&EPA
www.epa.gov/research
                                                                                             EPA/600/F-13/223
science    in   ACTION
INNOVATIVE  RESEARCH FOR A SUSTAINABLE  FUTURE
          Development of a Tool to Identify Nitrogen Sources and Sinks within a

                                        Watershed Framework
 The management of reactive
 nitrogen in watersheds requires
 sound scientific tools.
 Although nitrogen fertilization is vital to
 maintain a productive and vigorous food
 supply, excess reactive nitrogen (N)
 released to the environment causes
 deleterious effects on human and
 ecosystem health. Excess N in aquatic
 systems brings about harmful algae and
 weeds, causes eutrophication induced
 hypoxia in coastal systems that leads to
 fish kills, and excess N contaminates
 many potable drinking water supplies.
 In order to manage the widespread N
 pollution problem in watersheds it is
 requisite for decision makers to have a
 strong technical grasp of the factors that
 control N sources, sinks (regions or areas
 that can retain N), and pathways along
 which nitrogen is moved and transformed
 (U.S. EPA 2011). However, this
 scientific rigor should not serve to
 confuse the problem but communicate
 alternatives in such a way that
 management of land use is attainable for
 decision makers (U.S. EPA 2012). A
 fruitful approach to communicate the
 relationships between N processing and
 land use or land cover is through static
 and interactive maps supported by models
 of N processing (Kellogg et al. 2010).
 The N-Sink nitrogen management tool
 summarizes the complex biological,
 chemical, and physical conveyance of N
 to support watershed N management
 decisions with sound scientific
 information and a means by which to
 visualize alternative decisions.
 Since the sources, sinks, and conveyance
 of N is highly landscape and hydrology
 dependent, the N-Sink tool helps decision
 makers summarize the influence of
 sources and sinks within a watershed. In
 terms of sources, N export from urban
 and suburban watersheds is much higher
 than from forested watersheds, although
 lower than from agricultural watersheds
           This screen capture shows calculation of a flow path from source to watershed
           outlet (red line). A web-based beta version of N-Sink is available at
           http://clear.uconn.edu/projects/nsink
            (Groffman et al. 2004). High
            concentrations of nitrate in shallow
            groundwater and streams are correlated
            with agricultural land use and unsewered
            residential developments (Nowicki and
            Gold, 2008). Sink areas include wetlands,
            hydric soils, reservoirs, small-order
            streams and impoundments (Groffman et
            al., 2003). In particular, riparian wetlands
            can be a significant sink for N due to the
            combination of surface filtering of
            sediments, plant and microbial uptake,
            and subsurface denitrification (Gold et
            al., 2001). Studies in both urbanizing
            (Kaushal et al.  2008) and agricultural
            (Clausen et al. 2000) watersheds have
            demonstrated that riparian restoration can
            reduce the delivery of nitrogen to
            streams. Given the complexity of N
            dynamics, there is a need to incorporate
            our understanding of land use and
            nitrogen cycling relationships into a tool
            that can guide land use decisions that
            support sustainable and healthy
communities. In most areas local land
use decision makers have little
knowledge about N sources and sinks,
and thus no way in which to factor N
pollution into their land use policies and
decisions. A relatively easy-to-use
decision support tool that identifies N
sources and sinks in a watershed, and
estimates delivery efficiencies from
particular locations in the watershed to
the outlet is a valuable asset for
communities to help reduce N pollution
to their waters. This is the objective
behind the development and testing of the
N-Sink tool.

The N-Sink Tool

N-Sink is a customized ArcMape
program that provides maps of N sources
and sinks within a watershed, and
estimates the delivery efficiency of N
movement from sources to the watershed
outlet. The primary objective of N-Sink is
to assist land use planners, watershed
         U.S. Environmental Protection Agency
         Office of Research and Development

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managers, and land conservation
organizations to evaluate proposed
development, prioritize restoration
projects, and focus resources in areas that
are most likely to yield reductions in N
delivery to coastal waters.

Land cover and N movement
relationships taken from the scientific
literature  are used to identify N source
and sink areas, and to roughly quantify
their impact on the N budget. This
information, combined with modeling of
water flow at the catchment scale using
the ArcHydro extension to ArcGIS
(Maidment, 2002) is used to estimate
downstream delivery efficiencies. N-Sink
is developed with widely available
national databases in order to provide
broad applicability. These data include:
 •  Topography (National Elevation
    Dataset, USGS)
 •  Hydrography (National Hydrography
    Dataset, USGS)
 •  Soils (Soil Survey Geographic
    Database, USDA/NRCS)
 •  Land cover (National Land Cover
    Dataset, multi-agency consortium)

N-Sink incorporates many complex
biogeochemical and hydrologic
relationships inaccessible to decision
makers. However, the goals of broad
applicability and ease of use dictate a
trade-off in precision of the N delivery
estimates. N-Sink works as a
prioritization and visualization tool,
which enables users to understand how N
moves in  a given watershed and
investigate the relative N-related impacts
of various land use scenarios. As such,
the numeric outputs of the tool focus on
percent removal of nitrogen from source
to receiving water, rather than specific
loading estimates.

