United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park, NC 27711
EPA-454/R-99-017B
June 1999
AIR
   &EPA

   Final Report - Volume II of II

   Iron and Steel Foundries Manual
   Emissions Testing of Cupola
   Baghouse at Waupaca Foundry  in
   Tell City, Indiana
           >7^at>

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                    GENERAL DISCLAIMER

     This document may be affected by one or more of the following statements:


*  This document has been reproduced from the best copy furnished by the
   sponsoring agency.  It is being released in the interest of making
   available as much information as possible.

«  This document may contain data which exceeds the sheet parameters. It
   was furnished in this condition by the sponsoring agency and is the best
   copy available,

•  This document may contain tone-on-tone or color graphs, charts and^or
   pictures which have been reproduced in black and white.

»  The document is paginated as submitted by the original source,

*  Portions of this document are not fully legible due to the historical nature
   of some of the material.  However, it is the best reproduction available
   from the original submission.

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             FINAL REPORT

      IRON AND STEEL FOUNDRIES
      MANUAL EMISSION TESTING
          CUPOLA BAGHOUSE
WAUPACA FOUNDRY, TELL CITY, INDIANA

             VOLUME II OF II
            APPENDICES C - F
         EPA Contract No. 68D7Q069
         Work Assignment No. 2-08

               Prepared for:

        Mr. Michael K. Ciolek (MD-19)
         Work Assignment Manager
           SMAG, EMC, OAQPS
     U.S. Environmental Protection Agency
      Research Triangle Park, NC 27711

                June 1999
            p:\i528\fintpt\waupaca\report

               Submitted by

 PACIFIC ENVIRONMENTAL SERVICES, INC.
        5001 S. Miami Blvd., Suite 300
           Post Office Box 12077
    Research Triangle Park, NC 27709-2077
              (919)941-0333
            FAX (919) 941-0234

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                                  DISCLAIMER

      This document was prepared by Pacific Environmental Services, Inc. (PES) under EPA
Contract No. 68D70069, Work Assignment No. 2-08. This document has been reviewed
following PES' internal quality assurance procedures and has been approved for distribution.
The contents of this document do not necessarily reflect the views and policies of the U.S. EPA.
Mention of trade names does not constitute endorsement by the EPA or PES.

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                        TABLE OF CONTENTS


VOLUME 1                                                     Page

1.0   INTRODUCTION	1-1

2,0   SUMMARY OF TEST RESULTS	,	2-1

     2.1   EMISSIONS TEST LOG	,. 2-1
     2.2   PARTICULATE MATTER AND METALS 	2-1
     2.3   DIOXINS AND FURANS	2-7
     2.4   SEMIVOLATILE ORGANIC HAZARDOUS AIR POLLUTANTS	2-14

3.0   PROCESS DESCRIPTION	3-1

     3.1   INTRODUCTION	3-1
     3,2   PROCESS DESCRIPTION	3-1
     3.3   SUMMARY OF PROCESS OPERATING DATA COLLECTED
          DURING SOURCE TEST	3-5

4.0   SAMPLING LOCATIONS	4-1

     4.1   CUPOLA BAGHOUSE INLET 	4-1
     4.2   CUPOLA BAGHOUSE OUTLET 	4-1

5.0   SAMPLING AND ANALYTICAL PROCEDURES	5-1

     5.1   LOCATION OF MEASUREMENT     AND
          SAMPLE/VELOCITY TRAVERSE POINTS 	5-1
     5.2   DETERMINATION OF STACK GAS VOLUMETRIC
          FLOWRATE	5-1
     5.3   DETERMINATION OF DRY MOLECULAR WEIGHT
          AND EMISSION CORRECTION FACTORS	5-1
     5.4   DETERMINATION OF STACK GAS MOISTURE CONTENT 	5-3
     5.5   DETERMINATION OF PARTICULATE MATTER
          AND METALS	5-3
     5.6   DETERMINATION OF DIOXINS AND FURANS	5-7
     5.7   DETERMINATION OF SEMIVOLATILE ORGANIC
          HAZARDOUS AIR POLLUTANTS (SVOHAPS)	5-7
                               in

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                      TABLE OF CONTENTS (Concluded)

6,0   QUALITY ASSURANCE/QUALITY CONTROL (QA/QC)	6-1

     6.1   CALIBRATION OF APPARATUS	 6-1
     6.2   ON-SITE MEASUREMENTS	6-4
     6.3   LABORATORY ANALYSIS	6-6
     APPENDIX A - RAW FIELD DATA
     APPENDIX B - ANALYTICAL DATA - PARTICULATE MATTER
                 AND METALS

VOLUME 2

     APPENDIX C - ANALYTICAL DATA - D1OXINS/FURANS AND
                 SEMI-VOLATILE ORGANIC HAZARDOUS
                 AIR POLLUTANTS
     APPENDIX D - CALCULATIONS
     APPENDIX E - QA/QC DATA
     APPENDIX F - PARTICIPANTS
                               IV

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                               LIST OF TABLES
VOLUME 1

Table 2,1     Emissions Test Log, The Waupaca Foundry - Tell City, Indiana	2-2
Table 2.2     Particulate/Metals Emissions Sampling and Flue Gas Parameters,
             Cupola Baghouse Inlet, The Waupaca Foundry - Tell City, Indiana	2-3
Table 2.3     Particulate Matter Concentrations and Emission Rates, Cupola
             Baghouse Inlet, The Waupaca Foundry - Tell City, Indiana	,	2-4
Table 2,4     Metals Concentrations and Emission Rates, Cupola Baghouse Inlet,
             The Waupaca Foundry - Tell City, Indiana	2-5
Table 2.5     Particulate/Metals Emissions Sampling and Exhaust Gas Parameters,
             Cupola Baghouse Outlet, The Waupaca Foundry - Tell City, Indiana	2-8
Table 2.6     Particulate Matter Concentrations and Emission Rates, Cupola Baghouse
             Outlet, The Waupaca Foundry - Tell City, Indiana	2-9
Table 2.7     Exhaust Gas Metals Concentrations and Emission Rates, Cupola
             Baghouse Outlet, The Waupaca Foundry - Tell City, Indiana	2-10
Table 2.8     Particulate Matter and Metals Removal Efficiencies, Cupola Baghouse,
             The Waupaca Foundry - Tell City, Indiana	2-12
Table 2.9     PCDDs/PCDFs Emissions Sampling and Exhaust Gas Parameters
             Cupola Baghouse Outlet, The Waupaca Foundry - Tell City, Indiana  .... 2-13
Table 2.10    PCDDs/PCDFs Exhaust Gas Concentrations  and Emission Rates,
             Cupola Baghouse Outlet, The Waupaca Foundry - Tell City, Indiana  .... 2-15
Table 2.11    PCDDs/PCDFs Exhaust Gas Concentrations  and 2378 Toxic Equivalent
             Stack Gas Concentrations Adjusted to 7 Percent Oxygen,
             Cupola Baghouse Outlet, The Waupaca Foundry - Tell City, Indiana  .... 2-16
Table 2.12    SVOHAPs Emissions Sampling and Exhaust Gas Parameters
             Cupola Baghouse Outlet, The Waupaca Foundry - Tell City, Indiana  .... 2-17
Table 2.13    SVOHAPs Exhaust Gas Concentrations and Emission Rates, Cupola
             Baghouse Outlet, The Waupaca Foundry - Tell City, Indiana	2-19
Table 2.14    SOVHAPs In-Stack Detection Limits (PPBVD), Cupola Baghouse
             Outlet, The Waupaca Foundry - Tell City, Indiana	2-26

Table 3.1     Typical Cupola Charge Materials	3-4
Table 3.2     Summary of Cupola Charging During The Test Days	3-6
Table 3.3     Process Data During The Days of Cupola Testing  	3-8
Table 3.4     Periods When Cupola Was "On Relief During Testing	3-10
Table 3.5     Process Iron Chemistry  at Cupola	3-11

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                            LIST OF TABLES (Concluded)

VOLUME 1                                                                 Page

Table 5.1     Sources, Test Parameters, and Test Methods Summary,
             The Waupaca Foundry - Tell City, Indiana	5-2

Table 6.1     Summary of Temperature Sensor Calibration Data	6-2
Table 6.2     Summary of Pitot Tube Dimensional Data	6-3
Table 6.3     Summary of Dry Gas Meter and Orifice Calibration Data  	6-5
Table 6.4     Summary of EPA Methods 23 and 29 and SW-846 Method 0010
             Field Sampling QA/QC Data	6-9
Table 6.5     Summary of EPA Method 29 Analysis QC Data, Lab Control Spikes	6-10
Table 6.6     Summary of EPA Method 29 Analysis QC Data, Matrix Spikes
             (Post Digestion)	6-11
Table 6.7     Summary of EPA Method 29 Analysis QC Data, Duplicate Analyses	6-12
Table 6.8     Summary of EPA Method 29 Analysis QC Data, Serial Dilution	6-14
Table 6.9     Summary of EPA Method 29 Analysis QC Data, Method Blanks Results  .6-16
Table 6.10    Summary of EPA Method 29 Analysis QC Data, Field Blanks Results ... 6-17
Table 6.11    Summary of EPA Method 29 Analysis QC Data, Mercury Summary
             Report - Lab Control Spikes  	6-18
Table 6.12    Summary of EPA Method 29 Analysis QC Data, Mercury Summary
             Report - Matrix Spikes (Pre-Digestion)	6-19
Table 6.13    Summary of EPA Method 29 Analysis QC Data, Mercury Summary
             Report - Method Blank 	6-20
Table 6.14    Summary of EPA Method 29 Analysis QC Data, Mercury Summary
             Report - Field and Reagent Blanks  	6-21
Table 6.15    Summary of EPA Method 23 Standards Recovery Efficiencies	6-22
Table 6.16    Summary of SW-846 Method 0010 Field and Laboratory
             Blanks Results	6-23
Table 6.17    Summary of SW-846 Method 0010 Surrogate Recovery Results	6-24
                                       VI

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                                LIST OF FIGURES
VOLUME 1                                                                  Page

Figure 1.1    Air Flow Schematic and Sampling Locations at The Waupaca Foundry -
             Tell City, Indiana	1-3
Figure 1.2    Key Personnel and Responsibility for Testing Program at The Waupaca
             Foundry - Tell City, Indiana,	1-4

Figure 3.1    Simplified Schematic of Cupola Gas Handling System 	3-2
Figure 3.2    Hourly Melting Rates During Cupola Testing	3-7
Figure 3.3    Blast Air Flow Rate Through Cupola 	3-9

Figure 4.1    Cupola Baghouse Inlet Sampling Location, Waupaca Foundry -
             Tell City, Indiana	4-2
Figure 4.2    Cupola Baghouse Inlet Traverse Point Location, The Waupaca Foundry -
             Tell City, Indiana	4-3
Figure 4.3    Cupola Baghouse Outlet Sampling Location, Waupaca Foundry -
             Tell City, Indiana	4-4
Figure 4.4    Cupola Baghouse Outlet Traverse Point Locations, The Waupaca Foundry -
             Tell City, Indiana	.4-5

Figure 5.1    Sampling Train Schematic for EPA Method 29	5-4
Figure 5.2    EPA Method 29 Recovery Scheme	5-5
Figure 5,3    Sample Preparation and Analysis Scheme for EPA Method 29	5-6
Figure 5.4    Sampling Train Schematic for EPA Method 23 and
             SW-846 Method 0010	 5-8
                                       Vll

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            APPENDIX C

ANALYTICAL DATA - DIOXINS/FURANS AND
SEMIYOLATILE ORGANIC HAZARDOUS AIR
            POLLUTANTS

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        Appendix C. 1




Analytical Data - Dioxins/Furans

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                             CASE NARRATIVE
                      Analysis of Samples for the Presence of


             Polychlorinated Dibenzo-p-Dioxins and Dibenzofurans by


      High-Resolution Clironiatography / High-Resolution Mass Spectrometry
                                Method 23 (6/93)
              Date:

              Client ID:

              P.O. Number:

              TLI Project Number:
September 22,1997

Pacific Environmental Services


8414,003


43229
This report should only be reproduced in full. Any partial reproduction of this report requires permission from
Triangle Laboratories, Inc.
Rev, 05/08/97
                                             Triangle Laboratories, Inc.
                                  801 Capitola Drive             P.O. Box 13485
                                  Durham, NC 27713-4411         Research Triangle Park, NC 27709-3485
                                  913-544-5729                 Fax # 919-544-5491

                                                                            •t

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Triangle Laboratories, Inc.                                             September 22,1997
Case Narrative                                                                 43229
Overview

Six M23 samples were received from Pacific Environmental Services at 5 °C in good
condition on September 12,1997 and were stored in a refrigerator at 4°C, The samples
and any associated QC samples were extracted and analyzed according to procedures
described in the Triangle Laboratories' Data User's Manual (Rev, 12/92-HK-2-AH-2/93),
Any particular difficulties encountered during the sample handling by Triangle
Laboratories will be discussed in the QC Remarks section below. Results reported relate
only to the items tested.

Quality Control Samples

A laboratory method blank, identified as the TLI Blank, was prepared along with the
samples,

Quality Control Remarks

This release of this particular set of Pacific Environmental Services analytical data by
Triangle Laboratories was authorized by the Quality Control Chemist who has reviewed
each sample data package individually following a series of inspections/reviews. When
applicable, general deviations from acceptable QC requirements are identified below and
comments are made on the effect of these deviations upon the validity and reliability of the
results.  Please consult Triangle Laboratories'  Data User's Manual for further details.
Specific QC issues associated with this particular project are:

Sample Preparation Laboratory: None

Mass Spectrometry: None

Data Review: None

Other Comments: Any analytes found in the TLI Blank are detected at a level equal to or
less than the Target Detection Limit. This level of contamination is acceptable as per TLI
guidelines.

Sample Calculations:

Analyte Concentration
                                                                             O

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Triangle Laboratories, Inc.                                              September 22,1997
Case Narrative                                                                  43229
The amount of any analyte is calculated using the following expression.

                            A,, *Qp
                     Amt«,) = 	
                            Ap * RRF(
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Triangle Laboratories, Inc.                                             September 22,1997
Case Narrative                                                                 43229
F is an empirical number that approximates the area to height ratio for a GC signal. This
number is 3.7 for both the DB-5 GC column and the DB-225 GC column,

H is the height of the noise

Ap  is the integrated current of the characteristic ions of Ihe corresponding internal
standard,

Qp  represents the amount of internal standard added to the sample before extraction,

RRF(0) is the mean analyte relative response factor from the initial calibration (ICal) and,

W is the sample weight or volume

The detection limit is expressed in nanopams (ng) or picograms (pg).

Other sample calculations may be found in the Triangle Laboratories Data User's Manual.


 Data Flags

In order to assist with data interpretation, data qualifier flags are used on the final reports,
as discussed in Triangle Laboratories* Method 23 Data User's Manual.  Please note that all
data qualifier flags are subjective and are applied as consistently as possible.  Each flag has
been reviewed by two independent Chemists and the impact of the data qualifier flag on
the quality of the data discussed above. The most commonly used flags are;

A 'B' flag is used to indicate that an analyte has been detected in the laboratory method
blank as well as in an associated field sample. The *B' flag will be used only when the
concentration of analyte found in the sample is less than 20 times that found in the
associated blank. This flag denotes possible contribution of background laboratory
contamination to the concentration or amount of that analyte detected in the field sample.
Under Triangle Laboratories guidelines, a laboratory blank is acceptable if the terra-
through hepta-CDD/CDF levels are all below the target detection limits (TDLS) or if the
contamination levels are less than 5% of the levels detected hi the associated field samples.
If these conditions are satisfied or if the blank is unable to be reextracted, the
interpretation of the contamination levels relative to the samples should be as follows: 1)
analyte quantitations should be considered valid if the level of blank contamination is less
than five percent of the level detected in the field sample, 2) analyte quantitations should
be considered estimated if the analyte level in the sample is five to twenty times the level
of the analyte in the blank, or 3) analytes whose level in a sample is the same as or less
than five times the level  detected in the associated blank should be considered present
likely due to laboratory contamination and not native to the sample.

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Triangle Laboratories, Inc.                                             September 22,1997
Case Narrative                                                                 43229
An 'E' flag is used to indicate that an PCDF peak has eluted at the same time as the
associated diphenyl ether (DPE) and that the DPE peak intensity is ten percent or more of
the PCDF peak intensity. Total PCDF values are flagged 'E' if the total DPE contribution
to the total PCDF value is greater than ten percent. All PCDF peaks that are significantly
influenced by the presence of DPE peaks are quantitated with EMPC values, regardless of
the isotopic abundance ratio. These EMPC values are most likely overestimated due to
the DPE contribution to the peak area.

An 'I' flag is used to indicate labeled standards have been interfered with on the GC
column by coeluting, interferent peaks. The interference may have caused the standard's
area to be overestimated. All quantitations relative to this standard, therefore, may be
underestimated.

A 'PR' flag is used to indicate that a GC peak is poorly resolved. This resolution problem
may be seen as two closely eluting peaks without a reasonable valley between the peak
tops, overly broad peaks, or peaks whose shapes vary greatly from a normal distribution.
The concentrations or amounts reported for such peaks are most likely overestimated.

A 'Q' flag is  used to indicate the presence of QC ion instabilities caused by  quantitative
interferences. Affected analytes may be overestimated or underestimated as a result of this
interference.  A peak is flagged 'Q'  only if it is affected by a QC ion deviation greater than
20% full scale as determined relative to the labeled standard against which it is
quantitated. Total PCDF/PCDF quantitations will be flagged 'Q' if the interferences affect
ten percent or more of the total PCDD/PCDF peak areas.

An 'RO' flag is used to indicate that a labeled standard has an ion abundance ratio that is
outside of the acceptable QC limits, most likely due to a coeluting interference. This may
have caused the percent recovery of the standard to be overestimated. All quantitations
versus this standard, therefore, may be underestimated.

A 'U' flag is  used to indicate that a specific (2,3,7,8-substituted) isomer cannot be
resolved from a large, coeluting interferent GC peak.  The specific isomer is reported as
not detected as a valid concentration/amount cannot be determined. The calculated
detection limit, therefore, should be considered an underestimated value.

A 'V flag is used to indicate that, although the percent recovery of a labeled standard may
be below a specific QC limit, the signal-to-noise ratio of the peak is greater than ten-to-
one. The standard is considered reliably quantifiable.  All quantitations derived from the
standard are considered valid as well.

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Triangle Laboratories, Inc.                                              September 22,1997
Case Narrative                                    ,                             43229
By our interpretation, the analytical data ia this project are valid based on the guidelines
of EPA Method 23 (6/93) and Triangle Laboratories' Method 23 Data User's Manual.
Any specific QC concerns or problems have been discussed in the QC Remarks section of
this case narrative with emphasis on their effect on the data. Should Pacific
Environmental Services have any questions or comments regarding this data package,
please feel free to contact our Project Scientist, Amy Boehm, at 919/544-5729 ext. 268.
For Triangle Laboratories, Inc.,



Report Preparation                        Quality Control


                                                9, 0 /   /
                                                -ft M, fyj. f^f
Vijay S, Chhabra                         Skfi
Report Preparation Chemist                Report Preparation Chemist
The total number of pages in the data package is :.
                                                                             G

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                     TRIANGLE LABORATORIES, INC.

                LIST OF CERTIFICATIONS AND ACCREDITATIONS
ENVIRONMENTAL

American  Association  for Laboratory Accreditation. Certification pending.  Certificate
Number 0226-01. Accreditation for technical competence in Environmental Testing.(lnc!uding
Waste Water, Sol/Haz Waste, Pulp/Paper, and Air Matrices)  Parameters are AOX/TOX.
Volatiles, Pesticides, PCB's, BNA's, and Dioxin/Furan. Method 1613 for Drinking Water.

State of Alabama, Department of Environmental Management Expires December 31,1997.
Laboratory I.D. #40950. Dioxin in drinking water.

State of Alaska, Department of Environmental  Conservation.  Expires  December 21, 1997.
Certificate number OS-00397. Dioxin in drinking water.

State of Arizona, Department of Health Services.  Expires May 26,  1998. Certificate
#AZQ423. Drinking Water for Dioxin, Dioxin in WW and S/H Waste.

State of Arkansas, Department of Pollution Control and Ecology.   Expires February 18,
1998. Pulp/paper, soil, water, and Hazardous Waste for Dioxin/Furan; AOX/TOX.

State of California, Department of Health Services. Expires August 31, 1999. Certificate
#1922. Selected Metals in Waste Water; Volatiles, Semi-volatiles, and Dioxin/furan in WW and
Sol/Haz Waste. Dioxin in drinking water.

State of Connecticut,  Department  of Health Services.  Expires September 30,  1997.
Registration # PH-0117.  Dioxin in drinking water.

Delaware Health and Social Services.  Expires December 31, 1997. Certificate #NC 140.
Dioxin in drinking water.

Florida Department of Health and Rehabilitative Services. Expires June 30, 1998.Dioxin  in
DW. Drinking Water ID HRS# 87424. Metals, Extractable Organics (GC/MS), Pesticides/PCB's
(GC)  and  Volatiles (GC/MS) in Environmental  Samples.   Environmental water ID  HRS#
E87411.

Hawaii Department of Health.  Expires March 1, 1998. Dioxin in drinking water. "Accepted"
status for regulatory purposes.
Revised 9/18/97 RM

Printed 9/1*97

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Idaho Department of Health and Welfare,  Expires November 30,  1997, Dioxin in drinking
water.

State of Kansas, Department of Health and Environment Expires January 31, 1998.
Environmental Analyses/Non potable Water and Solid and Hazardous Waste.  Method 1613
for drinking water. ID #'s - Drinking water and/or pollution control - E-215. Solid or Hazardous
Waste-E-1209.

Commonwealth of Kentucky, Department for Environmental Protection. Expires December
 31,1997.1DS90060. Dioxin in drinking water.

Maryland Department of Health and  (Mental  Hygiene,   Expires September  30, 1997.
Certification #235. Drinking water by Method 1613A.

State of Michigan, Department of Public Health.  Expires March 31, 1998. Drinking water by
Method  1613.

Mississippi State Department of Health. No expiration date.. Dioxin in drinking water.

Montana Department of Health and Environmental Services. Expires December 31,1997.
Dioxin in drinking water.

State of New Jersey,  Department of Environmental Protection and Energy, Extended by
state. Temporary certificate until December 31,1997. ID #67851. BNAs and Volatiles. Dioxin in
drinking water.

State of New Mexico, Environment Department. Certification pending. Dioxin in  drinking
water.

New York State Department of Health, Expires  June  30, 1997. ID #11026.  Environmental
Analyses of  non-potable Water, Solid and Hazardous Waste. Method 1613 in DW,

State of North Carolina, Department of Environment Health and  Natural Resources
Expires August 31, 1999. Certificate # 37751.  Dioxin in drinking water.

State of North Carolina,  Department of Environment, Health, and Natural Resources,
Division of  Environmental Management  Expires December 31, 1997. Certificate # 485.
Metals,  pesticides & PCBs, semi-volatiles and volatiles; TCLP.

North Dakota  State  Department  of  Health  and Consolidated  Laboratories.   Expires
December 31,  1997. Certificate # R-076. Effective October 4,1993. Dioxin in drinking water.
 Revised 9/1S/97RM
 Printed 9*18/97
                                                                          8

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Oklahoma Department of Environmental Quality.  Expires October 31, 1997. Laboratory
#9612. Dioxin by 1613A, 8290 and 8280.

State of South Carolina, Department of Health and Environmental Control.  Expires June
30, 1997. Certificate number #99040001 (drinking water). Expires August 31, 1999. Certificate
number #99040002 (other parameters).  Dioxin/Furans, SNA, Volatiles, and PCBs/pesticides
under Clean Water Act, 2,3,7,8-TCDD for Drinking Water, and Organic extractables for Solid
and Hazardous Waste.

State of Tennessee. Department of Environment and Conservation. Expires February 5,
1999. ID #02992.  Method 1613 Drinking water only.

U.S. Department of Agriculture Soil  Permit  Expires September 30, 2001. Permit No.  S-
3790. Under the authority of the Federal  Plant Pest Act, permission  is granted to receive
foreign soil samples for use in laboratory analysis.

U.S. Army Corps of Engineers. Expires November 30, 1997.  Validated to perform methods
8280 & 8290 for Lockboume Landfill Site Investigation, Defense Distribution Depot Projects,
and assorted projects for the USAGE North  Pacific Division Laboratory.

U.S. EPA Region V. Expires November 14,1999. Dioxin in drinking water.

U.S. EPA Region  VIII,  for the State  of Wyoming.  Expires November 13,  1997.  Dioxin in
drinking water.

State of Utah, Department of Health.  Expires December 31, 1997. Certificate Number E-166.
Certification for the following parameters:  Semi-Volatiles and Volatiles under RCRA; Volatiles
under Clean Water Act; Dioxin/furans  by Method 8280; Drinking water for Dioxin by Method
1613; Metals including Mercury and Microwave Digestion.

Commonwealth of Virginia, Department of General Services, Division of Consolidated
Laboratory Services. Expires June 30, 1998. ID # 00341. Dioxin in drinking water.

State of Washington, Department of Ecology. Expires September 1998. Lab Accreditation
Number C067. Scope of Accreditation  applies to water analyses for Polychlorinated Dibenzo-
p-dioxins and Polychlorinated Dibenzofurans, BNA Extr (Semivolatile) Organics and Purgeable
(Volatile) Organics.

State of Washington, Department of Health. Expires April 30, 1998. Dioxin in drinking water.
 Lab I.D. 129

State of West Virginia, Department of Health.  Expires December 31, 1997. Certificate No.
9923(C). Dioxin in drinking water.
Revised 9/13/97 RM

Printed 9/18/97

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State of Wisconsin, Department of Natural Resources. Expires  August  31,  1998.
Laboratory  ID  Number 999869530. Certification for the following  categories of  Organics:
Purgeable, Base/Neutral, Acid, PCBs, and Dioxin. Expires November 14, 1999. Laboratory ID
999869530. Dioxin in drinking water.

PHARMACEUTICAL

Drug Enforcement  Agency (DEA).  Expires  November 30, 1997.  Registration  number
RT01195835. Controlled substance registration for schedules 1,2,3,3N,4,5.

N.C. Department of Human Resources. Expires October 31, 1997.  Registration number NC-
PT 0000 0031. North Carolina controlled substances registration. Application submitted for
renewal.

Food &  Drug Administration  (FDA) Registration. Expires June 1998.  ID  #'s  001500
1053481. Annual registration of drug establishment. Annual registration of drug establishment.

OTHER

Clinical Laboratory Improvement Amendments (CL1A)  Registration. Expires May 30, 1999.
ID  # 34D0705123.   Department of Health  & Human Services, Health  Care  Financing
Administration.

U.S. EPA  Large Quantity Hazardous Waste Generator.   No expiration date.   EPA ID
#NCD982156879. Permit indicates that the laboratory is a large generator of hazardous waste.

North Carolina Radioactive Materials License.   Expires April 30 1998. License No.  032-
0954-1. License authorizes the licensee to receive, acquire, own, possess, transfer, import and
use such radioactive materials as designated.

North Carolina General License for Radiation Protection. No. expiration date. License No.
032-875-OG.  The general license applies only to radioactive material contained  in  devices
which have been manufactured and labeled in accordance with specific requirements.
 Revised 9/18/97 RM
 Printed 9/18/97

                                                                         10

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DOCUMENT
  CONTROL
          Triangle Laboratories, Inc.
    801 Capitols Drive      P.O. Box 13485
    Durham, NC 27713-4411    Research Triangle Park, NC Z7709-348S
    H 9-544-5729        Fax # 919-S44-S491
                        i:

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  CLIENT CHAIN OF CUSTODY

     From: Pacific Environmental Services
         5001 S. Miami Blvd. Suite 300

         RTF, NC 27709
    Project Tell City, IN
                                           SAMPLER'S SIGNATURE.

                                               Contact Prank Meadows
                                                Phone: 919-941-0333
                                                  Fax: 919-941-0234
                                                ROJ;    ''	
   {PES03 /A JB)
                             If the data will be reported to a state agency, which one?.
  Sample Name
                      Date
Time
Comp
Grab
Matrix
Sample Amt.
                                                       Analysis Wanted:
                                                                                              -.sc
                                                                  P/Q 03898/0700003270
                                                                     ••••Hill. . J mi	i|iiininnniiiiiiiiiiiii,..i.....ii..^;»
                                                                     a..m—1.J1' V fffffff* S:f!S!SS~™..^*!T
                                                                     Total Number of

                                                                     Containers:
Remarks
£6±
                                                                     3
                                                      £
                                                                     .7  •
                                                                                   K,
fa ~
                                                     ?,/**-,
                                                                                   X
(So-23-3
                                                     ff/M, KAO
                                                                    7 rf»
                                                                                   y
                                                     fffar,
                                                           t, «o*M,
                                                                                   X
  Received for Laboratory By/Signature
                                           ale/Time
                                 Send Samples to: Triangle Laboratories, Inc.
                                               Attn: Sample Custodian
                                               801 Capl'.jla Drive
                                               Durham, NC 27713 USA
                                	Phone: (919) 544-5729 * Fax: (919) 544-5491

-------

                      ANALYTICAL REQUEST AND CHAIN OF CUSTODY
RECOVERY
PERSON:
SAMPLE   __>,

TECHNICIAN:  f,
SAMPLE IDENTIFICATION
    / ,,

    / (0 ,
                 CWLLECTION
                 DATE
      TIME
                            SAMPLE NAME
                      NUMBER OF
                      CONTAINERS
                                                   /
                                                               ANALYTICAL REQUEST
FBI-23..
                      /((OO
                               X
                                                                           •n
                           f&l-oa/O
                fl/
   f?
                                      .
                                     u Rit
                                     / Ca*
y
                                      fttfv,
                                «. f
                                       X
                                                                                    U?
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t/to/17
                                        ,
                                     i/r>*t*, if
                                     i  tt-Aa
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   - oofe-2-
                                       X
                                      'm
                                        », x/»o.
                                         *  ***
                               /*.
                                       X
                 tft/1?
                       *+-£&&•
                                2-*
                      Wttf,
                                      £ flU***"!

                                      •*  «W*1
                 7/H/W
          U .
  _

  nlUNQUSHERS NAME
     CEiVEW
     kl
                          S%Jffr4A
                           flEUNQUISHtfrS SIGNAJl)
                                'En'SSpMATlWE^'
                                ^F^F""~
                                                                              SHIPPER'S NAME AND ID NUMBER


-------
,09/09/97   10:13
               ©19199410234
                                        PES RTF NC
                                                                               003

                                                                           //wiJAft.V
                                                         Run No.: f fi> -
   Sample Date;
                             Filter No.fs): F6 - U, - \
   Sample Location:  2> A-S J-touS^P. "DiA-n KT
   Recovery Date: °\ JB R >
                             XAD-2 Trap Ho.(€):   Ffe - Z^>- I
   Sample Recovery Person: £^M fe£-

   Impingars
          XAD-2
            Trap
    1
(knockout)
(100mIHZO)
 (untipped)
(100mlH20)
  (tipped)
    4
(knockout)
(untipped)
Silica gel
(untiped
   Final wi
                                  . -2.
   Initial wt
                                                      51b.c
   NetwL
                       O.O
   Filter Color-
                                  Loading-   A)O/M£:
   Impinger Contents:
Silica'Gei: ©Grams Used- 3OO     Color- P>\u^
                                                     % Spent-
   Filter Container No,
                                                         marked/seatadfjE
                              ..
  XAD Module Container No.:   2.
   Probe (FH) & Back Half Rinse (Acetone) Container No.:  3
                                                         Uquid level
                                                         marked/sealed:
Probe 
-------
.-09/Q9/97   10; 19
•S19199410234
                                               FES  RTF NC
                                                                       003
- - - ----- - ~f^ 	 f
METHOD 23 CDD/CDF SAMPLE RECOVERY DATA



Plant: WAtjPACft .K^WD^Y
Sample Date: ^h\1> Filter No.fe): 80-2.3-1
Sample Location: B A6, H Q u-5 £ £> a-r ue-r
Recovary Date: ^ \Q k> XAD-2 Trap No.(s): 6D - *3 -
Sample Recovery Person: K^V-l ft£-
Run No.: 8 e -53-1
Job No.: SHIH. 0153




,1 2 3 4
Jmpingers XAD-2 (knockout) (100mlH2O) (100mIH2O) (knockout) SiBcagel
Trap • (untipped} (tipped) (untipped) (unflopedl
Final wt — 5^.6 >/>.> ?61-1 6i
initial wt. - MfV«0- 7 1^.55 >//.5 5?
Netwt — fcD.fe -AS --{.3 V
>33 ^^A.ld g
1,Jl ^Oto.^ j
•/ ^.T- g

Train System: Me^ha^n ^3 ~T/2/r/<"/
Probe: T C/^S5
Rlten Color- t-U/i^ TA/J Loading- Lifyjr
Implnger Contente: 0 ' Type -°- "2 O
Sfflca'Gel: ©Grams Used - JoO Color- //. i>K f % Spent- ^
Condensate Observed In Front Half: Aj&wE- •
^^it-ii^Sa^sS&^^^^^^fJf.?:^^^5^!^*^^^^^^^^;^^
Filter Container No. T"
XAD Module Container No.: Q
Probe (FH) & Back Half Rinse (Acetone) Container No.: ^
Probe-(FH) & Back Half Rinse (Toluene) Container No.: H
Impinger Contents Container No.: / 0
Impfnger Rinse (AcetonertJseS) Container No.: /

marked/sealed: .$?
marked/sealed: ^_
Liquid level *^
Liquid level -Sr""
marked/sealed: B<
Liquid level "
marked/sealed: ?<
Liquid level ^.
marked/sealed: 3%,
15




-------
09/09/97   10:19
               1^19199410234
                    PES RTF NC
                                                                               003
                  METHOD 23 CDD/CDF SAMPLE RECOVERY DATA
   Plant   \AJAu Pifcd   .
                                                        Run No.:
Sample Date:
                               Filter No. fs):
                                       Job No.:
  Sample Loeatton:    O AVfTl £rr~
Recover/ Date:
ID
                            XAD-2 Trap No.(s):
                                                       -  2-5-2-
  Sarnpte Recovery Person:

   Impingers
          XAD-2
           Trap
     1
 (knockout)
                            (100 ml H2O)
                              (unti'pped)
(100mlH2O)
  (tipped)
    4
(knockout)
(unHpped)
SiBca gel
(unti'pped)
  Final vrt.
   Initial wi
   Netwt
Train System:
                                 23
  Probs:
  Filten Cater-  f4...
                      ittrv
                                  Loading-
  Impinger Contents:
  Sifica'Gefc @<3ramsUsed- 3Qo    Color- |j. My.t    % Spent- fTO
  Condensate Observed In Front Haft  kfox) E.
  Filter Conteiner No.
                                                         marked/seated:^
  XAD Module Container No.:
  Probe (FH) & Back Half Rinse (Acetone) Container No.:
                                                 18
                                       Liquid level    -^
                                       marked/sealed;£&-
  Probe-(FH) & Back Half Rinse (Toluene) Cgntatner.No.:
                                                         Liquid level
                                                         marked/sealed:^
  Impinger Contents Container No.:     I i
                                                         Liquid level
                                                         marked/sealed:1:
  Impinger Rinse (Acetone/M^6) Container No.
                                                        Liquid level     _
                                                        marked/sealed:
                                                                    16

-------
09/09/97   10:19
©19199410234
PES RTF NC
a 003
METHOD 23 CDD/CDF SAMPLE RECOVERY




Plant" UlrtuP/kx-l f-OH^D/lv
Sample Date: (\ ( 1 o 1^- Filter No,®:
Sample Location: D A t) Mb U^ £ U^~tt
feo-Z3-3
-E-T
Recovery Date: ^1)1 H"^" XAD-2 Trap No.(s); B<3 - 1
Sample Recovery Person: j%li_}L
«
DATA
Run No.: ID -Z3-^'
Job No.; SHH. Oo3

-3-3


1 2 .
Irnpingers XAD-Z (knockout) (100mlH2O)
Trap ' (untipped}
Final wt
Initial wt. - Hfl5-H ^TAf\
NetwL ~ £%,7 . 72$, ^
3
(100rnlH2O5 (k
(tipped) (u

">"25.S t
-72.3,5" ^
4
nockout) Silica gel
niipped) (untipped)
S

*z.$ feffeV g

Train System: E-Pft " ^&r«i5D 2-5 / 6c
Probe: ~~\^ ^LA5S
^ It: w-^1



Filten Color- /^^ Loading- £j :^f
Impinger Contents: "/^ jf L(J*4«~~
Silica' Gel: ©Grams Used - 3P^ Color -H. Hue % Spent- f£p
Condensate Observed In Front Halft /Joft&

Filter Container No. At?
XAD Module Container No.: / ^

\
Probe (FH) & Back Half Rinse (Acetone) Container No.: XT
Probe -(FH) & Back Half Rinse (Toluene) Container No.: r T"
mpinger Contents Container No.: / G
Impinger Rinse (Acetone/Me€G) Container No.:


- 	

marked/sealed?^
marked/sealed^:
Liquid level '//-
marked/sealed^^
Liquid level ,/~*
marked/sealed^; „
Uquld level flV
marked/sealed!^
Uquld level ______ .
marked/sealed:
17





-------
39/09/97   10U9
'SM9199410234
                                                 RTF NC
                                                                       002
- - ^ 	 	 p^ 	 ? 	
METHOD 23 CDD/CDF SAMPLE RECOVERY DATA ^f, ***


Plant {AJfoPACfi fbudly-
Sample Date; V' ' A 7 Filter No.fs); /^^ 2 3
Sample Location: /><5^f fsi**f< *f -54s*/*' ,J/Tk -
Recovery Date: ' 9/7 A? 7 XAD-2 Trap No.(s): /SSfc-
Sample Recovery Person: (${£*& /$• &/*~f}
_ f^ _-:
KUH NO;,"/ ^J"2~* i
JobNa^jffMtfpS
%/Sc*c, O^/
-2,3


1 23
Impingers XM3-2 (knockout) (100mIH2O) (1oamlH2O]
Trap ' (untipped) (tipped)
Final wt ~
Initialwt. - tj~?(ff3 ~7s>2.lf 7&7.fy
Netwt — tyJifA "7&3.,?> "~?o~7.g
4
(knockout) Silica gel
(untipped) (uniipped)
f
G^i'tc 8?O-*-l f
4 11 6 €70/2" g

Train System: 6^4 ^C-VKcol ^3
Probe: T Qla-$5


Rlter: Color- Ui^i^ Loading- A^o^e^
Impinger Contents: C/^A,
Silica' Gel: ©Grams Used- " ^Q Color- M^/L^i* % Spent- &
Condensate Observed In Front Halft Af® i*s/

Filter Container No. • 177
XAD Module Container No.; 90 \ '
Proba (FH) & Back Half Rinse (Acetone) Container No.: y\e
Probe 
-------
    PACIFIC ENVIRONMENTAL SERVICES, INC.
    Prepared By
Date
Checked By
                                        Projf ct No.
                                                          Page
                                                                of
                                        Client
                                        Location
                                      Date
Sheet Title
 flktkr
            -00(0
                                                          Hi*
                                                                                   ©
                                                                                   cp
                                                                                  ^
                      *f7
                                                       &*»; - 6*£\
                                                             __
                                                               — -
THH& /?2.f
                                                                                          19
                     WASHINGTON, DC • RESEARCH THIANGlf WBK, NC • LOS ANGELES, CA • CINCINNATI, OH

-------
Prepared By       Date   Checked By   Date   Sheet Title

'OSk
                                                                        is**
                                                   .
                                                                                                 20
                   WASHINGTON. DC • RESEARCH TRIANGLE PARK, NC • LOS ANGELES, CA • CINCINNATI. OH

-------
                  AIR QUALITY PREPARATION WORK ORDER FORM
                          TRIANGLE LABORATORIES, INC.
 TLI Project Number:
  Client/Company Name:
  Project Manager:
  Client MILES Code:
  Quote Number:
     _RIters
     _3%"/9.0 cm
     _4"/1Q.16cm
              Due Date:
                                                                   j / 5
                                ORDER INFORMATION
             Order Date:
             Client Project #:
             Client P.O. #:
                                                                   X>gA
     jH4Y11.0c-/Ball and Socket      Sandwich PUF:
	Socket and Socket    Ship PUFs in :
	Screw cap
	Other	*__
                                                                yes
                                                                jars
                               no
                               sleeves
 Filter Material:
 Ship filter in:
                   .Quartz
                   . one petri dish
. glass fiber     other.
. separate petri dishes
 Prepare r:
 f of Laboratory Blanks:
 XAD Resin Batch #:
 Pre-spike required:
 intended Analysis:
  (Ckeii til acpfica=l»)

 Spiker/Observer Initials:
 Spiking Date:
 Spiking Solution ID:
 Volurnn Spiked (uL):
 Nominal Concentration:
 Expiration Date:

 PCDD/PCDF Surrogates
WCI.-2,3,7,S-TCDO
"C,r2,3,4,7,a-PeCDF
I3C«-1,2,3,4,7,8-HxCDF
"C,*-1,2,3,4,7,8-8x000
aC«-1,2,3,4,7,8,9-HpCOF
Ship to the Attention of
Mailing Address
Street Address

Phone Number
Special Instructions:
                         AtfpL€)>REPARATION INFORMATION
                                                       Date:
                       (  \
                       ^
                                 HR-PAH    HR-PCB
                       4L^L/_>:

                 Supplier:  ^f^feJc-^

                 LR-PAH     SV Table 2
                                                             Qrganfcs
                                             pg/mL
                             PAH-HRMS Surrogates
                             Terphenyl-dw    	n
                             FIuorene-dia
                             PAH-LRMS Surrogates
                             Terphenyl-d«      ^\ia

                               SHIPPING INSTRUCTIONS
                PC B-HRMS Surrogates
                >3C»z-3f3',S,5'-TatraCB       	ng
                "C,I-212',4,5,5'-PentaCB    	ng.
                aC,l-2,2',3I4,4t,5'-HexaCB  	ng"
                13C,i-2,2',3,3',5,S',6,r-OcteCB	ng
                                           U.
                                                  UMM-Lu£
Form Prepared by
                                   Signature
Please return this form to Triangle Laboratories, Inc. with the samples.
                                                                          21

-------
-THIMJSLE LABORATORIES,  IRC.  -- M» III RECORD/CHMH OP CUSTODY-
U Custody Seal t Absent Sample Seals: Absent
| Chain at Custody ! Present Cont«ln»r, ,. i Intact
| Sample Tags : Absent
| Sample Tag Humbert?; Not Listed on Chain o€ Custody
( SHO Forms ; M/A
| TM Project number 4322i | Book |
| Client: PESO 3 - Pacific Environmental Service* | j
1 J/ 1^1" 1
I s^ S J1 jf >ff
j Date Received j 09/12/S7 j B^X^%^^^^«^Q-
	 , 	
|| Ice Chest ICE Temp 5.0 C | carrier and number | MICHAEL MELBOURNE | 1 f I
HTLI Kumber ..Client Sample ID. 	 	 	 	 	 .Hatrix| To LAB | To STORAGBf


JJ183-1-1A FB1-23 HI MWBfcHt^ f\ "VW
| FB1-23 « C01 j C^"Y\^T j |*tM*R
|1»3-1-1B FB1-23 *2 3WD| \ 1
j FB1-23 • C01 | 1 / /\
i i i / v
|1«3-1-1C FB1-23 R3 ACE/TO& RIHSBJ " 1 j IjjS
|| FB1-23 * C01 j 1 \f*
1 1 1 I\-
JJ1B3-1-SA BO-23-1 »7 FIMERJ 1 j \
|| BO-23-1 * C01 I 1 1 \
»l 1 1 \ 	
It j 1
J1BJ-1-2B BO-23-1 *8 XAD| 1 | 1
B BO-23-1 * C01 ill
1 1 \ i /
J1I3-1-2C BO-23-1 »S ACB/TOI, MHSEJ \ j /
1 BO-23-1 * GDI * 1 1 \*S
1)199-1-20 BO-23-1 flO 1ST IMP COKDENSATE] 1 | 1
| BO-Z3-1 * C01 | | U /
jjli3-l-3A BO-23-2 dlB FIWERJ J"\
|| BO-23-2 * C01 • j | )
I1I3-1-3B BO-23-2 »17 XAD| \f ..
I) , BO-23-2 * C01 | 1 j( V^W "
J1H-1-3C BO-23-2 #11 ACi/TOL RINSE i j {
|| SO-23-2 * CO! 1 j 1
u I ' -t^-
||H3-1-3D BO-23-2 «19 1ST IMP COHDEHSATE| |
|| BO-23-2 « C01 | !*(/
t! in i — i - — ^ / 	
II 1 -p^
||1«3-1-
-------
                                        -TRIAHOLH LABORATORIES, INC.  — LOO IK RECORD/CHAIN OF CUSTODY-
Custody Semi » Ahsiont Sample Seals 1 Absent
Chain ot Custody t Present Container . * i Intact
Sample Tags t Absent
Sample Tag numbers j Not Listed on chain o£ Custody
SHO Forma i H/A
Ice Chest ICE Temp S.O C
•I Number.. ....Client Sample ID,. 	 Matrix j To
t/HiCPM. ..... Client COC ID.,,,..* 'Location 	 | Dak

LAB
e/Init
*^
I3-1-4D BO-23-3 128 1ST IMP COMPENSATE p^
BO-23-3 • C01 iH-rt'^l^'
I3-1-5A FD2-23 S34 F1LTER|
F12-23 * Col |
I3-1-SB PB2-23 *3S XM>|
PB2-23 * C01 j
	 — . . 	 -. 	 _ 	 j 	
IJ-X-SC FB2-2J #36 ACI/fOIi RINSE | *•
F82-33 * C01 I
	 1 —
13-1-6A FILTER BLANK 837 FILTERJ
TRIP BtABK * C01 |
13-1-6B XAD TRAP BLANK S38 XAD|
TRIP BLANK * CD1 j
j
13-1-6C AC6TOHB BLANK »39 ACETONE BLANK |
TRIP BLANK * COJ j
- 	 1 	
U-1-6D TOLUENE BLWK §40 TOUJRN1 BUNK)
TRIP BUWK * COJ j
	 	 	 ,• 	 j 	
t


	 1


\,
13-1-6B TtVB II MAT1R BLMK #41 WP8 II KATER BLANK) M|
tup syusic * on. 1 y
	 ,. 	 	 , 	 	 _ 	 » 	 i. 	
1
1
	 	 	 „ 	 	 	 	 	 	 	 -. 	
1
1
1
i
i
i



TLI Project Number 43229 * | Book |1
Client! PESOS - Pacific Environmental Services | )
Bate Received !„/„/„ j By/^^^ JT^^^j
1 	 • 	 — 	 -~r-\ ||
Carrier and Number | MICHAEL MELBOURNE | i [
To STORAGE
tmte/Init
i/VL- 	 1
ci^W)
f
")
1
i
i \ >r .*4.)

