Northeast Analytical, Inc.
LRF 10070245
Page 26 of 26
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APPENDIX G
EPA Region 4 Laboratory
PCB Analysis Results
-------
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-------
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 10-0375
Project: 10-0466, Miami ODMDS - Reported by Jason Collum
June 17, 2010
4SESD-ASB
MEMORANDUM
SUBJECT: FINAL Analytical Report
Project: 10-0466, Miami ODMDS
Surface Water Protection
FROM:
THRU:
TO:
Jason Collum
ASB Analyst
Gary Bennett, Chief
Analytical Support Branch
Morris Flexner
Attached are the final results for the analytical groups listed below. These analyses were performed in
accordance with the Analytical Support Branch's (ASB) Laboratory Operations and Quality Assurance Manual
(ASB LOQAM) found at www.epa.gov/region4/sesd/asbsop. Any unique project data quality objectives
specified in writing by the data requestor have also been incorporated into the data unless otherwise noted in the
Report Narrative. Chemistry data have been verified based on the ASB LOQAM specifications and may have
been qualified if the applicable quality control criteria were not met. For a listing of specific data qualifiers and
explanations, please refer to the Data Qualifier Definitions included in this report. The reported results are
representative only of the samples as received by the laboratory.
Analyses Included in this report:
Method Used:
PCB Congeners (PCBC)
PCB Congeners
EPA 8082
Page 1 of7
E102114 PCBC FINAL
6/17/10 9:45
-------
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 10-0375
Project: 10-0466, Miami ODMDS - Reported by Jason Collum
Report Narrative for Work Order E102114, Project: 10-0466
The samples contained a number of large unidentified peaks which caused interference with some of the
PCB Congeners. Samples E102114-01 (MT10-01) and -03 (MT10-36) contained peaks which interfered with
PCB Congener 8, while sample E102114-02 (MT10-18) contained peaks which interfered with PCB Congeners
8, 52, and 101. Due to this interference, the MRLs for all of these Congeners were raised.
All three samples were also extracted in dichloromethane and analyzed on the GC/MS. The GC/MS
results showed possible interfering peaks, but showed no evidence of PCB Congeners 8, 52 and 101.
Sample E102114-02 (MT10-18) was found to contain the presence of a PCB. The possible PCB in the
sample is Arl260 at an estimated value of 13 NJ ug/kg. Congeners were also reported in E102114-02
(MT10-18).
There was no clear evidence of an oil residue/"humpogram" in any of the samples.
Sample Disposal Policy
Because of the laboratory's limited space for long term sample storage, our policy is to dispose of samples on a
periodic schedule. Please note that within 60 days of this memo, the original samples and all sample extracts
and/or sample digestates will be disposed of in accordance with applicable regulations. The 60-day sample
disposal policy does not apply to criminal samples which are held until the laboratory is notified by the criminal
investigators that case development and litigation are complete.
These samples may be held in the laboratory's custody for a longer period of time if you have a special project
need. If you wish for the laboratory to hold samples beyond the 60-day period, please contact our Sample Control
Coordinator, Debbie Colquitt, by e-mail at Colquitt.Debbiefgiepa.gov. and provide a reason for holding samples
beyond 60 days
Page 2 of 7 E102114 PCBC FINAL 6/17/10 9:45
-------
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 10-0375
Project: 10-0466, Miami ODMDS - Reported by Jason Collum
SAMPLES INCLUDED IN THIS REPORT
Project: 10-0466, Miami ODMDS
Sample ID
MT10-01
MT10-18
MT10-36
Laboratory ID
E102114-01
E102114-02
E102114-03
Matrix
Sediment
Sediment
Sediment
Date Collected Date Received
4/21/10 10:01 5/18/10 10:10
4/22/10 11:50 5/18/10 10:10
4/21/10 16:03 5/18/10 10:10
Page 3 of7
E102114 PCBC FINAL
6/17/10 9:45
-------
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 10-0375
Project: 10-0466, Miami ODMDS - Reported by Jason Collum
DATA QUALIFIER DEFINITIONS
U The analyte was not detected at or above the reporting limit.
D-4 MRL elevated due to interferences.
J The identification of the analyte is acceptable; the reported value is an estimate.
OS-3 Surrogate recovery is lower than established control limits.
ACRONYMS AND ABBREVIATIONS
CAS Chemical Abstracts Service
Note: Analytes with no known CAS identifiers have been assigned codes beginning with "E", the EPA ID as assigned by
the EPA Substance Registry System (www.epa.gov/srs), or beginning with "R4-", a unique identifier assigned by the EPA
Region 4 laboratory.
MDL Method Detection Limit - The minimum concentration of a substance (an analyte) that can be measured and
reported with a 99% confidence that the analyte concentration is greater than zero.
MRL Minimum Reporting Limit - Analyte concentration that corresponds to the lowest demonstrated level of acceptable
quantitation. The MRL is sample-specific and accounts for preparation weights and volumes, dilutions, and
moisture content of soil/sediments.
