Primary Lead Smelter: Doe Run Herculaneum Missouri Volume II of Ill


United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park, NC 27711
EPA-454/R-99-032b
August 1999
Air
    &EPA
    Primary Lead  Smelter

    Doe Run
    Herculaneum, Missouri
    Volume II  of

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            FINAL REPORT
       PRIMARY LEAD SMELTER
               DOE RUN
       HERCULANEUM, MISSOURI

           VOLUME II OF III
            APPENDIX B,l
        EPA Contract No. 68D70069
        Work Assignment No. 2-09


              Prepared for:

        Thomas J. Logan (MD-14)
        Work Assignment Manager
       SCGB, EMC, EMAD, OAQPS
    U.S. Environmental Protection Agency
     Research Triangle Park, NC  27711


              August 1999
              Submitted by:

PACIFIC ENVIRONMENTAL SERVICES, INC
       5001 S. Miami Blvd., Suite 300
          Post Office Box 12077
   Research Triangle Park, NC 27709-2077
    (919)941-0333 FAX (919) 941-0234

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                                 DISCLAIMER

      This document was prepared by Pacific Environmental Services, Inc. (PES) under EPA
Contract No. 68D70069, Work Assignment No. 2-09. This document has passed PES'
internal quality assurance review and has been approved for distribution. The contents of this
document do not necessarily reflect the views and policies of the U.S. EPA. Mention of trade
names does not constitute endorsement by the EPA or PES.

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                       TABLE OF CONTENTS

                                                            Page

VOLUME!

1.0   INTRODUCTION	1-1

2.0   SUMMARY OF RESULTS  	2-1

     2.1   EMISSIONS TEST LOG	2-1
     2.2   NO. 5 BAGHOUSE OUTLET	2-1
     2.3   BLAST FURNACE OUTLETS	2-19

3.0   PROCESS DESCRIPTION	3-1

4.0   SAMPLING LOCATIONS	4-1

     4.1   BLAST FURNACE OUTLETS	4-1
     4,2   NO. 5 BAGHOUSE OUTLET	'	4-4

5.0   SAMPLING AND ANALYTICAL PROCEDURES 	5-1

     5.1   LOCATION OF MEASUREMENT SITES AND SAMPLE/
          VELOCITY TRAVERSE POINTS	5-1
     5.2   DETERMINATION OF FLUE GAS VOLUMETRIC FLOW RATE	5-1
     5.3   DETERMINATION OF FLUE GAS DRY MOLECULAR WEIGHT	5-4
     5.4   DETERMINATION OF FLUE GAS MOISTURE CONTENT	5-4
     5.5   DETERMINATION OF CARBON MONOXIDE CONCENTRATION . . . 5-4
     5,6   DETERMINATION OF VOLATILE ORGANIC HAZARDOUS AIR
          POLLUTANTS (VOHAPS)	5-5
     5.7   DETERMINATION OF SEMI-VOLATILE ORGANIC HAZARDOUS
          AIR POLLUTANTS (SVOHAPS) 	5-5
     5.8   DETERMINATION OF ALDEHYDES AND KETONES	5-8
     5.9   DETERMINATION OF GASEOUS ORGANIC COMPOUNDS BY
          DIRECT INTERFACE GC/MS	5-8
                               111

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                   TABLE 01* CONTENTS (Continued)
                                                             Page

6.0   DATA QUALITY OBJECTIVES	6-1

7.0   QUALITY ASSURANCE/QUALITY CONTROL (QA/QC)	7-1

     7.1   CALIBRATION AND PREPARATION OF APPARATUS 	7-1
     7.2   REAGENTS AND GI.ASSWAKK PREPARATION	7-4
     7.3   ON-SITE SAMPLING	7-6
     7.4   SAMPLE RECOVERY	7-9
     7.5   ON-SITE ANALYSES 	7-9
     7.6   LABORATORY ANALYSIS	7-10
APPENDIX A:
APPENDIX A.I:
APPENDIX A. 1.1:

APPENDIX A. 1.2:

APPENDIX A. 1.3:

APPENDIX A. 1.4:

APPENDIX A.2:


VOLUME. II

APPENDIX B:
APPENDIX B.I:
RAW FIELD DATA 	  A-l
RAW FIELD DATA, NO. 5 BAGHOUSE OUTLET
RAW FIELD DATA, NO. 5 BAGHOUSE OUTLET,
VOLATILE ORGANIC HAPS
RAW FIELD DATA, NO. 5 BAGHOUSE OUTLET,
SEMIVOLATILE ORGANIC HAPS
RAW FIELD DATA, NO. 5 BAGIIOUSE OUTLET,
ALDEHYDES AND KETONES
RAW FIELD DATA, NO. 5 BAGHOUSE OUTLET,
CO & FLUE GAS COMPOSITION
RAW FIELD DATA, NOS. 1, 2 AND 3 BLAST FURNACE
OUTLETS
ANALYTICAL DATA 	  B-l
ANALYTICAL DATA, VOLATILE ORGANTCS
VOLUME III

APPENDIX B.2:
APPENDIX B.3:

APPENDIX C:
APPENDIX C.I:
APPENDIX C.2:
APPENDIX C.3:
APPENDIX C.4:
ANALYTICAL DATA, SEMIVOLATILE ORGANICS
ANALYTICAL DATA, ALDEHYDES AND KETONES

CALCULATIONS	
CALCULATIONS, VOLATILE ORGANICS
CALCULATIONS, SKM1 VOLATILE ORGANICS
CALCULATIONS, ALDEHYDES AND KETONES
CALCULATIONS, VOLUMETRIC AIR FLOW RATES AND
MOISTURE
C-l
                                IV

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                   TABLE OF CONTENTS (Concluded)
APPENDIX D:     QA/QC DATA	,. .  D-l

APPENDIX E:     GASEOUS ORGANIC COMPOUNDS BY DIRECT
               INTERFACE GC/MS	E-l

APPENDIX F:     PROCESS DATA 	F-l

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   APPENDIX B




ANALYTICAL DATA

-------
   APPENDIX B.I




 ANALYTICAL DATA




VOLATILE ORGANICS

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                             CASE NARRATIVE
                    Analysis of Samples for the Presence of


                             Volatile Analytes by


 High-Resolution Gas Chromatography / Low-Resolution Mass Spectrometry
                        METHOD  8240A Rev. 1 (7/92)
          Date:

          Client ID :
July 25, 1997
Pacific Environmental Services
          TLI Project Number :     42284
This report should only be reproduced in full Any partial reproduction of this report requires permission from
Triangle Laboratories, Inc.
                                             Triangle Laboratories, Inc.
                                  801 Capltola Drive            P.O. Box 13485
                                  Durham, NC 27713-4411        Research Triangle Park, NC 27709-3485
                                  919-544-5729               Fax #919-544-5491

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Triangle Laboratories, Inc. July 25,1997
Case Narrative 42284

Objective: Analysis of eighteen VOST tube pairs for Method 8240 Table 2 and Clean Air Act (CAA)
volatile compounds and Tentatively Identified Compounds (TIC's).
Method:

Nineteen VOST tube pairs were received at Triangle Laboratories, Inc. on June 30, 1997 at 20°C and in
good condition. The samples were stored in a refrigerator at 4°C prior to analysis. The first field blank
pair was not analyzed per client request. The remaining VOST tube sample pairs were analyzed in tandem
according to the guidelines of Methods 8240A and 5040. The internal standards and surrogate standards
were added in the amount of 0.25 micrograms (ug) immediately prior to analysis by GC/MS. The internal
standards are bromochloromethane, 1,4-difluorobenzene, and chlorobenzene-d5 and the surrogate
standards reported are l,2-dichloroethane-d4, benzene-d«, and toluene-ds. The results reported relate
only to the items tested.

The GC/MS analysis conditions are listed below:

Purge and trap: Tekmar LSC-2000
Purge: 11 min.
Desorb Temperature: 250 C
Desorb Time: 3 min.

GC Conditions:
Column: 30 m x .53 mm x 0.3w J&W DB624
0 C hold .5 min, 10 C/min to 45C» 6 C/min to 90C, hold 1.5 min,
50 C/min to 200C.

MS Conditions:
Instrument: VG-TRIQ-1 Lab Base data system
Scan: 35-350 amu at ,6s/scan
Interface: Jet Separator, 200 C
Report:

Enclosed with die ease narrative are copies of the sample identification index, the project summary
sheets, client paperwork, sample log-in sheets, and log book pages. A sample identification index
summarizes the client sample name, TLI sample number, and analytical file name for each sample and
blank. The project summary lists the amounts for detected analytes in gray. The estimated detection
limits will be listed in parentheses when the target analytes are not detected.

The data are reported as quantitation reports, chromatograms, interim reports, and spectra of detected
target analytes and TICs. The quantitation report header lists the TLI project number, analysis method,
instrument sample file name, client sample name, client project number, TLI sample number, calibration
file, date received, and analysis date. The response factors used for all calculations are from the
calibration file listed in the header. All initial and continuing calibration data are located in the back of die
data package. The amount is reported in total ug for the VOST tubes. The retention lime (RT) will be

-------
Triangle Laboratories, Inc. July 25,1997
Case Narrative 42284

listed for all internal standards and analytes which are detected. If a target analyte is not detected, it will
be flagged with a "U" and a detection limit will be listed. Estimated detection limits are calculated for all
analytes which were not found in the samples by using an area of 2000. The estimated detection limits
reported are the average detection limits achievable over time on an instrument type. The actual
detection limit for a given compound on a given day may vary from the estimate reported. The
quantitation limit for all analytes is half of the low point of the initial calibration. Below this point the
calibration cannot be considered to be linear. Any amount reported at a level below the quantitation limit
will be flagged with a "J" and should be considered estimated. If any compounds are found at a level
above the upper calibration range, the analyte will be flagged with an "E" and the amounts reported
should be considered estimated. If any target analytes found in the laboratory blanks are detected in the
associated samples, they will be flagged with a "B" on each sample topsheet All analytes are quantitated
against the internal standard preceding them on the target analyte list. Surrogate standards are
quantitated against the internal standard with the matching internal standard reference number. For
example, toluene-d8 has 3 in the IS Ref column and would be quantitated against the internal standard
which has IS3 listed in the flag column. If an internal standard area is above or below the quality control
limits as defined by the continuing calibration, it will be flagged with "High" or "Low" in the flag column.

In addition to the quantitation report, a tentatively identified compound (TIC) report is also
present. The TIC report includes the TIC name, retention time and area, and the internal standard
retention time and area. TIC's are reported when they elute within a window of minus one
minute from the first and plus one minute from the last target analytes' retention times, and are
greater than ten percent of the nearest internal standard area. The results should be considered
estimates because they are calculated using the total ion current areas of the internal standards.
These TIC's were searched against the NIST library and the best three matches were obtained.
From this information a tentative identification was assigned. All of the spectral searches are
included in the data package behind the spectra of the target analytes.
Results:

There were minor discrepancies between the sample identifications listed on the client chain of
custody and those listed on the samples which arrived. The identifications on the sample labels
were used for analytical and reporting purposes.

The VOST tube pairs were analyzed within the fourteen day sampling to analysis holding time. The
VOST tubes were analyzed in tandem per client request.

Several target analytes were found at an amount above the upper calibration limit of one microgram in
several of the samples. These compound is flagged with "E" and the amounts reported should be
considered estimated.

All internal standard areas and surrogate standard percent recoveries were within quality control limits for
all samples and blanks.

Up to ten of the largest non-target peaks were reported as TIC's. The majority of non-target analytes
were siloxanes and hydrocarbons.

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Triangle Laboratories, Inc.                                         July 25,1997
Case Narrative                                                             42284

The laboratory blanks contained target analytes at amounts below the quantitation limit.  The target
analytes in the laboratory blanks should not be considered as truly present in the native samples unless
found at a level at least five times the amount found in the associated blank. In the event that the amount
of a target analyte found in the samples is twenty times the amount found in the associated blank, the
contribution from the blank can be considered negligible.
Sample Calculations:

Response Factor (RF) =     (area analyte) x famt IS)
                           (area IS) x (ami analyte)

Amount  (ug) =             (area analyte in sample) x (amt IS)
                           (area IS) x (avg ical RF)

TIC amount (ug) =         (Total Ion Current Area of TIC) x (amt IS)
                           (Total Ion Current Area of IS)

Where:

amt IS = amount of internal standard = 0.25 ug
ical = initial calibration


The data in this package has been judged to be valid according to the guidelines of Methods 8240A and
5040 except as noted above.  Should you have any questions, please feel free to contact our Project
Scientist, Amy Boehm, at (919) 544-5729, ext. 268.
For Triangle Laboratories, Inc.,

Report Preparation:                                Quality Control:
Warden
Tracy Warden                                     £>^<*.W A . (\>\o
Report Preparation Chemist                         Report Preparation Chemist
 The total number of pages in this data package is

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                                 -1 fVTi P
                    TRIANGLE LABORATORIES, INC

                USTT OF CEHT7RCATIONS AND ACCaBDTTA'nONS
fflVmONMENTAL

American Association for Laboratory Accreditation.  Expires July 31,  1997,  Certificate
Number 0226-01.  Accreuitaflcn for tetfmical competence in Environmental Testing.(lndudlng
Waste Water. Sol/Haz Waste,  Pulp/Paper,  and Air Matrices)  Parameters are AOX/TCX,
Vaiatiles. Pesticides, PCS's. SNA's, and OioxWFuran. Method 1613 for Drinking Water.

Stats of Alabama. Department of Environmental Management. Expires December 31,
1997. Laboratory I.O. * 40950. Otoxin in drinking'water.

State of Alaska, Department of Environmental Conservation.  Expires Decamner 21,1997,
Certificate number QS-Q0397. Dk3»n in drinking water.

Stats of Arizona, Department of Health  Services.   Expires May 26. 1997. Certificate
»AZQ423. Drinking Water far Dioxin. Dtoxin in WW and S/H Waste.

State of Arkansas, Department of Pollution Control and Ecology.  Expires February 18,
1998. Pulp/paper, soil, '/rater, and Hazardous Waste far Dtaxin/Furan: ACX/TQX

State of California, Department of Health Services. Expires August 31, 1997. Certificate
#1922. Selected Metals in Waste Water Vdafles, Semf-voiatfes, and Cioxrn/furart in WW and
Soi/Haz Waste. Dioxin in drinking water.

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Registration #PH-0117. Dioxin in drinking water.

Delaware Health and Social Services. Expires December 31, 19S7. Certificate *NC 140.
Dfexin in drinking water.

Florida Department of Health and Rehabfiufte Services. Expires June 30,1997.Dfoxtn in
DW, Drinking Water ID HRS# 37424.  Metate, Extractabie Crgarrics (GC/MS), Pastfddes/PCS's
(GC) and Valatiles (GC/MS) in Environmental Samples.  Envitanmental water ID HRS*
687411.
                                          Tritngi* Laboratories, Inc.
                                 8O1 C*Ma Drive            P.O. Box 13485
                                 Ourta^WC27773-W7T         Flwttrtti THmig* Paric, NC ZJT09-348S
                                 919W&2S                Fax*919444-S49t
                                                                              •1_L 1

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status far regulatory purposes.

Idaho Department at Heaflh aid Welfare. Expires November 30, 1997. Cloadn in drinking
water.

Slate of Kansas, Department of Health and Environment Expires January 31, 1998.
Environmental Artaiyses/Ncn potable Water and Sotid and Hazardous Waste. Method 1613
for drinking water. ID fs - Drinking 'water and/or pollution control - E-215. SaM or Hazardous
Waste -E-12CS.

Commonwealth of Kentucky, Department for Environmental Protection. Expires
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Maryland Department of Health and Mental Hygiene. Expires September 30, 1997.
Certification *23S. Drinking water by Method 1813A.
Slate of Michigan, Department of Public Health. Expires March 31, 1997. Drinking -water by
Method 1613.

Mississippi State Departmet of Health. No aspiration date.. Oioan in drinking water.

Montana Department of Heatt and Environmental Services. Expires December 31 , 1997.
Dioxin in drinking water.
Slate of New Jersey, rifpiwteiiiii of Environmental Projection and Energy. Extended by
state. Temporary certificate tnti June 30, 1997 or sooner. ID #67351. BNAs and Vojatfles.
Otaxin in drinking water.

Stats of New Mexico, Unriroumeitt Department Expires July 31, 1997. Dioxin in drinking
water.

New York Slate Department o* Health. Expires June 30, 1997. ID §11023. Environmentai
Analyses of non-potable Vista, Sold and Hazardous Waste. Mettiod 1613 !n DW.

State of North Carolina, Depjttnem of Etivfaumnent Health and Natural Resources
Expires December 31 , 197. Certfficate # 37751. Chain in drinking water.

State of North CaroBna, Depatment of Environment, Hearth, and Natural Resources,
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Metals, pesticides & PCSs. sanH*ciatfles and vdatfles; TCLP.

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£9612. OteJdn by 1813A, 3290 and 8280.

Stats of Soutfi Carolina, Department of Health and Environmental Control. Expires April
1, 1997. Certificate number 199040001 (drinking water). Expires August 31, 1997, Certificate
number #99040002 (ottier parameters). Cioxn/Furans, SNA, Vdatiies, and PCSsfpesticsdes
under Clean Water Act 2,3,7,3-TCOO for Drinking Water, and Organic extractabies for Solid
and Hazardous Waste.

State of Tennessee. Department of Environment and Conservation. Expires February 5,
1999. ID #02992. Mejftod 1613 Drinking water onty.

U.S. Department of Agriculture Soil Permit. Expires September 30, 2002. Permit No. S*
4958. Under fie authority of trie Federal Rant Pest Act, permission is granted to receive
foreign soil samples tor use in laboratory analysis.

U.S- Army Carps of Engineers. Expires November 30, 1997. Validated to perform metticds
3280 & 3290 for LocWoourne LandOI Site Investigation, Defense Distribution Depot Projects,
and assorted projecs tor the USACS North Pacific Division laboratory.

U.S. EPA Region V. Expires November 14,1999. Otaxin in drinking water.

U.S. EPA Region VII, tor the State of Wyoming. Expires November 13, 1997. Dtaxin in
drinking water,

State of Utah, Department of Health. Expires December 31, 1997. Certificate Number E-
166. Certification tor !he Sotowrng parameters: Sefrn-Vdafles and Voiatfles under RCHA;
Valatiles under Qean Water Act Dioxn/turans by Method 8280; Drinking water for Dfcwin by
Metfiod 1613; Metals Mudng Mercury and Nteosmawe Digestot

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Organics and Purgeabte (Votelfle) Organics.

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Lab I.D. 129

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8

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                                   Triangle Laboratories of RTF
                            Sample Identification Index for Project: 42284
Client Id:
TLIIfl:
File Name;
VOST-1 SET 1 TUBEA/B T/TC
VOST-1 SET 2 TUBEA/B T/TC
VOST-1 SET 3 TUBEA/B T/TC
VOST-1 SET 4 TUBEA/B T/TC
VOST-2 SET 1 TUBEA/B T/TC
VOST-2 SET 2 TUBEA/B T/TC
VOST-2 SET 3 TUBEA/B T/TC
VOST-2 SET 4 TUBEA/B T/TC
VOST-3 SET 1 TUBEA/B T/TC
VOST-3 SET 2 TUBEA/B T/TC
VOST-3 SET 3 TUBEA/B T/TC
VOST-3 SET 4 TUBEA/B T/TC
VOST FB 2 TUBEA/B T/TC
VOST FB 3 TUBEA/ B T/TC
VOST-4 SET 1 TUBEA/B T/TC
VOST-4 SET 2 TUBEA/B T/TC
VOST-4 SET 3 TUBEA/B T/TC
VOST-4 SET 4 TUBEA/B T/TC
VOSTBLK 070897 T/TC
VOSTBLK 070997 T/TC
17346-1A.B
17346-2A,B
17346-3A,B
17346-4A,B
17346-6A,B
173-46-7A,B
17346-8A,B
17346-9 A,B
17346-10A,B
173-46-1 1A,B
17346-12A,B
17346-14A,B
17346-15A,B
17346-16A,B
17346-17A,B
17346-18A,B
17346-19A,B
VOSTBLK 070W7
VOSTBLK 0709^7
HS351
HS352
HS353
HS354
HS355
HS365
HS366
HS367
HS368
HS369
HS370
HS371
HS349
HS350
HS372
HS373
HS374
HS375
HS348
HS364
Triangle Laboratories of RTP, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 344-5491
                                                Proj_Sum v4.0

-------
                                            Triangle Laboratories of RTF
                                         Project Summary for Project 42284
Client ID: VOST-1 SF.T
1TUBEA/B
T/TC
Filename : HS351
TLJ Id : 173-46-lA,B
Matrix : VOST
Units : ug
VOST-1 SFT VOST-1 SET
2TUBEA/B 3TUBEA/B
T/TC T/TC
HS352 HS353
173-t6-2A,B 173-46-3A,B
VOST VOST
VOST-1 SET
4TUBEA/B
T/TC
HS354
VOST
ug
VOST-2 SFT
1 TUBEA/B
T/TC
HS355
173-i6-6A,B
VOST

' ChJoromethane ;K;;;::™;';™J
Z Vinvl Chloride
; 1,3-Butadiene K'M:%iM
-• Bromomethane S^fE'-:
^ Chloroethane
i, Vinyl bromide
- Trichlorofluoromethane > wSfKm
i 1,1-Dichloroethene
- lodomethane
• Carbon disulfide fg:?j:S®JsK
; Acetone :2, WJ3K-&
> I Allyl chloride
» • .1 i ii . i -.••.••.•:•.•::•..•.•:•:•..•.-..•
trans-l,2-Dichloroethene
tert-Butyl methyl ether
.- Acrylonitrilc
• - n-Hexane I'llfli;
> 1,1-Dichloroethane
.c 1,2-Epoxybutane
'.o cis-l,2-Dichloroethene
z'- Chloroform
•• . 1,2-Dichloroethane
- Isooctane . „ ,, .,,
Vinyl acetate
2-Butanone •• '<•
'••• 1,1,1-Trichloroethane .'?'?• ':% '!
••> Carbon tetrachloride ..<.".
Benzene f~. '• \ [ . ,
-1- Tricnloroethene
•'. - 1,2-Dichloropropane
- Ethyl acrylate
:• . Methyl methacrylate •', -ir
'- Bromodichloromethane
cis-l^-Dichloropropene
'" trans-13-Dichloropropene
:::;()2|g^:
(0.001)
'•••••/^-Jl'2'iK"
iiffioii
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
y--*-:ii«..-:'.v^j:-7*W/V': :•.-:•::•:•:•:••>•:;.:•
(0.001)
(0.001)
(0.003)
IfSIBIW^i
(0.001)
(0.003)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
)-E»timated Detection Limit
:•:::::!: 0320;
(0.001)
i;it(HJ2*
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.003)
lES!:
(0.001)
(0.003)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
Page 1
::H-::i-i:KH?H:l::::8iS7J?
(0.001)
Slliiftlioiii
(0.001)
(0.001)
(0.001)
iiliiiilili
(0.001)
(0.001)
(0.001)
(0.003)
(0.001)
(0.003)
(0.001)
(0.001)
(0.001)
; -BJSS3.
(0.001)
(0.001)
' . ftOOS
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
:::;:-;:;;::.:"i-:::::;.::i i'Oi^jT:
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.003)
(0.001)
(0.003)
(0.001)
(0.001) v
(0.001)
(0.001)
(0.001) v
(0.001) ,-
(0.001)
(0.001)
(0.001) x
(0.001)
(0.001)
(0.001)
Triangle Laboratories of RTF, Inc.
801 CapitoU Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
             Savor v3.5
Printed: 22:45:50 07/25/97
                                                                                                                      10

-------
                                              Triangle Laboratories of RTP
                                           Project Summary for Project 42284
Client ID:


Filename :
TLlId :
Matrix :
Units :
3'- 1,1,2-TrichJoroethane
7 "• Dibromochloromethane
-'• Ethylene dibromide
" - Bromoform
' 4-Methyl-2-pentanone
~ Toluene i
• • Tetrachloroethene
- ; 2-Hexanone
Chlorobenzene
'•• - Ethylbenzene
.., m-/p-Xylene
•--• ' o-Xylene
VS Styrene
ft 1,1,2,2-Tetrachloroethane
^ » Cumene
VOST-l SET
1 TUBEA/B
T/TC
HS351
17346-1A,B
VOST
"g
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
0.2B4
(0.001)
(0.001)
- 	 B.Q03
: i>.os?
':'. 0.10$
; 39
': - 0.24Z
(0.001)
••"'"] -'(axxxr
VOST-l SET
2 TUBEA/B
T/TC
HS352
17346-2A,B
VOST
ug
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
'.• . . . ..'.;
-------
                                             Triangle Laboratories of RTF
                                         Project Summary for Project 42284
Client ID: VOST-2 SET
2TUBEA/B
T/TC
Filename : HS365
TLI Id : 173-46-7A.B
Matrix : VOST
Units : ug
Chloromethane !
Vinyl Chloride
1,3-Butadiene '.' •
Bro mo methane ' ••
Chloroethane , , -
Vinyl bromide
Trichlorofluoromethane " ;
1,1-Dichloroethene
lodomethane
Carbon disulfide ..sM;:x
Acetone IS!
Allyl chloride
Methvlene chloride :;;SS
trans-1 ,2-Dich lo roerhene
tert-Butyl methyl ether
Acrylonitrile
n-Hexane
1,1-Dichloroethane
1,2-Epoxybutane
cis-l,2-Dichk>roethene
Chloroform
1,2-Dichloroe thane
Isooctane
Vinyl acetate
2-Butanone
1,1,1-Trichloroethane
Carbon tetrachloride
Benzene --," ,
Trichloroethene
1,2-Dichluropropane
Ethyl acrylate
Methyl methacrylate SM
Bromodichloromethane
cis-l,3-Dichloropropene
trans-l,3-Dichloropropene

6.663
(0.001)
' .;: 0.143
,'o.fl»
T- ,"0.004
(0.001)
- : -GJOS3.
(0.001)
(0.001)
:;:K:1:rSS.tfci90:
miimm
(0.001)
:;•;«;; ;fs;0«3'$9:
(0.001)
(0.001)
(0.003)
/ jyia
(0.001)
(0.003)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
\. . . {Lfll3
(0.001)
(0.001)
". ;' 0.933
(0.001)
(0.001)
(0.001)
^t^ifopcsf
(0.001)
(0.001)
(0.001)
1
VOST-2 SET VOST-2 SET
3 TUBF.A /B -I TUBE A / B
T/TC T/TC
HS366 HS367
173-46-8A,B 173-46-9A,B
VOST VOST
." . *ea» '
(0.001)
" ;•:. ati4- •.::•":
• ',. .••'.;'" oma- :"-:'
(o.ooi) , , ;
(0.001)
: - 'i>^.OiW4
(0.001)
(0.001)
i::K?^;:i:K:;i:;l:.i.;;6t|a6:i siisi:^!
::S:"!>::i::;::;::;::;i*A:>:>|:i\i*t: ::.:-:.-:.-:;';;::>
^i^iiii :i:. '•••- :i:
(0.001)
E::5-::-::S:':":':'ft:::Oi2bft: ^SS?1""1
(0.001)
(0.001)
(0.003) '? .- 1 )
- '-A- :. ftii* .;• ,„
(0.001)
(0.003)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.006) S!!;«
(0.001)
(0.001)
;?-l^'^-ft948 •;{•', ;
(0.001)
(0.001)
(0.001)
llSiiiSSiOTi: ll-14-v
(0.001)
(0.001)
(0.001)
1 VEirimited Detection Limit
..M52
(0.001)
: 0.124 '
&018. ...
JOJD04
(0.001)
" • &.051 " -
(0.001)
(0.001)
iliiiTi?! i&s
iM*MM 11
(0.002)
':;''':;::":"$23*jS JS":
(0.001)
(0.001)
-,-; l-aSSlS
... JQAGL
(0.001)
(0.004)
(0.001)
(0.001)
(0.001)
(0.001) -
(0.001)
:;-;-...-:jJ|6S§
(0.001) „
(0.001)
"„ J"m&
(0.001)
(0.001)
(0.001)
iim&& fcl
(0.001)
(0.001)
(0.001)
Page 3
VOST-3 SET
1TUBEA/B
T/TC
HS368
VOST
"g
. . ' 
-------
                                            Triangle Laboratories of RTF
                                         Project Summary for Project 42284
Client ID; VOST-2 SET
2 TUBEA/B
T/TC
Filename : HS365
TLlId : 173-46-7 A,B
Matrix : VOST
Units : ug
1,1,2-Trichloroethane
DibromochJoromethane
Ethyiene dibromide
Bromoform
4-Methyl-2-pentanone
Toluene Sil
Tetrachloroethene llli
2-Hexanone
Chlorobenzene litp?
Ethylbenzene Slss;
m-/p-Xylene 111!
o-Xylene
Styrene
1 ,1,2,2-Tetrachloroethane
Cumene
(0.001)
(0.001)
(0.001)
(0,001)
(0.001)
WBWS&
llllaii
(0.001)
|*3$fKR|
lpsttQ6$
lllii
l^Pi
•""•'""'0273
O815
0.007
VOST-2 SET
3 TUBEA/B
T/TC
HS366
173-46-8 A,B
VCST
»g
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)

