EPA/ROD/R02-98/141
1998
EPA Superfund
Record of Decision:
CHEMSOL, INC.
EPA ID: NJD980528889
OU01
PISCATAWAY, NJ
09/18/1998
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EPA 541-R98-141
RECORD OF DECISION
Chemsol, Inc. Superfund Site
Piscataway, Middlesex County, New Jersey
United States Environmental Protection Agency
Region II
New York, New York
September 1998
DECLARATION FOR THE RECORD OF DECISION
SITE NAME AND LOCATION
Chemsol, Inc. Superfund Site
Piscataway, Middlesex County, New Jersey
STATEMENT OF BASIS AND PURPOSE
This Record of Decision (ROD) documents the U.S. Environmental Protection Agency's selection of a second
remedial action to address soil and groundwater contamination at the Chemsol Site (the "Site"), in accordance
with the reguirements of the Comprehensive Environmental Response, Compensation and Liability Act of 1980, as
amended (CERCLA) [42 U.S.C. °9601-9675], and to the extent practicable, the National Oil and Hazardous
Substances Pollution Contingency Plan, as amended, 40 CFR Part 300. This decision document explains the
factual and legal basis for selecting the remedy for this second operable unit of the Site.
The New Jersey Department of Environmental Protection (NJDEP) has been consulted on the planned remedial
action in accordance with CERCLA °121(f) [42 U.S.C. °9621(f)]. NJDEP is not in agreement with EPA's soil
cleanup goals but does not object to the groundwater component of the remedy, (see Appendix IV. The
information supporting this remedial action is contained in the Administrative Record for the Site, the index
of which can be found in Appendix III to this document.
ASSESSMENT OF THE SITE
Actual or threatened releases of hazardous substances from the Chemsol Site, if not addressed by implementing
the response action selected in this ROD, may present an imminent and substantial endangerment to public
health, welfare, or the environment.
DESCRIPTION OF THE SELECTED REMEDY
The selected remedy is the second of three operable units planned for the Chemsol Site. The major components
of the selected remedy include:
Soil
! Excavation and off-site disposal of approximately 18,500 cubic yards of soil contaminated with
polychlorinated biphenyls (PCBs) above 1 part per million (ppm) and lead above 400 ppm. The excavated
areas will be backfilled with clean imported fill from an off-site location, covered with topsoil,
then seeded with grass.
! Disposal of the excavated soils at an appropriate off-site disposal facility, depending on waste
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characteristics.
Groundwater
! Installation and pumping of approximately five additional extraction wells to contain contaminated
groundwater on-site.
! Continued treatment of extracted groundwater through the existing groundwater treatment facility. The
treated groundwater may continue to be released to the Middlesex County Utilities Authority (MCUA). If
discharge to the MCUA becomes infeasible, treated groundwater will undergo additional on-site
biological treatment, prior to being released on-site to Stream 1A.
! Performance of an additional groundwater investigation to determine the extent to which contaminated
groundwater is leaving the property boundaries.
Surface Water and Sediments
! Monitoring of sediments and surface water to determine whether remediation of Lot IB will result in
lower PCB levels in the on-site streams, Stream 1A and IB, over time.
DECLARATION OF STATUTORY DETERMINATIONS
The selected remedy meets the reguirements for remedial actions set forth in CERCLA °121 in that it: (1) is
protective of human health and the environment; (2) complies with Federal and State reguirements that are
legally applicable or relevant and appropriate to the extent practicable given the unpredictable nature of
groundwater hydrogeology in fractured bedrock; (3) is cost-effective; (4) utilizes alternative treatment (or
resource recovery) technologies to the maximum extent practicable; and (5) satisfies the statutory preference
for remedies that employ treatment to reduce the toxicity, mobility, or volume of the hazardous substances,
pollutants or contaminants at the Site.
As part of this Record of Decision, EPA conducted a review of remedies selected at the Site consistent with
CERCLA, Section 122(c), the National Contingency Plan, Section 300.430(f)(4)(ii) and OSWER Directives
9355.7-02 (1991), 2a(1994) and 3a (1995). EPA conducted a Type la review which is applicable to a site at
which the remedial response is ongoing. I certify that the remedies selected for this Site remain protective
of human health and the environment.
Because this remedy may result in hazardous substances remaining on the Site above health-based levels, a
review will be conducted within five years after the initiation of the remedial action to ensure that the
remedy continues to provide adeguate protection of human health and the environment.
Regional Administrat
/ Date
e/
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RECORD OF DECISION
DECISION SUMMARY
Chemsol Site
Piscataway, Middlesex County, New Jersey
United States Environmental Protection Agency
Region II
New York, New York
September 1998
TABLE OF CONTENTS
page
SITE NAME, LOCATION AND DESCRIPTION 1
SITE HISTORY AND ENFORCEMENT ACTIVITIES 1
HIGHLIGHTS OF COMMUNITY PARTICIPATION 3
SCOPE AND ROLE OF OPERABLE UNIT 4
SUMMARY OF SITE CHARACTERISTICS 4
SUMMARY OF SITE RISKS 7
REMEDIAL ACTION OBJECTIVES 13
DESCRIPTION OF REMEDIAL ACTION ALTERNATIVES 14
SUMMARY OF COMPARATIVEANALYSIS OF ALTERNATIVES 20
SELECTED REMEDY 28
STATUTORY DETERMINATIONS 29
APPENDICES
APPENDIX I FIGURES
APPENDIX II TABLES
APPENDIX III ADMINISTRATIVE RECORD INDEX
APPENDIX IV STATE LETTER
APPENDIX V RESPONSIVENESS SUMMARY
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SITE NAME, LOCATION AND DESCRIPTION
Site History
Chemsol, Inc. (Chemsol or Site) is located on a 40 acre tract of land at the end of Fleming Street,
Piscataway, Middlesex County, New Jersey. The Site is comprised of two areas: in undeveloped parcel known as
Lot 1A and a cleared area referred to as Lot IB. Two small intermittent streams (Stream 1A and Stream IB) and
a small trench, known as the Northern Ditch, drain northward across the Site into a marshy wetland area
located near the northeastern property boundary (see Figures 1 and 2).
Land use in the vicinity of the Site is a mixture of commercial, industrial, and residential uses. The Port
Reading Railroad is directly south of the Site. Single family residences are located immediately to the west
and northwest of the Site. An apartment complex with greater than 1,100 units is located to the north.
Industrial and retail/wholesale businesses are located to the south and east of the Site.
Approximately 180 private wells at residential and commercial addresses were reported by the local health
departments to be potentially active (i.e., not sealed) within a radius of two miles of the Site. Twenty-two
of these wells are located at a distance less than 1/2 mile from the Site. The nearest public water supply
well is over two miles away in the Spring Lake area of South Plainfield. No federally listed or proposed
threatened or endangered species were found at the Site.
SITE HISTORY AND ENFORCEMENT ACTIVITIES
Chemsol operated as a solvent recovery and waste reprocessing facility in the 1950's through approximately
1964. Historically, the Site experienced numerous accidents, fires and explosions resulting from the storage,
use or processing of flammable materials. In September 1958, a still exploded. In June 1964, a fire started
when a 50-gallon drum of hexane exploded and in June 1962, a fire started when a pile of approximately
500,000 pounds of wax was ignited. In October 1964, a reaction between aluminum chloride and water generated
hydrogen chloride gas resulting in the evacuation of the adjacent residential areas. Following this accident,
Piscataway Township ordered the facility to cease operations. In 1978, the property was rezoned from
industrial to residential. The Site is currently owned by Tang Realty Corporation. In September 1983, the
Chemsol Site was formally placed on the National Priorities List (NPL) making it eligible for federal funds
for investigation of the extent of contamination and for cleanup activities.
From 1983 to 1990, the New Jersey Department of Environmental Protection (NJDEP) directed Tang Realty, under
various enforcement actions, to perform a series of Site investigations related to groundwater and soil
contamination. Approximately 40 groundwater monitoring wells were installed on or in the vicinity of the Site
by contractors for Tang Realty. Sampling results from these monitoring wells indicated that groundwater was
contaminated with various volatile organic compounds (VOCs) including trichloroethylene, chloroform,
chloroethane, toluene, carbon tetrachloride and methylene chloride. Furthermore, sampling and analyses of the
soils (performed between 1980 and 1987) revealed the presence of polychlorinated biphenyls (PCBs) and other
organic compounds.
In the summer of 1988, Tang Realty removed approximately 3,700 cubic yards of PCB-contaminated soils for
off-site disposal. During the soils excavation, several thousand small (less than 1 gallon) containers of
unknown substances were discovered. These unknown substances were stored in a trailer on-site. As a part of a
U.S. Environmental Protection Agency (EPA) removal action undertaken in 1990 and 1991, these unknown
substances were analyzed, grouped with other compatible Site wastes, and transported off-site. Approximately
10,000 pounds of crushed lab pack bottles, 13,500 pounds of hazardous waste solids, 615 gallons of hazardous
waste liguids and 150 pounds of sulfur trioxide were disposed of off-site during the removal action. This
removal action was completed in October 1991 by EPA.
In the fall of 1990, EPA and the NJDEP agreed that EPA should fund the remainder of the investigatory work.
Subseguently, EPA initiated a Remedial Investigation and Feasibility Study (RI/FS) in order to assess the
nature and extent of contamination at the Site and to evaluate remedial alternatives. EPA determined that the
RI/FS would be performed in two phases. The first phase consisted of development of a Focused Feasibility
Study (FFS) to evaluate the usefulness of an interim remedy to restrict off-site migration of contaminated
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groundwater. The second phase was to determine the nature and extent of contamination at the Site.
As part of the FFS, EPA sampled 22 on-site monitoring wells. The results of the FFS indicated that
groundwater at the Site exists in a perched water zone (at depths of less than five feet), and also in the
upper bedrock aguifer (to depths of at least 130 feet). Sampling results revealed that groundwater was
highly contaminated with a wide variety of hazardous substances, including volatile organics, semi-volatile
organics, as well as pesticides and inorganic compounds.
Based on the results of the FFS, EPA selected an interim remedy for the Chemsol Site in a Record of Decision
(ROD) that was signed on September 20, 1991. The objective of this interim remedy was to restrict the
migration of the contaminated groundwater until a more comprehensive Site-wide remedy could be selected and
implemented. The interim remedy consisted of pumping groundwater from well C-l, a former monitoring well
installed by Tang Realty's contractors found to be highly contaminated with VOCs. The pumped groundwater from
C-l would then be treated on-site through an air stripper, after which it would be filtered, followed by
treatment by activated carbon and biological treatment. After treatment, the water was to be discharged to
the on-site stream.
On March 9, 1992, EPA issued a Unilateral Administrative Order (UAO) to Tang Realty, Schering Corporation,
Union Carbide Corporation and Morton International, Inc. (the Respondents) for performance of the interim
remedy. Schering Corporation, Union Carbide Corporation and Morton International, Inc. were identified by EPA
as potentially responsible for the contamination at the Site by having sent their waste to the Chemsol Site
for reprocessing. Tang Realty was identified as the owner of the property.
In November 1993, the Respondents reguested that the interim remedy be modified so that water from the
treatment system could be discharged into the sewer system that leads to the Middlesex County Utilities
Authority (MCUA), instead of into an on-site surface water body (Stream 1A), as specified in the ROD. As a
result, in July 1994, EPA issued an Explanation of Significant Differences which modified the interim remedy
to allow for discharge of treated groundwater to the sewer system. However, EPA also reguired that the
Respondents design and build the biological portion of the treatment system so that, in the future, if the
treated groundwater could not be sent to MCUA, the biological system could be brought guickly online to allow
for direct discharge of treated groundwater to Stream 1A on-site.
Construction of the groundwater treatment plant was completed by the Respondents in June 1994 and the plant
was brought into operation in September 1994. The well has been pumped at varying rates, averaging
approximately 25 gallons per minute. The results of monthly monitoring indicate that the interim remedy has
been effective in restricting the migration of highly contaminated groundwater from the Site. The second
phase RI/FS for the Site was completed in June 1997.
Enforcement Activities
EPA initiated a Potentially Responsible Party (PRP) search by issuing Reguest for Information and Notice
Letters in September 1990. Additional letters were issued in December 1991 and February 1992. Due to the need
to restrict contaminated groundwater from migrating off the Site, an interim remedy was selected in a Record
of Decision issued by EPA, on September 20, 1991. A UAO was issued to four companies to design and construct
the interim remedy. During the course of the performance of this UAO, EPA was notified that a PRP group had
been formed and was assisting the UAO Respondents in financing the interim remedy. The UAO, Respondents
continue to operate the interim remedy, extraction and treatment system.
HIGHLIGHTS OF COMMUNITY PARTICIPATION
The second phase RI/FS report, the Proposed Plan and supporting documentation were made available to the
public in the administrative record file at the Superfund Document Center in EPA Region II, 290 Broadway, New
York, New York and the information repository at the Kennedy Library, 500 Hoes Lane, Piscataway New Jersey.
The notice of availabilily for the above-referenced documents was published in the Home News and Tribune on
August 11, 1997. The public comment period which related to these documents was held from August 11, 1997 to
September 10, 1997 and later extended to October 10, 1997.
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On August 27, 1997, EPA conducted a public meeting at the Piscataway Municipal Complex. The purpose of this
meeting was to inform local officials and interested citizens about the Superfund process, to review planned
remedial activities at the Site, to discuss the Proposed Plan and receive comments on the Proposed Plan, and
to respond to guestions from area residents and other interested parties. Responses to the comments received
at the public meeting and in writing during the public comment period are included in the Responsiveness
Summary (see Appendix V).
SCOPE AND ROLE OF THIS OPERABLE UNIT
This action is the second operable unit or phase taken to address the Site. The first operable unit consisted
of an interim groundwater containment system which is currently operational at the Site. This action will
address contaminated groundwater and soil within the Chemsol property boundaries. A third operable unit is
planned to investigate the extent of groundwater contamination outside the property boundaries and to
determine if any further groundwater remediation is necessary.
SUMMARY OF SITE CHARACTERISTICS
The second phase of the RI field work commenced in October 1992. The purpose of the RI was to accomplish the
following: identify the nature and extent of contaminant source areas; define contamination of ground water,
soils, surface water and sediment; characterize Site hydrogeology; and determine the risk to human health and
the environment posed by the Site. The work was conducted by CDM Federal Programs Corporation under contract
to EPA.
The results of the RI can be summarized as follows.
Soil Investigation
A soil sampling program was designed based on historical Site usage, aerial photographs and the findings of
previous investigations. Samples were taken using an extensive grid system. Group A samples were collected at
200 foot grid spacing in Lot IB and 400 foot grid spacing in Lot 1A. These samples were analyzed for a full
range of organic and inorganic contaminants. Group B samples were collected from Lot IB at 100 foot grid
spacing and field screened for PCBs. Group C samples were collected from biased sampling locations based on
aerial photographs and previous investigations and on a 50 foot grid spacing around those Group B samples
which showed PCBs in their field screening results. In addition, samples from Lot IB were analyzed using the
Toxicity Characteristic Leaching Procedure (TCLP), a test which is used to determine whether a material is a
hazardous waste, as defined by the Resource Conservation and Recovery Act (RCRA). Samples passing the TCLP
test can be disposed at a facility which accepts non-hazardous waste, a so-called Subtitle D facility under
RCRA. Subsurface soil samples were also taken from 102 locations across the Site.
The results of the RI show that the surface and subsurface soils in Lot 1A and Lot IB contain various
contaminants. The contaminants found were: VOCs, including carbon tetrachloride, trichloroethane,
trichloroethene, tetrachloroethene, toluene, ethylbenzene, and xylenes; semi-volatile organic compounds
(SVOCs), including polyaromatic hydrocarbons, phthalates, pesticides (such as aldrin, dieldrin, and DDE) and
PCBs; and inorganics, including manganese and lead. The range of concentrations of certain contaminants
detected in surface and subsurface soil is presented in Table 1. All the soil samples that were analyzed for
TCLP, passed the TCLP test. Based on these data, EPA believes that all soils at the Site will pass the TCLP
test.
Of the contaminants found, PCBs contributed the most to the risks at the Site (see the section entitled
"Summary of Site Risk," below). The majority of PCB and lead contamination occurs in surface soils (0-2 feet
depth), with the exception of one location where PCBs are found at a depth of 6 feet, near boring 76 (see
Figure 3). The VOCs were found to be co-located with the PCBs and lead; therefore, any actions taken to
address PCBs and lead would also address the VOCs.
Groundwater Investigation
As a part of the RI, additional groundwater monitoring wells were installed. Two rounds of groundwater
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sampling were performed during the RI. Samples were collected and analyzed from the 49 wells on the Site. EPA
was initially unsuccessful in obtaining voluntary cooperation to install monitoring wells on properties
adjacent to the Chemsol property. EPA continues to pursue this matter in order to facilitate further
investigation of groundwater migration from the Site.
The geologic formation which underlies the Site is commonly referred to as the Brunswick formation and lies
generally 3 to 14 feet below the ground surface. The Brunswick formation in general contains areas of red
shale, gray shales and siltstones. A gray shale layer acts to preclude groundwater flow in some areas and
separates the bedrock into an upper zone which is located above the gray shale, and a so-called "deep gray
unit" bedrock zone. The Brunswick formation is overlain by a thin layer of overburden which consists of
unconsolidated sand, silt, clay and cobble deposits and fill. This overburden was determined to be typically
3 to 6 feet thick at the Site.
Groundwater flow at the Site is complex. There is perched groundwater present in some areas of the
overburden. However, the primary groundwater flow is through interconnected fractures in the bedrock. Due to
the unpredictable nature and distribution of these fractures, the precise direction of flow and the rate of
groundwater flow can be difficult to predict. In general, groundwater in the upper zone, above the gray
shale, flows to the south. Below the gray shale, groundwater generally flows to the north. Near the southern
boundary of the Site, groundwater is influenced by off-site commercial pumping activities to the south.
With regard to chemical contamination, the RI confirmed that well C-l was by far the most contaminated of all
on-site monitoring wells. The results also confirmed that VOCs are the primary contaminants in groundwater.
The major VOC contaminants include benzene, carbon tetrachloride, chloroform, 1,2,-dichloroethane,
1,2-dichloroethene, tetrachloroethene, toluene and trichloroethene. The bedrock aguifer is contaminated far
in excess of EPA's Safe Drinking Water Act maximum contaminant levels (MCLs) which are the federal regulatory
standards for drinking water. The analytical results also indicate that MCLs for aluminum, iron and manganese
have been exceded in many wells at the Site. Although many pesticides were detected in the groundwater, no
MCLs were exceeded. In the second round of sampling, PCBs slightly in excess of MCLs were found in two wells,
C-l and TW-4 (see Table 2).
Groundwater contamination is present in the bedrock aguifer at both the northern and southern boundaries of
the Site. Evaluation of the hydrogeological data indicates that contaminated groundwater continues to migrate
off-site. However, due to the influences of groundwater pumping from off-site sources and the limited amount
of off-site groundwater sampling data, there remains uncertainty as to the extent of this migration.
Additional off-site sampling is reguired to further define the extent and source of off-site contamination.
In addition to sampling activities, EPA's consultant used mathematical modeling to help determine the optimum
pumping plan which would best capture contaminated groundwater and minimize the amount of contaminated
groundwater which leaves the Site. The modeling showed that, by pumping five additional wells, the
contamination could be contained on-site except possibly for the deep bedrock groundwater in the northwest
corner of the Site.
In addition, during the RI, EPA conducted an assessment to determine whether contamination previously
detected in the Nova-Ukraine section of Piscataway was related to the Chemsol Site. The Nova-Ukraine is a
housing development whose nearest part is located approximately 900 feet south-southeast of the Chemsol Site.
Residential wells in this development had been sampled several times since 1980 by various government
agencies and private consultants. Due to concentrations of VOCs in the wells, NJDEP delineated an Interim
Groundwater Impact Area for a portion of the Nova-Ukraine area. This delineation made residents eligible for
financial assistance to connect to a public water supply. All but four residences elected to be connected to
a public water supply. Based on the results of the RI, EPA does not believe that the groundwater
contamination of residential wells in the Nova-Ukraine area is related to the Chemsol Site.
Surface Water and Sediment Investigation
The ground elevation at the Site is generally lower than the adjacent area. Surface water runoff is towards
the Site during rain events. There are several wetland areas, one drainage ditch, and two streams present at
the Site. During sampling for the FFS in 1991, Stream 1A was sampled and determined to be free of
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contamination from the Site. During the RI, two rounds of sampling were conducted in Stream IB. Twelve
sampling locations were selected. At each location, one surface water sample and two sediment samples were
collected.
Surface water sampling has indicated that the Chemsol Site is contributing low levels of contamination
including VOCs, pesticides and organics to Stream IB (Table 3). However, low levels of pesticides and
inorganics also appear to be entering the Site from off-site sources. Levels of several contaminants exceeded
State Water Quality Criteria. As noted in the previous section, the area surrounding the Site contains many
industrial/commercial establishments. Sediment sampling conducted in conjunction with the surface water
sampling indicates the presence of VOCs, SVOCs, pesticides, PCBs and metals (Table 4).
SUMMARY OF SITE RISKS
Based upon the results of the RI, a baseline risk assessment was conducted to estimate the risks associated
with current and future Site conditions. The baseline risk assessment estimates the human health and
ecological risk which could result from the contamination at the Site if no remedial action were taken.
Human Health Risk Assessment
To perform a Human Health Risk Assessment, the reasonable maximum human exposure is evaluated. A four-step
process is then utilized for assessing site-related human health risks for a reasonable maximum exposure
scenario: Hazard Identification-- identifies the chemicals of potential concern at the Site based on several
factors such as toxicity, freguency of occurrence, and concentration. Exposure Assessment- estimates the
magnitude of actual and/or potential human exposures, the freguency and duration of these exposures, and the
pathways (e.g., ingesting contaminated well-water) by which humans are potentially exposed. Toxicity
Assessment-- determines the types of adverse health effects associated with chemical exposures, and the
relationship between magnitude of exposure (dose) and severity of adverse effects (response). Risk
Characterization-- summarizes and combines outputs of the exposure and toxicity assessments to provide a
guantitative (e.g., one-in-a-million excess cancer risk) assessment of site-related risks.
The baseline risk assessment began with selecting chemicals of potential concern which would be
representative of the contamination found in various media (surface soil, subsurface soil, surface water,
sediment, and groundwater) at the Site (See Table 5 - Chemicals of Potential Concern). Due to the large
number of chemicals detected at the Site, only those chemicals which were thought to pose the highest risk
(based on factors such as freguency of detection and concentration detected) were retained as chemicals of
potential concern. The chemicals of potential concern include: benzo(a)pyrene, pesticides, PCBs and
inorganics in surface soil; 1,1,2,2-tetrachloroethane, pesticides, PCBs, and inorganics in subsurface soils;
VOCs and SVOCs in surface water; and, polyaromatic hydrocarbons, PCBs, and inorganics in sediment. Several of
the contaminants of concern listed above are known or suspected of causing cancer in animals and/or humans or
of causing non-cancer health effects in the liver, kidney, respiratory tract, and the central nervous system.
In the exposure assessment, the potential exposure for human exposure to the chemicals of concerns, in terms
of the type, magnitude, freguency, and duration of exposure, is estimated. The assessment is made for
potentially exposed populations at or near the property considering both the current situation and potential
future conditions. Please see Table 6 for a listing of potential exposure pathways.
An important factor which drives the risk assessment is the assumed future use of the Site. Based on
discussions with the town and the fact that the Site is now zoned for residential, rather than industrial
use, EPA assumed that the most probable future use of the Site would be for residential or recreational
purposes. The Town expressed a preference for recreational use as the property is one of the last parcels of
open land available in the Township. The current land uses at this Site have the potential to impact nearby
residents (adults and children) and possible trespassers onto the Site. In the future, it is possible that
potential human receptors would include residents (adults and children), Site workers (employees), and
construction workers.
Pathways of exposure evaluated for the Site include: 1) sediment and soil ingestion; 2) dermal contact with
soil and sediment; 3) ingestion of contaminated groundwater and surface water; 4) dermal contact with surface
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water; and, 5) inhalation of VOCs and particulates during showering. Because EPA assumed a future
residential/recreational land use of the Site, the list of possible human receptors identified in the
exposure assessment included trespassers, residents (adults and children), Site workers (employees), and
construction workers. Exposure intakes (doses) were calculated for each receptor for all pathways considered.
Potential carcinogenic risks are evaluated using the cancer slope factors developed by EPA for the
contaminants of concern. Cancer slope factors (Sfs) have been developed by EPA's Carcinogenic Risk Assessment
Verification Endeavor for estimating excess lifetime cancer risks associated with exposure to potentially
carcinogenic chemicals (See Table 7). Sfs, which are expressed in units of [mg/kg-day] [-1] are, multiplied
by the estimated intake of a potential carcinogen, in mg/kg-day, to generate an upper- bound estimate of the
excess lifetime cancer risk associated with exposure to the compound at that intake level. The term "upper
bound" reflects a conservative estimate of the risks calculated from the SF. Use of this approach makes the
underestimation of the risk highly unlikely.
EPA's acceptable cancer risk range is 10 -4 to 10 -6 which can be interpreted to mean that an individual may
have a 1 in 10,000 to 1 in 1,000,000 increased chance of developing cancer as a result of Site-related
exposure to a carcinogen over a 70-year lifetime under the specific exposure conditions at the Site. The
State of New Jersey's acceptable risk standard is one in one million (10 -6).
EPA found that contaminants in the surface soil at the Site posed an unacceptable total cancer risk of 2.2 x
10 -3 (i.e., 2.2 in a thousand) to potential future residents through ingestion and dermal contact. In
addition, ingestion and inhalation (during showering) of contaminants in groundwater also posed unacceptable
cancer risks (maximum of 2.4 x 10 -2) (i.e., 2.4 in a hundred) to potential future residents. For Site
workers only the groundwater ingestion pathway was evaluated. The contaminants found in the groundwater posed
unacceptable cancer risks of 5.4 x 10 -3 (i.e., 5.4 in a thousand) to Site workers. Benzene, carbon
tetrachloride, vinyl chloride, chloroform, 1,1-dichloroethene, trichloroethene, 1,2-dichloroethane, and PCBs
are the predominant contributors to the estimated cancer risk in groundwater. The other receptors/exposure
routes including ingestion or direct contact with subsurface soil, and dermal contact with surface water and
sediment) have estimated cancer risk within or below EPA's acceptable risk range.
Noncarcinogenic risks were assessed using a hazard index (HI) approach, (see Table 8) based on a comparison
of expected contaminant intakes and safe levels of intake (Reference Doses). Reference doses (RfDs) have
been developed by EPA for indicating the potential for adverse health effects (see Table 9). RfDs, which are
expressed in units of milligrams per kilogram per day (mg/kg-day), are estimates of daily exposure levels for
humans which are thought to be safe over a lifetime (including sensitive individuals). Estimated intakes of
chemicals from environmental media (e.g., the amount of a chemical ingested from contaminated drinking water)
are compared to the RfD to derive the hazard guotient for the contaminant in the particular medium (i.e., the
hazard guotient eguals the chronic daily intake divided by the RfD). The HI is obtained by adding the hazard
guotients for all compounds within a particular medium that impact a particular receptor population. An HI
greater than 1.0 indicates that the potential exists for noncarcinogenic health effects to occur as a result
of site-related exposures. The HI provides a useful reference point for gauging the potential significance of
multiple contaminant exposures within a single medium or across media. With regard to non-cancer effects,
based on the calculated His, EPA found that several potential exposure pathways could have unacceptable
health effects including: ingestion of surface soil by children (HI=6.2) (see Table 8); ingestion of
disturbed surface soil along the current effluent discharge line by children (HI=3.7); inhalation of
particulates along the current effluent discharge line by children (HI=1.5); ingestion of contaminated
groundwater by adults and children (HI=340 for adults and 800 for children); and, ingestion of contaminated
groundwater by Site workers and construction workers (HI=120 for Site workers and 17 for construction
workers). No noncancer effects were associated with subsurface soils, surface water and sediment.
In summary, the Human Health Risk Assessment concluded that exposure to surface soil and ground water, if not
addressed by the preferred alternative or one of the other active measures considered, may present a current
or potential threat to public health or welfare. In contrast, exposure to subsurface soils, sediments, and
surface water was determined not to pose a significant threat to human health.
Ecological Risk Assessment
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A qualitative and/or semi-quantitative appraisal of the actual or potential effects of a hazardous waste site
on plants and animals, constitutes an ecoloqical risk assessment. A four-step process is utilized for
assessinq site-related ecoloqical risks: Problem Formulation - a qualitative evaluation of contaminant
release, miqration, and fate; identification of contaminants of concern, receptors, exposure pathways, and
known ecoloqical effects of the contaminants; and selection of endpoints for further study. Exposure
Assessment - a quantitative evaluation of contaminant release, miqration, and fate; characterization of
exposure pathways and receptors; and measurement or estimation of exposure point concentrations. Ecoloqical
Effects Assessment - literature reviews, field studies, and toxicity tests, linkinq contaminant
concentrations to effects on ecoloqical receptors. Risk Characterization - measurement or estimation of both
current and future adverse effects.
The environmental evaluation focused on how the contaminants would affect the Site's natural resources.
Natural resources include existinq flora and fauna at the Site, surface water, wetlands and sensitive species
or habitats. A wetlands delineation performed on-site determined that wetlands cover approximately 22 acres
in Lot 1A and 3 acres in Lot IB. Uplands in Lot 1A are wooded. No federally or State listed or proposed
threatened or endanqered flora or fauna are known to occur at or near the Site. However, white-tailed deer,
woodchucks, rabbits, froqs, turtles and birds are known to inhabit the Site.
of exposures to ecoloqical receptors considered for this ecoloqical assessment include surface soil
(qenerally collected from 0 to 2 feet below qround surface), surface sediment (qenerally collected from 0-6
inches), and surface water. Data from subsurface soils (soils under pavements or from depths qreater than 2
feet) were not evaluated. These depths are qreater than those considered likely for potential contact with
burrowinq animals or roots of veqetation. Subsurface sediments (sediments from depths qreater than 6 inches)
also were not evaluated since fish and micro invertebrates are not likely to be exposed to contaminants at
qreater depths. Similarly, qroundwater data were riot used in this ecoloqical assessment because it is
unlikely that ecoloqical receptors can contact contaminants associated with qroundwater. Exposure may occur
throuqh: 1) inqestion of contaminated food items; 2) inqestion of contaminated surface water; 3) incidental
inqestion of contaminated media (i.e., soil, sediment, or water inqested durinq qroominq, eatinq, burrowinq,
etc.); 4) inhalation of contaminants; and, 5) adsorption upon contact with contaminated media.
Site surface soils were evaluated to assess terrestrial ecoloqical risk from food chain transfer effects.
Mathematical modelinq was conducted to estimate exposure doses to representative mammalian and avian
receptors (short-tailed shrew, American robin, and red-tailed hawk). A hazard quotient (HQ) approach was used
to compare the calculated doses to reference toxicity values; a value exceedinq unity (HQ > 1.0) indicates
the potential for adverse ecoloqical effects. The chemicals of concern selected for this evaluation included:
toluene, carbon tetrachloride, 1,1,1-trichloroethene, chlorobenzene, xylenes, naphthalene, PCBs, pesticides,
lead, and mercury.
Based on the terrestrial risk evaluation, the potential for adverse ecoloqical effects exists for Lot 1A and
Lot IB. On Lot IB, many of the contaminants qreatly exceeded their respective reference toxicity values and
require remediation. Lot IB is also hiqhly physically disturbed by development. On Lot 1A, the potential risk
is from only a few contaminants that sliqhtly exceed their respective reference toxicity values. Lot 1A
exists in a relatively undisturbed state and is considered a locally valued habitat (i.e., predominantly
forested wetland). Remedial action to address the potential risk assessed for Lot 1A would likely result in
siqnificant habitat disturbance or destruction. Therefore, it was determined that active remediation is not
warranted in Lot 1A at this time to address terrestrial risk.
The assessment of aquatic risk evaluated the ecoloqical siqnificance of sediment contamination in Stream IB
and the associated ditch by comparinq contaminant concentrations to ecoloqically-based screeninq values (D.
Persaud, et al. Auqust 1993. "Guidelines for the Protection and Manaqement of Aquatic Sediment Quality in
Ontario." Ontario Ministry of Environment and Enerqy). Ecoloqical risks in these sediments, while indicated,
are considered minimal. Additionally, these areas may not represent actual sources of contamination, but may
represent the presence of a miqration pathway from the more heavily contaminated Lot IB. Thus, while
remediation of the Stream IB and the ditch is not warranted at this time, they will be monitored to assess
the affect of the remedial action in Lot IB on contaminant levels.
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The assessment of aquatic risk also evaluated the potential risk from surface water in Stream IB. The
potential risk is considered similar to the potential risk from sediment in that, while several contaminants
exceed NJ State Surface Water Quality, the contaminants may be migrating from more heavily contaminated areas
of the Site. Therefore, surface water is also included in the stream monitoring.
Uncertainties
The procedures and estimates used to assess risks, as in all such assessments, are subject to a wide variety
of uncertainties. In general, the main sources of uncertainty include:
! environmental chemistry sampling and analysis
! environmental parameter measurement
! fate and transport modeling
! exposure parameter estimation
! toxicological data
Uncertainty in environmental sampling arises in part from the potentially uneven distribution of chemicals in
the media sampled. Conseguently, there is significant uncertainty as to the actual levels present.
Environmental chemistry analysis error can stem from several sources including the errors inherent in the
analytical methods and characteristics of the matrix being sampled.
Uncertainties in the exposure assessment are related to estimates of how often an individual would actually
come in contact with the chemicals of concern, the period of time over which such exposure would occur, and
in the models used to estimate the concentrations of the chemicals of concern at the point of exposure.
Uncertainties in toxicological data occur in extrapolating both from animals to humans and from high to low
doses of exposure, as well as from the difficulties in assessing the toxicity of a mixture of chemicals.
These uncertainties are addressed by making conservative assumptions concerning risk and exposure parameters
throughout the assessment. As a result, the baseline risk assessment provides upper bound estimates of the
risks to populations near the Site, and it is highly unlikely to underestimate those actual risks related to
the Site.
More specific information concerning public health risks, including a quantitative evaluation of the degree
of risk associated with various exposure pathways, is presented in the RI report.
Actual or threatened releases of hazardous substances from this Site, if not addressed by implementing the
response action selected in this ROD, may present an imminent and substantial endangerment to public health,
welfare, or the environment.
REMEDIAL ACTION OBJECTIVES
Remedial action objectives are specific goals to protect human health and the environment. These objectives
are based on available information and standards such as applicable or relevant and appropriate requirements
(ARARs) and risk-based levels established in the Risk Assessment.
The following objectives were established for the Chemsol Site:
(1) Restoring the soil at the Site to levels which would allow for residential/recreational use (without
restrictions);
(2) augment the existing groundwater system to contain that portion of contaminated groundwater that is
unlikely to be technically practicable to fully restore and restore the remaining affected groundwater to
State and federal drinking water standards;
(3) remove and treat as much contamination as possible from the fractured bedrock;
(4) prevent human exposure to contaminated groundwater;
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(5) prevent human exposure to surface soils contaminated with PCB concentrations above 1 part per million
(ppm) and lead concentrations above 400 ppm; and
(6) eliminating, to the greatest extent practicable, continuing sources of contamination to the groundwater.
Soil cleanup levels for PCBs at the Site are based on the toxicity reassessment developed by EPA since the
original 1990 EPA "Guidance on Remedial Actions for Superfund Sites with PCB Contamination". For residential
land use, an action level of 1 ppm is specified for PCBs. The 400 ppm lead cleanup level is based on EPA's
1994 "Revised Interim Soil Lead Guidance for CERCLA Sites and RCRA Corrective Action Facilities." VOCs in
soil were found to be co-located with the PCBs and lead; therefore EPA did not develop separate cleanup
levels for VOCs in soil. EPA estimates that there are approximately 18,500 cubic yards of soil that contain
PCBs at levels above 1 ppm and/or lead at levels above 400 ppm.
The State of New Jersey has developed State-wide soil cleanup criteria for several of the contaminants found
at the Chemsol Site, including several VOCs, SVOCs, lead (400 ppm) and PCBs (0.49 ppm). Based on the data
collected to date, in meeting EPA's cleanup levels for PCBs and lead cited previously, EPA believes the
remedy will also achieve the State of New Jersey residential direct contact and impact to groundwater soil
cleanup criteria. For instance, VOC and PCB, contamination is concentrated in the areas around borings 74 and
76 and extends as deep as 6 feet in these locations. As these locations are excavated to achieve the 1 ppm
action level for PCBs, it appears based on current data, that NJDEP's cleanup criteria of 0.49 ppm for PCB
and its VOCs criteria may be achieved through the use of NJDEPs compliance averaging procedure.
The ultimate goal of the Superfund Program approach to groundwater remediation as stated in the National Oil
and Hazardous Substances Pollution Contingency Plan (40 CFR part 300) is to return usable groundwater to
their beneficial uses within a time frame that is reasonable. Therefore, for the Chemsol Site, the final
groundwater remediation goals will be federal MCLs and State groundwater guality standards. Due to the
complex geology and the possible presence of non-agueous phase liguids at this Site, EPA believes that it may
not be technically practicable to fully restore some portion of the contaminated on-site groundwater to
federal and State standards. By law, any areas of contaminated groundwater which cannot be restored to meet
federal and/or State groundwater standards reguire a waiver of such standards on the basis of technical
impracticability. As will be discussed in subseguent sections, if after implementation of the remedy, it
proves to be technically impracticable to meet groundwater guality standards, EPA will waive such standards
for that portion of the plume that is found to be technically impracticable to remediate. Such a waiver would
be documented in an Explanation of Significant Differences (BSD). A Classification Exception Area (CEA) would
be established for the Site until such time that it can be shown that State groundwater guality standards are
not exceeded. Performance data from any groundwater system selected for the Site would be used to determine
the parameters and locations (both vertically and horizontally) which may reguire a technical
impracticability waiver.
DESCRIPTION OF REMEDIAL ACTION ALTERNATIVES
CERCLA °121(b)(1), [42 U.S.C. °9621(b)(1)] mandates that a remedial action must be protective of human health
and the environment, cost-effective, and utilize permanent solutions and alternative treatment technologies
or resource recovery technologies to the maximum extent practicable. Section 121(b)(1) also establishes a
preference for remedial actions which employ, as a principal element, treatment which permanently and
significantly reduces the volume, toxicity, or mobility of the hazardous substances, pollutants and
contaminants at a site. CERCLA °121(d), [42 U.S.C. °9621(d)], further specifies that a remedial action must
attain a level or standard of control of the hazardous substances, pollutants, and contaminants, which at
least attains ARARs under federal and state laws, unless a waiver can be justified pursuant to CERCLA
°121(d)(4),[42 U.S.C. °9621(d)(4)].
EPA's FS evaluated, in detail, four remedial alternatives for addressing soil contamination at the Site and
three remedial alternatives for addressing groundwater contamination. Cost and construction time, among other
criteria, were evaluated for each remedial alternative. The time to implement a remedial alternative reflects
the estimated time reguired to construct the remedy. The estimates do not include the time to possibly
negotiate with the potentially responsible parties, prepare design documents, or procure contracts.
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The remedial alternatives are:
SOIL
Alternative S-l: No Further Action
Estimated Capital Costs:$388,660
Estimated Annual O&M Costs (30 years):$0
Estimated Total Present Worth Value:$388,660
Estimated Implementation Period:3-6 months
The Superfund process requires that the "no-action" alternative be considered as a baseline for comparison
with other alternatives. Under Alternative S-l, EPA would take no action at the Site. However, the No-Action
alternative includes, as with the other soil alternatives, a single sampling event for drummed waste and soil
stockpiled at the Site, along with their transportation and off-site disposal. The drummed wastes were
generated from the various investigations performed at the Site and the stockpiled soils were generated from
construction activities performed at the Site. Since contaminants would remain on-site, institutional
controls (e.g., a deed restriction) would be placed on property that would restrict future use of the Site.
Because this alternative would result in contaminants remaining on-site above health based levels, a review
would be conducted within five years from initiation of the remedial action to ensure that the remedy
continues to provide adequate protection of human health and the environment.
Alternative S-2A: Capping with Soil
Estimated Capital Costs:$1,855,850
Estimated Annual O&M Costs (30 years):$2,000
Estimated Total Present Worth Value:$1,894,000
Estimated Implementation Period:3-6 months
Alternative S-2A includes the construction of a single layer (18 inches thick) soil cap covering 12 acres of
the property which are contaminated above the soil cleanup levels. It would also require institutional
controls to ensure that no intrusive activities would be performed on the capped area in the future since
such activities would affect the cap's integrity. This alternative would allow for many recreational uses of
the property, such as a park or playground, among others. A single sampling event of drummed waste and
stockpiled soil along with their transportation and off-site disposal would be performed. Because this
alternative would result in contaminants remaining on-site above health based levels, a review would be
conducted within five years from the initiation of the remedial action to ensure that the remedy continues to
provide adequate protection of human health and the environment.
Alternative S-3: Excavation and Off-Site Disposal
Estimated Capital Costs:$5,573,001
Estimated Annual O&M Costs (30 years):$0
Estimated Total Present Worth Value:$5,573,000
Estimated Implementation Period:6-12 months
Alternative S-3 includes excavation and off-site disposal of all surface soils contaminated with PCBs and
lead that are above EPA's cleanup levels. Approximately 18,500 cubic yards of soil with PCB levels greater
than 1 part per million and lead levels greater than 400 parts per million will be trucked off-site and
disposed of at a licensed and approved RCRA/TSCA (Toxic Substances Control Act) facility. The excavated areas
would be backfilled with imported clean fill from an off-site location, and covered with topsoil and seeded
with grass. The excavation and off-site disposal of the contaminated soils will allow for residential or
recreational use of the Site in the future. As with Alternative S-l, this alternative includes a single
sampling event of drummed waste and stockpiled soil prior to disposal off-site. Since this alternative would
result in the removal of soils above EPA's cleanup levels no contaminants would remain in on-site soils above
health-based levels and, therefore, five year reviews of the remedy would not be necessary.
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Alternative S-4A: Excavation and On-Site Low Temperature Thermal Desorption of PCB-Contaminated Soil with
Disposal of Lead Contaminated Soil.
Option-A [On-Site Solidification of Lead Contaminated Soil]
Estimated Capital Costs:$11,963,134
Estimated Annual O&M Costs (30 years):$0
Estimated Total Present Worth Value:$11,963,134
Estimated Implementation Period:3-6 months
For Option A, all surface soil contaminated with PCBs above 1 part per million (18,500 cubic yards) would be
excavated. The excavated soil would be treated on-site by low temperature thermal desorption (LTTD) to remove
PCBs and VOCs. The LTTD unit would be operated in compliance with the Clean Air Act (CAA), RCRA, and all
applicable State regulations. The treated soil would then be backfilled to the excavated areas, topsoil would
be placed on the treated soils and the area seeded. As with the other soil Alternatives, Alternative S-4A
includes a single sampling event of drummed waste and stockpiled soil prior to disposal off-site.
The lead contaminated soils would be solidified/stabilized on-site by mixing with Portland cement. The area
on-site where this contaminated soil is placed would be protected from future intrusions. Because this
alternative would result in contaminants remaining on-site above health based levels, a review would be
conducted within five years from initiation of the remedial action to ensure that the remedy continues to
provide adeguate protection of human health and the environment.
Option-B [Off-Site Disposal of Lead Contaminated Soil]
Estimated Capital Costs:$12,241,639
Estimated Annual O&M Costs(30 years):$0
Estimated Total Present Worth Value:$12,242,000
Estimated Implementation Period:6-9 months
As in Option A, all surface soil contaminated with PCBs above 1 part per million (18,500 cubic yards) would
be excavated. The excavated soil would be treated on-site by low temperature thermal desorption (LTTD) to
remove PCBs and VOCs. The LTTD unit would be operated in compliance with the CAA, RCRA, and all applicable
State regulations. The treated soil would then be backfilled to the excavated areas, topsoil would be placed
on the treated soils and seeded. As with the other soil Alternatives, Alternative S-4B includes a single
sampling event of drummed waste and stockpiled soil prior to disposal off-site.
Under Option B, the lead-contaminated soil would be excavated and transported off-site for disposal at a
licensed and approved RCRA disposal facility. The excavated areas would be backfilled with clean fill, and
seeded. Since this alternative would result in the removal of soils above EPA's cleanup levels no
contaminants would remain in on-site soils above health-based levels and, therefore, five year reviews of the
remedy would not be necessary.
GROUNDWATER
Alternative GW-1: No Action with Monitoring
Estimated Capital Costs:$0
Estimated Annual O&M Costs(30 years):$59,336
Estimated Total Present Worth Value:$912,000
Estimated Implementation Period:0 months
The Superfund program reguires that a "No-Action" alternative be considered as a baseline for comparison with
other alternatives. Under this alternative, EPA would cease actions at the Site to treat the contaminated
groundwater and to restrict the off-site migration of contaminated groundwater. However, the No-Action
alternative does include long-term monitoring. Because this alternative would result in contaminants
remaining on-site above health based levels, a review would be conducted within five years from initiation of
the remedial action to ensure that the remedy continues to provide adeguate protection of human health and
the environment.
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Alternative GW-2(A and B): Continue Existing Interim Action - Extract Groundwater from Well C-l
Option - A
Estimated Capital Costs:$45,097
Estimated Annual O&M Costs(30 years):$452,738
Estimated Total Present Worth Value:$7,000,300
Estimated Implementation Period:0 months
Under Option-A of this alternative, the current extraction of the groundwater from well C-l would continue.
The extracted groundwater first passes through an air stripper, after which it is filtered, followed by
activated carbon adsorption. The treated water is then discharged to the Middlesex County Utilities Authority
(MCUA) Publicly Owned Treatment Works (POTW) . The treatment process generates a small guantity of
non-bio-solids waste annually. The capital cost of $45,097 includes costs for replacing the existing pipeline
(which carries water from well C-l to the treatment plant) with an underground pipeline in order not to
restrict the future uses of the property. This pumping is expected to continue until MCLs and State
groundwater guality standards are reached in the plume. Because this alternative would result in contaminants
remaining on-site above health based levels, a review would be conducted within five years from initiation of
the remedial action to ensure that the remedy continues to provide adeguate protection of human health and
the environment. Also, a CEA would be established for the Site until such time that it can be shown that
State groundwater guality standards are not exceeded.
Option - B
Estimated Capital Costs:$45,097
Estimated Annual O&M Costs(30 years):$726,336
Estimated Total Present Worth Value:$11,209,000
Estimated Implementation Period:3 months
In addition to the treatment described in Option-A, a biological treatment phase would be added for Option-B.
This would be done by starting up the existing (currently unused) biological treatment plant. This phase is a
contingency in the event that in the future, treated groundwater cannot be sent to MCUA. The biological
treatment will provide additional treatment so the groundwater will achieve federal and State surface water
guality standards which would allow for discharge to Stream 1A. The capital cost of $45, 097 includes costs
for replacing the existing pipeline (which carries water from well C-l to the treatment plant) with an
underground pipeline in order not to restrict the future uses of the property. Because this alternative would
result in contaminants remaining on-site above health based levels, a review would be conducted within five
years from initiation of the remedial action to ensure that the remedy continues to provide adeguate
protection of human health and the environment. Also, a CEA would be established for the Site until such time
that it can be shown that State groundwater guality standards are not exceeded.
GW-5(A and B): Extract Groundwater from Additional Wells - Use Existing Treatment Processes Air
Stripping/Aerobic Mixed Growth Biotreatment/Filtration/Activated Carbon Adsorption
Option - A
Estimated Capital Costs:$390,189
Estimated Annual O&M Costs(30 years):$670,892
Estimated Total Present Worth Value: $10,699,000
Estimated Implementation Period:3 months
Option-A of this alternative is almost identical to Alternative GW-2A. They differ in that, in addition to
well C-l, groundwater would be pumped from other on-site wells. EPA cost estimates are based on pumping five
additional wells. However, the number of wells to be pumped will be determined during the remedial design.
Pumping from these additional wells will allow for more effective on-site containment of the plume, and also
allow for groundwater extraction from other contaminated areas on-site. As in Alternative GW-2A, the treated
groundwater would be discharged to MCUA POTW. The capital cost of $390,189 includes costs for replacing the
existing pipeline (which carries water from well C-l to the treatment plant) with an underground pipeline in
order not to restrict the future uses of the property as well as costs associated with installation of
additional extracting wells. Because this alternative would result in contaminants remaining on-site above
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health based levels, a review would be conducted within five years from initiation of the remedial action to
ensure that the remedy continues to provide adequate protection of human health and the environment. Also, a
CEA would be established for the Site until such time that it can be shown that State groundwater quality
standards are not exceeded.
Option - B
Estimated Capital Costs:$390,189
Estimated Annual O&M Costs(30 years):$766,336
Estimated Total Present Worth Value:$12,169,000
Estimated Implementation Period:3 months
A bioloqical treatment phase would be added for Option-B. This would be done by starting up the existing
(currently unused) biological treatment plant. Use of the biological treatment phase would allow for
discharge to Stream 1A in compliance with federal and State standards. The capital cost of $390,189 includes
costs for replacing the existing pipeline (which carries water from well C-l to the treatment plant) with an
underground pipeline in order not to restrict the future uses of the property as well as costs associated
with installation of additional extraction wells. Because this alternative would result in contaminants
remaining on-site above health based levels, a review would be conducted within five years from initiation of
the remedial action to ensure that the remedy continues to provide adequate protection of human health and
the environment. Also, a CEA would be established for the Site until such time that it can be shown that
State groundwater quality standards are not exceeded.
SUMMARY OF COMPARATIVE ANALYSIS OF ALTERNATIVES
In selecting a remedy, EPA considered the factors set out in CERCLA °121, 42 U.S.C. °9621, by conducting a
detailed analysis of the viable remedial alternatives pursuant to the NCP, 40 CFR °300.430(e)(9) and OSWER
Directive 9355.3-01. The detailed analysis consisted of an assessment of the individual alternatives against
each of nine evaluation criteria and a comparative analysis focusing upon the relative performance of each
alternative against those criteria.
The following "threshold" criteria are the most important and must be satisfied by any alternative in order
to be eligible for selection:
1. Overall protection of human health and the environment addresses whether or not a remedy provides
adequate protection and describes how risks posed through each exposure pathway (based on a reasonable
maximum exposure scenario) are eliminated, reduced, or controlled through treatment, engineering controls, or
institutional controls.
2. Compliance with ARARs addresses whether or not a remedy would meet all of the applicable (legally
enforceable), or relevant and appropriate (pertaining to situations sufficiently similar to those encountered
at a Superfund site such that their use is well suited to the site) requirements of federal and state
environmental statutes and requirements or provide grounds for invoking a waiver.
The following "primary balancing" criteria are used to make comparisons and to identify the major trade-offs
between alternatives:
3. Long-term effectiveness and permanence refers to the ability of a remedy to maintain reliable
protection of human health and the environment over time, once cleanup goals have been met. It also addresses
the magnitude and effectiveness of the measures that may be required to manage the risk posed by treatment
residuals and/or untreated wastes.
4. Reduction of toxicity, mobility, or volume through treatment refers to a remedial technology's expected
ability to reduce the toxicity, mobility, or volume of hazardous substances, pollutants or contaminants at
the site.
5. Short-term effectiveness addresses the period of time needed to achieve protection and any adverse
impacts on human health and the environment that may be posed during the construction and implementation
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periods until cleanup goals are achieved.
6. Implementability refers to the technical and administrative feasibility of a remedy, including the
availability of materials and services needed.
7. Cost includes estimated capital and operation and maintenance costs, and the present-worth costs.
The following "modifying" criteria are considered fully after the formal public comment period on the
Proposed Plan is complete:
8. State acceptance indicates whether, based on its review of the RI/FS reports and the Proposed Plan, the
State supports, opposes, and/or has identified any reservations with the selected alternative.
9. Community acceptance refers to the public's general response to the alternatives described in the
Proposed Plan and the RI/FS reports. Factors of community acceptance to be discussed include support,
reservation, and opposition by the community.
A comparative analysis of the remedial alternatives based upon the evaluation criteria noted above follows:
Overall Protection of Human Health and the Environment
Soil
Alternative S-l, No Action, would not be protective of human health and the environment because the Site
would remain in its current condition. The soils would continue to pose a threat to potential future
residents, trespassers, potential ecological receptors and the environment. Therefore, Alternative S-l has
been eliminated from consideration and will not be discussed further.
Alternative S-2A relies on containment and institutional controls to provide protection over time. Deed
restrictions would have to be enforced to ensure that the cap is not breached in the future in order for this
alternative to be protective.
Upon completion of Alternative S-3 and Alternative S-4(A and B), the potential risks to human health and the
environment from organic and inorganic contaminants would be minimized if not eliminated through off-site
removal or treatment of contaminants in the surface soils to protective levels.
Groundwater
Alternative GW-1, No Adion, would not be protective of human health and the environment because the
groundwater would continue to migrate off-site continuing to pose a potential threat to users. Therefore,
Alternative GW-1 has been eliminated from consideration and will not be discussed further.
Alternatives GW-2 (A and B) and GW-5 (A and B) would be protective of human health by controlling the
migration of contaminated groundwater through pumping and by removing contaminants through treatment of
pumped groundwater. GW-5 (A and B) captures and removes more contamination than GW-2 (A and B).
Compliance with ARARs
Soil
There are no chemical specific ARARs for soil. However, the State has developed State-wide soil cleanup
criteria that while not legally applicable, were considered by EPA in selecting cleanup levels for the Site.
If implemented, Alternatives S-3 and S-4(A and B) would meet location-specific and action-specific Federal
and State ARARs for the contamination in the soils. The major ARARs for Alternative S-3 are Federal and State
Resource Conservation and Recovery Act (RCRA) reguirements which control the transportation and disposal of
hazardous waste. For example, the soil excavated under Alternative S-3 would be disposed at a facility which
is licensed under RCRA to accept hazardous waste. Alternatives S-4(A and B) would involve the use of an
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on-site treatment technology which would be subject to RCRA treatment regulations and Clean Air Act
reguirements regarding emissions from the treatment system. Air emissions will reguire air permit
eguivalences from the State of New Jersey. In addition, because a portion of the Site is classified as
wetlands, all alternatives (soil and/or groundwater) would need to comply with Section 404 of the Clean Water
Act and federal Executive Order 11990 which reguires federal agencies to take actions to minimize the
destruction, loss, or degradation of wetlands and to preserve and enhance the natural and beneficial values
of wetlands. A wetland restoration and monitoring plan will be prepared as a part of the remedial design plan
to address potential impact to the wetlands, such as groundwater drawdown.
Groundwater
Alternatives GW-2 (A and B) and GW-5(A and B) would meet the chemical-specific ARARs for the treated water
before discharge. These include New Jersey Pollutant Discharge Elimination System reguirements for discharges
to surface water. In addition, air emissions from the treatment plant would need to comply with Federal and
State emissions standards. Alternatives GW-2(A and B) and GW-5(A and B) produce a non-hazardous filter cake.
Also, a CEA would be established for the Site until such time that it can be shown that State groundwater
guality standards are not exceeded.
Alternative GW-5(A and B) is more likely to achieve State and federal water guality standards in the aguifers
than is GW-2, because GW-5(A and B) would utilize several wells to extract contaminated groundwater from the
aguifer whereas GW-2 would utilize only one extraction well. The additional extraction will provide greater
capture of contaminants and therefore increase the likelihood of achieving State and federal water guality
standards. It is possible that it will be technically impracticable to restore all portions of the aguifers
to meet State and federal standards. Any areas of contaminated groundwater which cannot be restored to meet
State and/or federal groundwater guality standards reguire a waiver of such standards on the basis of
technical impracticability. If after implementation of the remedy, it proves to be technically impracticable
to meet water guality standards, EPA would waive such standards. Performance data from any groundwater system
selected for the Site would be used to determine the parameters and locations (both vertically and
horizontally) which may reguire a technical impracticability waiver.
Remedial activities for groundwater at the Site may disturb or impact wetlands. Impacts may include
groundwater drawdown or alteration of the hydrologic characteristic of the area, as well as improvement or
installation of wells. These potential impacts will be considered in the remedial design report.
Long-Term Effectiveness and Permanence
Soil
Alternatives S-4(A and B) provide the highest degree of long-term effectiveness and permanence since the
waste would be treated to permanently remove organic contaminants. Alternative S-3 provides a high degree of
long-term effectiveness by removing waste from the Site but does not provide a high degree of permanence
since waste would not be destroyed but only contained off-site.
Under Alternative S-2A, contaminated soils would remain on-site and, therefore, this remedy would provide the
least amount of long-term effectiveness and permanence. In addition, institutional controls would need to be
employed and enforced in order to ensure effectiveness.
Groundwater
Alternatives GW-2(A and B) and GW-5(A and B) provide varying amounts of containment of the contaminated
groundwater. Additional off-site investigations to determine the extent of groundwater contamination are
necessary to ensure that risks to neighboring communities are minimized. Alternatives GW-5 (A and B) provide
a higher degree of long-term effectiveness than Alternatives GW-2 (A and B) by capturing a larger mass and
volume of contaminants in the groundwater. The on-site treatment facility will therefore, treat a greater
guantity of contaminated groundwater and remove a larger mass of contain)nants from the extracted groundwater.
The additional extraction wells would also better contain the plume on-site.
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Short-Term Effectiveness
Soil
Alternatives S-2A, S-3, and S-4(A and B) do involve construction activities that would pose a low level risk
of exposure to soils by ingestion, direct contact and inhalation to Site workers; however this risk can be
managed by appropriate health and safety measures. All of the alternatives can be implemented relatively
guickly, in less than a year following completion of design.
Alternative S-3 involves a significant increase in dust, vapor, and noise generation during soil excavation.
These would be minimized through the use of measures which would be undertaken to ensure that all activities
are performed in such a way that vapors, dust, and other materials are not released to the surrounding
community during excavation. In addition, Alternative S-3 includes off-site transportation of the excavated
soils. This will increase truck traffic and noise in the community during the period when soil is being
transported off-site. Transportation flow patterns will be designed to minimize traffic impacts on the
community. This may entail constructing a road from the Site which will bypass residential areas.
Under Alternative S-4(A and B), a thermal desorber would be placed on-site, causing increases in noise and
emissions from the unit. To minimize the risk from inhalation of vapors from the thermal desorber which is
reguired, a secondary chamber would be utilized that would oxidize all organic compounds released from the
LTTD process to carbon dioxide, water and hydrochloric acid.
Groundwater
All the groundwater alternatives provide short-term effectiveness in protecting the Site workers and
neighboring communities from the risks due to ingestion and inhalation of VOCs. Alternatives GW-2(A and B)
and GW-5(A and B) would pose a low level risk to Site workers during construction; however, this risk can be
managed by the use of appropriate health and safety measures. Alternative GW-2 is a continuation of the
existing system and is running now. Alternatives GW-5 (A and B) can be implemented very guickly (in
approximately 3 months) since they are simply an addition to the current system.
Reduction of Toxicity, Mobility or Volume Through Treatment
Soil
Alternatives S-4 (A and B) provide for physical removal of the contaminated material and the maximum reduction
in toxicity and mobility through treatment. Alternative S-2A and Alternative S-3 do not include the use of
treatment to reduce the toxicity, mobility or volume of contaminated soil. For Alternative S-2A, reduction in
the mobility of the contamination would be achieved through the use of containment. For Alternative S-3,
reduction in toxicity, mobility and volume would be achieved through excavation and off-site disposal rather
than through treatment.
Groundwater
Alternatives GW-2(A and B) and GW-5(A and B) reduce the toxicity and volume of contamination from the
extracted groundwater. However, Alternative GW-5(A and B) would operate at approximately twice the pumping
rate of Alternative GW-2(A and B). The mobility of the contaminants is completely controlled by the
pump-and-treat alternatives to the extent that the groundwater is within the capture zone of the wells.
Greater reduction of volume and toxicity of contaminated groundwater is achieved by GW-5 than GW-2.
Alternative GW-5 also results in greater capture and containment of contaminated groundwater.
Implementability
Soil
All of the services and materials needed to implement the soil alternatives are readily available
commercially. Each alternative utilizes standard technologies for excavation, capping and transportation of
-------
soils. However, due to the high demand for thermal desorption units, there may be a delay in implementing
Alternative S-4 (A and B) . All the alternatives are technically feasible but Alternatives S-4 (A and B)
reguire a treatability study to obtain design parameters for the full-scale system. Alternatives S-4(A and B)
have complex administrative issues because of the guantity of eguipment that needs to be set up at the Site
and the need to provide substantive compliance with State air emissions permit reguirements. Alternative S-3
is easily implementable using standard excavation technology. If possible, a temporary access road that would
provide more direct access from the Site to nearby highways, would be built, in order to minimize the number
of trucks traveling through the community. Engineering controls are readily implementable to minimize air
borne dust and contaminants for all excavation activities. If necessary, a small pilot-scale study will be
undertaken to help in estimating the ambient air impact for soil excavation at the Site.
Groundwater
All of the services and materials needed to implement the groundwater alternatives are readily available
commercially. All the alternatives are technically feasible but Alternatives GW-2(A and B) and GW-5(A and B)
reguire skilled operators to successfully implement the remedy. The alternatives are also feasible from an
administrative standpoint. The reguired activities for the pump-and-treat would occur on Chemsol property.
The treatment plant for the interim remedy has already been built and has been in operation for the last
three years with discharge to the MCUA POTW. The effluent line for the discharge to Stream 1A has also been
installed even though it is not currently being used.
All the services needed to implement the alternatives already exist. The pump-and-treat alternatives reguire
the most services since they reguire operation of the treatment plant and disposal of filtered waste from the
plant.
Costs
The capital, annual operation and maintenance, and present worth costs are presented in Tables 10 and 11,
(Appendix II). Present worth costs for all the alternatives were calculated assuming a 5% interest rate and a
30-year operation and maintenance period.
Soil
Capital costs for Alternative S-l are estimated to be $338,660 which includes costs for a single sampling
event of drummed waste and stockpiled soils along with transporting and off-site disposal of the drummed
waste and the stockpiled soil. There would be no operation and maintenance costs so that the total present
worth is estimated to be $338,660.
Capital costs for Alternative S-2A are estimated to be $1,855,850. This includes the costs of the sampling
and off-site disposal described for Alternative S-l plus the costs of constructing and seeding the soil cap.
Annual operation and maintenance costs are estimated to be $2,000. The total present worth is estimated to be
$1,894,000.
Capital costs for Alternative S-3 are estimated to be $5,573,000. This includes the costs of the sampling and
off-site disposal described for Alternative S-l plus the costs of excavating and disposing of the
contaminated soils off-site. There are no annual operation and maintenance costs so that the total present
worth is estimated to be $5,573,000.
Capital costs for Alternative S-4A are estimated to be $11,963,134. This includes the costs of the sampling
and off-site disposal described for Alternative S-l plus the costs of excavating and treating the
contaminated soils on-site. There are no annual operation and maintenance costs since the treatment would be
accomplished in less than a year so that the total present worth is estimated to be $11,963,134.
Capital costs for Alternative S-4B are estimated to be $12,241,639. This includes the costs of the sampling
and off-site disposal described for Alternative S-l plus the costs of excavating and treating the
contaminated soils on-site and disposing the lead-contaminated soils off-site. There are no annual operation
and maintenance costs since the work would be accomplished in less than a year so that the total present
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worth is estimated to be $12,242,000.
Groundwater
In the case of all groundwater alternatives, the costs (Table 11, Appendix II) are in addition to those
already incurred to install and operate the existing interim extraction and treatment system at the Site.
Alternative GW-1 does not have any capital cost. The annual operation and maintenance costs are estimated to
be $59,336 and include costs for monitoring the groundwater. The total present worth cost is estimated to be
$912,000.
Capital costs for Alternative GW-2A are estimated to be $45,097. These costs include costs associated with
installation of underground piping from well C-l to the treatment plant. The annual operation and maintenance
costs are estimated to be $452,738. The total present worth is estimated to be $7,000,300.
Capital costs for Alternative GW-2B are estimated to be $45,097 and include costs associated with
installation of underground piping from well C-l to the treatment plant. Annual operation and maintenance
costs are estimated to be $726,336. The total present worth is estimated to be $11,209,000.
Capital costs for Alternative GW-5A are estimated to be $390,189 and include costs associated with
installation of underground piping from well C-l to the treatment plant and costs for installing piping to
five additional extraction wells. Annual operation and maintenance costs are estimated to be $670,892. The
total present worth is estimated to be $10,699,000.
Capital costs for Alternative GW-5B are estimated to be $390,189 and include costs for installing piping to
five additional extraction wells. Annual operation and maintenance costs are estimated to be $766,336. The
total present worth is estimated to be $12,169,000.
State Acceptance
The NJDEP will not concur with this ROD. This stems from the fact that EPA's residential cleanup level for
PCBs in soil is 1 ppm while NJDEP's residential cleanup criterion is 0.49 ppm. NJDEP cannot concur with the
ROD unless it specifically reguires institutional controls if the Site is not remediated to the NJDEPs 0.49
ppm residential use criterion for PCBs. However, NJDEP does not object to EPA's groundwater remedy.
Community Acceptance
EPA solicited input from the community on the remedial alternatives proposed for the Chemsol Site. While the
community is supportive of EPA's preferred remedy, some citizens have indicated their preference for EPA to
cleanup the soils at the Site to NJDEP cleanup criteria of 0.49 ppm for PCBs, instead of EPA's cleanup level
of 1 ppm. The attached Responsiveness Summary addresses the comments received during the public comment
period.
SELECTED REMEDY
Based upon consideration of the results of the RI/FS, the reguirements of CERCLA, the detailed analysis of
the alternatives, and public comments, EPA has determined that Alternative S-3 and Alternative GW-5 are the
appropriate remedies for the Site, because they best satisfy the reguirements of CERCLA °121 and the NCP's
nine evaluation criteria for remedial alternatives, 40 CFR °300.430(e)(9). This remedy is comprised of the
following components:
Soil
Excavation and off-site disposal of approximately 18,500 cubic yards of contaminated soil with PCBs
above 1 part per million (ppm) and lead above 400 ppm. The excavated areas will be backfilled with
clean imported fill from an off-site location, covered with topsoil, then seeded with grass.
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! Disposal of the excavated soils at an appropriate off-site disposal facility, depending on waste
characteristics.
Groundwater
! Installation and pumping of additional extraction wells to contain contaminated groundwater on-site.
! Continued treatment of extracted groundwater through the existing groundwater treatment facility. The
treated groundwater may continue to be released to the Middlesex County Utilities Authority (MCUA), if
not, will undergo on-site biological treatment, prior to being released on-site, to Stream 1A.
! Perform an additional groundwater investigation to determine if contaminated groundwater is leaving
the property boundaries.
Surface Water and Sediments
! Monitoring of sediments and surface water to determine if remediation of Lot IB results in lower PCB
levels in the on-site streams, Stream 1A and IB over time.
The selection of this remedy is based on the comparative analysis of the alternatives discussed above and
provides the best balance of tradeoffs with respect to the nine evaluation criteria.
STATUTORY DETERMINATIONS
As was previously noted, CERCLA °121 (b)(1), mandates that a remedial action must be protective of human
health and the environment, cost-effective, and utilize permanent solutions and alternative treatment
technologies or resource recovery technologies to the maximum extent practicable. Section 121 (b)(1) also
establishes a preference for remedial actions which employ treatment to permanently and significantly reduce
the volume, toxicity, or mobility of the hazardous substances, pollutants, or contaminants at a site. CERCLA
°121(d), further specifies that a remedial action must attain a degree of cleanup that satisfies ARARs under
federal and state laws, unless a waiver can be justified pursuant to CERCLA °121 (d)(4).
For the reasons discussed below, EPA has determined that the selected remedy meets the reguirements of CERCLA
°121.
Protection of Human Health and the Environment
The selected soil remedy protects human health and the environment by removing contaminated surface soils
(0-2 feet depth) for off-site disposal. In addition, borings 74 and 76 with PCB contamination down to 6 feet
depth, will also be excavated. Such excavation may also enable the NJDEP soil cleanup criteria to be achieved
through soil compliance averaging. All excavated soils will be disposed of off-site at an appropriate
disposal facility, depending on the characteristics of the soils.
The selected groundwater remedy will be protective of human health and the environment by controlling the
migration of contaminated groundwater through pumping and the removal of contaminants through treatment of
the pumped groundwater. This action will contain the highly contaminated groundwater on-site as well as
provide for removal of contaminants, through treatment.
Compliance with ARARs
As part of the selected remedy, contaminated soils will be excavated and disposed of off-site. There are no
chemical specific ARARs for soil. However, EPA and the State have promulgated guidances that while not
legally applicable, were considered by EPA in establishing cleanup levels for the Site. The selected soil
remedy will meet location - specific, and action-specific federal and State ARARs. Chemical-specific ARARs
include: the Clean Air Act of 1976 which governs emissions resulting from excavation and off-site disposal of
soils and Section 112 of the Clean Air Act which defines National Emissions Standards for Hazardous Air
Pollutants (NESHAPs) (See Table 12).
-------
Location-specific ARARs for the selected soil remedy include: Executive Order 11990 (Wetlands Protection);
the Wetlands Construction and Management Procedures (40 CFR, Appendix A); Executive Order 11988 (Floodplain
Management); and, the National Historic Preservation Act of 1966. Since a portion of the Site is classified
as wetlands, the soil remedy needs to comply with Section 404 of the Clean Water Act and federal Executive
Order 11990 which requires federal agencies to take actions to minimize the destruction, loss, or degradation
of wetlands and to preserve and enhance the natural and beneficial values of wetlands. Any actions which
disturb or impact wetlands would additionally require development of a wetland mitigation plan.
Action-specific ARARs for the soil remedy include: portions of the Resource Conservation and Recovery Act and
its implementing regulations, specifically those portions dealing with the transportation, storage and
disposal (including land disposal) of hazardous wastes and Department of Transportation requirements
governing the off-site transport of hazardous materials.
As far as the selected groundwater remedy, the major chemical-specific ARARS are the Safe Drinking Water Act
(SDWA) Maximum Contaminant Levels( MCLs) and the New Jersey Groundwater Quality Standards. For a given
contaminant, at the conclusion of the groundwater remedy, groundwater in the aquifer at the Site boundaries
should meet either the MCL or the Groundwater Quality Standard, whichever is more stringent (see Table 2).
However, it is possible that the selected groundwater remedy will not meet chemical-specific ARARS for the
organic contaminants in all groundwater beneath the Site. The water quality in the fractured bedrock aquifer
is not expected to be restored to below MCLs or background levels for at least several decades due to the
potential presence of DNAPLs. Any areas of contaminated groundwater which cannot be restored to meet State
and/or federal groundwater quality standards (see Table 2) would require a waiver of such standards on the
basis of technical impracticability. If after implementation of the remedy, it proves to be technically
impracticable to meet the ARARS in Table 2, EPA would waive such standards. Performance data from the
groundwater system would be used to determine the parameters and locations (both horizontally and vertically)
which require such a technical impracticability waiver. Extracted groundwater would be treated to meet
federal and State ARARS related to discharge of treated groundwater such as National Pollutant Discharge
Elimination System (NPDES) and New Jersey Pollutant Discharge Elimination System (NJPDES) requirements.
Location-specific ARARS, include for the selected groundwater remedy include: Executive Order 11990 (Wetlands
Protection); the Wetlands Construction and Management Procedures (40 CFR, Appendix A); Executive Order 11988
(Floodplain Management); and, the National Historic Preservation Act of 1966. Since a portion of the Site is
classified as wetlands, the groundwater remedy would comply with Section 404 of the Clean Water Act and
federal Executive Order 11990 which requires federal agencies to take actions to minimize the destruction,
loss, or degradation of wetlands and to preserve and enhance the natural and beneficial values of wetlands.
Any actions which disturb or impact wetlands would additionally require development of a wetland mitigation
plan.
Action-specific ARARS for the groundwater remedy include: portions of the Resource Conservation and Recovery
Act and its implementing regulations, specifically those portions dealing with the transportation, storage
and disposal (including land disposal) of hazardous wastes.
Cost Effectiveness
The selected soil remedy is cost-effective as it has been determined to provide the greatest overall
long-term and short-term effectiveness in proportion to its present worth cost, $5.6 million with no annual
operation and maintenance. Alternative S-4(A and B) would provide an equivalent level of protection, but at
almost twice the cost [$11.96 - $12.24] million. Alternative S-2A (Capping with Soil), is estimated to cost
$1.9 million, which is less than the selected remedy, but since contamination would be left on Site,
Alternative S-2A would not provide a high degree of long-term effectiveness.
The selected groundwater remedy is cost-effective as it has been determined to provide the greatest overall
long-term and short-term effectiveness. Even though the selected remedy, GW-5, has a higher O&M cost than
GW-1 and GW-2, the pumping of these additional groundwater extraction wells allows for more effective on-site
containment of the plume and also allows for groundwater extraction from other contaminated areas on-site.
-------
Utilization of Permanent Solutions and Alternative Treatment Technologies to the Maximum Extent Practicable
The selected soil and groundwater remedies represent the maximum extent to which permanent solutions, and
alternative treatment technologies can be utilized in a cost-effective manner for the Chemsol Site.
Furthermore, the selected remedies provide the best balance of tradeoffs with respect to the nine evaluation
criteria.
Preference for Treatment as a Principal Element
The selected groundwater remedy satisfies the statutory preference for treatment as a principal element. The
selected remedy utilizes treatment to reduce levels of contamination in groundwater to achieve ARARs, to the
extent practicable. The activated carbon in the extracted groundwater are either destroyed by catalytic
oxidation or are collected on liguid phase carbon which are later regenerated. Regeneration of the carbon
converts the organic contaminants to carbon dioxide, water and hydrochloric acid, thereby eliminating the
toxicity.
DOCUMENTATION OF SIGNIFICANT CHANGES
The Proposed Plan for the Site was released to the public in August 1997. This Plan identified Alternative
S-3 as the preferred alternative to address the soil contamination and Alternative GW-5 as the preferred
alternative to address the groundwater contamination at the Chemsol, Inc. Site. Upon review of all comments
submitted, EPA determined that no significant changes to the selected remedy, as it was presented in the
Proposed Plan, were necessary.
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APPENDIX I
FIGURES
APPENDIX II
TABLES
TABLE - 1
CONTAMINANTS IN SURFACE AND SUBSURFACE SOILS
Contaminants Concentrations Surface Soil Concentrations Subsurface Soil
(parts per billion) (parts per billion)
VOLATILE ORGANICS
Carbon Tetrachloride 0 - 5,000 680 - 1700
Trichloroethene 3,500 - 32,000 3 - 18,000
Tetrachlorothene 0 - 7,000 2 - 12,000
1,1,2,2, - Tetrachlorethane 15 - 110 49,000
Chlorobenzene 0 - 3,300 4 - 8,300
Xylene (Total) 56,000 - 110,000 2 - 40,000
Toluene 2 - 380,000 10 - 27,000
Ethybenzene 2,900 - 15,000 8 - 8,800
SEMI-VOLATILES
Bis(ethylhexyl)phthalate 0 - 63,000 66 - 17,000
Naphthalene 29 - 18,000 44 - 3,800
1,2,-Dichlorobenzene 200 - 1,600 34 - 10,000
PESTICIDES/PCB
Aldrin 58 - 8,300 0.3 - 2,000
Dieldrin 43 - 13,000 1.1 - 130
4,4-DDE 0 - 4,600 0.13 - 120
Toxaphene 0 - 3,400
PCBs 540 - 310,000 21 - 2,600
INORGANICS
Manganese 30.4 - 1,840 (parts per million) 282 - 2,300 (parts per million)
Lead 7 - 1,920 (parts per million) 2.4 - 914 (parts per million)
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TABLE - 2
CONTAMINANTS IN GROUNDWATER
Contaminants
VOLATILE ORGANICS
Carbon Tetrachloride
Trichloroethene
Tetrachloroethene
Chlorobenzene
Xylene (Total)
Toluene
Ethylbenzene
Vinyl Chloride
Benzene
2-Butanone
Chloroform
1,2-Dichloroethene
SEMI-VOLATILES
1,2-Dichlorobenzene
PCBS
INORGANICS
Manganese
Aluminum
Concentrations
(parts
2
0.9
1
4
1
2
11
3
1
270
1
0.5
2
6.1
63.9
per billion)
- 35,000
- 180,000
- 5,700
- 4,200
- 5,700
- 27,000
- 1,600
- 3,310
- 16,000
- 21,000
- 55,000
- 39,000
- 3,300
0-10
- 19,100
- 61,000
Federal
MCLs
(parts per
billion)
5
5
5
100
10
1,000
700
2
5
NA
80**
70 - 100***
600
0.5
50
50 - 200
State of New Jersey
Water Quality
Standards
(parts per billion)
2
1
1
4
44
1,000
700
2
1
NA
100*
10
600
0.5
50
50 - 200
NA - Not available for this constituent
* - MCL is for Trihalomethanes
** - Proposed
*** - [cis-70 ppb, trans-lOOppb]
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TABLE 3
SUMMARY OF CHEMICALS IN
SURFACE WATER
TABLE 4
SUMMARY OF CHEMICALS IN
SEDIMENT
TABLE 5
CHEMICALS OF POTENTIAL CONCERN
TABLE 6
POTENTIAL EXPOSURE PATHWAYS
TABLE 7
CARCINOGENIC TOXICITY VALUES
TABLE 8
HAZARD INDEX
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TABLE
CHEMSOL, INC SITE
TOXICITY ENDPOINTS/TARGET ORGANS FOR NONCARCINOGENIC CHEMICALS OF POTENTIAL CONCERN
QUANTITATIVELY EVALUATED IN THE RISK ASSESSMENT
MATRIX
Surface Soil:
(Lot 1A)
CHEMICALS
TOXICITY
ENDPOINT/TARGET
ORGAN*
Acetaldehyde (TIC)
Acetone
Acrotein
Carbon Tetrachloride
Chloroform
1,2-Dichlorethene (Total)
Trichloroethene
Manganese
EXPOSURE
ROUTE
Ingestion
Inhalation of
Particulates
Respiratory Tract
Liver, Kidney
Respiratory Tract
Liver
Liver
Liver
Liver, Kidney
Central Nervous System
RECEPTOR
Residents:
Children
Children
HAZARD INDEX
1.5
0.6
HAZARD INDEX BY
TOXICITY ENDPOINT/TARGET ORGAN
Manganese - 1.2
Manganese - 0.6
(Lot IB)
Ingestion
Residents:
Children
6.2
Manganese - 2.6
Inhalation of
Particulates
Children
0.9
Manganese - 0.91
Surface/Subsurface Soil:
(Effluent Discharge Line)
Ingestion
Inhalation of
Particulates
Residents:
Children
Children
3.7
1.5
Manganese - 3.1
Manganese - 1.5
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TABLE 8 (cont'd)
CHEMSOL, INC SITE
TOXICITY ENDPOINTS/TARGET ORGANS FOR NONCARCINOGENIC CHEMICALS OF POTENTIAL CONCERN
QUANTITATIVELY EVALUATED IN THE RISK ASSESSMENT
MATRIX
Ground Water:
(Site-Wide)
EXPOSURE
ROUTE
Ingestion
RECEPTOR HAZARD INDEX
Residents:
Adults
340
Ingestion
Children
800
Ingestion Site Workers/ 120
Employees
HAZARD INDEX BY
TOXICITY ENDPOINT/TARGET ORGAN
Acetone - 3.0
Carbon Tetrachloride - 130
Chloroform - 35
1,2 - Dichloroethene (Total)
Trichloroethene - 70
Manganese - 40
- 61
Acetone - 6.9
Carbon Tetrachloride - 310
Chloroform - 82
1,2-Dichloroethene (Total) - 140
Trichloroethene - 160
Manganese - 94
Acetone - 1.1
Carbon Tetrachloride - 48
Chloroform - 13
1,2-Dichloroethene (Total) - 22
Trichloroethene - 25
Manganese - 14
Ingestion Construction Workers 17
Carbon Tetrachloride - 4.4
Chloroform - 3.3
1,2-Dichloroethene (Total) - 5.7
Manganese - 3.7
*Sources: Integrated Risk Information System (IRIS) on-line September and November 1994 and January 1995, HEAST FY 1994 - Annual.
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TABLE 9
NONCARCINOGENIC TOXICITY VALUES
98141C4>
98141C5>
98141C6>
98141C7>
98141C8>
TABLE 10
SUMMARY OF COST ESTIMATES FOR SOIL ALTERNATIVES
ALTERNATIVE
TOTAL CAPITAL
COST
ANNUAL O&M
COST
TOTAL PRESENT
WORTH
No Action
1
$388,660
$0
$388,660
Capping
with soil 2A
with asphalt 2B
Off-Site Disposal
3
$1,855,850
$2,650,481
$5,573,001
On-site LTTD for PCBs
on-site solidification for Lead 4A $11,963,134
off-site disposal for Lead 4B $12,241,639
TABLE 11
SUMMARY OF COSTS ESTIMATES FOR GROUNDWATER ALTERNATIVES
$2,000
$175,000
$0
$0
$0
$1,894,000
$6,013,000
$5,573,000
$11,963,000
$12,242,000
ALTERNATIVE
No Action -1
TOTAL CAPITAL
COST
$0
ANNUAL O&M
COSTS
$59,336
TOTAL PRESENT
WORTH
$912,000
Continue, Existing Interim Action
Extract from C-1.21gpm
Discharge to POTW - 2A $45,097
Discharge to Stream - 2B $45,097
Extract from C-l, C-2, TW-4
TW-5, TW-8, DMW-9, 55 gpm
Discharge to POTW - 5A
Discharge to Stream - 5B
$390,189
$390,189
$452,738
$726,336
$670,892
$766,336
$7,000,300
$11,209,000
$10,699,000
$12,169,000
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TABLE 12
POTENTIAL ARARs/TBCs
Table 12-1
Potential Chemical Specific ARARs/TBCs
Feasibility Study For the Chemsol Inc. Site
Statute, Standard, Requirement, Criteria
Or Limitation
Federal
Soil:
Toxic Substances Control Act.
Toxic Substances Control Act
Toxic Substances Control Act
Toxic Substances Control Act
Resource Conservation and Recovery
and Recovery Act (RCRA)
Citation Or Reference
Description
Status
Comments
15 USC 2605
Requirements for PCB
Spill Cleanup (40 CFR
761.125)
Guidance on Remedial
Actions for Superfund
Sites with PCB
Contamination (OSWER
Directive 9355.4-01)
Revised interim Soil Lead
Guidance for CERCLA
Sites and RCRA
Corrective Action Facilities
(OSWER Directive
9355.4-12)
Hazardous Waste
Determination - Toxicity
Characteristic (40 CFR
261.24)
Applicable to storaqe and disposal of PCB
and pesticide contaminated material.
