United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park, NC 27711
EPA-454/R-99-001b
February 1999
AIR
&EPA
Final Report - Volume II of
Emissions Testing of Combustion
Stack and Pushing Operations at
Coke Battery No. 2 at Bethlehem
Steel Corporation's Burns Harbor
Division in Chesterton, Indiana
"V^Ist*
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FINAL REPORT
EMISSIONS TESTING OF COMBUSTION STACK AND
PUSHING OPERATIONS AT COKE BATTERY NO. 2 AT
BETHLEHEM STEEL CORPORATION'S
BURNS HARBOR DIVISION
IN CHESTERTON, INDIANA
Volume II
Appendix C
EPA Contract No. 68-D-98-004
Work Assignment No. 2-01
Prepared for;
John C. Bosch Jr. (MD-19)
Work Assignment Manager
SCGA, EMC, EMAD, OAQPS
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
February 1999
p:\sS11.0QO\fmalrpt.wpd .
Submitted by:
PACIFIC ENVIRONMENTAL SERVICES, INC.
5001 S. Miami Blvd., Suite 300
Post Office Box 12077
Research Triangle Park, NC 27709-2077
(919)941-0333 FAX (919) 941-0234
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DISCLAIMER
This document was prepared by Pacific Environmental Services, Inc. (PES) under EPA
Contract No. 68D98004, Work Assignment No. 2-01. This document has been reviewed
following PES' internal quality assurance procedures and has been approved for distribution.
The contents of this document do not necessarily reflect the views and policies of the U.S. EPA.
Mention of trade names does not constitute endorsement by the EPA or PES.
n
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TABLE OF CONTENTS
Page
1.0 INTRODUCTION 1-1
2.0 SUMMARY OF RESULTS 2-1
2.1 EMISSIONS TEST LOG 2-1
2.2 FILTERABLE PARTICULATE MATTER, METHYLENE CHLORIDE
EXTRACTABLE MATTER (MCEM), AND METALS 2-1
2.3 POLYCYCLIC AROMATIC HYDROCARBONS (PAHs) 2-22
3.0 PROCESS AND CONTROL EQUIPMENT OPERATION 3-1
3.1 INTRODUCTION 3-1
3.2 PROCESS DESCRIPTION 3-1
3.3 PROCESS AND CONTROL DEVICE MONITORING 3-4
4.0 SAMPLING LOCATIONS 4-1
4.1 COKE OVEN BATTERY NO. 2 4-1
5.0 SAMPLING AND ANALYTICAL PROCEDURES 5-1
5.1 LOCATION OF MEASUREMENT SITES AND
SAMPLE/VELOCITY TRAVERSE POINTS 5-1
5.2 DETERMINATION OF STACK GAS VOLUMETRIC FLOW RATE 5-3
5.3 DETERMINATION OF STACK GAS EMISSION RATE CORRECTION
FACTORS, DRY MOLECULAR WEIGHT, AND EXCESS AIR 5-3
5.4 DETERMINATION OF STACK GAS MOISTURE CONTENT 5-3
5.5 DETERMINATION OF PARTICULATE MATTER/METHYLENE
CHLORIDE EXTRACTABLE MATTER/METALS 5-3
5.6 POLYCYCLIC AROMATIC HYDROCARBONS 5-4
in
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TABLE OF CONTENTS (Concluded)
6.0 QUALITY ASSURANCE/QUALITY CONTROL PROCEDURES
AND RESULTS 6-1
6.1 CALIBRATION OF APPARATUS 6-1
6.2 ON-SITE MEASUREMENTS 6-5
6.3 LABORATORY ANALYSES 6-9
APPENDIX A PROCESS DATA
APPENDLX B RAW FIELD DATA
APPENDIX C ANALYTICAL DATA
APPENDIX D CALCULATIONS
APPENDIX E QA/QC DATA
APPENDIX F PARTICIPANTS
APPENDLX G SAMPLING AND ANALYTICAL PROCEDURES
IV
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LIST OF TABLES
Table 2.1 Emissions Test Log, Bethlehem Steel Corporation, Chesterton,
Indiana 2-2
Table 2.2 Particulate Matter/MCEM/Metals Emissions Sampling and Flue Gas
Parameters - Baghouse Inlet, Bethlehem Steel, Chesterton, Indiana 2-4
Table 2.3 Filterable Particulate Matter Concentrations and Emission Rates -
Baghouse Inlet, Bethlehem Steel, Chesterton, Indiana 2-5
Table 2.4 Methylene Chloride Extractable Matter Concentrations and Emission
Rates - Baghouse Inlet, Bethlehem Steel, Chesterton, Indiana 2-6
Table 2.5 Multiple Metals Concentrations and Emission Rates Baghouse Inlet,
Bethlehem Steel, Chesterton, Indiana 2-7
Table 2.6 Particulate Matter/MCEM/Metals Emission Sampling and Flue Gas
Parameters - Baghouse Outlet, Bethlehem Steel, Chesterton, Indiana 2-12
Table 2.7 Filterable Particulate Matter Concentrations and Emission Rates -
Baghouse Outlet, Bethlehem Steel, Chesterton, Indiana 2-13
Table 2.8 Methylene Chloride Extractable Matter Concentrations and Emission
Rates - Baghouse Outlet, Bethlehem Steel, Chesterton, Indiana 2-14
Table 2.9 Multiple Metals Concentrations and Emission Rates - Baghouse Outlet,
Bethlehem Steel, Chesterton, Indiana 2-15
Table 2.10 Baghouse Dust Multiple Metals Concentrations, Bethlehem Steel,
Chesterton, Indiana 2-18
Table 2.11 Filterable Particulate Matter and Methylene Chloride Extractable
Matter Removal Efficiencies, Coke Oven Battery No. 2 Baghouse,
Bethlehem Steel, Chesterton, Indiana 2-20
Table 2.12 Particulate Matter/MCEM/Metals Emissions Sampling and Flue Gas
Parameters - Underfire Stack, Bethlehem Steel, Chesterton, Indiana ... 2-21
Table 2.13 Filterable Particulate Matter Concentrations and Emission Rates -
Underfire Stack, Bethlehem Steel, Chesterton, Indiana 2-23
Table 2.14 Methylene Chloride Extractable Matter Concentrations and Emission
Rates - Underfire Stack, Bethlehem Steel, Chesterton, Indiana 2-24
Table 2.15 Multiple Metals Concentrations and Emission Rates - Underfire Stack
Bethlehem Steel, Chesterton, Indiana 2-25
Table 2.16 PAH Emissions Sampling and Flue Gas Parameters - Baghouse Inlet
Bethlehem Steel, Chesterton, Indiana 2-29
Table 2.17 PAH Concentrations and Emission Rates, Baghouse Inlet,
Bethlehem Steel, Chesterton, Indiana 2-30
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LIST OF TABLES (Concluded)
Table 2.18 PAH Emissions Sampling and Flue Gas Parameters - Baghouse Outlet
Bethlehem Steel, Chesterton, Indiana 2-34
Table 2.19 PAH Concentrations and Emission Rates, Baghouse Outlet,
Bethlehem Steel, Chesterton, Indiana 2-35
Table 2.20 PAH Emissions Sampling and Flue Gas Parameters - Underfire Stack
Bethlehem Steel, Chesterton, Indiana 2-38
Table 2.21 PAH Concentrations and Emission Rates Underfire Stack
Bethlehem Steel, Chesterton, Indiana 2-40
Table 3.1 Summary of Pushing Process and Control Device Parameters 3-4
Table 3.2A Combustion Stack Parameters Test Run No. 1, 8/14/98 3-6
Table 3.2B Combustion Stack Parameters: Test Run No. 2, 8/14/98 3-7
Table 3.2C Combustion Stack Parameters: Test Run No. 3, 8/15/98 3-8
Table 4.1 Summary of Sampling and Analytical Methods, Bethlehem Steel Corp.,
Chesterton, Indiana 4-2
Table 4.2 Summary of Sampling Locations, Test Parameters, Sampling Methods, and
Number and Duration of Tests, Bethlehem Steel Corp., Chesterton, Indiana .. 4-3
Table 4.3 PAH In-Stack Detection Limits 4-4
Table 4.4 Estimated Metals In-Stack Detection Limits 4-9
Table 5.1 Summary of Sampling Locations, Test Parameters, Sampling Methods,
and Number and Duration of Tests, Bethlehem Steel Corporation,
Chesterton, Indiana 5-2
Table 6.1 Summary of Temperature Sensor Calibration Data 6-2
Table 6.2 Summary of Pitot Tube Dimensional Data 6-4
Table 6.3 Summary of Dry Gas Meter and Orifice Calibration Data 6-6
Table 6.4 Summaryof EPA Method 315 and CARS Method 429 Field Sampling
QA/QC Data 6-8
Table 6.5 Summary of EPA Method 315 Analytical QC Data Lab Blank Analysis 6-10
Table 6.6 Summary of EPA Method 315 Analytical QC Data Field Blank Analysis ... 6-11
Table 6.7 Summaryof EPA Method 29 Analytical QC Data Lab Control Sample
(LCS) Recovery and Duplicate Analysis 6-13
Table 6.8 Summary of CARB Method 429 Analytical QC Data Field Blank
Results 6-14
Table 6.9 Summary of CARB Method 429 Analytical QC Data Lab Control
Sample (LCS) 6-15
Table 6.10 Summary of CARB Method 429 Analytical QC Data Surrogate
Standard Recoveries 6-17
VI
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LIST OF FIGURES
Figure 1.1 Key Personnel and Responsibility for Testing at Bethlehem Steel Corp.,
Chesterton, Indiana ., 1-2
Figure 3.1 Schematic Of Pushing Emission Control For Battery No. 2 3-2
Figure 4.1 Baghouse Inlet Sample Location, Bethlehem Steel Corp., Chesterton,
Indiana 4-2
Figure 4.2 Baghouse Inlet Traverse Point Locations, Bethlehem Steel Corp.,
Chesterton, Indiana 4-3
Figure 4.3 Baghouse Outlet Sample Location, Bethlehem Steel Corp., Chesterton,
Indiana 4-4
Figure 4.4 Baghouse Outlet Traverse Point Locations, Bethlehem Steel Corp.,
Chesterton, Indiana 4-5
Figure 4.5 Combustion (Underfire) Sampling Location, Bethlehem Steel Corp.,
Chesterton, Indiana 4-7
Figure 4.6 Method 1 Calculation Sheet, Combustion Stack, Bethlehem Steel Corp.,
Chesterton, Indiana 4-8
Figure 5.1 Sampling Train Schematic for EPA Method 315 5-5
Figure 5.2 Sampling Train Schematic for CARB Method 429 5-7
Figure 5.3 CARB Method 429 Sample Recovery Schematic 5-8
Figure 5.4 CARB Method 429 Analytical Schematic 5-9
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APPENDIX C
ANALYTICAL DATA
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P.O. Box 2010
Morrisville, NC 2756*
"EASTERN RESEARCH GROUP. INC. Ph.(919)468-7800
Narrative
Site: Bethlehem Steel
Prepared for: Frank Meadows (PES)
Prepared by: Link Nguyen
Description of Procedures for EPA Method 315 and Observations:
**Note: All extractions were done with toluene as opposed to Methylene Chloride
Filters -
Procedure:
The filters (including any loose particles) were transferred to a tared amber jar. The amber jars were placed into
a desiccator overnight in a temperature controlled environment. The following day, the samples were weighed
and initial weights were taken. To ensure that all conditions remained the same, the samples were placed back
into the desiccator and allowed to sit overnight and the second weighings were taken at the same time the next
day. Once constant weight had been attained, 100 mL of toluene was added to each jar. The jars were placed in i
sonicator and allowed to sonicate for 3 minutes. After sonication was complete, the samples were taken out of
the sonicator. Each sample was filtered through a buchner funnel reinforced with an additional Whatman 934-
AH filter to prevent cross contamination on the buchner funnels. Once the solutions were vacuum filtered, the
extract was placed into a triple rinsed beaker (methylene chloride solvent). The beaker containing the extract
was placed onto a hotplate at low heat and the solvent was allowed to evaporate. Once the samples almost
reached dryness, the samples were taken off the hotplate and poured into a tared aluminum pan. The beakers
were triple rinsed with toluene and then the solvent was poured into the aluminum pan. The rinse was
performed to ensure that no material remained in the beaker. The aluminum weighing pan was heated to
complete dryness, placed into a desiccator and allowed to sit in the desiccator overnight. The following day, the
samples were weighed and the weights recorded.
Observations:
The filters had a lot of loose, black particles which were also placed into the jars for PM weights. This was seen
mostly on the Inlets.
Acetone Front Half Rinse-
Procedure:
The rinses were taken and poured into tared 400 mL beakers. The beakers were triple rinsed with MeCl2. The
weights of the beakers including the rinses were taken. This gives an initial and a final weight to which the
volumes of the rinses were calculated. A separate sheet is attached explaining how the volumes were calculated.
The beakers containing the rinses were allowed to sit overnight in a hood to allow the acetone solvent to
evaporate. The next day the beakers, which now contain no solvent, were taken and placed into the dessicator.
The beakers were allowed to sit in the dessicator overnight. The next day, initial weighings for the samples were
Page 1 of 3
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taken. The samples were then allowed to sit in the dessicator again for 24 hours. The next day at approximately
the same time, the samples were weighed again for the second weighings. Once constant weight has been
attained, the weights were recorded for the Paniculate Mass (PM) portion of the analysis. Next, the beakers
were taken and 25 mL of MeCl2 was added to each beaker. Aluminum foil was placed over the tops of the
beakers. The beakers were then placed into a sonicator and allowed to sonicated for 3 minutes. This fraction will
be combined with the MeCl2 Front Half Rinse.
Observations:
No observations out of the ordinary were noted.
Methylene Chloride Front Half Rinse-
Procedure:
The rinses were taken and poured into tared 400 mL beakers. The beakers were triple rinsed with MeCl2. The
weights of the beakers including the rinses were taken. This gives an initial and a final weight to which the
volumes of the rinses were calculated. At this point, the extracts from the Acetone Front Half Rinse were
combined with this fraction. The combined fractions were placed onto a hotplate and allowed to heat gently at a
low temperature setting. Once the solution has almost reached dryness, the solution was poured into a tared
aluminum pan. The pan was then was placed back onto the hotplate and taken to complete dryness. The pans
were then transferred to the dessicator and allowed to sit overnight. The following day, the samples were
weighed and the weights recorded.
Observations:
No observations out of the ordinary were noted.
Impinger, Back Half Water-
Procedure:
Each sample was then poured into a clean, 1000 mL separatory funnel. Once in the separatory funnel, the amber
jars containing the original samples were triple rinsed with toluene and then poured into the separatory funnel.
The approximate volume of this rinse is 50 mL. The samples were then shaken for 1 minute. After 1 minute, the
bottom water layer was drained into a clean, 1000 mL amber jar. After the water was drained, the remaining
toluene layer was emptied into a clean 250 mL beaker. An additional 25 mL of toluene was added. The solution
was then shaken for another minute and the bottom water layer was drained into the same 1000 mL amber jar.
This was repeated once more. Once the third shake was completed, and the remaining toluene layer was drained
into the 250 mL beaker, the beaker was placed onto a hotplate and was gently heated to evaporate the solvent.
Once the solution was almost to dryness, the solution was transferred to a tared aluminum pan. The pan was
then placed back onto the hotplate and heated to complete dryness. Afterwards, the pans were placed into the
dessicator to sit overnight. The following day, the pans were weighed and the weights recorded.
Observations:
No observations out of the ordinary were noted.
Page 2 of 3
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Acetone, Back Half Rinse-
Procedure:
The exact same procedure was used for the Back Half Rinse as was used for the Front Half Rinse, The only
difference was that since PM analysis was not required, when the solvent dried down in the beaker, constant
weight was not taken for these samples. After the solvent had evaporated, 25 mL of toluene was added to each
beaker and sonicated for 3 minutes each. The rest of the procedure was the same as that of the Acetone Front
Half Rinse.
Observations:
No observations out of the ordinary were noted.
Methylene Chloride, Back Half Rinse-
Procedure:
The solution was poured into a tared beaker. After the solution had been poured into the beaker, another weight
was taken to calculate the volume. Once the volume had been determined, the samples were placed onto a
hotplate to heat the sample to dryness. Once the sample was dried, 25 mL of toluene was added to the beakers.
The beakers were sonicated for 3 minutes. Once sonicated, the samples were filtered through the buchner
funnel. The extract was placed into a clean, 250 mL beaker. The beaker containing the rinse was placed onto a
hotplate and gently heated almost to dryness. Once the rinse was almost dry, the solution was transferred to a
tared aluminum pan. The pans were placed back onto the hotplate and the solution heated to complete dryness.
Once the pans were dry, the aluminum pans were transferred to a desiccator and allowed to sit overnight. The
following day, the pans were weighed and the weights recorded.
Observations:
No observations out of the ordinary were noted.
Field Reagent Blanks-
Procedure:
The samples were poured into tared beakers. Weights were taken after the reagent blank rinses were poured in.
These final weights were used to calculated the volumes of the reagent blanks. The reagent blanks were allowed
to sit on a hotplate at low heat. After the solvents had evaporated, the final weights of the beakers with any
contents remaining were taken. Particulate Mass was calculated. For the filter blank, 100 mL of methylene
chloride was added to the beaker and sonicated for 3 minutes. Afterwards, the methylene chloride was filtered
and poured into a clean beaker. The beaker containing the solvent was heated down to near dryness. The solvent
was then transferred to a tared aluminum pan. The pan was placed onto the hotplate and reduced to dryness. The
pan was desiccated and weights recorded the next day.
Observations:
No observations out of the ordinary were noticed.
Laboratory Reagent Blanks-
Page 3 of 3
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Procedure:
The same procedures were used for Laboratory Reagent blanks as for the Field Reagent Blanks. Solvents that
were used during the extraction process were tested in the reagent blank, A filter from the same lot that was sent
to the field was used to go through the extraction process.
Observations:
No observations out of the ordinary were noticed
Page 4 of 3
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Matrix = FILTERS
Meadows-Final
81003
Method = PM
Sample ID:
B-I-M315-1-F (080798-05)
B-I-M315-1-F (080798-16)
B-I-M315-2-F (080798-04)
B-I-M315-2-F (080798-19)
B-I-M315-3-F (080798-11)
B-I-M315-3-F (080798-15)
B-I-M315-FB-F (080798-2)
B-O-M315-1-F (080798-06)
B-O-M315-2-F (080798-23)
B-O-M315-3-F (080798-22)
B-OM315-FB-F (080798-24) '
B-U-M315-1-F (080798-17)
B-U-M315-2-F (080798-12)
B-U-M315-3-F (080798-01)
B-U-M315-FB-F (080798-07)
Weight of
Petri dish (g)
168.7107
169.1583
162.9469
175.7047
160.6746
163.3534
172.1577
172.5921
166.2064
149.5202
181.8306
147.9548
166.9930
170.3177
168.0875
Filter Pre-
weight (g)
0.32825
0.32116
0.31677
0.32332
0.32119
0.31589
0.32242
0.32402
0.32027
0.31509
0.33064
Q.31669
0.32378
0.32254
0.32563
Final wt. Of
filter+dish (g)
170.7471
170.3306
165.0058
177.6603
162.3930
164.9029
172.4818
172.9172
166.5295
149.8357
182.1624
148.3507
167.4157
170.7125
168.4190
Final weight of
filter PM (g)
1.7081
0.8511
1.7421
1.6323
1.3972
1.2336
0.0017
0.0011
0.0028
0.0004
0.0011
0.0792
0.0989
Q.Q722
0.0058
Method =
Sample ID:
MCEM
Weight of
Alum, pan (g)
B-I-M31 5-1 -F (080798-05)
B-I-M31 5-1 -F (080798-1 6)
B-I-M31 5-2-F (080798-04)
B-1-M31 5-2-F (080798-1 9)
B-I-M31 5-3-F (080798-11)
B-I-M31 5-3-F (080798-1 5)
B-I-M315-FB-F (080798-2)
B-O-M315-1-F
B-O-M31 5-2-F
B-OM31 5-3-F
B-O-M315-FB-F
B-U-M315-1-F
B-U-M31 5-2-F
B-U-M31 5-3-F
B-U-M315-FB-F
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
1.6590
1.6590
1.6535
1 .6491
1.6367
1 .6555
1 .6450
1.6415
1.6429
1.6427
1.6435
1.6332
1.6401
1.6522
1.6232
Weight after
evaporation (g)
1.6595
1.6593
1.6535
1.6494
1.6382
1.6560
1.6453
1.6418
1.6435
1.6427
1.6437
1.6335
1.6402
1.6522
1.6232
Final weight of
MCEM (g)
0.0005
0.0003
O.OOQO
0.0003
0.0015
0.0005
0.0003
0.0003
0.0006
0.0000
0.0002
0.0001
0.0000
0.0000
Page 1 of 4
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Meadows-Final
Matrix =
Method =
Sample ID:
B-I-M315-1-FH-A
B-I-M315-2-FH-A
B-I-M315-3-FH-A
B-I-M315-FB-FH-A
B-O-M315-1-FH-A
B-O-M315-2-FH-A
B-O-M315-3-FH-A
B-O-M315-FB-FH-A
B-U-M315-1-FH-A
B-U-M315-2-FH-A :
B-U-M315-3-FH-A
B-U-M315-FB-FH-A
Matrix =
Method =
Sample ID:
B-I-M315-1-FH-M
B-I-M315-2-FH-M
B-I-M315-3-FH-M
B-I-M315-FB-FH-M
B-O-M315-1-FH-M
B-O-M315-2-FH-M
B-O-M315-3-FH-M
B-O-M315-FB-FH-M
B-U-M315-1-FH-M
B-U-M315-2-FH-M
B-U-M315-3-FH-M
B-U-M315-FB-FH-M
Acetone FHR
EM
Volume of
liquid (ml_)
267.4
339.2
303.2
121.9
129.7
227.1
299.8
149.6
229.8
236.5
201.3
139.0
Methvlene Chloride
MCEM
Weight of
Alum, pan (g)
10 1.6506
11 1.6571
12 1.6543
13 1.6422
14 1.6212
15 1,6169
16 1.6354
17 1.6238
18 1.6195
19 1.6472
20 1.6551
21 1 .6451
Weight of
beaker (g)
175,8228
155.0218
165.0352
178.5494
179.0007
166.2611
179.7362
170.3356
165.7417
178.6304
164.5489
167.2803
FHR
Weight after
evaporation (g)
1.6528
1.6583
1.6560
1.6423
1.6231
1,6178
1.6380
1.6247
1,6599
1.6786
1.7924
1,6454
Final weight of
rinse (g)
175.9928
155.3708
165.1712
178.5516
179.0069
166.2652
179.7436
170.3371
165.8741
178.7571
164.8105
167.2825
Final weight of
filter PM (g)
0.1700
0.3489
0.1360
0.0022
0.0061
0.0041
0.0074
0.0014
0.1324
0.1267
0.2616
0.0022
Final weight of
MCEM (g)
0.0022
0.0012
0.0017
D.OOQ1
0.0019
0.0009
0.0026
0.0009
0.0404
0.0314
0.1373
0.0003 o
Page 2 of 4
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Meadows-Final
Matrix =
Method =
Sample ID:
B-1-M315-1-BH-A
B-I-M315-2-BH-A
B-I-M315-3-BH-A
B-I-M315-FB-BH-A
B-O-M315-1-BH-A
B-O-M315-2-BH-A
B-O-M315-3-BH-A
B-O-M315-FB-BH-A
B-U-M315-1-BH-A
B-U-M315-2-BH-A
B-U-M315-3-BH-A
B-U-M315-FB-BH-A
Matrix =
Method =
Sample ID:
B-I-M315-1-BH-M
B-1-M315-2-BH-M
B-I-M315-3-BH-M
B-1-M315-FB-BH-M
B-O-M315-1-BH-M
B-O-M315-2-BH-M
B-O-M315-3-BH-M
B-O-M315-FB-BH-M
B-U-M315-1-BH-M
B-U-M315-2-BH-M
B-U-M315-3-BH-M
B-U-M315-FB-BH-M
Acetone BHR
MCEM
1
2
3
4
5
6
7
8
9
10
11
12
Volume of Weight of
liquid (mL) Alum, pan (g)
408.0 1.6436
349.1
348,4
263,2
56.0
177.9
263.6
190.5
147.8
202.8
165.6
120.2
1 .5877
1.6713
1.6485
1.6396
1.6753
1.6550
1.0260
1.0324
1.0330
1.0305
1.0244
Methvlene Chloride BHR
MCEM
Volume of Weight of
liquid (mL) Alum, pan (g)
1 231.2 0.9950
2
3
4
5
6
7
8
9
10
11
12
244.9
228.1
204.1
75.4
199.6
132.7
250.1
82.5
143.8
132.1
136.4
0.9969
0.9985
0.9953
1.0178
1.0197
1.0176
1.0163
1.0160
1.0164
1.0257
1.0150
Weight after
evaporation (g)
1.6460
1.5893
1.6726
1.6485
1.6402
1.6766
1 .6558
1 ,0260
1 .0325
1 .0335
1.0310
1 .0244
Weight after
evaporation (g)
0.9969
1.0013
0.9991
0.9954
1.0178
1.0199
1 .0202
1.0163
1.0160
1.0168
1.0258
1.0150
Final weight of
MCEM (g)
0.0024
0.0016
0.0013
0.0000
0.0006
0.0013
0.0008
0.0000
0.0001
0.0005
0-0005
0.0000
Final weight of
MCEM (g)
0.0019
0.0044
0.0006 •
0.0001
0.0000
0.0002
0.0026
0.0000
. 0.0000
0.0004
0.0001
0.0000
Page 3 of 4
-------
Matrix =
Method =
Sample ID:
B-I-M315-1-IMPH20
B-1-M315-2-IMPH20
B-I-M315-3-1MPH20
B-1-M315-FB-IMPH20
B-0-M315-1-1MPH20
B-0-M315-2-IMPH20
B-O-M315-3-IMPH20
B-O-M315-FB-IMPH20
B-U-M315-1-IMPH20
B-U-M315-2-IMP H20
B-U-M315-3-IMP H20
B-U-M315-FB-1MPH20
H20 Impinger rinses
MCEM
Weight of
Alum, pan (g)
13
14
15
16
17
18
19
20
21
22
23
24
1.6011
1.6170
1.6060
1.6549
1 .6460
1.6645
1.6595
1 .6426
1.6232
1.6084
1.6739
1.6291
Meadows-Final
Weight after
evaporation (g)
1.6041
1.6206
1.6090
1,6565
1.6486
1.6673
1.6599
1.6427
1.6235
1.6086
1.6742
1.6291
81003
Final weight of
MCEM (g)
0.0030
0.0036
0.0030
0.0016
0.0026
0.0028
0.0004
0.0001
0.0003
0.0002
0.0003
0.0000
Matrix =
Method =
Sample ID;
B-LB-F
Sample ID:
B-LB-Acetone
B-LB-MeCI2
B-LB-H20
Method =
Sample ID:
B-LB-F
Weight of
Petri dish (g)
171.0074
Volume of
liquid (mL)
199.6
203.1
199.6
MCEM
Weight of
Alum, pan (g)
1.6526
Final wt. Of
filter+dish (g)
171.3363
Weight of
beaker(g)
177.4500
176.8191
175.6222
Weight after
evaporation (g)
1.6526
Filter Pre-weight
(9)
0.32563
Final weight of
rinse (g)
177.4502
176.8192
175.6223
Final weight of
filter PM (g)
0.0032
Final weight of
filter PM (g)
0.0002
0.0000
0.0001
Final weight of
MCEM (g)
0.0000
Page 4 of 4
-------
ANALYTICAL REQUEST AND CHAIN OF CUSTODY
PROJECT*:
RECOVERY
PERSON:
SAMPLE
SAMPLE IDENTIFICATION
COLLECTION
DATE TIME
SAMPLE NAME
NUMBER OF
CONTAINERS
»ANALYTICAL REQUEST
\
/
1
COMMENTS
tpMtal pnpamton.
Bfwcial handling. «te.)
-7
V
7
(
e
£0.
X
^ - —
(o
VIZ;
•-B-i
i-
REUNQUISHER'S NAM
RECEIVER'S NAME
DATEfllME
DATE/TIME
RECEIVER'S SIGNATURE
SHIPPER'S NAME AND ID NUMBER.
-------
U.S. EPA - Bethlehem Steel - Chesterton, Indiana - S506.000
Master Sample Log
Sample Run
No.
Date/Time
Sample Description
Liquid Level
Marked/
Sealed
Being
Stored
Below 4°C
*//*
J-J-
tfttfa
* /
/ m^
f
2.
fM,
ft
*#. &* £L fa*.
63071 $'
Kff. A* tit At
flu
ft
*.
5^
-------
U.S. EPA - Bethlehem Steel - Chesterton, Indiana - S506.000
Master Sample Log
Sample Run
No.
Date/Time
Sample Description
r. H.
Liquid Level
Marked/
Sealed
Being
Stored
Below 4°C
S
?&,* 0*0*79-06
f#
Mf fed
- 2-3
fff.
* ZZ-
fact,,
8%
Page of
/
-------
U.S. EPA - Bethlehem Steel - Chesterton, Indiana - S506.000
Master Sample Log
Sample Run
No.
Date/Time
Sample Description
Liquid Level
Marked/
Sealed
Being
Stored
Below 4'C
G/Ii/98
fin
_i£
x.
er/r*
ft/
fa
Page J of
-------
U.S. EPA - Bethlehem Steel - Chesterton, Indiana - S506.000
Master Sample Log
Sample Run
No.
/./ M
Date/Time
i*,k*
Sample Description
/r6*r OBo7n-o7
$&4tWL*
AU&*
#PU **ut. A.O
$
Liquid Level
Marked/
Sealed
Being
Stored
Below 4°C
Page
-------
-------
First Analytical Laboratories
ANALYSIS REPORT
Metals Residues
Project # S511.000
Indiana Coke Oven
Prepared for;
/
Pacific Environmental Services, Inc.
560 Herndon Parkway; Suite 200
Herndon, VA 20170-5240
Reviewed and Appro ved^y:
William H. Wadlin, Ph. D.
Laboratory Manager
October 26, 1998
-------
First Analytical Laboratories
CASE NARRATIVE
Project #: 81003 Report Date: 26-Oct-98
Client: Pacific Environmental Services, Inc.
Client Project ID: S511.000
Samples:
Twelve sets of samples were submitted for determination of various metals.
A blank filter was also provided which required the same analyses. Each set
consisted of a filter and several aluminum pans in which extracts of the filters had
been dried for a gravimetric measurement already performed by another laboratory.
The target elements were antimony, arsenic, barium, beryllium, cadmium,
chromium, cobalt, copper, lead, manganese, mercury, nickel, phosphorus,
selenium, silver, thallium and zinc. All of the samples were hand delivered in good
condition, with no apparent damage.
Preparation:
Since there is no standard method for preparation of such samples, some
method development effort was required. In particular, we did not initially know
how best to remove the residues from the pans quantitatively, without removing any
of the base material of the pan itself.
For the initial trials we selected the set identified as B-1-M315-3, as it had
visible material in each pan, including a variety of physical appearances. A few
milliliters of water were added to each pan and allowed to stand for ten minutes.
This had no visible effect on the residues, neither removing or softening any of the
residues. Similar treatment with dilute nitric acid had no useful effect either. The
residues were probed with a plastic spatula to determine whether it would now come
loose from the pan. Most of the residues seemed to be stiff, tacky tars. Since the
materials could be smudged and, to some extent, scraped up with the spatula, we
decided to use the corresponding filters themselves to wipe up the residues. This
was most effective, since the filters were to be combined with the residues anyway.
This also avoided the problem of quantitatively cleaning a tarry spatula, (much like
the initial problem of cleaning the tarry pan).
The procedure adopted was to wrap a portion of one of the sample filters
around the end of a clean spatula, and use this assembly to swab all of the residue
-------
out of all of the corresponding pans of the sample subset. This cleaning was
facilitated by the fortuitous finding that the filters were still damp with solvent which
appeared to soften the residues. It was then possible to use another filter portion for
a second cleaning, taking up any film of desired residue missed by the first swab.
When the pans were cleaned of residue in this way, and all of the residue was
on the filters, the filter portions used and any remaining unused were placed in a
beaker for digestion. The samples were then prepared according to EPA Method
3050A, which is a nitric acid digestion.
A remaining issue was that one set of pans had been treated with dilute nitric
acid in the method development effort, while the others had not been so treated.
Thus we treated a blank pan with dilute nitric acid in the same way and used all of
the washings so derived to create a blank for this aspect of B-1-M315-3 only. In the
report it is the one called "Blank Pan". In the raw data it is called RB-AP for
"reagent blank; Acid-washed Pan". It was gratifying to find after the analysis that
this special blank did not show any noteworthy hits for the target elements.
Analysis:
Cadmium, manganese, lead (inlets only), and zinc were determined by Direct
Aspiration Flame Atomic Absorption Spectrophotometry (FLAA). Antimony,
arsenic, beryllium, lead (O, U, and blanks), nickel, selenium, silver and thallium
were determined by Graphite Furnace Atomic Absorption Spectrophotometry
(GFAA). Barium, chromium, cobalt, copper and phosphorus were determined by
Inductively Coupled Plasma - Optical Emission (ICP).
Results:
The results are reported as total micrograms in the whole combination of
original samples for each subset. All of the target elements were detected in all of
the inlet samples. Antimony, beryllium, chromium, cobalt, mercury and phosphorus
were not found on any of the samples other than the inlets. The highest levels were
found for lead and zinc.
Quality Control:
Traces of barium, cadmium, manganese, lead and zinc were found in the
blank filter. None of these are unusual. They are commonly found on blank filters
at these low levels. In all cases, many of the O and U samples are indistinguishable
from these blank levels, meaning that after blank correction, we cannot show the
presence of such elements in the corresponding residues.
The spike recoveries were all within the normal range of 70% to 130%. The
-------
duplicates were all within the normal limit of 20% for all cases in which the sample
level is more than five tunes the detection limit. If the sample level is lower than
this it is not possible to make a meaningful evaluation of the deviation between the
duplicates,
-------
First Analytical Laboratories
1126 Burning Tree Dr. Chapel Hill, NC 27514
Tel. (919) 942-8607
FAX (919) 929-8688
ANALYSIS REPORT
Project #: 81003
Client: Pacific Environmental Services
Client Project ID: S511.000
Report Date: 26-Oct-98
Date Received: 06-Oct-98
Sample
B-O-M315-1
B-O-M315-2
B-O-M315-3
B-O-M315-FB
B-U-M315-1
B-U-M315-2
B-U-M315-3
B-U-M315-FB
B-I-M315-1
B-I-M315-2
B-I-M315-3
B-UM315-FB
BLANK PAN
BLANK FILTER
Total Micrograms in Combined Sample
Sb
GFAA
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
4.3
3.7
3.4
<0.5
<0.5
<0.5
As
GFAA
<0.5
<0.5
<0.5
<0.5
4.8
4.0
5.8
<0.5
62.9
81.8
92.3
<0.5
<0.5
<0.5
Ba
ICP
1.2
1.5
0.8
1.1
1.2
2.6
1.3
1.4
27.4
35.7
28.4
1.6
<0.2
0.8
Be
GFAA
<0.02
<0.02
<0.02
<0.02
<0.02
<0.02
<0.02
<0.02
0.96
1.07
1.02
<0.02
<0.02
<0.02
Cd
FLAA
1.8
1.4
1.7
2.0
1.9
1.6
1.1
1.8
3.0
3.8
4.3
2.0
1.9
1.7
Cr
ICP
<2.5
<2.5
<2.5
<2.5
<2.5
<2.5
<2.5
<2.5
6.0
9.7
6.8
<2.5
<2.5
<2.5
Spikes
% Recovery
Duplicates
%RPD
QC SUMMARY
94%
85%
96%
91% 97% 85%
0.0%
-------
11/12/98 08:01
w 11 98 Q8:OSp
^5134886618
323-8KB8
First Analytical Laboratories
1126 Burning Tree Dr. Chapel Hffl, NC 27514
Tel- (919) 942-5607
FAX (919) 9ZW68B
ANALYSIS REPORT
Project*; 8T003
Client; Pacific Environmental Services
Client Project ID: S511.000
Report Date: 26-Oct-98
Date Received: 06-Oct-98
Sample
B-0-M315-1
B-O-M315-2
B-O-M315-3
B-O-M315-FB
B-U-M315-1
B-U-M315-2
B-U-M315-3
B-U-M315-FB
B-I-M3T5-1
B-NM315-2
B-J-M315-3
B-I-M315-FB
BIANK PAN
SUNK FILTER
Total Micrograms in Combined Sample
Co
ICP
<2
<2
<2
<2
<2
<2
<2
<2
3
5
3
<2
2
<2
Cu
ICP
<2
2
<2
<2
<2
3
2
<2
14
21
20
<2
<2
<2
Mn
F1AA
3
7
3
3
3
3
1
2
42
46
44
3
3
3
Hg
CVAA
<0.4
< 0.4
<0.4
<0.4
<0.4
<0.4
<0.4
<0.4
0,50
0.60
0.50
<0.4
<0.4
< 0.4
Pb
FUUVGFAA
0.8
0.5
0.5
0.5
4.1
3.6
2.7
0.6
103
153
128
0.6
0.3
0.7
Mi
GFAA
<0.5
0.9
<0.5
<0.5
<0.5
<0.5
<0.5
<0.5
87.0
86.5
61.4
<0.5
<0,5
<0.5
Spikes
% Recovery
Duplicates
%RPD
QC SUMMARY
88% 89% 95%
0.0%
95%
98%
98%
2.6%
86%
-------
First Analytical Laboratories
1126 Burning Tree Dr. Chapel Hill, NC 2V514
Tel. (919) 942-8607
FAX (919) 929-8688
ANALYSIS REPORT
Project #: 81003
Client: Pacific Environmental Services
Client ProjectlD:S511.000
Report Date: 26-Oct-98
Date Received: 06-Oct-98
Sample
B-O-M315-1
B-0-M315-2
B-O-M315-3
B-O-M315-FB
Total Micrograms in Combined Sample
p
ICP
< 10
< 10
< 10
< 10
Se
GFAA
<0.3
0.5
<0.3
<0.3
Ag
GFAA
<0.2
2.1
< 0.2
< 0.2
Tl
GFAA
< 0.3
< 0.3
< 0.3
<0.3
Zn
FLAA
8.3
11.7
7.8
10.0
B-U-M315-1
B-U-M315-2
B-U-M315-3
B-U-M315-FB
B-I-M315-1
B-I-M315-2
B-I-M315-3
B-I-M315-FB
< 10
< 10
< 10
< 10
2.3
2.0
1.0
<0.3
< 0.2
< 0.2
<0.2
< 0.2
0.9
<0.3
1.0
< 0.3
12.7
11.8
10.1
10.3
40
45
43
< 10
14.4
21.1
19.1
< 0.3
0.3
0.6
0.4
0.2
3.7
4.9
4.6
< 0.3
178
242
228
13
BLANK PAN
BLANK FILTER
< 10
< 10
< 0.3
< 0.3
0.2
0.2
<0.3
<0.3
10.0
10.9
Spikes
% Recovery
Duplicates
%RPD
QC SUMMARY
83% 103% 106%
88%
104%
9.8%
-------
ANTIMONY
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #:81003
Dote: 26-Oct-98
Sample ID
Client
FAL
B-O-M315-1 81003.O1
B-0-M315-2 81003.02
B-0-M315-3 81003.03
B-O-M315-FB 81003.OB
B-U-M315-1 81003.U1
B-U-M315-2 81003.U2
B-U-M315-3 81003.U3
B-U-M315-FB 81003.UB
B-I-M315-1 81003.11
B-I-M315-2 81003.12
B-I-M315-3 81003.13
B-I-M315-FB 81003.IB
BLANK PAN
BLANK FILTER
81003.RBAP
81003.RBF
Test
Sol'n
W/L
-2.5
-4.7
3.1
-0.9
-3.5
3.8
0.6
-3.5
42.6
37.2
33.7
-3.7
-2.4
-1.2
Digte
Cone
WJ/L
-2.5
-4.7
3.1
-0.9
-3.5
3.8
0.6
-3.5
42.6
37.2
33.7
-3.7
-2.4
-1.2
Postdig'n
Dil'n
IDL = 5 fjg/L
spike cone. 100 pg/L
Init. Vol.
FV Factor Vol. Dig'd
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
100
ml ml
1 <
1 <
1 <
1 <
1 <
1 <
1 <
1 <
1
1
1
1 <
1 <
1 <
Total
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
4.3
3.7
3.4
0.5
0.5
0.5
SPIKE
81003.O1 S
93.9
%REC
93.9%
-------
ARSENIC
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #:81003
Dale: 26-Oct-98
IDL =
Postdig'n spike cone.
5
1 00 pg/L
Sample ID
Client
B-O-M315-1
B-O-M315-2
B-O-M315-3
B-O-M315-FB
B-U-M315-1
B-U-M315-2
B-U-M315-3
B-U-M315-FB
B-1-M315-1
B-I-M315-2
B-I-M315-3
B-I-M315-FB
BLANK PAN
BLANK FILTER
FAL
81003.O1
81003.O2
81003.O3
81003.OB
81003.U1
81003.U2
81003.U3
81003.UB
81003.11
81003.12
81003.13
81 003. IB
8 1003. REAP
81003.RBF
Test
Sol'n
MI/L
0.3
2.2
4.8
1.9
47.5
40.3
57.8
2.1
125.7
163.6
184.6
2.8
1.8
-1.9
Digte
Cone
W3/L
0,3
2.2
4.8
1.9
47.5
40.3
57.8
2.1
628.5
818.0
922.8
2.8
1.8
-1.9
Dil'n Init.
FV Factor Vol.
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
100
ml
1
1
1
1
1
1
1
1
5
5
5
1
1
1
Vol. Total
Dig'd pig
ml
< 0.5
< 0.5
< 0.5
< 0.5
4.8
4.0
5.8
< 0.5
62.9
81. B
92.3
< 0.5
< 0.5
< 0.5
SPIKE
81003.O1 S
85.1
%REC
85.1%
-------
BARI UM
ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #;81002
Date: 26-Oct-98
Sample ID
Client
FAL
B-O-M315-1 81003.O1
B-O-M315-2 81003.O2
B-O-M315-3 81003.O3
B-O-M315-FB 81003.OB
B-U-M315-1 81003.U1
B-U-M315-2 81003.U2
B-U-M315-3 81003.U3
B-U-M315-FB 81003.UB
B-I-M315-1 81003.11
B-I-M315-2 81003.12
B-I-M315-3 81003.13
B-I-M315-FB 81003.IB
BLANK PAN 81003.RBAP
BLANK FILTER 81003.RBF
Test
Sol'n
pgA
12
15
8
11
12
26
13
14
274
357
284
16
-1
8
Digte
Cone
yg/L
12
15
8
11
12
26
13
14
274
357
284
16
-1
8
Postdig'n
Dil'n
IDL =
spike cone.
Init.
FV Factor Vol.
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
100
ml
1
1
1
1
1
1
1
1
1
1
1
1
1
1
2/ig/L
1000 pg/L
Vol. Total
Dig'd tig
ml
1.2
1.5
0.8
1.1
1.2
2.6
1.3
1.4
27.4
35.7
28.4
1.6
< 0.2
0.8
SPIKE
81003.O1 S
968
%REC
95.6%
-------
BERYLLIUM
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj, #-.81003
Date: 26-CM-98
IDL =
Postdig'n spike cone.
0,15pg/L
5.00 /Jg/L
Sample ID
Client
B-O-M315-1
B-O-M315-2
B-O-M315-3
B-O-M315-FB
B-U-M315-1
B-U-M315-2
B-U-M315-3
B-U-M315-FB
B-I-M315-1
B-I-M315-2
B-I-M315-3
B-1-M315-FB
BLANK PAN
BLANK FILTER
FAL
81003.O1
81003.O2
81003.O3
S1003.OB
81003. Ul
81003.U2
81003.U3
81003.UB
81003.11
81003.12
81003.13
81003. IB
81003.RBAP
81003.RBF
Test
Sol'n
Pg/L
0.02
0.05
0.00
-0.03
0.06
0.17
0.12
0.02
9.57
10.73
10.17
0.03
-0.02
-0.01
Digte
Cone
M9/L
0.02
0.05
0.00
-0.03
0.06
0.17
0.12
0.02
9.57
10.73
10.17
0,03
-0.02
-0.01
FV
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
100
DilVi Init. Vol.
Factor Vol. Dig'd
ml ml
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Total
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.96
1.07
1.02
0.02
0.02
0.02
SPIKE
81003.O1S
4.56
%REC
91.2%
-------
CADMIUM
FLAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #:81002
Date: 26-Oct-98
Sample ID
Client
FAL
B-O-M31S-1 81003.O1
B-O-M315-2 81003.O2
B-O-M315-3 81003.O3
B-O-M315-FB 81003.OB
B-U-M315-1 81003.U1
B-U-M315-2 81003.U2
B-U-M31S-3 81003.U3
B-U-M315-FB 81003.UB
B-I-M315-1 81003.11
B-I-M315-2 81003.12
B-I-M315-3 81003.13
B-I-M315-FB 81003.IB
BLANK PAN
BLANK FILTER
SPIKE
DUPLICATE
81003.RBAP
81003.F
81003.11 S
81003.O2D
1DL =
Postdig'n spike cone.
Test
Sol'n
Itg/l
18
14
17
20
19
16
11
18
30
38
43
20
19
17
418
14
Digte
Cone
wfl-
18
14
17
20
19
16
11
18
30
38
43
20
19
17
FV
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
100
DiTn Init.
Factor Vol.
ml
1
1
1
1
1
1
1
1
1
1
1
1
1
1
% REC 97.0%
%RPD 0.0%
5 Jifl/L
400 |ig/L
Vol. Total
Dig'd fig
ml
1.8
1.4
1.7
2,0
1.9
1.6
1.1
1.8
3.0
3.8
4.3
2.0
I-9
1.7
-------
CHROMIUM
ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81002
Date: 26-Oct-98
Sample ID
Client
FAL
B-O-M315-1 81003.O1
B-O-M315-2 81003.O2
B-O-M315-3 81003.O3
B-O-M315-FB 81003.OB
B-U-M315-1 81003.U1
B-U-M315-2 81003.U2
B-U-M315-3 81003.U3
B-U-M315-FB 81003.UB
B-I-M315-1 81003.11
B-1-M315-2 81003.12
B-I-M315-3 81003.13
B-1-M315-FB 81003 .IB
BLANK PAN
BLANK FILTER
8 1003. REAP
81003.RBF
Test
Sol'n
pg/L
-17
.4
-21
-32
_2
-5
4
-25
60
97
68
-26
-32
-32
Digte
Cone
yg/L
-17
_4
-21
-32
_2
-5
4
-25
60
97
68
-26
-32
-32
Postdig'n
Dil'n
IDL =
spike cone.
Init.
FV Factor Vol.
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
100
ml
1
1
1
1
1
1
1
1
1
1
1
1
1
1
25 jug/L
2000 j/g/L
Vol.
Dig'd
ml
<
<
<
<
<
<
<
<
<
<
<
Total
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
6.0
9.7
6.8
2.5
2.5
2.5
SPIKE
81003.O3 S
1761
%REC
85.1%
-------
COBALT
ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #:81002
Date: 26-Oct-98
IDL = 20 pg/L
Postdig'n spike cone. 1000 j/g/L
Sample ID
Client
FAL
Test Dig'te
Sol'n Cone
//g/L /jg/L
B-O-M315-1
B-O-M315-2
B-0-M315-3
B-O-M315-FB
B-U-M315-1
B-U-M315-2
B-U-M315-3
B-U-M315-FB
B-I-M315-1
B-I-M31 5-2
B-I-M315-3
B-I-M315-FB
BLANK PAN
BLANK FILTER
81003.O1
81003.02
81 003,03
81003.OB
81003.U1
81003.U2
81003.U3
81003.UB
81003,11
81003.12
81003,13
81003.IB
81003.RBAP
81003.RBF
3
5
9
13
7
8
5
12
34
45
31
8
24
4
3
5
9
13
7
8
5
12
34
45
31
8
24
4
Dil'n Init. Vol. Total
FV Factor Vol. Dig'd fig
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
100
ml
1
1
1
1
1
1
1
1
1
1
1
1
1
1
ml
< 2,0
< 2.0
< 2.0
< 2.0
< 2.0
< 2.0
< 2,0
< 2.0
3.4
4.5
3.1
< 2.0
2,4
< 2.0
SPIKE
81003.O3S
881
%REC
88.1%
-------
COPPER
1CP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #; 81002
Dafe: 26-Oct-98
Sample ID
Client
FAL
B-O-M315.1 B70Q3.O1
B-O-M315-2 81003,02
B-O-M315-3 81003.O3
B-O-M315-FB 81003.OB
B-U-M315-1 81003.U1
B-U-M315-2 81003.U2
B-U-M315-3 81003.U3
B-U-M315-FB 61003.UB
B-I-M315-1 81003.11
B-I-M315-2 81003J2
B-I-M315-3 61003,13
B-I-M315-FB 81003.IB
Test
Sol'n
IDL
Postdig'n spike cone.
Digte Dil'n tnh.
Cone FV Factor Vol.
//g/L mJ ml
20
2000 fig/L
BLANK PAN
BLANK FILTER
81003.RBAP
81003.RSF
12
20
9
7
19
30
21
10
143
212
203
11
2
11
12
20
9
7
19
30
21
10
143
212
203
11
2
n
100
100
100
100
100
100
100
100
100
100
100
100
TOO
100
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Vol.
Dig'd
ml
Total
2.0
2.0
2.0
2.0
2.0
3.0
2.1
2.0
14.3
21.2
20.3
2-0
2.0
2.0
SPIKE
DUPLICATE
81003.O3S
8 1003. 02 D
1775
%REC
%RPD
88.8%
NA
-------
MANGANESE
FLAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #;81002
Date: 26-Oct-98
Sample ID
Client
FAL
B-O-M315-1 81003.O1
B-O-M315-2 81003.O2
B-O-M315-3 81003.O3
B-O-M315-FB 81003.OB
B-U-M315-1 81003.U1
B-U-M315-2 81003.U2
B-U-M315-3 81003.U3
B-U-M315-FB 81003.UB
B-I-M315-1 81003,11
B-I-M315-2 81003.12
B-I-M315-3 81003.13
B-1-M315-FB 81003.IB
BLANK PAN
BLANK FILTER
SPIKE
DUPLICATE
81003.RBAP
81003.RBF
81003.11 S
81003.O2 D
IDL =
Postdig'n spike cone.
Test
Sol'n
M/L
28
65
34
26
29
31
14
24
421
458
444
27
27
25
800
65
Digte
Cone
WJ/L
28
65
34
26
29
31
14
24
421
458
444
27
27
25
FV
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Dil'n Init.
Factor Vol.
ml
1
1
1
1
1
1
1
1
1
1
1
1
1
1
% REC 94.8%
%RPD 0.0%
lOj/g/L
400jug/L
Vol. Total
Dig'd //g
ml
2.8
6.5
3.4
2.6
2.9
3.1
1.4
2.4
42.1
45.8
44.4
2.7
2.7
2.5
-------
MERCURY
CVAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #:81002
Date: 26-Oct-98
1DL = 0.20 tig/I
Postdig'n spike cone. 5.00 pg/L
Sample ID
Client
B-O-M31 5-1
B-O-M315-2
B-O-M315-3
B-O-M315-FB
B-U-M315-1
B-U-M315-2
B-U-M315-3
B4J-M315-FB
B-1-M315-1
B4-M315-2
B-I-M315-3
B-I-M315-FB
BLANK PAN
BLANK FILTER
FAL
81003
81003
81003
81003
81003
81003
81003
81003
81003
81003
81003
81003
81003
81003
.01
.02
.03
.OB
,U1
,U2
.U3
.UB
.11
.12
.13
.IB
.REAP
.RBF
Test
Sol'n
pg/L
0.02
-0.02
-0.06
-0.01
0.16
-0.01
0.17
-0.01
0.23
0.30
0.25
0.00
-0.04
0.02
Digte
Cone
pg/L
0.02
-0.02
-0.06
-0.01
0.16
-0.01
0.17
-0.01
0.23
0.30
0.25
0,00
-0.04
0.02
Dil'n
F¥ Factor
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
100
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Init. Vol.
Vol. Dig'd
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
100
ml
5 <
5 <
5 <
5 <
5 <
5 <
5 <
5 <
5
5
5
5 <
5 <
5 <
Total
Pi
0.4
0.4
0.4
0.4
0.4
0.4
0.4
0.4
0.5
0.6
0.5
0.4
0.4
0.4
SPIKE
81003.O3S
4.75
%REC
95.0%
-------
LEAD
FLAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81002
IDL =
Postdig/n spike cone.
100
2000
Dote; 26-Oct-9S
Sample ID
Client
B-O-M315-1
B-O-M315-2
B-0-M315-3
B-O-M315-FB
B-U-M315-1
B-U-M315-2
B-U-M315-3
B-U-M315-FB
B-I-M315-1
B-I-M315-2
B-I-M315-3
B-I-M315-FB
BLANK PAN
BLANK FILTER
SPIKE
DUPLICATE
FAL
81003.O1
81003.O2
81003.O3
81003.OB
81003.U1
81003.U2
81003.U3
81003.UB
81003.11
81003.12
81003.13
81003. IB
81003.RBAP
81003.F
81003.11 S
81003.12 D
Test Dig'te
Sol'n Cone
pg/L pg/L
0
0
0
0
0
0
0
0
1030 1030
1530 1530
1280 1280
0
0
0
2980
1570
FV
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Dil'n Init.
Factor Vol.
ml
1
1
1
1
1
1
1
1
1
1
1
1
1
1
% REC 97.5%
%RPD 2.6%
Vol.
Dig'd
ml
Total
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
103.0
153.0
128.0
10.0
10.0
10.0
-------
LEAD
6FAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Pro], #: 81002
Date; 26-Oct-98
IDL m 3 pg/L
Postdtg'n spike cone. TOO Jig/l
Sample ID
Client
B-O-M315-1
B-O-M315-2
B-O-M315-3
B-O-M315-FB
B-U-M315-1
B-U-M315-2
B-U-M315-3
B-U-M315-FB
B-1-M315-1
B-I-M315-2
B-I-M315-3
B-I-M315-FB
BLANK PAN
BLANK FILTER
SPIKE
DUPLICATE
FAL
81003.O1
81003.O2
81003.O3
81003.OB
81003.U1
81003.U2
81003.U3
81003.UB
81003.11
81003.12
81003.13
81 003. IB
81003.RBAP
81003.F
81003.O1 S
81003.12 D
Test
Sol'n
W/l
7.8
5.0
4.6
4.8
41.4
36.4
27.4
5,5
5.7
3.0
7.3
105,9
Digte
Cone
M9/L
7.8
5.0
4.6
4.8
41.4
36.4
27.4
5.5
0.0
0.0
0.0
5.7
3.0
7.3
FV
ml
TOO
100
100
100
100
100
100
100
100
100
100
100
100
TOO
Dil'n Init. Vol.
Factor Vol. Dig'd
ml ml
1
1
1
1
1
1
1
1
1
1
1
1
1
1
%REC 98.1%
%RPD ERR
Total
0.8
0.5
0.5
0.5
4.1
3.6
2.7
0.6
0.6
0.3
0.7
-------
NICKEL
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81003
Date: 26-Oct-98
IDL*
Postdig'n spike cone.
100 //g/L
Sample ID
Client
B-O-M315-1
B-O-M315-2
B-O-M315-3
B-O-M315-FB
B-U-M315-1
B-U-M315-2
B-U-M315-3
B-U-M315-FB
B-I-M315-1
B-I-M315-2
B-I-M315-3
B-I-M315-FB
BLANK PAN
BLANK FILTER
FAL
81003.O1
81003.O2
81003.O3
81003.OB
81003.U1
81003.U2
81003.U3
81003. UB
81003.11
81003.12
81003.13
81 003. IB
81003.RBAP
81003.RBF
Test
Sol'n
M/L
-13.7
9.2
-7.0
-2.5
4.9
1.3
-0.2
2.7
173.9
172.9
122.7
-2.9
-3.5
-1.8
Digte
Cone
MJ/L
-13.7
9.2
-7.0
-2.5
4.9
1.3
-0.2
2.7
869.5
864.5
613.5
-2.9
-3.5
-1.8
FV
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Dil-n Init.
Factor Vol.
ml
1
1
1
1
1
1
1
1
5
5
5
1
1
1
Vol.
Dig'd
ml
<
<
<
<
<
<
<
<
<
<
Total
j/g
0.5
0.9
0.5
0.5
0.5
0.5
0.5
0.5
87.0
86.5
61.4
0.5
0.5
0.5
SPIKE
81003.O1 S
86.0
%REC
86.0%
-------
PHOSPHORUS
1CP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #: 81002
Dote: 26-Oct-98
Sample ID
Client
FAL
B-O-M315-1 81003.O1
B-O-M315-2 81003.O2
B-O-M315-3 81003.O3
B-O-M315-FB 81003.OB
B-U-M315-1 81003.U1
B-U-M315-2 81003.U2
B-U-M315-3 81003.U3
B-U-M315-FB 81003.UB
B-KM315-1 81003.11
B-I-M315-2 81003.12
B-I-M315-3 81003.13
B-I-M315-FB 81003.IB
BLANK PAN
BLANK FILTER
81003. REAP
81003.RBF
IDL= lOOjUg/L
Postdig'n spike cone. 2000 jUg/L
Test
Sol'n
/^gA
-21
8
11
-8
87
25
69
-25
397
446
426
8
-77
23
DJg'te
Cone
M9A
-21
8
11
-8
87
25
69
-25
397
446
426
8
-77
23
FV
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Dil'n In'rt. Vol.
Factor Vol. Dig'd
ml ml
1 <
1 <
1 <
1 <
1 <
1 <
1 <
1 <
1
1
1
1 <
1 <
1 <
Total
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
39.7
44.6
42.6
10.0
10.0
10.0
SPIKE
81003.OSS
1661
%REC
83.1%
-------
SELENI UM
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client; PES
Proj. #: 81003
Date: 26-Oct-98
Sample ID
Client
FAL
B-O-M315-1 81003.O1
B-O-M315-2 81003.O2
B-O-M315-3 81003.O3
B-O-M315-FB 81003.OB
B-U-M315-1 81003.U1
B-U-M315-2 81003.U2
B-U-M315-3 81003.U3
B-U-M315-FB 81003.UB
B-I-M315-1 81003.11
B-I-M315-2 81003.12
B-I-M315-3 81003.13
B-I-M315-FB 81003.IB
BIANK PAN
BUNK FILTER
81003.RBAP
81003.RBF
IDL =
Postdig'n spike cone.
Test
Sol'n
yg/L
0.6
4.8
0.6
2.4
22.7
19.6
10.3
-0.2
28.8
42.1
38.3
0.0
-1.0
0.4
Digte
Cone
pg/L
0.6
4.8
0.6
2.4
22.7
19.6
10.3
-0.2
144.2
210.7
191.3
0.0
-1.0
0.4
FV
ml
100
100
100
100
100
100
100
100
100
100
100
100
100
100
Dil'n In it.
Factor Vol.
ml
1
1
1
1
1
1
1
1
5
5
5
1
1
1
3 pg/L
50 pg/L
Vol. Total
Dig'd pg
ml
< 0.3
0.5
< 0.3
< 0.3
2.3
2.0
1.0
< 0.3
14.4
21.1
19.1
< 0.3
< 0.3
< 0.3
SPIKE
81003.O1 S
51.6
%REC 103.2%
-------
SILVER
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Prof. #; 81003
Dote; 26-Oct-98
IDL = 2.00 /jg/L
Postdig'n spike cone, 10.00 jig/I
Sample ID
Client
B-O-M315-1
B-O-M315-2
B-O-M315-3
B-O-M315-FB
B-U-M315-1
B-U-M315-2
B-U-M315-3
B-U-M315-FB
B-I-M315-1
B-I-M315-2
B-1-M315-3
B-1-M315-FB
BLANK PAN
BLANK FILTER
FAL
81003.O1
81003.O2
8 1003 .03
81003.OB
81003.U1
81003.U2
81003.U3
81003.UB
81003.11
81003.12
81003.13
81003.IB
81003.RBAP
81003.RBF
Test
Sol'tt
WJ/L
1.46
20.67
-0,40
1.49
-1.25
-1.59
-1.46
-0,97
3.08
5.93
4.04
-1.06
-1.27
-1.07
Digte
Cone
lig/L
1.46
20.67
-0.40
1.49
-1.25
-1.59
-1.46
-0.97
3.08
5.93
4.04
-1.06
-1.27
-1.07
FV
ml
100
100
100
100
TOO
TOO
100
100
100
100
100
100
100
100
Dil'n Init. Vol.
Factor Vol. Dig'd
ml ml
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Total
0.20
2.07
0.20
0.20
0.20
0.20
0.20
0.20
0.31
0.59
0,40
0.20
0.20
0.20
SPIKE
81003.O1 S
10.56
%REC 105,6%
-------
THALLIUM
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #:81003
Date: 26-Oct-98
Sample ID
Client
FAL
B-O-M315-1 81003.O1
B-O-M315-2 81003.O2
B-O-M315-3 81003.O3
B-O-M315-FB 81003.OB
B-U-M315-1 81003.U1
B-U-M315-2 81003.U2
B-U-M315-3 81003.U3
B-U-M315-FB 81003.UB
B-I-M315-1 81003.11
B-I-M315-2 81003.12
B-I-M315-3 81003.13
B-I-M315-FB 81003.IB
BLANK PAN
BLANK FILTER
81003.RBAP
81003.RBF
Test
Sol'n
MI/L
-2.5
1.9
0.9
1.5
8.6
2.8
10.3
-0.7
36.5
49.3
46.2
-0.8
-0.5
-2.1
Dig'te
Cone
pg/L
-2.5
1.9
0.9
1.5
8.6
2.8
10,3
-0.7
36.5
49.3
46.2
-0,8
-0.5
-2.1
Postdig'n
Dil'n
1DL = 3 /ig/L
spike cone. 50 /ig/L
Init. Vol.
FV Factor Vol. Dig'd
ml
100
100
100
100
100
100
100
100
100
100
100
100
TOO
100
ml ml
1 <
1 <
<
<
<
1 <
1
1
1
1 <
1 <
1 <
Total
0.3
0.3
0.3
0.3
0.9
0.3
1.0
0.3
3.7
4.9
4.6
0.3
0.3
0.3
SPIKE
81003.O1 S
44.2
%REC
88.4%
-------
ZINC
FLAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj. #:81002
Dale: 26-Ocl-98
Sample ID
Clierrf
FAL
B-O-M315-1 81003.O1
B-O-M315-2 81003.O2
B-O-M315-3 81003.O3
B-O-M315-FB 81003.OB
B4J-M315-1 81003.U1
B-U-M315-2 81003.U2
B-U-M315-3 81003.U3
B-U-M315-FB 81003.UB
B-I-M315-1 81003.11
B-I-M315-2 81003.12
B-I-M315-3 81003.13
B-I-M315-FB 81003.IB
BLANK PAN 81003.RBAP
BLANK FILTER 81003.RBF
SPIKE
DUPLICATE
81003.11 S
81003.O2 D
Test
SoPn
08/L
83
117
78
100
127
118
101
103
356
483
455
128
100
109
772
129
Digte
Cone
AJg/L
83
117
78
100
127
118
101
103
1780
2415
2275
128
100
109
i
IDL =
Postdig'n spike cone.
Dii'n In it.
FV Factor Vol.
ml ml
100 1
100 1
100 1
100 1
100 1
100 1
100 1
100 1
100 5
100 5
100 5
100 1
100 1
100 1
%REC 104.0%
%RPD 9.8%
10 /Jg/L
400 pg/L
Vol. Total
Dig'd }ig
ml
8.3
11.7
7.8
10.0
12.7
11.8
10.1
10.3
178.0
241.5
227.5
12,8
10.0
10.9
-------
Client PES
Proj»#:ffl0030nd81006
Dote: 26-Oct-98
Calibration Data
ARSENIC
QUALITY CONTROL DATA
Abs, True cone., pig/L
Blank
Standard 1
Standard 2
Standard 3
Standard 4
0.000
0.028
0.128
0.238
0.441
0.0
10.0
50.0
100.0
200.0
Calibration Verifications
ICV=100 103.1
ICB = 0 2.1
CCV2 =100
CCB2 = 0
107.2
4.6
CCV1 =100
CCB1 m 0
110.0
0.9
CCV3 =100
CCB3 = 0
111.2
2.8
-------
Client: PES
Proj, #: 81003 and 81006
Date: 26-Oct-98
ANTIMONY
QUALITY CONTROL DATA
Calibration Data
Abs, True cone., jUg/L
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Calibration Verifications
ICV= 100
ICB = 0
CCV1 = 100
CCB1 = 0
0.000
O.QT6
0.081
0.153
0.285
97,3
3.2
97.6
-3.9
0,0
10.0
50.0
100.0
200.0
CCV2 = TOO
CCB2 = 0
CCV3 = 100
CCB3 - 0
CCV4 = 100
CCB4 = 0
104.1
-0,8
111.0
-5.7
101.0
-5.9
-------
BARIUM
QUALITY CONTROL DATA
Client: PES
Proj, #: 81002 and 81006
Date: 26-Oct-98
Calibration Data
Emiss. True cone.,
Blank 32 0
Standard 1 54 20
Standard 2 739 500
Standards 1397 1000
Standard 4 2754 2000
Calibration Verifications
ICV=1000 967 CCV2 = 1000 1116
ICB = 0 0 CCB2 = 0 0
CCV1 =1000 1057
CCB1 = 0 1
-------
Client: PES
Proj. #-.81003 and 81006
Date; 26-Oct-98
Calibration Data
BERYLLIUM
QUALITY CONTROL DATA
Abs. True cone.,
Blank
Standard 1
Standard 2
Standard 3
Standard 4
0.000
0.012
0.043
0.105
0.175
0.0
0.5
2,0
5.0
10.0
Calibration Verifications
)CV = 5
ICB = 0
5,07
0.16
CCV2 = 5
CCB2 = 0
5.15
0.05
CCV1 = 5
CCB1 = 0
4.83
-0.01
CCV3 = 5
CCB3 = 0
5.07
0.08
CCV4 = 5
CCB4 m 0
-------
CADMIUM
FLAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEE
Client: PES
Proj. #:81002
Date: 26-Oct-98
Calibration Data
Abs. True cone., jug/L
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Standard 5
Calibration Verifications
ICV = 500
ICB = 0
CCV1 = 500
CCB1 = 0
0.000
0.017
0.032
0.064
0.151
0.295
522
3
495
1
0
50
100
200
500
1000
CCV2 = 500
CCB2 = 0
511
3
-------
Client: PES
Pro]. #: 81002 and 81006
Date: 26-Oct-98
CHROMIUM
QUALITY CONTROL DATA
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Emiss. True cone.,/Ljg/L
603 0
758 100
3049 1000
5860 2000
13550 5000
Calibration Verifications
ICV = 2000 1829
1CB = 0 -14
CCV2 = 2000
CCB2 = 0
2107
-14
CCV1 = 2000 2124
CCB1 =0 -9
-------
Client: PES
Proj. #; 81002 and 81006
Date: 26-Oct-98
CHROMIUM
QUALITY CONTROL DATA
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Emiss. True cone., /ig/L
510 0
679 100
2957 1000
5337 2000
12453 5000
Calibration Verifications
ICV = 2000 1981
ICB = 0 -20
CCV2 = 2000
CCB2 = 0
2121
-25
CCV1 = 2000 1842
CCB1 = 0 -24
-------
Client; PES
Proj. #: 81003 and 81006
Date: 26~Oet-98
COBALT
QUALITY CONTROL DATA
Calibration Data
Emiss. True cone,,
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Calibration Verifications
ICV - 500
ICB = 0
CCV1 « 500
CCB1 = 0
336
375
440
709
1519
500
14
493
15
0
20
50
150
500
CCV2 = 500
CCB2 = 0
CCV3 = 500
CCB3 = 0
510
14
530
10
-------
Client: PES
Proj. #: 81003 and 81006
Date: 26-Oct-98
COPPER
QUALITY CONTROL DATA
Calibration Data
Emiss. True cone., //g/L
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Calibration Verifications
ICV = 2000
ICB = 0
CCV1 = 2000
CCB1 = 0
1285
2949
18473
36484
89349
1998
8
2127
13
0
100
1000
2000
5000
CCV2
CCB2
CCV3
CCB3
CCV4
CCB4
= 2000
= 0
= 2000
= 0
= 2000
= 0
2248
11
2106
13
2017
11
-------
LEAD
FLAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES
Proj, #: 81002
Date: 26-Oct-98
Calibration Data
Abs. True cone.,
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Standard 5
Calibration Verifications
ICV = 2000
ICB = Q
CCV1 * 2000
CCB1 m 0
0.000
0,003
0.007
0,015
0,029
0,073
1950
10
1950
-20
0
200
500
1000
2000
5000
CCV2 = 2000
CCB2 = 0
CCV3 = 2000
CCB3 = 0
1940
-30
-------
LEAD
FLAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEE
Client: PES
Proj. #:81002
Date: 26-Oct-9S
Calibration Data
Abs. True cone, pg/l
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Calibration Verifications
ICV= TOO
ICB = 0
CCV1 = 100
CCB1 =0
0.000
0.022
0.120
0.233
0.414
101.4
1.6
101.7
-1.4
0
10
50
100
200
CCV2 = 100
CCB2 = 0
CCV3 = 100
CCB3 = 0
99.4
1.1
107.4
5,1
-------
Client: PiS
Proj. #: 81002 and 81006
Date; 26-Oct-98
MANGANESE
QUALITY CONTROL DATA
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Standard 5
Calibration Verifications
ICV = 500
ICB = 0
Abs. True cone,,
0,000
0.006
0,013
0,026
0.065
0,125
0
50
100
200
500
1000
496
0
CCV2 = 500
CCB2 = 0
497
.7
CCV1 = 500
CCB1 * 0
483
1
-------
Client: PES
Proj. #: 81003 and 81006
Date: 26-Oct-98
MERCURY
QUALITY CONTROL DATA
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Standard 5
Calibration Verifications
ICV = 5
ICB = 0
Abs. True cone., fig/L
0.000
0.010
0.025
0.042
0.125
0.278
0.00
0.50
1.00
2.00
5.00
10.00
4,79
-0.13
CCV2 = 5
CCB2 - 0
4.76
-0.06
CCV1 = 5
CCB1 » 0
4.53
-0.18
CCV3 = 5
CCB3 = 0
4.42
-0.09
CCV4 = 5
CCB4 = 0
4.95
-0.09
-------
Client: PES
Proj. #: 81003 and 81006
Date: 26-Oct-98
NICKEL
QUALITY CONTROL DATA
Calibration Data
Abs, True cone., ffg/L
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Calibration Verifications
ICV= TOO
ICB = 0
CCV1 » 100
CCB1 = 0
0.000
0.030
0.082
0.173
0.340
108.0
3.1
87.4
-1,0
0.0
20,0
50.0
100.0
200.0
CCV2 = 100
CCB2 = 0
CCV3 = 100
CCB3 = 0
89.7
-3.3
88.4
-4.2
-------
Client: PES
Proj, #: 81003 and 81006
Date: 26-Oct-98
PHOSPHORUS
QUALITY CONTROL DATA
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Standard 5
Calibration Verifications
1CV = 2000
ICB = 0
Emiss. True cone., /Jg/L
316 0
369 200
558 1000
518 2000
1567 5000
6099 20000
2010
21
CCV2 = 2000
CCB2 = 0
2043
61
CCV1 = 2000 1934
CCB1 =0 99
CCV3 = 2000
CCB3 -0
2039
-56
CCV4 = 2000
CCB4 = 0
1960
-43
-------
SELENI UM
QUALITY CONTROL DATA
Client: PES
Proj. #: 81003 and 81006
Dote: 26-CM-98
Calibration Data
Abs, True cone., /lg/L
Blank 0.000 0,0
Standard! 0.017 10.0
Standard 2 0.049 25.0
Standard 3 0.097 50.0
Standard 4 0.206 100.0
Calibration Verifications
1CV = 50 50.4 CCV2 = 50 53.3
ICB = 0 -4.3 CCB2 = 0 -0.3
CCV1=50 51.7 CCV3 = 50 54.1
CCB1 =0 2.1 CCB3 = 0 6.4
-------
Client: PES
Proj. #: 81003 and 81006
Date: 26-Oct-98
SELENIUM
QUALITY CONTROL DATA
Calibration Data
Abs. True cone., f/g/L
Blank
Standard 1
Standard 2
Standard 3
Standard 4
fications
ICV = 50
ICB = 0
CCV1 = 50
CCB1 - 0
0.000
0.008
0.046
0.086
0.171
50.8
2.1
50.9
1.7
0.0
10.0
25.0
50.0
100.0
CCV2 - 50
CCB2 = 0
CCV3 - 50
CCB3 = 0
-------
Client: PES
Proj. #: 81003 and 81006
Date: 26-Oct-98
SILVER
QUALITY CONTROL DATA
Calibration Data
Abs. True cone., /ug/L
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Fications
ICV = 20
ICB = 0
CCV1 = 20
CCB1 m 0
0.000
0.096
0.191
0.383
0.544
20.2
-1.0
19.5
-1.1
0.0
5.0
10.0
20.0
30.0
CCV2 = 20
CCB2 = 0
CCV3 = 20
CCB3 = 0
18.6
-1.1
18.6
-1.3
-------
Client: PES
Proj. #: 81003 and 81006
Date: 26-Od-98
THALLIUM
QUALITY CONTROL DATA
Calibration Data
Abs. True cone., pg/L
Blank
Standard 1
Standard 2
Standard 3
Standard 4
fi cations
ICV = 50
ICB = 0
CCV1 = 50
CCB1 = 0
0.000
0.017
0.030
0.079
0.149
48.9
-2.6
48.6
-0.3
0.0
10.0
20.0
50.0
100.0
CCV2
CCB2
CCV3
CCB3
CCV4
CCB4
= 50
= 0
= 50
= 0
= 50
= 0
49.7
-0.5
46.9
-0.3
54.3
-2.0
-------
Client; PES
Proj.*; 81002 and 81006
Date: 26-Oct-98
ZINC
QUALITY CONTROL DATA
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Standard 5
Calibration Verifications
ICV = 500
ICB = 0
Afas. True cone,/Jg/L
0.000
0,035
0.056
0,091
0.205
0.367
0
50
100
200
500
1000
488
3
CCV2 = 500
CCB2 = 0
478
0
can = 500
CCB1 = 0
501
-4
-------
•~B. BEL,
'•a!, e: 1C,-'15/90
>ata File:
echniaue: HOA
Element: Sb
Time: 10:00
ID/Wt File: 81002. IDUI
Calib. Type: Linear
Wavelength! 217.<
Slit: 0-7 L
Lamp Current: O
Energy: 3B
ID: BLANK
Sen. No.: OO14B
A/S Pos.