(0.001)
(0.001)
:
!
I
'. iUBSIfliii?
''''"SilSi
(0.001)
siiiisii
VOST-2 SET
4 TUBEA/B
T/TC
HS367
173-46-9A,B
VCST
ug
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
illll liS!! W*
%&%&> JSinMf
:•:•:•••:•:•:•::•::-:•:•:••: :-::-:-~v::^!r^:^:
(0.001)
«||i|t :)||||il: llli
:§^|gg; i g
1 Jiiiii l i
iiiffflp' i II
lil!llliili; !l il
(0.001)
iitliiiliBi lit
VOST-3 SET
1 TUBEA/B
T/TC
HS368
173^6-10A,B
VOST
ug
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)

(0.001)
(0.001)
iigl^B
III


ill ?|iii::
(0.001)
gi;|g||ji^
VOST-3 SET
2 TUBEA/B
T/TC
HS369
173-46-llA,B
VOST
US
(0.001)
(0.001)
(0.001)
(0.001)
(0«)1)

(OXJ01)
(QOQl]
liH^
BSII §1pK
SBIile: ;l??«?i«ra:
•.y.w.;.; -.;,£, M", V-*«' V«lMM»»S*J'''*

liSK
(OD01)
isiii iiiiife
                                          ( )-Esti»at»d Delcelion limit
Page 4
Triangle Laboratories of RTF, Inc.
801 Capltola Drive » Durham, North Carolina 27713
Phone (919) 544-5729 • Fax: (919) 544-5491
                                       Savar v3.5
                          Printed:22:4550 07/25/97
                                                                                                                  13
-------
                                             Triangle Laboratories of RTF
                                         Project Summary for Project 42284
Client ID:


Filename :
TUld :
Matrix :
Units :
Chloromethane ;;;;;;:
Vinyl Chloride
1,3-Butadiene H
Bromornethane -si!H|
Chloroethane
Vinyl bromide
Trichlorofluoromethane K
1,1-Dichloroethene
lodomethane
Carbon disulfide
Acetone
Allyl chloride
Methy lene chloride . •
trans-l,2-Dichloroethene
tert-Butyl methyl ether
Acrylonitrile
n-Hexane X •,
1,1-Dichloroethane
1,2-Epoxybutane
cis-l,2-Dichloroethene
Chloroform
1 ,2-Dichloroethane
Isooctane
Vinyl acetate
2-Butanone
1,1,1-Trichloroethane
Carbon tetrachloride
Benzene
Trichloroethene
1 ,2-Dichloropropane
Ethyl acrylate
Methyl methacrylate |i
Bromodichloromethane
cis-1 ,3-Dichloropropene
trans- 1 ^-Dichloro propene
VOST-3 SET
3TUBEA/B
T/TC
HS370
173^6-12A,B
VOST
ug

..,.;:U Q.9SO -*~^
(0.001)
(0.003)
(0.001)
y;7";' ;"^J^P
(0.001)
;:.;^|r .;• -cum1
(0.001)
(0.005)
(0.001)
;£;:::, 'IT '.I^ia;
.»,-•;•' ...-.-. <£6*2 ::..
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
VOSTFB3
TUBEA/BT/
TC
HS350
173-46-15A,B
VOST
ug
lllmoJii if
(0.001)
(0.001) lit
(0.001) HI
(o.ooi) iif:
(0.001)
(0.001) H
(0.001)
(0.001)
(0.001) '..,.
.,0037 .,..,
(0.001)
.:• ;,0.0*l" '•,;.;,.
(0.001)
(0.001)
(0.003) - -
"~~~ """QMS" S
(0.001)
(0.003)
(0.001)
(0.001)
(0.001)
(o.ooi) '::"'',
(0.001)
(0.006) fr~
(0.001)
(0.001)
v" TOJKO } -.
(0.001) .. '.
(0.001)
(0.001)
(0.001) ''-'
(0.001)
(0.001)
(0.001)
VOST-4 SET
1TUBEA/B
T/TC
HS372
173-46-16A,B
VOST
ug
iillilii;
(0.001)

|!.:::::?|||;:g5gHji
iii;»
(0.001)
sgiiiffi
(0.001)
(0.001)
>: ;:.:.'- p^
r,l "osm
(0.001)
.- - ^ii*^
(0.001)
(0.001)
-~ -'. . 1532
n?r 0^3
(0.001)
(0.003)
(0.001)
(0.001)
(0.001)
'Vt ' ' Q&Q6
(0.001)
^-"-0-625
(0.001)
(0.001)
", ; .aasa
.. .8.001
(0.001)
(0.001)
r'! 013T
(0.001)
(0.001)
(0.001)
( )-EsHmatcd Detection Limit Page 5
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
             Savar v3.5
Printed: 22:45:50 07/25/97
-------
                                            Triangle Laboratories of RTF
                                         Project Summary for Project 42284
Client ID:
Filename :
TUId ;
Matrix :
Units :
1,1,2-Triehloroethane
DibromochJoromethane
Ethyiene dibromide
Bromoform
4-Methyl-2-pentanone
Toluene
Tetrachloroethene
2-Hexanone
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylcne
Styrene
1,1,2,2-Tetrachloroethane
Cumene
VOST-3 SET
3TUBEA/B
T/TC
HS370
VOST
ug
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
0351
(0.001)
(0.001)

(0.001)
iiillslJilR
VOST-3 SET
4TUBEA/B
T/TC
HS371
173-46-13A,B
VOST
ug
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
W99
(0.001)
(0.001)
m
i!
(0.001)
111 |||siB^
VOST FB 2
TUBEA/BT/
TC
HS349
173-46-14A,B
VOST
ug
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
04151
(0.001)
(0.001)
(0.001)
HHiitllMi

(0.001)
IBIS illiMH
VOSTFB3 VOST-4SET
rUBEA/B T/ 1 TUBEA/B
TC T/TC
HS350 HS372
173^16-15A,B 173-46-16A,B
VOST VOST
ug ug
(0.001) (0.001)
(0.001) (0.001)
(0.001) (0.001)
(0.001) (0.001)
(0.001) (0.001)
D-Oli 0.433
(0.001) (0.001)
(0.001) (0.001)
(0.001)
(0.001) 1 ill
(0.001) " i i!
(0.001) 1 "iiff
(0.001)
(o.ooi) 1 Hi
IJiJjQf

(0.001)
                                          (  >-Ejtinuttd Detectm Umll     Page 6
Triangla Laboratories of RTF, Inc.
801 Capitola Drive « Durham, North Carolina 27713
Phone; (919) 544-5729 • Fax- (919) 544-5491
             Savar v3.5
Printed: 22:45:50 07/25/97
                                                                                                                  15
-------
                                            Triangle Laboratories of RTF
                                         Project Summary for Project 42284
Client ID: VOST-4 SET
2TUBEA/B
T/TC
Filename : HS373
TLIId : 173-46-17A,B
Matrix : VOST
Units : ug
Chloromethane ^filfel!
Vinyl Chloride
1,3-Butadiene SS1I1
Bromomethane liPIII
Chloroethane Jllil j *
Vinyl bromide
Trichlorofluoromethane i:c:::o;mi
1,1 -Dichloroethene
lodomethane
Carbon disulfide tlsiii!:?
Acetone :S;S:'-:I1
Allvl chloride
Methylene chloride sildiS
trans-1 ^-Dichloroethene
tert-Butyl methyl ether
Acrylonitrile — ~
n-Hexane
1,1-Dichloroe thane
1,2-Epoxybutane
cis-l,2-Dichloroethene
Chloroform
1 ,2-Dichloroethane
Isooctane
Vinyl acetate
2-Butanone .•:, .... ., ,
1,1,1-Trichloroethane
Carbon tetrachloride
Benzene .>J, _- .;
Trichloroethene
1,2-Dichloropropane
Ethyl acrylate
Methyl methacrylate
Bromodichlorome thane
cis-13-Dichloropropene
trans-1 ,3-Dichloropropene

?mm
(0.001)
11:04215

yilftxjsii
(0.001)
m'Stife
(0.001)
(0.001)
IfliOITIS!
loipli
(0.001)
gSIPSSS;
(0.001)
(0.001)
Z295
»*« :«•*
111

: ft:-':-:-:-: : :•::•: :-::V»vSf2- ">-•": '• •'•'••'
(0.001)
mm n tl^il:
(0.001)
(0.001)
mm. - ^358 .,/..„ :
IIEI .?'.!'-o;o«i .'"/",
(0.001)
1B| „ ,077^ *.!~™""'
(0.001)
(0.001)
x. ,LlZJft«is ,'
-, "0:355 --" :
(0.001)
(0.003)
(0.001)
(0.001)
(0.001)
£• J Zj^oia?''
(0.001)
:^;4J „„, ,04«[i:: :
(0.001)
(0.001)
' ";:!-• 1339 .,". ".-
(0.001)
(0.001)
(0.001)
abitf •>"" -
(0.001)
(0.001)
(0.001)
^Estimated Detection Limit
iiifn;
(0.001)
S Sjjjgjgiij::
Ilffll;

:;:•:: ::::(Ji235:
(0.001)
i«:sOi02S;
(0.001)
(0.001)
,,-",0.511
';":OMI :;..
(0.001)
"': "&JJ70: 1:';;
(0.001)
(0.001)
0316
0.1B4
(0.001)
(0.003)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
O,0£J
(0.001)
(0.001)
;: ;.i:J205 f
(0.001)
(0.001)
(0.001)
": oJip!
(0.001)
(0.001)
(0.001)
Page 7
VOSTBLK 07 VOSTBLK 07
0897 T/TC 0997 T/TC
HS348 HS364
VOSTBLK 0708 VOSTBLK 0709
VOST VOST
ug ug
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
.'"'"'' 04J29 ."'""
(0.001)
"V 	 "ftjQ&f, *'*•?•-»
(0.001)
(0.001)
(0.004)
(0.001)
(0.001)
(0.003)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.006)
(0.001)
(0.001)
- . -"- ' fldoess: ~"y'"v
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)

(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
''V-0J022;
(0.001)
'. '£814
(0.001)
(0.001)
(0.004)
(0.001)
(0.001)
(0.003)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.007)
(0.001)
(0.001)
1 '0.037-
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)

Triangle Laboratories of RTF, Inc
801 Capitoia Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
             Savar v3.S
Printed: 22:45:50 07/25/97
                                                                                                                  16
-------
                                              Triangle Laboratories of RTF
                                          Project Summary for Project 47784
Client ID:


Filename :
TLJId :
Matrix :
Units :
1,1,2-Trichloroethane
Dibromochloromethane
Ethylene dibromide
Bromoform
4-Methyl-2-pentanone
Toluene
Tetrachloroethene
2-Hexanone
.-, , ,
^ruoroDerizerie
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrene
1,1,2,2-Tetrachloroethane
Cumene
VOST-4 SET
2 TUBEA/B
T/TC
HS373
173-46-17A,B
VOST
ug
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
0.621
(0.001)
(0.001)
«?!;:; ;;!" i i ii^oiftJ
.:-::::::•.:•:::;• :-:::;::;:::::y?W~^:
msmwm^
:•:-:-: 	 : •: ;•:• -:- •:•::> :•:•:•::.':& :-J^'il: .
: ;.\\ . . .;:. •:?:%. -^SK^;??;"*****-
ll:Kl:Ilffi!?P.-
ItPfffifliSesi':
(0.001)
lllSISSil&li
VOST-4 SET
3 TUBEA/B
T/TC
HS374
173-46-18A,B
VOST
ug
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
;: - - " 0435
(0.001)
(0.001)
ji£i;i !;-ix; i^:iiii-i'^yi!K^i
• >V::::::::::::::::-.:' :::'::-'.::>*^M?*y:'
mmtmiitm
. mmmmi^M
mmsmwm
- ifiiiiiiioaii
(0.001)
;
VOST-4 SET
4 TUBEA/B
T/TC
HS375
173-46-19A,B
VOST
"g
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
* '.V "'042* .
(0.001)
(0.001)
iii!«;l'H 'i!i.iiiii!':':"sj'«|»^
"i'trSS^lSftW^^Mf^??*-;1
liiiniiw

iiilnlS'
mm
(0.001)
Illilll IIMI
VOSTBLK 07
0897 T/TC

HS348
VOSTBLK 0708
VOST
U8
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
.; . . OJ308 ;;;;;;;
(0.001)
(0.001)
CO Ofll^
\\J.\AJ1./
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
VOSTBLK 07
0997 T/TC

HS364
VOSTBLK 0709
VOST
"g
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
'\'; 6JM9
(0.001)
(0.001)
foonii
\\J-\J\J i j
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
(0.001)
                                           ( )-Esrimatcd Detection Limit     Page 8
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone (919) 544-5729 •  Fax: (919) 544-5491
             Savar v3.5
Printed: 2245:50 07/25/97
-------
PACIHC ENV1RONHEKTAL SiRVICEa.
                          Centra! Park West
     5001 South Miami Boulevard. P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
           (919) 941-0333 FAX: (919} 941-0234
                                               Chain of Custody Record
Project Hum
S4Q7-003
Project Nam«
Samplers:
Abarnalhy
Dale
6/25/97
6/25/97
6/25/97
635/97
6/25/97
6/25/97
6/25/97
6/25/97
6/25/97
6/25/97
6/25/97
6/25/97
6/25/97
6/25/97
6/25/97
6/25/97
0/25/97
^6/25/97
^
Tims
1012
1012
1026
1026
1046
1046
1109
1109
1530
1530
1509
1509
1525
1525
1543
1543
1600
1600
US EPA EMC/ESD LEAD SMELTER
SW-848 M0030 (Volatile Organic Sampling Train)
FfcM Sample ID
V-1-1-A
V-1-1-B
V-1-2-A
V-1-2-B
V-1-3-A
V-1-3-B
V-1-4-A
V-1-4-B
V-FB1-A
V-FB1-B
V-2-1-A
V-2-1-B
V-2-2-A
V-2-2-B
V-2-3-A
V-2-3-B
V-2-4-A
V-2-4-B
iy: (Signature)
(Jr <>
Relinquished by: (Signature)
Relnqubhed by: (Signature)

Data/Time
fafo-ftc
Oale/Tlnw
Data/1 lirva
Sample Description
Sample Description
VOST Run Set 1 Tube A
VOST Run Set 1 Tube B
VOST Run Set 2 Tube A
VOST Run Set 2 Tube B
VOST Run Set 3 Tube A
VOST Run Set 3 Tube B
VOST Run Set 4 Tube A
VOST Run Set 4 Tube B
WpS^Fie^^a^AjbftA^
V<^rX^el^l^KVTdge^
VOST Run 2 Set 1 Tube A
VOST Run 2 Set 1 Tube B
VOST Run 2 Set 2 Tube A
VOST Run 2 Set 2 Tube B
VOST Run 2 Set 3 Tube A
VOST Run 2 Set 3 Tube B
VOST Run 2 Set 4 Tube A
VOST Runlet 4 Tube B
Recpluad by: {SlgMltirij/a^
^ /J^h^
Received by: (Signature)
Received for tab by: (Signature)
Anal jilt Requested
8240
•
•
•
•
•
•
•
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Dale/Time
Dato/Tlma
REMARKS
Remarks
rVl^y*a- A"tB
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BROKEN - NOT INCLUDED









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(Page:_1 	 of 3
-------
                                                                                                                                   •t
                                                                                                                                 -•»>*
PACIFIC ENVIRONMENTAL SERVICES. INC.
                          Central Park West
     5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Part, North Carolina 27709-2077
           (910) 941-0333 FAX: (919) 941-0234
                                                Chaln of Custody Record
Project Num
S407-003
Project Name
US EPA EMC/ESD LEAD SMELTER
Samplers:
McDonnell, Dickaraon SW-M8 M0010 (Semi volallai)
Dale
6/26/97
6/26/i7
6/26/97
6/26/97
6/26/97
6/26/97
6/26/97
6/26/97
6/26/97
6/26/97
6/26/i7
6/26/97
6/26/97
6^6/97
6/26/97
6/26/97
6/26/97
^sjj/26/97
^eHntjhJ;
L
Time
928
928
943
943
958
958
1013
1013
1400
1400
1400
1400
1420
1420
1436
1436
1457
J457
Field Sample ID
V-3-1-A
V-3-1-B
V-3-2-A
V-3-2-B
V-3-3-A
V-3-3-B
V-3-4-A
V-3-4-B
V-FB2-A
V-FB2-B
V-FB3-A
V-FB3-B
V-4-1-A
V-4-1-B
V-4-2-A
V-4-2-B
V-4-3-A
V-4-3-B
ihed^n (SlAialure)
Relinquished by: (Signature)
Reltnqubhad by: (Signature)
Date/Time
DatefTlme
Data/Time
Sample Description
VOST Run 3 Set 1 Tube A
VOST Run 3 Set 1 Tube B
VOST Run 3 Set 2 Tube A
VOST Run 3 Set 2 Tube B
VOST Run 3 Set 3 Tube A
VOST Run 3 Set 3 Tube B
VOST Run 3 Sit 4 Tube A
VOST Run 3 Set 4 Tube B
VOST Field Blank 2 Tube A
VOST Field Blank 2 Tube A
VOST Field Blank 3 Tube A
VOST Field Blank 3 Tube A
VOST Run 4 Set 1 Tube A
VOST Run 4 Set 1 Tube B
VOST Run 4 Set 2 Tube A
VOST Run 4 Set 2 Tube B
VOST Run 4 Set 3 Tube A
VOST Run 4 Set 3 Tube B
Received by: (Signature)
Received by: (Signature)
Received for lab by: (Signature)
Analysis Requested
8240
*
*
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*
*
*
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REMARKS
Remarks


















Received by; (Signature) (^ $ff/?"J
Received by^fSttfnstiffe)

[Pane: 2 at 3
-------
PACIFIC ENVIRONMENTAL SERVICES. INC.
                          Central Park Wast
     6001 South Miami Boulevard, P.O. Box 12077
Research Triangle Pack, North Carolina 27709-2077
           (919)941-0333 FAX: (919)941-0234
                                               Chain of Custody Record
Project Num
S407-003
Projad Name
Samplers:
McOonnaD, Dlckerson
Date
6/26/97
6/26/97















x"\ *
Rgflftquf&H
~t%
Time
1511
1511















J-N y
US EPA EMC/ESD LEAD SMELTER
SW-848 M0010 (Seml-volatles)
Field Sample ID
V-4-4-A
V-4-4-B
















M(sBnuJ»l
Relinquished by: (Signature)
Relinquished by. (Signature)

Data/Time
Date/Time
Date/Dm*
Sample Description
VOST Run 4 Set 4 Tube A
VOST Run 4 Set 4 Tube B
















Received by: (Signature)
Received by. (Stratum)
Received for lab by; (Signature)
Analyst* Raquastsd,
8240
*
*

















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Remarks


















Received by: (SloiMlure) S/ ,-/~,
""""^ l&Ur">

^«i«:_a 	 o»_3 	
-------
|| Custody Seal Absent Sample Seals i Absent
j| Chair of Custody Present Container...! Intact
I Sample Tags Absent
I Sample Tag Numbers Not Listed on Chain of Custody
jj SMO Form N/A
|| Ice Chest ICB Temp 20.0 C
j|TLI Number ...Client Sample ID 	 Matrix
||mR/H:CPM. 	 Client COC ID 	 • Location 	
g
To LAB
Date/Init
(173-46-1A VOST-1 SET 1 TUBEA TENAX
| V-l 1-A • R026
§173-46-18 VOST-1 SET 1 TUBES TNX/CHAR
1 V-l 1-B * ROJS
R173-46-2A VOST-1 SET 3 TUBEA TENAX
jj V-l 2 -A « ROJS
II


R173-46-2D VOST-1 SET 2 TUBES TNX/CHAR |
9 V-l 2-B • R02S
g j
(173-46-3A VOST-1 SET 3 TUBEA TENAX |
j V-l 3-A • R026 |
||173-46-3B VOST-1 SET 3 TUBES TNX/CHAR
|| V-l 3-B * R02S

||173-4S-4A VOST-1 SET 4 TUBBA TENAX |
IJ V-l 4-A * R026 j
||
yi73-46-4B VOST-1 SET 4 TUBES TNX/CHAR
§ V-l 4-B • R026
g
J173-46-S VOST FB SET1 TUBE B TNX/CHAR
| V-FB1-B • R026
(173-46-6A VOST-2 SET 1 TUBBA TENAX
1 V-2 1-A • R02«
1)173-46-68 VOST-2 SET 1 TUBBB TNX/CHAR
U V-2 1-B • R026




|173-46-7A VOST-2 SET 2 TUBEA TENAX |
S V-2 2 -A « R02S
J173-46-7B VOST-2 SET 3 TUBBB TNX/CHAR
j V-2 2-B • R02S
|!73-4«-8A VOST-2 SET 3 TUBEA TBNAX
| V-2 3-A • R026
To STORAGE
Date/Init














To LAB
D*t«/Init














Till Project Number 42264 j Book
Client t PBS03 - Pacific Environmental Services j
Data Received
Carrier and Number
To STORA3B
Date/Init



















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Date/Init







1 / S/ J> / .?/ / S \
06/30/97 | B/^/\/ £-*?{ 1 P*ff*
///? \ «
TO STORAGE
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Date/Init
I
t






1







1
1
1


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1
1
1




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Date/Init


















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Date/Init

1
II
1
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II
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|| Receiving Remarks:
II -
II
|| ' Archive Remarks t
-------
                                                    =TRIA1*3LB LABORATORIES, INC. -- LOO IN RECORD/CHAIN OF CUSTODY-
|| Custody Sen! : Absent Sample Seals; Absent
|[ Chain of Custody : Present Container. .. i Intact
|| Sample Tags ; Absent
|| Sample Tag Numbers i Hot Liated on Chain ot Custody
|| SHO Forum t Jt/A
|| Ice ChBBt ICS Temp 20.0 C

JinR/HiCPM 	 Client COC ID,,...,* Location 	

	 - 	
||!7J-46-»B VOST-2 SET 3 TOB1B TNX/CHAR
1| V-J 3-B * R026
"
(173-46-9A VOST-2 SET 4 TUBEA TENAX
H V-2 4 -A * R026
1! 	 — -•
[113-4S-9B VOST-2 SET 4 TUBEB TNX/CHAR
|| V-2 4-B * R02C
H113-46-3.0A VOST-3 SBT 1 TBBBA TSMUC
J V-3 1-A * R02S
	
|l73-4*-10B VOST-3 SIT 1 TUBEB TNX/CHAR
|| V-3 1-B * H02S
(173-46-J1* VOST-3 SET 2 TUBRA TFNAX
J V-3 2-A * 102«
||l73-46-llB VOST-3 SET 2 TUBEB TNX/CHAR
1 V-3 2-B * R026
[173-4S-12A VOST-3 SET 3 TUBBA TEHAX
| V-3 3-* * R02S
(173-45-12B VOST-3 SET 3 TUBES TKX/CHAR
| V-3 3-B * ISOaf
|n3-4«-UA VOST-3 SET 4 TUBBA TEMAX
| V-3 4-A * 102«
(17J-48-13B VOST-3 SET 4 TOBBB THX/CHAK
jj V-3 4-B * *02«
	
H173-4C-14A VOST FB 2 TUBBA TENAX
|| V-FB2-A * R026
IJ173-4S-14B VOST FB 2 TU9EB TNX/CHAR
I) V-TB2-B » R026
To L*B To STOWWB
Date/Inie B«t«/Init


1




















I173-4S-15A VOST FB 3 TOBBA TEHAX | |
| V-FB3-A « R02S j
TO LAB
Dat*/Init














TLI Project Number 42284 Book f
Client) PBS03 - Pacific Environmental Service* f
s,s9^* ^ 173 ,
Data Feoeiv«d
Carrier and Nunber
TO STORAGE
Data/lnit








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                                                                                                                                                                           CM

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i '   -
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| 'Archive Rawarksi
                                                                     R*via»d 05/27/1997 •- Pige 2 Or 3-
-------
I) Custody Seal Absent Sample Seals i Absent
|| chain of Custody Present Container. . . i Intaat
jj Sample Tags Absent
U Sample Tag Numbers Hot Listed on Chain of Custody
|| SMO Forms N/A
|| Ice Chest ICB Temp 20.0 C
HTLI Number 	 Client Sample ID 	 Matrix To LAB
j|rnR/H'CPM Client COC ID 	 * Location Date/Inlt

||173-4S-15B VOST FB 3 TUBEB TNX/CHARj
j] V-FB3-B * R026
||173-46-16A VOST-4 SET 1 TUBEA TEN AX |
|| V-4 1-A • R026
II
||173-46-16B VOST-4 SET 1 TUBEB Trat/CHARJ
|| V-4 1-B * R026 j
|l73-46-17A VOST-4 SBT 2 TUBEA TEN AX |
1 V-4 2-A « R026
||173-4S-17B VOST-4 SBT 2 TUBEB TNX/CHAR)
U V-4 2-B • R026 j
R173-4S-1SA VOST-4 SET 3 TUBEA TEHAX j
() V-4 3-A • R02S
||173-46-18B VOST-4 SET 3 TUBEB THX/CHAR
| V-4 3-B • R02S
||l73-4«-l»A VOST-4 SBT 4 TUBEA TBNAX
|| V-4 4-A • R02S
|
||!73-46-lSB VOST-4 SET 4 TUBEB THX/CHAR |
jj V-4 4-B • R02K
II
i



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Date/Inlt


.




-






TLI Project Number 42294 Book
Cllentt PE803 - Pacific Environmental Services
Date Received j OS/30/J7 j *^7^/Y.J£s~'£^ *•'•
Carrier and Number | ' Jr /'s^ ' 48
To LAB | To STORAGE) To LAB
Date/Init j Date/Init Date/Inlt
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Date/Init




TO LAB
Dmte/Inlt










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Date/Init












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1


I) Receiving Remarks:
II
II
||' Afclilve Remarks:
                                                                                                         00
-Form Revised- 05/21/1997 -- Page 3 OP 3-
-------
                                                 Triangle Laboratories, Inc.