Applicable
Establishes PCB cleanup levels for soils and Applicable
solid surfaces.
Provides quidance on identifyinq principal
threat and low-threat areas of PCB
contamination. At industrial sites, PCBs at
concentrations of 500 ppm or qreater
qenerally pose a principal threat.
Recommends a screeninq level for lead of
400 ppm in soil for residential land use.
Applicable
Applicable
Establishes maximum concentrations of
contaminants for the toxicity characteristic
usinq the test method described in 40 CFR
261 Appendix II.
Applicable
Establishes requirements for soil
containinq > 50 ppm PCBs.
Applicable to spills of materials
containinq PCBs at concentrations of
50 ppm or qreater than occurred after
February 17, 1978. These
requirements my be relevant and
appropriate to the evaluation of PCB
levels in site soils.
Will be considered at Chemsol with
respect to soil PCB contamination.
Chemsol is expected to be developed
for residential use. This will be
considered to screen soil lead
contamination levels.
Applicable to the determination of
whether soils, if excavated, require
handlinq as a hazardous waste.
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Table 12-1
Potential Chemical Specific ARARs/TBCs
Feasibility Study For the Chemsol Inc. Site
Statute, Standard, Requirement, Criteria
Or Limitation
Federal
Air:
Clean Air Act.
National Primary and Secondary
Ambient Air Quality
Standards (NAAQS).
Citation Or Reference
Description
Status
Comments
42 USC 7401 Section 112
40 CFR 50
Establishes limits on pollutant emmissions to
atmosphere.
Establishes primary and secondary NAAQS
under Section 109 of the Clean Air Act.
National Emission Standards
for Hazardous Air Pollutants
(NESHAPS).
40 CFR 61
Establishes NESHAPs.
Applicable
Potentially
Applicable
Potentially
Applicable
Pollutants deemed hazardous or non-
hazardous based on public health.
Primary NAAQS define levels of air
quality necessary to protect public
health. Secondary NAAQS define
levels of air quality necessary to
protect the public welfare from any
known or anticipated adverse effects
of a pollutant. Applicable to remedial
action alternative(s) that may emit
pollutants to the atmosphere
Establishes NESHAPs for toxic
emissions.
Ground Water:
Safe Drinkinq Water Act
(SDWA) .
National Primary Drinkinq
Water Standards.
Pub. L. 95-523, as
amended by Pub. L.
96502, 22 USC 300 et.
seq.
40 CFR Part 141
Set limits to the maximum contaminant Applicable
levels (MCLs) and maximum contaminant
level qoals (MCLGs).
Applicable to the use of public water Applicable
systems; Establishes maximum contaminant
levels, monitorinq requirements and
treatment techniques.
The aquifer system has been
desiqnated as a drinkinq water aquifer
by the EPA.
Primary MCLs are legally
enforceable.
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Table 12-1
Potential Chemical Specific ARARs/TBCs
Feasibility Study For the Chemsol Inc. Site
Statute, Standard, Requirement, Criteria
Or Limitation
Federal
National Secondary
Drinking Water Standards.
Surface Water:
Clean Water Act (CWA).
Clean Water Act (CWA).
Clean Water Act (CWA).
RCRA:
Resource Conservation and
Recovery Act (RCRA) -
Identification and Listing of
Hazardous Waste.
Resource Conservation and
Recovery Act Maximum
Concentration Limits.
Citation Or Reference
40 CFR Part 143
Description Status
Comments
33 USC 1251 et.seg.
Ambient Water Quality
Criteria (AWQC) (40 CFR
131.36(b)(1))
Effluent Discharge
Limitations (40 CFR
401.15)
40 CFR Part 264.1
Applicable to the use of public water
system; Controls contaminants in drinking
water that primarily effect the aesthetic
qualities relating to public acceptance of
drinking water.
Applicable Secondary MCLs pertain to aesthetic
charateristics (taste, odor) and are
not legally enforceable.
40 CFR Part 264
Applicable for alternatives involving Potentially
treatment with point-source discharges to Applicable
surface water.
Non-enforceable guidelines established for
the protection of human health and/or
aquatic organisms.
Regulates the discharge of contaminants
from an industrial point source.
Defines those solid wastes which are subject Potentially
to regulations as hazardous wastes under 40 Applicable
CFR parts 262-265 and Parts 124, 270,
271.
Groundwater protection standards for toxic Potentially
metals and pesticides. Applicable
Criteria available for water and fish
ingestion, and fish consumption for
human health. State criteria are also
available.
AWQC will be applicable to remedial
alternatives which involve discharges
to surface water.
Regulations will be applicable to
remedial alternatives which involve
discharges to surface water.
May be considered an ARAR for
solids produced during groundwater
treatment.
These provisions are applicable to
RCRA regulated units that are subject
to permitting.
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Table 12-1
Potential Chemical Specific ARARs/TBCs
Feasibility Study For the Chemsol Inc. Site
Statute, Standard, Requirement, Criteria
Or Limitation
Federal
Land Disposal Restrictions
Pretreatment Standards.
Citation Or Reference
40 CFR 268
40 CFR 403
Description Status
Comments
Established maximum concentrations of
contaminants on the basis of which
hazardous wastes are restricted from land
disposal.
Potentially This regulation will be applicable to
Applicable remedial alternatives which utilize
land disposal of soils determined to
be a hazardous waste.
Establishes pretreatment standards to Potentially
control pollutants that pass through or Applicable
interfere with POTW treatment processes or
may contaminate sewage sludge.
Applicable to remedial action
alternative that includes discharge to
POTW or to a sewer system that is
connected to a POTW.
State
Soil
NJ Soil Cleanup Criteria
Groundwater
and Surface Water:
NJ Water Pollution Control Act
NJ Groundwater Quality Standards
NJ Surface Water Quality
Standards (NJAC 7:9B-
NJAC 7:9-Subchapter 6
Non-promulgated soil criteria developed
based on protection of human health or
ground water quality used for developing
site-specific cleanup levels.
TBC TBCs for the evaluation of soil
Applicable quality.
Established water quality standards for Applicable
various surface water classes.
Establishes constituent standards for Applicable
groundwater pollutants. It defines
numerical criteria for limits on discharges to
groundwater and standards for cleanups.
Potential ARARs due to classification
of Stream 1A near site as FW2-NT.
Will affect alternatives which include
discharges to the Stream 1A.
Potential ARARs for groundwater
alternatives.
Hazardous Waste Criteria, Identification
and Listing
NJAC 7:26-Subchapter 8
Defines those solid wastes that are subject Applicable
to regulation as hazardous waste
Applies to offsite disposal of material,
TCLP limits are applicable.
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Table 12-2
Potential Chemical Specific ARARs/TBCs
Feasibility Study For the Chemsol Inc. Site
Standard, Requirement, Criteria
Or Limitation
Federal
Citation Or Reference
Description
Status
Comments
Ground Water and
Surface Water:
Clean Air Act.
Section 404
Prohibits discharge of dredged or fill
material into wetlands without a permit.
Preserves and enhances wetlands.
Applicable Requires a permit for any
remedial activity that
proposes to discharge
dredged or fill material into
wetlands.
Regulations of Activities
Affecting Water of the U.S.
Standards for Owners and
Operators of Hazardous Waste
Treatment, Storage and
Disposal Facilities.
Fish And Wildfife:
Fish And Wildlife
Coordination Act.
Endangered Species Act.
33 CFR 320-329
40 CFR, Part 264.18
16 USC 661
16 USC 1531
Corps of Engineers, Department of the Applicable
Army regulations are codified in Title 33
(Navigation and Navigable Waters) of the
Code of Federal Regulations (33 CFR
Parts 200-399).
Part 264.18 establishes location standards Potentially
including seismic considerations and flood Applicable
plain requirements.
Provides procedures for consultation Potentially
between regulatory agencies to consider Applicable
wildlife conservation during water
resource-related projects.
Requires Federal agencies to ensure that Potentially
actions they authorize, fund or carry out Applicable
are not likely to jeopardize the continued
existence of endangered/threatened species
or adversely modify or destroy the critical
habitats of such species.
Applicable to remedial
activities that affect U.S.
waters subj ect to Army
Corps of Engineers
regulations.
May be applicable to
remedial activities affected
by seismic considerations
or remedial activities
conducted in flood plain
areas.
May be applicable to
remedial activities that may
affect fish and wildlife
resources.
Applicable to remedial
activities that may affect
endangered or threatened
species that may exist in
areas affected by the
remedial activity.
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Table 12-2
Potential Chemical Specific ARARs/TBCs
Feasibility Study For the Chemsol Inc. Site
Standard, Requirement, Criteria
Or Limitation
Federal
Citation Or Reference
Description
Status
Comments
Fish And Wildlife
Coordination Act.
Protection of Wildlife
Habitats
16 USC 661
Prevents the modification of a stream or a
river that affects fish or wildlife.
Potentially Potential ARAR if remedial
Applicable activities result in
modifications to the Stream
1A which affect fish or
wildlife.
Floodplain, Wetland,
Coastal Zone:
Executive Order On
Floodplain Management.
Wetland Executive Order.
Wetland Executive Order.
Other:
National Historic Preservation
Act (NHPA).
Executive Order No 11988
40 CFRs 6.302(b) and
Appendix A
Executive Order No. 11990
Protection of Wetlands
Wetlands Construction and
Management Procedures (40
CFR 6, Appendix Z)
7 CFR 650
Requires Federal agencies to evaluate the Potentially
potential effects of actions that may take Applicable
place in a floodplain to avoid the adverse
impacts associated with direct and indirect
development of a floodplain.
Regulates activities conducted in a wetland Potentially
area to minimize the destruction, loss or Applicable
degradation of the wetlands
Sets forth EPA policy for carrying out the Potentially
provisions of Executive Order 11900. Applicable
Regulates activities conducted in a wetland
area to minimize the destruction, loss or
degradation of the wetlands
Establishes regulations for determining a Applicable
site's eligibility for listing in the National
Registery of Historic Places.
Applicable to remedial
actions that affect wetland
areas.
Potential ARARs if a
remedial action is proposed
within a wetland area.
Potential ARARs if a
remedial action is proposed
within a wetland area.
Requires consideration of
remedial activity impact
upon any property included
in or eligible for inclusion
in The National Registry of
Historic Places.
-------
Requires actions to take into account
effects on properties included in or eligible
for the National Register of Historic Places
and minimizes harm to National Historic
Landmarks.
Potential ARAR if activities
impact areas identified as
having the potential for
cultural resources.
Wetlands:
NJ Freshwater Wetlands
Protection Act
Provides for classification of freshwater
wetlands and establishes permit
requirements for activities which impact
freshwater wetlands.
Potentially
Applicable
NJ Freshwater Wetlands
Regulations
Potentially
Applicable
Potential ARAR if a
remedial action is proposed
within a wetland area.
Historic Areas:
NJ Conservation Restriction and
Historic Preservation Restriction
Allows for the acquisition and enforcement
of conservation restrictions and historic
preservation restrictions by the NJDEP at
historic sites.
Potentially
Applicable
Potential ARAR if activities
impact areas identified as
having the potential for
cultural resources.
-------
Description
Hazardous and Solid Waste Amendments
of 1984 (HSWA)
Clean Air Act
Clean Air Act
Land Disposal Restrictions
National Ambient Air
Quality Standards
(NAAQS)-Particulates (40
CFR 50)
Emissions Standards for
Hazardous Air Pollutants
(NESHAPS) (40 CFR 61)
Prohibits placement of hazardous wastes
in locations of vulnerable hydrogeology
and lists certain wastes, which will be
evaluated for prohibition by EPA under
RCRA.
Potentially
Applicable
Potentially
Applicable
Potential ARARS which may limit the
use of land disposal in remediating
certain hazardous wastes.
Potentially
Applicable
Potentially
Applicable
Potentially
Applicable
Potentially
Applicable
-------
Description
Threshold Limit Values, American
Conference of Governmental
Industrial Hygienists.
Threshold Limit Value (TLVs) and
Biological Exposure Indices (BEIs) are
listed as guidelines to assist in the control
of health hazards.
TLVs and BEIs were not developed
for use as legal standards but may be
used as a basis for a health and safety
program during site remedial
activities.
Effluent Limitations.
Water Quality Standards And
Implementation Plans.
Toxic And Pretreatment Effluent
Standard.
NPDES Regulations,
May be applicable for treatment
alternatives including discharge to
surface water or POTW.
-------
Description
Guidance on Remedial Actions for
Contaminated Ground Water at
Superfund Sites, USEPA Office of
Emergency and Remedial Response.
RCRA:
Resource Conservation And
Recovery Act (RCRA)
Subtitle C - Hazardous Waste.
Applicable to the treatment, storage,
transportation and disposal of hazardous
waste and wastes listed under 40 CFR
Part 261.
Potentially
Applicable
Applicable for alternatives including
discharge to surface water or POTW.
Guidance for selecting remedial
alternative. Includes action related
considerations, such as overall
protection of human health and the
environment, and implementability.
40 CFR Part 264
RCRA Subtitle D
40 CFR Part 264
Potentially
Applicable
Applicable to alternatives involving land
disposal of hazardous wastes, and
reguires treatment to diminish a waste's
toxicity and /or minimize contaminant
migration.
Potentially
Applicable
Potentially
Applicable
-------
Federal
Transportation of Hazardous Wastes.
Description
Federal Highway Administration,
Department of Transportation, and
National Highway Traffic Safety
Administration regulations are codified in
Title 23 (Highways) of the Code of
Federal Regulations
(23 CFR Parts 1-1399)
Additional Transportation regulations are
codified in Title 49 (Transportation) of
the Code of Federal Regulations
(49 CFR Parts 1-1399)
Potentially
Applicable
Wetlands:
Wetland Permits.
Other:
National Historic Preservation
Act (NHPA).
Potentially
Applicable
Covers the basic permitting,
application, monitoring, and reporting
reguirements for off-site hazardous
waste management facilities.
Applicable to treatment options
involving excavation or dredging in
and around wetlands if discharge to
Stream 1A is chosen.
A federal agency must take into
account the effect of a project on any
property included in or eligible for
inclusion in the National Register of
Historic Places.
-------
Description
NJ Hazardous Waste Regulations
Potentially
Applicable
Requires the documentation and
maintenance of engineering or
institutional controls when such are used
in lieu of remediating a site; also
establishes a one in one million additional
cancer risk as a basis for residential and
non-residential soil remediation standards.
Potential ARARs for active
remediation alternatives and for
alternatives which involve the use of
institutional or engineering controls in
lieu of permanent remediation.
Pollutant Discharge
Elimination System
Permit/Discharge
Requirements (NJAC
7:14A-2.1)
NJ Water Pollution Control Act
Potentially
Applicable
NJ Water Pollution Control
Effluent
Standards/Treatment
requirements (NJAC 7.9B-
1.6)
-------
State
NJ Air Pollution Control Act
Description
Requires sources which emit VOCs be
registered and permitted with the NJDEP
and meet design specifications.
Potentially
Applicable
ARARs for alternatives involving
treatments which impact ambient air
(e.g., air stripping).
NJ Air Pollution Control Act
NJ Air Pollution Control Act
NJ Water Quality Planning Act (NJS
58:4A-14)
Well Drilling Permits and
Well Certification Forms
Requires NJDEP approval for drilling and
construction of new wells.
ARARs for alternatives involving
installation of monitoring wells.
Page 6 of
-------
APPENDIX III
ADMINISTRATIVE RECORD INDEX
Document Number: CHM-001-0001 To 0147 Date: 10/02/92
Title: (Letter forwarding the enclosed Project Operations Plan for Remedial Investigation/Feasibility Study
activities at the Chemsol, Inc. site)
Type: CORRESPONDENCE
Category: 3.1.0.0.0 Sampling and Analysis Plan (SAP)
Author: Goltz, Robert D.: COM Federal Programs Corporation
Recipient: Haklar, James: US EPA
Kollar, Keith: US EPA
Document Number: CHM-001-0148 To 0471 Date: 10/02/92
Title: Project Operations Plan for Remedial Investigation/Feasibility Study, Chemsot Inc. Site, Piscataway,
New Jersey, Appendices
Type: PLAN
Category: 3.1.0.0.0 Sampling and Analysis Plan (SAP)
Author: none: COM Federal Programs Corporation
Recipient: none: US EPA
Document Number: CHM-001-0472 To 0594 Date: 10/14/92
Title: Chemsol, Inc., Revised Health and Safety Plan, October 1992, Contractor QA/QC Sign Off
Type: PLAN
Category: 3.1.0.0.0 Sampling and Analysis Plan (SAP)
Author: Bilimoria, Maheyar: COM Federal Programs Corporation
Goltz, Robert D.: COM federal Program Corporation
Recipient: none: US EPA
Document Number: CHM-001-0595 To 0897 Date: 10/02/92
Title: (Letter forwarding the enclosed Volume 1 of the Final Remedial Investigation/Fessibitfty Study
Work Plan for the Chemsol, Inc., site)
Type: CORRESPONDENCE
Category: 3.3.0.0.0 Work Plan
Author: Goltz, Robert D.: COM Federal Program Corporation
Recipient: Maklar, James: US EPA
Kollar, Keith: US EPA
Document Number: CHM-001-0898 To 0903 Date: OS/12/92
Confidential
Title: (Letter announcing a September 2, 1992, public meeting for the Chemsol, Inc., site, with attached List
of addressees)
Type: CORRESPONDENCE
Category: 10.3.0.0.0 Public Notice(s)
-------
Author: Katz, Steven: US EPA
Recipient: various: resident
Attached: CHM-001-0918
Doc
ument Number: CHM-001-0904 To 0907 Date: 09/02/92
Title: Public Meeting, Chemsol Superfund Site, September 2, 1992, Sign-in Sheet
Type: OTHER
Category: 10.5.0.0.0 Documentation of Other Public Meetings
Author: various: various
Recipient: none: none
Attached: CHM-001-0908
Document Number: CHM-001-0908 To 0911 Parent: CHM-001-0904 Date: 08/02/92
Confidential
Title: Public Meeting, Chemsol, Superfund Site, September 2, 1992, Sign-in Sheet
Type: OTHER
Category: 10.5.0.0.0 Documentation of Other Public Meetings
Author: various: various
Recipient: none: none
Document Number: CHM-001-0912 To 0912 Date: 08/19/92
Title: (Newspaper article entitled:) EPA to present plan for contamination cleanup at Chemsol
Type: CORRESPONDENCE
Category: 10.6.0.0.0 Fact Sheets and Press Releases
Author: Glick, Andrea: Home News
Recipient: none: none
Document Number: CHM-001-0913 To 0914 Date: 08/30/92
Title: (Newspaper article entitled:) EPA targets tainted superfund site in Piscataway for extensive study
Type: CORRESPONDENCE
Category: 10.6.0.0.0 Fact Sheets and Press Release
Author: Melisurgo, Lenny: The Star Ledger
Recipient: none: none
Document Number: CHM-001-0915 To 0917 Date: 10/01/92
Title: Chemsol Inc., New Jersey, EPA Region 2, Congressional Dist. 12 Middlesex County, Piscataway
Type: OTHER
Category: 10.6.0.0.0 Fact Sheets and Press Releases
Author: none: none
Recipient: none: none
Document Number: CHM-001-0918 To 0923 Parent: CHM-001-0898 Date: OS/12/92
-------
Title: (Letter announcing a September 2, 1992, public meeting for the Chemsol, Inc., site, with attached list
of addresses)
Type: CORRESPONDENCE
Category: 10.3.0.0.0 Public Notice(s)
Author: Katz, Steven: US EPA
Recipient: various: resident
Document Number: CHM-001-0924 To 1471 Date: 10/01/96
Title: Remedial investigation Report, Chemsol Inc. Superfund Site, Volume 1
Type: REPORT
Category: 3.4.0.0.0 RI Reports
Author: none: COM Federal Programs Corporation
Recipient: none: US EPA
Document Number: CHM-001-1472 To 1531 Date: 10/01/96
Title: Remedial Investigation Report, Chemsol Inc. Superfund Site, Volume 1A
Type: REPORT
Category: 3.4.0.0.0 RI Reports
Author: none: COM Federal Programs Corporation
Recipient: none: US EPA
Document Number: CHM-001-1532 To 2023 Date: 10/01/96
Title: Remedial Investigation Report, Chemsol Inc. Superfund Site, Volume II
Type: REPORT
Category: 3.4.0.0.0 RI Reports
Author: none: COM Federal Programs Corporation
Recipient: none: US EPA
Document Number: CHM-001-2024 To 2348 Date: 10/01/96
Title: Remedial Investigation Report, Chemsol Inc. Superfund Site, Volume III
Type: REPORT
Category: 3.4.0.0.0 RI Reports
Author: none: COM Federal Programs Corporation
Recipient: none: US EPA
Document Number: CHM-001-2349 To 0399 Date: 10/01/96
Title: Remedial Investigation Report, Chemsol Inc. Superfund Site, Volume IV
Type: REPORT
Category: 3.4.0.0.0 RI Reports
Author: none: CHM Federal Program Corporation
Recipient: none: US EPA
-------
Document Number: CHM-002-0400 To 0947 Date: 10/01/96
Title: Remedial Investigation Report, Chemsol Inc. Superfund Site, Volume V
Type: REPORT
Category: 3.4.0.0.0 RI Reports
Author: none: COM Federal Programs Corporation
Recipient: none: US EPA
Document Number: CHM-002-0948 To 1373 Date: 10/01/96
Title: Remedial Investigation Report, Chemsol Inc. Superfund Site, Volume VI
Type: REPORT
Category: 3.4.0.0.0 RI Reports
Author: none: COM Federal Programs Corporation
Recipient: none: US EPA
Document Number: CHM-002-1374 To 1709 Date: 10/01/96
Title: Remedial Investigation Report, Chemsol Inc. Superfund Site, Volume VII
Type: REPORT
Category: 3.4.0.0.0 RI Reports
Author: none: COM Federal Programs Corporation
Recipient: none: US EPA
Document Number: CHM-002-1710 To 2084 Date: 10/01/96
Title: Remedial Investigation Report, Chemsol Inc. Superfund Site, Volume VIII
Type: REPORT
Category: 3.4.0.0.0 RI Reports
Author: none: COM Federal Programs Corporation
Recipient: none: US EPA
Document Number: CHM-002-2085 To 2484 Date: 10/01/96
Title: Remedial Investigation Report, Chemsol Inc. Superfumd Site, Volume IX
Type: REPORT
Category: 3.4.0.0.0 RI Reports
Author: none: COM Federal Programs Corporation
Recipient: none: US EPA
Document Number: CHM-002-2485 To 0581 Date: 10/01/96
Title: Remedial Investigation Report, Chemsol Inc. Superfund Site, Volume X
Type: REPORT
Category: 3.4.0.0.0 RI Reports
Author: none: COM Federal Programs Corporation
Recipient: none: US EPA
-------
Document Number: CHM-003-0582 To 0740 Date: 10/01/96
Title: Remedial Investigation Report, Chemsol Inc. Superfund Site, Volume XI
Type: REPORT
Category: 3.4.0.0.0 RI Reports
Author: none: COM Federal Programs Corporation
Recipient: none: US EPA
Document Number: CHM-003-0741 To 1439 Date: 10/01/96
Title: Remedial Investigation Report, Chemsol Inc. Superfund Site, Volume XII
Type: REPORT
Category: 3.4.0.0.0 RI Reports
Author: none: COM Federal Programs Corporation
Recipient: none: US EPA
Document Number: CHM-003-1440 To 1977 Date: 10/01/96
Title: Remedial Investigation Report, Chemsol Inc. Superfund Site, Volume XIII
Type: REPORT
Category: 3.4.0.0.0 RI Reports
Author: none: COM Federal Programs Corporation
Recipient: none: US EPA
Document Number: CHM-003-1978 To 2435 Date: 10/01/96
Title: Remedial Investigation Report, Chemsol Inc. Superfund Site, Volume XIV
Type: REPORT
Category: 3.4.0.0.0 RI Reports
Author: none: COM Federal Programs Corporation
Recipient: none: US EPA
Document Number: CHM-003-2436 To 0174 Date: 10/01/96
Title: Remedial Investigation Report, Chemsol Inc. Superfund Site, Volume XV
Type: REPORT
Category: 3.4.0.0.0 RI Reports
Author: none: COM Federal Programs Corporation
Recipient: none: US EPA
-------
CHEMSOL, INC. SUPERFUND SITE
OPERABLE UNIT ONE
ADMINISTRATIVE RECORD UPDATE
INDEX OF DOCUMENTS
3.0 REMEDIAL INVESTIGATION
3.3 Work Plans
P. 300001- Plan: Remedial Investigation and Feasibility Study
300386 Work Plan, Chemsol, Inc. Superfund Site,
Piscataway, Middlesex County, New Jersev, Volume 1
of 2, prepared by U.S. EPA, Region II, June 1992.
Plan: Project Operations Plan for Remedial Investigation/Feasibility Study, Chemsol, Inc. Site, Piscatawav,
New Jersey, Appendices, prepared by COM Federal Programs Corporation, prepared for U.S. EPA, Region II,
October 2, 1992. (This document can be found in the Chemsol, Inc. Superfund Site, Operable Unit One,
Administrative Record File, pages CHM-001-0148 to CHM-001-0471.)
Plan: Chemsol, Inc., Revised Health and Safety Plan, October 1992, Contractor OA/OC Sign Off, prepared by COM
Federal Programs Corporation, prepared for U.S. EPA, Region II, October 14, 1992. (This document can be found
in the Chemsol, Inc. Superfund Site, Operable Unit One, Administrative Record File, pages CHM-001-0472 to
CHM-001-0594.)
3.4 Remedial Investigation Reports
Report: Remedial Investigation Report, Chemsol, Inc. Superfund Site, Volumes 1 - 15, prepared by COM Federal
Programs Corporation, prepared for U.S. EPA, Region II, October 1, 1996. (This document can be found in the
Chemsol, Inc. Superfund Site, Operable Unit One, Administrative Record File, pages CHM-001-0924 to
CHM-004-0174.)
3.5 Correspondence
Letter to Mr. James Haklar and Mr. Keith Kollar, U.S. EPA, Region II, from Mr. Robert D. Goltz, COM Federal
Programs Corporation, re: Letter forwarding the enclosed Project Operations Plan for Remedial
Investigation/Feasibility Study activities at the Chemsol, Inc. site, October 2, 1992. (This document can be
found in the Chemsol, Inc. CHM-001-0147.)
4.0 FEASIBILITY STUDY
4.3 Feasibility Study Reports
P. 400001- Report: Feasibility Study Report, Chemsol, Inc,
400442 Superfund Site, Township of Piscataway, Middlesex
County, New Jersey, prepared by COM Federal
Programs Corporation, prepared for U.S. EPA,
Region II, June 24, 1997.
P. 400443- Affidavit (w/attachments) of Mr. Willard F Potter,
400465 Senior Project Director, de maximis, inc.,
Facility Coordinator, Chemsol, Inc. Superfund
Site, prepared for U.S. EPA, Region II, October
10, 1997.
4.4 Proposed Plans (SOP, FOP)
-------
P. 400466- Plan: Superfund Proposed Plan, Chemsol, Inc.
400486 Superfund Site, Piscataway, Middlesex County, New
Jersey, prepared by U.S. EPA Region II, August
1997.
4 . 6 Correspondence
P. 400487- Fax transmittal, to Mr. Nigel Robinson, U.S. EPA,
400487 Region II, from Mr. Gil Horwitz, BSM, NJDEP, re:
Geologist's comments to follow and if comments not
accepted, explain why or call to discuss with Dave
Barskey, December 3, 1996.
P. 400488- Letter to Mr. James Haklar, Project Manager, New
400489 Jersey Superfund Branch, U.S. EPA, Region II, from
Mr. Paul Harvey, Case Manager, Bureau of Federal
Case Management, NJDEP, re: Draft Feasibility
Study Report, Dated October 1996, Chemsol
Superfund Site, Piscataway Township, December 18,
1996.
5.0 RECORD OF DECISION
5.4 Correspondence
P. 500001- Letter to Ms. Carole Petersen, Chief, New Jersey
500002 Remediation Branch, U.S. EPA, Region II, from Mr.
Bruce Venner, Chief, Bureau of Federal Case
Management, NJDEP, re: Draft Record of Decision,
Chemsol Superfund Site, Piscataway Township, March
25, 1998.
P. 500003- Letter to Ms. Jeanne M. Fox, Regional
500003 Administrator, U.S. EPA, Region II, from Mr.
Richard J. Gimello, Assistant Commissioner, NJDEP,
re: Record of Decision, Non-Concurrence, Chemsol
Site, Piscataway Township, August 27, 1998.
8.0 HEALTH ASSESSMENTS
8.1 ATSDR Health Assessments
P. 800001- Report: Site Review And Undate, Chemsol,
800041 Incorporated, Piscataway, Middlesex County, New
Jersey, Cerclis No. NJD980528889, prepared by U.S.
Department of Health and Human Services, Agency
for Toxic Substances and Disease Registry,
(ATSDR), July 20, 1995, revised December 5, 1995.
10.0 PUBLIC PARTICIPATION
10.3 Public Notices
P. 10.0001- Notice: "The United States Environmental
10.0001 Protection Agency Announces An Extension Of The
Public Comment Period For The Chemsol, Inc.
-------
Superfund Site", prepared by U.S. EPA, Region II,
undated.
P. 10.0002- Letter to Interested Citizen, from Ms. Pat Seppi,
10.0002 Community Involvement Coordinator, U.S. EPA,
Region II, re: Announcement of a 30-day public
comment period beginning August 11, 1997, until
September 10, 1997 and public meeting to be held
Wednesday, August 27, 1997, for the Chemsol, Inc.
Superfund Site, Piscataway, New Jersey, August 11,
1997.
10.4 Public Meeting Transcripts
P. 10.0003- Chemsol, Inc. Superfund Site (1) Appendix - A,
10-0539 Public Meeting Transcript for The Proposed Plan
For Final Cleanup at the Chemsol, Inc. Superfund
Site in Piscataway, New Jersey, prepared by Fink &
Carney, Computerized Reporting Services, Certified
Stenotype Reporters, prepared for U.S. EPA, Region
II, August 27, 1997; (2) Appendix - B,
Responsiveness Summary - Written comments received
by EPA during the public comment period, Volume 1
of 2, October 10, 1997; (3) Appendix - B,
Responsiveness Summary - Written comments received
by EPA during the public comment period, Volume 2
of 2, October 10, 1997; (4) Appendix - C, Proposed
Plan, August 1997; (5) Appendix - D,
Responsiveness Summary - Public Notice Printed in
The Home News and Tribune on August 11, 1997.)
10.6 Fact Sheets and Press Releases
P. 10.0540- Fact Sheet: Chemsol, Inc. Superfund Site,
10.0542 Piscataway, New Jersey, U.S. EPA, Region II,
August 1997.
P. 10.0543- Press Release: EPA proposes cleanup plan for
10.0544 contaminated soil and groundwater at Chemsol
Federal Superfund Site in Piscataway, New Jersey,
prepared by U.S. EPA, Region II, Thursday, August
21, 1997.
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APPENDIX IV
STATE LETTER
State of New Jersey
Christine Todd Whitman Department of Environmental Protection Robert C. Shunn, Jr.
Governor Commissioner
MAR 25 1998
Carole Petersen, Chief
USEPA - Region II
New Jersey Remediation Branch
290 Broadway
New York, N.Y. 10007-1866
Dear Ms. Petersen:
Re: Draft Record of Decision, Chemsol Superfund Site, Piscataway Township
The Department of Environmental Protection has reviewed the draft ROD for the Chemsol site. As discussed
between Pam Lange and Lisa Jackson in a recent conference call, the Department does not anticipate concurring
with this ROD due to the issues outlined below.
1. The main issue is guite similar to the Renora Superfund site. The different PCB cleanup criteria of the
two agencies is the most significant problem. The Department cannot concur with the ROD unless it
specificially states that if the site is not remediated to the State's 0.49 ppm residential use criterium,
then a Declaration of Environmental Restriction (DER) must be established for the site.
2. Declaration for the Record of Decision. Statement of Basis - This section should state that the ROD is for
on-site ground water and that the off-site ground water is not fully delineated.
3. Declaration for the Record of Decision, Description of Selected Remedy, Ground Water, third bullet - This
statement is contradicted at Page 6, Paragraph 3 where it states that ground water is migrating off-site.
This third bullet should be modified to state that the extent of off-site contamination needs to be
determined.
4. Page 9, Paragraph 2 - The ROD should address whether the calculated risk meets the New Jersey standard of
one in a million.
5. Page 12, Remedial Action objectives, #2. - This statement is very confusing as written. Split into two
sentences and delete the "technical practicable" issue.
6. Page 13, last paragraph - This section should include the reguirement that a Classification Exception Area
(CEA) must be established for the Chemsol site and the full extent of ground water contamination.
7. Page 16, Option A - The ROD should state that a DER would be necessary for this scenario.
8. Page 17, Groundwater Alternatives Section A general statement should be included at the beginning of this
section which states that a CEA must be established for all of the ground water alternatives.
9. Page 22, First Paragraph under "Groundwater", Last sentence - A CEA would have to be established for the
on-site contamination concurrent with the remedy. An off-site CEA would be established once the extent of
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contamination is determined.
10. Page 28, Third Bullet under "Groundwater" - Same as number 3 above.
11. Page 30, Paragraph 2 - The last three sentences contain typos and incorrect structure.
12. Figure 1 - Does not include the town and county, address, scale, etc.
13. Responsiveness Summary - The Department has not received this document and therefore cannot provide
comments at this time.
As stated above, the Department does not anticipate concurring with the ROD unless all of our comments are
addressed. Should you wish to further discuss these issues, please contact me at (609) 633-1455.
c:
Paul Harvey, BFCM
John Prendergast, BEERA
Joe Marchesani, BGWPA
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APPENDIX V
RESPONSIVENESS SUMMARY
RESPONSIVENESS SUMMARY
CHEMSOL, INC. SUPERFUND SITE
PISCATAWAY, NEW JERSEY
As part of its public participation responsibilities, the U.S. Environmental Protection Agency (EPA) held a
public comment period from August 11 through October 10, 1997, for interested parties to comment on EPA's
Proposed Plan for the Chemsol Inc. Site ("the Site") in Piscataway, New Jersey. The Proposed Plan described
the alternatives that EPA considered for remediating contaminated soil and groundwater at the Site.
EPA held a public meeting at the Piscataway Municipal Complex on August 27, 1997. During the public meeting,
representatives from EPA discussed the preferred remedy, answered guestions, and received oral and written
comments on the alternative recommended in the Proposed Plan and other remedial alternatives under
consideration.
In addition to comments received during the public meeting, EPA received written comments throughout the
public comment period. EPA's responses to significant comments, both oral and written, received during the
public meeting and public comment period, are summarized in this Responsiveness Summary. All comments
summarized in this document were factored into EPA' s final determination of a remedy for cleaning up the
Site. EPA's selected remedy for the Site is described in the Decision Summary of the Record of Decision.
This Responsiveness Summary is divided into the following sections:
I. Overview: This section discusses EPA's preferred alternative for remedial action.
II. Background: This section briefly describes community relations activities for the Chemsol, Inc. Site.
III. Response to Written Comments from Potentially Responsible Parties: This section provides responses to
comments received from the Chemsol Site Potentially Responsible Parties (PRP) Group during the public comment
period. No other written comments were received.
IV. Public Meeting Comments and EPA's Responses: This section provides a summary of commenters' major issues
and concerns, and expressly acknowledges and responds to all significant comments raised at the August 27,
1997 public meeting.
V. Response to Written Comments: This section provides a summary of, and responses to, comments received in
writing during the public comment period.
Appendix A: Transcript of the August 27, 1997 public meeting.
Appendix B: Written comments received by EPA during the public comment period.
Appendix C: Proposed Plan
Appendix D: Public Notice printed in the August 11, 1997 Home News and Tribune
I. OVERVIEW
At the initiation of the public comment period on August 11, 1997, EPA presented its preferred alternatives
for the Chemsol, Inc. Site located in Piscataway, New Jersey. The preferred remedy for the contaminated soils
included the excavation and off-site disposal of approximately 18,500 cubic yards of contaminated soil, and
backfilling of the excavated areas with clean imported fill from an off-site location, followed by grass
seeding. The preferred remedy also included the installation, and pumping of additional extraction wells with
discharge to the existing treatment plant and an additional groundwater investigation to determine if
contaminated groundwater leaves the site, after implementation of the remedy. The preferred remedy is
identical to the remedy selected by EPA for this Site.
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II. BACKGROUND
The Remedial Investigation and Feasibility Study(RI/FS) and Proposed Plan for the Site were made available at
the information repositories for the Site: EPA Superfund Document Center at EPA's Region II office in New
York City, and at the Kennedy Library in Piscataway, New Jersey. The notice of availability for these
documents was published in the Home News and Tribune on August 11, 1997. The public was given the opportunity
to comment on the preferred alternative during the public comment period which began on August 11, 1997 and
concluded on October 10, 1997. In addition, a public meeting was held on August 27, 1997 at the Piscataway
Municipal Complex. At this meeting, representatives from EPA answered guestions concerning the Site and the
remedial alternatives under consideration. It should be noted that the public comment period originally was
to have ended on September 10, 1997. However, in response to a reguest made from the responsible parties, the
comment period was extended to October 10, 1997.
III. RESPONSES TO WRITTEN COMMENTS FROM THE RESPONSIBLE PARTIES
Please note that the comments provided by the Chemsol Site PRP Group include a brief summary comment followed
by a narrative which may extend to several pages. Only the summary comment has been provided below. For the
full comment, see Appendix B.
Note: For ease of reference, the comments are numbered to match those in the Chemsol Site PRP Group comments.
Section 1 of these comments consisted of an introduction which summarized the more detailed comments in
Sections 2 and 3.
COMMENTS REGARDING PROPOSED SOIL REMEDY
PRP Comment 2.1
The remedial action objective to allow for future site use without restrictions cannot be achieved by the
selected remedy.
PRP Comment 2.1.1
Because the proposed remedy would not achieve the state soil cleanup criteria, it cannot satisfy the remedial
action objective to allow for future site use without restrictions.
EPA's Response 2.1/2.1.1
EPA has examined the selected soil excavation contours in light of its cleanup levels and has determined that
the remedial action objectives can be met by the selected remedy. As stated in Section 2.4.2 on Page 2-9 of
the FS Report, by excavating all surface soils contaminated with PCB concentrations > 1 ppm and lead
concentrations > 400 ppm and isolated localized subsurface soils,contaminated with PCB concentrations > 1 ppm
and lead concentrations > 400) ppm. EPA believes that the selected remedy (Alternative S-3) may also comply
with the State of New Jersey's PCB soil cleanup criterion of 0.49 ppm through its soil compliance averaging
methodology .
There are no chemical specific ARARs for soil. However, the NJDEP has developed, but not promulgated
State-wide soil cleanup criteria. EPA does not consider these levels to be ARARs. EPA's cleanup criterion for
PCB contaminated soils is 1 ppm and the NJDEP's soil cleanup criterion is 0.49 ppm.
After this excavated soil is replaced with imported clean soil, according to EPA's risk assessment and PCB
guidance, there will be no unacceptable risks to human health through direct contact and therefore no use
restrictions will be reguired by EPA. As shown on revised Figure 2-2 of the FS Report, the subsurface soils
represented by soil borings SB-74 and SB-76 will also be excavated because they are contaminated with VOCs
and may serve as a continuing source of groundwater contamination. At soil boring SB-76, the VOC contaminated
subsurface soil also contains the highest concentration of PCBs (5.8 ppm) in the site subsurface soil. Hence,
removing these isolated localized "hot spots" may result in the State of New Jersey's PCB soil cleanup
criterion of 0.49 ppm to be met. If it is later determined the New Jersey 0.49 ppm criteria is not met,
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additional excavation can be performed by the PRPs or the State can pay for the added cost of excavation if
the remedy is funded under Superfund. If additional excavation is not performed, New Jersey will require that
some restriction be put on the property. The nature of the restriction will depend on the nature of the PCB
contamination above 0.49 ppm.
PRP Comment 2.1.2
If the remedial action objectives are revised to consider the State soil cleanup criterion, a new remedial
alternative analysis must be performed to comply with the NCP, as a remedial alternative which complies with
the State's soil cleanup criterion was not previously evaluated and is expected to result in significantly
greater costs and increased risk to human health and the environment. (The comment goes on to make several
assertions regarding the soil excavation volumes and costs associated with the State soil cleanup criterion
of 0.49 ppm for PCBs).
EPA's Response 2.1.2
As stated in the response to comment 2.1 and 2.1.1 above, there is no reason to revise the remedial action
objectives. The selected remedy (Alternative S-3)will comply with EPA's cleanup criterion of 1 ppm and based
on available data, may also meet the State of New Jersey's PCB soil cleanup criterion of 0.49 ppm. The costs
for Alternative S-3 which are shown on Table 4-6 in the FS Report include both scope and bid contingencies
and so there will be no significant greater costs. Table 5-2 of the FS report provides the sensitivity of the
cost estimates due to change in estimated volumes of contaminated soil. There will also be no need to conduct
a new remedial alternative analysis, because the one performed in the FS report is in full compliance with
the NCP.
Note that Superfund requires compliance with applicable or relevant and appropriate requirements (ARARs). EPA
does not agree that the NJDEP PCB cleanup criterion is an ARAR. EPA considered this a "to-be-considered"
requirement [(40 CFR 300.5) (SARA 122d(2c)] since it is not a promulgated standard. EPA has chosen to adopt
its own PCB cleanup level of 1 ppm, rather than the State's non-promulgated criterion.
PRP Comment 2.1.3
The selected soil remedy cannot satisfy the remedial action objective to allow
for future site use without restrictions based on the significant present and
anticipated future environmental and physical development constraints
located on the site.
EPA's Response 2.1.3
As stated in the response to comment 2.1.1, Section 2.4.2 on page 2-9 of the FS Report clearly recognizes
that certain portions of the property are being used and will be used in the future for groundwater
extraction, treatment, and discharge. The FS report also recognizes that groundwater in the fractured bedrock
aquifer underneath the Chemsol site is contaminated and is likely to remain contaminated for a long period of
time. In the context of the Superfund program, land use restrictions on a property are solely based on the
level of contamination above a specific contaminant concentration (the soil cleanup criteria or action levels
for PCBs and lead). The ability to develop or not develop a property based on considerations of total
available acreage or the presence or absence of wetlands is not applicable. Such "use restrictions" would be
present even if the property being considered for development were totally free of any chemical
contamination.
PRP Comment 2.2
The selection of the remedy is not supported by the administrative record.
PRP Comment 2.2.1
By requiring the soil be disposed as a hazardous waste, the Proposed Plan proposes a remedy not evaluated by
the FS, contrary to the requirements of the NCP.
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EPA's Response 2.2/2.2.1
The PRP Group may have misinterpreted the Proposed Plan. The Proposed Plan does not anticipate any soil to be
disposed of as hazardous waste. It merely states that disposal would take place at a licensed and approved
disposal facility. EPA believes that it is highly probable that most of the PCB contaminated soil could be
taken to a licensed Subtitle D facility for disposal. It is possible that isolated very small portions of
the PCB contaminated soil may have to be taken to a licensed Subtitle C or TSCA regulated facility for
disposal if the concentration is 50 ppm or greater.
Please note that samples collected for TCLP analysis during the RI were collected along a systematic grid
across the entire Lot IB of the site property and are as such considered to be representative samples for the
area to be excavated. It is therefore incorrect to state that the selected remedy (Alternative S-3) is not
supported by the administrative record or that it is contrary to the reguirements of the NCP. All samples
taken and analyzed for TCLP, passed the TCLP test.
PRP Comment 2.2.2
Should soil sampling during remedial design reveal a larger volume of soil reguiring excavation, the remedy
must be re-evaluated as selection would not be based on all relevant facts, information, and alternatives.
EPA's Response 2.2.2
Costs estimates in the Record of Decision are generally +50% - 30%. The specifics of the remedy (i.e., actual
amount of soil and area of excavation) are determined during the remedial design stage. If, during the
remedial design of the remedy, a larger volume of soil is reguired for excavation and differs significantly
from the remedy selected in the Record of Decision with respect to scope, performance, or costs, EPA may
reguire a re-evaluation of the remedial alternatives. This re-evaluation can be performed through an
Explanation of Significant Differences (BSD). ESDs are utilized to describe modifications to the remedy
chosen in the ROD due to site-specific conditions that may be discovered during remedial design. Based on the
Administrative Record, EPA believes that the remedy currently selected in this Record of Decision most
appropriately complies with the NCP criteria.
PRP Comment 2.2.3
Stockpiled soils meeting the criteria for backfill should not be reguired to be disposed of, but should be
permitted to be used as backfill.
EPA's Response 2.2.3
It is EPA' s understanding that soils presently stockpiled behind the groundwater treatment plant were put
there under protective cover, because they are either hazardous, contaminated, or do not meet the New Jersey
soil cleanup criteria. If additional future sampling performed during remedial design indicates that some
portions of these soils are not contaminated or hazardous and meet all of the New Jersey soil cleanup
criteria then they can be used as backfill.
PRP Comment 2.3
A selection of soil capping as the remedial alternative is supported by the administrative record.
EPA's Response 2.3
In selecting the preferred alternative, EPA evaluated all of the alternatives based on the nine criteria.
Especially important in the case of the capping alternative is the criterion regarding long-term
effectiveness and permanence. EPA did not select capping as the preferred remedy because soil contamination
above the soil cleanup criteria would be left in place indefinitely reguiring long term monitoring. In
addition, the capping alternative, does not meet the remedial objective for unrestricted use. The selected
soil remedy is cost-effective as it has been determined to provide greatest overall long-term and short-term
effectiveness in proportion to its present worth cost, $5.6 million with no annual operation and maintenance.
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Alternative S-4(A and B) would provide an equivalent level of protection, but at almost twice the cost
[$11.96 - $12.24] million. Alternative S-2A (Capping with Soil), is estimated to cost $1.9 million, which is
less than the selected remedy, but since contamination would be left on site, Alternative S-2A would not
provide a high degree of long-term effectiveness and would be more permanent.
PRP Comment 2.3.1
The Proposed Plan is not consistent with the EPA guidance on which soil cleanup levels were based;
consequently, the remedy selection should be reconsidered as these guidance documents recommend capping for
sites with contaminant concentrations at the levels present at the Chemsol site.
EPA's Response 2.3.1
EPA disagrees with this comment. EPA notes that its PCB guidance (Solid Waste and Emergency response,
Directive 9355.4-01 FS, August 1990) is currently being revised to reflect changes in how risks associated
with PCBs are calculated by EPA as well as recent changes in PCB regulations. EPA's Proposed Plan is
consistent with the goals and expectation for Superfund cleanups as outlined in the National Contingency
Plan, 40 CFR Part 300 (the "NCP"). Although the PCB guidance is being re-evaluated, EPA notes that its
selected remedy is entirely consistent with the guidance as currently written. EPA notes that, for a future
residential area, its PCB guidance recommends either on-site or off-site containment of soil with PCB
concentrations below 100 ppm. The comment seems to misinterpret the PCB guidance as saying that containment
should occur on-site. This is an incorrect interpretation of the guidance. EPA's PCB guidance does not
dictate on-site or off-site containment of PCB-contaminated waste. The decision-making process to determine
whether on-site or off-site containment is appropriate is part of the detailed analysis of alternatives as
outlined in the NCP. EPA's PCB guidance merely discusses some of the unique factors associated with response
actions at PCB-contaminated sites that might be considered under the detailed analysis of alternatives.
Therefore, EPA's selected remedy, excavation and off-site containment of PCB contaminated soils is entirely
consistent with the current PCB guidance and the NCP.
Cleanup standards are primarily selected based on site specific human health and ecological risk assessment.
The risk assessment showed that soils contaminated with PCBs greater than 1 ppm and lead greater than 400 ppm
posed unacceptable risks. Removing these PCBs and lead contaminated soils would also remove co-mingled VOCs,
thereby speeding up the groundwater cleanup. In addition, VOC contaminated soils would also be excavated from
deeper soils in selected areas such as in the areas around borings 74 and 76. While Guidances may be helpful
in making determinations as to the appropriate cleanup standards, they do not constitute rule making by the
Agency and the Agency may take action at variance with the guidance based on the facts and information for a
particular Superfund site. EPA believes that the soil clean up levels chosen are consistent with EPA's
guidance documents and EPA site specific risk assessment.
PRP Comment 2.3.2
The FS and Proposed Plan overestimate the costs of capping, resulting in an invalid cost comparison.
EPA's Response 2.3.2
EPA does not agree that it has overestimated the costs of capping resulting in an invalid costs comparison.
The physical properties of a soil required for the purposes of constructing an engineered cap are necessarily
different from those required for merely backfilling an excavation. Also, please note that the acreage of the
cap and the acreage of the area requiring excavation are different by design. The excavation contours have an
irregular shape and they have been designed to remove the bare minimum of soil that is contaminated above the
cleanup criteria defined for lead and PCBs in the FS and the Proposed Plan. The cap will be constructed using
a regular shaped area that completely covers the irregular shaped contaminated soil area and allows for
proper surface water infiltration and drainage. That is why the area to be capped is necessarily larger than
the area to be excavated.
Further, stockpiled soils have been dealt with in the FS and the Proposed Plan in the same consistent manner
in both the capping alternative (S-2A) and the preferred alternative (S-3), so that a proper unbiased
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comparison can be made between the various alternatives. EPA's cost comparison is fully valid and completely
consistent with relevant EPA guidance on costing of alternatives for a RI/FS and the NCP.
COMMENTS REGARDING PROPOSED GROUNDWATER REMEDY
PRP Comment 3.1
Geologic and contaminant-related factors dictate that a Technical Impracticability ARAR waiver should be
granted and the remedial action objective be revised accordingly to seek containment of the contaminated
groundwater.
EPA's Response 3.1
Please note that the remedial action objective in the Proposed Plan and FS Report clearly states that the
goal of the selected remedial action is to contain the contaminated groundwater (that which is above Federal
and State MCLs) from all depth zones and, as an element of this containment, reduce the mass of contaminants
to the maximum extent possible. The remedial action objective further states that another goal of the
selected remedial action is to augment the existing interim remedy as necessary, in order to achieve these
goals. The FS report also states that aguifer restoration is highly unlikely in this fractured bedrock,
precisely because it recognizes the potential existence of DNAPLs. The Proposed Plan also states that, if
after implementation of the remedy, it proves to be technically impracticable to meet groundwater guality
standards, EPA would seek waivers for such standards. Performance data from any groundwater system selected
for the Site would be used to determine the parameters and locations (both horizontally and vertically) which
may reguire a technical impracticability waiver. The goals of containing the most contaminated water to
prevent offsite migration and reducing the contaminant mass to the maximum extent possible are not
necessarily mutually exclusive. The interim remedy groundwater treatment plant is currently performing very
similar reduction in contaminamt mass as is envisioned for the selected remedy. The current interim remedy
groundwater extraction system, however, does not contain all of the contaminated groundwater across the site
from all depth zones and this has been clearly demonstrated by measurements made over the past several years
of operation. The decision to waive ARARs can only be made after a sufficient amount of performance data
from the selected groundwater extraction and treatment system becomes available. EPA does not believe that
sufficient data exist to support a technical impracticability ARAR waiver at this time.
PRP Comment 3.2
The remedial action objectives in the Proposed Plan must conform to those in the FS because the remedy
selection is based on the screening and evaluation of alternatives presented in the FS.
EPA's Response 3.2
The remedial action objectives stated in the FS Report and in the Proposed Plan are not different but rather
complementary. The purpose of the Proposed Plan is to supplement the RI/FS, briefly describe the remedial
alternatives analyzed by the agency, propose a preferred remedial action alternative, and summarize the
information relied upon to select the preferred alternative. The Proposed Plan gives notice to the public and
an opportunity for them to comment on the selected remedy.
With respect to the Chemsol Site, the Proposed Plan merely seeks to recognize that over time, there may some
portions of the aguifer that are unlikely to be technically practicable to restore. The Proposed Plan also
states that there may be other portions of the same fractured bedrock aguifer where the groundwater guality
does improve with time due to operation of the selected groundwater remedy, and therefore, such portions of
the aguifer could be restored to Federal and State drinking water standards. The determination of the
horizontal and vertical extent of the above referenced portions of the aguifer that can and cannot be
remediated is not possible based on all of the information gathered at present and will reguire further
offsite investigations.
PRP Comment 3.3
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The EPA uses a "preliminary" groundwater model in its remedy selection, resulting in misinterpretation of key
model parameters and, conseguently, a remedy selection process based on incomplete and, at times, inaccurate
information.
EPA's Response 3.3
The following responses are to the main points raised in this section. The discussion of conceptual and
numerical models in the RI and the FS reports clearly recognized the limitations of the models and the
existence of data gaps in the vast body of information gathered during the RI/FS. EPA has reviewed the
groundwater model submitted by Eckenfelder, Inc., the Chemsol Site PRP Group technical consultants. EPA
believes that this model is not necessarily any better and has many technical limitations and unresolved
problems of its own. In particular, the Chemsol PRP Site Group criticized the EPA's conceptual model as
mapping groundwater elevations based on depth below ground surface without regard to hydrostratigraphic
zones. Yet, the Eckenfelder numerical model uses horizontal layers that do not necessarily account for the
dipping stratigraphic layers. ( For a more complete discussion, see the separate technical review comments
prepared for EPA by CDM Federal Programs Corporation in Section 4 of this Responsiveness Summary.)
The FS model (CDM's DYNFLOW model which is a true 3-dimensional model that directly accounts for the dipping
stratigraphic layers) incorporated the major known features of the local groundwater system, both on site and
off site. It was reasonably well calibrated to two comprehensive water level data sets: one without recovery
pumping and one with recovery pumping at the site. By using these two comprehensive water level data sets,
EPA believes that the model results are reliable. It is appropriate, however, that a more refined model may
be developed prior to final design. The conceptual model incorporated into the FS numerical model is very
similar to the conceptual model presented by Eckenfelder Inc. The FS model explicitly represents a system of
dipping stratigraphic aguifer units as described by Eckenfelder, including a seguence of relatively
conductive layers separated by relatively low permeability layers (e.g. the gray shale marker beds) which
provide some hydraulic confinement to the aguifer units. One difference between the conceptual models is that
the FS model explicitly includes a "deep conductive zone" identified for a portion of the interval between
the gray shale marker units, while the Eckenfelder conceptual model represents the interval between the gray
shale marker layers as a single "Principal Aguifer" layer.
The PRP Group also objected to EPA's inclusion of the car wash well in its groundwater model. EPA decided to
include the car wash well after observing its operations during groundwater sampling at off-site locations.
The interval between the gray shale units ("Principal Aguifer") was represented in the FS model by a lower
conductivity "Red Shale" property set above and below a "Deep Conductive" layer of limited thickness. The
composite hydraulic conductivity for the interval is actually somewhat less than that assigned to the
"Principal Aguifer" by Eckenfelder. The "Regional Shale" aguifer property set, which has a horizontal
hydraulic conductivity of 25 feet/day in the strike direction, was not used for the interval between the gray
shale units in the FS model. The FS model was reasonably well calibrated to site conditions both with and
without recovery pumping in long term operation. A comprehensive set of site water level data was available
and used for comparison with model simulated results for each case.
It was, indeed, incorrect to state in the FS Report that DYNFLOW is "certified" by the International Ground
Water Modeling Center (IGWMC). However, the DYNFLOW and DYNTRACK codes have been reviewed and tested by the
IGWMC at the reguest of USEPA. Subseguent to this review the codes were adopted for use on a particular site
by USEPA. Since that time, DYNFLOW and DYNTRACK have been used on a number of USEPA Superfund sites. EPA's
consultant would be willing to make DYNFLOW and DYNTRACK available free of charge to the Chemsol Site PRP
Group for use on this study. Similar arrangements have been made in the past. Generally, the codes are
available for sale to consulting organizations and others; a number of consulting companies have purchased
DYNFLOW and DYNTRACK in the past few years.
PRP Comment 3.4
The capture zones should be defined by a refined, calibrated groundwater model.
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EPA's Response 3.4
The competing effects of the "car wash well" and Site groundwater extraction wells clearly have a significant
influence on the capture zones. The FS model allowed for offsite pumping from the "car wash well." EPA agrees
that the FS model should be further refined and calibrated during remedial design. However, the current
Eckenfelder model is not the refined and calibrated model that both EPA and the PRP Group are seeking. The
Eckenfelder model has significant problems with the way boundary conditions have been defined and the
recharge rates used in the model are much lower than other studies from the same area of New Jersey. No
guantitative justification was provided for those lower recharge rates.
PRP Comment 3.5
Off-site delineation sampling should be limited o the area down gradient of the Site, as defined by the
refined groundwater model.
EPA's Response 3.5
Please note that the observed gradients in various stratigraphic zones at the Chemsol site are relatively
flat and they can be strongly influenced by offsite pumping. Hence, defining the area "down gradient" of the
site is difficult and can vary with time. Definition of such "down gradient" areas is better performed
through actual offsite investigation measurements than by relying on a groundwater model alone. Naturally
defined "down gradient" areas can only be determined in an idealized imaginary situation where there are no
external pumping sources that alter and sometimes reverse gradients.
PRP Comment 3.6
The final remedy must consider the significant constraints on the groundwater treatment plant discharge.
EPA's Response 3.6
The total flow rates defined in the existing interim remedy permit for discharge to the MCUA sewer system and
the NJDEP surface water discharge permit eguivalent are based on the March 1994 Final Remedial Design Report.
These total flow rates are not absolute numbers that can be considered to be valid constraints. The designed
capacity of the existing groundwater treatment plant is 50 gpm. EPA reguired the construction of both
discharge pipelines (to the MCUA and to Stream 1A) in 1994, because EPA always anticipated that MCUA could
decide in future to stop accepting discharges of partially treated groundwater from Superfund sites. Stream
1A clearly has more than sufficient flow capacity to accept rates defined in the selected remedy. The
extraction system has to be designed to achieve capture of all of the contaminated groundwater from all depth
zones and to achieve the remedial action objectives. The selected remedial extraction system for Alternative
GW-5 in the FS Report was designed to capture groundwater from the most contaminated wells based on two
rounds of sampling conducted during the RI.
PRP Comment 3.7
The reguirement to operate the biological treatment plant if the groundwater treatment plant discharges to
surface water has no technical basis.
EPA's Response 3.7
It is incorrect to state that the options in the selected groundwater remedy have no technical basis. The
construction of the biological treatment plant was based on the March 1994 Final Remedial Design Report. This
design was recommended to EPA by the Chemsol Site PRP Group based on the findings of the treatability studies
performed in 1992 by consultants chosen by the PRP Group's Design Engineer. The selected remedy is based on
the existing treatment system which in turn is based on the above referenced design. It is also irrelevant to
state that a supplemental food source would have to be added to establish adeguate biofilm growth. EPA's
guarterly and semi-annual inspections of the existing treatment plant have observed that biofouling of the
air stripper packing material occurs regularly and that freguent backwashing of the pressure filtration media
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is required due to accumulation of biosolids in the filter cake. In fact regular preventive in measures are
implemented by Bigler Associates (current plant operator) to destroy this biofilm that is very persistent.
Biofilm growth in the existing treatment system as operating currently is well documented in the Chemsol Site
PRP Group's reports to EPA. If the treatment plant can achieve surface water discharge standards defined by
NJDEP, without operating the biological treatment system, then such data should be provided to EPA for
evaluation. A limited amount of data has been presented to show that the effluent may be able meet toxicity
requirements of the surface water discharge permit. However, no data has been provided to explain how other
permit parameters such as phosphorus and total dissolved solids would be satisfied.
PRP Comment 3.8
A refined, calibrated groundwater model should be used to develop any long-term monitoring program.
EPA's Response 3.8
As stated in the response to previous comments, EPA expects that the FS groundwater model will be further
refined and calibrated with more investigative data collected during remedial design. The sampling
requirements stated in the Proposed Plan are completely consistent, relevant, and necessary to evaluate and
monitor performance of the selected remedy. They can not be eliminated.
EPA'S RESPONSE TO POTENTIALLY RESPONSIBLE PARTIES' COMMENTS REGARDING THE RI REPORT
EPA examined Eckenfelder's Technical Review of the Chemsol Site Remedial Investigation (RI) Report.
Eckenfelder has presented a revised conceptual hydrogeologic model of the Chemsol Site, based on their review
of the RI Report and additional review of previous data. They clearly state in Section 1 of the Monitoring
Report 1 that because of the complexity of the site, additional revision may be required as additional data
are obtained. This is an entirely reasonable stipulation. Furthermore, in Section 1 of the Technical Review
they state that the document is "..intended to facilitate a technical dialog between the USEPA and the
Chemsol Site PRP Group (Group) regarding the issues related to site remediation." This is another commendable
and entirely reasonable idea.
The EPA and Eckenfelder conceptual hydrogeologic models of the Site are not identical, but they share a
number of common ideas. Just as Eckenfelder has observed that additional revision of the model may be
appropriate, there are some aspects of the EPA model that might be reconsidered.
Eckenfelder's primary criticism of the RI Report relates to the grouping of monitoring wells. In Section 2.1
of the Technical Review, Eckenfelder concurs with several conclusions EPA made regarding behavior of the
aquifer based on observations from the packer testing program, but then states that EPA ignored their own
observations and grouped monitoring wells strictly on the basis of elevation. It is true that elevation was
considered as an important aspect of the well grouping, but it was not the only one. Stratigraphic
relationships and hydraulic connections were considered as well by EPA.
It is possible that Eckenfelder's criticism is based at least in part on a misinterpretation of the RI
Report. On page 2-2 of the Technical Review, they cite RI Figure 3-23 as an example of EPA grouping wells in
separate hydrostratigraphic units. It is true that water elevations observed in wells above and below the
gray shale are plotted on a single map. However, it is clearly shown on the figure and explicitly stated in
the text of the report that the water levels were not contoured together, and were not to be considered
representative of a single hydraulic zone.
What is not apparent is the rationale for Eckenfelder's statement that the zone represented by the TW-series
wells above the gray shale is an aquitard, and therefore not appropriate for mapping of horizontal hydraulic
gradients. There is no doubt that this zone has lower hydraulic conductivity than the highly fractured zone
immediately above the gray shale and some relatively highly fractured zones observed in the zone between the
upper and lower gray shales. It does not necessarily follow, however, that the zone deserves classification
as an aquitard. EPA is not aware of any evidence that the conductivity of this zone is significantly lower
than what might be called "average" Brunswick Shale. Furthermore, the zone certainly has a horizontal
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component of flow. If Eckenfelder believes that the magnitude of that component is small enough to be
ignored, they should support that position with data.
Eckenfelder points out in Section 3 of the Technical Review that vertical head losses indicate that there are
zones of moderate to low vertical conductivity. There is a reasonable vertical head loss between some of the
TW-series wells and the C-series wells immediately above the shallow gray shale. Specifically, significant
vertical head differences (several feet) are observed at the TW10/C-7 and TW-ll/C-6 clusters. However, the
vertical head differences at the TW-3/C-8, TW4/C-10 and TW-2/C-9 clusters are on the order of only a few
tenths of a foot. Classification of the zone as an aquitard on the basis of vertical head loss, therefore,
does not seem justified.
The argument that the TW-series wells above the gray shale should not be considered as part of the aquifer
because they are within the upper, presumably weathered rock zone could also be applied to the TW-series
wells below the gray shale, which Eckenfelder has grouped in the primary aquifer. As noted above, some of
the TW-series have heads several feet higher than wells completed at the same location but in deeper
intervals. The August 29, 1994 pre-pumping water elevations in wells TW-7, TW-14 and TW-15 are in the same
range (about 62 feet above sea level), but there are no deeper wells similar to the C-series for evaluation
of vertical head loss.
No wells open to zones monitored by the TW-series wells above the gray shale were pumped during the EPA
packer testing program, or during any of the previous groundwater investigations. Therefore, the hydraulic
properties of this zone can only be estimated. Eckenfelder used the Neuman-Witherspoon method to estimate
vertical hydraulic conductivity for both the unit they call the principal aquifer (between the upper and
lower gray shales) and the upper bedrock (the zone monitored by the TW-series wells above the upper gray
shale, identified as an aquitard). The K v of the principal aquifer calculated was 3.5 x 10 -4 cm/sec. Two
values were calculated for the upper bedrock zone. At the C-8/TW-3 cluster, the K v was 1.1 x 10 -4 cm/sec,
and at the C10/TW-4 cluster, K v was 6.5 x 10 -5 cm/sec. It is noted that these values are lower than the one
estimate for the principal aquifer, but not much lower.
Eckenfelder has defined the thickness of the upper permeable aquifer (the zone monitored by the C-series
wells above the upper gray shale) as 40 feet. They do not provide any rationale for selecting this thickness.
Based on EPA observations, a thickness of 15 to perhaps 20 feet for this zone is more realistic. Using EPA's
observed thickness of the highly permeable zone, the thickness of the upper bedrock in the vicinity of the
C-8/TW-3 and C10/TW-4 clusters is 100 feet and 90 feet, respectively.
It is reasonable to assume that horizontal hydraulic conductivity (K) is at least 10 times K v. In their
previous submissions, Eckenfelder estimated that K was as much as 33 times K v, . If a 10-fold difference is
assumed, and units are converted from cm/sec to gpd/ft 2, the estimated values of K at the clusters discussed
above are 23 gpd/ft 2 and 14 gpd ft 2, respectively. Multiplying these values for K by the respective
thicknesses, transmissivity (T) values at the cluster locations of 2,300 gpd/ft and 1,260 gpd/ft, can be
estimated. Compared with estimates of T for other zones presented in Table 3-1 of the Technical Review
(>5,000 gpd/ft to 29,000 gpd/ft), it is obvious that these values are lower. However, they are within a
range that is generally observed in moderately productive aquifers.
Based on the above discussion, the Chemsol PRP group must make the following modifications in classifying the
hydrostratigraphic units at the Chemsol Site;
! Overburden Zone (OZ) - This unit is the shallowest water-bearing unit at the site. It is composed of
the thin unconsolidated soils and the weathered bedrock. It is monitored by all the OW-series wells
(and perhaps the shallow PZ-series piezometers). The zone has been defined in this manner in both the
RI and the Eckenfelder Technical Review. Groundwater flow is generally north to northeasterly, and the
zone likely interacts with shallow surface water.
! Upper Bedrock Zone (UBA) - The UBA stratigraphically overlies the upper gray shale. At the site, the
UBA thickens down dip (to the northwest) from a feather edge to nearly 200 feet. The shallowest part
of the UBA may have some weathered, low permeability areas, and is likely influenced by local surface
features. A highly fractured sub-unit (UBFZ) exists within the UBZ, immediately above the shallow gray
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shale. The UBFZ contains some of the most productive zones observed during the packer testing program.
Wells monitoring the shallow part of the UBA include TW-1, TW-2, TW-3, TW-4, TW-5, TW-5A, TW-10, TW-11 and
TW-12. Wells monitoring the UBFZ include C-6, C-7, C-8, C-9 and C-10. It should be noted that TW-11 and TW-12
are included in the UBA on the basis of stratigraphic position only.
Pre-pumping hydraulic gradients in the UBA suggested generally southerly flow from the northern site boundary
to the vicinity of well TW-4, where discharge to the UBFZ may be occurring. The pre-pumping hydraulic
gradient in the UHPZ is not well defined. It was generally northerly on the August 29, 1994 measurement, but,
as shown in the RI report, significant fluctuations were observed in the C-series wells, which were
considered likely indications of external pumping influences.
! Shallow Gray Shale Aquitard (SGSA) - This approximately 15-foot zone apparently acts primarily as an
aguitard. The packer testing program did note some hydraulic communication across the shallow gray
shale, but in most cases the communication could be correlated with open bore holes across the shale
unit. Three of the TW-series wells (TW-6, TW-8 and TW-14) completely or partially straddle the shallow
gray shale within the general area in which the unit subcrops. It is likely that the topographic
position (i.e. shallowest water zone at their location) is more important than stratigraphic position
of these wells. However, as discussed below, these wells will be grouped with the underlying zone.
! Upper Principal Aguifer (UPA) - This zone includes the upper 100 feet of shale stratigraphically below
the SGSA. The 100-foot limit is essentially an arbitrary boundary applied for mapping purposes.
Wells included in the UPA are: TW-6, TW-7, TW-8, TW-9, TW-13, TW-14, TW-15, C-3, C-4, C-5, DMW-9 and DMW-10.
As noted above, three of the TW-series wells completed within the SGSA Well TW-6 showed far greater hydraulic
response during packer tests pumping from below the SGSA than above. Therefore, it is grouped with the UPA
wells. Wells TW-14 and TW-15 are included primarily on the basis of stratigraphic position. The extent of
hydraulic connection between these wells and the main part of the Site is not known. It should be noted that
since they are shallow wells, are completed in potentially weathered rock, are located some distance from the
Site, are separated from the Site by a railroad right-of-way with associated drainage ditches and other
structures, there is a distinct possibility that heads measured in the wells are not directly related to
heads measured in other wells in the group. Figure 4-4 of Eckenfelder's Technical Review of the RI report
shows the August 29, 1994 water elevations in the UPA. If wells TW-14 and TW-15 were not included on the map,
the overall magnitude of the northerly gradient would drop from about 0.003 to less than 0.001. Eckenfelder's
conclusion that pre-pumping flow was northerly must be used with caution. It was apparently northerly on
August 29, 1994, but it would not have reguired much off-site influence to significantly change the direction
of the hydraulic gradient.
! Intermediate Principal Aguifer (IPA) - This zone is similar to Eckenfelder's proposed Lower Principal
Aguifer. Eckenfelder proposed a well grouping for mapping purposes to include the portion of the
principal aguifer below approximately a 100-foot stratigraphic thickness, but above the lower gray
shale). The packer testing program did not show any significant hydraulic barrier at the lower gray
shale, with the possible exception of the off-site influences noted at wells DMW-1 and DMW-2. Because
of the lack of evidence for a significant barrier, grouping based on position relative to the shale
seems unnecessarily arbitrary. By using the shale, Eckenfelder has placed both wells at the DMW-5
/DMW-6 cluster above the shale and both wells at the DMW-3/DMW-4 cluster below it. It seems more
appropriate to recognize depth, and separate wells in cluster locations.
The IPA includes wells DMW-1, DMW-3, DMW-5, DMW-7, DMW-11, C-2 and MW-104. The August 29, 1994 gradient in
this set of wells was northerly, at low magnitude.
! Deep Principal Aguifer(DPA) - This is the bedrock zone primarily below the lower gray shale. As
discussed above, it seems more appropriate to move MW-104 and DMW-3 to the Intermediate group, based
on the lack of an identifiable hydraulic barrier and grouping wells of approximate egual elevation.
For the same reasons, MW-103 and DMW-6 are included in the DPA. The DPA includes, therefore, wells
MW-103, DMW-6, DMW-8, MW-101, DMW-2, MW-102 and DMW-4.
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Eckenfelder did not plot a contour map for the deep group. The August 29, 1994 data plotted for the DPA wells
show a very flat gradient, generally to the southeast.
There is one additional unexplained item in the effectiveness Monitoring Report. Eckenfelder did not use the
elevation for well C-4 on the contour maps of the UFA for January 2 and February 6, 1997. A note on the maps
states that the elevations were anomalous compared with the historic data. The "anomalous" values were 56.65
and 58.01 feet, respectively. Considering that recorded elevations for well C-4 vary, Eckenfelder plotted and
used the 60.16 feet elevation measured on March 12, 1997. Considering that the August 29, 1994 elevation for
well C-4 was 58.2 feet, and the previously reported values vary from less than 53 to greater than 60 feet,
the classification of the January and February 1997 values as anomalous must be explained.
EPA'S RESPONSE TO TECHNICAL COMMENTS ON POTENTIALLY RESPONSIBLE PARTIES' EVALUATION OF GROUNDWATER EXTRACTION
ALTERNATIVES
KEY ISSUES
Model Boundary Conditions
The description of model boundary conditions provided in Appendix A does not present a clear and consistent
relationship between the model boundary conditions and field conditions.
It is difficult to understand how a river boundary condition was appropriately applied to all of the model
layers at the northwestern boundary which corresponds (in plan) with Bound Brook. At Bound Brook, the
stratigraphic units represented in the model would have dipped hundreds of feet below the river. River
boundary parameters were not provided in the Appendix.
The General Head boundary condition parameter values applied at the northeast and southwest model boundaries
were not documented. An explanation of how these values were derived is also needed.
Insufficient justification was provided for applying a uniform rate of inflow at the upper model boundary.
Downdip, there might be flow out of the stratigraphic unit represented by the top model layer to the
overlying shale. If the top model layer was intended to represent the overlying shale to the northwest as
well as the "Upper Aquitard" unit described at the Site, then the increase in thickness of this layer to the
northwest (downdip) must be accounted for.
No justification was provided for specifying a no-flow boundary condition at the bottom of the model. Near
the subcrop to the southeast, there may be leakage into or out of the aguifer unit represented by the bottom
model layer.
Recharge
Previous model studies in the area have used recharge rates of 8.2 inches/year (Brown, 1994) and 6
inches/year (CDM, 1996). The model being reviewed uses a much lower recharge rate of 2 inches/year at subcrop
areas. It is assumed that most of the surface recharge is diverted by the overburden, which is not included
in the model, before reaching the shale. More detailed, quantitative justification for the greatly reduced
recharge rate must be provided. This is important because the simulated capture zone achieved for a given
rate of pumping will be very sensitive to the recharge rate applied.
Calibration
Appendix A did not present detailed calibration of the model to conditions with long term continuous site
pumping. Since the model is being used to predict the effects of such pumping, a detailed calibration should
be presented for conditions both with and without recovery pumping operational.
SPECIFIC COMMENTS
Page Comment
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A2-I The "Deep Conductive Zone" identified by CDM is not explicitly included in the conceptual
stratigraphy or the model. Some model detail is lost by lumping this unit within a more general "Principal
Aguifer".
Table A2-I Well DMW-3 is listed for both the lower Principal Aguifer and Deep Bedrock.
A2-2 The "Upper Bedrock Aguitard" may not merit the "aguitard" designation. The vertical hydraulic
conductivity of 0.2 to 0.3 feet/day ascribed to this unit is not so different from that ascribed to the
"Principal Aguifer" of 1 foot/day. Similarly, the model horizontal hydraulic conductivities are not so
different, 2.5 versus 9.4 feet/day.
A2-4 There appear to be as many data points for the Deep Bedrock as for other stratigraphic units. Is
the reason that no flow direction was determined that no consistent gradient is indicated by the data?
A3-2 Representing dipping hydrostratigraphic beds as horizontal grid layers can lead to complications
for establishing boundary conditions as described previously.
Fig. A3-2 No scale is provided. It would be helpful to know the width of the subcrops.
A3-3 The statement "Although layer thickness is not centered into the model directly, transmissivity
was used to represent the pinching out of Layer 1 on site." needs clarification. Based on Table A3-2, it
appears that a constant hydraulic conductivity (not transmissivity) was specified for this layer.
A3-3 What is the basis for assigning "river" boundary conditions at Bound Brook? The model layers dip
well below the stream.
A3-3 The General Head boundary condition parameters should be documented, with more explanation of how
they were derived.
A3-4 CDM concluded from the base flow analysis that the most reasonable range of recharge was from 6
to 7.5 inches/year, not 4 to 7.5 inches/year.
A3-4 More justification and guantification is needed to support the statement that "The effective
recharge to the bedrock units will be considerably less than the estimated 4 to 7.5 inches per year."
A3-4 If the "car wash" well is operating, or might be operating in the future, this may have a
significant effect on the capture zone of site recovery wells. It would be helpful if evidence that it is not
operating be provided in more detail.
A3-5 A MODFLOW type 3 aguifer is confined/unconfined, not confined as indicated for layer 1. Which
representation was used?
A3-5 For layer 2, it should probably state that a transmissivity (not hydraulic conductivity) of 1,690
sguare feet per day was used for the initial run. Elsewhere on pages A3-S and A3-6, the units of
transmissivity should be expressed as sguare feet per day. Based on Table A3-2, layer 2 was probably
represented as a type 0 (confined) aguifer, not type 3.
A3-5 For layers 3, 4 and 5, MODFLOW aguifer type 0 is a confined aguifer, not type 3.
A3-6 The initial leakance value of 0.0001/day selected for the Gray Shale units seems very low. Since
these units are 10 to 20 feet thick, this leakance corresponds to a vertical hydraulic conductivity of 0.001
to 0.002 feet/day. For comparison, it was previously stated that the Upper Aguitard vertical conductivity was
estimated from pumping test data to be 0.2 to 0.3 feet/day, or 2 orders of magnitude higher.
A3-7 References to April 29, 1994 should be changed to August 29, 1994.
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A3-7 As discussed above, a more detailed model calibration to conditions with recovery pumping
operating should be documented. Comparison of simulated and measured response at a comprehensive set of site
monitoring wells should be provided. Comparing model results to target head contours developed from a few
data points is not sufficient. In particular, the drawdown cone indicated by the target head contours shown
in Figure A3-6 appears to be defined entirely by an estimated head at the pumping well, C-l.
Table A3-1 Water level measurements for a number of the wells shown in Table A2-2 are not included in
Table A3-1. No explanation is provided.
Table A3-2 The leakance value of 0.001/day shown for the Upper Aguitard seems low. For a thickness of 20 to
40 feet, this corresponds to a vertical hydraulic conductivity of 0.02 to 0.04 feet/day, compared with a
previous estimate based on pumping test data of 0.2 to 0.3 feet/day. This should be explained.
Table A3-2 The leakance values shown for the Upper and Lower Gray Shale units, 0.000014/day and 0.00065/day,
are also very low. Selection of these values should be explained.
Table A3-2 As discussed previously, the basis for selecting a recharge rate of 2 inches/year for subcrop
areas needs to be guantified. Similarly, the use of a constant inflow rate to the top layer of the model
needs to be explained.
Fig. A3-8 Simulated response in the Upper Aguitard and Upper Permeable units are indicated in the legend,
but are not graphed.
A3-8 It should be stated how the pumping flux for well C-l is distributed among model layers.
A3-9 Although recharge is shown to be a sensitive model parameter, for many models, it is possible to
maintain a satisfactory calibration when adjustments are made to recharge together with adjustments to
boundary conditions and/or hydraulic properties.
A4-2 It should be indicated to which model layers fluxes are assigned to represent pumping from well
C-l. It is implied that it pumps from the Principal Aguifer only. In fact, well C-l probably pumps from the
Upper Permeable Aguifer also.
A4-3 The model's ability to represent long-term pumping from well C-l was not thoroughly demonstrated
in the model documentation.
A4-3 It is not clear how the model uncertainty of plus or minus 30 percent was arrived at.
IV. PUBLIC MEETING COMMENTS AND EPA'S RESPONSES
Questions or comments are summarized in bold, followed by EPA's response.
1. Several members of the audience expressed their preference for the State of New Jersey cleanup
guideline of 0.49 ppm instead of EPA's level of 1 ppm for PCBs in soil.
EPA's Response: There are no chemical-specific ARARs for soil. However, the State has developed State-wide
soil cleanup criteria that while not promulgated, were considered by EPA in developing cleanup levels for the
Site. Based on EPA's guidance, EPA has selected a PCB cleanup level of 1 ppm for soils at the Chemsol Site.
The NJDEP's cleanup criterion for PCB contaminated soil in residential areas is 0.49 ppm; it is not legally
applicable and EPA believes that a PCB cleanup level of 1 ppm is protective of human health and the
environment.
With the implementation of Alternative S-3, the levels of PCBs remaining in the soil after excavation will
not exceed 1 ppm. However, EPA intends on excavating additional soils from three hot spots; these excavations
may go as deep as six feet, down to bedrock. With the excavation of these hot spots and by using NJDEPs soil
compliance averaging methodology, EPA believes it will achieve the State of New Jersey cleanup guideline of
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0.49 ppm.
2. State Assemblyman Smith asked if the responsible parties have stepped up to the plate, and if so, have
they been acting in accord with the Superfund Law.
EPA's Response: The responsible parties had spent approximately $10 million on the current interim remedy to
date. They have designed, constructed and are currently operating and maintaining the on-site treatment
system. At the meeting, EPA also indicated that the responsible parties are complying with the Superfund Law.
3. Assemblyman Smith asked if there is any reason to believe that the responsible parties would not
implement EPA's recommended alternatives, estimated at $18 million.
EPA's Response: EPA indicated that the responsible parties have indicated that they are willing to negotiate
with EPA the implementation of the Record of Decision.
4. Assemblyman Smith and Mike Beson, representing Congressman Pallone, asked if the 22 potentially active
groundwater wells within a half mile radius of the site were tested for contamination. They also asked EPA to
re-sample the wells.
EPA's Response: Approximately 5 years ago, EPA offered to sample residential wells. Some of the residents
agreed, and EPA sampled their wells. Others did not want their wells to be sampled. EPA is willing to sample
all wells within the half mile radius of the Site. EPA will coordinate this effort with the Piscataway Health
Department.
5. Assemblyman Smith followed up by making reference to Page 19 of the Proposed Plan, "The State of New
Jersey cannot concur on the preferred remedy unless its site direct contact criteria are met or institutional
controls are established to prevent direct contact with soils above direct contact criteria." He wanted to
know the status of the State of New Jersey's response to EPA's cleanup.
Response: Mr. Paul Harvey from the State of New Jersey indicated that they have commented on the Proposed
Plan, and the State prefers its 0.49 ppm cleanup criterion for PCBs in unrestricted use areas.
6. The guestion was asked, if it was a part of EPA's plan to activate the biological treatment plant and
discharge the treated water directly to Stream 1A.
EPA's Response: It may eventually happen. Currently, EPA prefers Option A, which calls for discharge of
treated groundwater to the Middlesex County Utilities Authority (MCUA). However, the responsible parties are
not sure how much longer they will be allowed to discharge the treated groundwater to MCUA. In the event that
MCUA stops accepting discharge from the treatment plan, the biological process would be activated. The
treated groundwater from the treatment plant would undergo additional treatment (biological treatment) that
would enable direct discharge to Stream 1A.
7. Members of the audience indicated that EPA and the responsible parties should do everything in their
power to make sure that MCUA continues to accept the treated groundwater so there would be no discharge to
the stream.
EPA's Response: No response necessary.
8. The guestion was asked about the logistics of trucking 18,000 cubic yards of soil and the risk of
contaminated soil becoming airborne or spilling onto the street.