Date: 10/15,
ieolicate 1
'eak Area (A-s): 0.010
)ackqround Pk Area (A-s): 0.127
Hank Corrected Pk Area (A-s): -0.000
Concentration (ug/L ): -0.1
!eol icate 2
'eak Area (A-s): -O.004
lackaround Pk Area (A-s): O.138
Hank Corrected Pk, Area (A-s): -O.014
Concentration (ua/L ): —9.1
Time: 10:02
Peak Height (A): 0.020
Backqround Pk Heiaht (A): 0.082
Time: 10:O6
Peak Height (A): O.018
Backoround Pk Heiaht (A): O.088
lean Cane (ug/L ):
luto-zero performed .
-4.6
3D: 6.35
RSD C/.): 139. <
TO: 10 PPB
Sea. No.: O0149
A/S Pos.: 1
Date: 10/15-
ienl icate 1
'eak Area (A-s): 0.024
lackaround Pk Area (A-s)J 0.123
(lank Corrected Pk Area (A-s): O.O21
loncentration (ug/L ): 12.9
icats 2
Area (A-s): O.014
lackaround Pk Area (A-s): O.134
Hank Corrected Pk Area (A-s): O.O11
loncentration (ua/L ): 7.O
Time: 10:O9
Peak Height (A): 0.040
Background Pk Height (A): 0.083
Time: 1O:12
Peak Height (A): 0.035
Backaround Pk Heiaht (A): 0.073
lean Cone Cua/L )s
9.9
SD: 4.20
RSD (7.): 42.3<
itandard number 1 aoolied. C1O.O]
Correlation coefficient: l.OOOOO
Slope: 0.0016
Date: 10/15/
ib
ID: 50 PPB
Sea. No,
00150
A/S Pos.: 2
len 1 i cate 1
'eak Area (A-s): O.OB3
iackaround Pk Area (A-s)s 0.129
Hank Corrected Pk Area (A-s): O.OBO
Concentration (ug/L ): 50.2
?en 1 i cate 2
5eak Area (A-s): O.OB5
lackoround Pk Area (A-s): 0.136
Hank Corrected Pk Area (A-s>: O.OB1
Concentration (ug/L ): 51.2
Time: 10:15
Peak Height (A): 0.127
Background Pk Height (A): 0.079
Time: 10:19
Peak Height (A): 0.130
Background Pk Height (A)
0.075
-------
ean Cone (ua/L
5O.7
u i /. ; : j.
tandard number 2 applied. [50.01
orrelation coefficient: 0.99999
Slope: O.OO16
ID: 100 PPB
Sea. No,
00151
A/S Pos.: 3
Date: 1O/15
enlicate 1
eak Area (A-s): 0.153
Backaround Pk Area (A-s): 0.143
lank Corrected Pk Area (A-s): O.150
oncentration (ug/L ): 93.2
'ep 1 icate "2
'eak Area (A-s)s 0.159
iackqround Pk Area (A-s): O.136
ilank Corrected Pk Area (A-s): 0.155
oncentration (uo/L ): 96.4
Time; 10:22
Peak Height (A): O.22O
Backaround Pk Heiaht (A): O.OS7
Time: 10:25
Peak Height (A): O.241
Backaround Pk Height (A): O.O72
lean Cone (ua/L ) :
94.8
SD: 2.26
RSD < 7.) : 2 . 38
standard number 3 applied. C100.0]
iorrelation coefficient: 0.99925
Slope: 0.0015
;b
ID: 2OO PPB
5en. Na,
: 0.151
(A-s): O.2BB
186.4
'eak Area (A-s): 0.285
lacknround Pk Area (A-s): 0.152
Hank Corrected Pk Area (A-s): O.281
)oncentration (ua/L ): 1B2.0
O0152
A/S Pos.s 4
Date: 10/15,
feolicate 1
'eak Area (A-s): 0.291
iackoround Pk Area (A-s)
tlank Corrected Pk Area
.'Dncentratian (ua/L ):
Time: 10:28
Peak Height (A): 0.396
Background Pk Height (A): O.O78
Time: 10:32
Peak Height (A): 0.396
Backoround Pk Height (A): 0.081
lean Cone (ug/L );
184.2
Standard number 4 applied. [200.0]
iorrelation coefficient: O.99817
SD: 3.07
Slope: 0.0015
RSD(X): 1.67
-------
calibration -
a a
2CD.D
-------
9ta ID: JCV Sea. No.: O0153 A/S Pos . : 5 Date: 10/1=
^eolicate 1 . Time: 10:38
Concentration (ug/L ): 100.5
^eolicate 2 Time: 1O:41
Concentration (ua/L ): 94.1
"lean Cone (ug/L >: 97.3 SD : 4 . 54 RSD ('/.): 4.67
1C sample is within range 79.5 - 120.49
•
Th ID: ICB Sea . No.: 00154 A/S Pos.: 0 Date: 10/15
^eolicate 1 Time: 1O:45
Concentration (ua/L ): 4.6
2 Time: 10-.4B
Concentration (ua/L ): 1.8
Cone (uq/L ): 3.2 SD : i.95 RSD ( 7. ) : 61.0
1C samnle is within range -15.49 - 15.49
Tb !D: B1002.B-1 Sea. No.: O0155 A/S Pos.: 6 Dates 10/15
^eolicate 1 Time: 1O:51
Concentration (ua/L )s 2.1
2 Time: 10:54
Doncentration (ug/L ): -4.1
Mean Cone (ua/L ); -1.0 SD: 4.36 RSD (7.): 43O.1
/
•i
Rta ID: 81.O02.8-1 Sea. No.'; OO1S6 A/S Pos.: 7 Date: 10/15
Replicate 1 Time: 10:58
Concentration (uo/L ): -0=3
o 1 i cats 2. Time; 11:01
Concentration (ua/L ): 4.S
lean Cone fuq/L ): 2.3 SD: 3.63 RSD ('/.): 159. <
Sb ID: 81002. 8-1 Sea. No.: 00157 A/S Pos.; 7 Date: 10/15,
Reolicate 1 Times 11:04
Concentration fua/L ): 94.9
2 . Time: 11:08
Concentration iun/L )s 104.6
Mean Cone (ua/L ): 99.7 SD: 6.95 RSD ( 7. ) : 6 . B6
-------
Recovery is 97.57.
ID: S1.OO2.9-1
Sea. No.
-oncentration (ua/L
i rate 2
Zoncentration iua/L )
lean Cone (ua/L ) :
5b TD: 810O2.10-1
3eolicate 1
3nncentration (ua/L )
1.9
3.0
2.5
O0158 A/S Pos,
Time: 11:11
Time: 11:14
3D: 0.75
8
Datej 10/15
RSDC/.): 3O.61
-1.5
i cate 2
Concentration (ua/L )
•lean Cone (ua/L ):
B^»*\,^,i^^,»\,^,"V^»^^»^^»^»*\»*V\*^«^**VW^»^»1*^»*W*W1**W^^^»*\»*\»*\»*V^f^****V*W'
Sea. No.: 00159 A/S Pos.: 9 Date: 1O/15
Times 11:17
Time: 11:21
5.2
l.S
5D: 4.72
RSDC/.): 258. <
b TD: 81002. B-2A
eol icate 1
oncentration (uq/L )
Sea. No.
: -2.0
Concentration (uq/L )
•lean Cone (ua/L ):
4.8
-3.4
00160 A/S Pos.
Time: 11:24
Time: 11:27
SD: 1.99
1O Dates 1O/15,
RSD (*/.)! 58. 5<
11 Date: 10/15,
nh TD: 81002. 1-2A
^eolicate 1
Zoncentration (uo/L )
i cate 2
Concentration (uq/L )
lean Cone fua/L )s
2.4
-1.7
Sea. No./: OO1A1 A/S Pos,
Time: 11:31
Time: 11:34
0.4
SD: 2.96
RSDC/.): 830."
=ih TD: Q1O02.1-2A
Replicate 1
Concentration (uq/L )
Sea. No,
Toncentration (uq/L )
lean Cone (ua/L ):
is 99.67.
1OO.O
99.8
99.9
00162 A/S Pos,
Time: 11:37
Time: 11:40
SD: 0.16
11 Date: 10/15,
RSDC/.): 0.16
-------
in ID: 91002.2-2A
?eolicate 1
Concentration nl icate 2
Concentration (ua/L ): -0.6
Sea. No.: 00167 A/S Pos.: 14 Date: 10/15,
Time: 12:O9
Time: 12:12
lean Cone (uo/L 1: -2.4
SD: 2.64
RSD ('/.) : 1O8 .',
-------
TD: B1QO3.RB-F Sep. No.: OO168 A/S Pos . : 15 Date: 1O/15
1 Time: 12:16
Concentration (ua/L ): -1.9
3*=olicate 2 ' Time: 12:19
Doncentrstion
-------
-Concentration (uq/L ): 91.6.
*(?olicate 2 Time: 12:5O
Concentration
-------
Sb ID: S1OO3.U1
Reolicate 1
Concentration (uq/L
Sea. No.:
Concentration (ua/L
Mean Cone (ua/L ):
): -4.5
): -2.5
-3.5
0017B A/S Pos,
Time: 13:19
Time: 13:23
SD: 1.41
22 Date: 10/15
BSD ('/. ) s 40.9
Sb TD; 81003.Ul
Reolicate 1
Concentration (ua/L ): 71.6
Sea. No.: O0179 A/S Pos.: 22
Time: 13:26
Concentration (up/L ): 93.5
Mean Cone (uo/L ): 82.5
Recovery is 85.97.
Time: 13:29
SD: 15.53
Date: 10/15
RSDC/.): 18.8:
^h TD: BIO03.U2
Renlicate 1
Concentration (uq/L ): 3.8
pb=,n} f.cate 2
Concentration (ug/L ): 3.B
Mean Cone (ua/L )5
Sea. No.: 001BO A/S Pos.: 23 Date: 1O/15
Time: 13:32
Time: 13:36
SD: 0.00
RSDC/.): O.OB
TDs 81003. U3
icate 1
Concentration (ua/L
1: -2.1
n 1 i c 31 <= 2
Concentration (uo/L ): 0.9
Mean Cone fua/L ): -0.6
Sea. No.: OO181 A/S Pos.: 24 Date: 10/15=
Time: 13:39 '
Time: 13:42
SD: 2.09
RSDC/.): 364.
TD: 81OO3.I
Renlicate 1
Concentration
i c
OO182 A/S Pos.: 25 Date: 10/15
Time: 13:46
Time: 13:49
Concentration (ua/L ): ySS.3
Mean Con/C (ua/L ): / 17.
SD: 29.99
RSDC/.): 174.
-------
ID: 81003.11
Sea. Mo
Concentration (uq/L ): 46.4
1 icate 2
r.oncentration fua/L ): 38. 8
lean Cone (ua/L ):
42.6
00183 A/S Pos,
Time: 13:54
Time: 13:57
SD: 5.39
25 Date: 10/1
RSD ('/.): 12.,
=?h ID: 81.003.12
Reolicate 1
Concentration (ua/L ): 36.O
Sea. No.: 00184 A/S Pos.: 26 Date: 10/1'
Time: 14:01
Concentration (uo/L ): 38.3
Mean Cone fua/L Is 37.2
Time: 14:O4
SD: 1.65
RSD i •/.)•. 4.4'
Sta TD: B1003.I3
Reol icate 1
Concentration (ua/L
Reo 1 i ca'te 2
Cnncentration (ua/L
Mean Cone t'uq/L 5
): 38.1
): 29.
Sea. No.: O01S5 A/5 Pos.: 27
Timei 14:07
Time: 14:10
5.7 SD: 6.29
Date: 10/if
RSDC/.):
^hr TD: CCV
Realicate 1
Concentration
-------
Rb ID: 81OO6.1 Sea. No.: 001B8 A/S Pos.: 28 Date: 1O/15
Reolicate 1 Time: 14:26
Concentration (ua/L ): O.4
Rf=nlicste 2 Time: 14:3O
Concentration (ua/L ): 6.0
Mean Cone (ua/L ): 3.2 SD: 3.97 RSD ( % ) : 122.!
*b TD: 91006.1 Sea. Mo.: 00189 A/S Pos . : 28 Date: 10/15,
Reolicate 1 Time: 14:33
Concentration (uo/L ): 100.3
icats 2 Time: 14:36
Concentration «UQ/L ): 102. B
Mean Cone (uq/L ): 101.5 SD: 1 . 82 RSD ('/.): 1.79
Recovery is 98.3V.
^b TD: 910O6.2 3ec- . Mo.: 00190 ' A/S Po=.: 29 Date: 10/15,
PSD! ics !:e i T A m= : 14:40 ,
~:~.f---~s; trat - :"n . ^ici/L '.: -3,7
5D: 0.63 RSDC/.): 19.5(
^!« TD: 810O6.3 Sea. Mo.: 00191 A/S Pos . : 3O Date: 10/15;
Replicate 1 Time: 14:46
Concentration (ua/L ): 0.7
i
•^=>nlicate 2 Time: 14:49
Concentration (uq/L ): 0.6
Mean Cone (uo/L >: 0.6 SD: 0.08 RSDC/.): 13. 3J
rnb TD: CCV Sea. No.: O0192 A/S Pos.: 3 Date: 1O/15J
Reolicate 1 Time: 14:52
Concentration (uq/L ]: 98.8
2 Time-. 14:56
Concentration (ua/L ): 103.1
>lean Cone (ua/L ): 101.0 SD : 3.07 ' RSDC/.): 3.04
DC samcle is within ranoe 79.5 - 120.49
-------
Rh ID: COB ' Sea. No,: O0193 A/S Pos.: 0 Dates 1O/1
Reolicate 1 Time* 14:59
Concentration
-------
lemsnt File: AS.GEL
ate: J.O/20/98
ata File:
schnioue: HGA
Element: As
Time: 09:30
ID/Wt File:
Calib. Tvoe :
81O02.IDW
Linear
Wavelength: 193.7
Slit: 0'.70 L
Lamo Current: O
Energy: 33
ID: BLANK
Sea. No.: O0104
A/S Pos.: 0
Date: 10/20/1
solicate 1
eak Area (A-s)s 0.007
ackaround PR Area (A-s): 0.135
lank Corrected Pk Area (A-s): O.OO6
oncentration (ug/L ): 2.i>0
Time: 09:30
Peak Height (A): 0.040
Background Pk Height (A)
0.149
scli cats 2.
eak Area (A-s): -O.010
ackaround Pk Area (A-s): 0.130
lank Corrected Pk Area (A-5): -0.01O
oncentration (ua/L ): — 4.O7
Time: 09:33
Peak Height (A): 0.039
Backaround Pk Heiaht (A): O.119
ean Cone (uo/L )
-O.74
SD: 4.715
RSD ( V.) : 639 .0;
utD-zero performed.
ID: 10 PPB AS
Sea. No.: OO105
eolicate 1
eak Area (A-s)j O.O26
ackaround Pk Area (A-s): 0.129
lank Corrected Pk Area (A-s): 0.028
oncentration (ug/L ): 11.24
A/S Pos.: 1
Date: 10/20/<
Time: 09;36
Peak Height (A): O.057
Backaround Pk Heiaht (A): 0.100
'eak Area i A-s ) i 0.026
iackaround Pk Ares (A-s): 0.114
Hank Corrected Pk Area (A-s): 0.028
:oncentration (ua/L ): 11.26
lean Cone (uo/L )
11.25
Time: 09:40
Peak Height (A): O.047
Background Pk Height (A): 0.096
SD: 0.012
RSD ('/.): O.ll
Standard number 1 aoolied. t10.003
:orrelation coefficient: l.OOOOO
Slooe: O.OO2B
is ID: 50 PPB AS
feolicate 1
>eak Area (A-s): 0.118
)ackqrotind Pk Area (A-s
31ank Corrected Pk Area
Concentration (ua/L ):
Sea. Mo.: CO106
A/S Pos.s 2
Dates 10/20/1
; O.105
(A-s): 0.119
42.59
Time: 09:43
Peak Height (A): 0.20B
Background Pk Height (A): 0.094
eak Area (A-s): 0.086
Sackaround Pk Area (A-s): 0.119
31ank Corrected Pk Area (A-s): 0.090
Concentration (ua/L ): 32.05
Time: 09:46
Peak Height (A): 0.175
Background Pk Height (A): 0.112
-------
lean Cone (ua/L )
37 .32
SD: 7.451
RSD(7.)s 19
Standard number 2 applied. [ 5O . OO ]
:orrelation coefficient: 0.99324
Slope: O.OO21
ID: 100 PPB AS
Sea. No.: O0107
A/S Pos.
Date: 10/2C
feolicats 1
!eak Area < A-s) : O,
lackoround Pk Area
Hank Corrected Pk
232
(A-s): O.I2O
Area (A-s): 0-234
)oncentration (ua/L ): 109.75
'eak Area iA-s): 0.239
,'ackaround Pk Area (A-s) : 0.114
Jlank Corrected Pk Area (A-s): 0.241
Concentration (ua/L ): 113.04
Time: 09:49
Peak Heiaht (A): 0.362
Backaround Pk Heiaht (A): O.OB5
Time; O9:53
Peak Heiqht (A): 0.428
Backaround Pk Heiaht (A): O.O84
lean Cone (uq/L )
111.40
SDs 2.326
BSD ('/.): 2.09
Standard number 3 applied. [100.001
Correlation coefficient: O.99591
51 ODE: 0.0023
ID: 200 PPB AS
5ea. No
O0108 A/S Pos.: 4'
Date: 10/2O
1
'eak Area (A-s): O.429
'ackoround Pk Area iA-s): 0.121
Blank Corrected Pk Area (A-s): 0.431
loncentratiDn (ua/L ): 195.23
Time: 09:56
Peak Heiqht (A)i 0.723
Background Pk Heiaht (A)i 0.070
3eak Area iA-s3i O.449
Backoround Pk Area (A-s): 0.121
31ank Corrected Pk Area (A-s): O.451
"oncentration (uq/L ): 194.04
lean Cone (ua/L
1B9.64
Time: 09:59
Peak Heiaht (A): O.738
Backaround Pk Heiaht (A): 0.079
SD: fa.23-
RSD ('/.): 3.29
Standard number 4 applied. [200.OO]
Correlation coefficient: 0.99B49
Slope: 0.0022
ID: ,50 PPB AS
Sea. Mo.
Replicate 1
=eak Area (A-s):- 0.138
Backaround Pk Area (A-s): 0.100
Blank Corrected Pk Area (A-s): 0.139
Concentration (ua/L ): 56.73
00109
A/S Pos.: 2
Date: 10/20,
Time: 10:09
Peak Heiqht (A): O.222
Backaround Pk Heiaht (A): 0.068
'eak Area (A-s): 0.115
Backaround Pk. Area ( A-s ) 5 0.094
Blank Corrected Pk Area (A-s): 0.117
Concentration (ua/L ): 47.22
Time: 1O:12
Peak Heiaht (A): 0.199
Backaround Pk Heiaht (A): 0.064
-------
ean Cone (ua/L ):
51.95
SD: 6.724
RSD C/.): 12.94
tandard number 2 aoolied, T5O.OO]
orrelation coefficient: 0,99999
Slope: O.O029
iMbU01i9 Clliof alien - C:\ffi OS ti
In.**.,
1
1
1
1
! *.
i
i
! *\
^*"
.^""
ST^"13^ B^ift^..,^
0 I •jr.r^fitrataoPi tOO.CO
i
i
*
1
Data - C:\fift USER\flfl FILES\ELB1EHT\
J~L!
3 J « yy ug/L He an si
QC sample is within range 79,58 - 120,49
i t
Atonic Signal
Background Signal
Repl. 2
Hean:
of 2
183.86
Area: B.239 A-s
Area: 0.103 A-s
Cone, 101,19 us/L
SO: 2.646
Heii
i«
-------
ID: ICE -
Replicate 1
Concentration \'up/L ): 0.98
•I" i cats —
Concentration sua/L ): 3.21
Sea. No.: 00111 A/S Pos.
Time: 1O:26
Time: 10:29
Mean Cone (ua/L }: 2.O9 SD: 1.576
,*
QC sample is within ranae -5,49 — 5.49
Date: 1O/2
RSD (•/.): 75.
As ID: S10O3.RB-AP Sea. No.:
Reolicate i
Concentration (ua/L 3: 3.39
Concentration (ua/L >: 0.24
Cone (ua/L Ji 1.81
00112 A/S Pos.: 14
Time: 10:32
Time: 10:35
SD: 2.234
ID: 8 1003.RB-F Sea. Wo.
icate 1
Concentration iua/L ): —0.48
oncentration (ua/L 1: -3.37
Cone
-------
^3 ID: 31003.IB
Seal icate 1
Concentration (ug/L ): 3.73
teolicate 2
Concentration £ua/L ): 1.80
Seo. No.
Cone fuo/L 5:
2.76
OO116 A/S Pos
Time: 10:58
Time: 11:01
SD: 1.363
IB Date: 10/20/
RSD(X): 49.2d
^s ID: S10O3.01 Sea. Mo.
3eolicate 1
Concentration (ua/L ): -1.40
i c a t e 2
oncentration (ua/L ): 1.92
lean Cone (ua/L ):
0.25
O0117 A/S Pas
Time: 11:04
Time: 11:07
SD: 2.344
19 Date: 10/20/
RSD ('/.): 903.
As ID: 81003.01
•^eolicate 1
Concentration (ua/L ): B3.-OO
"eo IIcats- 2
Concentration iuo/L 3: 87.23
Sea. No.: 00118 A/S Pos.: 19
Time: llslO
Time: 1'1:14
Date: 10/20/
viean Cone (ua/L 3:
Recovery is 84.97.
85.11
SDs 2.991
RSD (•/.): 3.51
As ID: 91003.O2
Reelicate 1
Concentration (ua/L ): 2.85
Renlicats 2
Concentration (ua/L ): 1.63
Mean Cone (uo/L ):
Sea. Mo.: 00119 A/S Pos.: 20
Time: 11:17
Time: 11:20
Date: 10/20/
1.24
SD: O.B5B
RSD(7.): 3B.32
A=s !D: 81O03.03
Reolicate 1
Concentrat iors (ua/L ): 5.13
Sea. No.: OO12O A/S Pos.: 21
Time: 11:23
Concentration lua/L ): 4.54
Hean Cone (ua/L ): 4 . 84
Time: 11:27
SD: 0.419
Date: 10/20/
RSD(7.): 8.65
-------
^= ID: CCV Sea. No.: O0121 A/5 Pos.: 3 Date: 10/2C
^eolicats 1 Time: 11:30
Concentration (uq/L ): 89.55
^eoltcate 2 Time: 11:33
Concentration tuq/L ): ,87.92
lean Cone (uo/L !: BS.73 SD: 1.155 RSD <'/.): 1.3C
3D samDl& is within ranae 79.5O - 120.49
•3
A5 ID: CCV Sea. No.: O0122 A/S Pos.: 3 Date: 1O/20
Replicate 1 Times 11:33
Concentration (ua/L ): 104.82
Real .tests 2 Time: 11:41
Concentration (uq/L ): 115=30
Mean Cone (ua/L J: 110.04 SD: 7.4O7 RSDC/.): 6.73
£5C sample is within ranqe 79. 5O - 12O.49
t
a= IE: CCB Sea. No.: O0123 A/S Pos.: 0 Date: 1O/20
Replicate 1 Time: 11:44
Concentration (ua/L ): 1.53
Re'Dlicate 2 Time: 11:47
Concentration (ua/L ): 0.17
Mean Cone (ua/L ): 0.85 3D: 0.961 RSD(X): 113.
QC sample is within ranae -5.49 - 5.49
As ID; S1O03.U1 Sea. No.; OO124 A/S Pos.: 22 Date: 1O/20
Replicate 1 Time: 11:51
Concentration (ua/L ): 44.63
"eplicate 2 Time: 11:54
Concentration iua/L ): SO.43
Mean Cone fuo/L ): 47.52 SD J 4.1O4 RSD (7.): B.63
As ID: 31003.U2
Reolicate i
Sea. No.: 00125 A/S Pos.: 23
Time: 11:57
Date: 10/20-
-------
Concentration Cua/L )j 39,36
^s o 1 L cats 2
Zoncentrat ion (ua/L ): 41.10
lean Cone Cua/L ):
4O.23
Time: 12:OO
BD: 1.232
RSD C/.)! 3.06
ID: 81003. U3
Concentration fuo/L ): 61.76
Dedicate 2
Zoncentration (uo/L )': 53 . B2
Sea. Mo.: 00126 A/S Pos,
Time: 12:O4
Time: 12:O7
24 Date: 10/20
'"lean Cone i ua/L ).:
57/77
SD: 5.612
RSD ('/.): 9.71
ID: 81003.11
Sea. Mo.: 00127 A/S Pos.: 25 Date: 1O/20
Samole ab&. is oreater than that of the largest standard.
Replicate 1 Time; 12:10
Concentration iua/L ): 556.26
As TD: AS Position OOO Sea. No.
Reolicate 1
Concentration (ua/L ): 13.54
Reolicste 2
Concentration (uq/L ): 6.09
Mean Cone fua/L ):
9.77
00128 A/S Pos
Time: 12:16
Time: 12:19
SD: 5.267
. : 0
Dates 10/20
RSD C/.): 53 .61
As ID: 810O3.I1
Sea. No.:
Reolicate 1
Concentration tuq/L ): 11S.67
ffeolicats 2
Concentration (ua/L ): 132.72
Mean Cone (ua/L
125.67
O0129 A/S Pos,
Time: 12:22
Times 12:25
SD: 9.939
25 Date: 10/20
RSD(7.): 7.91
TD: 81003.12
Sea. No.
Reolicate 1
Concentration
•Concentration (ua/L ): 220-40
0013O A/S.Pos,
Time: 12:1
26 Date: 10/20,
Mean Cone (uo/L ):
185.79
Time: /12:32
SD: 48.044
RSDC/.): 25.8:
-------
ID: 8100
3.I2XC
Sea. No.: OO131 A/S Pos.: 26 Date: 1O/2C
Time: 12:35
Concentration (ua/L ): 138,93
^"sol ics te 2
-oncentration (ua/L ): 188.76
Cone (ua/L ):
163.63
Time: 12:39
SD: 35.236
RSD (/I): 21.5
ID: S1003,I3x5
Concentration iua/L ):
3ec
-------
3MA 4OO Analysis Ver. 4.10 Thu 10/15/98 -
lod File Name
arks: BA ONLY
•Jt file is 10
™D«RD
«MD«RD
-ftiMD^RD
•ANDARD
-ANDARD
^IMDftRD
"ANDARD
"ANDARD
-ANDARD
rP>Mr>«Rt>
r~ dQ| tsl r^ ^— ^f^^T^
r rf^^ t\jT"^^^ f?T^
.«MK
_«NK
: BA
236
#1
BA455
BA455
#1
BA455
BA455
BA455
BA455
BA455
BA455
4*»3
BA455
BA455
4*3
BA455
BA455
BA455
4*-*
BA455
BA455
BA455
BA455
BA455
EM
EM
EM
AV
EM
EM
EM
AV
EM
EM
EM
AV
EM
EM
EM
AV
EM
EM
Repl icates :3
REF*I_ I GATE
49
REF>1_ I C ATE
53
60
54. 0 SD 5.6
788
709
REF*!- I C ATE
719
738.7 SD 43. O
1410
1360
1420
1396.7 SD 32.1
2707
REFM— I GATE
2803
2751
2753.7 SD 48.1
REF^L. I GATE
36
REF>I_ I GATE
26
Read Delay: 65
Data File:
4*1 11O8 1O/ 15/98
*=>
peak-noisy
CV 1O.3 CONC O.O2OO
4*± 1111 1O/ 15/98
4*2
4*3
CV 5.8 CQNC O.5OOO
4* ± 1113 1O/ 15/98
*2
W3
CV 2.3 CONC l.OOOO
4*1 1115 1O/15/98
*2
*3
CV 1.7 CONC 2.OOOO
4*1 1117 1O/15/9B
4*2
-------
BA455
BA455
BA455
BA455
BA455 CC
EM
AV
34
32.0 SD
0.9999 SLOPE
EM
EM
BA455 EM
BA455
BA455
1358
1360
F>EF>I_ i cftTE
0.9708 mg/L
REF>I_I
O.9723 mg/L
5.3 CV
1360.5981 INT
4*1
16.5 CONC O.OOOO
37,1389
1119 10/15/98
BA455
3
BA455
B
BA455
EM
BA455
BA455
EM
EM
1342
AV
AV
39
37
O.9590 mg/L
1353.3 EM SD
0.9674 mg/L SD
F>EF*I_I
0.0014 mg/L
9.9 CV
O.OO73 CV
E 4*1
0.7
O.75
1121 1O/15/98
I CftT
-0.0001 mg/L
peak-noisy
4*2
peak—noisy
34 -0.0023 mg/L
AV 36.7 EM SD
AV -O.OOO3 mg/L SD
peak-noisy
2.5 CV 6.9
0.0018 CV 532.91
L
L
L
—
—
—
—
002
BA455
002
BA455
002
BA455
*fl ^^f ^j^
BA455
-• -^r »*j»
BA4S5
1 X2
BA45S
1 X2!
BA455
- B— A
EM
- B — 1
EM
EM
BA455
BA455
EM
EM
EM
BA455
BA455
B
EM
REI=I_ I CftTEI
999 O.7069 mg/L
1009 0
R
1039 0
AV 1015.7
AV O.7192
572 0
596 0
584 0
AV 584. O
AV O.4O19
F>
1330 0
EIR-I-
.7143
ETF^L
.7363
EM
mg/L
EF"!-
.3931
Eri=>i_
.4107
EF>I_
.4019
EM
mg/L
El=l_
. 9502
-ICftTE
mg/L
. IC«TE
mg/L
SD
SD 0.
_ic#=n-E
mg/L
mg/L
mg/L
SD
SD O.
mg/L
4*±
4*2
4*3
20. 8
0153
4*1
4*2
4*3
12. O
0088
4*1
CV
CV
1
CV
CV
1123 1O/15/98
2.O
2.13
1125 1O/15/9B
2.1
2.19
1127 10/15/98
-1
I CftTE
-------
-± X2S
BA455 EM
BA455
BA455
-1 X2
BA455 EM
-1 X2
BA455 EM
-± X2
BA455 EM
BA455
BA455
-± X2D
BA455 EM
-1 X2JD
BA455 EM
-± X2E>
BA455 EM
BA455
BA455
:>— ± X2
BA455 EM
>— 1 X2
BA455 EM
:>— ± X2
BA455 EM
BA455
BA455
-2ft
BA455 EM
—2ft
BA455 EM
— 2ft
BA455 EM
BA455
V. BA455
—2ft
BA455 EM
—2ft
BA4SS EM
REF=>L_ I CftTE: =1*3
1404 1.0046 mg/L
AV 1363.7 EM SD 37.4 CV 2.7
AV 0.975O mg/L SD O.O275 CV 2.82
REiF^L. I CftTE 4t=± 1129 1O/15/98
615 0.4247 mg/L
R:EF=>L_ i eft-re: *2
575 0.3953 mg/L
R£EF>I_ I CftTE 4*3
GO6 0.4181 mg/L
AV 598.7 EM SD 21.0 CV 3.5
AV O.4127 mg/L SD O.O154 CV 3.74
REF^LICftTE =»± 1132 1O/15/98
530 0.3622 mg/L
REF*I_ I Cft-TE =H=2
581 0.3997 mg/L
R!EI=>I_ I CftTE 4*3
567 0.3894 mg/L
AV 559.3 EM SD 26.4 CV 4.7
AV 0.3838 mg/L SD O.O194 CV 5.O5
REF"I_ I CftTE 4*± 1134 1O/15/98
569 0.3909 mg/L
REF31!— I CftTE: 4*2
55& 0.3813 mg/L
REff31!- I CftTE 4*3
567 O.3894 mg/L
AV 564.0 EM SD 7.O CV 1.2
AV 0.3872 mg/L SD O.0051 CV 1.33
REIR-L. I CftTE 4*± 113G 1O/15/98
43 O.OO43 mg/L peak-noisy
REF"!— I CftTE 4*2
37 -0.0001 mg/L peak-noisy
RER-LICftTE 4*3
34 -O.OO23 mg/L peak-noisy
AV 38.0 EM SD 4.6 CV 12.1
AV 0.0006 mg/L SD O.OO34 CV 532.18
REF>I_ I CftTE 4*± 1138 1O/15/98
43 0.0043 mg/L
REF*!— I CftTE 4*2
39 0.0014 rng/L peak-noisy
-------
BA455 EM
BA455
BA455
BA455 EM
BA455 EM
BA45S EM
BA455
BA455
BA455 EM
4T
BA455 EM
4T
BA455 EM
BA455
BA455
bv/
42: u.uujb mg/u.
AV 41.3 EM SD
AV O.OO31 mg/L SD
1164
1115
peaK—noisy
2.1 CV 5.0
0.0015 CV 49.63
**1 114O 10/15/98
0.8282 mg/L
1113
AV 1130.7 EM
AV 0.8037 mg/L
41
0.7922 mg/L
FSEF^LICATE: +1=3
0.7907 mg/L
SD 28.9 CV
SD 0.0212 CV
2.6
2.64
0.0028 mg/L
37
-0.0001 mg/L
«=! 1142 1O/15/9B
peak-noisy
peak-noisy
42
AV 40.0 EM
AV O.O021 mg/L
1449
145S
REF-L I OftTE +1=3
O.OO36 mg/L peak-noisy
SD 2.6 CV 6.6
SD 0.0019 CV 92.47
1144 1O/15/98
i GATE: **±
1.0377 mg/L
1.0428 mg/L
BA455 EM
k/
BA455 EM
V
BA455 EM 1521 1.0906 mg/L
BA455 AV 1475.3 EM SD 39.7 CV
BA455 AV 1.O570 mg/L SD 0.0292 CV
2.7
2.76
BA455 EM
BA4SS
EM
BA455 EM
38
40
0.0006 mg/L
«=! 1146 1O/15/98
peak-noisy
0.0021 mg/L
BA455 EM
BA455 AV
BA455 AV
peak—noisy
#3
-0.0008 mg/L peak-noisy
38.O EM SD 2.O CV 5.3
O.O006 mg/L SD 0.0015 CV 232.26
icATE: **i 1148 io/is/98
44 0.0050 mg/L peak-noisy
-------
BA455
BA455
BA455
BA455
3 — AF>
BA455
BA455
BA455
I
—fa •
^ f^
BA455
3— F"
BA455
3 — F-
BA455
3
BA455
B
BA455
3
BA455
B
BA455
EM
BA455
BA455
EM
EM
EM
BA455
BA455
EM
EM
EM
BA455
BA455
EM
EM
EM
BA455
BA455
EM
EM
EM
BA455
BA455
EM
40 0.0021 mg/L peak-noisy
AV 42.3 EM SD 2.1 CV 4.9
AV O.OO38 mg/L SD O.OO15 CV 4O.08
FiEF*!— I GATE 4*1 115O 1O/15/98
36 —O.OOOS mg/L peak-noisy
38 0.0006 mg/L peak-noisy
REF>LICATE 4*3
36 -0.0008 mg/L peak-noisy
AV 36.7 EM SD 1.2 CV 3.1
AV -O.OOO3 mg/L SD O.OOO8 CV 244.52
REF"l_IOATE 4*± 1152 10/15/98
33 -0.0030 mg/L peak -noisy
REF"!— i c ATE 4*2:
38 O.OOOS mg/L peak -noisy
REF*LICATE 4*3
38 0.0006 mg/L peak-noisy
AV 3G.3 EM SD 2.9 CV 7.9
AV -0.0006 mg/L SD O.OO21 CV 358.35
REF"l_ICATE 4*1 1154 1O/15/98
47 0.0072 mg/L peak-noisy
REF*l_ICATE 4*2:
46 0.0065 mg/L
49 0.0087 mg/L peak-noisy
AV 47.3 EM SD 1.5 CV 3.2
AV O.OO75 mg/L SD O.O011 CV 14.98
REF*I_ I C ATE 4*1 1156 10/15/98
55 0.0131 mg/L peak-noisy
REF*I_ICATE 4*2:
53 0.0117 mg/L peak-noisy
REF*!— I GATE 4*3
49 0.0087 mg/L peak-noisy
AV 52.3 EM SD 3.1 CV 5.8
AV 0.0112 mg/L SD 0.0022 CV 20.11
REF>L_ICATE 4*1 1159 1O/15/98
55 0.0131 mg/L peak-noisy
BA455
EM
REF>I_ICATE 4*2:
0.0117 mg/L peak-noisy
-------
BA455 EM
BA455
BA455
BA455 EM
BA455 EM
BA455 EM
BA455
BA455
V
BA455 EM
V
BA455 EM
k^
BA455 EM
BA455
BA455
62
AV
AV
0.0183 mg/L peak-noisy
56.7 EM SD 4.7 CV 8.3
O.0144 mg/L SD . 0.0035 CV 24.20
4*± 12O1 1O/15/98
peak-noisy
X C*=*TI
0.0190 mg/L
0.0153 mg/L
63
58
56 0.0139 mg/L
AV 59.0 EM SD
AV O.O161 mg/L SD
1516
1590 1.1413 mg/L
peak-noisy
4*3
peak-noisy
3.6 CV
O.OO26 CV
E 4*1
1.0869 mg/L
I GATE 4*3
1.1200 mq/L
1561
AV 1555.7 EM SD
AV 1.1161 mg/L SD
37.3 CV
O.O274 CV
6.1
16.49
12O3 1O/15/9B
2.4
2.46
BA455
EM
BA455 EM
Et
BA455 EM
BA455
BA455
BA455 EM
BA455 EM
BA455 EM
BA455
BA455
5
BA455 EM
39
36
38
0.0014 mg/L
-O.OOO8/mg/L
REF>l_I
0,0006 mg/L
AV
AV
37.7 EM
O.OOO4 mg/L
53
58
53
0.0117 ma/L
R
0.0153 mg/L
REF>I_ I
0.0117 mg/L
AV 54.7 EM
AV O.O129 mg/L
1342
1 1205 1O/15/9B
peak-noisy
peak-noisy
4*3
peak-noisy
SD 1.5 CV
SD O.O011 CV
4.1
289.44
4*± 12O7 1O/15/98
peak-noisy
peak-noisy
4*3
SD 2.9 CV
SD O.OO21 CV
4*1
5.3
16.47
1209 10/15/98
0.9590 mg/L
ICrf=hTE 4*:2
-------
BA455 EM 1364
BA455 AV
BA455 AV
BA455 EM 57
BA455 EM 52
BA455 EM 65
BA455 AV
BA455 AV
BA455 EM 47
BA455 EM 44
BA455 EM 52
BA455 AV
BA455 AV
BA455 EM 52
BA455 EM 50
BA455 EM 57
BA455 AV
BA455 AV
BA455 EM 69
BA4S5 EM 70
BA455 EM SO
BA455 AV
BA455 AV
BA455 EM 56
BA455 EM 55
0.9752 mg/L
1353.7 EM SD
O.9676 mg/L SD
0.0146 mg/L
0.0109 mg/L
RE:I=-I_ i
0.0205 mg/L
58.O EM
O.O153 mg/L
SD
SD
4*3
11.1 CV
O.OO81 CV
4*1
4*2
4*3
peak-
6.6 CV
O.OO48 CV
O.8
0.84
1211 1O/15/98
I CftTE 4*1
0.0072 mg/L peak-
•noisy
11.3
31.43
1213 1O/15/98
•noisy
O.O050 mg/L
peak-noisy
0.0109 mg/L
47.7 EM SD
O.OO77 mg/L SD
I Cf^TEL =1*3
peak-
4.O CV
O.O030 CV
E 4*1
•noisy
8.5
38.39
1215 10/15/98
0.0109 mg/L
0.0095 mg/L
peak-noisy
0.0146 mg/L
53.O EM SD
0.0117 mg/L SD
0.0234 mg/L
0.0242 mg/L
0.0315 mg/L
73.O EM SD
0.0264 mg/L SD
REF>I_I
0.0139 mg/L
E 4*3
peak-
3.6 CV
O.O026 CV
4*1
peak'
4*2
4*3
peak-
6.1 CV
O.OO45 CV
I 4*1
peak-
•noisy
6.8
22.73
1217 1O/15/98
•noisy
•noisy
8.3
16.96
1219 1O/15/98
•noisy
I GATE 4*2
0.0131 mg/L peak-noisy
-------
BA455 EM
BA455
BA455
BA455
EM
BA455 EM
BA455 EM
BA455
BA455
BA455 EM
BA455 EM
BA455 EM
BA455
BA455
BA455 EM
BA455 EM
BA455 EM
BA455
BA455
^
BA455 EM
V
BA455 EM
k/
BA455 EM
BA455
BA455
B
BA455 EM
&
BA455 EM
54 0.0124 mg/L
AV 55.O EM SD
AV 0.0131 mg/L SD
402
431
REF>1_ I GATE 4*1
0.2682 mg/L
peak-noisy
l.O CV 1.8
O.OOO7 CV 5.60
1221 1O/15/98
0.2895 mg/L
F*EF>I_ I
0.2652 mg/L
3S8
AV 41O.3 EM SD
AV 0.2743 mg/L SD
523
536
FSEF>1_ I
0.3571 mg/L
4*3
18.O CV
O.O132 CV
4*1
510
0.3666 mg/L
REF>I_ I CftTI
0.3475 mg/L
AV
AV
523.O EM SD
O.3571 mg/L SD
408
455
406
AV
AV
1515
1611
1498
AV
AV
42
41
FSEF=-L_ I CftT
0.2726 mg/L
REF>L_I
0.3O71 mg/L
RJER-L-I
0.2711 mg/L
4*3
13.O CV
0.0096 CV
4*1
423.O EM SD
O.2836 mg/L SD
4*3
27.7 CV
0.0204 CV
4*1
F?EF>L_ I GAT
1.0862 mg/L
IREFUL. I CftTE 4*S
1 . 1567 mg/L
REF^L. I Crf=fcTE:
1.0737 mg/L
4*3
1541.3 EM SD
1.1055 mg/L SD
60.9 CV
O.O448 CV
F>L_ I GATE 4*1
4.4
4.83
1223 10/15/98
2.5
2.68
1225 1O/15/9B
6.6
7.19
1227 1O/15/98
4.0
4.05
1230 1O/15/98
0.0036 mg/L
peak-noisy
REF31!- I CftTE 4*^2
0.0028 mg/L peak-noisy
-------
OO&
BA455
BA455
BA455
1
EM
OO& - 1
BA455 EM
OO& . 1
BA455 EM
BA455
BA455
BA455 EM
BA455 EM
f
BA455 EM
BA455
BA455
BA455 EM
BA455 EM
BA45S EM
BA455
BA455
•
BA455 EM
k
BA455 EM
>
BA455 EM
BA455
BA455
BA455 EM
BA455 EM
AV
AV
40.7 EM
O.O026 mg/L
813
835
824
AV
AV
1841
1996
1899
AV
AV
1079
1024
1160
AV
AV
1034
1058
1038
AV
AV
836
853
SD 1.5 CV
SD O.OO11 CV
I Crf=fcTEI 4*1
0.5702 mg/L
0.5864 mg/L
0.5783 mg/L
824.0 EM SD
0.5783 mg/L SD
I 4*3
11.0 CV
0.0081 CV
1.3258 mg/L
1.4397 mg/L
F9: EF" l_ I
1 .3684 mg/L
1912.O EM
1.378O mg/L
SD 78.3 CV
SD O.O576 CV
4*1
0.7657 mg/L
I CftT
0.7253 mg/L
4*3
0.8253 mg/L
1O87.7 EM SD
0.7721 mg/L SD
68.4 CV
0.0503 CV
I 4*1
0.7327 mg/L
RE:F>-L_I
0.7503 mg/L
REF^L-I
0.735& mg/L
1043.3 EM SD
0.7395 mg/L SD
RE:F>L_I
0.5871 mg/L
12.9 CV
O.OO95 CV
4*1
O.5996 mg/L
I
3.8
43. 3O
1232 10/15/98
1.3
1.40
1234 1O/15/98
4.1
4.18
123S 10/15/9B
6.3
£.51
1238 1O/15/98
1.2
1.28
1240 10/15/98
4*3
-------
V
BA455
V
BA455
V
BA455
Et
BA455
Et
BA455
B
BA455
DHtOO
BA455
EM
EM
EM
BA455
BA455
EM
EM
EM
BA455
BA455
HV «'*/'. a tn
AV O.5955 mg/L
REI^L.
1508 1.0810
RER-L
1531 1.0979
RETI^L.
1501 1.0759
AV 1513.3 EM
AV 1.085O mg/L
REI=L
39 O.O014
REF>L
41 O.OO28
REF>L
35 -0.0016
AV 38.3 EM
AV O.OO09 mg/L
t»iJ y.a
SD O.OO72
. IO«TE =«=
mg/L
LV
CV
±
1 m'^.
1.21
1242 1O/ 15/98
T Ct£i~l~E" -§§••'">
H ^L ^™rf- •""• • ^^_ "*^ -^^
mg/L
. ICftTEI «=:
mg/L
SD 15.7
SD O.0115
mg/L
mg/L
. ICftTE *:
mg/L
SD 3.1
SD O.OO22
3
CV
CV
peak-
2
peak-
1.0
1.O6
1244 1O/ 15/98
-noisy
-noisy
5
peak-noisy
CV
CV
8.O
255.78
-------
iement Files BE.SEL
ate: 10/22/93
ata Files
echniaue: HGA
Element: Be
Time: 16:30
ID/Wt File: B1O13.IDW
Calib. Type: Linear
Wavelength: 234.?
Slit: O.7 L
Lamp Current: 3O
Energy: 65
ID: BLANK
Sec. No.: 00050
A/S Pos. J 0
Date: 10/22/
eolicate 1
eak Area (A-s): -0.003
ackqround Pk Area (A-s): 0.550
lank Corrected Pk Area (A-s): -O.006
concentration (ug/L ): -0.37
eoiicate 2
eak Area iA-sis -Q.OG3
Background Pk Area (A-s)» 0.2BO
ilank Corrected Pk Area (A-s): -O.O06
:oncentration (uq/L ): -0.36
Time: 16:30
Peak Height (A): 0.003
Background Pk Height (A)! O.195
Time: 16s33
Peak Height (A): O.OO2
Background Pk Height (A): 0.101
lean Cone (ug/L ):
luto—zero performed.
ID: 0.5 PPB
-0.37
SD: O.005
.•%,-„
ie
Sea. No.: OO051
A/S Pos.: 1
RSDC/.): 1.39
Date: 10/22/
ieclicate 1
'eak Area (A-s): O.OO8
lackground Pk Area (A-s): 0.180
Hank Corrected Pk Area (A-s): 0.011
loncentration iug/L ): 0.68
;eaK Area lA-s): 0.010
iackaround Pk Area (A-s): 0.149
ilank Corrected Pk Area (A-s): O.013
,'oncen tration (ug/L )s 0.79
Time: 16:36
Peak Height (A): 0.023
Background Pk Height (A): 0.122
Time: 16:4O
Peak Height (A): O.029
Background Pk Height (A): 0.121
lean Cone (ug/L ):
0.73
Standard number 1 applied. CO.50]
Correlation coefficient! l.OOOOO
SD: 0.079
Slope: 0.0237
RSDC/.): 10.74
ID: 2 PPB
Sea. No
O0052 A/S Pos.: 2
Date: 10/22/
\eolicate 1
5eak Area (A-s): O.039
Background Pk Area (A-s): 0.186
Blank Corrected Pk Area (A-s)i O.042
loncentration (ug/L ): 1.76
Seak Area trt— s>: O.O41
aackqround Pk Area ( A-s ) : 0.182
ilank Corrected Pk Area (A-s): O.044
Concentration (uq/L ): 1.S7
Time: 16:43
Peak Height (A)» 0.096
Background Pk Height (A): O.245
Tune: 16:46
Peak Height (A): O.118
Background Pk Height (A): 0.276
-------
lean Cone tua/L );
1.B1
SD s 0.082
4.5:
standard number 2 applied. [2.00]
lorrelation coefficient: 0.99B91
Slopes O.O216
ID: 5 PPB
Sea. No.: 00053
A/S Pos.: 3
Date: 10/2:
Dedicate 1
seak Area (A-s): 0.1OO
Background Pk Area (A-s): O.3O5 .
31ank Corrected Pk Area (A-s): O.103
Concentration (ug/L )s 4.76
^eoiicate 2.
-eak Area iA—s): C.1O3
3ackground Pk Area (A-s); 0.297
31ank Corrected Pk Area (A-s): 0.106
Concentration (ug/L ): 4,88
Time: 16:49
Peak Height (A): 0.255
Background Pk Height (A); 0.632
Time: 16:52
Peak Height (A): 0.250
Background Pk Height (A)s 0.63O
lean Cone (uq/L );
4.02
SD: O.085
RSD ('/.): 1.7:
Standard number 3 applied. [5.001
Correlation coefficients O.99966
Slopes 0.0210
v -^ **v .«„ i*v«-v >». -v -V "V "
3e
ID: 10 PPB
Sea. No.: OOO54
A/S Pos.: 4
Date: 10/2:
^eolicate 1
^eak Area (A-s): 0.173
^ackoround Pk Area (A-s): O.505
31ank Corrected Pk Area (A~s)s O.176
Concentration (ug/L ): 8.39
•^eolicate 2
^eak Area
-------
"iDisiiliy Cilitirition - C:\Ari
'4
1 "
Seo. No.s OO056 A/S Pos.: O Date: 10/22>
Time: 17:11
Time: I/:14
."lean Cone iug/L j: O.16 SD: O.002
LJC samole is within range -1.49 - 1.49
Huto-zero oertormea.
RSD(7.): 1.25
Be ID: 81OO3.RB-AP
fieolicate 1
Concentration iug/L ): -O.O1
neoiicate 2
Concentration (uo/L )t —O.O2
Sea. No.s OO057 A/S Pos.: 14 Date: 1O/22/
i
Time: 17:17
Time: 17:20
nean Cone (ug/L ):
Re ID: BIOO3.RB-F
Reoiicate i
-0.02
SD: O.OOS
RSD r/.) s 44 .'
«^bf\,JVl^'V'V'iw'\*'V'\rf^'V'V«^'V'V^A«/VrV^y\«'V^'^'VA«'^'V'V^'V^A«A(^^'V'XrrV'V'V^^'V'W'WM|
Sea. No.: OOO58 A/S Pos.: 15 Date: 10/224
Time: 17:24 i
-------
Concentration (ug/l_ ): O.Ol
: J.7:27
Concentration luq/L j: — G.O3
lean Cone iuq/L ;: -O.Ol SD: 0.027 RSDC/.): 232
ie ID: 81O03.OB Sea. No.: OO059 A/S Pos.: 16 Date: 1O/2!
teoiicate 1 Time: 17:30
Concentration (uq/L ) : -O.Ol
>^'V*V-v"V.'V.^'V,'V'V^%'^^^^Xf^^^^~«to^^
3e IDt B1Q03.UB Sea. No.: OO06O A/S Pos.: 17 Date: 10/2:
. '-w.'V'V'V •V'\-'\i*\»'"M.~lj'\ii '^/•v'^Aj-W^ ^'V*V'V'^'^'^^'^%f'V^'^lV'V^lVlV'VIV^'V'\*^^'V^'V^^l^^'^JV^^^^^^^'V^^^'V^^*W'V^'V»^
3e IDs 81OO3.01 Sea. No.: 00062 A/S Pos.: 19 Dates 10/22
xeolicate 1 Time: 17:49
Concentration (uq/L }: O.04
2 Time: 17:52
Loncentration » ug/L j: -O.OO
•lean Cone (uq/L J; O.O2 SD: O.O28 RSD(7.1: 163.
'•i 'V ' v 'V •' w " v "V "!.• 'V "V''i/ 'W ' V w 'V PX* *V *V *V ^ "V *VV "V *W *V 'V ^ *W -^ *V 'V 'V *^ ^ *V ^ ^rf*^ ^-^ ^ ^ *^* *^ *V *V 'V *V ^ 'V 'V f\r 'V *V ^ ^^^*\* *\f^^if^ ^f ^t ^t *V A»
3e IDs B1O03.01 Sea. No.: 00063 A/S Pos.: 19 Date: 1O/22
-------
lean Cone (ug/L )! 4.56
Recovery is 9O.8%
3e IDi 81OO3.D2
^eolicate 1
Concentration (ua/L ): 0.04
Sea. No.
Concentration (ug/L J: O.O5
"lean Cone lug/L j: O.O5
SD: O.O73
OOO64 A/S Pos,
Time: 18:O2
Time: 18sO5
3D: O.OO6
RSD <•/.): 1.60
^'^*'\*'\*•v'^
20 Date: 1O/22
RSD (7.1: 12.9
Se ID: 810O3.03 Sea. Mo,
-
-------
-concentration (uq/L ): O.OB
lean Cone (ua/L >: G.O6
SD: 0.022
RSD C/.): 35.'
5e JD: B10O3.U2
-------
^•^•^^•^t\f'^'\f'\,'\e'\.'\l'^'\f^'^f^f^'^f^^lf^lf'^^f^^^lff\f^'\ff^f\t^f\t'^^
Be ID: CCV Sea. No.: OO074 A/S Pos. ; 3 Dates IO/22
1 Time: 19:O4
Concentration (ug/L ); 5.36
^eolicate 2 Time; 19:07
Concentration (uq/L ): 4.95
lean Cone «uq/L ): 5.15 3D: 0.297 RSD(V.)j 5.75
3C sample is within range 3.5 - 6.49
Be ID: CCB Sea. No.: OOO75 A/S Pos.: O Dates 1O/22
Replicate 1 Time: 19:10
Concentration : 6.62
Heoiicate 2 Times 19sl9
Concentration (uq/L >: 7.39
Mean Cone (uq/L ): 7,OO SD: 0.546 RSDf/.): 7.80
/'
Be ID: 81O06.1 Sea. No'.: 00077 A/S Pos.: 28 Date: 1O/22
fieolicate 1 Time: 19:22
Concentration (ug/L ): 9.59
Heoiicate '2 Time: 19:26
Concentration lug/L ): 1O.54
Mean Cone (ug/L ): 1O.05 SD: O.671 RSD(7.): 6.66
Recovery as 61.1%
Be ID: 81OO6.2 Sep. No.: O0078 A/S Pos.: 29 Date: 10/22
Reolicate 1 Time: 19:29
Concentration (ug/L )s 7.16
2 Time: 19:32
Concentration (up/L ): 7.66
-------
M .11 GO
MAIN: 0.001
AA
HO 0.001
MAIMs 0.000
: 1.5
A A
MAIN: O.OOB MG/L HQ O.OOO
AA
MAIN: 0.008 MB/L. HO 0.000
CD
MEAN: O.OOf? MG/L Bn« 0,000 RGDv
AUTDZERO 0,000
-------
PERKIN-ELMER M 1100 98/10/15 PAGE 11
AA AA
MAIN! 0.520 MG/L. HO O.155 MAIN: O.524 MB/L HO 0.156
CD $£\) MEANs O.522 MB/L SD: O.002 RSD; 0.5
AA AA
MAIN: 0.003 MG/L HO O.001 MAIN: O.O03 MS/L, HO 0.001
CD xv f> MEANs 0,003 MB/L BD: 0.001 RED: 22.1
AA AA
MAINs 0.004 MB/L HO O.001 MAIN: 0.003 MG/L HO O.OO1
CD £^p MEAN; 0.004 MG/L. GD: O.001 RSDs 18.5 AUTOZERO O.OOO
AA AA
MAIN: 0.020 MG/L HO 0,006 MAIN? 0,019 MG/L HO 0.006
D g— I MEANs O.O2O MB/L SD: O.OO1 RSD: 3.6
AA AA
MAIN: 0.012 MG/L HO 0,004 MAIN: 0.013 MB/L HO 0.004
CD g-( MEAN; 0.013 MB/L SD: 0.001 RSD: 6.0
AA AA
MAIN: 0,414 MG/L HO 0,123 MAIN: 0.418 MG/L HO 0.124
CD f-U. MEAN; 0,416 M6/L SDn 0.003 RBD: 0.6
AA AA
MAIN: 0.017 MS/L HO O.005 MAIN: 0.018 MG/L HO 0.005
CD 5»_( MEANs O.O17 MG/L BD: 0.000 RBDt 2.6
AA AA
MAIN; 0.016 MB/L HD 0,005 MAINE 0.017 MG/L HO O.OOS
-I> ?~VJ>MEA1M: 0.017 MG/L SD; 0.000 RSDs 2.6
AA AA
MAIN-, 0.021 MG/L HO O.OO6 * MAIM: 0.021 MG/L HO 0.006
CD /6~\ MEANs 0.021 M6/L BD: 0.000 RSDs 2.3
AA AA
MAINs 0.024 MB/L HO 0., 007 MAIM: O.O26 MB/L HO O.OOB
CD -1sA MEANs 0.025 MG/L BD: 0.001 RSD: 3.9
-------
PERKINHELMER M HOC 9B/10/15 PABE 12
AA AA
MAINE 0.029 MS/L HD 0.009 MAIN: O.029 MG/L HO O.O09
CD %'>/i MEAN: O.O29 MB/L SDr, 0.000 RSDs 1.4
AA AA
s 0.387 MG/L HO 0.115 MAIN: 0.3B9 MB/L HO 0.116
CD "2£$MEANs 0.3S8 MS/L 3D: 0.001 RED: 0.3
AA AA
HAINs 0.502 MG/L HO 0.149 MAIN?, 0.488 MB/L HO O. 145
.^^....^^..,. . , ,
CD S^u* ME AW; 0.495 MB/L SDs 0.009 RBD; 1,9
AA AA
MAIN: 0.002 MB/L HO 0,001 MAIIMs 0.001 MB/L HD 0.000
CD CC MEAN: O.O01 MS/L SD: 0.000 RSD: 29.9
AA AA
MAIN; 0.029 MB/L HO 0,009 MAIN: 0.031 MB/L HO 0.009
CD 1-1 # MEAN: O.O3O MB/L SDs O.002 RSDs 5.4
AA AA
MAIN: 0.026 MG/L HQ 0,003 MAIM: 0.030 MB/L HO 0.009
CD 5-7*i£> MEANs O. 028 MB/L BD: O.OO3 RSDs 10.2
AA AA
MAIN: 0.027 MB/L HO O.OOS MAIN: O.O29 MG/L HO 0.009
CD /o-TrJ MEAN: 0.028 MB/L SDs 0.001 RSD: 3.2
TTFT • A A
MAINs 0,020 MG/L HO O.OO6 MAIN; 0.0IB MG/L HQ 0.005
MEAN: 0,019 M6/L 3D: 0.002 RSDs 10.0
A A A A
MAIN; On017 MB/L HO 0.005 MAIN; 0.017 M6/L HO 0.005
CD ftS-\~MEAN: 0,017 MB/L GD: 0.000 RSD: 2.1
A A ' A A
MAINs 0.020 MB/L HO O.006 MAIN: 0.019 MB/L HO O.006
CJ) & MEAN; 0,020 MG/L SD: 0,001 RSD; 3.8
-------
PERKIN-ELMER M 11OO 9E3/10/IS PAGE 13
AA AA
MAIN* G. 018 MG/L HO O. OO5 MAIN: 0.017 MG/L HD 0.005
CD /. f) MEAN: 0.01B MG/L BD: 0.001 RSDs 3.0
AA AA
MAIN: 0.022 MG/L HO O.OOi MAIN: 0.019 MG/L HO 0.006
CD /£ MEANs 0,020 MB/L SDs 0.002 RSD: 9.6
AA AA
MAIN;- 0.503 MG/L HO 0.149 MAIM: 0.519 MB/L HO 0.154
CD r
-------
PERKIN--ELMER M 1100 9B/10/15 PAGE 14
AA AA
MAIW? O.O16 MS/L HO 0.005 MAINs 0.017 MG/L HO O.OO5
MEAM; 0.016 MG/L SD; 0.001 RSDs 7.0
AA AA
MAINs O.OU MB/L HO 0.003 MAIN: 0.012 MB/L HO 0.003
CD MEANs 0.011 MB/L 3D: 0.001 RSDi 5.9
AA AA
MAIN; 0,499 MG/L HO 0.148 MAIN: 0.500 MS/I. HO O. 14
MEAN: 0,500 MG/L SDs 0.001 RSDs 0.2
AA AA
MAIN: 0.001 MG/L HO 0.000 MAIN: 0.002 MG/L HO O.OO1
CD !V!EAN; °-(>°2 MG/L SDs O.001 RSD: 35.5
A A A A
MAINs 0,030 MS/L HO 0.009 MAIN: O.O30 MB/L. HD O.OO9
CD /£ j MEANs 0.030 MB/L SD: 0.000 RGD: 0,6
AA AA
MAIN:: 0.415 MG/L HO 0.123 MAIN; 0,421 MG/L HO 0.1.25
CD 4-1 < MEAN: 0,418 MB/L SD: O.004 RSDs 0.9
A A A A
MAIN.- 0.038 MB/L HO 0,011 MAINt 0.038 MG/L HO 0.011
MEAN: O.O3B MB/L BD: 0.000 RSDs: 0.9
AA AA
MAINs O.O41 MG/L HD O.012 MAIN: O.044 MG/L HO 0.013
:i) -$3 MEANf 0.043 MB/L S»: 0.002 RSDr
i3...5
AA AA
MAIM; 0.0.24 MB/L HO 0.007 MAIN: 0.026 MG/L HQ 0.008
>k CD I MEAN: 0-025 MG/L SB: 0=001 RSD; 5,,B
AA AA
MAIN:. 0,412 MG/L. HO O., 122 MAIN: 0.406 MG/L. HO 0.. 121
CD /.£ MEAN; 0.409 MB/L SD: 0.005 RSDs 1.1
-------
PERKIN-ELMER M 1.1.00 9S/10/15 PAGE 15
AA AA
MAIN: O.O20 MS/L HO O.O06 MAIN: 0.02O MG/L. HO O.OOA
CD 7- MEAN: 0.020 MG/L SD: 0.OOO RBD; 0.1
AA AA
MAIN: 0.01B MB/L HO 0,005 MAIN: 0.018 MG/L HO 0.005
CD 7-X) MEAN* 0,018 MG/L SDs 0.000 RBDs O.B
AA AA
MAIN: 0.025 M6/L HO 0.007 MAIN: 0.025 MG/L HO 0.007
CD 3> MEANs 0-025 MG/L BD: 0.000 RSD: 0.1
AA AA
MAINs 0.511 MG/L HO 0. .152 MAIN* 0.514 MG/L HO 0.153
CD *e"^ MEAN: 0.513 MB/L SDs 0.002 RSD: 0.5
A A A A
MAIN: 0.005 MG/L. HO O. 002 MAIN: 0.005 ME/L HO 0.001
CD <"<:<& MEAN: O.OQ5 MS/L SD^ 0.000 RSD: 7,0
-------
BMA 400 Analysis Ver. 4.10 Fri 10/16/98 - 15sO5:lO
hod File Names CR
arks: CR ONLY
Wt file is 10236
cr267 EM
cr267 EM
cr267 EM
cr267 EM
cr267 AV
f^^lNlIDARD 4*2:
cr267 EM
cr267 EM
cr267 EM
r^l-MD^RD 4*2:
cr267 EM
cr267 AV
~rf=HMID«=fcRD 4*3
cr267 EM
r«iMD«Rr> 4*3
cr267 EM
r^MDftRr> 4*3
cr267 EM
rAIMDftRO 4*3
cr267 EM
Repl icates :4
REF^LICftTE 4*1
683
667
679
685
678.5 SD 8.1 CV
2848
2825
3371
REF>L_ I Crf=fc~TE 4*-*
2785
2957.3 SD 277.1 CV
REF>I_ I CftTE 4*1
5289
REF=-I_ I Crf=»jTE 4*2:
5532
•—^rr^i T i — ^^v^rFr* jf^s
r^_ ™^-. m m J- «^-^- W~~l • ™^-. ^r +~^r
5139
REF>l_IC^ftTE 4*-*
5327
Read Delay: 65
Data File:
1506 10/16/98
1.2 CONC 0.1OOO
1508 10/16/98
9.4 CONC 1 .OOOO
151O 1O/16/98
cr267 AV 5336.B SD 188.5 CV
3.5 CONC 2.OOOO
1512 10/16/98
cr267 EM 12473
REF^L I CftTE 4*2:
cr267 EM 12358
REF^L I CftTE 4*3
-------
I C<=kTI
cr267 EM 12446
cr267 AV 12453.0 SD
73.5 CV
O.6 CONC 5.OOOO
1514 1O/16/98
cr2&7
EM
514
cr267 EM
50fi
cr267
EM
489
cr267 EM 529
cr267 AV 5O9.5 SD 16.7 CV 3.3 CDNC
cr267 CC 0.9999 SLOPE 2393.3426 INT 508.8128
o.oooo
cr267
EM
cr267 EM
"^
cr267 EM
V
cr267 EM
cr267
cr267
B
cr267 EM
cr267
EM
cr267 EM
cr267
LOOS
cr267
L OO2
!. cr267
1002
cr267
LOOS
cr267
EM
cr267
cr267
B—3.