                                                        Run Log
Column Type
fofeta*
Column #
*>2n loc*.
Analysis*
t^fO
Acquisition
Method
VJ*&
GC Method'
^thrt-
Flnd DBs*
"^^lA
Oilier*
A/nus^/v
Standards
Internal / Surrogate 1 Recovery
V/^'/Of-l Al«!-/OVZ-
wpnvti\\T /»;> nVi.lii
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Analyte

                                                                        Extract / Sample volume
3ale"
Tims
          Pruject
                                                                                                             Chcteimrt

                                                                                                             iL   mL
                 Sample*
Client ID
Filename
J?H*
Operalor/Dala
                                                                                    Slgrwrtwe
                                                                                                      Data
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Volatile Data Only
                                                                                         u
                              Transcribed Dala
                                                 Dated Blgnalure/lnillals Required
-------
                                                  Triangle Laboratories, Inc.
                                                          Run Log
Column Typo
         Column #
     Analysts*
  Acquisition
    Method
                                                                 OC Method
Standards
Internal t Surrogate / Recovery
B^f. j-Jlf~tf 7 w
-------
                                                      Triangle Laboratories, Inc.
                                                               Run Log
Volatile Data Only
Transcribed Data
"*  Dated Signature/Initials Required
P«fle	154—
-------
                                                      Triangle Laboratories, Inc.
                                                             Run Log
Standards
Internal / Suriogaie / Recovery
vj^l-ffcb-^
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Internal / Surrogate / Recovery

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                                                                                                                      Cltcta ut
                                                                                                              Dita
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                                            ^
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-------
                                                     Triangle Laboratories, Inc.
                                                             Run Log
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                                                                                                                                     CM
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Volatile Dala Only
                                Transcribed Dala
                                                 ***  Dated Signature/Initials Required
-------
Project Number: 42284
Sample File: HS351
                       Method 8240A VOST
Sample ID: VOST-1 SET 1 TUBEAyB T/TC
Ill
•*•: jtiwri*!^*- JiiM*^!^CS^*;Efe;U'-- ••• •• • ••••• <: '•• ••"•• •>'K:-'-x-'*§i;^:
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Chloromethane
Vinyl Chloride
1,3-Butadiene
Bromomethane
Chloroe thane
Vinyl bromide
TrichlurofluorornetJiane
1 , 1 -Dichloroethene
lodomethane
Carbon disulfide
Acetone
Ally! chloride
Methyiene chloride
trans-1 ,2- Dichloroethene
ten- Butyl methyl ether
Acrylonitrik
n-Hexane
1,1- Dichloroe thane
1 ,2-Epoxybutane
cis-1 ,2-Dichloroeihenc
Chloroform
,2- D ichloroe thane
Isooccane
1 ,4-Difluomben?£ne
Vinyl acetate




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0.122
0.017 J
U
U
1.461 E
U
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0.322
0.108 B
U
1,385 BE
U
U
U
0.412
U
U
U
0.007 J
U
0.018 J
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4.51
0.94

1.09
1.43


1.85


2.51
2.58

2.98



3.57



4.66

5.30
5.67

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0.001
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0.001
0.003
0.001

0.001


0.001




....-: -.•-.-.-.-.•::.---: .•••:• -:• •:• •:- •, •: :-:•

0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05

0.05
                        NA-No* Applicable; Dtt Limit:Detection Limit;Qtuui. Limit: Qujntiution Limit
    IS: Internal Standard; U: Undetected; B; Present In Blank; I: Estimated- Below QuantiUtion Limit E; Estimated- Above Calibration Range
Triangle Laboratories at RTF, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 54«7» • Fax; (919) 544-5491
                                       Savar V3.S
                            Printed: ISM 07/22/1997
                                                                                                       29
-------
;>^iS«.;;^?:^;^S4Sy|-jiptey«4|yS^!j^
Project Numben 42284
Sample File: HS351
Client Pm|«efc S407-003
TU ID: 173-4&-lA,8


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Method 8240A VOST
Sample ID:
Date Received: H6/30/97

Date Analyzed : 07/08/97
VOST-1 SET 1 TUBEA/B
TYTC
Response File: ICALH708






•:•,-:•.•:•:• ••••:••: •'• ."•::•>•' •'."•" : "•'- -----•--. : •:«;-:'::;:"::v:'':ii:;:; '•••-"•""'{•:•"-"•;•••*-; •;'•"•"•.'-'•'• :*i"- :••••••••••••.•.•
K%«» WIT ,*'»vri'.?iv:*v': ?;*:;•?'•'.- '''v'.S'vv •'••;•?:•'>:•?: SKK ;•:?>:•"•;:• ;•"•!• v*t*"-' •".-"•/ vS">/tv't<
J_.;L_.^;:_: .:..,*;..;:, v .:,:'- ;::,:•:•...;,.;.;.-.;.,..-, ,- , ;-;.:>::. .;:-;.f;;;;x-;- ;--.;.;••'-;• ::V;:V"V:>;:J:!-;M:A •: . x-;1"':- •:•'
.y .•.-,;.;.-.; .'..;..;,-.y.'.; -.-..; .•;.-• v.y//£.y..;_y,y.^y;A.y,;,w.;,£:\y .y.^^^^^^
ST^fS^jvv^
2-Butanone
1 ,1 , 1 -Trichloroethane
Carbon teirachloride
Benzene
T richloroethe ne
1 ,2-Dichloropropane
Ethyl acrylate
Methyl mcthacrylatc
Bromodichloromechane
cis-1 J-Dichloropropene
trans-1 ,3-Dichloropropene
1 , 1 ,2-Tf idiloroc thane
Dibromochloroinediane
Ethylene dibromide
Btomoform
Chlorobenzene-d
4-Mcthyl-2-penianone
Toluene
Tetrachlorocthenc
2-Hexanone
Chlorobcnzcne
Ethylbenzenc
tn-/p-Xylene
o-Xylene
Styrcne
1 ,1 ,2,2-Tetrachlotocthane
NA- Not Applicable;
-:^:^\.:;:.vv-x;yX-Xv;v|v>.-v ;>];:y>,-:->:->v:x ••;••;::-:•.-:-:-..•..:;.,:•:;..>. .-:>;:.;:•-•: -I-.:-::-.:-::-:.
t^^M*M^ "^SvS?: '•''Vff&jX*-'- '• ££££-?:?*&&£&'&. Xiv :;Xv
^I^WM^^^tMWk^ :.:.y:y>;.i:.:y;^fa:f ;--;.::.;;-::.>

x >•.•;%•.-.-;•>;.• :>>-'>:• ^>><->>.;,:.\;.->:%'>>.-;v>.:x:> ^;^>>^;.x,;yx;-yx;'.;5:y;:;;:;;-;:;%> !'!:•:•>;;:
|;5^?K;;:|;||||:.;:s|?l|p p:j;i»I||;ll|iSlil|
0.011 J 4.39
0.006 ] 4.75
0004 J 4.93
0,810 B 5.14
U
U
0.016 J 6.23
0.258 6.49
U
U
U
U
U
U
U
IS 3 9.79
U
0.284 B 7.60
U
U
0.003 J 9-84
0.057 10.12
0.108 1036
0.039 J 11,06
0.242 11.11
U
;:•:•: :-'::::y :.•:•::::;::•:•.:;.:•.•:•::•;:•:: :-:-:•:•: ;;:yiy.::-;-;y:;:::, ;:•?>.;•;•::••• vx.xv.
.v.:.;y4l^ll:.:-fcj| -jlytit-"-'- :---:-: ':-.-•-•-'-'•-.• •.:-:-.'jl^tfj^:|Kj l'»:'-;1
«:Mftfc:.WttOaS i-KiK :iiw*:K:i:K«!^Wltti:.!

;:•:>:•;;'->>.;:;.;>: '.-'.y". '.-:•:•'.•: '.-'•'•: :•'. :•:•'•'• •>"::•:;'•: v.vx-: :-:•: :•:•:• ':'•"•'•':' •:•;'-'; x ;':"••'' ';'
lilliS^f;5!!!;^!!^^!^!^




0.001
0.001


0.001
0.001
0.001
0.001
0.001
0.001
0.001

0.001

0.001
0.001





0.001

Siaiti:

'•'"*';• 'I';'!';';.""'' '•',

0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05

0.05
0.05
0.05
0.05
0.05
0.05
0.10
0.05
0.05
0.05
Det. Limit: Detection Limit; Quart. Limit Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; } Estimated- Below Qouitiution Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 54*5729 » Fax (919) 544-5491
             Savar v3.5
Printed: 15:01 07/22/1997
                                                                                                                     30
-------
Project Number 42284                                                              Method 8240A VOST
Sample File: HS351                                          Sample ID: VOST-1 SET 1 TUBEA/B T/TC

£lttEnJ^i^e^:^S^D^:^;i jig^ § ;:




Analyte .".. '.. :

Cumene
Surrogate Sununarjr • • •. ' ".-- • --•'- —- • ~
\ ,2-Dichloroethane-d
Benzene-d
6
Tolucnc-d
• •:•:•:•: -;:• :•.:•::•::•:-.•:-•:- :- :-x-: •:•>::::•:•:••.•:••: •:•:•:•.•:••:•::•::•:•.•:••;•.•:• :-•:••:••»:•::'•::•".•".•
::'::;:: S.ii^di^iJE^Miiilfeifi^/S'ffii!^:

i||||^^^^^^lp§5ptts


Amount • - FLAG - • • RT = :
;'" ag ;•• ' ; : ; ;:; ";•; ;••;
0.007 J 11.85
Amount -.:-?• -.." . . -U3P»\.
0.277 5.11
0.286 5.10
0.281 7.51

^^n^^^sj^^^^BSsa^

liBlilHlilllllillS'iliW^^^^


' D«fc: limit ' Quan- limit
''veg.' • '•''"' " '"••'• *g '
0.05
!^.^-*W^V»^-
1 111
2 114
3 112
Reviewed by	'TIP
                          NA- Not Applicable; Det Limit: Detection Limit; Quart. Limit: Quanritation Limit
    IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.                                                                               Savar v3.5
801 Capitola Drive « Durham, North Carolina 27713                                                      Printed: 15:01 07/22/1997
Phone: (919)544-5729 • Fax: (919) 544-5491
                                                                                                  :-      31
-------
                                 Pacific Environmental Services
Project Number:  42284                      Method 8240A
Sample File:     HS351                      Sample ID:         VOST-1 SET 1TUBEA/BT/TC
Client Project
TLIID:

S407-003


Dilution Factor:
Date Received:
Date Analyzed:
1.00
06/30/97
07/08/97

                            Tentatively Identified Compounds
         Name          :       :  Fff::: -     Area      1SHT    tSArea     Amount, aq
1 Methylbutane Isomer
? Hexamethylcyclotrisiloxane
i Unknown
" C4H8 Isomer
'J. C5H8 Isomer
'f Methyl Propane Isomer
"> Pentane
^ Tetrahydrodimethyl Pyranone Isomer
ci C6H12 Isomer
1.640
8.691
0.72
1.03
2.210
0.87
1.96
4.120
3.48
136906976
96524680
33730636
10855208
7988264
5992627
4933298
3436458
2442128
4511
9.791
4511
4511
4511
4.511
4.511
4511
4511
5104886
10613405
5104886
5104886
5104886
5104886
5104886
5104886
5104886
6.705
2.274
1.652
0.532
0.391
0293
0.242
0.168
0.120
 Triangle Laboratories, Inc.
 801 Capitola Drive * Durham, North Carolina 27713                         Printed:   10:26  07/25/97
 Phone: (919) 544-5729 * Fax: (919) 544-5491
                                                                                    32
-------
                                                                                     CO
                                                                                     CO
07-08-97  21:53         Triangle Laboratories of RTF, Inc.
Sarnie: UOSI-1 SET 1 TUBEA/B   T/TC  173-46-1A/B  TLIB42284
(919) 544-5729
  Instrument H
HS351
103


X.FS -


7 /V
r\
Nj
r> v/J
@-

2.^




i
l|
ill".,
Ii "V V\;


•f

4 9./3




3.157


ij
Min


c
L-.,A^W,




7/8
^* 1
&} j|
* ** 	 -•'* * ^ '. . ~ »-~-r^»/~i*
4.8 6.0


A\^





9.x

JU





Ul 1111
79 IT 12Q
I/ x<^

8.8 18.8 12
6728157
TIC
#1


I "

»
7§6 J j 14 53

U uu
66



i
0 14.8 16.8
                                                                                   p
                                                                                   $  r
                                                                                   o;
                                                                                   P 0
-------
UJAN'DS  :  H3351




No,  MAT FOR  REV  Delt;
   LAB-BASE   QUAN
Area P.Flag:
              07-08-97
RT
QH Name
1
•2
3
4
5
6
3
9
10
11
JM -L.
12
13
14
15
16
17
18
19
20
21
22
*^~T
•iS.01


25
26
28
29
30
31
T«"^

33
34
35
36
37


39
40
41
42
43
44
45
46
47
Af$a::

49
5O
1OO
1OO
10O
58
1OO
1OO
100
100
0

89
0
0
100
0
o
100
78
0
100
0
cr IT
*-*— '

feW
1OO
0
OS
0
47
0
94
•Z.JL.

92
38
29
100
0
* .-"*,
-fc. *
69
100
0
o
0
0
0
0
0
& "p

100
0
91
92
96
23
82
90
87
85
0
70
49
0
0
92
0
O
79
47
O
90
O
irt rt



98
O
0
11
0
6O
"9 1

72
14
10
91
0
1 n

43
96
O
O
o
o
o
0
0
r*

94
0
99
97
98
7O
84
98
94
92
0

95
0
0
99
O
O
99
81
0
98
0
j* O
- "'"*

s-*— '
100
0
0
64
0
91
/• •">

75
48
37
99
0
jfl *"*
•H .fa.
70
99
0
O
O
0
0
0
o
8,4

99
O
0
1
-3
1
O
1
0
1
0

1
0
0
1
0
o
1
1
o
1
0
-%
W1


0
0
0
0
0
1


0
— i
1
0
o
-r -I
v-*-J™
1
-1
0
0
o
o
o
0
0
•5*

1
0
359816
2204376
2834564
1073968
2918552
3619O80
18O2496
510304
0
^JffffpfiS
53160
0
0
6042424
O
0
2921O32
2O2534
0
3926276
0
53*10



2772796
0
0
39600
0
419180


3784
26308
14348
9053578
0
/ jdnii •">

71876
S50304
0
0
0
0
o
0
0
T -1 *" ^fi

2383344
0
bb
bb
bv
bv
bv
bv
vv
vv
(C
\ 31-fnHi
bb


bb


bv
vb

bv

hh



bv


bv

bv
u -.

A
bb
bb
bv

A

A
vv







,-,

bv

4
5
9
5
5
7
12
0
»Wl 0
MBT.ii.«!_
1
0
0
1
0
0
2
2
0
2
0
-r
w

w
3
0
0
4
0
5
•*yr

4
4
4
5
0
(C
— '
6
6
O
0
0
0
0
0
0
™»

7
0
.51
.67
, 79
.11
. 1O
.51
"ZQ
. O ?
,06
.94
.00

.43
.00
.00
.85
.00
.00
.51
.58
.OO
.98
.00
~Z_A
t* V-1 .

M ^.W
.57
,OO
.00
.66
.00
.30
	 IT..-?

.39
.75
.93
.14
.OO
x -7
.* O i
.23
.49
.OO
.00
.OO
,00
.00
,00
.00
tr -o

.60
.00
128
114
117
65
84
98
95
50
62
5r\ 39
94
64
106
101
96
142
76
43
76
84
96
73
S3
57
63
96
83
62
57
43
72
97
117
78
130
e T

55
69
83
75
75
97
129
107
173
43
92
164
Bromochlorome thane
1 , 4-Di f i uorobenzene
Chlorooenzene-d5
1 , 2-Oi chloroethane-~d4
Benzene— d6
Toluene-da .^SV^w
4-Bromof luoroBenzene
Chlorome thane
Vinyl Chloride
1 3~But3cJiene ^ivi'vTX'O
Brornornethane
Chloroethane
Vinyl bromide
Trichlorof luorometharie
1,1-Oichloroethene
lodornethane
Carbon disulfide
Acetone
Allyl chloride
Methylene chloride
trans-l,2-0ichloroethen«s
tert-Butyl methyl\eth^<
Acrylonitrile )
n-Hexane
1,1-Dichloroethane "\
1,2 Epoxybuts ns^ig^CV/
cis-l,2~Dichloraethene
Chloroform
1 ,2-Dichloroethane
Isooctane \
Vinyl acetats/iwQv
2-Butanone ^— ^
1,1 ,1— Trichloroethane
Carbon tetrachloride
Benzene
Trichloroethene /J=~Vw>
l,2-0ichloropropane(x^/v'
Ethyl acrylate
Methyl methacrylate
Bromodichloromethane
cis-l,3-Dichloropr opens
trans-l,3-0ichloropropen
1,1,2-Tri Chloroethane
Oibromochloromethane
Ethylene "dibromide
Bromoform 	 s >
4-Methyl-2-pentanonejvv^"
Toluene
TetrachloroGthene
                              Date:
                                   7-
                                                                          34
-------
No. MAT FOR REV Delta
Area P.Flags
QM Name

•-J _L
52
53
54
55
56
58
_-
s-»W
48
100
100
97
100
1 n
68
.,
'
15
89
86
76
94
39


63
98
94
33
98
73

u
1
0
0
0
0
1


36824
332296
782144
269684
2763012
*~* iT""1 l^l *1
167072

%' /
bb
bv
vv
bv
bv
vv


9
10
10
11
11
io,
11

- / _*.
.34
.12
.36
.06
.11
.85

MO
112
1O6
1O6
106
104
OT:
105

nexanone \\~~/\^
Chlorcbenzene
Ethylbenzane
m-/p-Xylene
o-Xylene
Sty re re >
Cumene
-------
                                                                                       CO
                                                                                       CO
07-88-97 21:53          Triangle Laboratories of RIP, Inc.
Sanple:  WST-i SEI 1 TUBEA/B  T/fC  173-4&-1A/B  TLIM2284
(919) 544 5729
  Instrument H
HB351 94 (8.940)
188
B
M/Z
5
44
,^,t)J! |ljjj
5
M
52
f,«
0 100 150 200 250
HS351'94 (0.941) HEFIHE
100
KFS-
.9
5

49
. ,_. 1.1
5
e
52
|
e 130 150 200 250
9 (8.938) Chloronethane
183
X.FS-
0-
M/Z
5

44
• i M-'
a
52

58 100 150 208 250

103424

300 350

94208


300 350
FIND
100


300 350
-------
                                                                                   r-
08-Jul-97 21:53
Sample: MOSf-1 SET i
   Triangle Laboratories of RTPj Inc.
TUBEA/B  T/TC  173-46-1A/B  TLIft42284
(919)  544-5729
  Instrunent H
HS351 109 (1.890)
I00i
XFS
0-
M/Z
3
A
9 77824
i
57
50 180 150 200 250 300 350
HS351'1B9 (1.091) KEFIHE
100i 5« 55296

XFS
0-
M/Z
53
58


50 180 ' 150 ' 280 ' 250 ' 300 ' 358
T2CAA 11 (1.080) 1,3-Butadiene FIND
108
XFS
0-
M/Z


c,
53
50
14 100

50 ' 100 ' 150 ' 280 ' 250 ' 300 ' 350
-------
                    00
                    CO
07-08-97  21:53         Triangle Laboratories of RTP, Inc.
Sample:  UOST-1  SET 1 TUBEA/B  T/TC  173-46-1A/B  TLIH42284
(919) 544-5729
  Instrument H
HS351 143
180-
XFS-

Q
44


I .
H/Z 58
HS351' 143
100
XFS
0



. . , •
3/s 58
HT2CAA 12
180
XFS


0-



46
40 /

KI/S 58
(1.438)
26624
94
93 1
U- HI
1B0 158 200 250 388 350
(1.431) REFINE
9
93
81 ]
II. ,1
• . | '," • ."
4 9408


I • • i i | • . i . 1 i i • • i .......... ....,....,....,.-.-,.--,
103 158 2O0 258 308 350
( 1 . 42B ) BroMO we thane F I ND
9

93
••-.
81 1
1,1. iJ
4 100



.

100 158 200 250 388 350
-------
                                                                                       CD
                                                                                       CT3
07-88-97  21:53
Sample: UOSf-1
i SEI
   Triangle Laboratories of RTF, Inc.
TUBEA/B  f/TC  173-46-1A/B  TLIH42284
(919) 544-5729
  Instrument H
HS351 185 (1.858)
188i 1(
47 66 82
SI
183
185
H/Z 58 180 150 200 250
HS351'1B5 (1.851) REFINE
101

XFS-
e -• -i-, 1^ 82-
183

165
i.
H/Z 58 100 158 280 258
15 (1.848) TrichlorofhioroMBthane
1801 1J
XFS-
g .,, i. 1., 82
U
103

105
117
M/Z 50 188 150 288 258

802816

300 350

745472



300 350
FIND
100


300 350
-------
-08-97 21:53          Mangle Laboratories of  RIP,  Inc.
   e: UOST-1 SET  1 TUBEA/B  T/IC  173-46-1A/B  TLH42284
(919) 544-5729
  Instrument H
HS351 251 (2.510)
1«H 7
44
0 	 i. 33^6,7
6
7? ^ ^^
w/s 58 1O0 150 200
HS351'Z51 (2.511) REFINE
7
44
e '..„,. 1 5.3 4,7
6
78
'
*%/s 59 ' 109 ' 150 ' 200
18 (2.588) Carbon disulf ide
I00i 7
XFS-
g'.i, 1 	
6

78
.'"
13 . . . , , . i .,,...,,..,,..,. j .... , ........
M/Z 50 100 150 200

552960

250 300 350

544768


250 300 350
FIN»
100


250 300 350
-------
07-08-97  7.1:53         Triangle Laboratories of BfP, Inc.
Sanple: WST-1 SET 1 IUBEA/B  I/fC  173HI&-1A/B  TLIft42284
                                                                  (919)  544-5729
                                                                    Instrument H
HS351 258  (2.58B)
1801 43
XFS
  0
      44
             76
        58
          &§
                                                                          21584
       58
                  ieo
158
208
258
           356
HS351J258 (2.581)  REFINE
    43
        58
  0
M/Z
       56
                  iee
158
288
250
                                                                           17152
300
356
NT2CAA 19  (2.578)  Acetone
180!
y.FS-
  8
M/3
      44
        5.8
                  100
                              150
            200
            250
                                                                           FIND
                                                                            100
            308
           358
-------
                     CJ
07-88-97  21:53          triangle Laboratories of BTP, Inc.
Sawle: UQST-1 SIf 1 TUBWB  T/TC  173-46-1A/B  TLlt42284
(919) 544-5729
  Instrument H
HS351 298 (2. 988)
100-
XFS -
8-
M/Z
4
47
9 1261568
8
55
4
88
, .L
58 1@8 158 288 258 380 358
HS3hi'2U8 (2.981) REFINE
100-
;
-------
97-88-97  21:53
                  Triangle Laboratories of RTF, Inc.
:  WST-1 SET 1 TUBEA/B  T/TC  173-46-1A/B  TLIB42284
(919) 544-5729
  Instriinent H
HS351 357 (3.578)
1pQ 57 368640


8
H/Z
41


56
i,5^


58 ofi.
LH. 8r
50 108 153 200 250 380 350
HS351'357 (3.571) REFINE
1001

XFS-
8
H/Z
5
41


56
55
.. 	 i
7 344064


58 86
58 103 153 200 250 300 350
HT2CAA 25 (3.57B) n-Hexane FIND
100

XFS-
8
H/Z
5
43



56
••-
55
. ....i
7 100


71 8|6
53 100 153 200 250 300 350
-------
87-68-97  21:53          Triangle Laboratories of RTP, hie.
Sanple: TOST-i SET 1  TUBEA/B  T/IC  173-46-1A/B  TLUW2284
(919) 544-5729
  Instrument H
HS351 466 (4.661)
108-
XFS-
e-
H/Z

39
1 f'5S
r
»!_.
5S
5 24064
79
ff3
ilJlil}.
183 158 200 250 3U0 350
HS351M66 (4,661) REFINE
ie.g
XFS
0-
6

47 53
.„ f. .,,1 1 ii, i..ji
7
7


50
5 19968

,1
2
lee 150 200 250 308 358
NT2CAA 29 (4.661) Chloroform FIND
iee

XFS
e
B/Z
8


,« - fiij' , i
3 100
85

87
50 180 150 200 250 300 350
-------
                                                                                     in
67-88-97  21:53         Triangle Laboratories of RIP, hie.
Sample: YGST-1 SET 1 TUBEA/B   T/TC   173-4&-1A/B  TL1842284
(919) 544-5729
  Instrument H
HS351 538 (5.381)
188
KFS
e
H/Z
5
56
c
56
7 39688

L 	 ? .^Al-.-jl* it.l, ,t , . it 	 ... „ „,,,,„
. t I n^il.,!!,., ,,. . ( . . . j[ , , , ,Wj, . , ,j (M| , . . . ( , » „„ , ,,,,„,„. j .... jl .... f . . . , , | r . -(
188 150 280 258 300 358
HS351'538 (5.3B1) REFINE
1B31
XFS-
0-
fl/Z
5
56
D3 J
7 27984

99 131
50 188 150 200 258 300 35C
HT2CAA 31 (5.291) Isooctane FIND
1001
•
XFS-
8-
M/Z
5
5&

4155
? 108


58
58 188 158 288 258 308 358
-------
                  to
07-88-97  21:53         Triangle Laboratories of BfP, Inc.
      :: WST-1  SET 1 TUBEA/B  T/TC  173-46-1A/B  fLIt42284
(919) 544-5729
  Instrument H
H8351 439 (4.391)
100
XFS-
0-
H/Z
4

|(
3
44
5
5B


5 „
100 150 200 250
4160


see 350
HS351'439 (4.391) REFINE
100
xFS
0-
M/Z
4

-41
3

c
58


i? ¥ 84
i 1 I
100 158 200 250
33 (4.388) 2-Butanone
186
XFS -
0-
M/Z
4


3

5
58


72
,7 f
103 150 200 250
3040


300 35O
FIND
100


300 350
-------
R7-0R-97  21:53         Triangle Laboratories of RTF, Inc.
Sample: VOST-1 SET 1 TUBEA/B  T/TC  173-46-1A/B  TL1*42284
(919) 544-5729
  Instrument H
HS3E
168-
XFS
8-
>1
4
,,il
H/Z
HS3E
100:
XFS
8
H/S
HT2C
XFS
0
47*
5
1
55
\
43
Ulii
6
(
1 .
(4.75:
8
*\ 78
L,.ll,. 11,1,1
50
il'47
52
38

• !
51
?5
6
,
3

;AA 34
6
I A?61*
M/Z
5!
J

L)
16320
4
97
ll 14.7
100 150 200 250 300 350
(4.7
7
A77
! J

51)
8
9

REFINE
4016
7
99
r H7
180 150 200 250 300 350
(4.751)
9
1
63
1. .8,8


1,1,1-Trichloroethane FIND
? 100
99
.•
100 150 200 250 300 350
-------
                                                                                       oo
                                                                                       «et»
R7-B8-97 21:53         Triangle Laboratories of RIP,  Inc.
Sanple:  UQST-1 SET 1 IUBEA/B  T/TC  173-46-1A/B  fLl»42284
(919) 544-5729
  Instrument H
HS351 493 (4.931)
100-i
XFS-
01
H/Z
41 56
12736
I 6,9 ill5 11?
ji.flj illi. iU 9* II.
50
HS3B1M93 (4
100
XFS
01
M/Z

47 52 7
l|(, 1
5B
NTZCflA 35 (4
IBB
*FS



4?
«/z 50
108 ISO 200 250 300 358
.931) REFINE
1.
0 98117
84 \
L9 1728
121
130 150 200 25O 300 353
.911) Carbon tetracliloride FIND
l:

t
? IBB
121
123
138 150 200 25O 300 350
-------
07 00-97  21:53         Triangle Laboratories of RIP, Inc.
Sample: UOSf-1 SEI 1 TUBEA/B  f/IC  173-46-1A/B  TL1*42284
(919) 544-5729
  Instrument H
HS351 514
100
%FS
5lf
g r.ii, 	 P..,..
H/Z 58
HS35if514
100
"" , T
o •"' 4
M/Z 58
NTZCAA 36
iee.
%FS
.- r
M/Z- 50
(5.141)
78
77
65 18.4
H-Lfi^^y I,,.!,. ... . _
130 150 200
(5,141) REFINE
78
77
74 "} 79
iee 150 200
(5 . 131 ) Benzene
78
77
6.3 .,/
108 15B 283

1327104

250 300 350

1261568

258 300 350
FIND
180


250 300 350
-------
                                                                                       CD
                                                                                       in
87-88-97  21:53         Triangle Laboratories of RIP, Inc.
Sawple: UOST-1 SET 1 TUBEA/B  T/TC  173-46-1A/B  TLIB42284
(919) 544-5729
  Instrument H
HS351 623 (6.231)
180-
y.FS-
M/Z
5
43
jii il
5 7936
67
68 g?
58 100 158 208 258 3B8 358
H8351*623 (6.231) REFINE
IBBn
XFS-
8-
M/S
5

45
. i
5 3984

67 73
50 lee 150 200 250 300 358
HT2CAA 39 (6.211) Ethyl aery late FIND
168-
KFS-

e-
H/S
5


f -
5 108

56
"', 7.3 p5 9,9
5f9 10O 158 288 258 388 358
-------
                                                                                    in
07-08-97  21:53         Triangle Laboratories of RIP, Inc.
Sample: UGS1-1 SET 1 TUBEA/B  T/TC  173-46-1A/B  ILI142284
(919) 544-B729
  Instrument H
HS351 649 (6.491)
iee-

0
H/Z
4

.J
1 123904
69
f 2 s*
70 100
It 5 IE
I.. . . .1.1 . 11.
• • i • • • • i • • • i • • • • i • • • • i • • • • i • • • • i • • • • i • • • • i • • • • i • • • • i • • • • i • • • • i
50 100 15Q 208 250 388 358
HS351J649 (6,491) BEFINE
1801
XFS
M/?~
4

J
1 110592
6
** *?
9
U *"i 1
.•' O ij 1 1
58 188 158 200 258 388 350
48 (6.491) Methyl nethacrylate F1HD
41 100

KFS -
0-


_a
69

42 59
ii ..!,.! .