EPA's Response: Soil excavation is a relatively standard procedure in the construction industry and that
there are standard practices that address the issues such as possible airborne dust and spillage. Health and
safety issues would be addressed in the remedial design report. When the treatment plant was being built,
monitoring was done to determine the level of dust in the air, especially when trucks travel back and forth
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on Fleming Street. If the dust levels were too high, work would cease or some form of standard dust
suppression measures would be implemented.
9. A member of the audience indicated that the magnitude of soil to be excavated will be higher than
during the construction of the treatment plant and was concerned especially with the close proximity of
apartment buildings adjacent to the site.
EPA's Response: EPA has been involved in several site constructions, especially in the summer when the
weather is dry. EPA has done monitoring at these sites and has been successful in implementing dust
suppression measures, and can implement the same measures at this site.
10. Will incineration of the contaminated soil at the Site cause any air pollution problem?
EPA's Response: EPA did not choose that alternative. At the meeting, EPA indicated that the alternative was
not incineration but low temperature thermal desorption and that such a system would be eguipped with the
necessary devices to eliminate or minimize the release of dust and other pollution to the air.
11. A home owner asked what can parents expect of children, now adults who twenty years ago played on
mounds of dirt and materials at the site, and rode their bicycles freely throughout the site. What is the
potential of them coming down with cancer, and what kind of cancer?
EPA's Response: This guestion came up at a past public meeting. At that time, EPA indicated that, it was
impossible to guantify the risk for exposures so long ago. Based on its studies, EPA can say what the current
and future risks are for people going on-site (including children) and if the site is not remediated a year,
two years or three years from now. Unfortunately, EPA cannot say what the risks were back in the 1960's and
1970's.
12. EPA was asked to translate the unacceptable total risk of 2.2 X 10 -3.
EPA's Response: This means that there would be an additional two people in a thousand who can be expected, if
they were exposed to the site on a regular basis over a 70 year period, to come down with cancer based on the
current exposure at the site.
13. Has the EPA ever considered conducting a door to door survey to find out how many people in the
neighborhood have died of cancer?
EPA's Response: EPA does not do that type of work. Congress in the last Superfund Law authorized an agency
that is part of the Centers for Disease Control, the Agency for Toxic Substances and Disease Registry
(ATSDR), to perform such a health evaluation. EPA indicated that it would be willing to put the resident in
touch with one of the biological scientists from the ATSDR. EPA held a conference call on September 26, 1997
with ATSDR to hear the citizen's concerns. During the conference call, the Superfund and health assessment
processes were explained to the citizen in detail. A copy of the health assessment that was prepared by ATSDR
was forwarded to the concerned citizen.
14. A resident indicated that from what she has seen at the site, only the plant seems to fenced in.
EPA's Response: This is not true. Areas other than the plant are fenced. Lot IB, the area where industrial
activities occurred, has been fenced for at least five years.
15. The individual followed up the guestion, asking if that's where most of the contaminants were found.
EPA's Response: The majority of the contamination was found in Lot IB.
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16. A resident made reference to the statement on page 17 of the Proposed Plan regarding EPA bypassing the
residential areas (Fleming Street) when trucking out the excavated soil and asked where EPA would locate such
a road.
EPA's Response: EPA indicated the proposed road location on a map to the audience. The proposed road will be
located in the southeast portion of the site, next to the Port Reading Railroad Line. EPA was then urged to
work with the Mayor's Office in ironing out details if such a temporaiy road had to be built. EPA indicated
that it would cooperate with the local authorities to ensure that the community is impacted as little as
possible during construction activities.
17. The statement was made by the Councilman that the responsible parties should absorb the cost for
sampling the local residential wells and for hooking up such residents to the city water system as necessary.
EPA's Response: EPA will perform additional sampling of local residential wells to see what impact the Site
has had since EPA's last sampling activities. EPA will ask the Potentially Responsible Parties (PRPs) to
either perform the sampling activities, or to pay the cost if EPA performs them.
18. A member of the audience asked to be provided with a list of the Safe Drinking Water Act MCLs for the
contaminants listed on page 6 and 7 that were found in surface and subsurface soils and groundwater.
EPA's Response: This information is available in Table 1-12 of the feasibility study report which is
available in the repository, located at the Kennedy, Library, 500 Hoes Lane, Piscataway, NJ.
19. With the high level of removal of organic contaminants, as indicated in the data, is there a reason why
the sewer authority would not let you continue to pump basically potable water to the sewer.
EPA's Response: The Middlesex County Utilities Authority (MCUA) is authorized to make the determination as to
what material it will accept. At times, there are concerns on the part of the sewer authority on how much
capacity they have to handle Superfund waste. EPA cannot comment on the sewer authority's decision making
process in this matter.
20. EPA was asked if the 50 gallons per minute of groundwater that the treatment plant would be handling
was excessive and if it was a case of the sewer authority not being able to handle it.
EPA's Response: EPA has no reason to believe that the sewer authority cannot handle the increased flow from
the selected remedy.
21. Are soils contaminated with PCBs at the same location (hot spots) with other contamination?
EPA's Response: Yes, they are co-located.
22. If the soils were to be excavated, is there a possibility that volatiles may enter the air while the
soil is being placed in the truck?
EPA's Response: Such a possibility does exist. However, EPA will take all precautions to ensure that the
public is not exposed to any hazardous materials during construction.
23. Will trucks transporting the excavated soils be completely sealed to eliminate VOCs emission from the
soil or will only a tarp be placed over the trucks?
EPA's Response: No decision has yet been made, but as the excavation proceeds, there will be procedures to
monitor dust and organic emissions and contingencies to address any such elevated levels. The main
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suppression methods used in the past have been water and/or use of a tarp to cover the vehicle.
24. In trucking the material off-site, will EPA just be disposing of the material or will it be treated?
EPA's Response: EPA does not expect that treatment will be necessary prior to off-site disposal. PCBs are
present at the Site in concentrations as high as 310 parts per million. Under the Toxic Substances Control
Act (TSCA) law, soil contaminated with these levels can be disposed of at landfills without any treatment.
For other contaminants found in the soil, all contaminants; are at levels that would not reguire any
treatment pursuant to Resource Conservation and Recovery Act (RCRA) reguirements. EPA also performed Toxicity
Characteristic Leaching Procedure (TCLP) tests to determine if the contaminated soils could be disposed at a
RCRA landfill. The samples tested passed the TCLP tests which indicates that the Site soils can be disposed
at a RCRA landfill without prior treatment.
25. An individual concerned with sedimentary toxicity, asked if an ecological risk assessment was
performed.
EPA's Response: An ecological risk assessment was performed. It involved a gualitative and/or
semi-guantitative appraisal of the actual or potential effect of a hazardous waste site on plants and
animals. A four-step process is utilized for assessing site-related ecological risks: Problem Formulation - a
gualitative evaluation of contaminants release, migration, and fate; identification of contaminants of
concern, receptors, exposure pathways, and known ecological effects of the contaminants; and selection of
endpoints for further study. Exposure Assessment - a guantitative evaluation of contaminant release,
migration and fate; characterization of exposure pathways and receptors; and measurement or estimation of
exposure point concentrations. Ecological Effect Assessment - literature reviews, field studies, and toxicity
tests, linking contaminant concentration to effects on ecological receptors. Risk Characterization -
measurement or estimation of both current and future adverse effects.
26. As a follow-up, the individual asked if there are heavy metals in the sediment and if so, would a
release of 50 gallons per minute of treated groundwater to the streams increase the toxicity of the stream by
stirring up the contaminants in the sediments.
EPA's Response: The contamination is primarily in Stream IB which is an intermittent
ditch and does not have flow at certain times of the year. The treated groundwater would
be released to Stream 1A, not to Stream IB, and therefore would not be stirring up
contaminated sediments.
27. A individual asked if EPA would be excavating Lot IB, or both Lot IB and 1A.
EPA's Response: It was indicated that most of the soil to be excavated will come from Lot IB, but that some
soils from Lot 1A will also be excavated.
28. The guestion was followed up as to at what depth would excavation take place.
EPA's Response: The depth of excavation varies from area based on testing performed in the remedial
investigation. For some areas, EPA will excavate to two feet, others, four feet and six feet.
29. The guestion was asked if six feet was the deepest depth EPA was planning to excavate.
EPA Response: That is correct based on data available at this time.
30. The same individual asked how soon after excavation could houses be built, or would one have to wait 30
years for the groundwater remedy to be completed.
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EPA's Response: One would not have to wait 30 years for the groundwater to be cleaned up before houses could
be built at the Site. Upon excavation of the contaminated soils followed by backfilling with clean fill,
houses could be built. However, the NJDEP may reguire some deed restrictions on the Site if its PCB cleanup
criterion of 0.49 ppm is not achieved.
31. Follow-up guestion. With the allotted time being 30 years, would it take that time to be deleted from
the NPL or could it be deleted before 30 years.
EPA's Response: The 30 year timeframe mentioned in the Proposed Plan for groundwater pump and treat may not
be an accurate estimate of how long it will take to clean up the site. The 30 year timeframe is used for
costing purposes only. It is very difficult, if not impossible, to predict exactly how long it will take to
clean-up the groundwater at the site. The Site cannot be deleted from the National Priorities List (NPL)
until no further groundwater response is appropriate. Due to the complex nature of the fractured bedrock
found at the Site, contaminants get trapped in spaces and are very difficult to remove. EPA intends to pump
as much water, very aggressively into the treatment plant to remove the contaminants, and to minimize the
potential for the contaminants from leaving the facility boundaries.
32. The same individual was interested in knowing if after performing the five year review and the
groundwater has been cleaned up, would the site be ready for houses?
EPA's Response: The Site could be used for building houses before the groundwater is cleaned up, providing it
does not interfere with the remediation and no potable wells are installed or utilized. However, as mentioned
earlier, EPA's cleanup criteria for soils contaminated with PCBs is 1 ppm and the NJDEP's cleanup criteria is
0.49 ppm. So even though the soils will achieve EPA's cleanup criteria, the State of New Jersey may restrict
some uses of the Site if its cleanup criteria are not achieved.
33. The same individual asked how deep is the groundwater and soil contamination.
EPA's Response: Based on current data, the groundwater contamination goes down several hundred feet and the
soil contamination goes as deep as 6 feet.
34. The guestioner was interested in determining the risk if houses were built at the site since excavation
would only go as deep as six feet and in certain area the soil contamination is as deep as ten feet, possibly
leaving some contaminated soils on-site.
EPA's Response: Based on EPA's risk assessment, soils below two feet at the Site do not pose any cancer or
non-cancer threats associated with residential use. However, there is a small pocket of soil around borings
74 and 76 with levels of VOCs that are higher than the remaining subsurface soils. This area, if not removed,
will continue to be a source for future groundwater contamination. Based on EPA's proposed remedy, this area
of contamination would be excavated down to six feet, where the contamination exists, then disposed of
off-site. Therefore, the subsurface soils would not pose any risk to future development of houses at the
Site.
35. An individual was interested in knowing where Streams 1A and IB go after leaving the site.
EPA's Response: EPA indicated that both streams flow to New Market Pond, which ultimately flows into the
Bound Brook. The Bound Brook eventually flows into Raritan River.
36. The individual followed up her guestion asking if EPA intends to do off-site testing of the streams to
be sure that contamination has not left the site.
EPA's Response: Elevated levels of PCBs were detected in portions of the streams. It is not clear if the PCB
concentration in the stream sediments represent actual source areas of contamination or indicate the presence
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of a migration pathway for contaminants from the more heavily contaminated Lot IB. In addition, ecological
risks associated with PCBs are minimal. Therefore, remediation of the streams is not warranted at this time.
Rather, monitoring is reguired to determine whether remediation of Lot IB results in a lowering of PCB levels
in the streams in Lot LA.
37. The guestion was asked, since a railroad track exists next to the track, EPA should consider disposing
of the excavated soils by rail.
EPA's Response: EPA evaluated this option, and though 18,000 cubic yards of soil seems like a large volume of
soil, it is often guicker and more economical to transport the soil by truck than by rail.
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Chemsol,Inc. Superfund Site
Appendix - A
Transcript of the August 27, 1997 Public Meeting
1
2 UNITED STATES ENVIORNMENTAL PROTECTION AGENCY
3 _____________________x
PUBLIC MEETING
4 FOR THE PROPOSED PLAN FOR FINAL CLEANUP
AT THE CHEMSOL, INC. SUPERFUND SITE IN :
5 PISCATAWAY, NEW JERSEY
------------------X
6
7
Municipal Building
8 455 Hoes Lane
Piscataway, New Jersey
9
August 27, 1997
10 7:15: o'clock p.m.
11
12 Before:
13 PAT SEPPI,
Community Relations Coordinator
14
NIGEL ROBINSON
15 Project Manager
16 LISA JACKSON,
Chief of Central New Jersey Superfund
17 Section.
18 JIM HACKLER,
Previous Project Manager
19
20
21
22
23
24
25
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2 PROCEEDINGS
3 MS. SEPPI: I would like to
4 thank everybody for coming out tonight
5 to this public meeting for the Proposed
6 Plan for Final Cleanup at the Chemsol
7 Superfund Site in Piscataway, New
8 Jersey.
9 I am Pat Seppi, Community
10 Relations Coordinator with the EPA,
11 Region 2, in New York City. I would
12 like to introduce the people that will
13 be giving short presentations tonight.
14 Nigel Robinson is EPA Project
15 Manager for the Chemsol site.
16 Jim Hackler is the old project
17 manager for the Chemsol site and we have
18 asked him to come tonight and Lisa
19 Jackson is the Chief of the Central New
20 Jersey Superfund Section.
21 Also Paul Harvey from the NJ
22 Department of Environmental Protection
23 is here and also Meyhear Billimoria is
24 here and if anybody has guestions for
25 them they will be happy to answer them,
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2 I am sure.
3 If you did not already, please
4 sign in. That is the way we make sure
5 you are on our mailing list for updates
6 or documents that we may want to send
7 out to you. The reason we are here is
8 to present EPA"s proposed plan. We have
9 done a lot of studies, a lot of
10 investigations and this is our plan that
11 addresses the best way we found to clean
12 up the contaminated soil and water.
13 Nigel will go into more detail
14 about the other alternatives we have
15 looked at during the presentation. It
16 is important to us that the public is
17 well aware and understand what it is we
18 are trying to do. That is why we have
19 the public meeting and 30-day public
20 comment period.
21 Most of you probably received a
22 copy of the proposed plan in the mail.
23 If you did not there are copies in the
24 back and copies of the fact sheet that
25 went out with the proposed plan. The
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2 public comment period started August
3 llth and extends until September 10th.
4 That is our typical 30-day public
5 comment period. If you have any written
6 comments after you leave here tonight or
7 know anybody who has a comment please
8 have them send it to Nigel so that it is
9 in the proposed plan.
10 You will notice we have a court
11 stenographer. The transcript from this
12 meeting along with any other comments we
13 receive in the mail will be part of the
14 permanent record and will be addressed
15 in what is called a responsiveness
16 summary, which is attached to our final
17 decision document, which is called the
18 Record of Decision.
19 Lisa will explain a little bit
20 more about that when she talks about the
21 Superfund proposals. One of the other
22 thing I wanted to mention was we have
23 received from the public a reguest to
24 extend the comment period an extra 30
25 days and we have granted that reguest.
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2 Instead of the comment period being over
3 on September 10th it will be over at the
4 close of business on October llth.
5 We usually do that if someone
6 requests an extension. We try to
7 accommodate them as much as possible.
8 As I mentioned before there are a lot of
9 documents that relate to Chemsol. You
10 will find the documents in the
11 repository that is right down the street
12 in the library. You are certainly
13 welcome to go look at those at any time.
14 We have tried to leave the bulk
15 of the time for you for your guestions
16 and answers. As soon as we are finished
17 we will open the floor for guestions and
18 answers. The Mayor of Piscataway is
19 here. Camille Fernicola is here;
20 Assemblyman Bob Smith, who has been very
21 interested in this site and what is
22 going on; two gentlemen Jim Stewart from
23 Ward 4 and Brian Wahler from Ward 2.
24 I would like to turn this over
25 to Lisa.
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2 MS. JACKSON: I will keep this
3 very brief because I assume most of you
4 are somewhat familiar with what the
5 Superfund process is about and I
6 apologize, I think I have the longest
7 overhead and this is the shortest screen
8 I have ever seen.
9 The Superfund is the Federal
10 government program for cleaning up
11 abandoned hazardous waste sites
12 throughout the county and it is a
13 multi-step process. It kind of evolved
14 when the Superfund came to be. The
15 first step in the process is usually
16 what we call site discovery. Someone,
17 some entity phones into EPA a complaint
18 about a site, which usually starts a
19 whole gamut of investigatory activities
20 to determine what the status of the site
21 is.
22 As you might guess, most sites
23 are found to be no problem or someone is
24 addressing them or the contamination is
25 not severe enough to warrant Federal
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2 Government attention. There are those
3 sites that are just the opposite. They
4 do require attention and those
5 eventually are ranked numerically and
6 based on the number they are assigned
7 the numbers above 28.5 they are put on
8 the National Priorities List.
9 I am going to go through a few
10 of the words that you will hear about
11 night. Once a site is listed on that
12 list it becomes available for long term
13 response, sometimes by the Federal
14 Government sometimes by the State of New
15 Jersey. Chemsol was put on the
16 Superfund list in 1983.
17 The first thing that usually
18 happens even before it goes on the list,
19 but I was not guite sure where to put
20 this on the slide, someone comes up and
21 starts to look at the site to determine
22 whether or not there is something that
23 should be done guickly to try to
24 mitigate any immediate threat, to stop
25 the contamination from getting worse
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1
2 while we do what has become a pretty
3 long term investigation to look for
4 contamination, the remedial
5 investigations and feasibility studies
6 and at this site we actually did
7 something kind of inventive when Jim was
8 project manager.
9 He did a focused feasibility
10 study to accelerate the response, to
11 make sure we address the problem as
12 guickly as possible.
13 The other thing that goes on
14 during all these processes is what I
15 loosely term enforcement activities.
16 The way the law is written as to how
17 Federal money can be spent to clean up a
18 site, to investigate a site but there is
19 a strong preference and legally we are
20 required to try to get those parties who
21 placed the contamination, who owned the
22 property that is contaminated to do the
23 cleanup.
24 We spend quite a bit of effort
25 and an awful lot of time trying to
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2 negotiate with what we what call
3 responsible parties, instead of spending
4 tax dollars to do it. At the
5 culmination of all the study phases we
6 issue what is called a Record of
7 Decision. That is actually part of why
8 we are here tonight.
9 The government is legally
10 obligated to take comments on all
11 decisions that it makes for cleanup of a
12 site, other than those emergency type
13 activities, and what we usually try to
14 do is take comment or get public input
15 if it is not a screaming emergency.
16 Part of our process is to put
17 forth to you in the proposed plan our
18 proposal of how we think we should be
19 addressing this next phase of work. The
20 comments can be given tonight orally
21 because they are recorded by the
22 stenographer, or you can write and send
23 them to Nigel at the EPA. Either way
24 they will become part of the official
25 record.
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2 If you think of something after
3 you leave here tonight you still have
4 plenty of time to get it on the record.
5 The EPA will take those comments and at
6 the end of that issue a legal document
7 called a Record of Decision which
8 outlines our final decision for that
9 cleanup.
10 Once that document is issued we
11 go and do more negotiating with the
12 responsible parties to try to get them
13 to implement the work with their money.
14 If not we spend Federal money to
15 implement it. Like Chemsol we also
16 spend guite a bit of time in operating
17 and maintenance. We are pumping water
18 and continually pumping in order to
19 monitor to see if we are seeing
20 decreasing levels of contamination.
21 After this is all completed
22 there is the deletion of a site from the
23 NPL. Way back when it went on the NPL.
24 Depending on the nature of the
25 contamination it can be decades or many,
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2 many years before it is finally deleted.
3 I am now going to turn it over
4 to Nigel, who is going to describe the
5 process for the Chemsol site.
6 MR. ROBINSON: Can everybody
7 hear me?
8 Well, as Lisa and Pat said we
9 are here to bring forth our proposed
10 plan for the Chemsol Superfund Site here
11 in Piscataway, New Jersey. Here we have
12 put down two bullets as the purpose of
13 the proposed plan and it is basically to
14 identify EPA' s preferred remedial
15 alternative and rationale for its
16 preference.
17 Basically we want to tell you
18 what we have chosen and the reason why
19 we chose it and to encourage the public
20 to review and comment on the
21 alternatives that are presented here in
22 the proposed plan.
23 Before I move along I just want
24 to show everybody here, I think you are
25 probably all aware where the site is,
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2 but this is the location of the site
3 right at the end of Flemming Street and
4 right across from Stelton Road.
5 This is just a more detailed
6 view of the site and right along here,
7 this is basically the site along here
8 and here right along the railroad. It
9 is divided into two lots. It is
10 approximately 40 acres. The larger lot,
11 Lot 1-A is about 27 acres. Lot 1-B is
12 about 13 acres.
13 The treatment plant, which I
14 will talk a little bit more about as we
15 go along is located right here. Just to
16 give a brief background on the site, the
17 site was previously a solvent recovery
18 and waste reprocessing facility. They
19 basically accepted waste from different
20 generators and different companies and
21 tried to reprocess it and sell it.
22 They operated from the 1950's
23 through 1964. During their period of
24 operation they had a whole series of
25 accidents, explosions and fires. The
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2 plant was closed down or ceased
3 operation back in 1964. The property
4 was eventually rezoned for residential
5 use in 1978.
6 The current owner of the site is
7 Tang Realty, and as Lisa mentioned
8 earlier the site was placed on the
9 National Priorities List in 1983 and the
10 EPA and the New Jersey DEP has been
11 involved ever since.
12 From 1983 through 1990 the
13 current owner, Tang Realty, under the
14 direction of the New Jersey Department
15 of Environmental Protection undertook
16 groundwater investigation and in 1988
17 and 1990 removal actions were performed
18 at the site and basically what happened
19 was that we had hazardous waste in
20 drums, in lap packs, bottles at the
21 site, so we went there and we undertook
22 a removal action.
23 Okay, after the removal action
24 was completed we initiated what we call
25 remedial investigation and feasibility
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2 study. That was done in 1990. We
3 decided that we would use a two phase
4 approach and we basically broke it up
5 into Phase 1 and Phase 2, and primarily
6 based on the result we realized that the
7 groundwater was severely contaminated
8 with various substances dumped to a
9 depth of about 130 feet.
10 We wanted to move quickly so we
11 could evaluate the options for
12 containment of the contaminated
13 groundwater and soil and prevent it from
14 traveling off site.
15 In the second phase we decided
16 that we would undertake it, so we could
17 determine the nature and extent of the
18 contamination at the site. The remedial
19 investigation was completed last year
20 and these are basically the findings for
21 Phase 2.
22 What we found was that the soil
23 and groundwater is contaminated with
24 volatile organics, semi-volatile
25 organics, pesticides, PCB's and metals.
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2 Sediment samples also indicates the
3 presence of volatile organic,
4 semi-volatile organics, pesticides and
5 metals and the surface water indicates
6 low levels of pesticides and organics
7 which appear to be entering from off
8 site.
9 I did not prepare a table here
10 to show the different contaminates that
11 we found, but it is presented in the
12 proposed plan so anybody that is
13 interested can see all the contaminants
14 we found there.
15 We also prepared what we call a
16 risk assessment and the risk assessment
17 is to evaluate the risk posed by
18 whatever contamination we find at the
19 site and so we looked at contamination
20 that was found in the soil, the
21 groundwater, the surface water, the
22 sediment and the air and performed the
23 risk assessment.
24 EPA acceptable cancer risk range
25 is 10 to the minus 4 to 10 to the minus
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2 6. What that means is there is a one in
3 10,000 to one in one million increased
4 chance of developing cancer over a 70
5 year lifetime from exposure at the site.
6 Based on our risk assessment we found
7 unacceptable risk at the site and
8 basically exposure to surface soil was
9 2.2 times 10 to the minus three and
10 exposure to groundwater and that is 2.4
11 times 10 to the minus two.
12 In addition to a cancer risk we
13 also found non-cancer risk and here we
14 have non-cancer effects are assessed
15 using a hazard index, HI. A hazardous
16 index greater than one indicates a
17 potential for non-cancer health risk.
18 Acceptable non-cancer health effects
19 associated are ingestion of surface soil
20 and groundwater by children, adults,
21 site employees and workers.
22 No risk or non-cancer effects
23 associated with subsurface soil,
24 sediment or surface water was found so
25 basically most of the non-cancer risks
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2 were associated with soil on the
3 surface, zero to two feet down and they
4 are associated with children and adults
5 and employees or workers at the site.
6 We also did an ecological risk
7 assessment and what that entails is an
8 appraisal of the actual or potential
9 effect of a hazardous waste site on
10 plants and animals. What we found from
11 the ecological risk assessment is that
12 there is a potential risk from surface
13 soil to small mammals and birds.
14 We found a minimal potential
15 risk from sediments but it was not
16 sufficient to warrant disturbance or
17 remediation of the stream bed. What we
18 are saying is the risk was so small
19 there was nothing to warrant digging up
20 the stream and replace it. We found no
21 significant potential for risk from
22 surface water to water column receptors.
23 Here the topic is remedial
24 action objectives. When we are working
25 through the process of deciding what
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2 alternatives we will choose we have to
3 have objectives and these are the
4 objectives that we set about achieving.
5 Restoring the soil at the site
6 to levels which would allow for
7 residential, recreational use without
8 restrictions so we want to clean up the
9 site with as little restrictions as
10 possible, so it can be used for
11 residential recreational use such as
12 parks, playgrounds, et cetera.
13 The other objective we had was
14 to augment the existing groundwater
15 system to contain that portion of
16 contaminated groundwater that is
17 unlikely to be technically practical to
18 fully restore. Restore remaining
19 groundwater to State and Federal
20 drinking water standards and whatever
21 contaminated groundwater that is there
22 we want to be able to clean it up so we
23 can restore it to whatever the State
24 drinking water standard is or whatever
25 the Federal government drinking water
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2 standard is.
3 We want to remove and treat as
4 much contamination as possible from the
5 fractured bedrock. I didn't touch on
6 much of it, but one of the problems with
7 this site is that after about six feet
8 down you encounter bedrock and it is
9 fractured. There are a lot of cracks in
10 it, so a lot of contamination has seeped
11 through these cracks.
12 So even though we are currently
13 pumping and we are getting contamination
14 out, a lot of it is still locked up in
15 there and it is difficult to get out, so
16 this was one of other objectives that we
17 had. Remove and treat as much
18 contamination as possible from the
19 fractured rocks. The next one was to
20 prevent human exposure to contaminated
21 groundwater.
22 We want to minimize the exposure
23 to whatever degree we can to humans. We
24 want to prevent exposure to surface soil
25 containing PCB's, one part per million
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2 and lead at 400 parts per million.
3 PCB's at one part per million is the
4 Federal cleanup standard for PCB's in
5 residential areas and the lead standard
6 is 400 parts per million.
7 So we want to clean up the site
8 to meet these criterias. We want to
9 eliminate the source of contamination to
10 the groundwater. So if there is any
11 organics, any chemical in the soil
12 currently we want to be able to remove
13 that soil so it will not continue to
14 leach into the groundwater.
15 So basically we had to come up
16 with remedial alternatives. Since we
17 have two media that we have to contend
18 with that are contaminated at the site,
19 we have soil contamination and we have
20 groundwater contamination our aim is to
21 develop different alternatives so we can
22 address the soil contamination and also
23 address the groundwater contamination.
24 This is a short list of some of
25 the alternatives that we looked at that
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2 will address the soil contamination.
3 Some of them were eliminated for several
4 different reasons, but this is the final
5 list that we use for our evaluation and
6 for the first alternative, S-l, that is
7 no further action.
8 Under the Superfund law we have
9 to look at no further action, which is
10 basically what would happen if we did
11 nothing at the site and we use that as a
12 bench mark to compare it with the other
13 alternatives that we will choose or look
14 at.
15 The second one was capping the
16 area with soil. Basically that is
17 moving soil in, placing it over the
18 entire site or the areas that are
19 contaminated. Seeding it with grass and
20 by doing that that would eliminate the
21 exposure of contaminants in the surface
22 soil to adults, kids, workers or
23 employees at the site.
24 The third alternative was
25 excavation an off-site disposal. Under
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2 that alternative we basically would
3 excavate the contaminated soil and just
4 truck it off to some off-site disposal
5 facility and that would pretty much take
6 care of whatever source of contamination
7 we have in the soil.
8 There is another alternative,
9 S-4A. We would excavate and perform
10 on-site low temperature thermal
11 desorption of PCB contaminated soil.
12 Basically what that is, it is not an
13 incinerator but it is something close
14 and we would excavate the soil, put it
15 in this machinery and provide it with
16 heat.
17 It would remove the PCB's and
18 other organics, some of the other
19 organics from the soil. It would be
20 free of PCB's and organics and the
21 portion of soil that contains lead, what
22 we would do, since we cannot destroy
23 lead we would just have to solidify it
24 and leave it on site, so basically in
25 solidifying it we would end up mixing it
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2 with cement and placing it in a certain
3 area on site and once you do that then
4 that minimizes the risk and contact of
5 lead contaminated soil to children,
6 adults, workers and just the environment
7 in general.
8 The other one is basically the
9 same process as the one before it, but
10 instead of solidifying the lead
11 contaminated soil on site we would truck
12 it off to disposal facilities off-site.
13 The groundwater alternatives.
14 As most people here know the groundwater
15 treatment facility has been in operation
16 since, I think, 1994 at the site, and
17 basically what it does is we have a
18 treatment plant and we pump from one
19 well, now I think it is about 25 gallons
20 per minute, and we pass it through a
21 whole host of treatment processes that
22 will remove organics and/or contaminants
23 from the groundwater.
24 We looked at different
25 groundwater alternatives that we could
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2 use to augment the current treatment
3 facility there, and as I mentioned
4 earlier we always have to look at the no
5 action alternative. Basically what
6 would happen if we did nothing and just
7 walked away from the site.
8 The next one would be continue
9 existing interim action, extract
10 groundwater from Well C-l and pass it
11 through these different treatment
12 processes. Under that one we have two
13 options. We looked at two options.
14 Currently we are using Option A, where
15 the treated groundwater is released to
16 the Middlesex County Utilities Authority
17 and also Option B where the treated
18 water is released to Stream 1A.
19 The third alternative for
20 groundwater is basically just an
21 addition to Alternative 2. We currently
22 pump from just one well. What we would
23 do in this alternative is to pump from
24 additional wells, and we are looking at
25 about five additional wells so we would
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2 pump here and just pump it right to the
3 current treatment facility and whatever
4 is going on now would continue to go on.
5 Currently we are pumping about 25
6 gallons per minute. Under this
7 alternative it would go up to about 50,
8 55 gallons per minute.
9 We previously looked at soil
10 alternatives and now we have to look at
11 the cost. The cost is always an issue.
12 Whether it is viable or not, too cheap,
13 too expensive and we have different
14 factors that we look at. We look at the
15 capital cost. How much capital would it
16 cost to implement it.
17 We have all of the different
18 alternatives under the soil that I
19 previously mentioned, the no action,
20 capping the soil, excavation, thermal
21 desorption treatment on site. When
22 looking at the costs we have to look at
23 operation and maintenance costs.
24 What that is, currently the
25 facility there that is in operation
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2 incurs operation and maintenance costs
3 because the groundwater has to be pumped
4 and it has to be treated. You have to
5 pay for electricity. You have to pay
6 for treatment. You have to pay for
7 maintenance, et cetera.
8 That is also another factor that
9 we have to look at. Here we look at
10 what we call the net present worth.
11 That is how much money would we need to
12 put up front so that over the next 30
13 years we could not meet the projected
14 cost expenses. All of these costs here
15 are based on a 30 year schedule. How
16 much money would we need to put up front
17 now so I could pay for the costs and pay
18 for the operational costs over the next
19 30 years.
20 Then this column, this would be
21 the implementation time. How long would
22 it take to implement the remedy. In
23 this case this is basically once you get
24 the go ahead how long would it take
25 physically on site to do whatever you
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2 need to do to the soil and whatever you
3 need to do to the groundwater to get the
4 whole thing running, and so from here we
5 can see this is more in terms of cost.
6 The net present worth is really the
7 column that we need to focus on and we
8 see for the no action it would cost us
9 $338,000 that being the lowest and the
10 most expensive one would cost us $12
11 million.
12 We had to do the same cost
13 analysis for the groundwater alternative
14 that we looked at and here we have a
15 capital costs, annual cost, annual
16 operation and maintenance cost and you
17 can see here that it gets pretty high.
18 Under the existing operation that we
19 have at the plant you are looking at
20 almost a half a million dollars a year
21 to operate the plant.
22 Under another option, GW-5 it is
23 close to three-guarters of a million
24 dollars to operate it on an annual basis
25 so this is the important column in that
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2 present net present worth, and we see
3 what the costs are and for the no
4 further action that is the cheapest one
5 and it is over $900,000 and under GW-5,
6 Option B, which would be releasing it to
7 the stream it is a little over $12
8 million.
9 After we have come up with our
10 list of alternatives, the soil
11 alternatives and the groundwater
12 alternatives we have to go through what
13 we call an evaluation criteria.
14 Basically we have a list of nine
15 criteria that we have to evaluate, and
16 the first one on the list of
17 alternatives that we decide on we have
18 to look at overall protection of human
19 health and environment and determine if
20 this alternative provides us with enough
21 protection for human health in the
22 environment.
23 We also have to look at
24 compliance with ARAR's among other
25 relevant and appropriate reguirements.
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2 To put it in a nutshell, we have to see
3 if the alternatives comply with other
4 environmental laws. We have to look at
5 the long-term effectiveness of the
6 alternatives.
7 We have to look at whether it
8 reduces the toxicity or mobility or
9 volume of the treatment whether they are
10 in the soil or groundwater. We look at
11 the short-term effectiveness,
12 implementability. How easy is it to
13 implement it. We look at cost and we
14 look at whether the State will accept
15 the alternatives that we choose and
16 whether the community will accept the
17 alternatives we chose.
18 That is one of reasons we are
19 here today, to show you the alternatives
20 that we prefer and see if you are
21 accepting of it and what comments you
22 have on it. So after going through all
23 of that we did an analysis of what we
24 thought was best based on all of those
25 nine criterias that we just went
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2 through.
3 The EPA' s preferred alternative
4 for the soil portion of the
5 contamination, we preferred the
6 excavation and off-site disposal of the
7 contaminated soils that are currently
8 there at the site and for the
9 groundwater portion, we prefer to
10 extract and treat the groundwater with
11 additional wells using existing
12 treatment technology. So basically the
13 treatment plant is there in operation.
14 What we prefer to do is just to add
15 additional wells, pump from them and
16 pass that water through the treatment
17 facility.
18 The next step in the process,
19 and as Lisa mentioned earlier and
20 briefly described is a Record of
21 Decision and after going through this
22 entire process we have to come up with a
23 Record of Decision. That is what is our
24 decision, what alternatives have we
25 chosen and put it in a document, which
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2 is a legal document which is to be
3 implemented at site.
4 So after the proposed plan,
5 after we get the comments from the
6 public we will prepare a Record of
7 Decision and whatever decisions we make
8 will be implemented, and in addition to
9 that Lisa also mentioned that we will do
10 additional groundwater investigation to
11 determine if the contaminated
12 groundwater is leaving the property
13 boundaries.
14 Right now Well C-l is capturing
15 most of the groundwater at the site, but
16 we still feel that some groundwater
17 could be leaving the site and based on
18 the alternative that we have chosen in
19 adding additional wells, pumping wells
20 at the site we think we will be
21 capturing most of the groundwater at the
22 site and basically capturing everything
23 at the site, but we feel we still need
24 to do additional investigation just to
25 be sure that none is leaving the site or
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2 if any, minimal.
3 With that comes the end of my
4 presentation and I will turn you over to
5 Pat Seppi who will act as moderator in
6 taking questions and answers.
7 MS. SEPPI: I know it seems we
8 have thrown you a lot of information,
9 but we have tried to keep it short
10 because found in the past these long
11 full blown explanations sometimes it is
12 better to just let you ask guestions and
13 since we do have a court stenographer
14 this is part of the record. We would
15 ask you to come up to the mike to ask
16 your guestion and state your name first
17 so we will have it for the record, and
18 if you could spell it also.
19 ASSEMBLYMAN SMITH: Actually let
20 me thank the U.S. EPA for a very
21 informative presentation and also for
22 the work you have done so far to clean
23 up the site. Your presentation did
24 generate some guestions.
25 No. 1, just prior to the
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2 presentation we had a chance to talk
3 informally and I believe Mr. Hacklar
4 indicated that so far on the site
5 approximately $10 million has been spent
6 associated with the current clean up.
7 MR. HACKLAR: Roughly.
8 MR. SMITH: You mentioned to me
9 the responsible party has stepped up to
10 the plate and has been acting
11 responsibly.
12 MR. HACKLAR: Tang Realty is one
13 of a group of responsible parties. What
14 has happened is that Tang Reality is one
15 of a group of responsible parties that
16 designed and constructed and is
17 operating and maintaining the treatment
18 system on the site, and that group is
19 really the group that has spent the
20 majority of the money so far.
21 ASSEMBLYMAN SMITH: But they are
22 acting in accord with the Superfund Law.
23 The responsible party is taking
24 responsibility.
25 MR. HACKLAR: That is correct.
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2 ASSEMBLYMAN SMITH: It appears
3 that the alternatives recommended by the
4 EPA for both groundwater and soil are on
5 the order of $18 million dollars for
6 that clean up that is currently being
7 recommended; is that true.
8 MR. HACKLAR: Is that is
9 correct.
10 ASSEMBLYMAN SMITH: Is there any
11 reason to believe that the responsible
12 parties will not be responsible with
13 regard to that $18 million.
14 MR. ROBINSON: At this point
15 there is no reason to believe they will
16 not pay. As a matter of fact they are
17 willing and looking forward to
18 negotiating with us for implementing the
19 Record of Decision.
20 ASSEMBLYMAN SMITH: That is
21 certainly also good news. In the
22 background information there is the
23 statement, I believe on Page 2 that
24 there are approximately 180 private
25 wells at residential and commercial
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2 addresses that are potentially active,
3 that means not sealed within a radius ot
4 two miles of the site and 22 of these
5 wells are located at a distance less
6 than a half a mile from the site.
7 I guess the obvious question, at
8 least with regard to the 22 wells that
9 are at within a half a mile from the
10 site is, have they been tested for
11 contamination?
12 MR. HACKLAR: Previously,
13 several years ago we did have a sampling
14 event of residential wells in the area.
15 That was probably five years ago.
16 People that wanted their wells sampled
17 approached us and we went out and
18 sampled those wells.
19 While there are wells there
20 sealed there are probably still wells in
21 the area that may in fact not be sealed.
22 It is my understanding that there is
23 municipal water available to people if
24 they want it in the area.
25 ASSEMBLYMAN SMITH: I believe
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2 that is true. We are pretty much a
3 fully -- our infrastructure is pretty
4 much in place in Piscataway. That being
5 said the recommendation to you from me
6 is with respect to those 22 homes or
7 those 22 wells which maybe active that
8 whether the property owner has requested
9 testing or not, I think the testing
10 should be done.
11 We have now had several years
12 elapse. You have been pumping water out
13 of that site for three years.
14 Groundwater is moving and I think with
15 regards to those 22 wells it would
16 provide some piece of mind to the
17 community to know that the contamination
18 is not migrating or the groundwater is
19 not moving off-site and I know of you
20 have your consultant here and
21 hydrogeologists have looked at this
22 thing and the technical people, that
23 being said it would be nice to know with
24 regard to those 22 wells that we know
25 for a fact by means of current testing
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2 that the contamination has not moved and
3 there is no potential threat to those
4 people.
5 With regard to those 22 wells,
6 if there are residential wells that are
7 still active I believe Tang Realty
8 should be responsible for the cost to
9 connect them to the city water. The
10 reason is the owner, if there is a home
11 owner with an active well they would
12 have to connect to city water. I would
13 like to throw that on the table.
14 The guestion with regard to
15 clean up standards are they the result
16 of the risk assessment standards EPA put
17 on the screen or are they dictated by
18 the zoning on the site, would there be a
19 different clean up if this was zoned
20 industrial versus residential?
21 MR. HACKLAR: Basically it is a
22 combination of both. The risk
23 assessment showed us that there was a
24 threat from the soil and that PCB's were
25 a major factor. EPA does have a cleanup
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2 level for lead and because we saw that
3 they were exceeding that level we felt
4 it would be appropriate to remediate for
5 lead.
6 In looking at the areas to clean
7 up and not to clean up we did apply the
8 EPA cleanup criteria as a guide, so it
9 really is a combination of both.
10 MS. JACKSON: The even more
11 direct answer to the guestion, PCB's are
12 a good example. If we believe the site
13 is going to be used for residential, the
14 cleanup number for residential is 10
15 parts per million. We are not proposing
16 to go to 10. We are proposing to go to
17 one. We want to allow the site to be
18 used for residential, recreational.
19 ASSEMBLYMAN SMITH: If the
20 proposed use was industrial what would
21 be the number?
22 MS. JACKSON: The PCB's cleanup
23 number is 10. If we thought we were
24 going to have an industrial property
25 actually the guideline is 10 to 25. it
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2 could be as high as 25.
3 ASSEMBLYMAN SMITH: Would it be
4 fair to conclude to that the most
5 conservative approach is to keep the
6 residential zoning in place because that
7 reguires the greatest degree of cleanup?
8 MS. JACKSON: As far as our
9 using residential it is almost a more
10 stringent cleanup number.
11 ASSEMBLYMAN SMITH: That was the
12 whole point of guestion. I did not
13 phrase it articulately. I know that is
14 information counsel needs to know and
15 that is very helpful. There is a
16 statement in here on Page 19, "The State
17 of New Jersey cannot concur on the
18 preferred remedy unless its soil direct
19 contact criteria are met or
20 institutional controls are established
21 to prevent direct contact with soils
22 above direct contact criteria."
23 What is the status of the State
24 of New Jersey's response to your
25 proposed cleanup or has there not been a
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2 response received?
3 MR. HARVEY: We have commented
4 on this proposed plan. The only
5 potential problem is the State's
6 criteria, it is not a standard, not a
7 law, for PCB's is .49 parts per million.
8 EPA criteria that they use is one part
9 per million, so there is a slight
10 different criteria. That is really the
11 main potential problem.
12 ASSEMBLYMAN SMITH: It is not a
13 happy thought, but I thought the
14 legislature passed a statute earlier
15 this session that indicated the State's
16 standard could not be more stringent
17 than Federal.
18 MR. HARVEY: That is true, but
19 there is not a law.
20 ASSEMBLYMAN SMITH: Keep up your
21 criteria. Fight hard for it. From an
22 environmental point we want to see the
23 site as clean as possible so please
24 continue to push for the . 49.
25 What happens if you do not come
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2 to agreement. What happens if the State
3 does not agree with the preferred
4 alternative because their cleanup
5 criteria is more stringent than yours?
6 MS. JACKSON: There are a couple
7 of ways we can go. We would like to
8 approach the responsible parties in
9 negotiations and ask them to use the
10 State number because the State will
11 insist if we do not use their number and
12 do not meet it we leave restrictions on
13 the property, which we do not want to
14 do.
15 Our first hope is we will be
16 able to work it out to use the state
17 number, even though it is not law, but
18 we intend and we have been cooperating
19 all along and hope that will happen. If
20 that does not happen there are
21 alternatives. We can ask the State to
22 help us fund whatever additional cleanup
23 in order to meet their number.
24 Usually we can work it out in
25 negotiations. It is one of those
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2 regulatory points that we are familiar
3 with. It has happened at a couple of
4 other sites. We usually try to work it
5 out.
6 ASSEMBLYMAN SMITH: Does the
7 public and Mayor and council as these
8 negotiations proceed between the
9 responsible parties and the State, is
10 the local government informed of the
11 status of those negotiations? Does the
12 public ever know the status of those
13 negotiations?
14 MS. JACKSON: Not usually. The
15 legal document that would specify the
16 cleanup level would be the Record of
17 Decision. The public's opportunity to
18 weigh in, is now.
19 If there is a strong feeling on
20 the part of elected officials or the
21 public at large this would be the time
22 to make that clear.
23 ASSEMBLYMAN SMITH: I am very
24 happy that you made that point because
25 certainly everyone in the audience has
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2 to take that under advisement.
3 For myself I would endorse the
4 State standard, the .49. Can you
5 elaborate why the State picked .49?
6 MR. HARVEY: It is based on our
7 own risk assessment work and that is
8 done by our state scientists. That is
9 all I really know. I do not know any
10 details.
11 ASSEMBLYMAN SMITH: I would
12 assume since it is a lower number it
13 would result in lower risk numbers than
14 on the overhead projector.
15 MS. JACKSON: it is not going to
16 result in a huge difference. It is a
17 lower number, a lower risk.
18 ASSEMBLYMAN SMITH: Has EPA
19 guantified the cost?
20 MS. JACKSON: That is the
21 interesting point. Right now there is
22 no reason to believe it will cost any
23 more. We are very hopeful. If you go
24 to one you can go to .49. There are
25 legal reasons but we believe we are
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2 talking about a difference of a couple
3 of shovel fulls.
4 ASSEMBLYMAN SMITH: For the
5 record, I am for the .49. As I read
6 this it appears you are talking about a
7 30 year timeframe for the cleanup
8 approximately plus or minus.
9 MR. ROBINSON: Yes, basically
10 for all groundwater treatment we use a
11 30 year as a standard for costing and
12 for evaluation, so what we do is we pump
13 and every five years we look at the data
14 that we have collected, reevaluate it
15 and make a decision whether we continue
16 pumping the way we have been pumping or
17 whether changes need to be made or
18 whether we shut down the facility
19 because we are within the cleanup
20 criteria.
21 ASSEMBLYMAN SMITH: My last
22 comment is congratulations for working
23 hard on this site, bringing it to where
24 it is. I know the people in Piscataway
25 appreciate the fact the Superfund
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2 cleanup is going forward. We know this
3 is an enormous expense. The technical
4 expertise is also enormous and we
5 appreciate the full force of the State
6 and Federal government to see that the
7 cleanup occurs.
8 That being said, I would also
9 endorse your proposals in terms of
10 cleanup. It sounds to me removal from
11 the site, while it is less expensive
12 than the cleanup at the site and the
13 groundwater alternative appears to be a
14 reasonable alternative as well.
15 The two things that are a little
16 unsatisfactory, I would like to press a
17 little harder on is the fact there needs
18 to be a way for the public and local
19 officials to know what the final status
20 of the negotiations are before its is
21 signed on the dotted line. I think
22 people want to know what is going to be
23 agreed to, what is about to be agreed to
24 before it is a done deal.
25 If there is some way to do that
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2 I would urge they consider doing that on
3 the site because it is of such an
4 important interest to the community.
5 The second comment I want to
6 make is to urge that those 22 wells that
7 maybe active need sampling and in the
8 event there is contamination the
9 responsible party be held responsible.
10 MS. JACKSON: You do not have to
11 speak now but if there is anyone in this
12 situation and you are interested in
13 having your well tested please come up
14 after the meeting. We would love to
15 hear from you. It is not a problem to
16 do the test. I think that is a good
17 suggestion.
18 MR. BESON: I am Mike Beson,
19 B-e-s-o-n. I work for Congressman
20 Palone. I am here representing him
21 tonight.
22 I wanted to thank the EPA for
23 coming out. Clearly Assemblyman Smith
24 is correct in saying this is a very good
25 plan in the terms of the way you are
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2 getting rid of the soil and groundwater.
3 I think it is tremendous. Unfortunately
4 it had to take this long. I know we
5 have worked all in concert in trying to
6 make this happen. I just wanted to say
7 that we have to make sure that we test
8 as many off-site wells as we possibly
9 can. That is very important because we
10 have a responsible party and because of
11 off-site the groundwater contamination
12 we have to make sure we get to as many
13 off-site places as we can.
14 I encourage the people if you
15 have those wells please come up. I an
16 also agree with Assemblyman Smith about
17 the PCB's standard, please use the State
18 standard. The lower the standard the
19 better. Certainly if it is not costing
20 any more money it is probably the
21 smarter thing to do.
22 Alternative Groundwater 5,
23 Option B, that part of Option B it says:
24 "Starting up existing biological
25 treatment plan." Use of biological
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2 treatment plan will allow for discharge
3 into Stream LA. Is that part of your
4 plan?
5 MR. ROBINSON: It may eventually
6 become a part of the plan. Currently we
7 prefer Option A and the plan that is in
8 operation now uses Option A but there is
9 also a possibility and PRP and they have
10 indicated that to us that in the future
11 they are not sure how much longer they
12 can continue releasing the treated
13 groundwater to the Middlesex County
14 Utilities Authority and in the event
15 that the Authority will not accept the
16 water any more we have to resort to
17 Option B.
18 What option B is is an
19 additional piece of eguipment that goes
20 through an additional chemical process
21 and in this case it is a biological
22 process that will do an additional
23 treatment and will enable the water to
24 be released to the stream.
25 MR. BESON: I would encourage
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2 you to use the State standard. It is
3 very nice if things can be cleaned up to
4 a particular standard. In one case you
5 contradict yourself. You say on Page
6 16, "It is possible that it will be
7 technically impracticable to restore all
8 portions of the aguifers to meet State
9 and Federal standards."
10 I do not know if that has
11 implications to this.
12 MR. ROBINSON: No.
13 MR. BESON: Option B, releasing
14 it to the stream would be a last ditch
15 scenario. We have Assemblyman Smith and
16 Freeholder Brady. I know they would
17 work with our Utilities Authority to
18 make sure they would continue to accept
19 it.
20 The responsibility party should
21 do everything in its power to make sure
22 it does not have to be released. I
23 understand it would be within State and
24 Federal standards. If there is no
25 reason to do it you must pressure them
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2 and make sure it does not happen.
3 That was all I had to say.
4 Assemblyman Smith, on the final
5 negotiations I would be happy to keep in
6 touch with you to let you know where we
7 are. If you could filter information
8 about where we are I would be happy to
9 get it down to the local and state
10 level.
11 MR. HACKLAR: On the pumping
12 availability, the, status of the
13 negotiations. One of the avenues that
14 the EPA could proceed down with the
15 responsible parties would be to enter
16 into a consent order or administrative
17 order on consent.
18 If that were the case it would
19 go through a public notice period and
20 the public would be able to comment on
21 that.
22 MR. BESON: Okay. Thank you
23 very much for coming tonight.
24 MS. SEPPI: Thank you, Mike.
25 Councilman Stewart.
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2 COUNCILMAN STEWART: I am Jim
3 Stewart. I am the Councilman for Ward 4
4 in Piscataway. On behalf of the people
5 of Ward 4 I would like to agree with
6 previous speakers and Assemblyman Smith.
7 We should ask for the .49 parts per
8 million, especially in light of fact it
9 is really not much more involved and not
10 much more cost, some sort of
11 bureaucratic thing that has to be worked
12 out.
13 If that is the case I urge you
14 to please try to work it out for the
15 benefit of the people and I know
16 Councilman Wahler before I came up here
17 asked me to state he also feels the same
18 way. He represents the people in Ward 2
19 in Piscataway. I see our Freeholder,
20 Camille Fernicola from Piscataway is
21 here too and she will have some comments
22 later on, her thoughts about this.
23 Also, I agree very much with the
24 comments about paying for the testing of
25 the wells in the neighborhood. I
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2 remember back when this become an issue
3 and the people were just finding out
4 they had contamination in their wells,
5 part of the problem in the testing
6 involved was it was somewhat expensive
7 for the average homeowner to foot the
8 bill on a regular basis and I think to
9 go back down say to them you should pay
10 for testing the wells.
11 Even though it is a Superfund
12 Site out there I think it is sort of
13 unfair. If it could be worked out where
14 your agency could pay for the testing of
15 the wells I think it would be
16 appropriate. I think it would be a fair
17 thing to do. I also had some guestions
18 I would like to ask, one having to do
19 with the actual logistics of trucking
20 away, I think you are talking about
21 18,000 cubic yards of soil. What is the
22 possibility for airborne dust and
23 contamination or rain water washing some
24 of the stuff down the streets and so
25 forth and so on.
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2 MR. ROBINSON: There is always
3 that possibility, but a lot of these
4 issues, health and safety issues they
5 will be addressed and the remedial
6 design and soil excavation is relatively
7 standard procedure in the construction
8 industry and they have measures that
9 addresses all of these things. We will
10 be going through that in the remedial
11 design.
12 MR. HACKLAR: Just to give you a
13 little bit about the historical
14 information, when we were building the
15 treatment plant out at the site
16 monitoring was done to determine the
17 level of dust in the air and especially
18 if trucks were going back and forth on
19 Flemming Street and if the dust was too
20 high the work would cease or there would
21 be some sort of dust suppression
22 measures.
23 There are very standard
24 measures. They are easily
25 implementable.
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2 COUNCILMAN STEWART: I think
3 compared to the soil excavation so far
4 this would be on the magnitude bigger.
5 There might have been a little dust here
6 and there on what you have done so far,
7 but it sounds like there is a potential
8 for contamination airborne into the
9 nearby residences.
10 We do have high density
11 apartment building in that area. There
12 are a lot of people living in that small
13 area. It worries me. I would like to
14 get some more information exactly what
15 those suppression technigues are. I do
16 not claim to be an expert but I have
17 seen trucks hauling away dirt. You can
18 see it blowing in the street. Not that
19 we have potholes in Piscataway but if it
20 hits a bump, you know, what I am saying.
21 I would like to get some more
22 detail.
23 MS. SEPPI: That is very common.
24 We have a lot of sites in construction
25 in New Jersey, especially with the
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2 summer we have had, it has been dry. We
3 can get you that information. Dust
4 suppression the perimeter air
5 monitoring, it is a problem that we have
6 at all sites. I think we have some
7 pretty good ways of handling it.
8 As we did with the treatment
9 facility we spend a lot of time with
10 people in the town engineering the
11 traffic. Everything will be worked out.
12 COUNCILMAN STEWART: Will we be
13 able to get more specifics on the
14 technology you will be using?
15 MS. SEPPI: Yes.
16 COUNCILMAN STEWART: I am glad
17 to see we are going to truck the soil
18 away and not leave it in place. I like
19 the option of pumping out the water by
20 putting more wells in.
21 One guestion I have, just before
22 the meeting we were talking informally
23 and I mentioned oil well drilling.
24 Sometimes they use very aggressive
25 methods for extracting the last bit of
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2 oil out. During the presentation you
3 were talking about having something like
4 three-guarters of a million dollars in
5 operating expenses for a number of
6 years.
7 I was wondering if more
8 aggressive technigues you would not have
9 to spend that much money. Is it
10 technically feasible in this type of
11 situation.
12 MR. ROBINSON: It is hard to say
13 whether it is technically feasible now.
14 I have spoken with representatives of
15 PRP and they have indicated to me that
16 is one of the options that they have
17 looked at or are looking at and so once
18 we sit down and start talking that will
19 be something to bring up.
20 COUNCILMAN STEWART: It might
21 actually be part of the final process.
22 MR. ROBINSON: Well, chances are
23 it would not be written into the Record
24 of Decision, but if we look at it and it
25 is feasible it might be a case where it
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2 can be amended and can be implemented.
3 COUNCILMAN STEWART: I would
4 rather see it over with quicker, sooner
5 than later.
6 MR. ROBINSON: If you look at
7 operating costs at three-quarters of a
8 million dollars a year if we can qet it
9 done sooner it only makes financial
10 sense.
11 COUNCILMAN STEWART: Thank you,
12 very much.
13 MS. SEPPI: Yes, sir.
14 MR. PROSUK: My name is Richard
15 Prosuk. I live about two and a half
16 blocks away from your site. I have four
17 or five questions that these
18 distinquished qentleman asked already so
19 I only have one left now anyway.
20 You mentioned before about
21 incineration. With the type of dirt and
22 soil would that create any kind of smoq
23 or any kind of outlet into the
24 atmosphere durinq the incineration
25 process.
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2 MR. ROBINSON: Luckily we do not
3 have to worry about that because we have
4 not chosen that alternative. It is not
5 really incineration. It is very low
6 thermal desorption. It is like a big
7 cylinder turning around and once you put
8 this soil in there it has dust
9 collectors so it is more or less a
10 closed system and very little dust is
11 released to the air.
12 MR. PROSUK: Nothing escapes to
13 the atmosphere basically?
14 MR. ROBINSON: I would not say
15 nothing does not escape, but we have
16 safety measures there to try to collect
17 everything.
18 MR. PROSUK: It would be
19 monitored also; is that correct?
20 MS. SEPPI: That is not the
21 option we chose.
22 MR. PROSUK: I just picked up
23 that point when I was reading through
24 this.
25 MS. WOLFSKEHL: My name is
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2 Eileen Wolfskehl. I live at 1115 Kerwin
3 Street. I am a home owner. My concern
4 is — well, you mentioned on Page 9 that
5 you have a concern about the risks, the
6 total cancer risk to potential future
7 residents at the site. Well, my concern
8 is the risks to the people who were
9 children 20 years ago and played at the
10 site.
11 What can we as parents expect of
12 our now adult children. There are a lot
13 of carcinogens on the site. Children
14 went there freely with there bicycles.
15 They played on a mound of what was
16 supposed to be inert materials.
17 They slid down these mounds.
18 They touched the dirt. I would like to
19 know, you know, what is the potential
20 risk of them coming down with cancer and
21 what kinds of cancer. I think that the
22 residents who have had their children
23 play on the site, we should be aware so
24 we know what too look out for.
25 MR. HACKLAR: This question has
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2 come up at past public meeting. The
3 community has been concerned about its
4 children 20, 30 years ago playing on the
5 site. Unfortunately, it is extremely
6 difficult, if not impossible, for us to
7 guantify a risk or even tell you what
8 types of risks from things that happened
9 so long ago.
10 We can tell you and we have told
11 you tonight and in our studies what the
12 current risk is if people, if children
13 go on the site today or if the site is
14 not remediated and children go on the
15 site a year or two or three from now,
16 but we are really not able to tell you
17 what the risk was in the 1970's or the
18 late 1960's from going on the site.
19 MS. WOLFSKEHL: Could you
20 translate that on Page 9, the
21 unacceptable total cancer risk 2.2 times
22 10 to the third, what does that mean?
23 MS. JACKSON: There would be an
24 additional two people out of a thousand
25 who can be expected, if they played and
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2 were exposed to the site on a regular
3 basis over a 70 year period to come down
4 with cancer because of their exposure at
5 the site as it is today.
6 Of course we have no samples
7 from the 1970's so we do not know what
8 the conditions were then. I am not a
9 physician, but I am an engineer and I
10 can put you in contact with someone to
11 talk about the risk. Fortunately one of
12 the things I can say is all of our
13 exposure assumptions are very
14 conservative and usually based on long
15 time period of exposure.
16 Usually with a child you are
17 talking about a child under age 15 from
18 say age 12 to 15 they did have a period
19 of exposure, one of guestions is how
20 regularly they were over there and even
21 so that would be a seven to eight year
22 horizon as opposed to a 70 year horizon.
23 It is based on someone being in
24 and around that contamination every day,
25 it would assume, for instance if someone
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2 came and built a house on that site and
3 gardened every day. With children one
4 thing is they eat dirt, they make mud
5 pies.
6 MS. WOLFSKEHL: Or they do not
7 wash their hands before lunch.
8 MS. JACKSON: We do that too.
9 They sometimes run a higher risk. I
10 understand your concerns. If you want
11 to come up, we can put you in touch with
12 someone but a lot of guestions you are
13 asking we just do not have the data to
14 answer because we do not have samples
15 from that time period.
16 MS. WOLFSKEHL: With the
17 particular type of carcinogens that are
18 there could you pin it down to the types
19 of cancers. Let's say children did play
20 there almost on a regular basis from the
21 time they were allowed to ride there
22 bicycles at the age of eight to, I do
23 not know, 12, 15 what kinds of cancers
24 would there be.
25 MS. JACKSON: I think we are
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2 talking about kidney. There was liver
3 in there. There were tumors that could
4 affect the nervous system. There could
5 be brain tumors. I do not feel
6 qualified to talk about that type of
7 tumors.
8 Those would be the systems that
9 would be effected. There are non-cancer
10 effects to the same kind of systems,
11 liver as part of the hepatic system and
12 your kidneys that do not end in cancer
13 but could still make you ill.
14 A lot of solvents affects the
15 systems of the body, especially if they
16 are eaten. I can't be more specific.
17 We are not qualified to answer that.
18 MS. WOLFSKEHL: Has the EPA ever
19 considered conductinq a door to door
20 survey to find out how many people in
21 the neiqhborhood have died of cancer?
22 MS. JACKSON: We do not do that
23 type of work because we do not have
24 physicians in the aqency. Conqress in
25 the last law authorized an aqency that
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2 is part of the Center for Disease
3 Control, the Agency for Toxic Substances
4 and Disease Registry. A lot of
5 guestions you are asking it would be
6 really good if I put you one of our
7 biological scientists and they can do a
8 lot of those assessments.
9 MS. WOLFSKEHL: I am a measly
10 taxpayer that has no influence whereas
11 you are an agency that could say here is
12 a site, these people have been living
13 near the site raising children for over
14 20 years. You know, it is logical to me
15 that you would be the agency to
16 influence another agency to look into
17 this on our behalf.
18 MS. JACKSON: I will be happy to
19 reguest it tomorrow. If you want to
20 come up and leave your names I do not
21 have to wait for the transcript. I will
22 have him contact you to start that
23 process rolling.
24 I do not know whether it will
25 result in a full blown assessment or
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2 door to door survey because I do not
3 know how they do their medical
4 evaluations, but it does not require
5 that you petition and it is not going to
6 be they say no. They will come out and
7 talk to you and talk about your
8 concerns.
9 MS. SEPPI: They will be able to
10 tell you what they are able to do and
11 not able to do. All you have to do is
12 request it. It does not have to come
13 from another agency.
14 MS. WOLFSKEHL: I may be wrong
15 but from what I have seen of the site
16 only the plant is fenced in; is that
17 true?
18 MR. HACKLAR: No, the lot that
19 is identified as Lot IB, which was
20 historically the area where the
21 industrial activities occurred that is
22 fenced in and that has been fenced in
23 for at least the last five years or so.
24 MS. WOLFSKEHL: Is that where
25 most of the contaminants were found
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2 also?
3 MR. HACKLAR: The majority of
4 contamination is in Lot 1-B.
5 MS. WOLFSKEHL: All right.
6 MS. SEPPI: Councilman Wahler.
7 COUNCILMAN WAHLER: Councilman
8 Brian Wahler, Ward 2. It was brought to
9 my attention by one of my constituents
10 sitting behind me on Page 17 with the
11 Alternative S-3 you talk about the EPA
12 will also bypass the residential areas.
13 Right now you are using Flemming Street
14 for that. Do you have anywhere that
15 road might possibly go? I have the map
16 where the site is. I think that is on
17 Page 3.
18 MS. SEPPI: Do you want the map
19 up?
20 COUNCILMAN WAHLER: Let our
21 planning division know. Maybe we can
22 work with you on that, where it would
23 the least impact the residents.
24 MR. BILLIMORIA: This is Lot 1-A
25 and on the other side of this stream,
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2 this property there is a narrow strip
3 which is also owned by Tang Reality and
4 it fronts onto, I guess this is New
5 Brunswick Avenue.
6 COUNCILMAN WAHLER: Yes, that
7 would be New Brunswick Avenue.
8 MR. BILLIMORIA: It is a little
9 bit north of cardboard factory. It used
10 to be a drum operation. It is at the
11 corner of the railroad and south
12 Brunswick Avenue. Just north of that
13 there is a little access road that is
14 owned by Tang Realty and that could be
15 used that way, you bypass the apartments
16 or the residences on the other side.
17 COUNCILMAN WAHLER: Maybe could
18 you possibly contact the Mayor's office
19 so we can work with if you do go with
20 that. That might be an acceptable
21 route. I do know the county is going
22 into reconstruct Stelton Road. I am
23 sure you are not talking about starting
24 moving the earth any time soon.
25 MS. SEPPI: We will cooperate
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2 with everyone.
3 COUNCILMAN WAHLER: I agree with
4 all at statements that Assemblyman Smith
5 and some of my colleagues. If the
6 residents want to test their wells I do
7 believe that maybe the responsible party
8 should be picking up the cost of hooking
9 up to the water system.
10 On average if you have someone
11 come anywhere from a thousand to 1,500
12 depending upon the distance and most
13 people do not have a thousand or 1,500
14 to hook up immediately, so please keep
15 that in mind when you do negotiate a
16 settlement.
17 MR. MAGLIETTE: Ralph Magliette,
18 Chairman of Environmental Commission and
19 I have a couple of technical guestions
20 to ask.
21 On Page 6 and 7 we have
22 Contaminants in Surface and Subsurface
23 Soils, a list of contaminants and on
24 Page 7 Contaminants in Groundwater. Can
25 you provide the list what the MCL would
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2 be for each of the contaminants you have
3 listed. Could I get that data because I
4 couldn't look up all the compounds and
5 find them.
6 MR. HACKLAR: We can get that to
7 you. Just for the public's information
8 that would be in EPA' s remedial
9 investigation report, if you have to
10 time to look through it, but we can gets
11 you a copy of the MCL.
12 MR. MAGLIETTE: This table is
13 great but what level do we have to get
14 down to. You never say we need to get
15 down to one part per million or one part
16 per billion. We know what the actual
17 extent of the removal has to be, okay.
18 The other question I have is I
19 am going back to this treatment site you
20 have, going to Page 14. I was under the
21 impression that the pumping and
22 treatment facility as it is now has both
23 an air stripper followed by activated
24 carbon absorption. That being the case
25 why would the Sewage Authority not want
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2 the treated groundwater, if you removed
3 greater than 99 percent of all the
4 organic contaminants, you gave the data,
5 you had a high removal, is there a
6 reason why you think they would not let
7 you pump basically almost portable water
8 in the sewer?
9 MR. HACKLAR: There are several
10 possible reasons. Just being the
11 appearance of Superfund water going
12 through a public collection system,
13 through a treatment plant. Another
14 reason being that it is taking up space
15 in a collection and treatment system and
16 I do know, it is not necessarily with
17 MCUA but other sewage authorities space
18 can be at a premium.
19 MR. MAGLIETTE: Do you feel that
20 50 gallons per minute is an excessive
21 flow rate, that they could not take
22 that.
23 MR. HACKLAR: I do not know what
24 capacity MCUA has. If they are under
25 any restrictions due to any reguirement
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2 by the Clean Water Act. I could not
3 comment on that.
4 MS. WOLFSKEHL: The soils that
5 are contaminated with PCB's, are those
6 also the same hot spots where the
7 organic contamination is?
8 MR. HACKLAR: They are
9 co-located.
10 MS. WOLFSKEHL: If we were to
11 excavate the soil that has both there is
12 a possibility we might have volatile in
13 the air when you put it into the air and
14 put it on the truck.
15 MR. HACKLAR: That is a
16 possibility.
17 MR. MAGLIETTE: I am not
18 familiar with all of the new methods of
19 disposal. Are you going to have
20 completely sealed trucks so you do not
21 have VOC emissions come off the soil
22 when it is trucked away or are you going
23 to put a tarp over it?
24 MR. HACKLAR: At this point we
25 have not made a decision on that. As
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2 the excavation is proceeding there will
3 be procedures to monitor dust and also
4 organic emissions so if we do see a
5 problem we will correct it.
6 MR. MAGLIETTE: If you look at
7 the list of the soils and look at the
8 organics we have carbon tetrachloride
9 which has a very high vapor measurement.
10 If you excavate it and striped all the
11 VOC down it is in the air in an area
12 that is highly densely populated.
13 I understand it is a small
14 amount per say, but my guestion is are
15 you going to build in additional
16 safeguards to protect the residents,
17 what do they normally do?
18 MS. JACKSON: The main
19 suppression method is water or the use
20 of some type of cover, not a fully
21 enclosed vehicle but a tarp.
22 With the low levels we see at
23 the site, I think the risk assessment
24 did not show a risk of inhalation of
25 volatiles at that site so the levels are
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2 not high enough to show a risk. We
3 would be careful, but we would not spend
4 money just to be spending it.
5 MR. MAGLIETTE: When you say you
6 are going to truck the material
7 off-site, are you going to dispose of it
8 and treat it?
9 MR. ROBINSON: We are disposing
10 it.
11 MR. MAGLIETTE: You are taking
12 the contaminated soil from Piscataway
13 and putting it in somebody else's
14 backyard and burying it? You are not
15 detoxifying the soil?
16 MR. HACKLAR: Before any of the
17 soil is disposed of it will be tested to
18 determine if it is in fact a hazardous
19 waste as defined by the Resource
20 Recovery Act.
21 Depending on what the waste is,
22 whether it is classified as hazardous
23 waste or non-hazardous waste that will
24 determine where the material will go.
25 If it is determined to be hazardous
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2 waste and meets the criteria and we have
3 EPA special tests for that then it would
4 go to a facility that is operating in
5 accordance with RCRA.
6 MR. MAGLIETTE: Let us say
7 PCB's which is exguisitely toxic and
8 find some supplier or some waste
9 generator or shipper who is going to
10 take this waste and just bury it
11 somewhere else, are you going to blend
12 it to reduce the concentration of PCB'S?
13 MR. HACKLAR: It would be placed
14 in a commercial RCRA disposal facility.
15 MR. MAGLIETTE: Not that I would
16 want to have the waste treated on site,
17 but is it not better to detoxify the
18 soil? It is almost like you are saying
19 dilution is the solution.
20 We have soil that has x PCB
21 concentration. We are going to mix it
22 in non PCP soil. If we are below the
23 EPA number then it is safe. I would not
24 agree it is better to do it for this
25 site.
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2 MS. JACKSON: We have to look at
3 cost when we look at cleanup
4 alternatives. There is a couple of ways
5 that allows you to get rid of five
6 hundred parts per million. We would be
7 required to incinerate it. We are not
8 talking about levels above that.
9 MR. MAGLIETTE: If you look at
10 Page 6 you have levels of 21 to 2,600
11 and 540 to 310,000 parts per billion so
12 that would be 310 parts per million.
13 MS. JACKSON: That is the
14 highest level in soil. We are not
15 required by law to do the incineration.
16 Land disposal in a commercial facility
17 regulated by the Federal and State
18 government is acceptable. In this case
19 isn't it better the EPA is saying no, we
20 prefer the land disposal. We have to
21 look at cost at this and all the other
22 sites.
23 MR. MAGLIETTE: You have done
24 the ecological risk assessment. I was
25 concerned if sedimentary toxicity
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2 testing had been done.
3 MR. HACKLAR: It was not
4 performed. It was a qualitative and
5 quantitative assessment similar to what
6 we performed for the human health risk
7 assessment, where we looked at
8 reasonable maximum exposures but it was
9 felt at this staqe the actual laboratory
10 tests were not warranted.
11 MR. MAGLIETTE: Would you not
12 postulate that there would be at the
13 very least heavy metals in the sediment
14 of runoff after all these years?
15 My question is twofold. I am
16 not tryinq to bait you on it. Is the
17 fact we may in some future date not be
18 allowed to discharqe to the sewer
19 utility, we are qoinq to be pumpinq 50
20 qallons per minute into the stream. At
21 that flow rate you may have start
22 sediment toxicity testinq, which was not
23 done previously, because you miqht be
24 enhancinq the toxicity as it qoes
25 throuqh the channel because it is a very
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2 shallow
3 MR. HACKLAR: The streams on
4 site, when we talk about streams they
5 are really in essence just intermittent
6 ditches. At certain times of the year
7 they do not have any flow.
8 While there were contaminants
9 detected in the sediment we are
10 addressing the soil and as we go through
11 we do believe that we will be removing
12 the contamination that would be causing
13 any of the problems.
14 You are only talking about
15 sediment here. In essence you are
16 talking about soil just because the
17 streams are in the ditches.
18 MR. MAGLIETTE: Right, but we
19 have no data to base it on. That is all
20 supposition.
21 MR. HACKLAR: The sediment
22 values, the results are compared to
23 toxicity values in the ecological
24 assessment which is really our first
25 step. We would not initially jump to
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2 the laboratory tests at this point.
3 MR. MAGLIETTE: You have
4 reference data that you have made that
5 calculation?
6 MR. HACKLAR: Yes, that is
7 available in the remedial investigation.
8 MS. PICCIUTO: Hi, my name is
9 Rosemary Picciuto. I also am a local
10 residence of Piscataway for 32 years. I
11 live on Charter Street. My children
12 also played to that mound of dirt and I
13 am worried, they are now of child
14 bearing age. we have to worry about the
15 future generation.
16 Also, did you know in 1966 there
17 was a town picnic at this site also to
18 celebrate the 300th anniversary of this
19 township. We had a big picnic. I think
20 we all should have been notified before
21 that this was contaminated and it was a
22 risk to all of us.
23 When I bought my house in 1965 I
24 was not notified. If I want to sell my
25 house today I have to notify the people
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2 I am in a Superfund Site and that
3 decreases the value of my home. I do
4 not think it is fair for you taking so
5 long. I have been living with this for
6 32 years. I will be dead and buried by
7 then.
8 MS. SEPPI: I think someone else
9 had a guestion.
10 MR. COSTELLO: My name is John
11 Costello. I have some guestions about
12 this site. On the excavation are you
13 excavating Lot 1-B or both IB and 1A?
14 MR. ROBINSON: Most of the soil
15 will come from Lot 1-B. Some of the
16 excavation will come from Lot 1-A also.
17 MR. COSTELLO: Just the part of
18 1A around IB basically?
19 MR. ROBINSON: Basically.
20 MR. COSTELLO: How far down are
21 you going to excavate?
22 MR. ROBINSON: Well, --
23 MR. COSTELLO: You are saying
24 18,600 cubic yards. I am not sure what
25 that is going to translate into.
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2 MR. ROBINSON: It varies from
3 area to area basically based on soil
4 testing that we have done and for each
5 particular area and it is all in the
6 remedial investigation.
7 For some areas we might to go
8 two feet, for some areas four feet and
9 other areas six feet. It varies.
10 MR. COSTELLO: Would it be fair
11 to say six feet is the deepest you are
12 planning to go?
13 MR. ROBINSON: Basically, yes.
14 MR. COSTELLO: About how long
15 after the excavation is done would
16 houses potentially start going up if
17 approvals were made?
18 How guickly after you finish the
19 excavation could houses be built or
20 would we have to wait for the 30 years
21 for the ground groundwater also?
22 MS. JACKSON: There would not be
23 a restriction on time. I do not think
24 there is any way I could guess the
25 timeframe. My guess it would be
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2 difficult to have an attractive piece of
3 property while the treatment plant is
4 operating so it is really impossible for
5 me to give you an answer to that
6 guestion.
7 MR. COSTELLO: Well, then the
8 allotted time is 30 years, then would it
9 be fair to say that it probably would
10 not be off the NPL list until 30 years
11 from now or sometime or would it
12 probably be off sometime before that.
13 MS. JACKSON: Let me clarify one
14 point. The 30 years in the plan for
15 groundwater pumping and treatment is not
16 an estimate of how long it will take to
17 clean up the site.
18 Because of the fractured bedrock
19 underneath it, it is really rock with
20 cracks and fissures running through it,
21 contaminants get trapped in spaces, it
22 does not take a lot of contamination to
23 detect a part per billion or two.
24 So what we have tried to do
25 here, and I think it is a very important
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2 point, I have been kind of itching to
3 say, in our objectives is to pump as
4 much of the water from the site facility
5 as we can very aggressively and we are
6 saying five wells could be worked out in
7 design to try to remove the
8 contamination but also to insure that
9 the contamination does not leave those
10 facility's boundaries.
11 It is very difficult for our
12 scientists and Mr. Billimoria could
13 probably speak for hours. He said he
14 could probably write another
15 dissertation on it to come up with a
16 timeframe. While MCL's are important,
17 our first goal is to try to pump it and
18 try to see what response we get.
19 It could be longer than 30 years
20 or it could be shorter than 30 years.
21 MR. COSTELLO: You have no way
22 of knowing until you have done the
23 process and you will check every five
24 years. If it is done in five years then
25 it would be ready for the houses.
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2 MS. JACKSON: It would be ready
3 to start the deletion from the NPL list.
4 MR. COSTELLO: How long does
5 that take to delete it?
6 MS. JACKSON: It requires by law
7 we publish notice in the public register
8 and allow for 60 days of public comments
9 and final notice where we hereby notify
10 one and all this site is hereby off the
11 list.
12 MR. COSTELLO: That process
13 about six months.
14 MS. JACKSON: About.
15 MR. COSTELLO: How deep is the
16 contamination, how far down?
17 MR. HACKLAR: The contamination
18 goes down several hundred feet, the
19 groundwater contamination.
20 MR. COSTELLO: What about the
21 soil contamination?
22 MR. HACKLAR: The soil there is
23 roughly 10 feet or less of soil
24 throughout the site and we are looking
25 at contamination, like I said, roughly
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2 probably six feet or so.
3 MR. COSTELLO: Up to six feet is
4 what you are planning to excavate?
5 MR. HACKLAR: Roughly.
6 MR. COSTELLO: Say it is all
7 cleaned up and off the priorities list
8 and houses are ready to be built, there
9 are going to be basements, holes dug in
10 the ground for basements.
11 Okay, and I believe that they
12 would be going down more than the six
13 feet. What happens to the another four
14 feet that you are talking about? There
15 is 10 feet of soil, you know, where the
16 contamination is.
17 MR. HACKLAR: What we have
18 observed at the site is that when you
19 are talking about the subsurface you get
20 infiltration through rain and then what
21 you really get, you get a flushing of
22 contaminants into the groundwater
23 because the site has been around for so
24 long.
25 What we are finding is
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2 relatively speaking that the groundwater
3 is more contaminated than the soil.
4 When the groundwater pumps and treatment
5 is expanded and is running what you will
6 essentially find is really almost a
7 dewatering of the area. In effect any
8 water that is coming in will most likely
9 migrate downward and will be captured by
10 the pump and treat system, so the
11 potential threat from contaminated
12 basements would obviously be from any of
13 the groundwater, but the groundwater
14 would be controlled.
15 MR. COSTELLO: Let me see if I
16 understand this now. Basically you are
17 going to take out the excavated soil, a
18 certain amount of soil?
19 MR. HACKLAR: That is correct.
20 MR. COSTELLO: You are going to
21 remove or treat the groundwater?
22 MR. HACKLAR: Right.
23 MR. COSTELLO: As you have less
24 and less contamination in the
25 groundwater is it safe to assume there
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2 is less and less contamination in the
3 subsoil?
4 MR. HACKLAR: We will be
5 removing all the soil that would have
6 posed a threat. One of the pathways we
7 looked at in the risk assessment was any
8 risks to construction workers out at the
9 site or workers that would be digging
10 holes for whatever reason, for basements
11 or whatever, and we feel that through
12 what we are proposing today, that any of
13 those risks would be addressed before
14 anything would be built on site.
15 MR. COSTELLO: So like all this
16 contaminated stuff that would be left in
17 the subsoil would tend to filter down to
18 the groundwater?
19 MR. HACKLAR: There would not be
20 a contamination that would pose a risk.
21 MR. COSTELLO: I understand
22 that. What happens to all these things
23 as it continues to filter down?
24 MR. HACKLAR: Whatever minimal
25 amount would be in the subsurface would
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2 continue to basically migrate downward
3 as rain water and filtration would
4 percolate there.
5 MR. COSTELLO: That is about it
6 since we talked in great detail on the
7 groundwater and I kind of understand
8 that now.
9 I would also like to say the
10 more you can do to protect the site the
11 better. That is what I want to say.
12 MS. MASON: My name is Phyllis
13 Mason I am running for Assembly in this
14 district and giving myself a guick crash
15 course on toxic sites because we seem to
16 have several of them.
17 I have a few guestions and I
18 will be as fast as I can. First of all,
19 your plan shows Stream 1A and Stream IB
20 all flowing, merging through the site
21 and presumably continuing north. Where
22 do they go?
23 MR. HACKLAR: Ultimately the
24 streams and ditches could be tributaries
25 to the Bound Brook. They ultimately go
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2 to, I believe it is here. You can
3 correct me if I am wrong. It Goes to
4 New Market Lake, which really down
5 stream ultimately goes to the Raritan
6 River.
7 MS. MASON: I figured that was
8 perhaps where they went if they were
9 going north. The reason I am asking
10 that guestion is I know with the PCB's
11 from South Plainfield flowing into the
12 Bound Brook they are testing far beyond
13 the borders of the site and in fact the
14 boarders past New Market Pond for PCB's
15 and I am wondering before you clean it
16 up if you will also extend and do some
17 testing beyond this site of the Bound
18 Brook and along it to make sure nothing
19 has gotten out there.
20 MS. JACKSON: I am thinking, the
21 areas of the Bound Brook -- you are
22 asking for sampling of areas of the
23 Bound Brook that are not being sampled.
24 We are doing an extensive sampling along
25 the Hamilton Industrial Park site.
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2 MS. MASON: At least up to it.
3 MS. JACKSON: We will know, I
4 guess, whether there are PCB's in the
5 Bound Brook. I think we suspect there
6 are.
7 MS. MASON: This stream or
8 network of streams following the stream,
9 following up to the Brook, I do not know
10 where it really goes.
11 MS. JACKSON: If these were
12 streams and ran above ground and we
13 could say they were running into the
14 Bound Brook and contributing to it I
15 would say of course it would have been
16 part of the study.
17 The levels of PCB's found in
18 those ditches and streams were very low.
19 They did not pose a threat to warrant us
20 taking an action in the stream. Now, I
21 suppose the only other guestion is in
22 the past were there any levels.
23 What I would like to is sit down
24 with the guys. We actually scheduled a
25 meeting a couple of days ago. Once they
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2 get the results back from their Bound
3 Brook samples, we will sit down and look
4 at it. We are thinking along those
5 lines and I do not know what the answer
6 is to the guestion.
7 MS. MASON: My second guestion
8 has to do with risk and the concept of
9 potential risk. This has already been
10 raised, but the plan talked several
11 times about potential risk to humans and
12 also potential risk to wildlife in
13 particular three different species of
14 birds.
15 I do not remember which they
16 were. I remember there were three of
17 them. Now, since this plant has been in
18 existence since the 50's and these toxic
19 chemicals have been produced and flowing
20 wherever they go and going wherever they
21 go, although you do not take surveys
22 does anybody look at medical records for
23 higher incidents of cancer in this area?
24 No. 2, are there any kind of
25 records of an abnormally large number of
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2 dead birds, mutated birds, anything like
3 that that might indicate if you are
4 going to assess the risk and come up
5 with an alternative to solve the problem
6 I would think that you really have to
7 try to find out what has taken place so
8 far, what harm has actually taken place.