\

J
\
w



—


V





TO LAB
Date/Init

'-




| 	 1







To STORAGE]
Date/Init














To LAB
Date/Init






.







To STORAGE
Date/Init
**



-


'•






To LAB
Date/Init














To STORAGE
Date/lnlt
	

	 —
	 (






	 1



DISPOSED H
Date/Init |]
1
1
D
	 	 1
1
1
	 u
;

!
0
i
J
1
11
1
II





Receiving Remarks:
                                                                                                                                                               ri
                                                                                                                                                               c-J
Remarks:
                                                    -Form Revised OS/27/l«7 «

-------
                       TRIANGLE LABORATORIES, INC.
               SAMPLE TRACKING AND PROJECT MANAGEMENT FORM
	ADMINISTRATIVE INFORMATION	
 TLI Projt: 43229-      Samples: 6           TurnAround.:  7 Day(s)
 Prod Code: D23061      Matrix.: M23Train    Hold Time..:  0 Day(s)
 DetectLim: 0.05 ng     Type...: A           Start Date.:  09/12/97
                        Recvd..: 09/12/97    Ship By..,.:  09/18/97
                                             DWL Due Dt.:  09/16/97

 Analyte List.: M23/Tetra-Octa

 Method	: Method 23 :Tetra-Octa (Tol Combined)
 Client Proj..: S414.Q03/WAUPACA Foundry
 Client	: Pacific Environmental Services (PESOS)
 P.O. NO	: S414.003                     Collect Dt/Tm: 09/08/97
 Contact	: Frank Meadows                Phone	: 919-941-0333
 Proj . Mgr. . . . : Amy J. Boehtn                 Pax.	 . . : 919-941-0234
                                             Sample Origin:
		SPECIAL INSTRUCTIONS / QA REQUIREMENTS	
 Prep Project:  03897                     Prespike Standard: USD-C,  USD-S
                                         Prespike Amount..: 4.Ong
	REPORTING REQUIREMENTS-
 Reporting Format:  Report Option II

 See MILES for Instructions/Communications.
 Completed by:  	  DATE:
 Reviewed by:     /	  DATS: -q/teAp*     (PMGT0197)
                   *
                                                                  24

-------
                          PROJECT COMMUNICATION TRACKING FORM
                                                                             0age	of,
                            "TL1 Project Number:
     Use this form to record all exchanges of information between production units as well as personnel
     • handling triis project. Decisions, corrective actions and recommendations must also appear on this
                                      tracking document
Oate-jNarne  Comment / Decision / Resolution / Action / Observation







••-/
« ,.«-."

M
wv
r
1 '
1' i

I-L1
•] "•
.(„.:

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fc tl-^t~
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ot




\


ig-de
•tO
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-
x
ty
'f 0/-- b
SPIKES S*i2.
' ' PREPARES G.L." 	 ; 	 	
PACIFIC E/W.

.
•
ftLLTCASS SEbWN H-e9 1E.(3^CT c^?^>"
OS-CO BD.lX.-toKb ^c^^tlc-^xft^ c5\4 ?-A5C lcet.t5. PfODcc->B
"' .
»
' *•

«



•

-------
Date: 09/15/97
Time: 09:27
 Sample
 N  crci TI.I Number. .  Customer.Sample.Id.

 000    TH Blank    TLI M23 Blank

 001    183-1-1A-C   FB1-23

 002    JBJ-1-2A-C   BO-2J-1

 003    183-1-3A-C   BO-23-2

 004    183-1-4A-C   BO-23-3

 005    183-1-5A-C   PB2-23

 DOE    1B3-1-6A-D   Trip Blank

 007    TLI'LCS      TLI LCS

 008    TH LCSD     TLI LCSD
F.
No
0
1
1
1
1
1
1
0
0
TRIANGLE LABORATORIES, INC.
Het Lab MM5/PUF Observations
Project! 43229
XAD Filter Glaaa Kool PUF Air
Color 	 Color 	 Color 	 Color 	 Odor 	 Q.No. Entered. By,.
WHITE NA HA HA
WHIUTE WHITE WHITE NA
WHITE BEIGE WHITE NA
WHITE BEIQE WHITE NA
WHITE BEIQE WHITE NA
WHITE HHITB WHITE HA
WHITE WHITE WHITE HA
LOT P-935
LOT P-935
NA 03697 HILLKT
NONE 03897 HILLKT
NONG 03897 HILLKT
NONE 03897 HILLKT
NONE 03897 HILLKT
NONE 03897 HILLKT
NONE 03897 HILLKT
HILLKT
HILLKT
PRDPERC V4.0D
Page: 1
0
	 Date 	 Time 	 S CO
09/15 09:24
09/15 09:24
09/15 09:24
09/15 09:24
09/15 09:24
09/15 09:24
09/15 09:24
09/15 09:24
09/15 09:24
F
F
F '•
F
F
F
F
F
F
 «»* End of Report •••

-------
   Project:  43229
                                                     TSaK312 IABQRATORIES,  INC.
                                         Dioxin Sample Preparation Tracking & Management  Form
                                                                              Client:  Pacific  Environmental Services  i?SS03J
                                                 PAGE 1 OF 1      |
  Solvent{s)/Rcidl3>;
  toe numbers:
                                  /
  .Method: Method Z3:Tetra-Octa (Tol Combined)   Matrix;
Extraction Data: tl / 1
    IS Spike:    40 J»l  cone:    0.1000  r.g
MS Suite: 0 ill cone: 0.0000 na/ul 1 CX»?"1 | CS>?-fft^ I
LCS Spikes 0 jil cone: 0,0000 nq/fil 1 "SZ.^^'C. | o 255c I
OPR Spike: _20 Ml cone : 0.01 ng/jil n .-a*,! /-\l E.?/1^ /5l P* / '"^ /^ 1
+ 	 „ „ + 	 +. _ .jypTEft&.a'k//^ /fj'i cfi/iH ^^|
I t TLI / | SK3SS | SAMPLE | o( !^f/| | ^ i JjJ 1
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I
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                                                                             XXXXX » Grass Weight not provided £or WATER Sa
                                                                            	.	REy as/j7/97 (PS
                                                                                                                     27

-------
PAGE 1 OF 1
TRIANGLE LABORATORIES, INC.
DIOXIH SAMPLE EXTRACTION and CLEANUP TRACKING FORM '
TLI Project No. : 43229
Ext Stt.crd and |
TLI Number |
1 /• i j ' r ' •*
1 ^ 1 Ifr 1 u> 1 ~;
| ^ \j^$fiA $T$
iQ^.r
1B3-1-1A-C |
002 |
1B3-1-2A-C |
003 |
1B3-1-3A-C |
004 |
1B3-1-4A-C |
005 |
183-1-5A-C |
ooe |
183-1-SA-D |
007 |
TLI LCS |
»
008 | V/1
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7-1 i
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i i
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i i
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i i i
i \ i
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1 1 1
1 1 1
Enter the procedure number below into the
Initial and date each sample for each numl
tt PROCEDURE DETAILS
gfpEXTRACTION A ON_f OF]
^1 SPIKE AFTER EXTRACTION '1 fll'W^i
(5? ADD TRIDECANE ^ 1^
Qj) ROTOVAP CrS^cW '40mL /
C£? DIVIDE / LIPID DETERMINATION 20%/80%
 SOLVENT EXCHANGE
,g93 CLEANUP
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10) ADDITIONAL CLEANUP
11) FINAL TRANSFER
!
!
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!
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box at the top of each column to signify the step performed.
lered procedure performed.
(circle)
*_/^«Eiet / Jar / Sep Funnel / Steam Dist / Cont LL / ASE / Waste Dilution
m*^
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SPt/50% SmL/20mL Other
<^~s
(SsFJeO / DSP 225 / DSP 115 / DSP 215 / DSP 267 / Other
Mod. DSP 260 / DSP 225 / DSP 115 / DSP 21S / DSP 267
/ Other

Comments :








v 06/24/97 (PSTMP 4).=+
23

-------
                                                                    PAGE 1 OF 1
                           TRIANGLE LABORATORIES,  INC.
                          Transfer-Chain-of-Custody Form
                                  Project  43229

                       Transfer  Prom;  DWLH5      To:  DMS5

                              Initials, .    Date	,     Time.

                Released by.    {JLE        _3_j'_L2j'$2    26 :

                Accepted by:     $S>
           MILES. ID	   TLI No.
           43229-
           43229-
           43229-
           43229-
           43229-
           43229-
           43229-
           43229-
           43229-
-000
-001
-002
-003
-004
-005
-006
-007
-008
                       Gust.Id,
TLI Blank ^
183-1-1A-C ""
183-1-2A-C/
183-1-3A-CI'?
183-1-4A-CI/
183-l-5A-ClX.
183-1-6A-D1/
TLI LCS  /-
TLI LCSD /
TLI M23 Blank
FB1-23
BO-23-1
BO-23-2
BO-23-3
FB2-23
Trip Blank
TLI LCS
TLI LCSD
+				XfrCOC  (Rev 11/01/94)	
  Additional comments or instructions:
                                                                       29

-------
                                                                                                                 PAGE 1 OF 1
Method: Method ZSsTetjra-Occa (Tol Combined)
Required Detection Limit:  0.05 ng
                                                  TRIASCLE LABORATORIES, INC.
                                                     HI GC/HRHS MOU.YSIS
IPROJECT:   43239
                                                      SAMPLE XNFORMATTOW
                                    1ST CQUMH
                                                                            2KB COLOW
                                                                                                               RS Cone
                                                                                                          20 jil *  100.0 FQ/jil
| | TLI / | QC/MS KLENAMEj«0«FI8M [CONFIRM FILENAME -ftffl-ItS lOSF-BS,, (ANALYSIS ;
]S#,cnJ| SAMPLE It) / CLIENT | COLUMHs "Off*? 1 ICOLOMtC: ~|7p' ^f^OMMB-SJiWl IBM X-j> [COHMSHTS !
| i / SAMPLE ID | V ' | | ' [SOLS 1C |DATEL[^L i
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1
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| 133-1-3A-C 1
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Type: A |
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Spike file: SPX23704 |
Amt at Extract! SO* }
                                                                                                        -REV 03/87/9S  IPSWF *) —

-------
                                                        Triangle Laboratories, Inc.
                                                               Run Log
      Instrument ID
        Column Type
                    Column ID
                   Plot Name
                            Int. Vol.
                                    Acquisition
                                                                                          Signature
                                     G/e   en
                                                                                                       Date
    Filename
Data'
Time*
Sampled
No.
Client Sample ID
Syr
332
Operator/Date
Comments**
                                                      r
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*     Transcribed from chromatographic data
"     Dated initials required

srvrl/qa/forms/hrrun!og.doc (02/05/97)
                                        ConCal Due:
                                        ConCal Due:
                                                                                                                 Pane:
                                                                                                                          45

-------
                                                        Triangle Laboratories, Inc.
                                                               Run Log
Instrument ID Column Type Column ID Plot Name Ini. Vol. Acquisition C3/Q ^*
^-^7 ;. 	 *>/»fa
*~* — ""agnattfre
Date
    Filename
          Date*
Time*
Project #
Sampled
No,
Client Sample ID
Syr
332
Operator/Date
Comments**
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           ±
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Transcribed from chromatographic data
Dated initials required
shw1/qa/form8/hmmtog.doc
                                 ConCal Due:
                                 ConCal Due:
                                                                        f'-l
                                                                                                                           4G

-------
                                                      Triangle Laboratories, inc.
                                                              Run Log   *'$
Instrument ID Column Type Column ID Plot Name ! i. In). Vol. Acquisition
in *-M*MA»/^
Signature
®£ _ r.
1/M/tf
'Date
Filename
                 Dale*
Time*
Project*
Sample#
No.
Client Sample ID
Syr
332
Operator/Dale
Comments*
                                                         II
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       Transcribed from chromatographic data
**      Dated initials required

sivr1/qa/forms/hminlog,doc (02/05/97)
                                                        ConCal Due:
                                                        ConCal Due:
                                                                                                                             92

-------

-------
SAMPLE
  DATA
        Triangle Laboratories, Inc.
  801 Capitals Drive       P.O. Box 13485
  Ourtiam,NC 277134411     Research Triangle Park, NC 27709-3485
  919-544-5729          Fax # 919-544^1

-------
                           TRIANGLE LABORATORIES, INC.
                    Sample Result Summary for Project 43229
                     Method 23X Full Screen Analyses  (DB-5)
                                                 Page   1
                                                  09/22/97
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
T976373
TLI M23 Blank
ng
09/14/97
09/18/97
T
XAD
Soxhlet
T976374
FB1-23
ng
09/14/97
09/18/97
T
M2 3 TRAIN
Soxhlet
T976375
BO-23-1
ng
09/14/97
09/18/97
T
M2 3 TRAIN
Soxhlet
T976376
BO-23-2
ng
09/14/97
09/18/97
T
M23TRAIN
Soxhlet
 Analytas
 2378-TCDD
 12378-PeCDD
 123478-HxCDD
 123678-HxCDD
 123789-HxCDD
 1234678-HpCDD
 OCDD
 2378-TCDF
 12378-PeCDF
 23478-PeCDF
 123478-HxCDF
 123678-HxCDF
 234678-HxCDF
 123789-HxCDF
 1234678-HpCDF
 1234789-HpCDF
 OCDF
 TOTAL TCDD
 TOTAL PeCDD
 TOTAL HxCDD
 TOTAL HpCDD
 TOTAL TCDF
 TOTAL PeCDF
 TOTAL HxCDF
 TOTAL HpCDF
(0.03)
(0.04)
(0.04)
(0.04)
(0.04)
(0.05)
(0.06)
(0.02)
(0.03)
(0.03)
(0.03)
(0.02)
(0.03)
(0.03)
(0.03)
(0.05)
(0.06)
(0.03)
(0.04)
(0.04)
(0.05)
(0.02)
(0.03)
(0.03)
(0.04)
(0.02)
(0.04)
(0.04)
(0.04)
(0.03)
(0.04)
{0.02}
(0.02)
(0.03)
(0.03)
(0.02)
(0.02)
(0.02)
(0.03)
(0.02)
(0.04)
(0.04)
(0.02)
(0.04)
(0.04)
(0.04)
<0.02)
(0.03)
(0.02)
(0.03)
 Other Standards Percent Recovery Summary (% Rec)
 37C1-TCDD             94.
 13C12-PeCDF 234      105
 13C12-HXCDF 478       96.1
 13C12-HXCDD 478       94.8
 13C12-HpCDF 789       87.0
                101
                106
                 96.4
                111
                108
 Other Standards Percent  Recovery Summary (% Rec)
 13C12-HXCDF 789       53.6             70.2
 13C12-HXCDF 234       61.4             69.5

 Internal Standards Percent Recovery Summary (% Rec)
 13C12-2378-TCDF       48.2             51.0
 13C12-2378-TCDD       46.3             51.0
 13C12-PeCDF 123       40.6             40.5
 13C12-PeCDD 123       43.9             45.1
  0.23
  0.44
 {0.15}
  0.24
  0.32
  0.38
 {0.11}
 15.5
  3.1
  3.9
  2.9
  1.5
  0.93
  0.10
  0.97
  0.17
 {0.08}
  7.0
  3.4
  2.8
  0.67
131
 57.6
 15.0
  1.6
                 95.5
                102
                104
                 84.6
                 96.7
                                  62.2
                                  66.3
                                  52.4
                                  47.3
                                  44.9
                                  49.3
  0.54
  1.7
  0.74
  1.4
  1.9
  2.1
  0.59
 32.9
  9.5
 12.5
 13.2
  6.9
  4.8
  0.50
  5.6
  0.94
  0.41
 20.1
 14.4
 15.2
  4.0
262
175
 65.7
  9.3
                  94.9
                 100
                 103
                  90.7
                 116
                                   69.5
                                   63.8
                                  60.1
                                  49.4
                                  48.5
                                  47.3
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                   Printed: 17:05 09/22/97

-------
                         .  TRIANGLE LABORATORIES, INC.                  Page  2
                     Sample Result Suwnary for Project 43229             09/22/97
                      Method 23X Full Screen Analyses  (DB-5)
 Data File            T976373          T976374          T97637S           T976376
 Sample  ID         TLI M23 Blank        FB1-23          BO-23-1           BO-23-2

 Units                 ng               ng               ng                ng
 Extraction  Date    09/14/97         09/14/97         09/14/97          09/14/97
 Analysis Date      09/18/97         09/18/97         09/18/97          09/18/97
 Instrument              T                T                T                 T
 Matrix                 XAD           M23TRAIN         M23TRAIM          M23TRAIN
 Extraction  Type     Soxhlet          Soxblet          Soxhlet           Soxhlet
  Internal  Standards Percent Recovery Summary  (% Rec)
  13C12-HxCDF  678       62.2             71.2             62.3              58.7
  13C12-HXCDD  678       63.5             68.0             71,4              64.8
  13C12-HpCDF  S78       51.7             66.7             43.0              58.8
  13C12-HpCDD  678       59.8             81.0             51.8              72.8
  13C12-OCDD            55.1             82.4             48.2              70.5
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive » Durham, North Carolina 27713                                   Printed: 17:05 09/22/97
Phone: (919} 544-5729 « Fax: (919) 544-5491                                            3 6

-------
*


Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Analytes
2378-TCDD
12378 -PeCDD
123478-HxCDD
123678-HxCDB
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-JeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDP
234678-HxCDP
123789-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
TOTAL TCDD
TOTAL PeCDD
TOTAL HxCDD
TOTAL HpCDD
TOTAL TCDF
TOTAL PeCDF
TOTAL HxCDP
TOTAL HpCDF
Other Standards
37C1-TCDD
13C12 -PeCDF 234
13C12-HxCDF 478
13C12-HXCDD 478
13C12-HpCDF 789
Other Standards
13C12-HXCDF 789
13C12-HXCDF 234
TRIANGLE LABORATORIES, INC.
Sample Result Summary for Project
Method 23X Full Screen Analyses
T97S377 T976378
BO-23-3 FB2-23
ng ng
09/14/97 09/14/97
09/18/97 09/18/97
T T
M23TRAIK M23TRAIN
Soxhlet Soxhlet

0.73 (0.01)
2.S {0.02}
1.1 (0.02)
2.2 (0.02)
2. '5 (0.02)
3.2 {0.02}
{O.S7} {0.02}
48.1 (0.01)
13,8 <0,Q2J
18.8 (0.02}
18.6 {0.09}
9.0 0 . 04
7.0 (0.02)
0,75 (0.02)
7.3 {0.05}
1.3 (0.03)
0.65 (0.03)
33.2 (0.01)
30.2 0.05
22.6 0.12
6.0 0 . 04
336 (0.01)
260 0.22
94.4 0.23
12.7 {0.05}
Percent Recovery Summary (% Rec)
99.2 94.3
111 106
102 94.1
88.7 81.7
113 101
Percent Recovery Summary (% Rec)
70.8 68.2
66.5 73.1
Page 3
43229 09/22/97
(DB-5)
T975379
Trip Blank
ng
09/14/97
09/18/97
T
M23TRA.IN
Soxhlet

(0.03)
{0.04}
(0.03)
(0.03)
(0.03)
0.04
(0.05)
{0.28}
{0.10}
0.17
0.16
0.07
{0.05}
(0.03)
0.07
(0.04)
(0.04)
(0.03)
{0.20}
0.13
0.04
1.1
1.4
0.63
0.07

94.6
104
98.0
83.8
87.8

61.8
63.3
Internal Standards Percent Recovery Summary (% Rec)
13C12-237S-TCDF
13C12-2378-TCDD
13C12-PeCDF 123
13C12-PeCDD 123
64.4 53.6
47.0 56.0
43.5 44.1
43.3 47.4
49.6
50.4
39.8 V
43.3 RO
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
l: 17:05 09/22/97

-------
1*1
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
Internal Standards
13C12-HXCDF 678
13G12-HXCD0 678
13012-HpCDF 578
13C12-HpCDD 678
13C12-OCDD
TRIANGLE LABORATORIES , INC. Page 4
Sample Result Summary for Project 43229 09/22/97
Method 23X Full Screen Analyses (DB-5)
1976377
30-23-3
ng
09/14/97
09/18/97
T
M2 3 TRAIN
Soxhlet
Percent Recovery
57.3
73.9
65. 2
79.4
77.0
T976378
FB2-23
ng
09/14/97
09/18/97
T
M23TRAIK
Soxhlet
Summary {%
72.2
86.0
58.1
68.8
67.4
T976379
Trip Blank
ng
09/14/97
09/18/97
T
M23 TRAIN
Soxhlet
Rec)
52.6
72.7
57.4
67.0
67.5
  {Estimated Maximum  Possible Concentration},    (Detection Limit)
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 « Fax: (919) 544-5491
Erjqted: 17:05 09/22/97

-------

-------
TLI Project:      43229
Client Sample:   TLI M23 Blank
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:  T976373
Client Project: S414003/WAUPACA Foundry
Sample Matrix: XAD Date Received: / / Spike File: SPX23704
TLI ID: TLI Blank Date Extracted: 09/14/97 ICal: TF53286

Sample Size: 1.000
Dry Weight: n/a
GC Column: DB-5




Date Analyzed: 09118/97 ConCal: T976372
Dilution Factor: n/a % Moisture: n/a
Blank FUe: T976373 % Llpid: n/a
Analyst: KAS % Solids: n/a


ISSSlSS&iSfe^^S^^lis^^^Sf^pi^l^^l^
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxODF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF

Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF

Ssssdlll;:
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND

ND
ND
ND
ND
ND
ND
ND
ND

i™ftMafc^B8SiSS^S8^^fci^^^^^SS8^^8jtesss*5BBS^K«SI8^ss«^SHM
0.03 	
0.04 	
0.04 . 	
0.04 	
0.04 	
0.05 	 ,
0.06 	
0.02 	
0.03 	
0.03
0.03 	
0,02 	
0.03 	
0.03
0,03 	
0.05 	
0.06 	

0.03
0.04
0.04 	
0.05 	
0.02 	
0.03
0.03 	
0.04 	
                                      Page 1 of2
                                                                       x2j?j>SR »ioo. LAIS is.i urn
Triangle Laboratories, lnc.«
801 Caplola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                        id: 01:16 09/22/97

-------
TLI Project:
Client Sample:
                  43229
                  TLI M23 Blank
Method 23 PCDD/PCDF Analysis (a)
             Analysis File:  T976373
'JRtemaf Standards' ™-: v> ' — -"/
'3Ci2-2,3,7,8-TCDF
'3Cl2-2,3,7,8-TCDD
13Ci2-l,2,3,7,8-PeCDF
'3C12-l,2,3,7,8-PeCDD
13Cl2-l,2,3,6,7,8-HxCDF
13C,2-l,2,3,6,7,8-HxCDD
l3C12-l,2,3,4,6,7,8-HpCDF
l3CI2-l,2,3,4,6,7,8-HpCDD
13C12-1,2,3,4,6,7,8,9-OCDD
Surrogate Staadatste $%p* A^ , ~f
"CLrZSJ.S-TCDD
13C,2-2,3,4,7,8-PeCDF
13C12-l,2,3,4,7,8-HxCDF
13Cu-l,2,3,4,7,8-HxCDD
»Cn-l,2,3A7,8,9-HpCDF
^tea^^ndaRjs'trspe A^
13C,2-l,2,3,7,8,9-HxCDF
'3C,2-2,3,4,6,7,8-HxCDF
'ReGOwrVSlaadanlS' ,--v--;,^% -d^
13C12-1,2,3,4-TCDD
13C,2-l,2,3J,8,9-HxCDD
W«*
1.9
1.9
1.6
1.8
2.5
2.5
2.1
2.4
4.4

3.8
4.2
3.8
3.8
3.5
lint (ng
2.1
2.5
.s*v


l^^Kfto&jp
48.2
46.3
40.6
43.9
62.2
63.5
51.7
59.8
55.1
j t,-. v ^&Rd£&V6
94.1
105
96.1
94.8
87.0
) ^ ~ ^Reoww
53.6
61.4
--v'^Vp^-;


r^JtQdOmlte^^
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
\
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%
jy7««JS|fti"?t."
40%-130%
40%-130%
/>> v;V>"-%r:x


rRatfo? <:
0.77
0.76
1.60
1.44
0.49 ,
1.23
0.41
0.98
0.92
fc«fe" .

1.55
0.50
1.23
0.43
. * ... .
0.49
0.50
Ha"*- •:'}.
0.83
1^5
"RfV;™lFfegs^
20:49 	
21:36 	
25:02 	
26:09 	
28:44 	
29:27
31:25 	
32:15 	
34:45 	
WT Ffegs
21:38 	
25:47 	
28:38 	
29:22 	
32:37 	
fit „ Ffegs
29:57 	
29:15 	
*.*rv "ffegs ,
21:24 	
29:44 	
                     Data Reviewer
                                                             09/22/97
                                        Page 2 of 2
                                                                          X237.PSR vZOO, LARS 6 10.04
Triangle Laboratories, Inc.®
801 Captola Drive » Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                      Printed: 01:16 09/22/97
                                                                        40

-------
                        Initial
                                  	Bat*...
 Data Review By:
                                              Calculated Noise Area:
 The Total Area Cor each peak with an ion abundance ratio outside
 ratio limits has teen recalculated according to mathod requirements.
 Page Ha,

 09/22/97
Listing of T»76373B,iSs£
Matched GC Peaks / Ratio / Ret. Time
 H_Z..., QC.tog Omit Why  ..RT. OK Ratio Total. Area...  Area.Peak. 1..  Area.Peak.2.. Rel.RT Conpound.Hame..  ID.. Flags.
TCDF
364-306
0

304-306
13C12-TCDF
316-318




316-318
TCDD
320-322

D








320-322
37C1-TCDD
32S













DC
d
DC


DC
DC





DC
DC
a
DC
DC
DC
DC
DC
DC
DC
DC


EH
EN
SH
0

to.
KL



3

SH
SH
SH
SH
SH
SH
SN
SH
SH
SH
WH
0

18:25
20:51
21:38
Peaks

17:27
19:41
20:08
20:22
20:49
Peaks

18:41
18:59
19:47
20:21
20:28
21:27
21:36
21:54
22:11
22:20
22:50
Peaks
0.
RO
RO
RO

0.
RO
RO
RD
RO


0,
RO


RO
RO


RO
RO
RO
RO

.65-0.89
0
.56-
0.47
1

.93

0.53
1.13
o.so
0.00
.S5-O.89
1
6
1
3
0

.03
.15
.OS
.20
.77

,65-0.99
0
0
0
1
0
0
0
6
1
1
1

.44
.89
.73
.28
.91
,89
.66
.00
.21
.38
.08

O.S7
0.38
1.36 0.81
1.04 1.89
321,06 140. IS
323.46
TCDP / TCDD Follows -"•— —

0.09
0.68
1.37
0.57
0.60
O.S1
0.48
0.12
0.25
0.46
0.42
0.00
0.32S-1.097
0
1
1

.885
.002 2378-TCDF AN
.039

0.952-1.048
0
0
0.77 0
O.S9 0
180.90 1

.838
,946
.967
.378
.000 13C12-2378-TCDP ISO

0.861-1. 055
0
0
0
0
0
0
1
1
1
1
1

.855
.879
.»1S
.942
,948
.993
.000 2378-TCDD AM
.014
.027
.034
.057

0.907-1.093
DC
DC
DC
DC

DC

DC



DC
DC
ML
ML
HIi
WL

SN

SH



SM
SN
18:39
18:56
19:02
19:35
20:08
20:32
20:43
20:57
21:14
21:38
22:03
22:22
23:13







































0.19
0.58
0.37
0.32
0. 92 0.9}
O.OS
0,55 0.56
0.22
0.93 0.93
223. 7S 223.75
1.15 1.15
0.19
0.20
0
0
0
0
0
0
0
0
0
.863
.877
.881
.907
.932
.S51
.S5S
.870
,981
1.002 37C1-TCDD SUR1
1
.021
1.035
1.075
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North CaroBna 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 01:1609/22/97

-------
rPage NCT.
 O9/22/97
Listing of T9?S3?3B-dbf
Matched GC Peaks I Ratio / Set.. Time
 M_Z,,.. QC.Log Omic Why .,RT. OK Rmcia focal .Area...  te»a.teak.l., Ar«m.?eak.2..  Eel.Sf Compound.Nane,. ID.. Flags.


 32B                  § Peaks                227.31
13C12-TCOO
332-334












332-334
PeCDF
340-342 D




D





340-342
13C12-PSCBF
352-3B4










3S2-354
PeCDD
356-358

DC MIi 0:00
DC ML 19:13
DC ML 19:21
20:19
21:02
21:24
21:36
21:36
22:06
22:22
22:37
22:49
22:54
10 Peaks

d SH 24:36
DC SH 24:42
DC SH 24:55
DC SN 25:00
DC SN 25:23
d SH 25:27
DC SH 25:48
DC SH 26:07
DC SH 26:36
DC WH 27:02
DC WH 27:11
0 Peaks

24:09
24:40
25:02
25:12
25:21
DC SH 25i27
25:47
26:03
DC SH 26:11
DC SH 26:16
26:45
§ Peaks

DC SN 24:59
0.
RO
RO
RO
RO
RO


RO

RO
RO
RO
RO

1.

RO
RO

RO
RO
RO
RO
RO
RO
RO

1,
RO
RO

RO

RO

RO
RO
RO


1.

65-0.89
2
2
2
1
0
0
0
1
0
2
0
1
5

.43
.89
.84
.07
.62
.83
.76
.08
.77
.04
.36
.28
.30

1.42
0.99
1.63
2.35
3.65
515.28
260.41
8.69
3.85
0.92
2.09
3.38
1.19
801.81
,32-1.78
1
0
1
1
0
1
0
0
0
2
0

,33
1
1
1
2
1
2
1
0
2
0
1

.69
.96
.27
.51
.27
.21
.63
.5]
.54
.64
.43

-1.78
.11
.05
.60
.62
.13
.43
.55
.72
.55
.23
.58
»!__„_.
32-1.78
1
.47
1.29
0.3S
0.23
0.88
0,72
1.04
0.49
0.13
0.25
0.3S
0.11
0.00

2.42
1.48
257.92
1.7«
2.96
0.58
274. 6S
1.15
0.56
0.35
1.34
543.69
PftCBP /
0.79



1
1
234
112
5
1
1
0
2
3



.42
.59
.22
.40
.30
.67
.OS
.91
.45
.55



1.
2.
281.
143
4.
2.
0.
2.
1
0
0.



,33
.56
.06
.01
.SI
.18
.52
.55
.91
.67
907-1.093
0.000
0.890
0.896
0.941
0.974
0.991 13C12-1234-TCDO
1,000 13C12-2378-TCDD
1.015
1.023
1.035
1.047
1.056
1.060






RSI
iai





















1
0
153
1
1

166
0


O













.47
.90
.82
.11
.79

.84
.70


.82













1
0
99
0.
1.

107,
0,


0.












0.
.32
.86
.10
.69
.17

.82
.97


0.52
909-1.075
0.983
0.987
0.995
0.999 12378-SeCOF
1.014
1.017
1.031 23478-PeCDP
1.043
1.063
1.010
1.086

840-1.160
0.965
0.985
1.000 13C12 -PeCDF 123
1.007
1.013
1.017
1.030 !3C12-PeCBF 234
1.041
1.046
1.049
1.0S9




Ml


m








152



SDH2









0.

922-1.025
0.9SS


Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 01:16 09/22/97

-------
 Page no.
 09/22/97
Listing  of T97S373B.dbf
Hatched  GC Peaks /  Ratio /  Ret. Time
 Compound/
 H_Z.... QC.Log Omit Why  . .RT. OK Ratio Total. Area...  Area. Peak. 1.. Area. Peak. 2. . Rel.RT Compound. Name. .  ID.. Flags.






356-358
13C12-P6CDD
368-370





368-370
HxCDF
374-376






D
D



D


374-376
13C12-HXCDF
384-386











384-386
DC
DC
DC
DC
DC
DC


DC
DC


DC
DC


DC
DC
DC
DC
DC
DC
IX
d
d
DC
DC
DC
d
DC
DC


DC


DC
DC

DC
DC
DC

DC
DC

SN
SN
SN
SN
WH
MH
0

SN
SN


SN
SN
2

SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
WH
0

SN


SN
SN

EN
SN
SN

SN
SN
4
25:35
25:50
26:27
26:40
26:50
27:09
Peaks

25:01
25:11
26:09
26:17
26:30
26:48
Peaks

27:35
27:40
27:51
28:05
28:35
28:39
28:49
29:09
29:15
29:28
29:32
29:45
29:51
30:07
30:33
Peaks

28:28
28:38
28:44
28:58
29:01
29:15
29:29
29:33
29:51
29:57
30:10
30:22
Peaks
RO
RO
RO
RO
RO
RO

1
RO
RO


RO
RO

1.
RO
RO
RO
RO
RO
RO

RO
RO
RO
RO
RO
RO
RO
RO

0.
RO


RO
RO

RO
RO
RO

RO
RO

2
0
4
0
1
0

.14
.42
.75
.88
.13
.86

0.74
0
0
0
0
0
0
.16
.20
.36
.30
.39
.00
.32-1.78
0
0
1
1
0
4

.23
.72
.44
.78
.95
.25

.05-1.43
3
5
0
3
6
0
1
0
1
1
0
0
0
5
4

.38
.00
.18
.42
.92
.94
.27
.92
.04
.64
.60
.26
.64
.44
.33

0
0
163
14
0
0
.13
.21
.78 96.67
.49 9.27
.33
.10
0
0
1
1
1
1

.978
.988
.011
.020
.026
.038








0.847-1.153
0
0
67.11 1
5.22 1
1
1
.957
.963
.000 13C12-PSCDD 123
.005
.013
.025


IS3



178.27

0
0
0
0
0
0
0
1
1
0
0
0
1
0
.18
.07
.20
.27
.54
.79
.84
.72
.07
.31
.11
.18
.07
.20
0.07
0
.00
43-0.59
0
0
0
0
0
0
0
0
0
0
.65
.50
.49
.21
.13
.50
.79
.18
.40
.49
0.11
1

.48
1
0
261
291
.77
.08 87.48
.08 95.27
0.74
0
272
0
0
0
193
0
0
,018
.27
.92 91.41
.71
.74
.86
.89 64.18
.36
.32
.97
0.956-1.050
0
0
0
0
0
0
1
1
1
1
1
1
1
1
1

.960
.963
.969
.977
.995
.997 123478-HxCDP
.003
.015
.018 234678-HxCDF
.026
.028
.035
.039
.048
.063






AN


XX







0.861-1.139
0
173.60 0
195.81 1
1
1
181.51 1
1
1
1
129.71 1
1
1

.991
.997 13C12-HXCDF 478
.000 13C12-HXCDF 678
.008
.010
.018 13C12-HXCDF 234
.026
.028
.039
.042 13C12-HXCDF 789
.050
.057


SDR3
IS4


ALT2



ALT1



Triangle Laboratories, Inc.®  Analytical Services Division
801 Capctola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 01:16 09/22/97
                                                                   43

-------
_Page No.
 09/22/97
lasting  of T976373B.db£
Hatched  GC Peaks / Ratio / ReC.  Time
 M_Z.... QC«Lo«| Omit why ..RT.  OK Ratio Total .Ax«a...  Area.Peak.1.. Area * Peak. 2, . Rel.RT Compound. N«m«, -  ID..
HxCEE
390-392






D
D


390-392
13C12-HXCDB
402-404











402-404
HpCDF
408-410
D




40S-410
13C12-HpCDP
418-420





418-420

DC
DC
DC
DC
DC
DC
DC
d
d
DC
DC


DC
DC
DC
DC

DC
DC







DC
d
DC
DC
DC
DC




DC
DC

DC


EN
SH
SN
SN
.SN
an
SH
SH
SH
WH
WH
0

WL
VL
ss
ss

ss
SN





6

HL
SN
SN
SN
SH
SN
0



SN
SN

SH
3

28:02
28:10
28:23
28:28
28:37
28:52
29:06
29:15
29:21
30:03
30:13
Peaks

28:01
28:12
28:27
28:53
23:53
29:00
29:10
29:23
29:27
29:44
29:56
30:04
Peaks

31:12
31:18
31:26
31:37
32:13
32:38
Peafcs

31:25
31:34
31:41
32:00
32:37
32:59
Vtsaka
1.
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO


1.
RO
RO
RO
80
RO
RO
RO



RO
RO

0.
RO
SO
RO
BO
RO
RO

0.

RO
RO
RO

HO

OS-1.43
0.
0.
0.
0,
1.
0.
0.
1.
0.
0.
1.

30
70
79
69
88
31
95
58
47
72
06

o.os
0.13
0.20
0.16
0.36
0.27
0.72
1.16
0.87
0.33
0.33
0.00
05-1.43
0.
1.
0.
1.
0.
1.
2.
1,
1.
1.
0.
0,

84
76
38
86
75
53
13
23
23
25
71
S3

,88-1.20
4.
I.
0.
2,
O.
0.

IB
70
32
50
SB
10

0.29
0.94
0.25
0.63
O.S6 0.53
0.85
0.54
197.90 109.03
232.33 128.31
387.98 215.86
3.03 1.68
0.94 0.52
823.14

0.22
1.10
0.22
0.45
0.27
0.22
0.00
.37-0, SI
0.
1.
0.
0.
0.
1,

41
OS
21
94
43
85

114. SO 47.94
1.61 1.19
O.SS
0.46
113.01 34.13
0.49
279.22
O.S51-1.014
0.952
0.95S
0.964
a, 967
0.972
0.980
0.938
0.993
0,997 123478-HxCDD
1.020
1.026

0.9S6-1.034
0.951
0.958
0,966
O.9S1
0.71 0.981
0.985
0.99O
88,87 0.997 13C12-HXCDD 47S
104.02 1.000 13C12-HXCDD 673
172.12 1.01O 13C12-HXCC0 789
2.36 1.016
0.82 1.021

0.994-1.042
0.993
0.996
1.001 1234678-HpCDF
1.006
1.025
1,039 1234789-HpCDF

0.836-1,127
116.66 l.OOO l3C13-HpCBF 67S
1.12 1,005
1.008
1.019
78.88 1.038 13C12-HpCD? 789
1.05O










AS











SOR4
IS5
RS2






Ml


AD


IS6



SUSS


Triangle Laboratories, Inc.® Analytical Services Division
801 Capitate Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                       : 01:16 09/22/97

-------
  Pace Ho,
  09 22/97
         Listing of T97S373B.dbf
         Matched GC Peaks / Ratio /  Ret. time
  Compound/
  H_2—,  QC.Log Omit Why  , ,RT. OK  Ratio Total.ACM... MM. Peak. 1..  Area.?eak,2.. Kel.M Compound. Name.. ID.. Hags.
                                       Above: HpCUF / KpCDD Follows
  BpC30
  424-426
               0.18-1.20
DC  SH  31:29     0.89
DC  SH  31:46 HO  1.71
DC  WH  32:39 SO  1,76  ,
      0 Peaks
                                                 0,36
                                                 0.14
                                                 0.43
                                                 O.OO
             0,976-1.005
                 0.976
                 J.935
                 1.012
  13C12-HpCBD
  435-433
  436-438
  OCDP
  442-444

DC
DC
DC



DC
OC
DC
DC
DC
DC

DC


38
SH
ss

I

ss
SN
SH
SB
SN
SS

SS
I

31:31
31:41
32:08
32:15
Peak

31:48
12:34
33:34
34:04
34:09
34:19
14:48
35:38
Peak
0

RO
EO


0.
RO
to
RO
RO
RO

RO
RO

,18-1.20
1.14
4.13
0.75
0,98

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0.34
2.38
O.S4
0.17
0.30
0.80
1.16
0.50

                                                 0.15
                                                 0.16
                                                 0.29
                                               178.75
                                               178.75
                                            88.36
             0.969-1.031
                 0.977
                 0.982
                 a. 996
          90.39  1.000 13C12-HpCDD 678 IS7
                                       Above: HpCDD / Octa-CDD and CDF Follows
                                                 0.21
                                                 0.45
                                                 0.30
                                                 0.23
                                                 0.21
                                                 0.27
                                                 1.97          1.21
                                                 0.06
                                                 1.97
                                                             o.aas-i.iis
                                                                 0.915
                                                                 D.937
                                                                 0.966
                                                                 0.980
                                                                 0.983
                                                                 0.988
                                                            .04  1.001
                                                                 1.02S
  13C12-OCDD                     O.76-1.02
  470-472                 34s45     O.S2        257.37
                 DC  WH  34:55 RO  1.39          3.86
                 DC  WH  35:12 RO  1.39          0.33
  470-472               I Peak                  257.37
                                                             0.995-1.004
                                           123.10        134.27  1.000 13C12-OCDB
                                                                 1.005
                                                                 1.013
 Column Description............  "Why" coda Description	  QC Log Desc.
 M_Z   -nominal Ion Mass(*s|
 ..RT. -Retention Time (inn:33)
 Rac.l -Ratio of H/H+2 Ions
 OK    -RO=Ratio Outside Limits
 Rel. RT-Ralative Retention Time
 *»* Bod of Report •»•
                        Retention Tinie Window
                WH-Abovo Rotention Ti-ino Window
                SK-Belovr Signal to Noise Level
                
-------
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419.8220 T:4  SSUB(356, 30,-3.0) IXD(7,5,3,0.051,0.0,1.001, f,T)  XxpiEPCUS
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-------
riJ.eiT97S373 #1-390 Acq:ia-SEP-1997 18:29:26 Eli- Voltage SIS 70T
423.7766 Fl4 BSOBf 256,30, -3.0) PKJ)(7,5,3,0.t>5\,0.0,1.00*,T,T) ExplEPCUS
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425.7737 f:4 BSOB(256,30, -3.0) PlO>(7,5,3,0.05*,0.0,1.0t>1>,P,T) Exp:EPCUS
TRIANGLE LASS Text : TLI »4 3 22 9 TLI BLANK
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435.8169 T:4 BSOB(256r 30, -3.0) PKD(7,5,3,O.05lr28.0,1.00l,r,X) ExplEPCUS
TRIANGLE LASS Text: TLI #43229 TLI BLANK
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-------
file:T97S373  1U-3SO AcqtlB-SEP-1997 !St3St26 EH- Voltage SIX 70T
441.7428 r:4  BSOB(25Sr 30, -3.0} PSD I 7, 5, 3,0.051, 0.0, 1.00%, ffrf SzpiEPCOS
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430,9723  F!4 SxptStOtS
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XSIAHGLS LABS  X
-------
         34:36         34:42         34:48         34:54         35:00
flle:T97S373  91-390 Aoq:lB-SEP-lS97  18,29:26 EH- Voltage SIX 70T
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-------

-------
r ^S'Uf:
• TLI Project:
Client Sample:
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
%vw&i$t&&
43229
FB1-23
L°^&J,$^'&%&%8&Zt&j&&^
:,^yi|^^f^p|^B^i<:
Method 23
S414.003/WAUPACA Foundry
M23TRAIN Date Received: 09/12/97
183-1-1A-C Date Extracted: 09/14/97
Date Analyzed: 09/18/97
1.000
n/a
DB-5
Dilution Factor: n/a
Blank File: T976373
Analyst: KAS
^Hf^l^SiM^
PCDD/PCDF Analysis (a)
Analysis File: T976374
Spike File: SPX23704
ICal: TF53286
ConCal: T976372
% Moisture: n/a
% Lipid: n/a
% Solids: n/a

•£MfytM»^ V
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
-.r ;>, ^,;,-~,-;Anrt'.:(Hj
ND
ND
ND
ND
ND
ND
FJV1PC
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
r •• ''
?)'"- , vx ";x;¥^ ~" "> >',KmWC, , ;,-f
0.02
0.04
0.04
0.04
0.03
0.04
0.02
0.02
0.03
0.03
0.02
0.02
0.02
0.03
0.02
0.04
0.04
^ •" •" '
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- —
f<*teXv'; ^X'; <>;r\C:;^:^:-'^ber,ta,''^MP!S;^; - V^' -— , r^;v/>''J9iwi x
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
ND
ND
ND
ND
ND
ND
ND
ND
0.02
0.04
0.04
0.04
0.02
0.03
0.02
0.03
	
                                                 Page 1 of2
                                                                                           X237 J>SR V2 00. LARS «.IO.M
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 01:17 09/22/97

  5S

-------
TLI Project:
Client Sample:
43229
FB1-23
      Method 23 PCDD/PCDF Analysis (a)
                     Analysis File:   T976374

13CIS-2,3J,8-TCDF
>sC,r2,3,7,8-TCDD
13C«-U3,7,8-PeCDF
"Gu-l,23,7,8-PeCDD
l3Cla-l,23,6,7,8-HxO3F
»Ca-l,23,6,7,8-HxCDD
13Ci2-l,2,3A6,7,8-HpCDF
13C,rl,2,3,4,6>7,8-HpCDD
»Cu-U.3,4,6J,8,9-OCDD
             2.0
             2.0
             1.6
             1.8
             2.8
             2.7
             2.7
             3.2
             6.6
 51.0
 51.0
 40.5
 45.1
 71.2
 68.0
 66.7
 81.0
 82.4
40%-130%
40%-130%
4Q%-130%
40%-130%
40*-130%
4Q%-130%
25%-130%
25%-130%
25%-130%
0.74
0.84
1.54
1.49
0.52
1.22
0.43
1.01
0.86
20:47
21:34
25:01
26:08
28:43
29:26
31:24
32:15
34:44
"Cl.-2,3,7,8-TCDD
13Ci2-2,3,4,7,8-PeCDF
"Ci2-l,2,3>4,7,8-HxCDF
l3Cia-l,23,4,7,8-HxO5D
'3Ci2-l,2,3,4,7,8,9-HpCDF
             4.0
             4.2
             3.9
             4.4
             4.3
101
106
 96.4
111
108
70%-140%
70%-140%
70%-140%
70%-14Q%
70%-140%
1.45
0^1
1.18
0.43
21:36
25:46
28:37
29:21
32:36
»Ci2-l,23,7,8,9-HxCDF
13C,2-2,3,4,6,7,8-HxCDF
             2.8
             2.8
 70.2
 69.5
40%-130%
40%-130%
OJO
0.49
29:56
29:14
»Ci2-lA3,4-TCDD
»C,j-l,2,3,7,8,9-HxCDD
                                                       OJO
                                                       1.20
                                   21:22
                                   29:43
                         Data Reviewer..
                                                 09/22/97
                                               Page 2 of2
                                                                                       X237_PSR YlOO. LAKS 6.10 CJ
Triangle Laboratories, Inc.s
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                             Printegfl)):1709/22/i7

-------
  D&ta Revi«r By:
                                                   culatcd Noise Area:
 The Total Area for each peafc with an ion abundance ratio outside
 ratio limits has been recalculated according to nctbod requirements.
 rage Mo,
 09/22/91
         Listing of T976374B.dbt
         Hatched OC Peaks / Ratto I  Set. Time
 Compound/
 HJS.... QC.log Omit Why ..ST. OK Ratio Total.Area...  Area.Peak.1., Area.Ps«k.2..  Rei.RT Conpouad.XUM.. ID,. Fla
 TCDF
 304-30S
               0.65-0.89
DC  SH  18:10 RO  O.S1
DC  SH  18:33 RO  5.12
DC  SN  19:37 RO  0.50
d   SH  20:49 RO  0.49
      0 Peaks
                                                 0,25
                                                 0.30
                                                 0.71
                                                 2.18
                                                 0,00
                                                             0.826-1.097
                                                                 0.374
                                                                 0.893
                                                                 0.944
                                                                 1.002  2378-TCDF
  13C12-TCDF
  316-318
  316-318
                                0.65-0.89
DC
DC
DC



WL
ML
WL


2
17s 21
18:29
19:39
20 1 47
21:16
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0
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.85
.64
.67
.70
.76
.46
                                                            216.01
                                                              1.65
                                                             0.952-1.048
                                                                 0.835
                                                                 0.889
                                                                 0.945
                                                         290.69  1.000 13C12-2378-TCDF ISO
                                                           2.10  1.023
                                        Above:  TCDF /  TCDD Follows
 TCDD
 320-322
 320-322
DC  SH
DC  SH
DC  WH
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       0.65-0.89
19:55 HO  3.55
21:56 RO  0.10
22:51 RO
22:58 KO
Peaks
0.20
0.23
                                                 0.19
                                                 O.OS
                                                 0,09
                                                 0.13
                                                 0.00
                                                             0.861-1.056
                                                                 0.923
                                                                 1,017
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  37C1-TCDD
  328
 328
 13C12-TCDD
 332-334
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WL
WL
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18:41
19:10
20:07
20:21
21:36
21:56
22:34
22: a5
22:57
23:12
Peaks
O.S5-0.89
0:dO RO 3.97
18:45 RO 1.71
19:01 RO 1.63
19:25 RO 0.41
20:37 RO 1.06
                                                 0.52
                                                 0.44
                                                 0.31
                                                 4.43
                                                 0.13
                                               395.01
                                                 0.92
                                                 0.44
                                                 0.19
                                                 o.so
                                                 0.82
                                               402.59
                                                 1.13
                                                 2.46
                                                 2.18
                                                 1.56
                                                 2.19
                                             0.11
                                             4.43
                                           395.01
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                                                                 0.913
                                                                 0.933
                                                                 0.944
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                                                                 1.017
                                                                 1.046
                                                                 1.055
                                                                 1.064
                                                                 1.076
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                                                                0.000
                                                                0.869
                                                                S.332
                                                                0.900
                                                              4  0.956
                                                                                      SOR1
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                              Printed: 01:17 09/22/97
                                                                                       60

-------
 Page No.
 59/22/97
Listing of T976374B.db£
Matched 
-------
 Page" No.
 09/22/97
Listing  of T976374B.db£
Hatched  GC Peaks / Ratio / Ret.  Time
 Coispound/                                     ,
 8LS-..- QC.Log Omit Hby , ,RT. OK Eatlo Total. Area.,.  Area^Paaie.l. , Ar8a.Feak.2, ,  B»1.RV Gonpaimd.HajBSi..  IB.. Flags.