EM
B—1
EM
B—1
EM
B—1
EM
5005
164
5113
REF^L. I C#=*TE Wl
1.8782 mg/L
1516 10/16/90
1.9446 mg/L
ICftTE 41=3
1.9233 mg/L
REF"!—I C*=bTE 41=-*
2.1785 mg/L
-0.0133 mg/L
-0.0300 mg/L
-0.0313 mg/L
5724
AV 5251.5 EM
AV 1.9811 mg/L
477
437
434
496 -0.0054 mg/L
AV 461.0 EM SD
AV -O.O20O mg/L SD
446
490
475
464
SD 321.9 CV
SD O.1345 CV
6.1
6.79
44=1 1518 10/16/98
peak-noisy
window-edge
w i ndow—edge
«-*
window-edge
30.5 CV
O.0127 CV
6.6
63.74
-0.0262 mg/L
! 1520 10/16/98
peak-noisy
I CftTE
-0.0079 mg/L
-0.0141 mg/L
REF>1_ I
-0.0187 mg/L
peak-noisy
-------
cr267
AV
-O.O167 mg/L
SD
O.OO77 CV
-i
cr267
-±
cr267
-±
cr267
-±
cr267
-±
cr267
-a.
cr267
-±
cr267
-1
cr267
i
-ID
cr267
-ID
cr267
-ID
cr267
-AD
CV267
>— a.
cr267
> — a.
cr267
>— 1
cr267
> — 1
cr267
EM
EM
EM
EM
cr267
cr267
EM
EM
EM
EM
cr267
cr267
EM
EM
EM
EM
cr267
cr267
EM
EM
EM
EM
cr267
4119
3947
4154
4O42
AV
AV
3568
3640
3540
3524
AV
AV
3476
3637
3613
3455
AV
AV
3937
3902
3938
4404
AV
F£EF*I__ I GATE
1.5081 mg/L
REF*l_ I GATE
1 .4362 mg/L
1.5227 mg/L
1 .4759 mg/L
4*1
**s>
*3
4*4
4065.5 EM SD 91.8 CV
1.4857 mg/L SD O.O384 CV
FaEF"l_ I GATE
1 .2779 mg/L
1.3080 mg/L
1.2662 mg/L
REF>1_ I C^TE
1.2595 mg/L
3568. O EM SD 51
4*1
*s>
"»3
4*-4-
.3 CV
1.2779 mg/L SD O.O214 CV
REF*I_ I GATE
1.2395 mg/L
REF*1!— I G^TE
1.3067 mg/L
REF=-L_ I GATE
1.2967 mg/L
REF>I_ I GATE
1.2307 mg/L
3545.3 EM SD 93
4*1
4*2
4*3
4*-*
.0 CV
1.2684 mg/L SD 0.03BB CV
1.4320 mg/L
1 .4174 mg/L
1.4324 mg/L
REF>I_ I GATE
1.6271 mg/L
4045.3 EM SD 239
4*1
4*2
4*3
4*4
.8 CV
46.27
1522 1O/1G/98
2.3
2.5S
1524 10/16/98
1.4
1.68
1526 1O/16/98
2,6
3.06
1528 1O/16/98
5.9
-------
t_ r j_tjf
>— ±s
cr267 EM
>—IS
cr267 EM
>—IS
cr267
cr267
cr267
ft
ci-267
EM
>—IS
cr267 EM
cr267
cr267
EM
EM
cr267 EM
EM
cr267
cr267
cr267 EM
cr267 EM
cr267 EM
cr267 EM
cr267
cr267
cr267 EM
cr267 EM
cr267 EM
cr267 EM
cr267
7274
7597
7233
REF>L_ I CftTE
2.8260 mg/L
REF>L_ I CftTE
2.9609 mg/L
REF>1_ I CftTE
2.8088 mg/L
153O 1O/16/98
4*3
4*3
4*-*
7530
AV
AV
442
427
443
429
AV
AV
686
716
703
724
AV
AV
2 . 9329
7408.5 EM
2.8821 mg/L
REF>1_
-0 . 0279
REF*L_
-0.0342
REF>I_
-0.0275
REF*L_
-0 . 0333
435.3 EM
-0.0307 mg/L
0 . 0740
0 . 0865
REF3"!—
0.0811
0 . 0899
7O7.3 EM
0.0829 mg/L
mg/L
SD 181.8 CV 2.5
SD O.O760 CV 2.64
I CftTE 41=1 1531 10/16/98
mg/L peak-noisy
I CftTE 41=3
mg/L
. I CftTE 4*3
mg/L window-edge
I CftTE 4*-*
mg/L window-edge
SD 8.4 CV 1.9
SD O.O035 CV 11.45
I CftTE 4*1 1533 10/16/98
mg/L
mg/L peak-noisy
mg/L
I CftTE 4*-*
mg/L
SD 16.6 CV 2.3
SD O.0069 CV 8.37
538
533
557
REF>L_ I
O.0122 mg/L
41= ± 1535 1O/16/98
peak-noisy
REI=-L_ I OftTE 4*2:
0.0101 mg/L
I CftTE 4*3
0.0201 mg/L peak-noisy
567
REF>L_ I
0.0243 mg/L
4*«4-
peak-noisy
AV
548.8 EM
SD
16.0 CV
2.9
-------
JT
cr267 EM
JT
cr267 EM
JT
cr267 EM
JT
cr267 EM
cr267
cr267
cr267 EM
Cr267 EM
cr267 EM
cr2S7 EM
cr267
, cr267
REf=>l_ I GATE =1*1
-0.0087 mg/L
1537 1O/16/98
I CftT
0.0221 mg/L
-0.0250 mg/L
488
456
449
I
445 -0.0262 mg/L
AV 459.8 EM SD
AV -0.0205 mg/L SD
4703
5274
4799
I
4899 1.8339 mg/L
AV 4918.B EM SD
AV 1.8421 mg/L SD
peak-noisy
peak-noisy
peak—noisy
19.3 CV 4.2
O.OO81 CV 39.32
E *t=l 1539 1O/16/9B
1.7520 mg/L
1.9905 mg/L
RE:F>-I_ i cftTi
1.7921 mg/L
+1=3
25O.O CV
O.1O44 CV
5.1
5.67
cr267 EM
B
ci"2S7 EM
B
cr267 EM
B
cr267 EM
cr267
cr267
0.0233 mg/L
-O.O204 'img/L
453
460
441
455 -0.0225 mg/L
AV 452.3 EM SD
AV -O.0236 mg/L SD
-0.0283 mg/L
l 1541 10/16/98
peak-noisy
peak-noisy
peak-noisy
peak-noisy
8.1 CV 1.8
0.0034 CV 14.24
-------
CK2S7 EM
cr267 EM
cr267 EM
>—:
cr-267 EM
cr267
cr267
cr267 EM
cr267 EM
cr267 EM
cr267 EM
cr267
cr267
cr267 EM
cr267 EM
cr267 EM
cr267 EM
cr267
cr267
cr267 EM
cr267 EM
is—F-
cr267 EM
Jy-"*
111 •""
cr267 EM
cr267
413
437
424
-O.O4OO mg/L
O.O3OO mg/L
4*± 1543 10/16/98
peak-noisy
peak-noisy
-0,0354 mg/L
415 -0.0392 mg/L
422.3 EM SD
-O.O362 mg/L SD
peak-noisy
4*-*
window-edge
1O.9 CV
O.OO46 CV
1 CI=ITE 4*1
1.3882 mg/L
2.6
12.63
1545 1O/16/98
REF>1_]
1.4492 mg/L
REF»I_ICATI
1.5619 mg/L
41=3
I C*=*TE «=«=*
1.4638 mg/L
4017.8 EM
1.4658 mg/L
SD
SD
172.4 CV
O.O72O CV
4.3
4.91
AV
AV
3832
3978
4248
4013
AV
AV
415
447
432
434 -0.0313 mg/L window-edge
AV 432.O EM SD 13.1 CV 3.O
AV -O.O321 mg/L SD O.OO55 CV 17.11
REF*L_ I C#=I"T"E 4* 1 1549 1O/16/98
413 -0.0400 mg/L peak-noisy
4*2
peak-noisy
4*3
peak-noisy
F>EF*I_I
-0.0392 mg/L
REF3-!—!
-0.0258/mg/L
1 1547 10/16/98
peak-noisy
peak-noisy
F?EF*1_ I CftTE 4*3
-0.0321 mg/L peak-noisy
-0.0170 mg/L
-0.0225 mg/L
468
455
439 -O.O292 mg/L
AV 443.8 EM SD
23.7 CV
5.3
-------
*r
cr267
5
cr2£7
S
cr267
Et
cr2£7
3t
ct-267
3
cr267
*
cr267
3
cr267
^
cr267
i
cr267
3
cr267
3f
cr2£7
=V
cr267
^V
cr267
2V
cr267
?v
cr267
EM
EM
EM
EM
cr267
cr267
EM
EM
EM
EM
cr267
cr267
EM
EM
EM
EM
cr267
cr267
EM
EM
EM
EM
cr267
cr267
419 -0.0375 mg/L window-edge
REF=-|_ I GATE 4*2
419 -0.0375 mg/L peak-noisy
FaEF"I_ I GATE 4*3
433 -0.0317 mg/L peak-noisy
REf=*I_ICATE 4*-*
461 -0.0200 mg/L peak-noisy
AV 433. O EM SD 19.8 CV 4.6
AV -O.O317 mg/L SD O.OO83 CV 26.12
REF=-|_ I GATE 4* A 1553 1O/16/98
446 -O.O262 mg/L peak-noisy
REF^LICATE 4*2
452 -0.0237 mg/L
REF=-I_ i GATE: 4*3
453 -0.0233 mg/L peak -noisy
Rc-C3>| T f~ <-j~^-r*=r -«j- ^-i
1 a^ i J. ^— *•*—•• I i^. •• f m
444 -O.O271 mg/L peak-noisy
AV 448.8 EM SD 4.4 CV l.O
AV -0.0251 mg/L SD O.OO1B CV 7.37
FJEI=I_ I GATE 4*1 1555 1O/16/98
443 -0.0275 mg/L
C^^r-^^l x r"*"^"VT~F^ dHf^>
r"^c ^.r^i— j. ^— ^-rTi • ^^- *•*• -*^
444 -O.O271 mg/L peak-noisy
FSEIF'-L.IGATE 4*13
452 -O.O237 mg/L peak-noisy
REF>L_ICATE 4*-*
444 -O.O271 mg/L peak-noisy
AV 445.8 EM SD 4.2 CV O.9
AV -O.0263 mg/L SD O.OO18 CV 6.65
F?EF*I_ I GATE 4*1 1556 1O/16/98
5520 2.0933 mg/L
F>Ef=-L_ I GATE 4*2
5588 2.1217 mg/L
REF>I_ICATE 4*3
5657 2.1505 mg/L
REF>-|_ T GATE 4*-*
5580 2. 1183 mg/L
AV 5586.3 EM SD 56.1 CV l.O
AV 2.1210 mg/L SD O.O234 CV 1.10
rt-«
~r •—- r> '
-------
cr267
EM
cr267 EM
B
cr267 EM
cr267
cr2G7
cr267 EM
cr267 EM
cr267 EM
cr2G7 EM
cr267
cr267
-0.0158 mg/L
0.03OO mg/L
471
437
437 -0.0300 mg/L
AV 448.0 EM SD
AV -O.O254 mg/L SD
432
443
436
439 -0.0292 mg/L
AV 437.5 EM SD
AV -O.O298 mg/L SD
-0.0321 mg/L
-0.0275 mg/L
-0.0304 mg/L
peak-noisy
E =»-*
16.0 CV
O.OO67 CV
3.6
26.38
4*1 16OO 1O/16/9B
peak-noisy
peak -noisy
peak-noisy
peak-noisy
4.7 CV 1.1
O.OO19 CV 6.53
-------
tA 40O Analysis Ver. 4.1O
Men 10/19/98 - 14:34:28
3d File
-ks: CR
b file i
i=*NDPk
ftMr>«
f=kNDA
PkNOPh
f=hlN|D*=h
l=hlNlDA
PklMDA
PfeNDA
AlNlDAI
AlNlDAI
l=hlN|Dtf°tl
£%IMDtf°tl
PhlMDAI
PhNDAI
Name : CR
ONLY
5 1036
RD 4*1
cr267 EM
Rr> 4*1
cr267 EM
RD 4*1
cr267 EM
RE> 4*1
cr267 EM
cr267 AV
RD 4*2
cr267 EM
RD 4*2
c r267 EM
RD 4*2
cr2G7 EM
RD 4*2
cr267 EM
cr267 AV
RD 4*3
cr267 EM
RD 4*3
cr267 EM
RD 4*3
cr267 EM
R:D 4*3
cr267 EM
cr267 AV
RD 4*4
cr267 EM
RD 4*4
cr267 EM
Repl i -rates : 4
™,_io«-rE
733
738
742
758.0 SD 40.8
REF>I_ I CftTE
3063
REF*I_ I C«=*TE
3043
2965
REF>I_ I C*=fcTE
3123
3O4B.5 SD 65.2
REF*I_ I GATE
6422
REF*!- I GATE
5739
REF*L_ I GATE
57 B2
REF>1_ I GATE
5498
586O.3 SD 394.8
REF>L_ I C^TE
13437
13568
Read Delay: 65
Data File:
4*1 1437 1O/19/9B
4*2
4*3
4*4
peak-noisy
CV 5.4 CONC 0.1OOO
4*1 1439 10/19/98
4*2
4*3
4*4
CV 2.1 CONC l.OOOO
4* 1 1441 1O/19/98
4*2
4*3
4*4
CV 6.7 CONC 2.OOOO
4* 1 1443 10/19/98
4*2
4*4
REI=-1_ I CftTE 4*3
-------
AIMDARD 4*-*
cr267 EM 13968
V
ct-267
cr267
\S
cr267
B
cr267
ct-267
B
cr267
cr267 AV 13549.8 SD 312.4 CV
E 4*1
2.3 CONC 5.OOOO
1445 1O/19/98
AIMK
ftlMK
AIMK
cr267
cr267
cr267
EM
EM
EM
cr267 EM
cr267 AV
cr267 CC
EM 5227
cr267 EM
EM
EM
cr267
cr267
EM
EM
EM
cr267 EM
cr267
cr267
587
REF^I—ICATE 4*2:
694
REF*!— I CftT
580
E 4*-*
552
6O3.3 SD 62.4 CV 10.3 CONC O.OOOO
0.9999 SLOPE 2605.7290 INT 542.6687
E 4*1 1447 10/19/98
1 .7977 mg/L
1.8123 mg/L
1.8461 mg/L
5353
5384 1.8580 mg/L
AV 53O7.3 EM SD 73.5 CV
AV 1.8285 mg/L SD O.0282 CV
1.4
1.54
-0.0191 mg/L
REF"!— I CftTI
-0.0191 mg/L
493
493
482
560 0.0067 mg/L
AV 507.0 EM SD
-0.0233 mg/L
4*1 1449 1O/19/98
peak-noisy
4*2
peak-noisy
4*3
peak-noisy
4*-*
peak-noisy
35.7 CV
7.0
AV -0.0137 mg/L
SD O.0137 CV 100.12
OO3-Ol
cr267 EM
OO3-Ol
cr267 EM
O03 _ Ol
cr267 EM
479
497
521
REF=>I_ X
-0.0244 mg/L
-0.0175 mg/L
-O.0083 mg/L
1 1451 10/19/98
peak-noisy
peak-noisy
4*3
-------
cr2&7 EM
AV 498.8 EM
AV -O.O169 mg/L
514
53O
546
SD 17.2 CV
SD O.OO66 CV
3.5
39.19
I CftT
-0.011O mg/L
4*1 1453 10/19/9B
peak-noisy
I CftTE =t*S
-0.0049 mg/L
REF*I_ I
O.0013 mg/L
41=3
c 1-267
Jr2G7
c r267
cr2S7
cr267
/r267
crZ&J
EM
cr267
cr267
EM
.. EM
07
EM
EM
cr267
cr267
EM
4<
1, EM
542 -0 . 0003
AV
AV
493
487
496
474
AV
AV
|%£~572&
4687
533.0
-O.0037
-0
-0
R
-0
R
-0
487.5
-0.0212
R
1
R
1
EM
mg/L
EF*!-
.0191
EF^L
.0214
EF^L
.0179
EF3-!-
.0264
EM
mg/L
EF^L
.9892
EF*!-
.5905
mg/L
SD
SD O.
. IC*=fcTE
mg/L
. ICftTE
mg/L
. ICftTE
mg/L
. ICftTE
mg/L
SD
SD 0.
mg/L
mg/L
peak -noisy
14.4
OO55
4*
CV
CV
2
148.1
Bl
1 1455
peak -noisy
4*2
peak-
4*3
peak-
-noisy
-noisy
4*4
window-edge
9.7
0037
4*
4*:
CV
CV
1
2
2
17.1
.'
B'
1457
4*3
cr267 EM 4787
cr2&7 EM
cr267
cr267
cr267 EM 517
;cr267 EM 541
cr267 EM 554
cr267 EM 534
1.6288 mg/L
REF>L_ I CftTE 4*-*
1.8353 mg/L
5325
AV 5131.3 EM SD
AV 1.7610 mg/L SD
485.5 CV
0.1863 CV
9.5
10.58
REF=-|_ IGPfcT
-O.O099 mg/L
4*1 1459 1O/19/98
peak-noisy
REF"L_ i GATE: 4*2
-O.OOOE mg/L
0.0043 mg/L
4*3
peak-noisy
REF^L. I CPfcTEI 4*-*
-0.0033 mg/L peak-noisy
-------
cr267
cr267
cr267
cr267
cr267
cr267
cr267
cr267
cr267
cr267
cr267
cr267
cr267
cr267
cr267
cr267
cr267
EM
EM
EM
EM
cr267
cr267
EM
EM
EM
EM
cr267
cr267
EM
EM
EM
EM
cr267
cr267
EM
EM
EM
EM
AV -O.OO24 mg/L SD O.OO59 CV 249.'
REF^L I CftTE: 4*± 15Qi
501 -0.0160 mg/L peak-noisy
550 0.0028 mg/L peak-noisy
REF-L I C^TE 4*3
544 0.0005 mg/L peak-noisy
REF"L_ I GATE 4*-*
523 -0.0075 mg/L peak-noisy
AV 529.5 EM SD 22.2 CV 4
AV -O.OO51 mg/L SD O.OOB5 CV 168.'
RE1=1_ I CATE 4* ± 150:
535 -O.0029 mg/L
578 0.0136 mg/L peak-noisy
RER-LICATE: 4*3
561 O.O070 mg/L peak-noisy
«~^»T^hg ••• f^-JS^T^r -a*.j<«
• ~^ &^^ • L«B ^L ^i^rV^^ • •«« ^^^r ^^T
533 -O.0037 mg/L peak-noisy
AV 551.8 EM SD 21.7 CV 3
AV O.OO35 mg/L SD O.OO83 CV 238.'
REf=-|_ I CPlTE 4*1 150-
706 0.0627 mg/L
RrEF*l— ICrtTE 4*3
700 0.0604 mg/L
REf=-|_ I CftTE 4*3
679 0.0523 mg/L
715 0.0661 mg/L
AV 7OO.O EM SD 15.3 CV 2
AV O.O6O4 mg/L SD O.OO59 CV 9.:
REF*!— T CrtTE 4* 1 15O<
799 0.0984 mg/L
769 0.0869 mg/L
RER-L T CftTE 4*3
828 0.1O95 mg/L
REF»I_ I CftTE 4*-*
784 0.0926 mg/L
15OO 1O/19/98
1502 1O/ 19/98
1504 1O/ 19/98
15O6 1O/19/98
cr267
AV
795.O EM
SD
25.2 CV
3.2
-------
1508 1O/19/98
0-267 EM
0-267 EM
0-267 EM
0-267 EM
cr267
cr267
cr267 EM
V
cr267 EM
cr267 EM
cr267 EM
cr267
cr267
'l
B
cr267 EM
cr267
cr267
EM
EM
0-267 EM
cr267
cr267
692
724
687
780
0.0573 mg/L
I GATE
0.0696 mg/L
4*3
O.0554 mg/L
FSEF>I_ I CftTE 4*-*
0.0911 mg/L
720.8 EM
0.0683 mg/L
REI=>I_ I
2.1043 mg/L
2.1665 mg/L
R:EF>L i GATE 4*3
2.1262 mg/L
4*-*
I GftT
2.0990 mg/L
AV
AV
6026
6188
6083
6012
AV
AV
546
516
516
495 -0.0183 mg/L
AV 518.3 EM SD
AV -O.O094 mg/L SD
SD 42.8 CV
SD 0.0164 CV
E 4*±
4*2:
&O7703 EM
2.1240 mg/L
SD 8O.O CV
3D O.O3O7 CV
I GATE 4*1
0.0013 mg/L
O.0102 mg/L
I GAT
-O.O102 mg/L
5.9
24. Ol
151O 10/19/98
1.3
1.44
1512 1O/19/98
4*3
peak-noisy
peak-noisy
21.0 CV 4.0
O.O081 CV 85.93
OO& -
cr267
OO& .
cr267
QO& .
cr267
OO& -
cr267
1514 1O/19/98
EM
EM
1
EM
±
EM
cr267
1414
1402
1396
1508
AV 1430.0 EM
0.3344 mg/L
FSEF>I_ I GATE 4*3
0.3298 mg/L
4*13
I GATE 4*-*
0.3705 mg/L
0.3275 mg/L
SD
52.5 CV
3.7
-------
Jt file is 10236
> 4*1
C0228
» 4*1
C022S
> 4*1
C0228
CD228
C022S
n 4*2
CD228
» 4*2
C0228
CO228
• 4*3
C0228
• 4*3
CO228
CO228
CO228
i 4*-4
C0228
' 4*4
C0228
> 4*4
C0228
C0228
CD228
CD228
C022B
C0228
EM
EM
EM
AV
EM
EM
EM
AV
EM
EM
EM
AV
EM
EM
EM
AV
EM
EM
EM
AV
378
379
REF*
369
375.3
REF*
444
430
REF*
446
440. O
683
739
705
7O9.O
1538
1482
REF*
1537
1519.0
328
REF>
344
REF>
337
336.3
l_ I C<=fcTE
LXCA-TE
LICftTE
SD 5.5
LIC^TE
LIC«TE
l_ I CftTE
SD 8.7
Lio«-re
LICftTE
LicftTE:
SD 28.2
LICftTTE:
LICftTE
l_ I CftTTE
SD 32. O
LICftTE
LICftTE
LICftTE
SD B.O
4*1
1615 1O/22/98
4*2
peak -noisy
4*3
peak— noisy
CV
4*1
«*>
4*3
CV
4*1
*=
4*3
CV
4*1
*^
=t*3
CV
4* 1
4*2
4*3
CV
1.5 CONC 0.0200
1617 1O/22/98
2.O CONC O.O5OO
1618 1O/22/98
4.O CONC O.15OO
162O 1O/22/98
2.1 CONC O.5OOO
1622 1O/22/9S
2.4 CONC O.OOOO
C0228 EM
C0228 CC 0.9997 SLOPE 2379.9478 INT 333.2209
REF-LICftTE: 4*1 1624 10/22/98
1481 0.4823 mg/L
-------
C0228 EM
1536
0.5054 mg/L
CO 228 EM
CO228
CO228
;B
C0228 EM
C022S EM
C022B EM
CO228
C0228
LOOS-B—1
C0228 EM
L OOS . B— 1
C0228 EM
C0228 EM
CO228
CD228
C0228 EM
1
C0228 EM
C0228 EM
CD228
CO228
— 1
CO 228 EM
— 1
CO228 EM
,_,_ -•
CO22S EM
C0228
CD228
C0228 EM
1552
AV 1523.0 EM
AV 0.4999 mg/L
REF"!— I C*=fcTI
0.5121 mg/L
4*3
SD 37.2 CV 2.4
SD O.0156 CV 3.13
356
373
REF>I_ I
0.0096 mg/L
0.0167 mg/L
4*± 1625 10/22/98
peak-noisy
4*2
peak-noisy
368
AV
AV
375
404
0.0146 mg/L
365.7 EM SD
O.O136 mg/L SD
REP-LI
0.0176 mg/L
peak-noisy
8.7 CV 2.4
O.OO37 CV 26.93
4*± 1627 10/22/98
peak-noisy
387
ICrf=%TE
0.0297 mg/L
REF"I_I
0.0226 mg/L
4*3
window-edge
AV
AV
388.7 EM
O.O233 mg/L
395
397
379
AV
AV
0.0260 mg/L
REF>I_I
0.0268 mg/L
REF"I_I
0.0192 mg/L
39O.3 EM SD
O.0240 mg/L SD
SD 14.6 CV 3.7
SD O.0061 CV 26.28
4*1 1629 10/22/98
peak-noisy
peak -noisy
386
406
REF"!— I C<=»TE 4*1
0.0222 mg/L
peak-noisy
9.9 CV 2.5
O.OO41 CV 17.27
1631 1O/22/9B
O.0306 mg/L
385
AV 392.3 EM
REF*I_ I
0.0218 mg/L
peak-noisy
4*3
peak-noisy
AV
0.0248 mg/L
SD ll.B CV 3.0
SD O.OO5O CV 20.O4
39
REF>I_ I CPITE 4*1 1632 10/22/98
0.0247 mg/L peak-noisy
-------
1
*
»
>
ID
C0228
— ±
C0228
-|
C0228
C0228
— IS
CQ228
>— IS
C022S
>
-g J— ».
•L -i r
C0228
EM
C0228
CO228
EM
EM
EM
CO228
CO228
EM
EM
EM
C0228
C0228
FS
406 0
AV 4O1.3
EF»I_
.O306
EM
AV 0.0286 mg/L
F5
402 0
ER-L-
.0289
REF>I_
382 0 . 0205
R
385 0
AV 389.7
AV 0.0237
EF=-L_
.0218
EM
mg/L
I CftTE
mg/L
SD
SD O.
I CftTE
mg/L
I CftTE
mg/L
I CftTE
mg/L
SD
SD O.
REF-L I CftTE
2719 1 .O025 mg/L
R
2G57 0
R
2574 O
AV 265O.O
AV 0.9735
EF"I_
. 9764
EF»I_
.9415
EM
mg/L
I CftTE
mg/L
mg/L
SD
SD 0.
4*3
peak -noisy
B.I
0034
4*
CV
CV
2.O
11.87
1 1634 1O/22/98
peak-noisy
window-edge
4*3
peak-
1O.8
0045
4*
CV
CV
±
-noisy
2.8
19.11
1636 10/22/98
4*2
4*3
72.8
0306
CV
CV
2.7
3.14
C0228
EM
347
REH=-L. I
0.0058 mg/L
4fr±
1638 1O/22/98
peak-noisy
2ft
C0228 EM
2ft
C0228 EM
C0228
C0228
2ft
CO228 EM
2ft
C0228 EM
2ft
C0228 EM
C0228
CO228
2ft
C022B EM
359 0.0108 mg/L
REF>l_ICft-
397 0.0268 mg/L
AV 367.7 EM SD
AV O.O145 mg/L SD
REF*I_X Cft"
358 0.0104 mg/L
FE 4*2
FE 4*3
peak -noisy
26.1 CV 7.1
0.0110 CV 75.78
FE 4* 1 164O 1O/22/98
peak-noisy
REF-L I CftTE 4*2
381 0.0201 mg/L
RER-LICftTE 4*3
344 0.0045 mg/L peak-noisy
AV 361.0 EM SD
AV O.O117 mg/L SD
340 0.0028 mg/L
18.7 CV 5.2
0.0078 CV 67.25
FE 4* 1 1641 10/22/98
window-edge
-------
C0228 EM
CD228
CO228
C0228 EM
T
CD228 EM
r
C022B EM
C0228
C022B
lw>
C022a EM
V
CQ22S EM
V
C0228 EM
C0228
C0228
336
C0228 EM
B
C0228 EM
C0228 EM
C0228
C0228
AV
AV
370
4O4
378
REF>I_I
O.OO12 mg/L
342.7 EM SD
O.OO40 mg/L SD
REF^LI
0.0155 mg/L
4*3
peak-noisy
8.3 CV
O.OO35 CV
E 4*1
2.4
88.15
1643 10/22/98
RE
0.0297 mg/L
RE
0.0188 mg/L
peak-noisy
peak -noisy
AV
AV
1518
1484
1516
AV
AV
377
367
361
384. O EM SD
O.O213 mg/L SD
REF»l_r G^V
0.4978 mg/L
RER-L. X C#V
0.4835 mg/L
REF=-l_ lCrf=»-
0.4970 mg/L
1506.0 EM SD
0.492B mg/L SD
0.0184 mg/L
REFILL I Crf=fc-
0.0142; mg/L
REF^I—ICft-
O.O117 mg/L
17.8 CV 4.6
0.0075 CV 35.01
TE 4*1 1645 10/22/98
T-E 4*2
TE 4*3
19.1 CV 1.3
O.OO8O CV 1.63
FE 4*1 1646 10/22/98
peak-noisy
FE 4*2
window-edge
FE 4*3
peak-noisy
AV 36B.3 EM SD
AV O.014B mg/L SD
8.1 CV 2.2
0.0034 CV 23.02
C0228 EM
o—:
CD228 EM
C022B EM
C0228
CO228
c»—:
328
333
33S
-0.0022 mg/L
0.0001 mg/L
REf=-L_ I
O.0020 mg/L
AV 333.0 EM
AV -O.OOO1 mg/L
SD
SD
4*1 1648 10/22/98
peak-noisy
4*2
peak—noisy
peak-noisy
5.0 CV 1.5
O.OO21 CV 2263.92
4*1 1650 10/22/98
-------
C0228 EM
CO22S EM
C022B
C0228
2131
0.7554 mg/L
41=3
2069 0.7293 mg/L
AV 21O2.3 EM SD 31.3 CV 1.5
AV 0.7433 mg/L SD O.O131 CV 1.77
C0228 EM
C0228 EM
371
433
REF>-|_ICrf=fcT
0.0159 mg/L
O.0419 mg/L
4* 1 1652 1O/22/98
window-edge
peak-noisy
C0228
* — f=~
CO228
•W Jmmm., |
C0228
J — F~
C0228
3
C0228
3
C0228
3t
C0228
3
C0228
3
C0228
3
C022B
EM
CD22B
CD22B
EM
EM
EM
CQ228
CO228
EM
EM
EM
C022B
CQ22B
EM
EM
EM
CD22B
C0228
REF>I_
368 0.0146
AV 39O.7 EM
AV O.O241 mg/L
REF^L
343 O.OO41
REF>L
327 -0.0026
REF-L
356 0 . 0096
AV 342.0 EM
AV O.OO37 mg/L
REF>I_
353 0.0083
REF-L
353 0.0083
REF>I_
386 0 . 0222
AV 364.0 EM
AV 0.0129 mg/L
REF-L
347 0 . 0058
REF-L
381 0.0201
REF^L
358 0.0104
AV 362.0 EM
AV O.O121 mg/L
mg/L
SD
SD 0.
mg/L
-ICftTE
mg/L
-ICftTE
mg/L
SD
SD O.
Itl w ^S. "M " f ""
• — f'm m B^_
mg/L
_IC<=fcTE
mg/L
mg/L
SD
#3
peak -noisy
36.7 CV 9.4
0154 CV 63.87
41=1 1653 10/22/98
window-edge
#2
window— edge
#3
peak-noisy
14.5 CV 4.2
OO61 CV 165.46
41=1 1655 1O/22/98
peak-noisy
window-edge
#3
peak -noisy
19.1 CV 5.2
SD O.O08O CV 61.90
Im — .^"V. "" rf " j^^T
^•^P^l • TT^Lr
mg/L
1^^^ ^^*- ' 1 1 -
• — *• •""• • ^^^
mg/L
mg/L
SD
4*1 1657 10/22/98
peak -noisy
window-edge
4*3
peak -noisy
17.3 CV 4.8
SD O.OO73 CV 6O.28
C0228
EM
350
0.0071 mg/L
4*1. 1659 10/22/98
peak-noisy
-------
C022S EM
358
0.0104 mg/L
peak-noisy
C022B EM
CD228
CD22B
L/
C0228 EM
C0223
EM
C0228 EM
CO228
CD228
B
C0228 EM
B
C0228 EM
B
C0228 EM
CO228
CD228
CO22S EM
CO228 EM
C0228 EM
CQ22B
C0228
CO228 EM
C0228 EM
CQ228 EM
CD228
CO228
CD228 EM
REF=»-|_ I CftTE *3
0.0071 mg/L peak-noisy
SD
SD
X GAT
0.5016 mg/L
350
AV 352.7 EM
AV O.O082 mg/L
1527
1526
1587 0.5268 mg/L
AV 1546.7 EM SD
AV O.5O99 mg/L SD
4.6 CV
0.0019 CV
4*1.
1.3
23.75
1701 1O/22/98
0.5012 mg/L
34.9 CV
0.0147 CV
2.3
2.88
REF=»-|_ X Crf=fcT
0.0121 mg/L
0.0134 mg/L
362
365
374 0.0171 mg/L
AV 367.0 EM SD
AV O.O142 mg/L SD
«= ± 17O2 1O/22/9B
peak-noisy
peak-noisy
window—edge
6.2 CV 1.7
O.OO26 CV 18.49
I C<=fcTE # 1 1704 10/22/98
336 O.OO12 mg/L window-edge
peak-noisy
0.0058 mg/L
347
338 0.0020 mg/L
AV 34O.3 EM SD
AV O.OO30 mg/L SD
347
peak—noisy
5.9 CV 1.7
O.O025 CV 82.38
I CftTE
O.OO58 mg/L
346
343
AV 345.3 EM
0.0054 mg/L
REF"!— X Crf=fcT
0.0041 mg/L
=1*1 1706 10/22/98
peak -noisy
peak-noisy
AV 0.0051 mg/L
RER-
353 0.0083 mg/L
SD
SD
peak-noisy
2.1 CV 0.6
O.OOO9 CV 17.19
1
peak-noisy
-------
C0228 EM
CO22B
CO228
C0228 EM
ts
CQ228 EM
ts
CD228 EM
C0228
C0228
C0228 EM
C0228 EM
C0228
C0228
CD228
C0228
CD228
C0228
C0228
C0228
EM
C0228
C0228
EM
EM
EM
C0228
CD228
EM
EM
EM
CO228
CO228
EM
354 O.OOS7 mg/L
354.7 EM SD
O.O090 mg/L SD
REF*!-!
0.8743 mg/L
4*3
peak-noisy
AV
AV
2414
2464
I
2412 0.8735 mg/L
AV 243O.O EM SD
AV O.8810 mg/L SD
2.1 CV
O.OOO9 CV
4*1
4*2
0.6
9.71
1709 1O/22/98
O.8953 mg/L
29.5 CV
0.0124 CV
1.2
1.41
338
356
REF*!—I CPfcTE 4*1 1711 1O/22/98
0.0020 mg/L peak-noisy
peak-noisy
O.OO96 mg/L
F5EIF»I_ I CPfcT
O.OOS2 mg/L
355
AV 349.7 EM 3D
AV O.OOG9 mg/L SD
REF>I_I
354 O.OO87 mg/L
I
352
347 0.0058 mg/L
AV 351.0 EM SD
AV O.O075 mg/L SD
339
peak-noisy
10.1 CV 2.9
0.0043 CV 61.51
E 4*1 1713 1O/22/98
window-edge
O.OO79 mg/L
window-edge
4*3
peak-noisy
3.6 CV
0.0015 CV
l.O
20.28
I CPfcHTI
O.OO24 mg/L
0.0028 mg/L
340
354 O.OOB7 mg/L
AV 344.3 EM SD
AV 0.0047 mg/L SD
REF»I
403 0.0318 mg/L
REF*I_I
4*1 1714 10/22/98
peak-noisy
peak-noisy
window—edge
8.4 CV 2.4
O.O035 CV 75.47
4*1 1716 10/22/98
peak—noisy
4*2
-------
CQ228 EM
CD228
CO228
C022B
EM
C0228 EM
C0228 EM
C022B
CO228
C022B EM
C0228 EM
CO228 EM
CO228
CO22S
k/
CO228 EM
V
C0228 EM
^
C022B EM
CQ228
CO228
412 0.0331 mg/L
AV 414.7 EM SD
AV 0.0342 mg/L SD
448
413
peak-noisy
7.4 CV l.B
0.0031 CV 9.05
0.0482 mg/L
± 1718 10/22/98
peak-noisy
O.O335 mg/L
REIF-I- i C^TE: 4*3
O.O541 mg/L peak-noisy
462
AV 441.O EM SD
AV O.0453 mg/L SD
25.2 CV
0.0106 CV
5.7
23.42
416
396
RlEf^l- I
0.0348 mg/L
0.0264 mg/L
41=3. 1720 10/22/98
peak-noisy
4*2
peak-noisy
RE:F*L. i C^TE: =1*3
O.O323 mg/L peak-noisy
SD
SD
0.5171 mg/L
410
AV 4O7.3 EM
AV 0.0311 mg/L
1564
I
1570
I
1646 O.5516 mg/L
AV 1593.3 EM SD
AV O.5295 mg/L SD
1O.3 CV
O.OO43 CV
4*±
2.5
13.85
1721 10/22/98
0.5197 mg/L
El 4*3
45.7 CV
0.0192 CV
2.9
3.63
CQ228 EM
Et
C0228 EM
B
C0228 EM
C022B
CD228
352
366
35O
r C#VTI
0.0079 mg/L
4*3.
1723 10/22/90
O.O138 mg/L
window-edge
i CATE: 4*3
0.0071 mg/L peak-noisy
AV 356.0 EM SD
AV O.OO96 mg/L SD
8.7 CV
0.0037 CV
2.4
38.27
-------
1A 400 Analysis Ver. 4.10 Thu 10/15/98 - 14:52:14
?d File Name: CD
rks: CU ONLY
t file is 10236
CU324
CLJ324
CU324
CU324
CU324
CU324
CU324
CU324
CU324
CU324
PhMDARD 4*3
CU324
CU324
CU324
CU324
t=*NI3ARE> 4*-*
CU324
CU324
EM
EM
EM
AV
EM
EM
EM
AV
EM
EM
EM
AV
EM
EM
EM
AV
Repl icates:3
2893
REF="I_ I C*=b~TE 4*:2
2322
3032
2949. O 3D 73.3 CV
REF=-|_ I Crf=V~TE #±
18716
18102
REF^I_IC<=*TE 41=3
18600
1B472.7 SD 326.2 CV
36619
RERL. I CftTE 4*S
36754
36078
36483.7 SD 357.7 CV
REF^L- I C<=»TE # ±
87901
REF*L_ICft~TE *»3
89983
RERLIOftTE 41=3
9O163
89349.0 SD 1257.2 CV
Read Delay: 60
Data File:
1455 10/15/98
2.5 CONC O.1OOO
1457 10/15/98
1.8 CDNC l.OOOO
1459 10/15/98
l.O CONC 2.OOOO
15O1 1O/ 15/98
1.4 CDNC 5.OOOO
REF*I_I
CU324 EM 1381
REF*I_ I CftTE
CU324 EM 1310
15O2 10/15/98
-------
CLJ324 tn
CU324 AV 1285.0 SD 11O.6 CV 8.6 CONC O.OOOO
CU324 CC 1.0000 SLOPE 17636.554 INT 1136.6479
CU324 EM
CU324 EM
CU324 EM
CU324
CU324
1.98O1 mg/L
1 .9853 mg/L
36O59
36151
I
3690O 2.0278 mg/L
AV 3637O.O EM SD
AV 1.9977 mg/L SD
4*1
4*2:
4*3
461.3 CV
0.0262 CV
1504 10/15/98
1.3
1.31
CU324
EM
1289
0.0086 mg/L
4*1 1506 10/15/98
peak-noisy
B
CU324
B
CU324
oos
CU324
O02:
CU324
002
CU324
1
CU324
1
CU324
1
CU324
1
CU324
EM
EM
CU324
CU324
EM
- B— 1
EM
- B— 1
EM
CU324
CU324
EM
EM
EM
CU324
CU324
EM
1294
1229
AV
AV
1792
1852
1842
AV
AV
3S93
3780
3746
AV
AV
3459
REF>I_
0.0039
0 . O052
1270.7 EM
O.OO76 mg/L
mg/L
mg/L
SD
SD O.
REF»I_ I C*=»TE
O.O372 mg/L
O.0406
REF>L_
0.04OO
1828.7 EM
0.0392 mg/L
0.1393
0.1499
mg/L
ICrf=fcTE
mg/L
SD
SD 0.
mg/L
mg/L
RE:F>L_ i C^TE:
0.1480 mg/L
3706.3 EM
O.I 457 mg/L
0.1317
SD
SD 0.
mg/L
4*2:
peak-noisy
4*3
peak-
36.2 CV
0021 CV
4*1
**
4*3
32.1 CV
0018 CV
4*1
4*2:
4*3
99.6 CV
0056 CV
4*1
-noisy
2
26. <
15O<
1,
4.1
150<
2,
3.{
1513
15O8 10/15/98
1509 10/15/98
1511 10/15/98
-------
CU324
EM
3534
0.1359 mg/L
1
CU324
ID
CU324
ID
CU324
ID
CU324
— 1
CU324
— 1
CU324
'—1
CU324
I
• — IS
CU324
»-m j_ fc
J. — *
CU324
>— IS
CU324
CU324
CU324
CU324
-2ft
CU324
EM
CU324
CU324
EM
EM
EM
CU324
CU324
EM
EM
EM
CU324
CLJ324
EM
EM
EM
CU324
CU324
EM
EM
EM
CU324
CU324
EM
3570
AV
AV
3456
3471
3445
AV
AV
3627
3410
3373
AV
AV
36048
36402
36139
REF*L
0. 138O
3521. O EM
0.1352 mg/L
REF>L
0.1315
REF>L
0.1324
REF>L
O.I 309
3457.3 EM
O.1316 mg/L
REF*L_
O. 1412
REF"L
0.1289
RER-L
0.1268
3470.0 EM
0.1323 mg/L
REF'-L
1.9795
_icftT
mg/L
SD
SD <
.ICftTl
mg/L
mg/L
. ICftTl
mg/L
SD
SD <
mg/L
mg/L
mg/L
SD
SD <
mg/L
REF>L_ I CftTI
1.9996 mg/L
REF>L
1 . 9846
AV 36196.3 EM
AV
1197
1191
1194
AV
AV
1416
1.9879 mg/L
REF>L_
0 . 0034
REF"L_
0.0031
REF"I_
0.0033
1194.0 EM
O.OO33 mg/L
REF-L
0.0158
mg/L
SD
SD (
.ICftTl
mg/L
mg/L
.ICftTl
mg/L
SD
SD C
.ICftTl
mg/L
: 4*3
56.6 CV
.OO32 CV
: 4*1
13.1 CV
0.0007 CV
I 4*3
137.2 CV
0.0078 CV
E 4*1
E 4*2
E 4*3
183.8 CV
0.0104 CV
1.6
2.38
1513 1O/15/9B
0.4
O.56
1515 10/15/98
4.0
5.88
1517 1O/15/98
4*1
0.5
0.52
1518 10/15/98
peak-noisy
4*3
peak-noisy
3.O CV
0.0002 CV
4*1
O.3
5.23
1520 1O/15/98
-------
CU324
CU324 EM
CU324
CU324
EM
EM
CU324 EM
CU324
CU324
CU324
CU324
CU324
CU324
CU324
REF>I_ I
O.0137 mg/L
CU324
CU324
CU324
SD
SD
0.0127 mg/L
0.0081 mg/L
EM
EM
1379
AV 14O4.O EM
AV O.0152 mg/L
1361
128O
1334 0.0112 mg/L
AV 1325.O EM SD
AV 0.01O7 mg/L SD
REF*I_I
1243 0.0060 mg/L
REF*!—!
1235 0.0056 mg/L
4*3
21.7 CV
O.OO12 CV
4*1
1.5
8.1O
1522 10/15/98
41.2 CV
O.OO23 CV
I 4*1
3.1
21.90
1523 1O/15/98
T
CU324
V
CU324
EM
CU324
CU324
EM
1283
AV
AV
38342
O.OO83 mg/L
1253.7 EM SD
O.OO66 mg/L SD
2.1209 mg/L
4*2
window-edge
4*3
peak-noisy
EM
EM
CU324
CU324
EM
EM
EM
CU324
CU324
38326
25.7 CV
0.0015 CV
'E 4* 1
REF"I_IC*=*TE 4*3
2.1087 mg/L
REF"I_ I Crf=fcTE 4*3
2.1501 mg/L
2.1
21.98
1525 10/15/98
33057
AV 38641.7 EM SD
AV 2.1266 mg/L SD
375.6 CV
0.0213 CV
1367
1356
REF>1_ I C*=fcT
O.O131 mg/L
4*1
1.0
l.OO
1527 10/15/98
ICrtTE
0.0124 mg/L
REF>1_ I Crf=fcTE
0,0138 mq/L
peak-noisy
4*2
peak-noisy
4*3
1380
AV 1367.7 EM SD
AV O.O131 mg/L SD
12.0 CV O.9
O.OOO7 CV 5.20
CU324
EM
1376
REF>l_ICl=*TE
0.0136 mg/L
4*1
1529 10/15/98
-------
CU324 EM
1376
0.0136 mg/L
peak-noisy
CU324 EM
CU324
CU324
CU324 EM
CU324 EM
2AS
CU324 EM
CU324 EM
CU324 EM
CU324
CU324
CU324 EM
CU324 EM
CU324 EM
CU324
CU324
CU324 EM
RE:F»L_ i
0.0155 mg/L
1410
AV 1387.3 EM
AV 0.0142 mg/L
30235
29750
SD 19.6 CV
SD O.OO11 CV
#±
1.4
7.83
1531 10/15/98
1.6499 mg/L
I GATE
1.6224 mg/L
CU324
CU324
CU324
CU324
EM
CU324
CU324
EM
EM
EM
CU324
CU324
31039
AV
AV
1178
1181
1170
AV
AV
1 . 6955
30341.3 EM
1.6559 mg/L
REF-L
O . 0023
REF^L
0 . OO25
REF»L
0.0019
1176.3 EM
0.0023 mg/L
mg/L
SD 651. O
SD 0.0369
.ICftTE 4*
mg/L
. I GATE *:
mg/L
mg/L
SD 5.7
SD O.OOO3
CV
CV
1
peak-
2.1
2.23
1532 10/15/98
-noisy
2
peak-noisy
3
peak-noisy
CV
CV
0.5
14.33
1340
1317
I GATE =H= 1
0.0.115 mg/L
1534 10/15/98
0.0102
I GftT
mg/L
=1*3
1329
AV 1328.7 EM
AV 0.0109 mg/L
1260
1234
REF-L. I GftHTE 4*3
0.0109 mg/L
SD 11.5 CV
SD O.OOO7 CV
0.0070
I
mg/L
O.9
5.99
1536 1O/15/98
1273
AV 1255.7 EM
AV O.OO67 mg/L
12Q8
0.0055 mg/L
RE:F>L_ i
0.0077 mg/L
SD
SD
19.9 CV
O.OO11 CV
E #1
1.6
16.68
1538 1O/15/98
0.0086 mg/L
-------
CU324 EM
CU324
CU324
CU324 EM
CU324
CU324
CU324 EM
1318 0.0103 mg/L
AV 13O4.7 EM SD
AV O.O095 mg/L SD
peak-noisy
15.3 CV
O.OO09 CV
1.2
9.09
1539 1O/15/98
CU324
CU324
CU324
V
CU324
V
CU324
V
CU324
!
B
CU324
B
CU324
B
CU324
CU324
CU324
EM
EM
EM
CU324
CU324
EM
EM
EM
CU324
CU324
EM
EM
EM
CU324
CU324
EM
EM
1304
1334
1332
AV
AV
41066
40184
41O89
AV
AV
1273
1426
1272
AV
AV
1327
1366
0 . OO95
FSE:F>I_
0.0112
REIR-U
0.0111
1323.3 EM
0.0106 mg/L
REF*L
2 . 2640
mg/L
. IC*=fcT
mg/L
. ICftT
mg/L
SD
SD i
. IC*=*-TI
mg/L
RE£F>I_- I CftT
2.2140 mg/L
RE£F>I_
2.2653
40779.7 EM
2.2478 mg/L
mg/L
SD
SD <
REF-L- I CftTI
0.0077 mg/L
REF*I__
0.0164
0.0077
1323.7 EM
0.01O6 mg/L
O.0108
0.0130
ICftTI
mg/L
mg/L
SD
SD <
ICftTI
mg/L
I Crf=fcTI
mg/L
1331
O.011O mg/L
AV 1341.3 EM SD
AV O.0116 mg/L SD
1465 O.0186 mg/L
X
16.8 CV
O.OO10 CV
#1
1.3
8.98
1541 1O/15/98
516.O CV
O.O293 CV
1.3
1.30
4* 1 1543 10/15/98
peak-noisy
#2
peak-noisy
e.7
47.39
1545 10/15/98
88.6 CV
O.O050 CV
41=1
#2
21.5 CV
0.0012 CV
1.6
10.48
1547 1O/15/98
-------
CU324 EM
CU324
CU324
CU324 EM
CU324 EM
CU324 EM
CU324
CU324
5
CU324 EM
5
CU324 EM
S
CU324 EM
CU324
CU324
CU324 EM
CU324 EM
CU324 EM
CU324
CU324
CU324 EM
CU324 EM
CU324 EM
CU324
CU324
CU324 EM
CU324 EM
1519
AV 149O.3 EM
AV O.O2O1 mg/L
1304
1299
FSEF=-I_ i c ATI
0.0217 mg/L
SD
SD
4*3
27.2 CV
O.OO15 CV
4*1
0.0095 mg/L
i GATE: 4*2
0.0092 mg/L
FiEF>l_ICATE 4*3
0.0090 mg/L
1295
AV 1299.3 EM SD
AV O.O092 mg/L SD
4.5 CV
O.OO03 CV
4*1
32616
32426
REF>L_ I CAT
1.7849 mg/L
REF>L_ I CATE 4*:2
1.7741 mg/L
FJEF>l_ICATE +1=3
1.7671 mg/L
32303
AV 32448.3 EM SD
AV 1.7754 mg/L SD
1459
1442
1493
AV 1464.7 EM
AV O.O1B6 mg/L
1647
1674
REF>l_I
0.0183 mg/L
REF>L_ I CATE
0.0173 mg/L
REF>L_ I CATE
0.0202 mg/L
157.7 CV
O.O089 CV
=: 4*1
SD 26.0 CV
SD O.O015 CV
•L 4*1
0.0289 mg/L
0.03O5 mg/L
1.8
7.6S
1548 1O/15/98
0.3
2.77
155O 1O/15/98
0.5
0.50
1552 1O/15/98
1.8
7.92
1553 1O/15/98
1697 O.O318 mg/L
AV 1672.7 EM SD
AV O.0304 mg/L SD
1529
REF^L-I CATI
1531 0.0224 mg/L
I CAT
0.0222 mg/L
peak-noisy
25.0 CV 1.5
O.OO14 CV 4.67
4*1 1555 10/15/98
peak-noisy
-------
CLJ324 EM
CU324
CU324
CU324 EM
CU324 EM
CU324 EM
CU324
CU324
CU324
EM
CU324 EM
CU324 EM
CU324
CU324
!
CU324 EM
CU324 EM
CU324 EM
CU324
CU324
CU324 EM
CU324 EM
CU324 EM
CU324
CU324
CU324 EM
:B
CU324 EM
1470 0.0189 mg/L
AV 1510.O EM SD
AV O.O212 mg/L SD
3679
3654
34.7 CV
O.OO2O CV
E 4*1
0.1442 mg/L
REf=-L. I
0.1427 mg/L
REF>I_ i
0.1410 mg/L
SD
SD
3624
AV 3652.3 EM
AV O.1426 mg/L
4844
4875
I
4907 0.2138 mg/L
AV 4B75.3 EM SD
AV 0.212O mg/L SD
27.5 CV
0.0016 CV
I CftTE =1*1
0.2102 mg/L
REF>L_ T
0.2120 mg/L
31.5 CV
O.OO1B CV
4641
4695
4789
FJEF>I_ I CftTE 4*1
0.1987 mg/L
REF>I_ I CftTE
0.2018 mg/L
0.2071 mg/L
AV 47O8.3 EM
AV 0.2025 mg/L
37874
SD 74.9 CV
SD 0.0042 CV
T GATE 4*1
2.0830 mg/L
38366
38573
AV 38271.O EM
AV 2.1055 mg/L
1442
1333
2.1109 mg/L
FSEF>I_ I CrtTE 4*3
2.1227 mg/L
SD 359.1 CV
SD 0,0204 CV
4*1
O.0173 mg/L
F£EF=>1_ I CftTE 4*2:
O.O111 mg/L
2.3
9.28
1557 1O/15/98
0.8
1.09
1559 10/15/98
O.6
0.84
16O1 1O/15/98
1.6
2.1O
16O2 10/15/98
0.9
O.97
1604 10/15/98
-------
OOS
CU324
QO&
CU324
OO&
CU324
CU324
CU324
1
EM
. ±
EM
_ ±
EM
CU324
CU324
CU324 EM
CU324 EM
CU324 EM
CU324
CU324
CU324 EM
CU324 EM
CU324 EM
CU324
CU324
CU324 EM
CU324 EM
CU324 EM
CU324
CU324
CU324 EM
CU324 EM
I O<=»T
0.2223 mg/L
\j . •>.< a. •>.<*. my/ i_
AV 1363.7 EM SD
AV O.0129 mg/L SD
5058
I
4994
I
5053 0.2221 mg/L
AV 5035.O EM SD
AV 0.2210 mg/L SD
68.4 CV
0.0039 CV
#1
0.2187 mg/L
4587
4592
REF=-L_ I
0.1956 mg/L
35.6 CV
0.0020 CV
4*1
4651
AV 4610.O EM
AV 0.1969 mg/L
0.1959 mg/L
REF*L_ I
O.1993 mg/L
SD
SD
Cl
O.1978 mg/L
35.6 CV
0.0020 CV
4659
0.1997 mg/L
4*12
REPLICATE 4*3
0.1982 mg/L
SD
SD
0.2031 mg/L
4633
AV 4639.0 EM
AV 0.1986 mg/L
4718
4626
4785 0.2069 mg/L
AV 47O9.7 EM SD
AV 0.2026 mg/L SD
34111
17.8 CV
0.0010 CV
#2
0.1978 mg/L
79.B CV
O.OO45 CV
1.8697 mg/L
5.O
30.12
16O6 1O/15/98
0.7
0.91
16O8 1O/15/98
O.8
1.02
1609 10/15/98
0.4
O.51
1611 1O/15/98
1.7
2.23
1613 10/15/98
35403
1.9429 mg/L
=11=3
-------
V
CU324
V
CU324
V
CU324
CU324
CU324
EM
EM
EM
CU324
CU324
AV
AV
35849
37568
36700
AV
AV
343Q3.3'
1.B8O6
R
1
EM
mg/L
EF>I_
. 9682
SU
SD
mg/L
REF>I_ I C#V
2.OS57 mg/L
R
2
367O5.7
2. 0168
EF^l-
.0165
EM
mg/L
101 /.* LV
O.OS77 CV
TE 4*±
T~E 4*2
O.lut
3.O7
*Dl3
.1C ATE 4*3
mg/L,
SD
SD
859.5 CV
0.0487 CV
2.3
2.42
CU324
CU324
B
CU324
EM
EM
EM
CU324
CU324
I CU324
,MF>I_E
CU324
EM
10/15/98
I CATE =1*1
1616 1O/IS/98
1441
1263
O.O173 mg/L
0.0072 rtig/L
peak-noisy
peaN-noisy
EM
1276
AV 1326.7 EM
AV O.O108 ing/L
1369
1337
REF^L I Cl=*T"E 4*3
0.0079 mg/L
SD 99.2 CV
SD O.0056 CV
4*±
7,5
52.22
1618 10/15/98
0.0132 mg/L
I CPlTTE
0.0114 mg/L
-------
:iement File: PB.GEL
iate: 10/14/98
)ata File:
"echniaue: HGA
Element; Pb
Time: 15:32
ID/Wt File: 81OO2.IDW
Calib. TVDe: Nonlinear
Wavelength: 283.:
Slit: 0.7 L
Lamp Current: 10
Energy: 46
ID: BLANK
Sea. No.: 00094
A/S Pos.: O
Date: 10/14>
'.eolicate 1
seak Area (A-s): -0.001
Background Pk Area (A-s): 0.030
Hank Corrected Pk Area (A-s): -0.002
Concentration fua/L ): -0.6
Time: 15:32 .
Peak Heiaht (A): 0.011
Backaround Pk Heiaht (A)
0.046
3s=ak Area (A-s): -O.001
Sackaround Pk Area (A-s): 0.025
31ank Corrected Pk Area (A-s): -0.002
Concentration (ua/L ): -0.5
Time: 15:35
Peak Heiqht (A): O.014
Background Pk Height (A)
0.041
lean Cone (ug/L ):
per-formed.
-0.6
SD: O.O2
RSD C/.): 4.31
ID: IO PPB PB
Sea. No.: OO095
A/S Pos.: 1
Date: 1O/14;
^eolicate 1
=eak Area (A-s): O.020
Background Pk Area (A-s): O.O33
plank Corrected Pk Area (A-s): 0.021
Zoncentration (ua/L ): 5.6
Time: 15:39
Peak Heiqht (A): O.O56
Backaround Pk. Heiqht (A): O.049
3.eoil cats 2
Deak Area (A-s): O.O23
Sackoround Pk Area (A-s): 0.034
Blank Corrected Pk Area (A-s): O.O23
"oncentration (uo/L ): 6.3
Time: 15:42
Peak Heiaht (A): O.O53
Backaround Pk Heiaht (A): O.O44
""lean Cone (uo/L
6.0
SD: 0.47
RSD C/.): 7.93
Standard number 1 applied. [10.0]
Correlation coefficient: 1.OOOOO
Slope: 0.0022
Pb
ID: 50 PPB PB
Sea. No.: OOO96 A/S Pos.: 2
Date: 10/14/
Reolicate 1
Peak Area (A-s): O.117
Backoround Pk Area (A^s): O.051
Blank Corrected Pk Area (A-s): 0.118
Concentration (ug/L ): 53.2
H"=D? icate 2
Peak Area
-------
lean Cone (uo/L 1: 53.? SD: O.97 RSD ('/.): l.BO
itandard number 2 applied, [50.0]
:orrelation coefficient: 1 . OOOOO Slope: O.O022
'b ID: IOC PPB PB Sea, No.: OOO97 A/S Pos . : 3 Date: 10/14,
Jeolicate i Time; 15:52
'eak Area (A-s): 0.234 Peak Height (A): 0.451
tackaround Pk Area ( A™s ) : 0 .077 Background Pk Height (A): 0.106
tlank Corrected Pk Area (A-s): O.234
:oncentration (ug/L )s 90.5
-:=n3.ic3te 2 Time: 15:55
»eak Area b ID-. 2OO PPB PB Sea. No.: O009Q A/S Pos.: 4 Date: 10/14/
?enlicate i Time: 15:59
'eak Area IA-s): O.419 Peak Height (A): O.754
lackground Pk Area (A-s): 0.129 Background Pk Height (A): 0.213
31ank Corrected Pk Area (A-s):. 0.419
Concentration (ug/L ): 171.2
2. . Time: 16:02
'eak Area (A-s):.0.4O7 Peak Height ( A ) s 0.743
Backoround Pk Area (A-s): O.124 Background Pk Height (A): 0.198
31ank Corrected Pk Area (A-s): 0.40S
Concentration (ug/L ): 166.8
lean Cone fua/L ): 169.0 SD : 3.07 RSDC/.): 1.82
D-shaoed calibration curve detected. 2-coef. equation used.
Standard number 4 applied. P200.01
Torrelation coefficients 0.99B37 Slooe: 0.0024
-------
Calibration - Ci \ftfl OS I
0.41,
VI
i "
a
D.
^-"'"^
^
j^
#J*^*
GssT'
^ Nonlinear
r~y^ C?rr. Cosf".: C.**437
^* »^l 5j.o&(*' 0 Uu24>
0 Carvcentf otlon £OO.D
*
1
b ID; ICV
eolicate 1
oncentration (ug/L ): 100.1
eolicate 2
oncentration Cua/L )j 102.7
Sea. No.: OOO99 A/5 Pos.
Time: 16:O7
Time: 16:10 .
: 5
ean Cone olicate 2
Concentration (ua/L V: 1.7
Sea. No.: 00100 A/S Pos.
Time: 16il4
Time: 16:17
lean Cone (uo/L ): 1.6 SD: O.10
iC samole is within ranae —5.49 - 5.49
Date: 1O/14/
RSD (7.): 6.16
>b ID: 81.O02.8-i Sea. No,
ieolicate 1
Concentration fuq/L ): 19.5
?=o 1 icate 2
Concentration lua/L ): 19.1
tean Cone (ua/L ): 19.3
001O1 A/S Pos.: 6
Time: 16:20
Time: 16:23
SD: 0.26
Date: 10/14/
RSD (•/.)-. 1.33
3b ID: 81002.8-1
i'e o 1 i c a t e i
. on csr, t rs. 1 i c-.r* > ...-3
Sea. No.: 00102
i/S FOB. : 7
Date: 1C/14/1
-------
RSD ('/.): 5.91
••, •-. . •-,, -,,,-,, -..-,, /i. -.. r. "• i '-,"-% "v ",- •" • ™- *V *v ",- *v -V '• • -v --T- f\ • *v "V -\- V TJ- 'V- -^ 'V '"V »V *V*\,'V'V'V'V'V'\'*V'W'\*'\*'V'V*V*V'V'V'V'\*'V'V'\*A*1^'\'*V'\*^'VIVV'\*'V*V\*'VI
fj ir.: Rloo~.8-l Sea. No.: OO1O3 A/S Pos . s 7 Date: 10/14,
eolicate 1 Time: 16:33
oncentratiDn (uo/L ): 114.4
eolicate 2 Time: 16:36
oncentration (ug/L ): 114.1
ean Cone v'ua/L ): 114.3 SD: O.21 . RSD(%): 0.18
ecoverv is 9O.8"/.
h TD: 9:1002.9-1 Sea, No.: 00104 A/S Pos.: 8 Dates 10/14>
enlicate 1 Time; 16:4O
oncentration (ua/L ): 22.5
=?Dlicate "2 Time: 16:43
oncentration (uq/L ): 19.1
iean Cone (un/L ) i 20. 8 SD: 2.4O RSD ( 7. } : 11.5:
}b T.D: 81002.10-1 Sen. Mo.: OO105 A/S Pos.: 9 Date: 1O/14/
'eolicate 1 Time: 16:46
;oncentration (ua/L 1: 26.4
;<=Dlicats 2 Time: 16:49
loncentration (uq/L ): 25.4
lean Cone (ua/L ): 25.9 SD: 0.73 RSD ('/.): 2.81
'H TD: 81002, B-2A Sea, No.: OO106 A/S Pos.-. 10 Date: 10/14/
ieolicate 1 Times 16:53
.'oncentration (ua/L ); 2.9
'oncentration (ua/L }: 5.1
lean Cone (uq/L ): 4.0 SD : 1.51 RSD(7=): 37. 8S
3h TD: 81002. 1-2A Seo . No.: 00107 A/S Pos . : 11 Date: 1O/14/
'eolicate 1 Time: 16:59
Concentration iuo/L ): IB. 4
?<=nlirst£ 2 Time: 17-.O2
-concentration (ua/L ): 18.5
-------
ean Cone (ua/L
IS. 5
SD: O.O5
RSD (*/.): 0.29
h ID: 81002.1-2A Sea. No.
eolicate 1
oncentration (uq/L ): 115.B
= ol icste. 2
oncentration (ua/L ): 115.2
O010B A/S Pos.: 11 Date: 1O/14/
Time: 17:05
Time: 17:09
ean Cone (ua/L
ecoverv is 97.17.
115.5
SD: 0.42
BSD ('/.): 0 .36
h ID: 810O2.2-2A
eolicate 1
oncentration (uo/L ): 12.7
f=n 1 i cats 2
:oncpntration ('ua/L ): 14.3
Sea. Mo
lean Cone (ua/L ):
13.5
O0109 A/S Pos.
Time; 17:12
Time: 17:15
SD: 1.13
12 Date: 10/14/
RSD m : 8 .36
>b ID: S1002.3-2A
?eol icate 1
Concentration (ua/L ): 15.9
>e=>ol icate 2
Concentration (uo/L ): 17.2
Sea. No.: OO110 A/S Pos,
Time: 17:18
Time: 17:21
13 Date: 10/14/
lean Cone (uo/L ):
16.6
SD: O.SB
RSD ('/.) : 5 .34
fb ID:
i cate 1
'concentration £ua/L ): 104.3
Sea. No.: OO111 A/S Pos.
Timet 17:25
Time: 17:28
:oncentration (ua/L ): 99.2
lean Cone fua/L 1
101.7
SD: 3.57
3C samole is within ranae 79.5 - 120.49
Date: 10/14/
RSD(V.) : 3.51
=h TO: CCB
;.HD! icate 1
Concentration (ug/L 5: 0.4
Concentration (ua/L ): -1.4
Sea. No.: OO112 A/S Pos.! 0
Time: 17:31
Time: 17:34
Date: 10/14/
-------
ean Cone
-------
ecoverv is BO. 07.
h TO: 81O03.U2 Sea. No.:
eolicate 1
oncentration (ug/L ): 36.9
=?D 1 i cate 2
oncentration (ug/L 5: 35.8
iean Cone (ua/L ): 36.4
00130 A/5 Pos.: 23 Date: 10/14/
Time: 19:23
Time: 19:26
SD: 0.76
RSD ('/.): 2.10
OO131 A/S Pos.: 24 Dates 10/14/
Time: 19:29
Time: 19:32
'h TOs 81OO3.U3
,'eol icate 1
loncentration (ug/L ) s 27.7
!f=ol i cste '2
:oncentration (uq/L ): 27.1
Sea. No,
lean Cone (ua/L ):
27.4
SD: 0.45
RSD C/.): 1.63
'h TD: CCV '
feolicate 1
Oncentration (uq/L ): 106.4
:PD! i ca ts 2
Concentration (ug/L ): 108.4
Sea. Mo.: OO132 A/S Pos.
Time: 19:36
Time: 19:39
lean Cone (ua/L ): 107.4 SD: 1.44
)C samole is within ranae 79.5 — 120.49
Date: 10/14/'
RSD(%): 1.34
Jh TD: CCB
?s?nlicate 1
Concentration (uo/L ); 5.1
?=olicate 2
!.oncentration (ug/L ): 5.1
Sen. No.s 00133 A/S Pos.: 0 Date: 10/14/1
Time: 19:42
Time: 19:46
lean Cone (uo/L ): 5.1 SD: O.06
3C samole is within range -5»49 - 5.49
RSD C/.): 1.17
TD: 8] 005,0-1
^'V'^r^-'V'V'^'V^^-'VA^'VAf'V'V'V'V'V'VfAfAf'V'V'^^'V'V'V'V'V^f'V'VAf'^'V'V'V'V^^'V^'^^'V'^'V'V'
Seo. No.: 00134 A/S Pos.: 31 Date:
Concentration (ug/L ): 11.1
~.'&ri ] i c
Concentration (ug/L ): 10.9
Time: 19:49
Time: 19:52
-------
ean Cone (ug/L ): 11. 0 SD: 0.11 RSDC/.): 1.01
h ID: B1005.1-1 Sea. No.: 00135 A/S Pos . : 32 Date: 10/14
enlicate 1 Times 19:55
oncent ration (ua/L ): 39,6
•polieate 2 Time: 19:58
ancentration luo/L ): 38.8
lean Cone
-------
'b ID: BIOO5.1-2A Sen. No.: OO140 A/S Pas.: 35 Date: 10/14/
eolicate 1 , Time: 2O:28
:oncentration (up/L ) : 122.1
:f=olicate 2 Times 20:31 .