9 MS. JACKSON: The agency I
10 mentioned before would do the evaluation
11 of that. We are going to petition to
12 see what they can do at this site. On
13 the fish and wildlife side I do not have
14 any specifics because again I am an
15 engineer, but the sites I have worked on
16 where we have had severe impacts to fish
17 and wildlife, in those cases you can do
18 studies of fish living in the stream and
19 wildlife living around the area.
20 Because of the type of area this is we
21 are not talking about a lot of species
22 so I could not see it doing it.
23 MS. MASON: My last two
24 guestions have to do with disposal and I
25 think they are pretty fast. This is a
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2 really genuine question. When you talk
3 about the MCUA might not accept this
4 flow why might they not accept it? Is
5 it because of their capacity or because
6 of the toxicity or what?
7 MR. HACKLAR: I cannot speak for
8 MCUA. I am not sure at this point
9 whether it is a capacity issue. In
10 other utility authorities there are
11 capacity issues. It could be that.
12 They are under a discharge
13 permit to discharge their water and they
14 could possibly be concerned about levels
15 of effluents or in their treatment plant
16 they have to deal with the sludge they
17 generate. They could be concerned with
18 that or it could possibly be a
19 perception issue, just-accepting waste
20 water.
21 I do know as of several years
22 ago, and again I have not had contact
23 with personnel from MCUA in recent
24 times, but their policy on Superfund
25 waste water or groundwater is if there
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2 was another option for the groundwater
3 then they would be very reluctant to
4 take the water themselves?
5 For example, if there was the
6 option to discharge in a surface water
7 body they would be reluctant to take the
8 water themselves. That is why the
9 system that is out there today was
10 designed to basically go either way.
11 We are currently discharging to
12 the sewer system. The whole treatment
13 process and the outflow pipe is in place
14 to discharge to the stream if that were
15 to be the case.
16 MS. MASON: My final guestion is
17 somebody raised a concern earlier about
18 dirt removal and dirt blowing off trucks
19 and through residential neighborhoods
20 and so forth.
21 It occurred to me looking at the
22 map since you have a railroad going
23 right by the site have you considered
24 putting the dirt in closed cars and
25 taking it out of the my cars and to the
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2 railroad.
3 MS JACKSON: That was my
4 question and they laughed at me because
5 it must been looked at and it is not an
6 inexpensive proposition. 18,000 cubic
7 yards sounds like a lot of dirt. It is
8 not a huge amount compared to some
9 places, so trucking would be much more
10 economical and would probably be the
11 best way.
12 I can't remember when you walked
13 the rails what was your final
14 determination?
15 MR. BILLIMORIA: it can be done
16 but there is a lot of steps you would
17 have to go through. You would have to
18 consider rail accidents like the one
19 that occurred not very far from that
20 location just a few weeks ago.
21 MS. MASON: That is true, but of
22 course there could be a truck accident
23 MR. BILLIMORIA: I know that.
24 MR. HACKLAR: I walked with
25 Meyhear the railroad that day.
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2 Theoretically it is doable. It would be
3 expensive. It would take a lot of
4 coordination with the railroad itself.
5 We would probably have to build
6 a new site. There would be issues in
7 terms of bringing, of actually digging
8 the soil out, putting it on let it say a
9 truck to transport it to the site that
10 we would build and loading it on a car
11 there. There would be a lot of
12 intermediate steps before you would get
13 it onto the railroad car.
14 MS. MASON: What if it were done
15 with containers?
16 MS. SEPPI: It would still be
17 the same problem. You would have to
18 truck it to the site, put it in the rail
19 cars, put it into another truck to get
20 it to your permitted landfill.
21 MR. HACKLAR: Also where the
22 site, just by necessary would need to be
23 placed, would it be located close to
24 when the land areas which would entail
25 building a good access road to the site.
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2 It is an alternative that could be done,
3 but it is not easily inplementable. The
4 trucking alternative is much more
5 implementable.
6 MS. SEPPI: Okay, just keep it
7 in mind. Before we go on could I just
8 have a show of hands of how many more
9 people want to speak? Our court
10 stenographer probably needs a break.
11 (A short recess was taken.)
12 MS. SEPPI: If everyone is ready
13 let us go on with the rest of the
14 guestions.
15 FREEHOLDER FERNICOLA: I am
16 Camille Fernicola, Freeholder and former
17 Piscataway Councilwoman. I become a
18 Councilwoman in 1979 and right after
19 that I remember a young man came to us
20 who lived in the neighborhood around the
21 Chemsol site and his name is was Ralph
22 Magliette and he is now our
23 Environmental chairman and he has been
24 for many years and Ms. Wolfskehl brought
25 to us the problem of leaching and all
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2 the chemicals at that time a housing
3 development was proposed and they as
4 ordinary citizens were very concerned
5 about their neighborhood and township
6 and brought it to our attention and
7 Assemblyman Smith was a Councilman at
8 the time and he later become Mayor and
9 we have been dealing with this obviously
10 for many years.
11 The first ten years or so
12 nothing was done physically on the site.
13 It was going around in the courts. The
14 lawyers were sending their grandchildren
15 to college and it just went on and on
16 and I remember the voters also adopted
17 the Chemsol Site as their own and made
18 it a point to have an annual program.
19 It was about seven or eight years ago we
20 really saw movement.
21 Several years ago the Mayor and
22 council had the opportunity, we were
23 invited to view the site and the
24 transformation was wonderful. Many
25 people are still upset, and I cannot
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2 blame them, for the health of their
3 family, especially the ones that have
4 been there for many years, but like I
5 said the transformation that we see now,
6 there is grass growing, the plant is
7 cleaning up the water.
8 Yes, it may take 30 more years,
9 but at least something is being done and
10 I thank you for coming tonight. You are
11 a very fine team that I can see and it
12 looks like you are on top of everything.
13 You are working hard at making the
14 Chemsol Site a Superfund Site of the
15 past and back in 1979 nobody ever heard
16 the term Superfund and now it rolls off
17 everybody lips. Soon we hope that this
18 Superfund Site will die a death and we
19 will all have a party.
20 Thank you, very much for all the
21 information you have given us tonight.
22 MS. SEPPI: Thank you. One
23 thing I would like to say is Superfund
24 become a law in 1980. That is why no
25 one heard of it in 1979.
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2 That is why we did not do
3 anything. EPA did not start until 1970
4 and Superfund 1980 and 1984. It still
5 has been a long time but your right some
6 things have been accomplished and
7 hopefully this will be the end of things
8 FREEHOLDER BRADY: I am Jane
9 Brady, Freeholder/Director of Middlesex
10 County. I want to thank you for being
11 here and straightforward with all of
12 your information.
13 You have to understand, of
14 course, Middlesex County has 12
15 Superfund Sites. We have more than any
16 county. We are greatly concerned about
17 not only Chemsol but the other sites as
18 well, also guite honestly the length of
19 time that it is taking for the EPA to
20 get around to these sites and the
21 damaged is around the county.
22 I encouraged you to move as
23 guickly as possible to make sure
24 everything is taken care of. We are
25 gravely concerned. So many of our
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2 sites, some of them have been removed
3 from the priority list. I urge you to
4 please use your influence to encourage
5 more cleanup in Middlesex County so we
6 can feel more comfortable to use them
7 for recreational purposes or whatever
8 might be the best use. The MCUA have
9 they indicated to you they will not
10 accept this water, or is this just a
11 possibility? I would like that
12 clarified, if possible.
13 MR. HACKLAR: At this point we
14 have not had direct contact with them on
15 this matter. At this point it is a
16 possibility.
17 FREEHOLDER BRADY: They have not
18 said no?
19 MR. BACKLAR: We have not had
20 contact with them.
21 FREEHOLDER BRADY: Thank you,
22 very much.
23 COUNCILMAN STEWART: I just had
24 one final comment I wanted to make and I
25 remember making the same point at the
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2 time Ms. Fernicola went to visit the
3 brand new facility cleaning up the site.
4 As you pointed out your agency did not
5 really exist until 1970 and the
6 Superfund Law did not go into effect
7 until 1980.
8 This plant was there in the
9 1950's causing that contamination. That
10 was sort of a heyday of industrial
11 growth with little or no regulations. I
12 know Assemblyman Smith when his party
13 was in the majority party and he worked
14 very hard too make sure that New Jersey
15 had adeguate regulations to prevent that
16 sort of thing, but I know more recently
17 there has been more talk of deregulation
18 and certain feelings that maybe industry
19 is regulated too much, there is over
20 regulation and it is more than
21 necessary, but as a counter argument all
22 I have to do is point to the Superfund
23 Site in my ward.
24 Whereas the Freeholder Director
25 was pointing out the 12 sites in
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2 Middlesex County I would like to put on
3 to the official record my hope that the
4 taxpayers take these Superfund Sites as
5 a message that we in fact need
6 regulations, government regulations at
7 the state and federal level to insure
8 the guality of our environment and the
9 guality of all of our lives and
10 children's lives so never again will we
11 have to listen to the impassioned
12 please, my children played there and
13 about township picnics, on that how
14 could this be.
15 This came about because of the
16 lack of adeguate regulations. I just
17 want to make sure I get that on to the
18 record. Thank you, very much.
19 MR. COSTELLO: I had one final
20 guestion. After you excavate the soil
21 you are going to put new soil down, I
22 presume. Where are you going to be
23 getting that soil from?
24 MR. ROBINSON: The soil WILL be
25 coming from some off-site facility. We
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2 do not know where yet, but wherever it
3 comes from the soil will be tested to
4 make sure it is clean before it is
5 brought to the site.
6 MR. COSTELLO: Could it be soil
7 that had been previously contaminated
8 and now officially clean, could that be
9 a possibility?
10 MR. ROBINSON: Highly unlikely.
11 We basically do not go through that
12 route. We normally just go to an area
13 and take virgin soil, but we test it
14 before we bring it to the site.
15 MR. COSTELLO: Take part of a
16 mountain and put it there?
17 MS. SEPPI: There are plenty of
18 facilities in New Jersey that we get
19 soil from for our sites, let alone going
20 to another site if we had to.
21 MR. COSTELLO: If it is deemed
22 really hazardous this soil that you are
23 going to be excavating from the site
24 where exactly does it go?
25 MR. ROBINSON: If it is deemed
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2 really hazardous it will end up at what
3 we call a RCRA facility, which is
4 regulated by the State and Federal
5 government.
6 MR. COSTELLO: Where is the
7 closest one to Piscataway?
8 MR. ROBINSON: I am not sure.
9 MR. BILLIMORIA: We did not use
10 any particular one.
11 MS. JACKSON: Just estimated
12 distance.
13 MR. BILLIMORIA: I understand
14 there is possibly one in Pennsylvania.
15 MR. COSTELLO: I heard there is
16 a large one in Alabama.
17 MS. JACKSON: Yes. Thank you.
18 MR. SCHANCK: I just have a
19 couple of questions. Thank you. My
20 flame is Garrett Schanck. I am a home
21 owner and I just have a couple of
22 guestions for clarification on that
23 business of the statistical analysis
24 here of 2.2 per thousand.
25 If a person, such as a child,
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2 people are concerned about that were
3 playing on that for a few years, okay,
4 how does that compare to this risk
5 assessment here which the way I
6 interpret it, if I am not wrong here, if
7 you have 2.2 per thousand over 70 years,
8 is that a continual 70 years exposure?
9 MS. SEPPI: Yes.
10 MR. SCHANCK: Let us say you had
11 a homeless guy sitting out there for say
12 70 years, two of them statistically
13 would get cancer?
14 MR. HACKLAR: Yes.
15 MR. SCHANCK: That is what you
16 are saying to is the risk to that site?
17 MS. JACKSON: Yes
18 MR. SCHANCK: It seems kind of
19 small. Obviously if someone gets cancer
20 they are very concerned. The other
21 thing is the last time I was here and
22 this time there was a lot of information
23 or a lot of discussion on why it took so
24 long. There is a woman out there almost
25 in tears going out of here very upset
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2 about why it took so long, lawyers
3 haggling about what-have-you, is it a
4 possibility why this took so long, one
5 of reasons was because you had to find a
6 person to pay for this thing like Tang
7 Realty?
8 Did it take so long because by
9 law you had to find somebody at fault or
10 could this money just come straight out
11 of the Superfund money and been taken
12 care of 20 years ago.
13 MR. HACKLAR: What happens is
14 that the site was placed on EPA's
15 National Priorities List in 1983. Once
16 that happens the government can spend
17 money on the site to investigate and to
18 clean up the site.
19 Now, what happened during the
20 1980's the site was being investigated
21 initially by the site owner, Tang Realty
22 and the NJ DEP was overseeing that
23 investigations. Data was collected,
24 material was removed from the site, but
25 because it was taking the site owner a
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2 very long time to do their
3 investigations, both DEP and EPA jointly
4 decided it would be in the best interest
5 of the project to get it really moving
6 along to basically transfer the site to
7 EPA and have EPA perform the studies
8 itself.
9 MR. SCHANCK: What year was
10 that?
11 MS. SEPPI: That was 1990.
12 MR. SCHANCK: Okay, I
13 understand. I guess the last guestion I
14 have, a LOT of people are concerned
15 about transportation of soil in case a
16 dump truck dumps it on the ground. I am
17 kind of curious I guess PCB's is the
18 biggest concern?
19 MR. HACKLAR: PCB's and lead.
20 MS. WOLFSKEHL: If this soil
21 overturns what is the risk if you are
22 talking 70 years to be a problem, if a
23 dump trucks dumps over accidentally for
24 whatever reason, an accident or whatever
25 it is a big two tons of soil being
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2 picked up in a matter of what, a couple
3 of hours?
4 That is a far cry from 70 years.
5 I mean it seems to me maybe we are a
6 little bit over concerned there. It
7 just seems to me, that is just my
8 opinion on that. That is it. Thanks
9 very much. I appreciate your time.
10 MS. SEPPI: Thank you.
11 Are there any other questions?
12 (No response.)
13 MR. SEPPI: All right. Well, we
14 thank you again for coming. You have
15 the names and phone numbers on the
16 proposed plan. Do not hesitated to call
17 any of us at any time.
18 If anybody has information they
19 want to give us about a well they need
20 tested please come up and if anybody is
21 interested in the ATSDR we can give you
22 that number also. Thank you.
23 (Whereupon, at 9:30 o'clock p.m.
24 the proceedings were concluded.)
25
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1
2 CERTIFICATE
3 STATE OF NEW YORK )
) ss.
4 COUNTY OF NEW YORK )
5 I, TINA DeROSA, a Shorthand
6 (Stenotype) Reporter and Notary Public
7 of the State of New York, do hereby
8 certify that the foregoing Proceedings,
9 taken at the time and place aforesaid,
10 is a true and correct transcription of
11 my shorthand notes.
12 I further certify that I am
13 neither counsel for nor related to any
14 party to said action, nor in any wise
15 interested in the result or outcome
16 thereof.
17
18
19
20
21
22
24
25
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Chemsol, Inc. Superfund Site
Responsiveness Summary
Appendix - B
Written comments received by EPA during the
public comment period
PITNEY, HARDIN, Kipp & SZUCH
(MAIL TO)
P.O. BOX 1945
WILLIAM H. HYATT, JR. MORRISTOWN, NEW JERSEY 07962-1945 152 WEST 57th STREET
NEW YORK, N.Y. 10019-3310
DIRECT DIAL NUMBER (DELIVERY TO) (212) 371-8880
(201) 966-8041 200 CAMPUS DRIVE FACSIMILE (212) 371-8540
FLORHAM PARK, NEW JERSEY 07932-0950
(973) 966-6300
FACSIMILE (973) 966-1550
October 10, 1997
VIA HAND DELIVERY
Nigel Robinson
Project Manager
U.S. Environmental Protection Agency
290 Broadway, 19th Floor
New York, New York, 10007
Re: Comments on Remedial Investigation, Feasibility Study, and Proposed Plan Chemsol, Inc. Superfund Site,
Piscataway, New Jersey
Dear Mr. Robinson:
Enclosed, on behalf of the Chemsol PRP Group (the "Group"), are a Technical Review of the Remedial
Investigation Report 1 and Comments on the Feasibility Study ("FS") and Proposed Plan for the Chemsol, Inc.
Superfund Site (the "Site"). The comments address the proposed remedies for both soil and groundwater at the
Site. Also, an Evaluation of Groundwater Extraction Alternatives is appended in support of the comments.
Upon review of the RI, FS and Proposed Plan, the Group concludes that the proposed soil remedy of excavation
and disposal will not achieve the remedial action objective to allow for future site use without
restrictions. Furthermore, the proposed remedy is not supported by the administrative record. In contrast,
the selection of soil capping as the remedial alternative is supported by the administrative record. In
particular, capping is protective of human health and the environment, would satisfy federal and state soil
cleanup criteria, is recommended by USEPA guidance, and is consistent with realistic options for any future
site use based on development constraints.
If the USEPA rejects the recommendation of the Group that capping be selected as the remedial alternative for
soils, as supported by these comments, at a minimum, the USEPA should consider a soil remedy composed of
selective excavation, a soil cap, and deed restriction. Such a remedy would remove those soils perceived by
the community to present a risk, cap soils above federal and state cleanup criteria, and restrict site access
to preserve the Site's use as open space. The Group believes that the State of New Jersey and the Township of
Piscataway may prefer such a remedy, which would meet their objectives. In particular, by capping the site,
the State's PCB criterion would be satisfied. By retaining restrictions on the Site, inappropriate
residential use could be avoided, so that future site use would be recreational, as preferred by the
Township.
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The comments regarding the proposed groundwater remedy, in part, similarly address the inability of the
proposed remedy to achieve the remedial action objectives. Specifically, as acknowledged by the FS, geologic
and contaminant-related factors indicate that aguifer restoration is highly unlikely at the Site.
Conseguently, a waiver of ARARs based on the technical impracticability of restoring groundwater should be
granted. Because groundwater cannot be restored, the remedial action objective should be to contain
contaminated groundwater to protect human health and the environment. Under a containment remedial action
objective, extraction geared to achieve mass reduction would result in no additional protection of human
health and the environment beyond that provided by a system designed for containment alone. Accordingly, the
remedial action objectives should be revised to delete any reguirement to restore the groundwater and to
remove mass, beyond that removed by containment.
The comments regarding the proposed groundwater remedy also identify several deficiencies in the
administrative record that render the proposed remedy unsupported. In particular, because the proposed remedy
is based on a "preliminary" groundwater model, the description of the remedy selected in the Record of
Decision ("ROD") should permit adeguate flexibility to allow the incorporation of the findings of a refined,
calibrated groundwater flow model into design of the extraction system, adeguate capture zones, the long-term
monitoring program, and the off-site delineation investigation.
Finally, the comments address certain reguirements of the proposed groundwater treatment system. First, the
proposed remedy fails to consider the significant discharge constraints presented by the current discharge
permits. If the proposed remedy is selected in the ROD, the ROD should provide adeguate flexibility in the
design of the extraction system to allow for discharge within the existing permit limits. Second, the
reguirement to operate the biological treatment plant if the treated groundwater is discharged to surface
water is unnecessary. In the groundwater treatment plant's current configuration, there have been no
exceedences of the surface water discharge standards for soluble organics. In addition, the concentrations of
soluble organics in the plant effluent have decreased substantially. Based on these factors, as further
detailed in the comments, the biological treatment plant does not need to be operated to achieve discharge to
surface water standards and the reguirement to operate the biological treatment plant should be eliminated.
The Group would be pleased to meet with you to discuss these comments or to provide any assistance reguired
to select an appropriate remedy. Provided the final remedy selection reflects a consideration by USEPA of
these comments, the Group, or a significant number of its current members, would expect to offer to perform
and pay for that remedy in the context of a negotiated consent decree. We look forward to the opportunity to
work with you to implement such a remedy.
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PITNEY, HARDIN, Kipp & SZUCH
(MAIL TO)
P.O. BOX 1945
WILLIAM H. HYATT, JR. MORRISTOWN, NEW JERSEY 07962-1945 152 WEST 57th STREET
NEW YORK, N.Y. 10019-3310
DIRECT DIAL NUMBER (DELIVERY TO) (212) 371-8880
(201) 966-8041 200 CAMPUS DRIVE FACSIMILE (212) 371-8540
FLORHAM PARK, NEW JERSEY 07932-0950
(973) 966-6300
FACSIMILE (973) 966-1550
October 10, 1997
Paul Harvey
New Jersey Department of Environmental Protection
401 East State Street
Trenton, New Jersey 08625
Re: Comments on Remedial Investigation, Feasibility Study and Proposed Plan
Chemsol, Inc. Superfund Site, Piscataway, New Jersey
Dear Mr. Harvey:
Enclosed is a copy of the comments provided on behalf of the Chemsol PRP Group to the USEPA regarding the
above-referenced documents. This copy is being provided directly to you as a courtesy to the NJDEP and the
USEPA.
Very truly yours,
WILLIAM H. HYATT, JR.
cc: L. Jackson, USEPA
N. Robinson, USEPA
P. Seppi, USEPA
A. Wagner, USEPA
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COMMENTS ON THE FEASIBILITY STUDY AND PROPOSED PLAN
CHEMSOL, INC. SUPERFUND SITE
PISCATAWAY, NEW JERSEY
Prepared on behalf of:
Chemsol Site PRP Group
September 1997
CONTENTS
1. 0 INTRODUCTION 1-1
2. 0 COMMENTS REGARDING PROPOSED SOIL REMEDY 2-1
2.1 The remedial action objective to allow for future site use without restrictions cannot be
achieved by the proposed soil remedy 2-1
2.1.1 Because the proposed soil remedy would not achieve the State soil cleanup
criteria, it cannot satisfy the remedial action objective to allow for future site use
without restrictions 2-1
2.1.2 If the remedial action objectives are revised to consider the State soil cleanup
criterion, a new remedial alternatives analysis must be performed to comply with
the NCP, as a remedial alternative which complies with the State's soil cleanup
criterion was not previously evaluated and is expected to result in significantly
greater costs and increased risk to human health and the environment 2-2
2.1.3 The proposed soil remedy cannot satisfy the remedial action objective to allow
for future site use without restrictions based on the significant present and
anticipated future environmental and physical development constraints located on
the Site 2-3
2.2 The selection of the proposed remedy is not supported by the administrative record 2-4
2.2.1 By reguiring the soil be disposed as a hazardous waste, the Proposed Plan
proposes a remedy not evaluated by the FS, contrary to the reguirements of the
NCP 2-4
2.2.2 Should soil, sampling during remedial design reveal a larger volume of soil
reguiring excavation, the remedy must be re-evaluated as the selection would not
be based on all relevant facts, information, and alternatives 2-5
2.2.3 Stockpiled soils meeting the criteria for backfill should not be reguired to be
disposed of, but should be permitted to be used as backfill 2-5
2.3 A selection of soil capping as the remedial alternative is supported by the administrative
record 2-6
2.3.1 The Proposed Plan is not consistent with the USEPA guidance on which soil
cleanup levels were based; conseguently, the remedy selection should be
reconsidered as these guidance documents recommend capping for sites with
contaminant concentrations at the levels present at the Chemsol site 2-6
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2.3.1.1 The Proposed Plan does not follow USEPA's Guidance on Remedial
Actions for Superfund Sites with PCB Contamination which states that, for
sites with future residential use scenarios, capping is typically the
preferred remedial alternative where PCB concentrations are below 100
ppm 2-6
2.3.1.2 The lead cleanup standard adopted in the Proposed Plan is not consistent
with the procedures set forth in USEPA's Revised Interim Soil Lead
Guidance for CERCLA Sites and RCRA Corrective Action Facilities,
upon which the cleanup standard is purportedly based, and, therefore,
the remedy selection should be re-evaluated to conform with the
guidance 2-8
2.3.2 The FS and Proposed Plan overestimate the costs of capping, resulting in an
invalid cost comparison of remedial alternatives 2-9
3. 0 COMMENTS REGARDING PROPOSED GROUNDWATER REMEDY 3-1
3.1 Geologic and contaminant-related factors dictate that a Technical Impracticability ARAR
waiver should be granted and the remedial action objective be revised accordingly to seek
containment of the contaminated groundwater 3-1
3.2 The remedial action objectives in the Proposed Plan must conform to those in the FS
because the remedy selection is based on the screening and evaluation of alternatives
presented in the FS 3-6
3.3 The USEPA uses a "preliminary" groundwater model in its remedy selection, resulting in
misinterpretation of key model parameters and, conseguently, a remedy selection process
based on incomplete and, at times, inaccurate information 3-7
3.4 The capture zones should be defined by a refined, calibrated groundwater model 3-13
3.5 Off-site delineation sampling should be limited to the area downgradient of the Site, as
defined by the refined groundwater model 3-14
3.6 The final remedy must consider the significant constraints on the groundwater treatment
plant discharge 3-14
3.7 The reguirement to operate the biological treatment plant if the groundwater treatment
plant discharges to surface water has no technical basis 3-15
3.8 A refined, calibrated groundwater model should be used to develop any long-term
monitoring program 3-16
4 . 0 CONCLUSION 4-1
5 . 0 REFERENCES 5-1
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1.0 INTRODUCTION
A Feasibility Study ("FS"), dated June 1997, was prepared by CDM Federal Programs ("CDM") on behalf of the
USEPA for the remediation of contaminated groundwater, soils, surface water and sediments at the Chemsol,
Inc. Superfund Site (the "Site" or "Chemsol site"), located in Piscataway, New Jersey. As stated in the FS,
the "primary objective of the FS [was] to provide [the United States Environmental Protection Agency
("USEPA") and the New Jersey Department of Environmental Protection "NJDEP")] with sufficient data to select
feasible and cost-effective remedial alternatives that protect public health and the environment from
potential risks posed by contamination in groundwater, soils, surface water and sediments" at the Chemsol
site. Accordingly, the FS included a presentation of the results of the Remedial Investigation ("RI"), as
well as an identification, screening, and evaluation of remedial alternatives. Based on the FS, in August
1997, USEPA issued a Proposed Plan for the Chemsol site.
The Proposed Plan recommends preferred alternatives to address soil and groundwater at the Site. The proposed
alternative for soil consists of excavating contaminated soil and disposing of it at an approved disposal
facility. This alternative was preferred by USEPA over a soil capping alternative, which includes covering
the site with a layer of clean soil to prevent contact with contaminated soils. The proposed alternative for
groundwater consists of extracting and treating groundwater at an extraction rate in excess of that of the
interim remedy. Treated water would be discharged either to the Middlesex County Utilities Authority ("MCUA")
or to a nearby The National Contingency Plan ("NCP") reguires the reconsideration of the preferred
alternative if:
[a]fter publication of the proposed plan and prior to adoption of the selected remedy in the record of
decision ... new information is made available that significantly changes the basic features of the
remedy with respect to scope, performance, or cost, such that the remedy significantly differs from
the original proposal in the proposed plan and the supporting analysis. 40 C.F.R. °
300.4310(f)(3)(ii).
Further, principles of administrative law reguire that agency "engage in 'reasoned decision making.'" United
States v. Garner, 767 F.2d 104, 118 (5th Cir. 1985). Decisions must be "based on a consideration of the
relevant factors" and will be reversed for a "clear error in judgment." Citizens to Preserve Overton Park
Inc. v. Volpe, 401 U.S. 402, 416 (1971). The agency must not:
rel[y] on factors which Congress has not intended it to consider, entirely fail[] to consider an
important aspect of the problem, offer[] an explanation for its decision that runs counter to the
evidence before the agency, or is so implausible that it could not be ascribed to a difference in view
or the product of agency expertise." Motor Vehicle Mfr. Assoc. of the United States, Inc. v. State
Farm Mutual Auto. Ins. Co., 463 U.S. 29, 43 (1983).
Instead, the agency must consider all relevant facts, information and alternatives, Citizens to Preserve
Overton Park Inc., v. Volpe, 401 U.S. at 416, comply with its own regulations and procedures, 2 Montilla v.
Immigration and Naturalization Serv., 926 F.2d 162, 166-67 (2d Cir. 1991); Frisby v. United States Dept of
Housing and Urban Dev. (HUD), 755 F-2d 1052, 1055 (3d Cir. 1985), and adeguately explain its decisions by
providing a rational connection between the facts and the resultant decision. Sierra Club v. United States
Army Corps of Engineers, 772 F.2d 1043, 1051 (2d Cir. 1985).
Similarly, the Ninth Circuit held that the agency should have reexamined the remedy selection when the volume
of hazardous material was underestimated by 160%. Washington State Dept. of Transportation v. Natural Gas
Co., 59 F.3d 793, 804 (9th Cir. 1995). An agency may not disregard its own rules and regulations during the
course of agency decision-making. See, eg., Frisby v. United States Dept. of Housing and Urban Dev. (HUD),
755 F.2d 1052, 1055 (3d Cir. 1995) ("[T]he agency itself is bound by its own regulations. Failure on the part
of the agency to act in compliance with its own regulations is fatal to such action. Such actions are 'not in
accordance with law.'"); Simmons v. Block, 782 F.2d 1545, 1550 (11th Cir. 1986) and cases cited therein.
Moreover, an agencys failure to comply with its own prescribed procedures, including those not attaining the
status of formal regulations, has been determined to be arbitrary and capricious. See Montilla v. Immigration
and Naturalization Serv., 926 F.2d 162, 166-67 (2d Cir. 1991) (guoting Morton v. Ruiz, 415 U.S. 199, 235
(1974); D'Torio v. County of Delaware, 592 F.2d 681, 695 n.2 (3d Cir. 1978). Accordingly, when an agency
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departs from its precedents, the agency must provide a reasoned explanation, in particular why the original
reasons for adopting the rule or policy are no longer applicable, or the decision will be vacated as
arbitrary and capricious. See Graphic Communications Int'1 Union, Local 554 v. Salem-Gravure Div. of World
Color Press, Inc., 843 F.2d 1490, 1493 (B.C. Cir. 1998), cert, denied 489 U.S. 1011; New York Council, Ass'n
of Civilian Technicians v. Federal Labor Relations Auth., 757 F.2d 502, 508 (2d Cir. 1985), cert, denied 474
U.S. 846.
This document provides, comments on behalf of the Chemsol PRP Group 3 on the FS and Proposed Plan. 4 In
accordance with the NCP and principles of administrative law, the comments presented below support
re-evaluation of certain components of the proposed remedies based on errors in the record and the failure to
consider USEPA guidance and certain facts and reconsideration of several remedial objectives to provide for
flexibility in the Record of Decision ("ROD") regarding the design of the remedy. Failure to re-evaluate
certain components of the proposed remedies or to reconsider the remedial action objectives based on the
errors in the FS and Proposed Plan and the information presented herein, which "significantly changes the
basic features of the remedy with respect to scope, performance, or cost," would render the USEPA's decision
in a subseguent ROD arbitrary and capricious. The comments are summarized below.
Comments on Proposed Soil Remedy
! The remedial action objective to allow for future site use without restriction cannot be achieved by
the proposed soil remedy.
• The FS and the Proposed Plan state that one of the remedial action goals is to address soil
contamination so as to allow for unrestricted residential or recreational use of the Site.
However, the PCB cleanup criterion of 1 ppm applied by the Proposed Plan does not meet the
State's standards. Conseguently, even after excavation and disposal of approximately 18,500
cubic yards of soil, a deed restriction, likely with some other control such as capping, would
be reguired by the NJDEP and, therefore, the proposed remedy would not achieve the remedial
action objectives.
• Excavation to the State's criterion has not been analyzed as an alternative. Accordingly, the
ROD cannot impose this reguirement without performing another remedial alternatives analysis,
as excavating to the State's criteria may substantially increase the volume of soil to be
excavated, which translates into significantly higher costs and increased risks to human health
and the environment, such as risks associated with excavation-related air emissions, truck
traffic through residential neighborhoods, and short-term risks to site workers.
• The current and future physical constraints located on the Site prohibit future site use
without restrictions. Wetlands cover a large percentage of the Site, severely limiting the
acreage of usable land. Further, the majority of the uplands is located in the vicinity of the
groundwater treatment plant. The operation of the plant and the presence of the appurtenances
associated with the plant further restrict available acreage and ability to develop.
! The selection of the proposed remedy is not supported by the administrative record.
• Errors in the cost estimating reguire reconsideration of the appropriateness of the proposed
remedy. In particular, the Proposed Plan reguires excavated soil to be disposed of as hazardous
waste; while the FS assumes disposal as nonhazardous waste. The ROD cannot reguire disposal as
a hazardous waste, because disposal costs will significantly increase beyond those presented in
the FS and, in accordance with the NCP and principles of administrative law, the USEPA will
have to consider those higher costs prior to remedy selection. However, no representative waste
characterization has been performed to determine the RCRA waste classification. Conseguently,
the ROD should state that disposal reguirements will be determined by sampling and analysis
conducted during implementation of the remedial action. If, as a result of this sampling and
analysis, a majority of the soil is classified as hazardous, the costs will increase
substantially and, in accordance with the NCP, the remedy selection will have to be
reconsidered.
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• The RI sampling did not adequately define the soil excavation contours. In accordance with the
NCP, USEPA must "collect data necessary to adequately characterize the site for the purpose of
developing and evaluating effective remedial alternatives." 40 C.F.R. ° 300.430(d)(1). To this
end, USEPA must:
characterize the nature of and threat posed by the hazardous substances and hazardous materials and
gather data necessary ... to support the analysis and design of potential response actions by
conducting, as appropriate, field investigations to assess the following factors: .. (iii) The general
characteristics of the waste, including quantities, state, concentration, toxicity, propensity to
bioaccumulate, persistence, and mobility; ... 40 C.F.R. ° 300.430(d)(2).
Accordingly, the ROD should allow for additional investigation or re-analysis of the data. Further, given the
uncertainty in the soil sampling, increases in both excavated volume and remedial cost may occur. Should the
volume required to meet the remedial action objectives significantly increase beyond that anticipated in the
Proposed Plan, in accordance with the NCP and principles of administrative law, the USEPA will have to
reconsider the remedy selection.
The FS and Proposed Plan require disposal of soils stockpiled on Site. However, if analysis demonstrates that
these soils comply with New Jersey soil cleanup criteria, the ROD should permit these soils to be used as
backfill if demonstrated to be acceptable for that purpose.
! The selection of soil capping as the remedial alternative is supported by the administrative record,
as it is protective of human health and the environment, complies with ARARs, is recommended by USEPA
guidance, and is consistent with realistic options for any future site use.
• The proposed soil cleanup standards are not supported by the guidance referenced as their
source, and no further explanation is provided to support the selection of the cleanup
standards. Moreover, the guidance documents referenced do not support the selection of the
remedial alternative. These guidance documents acknowledge the appropriateness of capping for
sites with contamination at the levels present at the Chemsol site. Because no reason for
departing from the guidance purportedly relied upon is provided, the soil cleanup goals and
remedy must be re-evaluated based on the guidance. Moreover, consistent with the guidance,
capping should be the selected remedy in the ROD.
• Errors in the cost estimating for soil capping require reconsideration of the appropriateness
of the proposed remedy. These errors overestimate the extent of the remedial action and cost
for soil cover. Also, the cost estimate arbitrarily assumes stockpiled soils cannot be used as
soil cover. As detailed herein, because the cost estimate for the capping alternative is
grossly overestimated, the selection of the proposed remedy is based on faulty assumptions
regarding the costs of the remedial alternatives. Consequently, there has not been a valid cost
comparison of the remedial alternatives as required by the NCP and, therefore, the remedy
selection must be re-evaluated.
Comments on Proposed Groundwater Remedy
! As recognized in the FS and various USEPA guidance documents, there is a high degree of certainty that
aquifer restoration and significant mass reduction cannot be achieved at the Chemsol site based on
hydrogeologic and contamination-related factors, specifically the presence of DNAPL in fractured
bedrock. Consequently, the ROD should waive ARARs for groundwater restoration based on the technical
impracticability of restoring the aquifer. 40 C.F.R. ° 300.430(f)(1)(ii)(C)(3). Moreover, the ROD
should not require extraction of groundwater to achieve mass reduction, to the extent it can be
achieved at all, because it will provide no additional protection of human health and the environment.
The remedial action objectives should be mvised to require hydraulic containment of the groundwater
plume.
! The groundwater flow model used in the FS, which forms the basis for the selection of the remedy in
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the Proposed Plan, is described as "preliminary" because of a limited calibration and the existence of
data gaps. The preliminary groundwater flow model should not have been used for predictive purposes.
Conseguently, the ROD should embrace the recommendations set forth in the groundwater modeling report
which state, "[T]he model should be upgraded from 'preliminary' status to 'predictive' status by
resolving data gaps and uncertainties and performing additional calibration." Because the preliminary
model is based on inadeguate and, at times, inaccurate data, the ROD must be written in such a manner
to allow for the incorporation of the findings of a refined, calibrated groundwater model into the
design of the groundwater extraction system, including the number of extraction wells, the well
locations, the well extraction rates, and the aggregate extraction rate.
! The proposed alternative reguires pumping from all groundwater zones up to a saturation depth of
approximately 375 feet. No justification is provided for reguiring extraction of certain
uncontaminated portions of the aguifer, either on-site or beyond the Site boundaries. The agency has
defined the extraction boundaries based on a only a preliminary groundwater model. The ROD should not
specify the extent of the capture zone; rather, the capture zone should be identified as the
contaminated area defined by the RI, and any additional investigations conducted as part of remedial
design, and be determined using a refined, calibrated groundwater model.
! Off-site groundwater plume delineation should be limited to the downgradient area of the Site.
Further, the definition of the downgradient area should be determined using a refined, calibrated
groundwater model.
! The existing MCUA permit and NJDEP surface water discharge permit eguivalent present significant
constraints on the effluent discharge, as they are based on a discharge flow rate of 30 gpm. These
discharge limitations are not considered in the evaluation of the remedial alternatives. By failing to
do so, the agency has entirely failed to consider an important aspect of the problem. Due to this
oversight, the ROD must be written to permit flexibility in the extraction system design to conform to
these limitations.
! There is no technical basis for the reguirement in the FS and Proposed Plan to operate the biological
treatment plant if the treatment plant effluent is discharged to surface water. Currently, the plant
effluent discharged to the MCUA would exceed surface water discharge standards for only barium,
manganese and total dissolved solids ("TDS"). In its current configuration, there have been no
exceedences for soluble organics. Operation of the biological treatment plant will not assist in
reaching the standards for those criteria exceeded. Moreover, the influent concentrations of soluble
organics have decreased significantly. Accordingly, the reguirement of operating the biological
treatment plant should not be an explicit element of the selected alternative in the ROD.
! A refined, calibrated groundwater model should be used to structure any long-term monitoring program,
including the number and location of wells to be sampled. Similarly, the long-term monitoring sampling
parameters should be developed during remedial design based on site contaminants.
2.0 COMMENTS REGARDING PROPOSED SOIL REMEDY
2.1 The remedial action objective to allow for future site use without restrictions cannot be achieved by
the proposed soil remedy.
2.1.1 Because the proposed soil remedy would not achieve the State soil cleanup criteria, it cannot satisfy
the remedial action objective to allow for future site use without restrictions.
Two of the remedial action objectives for soil remediation are in direct conflict and reguire revision by the
USEPA. These objectives are:
! restoring the soil at the Site to levels which will allow for residential/recreational use
(without restrictions); and
! prevent human exposure to surface soils contaminated with PCB concentrations above 1 part per
million (ppm) and lead concentrations above 400 ppm.
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The Proposed Plan's goal of "restoring the soil at the Site to levels which would allow for
residential/recreational use (without restrictions)" apparently ignores the fact that by not remediating to
New Jersey's soil cleanup standard, future Site use would continue to be subject to restrictions. As the
USEPA recognized in the Proposed Plan, the State of New Jersey has developed a state-wide soil cleanup
criterion for PCBs of 0.49 ppm. (USEPA, 1997b) The USEPA further recognized that, "if the remedy does not
achieve the State [criterion], the State will reguire that restrictions be placed on the property to prevent
future direct contact with soils above 0.49 ppm." (USEPA, 1997b) Indeed, "the State of New Jersey cannot
concur on the preferred remedy unless its soil direct contact criteria are met or institutional controls are
established to prevent direct contact with soils above direct contact criteria." (USEPA, 1997b) Conseguently,
even after excavation and disposal of approximately 18,500 cubic yards of soil at an estimated cost of $5.5
million, the Proposed Plan acknowledges that a deed restriction, and possibly other institutional controls or
engineering controls, such as a cap, would still be reguired by the NJDEP. The remedial action objective to
allow for future site use without restrictions cannot be achieved under these circumstances.
To remedy this error, the USEPA should delete the "without restrictions" reguirement in the remedial action
objective so it is revised to read:
! restoring the soil at the Site to levels which will allow for residential/recreational use.
2.1.2 If the remedial action objectives are revised to consider the State soil cleanup criterion, a new
remedial alternatives analysis must be performed to comply with the NCP, as at remedial alternative which
complies with the State's soil cleanup criterion was not previously evaluated and is expected to result in
significantly greater costs and increased risk to human health and the environment.
The proposed remedial alternative of excavation and disposal of contaminated soils will have to be revised to
achieve the State soil cleanup criterion if the remedial action objective of unrestricted future use of the
property is to be achieved. If additional excavation is to be considered to achieve the State criterion, the
remedy selection would have to be re-evaluated as it is not evaluated by the FS or Proposed Plan.
The additional excavation work reguired to achieve the New Jersey criterion is likely to be significant. The
proposed remedy addresses only surface (0-2 feet) soil. (USEPA, 1997a) Based on the analytical results
presented in the RI, some areas of the Site may reguire up to six (6) feet of excavation to meet the New
Jersey criterion. (USEPA, 1996) The RI data indicate that additional excavation volumes could be more than
25% greater than USEPA estimates, depending on the vertical distribution of soil constituents at the Site.
(Affidavit of Willard F. Potter dated October 10, 1997 [hereinafter, "Potter Affidavit"]) As a result, if the
remedy is altered to meet this goal, significant costs and increased risks to human and health and the
environment would ensue.
Depending on the classification of the excavated soil for off-site disposal (see Section 2.7), the actual
cost of the proposed remedy could increase to $6.7 million up to $18.4 million. (Potter Affidavit) Should
costs increase, review by the National Remedy Review Board may be reguired as the estimated cost of the
proposed remedy would be expected to exceed $10 million and, if so, would be 50% greater than the least
costly, protective, ARAR-compliant alternative.
Furthermore, increased risks would result from any additional excavation. In particular, the additional
excavation would result in larger volumes for excavation, which translates, into proportionately higher truck
traffic through residential neighborhoods and on the roads and highways, increased potential for
excavation-related air emissions, and greater short term risks to site workers.
Because the additional excavation would significantly increase costs, resulting in this alternative being
materially different from the proposed remedy, a new remedial alternatives analysis would have to be
performed before the ROD is issued to satisfy the reguirements of the NCP.
2.1.3 The proposed soil remedy cannot satisfy the remedial action objective to allow for future site use
without restrictions based on the significant present and anticipated future environmental and physical
development constraints located on the Site.
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The remedial action objective to "restore the soil at the Site to levels which will allow for
residential/recreational use (without restrictions)" cannot be achieved due to development restrictions posed
by the presence of wetlands and the groundwater treatment facility on Site.
Wetlands cover a large percentage of the Site. (USEPA, 1997a (Figure 1-31); USEPA, 1996) Indeed, only
approximately three (3) to four (4) acres will be available for use without causing impact to the designated
onsite wetlands. (USEPA, 1997a; USEPA, 1996) This fact is not considered by the FS or Proposed Plan in the
analysis of the alternatives. Furthermore, no cost for mitigation of wetlands disturbed by the proposed soil
remedy has been considered.
Moreover, the majority of the uplands is located in the vicinity of the groundwater treatment plant. (USEPA,
1996) Conseguently, any development would be restricted to a relatively small area in the vicinity of the
groundwater treatment plant. However, the appurtenances associated with the plant, such as underground lines,
extraction wells, and monitoring wells, would further reduce the acreage available for development and would
restrict the type of development. In fact, the presence and operation of the groundwater treatment plant may
entirely preclude any development or site use until the groundwater remedial action is complete.
In consideration of these significant constraints on development, the "without restrictions" reguirement
should be deleted from the remedial action objective, so it is revised to read:
! restoring the soil at the Site to levels which will allow for residential/recreational use.
2.2 The selection of the proposed remedy is not supported by the administrative record.
2.2.1 By reguiring the soil be disposed as a hazardous waste, the Proposed Plan proposes a remedy not
evaluated by the FS, contrary to the reguirements of the NCP.
The Proposed Plan states that the excavated soil "would be disposed at a facility which is licensed under
RCRA to accept hazardous waste." (USEPA, 1997b) This statement is inconsistent with the conclusions reached
in the RI that were adopted by the FS. (USEPA, 1996; USEPA, 1997a) In fact, disposal at a hazardous waste
landfill would result in the FS cost estimate being grossly understated. (Potter Affidavit) The RI/FS
Guidance states that FS cost estimates "are expected to provide an accuracy of +50 percent to -30% and are
prepared using data available from the RI." (USEPA, 1988) Reguiring disposal as a hazardous waste results in
the estimated cost for the proposed alternative being underestimated by more than $9.1 million (Potter
Affidavit), well beyond the accepted cost estimating tolerance prescribed in USEPA guidance. (USEPA, 1988)
The excavated soil transportation and disposal costs for a RCRA landfill can be more than four (4) times
higher than the comparable costs for nonhazardous soils used in the FS. (Potter Affidavit) The estimated cost
for the excavation and disposal alternative may increase by as much as $9 million, for a total estimated cost
of over $14.5 million. (Potter Affidavit) Conseguently, the ROD cannot reguire disposal as a hazardous waste
as, in accordance with the NCP and principles of administrative law, the USEPA would have to consider those
higher costs prior to such a remedy selection.
However, none of the samples analyzed for hazardous characteristics by the TCLP testing procedures specified
at 40 C.F.R. ° 261.24 are within the extent of the proposed excavation. While none of soil samples leached
hazardous constituents in excess of the RCRA hazardous waste criteria, because none are in the within the
extent of excavation, the RI's conclusion that the soil is nonhazardous is unsupported.
The ROD should state that the soil disposal facility will be determined by soil sampling and classification
conducted during the implementation of the selected remedy. However, if a majority of the soil is classified
as hazardous, and the costs increase substantially, the remedy selection in the ROD would have to be
re-evaluated in accordance with the NCP.
2.2.2 Should soil sampling during remedial design reveal a larger volume of soil reguiring excavation, the
remedy must be re-evaluated as the selection would not be based on all relevant facts, information, and
alternatives.
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If the USEPA retains the proposed remedy of excavation and disposal of soil, the ROD should be written to
allow additional soil sampling during the remedial design to determine more accurately the volume of material
that is reguired to be excavated. Neither the PCB contamination contours nor the lead contamination contours
are well-defined by the RI sampling. For example, the lead contamination contours are based on only three
soil borings. (USEPA, 1997a) Moreover, the areas to be excavated appear to include sediments near the
confluence of the Northern Ditch and Stream IB. The Proposed Plan determines remediation of these sediments
is not warranted at this time. (USEPA, 1997b)
However, as a result of this additional delineation, significantly greater guantities of soils may be
identified as reguiring excavation and disposal under the Proposed Plan, thereby greatly increasing cost. If
the volumes significantly increase, the assumptions in the Proposed Plan would be materially incorrect and
the NCP will compel reconsideration of the remedy selection. 40 C.F.R. ° 300.435(c) (2).
2.2.3 Stockpiled soils meeting the criteria for backfill should not be reguired to be disposed of, but
should be permitted to be used as backfill.
The Proposed Plan reguires that the soil presently stockpiled on-site be disposed of off-site. However, the
reguirement for off-site disposal presently is confirmed only for the soils excavated in connection with the
removal of the underground storage tank. (USEPA, 1997a (Appendix C)) The other two soil stockpiles were
excavated from the area in the vicinity of the groundwater treatment plant building, which area is believed
not to be contaminated. The RI sampling supports this conclusion, as samples collected in the vicinity of the
treatment plant do not exhibit contamination above the cleanup standards set forth in the Proposed Plan.
(USEPA, 1996) If sampling confirms that these soils do not contain contaminants above the New Jersey soil
cleanup criteria, the ROD should permit the use of these soils as acceptable backfill or cover material.
2.3 A selection of soil capping as the remedial alternative is supported by the administrative record.
In accordance with USEPA guidance, the FS states that, based on its proposed future use, capping is an
appropriate remedial action for the levels of contamination present at the Chemsol site. (USEPA, 1997a) The
Proposed Plan assumes that the most probable future use of the site would be for residential or recreational
purposes, stating that the municipality has expressed a preference for recreation use for the property.
(USEPA, 1997b) As discussed in Section 2.3.1, USEPA Guidance expressly recommends capping for residential-use
sites with contamination levels eguivalent to those detected at the Chemsol site. (USEPA, 1994b; USEPA, 1990)
Further, for the Chemsol Site, the FS states that capping will allow for "many residential type uses of the
property, such as for recreational purposes as a park or a playground among others." (USEPA, 1997a)
Capping is protective of human health and the environment, recommended by USEPA guidance, and consistent with
realistic options for any future site use based on site development constraints. Further, capping would
satisfy not only the cleanup levels set forth in the Proposed Plan, but also would satisfy the State PCB
cleanup criterion. The proposed remedy should be re-evaluated in consideration of these significant facts, as
soil capping is supported by the administrative record.
2.3.1 The Proposed Plan is not consistent with the USEPA guidance on which soil cleanup levels were based;
conseguently, the remedy selection should be reconsidered as these guidance documents recommend capping for
sites with contaminant concentrations at the levels present at the Chemsol site.
2.3.1.1 The Proposed Plan does not follow USEPA's Guidance on Remedial Actions for Superfund Sites with PCB
Contamination which states that, for sites with future residential use scenarios, capping is typically the
preferred remedial alternative where PCB concentrations are below 100 ppm.
In the Proposed Plan, USEPA states, "Soil cleanup levels for PCBs at the Site were obtained from EPA's 1990
'Guidance on Remedial Actions for Superfund Sites with PCB Contamination.'" (USEPA, 1997b) This guidance, in
part, "summarizes the primary considerations associated with determining the appropriate response action for
a PCB contaminated Superfund site in terms of the nine evaluation criteria used in the detailed analysis."
(USEPA, 1990) In doing so, the guidance provides USEPA's interpretation of the reguirements of the NCP at
Superfund sites with PCB contamination. However, without explanation, the Proposed Plan did not follow the
guidance and, correspondingly, did not satisfy the reguirements of the NCP.
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In the guidance, USEPA acknowledges that a cap is the preferred remedial alternative for sites where only
"low-threat" concentrations of PCBs are present. The guidance recognizes an action level of 1 ppm for sites
with unlimited exposure under residential land use scenarios; however, this 1 ppm standard is a "starting
point action level," not a cleanup standard. (USEPA, 1990) Instead, the guidance reguires that final cleanup
levels reflect all relevant exposure pathways and be defensible on a site-specific basis. (USEPA, 1990)
According to the guidance, the expectation of the Superfund program that "principal threats at a site will be
treated wherever practicable and that low-threat material will be contained and managed" should be followed
in determining an appropriate cleanup standard and remedial action for a Site. (USEPA, 1990) The guidance
defines principal threats to include "soil contaminated at 2 to 3 orders of magnitude above the [1 ppm]
action level," or "[f]or sites in residential areas, ... soil contaminated at concentrations exceeding 100
ppm. PCBs." (USEPA, 1990) The guidance states that material above action levels not constituting a principal
threat (less than 100 ppm for residential areas) should be "contained to prevent access." (emphasis added)
(USEPA, 1990) Moreover, "where low concentrations of PCBs will remain on site and direct contact risks can be
reduced sufficiently, minimal long term management controls are warranted." (USEPA, 1990) The USEPA estimates
that a ten (10) inch soil cover will reduce risks by approximately one order of magnitude. (USEPA, 1990)
Accordingly, the PCB Spill Cleanup Policy recommends a 10 ppm cleanup level with a 10 inch cover for
residential areas. 40 C.F.R. ° 761.125(c)(4)(v).
Based on the detected PCB concentrations at the Chemsol site, the guidance recommends capping as the
preferred remedial alternative. For surface soils, PCBs are detected below 5 ppm in 73% of the screening
samples from the RI, while PCBs are detected below 5 ppm in 84% of the laboratory-analyzed samples. (USEPA,
1996) For subsurface soils, PCBs are detected below 5 ppm in 90% of the screening samples, while PCBs are
detected below 5 ppm in 98% of the laboratory-analyzed samples. (USEPA, 1996) Only one laboratory-analyzed
sample detected PCBs in excess of 50 ppm, while the geometric mean of all laboratory-analyzed samples is
0.099 ppm (0.177 ppm for surface soils). (USEPA, 1996) The Proposed Plan fails to apply the guidance to these
data and, therefore, fails to comply with USEPA's interpretation of the reguirements of the NCP at Superfund
sites with PCB contamination. As a result, the proposed alternative should be re-evaluated to conform with
the USEPA guidance. Furthermore, in accordance with the guidance, a soil cap should be selected as the remedy
in the ROD.
2.3.1.2 The lead cleanup standard adopted in the Proposed Plan is not consistent with the procedures set
forth in USEPA's Revised Interim Soil Lead Guidance for CERCLA Sites and RCRA Corrective Action Facilties,
upon which the cleanup standard is purportedly based, and, therefore, the remedy selection should be
reevaluated to conform with the guidance.
The Proposed Plan states, "The 400 ppm lead cleanup level is based on EPA's 1994 'Revised Interim Soil Lead
Guidance for CERCLA Sites and RCRA Corrective Action Facilities.'" (USEPA, 1997b) The guidance, in part,
"establishes a streamlined approach for determining protective levels for lead in soil at CERCLA Sites,"
thereby providing USEPA's interpretation of the reguirements of the NCP at Superfund sites with lead
contamination in soils. (USEPA, 1994b) Similar to the PCB guidance, the Proposed Plan, without explanation,
does not follow the guidance and, correspondingly, does not satisfy the reguirements of the NCP.
The guidance recommends using 400 ppm as a screening level for lead in soil at residential sites. However,
the guidance specifically states:
Screening levels are not cleanup goals. Levels of contamination above the screening level would NOT
automatically reguire a removal action, nor designate a site as 'contaminated.'" (emphasis in
original) (USEPA, 1994b)
In fact, residential preliminary remediation goals of "more than twice the screening level have been
identified," and "[a]fter considering other factors such as costs of remedial options, reliability of
institutional controls, technical feasibility, and/or community acceptance, still higher cleanup levels may
be selected." (USEPA, 1994b) No such analysis has been performed for the Chemsol site. Indeed, no
justification for the selection of the cleanup goals has been provided.
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Moreover, the guidance goes on to state that exceedence of an appropriate cleanup standard does not
necessarily reguire excavating soil. Instead, intervention measures (e.g., capping, institutional controls)
may be more appropriate than excavation at many sites. (USEPA, 1994b)
The Proposed Plan fails to consider the guidance correctly and, therefore fails to comply with the USEPA's
interpretation of the reguirements of the NCP at Superfund Sites with lead contamination. As a result, if the
proposed alternative should be re-evaluated to conform with the USEPA guidance. Furthermore, in accordance
with the guidance, a soil cap should be selected as the remedy in the ROD.
2.3.2 The FS and Proposed Plan overestimate the costs of capping, resulting in an invalid cost comparison
of remedial alternatives.
The cost for the capping alternative is overestimated by up to $1.15 million, which is 60% of the cost
presented in the FS and relied upon by the Proposed Plan. (Potter Affidavit) The RI/FS Guidance states that
FS cost estimates "are expected to provide an accuracy of +50 percent to - 30% and are prepared using data
available from the RI." (USEPA, 1988) However, as detailed below, the cost estimate for the capping
alternative misinterprets the data generated as part of the RI and, as a conseguence,) overestimates the
costs beyond the tolerances acceptable to USEPA. These effors in the cost estimating dictate that the
proposed remedy must be reconsidered as there has not been a valid cost comparison of remedial alternatives
as reguired by the NCP. Moreover, because the costs for the capping alternative are significantly lower than
estimated by the FS, the proposed alternative becomes significantly more expensive without a corresponding
increase in protection of human health and the environment.
The unit cost for soil cover in the capping alternative exceeds the unit cost for backfill under the
excavation alternative by $10.67 per cubic yard. (USEPA, 1997a) The record states no reason, nor is there any
justifiable reason, why more expensive soils/backfill would be reguired for the capping alternative. In fact,
the FS reguires that "clean common fill ... satisfying] New Jersey soil cleanup criteria for residential
use" be used for both alternatives. (USEPA, 1997a) Conseguently, the estimated cost for capping of 12 acres
is overstated by over $0.4 million (including multipliers). (Potter Affidavit)
In addition, the FS and Proposed Plan state that 5.73 acres would be disturbed by excavation, while 12 acres
would have to be capped. Again, the record contains no explanation or justification for this difference. The
areal extent of soil exceeding cleanup levels is defined by the excavation alternative to be 5.73 acres;
there is no reason to reguire a soil cap for any area not presenting an alleged risk. Further, constructing a
soil cap over 12 acres would impact on-site wetlands. No cost for mitigation of the impacted wetlands is
included in the FS cost estimate. Using the correct unit cost for soil cover, without even considering the
cost for mitigation of any impacted wetlands, the cost for constructing the capping alternative is overstated
by over $0.9 million. (Potter Affidavit) Therefore, the more accurate cost estimate for the capping
alternative is $959,938, as compared to the FS estimate of $1,894,275.
Furthermore, if analytical results of the stockpiled soil demonstrate that the soil is acceptable for use as
cover material (i.e., meets the New Jersey soil cleanup criteria), the total cost of the capping alternative
(including capping and disposal of drums and stockpiled soil) is reduced by an estimated additional $216,000,
for a total reduction of $1.15 million. (Potter Affidavit)
3.0 COMMENTS REGARDING PROPOSED GROUNDWATER REMEDY
3.1 Geologic and contaminant-related factors dictate that a Technical Impracticability ARAR waiver should
be granted and the remedial action objective be revised accordingly to seek containment of the contaminated
groundwater.
USEPA guidance and extensive experience demonstrate that two of the groundwater remedial action objectives in
the Proposed Plan are unachievable based on the hydrogeologic conditions and contamination present at the
Chemsol site. The groundwater remedial objectives in the Proposed Plan seek, in part, to "remove and treat as
much contamination as possible from the fractured bedrock." and to "restore remaining affected groundwater to
State and federal drinking water standards." (USEPA, 1997b) However, based on the investigations conducted
during the RI, dense, nonagueous phase liguid (DNAPL") is present across the site in fractured bedrock.
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(USEPA, 1996) The FS expressly acknowledges that "[a]quifer restoration is highly unlikely in this fractured
bedrock." (USEPA, 1997a) Accordingly, an ARAR waiver, based on the technical impracticability of restoring
groundwater, should be granted. 40 C.F.R. ° 300.430(f)(1)(ii)(C)(3). Moreover, in conformance with the NCP,
USEPA guidance, and the FS remedial action objectives, the remedial action objectives for groundwater
remediation at the Chemsol site should be revised correspondingly to seek only hydraulic containment of the
groundwater plume. Extraction for mass reduction has little, if any, utility because groundwater ARARs are
impossible to achieve in a reasonable timeframe.
When DNAPL is present in a fractured rock media, little in the way of meaningful groundwater restoration can
be accomplished through efforts to remove contaminant mass by groundwater extraction. (USEPA, 1993) In
summary, the science has demonstrated over the years that removal of DNAPL in fractured bedrock is
complicated by inaccessibility (e.g., in dead-end fractures in bedrock), flow mechanics independent of
groundwater flow, complex flow patterns, and difficulties in locating DNAPL accumulations. (Parker, Gillham
and Cherry, 1994) USEPA recognizes these difficulties in its various guidance documents, including the
Guidance for Evaluating the Technical Impracticability of Ground-Water Restoration, OSWER Directive 9234.2-25
(September 1993) ("TM Guidance"). Indeed, it has been demonstrated time and again that attempts of any kind
to remove contaminant mass in the conditions present at the Chemsol site would be futile. (Parker, Gillham
and Cherry, 1994) Accordingly, the currently accepted practice under these conditions is to contain
groundwater to protect downgradient receptors. (Parker, Gillham and Cherry, 1994; see also USEPA, 1993)
The RI concludes that DNAPL exists in numerous overburden and bedrock wells at the Chemsol site. (USEPA,
1996) This conclusion is based primarily on a comparison of groundwater guality data to constituent
solubilities, the methodology described in Estimating Potential for Occurrence of DNAPL at Super Sites
(USEPA, 1992). USEPA guidance identifies "concentrations of DNAPL-related chemicals in groundwater [that]
are greater than 1% of pure phase solubility or effective solubility" as a condition indicating the potential
for DNAPL. (USEPA, 1992) For example, historical groundwater guality data for monitoring well C-l at the
Chemsol site indicate that trichloroethene was present in concentrations in excess of 20% of its solubility,
clearly demonstrating the presence of DNAPL. (USEPA, 1991) The RI provides additional evidence of the
presence of DNAPL in that material resembling "tar balls" has been observed during maintenance of the
groundwater extraction system. (USEPA, 1996)
The importance of the presence of DNAPL in the remediation of contaminated sites has been recognized since
the early 1980s. (Freeze and Cherry, 1979) More recently, the USEPA has acknowledged the problems presented
by the presence of DNAPL:
Once in the subsurface, it is difficult or impossible to recover all of the trapped residual DNAPL.
The conventional aguifer remediation approach, groundwater pump-and-treat, usually removes only a
small fraction of trapped residual DNAPL. Although many DNAPL removal technologies are currently
being tested, to date there have been no field demonstrations where sufficient DNAPL has been
successfully recovered from the subsurface to return the aguifer to drinking water guality. (USEPA,
1992)
The presence of DNAPL contamination within the rock matrix itself is of particular importance to the ability
to achieve groundwater restoration within a reasonable time frame. The entrance to and eventual release of
contaminants from the rock matrix are diffusion controlled processes. (Parker, Gillham and Cherry, 1994) As
contaminated groundwater moves through the fractures of a bedrock aguifer, diffusion of contaminants will
occur into the essentially stagnant matrix pore water of the rock, as illustrated in Figure 3-1. (Parker,
Gillham and Cherry, 1994) The extent of the diffusion and its hydrogeologic significance will depend upon the
concentration gradient, the matrix diffusivity and porosity, the fracture spacing of the rock, and the
duration of exposure. (Parker, Gillham and Cherry, 1994)
The diffusion of contaminants into the rock matrix can be considered beneficial in that it retards the
advance of a contaminants plume through the fractured rock. (Lever and Bradbury, 1985) However, when the
objective is to purge contamination from an aguifer, the diffusion-controlled release of contaminants from
the rock matrix can greatly prolong aguifer cleanup efforts over what would be possible in a simple porous
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medium of equivalent hydraulic conductivity. Consequently, contaminants in the rock matrix become a
lonq-term source of qroundwater contamination for which there is no remedial measure currently available.
(USEPA, 1993) One would expect qroundwater remediation time within rock aquifers contaminated with DNAPL
chemicals to be measured in hundreds of years. (USEPA, 1993) The failure to discuss adequately the
siqnificance of DNAPLs and matrix diffusion as they relate to overall site remediation is a fatal flaw in the
FS.
Furthermore, the siqnificance of matrix diffusion to qroundwater restoration is not limited to the DNAPL
zone. In fact, the diffusion process will play a similar role in substantially delayinq the removal of mass
in the area of the aqueous plume downqradient of the DNAPL zone. (USEPA, 1993) USEPA has also acknowledqed
the siqnificance of this phenomenon:
EPA recoqnizes, however, that there are technical limitations to qround-water remediation technoloqies
unrelated to the presence of a DNAPL source zone. These limitations, which include contaminant-related
factors (e.g., slow desorption of contaminants from aquifer materials) and hydroqeoloqic factors
(e.g., heterogeneity of soil or rock properties), should be considered when evaluatinq the technical
practicability of restorinq the aqueous plume. (USEPA, 1993)
In the TI Guidance, the USEPA recoqnizes the foreqoinq and states that hydroqeoloqic and contaminant-related
factors can inhibit qroundwater restoration. The TI Guidance further states that the presence of fractured
bedrock and DNAPL "makes extraction or in-situ treatment of contaminated qroundwater extremely difficult,"
specifically notinq that DNAPL "qenerally is not capable of miqratinq or beinq displaced by normal
qroundwater flow." (USEPA, 1993)
A front-end TI decision is; appropriate where "adequate site characterization data [is] present[]to
demonstrate, not only that [a known remediation] constraint exists, but that the effect of the constraint on
contamination distribution and recovery potential poses a critical limitation to the effectiveness of
available technoloqies." (USEPA, 1993) Based on the qroundwater characterization conducted durinq the RI and
the qroundwater model presented in Appendix A, the site has been characterized adequately to support a TI
decision.
The TI quidance provides:
[C]ertain types of source contamination are resistant to extraction and can continue to dissolve
slowly into qround water for indefinite periods of time. Examples of this type of source constraint
include certain occurrences of NAPLs, such as where the quantity, distribution, or properties of the
NAPL render its removal from, or destruction within, the subsurface infeasible or inordinately costly.
(USEPA, 1993)
Furthermore,
Geoloqic constraints... also may critically limit the ability to restore an aquifer...Some qeoloqic
constraints, however, may be defined sufficiently durinq site characterization so that their impacts
on restoration potential are known with a relatively hiqh deqree of certainty. An example of this type
of constraint includes complex fracturinq of bedrock aquifers, which makes recovery of contaminated
qround water or DNAPLs extremely difficult. (USEPA, 1993)
The RI concludes that indications of DNAPL are present in at least 23 wells on the Chemsol site. (USEPA,
1996) In addition, fractured bedrock is present across the Site. (USEPA, 1996) Based on the presence of DNAPL
in fractured bedrock, a front-end TI decision is appropriate for the Site.
The NCP requires restoration of qroundwater only "wherever practicable, within a timeframe that is reasonable
qiven the particular circumstances of the site." 40 C.F.R. ° 300.430(a) (1) (iii) (F) . USEPA has determined 100
years to be a "very lonq restoration timeframe.". (USEPA, 1993) The USEPA acknowledqes that "[DNAPL]
compounds... are often very difficult to locate and remove from the subsurface environment and may continue to
contaminate qround water for many hundreds of years despite best efforts to remediate them." (emphasis added)
(USEPA, 1993) USEPA concludes that "in cases where there is a hiqh deqree of certainty that cleanup levels
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cannot be achieved, a final ROD that invokes a TI ARAR waiver and establishes an alternative remedial
strategy may be the most appropriate option." (USEPA, 1993) "Where it is technically impracticable to remove
subsurface DNAPLs, EPA expects to contain the DNAPL zone to minimize further release of contaminants to the
surrounding ground water, wherever practicable." (USEPA, 1993)
Similarly, in the USEPA's Superfund Administrative Reforms, USEPA has promoted updating remedy decisions
where "significant new scientific information or technological advancement will achieve the same level of
protectiveness." (USEPA, 1995) In particular:
By the 1990s, experience indicated that sites contaminated with [DNAPLs] could reguire an inordinate
amount of time to restore the ground water to drinking water levels using conventional pump and treat
technology alone. ...[C]urrent policy is to isolate and contain the DNAPL source, removing the source
only to the degree practicable. (USEPA, 1995)
Based on the hydrogeologic and contaminant factors at the Chemsol site, there is a high degree of certainty
that the attainment of the remedial action objectives in the Proposed Plan is not technically practicable. As
discussed above, both the USEPA and experts recognize that the use of groundwater extraction for the purpose
of contaminant mass removal has little overall effect on groundwater guality under the geologic and
contaminant conditions present at the Chemsol site. Specifically, because of the presence of DNAPL in
fractured bedrock, groundwater restoration cannot be achieved at the Chemsol site, particularly within a
reasonable timeframe. Conseguently, a TI ARAR waiver should be granted.
Because groundwater restoration is not achievable at the Site, the remedial action objective should be
revised, in conformity with the objective set forth in the FS, to seek the containment of the groundwater.
References in the remedial action objectives to groundwater restoration and/or mass removal should be
removed. Because groundwater cannot be restored, mass reduction pumping is unnecessary. Accordingly, the
remedial action objective should be revised, as follows:
! prevent migration of the contaminated groundwater in the fractured bedrock aguifer; augment the
existing groundwater system to contain the contaminated groundwater from all depth zones.
Even if USEPA were not to grant a TI waiver or revise the remedial action objectives, groundwater pumping
scenarios should be optimized to achieve containment of the groundwater rather than to be geared toward mass
reduction, as it is the hydraulic containment that will serve to protect human health and the environment. An
extraction system that contains the groundwater will prevent downgradient migration and, thereby, protect
human health and the environment by eliminating the contributing source. Based on the presence of fractured
bedrock and DNAPL, the potential for achieving additional significant mass reduction at this Site beyond that
provided by containment is extremely low. The goal to achieve mass reduction should not dictate the location
of extraction wells. As groundwater extraction will not stimulate matrix diffusion, and may actually decrease
the diffusion of contaminants into groundwater, a source reduction pumping scheme is no more effective in
providing mass reduction than the recommended containment scheme. (National Research Council, 1994)
3.2 The remedial action objectives in the Proposed Plan must conform to those in the FS because the remedy
selection is based on the screening and evaluation of alternatives presented in the FS.
It is erroneous for the Proposed Plan to rely on the remedial alternatives analysis conducted in the FS, but
alter the remedial action objectives. The entire FS remedy evaluation, from the screening to the detailed
evaluation, relies on the remedial action objectives set forth in the FS. The Proposed Plan cannot
arbitrarily change these objectives, but rely on the analysis.
In particular, the remedial action objectives in the FS seek to:
! Prevent/minimize offsite migration of groundwater contamination in the fractured bedrock
aguifer. Contain the contaminated groundwater (that is above Federal and State MCLs) from all
depth zones and, as an element of this containment, reduce the mass of contaminants to the
maximum extent possible. Augment the existing interim remedy as necessary, in order to achieve
these goals. Aguifer restoration is highly unlikely in this fractured bedrock. (USEPA, 1997a)
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In contrast, the remedial action objectives in the Proposed Plan seek to:
! augment the existing groundwater system to contain that portion of contaminated groundwater
that is unlikely to be technically practicable to fully restore and restore remaining affected
groundwater to State and federal drinking water standards
! remove and treat as much contamination as possible from the fractured bedrock. (USEPA, 1997b)
Because the FS concludes that "[a]quifer restoration is highly unlikely in this fractured bedrock," the FS
remedial action objectives do not seek to restore the groundwater to drinking water standards. The remedial
action objectives in the Proposed Plan should be revised to conform to those presented in the FS, with the
appropriate revisions discussed above, as follows:
! prevent migration of the contaminated groundwater in the fractured bedrock aquifer; augment the
existing groundwater system to contain the contaminated groundwater from all depth zones.
3.3 The USEPA uses a "preliminary" groundwater model in its remedy selection, resulting in misinterpretation
of key model parameters and, consequently, a remedy selection process based on incomplete and, at times,
inaccurate information.
The groundwater flow model used in the FS as the basis for the selection of the remedy in the Proposed Plan
has been acknowledged to be "preliminary" and, therefore, cannot serve as a basis for a properly conducted
remedial selection. The groundwater modeling report (FS, Appendix A at 1) states that "the model is ...
preliminary because it was developed using the existing database which contains data gaps." As the model has
not been sufficiently developed and calibrated for use, its predictions relative to groundwater extraction
rates and capture zones are highly speculative. Accordingly, using this model as the basis for remedial
selection is improper since the proposed remedy is evaluated based on incomplete information.
Proper modeling protocol requires the development of a sound conceptual model, calibration, sensitivity
analysis, and a discussion of the uncertainty of the predictions. (Anderson, 1991) The conceptual model
incorrectly interprets the water-bearing zones beneath the Site and admittedly contains data gaps. (USEPA,
1994a) Consequently, the groundwater model uses inaccurate assumptions for key model input parameters.
Further, only a limited calibration was conducted, with no formal analysis of the sensitivity of the various
input parameters. Finally, there is no discussion of the uncertainty of the predicted extraction rate or well
placement. The failure to do each of these tasks thoroughly renders the groundwater flow model inappropriate
for predictive use. Using the model for predictive use, such as for determining the number of extraction
wells, the well locations, the well extraction rates, and aggregate extraction rate, is improper and a remedy
should not be selected on the basis of such a model.
As explained in the ECKENFELDER, INC.'s Technical Review of the Remedial Investigation Report, Chemsol, Inc.
Site, Piscataway, New Jersey, which was submitted to the USEPA on April 9, 1997, the most significant error
in the conceptual model concerns the interpretation of the water-bearing zones beneath the site and the
related implications regarding the directions of groundwater flow. Interpretation of the site hydrogeologic
conditions is based on a faulty assumption regarding the grouping of wells for mapping purposes.
Specifically, the wells have been grouped on the basis of equal elevation rather than on the basis of
stratigraphic position within the dipping bedrock units. Experience has shown that this type of approach
results in the incorrect determination of groundwater flow directions. (USEPA, 1994a) Indeed, USEPA
recognizes that "it is critical that potentiometric surface maps be developed using hydraulic heads measured
in comparable stratigraphic intervals to avoid misinterpreting horizontal flow directions, especially where
significant vertical gradients are present.... Potentiometric surface maps developed from wells completed in
different geologic units may result in misleading interpretations and containment." (USEPA, 1994a)
As recognized in the FS report, the results of the packer tests should be used to group the wells for the
purpose of potentiometric mapping. The following statement is made on page 1-41 leading to the discussion
regarding well grouping:
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Based on the results of the packer tests, it appears that:
! the bedrock that lies stratigraphically above the [upper] gray shale is near isotropic
and homogeneous conditions [sic](but flow is still controlled by fractures),
! the [upper] gray shale appears to be a hydraulic barrier,
! the bedrock below the [upper] gray shale is near isotropic and homogeneous conditions
[sic](but flow is still controlled by fractures), and
! the deep gray unit may have some hydraulic control, but the collected data are not
significant enough to make any conclusion regarding this unit. (USEPA, 1997a)
However, these conclusions, which should have been used as the basis for well grouping for potentiometric
mapping, are then not used as wells are subseguently grouped entirely on the basis of elevation. The result
of grouping wells based on elevation yields the comparison of data from wells that are in disparate
water-bearing zones. As a result, the conceptual model, for example, assumes that groundwater from wells
located below the upper gray shale are hydraulically connected to wells at similar elevation above the upper
gray shale, even though the FS concludes the upper gray shale acts as a hydraulic barrier that would prohibit
this flow. See Figure 3-2. This misinterpretation precludes the preliminary model's ability to accurately
model flow in the Site's complicated geologic units. The geology of the Chemsol site is complicated because
of the significantly complex hydrostratigraphic vertical relationships, such as the dipping of the bedrock
units and the presence of hydraulic barriers with the associated effects on hydraulic head. Further,
groundwater flow at the Site demonstrates a significant downward, vertical flow component due, in part, to
the presence of hydraulic barriers. Because the FS model compares wells in disparate water-bearing zones (FS
Figures 1-15 through 1-19), thus, not taking into account the complicated groundwater flow regime at the
Site, it misinterprets the direction and magnitude of groundwater flow, which renders the model unable to
depict site conditions, predict capture: zones, or design an appropriate long-term monitoring program.
Regarding data gaps, one of the most significant is the uncertainty of the influence of the "car wash" well.
On page 21, the groundwater modeling report states, "[D]uring calibration, it was discovered that the car
wash well exerts a major influence on the direction of groundwater gradients on-site and it was important
that it be included. However, the actual pumping rate is unknown. Therefore, it was assumed that the average
pumping rate is half the capacity of the well." (USEPA, 1997a) It is improper to include this assumption in
the groundwater model. First, the basis for this; assumed flow rate is not provided. The data from which the
"capacity" of the well is estimated is not identified, nor is the rationale for assuming a car wash would be
active often enough to account for half of the maximum yield of the well. Any data relied upon must be in the
administrative record. Second, according to a representative of the Piscataway Township Department of Public
Works, the car wash uses municipal water for its operation and thus the well is not currently in operation.
(Potter Affidavit) Mr. Evans further stated that the Department of Public Works has inspected the well on a
number of occasions to verify it is not operating. (Potter Affidavit) Accordingly, the influence of the car
wash well should not have been considered in the model. Since each of the simulations contained in the FS
includes the influence of this well, the model predictions of groundwater extraction rate and capture zone
are incorrect.
Another concern with the preliminary model is the assumption that is used regarding the hydraulic
conductivity of the bedrock. Overestimating the hydraulic conductivity will correspondingly overestimate the
extraction rate necessary to achieve containment. (Freeze, 1979) The preliminary model is "calibrated" using
hydraulic conductivities ranging from 20 to 50 ft/day for the "shallow and deep conductive zones,"
respectively, and 25 May for the intervening "general shale" (Table 9). These values are reportedly based on
an analysis of packer test data. ECKENFELDER INC. has subseguently conducted a more in-depth review of the
packer test results, as well as data previously collected by AGES in 1987 and McLaren-Hart in 1993.
(Attachments A and B, Appendix A) The results indicate that the hydraulic conductivity for a comparative
depth interval (principal aguifer) is approximately 10 ft/day. Since the groundwater extraction rate
necessary for containment is generally proportional to hydraulic conductivity (Freeze, 1979) and the
preliminary model uses overestimated hydraulic conductivities, it over-predicts the pumping rates reguired
for containment. This supposition is supported by the results of the MODFLOW model presented in Appendix A to
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these comments.
Another shortcoming of the preliminary model is the limited calibration that was conducted. On page 11 the
groundwater modeling report states, "Since this is a preliminary model application, a limited calibration was
performed. This calibration was limited because there are data gaps and because assumptions and
interpretations as discussed above had to be made." Model calibration should include "history matching" or
simulating the measured response to a known stress, such as the pumping of well C-l by McLaren-Hart in 1993.
(Konikow, 1992) The MODFLOW Model presented in Appendix A is calibrated with "history matching."
As indicated above, the model that forms the basis for the selection of the groundwater extraction remedy is
preliminary and should be refined prior to final selection of the number and pumping rate of individual
extraction wells. At a minimum, refinement should include:
Re-grouping of monitoring wells into similar hydrostratigraphic zones, re-contouring groundwater
elevations based on this distribution, and using these data for re-calibration. One of the concerns
regarding the conceptual basis of the model is the decision to map groundwater elevations as a
function of depth below ground surface rather than on the basis of hydrostratigraphic zones. (USEPA,
1994a) When groundwater elevations are contoured based on their appropriate hydrostratigraphic
position, as discussed in Section A-l (Appendix A), groundwater flow is shown to be to the north in
each groundwater zone, including the upperzone above the gray shale in which the FS model predicts
groundwater flow to the south. Groundwater guality data support this groundwater flow scenario, as
dissolved VOCs are detected to the north of the former source area(s). (USEPA, 1996 (Appendix T))
! Refining the assumptions used in the model regarding the operation and pumping rate of the adjacent
"car-wash" well. This well is reported not to be in operation and thus both the calibration and
prediction runs will need to be revised.
! Revising the boundary conditions. Due to the variable nature of individual water-bearing zones within
the Passaic Formation (Michalski, 1990) and the regional dip of approximately 12 degrees (Drake,
1995), the hydrostratigraphic units present onsite do not extend to the regional boundary features
used in the model. As a conseguence, the influence of these boundaries is over-stated by the model
simulations. Considering the relatively small and localized nature of the stress to be simulated,
both in calibration and prediction (ie., pumping several closely spaced wells at relatively small flow
rates), a smaller model domain with closer boundaries would more accurately model actual conditions.
(Anderson, 1991) The regional boundaries used in the model may be one reason why the on-site flow
direction has been incorrectly simulated to the west and south, rather than to the north.
! Revising estimates of hydraulic head based on all the available data. This analysis will yield more
accurate estimates of the key aguifer properties (transmissivity) than the current analysis of packer
test data. Unlike individual borehole packet tests that measure aguifer properties in the immediate
vicinity of the well, the aguifer test induces a more regional (site-wide) stress that, in turn,
provides estimates of the bulk hydraulic conductivity of the bedrock. (Freeze, 1979)
! Conducting a transient calibration of the model using the results of the C-l aguifer test. The closer
the predicted stress (in terms of the length of the simulation, number of wells, flow rate, etc.) is
to the calibrated stress, the more accurate the predicted response will be. (Konikow, 1992) By
calibrating the refined model to accurately simulate the measured response of the C-l aguifer test,
the refined model will be able to more accurately predict the response to slightly different, but
similar stresses such as those that would be imposed in operating the proposed remedy.
! Re-evaluating various remedial scenarios using the revised model. Specifically, the simulations should
strive to define the optimum number and placement of extraction wells to achieve the containment
objective. As discussed above, pumping additional groundwater for the purpose of mass removal should
not be a remedial action objective. Due to the effects of matrix diffusion, it is clear that mass
removal will not have an appreciable impact on groundwater guality, nor shorten the duration of the
operation of the extraction system. Thus, scenarios that involve the installation and pumping of
extraction wells for the sole purpose of mass removal should not be considered, and optimal
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containment should be the objective of the extraction system.
The modeling report recommends (FS, Appendix A at 22) that "the model should be upgraded from 'preliminary'
status to 'predictive' status by resolving data gaps and uncertainties and performing additional calibration.
. . . As more specific data is obtained for calibration, it should be used for both remedial design and
remediation action activities." (USEPA, 1997a) To this end, the ROD should incorporate these recommendations
and provide the necessary flexibility in describing the pumping scenarios to allow a refined model to be
developed to optimize the various components of the groundwater extraction system, such as the number of
extraction wells, the well locations, the well extraction rates, and aggregate extraction rate.
A modified conceptual hydrogeologic model has been prepared by ECKENFELDER INC., as presented in Section A-l
(Appendix A) of this document. In accordance with USEPA guidance (USEPA, 1994a), this model utilizes well
groupings based on hydrostratigraphic units defined on the basis of observed stratigraphic conditions and
based on response to the packer pump testing. Finally, this model presents a revised set of the
potentiometric surface contour maps for the August 29, 1994 measurement date, which, based on the model
refinements, represent more accurately the site conditions than the maps presented in the FS.
On page 9, the groundwater modeling report states that the numerical code used in the Feasibility Study
(DYNFLOW) is "certified by the International Groundwater Modeling Center (IGWMC)." However, based on personal
communication with Ms. Judith Schenk of the IGWMC (September 16,1997), the IGWMC does not "certify"
groundwater models. Since DYNFLOW is proprietary to COM, it is not readily available for independent testing
or review. It is inappropriate for the USEPA to allow the use of a proprietary model that cannot be
scrutinized by the public, as using such a proprietary model provides no meaningful opportunity for public
comment.