TIC Tentatively Identified Compound - An analyte identified based on a match with the instrument software's mass
spectral library. A calibration standard has not been analyzed to confirm the compound's identification or the
estimated concentration reported.
Page 4 of7
E102114 PCBC FINAL
6/17/10 9:45
-------
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 10-0375
Project: 10-0466, Miami ODMDS - Reported by Jason Collum
Project: 10-0466, Miami ODMDS
Sample ID: MT10-01
Station ID: MT01
Date Collected: 4/21/10 10:01
PCB Congeners
Lab ID: E102114-01
Matrix: Sediment
CAS
Number
Analyte
Results Qualifiers
Units
Analyzed Method
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
0.69 U, J
0.69 U, J
0.69 U, J
0.69 U, J
0.69 U, J
, J
0.69 U, J
0.69 U, J
0.69 U, J
0.69 U, J
0.69 U, J
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
34883-43-7
37680-65-2
7012-37-5
41464-39-5
41464-40-8
35693-99-3
32598-10-0
35065-27-1
PCB Congener # 8
PCB Congener # 18
PCB Congener # 28
PCB Congener # 44
PCB Congener # 49
PCB Congener # 52
PCB Congener # 66
PCB Congener # 77
PCB Congener # 87
PCB Congener #101
PCB Congener #105
PCB Congener #118
PCB Congener #126
PCB Congener #128
PCB Congener #138
PCB Congener #153
38380-08-4
32774-16-6
35065-29-3
52663-69-1
74472-48-3
52663-68-0
52663-78-2
40186-72-9
2051-24-3
PCB Congener #156
PCB Congener #169
PCB Congener #170
PCB Congener #180
PCB Congener #183
PCB Congener #184
PCB Congener #187
PCB Congener #195
PCB Congener #206
PCB Congener #209
Page 5 of7
E102114 PCBC FINAL
6/17/10 9:45
-------
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 10-0375
Project: 10-0466, Miami ODMDS - Reported by Jason Collum
Project: 10-0466, Miami ODMDS
Sample ID: MT10-18
Station ID: MT18
Date Collected: 4/22/10 11:50
PCB Congeners
Lab ID: E102114-02
Matrix: Sediment
CAS
Number
Analyte
Results Qualifiers
Units
Analyzed Method
ug/kg dry
ug/kg dry
1.8 U,D-4
0.63 U
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/k
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
5/20/10
1306
5/20/10
1306
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
0.63 U
0.63 U
0.63 U
34883-43-7
37680-65-2
7012-37-5
41464-39-5
41464-40-8
35693-99-3
32598-10-0
35065-27-1
PCB Congener # 8
PCB Congener # 18
PCB Congener # 28
PCB Congener # 44
PCB Congener # 49
PCB Congener # 52
PCB Congener # 66
PCB Congener # 77
PCB Congener # 87
PCB Congener #101
PCB Congener #105
PCB Congener #118
PCB Congener #126
PCB Congener #128
PCB Congener #138
PCB Congener #153
38380-08-4
32774-16-6
35065-29-3
52663-69-1
74472-48-3
52663-68-0
52663-78-2
40186-72-9
2051-24-3
PCB Congener #156
PCB Congener #169
PCB Congener #170
PCB Congener #180
PCB Congener #183
PCB Congener #184
PCB Congener #187
PCB Congener #195
PCB Congener #206
PCB Congener #209
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UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
Region 4 Science and Ecosystem Support Division
980 College Station Road, Athens, Georgia 30605-2700
D.A.R.T. Id: 10-0375
Project: 10-0466, Miami ODMDS - Reported by Jason Collum
Project: 10-0466, Miami ODMDS
Sample ID: MT10-36
Station ID: MT36
Date Collected: 4/21/10 16:03
PCB Congeners
Lab ID: E102114-03
Matrix: Sediment
CAS
Number
Analyte
Results Qualifiers
Units
Analyzed Method
ug/kg dry
ug/kg dry
1.2 U,D-4
0.72 U
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
ug/kg dry
34883-43-7
37680-65-2
7012-37-5
41464-39-5
41464-40-8
35693-99-3
32598-10-0
35065-27-1
PCB Congener # 8
PCB Congener # 18
PCB Congener # 28
PCB Congener # 44
PCB Congener # 49
PCB Congener # 52
PCB Congener # 66
PCB Congener # 77
PCB Congener # 87
PCB Congener #101
PCB Congener #105
PCB Congener #118
PCB Congener #126
PCB Congener #128
PCB Congener #138
PCB Congener #153
38380-08-4
32774-16-6
35065-29-3
52663-69-1
74472-48-3
52663-68-0
52663-78-2
40186-72-9
2051-24-3
PCB Congener #156
PCB Congener #169
PCB Congener #170
PCB Congener #180
PCB Congener #183
PCB Congener #184
PCB Congener #187
PCB Congener #195
PCB Congener #206
PCB Congener #209
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