:oncentration (uq/L ): 121.4
lean Cone (uq/L ): 121.8 3D: 0.50 ' RSD(7.): 0.41
tecoverv is 1O2.6*/,
'h TD: 81005. 2-2A Sea. No.: O0141 A/S Pas.: 36 Date: 10/14/
.'eolicate 1 Time: 20:35
Concentration (uq/L ): 40.0
2 Time: 20:38
Concentration (ua/L 3s 39.5
lean Cone (uq/L 1: 39.8 SD: O.37 RSD (*/.): O.94
* ^f *v ^*^/ 'w JV^'%j'V *V^i*^* *V 'W'V ^^'\>'W* ^*^V ^f^f *\* *\?^ *\t ^ ^ *V ^f^ f\f^f^f^f ^» ^f ^r ^•'V'^ *V*^ ^* ^^^ff^^^f^f i\ff\ff^f ^ ^f r^ff\jJ\t f^t+l? ^ f^-f^rf\f ^ ^ ^,^^ "N*^ ^*^* ^^^^*^
>h TD: CCV Sea. No.: OO142 A/S Pos . : 3 Date: 10/14/
(eolicate 1 Time: 20:41
Concentration (uq/L ): 114.1
leolicat.B 2 Time: 20:44
foncentration (uq/L ): 109.9
lean Cone (up/L ): 112.0 SD: 2.96 RSDC/.): 2.65
3C samole is within range 79.5 - 120.49
"V^V 'X» ^*^V *V^ *V *Vj *V *V *\»*V
IDs CCB Sec. No.: OO143 A/S POB . : 0 Date: 10/14/
1 Time; 20:48
Concentration (uq/L ) : 3.B
: 2.7 SD: 1.64 RSD ('/.): 61.05
3C samole is nithin ranqe -5.49 - 5.49
-------
PERKINS-ELMER
M 1100
98/10/15
PA BE 1
MAlNs -0.000
PB MEAN5-0.000
A A
HO-0., 000
AA
MAIN: -0,000 HO O.OOO
SDn 0.000 RSDs 99 „ 9 AUTOZERO 0.000
MAIN: 0.003
AA
HO 0„OO3
MAINs 0.003
AA
HO O.OO3
PB MEANs 0.003
MAIN:
AA
0.48 MBXL HO O.OO7
SDt 0,000 RSD.' 2.2 1. STANDARD 0.20 MB/L
AA
MAIN: 0.48 MB/L HO 0.007
MEANs 0.48 MB/L SDs 0.001 RBD: 0.3 2.STANDARD 0.50 MB/L
AA
AA
MAINE 0.9S MS/L HO 0.014 MAIN; 1.00 MS/L HO 0.015
PB MEANs 0.99 MB/L SDr, 0.017 RED: 1,7 3. STANDARD 1.00 MB/L
A A
AA
MAIM: 1,97 MS/L HO 0,. 029 MAIN: 1,95 MB/L HO O.O29
PB MEAN: 1.96 MB/L. SDs 0.015 RBD: 0,8 4. STANDARD 1.99 MB/L
MAIM: 5,. 00 MB/L
AA
HO 0„072
MAIN:
AA
5.01 MB/L HO 0.073
PB
MEAN; 5.00 MG/L SDs O.OO7 RSD: 0.1
TANDARD 5.00 MS/L
FLftiC DISPLftY CALIBRATION MODE
ELEMENT; PE
REPL. 3 OF 2
\
PRINTER: ON
B6 CORP.: OFF
UNITS J MG/L
FIBS.
S2
SI
CONCENTRATION (MS/L )
ftBS, READING
S5 fifl ; 0,073
5.00
STATISTICS
MEAN: 5.00
SD: 0.007
RSIX%): 0.1
C2R2; 2.5 L/MIN OXIDftNT; 8,0 L/HIN
FLflMEs C2H2-PIR
AA
AA
MAIN:
-0..0! MB/L HQ-0,000 MAIN; 0,02 MB/L HO 0.000
i¥:EANs 0..01 MB/L 9Or 0,. O7& RSDt 99,, 9 AUTD7FRO O, 00
-------
PERK1W--ELMER H 1100 98/10/15 PAGE 2
AA AA
MAIN: 1.98 ME/L HO O.O29 MAIN: 1.92 MG/L HP 0,028
PB ^f\J MEANs 1.95 MG/L SD: 0.039 RSD: 2.0
AA AA
MAIN; O.O1 MB/L HQ O.OOO MAIN; 0.00 MG/L HO 0..000
PB - MEAN: 0.01 MG/L BD: O.OO7 RSD; 99.9
A A A A
MAINs 1.0.2 ME/L HO O.OiS MAIN; 1.04 MB/L HO 0,015
PB
j MEAMs K03 MB/L SDs 0.018 RSDs 1.7
AA AA
MAIM; 3.00 MG/L HO 0.044 MAIN: 2.95 MG/L HO 0.043
PB 3 MEAN: 2.9B MG/L SDs 0.036 RSD; 1.2
AA AA
MAINs 1.54 MG/L HO 0.022 MAIN: 1.53 MG/L HO O.022
PB O- *" MEANs 1.53 MB/L SD: 0.010 RSD: 0.6
AA AA
MAIN; 1.55 MG/L HO 0.022 MAIN'. 1.60 MG/L HO 0.023
PB <£X.£> MEAN: 1.57 MB/L SD: 0.03B RSDs 2.4
_-,....._., ,..-.,«...„._.. „-.,.__ _....,„. «.._,^.«^, .„..„..„..._._„ ..,.„,^„_.».„M_^„„_..^„„,_.™1,«_...,.„_u..»^u„..t^„i.t„»^„„»-„,w„™..__ —_^, —.....,..,. ....
f
\
AA '' AA
MAIN: 1.28 MG/L HO 0.019 MAIN; LTD i^G/L HO 0,0:19
PB ,f"i MEAN: 1 .2?" MG/L ?Z. O.ODI RSD;
AA AA
HA;:;:: ...':?.: -':o/:_ I-IG 0,029 MAINS 1.93 MB/L. HO 0,028
•'''-'• ffv KE'AN; .U 95 MB/L BD£ 0,039 RBDr 2,0
AA . AA
-0.0? MG/L. HO~G,OOO MAIN? -0.01 MG/L. HO-0.000
MEANs -O.02 MB/L BD: O.OO9 RSD: 55.4
AA AA
MAINs 0.46 MG/L HO 0.007 MAIN: 0.41 MG/L HO 0.006
PB / MEAN: 0,43 MB/L. SD: 0.036 RSD: 8.2
-------
PERKIN-ELHER M 1100 9B/1.0/15 PAGE 3
AA AA
MAINs 2,41 MB/1. HO 0,035 MAIN: 2.36 MS/L HO 0-034
PB /_£, MEANs 2,3B MG/L SD: 0.034 RSDs 1.4
AA AA
MAIN: 0.33 MG/L HO O.OO5 MAIMs 0.36 M6/L HO 0.005
PS "V MEAN is 0,34 MG/L SD: 0.021 RSD:
AA AA
MAIN: 0,35 MB/L HO 0.005 HAIIvs 0.30 MB/L HO O.O04
PB 2-D MEAN:; 0.32 MB/L SD: 0.037 R5D: 11.4
AA AA
MfliN: 0,33 MB/L HO 0.005 MAIN: 0.38 MB/L HO 0.005
PB £ MEAN: 0.35 MG/L SDs 0.036 RSD: 10.1
AA AA
MAIN; 1.94 MG/L HO 0.028 MAIN: 1,. 94 MG/L HO 0.028
PB MEAN: 1.74 MG/L EDs O.OOS RSD: 0.3
AA AA
MAINs -0.02 MS/L HO-0.000 MAIN: -0.05 MB/L HO-0,,001
MEAN: -0.03 MG/L SD: O.023 RSD: 69.5
-------
PERKIN-ELMER
M 1100
98/10/15 PAGE 4
MAINE -O.OOO
AA
HO-O.OOO
MAIM: -O.OOO
AA
HO O.OOO
MN
MEAN: --O.OOO
SO* 0.000 RSD: 52.8 AUTOZERO O.OOO
MAINs 0.006
AA
HO 0.006
MAIN: 0.006
AA
HO 0.006
MM MEANs 0.006 SO: O.OOO RSD: 1.1 1.STANDARD 0.050 MB/L
AA
MAIN: 0.101 MG/L HO 0.013
AA
MAIN: 0.102 MG/L HO O,013
MN MEAN; 0.101 MB/L SD: 0.000 R3D: 0.3 2,STANDARD 0.100 MB/L
AA
AA
MAIN: 0.194 MB/L HO 0.025 MAIN-. 0.20O MG/L HO O.O26
MN MEAN: 0.197 MG/L SDt 0.005 R6D: 2.3 3.STANDARD 0.199 MG/L
A A
AA
MAINs 0.516 MG/L HO 0.065 MAIN: 0.514 MG/L HO O.O65
MN MEANs 0.515 MB/L SDs 0.002 RSD: 0.3 4.STANDARD 0.503 MG/L
AA
AA
MAINs 0.943 MB/L HO 0,122 MA.IN: 0.950 MB/L HO O.I23
MN MEAN; 0.947 MB/L BD: 0.005 RSD: O.6 5.STANDARD 0.987 MG/L
AA
MAINt 1.015 MG/L HG 0.126
AA
MAIN: 0.988 MG/L HO 0.123
MN MEAN; 1,002 MB/L BD; 0.019 RSD; 1.9 5,, STANDARD 0.990 MG/L
FLfiME I> I SPLAY CALIBRATION MODE
ELEMENT; MN
REPL, 0 OF 2
0.125
ABS.
PRINTER: ON
B6 CORR: OFF
UNITS : MG/L
,990
ABB, READING
S5 AA ; 0.123
SI
CONCENTRATION (MG/L )
1.000
STATISTICS
MEAN: i.002
SD! 0.019
~» RSDCJO; 1,9
C2H2: 2,5 L/MIN OXIDftNT: 8,9 L/MIN
FLAME: C2H2-AIR
-------
PERKIN-ELMER M 11OO 9B/1O/15 F'ABE 5
AA AA
MAIN: 0.005 MB/L HO-Q.OOO MAIM: 0.004 MB/L HO-O.QOQ
MN MEANs O.OOS MG/L SDs 0.001 RSD: 18.9 AUTDZERO 0,000
AA AA
0.494 MG/L HO 0.062 MAIN: 0.499 MB/L HO O.063
MEAN: 0.496 MG/L SDs O.OO4 RSD: 0.7
AA AA
MAINs 0.001 MG/L HO O.OOO MAIN: -0.001 MG/L HO-O.OOO
MIM^JJ MEAN: -0.000 MG/L SD: 0.002 RSD: 99.9
AA AA
MAIN; 0,050 MG/L HO 0,006 MAIN; 0.057 MG/L HO O.OO7
MN _ 1 MEANs 0.053 MB/L SD: 0.005 RSD; 9.9
AA
MAIMs 4.074 MB/L HO 0.513
£61 Sample concentration greater than highest standard
AA
MAIN: 4.113 MB/L HO 0.518
E6I Samp 1 ejstSn cent ration greater than highest standard
MEANs >K 094 MB/L SD: 0.027 RSD? 0.7
AA AA
MAIN; O..O04 MG/L HO 0,001 MAINs 0.005 MB/L HO 0.000
MM <( MEf;r:. 0.005 MG/L SDs O.OO1 RSD: 19. E AUTOZERO 0.000
AA AA
MAIN; 0.352 MS./L HO 0,044 MAIN: 0.360 MB/L HO 0.045
MN r-O MEAN: 0,356 MG/L SD: 0.006 RSDi 1.6
AA AA
MAIN: O.B4B MB/L HO 0,107 MAIN: 0.845 MB/L HO 0.1O6
...,„ ,_ MEAN; O.B47 MG/L SD: 0.002 RSD: 0.3
ss.'ssssssrKis.ra*! .try s;-,^«,irr:,,.,=r-:5,= ^==ti=5-s:5: :-. — , — -- —. - - » —-
AA AA
MAIN! 0.680 ME/L HO 0,086 MAIN: 0.687 MG/L HO O.OB7
MN?-UC~ MEAN: 0.684 MB/L SD: 0.005 ftSDt O.B
-------
PERKU4-ELMER M 11OO 98/10/15 PAGE 6
AA AA
MAINt 0.684 MB./L HO 0.086 MAIN: O.6B5 MB/L HO 0.086
^ : 0.6B4 MB/L SD: O.OO1 RBD: 0.1
AA AA
MAINE 0. 106 MG/L HO O.O23 MAINs 0.195 MG/L HO 0.024
MN /6~lv!i£>MEAN: 0.190 MB/L SD: 0.006 RSD: 3.1
AA AA
KAIN: O.OSB MB/L HO O.O07 MAINs 0.063 MG/L HO O.OOB
MN -2-J MEANs 0.061 MG/L SDs 0.003 RSDs 5.0
AA AA
MAIN; O.061 MB/L HO O.OOG MAIN: O.061 MB/L HQ O.OOB
MEAN: 0.061 MG/L SDs O.OOO RED: 0.2
AA AA
MAIN; 0.428 MG/L HO 0.054 MAINs 0.445 MB/L HO O.O56
MN S-~2^»MEAN: 0.436 MG/L SDs 0.012 RSD: 2.7
AA AA
MAINs 0.480 MG/L HO 0.060 MAIN: 0.486 MG/L HO 0.061
MN ccx/ MEAN: 0.483 MG/L BD: O.OO4 RSDt 0.9
A A A A
MAIN: 0.001 MG/L HO 0.000 MAINs 0.001 MG/L HO 0-000
MN f<-& MEAN: 0.001 MG/L SD: 0.000 RSD: 32-8
AA AA
MAINs 0.167 MB/L HO 0,021 MAIN: 0.166 MG/L HO 0,O21
MM 5-tJ MEAN: 0,167 MG/L. SD; 0.001 RED: 0.5
AA AA
MAIN: 0.168 MG/L HO 0.021 MAIN: 0,148 MB/L HQ O.O19
?-*(•&
MEAN: 0.158 MG/L SD: O.015 RBDs 9.2
AA AA
MAINs 0.067 MG/L HO 0,009 MAIN: 0.065 MG/L HO O.OOB
MN /(rt{ MEAN: O.O66 MB/L SDs 0.001 RBDs 1.8
-------
PERKIN-ELMER M 1100 98/10/15 PAGE 7
AA AA
MAINs CK02B MB/L HO 0.004 MAIN,- 0,, 026 MB/L HO O.O03
MEANs 0.027 MB/L BD: 0.001 RSD: 4_9
AA AA
MAINs 0.026 MB/L HO O.O03 MAINs 0.024 MB/L HO 0,003
MN fL&rf MEAN: 0.025 MB/L 3D: 0.002 RSD: 7.4
AA AA
MAINs 0.025 MB/L HO O.O03 MAIM: 0.027 MB/L HO 0.003
MN MEAN: 0.026 MB/L SD: 0.OO1 RSDs 5.2
AA AA
MAIN: -0.015 MB/L HO-0.002 MAIN: -O.014 MG/L HQ 0,000
JIN OG» MEAN: -0.014 MB/L SDs 0.001 RSD;: 3.6 AUTDIERO O.OC
AA AA
MAJNs 0.025 MG/L. HD 0,003 MAIN: 0.022 MB/L HO O.003
MN ^ MEAMs 0.02-'! MB/i... SDs 0.002 RSDs 7.7
AA AA
MAIM: 0.029 MB/I. HO 0.004 MAIN: 0.025 MB/L HO O. 003
MM MEANs 0.027 MG/L SD: O.OO3 RSD; 11.0
AA AA
MAIN;; 0,497 MB/L HO 0,O63 MAIN: 0.497 MG/L HO O. O63
MN rv/ MEAN: 0,497 MG/L BDs 0.000 RSD: 0.1
AA AA
MAIN: -0,006 MB/L HO-O.OOl MAIM: -0,008 MB/L HO-0,,001
MM rc<3 MEAN: -0.007 MB/L BD: O.OO1 RSD: 12.5
AA AA
MAIM; -0.006 MS/L HQ-O.001 MAIN: -0.009 MG/L HO-0.001
MN * J-/6 ME AN: -0.007 MG/L SO: O.OO2 RSD: 26.1 AUTOZERO O. 000
AA AA
MAIN: 0.029 ME/L HO 0.004 MAIN.", O.O2B MB/L HO 0.004
MN @-\ MEAN: O.O2B MG/L BD: 0.001 RSD: 2.4
-------
PERKIN-ELMER M 1100 9B/10/15 PAGE B
AA AA
MAINi: O.O&4 MS/L HO O.O08 MAIN; 0.067 MG/L HO O. O08
MN 3_£. MEAN; 0.065 MG/L SDs O.004 RSD: 6.2
AA AA
MAIN: 0.033 MB/L HO 0.004 MAIN: 0.034 MG/L HO O.O04
MEAN: 0.034 MG/L SDs 0.000 RSD: 1.4
AA AA
MAIN: 0.027 MG/L HO 0,003 MAIN: O.O31 MB/L HO 0,004
MN U\ MEANs 0.029 MB/L SDs O.OO3 RSDs 10.8
AA AA
MAINi O.O32 MG/L HO 0.004 MAIN: 0.029 MS/L HO O.OO4
MN W 1- MEANs 0.031 MG/L SD: O.O02 RSD: 5.6
AA AA
MAINS 0.014 MG/L HO 0.002 MAIN: 0.013 MG/L HO 0.002
MN (A •> MEANs 0.014 MG/L SDs 0.001 RSDs 6.5
AA AA
MAIN: 0.489 MB/L HO O.O62 MAIN: 0.4GO MS/L HO 0.060
MN
-------
PERKIN-ELMER M 110O 98/10/15 PAGE 9
AA AA
MAIN: 0.451 MG/L. HO O.O57 MAINs 0.465 MB/L HO O.O59
MN /T-L- MEAN; 0.45S MS/L SDs 0.010 RBD: 2.2
AA AA
MAINs 0.446 MG/L HO 0,056 MAIN: 0.442 MG/L HO 0,056
MN <3« MEANs 0.444 MG/L SD: 0.003 RED: 0,6
AA AA
MAIN: 0.494 MG/L HO 0.062 MAIN: 0.516 MG/L HO 0.065
f MEAN: 0.505 MG/L BD: 0.016 RSD: 3.1
AA AA
MAIN: O.B79 MG/L HO 0,111 MAIN; 0.885 MG/L HO 0.111
MN MEANs 0.862 MB/L 3D: O. OO4 RSD: 0.5
AA AA
MAIN: O.345 MG/L. HO 0.043 MAIN: 0.322 MG/L HO O.041
MN MEANs 0.334 MG/L SDs O.O17 RSD: 5.0
AA AA
MAIN." 0.333 MG/L HO 0.042 MAINs 0,336 MG/L HO O.O42
MN 2-I> MEANs 0.334 MG/L SDs 0.002 RSD: 0.6
AA AA
MAIM: 0.359 MG/L HO 0.045 MAIN: O.356 MG/L HO 0.045
MN 3 MEAN: 0.358 MB/L BD: 0.003 RSD: 0.7
AA AA
MAIN: 0.473 MG/L HD 0., 060 MAINs 0.475 MG/L. HO 0.060
MEAN: 0.474 MG/L BD: 0.001 RSD: 0.2
AA AA
MAIN: -0.016 MG/L HO-O. O0.2 MAINs -0.020 MG/L HO-O.003
MN MEANs 0.0IB MG/L. EDs O.OO3 RBDs 17,7
-------
PARKIN-ELMER M 1100 "' '" ~ 98/10/20 PABE 2
HG AA-BG BB
MAINs 0.CO1 PA O„030 0.005
PH O.OO1 0.000
O.OOO AUTD2ERD
HB AA-BG BB
MAIN: 0.010 PA 0.141 0-018
PH 0.010 0.000
0.5O I,STANDARD .
HS AA-EB BB
MAIN-. 1.21 UG/L PA 0.428 -0.040
PH 0.025 -0,001
E61 Sample concentration greate-r than highest, standard
1.03 2.STANDARD
HB AA-E6 BG
MAIN: 1.70 UG/L PA 0.657 -0.025
PH 0.042 -0.001
E61 Sample concentration greater than highest standard
1.91 3.STANDARD
HG AA-BG EG
MAINs 5.75 UG/L PA 2,020 0-024
PH 0.125 0.002
E&l Sample concentration greater than highest standard
5.10 4.STANDARD
HG AA-BB BB
HA IN s 11.31 UB / L PA '1.198 0, O21
PH 0.27E 0.003
E61 Sample concentration greater than highest standard
10,25 5.STANDARD
-------
PERKIN--ELMER
M 1100
9B/10/2O
PAEE 3
HSft DISF
ELEMENT
0,278"
ABS.
:'LAY CALIBRATION MODE
HG - PEAK HEIGHT
^^
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SI S2
PRINTER: ON
B'3 CORR: ON
UNITS : UG/L
CH.MfiSS:
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MAIN; 4,. 79 UB/L. PA
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HB $JZ V
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MA I' M ;. •••• 0 , 03 UB / L P A-
HB it£
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HB CIS
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35 AA-B6; 4.198
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PEAK HEIGHT (A)
AA-BG i 0,278
BG! 0,003
i
£5
UB/L
UB/L
UG/L
UB/L
LIG/L
UG/L.
UB/L
UG/L
UB/L
UB/L
AA-BB
PA-0.09S
PH-0.004
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PH- 0.000
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-------
PERKIN-ELMER
M 11 CO
98/10/20
PAGE 4
HG
MAINf
HG
MAIN;
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-O.O6 UG/L PA
PH
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0.19 UG/L PA
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AA
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MAIM: 0,19 UB/L
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HG $ [
MAIN'S 0,22 UG/L
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0.0.13
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MAIN:
HG
MAIN:
0.24 UG/L PA
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0.32 US/L PA
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HG Cf^J
MAINE 4.76 UG/L
MAI
0.03 UG/L.
AA-BB
PA 2.145
PH 0. 129
AA-BG
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PH 0.001
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-0.001
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MAIN:
-0.06 UG/L PA-
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0.09 UG/L PA
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AA-BG
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MAIN*
7.39 UG/L
AA-BG BG HB AA-BG
PA 3.307 0.008 MAIN: 7.34 UG/L PA 3.355
PH 0.200 0.001 PH 0.199
HB
MAIN;
2.19 UG/L
AA-BG
PA 0,935
PH 0.059
BG
0.021
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MAIN:
2.29 UG/L PA
PH
HG
MA I Mr
4.42 UB/L
AA-BG
PA 2., 141
PH 0.120
BG
0,007
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MAIN:
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AA-BG
0.951
0. 062
AA-BG
-0 „ 066
-0.002
BG
0.050
0. 002
BG
0.011
0.002
BB
-0.009
-0.001
-------
PERKIM-ELMER
M 1 100
98/10/20
PAGE 5
HB Q -2*R,
MAIN: 2.38 UG/L
HB Z*»-*3
MAINs 1,27 US/L
HB
MAINs 1,30 UG/L
HB ^'^B
MAIN: 1..O8 UB/L
HB f£
MAIN; 4,95 UG/L
PA
PH
PA
PH
PA
PH
PA
PH
PA
PH
AA-BB
1 „ 083
O. O64
AA-BB
0 . 542
0.034
Pi A -EG
O.603
O.035
AA-BB
0.493
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2 . 283
0. 134
BG
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MAIN:
HB
MAIN:
HG
MAIN:
HB
MAINs
HG
MAINS
2. 17 UG/L PA
PH
1.37 UB/L, PA
PH
1.24 UB/L PA
PH
1.24 UG/L PA
PH
C^TI
-0.09 UG/L PA-
PH-
AA-BQ
O.993
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AA-BG
0.579
0.037
AA-BG
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0.538
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--0.016
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-------
Element File: NI.GEL
•ate: 10/19/98
•ata File:
echniaue: HGA
Element: Ni
Time: 1O:O9
ID/Wt File: 81OO2.IDW
Calib. Tvoe: Linear
Wavelength: 232.0
Sliti 0.2O L
Lamo Current: 25
Energy: 47
li
ID: BLANK
Sea. No,: O0001
ieolicate 1
'eak Area eak Area (A-s)J 0.016
Jackoround Pk Area (A-s): O.O63
jlank Corrected Pk Area (A-s): --O.Oi4
i
: O.O78
Blank Corrected Pk Area (A-s): O.032
•lean Pk. Area (A-s):
0.03O
Time: 10:22
Peak Height (A): O.032
Background Pk Height (A): 0.030
Time: 10:25
Peak Height
-------
K
ID: 5O PPB MI
Sea. No,
OO004
A/S Pos.: 2
Date: 1O/19
aeak Area (A~s): 0.103
Background Pk Area (A-s): 0.093
31ank Corrected Pk Area (A-s): 0.085
-oncentration (uo/L ): 56.3
l. icats 2
Area (A-s): O.097
Background Pk Area (A-s): 0.102
31ank Corrected Pk Area (A-s): 0.079
Concentration (utg/L ): 52.6
lean Cone (ug/L ):
54.4
Standard number 2 aoolied. T5O.OT
Zorrelation 'coefficient: O.99739
Time: 10:2B
Peak Heiqht (A): O.O56
Background Pk Heiqht (A): 0.037
Time: 10:32
Peak Height (A): O.054
Background Pk Height (A); 0.041
SD: 2.62
Slope: O.0016
RSD ('/.): 4 .82
TD: 1QO PPB MI
Sen, Mo,
=eak Area ( A-s ') : 0.190
Backaround Pk Area (A-s): 0.125
Blank Corrected Pk Area (A-s): 0.172
Concentration (uq/L 1: 106.0
00005
A/S Pos.-. 3
Date: 10/19
Time: 10:35
Peak Height (A): 0.097
Backaround Pk Heiaht (A): 0.046
icate 2
beak Area f A-s ) : 0.191
Background Pk Area (A-s): O.133
Blank, Corrected Pk Area (A-s): O.173
Concentration (ua/L ): 106.5
Mean Cone (ua/L
106.3
Standard number 3 aoolied. tlOO.Ol.
Correlation coefficient: 0.99841
Time: 10:33
Peak Heioht (A): 0.10O
Background Pk Height (A): O.O4S
SD: 0.37
Slope: O.O017
RSD(7.): O.35
Mi
TD: 20O PPB MI
Sea. No.: OOO06
A/S Pos,: 4
Date: 10/19,
Reolicate 1
Peak Area fA-s): O.35O
Backaround Pk Area (A-s): 0.171
Blank Corrected Pk Area (A-s): 0.332
Concentration (ua/L ): 195.0
"<=olicste 2
Peak Area (A-s): O.366
Background Pk Area (A-s): O.133
Blank Corrected Pk Area (A-s): 0.348
Concentration (ua/L ): 204.6
Cone (ua/L ):
199.8
Time: 10:41
Peak Height (A): O.171
Background Pk Height (A): O.O66
Time: 1O:44
Peak Height (A): 0.176
Background Pk Heiaht (A): O.054
SD: 6.78
RSD 17.) i 3 .39
Standard number 4 aoolied. T2O0.01
Correlation coefficient: O.99972
Slope: O.0017
-------
Calibration - CAftOTR
to. *4,
-,. .
; 9.0017
0.0
Canednrrataon
1:00.0
Mi
ID: ICV
Concentration (ug/L ): 106.1
dedicate 2
loncentration (up/L ) : 109.8
Cone (ua/L )j
Sea. No.: 00007 A/S Pos.: 5 Dates 10/19/
Time: 10:51
Time: 10:54
1O8.0
SD: 2.62
RSD(X): 2.42
3C samole is within ranae 7V.5 - 120.49
Mi
ID: 1CB
oncentration (uo/L ): 3.6
=?ol i cate 2
oncentration (uo/L ): 2.6
Sea. No.: OOOOB A/S Pos.: O Date:
Time: 1O:5B
Time: 11:O1
Mean Cone
-------
< 1= r> i i c a t e 2
Concentration i'ua/L '?
;uo.-'L 3 ; -2,4
Concentration [ua/L 'J : —2.7
lean Cone (ua/L 1: —2.5
00011 A/S Pos.: 16 Date: 10/19
Time: 11:17
Time: 11:20
SD: 0.24
RSD ('/.): 9.34
'ii ID: 81O03.UB
loncBntration (up/L ): -1.1
^^olics+e 2
Concentration :
Sea. No.: 00013 A/S PDS.: 18 Date: 10/19
Time: 11230
T ime: 11:33
'•lean Cone (ua/L ):
20.9
3D: 5.61
RSDC/.): 26.7
Mi TD: 81001.IS
Sea, No.: OOO14 A/S Pos,: 18 Date: 10/19
Time: 11:37
Ioncentration (ua/L ): —1.2 '
Concentration (ua/L ): —4.6
Cone (ua/L ): -2.9
Time: 11:40
SD: 2.36
RSDC/.): BO.9!
Mi TD; S10O3.01
Realicate 1
Concentration (ua/L ): -11.0
"3 a r, | j r ^j -t- = ~'
Concentration luo/L ): -16.5
Sea. No.: OOO15 A/S Pos.: 19 Date: 1O/19,
Times 11:43
Time: 11:47
Mean Cone (ua/L ):
-13.7
SD: 3.91
RSD (V.)z 28.4:
-------
Mi TD: 81O03.01 Sea. Mo,
^eolicate 1
Zoncentration (ug/L ): 85.3
Concentration fua/L j: 86.8
"lean Cone tuo/L ): 86,0
Recovery is 99.87.
00016 A/S Pos.: 19 Date: 10/19
Time: 11;5O
Time: 11:53
SD: 1.11
RSD (7.) ; 1.28
Tt): 81O03.02
icate 1
Concentration (uo/L J: 13.1
Sea. No,
.OO017 A/S Pas.: 2O Date: 1O/19
Time; 11:56
Time: I2:OO
oncentration (uo/L ): 5.3
Cone fua/L ): 9.2
SD: 5.50
RSD (7.)! 59.8
TT): 81O03.03
i cate 1
Concentration fua/L ): -7.2
?=nT i. cat= 2
Concentration : 86.4
^ean Cone (uo/L ): 87.4 SD: 1.36
3C samole is within ranae 79.5 - 12O.49
Date: 10/19,
: 1.56
Mi TD: CCB
Sea. No.:
icate 1
"oncentration iua/L >
"oncentrat ion (uo/L )
lean Cone f'ua/L ):
-13.5
-12.1
-12.8
OO020 A/S Pos.: 0
Time: 12:16
Time: 12:19
SD: 0.96
Date: 10/19;
RSD ( 7.) : 7 . 52
-------
Mi TH: TCB Sea. No.: OOO26 A/S Pos.: 0 Date: 1O/1<
Reelicate i Time: 13:09
Concentration (ug/L ): —1.9
F> = niic5te 2 Time: 13:12
Concentration fuo/L }: -0.1
Mean Cone (ua/L ): -1.0 SD: 1.33 RSDC/.): 131,
3C sample is within range -15.49 - 15.49
Mi ID: 81003.Ul Sen. Mo.: OOO27 A/S Pos.: 22 Date: 10/1£
iii ate 1 Time: 13:15
Concentration t'ua/L ): 5.1
^°n]ic3ts 2 Time: 13:18
Concentration (ua/L ): 4,7
Mean Cone iuo,'L 1: 4.9 SD: 0.30 RSDC/.)! 6.IT
Mi TO: 81003.U2 Sea. No.: 00029 A/S Pos.: 23 Date: 10/1<]
Dedicate 1 Time: 13:22
Concentration (uq/L )': 2.1
3 = u11 cats 2 Time: 13:25
Concentration Cuq/L ): 0.6
Mean Cone (uo/L ): 1.3 SD: 1.02 RSDC/.): 76.7
'H TD: 91O03.LI3 Sen. No.: OOO29 A/S Pos. : 24 Date:
icate i T*ime: 13:28
Concentration (ua/L ): 0.5
•Sap.i •; csts "" Time: 13:31
Concentration (uo./L ): •—O . 9
"lean Cone (ua/L V: -0.2 SD: 0.95 RSDC/.): 518.
v-li TF?: 81.003.11 See. No.: 00030 A/S Pas.: 25 Date: 10/19
icate 1 . Time: 13:34
Concentration } icats 2 Time: 13:3B
Concentration (ua/L ): 168.5
V1ean Cone (uo/L >; 173.9 SD: 7.69 RSDC/.): 4.42
-------
\H
ID: 81OO3.I2
i cate 1
Concentration (ua/L ): 178.5
Seo. No.: 00031 A/S Pos.: 26 Date: 10/19
Time: 13:41
Concentration t'ua/L ): 167.4
lean Cone (ua/L ): 172.9
Time: 13:44
BD: 7.88
RSD(7.): 4.56
Mi ID; 91003. T3
Reolicate 1
Concentration (ua/L ): 122.9
~<=ol i cats 2
Concentration Cua/L ): 122.4
^^A*A*^^A^A*^^^^^^^^^^^^^A*^^^^~^^^'^*W'\**V'\*'\*'\*'\*'V*W*V*^*W^*V*V*V'
Sea. No.: OOO32 A/S Pos.: 27 Date: 10/19
Time: 13:47
Time: 13:50
lean Cone Cuo/L >:
122,7
SD: 0.36
RSD ('/.): 0.30
Mi
TD: CCV
Icate 1
Zoncentration (ua/L ): 89.2
Sea. No.: OOO33 A/S Pos.
Time: 13:53
Time: 13:57
Concentration (ua/L ): 90.1
"lean Cone (ua/L ): • 89.7 SD: 0.7O
~3C sample is within ranoe 79.5 - 120.49
Date: 1O/19
RSD ('/.): 0. 78
Mf TD: CCB
Reolicate i
Concentration abs. is areater than that o"f the largest standard.
Reolicate 2 Time: 14:09
Concentration (ua/L ): 391.2
-------
3MA 400 Analysis Ver. 4.10 Thu 10/22/99 - 13:23:27
hod File Name: P
arks:
Wt file is 10236
P214 EM
P2 1 4 EM
P214 EM
P214 AV
P214 EM
P214 EM
I
FAIMDARD 4*2
P214 EM
P214 AV
FANDARO 4*3
P214 EM
FAIMDARD 4*3
P214 EM
P214 EM
P214 AV
FANDPhRD 4*«4-
P214 EM
F*=fclNlE>ARE> 4*-*
P214 EM
FANDARD 4*-*
P214 EM
P214 AV
P214 EM
Replicates:3
368
369
370
369.0 SD 1.0
550
563
562
558.3 SD 7.2
73B
816
838
817.3 SD 2O. O
REF>I_ I GATE
1550
1570
1581
1567.0 SD 15.7
REF^L I CATE
323
Read Delay: 65
Data File:
4*1 1327 10/22/98
peak-noisy
4*2
peak-noisy
4*3
peak-noisy
CV O.3 CONC 0.2OOO
4*1 1329 10/22/98
4*2
4*3
CV 1.3 CDNC l.OOOO
4* 1 1331 1O/22/98
4*2
4*3
CV 2.5 CONC 2.OOOO
4*1 1333 10/22/98
4*2
4*3
CV l.O CONC 5.OOOO
4* 1 1335 10/22/98
P214
EM
4*2
31
-------
P214
P214 EM
P214 AV
P214 CC
EM 787
312
315.7 SD
1.0000 SLOPE
P214 EM
P214
P214
002-B—±
P214 EM
LOO2 _ B—±
P214 EM
-B—3.
P214 EM
P214
P214
-1
P214
__ *fl
P214
P214
1
P214
P214
EM
EM
EM
P214
P214
EM
EM
ICl=fcT
1.8858 mq/L
£.4 CV 2.O CONC 0.0000
25O.2997 INT 314.9751
4* ± 1337 1O/22/9S
P214
S
P214
3
P214
3
P214
EM
EM
P214
P214
EM
EM
851
816
AV
AV
318
316
2.1415 mg/L
2.0017 mg/L
818.0 EM SD 32.0 CV
2.OO97 mg/L SD O.1280 CV
3.9
6.37
0.0121 mg/L
REF-L I Crf=»TI
0.0041 mg/L
327 0.0480 mg/L
AV 32O.3 EM SD
AV O.0214 mg/L SD
REF>1_I
478 0.6513 mg/L
RTEF>L_r
498 0.7312 mg/L
4*± 1339 10/22/98
peak-noisy
4*2
peak-noisy
peak-noisy
494 0.7152 mg/L
AV 49O.O EM SD
AV 0.6993 mg/L SD
5019
5017
REF>L_ I GATE
18.7936 mg/L
5.9 CV
0.0234 CV
4*±
4*2
4*3
10.6 CV
O.O423 CV
4*1
1.8
1O9.35
1341 1O/22/98
2.2
6.05
1343 10/22/9B
5349
AV 5128.3 EM
AV 19.2304 mg/L
426&
4548
18.7S56 mg/L
RER-L. T CftTI
20.1120 mg/L
SD
SD
15.7852 mg/L
REF»I_ I Crf=fcTI
16.9118 mg/L
4*3
191.1 CV
0.7635 CV
4*1
4*2
3.7
3.97
1345 10/22/98
-------
ID
P214
ID
P214
P214
» — JL
P214
1 „_ ••
P214
P214
P214
>—IS
P214
»—IS
P214
P214
P214
P214
P214
P2 1 4
P214
P214
EM
EM
EM
P214
P214
EM
EM
EM
P214
P214
EM
EM
EM
P214
P214
EM
EM
EM
P214
P214
EM
EM
AV 4368.7 EM SD
AV 16.1953 mg/L SD
4297
4272 15.8091 mg/L
F*EF>1_I
16.304& mg/L
REF>I_ i
15.9090 mg/L .
SD
SD
18.2982 mg/L
REF"I_I
18.1344 mg/L
4396
AV 4321.7 EM
AV 16.0076 mg/L
4895
4854
4920 18.3980 mg/L
AV 4889.7 EM SD
AV 18.2769 mg/L SD
52B7
5298 19.9082 mg/L
155.9 CV
O.6227 CV
E 4*1
4*2
4*3
65.6 CV
O.2620 CV
4*1
4*2
4*3
33.3 CV
0.1331 CV
4*1
19.8S43 mg/L
I CPfcTE 4*3
19.9722 mg/L
5314
AV 5299.7 EM SD
AV 19.9149 mg/L SD
13.6 CV
O.O542 CV
336
330
REF*!— I CftT
O.OB4O mg/L
3.6
3.84
1347 1O/22/98
1.5
1.64
1349 1O/22/9S
0.7
0.73
1351 10/22/98
O.3
O.27
4* 1 1353 10/22/98
peak-noisy
REF»I_ I GATE 4*3
O.060O mg/L peak-noisy
4*3
peak-noisy
I C*=*T
O.OSOO mg/L
330
AV 332.0 EM SD
AV 0.068O mg/L SD
3.5 CV
0.013B CV
1,O
20.35
RE^L-ICftTE 4*1 1355 10/22/98
343 0.1120 mg/L peak-noisy
333
REf=>l_ I
0.0720 mg/L
4*S
4*3
-------
P214
P214
-2ft
P214
JHT
P214
JT
P214
4T
P214
P214
P214
AV
AV
O
340.3
.1013
EM
mg/L
SD
SD
O
6.4
.0257
CV
CV
25
1
•
.9
35
EM
EM
EM
P214
P214
EM
EM
EM
P214
P214
343
343
RER-L I CftHT
O.112O mg/L
ICftTl
0.1120 mg/L
REF=-|_ I CftTI
0.0960 mg/L
339
AV 341.7 EM SD
AV O.I066 mg/L SD
4*± 1357 1O/22/98
peak-noisy
4*2
4*3
peak-noisy
2.3 CV 0.7
O.OO92 CV 8.65
REF^LIOftTE 4*± 1359 10/22/98
323 O.O321 mg/L window-edge
peak-noisy
0.0520 mg/L
328
311 -O.O159 mg/L
AV 320.7 EM SD
AV 0.0227 mg/L SD
peak-noisy
8.7 CV 2.7
O.O349 CV 153.51
#±
1401 10/22/98
1.9538 mg/L
1.8978 mg/L
P214 EM 804
P214 EM 790
^ I
P214 EM 803 1.9498 mg/L
P214 AV 799.0 EM SD
P214 AV 1.9338 mg/L SD
=1*3
7.8 CV
O.O312 CV
1.0
1.61
P214
P214
P214
O—
P214
EM
EM
EM
P214
P214
EM
REF"I_ I Crf=kT
0.0600 mg/L
0.0201 mg/L
330
320
369 0.2158 mg/L
AV 339.7 EM SD
AV O.O986 mg/L SD
324
REF>L I
0.0361 mg/L
± 1403 10/22/98
window-edge
peak— noisy
25.9 CV 7.6
0.1034 CV 104.86
14O5 1O/22/98
O—
4*2
i,_ ,-„ „ 1 . „
-------
P214
P214 EM
P214
P214
EM
EM
EM
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
EM
P214
EM
EM
P214
P214
EM
EM
EM
P214
P214
EM
RE:F>-|_ I CftTE 4*3
peak-noisy
323 0.0321 mg/L
AV 326.0 EM SD
AV O.O440 mg/L SD
693
718
735 1.6781 mg/L
AV 717.0 EM SD
AV 1.6062 mg/L SD
4.4 CV
0.0174 CV
4*1
1.3
39.54
14O7 1O/22/98
1.5303 mg/L
FSEIR-L- r C<=*TE: 4*s
1.6102 mg/L
18.5 CV
O.0740 CV
6135
602S
REF>l_IC<=fcTE: 4* A
23.2522 rog/L
2.6
4.61
1409 1O/22/98
22.8127 mg/L
H— *=n=- REF-L. i O^TE: 4*
P214 EM 6138 23.2642 mg/L
P214 AV 6099.3 EM SD 64.4
P214 AV 23.1097 mg/L SD O.2573
j— r=- REI=>I_ i C*=»TE: 4*
P214 EM 315 0.0001 mg/L
3
CV 1.1
CV 1.11
1 1411
peak-noisy
344
0.1160 mg/L
REII^L. r
-0=0478 mg/L
peak-noisy
4*2
303
AV 32O.7 EM SD
AV O.O227 mg/L SD
21.1 CV
0.0842 CV
6.6
370.36
REF-LIC^TE: «=x 1413 10/22/93
313 -0.0079 mg/L window-edge
333
0.0720 mg/L
window-edge
313
AV
AV
-0.0079 mg/L
319.7 EM SD
O.O187 mg/L SD
peak-noisy
11.5 CV 3.6
O.O461 CV 246.12
RER-L. i GATE: «=i 1415 10/22/93
304 -0.0433 mg/L peak-noisy
-------
my t w
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
EM
P214
P214
EM
EM
EM
P214
P214
EM
EM
P214 EM
P214
P214
P214
EM
EM
EM
P214
P214
EM
EM
EM
P214
P214
EM
0.0281 mg/L
308 -0.0279 mg/L
AV 308.7 EM SD
AV -O.O252 mg/L SD
REF>I_
313 -0.0079 mg/L
322
316 0.0041 mg/L
AV 317.0 EH SD
AV O.OOS1 mg/L SD
822
REF*1_ I C«=fc~TI
833 2.0696 mg/L
peak-noisy
5.O CV 1.6
O.O2O1 CV 79.79
1 1417 1O/22/98
window-edge
peak-noisy
peak-noisy
4.6 CV
0.0183 CV
4*±
1.4
226.31
1419 10/22/98
2.0257 mg/L
RE
2.0337 mg/L
SD
SD
0.1200 mg/L
-0.0478 mg/L
824
AV 826.3 EM
AV 2.0430 mg/L
345
303
I
343 0.1120 mg/L
AV 330.3 EM SD
AV O.O614 mg/L SD
300
311
5.9 CV
0.0234 CV
E 4*1.
0.7
1.15
1421 1O/22/98
=1*3
peak-noisy
23.7 CV
O.0947 CV
7.2
154.27
318
-0.05-38 mg/L
REF"1_
-0.0159 mg/L
F!EF>1_ I
0.0121 mg/L
4*± 1423 1O/22/9S
peak-noisy
peak-noisy
AV
309.7 EM
AV -O.O212 mg/L
322
peak-noisy
SD 9.1 CV 2.9
SD 0.0363 CV 170.93
R£EF>1_ I
O.0281 mg/L
J. 1425 10/22/98
peak-noisy
-------
P214 EM
P214
P214
P214
P214
P214
P214
SS
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
EM
EM
EM
P214
P214
EM
EM
EM
P214
P214
EM
EM
EM
P214
P214
EM
EM
EM
P214
P214
EM
EM
320 0.0201 mg/L
AV 317.O EM SD
AV O.O081 mg/L SD
4*3
peak-noisy
7.O CV
0.0280 CV
2.2
345.70
345
-0.0399 mg/L
REPLI
0.1200 mg/L
41=1 1427 10/22/98
peak-noisy
peak-noisy
FSE:F>I_ i GATE: 4*3
-0.0478 mg/L peak-noisy
303
AV 317.7 EM SD
AV O.O1O8 mg/L SD
REF>I_ I C*=fcT
1.6741 mg/L
23.7 CV
O.O947 CV
4*1
7.5
88O.25
1429 10/22/98
1.6541 mg/L
734
729
I
729 1.6541 mg/L
AV 73O.7 EM SD
AV 1.6608 mg/L SD
353
330
I
327 0.0480 mg/L
AV 336.7 EM SD
AV O.OB67 mg/L SD
2.9 CV
O.O115 CV
O.4
0.69
0.1519 mg/L
REF"!—!
0.0600 mg/L
4*1 1431 1O/22/98
peak-noisy
4*2
peak-noisy
319
323
peak-noisy
14.2 CV 4.2
0.0568 CV 65.58
I 4*1 1433 10/22/98
peak-noisy
E 4*2
322
AV 321.3 EM
AV O.O254 mg/L
331
334
REF>I_I
0.0161 mg/L
REF>I_I
0.0321 mg/L
FSEF^L. I C#VTE 4*3
O.O2B1 mg/L peak-noisy
SD 2.1 CV 0.6
SD 0.0083 CV 32.74
REF>1_ I
0.0640 mg/L
0.07&0 mg/L
4*1 1435 10/22/98
peak-noisy
peak-noisy
-------
P214 EM
P214
P214
332
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
EM
EM
EM
P214
P214
EM
EM
EM
P214
P214
EM
EM
EM
P214
P214
EM
EM
EM
P214
P214
EM
EM
AV
AV
O.068O mg/L
332.3 EM BD
O.0693 mg/L SD
438
404
peak-noisy
1.5 CV O.5
O.0061 CV 8.SO
i GATE 4* i 1437 10/22/99
O.4915 mg/L peak-noisy
401
0.3557 mg/L
RSEF»l_ICATE 4*3
0.3437 mg/L peak-noisy
AV
AV
414.3 EM
0.397O mg/L
SD 20.6 CV
SD O.O821 CV
432
435
0.4675 mg/L
I CPfcTI
0.4795 rag/L
#2
413
0.39 IS mg/L
426.7 EM SD
O.4462 mg/L SD
0.4316 mg/L
AV
AV
423
433
409 0.37565:mg/L
AV 421.7 EM SD
AV O.4263 mg/L SD
11.9 CV
O.O477 CV
0.4715 mg/L
834
824
818
RE:F>I_ i
2.0736 mg/L
FSEF*I_ i
2.0337 mg/L
12.1 CV
O.O482 CV
4*1
.0097 mg/L
AV 825.3 EM
AV 2.O39O mg/L
296
297
SD
SD
E 4*3
8.1 CV
O.O323 CV
I GATE
-0.0758 mg/L
REF"I_ I GATE
-0.0718 mg/L
4* ±
5.O
2O.68
1439 10/22/98
2.8
10.68
1441 10/22/98
2.9
11.30
1443 10/22/98
l.O
1.58
1445 10/22/98
window—edge
4*2
peak-noisy
-------
P214
P214
LOO& . 1
P214 EM
LOO& _ 1
P214 EM
L OO& _ 1
P214 EM
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
P214
EM
EM
P214 EM
P214
P214
EM
EM
EM
P214
P214
EM
EM
P214 EM
P214
P214
EM
EM
0.8111 mg/L
0.9110 mg/L
0.8511 mg/L
AV 3O1.O EM SD
AV -0.0558 mg/L SD
REIR-LI
521 0.8231 mg/L
I
518
I
518 0.8111 mg/L
AV 519.O EM SD
AV 0.8151 mg/L SD
I
543
I
528
I
519 0.8151 mg/L
AV 530.0 EM SD
AV O.8591 mg/L SD
514
526
I
578 1.05O8 mg/L
AV 539.3 EM SD
AV 0.8964 mg/L SD
499
I
506 O.7632 mg/L
REF*I_I
525 0.8391 mg/L
AV 51O.O EM SD
AV 0.7792 mg/L SD
I
914
I
918 2.4092 mg/L
I
0.7951 mg/L
0.8431 mg/L
0=7352 mg/L
2.3932 mg/L
7.8 CV
0.0312 CV
4*1
4*2
4*3
1.7 CV
0.0069 CV
2.6
55.89
1447 10/22/98
0.3
O.85
4*1 1449 10/22/98
peak-noisy
4*2
4*3
12.1 CV
0.0484 CV
=: 4*1
E: 4*2
34.0 CV
0.1359 CV
4*2
13.5 CV
O.0538 CV
4* 1
4*2
4*3
2.3
5.64
1451 10/22/98
6.3
15.16
1453 10/22/98
2.6
6.90
1455 10/22/98
-------
P214
P214
P214
P214
P214
EM
P214
P214
P214
P214
P214
P214
P214
P214
P214
AV
AV
914.3 EM
2.3946 ing/L
SD
SD
3.5 CV
O.0140 CV
E 4*1
O.4
O.59
1457 1O/22/9B
821
2.0217 mg/L
P214
P214
F=-L
P214
P214
P214
EM
EM
AV BOS. 7 EM SD
AV 1.9604 mg/L SD
REFL_ICrf=V
301 -0.0558 mg/L
REFI_ICrf=V
293 -0.0878 mg/L
15.0 CV 1.9
O.O&OO CV 3.06
TE 4*1 1459 10/22/98
window-edge
TE 4*2
peak-noisy
REFI_ICrf=fcTE 4*3
EM
P214
P214
: 4*4*3
EM
: 4*4-3
EiC
: 4$»4^3
EM
P214
P214
--v*__ ,.
^^*- *^~^
EM
4*44
EM
4*44
EM
P214
P214
: 4*4-5
EM
: 4*45
EM
: 4*45
EM
319 0.0161 mg/L
AV 3O4.3 EM SD
AV -O.O425 mg/L SD
flj8/"A^ REFI_ I C#V
2^8 -0. 1078 mg/L
REFl_IC
-------
Element File: SE.GEL
Date: 10/16/98
Data File:
Technique: HGA
Element: SB
Time: 12:42
ID/Wt File: 81002.IDW
Calin. Type: Linear
Wavelength: 196
Slit: 2.OO L
Lamo Current: 0
Energy: 38
ID: O PPB
Sea. No.: OO237
A/S Pos,
Replicate 1
= eak Area fA-s): O.OO6
Backaround Pk Area (A-s): 0.183
Blank Corrected Pk Area (A-s): 0.010
Concentration (ug/L ): 5.34
Rep.1 i cats "2
Peak Area (A-s): O.O11
Background Pk Area (A-s): O.192
Blank Corrected Pk Area (A-s): O.O15
Concentration (ua/L ): 8.28
Time: 12:42
Peak Height (A): O.Q37
Background Pk Height
-------
Mean Cone (ua/L ):
28.36
SD: 0.950
RSD(7.): 3.35
Standard number 2 applied. C25.0O1
Correlation coefficient: O.99443
Slooe: O.OO19
TD: 50 PPB
Sea. No.: 00240
A/5 Pos.: 3
Date: 1Q/16
Reolicate 1
Peak Area (A-s): 0.1O6
Backoround Pk Area (A-s); 0.174
Blank Corrected Pk Area (A-s): 0.097
Concentration (uq/L ): 5O.42
Time: 13:02
Peak Height (A): 0.169
Backaround Pk Height (A): O.091
i?>=ol icste 2
Peak Area ol i cate 2
Peak Area (A~s): 0.216
Background Pk Area (A-s): 0.191
Blank Corrected Pk Area (A-s): 0.208
Concentration (ug/L ): 107.39
Time: 13:09
Peak Heiaht (A): 0.297
Backaround Pk Height (A): 0.109
Time: 13:12
Peak Heiaht (A): 0.341
Background Pk Height (A): O.119
Mean Cone (ua/L
106.43
SD: 1.354
RSDC/.): 1.27
Standard number 4 applied. T100.00"]
Correlation coefficient: 0.998B8
Slope: 0.0020
-------
Calibration - C:\lfi ll
o.ai.
0-0
concentration
130". DO
Se
IDs ICV
Reolicate 1
Concentration iua/L ): 49.40
Reolicate 2
Concentration (uo/L 1: 51.48
Sea. No.: 00242 A/5 Pos,
Time: 13:23
Time: 13:26
Mean Cone (uq/L 1: 50.44
QC samole is within ranae
'SD: 1.466
Date: 10/1
RSD ('/.)» 2.9
le ID: ICB Sea. No.:
Replicate 1
Concentration (ua/L ): —5.35
Concentration (ua/L ): -3.31
Mean Cone fua/L }• -4.33
QC sample is within ranne
00243 A/S Pos,
Times 13:29
Time: 13:33
SD: 1.438
: O
Date: 10/1,
RSD (7.) : 33.:
oerfarmed=
If* TD: 61002.B-l
Reeli cate 1
Concentration (uo/L ): —1.13
Ron!icate 2
Concentration t'ua/L ): 1.78
Mean Cone i'uQ/L ): 0 = ^
Sea. No.: OO244 A/S Pos.
Time: 13:37
Time: 13:41
SD: 2.05B
Date: 10/H
RSDT/.): 633,
TD: 81OO2.8-1
Sea. No.: 00245
A/S Pos.: 7
Date: 10/1<<
-------
Rc=n] icats 2
Concentration
-------
P(=?nlicat.e 2
Concentration (ua/L ): O.95
Mean Cone »'uQ/L is 1.52
QC sample is within ranae
Time: 14:55
SD: .0.796
RSD Cxi): 52
Re ID; B1O03.RB-AP
Reolicate 1
Concentration (uq/L ): -2.62
Sea. No.: 00256 A/S FOB.: 14
Time: 14:58
Concentration (ua/L ): 0.55
Mean Cone (ua/L ): -1.O3
Time: 15;O2
SD: 2.240
Date: 1O/K
RSD (V.\ 5 216.
•=(? TD: 81Q03.RB-F
Reolieate 1
Concentration (ua/L )j 1.34
Sea, No.: O0257 A/S Pos.: 15 Date: 10/li
Time: 15:05
Concentration (ua/L 'i : -0.56
Mean Cone iua/L s: 0.3'
Time; 15: OB
RSDfV.U 3^1,
15:11
16 Dates 10/1£
-• ';.'»t i, on (ua/L
Cone
: 1.17
2.37
Time: 15:15
SD: 1.686
RSDC/.1 : 71 .2
TD: 830O3.UB
Concentration (ua/L >: -0»35
p=>r, ] i c a t «3 2
Concentration iua/L ): -0.06
Sea. No.: 00259 A/S Pos.: 17
Time: 15:18
Timet 15:21
Mean Cone (ua/L
-0.21
SD: 0.209
Date: 1O/16
RSD ('/.)! 100.
Re ID: 81O03.IB
Reolicate 1
Concentration (uo/L ): 1.07
Rf=>n1 icate 2
Concentration (ua/L
Sea. No.: O026O A/S Pos.: IB Date: 10/16
Time: 15:24
Time; 15:28
1.02
-------
Mean Cone (uq/L )s • O.O2 SD: 1.477 . RSDC/.): 6404
Se ID: S1003.D1 Sea. No.: 00261 A/S Pos.: 19 Date: 10/16
Reolicate 1 Time: 15:31
Concentration (ua/L ); —1.69
2 Time: 15:34
Concentration (ua/L >: 2.89
Mean Cone I'ua/L 1: O.60 3D: 3.236 RSDC/.): 5-41.,
fie ID: 81003.01 Sea. No.: OO262 A/S Pos.: 19 Date: 10/16
Reolicate 1 Time: 15:30
Concentration (ua/L 5: .47.19
^s=o1icate 2 . Time: 15:41
Concentration fua/L ): 56. CO
Mean Cone (ua/L >: 51.60 SD: 6.23O RSDC/.): 12.01
Recoverv is 102.O'/.
fi» TD: 81003.02 Sea. No.: OO263 A/5 Pos.: 20 Date: 10/16
Reolicate 1 Time: 15:44
Concentration (ua/L ): 2.42
Ronl . icate 2 Time: 15:48
Concentration fuq/L ): 7.09
Mean Cone (uo/L ): 4.75 SDi 3.303 RSDC/.): 69.4"
-o^/V^^'V*Vn^'V^^*'V^'VlV^'^^'vnjnrf'V'^'V^'^^'V'V'V'V'^^'^^'\r'V'V'^^'V'V'V'V'V*V'V
^e ID: 81003.O3 Seo . No.: OO264 A/S Pos.: 21 Date: 10/16,
Reolicate 1 Time: 15:51
Concentration (uq/L ): -1.81
R«?ol icats 2 Time: 15:54
Concentration (ua/L ): 3.03
Mean Cone
-------
3C samole is within ranoe
ID: CCB
icate i
Concentration (ug/L ): -1„58
^OD1icate 2
Concentration (ua/L ): 1.02
Sea. No.: OO266 A/S.Pas,
Time: 16:O4
Time: 16:O8
: 0 Date: 10/1<
Mean Cone (ua/L ): -0.2B
3C samnle is within ranae
SD: 1.839
R5DC/.): 66O
~e ID: B10O3.U1 Sea. No.
Reolicate 1
Concentration (ua/L ): 19.79
Concentration (ua/L ): 25.53
Mean Cone (ua/L ): 22.66
00267 A/S FOB
Time: 16:11
Time: 16:14
5D: 4.064
22 Date:
RSDC/.): 17.
SF? ID: B.1.003.U2 Sea. No.
Real icate 1
Concentration (ua/L ): 20.92
i cat e 7
Concentration (uq/L 1 : 18.30
Mean Cone v'ua/L ):
19.61
O0268 A/S Pos,
Time: 16:1B
Time: 16:21
SD: 1.854
23 Date:
RSDC/.): 9.4!
G.* ID- 850O3.U3 Sea. No.:
Reolicate 1
Concentration (ua/L ): 13.20
R(=>nl icats 2
Concentration (uo/L ): 7.45
Mean Cone (ua/L ):
10.3:
00269 A/S Pos,
Time: 16:24
Time: 16:2B
SD: 4.067
24 Date: 10/16
RSDC/.] : 39.4
Re ID: S1OO3.I1
Sea. No.: 00270 A/5 Pos.: 25 Date
Samole abs. is oreater than that of the laraest standard.
Reolicats 1 Time: 16:31
Concentration (ua/L ): 129.36
Sample aba. is greater than that of the laraest standard.
Reolicate 2 Time: 16:35
Concentration (ua/L ): 122.13
-------
Samole abs; is greater than that o-f the largest standard.
Mean Cone (ua/L ): 125.74 SD: 5,114
RSD C/.); 4.07
ID: 81O03.I2
Sen. No.: OO271
A/S Pos.: 26
Sample abs. is greater than that of the largest standard.
Reolicate 1 Time: 16:38
Concentration (ug/L ): 195.59
^amole sbs. is greater than that of the largest standard.
Reolicate 2' Time: 16:42
Concentration (ua/L ): 193.25
Samole abs. is greater than that of the largest standard.
Mean Cone (ua/L ): 194.42 SD: I.65O
Date: 10/16
RSD(7.): 0.05
ID: 81003.13
Sea. No.: OO272 A/S Pos.s 27
Samole abs. is greater than that of the largest standard.
Realicate 1 Time: 16:45
Concentration (ua/L 1: 175.49
abs. is areater than that of the largest standard.
Reolicate 2 Time: 16:48
Concentration (ua/L Is 182.48
Samole abs. is greater than that of the largest standard.
Mean Cone (ua/L ): 178.99 SD : 4.945
Date: 1O/16
RSD C/.): 2.76
^e ID: CCV
Reolicate 1
Concentration (ua/L ): 54.81
Sea. No.: 00273 A/S Pos.
Time: 16:52
Time; 16:55
Concentration (ua/L ): 53.45
Mean Cone fua/L
OC samole is within ranae
54.13
SD: 0.965
Date: 10/16
RSD (•/.).- 1. 78
Sf? ID: CCB
Reolicate 1
Concentration (ua/L ): 7.29
Sea. No.:
icats 2
Concentration (uo/L ): 5.46
Mean Cone (ua/L }: 6.37
QC samole is within ranae
OO274 A/S Pos
Time: 16:59
Time: 17:02
SD: 1.293"
Date: 10/16,
RSD C/.): 20.3
-------
t File: SE.GEL
)ate: 10/19/98
}ata FiIB:
rechnioue: HGA
Element: Se
Time: 15:35
ID/Wt File: 81O02.IDW
Calib. Type: Linear
Wavelength: 196,
Slit: 2.00 L
Lamp Current: O
Energy: 36
ID: 0-PPB
Sea. No.: OOO44
=eak Area (A-s): -0.003
Sackaround Pk Area (A-s): 0.159
31ank Corrected Pk Area (A-s): -O.O02
Concentration (ua/L ): -1.22
^enl icate 2
=eak Area (A-s): O.OO8
Backaround Pk Area (A-s): 0.134
Blank Corrected Pk Area (A-s): O.OO8
Concentration (ua/L ): 4.03
lean Cone (ua/L ):
^uto-zero performed,,
1.4O
A/S Pos,: O
Date: 1O/17
Time: 15:35
Peak Height (A): 0.030
Background Pk Height (A): 0.082
Time: 15:38
Peak Heiaht (A): 0.02B
Background Pk Height (A): 0.072
SD: 3.716
RSD C/.)! 264.
TO: IO PPB
Sea. No.: 00045
A/S Pos,: 1
^eol i cats 1
^eak Area (A-s): 0.010
Background Pk Area (A-s): 0.14S
Blank Corrected Pk Area (A-s): O.OO7
loncentration (ug/L ): 3.6O
icate 2
=eak. Area (A-s): O.O12
Backaround Pk Area ( A-5 ) : 0.132 /
Blank Corrected Pk Area (A-s): O.OO91;
Concentration (ua/L ): 4,55
Time: 15:42
Peak Height (A): 0.040
Background Pk Height (A)
Time: 15:45
Peak Height (A)s 0.047
Backaround Pk Heiaht (A)
Date: 10/19,
O.O9O
O.074
Mean Cone (ua/L ): 4.OB SD: 0.671
Exoansion >100 is not allowed. No calibration has occurred.
ID: 25 PPB
Sea. No.: O0046
A/S Pos.: 2
RSD C/.): 16.41
Date: 10/19/
Reoli cate 1
Peak Area (A-s): 0.036
Background Pk Area (A-s): 0.133
Blank Corrected Pk Area (A-s): 0.034
!?eol icate 2.
Peak Area (A-s): 0.O48
Backoround Pk Area (A-s): 0.116
Blank Corrected Pk Area (A-s): 0.046
Time: 15:48
Peak Height (A): O.OBO
Background Pk Height (A): 0.07B
Time: 15:52
Peak Height (A); O.O76
Backaround Pk Heiaht (A): 0,065
Mean Pk Area (A-s):
O.040
SD: 0.0086
RSD (7.): 21.63
-------
»e
ID: 25 PPB
Sea. No.: O0047
ieol icate 1
feak Area (A-s): O.050
iackaround Pk Area (A-s): O.116
!lank Corrected Pk Area (A-s): 0.048
A/S Pos.: 2
Date: 10/19/
Time: 15:55
Peak Heiaht (A): O.OB2
Backaround Pk Heiaht (A): 0.058
Iharacteristic Mass = 22.9 pg/O.0044 A-^i
;epl icate 2
!eak Area (A-s): 0.046
Jackoround Pk Area (A-s): O.115
31ank Corrected Pk Area (A-s): O.O44
lean Pk Area (A-s):
0.046
Standard number 2 applied. f.25.001
Correlation coefiicient: l.OOOOO
Time: 15:59
Peak Heiqht (A): 0.087
Backaround Pk Heiaht (A): O.052
SD: 0.0031
Slope: O.O01B
RSD ('/.): 6.80
ID: 50 PPB
Sea. No.; OO048
teolicate 1
3eak Area (A-s): 0.089
Jackqround Pk Area (A-s): O.124
Blank Corrected Pk Area (A-s): 0,086
Concentration (ua/L ): 47.04
Area (A-s): 0.089
Jackaround Pk Area (A-s): 0.117
31ank Corrected Pk Area (A-s): 0.086
Concentration (ua/L ): 47.28
•lean Cone (ua/L );
47.16
Standard number 3 applied. [5O.OO]
Correlation coefficient: O.99717
A/5 Pos.: 3
Date: 10/19/
Time: 16:02
Peak Height (A): O.158
Background Pk Height (A): 0.059
Time: 16;O5
Peak Height (A): 0.156
Backaround Pk Heiaht (A): 0.056
SD: 0.165
Slope: 0.0017
RSD ('/.): 0.35
ID: 100 PPB
Sea. No.: 00049
A/S Pos.: 4
Date: 10/19/
aeak Area (A-s): 0.182
Background Pk Area (A-s): 0.133
Blank Corrected Pk Area (A-s): 0.180
Toncentration (ua/L ): 1O2.88
=eak Area (A-s): O.165
3ackground Pk Area (A-s): O.124
31ank Corrected Pk Area (A-s): 0.162
Concentration lua/L ): 92.84
"lean Con- tuq/L ): 97.86
Standard number 4 applied. T10O.OO1
Time: 16:09
Peak Height (A): 0.320
Background Pk Height (A): 0.086
Time: 16:12
Peak Heiaht (A): 0.295
Backaround Pk Heiaht (A): 0.082
SD: 7.101
RSD ('/.): 7.26
-------
Correlation coef -f icien t: 0.99950
Slooe: 0.0017
S= ID: LO FPB
Reclicate i
Ps=tV-. A.-e=i ( A- = '; : •
Sec. No.; 000^.0
ac or DL-.no
Date: 10-
k Heioht
-------
Concentration (uo/L ): -5.3S
Mean Cone (uo/L ): —6.
QC sample is within range
SDt 1.B15
RSD (7.) : 27.2
5p TO: 81003,11x5
Reolicate 1
Concentration (ug/L ): 18.77
Reolicate 2
Concentration (ua/L ): 24.12
Mean Cone (uo/L ): 21.44
Corrected Cone (uo/L ); 107.2
Sea. No.: OOO53 A/S Pos.: 25 Date: 1O/19
Time: 16:49
Corrected Cone (ug/L ): 93.8
Time: 16:52
Corrected Cone (ug/L ): 12O.6
SD: 3.784
RSD ('/.): 17.6
S=> ID: CCV
Reolicate 1
Concentration (ug/L ): 5O.46
Seo. No.: OOO54 A/S Pos.: 3
Time: 17:07
Concentration (ug/L ): 51.16
Mean Cone (ua/L ): 5O.B1
QC samole is within ranoe
Time: 17:11
SD: 0.497
Date: 1O/19
RSD ('/.): O.98
Se ID: CCB
Reolicate 1
Concentration (ug/L ): 2.52
] cate "2
Concentration (uo/L ): 1.67
Sea, No.: OOO55 A/S Pos.: 0
Time: 17:14
Time: 17:17
Mean Cone (ua/L ): 2.10
QC sample is within ranoe
SD: O.601
Date: 10/19
RSDC/.)s 28.6
R* TD: 91003.11x5
Reol icate 1
Concentration (uo/L
Rf?ol i cs t.e 2
Concentration t'uo/L 5: 27.64
Sea. No,: OOO56 A/S Pos.: 25 Date: 1O/19,
Time: 17:21
: 3O.O3 Corrected Cone (ug/L ): 150.2
Time: 17:24
Corrected Cone (ua/L ): 138.2
Mean Cone (ug/L ): 28.84
Corrected Cone (ua/L ): 144.2
SD: 1.68B
RSDC/.): 5.85
^
TD: 81003.12x5
Sea. No.: OOO57
A/S Pos.: 26
Date:
-------
Reolicate 1
Concentration (ua/L ): 44.82
Concentration (uo/L ): 39.44
Mean Cone (un/L ): 42. 1-"
Corrected Cone (ua/L ): 210,6
Time: 17:27
Corrected Cone (ug/L ): 224.1
Time: 17:31
Corrected Cone (ug/L
SD: 3.803
: 197.2
RSD(7.)s 9.O;
Se ID: 81003.13x5
Replicate 1
Concentration (uq/L ): 36.09
Ren 1i cate 2
Concentration (ua/L ): 4O.43
Sea. No.: OO058 A/S FOB.: 27 Date: 1O/1C
Time: 17:34
Corrected Cone (ug/L )s 1BO.4
Time: 17:38
Corrected Cone (ua/L ): 202.2
Mean Cone (uo/L ): 38.26
Corrected Cone (ua/L ): 191.3
SD: 3.073
RSDC/.):
f\,f^^f\,f^r\fr^^\ff\rl^
ID: CCV
Sea. No.: 00059 A/5 Fos.. : 3
icate L
Concentration tua/L ): 48.IB
Replicate 2
Concentration (ua/L ): 53.63
Mean Cone (uq/L ); 5O.9O
QC sample is within range
Time: 17:41
Time: 17:44
SD: 3.849
Date:
RSD C/.): 7 . 56
^e TD: CCB
Reolicate 1
Concentration (ug/L ): 2.65
icate 2
Concentration (ua/L ): 0.78
Sea. No.: OOO60 A/S Pas..- O Date: 10/1S
Time: 17:48
Time: 17:51
Mean Cone (ua/L )s 1.72
QC sample is within ranae
SD: 1.321
RSD ( 7.) : 76.9
-------
Element File: AG.GEL
Date; 1O/15/9Q
Data File:
Techniaue: HGA
Element: Ag
Time: 16:02
ID/Wt File: 81OO2.IDW
Calib. Tvce: Linear
Wavelength: 328.;
Slits 0.7 L
Lamp Current: 10
Energy: 55
ID: BLANK
Sea. Wo.: 00195
A/S Pos.: 0
Date: 10/15,
Replicate 1
Peak Area (A-s): 0.102
Backoround Pk Area (A-s): 0.150
Blank Corrected Pk Area (A~s): 0.007
Concentration (ug/L ): O.10
Reolicate 2
Peak Area (A-s): O.OBB
Background Pk Area (A-s): 0.133
Blank Corrected Pk Area (A-s): -0.007
Concentration (ua/L ): -0.71
Time: 16:02
Peak Height (A): O.15B
Background Pk Height (A)s
0.062
Time: 16:05
Peak Height (A): O.139
Backaround Pk Heiaht (A): 0.061
Mean Cone (ua/L ):
Auto-zero oer-forroed.