Nevertheless, since the DYNFLOW code is not available, ECKENFELDER, INC. has used the USGS finite-difference
code MODFLOW to incorporate the various refinements recommended in the preliminary modeling report and
described above. As further discussed in Section A-2 (Appendix A), the model consists of 5 layers, each
representing an individual hydrostratigraphic layer. The boundary conditions are chosen to reproduce the
observed groundwater flow direction and gradient at the site. Calibration is conducted both for steady-state,
non-pumping conditions, and under transient conditions to simulate the pumping test at C-l. Calibration
statistics are developed using the appropriate well grouping described above and in Section A-2. Last,
predictions are made using the refined model to evaluate various containment scenarios.
Using the refined model, two predictions have been made to evaluate groundwater containment. Extraction
scenario 1 evaluates the extraction from three (3) on-site wells screened at various depths within the
formation. Using these three wells, the model predicts a capture zone similar to CDM's at an estimated flow
rate of 25 gpm. This scenario results in capture down to the Lower Bedrock Aquifer. Extraction scenario 2
evaluates the same three wells plus two additional extraction wells located in areas of high contamination in
the Upper Bedrock aguitard. Again, this scenario predicts a capture similar to CDM's at an estimated flow
rate of 27 gpm. These results are detailed in Section A-3 (Appendix A).
As recited above, the remedy selection process described in the FS and Proposed Plan is based on a
"preliminary" model with limited calibration. Because the model relied upon is admittedly "preliminary" and
would have to be upgraded to be used for "predictive" purposes, the remedy selection process in the FS and
Proposed Plan is based on insufficient and, at times, inaccurate information. At a minimum, the ROD should be
written in such a manner to allow for the incorporation of the findings from a refined, calibrated
groundwater model.
3.4 The capture zones should be defined by a refined, calibrated groundwater model.
The remedial action objectives set forth in the Proposed Plan seek containment of that portion of the
groundwater that is contaminated. The preferred alternative requires groundwater extraction from all
groundwater bearing zones up to a saturation depth of approximately 375 feet. The capture zones defined in
the FS and Proposed Plan are unnecessarily large to achieve the remedial action objectives, as certain areas
within the capture zone are not contaminated. While it is certainly acceptable to provide a buffer zone to
ensure adequate capture, no justification is provided in the record for such a large capture zone.
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Consequently, the ROD should not specify the extent of the capture zone; instead, the capture zone should
only be identified as the contaminated area defined by the RI and any additional investigations conducted as
part of remedial design and be determined using a refined, calibrated groundwater model.
3.5 Off-site delineation sampling should be limited to the area downgradient of the Site, as defined by the
refined groundwater model.
The Proposed Plan states that additional off-site sampling is required to define the extent of any off-site
contamination. As described in Section 3.3 and Appendix A, mapping the groundwater elevations based on
stratigraphic position in conformance with USEPA guidance shows groundwater flow to be to the north in each
groundwater zone, including the upperzone above the gray shale in which the FS model predicts groundwater
flow to the south. The ROD should allow refined groundwater modeling to demonstrate the correct groundwater
flow direction and limit the off-site delineation sampling to areas downgradient of the site.
3.6 The final remedy must consider the significant constraints on the groundwater treatment plant discharge.
The Proposed Plan states the preferred groundwater remedial alternative would operate at twice the pumping
rate of the Interim Remedy; however the FS and Proposed Plan fail to consider the constraints on the
discharge from the groundwater treatment plant. While it is true that the capacity of the groundwater
treatment plant is 50 gpm, the existing MCUA permit and the NJDEP surface water discharge permit equivalent
are based on a discharge flow rate of 30 gpm. These limitations must be considered, as it is anticipated
that it is not feasible to discharge 50 gpm to either discharge point.
The MCUA does not favor groundwater treatment plant discharges in its system. Accordingly, the MCUA presently
seeks to have the discharge from the Chemsol site removed from its system. In fact, the Chemsol Facility
Coordinator has been advised that the MCUA would not approve any increase in flow to its plant from the Site.
(Potter Affidavit)
Further, surface water discharge standards are based on surface water quality criteria. Should the flow to
the stream be increased, the discharge standards can be expected to decrease to allow for the increased load
to the stream. The plant may be unable to meet these lower standards, particularly for inorganics, such as
barium and manganese, which are naturally present in the formation.
The final remedy selection must consider the discharge constraints. At a minimum, the ROD should be written
in such a manner that the configuration of extraction wells can be designed to achieve the remedial action
objectives while minimizing the volume of water to be discharged so that it may be discharged within the
capacity of the existing permits. To achieve this, extraction for mass reduction, in particular, should be
eliminated as a remedial action objective. As described in Section 3.1, no significant benefit would be
realized by targeting extraction to achieve mass reduction, to the extent it can be achieved at all. The
Superfund Administrative Reforms require source removal "only to the degree practicable," not to the degree
"possible," as sought in the Proposed Plan's remedial action objectives. (USEPA, 1995) The discharge
constraints make any additional pumping targeted for mass reduction impracticable. Further, as described in
Section 3.3 and Appendix A, refined modeling demonstrates that the pumping rate need not be twice that of the
Interim Remedy to achieve containment. Consequently, the remedial action objectives should be revised to
eliminate any reference to mass reduction and to seek containment. At a minimum, the remedial action
objectives should be revised to "remove and treat as much contamination as practicable from the fractured
bedrock."
3.7 The requirement to operate the biological treatment plant if the groundwater treatment plant discharges
to surface water has no technical basis.
The USEPA's requirement to operate the biological treatment plant has no technical basis. The proposed remedy
requires that the biological treatment plant be operated if the treatment plant effluent is discharged to
surface water. In the first place, the operation of the biological treatment plant would not assist in
reaching discharge standards; second, the biological treatment plant cannot be effectively operated based on
influent concentrations. Moreover, the current plant discharge passes aquatic toxicity testing, indicating
further that the requirement is unnecessary.
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Presently, the groundwater treatment plant effluent does not meet surface water discharge limits for only
barium, manganese and total dissolved solids (TDS). However, aguatic toxicity testing demonstrates the
effluent is not toxic to aguatic life. (See attached results) Operation of the biological treatment plant
would not assist in reaching the standards for those criteria currently exceeded. As previously stated, the
only surface water discharge standards that are exceeded in The plant effluent are for barium, manganese and
TDS; there have been no exceedences for soluble organics.
Moreover, the influent concentrations of soluble organics have decreased significantly. Conseguently, to
successfully operate the biological treatment plant, a supplemental food source would have to be added to,
establish adeguate biofilm growth. The cost estimates in the FS do not consider these excess costs. The
current treatment plant operating configuration consistently provides eguivalent removal of soluble organics
as was forecasted for the biological treatment plant. Conseguently, the reguirement to operate the biological
treatment plant should be eliminated from the proposed remedy as it is not necessary to achieve the discharge
to surface water standards.
3.8 A refined, calibrated groundwater model should be used to develop any long-term monitoring program.
The ROD should state that the long-term groundwater monitoring program will be based on a refined, calibrated
groundwater model. The FS recommends twenty (20) existing monitoring wells be used to conduct an annual
groundwater monitoring program. The groundwater samples collected as part of this program would be analyzed
for TCL organics and TAL inorganics, while stream samples would be analyzed for TCL organics, TAL inorganics,
and conventional water guality parameters. However, as previously discussed, any long-term monitoring program
must be based on an accurate understanding of the hydrogeologic system. Conseguently, the refined groundwater
model should be used to structure any long-term monitoring program, including the number and location of
wells to be sampled. Further, it is unnecessary to analyze samples collected for select TCL organics, TAL
inorganics and, in the case of stream samples, conventional water guality parameters. These reguirements are
unnecessary in consideration of the site contaminants and, accordingly, should be eliminated.
4.0 CONCLUSION
On behalf of the Chemsol PRP Group, this document comments on the FS and Proposed Plan for the Chemsol site.
The comments are summarized below.
! The remedial action objective to allow for future site use without restriction cannot be achieved by
the proposed soil remedy. First, because the proposed remedy would not meet the State's PCB soil
cleanup criterion, future Site use would continue to be subject to restrictions. Second, current and
anticipated future environmental and physical constraints located on the Site prohibit future Site use
without restrictions. Conseguently, the remedial action objectives should be revised to delete the
"without restrictions" reguirement.
! A remedial alternative that complies with the State PCB soil cleanup criterion is expected to result
in significantly greater costs and increased risk to human health and the environment. Accordingly,
if additional excavation is to be considered to achieve the State criterion, the remedy selection
would have to be re-evaluated.
! The selection of the proposed soil remedy is not supported by the administrative record.
• The Proposed Plan reguires disposal of soil as hazardous waste; however, in estimating the cost
of the proposed alternative, the FS adopts the conclusion reached in the RI that the soil is
nonhazardous. Conseguently, the ROD cannot reguire disposal as a hazardous waste because the
associated significantly higher disposal costs would have to be considered prior to such a
remedy selection.
• None of the samples analyzed for hazardous characteristics during the RI are within the areal
extent of excavation; thus, the RI's conclusion that the soil is nonhazardous is unsupported.
The ROD should state that the soil disposal facility would be determined by soil sampling and
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classification conducted during the implementation of the remedy.
• Should soil sampling conducted during remedial design indicate a much greater volume of soil
reguires excavation and disposal to satisfy the remedial action objectives, the remedy must be
re-evaluated.
• Stockpiled soil meeting the criteria for backfill or soil cover should not be reguired to be
disposed of, but should be permitted to be used as acceptable backfill or soil cover.
! A selection of soil capping as the remedial alternative is supported by the administrative record.
• USEPA guidance, on which soil cleanup levels are based, recommends capping for sites with
contaminant concentrations at the levels present at the Chemsol site. Without explanation, the
remedy selection process does not follow these guidance documents. The remedy selection should
be re-evaluated to correctly apply these guidance documents. Furthermore, in accordance with
the guidance, a soil cap should be selected as the remedy in the ROD.
• The FS grossly overestimates the cost for a soil cap. Conseguently, there has not been a valid
cost comparison of remedial alternatives, as reguired by the NCP. The remedy selection must be
re-evaluated to consider the significantly lower cost estimate.
! The presence of DNAPL in fractured bedrock at the Chemsol site indicates that aguifer restoration is
highly unlikely. Accordingly, an ARAR waiver on the basis of technical impracticability should be
granted. Furthermore, because groundwater cannot be restored, extraction for mass reduction provides
no protection of human health and the environment beyond that achieved by a containment extraction
system. In conformance with the NCP, USEPA guidance, and the FS remedial action objectives, the
remedial action objectives should be revised to seek hydraulic containment, and references to
restoration and mass reduction should be eliminated.
! Because a "preliminary" groundwater model is used as the basis for remedy selection, the proposed
groundwater remedy is evaluated based on incomplete and, at times, inaccurate information. As a
conseguence of the limited calibration and data gaps, the preliminary model misinterprets key model
parameters, resulting in an unsupported remedy selection. The ROD should be written in such a manner
to allow for the incorporation of the findings from a refined, calibrated groundwater model into the
design of the extraction system, the determination of adeguate capture zones, the structure of a
long-term monitoring program, and the scope of the off-site delineation.
! The final remedy must consider the critical limitations on effluent discharge. In particular, the
current discharge permits are based on a discharge flow rate of 30 gpm, and it is anticipated that it
would be infeasible to discharge in excess of these limits. At a minimum, the ROD should be written in
such a manner that the configuration of the extraction system can be designed to discharge the
effluent within the capacity of the existing permits. To achieve this, extraction for mass reduction,
in particular, should be eliminated as a remedial objective as it would provide no additional
protection of human health and the environment beyond that achieved by containment.
! The reguirement to operate the biological treatment plant if the groundwater treatment plant
discharges to surface water has no technical basis. The operation of the biological treatment plant
would not assist in reaching discharge standards. Also, the biological treatment plant cannot be
effectively operated based on influent concentrations. Accordingly, the reguirement should be
eliminated from the proposed remedy.
5.0 REFERENCES
Anderson, M.P., and W.W. Woessner, 1991. Applied Groundwater Modeling, Academic Press, Inc., p. 381.
Drake, Avery Ala, et al. , 1995, Bedrock Geologic Map of Northern New Jersey, U.S. Geologic Survey, Map
I-2540-A.
-------
Freeze, R.A., and J.A. Cherry, 1979. Groundwater, Prentice-Hall, p. 604.
Konikow, L.F. and J.D. Bredehoet 1992. Groundwater Models cannot be Validated, Advances in Water Resources,
15 (1992),pp. 75-83.
Lever, D.A. and M.H. Bradbury, "Rock-Matrix Diffusion and its Implications for Radionuclide Migration,"
Miner. Mag., v. 49, pp. 245-254, 1985.
Michalski, Andrew, "Hydrogeology of the Brunswick (Passaic) Formation and Implications for Ground Water
Monitoring Practice," Groundwater Water Monitoring Review, v. 10, No. 4, 1990.
National Research Council, Alternatives for Groundwater Cleanup, 1994
Parker, B.L., R.W. Gillham, and J.A. Cherry, 1994. "Diffusive disappearance of dense, immiscible phase
organic liguids in fractured geologic media," Ground Water, 32, 805-820.
U.S. Environmental Protection Agency, Estimating Potential for Occurrence of DNAPL at Superfund Sites, Office
of Emergency and Remedial Response, Publication 9355.4-07FS, January 1992.
U.S. Environmental Protection Agency, Feasibility Study Report, Chemsol, Inc. Superfund Site, USEPA Region
II, June 1997a.
U.S. Environmental Protection Agency, Focused Feasibility Study, Interim Action for Ground Water, Chemsol,
Inc., Piscataway New Jersey, Draft Final, USEPA Region II, July 1991.
U.S. Environmental Protection Agency, Guidance for Conducting Remedial Investigations and Feasibility Studies
Under CERCLA, Interim Final, Office of Solid Waste and Emergency Response, EPA 540/G-89/004, October 1988.
U.S. Environmental Protection Agency, Guidance for Evaluating the Technical Impracticability of Ground-Water
Restoration, Office of Solid Waste and Emergency Response, EPA 540-R-93-080, September 1993.
U.S. Environmental Protection Agency, Guidance on Remedial Actions for Superfund Sites with PCB
Contamination, Office of Emergency and Remedial Response, EPA 540/G-90/007, August 1990.
U.S. Environmental Protection Agency, "Methods for Monitoring Pump-and-Treat Performance," EPA/600/R-94/123,
June 1994a.
U.S. Environmental Protection Agency, Remedial Investigation Report, Chemsol, Inc. Superfund Site, USEPA
Region II, October 1996.
U.S. Environmental Protection Agency, "Revised Interim Lead Guidance for CERCLA Sites and RCRA Corrective
Action Facilities," Office of Solid Waste and Emergency Response, EPA/540/F-94/043, August 1994b.
U.S. Environmental Protection Agency, "Superfund Administrative Reforms: Reform Initiatives," October 1995.
U.S. Environmental Protection Agency, "Superfund Proposed Plan, Chemsol, Inc. Superfund Site, Piscataway, New
Jersey," USEPA Region 2, August 1997b.
-------
APPENDIX A
EVALUATION OF GROUNDWATER
EXTRACTION ALTERNATIVES
CHEMSOL, INC. SITE
PISCATAWAY, NEW JERSEY
Prepared for:
Chemsol Site PRP Group
Prepared by:
ECHENFELDER INC.
1200 MacArthur Boulevard
Mahwah, New Jersey 07430
October 1997
-------
TABLE OF CONTENTS
Page No.
Al.O INTRODUCTION Al-1
A2.0 CONCEPTUAL HYDROSTRATIGRAPHIC MODEL A2-1
A3.0 GROUNDWATER FLOW MODEL A3-1
A3.1 Groundwater Model Setup A3-1
A3.2 Model Boundary Conditions A3-3
A3.3 Areal Recharge A3-4
A3.4 External Influences A3-4
A3.5 Model Calibration A3-4
A3.6 Model Sensitivity Analysis A3-8
A4.0 CAPTURE ZONE SIMULATIONS A4-1
A4 .1 Extraction Scenarios A4-1
A4.2 Model Limitations A4-3
ATTACHMENTS
Attachment A - Quantitative Analysis of the Hydrogeologic System
Attachment B - Aguifer Test Plots and Calculations
B-l - Distance Drawdown Analyses of RI Packer Test Data,
Well DMW-10(Round 3, Test 3)
B-2 - Neuman-Witherspoon Analyses of McLaren/Hart Aguifer Test
Data
B-3 - Theis Type-Curve Analyses of Recover Data from RI Packer Test,
Well C-6(Round 3, Test 3)
B-4 - Distance-Drawdown Analyses of RI Packer Test Data, Well C-7
(Round 3, Test 3)
B-5 - Neuman-Witherspoon Analyses of RI Packer Test Data (Round 3,
Test 3)
Attachment C - Well Survey
LIST OF TABLES
Follows
Table No. Title Page No.
A2-1 Well Groupings by Hydrostratigraphic Unit A2-1
A2-2 Groundwater Elevations A2-2
A3-1 Chemsol Inc. Site Groundwater Model, Calibration Statistics A3-7
A3-2 Calibration Parameter, Chemsol Groundwater Model A3-7
A3-3 Sensitivity Analysis, Chemsol Groundwater Model A3-8
-------
LIST OF FIGURES
Follows
Table No. Title Page No.
A2-1 Projected Bedrock Cross-Section A2-2
A2-2 Conceptual Geologic Cross-Section A-A' A2-2
A2-3 Conceptual Geologic Cross-Section B-B' A2-2
A2-4 Potentiometric Contour Map Wells Screened in the Overburden A2-2
Zone, August 29, 1994
A2-5 Potentiometric Contour Map Wells Screened in the Upper
Permeable Aguifer, August 29, 1994
A2-6 Potentiometric Contour Map Wells Screened in the Upper
Principal Aguifer, August 29, 1994
A2-7 Potentiometric Contour Map Wells Screened in the Lower A2-2
Principal Aguifer, August 29, 1994
A3-1 Model Grid A3-2
A3-2 Vertical Profile of Model Grid A3-2
A3-3 Comparison of Measured and Predicted Head Upper Permeable A3-7
Aguifer
A3-4 Comparison of Measured and Predicted Head Upper Principal A3-7
Aguifer
A3-5 Comparison of Measured and Predicted Heal Lower Principal A3-7
Aguifer
A3-6 Comparison of Measured and Predicted Heads A3-7
A3-7 Modeled (vs) Aguifer Test Drawdown C-4 A3-7
A3-8 Modeled (vs) Aguifer Test Drawdown DMW-5 A3-7
A3-9 Modeled (vs) Aguifer Test Drawdown C-3 & TW-9 A3-7
A3-10 Modeled (vs) Aguifer Test Drawdown TW-8 A3-7
A4-1 Estimated Capture Zone, C-l @ 15 gpm Principal Aguifer A4-2
-------
LIST OF FIGURES (CONTINUED)
Follows
Figure No. Title Page No.
A4-2 Estimated Capture Zone 1 Well @ 5 gpm Upper Permeable A4-3
Aguifer
A4-3 Estimated Capture Zone 1 Well @ 5 gpm Lower Bedrock A4-3
Aguifer
A4-4 Estimated Capture Zone Pumping 2 Wells @ 1 gpm Ea. A4-3
-------
Al.O INTRODUCTION
A numerical groundwater flow model was constructed for the Chemsol Inc. Superfund Site both as an
interpretative tool and as a tool to evaluate potential groundwater extraction remedies. The interpretative
modeling process produced a calibrated base case simulation of existing hydrogeologic conditions, which was
then used to evaluate potential remedial scenarios for the Site. The model was used to establish the
locations and pumping rates of potential groundwater extraction remedies.
The body of information used to develop the groundwater model was derived from a site-wide Remedial
Investigation (RI) which was conducted for Operable Unit I of the Chemsol Inc. property located in Piscataway
Township, New Jersey. The field investigation portion of the RI was conducted from October 1992 through
November 1994 by CDM Federal Programs Corporation for the U.S. Environmental Protection Agency. The results
of the RI were reported in a document titled "Remedial Investigation Report, Chemsol Inc. Superfund Site"
(hereinafter referred to as the RI report), dated October 1996.
The RI has been reviewed by ECKENFELDER INC. on behalf of the Chemsol Site PRP Group. The results of this
review have been used to support this groundwater modeling effort. ECKENFELDER INC. has performed further
analysis of the hydrogeologic data beyond that presented in the RI. This includes a quantitative analysis of
pump test data obtained during the RI and previous investigations (See Attachments A and B) and a
re-interpretation of the conceptual hydrogeologic model for the site (Section A2.0). The re-interpretation of
the conceptual hydrogeologic model serves as the bases for the numerical model presented Section A3.0.
A2.0 CONCEPTUAL HYDROSTRATIGRAPHIC MODEL
The hydrostratigraphic setting beneath the Chemsol Superfund site is complex, being characterized by a
dipping, multi-layered bedrock system. Numerous monitoring wells have been installed at various depths during
previous investigations in an effort to evaluate the hydrogeologic and water quality conditions.
A review of the existing hydrogeologic data for the site has been conducted by ECKENFELDER INC. to develop a
refined conceptual model of the groundwater flow regime. This conceptual model represents a fundamental
departure from that described by CDM in the RI report in that it groups the wells for mapping purposes on the
basis of stratigraphic position rather than on the basis of depth (Table A2-1). The current conceptual model
was developed based on an analysis of the data from the RI report (CDM, 1996) and further review of previous
site investigation data by both McLaren/Hart and AGES Corporation. A quantitative analysis of available pump
test data is presented in Attachment A.
The site is conceptually subdivided into six units that have been identified on the basis of site
stratigraphy and the observed aquifer response to the various pump tests that have been performed at the
site.
! Overburden Water-Bearing Zone
! Upper Bedrock Aquitard
! Upper Permeable Aquifer
! Upper Gray Shale (Aquitard)
! Principal Aquifer
! Deep Bedrock Unit
-------
TABLE A2-1
WELL GROUPINGS BY HYDROSTRATIGRAPHIC UNIT
Chemsol Inc. Superfund Site
Overburden Water-Bearing Zone
OW-1 OW-10 OW-12 OW-14
OW-2 OW-11 OW-13 OW-15
OW-4
Upper Bedrock Aquitard
TW-1 TW-3 TW-5A TW-11
TW-2 TW-4 TW-10 TW-12
Upper Permeable Aquifer
C-6 C-8 C-10
C-7 C-9
Principal Aquifer
Upper Zone
TW-6 TW-13 C-l DWM-9
TW-7 TW-14 C-3 DMW-10
TW-8 TW-15 C-4
TW-9 C-5
Lower Zone
DMW-1 DMW-5 DMW-7 C-2
DMW-3 DMW-6 DMW-11 MW-103
Deep Bedrock Unit
DMW-2 DMW-4 MW-101 MW-104
DMW-3 DMW-8 MW-102
-------
The hydrostratigraphic units are depicted in the generalized cross section presented on Figure A2-1. Figure
A2-1 also depicts the spatial relationship between well screen depth and hydrostratigraphic units. Conceptual
geologic cross sections are presented on Figures A2-2 and A2-3.
Based on the well grouping presented in Table A2-1, generalized plan-view potentiometric maps (Figures A2-4
through A2-7) have been prepared that depict static pre-pumping conditions using data obtained on August 29,
1994 (Table A2-2) . These include maps for the hydrostratigraphic zones in which horizontal flow predominates
including the Overburden zone, Upper Permeable aguifer, and the upper and lower portions of the Principal
Aguifer.
The hydrostratigraphic units are described briefly, as follows:
! Overburden Water-Bearing Zone - represents the uppermost water-bearing unit at the site. This
zone is contained within the composite unit represented by the thin overburden soils and the
upper veneer of highly weathered bedrock. Groundwater within this unit flows laterally toward
the northeast (Figure A2-4), generally in response to ground surface topography. The overburden
zone is likely to be in hydraulic communication with the small ditches and streams, which flow
toward the northeast across the site.
! Upper Bedrock Aguitard - is represented by the bedrock below the overburden zone that is
characterized by relatively low hydraulic conductivity. The upper portion of this unit
represents weathered bedrock within which the joints and fractures are filled with silt or clay
serving to reduce the hydraulic conductivity. As a result, considerable vertical head loss is
observed within this unit downward to the underlying Upper Permeable Aguifer. For example, the
vertical head difference between well TW-10 screened in the upper portion of this unit with
well C-7 screened in the underlying Upper Permeable Aguifer is over 4 feet. The vertical
hydraulic conductivity of this unit has been estimated to range from 1.1 x 10 -4 to 6.4 x 10 -5
cm/sec on the basis of a Neuman-Witherspoon analysis of aguifer test data, described in
Attachment A. This is over two orders of magnitiude less than the hydraulic conductivity of the
underlying Upper Permeable Aguifer. This high permeability contrast results in a predominantly
vertical hydraulic gradient within the Upper Bedrock formation.
-------
TABLE A2-2
GROUNDWATER ELEVATIONS
CHEMSOL INC., SITE
PISCATAWAY, NEW JERSEY
Reference Ground
Well Elevation Zone (b.) Elevation
(ft., msl) (ft., msl)
Coordinates (c.)
Northing Easting
C-l
C-2
C-3
C-4
C-5
C-6
C-7
C-8
C-9
C-10
DMW-1
BMW- 2
BMW- 3
BMW- 4
BMW- 5
BMW- 6
BMW- 7
BMW- 8
BMW- 9
BMW- 10
BMW- 11
MW-101
MW-102
MW-103
MW-104
OW-1
OW-2
OW-4
OW-10
OW-11
OW-1 2
OW-1 3
OW-1 4
OW-1 5
PZ 1
PZ IB
PZ 2
PZ 2B
PZ 3
PZ 4
PZ 4B
PZ 5
PZ 5B
79.83
86.24
80.52
80.96
80.10
76.12
80.20
81.40
85.33
80.71
85.40
85.07
80.49
80.44
78.89
79.23
76.62
77.77
76.35
79.58
85.04
79.80
78.69
81.09
88.58
78.37
81.64
79.96
79.06
75.08
84.65
82.96
92.14
75.08
76.62
77.05
76.45
75.94
78.65
78.03
78.25
76.68
76.86
3/4
5
4
4
4
3
3
3
3
3
5
6
6
6
5
5
5
6
4
4
5
6
6
5
6
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
77
78
79
78
82
83
78
78
77
77
75
76
77
77
80
89
76
79
77
78
74
73
74
74
74
76
74
.60
—
.40
.00
.00
--
—
—
—
—
.90
.40
.70
.60
.10
.70
.60
.00
—
—
—
.40
.50
.00
.00
.20
.70
.60
.30
.70
—
—
—
.00
.90
—
.50
—
.30
.00
--
.90
--
629,
629,
629,
629,
629,
630,
630,
630,
629,
630,
629,
629,
629,
629,
630,
630,
630,
630,
630,
630,
629,
629,
629,
630,
628,
630,
629,
629,
629,
630,
629,
629,
629,
630,
630,
630,
630,
630,
629,
630,
630,
630,
630,
997
865
642
636
815
574
534
140
925
292
867
670
656
660
166
138
132
121
578
540
918
995
863
144
957
036
898
921
660
592
888
988
643
390
157
172
051
066
919
280
289
250
251
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
2,
062,
061,
062,
062,
062,
062,
061,
061,
061,
061,
062,
062,
062,
062,
062,
062,
062,
062,
062,
061,
061,
062,
062,
061,
062,
062,
062,
062,
062,
062,
061,
061,
061,
062,
062,
062,
062,
062,
062,
062,
062,
062,
062,
281
790
565
307
297
609
803
554
589
975
117
085
566
532
022
030
439
428
618
816
792
253
471
572
510
275
206
332
549
609
897
673
657
545
437
437
474
475
438
084
090
208
193
—
—
—
—
—
--
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
--
—
—
—
—
—
—
—
—
—
—
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
58.50
58.36
58.39
58.20
58.37
59.21
59.10
59.32
59.41
59.11
58.36
57.86
58.36
57.86
58.28
58.21
58.32
57.85
58.18
58.42
58.31
58.02
57.81
58.30
58.42
73.57
78.04
75.61
76.83
69.34
79.61
78.17
83.99
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
-------
TABLE A2-2
GROUNDWATER ELEVATIONS
CHEMSOL INC., SITE
PISCATAWAY, NEW JERSEY
Reference Ground
Well Elevation Zone (b.) Elevation
(ft.,msl) (ft., msl)
74.20
73.80
75.70
PZ 6
PZ 6D
PZ 7
PZ 8
PZ 8D
PZ 9D
PZ 10D
SG@PZ 4
SG@PZ 8
TW-1
TW-2
TW-3
TW-4
TW-5
TW-5A
TW-6
TW-7
TW-8
TW-9
TW-10
TW-11
TW-1 2
TW-1 3
TW-1 4
TW-1 5
76.15
76.14
75.71
77.57
77.51
75.98
79.08
71.67
73.95
90.15
85.81
81.59
78.31
76.24
75.98
78.88
80.16
85.11
80.29
79.96
75.76
75.73
78.17
89.23
82.90
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
4
4
4
4
2
2
2
4
4
4
89.10
84.20
79.60
76.60
74.30
74.30
76.70
78.10
83.30
78.60
78.50
75.00
73.60
76.30
88.60
82.20
Coordinates (c.)
Northing Easting
630,227
630,227
630,229
629,971
629,986
630,295
630,086
630,267
629,983
629,638
629,900
630,160
630,218
630,175
630,166
629,894
629,655
629,647
629,662
630,549
630,594
630,594
630,092
629,332
629,380
2,062,373
2,062,389
2,062,459
2,062,477
2,062,477
2,062,410
2,062,273
2,062,067
2,062,495
2,061,637
2,061,591
2,061,538
2,062,010
2,062,475
2,062,470
2,062,490
2,062,399
2,062,102
2,062,557
2,061,809
2,062,620
2,063,195
2,063,250
2,061,661
2,062,367
29-Aug-94
DTW
(ft.)
NM
NM
NM
NM
NM
NM
NM
NM
NM
—
—
—
—
—
--
—
—
—
—
—
—
—
—
—
--
Elev.
(ft., msl)
NM
NM
NM
NM
NM
NM
NM
NM
NM
59.56
59.98
59.56
59.37
62.98
62.28
58.76
61.46
59.15
58.17
63.45
67.21
65.27
59.76
62.01
62.15
Notes:
a. Abbreviations are as follows:
"NE" - no entry to well
"NM" - not measured
b. Wells are screened in the following zones:
1. Overburden Water-Bearing zone
2. Upper Bedrock Aguitard
3. Upper Permeable Aguifer
4. Upper of portion of Principal Aguifer
5. Lower of portion of Principal Aguifer
6. Deep Bedrock Zone
c. Northings & Eastings were obtained from surveyors coordinates, except for "PZ" wells which were obtained
from a map by McLaren/Hart.
d. Elevations for PZ wells with D suffix were derived from McLaren/Hart database.
e. Reference elevation for Staff Gauges PZ-4 and PZ-8 are for the 0 ft. mark. DTW reading is above the 0
mark.
-------
! Upper Permeable Aquifer - is a highly fractured bedrock zone of relatively high hydraulic
conductivity that lies immediately above the upper gray shale. The presence of this unit was
initially revealed in boreholes drilled during the RI. These data indicate that this zone
ranges from 15 feet to 40 feet thick.
The transmissivity of the Upper Permeable aguifer has been estimated to be approximately 12,650 gpd/ft on the
basis of aguifer testing described in Attachment A. Groundwater flow within this unit is predominantly
horizontal with a relatively flat hydraulic gradient to the northeast, as shown on Figure A2-5.
! Upper Gray Shale (Aguitard) - Analysis of aguifer test data indicate that the Upper Gray shale
provides hydraulic separation between the Upper Permeable Aguifer and the Principal Aguifer.
This separation is also observed in the vertical head losses observed between the two aguifers
across the Upper Gray shale.
! Principal Aguifer - is comprised of the bedrock zone between the upper and deep gray shale beds
with a thickness of approximately 180 feet. The transmissivity of this unit has been shown to
be typically on the order of 12,700 gpd/ft with a storativity of approximately 2 x 10 -4, as
described in Attachment A.
Slight downward gradients are observed within the Principal aguifer, based on a comparison of wells screened
in its upper and lower portions. To evaluate the horizontal components of flow, this unit has been subdivided
into an upper and lower portion for mapping purposes, based on the vertical heterogeneity observed during the
guantitative analysis (Attachment A) . Wells screened in the contiguous upper and deep gray shale units have
been observed to be in sufficient hydraulic communication with the Principal aguifer that they have been
included in the potentiometric mapping of this unit. Potentiometric maps for the upper and lower portions of
this unit (Figures A2-6 and A2-7, respectively) reveal a northerly direction of groundwater flow.
! Deep Bedrock Unit - includes the bedrock below the deep gray shale. The deep gray shale
provides some hydraulic separation between the Principal aguifer and the deep bedrock,
determined on the basis of aguifer testing. Insufficient data are available in this unit to
determine the horizontal direction of flow.
A3.0 GROUNDWATER FLOW MODEL
A numerical groundwater flow model was constructed for the Chemsol Inc. Site both as an interpretative tool
and an evaluation tool for design of the final groundwater remedy. The interpretative modeling process
produced a calibrated base case simulation of existing hydrogeologic conditions, which was then used to
evaluate potential remedial scenarios for the Site. The model was used to evaluate the capture zones produced
by various combinations of extraction well locations and pumping rates.
A3.1 GROUNDWATER MODEL SETUP
The modular, three-dimensional, finite difference groundwater flow model code, typically referred to as
MODFLOW, was used for this project. The original code was developed by the U.S. Geological Survey (McDonald
and Harbaugh, 1988); however, a slightly modified version of the code marketed by Boss International Inc. was
used for this Site. This version is designed to interact with the Groundwater Modeling System (GMS), a pre-
and post-processor developed by Boss International Inc.
As presented in Section A2.0, the hydrostratigraphic setting beneath the Chemsol Superfund site is complex
being characterized by a dipping, multi-layered bedrock system. Based on the guantitative analysis
(Attachment A) and the stratigraphic regrouping of monitoring wells, the site has been conceptually
subdivided into six hydrostratigraphic units. The units are as follows:
! Overburden Water-Bearing Zone
! Upper Bedrock Aguitard
! Upper Permeable Aguifer
! Upper Gray Shale (Aguitard)
-------
! Principal Aquifer
! Lower Gray Shale (Aquitard)
! Deep Bedrock Unit
Each of these hydrostratiqraphic units dips to the north-northwest and subsequently sub-crop on, or within
the vicinity of, the site (see Fiqures A2-2 and A2-3). The reqional model qrid used in this analysis is
superimposed over the project area on Fiqure A3-1. The qrid is centered around the site and consists of 43
rows and 87 columns. The model qrid is bounded to the north by Bound Brook and extends approximately 7,770
feet southwest, and 5,220 feet northeast from the Chemsol Inc. Site. The qrid was limited in extent in the
southwest and northeast directions due to the lack of qeoloqic information available off site. The qrid
extends to the southeast, correspondinq to the sub-crop of the associated hydrostratiqraphic units. The
dimensions of individual cells ranqe from 10 feet by 10 feet at extraction well C-l within the central
portion of the project area, to 810 feet by 720 feet near the perimeter of the qrid. The finer qrid spacinq
was selected to provide a more refined depiction of conditions at and near the Site, whereas larqer cells
were used beyond the project area which is not likely to be influenced by the proposed remedial activities
and where little field data exists for comparison. The qrid has been oriented to the north-northwest so that
the X-axis of the qrid parallels the sub-crops of the primary hydrostratiqraphic units.
Vertically, the qrid consists of five layers:
Layer 1 - Upper Bedrock Aquitard
Layer 2 - Upper Permeable Aquifer
Layer 3 - Upper Principal Aquifer
Layer 4 - Lower Principal Aquifer
Layer 5 - Lower Bedrock Aquifer
Setup of dippinq layers within MODFLOW can be accomplished by representinq the dippinq hydrostratiqraphic
units as horizontal qrid layers (Anderson, 1991). The vertical qrid confiquration used to represent the
hydrostratiqraphic units is presented on Fiqure A3-2. the stair-step qrid confiquration represents the
hydrostratiqraphic sub-crops. Areal recharqe is applied to the upper most active layer within the model. That
is, recharqe will be applied to the entire surface of layer 1, and only to exposed portions of the qrid for
Layers 2, 3, 4, and 5, representinq recharqe to the sub-crop areas. The Shallow Gray Marker Unit and the Deep
Gray Marker Unit are represented as leakance terms. The Overburden Water-Bearinq Zone was not represented in
the model due to its limited vertical extent.
Layer 1 simulates qroundwater flow within the Upper Aquitard which overlies the primary water bearinq units.
Althouqh layer thickness is not entered into the model directly, transmissivity was used to represent the
pinchinq oout of Layer 1 on site.
Layer 2 represents qroundwater flow within the Upper Permeable aquifer. The thickness of the Upper Permeable
aquifer was estimated to ranqe from a pinch-out to approximately 40 feet.
Layer 3 represents qroundwater flow within the Upper Principal Aquifer. The thickness of this unit was
estimated to ranqe from a pinch-out to approximately 91 feet. Layer 4 represents the Lower Principal Aquifer.
The thickness of Layer 4 was assumed to be the same as Layer 3. This division of the Principal aquifer is
based on the observed head differences between the top and bottom of the unit and the vertical heteroqeneity
observed within the unit as part of the quantitative analysis (see Attachment A).
Layer 5 represents qroundwater flow within the Lower Bedrock Aquifer. Althouqh little information is
available for this unit, its thickness was assumed be approximately 150 feet.
A3.2 MODEL BOUNDARY CONDITIONS
Based on the observed qroundwater flow directions on-site (qenerally to the north-northeast) Bound Brook is
considered to be the natural hydraulic boundary for model Layer 1 throuqh Layer 5 and has been simulated
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using "river" cells. An approximate elevation of the surface water (specified head) in these cells was
obtained from the USGS topographic map.
The southwest and northeast model perimeter is simulated using "general head" boundary (GHB) cells. These
boundary cells simulate the extension of the aguifer beyond the model boundary by allowing water to enter or
exit the model domain as a function of the local gradient, transmissivity, and cell dimensions. The specific
head values used were estimated by projection of groundwater elevation data collected from the Site on April
29, 1994 and by the elevation Bound Brook.
The southeastern perimeter of the model domain represents the pinch-out associated with the sub-crops of the
water-bearing units. Consistent with a pinch-out, the southeastern perimeter is represented as a no-flow
boundary.
A3.3 AREAL RECHARGE
CDM Federal Programs Corporation (March 1996) completed a water budget for the area associated with Chemsol
Inc. Site. The results of the water budget suggest that area recharge is likely to range between 4 and 7.5
inches pre-year. However, since the current model configuration does not include the Overburden Water-Bearing
Zone. The "effective1 recharge to the bedrock units will be considerably less than the estimated 4 to 7.5
inches per year.
A3.4 EXTERNAL INFLUENCES
A well record survey was conducted in the area surrounding the Chemsol Site to identify potential discharges
that may be influencing groundwater conditions associated with the site. Searches for high capacity wells
(greater than 100,000 gpd) and lower capacity wells have been completed. The results of this well record
survey are presented in Attachment C and indicate 12 high capacity wells are located within 1 to 2 miles of
the site. A review of the screened intervals and relative position to the site, as related to our
understanding of the area hydrogeology, indicates that their influence on the site would likely be small.
Additionally, all identified well locations fell out-side of the model domain. Numerous low capacity wells
were also identified (see Attachment C). The closest well to the site that would likely have an impact was
the "car wash" well. However, information provided by Piscataway Township indicates that this well is not
currently in operation.
A3.5 MODEL CALIBRATION
For this report, the term calibration refers to the standard approach (Anderson, 1991) of matching measured
heads to model heads at steady-state conditions and adjusting input parameters within reasonable limits until
an acceptable match is achieved. However, this process alone may not result in a unigue set of parameters
because different combinations of parameters may produce an egually good match with measured heads. The
steady-state calibration process, therefore, was supplemented by the simulation of a measured hydraulic
response to a known stress (aguifer test data). Data were collected from an aguifer test conducted
McLaren/Hart in 1993 and used in the transient calibration.
The first step in the calibration process is the selection of initial input parameters. The values used for
the initial run were obtained from the results of the RI and guantitative analysis (see Attachment A) and are
summarized below.
! Layer 1 (Upper Bedrock Aguitard) was simulated as a MODFLOW aguifer type 3 (confined). A
Neuman-Witherspoon analysis was completed of this unit. The results of this analysis indicated
that the vertical hydraulic conductivity ranges from 0.18 ft/day to 0.31 ft/day. The horizontal
hydraulic conductivity is estimated to be 1 ft/day to 4 ft/day, assuming that the horizontal
hydraulic conductivity. For the initial run, a hydraulic conductivity of 2.5 ft/day was used.
These values of hydraulic conductivity are consistent with the conceptual view that this unit
is an aguitard.
! Layer 2 (Upper Permeable Aguifer) was simulated as a MODFLOW aguifer type 3
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(unconfined/confined). Two-packer tests were completed in this unit resulting in a
transmissivity of 1,644 ft/day and 1,737 ft/day. A hydraulic conductivity of 1,690 ft/day was
used in the initial run.
! Layer 3 (Upper Principal Aquifer) was simulated as a MODFLOW aquifer type 3 (confined). As
presented in the quantitative analysis (see Attachment A) transmissivity was found to ranqe
from 668 ft/day to 3,877 ft/day. The transmissivity of this unit has been shown to be typically
on the order of 1,700 ft/day with a storativity of approximately 2 x 10 -4. The vertical
hydraulic conductivity was estimated to be 0.99 ft/day. These parameter values were used in the
initial run.
! Layer 4 (Lower Principal Aquifer) was simulated as a MODFLOW aquifer type 3 (confined). The
initial aquifer characteristics and parameters are consistent with that estimated for Layer 3
(Upper Principal Aquifer).
! Layer 5 (Lower Bedrock Aquifer) was simulated as a MODFLOW aquifer type 3 (confined). The
aquifer characteristics and parameters are consistent with that estimated for Layer 3 (Upper
Principal Aquifer). As a result, a transmissivity value of 1,425 ft/day was used in the initial
run.
! As discussed in Section A3.3, the "effective" aeral recharqe is expected to be less than the 4
to 7.5 inches per year estimated in the water budqet. Based on previous experience, an initial
estimate of 4 inches per year was chosen to beqin the model calibration process. Areal recharqe
rate at the various sub-crop areas is likely to be qreater than that associated with the lower
permeability, Upper Aquitard. Therefore, aeral recharqe associated with the Upper Aquitard was
considered approximately 50 percent less than that of the aquifer sub-crops.
! The quantitative analysis (see Attachment A) indicated that the Upper Gray Shale and the Deep
Gray Shale provided hydraulic separation between the associated aquifers. Therefore, these
aquitards are represented in the model as leakance terms. Since quantitative estimates of
leakance are not available from the field data, an initial leakance value of 0.0001/day was
selected to beqin the model calibration process based on experience.
Once the initial input parameters were selected, the initial base case simulations were conducted and results
were evaluated usinq a head residual analysis. A head residual is the difference between the measured head in
a well and the model-predicted head in the cell that represents the location and depth of the well. Positive
residuals indicate the predicted head is lower than the measured value, whereas neqative residuals indicate
the predicted head is hiqher than the measured value. The sum of the residuals is an indicator of an overall
bias (heads qenerally too hiqh or too low) in the prediction. If, for example, the predicted heads were quite
close to the measured heads but most were slightly hiqher, this term would be elevated in the neqative
direction. The averaqe of the absolute residuals is an indicator of the accuracy of the match and, as a
qeneral rule, should be less than 10 percent of the steady-state head chanqe across the project area.
Dependinq on the layer, head chanqes across the site ranqe from 12 feet in the Overburden to less than 0.2
feet in the Lower Principal Aquifer. A tarqet residual of 0.5 feet was selected for this site as it
represents a head chanqe in the middle of this ranqe (5 feet) and is consistent with the head chanqe of the
Upper Principal Aquifer.
Durinq the steady-state calibration process, the various input parameters were adjusted within reasonable
limits and the results noted. This process was continued until an acceptable match (as defined above) was
made with head values measured on April 29, 1994. Table A3-1 presents the results of the calibration
simulation. Of the 28 measured values, the sum of all residuals is -4.89 feet and the averaqe of the absolute
residuals is 0.47 feet which meets the 10 percent quideline defined previously.
The simulation usinq the calibrated, steady-state base case model parameters was further evaluated by
comparinq the computed head confiquration with the contoured qroundwater elevation data collected on April
29, 1994. The comparisons for the model heads versus measured heads for the Upper Permeable Aquifer, the
Upper Principal Aquifer and the Lower Principal Aquifer are provided on Fiqures A3-3, A3-4, and A3-5,
-------
respectively. Considering the uncertainty associated with fractured bedrock flow systems, the comparisons of
measured head contours to modeled head contours indicate a reasonable match to field conditions.
An additional observation, with respect to groundwater elevation data, relates to the additional
potentiometric surface map developed from groundwater elevation data collected in April 1997. This
potentiometric surface represents groundwater conditions within the Upper Principal Aguifer following
approximately two years of pumping C-l at approximately 22 gpm. As shown on Figure A3-6, the general
configuration of the observed head distribution was reproduced by the calibrated model.
To further test the calibrated model, a transient calibration was conducted using aguifer test data collected
by McLaren/Hart in 1993. McLaren/Hart conducted an aguifer test by pumping C-l at approximately 22.5 gpm for
72 hours. The transient calibration was completed by comparing measured drawdown to modeled drawdown.
Figures A3-7 through A3-10 present the comparison of measured versus modeled drawdown for the available data
from the Principal Aguifer. These plots illustrate that the predicted drawdown tracks close to the observed
drawdown in each of the observation wells.
The calibrated model parameters are presented on Table A3-2.
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TABLE A3-1
CHEMSOL INC. SITE GROUNDWATER MODEL
CALIBRATION STATISTICS
Well ID
Measured
Head
(ft.)
Modeled
Head
(ft.)
Residual
(ft.)
Upper Bedrock Aquitard
TW-3 59.56
TW-4 59.37
TW-2 59.98
59.14
59.06
59.28
0.42
0.31
0.7
Upper Permeable Aquifer
C-7
C-8
C-10
C-6
C-9
59.1
59.32
59.11
59.21
59.41
58.78
59.01
58.9
58.71
59.12
0.32
0.31
0.21
0.5
0.29
Upper Principal Aquifer
DMW-10
DMW-9
C-l
C-5
TW-6
TW-8
C-4
TW-13
C-3
58.42
58.18
58.5
58.37
58.76
59.15
58.2
59.76
58.39
58.53
58.43
58.74
58.84
58.78
58.93
58.92
58.59
58.88
-0.11
-0.25
-0.24
-0.47
-0.02
0.22
-0.72
1.17
-0.49
Lower Principal Aquifer
MW-103 58.3
DMW-5 58.28
DMW-6 58.21
DMW-7 58.32
DMW-1 58.36
58.7
58.67
58.69
58.77
58.91
-0.4
-0.39
-0.48
-0.45
-0.55
Lower Bedrock Aquifer
DMW-8 57.82
MW-101 58.02
DMW-2 57.83
MW-102 57.81
DMW-4 57.86
DMW-3 58.36
58.62
58.69
58.85
58.72
58.8
58.79
-0.8
-0.67
-1.02
-0.91
-0.94
-0.43
Averaqe of Absolute Residual = 0.477
Sum of Residual = -4.89
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A3.6 MODEL SENSITIVITY ANALYSIS
A sensitivity analysis was performed to identify the relative importance of the various parameters and to
evaluate the degree to which the base case represents a unique solution. The analysis was performed by
changing the value of one input parameter at a time and comparing the results (head residuals) to the base
case simulation. The sum of the residuals and the average absolute residual were calculated for each
sensitivity run and compared to the corresponding values for the base case simulation. To provide a standard
point of comparison, each input parameter value was increased (and decreased) until a change of at least 10
percent of the average absolute residual was observed.
The input parameters that were evaluated are shown in the first column of Table A3-3. The "factor" represents
the direction and magnitude of the change from the base case value. The results indicate that the least
sensitive parameters are the leakance values between the layers. For these parameters, changes of at least an
order of magnitude were required to alter the base case match by 10 percent. The most sensitive parameters
were the transmissivity of the Upper Principal Aquifer and effective recharge. Altering the base case value
of transmissivity by a factor of less than 2x achieved the 10 percent criterion for change. (Although an
increase in the transmissivity indicates a slightly better match than the base case values, these higher
values did not produce an acceptable match with the drawdown data when used to simulate the aquifer test.)
These results are generally consistent with our conceptual model in that the most permeable unit typically
controls the elevation of water levels and thus the direction of groundwater flow.
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TABLE A3-2
CALIBRATION PARAMETER
CHEMSOL GROUNDWATER MODEL
Water-bearing
Zone
Upper Aquitard
Upper Permeabel Aquifer
Upper Principal Aquifer
Lower Principal Aquifer
Lower Bedrock Aquifer
Upper Bedrock Aquitard
Upper Gray Marker Unit
Lower Gray Marker Unit
Model
Layer
Layer 1
Layer 2
Layer 3
Layer 4
Layer 5
Layer I/Layer 2
Layer 2/Layer 3
Layer 4/Layer 5
a - Indicates Arial recharqe and recharqe over
Model
Parameter
Hydraulic Conductivity
Transmissivity
Transmissivity
Transmissivity
Transmissivity
Leakance
Leakance
Leakance
Recharqe
the subcrop areas.
Value
2.5 ft/day
878 ft 2/day
849 ft 2/day
849 ft 2/day
1710 ft 2/day
1.0 e -3/day
1.4 e -5/day
6.5 e -4/day
0.7/2 in/year a
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TABLE A3-3
SENSITIVITY ANALYSIS
CHEMSOL GROUNDWATER MODEL
Water-bearing
Zone
Upper Aquitard
Upper Aquitard
Upper Permeabel Aquifer
Upper Permeable Aquifer
Upper Principal Aquifer
Upper Principal Aquifer
Lower Principal Aquifer
Lower Principal Aquifer
Lower Bedrock Aquifer
Lower Bedrock Aquifer
Upper Aquitard
Upper Aquitard
Upper Gray Marker Unit
Upper Gray Marker Unit
Lower Gray Marker Unit
Lower Gray Marker Unit
Model
Parameter
Hydraulic Conductivity Layer 1
Hydraulic Conductivity Layer 1
Transmissivity Layer 2
Transmissivity Layer 2
Transmissivity Layer 3
Transmissivity Layer 3
Transmissivity Layer 4
Transmissivity Layer 4
Transmissivity Layer 5
Transmissivity Layer 5
Leakance Layer 1/2
Leakance Layer 1/2
Leakance Layer 2/3
Leakance Layer 2/3
Leakance Layer 4/5
Leakance Layer 4/5
Recharqe
Recharqe
Base Case
Value Factor
2.5 ft/day
2.5 ft/day
878 ft 2/day
878 ft 2/day
849 ft 2/day
849 ft 2/day
849 ft 2/day
849 ft 2/day
1710 ft 2/day
1710 ft 2/day
1.0 e -3/day
1.0 e -3/day
1.4 e -5/day
1.4 e -5/day
6.5 e -4/day
6.5 e -4/day
0.7/2 in/year a
0.7/2 in/year
Sensitivity
Value Factor
12.5 ft/day x5
0.5 ft/day /5
1756 ft 2/day x2
220 ft 2/day /4
1953 ft 2/day x2
340 ft 2/day /2
1953 ft 2/day x2
340 ft 2/day /2.5
8550 ft 2/day x5
342 ft 2/day /5
1.0 e -2 /day xlO
1.0 e -4 /day /10
1.0 e -4 /day xlO
1.0 e -6 /day /10
6.5 e -3 /day xlO
6.5 e -5 /day /10
2/5 in/yeaar x2 . 5
.4/1 in/year /2
Sensitivity Analysis
Average Absolute Sum of
Residual Residual
(ft) (ft)
1.09
0.64
0.75
0.72
0.36
0.59
0.35
0.61
0.37
1.12
0.53
0.56
0.48
0.52
0.49
0.48
3.89
0.89
15.97
-15.32
3.61
-17.69
0.92
-9.89
1.29
-10.37
9.39
-27.85
-3.29
-12.92
-0.76
-6.27
-5.76
-6.67
-108.91
23.74
Average Absolute
Residual
(ft)
0.47
0.47
0.47
0.47
0.47
0.47
0.47
0.47
0.47
0.47
0.47
0.47
0.47
0.47
0.47
0.47
0.47
0.47
Sum of
Residual
(ft)
-4.89
-4.89
-4.89
-4.89
-4.89
-4.89
-4.89
-4.89
-4.89
-4.89
-4.89
-4.89
-4.89
-4.89
-4.89
-4.89
-4.89
-4.89
a - Indicates Areal recharge and recharge over the subcrop areas.
-------
Recharge was also a sensitive parameter in that a change of approximately 30 percent met the sensitivity
criterion of 10 percent of the average absolute residual. This suggests that heads within the bedrock will
respond guickly to precipitation events, but that the effects will be relatively short lived.
A4.0 CAPTURE ZONE SIMULATIONS
The development and calibration of the groundwater flow model for the Site not only provides a tool to
predict the impact of future events, but also supports and ties together the conclusions derived from the
guantitative hydrogeologic analysis (see Attachment A). Based on the model calibration and sensitivity
analysis described in Sections A3.4 and A3.5, the calibrated base case groundwater flow model developed for
the Chemsol Inc. Site provides a reasonable representation of the existing hydrogeologic conditions. In this
section, the calibrated model is used to develop and evaluate extraction simulations for the groundwater
remedy.
A4.1 EXTRACTION SCENARIOS
Extraction of groundwater and treatment has been selected by USEPA as the remedy for the Site. Some of the
objectives of this remedy are to:
! Prevent/minimize off-site migration of groundwater contamination in the fractured bedrock aguifer.
! Contain the contaminated groundwater (that which is above Federal and State MCLs) from all depth zones
and, as an element of this containment, reduce the mass of contaminants to the maximum extent
possible.
! Augment the existing interim remedy, as necessary, in order to achieve these goals.
To design an extraction system to satisfy these objectives, the groundwater flow model was used to predict
the effects of pumping from the bedrock aguifer system. A number of simulations were completed as part of
this process. Based on this evaluation two scenarios are presented. In Scenario 1 the objective was to
optimize the location and pumping rate of extraction wells to achieve the containment criteria. In Scenario
2, the objective was to locate extraction wells that would achieve the containment criteria and pump from the
portions of the site that have historically shown elevated levels of groundwater contamination. A detailed
discussion of these scenarios follows:
EXTRACTION SCENARIO 1
Extraction Scenario 1 provides a scenario in which containment is achieved within the contaminated portion of
the site. This scenario includes the existing interim remedy extraction well C-l pumping at 15 gpm and the
addition of extraction wells EX-1 (Upper Permeable Aguifer) and EX-2 (Lower Bedrock Aguifer) pumping at 5 gpm
each. The total extraction rate of this scenario is estimated to be 25 gpm. A particle tracking routine
(MODPATH) was used to demonstrate capture within the individual aguifers. To simplify the particle tracking
plots, the outline of the capture zone has been presented. Capture with the Principal Aguifer is presented on
Figure A4-1. The capture zone developed is as result of pumping C-l at a rate of 15 gpm. As shown, the
developed capture zone encompasses the estimated area of groundwater contamination with in the principal
aguifer.
Figure A4-2 shows the capture zone developed by pumping Extraction well EX-1 at 5 gpm within the Upper
Permeable Aguifer. This scenario demonstrates that a low extraction rate within the Upper Permeable Aguifer
can effectively capture the contaminated groundwater associated with this zone.
Figure A4-3 shows the capture zone developed by pumping Extraction well EX-2 at 5 gpm within the Lower
Bedrock Aguifer. Although the extent of contamination is not well defined within the Lower Aguifer, the
capture zone developed by extraction well EX-2, captures an area which is believed to encompass the
potentially impacted area.
EXTRACTION SCENARIO 2
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Extraction Scenario 2 provides a scenario in which containment objective is achieved and mass removal is
enhanced within the Upper Bedrock Aquitard. This scenario includes the wells and pumping rates presented in
Scenario 1 with the addition of two Upper Bedrock Aquitard wells EX-3 and EX-4. These Upper Aquitard wells
are simulated to pump at 1 qpm each, for a total extraction rate for Scenario 2 of 27 qpm. Fiqure A4-4
presents the location of EX-3 and EX-4 and the estimated capture zone.
A4.2 MODEL LIMITATIONS
The qroundwater flow model developed for the Chemsol Site provides a reasonably accurate representation of
the hydrogeologic conditions and qroundwater flow processes in the project area. However, by definition, all
models are approximations or simplifications of the real system (Anderson, 1991). They cannot simulate the
small-scale variations in soil or rock properties such as local chanqes in hydraulic conductivity and
thickness, or the presence of individual fractures. As a result, the natural heteroqeneity of the subsurface
materials is manifested in a deqree of uncertainty in the model results. The maqnitude of the uncertainty
will vary both spatially within the model domain, and with respect to the intended use. For example, the
uncertainty relative to bedrock hydraulic conductivity is much qreater at the model boundaries than within
the vicinity of the site proper. Thus, the model's ability to predict the response of the qroundwater flow
system to pumpinq will be most accurate near the site, and proqressively less accurate downqradient.
For this project, one of the primary objectives of the model was to evaluate the location of extraction wells
and predict the pumpinq rate necessary to achieve containment. The simulated extraction wells shown on
Fiqures A4-1 throuqh A4-4 are located on site, and in close proximity to the stresses imposed by the pumpinq
of well C-l, which were successfully reproduced by the model durinq calibration. Thus, based on this close
proximity of measured and predicted stresses, and the results of the sensitivity analysis, a model
uncertainty of plus or minus 30 percent is estimated and has been applied to the model predictions.
Therefore, the total extraction rate for Scenario 1 required to maintain the capture zones predicted in
Fiqures A4-1, A4-2, and A4-3 is expected to be within the ranqe of approximately 17.5 qpm to 32.5 qpm. The
total pumpinq rate for Scenario 2 is estimated to ranqe from 19 to 35 qpm.
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ATTACHMENT A
QUANTITATIVE ANALYSIS OF THE HYDROGEOLOGIC SYSTEM
ATTACHMENT A
QUANTITATIVE ANALYSIS OF THE HYDROGEOLOGIC SYSTEM
A quantitative analysis of the available hydrogeologic data has been conducted for the Chemsol Site. This
analysis included a review of data from the RI as well as a revisit of data by AGES and McLaren/Hart to
determine if additional information could be extracted from their efforts. The available data include aquifer
test, sluq test, and packer testing data.
This evaluation provides as much of a quantitative understanding of the hydrogeologic system as is reasonably
feasible given the complex hydrogeologic system. By the term "quantitative understanding", we mean the
ability to subdivide the hydrogeologic system into functional hydrostratigraphic units and assign
hydrogeologic properties to these units, such as transmissivity, hydraulic conductivity, and storativity.
This type of quantitative understanding of the system will be vital as a foundation for the numerical
modeling of the system, even if the properties are modified (as they almost certainly will be) during the
calibration of the model.
PRE-RI PUMP TESTING
In 1987, AGES Corporation performed a hydrogeologic assessment of the Chemsol site. As part of their work,
they conducted a step-drawdown test of Well C-l, and a subsequent aquifer test using the same well.
Extraction of much usable hydrogeologic data from the AGES work is problematic since the aquifer test at Well
C-l was begun shortly after the conclusion of the step-drawdown test and before sufficient time had elapsed
for the aquifer to fully recover from the drawdown produced by the step-drawdown test.
In 1993, McLaren/Hart conducted a hydrogeologic study of the Chemsol site. As part of their work, they
performed an aquifer test using Well C-l as the pumping well and a number of wells as monitoring points.
While procedurally, the work of McLaren/Hart is a considerable improvement over the earlier AGES work,
analysis of the data from the aquifer test is hindered by the fact that the open interval of Well C-l
actually spans two distinct water-bearing zones and an intervening hydrostratigraphic unit (the Gray Shale),
which generally acts as an aquitard. This was not recognized in 1993. Consequently, the well likely draws an
indeterminate amount of water from each zone, thus confounding precise definition of the hydrogeologic
properties of either zone. However, some useful data can be drawn from this test since apparently most of the
water is drawn from the Principal Aquifer.
INITIAL OBSERVATIONS
Before embarking upon an in-depth assessment of the aquifer tests, slug tests, and packer tests, several
general observations are made about the hydrogeologic system as a conceptual foundation for the subsequent
analyses:
1. The observed vertical hydraulic head losses at the site are indicative of moderate to low vertical
hydraulic conductivity in some zones.
2. The above observation, coupled with the relatively high yields observed in various pumping wells and
packer tests, suggests a hydrogeologic system composed of interlayered aquifers and aquitards.
3. Vertical anisotropy is also indicated on a system-wide basis and probably within individual strata as
well.
4. A degree of heterogeneous hydrogeologic behavior is evident in virtually all the data. This heterogeneity
significantly complicates the effort to precisely model the system. Nonetheless, the generalized behavior of
the system should be subject to modeling and reasonably accurate predictive analysis.
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5. The heterogeneity has particular implications to the implementation of a groundwater extraction system at
the site. No matter how thoroughly one probes the hydrogeologic data for insight into the properties of the
system or how diligently one strives to calibrate a numerical groundwater flow model based on those
calculated properties, performance of a groundwater extraction system will reguire careful verification. It
is likely that the Observational Method, in one form or another, will have to be utilized to design and
construct a cost-effective system.
ANALYSIS OF THE HYDROGEOLOGIC DATA
In analyzing the hydrogeologic system at the Chemsol site, principal emphasis has been placed upon the
aguifer test and packer test conducted by COM and McLaren/Hart. In particular, CDM conducted a packer test of
some duration, which they termed the long-term test. This packer test was, in essence, an aguifer test and
the data from tghis packer test are guite useful. The aguifer test conducted by McLaren/Hart in 1993 of Well
C-l is also useful. ECKENFELDER INC. has carefully evaluated all of the packer test data to see what
guantitative information can be extracted from this considerable body of data. While the packer tests were
primarily conducted to determine the interconnectedness of various zones, nonetheless, some of the tests lend
themselves to guantitative analysis.
The packer test data were first evaluated as to whether analyses could be conducted using the Theis type
curve match technigue on the drawdown data. Analysis of the drawdown data, however, was not feasible due to
the variable pumping rate employed in the early phase of the packer test. In most cases, the flow rate during
the packer test was increased in step-wise fashion during the early part of the test, and then held
relatively constant throughout the remainder of the test. While the early stepped pumping rate makes
time-drawdown analysis infeasible, analysis of time-recovery data is possible since water level recoveries
react more to the average pumping rate, particularly during the later phases of the test, than they do to
early fluctuations in pumping rate. Distance drawdown analyses were also employed to analyze the drawdown at
the conclusion of the packer test pumping. Lastly, packer test recovery data were also used to conduct
Neuman-Witherspoon ratio method analyses of the upper bedrock zone above the upper permeable zone. Each of
these methods of analysis is briefly described below. A summary of the results of the aguifer test analyses
is presented in Table 1.
Long-Term Test of CDM
CDM performed what they termed the "Long-Term Test" as part of their packer testing activities. During the
long-term test, drawdown was measured in a number of monitoring wells, and the results analyzed by CDM using
the AQTESOLV computer program. Three tests, in particular, provide insight into the transmissivity and
storativity of the principal aguifer. These tests are the analyses conducted based upon the drawdowns
observed in Wells DMW-1, DMW-5 and MW-103. These particular wells are well suited stratigraphically to
determine the aguifer parameters. The results of CDM's analyses are presented in Table 1.
-------
TABLE 1
SUMMARY OF AQUIFER TEST ANALYSES
Water-bearing
Zone
Principal Aquifer
Nature of
Test
Aquifer Test:
Theis Type Curve
Match - DMW-1
Analysis
Conducted by
CDM
Transmissivity Storativity
(qpd/ft) (dimensionless)
14,500
2.1 x 10 -4
Vertical Hydraulic
Conductivity
(cm/sec)
Principal Aquifer
Aquifer Test:
Theis Type Curve
Match - DMW-5
CDM
8,800
7.8 x 10 -5
Principal Aquifer
Aquifer Test:
Theis Type Curve
Match - DMW-5
CDM
8,800
2.2 x 10 -4
Principal Aquifer
Packer Test:
Round 3, Test 2
Distance - Drawdown Analysis
ECKENFELDER INC.
>5,000
2.3 x 10 -4
Principal Aquifer
Neuman-Witherspoon
ECKENFELDER INC.
3.5 x 10 -4
-------
TABLE 1 (cont'd)
SUMMARY OF AQUIFER TEST ANALYSES
Water-bearing
Zone
Principal Aquifer
Nature of
Test
Aquifer Test of Well C-l
Theis Type Curve
Match - TW-9
Analysis
Conducted by
McClaren-Hart
Transmissivity Storativity
(qpd/ft) (dimensionless)
8,500
9.9 x 10 -5
Vertical Hydraulic
Conductivity
(cm/sec)
Principal Aquifer
Aquifer Test of Well C-l
Theis Type Curve
Match - DMW-5
McClaren-Hart
10,300
4.1 x 10 -4
Principal Aquifer
Aquifer Test of Well C-l
Theis Type Curve
Match C-3
McClaren-Hart
10,800
1.7 x 10 -4
Principal Aquifer
Aquifer Test of Well C-l
Theis Type Curve
Match C-5
McClaren-Hart
29,000
2.1 x 10 -4
Upper Permeable Aquifer
Packer Test:
Theis Type Curve
Match of time-recovery data
Round 3, Test 3, Well C-6
ECKENFELDER INC.
12,300
1 X 10 -4
-------
TABLE 1 (cont'd)
SUMMARY OF AQUIFER TEST ANALYSES
Vertical Hydraulic
Water-bearing Nature of Analysis Transmissivity Storativity Conductivity
Zone Test Conducted by (gpd/ft) (dimensionless) (cm/sec)
Upper Permeable Aquifer Packer Test: ECKENFELDER INC. 13,000 6 x 10 -6
Distance-Drawdown
Analysis of Round 3, Test 3
Upper Bedrock N-W Ratio Method ECKENFELDER INC. 1.1 x 10 -4
Analysis of Round 3, Test 3
Packer Test
Upper Bedrock N-W Ratio Method ECKENFELDER INC. 6.5 x 10 -5
Analysis of Round 3, Test 3
Packer Test:
C-10, TW-4
-------
Distance Drawdown Analyses of Packer Test Round 3, Test 2
Efforts were undertaken by ECKENFELDER INC. to determine whether any of the packer test data would be
suitable for a distance drawdown analyses using the Cooper-Jacob method. This methodology is particularly
useful in defining transmissivity. However, most of the packer tests do not lend themselves to this type of
analysis for two reasons. First, there are generally not a sufficient number of wells at different radial
differences from the pumped interval to define the shape of the distance drawdown curve. Secondly, the pumped
interval typically cannot be used in the analysis because of excessive well losses. Nonetheless, one packer
test, specifically Round 3, Test 2, provided some insight into the transmissivity in that well losses in the
pumped interval in Well DMW-10 appeared to be more modest. Drawdown in the pumped interval was only 4.8 feet
(compared to many tens of feet in some of the other packer tests). An analysis of this packer test using the
Cooper-Jacob distance drawdown method, and assuming the drawdown in the pumped interval is reflective of
actual drawdown in the formation, yields a transmissivity of 5,000 gallons per day per foot and a storativity
of 2.3 x 10 -4. In all likelihood the transmissivity is higher than this figure since well losses likely
occur. For example, if well losses accounted for one-half of the observed drawdown, the transmissivity would
be approximately 10,000 gallons per day per foot. The plot of the data and the associated calculations are
provided in Attachment B-l.
Aguifer Test of Well C-l by McLaren/Hart
McLaren/Hart conducted an aguifer test of Well C-l measuring drawdown in a number of monitoring wells. The
analyses of the drawdowns observed in Wells TW-9, DMW-5, C-3, C-4, and C-5 are particularly appropriate as
these wells are well positioned stratigraphically to define the aguifer parameters of the principal aguifer.
These analyses, which are presented in McLaren/Hart's report, yielded transmissivities ranging from 8,500 to
29,000 gallons per day per foot and storativities ranging from 9.9 x 10 -5 to 4.1 x 10 -4, as presented in
Table 1.
As mentioned earlier, the aguifer test conducted by McLaren/Hart of Well C-l is limited in its accuracy due
to the fact that the well is likely pumping an indeterminate amount of water from both the principal aguifer
and the upper permeable zone. However, based upon the results of the analyses and a comparison to more recent
aguifer tests conducted by COM, it is likely that the majority of the water being pumped from Well C-l is
being drawn from the principal aguifer. Conseguently, it can be concluded that the calculated transmissivity
is reasonablyy reflective of the Principal Aguifer.
Neuman-Witherspoon Ratio Method Analysis of McLaren/Hart Aguifer Test
In order to gain some insight into the vertical hydraulic conductivity of the principal aguifer, ECKENFELDER
INC. conducted a Neuman-Witherspoon Ratio Method Analysis of the data from the McLaren/Hart Aguifer Test. A
vertical hydraulic conductivity of 3.5 x 10 -4 centimeters per second was estimated for the lower portion of
the principal aguifer. These data and associated calculations are presented in Attachment B-2.
Theis Type Curve Matching of Time Recovery Data from Packer Test
ECKENFELDER INC. conducted Theis type curve analysis of recovery data from aa number of the packer tests. One
test in particular generated data permitting a Theis type curve match analysis. These data were the packer
test recovery data from Round 3, Test 3 for Well C-6. This analysis permits estimation of the aguifer
parameters of the upper permeable zone. The analysis resulted in an estimated transmissivity of 12,300
gallons per day per foot and a storativity of 1 x 10 -4. The data, type curve match and associated
calculations are included in Attachment B-3.
Distance Drawdown Analysis of Packer Test Round 3, Test 3
The data from the Round 3, Test 3 packer test also lent itself to a distance drawdown analysis using the
Cooper-Jacob method. In this packer test, Well C-7 in the upper permeable zone was pumped and drawdowns in
Wells C-6, C-8, C-9 and C-10 were measured in the upper permeable zone. In this analysis Well C-6 and C-10
provide the most useful data since they are at significantly different radial distances from the pumped
interval. This test suggests some degree of areal anisotropy with a slightly higher transmissivity along the
-------
strike of the formation. Similar anisotropy is not observed in other data sets, however, and the apparent
areal anisotropy observed in Round 3, Test 3 is probably coincidental. The distance drawdown analysis results
in an average transmissivity of 13,000 gallons per day per foot and a geometric mean storativity of 6 x 10
-6. The data plots and calculations are included in Attachment B-4.
Neuman-Witherspoon Ratio Method Analysis of Packer Test Round 3, Test 3
In order to get some information as to the vertical hydraulic conductivity of the upper bedrock zone,
ECKENFELDER INC. conducted Neuman-Witherspoon ratio method analyses of the Round 3, Test 3 packer test. The
analysis specifically involved analysis of Wells C-8 and TW-3, and C-10 and TW-4. These analyses were done
using recovery data for the reasons described earlier. The time recovery plots and calculations of both ratio
method analyses are presented in the appendices. The analyses resulted in estimated vertical hydraulic
conductivity values of 1.1 x 10 -4 and 6.5 x 10 -5 centimeters per second. These analyses would be
representative of order of magnitude estimates. The data plots and calculations are presented in Attachment
B-5.
SUMMARY OF QUANTITATIVE ANNALYSES
In connection with the principal aguifer, the average transmissivity calculated from the three Theis type
curve match analyses conducted by CDM and the five Theis type curve match analyses conducted by McLaren/Hart
is approximately 12,700 gallons per day per foot. Similarly, the average storativity is approximately 2 x 10
-4. The average transmissivity of the upper permeable zone, calculated from the values obtained from the
Theis type curve match of time recovery data from packer test, Round 3, Test 3 of Well C-6 and the distance
drawdown analyses of packer test Round 3, Test 3 is 12,650 gallons per day per foot. The storativity is on
the order of 1 x 10 -4 as estimated from the time recovery analysis of Well C-6. The much lower value
calculated from the distance drawdown analyses is probably unrepresentative. Although some indication of
areal anisotropy was observed in the drawdowns of Packer Test, Round 3, Test 3, generally, areal anisotropy
is not indicated in the preponderance of the data. The spatial differences in drawdown are more likely
attributable to typical fractured rock heterogeneity than to a systematic areal anisotropy.
-------
ATTACEMENT B
AQUIFER TEST PLOTS AND CALCULATIONS
ATTACHMENT B-l
DISTANCE DRAWDOWN ANALYSES OF
RI PACKER TEST DATA
WELL DMW-10(ROUND 3,TEST 2)
ATTACHMENT B-2
NEUMAN-WITHERSPOON ANALYSES OF
McCLAREN-HART AQUIFER TEST DATA
ATTACHMENT B-3
THEIS TYPE-CURVE ANALYSES OF RECOVERY
DATA FROM RI PACKER TEST
WELL C-6 (ROUND 3, TEST 3)
ATTACHMENT B-4
DISTANCE-DRAWDOWN ANALYSES OF
RI PACKER TEST DATA
WELL C-7 (ROUND 3, TEST 3)
ATTACHMENT B-5
NEUMAN-WITHERSPOON ANALYSES OF
RI PACKER TEST DATA
(ROUND 3, TEST 3)
ATTACHMENT C
WELL SURVEY
-------
LOW CAPACITY WELLS
WITH IN 2 MILES OF THE CHEMSOL, INC. SITE
Map
Index Permit No. Date
1
2
3
3
3
3
4
5
5
5
6
6
6
7
7
7
8
9
9
9
10
11
11
12
12
13
13
13
13
14
14
15
15
16
17
18
19
2512153
261721
256775
2510586
2516248
2536222
2523596
2518766
2522656
4500252
2511162
2511288
2521575
251125
257340
257910
259223
256823
259770
2520865
2511765
258632
259771
258904
2536281
2519037
2520085
2520411
2525600
2519038
2526144
2517258
2517258
2527118
251208
222750
2523677
1964
NA
1957
1962
1972
1990
1983
1975
1982
1969
1963
1963
1980
1951
NA
1958
1960
1957
NA
1979
1964
1959
NA
NA
1990
1978
1978
1978
1984
1977
1985
1973
1973
1986
1951
1958
1983
Owner
Hall, Eugene B
Dichl, John K. Jr.
Campenella, Dominick
Spadafors, Fred
Mason Candlelight Co.
Polon, Art
Swarm, John
Dobusz, Gregory
Design Molding Services, Inc.
Design and Molding Services, Inc.
Max Scheefer & Sons
Beavers, Rose
Bybel, Robert
Viviano, John F.
Russonanm, Jerry
Lane, Russell
Wood Song. Inc
Mr. Wilson
Freile, Herbert
Breslin, Elaine
Haas, George
Alberino, August
Klein, Anderson
Osborn, Hollis
Warger, Robert
Global Development
Solvato, Leonard
Zazzora, Tony
Kiernan, James
Global Development
Perm Const. Co. Inc.
J.Middlesex Builders Inc.
J.Middlesex Builders Inc.
Pelmont Builders
Green, earl
Union Steel Corp.
Captive Plastics
Address
Use
ft of New Brunswick Ave.
New Market
S. side of Carpathia St., 200
New Market, Middlesex County
New Market
820 Lincoln Blvd, Middlesex, N.J.
341 High St., Dunellen, NJ
Lot 16 Block:55 Municipality: Dunellen Boro
Lot 53-54-55, Bl. 292, Pluscataway, Middlesex
Lot 1-15-32-47
25 Howard St. Piscataway
Grant Ave. off Country Club Rd., S. Madison Ave
Clay Ave., New Market NJ
Lot 1. Bl. 161, Piscataway Twp., Middlesex City
Box 196 Blackford Avenue, New Market, NJ
New Market, NJ
Mountain Ave, New Market
Pescalaway Twsp.
NA
North side of 3rd St., 200 ft W of Blackford Ave.
Lot 25-28,Bk, 156 Piscataway, Middlesex, NJ
Leunellen, New Jersey
E Side of Davis St., 200 Ft S of Williams St.
W side of Plainfield Ave, 500ft N of First Ave.
East side of No. Randolph Rd., 1500 ft South of New Market NJ
172 Middlesex Ave, Piscataway, NJ
Piscataway-Somerset
Lot, 26, Block 350, Piscataway Middlesex
Lot 4, Block 365, Piscataway, Middlesex
Lot 5-D bl. 364
Piscataway, Somerset Co.
Lot: 9194 Block: 452 Muncipality: Piscataway Twp.
Hillsborough Twp., Somerset, Camplain Rd, Lot: 40 Bl: 141
Hillsborough Twp., Somerset, Camplain Rd, Lot: 40 Bl: 141
Lot:6.01 Block: 823
Piscataway Twp., Middlesex County
Piscataway NJ
Lot: 11 Bl: 457B Municipality: Piscataway Twp.
Total
Depth
(ft)
NA
NA
NA
Domestic
NA
NA
NA
Na
NA
NA
NA
NA
Na
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
100
138
130
115
210
51
75
150
450
390
123
110
100
100
200
109
100
104
120
130
125
113
115
130
52
130
90
100
200
120
125
140
140
225
115
300
50
Capacity
(gpm)
15
10
10
10
40
8
15
12
125
120
25
50
60
4
50
35
20
10
15
25
20
15
15
10
10
20
10
10
10
10
10
40
40
40
16
120
200
NJDEP
Locator Easting
(ft)
Northing
(ft)
33042
33473
33665
33665
33665
33665
33666
33668
33668
33668
33669
33669
33669
33685
33685
33685
33688
33691
33691
33691
33693
33694
33694
33697
33697
33922
33922
33922
33922
33923
33923
33925
33926
33928
33935
33936
33937
2047858
2030480
2053991
2053991
2053991
2053991
2055013
2053991
2053991
2053991
2055013
2055013
2055013
2050924
2050924
2050924
2050924
2052969
2052969
2052969
2055013
2052969
2052969
2052969
2052969
2050924
2050924
2050924
2050924
2051946
2051946
2051946
2051946
2050924
2053991
2055013
2052969
627082
635082
637750
637750
637750
637750
637750
636416
636416
636416
636416
636416
636416
633750
633750
633750
632416
635082
635082
635082
635082
633750
633750
632416
632416
631082
631082
631082
631082
631082
631082
629750
626750
628416
629750
629750
628416
-------
19
19
20
21
21
22
22
22
22
2515990
2519951
257478
2525656
2525657
257561
257562
2516900
2527774
1971
1978
1958
1985
1985
1958
1958
1973
1986
Captive Plastics Inc.
Vocisano, Louie
Koenig, Shirley A.
Petmont Builders
Permont Builders
Newton, Clinton
Newton, Clinton
Marx, Peter
Pelmont Builders
Piscataway, Middlesex
Middlesex Ave.
Possumtown Rd. Possumtown, NJ
Lot:8 Block: 376 Municipality: Piscataway Twp.
Lot: 5 Block: 376 Municipality: Piscataway Twp.
NA
NA
Lot: 8 Blk: 352 Blackford Rd., Piscataway Twp., Somerset
Lot:6B Block: 823 Municipality: Piscataway Twp.
NA
NA
NA
NA
NA
NA
NA
NA
NA
240
125
40
150
175
98
93
145
200
100
10
30
30
30
10
10
40
0.71
33937
33937
33939
33952
33952
33953
33953
33953
33953
2052969
2052969
2055013
2050924
2050924
2051946
2051946
2051946
2051946
628416
628416
628416
627082
627082
627082
627082
627082
627082
-------
LOW CAPACITY WELLS
WITH IN 2 MILES OF THE CHEMSOL, INC. SITE
Map
Index Permit No. Date
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
24
25
25
25
25
25
25
25
26
26
27
27
27
27
27
28
28
29
29
30
30
2527976
2527975
25321978
2532198
25321994
25322001
25322010
25322028
25322036
25322044
25322052
25322061
25322079
25322087
25322095
25322109
258389
257557
257560
2510303
2527466
25300741
25300750
256463
251145
2534669
25176
2532241
2532242
2533622
253623
2530319
2530320
251261
2532371
2520861
25375
1986
1986
1988
1988
1988
1988
1988
1988
1988
1988
1988
1988
1988
1988
1988
1988
1959
1958
1958
1961
1986
1987
1987
1957
1951
1989
1948
1988
1988
1989
1989
1987
1987
1951
1988
1979
1948
Owner
Koba Corporation
Koba Corporation
Beecham Labs
Beecham Labs
Beecham Labs
Beecham Labs
Beecham Labs
Beecham Labs
Beecham Labs
Beecham Labs
Beecham Labs
Beecham Labs
Beecham Labs
Beecham Labs
Beecham Labs
Beecham Labs
Puzio, Walter
Piluso, Steve
Winklehoiz, Charles
Jay R. Smith MFG. Co.
Rosamelia, Tony
L.Tech Welding
L.Tech Welding
Gubernat, John
Kulak, Joseph
Bedell, Dan
Pastuck, Patrick
Beecham Labs
Beecham Labs
L-Tec
L-Tec
Inst. of Electrical Electronics
Inst. of Electrical Electronics
Hoegberg, Otto
Pelmont Builders
Tina Construction Co.
Kistler, Esther
Address
Lot:4 Block:361 Municipality: Middlesex Boro
Lot:4 Block:361 Municipality: Middlesex Boro
101 Possumtown Rd.,Piscataway, NJ 08854
101 Possumtown Rd.,Piscataway, NJ 08854
101 Possumtown Rd.,Piscataway, NJ
101 Possumtown Rd.,Piscataway, NJ
101 Possumtown Rd.,Piscataway, NJ
101 Possumtown Rd.,Piscataway, NJ
101 Possumtown Rd.,Piscataway, NJ
101 Possumtown Rd.,Piscataway, NJ
101 Possumtown Rd.,Piscataway, NJ
101 Possumtown Rd.,Piscataway, NJ
101 Possumtown Rd.,Piscataway, NJ
101 Possumtown Rd.,Piscataway, NJ
101 Possumtown Rd.,Piscataway, NJ
101 Possumtown Rd.,Piscataway, NJ
Bridgewater Twp.
NA
NA
NA
Lot: 1-6 Block:363 Municipality: Piscataway, NJ
239 Old New Brunswick Rd.,Piscataway, NJ
239 Old New Brunswick Rd.,Piscataway, NJ
Stelton, Middlesex Co.