79>? T
58 188 158 280 250 380 350
-------
                                                                                        ITS
87-88-97  21*.53         Triangle Laboratories of RIP, Inc.
Sample:  UOST-1 SET 1 IUBEA/B  I/IC  173-4&-1A/B  fLI«42284
(919) 544-5729
  Instrument H
HS351 768 (7.681)
160-

XFS-
i-
H/Z
9

39
i.^.li5,.,..^
1
92
93
SB me i5B
HS351'76B (7.601) REFINE
180-

XFS-
e-
«/z
9


f95! 65 89
Jp,,,.|, ,»lj „,., .,„}
1
92

93
59 100 150
N12CAA 4S (7.6B1) loluene
108i

X.FS-
e
M/Z
Q

?951 ^ ••
jr-,. r .TI -. r\
1
92
93
58 188 15B

528384


200 250 300 350

479232



200 250 300 350
FIND
100


200 250 300 350
-------










«3""s 	 flfj 	 art ~7 1 • m~~3
Fif tlo jr ^J. «t>j
Sample: WST-1
HS35I 984
189-

XFS "
0-
M/Z




CO
in
Triangle Laboratories of »TP, Inc. (919) 544-5729
SET 1 TUBEA/B T/TC 173-46-KV3 TLII42284 Instrunent H
(9.841)



U
82
54
15? ,

fr?7'
-' '"•'(*.•••(
5P
HS351i984
100-
XPS-
a



5


58
HTZCftA S2
1001

X;FS-
0
M/Z





51
e-
3
ftji


I.......... _,,-i
i.i ,.11
J00
7 114688

119

15B 2@e 250 308 350
(9.841)
8


.-.••. i




l:

93
4992
2
113
i
ISO

158 208 250 30B 350
(9.041) Chlorobenzene FIND

?

74

7

I
58
U



12 100


114

100

150 200 250 300 350












-------
                                                                                      in
87-88-9?  21:53          Triangle Laboratories of RIP, Inc.
Sarnie: MOSI-1 SEI 1 IUBEA/B  T/TC  173-46-1A/B  TLItt42284
(919) 544-5729
  Instrument H
HS351 1812 (18,121)
100
XFS-
8-
9
51 65 77
1
106
|107
i
58 180 158
HB351'iB12 (18,121) REFLHE
IB8-
XFS-
0
HI/Z
MT2(
100
v'.FS-
0
9

51 65 77
.., 	 ,4 •••ii', -,-.-
1
186
I
50 130 150
)fiA S3 (18,131
9
51 65 77
) Ethy Ibenzene
i
186
TIB?
50 100 150

122880

200 250 300 350

106496


200 250 300 350
FIND
100

200 250 300 350
-------
                                                                                      in
                                                                                      in
07-88-97  21:53          Triangle  Laboratories of IIP,  Inc.
Sample: MOST-1 SET 1 TUBEA/B   f/IC  173-46-1A/B  ILIM2284
(919) 544-5729
  Instriinent H
HS351 1836 (18.361)
1691
X.FS
H/Z
9
39
1 187392
?2 107
i 	 ilk 	
58 J8B 158 208 238 300 350
HS35I'1B36 (IB. 361) REFINE
1081
.
M^'Z
HT2(
100
%FS
,/r
9

32l
1 160768
186
;2 |i07
58 180 150 200 250 300 350
*lA 54 (IB. 371
9

/ ^ *>\ 77
) n-/p-Xylene FIND
1 108
186
>•]
53 188 158 280 250 300 350
-------
                                                                                     CO
                                                                                     10
87-08-97  21:53         Triangle laboratories of BTP, Inc.
Sample:  WSI-1  SET 1 TUBEA/B  I/TO  173-4&-1A/B  TLItt42284
(919) 544-5729
  Instrument H
HS351 11B6 (11.061)
lea-
X.FS -
e-
w/z
9
51 ?8
164 77824
1
106
i 	 I ....
58 180 150 280 258 388 350
HS351'1186 (11.861) REFINE
183
XFS-
e
s/z
9


1 54272
106
92
58 186 158 200 250 300 350
HI2CAH 55 (11.071) o-Xylene FIND
100
XFS-
8-
w/z
9
39 51
/ / 65 77
1 100
186
?2 107
< ,r
50 188 158 208 258 300 358
-------
                                                                                      r-
                                                                                      in
67-08-97  21:53
Triangle Laboratories of IIP, Inc.
Sanple: UQST-1 SEI 1 TUBEA/B   I/fC   173-4&-1A/B   fLI»42284
(919) 544-5729

  IiisLrwnent H
HS351 1111 (11.111)
1BB-
XFS-
0-
11
V
51
, <*^
...1,..., ,ji. ,.., rrf,,...n,,ifi
103
8 "•••
91
i.,.- 	 i. 	
34 327688
185
i. ..
58 169 158 268 258 380 358
HB351JH11 (11.111) HEF1HE
100:, *•}
X.FS
0-
H/Z
NT2C
IB8

Q-
7
51
. 6376\|
,.,|r f, , l.. . ,JT1. r,i|il
183
8
102
, .89 .
)4 206720
185
5@ 188 158 280 258 308 358
:AA 56 (11.121)
It
183
7 «7*7
8 162
Styrene FIND
14 180

185
58 188 15B 208 258 308 358
-------
                                                                                     00
                                                                                     in
87 00 97  21:53         Triangle Laboratories of RTF, Inc.
Sample: UQSf-i  SET i TUBEA/B  T/TC  173-46-1A/B  TLI842284
(919) 544-5729
  Instrument H
HS351 1185 (11. BSD
100
XFS-
8
H/Z

4
-4
1 5
j
u-iy
50
11
7
I (l 94-
i jj-llljl . lll|lii| UJ.J. i
35 16648

128
!,,! L 1*0
108 150 200 250 300 350
HS351J1185 (11.851) REFINE
100
0J

4
S3
56
NKCflft 58
1B9
XFS-
0-
H/Z


51
50
1(
69
15 13O56
120
.. . L i
100 158 288 258 300 358
(11.851) Cuiiene FIND
if

?? 183
(j ^jt I I i
i.| . .1,1 i
}5 180

IT
160 150 288 258 300 350
-------
                03
                ID
     /5J7    xl:53         Triangle Laboratories of 1TP.«  Inc.
Sanple: UOSf-1 SET  1  TUBEiVB  T/fC  173-46-Ift/B
(919) 544-5729
           :  H
HS3bI 164 (1. 641
ISIEti I3 5
: 33
>;* S - :
«: _J:

55


My'S 30
si



72

100 158
!!S351'i64 (1,641) REFINE
IBOl „<
yj''S-
9 •
3 5
55
, -;
»L F--852 ftOf!
iae ai?3 _
•JQ
XFS- J'.
9 i.
7

7,2
HVDROXVLAIIINEj O- C2-METHYLPROP¥L> -

MBS
2713744



. ., ..,..,....,....,....,....,
358
HBS 242 Hits : 242 Searched
2277376


i , , ,
C4H110N a55
55 7i
44||58 /J-
ita F:76f .1.620: PROPANE, 2-HETHVL-l-HITRO-
41
t *•?*?•; ! " «;
	 33 -1
XFS-i %.|*I2
1*3 F;748 1.429
J 3-3 T ''3
r,i"3 -i7 OQ
"*"T1 "V/ i
g i ..it. . j,
5
-J5

H/S 5B

i1
1
: PENT ANE, 2 , 4-DIMETHVL-

?
5d ag
;•'.., . r .„ .4..,.. .
., r p, 11 -i . | .......................
1GO 150 269

, | .,.,,.-.. , ..,..,.,....,
255
C4H902M

i i . i
255
C7H16


250 36S 359
-------
                                                                                  CD
W/88/37    21:53        Triangle  Laboratories of RTF,  I«c.
Sarnie: WST-1  SET  1  IUBEA/B   I/TC  173-46-1A/B  TLIi42284
(919) 544-5729
 Instrument '•  H
869
f Qf|-j
i
al
--* ' " ' " i
H/Z
HS351'869
I BC3 i
; 	 • * i ' • 	 • • i • ' ' ' i < • • • i • • • • i • • ' • i • • • • i • • ' ' i • ' ' ' i
150 200 258 300 350
NBS 24 Hits : 24 Searched
267 417792
11
9,6 119 133 163 i^1?1 I! 218
45 fii 75 m [ , ;•; t 1^7 \ if 1, Ik
' '' • ' *•' • • >' ! "• '* • • 'i r
22491 :CVCLOf SIS


~V

ILOXANE, HEXftMETHVL-
-m #3«» *j «t cr
2?7 C6H1003Si3 2j5

H9l^3 l??!?!
208
£
22628 : 1 , 2-B!SCTRIMEfH¥LSILVL)BEN3EME

=^ 73
43 73 I?4 88
M .59. kir...!?

38155 :ARSENOUS


44 7,3 10
50 100
191 2CT? 25^

131
514-3 \t If 5 1611?5 1,
sea C12H22Si2
i
L 2^_2
• ,-«! | A'V . »•', . !T«T .[• i . i" i '(....,.. . . | ....,....,.,.. , ... i ,
flCI», TRIS(TRIHETH¥LSILVL> ESTER
207 255

5 1?3 . 191
2m C9H2703Si3As
jV-209
• • • I • ' • • 1 • • • • 1 	 " ' I • "•••• • 1 ' ' ' • 1 • • • • 1 ' ' • • I ' 	 ' 	 I1"'' " • ""' 	 T
150 200 250 368 350
-------
                     C£>
08-Ju 1-97 21:53         Triangle Laboratories of RTP,  Inc.
Simple:  UOST-1 SET  1  IUBEA/B   T/TC  173-46-1A/B  TLHH2284
(919)  544-5729
  Instrument H
KEIE
IFS;-
BB3iS
1HCI
sF5:-
ti
#1
JCiii
sf'S;-
61-
#2
JBil-
61
#3
1061-
»FS:-
,61-
,1. 7'2 (8.728)
60 2670592
44
1>Q 100 150 200 250 300 350
,i'72 (8.721) REFINE
6
"V3
, , 1 1 1 1 1 1 1 . .
F:645 2898:PENTftNOIC flCID, 3-
6
4142 43 55s 56
' F : 520 75i:BUTANblC ACID
6
p-27 __ 39^2
F:473 1543:PENTANOIC flCID
6
2627 ? 9 i\ 45 5'
\ ii^.j, ,?i*f?i, 	 ,,?^!,,
NBS 178 Hits : 178 Searched
0 2768896
63 ,
-METHVL-
0 255
61
f, , ,,, M8.7' -I
0 255
61 73
I"° 1 ji.--1..-.j.*l,|,...|....|-...^yj,.|,--.i-w»iij|
0 255
61 7374
iO 30 48 ' 50 ' 60 ' 70 ' 80 ' 90 100 ' 110 120
-------
                                                                                         CO
08-Jul~97 21:53         Triangle Laboratories of RIP,  Inc.
Sample:  UQST-1 SET 1 TUBEA/B  I/TC  173-46-1A/B  TLIft42284
(919) 544-5729
  Instrument  H
HS3E
100
XFS
0-
il 103 (1.030)
41 376832
1 ¥
,ii i. ..,,,.ii.i.
M/Z 58 180 ' 158 ' 280 ' 250 ' 380 ' 350
HS35
100-
XFS
0.
#1
108-
XFS
0-
il'103 (1.031) REFINE
41
37 39
,\ |
FI725 552:1-PEN1ENE, 4
4
2|7/28 3,4f
412 F:710 809:HVDROXYLflMIN
1001 41
XFSJ 39
01 - 1
#3
100-
XFS
0-
F:685 1642:HVDROXVLANI
4
41
NBS 58 Hits : 58 Searched
364544
56 58
, , ,?A 1 Ln
1,1. .i|ii . , 1 1 1 ii,... . , . . . . , . . . ...... , . . . . ,,..., . , . . ^ ... . j ...... ...
-METHyL-
3 255
AA 55
/ sail . 6,9 	 8,4
i | ... t | i riT | 1 i i ., i i i i | i i i 1 | i ., i | . i i i | i i i 1 | i - . ,...,,....,,...,.,..
E, 0-<2-HEfH¥LPROP¥L)-
r43 255
44 55X5|6 58 70 J1
ffft p^jl f,, ,'Vr?2,
NE, 0-<3-MEIHYLBUTYD-
3 255
44 55N 56 78 .J1
5.3l/r58 N|.
H/Z 28 30 40 50 60 78 88 90 100
-------
                                                                                  00
                                                                                  CO
            21:53        Ipiangle Laboratories of IIP, Inc
Sanple: MOSI-i SET 1 IUBEA/B  T/IC  173-46-tA/B  THIf42284
(919) G44 5729
 Instrument: II
Xi1 S~ 37 ,pl 6-
n '• -'11]llk..ii, ..
M/Z 50
HS351fZ21 (2.211
39 53
XFS- 37 15\ 6
Si F:9*ML 132=1
man 5:
XFS: 26 27y- g
ai Ml Jji r/
1
67
^-. 81
iee 158
I REFINE
fc?
5 J69
• ! LX
,3-BUIADI£N£. 2-METHi'L-
k ^O 1
4 J69
...ill;
«2 F:396 174:i.3-PEKTA»IENE, <3>-
1931 3.9 536|?
XFS- 26 Pr" J54869
S-3 F:394 l?H;l
!.Xj 2,7 39 53
-'•" »1 E6 i
Pl Si. ,|i ...
H/Z 50
,4-PENTftBIENE
?^.-68
eg
1@0 158
HB3
112640
280 350 308 35S
NBS 33 Hits : 33 Searched
106496
C5H8 255
255
C5H8
255
C5H8
298 253 380 353
-------
88-Jul-97 21:53         Triangle Laboratories of RTP, Inc.
Sample: MOSf-1 SET 1 TUBEA/B  T/TC  173-46-1A/B  TLI842284
(919) 544-5729
  Instrument H
HS351 87 (8
1001 43
XFSJ 44
M/Z 50
HS351J87 (8
100:
XFS-
0
ttl F:82O
1001
XFS-j
0 * i- 1- 1
f»2 F:726
100:
XFS:
0
#3 F:674
100:
XFS-
0 4-3
M/Z 28
.870)
'
.871)

100
REFINE
43
41 |
38 \\
Nl III

150 200 250
HBS 144
57
97:P10PftNl, 2-METHVL-
43
42
oo 29 39 \ 44
i / * 1 1 1 / 57
1298:
??
ftCEfIC ftCID,
43
39N 44
2-PROPENXL ESTER
57% 58
4489 ; 2 , 4-OXAZOLI DI NED I ONE, 5 , 5-DI HETHVL-
43
nr, 29 3 7 39 44 58 59
2.7/, \fiTii /r45 	 M. 7.0
• • ' • i
40
60 88 100
307200
300 350
Hits : 144 Searched
299008
1 " • I 1 • " I
255
255
255
129
120 140
-------
                  in
                  CO
08-Jul-97 21:53         Triangle Laboratories of RfP> Inc.
Sample: UQSI-i SET 1 TUBEA/B  T/TC  173-46-1A/B  TL1*42284
(919)  544-5729
  Instrument H
HS35
188
'XFS-
0. „
M/Z
1 196 (1.960)
43 201728
1 	 r? „,..,,
50 100 150 200 250 300 358
HS351J196 (1.961
108T 4i 4
XFS| 39 \
el All
188'
XFS
«2
1001
XFsJ
0i-
#3
108
XFS
8 -
M/Z
F:743 809:1
4114
3* 1
),ll
F:721 1298:
4
39s
F:716 6531!
4
41
, V| i
) REFINE NBS 83 Hits : 83 Searched
3 189440
44 5?
IVDROXYLAMINE, O-C2-MITH«LPROP¥L>-
3 =5" "'
44 53 758 70 J1
^r46,A, I ^ 1)1 r?|
ACETIC ACID, 2-PROPENVL ESTER
3 255
44 57 58
1 1 • • i • | n 1 1 • < II , , rt,»i | , ., , , | , 1 1 1 j 1 1 1 , ! 1 1 , , | , , , , , , , , , | , , , , , , , , , , ,., , , | , , , , ( ,, , , , , | , , , , | , , , , | , , , , , ,.,,., | , , , , j ,.,
HEPTANE, 4-flZI»0-
3 255
44 555,6r57 70
/ Nil T 84 9.8
.,....,....,. i«»i i .,..,,,.,..,,...,....,,...,,...,,., .,....,,.,,,...,,,..,,,,,,,..,,,.,,.,,.,,,,.,,,, .,,,,,, . i , ... , ..T..^^,.TT-^,
30 40 50 60 78 88 90 180 110 128 130 140
-------
                  C£>
                  CP
67/68/97     21:53        Triangle Laboratories of IIP, Inc.
Sample: MOST-1 SET 1 TUBEA/B  T/TC  173-46-1A/B  TLIM2284
(919) 544-5729
 Instrument'.  H
412 (4.120)
lea-, al 5
XFS-
„
".
i J
6
69

M/Z 56 180
(4.121)
n 56
_ -
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8-
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69


ttl F:855 4261;2H-P¥RAN-2-ONE,
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0-
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57 f?
i i
,...,... i | ,,,,..,, , ,...,.
m F;842 4288;2H-P«RAM-2-ONE,
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XFS-
0
42
3V3
.III, ...

?67 8A
.-..,,-. . I I .,..,...,,..,.,.
f3 F:819 559:CVCLOHEXANE
in-a7 56
_-Jrf
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s
41
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«i* . „ i.i-, 	 ,
84
57 / |85
	 L83.:u'
M/Z ' ge ' lee
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56328


158 250 306 358
NBS 66 Hits : 66 Searched




.•. i ....,.,..,....,..,....,., ,• i ....,....,
lEf RftHV»RO-3, 6-DIMETHVL-
C7H1202 255



TETRflHVI>KO-5,6-l>IMETHyL-, fRftNS-
255
C7H1202



255
C6H12


158 288 258 368 358
-------
                                                                                      CD
68-Ju1-97 21:53
Sample: UOST-1 SET 1
   Triangle Laboratories of RTPj Inc.
fUBEA/B  T/TC  173-46-1A/B  TLI»422B4
(919) 544-5729
  Instrunent H
HS3E
100-
XFS
li 348 (3.488)
TT
iJjjjff
0.
' ' • ' 1 • ' ' • 1 ' ' '
M/Z 50
HS351'348 (3.481)
1001 39 4
X.Fsl 38 N
0] . N i
ttl
100-
7.FS •
0.
100:
XFS
0.
100
XFS-
0
86016
100 • L,LQ • • ' • gee • 2^0 • 3^0 • 3g0
REFINE
5
: 53^
'F:77l' 555:2-PENfENE, 3
T
2^,7f?9 3", 1%, 505i25
F:764 4261:2
4
39
37 s
H-PVRftN-2-
J43 5
r si j
F:762 542:2-HEXENE
41 42 5
NBS 25 Hits : 25 Searched
5 33024
6? 69 84
\
-METHVL-, CE>-
69 255
556 67 70 84
", i i M i ( , r85
ONI, TETRftHyDRO-3,6-DIMEfH¥L-
5 255
" 6\¥ 8,4
5 255
56 04
( 67v69 70 85
1 ... . . A . - . f -3 	 rW3
M/Z20 ' 30 ' 40 ' 50 ' 60 ' ?i0 ' 80 99 '"' 100 ' 110 ' 120 ' 130
-------
tjgfg^<-...::^^j^+-»«^

I^S^^KlSlS^^^Si^SIS^f
Project Number: 42284 Method 8240A VOST
Sample File: HS352 Sample ID: VOST-1 SET 2 TUBEA/B T/TC
XX
'.X X x.x X: ':'•":•• X X x'xi-.- 'x::' "x-x'x':-:'x.:.:'x':--".:-:X> XX
i^i^iiiEiii^^^ii^^^^^i^ft l^iP^li
::-.;;;.x:::x-:-:;isx:sx:-^x-sx;:x4x-x' --..x. :••• ^-i-xr-:" *£*••••• •••if'--,-,f:'::-'
SISilll^i^^iP^^^tliPiKH^F:


Sxv"x;:P?;»xxiK: -:-x-:-£xx:& •*'• ''••'&
§as^|^?s||;;;;}:|l:|||:;W:_ :||
l||lIP|S?:;:||5xS||fl?;:;l| 1|
Bromochloromethane
Chloromethane
Vinyl Chloride
1,3- Butadiene
Bromomethane
Chloroedtane
Vinyl bromide
Trichlorofluoromethane
1 , 1 -Dichloroethene
lodomethane
Carbon disulfide
Acetone
Allyl chloride
Methylene chloride
trans- 1 ,2-Dichloroethene
ten- Butyl methyl ether
Acrylonitrile
n-Hexane
1 ,1-Dichloroethane
1 ,2-Epoxybucane
cis-1 ,2-Dichloroethene
Chloroform
1 ,2-Dichloroethane
Isooctane
1 ,4-Difluorobcnzene
Vinyl acetate
s3^||||^|^fe;S:l;l^^iwl8K:!S^S^^p^ft^Siife?:8.?
bxx-xX-lsxXiffiixKxSj^xJjItexixXyAe
;x:>x; •«: xjfftjxsii;:; s ;:;.>; '*&\ s •:•. i^xK ;i;- xx*?*:.;-;;-:;:;;;?*;; -;: t" *s;; : ;;;*;-;*s K;;;;;*?;;; "' ;:; :x;;;;-;-:S':::»:-:*;;
IS 1 4.51
0.114 0.93
U
0.091 1.09
0.018 } 1.43
U
U
1.026 E 1.84
U
U
0.253 2.50
0.094 B 2.57
U
1.220 BE 2.97
U
U
U
0.209 3.57
U
U
u
0.006 ] 4.66
U
0,011 } 5-30
IS 2 5.66
U

i^S^^^pi^^|fS^g^^?|lif

0.05
0.001 0.05
0.05
0.05
0.001 0.05
0.001 0.05
0.05
0.001 0.05
0.001 0.05
0.05
0.05
0.001 0.05
0.05
0.001 0.05
0.001 0.05
0.003 0.05
0.05
0.001 0.05
0.003 0.05
0.001 0.05
0.05
0.001 0.05
0.05

0.001 0.05
NA- Not Applicable; Det Limit Detection Limit; Quan, Limit: Quantitation Limit
IS; Internal Standard; U:
Undetected; B: Present In Blank; }: Estimated- Below Quantitation
Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, fac
801 Capitola Drive • Durham, North Carolina 27713
Phone (919) 544-5729 • Fax- (919) 544-5491
              Savar v3.5
Printed: 15:01 07/22/1997
              C Q
-------
If ;';::; i-v'1! jtii; ?*:;r:S: Wkii k i;Msi;Jii;?M'?i:8*Yf
'•''.''.' '.';'•''., '•' .""" !.' "!:". 'I'!'!!!!] ':''•" !"."!'! ". Y?! !'!:': YYX!: •!"""!'/: • ". , ', '. .' .''. '..'."'."'"I'
Project Number. 42284
Sample File: HS352
ppt|gp;i|^||||'
\tM^J^^I^:^&f2iS^^K'.Affi-W&!-J;

Pacific HnvikxHURCiital Servicfis


Sample
iiiiiimH^'i^H^li
xi^c;^;^y»-K^«:^Mf5xi;^'xJ^S! •¥SiSSiiSil:;ii8i*^:»i



Method
|lll»^vr

8240A VOST
ID: VOST-1 SET 2 TUBEA/B T/TC
|jj|ijlii||i|j|
S:5:S gt^ ? i S>. !S« »?SS x«x " i m^ K. 1


«® Si*!®! x 3 -:i IS i x" i : i'£.
|illl|||;i||if.s'


ki*lytfc •' -" " ...:.'-
. . . **" " *\^. .
2-Bucanone
1 , 1 , 1-Trichloroe thane
Carbon tetrachloridc
Benzene
Trichloroethene
1 ,2-Dichloropropane
Ethyl acrylate
Methyl methacrylate
Bromodichloromethane
cis-1 ,3-Dichloropropene
trans- 1,3-Dichloropropene
1 ,1 ,2-Trkhloroe thane
Dibromochloromcthanc
Ethylene dibromide
Bromoform
Chlorobenzene-d
5
4-Mcthyl-2-pentanonc
Toluene
Tetrachlorocthcnc
2-Hexanone
Chlorobcnzcne
Echylbenzcne
m-/p-Xylenc
o-Xylene
Styrcnc
1 ,1 ,2,2-Tetrachloroethanc
»- -AtoWib*"^ RAlCr.:- ' XT "
ag . ::/:"^'"" • ' 7:; •
0.008 J 4.39
0.006 J 4.75
U
0.741 B 5.13
U
U
U
0.103 6.49
U
U
U
U
U
U
U
IS 3 9-79

U
0.263 B 7.60
U
U
0.003 ] 9.84
0.050 10.13
0.092 ] 10.36
0.035 J 11.06
0.250 11.12
U
•;•': ; EXstfcuBit-, •.' ~;
,"~"" ^«STT:'' X:'* '


0.001

0.001
0.001
0.001

0.001
0.001
0.001
0.001
0.001
0.001
0.001


0.001

0.001
0.001





0.00 1
Qttan. limit
•;Bg ' '/':
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05


0.05
0.05
0.05
0.05
0.05
0.05
0.10
0.05
0.05
0.05
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit: Quantitation Limit
IS; Internal Standard- V: Undetected; B:
Present In Blank; ]-. Estimated- Below Quantitation
Limit; E: Estimated- Above Calibration Range
Triangl* Laboratories of RTP, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
             Savar v3.5
Printed-15:01 07/22/1997
                                                                                                                      69
-------
Project Number: 42284                                                              Method 8240A VOST
Sample File: HS352                                          Sample ID: VOST-1 SET 2 TUBEA/B T/TC


Anaiyte
^v^x:;: :-:-:*;vX;:v>/.
Cumene                                       0.006  J             11.85                                     0.05
1,2-Dichlorocthane-d^                            0.260                 5.11                  1                   104
Benzenc-d.                                     0.280                 5.09                  2                  112
Toluene-da                                     0.285                 7.51                  3                  114
Reviewed by	""TUj        Date""? l
                          NA- Not Applicable; DeL Limit: Detection Limit; Quan. Limit; QuantilaHon Limit
     IS; Internal Standaid; U; Undetected; B; Present In Blank;); Estimated- Below Quantitation Limit; EJ Estimated- Above Calibration Range

Triangle Laboratories of RTF, Inc.                                                                                Savarv3.5
801 Capitola Drive * Durham, North Carolina 27713                                                       Printed: 15:01 07/22/1997
Phone: (919) 544-S729 « Fax: (919) 544-5491                                                                           •* n
-------
                                   Pacific* EiwironmenteTServices
Project Number:  42284                       Method 8240A
Sample File:      HS352                      Sample ID:          VOST-1 SET 2 TUBEA/BT/TC
Client Project
TUID:

S407-003
173-46-2A,B


Dilution Factor:
Date Received:
Date Analyzed:
1.00
06/30/97
07/08/97

                              Tentatively Identified Compounds
  	Name	RT         Area      tSHT     tS Area     Amount uo

   Methylbutane Isomer                 1.630      111214760      4511     4803281           5.788
   Unknown                          072      35399944      4511     4803281           1.842
   C4H8rsomer                       1.03       9247143      4.511     4803281           0.481
   C5H8rsomer                       2.200       5723370      4511     4803281           0298
   HexamethylcydotrisUoxane           8.691      10030476      9.791     11242038           0.223
   Pentane                           1.95       3878523      4511     4803281           0.202
   Methyl Propane Isomer               0.87       3551444      4.511     4803281           0.185
   C6H12 Isomer                      347       2584441      4.511     4803281           0.135
   Cydohexane                       4.781       2087478      4511     4803281           0.109
   Tetrahydrodimethyl Pyranone Isomer   4.120       1957605      4.511     4803281           0.102
Triangle Laboratories, Inc.
801 Capitola Drive* Durham, North Carolina 27713                           Printed:   10:26  07/25/97
Phone: (919) 544-5729 * Fax: (919) 544-5491
                                                                                          71
-------
                                                                                      CM
87-88-97  22:19          Triangle Laboratories of RTP, Inc.
Sanple: UOST-i SET 2 TUBEA/B  T/TC  173-4&-2A/B  ILIU42284
            (919)  544-5729
              Instrument H
                                                                         3995156
                                                                             TIC
                                                                              ttl
                                                                          15  66
                                            10.8
12.8
14. B
16.0
                                                                                      i
                                                                                     r
                            O 0
                            -5-6
                            Q O
-------
JUAN 'OB :  HS352

 Mo. MAT  FOR  REV Delta
LAB-BflSE  QJAN
Area P.Flags
                                 07-08-97
                      QM Name
1
2.
3
4
5
6
~t
8
9

i i
12
14
15
16
17
18
19
20
21
22
XH, —r
•*" '"^
** A

25
26
28
29
30
31
33
34
35
36
37
-rf-s
wiJV
jS<^ f\
•~J X
40
41
42
43
44
45
46
47
A f
49
50
1OO
1OO
1OO
54
1OO
100
f\ f
100
100


95
X. V ""
O
100
0
0
100
89
O
1OO
O
f y.
O X
^ -T
A> /
10O
o
o
45
O
89
84
4O
0
100
o
'-> 1



100
o
o
0
0
o
0
0
54
100
o
92
93
96
21
86
90
1 n
88
86


6O
0
92
0
0
77
64
O
92
0
f A
^J'Q
/*!