The U.S.  EPA's Nitrogen Management
Group as  part of the Sustainable and
Healthy Communities program helps
support the ongoing development of N-
Sink. The early prototype base model for
N-Sink created by the University of
Rhode Island (URI), in partnership with
Arizona State University and the
University of Connecticut (UConn)
(Kellogg et al., 2010) was funded by the
USDA/NIFA Water Program. Together,
these groups work to bring N-Sink to
community decision makers.
Project Objectives

The objectives of the current project team
from UConn, URI, and EPA are to:

(1) Develop a web-based version (figure).
The original version, developed in 2010,
requires significant reprogramming to
take advantage of technological
improvements and modern ability to
bring the tool to the public. Geospatial
experts at URI and UConn are testing the
tool for the technical soundness of with
the modern upgrades and works to ensure
N-Sinks functionality in today's desktop
and internet environment.

(2) Develop visual (map) outputs of the
tool for their utility at the local level.
UConn's Center for Land Use Education
and Research, most notably the Nonpoint
Education for Municipal Officials
(NEMO) program, has a long and
successful history of taking geospatial
environmental information and folding it
into educational programs and products
that assist local land use decision makers
(Arnold et al., 2000).

(3) Characterize N sources and sinks in
two small (USGS Hydrologic Unit Code
12-digit) pilot watersheds in Connecticut
and/or Rhode Island. The Niantic River
watershed in Southeast Connecticut has
already been selected as one of these
pilots.

With a successful outcome to this project,
the N-Sink team hopes to incorporate the
N-Sink maps and information into
educational outreach programs for local
land use officials, watershed groups, and
nonprofit organizations beyond the pilot
watersheds.

References
Arnold, C.L., Jr., D.L. Civco, S. Prisloe J.D. Kurd,
  and J. Stacker. 2000. Remote sensing-enhanced
  outreach education as a decision support system
  for  local  land use officials. Photogrammetric
  Engineering &  Remote  Sensing  66(10):1251-
  1260.
Clausen, J. C., K. Guillard, C. M. Sigmund and K.
 M. Dors. 2000. Water Quality Changes from
 Riparian Buffer Restoration in Connecticut.
 Journal of Environmental Quality 29(6): 1751-
 1761
Gold, Arthur J., Peter M. Groffman, Kelly Addy, D.
 Q. Kellogg, Mark Stolt and Adam E. Rosenblatt.
 2001. Landscape attributes as controls on ground
 water nitrate removal capacity of riparian zones.
 Journal of the American Water Resources
 Association 37(6): 1457-1464.
Groffman, Peter M., D. J. Bain, L.E. Band, K.T.
 Belt, G.S. Brush, J.M. Grove, R.V. Pouyat, I.C.
 Yesilonis, and W.C. Zipperer. 2003.  Down by the
 riverside: urban riparian ecology. Frontiers of
 Ecology andthe Environment 1:315-321.
Groffman, Peter M., Neely L. Law, Kenneth T.
 Belt, Lawrence E. Band, and Gary T. Fisher.
 2004. Nitrogen fluxes and retention in urban
 watershed ecosystems. Ecosystems Volume 7:
 393-403.
Kaushal, Sujay S., Peter M. Groffman, Paul M.
 Mayer, Elise Striz, and Arthur J. Gold. 2008.
 Effects of stream restoration on denitrification in
 an urbanizing watersheds. Ecological
 Applications 18(3): 789-804.
Kellogg, D. Q., Arthur J. Gold, Suzanne Cox, Kelly
 Addy and Peter V. August. 2010. A geospatial
 approach for assessing denitrification  sinks within
 lower-order catchments. Ecological Engineering
 (36): 1596-1606.
Maidment, D.R. (Ed.), 2002. Arc Hydro: GIS for
 Water Resources. Environmental Systems
 Research Institute, Inc., Redlands, CA.Mass. DEP
 website, accessed 01/03/13: http://www.mass.gov/
 dep/water/resources/tmdls.htm
Nowicki, B. and A. J. Gold.  2008. Nutrient
  transport in groundwater at the coastal margin.
  In: Desbonnet, A. Costal-Fierce, B.A. (Eds),
  Science foe Ecosystem-based Management:
  Narragansett Bay in the 21st Century. Springer
  Series in Env. Mngt, New York NY. Pages 67-
  100. http://www.dec.nv.gov/docs/water pdf
  tmdlnitrpecn.pdf
U.S. EPA Science Advisory Board. 2011. Reactive
 Nitrogen in the United States: An Analysis of
 Inputs, Flows, Consequences and Management
 Options. A Report of the EPA Science Advisory
 Board (EPA-SAB-11-013) http://www.epa.gov/sab
U.S. EPA Science Advisory Board. 2012. Science
 Integration for Decision Making at the U.S.
 Environmental Protection Agency (EPA-SAB-12-
 008) http://www.epa.gov/sab


Contacts:
Dr. Ken J. Forshay
US EPA Office of Research and Development
(580)4368912
Forshav. Ken(g)EPA. gov

Dr. Q Kellogg
University of Rhode Island
(401)874-4866
qfgtedc.uri.edu

Chet Arnold
University of Connecticut
(860) 345-5230
Chester, arnoldfgjuconn.edu

Dr. David Burden
US EPA Office of Research and Development
(580) 436 8606
Burden.David(a).EPA.gov
         U.S. Environmental Protection Agency
         Office of Research and Development

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