-0.30
SD: 0.56S
RSD <•/.): 186. £
ID: 5 PPB AG
Sea. No.: OO196
A/S Pos.: 1
Date: 10/15>
Reolicate 1
Peak Area (A-s): O.194
'Backaround Pk Area (A-s): 0.136
Blank Corrected Pk Area (A-s): 0.099
Concentration (uo/L, ): 5.37
Peak Area (A-s): 0.187
Backoround Pk Area (A-s): O.129
Blank Corrected Pk Area (A-s): O
Concentration (ug/L ): 5.O1
Time: 16sOQ
Peak Height (A): 0.290
Backaround Pk Heiaht (A): O.O6O
Time: 16:12
Peak Height (A): 0.2B3
Backaround Pk Heiaht (A): 0.057
092
Mean Cone (ua/L )
5.19
SD: 0.254
RSD(7.): 4.90
Standard number 1 applied. [5.001
Correlation coefficient: l.OOOOO
Slope: 0.0191
Int: 0.000
ID: 10 PPB AG
Sea. No,
Reolicate 1
Peak Area (A-s): 0.282
Backaround Pk Area tA-s): 0.143
Blank Corrected Pk Area (A-s): 0.1B7
Concentration (ua/L ): 9.79
00197 A/S Pos.: 2
Date: 10/15/
Time: 16:15
Peak Height (A): O.428
Background Pk Height (A): 0.062
Reol.icate 2
Peak Area (A-s): 0.288
Backaround Pk Area (A-s): 0.148
Blank Corrected Pk Area (A-s): 0.194
Concentration (ua/L ): 10.13
Time: 16:18
Peak Heiaht (A): 0.435
Background Pk Height (A): 0.065
-------
Mean Cone (ua/L ):
9,96
3D; 0.244
RSD(X): 2.4!
Standard number 2 applied. H1O.OO)
Correlation coefiicient: l.OOOOO
Slooe: 0.019O
Int: O.OOO
fto
ID: 20 PPB AG
Sea. No,
Replicate 1
Peak Area (A-sJ: 0.482
Backnround Pk Area (A-s): O.152
Blank Corrected Pk Area (A-s)i 0.3B7
Concentration (ug/L ): 20.33
Ren 1icate 2
Peak Area (A-s): O.471
Backaround Pk Area (A-s): 0.159
Elank Corrected Pk Area (A-s): 0.376
Concentration (ua/L ): 19.76
Mean Cone (ua/L ):
20.04
00198
A/S Pos.: 3
Date: 10/1!
Time: 16:21
Peak Height (A): 0.724
Background Pk Height (A); 0.06S
Time; 16:24
Peak Height (A): 0.721
Background Pk Height (A): 0.067
BDs 0.402
RSDT/.) : 2.0J
Standard number 3 applied. T2O.001
Correlation coefficient: i.00000
Slope; 0.0191
Int: -O.OOO
AQ
ID: 3O PPB AG
Sea. No,
00199 A/S Pos.; 4
Date: 10/1S
Reolicate 1
Peak Area (A-s): 0.641
Backaround Pk Area (A-s): 0.168
Blank Corrected Pk Area (A-s): 0.546
Concentration (ug/L ): 2S.65
Peak Area (A-s): O.636
Backaround Pk Area (A-s): 0.162
Blank Corrected Pk Area (A-s): 0.541
Concentration (ug/L ): 2B.39
Mean Cone fua/L
2B.52
Standard number 4 applied. T3O.OO3
Correlation coefficient: O.99938
Time: 16:28
Peak Height (A): 0.955
Background Pk Height (A): O.O85
Time: 16:31
Peak Height (A): 0.947
Background Pk Height (A): 0.096
SD: O.184
Slopes O.O182
RSD(7.): 0.64
Int: 0.005
-------
jNliiplay Calibration • Ci\li USuRxAn Pill
i
i
i
i
i ? -
i *
i
i
!
i
i *•
.-£3 £4
^
^•'"~
J2** .
Jj2.c j C&?*?'*c&4f . | 0.99934
_^- llspa; S.iiii
- IrXarsss'S; pfjfSf n ••
a concAncraci^n to. SO
I
*
%
Aa ID: ICV Sea. No.! 00200 A/S Pos.: 5 Date: 10/1!
Renlicate i
Concentration (uq/L )i 20.25
Reolicate 2
Concentration iua/L ): 20.13
Mean Cone (ua/L ):
20.19
Time! 16:35
Time: 16:3=?
SDs 0.083
"QC samole is within ranae 15.5 - 24.49
RSD('/.): 0.4J
An ID: ICB
Reolicate 1
Concentration (ua/L ): -O.95
R^olicste 2
Concentration (ua/L ): -1.04
Mean Cone (ua/L ): -1.00
QC sample is within ranqe -5.49
Sea. No.: OO2O1 A/S Pos.
Time: 16:45
Time: 16:48
SD: O.061
Date: 10/1S
RSD(7.): 6.11
5.49
Aa
ID: B1.0O2.B-1
Reolicate 1
Concentration (uo/L ): -0.19
pRoli cate 2
Concentration (uq/L )
Mean Cone (ua/L ):
An ID: 81002.9-1
Reolicate 1
-0.21
-0.20
Sea. No.: OO202 A/S Pos.: 6
Time: 16:51
Time: -16:55
SD: 0.020
Date: 10/1S
RSDC/.): 10.0
w^Arf^^A*A*^^^^^^^^^A*^^A*A«'W*S*'
-------
!eol icate 2
Concentration (ua/L ): -O.BB
lean Cone (uo/L ): -0.99
Time: 17:34
SD: 0.163
RSD ('/.): 16.4
• a ID: 81G02.1-2A
leolicate 1
:oncentration (ug/L ): 8-10
'eol icate 2
Concentration (ua/L 5: 8.37
Sea, Mo,
lean Cone (ug/L ):
iecoverv is 92.3*/.
.8.23
OO209 A/S Pos.
Time: 17:37
Time: 17:40
SD: O.195
11 Date: 10/15
RSD ('/.): 2,37
*a TD: 810O2.2-2A Sea. No.
Jeolicate 1
Concentration (ug/L ): -1.00
!e?n 1 i cate 2
Concentration (ua/L ): -0.85
lean Cone (ua/L )s -0.92
00210 A/S Pos,
Time: 17:43
Time: 17:47
SD: 0.105
12 Date: 1O/15
RSD ('/.): 11.4
TD: 810O2.3-2A
Sea. No.
Concentration (ua/L ): -0.86
Jpo1! icate 2
Concentration (ua/L ): -1.03
lean Cone (uo/L ): -O.94
OO211 A/S Pos.
Time: 17:5O
Time: 17:53
SD: 0.123
13 Date: 10/15
RSD (7.): 13.0
in IDs CCV
Dedicate 1
Concentration (ua/L ): 19. i
Sea. No.: 00212 A/S Pos.
Time: 17:56
i cats 2
Concentration
-------
"»ol i cste 2
Concentration (uq/L ): — 1,O5
lean Cone (uq/L ): -1.O9
1C sample is within ranae —5.4*?
Time: 18:06
BD: O.05S
- 5.49
RSD C/.): 5 . 36
in TD: 81003.RB-AP
ieolicate 1
loncentration (uq/L ): -1.21
!f=ol icate 2
loncentration (ua/L 1: -1.32
Sean Cone (ua/L ): -1.27
Sea. No,: 00214 A/S Pas,
Time: 18:09
14 Date: 10/15;
Time: 18:12
SD: 0.072
RSDC/.): 5.68
(n TD: B1OO3.RB-F
leolicate 1
Concentration (uq/L ):
Sea. Na.: 00215 A/S Pas
Time: 18:15
15 Date: 1O/15,
icate 2
'oncentration (ua/L ):
lean Cone (ua/L ) :
-1.06
-l.OB
-1 .07
Time: 18:18
SD: 0.012
RSD(X): 1.14
i>n TD: B1O03.0B
?eol icate 1
Concentration (uq/L ): 1.51
Sea. No.
i. cste 2
Concentration (ua/L ): 1.47
lean Cone fua/L ):
1.49
00216 A/S Pos,
Time: 18:21
Time: 18:24
SD: 0.03O
16 Date: 1O/15/
RSDC/.): 2.O5
TD: 810O3.UB
i cate 1
Concentration (ua/L
?*=nl j cate 2
Concentration (ua/L
lean Cone (ua/L ):
Sea. No,
): -1.O1
): -0.93
-O.97
00217 A/S Pos,
Time: 18:28
Time: 18:31
SD: 0.057
17 Date: 10/15/
RSDC/.) : 5.82
^n TOr 81003.IB
Ieolicate 1
Concentration (uq/L ): -1.07
'<=nl icate 7
Concentration (ua/L ): -1.O4
Sea. No.: 00218 A/S Pos;
Time: 18:34
Time: 18:37
18 Date: 10/15X
-------
lean Cone (up/L ): -1.06 SD : 0.025 RSDC/.): 2.3£
in ID; 810O3.01 Sea. No.: O0219 A/S Pos.: 19 Date: 10/15
teolicate 1 Time: 18:4O
Concentration (uq/L ): 1.34
i«o licsts 2 Time: 18:43
Concentration (uq/L ) ; 1 . 59
lean Cone fua/L 1: . 1,46 SD : 0.179 RSD(X): 12.2
^n TD: 81OO3.Q1 Sea. No.: O0220 A/5 Pos.: 19 Dates 1O/15
?£?olicate 1 Time: 18:46
Concentration (ua/L ): 1O.71
ocate 2 Time: 18:50
:oncentration (ua/L 1: 1O.42
lean Cone iug/L ) : 10.56 SD : 0 . 2O3 RSDC7.): 1.92
Recovery is 91. 07.
*n ID: 81003.02 Sea. No.: O0221 A/S Pas,,: 2O Date: 10/15
j?eDlicate 1 Time: 18:53
Concentration (uq/L 1: 20.44
5=c licBte 2 ' Time: 18:56
Concentration ,.-: :'r-oi:
Concentration iuo.'L '> ; -":.37
' "• : S' ••':-.•.-• ' :-;,-,,. r.j(-;,: 0072T A/S Pos. : 22 Date: 10/15.
- - - ' Time: 19;O5
":-.. ..-:••:; ,,l ; on
-------
Dates 10/15;
An
D: CCV
icate 1
Concentration (ua/L ): 19.12
Sea. Mo.: O0224 A/S Pos.
Time: 19:12
Time; 19:15
Concentration I'uq/L ): 18.08
"lean Cone (ua/L ): 18.60 SD: 0.738
3C samole is within ranqe 15.5 - 24.49
RSDC/.): 3.97
An ID: CCB
Renlicate 1
Concentration (ua/L ): -1.13
R=>r,1 irate 2
Concentration (ua/L ): -1.06
Sea. No.: O0225 A/S Pos.
Time: 19:18
Time: 19:21
Mean Cone (ug/L Is -1.10 SD: 0.046
DC •samole is within ranoe -5.49 - 5.49
Date: 10/15/
RSD C/.): 4.23
An TD: 8:1 003, U2
Reolicate 1
Concentration (ua/L )s
Sea. No.
Concentration (ua/L 1:
Mean Cone (uo/L );,
-1.63
-1.54
-1.59
00226 A/S Pos.: 23 Date: 10/15/
Time: 19:24
Time: 19:28
SD: 0.064
RSD C/.): 4.04
An TD: 31O03.U3
Renlicate 1
Concentration
-------
:iement File: TL.GEL
sate: 10/19/98
*ata File:
'echniaue: HGA
Element: Tl
Time: 18:11
ID/Wt File: S1OO2.IDW
Calib. Type: Nonlinear
Wavelength: 276,
Slit: 2.OO H
Lamp Current: 7
Energy: 45
'1
ID: BLANK
Sea- No.: OOO61
A/S Pas.: 0
Date: 10/1S
!eolicate 1
>eak Area (A-s): O.O03
lacknrbund Pk Area (A-s)j O.O13
Hank Corrected Pk Area (A-s): 0.OO3
tenlicate 2
3eak Area (A-s): -O.OOO
Jackaround Pk Area ; O.021
3ackoround Pk Area (A-s3: O.O37 /
Blank Corrected Pk Area (A-B): O.019|
•lean Pk Area (A-s):
O.O17
Standard number 1 aonlied. [,10.00]
Torrelation coef1icient: l.OOOOO
Time: 1B:21
Peak Height (A) -. 0.027
Backaround Pk Heiaht (A): O.O23
SD: O.OO33
Slooe: 0.0017
RSD (7.): 19.4
:i-.aracteristic Mass = 22.6 oa/0.0044 A-s
ID: 20 PPB TL
5ea. No.: OO063
A/S Pos.i 2
Dates 10/19.
Replicate 1
^eak Area (A-5); 0.033
Backaround Pk Area (A-s): 0.055
Blank Corrected Pk Area (A-s): 0.031
Concentration (ua/L ): IS.34
Time: 1B:24
Peak Height (A): 0.034
Backoround Pk Heiaht (A): 0.031
'eolicate 2
Deak Area (A-s): 0.O3O
BackaroLind Pk Area (A-s): 0.059
Time; 18:27
Peak Heiaht (A): 0.040
Backaround Pk Heiaht (A); 0.032
-------
ilank Corrected Pk Area (A-s): 0.029
Concentration (ua/L )s 16.61
lean Cone (uo/L
17.47
standard number 2 aoDlied. £20.001
rorrelation coefficient: l.OOOOO
SD: 1.226
Slooe: 0.0020
RSD r/.J; 7.02
ID: 50 PPB TL
Sen. No
^eolicate 1
=eak Area fA-s): O.OBO
3acka round Pk Area (A-s): O.O93
31ank Corrected Pk Area (A-s): O.078
Concentration (ug/L ): 115.22
3e>ak Area (A-s): O.OB2
3ackaround Pk Area (A-s): O.093
Blank Corrected Pk Area (A-s): O.OBO
Concentration (uo/L ): 123.13
"lean Cone (ua/L ):
119.09
00064 A/S Pos.: 3 Date: 10/19/
Time: 18s3O
Peak Heiaht (A): O.OBO
Backoround Pk Heioht (A): O.O56
Time: IB;34
Peak Height (A): 0.081
Backaround Pk Heiaht (A): O.061
3-shaDed calibration curve detected. 2
standard number 3 applied. [50.00T
Correlation coefficient: 0.99BO9
SD: 5.597
-coef. equation used.
Slooe: O.OO17
BSD ('/.): 4 . 7O
Tl
ID: IOC PPB TL
Sea. No.: OO065
•=eak Area (A-s): 0.153
Backaround Pk Area
-------
- CAflft USERf*
VI
.
; C.301S
Concentration
100. DO
Tl
ID: ICV
Sea. No.: OOO66 A/S Pos,
Time: .18:44
Time: 18:47
SD: 3.O58
Date: 10/1S
Reolicate 1
Concentration (ua/L ): 51.09
Reolicate r
Concentration (ua/L I: 46.76
Mean Cone (ug/L i: 48.92
QC samole is within range
RSDC/,)s 6.25
Tl ID; ICB
Reolicate 1
Concentration (ua/L ): -2.91
Reolicste 2
Concentration (uq/L 5: -2.21
Mean Cone (uo/L )! -2.56
QC sample is. within ranae
Sea. No,: O0067 AVS Pos.: 0
Time: 18:51
Time: !Bs54
SDs 0.495
Date: 10/19
RSD(7.): 19.3
Tl ID: BJ003.RB-AP Sea. No,
Replicate 1
Concentration (uq/L ): 0.19
Rf=olicate 2
Concentration (uo/L ): -1.09
OOO68 A/S Pos.: 14 Date: 10/19
Time: 18:57
Time: 19:00
Mean Cone (ua/L ):
-0.45
SD: 0.911
RSD(7.): 202.
Tl
ID: 81003.RB-F
Reolicate 1
Concentration (ua/L ):
Sea. No.: OOO&9 A/S Pos.s 15 Date: 10/19
Time: 19:O3
-2.47
-------
R«=r>] icate 2 Time: 19:06
Concentration (ua/L 3: —1.71
Mean Cone (uq/L ): -2.O9 SDs O.543 RSD ("/.): 25.9
T1 ID: 81003. OB Ben. No.: OO070 A/S Pos . : 16 Date: 10/19
Reolicate 1 Time: 19:09
Concentration (ua/L ): 0.64
nl icate 2 Time: 19:12
Concentration
-------
^ecoverv is 93,47.
^a ^ *\j ^ 'V *V **•* *V f^f **? ^r 'V 'V ^- ^ 'I/ *V 'V '
T1 ID; 81003.02
•lean Cone (ug/L ):
Sea. Mo.
Concentration (ug/L ): O.O3
^eolicate 2
ZoncEntration (na/L ): 3.76
1.89
O0075 A/S Pos
Time: 19:41
Time; 19:44
SD: 2.
-------
Mean Cone (ua/L ): 8.62 SD: 5.441 RSDC/.): 62.9
T1 ID: B1OO3.U2 Sea. No.: OOO80 A/S Pos.: 23 Date: 10/19
Renlicate 1 Time: 2O:12
Concentration (up/L ): 2.75
R=D>icatB 2 Time: 20:16
Concentration (ua/L ): 2.7B
Mean Cone (ug/L ): 2.77 SD: 0.025 RSDC/.): 0.89
Tl TD: 01003.U3 Sea. No.: OOO81 A/5 Pos.: 24 Date: 1O/19
Reolicate 1 Time: 2O:19
Concentration (ug/L ): 8.87
n=Dlicate 2 Time: 20:22
Concentration (ug/L ): 11.73
Mean Cone (ug/L ): 1O.30 SD: 2.027 RSDC/.): 19.6
"V *
Tl ID: 81003.11x5 Sea. No.: OOOS2 A/S Pos.: 25 Date: 10/19
Reolicate 1 Time: 2O:25
Concentration (ug/L ): 7.88 Corrected Cone (ug/L ): 39.4
2 Time; 2O:29
Concentration (ug/L ): 10.56 Corrected Cone (ug/L ): 52.8
Mean Cone (ug/L ): 9.22 SD : 1.892 RSDC/.): 20.5
Corrected Cone (ug/L ): 46.1
Tl ID: 81003.12x5 Sea. No.: OOO83 A/S Pas.: 26 Date: 1O/19
Reolicate 1 Time: 20:32
Concentration (ug/L ,) : 8.93 Corrected Cone (ug/L ): 44.6
cate 2 Time: 20:35
Concentration
-------
rl
ID: CCV
?eolicate 1
Concentration (uq/L ): 44.91
'eolicate 2
:oncentration (ua/L ): 46.38
lean Cone (ug/L ) : 45.^
3C sample is within ranae
Sea. No.: OOOB5 A/9 Pos,
Time: 2O:45
Time: 20:48
SD: 1.038
: 3
Date: 10/19
1
ID: CCB
i cate 1
Concentration (ug/L ): 1.1O
icate 2
Concentration (ug/L ): -0.06
'lean Cone (ug/L ): O.52
3C samole is within ranae
Sea. No.: OOO86 A/S Pos,
Time: 20:51
Time: 2O:55
SD: 0.821
RSD ('/.): 2 . 27
/'W'W'W'V
Date: 1O/19
RSD (7.): 156.
ri
ID: 81006.1x5
^eolicate 1
Concentration (uq/L
^eo!tcate 2
Toncentration (ua/L
•lean Cone (ua/L ):
Sea. Mo.: 00087
A/S Pos.: 28
0.53
); 3.14
1.83
lorrected Cone (ua/L ): 9.2
Time: 20;58
Corrected Cone (ug/L
Time: 21:O1
Corrected Cone (uq/L
SD: 1.848
Date: 10/19
) : 2.6
): 15.7
RSDC/.): 1OO.'
Tl
IDs 81006.1x5
Sea. No.: OOO88
A/S Pos.: 28
Date: 1O/19,
Concentration (ug/L ): 51.97
"eolicate' 2
Zoncentratian (uo/L ): 48.19
lean Cone
-------
Concentration (ug/L ): 3.90
lean Cone fug/L ): 3.54
Corrected Cone (uo/L ): 17.7
Corrected-Cone (ug/L ): 19.5
SDs 0.513 RSD ('/.)! 14.5
ri
ID: 81006.3x5
Dedicate 1
Concentration (ug/L >: 5.05
Concentration v'ua/L ): 4.46
Sea. No.: OOO90 A/S Pos.; 30 Date: 10/19
Time: 21:17
Corrected Cone (ug/L ): 25.2
Time: 21:20
Corrected Cone (ug/L )s 22.3
•lean Cone (ug/L ): 4.75
Corrected Cone (ua/L ) : 23. B
SD: O.412
RSD (7.}: B.
00091 A/S Pos.: 3 Date: 1Q/19
Time: 21:23
Time: 21:27
TD: CCV
Sea. No.
Concentration (uq/L ): 49.51
^<=ol icate 2
Concentration (ug/L ): 49.92
Cone (ug/L ): 49.71
3C samole is within ranae
SD: O.2B7
Tl TD-. CCB Sea. No. :
Renlicate 1
Concentration (ug/L ): -2.06
ReDlicate 2
Concentration (uq/L ): 0.99
Mean Cone (uq/L ): -0.54
QC sample is within range
RSD C/.): 0. 58
00092 A/S Pos.: 0 Date: 10/19
Time: 21:30
Time: 21:33
SD: 2.163
RSD C/.): 4O4.i
Ti ID: CCV
Reolicate 1
Concentration (ug/L ): 48.50
Sea. No,
Concentration iua/L ): 45.22
Mean Cone (ua/L ): 46.85
QC sample is within ranae
O0093 A/S Pos
Time: 08:01
Time: 08:04
SD: 2.318
Date: 10/20
RSD m: 4.95
-------
M ID: CCB
lenlicate 1
Concentration (ua/L
Sen. Mo,
): -0.00
^™ol i c •?, ^~ s? ^ *"
loncentration (uq/L 3: -0.49
•lean Cone »uo/L ): -0.25
3C samole is within ranae
OO094 A/5 Pos
Time: 08:O7
Time: 08:10
SD: 0.344
0
Date; IO/2C
RSDm : 139.
IDs 31003.11 Sea. No,
i cats 1
loncentration (LIQ/L ): 35.62
^ e D 1 5" r 5 T. S ilZ
loncentration (ua/L ): 37.38
•lean Cone »uo/l_ ) :
36. 50
00095 A/S Pos,
Time: 08:14
Time: OS;17
SD: 1.249
: 25 Date: 1O/20
RSD C/.): 3.42
ID: B1003.T2
icate 1
oncentration iug/L
Sea. No.:
i : 49.66
Concentration iug/L ): 48.86
*!ean Cone (ua/L ): 49.26
OO096 A/S Pos
Time: 08:20
Time: 08:24
SD: 0.566
: 26 Date: 10/20
RSDC/.)s 1.15
ID: 81OO3.I3
Sea. No,
Concentration Cug/L ): 46.14
Concentration (ug/L >: 46.23
Mean Cone (ua/L ): 46.18
OO097 A/S Pos.! 27 Date: 1O/2O
Time: 06:27
Time: O8:30
SD: 0.065
RSD('•/.): 0.14
TI TD: 81O06.1 Sea. No
Reolicate 1
Concentration (ua/L ): 16.97
Concentration i'ua/L ): 18.19
^lean Cone I'uo/L ): 17.58
OOO98 A/S Pos.: 28 Date: 1O/2O,
Time: 08:33
Time: 08:37
5D: 0.861
RSDfV.): 4.90
-------
n
ID; 810O6.1
Seq. No,
icate 1
'concentration £ug/L >: 56.27
"oncentration I'uo/L ): 56.46
lean Cone fug/L >; 56.37
Recoverv is 77.67.
OOO99 A/S Pos.i 2B
Time: O8:4O
Time: 08:43
SD: 0.139
Dates 10/2O
r\ ID: 81006.2
Sea. No,
i cats 1
2oncentration (uq/L )
5e plicate 2
Don centra t ion ( uq/L )
Cone iua/L ):
13.37
16.79
15. OB
OO100 A/S Pos.: 29
Time; OB:46
Time: O8:50
SD; 2.419
RSD(7.)s 0.25
Dates 10/20
RSD(7.1: 16.0-
Date: 1O/20
n ID: 8'1006.3
^eol icate 1
loncentration (ug/L
Dedicate 2
Zpncentr ation (ug/L
Cone ! un/L
Seo. No.
): 15.00
): 11.39
13.18
O0101 A/S Pos.: 3O
Time: O8:53
Time: OS:56
SD: 2.561
RSD <•/.): 19.4!
ID: CCV
Sea. Ma,
Concentration (uo/L ): 54.96
Sen? 1 3 cat= 2
Concentration (uo/L ): 53.69
Mean Cone (uo/L- ):" 54.32
QC samole is within ranoe
001O2 A/S Pos.: 3
Time: 08:59
Time: 09:02
SD: O.B99
Date: 1O/20
/.>: 1.65
Tl ID: CCB
Reolicate 1
Concentration (ua/L ): -3.09
^ *? O I 1. C & X 5 "'
"oncsntration (ua/L ) : -O.94
Seo. Mo.: O0103 A/S Pos.: 0
Time: 0^:06
Time: O9:09
Date: 10/20.
Mean Cone «uo/L ):
-
.0
.
SD: 1.525
RSD £•/.); 75. 7C
-------
PERKIN--ELMER M 11,00
98/10/15 PAGE 18
AA
AA
MAINs 0,003 MB/L HO 0.001 MAIN: 0.002 M6/L HO 0.001
ZN MEAN: 0.002 M8/L BDs 0.001 RSD: 21.8 AUTOZERO O.OOO
AA AA
0.098 MS/L HO O.Q39 MAIN; 0.082 MB/L HO 0.032
ZN MEANs 0.090 MG/L BDs O.O12 RSD: 12.8 1,STANDARD 0.090 MB/L
AA AA
MAINE 0.145 MB/L HD 0.057 MAIN: 0.137 MG/L HO O.O54
ZN MEAN: 0.141 MG/L BDs O.O06 RSD: 4.1 2.STANDARD 0.140 MG/L
AA AA
MAIN: 0.220 MG/L HD 0.08B MAIN: 0.235 MG/L HO 0.093
ZN ' MEANs 0.22S MG/L EDs 0.010 RSD: 4.6 3.STANDARD 0.227 MB/L
AA AA
MAIN:: 0.. 516 MS/L. HO 0,. 2O6 MAIN: 0.512 ME/L HO 0.204
ZN MEANS 0.514 MS/L SDs 0,003 RED." 0.6 4, STANDARD 0.513 MS/L
AA AA
MAIM;. 0.919 MB/L HO 0.36(3 MAINs 0.910 MG/L HO 0.365
ZN MEANt 0.9:1.3 MB/L SD: O.006 RSD: 0.7 5. STANDARD 0.959 MB/L
FLAME DISPLAY CALIBRATION MOBE
ELEMENT: ZN
REPL. 3 OF 2
0.36fc'
flBS.
S3
PRINTER: W
BS CORR: OFF
UNITS : HG/L
CONCENTRATION (MS/L )
C2H£s 2.5 L/MIN OXIDfiMTs 8.0 L/MIM
0,959
READ
fflS, READING
S5 Afl : 0.365
1.005
FLAME: C2H2-AIR
STATISTICS
MEAN; 0.915
SD: 0.0Q6
1 RSD(J»s 0.7
AA
MAINr 0,00:1 h'G/L HO 0,001
?N MEAM: O, OOO MR/!.
MAINs -O.O01 MG/L HO-0.000
O.OOt F'BD: 99.. 9 AUTD7ERO O-OOO
-------
PERKIN-ELMER M 1100 98/10/15 PABE 19
AA AA
MAIN: 0.500 MG/L HO 0.207 MAIN: O.475 MG/L HO 0,198
ZN ^-vj MEAN: 0.488 MG/L SD: 0.01B RSD; 3.6
AA AA
MAIN: 0.005 MB/L HO 0.002 MAIN: 0.001 MG/L HO 0.001
ZN
^ (5 MEAN: 0.003 MG/L SB; 0.002 RSD: 86. 6
AA AA
MAINs 0,380 MB/L HO 0.163 MAINs 0.400 MG/L HO 0.170
0 ZN g--/ MEAN; 0.390 MG/L SD: 0.014 RBD: 3.6
j^ ...- -- .... _, _-„..,-. »»»„„ „ . ,„. ^^^.. _,- *,,„,.,„,-,, „.. .„._., ... „. , —,.„„,,„«,.- , „„ -...«„.._ : ™^ „., .,.,. ,>»__..„.. ...» „, „_. „ ,_-.«..,«.,-.* ... ™.-., *—».».-..,-., . ._.-(_„
AA AA
MAIN: O.272 MG/L HO 0.12O MAIN: 0.263 MB/L HO 0.116
ZN -- MEAN; 0.267 ME/L SD: 0.006 RSD: 2.4
AA AA
MAIN: 0.654 MB/L HO 0,260 MAINs 0.679 MG/L HO O.26S
ZN £~l-£>MEANs 0.666 M6/L SD: 0.018 RSD; 2.7
AA AA
MAINs 0.35S MG/L HO 0.154 MAINs 0-3B4 MG/L HO 0.164
ZW
— I MEAN: 0.371 MB/L BD: 0.018 RSD; 4.9
AA AA
MAIN: 0.360 MG/L. HO 0.155 MAINs 0.353 MG/L HO 0.152
ZN *?-U> MEAN: 0.356 MB/L ED: 0.006 RSD: 1.6
AA AA
MAINs 0.426 MG/L HO 0.180 MAIN: 0.439 MG/L HO 0,135
ZN /0-l MEAN: 0.433 MB/L SD: 0.009 RSD; 2.2
AA AA
MAIN; 0.013 MG/L HO 3.CO6 MAIN: 0.014 MG/L HO 0.007
ZN yL3* MEAN: 0.013 MG/L SD: O.OOO RSD: 2,, 3 AUT02ERO O.OOO
A^ AA
MAINi 0.115 MG/L. HO 0. OS3 MAIN: 0,114 MB/L HO 0.053
ZN g-T."* MEAN: 0.115 MG/L SDs 0.001 RSD: 0.6
-------
PERKIN-ELMER M 1100 98/10/15 PAGE 20
AA AA
MAIN: 0.170 MB/L HO 0.077 MAIN: 0.170 MB/L HO O.077
7iS! £.7.4 MEAN: 0.170 MP/L. BD: 0. 000 RSDs O.I
AA AA
MAIN: 0.519 MB/L HO 0.214 MAIN: 0.557 MB/L HO 0.227
ZN S-'2- MEANs 0.53B MB/L SDs 0.026 RSDs 4.9
AA AA
MAINs O.489 MB/L HO O.2O3 MAIN: 0.513 MB/L HO O.2i:
„„. »,- .,„. ^Tw £j ^^lu, ,„„ I.W. HH> li — ™« H>« HM BM — .«. -M. »«. _« «_ —. UH „«. _lt. ««l ^-. lu, «u. ,-., ««.. .«_ .^. ,_» ««, «»• ,-M UU* «f m,H n_l «. *—i, ^( uu ~_ U«> •*. >«_ —.. «• HHI imH •»> •«• fl«M ««• W« u« <•.» -"" ~« «•
ZM &A MEAN: 0.501 MB/L 60s 0.016 RBD: 3.3
AA AA
MAIN: -0.004 MB/L HQ-0.002 MAIN: -0.005 MG/L HO-0.002
ZN f"cg MEAN:-0.004 MB/L BD; 0.001 RSDi 16, B
AA AA
MAIWs 0.ISO MB/L HO O.OB2 MAIN: 0.172 MB/L HQ O.078
ZN 7-XT MEAN; 0,176 MB/L ED; 0.006 RSD: 3.3
AA AA
MAINE 0,164 MG/L HO O.O74 MAIN: 0.17O MB/L HO O.077
2N -U-^ MEAN: 0.167 MB/L BD; 0.004 RSD: 2.6
\
AA '' AA
MAIN; 0.220 M6/L HO 0.098 MAIN: 0.218 MS/L HO 0.099
ZN /f^ MEANs 0.219 MG/L SDi 0.001 RSDs O,, 5
A A A A
ifl»>.MAIN! 0.106 MG/L HO 0.049 MAIN: O.O93 MB/L HO O.043
Vx^-» ,,..,„.„._ . , . , . .
ZN rZ.4-/"f MEAN: 0.100 MB/L. SDs O.009 RSD: 9,, 4
AA AA
MAINS 0.10B MB/L, HO 0.050 MAIN: 0.111 MB/L HO 0.051
ZN AS-?- MEAN? 0,1O9 MB/L BDs 0.002 RBD: 2.2
AA AA
MAIN: 0.107 MB/L HO O.049 MAIN: 0.094 MB/L HO 0.044
ZN /*>(£ MEAN: O, 100 MB/L SD: 0.009 RSD: B. 8
-------
PERKIN-ELMER M 1100 98/10/15 PAGE 21
AA AA
MAIN; 0,092 MS/L HO 0.043 MAIN: O.I 14 M6/L HO O.053
ZN rt MEflNs 0.103 MG/L ED: 0.015 RSD: 14.8
AA AA
MAIN: 0,135 MB/L HO O.06.2 MAIN: 0.121 MG/L HO 0.056
ZN /- MEAN: 0,128 MB/L BDs 0.009 RSD: 7 = 3
AA AA
MAIN'.' 0.467 MB/L HO 0.195 MAIN: 0.439 MB/L HO O.203
MEAN: 0.47B MB/L BD: 0,015 RBDi; 3.2
AA AA
MAIN: 0.005 MS/L HO 0.003 MAIN: -0.005 MB/L HO-O.O02
ZN ^£ MEAN: O.OOO MB/L BD: 0.007 RBDz 99.9
AA AA
MAIN: 0.08S MB/L HO 0.040 MAINs 0.081 MG/L HO O.O38
ZN O{ MEAN: 0.083 MB/L BD: 0.003 RSD 2 4,0
ftA AA
MAINs 0.124 MG/L HO 0., 057 MAINs 0.1. .1.1 MS/L HO G.052
£) 1- MEAN; 0.117 MB/L GDt 0, OO9 REDr 7,, 2
ft A ' A A
MAINs 0.079 MG/L 1 !C 0., 037 MAIN;. 0.077 MB/L HO 0,036
ZM O^ MEAN;. 0, 07E MS/L SD: O.OO1 RSD: 1.8
AA AA
0,130 MS/L :-!Q 0.060 MAINs 0.129 MB/L HO 0.059
ZN ^jj MEAN: 0.129 MG/L 3D: O.OO1 RSD: 0.7
A A A A
MAIN;. 0.122 MB/L HO 0,056 MAIN: 0.133 MS/L HO 0.061
ZN MEANs 0.127 MG/L BD; 0.008 RSD: 6,0
AA AA
MAIN: 0.131 MB/L HQ Q.Q&Q MAIN: 0.105 MG/L HO 0.049
ZN MEAN: 0,1 IB MB/L SD^ 0.01B RBDs 15,6
-------
PERKI M~ ELMER M 1100 98/1O/1S PAGE 22
AA AA
MAIN; 0.104 MG/L HO 0.048 MAIN: 0,O99 MB/L HO O.046
ZN l{"2, MEANs 0.101 MG/L BDi: O.OO3 RSDj 3.2
AA AA
MAIN: 0.480 MG/L HO 0.200 MAIN: 0,477 MG/L HO O. 199
ZN CL MEAN: O.479 MG/L 3D: 0.002 RSD: 0.5
AA AA
MAIN: 0.000 MG/L HO O.OOO MAIN? -O,001 MG/L HD-O.OOO
ZN C MEANS -0.000 MG/L EDs 0.001 RSD: 99.9
AA AA
MAIN." 0.357 MG/L HO 0.154 MAIN: 0.356 MG/L HO 0.153
ZN#x5 MEANs 0.356 MB/L. GD: 0.001 RSD: 0.2
AA AA
MAINE 0.774 MS/L HQ 0.299 MAINs 0.770 MB/L HO 0.297
ZN /f/C-* MEANs 0.772 MG/L SDs 0.003 RSD: 0.4
AA AA
MAIN: 0.490 MG/L HO 0.204 MAIN: 0.476 MG/L HO 0.198
ZN s MEAN: 0.483 MB/L BDs 0,010 RSD: 2.1
AA AA
MAIN". 0.45H MB/L. HO 0.191 MAIN: 0.454 MG/L HO 0.191
ZN -L"^< MEANs 0.455 MB/L SDs O.OOO RSD: 0.1
A A A A
MAIN: 0.209 MB/L HO 0.094 MAIN; O.209 MG/L HO 0.094
$ ZN | ^^" MEAN:; 0,20? MB/L SD: 0.000 RSD; 0,0
AA AA
MAIN: 0.593 MB/L HO O.240 MAINs 0.607 MB/L. HO 0.244
ZN I<,s/C"~NEANs 0.600 MG/L SD: o.oio ROD,- 1.7
AA AA
MAINs 0.139 MG/L HO 0.064 MAIN: 0.138 MG/L HG 0.063
ZN I_/< MEANs 0.138 MB/L GD: 0.001 RED: 0.6
-------
PERKIM-ELMER M 1100 98/10/15 PABE 23
AA AA
MAINs 0.139 MG/L HO O. O&4 MA.TNs 0.136 MG/L HO O. O62
MEAN; O.137 MB/L SD: O.O02 RSD: 1.5
AA AA
MAIN; 0.153 MG/L HO 0.070 MAIN: 0.146 MG/L HO O.O67
ZN ^vC^ MEANs 0.149 MB/L SD: 0.005 RSD: 3.1
AA AA
MAIN: 0.507 MG/L HQ O.210 MAIN: 0.515 MG/L HO 0.212
ZN ^^ MEAN: 0.511 MG/L SD: 0.005 RSD: 1.0
AA AA
MAIN: --O.O04 MB/L HD-0.002 MAIN: -0.003 MB/L HO-Q.OG2
ZN xy fi MEANs-0.003 MS/L 3D: 0.000 RSD: 7.9
-------
SENT BY'EASTERN RESEARCH GROUP: 10- 5-MB ; !& =
0 I Of 89 IOV9-
I O I D9H I WCST'TT fc
VERG
RESEARCH OKOkJP. INC,
Eastern Research Group
Sample Chain of Custody
AtaM* « Filters
Connnfe In Amber Jars
represent sample* takon from filters,
B-I-M31 5-1 -F (080798-05)
B-I-M31 5-1 -F (000798-1 6)
B-I-W315-2-F (080798-04)
B-I-M3T5-Z-F (080798- 19)
B-1-M315-3-F (080798-11)
B-1-M315-3-F (080798-15)
B-I-M315-FB-F (080788-2)
B-0-M315-1-F
B-0-M315-3-F
B-O-M315-FB-F
B-U-M315-1-F
B-U-M315-2-F
B-U-M315-3-F
B-U-M315-FB-F
Content* in Aluminum Pans tor "FILTERS"
npneontMGEM from fhe filter Matrix
female ID
B-i-M315-1-F(oe0798-05)
B-I-M31 5-1 -F (080798-1 6)
B-I-M315-2-F (080798-04)
B-I-M315-2-F (080798-19)
B-1-M31 5-3-F (080798-T 1)
B-I-M31S-3-F (080798- 15)
B-I-M315-FB-F (080798-2)
B-0-M315-1-F
B-0-M315-2.F
B-0-M315-FB-F
B-U-M315-1-F
B-U-M31S-2-F
B-U-M315-3-F
B-U-M315-FB-F
Aluminum Pan
10
11
12
13
14
16
16
17
10
19
20
21
22
29
Contents in Aluminum Pan* far AteC/2 FHR
represent MCEM from Ma MeCfS Matrix
Matrix « Methylene Chloride FHR
Contents in Aluminum Pana tor H2O Imp Rinses
npnaant MCEM from tit* H20 Imp fftnao Matrix
Sample ID
B-I-M315-1-FH-M
B-I.M315-2-FH-M
B-1-M315«3-FH-M
B-I-M315-FB-FH-M
B-0-M315-1-FH-M
B.O.M315-5.FH-M
B-0-M315-3-FH-M
B-0-M315-FB-FH-M
B-U-M316-1-FH-M
B-U-M315-2-FH-M
B-U-M315-3-FH-M
B-U-M315-FB-FH-M
Aluminum Pan #
10
11
12
13
14
15
16
17
18
19
20
21
Matrix B H20 Implngar RlntM
Sample ID
B-I-M315-1-IMPH20
B-I-M315-2-IMPH20
6-hM315-3-iMP H20
B-I-M315-FB-IMPH20
B-O-M315-MMPH20
B-0-M315-2-IMPH20
B-O-M315-3-IMPH20
B-0-M315-FB-IMPH20
B-U-M315-1-IMPH20
B-U-M315-2-1MP M20
B-U W315-3-1MP H20
B-U-M315-FB-IWPH20
Aluminum part #
13
14
15
16
17
18
19
20
21
22
23
24
Date!
Data!
Paga1of2
-------
SENT BY'EASTERN RESEARCH WOUPMO- 5-88
15:49
B1B4B878D3-
Eastern Research Group
Sample Chain of Custody
Content* In Aluminum Pans for 'Acetone BHft"
represent MCF.M from ffw Acetone BHR Matrix
Matrix* Acetone DHR
Contents in Aluminum Pans lor M»C& BHR
ffpnsent MGEM from the M»CI2 BHfJ Matrix
Matrix e Mothylono Chloride BHR
B-UM31S-1-BH-A
B-I-M315-2-BH-A
D-I-M315-3-BH-A
3-I-M315-FS-BH-A
3O.M31S-1-BH-A
3-0-M315-2-RH-A
J-0-M315-3-BH-A
J-0-M315-FB-BH-A
J-U-M315-1-BH-A
{•U-M315-2-BH-A
I-U-M315-3-BH-A
I-U-M31S-FB-BH-A
1
Z
3
4
B
6
7
e
9
10
11
12
B-1-M315-1-BH-M
B-l-M315-li-BH-M
B-1-M315-3-BH-M
B-f-M31S-FB-BH-M
B-OM315-1-BH-M
D-0-M315-2-BH-M
B-O-M315-3-BH-M
B-0-miS-FB-BH-M
B-U-M315-2-BH-M
B-U-M31E-3-DH-M
B-U-M315-FB-BH-M
Aluminum Pap #
1
2
3
&
5
6
7
a
9
10
11
12
Relinquished by:
-------
Environmental
Quanterra Incorporated Services
880 Riverside Parkway
West Sacramento, California 95605
926 373-5600 Telephone
916 372-1059 Fax
September 17,1998
QUANTERRA INCORPORATED PROJECT NUMBER: 301036
PO/CONTRACT: CLC-950302
Ron Kolde
Pacific Environmental Services
4700 Duke Drive
Suite 150
Mason, OH 45040
Dear Mr, Kolde:
This report contains the analytical results for the thirteen samples which were received under
chain of custody by Quanterra Incorporated on 18 August 1998. This sample set is associated
with your "S506.000" project.
The case narrative is an integral part of this report.
If you have any questions, please feel free to call.
Sincerely,
A
Patrick Rainey
Project Manager
Advanced Technology
PR/rr
-------
Environmental
Services
TABLE OF CONTENTS
QUANTERRA INCORPORATED PROJECT NUMBER 301036
Case Narrative
Quanterra's Quality Assurance Program
Sample Description Information
Chain of Custody Documentation
Polynuclcar Aromatic Hydrocarbons - Method HRGC/HRMS
Includes Sample(s): 1 through 13
Method Blank Sheets
Sample Data Sheets
Laboratory Control Sample
-------
Environmental
Services
CASE NARRATIVE
QUANTERRA INCORPORATED PROJECT NUMBER 301036
One cooler containing 1-L AGB's was received at 9 degrees. Sample B-8-M429-1 container 6
had some volume lost due to leaking in transit. Sample B-I-M429-3 had water leak into the
ziploc and the petri dish containing the filter.
Sample trains were prepared and analyzed hy a modified CARB 429 procedure. All fractions of
each train were combined for a single extract which was analyzed by HRGC/HRMS.
Detection limits for PAHs are reported on a sample specific basis and all results are recovery
corrected per the isotope dilution technique. For an analyte reported as 'Not Detected' the
associated detection limit represents its maximum possible concentration.
Results above the reporting limits for Naphthalene, 2-Methylnaphthalene, and Phenanthrene
were detected in the laboratory method blank associated with your samples. These analytes are
common artifacts of XAD-2 resin and ubiquitous ambient levels. As the observed concentrations
may be due to laboratory artifact, these results should be reviewed for significance. Positive
concentrations detected for these analytes in your samples are qualified with a "B" footnote on
the data sheets.
All reported results for samples "B-I-429-1", "B-I-429-2", and "B-I-429-3"are from analysis of
extracts diluted 10X due to high analyte levels and/or matrix interferences observed in the
analysis of the undiluted extract. The concentrations reported for Naphthalene and 2-
Methylnaphthalene in samples "B-U-429-2" and "B-U-429-3" are from analysis of extracts
diluted 10X due to concentrations in excess of the method calibration range for these analytes.
All other results are reported from analysis of undiluted extracts. There are some analytes in all
samples that exceed the upper method calibration range, however, in most cases the
concentration of these analytes are within the linear response range of the detector, and data
quality is not adversely affected. The affected analytes are qualified with an "E" footnote on the
data sheets.
-------
wuanterra
**
Environmental
Services
QUANTERRA INCORPORATED QUALITY CONTROL PROGRAM
Quanterra has implemented an extensive Quality Control (QC) program to ensure the production
of scientifically sound, legally defensible data of known documentable quality. This QC
program is based upon requirements in "Test Methods for Evaluating Solid Waste", USEPA
SW-846, Third Edition. It applies whenever SW-846 analytical methods are used. It also applies
in whole or in part whenever project requirements fail to specify some aspect of QC practices
described here. It does not apply when other well defined QC programs (e.g. CLP or CLP-like)
are specified. This is Quanterra's base QC program for environmental analysis.
Definitions:
Quality Control Batch. The quality control (QC) batch is a set of up to 20 field samples plus
associated laboratory QC samples that are similar in composition (matrix) and that are processed
within the same time period with the same reagent and standard lots.
Surrogate. A surrogate (or internal standard) is an organic compound similar hi chemical
behavior to the target analyte, but not normally found in environmental samples. Surrogates (or
IS) are added to all samples in a batch to monitor the effects of both the matrix and the analytical
process on accuracy.
Method Blank. A method blank (MB) is a control sample prepared using the same reagents used
for the samples. As part of the QC batch, it accompanies the samples through all steps of the
sample extraction and cleanup procedure. The method blank is used to monitor the level of
contamination introduced to a batch of samples as a result of processing hi the laboratory.
Laboratory Control Sample. A laboratory control sample (LCS) is prepared using a well
characterized matrix (e.g., reagent water or Ottawa sand) that is spiked with known amounts of
representative analytes. Alternate matrices (e.g., glass beads) may be used for soil analyses when
Ottawa sand is not appropriate. As part of a QC batch, it accompanies the samples through all
steps of the sample extraction and cleanup process. The LCS is used to monitor the accuracy of
the analytical process independent of possible interference effects due to sample matrix.
Duplicate Control Sample. A duplicate laboratory control sample (DCS) consists of a pair of
LCSs analyzed within the same QC batch to monitor precision and accuracy independent of
sample matrix effects.
-------
(guanterra
Environmental
Services
SAMPLE DESCRIPTION INFORMATION
for
Pacific Environmental Services
Lab ID
301036-
301036-
301036-
301036-
301036-
301036-
301036-
301036-
301036-
301036-
301036-
301036-
301036-
301036-
0001-SA
0001-MB
0002-SA
0003-SA
0004-SA
0005-SA
0006-SA
0007-SA
0008-SA
0009-SA
0010-SA
0011-SA
0012-SA
0013-SA
Client ID
B-l-429-1
Method Blank
B-I-429-2
B-I-429-3
B-0-429-1
B-0-429-2
B-0-429-3
B-U-429-1
B-U-429-2
B-U-429-3
B-I-429-FB
B-0-429-FB
B-U-429-FB
B-BLANKS-LAB
Matrix
AIRTRAIN
AIRTRAIN
AIRTRAIN
AIRTRAIN
AIRTRAIN
AIRTRAIN
AIRTRAIN
AIRTRAIN
AIRTRAIN
AIRTRAIN
AIRTRAIN
AIRTRAIN
AIRTRAIN
AIRTRAIN
Sampled
Date Time
11 AUG 98
11 AUG 98
12 AUG 98
13 AUG 98
11 AUG 98
12 AUG 98
13 AUG 98
14 AUG 98
14 AUG 98
15 AUG 98
14 AUG 98
14 AUG 98
15 AUG 98
15 AUG 98
Received
Date
18 AUG 98
18 AUG 98
18 AUG 98
18 AUG 98
18 AUG 98
18 AUG 98
18 AUG 98
18 AUG
18 AUG
18 AUG 98
18 AUG 98
18 AUG 98
18 AUG 98
18 AUG 98
98
98
-------
ANALYTICAL REQUEST AND CHAIN OF CUSTODY
RECOVERY
PERSON:
SAMPLE jJl
TECHNICIAN:
SAMPLE IDENTIFICATION
COLLECTION
DATE
TIME
SAMPLE NAME
NUMBER OF
CONTAINERS
ANALYTICAL REQUEST
COMMENTS
(Type ol contalnw,
B/tt/n
Y
7
7
8ti
i «.»-«.
-------
jttle Order and
iain of Custody
Quartterra Incorporated
1721 South Grand Avenue
Santa Ana, California 92705
714 258-8610 Direct
714 258-0921 Fax
Quanterra Incorporated
880 Riverside Parkway
West Sacraments, California 95605
916 3TS-5600 Direct
916 372-1059 Fax
uanteri
Emironm
Services
-302M
70 (VTTv. {?or-v k'oU-
w.^
-OQfr ^uka. dr ^uiL* \S£>
Nf^n, \ ' *^DH5
«»»«(» ^^ ^^ -TSScL
a^MBy ^^ ^f^ °^}'2^^
TB*"? TQ ^>,*lVtef>v^Scv^ |j'4»'^
Ship By i 1 Hrf 1 — I 1 — 1
1 \LabCourier {A Fed-Ex 1 I UPS 1 I Client Pick-up
Cottier ID Humberts)
*• iv*' i — i *nchjae rV K?" i — i
jA, Ice Chest I i Box IA Blue Ice \A^ Chain ol Custody 1 — 1 Seals
Container/Preservative
vriVOA
Til VOA/HCI
> m/ >lmfter G/ass Bottle
> ml Amber Glass/H2S04
> m/ /4mber Glass/HNO3
) ml Amber Glass/NaOH
Amber Glass Bottle
Amber Glass/H2SO4
J ml Poly
1mlPoly/HNO3
1ml Poly
J ml P/HN03
) m/ P/NaOH
7 ml P/ZnAc/NaOH
Poly
P/HN03
z Glass Jar
z Glass Jar
02 Glass Jar
3 Blank
Ol Bottle/Sterile
lipore H20
" Tflxfe (W)
Bottle Lot Numbers
No. of Containers
Reauested
^0
Analysis
\LO Y A \ 1
- \ -
>y Relinquished By (Signature)
fffkj/
Y/^Af.
f/b>*0fri'} • —
fj" f
Received By (Signature)
f&b &*£
Date
t/l/1/
' 1
Time
STRIBUTtON: WHITE - Client; CANARY - Bottle Prep; PINK-Client Folder
-------
Ill
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Parameter
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Pacific Environmental Services
Method Blank
301036-0001-MB
wuanterra
Environmental
Services
AIRTRAIN
18 AUG 98
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo
Benzo
Benzo
Benzo
fluoranthene
f 1 uoranthene
pyrene
pyrene
Perylene
Indenofl,2,3-cd)pyrene
Di benz(a,hj anthracene
Benzo(g, h, i)perylene
Surrogate
13C-Fluorene
Naphtha!ene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo[a)anthracene-d!2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Sampled: NA
Prepared: 19 AUG 98
Benzo
Benzo
Benzo
b)f1uoranthene-d!2
k»fluoranthene-d!2
a)pyrene-dl2
Dibenz(a,n)anthracene-dl4
Benzo(g,h,i)perylene-d!2
Result Units
Recovery
80
80
76
81
74
80
82
82
91
90
92
93
94
90
85
88
91
Received: NA
Analyzed: 26 AUG 98
Reporting
Limit
520
14
ND
ND
ND
24
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
._
--
0.46
7.6
6.5
--
1.4
6.4
3.1
0.17
0.53
0.30
0.14
0.19
0.12
0.079
0.31
0.13
0.37
ND - Not detected
NA = Not applicable
(continued on following page)
Reported By: Clark Pickell
Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
wttanterra
POLYNUCLEAR AROMATIC HYDROCARBONS c .
HIGH RESOLUTION GC/MS-(CONT.) Sernces
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: Method Blank
Lab ID: 301036-0001-MB
Matrix: AIRTRAIN Sampled: NA Received: NA
Authorized: 18 AUG 98 Prepared: 19 AUG 98 Analyzed: Z6 AUG 98
Note E : Concentration exceeds calibration range. Value is
estimated.
ND - Not detected
NA = Not applicable
Reported By: Clark Pickell Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Parameter
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Pacific Environmental Services
B-I-429-1
301036-0001-SA
AIRTRAIN Sampled: 11 AUG 98
18 AUG 98 Prepared: 19 AUG 98
Environmental
Services
Naphthalene
2-Methyl naphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo
Benzo
Benzo
Benzo
fluoranthene
fluoranthene
pyrene
pyrene
Perylene
Indeno(1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Surrogate
13C-Fluorene
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-d!2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Received: 18 AUG 98
Analyzed: 26 AUG 98
Benzofb
Benzofk'
Benzofa
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-d!2
Result
27000
7900
5500
690
2200
20000
730
14000
2200
910
5500
7500
3000
2000
620
100
2700
1100
2200
Recovery
87
90
69
85
84
96
109
107
105
90
93
101
104
99
90
90
91
Units
Re
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
BE
BE
E
BE
E
E
E
ND - Not detected
NA - Not applicable
(continued on following page)
Reported By: Clark Pickell
Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
(rjtuanterra
Environmental
POLYNUCLEAR AROMATIC HYDROCARBONS Serrices
HIGH RESOLUTION GC/MS (CONT.)
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: B-I-429-1
Lab ID: 301036-0001-SA
Matrix: AIRTRAIN Sampled: 11 AUG 98 Received: 18 AUG 98
Authorized: 18 AUG 98 Prepared: 19 AUG 98 Analyzed: 26 AUG 98
Note B : Compound is also detected in the blank.
Note E : Concentration exceeds calibration range. Value is
estimated.
ND = Not detected
NA = Not applicable
Reported By: Clark Pickell Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
wuanterra
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Parameter
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION SC/MS
Method HRGC/HRMS
Pacific Environmental Services
B-I-429-2
301036-0002-SA .
Environmental
Services
AIRTRAIN
18 AUG 98
Sampled: 12 AUG 98
Prepared: 19 AUG 98
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo
Benzo
Benzo
Benzo
fluoranthene
fluoranthene
pyrene
pyrene
Perylene
Indenofl,2,3-cd)pyrene
Dibenz(a,hjanthracene
Benzo(g,h,i)perylene
Surrogate
13C-Fluorene
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-d!2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo
Benzo
Benzo
b)fluoranthene-d!2
k)fluoranthene-d!2
a)pyrene-d!2
Dibenz(a,n)anthracene-dl4
Benzo(g,h,i)perylene-d!2
Result
35000
6800
5900
470
1800
25000
690
18000
2500
770
6000
8200
3100
1900
430
ND
2700
1100
2200
Recovery
90
69
57
72
67
87
93
90
98
81
82
92
100
87
82
81
83
Received: 18 AUG 98
Analyzed: 26 AUG 98
Units
Re
ng/s ample
ng/s ample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
BE
BE
E
BE
E
E
E
60
ND =* Not detected
NA = Not applicable
(continued on following page)
Reported By: Clark Pickell
Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
(jjtuanterra
POLYNUCLEAR AROMATIC HYDROCARBONS 1^
HIGH RESOLUTION GC/MS (CONT.)
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: B-I-429-2
Lab ID: 301036-0002-SA
Matrix: AIRTRAIN Sampled: 12 AUG 98 Received: 18 AUG 98
Authorized: 18 AUG 98 Prepared: 19 AUG 98 Analyzed: 26 AUG 98
Note B : Compound is also detected in the blank.
Note E : Concentration exceeds calibration range. Value is
estimated.
ND = Not detected
NA - Not applicable
Reported By: Clark Pickell Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Parameter
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Pacific Environmental Services
B-I-429-3
301036-0003-SA
AIRTRAIN Sampled: 13 AUG 98
18 AUG 98 Prepared: 19 AUG 98
wuanterra
Environmental
Services
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)ant hracene
Chrysene
fluoranthene
fluoranthene
pyrene
Benzo b
Benzo k'
Benzo
Benzo a)pyrene
Perylene
Indeno(1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g, h, i)perylene
Surrogate
13C-Fluorene
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
" "fluoranthene-d!2
fluoranthene-d!2
,pyrene-d!2
Dibenz(a,h)anthracene-d!4
Benzo(g,h,i)perylene-d!2
Received: 18 AUG 98
Analyzed: 26 AUG 98
Benzo
Benzo
Benzo
L '
iJ
Result
29000
3000
2600
530
1300
20000
640
6600
380
130
1900
2900
830
390
130
ND
450
240
320
Recovery
82
82
63
76
76
91
94
93
105
88
94
110
98
96
87
92
96
Reporting
Units Limit
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample 22
ng/sample
ng/sample
ng/sample
BE
B
BE
E
ND » Not detected
NA » Not applicable
(continued on following page)
Reported By: Clark Pickell
Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
Environmental
POLYNUCLEAR AROMATIC HYDROCARBONS Sente
HIGH RESOLUTION GC/MS (CONT.)
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: B-I-429-3
Lab ID: 301036-0003-SA
Matrix: AIRTRAIN Sampled: 13 AUG 98 Received: 18 AUG 98
Authorized: IB AUG 98 Prepared: 19 AUG 98 Analyzed: 26 AUG 98
Note B : Compound is also detected in the blank.
Note E : Concentration exceeds calibration range. Value is
estimated.
ND = Not detected
NA = Not applicable
Reported By: Clark Pickell Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
^uanterra
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Parameter
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION EC/MS
Method HRGC/HRMS
Pacific Environmental Services
B-0-429-1
301036-0004-SA
AIRTRAIN Sampled: 11 AUG 98
18 AUG 98 Prepared: 19 AUG 98
Environmental
Services
Received: 18 AUG 98
Analyzed: 26 AUG 98
Naphthalene
2-Methyl naphtha!ene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
fluoranthene
fluoranthene
Benzo
Benzo
Benzo e)pyrene
Benzo ajpyrene
Perylene
Indenofl,2,3-cd)pyrene
Di benz(a,h)anthracene
Benzo(g,h,i)perylene
Surrogate
13C-Fluorene
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a}anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo
Benzo
Benzo
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-d!2
Result
7800
1600
300
140
300
1200
84
480
280
55
110
73
68
48
48
11
63
14
140
Recovery
83
67
73
79
70
78
81
81
87
85
99
74
107
84
93
103
91
Units
Re
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
BE
BE
BE
ND - Not detected
NA = Not applicable
(continued on following page)
Reported By: Clark Pickell
Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
//"iianferra
Environmental
POLYNUCLEAR AROMATIC HYDROCARBONS Services
HIGH RESOLUTION GC/MS (CONT.)
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: B-0-429-1
Lab ID: 301036-0004-SA
Matrix: AIRTRAIN Sampled: 11 AUG 98 Received: 18 AUG 98
Authorized: 18 AUG 98 Prepared: 19 AUG 98 Analyzed: 26 AUG 98
Note B : Compound is also detected in the blank.
Note E : Concentration exceeds calibration range. Value is
estimated.
ND = Not detected
NA = Not applicable
Reported By: Clark Pickell Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Parameter
P0LYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION EC/MS
Method HRGC/HRMS
Pacific Environmental Services
B-0-429-2
301036-0005-SA
AlSTRAIN Sampled: 12 AUG 98
18 AUG 98 Prepared: 19 AUG 98
uanterra
Envinramentat
Services
Received: 18 AUG 98
Analyzed: 26 AUG §8
Naphthalene
2-Methylnaphtha!ene
Acenaphthyiene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
fluoranthene
fluoranthene
pyrene
pyrene
Benzo b
Benzo k
Benzo e
Benzo a
Peryl ene'
Indenofl,2,3~cd)pyrene
Di benz(a,h)anthracene
Benzo(g»h,i)perylene
Surrogate
13C-Fluorene
Naphtha!ene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-d12
Indeno(123-cd5pyrene-dl2
Chrysene-dl2
Benzol
Benzo(k
Benzola
fluoranthene-dl2
fluoranthene-d!2
pyrene-dI2
Dibenz(a,n}anthracene~dl4
Benzo{g,h,i)perylene-dl2
Result
9300
2500
280
120
270
970
38
240
180
43
140
63
32
33
27
13
30
ND
45
Recovery
81
65
73
(76
79
84
85
86
93
86
103
79
104
91
97
104
93
Units
Reporting
Limit
ng/saiple
ng/sample
ng/sample
ng/sample
ng/saraple
ng/sample
ng/saraple
ng/sample
ng/sample
ng/saraple
ng/smple
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
m
BE
BE
7.5
ND - Not detected
NA » Not applicable
(continued on following page)
Reported By: Clark Pickell
Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
'/uanterra
Environmental
POLYNUCLEAR AROMATIC HYDROCARBONS &»*»
HIGH RESOLUTION GC/MS (CONT.)
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: B-0-429-2
Lab ID: 301036-0005-SA
Matrix: AIRTRAIN Sampled: 12 AUG 98 Received: 18 AUG 98
Authorized: 18 AUG 98 Prepared: 19 AUG 98 Analyzed: 26 AUG 98
Note B : Compound is also detected in the blank.
Note E : Concentration exceeds calibration range. Value is
estimated.
ND « Not detected
NA = Not applicable
Reported By: Clark Pickell Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
it.
fs/uanterra
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Parameter
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Pacific Environmental Services
B-0-429-3
301036-0006-SA
Environmental
Services
AIRTRAIN
18 AUG 98
Sampled: 13 AUG 98
Prepared: 19 AUG 98
Received: 18 AUG 98
Analyzed: 26 AUG 98
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
fluoranthene
fluoranthene
pyrene
Benzo b
Benzo k
Benzo
Benzo a)pyrene
Perylene
Indenon, 2,3-cd) pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Surrogate
13C-Fluorene
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzofb
Benzofk,
Benzo(a
fluoranthene-d!2
fluoranthene-d!2
pyrene-dl2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-d!2
Result Units
Recovery
80
58
76
83
78
86
82
83
99
84
104
89
111
93
96
105
95
Reporting
Limit
9700
1700
340
97
200
630
20
150
96
23
63
38
25
24
20
ND
25
ND
64
ng/s ample
ng/s ample
ng/s ample
ng/s ample
ng/s ample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sampl e
ng/sample
ng/sample
..
__
.-
--
--
__
--
--
--
--
_.
--
__
_.
--
6.5
-_
5.1
--
BE
BE
BE
ND = Not detected
NA = Not applicable
(continued on following page)
Reported By: Clark Pickell
Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
tek
v/uanterra
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS (CONT.)
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: B-0-429-3
Lab ID: 301036-0006-SA
Matrix: AIRTRAIN Sampled: 13 AUG 98 Received: 18 AUG 98
Authorized: 18 AUG 98 Prepared: 19 AUG 98 Analyzed: Z6 AUG 98
Note B : Compound is also detected in the blank.
Note E : Concentration exceeds calibration range. Value is
estimated.
ND = Not detected
NA = Not applicable
Reported By: Clark Pickell Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
wuanterra
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Parameter
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Pacific Environmental Services
B-U-429-1
301036-0007-SA
AIRTRAIN Sampled: 14 AUG 98
18 AUG 98 Prepared: 19 AUG 98
Environmental
Services
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo
Benzol
Benzo
Benzo
k
fluoranthene
fluoranthene
pyrene
pyrene
Perylene
Indeno(1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Surrogate
13C-Fluorene
Naphthalene-da
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-d!2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Received: 18 AUG 98
Analyzed: 26 AUG 98
Benzo
Benzo
Benzo
b)fluoranthene-dl2
k)fluoranthene-d!2
a)pyrene-dl2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-dl2
Result
11000
5800
950
190
810
1600
51
430
170
45
120
76
50
42
47
12
44
12
81
Recovery
105
64
68
77
70
75
72
68
78
68
77
71
88
86
73
80
70
Units
Reporting
Limit
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
BE
BE
E
E
BE
ND = Not detected
NA = Not applicable
(continued on following page)
Reported By: Clark Pickell
Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
wuanterra
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS (CONT.)
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: B-U-429-1
Lab ID: 301036-0007-SA
Matrix: AIRTRAIN Sampled: 14 AUG 98 Received: 18 AUG 98
Authorized: 18 AUG 98 Prepared: 19 AUG 98 Analyzed: 26 AUG 98
Note B : Compound is also detected in the blank.
Note E : Concentration exceeds calibration range. Value is
estimated.
ND = Not detected
NA - Not applicable
Reported By: Clark Pickell Approved By: Mike Flournoy
jn integral
Rev 230787
The cover letter is an integral part of this report.
- -307"
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Parameter
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Pacific Environmental Services
B-U-429-2
301036-0008-SA
Environmental
Services
AIRTRAIN
18 AUG 98
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo
Benzo
Benzo
fluoranthene
fluoranthene
pyrene
Benzo a pyrene
Perylene
Indeno(l,2,3-cd}pyrene
Dibenz(a,h)anthracene
Benzo(g,n,i)perylene
Surrogate
13C-Fluorene
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Sampled: 14 AUG 98
Prepared: 19 AUG 98
Received: 18 AUG 98
Analyzed: 26 AUG 98
Benzofb
Benzo(k
Benzofa
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Dibenz(a,n)anthracene-dl4
Benzo(g,h,i)perylene-dl2
Result Units
Recovery
96
94
57
60
75
85
84
75
75
58
81
78
92
94
67
88
76
Reporting
Limit
31000
2000
290
110
230
730
20
220
80
25
59
45
31
32
24
ND
32
ND
78
ng/s ample
ng/sample
ng/s ample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sampl e
ng/sample
ng/sample
ng/sample
__
._
--
__
--
-.
--
--
__
_-
--
--
__
--
7.1
--
7.2
__
BED
BD
BE
ND = Not detected
NA = Not applicable
(continued on following page)
Reported By: Clark Pickell
Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
wuanterra
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS (CONT.)
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: B-U-429-2
Lab ID: 301036-0008-SA
Matrix: AIRTRAIN Sampled: 14 AUG 98 Received: 18 AUG 98
Authorized: 18 AUG 98 Prepared: 19 AUG 98 Analyzed: 26 AUG 98
Note B : Compound is also detected in the blank.
Note E : Concentration exceeds calibration range. Value is
estimated.
Note D : Compound quantitated using a secondary dilution.
ND = Not detected
NA * Not applicable
Reported By: Clark Pickell Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Parameter
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION 6C/MS
Method HRGC/HRMS
Pacific Environmental Services
B-U-429-3
301036-0009-SA
Environmental
Services
AIRTRAIN
18 AUG 98
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo
Benzo
Benzo
Benzo
b)
fluoranthene
fluoranthene
pyrene
pyrene
Perylene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h}anthracene
Benzo(g,h,i)perylene
Surrogate
13C-FTuorene
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dlZ
Benzofb)f1uoranthene-d!2
Benzo mfluoranthene-d!2
Benzo(a)pyrene-dl2
Dibenz(a,n}anthracene-dl4
Benzo(g,h,i)perylene-dl2
Sampled: 15 AUG 98
Prepared: 19 AUG 98
Received: 18 AUG 98
Analyzed: 26 AUG 98
Result Units
Recovery
93
121
60
44
74
83
85
78
82
64
79
76
95
91
75
88
74
Re
180000
8200
2600
450
1300
1700
86
620
220
72
160
64
39
34
32
ND
35
ND
63
ng/sample
ng/sample
ng/sample
ng/sampl e
ng/sampl e
ng/sampl e
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sampl e
ng/sample
ng/sample
ng/sampl e
ng/sample
ng/sample
ng/sample
__
--
--
--
--
._
--
._
__
__
_.