98
0
0
11
0
56
67
15
0
92
0
1 /

*•%•—«•
*- f
93
0
O
O
0
o
o
o
e:
94
O
99
97
98
67
88
99
... -•?,
94
92
f, <—

95
0
99
0
0
99
80
0
99
0
r~ s
— '*-*
T ^
v^O
1OO
0
0
61
0
88
70
49
0
99
0
A 1

* s\

98
0
O
0
0
0
0
0
<™>c
99
0
0
o
-1
1
0
1
i -V
1
0
-,. _p

1
0
0
0
0
0
0
0
0
0
1

1

0
o
jf
0
o
0
1
1
0
o
o
0
f+> s
*~\~*
—f
*•-*
o
0
0
0
o
0
0
0
f*>
1
o
588280
2404288
3064640
1087S56
3114 1O4
3969236
" r 1 ' ° ""
1955371
373280
, *, ^ f ^ , ^s

611O4
O
4580724
0
0
2482784
191473
O
3733436
0
•*y S\ ~y /
S_)U t S^
•i 1 -?rt^

1516642
O
o
34704
O
274962
3012
32056
O
9O29139
O
^.^^
«w»».J 4..
e"T S~\

238688
0
0
o
0
0
0
0
Q"7Oc"*O
2385944
O
bb
bb
bv
bv
bv
bv
.*
vv
vv
fcb
A 3T070I
bb

bb


bv
vv

bv

^y

X. i j
*J •/
VV


bv

bv
A
bb

bv

u u

Si

bb







/%.
bv

4
C
•w'
9
5
5
7
1*^
12
0
^S

1
0
1
O
0
2
2
O
2
O
~y.
•W
T
vx
3
O
O
4
O
5
4
4
O
5
O
r-
~j
f
"vJ
6
0
O
0
0
0
0
0

7
0
,51
.66
.79
.11
. 09
.51
_. ~
.07
.93
-r-r
^o l.
.43
^
.00
.84
.00
.OO
.50
.57
.00
.97
.OO
"7O
m O^.
^^ ^

.57
.OO
.OO
.66
.OO
.30
f-T
" J3 >
.39
.75
.OO
.13
.00
f~>f*L

/-> r*
~ * 	 1
.49
.OO
.OO
.OO
,OO
.00
.OO
.00
C.1
.60
.OO
128
114
117
65
34
98
Op
95
50
ssy
0<1 -*Q
94
X A
OM
106
101
96
142
76
43
76
84
96
73
53
57
63
/lO
*-4x
96
83
62
57
/i T
HO
72
97
117
78
130
63


69
83
75
75
97
129
107
173
A~H
*•*<}
92
164
8 romoc hi. ore-methane
1 ,4-Dlf 1 yore-benzene
Chlorobenzane~d5
1, 2-Dichloroethane-o'4
Benzene-d6
Toluene-d8 x^viD
,,-1 ^1O fvm s\^
4-Bromcf 1 uorobenzene
Chloromethane s~\s3b
\t * 1 f 1 1 * f~\ n$ 7\^*
y ^&iij i 1^1
Bromomethane ~~x
Vinyl bromide
Trichlorofl uororne thane
l,l-Oichloroethene
lodomethane
Carbon disulfide
Acetone
Allyl chloride
Methylene chloride




















trans-l,2~Dich!oroethene
tart-Butyl methyl e^te,
Acrylonitrile /*&
n-Hexane
1,1-Oichloroethane — \
cis-1, 2--Oichloroethene
Chloroform
1,2-Oichloroe thane
Isooctane x~v^"7)
2-Butanone ^^^
1.1,1-Trichloroethane
Carbon tetrachlorlde
Benzene
Trichloroethene 	
1,2-Dichloropropa^vnP
Ethyl acrylate )\L/t
Methyl methacrylate
Bromodi chloromethane
f^U
















cis-l,3-Dichloropropene
trans-1 ,3-Dichloropropen
1 , 1 ,2-Tr ichloroethane
Oibromochlorome thane
Ethylene dibromide
Bromoform _e
/^™«Mca1"K /1w'?".Kscin-f-^ar^r\K(^ &Q
Toluene
Tetrachloroethene



'xn
W-
/*

                           Data Review:
                           Date: -_
                                                                          73
-------
No.  MAT FOR REV  Delta
Area P,Flags
RT
QM Name

_i _L
52
53
54
55
56
, 	 r
—7 f
58

\^f .-
47
100
100
98
1OO


75

J_ /
14
89
87
77
95


44


63
99
94
83
98


79

^^
1
1
O
o
1
^ Pi
*- ^
1

v^--l-4i.JL
36592
3155O4
722900
263740
3O92388


144508


bb
bv
vv
bv
bv
,v

bv
j~}
•,_i
9
10
10
11
11


11
.73
.84
.13
.36
.06
.12
^. ~y
- —• *-
.85
43
112
1O6
1O6
106
104
83
105
2-Hexanone (^^TLO
Chlorobenzene
Ethy Ibenzene
m— ,/p— Xy 1 ene
o-Xy lena
Sty rene
1,1,2,2-Tetrachloroei
Cumene
                                                                       74
-------
B?-flB~97  22:19         Triangle Laboratories of RfP, Inc.
Sample: VQST-I SET 2 TUB1A/B  T/TC  173-46-2A/B  ILW42284
                                                                  <919) 544-5729
                                                                    Instrument H
1B01
XFS -
      93 (8.930)
        52
      ilJ
      50
                  168
150
200
250
                                                                           73728
388
350
HS352J93  C0.931)  REFINE
       «m
1601
  0
M/Z
                                                                           66560
                  108
150
200
258
300
350
NIZCrlA 9 (0.938)  Chloronetliane
        52
  8
M/Z
                  133
                              158
            280
            258
                                                                            FIND
                                                                             100
            3B0
           350
-------
                CD
Jul-97 22:19         Triangle Laboratories of RTF, Inc.
   >: UOST-1 SET 2 TUBEA/B  T/TC  173-46-2A/B  ILI1H2284
(919) 544-5729
  Instrument H
HS352 109 (1.090)
100-
X.FS-
e-
M/Z
3
jj
9 71680
54
50
,11 j
57
1
Rr fjt f I3fjl 1 "££31 OOljl O "-k fji OCIQ O^f«l
•J KJ Ju viCp iiJ Kl £ MPKP c« w V£P OKIKI w%J tuP
HS352'109 (1.091) REFINE
100
XFS
0-
M/Z
53
\
•
50
1


50 ' i00 •••••-- ^^^ . 200 . 2g0 . 300 • 3g£
T2CAA 11 (1.080) 1,3-Butadiene FIND
100-
7.FS
0-
w/z


4
5
53
\
50
\
, ,1
4 100


50 100 150 200 250 300 350
-------
B7-88-97  22:19
                        triangle Laboratories of RfP, Inc.
Sample: WST-1 SET 2 IUBEA/B  T/TC  173-46-ZA/B  TLIf42284
(9193 544-5729
  Instrument H
143 (1.438)
180-

y,FS-
e-
M/Z
44 17488
94

93

.
50 100 150 2OO 250 300 350
HS352'143 (1.431) REFINE
109
XFS-
0
M/Z
9
93
Ti1 J
1 10496


5i 100 158 200 250 308 350
HTP.CAfl 12 (1.47.B) Browowethane FIND
160-
XFS -
0-
9-
93
46 fll ^.
49/ I1 J
4 100

.
58 100 150 20O 250 300 358
-------
                    GO
                    r-
M7-08-97  22:19         Triangle Laboratories of RTF, Inc.
Sample: UOSI-1  SET 2 fUBEA/B  T/TC  173-46-2A/B  TLIH42284
(919) 544-5729
  Instrument H
184
188-
0-
H/*Z

47
50
HS352T184
100-
0-
m/z

47
5B
NTZCAA 15
180:
KFS -
e-
H/Z


35
58
(1.840)
1«
I, 82
11
103
105
i
188 158 280 250
(1.841) REFINE
u
.*f. , ag
>1
103
185
£
10O 150 280 250
( 1 . 840 ) Tr icii lorof luoronethane
11

66
1 , 8,2
n
103

105
r 11.7
iee 150 200 250

606208

300 350

561152

300 350
FIND
180


300 350
-------
e7-R8-97  22113         Triangle Laboratories of RIP, Inn.
Sample: UOST-1 SET 2 TUDEA/B  T/TC  173-46-2A/B  fLI«42284
(919) 544-5729
  Instrument H
HS352 258 (2.SBB)
i«-
e-
Mf/S
7
44
€ 466944
78 .„.
1
-------



o
00
87-08-97 22:19 Triangle Laboratories of RTF, Inc. (919) 544-5729
Sample: UOST-1 SET 2 TUBEA/B T/TC 173-46-2A/B TLIB42284 Instalment H
257
180-

%FS
0-
f*/Z
4


Jli
3
44
(2.578)

7
j 58
.1.1
58
HS352'257
108-
eJ
w/z
4

3
5
58
NTZCAA 19
iee-
XFS-
e-
H/Z
4


3

44 5
58
..in
'

6
101
20736

f QO m *r m
85 I /"" A?x
.. .|, 11,11 . II.
100
150 200 250 300 350
(2.571) REFINE

a
1

,"?
• - - • i -
15808
8
150 200 250 300 338
(2.570) Acetone FIND


8




100
100


150 200 250 300 350










-------
                  00
87-08-97  22:19         triangle Laboratories of WfP, Inc.
     e: UOST-1 SIT 2 TUBEA/B  T/TC  173-46^2A/B  TLIt42Z84
(919) 544-5729
  Instrument H
HS352 297 (2.978)
189-

HFS
0
M/Z
4


^
9 1081344
84
51
55
../ .39 .

88
5e 100 isw 200 250 see 350
HS352'297 (2.971) REFINE
169-

KFS -
e
M/Z
4

•17
,t4L,Jl
5
9 1848576
84
51
83
J88
8 ' 108 ' 150 ' 208 ' 258 ' 308 ' 358
21 (2.978) Hethylene chloride FIND
1801

X.FS '
0
K/Z
4


47
y 100
84
51
83

88
,i
50 163 158 208 250 300 358
-------
                                                                                     oo
87-88-97  22:19
                        Triangle Laboratories of RTF* Inc.
Sample: UOST-1 SET 2 TUBEA/B  T/TC  173-46-2A/B  TLIM2284
(919) 544-5729
  Instalment H
HS352 357 (3.578)
100

XFS-
0
H/Z
5
41


J
56
X.
55
„ .....I
7 198656


58?1 8S
58 188 158 280 250 388 358
HS352'357 (3.571) REFINE
1881

XFS-
e
H/Z
5
43


56
\
55
7 183296


t*?l B\*
58 168 158 288 258 380 358
HT2CAA 25 (3.57i) n-Hexane FIND
186-
•
XFS-
0-
H/Z
5
43



56

55
. . .i
7 188


71 8i6
58 180 158 288 258 388 353
-------
                                                                                       00
87809?  22:19          fpiangle  Laboratories of RTF,  Inc.
Sample: WSf-1 SET 2 TUBEA/B   f/TC  173-4&-2A/B  TL!t42284
(919) 544-5729
  Iiistrunent H
HS352 466 (4.661)
100-
XFS-
9-
M/Z
6
39
5,3
..1 ! i,I !.,)!< L .,(.
7 21504
79ft^
„,. J,
r
se ley 150 200 259 330 353
(4.661)
188-
\
XFS-
0
H/Z
b
?9 53
I 47 /
58
7 16964
71
, 	 Jl
83
100 150 200 250 300 350
NfZCAA 29 (4.661) Chloroform FIND
1001
•
XFS:
.
e
H/Z
8


4750
- - !'f"
3 100
85

87
,"
. J
58 103 150 200 250 300 350
-------
                                                                                      00
87-88^9?  22:19         Triangle Laboratories of RIP, Inc.
Sample: VOSf-1  SET 2 TUBEA/B  T/TC  173-46-2A/B  TLI842284
(919) 544-5729
  Instrument H
530 (5.381)
168-

•/.**-
0-
5
56
4155/
l 1
JiillAi
7 24064

58 ?884
1, .ll .«„!, 9,9

H/Z 59 100 158 200 250 308 350
HS352J538 (5.301) REFINE
100
•/,FS
8
5
^56
1 1 ,
7 15296

?p
" * ji...j....j.-,.|.-..j,.,.|....|.-..|.-..j.-..j...-(.-.-|.-..,
H/Z 58 1O0 158 288 250 300 350
NT2CAA 31 (5.291) Isooctane FIND
108i

XFS

0-
5
56

4155
,1,1 ^
7 100


58
i" . , ^?
»/z 58 ' 108 ' 150 ' 200 ' 250 ' 300 ' 350
-------


88-Jul-97 22:19
in
00
Triangle Laboratories of RTF, Inc. (919) 544-5729
Sample: UQSf-1 SIf 2 fUBEA/B T/IC 173-46-2A/B TLW42284 Instrument H
HS352 438 (4.380)
100-
XFS-
0
M/Z
4

J
3
44
i 55 7,2 8
III 1
i i . I ......
50
3392

4
100 150 200 250 300 350
HS352J438 (4.381) REFINE
100
XFS
0
tt/Z
4

-J
3

55 7,2 8
|l 1
50
2864

4
100 ' 150 ' 200 ' 250 ' 300 ' 350
T2CAA 33 (4.641) 2-Butanone FIND
100
XFS
0-
M/Z
4

MlJU
3

72
57 f
i .. , .,!. Ji
50
100


100 150 300 250 300 350










-------
                   00
87-88-97  22:19         Triangle Laboratories of RfP, Inc.
Sample:  UOST-1 SET 2 TUBEA/B  f/IC  173-46-2A/B  TLIM2284
(919) 544-5729
  I instrument H
HB3E
IBB
XFS-
0
M/Z
HS3E
188:
X.FS
e
M/S
HI2C
168-
XFS-
01
$2
4
47!
5
1
55
6
(4.75
8
78
58
52' 4'
53
37
5
:AA :
35
H/Z
?[
— r
9
i (4.7
7
T 77i
it ,, i i

M
6
60
58
1)
16896
4
97
, II H7
188 158 288 258 388 358
51)
8 9
81
,*
i

REFINE
4416
?
99
117
188 158 288 258 388 358
(4.751)
9
1
JO C31
G \f
i .
1,1,1-Trichioroethane FIND
7 188
99
117
i 11,
188 158 288 258 388 358
-------
                                                                                     r-
                                                                                     oo
87-88-9?  22:13         Triangle Laboratories of RTF, Inc.

Sample: UOST-1 SET 2 TUBEft/i  I/TC  173-46-2A/B  TLIM2284
(919) 544-5729

  Instrument H
HS352 513
180-
X.FS -
Q

J 	 ]t
50
HS352J 513
108
XFS-
8-
M/Z

51
„! ,|
38
NT7CAA 36
1B0
XFS -
0-
H/Z

52
„! ,11,
58
(5.131)
7
77
\
§5
3
,T
lee 150
(5.131) HEFINE
7
77
74^
\
8
79
i .
100 158
(5.131) Benzene
7
77
6.3 ,.
8
75
i
ISO 156

1310720

200 250 308 350

1245184

200 250 380 350
FIND
100


208 250 300 350
-------
00
00
07-88-9? 22: 19 Triangle Laboratories of RTF, Inc. (919) 544-5729
Sanple: UOSI-1 SET 2 TUBEA/B T/IC 173-46-2A/B TLIf42284 Instrument H
849 (6.491)
108-

XFS "
8-
H/Z
4



LL 46592
69

SS ?0 108
^3 •*' 8JL T
' ! " ' 'I 1 " • 1 1 » • 1 • | • 1 1 I | • • • .|...l ,,...,., ,,....,.,,.,,. ..,,...,
50 180 150 200 250 300 35O
HS352'649 (6.491) REFINE
108

XFS '
8
«/z
HI2C
180-

XFS-
8-
H/Z
4



1 39680
69

42 <-„ 70 103
/ .5s f: «5 I
50 133 150 2O0 250 300 350
;A
4



A 40 (6.491) Hethyl nethacrylate FIND
1 100
69

42 59 ?®85 1f8
i 1 •••' *V* 1
i 	 li..l . ;. if II.
50 108 150 280 250 300 35O












-------
                   CD
                   00
*  22:19         Triangle Laboratories of RIP,  Inc.
UQST-1  SET 2 TUBEA/B  T/TC  173-46-2A/B  TLIM2284
(919) 544-5729
  Instrument H
HS352 768 (7.601)
169l 9l

XFS-

8
H/Z


39

92


93
50 100 150
HS352'768 (7.6B1) REFINE
91

KFS -

0


39

92


93
' r * \ • ' ' ' 1 ' • • ' ' 1 ' ' ' ' 1 "•- •''!••
50 iee 158
49 (7.681) Toluene
180-) fl

H/Z

39
f 51 t? »*x
.,!,..,. f. ,\.\ .,. ,.\
?2
93
50 108 150

532480




200 250 308 350

483328




200 250 380 350
FIND
100


200 250 300 350
-------
07-08-97  22:19         Triangle Laboratories of RTF, Inc.
Sample:  UQST-1 SET 2 TUBEA/B  T/TC  173-46-2A/B  TLIM2284
(919) 544-5729
  Instrument H
984
i8i!

XFS-
0-
w/z

(9.841)


117 130048
82
5
50
4
c
tw

HS352J984
180-)

XFS-
0-
w/z



59
5




NTZCAA 52
180^

XFS-
0-
M/Z

51
I j a.
50






6

119
100 150 200 250 300 350
(9.841) REFINE
8









5504
1J

108
9,3 \
.2
114
I
108 150 200 250 300 350
(9.841) Chlorobenzene FIND

7
74


7
£

1;

.(!" ,
2 100

114
.-*"
108 150 280 250 300 350
-------
07-88-97  22:19         Triangle Laboratories of RTP, Inc.
Sanple: MOST-1 SET 2 TUBEA/B  T/TC  173-46-2A/B  TLII42284
(919) 544-5729
  Instrument H
H3352 1813 (IB. 131)
180-
XFS-
0
H/Z
9
51 65 7?
1
106
58 188 15B 208 258
HS352'1B13 (18.131) REFINE
180-
>:FS
0-
H/Z
fITZf
lee
0J
H/Z
9

51 65 7?
1
106
i.. J...
50 168 150 288 258
:AA 53 (le.m
9
51 65 ??
..i. . L -,.. . ii. .,
) Eth*j 1 benzene
1
, 'T1*7
58 168 150 288 258

119808

388 358

102480


308 350
FIND
108

380 350
-------
                                                                                    CM
                                                                                    03
87-08-97  22:19         Triangle Laboratories of HIP, Inc.
Sample:  UOST-1 SET 2 TUBEA/B  T/TC  173-46-2A/B  TLIH42284
(919) 544-5729
  Instrument H
1836 (18.361)
180-
7.FS-
8-
M/Z
9
39
{ 51 65 7?
1
106
92 107
50 100 150
HS352'1036 (10.361) REFINE
160-
•/.FS-
e-
w/z
MT2C
180-
XFS -
0-
H/Z
9
39
i 5,1 65 7,7
.,!..., Ji, , I] 	 ..III,.-,-.,
1
T
92 107
i . .Jli' .
.!,»,, [• I ,, ..,.!'•,•'( l.,..tr. ., ,,..,,,.,,,,.,
59 180 150
JAA 54 (10.371
9
/* 6? ??
) ro-/p-XyIene
1
186
92
i' .1
50 100 150

175104

200 250 300 350

150528

200 250 300 350
FIND
100

200 250 300 350
-------
                                                                                     CO
                                                                                     en
87-88-97  22:19         Triable Laboratories of RIP, Inc.
     e: UOST-1 SET 2 TUBEA/B  I/IC  173-46-2A/B  ILW42284
(919) 544-5729
  Instrument H
HS352 1186 (11.061)

1
%rs -


0-

51 '
6376

i I'j. .1 i.li. ll.I.i,. l!!

M/Z 58
104 74752
91
S
79

j 	

92

t,, 1

136


»,.

1@3 153 280 253 338 353
HS35ZM18& (11,061) HEFIHE
IBB-
xn-
8



M/Z 58
NT2CAA 55 (11,
188-
^FS-


8-


39 51
9


1 53248
186
F i
188 158 288 258 380 358
871) o-Xylene FIND
9


•""" 7 65 77
.: »..' ' «lL „,!
M/Z 5B
(
i iee
186

?2 1 10?
.1
I*
lee 158 288 258 388 358
-------
                                                                                     •**
87-08-9?  22:19         Triangle Laboratories of RTF, Inc.
Sarnie:  UOST-i SET 2 TUBEA/B  T/TC  173-46-2A/B  TLIft42284
(919) 544-5729
  Instrument H
1112 (11.121)
180-

0-
M/Z


5
.„!,-.., ,
Li
7* m\
J_
1,.... ,jLt.,-,,._lii
182
34 372736

185
58 180 150 288 258 300 358
HS352'1112 (11.121) REFINE
100-
XFS-
Jg-
NfZC
1B8
XFS-
0
w/z

5
,€! i
i €/" ? 1
Siyrene FIND
14 100
185
i
58 18O 150 288 258 388 358
-------
                                                                                     in
87-08-97  22:19         Triangle Laboratories of RfP, Inc.
Sample: UQST-1 SET 2 TUBEA/B  T/TC  173-46-2A/B  TLIt42284
(919) 544-5729
  Instrument H
HS352 11B5
180-
•XFS-
0.

41 57
M ilu!, ,
«/•£ 5g
HS352' 1185
1S8
XFS -


fl


56
(11.851)
K

,lj,i l^ (4,1 i
35 13584

,.T
180 158 268 258 3B0 358
(11.851) REFINE
It

„., 1O4
43 \63 r,fR^
,i,,i. .... i
M^" 2 n3$3
, ,,, in TO* , , , ^
15 18568

120

i
lOe 150 288 258 388 358
NIZCAH 58 (11.851) Cunene FIND
IB8-
8-

51

H/Z 58
If
103
} II I
15 188
128

160 150 288 258 388 358
-------
                                                                CO
            22:19
Sample: UQST-1 SET
      Triangle Laboratories of RIP, Inc.
2 TUBEA/B  T/IC  173-46-2A/B  TLII42284
(919) 544-5729
 Instninent"  H
163 Cl
i0Bi 1
1 39 i
Xr S ~
.638)
=3 c^
j f
55
=~j jj
, 	 5 	 f.,2
M/Z ' 58 ' 100 ' 150 ' 200
HS352J163 (1
1001
1 39
XFS:
O ' - i ••'•
a • • 	 • ' i i •> *
II I F : 6 46 2
1001 4l1
'•"tti- 39>
01.
ttl F.763 1
"c| a**
XFS-j 27 29
o i ,'ii'. . ,
.631) IEFINE
3 57
55
....pl 	 ,7?
69 :HVDROXVLAMINE, o-<2-MEiHVLPiop¥L>-
3
44 (58 71
J/ j -j-j
Of, r ..{Ii, J-Tj*^ .
S26: PROPANE, 2-METHVL-l-NITRO-
5|?
42
L i " " t ' " ' *
429 : PENI ANE, 2 , 4-DIMETHVL-
57
E7tT trO
° K 30 gg
w'z ge iee 150 200

250 300
NBS
2506752
350
NBS 242 Hits : 242 Searched
2162688
4 , ••> •'. . , , . 4 , I , . » , . , 4 -, 4
C4H110N
. |,.!(ll|,,,.|i...|l.,
C4H902N
C7H16
250 3B0
• i • ' • • t
255
255
1 ' i • ' • 	 " • i
255
350
-------
                    0)
08-Jul-97 22:19         Triangle Laboratories of RIP, Inc.
Sanple: UOST-1 SET 2 TUBEA/B   T/TC  173-46-2A/B  TLIH42284
(919) 544-5729
  Instrunent H
HS3E
100
XFS-
0-
i2 72 C0.720)
60
44
...l.hl 	 i 	 i..
M/Z 5O
HS35
100
XFS-
#1
100-
X.FS-
#2
IBB
XFS-
0.
#3
100-
KFS-
0-
\2'72 (0.721)
F:638 2898:
FI472 751:1
2^
3047424
100 ' 150 ' 200 ' 250 ' 300 ' 350
REFINE
6
39 ^ 43
PENTftNOIC ACID, 3-METH
6
3941,?3 5^J6
Mill 1 II 1 1 I I 1 1
tUTANOIC ACID
6
F:470 1538:BUTflNOIC ACID, 3-MIfHY
29 "^ 56 *
2627 / 38 | 45 SS^f
1.51,8 \ ,131 .M. i .1 	 :\\\ .
M/Z 10 20
NBS 287 Hits : 287 Searched
0 3031840
62 85/??
eL~ C6H1202 255
61
ll, ,,!-.,,.. ll|, ,.,,,.. IJ.I. I,, ..,,,, I. J. ...,.,..,.,..,..!.,
0 255
C4H802
f ^
>,.,,,,lt\\,ttt,.,,,.,,,\,*l,t,., ,,!,..,. -..,,.,,,..--,....,
L-
0 C5H1002 255
f>J- f &*$& ffJ
•?. .63.VI . ..«'
30 40 50 60 70 80 90 100 110 120
-------
                                                                                       oo
                                                                                       CD
88-Ju1-97 22:19         Triangle Laboratories of RTF,  Inc.
Sample: UOST-i SET 2 TUBEA/B  T/TC  173-46-2A/B  TLI842284
(919) 544-5729
  Instrument H
HS3E
100-
XFS
0-
i2 103 (1.B30)
41 323584
1 5|6
.Ji!l.....,J.I.. .
M/Z 50 ' 180 •••'••• ^g ••-.-•• 2£fl ....... 2^ , ^ , ^
HS35
188-
XFS
0,
#1
108-
XFS-
0.
#2
180
XFS
0,
#3
108
XFS
0
;2'li3 (1.831) REFINE
41
37 3,9
^•Ij 1
FI723 552:l-PENIINE, 4
4
2i7?8 3ifl
F:721 B09:HVDROXVLAMIN
41
T i
FJ692 1642:HVDROXVLflMI
4
41
NBS 58 Hits : 58 Searched
327680
44 56 58
f\ , PA , n ,
i i . . . 1 1 i . . . iiiij. ,. .j... .,.., .^. .. 4 , . .,.,..,.,. i. . , . .............
-MEtHVL- PCUI-?
3 C6H12 255
55
r, M'^ 1" ..,, ,,,??,, ,, ,,,,,,?fl,
E, 0-<2-HlfHVLPROPyii)- ^^ ^ kl
,43 C4H110H 255
44 5^5|6 58 70 J1
(fk ,,33 1 ,',, "lir??,
NE, O-<3-METHtfLBUTVD-
3 C5H130N 255
44 55X 56 70 J1
/.. 5.3X/.r58 .M.
tt/z '20 ' 30 ' 40 ' 50 ' 60 ' 70 ' 88 ' 90 ' 108
-------
                                                                                   crs
                                                                                   en
                          Triangle  Laboratories nf RTPj IYIC.
Sample:         SET 2           T/IC  173-46-2A/B
                                                                     (919) 544-5729
                                                                      Instrtiraent.' H
I1B8
            3.9 53
                                                                            183424
	 1 ~ ~~ _
-"-.!-* \ 3f ."-^ '-'^3
1 '. H '•-. I
q 5 ^ ;; pi,, ji.l. ,..j.
M/3 50
HS352*22B (2.201)
.190] 39 53 6
xFS: 37 51 65
0-' .- • . -. ":i i' • -i> «. i— 'i
163] _ 53
XFS-j at> f7/ " 54
^ .' t , ''ta,, . i -. ;"' ..-
S3 F:914 174:1,
5. ^tv? i j-i *-. ^ "^
•i ^y - -
vf-r-4 o-- 27 / is-
.-,r ,» j ^jjj , |Dt
1 '. / 1:1 1 ;
« i ''•!, . ill .J7' ..,|j
S3 F:914 186:1.
300^ e; 6
-llt--^ gg 53
-^Sl 26 ffi 54
r*/S 5g
i
69
;' 01
1O0 158 288 250 380 358
REFINE NBS 33 Hits : 33 Searched
7 9728H
69
3-BUTADIENE, 2-METHVL-
67 ^m 255
69
3-PEMfft!>l!NE, -
7 255
; C5H8
£-?
3 - PENT ft B I ENE , < E > -
7 255
188 159 280 258 3gO 356
-------
              o
              o
87/08/W    22:19        Triangle Laboratories of KIP,  Inc.
Sanple: UQST-1 SET 2 TUBEA/B  f/TC  173-46-2A/B  ILItt4i
(919) 544-5729
           ."  H
869 (8,691)
10B1 m
xl? Si if q 177
«1 .... 56 L-\ 133 .... \ Ifl
M/T.
HS3z
100-
XFS -
e_
ttl
100-j
XFS-
^ B"
100
>;FS -
f? :
it 3
J.B-'el ;
XFS-;
s3 '
H/Z
MBS
17 315392
288
i.
58 188 158 288 258 380 308
i2'869 (8=691)
2(
119 177
ftfr \ 1^3 \ Ifl
F:847 22491:CVCLOTRISILOXAHE, HEXAHETHVL-
2(
F:6?0 38155 :ARSENOUS ACID, TRISCTRIHETHVLS
2C
44 73 105 1?3 i?l
F: 509 : 1 , 2-BISCTRIHETHVLS I LYL>
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HBS 24 Hits : 24 Searclied
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288
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i7 255
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288
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[ 222
5S 109 158 288 258 388 356
-------
08-Jul-97 22:19          Triangle Laboratories  of  RTF,  Inc.
Sanple: VOST-1 SET 2 TUBEA/B   T/TC  173-46-2A/B   TLIH42284
(919) 544-5729
  Instruneiit H
HS3E
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43
50 100