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27:47
27:49
27:59
28:09
28:15
28:34
28:40
28:54
29:09
29:15
28:43
29:52
29:56
30:25
30:32
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28:37
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28:27
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Triangle Laboratories, Inc.®  Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 01:17 09/22/97
                                                                          62

-------
 Page No.
 09/22/91
Listing ot T976374B.db£
Matched OC teaks /  Ratio / Ree. Time
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Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 * Fax: (919) 544-5491
                                                                              ? 09/22/97

-------
  Paga Ho.     5           tistitjg at T976374B,dbf
  09/22/97                 Hatched GC Veaks /  Ratio / Ret. Time
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  Rat.l  -Ratio of M/H+2  Ions      SN-Below signal Co No is a Level   0-Peak Deleted
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-------
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Fil'«st97S374 H-S93 Acq,lS-^EF-Tf37 lBtli:t7 EH- voltage SIM 70X
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                              25l00                         26:00
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369.8919  Fl2 BSOB(256,30,-3.0) PJO>( 7,5,3, 0. OS*, 0.0,1. aO*,?,X) SxpsEVCUS
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F±le:X976374  #1-435 Acq:18-SEP-1997 19:18:47 EI+ Voltage SIX 70T
373.8208 F:3  BSUS(256, 30, -3. 0) P1CD(7, 5,3,0.051, 0.0,1. 00*,F,T) Exp:EPCUS
TRIANGLE LABS  Tt*xt:YLI#43229 FBl-23                        IW. TIME -   19:20
1001                                                     Al. 8E4

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                 A3.18E3
           A3. 65E3
                                       A6.B3E3
                          A1L.12B3
            27:48  28:00 28:12 28:24  28:36 28:48 29:00 29:12 29:24  29:36 29:48 30:00 30:12  30:24
FiletT97S374  fl-435 Acq: 18-SBP-1997 19:18:47 EI+ Voltage SIS 70T
375.8178 r:3  BSUB(256, 30,-3.0)  PKD( 7,5, 3, 0.05%, 0. 0,1.00\,T,T)  ExpsEPCUS
TSIASGLE LABS  Tert:TLIf43229 fBl-23                        IKT. TOO! -   19:20
100*                                A3.59E3         A1.28E3
                                                                                                       OEO
                                                                                                        Time
                                                                                                       8E3
      27:36 27:48  28:00 28:12 28,24  38,36 28:48 29:00 29:12 29:24  39:36  29:48 30:00 30:12  30:24
rile:TS76374  11-435 Acq: 18-SEP-1SS7 19:18:47 EI+ Voltage SIS 70T Hoiaeil
383.8639 F:3  BSUB(256,30,-3.0)  PKD(7,5,3,0.05%,4.0,1.00\,T,X)  Sxp:EPCDS
TKIBXGLE LABS  Text:XLIf4322S 131-23                        HKT. TIME -   19,20
                                        A1.?9E6
                                                        A1.41E6
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                                                                              A1.18E6
      27:36 27:48  28:00 38:12 28:24  28:36 28:48 29:00  29:12  29:24  29:36 29:48 30:00 30:12  30:24
File,T976374  tl-435 Acq.-18-SEP-lS97 19:18:47 EH- Voltage SIS 70T SoiaetSS
385.8610 P,3  BSVB(256,30,-3.0)  PXD(7,5,3,0.05\,260.0,1.00\,r,T) Exp:EPCUS
XBIXXGLE LABS  Text:TLH 43229 fBl-23                        HKT. HUE -   19:20
100*
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                                                                              A2.35ES
      27:36 27:48  28:00 28:12 28:24  28:3S 28:48 29:00 29:12 29:24  29:36  29:43 30:00 30:12  30:24
rlletT976374 tl-435 AcqslS-SEP-1997 19:18:47 Eli- Voltage SIS 70T
392.9760 1:3 ExptEPCOS
TBI&NGLE LABS  Text:TLI#43229 FBl-23                        UKT.  TIME =   19:20
10°\»13* 27:44    *••"      %£**••»*•,»
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File:T976374 tl-435 Acq:18-SEP-1997 19:18:47 EH- Voltage SIS 701
445.7555 T:3 Exp:EPCUS
TSIANGLE LABS  Xcoct:TLI#4322a FBl-23                        UKT.  TIHE '   19:20
100*27:33                                  2*-'*5
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                                                                                                        Time
                                                                                                69

-------
"FS.'lS:3!l7S374  il-435 acg:lfl=IB-lSS7 19:18:47 EI+  voltage SlM  701
389.8156 J-.-J  *SVa(2S6,30,-3,0) ta>(7,5r3,O.OS
-------
WileiT976374 #1-390 HcqilB-SSP-1997 19il8s47 EI+
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XRXMNKLX LABS TextiTLTf43229 FS1-23
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TRIANGLE SABS Text:TLIf 43229 FB1-23
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100&
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UKT. TIME - 15:50




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' 32jl2 ' ' ' 33i24 ' ' ' 32i3~S " ' ' 32i4t ' ' *J3«CO'
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ISJ. HHf ' 19:20



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1 A
1 A
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HKT, mm - 19 -.20

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_riJ.esT976374 tl-390 Xcfs18-8EP-l997 19tlB:4J EH- Yol.ta.ge SIS'"79T
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 TXIANGLE LASS  TextlTLI#43229 FBI-23                         I1IJ.  TIME -   !Ss2tt
                                                                                                  -4.9X3
   31:30   31l3S  31:42   31:48  31:54  32:00  32': OS  32': 13  32il8  33:24
ril»:T97S374 H-39O Acq:18-SEP-1997 19:13,47 EH- Voltage SIS 70TJfaiee:3
43S.81S9  F:4 BSOS(256,33f-3.0)  MOtf7,$,3,0.05\,12.tt,1.00%,W,T) BJtp.-SPCDS
TBJANGLE  LAJ3S  Tf-xt:TLI#43229 PS 1-23                        OET. TIME  "
1003,                                                     U.fSES
  eo:

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  40.

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   31-30   31:36  31:42  31:48  31,54   32,00   32:08  32:12  32:13   32:24  32:30  32:36  32:42
 tU.ttsT976374 #1-390 Acqtia-SEf-lSS7 19tl8st7 SIf- Voltage SIS  70T
 42S.7737 F:1 »SO3(2SS,3Ot-3.0)  ?XB(7,5,3,0.05%,0.0fl.OO%,rfT) XxptBfCOa
 ZSIWSSZX L&BS  PCXtlZEI*«2JS rtl-23                        HW. TIMS •   13*30
 100*                                                               ,                              -3.3E3
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   31l30  31i36  31i4S  31s48   31iS4  32:00  32:OS   32tl2  32slB
M.le!fSfS374  fl-390 McyilS-aEP-1997  19il»:47 SI+ Voltag* SIS 70S
437.8140 F:4  BSOB(25S,30r-3.0} flO>(7,S,3,O.OS^,0.0,1.00%,FrI) Bcp
TSIAKSLE LHS9  TextiTLI»43229 FBI-23                        TH.T. TIME
100S                                                     Al.fBES
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                                                                     32:24   32:30   32:36  32:42
19:20
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   31:30  31,36   31:42  31:48  31:54   32:00  32:06  32:12   32:IB  32:24  32=30  33,36   32:42
MJ.esT97S374 tl-390 AcIt43229 TBl-23                         IKT.  TIME =•   19t20
                                                                                                  .O.OSO
                                                                                                     Time
1001

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                                                                                               72

-------
T±lesT97S374  tl-390 Acq: ia-SEP-1397 13:18:47 EI+ Voltage SIS TOT
141.7128 F:4  BSUB(256,30,-3.0) PSD(7,S,3,0 .05\,O.Or1.00%,,F,T) EzpsEPCVS
TRIANGLE LASS  Tezt:TLIf 43229 FBl-23                         UKT. TIME -
1003
 901
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 701
 sol
 sol
 401
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  A3.69E3       A3.06S3
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                                                                           AS.27E3
                    32:00               33:00           'J<:00
rils:T97S374  H-390 Aaj:lB-SEP-1997 19:18:47 EI+ Voltage SIS 70T
443.7399 F:4  BSO3(256,30,-3.0) PED(7,5,3,0.051,0.0,1. 00*,F,T) ElpiEPCUS
TRIANGLE LABS  Text:TLI»43229 FBl-23                         I1KT. TIMS -
1003,
  so
  70\
  ffflj
  sol
  40\
  JOJ
  201
  101
   0.
                                                                        35:00
                                                          A6.30E3
                                        33tOO
riletT976374  tl-390 Acqsia-SEP-1997 19ilSs47 EI+ Voltage SIS 701
430.9729 F:4  ExplEPCUS
TBIAHGLS LABS  TaxtsTLH43229 FBl-23                         UKT. TIKE -
                                                                                35:00
                                                                                              .2.6E4
                                                                                              '•-2.4E4
                                                                                              •-2.1E4
                                                                                              .1. SE4
                                                                                              11.5E4
                                                                                              11.2E4
                                                                                              :B.BE3
                                                                                              15.3E3
                                                                                              12.9E3
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                                                                                                  T±mi
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                                                                                       '.B.SE3
                                                                                       '.6.4E3
                                                                                       '-.4.3E3
                                                                                       [2.1E3
                                                                                        .O.OEO
                                                                                           Time
                    32:00               33:00               34:00
fileiT97S374  tl-390 Acq:lB-SEP-1997 19tlfi47 EI+ Voltage SIS 70T
513.S775 F:4  ExpiEPCBS
TSIANSLE LABS  Teit:TLIf43229 FS1-23                         UKT. TIKE  -
                                                                                35:00
                                                                             19:20
lOOi
 901
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 701
 601
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 401
 301
 201
 101
  0.
 31:28
1
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                                                                              35:17
                                      33:20
                           32:44
                                            33:38
                                                     34:04
                                                            34:24
                                                      JUU
                                                                   4:44
                                                                           35:08
                    32:00
                                        33:00
                                                            34:00
                                                                                   35:34
                                                                                35:00
 4.5E3
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13.SE3
[3.2E3
12.7E3
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ll.4E3
•.9. OE2
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    Time
                                                                                                 73

-------
^
l-ile:l97S374 tl-390 Acq:lB-SEP-1997 19:18:47 BI+ Voltage SIS 79T
457.7377 F:4 BSUB(256,30,-3.0) rKD(7,5,3,0.051,0.0,l .001,r,T) Ezp:EPCOS
TRIANGLE LASS Teit:TLIt43229 TB1-23 IKT. TIME =
1001
80.
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40.
20.
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/\/\ 1 1 A5.00E3
x-j-««_ / V ^ A ^^ ^-^
34:36 34:42 34:48 34:54 35:00
r±le:T976374 tl-390 Acq: 18-SEf -1997 19:18:47 EH- Voltage SIS 701
459.7348 T:4 BSUB(256,30, -3.0) tXD(7,S,3,0.05\,0.0,1.00*,P,T) ExpiEPCUS
TRIANGLE LABS Xezt:TZIt43229 FBl-23 UKT. TIME *
1001

ao.
60.
40.
20.
0
A1.53E4
Al . 44S4 A
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34:36 ' ' 34:42 ' ' ' 34:48 34:54 ' 35:00
rila:T97S374 tl-390 Acq:18-SEf-1997 19:18:47 EH- Voltage SIS 70T
469.7779 r:4 BSUB(25f, 30, -3.0) PJO>( 7,5, 3,0.051,0.0,1 . 00\,r,T) Exp:EPCUS
TRIANGLE LABS Tert:TLIt432S9 fBl-23 INT. TIME -
1003
BO.
60.
40.
20.

A2.48ES
A
/ \
/ \
/ V
/ \- 	 ^
34:36 34:42 34:48 34:54 35:00
F±le:T97S374 tl-390 Acq: 18-SEf -1997 19:18:47 EI+ Voltage SIS 70T
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File:T976374 #1-390 Acq:18-SEP~1997
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-------

-------
TLI Project:      43229
Client Sample:    BO-23-1
                     Method 23 PCDD/PCDF Analysis (a)
                                  Analysis File:   T976375
Client Project:
Sample Matrix:
TLI ID:

Sample Size:
Dry Weight:
GC Column:
S414.003/WAUPACA Foundry
M23TRAIN Date Received:
183-1-2A-C Date Extracted:
Date Analyzed:
1.000 Dilution Factor:
n/a Blank File:
DB-5 Analyst-

09/12/97
09/14/97
09/18/97
n/a
T976373
KAS

Spike File:
ICal:
ConCal:
% Moisture
% lipid:
% Solids:


SPX23704
TF53286
T976372
: n/a
n/a
n/a





'&&?X^&>y*V%3Jli«$&3jjj$
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
l,Z3,4,6,7,S-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF

§§^M$^s*&3:$^iib?^^
0.23
0.44
EMPC
0.24
0.32
038
EMPC
15.5
3.1
3.9
2.9
1.5
0.93
0.10
0.97
0.17
EMPC
^Sp^;fei^|^;fe$x^g^:':^i



0.15



0.11









0.08

^0lft?:?:W:S:^^S;lw^;il
0.72
1.67

1.09
1.19
1.02

0.84
1,65
1.55
1J3
1J4
1.24
1.27
1.09
1.12

Iwiipi
S&!%*!M5K
21:35
26:08

29:27
29:44
32:15

20:49
25:01
25:46
28:37
28:43
29:14
29:57
31:24
32:36

ilpjiilpti
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Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD

Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
  7.0
  3.4
  2.8
  0.67

131
 57.6
 15.0
  1.6
11
 7
 6
 2

15
14
12
 4
 7.7
 6.3
 2,9
57.8
                                         Page 1 of2
                                                                            X237_PSR»tQ0,I-*HS«.!0.«
Triangle Laboratories, Inc. 9
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                 : 01;18C»22/97

-------
TLI Project:       43229
Client Sample:    BO-23-1
                      Method 23 PCDD/PCDF Analysis (a)
                                     Analysis File:   T976375
"C,2-2,3,7,8-TCDF
1JC,i-2,3,7,8-TCDD
"C,2-l,2,3,7,8-PeCDF
»Cw-l,23,7,8-PeCDD
IJCw-l,23,6,7,8-HxCDF
»C,rl,2(3,6J,8-HxCDD
iaC,z-l,2,3,4,6,7,8-HpCDF
'3C,2-l,2,3,4,6.7,8-HpCDD
13Ciz-l,23,4,6,7,8,9-OCDD
2.1
1.9
1.8
2.0
2.5
2.9
1.7
2.1
3.9
 52.4
 47.3
 44.9
 49.3
 62.3
 71.4
 43.0
 51.8
 48.2
40%-130%
40%-130%
40%-130%
40%-130%
4Q%-130%
40%-130%
25%-130%
25%-130%
25%-130%
0.73
0.87
1.49
1.50
0.49
1.18
0.41
1.05
0.80
20:46
21:34
25:01
26:08
28:43
29:26
31:24
32:15
34:43
"04-2,3,7,8-TCDD
!3C«-l,23,4,7,8-HxCDF
"CB-l,23,4,7,S-HxeDD
13Cl2-l,2,3,4,7,8,9-HpCDF
3.8
4.1
4.2
3.4
3.9
 95.5
102
104
 84.6
 96.7
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%
1.42
0.50
1.20
0.40
21:35
25:46
28:37
29:21
32:35
"C,rl,2,3»7,8,9-HxCDF
BCij-2,3,4,6,7,8-HxCDF
2.5
2.7
 62.2
 66.3
40%-130%
40%-130%
0.50
OJO
29:56
29:13
13C,2-1,2,3,4-TCDD
13e12-l,2,3,7,8,9-HxCDD
                                          0.86
                                          1.22
                                    21:22
                                    29:43
                         Data Reviewer
                                               Page 2 of2
                                    09/22/97
                                                                                        XOIJSR "ZOO, IMS 6.10.M
Triangle Laboratories, Inc.®
801 CapHoIa Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                Print«rt A1:1 B 09/22/97
                                                     I a

-------
                         Initial,  	Data...
  Data Review By;
                                               Calculated Noise Aireas  n/a
  The Total Area for each peak with an Ion abundance ratio outside
  ratio limits has been recalculated according to method requirements.
  fag* So.
  09/22/97
Listing of T976375B.dbf
Matched GC Peaks  / Ratio / Eat.  Time
  Compound/
  H_Z.... QC.Log Omit Why  , .RT. OK Ratio Total,Area.,. Area. Peak. 1.,  area.Peak.2..  Rsl.RT Confound. Majae..  ID.,  Flags
TCCF
304-30S







M









304-306
13C12-TCDF
316-313

316-318
TCOD
320-322



H








320-322
0
DC NX, 0:00 RO
17:20-
17:50-
18:05-
18:29-
18:51
19:19-
19:38-
20:05-
20:19-
20:35
20:49-
21:15.
21:29-
21:45-
22:39"
DC KH 22:55 RO
DC HH 23:12 RO
15 Paaks
0,
DC ML 18:22 RO
20:46
1 Pea*
0.
18:44.
19:12.KO
19:32.
20:16,
20:35 .
21:00 -
21:22 »
21:29 •
21:35 •
21:46-
21:57-
22:10-
22:39 £0
13 Peaks
.65-0.89
0
0
0
0
.94
.83
.83
.84
0.84
0
0
0
0
0
0
0
0
0
0
0
0
1

.83
.82
.80
.84
.86
.79
.84
.83
.85
.87
.66
.63
.28

0
770
414
201
2,201
1,417
1,261
923
1.188
101
457
1,436
708
591
53
35
13
2
12,163
.87
.20
.47
.71
.78
.68
.69
.53
.00
.63
.32
.45
.59
.83
.52
.03
.17
.74
.43

348
187
91
1,001
642

.81
.85
.30
.90
.20
568.26
409.93
542.00
231.25
202.03
655 . 67
321.63
271.36
24.97
13.93







421
22S
109
1,199
775
693
513
646
270
25S
780
386
320
28
21



.65-0.89
22.07
0.73

K\
65-0.89
0.78
0.93
0.75
0.77
0.76
0.65
0.71
0.82
0.72
0.
0.
0.
84
89
71
0.64


0
340
340

123.
41.
28.
.27
.41
.41
5* / W
r / i\-
.75
.35
.61
114.56
66.20
27.24
SI. 52
£0.06
17.78
12.
28.
8.
6.
586.
23
61
65
00
56


143 . 93

196
0.826-1.097

.39
.62
.91
.88
,48
.43
.60
.00
.38
.29
.78
.91
.47
.55
.10



0
0
0
0
0
0
0
0
0
0
0
1
1
1
1
1
1
1

,000
.835
.859
.871
.890
.908
.930
.945
.967
.978
.991
.002 2378-TCDF RS
.023
.035
.047
.091
.104
.117

0.952-1.048

.43
0
1
.884
.000 13C12-2378-TCDF ISO


54.
21.
12.
49.
28.
1O.
21.
27.
7.
12
71
25
96
60
71
39
OS
47
5.60
13.
3.
47
58
2.61


69.
23,
0. 861 -1. 056
.S3
,36
16.36
64.
37.
16.
30.
32.
10.
6.
IS.
S.
4.

60
60
53
13
»7
31
63
14
07
07

0
0
.869
.890
O.SO6
0.940
0.954
0.974
0.991
0.996
1.001 2378-TCDD AN
1.009
1.018
1.028
1.050


Triangle Laboratories, Inc.® Analytical Services Division
801 Captela Drive • Durham, North Carolina 27713
Phone: (919) 544-5729« Fax: (919) 544-5491
                                                                            l :19 Oi/22/97

-------
 Page No.
 09/22/97
Listing of T976375B.dbf
Matched GC Peaks / Ratio / Ret.  Time
 compound/
 M_Z.... QC.Log Omit Why ..RT. OK Ratio Total .Area. ..  Area.Peak.1. . Area. Peak. 2..  Eel.RT Compound. Name..  ID.. Flags.
37C1-TCDD
328
328
13C12-TCDD
332-334





332-334
PeCDF
340-342









A
M





K



340-342
13C12-PeCDF
352-354


DC HL 19:03
DC ML 19:13
20:05
DC SN 20:19
DC SN 20:59
21:35
DC SN 21:56
22:02
DC SN 22:27
DC SN 22:55
3 Peaks
0.
DC NL 0:00 RO
21:22
21:34
DC SN 21:55 RO
DC SN 22:14 RO
DC SN 22:42 RO
2 Peaks
1.
DC SN 22:46 RO
22:55.
DC SH 23:02 RO
DC SH 23:12 RO
23:38. RO
23:58.
24:07.
24:17.
24:32.
24:44-
24:55.
25:01
25:11'
25:20.
25:46.
25:54,
26:14.
26:37 RO
26:45.
DC WH 26:57 RO
DC WH 27:08
16 Peaks
1.
DC SN 22:50
DC SN 24:40 RO
25:01
65-0.89
3
0
0
2
1
1

.12
.86
.87
.75
.73
.48

,32-1.78
0
1
0
3
2
1
1
1
1
1
1
1
1
1
1
1
1
1
1
0
1

.56
.52
.96
.21
.27
.57
.50 1
.49
.65
.52
.33
.65
.64
.62
.55.
.54
.69
.86
.39
.99
.48
4
8.
13.
582.
1.
0.
226.
0.
28.
1.
0.
836.
1.
502.
259.
4.
1.
3.
80
90
12
01
80
26
66
20
34
30
58
50
40
41
09
82
29
761.81

1.
549.
3.
5.
8.
346.
,472.
311.
99
63
42
05
19
12
33
30
151.94
332.
79.
233.
164.
199.
00
60
00
12
41
306.49
241.
18.
79
84
5.66
21.
2.
1.
,442.
64
14
19
06
582
226
28

232
120



.12
.26
.20

.61
.69





259
138



0.
0.

.79
.72



907-1.093
0.333
0.891
0.931
0.942
0.973
1.001 37C1-TCDD SUR1
1.017
1.022
1.041
1.063
907-1.093
0.
0.
1.
1.
1.
1.
000
991 13C12-1234-TTP P?1
000 13C12-237S-TCDD 1S1
016
031
053



331


7
211
883
186
94
200
45
145
101
123
186
146
11
4
12




.78


.28
.58
.58
.26
.57
.09
.40
.00
.89
.27
.14
.67
.83
.14
.59




217


3
134
588
125
57
131
34
38
62
0.

909-1.075
0.
.85 0.


.21
0.
0.
0.
.54 0.
.75
.04
.37
.91
.20
.00
.23
76.14
120
95
7
2
9



32-1.78
1
1
1
.36
.89
.49
1.
1.
278.
11
40
39


166


.52


111
.35
.12
.01
.22
.05



0.


.87
0.
0.
0.
0.
0.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.

910
916
921
927
945
958
964
971
981
989
996
000 12378-PeCDF AN
007
013
030 23478-PeCDF AH
035
049
064
069
077
085

840-1.160
0.
0.
1.
913
986
000 13C12-PeCDF 123 IS2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitals Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 01:19 09/22/97
                                                                      SO

-------
 Page So.
 OS/22/97
Listing of T976375B.dbf
Matched GC Peaks / Ratio  / Ret. Time
 Compound/
 M_Z....  Qc.t-og Omit Mhy ..ST. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2..  Rel.RT Compound. Name.. ID..  Flags.
 PeCDD
 3SS-358
 355-358
 13C12-PeCDD
 3i!-370
 368-370
 HXCIIP
 374-376
DC

DC
DC


SN 25:13
25:46
SN 26: 18
SM 27:03
2 Peaks

RO


RO

1.
24:16.RO












DC
DC
DC


DC


DC
DC





DC





DC
24:45
25:01
25:09
25:21
25:37
25:49
26:00
26:08
26:16
26:37
11 Peaks

SN 24:47
SB 25=30
SN 25:50
26:08
26:15
SN 26:59
2 Teaks

Mb 0:00
St) 27:29
27:38
27:46
27:56
28:05
28:14
SN 28:24
28:37
28:43
28:50
29:O1
29:14
SM 29:47

.
•
•HO


• RO
•
• ao
•

i.
RO
RO
BO


RO

1.



.

'
.

,
s



RO
29:57,
30:O1,
DC
DC
WH 30:11
WH 30:17
RO
RO
0.50
1.42
1.62
1.02

32-1.78
0.50
1.34
1.52
1.52
1.29
1.51
1.4$
0.69
1,67
1.80
1.33

32-1.78
0.32
1.27
1.00
1.50
1.36
0.60
i>Vttf»«
05-1.43
1.39
1,33
1.35
1.31
1.38
1.23
1.31
1.26
1.33
1.24
1.35
1.26
1.24
l.OO
1,27
1.12
0.20
0.88
1
290
1
0
.63
.01
.60
.76
563.40
INsCSP /

104
13
60
.63
.39
.64
25.78
36
34
18
6
24
14
10
3S1

0
1
.33
.70
.35
.78
.85
.66
.89
.00

.25
.17

170



.24



119



,77


1.011
1.030 13C12-PeCBF 234
1.051
1.081

SUR;




63
7
36
15
22
20
10
4
15
10
6




.60
.66
.54
.54
.08
.90
,86
.12
.54
.34
.21




127
5
24
10
17
13
7
5
9
5
4




0.
922-1.025

.72 0.929
,73
.10
.24
.16
,80
.49
,97
.31
.75
.68

0.


O.S4
179
2O
0
199
PaCD
i
0
111
450
48
63
22
1
231
147
31.
64
75
0,
7.
13,
O.
0.
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.90
.35
n /
U 1
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.91
.63
.66
.81
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.67
.58
.36
.62
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.61
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,76
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107
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71
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0.947
0.957
O.i62
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0.980
0.988
0.995
1.000 12378-PeCDD
1.005
1.018

847-1.153
0.948
0.976
0,989
1.000 13C12-PeCDD 123
1.004
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1.037
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Triangle Laboratories, inc.®  Analytical Services Division
801 Cap'rfola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 01:1 §09/22/97

                                                                       81

-------
Page No.
09/22/57
                       Listing of T976375B.dbf
                       Hatched GC Peaks / Ratio / Ret. Tine
Compound/
K_Z.... QC.Log Omit Why ..RT. OK Ratio Total .Area ---  Ar ea . Peak . 1 . .  Area. Peak.
                                                                           Rel.RT Compound. Name. .  ID.. Flags.
DC
DC
374-376
13C12-HXCDF
384-386 DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
384-386
HxCDD
390-392
DC
K



DC
DC
DC
DC
390-392
13C12-HXCDD
402-404 DC
DC
DC
DC



DC
DC
DC
WH
WH
12
ML
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
4
SN




WH
WH
WH
WH
7
30:22
30:30
Peaks
0:00
27:45
27:53
28:27
28:37
28:43
28:51
28:5B
29:08
29:13
29:23
29:32
29:56
30:08
30:15
30:23
30:28
Peaks
28:09
28:21
28:37
28:50
28:59
29:21.
29:27
29:44
29:54
30:01
30:09
30:15
Peaks
RO 0 . 60
1.12
0.43-0.59
0.48
RO 0.70
0.50
RO 0.27
0.50
0.49
RO 1 . 19
RO 0 . 09
RO 1.22
0.50
RO 0.63
RO 0.70
0.50
RO 0.69
RO 2.65
RO 1.51
RO 0.74
1.
RO
.
, RO


'RO
RO
RO
RO

05-1.43
1.15
1.62
1.32
1.32
1.21
0.99
1.09
1.19
0.67
O.S4
1.61
0.79

0.45 1.057
1.25 1.062
1,268.07
0.361-1.139
1.05 0.000
1.30 0.966
0.18 0.971
0.62 0.991
288.08 95.68 192.40 0.997 13C12-HXCDF 478
296.75 98.03 198.72 1.000 13C12-HXCDF 678
1.04 1.005
0.36 1.009
0.62 1.015
299.96 99.98 199.98 1.017 13C12-HXCDF 234
2.46 1.023
0.92 1.028
228.94 75.91 153.03 1.042 13C12-HXCDF 789
0.72 1.M9
0.39 1.053
0.62 1.058
0.98 1.061
1,113.73
SOR3
1 54
ALT2
ALT1
0.951-1.014
26.80 14.36 12.44 0.956
0.29 0.963
55.90 31.82 24.08 0.972
57.31 32.60 24.71 0.980
5
8
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22
0
0
0
0
192
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SN



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28:50
29:13
29:21
29:26
29:43
30:03
30:06
30:12
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RO

RO



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RO
0.43
0.38
1.09
0.96
1.20
1.18
1.22
0.64
0.35
0.59
0
0
2
0
202
265
394
2
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1
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.45
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.85
.83
.20
.74
.30
2.87 2.37 0.985
4.90 4.93 0.997 123478-HxCDD
8.28 7.62 1.001 123678-HXCDD
11.99 10.09 1.010 123789-HXCDD
1.016
1.020
1.024
1.028

0.966-1.034
0.000
0.955
0.980
0.993
110.15 92.05 0.997 13C12-HXCDD 478
143.98 121.87 1.000 13C12-HXCDD 678
217.20 177.63 1.010 13C12-HXCDD 789
1.021
1.023
1.026

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Triangle Laboratories, Inc.® Analytical Services Division
801 Captola Drive • Durham, North Carobia 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                        Printed: 01:19 09/22/97
                                                                                              82

-------
  Page Ho.
  09/22/97
Listing of T97S375B.db£
Maccbsd GC Peaks / Ratio / Ret. Time
 Compound/
 M_2..,. QC.Log Omic Why  . .El1- OK Ratio fatal -Area., -  Area. Peak. I.. Area,Peak.2. ,  Rel.ST Compound, Kaine., IB,, Flags.
  HpCDP
  403-410
  13C12-HpCDF
  418-420

  413-420
 HpCBD
 424-426

 424-426

 13C12-HpCB»
 436-438
 OCDF
 442-444
 OCDD
 458-450 X
 4S8-4SO

 13C12-OCDD
 470-472

















cc
DC

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31:24
31:37
31:44
32:36
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31:24
32:35
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31:40
32; IS
2 Peaks

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SH 32:02
32:15
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1 peak

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SS 32:52
SS 33:32
SB 34:25
3H 34:39
34:51
1 taak

34:43
1 Peak

34:43
WH 35:01
HH 35:13
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0.88-1.20
1.09
1.09
O.91
1.12

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0.41
0.40


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0.96
1.02

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RO 3.17
1.05
HO 1.61

0.76-1,02
RO 0.06
1O 0.47
0.84
0.77
RO 0.11
RO 1.18

0.76-1.02
RO 1.39

0.76-1.02
0.80
RO 1.47
RO 0 , 24

862.38

59.82
14.03
10.29
6.70
90.84

139.3!
106.35
245.70
Hwnir /
np^.ur /
10.72
14.52
2S.24

0.4S
0.12
1S7.S2
1.63
157,62
HpCDD f
o.os
0.30
0.81
0.23
0.08
2.59
2.59

3.18
3.18

228.98
1.23
0.25
228.98
HpCDP Follows — — 	 — -•— ——».«. — -.-.«.«,—— —
0.994-1.042
31.23 28.59 1.000 1234578-HpCDF
7.33 6.70 1.007
4.91 5.38 1.011
3.54 3.16 1,033 1234789-HpCDF

0.936-1.127
40.49 98,86 1,000 13C12-HpCDF 678
30.20 76.15 1.038 13C12-HJSCDP 789

HoCDD Follows —-""«-"""""•—"•-«-••——-•••«"«»-—-—-•
0.976-1.005
5.24 5.48 0.982
7.33 7.19 1.000 1234673-HpCBD

0.969-1.031
0.981
0.993
80. S» 77.03 1.000 13C12-HSCDD 678
1.007

0.885-1.115
0.935
0.947
0.966
0.991
0.998
1.62 1.37 1.004 OCDF

0.885-1.115
2.33 1.68 1.000 OCDD

0.995-1.004
101.50 127.48 1.000 13C12-OCB0
1.009
1.014



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Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                   Printed: 01:19 09/22/97
                                                                                                  83

-------
P age No,      6
09/22/97
                         Listing of T976375B.db£
                         Matcbad QC Peaks / Ratio / Bee. Time
 M_Z.... QC.Log Oinic Why ..RT. OK Ratio Total. Ar«a...  Area. Peak. 1..  Area. Peak. 2..  Rel.RT Compound. Maine..  ID.. Flags.
 Column Description.
                                     Code Description.........  QC Iiog Desc.
 M_2   -Nominal  Ion Mass (as)
 ..ST.  -Retention Tine  (muss)
 Sat.l  -Ratio of B/M+2  Ions
 OK    -RO=Kitio Outside limits
 Rel.RT-Relative Retention Time
     End of Report
                               HL-Below Retention Time window
                               WH-Abovs Retention Tine Window
                               SH-B@lDW signal  £Q Hoisa L^vel
                               
-------
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TRIANGLE LABS  Tgxt:TLI*43229 BO-23-1                       IKT. TIME
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-------
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-------
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-------
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-------
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File:T976375 11-435 Acq:18-SEP-1997 19:57:26 EI+ Voltage SIR 70T
445.7555 F:3 Exp:EPCUS
Sample Text:TLIt43229 BO-23-1                        INJ. TIME =
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File:T976375  #1-435  Acq:18-SEP-l997 19:57:26  El+  Voltage SIR 70T
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-------
File:T976375 #1-390 Acg:18-SEP-1997 19:57:26 EI+ Voltage SIR 70*
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-------
File:T976375 #1-390 Acq:18-SEP-l997 19:57:26 EI+ Voltage SIR 70T	~	
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471.7750 F:4 lxp:EPCUS
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-------
 TLI Project:      43229
 Client Sample:   BO-23-1
                          Method 23 TCDD/TCDF Analysis (DB-225)
                                               Analysis File;   P973984
 Client Project:    S414.003/WAUPACA Foundry
 Sample Matrix:   M23TRAIN        Date Received: 09/12/97
 TLI ID:          183-1-2A-C         Date Extracted: 09/14/97
                                    Date Analyzed: 09/19/97
                                                  Spike File:    SPC2NF04
                                                  ICal:         PF22206
                                                  ConCal:      P973982
 Sample Size:
 Dry Weight:
 GC Column:
1.000
n/a
DB-225
Dilution Factor:  n/a
Blank File:     T976373
Analyst:        ML
            % Moisture:   n/a
            % Lipid:      n/a
            % Solids:     n/a
2,3,7,8-TCDF
              3.5
                                 0.76
                      20:33
 "C,2-2,3,7,8-TCDF
              2.0
          48.9
40%-130%
0.76     20:31
13Ci2-l,23,4-TCDD
                                                   0.81
                                         19:34     	
                      Data Reviewer:
                                          Page 1 of 1
                                              09/22/97
                                                                             C2NFJSR fim, UUtS 0.1041
Triangle Laboratories, Inc.?
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                        Prirrtgd: 02:09 09/22/97

-------
 Data Review By:


 The  Total Area  for each peak with an  ion abundance  ratio outside
 ratio limits has been recalculated according to method requirements.
 Page  No.

 09/22/97
Listing of  P973934B.dbf
Matched GC  Peaks / Ratio /  Ret. Time
 Compound/
 M_Z....  QC.Log Omit Why . .RT.
     OK Ratio Total. Area... Area.Peak. 1..  Area. Peak. 2. .  Rel. RT Compound. Name. . ID.. Flags.
TCDF
304-305 DC NL 0:00
16:18
16:33
16:47
16:52
17:15
17:22
17:30
17:40
17:55
18:05
18:11
18:22
18:32
DC SN 13:41
18:51
19:02
19:08
19:16
19:31
19:42
19:54
20:04
20:26
20:33
20:44
20:57
21:04
21:14
21:43
22:20
DC HH 22:48
304-306 29 Peaks
1 3d 2 -TCDF
316-318 DC NL 0:00
DC VJL 17:25
DC ML 19:16
20:31
DC WH 22:22
316-318 1 Peak
0.65-0.89
RO 0
0
RO 1
RO 2
0
0
0
0
0
0
0
0
0
0
RO 2
0
RO 1
RO 0
0
0
0
0
0
0
0
0
0
0
0
0
0
RO 0

.64
.82
.07
.03
.88
.77
.79
.78
.76
.77
.77
.72
.78
.83
.15
.76
.06
.63
.78
.76
.77
.78
.76
.77
.76
.80
.76
.83
.73
.74
.77
.94

2.02
1,410.69
15.26
9.74
32.39
1.935.93
1.153.31
1,575.78
1,153.53
821.51
1,162.68
434.03
2,653.83
654.13
0.81
2.244.41
9.12
22.60
1.124.25
992.12
925.52
109.96
705.65
623.53
660.78
486.40
580.61
1,101.77
13.40
807.74
55.89
2.16
23.476.56

637.
9.
11.
15.
839.
508.
691.
496.
358,
507.
181.
1,165.
295,

971.
5,
9,
491,
429.
404.
48.
305
271.
285
216
250
498
5
344
24,



21
21
15
.14
.22
.86
.99
.70
.21
.23
.36
.37
.91

.64
.45
.83
.26
.35
.02
.26
.76
.00
.30
.02
.05
.19
.66
.44
.23



773,
8.
5.
17.
1,096.
644.
0.

48
.62
.50
.25
,71
.45
883.79
656
463.
655,
252
1,488
358

1,272
5.
15.
632
562
521
61
399
352
375
270
330
603
7
463
31


O.S5-0.89
RO 1
RO 7
RO 3
0
RO 0

.27
.36
.24
.76
.63

2.87
0.19
1.31
726.48
4.53
726.48



314.





.54





411


.83
.30
.45
.67
.46
.22

.77
.15
.71
.99
.77
.50
.70
.89
.53
.48
.38
.56
.58
.74
.30
.66


0.



.94


786-1.095
0.
0.
0.
0.
0.
0.
0.
0.
0,
0.
0,
0,
0,
0,
0,
0,
0,
0.
0,
0,
0,
0
0
0.
1
1
1,
1,
1
1,
1,
1

000
794
807
818
.822
.841
.846
.853
.861
.873
.881
.886
.895
.903
.911
.919
.928
.933
.939
.951
.960
.970
.978
.996
.002 2378-TCDF AN
.011
.021
.027
.035
.058
.089
.111

951-1.049
0
0
0
1,
1

.000
.849
.939
.000 13C12-2378-TCDF ISO
.090

Triangle Laboratories, Inc.®  Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                    Printed: 02:10 09/22/97

-------
  Page No,
  09/22/97
Listing of P9739S4B.dbf
Matched -3C Peaks  / Ratio / Ret. Time
  Compound/
  M_Z,.., QC.Log Oraic Why  . ,RT. OK Ratio Total .Area.., Area,Peak,1..  Area.Peak.2.. Rel.RT Compound. Name..  ID.. Flags,
  13C12-TCDD
  332-334
  332-334

oc



DC

ML 0:
19:
19:
20:
VJH 21:
0.
00 RC
21
34
14 RO
53
	 • 	 jrt.
5J-0.89
1.87
0.80
0.81
0.62
0.71
3 Peaks
                                        Above: TCDF  / TCDD Follows
                                                 1,54
                                               551.75
                                             1,070.9i
                                                 6.11
                                                 1.37
                                             1,628.77
                                  244.55
                                  477.97
                                    2.66
    0,3911-1.103
        0,000
307.20  1.000  13C12-2378-fCDD IS1
592.94  1.011  13C12-1234-TCDC SSI
  4.28  1.046
        1.131
 Column Description............  s^by* Code Description,,,,.....   QC &og Desc.
 M_S   -Nominal Ion Mass(es)     WL-Below Retention Time Window   &-Peak Added
 ..RT. -Retention Time Jmm:ss)   WH-Atoove Retention Time Window   K-PeaJc Kept
 Rat.l -Ratio of H/H+2 Ions      SN-Below Signal to Noise Iievel   D-Psak Deleted
 OK    -RO=Ratio Outside Limits  
-------
               17:00         18-00          1S:00         20:00         21:00
file:P973984  #1-755 Acq:19~SEP~1997 20s30:SO SI+ Voltage SIS  70P Hoiae:689
305.8987 BSm(256,30,-3.0> PKS>(5,3rl,0.10*,275S,0,0.00\,T,F)  Slp:O322S
         LABS  Tmxt:BO-23-l TLIM3229
nj.eifS739S4  #1-755 Acq:±9-SEP-1997 Ztts3Oi5a EH- Voltage SIR 7CP Nctise:442
303,3016 BStm(3Se,30r-3,!>} PJCDfS, 3,1. 0.10%, J7S8, 0, 0,0ff%,f» F; Ec
                                                                                       22:00
               17:00         lit: 00          IftOO         20:00         21:00
MJ.eiP973984  tl-755 &oi:19-SEP-1997 20t30t50 Elt Voltage SIB  70P Hbise:1027
315.9419 BSnB(25e,30,-3.0) PKDfS,3,1,0.101,4108,0,0.00l,rrf)  ExptDB225
ISrAHSEE LABS  SnxtlBO-23-1 TU:#4322S
100S                                                            M3.1SSS
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                                                                                       22:00
               17:00         18-00          15JOO         20-00
Kls:fS73984  tl-755 Mcq:lS-SEf-l9S7 20:30:50 Sit Voltage SIR 70P Ubises
317.9389 BSUB(25S,30,-3.0) tXD(S, 3,1,0.101,3236.0, 0.001,T,f) ExpsDB225
ZRI&HGLE LABS  TeltiSO-23-1 TLI&43229
lOOS                                                            A4.J.2E6
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                                                                        21:00
               17*00         18:00          19:00         SOlOtt
tila:f97398t tl-755 Jteyil9-ssr-1997 20130:50 EI+ Voltage SIS 7QP
375.B364 Sxp:Hf22S
TRIANGLE LABS   Text:BO-23-l  XLI#43229
1004
 so:
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                                                                        21:00
                                                                                       22:00
                                                                                       22:00
              17100
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    Tims
                                                                                              114

-------
 File:tS73aS4"'U-7S5 Ac-slSl>-lSS7 20:30:50' Eli- Voltage siR"7Sf Noi3e:7S7~
 319.8965  BSm(25S,30e-3.0) PKD(5,3,1, 0.10%,, 3068, 0, 0.00^,F,f)  SxpsDS225
 TXIKMGZE  IABS  XoxtsBO-23-1 TLH43229
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lfileiP9739B4 11-755 Acq:19-sep-1937 20:30t50 EH- Voltage SIS 70P Hoiae:704
321.B936 BSV3(256,30,-3.0) fIO}(5, 3, I, 0.10*,2B16.0,0. 00*,y,F;  Elp:DB225
TSIJUtGLZ TABS  Tmit:BO-23-l TLI$43223
100M1.SOBS
  80.
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  40.

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A7.3SES    R7.61E!
                                 A3.68ES
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                                             An   i \      AJ.iiEJ
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                                                      Al. OSES
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-------
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-------
tef, MSS   23E,S$5     Ptak top
Height  229 wits  Span   i8p
Systea file nate
Data   flU nas
Resolution
                            1
louzatton soda              El*
Mtchlng              VOLTfiGE
            &9B5,
ft  192.98ES
6  383,3815
C
D  315.9419
E  317,
F  319,9965
G  It,
   327,8847
I  338.9792
Qiamd  1  338,9791     Peak top
Help  248wits  Sp   Sip
                                                        117

-------

-------
TLI Project:     43229
Client Sample:   BO-23-2
Method 23 PCDD/PCDF Analysis (a)
            Analysis File:   T976376
Client Project:
Sample Matrix:
TLI ID:

Sample Size:
Dry Weight:
GC Column:
S414.003/WAUPACA Foundry
M23TRAIN
183-1-3A-C

1.000
n/a
DB-5
Date Received: 09/12/97
Date Extracted: 09/14/97
Date Analyzed: 09/18/97
Dilution Factor: n/a
Blank File: T976373
Analyst: KAS
Spike File:
ICal:
ConCal:
% Moisture
% Lipid:
% Solids:
SPX23704
TF53286
T976372
: n/a
n/a
n/a

'f^^^f'^fV^^'^^^^^^^'^^ry^f.