--
--
_.
--
9.7
--
8.6
--
BED
BED
E
E
E
BE
D
ND - Not detected
NA - Not applicable
Reported By: Clark Pickell
(continued on following page)
Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
[wuanterra
Environmental
POLYNUCLEAR AROMATIC HYDROCARBONS &«&«
HIGH RESOLUTION GC/MS (CONT.)
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: B-U-429-3
Lab ID: 301036-0009-SA
Matrix: AIRTRAIN Sampled: 15 AUG 98 Received: 18 AUG 98
Authorized: 18 AUG 98 Prepared: 19 AUG 98 Analyzed: 26 AUG 98
Note B : Compound is also detected in the blank.
Note E : Concentration exceeds calibration range. Value is
estimated.
Note D : Compound quantitated using a secondary dilution.
ND = Not detected
NA - Not applicable
Reported By: Clark Pickell Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Parameter
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Pacific Environmental Services
B-I-429-FB
301036-0010-SA
AIRTRAIN Sampled: 14 AUG 98
18 AUG 98 Prepared: 19 AUG 98
uanterra
Environmental
Services
Received: 18 AUG 98
Analyzed: 26 AUG 98
Naphthalene
2-Methylnaphthalene
Acenapnthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo
Benzo
Benzo
Benzo
b)fluoranthene
1 fluoranthene
pyrene
pyrene
Peryl ene
Indenon,2,3-cd)pyrene
Di benz(a , h) anthracene
Benzo (g,h,i) peryl ene
Surrogate
13C-F1 uorene
Naphthal ene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
"
Benzoi
Benzo
Benzo
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Di benz(a,h)anthracene-d!4
Benzo(g,h,i}perylene-d!2
Result
Recovery
94
85
65
74
72
81
95
97
99
86
92
99
104
94
81
99
89
Units
Re
1100
89
27
14
22
160
ND
78
29
13
23
18
15
13
14
ND
15
ND
41
ng/s ample
ng/s ample
ng/s ample
ng/sampl e
ng/s ample
ng/s ample
ng/s ample
ng/s ample
ng/sampl e
ng/s ample
ng/s ample
ng/s ample
ng/sampl e
ng/sampl e
ng/s ample
ng/s ample
ng/sampl e
ng/s ample
ng/sampl e
—
_.
_-
--
--
--
10
--
--
--
--
__
--
_.
--
3.6
_.
3.0
--
BE
B
BE
ND * Not detected
NA = Not applicable
(continued on following page)
Reported By: Clark Pickell
Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
§'uanterra
Environmental
POLYNUCLEAR AROMATIC HYDROCARBONS *»*»
HIGH RESOLUTION GC/MS (CONT.)
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: B-I-429-FB
Lab ID: 301036-0010-SA
Matrix: AIRTRAIN Sampled: 14 AUG 98 Received: 18 AUG 98
Authorized: 18 AUG 98 Prepared: 19 AUG 98 Analyzed: 26 AUG 98
Note B : Compound is also detected in the blank.
Note E : Concentration exceeds calibration range. Value is
estimated.
ND - Not detected
NA = Not applicable
Reported By: Clark Pickell Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
Aianferra
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Parameter
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Pacific Environmental Services
B-0-429-FB
301036-0011-SA
AIRTRAIN Sampled: 14 AUG 98
18 AUG 98 Prepared: 19 AUG 98
Environmental
Services
Received: 18 AUG 98
Analyzed: 26 AUG 98
Naphthalene
2-Methylnaphthalene
Acenaphthy1ene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
fluoranthene
fluoranthene
pyrene
pyrene
Benzo
Benzo
Benzo
Benzo
Perylene
IndenoU,2,3-cd)pyrene
Di benz(a,h)anthracene
Benzo(g,h, i)perylene
Surrogate
13C-Fluorene
Naphthalene-dS
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo
Benzo
Benzo
fluoranthene-d!2
fluoranthene-d!2
pyrene-d!2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-d!2
Result
Recovery
94
83
66
(73
75
81
92
93
90
86
96
89
96
99
84
102
93
Units
Re
620
76
ND
41
22
130
ND
44
54
11
17
15
12
11
12
ND
12
ND
37
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/ sample
ng/sample .
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
--
--
9.2
--
__
--
7.9
--
-_
_.
__
--
--
..
2.8
--
2.5
--
BE
B
ND = Not detected
NA = Not applicable
(continued on following page)
Reported By: Clark Pickell
Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
^uanterra
Environmental
POLYNUCLEAR AROMATIC HYDROCARBONS Services
HIGH RESOLUTION GC/MS (CONT.)
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: B-0-429-FB
Lab ID: 301036-0011-SA
Matrix: AIRTRAIN Sampled: 14 AUG 98 Received: 18 AUG 98
Authorized: 18 AUG 98 Prepared: 19 AUG 98 Analyzed: 26 AUG 98
Note B : Compound is also detected in the blank.
Note E : Concentration exceeds calibration range. Value is
estimated.
ND * Not detected
NA * Not applicable
Reported By: Clark Pickell Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 23?—
-------
wuanterra
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Parameter
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRMS
Pacific Environmental Services
B-U-4Z9-FB
301036-0012-SA
Environmental
Services
AIRTRAIN
18 AUG 98
Sampled: 15 AUG 98
Prepared: 19 AUG 98
Received: 18 AUG 98
Analyzed: 26 AUG 98
Naphthalene
2-Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
b)
fluoranthene
fluoranthene
pyrene
pyrene
Benzo
Benzo
Benzo
Benzo
Perylene'
IndenoU, 2,3-cd) pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
Surrogate
13C-Fluorene
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Perylene-dl2
Indeno(123-cd)pyrene-dl2
Chrysene-dl2
Benzo
Benzo
Benzo
b)fluoranthene-d!2
k)fluoranthene-dl2
(a)pyrene-dl2
Dibenz(a,n)anthracene-dl4
Benzo(g,h,i)perylene-dl2
Reporting
Result Units Limit
2900
840
280
97
140
370
25
97
58
18
30
21
15
12
13
ND
13
ND
32
ng/sample
ng/sample
ng/sampl e
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
ng/sample
--
--
--
__
-_
.-
..
..
--
--
--
__
..
--
--
2.6
__
2.9
--
Recovery
93
74
69
74
74
83
96
97
93
87
91
92
93
101
83
91
86
%
%
%
BE
BE
BE
ND = Not detected
NA - Not applicable
(continued on following page)
Reported By: Clark Pickell
Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
^uanterra
Environmental
POLYNUCLEAR AROMATIC HYDROCARBONS Se™ces
HIGH RESOLUTION GC/HS (CONT.)
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: B-U-429-FB
Lab ID: 301036-0012-SA
Matrix: AIRTRAIN Sampled: 15 AUG 98 Received: 18 AUG 98
Authorized: 18 AUG 98 Prepared: 19 AUG 98 Analyzed: 26 AUG 98
Note B : Compound is also detected in the blank.
Note E : Concentration exceeds calibration range. Value is
estimated.
ND = Not detected
NA - Not applicable
Reported By: Clark Pickell Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
wuanterra
Client Name:
Client ID:
Lab ID:
Matrix:
Authorized:
Parameter
POLYNUCLEAR AROMATIC HYDROCARBONS
HIGH RESOLUTION GC/MS
Method HRGC/HRHS
Pacific Environmental Services
B-BLANKS-LAB
301036-0013-SA
AIRTRAIN Sampled: 15 AUG 98
18 AUG 98 Prepared: 19 AUG 98
Environmental
Services
Benzo
Benzo
Benzo
Benzo
b
i.
Naphthalene
2-Methyl naphtha! ene
Acenaphthyiene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a) anthracene
Chrysene
fluoranthene
fluoranthene
pyrene
pyrene
Peryl ene
Indeno(l,2,3-cd) pyrene
Dibenz(a,h| anthracene
Benzo (g , h , i ) peryl ene
Surrogate
13C-Fluorene
Naphtha! ene-d8
Acenaphthylene-d8
Acenaphthene-dlO
Fluorene-dlO
Phenanthrene-dlO
Fluoranthene-dlO
Pyrene-dlO
Benzo(a)anthracene-dl2
Peryl ene-d!2
Indeno(123-cd)pyrene-dlZ
Chrysene-dl2
" '
Received: 18 AUG 98
Analyzed: 26 AUG 98
Benzo
Benzo
Benzo
i '
fluoranthene-d!2
fluoranthene-dl2
pyrene-d!2
Dibenz(a,h)anthracene-dl4
Benzo(g,h,i)perylene-dl2
Result
Recovery
108
59
57
64
60
64
65
67
66
66
67
68
69
74
66
68
64
Units
Reporting
Limit
650
230
ND
79
73
380
21
44
21
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ng/sampl e
ng/sampl e
ng/sampl e
ng/sampl e
ng/s ample
ng/sampl e
ng/sampl e
ng/s ample
ng/sampl e
ng/s ample
ng/sampl e
ng/sampl e
ng/sampl e
ng/sampl e
ng/sampl e
ng/sampl e
ng/sampl e
ng/sampl e
ng/s ample
--
--
9.2
--
--
--
--
--
--
1.4
4.3
2.8
1.8
1.6
1.2
0.26
1.3
0.26
2.5
BE
B
ND « Not detected
NA - Not applicable
(continued on following page)
Reported By: Clark Pickell
Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
Environmental
POLYNUCLEAR AROMATIC HYDROCARBONS &**»
HIGH RESOLUTION GC/MS (CONT.)
Method HRGC/HRMS
Client Name: Pacific Environmental Services
Client ID: B-BLANKS-LAB
Lab ID: 301036-0013-SA
Matrix: AIRTRAIN Sampled: 15 AUG 98 Received: 18 AUG 98
Authorized: 18 AUG 98 Prepared: 19 AUG 98 Analyzed: 26 AUG 98
Note B : Compound is also detected in the blank.
Note E : Concentration exceeds calibration range. Value is
estimated.
ND = Not detected
NA = Not applicable
Reported By: Clark Pickell Approved By: Mike Flournoy
The cover letter is an integral part of this report.
Rev 230787
-------
^uanterra
Environmental
Services
ABORATORY CONTROL SAMPLE REPORT
dvanced Technology Group - High Resolution
reject: 301036
ategory: PAH-HR-AIR PAH by HRGC/HRMS
est: PAH-HR-AIR
atrix: AIR
C Lot: 19 AUG 98-B
oncentration Units: ng/sample
nalyte
aphthalene
-Methylnaphthalene
cenapnthylene
cenaphthene
luorene
henanthrene
nthracene
luoranthene
yrene
enzo(a)anthracene
hrysene
f1uoranthene
fluoranthene
pyrene
enzo
enzo k
enzo elpyrene
enzo a)pyrene
erylene
ndeno(l,2,3-cd)pyrene
ibenz(a,hjanthracene
enzo(g,h,i)perylene
aphtha!ene-d8
cenaphthylene-d8
cenaphthene-dlO
luorene-dlO
henanthrene-dlO
luoranthene-dlO
yrene-dlO
enzo(a)anthracene-d!2
hrysene-dlZ
enzoCb
enzofk'
enzo(a
fluoranthene-dl2
fluoranthene-d!2
pyrene-d!2
erylene-d!2
ndenon23-cd)pyrene-dl2
i benz(a,h)anthracene-d14
enzo(g,h,i)perylene-dl2
QC Run: 26 AUG 98-A
Concentration
Spiked Measured
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
100
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
50
110
100
110
110
120
110
110
110
110
100
100
110
110
120
100
87
99
110
100
33
31
33
31
33
38
39
46
51
48
45
42
41
48
45
49
Accuracy (%)
LCS Limits
107
102
114
112
117
110
113
115
113
103
102
108
111
124
104
87
99
111
104
67
61
66
62
65
76
79
92
102
95
91
83
83
96
91
97
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
alculations are performed before rounding to avoid round-off errors in calculated results.
-------
sr, Analytics Division
Laboratory Corporation of America® Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No. C236091
Account No. 34419005
Report Date: 08/31/98
KOLDE
IFIC ENVIRONMENTAL SERVICES
SCHEFFEL
0 DUKE DRIVE SUITE 150
3N, OH 45040
Final Report
s Received: 08/24/98
pie Type.- 14 - Air Sample (s)
ject: EPA COKE-BTHLHM ST
lytical Results
Client ID
Parameter
PO Number: 103-99-322
Volume Amount
Concent rat i on
1 B-I-5506-1
Samp Date: 08/11/98 XAD-2
Acnapth-Front < 5.0 ug
Acnapth-Rear ND
Acnapht-Total NVG < 5.0 ug
Acnthy-Front < 5.0 ug
Acnthy-Rear ND
Acnthy-Total NVG < 5.0 ug
Anthr-Front < 1.0 ug
Anthr-Rear ND
Anthr-Total NVG < 1.0 ug
Bz(a)ant-Front < 1.0 ug
Bz(a)ant-Rear ND
Bz(a)ant-Total NVG < 1.0 ug
Bz(a)pyr-Front < 1.0 ug
Bz(aipyr-Rear ND
Bz(a)pyr-Total NVG < 1.0 ug
Bz(b)fnt-Front < 1.0 ug
Bz(b)fnt-Rear ND
Bz{b)fnt-Total NVG < 1.0 ug
Bzpery-Front < 1.0 ug
Bzpery-Rear ND
Bzpery-Total NVG < 1.0 ug
Bz(k)fnt-Front < 1.0 ug
Bz(k)fnt-Rear ND
Bz(k)fnt-Total NVG < 1.0 ug
Chy-Front < 1.0 ug
Page 1
-------
&. Analytics Division
Laboratory Corporation of America® Holdings
PO Box 25243
Richmond, Virginia Z326Q
Telephone: 300-8B8-8DB1
Group No. C23S091
Account No. 34419005
Report Date: 08/31/98
KOLDE
:FIC ENVIRONMENTAL SERVICES
SCHEFFEL
i DUKE DRIVE SUITE 150
IN, OH 45040
Final Report
s Received: 08/24/98
tie Type: 14 - Air Sample(s)
ect: EPA COKE-BTHLHM ST
.ytical Results
PO Number: 103-99-322
Client ID Parameter
Chy-Rear
Chy-Total
Db zan thr - Front
Dbzanthr-Rear
Dbzanthr-Total
F 1 anthr - F ront
Flanthr-Rear
Flanthr-Total
F luor ene - Front
Fluorene-Rear
Fluorene- Total
Indpyene - Front
Indpyene - Re ar
Indpyene -Total
Nap th- Front
Nap th- Rear
Nap th- Total
P anthr -Front
Panthr-Rear
Panthr- Total
Pyr ene -Front
Pyrene-Rear
Pyrene- Total
Volume
NVG
NVG
NVG
NVG
NVG
NVG
NVG
NVG
Amount
ND
c 1.0 ug
< 1.0 ug
ND
< 1.0 ug
< 5.0 ug
ND
< 5.0 ug
< 5.0 ug
ND
< 5.0 ug
< 1.0 ug
ND
< 1.0 ug
< 5.0 ug
ND
< 5.0 ug
1.88 ug
ND
1.88 ug
< 1.0 ug
ND
< 1.0 ug
Concentration
— __
__ __
__ __
__ __
__ __
__ __
__ —
— —
I B-I-5506-2
Samp Date: 08/12/98 XAD-2
Acnapth-Front
Acnapth-Rear
Page 2
< 5.0 ug
ND
-------
h Analytics Division
Laboratory Corporation of America® Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-8B8-8Q61
Group No. C236091
Account No. 34419005
Report Date: 08/31/98
KOLDE
IFIC ENVIRONMENTAL SERVICES
SCHEFFEL
) DUKE DRIVE SUITE 150
)N, OH 45040
Final Report
; Received: 08/24/98
jle Type: 14 - Air Sample(s)
ject: EPA COKE-BTHLHM ST
Lytical Results
Client ID
Parameter
PO Number: 103-99-322
Volume Amount
Concentration
Acnapht - To t a 1
Acnthy- Front
Acnthy-Rear
Acnthy- Total
Anthr- Front
Anthr-Rear
Anthr-Total
Bz (a) ant -Front
Bz (a) ant -Rear
Bz (a) ant-Total
Bz (a) pyr-Front
Bz (a)pyr-Rear
Bz (a)pyr-Total
Bz(b)fnt- Front
Bz(b)fnt-Rear
Bz (b) fnt-Total
B zpery- Front
Bzpery-Rear
Bzpery-Total
Bz{k)fnt~ Front
Bz (k) fnt-Rear
Bz(k) fnt-Total
Chy- Front
Chy-Rear
Chy-Total
Dbzanthr- Front
Dbzanthr-Rear
NVG
NVG
NVG
NVG
NVG
NVG
NVG
NVG
NVG
<5.0ug - - - -
< 5.0 ug
ND
<5.0ug __-_
< 1.0 ug
ND
< 1 . 0 ug ----
< 1.0 ug
ND
<1.0ug _--_
< 1.0 ug
ND
< 1.0 ug ____
< 1.0 ug
ND
< 1.0 ug - - - -
< 1.0 ug
ND
< 1.0 ug ----
< 1.0 ug
ND
< 1 . 0 ug __--
< 1.0 ug
ND
< 1 . 0 ug - - - -
< 1.0 ug
ND
Page 3
-------
d?i Analytics Division
Laboratory Corporation of America® Holdings
PO Box 2524S
Richmond, Virginia 23260
Telephone: 8DO-888-8061
Group No. C236091
Account No. 34419005
Report Date: 08/31/98
KOLDE
[FIG ENVIRONMENTAL SERVICES
SCHEFFEL
I DUKE DRIVE SUITE 150
)N, OH 4504D
Final Report
j Received: 08/24/98
jle Type: 14 - Air Sample(s)
ject: EPA COKE-BTHLHM ST
.ytical Results
PO Number: 103-99-322
Client ID Parameter Volume
Dbzanthr-Total NVG
Flanthr- Front
Flanthr-Rear
Flanthr-Total NVG
Fluorene- Front
Fluorene-Rear
Fluorene-Total NVG
Indpyene - Front
Indpyene-Rear
Indpyene -Total NVG
Nap th- Front
Nap th- Rear
Napth-Total NVG
Panthr-Front
Panthr-Rear
Panthr-Total NVG
Pyrene -Front
Pyrene-Rear
Pyrene - To t al NVG
B-I-5506-3 Samp Date: 08/13/98 XAD-2
Acnapth- Front
Acnapth-Rear
Acnapht -Total NVG
Acnthy- Front
Acnthy-Rear
Acnthy-Total NVG
Page 4
Amount Concentration
< 1.0 ug --_-
< 5.0 ug
ND
<5.0ug - - - -
< 5.0 ug
ND
<5.0ug --_-
< 1.0 ug
ND
< 1 . 0 ug - _ _ _
6.01 ug
ND
6 .01 ug __ __
3.15 ug
ND
3.15 ug -- --
< 1.0 ug
ND
< 1.0 ug --__
< 5.0 ug
ND
<5.0ug - - - -
< 5.0 ug
ND
< 5.0 ug - - - -
-------
* Analytics Division
Laboratory Corporation of America® Holdings
PO Bex 25249
Richmond, Virginia 23Z60
Telephone: 800-888-8061
Group No,
Account No.
Report Date:
C236091
34419005
OB/31/98
KOLDE
[FIG ENVIRONMENTAL SERVICES
SCHEFFEL
I DUKE DRIVE SUITE 150
)N, OH 45040
Final Report
; Received: 08/24/98
)le Type: 14 - Air Sample (s)
ject: EPA COKE-BTHLHM ST
.ytical Results
Client ID
Parameter
PO Number: 103-99-322
Volume Amount
Concentration
Anthr- Front
Anthr-Rear
Anthr-Total
Bz (a) ant -Front
Bz (a) ant-Rear
Bz (a) ant-Total
Bz (a)pyr-Front
Bz (a)pyr-Rear
Bz (a)pyr-Total
Bz (b) fnt-Front
Bz (b) fnt-Rear
Bz(b)fnt-Total
Bzpery- Front
Bzpery-Rear
Bzpery- Total
Bz (k.) fnt-Front
Bz (k) fnt-Rear
Bz (k) fnt-Total
Chy- Front
Chy-Rear
Chy-Total
Dbzanthr-Front
Dbzanthr-Rear
Dbzanthr-Total
Flanthr- Front
Flanthr-Rear
Flanthr-Total
NVG
NVG
NVG
NVG
NVG
NVG
NVG
NVG
NVG
< 1.0 ug
ND
< 1.0 ug -- --
< 1.0 ug
ND
<1.0ug __-_
< 1.0 ug
ND
< 1 . 0 ug - _ - -
< 1.0 ug
ND
< i.o ug - - - -
< l.o ug
ND
< 1 . 0 ug - - - _
< 1 . 0 ug
ND
-------
r. Analytics Division
Laboratory Corporation of America® Holdings
PO Box 25249
Richmond, Virginia 232BD
Telephone: 800-B88-BOB1
Group No. C236091
Account No. 34419005
Report Date: 08/31/98
KOLDE
:FIC ENVIRONMENTAL SERVICES
SCHEFFEL
) DUKE DRIVE SUITE 150
)N, OH 45040
Final Report
2 Received: 08/24/98
Die Type: 14 - Air Sample(s)
)ect: EPA COKE-BTHLHM ST
Lytical Results
Client ID
Parameter
PO Number: 103-99-322
Volume Amount
Concentration
Fluorene-Front
Fluorene-Rear
Fluorene-Total
Indpyene - Front
Indpyene-Rear
Indpyene-Total
Nap th- Front
Napth-Rear
Napth-Total
Panthr- Front
Panthr-Rear
Panthr-Total
Py r ene - Front
Pyrene-Rear
Pyrene-Total
NVG
NVG
NVG
NVG
NVG
< 5.0 ug
ND
<5.0ug _-__
< 1.0 ug
ND
< 1.0 ug --_-
< 5.0 ug
ND
<5.0ug ----
< 1.0 ug
ND
< 1 . 0 ug - - - -
< 1.0 ug
ND
< 1 . 0 ug ---_
4 B-O-5506-1 Samp Date: 08/11/98 XAD-2
Acnapth-Front
Acnapth-Rear
NVG
Acnapht-Total
Acnthy-Front
Acnthy-Rear
Acnthy-Total
Anthr-Front
Anthr-Rear
Anthr-Total
Bz{a) ant-Front
NVG
NVG
< 5.0 ug
ND
< 5.0 ug
< 5.0 ug
ND
< 5.0 ug
< 1.0 ug
ND
< 1.0 ug
< 1.0 ug
Page 6
-------
- Analytics Division
Laboratory Corporation of America® Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No.
Account No.
Report Date;
C236091
34419005
08/31/98
KOLDE
FIC ENVIRONMENTAL SERVICES
SCHEFFEL
i DUKE DRIVE SUITE 150
>N, OH 45040
Final Report
j Received: 08/24/98
>le Type; 14 - Air Sample(s)
iect: EPA COKE-BTHLHM ST
.ytical Results
PO Number: 103-99-322
Client ID Parameter Volume
Bz (a) ant -Rear
B2 (a) ant -Total NVG
Bz (a) pyr- Front
Bz (a)pyr-Rear
Bz(a)pyr-Total NVG
Bz(b)fnt-Front
Bz (b) fnt-Rear
Bz (b) f nt-Total NVG
Bzpery- Front
Bzpery-Rear
Bzpery-Total NVG
Bz(k)fnt -Front
Bz (k) fnt-Rear
Bz (k) f nt-Total NVG
Chy- Front
Chy-Rear
Chy-Total NVG
Dbzanthr-Front
Dbzanthr-Rear
Dbzanthr-Total NVG
Flanthr- Front
Flanthr-Rear
Flanthr-Total NVG
F luor ene - Front
Fluorene -Rear
Fluorene-Total NVG
Indpyene - Front
Page 7
Amount Concentration
ND
< 1 . 0 ug ----
< i.o ug
ND
cl.Oug ---_
< 1.0 ug
ND
<1 C\ 1 IfT — ™
j- « u uy
< 1.0 ug
ND
< 1 . 0 ug ---_
< 1.0 ug
ND
< 1 . 0 ug - - - -
< 1.0 ug
ND
< 1.0 ug - -
< 1.0 ug
ND
< 1 . 0 ug - - - _
< 5.0 ug
ND
<5.0ug ----
< 5.0 ug
ND
<5.0ug ----
< i.o ug
-------
^S: Analytics Division
Laboratory Corporation of America® Holdings
PO Box 25249
Richmond, Virginia 23260
Telephones: 800-888-8061
Group No. C236091
Account No. 34419005
Report Date: 08/31/98
KOLDE
CFIC ENVIRONMENTAL SERVICES
SCHEFFEL
) DUKE DRIVE SUITE 150
DN, OH 45040
Final Report
s Received: 08/24/98
>le Type: 14 - Air Sample(s)
ject: EPA COKE-BTHLHM ST
Lytical Results
Client ID
Parameter
PO Number: 103-99-322
Volume Amount
Concentration
Indpyene-Rear
Indpyene-Total
Napth- Front
Napth-Rear
Napth-Total
Panthr- Front
Panthr-Rear
Panthr- Total
Pyrene- Front
Pyrene-Rear
Pyrene -Total
NVG
NVG
NVG
NVG
ND
< l.O ug
< 5.0 ug
ND
< 5.0 ug
< 1.0 ug
ND
< 1.0 ug
< 1.0 ug
ND
< 1.0 ug
__ __
__ __
__ __
** ug/M3
B-O-550S-2 Samp Date: 08/12/98 XAD-2
Acnapth-Front
Acnapth-Rear
Acnapht -Total
Acnthy- Front
Acnthy-Rear
Acnthy- Total
Ant hr- Front
Anthr-Rear
Anthr-Total
Bz (a) ant-Front
Bz (a) ant-Rear
Bz (a) ant-Total
Bz (a) pyr-Front
Bz (a)pyr-Rear
NVG
NVG
NVG
NVG
< 5.0 ug
ND
< 5.0 ug
< 5.0 ug
ND
< 5.0 ug
< 1.0 ug
ND
< 1.0 ug
< 1.0 ug
ND
< 1.0 ug
< 1.0 ug
ND
-- --
__ __
-- --
__ __
Page 8
-------
r. Analytics Division
Laboratory Corporation of America® Holdings
PO Box 25249
Richmond, Virginia 232BO
Telephone: 800-888-8061
Group No. C236091
Account No, 34419005
Report Dates 08/31/98
KOLDE
:FIC ENVIRONMENTAL SERVICES
SCHEFFEL
) DUKE DRIVE SUITE 150
)N, OH 45040
Final Report
j Received: 08/24/98
>le Type: 14 - Air Sample(s)
ject; EPA COKE-BTHLHM ST
^ytical Results
Client ID
Parameter
PO Number: 103-99-322
Volume Amount
Concentrat ion
Bz (a)pyr-Total
Bz(b)fnt- Front
Bz (b) fnt-Rear
Bz(b)fnt -Total
Bzpery-Front
Bzpery-Rear
Bzpery-Total
Bz(k)fnt- Front
Bz (k) fnt-Rear
Bz(k)fnt-Total
Chy- Front
Chy-Rear
Chy-Total
Dbzanthr- Front
Dbzanthr-Rear
Dbzanthr-Total
F 1 anthr - Front
Flanthr-Rear
Flanthr-Total
Fluorene - Front
Fluorene-Rear
Fluorene-Total
Indpyene - Front
Indpyene-Rear
Indpyene - Tot a 1
Napth- Front
Napth-Rear
NVG
NVG
NVG
NVG
NVG
NVG
NVG
NVG
NVG
< 1 . 0 ug _-__
< 1.0 ug
ND
< 1 . 0 ug - - - -
< l.O ug
ND
< 1 . 0 ug _-__
< 1.0 ug
ND
< 1 . 0 ug _--_
< i.o ug
ND
< 1 . 0 ug - - - -
< 1.0 ug
ND
< 1 . 0 ug _ - - -
< 5.0 ug
ND
< 5.0 ug - -
< 5.0 ug
ND
<5.0ug - - - -
< 1,0 ug
ND
< 1 . 0 ug ____
< 5.0 ug
ND
Page 9
-------
*isl-. Analytics Division
Laboratory Corporation of America® Holdings
PO Box 25249
Richmond, Virginia 232EO
Telephone: 800-888-8061
Group No. C236091
Account No. 34419005
Report Date: 08/31/98
KOLDE
FIG ENVIRONMENTAL SERVICES
SCHEFFEL
DUKE DRIVE SUITE 150
)N, OH 45040
Final Report
; Received: 08/24/98
»le Type: 14 - Air Sample (s)
ect: EPA COKE-BTHLHM ST
.ytical Results
Client ID
Parameter
PO Number: 103-99-322
Volume Amount
Concentration
Napth- Total
Panthr- Front
Panthr-Rear
Panthr -Total
Pyrene- Front
Pyrene-Rear
Pyrene -Total
NVG
NVG
NVG
< 5.0 ug - - - -
< 1.0 ug
ND
<1.0ug _-__
< 1.0 ug
ND
< 1.0 ug ** ug/M3
J B-O-5506-3 Samp Date: 08/13/98 XAD-2
Acnapth- Front
Acnapth-Rear
Acnapht -Total
Acnthy- Front
Acnthy-Rear
Acnthy-Total
Anthr- Front
Anthr-Rear
Anthr-Total
Bz (a) ant -Front
Bz (a) ant -Rear
Bz (a) ant-Total
Bz(a)pyr-Front
Bz(a)pyr-Rear
Bz(a)pyr-Total
Bz (b) fnt-Front
Bz (b) fnt-Rear
Bz(b)fnt-Total
Page
NVG
NVG
NVG
NVG
NVG
NVG
10
< 5.0 ug
ND
<5.0ug - - - -
< 5.0 ug
ND
<5.0ug ----
< 1.0 ug
ND
< 1.0 ug - - - -
< 1.0 ug
ND
< 1 . 0 ug ----
< 1.0 ug
ND
< 1 . 0 ug _--_
< 1.0 ug
ND
< 1.0 ug ----
-------
£r Analytics Division
Laboratory Corporation of America® Holdings
PQ Box 25249
Richmond, Virginia Z32BO
Telephone: 8QO-B8B-8061
Group No. C236091
Account No. 34419005
Report Date: 08/31/98
KOLDE
'.PIC ENVIRONMENTAL SERVICES
SCHEFFEL
) DUKE DRIVE SUITE 150
)N, OH 45040
Final Report
i Received: 08/24/98
3le Type: 14 - Air Sample(s)
ject: EPA COKE-BTHLHM ST
Lytical Results
Client ID
Parameter
PO Number: 103-99-322
Volume Amount
Concentration
Bzpery- Front
Bzpery-Rear
Bzpery- Total
Bz(k)fnt-Front
Bz(k) fnt-Rear
Bz(k)fnt-Total
Chy- Front
Chy- Rear
Chy- Total
Db z anthr - Fr ont
Dbzanthr-Rear
Dbzanthr-Total
Flanthr-Front
Flanthr-Rear
Flanthr-Total
Fluorene - Front
Fluorene-Rear
Fluorene-Total
Indpyene - Front
Indpyene -Rear
Indpyene - Tot al
Napth- Front
Napth-Rear
Napth- Total
Panthr- Front
Panthr-Rear
Panthr-Total
Page
NVG
NVG
NVG
NVG
NVG
NVG
NVG
NVG
NVG
11
< 1.0
ND
< 1.0
< 1.0
ND
< 1.0
< 1.0
ND
< 1.0
< 1.0
ND
< 1.0
< 5.0
ND
< 5.0
< 5.0
ND
< 5.0
< 1.0
ND
< 1.0
< 5.0
ND
< 5.0
< 1.0
ND
< 1.0
ug
ug -- --
ug
ug -- --
ug
ug -- --
ug
ug -- --
ug
ug -- --
ug
ug
ug
ug -- --
ug
ug
ug
ug -- --
-------
S- Analytics Division
Laboratory Corporation of America® Holdings
PC Box 25249
Richmond, Virginia 23260
Telephone: 800-B88-80B1
Group No. C236091
Account No. 34419005
Report Date: 08/31/98
KOLDE
IFIC ENVIRONMENTAL SERVICES
SCHEFFEL
) DUKE DRIVE SUITE 150
)N, OH 45040
Final Report
; Received: 08/24/98
)le Type: 14 - Air Sample(s)
iect: EPA COKE-BTHLHM ST
PO Number:
103-99-322
.ytical Results
Client ID
Parameter
Volume Amount
Concentration
Pyrene-Front
Pyrene-Rear
Pyrene -Total
NVG
< 1.0 ug
ND
< 1.0 ug ** ug/M3
7 B-V-5506-1 Samp Date: 08/14/98 XAD-2
Acnapth-Front
Acnapth-Rear
Acnapht -Total
Acnthy- Front
Acnthy-Rear
Acnthy- Total
Anthr- Front
Anthr-Rear
Anthr-Total
Bz (a) ant -Front
Bz (a) ant-Rear
Bz (a) ant -Total
Bz (a)pyr-Front
Bz (a)pyr-Rear
Bz (a)pyr-Total
Bz(b)fnt~Front
Bz (b) fnt-Rear
Bz (b) fnt-Total
Bzpery- Front
Bzpery-Rear
Bzpery- Total
Bz(k)fnt- Front
Page
NVG
NVG
NVG
NVG
NVG
NVG
NVG
12
< 5.0 ug
ND
•c 5 . 0 ug _--_
< 5.0 ug
ND
<5.0ug - - - -
< 1.0 ug
ND
< 1 . o ug _--_
< l.O ug
ND
< 1 . 0 ug - - - -
< 1.0 ug
ND
< 1 . 0 ug _-__
< 1.0 ug
ND
< 1 . 0 ug _--_
< 1.0 ug
ND
< 1 . 0 ug ----
< 1.0 ug
-------
zr. Analytics Division
Laboratory Corporation of America® Holdings
PO Box 25249
Richmond, Virginia 232GO
Telephone: 8DO-B88-6061
Group No. C236091
Account No. 34419005
Report Date: 08/31/98
KOLDE
',FIC ENVIRONMENTAL SERVICES
SCHEFFEL
I DUKE DRIVE SUITE ISO
>N, OH 45040
Final Report
5 Received; 08/24/98
jle Type: 14 - Air Sample(s)
ject: EPA COKE-BTHLHM ST
.ytical Results
Client ID
Parameter
PO Number: 103-99-322
Volume Amount
Concentration
Bz (k) fnt-Rear
BzUOfnt- Total
Chy- Front
Chy-Rear
Chy-Total
Dbzanthr-Front
Dbzanthr-Rear
Dbzanthr-Total
Flanthr- Front
Flanthr-Rear
Flanthr-Total
Fluorene- Front
Fluorene-Rear
Fluorene -Total
Indpyene - Front
Indpyene -Rear
Indpyene-Total
Napth- Front
Nap th- Rear
Napth-Total
Panthr- Front
Panthr-Rear
Panthr-Total
Pyrene - Front
Pyrene-Rear
Pyrene-Total
NVG
NVG
NVG
NVG
NVG
NVG
NVG
NVG
NVG
ND
< 1.0
< 1.0
ND
< 1.0
< 1.0
ND
< 1.0
< 5.0
ND
< 5.0
< 5.0
ND
< 5.0
< 1.0
ND
< 1.0
< 5.0
ND
< 5.0
< 1.0
ND
< 1.0
< 1.0
ND
< 1.0
ug -- --
ug
ug -- --
ug
ug -- --
ug
ug -- --
ug
ug -- --
ug
ug — --
ug
ug -- --
ug
ug -- --
ug
Ug
Page 13
-------
jfcT^ ~~~-^i= -•—---^^-—5
«>••< ^^ ^^ 55
^sr: Analytics Division
Laboratory Corporation of America® Holdings
PD Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No. C236091
Account No. 34419005
Report Date: 08/31/98
KOLDE
CFIC ENVIRONMENTAL SERVICES
SCHEFFEL
) DUKE DRIVE SUITE 150
DN, OH 45040
Final Report
j Received: 08/24/98
pie Type: 14 - Air Sample(s)
ject: EPA COKE-BTHLHM ST
Lytical Results
Client ID
Parameter
PO Number: 103-99-322
Volume Amount
Concentration
3 B-V-5506-2 Samp Date: 08/14/98 XAD-2
Acnapth- Front
Acnapth-Rear
Acnapht-Total
Acnthy- Front
Acnthy-Rear
Acnthy-Total
Anthr- Front
Ant hr- Rear
Anthr- Total
Bz (a) ant-Front
Bz (a) ant-Rear
Bz (a) ant-Total
Bz (a)pyr-Front
Bz (a)pyr-Rear
Bz (a)pyr-Total
Bz (b)fnt-Front
Bz (b) fnt-Rear
Bz(b)fnt-Total
Bzpery- Front
Bzpery-Rear
Bzpery- Total
Bz (k) fnt-Front
Bz (k) fnt-Rear
Bz (k) fnt-Total
Chy- Front
Chy-Rear
NVG
NVG
NVG
NVG
NVG
NVG
NVG
NVG
< 5.0 ug
ND
<5.0ug - - - -
< 5.0 ug
ND
-------
r Analytics Division
Laboratory Corporation of America® Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group NO. C236091
Account No. 34419005
Report Date: 08/31/98
KOLDE
FIC ENVIRONMENTAL SERVICES
SCHEFFEL
• DUKE DRIVE SUITE 150
>N, OH 45040
Final Report
t Received: 08/24/98
tie Type: 14 - Air Sample (s)
ect: EPA COKE-BTHLHM ST
.ytical Results
PO Number: 103-99-322
Client ID Parameter
Chy-Total
Db z ant hr - Front
Dbzanthr-Rear
Dbzanthr-Total
Flanthr-Front
Flanthr-Rear
Flanthr-Total
Fluorene - Front
Fluorene-Rear
Fluorene-Total
Indpyene - Front
Indpyene - Rear
Indpyene -Total
Napth- Front
Napth-Rear
Napth- Total
Panthr- Front
Panthr-Rear
Panthr-Total
Pyrene- Front
Pyrene-Rear
Pyrene -Total
Volume
NVG
NVG
NVG
NVG
NVG
NVG
NVG
NVG
Amount Concentration
< 1.0 ug --_-
< 1.0 ug
ND
< 1 . 0 ug ----
< 5.0 ug
ND
<5.0ug --__
< 5.0 ug
ND
< 5.0 ug - - - -
< 1.0 ug
ND
< 1.0 ug -- --
< 5,0 ug
ND
<5.0ug ___-
< 1.0 ug
ND
<1.0ug _ _ - -
< 1.0 ug
ND
< 1 . 0 ug ----
9 B-V-5506-3 Samp Date: 08/15/98 XAD-2
Acnapth-Front
Acnapth-Rear
Acnapht -Total
NVG
< 5.0 ug
ND
<5.0ug - - - -
Page 15
-------
. Analytics Division
Laboratory Corporation of America® Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No. C236091
Account No. 34419005
Report Date: 08/31/98
KOLDE
IFIC ENVIRONMENTAL SERVICES
SCHEFFEL
} DUKE DRIVE SUITE 150
)N, OH 45040
Final Report
j Received: 08/24/98
3le Type: 14 - Air Sample(s)
ject: EPA COKE-BTHLHM ST
Lytical Results
Client ID
Parameter
PO Number: 103-99-322
Volume Amount
Concentration
Acn thy- Front
Acn thy- Rear
Acnthy-Total
Anthr- Front
Anthr-Rear
ftnthr-Total
Bz (a) ant -Front
Bz (a) ant-Rear
Bz (a) ant-Total
Bz (a)pyr-Front
Bz (a)pyr-Rear
Bz (a)pyr-Total
Bz (b) fnt- Front
Bz (b) fnt -Rear
Bz(b) fnt -Total
Bzpery- Front
Bzpery-Rear
Bzpery-Total
Bz (k) fnt -Front
Bz (k) fnt -Rear
Bz {k} fnt-Total
Chy- Front
Chy-Rear
Chy-Total
Dbzanthr- Front
Dbzanthr-Rear
Dbzanthr-Total
NVG
NVG
NVG
NVG
NVG
NVG
NVG
NVG
NVG
< 5.0 ug
ND
<5.0ug _ _ _ _
< 1,0 ug
ND
•cl.Oug ____
< 1.0 ug
ND
< 1.0 ug _-__
< 1.0 ug
ND
< 1.0 ug •-- --
< 1.0 ug
ND
< 1.0 ug - -
< 1 . 0 ug
ND
< 1.0 ug ----
< 1.0 ug
ND
<1.0ug - - - -
< 1.0 ug
ND
< 1 . 0 ug ----
< 1.0 ug
ND
<1.0ug _ - _ -
Page 16
-------
^sr. Analytics Division
Laboratory Corporation of America® Holdings
PQ Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No. C23S091
Account No. 34419005
Report Date: 08/31/98
KOIJ3E
:FIC ENVIRONMENTAL SERVICES
SCHEFFEL
) DUKE DRIVE SUITE 150
>N, OH 45040
Final Report
! Received: 08/24/98
>le Type: 14 - Air Sample(s)
ject: EPA COKE-BTHLHM ST
.ytical Results
PO Number: 103-99-322
Client ID Parameter
Flanthr- Front
Flanthr-Rear
Flanthr-Total
Fluorene- Front
Fluorene-Rear
Fluorene-Total
Indpyene - Front
Indpyene - Re ar
Indpyene-Total
Napth- Front
Napth-Rear
Napth-Total
Panthr-Front
Pan thr- Rear
P an thr- Total
Pyrene- Front
Pyrene-Rear
Pyrene-Total
Volume
NVG
NVG
NVG
NVG
NVG
NVG
Amount
< 5.0 ug
ND
< 5.0 ug
< 5.0 ug
ND
< 5.0 ug
< 1.0 ug
ND
< 1.0 ug
6.70 ug
ND
6.70 ug
3.27 ug
ND
3 .27 ug
< 1.0 ug
ND
< 1.0 ug
Concentration
-- --
__ __
__ __
__ __
__ __
-- --
0 B-V-5506-FB
Samp Date: 08/15/98 FB
Acnapth-Front
Acnapth-Rear
Acnapht-Tot al
Acnthy-Front
Acnthy-Rear
Acnthy-Total
Anthr-Front
XAD-2
. 0 ug
. 0 ug
. 0 ug
< 5,
ND
< 5
< S,
ND
< 5.0 ug
< 1.0 ug
Page 17
n
-------
Bsr Analytics Division
Laboratory Corporation of America® Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No. C236091
Account No. 34419005
Report Date: 08/31/98
KOLDE
:FIC ENVIRONMENTS SERVICES
SCHEFFEL
) DUKE DRIVE SUITE 150
)N, OH 45040
Final Report
j Received: 08/24/98
>le Type: 14 - Air Sample (s)
lect: EPA COKE-BTHLHM ST
.ytical Results
PO Number: 103-99-322
Client ID Parameter Volume
Anthr-Rear
Anthr-Total
Bz (a) ant-Front
Bz (a) ant-Rear
Bz (a) ant-Total
Bz (a) pyr- Front
Bz (a)pyr-Rear
Bz (a)pyr-Total
Bz(b)fnt- Front
Bz(b)fnt~Rear
Bz(b)fnt -Total
Bzpery- Front
Bzpery-Rear
Bzpery- Total
Bz(k)fnt- Front
Bz (k) fnt-Rear
Bz(k)fnt -Total
Chy- Front
Chy-Rear
Chy-Total
Dbz an thr- Front
Dbzanthr-Rear
Dbzanthr-Total
Flanthr- Front
Flanthr-Rear
Flanthr-Total
Fluorene- Front
Page
0
0
0
0
0
0
0
0
0
18
Amount Concentration
ND
< 1 . 0 ug
< 1.0 ug
ND
< 1 . 0 ug
< 1.0 ug
ND
< 1.0 ug
< 1.0 ug
ND
< 1.0 ug
< 1.0 ug
ND
< 1 . 0 ug
< 1.0 ug
ND
< 1 . 0 ug
< 1.0 ug
ND
< 1 . 0 ug
< 1.0 ug
ND
< 1 . 0 ug
< 5.0 ug
ND
< 5 . 0 ug
< 5 . 0 ug
-------
^** Analytics Division
Labnratory Corporation of America® Holdings
PO Box 25249
Richmond, Virginia 23ZBO
Telephone: BQO-88B-8061
Group No, C236091
Account NO. 34419005
Report Date: 08/31/98
KOLDE
!FIC ENVIRONMENTAL SERVICES
SCHEFFEL
) DDKE DRIVE SUITE 150
)N, OH 45040
Final Report
; Received: 08/24/98
:le Type: 14 - Air Sample(s)
iect: EPA COKE-BTHLHM ST
Lytical Results
Client ID
Parameter
PO Number; 103-99-322
Volume Amount
Cone ent ra t i on
Fluorene-Rear
Fluorene-Total
Indpyene - Front
Indpyene - Rear
Indpyene-Total
Nap th- Front
Nap th- Rear
Nap th- Total
Panthr -Front
Pan thr- Rear
Panthr -Total
Py r ene - Front
Pyrene-Rear
Pyrene-Total
11 LAB BLANK BLANK XAD-2
Acnapth- Front
Acnapth-Rear
Acnapht -Total
Acnthy- Front
Acnthy-Rear
Acnthy-Total
Anthr- Front
Anthr-Rear
Anthr-Total
Bz (a) ant -Front
Bz (a) ant-Rear
0
0
0
0
0
0
0
0
ND
< 5.0 ug
< 1,0 ug
ND
< 1.0 ug
< 5.0 ug
ND
< 5.0 ug
< 1.0 ug
ND
< 1 . 0 ug
< i.o ug
ND
< 1 . 0 ug
< 5.0 ug
ND
< 5 . 0 ug
< 5.0 ug
ND
< 5 . 0 ug
< 1.0 ug
ND
< 1 . 0 ug
< l.o ug
ND
Page 19
-------
^fe Analytics Division
Laboratory Corporation of America® Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No. C236091
Account No. 34419005
Report Date; 09/31/98
KOLDE
FIC ENVIRONMENTAL SERVICES
SCHEFFEL
DUKE DRIVE SUITE 150
>N, OH 45040
Final Report
: Received: 08/24/98
de Type: 14 - Air Sample(s)
ect:
EPA COKE-BTHLHM ST
.ytical Results
Client ID
Parameter
PO Number: 103-99-322
Volume Amount
Concentration
Bz (a) ant -Total
Bz (a)pyr-Front
Bz (a)pyr-Rear
Bz (a)pyr-Total
Bz (b) fnt-Front
Bz (b) fnt-Rear
Bz (b) fnt-Total
Bzpery- Front
Bzpery-Rear
Bzpery-Total
Bz (k) fnt-Front
Bz (k) fnt-Rear
Bz(k) fnt-Total
Chy- Front
Chy-Rear
Chy-Total
Dbzanthr- Front
Dbzanthr-Rear
Dbzanthr-Total
Flanthr- Front
Flanthr-Rear
Flanthr-Total
Fluorene - Front
Fluorene-Rear
Fluorene-Total
Indpyene - Front
Indpyene - Rear
0
0
0
0
0
/
0
0
0
0
< 1 . 0 ug
< 1.0 ug
ND
< 1,0 ug
< l.o ug
ND
< 1.0 ug
< 1 . 0 ug
ND
< 1 . 0 ug
< 1.0 ug
ND
< 1 . 0 ug
< 1.0 ug
ND
< 1 . 0 ug
< 1.0 ug
ND
< i . o ug
< 5.0 ug
ND
< 5.0 ug
< 5.0 ug
ND
< 5.0 ug
< 1.0 ug
ND
Page 20
-------
K
ar. Analytics Division
Laboratory Corporation of America® Holdings
PC Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No. C236091
Account No. 34419005
Report Date: 08/31/98
KOLDE
:FIC ENVIRONMENTAL SERVICES
SCHEFFEL
} DUKE DRIVE SUITE 150
)N, OH 45040
Final Report
3 Received: 08/24/98
jle Type; 14 - Mr Sample (s)
ject: EPA COKE-BTHLHM ST
Lytical Results
PO Number: 103-99-322
Client ID Parameter Volume
Indpyene -Total
Napth- Front
Napth-Rear
- Napth-Total
Panthr - Front
Panthr-Rear
Panthr-Total
Py rene - F r ont
Pyrene-Rear
Pyrene-Total
12 LAB BLANK BLANK XAD-2
Acnapth- Front
Acnapth-Rear
Acnapht -Total
Acnthy - Front
Acnthy-Rear
Acnthy-Total
Anthr- Front
Anthr-Rear
Anthr-Total
Bz (a) ant -Front
Bz (a) ant-Rear
Bz (a) ant-Total
Bz (a)pyr-Front
Bz (a)pyr-Rear
Bz (a)pyr-Total
Page
0
0
0
0
0
0
0
0
0
21
Amount Concentration
< 1 . 0 ug
< 5.0 ug
ND
< 5.0 ug
< 1.0 ug
ND
< 1.0 ug
< 1.0 ug
ND
< 1 . 0 ug
< 5.0 ug
ND
< 5 . 0 ug
< 5,0 ug
ND
< 5 . 0 ug
< 1.0 ug
ND
< 1 . 0 ug
< l.o ug
ND
< 1 . 0 ug
< 1.0 ug
ND
< 1.0 ug
-------
^ri Analytics Division
Laboratory Corporation of America® Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No. C236091
Account No. 34419005
Report Date: 08/31/98
KOLDE
:FIC ENVIRONMENTAL SERVICES
SCHEFFEL
) DUKE DRIVE SUITE 150
)N, OH 45040
Final Report
5 Received: 08/24/98
3le Type: 14 - Air Sample(s)
ject: EPA COKE-BTHLHM ST
Lytical Results
Client ID
Parameter
PO Number: 103-99-322
Volume Amount
Concentration
Bz(b)fnt -Front
Bz (b) fnt-Rear
Bz(b)fnt -Total
Bzpery-Front
Bzpery-Rear
Bzpery-Total
Bz (k) fnt- Front
Bz (k) fnt-Rear
Bz (k)fnt-Total
Chy- Front
Chy-Rear
Chy-Total
Dbzanthr- Front
Dbzanthr-Rear
Dbzanthr-Total
Flanthr- Front
Flanthr-Rear
Flanthr-Total
F luor ene - Front
Fluorene-Rear
Fluorene- Total
Indpyene - Front
Indpyene-Rear
Indpyene - Total
Napth- Front
Napth-Rear
Napth-Total
0
0
0
0
0
0
0
0
0
< 1.0 ug
ND
< 1 . 0 ug
< 1.0 ug
ND
< 1 . 0 ug
< 1.0 ug
ND
< 1 . 0 ug
< 1.0 ug
ND
< 1 . 0 ug
< 1.0 ug
ND
< 1.0 ug
< 5.0 ug
ND
< 5 . 0 ug
< 5.0 ug
ND
< 5 . 0 ug
< 1.0 ug
ND
< 1 . 0 ug
< 5 . 0 ug
ND
< 5 . 0 ug
Page 22
-------
mg~< ~—• — —"~ --^ SJ"7
%is£-. Analytics Division
Laboratory Corporation of America® Holdings
PO Box Z5249
Richmond, Virginia 23260
Telephone: 8DD-888-BQ61
Group No. C236091
Account No. 34419005
Report Date: 08/31/98
KOLDE
TIC ENVIRONMENTAL SERVICES
SCHEFFEL
i DUKE DRIVE SUITE 150
)N, OH 45040
Final Report
5 Received: 08/24/98
»le Type: 14 - Air Sample(s)
ect: EPA COKE-BTHLHM ST
.ytical Results
Client ID
Parameter
PO Number: 103-99-322
Volume Amount
Cone ent rat i on
L3 SPIKE XAD-2
Lking level - 10 ug
Lking level - 10 ug
iking level - 0.5 ug
iking level - 1.0 ug
iking level - 0.5 ug
Panthr- Front
Panthr-Rear
Panthr -Total
Pyrene - Front
Pyrene-Rear
Pyrene-Total
Acnapth-Front
Acnapht -Total
Acnthy- Front
Acnthy- Tot al
Anthr- Front
Anthr-Total
Bz (a) ant-Front
Bz (a) ant-Total
Bz (a) pyr-Front
Bz (a) pyr-Total
Bz(b)fnt- Front
Bz(b)fnt-Total
0
0
0
0
0
0
0
0
< 1.0 ug
ND
< 1 . 0 ug
< l.O ug
ND
< 1 . 0 ug
6.14 ug
6 . 14 ug
7.95 ug
7.95 ug
0.466 ug
0.466 ug
0.65 ug
0.65 ug
0.256 ug
0.256 ug
0.381 ug
0.381 ug
iking level - 0.5 ug
Bzpery-Front
Page 23
0.263 ug
•v •/
-J -J
-------
Bs- Analytics Division ~"
Laboratory Corporation of America® Holdings
PC Box 25Z49
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No. C236091
Account No. 34419005
Report Date: 08/31/98
KOLDE
TIC ENVIRONMENTAL SERVICES
SCHEFFEL
) DUKE DRIVE SUITE 150
)N, OH 45040
Final Report
; Received: 08/24/98
>le Type: 14 - Air Sample(s)
ject: EPA COKE-BTHLHM ST
Lytical Results
PO Number: 103-99-322
Client ID
Lking level -
iking level -
Lking level -
Lking level -
Lking level -
iking level -
iking level -
iking level -
iking level -
Parameter Volume
0.
0.
0.
0.
5.
10
0.
10
0.
5 ug
5 ug
5 ug
5 ug
0 ug
ug
5 ug
ug
5 ug
Bzpery-Total
Bz(k) fnt-Front
Bz(k)fnt -Total
Chy- Front
Chy-Total
Db z anthr - Front
Dbzanthr-Total
Flanthr-Front
Flanthr-Total
Fluorene - Front
Fluorene -Total
Indpyene - Front
Indpyene -Total
Napth- Front
Napth-Total
Panthr-Front
Panthr-Total
0
0
0
0
0
0
0
0
0
Amount Concentration
0.263 ug
0.514 ug
0.514 ug
0.398 ug
0.398 ug
0.398 ug
0.398 ug
5.01 ug
5.01 ug
6.67 ug
6.67 ug
0.366 ug
0.366 ug
6.23 ug
6.23 ug
0.477 ug
0.477 ug
Pyrene-Front
Page 24
0.473 ug
-------
E£. Anaiytics Division
Laboratory Corporation of America® Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-8061
Group No. C236091
Account No. 34419005
Report Date: 08/31/98
KOLDE
IFIC ENVIRONMENTAL SERVICES
SCHEPFEL
) DUKE DRIVE SUITE 150
)N, OH 45040
Final Report
i Received: 08/24/98
sle Type: 14 - Air Sample(s)
ject: EPA COKE-BTHLHM ST
Lytical Results
PO Number: 103-99-322
Client ID
Iking level -
L4 DESORPTION
iking level -
iking level -
iking level -
iking level -
iking level -
iking level -
iking level -
Parameter
Py rene - Tot al
0 .5 ug
XAD-2
Acnapth- Front
Acnapht -Total
10 ug
Acnthy- Front
Acnthy-Total
10 ug
Anthr- Front
Anthr-Total
0. 5 ug
Bz (a) ant -Front
Bz (a) ant-Total
1.0 ug
Bz (a)pyr-Front
Bz (a)pyr-Total
0.5
Bz (b)fnt- Front
Bz (b)fnt-Total
0.5 ug
Bzpery- Front
Bzpery-Total
0.5 ug
Bz (k)fnt-Front
Bz(k)fnt-Total
Page
Volume
0
0
0
0
0
0
0
0
0
25
Amount Concentration
0.473 ug
9.38 ug
9.38 ug
12.2 ug
12.2 ug
0,540 ug
0.540 ug
0.780 ug
0.780 ug
0.324 ug
0.324 ug
0.519 ug
0.519 ug
0.306 ug
0.306 ug
0.645 ug
0.645 ug
-------
£* Analytics Division
Laboratory Corporation erf America® Holdings
PO Box 25249
Richmond, Virginia 232BQ
Telephone: 80Q-888-8061
Group No. C236091
Account No. 34419005
Report Date: 08/31/98
KOLDE
:FIC ENVIRONMENTAL SERVICES
SCHEFFEL
) DUKE DRIVE SUITE 150
)N, OH 45040
Final Report
; Received: 08/24/98
>le Type: 14 - Air Sample(s)
)ect: EPA COKE-BTHLHM ST
.ytical Results
Client ID
Parameter
PO Number: 103-99-322
Volume Amount
Concentration
Iking level
Lking level
Lking level
Lking level
Lking level
iking level
iking level
iking level
iking level
- 1.0 ug
- 0.5 ug
- 0.5 ug
5.0 ug
- 10 ug
- 1.0 ug
- 10 ug
- 0 . 5 ug
- 0 . 5 ug
Chy- Front
Chy-Total
Dbzanthr-Front
Dbzanthr-Total
Flanthr-Front
Flanthr-Total
Fluorene-Front
Fluorene-Total
Indpyene-Front
Indpyene-Total
Napth- Front
Napth-Total
Panthr- Front
Panthr-Total
Pyrene- Front
Pyrene- Total
0
0
0
0
0
0
0
0
0.474 ug
0.474 ug
0.431 ug
0.431 ug
6.49 ug
6.49 ug
8.43 ug
8.43 ug
0.573 ug
0.573 ug
8.01 ug
8.01 ug
0.542 ug
0.542 ug
0.522 ug
0.522 ug
reviations: ug = micrograms, rag = milligrams, mg/M3 = milligrams per
bic meter of air, g = grams, ug/M3 = micrograms per cubic meter of air,
= liters, w/w = percent weight basis, all Volumes given in liters,
m = parts per million, ppb = parts per billion, Areas given in square
et; ND = Not Detected.
mary of Analytical Methods
pound Name Analytical Method
Abbreviat ion
naphthene
NIOSH 5506
Acnapht
-------
^sr. Analytics Division
Laboratory Corporation oi America® Holdings
PO Box 25249
Richmond, Virginia 23260
Telephone: 800-888-3061
Group No. C236091
Account No. 34419005
Report Date: 08/31/98
KOLDE
:FIC ENVIRONMENTAL SERVICES
SCHEFFEL
> DUKE DRIVE SUITE 150
)N, OH 45040
Final Report
; Received: 08/24/98
>le Type: 14 - Air Sample(s)
ject: EPA COKE-BTHLHM ST
PO Number: 103-99-322
.ytical Method - continued
laphthylene NIOSH 5506
iracene NIOSH 5506
;(a)anthracene NIOSH 5506
:o{a)pyrene NIOSH 5506
so(b)fluoranthene NIOSH 5506
so{ghi)perylene NIOSH 5506
:o(k)fluoranthene NIOSH 5506
/•sene NIOSH 5506
aiz(a,h)anthracene NIOSH 5506
>ranthene NIOSH 5506
jrene NIOSH 5506
;no(l,2,3-cd)pyrene NIOSH 5506
ithalene NIOSH 5506
lanthrene NIOSH 5506
jne NIOSH 5506
Acnthy
Anthr
Bz(a)ant
Bz(a)pyr
Bz(b)fnt
Bzpery
Bz(k)fnt
Chy
Dbzanthr
Flanthr
Indpyene
Napth
Panthr
Attached are the results we obtained on the analysis of your
samples. Any Chains-of-Custody associated with this sample
group are also enclosed. Air concentrations are calculated
as a convenience to the client and the overall accuracy of
this result depends on both the accuracy of the air volume and
the amount found by analysis. Theoretical Air Volumes for
passive monitors are calculated using the sampling time
submitted and the manufacturer's listed sampling rate for each
compound.
We appreciate your confidence in allowing Analytics to be your
testing laboratory. Any questions regarding this report can
be addressed by calling our client services department
(800-888-8061) .
James A. Calpin, CIH
Laboratory Director
Page 27
-------
ANALYTICAL REQUEST AND CHAIN OF CUSTODY
SAMPLE
TECHNICIAN:
SAMPLE IDENTIFICATION
CXHJJECTION
DATE TIME
SAMPLE NAME
NUMBER OF
CONTAINERS
ANALYTICAL REQUEST
COMMENTS
.
tf -0-53*6 -2"'
K
Me
fr
(7
X
ft
-• (JiJ
^
P
REUNQUISHER*S NAME
DATE/TIME
JSHBTS SIGNATURE
RECEIVER'S NAME
DATE/TIME
RECEIVER'S SIGNATURE
SHIPPER'S NAME AND ID NUMBER
-------
First Analytical Laboratories
ANALYSIS REPORT
Metals in Dust
Project # S506.000
Prepared for:
Pacific Environmental Services, Inc.
7209 E. Kemper Road
Cincinnati, OH 45249
Reviewed and Approved by:
William H. Wadlin, Ph. D.
Laboratory Manager
October 5, 1998
-------
First Analytical Laboratories
CASE NARRATIVE
Project #: 80915 Report Date: 05-Oct-98
Client: Pacific Environmental Services, Inc.
Client Project ID: S506.000
Samples:
Three samples of dust were submitted. The target elements were antimony,
arsenic, barium, beryllium, cadmium, chromium, copper, lead, manganese,
mercury, nickel, phosphorus, selenium, silver, thallium and zinc. All of the
samples were received in good condition, with no apparent leakage or damage.
Preparation:
The samples were prepared according to EPA Method 3050A, which is a
nitric acid digestion.
Analysis:
Cadmium, lead and zinc were determined by Direct Aspiration Flame Atomic
Absorption Spectrophotometry (FLAA). Antimony, arsenic, beryllium, selenium,
silver and thallium were determined by Graphite Furnace Atomic Absorption
Spectrophotometry (GFAA). Barium, chromium, copper, nickel and phosphorus
were determined by Inductively Coupled Plasma - Optical Emission (ICP).
Results:
The results are reported as concentration in the original sample, in
micrograms of element per gram of sample (/tg/g), which is equivalent to parts per
million by weight (ppm). All of the target elements were detected in all of the
samples, except for silver in sample #2. The highest levels were found for
manganese, phosphorus and zinc. These three elements were in the range of about
40 ppm, 50 ppm, and 70 ppm respectively.
Quality Control:
Traces of cadmium and zinc were found in the blanks. The cadmium blank
is about half of the sample levels, so these results should be blank corrected. The
zinc blank is only about ten percent of the sample values. The spike recoveries were
-------
all within the normal range of 70% to 130%. The duplicates were all within the
normal limit of 20% for all cases m which the sample level is more than five times
the detection limit.
-------
First Analytical Laboratories
1126 Burning Tree Dr. Chapel Hill, NC 27514
Tel. (919) 942-8607
FAX (919) 929-8688
ANALYSIS REPORT
Project #: 80915
Client: Pacific Environmental
Client Project ID: # S506.000
Report Date: 05-Oct-98
Date Received: 21 -Sep-98
Parts per million in original sample
Element BD-BS-1 BD-BS-2 BD-BS-3
QUALITY CONTROL DATA
Lab Spike Duplicate
Blank %Recovery %Diff.
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Copper
Lead
Manganese
Mercury
Nickel
Phosphorus
Selenium
Silver
Thallium
0.33
10.7
9.21
0.42
1.64
7.42
7.7
35.8
67.5
0.20
7.0
44.7
3.8
0.05
0.77
0.52
10.5
9.32
0.33
1.50
8.33
8.1
36.4
70.2
0.15
7.8
50.4
3.5
<0.02
0.88
0.36
11.0
8.62
0.29
1.80
6.39
6.5
38.9
66.2
0.18
6.7
43.5
3.2
0.06
0.72
<0.25
<0.25
<0.20
< 0.005
0.75
< 1.25
< 1.5
<5.0
<2.0
<0.07
<2.5
< 1.0
<0.2
<0.03
<0.15
74%
82%
93%
94%
104%
1 08%
101%
97%
1 05%
96%
76%
87%
100%
NA
2.2%
2.9%
1 5.9%
1 8.7%
1 .9%
4.5%
1 .9%
NA
NA
6.8%
1 3.0%
NA
13.7%
Zinc
37.5
36.1
39.7
4.7
4.8%
-------
ANTIMONY
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES IDL = 5
Proj. #; 80915 Spike Cone. = 100
Date; 05-Oct-98
Sample ID
Client
BD-BS-1
BD-BS-1
BD-BS-1
FAL
80915
80915
80915
.1
.2
.3
Test
Sol'n
pg/L
6.
10,
7,
6
5
3
Digte
Cone
Mg/L
6.