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HS352'195 (1.951) REFINE
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3 172032
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-------
                                                                                      OJ
                                                                                      o
88-Ju 1-97  22:19         Triangle Laboratories of RIP, hie.
Sanple:  MOST-1 SET 2 TUBEA/B  T/TC  173-4&-2A/B  TLIH42284
(919) 544-5729
  Instrument H
HS352 87 (0.870)

100-
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100-
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1 .45 \T. 1 8.0
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224256




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255




255


129
120 140
-------
                     CO
08-Ju1-97 22:19         Triangle Laboratories of RTP,  Inc.
Sample: VOSf-i SEI 2 TUBEA/B   T/fC   173-46-2A/B  ILItt42284
(919)  544-5729
  Instrument H
HS352
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57 6g
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30 40 50 60 70 80 90 100 110 120 130
-------
                                                                                  o
07/88/97     2Z:19        triangle Laboratories of HIP, Inc.
Sanple: MOST-I SE1 2 TUBEA/B  T/TC  173-46-2A/B  TLltt42284
(919) 544-5729
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478 (4,781)
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'$•'••'• y-y&w''&fc.£',-s: ;t:^'':;v •• '--•: yfe^fertxv £.*.•:• :::::
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Project Number: 42284
Sample File: HS353
|jlfesii§i^i||i;-|||}|||iQ
'.-_. i :-:x;_-:;v :••;;;;_•_•:;'::;-._,;,;•; •:•-•_.: *%•:. •:• vXvi :•:-::•:-:•::•:• -jx^ :•
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Method 8240A VOST
Sample ID: VOST-1 SET 3 TUBEA/B
uf;:'--.'::':i-;:::'':::-::-:>;:ssy;"::::,^->>i:;:>;::i'T ::vy-:-:;:':fc*:3l3B'*-llC;i6C'6t::Sr6l
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'''?.-:•:•:• -.-•:• -:• -/;-"-:• .'•: .-:•'•''.-:-.•:• •:••:-'/-' •

T/TC
w$&


^.•,'':':'>^->:<:i-:--J-::l^:^;:'^^
Siiiillllillllllllllll
Bromochloromethanc
Chloromethane
Vinyl Chloride
1,3-Butadiene
Bromomethane
Chloroe thane
Vinyi bromide
Trichlorofluoramethane
1 , 1 -Dichlorocthene
lodomethane
Carbon disulfidc
Acetone
Allyl chloride
Mcthylene chloride
trans- 1 ^2- Dichloroethene
ten-Butyl methyl ether
Acrylonitrile
n-Hexane
1,1-Dichloroe thane
1 ,2-Epoxybutane
cis-1 ,2-Dichloroethene
Chloroform
1 ,2-Dichloroethane
Isooctane
1 ,4-Difluorobcnzene
Vinyl acetate

IS I
0.120
U
0.134
0.024 J
0.003 J
U
0.039 J
U
U
0.313
0.082 B
U
0.359 B
U
U
u
0.178
U
U
U
U
U
0.008 J
IS 2
U
'.-^.•yfftf.'gvsf.; :;:•;•;•>:;>;•!;:• vc-xo:-:
: ::^-:->:^-x:>:<-:t^rfij:p-A •>>:•' •:•>: •: :•;•:
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4.50
0.93

1.09
1.42
1-54

1.83


2.50
2.57

2.97



3.56





5-29
5.66

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0.001



0.001

0.001
0.001


0.001

0.001
0.001
0.003

0.001
0.003
0.001
0.001
0.001


0.001
n

0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05

0.05
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitrtion Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Qtuntitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitda Drive » Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax (919) 544-5491
             Savar v3.5
Printed-1&23 07/22/1997
                                                                                                                106
-------
:" Pacific Environmental Services \
Project Number 42284
Sample File: HS353
(3ie»i^icfe;ii&||

1 11:;:®:: ;::::Sll31lpl

Sample ID:
BOSilliltlli^
:• v - -.-'.•'•'. ::•::• :• x-xx-vv-i-'X-x-' :•:•:•: xv •:•••:••: x .-xv -ivxxx.vx- :-•:•-:-;•:• ••'•'•'•: '•'.•'. i-vt-xx :•:••:••:•-•:• :•.•:•:•.•: M-X-: ;-:••.•-..-.•: •:-•:•-.••.•..-.:-..•
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Method 8240A VOST
VOST-1 SET
illlleipiii
•: .-. . .- •.•:- -.-.-.•. .-. .-.-. .- :-.•:*-:;-; x- •:-.•:•/:• •
•vx".-.;.v : :•:-:-:- -:' -:•:-'•:•:•; •-:- x .;:%;>;:;.y.v ;
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Analyte
•• /, * ^ ' '/,
2-Butanone
1,1.1 -Trichlorocthane
Carbon tetrachloride
Benzene
Trichloroethene
1 ,2-Dichloropropane
Erhyl acrylare
Methyl methacrylatc
Bromodichloromethane
cis-1 ,3-Dichloropropene
trans-1 ,3-Dichloropropene
1 , 1 ,2-Trichlorocthanc
DibromochJoromethane
Ethylene dibromidc
Brornofbrm
Chlorobcnrcnc-d
i
4-Methyl-2-pentanone
Toluene
Tetrachloroethene
2-Hocanone
Chlorobenzenc
Ethylbenzene
m-/p-Xyiene
o-Xylene
Styrcnc
1 , 1 ,2.2-Tetrachloroethane
Amo«nt:" ': W&MG .. . RTv '
'"" - : - ' • iig;-x-, : ;-;-/•• 	 	
0.013 J 4.39
U
U
0.743 B 5.13
U
U
U
0.095 6.49
U
U
U
U
U
U
U
IS 3 9.79

U
0.271 B 7.60
U
U
0.004 J 9.84
0.049 J 10.13
0.098 J 10.36
0.037 J 11.06
0.215 11.12
U
,8*1*8*
J,' ,«g- : *

0.001
0.001

0.001
0.001
0.001

0.001
0.001
0.001
0.001
0.001
0.001
0.001


0.001

0.001
0.001





0.001
<5«axi. limit
:b -',. Tag ;r~ "
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05


0.05
0.05
0.05
0.05
0.05
0.05
0.10
0.05
0.05
0.05
NA- Not Applicable; Det Limib Detection Limit; Quan. Limit Quantitation Limit
IS: Internal Standard; U:
Undetected; B: Present In Blank; ]: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
             Savar v3.5
Printed: 1623 07/22/1997
                                                                                                                107
-------

Project Number: 42284
Sample File: HS353
                                                 Method 8240A VOST
                         Sample ID: VOST-1 SET 3 TUBEA/B T/TC

Cumcne
       0.005  J
11.84
0.05
Toluene-d
 Reviewed by,
Dm "7;
                          NA- Not Applicable; Dct. Limit; Detection Limit; Quan. Limit: Quantitarion Limit
     IS: Internal Standard; U: Undetected; B: Prewnt In Blank; |: Estimated- Below Quanritation Limit; E Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                  Savar v3.S
                                                      Printed: 16:23 07/22/1997
                                                                                                        108
-------
                                 Pacfic Environmental Services
Project Number: 42284
Sample File:     HS353
                                           Method 8240A
                                           Sample ID:
VOST-1 SET 3 TUBEA/B T/TC
Client Project:
TLIID:

S407-003


Dilution Factor:
Date Received:
Date Analyzed:
1.00
06/30/97
07/08/97

                            Tentatively Identified Compounds

                                                                              Amount uq
Unknown                          0.72      29196276       4.511     4752864
C4H8 Isomer                       1.02      8162963       4.511     4752864
Hexamethylcyclotrisiloxane           8.691      19628418       9.791     11518189
Methylbutane Isomer                1.630      7398669       4.511     4752864
C5H8 Isomer                      2200      6169843       4.511     4752864
Pcntane                           1.940      5718449       4.511     4752864
Methyl Propane Isomer               0.86      4553779       4.511     4752864
C6H12 Isomer                       3.47      3123308       4.511     4752864
Tetrahydrodimethyl Pyranone Isomer   4.120      3086243       4.511     4752864
C8H16 Isomer                      7.821      4978136       9.791     11518189
                                                                                       1536
                                                                                       0.429
                                                                                       0.426
                                                                                       0389
                                                                                       0325
                                                                                       0301
                                                                                       0240
                                                                                       0.164
                                                                                       0.162
                                                                                       0.108
Triangle Laboratories, Inc.
801 Capitola Drive* Durham, North Carolina 27713
Phone: (919) 544-5729 " Fax: (919) 544-5491
                                                                  Printed:   10:26  07/25/97
                                                                                       109
-------
07-e8~97  22:43         Triangle Laboratories of RTF, Inc.
Sanple: UOST-1 SET 3 TUBEA/B  T/IC  173-46-3A/B  ILIf4Z284
(919) 544-5729
  Instrument H
HS353
108-

XFS -



0-






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                                                                                       o-
                                                                                       J
-------
'JUAN
No.
1
'2
3
4
5
6

3
9
10
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12
13
14
15
16
17
18
19
20
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30
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88
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LAS-BASE QUAN
Area
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2438752
3018852
1148376
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A
f 1
vb







A
n
bv


4
5
C)
5
5
7

12
O
O
1 iC i
1
•&•
o
1
o
o
2
2
O
2
O
T

~z
3
o
.*
0
o
o
5
rr
4
0
0
5
O
f

f
w
6
O
O
O
0
0
o
0
«r
'
7
0
RT
. 50
.66
.79
.1.1
.09
.51
1 1
.07
.93
.00
Oo >•
.42
7t^-|
.00
.33
.00
.00
.50
.57
.00
.97
.00
T Si

r-)^
.56
.00
1 °
.00
.00
.00
.29
fL/
.39
.OO
.00
.13
.OO
±-r

•"! >1

.49
.00
.00
.00
.00
.00
.00
.00
e -i
- — > X
.60
.00
GM
128
1.14
117
65
84
98
O Q
95
5O
_ 62
°S 30
94
.94 64
106
101
96
142
76
43
76
84
96
"7 X

53
%j o
57
63
d1?
M ,£
96
83
62
57
43
•"f sJ
72
97
117
78
130
63
C C
O O
69
83
75
75
97
129
107
173
43
92
164
07-08-97 23:
Name
& rrjmoc h 1 o rorne t ~a ne
1 ., 4-D i f 1 uorobepzene
Chlorobenzane-dS
l,2-0ichloroet..-.ane-d4
Benzene-d6 \
Toluene-da /3aflK
o— Xv 1 ene'-dl Or vv
•— ' ^. y J. C: I 1 tT *• -J JL "^1 yJ'
4-Brornof 1 uorobenzene
Chloromethane
Vinyl Chloride ^v
1 3~Butadiene t^^^5T\-^
Bromonethane ^
C h 1 o r oe t ha ne ^v^KTI^J
Vinyl bromide
Trichlorof luor one than
1 ., 1-Dichloroethene
lodometriane
Carbon disulfide
Acetone
Allyl chloride
Methylene chloride
i ,--.















s






trans-1 ,2-Dichloroethe_ne
tert-Butyl methyl ^frt»
Ac r y 1 on i t r i 1 e J^Q^
n-Hexane
1, 1-Dichloroetnane ^
1 -o 	 P'r\rswvt"bll't"*r:l r\f=>/l£?}n\J^
^
i^



c i s- 1 , 2-0 i c h 1 o i- oet he ne
Chloroform
1,2-Dichloroethane
Isooctane ^—J^\
VT n\/l ^^P*i"^i't"»» /vv^k*^^
2-Butanone
1,1,1-Trichloroethane
Carbon tetrachloride
Benzene
Tr ichloroethene
l,2-Dichloropropa>D^<^
Ethyl acrylate J&r
Methyl methacrylate
Bromodichlorome-hane








^^
P



cis-1 ,3-Dichloropropene
trans-l.,3-0ichloropropen
1,1,2-Trichloroethane
Dibromochloromethane
Ethylene dibromide
Bromof orm
4-Methyl-2-pentanonsn
Toluene
Tetrachloroethene



•N
-^y_
fyj-
S

Data Review: TtO





Dote: -,
1/-v Q-7





111
-------
No.  MAT FOR REV Delta
Area P.Flaas
RT
QM Name

•«.' X
52
Cl *5*
54
55
56
58


49
1OO
1OO
99
100
73

— .•
17
87
36
78
94
42


65
98
94
85
98
T <~S
77

ij>
1
1
O
0
1
—r
0
,
O *"» v-J s_' _'
453O4
3O47OO
755472
274128
2&13276
133563


bb
bv
vv
bv
bv
bv

>~j
9
1O
1O
11
11
11

- , vJ
.34
.13
.36
.06
.12
.84


112
1O6
1O6
106
104
O"T
oo
105

^'"Hexa no ne?
Chlorobenzene
Ethyl benzene
fn-/p-Xy lene
o-Xylene
Styrene
3 x , z , z i e urscn ioroE' ~n<:n i
Cumene
                                                                 112
-------
                                                                                      CO
07-08-97  22:43         Triangle Laboratories  of  BIP,  Inc.
Sanple: WST-1 SEI 3           f/IC   173-4&-3A/B   TLIft422e4
                                                                  (919) 544-5729
                                                                    Instrument H
      93 (0,93i)
1B8
                                                                           78848
XF'S
  8-
     44
    ^..4«J
        52
       58
                  100
150
100
250
300
350
HS3b3'93  (0.931)   BEFINE
  B_J^
                                                                           69632
        52
       58
                              150
            280
            259
            300
           350
MT2CAA 9  (0.938)  CMoronethane
       ET i"i
       JO
                                                                            FIND
                                                                             100
  0
     44
        52
                  100
                              150
            100
                        330
                       358
-------
88-Jul-97 22:43         Triangle Laboratories of RIP,  Inc.
Sample:  VOST-1 SET 3 TUBEA/B  T/TC  173-46-3A/B  ILIU42284
                                                                  (919) 544-5729
                                                                    Instrument H
HS353 108 (1.080)
    39
       5.4
1001
XFS
  0
M/2
         57
         /
                                                                          107520
                  100
150
200
250
3011
350
HS353'108 (1.081)  REFINE
       54
100
XFS-
  0
M/Z
      53
                                                                           81920
                  100
ISO
20(3
250
T2CAA 11  (1.080)  1,3-Butadiene
       54
1001
7.FS-
  0
M/Z
     53

     50
                  100
150
200
250
see
350
                                                                            FIHD
                                                                             100
300
350
-------
87-68-97
  22^43         Triangle Laboratories of BTP, Inc.
MOST-1 SEI 3 TUBEA/B  T/fC  173-46-3A/B  fLI»42284
(919) 544-5729
  Instrument H
HS353 142 (1.42B)
160-
%FS-
8-
P/Z
44 28416
g
93
4

50 1@0 150 288 250 308 358
HS353'142 (1.421) REFINE
100
XFS-
8-
M/Z
9

79 '"}
1,1. J
4 14976


59 180 150 200 250 388 350
HfZCAA 12 (1,428) Bronowethane FIND
188-
XFS-
8-
M/Z
9
93
46 fl i '"i
-------
  -Jul-97 22:43         Triangle Laboratories of RTF, Inc.
Sample: MOST-1 SET 3 TUBEA/B   T/TC  173-46-3A/B  TLIU42284
(919) 544-5729
  Instrument H
HS3G3 153
im\
XFS,

«J
44
!S

jijl i.

n/'z, 50

5

„


HSCIEI3"* 153
1CICI
av
Cl

49
!

w^'z; 50
6




MflSI'ER 13
1CICI
*j»z 'C' *
«r »JT *S*

0


49
i

w/'z 50
(1.530)
23296

7,0
'
• * 1 • .. - | ..--,---.,---- ( - - '•] ..-.,.,-.,....,..-. ,....,!.-.,
100 150 200 250 300 350
(1.531) REFINE
0


1392
66


100 150 200 250 300 350
(2 . 02B ) Ch loroethane F IHD
6







*!
4 100
66



100 150 200 250 300 350
-------
0V-08-97  22:43         friangle Laboratories of BTP, Inc.
Sanple: WSf-1 SET 3 TUBEA/B  I/TC  173-46-3A/B  TLIft42284
(919) 544-5729
  Instrument H
HS3b3 183 (1.838)
100-
XFS -
8
M/75
11
42
5564J0
H 22784
103
105
i
53 106 150 200 250 300 350
liS353'iB3 (1.831)
160
XFS
8-
M/S
li

4,7 'f B,?
>1 20736
103

185
/*
58 100 150 200 250 388 350
H12CAA 15 (1.848) Trichlorof luoronethane FIND
180-
XFS-

0-
M/Z
1C

35
1 4,7 T, 82
11 100
103
X

165
\ H.7
58 103 150 200 250 300 350
-------
                                                                                       00
Cf?
til
    3-97  22:43         Triangle Laboratories of IIP, Inc.
Sample: VOST-1 SET 3 IUBEA/B  T/TC   173-46-3A/B  TL1S42284
(919) 544-5729
  Instrument H
258 (2.588)
leei
XFS-

0-
H/Z
7

44
1 5,3 6,7
6 585728

78
.•'
.1.. , 	
58 160 150 200 250 308 350
H83S3'25B (2.581) REFINE
100:
XFS-
0-
M/Z
7

44^
6 577536

78
,1.
58 10e 158 200 250 308 350
NTZCArt 18 (2.508) Carbon disulf ide FIND
108:
XFS-
9-
w/z
7

,v
6 180

78
53 160 150 200 250 308 350
-------
97-88-97  22:43         Iriangle Laboratories of RTF,  Inc.
Sample: WSI-1 SET 3 TUBEA/B  I/IC  173-46-3A/B  !Li«42284
HS353 257 (2.578)

160! 43
XFS -
  0
      44
        58
       .....K
              78
 J^L
                                                                 (919) 544-5729
                                                                   Instrument H
                                                                          19968
                              158
                                         200
                                    253
                                   388
                                  350
H8353J25? (2.571)  REFINE
ieBi
    43
  0
m/z
        58
                   iSl
                                                                          17152
      58
186
150
280
258
300
350
NT2CAA 19 C2.570)  Acetone

IBB-, "3
XFS-
  e
M/Z
       ...
      44
        58
      58
18Q
150
208
250
308
                                                                           FIND
                                                                            100
350
-------
                                                                                     o
                                                                                     CM
07-88-97  22:43         Triangle Laboratories of RfP, Inc.

      :  UOST-1  SET 3 IUBEA/B  I/TC  173-4&-3A/B  TLI»42284
(919) 544-5729
  Instrument H
29? (2.978)
100-

XFS-
0-
H/Z
4


49
.II
9 315392
84
51
55
i.J?8. _

88
f
. .1
so iee 150 200 250 300 350
H8353'297 (2.971) REFINE
lee-

s'; FS-
0
M/Z
NT2C
168;

XFS-
0-
H/Z
4


JJ
9 307200
84
51
j 55
/ 70
«...' 	 I.-

lr
50 lee 150 200 250 300 350
;AA
4


47
.4,11,
21 (2.978) Methylene chloride FIND
9 100
84
51
83

88
56 lee 150 200 250 300 350
-------
                                                                                      OJt
07 00 97  22:43         Triangle  Laboratories of  RTP,  Inc.
Sample: WST-1 SET 3 IUBEA/B   T/TC   173-4&-3A/B   TLIft42284
(919) 544-5729
  Instmnent H
356 (3.5&B)
1801


XFS-
e-
M/Z
5
41


_M 1
56
\
55
^4
51
7 174080



58 t\f
/ y T
'"'•""^'F •""'" • 	 ' !"" ' ' ' • 1 ' • ' • ! ' ' ' ' 1 ' • • • '"I "'- ••'!-•'' ' I • • "•' • I" ..--,-.-- | . - - - ,
168 158 260 258 3G8 358
HS353'356 (3.561) REFINE
100-

XFS-
0
M/Z
5
43
I
J
56
55
»(™-|u*4
50
? 159744


CV *f
100 153 200 250 300 350
HT2CAA 25 (3.57B) n-llexane FIND
lee-;

XFS-

0-
M/Z
5
43


|
JJ
56

55

7 100


86
7,1 j
50 133 158 203 258 300 350
-------
                                                                                      CM
                                                                                      CM
67-88-97  22:43          Triangle Laboratories of RTF,  hie.
Sample: MQST-1 SET 3 TUBEA/B  T/TC  173-4&-3A/B  TLI842284
(919) 544-5729
  Instrument H
HS353 529 (5.291)
10@i
XFS
5
56
41 \
55
JiLN
50
7 17664
78 *7Q
f O
130 150 200 250 300 350
HS353J529 (5.291) REFINE
100
XFS

0
H/3
5

56
43 ^
7 10944


7,1 9,9
58 100 150 200 250 300 350
HT2CAA 31 (5.291) Isooctane FIND
5


XFS
S
H/Z
56
X

4155
7 100



58
/ _ gg
58 100 150 200 250 300 350
-------
                                                                                     cr>
87-88-97  22:43
                        Triangle Laboratories of  RTF.  Inc.
Sanple: UQST-1 SET 3 TUBEfl/B  T/TC  173-46-3A/B  TLI*42284
                                    (919)  544-5729
                                      Instrument H
HS353 439  (4.391)
                                                                            4808
XFS
  o
       59
                  139
158
288
250
388
350
HS353M39 (4.391)  REFINE
     AI
1801
        57
                                                                            3760
  0
       5O
                  100
158
200
250
388
358
HT2CAA  33  (4.388)  2-Butanone
     43
                                                                           FIND
                                                                            100
XFS-
H/Z    58
            72
             t
                  183
15Q
280
250
300
350
-------
87-08-97  72:43          Triable Laboratories of RTF, Inc.
Sanple: MuSf-l SEI 3 TUBEA/B  f/TC  173-4&-3A/B  TLIM2284
(919) 544-5729
  Iiistruneiit H
HS353 513
168-
0
M/Z

-T
• ' • i '
se
H83531 513
i9e:
B-
M/Z

-f
50
NTZCftA 36
188:
XFS-
8-
M/Z

52
„! f
58
(5,131)
7
77
65
8
i4 ...
100 158 200 250
(5.131) REFINE
7
V7
74 "'
\
8
79
108 158 288 250
(5 . 13.1. ) Benzene
7
T?
\
6.3 ,
8
79
i'"
iee 150 200 250

1343488

300 350

1277952

308 350
FIND
100


308 350
-------
                                                                                      in
                                                                                      CJ
07-08-97  22:43         Triangle Laboratories of IIP, Inc.

Sanple: WSf-1  SET 3 TUBEA/B  T/TC  173-46-3A/B  TLI842284
(919) 544-5729
  Instrument H
649 (6.491)
108
0-
M/Z
4
j
;1
6
i., ..i,l,i.l ,„
5O176
9
. . , i,.i II.
50 100 150 200 250 300 350
HS353'649 (6.491) REFINE
100-

"XFS
O-
M/Z
HT2C
100:
XFS -
e-
4


jj
1 42752
69

«5g

70 100
( 85 T
'"' • i • ' • • i • • • ' i • • > • i • ' • • t • • ' • i •"' • • • i ' • • • i 	 "i • "" • • • i • • • • i • • • • i • • • • i
58 100 150 2O0 250 308 350
:A


A 48 (6.491) Methyl nethacrylate FIND
1 100
6
42 5,9
; 	 i,..|
9
70 160
50 100 150 200 250 300 350
-------
                                                                                     CO
                                                                                     CM
R7-HR-97  ?.?,:43          Triangle  Laboratories of  RTF,  Inc.
Sample: UOST-1 SET 3 TUBEA/B   T/TC  173-4&-3A/B  TLItt42284
(919) 544-5729
  Instrument H
HS353 769 (7.601)
9
iQ&~\

XFS-
39
^ \ ^ —
til **
13 .1, ..,. ..ii 	 J.H.] 	 	 j-. i
«/z 59
HS353'76B (7.6B1)
9
•
vk" "
OQ
"•*- UQ
i 51 6.5 3^,
13 .,!..,. j. ,j!.i 	 ,.. i
H/Z 58
HTZCAH 49 (7.681)
• C"3 ^

XFS -
39
i 51 65 °^-
e.L . r^l . ,\\ „ . .. "';.
H/E 58

1
92
33
188 158
REFIHE
1
92

93
188 158
Toluene
i
92
93
188 158

548672


288 258 300 358

491528



288 258 338 350
FIND
188


283 258 388 358
-------
07-08-97  22:43         Triangle Laboratories of RTF,  Inc.
Sample: UOST-1  SET 3 TUBEA/B  T/TC  173-46-3A/B  TLIM2284
(919) 544-5729
  liistrunent H
984 (9.841)
100-

HFS-
e-
H/Z
117 126976
82
54 ;19
40 ( .F 7(g j?3 11\|
58 188 150 288 258 388 358
HS353'984 (9.841) REFINE
100-
•
-------
                  Cl
87-80-97  22:43         Triangle Laboratories of RfP, Inc.
Sample: UOST-1 SET 3 TUUEA/B  T/TC  173-46-3A/B  TLIM2284
(919) 544-5729
  Instrument H
HS353 1013 (18.131)
108-
XFS -


0-
9


51 65 7?
..I.I.. 4I..I.. J.l.i._ 	 Ill 	
1

106
)

M/Z 50 100 150 200 250 3O8
Hsasa^iBia (is.isi) REFINE
168
>;FS -

9


5 51 ft5 77
pi.. L 4... . 	 	 ..II..., ,
1

186

[ . , ,vij(
H/Z 5Q 158 288 258 3BB
HT2CAA 53 (IB. 131) Etfej Ibenzene
IBBi
XFS -


B-
3


5^1 65 77

1

186
Tie?

H^Z 50 10O 150 200 250 308

117769




358

106352




350
FIND
168




350
-------
                                                                                     CM
07-B8-97 22:43          Triangle Laboratories of RIP, Inc.
Sample:  UQSI-1 SET 3 TUBEA/B  T/TC  173-46-3A/B  TLIft42284
(919) 544-5729
  Instrument H
HS353 1036 (18,361)
100-
y.FS-


8-
9

^«J
{ 51 eg 77
...L, A..,.., !!,...,. ...JIL.,,.. ,
1 186368
1(

92
i 	 i
16

107
i.. .... __
' ' ' 1 ' 	 m,,,,|,n,,,,,,,,f. 	 , 	 , 	 , ,_, . ^,—r- 	 	 , 	 ,-~|~r- .,-- , 	 ,— , 	 T-.,~r r—j 	 -,- 	 	 	 .....,— (. ..^-,,_, 	 , 	 ,( ^- , 	 	 	 	 , , 	 , ,., , , , 	 . ... .,., , . ,., 	 , 	 ,
M-rs 58 100 150 208 250 388 350
H5353'1836 (10.361) REFINE
100-
XFS-

tj
9

/951 ^ 7?
| jt Yr lit
1 159744
life
92
i . j.
107
;•;
H/Z 56 108 150 200 250 388 350
NT2CAA 54 (IB, 371) n-/p-Xyiene FIND
, „„ 91 100
1.00-
XFS -




39 ,-«
f" 58 7


1C
92
i .1
16



M/Z 58 100 158 208 250 300 350
-------
                                                                                     o
                                                                                     CO
87-88-9?  22:43         Triangle Laboratories of RIP, Inc.
Sample: WSf-1 SET 3 TUBEA/B  T/TC  173-4&-3A/B  TLI842284
(919) 544-5729
  Instrunent H
HS353 1106 (11.061)
188
XFS-
^9"
9
78
51
1 fil ?9
...L |.|. J.|..,,-J|! I,,..,,.,
I 1C

92
L....J
)4 63488
1BG
ii- .
56 180 158 288 250 3G8 358
HS353'11B6 (11.8&1) REFIHE
iee-
>;FS-
J
HSB-^-iv-
lil
188-
XFS-
8-
H/Z
9


1 53584
1
92
i.
R6

58 168 15B 268 258 300 358
;flrt 55 (11,071
9
39 51
.]».,! I-,, 1|. ... i
) o-Xyiene FIND
?i 188
186
|2 187
58 188 158 288 258 388 358
-------
B7-88-97 22:43          Triangle Laboratories of RIP, Inc.
Sanple:  UOST-1 SET 3 TUBEA/B  T/fC  173-46-3A/B  !LI«42284
(919) 544-5729
  Instrument H
HS353 1112 (11.121)
i<
100"


XFS-


8-

103
7 fi
•
51
1 7fi
, il 63
.,...., l,....A(....,..i|!