2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxGDD
1,23,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
23,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpGDF
U,3,4,6,7,S,9-OCDF

Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
^;>»i:<-^:-^>>:*:-jf;»6-K::a^XS;^;y^:-:^'^;^:v:
S^^S:§»^>-5>^%^;»%^:^f^^S'J^fT»
034
1.7
0,74
1.4
1.9
2.1
0.59
32.9
93
12.5
13.2
6.9
4.8
030
5.6
0.94
0.41

20.1
14.4
15.2
4.0
262
175
65.7
9.3
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7 25.3
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0.75
1.53
1,16
1.21
125
1.09
0.96
0.82
1.49
130
1.32
1.28
1.32
1.22
1.09
1.09
0.81









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21:34 	
26:08 	
29:21 	
29:26 	
29:43 M.
32:15 	
34:43 	
20:48 	
25:00 	
25:45 	
28:36 it
28:43 	 •
29:13 M,
29:56 	
31:24 	
32:35 	
34:50 	




	




                                       Page 1 of2
                                                                        X237.PSR»100,LARS«.10.(M
Triangle Laboratories, Inc. 5
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                     Printed: 01:52 09/22/97
                    na

-------
TLI Project:       43229
Client Sample:    BO-23-2
                      Method 23 PCDD/PCDF Analysis (a)
                                     Analysis File:   T976376
J8PS«$gWH*i*S
nC«-2,3,7,8-TCX>F
BC,r2,3,7,8-TCDD
»CM-l,2,3,7,8-PeCDF
»Cu-l,2,3,7,8-PeCDD
»Ci2-l,2,3,6,7,8-HxCDF
l>C12-l,2,3,6,7,8-HxCDD
»Ci2-l,2,3,4,6,7,8-HpCDF
»Cu-l,2,3,4,6,7,8-HptI>D
l5Cn-l,2,3,4,6,7,8,9-OCDD
2.4
1.9
1.9
1.9
2.3
2.6
2.4
2.9
5.6
 60.1
 48.4
 48.5
 47.3
 58.7
 64.8
 58,8
 72.8
 70.5
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
0.73
0.85
1.48
1.46
0.50
1.25
0.41
1.01
0.81
20:45
21:33
24:59
26:07
28:42
29:25
31:23
32:14
34:42
wCl4-23,7,8-TCDD
l3C,2-2,3,4,7,8-PeCDF
»C,2-l,2,3,4,7,8-HxCDF
13CB-l,2,3,4,7,8-HxCDD
13C,2-l,2,3,4,7,8,9-HpCDF
3.8
4.0
4.1
3.6
4.6
 94.9
100
103
 90.7
116
70%-140%
70%-140%
70%440%
70%-140%
70%-140%
1.46
0.48
121
0.44
21:34
25:44
28:36
29:20
32:34
uCw-l,2,3,7,8,9-HxCDF
»Ciz-2,3,4,6,7,8-HxCDF
2.8
2.6
 69.5
 63.8
40%-130%
40%-130%
0.48
0.49
29:55
29:13
''C,2-1,2,3,4-TCDD
l3C12-l,2,3,7,8,9-HxCDD
                                          0.85
                                          1.20
                                    21:21
                                    29:42
                         Data. Reviewer
                                     09/22/97
                                                Page 2 of2
                                                                                        XS7.PS8 VIM. LARS«.KUW
Triangle Laboratories, Inc.®
801 Captola Drive « Durham, North Carolina 27713
Phone: (919) 544-5729 * Fax: (919) 544-5491
                                                Printed- (11:52 09/22/97
                                  rinjed: 0.1:

-------
                        Initial
 Data Review By:
                                              Calculated Noise Area: n/a
 The Total Area Cor each peak with an  ion abundance ratio outside
 ratio limits has  been recalculated according to method requirements.
 Page Ho.
 09/22/97
Listing of T97637SB.dibf
Batched OC Peaks / Ratio /  Ret. Time
 Compound/
 H_2,	QC.Log Omit Why , ,RT. OK Ratio Total. Ami.—  Area.Peak. 1..  Area.Peak.2,,  Bel.IT Compound. Mama,, ID.. Flags.

 TCDF
 304-306
 I3C12-TCDF
 316-318
 316-318
 TCDD
 320-322
0.
DC HL 0:00 BO
17:19-
17:50-
18:04'
18:2S.
18:48-
19:19.
19:37-
19:53-
20:19.
20:34'
20:49 •
21:14-
21:29'
21:44'RO
22:38 RQ
BC WH 22:55
15 Peaks
0,
OC WL 18:52 RO
20:45
DC Sft 21:32 RO
1 Pel*
0.
18:44'
19:11.
19:31-
20:17
20:23'
20:34 '
21:00 -
21: 18i
21:28
21:34 *
21:44-
21:56-
22:10 '
DC SH 22:21
22:38-
,£5-0.89
1.39
0.82 1
0.83
0.83
0.82 3
0.84 2
0.84 2
0.85 1
O.R6 2
0.82
0.84
0,82 2
0.84 1
0.81 1
0,98
0.93
0,8»
21
.65-0.89
2.72
0.73
0.22

65-0.89
0.77
0.70
0,86
0.79
0.82
0,83
0.75
0,78
0.72
0.75
0.32
0.81
0.68
O.S5
0.7S

0.78
,296.89
738.54
3«8.51
,784.88
,351.75
.120.92
.695.38
,083.72
82S.39
757.29
,656.91
,279.78
,334.84
74.27
56.59
37.50
.416.66

0.69
297.65
0.87
297.65
TCQF / TCDQ

298.04
115.53
7S.3S
209.43
43.99
90.83
SI. 08
67.17
91.89
32.28
20.37
65.10
16.61
0.33
13. 7i


583.22
335.73
167.60
1,701.86
1,075.51
966.75
77«.61
954.80
373.36
345.77
1,201.90
5 B 6. 09
598.70
40.93
29.84




12S.24



129.82
47.52
35. 28
92.34
19. 7S
41.18
28,26
29.03
38.48
13.86
9.17
29.22
6.70

5.S4
0.

713.67
402.81
200.91
2,083,02
1.276.24
1,154.17
S18.77
1,108.92
453.03
411.52
1,465.01
S93.69
736.14
41.96
31.97


0.

172.41


0.
168.22
68. 01
41.08
117.09
24.23
49.65
34.82
38.14
53.41
18.42
11.20
35,88
9.91

7.85
826-1.097
O.QOO
0.835
0,859
0,871
0.891
0.906
0.931
0.945
0.958
0.979
0.991
1.002 2378-TCDF AS
1.023
1.035
1.047
1.041
1.104

SS2-1.048
0.909
1.000 13C12-2378-TCW ISO
1.038

861-1.056
0.869
0,890
0,906
0.941
0.950
0.954
0.974
0.988
0.996
1,001 2378-TCnU AH
1.009
1.018
1,029
1.037
1.050
Triangle Laboratories, Inc.® Analytical Services Division
001 Capitals Drive»Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 01:53 09/22/97
                                                                     120

-------
 Page No.
 09/22/97
Listing of  T976376B.dbf
Hatched GC  Peaks / Ratio /  Ret. Tin
 Compound/
 H_Z---- QC.Log Omit Why . .RT. OK Ratio Total .Area.-.  Area.Peak.1. . Area.Peak.2. . Rel.RT Compound. Name.. ID.. Flags.


 320-322             14 Peaks              1.202.47
37C1-TCDD
323 DC WL 18:17
DC WL 19:04
DC WL 19:13
DC HL 19:32
DC SN 19:55
20:04
DC SN 20:21
DC SN 20:28
DC SN 20:47
DC SN 21:10
DC SN 21:19
21:34
DC SN 21:45
22:01
DC SN 22:32
DC SN 23:01
DC SN 23:10
328 3 Peaks
13C12-TCDD 0.
332-334 DC ML 0:00 RO
DC HL 18:42 RO
DC HL 19:00 EO
DC HL 19:13 RO
DC SN 19:39
DC SN 20:18 RO
DC SN 20:35 RO
21:21
21:33
21:52 RO
DC SN 22:10 RO
DC SN 22:17
332-334 3 Peaks
PeCDF 1 .
340-342 22:54'
23:11 RO
23:35 RO
23:57-
24:07.
24:17-
24:31'
24:43 •
A 24:55 •
M 25:00-
25:10'
25:18 •
65-0.89
4.11
0.52
2.51
0.92
0.73
1.87
2.
0.
0.
1.
2.
0.

99
85
85
42
83
as

32-1.78
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
52 1
83
99
49
52 3
51
56
52
53
49
53
50
1.40
6.28
4.74
0.70
0.32
124.74
0.72
0.23
0.24
0.06
0.37
175.50
0.58
30.53
0.17
0.13
0.45
330.77
0.97
2.07
0.33
1.12
2.53
1.93
1
383
202
5
0
4
.70
.15
.49
.77
.71
.12
591.41

,214
18
20
789
,717
774
339
849
193
592
430
518
.02
.59
.32
.67
.91
.91
.00
.59
.30
.00
.39
.32
124.
175.
30.

176.
93.
4.


74
50
53

49
27
64


0.907-1.093
0.872
0.885
0.892
0.906
0.924
0.931
0.944
0.950
0.964
0.982
0.989
1.001 37C1-TCDD
1.009
1.022
1.046
1.068
1.075
0.907-1.093
0.000
0.868
0.892
0.892
0.912
0.942

206
109
3



.66
.22
.26


0
0
1
1
1
1
.955
.991 13C12-1234-TCDD
.000 13C12-2378-TCDD
.015
.029
.034
SUR1

RSI
IS1





732.
13.
15.
472.
2,241.
466.
206.
512.
117.
354.
260.
311.
85
31
87
30
50
66
41
98
00
00
35
08
481
7
7
317
1.476
308
132
336
76
238
170
207
0.909-1.075
.17
.29
.97
.37
.41
.25
.59
.61
.30
.00
.04
.24
0
0
0
0
0
0
0
0
0
1
1
1
.917
.928
.944
.959
.965
.972
.981
.989
.997
.001 12378-PeCDF
.007
.013









AH


Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed U>1:53 09/22/97

-------
 M_Z
                        Listing at TS76376S.dbf
                        Hatched GC Peaks / Ratio  / Ret.  Time
         QC.Log Ondt Why . .RT. OK Ratio Total. Area,.. Area, Peak. 1.. Area.Peak.2..  Ral.RT Conpoynd. Maine.. ID,.  Flags,





340-342
13C12-P»CDF
352-354











352-354
PeCDD
356-358




M





356-358
13C12-P9CDD
368-370




368-370
H3CCBF
374-376


25:45'
25:53
26:12
26:45
DC WH 26:55
16 Peaks

DC SH 23 i 41
DC SN 23:55
DC SN 24i07
DC SH 24:35
24:59
DC SN 25:17
25:44
DC SN 26:02
DC SH 26:11
DC SH 26:28
DC SN 26:42
DC SN 26:53
2 Peaks
W
24:14.
24:44-
25:00.
25:09.
25:20.
25:36.
25:49.
25:56,
26:08-
26:15.
26:36 ,
11 Peaks

DC SH 25:01
DC SH 25:18
DC SH 25:28
26:07
26:16
2 Peaks

DC ML 0:00
27:37 '
27:46 •




RO

1,
RO
RO
RO
RO

RO

RO
RO
RO
RO
RO

t
RO




RO
RO
RO




1.
RO
RO
RO



1.



l.SO
1.53
1.41
1,58
0.97

.32-1.78
10.13
o.is
2.49
2.38
1.48
0.75
1.46
4.48
1.07
2.27
1.30
1.95

,32-1.78
1.14
l.SO
1.54
1.71
1.56
1.80
1.93
0.91
1.53
1.50
1.50

32-1.78
0.90
5.43
8,60
1.46
1.55

05-1.43
1.15
1.34
1.37
802.23
734.80
36.76
63.67
3,18
11,095.48

0.41
0,07
3.03
1.35
228.97
1.61
234 . 19
0.64
1.02
2.17
1.20
0.51
463.16
t PoCDF /
293.30
37.76
185.88
75.52
148.15
107.61
27.59
16.39
69.65
38.46
37.30
1,037.61
481
444
21
39







136

138

.23
.40
.48
.01







.52

.82

321
250
15
24







92

95

.00
.40
.28
.66


0,




.45

.37

1
1
1
1
1

.031 23478-PecnF
.036
.049
.071
.073

US





840-1.160
0
0
0
0
1
1
1
1.
.943
,957
.965
.984
.000 13C12-PeCOP 123
.012
.030 13C12-PaCDF 234
.042




IS2

SUR2

1.048




I
.059

1.069
1.076

•^•^••y*™™' *^ /
178
23
112
47
90
75
20
9
42
23,
22,

.28
,22
.57
.61
.31
.80
.91
.96
.17
.06
.36

156
14
73
27
57
O.S22-1.025
.78
.54
.31
.91
.84
42.20
10
10
27
15
14

.82
,94
.48
.40
.94

0.928
0,947
0.957
0.963
0.970
0.980
0.989
0,993
1.001 12378-PeCDD
AN
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Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 01:53 09/22/97
        , o
     122

-------
 Page No.
 09/22/St
Listing of T97S376B.dbf
Macch»d 
-------
 Page Mo,
I4s=ina of f97«37SB.db£

Matched OC Peaks /  Ratio / Ret. Time
 Compound/
 K_2.,., QC.Log Gait Why ..IT. OK Ratio Total. Urea.,, Area.leak. 1.. teem.Peak,2..  Rsl.ftT Confound. Hame..  ID..  Flags.
13C12-HXCDD
102-404








402-404
HpCDF
408-410





403-410
13C12 -HpCDF
418-420




418-420
HpCDD
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424-42S
13C12-HpCDZJ
436-438


43S-438
OCDF
442-444



DC WL 23:09
BC ML 28i2:
DC WL 28:14
DC SH 28:49
29:20
29:25
29 1 42
DC SH 29:54
DC SH 30:14
3 Peaks

31:24
31:37
31:44
32:35
DC WH 32:55
DC Ml 33:03
4 Peaks

31:23
DC SH 31:33
DC SB 33:18
32:34
DC SH 32:58
2 Peaks

31:38
DC SN 32:03
32:15
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2 Peaks

32:14
DC Sit 32:40
DC SH 32:43
1 Peak

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DC SN 32:18
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1
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RO



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1.09
0,94
1.03
1,99
0.69
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0.41
0.26
0.23
0.44
0.62

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0.9J
0.96
1.09
0.92

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1.01
1.64
0.57

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2.12
1.49
0.47

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0.3S
0.27
0.72
170.45 93.20
209.00 115,94
342.09 136.41
0,74
0.98
721.54
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9S.08 47.98
65.75 33.31
44.03 22,97
1.10
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0.93
1.36
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0.957
0.964
0.965
0.930
77.25 0.997 13C12-HXCDD 478
S3. OS 1.000 13C13-HXCDD 678
155. 68 1.010 13C12-HXC0D 789
1.01*
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0.994-1.042
195.47 1.001 1234678-HpCDF
51.10 1.007
32.44 1.011
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1.049
1.053

0.936-1.127
117.41 1.000 13C12-HpCDF «78
1.008
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104.71 1.038 13C12-HpCDF 789
1.050

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Triangle Laboratories, Inc.®  Analytical Services Division
801 Capttola Drive » Durham, North Carolina 27713
Phone: (919) 544-5729»Fax: (919) 544-S491
                                                                 Printed: 01:53 09/22/97
                                                                        "  "i ,T
12".

-------
 Page Ko,      S            Listing of T976376B.<3bf
 09/22/97                  Matched OC Peaks / Ratio /  ReC.  Time

 Compound/
 M_Z.... QC.Loa  Omic Why ..ST.  OK Ratio Total. Area...  Srea.Feak. 1.. Area. Peak. 2..  Rel.RT Compound. Mama..  IB..  Flags.

                 DC  SS  33:43  RO  0.50          0.2S                             O.974
                 DC  SH  34:11  RO  2.S7          0.17                             G.3SS
                 DC  SN  34:23  10  0.42          0.17                             0.991
                         34:50     0.81         17.64          7.8»          9.75  1.004 OCDF            AN
                 DC  SN  35:21  RO  0.44          0.08                         ,   1.01S
 442-444               1 Feak                  17.64

 OCDD                           0.76-1.02                                     0.885-1.115
 458-460         DC  SN  34:33  RO  0.11          0.13                             0.996
                         34:43     0.96         21.61        10.59         11.02  1.000 OCDD            AH
                 DC  at  35:03  BO  4.30          0.19                             1.010
 453-160               1 Peak                  21.61

 13C12-OCDD                     0.76-1.02                                     0.99S-1.004
 470-472                 34:42     0.81        290.40        130.16        160.24  1.000 13C12-OCDD      IS8
                 DC  MB  34s5«  RO  2.03          1.68                             1.007
 470-472               1 Peak                 290.40
 Column Description.	   "Why" Code Description.... —..  QC tog Besc,
 H_Z   -Nominal Ion Mass(es)      WL-Below Retention Tina Window  A-?aak Added
 .. RT. -Retention Tims (mm: 33)    WH-Above Retention Tims window  K-Psak Kept
 ftat.l -Ratio of H/M+2 Ions      SH-Belov signal to Boise Level  D-Peak Deleted
 OK    -RC-Ratio Outside Lindta  
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-------
 TLI Project:       43229
 Client Sample:    BO-23-2
                          Method 23 TCDD/TCDF Analysis (DB-225)
                                               Analysis File:   P973985
 Client Project:    S414.003/WAUPACA Foundry
 Sample Matrix:   M23TRAIN        Date Received:  09/12/97
 TLI ID:          183-1-3A-C         Date Extracted:  09/14/97
                                    Date Analyzed:  09/19/97
                                                 Spite File:   SPC2NF04
                                                 ICal:        PF22206
                                                 ConCal:     P973982
 Sample Size:
 Dry Weight:
 GC Column:
1.000
n/a
DB-225
Dilution Factor: n/a
Blank File:     T976373
Analyst        ML
% Moisture:  n/a
% Lipid:     n/a
% Solids:    n/a
2,3,7,8-TCDF
              6.8
                                0.77
          20:31
»CI2-2,3,7.8-TCDF
              1.9
          48.4     40%-130%
  0.78      20:31
                                                                    0.81      19:33
                      Data Reviewer:.
                                         Page 1 of 1
                                              09/22/97
                                                                             C3NPJSR viOO. IMtS S. 10O4
Triangle Laboratories, Inc.»
801 Capitola Drive » Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                          iBted: 02:10 09/22/97
                                   ^ BiRtea: 02:

-------
                      Initial.
     Review By:
:ial	Date.
1U^
                                          Calculated Noise Area: n/a
 The Total Area £or each peak with an ion abundance ratio outside
 ratio limits has been recalculated according to Method r«3uiremftnts.
Page 5Jo, 1 Listing
09/22/97 Matched
Confound/
M_2 	 gf.Lssg oiaie Why ..«t, OX
TCDP 0.
304- J06 DC Bti 0:00 RO
IS: 17
18:33 RO
16:42 RO
IS: 51
17:14
17:20
17:28
17:38
17:54
18:03
18:10
18:20
18:26
18:30
DC SH 18:39
18:50
18:53
19:07
19:16
19:31
19:41
19:53
20,03
20sll RO
20:15
20:25
20:31
20:42
20:56
21:03
21:13
DC SN 21:19 RO
21:42
DC Of 21:56 RO
22:19
DC HK 22:48 RO
304-306 32 Peaks
13C12-TCOP 0.
316-313 DC NIi 0:00 RO
DC WL 19:15 RO
20:31
of P973985B.db£
GC Peaks / Ratio / Ret. Time
Ratio Total .Area. .. Area, Peak. 1. . Area. Peak. 2. . Ral.RT Compcur.d.IJa,-tie. . ID.. Flags
65-0.89 0. 786-1. 09S
0
0
1
.92
.79
.11

2

0.63
0
0
0
0
0
0
0
0
.65
.77
.80
.BO
.77
.77
.78
.77
0.78
0
0
0
.55
.87
.81
0,83
0
0
0
0
0
0
0
.69
.70
.79
.81
.79
.78
.82

3
1
2
1
1
1

3



2
1

I
1
1

1
0.52
0
0
0
0
0
0
0
a
0
0
0
i

.74
.83
.77
.79
.77
.78
.72
.43
.77
.50
.77
.21


1
1

1
2


2



38
2.74
,082.99
2S.40
4.80
59.34
,108.58
,849.96
,295.58
,790.51
,219.48
,798.44
702.04
,928.30
SOS. 92
613.61
2.15
,205.38
,208.89
61.20
,708,01
,614.76
,506.20
195.25
,430.61
6.39
»,05
,225.12
.106.76
351.88
.133.56
,309.90
21.47
2.41
,004.78
1.63
§6.57
3.79
,681.73

920
15
2
23
1,351
820
1,017
777
530
786
306
1,721
198
286

999
492
25
753
723
664
85
£43
2
3
554
432
376
493
1.014
9

871

42



.61
.92
.09
.37
.82
.43
.92
.04
.23
.89
.00
,51
.91
.17

.72
.49
.23
.08
.93
.26
.57
.11
.78
.86
.36
.67
.40
.94
.50
.01

.11

.05



1,152
14
3
35
1,756
1,029
1,277
1,013
639
1.011
396

.38
.33
.30
.97
.76
.S3
.66
.47
.25
.55
.04
2,206.79
308
.01
327.44

1,205
716
35
954
890
341
109
787
5
5
670
624
475
639
1,295
12

1,133

54


.65-0.89
1
1
0
.38
.07
.78



1.98
3.66
629.63


275


.07


354

.66
.40
.92
.93
.83
.94
.68
.50
.31
.19
.76
.09
.48
.62
.40
.46

.67

.52


0.


.55
0
0
0
0
0
0
0
0
0
0
0
o
0
0
0
0
0
0
0
0
0
0
.000
.794
.807
.814
.321
.840
.845
.851
.359
.872
.880
.885
.894
.398
.902
.909
.913
.920
.932
.938
.951
.959
0.969
0
0
0
0
1
1
1
I
1
1
1
1
1
1

.977
.984
.987
.995
.000 2378-fCDF AN
.009
.020
.026
.034
.039
.058
.069
.088
.111

951-1.049
0
0
1
,000
.933
.000 13C12-2378-TCDF ISO
Triangle Laboratories, Inc.® Analytical Services Division
801 Capttola Drive * Durham, North CaroBna 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
| ain
                                                                  : 02:10 09/22/97

-------
 fage.Ha.     2           Listing of P973985B.dbf
 09/22/97                 Matched GC Seaks / Ratio /  Ret. Time

 Confound/
 K_Z,... QC.Log Onle Why ..RT. OK Ratio Total.Area,..  JUraa-Peak, 1.. Aiea.Peak.2..  Bwl.W Compound. Name

                                                                                  1.D2S
                                                                                  1.029
                                                                                  1.047
                                                                                  1,055
                                                                                  1,090
 316-318
DC
DC
DC
OC
DC

SN
SH
SN
HH
HH
1
21:02
21:07
21:29
21:39
22:22
Peak
RO
RO
RO
RO


1.
1.
1.
2.
0,

.43
.03
,34
,37
,87

0
1
0
0
5
S29
.80
.29
.37
.34
.15
,63
                                        Above: TCDF / 1CDD Follows
 13C12-TCBD                     0.65-0.39                                     0.897-1.103
 332-334         DC  HI.   0:00 BO  2,27          1.17                             0.000
                 OC  SS  17:40     0.71          1,14                             0,914
                 DC  SS  18:18 RO  0.31          0,81                             0.947
                         19:20     0.12        472.72       212.59        260,13   1.000 13C12-2378-TCDD IS1
                         19:33     0.81        936,97       418.99        517.98   1.011 13C12-1234-TCI1I> RSI
                 DC  SK  19:59 RO  1.83          0.71                             1.034
                         20:14 RO  0,98          S.71         3.72          3.79   1.047
                 OC  SH  21:16 RO  1.54          0.23                             1.100
                 DC  HH  31=57 SO  3.40          0.27                             1.135
                 OC  WH  22:08 RO  1,41          0.55                             1.149
 332-334               3 Peaks      '         1,416.40
 Column Description	  "Why* Cods Description	  QC Log Desc,
 M_Z   -Nominal Ion Mass(es)     Wt-Below Retention Tine Window   A-Pea)c Added
 ..RT. -Retention Tiaa (sm:ssl   WH-Abova Retention Time Window   K-Peak Kept
 Rat.l -Ratio of M/M+2 Ions      SH-Belov» Signal to Koiaa Laval   D-Ieak Deleted
 OK    -KO=Ratio outsida Limits  
-------
f£Le:f3?3SaS ......... '»I-75T Acq:lS-ssf-lSB7 21slSi33 ....... KtV Voltage
303.901S asaa(2SS,30,-3.0)  na>is,3ri,o.io
         IABS  TGZ-ttSO-23-2 XLH43229
               17100         18:00         JSiOO          20:110         21,00
rile!tS73983  #1-755 AaqslS-Sff-1997 21:18:32 .EH- Voltage SIB 7flF I»iaej773
JOS.8*87 asOBf25ff,JO,-J.(); jPJOJfS,J,l,0,lff
         IAJS  r&rt.ao-JJ-J 2XTMJ229
                                                                        Jii.jor7
                                                              70P flbiae8711
1001



 soi

 401

 20,
               17100         18100          IS'100         20:00         31:00
rU.msf9739BS  H-73S Acqsl9-SSP-1997 31:18,32 SX+ Voltage 31* 70P Boiaei775
31S.9419 BSVa(2S6,30,-3.0) rXD(5r3,lr0.10\,310:P9739aS «-755 Acqtl9-SSf-1937 31iia>32 fl+ Voltage SIX 70P HOiaet561
317.9389  BStnt(256,30,-3.0) fKO(S, 3,1, 0.101,2244.0,0.00\,f,F) XxpsOB225
TRIANGLE  LRBS  Sext:BO-23-2 TLI143229
1003,                                                            A3,?5E6
801


SOI


401


201
               17:00         18:00          19:00          20:00
fileit97398S #1-755 Acqt 19-SEt-lS97 21:18:32 XH- Voltage SIS 70V
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55RMJJGEE ULSS  TexttSO-33-2 XKH43239
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                                                 19:23
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               17.-BO

-------
 fileiP9739B5 #1-755 Acq:19-S£P-1997 21:J.UU1JBH- Voltage SIM 70P Noise:001
 319.8965 asVB(256,30,-3.0) fKD(S,3,1, 0.101,3204.0, 0.00\,r,r) XzpiBB225
 ZMUOtSLS JM»S  TextlBO-23-2 Ttl#43229
 1001,
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A A/W V - )w JU-"K - AI-"K
   17:00             18:00            19:00             20-00            21:00
 riletf9733BS  #1-755 Acq:19-SEP-1997 21:lBi32 EH-  Voltage  SIS  7OP Koine: 12S9
 321.8936 MSUa(2S6,30,-3.0) rKD(S,3,lrO
 THT3XSLE LAMS  TesxtlSO-23-2 TZXV43229
 loot.
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  so:
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   17:00             13:00            IStOO             20:00            21:00
rileiP97398S  #1-755 Acq:13-SEP-1397 21:18:32 EH- Voltage SIS  70P HO±Be:745
327,8847 BSUX(2SS,30,-3.0)  fXD(5,3,l, 0.101,2980. 0, 0.00*,r,f)  Eip:DB225
TSIANSLE LAMS TaxtlBO-23-2 TLH43239
                                           A4.24ES
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331.9368 BBOB(2S6,30,-3.0)  PXD(S,3,1, 0.10^,2996. 0, 0.00%,r,F) Ezp:DB225
TSIRNSLE LASS  Text:BO-13-2 XLX#43329
1001                                          A4,}3ES
                                          A2.13EI
   17100            18:00             15:00            20100            21:00
til»:f97399S tl-755 Acy!l9-SXP-1997 21:18:33 EH- Voltage SIS 70P So±ae:332
333.9338 Bsm(35S,30,-3.0i PKD(5,3,1, 0.101,1328.0, 0. 00%,r,J>) E
TRIANGLE LASS  Text:BO-23-2 TLH43229
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   17: tO
                    18100
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                                                                                  Tiat
                                                                                       144

-------
BileiP973SaS #1-755 Aoqsl9-SSr-lSa7 21:18:32 SH- Voltage
303.9016 Exp:DB325
TRIANGLE LABS  Tmxt.sBO-23-2 TLIt4J22S
1001
  §*ii
  so.:
  40:
  20:
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              17:00         ISiOfl          1S.-00
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TSIANSLE LASS  TertsBO-23-2 TLIH3229
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                                                          30:03

                             13:00
                                           19:00
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                                                                                                         Time
                                                                                                   15. IBS
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                                                                                                         Time

-------
ft  82.3825
I  33.3816
0
I
r
G  321,8938
H  327,884?
I  338,9792
Ref . §ass    292.988     Auk top
Height  2.18 wits  Span  288 p

Systa file me
Mi   fUftmi
fesdullon
Sro^nusber
lonizstion M!Jg              El*
Suitching               V1TRGE
tef, lasses   292.S25,   388.97S1
                            1
                  J  338.3792
                  K  331,338

                  I  £5,8364
Chanel  !  338,9793
Height  1,1 volts  Span  298 ppi
                                                    14C

-------

-------
TLI Project:      43229
Client Sample:   BO-23-3
Method 23 PCDD/PCDF Analysis (a)
             Analysis File:   T976377
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
S414.003/WAUPACA Foundry
M23TRAIN Date Received:
183-1-4A-C Date Extracted:
Date Analyzed:
1.000
n/a
DB-5
Dilution Factor:
Blank FOe:
Analyst:
09/12/97
09/14/97
09/18/97
n/a
T976373
KAS
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
TF53286
T976372
n/a
n/a
n/a

2,3.7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7^-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-QCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3A7,8-PeCDF
1,2,3,4.73-HxCDF
1,2,3,6,73-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF

Total TCDD
ToM PeCDD
Total HxODD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF

0.73
2.5
1.1
2.2
2.5
32
EMPC
48.1
13.8
18,8
18.6
9.0
7.0
0.75
7,3
1.3
0.65

33.2'
30.2
22.6
6.0
336
260
94.4
12.7

0.81
1.64
1.27
1.18
1.19
1.02
0.57
0.82
1.55
1.54
1.29
129
128
1.13
1.04
1.17
0.92

21:35 	
26:08 	
29:21 	
29:27 __
29:43 M
32:15 	
	
20:49 	
25:00 	
25:46 	
28:36 M.
28:43 	
29:14 £&
29:56 	
31:24
32:35 	
34:51 	

11 34.0
9 45.3
7
2
17
15 261
12
4



—




                                       Page 1 of2
                                                                             »«S.LARS6.10,0»
Triangle Laboratories, Inc.a
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                     Printed: 01:53 09/22/97

                       147

-------
TLI Project:      43229
Client Sample:   BO-23-3
      Method 23 PCDD/PCDF Analysis (a)
                   Analysis File:   T976377
;Irrt€urnat Standards ":' . '.
13C,2-2,3,7,8-TCDF
13C,2-2,3,7,8-TCDD
13Ci2-l,2,3,7,8-PeCDF
!3Ci2-l,2,3,7,8-PeCDD
13Ci2-l,2,3,6,7,8-HxCDF
l3Ci2-l,2,3,6,7,8-HxCDD
13Ci2-l,2,3,4,6,7,8-HpCDF
I3C,2-l,2,3A6,7,8-HpCDD
3Ct2-l,2,3A6,7,8,9-OCDD
Surrogate Standards {Type A)
J7CV2,3,7,8-TCDD
13Ci2-2,3A7,8-PeCDF
13C,2-l,2,3A7,8-HxCDF
13C,2-l,2,3A7,8-HxODD
13Ci2-l,2,3A7,8,9-HpCDF
/Utemate Stafidards ffyjm A) ;
13Ci2-l,2,3,7,8,9-HxODF
'3C,2-2>3A6,7,8-HxCDF
Re«TOry^tendsnls ~V :'
13Ci2-l,2,3,4-TCDD
3Ci2-l,2,3,7,8,9-HxCDD
""X ft ' V ''' "fj "j^A ""
2.6
1.9
1.7
1.7
2.3
3.0
2.6
3.2
6.2
AmM»&
4.0
4.5
4.1
3.5
4.5
V ""v "" \~" \\ f ? -, f
2.8
2.7
- -' '^,\'*-


v3pqi^5
64.4
47.0
43.5
43.3
57.3
73.9
66.2
79.4
77.0
, '• % f?6COV6tl
99.2
111
102
88.7
113
;^;&Bec -"
0.50
0.49
- {- :- Ffertto/"
0.86
170
£ ^f.™ l"Etags:
20:46 	
21:33 	
25:00 	
26:07 	
28:43 	
29:26 	
31:23 	
32:15 	
34:43 	
i-m iw .
21:34 	
25:45 	
28:36 	
29:20 	
32:35 	
.,:"<&' V
-------
 Data Raview 3y:
Initial    	Date... _x
 \!C   a  z>*n
  N)  '—• _J_/	/	  calculated Noise Area:  n/a
 1"h® Total Area for each peak with an ion abundance ratio outside
 ratio limits has been recalculated according  to method requirements.
 Page Ho,
 09/22/97
 Listing of T976377B.db£
 Matched <3C Peaks / Ratio / let. Tims
         QC.Log Omit Why ..ST.  OK Ratio Total-Area... Ar«a,Peak,!,,  Area, Peak. 2..  Rel.RT CoRpound.Hani»,.  ID.. Flags,
TCDP
304-306

















304-306
13C12-TCDP
316-318





316-318
TCDD
320-322




H





0
17:20,
17:49,
18:04 .
18:29,
18:48 •
19:19 •
19:37-
19:53-
20:05 »
20:19 .
20:34,
20:49 •
21:15*
21:29-
21:44'
21:54.
22:38.
DC ' WH 22:55 RO
17 Peaks
0,
DC HL 0:00 RO
EC ML 17:44 RO
20:46
21:29 RO
DC WH 22:22 RO
DC WK 22:43 RO
2 Peaks
0,
DC ML 0:00 RO
18:44-
19:10.
19:31 1
20:16 .
20:34,
21:00«
21:22 •
21:27 '
21:35 •
21:44 •
.65-0.89
0.82
O.iS
0.81
0.83
0,83
0.82
0.83
0.82
0.81
0.84
0.84
0.32
0.81
0.83
D.84
0.84
0,81
1.07

1
1

6
4
3
2
2
1
1
1
5
2
2




39
.65-0.89
3.28
11.09
0.78
0.90
1.48
1.03
«!.,___
65-0,89
1.70
0.74
0.79
0.77
0.75
0.77
0.77
O.S2
0.78
0.81
0.89







,924.37
,146
623
,530
.22
,34
.25
,066.75
.998
.46
.919.24
,621
,461
,694
, SOS
,651
.534
.486
177
IS
129
43
,489

1
1
431
10
.59
.37
.45
.92
.19
.43
.50
.37
.55
.00
.26
.00

.08
.17
.32
,62

$69
525
278
2,958

,65
.30
.78
.93
1,840.67
1.796
1,326
1,133
S52
773
687
2,540
1,137
1,129
81
7
57





188
5.
.33
.73
.69
.04
.56
.80
,57
.68
.89
.15
.08
.86





.61
.38

1,054
620
344
3,571
0.
.72
,92
.56
.32
2,226.08
2,202
1,592
1,437
809
920
821
3,110
1.396
1,356
96
8
71





242
6
.13
.16
.90
.33
.89
.12
.62
.75
.61
.22
.47
.14


0.


,71
.00
0.78



1
441
TCD3
.70
.94
? / 7CC0




826-1.097
0
0
0
0
0
0
0
0
0
0
0
1
1
1
1
1
1
1

.835
.858
,B">0
,»9D
,905
.930
.945
.957
.967
.97S
.990
.002 2378-TCDP AS
.023
.035
.047
.055
.090
.104

952-1.048
0
0
1
1
1
1
.000
.854
.000 13C12-2378-TCBF ISO
.OSS
.077
,094


0.
1.36
712,08
266.14
152.02
420.99

272.
,00
131.71


190.
235.
,01
,48
57.60

49.
71
3O3.
117.
66.
180,
118.
57.
85.
102.
25.
20.
.48
,71
,20
.87
.09
39
S6
83
84
30
408
148
35
240
154
74
104
132
31
29
.60
.43
.82
.12
.00
.32
.15
.65
.76
.41
861-1.056
0
0
0
0
0
0
0
0.
0.
1,
1,
.000
.869
.889
.906
,940
.9S4
.974
,931
,9tS
.002 237B-TCDD AN
.009
Triangle Laboratories, Inc.® Analytical Services Division
801 CapHola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                   Parted: 01:53 09/22/97

-------
 Paga No.
 09/22/97
Listing of T976377B.dbf
Hatched gc Paafcs  f Ratio / Ret.  Time
 M_Z.— QC.I^ig Omit Why . .KT. OK Ratio Total.area..,  Area.Peak. 1.» Ar«a.F«ak,2. ,
                                                                                                S.. Flags.




320-322
37C1-TCD0
328












328
13C12-TCDD
332-334













312-334

P«CDP
340-342







A
H



DC WH
13

DC WL
DC WL
DC WL
DC WL


DC SK
DC SN


DC SN

DC SH
5

DC NL
DC WL
DC WL
DC WL
DC SK
DC SH
DC SH
DC SH
DC SN
DC SH
DC SK



3












21*56
22:10
22:39
22:56
Peaks

18:44
19:04
19:12
19:32
20:05
20:19
20:28
20:36
21:00
21:34
21:50
22:02
23:02
Peaks

0:00
18:33
l»!ll
15:28
19:54
20:08
20:17
20:28
20:40
20:45
21:02
21:21
21:33
21:54
Peaks


22:54
23:13
23:36
23:58
24:07,
24:17
24:31
24:43
24:55
25:OO

-RO
.BO
RO
















0.
RO
RO

RO

RO
RO
RO
RO
RO
RO


RO


1.
-

RO



i
,
.
,
0.73
0.94
0.61
0.42
2





1








1
,65-0.89
2.55
12.72
0.85
2.65
0.88
1.62
3.22
1.84
2.50
f.14
1.82
0.86
0.80
1.61


.32-1.78
1.57 2
1.40
1.16
1.51 1
1.51 6
1.52 1
1.51
1.52 1
1.56
1.55 1
121.36
31.63
26.89
0.60
,667. 62

4.54
35.12
24. 57
0.63
,153.04
2.75
1.30
1.10
2.86
240.70
0.67
96.03
1.17
,495.38

1.68
0.44
2. SB
0,65
2,51
2.00
0.96
2.85
2.07
0.89
2,42
518.04
265.79
5.22
789.05
nnnm /
TwOI/ /
,069.63
45.22
36.51
,372.33
,777,92
,375.96
£48,01
,627.72
336.00
,039.00
53
16
11







1.153
2


2
240

96














239
118
4

.37
.81
.70







.04
.75


.86
.70

.03














.48
.03
.75

67.
17.
19.





























278
147
2

99
37
.17


0.














0.











1.018
1.029
1.051
1.064

907-1.093
0.869
0.885
0.891
0.906
0.932
0.943
0.950
0.9S6
0.974
1.001 37C1-TCDD
1.013
1.022
1.089

907-1.093
0.000
0.865
0.890
0.903
0.923
0.934
0.941
0.950
0.959
0.963
0.97S
.56 0.991 13C12-1234-TC00
.76
.95

1.000 13C12-2378-TCDD
1.016
















SUR1
















RSI
IS1




1.262
26
22
824
4,074
830
389
981
205
631
.89
.37
.19
.87
.47
.27
,4S
.04
.00
.00
SOS
18,
19,
547,
2,703,
545,
258,
646,
131,
4O8,
0.
.74
.85
.09
.45
.45
.69
.55
.68
.00
.00
9O9-1.075
0.916
0.929
0.944
0.959
0.965
0.971
0.981
0.989
0.9S7
I. 000 12378-PeCDF










AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capilola Drive » Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 01:53 09/22/17
                                                               150

-------
 Pag© No.
 09/22/97
Listing °J T976377B.dbf
Hatched se Peaks / Ratio /  Ret. Time
 HJZ. ... QC.Log Omit Why  ..RT. OK Ratio Total. Area.. .  Area. peak. 1. . Area.Peak.2. .  Rel.ET
                                                                                       d. Maine. , ID.. Flags.
340-342
13C12~PeCDF
352-354












352-354
PeCDD
356-333












356-353
13C12-PBCDD
363-370







DC

DC
DC
DC
DC
DC
DC


DC
DC
DC
DC
DC



DC










DC


DC
OC
DC
DC
DC



HH
16

3N
SI!
Sit
ss
SN
SN


SN
SH
SN
SN
SS
2


SN










WH
11

SH
SH
sm
SN
311



25:11
25:19
25:46
25:54
26:13
26:44
26:56
Peaks

12:52
23:16
23i23
23:45
24:07
24:20
25:00
25i45
26:03
26:10
26:17
26:52
27:10
teaks

24:15
24:32
24:44
2S:01
25:09
25:20
25:35
25:49
25:57
26:08
26:16
26:36
27:08
Peaks

24:45
2Si2S
25:39
25:48
25:57
26:07
25:15
26:59
SO
1.
RO

RO
RO
BO
RO


RO
RO
RO
RO
RO

1,
•RO
RO





.
,RO

4
*
RO

1.
RO
RO

KD
RO


RO
1
1
1
1
1
1
0
.56
.54
. 14
.54
.51
.43
.99
725.38
909.39
1,463.69
l,36i.ll
82 .24
117.39
5.15
19, 995. SO
441.62
550.69
836,«
830.86
49.54
69,18
.32-1.78
2
I
3
5
2
0
1
1
44
3
B
4
0

.12
.40
.14
.64
.75
.49
.54
.58
.38
.62
.69
.46
.21

.32-1.78
0
0
1
1
1
1
1
1,
1,
1,
1.
1,
1,

.96
.01
.37
.56
.56
.57
.58
.51
.00
.64
.60
,69
.00

1.99
2.06
O.7»
0.92
3.49
1.07
277.66
31S.OS
1.33
i.3S
1.40
1.38
0.12
SS2.7S

728.20
0.51
72.51
453.80
129.85
307.10
212.95
SB. 41
40.36
128.05
71.24
66.37
0.54
2,301.05


283.76
358.70
S77.27
538. 2S
32.70
48.21
1.
1.
1.
i.
I,
1.
1.
007
013
031 23478-PaCDF AH
036
049
069
077
0.840-1.160


0.
0.
S15
S31
0.935



163.48
192.89







442 . 63

41.88
277 . SS
73.05
187. 7i
13D.40
53.17
24.53
79.52
43.36
41.82


32-1. 78
3.
0.
1.
0.
0.
1.
1.
0.
22
90
46
82
63
65
46
42
0.23
1.84
3.15
1.60
1.22
162,29
16.69
S.65





101.10
9.91
4.04



109.18
122.20






0.
0.
0.
1.
1.
1.
1.
1.
1.
1.

950
965
973
000 13C12-P6CDF 123 IS2
030 13C12-P6CDF 234 SUE2
042
047
051
075
087

0.922-1.025
461.14

30. S3
178.15
50.81
119.34
82.55
35.24
24.45
48.53
27.38
24.75


0.
0.
0,
0.
0.
0,
0.
0.
0.
1.
1.
1.
1.

0.847-





61.19
6.78
9.60
0.
0.
0.
o.
0.
1.
1.
1.
929
939
947
958
9S3
970
980
989
994
001 12373-PeCDD AN
COS
019
039

1.153
948
975
382
988
994
000 13C12-PeCDD 123 IS3
005
033
Triangle Laboratories, Inc.®. Analytical Services Division
801 Capita la Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                Printed: 01:53 09/22/97
                                                                                          151

-------
page No.
OS/22/97
Listing  of T91S311B.dbf
Matched  GC Peaks / Ratio / Ret. Tims
Compound/
M_Z....  QC.tog Omit Why  ..RT. OX Ratio ToEal.Area.. .  Area. Peak. 1. .  Area.Peak.2. . Rel.FT Cojfflpound.Hamo. . ID.. Flags.


368-370
HXCDF
374-376












374-376
13C12-H5CCDF
384-386










384-386
HXCDD
390-392












190-392
1.
DC BL 0:00 RO
27:37-
27s46>
27:55-
28:04-
28:14"
28:36.
23:43-
28:50-
29:02-
29:14,
29:56'
30:00.
12 Peaks
0.
DC ML 0:00 RO
DC SN 27:33 RO
DC SN 27:45 RO
DC SN 28:12 RO
28:36
28:43
DC SH 29:01 RO
29:13
DC SN 29:36
DC SN 29:43 RO
29:55
4 Peaks
1_
DC MIi 0:00 RO
DC SN 27:59
28:09.
DC SH 28:16 RO
DC SH 28:37 EO
DC EH 28:29 RO
2S:37 .
28:50'
28:59 .
DC SN 29:14 RO
29:21,
29s27,
29:43
7 Peaks '
05-1.43
2.
1.
1.
1.
1,
1.
1,
1.
1,
1,
1.
1.
1

72
31
30
.31
.26
.32
.29
.29
,24
.27
.28
.13
.30

4
663
2,722
291
.68
.05
.52
,01
451.79
151
1,530
923
187
436
579
55
118
8,108
.26
.59
.02
,38
,18
.28
.67
.06
.81


375.
1.537.
165.
251.
86.
863.
519.
103.
244.
325.
29.
66.


69
51
05
89
12
58
86
86
24
04
49
82


286
1.185
125
199
65
667
0.954-1.050

.36
.01
.96
,90
.14
.01
403.16
83
191
254
26
51

.43-0.5*
2
3
0
0
0
0
1
0
0
0
.23
.56
.16
.96
.52
.51
.06
.49
.47
.40
0.50

J» !•.*«».
1
0
0
0
2B7
301
3
332
5
2
287
1,209
.03
.24
.21
.80
.59
.75
.49
.49
.16
.75
.82
.65
«* f
,05-1.43
1
1
1
1
2
0
1
1
1
4
1
1
1

.47
.22
.22
.02
.00
,88
.27
.22
.22
.28
.27
.18
.19

1
2
214
0
0
0
527
467
39
0
77
169
197
1,693
.48
.62
.61
.85
.36
.83
.11
.87
.28
.47
.01
.87
.14
.29




98.
101.