10,
6
5
7.3
FV
ml
100
100
100
Dit'n
Factor
1
1
1
Sample
Weight
g
2.0084
2,0053
2,0040
Cone.
in original
Sample
0.33
0.52
0.36
Lab Blank 80915.LB 0.0 0.0 TOO
Duplicate 80915.2D 4.5 4,5 100
1 2.0000 <
1 1,9956 <
% Difference =
Spike 80915.15 80.6 1.9929 %Recovery
QUALITY CONTROL DATA
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Abs. True cone., jig/l
0.000
0,020
0.088
0.175
0.310
0
10
50
100
200
0.25
0.25
NA
74.0%
Calibration Verifications/ pg/L
ICV=100 99.6
ICB = 0 0.5
CCV2 =100
CCB2 = 0
87.9
0.4
CCV1 = 100
CCB1 = 0
95.4
2.2
CCV3 =100
CCB3 = 0
88.5
1.6
-------
ARSENIC
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES IDL = 5 pg/L
Proj. #: 80915 Spike Cone. « 100 pg/L
Date: 05-Oct-98
Sample ID
Client
FAL
BD-BS-1
BD-BS-1
BD-BS-1
80915.1
80915.2
80915.3
Lab Blank 80915.LB
Duplicate 80915.2D
Post-spike
Pre-spike
80915.1
809T5.1S
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Calibration Verifications, j/g/L
ICV= 100
ICB = 0
CCV1 =100
CCB1 = 0
Test Digte Dil'n
Sol'n Cone FY Factor
/ug/L //g/L ml
21.7 216.5 100 10
105.6 211.2 100 2
110.5 221.0 100 2
2.4 2.4 100 1
102.8 205.6 100 2
111.7 10
206.81 5
QUALITY CONTROL DATA
Abs. True cone., fttj/L
0.000 0
0.039 10
0.148 50
0.305 100
0.620 200
/I
rL
104.8 CCV2 = 100
5.4 CCB2 = 0
99.4 CCV3 = 100
7.0 CCB3 = 0
CCV4 = 100
CCB4 = 0
Sample
Weight
g
2.0084
2.0053
2.0040
2.0000
1.9956
%
1.9929
95.9
2.7
97.8
5.2
95.B
1.5
Cone.
in original
Sample
jjg/g (ppm)
10.78
10.53
11.03
< 0.25
10.30
Difference = 2.2%
%Recovery = 90.1%
%Recovery = 81.8%
-------
BARIUM
ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES IDL = 4 fig/I
Proj. #: 8091 5 Spike Cone. = 100 jig/L
Date: 05-Oct-98
Sample ID
Client FAL
BD-BS-1 80915.1
BD-BS-1 80915.2
BD-BS-1 80915.3
Test
Sol'n
fig/I
184.9
186.8
172.8
Dig'te
Cone
pg/L
184.9
186.8
172.8
FV
ml
100
100
100
Dil'n
Factor
1
1
1
Sample
Weight
g
2.0084
2.0053
2.0040
Cone.
in original
Sample
p»g/g (ppm)
9.21
9.32
8.62
Lab Blank 80915.LB
2.0
2.0 100
1 2.0000
0.20
Duplicate 80915.2D 180.6 180.6 100
1 1.9956 9.05
% Difference = 2.9%
QUALITY CONTROL DATA
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Emissio True cone.,
76 0
171 100
517 500
949 1000
1788 2000
Calibration Verifications, fig/L
ICV = 1000 1010
ICB = 0 1
CCV2 =1000
CCB2 = 0
CCV1 = 100 1018
CCB1 =0 0
CCV3 = 1000
CCB3 « 0
-------
BERYLLI UM
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES IDL = 0.10 ^g/L
Proj. #: 8091 5 Spike Cone. = 5.00 yg/1
Date: 05-Oct-98
Sample
Client
BD-BS-1
BD-BS-1
BD-BS-1
ID
FAL
80915.1
80915.2
80915.3
Test
Sol'n
pg/L
0.84
0.66
0.59
Digte
Cone
pgA
8.40
6.60
5.90
FV
ml
100
100
100
Dil'n
Factor
10
10
10
Sample
Weight
9
2.0084
2.0053
2.0040
Cone.
in original
Sample
pg/g (ppm)
0.418
0.329
0.294
Lab Blank 80915.LB
-0.05 -0.05 100
1 2.0000
Duplicate 80915.2D 0.56 5.60
100
10 1.9956
Post-spike 80915.1
5.51
10
i Difference =
0.005
0.281
15.9%
%Recovery« 93.4%
QUALITY CONTROL DATA
Calibration Data Abs. True cone., j/g/L
Blank 0.000 0.00
Standard! 0.011 0.10
Standard 2 0.042 2.00
Standard 3 0.098 5.00
Standard 4 0.169 10.00
Calibration Verifications, jig/L
ICV = 5 5.25 CCV2 = 5
ICB = 0 0.04 CCB2 = 0
4.84
-0.01
CCV1 = 5
CCB1 = 0
5.26
0.07
CCV3 =5
CCB3 = 0
4.94
0.02
-------
CADMIUM
FLAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES IDL = 5 yg/L
Proj, #: 80915 Spike Cone. = 400 jjg/L
Date: 05-Oct-98
Sample
Client
BD-BS-1
BD-BS-1
BD-BS-1
Lab Blank
Duplicate
ID
FAL
80915.1
80915.2
80915.3
80915.LB
80915.2D
Test
Sol'n
M9/L
33
30
36
15
36
Digte
Cone
MA
33
30
36
15
36
FV
ml
100
100
100
100
100
Dil'n
Factor
1
1
1
1
\
Sample
Weight
g
2.0084
2.0053
2.0040
2.0000
1.9956
Cone.
in original
Sample
jjg/g (ppm)
1.643
1.496
1.796
0.750
1.804
% Difference =
18.7%
Pre-spike 80915.1 S 408.00 1 1.9929 %Recovery
QUALITY CONTROL DATA
93.8%
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Standard 5
Calibration Verifications, fig/L
ICV = 500
ICB = 0
CCV1 = 50
CCB1 = 0
Abs. True cone.,
0.000
0.021
0.040
0.080
0.193
0.360
ig/L
476
2
489
1
0
50
100
200
500
1000
CCV2 = 500
CCB2 = 0
CCV3 - 500
CCB3 = 0
498
0
503
1
-------
CH ROMIUM
Lab Blank 80915.LB
Duplicate 80915.2 D
ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES IDL = 25
Proj. #: 80915 Spike Cone. = 2000 j/g/L
Date: 05-Oct-98
Sample ID
Client
BD-BS-1
BD-BS-1
BD-BS-1
FAL
80915.1
80915,2
80915.3
Test
Sol'n
WJ/L
T49
167
128
Digte
Cone
WJA
149
167
128
FV
ml
100
100
100
Dil'n
Factor
1
1
1
Sample
Weight
g
2.0084
2.0053
2.0040
Cone.
in original
Sample
pg/g (ppm)
7.419
8.328
6.387
163
7 100 1 2.0000 < 1.250
163 100 1 1.9956 8.168
% Difference » 1.9%
Pre-spike 80915. IS
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
2220 1 1.9929 %Recovery = 103.6%
QUALITY CONTROL DATA
Emissio True cone., /jg/L
488 0
580 100
1146 500
1752 1000
3108 2000
Calibration Verifications, jlfg/L
ICV=1000 1025
ICB = 0 7
CCV1 = 1000
CCB1 o 0
1051
-1
CCV2 =1000
CCB2 = 0
CCV3 =1000
CCB3 = 0
1017
17
-------
COPPER
ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES 1DL = 30 yg/L
Proj. #:80915 Spike Cone. = 2000 j/g/L
Date: 05-Oct-98
Sample ID
Client
Test Digte
FAL Sol'n Cone
pg/L
Dil'n Sample
FV Factor Weight
ml g
BD-BS-1
BD-B5-1
BD-B5-1
80915.1
80915.2
80915.3
156
163
130
156
163
130
100
100
100
1
1
1
2.0084
2.0053
2.0040
Cone.
in original
Sample
/ig/g (ppm)
7.767
8.128
6.487
Lab Blank 80915 LB
19
19 100
1 2.0000
1.500
Pre-spike 80915.1 S 2319 1 1.9929 %Recovery
QUALITY CONTROL DATA
108.2%
Calibration Data
Emissio True cone., /Jg/L
Blank 1712 0
Standard 1 2222 100
Standard 2 6842 500
Standards 12301 1000
Standard 4 24207 2000
Calibration Verifications, pg/L
ICV= 1000 1019
ICB = 0 20
CCV2= 1000
CCB2 = 0
1166
27
CCV1 = 10
CCB1 = 0
1094
23
CCV3= 1000
CCB3 = 0
-------
LEAD
FLAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES IDL = TOO yg/L
Proj. #: 80915 Spike Cone. = 2000
Date: 05-Oct-98
Sample
Client
BD-BS-1
BD-BS-1
BD-BS-1
ID
FAL
80915.1
80915.2
80915.3
Test
Sol'n
W/L
720
730
780
Digte
Cone
WJ/L
720
730
780
FV
ml
100
100
100
Dil'n
Factor
1
1
1
Sample
Weight
g
2.0084
2.0053
2.0040
Cone,
in original
Sample
tig/g (ppm)
35.849
36.404
38.922
Lab Blank 80915.LB
70
70 100
1 2.0000
5.000
Duplicate 80915.2D
760
760 100
1 1.9956
% Difference
Pre-spike 80915.IS 2740 1 1.9929 %Recovery>
QUALITY CONTROL DATA
38.084
4.5%
101.0%
Calibration Data
Abs. True cone., /ig/L
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Standard 5
Standard 6
Calibration Verifications, fig/L
ICY = 5000
ICB = 0
CCV1 = 500
CCB1 = 0
0.000
0.004
0.009
0.017
0.032
0.080
0.159
n/I
g/u
4940
20
4930
-10
0
200
500
1000
2000
5000
10000
CCV2 = 5000
CCB2 = 0
CCV3 = 5000
CCB3 = 0
4870
10
5130
-10
-------
MANGANESE
FLAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES IDL = 40 jug/I
Pro]. #: 80915 Spike Cone. = 400 //g/L
Date: 05-Oct-98
Sample ID
Client
BD-BS-1
BD-BS-1
BD-BS-1
FAL
80915.1
80915.2
80915.3
Test
Sol'n
/jg/l
1355
1407
1326
Digte
Cone
/jg/L
1355
1407
1326
FV
ml
100
100
100
Dil'n
Factor
1
1
1
Sample
Weight
g
2.0084
2.0053
2.0040
Cone.
in original
Sample
tlg/g (ppm)
67.467
70.164
66.168
Lab Blank 80915.LB
32
32 TOO
1 2.0000
2.000
Duplicate 80915.2D
1374 1374 100
1 1.9956
% Difference
Pre-spike 80915.1S 1744 1 1.9929 %Recovery
QUALITY CONTROL DATA
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Abs. True cone., jug/I
0.000
0.030
0.075
0.142
0.271
0
200
500
1000
2000
68.851
1.9%
97.3%
Calibration Verifications, fig/L
ICV = 500 980
1CB « 0 6
CCV1 =500 1025
CCB1 =0 31
CCV2 = 500
CCB2 = 0
CCV3 = 500
CCB3 = 0
-------
MERCURY
CVAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES IDL = 0.20 /jg/L
Proj. #: 80915 Spike Cone. = 5.00 /Ltg/L
Date: 05-Oct-98
Sample
Client
BD-BS-1
BD-BS-2
BD-BS-3
ID
FAL
80915.1
80915.1
80915.2
80915.2
80915.3
80915.3
Test
Sol'n
W/L
0.55
0.65
0.30
0.61
0.50
0.56
Digte
Cone
M/L
0.55
0.65
0.30
0.61
0.50
0.56
FV
ml
100
100
100
100
100
100
Dil'n
Factor
1
1
1
1
1
1
Sample
Weight
g
0.2981
0,2996
0.3004
0.3034
0.2955
0.3013
Cone.
in original
Sample
//g/g (ppm)
0.185
0.217
Avg. = 0,201
Avg.=
Avg. =
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Standard 5
Abs. True cone., jug/L
0.000 0.00
0.010 0.50
0.026 1.00 \
0.044 2.00
0.119 5.00
0.242 10.00
Calibration Verifications, pg/L
ICY =5
ICB = 0
CCV1 =5
CCB1 = 0
CCV2 = 5
CCB2 m Q
5,08
0,02
4.91
-0.10
4.90
0.00
CCV3 =
CCB3 =
CCV4 =
CCB4 =
CCV5 =
CCB5 =
5
0
5
0
5
0
4.83
-0.03
4.51
-0.03
0.100
0.201
0.150
0.169
0.186
0.178
Pre-spike 80915.1 S 5.79 1 0.3010 %Recovery= 104.8%
QUALITY CONTROL DATA
-------
NICKEL
ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES IDL - 50 /jg/L
Proj. #: 80915 Spike Cone. = 2000 pg/L
Date: 05-Od-98
Sample ID
Client
BD-BS-1
BD-BS-2
BD-BS-3
FAL
80915.1
80915.2
8091 5.3
Test
Sol'n
Mg/L
140
157
134
Dig'te
Cone
P9/L
140
157
134
FV
ml
100
100
100
Dil'n
Factor
1
1
1
Sample
Weight
g
2.0084
2.0053
2.0040
Cone.
in original
Sample
f/g/g (ppm)
6.971
7.829
6.687
Lab Blank 80915.LB
8
8 100
1 2.0000
2.500
Duplicate 80915.2D
120
120 100
1 1.9956
% Difference
Pre-spike 80915.1S 2064 1 1.9929 %Recovery
QUALITY CONTROL DATA
Calibration Data
Emissio True cone., pg/L
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Calibration Verifications/ pg/L
ICV= 1000
ICB = 0
CCV1 = 100
CCB1 = 0
615
692
1228
1857
3229
I/I
956
16
1195
40
0
100
500
1000
2000
CCV2 = 1000
CCB2 = 0
CCV3 = 1000
CCB3 = 0
1021
23
6.013
26.2%
96.2%
-------
PHOSPHORUS
ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES IDL = 20
Proj. #;80915
Date: 05-Oct-98
Sample ID
Client
BD-BS-1
BD-BS-2
BD-BS-3
FAL
80915.1
80915.2
80915.3
Test
Sol'n
flg/l
898
1011
871
Digte
Cone
M/L
898
1011
871
FV
ml
100
100
100
Dil'n
Factor
1
1
1
Sample
Weight
g
2.0084
2.0053
2.0040
Cone.
in original
Sample
pg/g (ppm)
44.712
50.416
43,463
Lab Blank 80915. LB
8 100
1 2.0000
1.000
Duplicate 80915.2D
940 940 100 1 1.9956 47.104
% Difference 6.8%
Calibration Data
QUALITY CONTROL DATA
Emissio True cone., //g/L
Blank
Standard 1
Standard 2
Standard 3
Standard 4
414
444
626
859
1590
0
200
1000
2000
5000
Calibration Verifications, pg/L
ICV = 2000 2109
ICB = 0 -2
CCV2 = 2000
CCB2 = 0
CCV1 = 200
CCB1 = 0
2342
18
CCV3 = 2000
CCB3 = 0
-------
SELENIUM
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES IDL = 3 pg/L
Proj, #: 80915 Spike Cone, = 50 pg/L
Date: 05-Oct-98
Sample ID
Client
BD-BS-1
BD-BS-1
BD-BS-1
80915
80915
80915
FAL
.1
,2
.3
Test
Sol'n
Hg/L
75.
7
69.2
65.
0
Dig'te
Cone
JJ9/I-
75.
69.
65.
7
2
0
FV
ml
100
100
100
Dil'n
Factor
1
1
1
Sample
Weight
g
2.0084
2.0053
2.0040
Cone.
in original
Sample
/jg/g (ppm)
3.77
3.45
3.24
Lab Blank 80915.LB
1.8
1.8 100
1 2.0000
0.15
Duplicate 80915.2D
Post-spike 80915.1
60.4
113.6
60.4 100
1
1.9956 3.03
% Difference - 13.1%
%Recovery = 75.7%
QUALITY CONTROL DATA
Abs. True cone., ffg/L
Calibration Data
Blank 0.000 0
Standard 1 0.022 10
Standard 2 0.049 25
Standard 3 0.098 50
Standard 4 0.182 100
Calibration Verifications, jjg/L
ICV = 50 48.7 CCV2 = 50
ICB = 0 2.9 CCB2 = 0
can = so
CCBl = 0
48.4
1.8
CCV3 = 50
CCB3 = 0
-------
SILVER
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES IDL = 0.5 pg/L
Proj. #; 8091 5 Spike Cone, = 1 0.0 j/g/L
Date: 05-Oct-98
Lab Blank 80915.L6
Duplicate 80915.2D
Post-spike 80915.1
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Calibration Verifications, fig/L
ICV = 20
ICB = 0
CCV1 = 20
CCB1 = 0
Test Drgte Dil'n
Sol'n Cone FV Factor
//g/L /Ug/L ml
1.0 1.0 100 1
0.2 0.2 100 1
1.1 1.1 100 1
-0.4 -0.4 100 1
1.0 1.0 100 1
9.7 1
QUALITY CONTROL DATA
Abs, True cone., j/g/L
0.000 0
0.094 5
0.185 10
0.356 20
0.526 30
it
'L
20.7 CCV2 = 20
0.0 CCB2 = 0
20.8 CCV3 = 20
-0.1 CCB3 = 0
Sample Cone.
Weight in original
g Sample
//g/g (ppm)
2.0084 0,05
2.0053 < 0.02
2.0040 0.06
2.0000 < 0.03
1.9956 0.05
% Difference = NA
%Recovery = 86.9%
-------
THALLI UM
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES IDL = 3 j/g/L
Proj. #: 80915 Spike Cone. = 50 pg/L
Date: 05-Oct-98
Sample ID
Client
BD-BS-1
BD-BS-2
BD-BS-3
FAL
80915.1
80915,2
80915.3
Test
Sol'n
15.4
17.6
14.4
Dig'te
Cone
15.4
17.6
14.4
FV
ml
100
100
100
Dil'n
Factor
1
1
1
Sample
Weight
9
2.0084
2.0053
2.0040
Cone.
in original
Sample
pg/g (ppm)
0.77
0.88
0.72
Lab Blank 80915.LB
0,8
0.8 100
1 2.0000
0.15
Duplicate 80915.2 D
15.3 15.3 100 1 1.9956 0.77
% Differences 13.7%
Post-spike 80915.1
65.3 1
QUALITY CONTROL DATA
Abs. True cone., /Jg/L
%Recovery = 99.9%
Calibration Data
Blank 0.000 0
Standard 1 0.019 10
Standard 2 0.042 20
Standard 3 0.099 50
Standard 4 0.188 100
Calibration Verifications, yg/L
ICV = 50 50.5 CCV2 = 50
ICB = 0 1.8 CCB2 = 0
CCV1 = 50
CCB1 = 0
49.3
0.0
CCV3 = 50
CCB3 = 0
-------
ZINC
FLAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: PES IDL = 20 /Jg/L
Proj. #: 80915 Spike Cone. = 400 j/g/L
Date: 05-Oct-98
Sample ID
Client
BD-BS-1
BD-BS-2
BD-BS-3
FAL
80915.1
80915.2
80915.3
Test Digte
Sol"n Cone
jug/I
753
724
796
753
724
796
FV
ml
100
100
100
Dil'n
Factor
1
1
1
Sample
Weight
g
2.0084
2.0053
2.0040
Cone.
in original
Sample
V g/g (ppm)
37.493
36.104
39.721
Lab Blank 80915.LB
94
94 100
1 2.0000
4.700
Duplicate 80915.2D 756
756 100
1.9956 37.883
% Difference - 4.8%
Calibration Data
Blank
Standard 1
Standard 2
Standard 3
Standard 4
Standard 5
Calibration Verifications, f/g/L
ICV = 500 507
ICB = 0 0
QUALITY CONTROL DATA
Abs. True cone., j/g/L
0.000
0.019
0.041
0.085
0.204
0.397
0
50
100
200
500
1000
CCV2 = 500
CCB2 = 0
527
17
CCV1 = 50
CCB1 = 0
496
-2
CCV3 = 500
CCB3 = 0
507
-8
-------
O PACIFIC ENVIRONMENTAL SERVICES, INC.
Chain of Custody Record
mason, un
(513)398-2556
FAX: (513) 398-3342
Samplers:
roject Number:
Purchase Order No,:
PES Field Sample ID
Date
rojectName:
* 5W
Time
Sample Description
Number
of
Containers
Analysis Requested
/lfcAi/5
V
left?
Comments
BD-%5-1
8&-BS-3
f%^
' fiW
•j-L,
T-
£L
titfa
S*Lt°«*.
/ '
2.1*1*0
Relinquished by: (Signature)
Date/Time
Received by: (Signature)
Relinquished by, (Signature)
Date/Time
Received by: (Signature)
Relinquished by: (Signature)
Date/Time
Received for lab by: (Signature)
REMARKS
page:__
-------
. USA Airbill
fltbt
TfflcMftB
Numbl-
From
FACIFIC ENVIRQNHENTAL
^.(513)398-5556
4700 DUKE PR 5TE 15Q
MASON
. OH
4SQ40
Tout Internal Billing Reference Information,,
To
its
A//X 1^/1.^
1^-
[~| Check here
L—' jfreadsnca
.[!• nF,:& tacitnn, iinffl F«E. i
For H01D at FsdEic Location check hare
For WEEKEND Delivery check here
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It. No
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ES Express Package Service
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Your tignttura eirthorizB! fsitnl Expreau d
orant ividtfiuiob»ining i sl^iatwo and agrets tu i
nd to d hsrmlBii fo Jsill Eipr«l I'cni any rtsulfinj clairra.
Questions?
Call 1 800 Go-Fed&c* [800)463-3339
OOS7O0634 1
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-------
:iement Files SB.GEL
'ate: O9/3O/9G
'at a File:
echnioues HGA
Element: Sb
Time: 10:02
ID/Wt File: 8O911.IDW
Calib. Type: Nonlinear
Wavelength: 217.
Slit: 0.7 L
Lamp Current; 0
Enerqy: 39
ID: BLANK
Sea, No.: 00002
A/S Pas.: 0
Date: O9/30,
'eolicate 1
'eak Area (A-s) : -O.OO5
iackoround Pk Area (A-s): 0.161
tlank Corrected Pk Area (A-s): -O.006
Concentration (ua/L ): —2.8
Time: 10:05
Peak Height (A): 0.020
Background Pk Height (A): 0.079
'•sol i cats 2
leak Area (A-s): -O.OOO
lackground Pk Area (A-s): 0.161
tlank Corrected Pk Area (A-s): -O.OO1
loncentration (ua/L ): -0.4
lean Cone (ug/L ):
iuto-zero performed.
-1.6
Time: lOsOB
Peak Height (A): 0.021
Backoround Pk Heiaht (A)
0.078
SD: 1.70
RSD(X); 102
>b
ID: 10 PPB
Sea. No.
teolicate 1
'eak Area (A-s): O.021
^aekaround Pk Area (A-s): 0.183
Hank Corrected Pk Area (A-s): 0.024
Concentration (ug/L }: 12.5
Jeolicate 2
Jeak Area (A-s): O.014
Jaekaround Pk Area (A-s): O.1B2
Jlank Corrected Pk Area (A-5): 0.016
Concentration (uq/L ): 8.4
lean Cone (ua/L >
1O.5
OOOO3
A/S Pos.: 1
Date: O9/30/
Time: 1O:11
Peak Height (A): O.O41
Backaround Pk Heiaht (A): 0.086
Time: 10:15
Peak Height (A): 0.036
Backaround Pk Height (A): 0.080
SD: 2.85
RSD (7.): 27.25
standard number 1 aoolied. [1O.O]
Correlation coefficient: 1.OOOOO
Slope: O.O020
Date: 09/3O/
ID: 50 PPB
Sea, No.
OOO04
A/S Pos.: 2
Replicate 1
'eak Area (A-s): O.OS5
background Pk Area (A-s): O.184
Blank Corrected Pk Area (A-s): O.OBS
Concentration. (ua/L ): 43.7
Time: 1O:18
Peak Height (A): 0.127
Backaround Pk Heiaht (A): O.OB2
Area (A-s): O.085
aackaround Pk Area (A-s): 0.184
31ank Corrected Pk Area (A-s): O.O87
Concentration (ua/L ): 43.4
Time: 1O:21
Peak Height (A): 0.126
Backaround Pk Height (A)s 0.078
-------
ean Cone (ua/L ) :
43.5
SD: 0.19
RSD ('/.I: 0.44
tandard number 2 applied. [50.O]
orrelation coefficient; l.OOOOO
Slope: O.OO21
TD: 10O PPB
Sea. No.: OOOO5
enlicate 1
eak Area (A-s): 0.178
ackqround Pk Area (A-s): 0,184
lank Corrected Pk Area (A-s): 0.181
oncentration (ua/L ): 130.0
eolicate 2
eak Area (A-s): Q.165
ackoround Pk Area (A—s): O.185
lank Corrected Pk Area (A-s): 0.168
oncentration (ua/L ): 116.4
ean Cone (ua/L ):
123.1
A/S Pos.: 3
Time: 10:24
Peak Heiaht (A): 0.225
Background Pk Height (A)
Date: O9/3O/
O.080
Time: 1O:28
Peak Height (A): 0.223
Background Pk Height (A): O.O75
SD: 9.60
RSD(X): 7.79
-shaped calibration curve detected. 2-coef. equation used.
tandard number 3 applied. flOO.O]
orrelation coefficient: 0.99B33 Slooe: O.OO20
TD: 2OC PPB
Seo. No.: O0006
eplicate 1
eak Area (A-s): 0.304
ackground Pk Area (A-s): 0.197
lank Corrected Pk Area (A-s): 0.307
oncentration (ua/L ): 208.4
enlicate 2
eak Area (A-s): 0.310
ackoround Pk Area (A-s): O.192
lank Corrected Pk Area (A-s): 0.313
oncentration (ua/L ): 213.9
ean Cone (uo/L
211.1
tandard number 4 applied. C2O0.01
orrelation coefficient: 0.99976
A/S Pos.: 4
Date: O9/30/
Time: 10:31
Peak Height (A): 0.364
Backoround Pk Heiaht (A): 0.076
time: 10:34
Peak Height (A)s 0.38O
Backaround Pk Heiaht (A): 0.077
SD: 3.90
Slope: 0.0020
RSD(X): 1.85
-------
*|0i
JO. S',9-
i '
I "
«
c.
.snijy taJlfantiflfl - C:\AA U$IF!\ftft F
m^>-
^-r""
^""
_.x'
r_wX>" Honianaar .
1 C4iic^n tra ti&n • £90*0
4
1
Date; 09/30
>b ID: ICV
?eolicate 1
Concentration (ug/L ): 99.9
Sea. Mo.: OO007 A/S Pos.: 5
Time: 1O:53
Time: 10:57
"Concentration (uo/L >: 99.3
lean Cane (ua/L ) :
99.6
SD: 0.47
3C sample is within ranae 79.5 - 12O.49
RSD C/.): O . 47
'b ID: ICB
'eolicate 1
Concentration (ua/L ): -0.3
Sea. No.: OOOOB A/S Pos.
Time: 11:00
Time: 11:03
Concentration (ua/L ): 1.4
lean Cone (uo/L ): O.5 SDs 1.22
3C samole is within ranae -15.49 - 15.49
IDs S091KRB-1
Replicate ,1
(ua/L ): 3 . 9
ancerrtration (ua/L ): O.6
lean Cone (ua/L )s
Seo. No.: O0009 A/S Pos.: 6
Time: 11:06
Time? 11:10
2.2 SD: 2.32
Date: Q9/3O*
RSD(X): 227.
Date: 09/30/
RSD(7.) : 103.
ID: 80911.FB-1
Sea. No.: 00010 A/S Pos.: 7
Date: 09/30/
-------
3b T$: 80911.Il-2Ax20 Seo. No.: OO031 A/S Pos.: 19 Date: 09/30/
Reolicate rv. /*" Time: 13:52
Concentration IS^a/L/ 5: 12.9 Corrected Cone (uq/L ): 253.
^eolicate 2 ,^^\. Time: 13:55
Concentration y£g/L > = 7.7 Corrected Cone
-------
3C sample is within range -15.49 - 15.49
3b ID: B0915.LB Seo . No.; OO036 A/S PDS.: 22 Date: 09/3C
^eolicate 1 Time: 14:24
Concentration (ug/L ): -3.2
'enlicate 2 Time: 14:27
Concentration Cua/L ): 3.3
lean Cone (ua/L ): -O.O SD: 4.60 RSD(7.>: 226^
3b IDs 809 1 5. l#f .... Sea. No.: 00037 A/S PDS.: 23 Date: 09/3<
Dedicate 1 Time: 14:30
Concentration (ug/L ): 3.7 Corrected Cone (ug/L ): 37.
^eolicate 2 Time: 14:34
Concentration (ug/L ): 9.6 Corrected Cone (ug/L ): 96.
lean Cone (ua/L ): 6.6 SD s 4.20 RSD (*/.): 62. S
Corrected Cone (ua/L ): 66.
«i*» Sea. No.: 00033 A/S Pos.: 23 Date: 09/3C
T ime: 14:37
ua/L 5: B1.2 Corrected Cone (ug/L ): 812.
-.-:.• 1 i -.H.t =• 2 Time: 14:40
Honcentr ciL inn (ua/L ): 8O.O Corrected Cone ,(ug/L ): 80O„
lean Cone (ua/L ): BO.6 SDs 0.87 RSDC/.): l.OB
Corrected Cone (ua/L ): BO6.
Recovery is 74.0V.
TDs B09JJ?rikSrX3— Sea. No.: OO039 A/S Pos.: 24 Dates 09/30
Sample abs. is ajK^tvr than that of the largest standard.
Dedicate 1 Time: 14:44
Concentration (ug/L ): 554.5 Corrected Cone (ug/L ): 2772.
5b ID; 80915.2 Sep. No.: 00041 A/S Pos.: 25 Date: 09/30
3eolicate 1 Time: 14:5O
Zoncentration (ua/L i: 14.2
2 Time: 14:53
Concentration (ua/L ): 6.9
lean Cone (ua/L ): 1O.5 SD: 5. IB RSDC/.): 49.1
-------
Sb ID: 80915. 2D
Replicate 1
Concentration (uq/L ): 5.8
Sea. No.: 00042 A/S Pos . : 26 Date: 09/30
Time: 14:56
Concentration (uq/L )s 3.1
lean Cone (ua/L ): 4.5
Time: 15:OO
SD: 1.93
RSDT/.): 42.9
3b ID: 80915.3
^eolicate 1
Concentration (ua/L ): 6.9
Sea. No
Concentration (uo/L ): 7.7
lean Cone (uq/L ):
00043 A/S Pos
Time: 15:03
Time: 15:06
SD: O.55
27 Date: 09/30
RSDC/.): 7.57
5b ID: CCV Sea. No.: 00044 A/S Pos.: 3 Date; 09/3O
^eolicate 1
Concentration (uo/L ): 87. 7
Time: 15:O9
Time: 15:13
Concentration (uq/L ): 89.2
J
lean Cone (ua/L ): 88.5 SD: 1.1O
3C samole is within range 79.5 - 120.49
RSDC/.)! 1.24
3b ID: CCB
Concentration (uq/L ): 1.2
^eolicate 2 -
Concentration (uq/L ): 2.0
Seo . No.: 00045 A/S Pos.
Time: 15:16
Time: 15:19
lean' Cone (uq/L ): 1.6 SD: 0.59
3C samole is within ranae -15.49 - 15.49
Date: 09/30
RSD(X): 36.2
-------
-lement File: AS . GEL Element: As . Wavelength: 193.
Date: 09/29/98 Time: 1O:20 Slit: CK70 L
Data File: 8O911CUN.DAT ID/Wt File: S0911.IDW Lamp Current: 0
Techniaue: HGA Calib. Type: Nonlinear Energy: 34
As TD: BLANK Sea. No.: OO071 A/S Pos . s O Date: 09/29
Reclicate 1 Time: 1O:2O
Peak Area (A-s): O.O1O Peak Height (A): O.O34
Backoraund Pk Area ( A~s ) : O.133 Background Pk Height (A): O.101
Blank Corrected Pk Area (A-s)s O.O14
Concentration (ug/L ): 5.46
cate 2 Time: 1O: 23
Peak Area < A-s ) : O.019 Peak Height (A): O.O3O
Background Pk Area (A-s); O.123 Background Pk Height (A): O.O88
Blank Corrected Pk Area (A-s): 0.022
Concentration (ua/L ): 8.81
Mean Cone (ua/L ): 7.14 SD : 2.368 RBD ( 7. ) : 33.1
Auto-zero performed.
As ID: BLANK Sea. No.: 00070 A/S POB.: 0 Date: 09/29
Replicate 1 Time: 1O:26
Peak Area (A-s): 0.007 Peak Height (A): O.O2B
Background Pk Area (A-s): 0.133 Background Pk Height (A): 0.08B
Blank Corrected Pk Area (A-s): -O.O07
Concentration (ug/L ): -3.01
icate 2 Time: 10:29
Peak Area (A-s): -0.006 Peak Height (A): O.O27
Backaround Pk Area (A-s): O.148 Background Pk Height (A): O.096
Blank Corrected Pk Area (A-s): -O.O21
Concentration (ug/L ): -8.39
Mean Cone (ug/L ): -5.70 SDs 3. 805 RSD(7.): 66.7!
Auto-zero oerf armed .
As ID: 10 PPB AS Sea. No.: OOO71 A/S Pos.: 1 Date: 09/29.
Replicate 1 Time: 10:33
Peak Area (A-s): O.O36 Peak Height (A): O.07O
Background Pk Area (A-s): 0.137 Background Pk Height (A); O.094
Blank Corrected Pk Area (A-s): 0.035
Concentration (ug/L ): 14.27
2 Time; 1O:36
Peak Area (A-s): O_O43 Peak Height (A)s 0.077
Background Pk Area ( A-s ) s O.136 Background Pk Height (A)j O.O88
Blank Corrected Pk Area (A-s): 0.042
Concentration (ua/L ): 17.OO
-------
•lean Cone (ua/L ):
15.63
SD: 1.930
RSD(7.): 12.35
Standard number 1 applied. flO.OO]
Correlation coef f icient: l.OOOOO
ID: 50 PPB AS
Seo. Na,
Slope: O.OO39
OO072 A/S Pos.: 2 Date: 09/29/
Reolicate 1
3eak Area < A-s ) : O.154
5ackoround Pk Area (A-s): 0.150
Blank Corrected Pk Area (A-s): 0.153
Concentration (ug/L ): 39.66
3eak Area (A-s): 0.142
3ackoround Pk Area (A-s): 0.156
31ank Corrected Pk Area (A-s): 0.142
Concentration (ua/L ): 36. 6B
Time: 10:39
Peak Height (A): 0.234
Background Pk Height (A): 0.085
Time: 10:42
Peak Height (A): 0.228
Background Pk Height (A): O.081
lean Cone (ua/L ):
38.17
Standard number 2 aoplied. T.50.OO]
Correlation coefficient: l.OOOOO
3D: 2.107
Slope: 0.0042
RSD(X): 5.52
ID: 100 PPB AS
Sen . No.
O0073
A/S Pos.: 3
Date: 09/29/
3eak Area (A-s): 0.291
packground Pk Area (A-s): 0.158
Blank Corrected Pk Area (A-s): O.291
Concentration (ug/L ): 165.79
Time: 10:4£>
Peak Height (A): 0.437
Background Pk Height (A): O.OB3
Characteristic Mass = 15.1 oa/0,0044 A-s
=eak Area (A-s): 0.320
Background Pk Area (A-s): O.153
Blank Corrected Pk Area (A-s): 0.319
Concentration (ua/L ): 21O.73
Time: 1O:49
Peak Height (A): 0.431
Background Pk Height (A): 0.089
Cone (uo/L ):
186.61
SD: 31.776
RSD ('/.): 16.88
5-shaoed calibration curve detected. 2-coef. equation used.
Standard number 3 applied. r.100.00]
Correlation coefficient: 0.99089 Slope: O.OO3S
ID: 20O PPB AS
Sea. No.: O0074
A/S Pas.: 4
Date: 09/29/
^eolicate 1
Peak Area (A-s): 0.632
Backaround Pk Area (A-s)I 0.166
91ank Corrected Pk Area (A-s): 0.631
Concentration (ug/L ): 338.50
Time: 10:52
Peak Height (A): 0.834
Background Pk Height (A): O.O91
i.cate
Time: 10:56
-------
3eak Area s ID: 80911.RB-1
=?eolicate 1
Zoncentration tuq/L ): 4.54
Sea. No.: OOO77 A/S Pos.: 6
Timei 11:15
Date: 09/29/
-------
-5 ID: 8O911.O1-2A Sea. No.: OOO9S A/S Pos.: 16 Date: 09/29/
eolicate 1 Time: 14:OO
oncentration (ua/L ): B7.25
f=olic=)te 2 "Time: 14:O3
oncentration : \ SB.49 SD: 1.753 RSDC/.): 1.98
\
ecoverv is 85.. 87.
<; ID: 80911,02-2A SBO . No.: OOO99 A/S Pos.: 17 Date: O9/29/
eolicate 1 Time: 14:O6
oncentration (ug/L ): 5.39
s?Dlicate 2 \ Times 14:09
oncentration (ug/L ):X4.87
ean Cone fua/L )i 5.13 SD: 0.373 RSDC/.): 7.27
s ID: S0911.03-2A Sea. No.: OO10O • A/S Pos.: 18 Date: 09/29/
eolicate 1 Time: 14:13
oncentration (ua/L ): 1.13
eolicate 2 Time: 14:16
.oncentration (ua/L ): 6.45
lean Cone fuq/L ): 3.79 SD: 3.761 RSDC/.): 99.16
is ID: BO9H.I1-2A Sea. No.! 00101 A/S Pos. : 19 Date: O9/29/
leolicate 1 Time: 14:19
Concentration (ug/L ): 5.28
Eolicate 2 x Time: 14:22
loncentration (Ua/L ): 9.31
la/L
lean Cone (ua/L ): 7.29 SD: 2.851 X RSDC/.): 39.09
»«V
-------
PERKIM-ELMER
Mil 00
98/09/29
PAGE 2
HSfl DISPLAY CfiLIBRflTION MODE
ELEMENTi HG - PEAK HEIGHT
0.242
ABB.
SI
S3
PRINTER; ON
B6 CORR: ON
UNITS .• UG/L
CH.MflSS:
S4
10,06
PEAK AREA (fl-SJ
S5 AA-BG: 3.965
EG: 0,008
PEAK HEIGHT (ft)
AA-BG! 0,242
BG: -0.001
CONCENTRATION
-------
PERKIN ELMER
M 1100
98/O9/29
PAGE 4
HB o ^-.
MAIN! 0.00 UG/L
AA-B8 BG HB
F:'A O.OO1 -O.O10 MAIN:
PH O.OOO -0.002
0.05 LIB XL
AA--BG EG
PA O.046 0.004
PH O.OO1 -O.001
0.96 UB/L
HG
MA I Ms
HB
MAIN: 0.13 UB/L
AA-BG EG HG
PA O.420 -0.001 MAIN: O.BO UG/L
PH 0.023 -0.003
AA-BE EG HG
PA 0.060 0.004 MAIN; 0,13 UG/L
PH 0.003 -0.001
AA-BB BG
PA 0.390 -0.039
PH 0.019 -0.002
AA-BG BG
PA 0,073 -0.008
PH 0.003 -0.001
HG 1
MAIN:
r.^-3,£]
0.02
I
UG/L
PA
PH
AA-BG
0.045
0.000
B
0,,
-0 .
IB HG
002 MAIN:
002
<:^\J
4.83
UG/L
PA
PH
AA-BG
2. OBI
0. 116
BB
0.012
-0.001
HG £ C
MAIN; -0.03 UG/L
HG F&-2J2
MAIN? 0.03 UG/L
HB
MAIMJ
0.05 UG/L
AA-BG
PA-0.039
PH-0.001
AA-BG
PA-0,000
PH 0.00I
AA-BG
PA 0,022
PH O.OOi
BG
0.004
-0. 001
BG
-0.034
-0. OO3
BB
•-O.O09
-0. 002
HG
MAIN: O.OB UG/L
HB
MAINs 0.03 UG/L
HG
MAINs 0.07 UG/L
AA-BG BG
PA O.029 -0.006
PH 0.002 -0.002
AA-BG
PA-0.014
PH O.OOI
AA-BG
PA O.O03
PH O.O02
BG
-0.009
-O.OOI
BG
•O.OO6
-O.OOO
MAIM: 0.55 UG/L
HG if
MAIN: 0.61 UG/L
HB
MAIN;
0.30 UG/L
AA-BG
PA 0.248
PH 0.013
AA-BG
PA 0.237
PH 0.015
AA-BG
PA 0.162
PH 0.007
BG
-0. 006
-0.002
BG
-0.029
-0,, 003
BB
0.021
0.001
HG US
MAIN: 0.65 UG/L
HG
MAIN:
HG
MAIN:
l&
5.79 UB/L
-X£
0,61 UG/L
AA-BG
PA 0.288
PH 0.016
AA-BG
PA 2.503
PH 0.140
AA-BG
PA 0.22S
PH 0.015
BG
0.006
-0.000
BG
O.0.16
-O.OOI
BG
-0.007
-0.002
HG 3
MAIN; 0.50 UG/L
H6
MAIN;
4.51 UG/L
AA-BB
PA 0.241
PH O.OI2
AA-BS
PA 2.010
PH 0.109
BG
0.012
-0*O01
BB
0. O60
0. 00.2
HB
MAIN:
HG
MAIN:
0,56 UG/L.
'^3T~~
-0.03 UG/L
AA-BG BG
PA 0.281 -0.020
PH 0.014 -0.002
AA-BG BG
PA--0.049 -0.036
PH-0.001 -O.O04
-------
3MA 4OO Analysis V/er. 4.1O Tue 09/29/98 - 15:34:08
nod File Name: NI
arks: NI ONLY
*lt file is 80911
ni231
"ANDARD 41= 1
ni231
"AWDPfcRD 4* 1
ni231
ni231
rti231
ni231
ni231
ni231
"^ND^RD 4*2
ni231
ni231
™ ^^ BV.B v\ i^^. i _-• in"\ «*^ ^"j'
•""^ • ^9 M-J^ r*~M m^^ m-J "^T »— J
ni231
ni231
'ANDARD 4*3
ni231
ni231
ni231
ni23l
•^MOftRD 4*-*
ni231
*=*MO*=lRD 4*4
EM
EM
EM
EM
AV
EM
EM
EM
EM
AV
EM
EM
EM
EM
AV
EM
EM
Repl icates:4
692
REF*!— T C«==iTE
691
•^^ ^^^ fT^ I *f f'm* i^^^ T^™ C^r
• ~*^ L^K • L^_ ^L ^«ij*- ^~^B • ^^«>
689
REF>I_ I CftTE
694
691.5 SD 2.1
1185
1200
1240
1286
1227.8 SD 45.2
1855
REF>I_ I GATE
1823
REF>L_ I GATE
1873
REF"I_ I Crf=fcTE
1878
1857.3 SD 24.9
3069
3181
REF>L_ I CftTE
Read Delay: 65
Data File:
4*1 1537 9/29/98
4*2
4*3
peak-noisy
4*4
cv 0.3 COM; o.iooo
4*1 1539 9/29/9B
4*2
4*3
4*4
CV 3.7 CDNC 0.5OOO
4*1 1541 9/29/98
4*2
4*3
4*4
cv 1.3 COM: i.oooo
4*1 1543 9/29/98
4*2
4*3
-------
AND*
=*R:D 4*-* REF-L I CftTE 41=-*
ni231 EM 3604
ni231 AV 3228.5 SD 256.3 CV 7.9 CONC 2.OOOO
•*•*"*
^•MK
.AIMK
ftMK
FSE:F>L_ i C*=*TE 4* i 1545
ni231 EM 592
R:EF=-L_ I C«TE 41=2
ni231 EM 601
ni231 EM 583
REF>I_ I GATE 41=**
ni231 EM 685
9/29/98
ni231 AV 615.3 SD 47.1 CV 7.7 CONC O.OOOO
ni231 CC 0.9996 SLOPE 1315.8527 INT 576.6360
ni231
ni231
ni231
ni231
ni231
B
ni231
B
ni231
B
ni231
i _^T.....i -•
ni231
— 1
ni231
REF*1_ I CftTE 41=1 1547
EM 1833 0.9548 mg/L
EM 1828 0.9510 mg/L
REF*1_ I CftTE 41=3
EM 1823 0.9472 mg/L
REF*I_ I CftTE 4*-*
EM 1854 0.9707 mg/L
ni231 AV 1834.5 EM SD 13.6 CV 0.7
ni231 AV 0.9559 mg/L SD O.01O4 CV 1.O8
REF»1_ I CftTE 4*1 1549
EM 593 0.0124 mg/L peak-noisy
EM 600 O.0178 mg/L peak-noisy
EM 601 O.0185 mg/L peak-noisy
I^K^I^l T f^£±~W~f^" •**• -^*
v^^ ^^^ • • JL ^_^^ F^v • ~ T^ " w
EM 597 0.0155 mg/L peak-noisy
ni231 AV 597.8 EM SD 3.6 CV 0.6
ni231 AV O.O16O mg/L SD 0.0027 CV 17. O2
REI^I—ICftTE 4*1 1551
EM 594 0.0132 mg/L peak-noisy
EM 601 0.0185 mg/L
9/29/98
9/29/9S
9/29/98
-------
ni231 EM
*—:
ni231 EM
B—:
ni231 EM
ni231
ni231
XV
ni231
ni231
ni231
ni231
ni231
ni23i
ni231
EM
ni231 EM
EM
EM
ni231
ni231
EM
EM
EM
EM
ni231
ni231
EM
L_Ei
EM
EM
ni231
ni231
15
ni231
ni231 EM
ni231
ni231
IS _ 1
ni231 EM
590
591
F£EF>-i_ i cftT
O.O102 mg/L
6O9
AV 605.8 EM
AV O.O221 mg/L
1963
1830
1937
4*3
peak-noisy
peak-noisy
I Cl=fcTE *-*
O.O246 mg/L peak-noisy
0.01O9 mg/L
SD 20.2 CV
SD 0.0153 CV
REF=-l_ I
1.0536 mg/L
3.3
69.23
1633 9/29/98
0.9525 mg/L
1.0718 mg/L
I CftTE #-*
1899
AV
AV
609
612
598
607
AV
AV
603
582
573
592
AV
AV
1 . O049
1919.8 EM
1.O207 mg/L
O . O246
0 . O269
0.0162
FtEF>l_
0.0231
606.5 EM
O.O227 mg/L
FEEI=-l_
0 . 0200
O.OO41
REF*l_
-0 . 0028
0.0117
587.5 EM
O.OO83 mg/L
mg/L
SD
SD 0.
mg/L
mg/L
mg/L
mg/L
SD
SD 0.
mg/L
mg/L
mg/L
I CftTE
mg/L
SD
7O.4 CV 3.7
0535 CV 5.24
4*1 1635 9/29/98
peak -noisy
peak-noisy
4*3
peak-noisy
4*-*
peak-noisy
6.O CV l.O
OO46 CV 2O. 18
4*1 1637 9/29/98
peak -noisy
4*3
peak-noisy
4*3
peak-noisy
4*-*
peak-noisy
12.9 CV 2.2
SD O.OO98 CV 118.95
768
REI=-l_ I CftTE 4*1
0.1454 mg/L
1639 9/29/98
-------
ni231
EM
768
O.I454 mg/L
. ±
ni231
EM
. ±
ni231
ni231
ni231
EM
ni231
ni231
IS
EM
. IS
EM
. ±S
ni231
ni231
ni231
ni231
ni231
ni231
EM
EM
ni231
ni231
EM
22
EM
EM
EM
ni231
ni231
ni231
ni231
ni231
ni231
EM
EM
EM
ni231
EM
ni231
ni231
EM
771
REP^L. i
0.1477 mg/L
REF^L. I
737
AV
AV
3241
3139
3479
3310
AV
AV
806
O
761.0
O.1401
R
2
F>
1
R
2
2
3292.3
2.0638
R
0
. 1219
EM
mg/L
EF»I_
.0248
EF*I_
.9473
El=l_
.2057
.0773
EM
mg/L
EF»I_
.1743
mg/L
SD
SD
IC«T
mg/L
>^r ^^^^ i^^^. ^^r
J. ^— ^J~™1 •
mg/L
O.'
E
'E
XOftTTE
mg/L
mg/L
SD
SD
ICrf=*T
mg/L
E
1
0.
E
REF»L I CftTE
760
O
.1393
IREFUL
788
780
AV
AV
0
R
0
783.5
0.1572
.1606
EF»I_
.1545
EM
mg/L
mg/L
IC^T
mg/L
lOftT
mg/L
SD
SD
E
E
O.I
peak-noisy
**-*
peak—noisy
16.1 CV
O.O122 CV
*±
2.1
8.71
1641 9/29/98
#3
**-*
142.9 CV
O.1O86 CV
**±
4.3
5.26
1643 9/29/98
peak-noisy
4*3
703
744
746
R=EF=-|_ I
0.096O mg/L
19.1 CV
O.0145 CV
4*±
2.4
9.22
1644 9/29/98
0.1272 mg/L
REF=-|_ I
0.1287 mg/L
peak-noisy
peak-noisy
746
REF>I_ I CftTE **-*
0.1287 mg/L peak-noisy
AV
AV
728
734.8 EM SD
0.1202 mg/L SD
REF>I_I
O.I 150 mg/L
21.2 CV
0.0161 CV
2.9
13.40
**± 1646 9/29/98
peak-noisy
REF>L X
-------
ni231 EM
ni231 EM
ni231
ni231
0>
ni231 EM
V
ni231 EM
V
ni231 EM
765 0.1431 mg/L
762 0.1409 mg/L
AV 753.O EM SD
AV 0.1340 mg/L SD
1813
1738
1786
REF»I_ I
0.9396 mg/L
0.8826 mg/L
0.9191 mg/L
peak-noisy
*=-*
peak-noisy
17.O CV
0.0129 CV
ni231 EM 1763 0.9016 mg/L
ni231 AV 1775.O EM SD 32.O CV
ni231 AV O.9107 mg/L SD O.O243 CV
2.3
9.S3
1648 9/29/98
1.8
2.67
ni231
ni231
EM
EM
ni231 EM
587
632
584
O.0079 mg/L
REF*1_I
0.0421 mg/L
0.0056 mq/L
165O 9/29/98
peak-no
peak-noisy
#3
peak-noisy
ni231 EM 583 O.OO48 mg/L peak-noisy
ni231 AV 596.5 EM SD 23.7 CV 4.O
ni231 AV 0.0151 mg/L SD O.O180 CV 119.45
-------
SMA 400 Analysis Ver. 4.1O Wed O9/3O/98 - 13s43:52
hod File Name: P
arks:
Repli cates:3
Read Delay: 65
Data File:
Wt file is 80915
FANDARD 4*1
P214
FANDARD #1
P2i4
FANDARD 4*1
P214
P214
FAIMDARD 4*2
P214
FANDARD 4*2
P214
FANDARD 44=2
P214
P214
FAIMDARD 4*3
P214
PAIMDARD 4*3
P214
PAIMDARD
P214
P214
4*
P214
#
P214
-AIMK
ANK
P214
P214
P214
P214
EM
EM
AV
EM
EM
444
630
&33
EM 449
EM
EM
AV
EM
EM
EM
AV
EM
EM
EM
AV
EM 1563
i GATE:
I C ATE
1 1348 9/3O/9B
peak-noisy
peak-noisy
REF>I_ I GATE
440
444.3 SD 4.5
I GATE
I GATE
I GATE
CV 1.0 CONG 0.2OOO
4* 1 1350 9/30/98
616
626.3 SD 9.1
REF>L_ I GATE
859
REF>1_ I GATE
867
REF>L_ I GATE
851
859.0 SD 8.0
I GATE
CV 1.4 CONC 1.0000
4* 1 1352 9/30/98
CV
REF>L_ I GATE
1594
REF*L_ I GATE
1614
159O.3 SD 25.7
I GATE
4*2
4*3
CV
4* 1
418
R:
406
O.9 CONC 2.0OOO
1354 9/30/98
1.6 CONC 5.00OO
135& 9/3O/98
I GATE 4*2
-------
P214
P214
P214
P214
P214
EM
EM
EM
P214
P214
EM
EM
P214 EM
P214 AV
P214 CC
863
863
419
414.3 SD
O.9997 SLOPE
REF>l_I
1.9612 mg/L
REP-LI
1.9612 mg/L
RER-I—I
2.4042 mg/L
7.2 CV 1.7 CDNC
237.0154 INT 398.1614
o.oooo
** A
1358 9/3O/98
968
AV 898.O EM SD
AV 2.1O89 mg/L SD
60.6 CV
0.2558 CV
398
400
RETF*!— I
-0=0007 mg/L
=» ±
6.8
12.13
1400 9/30/98
REF*I_ I
0.0078 mg/L
peak-noisy
>
peak-noisy
'> -0.0133 mg/L
397.7 EM SD
-O.OO21 mg/L SD
0.0120 mg/L
peak-noisy
2.5 CV 0.6
0.01O6 CV 508.66
4*± 14O2 9/3O/9B
peak-noisy
- I—B
EM
EM
P214
P214
. 1
EM
. 1
EM
. ±
EM
P214
P214
REF>I_ I Crf=fcTE
401 O.0120 mg/L
REf=*I_ I C^TE
398 -O.0007 mg/L
AV 4OO.O EM SD
AV O.OO7S mg/L SD O.
REF-L. I C*=lTE
60S 0.8853 mg/L
REF>I_ I C(=fcTE
612 0.9022 mg/L
613 O.9064 mg/L
AV 611.O EM SD
AV O.898O mg/L SD O.
peak-noisy
: 4*3
window-edge
1.7 CV 0.4
OO73 CV 94.21
4*± 14O4 9/3O/98
peak— noisy
*=>
»3
2.6 CV O.4
0112 CV 1.24
1.O457 mg/L
REF^L.1
0.9993 mg/L
41= ± 14O6 9/3O/98
peak-noisy
peak-noisy
-------
SIS
P214
315
P214
315
P214
315
P214
315
P214
315
P214
«/
P214
J
P214
y/
P214
P214
P214
EM
EM
EM
P214
P214
i - 3
EM
EM
EM
P214
P214
EM
EM
EM
P214
P214
AV 637.7 EM
AV 1.0105 mg/L
RE:F=-I_
603 0.8642
587 0 . 7967
673 1.1596
AV 621.0 EM
AV O.9402 rog/L
601 0.8558
603 0 . 8642
SD 7.4 CV 1.2
SD O.0311 CV 3. OB
. I CftTE 4* 1 14OS 9/3O/9B
mg/L
mg/L
mg/L peak-noisy
SD 45.7 CV 7.4
SD 0.193O CV 20.53
XCftTEI 4*1 141O 9/30/9B
mg/L
mg/L
REF>L_ i C^TE: 4*3
610 0.8938 mg/L
AV 6O4.7 EM
AV O.8713 mg/L
948 2.3198
REIF»I_
954 2.3452
958 2.3620
AV 953.3 EM
AV 2.3423 mg/L
SD 4.7 CV O.B
SD O.O199 CV 2.29
IC^TE: 4*1 1412 9/30/93
mg/L
It~*£±~r^m i*^^
^M»B^^ P " ^^ -"^
mg/L
mg/L
SD 5.O CV 0.5
SD O.0212 CV 0.91
P214
P214
P214
EM
EM
EM
P214
P214
400
402
I GATE! 4*1 1414 9/3O/98
O.O078 mg/L peak-noisy
4*2
peak-noisy
i CATE: 4*3
O.O289 mg/L peak-noisy
O.O162 mg/L
405
AV 402.3 EM SD
AV 0.017G mg/L SD
2.5 CV
0.0106 CV
0.6
60.32
-------
lament File: SE.GEL
•ates 10/01/98
»ata File:
'echniaue: HGA
Element: Se
Time: 14:44
ID/Wt File: BO911.IDW
Calib. Type: Linear
Wavelengths 196.0
Slit: 2.00 L
Lamp Current: O
Energy s 36
ID: 0 PPB
Sea. No.: OO1OB
eolicate 1
eak Area (A-s): -0.006
.ackground Pk Area (A-s)s 0.146
lank Corrected Pk Area (A-s): -Oi006
eplicate 2
eak Area (A-s): -O.OO2
ackaround Pk Area (A-s): 0.153
lank Corrected Pk Area (A-s): -O.002
ean Pk Area
-------
orrelation coef1icient: 0.99489
Slooe: O.OO20
ID: 50 PPB
Sea . tic .
ealicste 1
esk Area ;ft-sl: 0.093
sckarour.ci P'- Area fA-si: O.i77
laiM- Corrected Pv, Are= (A-s): 0.097
oncentration iuq/L ): 49.12
s? n 1 i 17 A 11? 2
eak Area (A-s): 0.094
ackaround Pk Area (A-s): 0.175
lank Corrected Pk Area (A-s): 0.098
oncentration (ua/L ): 49.52
ean Cone (ua/L ):
49.32
tandard number 3 applied. C50.00]
orrelation coefficient: O.99923
00111
Date: 1C/O1.
Ti.Tie: 15:03
Peak Heiqnt (A): 0.128
Background Pk Height (A): O.O85
Time: 15:07
Peak Height (A): O.127
Backaround Pk Heiaht (A): O.O8O
SD; O.2B7
Slooe: O.0020
RSD ('/.): 0. 58
ID: 100 PPB
Sea. No.: 00112
eolicate 1
eak Area (A-sJ: 0.187
ackground Pk Area (A-s): O.19O
lank Corrected Pk Area (A-s): 0.192
oncentration (uq/L ): 97,81
eoli cate 2
eak Area (A-s): 0.168
ackaround Pk Area (A-s): O.197
lank Corrected Pk Area (A-s): 0.172
oncentration (ua/L ): 87.71
ean Cone (ua/L ):
92.76
tandard number 4 applied. C10O.OO]
orrelation coefficient: 0.99833
A/S Pas.: 4
Date: 10/O1/
Time: 15:10
Peak Height (A)s 0.236
Backaround Pk Height (A): O.O97
Time: 15:13
Peak Height (A): 0.212
Backaround Pk Heiaht (A): 0.096
SD: 7.137
Slope: O.O019
RSD C/.): 7.69
-------
-Tjfe-
!
?. <*£-
«
i
i
a.
LsSiay falilrition - £;\M ilSlS/USi)
^-"'£3"
i2fr*"x
_yr"
x--""*
+
fj«p«: 0.0021
o Cone«n*rot3on too. 00
*
i
ID: ICV
Sea. No.: 00113 A/S Pos,
Concentration (uq/L 1: 50.05
Reol icate 7
loncentration (ua/L i: 47.30
lean Cone (uo/L ) :, 48.67
|3C samole is within ranae
Time: 15;21
Time: 15:24
SD: 1.94&
Date: 1O/O1
RSD < V.) : 4. OO
ID; TCB Sea. No
icate 1
Concentration (ua/L Is 4.83
^en,1 icate 2
Zoncentration (ua/L ): 0.95
lean Cone (ua/L ); 2.88
3C samole is within ranae
00114 A/S Pas,
Time: 15:28
Time: 15:31
SDs 2.746
Date: 10/01
RSD C/.): 94.9
TDi 8091. 5. LB
icate 1
Concentration (ua/L ): 3.02
icate 2
"oncentration (uo/L ): 0.6O
Sea. No.: OO115 A/S POB.: 22 Date: 10/01-
Time: 15:34
Time: 15:37
"lean Cone (ua/L ):
IDs 90915.1
1 .81
SD: 1,710
RED('/.); 94.5:
* *\* "V *V "V *V*V*V *\^ *V *V *V '^ ^ ^* ^ ^^ »i^ *V^^ *V ^^*V ^ *V^w ^* ^ *V *V ^J ^'W ^f ^f ?\i ^ t *^ ^ ^* ^ 'W ^ ^ ^^» ^ ^ *
Sea. No.: O0116 A/S Pos.: 23 Date: 10/O1>
^eolicate 1
Time: 15:41
-------
oncentration (uo/L ): 78.1O
eolicate 2
oncentration (uo/L ): 73.35
ean Cone (uq/L ):
75.72
Time: 15:44
SD: 3.361
RSD(7.>: 4.44
ID: 80915.1
Seo. No.: 00117 A/S Pos.: 23 Date: 10/Oi/
amole abs. is Greater than that of the largest standard.
eolicate 1 Time: 15:47
concentration (ua/L )s 116.21
ealicate 2
oncentration *V -V *
Sea. Mo
enlicate 1
oncentration (uo/L ): 62.25
eolicate 2
oncentration (ua/L ): 50.62
SD: 2.286 RSDT/.): 3.30
00119 A/S Pos.: 26 Date: 10/01/'
Times 16:OO
Time: 16:03
ean Cone (ua/L ):
60.43
SD: 2.565
RSD (7.): 4.25
<= TD: 90915.3
enl i cate 1
oncentration (uo/L ): 63.69
Sea. No.
icate 2
oncentration (uo/L ): 66.33
ean Cone (uo/L ):
65.01
OO120 A/S Pos.: 27
Time: 16:07
Times 16:10
SD: 1.86B
Date: 10/01/<
RSD(7.): 2.87
R ID: CCV
eolicate 1
Sea. Mo.: OO121 A/S Pos.: 3
Time: 16s13
Date: 10/01/<
-------
concentration (ua/L ): 46.68
poll rate 2 Time: 16:17
concentration (ua/L ): 50. O3
lean Cone (ua/L ): 48.35 SD: 2.369 RSD ( 7. ) ; 4.90
1C samnle is within ranae
ie TD: CCB Sea. No.: O0122 A/S Pos . : 0 Date: 1O/01
(eolicate 1 Time: 16:20
:oncentration (ua/L ): 3.55
2 Time: 16:23
'oncentration iuo/L ); 0.12
lean Cone (ua/L ); 1.92 SD: 2.424 RSDC/.)s 132. «
3C samole is within ranae
-------
:iement File: AG.GEL
•ate: 10/O2/98
'ata File:
'echniaue: HGA
Element: Aq
Time: 1O:28
ID/Wt Files 8O911.IDW
Calib. TYDBS Linear
Wavelength: 328.J
Slit: 0.7 L
Lamo Currents 1O
Energy: 56
>a
ID: BLANK
Sea. No.: 00002
ieolicate 1
'eak Area (A-s): 0.094
Jackqround Pk Area (A-s): 0.026
Jlank Corrected Pk Area (A-s):. 0.094
!eak Area (A-s): 0.096
Jackground Pk Area (A-s): 0.04.5
31ank Corrected Pk Area (A-s): 0.096
lean Pk Area fA-s):
performed.
0.095
A/S Pas.: O
Date: 10/02/
Time: 10:28
Peak Heiaht (A): 0.084
Background Pk Height (A): 0.025
Time: 10:31
Peak Heiaht
-------
TO: 1O PPB AG
Sea. No.
00005
A/S Pos.z 2
Date: 10/O2
Jenl icate 1
>eak Area (A-s): 0,278
lackoround Pk. Area (A-s): 0.057
Jlank Corrected Pk Area (A-s): 0.1B3
Concentration (ua/L ): 9.77
Time: 1O:47
Peak Height (A): O.245
Background Pk Height (A): O.O32
'en 1 icate 2
5eak Area (A-s): G.2S2
Jackaround Pk Area (A-s): O.060
Jlank Corrected Pk Area (A-s): O.187
roncentration (ua/L ): 10.Ol
Time: 1O:5O
Peak Heiaht (A): O.245
Backaround Pk Heiaht (A): O.O35
lean Cone (ua/L )
9.89
Standard number 2 applied. FlO.00.1
Correlation coef1icient: 0.99998
SD: 0.167
Slooes 0.0185
RSD C/.): 1.69
Int: 0.000
ID: 2O PPB A6
Sea. No.: OOO06 A/S Pos.: 3
Date: 10/02*
icate 1
aeak Area (A-s); O.455
3ackaround Pk Area (A-s)s O.O71
Blank Corrected Pk Area (A-s): 0.360
Concentration (ua/L ): 19.46
Time: 10:53
Peak Heiaht (A): 0.399
Background Pk Height (A)s O,043
1i cate 2
Area (A-s): 0.447
3ackground Pk Area
-------
"SMsnlay Calibration - C:\fift USffi\
.526-
1 '
a
C.
.***
^'J'
,-•""*
'"^ Intercepts 9. OPS
e Cinesati'atsc.rr tp.up
*
1
ID ID: ICV
:eolicate 1
•oncentration (ua/L ): 20.77
Sen. No.: OOOO8 A/S Pos.
Time: 11:OB
Time: 11:11
;oncentration (ua/L ): 2O.72
lean Cone (ua/L ): 2O.74 SD: 0.037
1C sample is within ranae 15.5 - 24.49
ta ID: ICB
feolicate 1
)oncentration (ua/L ): 0.13
?f=ol i cats 2
Concentration (ua/L ): -0.04
Sea. No.: OOOO9 A/S Pos.
Time: 11:14
Time: 11:17
lean Cone (ua/L )
O.O4
SD: 0.117
3C samole is within ranae -5.49 - 5.49
Date: 10/02/
RSDr/.)s O.18
Date: 10/02/
RSD C/.): 267.4
in ID: 80915.LB
?eolicate 1
Concentration (ua/L )
Seo. No.:
1 i cats 2
Concentration (ua/L
lean Cone (ua/L )
-0.42
-0.3O
-0.36
00010 A/S Pos.: 22 Date: 10/02/
Time: 11:21
Time: 11:24
SD: O.OB4
in TD: 80915.1
Seolicate 1
Sea. No.:
Time: 11:27
RSD C/.): 23.40
-------
Concentration (ua/L ): l.OO
i ca te 2
Concentration (ua/L ); 0.92
lean Cone (ua/L ):
O.96
Time: 11:30
SD: O.O56
RSD(7.): 5. 83
TD: 80915.1
Concentration (ua/L ): 9.53
i rate 2
Concentration (ua'/L ): 9.78
Sea. No.: 00012 A/S Pos.s 23 Date: 10/O2
Time: 11:33
Time: 11:36
"lean Cone (ua/L ):
Recovery is 87.0"/.
9.65
SD: 0.174
RSD(7.): 1=81
ID: SO915.2
1 icate 1
Concentration tua/L
Sea. No,
1 1, cats 2
Concentration (uo/L
lean Cone (uq/L ):
): 0.49
): 0.61
0.55
00013 A/S Pos,
Time: 11:39
Time: 11:42
SD: O.OB5
25 Date: 1O/02,
RSD(7.): 15.
An ID: 8091 5. 2D
Sea. No,
icate 1
Concentration (ua/L ): 1 . OS
icate 2
Concentration (ua/L 1: O.91
Mean Cone (ua/L
1 .00
00014 A/S Pos,
Time: 11:46
T ime; 11:49
26 Date: 10/02-
: li : 52
Date: 10/O2/
Mp,ii> Ctjnc t'ua/L
): 1 . O9
1.11
Ti/ne: 11:55
SD: O.O32
RSD ('/.): 2.92
An TD: CCV
Reolicate 1
Concentration (ua/L ): 20.83
Sea. No.: O0016 A/S Pos.: 3
Time: 11:58
Date: 10/02/
-------
2 Time: 12:01
Concentration (ua/L ): 20.68
lean Cone fuo/L ): 20.76 SD: O.1O6 RSD f'/.) : 0.51
2C samole is within ranqe 15.5 - 24.49
ia TD: CCB Sea. No.: 00017 A/S Pos.: 0 Date: 10/02
?eo]icate 1 Times 12:04
"oncentration (uq/L ): -O.07
^eolicate 2 Time: 12:07
Concentration (uo/L ): -O.1Q
lean Cone fuq/L ): -O.13 SD: O.072 RSD(7.): 57.3'
3C 5amnle is within range -5.49 - 5.49
-------
lenient File: TL.GEL
ate: 10/01/98
ata File:
=chnioue: HGA
Element: Tl
Time: 12:29
ID/Wt File: B0911.IDW
Calib, Type: Linear
Wavelength: 276.8
Slit: 2.00 H
Lamp Current: 7
Energy: 45
ID: BLANK
solicate 1
Bak Area (A-s): 0.001
ackaround Pk Area (A-s): O.OO4
lank Corrected Pk Area (A~s): 0.001
eolicate 2
eak Area (A-5): O.OOO
ackaround Pk Area (A-s): -0.001
lank Corrected Pk Area (A-s): O.OOO
ean Pk Area (A-s):
uto-zero performed.
O.OO1
Sea. Na.: 00092
A/S Pos.: 0
Date: 10/01/
Time: 12:29
Peak Heiqht (A): 0.015
Background Pk Height (A): O.O11
Time: 12:32
Peak Height (A): O.013
Background Pk Height (A): 0.013
SD: O.OOO7
RSD ('/.): 120.0.
1
ID: 10 PPB TL
Sea. No.: 00093
A/S Pos.: 1
Date: 10/01/'
eplicate 1
eak Area (A-s): O.O15
ackoround Pk Area (A-s): O.O1B
lank Corrected Pk Area (A-s): O.015
eolicate 2
eak Area (A-s): O.024
ackaround Pk Area (A-s): O.O17
lank Corrected Pk Area (A-s): O.023
Time: 12:35
Peak Height (A): 0.024
Background Pk Height (A): O.O1B
Time: 12:38
Peak Height (A): 0.025
Backaround Pk Heiaht (A): O.O21
ean Pk Area (A-s)
O.O19
tandard number 1 applied. [10.001
orrelation coefficient: l.OOQOO
SD: O.OO61
Slope: O.OO19
RSD ('/.): 32 .22
Int: 0.000
1
ID; 20 PPB TL
Sea. No.: 00094 A/S Pos.: 2 Date: 10/01/c
lepl icatE 1
'eak Area (A-s): O.O42
lackaround Pk Area (A-s): O.O31
Hank Corrected Pk Area (A-s): 0.041
loncen tr ation (ug/L ): 21.54
implicate 2
'eak Area (A-s): O.O42
lackaround Pk Area (A-s): 0.O32
Hank Corrected Pk Area (A-s): 0.042
;oncentration (ua/L ): 21.B5
ean Cone (ua/L, ): 21.70
Standard number 2 applied. T20.O01
Time: 12:41
Peak Height (A): O.O43
Background Pk Height (A): 0,027
Time: 12:45
Peak Height (A): O.O38
Background Pk Height (A): 0.034
SD: 0.224
RSD ('/.): 1 .03
-------
Correlation coefficient: 0.99B9B Slope: O.OO21 Int: -0.001
Tl ID: 50 PPB TL Sen. No.: OO095 A/S Pos.: 3 Date: 10/01
1 Time: 12:46
=eak Area (A-s): 0.1OO Peak Height (A): O.O89
Backaround Pk Area (A-s): O.O73 Background Pk Height (A); O.063
Blank. Corrected Pk Area (A-s): O.100
Concentration (ua/L ): 48.58
3haracteristic Mass = 22.1 og/0.0044 A-s
^eolicate 2 Time: 12:51
?eak Area (A-s): O.O98 Peak Height (A): O.OB8
Backaround Pk Area (A-s): O.O71 Background Pk Height (A): 0.06O
Blank Corrected Pk Area (A-s): O.O9B
Concentration (ua/L ): 47.52
Mean Cone (uq/L ): 48.05 SD: 0.747 RSD ('/.): 1.55
Standard number 3 applied. [50.001
Correlation coefficient: 0.99968 Slope; 0.0020 Int: O.OOO
•\,'\/i\fnar^m^^^^f^i^f^f^nvf^r^i^rv^\j^\if\lf^i^i^i^f^
Tl TD: 1OO PPB TL Sea. No.: OQ096 A/S Pos.: 4 Date: 10/01
Replicate 1 Time: 12:54
Peak Area (A-s): 0.190 Peak Heioht (A): O.172
Backaround Pk Area (A-s): 0.136 Background Pk Height (A): 0.126
Blank Corrected Pk Area (A-s): O.189
Concentration (uq/L ): 95.55
Reolicate 2 Time: 12:58
Peak Area (A-s): O.186 Peak Height (A): 0.160
Backaround Pk Area (A-s): 0.139 Background Pk Height (A): 0.116
Blank Corrected Pk Area (A-s): 0.1B6;'
Concentration (uq/L ): 93.76 '
Mean Cone (ua/L ): 94.65 SD: 1.267 RSD(7.): 1.34
Standard number 4 applied. (I10O.001
Correlation coefficient: 0.9995O Slope: 0.0019 Int: O.002
-------
Calibration - C:\HH FIL
ID. 1*7-.
I I
t !
siopg; 'C?OOEO
190. ffff
1 IDs ICV
eolicate i
on cen trail on (ua/L ): 49.88
Sea. No.: OO097 A/S Pos.: 5 Date: 10/O1/
Time: 13:03
oncentration (ua/L ): 51. O7
ean Cone (ug/L ): 5O.47
C samole is within ranqe
Times 13:06
SD: 0.845
RSD(X)s 1.67
1 TD: ICB
en.licate 1
oncentration (uq/L ): 2.33
'eo ] i c'ate 2
Concentration (ua/L ): 1.22
Sea. No.: 00098 A/S Pos.: O Date: 10/01/
Time: 13:09
Time: 13:12
lean Cone (ua/L ): 1.78
1C samole is within ranae
SD! 0.786
RSD(7.1: 44.28
'1
IDs 80915. LB
Sea. No.:
,'eolicate 1
.oncentration (uo/L ): 0.66
leol icate 2
'.oncentration (ua/L ): 0 . 83
lean Cone (ua/L
0.75
O0099 A/S Pos,
Time: 13:15
Time: 13:18
SD: 0.116
: 22
Dates 10/01/
RSD ('/.)» 15.49
'1
ID: B0915.1
Jenlicate 1
Concentration (ua/L ): 15B19
Sea. No.: OO10O A/S Pos.: 23 Date: 10/01/1
Time: 13:22
-------
"-eolicate 2
Concentration (ua/L ): 15.59
Cone (ua/L ):
15.39
Time: 13:25
SD: 0,284
RSDC/.): i.85
\^^^-\ff^r^/^^.f^i^i^f\f^i^t^f^f^fi^i>^f^^f^f^i^1^tnaf^f^
tl ID: 80915.1 Sea. No.: OO1O1 A/S Pos. : 23 Date: 1O/O1
i Time: 13:28
loncentration (ua/L ): 64.93
Zoncentration (uq/L ): 65.71
*lean Cone fua/L ): 65.32
Recovery is 99.9"/i
Time: 13:31
SD: 0.554
RSD(7.)s Q.85
Sea. No
00102 A/S Pos.: 24 Date: 1O/O1
Times 13;35
Time: 13:38
Concentrati
Mean Cone (
SD: 0.565
RSDC/.): 3.21
fTl ID; 8O915.2 Sea. No
Replicate 1
Concentration (uo/L ); 17.57
Reolicate 2
Concentration (ua/L ): 17.70
O01O3 A/S Pos.: 25 Dates 1O/01
Time: 13:41
Times 13:44
Mean Cone (uq/L ):
17.63
SD: O.O95
RSDC/.): O.54
w "V <\* 'V 'V *
Tl ID: 80915. 2D Sea. No.:
Reolicate 1
Concentration (ua/L ): 14.73
Eeolicate 2
Concentration (ua/L ): 15.85
001O4 A/S Pos.: 26 Date: 10/O1,
Times 13:48
Time: 13:51
Mean Cone (ua/L ) :
15.29
SD: 0.792
RSDC/.)s 5.18
Tl ID: 80915.3
Reolicate 1
Concentration (ua/L' ): 14.22
Reolicate 2
Concentration (ua/L ): 14.63
Sea. No.: 001O5 A/S Pas.: 27 Date: 10/01,
Time: 13:54
Time: 13:57
-------
ean Cone (ug/L ):
14.42
SDs O.290
RBDC/.i: 2.01
Dates 10/01.