102
*•,
i 	 .1 	
M1U..4.....7JI.-V ,_|t,,ul|, _, 	 , 	 , 	 , 	 j_
34 307290




105
/

' \ ' ' ' 1 '" ••!'"' 'I .---|.---j... .j..,,,, ..»| ,,,. j
M/Z 58 100 150 200 250 300 350
H8353MI12 (11.121) REFINE
108-

•» * f-f*
XFS "


O-
li
103
78

51

...L., |i ...i 	 i)


182
....BS...,N
m 270336




105

^^ k • ' • • i • • •- 	 " 	 i • • • " "• i *-~" — • • — i • — • — • — • — i • — • — • • — i • — • — • — • — i — • — • — • — • — i — • — • — • — • — i — • — • — ^~" — i — • — • — • — • — i — • — • — • — • — i
H/Z 50 100 150 200 250 300 350
NT2CAA 56 (11.121) Styrene FIND
180-


0
if
103
51 ?67
,1. JL _.j^.. .„"
8 102
, 8.9 .'}
M 103

185

M/Z 58 100 150 200 250 300 350
-------
                                                                                    Cl
                                                                                    CO
87 80 -97  22:43
                        Triangle Laboratories of RTP, Inc.
Sample: WSf^l SET 3 TUBEA/B  I/fC  173-46-3A/B  TLIi42284
(919) 544-5729
  Instrument H
HS353 1184 (11.841)
180-
XFS-
8-
H/Z
11
41 57
77 91
15 12672

120
'11. 1
53 109 150 200 250 300 350
HS3S3'1184 (11.B41) REFINE
168-
XFS-
0-
W/2
It

^i35,1 63 79 \
illiL (» ,* ii— •, 1. «| m tr 1 ,,*
J5 3536

106
56 106 150 200 250 300 350
H12CAA 58 (11.851) Ciiwene FIND
IBB-
XFS -

8
M/Z
It

77 103
5^.6.3 | 1
15 100


i
58 188 150 200 250 300 356
-------
                   CO
                   CO
08-Jul-97 22:43          Triangle Laboratories of RIP, Inc.
Sample: MOSI-1 SET 3 TUBEA/B  T/TC  173-46-3A/B  TLIH42284
(919) 544-5729
  Instrument H
HS353 72 (8.720)
100, 6i 2588672
m/z 50 ' 100 ' 150 ' 200 ' 250 ' 380 ' 350
HS353'72 (8.721) REFINE HBS 49 Hits : 49 Searched
c.a PS^<}SPfl
100 60 £*3?*tv
*FSJ 38 4JL43 62
#1 FI389 12997
100-1 39 '
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1081 283638
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111 5,5 III r 1
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-------
                                                                                      en
08-Jul-97 22:43          Triangle Laboratories of 1TP, Inc.
Sample: UOST-1 SET 3  TUBEA/B  T/TC  173-46-3A/B  TLItt42284
                                                                  (919) 544-B729
                                                                    Instrument H
       182 C1.820)
10014*
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                                                                          397312
      50
                  100
150
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258
  300
      350
HS353'102  (1.821)   REFINE
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-------
                                                                                   in
87/00/37     22*43        Triangle Laboratories of IfPj  Inc.
Sapiple: UGST-1 SET 3          T/fC  173-4&-3A/B  TLItt42Z84
(919) 544-5729
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-------
                                                                                  CO
                                                                                  CO
:43
                         Triangle Laboratories of WP, Inc.
Sanple: MOSI-i SET 3          f/IC  173-46-3A/B  ILli42284
(919) 544-5729
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NBS 242 Hits : 242 Searched
282753
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C4H110N 255
255
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255
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2@9 250 359
-------
                          Triangle Laboratories of HP,  Inc.
:^\PI 1e:  UOST-1 SET 3  TUBEfVB   T/TC  173-46-3A/B  TLIJI42284
(919) 544-5729
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108544
208 258 308 350
NBS 33 Hits : 33 SeareJied
102400
255
255
C5H8
255
C5H8
208 250 300 358
-------
                                                                                  00
                                                                                  en
H7/IW97    22:43         Triangle Laboratories of IIP,  Inc.
5;arw»!e; UGST-i SET  3          I/TC  173-46-3A/B
(919) 544-5720
 instruwent' !i
H8353 194 (1,948)
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XFSJ S\| 'M*|!58 ,.J^
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250 380 350
NBS 83 Hits : 83 Searched
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111111
255
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i i i i • i • i
255
C4II110H
250 300 356
-------
                                                                                       CD
B8-Jul-97 22:43          Triangle Laboratories of RTF,  Inc.
Sample: UOSf-1 SET 3 IUBEA/B  T/TC  173-46-3A/B  TL1*42284
(919) 544-B729
  Instrunent H
HS353 86 (0.860)
1001 "44
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M/Z 58 ' 100
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158 208 250
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57
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242688
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: 114 Searched
235520
255
255
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129
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-------
BS-Jul-97 22:43         Triangle Laboratories of RIP, Inc.
Sample: UOST-1 SET 3 IUBEA/B  T/TC  173-46-3A/B  TLI»42284
(919) 544-5729
  Instrument H
HS353
1001 A
'/.FS- ,
0. J
M/Z
HS353
1601
XFS|
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106:
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0:^_
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347 (3.478)
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142 5
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100T 5
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t? ^' |iiil|llll|. .I.|1.1T[1»I.|1 -11J >I1I
M/Z 28 38 40 50
NBS 61 Hits : 61 Searched
,6 50688
6? 69 84
\
INK, TETROHYDRO-3,6-0IMETH¥L-
255
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f7 6?N6(9 8,4
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60 78 80 90 108 110 120 130
-------

      22:43        Triangle Laboratories of WIP, Inc.
:  WST-i SET 3 TUBEfVB  T/IC  173-46-3A/B  fLIft42284
(919) 544-5729
 Instruwent* H
412 (4.121
138] 5
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6
6,9
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!-. ^9
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M''Z 50 100 150
HBS
34560
209 258 389 350
NBS 66 Hits : 66 Searched
29440
.,....,. ...... i , ... i | t ...,.>..,
,6-DIMETHVL-
255
,6-MME!HVL-f fRANS-
255
C7H1202
255
C9H18
200 250 300 350
-------
                                                                                     CM
yy/ljjj/yv5    2Z:43        Triangle Laboratories  of  ItTP,  Inc.
Saw IB; UQST-1  SET 3 IUBEA/B  T/TC  173-4&-3A/B  fL 1*42284
(919) 544-5729
 Instrument', H
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58 188 158 289 156 3C8 353
(7.821) NBS 74 Hits : 74 Searched
5,5 „.., 61104
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triz- '3fi*l
41 ^ C8H16
|43 / "78810,, q? f12
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58 188 150 280 258 360 358
-------
Pacific Environmental Services :
Project Number 42284
Sample File: HS354
Client Project S487-003
IT3 ID: 173-46-4A,B

Date Received:
'Date Analyzed
Sample ID:
06/30/97
: 07/08/97
Method 8240A VOST
VOST-1 SET 4 TUBEA/B T/TC
Response
File: ICALH7GS


Axwlyte '" ."";' • .•'.-....:. ' .:':

Bromochloromethane
Chloromethane
Vinyl Chloride
1,3-Butadicne
Bromomethane
Chloroe thane
Vinyl bromide
Trichlorofluoromcthanc
1,1-Dichloroethcne
lodomethane
Carbon disulfidc
Acetone
Allyl chloride
Methylene chloride
trans-1 ,2-Dichloroethene
tert-Butyl methyl ether
Acrylonitrile
n-Hexane
1 ,1-Dichloroethane
1 ,2-Epoxybutane
cis-1 ,2-Dichloroethcne
Chloroform
1 ,2-Dichloroethane
Isooctane
1 ,4-Difluorobcnzcne
Vinyl acetate
•';' :{ :Aj*K«ttfc ' *-RAG.:-;:-
tig .-.•.::..• . •.". ••:
IS1
0.171
U
0.180
0.018 J
0.004 J
U
0.064
U
U
0.420
0.091 B
U
2.798 BE
U
U
U
1.272 E
U
U
U
U
U
0.051
IS2
U
.. 3RT;{ '' '.. "
"•7 •• •
4.50
0.92

1.08
1.41
1.53

1.82


2.49
2.57

2.97



3.56





5.30
5.67

•.•Etefc'limit--;-:-"-
•' ' '••<%


0.001



0.001

0.001
0.001


0.001

0.001
0.001
0.003

0.001
0.003
0.001
0.001
0.001


0.001
.r.t :i:Qtt«nTIJBBlt.
• ' « ' ' •: as ' '

0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05

0.05
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
             Savar v3.5
Printed: 15:02 07/22/1997
               143
-------

Project Number 42284
Sample File: HS354
Client PH>J«<* S4€74>0
-,-; . i» -' - •-.'
;•;••; :.".~: • ' :;;:••.:.•:::••• •m.:::xS-VfAf«-^«^^fv¥: :, KiSK.jiiiiHvSvi-ri-i :
11 lili I
Sample
5" - >~ Date Eeceived: ^30/97
Uate Analyzed i 67/OcV§7
s|l|||||pil||||||;
||i||i|||i|||||p.!Hrt
Method 8240A VOST
ID: VOST-1 SET 4 TUBEA/B T/TC
> -< Response
'•
File: ICALH708


,; '• , TO v ' ' . ' ' 	 ' ag< • . ag- ... • '.' • ' - •:',.,•.- tHt •
2-Butanone
1 , 1 . 1 -Trichloroethane
Carbon tctradiloridc
Benzene
Trichloroethene
1,2-Dichloropropane
Ediyl acrylate
Methyl methacrylatc
B romod ichlorome thane
cis-1 ,3-Dichloropropene
rrans-13-nichloropropene
1 , 1 , 2-Tri chlo roc thane
Dibromochloromethane
Ediylenc dibromide
Bromoform
Chloroben/rnc-d
4-Mcthyl-2-pentanonc
Toluene
Tetrachloroethcne
2-Hexanone
Chlorobcnzene
EthylbcnTene
m-/p-Xylcne
o-Xylene
Styrcnc
1,1,2,2-Tetrachloroethane
0.016 ] 4.40
U
0.008 ] 4.92
1.108 BE 5.13
U
U
U
0.097 6.50
U
U
U
U
U
U
U
IS 3 9.80
U
0.357 B 7.61
U
U
0.007 ] 9.85
0.050 10.14
0.122 10.37
0.045 ] 11.08
0.239 11.13
U

0.001


0.001
0.001
0.001

0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001

0.001
0001





0.001
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.10
0.05
0.05
0.05
NA- Not Applicable; Det Limit: Detection Limit Quan. Limit Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; ]: Estimated- Below Qtuntitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax; (919) 544-5491
             Savar v3.5
Printed; 15rf2 07/22/1997
                                                                                                                  144
-------
                                      Pacific Environmental Services
Project Number 42284                                                              Method 8240A VOST
Sample File: HS354                                         Sample ID: VOST-1 SET 4 TUBEA/B T/TC
Client Project S4Q7-003


Analyf* '-[\ •'• \"\ • • ••.:"••' '".'.

Cumene

Surrogate Staamarjr, - - ":
1 ,2-Dichloroethane-d
4
Benzene-d
Toluene-d
8
Date Received: Ofi^Q/97: ;
Date Analyzed :$?/08/9?


: Aaxnat* HAa-:" RT
. tig . •;• ... , ••••
0.005 J 11.86

.-/••Amount *< ,•:•.:.-•"* , —-US' • ': '-'
0.287 5.11
0.309 5.10
0.294 7.52
Response File: ICALH7Q8


Uettiatit ; ; Q^an-tinit
% • " . «*8.
0.05

-^^ -^(~i '^f^
\ 115
2 124
3 118
 Reviewed by.
                         NA- Not Applicable; Det. Limit: Detection Limit; Qoan. Limit: Quantitation Limit
     IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range

 Triangle Laboratories of RTF, Inc.                                                                              Savar v3.5
 801 Capitola Drive • Durham, North Carolina 27713                                                     Printed: 15:02 07/22/1997
 Phone: (919) 544-5729 • Fax: (919) 544-5491                                                                   A  * C
-------
                                    Pacific Environmental Services
Project Number: 42284                        Method 8240A
Sample File:     HS354                       Sample ID:        VOST-1SET4TUBEA/BT/TC
Client Project:
TUID:

S407-003


Dilution Factor:
Date Received:
Date Analyzed:
1.00
06/30/97
07/08/97

                               Tentatively Identified Compounds
          Name ........... ; _ Bf         Area       jSJRT
   Unknown                          0.72      37877712       4.511     5059289            1.872
   Methylbutane Isomer                1.620      33751072       4.511     5059289            1.668
   CSH8 Isomer                        2.16      11259503       4J11     5059289            0556
   Halogenated Hydrocarbon             1.02      10214934       4.511     5059289            0505
   Pentanc                           1.930      7658952       4-511     5059289            0.378
   Methyl Propane Isomer               0.85      5962515       4.511     5059289            OJ95
   Hexamethylcyclotrisiloxane           8.711      12839838       9.801     11919703           0.269
   Tetrahydrodimethyl Pyranone Isomer   4.120      5164354       4.511     5059289            0.255
   C6H12 Isomer                       3.48      3255152       4511     5059289            0.161
   C7H16 Isomer                       5.57      2870396       4.511     5059289            0.142
Triangle Laboratories, Inc.
801 Capitoia Drive * Durham, North Carolina 27713                            Printed:   22:30  07/25/97
Phone: (919) 544-5729 * Fax: (919) 544-5491
                                                                                         146
-------
§7-88-97  23:87
                 Triangle Laboratories of 1TP,  Inc.
:  MOSf-1 SET 4 TUBEA/B  T/IC  173-46-4A/B   ILIM2284
(919) 544-5729
  Instrument H
HS3E
108-

XFS -
A
Hsn
'A


M
'!»(.;
4? 8427872
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5.'


Jtfi
t3

1 15.95
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'5f7 ' 8/1 jW37f I 14 59 fl » i,
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4.8 6.0 8.8 10.3 12.0 14.0 16.0

                                                                            p
-------
Uft'rl OB- ,:  H3354
   LAS-8ASE  QUAN
              D7-08-97
No. HAT FOR REV Delta
Area P.Fiaqs
RT
3H Name
1
2
5
4
5
6
3
9
10
11
12
1 "^
14
15
±itfmmm.

17
18
19
21
22
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25
26
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28
29
30
31
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33
34
35
36
37

W X
40
41
42
43
44
45
46
47
"1C"*
49
50


1OO
100
100
54
99
1OO
1OO
100
o
100
39
•ati
•-S-L
0
90
.-, ^
•*-'-'
O
10O
87
100
0
*. t f^
i S
•-> r
*»-""
100
0
rr rr
0
0
0
100
•D"">
""' *•
93
0
36
1OO
0
In
-*fw
100
0
0
0
0
0
o
0
^y,~~T
1OO
0


91
92
96
2O
80
89
87
81
0
77
49
"TT
0
56
1 /-s

O
82
61
87
0
, ^
O A.
-y

99
0
A A
0
0
0
79
"'I

75
0
14
93
0
^n
wW
92
0
0
0
0
0
0
0
-i- cr
94
0


99
?7
9S
67
81
99
94
89
0
100
95
50
W W
0
95
e r'
— J'--*
O
99
82
96
O

ww
,3,,^,
•—•*•<•
100
o
c .j
o
0
o
95
/ '•i
W A-
76
O
45
100
0
ll 1
nX
w*.
97
0
O
0
0
0
0
0
-T5
99
0


-1
^
-2
2
0
1
2
__. i
0
_ -1
-1
-77
w f
0
— •""?
	 •"> /I

0
0
1
. 1
0




0
0
"7
0
o
o
2
•""X"1!
•*- •*
1
O
o
-1
0
1 "*"

0
o
o
0
0
0
0
0

1
0
Data
Date:
394903
2418048
3056432
121'?696
3454636
4G744S4
1968560
568848
0_
iO ( 1 S"7i O *-- "

63O32
-*-r-^/i-->o
0
292228
T-rrS ,'
WW X W
0
4184640
187589
8706852
0
_-,™-- - «*,
•<- ' xJJ,«<-


9400863
0
*T "7Of~)f~i£~i
O
0
o
128066O
£_ r\ A f^j ~r s tr
•-' ^ fL/Od'-.a1
61O4
O
35696
1357433O
O
n 'LA
'-> 'i*~,~r s> A

22680O
0
0
0
0
o
0
0
4 ~i'?71 P>
3225572
0
RevJewii)
/ „ -^ —
bo
bo
bv
bv
bv
tav
vv
VV

Tf4-f3.(e&

bv
A- S (c^lo

bb
i~ t^


bv
vb
bv





vv

V1'



bv
b^ ,
'
A

Db
bv

hl~
t^&
vb








bv

A
•u
4 ,
5 ,
9,
S ,
5.
7.
12 .
O«
0-
i

i.
-4_
0,
1.
^
4*. -
0.
2,
2.

0,
-_,
VJ M
^
•—* »
3.
O.
y|
O.
0.
o.
5,
-y
•w «
4.
O,
4.
5.
0.
•W1 H
W *
6.
O.
O.
o.
0.
o.
0.
0.
—.
7.
0.


50
67
80
11
1O
52
09
92
OO
j-*i '
•J-+,
41
A..,
OO
82
±/
•o
00
49
57
01
97
OO
-* ,



56
OO
i i
00
OO
00
30
i- -
Jf-^j
40
00
92
13
OO
TT
k-1 X
50
00
00
OO
00
OO
OO
00
T 1
61
OO


128
114
_17
6 Li
84
98
OO
ro
95
50
62
l-Ojf -yq
W ,r
94
1.63 64
1O6
101
96
142
76
43
'7 A
/ O
84
96
73
53
57
63
4?
*•+ ^.
96
83
62
57
43
72
97
117
78
130
55
69
83
75
75
97
129
107
173
4X
<-4 ^
92
164


Srornochioronnatrane
1. 4-0 if 1 uorober^ene
Chlorotaenzene-cS
1, 2-Oichloroet!-iane-d4
Benzene-d6
Toluene --dO ^f^\^\
4-Bromof 1 uorobonzene
Chloromethane
Vinyl Chloride ^
1 , 3-8 u rad £ e ne CSJTljJ
Br ornomethane .
ChloroethancfJ^^T? )
Vinyl bromide
Tr ichlorof luoromethan
l,l-0lchloroethene(^i
lodomethane
Carbon disulfide
Acetone /~\/\\
£ll 1 v/1 r-hl r\r- i Ho/vWiV'"'^
Hiiyj. c n i or i Qetj^\¥
Methylene chloride













<5
T^




trans-1 ,2-OIchloroethene
tert-Butyl methyl ether
Acrylonitri le/^^ftO
n-Hexane ^~^
1 ,, 1-Dl c hi o roe thane
1O— "P-'r^n vx/l^ i if~^i n («> &*Zsy *^fO i




9 ju i--.^ w /** y i*/ \ji w d i ic f'&T' Jl L»i™—^
cis-l,2-Dichloroethene
Chloroform
1, 2-Dlchloroe thane
Isooctane -x
Vinyl acetate ^^Tb-'
2-Butanone
1,1, 1-Trichlo roe thane
Carbon tetrachloride
Benzene
Trichloroethene
Ethyl acrylate $3?
Methyl methacrylate
BromodI chloromethane









"O


cis— 1,3-Oichloropropene
trans-1, 3-Dichloropropen
1,1, 2-Tr ichloroethane
Dlbromochlorome thane
Ethylene dlbromide
Bromof orm
ji^-Mc^^H^/l — ^"-r^^an^iarir^oca/^
Toluene
Tetrachloroethene






9V«I
JsiU



                                                                       148
-------
"lo.  MAT FOR REV Delta
   Area P.Flagc
    RT     QM Name
 52  57  22  73     1
 53 100  87  98     1
 54 1OO  87  94     O
 55  99  76  82     1
 56 100  93  98     1
 .5^	02—,—5  46	6-
  8869:2 bb
 311832 bv
 953364 vv
 334496 bv
2946956 bv
 58  66  36  72
 126173 bv
—8-;. 75     43 2-Hexanone
  9.85    112 Chlorobenzene
 10.14    106 Ethylbenzene
 10.. 37    1O6 m-/p-Xylene
 11.OS    1O6 o-Xylene
 11.13    1O4 Styrene
 12.50     S3 1,1,2,2-Tetrachloroe/^SWj
 11.86    105 Cumene              ^~/
                                                                         149
-------
                                                                                       o
                                                                                       in
87-88-y?  23:0/         Triangle Laboratories of RIP,  Inc.

Sanple: WST-1 SEI 4 TUBWB   T/IC   173-46-4A/B  TL1142284
(919) 544-5729

  Instrument II
IK354 92 C8.92e>
180-j "'
j 44
XFS-
e.^-Jiitii!
8

52
j 64
- - ' " ' * - i - * ' - I ' • " ' '| " • * ' 4 I l '
a/z t»a 108 158
(8.921)
ieei 5
XFS -
< 49
0 ,11!
8
53

M/Z 58 108 ' 150
9 (0.938) Chloronethane
lee! 5
XFS -
44
M/Z 5
0
52

8 10S 150

106496



209 258 3B3 350

95232


200 250 300 350
FIND
100


200 250 300 350
-------
88-Ju 1-97 23:87         Triangle Laboratories of RIP, Inc.
Sanple: MOST-1 SET 4 TUBEA/B  T/TC  173-46-4A/B  TLI842284
(919) 544-5729
  Instrument H
HS354 108 (1.888)
3.9 144384

XFS-

0-



•
r
50
\
ii ,
M/Z 51
4


I.L .1. t , , 4
) ' 100 ' 150 ' 200 ' 250 ' 300 ' 350
HS354'108 (1.081) REFINE
1001

XFS

_
c
39



50
\
.1
w/z 5t
»4 113664



i
1 100 ' 150 ' 200 ' 250 ' 300 ' 350
MASTER 11 (1.440) 1,3-Butadiene FIND
100
XFS

0
3



9
•%,
50
N

100
4



n/z 50 ' 100 ' 150 ' 200 ' 250 ' 300 ' 350
-------
                                                                                       in
B7-88-97  23:07         Triangle Laboratories of RfPj Inc.
Sanple: WST-1 SET 4 TUBEA/B  T/TC  173-4&-4A/B  TLIt42284
(919) 544-5729
  Instrunent H
HS354 141 (1,410)
100-
X.FS-

8-
H/Z
44 29696
94
93
7I ':


58 108 15B 200 250 300 350
HS354-141 (1.411) REFINE
180
'/.FS-
0-
M/Z
9
93
4 10752

58 103 150 200 250 300 350
12 (1.428) Bromumethaiie FIND
108-
>',FS -
0
M/Z
9.
93
46 n . %
48 / 8,1 tj
4 100


5B 180 150 200 250 388 358
-------
                                                                                      en
                                                                                      in
  -Jul-97 23^07         Triangle Laboratories of RTF, Inc.
Sanple:  UOST-1 SET 4 TUBEA/B  T/TC  173-46-4A/B  TLW42284
(919) 544-5729
  Instrument H
HS354 153 (1.530)
100
X.FS
8-
M/Z
A

Jl
L4
5
, .„!.
' • i
50
26112
5
70
' 100 ' 150 ' 280 ' 250 ' 300 ' 350
HS354'153 (1.531) REFINE
108
XFS-
8-
M/Z

,7
50
6

4 1680
66
100 ' 150 ' 200 ' 250 ' 300 ' 350
MASTER 13 (2.020) Chloroethane FIND
108-
XFS
8-
M/2

T
50
6

4 100
66
100 ' 150 ' 200 ' 250 ' 300 - 3g0
-------
                   in
87-88-97  23:87         Triangle Laboratories of RTF, Inc.
     e: W3T-1 SET 4 TUBEA/B   f/TC   173-46-4A/B  TLIf42284
(919)  544-5729
  Instrument H
H8354 182 (1.828)
100-
t
0-
H/Z
16
42
, 55
|| 70
ii 37120
103

105
50 ' 100 ' 150 ' 200 250 ' 300 ' 350
HS354'182 (1.821)
100 -•
>:FS -
0-
w/'z
11

€7 t,6 3o
, !.. J.i 8#
)1 34304
103

105
\ 119
5B 188 15B 260 250 300 350
MT2CAA 15 (1,8483 Trichlornf luoronethane FIND
100-
HFS-
e
H/Z-
1C

?V 6f 82
11 100
103

105
117
50 ie@ 158 200 250 300 350
-------
                                                                                       in
                                                                                       ID
§7-88-97 23:07          Triangle Laboratories of RfP, Inc.
Sample:  UOST-1 SET 4 TUBEA/B  T/TC  173-4&-4A/B  TLIM2284
(919) 544-5729
  Instrument H
249 (2,498)
IBB-i 7
XFS-
44
0^45.3.47
6

78
s/z 5@ ' 100 ' 158 ' 288
HS3S4'249 (2.491) REFINE
7
44- A-
6
78
H/Z 58 180 158 200
HT2CAA 18 (2.588) Carbon disulf ide
108i f"
44
0 ' ' ' -• i
6
78
/*
M/Z 58 ' 100 ' 158 ' 288

774144


258 380 358

761856

258 308 350
FIND
100

250 300 350
-------
                                                                                      CO
87-88-97
          23:07
Triangle Laboratories of RTF, Inc.
Sample: WST-1 SET 4 IUBEA/B  T/TC   173-4&-4A/B  TLIM2284
                        (919) 544-5729
                          Instrument H
HS354 257 (2.57B)
     A -3
1601
                                                                           18688
XFS1
         5.8
       57
M/-Z
                  100
      158
200
253
300
350
HS354*257  (2.571)  REFINE
iee- 43
                                                                           12288
  0
M/S
                              15B
                                         380
                                   358
       19  (2.578)  Acetone

1B01
                                                                            FIND
                                                                             130
XFS-
  0
        ,3,8
                              ise
                                          203
                              250
                        388
                       358
-------
                                                                                     in
87-88-97  23:07          Triangle  Laboratories of RTP,  Inc.
Sanple: WST-1 SET  4          f/IC   173-46-4A/B  TLW42284
(919) 544-5729
  Instrument H
29? (2.970)
49 2359296
100-

XFS -
0



fi
-i 1!