110.


96.




00
52

05


52




189
200

222


191
.52
,94
.24
.18
.24

0.




.59
.23

.44


.30
o.ooo
0.962
0.967
0.972
0.977
0.983
0.996 123478-HXCDF
1.000 123678-HXCDF
1.004
1.011
1.018 234678-HXGDF
1.042 123789-HXCDF
1.045

861-1.139
0.000
0.959
0.966
0.982
0.99S 13C12-KXCDF 478
1.000 13C12-HXCDF 678
1.010
1.017 13C12-HXCEF 234
1.031
1.035
1.042 13C12-HXCDF 7S»






AH
AN


AN
AH







SOR3
IS4

ALT2


AIVT1




117.



295.
257.
21.

43.
91.
107.



99



41
26
58

01
81
24



96



232
210
17

34
78
89

0.


.62



.10
.61
.70

.00
.06
.90

951-1,014
0.000
0.951
0.956
0.960
0.967
0.968
0.972
0.980
0.965
0.993
0.997 123478-HxCDD
1.001 123678-HxCDD
1.010 123789-HxCDD












AN
AN
AH

Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 01:53 09/22/97
                                                               152

-------
 ?age No.
 09/22/97
     Listing of  T97S377B.dbf
     Matched EC  Peaks / Ratio / Ret.
                                                       Tir.s
 Compound/
 H_Z....  QC.Log Omic Why . .RT. OK Ratio Total .Area... Area. Peak. 1.. Area.Peak.2.. Rel.RT Compound. Mane. .  ID..  Flags.
13C12-HXCDD
402-404











402-404
HpCDF
408-410





408-410
13C12-HpCDF
418-420




418-420
HpCDD
424-426


424-426
13C12 -HpCDD
436-438


436-438

DC ML 28:00
DC SN 28 : 55
DC SN 29:01
DC SN 29:04
DC SN 29:14
29:20
29:26
29:43
DC SN 29:57
DC SN 30:01
DC SN 30:09
DC SN 30:13
3 Peaks

DC NL 0:00
31:24
31:37
31:44
DC SN 32:16
32:35
4 Peaks

31:23
DC SN 31:42
DC SN 32:06
DC SN 32:20
32:35
2 Peaks

31:39
DC SN 32:00
32:15
2 Peaks

DC SN 31:29
DC SN 31:44
32:15
1 Peak
1
RO
RO
RO
RO
RO



RO
RO
RO
RO

0,
RO



RO


0,

RO
RO
RO


0.

RO


0.
RO
RO
.05-1.43
2
1
0
0
1
1
1
1
1
0
0
0

.62
.62
.80
.54
.02
.22
.15
.20
.02
.81
.86
.56
*V.n. m.
.88-1.20
1
1
1
1
0
1

.78
.04
.08
.07
.20
.17

1
0
0
0
0
242
304
436
1
0
1
1
.19
.29
.22
.34
.89
.61 133.48
.11 162.63
.30 237.74
.88
.76
.84
.77
0.





109.13
141.48
198.56




966-1.034
0
0
0
0
0
0
1
1
1
1
1
1
.951
.982
.986
.988
.993
.997 13C12-HXCDD 478 SOR4
.000 13C12-HXCDD 678 IS5
.010 13C12-HXCDD 789 RS2
.018
.020
.024
.027
983.02

1
765
193
151
0
88
1,199
.18
.76 390.13
.43 100.25
.42 78.10
.51
.58 47.69
.19
.37-0.51
0
0
0
0
0

.42
.71
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Triangle Laboratories, Inc.®  Analytical Services Division
801 Cap Kola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                       Printed: 01:53 09/22/97
                                                                      15

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                DC  SB  32:52     0.91         0.61                              0.947
                Be  SN  33:02 RO  2.4O         0.19                              0,952
                DC  SH  33:30 RO  '0.46         3.82                              0.965
                EC  SN  33:51 DO  0.35         0.32                              0,975
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                        34:51     0,92         38.95         18.71         20.25   1.004 OCDF            SK
                CC  SN  35:44 RO  0.61         0.19                              1.029
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 458-460                34:43 SO  0.73         29.16         13.73         18.89   1.000 OCDD            KS
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                        34:43     0.83        404.55        183.05        221.50   1.000 1SC12-OC0D      138
                BC  MH  34:57 RO  0.55         2.70                              1.007
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 column Description	•  "Why" Code Description	  QC log Besc.
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339.8597 F:2 Exp:EPCUS
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-------
File:T976377 #1-892 Acq:18-SEP-1997  21:16:46 EH- Voltage SIR 70T
339.8597 P:2 ExpiEPCUS
Sample Text:TLI#43229 BO-23-3                        INJ. TIME =
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341.8567 P:2  Exp:EPCUS
Sample Text:TLI#43229 BO-23-3                        INJ. TIME =   21;
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File:T976377 fl-892 Acq:18-SEP-1997  21:16:46  EH- Voltage SIR 70T
409.7974 F:2 ExpjEPCUS
Sample Tejtt:TLIt43229 BO-23-3                        INJ. TIME =   21:
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-------
FiIe:T976377 fl-435 Acq:18-SEp-1997 21:16:46
373.8208 F:3 Exp:EPCUS
 ample Text:TLIt43229 BO-23-3
100%                       2§A36
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File:T976377 fl-435 Acq:18-SEP-1997 21:16:46
375.8178 F:3 Exp:EPCUS
Sample Text:TLIf43229 BO-23-3
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File:T976377 fl-435 Acq: 18-SEP-1997 21:16:46
445.7555 F:3 Exp:EPCUS
Sample Text :TM#43229 BO-23-3
100%                             28; 40
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-------
File:T976377 #1-435  Acq: 18-SEP-1997 21:16:46 EI+ Voltage SIR 70T
373.8208 F:3 Exp:EPCUS
Sample Text:TLItt43229  BO-23-3
100%
       29:12    29:18    29:24    29:30    29:36
File:T976377 #1-435  Acq: 18-SEP-1997 21:16:46 EI+
375.8178 F:3 Exp:EPCUS
Sample Text:TLItt43229  BO-23-3
100%     29:13
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                                                                  21:19 File Text:TLItt43229 BO-»
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File:T976377 #1-435  Acq: 18-SEP-1997 21:16:46 EI+
445.7555 F:3 Exp:EPCUS
Sample Text:TLItt43229  BO-23-3
100%,                       29:26
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-------
File:T976377 #1-390 Acq:18-SEP-1997 21:16:46 fin- Voltage SIR 70f
457.7377 F:4 Exp:EPCUS
Sample Text:TLI#43229 BO-23-3 INJ. TIME = 21:19 File Text :TLI#43229 BO-»
100% A1.31E5 3.7E4
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File:T976377 #1-390 Acq:18-SEP-1997 21:16:46 EI+ Voltage SIR 70T
459.7348 F:4 Exp:EPCUS
Sample Text:TLIt43229 BO-23-3 INJ. TIME = 21:19 File Text:TLI#43229 BO-»
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File:T976377 #1-390 Acq:18-SEP-1997 21:16:46 EI+ Voltage SIR 70T
471.7750 F:4 Exp:EPCUS
Sample Text:TLI#43229 BO-23-3 INJ. TIME = 21:19 File Text:TLI#43229 BO-»
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-------

-------
 TLI Project:      43229
 Client Sample:   BO-23-3
                          Method 23 TCDD/TCDF Analysis (DB-225)
                                               Analysis File:  P973986
 Client Project:    S414003/WAUPACA Foundry
 Sample Matrix:   M23TRAIN        Date Received:  09/12/97
 TLI ID:          183-1-4A-C         Date Extracted:  09/14/97
                                    Date Analyzed:  09/19/97
                                                  Spike File:    SPC2NF04
                                                  ICal:         PF22206
                                                  ConCal:      P973982
 Sample Size:
 Dry Weight:
 GC Column:
1.000
n/a
DB-225
Dilution Factor: n/a
Blank File:     T976373
Analyst:       ML
            % Moisture:  n/a
            % Lipid:     n/a
            % Solids:    n/a
2,3,7,8-TCDF
             11.2
                                 0.76
                      20:32
 13C,2-2,3,7,8-TCDF
              1.9
          46.3
40%-130%
0.76
20:31
13C,2-1,2,3,4-TCDD
                                                   0.82
                                         19:33
                      Data Reviewer.
                                          Page 1 of 1
                                              09/22/97
                                                            C2SPJKR vl.00. LARS S.10.M
Triangle Laboratories, Inc.*
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 * Fax: (919) 544-5491
                                                        Printed: 02:1009/22/§7
                                                    174

-------
                       Initial
 Data Review Bys
 The Total Area for each peak with an ion abundance racio outside
 raeio limits has  been recalculated according to method requirements.
 Page ISfo.
 09/22/97
Listing of P973986B.db£
Matched GC Peaks / Ratio / Ret. Time
 Compound/
 M_S,,,. QC.Log Omit why , *RT. OK Satio Total .Area.,. Area. Peak. a.. Area. Peak. 2.. Rel.BT Confound, Same..  ID..  Flags.
TCDF
304-305 DC ML 0:00
16:20
16i35
16:42
16:52
17:15
17:22
17:29
17:39
17:55
18:03
18:11
18i21
18 1 27
13:30
18:41
18:50
19:07
19:16
19:31
19:42
19:54
20:03
20:15
20:26
20:32
20:43
20:56
21:04
21:14
DC SN 21tl»
21:42
22:19
DC WH 22:42
304-306 31 Peaks
13C12-TCDF
316-318 DC NL 0:00
DC Mb 18:30
DC HL 19:18
19:37
19:50
20:31
0.
RO
RO
RO
RO
RO









65-0.89
1.
0,
0.
1.
0.
0.
0.
0.
0.
0.
0.
0,
0.
0.
.20
.99
.47
.06
.48
75
,79
.73
,74
.74
.75
,75
,75
,78
0.77

RQ






RO





RO



RO

0.
RO
RO
RO
RO
RO

0.
J_
0,
0,
0,
0,
0,
0,
0,
0,
0,
0,
0
0,
0,
0,
0.
0,
1,

,70
,17
.72
.77
.75
.75
.71
.76
.48
.76
.76
.74
.75
.73
.93
,65
.76
.77
.03

2
106
13
19
71
4,565
2,776
3,635
.53
.87
.68
.61
.29
.43
.78
.89
2,690.75
1,931
2,878
1,204
6,253
834
879
3
.41
.49
.95
.08
.34
.12
.76
4,076.22
96
3,071
2,617
2,721
330
2.377
17
1,975
2,049
1,543
2.022
3.B21
28
1
3,020
171
3
57,907
.97
. »6
.11
.Si
.06
.04
.61
.20
.47
.18
.56
.31
.11
.29
.54
.39
.91
.25





2
1
1
1

1

2



2

1
1
1

1





1


1




59,
5.
11.
31.
,004.
.226.
,531.
,146.
819,
,232.
517.
,687.
359.
381.
j :
,698,
40,
,335.
,121,
,IS6.
137,
.025,
7,
830.
888,
657,
867.
,617.
14.

.302.
74.



68
95
30
01
07
65
85
67
.51
.87
.47
.39
.80
.36
.55
,62
.44
.13
.59
.78
.14
.32
,66
.00
,18
,55
.15
.50
.84

95
48



60.
12.
11.
64.
3, 662.
1,550.
2,104.
1,544.
1,111.
1,645.
687.
3,565.
475.
497.
2.
2,302.
56.
0.786-1.095

33
,67
.08
.43
36
.13
04
,08
.90
62
,48
19
04
.76
.21
,95
,53
1,736.83
1,495.
1,554,
192,
1,351,
16,
1,125,
1,161,
885,
1,155,
2,203,
IS,

1.717.
96.


65-0.89
2.
0.
0,
1.
0.
0.
.06
,43
,56
,03
.39
.76
3
5
8
4
9
706
.10
.63
.94
.25
.45
.72









2.
4.
304.



46
11
10



2.
.53
.80
.92
.72
.64
.20
,29
.63
.41
,81
,38

,59
,91


0.000
0.796
0.308
0.814
0.822
0.841
0.846
O.SS2
0.860
0,873
0.880
0.186
0.894
0.899
0.902
0.911
0.918
0.932
0.939
0.951
0.960
0.970
0.977
0.9S7
0,996
1.001 2378-TCDF
1.010
1.020
1.027
1,035
1.039
1.058
1.088
1.106

0.951-1.049



.40
10.64
402.
62
0.000
0.902
0.939
0.956
0.967
1.000 13C12-237!
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive* Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                             i?;
                                                                   Printed: 02:11 09/22/97

-------
  ?age  No.     2           Listing o£ P973986B.dbf
  09/22/97                 Matched GC Peaks / Ratio /  Ret.  Time

  Compound/
  M_Z,,.. QC.tog Omit why .,RT, OK Ratio Total.Area...  teea.Peak.l.. Area. Peak. 2. .  Rel.RT compound. Name..  10..  Flags.

  316-318               3 Peaks                 720.42

                	Above; TCDF /  TCDB Follows	
  13C12-TCOD                     0.65-0.89                                     0.897-1.103
  332-334         DC  KL   0:00 RO  2.01          1.50                              0.000
                         19:21     0.77        549.74        238.45        311.29  1.000 13C12-2378-TCDD IS1
                         19:33     0.32      1,099.78        495.78        604.00  1.010 13C12-1234-TCDD RSI
                 DC  WH  21:32 RO  0.51          0.90                              1.113
  332-334               2 Peaks               1,649.52
 Coluijn Description	  "Why* Code Description.........  QC Log Desc.
 !5_2   -Nominal Ion Hassles)      s&*-Below Retention Time Window   A-peak Added
  . .RT. -Retention Time (mssss)   WH-Above Reteutioa Time Window   K-PsaJc Kept
 Rat. 1--Ratio of H/M+2 Ions      SH-Belo» Signal  to Soise Level   D-PeaJc Deleted
 OK    -HO»Ratio Outside Limits  
-------
               17:00         18:00         19:00          20:00         21:00
File:P973986  #1-75* Aoj:19-SEP-1997 22:03:00 EI+ Voltage SIS  70S So±se:714
305.8987 BSOB(256,30,-3.0) PKU( 5, 3,1, 0.101, 2956. 0, O.DO%,f, F)  Ezp:DB225
TRIANGLE LABS  Text:SO-23-3 TZIM3229
File:f973935  #1-754 Acq:19-SEP-1997 23:03:00 EI+ Voltage SIR  70f Noise: Ob (J
303.3016 BSnS(2S6,30,-3.0) PXD(5, 3,1, 0.10\, 3440. 0, 0.00%,f, F)  ExpiDB225
TRIANGLE LABS  Text:BO-23-3 TLIV43229
100S
  ao:
                                                                                       22: 00
100S
  ao:
  so:
  40:
  20.
A2.66E7
                                 A3.S7E7
                       A2.30E7
                                                       A2.20E7
                                A1.50E7  .  ,.__
                             A1.74E3»    A1.35E7
                                              A1.13E7
                                                                Al. 72E7
               17:00         18:00         19:00          20:00
T±lesf973986  tl-754 Aoqil9-SEP-1997 22:03:00 SH- Voltage SIS 70P Noiaes
315.9419 BSOB(256,30,-3.0) PKD(5, 3, 1,0. 101,7200. 0,0.00*,?,?) Ex?:DB225
TRIANGLE LABS  Text:BO-23-3 TLI943229
100*                                                            A3.04ES
  ao:

  601

  40.

  20:
                                                                        21:00
               17:00         18:00         19:00          20:00         21:00
file:P973986  #1-754 Acq:19-SEP-1997 22:03:00 £H- Voltage SIR 70P Noise:874
317.93B9 BSnB(256,30,-3.0)  PSS(5,3,1, 0.10\,3496. 0, 0. 00*,P,F) Exp:DB225
TRIANGLE LABS  Text:BO-23-3 TLIH3229
                                                                A4.03E6
 801
 601
 401
 201
                                                                                       22: 00
              17:00          18:00         19:00         20:00
file:P97398S tl-754 Acq:19-SEP-1997 22:03:00 JSI+ Voltage SIR 70S
375.B364 Exp:DB225
TRIANGLE LABS  Tsit:SO-23-3  TLH43229
100*                                             19 23
                                                                                       22: 00
.7.1ES

.5.7ES

.4.3ES

.2.9ES

.1. 4E6

.O.OEO
    line



.B.5E5

.6.BE5

.5. IBS

.3.4E5

.1. 7E5

.O.OEO
    Tine



.LIES

.8.9E5

.6.7S5

.4.5E5

.2.2S5

.O.OEO
    Tine
              17:00
                                           19:00
                                                         20:00
                                                                        21:00
                                                                                       22:00
                                                                                    177

-------
 elletPS73SffS	#1-734 AcqilS-SEP-1997 22,03,06 EI+ voltage SIR 70P noise: 1447
 319.9965 SStn(2SS,30,-3.0} tKD(3,3,l,0,10l,57Ba.O,0.001eF,F) Exp,DB225
 OtXUIGLE LUBS  XextsBO-23-3 TLI443229
 100*
  901
  sol
401

301

 fl.
                                               A2.S7ES
JL
                                           .
                                                          A9.98JS5
   17:00             18:00             19:00            20:00             21:00
 File:f9739aS #1-754  Acy:19-SEP-1997 22:03:00 EH-  Voltage SIS 70P Noiae,1243
 321.8936  BSm(256,30,-3.0)  fXD(S,3,1,0.101,4973.0,0.00\,F,F) Elf:DB225
 TtllOKLS  MBS  Iextl.BO-2.J-J TLXt43229
 100A
  801
  601
  40.
  201
             R3.20E6
                         A2.49E6
                                               A3.73SS
                                       A
                                          A
                                                         JW.
   17:00            18:00             13:00             20:00            21:00
file:P973986 #1-754 Acq:19-SSP-1997  22:03:00 SI+ Voltage SIS  70? Oa±eeil097
327.8847 SStm(256, 30, -3. 0) PKD( S, 3,1, 0.101,4388,0, 0.00*, F,f)  ExptDB225
     (ISLE LABS TeixtiBO-23-3 ILH43229
1003,
   17:00            18:00            19:00            2fliOO             21100
 'ile:P973986 (1-754 AcqilS-SEP-1997 22:03100 El* Voltage Sim 70f Noise: 856
331.9368 BSUB(25S,30r-3.0) fKD(S, 3,1, 0.10%, 3424 .0, 0.00%, f,f) SxpsDB22S
   7UICEE LASS  TfSXtlBO-23-3 TLH43229
1003,                                          A4.?6E6
 so:
 40:
 201
   17:00            18:00            19:00            20,OO             21-00
file:P97398S At-754 &cqil9-Sm<-1997 22:03:00 SXf- Voltage SIM 70S Wlises425
 '33.9338 SSV3(2S6,30,-3.0) SKD(S,3rl,0.m,170t.O,a.aai,r,r) SxpsDS23S
TSIAHGLE LAMS  TfUCtlBO-23-3 XLI#43229
1003i                                         A6.04E6
                                          A3.11X1
                                                         _1. 7ES

                                                          .1.3ES

                                                          '.1. OES

                                                          '.S.7E5

                                                          -3.4E5
                                                                                                -O.OEO
                                                                                          22'100     Tim
                                                                                               2.2E6

                                                                                              il.7Ef

                                                                                              -1.3ES

                                                                                              '.B.7E5

                                                                                              14.4E5
                                                                                         22:00
                                                                                                .O.OSO
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Al , 7QS7 U
1
. . 11 « _ "All
Ai.esss
                                                                                              .S.OES

                                                                                              '.3.7S6

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                                                                                              '.1.2E6

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                                                                                                 Tim,



                                                                                             r!.4E6

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                                                                                              '.S.SES
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                                     19:00
                                                      20:00
                                                                        21sOO
                                                                                         22»00
                                                                                               .O.OEO
                                                                                                   Tint
                                                                                   170

-------
File:P973986  #1-754 Acq:19-SEP-1997 22:03:00 EI+ Voltage SIX 70P
303.9016 Exp,BB225
TRIANGLE LABS Text.-BO-2.3-J TLI#43229
                  17:15           1*
              17:00          18:00         19:00         20:00
F±le:P973986 tl-754 Acq:19-SEP-1997  22:03:00 EI+  Voltage SIS 70P
315.9419 ElpiD3225
TRIANGLE LASS  Text:BO-23-3  TLI#43229
1004                                                             20fJl

 eol
 eol
 40!
 201
                                                                        21:00
                                                                                      22: 00
              17:00          18:00         19:00         20:00
rile:P973986 tl-754 Acq:19-SEP-1997 22:03:00 Elf- Voltage SIB 70P
319.B965 Exp:DB225
TRIANGLE LABS  Tsxt:BO-23-3  ILJ443229
100*            17,07

  80:

  sol

  401

  201

   ol
                                                                        211 00
                                                                                      22:00
                        17:39
                                 18:18
                                                   19:36
                                                             2011.4
                                                                      20:53
              17:00          18x00         15-00         20:00
r±le:P97393e #1-754 Acq: 19-SEP-1997 22:03:00 EH- Voltage SIS 70P
331.936S Erp.-2B.225
TRIANGLE LABS  Text:BO-23-3  TLIM3229
100*                                               19:33
                                                                                      22:00
 80:
 50:
 401
 20:

   o:
                                                19!21\\
              17:00          ISiOO         19:00         20:00
T±le:P97393S tl-754 Acq:19-SEP-1997  22:03:00 ZI+  Voltage SIS 70S
292.9B25 EzpsDB225
XSIANGZE LABS  Text:BO-23-3  TU:t43229
                                                                                      221 00
              17:00          18,00         19,00         20-00          21:00
Zile:P973916 tl-754 Acqsl9-SEP-1997 22:03:00 EI+ Voltage SIS  TOP
330.9792 Elp:D3225
TRIANGLE LABS  Text:BO-23-3 TLH43229
           16,47  17,1717:42       ,   .jaiS119.:16        ^20,1320:36  21:04
                                                                                      22,00
              17:00
                             18:00
                                           19:00
                                                         20:00
                                                                        21:00
                                                                                      22:00
                                                                                                      8.6E5

                                                                                                     :S.9E5

                                                                                                     :5.1E5

                                                                                                     '-3.4E5

                                                                                                     Ll. 7ES
                                                                                                    t.O.OEO
                                                                                                         Tijae
.1.3E6

'.1.0E6

.6. 7E5

•.3.4E5
                                                                                                      O.OEO
                                                                                                        Time
 1.4ES

.1.1E6

'.8.4E5

'.5.6E5

.2.8E5
                                                                                                    •.O.OEO
                                                                                                        Time
                                                                                     179

-------
Re?, ias             hit top
Height  EJvotts  Sp  318p
Systaa file nae
Data   file nas
Resddlon
Icnliatlon aode
Switching
Ref. lasses
fl
D  315,9413
E  317,3389
H  327,88*7
I  338,9792
                        DB225
                           1
                          H+
                      VOLM
J


fl  mm
        I  338.97S    Me top
       Uvoltf  Span  296 fp*
                                                 1 an

-------

-------
 TLI Project:       43229
 Client Sample:    FB2-23
                       Method 23 PCDD/PCDF Analysis (a)
                                     Analysis File:   T976378
Client Project:
Sample Matrix:
TLI ID:
Sample Size:
Dry Weight:
GC Column:
S414.003/WAUPACA Foundry
M23TRAIN Date Received:
183-1-5A-C Date Extracted:
Date Analyzed:
1.000
n/a
DB-5
Dilution Factor:
Blank File:
Analyst:
09/12/97
09/14/97
09/18/97
n/a
T976373
KAS
Spike File:
ICal:
ConCal:
% Moisture:
% Lipid:
% Solids:
SPX23704
TFS3286
T976372
n/a
n/a
n/a
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD

2,3,7,8-TCDF
1,2,3,7,8-PeCDF
23,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7J-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF
 ND
 ND
 ND
 ND
 ND
EMPC
EMPC

 ND
 ND
 ND
EMPC
  0,04
 ND
 ND
EMPC
 ND
 ND
0.01
0.02
0.02
0.02
0.02
0.01
0.02
0.02
0.02
0.02

0.03
0.03
           0.02
           0.02
           0.09
0.05
                           129
                         28:44
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD

Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
 ND
 0.05
 0.12
 0,04

 ND
 022
 0.23
EMPC
    0.01
    0.01
           0.06
           0.35
           0.05
                                             Page 1 of 2
                                                                                   XZttJSR »2.00. LARS 6.10.SM
Triangle Laboratories, Inc.®
801 Capitola Drive « Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                               Printed: 16:55 09/22/97
                                              181

-------
TLI Project:
Client Sample:
43229
FB2-23
      Method 23 PCDD/PCDF Analysis (a)
                     Analysis File:   T976378
I3Cw-2,3,7,8-TCDF
13Cu-2,3,7,8-TCDD
13Ci2-l,2,3,7,8-PeCDF
13C,2-l,2j,7,8-PeCDD
l3e12-l,2,3,6,7,8-HxCDF
"Cl2-l,2,3,6,7,8-HxCDD
13C!2-l,2,3,4,6,7,8-HpCDF
"Ci2-l,2,3,4,6,7,8-HpCDD
»Ci2-l,2,3,4,6,7,8,9-OCDD
             2.1
             22
             1.8
             1.9
             2.9
             3.4
             2.3
             2.8
             5.4
 53.6
 56.0
 44.1
 47.4
 72.2
 86.0
 58.1
 68.8
 67.4
40%-130%
40%-130%
40%-13Q%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
0.78
0.78
1.56
1.56
0.51
1.20
0.42
1.05
0.85
20:46
21:34
25:01
26:08
28:44
29:26
31:24
32:15
34:44
"Cl,-2,3,7,8-TCDD
"C,r2,3,4,7,8-PeCDF
13Cirl,2,3,4,7,8-HxCDF
IJC12-l,2,3,4,7,8-HxCDD
»C,2-l,2,3,4,7,8,9-HpCDF
             3.8
             4.3
             3.8
             3.3
             4.0
 94.3
106
 94.1
 81.7
101
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%
1.46
0.51
1.16
0.41
21:36
25:46
28:37
29:21
32:36
I3Ci2-l,2,3,7,8,9-HxCDF
DC,r2,3A6,7,8-HxCDF
"Ci2-l,2,3,4-TCDD
13Ci2-l,2,3,7,S,9-HxCDD
                                                      0.86
                                                      1.23
                                   21:22
                                   29:44
                         Data Reviewer:,
                          Srt.
                     09/22/97
                                                                                       X137.PS1 »2.00, LARS «10 04
Triangle Laboratories, Inc.®
801 Capitola Drive « Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                             Printed: 16:55 09/22/97
                                                                             182

-------
                        Initial
                                  . . . -Date. , .

                                   7 _/ 2-
                                             Calculated Noise Area:   0,62
 The Total Area lor «ach peaJc wich an ion abundance ratio outside
 ratio limits has  be«n recalculated according to method requirements.
 Page No.
 09/22/97
Listing  of T976378B.db£
Matched  GC Peaks /  Ratio / Set.  Time
 Compound/
 M_Z	QC.Log OmiC Why . ,RT.  OK Ratio Total.Area— Area.Feak.l., Area.Peak.2.,  lei.8T Compound.Mama,. 10.. Flags.
TCDP
304-306 D

D
D
D
D
D
D
D
D
304-306
13C12-TCDF
316-318




31S-318
TCDD
320-322



320-322
37C1-TCDD
328













DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC
DC
DC
DC



DC
DC
DC
DC


SN
SB
SH
SH
SH
SN
SH
SN
SN
SH
0

WL
ML
Wi
ML

1

sw
SH
SH
SH
0

17:51
18:07
18:50
19:20
19:39
20:02
20:35
21slS
21:30
22:40
Peaks

18:44
19:02
19:15
19:39
20:4S
Peak

20:26
20:43
22:18
22:47
Peaks
0.
RO
SO
RO
HO
RO
RO

EO
EO
RO

0.
RO
RO
RO
RO


0.


ao
RO

.65-0.8*
0
0
1
1
1
0,
0.
0
0,
1.

.58
.52
.18
.06
.38
.48
.68
.48
.63
,27

3
1
4
7
6
2
4
6
10
1
0
.31
.52
.51
.01
.74
.90
.05
.37
.44
.58
.00
S5-0.89
4,
1.
4,
0.
0.

.56
.45
,00
.63
,78

65-0.89
0.
0,
2,
.89
,83
.11
0.24


0
0
0
1
414
.28
.67
.37
.20
.99 131.85
0.825-1.097
0
0
0
0
0
0
0
1
1.
1

.860
.872
.907
.331
.946
.965
.991
.024
.035
.091

0.952-1.048
0,
0
0
0,
233.14 1,
.902
.917
.927
.945
,000 13C12-2378-TCDV ISO
414.99

0
0
0
D
0
.34
.22
-IS
.30
.00
0.851-1.056
0.
0.
1.
1.

947
961
.034
056

0,907-1,093
DC
DC
DC

DC
DC
DC
DC
DC

DC

DC
HL
WL
SN

SH
SH
SN
SH
SN

SN

SN
19:07
19:21
19:47
20:06
20:19
20:44
21:09
21:10
21:20
31:36
21:54
22:03
22:11




































0
0
0
3
0
0
0
0
0
315
0
0
,3i
.11
.23
.35 3.35
.28
.16
.22
.25
.24
.44 315.44
.61
.87 0.87
0.7S
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
1.
1.
1.
886
897
917
932
942
9«1
981
981
989
002 37C1-TCDD SDR1
015
022
029
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 « Fax: (919) 544-5491
                                                                  Printed: 16:56 09/22/97
                                                             183

-------
 Page No *
 09/22/97
Listing o£ T9'6378B.dbf
Hatched OC Peaks / Ratio /  Ret, Time
 H_Z.... QC.Log Oraie Why ..ST. OK gaeio Total.Area	Jttea.Peak. 1, . Area. Peak. 2. . S»l. 8T Compound.Name. . ID.. Flags.
328
13C12-TCDB
332-334















332-334
feCDF
340-342 D


D
D
D
D
0
D
0


340-342
13C12-PBCDF
352-354







3S2-354
DC
DC
EC

DC
DC
DC
DC


DC

OC
DC



EC




DC
DC

DC
DC
DC
DC
DC
DC
OC
DC
DC







DC
DC
DC

ss
SN
SN
4

HL
Wt,
ML
WL


SN

SN
SH



SN


8

SN
SN

SN
SN
3N

SN
SN
SK
S3
HH
1






SN
SN
SN
5
22 1 17
22:24
22:45
23:01
Peaks

0:00
IS! 44
19:23
19:25
!Si54
20:03
20:1S
20:25
20:50
21:01
21:22
21:34
21:58
22:13
22:32
22:38
Peaks

22 1 56
23:34
24s 07
24:13
24:33
24:44
25:01
25:13
25:20
2S:B4
26:54
27:09
Peak

24:07
24:39
25:01
25.-17
25:46
26:10
26:45
26:59
feaks
0.79 0.79
3.32
0.47
0.17
320.45
0.
RO
RO
RO
RO
RO

RO
RO
RO
SO


RO
RO
RO
RO

1.
RO


RO
EO
RO
1O
RO
RO
ID
RO
RO

1.

RO

RO

EO
RO
RO

65-0.89
2
7
1
14
1
0
7
1
1
3
0
a
i
5
I
4

.51
.16
.76
.63
.38
.74
.37
.07
.42
.12
.86
.78
.10
.12
.48
.48

.32-1.78
1
1
1
1
.17
,75
.41
.02
0.53
1
2
0
2
1
0
0

.11
.66
.95
.39
.83
.74
.22

1
0
1
0
1
1
.22
.80
.10
.34
.70 1.32
.90 0,81
1.35
1
1
I
599
366
7
0
2
1
.66 1.01
.OS
.03
.39 276.44
.37 161.02
.52 4.68
.92
.02 1 . 69
,61 4.08
1.
1.
1.
1.
033
039
055
067

0.907-1.093
0.
0.
0,
0.
0.96 0.
1.09 0.
0,
0.94 0.
0.
0.
322.95 0.
205.35 1,
4. 25 1.
1,
1.14 1,
0.91 1.
000
.869
.899
.900
.923
.930
940
947
,966
.974
.991 13C12-1234-TCDD
.000 13C12-2378-TCDD
.019
.030
.045
.049










RSI
IS1




982.17

5
0
20
2
1
S
4
.86
.33
.OC 11.73
.42
.37
.56
.39
2.71
3
7
0
0
20
.57
.78
.38
.20
.06
32-1.78
1
1
1
1
1
2
2
0

.45
.15
.56
.03
.46
.41
.90
.97

2
1
325
2
3S2
0
1
a
685
.84 1.68
.51 0.92
.94 198.75
.35 1.43
.94 209,54
.43
.02
.59
.38
0.909-1.075
0.917
0.942
8.33 0.
0.
0,
0.
1.
1.
1.
1,
1.
1.

.964
.971
981
989
000 12378-PeCOF
,008
.013
.035
.075
.085





AH






0.840-1.160
1.16 0.
0.80 O.
127.19 1.
1.39 1,
143.40 1.
1.
1.
1.

.964
.965
000 13C12-P6CBP 123
Oil
,030 13C12-PeCDF 234
,046
069
079



IS2

SUR2




Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 * Fax: (919) 544-5491
                                                                 Printed: 16:56 09/22/97

                                                             184

-------
  Page He.
  09/22,'r"
Listing of T97S37SB.dM
Matched OC Peaks / Ratio /  Ret. Tina
  M_2,... QC.Lag Omit Why .,RT.  OK Ratio Total-Area... Area.Peak. 1.. Area. Peak. 2 ..  Rel.RT Compound, Name. . ID.. Flags,
  369-370
  368-370
 HxCDF
 374-376
 374-376
 13C12-KXCDF
 334-386


DC
DC
DC
DC
DC



SH
SH
sa
SH
SH
1

24:16
24:46
25:21
25:39
25:57
26:08
Peak
1

RO

RO
RO
RO

~— — — — *wuv0: feujjo: / jr«*-ui* r«iivi*e* — — "
.32-1.78
1
0
1
1,
.44
.70
.44
.80
8.92
2.

,40

3
0
1
1
0
0
3
.25 1.92
.46
.34
.15
.31
.77
.25
1.32-1.78
DC


DC


DC


EC

DC
DC


DC
d
d
DC
DC
DC
DC


DC


DC
DC


DC
DC
DC
DC

ss


SN
2

KL


SH

SN
SN


SN
SH
SN
SH
SN
SN
SN
5

SM


SN
SH


SN
SH
SH
SN

24:37
2S:OS
26:17
26:30
Peaks

0:00
27:38
27:47
27:57
28:06
28:14
28:31
28:37
28:44
28:51
29:01
29:14
29:42
29:47
29:56
30:01
Peaks

27:46
28:37
28:44
28:57
29:01
29:14
29:20
29:27
2St27
29:34
29:44
29:57
RO

RO
RO

1.
RO


ao
RO
RO
RO
RO

RO
RO
RO
RO
RO
RO
RO

0.
RO


RO
RO

RO
RO
RO
RO
RO

0.79
1.
.56
1.19
0.88


.05-1.43
0.77
1.
1.
0.
1.
41
20
51
03
1.83
1.
1.
1.
2.
0.
1.
0.
0.
1.
1.

43-
0.
0.
0,
0.
0.
0.
0.
0.
0.
0.
0.
o.
67
84
29
37
99
61
43
96
84
89

0.59
34
51
51
20
65
52
73
37
41
23
25
49
0
205
18
0
.13
.72 125.47
.44 11.21
,81
0.
1.33






0.
922-1.025
0
0
0,
0.
0.
1.

.929
.948
.970
,»82
,993
.000 12378-PeCDD






AD

847-1.153
O.J42
80.25
9.42
1.000 13C12-P8CDD 123
1.
006
I S3

1.014
224. IS

0
4
14
1
2
0
,49
.84 2.83
.19 7.73
.07
.94 1.63
.90
0.
956-1.050
0.000
2,01
6.46
0.
0,
962
967


0.973
1.S8

0.47
8
5
1
1
4
0
0
0
0
38

0
3ia
362
0
,98 7.37
.37 3.03
.16
.81
.39
.11
.45
.56
.SO
.32

.98
.30 107.22
.47 121.67
.38
4.01
2.34








0.

211.08
240 . SO

0.77
348.07 119.23
2.67 1.30
1.
} ,
.30
,30
228.84
1.77


0.95
0,
.44
264.37 87.11

177.26
0.
0.
978
983


0.992
0.
1.
1.
1,
1.
1.
t.
1.
1.

8S1-
0,
0,
1.
1.
1.
1.
1.
1.
1.
1.
1.
1.
996 123478-H3CCW
000 123678-H5CCDF
004
010
017 234678-HXCDF
034
037
042 123789 -HxCDF
045

1.139
966
996 13C12-HXCEF 478
000 11C12-HJCCDF 678
008
010
017 13C12-HXCDF 234
021
025
025
029
035
042 13C12-HXCBF 789
AH
AH


Ail


AH




SDR3
IS4


ALT2





ALT1
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 * Fax: (919) 544-5491
                                                                  Printed: 16:56 09/22/97
                                                                                     185

-------
 Page Ho.
 09/22/97
Listing of T9763"?8B-dbf
Matched GC Peaks / Ratio /  Ret, Time
 M_s..., QC.Log  Omit :,«hy . .RT. OK Ratio Total .Area. .. Area. Peak, l, ,  Area. PeaK. 2..  Rel.RT compound. Kame. .  113,. Flags.
DC SM 3O.14
DC SM 30:24

384-386
HxCDD
390-392






DC SN 30
:2S
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Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive» Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 16:56 09/22/S7
                                                                                   186

-------
  Pa^s So.
  09/22/97
                         Listing of M?6378B.abf
                         Matched GC Peaks / Ratio  /  Ret. Tin
  Coirfpound/
  M_Z,.,.  QC.Log Omit  Why . .RT.  OK Ratio Total.Area... Area. Peak. 1..  Area.Peak,2..  Rel.ET Compound. Maine.. 1C.. Flags.
  HpCDD
  424-42S
          MK
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                        31i39     0.89
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1.02
2.97
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                                                               0.52
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436-438         DC  SH  31:40 RO  0.13          0.16
                        32:15     l.OS         220.07
436-438               1 Peak                  220.07
                                                             112.82
                                                                               0.969-1.031
                                                                                   0.982
                                                                           107.25   1.000  13C12-HPCDD 67S 1ST
                                       Above: HpCDD / Oeta-CDD and COP Follows
  OCBP
  442-444
                               0.76-1.02
                DC  SH  31:39     0.88
                DC  SH  32:47 RO  0.75
                DC  SN  33:29 RO  1.64
                DC  SH  34:48     0.94
                      0 Peaks
                                                 0.30
                                                 0.19
                                                 0.21
                                                 0.64
                                                 0.00
                             0.883-1.115
                                 O.S11
                                 0.944
                                 0.964
                                 1.002 OCDF
  OCDD
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  458-460
                               0.76-1.02
                        34:45 RO  0.41
                      1  Peak
0.83
0.83
              0.39
                             0.385-1.115
                           0.94  1.000 OCOD
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  470-472
                               0.76-1.02
                        34:44     0.8S        337.30
                      1  Peak                 337.30
            15S.26
                             0.995-1.004
                         182.04  1.000 13C12-OCDD
                                                       158
 Column  Description.	  "Why Code Description.	   QC Log Desc.
 M_JZ   -Hominal Ion Hass(es)
  ..ST. -Retention Time  (ismjss)
 Rat.l -Ratio of M/M+2 Ions
 OK    -RO=Ratio Outside Limit*
                               WL-Below Retention Time Window
                               S^H-^bove Hetention Time Vlindow
                               SK-Below signal to Noise Level
                               
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53 35:25
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1 " * | j— 1« IT J i f "T- f "-"j""""!1- 	 -*f» 1 — f i niri-\111 »p- 	 j«"— iiiim*|..i -| 	
12 . 4E3
I.1.8E3
L1.2E3
L6.0E2
: O.OEO
35:00 35:12 35:24 35:36 Time
EI+ Voltage SIR 70T






\
\ 	
' 1 ' "
34:48

INJ, TIME = 21:59 File Text :TtI#43229 FB2»
4.8E5





i~ 	 "i J«««--|~™-,T-T- -| f,,,,n,, ....^J-IMJI.,.,.. | 	 j,™., — j — j_™>j — .— [ — ^p — rT" 	 ""i "•"•"|"™r-"" 	 t'"™*
_3.9E5
_2.9E5
_1.9E5
_9.7E4
0,010
35:00 35:12 35:24 35:36 Time

-------
File:T976378 fl-390 Acq:18-SEP-1997 21:56:23 EI+ Voltage SIR 70T
457.7377 F:4 Exp:EPCUS
Sample Text:TLI#43229 FB2-23                        INJ. TIME =   21;
100%
                                                                    59  File  Text :TLItt43229  FB2»
                                                                                       _2.3E3
      34iOO     34il2     34:24     34:36    34i48    35iOO     35il2
File:T976378 #1-390 Acq:18-SEP-1997 21:56:23 EI+ Voltage SIR 70T
459.7348 F:4 Exp:EPCUS
                                                                  21:
                                                                        35 24
                                                                                35 : 36
                          -O.OEO
                              Time
Sample Text :TLI#43229 FB2-23
                                                   INJ.  TIME =
       59 File Text:TLI#43229 FB2»
                          _3.0E3
                                                                       35:24
                                                                                  35:36
                           O.OEO
                              Time
      34:00     34:12     34:24     34:36    34:48     35:00     35:12
File:T976378 fl-390 Acq:18-SEP-1997 21:56:23 EI+ Voltage SIR 70T
469.7779 F:4 Exp:EPCUS
Sample Text:TLI#43229 FB2-23                        INJ. TIME =   21:59 File Text:TLI#43229 FB2»
1001                                     34:44
60 j
     34 fob
                34:12
34:24
— -I ................. i ................. |
 34:36
34:48
                                                      35:00
r ••" i ........ r • .......... ^ ..............
 35:12
—,—!—,—,_
 35:24
	j	_	^	

 35:36
13.9E5

L2.9E5

L1.9E5

L.9.7E4

LO.OEO
    Time

-------

-------
 TLI Project:     43229
 Client Sample:   Trip Blank
Method 23 PCDD/PGDF Analysis (a)
            Analysis File:   1976379
Client Project: S414.003/WAUPACA Foundry
Sample Matrix: M23TRAIN Date Received: 09/12/97 Spike File: SPX23704
TLIID: 183-1-6A-D Date Extracted: 09/14/97 KM: Tf 53286
Date Analyzed: 09/18/97 ConCal: T976372
Sample Size: 1.000
Dry Weight: n/a
GC Column: DB-5
Dilution Factor: n/a % Moisture: n/a
Blank File: T976373 %lipid: n/a
Analyse KAS % Solids: n/a


2,3,7,8-TO)D
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
15,3,4,7,8-HxCDF
lA3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
lA3,7,8,9-lxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,6,7,8,9-OCDF

Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF

ND 0.03 	
EMPC 0.04 	
ND 0,03 	
ND 0.03 	
ND 0.03 	
0.04 1.18 32:15 	
ND 0,05 	
EMPC 0.28 	
EMPC 0.10 	
0.17 1.53 25:46 	
0.16 , 1.10 28:36 	
0,07 1.41 28:43 	
EMPC 0.05
ND 0.03 	
0,07 1.10 31:24 	
ND 0.04
ND 0.04 	

ND 0.03
EMPC 020 	
0.13 2 	
0.04 1 0.06 	
1.1 7 1.6
1,4 7 1.9
0,63 7 0.69
0.07 1
                                       Page 1 of2
                                                                        X237_PSK vZOO. LARS6.ia.CU
Triangle Laboratories, Inc.a
801 CapHola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                     Printed: 17:03 09/22/97
                                                                   20

-------
TLI Project:      43229
Client Sample:   Trip Blank
            Method 23 PCDD/PCDF Analysis (a)
                        Analysis File:  T976379
fntemaf Standards
"Cu-iSJ.S-TCDF
13C,2-2,3,7,8-TCDD
I3C,2-l,2,3,7,8-PeCDF
13Ci2-l,2,3,7,8-PeCDD
"Ci2-l,2,3,6,7,8-HxCDF
'3C,2-l,2,3,6,7,8-HxCDD
13C,2-l,2,3,4,6,7,8-HpCDF
"Ci2- 1,2,3,4,6,7,8-HpCDD
"C,2-1,2,3,4,6,7,8,9-OCDD
Surrogate! Stanftards 0VP«
"CU-WJ.S-TCDD
I3C,2-2,3,4,7,8-PeCDF
I3C,2-l,2^,4,7,8-HxCDF
13G2-l,2,3,4,7,8-HxCDD
"C,2-l,2,3,4,7,8,9-HpCDF
^fe^;W Amt, (ng)
2.0
2.0
1.6
1.7
2.5
2.9
2.3
2.7
5.4
»fcH'Al«M8$^;
3.8
4.2
3.9
3.4
3.5
A>; \An3t^n0?
2.5
2.5
' />


.r^lfewwny
49.6
50.4
39.8
43.3
62.6
72.7
57.4
67.0
67.5
™v;-j*»Mtti«r|r;
94.6
104
98.0
83.8
87.8
>v% Recovery
61.8
63.3
V


-. f
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
40%-130%
25%-130%
25%-130%
25%-130%
^y«iir?rr
70%-140%
70%-140%
70%-140%
70%-140%
70%-140%
QCLimrte '
40%-130%
40%-130%
VV?X


Ratkr
0.77
0.77
1.47
1.31
0.50
1.24
0.45
1.01
0.82
^Mto;

1.49
0.50
1.21
0.43
vRat!o-
0.50
0.48
Ratio
0.85
1.18
-"wr— flags '
20:45 	
21:33 	
25:00 V 	
26:07 RO 	
28:43 	
29:26 	
31:23 	
32:15 	
34:43 	
'r '^-^SHL^i™' \'Jrfef}£
21:35 	
25:46 	
28:36 	
29:20 	
32:35 	
- -HT«- ^Ffcgs-
29:56 __
29:13 	
' * XHT „ ^fe^s
21:22 	
29:43 	
                    Data Reviewer
_SL
09/22^7
                                      Page 2 of 2
Triangle Laboratories, Inc.s
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                  Printed: 17:03 09/22/97

                                203

-------
  Data. Review Byi
                                  	Date...