Old New Brunswick Rd. Piscataway, NJ
480 Sidney Rd., Piscataway, NJ
Piscataway, Twp.,Middlesex Co.
101 Possumtown Rd.,Piscataway, NJ
101 Possumtown Rd.,Piscataway, NJ
239 Old New Brunswick Rd.,Piscataway, NJ
239 Old New Brunswick Rd.,Piscataway, NJ
Hoes Lane Piscataway, NJ
Hoes Lane Piscataway, NJ
Piscataway Twp. Middlesex Co.
31 Stelton Rd. Suite 5, Piscataway, NJ
27 Franklin St. Piscataway N.J.
RD#2, New Brunswick, NJ
Use
Total
Depth
(ft)
Capacity
(gpm)
NJDEP
Locator Easting
(ft)
Northing
(ft)
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Domistic
300
300
48
12
13
48
15
48
20
58
53
41
15
51
50
11.5
170
97
107
166
150
24
45
130
112
250
89
10
10
50
10
20
21
87
200
185
198.5
80
150
25
NA
NA
5
NA
12
NA
20
2
0.75
<1
<2
10+
NA
10
10
10
60
10
NA
NA
10
13
20
20
NA
NA
NA
NA
NA
NA
16
10
20
16
33956
33956
33956
33956
33956
33956
33956
33956
33956
33956
33956
33956
33956
33956
33956
33956
33959
33961
33961
33961
33961
33961
33961
33961
33962
33962
33964
33964
33964
33964
33964
33967
33967
33991
33991
33992
33995
2051946
2051946
2051946
2051946
2051946
2051946
2051946
2051946
2051946
2051946
2051946
2051946
2051946
2051946
2051946
2051946
2051946
2052969
2052969
2052969
2052969
2052969
2052969
2052969
2053991
2053991
2052969
2052969
2052969
2052969
2052969
2052969
2052969
2052969
2052969
2053991
2053991
625750
625750
625750
625750
625750
625750
625750
625750
625750
625750
625750
625750
625750
625750
625750
625750
624416
627082
627082
627082
627082
627082
627082
627082
627082
627082
625750
625750
625750
625750
625750
624416
624416
623082
623082
623082
621750
-------
31
31
31
32
32
33
34
34
NA
25677
2520864
25762
2512498
257609
2534508
25213248
1968
1950
1979
1950
1964
1958
1958
1971
National Starch & Chemical Corp.
Asphalt & Mineral Corp.
William & VEE Hamilton
Art Color Printing CO.
DeMatteo, Poi
Gray, Douglas
DeMatteo, Poi
Elizabethtown Water
1735 W. Front Street, Plainfield NJ
NA
171 Mountain Ave.Piscataway, NJ
South & Wasthington Ave.
Sunlit Dr. Watching, NJ
252 Pearl Place, Dunellen, NJ
586 Warfield Ave, North Plainfield, NJ
1341 North Ave, Plainfield, NJ
Industrail
Industrial
Domistic
Industrial
Domistic
Domistic
Domisiic
Public Sup
600
200
100
325
92
102
115
350
NA
250
10
226
6
10
10
400
34418
34418
34418
34418
34419
34419
34428
34428
2057058
2057058
2057058
2058080
2058080
2059102
2060124
2060124
640416
640416
640416
640416
640416
640416
640416
640416
34
2518634
1976 Nesler, J.
NA
Domestic
125
10
34428
2060124 640416
-------
LOW CAPACITY WELLS
WITH IN 2 MILES OF THE CHEMSOL, INC. SITE
Map
Index Permit No. Date
Owner
53
53
54
54
54
55
56
56
56
56
56
57
58
59
59
59
59
59
59
60
60
60
60
60
60
60
60
61
61
61
61
61
61
62
62
62
62
2522257
252258
2512829
2521571
2525751
2529539
2541529
41530
2541531
2541532
258617
2521332
259075
2524382
2530161
2530162
2534575
2530164
2530165
25316991
2531700
2530565
25316982
2524448
2513094
2522615
259517
259646
2520170
25344056
25344064
255344072
25344072
25844
2522109
2523878
2523879
1981
1981
1965
1980
1984
1987
1992
1992
1992
1992
NA
1980
1959
1983
1987
1987
1987
1987
1987
1988
1988
1987
1988
1983
1965
1982
1960
NA
1978
1989
1989
1989
1989
1951
1981
1983
1983
Atlantic Richfield Co.
Atlantic Richfield Co.
Keystone Plastics Inc.
Mastrianni, Patric
Campagna, Phillip
Barietta, Alex
Pulsafeeder Co.
Pulsafeeder Co.
Pulsafeeder Co.
Pulsafeeder Co.
Calvin, Frank H.
Pellegrino, John
Turi, Charles A.
Kays , Jane
Silverman, Ken
Silverman, Ken
Silverman, Ken
Silverman, Ken
Silverman, Ken
Atlantic tool & die Co.
Atlantic Tool & Die
Atlantic Tool & Die
Atlantic Tool & Die
Celeniano, Julius
Ladis, William
Gian, Di D. & son
Turi, Charles A.
Yulick, Robert
Global Development Company
Wilmer, Ivan
Wilmer, Ivan
Wilmer, Ivan
Wilmer, Ivan
Kentile, Inc.
Wood Constriction Co.
Raritan Oil Co.
Raritan Oil Co.
Address
Southeast corner f station property, 10'Wof sidewalk
17'W of Guard on Lakeview Ave., between creek & asphalt
S. Clinton Ave., S. Plainfield
Lot 3, Block 348, S. Plainfield, Middlesex Co.
Lot:9-10, Block:427, Municipality:South Plainfield Boro
700 delmore Ave., Middlesex S. Plainfield, NJ
2387 south Clinton Ave.
2387 south Clinton Ave.
2389 South Clinton Ave.
2387 South Clinton Ave.
S. side of Sage St.; 250ft W of South Clinton Ave.
Lot:15-20, Block:498, So. Pld Middlesex
South Plainfield NJ
Lot:5-E
Block:292
105 Sylvania Ave.
105 Sylvania Ave.
South Plainfield,
South Plainfield,
NJ
NJ
NJ
NJ
NJ
105 Sylvania Av. South Plainfield,
105 Sylvania Ave. South Plainfield,
105 Sylvania Ave. South Plainfield,
Lot:2.03
Lot:2.03, Block:447
Lot:2.03
Lot:2.03
Lot: 74-7, Block:315 Municipality: South Plainfield Boro
South Plainfield, N.J.
Lot: 73 Block: 315
South Plainfield
NA
Lot:ll-12, Block:316,S. Old Middlesex Co
375 Meluchen Rd. , S
375 Meluchen Rd. , S
375 Meluchen Rd. , S
374 Meluchen Rd. , S
South Plainfield, N
Lot:49-53,Block:457
NA
NA
Plainfield,
Plainfield,
Plainfield,
Plainfield,
J.
NJ
NJ
NJ
NJ
Use
NA
NA
NA
NA
NA
NA
NA
Na
NA
NA
Na
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Total
Depth
(ft)
10
20
300
50
150
140
71.4
76.7
74.8
75
113
125
100
170
10
10
10
10
38
38
38
12
40
150
100
150
100
130
110
13
13
13
13
461
51
8
24
Capacity
(gpm)
200
30+
25
25
12
14
15
12
Na
25
20
NJDEP
Locator Easting
(ft)
Northing
(ft)
NA
NA
NA
NA
NA
NA
NA
NA
NA
30+
40
25
15
15
30
NA
NA
NA
NA
310
15
NA
NA
34555
34555
34557
34557
34557
34559
34571
34571
34571
34571
34571
34572
34574
34575
34575
34575
34575
34575
34576
34576
34576
34576
34576
34576
34576
34576
34576
34582
34582
34582
34582
34582
34582
34583
34583
34583
34583
2069324
2069324
2068302
2068302
2068302
2070346
2065236
2065236
2065236
2065236
2065236
2066258
2065236
2068258
2066258
2066258
2066258
2066258
2067280
2067280
2067280
2067280
2067280
2067280
2067280
2067280
2067280
2069324
2069324
2069324
2069324
2069324
2069324
2070346
2070346
2070346
2070345
637750
637750
636416
636416
636416
636418
635082
635082
635082
635082
635082
635082
633750
633750
633750
633750
633750
633750
633750
633750
633750
633750
633750
633750
633750
633750
633750
635082
635082
635082
635082
635082
635082
635082
635082
635082
635082
-------
62
62
62
62
62
63
63
63
2523880
2523880
2534528
2534529
2534530
258228
258978
2519393
1983
1983
1989
1989
1989
1959
NA
1977
Raritan Oil Co.
Raritan Oil Co.
Sub Transit
Suburban Trasit
Suburban Trasit
Piscatelli, Michael
Zereconski, Mildred
Global Development
NA
NA
601 Market Ave., South Plainfield, N.J.
601 Market Ave., South Plainfield, NJ
601 Market Ave., South Plainfield, NJ
N. of New York., &W. of Hamillton Blvd.,South Plainfield NJ
N. side of New York Ave., 300ft W. of West Hamilton Blvd.
Lot:13, Block:426, CamdenAve., South Plainfield
NA
NA
Na
NA
NA
NA
NA
NA
19
19
12
13
13
113
200
120
NA
Na
NA
NA
35
12
15
34583
34583
34583
34583
34583
34584
34584
34584
2070345
2070345
2070346
2070346
2070346
2068302
2068302
2068302
635082
635082
635082
635082
635082
633750
633750
633750
63
2519392
1977 Global Development
Lot:14 Block:426 New York Ave., South Plainfield
NA
110
30
34584
2068302
633750
-------
LOW CAPACITY WELLS
WITH IN 2 MILES OF THE CHEMSOL, INC. SITE
Map
Index
Permit No. Date
35
36
37
37
37
37
37
38
38
39
3 9
40
40
41
42
42
43
44
45
46
46
46
46
47
47
47
47
47
47
47
47
48
4 9
49
4 9
50
51
52
52
52
53
53
53
NA
53
53
53
2510160
251194
256925
257530
258431
258821
258759
258202
2521914
259060
2431426
251121
259145
2510225
258109
258311
2532529
2510256
254289
256984
258037
256984
258037
25653
256716
256996
257170
257342
27499
258623
258885
2511102
256919
257117
2535868
2532832
254426
2540944
25190
25421
28490
252090
252091
525
253969
2522255
2522256
1961
1951
1957
1958
NA
NA
1959
1959
1961
1959
1988
1951
1960
1962
1958
1959
1989
1961
1963
1957
1958
1957
1958
1957
1957
1957
1957
1957
1958
NA
1959
1963
1957
1957
1990
1989
1963
1992
1949
1949
1986
1952
1952
440
1954
1981
1981
Hocke, Mary
S immons, Raymond
De Censo, Emilia
Pillsbury, Samul
Norman, Richard
Panzarello, P.
Barra, Louis
DiDario, Armond
Wedgie, Philip
Olechna, Clem
Macedo Concrete Corp.
Smith, M.
Vescovi, T
DeMatloo, Pio
Venture, Emil
NA
Turner £ Pacconi Constuction
Hanzl, A.
Milets, Racco
Beyerman, Vince
Shumsky, Peter
Beyerman, Vince
Shumsky, Peter
Beyerman
Papa, Barbara
Hahr, Arthur
Piluso, Steve
K.L.M. Builders
Calloway, Cleveland
Muglia, Albert
Newton, Clinton
Channin, Brown
Toshy, John
Guaranteed Block Co.
Bratone, Arther
Cillis, Joseph Jr.
Dodd, May
Penske Truck Leasing
Middlesex Water Co.
Middlesex Water Co.
Recifro, Frank
Middlesex Water Co.
Middlesex Water Co.
34555 2069324 637750
Middlesex Water Co.
Atlantic Richfield Co.
Atlantic Richfield Co.
Total
Depth
(ft)
NJDEP
Locator
Easting
(ft)
Piscataway
Piscataway
NA
Smith Stre
North Side
South side
NA
North of S
Lot 24, Bl
South Plai
Parker Rd.
Lehigh St.
1715 Meist
Piscataway
NA
New Market
Hall Stree
42 Maple S
New Market
NA
NA
NA
NA
NA
NA
South side
NA
NA
NA
North side
NA
Marion La.
710 Delmor
East side
2364 S. Cl
1521 Sage
Planfield
2364 South
Borough of
South Plai
222 Barone
South Plai
South Plai
. 10th St. £ east of New Brunswick Ave.
ock 33,Dunellen, Piscataway Township, NJ
nfield, NJ
, South Plainfield, NJ
Dunellen, NJ
er St. Arbor, NJ
Twp. NJ
Rd.
t Piscataway, NJ
treet, Oaktree Edison, NJ
list, off Washington Ave.
Plainfield Road, NJ
e Ave. South Plainfield Ave, NJ
of Clinton Ave., 200ft N. of New Market Ave.
inton Ave, South Clinton NJ
St., South Plainfield, NJ
Ave £
Clinton Ave. South Plainfield, NJ
South Plainfield, NJ
nfield, N.J.
Ave. South Plainfield, NJ
nfield N.J.
nfield NJ
Domestic
Domestic
Domestic
NA
Domestic
Domestic
Domestic
Domestic
Domestic
Domestic
Industrial
Domestic
Domestic
Domestic
Domestic
Domestic
Domestic
Domestic
Domestic
Domestic
Domestic
Domestic
Domestic
Domestic
Domestic
Domestic
Domestic
Domestic
Domestic
Domestic
Domestic
Domestic
NA
NA
NA
NA
Domestic
NA
NA
NA
NA
NA
NA
95
100
110
125
115
143
107
90
175
110
160
100
130
100
95
120
150
125
120
74
93
74
93
90
104
120
90
99
107
100
94
128
95
125
12
61
125
18
403
409
125
502
525
10
6.25
10
24
15
15
12
11
100
0.2
0.3
Na
15
7
10
15
0.3
10
10
10
10
10
10
10
10
10
10
10
10
15
10
8
10
15
NA
1
8
NA
412
542
NA
465
440
34429
34430
34437
34437
34437
34437
34437
34438
34438
34439
34439
34442
34442
34442
34445
34445
34446
34447
34449
34452
34452
34442
34452
34453
34453
34453
34453
34453
34453
34453
34453
34455
34547
34547
34547
34548
34550
34554
34554
34554
34555
34555
34555
2061146
2064213
2062169
2062169
2062169
2062169
2062169
2063191
2063191
2064213
2064213
2057058
2057058
2058080
2057058
2057058
2058080
2056036
2058080
2060124
2060124
2060124
2060124
2061146
2061146
2061146
2061146
2061146
2061146
2061146
2061146
2060124
2065236
2065236
2065236
2066258
2070346
2068302
2068302
2068302
2069324
2069324
2069324
640416
640416
640416
640416
640416
640416
640416
640416
640416
640416
640416
639082
639082
639082
637750
637750
637750
636416
636416
639082
639082
639082
639082
639082
639082
639082
639082
639082
639082
639082
639082
637750
636416
636416
636416
636416
636416
637750
637750
637750
637750
637750
637750
10
10
-------
LOW CAPACITY WELLS
WITH IN 2 MILES OF THE CHEMSOL, INC. SITE
Map
Index
Permit No.
259045
258203
2527382
2525605
2534040
25745
25725
2514113
2528345
2522763
2534157
2510690
2510227
258692
2534699
2511433
259453
25550
25453
25320611
25320602
258702
2543318
2526281
2526280
2521986
2532941
2529074
2529073
2529072
25331230
25331223
25331213
25330845
25330837
25330829
25330811
25330802
25330799
2512155
2511468
4500312
25324888
35324870
2522755
2522756
NA
1959
1986
1985
1989
1951
1950
1966
1986
1982
1986
1962
1961
NA
1989
1963
1960
1949
1949
1988
1988
1959
1994
1985
1985
1981
1989
1987
1987
1987
1989
1989
1989
1989
1989
1989
1989
1989
1989
1964
1963
1950
NA
NA
1982
1982
Shinkle, Anne
Butrico, Charles F.
Wood, Sal
Knight, Frank
Kentile floors. Inc.
Kentile Inc.
Cornell Dubilier Elec Corp.
Kentile, Inc.
Di Gian & Son Const Co.
Chevron Chemical Co.
Zwolak, Frank
Gordon, Earl C.
serido, Tony
Ronzo, Elizabeth
Chomut, Dimitri & Maria
Nesler, Joseph
Owens, John Evan
Westergard, C. J.
Roeth, Edward
National Can Corporation
National Can Corporation
Soden, John Edward
Eguity Associates
Rutgers State University
Rutgers State University
Boroughs Corp. CSG Division
Wilson, William B.
Nat'1 Can Corporation
Nat'1 Can Corporation
Nat'1 Can Corporation
Huls America, Inc.
Huls America, Inc.
Huls America, Inc.
Huls America, Inc.
Huls America, Inc.
Huls America, Inc.
Huls America, Inc.
Huls America, Inc.
Huls America, Inc.
Connelongo, Joseph
Colosi, Philip
National Starch
Texaco
Texaco
Passaro Builders
Passaro Builders
N. side of New York Ave., 400ft. W. of Hamilton Blvd.
E. of Garbaldi Ave., s S. of Tremont Ave.
Lot:7 Block:350 Municipality: South Plaifield Boro
Lot:10 Block:428
Lot:10 Bolck255 S. Plainfield, N.J.
south Plainfield, N.J.
South Plainfield, N.J.
Kentile Rd,. S. Plainfield, NJ
South Plainfield, N.J.
South Plainfield N.J.
Lot: 14 Block:354
1003 Delmore Ave., S Plainfield N.J.
Murih St., Dunlennel, N.J.
S side of Delmore Ave., 250 ft E. of Lorraine Ave.
8 Davidson Ave. Piscataway, Twp
Plainfield, NJ
New Market, Piscataway Twsp.
Old Brunswick Rd., New MArket, Middlesex Co.
New Market, Middlesex Co.
Lot:2, Block:461
Lot:2 Block:461
Edison Township, N.J.
Stelton Rd., Piscataway Twp.
Electrical Engineering
Electrical Engineering
S. Randolphville Rd. Lot:4A Block:460C
120' S. of t
Lot:2 Block:
Lot:2 Block:
Lot:2 Block:
Turner
Turner
Turner
Turner
Turner
Turner
Turner
Turner
Turner
PI. ,
PI. ,
PI. ,
PI. ,
PI. ,
PI. ,
PI. ,
PI. ,
PI. ,
New Market,
300 Stelton
lont
461
461
461
Box
Box
Box
Box
Box
Box
Box
Box
Box
Pis
Rd.
rose
365,
365,
365,
365,
365,
365,
365,
365,
365,
cataw
, New
Ave.; 160' W
Piscataway,
Piscataway,
Piscataway,
Piscataway,
Piscataway,
Piscataway,
Piscataway,
Piscataway,
Piscataway,
ay, NJ
Market
. of Keni
NJ
NJ
NJ
NJ
NJ
NJ
NJ
NJ
NJ
1735 West front St.
Apgar Dr., South Plainfield, NJ
Apgar Dr. South Plainfield, NJ
437 Jassard St., Piscataway, NJ 08846
437 Jassard St., Piscataway, NJ 08846
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Na
NA
NA
NA
NA
NA
NA
Na
NA
Na
NA
Na
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2 +
NJDEP
Locator
34584
34585
34586
34586
34591
34591
34591
34591
34594
34594
34597
34597
34597
34597
34699
34711
34713
34713
34713
34714
34714
34715
34716
34717
34717
34717
34718
34718
34718
34718
34719
34719
34719
34719
34719
34719
34719
34719
34719
34721
34721
34722
34722
34722
34722
34722
Easting
(ft.)
2068302
2069324
2070346
2070346
2071369
2071369
2071369
2071369
2071369
2071369
2071369
2071369
2071369
2071369
2082613
2056036
2058080
2058080
2058080
2056036
2056036
2057058
2058080
2056036
2056036
2056036
2057058
2057058
2057058
2057058
2058080
2058080
2058080
2058080
2058080
2058080
2058080
2058080
2058080
2059102
2059102
2060124
2060124
2060124
2060124
2060124
Northim
(ft. )
633750
633750
633750
633750
635082
635082
635082
635082
633750
633750
632416
632416
632416
632416
632416
631082
631082
631082
631082
629750
629750
629750
629750
628416
628416
628416
628416
628416
628416
628416
628416
628416
628416
628416
628416
628416
628416
628416
628416
631082
631082
631082
631082
631082
631082
631062
-------
LOW CAPACITY WELLS
WITH IN 2 MILES OF THE CHEMSOL, INC. SITE
Map
Index
Permit No.
2522757
25324845
258633
25324853
4500313
2519144
258351
259683
25317296
2523891
2526404
258903
259064
2533537
2511101
2533533
2533534
2533535
2533536
258616
257605
25309838
25309846
25309854
2530824
2530825
2530823
2520883
2530822
25316559
25313367
25313223
25313215
25313207
258615
259156
2510635
2529291
2529292
25313193
2510572
2525320
2520884
2510098
2527597
1982
NA
NA
NA
1950
1977
1959
NA
1988
1983
1985
1959
1960
1989
1963
1989
1989
1989
1989
NA
1958
1988
1988
1988
1988
1988
1988
1979
1988
1988
1988
1988
1988
1988
NA
1960
1962
1987
1987
1988
1962
1984
1979
NA
1986
Passaro Builders
Texaco
Alberino August
Texaco
National Starch
Huben, Robert
Covallo, Joseph
Manzell, Vincent
United Jersy Bank
Fischer, Chris
Jersey Concrete
Crawford, Earl
Robertson, Clarence
United Jersey Commercial
Chemsol, Inc.
United Jersey Commercial
Untied Jersey Commercial
United Jersey Commercial
United Jersey Commercial
Formal Builders
Saunders, Bruce J.
768 Broad Corp.
Broad Corp.
Broad Corp.
Tano Realty
Tono Realty
Tano Realty
Marra, A.
Tano Realty
76B Broad Corp.
Tano Realty
Tano Realty
Tano Realty
Tano Realty
Formal Builders
Parkway Plastics
All American Homes, Inc.
ARCO
ARCO
Tano Realty
Brown, Raymond C.
Doryea, Jeannette R.
Marra, Anthony
Schreiber, Gilbert
Trus-
Trus-
Trus-
Trus-
Trus-
Sterling Extruder Corporation
437 Jassard St., Pise
Apgar Dr., Plainfield
E side of Maple Ave.
Apgar Rd., South Plai
1735 West Front St.
Lot:494, BlockzlOC, P
NE corner of Eva St.
S. side of Cumberland
Lot:32B, Block:484
1450 S. Washington Av
Lot:388 Block:5 Munic
Lot:388 Block:5 South
W. side of New Bruns
NA
Stelton Rd., Piscataw
Stelton Rd, Piscatawa
Stelton Rd. Piscatawa
Stelton Rd., Piscataw
Stelton Rd., Piscataw
Stelton Rd., Piscataw
S side Of Carpathia
Randolph Rd. , Piscata'
3100 Hamilton Blvd.,
3100 Hamilton Blvd.,
3100 Hamilton Blvd.,
Fleming St., Piscatav
Fleming St., Piscatav
Fleming St., Piscatav
Lot:31-A2 Block:484,
NA
3100 Hamilton Blvd.,
Fleminono St., Piscat
Flemino St., NJ
Flemino St., Piscatav
Flemino St., Piscatav
N. side of St. Michae
New Market
Piscataway Twp, Middl
Lot:9-12, Block:487;
Lot:9-12, Block:487;
Fleming St., Piscatav
583 S. Randolph Rd. N
Lot:3 Block:500A Muni
Lot:31-Al Block:484,
S. side of Stelton Rd
Lot:4 Block: 550 Muni
ataway, NJ 08846
, NJ
200ft N of Winans St.
nfield
e., Piscataway, NJ
ipality: S. Plainfield
Plainfield Boro
•ick Ave.; 1000ft N of R.R. tracks
t; 170 ft W Of Franko St.
ay, NJ
South Plainfield, NJ
South Plainfield, NJ
South Plainfield, NJ
•ay, NJ
•ay, NJ
•ay, NJ
Piscataway, N.J.
South Plainfield, NJ
away, NJ
•ay, NJ
•ay, NJ
1 St., 175ft W of Franko St.
esex Co.
780 Stelton St.
780 Stelton St.
•ay, NJ
ew Market, NJ
cipality:Piscataway Twp
Piscataway NJ
1000ft W. of Hamilton Blvd.
cipality: South Plainfield
Ise
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NAa
NA
NA
NA
NA
NA
NA
NA
NA
NA
Na
Total
Depth
(ft. )
150
10
115
10
304
195
113
130
210
17
285
340
145
152
15
305
10
12
10
10
200
100
61
75
76
250
325
325
190
250
60
80
250
340
250
143
340
122
19
18
330
125
125
190
130
15
Capacity
(gpm)
15
NA
15
NA
350
40
15
12
5
NA
90
60
12
7
NA
190
NA
NA
NA
NA
15
10
2 +
2 +
2 +
3
8
40
40
6
NA
1
30
7
7
15
150
8
1
1
NA
8
25 +
12
10
0
NJDEP
Locator
34722
34722
34722
34722
34723
34723
34725
34725
34726
34726
34731
34731
34732
34732
34734
34734
34734
34734
34734
34734
34735
34736
34736
34736
34736
34737
34737
34737
34737
34737
34738
34738
34738
34738
34738
34738
34738
34738
34738
34738
34738
34742
34742
34756
34762
34764
Easting
(ft.)
2060124
2060124
2060124
2060124
2061146
2061146
2060124
2060124
2061146
2061146
2062169
2062169
2063191
2063191
2062169
2062169
2062169
2062169
2062169
2062169
2063191
2064213
2064213
2064213
2064213
2062169
2062169
2062169
2062169
2062169
2063191
2063191
2063191
2063191
2063191
2063191
2063191
2063191
2063191
2063191
2063191
2057058
2057058
2061146
2063191
2062169
Northim
(ft. )
631082
631082
631082
631082
631082
631082
629750
629750
629750
629750
631082
631082
631082
631082
629750
629750
629750
629750
629750
629750
629750
629750
629750
629750
629750
628416
628416
628416
628416
628416
628416
628416
628416
628416
628416
628416
628416
628416
628416
628416
628416
627082
627082
625750
627082
625750
-------
LOW CAPACITY WELLS
WITH IN 2 MILES OF THE CHEMSOL, INC. SITE
Map
Index
9 9
100
101
102
103
104
104
104
105
106
106
106
106
107
108
108
108
108
108
108
108
108
108
109
110
111
111
111
112
113
114
115
115
115
115
116
116
116
Permit No.
252598
252144
259089
2527598
25284517
2528450
259896
261406
261406
2516338
256793
2534029
2521533
2519501
2511063
256886
2543964
25322150
25322176
25304500
25322184
256715
2521522
2518953
2518952
2518951
2518950
2578949
2518948
259657
454978
2510547
4549251
2532921
2532920
2532191
2520350
2511472
2521010
258231
2523303
2523304
2523305
25324
2526179
2526181
1986
1979
1960
1986
1986
1986
1961
1956
1956
1972
1957
1989
1980
1977
1962
1957
1993
1988
1988
1987
1988
1957
1980
1977
1988
1977
1977
1977
1977
NA
1996
1962
1996
1989
1989
1988
1978
1963
1979
1959
1981
1981
1981
1997
1986
1980
sterling Extruder Corporation
Dematio & Amato
Westman, James
Sterling Extruder Corporation
sterling Extruder corporation
sterling Extruder Corporation
Olechna, Clem
Schenck, Richard
Schenck, Richard
Skladany, Edward T.
Lake Nelson Memorial
Marinelei, Joseph P.
J. DiLeo Associates
Gerictont, Theodore
Winkler, John
Szutlej, Henry
Vocisano, Vincent
Boyer Properties of NJ
Boyer Properties of NJ
Texize, Dow
Boyer Properties of NJ
Bostas, James
Janver Bldrs.
Global Development Cororation
Global Development
Global Development
Global Development Corporation
Global Development Corp.
Global Development Corp.
Ice Palace, Co., Inc.
DeGussa
Coueelesia, Patrick
L. R. Metal Treating
Platina Labs
Platina Labs
Platina Labs
Gaster, John
Yulik, Joseph
Rothberg, Louis
Risoli, John
Kearney Industries
Kearney Industries
Kearney Industries
Atlas Oil Company
Development Corp.
Screnda, Inc.
Lot:4 Block:550 Minicipality: South Plainfield
Lot:27-33, Block:59, Muriel Ave, Piscataway NJ
74 26' 37", 40 33'4"
Lot:4 Block:550 Municipality: South Plainfield
Lot:4 Block:550 Durham Ave., South Plainfield, NJ
Lot:4 Block:550 Durham Ave., S. Plainfield
Piscataway Twp.
New Market
New Market, NJ
Piscataway, NJ
Lake Nelson
604 S. Randolphville Rd.
120 Sylvan Ave., Block:496, Lot:12 Piscataway Twp., Somers
Lot:9B Block:844C Middlesex Co.
30 Lakeway St. New Market Ave.
N. side of Woodlawn Rd., Lake Nelson Development, Piscataway, N.J.
Woodlake Dr.
Lot:15-16, Block:409
Lot:15-16, Block:409
Piscataway, No. 08554
Lot:15-16 BlockL:409
Lot:18, Hamilton Blvd, Middlesex, NJ
Woolworth Ave., S. Plfd Lot:5 Block:437
South Plainfield, Middlesex Co.
Lot:8 Block:437
Lot:2D, Block:438
Lot:2 Block:438
Lot:l, Block:437
Lot:09, Block:437
W. side of Hamilton Blvd., 1000' N of South Clinton Ave.
3900 S. Clinton Ave., South Plainfield, NJ
South Plainfield, Middlesex, NJ
3651 S. Clinton Ave.
3601 S. Clinton Ave. South Plainfield,
NJ
Lot:4, Block:353, South Plainfield,; Middlesex Co.
916 Arlington Ave., s. Plainfield, N.J.
Lot:5678, Block:477, Ryan St.
W. of easton # Blvd., s South of Hamilton Blvd.
2624 Hamilton Blvd.
2624 Hamilton Blvd. South PLainfield
2624 Hamilton Blvd.
318 Durham Ave. S. Plainfield B.
Lot:41.23 Block:70 Naraticong Trail, Readington, Hunterdor
Lot:4127 Block: 70 Municipality:Readington
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Na
NA
NA
NA
NA
NA
NA
NA
NA
NA
17.5
140
125
160
110
100
140
130
50
310
43
197
200
40
40
35
100
95
300
113
750
NJDEP
Locator
34764
34764
34764
34764
34767
34767
34769
34773
34773
34774
34775
34784
34786
34791
34791
34791
34795
34813
34813
34813
34813
34815
34816
34816
34816
34816
34816
34816
34816
34816
34816
34818
34819
34821
34821
34821
34822
34824
34825
34827
34827
34827
34827
34828
34828
34828
Easting
(ft.)
2062169
2062169
2062169
2062169
2062169
2062169
2064213
2058080
2058080
2056036
2057058
2059102
2061146
2062169
2062169
2062169
2063191
2067280
2067280
2067280
2067280
2066258
2067280
2067280
2067280
2067280
2067280
2067280
2067280
2067280
2067280
2066258
2067280
2068302
2068302
2068302
2069324
2068302
2069324
2068302
2068302
2068302
2068302
2069324
2069324
2069324
Northim
(ft. )
625750
625750
625750
625750
624416
624416
624416
623082
623082
621750
621750
621750
621750
623082
623082
623082
621750
631082
631082
631082
631082
629750
629750
629750
629750
629750
629750
629750
629750
629750
629750
628416
628416
631082
631082
631082
631082
629750
629750
628416
628416
628416
628416
628416
628416
628416
-------
LOW CAPACITY WELLS
WITH IN 2 MILES OF THE CHEMSOL, INC. SITE
Map
Index
117
118
119
120
121
122
123
123
124
124
125
125
125
126
126
127
127
127
127
127
128
129
129
130
131
131
132
133
134
135
135
136
136
136
136
137
138
Permit No.
2533861
2523946
2522849
253645
258124
2527530
2526651
2541341
2520980
2527117
256846
2510099
2510101
25310542
25310551
2522442
2527324
25288750
25288768
2528877
2527116
259733
256464
2511197
257251
2516775
2517306
2520469
2518023
2519327
2519608
259901
2521000
2527518
2529446
2525868
2520180
1989
1983
1982
1954
1958
1988
1985
1992
1979
1986
1957
NA
NA
1988
1988
1981
1986
1987
1987
1987
1986
1960
1957
1963
1959
1973
1974
1979
1975
1977
1977
1961
1979
1986
1987
1985
1978
Myrush, Sieve
Sullivan, Sylvester
Rubino, Joseph
Corp. of Engineers, U.S. Arm
Kowalski, Emil
Gulf/Chevron, U.S.A.
Risoli, John F.
Seeman Development
Plfd. Curling Culb
Pelmont Bulders
Gollis, Robert
Tufaro, Vincent
Lyng. Ralph U.
L-R Metal Treating
L-R Metal Treating
Carney Ltd., Federal Carbide
Arometics International Inc.
United States Land Resources
United States Land Resources
United States Land Resources
Pelmont Builders
Tingley Rubber Co.
Gubernat, John F.
Biondella, David
Lynor, E.M.
Schwalje, Nicholas
Breslin, James
Riedel Construction Co., Inc
De Paola, Joseph
Sparacio, Joseph
Sparacio, Joseph
Black, Lafayette W.
Greco, D
Vocisano, Vincent
Vocisano, Dominick
Vocisano, Antonio
Agel, Catherine
101 West St. Middlesex
Lot:7-8, Block:55 Municipality: Somerville Boro
1328 Yurgel Dr., S. Plainfield, NJ
Plainfield, NJ
Piscataway Township, Middlesex Co. N.J.
Stelton and New Durham Rd., NJ
Lot:4 Block:537, Municipality: South Plainfield Boro
86 Commonwealth Ave., Middlesex, NJ
McKinney St. Lot:l Block:488 S. Plfd.
Lot: 7679, Block:774, Municipality:Piscataway Twp
S. Ave Plainfield, NJ
Northwest corner of Pleasant Ave and Monroe Ave.
East side of Chimney Rock, 700ft S. of Gilbride Rd.
3651 S. Clinton Ave., S. Plainfield
3651 S. Clinton Ave, S. Plainfield
Lot:2D,Bl:21 New Durham Rd. Edison, NJ
Lot:45 Block:734A Municipality:Piscataway
Lot:3A12 Block:55
Lot:3A12 Block:55
Lot:3A12 Block:55
Lot:52 Block:710 Municipality: Piscataway Twp.
South Plainfield NJ
Stelton, Middlesex
Palisade Ave. Piscataway
North Stelton, NJ
School St., Piscataway Township, Middlesex Co., NJ Kilmerner Sub Station
Lot:29-32, Block 156, Piscataway, Middlesex
Lot:6, Block:705, Piscataway Twp., Somerset
Lot:l-B, Bl, Bl:74, Piscataway, NJ
Wickley Ave., Piscataway, NJ
Wickley Ave, Piscataway, NJ
Zircle Ave., New Market
Orris Ave., Piscataway, NJ
Lot:13A Block:737: Municiplity: Piscataway, NJ
Lot:9-10 Block:736
Lot:13A Block:737 Municipality:Piscataway Twp.
Sheldon Place, Piscataway, NJ
200
200
200
124
145
190
24 .25
25
550
505
20
20
19
200
428
150
120
440
224
120
145
150
135
125
90
180
190
50
190
165
NJDEP
Locator
34829
34838
34842
34845
34846
34848
34851
34851
34852
34852
34853
34853
34853
34855
34855
34856
34856
34856
34856
34856
34858
34861
34861
34872
34876
34876
34882
34884
34885
44121
44121
44122
44122
44122
44122
44123
44132
Easting
(ft.)
2070346
2072391
2066258
2066258
2067280
2006258
2068302
2068302
2069324
2069324
2070346
2070346
2070346
2069324
2069324
2070346
2070346
2070346
2070346
2070346
2069324
2071369
2071369
2066258
2067280
2067280
2069324
2068302
2069324
2059102
2059102
2060124
2060124
2060124
2060124
2061146
2063191
Northim
(ft. )
628416
628416
627082
625750
625750
624416
627082
627082
627082
627082
627082
627082
627082
625750
625750
625750
625750
625750
625750
625750
624416
627082
627082
623082
621750
621750
623082
621750
621750
619082
619082
619082
619082
619082
619082
619082
619082
-------
HIGH CAPACITY WELLS
WITH IN 2 MILES OF THE CHEMSOL, INC. SITE
Map
Index Permit No.
1
1
2
3
3
4
5
6
6
7
8
8
10215W
10215W
10247W
10660W
10660W
10929W
2105P
2194P
2194P
5045
MI0028
MI0028
Owner
Captive Plastics
Captive Plastics
keystone Plastics
Jersey Concrete Co.
Jersey Concrete Co.
L.R. Metal Treating
Tingley Rubber Corporation
Design and Molding Services
Design and Molding Services
Elizabethtown Water Company Clinton Av
Coppola, Frank
Coppola, Frank
Well
Name
#1
#2
Well 2
1
2
1
1
1
2
r .
POND
Well 1
Distance
(miles)
1.9
1.9
1.9
1.8
1.8
1
1.8
1.3
1.3
2
1.8
1.7
Total
Depth
(ft.)
240
230
300
285
340
200
428
390
294
350
17
310
Geologic
Unit
GTRB
GTRB
GTRB
GTRB
GTRB
GTRBP
GTRB
GRTB
GTRB
GTRB
GTRB
GTRB
Capacity
(gpm)
65
130
48
87
82
100
200
120
120
450
300
100
NJDEP
Locator
33929
33929
34654
34831
34831
34819
34861
34468
34468
34439
34858
34858
Easting
(ft.)
2051946
2051946
2077502
2071369
2071369
2067280
2071369
2063191
2063191
2064213
2069324
2069324
Northing
(ft.)
628416
628416
637750
631082
631082
628416
627082
636416
636416
640416
624416
624416
-------
AFFIDAVIT OF
WILLARD F. POTTER
STATE OF NEW JERSEY )
)SS. :
COUNTY OF MORRIS )
WILIARD F. POTTER, being duly sworn, upon his oath, deposes and says:
1. I am a Senior Project Director at de maximis, Inc., which firm is principally engaged in the business of
environmental consulting.
2. In 1971, I obtained my B.S. in Chemical Engineering from the University of Virginia. A copy of my resume
is attached hereto as Exhibit A.
3. I serve as the Facility Coordinator of the groundwater treatment plant at the Chemsol, Inc. Superfund
Site (the "Site").
4. On or about October 30, 1996, Richard L. Fitament, Executive Director, and Kevin T. Aiello, Administrator,
Environmental Quality, of the Middlesex County Utilities Authority ("MCUA") advised me that the MCUA would
not accept any increased discharge flow from the groundwater treatment plant at the Site.
5. On or about March 10, 1997, Thomas Evans, Director, Piscataway Township Department of Public Works,
advised me that use of the well located at the car wash on Stelton Road has been discontinued.
6. On or about September 3, 1997, Thomas Evans, Director, Piscataway Township Department of Public Works,
advised me that, based on numerous site inspections of the well at the car wash on Stelton Road, the well
continues not to be in use.
7. I have reviewed the proposed remedial actions evaluated in the Feasibility Study Report, Chemsol Inc.
Superfund Site, June 1997 (the "FS") and described in the Superfund Proposed Plan, Chemsol, Inc. Superfund
Site, Piscataway, Middlesex County, New Jersey, August 1997.
8. Attached hereto as Exhibit B is a cost estimate I prepared for Alternative S-2A (Capping with Soil) that
was evaluated in the FS.
9. The FS requires that clean common fill meeting New Jersey soil cleanup criteria be used for cover material
for Alternative S-2A.
10. The FS requires that clean common fill meeting New Jersey soil cleanup criteria be used for backfill for
Alternative S-3 (Excavation and Disposal).
11. Exhibit B uses a unit cost of $5.33/cubic yard for soil cover material for Alternative S-2A, which unit
cost was used for backfill in the cost estimate for Alternative S-3. In my professional opinion, based on my
experience, this revision to the FS cost estimate is reasonable and is within the cost estimating tolerances
prescribed by the Guidance for Conducting Remedial Investigations and Feasibility Studies Under CERCLA,
Interim Final, October 1988.
12. Attached hereto as Exhibit C is a cost estimate prepared for constructing Alternative S-2A over 5.73
acres of the Site using $5.33/cubic yard for soil cover material. In my professional opinion, based on my
experience, these revisions to the FS cost estimate are reasonable and are within the cost estimating
-------
tolerances prescribed by the Guidance for Conducting Remedial Investigations and Feasibility Studies Under
CERCLA, Interim Final, October 1988.
13. Attached hereto as Exhibit D is a cost estimate I prepared for disposal of the stockpiled soil excavated
during the removal of the underground storage tank. The disposal guantit was obtained from the Feasibility
Study Report, Chemsol, Inc. Superfund Site, June 1997, Appendix C. In my professional opinion, based on my
experience, this cost estimate is reasonable and is within the cost estimating tolerances prescribed by the
Guidance for Conducting Remedial Investigations and Feasibility Studies Under CERCLA, Interim Final, October
1988.
14. Attached hereto as Exhibit E is a cost estimate I prepared for constructing Alternative S-2A over 5.73
acres of the Site, using clean common fill at a unit cost of $5.33/cubic yard, disposing of those soils
excavated during the removal of the underground storage tank, and using the remainder of the stockpiled soils
as cover material. In my professional opinion, based on my experience, these revisions to the FS cost
estimate are reasonable and are within the cost estimating tolerances prescribed by the Guidance for
Conducting Remedial Investigations and Feasibility Studies Under CERCLA, Interim Final, October 1988.
15. On or about September 26, 1997, I obtained a verbal cost estimate for disposal of RCRA hazardous soils at
Chemical Waste Management, Inc.'s RCRA Subtitle C Hazardous Waste Landfill located in Model City, New York,
which estimate was $300/cubic yard for transportation and disposal.
16. Attached hereto as Exhibit F is a cost estimate I prepared for Alternative S-3 using the verbal cost
estimate for disposal of RCRA hazardous soils at Chemical Waste Management, Inc.'s RCRA Subtitle C Hazardous
Waste Landfill located in Model City, New York. In my professional opinion, based on my experience, this
revision to the FS cost estimate is reasonable and is within the cost estimating tolerances prescribed by the
Guidance for Conducting Remedial Investigations and Feasibility Studies Under CERCLA, Interim Final, October
1988.
17. Using the analytical data presented in the Remedial Investigation Report, Chemsol, Inc. Superfund Site,
October 1996, including, but not limited to, the figures presented in Appendix H, I estimate the additional
soil volume that would be reguired to be excavated to achieve the State of New Jersey's PCB cleanup criterion
of 0.49 ppm to be approximately 6,000 cubic yards.
18. Attached hereto as Exhibit G is a cost estimate I prepared for Alternative S-3 for excavating soil to
achieve the State of New Jersey's PCB cleanup criterion and disposing of that soil at a nonhazardous waste
landfill. In my professional opinion, based on my experience, this revision to the FS cost estimate is
reasonable and is within the cost estimating tolerances prescribed by the Guidance for Conducting Remedial
Investigations and Feasibility Studies Under CERCLA, Interim Final, October 1988.
19. Attached hereto as Exhibit H is a cost estimate I prepared for Alternative S-3 for excavating soil to
achieve the State of New Jersey's PCB cleanup criterion and disposing of that soil at a hazardous waste
landfill, using the verbal cost estimate for disposal of RCRA hazardous soils at Chemical Waste Management,
Inc.'s RCRA Subtitle C Hazardous Waste Landfill located in Model City, New York. In my professional opinion,
based on my experience, these revisions to the FS cost estimate are reasonable and are within the cost
estimating tolerances prescribed by the Guidance for Conducting Remedial Investigations and Feasibility
Studies Under CERCLA, Interim Final, October 1988.
20. The foregoing statements are made to the best of my knowledge and belief.
-------
Exhibit A
Willard F. Potter
Professional Qualificaions
Mr. Potter is a Chemical Engineer with twenty five (25) years of diversified environmental project management
and engineering experience in the industrial, regulatory and consulting areas. Mr. Potter was formerly
Corporate Director of Hazardous Waste Control for Allied-Signal. He was responsible for all Superfund site
investigations and negotiations with regulatory agencies. Mr. Potter represented Allied on numerous industry
lead potentially responsible party (PRP) groups for Superfund National Priority List (NPL) sites.
As Vice President of Technical Litigation Support Services for Dunn Gaoscience Corporation, Mr. Potter
represented industrial clients during litigation involving environmental insurance coverage, acguisition and
divestiture indemnification issues and agency negotiations.
Mr. Potter's project management experience includes Remedial Investigation/Feasibility Studies (RI/FS), waste
minimization, remedial design, RCRA corrective action and development/implementation of an; experience also
includes six (6) years with USEPA Region III in the NPDES permit program.
Education
B.S., Chemical Engineering, University of Virginia, Charlottesville, Virginia; 1971
Major Projects
! Primary Project Coordinator for PRP Group which conducted a RD/RA for a $3.5MM groundwater treatment
facility at a NPL solvent recycling facility in Region II. Activities/responsibilities include
coordination and negotiation of work plans, day-to-day management of general contractor, contracting,
financial management/tracking and regulatory liaison for PRP Committee. The treatment facility, was
completed on schedule and is now operating in compliance with permits. The facility design
incorporated process automation and remote monitoring to minimize operator coverage.
! Primary Project Coordinator for PRP Group conducting a RD/RA of NPL municipal landfill in Region II.
Activities include coordination of a supplemental hydrogeologic; investigation to support the design
of a groundwater extraction and reinjection system.
! Primary Project Coordinator for a PRP Group conducting a RD/RA of two related NPL sites in the Now
Jersey Pine Barrens Preservation District. Responsibilities; include coordination and communications
with multiple contractors, the PRP Group and the NJDEPE. Coordination of ecological assessments,
modeling of potential ecological impacts from groundwater extraction and remedial design optimization
a major activity. Other significant responsibilities include financial management/invoice review,
progress reports, strategy development and public relations program support.
! Technical litigation and case management support for a lawsuit involving over $50 million in
environmental damage claims associated with contract of sale indemnification language. Activities
include review and critigue of proposed remedial activities and cost estimates, file searches,
participation at depositions and expert witness testimony.
! Technical litigation and case management support in two (2) environmental insurance coverage lawsuits.
Activities include file searches, regulatory research and interviews of potential expert witnesses.
! Original member of Chemical Manufacturer Association's Hazardous Waste Response Center Activities
Included site inspections of six (6) NPL sites to provide EPA and State agencies with guidance on the
conduct of Remedial Investigations. The group authored CMA's "Hazardous Waste Site Management Plan".
! Provided technical support to NJDEPE during remedial activities at an incineration facility on the
-------
NPL. Developed waste compatibility protocol for bulking of containerized waste material.
Responsible for eight (8) ECRA investigations in New Jersey resulting from major corporate
acguisition.
Responsible for in-house guidance manuals and associated training on Superfund contracting, selection
of outside laboratories, assessment of emerging remedial technologies and RI/FS planning activities.
-------
EXHIBIT B
COST ESTIMATE FOR ALTERNATIVE S-2A
CAPPING WITH SOIL
Item Size or Quantity Capital Costs O&M Costs($)
($) Annual Present Worth
1. DEED RESTRICTION 1LS 25,000
2. OFFSITE DISPOSAL OF DRUMMED WASTE
- Sampling and Analysis 10 20,000
- Well Cuttings 167 drums 23,380
- Baker Tank Sediment 95 drums 13,300
- PPE 56 drums 7,840
- Plastic Sheeting 22 drums 3,080
- Hose/Wire/Polytubing 3 drums 420
- Misc. Solid Waste 25 drums 3,500
3. OFFSITE DISPOSAL OF SOIL STOCKPILE
- Sampling and Analysis 10 20,000
- Loading onto Dumpsters 4 days 5,200
- Transportation and Disposal 1,450 cy 101,500
4. CAPPING WITH SOIL
- Site Clearing and Grubbing, Rough Grading 12 acres 36,000
and 'Dewatering
- Soil Cover 12 acres 12-in thick 103,200
- Topsoil and Seed 12 acres 6-in thick 377,520 2,000 30,740
Subtotal 739,940 2,000 30,740
CONSTRUCTION SUBTOTAL 739,940 2,000 30,740
Health and Safety 10% 73,994 3,074
Bid Contingency 15% 110,991 4,611
Scope Contingency 30% 221,982
CONSTRUCTION TOTAL 1,146,907 2,000 38,425
Permitting & Legal 5% 57,345
Services During Construction ' 10% 114,691
TOTAL IMPLEMENTATION COSTS 1,318,943 38,425
-------
Engineering & Design 10% 131,894
TOTAL ESTIMATED COSTS 1,450,837 38,425
NET PRESENT WORTH OF COSTS $1,489,262.36
5% discount
1. Costs for offsite disposal are based on assumption that all soil and wastes are disposed of at a non-TSCA facility.
2. Costs for soil cover are based on $5.33/cy used by USEPA in Alternative S-3.
-------
EXHIBIT C
COST ESTIMATE FOR ALTERNATIVE S-2A CAPPING WITH SOIL
Item
1. DEED RESTRICTION
2. OFFSITE DISPOSAL OF DRUMMED WASTE
- Sampling and Analysis
- Well cuttings
- Baker Tank Sediment
- PPE
- Plastic Shooting
- Hose/Wire/Polytubing
- Misc. Solid Waste
3. OFFSITE DISPOSAL OF SOIL STOCKPILE
- Sampling and Analysis
- Loading onto Dumpsters
- Transportation and Disposal
4. CAPPING WITH SOIL
- Site Clearing and Grubbing, Rough Grading
and'Dewatering
- Soil Cover
- Topsoil and Seed
Subtotal
CONSTRUCTION SUBTOTAL
Health and Safety
Bid Contingency
Scope Contingency
CONSTRUCTION TOTAL
Permitting & Legal
Services During Construction
Size or Quantity
1LS
10
167 drums
95 drums
5 6 drums
22 drums
3 drums
2 5 drums
10
4 days
1,450 cy
5.73 acres
5.73 acres 12-in thick
5.73 acres 6-in thick
10%
15%
30%
5%
10%
Capital Costs
($)
25,000
20,000
23,380
13,300
7,840
3,080
420
3,500
20,000
5,200
101,000
17,190
49,300
180,270
469,980
469,980
46,998
70,497
140,994
728,469
36,423
72,847
O&M Costs ($)
Annual Presen
2,000 30,740
2,000 30,740
2,000 30,740
3,074
4,611
2,000 38,425
TOTAL IMPLEMENTATION COSTS
837,739
38,425
-------
Engineering & Design 10% 83,774
TOTAL ESTIMATED COSTS 921,513 38,425
NET PRESENT WORTH OF COSTS $959,938.29
5% discount
1. Costs for offsite disposal are based on assumption that all soil and waste are disposed of at a non-TSCA facility.
2. Costs for soil cover are based on S5.33/cy used by USEPA in Alternative S-3.
-------
Exhibit D
EXHIBIT D
COST ESTIMATE FOR
DISPOSAL OF STOCKPILED SOIL
Item
Sampling and Analysis
Loading into Dumpsters
Transportation and Disposal
TOTAL
Size or Quantity
2 Samples
1 day
250 cy
cost (&)
4,000
1,300
17,500
$22,800
1. Cost for sampling and analysis based on $2,000 per sample and rate 1 sample per 145 cy used in
Alternative S-2A by USEPA.
2. Cost for loading into dumpsters based on $1,300 per day and rate of 362.5 cy of soil loaded per day used
in Alternative S-2A by USEPA.
3. Cost for transportation and disposal based on rate used in Alternative S-2A by USEPA and the excavated
soil volume associated with the leaking underground storage tank (FS Appendix C).
-------
EXHIBIT E
COST ESTIMATE FOR ALTERNATIVE S-2A CAPPING WITH SOIL
Item Size or Quantity Capital Costs Jam Costs($)
($) Annual Present Worth
1. DEED RESTRICTION 1LS 25,000
2. OFFSITE DISPOSAL OF DRUMMED WASTE
- Sampling and Analysis 10 20,000
- Well Cuttings 167 drums 23,390
- Baker Tank Sediment 95 drums 13,300
- PPE 58 drums 7,840
- Plastic Sheeting 22 drums 3,080
- Hose/Wire/Polytubing 3 drums 420
- Misc. Solid Waste 25 drums 3,500
3. OFFSITE DISPOSAL OF SOIL STOCKPILE
- Sampling and Analysis 2 4,000
- Loading onto Dumpsters 1 day 1,300
- Transportation and Disposal 250 cy 17,500
4. CAPPING WITH SOIL
- Site Clearing and Grubbing, Rough Grading 5.73 acres 17,190
and Dewatering
- Soil Cover 5.73 acres 12-in thick 42,900
- Topsoil and Seed 5.73 acres 6-in thick 180,270 2,000 30.740
Subtotal 359,680 2,000 30,740
CONSTRUCTION SUBTOTAL 359,680 2,000 30,740
Health and Safety 10% 35,968 3,074
Bid Contingency 15% 53,952 4,611
Scope Contingency 30% 107,904
CONSTRUCTION TOTAL 557,504 2,000 38,425
Permitting & Legal 5% 27,875
Services During Construction 10% 55,750
TOTAL IMPLEMENTATION COSTS 641,130 38,425
-------
Engineering & Design 10% 64,113
TOTAL ESTIMATED COSTS 705,243 38,425
NET PRESENT WORTH OF COSTS $743,667.56
5% discount
1. Costs for offsite disposal are based on assumption that all soil and wastes are disposed of at a non-TSCA facility.
2. Costs for soil cover are based on $5.33/cy used by USEPA in Alternative S-3.
3. Soil cover costs are reduced because 1,200 cy of stockpiled soil now assumed to be used as soil cover.
-------
EXHIBIT F
COST ESTIMATE FOR ALTERNATIVE S-3 EXCAVATION AND OFFSITE DISPOSAL
Item Size or Quantity Capital Costs O&M Code($)
($) Annual Present Worth
1. EXCAVATION
- Clearing and Grubbing 3 acres 9,240
- Temporary Drainage/watering 1 Is 20,000
- Excavation 18,500 cy 55,000
- Confirmatory Sampling 160 72,000
2. OFFSITE DISPOSAL OF DRUMMED WASTE
- Sampling and Analysis 10 20,000
- Wall Cuttings 167 drums 233,800
- Baker Tank Sediment 95 drums 13,300
- PPE 58 drums 7,840
- Plastic Sheaft 22 drums 3,080
- Hose/Wire/Polylubing 3 drums 420
- Misc. Solid Wastes 25 drums 3,500
3. OFFSITE DISPOSAL OF SOIL STOCKPILE
- Sampling and Analysis 10 20,000
- Loading onto Trucks 4 days 5,200
- Transportation and Disposal 1,450 cy 435,000
4. OFFSITE DISPOSAL OF EXCAVATED SOIL
- Sampling and Analysis 225 450.000
- Offsite Transportation & Disposal 18,500 cy 5,550,000
6. BACKFILLING
- Imported Common Fill 12 acres 1.5-ft 154,880
- Topsoil and Seed 12 acres 6-in 377,520
Subtotal 7,430,780 0 0
CONSTRUCTION SUBTOTAL 7,430,780 0
Health and Safety 10% 743,078 0
Bid Contingency 15% 1,114,617 0
Scope Contingency 30% 2,229,234
-------
CONSTRUCTION TOTAL 11,517,709 0 0
Permitting & Legal 5% 575,885
Services During Construction 10% 1,151,771
TOTAL IMPLEMENTATION COSTS 13,245,365 0
Engineering & Design 10% 1,324,537
TOTAL ESTIMATED COSTS 14,569,902 0
NET PRESENT WORTH OF COSTS $14,569,902
1. Costs for offsite disposal are based on assumption that all soil and wastes are disposed of at a RCRA facility @ $300/cy.
2. Sample number for offsite disposal of excavated soil is based on NJDEP waste classification reguirements consistent with FS.
3. Apparent FS error in wall cuttings disposal cost maintained for consistency.
-------
EXHIBIT G
COST ESTIMATE FOR ALTERNATIVE S-3 EXCAVATION AND OFFSITE DISPOSAL
Item Size or Quantity Capital Cost O&M costs ($)
($) Annual Present Worth
1. EXCAVATION
- Clearing and Grubbing 3 acres 9,240
- Temporary Drainage/Dewatering 1 is 20,000
- Excavation 24,600 cy 72,770
- Confirmatory Sampling 160 72,000
2. OFFSITE DISPOSAL OF DRUMMED WASTE
- Sampling and Analysis 10 20,000
- Well cuttings 187 drums 233,800
- Baker Tank Sediment 95 drums 13,300
- PPE 56 drums 7,840
- Plastic Sheeting 22 drums 3,080
- Hose/Wire/Polytubing 3 drums 420
- Misc. Solid Waste 25 drums 3,500
3. OFFSITE DISPOSAL OF SOIL STOCKPILE
- Sampling and Analysis 10 20,000
- Loading onto Trucks 4 days 5,200
- Transportation and Disposal 1,450 cy 101,500
4. OFFSITE DISPOSAL OF EXCAVATED SOIL
- Sampling and Analysis 298 596,000
- Offsite Transportation & Disposal 24,500 cy 1,715,000
5. BACKFILLING
- Imported Common Fill 12 acres 1.5-ft 154,880
- Topsoil and Seed 12 acres 6-in 377,520
Subtotal 3,426,050 0 0
CONSTRUCTION SUBTOTAL 3,426,050 0
Health and Safety 10% 342,605 0
Bid Contingency 15% 513,908 0
Scope Contingency 30% 1,027,815
-------
CONSTRUCTION TOTAL 5,310,378 0 0
Permitting & Legal 5% 265,519
Services During Construction 10% 531,038
TOTAL IMPLEMENTATION COSTS 6,106,934 0
Engineering & Design 10% 610,693
TOTAL ESTIMATED COSTS 6,717,628 0
NET PRESENT WORTH OF COSTS $6,717,628
5% discount
1. Costs for offsite disposal are based on assumption that all soil and wastes are disposed of at a non-TSCA facility.
2. Sample number for offsite disposal of excavated soil is based on NJDEP waste classification reguirements consistent with FS.
3. 6,000 cy additional soil for sampling and offsite disposal.
4. Apparent FS error in well cuttings disposal cost maintained for consistency.
-------
EXHIBIT H
COST ESTIMATE FOR ALTERNATIVE S-3 EXCAVATION AND OFFSITE DISPOSAL
Item Size or Quantity Capital Costs O&M Costs ($)
($) Annual Present Worth
1. EXCAVATION
- Clearing and Grubbing 3 acres 9,240
- Temporary Drainage/Dewatering 1 Is 20,000
- Excavation 24,500 cy 72,770
- Confirmatory Sampling 160 72,000
2. OFFSITE DISPOSAL OF DRUMMED WASTE
- Sampling and Analysis 10 20,000
- Well Cuttings 167 drums 233,800
- Baker Tank Sediment 95 drums 13,300
- PPE 56 drums 7,840
- Plastic Sheeting 22 drums 3,080
- Hose/Wire/Polytubing 3 drums 420
- Misc. Solid Waste 25 drums 3,500
3. OFFSITE DISPOSAL OF SOIL STOCKPILE
- Sampling and Analysis 10 20,000
- Loading onto Trucks 4 days 5,200
- Transportation and Disposal 1,450 cy 435,000
4. OFFSITE DISPOSAL OF EXCAVATED SOIL
- Sampling and Analysis 298 596,000
- Offsite Transportation & Disposal 24,500 cy 7,350,000
5. BACKFILLING
- Imported Common Fill 12 acres 1.5-ft 154,880
- Topsoil end Seed 12 acres 6-in 377,520
Subtotal 9,394.550 0 0
CONSTRUCTION SUBTOTAL 9,394,550 0
Health and Safety 10% 939,455 0
Bid Contingency 15% 1,409,183 0
Scope Contingency 30% 2,818,365
-------
CONSTRUCTION TOTAL 14,561,553 0 0
Permitting & Legal 5% 728,078
Services During Construction 10% 1,456,155
TOTAL IMPLEMENTATION COSTS 16,745,785 0
Engineering & Design 10% 1,674,579
TOTAL ESTIMATED COSTS 18,420,364 0
NET PRESENT WORTH OF COSTS $18,420,364
1. Costs for offsite disposal are based an assumption that all soil and wastes are disposed of at a RCRA facility @ $300/cy.
2. Sample number for offsite disposal of excavated soil is based on NJDEP waste classification reguirements consistent with FS.
3. 6,000 cy additional soil for sampling and offsites disposal.
4. Apparent FS error in well cuttings disposal cost maintained for consistency.
-------
Chemsol, Inc. Superfund Site
Responsiveness Summary
Appendix - B
Written comments received by EPA during the public comment period
CHEMSOL TREATMENT SYSTEM
INITIAL STUDY - EFFLUENT CHRONIC TOXICITY
Prepared by
Bigler Associates, Inc.
September 9, 1996
Introduction
The purpose of this study, was to determine if the Chemsol Treatment Plant effluent could meet the proposed
surface water discharge reguirements for Chronic Toxicity, and what if any pretreatment of the effluent would
be reguired to achieve compliance. Since start up of the facility, no Acute or Chronic Toxicity testing of
the effluent has ever taken place. Agua Survey, Inc. of Flemington, NJ was selected as the contract
laboratory to run the Chronic Toxicity testing. Bigler Associates supervised the project, ran on site testing
and pretreatment of the split samples.
Chronic Toxicity
The Chronic Toxicity test is used to determine the effect of the discharge on aguatic biota. Aguatic
organisms are exposed to various concentrations of the treatment system effluent for a six or seven day
period (depending on type of organism used). After the exposure, observations are made regarding the
organisms' survival rate, weight gain, reproductive ability, and other indicators of health of the organism.
The data is compared to a control group and statistical analysis is performed.
Measurement of the chronic toxicity is reported several ways as follows.
NOEC : No-observed-effect concentration - the highest toxicant concentration in which the values for the
measured parameters (weight, survival, reproduction, etc.) are not significantly different from the control.
A high NOEC value indicates low Chronic Toxicity.
LOEC : Lowest-observed-effect concentration - the lowest toxicant concentration in the values for the
measured parameters are statistically significantly different from the control. A high LOEC value indicates
low Chronic Toxicity.
1C 25 : Incipient Concentration 25% - The concentration of effluent which produced a chronic toxic effect on
25% of the organisms as compared to the control group. A high 1C 25 value indicates low Chronic Toxicity.
The proposed surface water discharge limitations include an NOEC limit of 100% (the lowest possible measured
Chronic Toxicity) for two test organisms. The organisms tested are the Fathead minnow (Pimephales promelas) 7
day larval survival and growth test and Cladoceran (Ceriodaphnia dubia) 3 brood survival and reproduction
test. Simultaneous split sample tests are run on both organisms and the more stringent results apply to the
permit.
-------
Chemsol Effluent Testing
In order to determine if the effluent could meet the strict requirements indicated in the permit equivalent,
a full set of toxicity testing was run. Since the persistent presence of Hydrogen Sulfide (H 2 S) in the
effluent was a concern regarding the Chronic Toxicity, two sets of samples were run to determine if removal
of the H 2 S was necessary. One set was labeled "untreated effluent" and consisted of samples collected
during the week period that were delivered to the lab untreated. The second set of samples labeled "treated
effluent" consisted of samples that were treated with 0.5 mg/L Hydrogen Peroxide and 45 minutes of aeration
to remove any Hydrogen Sulfide.
Routine testing of the over the past two years indicated that the H 2 S concentration in the effluent is
typically 2.5 mg/L. BAI performed bench testing of the effluent with Hydrogen Peroxide and aeration and
determined the normal dosage requirements for oxidation of H 2 S. Once the samples were collected for the
Toxicity test, they were tested on site to determine the concentration of H 2 S before treatment and delivery
to the laboratory. The results indicated that no H 2 S was present in the sample after collection, although a
grab sample of the effluent was measured with 2.1 mg/L H 2 S. This absence of Hydrogen Sulfide was
attributed to the method of sample collection which relied on sample flowing at a slow rate into an open
container. The long detention time in the shallow container allowed for atmospheric oxidation of the H 2 S.
It was decided to treat one set of samples with a minimum dosage of Hydrogen Peroxide and continue to
determine if there would be any positive effect from the pretreatment since the peroxide would also oxidize
many organic compounds that may remain.
Test Results
The following table summarizes the results of tests contained in the attached reports.
Sample
Untreated Eff.
Untreated Eff.
Treated Eff.
Treated Eff.
The above results indicate that the untreated sample demonstrated no Chronic Toxicity in either species
tested. The treated sample showed no Chronic Toxicity in the Fathead minnow, but toxicity was indicated with
the daphnia in this sample. It is likely that even at 0.6 mg/L the Hydrogen Peroxide concentration was too
great for this organism, however based on this one test pretreatment of the effluent with Hydrogen Peroxide
to remove Hydrogen Sulfide is not needed.
Recommendations
To verity the results, BAI recommends that the Chronic Toxicity test be repeated at least one more time on
the untreated effluent. Consideration should also be given to running an additional test on effluent from a
clean carbon bed to determine if the biological activity in the carbon unit is responsible for positive
results. BAI would also recommend a post aeration system be added to the existing effluent tank to facilitate
stripping of residual H 2 S if discharge to surface water becomes a viable alternative.
Organism
C.
P.
C.
P.
dubia
Promelas
dubia
promelas
NOEC
100.0%
100.0%
12.5%
100.0%.
LOEC
>100%
>100%
25.0%
>100%
1C 25
>100%
>100%
26.7%
>100%
-------
CHRONIC BIOMONITORING REPORT
Chemsol Plant
Pimephales promelas
(Untreated)
BIEGLER ASSOCIATES
PO BOX 261
RIDGEFIELD PARK, NJ 07660
September 4, 1996
JOB #96-294
499 Point Breeze Road D Flemington, New Jersey 08822 D Telephone (908)788-8700 FAX (908)788-9165
-------
NJPDES BIOMONITORING REPORT FORM
CHRONIC TOXICITY TESTS
FACILITY NAME: Chemsol Plant
FACILITY LOCATION:
LABORATORY NAME: Aqua Survey,Inc. ACUTE TOXICITY ID./CERTIFICATION: 10309
DATE OF LAST SRT TEST: 7/22/96 NOEC/IC 25: 0.5 ppt KCI /0.56
CONTROL CHART MEAN(NOEC/IC 25): 0.35/0.60 UPPER CONTROL LIMIT: 0.70/0.89
LOWER CONTROL LIMIT: 0.18/0.33
TEST START DATE: 8/13/96 TEST END DATE: 8/20/96
TEST TYPE AND RESULTS (Check applicable test and fill in NOEC and LOEC):
X Fathead minnow, (CN/FM) NOEC: 100% LOEC: >100% 1C 25: >100%
Method 1000.0 (Pimephales promelas) 7 day Larval Survival and Growth Test)
_ Cladoceran, (CN/CD) NOEC LOEC
Method 1002.0 (Ceriodaphnia dubia) 3 brood Survival and Reproduction Test)
_ Sheepshead minnow,(CN/SM) NOEC LOEC
Method 1005.0 (Cyprinodon variegatus) 7 day Larval Survival and Growth Test)
_ Inland Silverside, (CN/IS) NOEC LOEC
Method 1006.0 (Menidia beryllina) 7 day Larval Survival and Growth Test)
Mysid, (CN/MS) NOEC LOEC
Method 1007.0 (Mysidopsis bahia) 7 day Survival, Growth and Fecundity Test)
Alga, (CN/SC) NOEC LOEC
Method 1003.0 (SelEnastrum capricornutum) Growth Test)
_ Macroalga, (CN/CP) NOEC LOEC
Method 1009.0 (Champia parvula) Sexual Reproduction Test)
CONTROL MORTALITY (Percent): zero
Did the test meet the acceptability criteria for the test species as specified in Part M of the Chronic
Methods Document?
Yes X No _
CERTIFICATION:
Accuracy of report certified by:
-------
Number of Effluent Concentrations: 5
Number of Replicates per Test Concentration: 4
Number of Test Organisms per Replicate: 10
Number of Test Organisms per Test Concentration: 40
Test Chamber Size: 1000 ML
Explain any deviations from the specified testing methodology:
EFFLUENT SAMPLING
Plant Sampling Location:
Effluent Type:
Sample Type:
Sample Collection
24 hour Composite
X
Other
Sample Data taken upon
arrival at laboratory
Beginning
Date/Time
8/11 - 8-00 am
8/13 - 8.00 am
8/15 - 8:00 am
Ending
Date/Time
9/12 - 8:00 am
8/14 - 8:00 am
8/16 - 8:00 am
D.O.
6.7
5.7
6.0
PH
7.3
7.2
7.4
Maximum holding time of any effluent sample 72 hrs.
Describe any pretreatment of the effluent sample:
Testing Location:
On-site Mobile Laboratory _
On-site Commercial Laboratory
Remote Laboratory x
Exposure Volume: 500 mL
Describe: _
Use in Toxicity Test
Date(s)
9/13-14
8/15-16
8/17-19
Time(s)
3:00 pm
2:30 pm
9:00 am
DILUTION WATER
Effluent Receiving Water:
Dilution Water Source: 100% EPA Moderately Hard Reconstituted Water
Describe any adjustment to the dilution water
If receiving water used as dilution water source, describe collection location and dates of collection:
499 Point Breeze Road D Flemington, New Jersey 08822 D Telephone (908) 788-8700 FAX(908) 788- 9165
-------
SUMMARY SHEET FOR THE FATHEAD MINNOW, SHEEPSHEAD MINNOW,
INLAND SILVERSIDE AND MYSID TESTS
Percent Effluent
Control
6.25
12.5
25
50
1100
Mean Percent Survival
100.0
90.0
95.0
92.5
95.0
97.5
x Cultured Stock
Mean Dry Weight Percent of Surviving
Females with Eggs
0.608
0.565
0.573
0.555
0.660
0.625
_ Commercial Supplier
Organism source:
Name of Supplier:
Hatch Dates: 8/12/96
Organism Age (days/hrs): <24 hrs.
Describe any aeration which was performed during the test: No aeration was reguired during the test period.
Describe any adjustments to the salinity of the test concentrations:
How long after test termination were the organisms prepared for weighing/drying? immediately
Was the average dry weight per test chamber determined by dividing the final dry weight by the number of
original test organisms in the test chamber? X Yes _ No
Did the temperature in the test chambers vary by more than 15C each day?
x Yes _ No
Did the salinity in the test chambers vary more than 2ppt between replicates each day?
_Yes _ No
* How long after test termination were the mysids examined for eggs and sexes?
* Applies to mysid test only
499 Point Breeze Road D Flemington, New Jersey 08822 D Telephone (908) 788-8700 FAX(908)788-9165
-------
A
P
P
E
N
D
I
X
Chemsol 96-294 untreated P. promelas Survival
File: 294upps Transform: ARC SINE(SQUARE ROOT(Y))
Shapiro - Wilk's test for normality
D = 0.184
W = 0.967
Critical W (P = 0.05) (n = 24) = 0.916
Critical W (P = 0.01) (n = 24) = 0.884
Data PASS normality test at P=0.01 level. Continue analysis.
Hartley's test for homogeneity of variance
Bartlett's test for homogeneity of variance
These two tests can not be performed because at least one group has zero variance.
Data FAIL to meet homogeneity of variance assumption.
Additional transformations are useless.
-------
TITLE: Chemsol 96-294 untreated P. promelas Survival
FILE. 294upps
TRANSFORM: ARC SINE(SQUARE ROOT(Y)) NUMBER OF GROUPS: 6
GRP
IDENTIFICATION REP
VALUE
TRANS VALUE
Control
Control
Control
Control
6.25
6.25
6.25
6.25
12.5
12.5
12.5
12.5
25
25
25
25
50
50
50
50
100
100
100
100
1
2
3
4
1
2
3
4
1
2
3
4
1
2
3
4
1
2
3
4
1
2
3
4
1.
1.
1.
1.
0.
0.
1.
0.
1.
0.
1.
0.
0.
1.
0.
1.
1.
0.
1.
0.
1.
1.
1.
,0000
,0000
,0000
,0000
,9000
,8000
,0000
,9000
,0000
,9000
,0000
,9000
,8000
,0000
,9000
,0000
,0000
,9000
,0000
,9000
,0000
,0000
,0000
1,
1,
1,
1,
1,
1,
1,
1,
1,
1,
1,
1,
1,
1,
1,
1,
1,
1,
1,
1,
1,
1,
1,
.4120
.4120
.4120
.4120
.2490
.1071
.4120
.2490
.4120
.2490
.4120
.2490
.1071
.4120
.2490
.4120
.4120
.2490
.4120
.2490
.4120
.4120
.4120
0.9000
1.2490
SUMMARY STATISTICS ON TRANSFORMED DATA TABLE 1 of 2
GRP
IDENTIFICATION
MIN
MAX
MEAN
Control
6.25
12.5
25
50
100
4
4
4
4
4
4
1.412
1.107
1.249
1.107
1.249
1.249
1.412
1.412
1.412
1.412
1.412
1.412
,412
,254
,331
,295
,331
1.371
Chemsol 96-294 untreated P. promelas Survival
File: 294upps Transform: ARC SINE(SQUARE ROOT(Y))
SUMMARY STATISTICS ON TRANSFORMED DATA TABLE 2 of 2
GRP
IDENTIFICATION
VARIANCE
SD
SEM
C.V. %
Control
6.25
12.5
25
50
100
0.000
0.016
0.009
0.022
0.009
0.007
0.000
0.125
0.094
0.147
0.094
0.081
0.000
0.062
0.047
0.073
0.047
0.041
0.00
9.93
7.07
11.35
7.07
5.94
-------
STEEL'S MANY-ONE RANK TEST - Ho:ControKTreatment
TRANSFORMED
GROUP
1
2
3
4
5
6
IDENTIFICATION
Control
6.25
12.5
25
50
100
MEAN
1
1
1
1
1
1
.412
.254
.331
.295
.331
.371
RANK
SUM
12.
14.
14.
14.
16.
00
00
00
00
00
GRIT.
VALUE
10,
10,
10,
10,
10,
.00
.00
.00
.00
.00
4
4
4
4
4
df
.00
.00
.00
.00
.00
Critical values use k = 5, are 1 tailed, and alpha = 0.05
Shapiro - Wilk's test for normality
D = 0.053
W = 0.968
Critical W (P = 0.05) (n = 24) = 0.916
Critical W (P = 0.01) (n = 24) = 0.884
Data PASS normality test at P=0.01 level. Continue analysis.
Bartlett's test for homogeneity of variance
Calculated Bl statistic = 3.53
Table Chi-square value = 15.09 (alpha = 0.01, df = 5)
Table Chi-square value = 11.07 (alpha = 0.05, df = 5)
Data PASS Bl homoqeneity test at 0.01 level. Continue analysis.
SIG
-------
TITLE: Chemsol 96-294 Untreated P. promelas Dry Weight
FILE: 294uppdw
TRANSFORM: NO TRANSFORMATION NUMBER OF GROUPS: 6
GRP IDENTIFICATION
REP
VALUE
TRANS VALUE
1
1
1
1
2
2
2
2
3
3
3
3
4
4
4
4
5
5
5
5
6
6
6
6
Control
Control
Control
Control
6.25
6.25
6.25
6.25
12.5
12.5
12.5
12.5
25
25
25
25
50
50
50
50
100
100
100
100
1
2
3
4
1
2
3
4
1
2
3
4
1
2
3
4
1
2
3
4
1
2
3
4
0.6100
0.6800
0.5500
0.5900
0.5500
0.4900
0.5400
0.6800
0.5400
0.5700
0.5700
0.6100
0.5400
0.5900
0.4800
0.6100
0.6700
0.6200
0.7000
0.6500
0.6400
0.5600
0.6900
0.6100
0.6100
0.6800
0.5500
0.5900
0.5500
0.4900
0.5400
0.6800
0.5400
0.5700
0.5700
0.6100
0.5400
0.5900
0.4800
0.6100
0.6700
0.6200
0.7000
0.6500
0.6400
0.5600
0.6900
0.6100
-------
Control
6.25
12.5
25
50
100
4
4
4
4
4
4
0.550
0.490
0.540
0.480
0.620
0.560
0.680
0.680
0.610
0.610
0.700
0.690
0.608
0.565
0.573
0.555
0.660
0.625
SUMMARY STATISTICS ON TRANSFORMED DATA TABLE 1 of 2
GRP IDENTIFICATION N MIN MAX MEAN
1
2
3
4
5
6
SUMMARY STATISTICS ON TRANSFORMED DATA TABLE 2 of 2
GRP IDENTIFICATION VARIANCE SD SEM C.V. %
1 Control 0.003 0.054 0.027 8.95
2 6.25 0.007 0.081 0.041 14.34
3 12.5 0.001 0.029 0.014 5.02
4 25 0.003 0.058 0.029 10.45
5 50 0.001 0.034 0.017 5.10
6 100 0.003 0.054 0.027 8.71
ANOVA TABLE
SOURCE DF SS MS F
Between 5 0.033 0.007 2.223
Within (Error) 18 0.053 0.003
Total 23 0.086
Critical F value - 2.77 (0.05,5,18)
Since F < Critical F FAIL TO REJECT Ho: All equal
DUNNETT'S TEST - TABLE 1 OF 2 Ho: ControKTreatment
TRANSFORMED MEAN CALCULATED IN
GROUP IDENTIFICATION MEAN ORIGINAL UNITS T STAT SIG
1 Control 0.608 0.608
2 6.25 0.565 0.565 1.103
3 12.5 0.573 0.573 0.908
4 25 0.555 0.555 1.363
5 50 0.660 0.660 -1.363
6 100 0.625 0.625 -0.454
Dunnett table value - 2.41 (1 Tailed Value, P =0.05, df=18,5)
-------
DUNNETT'S TEST - TABLE 2 OF 2
Ho:Control
-------
YSI 6000 Time series
Date Time
mm/dd/yy hh:mm:ss
8/17/96 8 09:27
8/17/96 8 09:43
8/17/96 8 09:52
8/17/96 8 10:02
8/17/96 8 10:09
8/17/96 8 10:21
YSI 6000 Time Series
Date Time
mm/dd/YY hh:mm:ss
8/19/96 9:50:17
8/19/96 9:50:24
8/19/96 9:50:30
8/19/96 9:50:35
8/19/96 9:50:40
8/19/96 9:50:47
Report
Temp
c
24.44
24.52
24.56
24.59
24.59
24.62
Report
Temp
c
24.87
25.37
25.35
25.30
25.31
25.44
Cond
US /cm
304.00
322.00
338.00
366.00
429.00
552.00
Cond
US /cm
321.00
336.00
344.00
381.00
440.00
572.00
Salinity
PPT
0.2
0.2
0.2
0.2
0.2
0.3
Salinity
PPT
0.2
0.2
0.2
0.2
0.2
0.3
DO
mg/L
7.51
7.72
7.72
7.74
7.76
7.73
DO
mg/L
7.43
7.64
7.64
7.65
7.66
7.65
Page 1
PH
8.19
8.08
8.02
7.95
7.85
7.64
Page 1
PH
8.35
8.03
7.98
7.92
7.84
7.66
YSI 6000 Time Series Report
Date Time '.
mm/dd/YY hh:mm:ss
8/17/96 7:45:12
8/17/96 7:45:28
8/17/96 7:45:36
8/17/96 7:45:41
8/17/96 7:45:50
8/17/96 7:45:58
YSI 6000 Time Series Report
Date Time
mm/dd/YY hh:mm:ss
8/18/96 9:03:27
8/18/96 9:03:34
8/18/96 9:03:47
8/18/96 9:03:54
8/18/96 9:04:00
8/18/96 9:04:06
25.06
25.07
25.51
25.65
25.75
25.72
Temp
C
24.10
24.92
25.06
25.08
25.09
25.04
Page 1
'emp
c
25.06
25.07
25.51
25.65
25.75
25.72
Cond
US /cm
323.00
347.00
363.00
397.00
462.00
596.00
Salinity
PPT
0.2
0.2
0.2
0.2
0.2
0.3
DO
mg/L
7.12
6.84
6.51
6.31
6.00
5.60
PH
6.84
6.91
6.90
6.90
6.87
6.88
Page 1
Temp
C
24.10
24.92
25.06
25.08
25.09
25.04
cond
US /cm
345.00
349.00
367.00
391.00
454.00
576.00
Salinity
PPT
0.2
0.2
0.2
0.2
0.2
0.3
DO
mg/L
7.50
6.07
5.95
5.97
5.89
5.76
PH
8.48
8.14
7.98
7.90
7.85
7.77
-------
6000 Time series
Date Time
mm/dd/yy hh:mm:ss
8/19/96 9:19:44
8/19/96 9:19:54
8/19/96 9:20:00
8/19/96 9:20:06
8/19/96 9:20:11
8/19/96 9:20:17
Report
Temp
C
25.58
25.55
25.60
25.62
25.59
25.52
Cond
US /cm
346.00
367.00
382.00
398.00
454.00
585.00
Salinity
PPT
0.2
0.2
0.2
0.2
0.2
0.3
DO
mg/L
5.38
5.16
5.12
5.09
5.07
4.87
Page 1
PH
7.78
7.54
7.49
7.46
7.40
7.35
YSI 6000 Time Series Report
Date Time
mm/dd/yy hh:mm:ss
8/20/96 8:58:33
8/20/96 8:58:48
8/20/96 8:59:00
8/20/96 8:59:10
8/20/96 8:59:19
8/20/96 8:59:32
Page 1
Temp
C
24.61
24.75
24.78
24.76
24.71
24.60
Cond
US /cm
373.00
368.00
376.00
406.00
468.00
599.00
Salinity
PPT
0.2
0.2
0.2
0.2
0.2
0.3
DO
mg/L
6.31
5.77
5.78
5.48
5.20
4.98
PH
8.20
7.87
7.80
7.74
7.69
7.65
-------
CHRONIC BIOMONITORING REPORT
Chemsol Plant
Ceriodaphnia dubia
(Untreated)
BIEGLER ASSOCIATES
PO BOX 261
RIDGEFIELD PARK, NJ 07660
September 4,1996
JOB #96-294
TEST DESIGN
Number of Effluent Concentratiions: 5
Number of Replicates per Test Concentration: 10
Number of Tea Organism per Replicate: 1
Number of Test Organisms per Test Concentration: 10
Tea Chamber Size: 30 mL Exposure Volume: 15 mL
Explain any deviations from the specified testing methodology:
EFFLUENT SAMPLING
Plant Sampling Location:
Effluent Type:
Sample Type: 24 hour Composite x Other Describe:
Sample Collection Sample Data taken upon Use in Toxicity Test
arrival at laboratory
Beginning Ending D.O. pH Date(s) Time(s)
Date/Time Date/Time
8/11 - 8:00 am 8/12 - 8:00 am 6.7 7.3 8/13-14 11:30 am
8/13 - 8:00 am 9/14 - 8:00 am 5.7 7.2 8/15-16 11:10 am
8/15 - 8:00 am 8/16 - 8:00 am 6.0 7.4 8/17-18 9:30 am
Maximum holding time of any effluent sample 72 hrs.