1 ID: CCV
eolicate 1
oncentration (ua/L ): 50.55
eolicate 2
oncentration (ua/L ): 48.05
Sea. No.: O0106 A/S Pos . : 3
Time: 14:O1
Times 14:O4
ean Cone (ua/L i: 49. 3O
C sample is within range
5D: 1.766
1 ID: CCB '
eolicate 1
nncen tra tion (ua/L ): -1.92
<=nl icate 2
oncentration (ug/L ): 1.95
ean Cone fuo/L ) :• 0.01
'C samnle is within ranae
Sea. No.: 00107 A/S Pos.
Time: 14:07
Time: 14;10
SD : 2.733
RSD(7.)s 3 . 58
Date: 10/01/
RSDC/.): 2093S
-------
PERKIM-ELMER
M 110O
987.10/02
PAGE 1
AA
AA
MAINs -0.001 MG/L HQ--0-000 MAIN; -0.003 MB/L HO-O.OOi
2N ME AN s-0.002 MG/L SDs 0.001 RBD: 54,4 AUTOZERD O.OOO
AA AA
MAIN: 0.051 MS/L HO 0-018 MAINs 0.053 MB/L HO 0.019
ZN MEAN; 0.052 MB/L SD: 0,002 Rt3D: 3,3 1, STANDARD 0.052 MB/L
AA AA
MAIN: O.I 16 MG/L HO 0.04.1 MAIN: 0.115 M6/L HO O.O41
ZN MEAN; 0.115 MG/L SDs O.O01 RBD: 0.9 2. STANDARD 0.115 MB/L.
AA AA
MAIN: 0.235 MG/L HO O.OO4 MAIN: 0.238 MG/L HO 0.085
ZN MEAN; O.237 MB/L BDt O.O02 RSDt 0.7 3.STANDARD 0.235 MB/L
AA AA
MAINs 0.562 MG/L HO 0.202 MAIN: 0.573 MB/L HO O.205
ZN MEAN: 0.56B MB/L SDi 0.008 RSDs 1.4 4.STANDARD 0.552 MB/L
AA AA
MAIN: 1.077 MG/L HO 0.397 MAIN: 1.076 MB/L HO 0.397
ZN MEAN: 1. . 076 MB/L 5Dr 0.001 Rf3D: 0.1 5. STANDARD O.993 MG/L
FLfiME DISPLAY CALIBRATION MODE
ELEMENT-. ZN
REPL, 0 OF 2
0,397
ftBS.
"S3
PRINTERS ON
B6 CORR: OFT
UNITS : MG/L
0.993
, READ
"^" flBS. READING
S5 flfl ; 9,397
61
CONCENTRATION (MG/L )
1.303
STATISTICS
HEnN: 1.076
SD: 3.001
RSD'I'O: 0.1
:2H2: 2.5 L/MIN OXIDAHT: 3.0 L/MIN
FLAME: C2H2-A1R
A A
O.OO4 MG/L HO 0,000
AA
MAIN: 0.. 004 MG/L HO 0,000
-------
PERK.IN-F.LMER M HOC 98/10/02 PAGE 2
AA AA
MAIN? 0.505 MB/I. HO 0,202 MAIN: 0.510 MG/L HO 0.204
ZW MEAN; 0.507 MG./L SDc 0.003 RBD: 0,7
AA AA
MAINs O.OOi MB/L HO 0,000 MAIN; -O.OOO MB/L HO-O.OOO
ZN f vy^-IEANs; O.OOO MB/L 3D: 0.001 RSD: 99.9
AA AA
MAIN: 0.119 M3/L HO 0..04S MAIN: O.OB6 MS/L HO O..035
ZN $£,~-\ MEAN; 0,103 MG/L SDs 0.023 RSDs 22.7
AA AA
MAIN; 0.094 MG/L HO 0.03S MAIN: O.093 MG/L HO 0,037
ZN (2.S-\MEflNs 0.094 MG/L. SDs 0.001 RSDs 0.7
AA AA
MAIN: 0. 136 MG/L HO 0.055 MAIN: 0. .131 MG/L HO 0.052
ZN jS
-------
PERKIN-ELMER M 3.100 9B/ 10/02 PAGE 4
A A A A
MAIN: 0,204 MG/L HO 0.081 MAIN: O.233 MS/L HO 0.093
ZN Ol-I^I MEANs 0.21B MB/L BD; 0. O20 RSD: 9.4
Aft AA
MAIN: 0.21B MB/1,. HO O.OB7 MAINs 0.187 MG/L HO 0.075
ZN i> MEAN;: O.2O2 MG/L BDs 0.021 RGD: 10.6
AA AA
MAINt 0.155 MG/L HO O.O62 MAIN: 0. .1.40 MB/L HO 0,056
02-2^ MEAN: 0. 147 MG/L SD: O.Oii RBD? 7.3
A A A A
MAIN',' O.225 MB/L HO 0.090 MAIN: 0*241 MB/L HO O.O96
ZN^^l^* MEAN: 0.233 MB/L SD: 0.011 RSD." 4,, 9
AA AA
HAINt 0.175 MG/L HO 0.070 MAIN* O.177 MB/L HO O.071
MEANs 0.176 M6/L, SDt 0.001 RSD; 0.7
AA AA
MAINs 0.204 MB/L HO 0.. 081 MAIN: 0, 1B3 MB/L HO O.O73
MEANs 0.193 MB/L SDs 0.015 RSD: 7.6
AA AA
MAIN; 0.523 MB/L HO 0.209 MAINs 0.532 MG/L HO 0.213
ZN CoJ MEANs 0. 527 MB/L SD: 0.007 RSD: 1.3
AA AA
MAIN? 0,. 017 MG/L HO 0.007 MAINs O.O16 MG/L HO O.007
ZN Cd» MEAN:; 0.017 MG/L SDs 0.000 RSIDr 2.3
AA AA
MAIN: 0.014 MG/L HO 0.006 MAINs 0.021 MG/L HO 0.008
ZN t MEANs 0,018 M8/L SD: 0.005 RED: 26.0
AA AA
MAIN: O.O10 MG/L HO 0.004 MAIN: 0.009 MG/L. HO-O.OOC
MEANs 0,009 HG/L SD: O.OOO RSD: 1.8 ALITDZERD O.OOO
-------
PERKIM-ELMER M 1100 9B/10/02 PAGE 5
AA AA
O.:101 MG/L HO 0..040 MAIN: O.OSB MB/L HO 0.035
MEANs 0.094 MG/L SD: 0.009 RBD: 9.9
A A A A
MAIMs 0,. 747 MB/L HO 0.299 MAIN: 0.750 MG/L HO 0.303
ZN | MEAN-. 0.753 MG/L SD: 0.008 RSD: 1 „ O
AA AA
MAIN; O.724 MG/L HO 0.2B9 MAIN: 0.725 MB/L HO 0.29O
ZN 2- MEANs 0.724 MB/L SDc 0.001 RBD;; 0.1
AA AA
MAIN: 0.772 MG/L HO 0.308 MAINu 0.741 MK/L J-50 0,296
ZN 1> MEAN; 0.756 MG/L BDi 0,. 0"»:: H^D: ?,'/
AA AA
MAIN: 0.76D --^/L • :n ".'307
0.04O RGD; 5,,0
A A A A
0.53,5. M3/L. HO 0,204 MAIN; 0,504 MG/L HO 0.201
MEANt 0,507 MG/L BD: 0.005 RED: 1.0
AA AA
0.009 MG/L. HO-0,004 MAJNt --O.OO6 MG/L HD--O.G03
ME AN s -0.008 MG/L BDr. 0.002 RBDs 2.2.4
-------
« ID; CCB
eoli cate 1
oncentration (ug/L ): 3.71
eolicate 2
oncentration (ug/L ): 1.69
Sea, No.: O01O3 A/S Pos.
Time: 14:32
Time: 14:35
ean Cone (ug/L )
2.70
SD : 1.432
C sample is within ranae —5.49 - 5.49
Date: O9/29/1
RSD C/.): 53.06
•=, ID: SO911.I2-2A
eolicate 1
oncentration (uq/L I: 17.43
eol icate "2
on-centration (ua/L ): 18.54
Sea. No.: 001O4 A/S Pos,
Time: 14:38
Time: 14:42
20 Date: O9/29/1
;ean Cone (ua/L ):
17.99
3D: O.791
RSD ('/.) : 4 . 40
,=; TD: 80911. I3-2A
leolicate 1
loncentration (ua/L i: 17.77
icats 2
loncentration (ua/L ): 18.05
Sea. No.: 00105 A/S Pos
Time: 14:55
Time: 14:59
21 Date: O9/29/c
lean Cone fua/L ):
17.91
SDs 0.2OO
RSD(7.)s 1.12
»s TD: 8O915.LB
?en>licate 1
Concentration Cua/L ): 2.82
>eol icate 2
Concentration fum/L ): 1.99
lean Cone fuo/L ):
Sea. No.: 001O6 A/S Pos.
Time: 15:02
Time: 15:05
22 Date: O9/29<
1.40
SD: O.585
RSD < 7.1 : 24 . 3
-------
TD: B0915.1X1O
Sea. No.: OO1OB
A/S Pos.: 23
Date: 09/29
Concentration (ua/L ): 111.15
Concentration (uq/L ): 112.27
Time: 15:15
Corrected Cone (uq/L ): 1111.5
Time: 15:18
Corrected Cane (ua/L ): 1122.7
Cone (uq/L >: 111.71
Corrected Cone (uq/L ): 1117.1
Recovery is 9O.17.
SD: O.792
RSD(X): O.71
As TD: CCV
Reolicate 1
Concentration (uq/L ): 97.14
Sea. No.: OO1O9 A/S Pos.: 3
Time: 15:22
Concentration (ua/L ); 9B.41
Mean Cone (uq/L ): 97.77
QC sample is within ranae 79,5O
Time: 15:25
SD: 0.897
120.49
Date: 09/29
RSD ('/.): 0.92
As ID: CCB
Replicate 1
Concentration (uq/L ): S.61
Realicste 2
Concentration (ua/L ): 1.78
Sea. No.: OO110 A/S Pos.
Time: 15:28
Time: 15:31
Mean Cone (ua/L ): 5.20 SD: 4.825
QC samnle is within ranpe -5.49 - 5.49
Date: O9/29
RSD (•/.): 92. B«
TD: 80915.1SX5
Sea. No.: 00111 A/S Pos.: 24 Date: 09/29,
Reoli cate 1
Concentration (ua/L ): 2O6.84
Reoli cate 2
Concentration (ua/L ): 2O6.7B
Mean Cone (uq/L ): 206.61
Corrected Cone (uq/L ): 1034.0
Time: 15:58
Corrected Cone (ug/L ): 1034.2
Time: 16:O1
Corrected Cone (ug/L ): 1033.9
SDs O.O41
RSD ('/.): 0*02
As ID: 8O915.2X2
Renlicate 1
'Concentration (ua/L J:
Sea. Mo.: 00112 A/S Pos.: 25 Date: 09/29.
112.49
Time: 16:O4
Corrected Cone (ug/L ); 224.98
Reo!icate 2
Time: 16:08
-------
Concentration (ua/L ): 1O5.60 Corrected Cone (uq/L ): 211.21
lean Cone (uq/L ): 1O9.05 SD : 4.871 RSD ( 7. ) : 4.47
;orrected Cone (uq/L ): 21S.1O
<•= ID: 80915. 2DX2 Sea. No.: O0113 A/S Pos.: 26 Date: 09/29/
ieolicate 1 Time: 16:11
loncentration (uq/L )s 98.49 Corrected Cone (ug/L ): 196.97
ieolicate 2 . Time: 16:14
:oncentration (un/L ): 1O7.O8 Corrected Cone (uq/L ): 214.16
lean Cone (ug/L ): 1O2.78 SD: 6.075 ' RSDC/.): 5.91
Corrected Cone (uo/L ): 205.57
is ID: 80915.3X2 Sea. No.: O0114 A/S Pos.: 27 Dates 09/29/
?enlicate 1 Time: 16:18
Concentration (uq/L ): 1OB.69 Corrected Cone (ug/L ): 217.37
2 Time: 16:21
Concentration (uq/L ): 112.27 Corrected Cone (uq/L ): 224.54
lean Cone : 110.49 SD: 2.536 RSDC/.): 2.30
2orrected Cone (uq/L ): 220.96
vi^i^r^f^l^f^li\ff\^r^ru^f\fr^r^i\Jj^^^i^.f^f^rilar\ti^r^i^i^
><=, ID: CCV Sea. No.: 00115 A/S Pos.: 3 Date: 09/29/
?eolicate 1 Time: 16:24
Concentration (uo/L ) : 95.87
Dedicate 2 Time: 16:28
Concentration (uq/L ): 95.68
lean Cone (uq/L ): 95.77 SD: 0.136 RSD ('/.): 0.141
3C samole is within range 79 . 5O - 120.49
=*-s ID: CCB Sea. No.: O0116 A/S Pos.: 0 Date: O9/29,
^eolicate 1 Time: 16:31
3oncentration (uq/L ): 2.38
icste 2 Time: 16:34
Concentration (uq/L ): 0.63
Mean Cone (uq/L ): 1.51 SD: 1.237 RSDC/.): 82. 1J
QC sample is within ranoe -5.49 - 5.49
-------
SMA 4OO Analysis Ver. 4.1O Wed O9/30/98 - 13:01:58
hod File Name: BA
arks: BA ONLY
Wt file is 80915
BA45S
BA455
BA455
BA455
r*=lNE>*=lRE> 4*2
BA455
FAIMI>tf°kRD 4*2
BA455
FANDARD 4*2
BA455
BA455
FANDARD 4*3
BA455
FANDARD 4*3
BA455
r<=kMDftRD 4*3
BA455
BA455
FAMDARD 4*-*
BA455
EM
EM
EM
AV
EM
EM
EM
AV
EM
EM
EM
AV
EM
Replicatess3
163
REF*!— I C*=fcTE
166
184
171.0 SD 11.4
490
517
545
517.3 SD 27.5
REF"I_ I CftTE
939
951
REP-L- I C*=»~TE
957
949. 0 SD 9.2
1771
Read Delay: 65
Data File:
4*1 1306 9/30/9B
4*2
peak -noisy
4*3
CV 6.6 CONC 0.1OOO
4* 1 13O8 9/3O/98
4*2
4*3
CV 5.3 CONC 0.5OOO
4* 1 131O 9/30/98
4*2
4*3
CV 1.0 CONC 1.0000
4* 1 1313 9/3O/98
BA455 EM
RERL-I
1769
BA455 EM
BA455 AV
BA455 EM
BA455 EM
1824
1788.O SD
REF"L I
75
REF*!-!
7B
4*2
4*3
31.2 CV 1.7 CONC 2.OOOO
4*1 1315 9/30/98
4*2
-------
BA455 EM 75
BA455 AV 76.0 5D 1.7 CV 2.3 CONC O.OOOO
BA455 CC O.9999 SLOPE 854.50O2 INT 85.O266
REF*!— I C<=fcT
4*1
1317 9/30/98
BA455 EM 933 O.9924
mg/L
= V REF>I_ I CftTE 4*2
BA455 EM 937 0.9970 mg/L
iS/ REF=-|_
BA455 EM 975 1.0415
BA455 AV 948.3 EH
BA455 AV 1.0103 mg/L
^B REF"!-
BA455 EM 86 0.0011
-B REF=-|_
BA455 EM 90 O.O058
-B REF*!-
BA455 EM 82 -0.0035
BA455 AV 86.0 EH
'' BA455 AV O.O011 mg/L
3-915.1 REF»I_
BA455 EM 91 O.OO70
3-915- I/S? REF*I_
BA455 EM "^ S3 -0.0024
BA455 * EM 85 -0.0000
BA455 AV 86.3 EH
BA455 AV O.O015 mg/L
BA455 I 1 240 0.1814
3-91 5-1! 3 | REF>L_
BA455 E 1 ^ 244 0.186O
3-915.111 REF=-L_
BA455 EM 245 0.1872
BA455 AV 243.0 EH
BA455 AV O.1849 mg/L
• T r^^iT"^ -ff-^a
J. *^*-r-t I r^ ~ww -m^f
mg/L
SD 23.2 CV
SD O.0271 CV
2.4
2.69
I CftTE 4* 1 1319 9/30/98
mg/L peak-noisy
mg/L peak-noisy
IC#=fcTE 4*3
mg/L peak-noisy
SD 4.0 CV
SD O.0047 CV
4.7
410.91
ICl=fcTE 4*1 1321 9/30/98
mg/L peak-noisy
XOftTE 4*2
mg/L peak-noisy
Xf-jE<-f-r=- W^t
1— ff-^9 • w^ YFv^V
mg/L peak-noisy
SD 4.2 CV
SD 0.0049 CV
IOft"TE 4*1
mg/L
mg/L
IC*=»-TE 4*3
mg/L
SD 2.6 CV
SD O.OO31 CV
4.8
318.60
1323 9/30/98
1.1
1.67
BA455
'EM
57
0.2O13 mg/L
RE
4*1
4*2
1325 9/3O/98
-------
BA455
BA455
EM 274
BA455 AV
BA455 AV
» 244
0.2212 mg/L
261.O EM SD
0.2059 mg/L SD
4*3
peak-noisy
0. I860 mg/L
BA455
BA455
315
BA455
31 S
BA455
31S
BA455
efi
EM
BA455
BA455
*
•• "»
df
f
*
i
EM
S
EM ^
!
EM
BA455
BA455
t/^ 243 0.1849 mg/L
247 0. 1896 mg/L
AV 244.7 EM SD
AV O.I 868 mg/L SD O.
234 0.1743 mg/L
*^ REF>I_ I GATE
11 244 0.1860 mg/L
REF>I_ I CftTE
240 0.1814 mg/L
AV 239.3 EM SD
AV 0.1 8O6 mg/L SD O.
BA45
BA455
EM
EM
BA455
BA455
r
EM
11.5 CV
O.O135 CV
4*1
4*2
4*3
2.1 CV
0.0024 CV
4*1
5.O CV
O.O059 CV
4*1
229
235
O.1685 mg/L
0.1755 mg/L
BA455 EM 234
BA455 AV
BA455 AV
0.1743 mg/L
232.7 EM SD
0.1728 mg/L SD
3.2 CV
O.O03B CV
4*1
945
961
1.0O64 mg/L
I OftTE 41=2
1.0251 mg/L
BA455 EM 958
BA455 AV
BA455 AV
4* 1 O
EM
4* 1 O
EM
1.0216 mg/L
954.7 EM SD
L.0177 mg/L SD
B.5 CV
O.O1OO CV
BA455
4.4
6.55
1327 9/3O/98
0.9
1.3O
1329 9/30/98
2.1
3.26
1331 9/30/98
1.4
2.18
1333 9/3O/98
O.9
0.98
-O.OOOO mg/L
1 1336 9/30/98
peak-noisy
BA455
I GATE 41=2
-O,,OO:24 mq/L peak-noisy
-------
BA455 EM ^ 86 0.0011 mg/L peak-noisy
BA455 AV 84.7 EM SD 1.5 CV 1.8
BA455 AV -0.0004 mg/L SD O.OO18 CV 424.44
-------
Element File: BE.GEL
Date: O9/2B/9B
Data File: B0911BE.DAT
Technique: HGA
Element: Be
. Time: 12:28
ID/Wt File: 80911.IDW
Calib. Type: Linear
Wavelength: 234,
Slit: O.7 L
Lamp Current: 3(
Energy: 66
Be ID: BLANK
Sea. No.: 00001
Replicate 1
Peak Area (A-s): -O.O02
Background Pk Area (A-s): 0.321
Blank Corrected Pk Area CA-s): -0.002
Rpnlicate 2
Peak Area (A-s): -0.002
Background Pk Area (A-s): O.167
Blank Corrected Pk Area (A-s)s -0.002
Mean Pk Area (A-5 ) s
Auto-zero oerformed.
-O.OO2
A/S Pos.: O
Date: O9/2E
Time: 12:2B
Peak Height (A): 0.002
Background Pk Height (A): O.175
Time: 12:31
Peak Height (A): 0.OO3
Background Pk Height (A): 0=103
SD: O.OOO4
RSD (*/.): 19
'V^'V'V^'V'V'^'V'V'V'V'V'Vnr'V'V^
Be
TD: 0.5 PPB
Sea. No.: OOOO2 A/S Pos.: 1
Reolicate 1
Peak Area (A-s): 0.OO9
Background Pk Area (A-s)s 0.124
Blank Corrected Pk Area (A-s): 0.011
Reolicate 2
Peak Area (A-s): 0.009
Backaround Pk Area (A-s)s 0.107
Blank Corrected Pk Area (A-s): 0.011
Mean Pk Area (A~s) :
O.O11
Standard number 1 applied. TO.501
Correlation coefficient: 1.OOOOO
Date: 09/2E
Times 12;34
Peak Height (A)j O.O25
Background Pk Height (A): O.134
Time: 12:37
Peak Height (A): O.O27
Background Pk Height (A): O»132
SD: O.O003
Slope: O.O222
RSD C/.): 2. 52
Ints O.OOO
ID;
PPE
Sea. No,
Reolicate 1
Peak Area (A-s): O.O39
Backaround Pk Area (A-s): 0.171
Blank Corrected Pk Area (A-s): 0.041
Concentration (ug/L ): 1.B7
Renl i cate 2
Peak Area (A-s): 0.041
Backaround Pk Area (A-s): O.165
Blank Corrected Pk Area (A-s): O.043
Concentration (ug/L ): 1.95
,1ean Cone (ug/L ): 1.91
Standard number 2 applied. [2.001
OOOO3
A/S Pos.: 2
Date: 09/28
Time: 12:40
Peak Height (A): 0.118
Background Pk Height (A): O.317
Time: 12:43
Peak Height (A): O.120
Background Pk Height (A): O.322
SD: 0.056
-------
Correlation coefficient: 0.99992
Slooe: 0.0211
Int: O.GOG
No.: QOOO4
= ~iik Area .'A-s't: 0.096
Backoround Pk Are-a (A-s): 0.296
Blank Corrected Pk Area (A-s): O.O98
Concentration (ug/L ): 4.64
Reolicste 2
Peak Area (A-s); 0.096
Backaround Pk Area (A-s): 0.295
Blank Corrected Pk Area (A-sJ: 0.098
Concentration (ua/L ): 4.65
Mean Cone (uo/L ):
4.64
Standard number 3 applied. C5-001
Correlation coefficient: 0.99947
A/5 Pos.5
Date: 09/2E
Time: 12:47
Peak Height (A): 0.224
Background Pk Height (A): O.644
Time: 12:5O
Peak Heiqnt IA): 0.230
Background Pk Height (A): 0.681
SD: 0.011
Slope: 0.0195
RBDC/.) : O.24
Int: O.O01
Be
ID: J0 PPB
Sea. No,
Reolicate 1
Peak Area (A-s): 0.162
Backaround Pk Area (A-s): O.515
Blank Corrected Pk Area (A-s): O.164
Concentration (ug/L ): 8.34
i
Peolicate 2
Peak Area (A-s): 0.172
Background Pk Area (A-s): 0.554
Blank Corrected Pk Area (A-s): O.174
Concentration (ua/L ): 0.83
Mean Cone (uq/L ):
8.58
Standard number 4 applied. £10.00]
Correlation coefficient: O.99634
00005
A/S Pos.: 4
Date: O9/2E
Time: 12:53
Peak Height
-------
Be
ID: ICV
Sea. No.
Replicate 1
Concentration
-------
'oneentration (uq/L ); O.O4
lean Cone !ua/!_ >: 0.04
Time: 15:22
SD: O.OOO
RSDC/. >: O.60
te TD: 80911. O3-2A
?eolicate 1
:oncentration (uq/L )
BSD. No.: O0028 A/S Pas.: IB Date: Q9/28/
Time: 15:25
Concentration (uq/L )
lean Cone iuo/L ) :
-O.OO
-O.O4
-0.02
Time: 15:28
SD: O.O31
R5DC/.): 134. S
ID: 80911, . I1-2A
Jeolicate 1
Concentration (uci/L ): -O.O3
Sea. No.: OO029 A/S Pos.: 19 Date: 09/28/
Time: 15:31
Concentration (uo/L )
lean Cone (ua/L ):
.^r^'^JV'\*'VIV^'V'V'\*%'^'(V-'^'\^p^'\^'V'\*X''V'
^e ID: BO9U..I2-2A
Seolicate 1
Concentration (uq/L )
?=nlicat= 2
Concentration (UQ/L )
-lean Cone (ug/L ):
O.02
-O.OO
Time: 15:35
SD: O.O30
RSDC/.): 624. S
'V'N/'V'%/^n^ *V*V »\*rx/'V^»'VAr^''Vrv^^*Vf\r*\»'Vf\r^«'%
Sen. Mo.: 00030 A/S Pos.: 20 Date: 09/28^
-O.01
O.O2
O.OO
Time: 15:38
Time: 15:41
3D: 0.024
RSDC/.l: 945.6
=!
-------
3C sample is within ranae 3.5 - 6.49
Is? TD: CCB
l icate 1
Concentration (uq/L ): 0.03
Sea. No.: OOO33 A/S Pas.
Time: 15:57
Time: 16:00
3e?o 1 i cats !2
Toncentratian (ua/L ): -O.05
"lean Cone (ug/L ): -0.01 SD: 0.059
3C sample is within ranae -1.49 - 1.49
Date: O9/2E
RSD (7.) : 536.
Date: O9/28
He ID: 8O915.LB
Sea. No.
oncentration <=ol icate 7
Concentration (ua/L • ): 6*69
Sea. No.
Mean Cone (ua/L );
Recovery is 21.17.
6.65
OOO36 A/S Pos,
Time! 16sl5
Time: 16^18
SD: O.047
23 Date: 09/28
RSD 17. )s O.71
Se ID; 80915.15
Replicate 1
Concentration (uq/L ): 7.17
. 5«? o 1 i r a t B 2
Concentration (ua/L ): 6.94
Sea. No.: O0037 A/S Pos.: 24
Time: 16:21
Time: 16:25
Date: 09/28,
-------
Mean Cone (ua/L ): 7.06 SD : 0.161 RSDf?.): 2.29
R» ID: 80*515. 1X10 Sea. No.: OOO3S A/S Pos . : 23 Date: 09/28
Replicate 1 Time: 16:30
Concentration (uq/L ): 0.99 Corrected Cone (ug/L ): 9.9
ieate 2 Time: 16:33
Concentration (uq/L ): 0.70 Corrected Cone (ug/L ): 7.0
Mean Cone (ug/L ): 0.84 SD : 0.201 RSD ( */. ) s 23. B
Corrected Cone (ug/L ): 8.4
1=5 p ID: 80915. 1X1O Sea. No.: OOO39 A/S Pos.: 23 Date: 09/28
Reolicate 1 Time: 16:36
Concentration (up/L 1: 5.50 Corrected Cone (ug/L ): 55.0
Reolicate 2 Time: 16:39
Concentration (ug/L ) ; 5.52 Corrected Cone (ug/L ): 55.2
Mean Cone (ug/L ): 5.51 SD : 0.013 RSD(X): 0.24
Corrected Cone (ug/L ): 55.1
Recovery is 93 . 3X
Be ID; 80915.2X10 Sea. No.: 00040 A/S Pos.: 25 Date: 09/28
}
Reolicate 1 Time: 16:43
Concentration (uq/L ): 0.75 Corrected Cone (uq/L ): 7.5
Reolicate 2 Time: 16:46
Concentration (uq/L ): O.5B Corrected Cone (ug/L ): 5.8
Mean Cone (uq/L ): 0.66 SD: 0.121 RSDC/.i: 18.3
Corrected Cone (uq/L ): 6.6
Be ID: 80915. 2DX10 Seq . No.: 00041 A/S Pos.: 26 Date: 09/28
Reolicate 1 Time: 16:49
Concentration (uq/L ): 0.55 Corrected Cone (ug/L )s 5.5
"eolicate 2 Time: 16:52
Concentration (uo/L ): 0.57 Corrected Cone (uo/L ): 5.7
Mean Cone (uo/L ): O.56 SD: O.O16 RSD(7.): 2.93
Corrected Cane
-------
Concentration ; CCB
^eolicate 1
Concentration (ua/L ): O.O6
Sea. No.: O0044 A/S Pos.s 0
Time: 17:07
Time? 17:10
icate 2
Concentration (ua/L 1: -O.O2
lean Cone (ua/L ): 0.02 SD: 0.053
3C sample is within ranae —1.49 - 1.49
Dates O9/28>
RSD C/.)i 250.
-------
PERKIN-ELMER
M 1100 9B/09/30 PAGE 6
AA AA
MAIN.- -O.O02 MB/L HO--0.001 MAIN: --G.001 MS/L HO-0-, O01
CD MEAN: -0.002 MB/L SD: 0,001 r<8D; '.'I.,-* AUTDZERD O.OOO
MAIN: 0.053 f;3/L HO C- , 02O
A A
MAINs O.C55 MG/L HO 0.021
-33 MEAN: 0. 054 MB/L SD-. 0,001 RSDt 2,, 1 1 . STANDARD 0.054 MG/L
AA
AA
MAIN:; 0.107 MG/L HO 0,, 040 MAIN: O.105 MG/L. HO O.O39
CD siFANs 0. 10& MG/L SD: 0.002 RSD; l.B 2. STANDARD 0.106 MG/L
AA
AA
MAIN; 0.213 MB/L HO O.OBO MAIN; O.212 MB/L HO 0.080
CD MEANs 0.213 ME/L SDj O.O01 RSD: 0.3 3. STANDARD 0.212 MB/L
AA
AA
MAIN: 0.518 MG/L HQ 0.195 MAIN: 0.506 MB/L HO 0.191
CD MEAN: 0.512 MB/L BD: 0.009 RSD: 1.7 4. STANDARD 0.510 MG/L
AA
AA
MAINS O.95S MG/L HO 0.362 MAIN; 0.943 MG/L HD 0.357
CD MEAN-. 0.949 MG/L BD: 0.008 RSD: O.B 5. STANDARD 0.9BO MB/L
FLflME DISPLAY CflLIBRflTION MODE
ELEMENT: CD
REPL. B OF 2
0.359
ABS.
PRINTER: ON
BS CORR: OFF
UNITS : MG/L
0,980
ABS. READING
S5 ftfl : 0.357
SI
CONCENTRATION (MG/L )
C2H2: £.5 L/MJN OXIDflNTs 8.0 L/NIN
1.00Q
FLflME: C2H2-fllR
STATISTICS
MEAN; 0.949
5D: 0.908
1 RSIKJO: 0.S
AA
MAIN: -0.000 MG/L. HQ-~0«000
AA
MAIN: 0.002 MG/L HO 0,001
-------
PERKIN-ELMER M 110O 98/09/30 PAGE 7
AA AA
MAIN: 0.473 MB/L HO 0.182 MAIN: 0.480 MG/L HO 0.184
CD v/ MEANs 0,476 MG/L SDa O.O04 RSD: 0.9
AA AA
MAIM; 0.002 MG/L HO 0,, 001 MAIN: O.OO1 MG/L HO O.OOi
MEANs O.O0.2 MB/L BD: O.OOi RSDs 39.5
AA AA
MAlNs 0.014 MG/L HO 0.006 MAIN: 0.013 MB/L HO O.005
CD £,£— A MEAN: 0.014 ME/L BD: 0.001 RSD: 4.
0
AA AA
MAIN: O.Oli MB/L HO 0.005 MAIN: 0.012 MG/L HO 0.005
CD £&- \ MEAN: O.O12 MG/L SDs O.OOI RSD: 6.9
AA AA
MAIM; 0,297 MG/L HO 0,117 MAIN: 0.3OO MG/L HO 0.1 IB
-[ MEAN: 0.298 MG/L SD? 0.002 RSDs 0,8
AA AA
s 0.71.3 MB/L HQ 0.266 MAIN: 0.693 MB/L HO 0.259
CD 6/-(S MEAN: 0.703 MB/L SD: p.014 RSD: 2.0
AA AA
MAINs 0.343 MG/L HO 0.134 MAINs 0.353 MS/L HO 0.138
Ql-\ MEAN: 0.34B MB/L BD". O.OO7 RSD: 2.O
CD
iy *- • ^_
AA AA
MAIN: 0.333 MB/L HO 0.13O MAIN: 0.341 MG/L HO 0.13:
MEAN: O.337 MG/L SD: O.OO6 ROD: 1.0
A A A A
MAIN: 0.424 MG/L HO O.164 MAIN: 0.432 MG/L HO 0.167
CD p£- \ MEAN-. 0.428 MG/L SD: 0.006 RSD: 1.3
AA AA
MAINs 0.353 MG/L HO 0,138 MAIN: O.350 MG/L HO 0.137
CD f'-t^' MEAN; 0.352 MG/L BD: 0. OO2 RSDs 0.6
-------
PERKIN-ELMER M 1100 9S/09/3O PABE 9
AA AA
MAIN: 0.019 MB/L, HO O.O08 MAIN: O.O21 MS/L HO 0.009
CD C?- MEAN; O.O2O MG/L ED: 0.001 RSD: 6.9
AA AA
MAIN: 0.026 MG/L HO O.010 MAIN: 0.025 MG/L HO O.010
CD £|~Z.fl MEANs 0.026 MG/L SD: 0.000 RSD: 1.3
AA AA
MAIN: 0.025 MG/L HO O.010 MAIN: 0.026 MG/L HO 0.011
CD -W MEANs 0.026 MS/L BD: 0.000 RSD; 1.9
AA AA
MAIN: 0.022 MG/L HO O.009 ' MAIN: O.O23 MB/L HO O.009
CD £2-2-4 MEAN: 0. 022 MB/L 3D; 0.001 RSD: 2.8
AA AA
MAIN: 0.503 MG/L HO 0.192 MAIN: 0,494 MS/L HO 0.189
CD
J MEAN: 0.49S MB/L SD; 0.006 RSD: 1.2
AA AA
MAIN? O.OO1 MG/L HO O.OOO MAIN: -O.OOO MG/L HO-0.000
CD MEAN: 0.000 MB/L SD: 0.001 RSD: 99.9
I
AA AA
0.016 MB/L HO 0.007 MAIN: O.O14 MG/L HO O.006
CD (_ Q MEAN: 0.015 MB/L SD: O.OO2 RSD: 11.4
AA AA
MAIN: 0.032 MB/L HO 0.013 MAIN: 0.034 ME/L HO 0.014
CD I MEAN: O.O33 MB/L SD: 0.001 RSDs 3.1
AA AA
MAIN: 0.403 MB/L HO 0.156 MAIN: 0.414 MB/L HO 0.160
CD MEAN: 0.408 MG/L SD: 0.007 RSDr l.B
AA AA
MAIM: 0.029 MB/L HO O.012 MAIN: O.030 MB/L HO 0.012
CD MEANs 0.030 MB/L BD: 0.001 RGD: 2.7
-------
PERKIN-ELMER M 11OO 98/09/30 PAGE 10
AA
MAIM: 0.014 MB/C HO £xT006 MAIN: 0.013 MG/L HO O.O05
CD -^lEftNt^&TQlQ MG/L BDs O.O01 RSD: 6.6
AA AA
MAINs 0.036 MB/L HO 0,015 MAIN: 0.036 MB/L HO O.O15
CD « MEANs 0.036 MG/L SDs 0.000 RSD: 0.6
AA AA
MAIN: 0,035 MB/L HO O.O14 MAIN; O.O3Q MG/L HO 0,015
CD 3 MEAN: 0.036 MS/L SD: O.O02 RSD: 6.O
AA AA
MAIN: 0.503 MG/L HO 0. 193 MAIN: 0.503 MG/L HO 0.193
CD C/ \f MEAN- 0.503 MG/L SDr 0.000 RSD: O.I
AA AA
MAIN: 0.001 MG/L HO O.OOO MAIN: 0.OO2 MB/L HO 0.001
CD CtT42. MEAN.- 0,001 MG/L. BDs 0.001 RSD: 72.1
-------
3MA 400 Analysis Ver. 4.1O Wed O9/3O/98 - 08:33:52
tod Fi
arks:
«lt fil
•~AIMI
~£^MT
1 e Name i CR
CR ONLY
e is 80911
:>ARD 44= ±
cr267 EM
:>AR£> 44= ±
cr267 EM
:>ARr> 44=1
cr267 EM
>ARD 44=1
cr267 EM
cr2G7 AV
:>ARD 44=2
cr267 EM
DARD 44=2
cr267 EM
:>ARD 44=2
cr267 EM
3ARD 44=2
cr267 EM
cr267 AV
>ARE> 44=3
cr267 EM
}ARE> 44=3
cr267 EM
>ARD 44=3
cr267 EM
>ARD 44=3
cr267 EM
cr267 AV
Repl icates :4
565
564
596
596
58O.3 SD 18.2
REF*I_ I GATE
1122
1218
1110
1135
1146.3 SD 48.9
REF>I_ I GftTE
1781
REF*L_ I GATE
1735
REF>1_ I GATE
1795
1699
1752.5 SD 43.9
Read Delay: 65
Data File: 911CR
44=1 0837 9/30/98
peak -noisy
44=3
peak-noisy
44= -4
peak-noisy
CV 3.1 CDNC O.1OOO
44=1 0839 9/30/98
*2
41=3
#•4
CV 4.3 CQNC O.5OOO
44= 1 0841 9/3O/98
4*2
4*3
4* -4
CV 2.5 CONC 1.0000
cr2&7
cr267
REF>L X GATE
EM 3118
EM 3153
REF*L_ I
44=1 0843 9/30/98
44=2
44=3
-------
=»-*
cr267 EM 3139
cr267 AV 31O7.8 SD
59.& CV
4* :
1.9 CONG 2.OOOO
0845 9/30/98
cr267 EM
cr267
EM
475
467
cr2&7 EM
492
*•=•*!•
cr267 EM
V
cr267
cr267
EM
EM
cr267 EM
cr267
cr267
cr2&7 EM
cr267 EM
cr267 EM
cr267 EM
cr267
cr267
1—JL
cr267 EM
It— 1
; cr267
*_ _ *•
P^~ JL
— X
cr2&7
EM
EM
EM
cr267 EM 519
cr267 AV 488.3 SD 23.0 CV 4.7 CONC O.OOOO
cr267 CC 0.9998 SLOPE 1313.7744 INT 469.0825
ftTE 4* ± 0847 9/3O/98
1810
1811
1817
RrEF=-|_ I C
1,0207 mg/L
1.0214 mg/L
^ER-LIC
1.0260 mg/L
41=3
1823
AV
AV
489
473
474
1.0306 mg/L
1815.3 EM SD
1.O247 mg/L SD
6.O CV
O.O046 CV
0.3
0.45
0.0152 mg/L
FSEF^L-I
0.0030 mg/L
1 0849 9/3O/98
peak-noisy
0.0037 mg/L
477
I CftT
0.0060 mg/L
4*3
peak-noisy
4*-*
AV
AV
478.3 EM
O.OO7O mg/L
SD 7.4 CV
SD O.OO56 CV
1.5
80.34
471
455
466
459
0.0015 mg/L
4*1 0851 9/30/98
wi ndow-edge
I GATE
-0.0107 mg/L
-0.0023 mg/L
REF*!- X CftTI
-0.0077 ma/L
peak-noisy
4*3
peak-noisy
4*«4-
peak-noisy
-------
cr267
EM
460
-0.0069 mg/L
peak-noisy
cr267 EM
cr267
cr267
cr267 EM
cr267
cr267
cr267 EM
cr267 EM
I cr267 EM
cr267 EM
cr267
cr267
cr267 EM
cr267 EM
cr267 EM
15 . I_B
cr267 EM
cr267
cr267
L5 . 1
cr267 EM
L5 . 1
cr2£7 EM
15.1
i GATE:
0.0083 mg/L
cr267
V
cr267
cr267
EM
EM
EM
1865
1825
1764
480
AV 476.8 EM SD
AV 0.0058 mg/L SD
REF=»l_I
1.0625 mg/L
REF>l_I
1.0321 mg/L
REF»l_I
O.9856 mg/L
REF=-I_I
O.9887 mg/L
peak-noisy
12.1 CV
0.0092 CV
4*1
2.5
158.44
0933 9/30/98
1768
AV 1805.5 EM
AV 1.O172 mg/L
506
489
488
SD
SD
4*3
4*-4
48.5 CV
0.0369 CV
E 4*1
2.7
3.63
O935 9/3O/9B
0.0281 mg/L
0.0152 mg/L
481
O.O144 mg/L
REF>1_ I CftTE
0.0091 mg/L
peak-noisy
peak-noisy
AV
AV
491.0 EM
O.O167 mg/L
SD
SD
501
489
457
O.0243 mg/L
REF=»1_ I CftTTI
0.0152 mg/L
peak-noisy
10.6 CV 2.2
0.0081 CV 48.43
E 4*1 O937 9/3O/98
peak-noisy
4*
-O.0092 mg/L
peak-noisy
peak-noisy
466
REF»I_ I C#=iTE 4*-*
-O.OO23 mg/L peak -noisy
AV
AV
478.3 EM SD
O.OO70 mg/L SD
20.3 CV
0.0154 CV
713
641
REF^L I CftTE 4* 1
0.1857 mg/L
4.2
221.30
OS39 9/3O/98
REF*I_IC«T
0.1309 mg/L
4*2
REF*l_ICftTE 4*3
-------
cr267
cr267
cr267
EM
cr267
cr267
IS
EM
IS
EM
. I
cr267
EM
. I
cr267
cr267
EM
cr267
cr267
EM
2. 1936 mg/L
654 0.140S mg/L
AV 664.8 EM SD
AV 0.1489 mg/L SD
3351
3408
3443
I
3340 2.1852 mg/L
AV 3385.5 EM SD
AV 2.2199 mg/L SD
4*4
32.6 CV
O.0248 CV
4*1
4.9
16.68
O941 9/3O/98
2.2370 mg/L
RE:F>I_I
2.2636 mg/L
4*3
48.6 CV
0.0370 CV
751
REF>I_ i GATE: 4*1
0.2146 mg/L
1.4
1.66
O943 S/3O/98
cr267
315
cr267
315
cr267
315
cr267
315
cr2G7
315
cr267
315
cr267
315
cr267
315
cr267
315
cr267
EM
. 2
EM
EM
cr267
c 1-267
EM
EM
EM
EM
cr267
cr267
- 3
EM
. 3
EM
EM
670 0.1529 mg/L
RE:F>L_ i CPITE: 4*3
665 0.1491 mg/L
REF>1_ I GATE 4*-*
669 0.1522 mg/L
AV 688.8 EM SD 41.6 CV 6.O
AV 0.1672 mg/L SD 0.0316 CV 18.92
RER-U- I G*=fcTE 4* 1 O945 9/3O/98
649 0.1369 mg/L peak-noisy
655 0.1415 mg/L peak-noisy
RE=-E=»| T t~~f^"T~f=' 4*'"^
• r T. tMf *—i-W^^ • ••_ ^1T m^^
798 O.2504 mg/L peak-ncdsy
REF*l_ICftTE 4*-*
632 0. 1240 mg/L
AV 683.5 EM SD 77. O CV 11.3
AV 0.1632 mg/L SD O.O586 CV 35.89
REF="I_ I CftTE 4*1 0947 9/3O/98
628 0. 1210 mg/L
REF-I— i GATE: 4*s
661 0.1461 mg/L peak-noisy
REF-LIC^TE: 4*3
623 0. 1172 mg/L
-------
cr267 AV 637.3 EM
cr267 AV O.12BO mg/L
SD 16.9 CV
SD O.O128 CV
2.6
1O.O3
O949 9/3O/98
cr267 EM
^
cr267 EM
k/
cr267 EM
V
cr267 EM
cr267
cr267
B
cr267 EM
1. 1729 mg/L
EF>LIC:
1.0420 mg/L
1.0755 mg/L
cr267
cr267
cr267
EM
EM
EM
cr267
cr267
2010
1838
1882
1877 1.0717 mg/L
AV 1901.8 EM SD
AV 1.0905 mg/L SD
49O
496
494
#2
74.8 CV
0.0569 CV
3.9
5.22
I C<=fcTI
0.0159 mg/L
0.0205 mg/L
0.019O mg/L
499
AV
AV
IM
c>267
cr267
RA
cr267
EM
R-OS
EM
F>OS
EM
1865
1-4
0.0228 mg/L
494.8 EM SD
0.0195 mg/L SD
REF"LI
1.0625 mg/L
1730
cr267
cr267
Rrt
cr267
cr267
cr267
EM
cr267
cr267
EM
EM
EM
EM
N
1781
1830
AV
AV
1316
1346
1321
1347
0.9598 mg/L
RER-LI
O.9986 mg/L
REF>LI
1.0359 mg/L
1801.5 EM SD
1.O142 mg/L SD
REF=-l_I
0.6446 mg/L
REF>1_]
0.6675 mq/L
0.6485 mg/L
REF=-L I
0.6682 mg/L
1 O951 9/3O/98
peak-noisy
peak -noisy
peak-noisy
peak—noisy
3.8 CV O.8
O.OO29 CV 14.71
E #± O953 9/30/98
E #2
58.8 CV
O.O448 CV
3.3
4.41
0954 9/30/9B
=»-*
-------
SMA 400 Analysis Ver. 4.1O Tue 09/29/98 - 13:22:07
Replicates:3
hod File Name: CU
arks: CU ONLY
Read Delay: 60
Data File:
Wt file is 8O911
CU324
4*1
CU324
4* 1
CU324
CU324
CU324
4*2
CU324
CU324
CU324
CU324
4*3
CU324
CU324
CU324
4*^1-
CU324
4*^1-
CU324
4*-*
CU324
CU324
CU324
CU324
EM
EM
EM
AV
EM
EM
EM
AV
R
2203
4*1
1326 9/29/98
2206
2256
2221.7 SD
EM 12159
EM 12295
EM
AV
EM
EM
EM
AV
EM
EM
29.8
CV
#1
7O2O
RE
6757
6749
G842.0 SD 154.2
X
CV
4* 1
I
I
12450
12301.3 SD 145.6
R
24616
R
24309
CV,
4*1
#2
REF>I_ I
23697
242O7.3 SD 467.9
REF3-!- I
1765
REF31!— I GATE
1674
CV
4*1
4*2
1.3 CONC 0.1OOO
1327 9/29/9S
2.3 COIMC O.5OOO
1329 9/29/98
1,2 CONC l.OOOO
1331 9/29/98
1.9 CQNC 2.OOOO
1333 9/29/98
-------
CU324 EM 1696
CU324 AV 1711.7 SD 47.5 CV 2.8 CONC
CU324 CC 0.9994 SLOPE 11362.325 INT 1275.9258
o.oooo
#1
1335 9/29/98
CU324 EM
-------
5—
CU324
J—
CU324
5— :
CU324
L—
CU324
-CU324 EM
CU324
CU324
EM
EM
EM
CU324
CU324
EM
EM
EM
CU324
CU324
EM
EM
CU324 EM
CU324
CU324
L—
CU324
L—
CU324
CU324
CU324
CU324 EM
3—:
CU324 EM
3—:
CU324 EM
CU324
CU324
CU324 EM
CU324 EM
0.0243 mg/L
REF>I_ I GATE
0.0224 mg/L
12233 0.3643 mg/L
AV 12208.O EM SD
AV O.9621 mg/L SD
1552
1530
I
1593 0.0279 mg/L
AV 1558.3 EM SD
AV O.O249 mg/L SD
1639
1638
I
1685 O.O3SO mg/L
AV 1660.7 EM SD
AV O.O339 mg/L SD
66.1 CV O.5
O.OO58 CV 0.61
E 4*1 1410 9/29/98
peak-noisy
peak-noisy
RER-L- I
O.O337 mg/L
RER-L-X
O.O319 mg/L
peak—noisy
32.0 CV 2.1
O.OO28 CV 11.32
E 4*1 1412 9/29/98
1631
1616
RER-L I Crf=fcTI
0.0313 mg/L
RERL- I Cf*-T\
0.0293 mg/L
RERL-I
0.0328 mg/L
peak-noisy
23.5 CV 1.4
.0021 CV 6.12
I 4*1 1414 9/29/98
peak-noisy
SD
SD
O.0382 mg/L
1649
AV 1632.0 EM
AV O.O313 mg/L
1710
I
1664
I
1678 0.0354 mg/L
AV 1684.0 EM SD
AV 0.0359 mg/L SD
4*3
16.5 CV
,OO15 CV
i.O
4.64
0.0342 mg/L
4*1 1415 9/29/98
peak-noisy
4*2
peak-noisy
4*3
14658
14416
REF>I_ I CftT
1.1778 mg/L
23.6 CV
,OO21 CV
: 4*1
4*2
1.4
5.78
1417 9/29/98
1.1565 mg/L
-------
CU324 AV 14527.3 EM
CU324 AV 1.1663 mg/L
SD 122.2 CV 0.8
SD O.O1OB CV O.92
CU324
CU324
EM
EM
CU324
CU324
1569
1576
RERI_]
O.O258 mg/L
RE
0.0264 mg/L
4*1 1419 9/29/9B
peak-noisy
peak-noisy
CU324
315
CU324
315
CU324
315
CU324
315
CU324
315
CU324
315
CU324
315
CU324
315
CU324
315
CU324
EM
CU324
CU324
EM
EM
EM
CU324
CLJ324
. 1
EM
. 1
EM
_ 1
EM
CU324
CU324
- IS
EM
. IS
EM
. IS
EM
1593
AV
AV
1519
1447
1491
AV
AV
3009
2964
3187
AV
AV
27070
27640
28171
O.O279
1579.3 EM
O.0267 mg/L
RERL
0.0214
RERL
0.0151
RERL
O.O189
1485.7 EM
O.O185 mg/L
mg/L
SD
SD
mg/L
. ICftTT
mg/L
O.I
E
E
_ICftTE
mg/L
SD
SD
I
O.I
FiEIF^L- X f^f^TE— '
0.1525 mg/L
RERL
0.1486
RERL
0.1602
3053.3 EM
0.1564 mg/L
RERL
2.2701
mg/L
mg/L
SD
SD
mg/L
E
E
1
0.4
^
RERL- I Crf=bTE
2.3203 mg/L
RERL
2 . 3670
mg/L
E
RERI_ I CftTE 4*3
peak-noisy
12.3 CV 0.8
0.0011 CV 4.07
41= X 1421 9/29/98
peak-noisy
peak-noisy
36.3 CV
0.0032 CV
#1
2.4
17.30
1422 9/29/98
117.9 CV
0.0104 CV
»±
3.9
6.63
1424 9/29/98
CU324 AV 27627.O EM SD
CLJ324 AV 2.3192 mg/L SD
2 RERI_:
EM 3196 0.1690 mg/L
2 RERI_]
EM 3139 0.1640 mg/L
55O.6 CV
0.0485 CV
E 4*1.
#2
2.0
2.09
1426 9/29/98
-------
CU324 EM
CU324
CU324
CU324 EM
CU324 EM
CU324 EM
CU324
CLJ324
fcv
CU324 EM
CU324 EM
CU324 EM
CU324
CU324
CU324 EM
CU324 EM
IZTBt
CU324 EM
CU324
CU324
3049 0.1560 mg/L
AV 3128.O EM SD
AV O.1630 mg/L SD
74.1 CV
O.OO65 CV
9129
8946
9268
AV
AV
R:EF=>I_ i
0.6912 mg/L
0.6750 mg/L
REPL-I
0.7034 mg/L
9114.3 EM
06899 mg/L
SD 161.5 CV
SD O.O142 CV
REP3-!— I OftTE «= 1
0.1248 mg/L
0.1354 mg/L
2694
2814
I
2759 0.1305 mg/L
AV 2755.7 EM SD
AV 0.1302 mg/L SD
14289
14323
I
13937 1.1143 mg/L
AV 14183.O EM SD
AV 1.1360 mg/L SD
1656
1557
60.1 CV
0.0053 CV
I CftTE 4*±
1.1453 mg/L
REF^L. I
1.1483 mg/L
213.7 CV
0.0188 CV
REF-L.I
0.0335 mg/L
REF>L_I
O.0247 mg/L
2.4
4.0O
142B 9/29/98
1.8
2.O6
1429 9/29/98
2.2
4.O6
1431 9/29/98
1.5
1.66
*± 1433 9/29/98
peak-noisy
peak-noisy
F5EF-L- X OftTE =1*3
O.0227 mg/L
1534
AV 1582.3 EM SD
AV O.O270 mg/L SD
64.8 CV
O.OO57 CV
4.1
21.16
-------
PERKIN-ELMER M 1100 90/09/30 PAGE 1
AA AA
MAJNs -0.02 MG/L HO-O.000 MAIN: -O.02 MG/L MO-0.000
PE MEAN: -0.02 MG/L BD: O.O05 RSD: 25.8 AUTOZERO O.00
AA AA
MAIN: 0.23 MG/L HO 0.004 MAIN: 0.23 MG/L HO 0. OO4
PB MEAN: 0.23 MB/L SD: 0.003 RSDs 1.2 1.STANDARD 0.23 MB/L
AA AA
MAIN: 0.5--1 MG/L HO O.OO9 MAINi 0.54 MB/L HO O.O09
PB MEANs 0.54 MG/L SD: 0,002 RSD: 0.4 2.STANDARD 0.54 ME/L
AA AA
MAIN! 1,07 MB/L HO 0«017 MAIN: 1.08 MB/L HO 0.017
PS MEANs i.07 MG/L SDs O.O08 RBD: 0.7 3.STANDARD 1.07 MG/L
AA AA
MAIN; 0,02 MG/L HO O.OOO MAINs 0.03 MG/L HO 0.000
PB MEAN: 0.02 MB/L SD: 0.008 RBD: 34.2 AUTOZERO 0.00
AA AA
MAIN: 2.02 MD/L HO 0.032 MAIN: 2.04 MB/L HO 0.032
PB MEAN: 2.03 MG/L BDs O.O13 RSD; 0.6 4.STANDARD 2.03 MB/L
AA AA
MAIN; 5.OB MB/L HO O.OSO MAIN: 5.04 MB/L HO 0.080
PB MEAN: 5.06 MG/L SDr 0.02& RBD:; 0.5 5, STANDARD 4.9B MB/L
AA AA
MAINs 9.81 ME/L HO 0,, 157 MAIN: 10.04 MS/L HO 0. 161
PB MEANs 9.92 MB/L SD: 0.162 RBD: 1.6 6.STANDARD 9.98 MB/L
-------
PEIRK.IN-ELMER
M 1100
9B/O9/30 PAGE 2
FLAME DISPLAY CfiLIBRfiTION MODE
ELEMENT: PB
REPL. 8 OF 2
0,1531
flBS.
PRINTER: ON
EG CORR: OFF
UNITS : MG/L
9.98
fiBS. READING
S6 flfl ! 0,161
155
SS2
CONCENTRATION (MG/L )
BTflTISTICS
MEAN: 9,92
SDs 0,162
1 RSD
-------
PERK1N-ELMER M 1100 98/09/30 PAGE 4
AA AA
MAIN: 0,13 MS/L HO 0.002 MAIN: 0.10 M6/L HO O.O02
PE --AMEANs 0.12 MG/L SD: 0,016 RGD; 14.1
AA AA
MAIN: 2.06 MG/L HO 0.033 MAIN: 2.10 ME/L HO 0..034
PB &l-&> MEAN: 2.08 MB/L BDs 0.033 RGD: 1.6
AA AA
MAINE 0.15 MB/L HO O.O02 MAIN: 0.16 MG/L HO 0,003
PB 2-- MEAN: 0.16 MG/L SD: 0.008 RED: 4.7
AA AA
MAIN: 0.16 MG/L HO O.002 MAINs 0.11 MG/L HD O.OO2
PB 02-T.AbMEAN:; 0.13 MG/L BDs 0.030 RED: 22.4
AA AA
MAINs 0,. 12 ME/L HD 0.002 MAIN! 0. 12 MG/L HO O.OO2
PB flVZ^AHEANs 0,12 MG/L SD: O.002 RSDf, 1.6
AA AA
MAIN; O.06 MS/L. HO 0.001 MAIN: 0.04 MG/L HO 0.001
PE & MEANs °-05 h1B/L ED: 0-015 RSDr 30.9 AUTDZERD 0.00
AA AA
MAIN: 0.10 MG/L HO 0.002 MAIN: 0.11 MG/L HD 0,002
A MEANs 0. 10 MG/L BD: 0.010 RSD: 9.5
AA AA
MAINs 0.10 MG/L HO 0.002 MAIN: 0. H MG/L HD 0.00
O-H MG/L 5Di 0.002 RSD: 1.7
AA AA
MAIN: O.ll MG/L HO O.OO2 MAIN: 0.11 MG/L HO O.OO2
0,11 MG/L 3D: 0.001 RSDr 1.3
AA AA
MAIMs 4. 89 MB/L. HO 0.078 MAIN: 4.B6 MG/L HO 0.070
PB Cf
\J Mi"AM;; -1.07 MB/L BD; 0.020 RSD: 0.4
-------
PERKIN ELMER H 1100 98/09/30 PAGE 5
AA AA
MAIN: 0.03 MB/L. HO 0.000 MAIN! -0.00 MB/L HD-0.000
PB r^R MEAN: 0.01 MB/L SD: 0.023 RSDs 99.9
AA AA
0.06 MS./L HO 0,001 MAIN: 0,07 MB/L HO O.OOl
"PB LB> MEAN: 0.07 MB/L SD: O.OO3 RSD: 5.2
AA AA
MAIN: 0.72 MB/L. HO 0.011 MAIN: 0.72 M6./L HO 0.012
PB { MEAN: 0,72 MB/L BDs 0.002 RSD: 0.3
AA AA
MAIN* 2.74 MB/L HO 0.044 MAIN: 2.75 MB/L HO 0-044
PB \S MEAN: 2,74 MG/L. SD; O.003 RSD: 0.1
AA AA
MAIN: 0.72 MB/L HO O.O11 MAINs 0.74 MB/L HO O.O12
PB « MEAN: 0.73 MG/L SD: O.Oli RSD: 2.2
AA AA
MAIMr 0.76 MB/L HO 0.. 012 MAIN: 0.75 MB/L HO O.O1S
PB "2-D MEAN: 0,76 MB/L 60s 0.005 RSD; 0.7
AA AA
MAINs O.76 MG/L HO 0.012 MAIN; 0.80 MG/L, HO 0.013
PB ^ MEAN: 0.78 MSXL SO* O.O31 RSD: 3.9
AA AA
MAINa 5.3.6 MGi/L HO OUOB2 MAIN: 5.10 MB/L HO 0.081
PB €£\J MEAN: 5.13 MG/L SDs O.O4B RBD: 0,9
AA AA
MAIN; -0.02 MG/L HO-0.000 MAIN: -0.00 MB/L HG-0-. 000
PB C^MEAN; -0.01 MB/L SD: 0.014 RBD; 99.9
-------
PERKIN-ELMER
M 1100
9B/10/02 PAGE
MAIN; --O.OOO
MN MEAN:-0,000
AA
HO-0.OOO
A A
HA IN: -- 0. OOO HO-0. OOO
SD: 0.000 RSDt 13.9 AUTDZERO O.OOO
MAIN: 0.001
MN MEAN: 0.001
AA
HO 0,001
AA
MAINs 0.001 HD 0.000
5Ds 0,000 RSD: 26.B AUTOZERO 0,000
MAIN; O.O30
MN MEAN: O.O30
A A
HO 0.030
AA
MAIN: 0.03O HD O.O30
SDi 0.000 RSD: 0.3 1. STANDARD 0,, 200 MG/L
AA
AA
MAIN: 0.497 M6/L HO 0.076 MAIN: 0.480 MB/L HD 0.073
MN MEANr 0.488 MB/L BDs 0.011 RBD: 2.3 2. STANDARD 0..49B MB/L
AA
MAIN: 0„961 MB/L HO 0„143
AA
MAIN: 0.943 MB/L HO C,,141
I MN
MEAN: 0.9S2 MG/L BDs 0.013 RSDs 1.4 3.STANDARD 0.9BB MB/L
AA
AA
MAINs 1.895 ME/L HO 0.272 MAIN: 1.882 MB/L HO O.270
MN MEAN: 1.BBB MG/L BDi 0.009 RSD: 0.5 4.STANDARD 1.970 MB/L
FLAME DISPLflY CfiLIBRflTION MODE
ELEMENT-. MN
REPL. 0 Cf 2
0.271
ftBS.
PRINTER: ON
BG CORR: OFF
UNITS : MG/L
1.970
flBS.
34 flft
READ
NS
0.270
S3
S2
CONCENTRATION (MS/L )
C2H2: 2.5 L/HIN OXFDflNT: 3.0 L/MIN
STftTISTICS
MEW: i.eea
SD: 0,009
R3D(%): 0.5
2.002
FLflME: C2H2-AIR
AA
0,. 01 e MG/L HO 0.003
AA
MAIN; 0,020 MB/L HO O.003
-------
PERKIN-ELMER M 1100 98/10/02 PASE 7
AA AA
MAJN; 0,969 MB/L HD O. 138 MAIN;: 0.990 MB/L. HO 0.14.1.
MN s£j£^ MEAN: 0.980 MG/L SD: 0.015 RSDs 1.6
AA AA
MAIN? 0.005 MB/L HO 0.001 MAIN: 0.006 MB/L. HO 0.001
<-h 0.006 MB/L 3Ds 0.001 RSDs 12.3
AA AA
MAIN: 0.028 MG/L HO O. OO4 MAIN: O. 036 MB/L HO 0.006
MN c MEAN: 0,032 MB/L SD: 0.006 RSDs 17.8
AA AA
MAINs 1.352 MB/L HO 0.189 MAIN: 1.359 MG/L HO 0.190
I
MN MEANt 1.355 MB/L. SD: 0.005 RSDs 0.4
A A A A
MAIN: 1.7S7 MS/L HD 0.240 MAIN: 1.73.1 MB/L HO 0.237
MN / ^ MEANs 1.744 MB/L SD: 0.010 RSD: 1.0
AA AA
MAINs 1,403 MG/L HO O.I 95 MAIN: 1.412 MB/L HO 0.196
MM-, MEANs 1,407 MB/L BD: O.G06 RBDt 0.4
- AA AA
MAIN; 1.369 MB/L HD 0.191 MAIN: 1.379 MB/L HG 0.192
MM - MEAN: 1.374 MS/L SDs 0.007 RSD: O.5
A A A A
MAIN; 1.330 MB/L HO 0., 136 MAIN: 1.323 MB/L HO 0.185
MN 3> MEAN: 1.326 MB/L SDt 0.005 RSD: 0.4
A A A A
MAIN; 1.020 MG/L HO 0.145 MAIN: 1.030 MB/L HO 0.146
MN OL V MEANs 1.025 MG/L SD: 0.007 RBD: 0.7
AA AA
SAIN: 0.030 MB/L. HO 0., 005 MAIN: O.O32 MB/L, HO 0.005
MN MEANs 0.031 MB/L SD; O.OO1 RSD: 4,, 2
-------
iM-ELMER M 11OO ^"^ im " 9B/09/2? PAGE 1
AA-BG EG
s -0.005 PA-0.013 O.006
PH-O.OO5 O.OO2
DO AUTOZERO
AA-BG EG
0,010 PA 0.193 -0.014
PH 0.010 -0.002
50 1.STANDARD
AA-BG EG
1.30 UB/L PA 0.364 -0.034
PH 0.026 -0.004
Sample concentration greater than hicihest standard
04 2., STANDARD
AA-BB EG
: i.77 US/L PA 0.736 -0.016
PH 0.044 -0,002
feample concG?nt.raition greater than highest standard
94 3.STANDARD
AA-BG EB
5.18 UG/L PA 1.903 O.OOO
PH 0.119 -0.002
Sample concentration greater than highest standard
03 4.STANDARD
AA-BG ES
: 10.26 UG/L PA 3.965 0.008
PH 0.242 -O.001
Sample concentration greater than highest standard
06 5.STANDARD
-------
TECHNICAL REPORT DATA
Please read instructions on the reverse before completing
1. REPORT NO,
EPA-454/R-99-001b
2.
4. TITLE AND SUBTITLE
Final Report - Emissions Testing of Combustion Stack and Posh ing Operations at Coke
Battery No. 2 at Bethlehem Steel Corporation's Bums Harbor Division in Chesterton, Indiana
Volume I! of III
7. AUTHOR(S)
Franklin Meadows
Daniel F, Scheffel
9, PERFORMING ORGANIZATION NAME AND ADDRESS
Pacific Environmental Services, Inc.
Post Office Box 12077
Research Triangle Park, North Carolina 277 09-2077
12, SPONSORING AGENCY NAME AND ADDRESS
U.S. Environmental Protection Agency
Office of Air Quality Planning and Standards
Emissions, Monitoring and Analysis Division
Research Triangle Park, North Carolina 27711
3. RECIPIENT'S ACCESSION NO.
5. REPORT DATE
February 1999
6. PERFORMING ORGANIZATION CODE
8. PERFORMING ORGANIZATION REPORT NO.
10, PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-D-98-004
13. TYPE OF REPORT AND PERIOD COVERED
Final
14. SPONSORING AGENCY CODE
15, SUPPLEMENTARY NOTES
16. ABSTRACT
The United States Environmental Protection Agency (EPA) is investigating the coke making industry to characterize hazardous air pollutants (HAPs)
emitted from coke pushing operations and combustion (undcrfirc) stacks. This test report addresses pushing emissions from a coke oven, and emissions
from the combustion (underfire) stack that serves Coke Battery No. 2 at Bethlehem Steel Corporation's Bums Harbor Division in Chesterton, Indiana.
The purpose of this test program was to quantify emissions from the inlet and outlet of the baghouse controlling emissions from the coke pushing
operation and to quantify emissions from the combustion outlet stack. The data may be used by the EPA in the fliture to support a residual risk
assessment for coke oven facilities.
The testing was performed to quantify uncontrolled and controlled air emissions of filterable particulate matter (PM), methylene chloride extradable
matter (MCEM) and 19 polycyclic aromatic hydrocarbons (PAHs) including acenaphthene, acenaphthylene, anthracene, benzo(a)anthracene,
benzo(a)pyrene, benzo(b)fluoranthene, benzo(e)pyrene, benzo(k)fluoranthene, benzo(ghi)perylene, chrysene, dibenzo(a,h)anthracene, fluoranthene,
iluorene, indeno(l ,2,3-cd)pyrene, 2-melhylnapthalene, naplhalene, perylene, phenanthrene, and pyrene. In addition, following the PM and MCEM
analyses, the samples were analyzed to screen for the presence of 17 trace metals. Baghouse dust samples were also collected and analyzed for 16 trace
metals. Simultaneous testing was performed at the inlet and outlet of the baghouse controlling emissions from the coke pushing operation. Sampling
was also performed on the combustion outlet stack. In addition to pollutant testing, oxygen (OJ and carbon dioxide (CO2) were measured at each
location. During the sampling program, Research Triangle Institute (RTI), another EPA contractor, monitored and recorded process and emission
control system operating parameters.
This volume (Volume 11) is comprised of 376 pages and contains Appendix C (Analytical Data)
1 7. KEY WORDS AND DOCUMENT ANALYSIS
a. DESCRIPTIONS
Baghouse
Coke Ovens
Emission Measurements
Hazardous Air Pollulants
Metals
Methylene Chloride Extractable
Matter
Particulate Matter
Polycyclic Aromatic Hydrocarbons
18. DISTRIBUTION STATEMENT
Unlimited
b. IDENTIFIERS/OPEN ENDED TERMS
19. SECURITY CLASS (This Report)
Unclassified
20. SECURITY CLASS (This page)
Unclassified
c. COASTI Field/Group
21. NO. OF PAGES
960
22. PRICE
EPA Form 2220-1 (Rev, 4-77) PREVIOUS EDITION IS OBSOLETE
F:\U\FMeadows\TRD.Frrn\WP t
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