                                   i /   /	  Calculated Hoise Area
 fhe Total Area for each gt&ak with  an ion abundance ratio outside
 ratio limits has been recalculated according co method ragwlremeKi
  Page No,
  09/22/97
Listing of TS?63?9B.dbf
Hatched GC Peaks / Ratio /  Ret. Time
 KJ2..., QC. tag Omit Why ..ST.  OK Hatia 'Total,Areau ,. Area. Peak. 1..  Area. Peak. 2..  Rtl.KT Compound, Haiae..  ID..  Flags.
TCDF
304-306
A
K
D

A


D

D






304-30S
13C12-TCDF
316-318






316-318
TCBD
320-332
D










DC


DC




d

d



DC
DC
DC


DC
DC
DC
DC
DC

DC


BC
d
DC
DC
EC
DC
DC
DC
DC
DC
•DC

ML


SB




SH

SU



SH
sa
UH
10

Nl>
WL
WL
WL
SB

SN
1

NL
SH
SN
311
3B
SB
SK
SN
SN
SN
SN

0:00
17:19
17:51
18:03
18:29
18:50
19:18
IS! 39
19:54
20:18
20:34
20:48
21:15
21:29
Hi 44
21:55
23:03
Feaks

0:00
17:43
18:05
18:50
19:57
20:45
21:44
Peak

0:00
18:45
19:12
19t5S
20:18
21:07
21:14
21:20
21:26
21:41
22:10
0
RO


RO



RO
EO
RO
SO
80


RO
RO
RO

0,

RO
RO

RO

RO

0,
RO


RO

RO
RO
RO



.65-0.89
1
0
0
I
0
0
0
1
1
0
1
0
0
a
0
0
1

.38
.83
.80
.26
,80
.72
.73
.08
.26
.51
.24
.96
.82
.86
.17
.61
.40

0
7
5
2
25
IS
15
12
5
8
S
26
15
18
0
.14
.35 3,34
.90 2.62
.02
,69 11.43
.27 6.37
.57 6.59
.50 7.03
.S3
.46 3.68
.69
.82 14.47
.68 7.08
.32 8.74
.51
0.78
0
152
.92
.16
.65-0.89
0
2
3
0
0
0
1

.88
.73
.08
.68
.46
.77
.68

BS-0.89
1
0
0
0
0
7
s
1
0
0
0
.40
.76
.85
.15
.75
.75
.67
.29
.86
.82
.82
0
0
0
0
0
356
1
.15
.39
.44
.64
.55
.87 154.82
.73
0.826-1.097
0
4.01 0
3.28 a
a
14.26 0
8.90 0
8.98 0
7. OS 0
0
6.01 0
0
15.15 1
8.60 1
10.18 1
1
1
1

.000
.835
.860
.870
.891
.908
.930
.947
.959
.978
.991
.002
.024
.035
.047
.056
.111












2378-fCOP






0. 952-1. 048
0
0
0
0
0
202.05 1
1
.000
.854
.871
.90S
.961
.OOO
.047





13C12-2378-TCDF

356.87

0
3
1
0
.09
.84
.09
.18
1.B8
0.07
0.05
0.67
1
.71
0.31
0,
89
0.881-1.056
0,
0,
0,
0,
.000
.870
,891
.924




0.942
0,
0.
0,
930
,985
,9JO



0.995
1.006
1.
029

Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 17:04 09/22/97

                                                                204

-------
 Page No.
 09/22/97
                       Listing of T976379B.dbf
                       Matched GC Peaks I  Ratio / Ret. Time
Compound/
M_Z....  QC.Loff Omit Why  . .RT. OK Ratio Total .Area.. ». Area. PeaJc. 1. .  Area. Peak.2 . .  Rel.RT Confound. NJ
                                                                                           ame. . ID..  Flags.




320-322
37C1-TCDD
328


















328
13C12-TCDD
332-334













332-334
DC
DC
DC
DC

SN
SN
S1I
WH
0
22:17
22:29
22:37
22:50
Peaks

RO
RO
RO

0
0
2
0

.79
.17
.43
.22

0
0
0
0
0
.25
.05
.41
.64
.00
1
1
1
1

.034
.043
.049
.060

0.907-1.093
DC
DC
DC
DC
DC
DC
DC
DC

DC
DC
DC

DC

DC
DC
DC
DC


DC
DC
DC
DC
DC
DC







DC

NL
WL
WL
WL
WL
WL
WL
EN

SN
SN
SN

SN

SN
SN
SN
SN
3

NL
WL
ML
SN
SN
SN







SN
7
0:00
18;33
18:47
19:00
19:02
19:15
19:32
19:43
20:05
20:33
20:54
21:11
21:35
21:48
22:02
22:28
22:39
22:58
23:06
Peaks

0:00
18:37
18:45
19:37
19:44
19:54
20:12
20:18
20:36
21:22
21:33
21:56
22:17
22:46
Peaks










































0
0
0
0
0
0
0
0
3
0
0
0
264
0
.07
.36
.15
.22
.31
.44
.31
.25
.01 3.01
.11
.65
.77
.49 264.49
.78
1.06 1.06





0.
RO
RO
RO
RO
RO


RO
RO


RO
RO
RO











0
0
0
0
268
.40
.73
.32
.23
.56
.65-0.89
3
3
1
3
2
0
0
3
1
0
0
1
1
9

.36
.31
.05
.91
.72
.80
.78
.02
.60
.85
.77
.33
.77
.67

1
1
2
0
1
1
2
2
1
556
306
6
2
1
878
.17
.20
.30
.81
.68
.26
.31 1.01
.18 3.71
.86 1.68
.59 255.48
.30 133.52
.04 4.53
.80 2.79
.12
.08
0
.000
0.861
0
0
0
0
0
0
0
0
0
0
1
1
1
1
1
1
1

.872
.882
.883
.893
.906
.915
.932
.954
.970
.983
.002 37C1-TCDD SDR1
.012
.022
.043
.051
.066
.072

0.907-1.093
0
0
0
0
0
.000
.864
.870
.910
.916
0.923
1.30 0
1.23 0
1.05 0
301.11 0
172.78 1
3.41 1
1.58 1
.937
.942
.956
.991 13C12-1234-TCDD RSI
.000 13C12-2373-TCDD IS1
.018
.034
1.056


Mi.-_m tri-nri / iv-. i— riTt TT.. 1 1 ..• . r.
PeCDF
340-342




DC

DC
DC

ML

SN
SN

0:00
22:54
23:05
23:08
1.
RO


RO
32-1.78
1
1
1
1
.00
.33
.36
.09

0
16
0
0
.13
.55 9.46
.33
.39
0.909-1.075
0
7.09 0
0
0
.000
.916
.923
.925
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                         Printed: 17:04 09/22/97
                                                                                          205

-------
 Page No.
 09/22,97
Listing of T976379B.dbf
Hatched GC Peaks /  Ratio / Set. Time
 Compound/
 H_Z.... QC.Log Omit Why  ..RT. OK Ratio Total. Area...  Area. Peak. 1. .  Area.Peak.2..  Rel.RT Compound. Name.. ID..  Flags.







A
H







D
340-342
13C12-PeCDF
352-354












352-354
PeCDD
356-358
A

K




K




356-358
DC
DC
DC








DC


DC
DC
a


DC
DC

DC
DC


DC


DC
DC
DC


DC

DC

DC

DC
DC

DC
DC
DC
DC

SN
SN
SN








SN


SN
SN
SN
11

NL
SN

SN
SN


SN


SN
SN
SN
5

NL

SN

SN

SN
SN

SN
SN
SN
HH
4
23:29 RO
23:39 RO
23:48 RO
23:59
24:07
24:18 RO
24:27
24:40 RO
25:01 RO
25:11
25:19
25:39 RO
25:46
25:55 RO
26:01 RO
26:12
26:45 RO
Peaks
1.
0:00 RO
23:30 RO
24:05 RO
24:18 RO
24:37 RO
25:00
25:18 RO
25:34 RO
25:46
26:06 RO
26:30 RO
26:45 RO
26:53
Peaks
1.
0:00 RO
24:14 SO
24:34 RO
25:02 RO
25:10 RO
25:19 RO
25:31 RO
25:41
26:08 RO
26:17 RO
26:28 RO
26:37 RO
26:53 RO
Peaks
1.13
0.61
0.71
1.43
1.57
1.15
1.40
1.99
1.31
1.55
1.36
0.93
1.53
1.28
1.22
1.72
0.76

.32-1.78
0.88
0.19
1.31
0.44
1.14
1.47
0.91
1.20
1.49
1.01
O.SS
0.36
1.52

32-1.78
1.00
0.80
0.19
2.01
2.51
1.26
2.64
1.67
2.45
0.69
3.75
0.52
0.63

0.56
0.33
0.53
12.10
44.41
8.33
5.16
9.54
7.70
5.53
9.95
0.64
13.03
10.86
0.92
1.28
1.88
143.71

0.12
0.18
4.61
0.31
1.07
273.30
2.39
0.69
290.34
2.04
0.43
0.59
1.16
572.63

0.10
4.24
0.15
2.09
0.89
2.39
0.99
0.72
2.12
0.97
0.31
0.48
0.20
10.34



7.
27.
5.
3.
7.
4.
3.
5.

7.
6.







2.


162.
1.

173.
1.






12
10
37
01
46
68
39
73

87
60







80


79
45

60
24






4.98
17.31
4.65
2.15
3.74
3.56
2.19
4.22

5.16
5.17




0.


2.13


110.51
1.59

116.74
1.23



0
0
0
0
0
0
0
0
1
1
1
1
1
1
1
1
1

.939
.946
.952
.959
.965
.972
.978
.987
.001 12378-PeCDF
.007
.013
.026
.031 23478-PeCDF
.037
.041
.048
.070









AN



AN





840-1.160
0
0
0
0
0
1
1
1
1
1
1
1
1
.000
.940
.963
.972
.985
.000 13C12-P6CDF
.012
.023
.031 13C12-PeCDF
.044
.050
.070
.075





123 IS2


234 SOR2







2.

1.

1.


2.






58

65

45


03





0.

3.23

0.82

1.15


0.83





922-1.025
0
0
0
0
0
0
0
0
1
1
1
1
1

.000
.928
.941
.959
.964
.969
.977
.983
.001 12378-PeCDD
.006
.013
.019
.029









AN





Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 17:04 09/22/97
                                                                   20G

-------
Pag« No.
OS/22/97
Listing of T976379B.dbf
Matched OC Peaks / Ratio / Ret. Tim
H_Z.	QC.Log emit  why . ,RT.  OK Ratio Total. Area.... Area.Psak.l-. Area.Peak.2.. Rel.RT Confound. Name..  ID.. Flags.
13ClZ-PeCDD
3S8-370






368-370
HSCCDF
374-376



















374-376
13C12-HXCDP
384-386
















DC
DC
DC


DC
DC


DC




DC


DC


DC
DC
DC
DC
DC
DC
DC
DC
DC


DC
DC
DC
DC
EC


DC

DC
DC
DC

DC
DC
EC

NL
SN
SN


SN
SN
2

NL




SN


SN


SN
SN
SN
SN
SH
SH
SH
HH
WH
8

NL
SN
SH
ss
SH


SN

SN
SN
SH

SN
SN
EN

OsOO
25tlO
25:31
26:07
26:15
26:38
26:53
Peaks

0:00
27:37
27:47
27:56
28:04
28:26
28:3S
28:43
28:49
29:02
29:13
29:21
29:29
29:34
29:44
29:46
29(55
30:00
30:12
30:22
Peaks

0:00
27i37
27 1 45
37:52
28:08
28:36
28:43
28:59
29:13
29:25
29:38
29:49
29 1 56
30:05
30:13
30:26
1.
RO
RO
RO
SO

RO
RO

1.





RO


RO

ao
EO
RO
RO
RO


80
12-1.78
0.88
0
0
1
1
4
0

.94
.92
.31
.75
.31
.87

05-1.43
1
1
1
1
1
4
1
1
1
1
1
2
0
.20
.22
.21
.05
.32
.18
,10
.41
.58
.37
O.
0,
12
54
0.56
174.
16.
0.
£2 106.14
91 10.75
41
0.66
0. (47-1. IS*
O.OOO
0.961
0
.977
81.23 1.000 13C12-PeCDB 123
6.16 1
I
1
.oos
.020
.033

I S3



191,53

0.11
6.07 3.33
21,
2.
,65 11.87
,38 1.22
3,69 2.10
0.38
14. SO 7.61
8.46 4.95
1.77
4.12 2.38
.63 4.79 3.48
.29
.84
3.43
0
1
1
2
.72
.14
.08
.SO
i.oa
RO

0,
RO
RO

RO
RO


RO

RO
RO
RO

RO
RO
RO
0

.22

0
.16
0.29
0
0
O
O
D
0
0
65
.16
.23
,15
,83
,81
.27
.04
.56
.43-0.59
0
0
o
1
0
0
0
0
0
2
0
0
0
2
2
1
,10
,37
.51
.85
.92
.50
.50
.76
.48
.as
.76
,07
.50
,94
.51
.31
0.18
0
2
0
0
.65
.90
.26
.59
307.16 102.43
335.80 111.39
1
.21
322.47 104.74
0.94
1.68
0.09
2S6
,08 35.26
O.S1
0.59
0.54
0. 956-1. 050
0.000
2.74 0
9.78 0
1.16 0
1.59 0
0
S.8S 0
3. 51 1
1
1.74 1
2.14 1
1
1
1
1
1
1
1
.962
.967
.973
.977
.990
.995 123478-HXCOP
.OOO 123878-HXCOP
.003
.011
.017 23467S-HXCDP
.022
.027
.030
.035
.037
.042 12J7S9-HXCDF
.045





AH
AH


AH





JBt

1.052
1

.057



0.861-1.139
0
0
0
0
0
204.73 0
224.41 1
1
217.73 1
1
1
1
170.82 1
1
1
1
.000
.962
.966
.970
.980
.996 13C12-HXCDF 478
.000 13C12-HXCDF 678
.009
.017 13C12-HXCD? 234
.024
.032
,038
.042 13C12-HXCDF 789
.048
.052
.060





SURj
XS4

ALT2



Alffl



Triangle Laboratories, Inc.®  Analytical Sendees Division
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729»Fax: (919) 544-5491
                                                                Printed: 17:0409/22/97
                                                                   207

-------
 Page No.
 09/22/97
Listing of T976379B.dbf
Hatched GC Peaks / Ratio
                                                  Ret. Time
 Compound/
 H_Z.... QC.Log Omit why . .RT.  OK Ratio Total.Area... Area. Peak. 1.. Area. Peak. 2. . Rel.ST Compound, name..  ID..  Flags.
                      1 Peaks
                                           1,221.51
HxCDD
390-392

















390-392
13C12-HXCDD
102-104















402-404
HpCDF
408-410





DC
DC
DC
DC
DC

DC

DC
DC
DC
DC
DC
DC
DC
DC
DC
DC


DC
DC
DC
DC
DC
DC
DC
DC
DC
DC




DC
DC


DC

DC
DC
DC

ML
SN
SN
SN
SN

SN

SN
SN
SN
SN
SN
SN
HH
HH
HH
HH
2

ML
WL
WL
WL
WL
SN
SN
SN
SN
SN




SN
SN
4

NL

SN
SN
SN

0:00
28:02
28:10
28:17
28:24
28:37
28:41
28:51
28:59
29:05
29:13
29:21
29:27
29:47
29:56
30:02
30:06
30:12
Peaks

0:00
28:02
28:07
28:11
28:23
28:30
28:32
28:36
28:43
29:02
29:20
29:26
29:43
29:56
30:02
30:13
Peaks

0:00
31:24
31:36
31:15
32:10
1
RO
RO
RO
RO
RO

RO

RO
RO
RO
RO
RO
RO
RO
RO
RO


1,
RO
RO
RO
RO
RO
RO







RO
RO
RO
.05-1.43
0
1
1
5
0
1
2
1
1
0
1
.63
.50
.49
.56
.56
.28
.29
.28
.70
.21
.00
0.92
0
0
0
0
0
1

.79
.78
.67
.38
.50
.17

Lre: rucwii
0
0
1

.09
.40
.59
0.20
0
4
0
4
0
0
.33
.79 2.69
.31
.72 2.65
.83
.09
0.45
0
1
0
.83
.41
.13
0.18
0
0
0
9
.05
.13
.26
.51
.05-1.43
5
4
0
3
5
0
1
1
1
1
1
1
1
0
9
1
.00
.50
.71
.21
.42
.37
.38
.11
.36
.24
.21
.24
.13
.86
.70
.60
0
0
0
0
0
0
0
0
0
1
229
.18
.13
.51
.31
.27
.20
.31
.10
.78
.21
.60 125.86
304.83 168.87
444.57 240.48
2.64 1.46
0.45
0.78
0.951-1.014
0
0
0
0
0
2.10 0
0
2.07 0
0
0
0
0
1
1
1
1
1
1

.000
.952
.957
.961
.965
.972
.976
.980
.985
.988
.993
.997 123478-HxCDD
.001 123678-HxCDD
.012
.017
.020
.023
.026












AN
AN






0.366-1.034
0
0
0
0
0
0
0
.000
.952
.955
.958
.964
.968
.969







0.972
0
0
103.74 0
135.96 1
204. OS 1
1.70 1
1
1
.976
.986
.997 13C12-HXCDD 478
.000 13C12-HXCDD 678
.010 13C12-HXCDD 789
.017
.020
.027


SCR4
IS5
RS2



981.54
0.
RO

RO

RO
88-1.20
0
1
1
0,
0,
.71
.10
.22
.98
.41

0.10
6.73 3.52
1.55
1.21
0.29
0.991-1.042
0
3.21 1
1
.000
.001 1234678-HpCDF
.007

AN

1.012
1.025
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Printed: 17:04 09/22/97
                                                                                                208

-------
 Page No.
 09/22/97
Listing of T976379B.dbf
Hatched OC Peaks  / Ratio / Ret. Time
 Compound/
 M_Z---- QC.Log Omit Why . .RT.  OK F.acio Tocal .Area. . . Area.Peak.1.. Area.Peak.2. . Rel.RT Compound. Name. . ID.. Flags.



408-410
13C12-HpCDF
413-420






418-420
HpCDD
424-426
K

MX



424-426
13C12-HpCDD
436-438



436-433
OCDP
442-444














DC
DC
DC

SN
SN
WH
1
32:15
32:31
32:56
Peak
SO
RO
RO

2
0
2

.26
.80
.76

0.55
0.
0.
S.
71
59
73
0.37-0.51
DC

DC
DC
DC

DC


DC

DC

DC
DC
DC

NL

SN
SN
SN

SN
2

NL

SN

SN
WH
WH
2
0:00
31:23
31:54
32:07
32:20
32:35
33:02
Peaks

0:00
31:38
31:54
32:15
32:19
32:31
32:46
Peaks
RO

RO
RO
RO



0.

RO


RO
RO
RO

1
0
2
0
2
0
0

.20
.45
.40
.99
.00
.43
.40

88-1.20
1
0
1
1
1
.00
.71
.13
.18
.56
1.45
0

.57

0.
209.
0.
1.
0.
144.
1.
07
34
14
01
17
95
71
354.29
Hp COP /
0.
1.
0.
2.
0.
0.
0.
3.
14
47
81
01
18
22
26
48
0.88-1.20
DC
DC
DC



DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
DC
NL
SN
SN

1

NL
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
SN
0:00
31:39
31:55
32:15
Peak

0:00
31:48
32:29
32:38
32:59
33:17
33:36
33:47
34:00
34:03
34:20
34:43
34:48
35:15
35:26
RO
RO
RO


0.

RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
RO
0
0
2
1

.75
.59
.50
.01

.76-1.02
1
0
0
0
0
6
4
0
2
0
0
0
1
0
0
.00
.29
.08
.23
.40
.11
.40
.23
.43
.35
.45
.43
.09
.45
.25
0.
12
0.80
0.53
229.
24
229.24
HpCDD /
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
12
11
04
15
13
17
09
19
26
40
19
45
42
55
19
1
1
1

.028
.036
.049





0.936-1.127
0
65.02 144.32 1
1
1
1
43.75 101.20 1
1

.000
.000 13C12-HpCDF 678
.016
.023
.030
.038 13C12-HpCDP 789
.053


IS6



SUR5


0.976-1.005
0.000
0.75 1.05 0
0
1.09 0.92 1
1
1
1

.481
.989
.000 1234678-HpCDD
.002
.008
.016



AN




0.969-1.031
0
0
0
115.08 114.16 1

.000
.981
.990
.000 13C12-HpCDD 678




1ST

0.885-1.115
0
0
0
0
0
0
0
0
0
0
0
1
1
1
1
.000
.916
.936
.940
.950
.959
.968
.973
.979
.983
.989
.000
.002 OCDP
.015
.021












AN


Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                 Printed: 17:04 09/22/97
                                                                   209

-------
  Page No.
  09/22/97
     Listing o£  T9"6379B.dbf
     Matched GC  Peaks / Ratio / Ret.  Tin
 Compound /
 M_Z.... QC.Log Omit Why . .RT.  OK Ratio Total.Area... Area. Peak. 1. . Area. Peak. 2. .  Rel.RT Compound. Name..  ID.. Flags.
                 DC
                 DC
SN  35:39  RO
SN  35:49  RO
  0 Peaks
0.49
0.50
0.36
0.13
0.00
1.027
1.032
 OCDD
 458-460
                 DC  NL
                 DC  SN
                 DC  SN
                 DC  SN
           0.76-1.02
     0:00     0.86
    34:38 RO 21.33
    34:56 RO  1.06
    35:02 RO  0.02
    Peaks
              0.13
              0.06
              0.59
              0.04
              0.00
                             0.885-1.115
                                 0.000
                                 0.998
                                 1.006
                                 1.009
  13C12-OCDD                     0.76-1.02
  470-472         DC  NL   0:00     0.8S         0.13
                         34:43     0.82       361.14
  470-472               1 Peak                 361.14
                                       162.91
                                                        0.995-1.004
                                                            0.000
                                                    198.23  1.000  13C12-OCDD
 Column Description.
                                 •Why  Code Description	  QC Log Desc.
 M_Z   -Nominal Ion Mass (es)
 ..RT. -Retention Time (mmras)
 Kat.l -Ratio of M/M+2 Ions
            WL-Below Retention Tine Window
            WH-Above Retention Tima Window
            SN-Below Signal to Noise Level
 OK
       -RO=Ratio outside Limits  
-------
file:T976379 #1-892 Acq:18-SEP-1997 22:36:00 riv- Voltage SIS 701 «0ise:56
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-------
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-------
 TLI Project:      43229
 Client Sample:    Trip Blank
           Method 23 TCDD/TCDF Analysis (DB-225)
                                Analysis File:   P973987
 Client Project:    S414.Q03/WAUPACA Foundry
 Sample Matrix:   M23TRAIN       Date Received:  09/12/97
 TLI ID:          183-1-6A-D        Date Extracted:  09/14/97
                                   Date Analyzed:  09/19/97
                                   Spike File:   SPC2NI04
                                   ICal:        PF22206
                                   ConCal:      P973982
 Sample Size:     1.000
 Dry Weight:      n/a
 GC Column:     DB-225
     Dilution Factor: n/a
     Blank File:     T976373
     Analyst:       ML
                     % Moisture:  n/a
                     % Lipid:     n/a
                     % Solids:    n/a
23,7,8-TCDF
0.06
                      0.83
20:32
 I3C12-2,3,7,8-TCDF
2.0
48.9      40%-130%      0.76      20:30
 BCtrl,2,3,4-TCDD
                                    0.79      19:33     	
                      Data Reviewer
                                       V'C
                                         Page 1 of!
                                09/22/97
                                              canysR vioa uas «.HUM
Triangle Laboratories, Inc.s
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                          Printed: 02:1109/22/97
                                                                     23 r,

-------
                       Initial   ..,.0ae«—
 Data Review By;
                                             Calculated Noise Area: n/a
 The Total Area for each peak witfc an ion abundance ratio outside
 ratio  limits has been recalculated according to method requirements.
 Page No.
 09/22/97
Listing at P973987B.dbf
Matched SC WmUks I Ratio / Set, Tim
 Coinpound/
 B_Z,,., QC.log Colt Shy ,.&?. OK Ratio Total.Area,.
                          Area. Peak. 1.. Area,Peak.2,.  Rol.RT Compound. Same.. ID.. Flags.
TCD?
304-306



















M






304-306
13C12-TCDP
316-318






316-Jli
13C12-TCDD
332-334

DC NL OiOO
16:16
DC SH 16:42
DC SK 16s49
17:13
17:21
17:27
17:38
17:54
18:09
18:20
18:28
18:50
19:13
DC SH 19:21
19:31
19:40
DC SS 19:54
20:02
20:24
20:32
20:42
20:56
21:03
21:41
DC SH 21:50
DC SH 22:19
20 feaks

DC NL 0:00
DC WL 17»57
19:30
DC SN 20:11
20:30
DC SS 21:02
DC WH 22:20
2 Peaks

DC NL 0:00
0.



RO
65-0,89
0
0
0
0
,68
.78
.73
.96
0.81
HO



RO
RO
RO

RO

RO

HO

RO


RO


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RO
RO
RO
RO

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RO

0.
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0
0
0
0
0
1
0
0
1
0
0
0
1
0
0
0
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1
0
0
1
0

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.71
.73
.70
,99
.25
.90
.80
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.85
.99
.S3
.80
.11
.79
.69
.04
.72

1.73
13.28
0.76
0.44
20.28
11. SS
17.96
12.58
8.31
4.18
20.12
7.88
14.54
11.22
1.86
12.37
11.27
0.89
13.55
11.24
11.19
8.95
9,59
21.50
19.33
0.41
1,00
261.79

5


9
S
7
5
3
2
14
4
6
6

5
4

6
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6
9
7




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.33
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.23
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.06
.97
.01
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.87




7


11
8
10
7
5
2
11
4
8
6

9
6

7
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4
5
12
11



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0
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4
0
1
0

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.09
.60
ftlu~..
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1
,71
1.81
0.74
4.04
0.14
676.34
1.52
3.38
680.38
is * TCD? / TCDD

1.24


2

291




.26

.38




2

384


0.

.48


.20
.09
.52
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.02
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0.


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.96


78S-1.095
0.000
0.793
0.815
0.820
0.840
0.846
0.851
0.860
O.S73
0,885
0.894
0.901
0.919
0.939
0,944
0.952
0.959
0.971
0.977
0.995
1.002 2378-TCDF AH
1.010
1,021
1.027
1.058
1.065
1.039

931-1.04}
0.000
0.876
0,951
0.985
1.000 13C12-2378-TCBF ISO
1.026
1.089





0.

897-1.103
0.000
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive « Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                   Printed: 02:11 09/22/97
                                                            23'

-------
 Page to.     2           Listing of P9739S?B.dM
 09/22/97                 Matched OC Peaks / Ratio /  Ret.  Time
 M_Z	 QC.Log Omit Why ..ST. OK Hatio Total .Area...  Area.Peak. 1..  Area.Peak.2,.  Ral.RT Compound. Name.. ID.. Flags.

                                                                                0.946
                                                                                l.OOO 13C12-2378-TCDD IS1
                                                                                1.012 13C12-1234-TCDD RSI
                                                                                1.045
                                                                                1.126
 332-334
18:16 RO
19:19
19:33
20:12
21. 4S RO
Peaks
1.38
0.77
0.79
0.87
1,68

2.32"
496.11
997.05
7,96
0,71
1,504.25
1.81
218.91
441.36
3.71


1.31
280. CO
555.70
4. 25


 column Description	   "Why Code Description	  QC Log 0esc.
 MJS   "Hominal Ion Mass (es)     WI*»8elow Retention Time Hicdow   A-Peak Added
 ..RT, -Retention Time {imnissS   WH-Above Retention Time Window   K-Peak Kept.
 Rat.l -Ratio of H/H+2 Ions      SN-Below Signal to Noiss Level   D-Peak Deleted
 OK    -ROsRatio Outside Limits  
-------
rile:f973987"f 1-755 HcyilS-SSf-1997 ,22:4*818"BI+ Voltage SIS 70f KMSes
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         LASS  TextiTRTF SLAKX TMM3229
              17:00          18:00          19:00          20:00         21:00
rilestS739S7 tl-755 Ha?! 19-SSt-1997 22,49:18 Eli- Voltage SIR  70t H>iae:5l4
30S.89B7 BStm(25S,3Q,-3.0) WCDf5,3,1,0.101,2056.0,0,1
TSIKKSLS LABS  Tezt-.TXIt BIANK TLH43229

                 M.12SS         U-**SS
                                                                                       22>0t
              17:00          18-00          19:00          20:00         21:00
rileiP9739S7 tl-755 ArxjiJ.9-S£f-lS97 23st9tlB EH- Voltage SIS 70f Noise:465
315.9419 BSU13(2Se,30,-3.0> PKBf 5,3,1, 0.101i,1860.0,0.OQ\,r,T) Sxp:DB225
IKIAXStE LASS  TexCjTEIP BiANT TLH4322S
lOOi,                                                            A2.S1S6
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              17:00          18:00          19:00          20:00         21:0
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317.9389 »SUB(25S,30r-3,0) FKB(5,3,1,0.10^,2049.0, 0,00%,r,r)  SxpiBB225
TRIANGLE LABS  lextlXSXP BLANK TtH43229
ion                                                            A3.S5SS
 to:

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37S.83S4 Xxpim225
TRIANGLE LASS  Text:TEIP  SLANT. TLIH3229
ion, ,
                                                                        21-00
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    Time
              17,00
                             18:00
                                                          201 00
                                                                        21,00
                                                                                      22:00
                                                                                   239

-------
   LetPS/JS&J #1-755 Acq:lS-SJt:P~191f7 22l49tlB EI+-  voxcagre  SIM  7SP
 319.B965 asVB(25S,30,-3.0j PKD(S,3tltO,10%,1268.trt,OOl,f,F)  firj>
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 100*
   17:00             IS:00            IS:00             JO:00            21:00
Mlo:J>S73987 #1-755 Aeffil.9-S«-l.*S7 22t49tlB a* Voltage SIM  70r Nc±sg:333
321.8936 SSOS(2SSf30,-3.0) fKD(5f3,l, 0.101,1332. 0, a.OOt,F,r)  Exp,DB325
TKIAHSLE LASS  TeztlTRIf BLANK SLIf43229
 1003,
  so:
                                                                                          22s 00
   17ttO             IBtOB            1S:00             lOiOO             31tOO
rilatP9739S7 tl-7S5 AcyilS-SKf-1997 32,49:18 XH- Voltage SIS 70? Ht>±ae:273
327.8847 MSO»(2Sf, 30,-3.0}  fXD(5, 3,1,0.101,1092. Ort.001er,f) SrftOKt25
SSXStfStS LUSS  TKlt:TSI? BLAST TLI#43229
                                           A4.38E6
aoi

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   17:00            10iOO             19:00            20:00             21:00
n.lsiPf?3987 H-7S5 &c%tia-$EI-1997 22:49:13 Sit Voltage SIR 70P K>±se:598
331.9368 SStm(2Sf,30, -3.0)  fOl(5f3rl, 0.104,2392.0,0.00%, I,t) Si
TSIAXsa UU!S  SeltlSSIP 9UUDC TLH43229
1001

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                                         A2.ni:
                                                  1ES
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333.9338 astm(25e,3t,-3.tl IX3}(5,3,1, 0.10*, 1392,0,0.
TSIANGLE LABS  Text:TRIP BLANK XL*f43229
1001:
 SO.

 sal

 40.

 301
                                                                                          22:00
                                                                                                 .9.4E5

                                                                                                 : 7.1*5

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                    10100
                                                       20: SO
                                                                        21:00
                                                                                                10, 0*0
                                                                                          22:00     Tins
                                                                                   240

-------
f±leif9739S7 #1-755 aaqslS-aSf-1997 32s49tl8 EH- Voltage SIX 70t
303.SOIS Eip:DB235
               fGxttTRXf  SLasK ILXI4323S
                                  ItfSO
                  17113
                             1B»00         15-00          20100
Viletf973S87 #1-755 tcqilS-SEP-1997 22:49:IS MI* Voltage SIS  70f
315.3*19 Eip:DB225
TRIANGLE LABS  feXtsXBIP  BLANK TLIf43229
              17:00          18-00         19:00          20:00
rilasf9739a7 #1-755 Aojil9-SSP-1997 22:49:18 JTJf Voltaga SH  70r
319.8S65 Eip:DB225
TRIANGLE OLBS  TaXt:TRIP  SLANT: TZXt43229
                                                                        21i 90
                                                                                      22,00
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                                                                 20:30
                                                                        31:00
                                                                                      21:00
              17:00          IB': 00         19:00          20:00
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TSTAHCZE LABS  TajctiTSIP SLAtTX XLXM3339
1004                                               19;33
 aol
 sol
 401
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  el
                                                                        21:00
                                                                                      22:00
                                                IS 119}
              17>00          18:00         19:00          20,00
rilBir973Sa7 U-7SS &cqil9-SEf-1997 22it9:18 SJ+ Voltage SIX 701
292.S82S Eip:DB225
XBVOftLE LABS  Text,TXIP BLUOC TLH43229
 80:
 sol
 401
 20.
  ol
                                                                        31:00
                                                                                      22:00
                                                                                                    JLO.OSO
                                                                                                        fine
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                                                                                                     .3.2ES
                                                                                                     0.0X0
                                                                                                        TiBB
                                                                                                     .o.oea
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                                                                                                    -J..2S6
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                                                                                                     17.2SS
                                                                                                    E.*.*S5
                                                                                                    --2.4E5
                                                                                                    -O.OMO
                                                                                                        Tim,
              17-00          itiOO         19s 00          20:00
filmr9739S7 H-75S AcyilS-SEf-1997  22ii9tl8 fit Voltage SIS 71
330.9792 Exp,DB225
TSIAJKLE LABS  ToxtiTSlr BLANK TLIM3229
              17iOI       17i50           18t5aiSt23 19'SO     20*33
    •^>v«*w>/-5v^./\^V''1'Y"*"N/v^~s^y'W^^                      •-
 80j
 SO:
 «:
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  ol
                                                                                                    -1.0X7
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                                                                                                     O.OEO
                                                                        21s 00
                             16:00
                                                          20:00
                                                                        31*00
                                                                                      22:00
                                                                                                    r1.0E7
                                                                                                    -3.2E6
                                                                                                     S.3Z6
                                                                                                     4.1E6
                                                                                                     2.1SS
                                                                                                     O.OEO
                                                                                                        Tine
                                                                                  241

-------
fef ,  tass    292,8825    Peak top
Height  UvoUi  Span   2ip
Systai fill
Data  flit nase
Resolution
lonizklon »ode
                  1
                El*
B   383,9816
    C2K 0007
    gwiSs?
0   315,9419

F   319,898
    321,891
H   327,8847
I   338.97%
232,SBi5,
       J   339.3792
       K   331.3368
       L   233.3338
       I   375,8384
QsmeL  I  339,3782
        1,48 volts

-------
Pile:J>973987 #1-755 Acq:19-SEP-1997 22:49:18 EI+ Voltage SIR  70P
303.9016 Exp:DB225
Sample Text:TRIP BLANK TLI#43229 Pile Text:TRIP BLANK TLI#43229
100%
    igloo                      20:00                      21:00
File:P973987  #1-755 Acq:19-SEP-1997 22:49:18 EI+ Voltage SIR 70P
305.8987 Exp:DB225
Sample Text:TRIP BLANK TLI#43229 File Text:TRIP BLANK TLI#43229
100%
    igloo                      20:00                      21:00
File:P973987  #1-755 Acq:19-SEP-1997 22:49:18 EH- Voltage SIR 70P
317.9389 Exp:DB225
Sample Text:TRIP BLANK TLI#43229 File Text:TRIP BLANK TLI#43229
100S,                                        20j31
  60

  40J
  OJ
    19! oo
	1	1	r
 20:00
                                                                                    22:00
                                                                                    22 TOO
                                                                                         .O.OEO
                                                                                             Time
                                                                                          1.0E6

                                                                                         L8.4E5

                                                                                         L6.3E5

                                                                                         L4.2E5

                                                                                         L2.1E5
                                                                                    22:00
                                                                                        LO.OEO
                                                                                             Time

-------

        :,- y t .-  ~."/ _...,  _-;'   . _
           --         -
CALIBRATION
       DATA
            Triangle Laboratories, Inc.
       801 Capitola Drive       P.O. Box 13435
       Durham, NO 27713^411     Research Triangle Park, NC 2770S-34SS
       919-544-5729         Fax i 919-544-5491
                            24

-------
   ,                     tRISNSiE IABOBATOEIES OF RTP, BK.         Date: 02/20/96
                      Initial Calibration Suranary for PF22206

  Analysis Date....: 02/20/96                  Method	:  C2NF
  Instrument	s P                         GC Column...:  BB-225
  Aaalytes            RF     SD   %RSD      RT   RT/KJ  BT/HX  Batiol  Hatio2   K
  2378-TCDF          1.040 0.109   10%    21:32  14:31  25s31    0.7S7          10
  TOTAt TCDP         1.040 0.109   10%                          0.7S7          10
  2378-fCDC          0,992 Q.101   10%    20:12  16:11  24:11    0.782          10
  TOTAL TCDD         0.992 0.101   10%                          0.782          10

  Other Standards     RF     SD   %RSD      RT   RT/M  BS/HI  Ratiol  Hatio2   S
  37C1-TCOD          1.014 0.048    5%    20:12  18:11  22:11                  10

  Intarnal Standards  RF     SD   %RSD      RT   RT/LO  RT/HI  Ratio1  RatioZ   N
  13C12-237S-TCDF    1.3880.062    4%    21:31'20131  22«31    0.75S          10
  13a.2-237i-fO3D    1.0S7 0.03S    3%    20:11  18:11  22:11    0.786          10

  Recovery Standards  RF     SD   %RSD      R?   RT/LO  RT/HI  Ratiol  RatioZ   N
  13C12-1234-TO3D    1.000 0,000    0%    20:27                 0.794          10

  »»* End of Report **»
                                  Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitols Drive * Durham, North Carolina 27713                                        Printed: 23:10 02/20/96
Phone: (919) 544-5729 » Fax: (919) 544-5491

-------
                                          LiAuuiUKi.xttc.uu>,  ±j&--
                          Initial Calibration Sunsamxy far TFS3286
                                                                                  wmt vw;
                                                      Jtetliod	: H237

Analytes
Total MCDF
Total MCDD
Total OCOF
local DCDD
Total TriCDF
Total TriCOD
2378-TCDF
TOTAL TCDF
2378-TCDD
TOTAIi TCDO
12378-PaCBF
23478-PeCDF
TOTAL PeCDF
12378-P«OJD
TOTAL PeCDD
123478-HxCDF
123678-13803?
234678-HxCDF
123789-ffieCDF
TOTAL HxCDF
123478-HxeDB
123678-HxCDD
1237S9-13CCDD
TOTAL HxODD
1234678-HpCDF
12347S9-B&CDF
TOTAL HpCDF
1234678-IpCDD
TOTAL HpCDD
CCDF
QCED
other Standards
37C1-TCDD
13C12-3PaO3F 234
13C12-HKCDF 478
13C12~HjeCDF 234
13C12-HxCBF 789
13Cl2-HseCBD 478
13C12-H)pCD? 789
Inramal Standards
13C12-2378-TCBF
13C12-2378-TCDD
13C12-P«CDP 123

T
RF
1.3SS
1,558
0.598
1.067
0.594
0.2SO
1.090
1.090
1.182
1.182
1.086
1.122
1.104
1.231
1.251
1.088
1.353
1.094
0.985
1.130
0.914
1.000
1.03S
0.933
1.7S4
1.132
1.448
Q.9S1
0.9S1
1.180
1.017
HF
0.913
1.018
0.933
0.949
0.772
0.899
0.739
RF
1.292
1.092
1.233

t •*

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
0

SO
.000
.000
.000
.000
.000
.000
.079
.079
.130
.130
.072
.048
.059
.052
.052
.050
.080
.092
.051
.0€7
.060
.051
.968
.058
.090
.033
.057
.028
.028
.036
.027
3D
.018
.016
.040
.042
.037
.067
0.027

SD
0.017
0.015
0.053



%ESO
0%
Q%
0%
0%
0%
0%
7%
7%
11%
11%
7%
4%
5%
4%
4%
5%
6%
8%
5%
S%
7%
5%
7%
6%
5%
3%
4%
3%
3%
3%
3%
%RSD
2%
2%
4%
4%
5%
7*
3%
%RSD
1%
1%
5%
Page

KT
8:41
9:09
11.- 10
11:42
14:42
14:46
20:40

21:28

24:55
25:39

26:02

28:31
28:37
2J:QT
29:50

29 -.IS
29:20
29i3T

31sl7
32:28

32:08

34:42
34:36
HI
21:28
25:39
28:30
29:07
29:49
29*15-
32:28
SS
20:39
21:27
24:54
1

BT/LO
0:39
1:27
7:39
8:27
11:39
13:27
16:39

.17:27

20:54
.

22:01

24:36




25:19



27:17


28:08

30:36
30:36
SS/liQ
19*27
22:54




23:17
RT/M
19:39
13:27
20:54


• HX/BI
14:39
15:27
!Ss39
16:27
18:39
19 -.27
24:39

25:27

28:54


30:01

32:36




33s 19



3Ssl7


36:08

38:36
38:36
HZ/HX
23:27
26:54



•
35:17
HT/HI
21:39
23:27
28:54


Ratio 1 Eatio2
2.731
2.930
6.138
1.530
1.051
1.122
0.780
0.780
0.725
ff-.72S
1.512
1. 514
1.513
1.S73
1.S73
1,246
1.252
1.238
1,242
1.245
1.221
1.230
1.216
1.223
i.osa
1.030
1.047
1.025
1.025
0.894
0.834
Batiol Ratio2

1.475
0.513
0.501
O.S07
1.213.
0.433
Batiol Ratio2
0.736
0.791
1.473


KT
1
1
1
1
1
1
S
5
5
5
5
5
5
5
5
i
5 '
5-
5
5
5
S
S
5
S
5
5
5
S
5
5
S
S
5
S
S
5 .
5
S
H
5
5
5

Triangto Laboratories, Inc.® Analytical Sarvfcas Division
801 Captela Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 » Pax: (919) 544-5491
Printed: 13:47 04/03/96

-------
                                     CABQHA20R11S, INC.             oaca:
                       initial Calibration Sumnary for TFS3286
  13C12-?eCnO 123    0.724 0.033    5%    26:01  22:01  30:01   1.488            5
  13C12-HXCOF S78    1.207 O.OSa    5%    28:36  24:36  32:36   O.S1S            S
  13C2-HJICDD S78    0.943 0.047    S%    29:19  28:19  30:19   1.206            5
  13Ci2-HBCDF €78    0.821 0.01S    2%"   31:17  29:17  33:17   0.431            5
  13C12-BPCDD S7S    0.770 0.032    4%    32:08  31:08  33:08   1.019            5
  13C12-OCDD         0,5020.028    S%    34:36  32:36 •3S:3S   0,864            S

  EncoVBcy StandaLrtia   SF     SO   %RSD      RT   HZ/LO  HT/HI  Ratiol.  ELatio2    N
  13CTl2-1234-tCaX3    1.000 0.000    0%    21:IS                 0,797            3
  13C12-HxCUn 789    1.000 0.000    0%    29:37                 1.207            5

          of BaporC ***
                                   Page
Trtengi* LaboiatoriM, Inc.® Analytical Stwiwa Division
801 Capitaia Drive * Ourtiam. North Caraina 27713                                   Prfntecfc 13:47 04/03/56
    K (919) 544-5729 « Fax: (919) 544-5491

-------
. . Date:.09/18/97
  TRIANGLE LABORATORIES. INC.
Continuing Calibration for T976372
Operator . • .

lait Calibration.;
ICal Date, . . .

Analyta Summary
Hani®
KAS
Tf|Ki*« T-itrnanl"
1FS3286
Slid _r*f5nr?
. : T





";n nn
03/28/96
SF Ratio
1S2
Total MCDF

Total MCDD

Total DCDF

Total DCDD

total f riCDF

Total TriCDD

2378-TCBF

TOTAL TCDF
2378-TCD0

TOTAL TCDD
12378-PeCDF

23478 -PeCDF
TOTAL PeCDF
12378-PeCBD

TOTAL PeOJD
123478-HxCDF

123678-HxCDF
234678 -HXCDF
123789-ffltCDF
TOTAL HXCDP
123478-HxCDD

123678 -HxCDD

0

0

0

0

0

0

I

1
1

1
1

1
1
1

1
.000

.000

.000

.000

.000

.000

.156

,156
.216

.216
.122

.187
.154
.276

.276
1.186

1.

.510
1.176
1,
,143
1.254
0.

1.

393

056













0

0
0,

0,












.84

.84
.78

.78
1.53


1.S3
1.
1.

1.
1.

1.
1.
1.
1.
1.

1.

,53
,58

,58
30

29
23
30
29
21

22

HI RT Rel. RT
to/High
0:48
14:48
1:36
15:36
7:48
15:48
8:36
16:36
11:48
18:48
13:36
19:36
17:11 20:49 1.0008
22:49

18:36 21:37 1.0008
22:49

22:45 25:02 1.0000
26:55
25:47 1.0300

24:05 26:09 1.0006
26:47

27:28 28:38 0.9965
30:11
28:45 1.0006
29:15 1,0180
29:57 1.0423

28:00 29:22 0.9972
29:52
29:28 1.0006
Page 1
ICal
HF

1

1

0

.1

0

0

1

1,
1,

1,
1,

1,
1.
1.

1.
1.

1.
1.
0.
1.
0.

1.


.365

.558

.598

.067

-S94

.260

.090

.090
,182

.182
,086

,122
.104
.251

251
oaa

353
094
985
130
914

000


Delta
RF

-1

-1

-0

-1

-0

-0

Q

0
0

0
0

0
Q
0

0

.365

,558

.598

.067

.594

.260

.066

.066
.034

.034
.036

.065
.050
.025

.025
0.098

0,
0.
0.

.157
,082
,158
0.124
-0.

0.

021

056

*D

100

100

100

100

100

100

6

6


.0%

. Q%

. 0%

.0%

.0%

. 0%

.1%

.1%
2.9%

2
3

5.

.9%
.3*

,8%
4.6%
2.

2.
.0%

.0%
9.0%

11.
7.
16.
10.
-2.

5.