Describe any pretreatment of the effluent sample:
Testing Location: On-site Mobile Laboratory
On-site Commercial Laboratory
Remote Laboratory x
DILUTION WATER
Effluent Receiving Water:
Dilution Water Source: 100% EPA Moderately Hard Reconstituted Water
Describe any adjustment to the dilution water:
If receiving water used as dilution water source, describe collection location and dates of collection:
-------
SUMMARY SHEET FOR THE CLADOCERAN
CERIODAPHNIA DUBIA TEST
Percent Effluent Mean Percent Mean Number of Young Percent of Females
Survial per Surviving Female with Third Brood
Control 100 18.0 70.0
6.25 100 24.0 100
12.5 100 21.8 77.8
25 100 24.6 90
50 100 21.8 60
100 100 27.0 80
Organism source: x Cultured Stock Commercial Supplier
Name of Supplier:
Organism Age at test start(hrs.): <24 hrs.
Test organisms all released with an 8 hour period? X Yes No
Neonates obtained from (check one):
Mass cultures
X individually cultured organisms
Was the test terminated when 60% of the surviving females in the controls had produced their third brood? x
Yes No
Within how many hours after test termination were the test organisms counted? Immediately
Number of Males/Ephippia
Percent Effluent Number of Males Number of Ephippia
Control 0
6.25 0
12.5 0
25 0
50 0
100 0
Did the number of males in the controls and/or test concentrationsl influence the determination of the
NOEC/IC25?
Yes No
499 Point Breeze Road D Flemington, New Jersey 08822 D Telephone (908)788-8700 FAX (908)788-9165
-------
A
P
P
E
N
D
I
X
FISHER'S EXACT TEST
IDENTIFICATION
CONTROL
6.25
TOTAL
CRITICAL FISHER'S VALUE (10,10,10) (p=0.05) IS 6. b VALUE IS 10.
Since b is greater than 6 there is no significant difference between CONTROL and TREATMENT at the 0.05 level.
NUMBER OF
ALIVE
10
10
20
DEAD
0
0
0
TOTAL ANIMALS
10
10
20
FISHER'S EXACT TEST
IDENTIFICATION
CONTROL
12.5
TOTAL
ALIVE
10
9
19
NUMBER OF
DEAD TOTAL ANIMALS
0 10
0 9
0 19
CRITICAL FISHER'S VALUE (10,9,10) (p=0.05) IS 5. b, VALUE IS 9.
Since b is greater than 5 there is no significant difference between CONTROL and TREATMENT at the 0.05 level.
-------
FISHER'S EXACT TEST
IDENTIFICATION
CONTROL
25
TOTAL
ALIVE
10
10
20
DEAD
0
0
0
NUMBER OF
TOTAL ANIMALS
10
10
20
CRITICAL FISHER'S VALUE (10,10,10) (p=0.05) IS 6. b VALUE IS 10.
Since b is greater than 6 there is no significant difference between CONTROL and TREATMENT at the 0.05 level.
FISHER'S EXACT TEST
IDENTIFICATION
CONTROL
50
TOTAL
NUMBER OF
ALIVE
10
10
20
DEAD
0
0
0
TOTAL ANIMALS
10
10
20
CRITICAL FISHER'S VALUE (10,10,10) (p=0.05) IS 6. b VALUE IS 10.
Since b is greater than 6 there is no significant difference between CONTROL and TREATMENT at the 0.05 level.
FISHER'S EXACT TEST
IDENTIFICATION
CONTROL
100
TOTAL
ALIVE
10
10
20
DEAD
0
0
0
NUMBER OF
TOTAL ANIMALS
10
10
20
CRITICAL FISHER'S VALUE (10,10,10) (p=0.05) IS 6. b VALUE IS 10.
Since b is greater than 6 there is no significant difference between CONTROL and TREATMENT at the 0.05 level.
-------
SUMMARY OF FISHER'S EXACT TESTS
GROUP
1
2
3
4
5
IDENTIFICATION
CONTROL
6.25
12.5
25
50
100
NUMBER
EXPOSED
10
10
9
10
10
10
DEAD
0
0
0
0
0
0
NUMBER
(P=.05)
SIG
Chi-square test for normality: actual and expected frequencies
INTERVAL <-1.5 -1.5 to <-0.5 -0.5 to 0.5 >0.5 to 1.5
EXPECTED
OBSERVED
3.953
7
14.278
10
22.538
20
14.278
22
3.953
0
Calculated Chi-Square, qoodness of fit test statistic = 12.0455
Table Chi-Square value (alpha =0.01) = 13.277
Data PASS normality test. Continue analysis.
Bartlett's test for homoqeneity of variance
Calculated Bl statistic = 17.16
Bartlett's test usinq averaqe deqrees of freedom
Calculated B2 statistic = 16.86
Based on averaqe replicate size of 8.83
Table Chi-square value = 15.09 (alpha = 0.01, df = 5)
Table Chi-square value = 11.07 (alpha - 0.05, df = 5)
Data FAIL Bl homoqeneity test at 0.01 level. Try another transformation.
Data FAIL B2 homoqeneity test at 0.01 level. Try another transformation.
-------
TITLE: Chemsol 96-2S4 untreated C. dubia Reproduction
FILE: 294ucdr
TRANSFORM: NO TRANSFORMATION NUMBER OF GROUPS: 6
GRP IDENTIFICATION
REP
VALUE
TRANS VALUE
Control
Control
Control
Control
Control
Control
Control
Control
Control
Control
6.25
6.25
6.25
6.25
6.25
6.25
6.25
6.25
6.25
6.25
12.5
12.5
12.5
12.5
12.5
12.5
12.5
12.5
12.5
25
25
25
25
25
25
25
25
25
25
25
50
50
50
50
50
50
50
50
50
100
100
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
22.
21.
20.
23.
12.
23.
16.
12.
22.
9.
26.
25.
25.
22.
21.
24.
21.
25.
26.
25.
24.
12.
13.
26.
24.
21.
23.
26.
27.
24.
23.
25.
21.
26.
22.
28.
22.
27.
28.
29.
22.
10.
24.
24.
26.
29.
25.
14.
15.
33.
28
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
.0000
22.
21.
20.
23.
12.
23.
16.
12.
22.
9.
26.
25.
25.
22.
21.
24.
21.
25.
26.
25.
24.
12.
13.
26.
24.
21.
23.
26.
27.
24.
23.
25.
21.
26.
22.
28.
22.
27.
28.
29.
22.
10.
24.
24.
26.
29.
25.
14.
15.
33.
28
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
.0000
-------
6
6
6
6
6
6
6
6
100
100
100
100
100
100
100
100
3
4
5
6
7
8
9
10
29.
28.
30.
29.
30.
10.
30.
23.
,0000
,0000
,0000
,0000
,0000
,0000
,0000
,0000
29.
28.
30.
29.
30.
10.
30.
23.
,0000
,0000
,0000
,0000
,0000
,0000
,0000
,0000
SUMMARY STATISTICS ON TRANSFORMED DATA TABLE 1 of 2
GRP IDENTIFICATION
MIN
MAX
MEAN
1
2
3
4
5
6
Control
6.25
12.5
25
50
100
10
10
9
10
10
10
9.000
21.000
12.000
21.000
10.000
10.000
23.000
26.000
27.000
28.000
29.000
33.000
18.000
24.000
21.778
24.600
21.800
27.000
SUMMARY STATISTICS ON TRANSFORMED DATA TABLE 2 of 2
GRP IDENTIFICATION
VARIANCE
SD
SEM
C.V.
1
2
3
4
5
6
Control
6.25
12.5
25
50
100
28.000
3.778
30.944
6.711
43.067
42.000
5.292
1.944
5.563
2.591
6.563
6.481
1.673
0.615
1.854
0.819
2.075
2.049
29.40
8.10
25.54
10.53
30.10
24.00
WILCOXON'S RANK SUM TEST W/ BONFERRONI ADJUSTMENT
TRANSFORMED
GROUP IDENTIFICATION MEAN
Ho:Control
-------
*** Inhibition Concentration Percentage Estimate
Toxicant/Effluent: Effluent
Test Start Date: 8/13/96 Test Ending Date: 8/19/96
Test Species: C. dubia
Test Duration: 6
Cone. Number
ID Replicates
10
10
9
10
10
10
Concentration
0.000
6.250
12.500
25.000
50.000
100.000
Response
Means
Std. Pooled
Dev. Response Means
18.000
24.000
21.778
24.600
21.800
27.000
5.292
1.944
5.563
2.591
6.563
6.481
22.881
22.881
22.881
22.881
22.881
22.881
*** No Linear Interpolation Estimate can be calculated from the input data since none of the (possibly
pooled) group response means were less than 75% of the control response mean.
YSI 6000 Time Series Report
Date Time Temp
mm/dd/yy hh:mm:ss C
8/15/96 10:03:59 24.09
8/15/96 10:04:11 24.88
8/15/96 10:04:18 24.91
8/15/96 10:04:24 24.95
8/15/96 10:04:30 25.00
8/15/96 10:04:37 25.08
Cond
US/cm
326.00
345.00
360.00
393.00
465.00
608.00
Salinity
PPT
0.3
Page
DO
mg/L
8.75
7.70
7.71
7.70
7.68
7.65
1
PH
8.46
7.90
7.86
7.79
7.68
7.52
YSI 6000 Time Series Report
Date Time
mm/dd/yy hh:mm:ss
8/17/96 8
8/17/96 8
8/17/96 8
8/17/96 8
8/17/96 8
8/17/96 8
09:27
09:43
09:52
10:02
10:09
10:21
Temp
C
24.44
24.52
24.56
24.59
24.59
24.62
Cond
US /cm
304.00
322.00
338.00
366.00
429.00
552.00
Salinity DO
PPT mg/L
Page 1
PH
0.2
0.2
0.2
0.2
0.2
0.3
7.51
7.72
7.72
7.74
7.76
7.73
8.19
8.08
8.02
7.95
7.85
7.64
-------
YSI 6000 Time Series Report
Date Time
mm/dd/yy hh:mm:ss
8/16/96 17:46:09
8/16/96 17:46:15
8/16/96 17:46:21
8/16/96 17:46:26
8/16/96 17:46:32
8/16/96 17:46:38
YSI 6000 Time Series Report
Date Time
mm/dd/yy hh:mm:ss
8/17/96 9:38:30
8/17/96 9:39:01
8/17/96 9:39:16
8/17/96 9:39:28
8/17/96 9:39:40
8/17/96 9:39:52
YSI 6000 Time Series Report
Date Time
mm/dd/yy hh:mm:ss
8/18/96 10:59:58
8/18/96 11:00:08
8/18/96 11:00:17
8/18/96 11:00:26
8/18/96 11:00:36
8/18/96 11:00:45
YSI 6000 Time Series Report
Date Time
mm/dd/yy hh:mm:ss
8/19/96 16:29:16
8/19/96 16.29:27
8/19/96 16:29:38
8/19/96 16:29:46
8/19/96 16:29:55
8/19/96 16:30:05
Temp
C
24.91
25.56
25.65
25.75
25.73
25.70
Temp
C
25.86
25.97
25.83
25.62
25.68
25.69
Temp
C
24.05
24.14
24.26
24.31
24.31
24.30
Temp
C
25.13
25.11
25.07
25.11
25.04
25.09
Temp
C
24.91
25.56
25.65
25.75
25.73
25.70
Temp
C
25.86
25.97
25.83
25.62
25.68
25.69
Cond Salinity
US /cm
402.00
418.00
431.00
463.00
532.00
674.00
Cond
US /cm
295.00
236.00
218.00
315.00
353.00
429.00
PPT
0.2
0.2
0.2
0.2
0.2
0.3
Salinity
PPT
0.1
0.1
0.1
0.2
0.2
0.2
DO
mg/L
7.89
7.80
7.79
7.78
7.81
7.82
DO
mg/L
7.50
7.26
7.23
7.16
7.44
7.14
Page 1
PH
7.98
7.95
7.94
7.92
7.93
7.96
Page 1
PH
7.92
7.81
7.81
7.75
7.75
7.85
Page 1
Temp
C
24.
24.
24.
24.
24.
24.
Cond
Salinity
US /cm
05
14
26
31
31
30
344.
366.
382.
407.
484.
608.
00
00
00
00
00
00
PPT
0,
0,
0,
0,
0,
0,
.2
.2
.2
.2
.2
.3
DO
PH
mg/L
7
7
7
7
7
7
.53
.51
.51
.53
.55
.57
7.
7.
7.
7.
7.
8.
,96
,92
,92
,93
,94
,02
Page 1
Temp
C
25.13
25.11
25.07
25.11
25.04
25.09
Cond
US /cm
368.00
393.00
401.00
418.00
481.00
613.00
Salinity
PPT
0.2
0.2
0.2
0.2
0.2
0.3
DO
mg/L
7.64
7.54
7.53
7.50
7.50
7.50
PH
8.01
7.99
7.98
7.98
7.99
8.03
-------
CHRONIC BIOMONITORING REPORT
Chemsol Plant
Pimephales promelas
(Treated)
BIEGLER ASSOCIATES
PO BOX 261
RIDGEFIELD PARK, NJ 07660
September 4, 1996
JOB #96-294
499 Point Breeze Road D Flemington, New Jersey 08822 D Telephone (908)788-8700 FAX (908)788-9165
-------
Number of Effluent Concentrations: 5
Number of Replicates per Test Concentration 4
Number of Test Organisms per Replicate: 10
Number of Test Organisms per Test Concentration: 40
Test Chamber Size: 1000 mL Exposure Volume: 500 mL
Explain any deviations from the specified testing methodology:
EFFLUENT SAMPLING
Plant Sampling Location:
Effluent Type:
Sample Type:
Sample Collection
24 hour Composite
Other
Sample Data taken upon
arrival at laboratory
Describe:
Use in Toxicity Test
Beginning
Date/Time
8/11 - 8:00 am
8/13 - 8:00 am
8/15 - 8:00 am
Ending D.O. pH
Date/Time
8/12 - 8:00 am 7.9 7.9
8/14 - 8:00 am 7.5 8.0
8/16 - 8:00 am 8.3 8.2
Date(s)
8/13-14
8/15-16
8/17-19
Time(s)
3:30 pm
3:00 pm
8:15 am
Maximum holding time of any effluent sample 72 hrs.
Describe any pretreatment of the effluent sample:
Testing Location: On-site Mobile Laboratory
On-site Commercial Laboratory
Remote Laboratory x
DILUTION WATER
Effluent Receiving Water:
Dilution Water Source: 100% EPA Moderately Hard Reconstituted Water
Describe any adjustment to the dilution water:
If receiving water used as dilution water source, describe collection location and dates of collection:
499 Point Breeze Road D Flemington New Jersey 08822 D Telephone (908)788-8700 FAX (908)788-9165
-------
SUMMARY SHEET FOR THE FATHEAD MINNOW, SHEEPSHEAD MINNOW,
INLAND SILVERSIDE AND MYSID TESTS
Percent Effluent Mean Percent Survival Mean Dry Weight Percent of Surviving
Females with Eggs
Control 97.5 0.457
6.25 97.5 0.560
12.5 100.0 0.515
25 100.0 0.618
50 92.5 0.605
100 92.5 0.678
Organism source: x Cultured Stock Commercial Supplier
Name of Supplier:
Hatch Dates: 8/12/96
Organism Age (days/hrs.): <24 hrs.
Describe any aeration which was performed during the test: No aeration was reguired during the test period.
Describe any adjustments to the salinity of the test concentrations:
How long after test termination were the organisms prepared for weighing/drying? immediately
Was the average dry weight per test chamber determined by dividing the final dry weight by the number of
original test organisms in the test chamber? X Yes No
Did the temperature in the test chambers vary by more than 15C each day?
X Yes No
Did the salinity in the test chambers vary more than 2ppt between replicates each day?
Yes No
*How long after test termination were the mysids examined for eggs and sexes?
*Applies to mysid test only
499 Point Breeze Road D Flemington, New Jersey 08822 D Telephone (908)788-8700 FAX(908)788-9165
-------
A
P
P
E
N
D
I
X
Shapiro - Wilk's test for normality
D = 0.125
W = 0.915
Critical W (P = 0.05) (n = 24) = 0.916
Critical W (P = 0.01) (n = 24) = 0.884
Data PASS normality test at P=0.01 level. Continue analysis.
Hartley's test for homogeneity of variance
Bartlett's test for homogeneity of variance
These two tests can not be performed because at least one group has zero variance.
Data FAIL to meet homogeneity of variance assumption.
Additional transformations are useless.
-------
TITLE: Chemsol 96-294 Treated P. promelas Survival
FILE: 294tpps
TRANSFORM: ARC SINE(SQUARE ROOT(Y))
NUMBER OF GROUPS: 6
GRP IDENTIFICATION
1 Control
1 Control
1 Control
1 Control
2 6.25
2 6.25
2 6.25
2 6.25
3 12.5
3 12.5
3 12.5
3 12.5
4 25
4 25
4 25
4 25
5 50
5 50
5 50
5 50
6 100
6 100
6 100
6 100
REP
1
2
3
4
1
2
3
4
1
2
3
4
1
2
3
4
1
2
3
4
1
2
3
4
SUMMARY STATISTICS ON TRANSFORMED
GRP IDENTIFICATION
1 Control
2 6.25
3 12.5
4 25
5 50
6 100
N
4
4
4
4
4
4
VALUE
1.
0,
1.
1.
1.
1.
0,
1.
1.
1.
1.
1.
1.
1.
1.
1.
0,
0,
0,
1.
0,
1.
0,
1.
DATA TABLE
MIN
1.249
1.249
1.412
1.412
1.249
1.107
.0000
.9000
.0000
.0000
.0000
.0000
.9000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.0000
.9000
.9000
.9000
.0000
.8000
.0000
.9000
.0000
1 of 2
MAX
1.412
1.412
1.412
1.412
1.412
1.412
TRANS VALUE
1.4120
1.2490
1.4120
1.4120
1.4120
1.4120
1.2490
1.4120
1.4120
1.4120
1.4120
1.4120
1.4120
1.4120
1.4120
1.4120
1.2490
1.2490
1.2490
1.4120
1.1071
1.4120
1.2490
1.4120
MEAN
1.371
1.371
1.412
1.412
1.290
1.295
-------
SUMMARY STATISTICS ON TRANSFORMED DATA TABLE 2 of 2
GRP IDENTIFICATION VARIANCE
1 Control 0.007
2 6.25 0.007
3 12.5 0.000
4 25 0.000
5 50 0.007
6 100 0.022
STEEL'S MANY-ONE RANK TEST Ho:
SD
0.081
0.081
0.000
0.000
0.081
0.147
SEM
0.041
0.041
0.000
0.000
0.041
0.073
C.V. %
5.94
5.94
0.00
0.00
6.32
11.35
: Control
-------
Shapiro - Wilk's test for normality
D = 0.058
W = 0.930
Critical W (P = 0.05) (n = 24)
Critical W (P - 0.01) (n = 24)
0.916
0.884
Data PASS normality test at P=0.01 level. Continue analysis.
Bartlett's test for homogeneity of variance
Calculated Bl statistic = 1.78
Table Chi-square value = 15.09 (alpha = 0.01, df = 5)
Table Chi-square value = 11.07 (alpha = 0.05, df = 5)
Data PASS Bl homoqeneity test at 0.01 level. Continue analysis.
TRANSFORM: NO TRANSFORMATION NUMBER OF GROUPS: 6
GRP IDENTIFICATION
1
1
1
1
2
2
2
2
3
3
3
3
4
4
4
4
5
5
5
5
6
6
6
6
Control
control
Control
Control
6.25
6.25
6.25
6.25
12.5
12.5
12.5
12.5
25
25
25
25
50
50
50
50
100
100
100
100
REP
1
2
3
4
1
2
3
4
1
2
3
4
1
2
3
4
1
2
3
4
1
2
3
4
VALUE
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
.4100
.4400
.4900
.4900
.5800
.4800
.5800
.6000
.4800
.4400
.6000
.5400
.5500
.6600
.6400
.6200
.6200
.5400
.6400
.6200
.6400
.7300
.7500
.5900
TRANS VALUE
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
.4100
.4400
.4900
.4900
.5800
.4800
.5800
.6000
.4800
.4400
.6000
.5400
.5500
.6600
.6400
.6200
.6200
.5400
.6400
.6200
.6400
.7300
.7500
.5900
SUMMARY STATISTICS ON TRANSFORMED DATA TABLE 1 of 2
-------
GRP IDENTIFICATION
MIN
MAX
MEAN
1
2
3
4
5
6
Control
6.25
12.5
25
50
100
4
4
4
4
4
4
0
0
0
0
0
0
.410
.480
.440
.550
.540
.590
0
0
0
0
0
0
.490
.600
.600
.660
.640
.750
0,
0,
0,
0,
0,
0,
.457
.560
.515
.618
.605
.678
SUMMARY STATISTICS ON TRANSFORMED DATA TABLE 2 of 2
GRP IDENTIFICATION
VARIANCE
SD
SEM
C.V.
1
2
3
4
5
6
Control
6.25
12.5
25
50
100
0
0
0
0
0
0
.002
.003
.005
.002
.002
.006
0,
0,
0,
0,
0,
0,
.039
.054
.070
.048
.044
.075
0.
0.
0.
0.
0.
0.
,020
,027
,035
,024
,022
,038
8
9
13
7
7
11
.63
.67
.59
.75
.33
.14
ANOVA TABLE
SOURCE
Between
Within (Error)
Total
DF
5
18
23
SS
0.
0.
0.
,123
,058
,181
MS F
0.025 7.642
0.003
Critical F value = 2.77 (0.05,5,18)
Since P > Critical F REJECT Ho: All equal
DUNNETT'S TEST - TABLE 1 OF 2
Ho:Control
-------
1
2
3
4
5
6
Cone. ID
Cone. Tested
Response 1
Response 2
Response 3
Response 4
Control
6.25
12.5
25
50
100
1
0
.41
.44
.49
.49
4
4
4
4
4
4
2
6.25
.58
.48
.58
.60
0.097 21.1
0.097 21.1
0.097 21.1
0.097 21.1
0.097 21.1
345
12.5 25 50
.48 .55 .62
.44 .66 .54
.60 .64 .64
.54 .62 .62
-0.103
-0.058
-0.160
-0.148
-0.220
6
100
.64
.73
.75
.59
*** Inhibition Concentration Percentage Estimate ***
Toxicant/Effluent: Effluent
Test Start Date: 8/13/96 Test Ending Date: 8/20/96
Test Species: P. promelas
Test Duration: 7 day
DATA FILE: 294tppdw.icp
Cone. Number
ID Replicates
1
2
3
4
5
6
4
4
4
4
4
4
Concentration
%
0.
6.
12.
25.
50.
100.
000
250
500
000
000
000
Response
Means
0
0
0
0
0
0
.457
.560
.515
.618
.605
.678
Std. Pooled
Dev. Response Means
0.
0.
0.
0.
0.
0.
,039
,054
,070
,048
,044
,075
0,
0,
0,
0,
0,
0,
.572
.572
.572
.572
.572
.572
*** No Linear Interpolation Estimate can be calculated from the input data since none of the (possibly
pooled) group response means were less than 75% of the control response mean.
98141L>
98141L1>
98141L2>
98141L3>
98141L4>
98141L5>
98141L6>
98141L7>
-------
YSI 6000 Time Series Report
Page 1
Date
mm/dd/yy
8/17/96
8/17/96
8/17/96
8/17/96
8/17/96
8/17/96
YSI 6000 Time
Date
mm/dd/yy
8/18/96
8/18/96
8/18/96
8/18/96
8118196
8/18/96
YSI 6000 Time
Date
mm/dd/yy
8/19/96
8/19/96
8/19/96
8/19/96
8/19/96
8/19/96
8/19/96
YSI 6000 Time
Date
mm/dd/yy
8/20/96
8/20/96
8/20/96
8/20/96
8/20/96
8/20/96
Time
hh:mm
7:46
7:46
7:46
7:46
7:47
7:47
:
:
:
:
:
:
:
Series
ss
33
40
48
56
10
17
Report
Time
hh:mm
8:51
8:51
8:51
8:51
8:51
8:51
:
:
:
:
:
:
:
Series
ss
20
27
33
40
47
53
Report
Time
hh:mm
9:15
9:15
9:16
9:16
9:17
9:17
9:18
:
:
:
:
:
:
:
:
Series
Time
hh:mm
9:00
9:00
9:00
9:01
9:01
9:01
:
;
:
:
:
:
:
ss
24
55
14
35
25
45
42
Report
ss
33
45
57
09
24
37
Temp
C
24.
25.
25.
25.
25.
25.
54
15
40
58
74
76
Temp
C
24
24
24
24
24
24
.16
.42
.58
.76
.84
.88
Temp
C
25
26
24
24
24
24
25
Temp
C
24.50
24.57
24.63
24.65
24.70
24.75
.31
.95
.92
.99
.32
.43
.43
Cond
uS/CM
318.00
347.00
364.00
393.00
460.00
589.00
Cond
uS/cm
326.00
346.00
359.00
385.00
453.00
581.00
Cond
uS/cm
378.00
389.00
391.00
407.00
467.00
602.00
345.00
Cond
uS/cm
352.00
365.00
387.00
408.00
475.00
616.00
Salinity
PPT
0.2
0.2
0.2
0.2
0.2
0.3
Salinity
PPT
0.2
0.2
0.2
0.2
0.2
0.3
Salinity
PPT
0.2
0.2
0.2
0.2
0.2
0.3
0.2
Salinity
PPT
0.2
0.2
0.2
0.2
0.2
0.3
DO
pH
mg/L
7.
6.
6.
5.
5.
5.
DO
mg/L
7.29
6.54
6.72
6.63
6.42
6.47
DO
mg/L
6.63
6.92
7.50
7.22
7.27
6.81
5.44
DO
mg/L
6.00
5.92
5.74
5.80
5.83
6.07
35
08
03
68
47
38
Page
Page 1
PH
7.
7.
8.
8.
8.
7.
7.
Page
PH
7.
7.
7.
7.
7.
7.
7.
7.
7.
7.
7.
7.
1
PH
7.21
7.12
7.11
7.10
7.10
7.15
93
84
11
10
08
97
89
1
83
72
66
62
63
70
39
27
21
15
14
19
-------
CHROMC BIOMONITORING REPORT
Chemsol Plant
Ceriodaphnia dubia
(Treated)
BIEGLER ASSOCIATES
PO BOX 261
R1DGEFIELD PARK. NJ 07660
September 4, 1996
JOB #96-294
499 Point Breeze Road D Flemington, New Jersey 08822 D Telephone(908)788-8700 FAX(908)788-9165
-------
SUMMARY SHEET FOR THE CLADOCERAN
CERIODAPHNIA DUBIA TEST
Percent Effluent Mean Percent Mean Number of Young
per Surviving Female
23.7
21.6
20.4
19.1
0
0
x Cultured Stock
<24 hrs.
Test organisms all released with an 8 hour period? xYes
Control
6.25
12.5
25
50
100
Survival
100
100
100
100
0
0
Organism source:
Name of Supplier:
Organism Age at test start (hrs.):
Percent of Females
with Third Brood
70
100
70
70
0
0
Commercial Supplier
No
Neonates obtained from (check one):
Mass cultures
x individually cultured organisms
Was the test terminated when 60% of the surviving females in the controls had produced their third brood?
xYes No
Within how many hours after test termination were the test organisms counted? Immediately
Number of Males/Ephippla
Percent Effluent.
Control
6.25
12.5
25
50
100
Number of Males
0
0
0
0
0
0
Number of Ephippia
Did the number of males in the controls and/or test concentrations], influence the determination of the
NOEC/IC25?
Yes x No
499 Point Breeze Road DFlemington. New Jersey 08822 D Telephone (908)788-8700 FAX(908)788-9165
-------
A
P
P
E
N
D
I
X
FISHER'S EXACT TEST
NUMBER OF
IDENTIFICATION ALIVE DEAD TOTAL ANIMALS
CONTROL 10 0 10
6.25, 12.5, 25 10 0 10
TOTAL 20 0 20
CRITICAL FISHER'S VALUE (10,10,10) (p=0.05) IS 6. b VALUE IS 10.
Since b is greater than 6 there is no significant difference between CONTROL and TREATMENT at the 0.05 level.
FISHER'S EXACT TEST
NUMBER OF
IDENTIFICATION ALIVE DEAD TOTAL ANIMALS
CONTROL 10 0 10
50,100 0 10 10
TOTAL 10 10 20
CRITICAL FISHER'S VALUE (10,10,10) (p=0.05) IS 6. b VALUE IS 0.
Since b is less than or egual to 6 there is a significant difference between CONTROL and TREATMENT at the
0.05 level.
-------
SUMMARY OF FISHER'S EXACT TESTS
NUMBER NUMBER SIG
GROUP IDENTIFICATION EXPOSED DEAD (P=.05)
CONTROL 10 0
1 6.25, 12.5, 25 10 0
2 50,100 10 10
Chi-square test for normality: actual and expected frequencies
INTERVAL <-1.5 -1.5 to <-0.5 -0.5 to 0.5 >0.5 to 1.5 >1.5
EXPECTED 2.680 9.680 15.280 9.680 2.680
OBSERVED 38 13 15 1
Calculated Chi-Square qoodness of fit test statistic = 4.6469
Table Chi-Square value (alpha - 0.01) = 13.277
Data PASS normality test. Continue analysis.
Bartlett's test for homoqeneity of variance
Calculated Bl statistic = 5.25
Table Chi-square value = 11.34 (alpha = 0.01, df = 3)
Table Chi-square value = 7.81 (alpha = 0.05, df = 3)
Data PASS Bl homoqeneity test at 0.01 level. Continue analysis.
-------
TRANSFORM:
NO TRANSFORMATION
NUMBER OF GROUPS: 4
GRP
1
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
3
4
4
4
4
4
4
4
4
4
4
SUMMARY
GRP
1
2
3
4
IDENTIFICATION
Control
Control
Control
Control
Control
Control
Control
Control
Control
Control
6.25
6.25
6.25
6.25
6.25
6.25
6.25
6.25
6.25
6.25
12.5
12.5
12.5
12.5
12.5
12.5
12.5
12.5
12.5
12.5
25
25
25
25
25
25
25
25
25
25
REP
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
STATISTICS ON TRANSFORMED
IDENTIFICATION
Control
6.25
12.5
25
N
10
10
10
10
VALUE TRANS VALUE
24.0000
22.0000
21.0000
26.0000
30.0000
26.0000
24.0000
23.0000
17.0000
24.0000
26.0000
24.0000
21.0000
16.0000
22.0000
20.0000
22.0000
19.0000
25.0000
21.0000
24.0000
10.0000
14.0000
21.0000
25.0000
25.0000
22.0000
24.0000
26.0000
13.0000
22.0000
21.0000
15.0000
15.0000
23.0000
14.0000
22.0000
22.0000
18.0000
19.0000
DATA TABLE 1 of 2
MIN MAX MEAN
17.000 30.000 23.700
16.000 26.000 21.600
10.000 26.000 20.400
14.000 23.000 19.100
24.0000
22.0000
21.0000
26.0000
30.0000
26.0000
24.0000
23.0000
17.0000
24.0000
26.0000
24.0000
21.0000
16.0000
22.0000
20.0000
22.0000
19.0000
25.0000
21.0000
24.0000
10.0000
14.0000
21.0000
25.0000
25.0000
22.0000
24.0000
26.0000
13.0000
22.0000
21.0000
15.0000
15.0000
23.0000
14.0000
22.0000
22.0000
18.0000
19.0000
-------
SUMMARY STATISTICS ON TRANSFORMED DATA TABLE 2 of 2
GRP
1
2
3
4
IDENTIFICATION
Control
6.25
12.5
25
VARIANCE
11
8
34
11
.789
.711
.044
.656
3
2
5
3
SD
.433
.951
.835
.414
SEM
1.
0.
1.
1.
,086
,933
,845
,080
C
14
13
28
17
.V. %
.49
.66
.60
.87
-------
ANOVA TABLE
SOURCE
Between
Within (Error)
Total
Critical F value =
since F < Critical
DUNNETT'S TEST -
DF
3
36
39
2.92 (0.05,
F FAIL TO
TABLE 1
SS
114.600
595.800
710.400
3,30)
REJECT Ho:
OF 2
MS F
38.200 2.308
16.550
All equal
Ho : Control
-------
*** Inhibition Concentration Percentage Estimate ***
Toxicant/Effluent: Effluent
Test Start Date: 8/13/96 Test Ending Date: 8/19/96
Test Species: C. dubia.
Test Duration: 6 day
DATA FILE: 294tcdr.icp
Cone.
ID
1
2
3
4
5
6
Number
Replicates
10
10
10
10
10
10
Concentration
%
0.
6.
12.
25.
50.
100.
000
250
500
000
000
000
Response
Means
23.
21.
20.
19.
0.
0.
700
600
400
100
000
000
Std. Pooled
Dev. Response Means
3.
2.
5.
3.
0.
0.
,433
,951
,835
,414
,000
,000
23.
21.
20.
19.
0.
0.
,700
,600
,400
,100
,000
,000
The Linear Interpolation Estimate:
26.7343
Entered P Value: 25
Number of Resamplings: 1000
The Bootstrap Estimates Mean:
Original Confidence Limits:
Resampling time in Seconds:
25.7205 Standard Deviation: 3.6508
Lower: 11.7647 Upper: 29.2079
1.43 Random Seed: 511093648
98141M7>
98141M8>
98141M9>
98141N>
98141N1>
98141N2>
98141N3>
YSI 6000 Time Series Report
Page 1
Date Time
mm/dd/yy hh:mm:ss
8/16/96 17:45:11
8/16/96 17:45:17
8/16/96 17:45:24
8/16/96 17:45:30
Temp
c
24.65
25.30
25.48
25.54
Cond
uS/cm
383.00
398.00
419.00
451.00
Salinity
PPT
0.2
0.2
0.2
0.2
DO
mg/L
7.79
7.72
7.72
7.72
PH
7.76
7.79
7.83
7.84
YSI 6000 Time Series Report
Page 1
Date Time
mm/dd/yy hh:mm:ss
8/17/96 9:27:21
8/17/96 9:27:53
8/17/96 9:28:08
8/17/96 9:28:21
Temp
c
25.06
25.35
25.95
25.22
Cond
uS/cm
212.00
284.00
229.00
368.00
Salinity
PPT
0.1
0.1
0.1
0.2
DO
mg/L
6.64
7.63
7.38
7.67
PH
7.71
7.78
7.75
7.76
-------
YSI 6000 Time Series Report
Date Time
mm/dd/yy hh:mm:ss
8/18/96 10:57:29
8/18/96 10:57:43
8/18/96 10:57:51
8/18/96 10:58:02
YSI 6000 Time Series Report
Date Time
mm/dd/YY hh:mm:ss
8/19/96 17:04:00
8/19/96 17:04:10
8/19/96 17:04:17
8/19/96 17:04:24
Temp
c
24.10
24.27
24.33
24.32
Temp
c
24.47
25.03
24.45
24.20
Page 1
Temp
c
24.10
24.27
24.33
24.32
Cond
uS/cm
334.00
371.00
380.00
409.00
Salinity
PPT
0.2
0.2
0.2
0.2
DO
mg/L
7.41
7.38
7.40
7.46
PH
8.03
7.95
7.94
7.94
Page 1
Temp
c
24.47
25.03
24.45
24.20
Cond
uS/cm
382.00
378.00
404.00
420.00
Salinity
PPT
0.2
0.2
0.2
0.2
DO
mg/L
7.20
7.15
7.25
7.31
PH
8.29
8.18
8.14
8.11
-------
CHRONIC BIOMONITORING REPORT
Chemsol Plant
Pimephales promelas
(Final)
BIEGLER ASSOCIATES
PO BOX 261
RIDGEFIELD PARK, NJ 07660
December 20, 1996
JOB #96-424
5
4
10
40
TEST DESIGN
Number of Effluent Concentrations:
Number of Replicates per Test Concentration:
Number of Test Organisms per Replicate:
Number of Test Organism per Test Concentration:
Test Chamber Size: 1000 inL
Explain any deviations from the specified testing methodology:
EFFLUENT SAMPLING
Plant Sampling Location: Final effluent hose
Effluent Type: Final
Sample Type: 24 hour Composite x Other
Sample Collection
Exposure Volume: 500 inL
Beginning
Date/Time
11/17 - 9:00 am
11/19 - 9:00 am
11/21 - 9:00 am
Sample Data taken upon
arrival at laboratory
Ending D.0. pH
Date/Time
11/18 - 9:00 am 7.5 7.9
11/20 - 9:00 am 5.6 7.3
11/22 - 9:00 am 8.1 7.4
Describe: _
Use in Toxicity Test
Date(s)
Time(s)
11/19-20 11:15 am
11/21-22 1:15 pm
11/23-25 11:40 am
Maximum holding time of any effluent sample 72 hrs.
Describe any pretreatment of the effluent sample:_
Testing Location: On-site Mobile Laboratory_
On-site Commercial Laboratory_
Remote Laboratory x
-------
DILUTION WATER
Effluent Receiving Water:
Dilution Water Source: 100% EPA Moderately Hard Reconstituted Water
Describe any adjustment to the dilution water:
If receiving water used as dilution water source, describe collection location and dates of collection:
499 Point Breeze Road 6 Flemington, New Jersey 08822 6 Telephone (908)788-8700 FAX(908)788-9165
-------
SUMMARY SHEET FOR THE FATHEAD MINNOW, SHEEPSHEAD MINNOW, INLAND SILVERSIDE, AND MYSID TESTS
Percent Effluent Mean Percent Survival Mean Dry Weight Percent of Surviving
Females with Eggs
Control 100.0 0.378
6.25 95.0 0.378
12.5 95.0 0.375
25 100.0 0.468
50 97.5 0.488
100 90.0 0.420
Organism source: x Cultured Stock _Commercial Supplier
Name of Supplier:
Hatch Dates: 11/18/96;1650
Organism Age (days/hrs.): <24 hrs.
Describe any aeration which was performed during the test: No aeration was reguired during the test period.
Describe any adjustments to the salinity of the test concentrations:
How long after test termination were the organisms prepared for weighing/drying? immediately
Was the average dry weight per test chamber determined by dividing the final dry weight by the number of
original test organisms in the test chamber? X Yes _No
Did the temperature in the test chambers vary by more than 15C each day?
_Yes X No
Did the salinity in the test chambers vary more than 2ppt between replicates each day?
_Yes _No
*How long after test termination were the mysids examined for eggs and sexes? _
*Applies to mysid test only
499 Point Breeze Road 6 Flemington, New Jersey 08822 6 Telephone (908)788-8700 FAX(908)788-9165
-------
A
P
P
E
N
D
I
X
SRC 9814101>
SRC 9814102>
SRC 9814102A>
TRANSFORM: ARC SINE
GRP
1
1
1
1
2
2
2
2
3
3
3
3
4
4
4
4
5
5
5
5
6
6
6
6
IDENTIFICATION
control
control
control
control
6.25
6.25
6.25
6.25
12.5
12.5
12.5
12.5
25
25
25
25
50
50
50
50
100
100
100
100
( SQUARE
REP
1
2
3
4
1
2
3
4
1
2
3
4
1
2
3
4
1
2
3
4
1
2
3
4
ROOT (Y) )
VALUE
1.0000
1.0000
1.0000
1.0000
0.9000
1.0000
0.9000
1.0000
0.9000
1.0000
1.0000
0.9000
1.0000
1.0000
1.0000
1.0000
0.9000
1.0000
1.0000
1.0000
0.8000
0.9000
0.9000
1.0000
NUMBER OF GROUPS: 6
TRANS VALUE
1.4120
1.4120
1.4120
1.4120
1.2490
1.4120
1.2490
1.4120
1.2490
1.4120
1.4120
1.2490
1.4120
1.4120
1.4120
1.4120
1.2490
1.4120
1.4120
1.4120
1.1071
1.2490
1.2490
1.4120
-------
SUMMARY STATISTICS ON TRANSFORMED DATA TABLE 1 of 2
GRP IDENTIFICATION
MIN
MAX
MEAN
1
2
3
4
5
6
control
6.25
12.5
25
50
100
4
4
4
4
4
4
1
1
1
1
1
1
.412
.249
.249
.412
.249
.107
1.
1.
1.
1.
1.
1.
,412
,412
,412
,412
,412
,412
1
1
1
1
1
1
.412
.331
.331
.412
.371
.254
SUMMARY STATISTICS ON TRANSFORMED DATA TABLE 2 of 2
GRP IDENTIFICATION
VARIANCE
SD
SEM
C.V.
1
2
3
4
5
6
control
6.25
12.5
25
50
100
0.
0.
0.
0.
0.
0.
000
009
009
000
007
016
0.
0.
0.
0.
0.
0.
,000
,094
,094
,000
,081
,125
0
0
0
0
0
0
.000
.047
.047
.000
.041
.062
0.
7.
7.
0.
5.
9.
00
07
07
00
94
93
STEEL'S MANY-ONE RANK TEST
Ho:Control
-------
Table Chi-square value = 15.09 (alpha = 0.01, df = 5)
Table Chi-square value = 11.07 (alpha =0.05, df = 5)
Data PASS Bl homoqeneity test at 0.01 level. Continue analysis.
TRANSFORM: NO TRANSFORMATION NUMBER OF GROUPS: 6
GRP IDENTIFICATION
REP
VALUE
TRANS VALUE
control
control
control
control
6.25
6.25
6.25
6.25
12.5
12.5
12.5
12.5
25
25
25
25
50
50
50
50
100
100
100
100
0.4300
0.3800
0.3000
0.4000
0.3000
0.3900
0.3800
0.4400
0.3500
0.4500
0.3700
0.3300
0.4400
0.5100
0.4600
0.4600
0.5100
0.4700
0.5100
0.4600
0.3600
0.3800
0.4500
0.4900
0.4300
0.3800
0.3000
0.4000
0.3000
0.3900
0.3800
0.4400
0.3500
0.4500
0.3700
0.3300
0.4400
0.5100
0.4600
0.4600
0.5100
0.4700
0.5100
0.4600
0.3600
0.3800
0.4500
0.4900
SUMMARY STATISTICS ON TRANSFORMED DATA TABLE 1 of 2
GRP IDENTIFICATION N MIN MAX MEAN
1 control 4 0.300 0.430 0.378
2 6.25 4 0.300 0.440 0.378
3 12.5 4 0.330 0.450 0.375
4 25 4 0.440 0.510 0.468
5 50 4 0.460 0.510 0.488
6 100 4 0.360 0.490 0.420
SUMMARY STATISTICS ON TRANSFORMED DATA TABLE 2 of 2
GRP IDENTIFICATION VARIANCE SD SEM C.V. %
1 control 0.003 0.056 0.028 14.73
-------
2
3
4
5
6
6.25
12.5
25
50
100
0.003
0.003
0.001
0.001
0.004
0.058
0.053
0.030
0.026
0.061
0.029
0.026
0.015
0.013
0.030
15.35
14.03
6.39
5.39
14.42
ANOVA TABLE
SOURCE
Between
Within (Error)
Total
DF
5
18
23
SS MS F
0.050 0.010 4.118
0.043 0.002
0.093
Critical F value = 2.77 (0.05,5,18)
Since F > Critical F REJECT Ho: All equal
DUNNETT'S TEST - TABLE 1 OF 2
Ho:Control
-------
r** Inhibition Concentration Percentage Estimate ***
Toxicant/Effluent: 96-424
Test Start Date: 11/19/96 Test Ending Date: 11/26/96
Test Species: P.promelas
Test Duration: 7 days
DATA FILE: 96424p.icp
Cone.
ID
1
2
3
4
5
6
Number
Replicates
4
4
4
4
4
4
Concentration
%
0.
6.
12.
25.
50.
100.
000
250
500
000
000
000
Response
Means
0,
0,
0,
0,
0,
0,
.378
.378
.375
.468
.488
.420
Std. Pooled
Dev. Response Means
0
0
0
0
0
0
.056
.058
.053
.030
.026
.061
0
0
0
0
0
0
.418
.418
.418
.418
.418
.418
** No Linear Interpolation Estimate can be calculated from the Input data since none of the (possibly pooled)
group response means were less than 75% of the control response mean.
9814104>
9814105>
9814106>
9814107>
9814108>
9814109>
98141P>
98141P1>
98141P2>
98141P3>
98141P4>
98141P5>
98141P6>
-------
CHRONIC BIOMONITORING REPORT
Chemsol Plant
Ceriodaphnia dubia
(Final)
BIEGLER ASSOCIATES
PO BOX 261
RIDGEFIELD PARK, NJ 07660
December 20,1996
JOB #96-424
TEST DESIGN
Number of Effluent Concentrations: 5
Number of Replicates per Test Concentration: 10
Number of Test Organisms per Replicate: 1
Number of Test Organisms per Test Concentration: 10
Test Chamber Size: 30 mL Exposure Volume: 15 mL
Explain any deviations from the specified testing methodology:
EFFLUENT SAMPLING
Plant Sampling Location: Final effluent hose
Effluent Type: Final
Sample Type: 24 hour Composite x Other Describe:
Sample Collection
Beginning Ending
Date/Time Date/Time
11/17- 9:00 am 11/18- 9:00 am
11/19- 9:00 am 11/20- 9:00 am
11/21- 9:00 am 11/22- 9:00 am
Sample Data taken upon
arrival at laboratory
Use in Toxicity Test
D.O.
7.5
5.6
8.1
PH
7.9
7.3
7.4
Date(s)
11/19-20
11/21-22
11/23-24
Time(s)
11:15 am
11:40 am
8:55 am
Maximum holding time of any effluent sample 72 hrs.
Describe any pretreatment of the effluent sample:
Testing Location: On-site Mobile Laboratory
On-site Commercial Laboratory
Remote Laboratory x
-------
DILUTION WATER
Effluent Receiving Water
Dilution Water Source: 100% EPA Moderately Hard Reconsituted Water
Describe any adjustment to the dilution water:
If receiving water used as dilution water source, describe collection location and dates of collection:
499 Point Breeze Road D Flemington, New Jersey 08822 D Telephone (908) 788- 8700 FAX(908) 788- 9165
-------
SUMMARY SHEET FOR THE CLADOCERAN
CERIODAPHNIA DUBIA TEST
Percent Effluent Mean Percent Mean Number of Young Percent of Females
Survival per Surviving Female with Third Brood
Control 100 14.7 70.0
6.25 90 16.4 70
12.5 100 15.5 90
25 100 15.3 100
50 100 16.7 60
100 100 15.5 60
Organism source: x Cultured Stock Commercial Supplier
Name of Supplier:
Organism Age at test start (hrs.): <24 hrs. 11/18/96; 1130
Test organisms all released with an 8 hour period? X Yes No
Neonates obtained from (check one):
Mass cultures
x individually cultured organisms
Was the test terminated when 60% of the surviving females in the controls had produced their third brood? x
Yes No
Within how many hours after test termination were the test organisms counted? Immediately
Number of Males/Ephippia
Percent Effluent Number of Males Number of Ephippia
Control 0
6.25 0
12.5 0
25 0
50 0
100 0
Did the number of males in the controls and/or test concentrationsl influence die determination of the
NOEC/IC25?
Yes x No
499 Point Breeze Road D Flemington, New Jersey 08822 D Telephone (908)788-8700 FAX(908)788-9165
-------
A
P
P
E
N
D
I
X
FISHER'S EXACT TEST
IDENTIFICATION
CONTROL
6.25
TOTAL
ALIVE
10
9
19
DEAD
0
1
1
NUMBER OF
TOTAL ANIMALS
10
10
20
CRITICAL FISHER'S VALUE (10,10,10) (p=0.05) IS 6. b VALUE IS 9.
Since b is greater than 6 there is no significant difference between CONTROL and TREATMENT at the 0.05 level.
FISHER'S EXACT TEST
IDENTIFICATION
CONTROL
12.5, 25, 50, 100
TOTAL
ALIVE
10
10
20
DEAD
0
0
0
NUMBER OF
TOTAL ANIMALS
10
10
20
CRITICAL FISHER'S VALUE (10,10,10) (p=0-05) IS 6. b VALUE IS 10.
Since b is greater than 6 there is no significant difference between CONTROL and TREATMENT at the 0.05 level.
-------
SUMMARY OF FISHER'S EXACT TESTS
GROUP
IDENTIFICATION
CONTROL
1 6.25
2 12.5, 25, 50, 100
NUMBER
EXPOSED
10
10
10
NUMBER
DEAD
0
1
0
SIG
(P=05)
Chi-square test for normality: actual and expected frequencies
INTERVAL <-1.5 -1.5 to <-0.5 -0.5 to 0.5 >0.5 to 1.5
EXPECTED
OBSERVED
4.020
0
14.520
22
22.920
20
14.520
11
4.020
7
Calculated Chi-Square qoodness of fit test statistic = 11.3077
Table Chi-Square value (alpha =0.01) = 13.277
Data PASS normality test. Continue analysis.
Bartlett's test for homoqeneity of variance
Calculated Bl statistic = 0.46
Table Chi-square value = 15.09 (alpha = 0.01, df = 5)
Table Chi-square value = 11.07 (alpha = 0.05, df = 5)
Data PASS BI homoqeneity test at 0.01 level. Continue analysis.
TRANSFORM: NO TRANSFORMATION NUMBER OF GROUPS: 6
'ICATION
control
control
control
control
control
control
control
control
control
control
6.25
6.25
6.25
6.25
6.25
6.25
6.25
6.25
6.25
6.25
12.5
12.5
12.5
12.5
12.5
REP
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
VALUE
24.0000
11.0000
10.0000
15.0000
12.0000
9.0000
12.0000
19.0000
22.0000
13.0000
9.0000
13.0000
13.0000
26.0000
13.0000
23.0000
25.0000
14.0000
12.0000
10.0000
10.0000
12.0000
10.0000
21.0000
15.0000
TRANS VALUE
24.0000
11.0000
10.0000
15.0000
12.0000
9.0000
12.0000
19.0000
22.0000
13.0000
9.0000
13.0000
13.0000
26.0000
13.0000
23.0000
25.0000
14.0000
12.0000
10.0000
10.0000
12.0000
10.0000
21.0000
15.0000
-------
3
3
3
3
3
4
4
4
4
4
4
4
4
4
4
5
5
5
5
5
5
5
5
5
5
6
6
6
6
6
6
6
6
6
6
12.5
12.5
12.5
12.5
12.5
25
25
25
25
25
25
25
25
25
25
50
50
50
50
50
50
50
50
50
50
100
100
100
100
100
100
100
100-
100
100
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
1
2
3
4
5
6
7
8
9
10
16.0000
13.0000
11.0000
25.0000
22.0000
10.0000
13.0000
17.0000
24.0000
12.0000
14.0000
12.0000
12.0000
13.0000
26.0000
21.0000
15.0000
17.0000
14.0000
14.0000
11.0000
23.0000
10.0000
28.0000
14.0000
7.0000
19.0000
12.0000
21.0000
18.0000
25.0000
14.0000
10.0000
9.0000
20.0000
16.0000
13.0000
11.0000
25.0000
22.0000
10.0000
13.0000
17.0000
24.0000
12.0000
14.0000
12.0000
12.0000
13.0000
26.0000
21.0000
15.0000
17.0000
14.0000
14.0000
11.0000
23.0000
10.0000
28.0000
14.0000
7.0000
19.0000
12.0000
21.0000
18.0000
25.0000
14.0000
10.0000
9.0000
20.0000
-------
control
6.25
12.5
25
50
100
10
10
10
10
10
10
9.000
9.000
10.000
10.000
10.000
7.000
24.000
26.000
25.000
26.000
28.000
25.000
14.700
15.800
15.500
15.300
16.700
15.500
27.122
40.178
29.167
29.567
32.011
35.389
5.208
6.339
5.401
5.438
5.658
5.949
1.647
2.004
1.708
1.719
1.789
1.881
35.43
40.12
34.84
35.54
33.88
38.38
SUMMARY STATISTICS ON TRANSFORMED DATA TABLE 1 of 2
GRP IDENTIFICATION N MIN MAX MEAN
1
2
3
4
5
6
SUMMARY STATISTICS ON TRANSFORMED DATA TABLE 2 of 2
GRP IDENTIFICATION VARIANCE SD SEM C.V.
1 control
2 6.25
3 12.5
4 25
5 50
6 100
ANOVA TABLE
SOURCE DF SS MS F
Between 5 21.683 4.337 0.135
Within (Error) 54 1740.900 32.239
Total 59 1762.583
Critical F value = 2.45 (0.05,5,40)
Since F < Critical F FAIL TO REJECT Ho: All equal
DUNNETT'S TEST - TABLE 1 OF 2 Ho: ControKTreatment
TRANSFORMED MEAN CALCULATED IN
GROUP IDENTIFICATION MEAN ORIGINAL UNITS T STAT SIG
1 control 14.700 14.700
2 6.25 15.800 15.800 -0.433
3 12.5 15.500 15.500 -0.315
4 25 15.300 15.300 -0.236
5 50 16.700 16.700 -0.788
6 100 15.500 15.500 -0.315
Dunnett table value = 2.31 (1 Tailed Value, P=0.05, df=40,5)
DUNNETT'S TEST - TABLE 2 OF 2 Ho: ControKTreatment
NUM OF Minimum Sig Diff % of DIFFERENCE
GROUP IDENTIFICATION REPS (IN ORIG. UNITS) CONTROL FROM CONTROL
1 control 10
2 6.25 10 5.866 39.9 -1.100
3 12.5 10 5.866 39.9 -0.800
4 25 10 5.866 39.9 -0.600
5 50 10 5.866 39.9 -2.000
6 100 10 5.866 39.9 -0.800
-------
Cone.ID
Cone. Tested
6.25
12.5
25
50
100
7
19
12
21
18
25
14
10
9
20
*** Inhibition Concentration Percentage Estimate ***
Toxicant/Effluent: 96-424
Test Start Date: 11/19/96 Test Ending Date: 11/25/96
Test Species: C. dubia
Test Duration: 6 days
DATA FILE:
Response 1
Response 2
Response 3
Response 4
Response 5
Response 6
Response 7
Response 8
Response 9
Response 10
24
11
-10
15
12
9
12
19
22
13
9
13
13
26
13
23
25
14
12
10
10
12
10
21
15
16
13
11
25
22
10
13
17
24
12
14
12
12
13
26
21
15
17
14
14
11
23
10
28
14
Cone.
ID
1
2
3
4
5
6
Number
Replicates
10
10
10
10
10
10
Concentration
0.000
6.250
12.500
25.000
50.000
100.000
Response Std. Pooled
Means Dev. Response Means
14.700
15.800
15.500
15.300
16.700
15.500
5.208
6.339
5.401
5.438
5.658
5.949
15.600
15.600
15.600
15.600
15.600
15.500
*** No Linear Interpolation Estimate can be calculated from the input data since none of the (possibly
pooled) group response means were less than 75% of the control response mean.
98141Q5>
98141Q6>
98141Q7>
98141Q8>
98141Q9>
98141R>
98141R1>
98141R2>
98141R3>
98141R4>
98141R5>
98141R6>
98141R7>
-------
TECHNICAL REVIEW OF THE
REMEDIAL INVESTIGATION REPORT
CHEMSOL,INC. SITE
PISCATAWAY, NEW JERSEY
Prepared for:
Chemsol Site PRP Group
Prepared by:
ECKENFELDER INC.
1200 MacArthur Boulevard
Mahwah. New Jersey 07430
April 1997
-------
TABLE OF CONTENTS
Page No.
1.0 INTRODUCTION 1-1
2.0 TECHNICAL REVIEW OF THE REMEDIAL INVESTIGATION REPORT 2-1
2.1 Conceptual Hydrogeologic Model 2-1
2.2 General Comments - Volume 1 (Text) 2-4
2.3 General Comments - Volume 1A (13"x20" RI Figures) 2-4
2.4 General Comments - Other Appendices 2-5
3.0 QUANTITATIVE ANALYSIS OF THE HYDROGEOLOGIC SYSTEM 3-1
3.1 Pre-RI Pump Testing 3-1
3.2 Initial Observations 3-2
3.3 Analysis of the Hydrogeologic Data 3-3
3.3.1 Long-Term Test of COM 3-3
3.3.2 Distance Drawdown Analyses of Packer Test Data 3-4
3.3.3 Aguifer Test of Well C-l by McClaren-Hart 3-4
3.3.4 Neuman-Witherspoon Ratio Method Analysis of 3-5
McClaren-Hart Aguifer Test
3.3.5 Theis Type Curve Matching of Time Recovery Data from 3-5
Packer Test
3.3.6 Distance Drawdown Analysis of Packer Test 3-6
Round 3, Test 3
3.4 Summary of Quantitative Analyses 3-6
4.0 CONCEPTUAL HYDROSTRATIGRAPHIC MODEL 4-1
5.0 EFFECT OF DNAPL AND MATRIX DIFFUSION ON GROUNDWATER 5-1
REMEDIATION
5.1 Impact of DNAPLs on Grounwater Restoration 5-1
5.2 The Significance of Matrix Diffusion 5-3
APPENDICES
Appendix A - Summary of Volumes - RI Report
Appendix B - Aguifer Test Analyses
LIST OF TABLES
Follows
Table No. Title Page No.
3-1 Summary of Aguifer Test Analyses 3-3
4-1 Well Groupings by Hydrostratigraphic Unit 4-1
4-2 Groundwater Elevations 4-2
-------
LIST OF FIGURES
Follows
Figure No. Title Page No.
4-1 Projected Bedrock Cross Section 4-2
4-2 Potentiometric Contour Map Wells Screened in the 4-2
Overburden Zone
4-3 Potentiometric Contour Map Wells Screened in the Upper 4-2
Permeable Aguifer
4-4 Potentiometric Contour Map Wells Screened in the Upper 4-2
Principal Aguifer
4-5 Potentiometric Contour Map Wells Screened in the Lower 4-2
Principal Aguifer
5-1 Matrix Diffusion in Fractured Rock Aguifers 5-3
-------
1.0 INTRODUCTION
A site-wide Remedial Investigation (RI) was conducted for Operable Unit I of the Chemsol Inc. property
located in Piscataway Township, New Jersey. The RI was conducted from October 1992 through November 1994 by
CDM Federal Programs Corporation for the U.S. Environmental Protection Agency. The results of the RI were
reported in a document titled "Remedial Investigation Report, Chemsol Inc. Superfund Site" (hereinafter
referred to as the RI report), dated October 1996.
A stated objective of the RI was to provide a basis for the "technical development and detailed evaluation of
the remedial alternatives in the FS [Feasibility Study]". Accordingly, the RI investigation included the
installation and testing of additional monitoring wells and piezometers and the collection and analysis of
samples to assess chemical constituents present within groundwater, surface water, stream sediment and soil.
The RI report included a description of hydrogeologic conditions, an analysis of probable source areas and
transport pathways, and a risk assessment to public health and the environment. The RI report is contained in
a series of 15 volumes, which have been briefly summarized in Appendix A.
The RI has been reviewed by ECKENFELDER INC. on behalf of the Chemsol Site PRP Group. The results of this
review are described in Section 2.0. In addition, a further analysis of the hydrogeologic data for the site
has also been conducted, beyond that as presented in the RI. This includes a guantitative analysis of pump
test data obtained during the RI and previous investigations (Section 3.0) and a re-interpretation of the
conceptual hydrogeologic model for the site (Section 4.0). Finally, a discussion is presented in Section 5.0
regarding implications for groundwater remediation due to the effects of DNAPLs and matrix diffusion that
should be considered in the upcoming FS.
This document is intended to facilitate a technical dialog between the USEPA and the Chemsol Site PRP Group
(Group) regarding the issues related to site remediation. Specifically, it is particularly important to
achieve technical concurrence regarding the conceptual hydrogeologic conditions of the site and the
significance of DNAPLs and matrix diffusion as they relate to groundwater remediation. Agreement on these and
other technical issues is critical in order to provide an objective analysis of the various remedial options
that will be considered as a part of the Feasibility Study.
2.0 TECHNICAL REVIEW OF THE REMEDIAL INVESTIGATION REPORT
A technical review of the RI report has been performed. The RI report presents the results of a generally
well implemented field investigation. However, the narrative report is somewhat limited by a rather cursory
analysis of the data, particularly as it relates to the site bydrogeologic conditions. Furthermore, the RI
report could be a more useful document if it had been structured to serve as a comprehensive presentation of
both the newly collected and existing site data.
The intent of Otis review is not to provide a point-by-point critigue of each of the 15 volumes that
constitute the RI report. Rather, a brief discussion is provided regarding the highlights of the document
review. Most of the technical comments are relatively minor and do have a critical bearing on use of the
report as it relates to site remediation. A significant exception, however, is the interpretation of the
water-bearing zones beneath the site and the related implications regarding the directions of groundwater
flow. The critigue is presented as follows.
2.1 CONCEPTUAL HYDROGEOLOGIC MODEL
Interpretation of the site hydrogeologic conditions is based on a faulty assumption regarding the grouping of
wells for mapping purposes. Specifically, the wells have been grouped, by CDM, on the basis of egual
elevation rather than on the basis of stratigraphic position within the dipping bedrock units. Our experience
has shown that this type of approach results in the incorrect determination of groundwater flow directions.
It was correctly stated in the RI report that the results of the packer tests should be used to group the
wells for the purpose of potentiometric mapping. The following statement was made on page 3-21 leading to the
discussion regarding well grouping:
-------
"Based on the results of the packer tests, it appears that:
! the bedrock that lies stratigraphically above the [upper] gray shale is near isotropic and
homogeneous conditions [sic] (but flow is still controlled by fractures),
! the [upper] gray shale appears to be a hydraulic barrier,
! the bedrock below the [upper] gray shale is near isotropic and homogeneous conditions [sic]
(but flow is still controlled by fractures), and
! the deep gray unit may have some hydraulic control, but the collected data are not significant
enough to make any conclusion regarding this unit."
The aforementioned conclusions, which should have been used as the basis for well grouping for potentiometric
mapping by CDM, were apparently ignored in that wells were subseguently grouped entirely on the basis of
elevation. The result of grouping wells in this fashion yielded the comparison of data from wells that are in
disparate water-bearing zones. This is a particular problem at this site because of the significantly complex
hydrostratigraphic vertical relationships between the various units, which includes a significant downward,
vertical flow component. Accordingly, much of the potentiometric mapping by CDM (RI Figures 3-23 through
3-40) has yielded misinterpretation regarding the direction and magnitude of groundwater flow.
Specific comments regarding the potentiometric surface contour maps are offered, as follows:
! TW-Series Wells Above and Below the Gray Shale (RI Figure 3-23) - This map is erroneous in that
it employs wells that are screened both stratigraphically above and below the gray shale and
which are, thus, in two different hydrostratigraphic units. Furthermore, the wells screened
above the gray shale are in an aguitard which is characterized, predominantly by a vertical,
downward flow system. Accordingly, it is inappropriate to use the TW-series wells above the
gray shale for the purposes of mapping horizontal gradients.
! C-Series Wells Above the Gray Shale - (RI Figures 3-24 through 3-26) - These maps depict the
highly fractured zone immediately above the gray shale. Use of data from Well C-7 would have
provided a greater spatial data distribution that may have yielded a greater predominance in
the direction of groundwater flow than is observed from the small changes in the waterlevel
variations in the four closely spaced wells that were used. The RI report states that C-7 was
not used because it is at a lower elevation even though it is at a stratigraphically similar
position as the other C-series wells that were used.
! C-Series Wells Below the Gray Shale - (RI Figures 3-27 through 3-33) - The wells used to
construct these maps are too small in number and are too closely spaced to yield useful
information regarding groundwater flow direction at this interval. These wells can, however, be
grouped with numerous other wells in a similar bydrostratigraphic zone (but at different
depths) to a provide maps with considerably greater geographic coverage.
! Upper DMW/MW Series Wells (RI Figures 3-34 through 3-37) - These maps are problematic in that
they include wells screened both above and below the lower gray shale which may, therefore, be
in two separate hydrostratigraphic regimes.
! Lower DMW/MW Series Wells (RI Figures 3-38 through 3-40) - In a similar manner as the previous
maps, these maps mix wells that are screened above and below the lower gray shale.
A modified hydrogeologic model has been prepared by ECKENFELDER INC., as presented in Section 2.0 of this
document. This model utilizes well groupings based on hydrostratigraphic units defined on the basis of
observed stratigraphic conditions and based on response to the packer pump testing. Finally, this model
presents a revised set of the potentiometric surface contour maps for the August 29, 1994, measurement date
that is believed to more accurately represent the site conditions than maps presented, in the RI.
-------
2.2 GENERAL COMMENTS - VOLUME 1 (TEXT)
! The RI functions adequately as a data presentation report but lacks the depth of data analysis
that is typically found in a report of this type.
! The packer testing was generally well implemented and provides invaluable data for the
differentiation of the various hydrostratigraphic units. However, additional detail could have
been provided regarding response to pumping if supplemental manual water level measurements
were obtained from wells that were not instrumented with data loggers.
! Data are presented in various figures that are not supported in accompanying tables or in the
appendices. Examples include tables that present well construction details for all (newly
installed and existing) wells and water level data.
! Collection of additional full rounds of water level data prior to implementation of the interim
remedy (pumping of Well C-l) would have been useful for the characterization of groundwater
flow directions.
! The occurrence of DNAPLs at the site is critical to overall site remediation and should be more
prominently presented in Volume I. Specifically, the text should present a more detailed
discussion regarding the occurrence of DNAPLs rather than simple reference to the handwritten
calculations in Appendix X. This discussion should be supported by tables and maps that
describe the presence and distribution of the specific DNAPL constituents.
2.3 GENERAL COMMENTS - VOLUME 1A (13" X 20" RI FIGURES)
! The geophysical cross sections (natural gamma and caliper log) presented on RI Figures 3-5A and
3-5B have a vertical scale that is too small to adequately resolve details of the log.
Furthermore, the cross sections would be much more informative if stratigraphic correlation and
associated annotations were included.
2.4 GENERAL COMMENTS - OTHER APPENDICES
! The appendices should provide a comprehensive presentation of both new and historic boring and
well construction logs.
! Logs of previously existing monitoring wells and piezometers should be included for reference
to the newly installed wells.
! Water level data logger data tabulations (Appendix V) would be much easier to use if they were
annotated with test details (e.g., test start, test stop, etc.) and if they had been provided
in a computer format (on disk).
! The concentration contour maps (Appendix T-l) present a misleading depiction or the contaminant
distribution for the following reasons:
• It would be more appropriate to group the maps by hydrostratigraphic unit rather than by well
depth for the same reasons as described previously for the potentiometric surface maps.
• Complete reliance of computer contouring methods can result in misleading representations of
contaminant distribution that are often too strongly controlled by individual data points
(e.g., "bulls-eye" effect around individual data points). Manual contaminant contouring and the
related application of professional judgment regarding the effects of groundwater flow would
likely result in the preparation of maps that are more accurate.
• The color concentration scale should be standardized for all maps. Use of the full range of
colors for each map prevents the rapid visual comparison of the relative concentration
-------
differences by color. This fact obviates what is perhaps the greatest advantage in the use of
color maps beyond that of simple physical attractiveness.
3.0 QUANTITATIVE ANALYSIS OF THE HYDROGEOLOGIC SYSTEM
A guantitative analysis of the available hydrogeologic data has been conducted for the Chemsol Site. This
analysis included a review of data from the RI as well as a revisit of data by AGES and McClaren-Hart to
determine if additional information could be extracted from their efforts. The available data include aguifer
test, slug test, and packer testing data.
This evaluation provides as much of a guantitative understanding of the hydrogeologic system as is reasonably
feasible given the complex hydrogeologic system. By the term "guantitative understanding", we mean the
ability to subdivide the hydrogeologic system into functional hydrostratigraphic units and assign
hydrogeologic properties to these units, such as transmissivity, hydraulic conductivity, and storativity.
This type of guantitative understanding of the system will be vital as a foundation for the numerical
modeling of the system, even if the properties are modified (as they almost certainly will be) during the
calibration of the model.
3.1 PRE-RI PUMP TESTING
In 1987, AGES Corporation performed a hydrogeologic assessment of the Chemsol site. As part of their work,
they conducted a step-drawdown test of Well C-l, and a subseguent aguifer test using the same well.
Extraction of much usable hydrogeologic data from the AGES work is problematic since the aguifer test at Well
C-l was begun shortly after the conclusion of the step-drawdown test and before sufficient time bad elapsed
for the aguifer to fully recover from the drawdown produced by the step-drawdown test.
In 1993, McClaren-Hart conducted a hydrgeoologic study of the Chemsol site. As part of their work, they
performed an aguifer test using Well C-l as the pumping well and a number of wells as monitoring points.
While procedurally, the work of McClaren-Hart is a considerable improvement over the earlier AGES work,
analysis of the data from the aguifer test is hindered by the fact that the open interval of Well C-l
actually spans two distinct water-bearing zones and an intervening hydrostratigraphic unit (the Gray Shale),
which generally acts as an aguitard. This was not recognized in 1993. Conseguently, the well likely draws an
indeterminate amount of water from each zone, thus confounding precise definition of the hydrogeologic
properties of either zone. Nonetheless, as will become clear subseguently, some useful data can be drawn from
this test since apparently most of the water is drawn from the Principal Aguifer.
3.2 INITIAL OBSERVATIONS
Before embarking upon an in-depth assessment of the aguifer tests, slug tests, and packer tests, several
general observations need to be made about the hydrogeologic system as a conceptual foundation for the
subseguent analyses.
1. The observed vertical hydraulic head losses at the site are indicative of moderate to low vertical
hydraulic conductivity in some zones.
2. The above observation, coupled with the relatively high yields observed in various pumping wells and
packer tests, suggests a hydrogeologic system composed of interlayered aguifers and aguitard.
3. Vertical anisotropy is also indicated, certainly on a system-wide basis and probably within individual
strata as well.
4. A degree of heterogeneous hydrogeologic behavior is evident in virtually all the data. This heterogeneity
will certainly defy efforts to precisely model the system. Nonetheless, the generalized behavior of the
system should be subject to modeling and reasonably accurate predictive analysis.
5. The heterogeneity has particular implications to the implementation of a groundwater extraction system at
the site. No matter how thoroughly one probes the hydrogeologic data for insight into the properties of the
-------
system or how diligently one strives to calibrate a numerical groundwater flow model based on those
calculated properties, performance of a groundwater extraction system will reguire careful verification. It
seems inescapable that the Observational Method, in one form or another, will have to be called upon to
design and construct a cost-effective system.
3.3 ANALYSIS OF THE HYDROGEOLADGIC DATA
In analyzing the hydrogeologic system at the Chemsol site, principal emphasis has been placed upon the
aguifer test and packer test conducted by CDM and McClaren-Hart. In particular, CDM conducted a packer test
of some duration which they termed the long-term test. This packer test was, in essence, an aguifer test and
the data from this packer test are guite useful. The aguifer test conducted by McClaren-Hart in 1993 of Well
C-l is also useful. ECKENFELDER INC. has carefully evaluated all of the packer test data to see what
guantitative information can be extracted from this considerable body of data. While the packer tests were
primarily conducted to determine the interconnectedness; of various zones, nonetheless, some of the tests
lend themselves to guantitative analysis.
The packer test data were first evaluated as to whether analyses could be conducted using the Theis type
curve match technigue on the drawdown data. Analysis of the drawdown data, however, was not feasible due to
the variable pumping rate employed in the early phase of the packer test. In most cases, the flow rate during
the packer test was increased in step-wise fashion during the early part of the test, and then held
relatively constant throughout the remainder of the test. While the early stepped pumping rate makes
time-drawdown analysis infeasible, analysis of time-recovery data is possible since water level recoveries
react more to the average pumping rate, particularly during the later phases of the test, than they do to
early fluctuations in pumping rate. Distance drawdown analyses were also employed to analyze the drawdown at
the conclusion of the packer test pumping. Lastly, packer test recovery data were also used to conduct
Neuman-Witherspoon ratio method analyses of the upper bedrock zone above the upper permeable zone. Each of
these methods of analysis is briefly described below. A summary of the results of the aguifer test analyses
is presented in Table 3-1.
3.3.1 Long-Term Test of CDM
CDM performed what they termed the "Long-Term Test" as part of their packer testing activities. During the
long-term test, drawdown was measured in a number of monitoring wells, and the results analyzed by CDM using
the AQTESOLV computer program. Three tests, in particular, provide insight into the transmissivity and
storativity of the principal aguifer. These tests are the analyses conducted based upon the drawdowns
observed in Wells DMW-1, DMW-5 and MW-103. These particular wells are well suited stratigraphically to
determine the aguifer parameters. The results of CDM's analyses are presented in Table 3-1.
-------
TABLE 3-1
SUMMARY OF AQUIFER TEST ANALYSES
Water-bearing
Zone
Principal Aquifer
Principal Acquirer
Principal Aquifer
Principal Aquifer
Principal Aquifer
Nature of
Text
Aquifer Test:
Theis Type Curve
Match - DMW-1
Aquifer Test:
Theis Type Curve
Match - DMW-5
Aquifer Test:
Theis Type Curve
Match - MW-103
Packer Test:
Round 3, Test 2
Distance - Drawdown Analysis
Neuman-Witherspoon
Ratio method
Analysis of McClaren-Hart
Aquifer Test
Analysis
Conducted by
COM
CDM
CDM
ECKENFELDER INC.
ECKENFELDER INC.
Transmissivity
(gpd/ft)
14,500
8,800
3,800
>5,000
Vertical Hydraulic
Storativity Conductivity
(dimensionless) (cm/sec)
2.1 x 10 -4
7.8 x 10 -5
2.2 x 10 -4
2.3 x 10 -4
3.5 x 10 -4
-------
TABLE 3-1(cont'd)
SUMMARY OF AQUIFER TEST ANALYSES
Water-bearing
Zone
Principal Aquifer
Nature of
Text
Acquirer Test of Well C-l
Theis Type Curve
Match TW-9
Analysis
Conducted by
McClaren-Hart
Transmissivity
(gpd/ft)
8,500
Storativity
(dimensionless)
9.9 x 10 -5
Vertical Hydraulic
Conductivity
(cm/sec)
Principal Aquifer
Aquifer Test of Well C-l
Theis Type Curve
Match DMW-5
McClaren-Hart
10,300
4.1 x 10 -4
Principal Aquifer
Aquifer Test of Well C-l
Theis Type Curve
Match C-3
McClaren-Hart
10,800
1.7 x 10 -4
Principal Aquifer
Aquifer Test of Well C-l
Theis Type Curve
Match C-4
McClaren-Hart
10,800
1.9 x 10 -4
Principal Aquifer
Aquifer Teat of Well C-l
Theis Type Curve
Match C-5
McClaren-Hart
29,000
2.1 x 10 -4
Upper Permeable Aquifer
Packer Test:
Theis Type Curve
Match of time-recovery data
Round 3, Test 3, Well C-6
ECKENFELDER INC.
12,300
1 x 10 -4
-------
TABLE 3-1(cont'd)
SUMMARY OF AQUIFER TEST ANALYSES
Water-bearing
Zone
Upper Permeable Acquirer
Upper Bedrock
Upper Bedrock
Nature of
Text
Packer Test:
Distance-Drawdown
Analysis or Round 3, Test 3
N-W Ratio Method
Analysis of Round 3, Test 3
Packer Test:
C-8, TW-3
N-W Ratio Method
Analysis of Round 3, Test 3
Packer Test:
C-10, TW-4
Analysis
Conducted by
ECKENFELDER INC.
ECKENFELDER INC.
ECKENFELDER INC.
Transmissivity
(gpd/ft)
13,000
Storativity
(dimensionless)
6 x 10 -6
Vertical Hydraulic
Conductivity
(cm/sec)
1.1 x 10 -4
6.5 x 10 -5
-------
3.3.2 Distance Drawdown Analyses of Packer Test Data
Efforts were undertaken by ECKENFELDER INC. to determine whether any of the packer test data would be
suitable for a distance drawdown analyses using the Cooper-Jacob method. This methodology is particularly
useful in defining transmissivity. However, most of the packer tests do not lend themselves to this type of
analysis for two reasons. First, there are generally not a sufficient number of wells at different radial
differences from the pumped interval to define the shape of the distance drawdown curve. Secondly, the pumped
interval typically cannot be used in the analysis because of excessive well losses. Nonetheless, one packer
test, specifically Round 3, Test 2, provided some insight into the transmissivity in that well losses in the
pumped interval in Well DMW-10 appeared to be more modest. Drawdown in the pumped interval was only 4.8 feet
(compared to many tens of feet in some of the other packer tests). An analysis of this packer test using the
Cooper-Jacob distance drawdown method, and assuming the drawdown in the pumped interval is reflective of
actual drawdown in the formation, yields a transmissivity of 5,000 gallons per day per foot and a storativity
of 2.3 x 10 -4. In all likelihood the transmissivity is higher than this figure since well losses likely
occur. For example, if well losses accounted for one-half of the observed drawdown, the transmissivity would
be approximately 10,000 gallons per day per foot. The plot of the data and the associated calculations are
provided in Appendix B-l.
3.3.3 Aguifer Test of Well C-l by McClaren-Hart
McClaren-Hart conducted an aguifer test of Well C-l measuring drawdown in a number of monitoring wells. The
analyses of the drawdowns observed in Wells TW-9, DMW-5, C-3, C-4, and C-5 are particularly appropriate as
these wells are well positioned stratigraphically to define the aguifer parameters of the principal aguifer.
These analyses, which are presented in McClaren-Hart's report, yielded transmissivities ranging from 8,500 to
29,000 gallons per day per foot and storativities ranging from 9.9 x 10 -5 to 4.1 x 10 -4, as presented in
Table 3-1.
As mentioned earlier, the aguifer test conducted by McClaren-Hart of Well C-l is limited in its accuracy due
to the fact that the well is likely pumping an indeterminate amount of water from both the principal aguifer
and the upper permeable zone. However, based upon the results of the analyses and a comparison to more recent
aguifer tests conducted by COM, it seems likely that the majority of the water being pumped from Well C-l is
being drawn from the principal aguifer. Conseguently, it is probably reasonable to conclude that the
calculated transmissivity is reasonably reflective of the Principal Aguifer.
3.3.4 Neuman-Witherspoon Ratio Method Analysis of McClaren-Hart Aguifer Test
In order to gain some insight into the vertical hydraulic conductivity of the principal aguifer, ECKENFELDER
INC. conducted a Neuman-Witherspoon Ratio Method Analysis of the data from the McClaren-Hart Aguifer Test. A
vertical hydraulic conductivity of 3.5 x 10 -4 centimeters per second was estimated for the lower portion of
the principal aguifer. These data and associated calculations are presented in Appendix B-2.
3.3.5 Theis Type Curve Matching of Time Recovery Data from Packer Test
ECKENFELDER INC. conducted Theis type curve analysis of recovery data from a number of the packer tests. One
test in particular generated data permitting a Theis type curve match analysis. These data were the packer
test recovery data from Round 3, Test 3 for Well C-6. This analysis permits estimation of the aguifer
parameters of the upper permeable zone. The analysis resulted in an estimated transmissivity of 12,300
gallons per day per foot and a storativity of 1 x 10 -4. The data, type curve match and associated
calculations are included in Appendix B-3.
3.3.6 Distance Drawdown Analysis of Packer Test Round 3, Test 3
The data from the Round 3, Test 3 packer test also lent itself to a distance drawdown analysis using the
Cooper-Jacob method. In this packer test, Well C-7 in the upper permeable zone was pumped and drawdowns in
Wells C-6, C-8, C-9 and C-10 were measured in the upper permeable zone. In this analysis Well C-6 and C-10
provide the most useful data since they are at significantly different radial distances from the pumped
interval. This test suggests some degree of areal an isotropy with a slightly higher transmissivity along the
-------
strike of the formation. Similar an isotropy is not observed in other data sets, however, and the apparent
areal an isotropy observed in Round 3, Test 3 is probably coincidental. The distance drawdown analysis
results in an average transmissivity of 13,000 gallons per day per foot and a geometric mean storativity of 6
x 10 -6. The data plots and calculations are included in Appendix B-4.
Neuman-Witherspoon Ration Method Analysis of Packer Test Round 3, Test 3
In order to get some information as to the vertical hydraulic conductivity of the upper bedrock zone,
ECKENFELDER INC. conducted Neuman-Witherspoon ratio method analyses of the Round 3, Test 3 packer test. The
analysis specifically involved analysis of Wells C-8 and TW-3, and C-10 and TW-4. These analyses were done
using recovery data for the reasons described earlier. The time recovery plots and calculations of both ratio
method analyses are presented in the appendices. The analyses resulted in estimated vertical hydraulic
conductivity's of 1.1 X 10 -4 and 6.5 x 10 -5 centimeters per second. These analyses should probably be
regarded only as order of magnitude estimates. The data plots and calculations are presented in Appendix B-5.
3.4 SUMMARY OF QUANTITATIVE ANALYSES
In connection with the principal aguifer, the average transmissivity calculated from the three Theis type
curve match analyses conducted by CDM and the five Theis type curve match analyses conducted by McClaren-Hart
is approximately 12,700 gallons per day per foot. Similarly, the average storativity is approximately 2 x 10
-4. The average transmissivity of the upper permeable zone, calculated from the values obtained from the
Theis type curve match of time recovery data from packer test, Round 3, Test 3 of Well C-6 and the distance
drawdown analyses of packer test Round 3, Test 3 is 12,650 gallons per day per foot. The storativity is most
likely on the order of 1 x 10 -4 as calculated from the time recovery analysis of Well C-6. The much lower
value calculated from the distance drawdown analyses is probably unrepresentative. Although some suggestion
of areal anisotropy was observed in the drawdowns, of Packer Test, Round 3, Test 3, generally, areal
anisotropy is not indicated in the preponderance of the data. The spatial differences in drawdown seem to be
more attributable to typical fractured rock heterogeneity than to a systematic areal anisotropy.
4.0 CONCEPTUAL HYDROSTRATIGRAPHIC MODEL
The hydrostratigraphic setting beneath the Chemsol Superfund site is complex being characterized by a
dipping, multi-layered bedrock system. Numerous monitoring wells have been installed at various depths during
previous investigations in an effort to evaluate the hydrogeologic and water guality conditions.