8%
5%
0%
9*
34

6%

Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                            Printed: 20:56 09fl 8/37

-------
Date: 09/3.B/97
TRIANGLE LABORATORIES,
Continuing Calibration
123789-HxCDD
TOTAL HxCDD
1234678-HpCDF

1234789-HpCDF
TOTAL HpCDF
1234578-HpCDD

TOTAL HpCDD
OCDF

OCDD

1.038
0.996
1.461

1.284
1.373
0.975

0.975
1.249

1.011

1.24
1.22
1.09

1.08
1.09
1.01

1.01
0.91

0.83



31:14
32:45


31:29
32:25

30:44
38:44
30:44
38:44
29

31:

32:

:4S

-.25

:37

32:15




34:51


34:44


INC.




for T976372
1

1

1

1


1

1

.0102

.0000

.0382

.0000


.0034

.0000

Other Standarf Suaaary
Name

37C1-TCDD

13C12-PeCDF 234

13C12-HXCDF 478
13C12-HXCDF 334
13C12-HXCDF 789
13C12-HXC0D 478
13C12-EpCOF 789

Internal Standard
Name

13C12-2378-TCDF

13C12-23?a-fCDD

13C12-PeCDF 123

13C12-PeCDD 123

13C12-HXCDF 678

13C12-HXCDD 678


RF

0.982

1.047

0.939
0.920
0.861
0.948
0.901

Suutinaj
RF

1.562

1.067

1.271

0.720

1.191

0.979


Ratio
Is2


1.49

0.51
0.50
0.31
1.24
0.41

T
Ratio
U2
0.73

0.84

1.46

1.43

O.SO

1.15


RT
La/High
19:36
23:36
21:02
29:02




29:25
35:25

RT
to/High
19:48
21:48
19:36
23:36
21:02
29:02
22:08
30:08
24:44
32:44
28:27
30:27
Page 2
RT

21:

25:

28:
29:
29:
29:
32:



37

46

37
14
57
22
36


HT

20:

21:

25:

26:

28:

29:



48

36

02

08

44

27


Sel. BT

1

1

0
1
1
0
1



.0008

.0293

.9959
.0174
.0423
.9972
.0377


Red. ET

1


.0000

1.0000


1.0000


1.0000


1.0000


1.0000




1.036
0.983
1.764

1.132
1.448
0.961

0.961
1.180

1.017

ICal
RF

0.913

1.018

0.933
Q.949
0.772
0.899
0.789

ICal
RF

1.292

1.092

1.233

0.724

1.207

0.943


0.002
0.013
-0.303

0.1S2
-0.075
0.014

0.014
0.069

-0.006

Delta
RF

0.069

0.029

0.006
-0.029
0.089
0.049
0.112

Delta
RF

0.270

-0.025

0.038

-0.004

-0.016

0.036


0
1
-17

13
-5
1,

!•
5.

-0.


%D

.2*
.3*
.2%

.4%
.2%
.54

.5»
.9%

.6%




7.6*


2.3%

0.
-3.
11.
5.
14.


%D

20.

-2.

3.

-0.

-1.

3.



6%
It
61
,5*
2t




9%

3%

1%

6%

3%

8%


rtangle Laboratories, Inc.® Analytical Services Division
)1 Capitals Drive * Durham, North Carolina 27713
Hone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 20:56 09/18/97

-------
  Date: 09/18/97           TRIANGLE LABORATORIES, INC.
                         Continuing Calibration for T976372
  13C12-HpCDF 678   0.871  0.41    29:25  31:25 1.0000   0.821  0.050   5.II
                                   35:25
  13C12-HpCDD 673   a.387  1.02    31:15  32:15 1,0000   0,770  0.117  IS.2*
                                   33:15
  13C12-OOD0        0.762  0.81    34:33  34:44 1.0000   0.602  0.160  26.6*
                                   34:53
  Recovery Standard Summary
  Hame               BP   Ratio
             ICal
Rt   lei.  RT  RF
Delta
  RF
                           IS3    to/High
  13C12-1234-TCDD   1.000  0.83           21:24 0.9907   1.000  0.000   0.0*
  13C12-HXCDD 789   1.000  1.18
                                          29:44 1.0096    1.000  0.000   0.0%
                        QC Front End Check:
                                                0.7030
                                  Page
Triangle Laboratories, inc.® Analytical Services Division
801 Caprtola Drive * Durham, North Carofina27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                          Printed: 20:56 09/18/97

-------
 Dafce:  .,09/19/97        TRIANGLE lABCSATORIES OF RTF,  IHC.
                        Continuing Calibration for P973982
 Analysis Date ---- i 09/19/97                  Method ...... : C2HF
                  : ML
Operator
Init Calibration.!  PF2220S
ICal Dace ..... ...!  Q2/2Q/9S
Analysis Tina ---- :  18:18
                                              Instrument..: P
                                              Std.Conc ---- :        S.QO

                                              QC Colon...: DB-22S
 Analyte Sumnary                                       ICal   Delta
 Hame               SB   Ratio     R?     RT   Rel.  RT RF      RF    %D
                          IS 2    Lo/High
 2378-TCDF         0.959  0.77    16:07  20:31 1.0000   1.040 -0.081  -7.8%
                                  22:23
 TOTAL TOJF        0.959  0.77                         1.040 -0.081  -7.8%

 2378-TCDD         1.120  0.78    15:5S  13:21 1.0009   0.992   0.128  12.9%
                                  21:52
 TOTAL TCBD        1.120  0.78                         O.S92   0.128  12.9%
 Otter Standard Sinsnary
 Haste               IF   Ratio
                          1S2
 37C1-TCBB         0.982
                                                      ICal   Delta
                                   RT    RT   Rel. IT  RF      RF    %B
                                 Lo/Hign
                                  17:20   19:21 1.0009   1.014 -0.032  -3.2%
                                  21:20
 Kane               RF   Ratio
                          1K2
 13C12-2378-TCOF   1.3S4  0.78

 13C12-2378-KH3   1,002  0.77
                                                      ICal   Delta
                                   RT    Iff  Hal. RT  HF      RP    %D
                                 Lo/High
                                  ISsSl  20s31 1.0000   1,388 -€.034  -2,5%
                                  21:31
                                  17:20  19:20 1.0000   1.067 -0.065  -6.1%
                                  21:20
 Recovery Standard Sumnary
 Mama               RF   Ratio
                           It2
 13C12-1234-TCDD   1.000   0.79
Lo/High
                                                      ICal   Delta
                                          RT  Rel. RT  SF      RF    %D

                                         19:33 1.0112   1.000  0.000   0.0%
                                 Faga   1
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                    Printed: 19:56 09/19/97

-------
                       Appendix C.2




Analytical Data - Semivolatile Organic Hazardous Air Pollutants

-------

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                            CASE NARRATIVE
                    Analysis of Samples for the Presence of

                           Semivolatile Analytes by

 High-Resolution Gas Chromatography / Low-Resolution Mass Speetrometry
                       METHOD 8270A Rev. 1 (7/92)
            Date:


            Client ID:
September 22,1997

Pacific Environmental Services
            TLI Project Number: 43230
This report should only be reproduced in full. Any partial reproduction of this report requires permission from
Wangle Laboratories, Inc.
                                           Triangle Laboratories, Inc.
                                 801 Capttola Drive            P.O. Box 13485
                                 Durham, NC 27713-4411        Research Triangle Park, NC 27709-3485
                                 919-544-5729               Fax # 919-544-5491        1

-------
TRIANGLE LABORATORIES, INC.                         September 22,1997
CASE NARRATIVE                                                     43230

Objective: Analysis of five MM5 train samples for Method 8270 polynuclear aromatic
hydrocarbon (PAH) semivolatile compounds and Clean Air Act (CAA) semivolatile compounds.
Method:

Five MM5 train samples were received by Triangle Laboratories, Inc. on ice at 5°C in good
condition on September 12,1997. The samples were stored in a cooler at 4°C prior to extraction.
The XAD traps used for sampling were pre-spiked with 100 micrograms (ug) of terphenyl-dn
prior to sampling. Prior to extraction, the XAD, filter, and rinses were spiked with 100 ug of
phenol-ds, 2,4,6-tribromophenol, l,4-dibromobettzene-d4» and pyrene-dio. These portions of the
MM5 trains were Soxhlet extracted with methylene chloride for 16 hours. The impinger
condensates, when present, were spiked with 100 ug of the surrogate standards anthracene-dlO,
2-fluorobipheayl, nitrobenzene-dj and l,3,5-tricblorobenzene-d3 before being extracted with
methylene chloride using a separatory funnel.  The extracts were combined and brought to a final
volume of 1.0 mL for the semivolatile analysis. The analysis is based on the guidelines of Method
8270A Rev.  1 (7/92). The results reported relate only to the items tested.

The internal standards, l,4-diehlorobenzene-d4, naphthalene-dg, acenaphthene-dio, phenanthrene-
dio, chrysene-dn, and perylene-dia, were added to the extracts such that the final internal standard
concentration was 40 ug/mL immediately prior to analysis by GC/MS.

The GCMS analysis conditions are listed below:

GC Conditions:
  Column:                              J&W DB5-625,30m x ,32mm x l«m
  Program:                             35C, ramp at 12C/min to 285C, hold for 2 min.
                                       ramp at 8.5C/min to 315 C, hold for 6.5 min.
  Carrier Gas:                          Helium

MS Conditions:
  Instrument:                           HP MSD, Chemsystem and Target data systems
  Scan:                                35-550 amu at 1.67 scan/sec
  Interface:                             Capillary, Injector:  250C, Detector:  275C
Report:

Enclosed with the case narrative are the sample identification index, project summary sheets,
client and TLI chain of custody sheets, wet laboratory extraction information sheets, GC/MS
tracking forms, and analytical run logs. The sample identification index correlates the client
sample name, TLI sample number and the analytical file name for the each sample. The project
summary sheets list the amounts of analytes detected in gray and list the estimated detection limits
in parentheses for analytes which were not detected.

The data are reported as quantitation reports, chromatograms, interim reports, and spectra of
detected target analytes. The quantitation report header lists the TLI project number, analysis

-------
v TBIANGLE LABORATORIES, INC.                         September 22,1997
  CASE NARRATIVE                                                       43230

  method, instrument sample file name, and client sample name. The client project number, TLI
  sample number, calibration file, dilution factor, and date received, extracted, and analyzed are also
  listed in the quantitation report header. The response factors used for all calculations are from the
  continuing calibration listed in the header. All initial and continuing calibration data are located in
  the back of the data package.  The amount reported for each target analyte detected in the
  samples is reported in total ug. The retention time (RT) will be Hsted for all internal standards
  and analytes which are detected. If a target analyte is not detected, it will be flagged with a "U"
  and a detection limit will be listed. Estimated detection limits are calculated using an area of
  10,000 for all analytes which were not found in the samples. The estimated detection limits
  reported are the average detection limits achievable over time on an instrument type. The actual
  detection limit for a given compound on a given day may vary from the estimate reported. The
  quantitation limit for all analytes is half of the low point of the initial calibration adjusted for
  dilution when appropriate. Below this point the calibration cannot be considered to be linear.
  Any amounts reported at a level below the quantitation limit will be flagged with a "J" and should
  be considered estimated. If a target analyte is found at a level exceeding the upper calibration
  limit, it will be flagged with an "E" and should also be considered estimated. Any analytes flagged
  with a "B" on the sample topsheets were detected in the associated laboratory blank. All target
  analytes are quantitated against the internal standard preceding them on the target analyte list.
  Surrogate standards are quantitated against the internal standard with the matching internal
  standard reference number. For example, phenol-d$ has 1 in the IS Ref column and would be
  quantitated against the internal standard which has IS 1 listed in the flag column. If an internal
  standard area is above or below the quality control limits as defined by  the continuing calibration,
  it will be flagged with "High" or "Low" in the flag column.

  Immediately following the quantitation report are two pages which comprise the total ion chro-
  matograms. Labeled internal and surrogate standards present in the sample have their identifica-
  tions and retention time printed above their peak on the chromatogram. The chromatogram is
  followed by the interim report. On the interim report a $ is indicative of a surrogate standard and
  a * represents an internal standard. The interim report from the instrument is followed  by the
  target spectra of detected compounds. Four spectral plots are included  for each compound: a raw
  spectrum of the peak, a background subtracted version of the same spectrum, a library  spectrum
  of the compound, and a plot showing the percent difference between the library spectrum and the
  background subtracted spectrum. Extracted ion current profiles are plotted on the right-hand side
  of the page showing the quantitation  mass and one or two other prominent ions known to be
  present in  target compound as  they appear in the sample peak.
  Results:

  All samples were extracted and analyzed within the Method 8270 holding times.

  Please note that several target analytes were found at levels below the quantitation limit in the
  laboratory blank. These analytes should not be considered truly present in the native samples
  unless detected at a level at least five times the level in the blank. If the analyte level in the sample
  is twenty times the level in the blank, the blank contribution can be considered statistically
  insignificant.

-------
TRIANGLE LABORATORIES, INC.
CASE NARRATIVE
                                 September 22,1997
                                              43230
Bach sample was processed twice, once against the calibrations containing PAH compounds and
once against the calibrations containing CAA compounds. Therefore, each sample reported
contains topsheets and interim reports for both the PAH and CAA analyses as well as a chroma-
togram and spectra for all analytes. Please note that the surrogate standards have been reported
from the PAH analyses only.

All internal standard areas were within Method 8270 quality control criteria.

With the exception of terphenyl-d!4 in all the samples and l,3,5-triehlorobenzene-d3 in sample
BO-0010-2 , all surrogate standard percent recoveries were within in-house quality control limits
as defined by the following 95 percent confidence intervals:
Surrogate Standards

1,3>5-trichlorobenzene-d3
1,4-dibromobenzene-d*4
2,4,6-tribromophenol
2-fluorobiphenyl
aathracene-dio
nitrobenzene-ds
phenol-ds
pyrene-dio
terphenyl-di4
            Mean

            55
            69
            78
            77
            77
            68
            70
            80
            77
95% confidence interval
      22.19
      34.65
      32.43
      37.70
      37.45
      30.52
      28.39
      33.65
      18.86
87.75
103.19
123.81
115.87
116.75
105.65
112.40
126.15
135.64
Sample Calculations:
Response Factor, RF =
Area analyte x Amt Is
Area IS x Amt analyte in the ccal
Amount ug =
Area analyte x Amt IS x DF
Area IS x RF
Where:

Amt IS = amount of internal standard = 40 ug
Amt analyte in the ccal = amount of analyte in the continuing calibration = 50 ug
DF = dilution factor

-------
TRIANGLE LABORATORIES, INC.                       September 22,1997
CASE NARRATIVE                                                   43230

The data reported has been judged to be valid and in compliance with the guidelines of Method
8270A Rev. 1 (7/92) except as noted above. Should you have any questions about this project,
please feel free to contact our Project Scientist, Amy Boehm, at (919) 544-5729, extension 268.
For Triangle Laboratories, Inc.,

Report Preparation:                                  Quality Control:
                                                           M
Sarah A. Hubbard                                  ~T?"cxCxy   VVa i^cf e U
Report Preparation Chemist                           Report Preparation Chemist
The total number of pages in this data package is.

-------
                     TRIANGLE LABORATORIES, INC.

                LIST OF CERTIFICATIONS AND ACCREDITATIONS
ENVIRONMENTAL

American  Association  for  Laboratory  Accreditation. Certification  pending.  Certificate
Number 0226-01. Accreditation for technical competence in Environmental Testing.(fncluding
Waste Water, Sol/Haz Waste, Pulp/Paper, and Air Matrices)  Parameters are AOX/TOX,
Volatiles, Pesticides, PCB's, BNA's, and Dioxin/Furan. Method 1613 for Drinking Water.

State of Alabama, Department of Environmental Management Expires December 31,1997.
Laboratory i.D. #'40950. Dioxin in drinking water.

State of Alaska, Department of Environmental Conservation. Expires December 21, 1937.
Certificate number OS-00397. Dioxin in drinking water.

State of Arizona, Department of  Health Services.   Expires May 26,  1998. Certificate
#AZ0423. Drinking Water for Dioxin, Dioxin in WW and S/H Waste.

State of Arkansas, Department of Pollution Control and Ecology.  Expires February 13,
1998. Pulp/paper, soil, water, and Hazardous Waste for Dioxin/Furan; AOX/TOX.

State of California,  Department of Health Services.  Expires August 31, 1999. Certificate
#1922. Selected Metals in Waste Water; Volatiles, Semi-volatiles, and Dioxin/furan in WW and
Sol/Haz Waste.  Dioxin in drinking water.

State  of Connecticut,  Department of Health Services. Expires September 30, 1997.
Registration #PH-Q117.  Dioxin in drinking water.

Delaware Health and  Social Services.  Expires December 31, 1997. Certificate #NC  140.
Dioxin in drinking water.

Florida Department of Health and Rehabilitative Services. Expires June 30,  1998.Dioxin in
DW. Drinking Water ID HRSi 87424. Metals, Extractable Organics (GC/MS), Pesticides/PCB's
(GC) and Volatiles  (GC/MS) in  Environmental Samples.  Environmental water  ID HRS#
E87411.

Hawaii Department of Health.  Expires March 1, 1998. Dioxin in drinking  water. "Accepted*
status for regulatory purposes .
 Revised 913/97 RM

 Printed »18«7

-------
Idaho Department of Health and Welfare.  Expires November 30, 1997. Dioxin in drinking
water.

State of Kansas, Department of Health and Environment Expires  January  31, 1998.
Environmental Analyses/Nan potable Water and Solid and Hazardous Waste.  Method 1613
for drinking water. ID #'s - Drinking water and/or pollution control - E-215. Solid or Hazardous
Waste - E-12Q9.

Commonwealth of Kentucky, Department for Environmental Protection. Expires December
 31,1997.1D#90060. Dioxin in drinking water.

Maryland Department of Health and  Mental  Hygiene.   Expires September  30, 1997.
Certification #235. Drinking water by Method 1613A.

State of Michigan, Department of Public Health.  Expires March 31, 1998. Drinking water by
Method  1613.

Mississippi State Department of Health. No expiration date..  Dioxin in drinking water.

Montana Department of Health and Environmental Services. Expires December 31, 1997.
Dioxin In drinking water.

State of New Jersey,  Department of Environmental Protection and Energy. Extended by
state. Temporary certificate until December 31,1997. ID £67851. BNAs and Volatiles. Dioxin in
drinking water.

State of New Mexico, Environment Department  Certification pending. Dioxin in drinking
water.

 New York State Department of Health. Expires  June 30, 1997, ID #11028.  Environmental
Analyses of non-potable Water, Solid and Hazardous Waste. Method 1613 in DW.

 State of North  Carolina, Department of Environment Health and Natural Resources
 Expires August 31, 1i99. Certificate # 37751.  Dioxin in drinking water.

 State of North Carolina, Department of Environment, Health, and Natural  Resources,
 Division of Environmental Management  Expires December 31,  1997. Certificate # 485.
 Metals, pesticides & PCBs, semi-volatiles and voiatiles; TCLP,

 Norm Dakota  State  Department of  Health  and Consolidated  Laboratories.   Expires
 December 31,1997. Certificate # R-076. Effective October 4, 1993. Dioxin in drinking water.
 Reuisad 3/1S/97 RM

 Printed M1S9T

-------
Oklahoma Department of Environmental  Quality.  Expires October 31, 1997. Laboratory
#9612. Dioxin by 1613A, 8290 and 8280.

State of South Carolina, Department of Health and Environmental Control,  Expires June
30. 1997. Certificate number #99040001 (drinking water). Expires August 31, 1999. Certificate
number #99040002  (other  parameters).  Dioxin/Furans, SNA, Valatiles, and PCBs/pestlcides
under Clean Water Act, 2,3,7,8-TCDD for Drinking Water, and Organic extractables for Solid
and Hazardous Waste.

State of Tennessee, Department of Environment and Conservation. Expires February 5,
1999. ID #02992.  Method 1613 Drinking water only.

U.S. Department of Agriculture Soil Permit  Expires September 30, 2001. Permit No.  S-
3790. Under the authority  of the Federal Plant Pest Act, permission  is granted to receive
foreign soil samples for use in laboratory analysis.

U.S. Army Corps of Engineers. Expires November 30, 1997. Validated to perform methods
8280 & 8290 for Lockboume Landfill Site Investigation, Defense Distribution Depot Projects,
and assorted projects for the USAGE North Pacific Division Laboratory.

U.S. EPA Region V, Expires November 14,1999. Dioxin in drinking water.

U.S. EPA Region Vlll, for the State of Wyoming. Expires November 13, 1997.  Dioxin in
drinking water.

State of Utah, Department of Health. Expires December 31, 1997. Certificate Number E-166.
Certification for the following parameters: Semi-Volatiles and Voiatiles under RCRA; Volatiles
under Clean Water  Act; Dioxin/furans by Method 8280; Drinking water for Dioxin by Method
 1613; Metals including Mercury and Microwave Digestion.

 Commonwealth of Virginia, Department of General Services, Division of  Consolidated
 Laboratory Services. Expires June 30,1998. ID # 00341. Dioxin in drinking water.

 State of Washington, Department of Ecology. Expires September 1998. Lab Accreditation
 Number C067. Scope of Accreditation applies to water analyses for Polychlorinated Dibenzo-
 p-dioxins and Polychlorinated Dibenzofurans, SNA Extr (Semivolatile) Organics and Purgeable
 (Volatile) Organics.

 State of Washington, Department of Health. Expires April 30,1998. Dioxin in drinking water.
  Lab I.D. 129

 State of West Virginia, Department of Health. Expires December 31, 1997. Certificate No.
 9923(C). Dioxin in drinking  water.
 Revised 9/18/97 RM

 Printed 9f18S?
                                                                                 8

-------
State of Wisconsin,  Department of Natural Resources.  Expires  August 31,  1998,
Laboratory  ID  Number 999869530. Certification for the  following categories  of  Organies:
Purgeable, Base/Neutral, Acid, RGBs, and  Dioxin. Expires November 14. 1999. Laboratory ID
999869530. Dioxin in drinking water.

PHARMACEUTICAL

Drug Enforcement Agency (DEA).  Expires  November 30, 1997.  Registration number
RT01195835. Controlled substance registration for schedules 1,2,3,3N,4,5.

N.C. Department of Human Resources. Expires October 31, 1997. Registration number NC-
PT 0000 0031, North  Carolina controlled substances registration. Application submitted for
renewal.

Food &  Drug Administration  (FDA) Registration. Expires  June  1998.  ID #'s 001500
1053481. Annual registration of drug establishment. Annual registration of drug establishment

OTHER

Clinical Laboratory Improvement Amendments (CLIA) Registration. Expires May 30, 1999.
ID  # 34D0705123.   Department of Health  & Human  Services, Health Care  Financing
Administration.

U.S. EPA  Large  Quantity Hazardous Waste Generator.   No expiration  date.  EPA ID
SNCD982156879. Permit indicates that the laboratory is a large generator of hazardous waste.

North Carolina Radioactive Materials License.   Expires April 30 1998. License No. 032-
0954-1. License authorizes the licensee to receive, acquire, own, possess, transfer, import and
use such radioactive materials as designated.

North Carolina General License for Radiation Protection. No. expiration date. License No.
032-875-OG.  The general license applies only to radioactive material contained in  devices
which have been manufactured and labeled in accordance with specific requirements.
 Revised 9J18/97 RM

 Printed 9/18/97

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                                        Triangle Laboratories of RTF
                                Sample Identification Index for Project: 43230
BO-0010-1
BO-0010-2
BCMJ010-3
FB1-0010
M0010 Blank
SBLK091497
183-2-2A-E
183-2-3A-E
183-2-4A-E
183-2-1A-C
183-2-5A-C
SBLK091497
VG290
VG291
VG292
VG287
VG286
VG284
 Triangle Laboratories of RTF, Inc.
 801 Capitals Drive • Durham, North Carolina 27713
 Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                      fto(_Sumv4.0
                                                        10

-------
Client ID:
               Triangle Laboratories of RTF
            Project Summary for Project 43230
BO-00104        BO-0010-2        BO-0010-3
                                                                                 FB1-0010
                                                               M0010 Blan
Filename :
TLIId :
Matrix ;
Units :
VG290
183-2-2A-E
MM5
u§
VG291
183-2-3A-E
MM5
US
VG292
183-2-4A-E
MM5
wg
VG287
183-2-1A-C
MM5
ug
VG286
183-2-SA-C
MM5
U8
Naphthalene
2-Methylnaphthalerie
2-Chloronaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
BenEo(k)fluoranthene
Benzo(e)pyrene
Benzo(a)pyirene
Perylene
Indeno(l,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
(0.25)

(0.31)
(0.40)
(0.43)
(0.54)
(0.52)
(OJ3)
(040)
(0.60)
(0.72)
(0.98)
(0.82)
                                                    (031)
                                                    (0.28)
                                                    (0.42)
                                                    (0.53)
                                                    (0.57)
                                                    (0.89)
                                                    (037)
                                                    (0.88)
                                                    (1.00)
                                                    (1.00)
                                                    (120)
                                                    (1.62)
                                                    (1.37)
                                         (0-23)

                                         (0.30)
                                         (0.38)
                                         (0.41)
                                         (0.54)
                                         (0.52)
                                         (0.53)
                                         (0.60)
                                         (0.60)
                                         (0.72)
                                         (0.97)
                                         (0.82)
(027)
(0.18)
(029)
(026)
(022)
(023)
(021)
(0.26)
(0.33)
(0.35)
(0.45)
(0.44)
(0.44)
(050)
(050)
(0.60)
(0.82)
(0.69)
(0.25)
(0.26)
(0.18)
(028)
(025)
(021)
(022)
(0.20)
(025)
(032)
(0.35)
(0.45)
(0.44)
(0.44)
(OJO)
(0.50)
(0.60)
(0.81)
(0.69)
                                         (  ^Estimated Detection Limit    Page 1
Triangle Laboratories of RTF, Inc.
801 Capitola Drive » Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                        SsvarvlS
                                                           Printed: 15-22:56 09/22/97

-------
                                            Triangle Laboratories of RTF
                                        Project Summary for Project 43230
'Client ID:                    SBLK091497
Filename :
TLIId :
Matrix :
Units :
VG284
SBLK091497
XAD
"8
 Naphthalene              <  ,. ^  - J.6*
 2-MethylnaphthaIene         —    (0.28)
 2-Chloronaphthalene               (0.28)
 Acenaphthylene                    (0.19)
 Acenaphthene                      (0.30)
 Fluorene                           (0.27)
 Phenanthrene                      (0.24)
 Anthracene                        (0.25)
 Fluoranthene                      (0.23)
 Pyrene                             (0.26)
 Benzo(a)anthracene                (0.33)
 Chrysene                          (0.35)
 Benzo{b)fluoranthene              (0.44)
 Benzo(k)fluoranthene              (0.43)
 Benzo(e)pyrene                    (0.43)
 Benzo(a)pyrene                    (0.49)
 Perylene                           (0.49)
 Indeno(l,2,3-cd)pyrene             (0.58)
 Dibenz(a,h)anthracene             (0.79)
 Benzo(g,h,i)perylene               (0.67)
                                          ( )'Eitimated Detection Limit     Page 2
 Triangle Laboratories of RTF, Inc.                                                                                Savar v3.5
 801 Capitola Drive • Durham, North Carolina 27713                                                      PrinfecL IS J2.-S6 09/22/97
 Phone: (919) 544-5729 • Fax: (919) 544-5491                                                                            •« O

-------
Client ID:
               Triangle Laboratories of RTF
           Project Summary for Project 43230
BO-001G-1        BO-0010-2       BO-0010-3
                                  FB1-Q010
                                   M0010 Blan
Filename:
TLIId  :
Matrix  :
Units   :
VG290
183-2-2A-E
MM5
ug
VG291
183-2-3A-E
MM5
VG292
183-2-4A-E
MM5
ug
                                                                               VG287
                                                                               183-2-1A-C
                                                                               MM5
                                                                               "g
            VG286
            183-2-5A-C
            MM5
n-Nitrosodimethylamine           (0.79)
Cumene
Phenol
Aniline                           (030)
Benzyl Chloride                   (0.17)
1,4-Dkhlorobenzene
2-Methylphenol                   (032)
Acetophenone
n-Nitrosomorpholine              (0.73)
o-Toluidine                       (034)
Hexachloroethane                 (0.74)
l^-Dibromo-3-chloropropane      (0.87)
bis-(2-Chloroethyl)ether            (0.71)
N,N-Diethylaniline                (028)
3/4-Methylphenol                 (0.46)
Nitrobenzene                     (024)
N,N-Dimethylaniline              (0.26)
Isophorone                       (023)
o-Anisidine                       (0.56)
1,4-Phenylenediamine             (0.42)
     _, , . .   .           re:Wv:*&:£tf£*:::vAv::;W£
12,4-Trichlorobenzene
Hexachlorobutadiene              (0.57)
a,a,a-Trichlorotoluene              (0.28)
iiyorcxiuiriQne           Msvi^MfSi^fiSMI^^si
2-Chloroacetophenone             (0.24)
Hexachlorocyclopentadiene        (0.56)
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
Biphenyl
Dirnethylph thalate
4-Nitrophenol
2,4-Dinitrotoluene
Dibcnzofuran            ||
4,6-Dinitro-2-methylphenol
Trifluralin
                                   (1.45)
                                   (0^83)
                          >^f55^sM^^M^w^^-
                                   (2.05)
                                   (0.98)
                                                   (0.91)
                                                   (034)
                                                   (020)
                                                   (0.60)
                                                   (0.84)
                                                   (039)
                                                   (0.86)
                                                   (1.00)
                                                   (0.82)
                                                   (032)
                                                   (058)
                                                   (0.31)
                                                   (032)
                                                   (0.29)
                                                   (0.72)
                                                   (053)
                                                    (0.73)
                                                    (0.35)
                                                    (0.69)
                                                    (0.30)
                                                    (0.73)
                                        (0.68)
                                         (0.26)
                                         (0.15)
                                         (0.45)
      (0.63)
      (0.29)
      (0.64)
      (0.75)
      (0.62)
      (0.24)
      (0.41)
      (0.22)
      (023)
      (0.21)
      (0.51)
      (0.37)

      (052)
      (0.25)
      (0.49)
      (0.21)
      (0.52)
                                        (0.72)
                                        (0.27)
                                        (0.16)
                                        (0.36)
                                        (0.48)
                                                         (0-66)
                                                         (0.31)
                                                         (0.68)
                                                         (0-79)
                                                         (0.65)
                                                         (0.25)
                                                         (0.42)
                                                         (0.22)
                                                         (0.23)
                                                         (0.21)
                                                         (0.52)
                                                         (0.38)
                                                         (0.41)
                                                         (OJ3)
                                                         (0.25)
                                                         (050)
                                                         (022)
                                                         (052)
                                                         (0.65)
                                                         (0.64)
                                                         (0.20)
                                        (0.71)
                                        (0.18)
                                        (0.26)
                                        (0.16)
                                        (035)
                                        (0.47)
                        (1.89)
                        (1.09)
                        (027)
                        (2.68)
                        (129)
      (1.92)
      (0.92)
(1.36)
(0.78)
(0-19)
(1.93)
(0.93)
                                                         (0.65)
                                                         (0.30)
                                                         (0.66)
                                                         (0.77)
                                                         (0.63)
                                                         (0.25)
                                                         (0.42)
                                                         (022)
                                                         (023)
                                                         (021)
                                                         (0.52)
                                                         (038)
                                                         (0-41)
                                                         (OJ3)
                                                         (0-25)
                                                         (0-49)
                                                         (0.22)
                                                         (051)
                                                         (0.63)
                                                         (0.62)
                                                         (0.20)
                                                         (0.25)
                                                         (132)
                                                         (0.76)
                                                         (0.19)
                                                         (1ST)
                                                         (0.90)
                                        ( (-Estimated Detection Limit    Page 1
 Triangle Laboratories of RTF, Inc.
 801 Capitate Drive * Durham, North Carolina 27713
 Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                             SavatvS.S
                                                                 Flirted: 133*48 09/22/97
                                                                                                        13

-------
Client ID:
              Triangle Laboratories of RTF
           Project Summary for Project 43230
BO-0010-1        BO-0010-2       BO-0010-3
                                                                             FB1-0010
                                                  M0010 Blan
                                                  k     -   -
Filename:
TLIId :
Matrix :
Units  :
VG290
183-2-2A-E
MM5
VG291
183-2-3A-E
MM5
VG292
183-2-4A-E
MM5
U8
VG287
183-2-1A-C
MM5
"g
VG286
183-2-5A-C
MM5
2,4-Dinitrophenol
Di-n-butylphthalate ~*
Hexachlorobenzene
4-Aminobiphenyl
Pentachlorophenol
Pentachloronitrobenzene
4-Nitrobiphenyl
Benzidine
4,4'-Methylenedianiline
Dimethylamino azobenzene
3,3'-Dimethylbenzidine
3,3'-Dimethoxybenzidine
3,3'-Dichlorabenzidine
Methylene bis-chloroaniline
bis(2-Ethylhexyl)phthalate~ ' f;~ '"
(3.47)
SJ8%
(0.65)
(0.26)
(1.00)
(1.54)
(0.69)
(053)
(1-29)
(0.99)
(0.77)
(158)
(1.30)
(2.26)
0iIM*
(454)
- " 358 '
\ X. 454
(0.31)
',"',"Lr,*J>;i$£, «\"
(1.89)
(0.85)
(0.69)
(1.71)
(131)
(1.01)
(2.08)
(1.72)
(2.99)
'7™"™f7";5M ^
(3.26)
xM
ftsr
(0-24)
;'-*•» '-xstfflf
(1.43)
(0.64)
(050)
(1.23)
(0.94)
(0.73)
(150)
(1.24)
	 (2-16)
"™''-^-)#37
(327)
335
(0.61)
(0.24)
(0.93)
(1.43)
(0.64)
(0.43)
(1.05)
(0.80)
(0.62)
(1.28)
(1.06)
(1.83)^
"'"'' " "" \&9S '
(3.16)
"iaoi
(059)
(0.23)
(0.90)
(1.39)
(0.62)
(0.42)
(1.04)
(0.80)
(0.61)
(1.27)
(1.05)
(1.82)
" "".Ifir
                                        ( )-Estimated Detection Limit
                                                                  Page 2
 Triangle Laboratories of RTF, Inc.
 801 Capitola Drive • Durham, North Carolina 27713
 Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                           Savarv3.5
                                                               Printed: 1334:48 09/22/97
                                                                           14

-------
Client ID:
                                          Triangle Laboratories of RTF
                                      Project Summary for Project 43230
SBLKD91497
Filename :
TLIId :
Matrix :
Units :
n-Nitrosodimethylamine
Cumene
VG284
SBLK091497
XAD
"8
(0.85)
- (0.22)
Phenol
Aniline
Benzyl Chloride
1,4-Dichlorobenzene
2-Methylphenol
Acetophenone
n-Nitrosomorpholine
o-ToIuidine
Hexachloroethane
l,2-Dibromo-3-ehloropropane
bis-(2-Chioroethyl)ether
N,N-Diethylaniline
3/4-Methylphenol
Nitrobenzene
NjSJ-Dimethylaniline
Isophorone
o-Anisidine
1,4-Phenylenediarnine
1,2/4-TricMorobenzene
Hexachlorobutadtene
a Aa-Trichloro toluene
Hydroquinone
2-Chloroacetophenone
Hexachlorocyclopentadiene
2/4,6-Trichlorophenol
2,4,5-Trichlorophenol
Biphenyl
Dimethylphthalate
4-Mtrophenol
2,4-Dinitrotoluene
Dibenzofuran
4,6-Dinitro-2-methylphenol
Trifluralin
                                       ( ^Estimated Detection Limit    Page 3
Triangle Laboratories of RTF, Inc.
Ml Capitola Drive « Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                            Savarv3.5
                                                                Printed: 1334:48 Og/M/97

-------
Client ID:
                                          Triangle Laboratories of RTF
                                      Project Summary for Project 43230
SBLK091497
Filename:
TLIId :
Matrix  :
Unite  :
VG284
SBLK091497
XAD
Ug
2,4-Dinitrophenol
Di-n-butylphthalate
Hexachlorobenzene
4-AminobiphenyI
Pentachlorophenol
Pentachloronitrobanzene
4-Nitrobiphenyl
Benzidine
4,4'-MethylenedianiMne
Dimethylanninoazobenzene
33'-Dimethylbenzidkie
3,3'*Dteielhoxybenzidine
33'*Dichlorobenzidine
Methylene bis-chloroaniline
bis(2-Ethylhexyl)phthalat^|
       (3.41)
                                        (  ^Estimated Detection Limit    Pagt 4
 Trianglt Uboratories of RTF, Inc.
 801 CapMa Drive « Durham, North Carolina 27713
 Phone (919) 544-5729 • Pax: (919) 544-5491
                                                                            SavarvSJ
                                                                Printed: 13:34:48 0*^97

-------
 CLIENT CHAIN OF CUSTODY
                                         SAMPLER'S SIGNATURE
                                                                       '  P/Q 03897/0700003270
    From': Pacific Environmental Services
         5001 S. Miami Blvd. Suite 300
        : RTF, NC 277Q9
    Project Tell City, IN            •
                 Contact; Frank Meadows
                  Phone: 919-941-0333
                    fax 919-941-0234
                   P,O.#:	
  (PESOS 1MB)
                          If the data will be reported to a state agency, which one?.
                                                                                  Analysis Wanted:


                                                                                                       Total Number of
                                                                                                       Containers:
  Sample Name
                    Date
Time
                                  Comp
                                           Grab
        Matrix
Sample Ami.
.  Remarks
      -00(0
                                                  MM-,!
                                                  4'***'
                                                  /fvfcT
  0 - Go/0-/
                   f/f/17
                                                     Y
           -2*
$0 -OOfQ "
                                                                                  y
Relinquished By/Sign.
                                Date/Time
                                                               Relinquished By/Sign.
                                                                           /r"V-^"nT	in /
                                                               Relinquished By/Sign.
                                                                                              Date/Time
                                                                               Received By/Sign.
Relinquished By/Sign.
                                Date/Time
         y   7
Received By/Sign.
Received for Laboratory By/Signature
            Date/Time
                                      »j&
                                                                                              Date/Time
                                                                               Received By/Sign.
                                                              Send Samples to: Triangle Laboratories, Inc.
                                                                            Attn: Sample Custodian
                                                                            801 Capitola Drive
                                                                            Durham, NC 27713 USA
                                                                     Phone: (919) 544-5729 • Fax: (919)544-5491

-------
                     ANALYTICAL REQUEST AND CHAIN OF CUSTODY
                                                                                          oo
RECOVER*
PERSON:
SAMPLE   -*• »|     1  /r
TECHNICIAN: f. fibtr *.&.?*•/ / fa,
-I
 REUI
iUNQUISHER'jB NAME,

   *lt
REUINQUISHBTS SIGNATURE/
   f21:^^^^
                                             OT9 ^NATURE '"
                                               •^p-
                                                                         SHIPPER'S NAME AND 10 NUMBER
                                                                          q/n/j7

-------
09/U9/97   10:19
S18199410234
PES RTF NC
                  OH
METHOD 23 6BB/GDF SAMPLE RECOVERY DATA
C>O|Q

Plant U/AuPA^M . ^H^JOHV
Sample Date: ^ 1 9 1^"}
Sample Location: Rfl ^-tKU^
Recovery Date: >cl|d Hi-
.Filter No,(s): F"£> - O0i& - }
.P. Dw-Lfer
XAD-2 Trap No.(sX Ffe -
TtfSfff
Run No.: F6-aoia-j
Job No.: SHW. Oz>3

"bDio- 1

Sample Recovery Person: KT^ o&

Irnpingers
Final wt
Initial wt.
Netwt.
XAD -2
Trap
—
—
—
1
(knockout)
MV^.-d
H>-!-^
D.O
Sl^^^'^SlS^^iS^S^i^SJiSSS
2 3
(IQOmlHZO) (100mlH2O]
(untipped) (tipped)
^Kt^.'s >Z-S-t
T-1-^.^ T-K'I
D • o b .£>
4
1 (knockout)
(untipped)
^^.^
bl1--S"
o .0
Silica gel
(untipped)
99^ ^ g
fe^l'^ f
O-D g

Train System: HMI6 -TfcAiO /tor

Loading- MSA,<

ID'- F)- \O






Used- 3Ot> Color -giu^ % Spent- B.T2"
Condensate Observed In Front Half: f\)o^

Filter Container No, |
XAD Module Container No.: 5
Probe (FH)
Probe '(FH)
& Back Half Rinse (Acetone-) Container No.: {g
«X
& Back Half Rinse PC
>beee)- Container No.: — -
Impinger Contents Container No.:
Impinger Rinse (Acetone/MeCE)
Container No.: — —


marked/sealed: *~J^-
marked/sealed: Q^-~
Liquid level v—'
marked/sealed: ^li.
LJquid level
marked/sealed: 	
Liquid level
marked/sealed: "~~
Liquid level 	 .
marked/sealed:
-


1

-------
08/09/97   10:18
S18183410234
PES RTF NC
                                              O
                                                                      ID
1(003

ME

. 1 HUD £.Jf*iQUn3\Jt~ SAMr
»LE RECOVERY DATA
Plant WAuPAcft P-ouOpa-Y
Sample Date; ^talTV
Sample Location:

Recovery Date: ' ^ 1'1\*\V
Sample Recovery Person: R-VL
Filter No.Cs): r}0-5oio-|
1 L\rrv.en-
XAD-2Trap No.(s): 8O - bt
Run No.: Bt)-ooib-i
Job No.: Sm^. 0£>3

3i* -\
BE_
\t ••^•i^ZZ?}^£"S??$£^S$^^~'^'&?;i^^^
Impingers XAD - 2
Trap
Final wt. —
Initial wt.
Net wt. — •
(knockout)
55D.S
K^.'i
Ste-'D
2
(100 ml H2O)
(untipped)
l*ii.S
ms-s
0 Cs
3 4
(IdOmlHaO) (knockout) Silica gel
(tipped) (untipped) (untipped)
•^2.5,5 Crli.M ^ifc.o g
7ZS-I UI1-S ^^.^ a
-/.& 3
°\ 2(ff,\ Q

Train System: f P
Probe: u? C 'fliS
A f\en\oc

Fitter: Color- LJ^wt TAM
Irnpinger Contents:
Silica' Gel: @Grams
.tn -rr(
i 2s) 'T^Aiii'

I &QV it>; V- 1®


Loading - ) »<=,MT
^E JE >^z.b
Used- 350 Color-


)4.b)u* % Spent- ^0
Condensate Disserved In Frortt Half: K) owe.

Filter Container No.
' 11


XAD Module Container No.: I A
Probe (FHUt Back Half Rinse (Aeetene) Container No.: \^>
Probe '(FH) & Back Half Rinse (Toiuono) Container No.: )\
Irnpinger Contents Container No.
Irnpinger Rinse (Acs^wrc/MeClZ)
: '^
Container No.:

. N

na
marked/sealed: 577.
marked/sealed: Vf~
Liquid level
marked/sealed: £_£
Liquid Eevei
marked/sealed: <^
-------
09/08/97   10:10
               ©18199410234
                          FES RTP NC
               METHOD
                                      SAMPLE RECOVERY DATA
Plant:
                                                            Run No.: SO-
Sample Date
:  c] 1 1
                               Filter No.fs):
                                             - PtXO ~
   Job No.:
                             Oi>3
Sample Location: BAfiH6U^£.
Recovery Date: ^ ||o fa}      XAD-2 Trap No.fs):    6b- D>'0 -
Impingers
Final wt
             XAD-2
              Trap
           1
       (knockout)
                     551.4
                             (100mlH20)
                              (untipped)
(100mlH2O)
  (tipped)
(knockout)
(untipped)
Silica gel
(untipped)
Initial wt.     ~     M^b^i    K^-l-	^52. -I-
Netwt   I   ~     I                       I         "~


Train System:   M^l?  TlAifJ   I   £>DX  i£>: K/-'D
Probe:   .U_v ^Ml^	
Filter: Color- uVv DcswyN	Loading-  LiOJcT
                                              l^^^/^i:S&fj%^ff?^^^&
                                              l-jni.T.g^^gr^:^^^^^-?^^-^Ss.^£.a,^^i=
-------
09/08/a?   10:19    ©Iil98410234
res RTF NC
^003
METHOD go GDD/GDF SAMPLE RECOVERY

Plant: \VJ$U.PAcA . r"0n
Sample Date: c|piel"V
Sample Location: B A^ Kv) U *b
*
Recovery Date: ®\ ] U \ IT

Filler No. (s): S*> - D"DID -3
F OviTl£-
XAD-2 Trap No.(s): BO - &
tf//£f-f
DATA
Run No.: S^-PL-IO -3
Job No.: StfM' cd 3

C1 1"0 - 2,
Sample Recovery Person: \ffi\ fi^-—

1
Impingers XAD-2 (knockout)
Trap
Final wt. «• 53tc
Initial wt. - "-RS^
Net wt. -
2 3
(iaOmlH2O) (100mlH2O) (k
(untipped) (tipped) (L
TfV.o 7^-2^ /
T-M&4 V2-3-T i<


4
nockout) Silica gel
intipped) (untipped)
jr2-*T'7 ^'2(3,$ g
>tj%tt.ci. g)^b.O q
a

Train System: G-PA MerMo
Probe: v0 ^L$<£t3>
Filten Color- '^ j)fiwv\
Q D^^o / jHA-iw i ft-. M

Loading- |j£ v^
Impinger Contents: O CA r
-fO



Siliea'Gel: @Grams Used - ^00 Color- \\. blue % Spent- b^
Condensate Observed In Front Haift AJ^i4£.

Fitter Container No. ^ '
XAD Module Container No.: P^ x
" <%C!i/W^V^«t .,
Proba (FH) & Back Half Rinse (Acetone) Container No.: y\
Probe -(FH) & Back Half Rinse (Tefae«e) Container No.: 3 Z
Impinger Contents Container No.
M-U-,*

33
Container No.: 3*~
marked/sealednf
• marked/sealed^X^
Liquid level - x?
marked/sealed^/.
Liquid level "/H
marked/seafedcS
Uquld level /j?
Liquid level /^
marked/sealed^tL-
-
.'no

-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
                                    Project No.
                                                          Page        of
                                    Client
                                    Location
 Prepared By
Date  Checked By   Date   Sheet Title

                                 ^
                               _ ._X(>._.?^cJ.A.'iX«^,* „ _;
                                                                                              23
                  WASHINGTON, DC»RESEWCH THIANQLE PARK, NO • LOS ANGELES, CA • CINCINNATI, OH

-------
PACIFIC ENVIRONMENTAL SERVICES, INC.
                                     Project No.
                                                          Page
of
                                     Client
                                     Location
 Prepared By
Date   Checked By   Date   Sheet Title
                                                                  .^Ostfa	^fafar	L_
                       __^
                                                                  -V-_ .&»&£_..._
              32o.Y
                  WASHINGTON, DC • RESEARCH TRIANGLE PARK, NC • LOS ANGELES, CA • CINCINNATI. OH
                                                                                             •24

-------
1   Custody Seal      i Absent
1   Chain of Custody  i Present
                                                     'TRIANGLE LABORATORIES,  INC. -- LOO IK RECORD/CHAIN OP CUSTODY*-
                                            Sample Seals:  Absent
                                            Container,,.!  Intact
I   Sample Tags        : Absent
1   Sample tag Numbers: Mot Listed on Chain at  CMntody
|   SMO Forms          : H/A
                                                                                                        TLI  Project Kumber   41230   •
                                                                                                        Client i  PES03  -  Pacific Environmental Services

                                                                                                                                             AS  ,
                                                                                                                                                                  Book
                                                                                                         Date Received
                                                                                                                              09/12/97
U
    Ice  Chest
                                     ICE
                                                     Temp
                                                            5,0 C
                                                                                                         Carrier and Number | MICHAEb HEIBOSHB
JTLI Number 	 Client Sample ID 	 Matrix] To
1 1
LAB j To STORRGE
te/lnlt i Date/anit
i 1
J183-2-1A FB1-0010 14 FILTERJ f- p .. !'• J
1 FB1-0010 COI I iP^HWOLY*^
|!83-2-lB FB1-0010 *S XAD| '
j PB1-0010 * COI j
(1I3-2-1C FB1-0010 ft CH2CL2/CHSQH R1RSB)
| FB1-0010 * COI j
> 1
H 	 I
|183-Z-2A BO-0010-1 811 FILTER]
( BO-0010 * COI j
« j
11H-2-2B BO-0010-1 #12 XADJ
j BO-0010 * COI - 1
II
1
(K3-2-2C • BO-0010-1 R13 FH/RIHSE)
| BO-0010 * COI I
1
I I
|l$3-2-2D BO-0010-1 #14 BH/RIKSEJ
1 BO-0010 * COI j
»f
	 1
|U3-2-2B BO-0010-1 815 1ST INF CONDENSATE)
| BO-0010 * COI I
|li3-2-3A BO-0010-2 »20 . FILTER)
| • BO-0010 * COI |
• 1
(183-2-3B BO-0010-2 021 XAD|
| BO-0010 * COI I
n i
U 1
|l83-2-3C BO-0010-2 #22 FH/R1NSEJ
H BO-0010 * COI 1
II 1 1
u 	 • i
J183-2-3D BO-0010-2 (23 BH/RINSS)
i - BO-0010 • COI |
Ij
	 - 	 	 	 	 ' I
IJ1B3-2-3E BO-0010-2 fit 1ST IMP COBDiWSATB|
j) BO-0010 * COI |

J^\


il«3-2-4R BO-0010-3 #29 FILTER) V \/ i^ijt,^)
1 BO-tOl.0 • COI | \ Y \'
1 Receiving Remarks:
To UB To STORAGE
Date/Init j Date/Init
„
ty




S«L






















To LAB
Date/Init





,

....






To STOIAQE1
Datc/lnit



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Date/Init














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Date/Init







	






DISPOSED \
Date/Init \
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I'  Archive Remarks:
                                                                 •Form Revised 05/27/1997'=.-  Page  1  OF 3«

-------
                                         Sample Seals:  Absent
                                         Container.*.i  Intact
Custody Seal'      i Absent
Chsin of Custody  t Present
Sarnplo Tags :      t Absent
Sample fag (lumbers: Not Listed on  Chain of Custody
                                                  -TRIANGLE  LABOWffemjIi,  IMC,  -•  UX3 Itt RECORD/CHAIH 0? CUSTODY—r
|  TLI Project Number   43230
|  Client]  PESO3 - faciflc Environmental Service!
  Book jj    -Q
I       1
   ui|  .01
       I
iMO Forms * ! N/A
j MM Raaelved J M/U/tl J "^$^fc^y^gfel
Ice Cheat ICE Temp S.O C | Carrier end Number | MICHAEL MELBORNE ' j 2

*/HiCPN 	 Client COC ID 	 * "Location 	

J3-2-4B BO-0010-3 #30 XAD
BO-B010 * C01
IJ-3-4C BO-0010-3 #31 FH/HIKSE
BO-0010 * C01
i3-3-*B BO-0010-J #33 BH/RIHSE
BO-9010 * C01
I1-2-4R BO-0010-3 «SJ 1ST IMP CONDENSATE
BO-0010 • CO!
81-2-SA PIMM BLAHK #42 FILTER BIiSMC
METHOD 0010 BLANKS * C01
13-2-SH XAD TRAP BLANK #43 XAD TRAP BIJINX
' METHOD 0010 BLANKS * C01
•3-2-SC CH2CL2/CH30H BLMJK CH2CL2/CK30H BLANK
METHOD 0010 BLANKS * C01 '




'


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Date/Init
(

„



s.
!<$$*




1
1
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Date/Init
-

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_____

	

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Date/Init














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*






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'













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Date/Init














DISPOSED
Date/Init
	 1

	




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Receiving Remarkai
Archive Remarks:
                                                             -Form Revised OS/27/1997 — Page 2 OF 2»«

-------
                                                                                                                  PAGE 3, OF
Project: 43230
                                                  TRIANGLE  LABORATORIES, INC.
                                         Sample Preparation Tracking & Management Form                       " "     —•-*-_
                                                                            Client: Pacific Environmental Services (FESQ3)
                                                 1       1
                                                 1       1
                                                                                                      -REV" :*7/26/£j (PSTEHF 7)-**
                                                                                                                           27

-------
PROJECT COMMUNICATION TRACKING FORM
page	of	
) ;
~~""TU Project Number: '^T^L' ~ " — ~
•
Use this form to record all exchanges of information between production units as well as personnel
•handling this project Decisions, corrective actions and recommendations must also appear on this
tracking document.
Date •







••-.-*
« . »« *

~*.
_ •
if:--
. jrj .;
~ —
- *—••*.









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Comment / Decision / Resolution / Action / Observation
ficraz. xi^ t*jfA®&- MLTeAP6 Ml ^M
fT) ukt? P,pf U^\r OvtV??' DC.V ?6£? 9Q55cCT 0=5 5"^ 2, -
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-
T»J-» ^ i**,******^. r«a.
TLI PROJECT* 038 9S •' t>, ...V
_~ _: DATE 9/5/97 TV T tu AUK ^ ,H"SrPJ^-'
SPIKE 15|^ TEKPHENVL-D14 ,
^^^SciFir PM1/i . .
.... ^- -- - .;,>^,,^. . ,,,,,. ^,-^^,^R«R:^¥K»^^!^^ ...... - ..
	
•
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. -


* "

•

•

•
                                               28'

-------
P-C-sop
                   [   ] kabala
                                                   05/21/96  15:05:12
                OWL SAMPLE EXTRACTION AND CLEANUP TRACKING FORM
                                SINGLE ANALYSIS
S.NO.
 All
 SOPS
OWL-118
OWL-111
OWL-118
OWL- 118
DSP-128
DSP-128
OWL- 118
OWL-111
OWL-118

OWL-118
DSP-128
OWL-jll8
OWL-118
OWL-111
OWL-111
OWL-111

OWL-111
STEP DESCRIPION
Prep glassware                     .
K/D front half and back half rinses to 1
                                                         ml
                Place filter in thimble and empty'XAD into thimble
                Add FH and BH rinses to thimble
                Spike appropriate surrogates
                Spike appropriate QC spikes, if needed
               . Extracffor is hours with CH2C12 on Sox
                K/D down impinger rinses, if any  JVTfr"
                Pour impinger water in separatory funnel,  measure an
                record pH and volume
                Add impinger rinses to the water
                Add appropriate surrogates to the water
                Adjust pH of H20 to <2 and extract 3 X SO  ml CH2C12
                Adjust pH of H20 to >11 and extract 3 X 60 mL CH2C12
                Filter both Sox and impinger extracts through Na2SQ4,
                K/D both extracts to about 5 mL,  combining upon K/D'ing
                N2 extract to 1 mL,  vialize, and rinse  with 2 X 0.5 mL
                CH2C12
                N2 to 1 mL
                Relinquish to GC/MS                                 v
                                                                          29

-------
                                                                                                                                                                               X
Umtei
Timei 14)10
 sample     ,-
 I  crd TLI_Mun*er..  Customer.Sample. Id	

 tOU    TLI Blink    TLI  SBlanfc

 002    163-2-2A-K   BO-0010-1

 003    1I3-2-3A-B   BO-0010-2

 004    183-2-4A-E   BO-0010-3

 00*    TLI LCS      TIJ  LCS
 0*6     
0.1   2.00  HPW: WATER  COLORtESS   MONB      65  PORTERS

0.1   2.00  CLIM       COLORLESS   HONE      57  FORTSRB

0.1   2.00  CLEAR       COLORLESS   MODE      SI  PORTERS

0.1   2.00  CtEftH       COLORLESS   HOKS      64  PORTBHB
                                                                            PRBPERC V4.00
                                                                                  Pagei  1
Date,,,.  Time,.,. S

09/15/97  14:08:40 F

09/15/57  14:08:40 F

09/15/97  14:08:40 F

09/15/97  14:08:41 t
                                                                                                                                                                         o
                                                                                                                                                                         CO
 •** End of Report "*

-------
Datei 09/lS/!
TinaI 09:32
 Sample     ,
 ft  crd TLI^Ntflnfaer.. Customer.Sample, Id

 000    TLI Blank    TLI SBlank

 001    U3-2-1A-C   Ffll-0010

 002    U3-2-2A-B   BO-OOJO-1

 003    1S3-2-3A-E   BO-0010-2

 004    183-2-4A-1   BO-0010-3

 OOS    183-2-SA-C   M0010 Blank

 00€    TUX LCS      TU LCS

 007    TDI LCSD     TLI LCSD
 TRIANGLE LABORATORIES, INC.
Net Lab HM5/PUF obeervatlona
       Project! 43230
PRDPERC V4.00
      Pagei  1
P.
	 Ho
0
1
1
1
1
1
0
0
XK> Filter Glass nool PUT
Color, , , , , Color 	 Color, . . • . Color. ,
WHITE NA NA HA
HHITE MHITB WHITE NA
WHITE BEME MHITB HA
WHITE BEIGE MHITi NA
HHITE BEIGE WHITE . NA
HHITE WHITE WHITE MA
LOTP-10I0*
LOTP-1010A
Air
, . . . Odor 	 Q.tlo. Enbered.By. ,
NA 03898 HIIACT
NONE 03698 ItlLLKT
HOSE 03898 HILLKT
NONE 03833 HII.LKT
NONE 03898 HILLKT
MONB 03B98 HIIJ.KT
miaa
Htisxr
.... Pats .
OS/IS
09/15
09/1S
OS/IS
09/15
09/15
09/15
09/15
. » . . 1
09:32
09:32
09:32
09:32
09:32
09:32
09:32
09:32
fits*. ,
F
F
P
F
F
F
F
F
 »** End of Report «*«

-------
                AIR QUALITY PREPARATION WORK ORDER FORM
                         TRIANGLE LABORATORIES, INC.
TLi Project Number:
                                                    Due Date:
Client/Company Name:.
Project Manager
Client MILES Code:
Quote Number:
                               ORDER INFORMATION
                        J3>
                                                                  c.        ._
                                                   Order Date:     J/3/ /  '
                                                   Client Project £
                                                   Client P.O. ft
	Rlters
	3%79.0 cm
	4710.16cm
	414711.0 cm
	5712.5cm
	Other	
Filter Material:
Ship filter in:
                           ,   MATERIALS NEEDED
                           4.XAD traps           	PUFs
                          t-xBall and Socket      Sandwich PUF:
                         	Socket and Socket    Ship PUFs in :
                         	Screw cap
                          	Other
                               yes
                               jars
                         no
                         sleeves
                   .Quartz
                   , one petrl dish
     . glass fiber     other.
     . separate petri dishes
Prepares
f of Laboratory Blanks:
XAD Resin Batch ft
Pre-spike required:
Intended Analysis:
                       SPAjyipAPREPARATlON INFORMATION
                                                       Date:
                        no
                  PCDD/PCDF
                  Other: 	
HR-PAH
HR-PCB
Spiker/Observer Initials:
Spiking Date:
Spiking Solution ID:
Volumn Spiked (pL):
Nominal Concentration:
Expiration Date:

PCDD/PCDF Surrogates
"CL-2.3.7.8-TCDD
"C«-2,3,4,7,8-PeCDF
aC,a-1,2,3,4,7,8-HxCDF
13C«-1 ^,3,4,7,8-HxCDD
'3C,I-1,2,3,4,7,8,9-HpCDF


Ship to the Attention of
Mailing Address
Street Address

Phone Number
Special Instructions:
                                 Dioxin
                                                              CTganics
                                                               /
                                    /  f7
                            USF-C, -S.
                                            .pg/mL
                             PAH-HRMS Surrogates
                          ng  Terphenyl-dw    	ng
                          g  Fluorene-dio      •   no
                          o
                          .ng  PAH-LRKIS Surrogates
                          ng  Terphenyl-du
                       'CB-HRMS Si/rrogates
                      aC,r313',S,S'-TetraCB     '	ng
                      "Cu-^ZAS.S-PentaCB   	ng-
                      uC,l-2,2',3,4,4',5'-HexaCB  	ng*
                      uC,»-212',3,3',5,5>,6,6>-OctaCB	ng
                                SHIPPING INSTRUCTIONS
                                     P?fo k^Act-
                                    t=Wf
Form Prepared by
                                    Signaiuni         I             ' OMB
Please return this form to Triangle Laboratories, Inc. with the samples.

                                                                                 32

-------
                                                                  PAGE 1 OF 1
           TRIANGLE LABORATORIES,  INC.
          Transfer Chain-of-Custody Form
                  Project 43230

       Transfer  From: OWLS5    To: OMSSV

              Initials. .     Date	     Time. ..

Released by:  	

Accepted by:	
                                          JL/JMi    JS.52
           MILES.ID.

           43230-
           43230-
           43230-
           43230-
           43230-
           43230-
           43230-
           43230-
     -000
     -001
     -002
     -003
     -004
     -005
     -DOS
     -007
              TLI No	   Cust.Id.
TLI Blank
183-2-1A-C
183-2-2A-E
183-2-3A-E
183-2-4A-E
183-2-5A-C
TLI LCS
TLI LCSD
TLI SBlank
FB1-0010
BO-0010-1
BO-0010-2
BO-0010-3
M0010 Blank
TLI LCS
TLI LCSD
+	XfrCOC (Rev 11/01/94) --•
  Additional comments or instructions:
                                                                         33

-------
                 SEMIVOLATILE GC/MS TRACKING FORM
TL-RTP Project #:
MATRIX: mfiMSj PDF Water Soil  Other
METHOD:<<8270j62S  CLP

ANALYTE LIST: Table 2  TCLP  625  CL1

ICALName: ICAL
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                                                        Triangle Laboratories, Inc.
                                                            ',,   Run Log
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                                                                                               Signature
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-------
                                                     Triangle Laboratories, Inc.
                                                             Run Log
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-------
                                                     Triangle Laboratories, Inc.
                                                             Run Log
Column Type
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Date"  Time"  Prolect      Sample*    Client ID
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-------
                                                     Triangle Laboratories, Inc.
                                                             Run Log
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Column Type
ObOQ^
Column #
45gicj4-1
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s^~~
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                                                                                                     Page   j> Z»_

-------
Column type
t>B*S Lolff
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                                                                                      Page   £3
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-------
                                                    Triangle Laboratories, Inc,
                                                            Run Log
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Column Type
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*  Volatile Data Only
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-------
                                                    Triangle Laboratories, Inc.
                                                            Run Log
Column Type
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Analysis*
                                                     Acquisition
                                                       Method
                                         GC Method*
                                                                                    Find DBs*
                                                                                           Other'
                                  Standards
JnlfiBUkWSurroQale 1 Recovery   Internal/ Surrogate /Recovery
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-------
                                                             Run Log
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-------
Project Number. 43230
Sample File: VG290
  Method8270AMM5.
Sample ID; BO-OOlQ-l-
                                             Dilution Factor:    1.00

1 ,4-DichlorobenKne-d
4
Naphthalene-d
Naphthalene
2-Metli5rInaph.thalene
Acenaphchene-d
2-ChIoronaphthmlene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene-d
10
Phenanthrene
Anthracene
Fluorandiene
Chrysene-di
Pyrerte
Benzn(a)anthraccne
Chrysene
Petylene-d
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(e)pyrene
Benzo(a)pyrene
Perylene
Indenofl ,2»3-cd)pyrene
Dibenz(a,h)anchracene
Benzo(g,h,i) perylene

IS1

IS 2
20.76 B
5.88 J
IS 3
U
0.54 J
U
0.86 J
IS 4

3.25 J
U
0.55 J
IS 5
U
U
U
IS 6
U
U
U
U
U
U
U
U

10.46

13.01
13.05
14.48
1(5.67

16.37

17.82
19.80

19.85

2X35
25.61



29.76















0.29

0.31




0.25


0.31
0.40
0.43

0.54
0.52
0.53
0.60
0.60
0.72
0,98
0.82




10
10

10
10
10
10


10
10
10

10
10
10

10
10
10
10
10
10
10
10
                         NA- Not Applicable; D«t Limit Detection Limit; Quail. Limit Quantiution Limit
    IS; Internal Standard; tl; Undetected; B: Present In Blank; J: Estimated- Below Quantltation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Cajsftola Drive * Durham, North Carolina 27713
Phone; (919) 544-5729 • Fax: (919) 544-5491
                 Savar v3.S
      PrWled: 15:21 09/22/ 1JW7
                      43

-------
Project Number: 43230
Sample File: VG290
                                                  Method 827QA MM5.
                                                Sample ID: 80-0010-1^
                                             Dilution Factor:    1.00
Phenol-d
Nitrobenzene-d
             j
1,3,5-TridilorobcnzEne-d
1,4-Dibromobenie2ne-d
2-Pluorobiphenyl
2,4,6-Tribtomophenol
Anthracenc-d
           10
Pyrene-d
Terphenyl-d
       80.04
       75.65
       74.40
       81.66
       83.41
      110.30
      101.00
      117.19
      14S.66
 9.69
11,54
12.22
13.12
15.25
1832
19.92
22.79
23.14
 m
 76
 74
 82
 83
110
101 .
117
149
 Reviewed by.
Date °1 I Z^/^7
                          NA- Not Applicable; Det Umlb Detection Limit Quan. Ltalb Quantitation limll
     IS; Internal Standard; U: Undotoctgd; B: Present In Blank; J: Estimated- Below QuantiUtion Limit E: Estimated- Above Oil ibntion Rang*
 Tnangl* Laboratories of RTF, Inc.
 601 Capitola Drive » Durham, North Carolina 27713
 Phone: (919) 544-5729 • Fax (919) 544-5491
                                                                  Smiatv33
                                                      Pririted! 1521 09/22/1997
                                                                      44

-------
Project Number: 43230
Sample File: VG290
                                            Method 8270A MMS_
                                          Sample ID: BO-OQ10-1-
                                               Dilution Factor:    1.00
1,4-Didilorobcnzcne-d
                    4
n-Nitrosodiflnethyiamine
Cumene
Phenol
Aniline
bi$-{2-Chloroethyl) ether
Benzyl Chloride
1,4-Dichlorobenzene
2-Methylphenol
Acetophenone
n-Nio
-------
Project Number: 43230
Sample FUe: VG290
  Method 8270A MM5_
Sample ID: BO-0010-1"
                                            Dilution Factor:   1.00

2-Chtoroacctophenone
Acenaphthene-d
r 10
Hexachlorocyclopen cadiene
2,4,6-Trichlorophenol
2,4,5-Trichlorophenol
Biphenyl
Dimethylphthalate
2,4-Dinitrophenol
4-Niirophenol
2,4-Dinitrotoluene
Dibenzofuran
4,6- Dinicro-2-methytphenol
Trifluralin
Phenanchrene-d
10
Di-n-butylphthakie
Hexachbrobenzene
4-Aminobiphenyl
Penwchlorophenol
Penaehloronitrobenzene
4-Nitrobiphenyl
Chrysene-d
Benxtdine
4,4*-M«hyIenedianiline
Dimethylaminoazobeniene
SJ'-Dimethylbenzidine
3,3'-Dimethoxybenzidine

U
IS 3 16.67
U
21.86 15.05
U
523 J 15.46
3.63 ] 16.08
U
U
U
2.63 J 17.10
U
U
IS 4 19.80
5.65 BJ 21.00
U
U
U
U
U
IS 5 25.61
U
U
U
U
U
fc^f^c??^:->:-:?:A^S»
^•^'.f^-Kf->^--vi:>--:-:->:--
0.24

0.56

0.68


3.47
1.45
0.83

2.05
0.98


0.65
0.26
1.00
1.54
0.69

0.53
1.29
0.99
0.77
1.58

10

10
1U
10
10
10
25
25
10
10
25
10

10
10
10
25
10
10

10
10
10
10
10
                         NA- Not Applicable; Det, Until: Detection Limit; Quan. limit Quantilation Limit
     IS; Internal Standard; U; Undetected; B; Present In Blank; Js Estimated- Below Quanriurion Limit; Es Estimated* Above Calibration Range
 Triangle Laboratories of RTF, Inc.
 801 Capttola Drive * Durham, North Carolina 27713
 Phone: (919) 544-5729 • Pax: (919) 544-5491
                 Savafv3.5
      Printed: 12-34 09/22/1997
                    46

-------
Project Number: 43230
Sample File: VG290
                                                  Method 827fiA MM5_
                                                Sample ID: BO-0010-1-
                                            Dilution Faeton    1.00
3,3'-Dichlorobenzidine
Methylcnc bis
-------
JgO^

- i,4-Dichlerobenz*ne-d4 (10.4S)
                     •- Phenol-d5 (9.691)
                  1,3,5-Trlchlorobekene-cB (12.223)**
                   1   l,4-Dibro»abenzene-d4 <13.:
                           2-Fluorobiphfnyl (15.246V
   ' - flcenaphthene-tttO (16.674)*
               -- 2,4,6-Trikrotwphenol (18.317)
                uata Review;
                Date: ^
                                                            i
                                                     ilil
                                                     -
                                                                I
                                                            15


                                                             I
                                                                                               48

-------
Bits Fits: ,/chM^.i/09-ie-97.b/yG290.d
Bate I  1MEP-1W7 19J25
Instrument • V.I
    le  IB S 10-0010-1
     i  phase : DB-5
Volwe  Injected 
-------
Data File:  /chen/V.i/09-18-97.b/VG290.a
Report  Dates  19-Sep-1997  07:07
Page  1
                                     TRIANGLE  LABORATORIES,  INC.
SEMI-VOIATILE QOANTITATION REPORT
Data file
Lab, Id.
Inj Date
Operator
Snip Info
Misc Info
Comment
Method
Meth Date
Cal Date
Ala bottle
Oil Factor
Integrator
/chem/V. i/09-18-97 . b/VG290 . d
4323O
18-SEP-1997 19:29
DD
BO-001Q-1
183-2-2A-!
m m
/chem/V, i/09-18-97 .b/cclist.
18-Sep-1997 11:31 target
18-SEP-1997 10:43
10
1.000
HP RTE


Autotune Date: 17-Sep-97 07:05:4
Inst ID: V.i



m

Cal File: VG279.d

Target Version: Target 2.20
Compound Sublist: pah. sub
 Sample Type: AIR
                                                                   CONCENTRATIONS
   Compounds

    1 1,4-Dichtorobeniene-d4
    Z NaphthaIene-d8
    3 ftctn*phttiene-d1Q
    4 Phenanthrene-dlO
    5 Chrysene-d12
    6 Perylene-d12
 *  7 2-Fluorophenol
 $  8 Phenol-d5
 $  9 2-Ehlorophenol-d4
 * 10 1,2-Dichlorobenzene-d4
 $ 11 Nitrabenzene-d5
 $ 12 1,3,5-Trfchlorob4miene-(S
 * 13 1,4-D!bro«obenzene-d4
 S 14 2-Ftuarobiphenyl
 S 15 2,4,6-Trfbrcmophenol
 $ 16 Anthracene-did
 * 17 Pyrene-dlO
 $ 18 Ter-phenyl-dH
   42 Naphthalene
   W 2-Hethytnaphthalene
   SO 2-Chloronaphthatene
   56 Acenaphthylene
   58 Acenaphthene
   65 Fluorene
   73 Phenanthrene
   74 Anthracene
   77 Fluoranthene
   78 Pyr*ne
   83 Benzo(a)anthracww
   84 Chrysene
   86 Benzo(b)fluoranthene
QUANT 5IG
MASS XT (REL RT)
152.00 10.455(1.000)
136.00 13.011(1.000)
164.00 16.674(1 .000)
188.00 19.798(1.000)
240.00 25.614(1.000)
264.00 29.755(1.000)
Compound Not Detected.
99.00 9.691(0.927)
Compound Not Detected.
Compound Hot Detected.
82.00 11.542(0.887)
185.00 12.223(0.939)
240.00 13.119(1.255)
172.00 15.246(0.914)
329.80 18.317(1.098)
188.00 19.920(1.006)
212.00 22.794(0.890)
244.00 23.145(0.904)
128.00 13.054(1.003)
142.00 14.482(1.113)
• r-i nn «r- rr < m vam^i
loZ.Ou l>x230MJT9337 —
152.00 16.372(0.982)
154.00 16.67/i(1iOOO)
166.00 17.820(1.069)
178.00 19.848(1.003}


Compound Not Detected.
Compound Not Detected.
Compound Not Detected.
Compound Not Detected.
QH-COUMN
RESPONSE
763020
2520609
1265600
1823769
854146
735866

2372560


2030893
1762865
1601256
3481141
879457
4545269
3808751
E777654
1259598
217711
	 __
27533
	 7356 —
31573
137271
1X7371





( ng)
40.00
40.00
40.00
40.00
40.00
40.00

80.06


7S.58
74.44
81.66
83.39
110.16
100.97
117.18
148.62
20.76
5.88

7Z3T
0.54
0 %\
0.86
3.26
i &;» —
~!?e>l>




FINAL
< ug)







80.06


75.58
74.44
81.66
83.39
110.16
100.9?
117.18
148.6Z(R)
20.76
5.88(a)
n JJ<_L f P
O^ZZCaV i *
0.54(8)
U yi/j|\ p
0.86(a)
3.26(a)
H J




                                                       Data Review:
                                                       Date:  i!H
    50

-------
Data File:  /ehem/V.i/09-18-97.b/VG290.d
Report  Date: 19-Sep-1997  07:07
                                 Page 2
                             QUANT SIC
            RT (811 RTJ

  Coenpound Hot Detected.
  Confiound Not Detected.
252.00     2
252.00     i
        CONCENTRATIONS
       QN-COUMN    FIHAL
RESPONSE   t  («)   C  UB>
                                                     1080
                                                              0.07-
  Coopcund*

  87 BenioCkJfluoranthen*
  88 ienzeCelpyrene
  89 Eenzo(a}pyrene
  90 Perylene
  91 Indenal1,2,3-ed>|jyrene
  92 Dibenz(a,h)anthracene
  93 Betuo(9,h,i)perylene  —

QC  Flag Legend

a - Target compound detected  but,  quantitated  amount
     Below  Limit Of Quantitation(BLOQ).
R - Spike/Surrogate failed recovery limits.
                                                                      O.OOtT)
                                                                      0.07(i)
                                Compound Hot Detected.
                                Compound Hot Detected.
                                Conpoind Hot Detected.
                                                                                         51.

-------
Data  File:   /chem/V.i/Q9-i8-97.b/CAA/VG290.d
Report  Date:  19-Sep-1997 07:38
                            Page 1
                                    TRIANGLE LABORATORIES,  INC.
SEMI-VOLATILE QTJAOTITATION
Data file
Lab. Id.
Inj Date
Operator
Sap Info
Misc Info
Comment
Method
Meth Date
Cal Date
Als bottle
Oil Factor
Integrator
RETORT


/chem/V.i/09-18-97.b/CAA/VG290.d
43230
18-SEP-97 19:29
DD
BO-0010-1
183-2-2A-1

/chem/V. i/ 09-18-97 .b/tlicaa
18-Sep-l997 12:15 target
18-SEP-1997 11:32
10
1,000
HP RTI
Sample Type: nm5

Autotune
Inst ID:



.m

Cal File




Date: 17-Sep-97
V.i





: VG280.

Target Version:
Compound

Sublist







d

Target
: CAAl










.s

                                                                                            O7:05:4
                                                                                           2.20
                                                                   CONCENTRATIONS
   Compounds

    1  1,4 Dichlorobcnzme-tK
    2  MaphthBlene-d8
    3  Acenaphtherx-d10
    4  Phenanthrene-dIO
    5  Chrysene-d12
    &  Perylene-d12
    7  2-Fluorophenol
    8  Phenol-dS
    9  2-Ghlorophenol-d4
   10  1,2-Dichloroben«n«-d4
   11  Mltrobenzene-d5
   12  1,3,5-Trichlorobenzene-dB
   13  1,4-Dibromobeniene-d4
   14  2-Fluorobfphenyl
   15  2,4,6-Tribromophenol
   16  Anthracene-d10
   17 Pyrene-d10
   18  Terphenyl-dH
   19  n-Hitrosodimethylamir*
   20  CXncne
   22  Phenol
   23  Aniline
   26  bis-(2-Chloroethyl)ethcr
   27  Benzyl  Chloride
   28  1,4-Dichlorobenzene
   30  2-Ncthylphenol
   31  3/4-Hethylph«nol
   32  Aettaphenona
   S3  n-Nitrosooorpholine
   34  o-Toluidine
   35  HexachlorMthww
QUANT SIG
MASS
152.00
136.00
164.00
188.00
240.00
254.00
Compound
99.00
Compound
Compound
82.00
185.00
240.00
17Z.OO
329.30
188.00
212.00
244.00
74.00
105. DO
94,00
93.00
jr^ nn
&3.UU
01 fin
T 1 *UU
146.00
1031.00
4 ft a fifi
ivo.uu
105.00
«jt nn
JO*UV
106.00
Compound
ON-COLUMN
RT (REL RT>
10.455(1.000)
13.011(1.000)
16.674(1.000)
19.796(1.000)
25.614(1.000)
29,755(1.000)
Not Detected.
9.691(0.927)
Not Detected.
Not Detected.
11.542(0.887)
12.223(0.939)
13.119(1.255)
15.246(0.914)
16.317(1.098)
19.920(1.006)
22.794(0.890)
23.145(0.904)
4 8?1fO 46fl^
8.943(0.855)
9.713(0.929)
«'««<•»<•»
' { 3
10.491(1.003)
tlj. 191(1 iQTO) —

11.227(1.074}
il.TVin nn^i
Not Detected.
RESPONSE
763020
2520609
1265600
1823769
854146
735866

2372560


2030893
1762865
1601256
3481141
879457
4S45269
3808751
2777654
	 _81408—
10523S
419956


51876

847497
121B1

( nel
40,00
40.00
40.00
40.00
40.00
40,00

88.64


72.64
72.85
84.74
S2.44
110.05
94.31
117.73
133.67
4 4"
2.17
IS. 72
0 03

775
2.03
	 d;3f — "

27.92
	 8*4-1 —

FINAL
( ug>







88.64


72.64
72.85
84.74
82.44
110.05
94.31
117.73
133.67
* A* (=
2.17
15.72
n Tf 1 1
•Sx1
2.03
2-x
27.92
^

Data R
Date:
                                                                            iew:
                                                                                                    52

-------
.Data  File:  /cheia/V.i/09-ia-97.b/CJkA/VG290.d
 Report  Date:  19-Sep-1997  07:38
Page  2
    Compounds

    36 nitrobenzene
    37 N.M-Oinethylaniline
    38 1(2-Bibroino-3-elilaraprop»ne
    39 Isophoron*
    40 o-Anfsidinc
    41 1,4-PhenylMedfMfne
    42 1,2,4-Trichlorobenzene
    43 Naphthalene          ***
    45 Hexaehlorobutadiene
    46 H.N-DiethylanUine
    47 a,a,a-Trichlorotoluene
    48 Hydroquinone
    50 2-ChloroBcetophenane
    51 Hexachlorocyclopentadiene
    52 2,4,6-THehlorophenol
    53 2,4,5-Trfchlorophenol
    59 Bfphenyl
    60 DimetNylphthalate
    71 2,4*Dinitrophenal
    61 4-Nltrophwwt
    62 2,4-Dfnftrotoluene
    £3 Dibenzofuran
    64 Oi-n-butylphth»t»te
    65 4,&-Oinftro-2-raethylph«nol
    66 TrtfluraUn
    67 Hexachlarobenzene
    68 4-*«inobiphenyl
    69 PentBchlorophenol
    70 Pentachloronitrobenzene
    72 4-Nltrobiphenyl
    73 Benzfdfne
    74 4,4'-Methylened?anilfne
    76 DIittthylMlnoizQberaene
    77 3,3'-Dfmethylbenzfdine
    79 3,3'-Dimethoxybenzidine
    80 3,3'-Dichlorobenzidine
    81 Hethylene bis-chloroaniline
    82 bis(2-Ethvlhexyl)phthBlate
aUHNT SIS
MASS RT (REL RT>
77 00 H^flVftiBK)
120 00 11 51440*885)
Compound Not Detected.
82.00 11.621tajS93J—
Confound Not Detected.
108.00 13.181(1.065*—
180.00 12.889(0.991)
128.00 13.054(1.003)
Compound Mot Detected.
134.00 13.S35O i39*y~

105 09 t4JS5(1 091)
Compound Not Detected.
196.00 15.052(0.903)
196 00 15.CK?f n 9935 —
154.00 15.455(0.927)
163.00 16.076(0.964)
Compound Not Detected.
139 00 16«S62(liQ11)
165 00 17.12H14027)
168.00 17.099(1.025)
149.00 20,997(1.061)
Compound Not Detected.
Compound Not Detected.
266 00 11367(0.8783
142 00 19 257<0i971)


Compound Not Detected.
120.00 iL5.KHO.904)
Compound Not Detected.
Compound Mot Detected.
Compound Not Detected,
Compound Not Detected.
149.00 25.636(1.001)
RESPONSE
87064
— «093T"
• 	 T79T"
64263
1259595
1W74
1*425
170991 —
317406
— 317406—
243084
132321
«i48
128239
285S44

8?74

,...,
65TOT

29619
247060
COHCOtTRATIONS
ON-COUMN FINAL
(no) ( ug)
1 7. 67 	 sx-at — FT
? 77


0.07 —
2.88
16.88
O.S4 '
	 	 ftf!
21.84
	 21" '»'*
5.23
3.63
0.1S
1 2fl
2.63
5.64


0 ""
0 06
** 4Q — —

Z.95 —
15.94
. „__ />CMlr
1 41 pf-S*
2.88
16.88
	 ^i. iff
	 	 L Jff f £J "ij
*"w^ r /~^ J*
5.23
3.63
	 .Q.70 N -^ |7
1,?B /
2.63
5.64
F. O ^

0.06 '


15.94
                                                                                                            53

-------
 Data Pile: /chew'V.l/09-iB-97.h/VG290.d
 Date s 1B-SEP-1997 Mj29
 Instrument : V.i
 Sanple 10 : BO-0010-1
 Column phase : DB-5
 Volwe Injected - '
2.0^
0 0-
42 Naphthal





. i A h,. . J.
ene • * :
2.0-

1.0-i






^
s
CM
1
A A,
-s
<5
*
3







1
12.6 12.8 13.0 13.2 13.4
Tine (win.)
Hass 129.00
i.o-i
8.0-:
7.0^
g 0-

o :
34«°i
2.0-=







§
A

1
a





A

,0 | i i i i i r i i i i1 1 i i i | i i i
12.6 12.8 13.0 13.2 13.4
Time fain.)
Mass 127.00
1.2-1

1 O-2
0 9-

0.8-

aO.7-^

io!^
^•*]
0.2H
0.1-i









1
sJ
1
4/W_ ^
"?
M










12.6 12.8 13.0 13.2 13.4
Tine (din.)

-------
 Data File: /ch«*/V.i/09-iS-97.b/VG290.d
 Date : 18-SEP-1997 19:29
 Instrument ; V.I
 Sanple ID : BO-0010-1
 Coluan phase : DB-5
 Volute Injected (uL> : 1.0
46 2-Hethaln*phthalene
                                             Pace 12
Colum dlaaeter ;  0.32
Scan 1264 (14.482 »in> of VG290.d
1.2-^
1.0-i
~0.8^
1H
0.2-i
0,0-
4
±*2-.
1.0-1
,-,0.8-i
!°*6i
^0.4-;
0.2-;
0.0-

8.0-
**2.0:
0.0-
100-
75^
jj. O't
S-25^
M-50-
-75^
-100-



H'M,4 -*,- J|

~

I .
10 80120160200240280320360400440
Hassitharee
Sean 121


i- MM / 1 .1
i > • 't ' ^"v i *
W 80 120
y (14.482 nin> of VG290.d (Subtracted)



160 200 240 280 320 360 400 440
Hass/Chare*
46 2-Hethalnaphthalene (PBH Reference Spectn«>
| MM1 ^ r '(%

40 80 120160200240280320360400440
Scan 1264 (14.482 mM of VG290.d (2 DIFFERENCE)

•*-—- -L— i-r""


40 801201&02002402803203604004XO
Mass 142.00
1.2-

1.0-
0.8-
"0.4-
0.2-
0.0:
1

i.o4
0.9-^
0.8-:
0.3-j
0.2-i
0.1-i
0.0^
1
I *
1 "*


t.O 14.2 14.4 14.6 14.8
Tine (win.)
Mass 141.00
•

i MD
jj ^Lffof^ ~
4.0 14.2 14.4 14,6 14.8
Tine (Kin.)





                                                                                                             55

-------
   Bafca File: /<*e»/V,l/'09-li-97.b/VG2».d

   Bat* : 18-SEP-1997 13:29
   Instrument ; V.I

   Sample ID : BO-0010-1

   Colunn phase : DB-5

   Volume Injected 
-------
 Data File: A*e«/V.i/W-liJ97.b/VG290.d
 Bat* j 18-SEP-1997 19:29
 Irwtruaent : V.l
 Sanple ID : BO-0010-l
 Coluwi phase S DB-5
 Volwe Injected (iL> : 1.0
65 Fluorene
0.32

1.8-^
1.5-^
^1.2-J

Scan 1727 <17.©0 mn) of VG290.d

—

yybkkU,»y.



!u,J iii, i, n i I.
,(|-"| . i i | i i i | i i \ . i i | . i i | ••• i r i | i 1 • | i » • | • • • |
40 80 120 160 200 240 280 320 360 400
Hass/Charee
1.8-1
1.5-i

1.2-1
pi.o-j
Ho.B-i
>-Q.$-,
0.2-i

Scan 1727 C17.8






j
II,,* JljL ll, ,1 ,i t 1 1 1
120 «in5 of VC2».d (Subtracted)







Li . ii i n
1 ' "" ' '( ™ ' 'I ' " ' ••' 1 ' ' ' I' i i i i • • i i " • i • • • i i— >-T— r
40 80 120 160 200 240 280 320 360 400
Hass/Charee

B.O-;
.
g6.0:
§4,0-
y.
2.0:
0 0-
6S Fluor






X I i 1 L II 1
ene (PW i?eference Spectrun)







40 80 120 160 200 240 280 320 360 400
Hass/Charw
100-g
75 J
50 -;

25-j
t4- Q™
<*- :
s-25-i
-75-i
100 =
Scan 1727 (17.820 *in> of VG290.d 
-------
 Data File: A*e*/V. IAS-18-97.b/VG290.d
 Date : 1B-SEP-1997 19:29
 Instnuent ; V.I
 Saaple ID S BO-0010-1
 Colum phase : BB-5
 VoiuM Injected -z^
1.0-i



—



. !








..I

40 £0 80 100 120 140 160 1BO 200
Scan 2009 <19.848 »in) of VC290.d -
2.0-
OA-
73 Phenanthrene (PBM Reference Spectrun)






. . , J J . . ,11 .1








.M | ,,.,,,, | ... | ,,. | ,., | .,.,...,,..,,
40 CO 80 100 120 140 160 180 200
Hass/Chanre
Scan 2009 (19.849 nin) of VG290.d (Z DIFFERENCE)
100-
75-
50-
25-
«*• d-
ft*. ^
"** MB
**-so-
-75-




	 r' "• 	 	 	


40 60 80 100 120 140 160 ISO 200
Hass/Chares
Hass 178.00
8.0-:
7.0-i

6.0-i
5.0^
14.0-
3_ ,:
*• * ':
2.0-i
1.0-;











^. . . . ^i
1
a








h — 	
19.4 19.6 19.8 20.0 20.2
Tine Cain.)
Mass 179.00
1.2-3
1.1-1
1.0^
0.9-i
0.8-;
^.0.7-:
oO,6-i
f°*51
0.3^
0.2-i
0.1-1
0 0~
rs
• QD
1"





I
jy

19.4 19.6 19.8 20.0 20.2
Tine (nin.)
Hass 176.00

1.2:

1.0-

^0.8-
s
30.6-
""0.4-
0.2-











tl 1 i JAtjN
rs
s








k « . , ,4ww
19.4 19.6 19.1 20.0 20.2
TlneJMin.)
                                                                                                          58

-------
 Data File: /ch™/V.i/09-lB-97.b/VG290.d
 Date : 18-SEP-1937 19:29
 Instrusent ; V.i
 Sample IB : BO-0010-1
 Column phase : DB-5
 Volume Injected (uL) : 1.0
77 Fluoranthtne
                                             Page 11
Column diameter :  0.32
Scan 2KB (22.350 nln) of VG290,d
1.2-i
1.0-;
50.8:
^0.4-;
0.2-;
0.0-

«w

,




ll, Jiiln il|l!li!,!ll!ii,l,J,lll,l, III! iMijnll.lilill, illji MI ,i illi

40 60 80 100 120 140 160 180 200
Scan 2358 (22.350 win} of VG290.d (Subtracted)
1.2--
I ft™

^O.B-1
f OJ5J
~0,4-i
0.2-i
0,0-






i 1
i Li i L.I!* him.. Jill., j Hi tu.lili .1 lilli , . i i ll






I
1 t
1 ' ' 1 ' r ' 1 ' ' ' 1 1 f "f 1 ' ' ' 1 ' 1 ' 1 ' ' ' 1 ' ' ' 1 "
40 60 80 , 100 120 140 160 180 200
HassiCharee
77 Fluoranthene (PBH Reference Spectrum)
-
*
8.0-:

-6.0-
S :

>- '•
2.0-;
0 0-








1 J











40 60 80 100 120 140 160 180 200
Mass/Char-ee
Scan 2358 (22.350 i»ln> of VG290.d (2 DIFFERENCE)
100-g
75-1
50-j

25"s
& 0-i
S-25^
"-50^
-75-:





.1., i. L<|. .k ii.r, au. i.i j ii, iuw.ii .1 nil. , , ». . ,,».. i
r


40 60 80 100 120 140 160 180 200
Hass/Charee
Hast 202.00
1>2:
•
1.0-;
%°'9~:
^0.6:
X
"0.4^
On_
.£
0+0-







j\ k n j
n
N



II
n
V\ il A /
• 1 ) • i 1 | • 1 • | i 1 I | r-r , j
22.0 22.2 22.4 22.6 22.3
Time (win.)
Mass 101.00
7.0-
6,0:
5.0-^

— 4,0-
2 '-
3^i
>• •
2.0^


l.O-i
ft rtj^






in
• . . t • • . | , . . t . • i
22.0 22.2 22.4 22.6 22.8
Tine Cmlru)
Mass 100.00
4,0-
3£-
.O.
3.2-i
2.8^
2 4-^
5 * :
o2.0-f
x :
>• ~
1.2-
0.8:
0.4-i
0.0—










in
S.
? ,/N.













22.0 22.2 22.4 22.6 22.8
fine 
                                                                                                              59

-------
 Data File:  /chM/V.i/09-l&-97.h/Cm/VG290.d
 Date : 18-SEP-97 19:29
 Instrtwent  :  V.I
 Sa*le ID : BO-0010-1
 Column phase  : DB.5-625
 Volixe Injected •
2.0-
0.0-
20 Cunene  of VG290.d (X DIFFERENCE)
100 •:

75-j
so-;
251
Jt °
S-25-
X :
-50-f

-75-i
-100-





T 	 , 	 J'" — ' 	 	






40 60 80100120140160180200
Hass/CharEe
Mass 105.00
6.0-:
5.5-1
s.o-i
4.5-i
4.0-j
32.5-i
>-2.0^
1.5-i
1 0-
^«v <
0.5-
0.0J









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CD







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p i H | 'i f i | -i r i , i i i i i i i •
8.60 8.80 9.00 9.20 9.40
Time (win.)
Hass 120.00
14j
i
*"2~.
1.0-j
^ :
o
3o.6-i
0.4-i
0.2-
0.0J








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8.60 8.80 9.00 9.20 9.40
Tine (Bin.)
Hass 77.00

M:

1.2-

I.Q:

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0.4-


0.2-


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ti

II
II
II

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-------
 Bat* File: /che«XV.iA)9-18-97.bA»WG290.d
 Date : 18-SEP-97 19:29
 Instrument t V.I
 Sample ID : BO-0010-1
 Coluwi phase :  DB.5-625
 Volute Injected (uL> : 1.0
22 Phenol
                                             Page 14
Coluv) diameter :  0.32

2.4-;
2.0-i
a1-6":
£1>2j
~OJH
0.4-;
0.0-




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40 60


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2.0-i
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40 60


8.0-
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34'0:
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1 ,11,1 1
40 60

100,
75^
504
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Scan 598 (9.713 *ln) of VG290.d




f^*1 . .'

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1 . .[
80 100 120 140 160 180 200 220 240 260 280
Hass/Charec
Scan 598 (9.713. »in> of VG290.d (Subtracted)





•}•>(•' _ L




1
JL 	 . .. _ ,L . , L I
80 100 120 140 160 180 200 220 240 260 280
Hass/Charee







22 Phenol (PBH Reference Spectrtu)






_
80 100 120 140 160 180 200 220 240 260 280
Hass/Chartre
Scan 598 (9.713 nin> of VG290.d (2 DIFFERENCE)


L_t. . (, .1 ^ ,, , L



80 100 120 140 160 180 200 220 240 260 280
Hass/Charee
Hass 94.00
2.5-j
2.2-.
2.0-.
1.8-j
ffil-5-j
I1*2!
0.8H
0.5-i
0.2-:
0.0-3







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9.40 9.60 9.80 10.00 10.2C
Tine (nin.)
Has* 65.00
9.0-i
8.0-i
7.0-i
60-
»K nJ

34.0-i
2.0-!
1.0-i
0 0-
fs










n

rvAn J V.-'W VA/^VV* « W
9.40 9.60 9.80 10.00 10.2C
Tine (xln.)

*"2~.

1.0-
0.8-
£ .
3°-b"
* 0.4-

0.2-j
Hass 66.00
PS
1
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9.40 9.60 9.80 10.00 10.2<
Tine 
-------
 D*ta File: /chn^V.i/09-18-97.b<^«WG290.d
 late : 1B-SEP-97 19:29
 Instrucnt : V.i
 Swple ID : BO-0010-1
 Calum phase : BB.5-625
 Volune Injected