A review of the existing hydrogeologic data for the site has been conducted by ECKENFELDER INC. to develop a
refined conceptual model of the groundwater flow regime. This current understanding represents a revision of
the preliminary conceptual model that was presented previously by ECKENFELDER INC. Moreover, this conceptual
model represents a fundamental departure from that described by CDM in the RI report. Specifically, the
current model, as presented, groups the wells for mapping purposes on the basis of stratigraphic position
rather than on the basis of depth (Table 4-1).
The current conceptual model was revised on the basis of an analysis of the data from the RI report (CDM,
1996) and further review of previous site investigation data by both McClaren-Hart and AGES Corporation. A
guantitative analysis of available pump test data has been presented previously in Section 3.0. This
conceptual model may be subject to further revision based on the results of pending numerical modeling and/or
additional field data that may be obtained in the future.
The site is conceptually subdivided into six units. This has been primarily accomplished on the basis of site
stratigraphy and the observed aguifer response to the various pump tests that have been performed at the
site.
! Overburden Water-Bearing Zone
! Upper Bedrock Aguitard
! Upper Permeable Aguifer
! Upper Gray Shale (Aguitard)
! Principal Aguifer
! Deep Bedrock Unit
-------
TABLE 4-1
WELL GROUPINGS BY HYDROSTRATIGRAPECIC UNIT
Chemsol Inc. Superfund Site
Overburden Water-Bearing Zone
OW-1
OW-2
OW-4
OW-10
OW-11
OW-12
OW-13
OW-14
OW-15
Upper Bedrock aquitard
TW-1
TW-2
TW-3
TW-4
TW-5A
TW-10
TW-11
TW-12
Upper Permeable Aquifer
C-6
C-7
C-8
C-9
C-10
Principal Aquifer
Upper Zone
TW-6 TW-13 C-l
TW-7 TW-14 C-3
TW-8 TW-15 C-4
TW-9 C-5
DWM-9
BMW-10
Lower Zone
DMW-1 DMW-5 DMW-7 C-2
DMW-3 DMW-6 DMW-11 MW-103
Deep Bedrock Unit
BMW-2 BMW-4
BMW-3 BMW-8
MW-101
MW-102
MW-104
-------
The hydrostratigraphic units are depicted on Figure 4-1. Plan-view potentiometric maps (Figures 4-2 through
4-5) have been prepared that depict static pre-pumping conditions using data obtained on August 29, 1994
(Table 4-2). These include maps for the hydrostratigraphic zones in which horizontal flow predominates
including the Overburden zone, Upper Permeable aguifer, and the upper and lower portions of the Principal
Aguifer.
The hydrostratigraphic units are described briefly, as follows:
! Overburden Water-Bearing Zone - represents the uppermost water-bearing unit at the site. This
zone is contained within the composite unit represented by the thin overburden soils and the
upper veneer of highly weathered bedrock. Groundwater within this unit flows laterally toward
the northeast (Figure 4-2), generally in response to ground surface topography. The overburden
zone is likely to be in hydraulic communication with the small ditches and streams which flow
toward the northeast across the site.
! Upper Bedrock Aguitard - is represented by the bedrock below the overburden zone. This unit is
comprised of bedrock with relatively low hydraulic conductivity. The upper portion of this unit
also likely represents weathered bedrock within which the joints and fractures are filled with
silt or clay serving to reduce the hydraulic conductivity. Considerable vertical head loss is
observed within this unit downward to the underlying Upper Permeable Aguifer. The vertical
hydraulic conductivity of this unit has been determined to range from 1.1 x 10 -4 to 6.4 x 10
-5 cm/sec on the basis of a Neuman-Witherspoon analysis of aguifer test data, described in
Section 3.0.
! Upper Permeable Aguifer - is a highly fractured bedrock zone of relatively high hydraulic
conductivity that lies immediately above the upper gray shale. The presence of this unit was
initially revealed in boreholes drilled during the RI. These data indicate that this zone is
approximately 40 feet thick.
-------
TABLE 4-2
GROUNDWATER ELEVATIONS
CHEMSOL INC., SITE
PISCATAWAY, NEW JERSEY
Well
Reference
Elevation Zone (b.
(ft., Msl)
C-l
C-2
C-3
C-4
C-5
C-6
C-7
C-8
C-9
C-10
BMW-1
BMW- 2
BMW- 3
BMW- 4
BMW- 5
BMW- 6
BMW- 7
BMW- 8
BMW- 9
BMW- 10
BMW- 11
MW-101
MW-102
MW-103
MW-104
OW-1
OW-2
OW-4
OW-10
OW-11
OW-1 2
OW-1 3
OW-1 4
OW-1 5
79,
86,
80,
80,
80,
76,
80,
81,
85,
80,
85,
85,
80,
80,
78,
79,
76,
77,
76,
79,
85,
79,
78,
81,
88,
78,
81,
79,
79,
75,
84,
82,
92,
75,
.83
.24
.52
.96
.10
.12
.20
.40
.33
.71
.40
.07
.49
.44
.89
.23
.62
.77
.35
.58
.04
.80
.69
.09
.58
.37
.64
.96
.06
.08
.65
.96
.14
.08
3/4
5
4
4
4
3
3
3
3
3
5
6
6
6
5
5
6
6
4
4
5
6
6
5
6
1
1
1
1
1
1
1
1
1
Ground
Elevation
(ft., Mai)
77.60
78.40
79.00
78.00
Coordinates (c.)
Northing Easting
82.90
83.40
78.70
78.60
77.10
77.70
75.60
76.00
77.40
77.50
80.00
89.00
76.20
79.70
77.60
78.30
74.70
73.00
629,997
629,865
629,642
629,636
629,815
630,574
630,534
630,140
629,925
630,292
629,867
629,670
629,656
629,660
630,166
630,138
630,132
630,121
630,578
630,540
629,918
629,995
629,863
630,144
628,957
630,036
629,898
629,921
629,660
630,592
629,888
629,988
629,643
630,390
2,062,281
2,061,790
2,062,565
2,062,307
2,062,297
2,062,609
2,061,803
2,061,554
2,061,589
2,061,975
2,062,117
2,062,085
2,062,566
2,062,532
2,062,022
2,062,030
2,062,439
2,062,428
2,062,618
2,061,816
2,061,792
2,062,253
2,062,471
2,061,572
2,062,510
2,062,275
2,062,206
2,062,332
2,062,549
2,062,609
2,061,897
2,061,673
2,061,657
2,062,545
29-Aug-94
DTW Elev.
(ft.) (ft., Msl)
58.50
58.36
58.39
58.20
58.37
59.21
59.10
59.32
59.41
59.11
58.36
57.86
58.36
57.86
58.28
58.21
58.32
57.85
58.18
58.42
58.31
58.02
57.81
58.30
58.42
73.57
78.04
75.61
76.83
69.34
79.61
78.17
83.99
NM NM
-------
PZ
PZ
PZ
PZ
PZ
PZ
PZ
PZ
PZ
1
ID
2
2D
3
4
4D
5
5D
76,
77,
76,
75,
78,
78,
78,
76,
76,
.62
.05
.45
.94
.65
.03
.25
.68
.86
1
1
1
1
1
1
1
1
1
74.90
74.50
74.30
76.00
74.90
630,157
630,172
630,051
630,066
629,919
630,280
630,289
630,250
630,251
2,062,437
2,062,437
2,062,474
2,062,475
2,062,438
2,062,084
2,062,090
2,062,208
2,062,193
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
NM
-------
TABLE 4-2
GROUNDWATER ELEVATIONS
CHEMSOL INC., SITE
PISCATAWAY, NEW JERSEY
Well
PZ
PZ
PZ
6
6D
7
PZ 8
PZ 8D
PZ 9D
PZ 10D
SG@PZ 4
SG@PZ £
TW-1
TW-2
TW-3
TW-4
TW-5
TW-5A
TW-6
TW-7
TW-8
TW-9
TW-10
TW-11
TW-1 2
TW-1 3
TW-1 4
TW-1 5
Reference
Elevation Zone (b
(ft,
76,
76,
75,
77,
77,
75,
79,
71,
73,
90,
85,
81,
78,
76,
75,
78,
80,
85,
80,
79,
75,
75,
78,
89,
82,
. , Msl)
.15
.14
.71
.57
.51
.98
.08
.67
.95
.15
.81
.59
.31
.24
.98
.88
.16
.11
.29
.96
.76
.73
.17
.23
.90
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
4
4
4
4
2
2
2
4
4
4
Ground
Elevation
(ft., Mai)
74.20
73.80
75.70
Coordinates (c.)
Northing Easting
89.10
84.20
79.60
76.60
74.30
74.30
76.70
78.10
83.30
78.60
78.50
75.00
73.60
76.30
88.60
82.20
630,227
630,227
630,229
629,971
629,986
630,295
630,086
630,267
629,983
629,638
629,900
630,160
630,218
630,175
630,166
629,894
629,655
629,647
629,662
630,549
630,594
630,594
630,092
629,332
629,380
2,062,373
2,062,389
2,062,459
2,062,477
2,062,477
2,062,410
2,062,273
2,062,067
2,062,495
2,061,637
2,061,591
2,061,538
2,062,010
2,062,475
2,062,470
2,062,490
2,062,399
2,062,102
2,062,557
2,061,809
2,062,620
2,063,195
2,063,250
2,061,661
2,062,367
29-Aug-94
DTW
(ft.)
NM
NM
NM
NM
NM
NM
NM
NM
NM
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
—
Elev.
(ft., Msl)
NM
NM
NM
NM
NM
NM
NM
NM
NM
59.56
59.98
59.56
59.37
62.98
62.28
58.76
61.46
59.15
58.71
63.45
67.21
65.27
59.76
62.01
62.15
-------
Notes:
a. Abbreviations are as follows:
"NE" - no entry to well
"NW" - not measured
b. Wells are screened in the following zones:
1. Overburden Water-Bearing zone
2. Upper Bedrock Aguitard
3. Upper Permeable Aguifer
4. Upper of portion of Principal Aguifer
5. Lower of portion of Principal Aguifer
6. Deep Bedrock Zone
c. Northings & Eastings were obtained from surveyors coordinates, except for "PZ" wells which were obtained from a map by McLaren Hart
d. Elevations for PZ wells with D suffix were derived from McLaren Hart database.
e. Reference elevation for Staff Gauges PZ-4 and PZ-8 are for the 0 ft. mark. DTW reading is above the 0 mark.
-------
The transmissivity of the Upper Permeable aquifer has been determined to be approximately 13,000 gpd/ft on
the basis of aquifer testinq described in Section 3.0. Groundwater flow within this unit is predominantly
horizontal with a relatively flat hydraulic qradient to the northeast, as shown on Fiqure 4-3.
! Upper Gray Shale (Aquitard) - Analysis of aquifer test data indicate that the Upper Gray shale
provides hydraulic separation between the Upper Permeable Aquifer and the Principal Aquifer. This
separation is also observed in the vertical head losses observed between the two aquifers across the
Upper Gray shale.
! Principal Aquifer - is comprised of the bedrock zone between the upper and deep qray shale beds with a
thickness of approximately 180 feet. The transmissivity of this unit has been shown to be typically on
the order of 12,700 gpd/ft with a storativity of approximately 2 x 10 -4, as described in Section 3.0.
Sliqht downward qradients are observed within the Principal aquifer so that it has been subdivided into upper
and lower portions for mappinq purposes. Wells screened in the contiquous upper and deep qray shale units
have been observed to be in sufficient hydraulic communication with the Principal aquifer that they have been
included in the potentiometric mappinq of this unit. Potentiometric maps for the upper and lower portions of
this unit (Fiqures 4-4 and 4-5, respectively) reveal a northerly direction of qroundwater flow.
! Deep Bedrock Unit-includes the bedrock below the deep qray shale. The deep qray shale provides some
hydraulic separation between the Principal aquifer and the deep bedrock, determined on the basis of
aquifer testinq. Insufficient data are available in this unit to determine the horizontal direction
of flow.
5.0 EFFECT OF DNAPL AND MATRIX DIFFUSION ON GROUNDWATER REMEDIATION
The primary objective of qroundwater extraction, at the Chemsol site, should be to provide hydraulic
containment of the qroundwater plume for the prevention of further downqradient miqration. Conversely, little
in the way of meaninqful qroundwater restonition can be accomplished at this site throuqh efforts to remove
contaminant mass by qroundwater extraction. This is due to the presence of dense non-aqueous phase liquids
(DNAPL) and the siqnificance of diffusion into the bedrock matrix to the practicability of qroundwater
restoration.
5.1 IMPACT OF DNAPLS ON GROUNDWATER RESTORATION
The RI report concluded that DNAPLs likely exist in numerous overburden and bedrock wells at the Chemsol
site. This is based primarily on comparison of qroundwater quality data to constituent solubilities usinq
USEPA methodoloqy described in its quidance "Estimatinq Potential for Occurrence of DNAPL at Superfund Sites"
(USEPA, 1992). The fact that analysis of rock core samples by ultraviolet florescence (as a part of the RI)
did not reveal NAPL is not surprisinq qiven the fact the that chlorinated orqanics typically do not
fluoresce. However, the RI provides additional evidence of DNAPL in the presence of material resemblinq "tar
balls" that have been observed durinq maintenance of the qroundwater extraction treatment system.
Dense non-aqueous phase liquids (DNAPLs) are a class of chemicals with relatively low solubility in water
which are therefore capable of movinq as a separate phase throuqh qroundwater systems. In addition, they have
densities qreater than that of water so that they tend to sink vertically throuqh aquifers. These factors,
coupled with the fact that many of the DNAPL chemicals are considered potentially harmful at even low part
per billion levels, dictate that even relatively small amounts of DNAPL can contaminate larqe portions of an
aquifer.
Trichloroethylene (TCE) is shown, in the RI, to be one of the more prevalent DNAPL compounds at the Chemsol
site. Of particular note is this compound's solubility. From one perspective, the solubility is sufficiently
low that this chemical will, in fact, behave as a separate phase in qroundwater before ultimately beinq
solubilized. However, from another perspective, it can be seen that the solubility is six orders of
maqnitude hiqher than the qroundwater cleanup standards. Consequently, in spite of the relatively low
solubility compared to other chemicals, the solubility of TCE is sufficiently hiqh to render qroundwater
non-potable even when concentrations are only a minute fraction of the solubility limits.
-------
The importance of DNAPL, where present, has been recognized sinee the early 1980s regarding the ultimate
remediation of sites. More recently, the regulatory agencies have begun to acknowledge the occurrence and
problems presented by the presence of DNAPL chemicals at sites. One of the more important acknowledgments is
presented in the 1992 USEPA guidance, as follows:
"Once in the subsurface, it is difficult or impossible to recover all of the trapped residual DNAPL.
The conventional aguifer remediation approach, groundwater pump-and-treat, usually removes only a
small fraction of trapped residual DNAPL. Although many DNAPL removal technologies are currently being
tested, to date there have been no field demonstrations where sufficient DNAPL has been successfully
recovered from the subsurface to return the aguifer to drinking water guality."
The presence of DNAPL in bedrock further complicates site remediation through inaccessibility (e.g., in
dead-end fractures of bedrock), flow mechanics independent of groundwater flow, complex flow patterns, and
difficulties in locating DNAPL accumulations to name a few.
USEPA (1993) has reeognized these difficulties in the TI guidance document:
"Delineation of the extent of the DNAPL zone may be difficult at certain sites due to complex geology
or waste disposal practices. In such cases, the extent of the DNAPL zone may need to be inferred from
geologic information (eg., thickness, extent, structure, and permeability of soil or rock units) or
from interpretation of the agueous concentrations of contaminants derived from DNAPL sources." (USEPA,
1993, p. 8)
The absence of the observation of large guantities of visible DNAPL (e.g., as "free product) during the RI
and in previous investigations is completely consistent with the presence of DNAPL at the site. Recent
research has shown that actual DNAPL would not likely persist in appreciable guantities in the fractures at
the site given the time since manufacturing operations at the site were discontinued. The research indicates
that DNAPL is likely to diffuse from the fractures into the matrix of the rock on a time scale that varies
from as little as a few days to perhaps unlikely that significant DNAPL would remain in pooled form. The
diffusion of contaminants into the rock matrix, both from DNAPL and from the dissolved phase, presents the
single most significant limitation to aguifer restoration at the Chemsol site. The influence of matrix
diffusion is discussed in more detail below.
5.2 THE SIGNIFICANCE OF MATRIX DIFFUSION
As noted above, the presence of contamination within the rock matrix itself is of particular importance to
our ability to achieve groundwater restoration within a reasonable time frame. (USEPA [1993] has used a time
period of 100 years or more in its discussions regarding what constitutes a reasonable time frame for aguifer
restoration). The entrance to and eventual release of contaminants from the rock matrix is a diffusion
controlled process. DNAPL chemicals in rock fractures and dissolved within groundwater establish the
concentration gradients that drive diffusive transport into the rock matrix. The matrix diffusivity of the
rock has the single most significant influence an the rate of movement of contaminants into and out of the
bedrock matrix. Further, even after a source of contamination is removed, diffusion into the rock matrix can
continue due to internal concentration gradients set up during the contamination phase. Contaminants in the
rock matrix become a long-term source of groundwater contamination for which there is no remedial measure
currently available. One would expect groundwater remediation time within rock aguifers contaminated with
DNAPL chemicals to be measured in hundreds of years.
As contaminated groundwater moves through the fractures of a bedrock aguifer, diffusion of contaminants will
occur into the essentially stagnant matrix pore water of the rock, as illustrated in Figure 5-1. The extent
of the diffusion and its hydrogeologic significance will depend upon the concentration gradient, the matrix
diffusivity and porosity, the fracture spacing of the rock, and the duration of exposure. From one
perspective, the diffusion of contaminants into the rock matrix is beneficial in that it retards the advance
of a contaminant plume through the fractured rock. Lever and Bradbury (1985) reported that matrix diffusion
can lead to effective retardation factors in excess of 100 and can reduce peak concentrations by three to
four orders of magnitude, provided that the groundwater velocity is relatively small. However, when the
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objective is to purge contamination from an aquifer, the diffusion-controlled release of contaminants from
the rock matrix can greatly prolong aguifer cleanup efforts over what would be possible in a simple porous
medium of eguivalent hydraulic conductivity.
It is important to recognize that the significance of matrix diffusion to groundwater restoration is not
limited to the DNAPL zone. In fact, the diffusion process will play a similar role in substantially delaying
the removal of mass in the area of the agueous plume downgradient of the DNAPL zone. USEPA has also
acknowledged the significance of this phenomena:
"EPA recognizes, however, that there are technical limitations to ground-water remediation
technologies unrelated to the presence of a DNAPL source zone. These limitations, which include
contaminant-related factors (e.g., slow de-sorption of contaminants from aguifer materials) and
hydrogeologic factors (e.g., heterogeneity of soil or rock properties), should be considered when
evaluating the technical practicability of restoring the agueous plume." (USEPA, 1993, p.9)
Groundwater extraction in fractured bedrock for the purpose of contaminant mass removal is likely to meet
with only limited success in restoring the guality of water in a reasonable period of time. In particular,
over-pumping to increase flow rates appreciably beyond those required to prevent further migration of the
contaminant plume is not likely to result in significant benefits due to "rebound" effects that usually occur
upon the cessation of pumping. In fractured rock aquifers, the rate of cleanup is controlled by the rate of
contaminant diffusion from the rock matrix into the fractures--a process which cannot be significantly
enhanced by increasing groundwater velocities in the fractures, since increasing fracture flow velocity
generally only marginally increases the concentration gradient between the rock matrix and the fracture flow
system and has no effect on the low diffusivity of the contaminant in the porous medium. Thus, the rate of
diffusion and the rate of cleanup are increased only marginally by pump and treat operations under these
conditions.
In summary, the use of groundwater extraction for the purpose of contaminant mass removal will have little
overall effect on groundwater quality conditions. This is due to the presence of DNAPLs in bedrock and the
recognition of the significance of matrix diffusion in groundwater restoration efforts. Accordingly, the
overall goal of groundwater extraction should be to achieve hydraulic containment of the migrating
groundwater plume.
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APPENDIX A
SUMMARY OF VOLUMES
RI REPORT
SUMMARY OF REMEDIAL INVESTIGATION REPORT
CHEMSOL INC. SUPERFUND SITE
COM Federal Program Corporation
October 1996
An outline of the Remedial Investigation (RI) report prepared by CDM Federal Programs Corporation for USEPA
is presented herein. In addition, text sections of the RI report have been briefly summarized.
Volume I-(RI Report text)
1.0 Introduction
2.0 Study Area Investigations
A description of the RI field investigation was provided, which included the following:
! Two (2) rounds of ambient air guality samples; 1993 and 1994
! Two (2) rounds of surface water and sediment guality samples; 1992 and 1993
! Bedrock core samples collected from six (6) boreholes
! Gridded soils samples taken at 102 locations
! Installation of eight (8) bedrock and three (3) overburden monitoring wells
! Downhole geophysical logging conducted in 30 new and existing wells
! Packer pump testing in three (3) rounds
! Two (2) rounds of water level measurements
! Two (2) rounds of groundwater guality samples in 1994
! Ecological Investigation of the Chemsol property and surrounding properties
3.0 Physical Characteristics of the Chemsol Site
A rather brief discussion of site characteristics including meteorology, air guality, surface water and
sediment, geology, hydrogeology, soils biota, demographics and land use. The primary conclusions made by CDM
regarding geologic and hydrogeologic conditions are summarized below:
! The site is underlain by the Brunswick formation with a strike and dip of N595 E and 95 NW,
respectively.
! A gray shale bed and/or a highly fractured zone above it have the characteristics of a
hydraulic barrier.
! Beds above and below the gray shale bed are described by CDM to be nearly isotropic and
homogeneous even though groundwater flow is controlled by fracture orientation.
! It is not conclusive if a deep gray shale bed acts as a hydraulic barrier.
! Downward vertical gradients are observed across the site.
! Wells were grouped based on egual elevation on either side of the gray marker bed for the
purpose of isopotentiometric mapping.
! Groundwater in the uppermost water bearing zone (OW- wells) flows to the northeast.
! The direction of groundwater flow in deeper zones is not well defined and is shown to flow in
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various directions, dependent upon the group of wells that is mapped.
! Residential water supply wells in the Nova-Ukraine neighborhood are not in hydraulic
communication with the site
! Off-site groundwater pumping may influence the direction of groundwater flow.
4.0 Nature and Extent of Contamination
! Air sampling data indicate no clear evidence of significant off-site
contamination from the Chemsol site.
! Surface water sediment data were reported to contain VOCs, SVOCs
(primarily PAHs), pesticides, PCBs, and various metals.
! Surface water samples contained VOCs, low levels of several pesticides, and
several metals.
! Soil data revealed exceedances of NJ proposed soil cleanup criteria for a
number of constituents including PCBs, several VOCs, SVOCs, pesticides
and metals including lead.
! Groundwater contamination consists largely of chlorinated VOCs. The
highest concentrations are found in the center of the site. However,
significant VOCs in the deeper bedrock are also found at the northeast edge
of the property.
! VOC coneentrations exceed 1% of solubility at many locations indicative of the presence of
DNAPLs.
5.0 Contaminant Fate and Transport
General discussion regarding various routes of contaminant migration and the persistence of various
constituents in the environment.
6.0 Baseline Human Heallb Risk Assessment
The following exposures were determined by CDM to exceed the USEPA acceptable risk ranges:
! Carcinogenic risks due to potential future residential exposure to surface soil and groundwater
! Non-carcinogenic risks due to present and potential future exposure to surface soil and
groundwater, and potential exposure to construction workers via groundwater ingestion.
7.0 Ecological Risk Assessment
The following conclusions are made by CDM regarding ecological risk:
! Exposure of ecological receptors to subsurface soil and groundwater contamination is not
likely.
! A potential exists for adverse effects on selected indicator species, including shrews, robins
and red-tailed hawks, due to exposure to surface soils.
! There is little or no ecological risk associated with surface water or sediment.
8.0 Summary and Conclusions
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9.0 References
Volume IA
Set of 11" x 20" figures to accompany Volume I (text) of the RI.
Volume II
Appendix A - Drilling Logs
Appendix B - Coring Logs
Appendix C - Well Construction Logs
Appendix D - Downhole Geophysical Logging Data
Appendix E - Packer Testing Figures/AQTESOLV Graphs
Appendix F - Soil Boring Logs
Appendix G - PCB Field Screening Logs
Volume III
Appendix H - Sampling Trip Reports
Volume IV - (CLP data summary sheets)
Appendix I - Air Sampling Results - Form One
Appendix J - Surface Water/Sediment Sampling Results - Form One
Volume V & VI - (CLP data summary sheets)
Appendix K - Soil Sampling Results - Form One
Volume VII & VIII - (CLP data summary sheets)
Appendix L - Groundwater Sampling Results - Form One
Volume IX - (BHHRA & ERA backup)
Appendix M - 95 Percent Upper Confidence Limit Calculations
Appendix N - Toxicological Profiles
Appendix 0 - Spreadsheet Calculations
Appendix P - Central Tendency Calculations
Appendix Q - Threatened and Endangered Species/Significant Habitats
Appendix R - Ecological Exposure and Toxicity
Volume X - (formatted analytical data tables)
Appendix S - EDM Data Tables (Air, Surface Water, Sediment, Soil, & Groundwater)
*Volume XI - (11" x 17" color drawings)
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Appendix T - GEOSOFT Concentration Contours - Groundwater
Appendix U - GEOSOFT Concentration Contours - Soil
Volume XII, XIII, XIV - (data logger data)
Appendix V-Packer Testing Data (Rounds 1,2,& 3)
Volume XV
Appendix W - Soil Averaging
Appendix X - Estimating Potential for Occurrence of DNAPL
Evaluation of exceedances of 1% of effective solubility of organic constituents per USEPA methodology
revealed the likely presence of DNAPL in 23 wells, listed as follows:
MW-104 DWM-1
DWM-3
DWM-7
DWM-8
DWM-9
DWM-11
OW-1
OW-2
OW-4
OW-1 2
C-l
C-2
C-5
C-7
C-10
TW-1
TW-4
TW-5
TW-5A
TW-7
TW-8
TW-1 5
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APPENDIX B
AQUIFER TEST ANALYSES
APPENDDIX B-l
Distance-Drawdown Analyses of RI Packer Test Data Well DW-10 (Round 3, Test 2)
APPENDIX B-2
Neuman-Witherspoon Analyses of McClaren-Hart Aquifer Test Data
APPENDIX B-3
Theis Type-Curve Analyses of Recovery Data From RI Packer Test Well C-6 (Round 3, Test 3)
APPENDIX B-4
Distance-Drawdown Analyses of RI Packer Test Data Well C-7 (Round 3, Test 3)
APPENDIX B-5
Neuman Witherspoon Analyses of RI Packer Test Data (Round 3, Test 3)
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Chemsol, Inc. Superfund Site
Appendix - C
Proposed Plan
USEPA Region II
Superfund Document Center
290 Broadway -18th Floor
New York, NY 10007
By Appointment: (212) 637-4308
Monday-Friday: 9:00am. - 4:30pm
EPA, after consultation with NJDEP, will select a remedy for the Site only after the public comment period
has ended and the information submitted during that time has been reviewed and considered. EPA is issuing
this proposed Plan as part of its public participation responsibilities under Section 117(a) of the
Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) , as amended, and Section
300.430(f) of the National Contingency Plan (NCP).
SITE BACKGROUND
Chemsol, Inc. (Chemsol) is located on a 40 acre tract of land at the end of Fleming Street, Piscataway,
Middlesex County, New Jersey. The Site is comprised of two areas: an undeveloped parcel known as Lot 1A and
a cleared area referred to as Lot IB. Two small intermittent streams - (Stream 1A and Stream IB) and a small
trench, known as the Northern Ditch, drain northward across the Site into a marshy wetland area located near
the northeastern property boundary (see Figures 1 and 2).
Land use in the vicinity of the Site is a mixture of commercial, industrial, and residential uses. The Port
Reading Railroad is directly south of the Site. Single family residences are located immediately to the west
and northwest of the Site. An apartment complex with greater than 1,100 units is located to the north.
Industrial and retail/wholesale businesses are located to the south and east of the Site.
Approximately 180 private wells at residential and commercial addresses were reported by the local health
departments to be potentially active (i.e., not sealed) within a radius of two miles of the Site. Twenty-two
of these wells are located at a distance less than 1/2 mile from the Site. The nearest public water supply
well is over two miles away in the Spring Lake area of South Plainfield.
Chemsol operated as a solvent recovery and waste reprocessing facility in the 1950's through approximately
1964. The facility was closed after a series of industrial accidents, explosions and fire. In 1978, the
property was rezoned from industrial to residential. The Site is currently owned by Tang Realty Corporation.
In September 1983, the Chemsol Site was formally placed on the National Priorities List (NPL) making it
eligible for federal funds for investigation of the extent of contamination and, for cleanup activities.
From 1983 to 1990, NJDEP directed Tang Realty, under various enforcement actions, to perform, a series of
Site investigations related to groundwater and soil contamination. Approximately 40 groundwater monitoring
wells were installed on or in the vicinity of the Site by contractors for Tang Realty. Sampling results from
these monitoring wells indicated that groundwater was contaminated with various volatile organic compounds
(VOCs) including trichloroethylene, chloroform, chloroethane, toluene, carbon tetrachloride and methylene
chloride. Furthermore, sampling and analyses of the soils (performed between 1980 and 1987) revealed the
presence of polychlorinated biphenyls (PCBs) and other organic compounds.
In the Summer of 1988, Tang Realty removed approximately 3,700 cubic yards of PCB-contaminated soils for
off-site disposal. During the soils excavation, several thousand small (less than 1 gallon) containers of
unknown substances were discovered. These unknown substances were stored in a trailer on-site. As a part of
an EPA removal action undertaken in 1990 and 1991,these unknown substances were analyzed, grouped with other
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compatible Site wastes, and transported off-site. Approximately 10,000 pounds of crushed lab pack bottles,
13,500 pounds of hazardous waste solids, 615 gallons of hazardous waste liquids and 150 pounds of sulfur
trioxide were disposed of off-site during the removal action. This removal action was completed in October
1991 by EPA.
In the fall of 1990, EPA and the NJDEP agreed that EPA should fund the remainder of the investigatory work.
Subsequently, EPA initiated a Remedial Investigation and Feasibility Study (RI/FS) in order to assess the
nature and extent of contamination at the Site and to evaluate remedial alternatives. EPA determined that the
RI/FS would be performed in two phases. The first phase consisted of development of a Focused Feasibility
Study (FFS) to evaluate the usefulness of in interim remedy to restrict off-site migration of contaminated
groundwater. The second phase was to determine the nature and extent of contamination at the Site.
As part of the FFS, EPA sampled 22 on-site monitoring wells. The results of the FFS indicated that
groundwater at the Site exists in a perched water zone (at depths of less than five feet), and also in the
upper bedrock aquifer (to depths of at least 130 feet). Sampling results revealed that groundwater was highly
contaminated with a wide variety of hazardous substances, including volatile organics, semi-volatile
organics, as well as pesticides and inorganic compounds.
Based on the results of the FFS, EPA selected an interim remedy for the Chemsol Site in a Record of Decision
(ROD) that was signed on September 20, 1991. The objective of this interim remedy was to restrict the
migration of the contaminated groundwater until a more comprehensive Site-wide remedy could be performed.
The interim remedy consists of pumping groundwater from well C-l, a former monitoring well installed by Tang
Realty's contractors found to be highly contaminated with VOCs. The pumped groundwater from C-l is then
treated on-site through an air stripper, after which it is filtered, followed by treatment by activated
carbon.
On March 9, 1992, EPA issued a Unilateral Administrative Order (UAO) to Tang Realty, Schering Corporation,
Union Carbide Corporation and Morton International,Inc. (the Respondents) for performance of the interim
remedy. Schering Corporation, Union Carbide Corporation and Morton International, Inc. were identified by EPA
as potentially responsible for the contamination at the Site by having sent their waste to the Chemsol Site
for reprocessing. And Tang Realty was identified as the owner of the property.
In November 1993, the Respondents requested that the interim remedy be modified so that water from the
treatment system could be discharged into the sewer system that leads to the Middlesex County Utilities
Authority (MCUA), instead of into an on-site surface water body, as specified in the ROD. As a result, in
July 1994, EPA issued an Explanation of Significant Differences which modified the interim remedy to allow
for discharge of treated groundwater to the sewer system. However, EPA also required that the Respondents
design and build the biological portion of the treatment system so that, in the future, if the treated
groundwater could not be sent to MCUA, the biological system could be brought quickly online to allow for
direct discharge of treated groundwater to Stream 1A on-site.
Construction of the groundwater treatment plan was completed by the Respondents in June 1994 and the plant
was brought into operation in September 1994. The well has been pumped at varying rates, averaging
approximately 25 gallons per minute. The results of monthly monitoring indicate that the interim remedy has
been partially effective in restricting the migration of highly contaminated groundwater from the Site.
REMEDIAL INVESTIGATION SUMMARY
The second phase of the RI, which was conducted to determine the nature and extent of the contamination at
the Site, was completed in October 1996. During this phase, EPA's consultant installed groundwater monitoring
wells, conducted sampling of the various media at the Site including air, sediment, surface water, surface
soil, subsurface soil, and groundwater.
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Soil Investigation
A soil sampling program was designed based on historical Site usage, aerial photographs and the findings of
previous investigations. Samples were taken using an extensive grid system. Group A samples were collected at
200 foot grid spacing in Lot IB and 400 foot grid spacing in Lot 1A. These samples were analyzed for a full
range of organic and inorganic contaminants. Group B samples were collected from Lot IB at 100 foot grid
spacing and field screened for PCBs. Group C samples were collected from biased sampling locations based on
aerial photographs and previous investigations and on a 50 foot grid spacing around those Group B samples
which showed PCBs in their field screening results. In addition, samples from Lot IB were analyzed using the
Toxicity Characteristic Leaching Procedure (TCLP), a test which is used to determine whether a material is a
hazardous waste, regulated by specific federal and State hazardous waste regulations. In addition, subsurface
soil samples were taken from 102 locations across the Site.
The results of the RI show that the surface and subsurface soils in Lot 1A and Lot IB contain various
contaminants. The contaminants found were: VOCs including carbon tetrachloride, trichloroethane,
trichloroethene, tetrachloroethene, toluene, ethylbenzene, and xylenes, semi-volatile organic compounds
(SVOCs) including polyaromatic hydrocarbons, phthalates, pesticides (such as aldrin, dieldrin, and DDE) and
PCBs; and, inorganics including manganese and lead. The range of concentrations of certain contaminants
detected in surface and subsurface soil is presented in Table 1.
Of the contaminants found, PCBs contributed the most to the risks at the Site (see the section entitled
"Summary of site Risk," below. The VOCs were found to be co-located with the PCBs and lead; therefore, any
action taken to address PCBs and lead would also address the Vocs.
Groundwater Investigation
As a part of the RI, additional groundwater monitoring wells were installed. Two rounds of groundwater
sampling were performed during the RI. Samples were collected and analyzed from the 49 wells on the Site.
However, certain property owners adjacent to the Site continue to deny EPA access to install groundwater
monitoring wells on their properties. EPA will try to resolve these access issues.
The geologic formation which underlies the Site is commonly referred to as the Brunswick formation and lies
generally 3 to 14 feet below the ground surface. The Brunswick formation is generally referred to as bedrock
and contains areas of red shale, gray shales and siltstones. A gay shale layer acts to preclude groundwater
flow in some areas and separates the bedrock into an upper zone which is located above the gray shale, and a
so-called "deep gray unit" and a deep gray unit bedrock zone. The Brunswick formation is overlain by a thin
layer of overburden which consists of unconsolidated sand, silt, clay and cobble deposits and fill. This
overburden was determined to be typically 3 to 6 feet thick.
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TABLE -1
CONTAMINANTS IN SURFACE AND SUBSURFACE SOILS
Contaminants
Concentrations Surface Soil
(parts per billion)
VOLATILE ORGANICS
Carbon Tetrachloride
Trichloroethene
Tetrachlorothene
1,1,2,2,- Tetrachloroethane
Chlorobenzene
Xylene (Total)
Toluene
Ethybenzene
SEMI-VOLATILES
Bis(ethylhexyl)phthalate
Naphthalene
1,2,-Dichlorobenzene
PESTICIDES/PCB
Aldrin
Dieldrin
4,4-DDE
Toxaphene
PCBs
INORGANICS
Manganese 30.4
Lead 7-
0-5,000
3,500-32,000
0-7,000
15-110
0-3,300
56,000-110,000
2-380,000
2,900-15,000
0,63,000
29-18,000
200-1,600
58-8,300
43-13,000
0-4,600
0-3,400
540-310,000
-1,840 (parts per million)
1,920 (parts per million)
Concentrations Subsurface Soil
(parts per billon)
680-1700
3-18,000
2-12,000
4-9,000
4-8,300
2-40,000
10-27,000
8-8,800
66-17,000
44-3,800
34-10,000
0.3-2,000
1.1-130
0.13-120
21-2,600
282-2,300 (parts per million)
2.4-914 (parts per million)
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TABLE - 2
CONTAMINANTS IN GROUNDWATER
Contaminants
Concentrations (parts per billion)
VOLATILE ORGANICS
Carbon Tetrachloride
Trichloroethene
Tetrachloroethene
Chlorobenzene
Xylene (Total)
Toluene
Ethylbenzene
Vinyl Chloride
Benzene
2-Butanone
Chloroform
1,2-Dichloroethene
SEMI-VOLATILES
1,2,-Dichlorobenzene
PCBS
INORGANICS
Manganese
Aluminum
2-35,000
0.9-180,000
1-5,700
4-4,200
1-5,700
2-27,000
1-1,600
3-3,310
1-16,000
270-21,000
1-55,000
0.5-39,000
2-3,300
0-10
6.1-19,100
63.9-61,000
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Groundwater flow at the Site is very complex. There is perched groundwater present in the overburden.
However, the primary groundwater flow is through interconnected fractures in the bedrock. Due to the
unpredictable nature and distribution of these fractures, the precise direction of flow and the rate of
groundwater flow can be difficult to predict. In general, groundwater in the upper zone, above the gray
shale, flows to the south. Below the gray shale, groundwater generally flows to the north. Near the southern
boundary of the Site, groundwater is influenced by off-site commercial pumping activities to the south.
With regard to chemical contamination, the RI confirmed that well C-l was by far the most contaminated of all
on-site monitoring wells. The results also confirmed that VOCs are the primary contaminants in groundwater.
The major VOC contaminants include benzene, carbon tetrachloride, chloroform, 1,2,-dichloroethane,
1,2-dichloroethene, tetrachloroethene, toluene and trichloroethene. The bedrock aguifer is contaminated far
in excess of EPA's Safe Drinking Water Act maximum contaminant levels (MCLs) which are the federal regulatory
standards for drinking water. The analytical results also indicate that MCLs for aluminum, iron and manganese
have been exceeded in many wells at the Site. Although many pesticides were detected in the groundwater, no
MCLs were exceeded. In the second round of sampling, PCBs slightly in excess of MCLs were found in two wells,
C-l and TW-4 (see Table 2).
Groundwater contamination is present in the bedrock aguifer at both the northern and southern boundaries of
the Site. Evaluation of the hydrogeological data indicates that contaminated groundwater continues to migrate
off-site. However, due to the influences of groundwater pumping from off-site sources and the limited amount
of off-site groundwater sampling data, there remains uncertainty as to the extent of this migration.
Additional off-site sampling is reguired to further define the extent and source of off-site contamination.
EPA's consultant used mathematical modeling to help determine the optimum pumping plan which would best
capture contaminated groundwater and minimize the amount of contaminated groundwater which leaves the Site.
The modeling showed that, by pumping five additional wells, the contamination could be contained on-site
except for the deep bedrock groundwater in the northwest corner of the Site.
In addition, during the RI, EPA conducted an assessment to determine whether contamination previously
detected in the Nova-Ukraine section of Piscataway was related to the Chemsol Site. The Nova-Ukraine is a
housing development whose nearest part is located approximately 900 feet south-southeast of the Chemsol Site.
Residential wells in this development had been sampled several times since 1980 by various government,
agencies and private consultants. Due to concentrations of VOCs in the wells, NJDEP delineated an Interim
Groundwater Impart Area for a portion of the Nova-Ukraine area. This delineation made residents eligible for
financial assistance to connect to a public water supply. All but four residences elected to be connected to
a public water supply. Based on the results of the RI, EPA does not believe that the groundwater
contamination of residential wells in the Nova-Ukraine areas is related to the Chemsol Site.
Surface Water and Sediment Investigation
The ground elevation at the Site is generally lower than the adjacent area. Surface water runoff is towards
the Site during rain events. There are several wetland areas, one drainage ditch, and two streams present at
the Site. During sampling for the FFS in 1991, Stream 1A was sampled and determined to be free of
contamination from the Site. During the RI, two rounds of sampling were conducted in Stream IB. Twelve
sampling locations were selected. At each location, one surface water sample and two sediment samples were
collected.
Surface water sampling has indicated that the Chemsol Site is contributing low levels of contamination
including VOCS, pesticides and organics to Stream IB. However, low levels of pesticides and inorganics
appear to be entering the Site from off-site sources. Levels of several contaminants exceeded State Water
Quality Criteria. As noted in the previous section, the area surrounding the Site contains many
industrial/commercial establishments. Sediment sampling conducted in conjunction with the surface water
sampling indicates the presence of VOCs, SVOCs pesticides, PCBs and metals.
SUMMARY OF SITE RISK
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Based upon the results of the RI, a baseline risk assessment was conducted to estimate the risks associated
with current and future Site conditions. The baseline risk assessment estimates the human health and
ecological risk which could result from the contamination at the Site if no remedial action were taken.
Human Health Risk Assessment
The following four-step process was used to conduct the Risk Assessment:
1. Hazard Identification- identifies the contaminants of concern at the Site based on several factors such as
toxicity, freguency of occurrence, and concentration.
2. Exposure Assessment- estimates the magnitude of actual and/or potential human exposures, the freguency and
duration of these exposures, and the pathways (e.g., ingesting contaminated groundwater) by which humans are
potentially exposed.
3. Toxicity Assessment- determines the types of adverse health effects associated with chemical exposures,
and the relationship between magnitude of exposure (dose) and severity of adverse effects (response).
4. Risk Characterization- summarizes and combines outputs of the exposure and toxicity assessments to provide
a guantitative (e.g., one-in-a-million excess cancer risk) assessment of Site-related risks.
The baseline risk assessment began with selecting contaminants of concern which would be representative of
the contamination found in various media (surface soil, subsurface soil, surface water, sediment, and
groundwater) at the Site. Due to the large number of chemicals detected at the Site, only those chemicals
which were thought to pose the highest risk (based on factors such as freguency of detection and
concentration detected) were retained as contaminants of concern. The contaminants of concern include:
pesticides, PCBs and inorganics in surface soil; 1,1,2,2-tetrachloroethane, benzo(a)pyrene, pesticides, PCBs,
and inorganics in subsurface soils; VOCs in groundwater; VOCs and SVOCs in surface water, and, polyaromatic
hydrocarbons, PCBs, and inorganics in sediment. Several of the contaminants of concern listed above are
known or suspected of causing cancer in animals and/or humans or of causing non-cancer health effects in the
liver, kidney, respiratory tract, and the central nervous system.
An important factor which drives the risk assessment is the assumed future use of the Site. Based on
discussions with the town and the fact that the Site is now zoned for residential, rather than industrial
use, EPA assumed that the most probable future use of the Site would be for residential or recreational
purposes. The Town expressed a preference for recreational use as the property is one of the last parcels of
open land available in the Township. The current land uses at this Site have the potential to impact nearby
residents (adults and children) and possible trespassers onto the Site. In the future, it is possible that
potential human receptors would include residents (adults and children), Site workers (employees), and
construction workers.
Pathways of exposure evaluated for the Site include: 1) sediment and soil ingestion; 2) dermal contact with
soil and sediment; 3) ingestion of contaminated groundwater and surface water 4) dermal contact with surface
water, and, 5) Inhalation of VOCs and particulates. Because EPA assumed a future residential/recreational
land use of the Site, the list of possible human receptors identified in the exposure assessment included
trespassers, residents (adults and children), Site workers (employees), and construction workers. Exposure
intakes (doses) were calculated for each receptor for all pathways considered.
EPA's acceptable cancer risk range is 10 -4 to 10 -6 which can be interpreted to mean that an individual may
have a 1 in 10,000 to 1 in 1,000,000 increased chance of developing cancer as a result of Site-related
exposure to a carcinogen over a 70-year lifetime under the specific exposure conditions at the Site. The
State of New Jersey's acceptable risk standard is one in one million (10 -6.
EPA found that contaminants in the surface soil at the Site posed an unacceptable total cancer risk (2.2 x 10
-3 ) to potential future residents through ingestion and dermal contact. In addition, ingestion and
inhalation (during showering) of contaminants in groundwater also posed unacceptable cancer risks (maximum of
2.4 x 10 -2) to potential future residents and Site workers. Benzene, carbon tetrachloride, vinyl chloride,
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chloroform, 1,1-dichloroethene, trichloroethene, 1,2-dichloroethane, and PCBs are the predominant
contributors to the estimated cancer risk.
The other receptors/exposure routes (including ingestion or direct contact with subsurface soil, and dermal
contact with surface water and sediment) have estimated cancer risks within or below EPA's acceptable risk
range.
To assess the overall potential for non-carcinogenic effects posed by more than one contaminant, EPA has
developed a hazard index (HI). This index measures the assumed exposures to several chemicals at low
concentrations, simultaneously, which could result in adverse health effects. In accordance with this
approach, a hazard guotient (i.e., the ratio of the level of exposure to an acceptable level) greater than
1.0 indicates a potential of noncarcinogenic health effects. The HI is summed for all media common to a
particular receptor.
With regard to non-cancer effects, based on the calculated His, EPA found that several potential exposure
pathways could have unacceptable health effects including: ingestion of surface soil by children (HI=6.2);
ingestion of disturbed surface soil along the current effluent discharge line by children (HI=3.7);
inhalation of particulates along the current effluent discharge line by children (HI=1.5); ingestion of
contaminated groundwater by adults and children 340 for adults and 800 for children); and, ingestion of
contaminated groundwater by Site workers (employees) and construction workers (HI=120 for employees and 17
for workers). No noncancer effects were associated with subsurface soils, surface water and sediment.
In summary, the Human Health Risk Assessment concluded that exposure to surface soil and ground water, if not
addressed by the preferred alternative or one of the other active measures considered, may present a current
or potential threat to public health or welfare. In contrast, exposure to subsurface soils, sediments, and
surface water was determined not to pose a significant threat to human health.
Ecological Risk Assessment
The Ecological Risk Assessment involves a gualitative and/or semi-guantitative appraisal of the actual or
potential effects of a hazardous waste site on plants and animals. A four-step process is utilized for
assessing site-related ecological risks: Problem Formulation - a gualitative evaluation of contaminant
release, migration, and fate, identification of contaminants of concern,
receptors, exposure pathways, and known ecological effects of the contaminants; and selection of endpoints
for further study. Exposure Assessment -a guantitative evaluation of contaminant release, migration, and fate
characterization of exposure pathways and receptors; and measurement or estimation of exposure point
concentrations. Ecological Effects Assessment - literature reviews, field studies, and toxicity tests,
linking contaminant concentrations to effects on ecological receptors. Risk Characterization - measurement or
estimation of both current and future adverse effects.
The environmental evaluation focused on how the contaminants would affect the Site's natural resources.
Natural resources include existing flora and fauna at the Site, surface water, wetlands and sensitive species
or habitats. A wetlands delineation performed on-site determined that wetlands cover approximately 22 acres
in Lot 1A and 3 acres in Lot IB. Uplands in Lot 1A are wooded. No federally listed or proposed threatened or
endangered flora or fauna are known to occur at or near the Site. However, white-tailed deer, woodchucks,
rabbits, frogs, turtles and birds are known to inhabit the Site.
Sources of exposures to ecological receptors considered for this ecological assessment include surface soil
(generally collected from 0 to 2 feet below ground surface), surface sediment (generally collected from 0-6
inches), and surface water. Data from subsurface soils (soils under pavements or from depths greater than 2
feet) were not evaluated. These depths,are greater than those considered likely for potential contact with
burrowing animal or roots of vegetation. Subsurface sediments (sediments from depths greater than 6 inches)
also were not evaluated since fish and microinvertebrates are not likely to be exposed to contaminants at
greater depths. Similarly, groundwater data were not used in this ecological assessment because it is
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unlikely that ecological receptors can contact contaminants associated with groundwater. Exposure may occur
through; 1) ingestion of contaminated food items; 2) ingestion of contaminated surface water, 3) incidental
ingestion of contaminated media (i.e. soil, sediment, or water ingested during grooming, eating, burrowing,
etc.); 4) inhalation of contaminants; and 5) through adsorption upon contact with contaminated media.
Three receptor species were chosen for the Site to assess the Potential adverse ecological risk of Site
chemicals in the surface soil. They are the northern short-tailed shrew, the American robin, and the
red-tailed hawk.
Aguatic biota and benthic invertebrates were selected as receptor species for surface water and sediment.
The chemicals of concern selected for the environmental risk assessment include: toluene, carbon
tetrachloride, 1,1,1-trichloroethane, trichloroethene, chlorobenzene, xylenes, naphthalene, PCBs, pesticides,
lead and manganese.
In Lot 1A and Lot IB, the ecological risk assessment shows that the potential exists, for adverse effects to
shrews, robins and red-tailed hawk. While Lot IB is a disturbed habitat, Lot 1A exists in a relatively
undisturbed state. Therefore, the ecological assessment included an analysis of the potential remedial impact
to Lot 1A habitat. Sediment and surface water for Lot 1A were assessed using published ecological screening
values designed to be protective of benthic and water-column receptors. The results of the assessment
indicate that there is a potential for risk from surface soils to small mammal and birds, a potential for
risk from sediment to benthic receptors, and no significant potential for risk from surface water to water
column receptors.
Two tributaries join in Lot 1A before exiting the Site to the north. Elevated levels of PCBs were detected in
portions of the streams. It is not clear if the PCB concentrations in the stream sediment represent actual
source areas of contamination or indicate the presence of a migration pathway for contaminants from the more
heavily contaminated Lot IB. In addition, ecological risks associated with the PCBs are miminal. Therefore,
remediation of the stream is not warranted at this time. Rather, monitoring is reguired to determine whether
remediation of Lot IB results in a lowering of PCB levels in the streams in Lot 1A.
REMEDIAL ACTION OBJECTIVES
Remedial action objectives are specific goals to protect human health and the environment. These objectives
are based on available information and standards such as applicable or relevant and appropriate reguirements
(ARARs) and risk based-based levels established in the risk assessment.
The following objectives were established for the Chemsol Site:
! restoring the soil at the Site to levels which would allow for residential/recreational use
(without restrictions)
! augment the existing groundwater system to contain that portion or contaminated groundwater that is
unlikely to be technically practicable to fully restore and restore remaining affected groundwater to
State and federal drinking water standards
! remove and treat as much contamination as possible from the fractured bedrock
! prevent human exposure to contaminated groundwater, and
! prevent human exposure to surface soils contaminated with PCB concentrations above 1 pan per million
(ppm) and lead concentrations above 400 ppm.
! eliminating, to the greatest extent practicable, continuing sources of ntamination to the groundwater.
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Soil cleanup levels for PCBs at the Site were obtained from EPA's 1990 "Guidance on Remedial Actions for
Superfund Sites with PCB Contamination." For residential land use, an action level of 1 ppm is specified for
PCBs. The 400 ppm lead cleanup level is based on EPA's 1994 "Revised Interim Soil Lead Guidance for CERCLA
Sites and RCRA Corrective Action Facilities." EPA estimates that there are approximately 18,500 cubic yards
of surface soil (up to a depth of 2 feet) that contain PCBs at levels above 1 ppm, and/or lead at levels
above 400 ppm.
The State of New Jersey his developed State-wide soil cleanup criteria for several of the contaminants found
at the Chemsol Site, including several VOCs, SVOCs, lead (400 ppm) and PCBs (0.49 ppm). Based on the data
collected to date, in meeting EPA's cleanup levels for PCBs and lead cited previously, EPA believes the
remedy will achieve the State of New Jersey residential direct contact and impact to groundwater soil cleanup
criteria. If the remedy does not achieve the State residential direct contact soil cleanup criteria of 0.49
ppm for PCB, the State will reguire that restrictions be placed on the property to prevent future direct
contact with soils above 0.49 ppm.
Due to the complex geology and the possible presence of non-agueous phase liguids at this Site, EPA believes
that it may not be technically practicable to fully restore some portion of the contaminated on-site
groundwater to State and federal water guality standards. By law, any areas of contaminated groundwater which
cannot be restored to meet State and/or federal groundwater guality standards reguire a waiver of such
standards on the basis of technical impracticability. As will be discussed in subseguent sections, if after
implementation of the remedy, it proves to be technically impracticable to meet groundwater guality
standards, EPA would waive such standards. Performance data from any groundwater system selected for the Site
would be used to determine the parameters and locations (both vertically and horizontally) which may reguire
a technical impracticability waiver.
SCOPE AND ROLE OF ACTION
This action is the second action taken to address the Site. The first action consisted of the interim
groundwater containment system which is currently operational at the Site. This action will address on-site
contaminated groundwater and soil. A third action or "operable unit" is necessary to investigate the extent
of groundwater contamination outside the property boundaries.
SUMMARY OF REMEDIAL ALTERNATIVES
CERCLA reguires that each remedy be protective of human health and the environment, be cost effective, comply
with other statutory laws, and utilize permanent solutions and alternative treatment technologies and
resource recovery alternative to the maximum extent practicable. In addition, the statue includes a
preference for the use of treatment as a principal element for the reduction of toxicity, mobility, or volume
of hazardous substances.
Based on the remedial action objectives, EPA performed an initial screening process of potential alternatives
that would address the soils and groundwater concerns at the Site. This Proposed Plan evaluates three
Groundwater Remedial Alternatives and four Soil Remedial Alternatives for adding the contamination associated
with the Chemsol Site.
CERCLA reguires that if a remedial action is selected that results in hazardous substances, pollutants, or
contaminants remaining at the Site above levels that allow for unlimited use and unrestricted exposure, EPA,
must review the action no less often than every five years after initiation of the action. As such, all of
the groundwater alternatives presented in this section include a five-year review and two of the four soil
alternatives include a five-year review.
It should be noted that the estimated implementation times are for construction of the remedy only. The
estimates do not include the time to negotiate with the Respondents, prepare design documents, or procure
contracts which may be significantly longer (approximately 18 months) than the construction times shown.
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The alternatives are:
SOIL
Alternative S-l: No Further Action
Estimated Capital Costs: $388,660
Estimated Annual O&M Costs (30 years): $0
Estimated Total Present Worth Value: $388,660
Estimated Implementation Period: 3-6 months
The "No-Action" alternative is used as a baseline for comparison of other soil alternatives. Under this
alternative, EPA would take no action at the Site. However, the No-Action alternative includes, as with the
other soil alternatives, a single sampling event for drummed waste and soil stockpiled at the Site, along
with their transportation and off-site disposal. The drummed waste were generated from the various
investigations performed at the Site and the stockpiled soils were generated from construction activities
performed at the Site. Since contaminants would remain on-site, institutional controls (e.g., a deed
restriction) would be placed on the property that would restrict future use of the Site. A review of the Site
conditions at the end of five years would be performed to determine whether or not the contamination in the
soils has spread both horizontally or vertically.
Alternative S-2A: Capping with Soil
Estimated Capital Costs: $1,855,850
Estimated Annual O&M Costs (30 years): $2,000
Estimated Total Present Worth Value: $1,894,000
Estimated Implementation Period: 3-6 months
This alternative includes the construction of a single layer (18 inches thick) soil cap covering 12 acres of
the property which are contaminated above the soil cleanup levels. It would also reguire that no intrusive
activities be performed on the capped area in order to ensure its integrity. This alternative would allow for
many recreational uses of the property, such as park or playground, among others. However, a restriction
would have to be placed on the property to ensure that the cap is not breached. A single sampling event of
drummed waste and stockpiled soil along with their transportation and off-site disposial would be performed.
After completion of the remedy, a review of Site conditions every five years would be performed as reguired
under the Superfund law.
Alternative S-3: Excavation and Off-Site Disposal
Estimated Capital Costs: $5,573,001
Estimated Annual O&M Costs (30 years): $0
Estimated Total Present Worth Value: $5,573,000
Estimated Implementation Period: 6-12 months
This alternative includes excavation and off-site disposal of all surface soils contaminated with PCBs and
lead that are above EPA's cleanup levels. Approximately 18,500 cubic yards of soil with PCBs levels greater
than 1 part per million and lead levels greater than 400 parts per million will be disposed of at a licensed
and approved disposal facility. The excavated areas would be backfilled with imported clean fill from an
off-site location, and covered with topsoil and seeded with grass. The excavation and off-site disposal of
the contaminated soils will allow for residential, or recreational use of the Site in the future. As with
Alternative S-l, this alternative includes a single sampling event of drummed waste and stockpiled soil
prior-to disposal off-site.
Alternative S-4A: Excavation and On-Site Low Temperature Thermal Desorption of PCB-Contaminated Soil with
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On-Site Solidification of Lead Contaminated Soil.
Estimated Capital Costs: $11,963,134
Estimated Annual O&M Costs (30 years): $0
Estimated Total Present Worth Value: $11,963,000
Estimated Implementation Period: 3-6 months
Alternative S-4B: Excavation and On-Site Low Temperature Thermal Desorption of PCB-Contaminated Soil with
Off-Site Disposal of Lead Contaminated Soil.
Estimated Capital Costs: $12,241,639
Estimated Annual O&M Costs (30 years) : $0
Estimated Total Present Worth Value: $12,242,000
Estimated Implementation Period: 6-9 months
For both Option A and B, all surface soil contaminated with PCBs above 1 part per million (18,500 cubic
yards) would be excavated. The excavated sod would be treated on-site by low temperature thermal desorption
(LTTD) to remove PCBs. The treated soil would then be backfilled to the excavated areas, topsoil would be
placed on the treated soils and seeded. As with the other soil Alternatives, Alternative S-4(A and B)
includes a single sampling event of drummed waste and stockpiled soil prior to disposal off-site.
Under Option A, the lead contaminated soil would be solidified/stabilized on-site by mixing it with Portland
cement. The area on-site where this contaminated soil is placed would be protected from future intrusion.
Under Option B, the lead-contaminated soil would be excavated and transported off-site for disposal at 2
licensed and approved RCRA disposal facility. The excavated areas would be backfilled with clean fill, and
seeded.
GROUNDWATER
Alternative GW-1: No Action
Estimated Capital Costs: $0
Estimated Annual O&M costs (30 years): $59,336
Estimated Total Present Worth Value: $912,000
Estimated Implementation Period: 0 months
The Superfund program reguires that the "No-Action" alternative be considered as a baseline for comparison
with other alternatives. Under this alternative, EPA would cease actions at the Site to treat the
contaminated groundwater and to restrict the off-site migration of contaminated groundwater. However, the
No-Action alternative does include long-term monitoring of on-site groundwater, to monitor the concentrations
of contaminants remaining at the Site.
Alternative GW-2(A and B): Continue Existing Interim Action - Extract Groundwater from Well C-l
OPTION - A
Estimated Capital Costs: $45,097
Estimated Annual O&M Costs (30 years): $452,738
Estimated Total Present Worth Value: $7,000,300
Estimated Implementation Period: 0 months
Under Option-A of this alternative, the current extraction of the groundwater from well C-l would continue.
The extracted groundwater first passes through an air stripper, after which it is filtered, followed by
activated carbon adsorption. The treated water is then discharged to the Middlesex County Utilities Authority
(MCUA) Publicly Owned Treatment Works (POTW) . The capital cost of $45, 097 includes costs for replacing the
existing pipeline (which carries water from well C-l to the treatment plant) with an underground pipeline in
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order not to restrict the future uses of the property.
Option - B
Estimated Capital Costs: $45,097
Estimated Annual O&M Costs(30 years): $726,336
Estimated Total Present Worth Value: $11,209,000
Estimated Implementation Period: 3 months
In addition to the treatment described in Option-A, a biological treatment phase would be added for Option-B.
This would be done by starting up the existing (currently unused) biological treatment plant. This phase is a
contingency in the event that in the future, treated groundwater cannot be sent to MCUA. The biological
treatment will provide additional treatment so the groundwater will achieve federal and State surface water
guality standards which would allow for discharge to Stream 1A. The capital cost of $45,097 includes costs
for replacing the existing pipeline (which carries water from well C-l to the treatment plant) with an
underground pipeline in order not to restrict the future uses of the property.
Alternative GW-5(A and B): Extract Groundwater from Additional Wells - Use Existing Treatment Processes Air
Stripping/Aerobic Mixed Growth Biotreatment/Filtration/Activated Carbon Adsorption
Option - A
Estimated Capital Costs: $390,189
Estimated Annual O&M Costs(30 years): $670,892
Estimated Total Present Worth Value:
$10,699,000
Estimated Implementation Period: 3 months
Option-A of this alternative is almost identical to Alternative GW-2A. They differ in that, in addition to
well C-l, groundwater would be pumped from other on-site wells (EPA cost estimates are based on pumping five
additional wells. However, the number of wells to be pumped will be determined during the remedial design.)
Pumping from these additional wells will allow for more effective on-site containment of the plume, and also
allow for groundwater extraction from other contaminated areas on-site. As in Alternative GW-2A, the treated
groundwater would be discharged to MCUA POTW. The capital cost of $390,189 includes costs for replacing the
existing pipeline (which carries water from well C-l to the treatment plant) with an underground pipeline in
order not to restrict the future uses of the property as well as costs asociated with installation of
additional extracting wells.
Option - B
Estimated Capital Costs: $390,189
Estimated Annual O&M Costs (30 years): $766,336
Estimated Total Present Worth Value: $12,169,000
Estimated Implementation Period: 3 months
A biological treatment phase would be added for Option-B. This would be done by starting up the existing
(currently unused) biological treatment plant. Use of the biological treatment phase would allow for
discharge to Stream 1A in compliance with federal and State standards. The capital cost of $390,189 includes
costs for replacing the existing pipeline (which carries water from well C-l to the treatment plant) with an
underground pipeline in order not to restrict the future uses of the property as well as costs asociated with
installation of additional extraction wells.
EVALUATION OF ALTERNATIVES
Each of the above alternatives was evaluated against specific criteria on the basis of the statutory
reguirements of CERCLA Section 121. A total of nine criteria are used in evaluating the alternatives. The
first two criteria are threshold criteria which must be met by each alternative. The next five criteria are
the primary balancing criteria upon which the analysis is based. The final two criteria are referred to as
modifying criteria and are applied, following the public comment period, to evaluate state and community
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acceptance. The Glossary of Evaluation Criteria describes the nine criteria used in evaluating remedial
alternatives.
A comparative analysis of these alternatives based upon these evaluation criteria is presented below.
Overall Protection of Human Health and the Environment
Soil
Alternative S-l, No Action, would not be protective of human health and the environment because the Site
would remain in its current condition. The soils would continue to pose a threat to potential future
residents and trespassers. Therefore, Alternative S-l has been eliminated from consideration and will not be
discussed further.
Alternative S-2A relies on containment and institutional controls to provide, protection over time. Deed
restrictions would have to be enforced to ensure that the cap is not breached in the future in order for this
alternative to be protective.
Upon completion of Alternatives S-3 and Alternative S-4(A and B), all risks to human health and the
environment from organic and inorgamc contaminants would be eliminated through off-site removal or treatment
of contaminants in the surface soils to protective levels.
Groundwater
Alternative GW-1, No Action,would not be protective of human health and the environment because the
groundwater would continue to migrate off-site continuing to pose a potential threat to users. Therefore,
Alternative GW-1 has been eliminated from consideration and will not be discussed further.
Alternatives GW-2 (A and B) and GW-5 (A and B) would be protective of human health by controlling the
migration of contaminated groundwater through pumping and by removing contaminants through treatment of
pumped groundwater. GW-5 (A and B) captures and removes more contamination than GW-2 (A and B), and therefore
best meets this criterion.
GLOSSARY OF EVALUATION CRITERIA
Threshold Criteria
Overall Protection of Human Health and the Environment: This criterion addresses whether or not a remedy
provides adequate protection and describes how risks are eliminated, reduced, or controlled through
treatment, engineering controls, or institutional controls.
Compliance with ARARs: This criterion addresses whether or not a remedy will meet all of the applicable or
relevant and appropriate requirements of other environmental statutes and requirements or provide grounds for
a waiver.
Primary Balancing Criteria
Long-term Effectiveness: This criterion refers to the ability of a remedy to maintain protection of human
health and the environment, once cleanup goals have been met.
Reduction of Toxicity, Mobility or Volume through Treatment: This criterion refers to the anticipated
performance of the treatment technologies a remedy may employ.
Short-term Effectiveness: This criterion considers the period of time needed to achieve protection and any
adverse impacts on human health and the environment that may be posed during the construction and
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implementation period until cleanup goals are achieved.
Implementability: This criterion examines the technical and administrative feasibility of a remedy, including
the availability of materials and services needed to implement a particular option.
Cost: This criterion includes capital and operation and maintenance costs.
Modifying Criteria
State Acceptance: This criterion indicates whether, based on its review of the RI/FS report and Proposed
Plan, the state concurs, opposes, or has no comment on the preferred alternative.
Community Acceptance: This criterion will be addressed in the Record of Decision following a review of the
public comments received on the RI/FS report and the Proposed Plan.
Compliance with ARARs
Actions taken at any Superfund site must meet all applicable or relevant and appropriate reguirements of
federal and state law or provide grounds for invoking a waiver of these reguirements. There are several types
of ARARs: action specific, chemical-specific, and location specific. Chemical-specific ARARs are usually
numerical values which establish the amount or concentrations of a chemical that may be found in, or
discharged to, the ambient environment. Location-specific reguirements are restrictions placed on the
concentrations of hazardous substances or the conduct of activities solely because they occur in a special
location. Action-specific ARARs are technology or activity-specific reguirements or limitations related to
various activities.
Soil
There are no federal or State promulgated soil cleanup standards. Alternative S-2A does not meet State soil
cleanup criteria which, while not legally applicable, were considered by EPA as cleanup levels for the Site.
If the State soil criteria were not met, institutional controls would be reguired by the State.
In addition, because a portion of the Site is classified as wetlands, all alternatives (soil and/or,
groundwater) would need to comply with Section 404 of the Clean Water Act and federal Executive Order 11990
which reguires federal agencies to take actions to minimize the destruction, loss, or degradation of wetlands
and to preserve and enhance the natural and beneficial values of wetlands. Any actions which disturb or
impact wetlands would additionally reguire development of a wetlands mitigation plan.
If implemented, Alternatives S-3 and S-4 (A and B) would meet chemical-specific, location-specific and
action-specific Federal and State ARARs: for the contamination in the soils. The major ARARs for Alternative
S-3 are Federal and State Resource Conservation and Recovery Act (RCRA) reguirements which control the
transportation disposal of hazardous waste. For example, the soil excavated under Alternative S-3 would be
disposed at a facility which is licensed under RCRA to accept hazardous waste. Alternatives S-4(A and B)
would involve the use of an on-site treatment technology which would be subject to RCRA treatment regulations
and Clean Air Act reguirements regarding emissions from the treatment system. Air emissions will reguire air
permit eguivalences from the State of New Jersey.
Groundwater
Alternatives GW-2 (A and B) and GW-5(A and B) would meet the chemical-specific ARARs for the treated water
before discharge. These include New Jersey Pollutant Discharge Elimination System reguirements for discharges
to surface water. In addition, air emissions from the treatment plant would need to comply with Federal and
State emissions standards. Alternatives GW-2(A and B) and GW-5(A and B) produce a filter cake that might need
to be disposed of as a RCRA hazardous waste. In accordance with State regulations, a classification
exception area (CEA) will have to be established once the extent of contamination on associated with the
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Chemsol Site has been determined.
Alternative GW-5(A and B) is more likely to achieve State and federal water quality standards in the aquifers
than is GW-2. It is possible that it will be technically impracticable to restore all portions of the
aquifers to meet State and federal standards. Any areas of contaminated groundwater which cannot be restored
to meet State and/or federal groundwater quality standards require a waiver of such standards on the basis of
technical impracticability. If after implementation of the remedy, it proves to be technically impracticable
to meet water quality standards, EPA would waive such standards. Performance data from any groundwater system
selected for the Site would be used to determine the parameters and locations (both vertically and
horizontally) which may require a technical impractibility waiver.
Long-Effectiveness and Permanence
Soil
Alternatives S-4(A and B) provide the highest degree of long-term effectiveness and permanence since the
waste would be treated to permanently remove organic contaminants. Alternative 3 provides a high degree of
long-term effectiveness by removing waste from the Site but does not provide a high degree of permanence
since waste would not be destroyed but only contained off-site.
Under Alternative S-2A, contaminated soils would remain on-site and, therefore, this remedy would provide the
least amount of long-term effectiveness and permanence. In addition, institutional controls would need to be
employed and enforced in order to ensure the effectiveness.
Groundwater
Alternatives GW-2(A and B) and GW-5(A and B) provide varying amounts of containment of the contaminated
groundwater. Additional off-site investigations to determine the extent of groundwater contamination are
necessary to ensure that risks to neighboring communities are minimized. Alternatives GW-5 (A and B) provide
a higher degree of long-term effectiveness than Alternative GW-2 (A and B) by, increasing the amount of
groundwater captured on-site and removing more contaminants from the extracted groundwater through treatment.
Short-Term Effectiveness
Soil
Alternatives S-2A, S-3, and S-4(A and B) do involve construction activities that would pose a low level risk
of exposure to soils by ingestion, direct contact and inhalation to Site workers; however this risk can be
managed by appropriate health and safety measures. All of the alternatives can be implemented relatively
quickly, in less than a year, following completion of design.
Alternative S-3 involves a significant increase in dust, vapor, and noise generation during soil excavation.
These would be minimized through the use of measures which would be undertaken to ensure that all activities
are performed in such a way that vapors, dust, and other materials are not released to the surrounding
community during excavation. In addition, Alternative S-3 includes off-site transportation of the excavated
soil. This will increase truck traffic and noise in the community during the period when soil is being
transported off-site. EPA will design transportation flow patterns to minimize traffic impacts on the
community. EPA will also explore the use of constructing a road from the Site which will bypass residential
areas.
Under Alternative S-4(A and B), a thermal desorber would be placed on-site, causing increases in noise and
emissions from the unit. To minimize the risk from inhalation of vapors from the thermal desorber which is
required, a secondary chamber would be utilized that would oxidize all organics compounds released from the
LTTD process to carbon dioxide, water and hydrochloric acid.
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Groundwater
All the groundwater alternatives provide short-term effectiveness in protecting the Site workers and
neighboring communities from the risks due to ingestion and inhalation of VOCs. Alternatives GW-2(A and B)
and GW-5(A and B) would pose a low level risk to Site workers during construction; however, this risk can be
managed by the use of appropriate health and safety measures. Alternative GW-2 is a continuation of the
existing system and is running now. Alternatives GW-5 (A and B) can be implemented very guickly (in
approximately 3 months) since they are simply an addition to the current system.
Reduction of Toxicity, Mobility or Volume Through Treatment
Soil
Alternatives S-4 (A and B) provide for physical removal of the contaminated material and the maximum reduction
in toxicity and mobility through treatment. Alternative S-2-A and Alternative S-3 do not include the use of
treatment to reduce the toxicity, mobility or volume of contaminated soil. For Alternative S-2A, reduction
in-the mobility of the contamination would be achieved through the use of containment. For Alternative S-3,
reduction in toxicity, mobility and volume would be achieved through excavation and off-site disposal.
Groundwater
Alternatives GW-2(A and B) and GW-5(A and B) reduce the toxicity and volume of contamination from the
extracted groundwater. However, Alternative GW-5 (A and B) would operate at twice the pumping rate of
Alternative GW-2(A and B). The mobility of the contaminants is completely controlled by the pump-and-treat
alternatives to the extent that the groundwater is within the capture zone of the wells. Greater reduction of
volume and toxicity of contaminated groundwater is achieved by GW-5 than GW-2. Alternative GW-5 also results
in greater capture and containment of contaminated groundwater.
Implementability
Soil
All of the services and materials needed to implement the soil alternatives are readily available
commercially. Each alternative utilizes standard technologies for excavation, capping and transportation of
soils. However, due to the high demand for thermal desorption units, there may be a delay in Alternative S-4
(A and.B). All the alternatives are technically feasible but Alternatives S-4(A and B) reguire a treatability
study to obtain design parameters for the full-scale system. Alternatives S-4(A and B) have complex
administrative issues because of the guantity of eguipment that needs to be set up at the Site and the need
to provide substantive compliance with State air emissions permit reguirements. Alternative S-3 is easily
implementable using standard excavation technology possible, a temporary access road that would provide more
direct and access from the Site to nearby highways, would be built, in order to minimize the number of trucks
traveling through the community.
Groundwater
All of the services and materials needed to implement the groundwater alternatives am readily available
commercially. All the alternatives are technically feasible but Alternatives GW-2(A and B) and GW-5(A and B)
reguire skilled operators to successfully implement the remedy. The alternatives are also feasible from an
administrative standpoint. The reguired activities for the pump-and-treat would occur on Chemsol property.
The treatment plant for the interim remedy has already been built and has been in operation for the last two
years with discharge to the MCUA POTW. The effluent line for the discharge to Stream 1A has also been
installed even though it is not currently being used.
All the services needed to implement the alternatives already exist. The pump-and-treat alternatives reguire
the most services since they reguire operation of the treatment plant and disposal of filtered waste from the
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plant.
Costs
The capital, annual operation and maintenance, and present worth costs are presented below for each
alternative. Present worth costs for all the alternatives were calculated assuming a 5% interest raze and a
30-year operation and period.
Soil
Capital costs for Alternative S-l are estimated to be $338,660 which includes costs for a single sampling
event of drummed waste and stockpiled soils along with transporting and off-site disposal of the drummed
waste and the stockpiled soil. There would be no operation and maintenance costs so that the total present
worth is estimated to be $338,660.
Capital costs for Alternative S-2A are estimated to be $1,855,850. This includes the costs of the sampling
and off-site disposal described for Alternative S-l plus the costs of constructing and seeding the soil cap.
Annual operation and maintenance costs are estimated to be $2,000. The total present worth is estimated to be
$1,894,000.
Capital costs for Alternative S-3 are estimated to be $5,573,000. This includes the cost of the sampling and
off-site disposal described for Alternative S-l plus the costs of excavating and disposing of the
contaminated soils off-site. There are no annual operation and maintenance costs so that the total present
worth is estimated to be $5,573,000.
Capital costs for Alternative S-4A are estimated to be $11,963,000. This includes the costs of the sampling
and off-site disposal described for Alternative S-l plus the costs of excavating and treating the
contaminated soils on-site. There are no annual operation and maintenance costs since the treatment would be
accomplished in less than a year so that the total present worth is estimated to be $11,963,000.
Capital costs for Alternative S-4B are estimated to be $12,241,000. This includes the cost of the sampling
and off-site disposal described for Alternative S-l plus the costs of excavating and treating the
contaminated soils on-site and disposing the lead-contaminated soils off-site. There are no annual operation
and maintenance costs since the work would be accomplished in less than a year so that the total present
worth is estimated to be $12,241,000.
Groundwater
In the case of all groundwater alternatives, the costs presented below are in addition to those already
incurred to install and operate the existing interim extraction and treatment system at the Site.
Alternative GW-1 does not have any capital cost. The annual operation and maintenance costs are estimated to
be $59,336 and include costs for monitoring the groundwater. The total present worth cost is estimated to be
$912,000.
Capital costs for Alternative GW-2A are estimated to be $45,097. These costs include costs associated with
installation of underground piping from well C-l to the treatment plant. The annual operation and maintenance
costs are estimated to be $452,738. The total present worth is estimated to be $7,000,300.
Capital costs for Alternative GW-2B are estimated to be $45,097 and include costs associated with
installation of underground piping from well C-l to the treatment plant. Annual operation and maintenance
costs are estimated to be $726,336. The total present worth is estimated to be $11,209,000.
Capital costs for Alternative GW-5A are estimated to be $390,189 and include costs associated with
installation of underground piping from well C-l to the treatment plant and costs for installing piping to
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five additional extraction wells. Annual operation and maintenance costs are estimated to be $670,892. The
total present worth is estimated to be $10,699,000.
Capital costs for Alternative GW-5B are estimated to be $390,189 and include costs for installing piping to
five additional extraction wells. Annual operation and maintenance costs are estimated to be $766,336. The
total present worth is estimated to be $12,169,000.
State Acceptance
The State of New Jersey cannot concur on the preferred remedy unless its soil direct contact citeria are met
or institutional controls are established to prevent direct contact with soils above direct contact criteria.
Community Acceptance
Community acceptance of the preferred alternative will be assessed in the Record of Decision following review
of public comments received on the RI/FS report and the Proposed Plan.
PREFERRED ALTERNATIVE
Based upon an evaluation of the various alternatives, EPA recommends Alternative S-3 as the preferred
alternative for the cleanup of the soil at the Site and Alternative GW-5 as the preferred alternative for the
cleanup of the groundwater at the Site.
Soil
The preferred soil alternative, Alternative S-3, provides for excavation and off-site disposal of
approximately 18,500 cubic yards of contaminated soils, followed by backfilling with clean fill and topsoil
and seeding. The preferred remedy will allow for future unrestricted use of the Site. In addition, sediment
and surface water monitoring would be conducted to determine whether remediation of Lot IB results in a
lowering of PCB levels in the streams in Lot 1A.
The cost for the soil excavation is estimated at approximately $5,600,000 with no annual operation and
maintenance. EPA prefers Alternative S-3 over Alternative S-4(A and B) because it would provide an equivalent
level of protection at less than half the cost of Alternative 4(A and B) which is estimated at $11,963,134 -
$12,242,000. The preferred alternative will also meet all ARARs.
Off-site disposal provides a higher degree of permanence and long-term effectiveness than on-site
containment. While treatment would provide a higher degree of permanence than off-site disposal, the costs
of treatment are high in comparison to those for off-site disposal. While there are short-term impacts
associated with excavation and transportation of contaminated soil, these can be minimized through proper
planning. For instance, during design, EPA would explore the feasibility of constructing a road from the Site
which would minimize the amount of truck traffic through the surrounding neighborhood.
Groundwater
The preferred groundwater remediation alternative, Alternative GW-5, includes installation of additional
extraction wells to contain the contaminated groundwater on the Site. The selection and number of additional
extraction well to be pumped will be determined during the remedial design. The preferred alternative is
similar to the existing interim groundwater remedy except that additional extraction wells would be pumped.
The existing treatment facility would not need to be changed.
Based on groundwater flow modeling, the preferred alternative provides protection by capturing all
contaminated groundwater from the upper water bearing zone (including some off-site areas) and most of the
contamination within the middle and deep water bearing zones. The preferred remedy will extract groundwater
at more than twice the current rate and provide greater protection by capturing, containing and treating the
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contaminated groundwater. The discharge from the treatment plant would continue to be sent to the MCUA POTW.
However, if the discharge cannot be sent to MCUA, the biological treatment portion of the plant will be
brought online. The biological treatment step, will allow for direct discharge to Stream 1A.
The present worth cost of the preferred groundwater alternative is $10,700,000 (assuming discharge to MCUA)
which is $3,700,000 more than the present worth cost of the current interim remedy. These higher costs result
from a higher capital cost due to the additional extraction wells and the higher operation and maintenance
costs resulting from the increased pumping rate and the additional wells to be maintained. In the event the
biological unit is brought on line, the total present worth for the preferred remedy will increase by
$1,500,000 from the current interim remedy.
These cost estimates are based on an assumption that the system will operate for 30 years. However, it is
possible that the system will operate for longer or shorter periods depending on the results of future
monitoring. The groundwater system would be shutdown if ARARs are achieved or if monitoring results show that
further operation of the system will not reduce the concentrations in groundwater and that contaminated
groundwater will not migrate off-site at levels which are above health-based limits for the nearest
receptors. EPA will undertake additional groundwater investigations to determine if contaminated groundwater
is leaving the property boundaries.
The preferred alternatives will provide the best balance of trade-offs among alternatives with respect to the
evaluating criteria. EPA believes that the preferred alternatives will be protective of human health and the
environment, will be cost effective, and will utilize permanent solutions and alternative treatment
technologies or resource recovery technologies to the maximum extent practicable.
NEXT STEPS
After EPA has presented the preferred alternative at the public meeting and has received any comments and
guestions during the public comment period, EPA will summarize the comments and provide its responses in a
document called the "Responsiveness Summary." The Responsiveness Summary will be appended to the Record of
Decision, which will describe the final alternative selected by EPA and provide EPA's rationale for that
selection.
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Chemsol, Inc. Superfund Site
Responsiveness Summary
Appendix - D
Public Notice
Printed in The Home News and Tribune
on
August 11, 1997
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RECORD OF DECISION FACT SHEET
EPA REGION II
SITE:
Site name: Chemsol, Inc. Site
Site location: Piscataway, Middlesex County, New Jersey
HRS score: 42.,69
Listed on the NPL: September 1, 1983
Site ID #: NJD980528889
RECORD OF DECISION.
Date signed: September 18, 1998
Selected remedies: Soil Alternative 3: Excavation and off-site disposal of contaminated soil. Groundwater
Alternative 5: Installation and pumping of additional wells to treat and contain contaminated groundwater
within the property boundaries.
Operable Unit #: OU-2
Capital cost: Soil Alternative 3 - $5,573,000 (1998-$)
Groundwater Alternative 5 - $390,189
Anticipated Construction Completion: September 2002
0 & M cost: Soil Alternative 3 - $0
Groundwater Alternative 5 - $670,892 (1998 dollars for 30 year period)
Present-worth cost: Soil Alternative 3 - $ 5,573,000
Groundwater Alternative 5 - $10,699,000
Total $16,272,000
LEAD:
Site is currently fund and PRP lead - EPA is the lead agency
Primary Contact: Nigel Robinson (212) 637-4394
Secondary Contact: Lisa Jackson (212) 637-4380
Main PRPs: Union Carbide, Schering-Plough, Morton International and Tang Realty
PRP Contact: William H. Hyatt, Jr., (973) 966-8041
WASTE:
Waste type: Volatile organics, semi-volatile organics, PCBs, pesticides, metals
Waste origin: Hazardous waste
Contaminated medium: Soil and Groundwater
Origin: Dumping and recycling
Est. Waste Quantity: 25,000 cubic yds. of PCB-contaminated soils
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