84
51
55
..[,,. «,..„„„!» , j,

88

H/Z 50 188 150 208 258 380 358
H8354'297 (2.971) REFINE
100 :

y;FS-


a
4


47
\
_ j I
9 2318144
84
51
/
55
../ 	 78


88
/
H/Z 58 ' 100 ' 158 ' 288 ' 258 ' 388 ' 350
HT2CAA 21 (2.978) Hethylene chloride FIND
49 188
1001

XFS-


6-



47

.4,1 1

8'
51

83
V
4


88
.1
»/z 5i 180 ' 158 ' 200 ' 250 ' 380 ' 358
-------
                                                                                     QQ
                                                                                     in
87-88-97  23:87         Iriangle Laboratories of RTP, Inc.
Sanple: WST-1 SET 4 TUBEA/B  T/TC  173-4&-4A/B  TL1M2284
(919) 544 5729
  Instrunent H
HS354 356 (3.560)
180-


X.FS -


a
5
41




.
56

•JCJ
3\
	 _
h^*^ -,- T ^
7 1245184




/ 71 8,6
«.J tr . .1
, lfn.|«I»|«« Y1'1"! '"M«l •"» 	 "[ 	 	 " '1 "I" 	 !'"»» 	 1" 	 I— ^— -1 	 f 	 | 1 	 • "' 	 t 	 | • 	 '" • 	 '' 	 '1 " ' *-- W-----| t 1 1 . 	 1 . V^rn^ p-, prr Vnn 	 .n,,™^ . T_-.. , I ( , ^ - I ,
M/Z 58 169 158 206 258 388 356
H8354*356 (3.561) REFINE
169i

"ks-

5
41

|
56
55
7 1146888


**?*. 8l&
—_ , , j , ^— ,-^ j 	 . ,_ 	 , , , 	 . 	 , , 	 j 	 , 	 , 	 , 	 : 	 1 	 , 	 , 	 , 	 , 	 j 	 , 	 , 	 , 	 , 	 j 	 , 	 , 	 , 	 , 	 j 	 . 	 , 	 , 	 , 	 j 	 , 	 , 	 , 	 j -,-^--, j -.- - , r- 	 j . , ,- , (
^/?s S6 1©Q 150 203 250 380 356
HTZCftH 2S (3,570) n-Hexane FIND
IBE-i



X.FS-


0-
5
43
i






56

55
'••
!, ....
7 100




B6
71 [

M/E 50 ' 108 ' 158 ' 200 ' 258 ' 388 ' 350
-------
07-08-97  23:07         Triangle Laboratories of  RIP,  Inc.
Sample: WDSf-1 SET 4 TUBEA/B  T/TC   173-46-4A/B   TLIft42284
(919) 544-5729
  Instru.neint H
HS354 53B (5,301)
IN-
0-
«/ s
5
jl, ^
7 1198O8
5878
50 100 158 280 258 308 358
HS354'538 (5.381) REFINE
1001
XFS -
0-
H/Z
5
56
|.i
? 84992

9,9
50 180 158 260 258 388 358
NT2CAA 31 (5.291) Isooctane FIND
188
XFS-
B
M/Z
5

4155
Jj >,
? 108

58
' . _ 99
50 100 158 200 250 300 350
-------
                                                                                      o
                                                                                      CO
87-88-97  23:0?         Triangle Laboratories of IIP, Inc.
Sample: WST-1 SET 4 IUBEA/B  I/fC  173-46-4A/B  ILIf42234
(919) 544 5729
  Instrument H
HS354 448
190] 43
XFS-
' . 55
, |i |»
H/Z 58
HS354r44M
lae-j 43
XFS '
0- _iL_

H/Z 58
33
100-1 43
XFS-

57
0 .UA-.t.-,.L
K/E 59
(4.488)




100 ise
(4.4B1) HEFIHE


T

ieo 158
C4.38§) 2-Butanone


72

1
* • i - - - - i - • • • i •• 	 • i • •
180 150

5312



280 253 300 358

4224



280 256 30B 350
FIND
180





280 250 380 350
-------
                                                                                       CD
87-88-97  23:87          Triangle Laboratories of RIP, Inc.
Sample: UOST-i SET 4 TUBEA/B  T/TC  173-46-4A/B  TLI&42284
(919) 544-5729
  Instrument H
492 (4.921)
188-
XFS-
0-
H/Z
41
5
55
, i'
21504
6

69 8 if5 117
, ,iJa..,Ll 9.^. 11,
50 168 158 280 258 388 358
H8354M92 (4.921) REFINE
ie@-
XFS-
0
M/Z
5

Pf?.,
6 11776
117
fBl^ 96 |/21
58 108 158 200 250 388 358
HT2CAA 35 (4.911) Carbon tetrachloride FIND
IBB:
%FS-
8-
M/Z
117 100
121
Y* 8ii >3
58 l©e ' 158 ' 280 ' 258 ' 308 ' 350
-------
                                                                                      CVJ
                                                                                      CO
87-88-17  23:0?         triangle Laboratories of BfP, Inc.
Sample: WST-i SET 4 TUBEA/B  T/TC  173H&-WB  TLIf42284
(919) 544-5729
  Instrument H
H83S4 513
108-
XFS-
0

51
'UV1. .rJ|t-^
56
118354*513
100-
XFS-
0

51
5B
MT2CAR 3b
IBS-;
XFS '
0-


,.T
se
(5.131)
?
7?
\
65
8 1933312
84
109 158 20O 258 300 350
(5.131) REFINE
7
77
74
g 1835088
79
i
' 188 ' ^Q ' 2&9 ' 250 ' 300 ' 350
(5.131) Benzene FIND
V
77
6.3 _,,
e 100

i
168 150 280 258 300 350
-------
                                                                                     cr>
                                                                                     CD
0/88-97  23:07         Triangle Laboratories of IIP,  Inc.
Sanple: UOST-1 SET 4 fUBEA/B  T/TC  173-46-4A/B  TLI842284
(919) 544-5729
  Instrument H
658 (6.581)
188

XFS-
0-
H/Z
4


tl 45824
69
!„ ,lJaJ ^ja
50
• • •''•! i- '(• i -- -j
108 158 208 250 308 358
HS354'65B (6.501) REFINE
lee-

XFS
e
w/z
4


ai
1 38144
69

42 5f

70 ISO
;:' .82 ii.
5i 160 150 208 250 380 350
4B (6.491) Methyl nethacrylate FIND
100

XFS-
0-
H/S
4



1 100
69

42 g9

;08? 1fe
58 160 150 200 250 300 358
-------
                                                                                     CD
87-08-97  23:87         Triangle Laboratories of RTF, Inc.
Sample; WSI-1 SIT 4 TUBEA/B  I/TC  173-46-4A/B  TLI»4ZZ84
(919) 544-R7Z9
  Instrument H
761
lee-

XFS-
0
M/Z



39
7 ?
5H
HS354' 761
1001

e-
M/S


39
' ¥
... r . i. j..
56
fHffCAA 49
10@1

XFS-
•
•
0-
M/Z

39
'"' 5jl
58
(7.&11)
9


65 89
1
92

93
100 150
C7.&11) REF1HI
9

65 89
,4 .,,.,. ,.,,.J
1
92
93
180 158
(7.681) Toluene
91

65 89
J. . ,.";,
92
53
100 150

737288



2O0 256 300 353

671744


208 250 388 353
FIND
108


200 250 300 350
-------
                                                                                       in
                                                                                       CD
07-88-97  23:07         Triangle Laboratories of RTF, Inc.
Sanple: MOST-1 SET 4 TUBEA/B  T/IC  173-46-WB  TLIM2284
(919) 544-5729
  Instrument H
985 (9.851)
189!

XFS-
0-
M/Z
8
54
40 ?5 7*
.,(, I., f..l 1 JJI,..-,...,,. Ulll,|l
58
117 134144
2
llf
83 113^
100 150 200 250 300 350
HS354'905 (9.851) REFINE
180-
>:FS -
0-
**/3
58
77

37
f t
• ' ! ' ' J • I '
58
I:

93
2 9856
114
1
108 15i 200 250 300 358
52 C9.841) Chlorotenzene FIND
ieQ

XFS-
0-
H/a
77

51 74
• • f • • ' • -1 •
se
1;



^2 100

114

lee 150 200 250 300 350
-------
                                                                                   CO
                                                                                   CO
67-08-97  23:07         Triangle Laboratories of KTP, Inc.
Sample: MQST-1 KE1 4 TUBEA/B  T/TC  173-46-4A/B  ILW42284
(919)  544-5729
  Instrument H
HS354 1B14 (18.141)
1801 9
%FS-
51 65 77
e ..!.(.. .ft,.;,, .i.j_,. ...III........
1
106
i.. 	 J 	
*/z 59 100 150 280
HS354'1B14 (18.141) REFINE
180 9
>:FS
B ^ SfS-
1
106
I
H/Z 50 168 150 280
53 (18.131
188I 9
51 65 77
g ..lr . i, -4 , TH. .,
) Ethyl benzene
l
18fe
(107
i J;'
M/Z 5B ' 180 ' 150 ' 200

119808


250 300 350

1O2400


250 300 350
FIND
160

250 300 350
-------
                                                                                       CD
07-66-97  23:07         Triangle Laboratories  of  KIP,  Inc.
Sample: UGST-1 SET 4 TUBEA/B  T/TC  173-46-4A/B  TL1M2284
(919) 544-5729
  InstniPieiit H
1B37 (18.371)
108
'XFS
8
H/Z
9
39
51 £ 5 77
1 230408
186
92 he?
1 	 IJIi —
59 100 150 200 250 388 350
US354J1B37 (18.371) REFINE
iee
w*-
8-
M/Z
9

39
51 f^ 77
	 J,. ..S? ..,.!,,..,_.
1 198656
186
?2 187
i . . .1 £. .
' • ! • • ' • 1 	 "" "• '1 . l I | i , i l | ». l . J I ...;.... | ,. - . | ....,..•.].... | . . • . |
56 160 150 200 250 388 350
NT2CAA 54 (10.371) n~/p-Xylene FIND
iee-
XFS-
e
H/Z
9

39 cq
M 77
1 188
136
92
i .1 1. .
50 100 158 200 250 308 358
-------
                                                                                     oo
                                                                                     CO
87-08-97  23:07         Triangle Laboratories of RIP, Inn.
Sarnie: UOST-1 SET 4 TUBEA/B  I/TC  173-46-4A/B  TLIH42284
(919) 544-5729
  Instrument H
HS354 1188 (11.881)
180-
HFS-

0
st/z
104 185472
Q i
¥ ?S
1 i,r 7Q
1 G'-l "
.1^1. . ll.|,, ll.|a.v.l|i j,..^- .
186-
92
/*
i. 	 i ....
53 163 150 200 258 308 353
HS354'1108 (11.881) REFIHE
100-
XFS -
e-
M/Z
9


1 68608
186
92 187
i K
58 168 158 209 258 388 358
55 (11.871) o-Xylene FIND
188-
XFS-
0
M/'Z
9
39 51
i"i i €'5 77<
1 180
92 |i07
50 188 150 208 258 300 350
-------
                                                                                     CD
07-08-97  23:87          Triangle Laboratories of  RIP,  Inc.
Sanple: WST-1 SEf  4  TUBEA/B  f/TC   173-46-4A/B  TLI»42284
(919) 544-5729
  Instrument H
1113
100

XFS-

0-




51

.1 -

1
i ,*

M/Z 58
1113
180-

XFS-



6






(11.131)
n
103
7
76
3 i
8

91
! 	 1 	

34 34816O


105

1 , . ) .... . ........... I , . t .... 4 . t J ...-,....,....,
189 150 288 258 308 350
(11.131) REFINE
11
103
78
51


,1 	


63
	 ,
M/Z 50
	 Biiii

102
Cfc f\
89 i
»... .IK--' .... .1
14 3072O0



IBS

i ..
180 150 208 258 300 350
56 (11.121) Styrene FIND
1801

XFS-

0-



5
,1




1
lts
103

7
76
63 \

M/S 50
B 102
,89 _j

14 100


185

i — , — ,; 	 , — . 	 ,_— , 	 , 	 , — —— , — , 	 +— , 	 	 — , 	 , — . 	 , — . 	 , — , 	 , — , 	 	 — , 	 , — ._ T _ — , 	 , — r— » — i -* — i .- -*••• 	 i : i — r— i — i r—T 	 	 - i
180 150 288 258 308 358
-------
                                                                                      o
                                                                                      IN.
07-08-97  23:07         Triangle  Laboratories of  RIP,  Inc.

Sample: WS1-1 SET 4 TUBEA/B   I/TC   173-46-4A/B  TLI842284
(919) 544-5729

  Instrunent H
HS354
168i

XFS-
P-

4

I
H/Z
1186 (11.861)

i

M

57

,

69 •;
50
11


J,l, ,
15 18944


128
iih Li
188 150 288 258 380 358
HS354'1186 (11.861) REFIME
lee-
XFS -
0-


H
tt/Z


l5


5
11

, „ \ 7i9 , 9JL ^
59
NT2CAA 58 (11.
IBB-
XFS-






0,
M/Z



5
*
5



1 6.3 ?!
I
e
35 8256

128
i ,* LE t
188 158 283 258 3B8 358
851) Cuwene FIND
1C

183
7
I i
35 108

128
, [
188 158 288 258 388 358
-------
BB-Jul-97 23:07         Triangle Laboratories of RTF, Inc.
Sample: UOST-1 SET 4 TUBEA/B  T/TC  173-46-4A/B  TLIU42284
(919)  544-5729
  Instrument H
HS354 72
100
XFS- 44
Q:JK^.
(0.720)
60 3014656
J 	 .... ... 	
M/Z 50 ' 100 ' 150 ' 200 ' 250 ' 300 ' 350
HS354' 72
1001
XFSJ
0 '
(8.721) REFINE
6
3V*/43
... 1 1 1 1 1 1 . . .
ttl F:644 2898:PENTANOIC ACID, 3-METH
1001 6
XFS 3?41,?3 «J6
0i .v r i . . . . ^ 1 1 . .
«2 F:5
100-
XFS
0 t , j
15 751:BUTANOIC ACID
6
*?*? *\r&
*3 F:489 1538:BUTANOIC ACID, 3-METHY
1001 39 41 6
XFSJ 2627 ?9 38 | ' 14,5 555,6
01 ,1.518 \ ,131 \l ,H >.!i
M/Z 10
NBS 258 Hits : 258 Searched
0 2916352
ft2, , , 85, , , ,
VL-
0 255
61
L , ,,, M8-7. . i
1 1 .., i ...... i 1 1 ........ i I . i . i ,....,.. i . I ................. i .,
0 255
61 7|3
L-
0 255
P- t"W 8,7
i • • • • i • • • • i • • • • i • • • • i • • • • i • • • • i • • • • i • • • • i 	 ,,...,....,....,....,.... , . ... i .... i ......... , ....,....,
20 30 40 50 68 70 88 98 180 110 120
-------
               CVJ
               r-
            23*07         Triangle Laboratories  of  IIP,  Inc.
Sample: UGST-1 SET 4  TUBEA/B   T/TC   173-46-4A/B  TLIH42284
(919) 544-5729
 Instrument: H
ibZ (1
188] *
xrsj 3!>
o J ..Li
.628)
.3
1 .=.,
«T
" j *"!•**
1 	 1;} 	 2f-
H/Z ' 50 ' 100 ' 158 ' 208
•= fsrs-~!;s — : .a ? Jt f -*~t /" a
Mi 3 :_rt lb£ ( i
saai ^
^FS 39J
g J .,'j
MI F:841 8
1801 41-
i ^H
v.FSj J\
e^ , I,
»?. F:747 1
189i 4
^FSJ 27 29
fl ^ , ^JlL J
13 F:734 6
liisi 4
XFS-] 39 ,
nl "l
621)
3
57
j **3J ^j,
A f i£
QgrHVDROKV'LftHINE, Q-C2-METH¥LFRQP¥L>-
3
44|"|58 J"1
il..J<' ./r?2 .
429:PENTANE, 2, 4-DIHETHYL-
3
57
55J58 85
1 i • • • • !'• •' ' • ! 	 • 	 ' 	 -• !"' 	 '•''•--• | "' ' 	 ' ' 'i '• • » i | « i «
531: HEPTANE, 4-ftSIDO-
3
5?
44 / 7fl
/ J 'I® 64 98 .
H'S 58 106 150 208
NBS
104O384
250 360 338
NBS 242 Hits : 242 Searched
^50272
. | i . - . ^ - - . • | . . . J | i , . , j i , < , ^
C4H110M 255
255
C7H16
• 	 § •• ' "•• • i • •• ' 	 • 	 f •• • • ' i" ' • "• 	 t • • • - i
255
C7H15N3
25© 3GS 359
-------
                                                                                        CO
                                                                                        IN.
08-Ju1-97 23:87          Triangle Laboratories of RTF, Inc.
Sample: UOST-1 SET  4  TUBEA/B  T/TC  173-46-4A/B  TLIU42284
                                                                   (919) S44-S729
                                                                     Instrument H
HS354  216 (2.168)
              81
100
X.FS
  0
        61
      45   \67
                                                                           254976
M/Z   50
                  108
                               150
                                          200
        250
        300
       350
HS354'216  (2.161)   REFINE
180
  0-
                    33L
                          4547
                           1 .
                                                     NBS  127 Hits  :  127  Searched
                                                8.1                        241664
                                                  83
                            . 
-------
08-Ju1-97 23:07         Triangle Laboratories of RfP, Inc.
Sample: UOSf-1 SEf 4 IUBEA/B  I/TC  173-46-4A/B  TL1*42284
(919) 544-5729
  Instrument H
HS3!
100
XFS-
8-
'A 102 (1.028)
43 434176
1 5i6
..I i L .... J.i 	
M/^Z 58 ' 188 ' 158 • 20e , 2^0 , 3^0 .... 3g^
HS35
100
X.FS
0,
ttl
100
X.FS
0.
4»2
100
XFS
0.
tt3
100
XFS
8-
i4'lB2 (1.021) REFINE
41
37 39
>,,li 1
F:?38 OagiHYDROXVLflMINE
3i'ji
FJ724 552:i-PENTEHE, 4-
4
2i7'8 T]|
F:704 1G42: HVDROXYLfiMIN
4
41
3?\
NBS 58 Hits : 58 Searched
441368
44 56 58
f', ,5,1 |,|,,
, O-C2-HETHVLPROPVD-
r43 255
44 555,6 58 ?0 71
W ,-5^ n, .m?s
1 | 1 I ,, | I .11 1 1 1 1 | ........ 1 | 1 1 1 1 | ......... , ... T ( ,..,,...,,.,..,..,.
METHVL-
3 255
/4 MI?3 | 	 |((ffl 	 ,,,«,«,
E, 0-O-HElHVLBUfVD-
3 255
44 55X 56 78 J1
53X/. M.
M/Z18 ' 28 ' 38 ' 48 ' 58 ' 60 ' 78 ' 88 ' 98 ' 188 '
-------
                                                                                     in
                                                                                     f-
Ff/'-TlR/y/    23:S7        IFiangle Laboratories of RTPj  Inc.
Sarnie;         SET 4          T/TC  173-46-4A/B
(919) 544-5729
           : H
l!S35i 193 (1,939)
.5 ,.,,, 43
jLwiJI
vrc-j 3? ,
	 j '-;!
I3 ' -«r


, 5,? 7?
K/Z ' 58 ' 180 ' 15S ' 28Q
HS354'"I93 (1,931) REFINE

I MM-. 42-
3< i.l

57... 7.2
. | . ... i ,,.,,.,,,..,.... j .... , ...... | ..
ttl F:726 1298:ftC£Tie flCID, 2-PRGPEWL ESTER
1 Q£J- 4
KFS- 39
n -- - , -- f '- V
3
44 57
f, ,-»! !
#2 Ft 734 €531: HEPTANE, 4-AZ1DO-
4:1
iS%-"4
''' ff ""* "j " -
** i i
57
44 •' 70
y j i 84 98
=3 - , ..,...., ..,,..- ( .... ; .... 5 , . , , j , , ,
f-J inviY S09 ni'iBSOXi'LAMIHE. O-C2-tfETH¥LP10?¥L)-
. a ^ 43
"""_" r?4] .55 71

44|i 58 /^
H.-'Z 53 168 150 208





25e see
NB8 83 Hits : 83 S





C5H802


•""I ''"' • • i • ' • • r • •- • - i • • •

C7H15N3


• 4 • i • - i ... , .,,.,-, T .


C4H110H

25fl 38©
HBS
229376



1 ' " ' * 1
356
earched
214016




255


1 '
SS5


^™.r^ 	 r--, 	 ,-».

255


1 i ' ' • - i
358
-------
                                                                                       CD
08-Ju1-97 23:87          Triangle Laboratories of RTF,  Inc.
Sample: MOST-1 SEI 4 IUBEA/B  T/IC  173-46-4A/B  IL1*42284
(919) 544-5729
  Instrument H
HS354 85 (0.858)
1801 43
44
y.FS ,/
0:J,lr.rr,T.. ri.
n/z 58 ' 100 ' 158 ' 200 ' 250
HS354'85 (0.851) REFII
1801 41 4
XFS^ 38 Y
o: V "I
#1 F:818 97:PR0PftNE,
1001 424
XFS^ n9* 3\,1
0 (J4J| 4 -tf|'| -^ 1 '« 'l M
#2 FI726 1298:ftCETI(
188-j 4
X.FS 39
0 2? >,'.
tt3 F:686 452i:ISOXfti
^i « T
XFSl \ 1
0« M
HE NBS 115
3
, -,-?-?- , ,
2-HETHVL-
3
44
/ ,,,.,.,. ^.7.,
; ACID, 2-PROPENYL ESTER
3
44 57 58
/ > f r61
JOLIDINE, 4-ETHVL-2f5-DIMETHyL-J 'CIS~
^43
'«53x5,5 'l0
W I • • • • 1 • * • • i • " • - I • • I • T "• •'-' I • • • • 1 • • • ' 1 * • • • 1 • • • • 1 • • • •
H/Z 20 40 60 80 180
364544
308 ' 350
Hits : 115 Searched
352256
1 * * * * I "'"1 .--I.
255
|,JIIW|--.-j ,,,|l
255
255
129
120 140
-------
                                                                                  r-
                                                                                  r-
Hy/a8/9/    23;«7         Triangle Laboratories of IIP,  Inc.
Sanplc: yyST-1 SET 4 TUBEfVB   T/TC   173-4&-4A/B  ILIM2284
(919) 544-5729
 Instrument: H
11S3G4 071 (8.711)
1 j
XFS< „, 119 177 ,„.
ni 6? 9.6 153 .... . .. \_ 111
MBS
J67 481403
.rs/g g@ 1G3 159 288 250 386 356
HS3R4/871 (8.711) REFINE
f
*FS1 a. ii? 177 to.
q \ .. . 9& '-: l.^-> 	 ':-. Af.7
NBS 24 Hits : 24 Searched
!«? 217688
•"Tt JTfeQ
aalEFO
IL
it!. F;827 22491 JCVCLOTRISILOXAME, HEXAHETHVL-
IBBJ 2|7 C6H1803Si3 255
xrs-1 iee
q^ 1.5 . . . ¥ 113133 .. . 17.7i?l If .
«2 F;736 38155 : ARSEHOUs ACID, TRIStTRIRETHVL;
-- G3-, 2
a 5 4.4 "3 IBS 1^3 191
*TJ i-;lsI4 22620 :i,2-BISCTRIFIETH¥LSIl,VL)EEHSEH]
. o.-m, 1?1 2
•A. T,t5 j
-,i;-5j sg 4^ 'J?d 88 131
o\ M .3,9 . (Si t<. . 1B5U9 jj.l45i ESTER
'O? ._^._ , .255
263
r2S9
j
.87 255
268 C12H22S12
w/z ' 5Q ' 10Q ' 158 ' 209 ' 250 ' 306 ' 358
-------
                                                                           00
       §7         Triangle  Laboratories of  RTF,  Inc.
MOST-I SET 4  TUBEA/B   T/TC  173-4&-4A/B  TLW42284
(919) 544-5729
 I mstruneiit '•  H
lHS-3b4 TL 1
199-
»_*TTJP- J
H/Z
!ii354'41
1H0;
XFS-;
tti F;8-
ise-j
XFS •]
M : - i . *

ff'3 F I *5~-
=/r^J
#3 F:8;
188;
M/Z
IT
4155
?) NBS
6 175184
69
	 j. .84
58 106 158 250 300 350
2 (4.12J
5
4155
I 'l ' Tr-
€0 4261
42 ^
37 , f43!
*~ -^e er ET A =
3-Li ^?D J8 r
5
41
OO /__-
*-" -T j I> 5 -*
36
5
3C .."'" « n.
<_ -43
, .1 1 1 ,....
L) REFINE .NBS &1 Hits : 61 Searched
6 153688
69
. .,..!. .8,4
: 2H~P"ii«AN-2-ONE, TETRAHVDRO-3, 6-]>IMETHVL-
5 C7H1202 255
n? 69
•'" / ^ . . .
CVCLOHEXftNE
6 255
64 C6H12
^Tk *? .- & 'T
V » / if J
j p5-./'
• •• | 1 '••(•••• | •-•••(•••- | •••• | •••• | -••-•[ ...... 1 4 | >t ... | 1 , 	 » 1 j
: 2H-P¥P.AN-ii-OHE, f EOflHi!DRO-5, 6-»!METH¥L- f TEflNS-
ft 255
5? C7H1202
58 ' 100 ' 158 ' 288 ' 258 ' 3©8 ' 358
-------
88-Jul-97 23:07         Triangle Laboratories of HIP,  Inc.
Sample: VOST-i SET 4 TUBEA/B  T/TC  173-46-4A/B  TLIH42284
(919)  544-5729
  Instrument  H
HS35
100
KFS-
0-
w/z
4 348 (3.488)
41 gs 121856
J57
50 100 150 200 250 300 350
HS354I348 (3.481) RE
1001 5
* 01 . 51
ttl
100-
XFS
0.
#2
100
XFS-
0
1001
M/Z
FI599 7875:2-PR
5
2.7 3.9 51
FI260 3461:IRIC
5
27 39
FINE NBS 22 Hits : 22 Searched
5 38288
6.7 85
OPENOIC flCID, PHENVL ESTER
5 255
76 /3 77 94 *f8
YCLO 4.2.0.02.4 OCTAN-5-ONE, (1. ALPHA. , 2 . BElfl . , 4. BETA. ,6fl)
5 255
56ft3|lf87179 9,4 121N123
/ !,IK l.ir?0 9JL.Ir95 106 \/
FJ177 11180 :BIC¥CLO 4.1.8 HEPTftHE, 7,7-DICHLORO-'
68 255
39 g«
2?2938 { d1 4ql 55 61 69737781858993 99 i?2|94
i/ Vir v,', <• 'J •"'' ^- v ( /•/. i /., m. IT
48 ' 66 ' 88 ' 188 ' 120 ' 140 ' 168
-------
                     o
                     00
88-Ju1-97 23:07         Triangle Laboratories of RTP,  Inc.
Sample: MOSf-1 SEI 4 TUBEA/B  T/TC  173-46-4A/B  TL1*42284
(919) 544-5729
  Instrument H
HS3E
100
XFS
0-
J4 557 (5.571)
T " 71
M/Z 58 ' 108
HS35
188
XFS
0.
100"
XFS-
0:
f»2
100
XFS
8:
#3
188
XFS
0.
185472
' 158 ' 288 ' 258 ' 300 ' 358
;4'55? (5.571) REFINE NBS 133 Hits : 133 Searched
4:3 93184
3,d*4 55Nf7 T;8 i*.
FI855 809:HVDROXVI
F:836 1642 ! HVDROXV
4
F:813 1428:HEXANE,
29
.AMINE, 0-(2-METHVLPROPVL)-
,43 255
¥ 5556 71
> 44 D\ 1 58 78 /*
,11 ^ ,,5,3, I {n ^ r??,
LANINE, 0-<3-HETHVLBUTVL>-
43 155
\ 44 ||X56 78xJ1
3-HETHVL-
43 255
41 44 555,6 \(
>!, / 	 > 1 	 II.. 8.5 . 180
-------
Project Number 42284
Sample File: HS355
                        Method 8240A VOST
Sample ID: VOST-2 SET 1TUBEA/B T/TC
Client Projecfc S487-003
TI3 ID; 173-46-6A>B~


Date
-.- • .— ---• > - »
>.
Dtfe
Received:
> '-' - - r

Analyzed
06/3«/97
. , , ;'- ,.

j Q7/Q8/97
Response FSiKlOkLHTGS
" '. , • f ~-~.-


. . " ' %

J" *„:, >-.-'


Analyte
; ? '1 ' • ', ' I
Bromochloromethane
Chloromethane
Vinyl Chloride
1,3- Butadiene
Bromomethane
Chloroethane
Vmyl bromide
Trichlorofluoromethanc
1,1-Dichloroethene
lodomethane
Carbon di.sulflde
Acetone
Allyl chloride
Methylcnc chloride
trans-1 ,2-Dichloroethene
tcrt-3utyl methyl ethcr
Acrylonitrilc
n-Hccane
1 , 1 -Dichloroethane
1 ,2-Epoxybutane
cis- 1 ,2- Dichloroethcnc
Chloroform
1,2-Dichloroe thane
Isooctane
1 ,4- Uifluoro benzene
Vinyl acetate
, •' .,/ Am««a*J
; -, d- ™ u'g; •:

0.217

0.112
0.022
0.009

0.074


0.419
0.059

1.264



0.814





0.038


;;HAC
f /'<\ '
ISl

U

}
}
U

U
U

B
U
BE
U
U
U

U
U
U
U
U
]
IS 2
U
' 'RT ' . •
- ;.',, ; •
4.51
0.93

1.06
1.43
1.80

1.84


2.51
2.58

2.98



3.57





5.30
5.67

....DcfcUaiit
''- *&•' •


0.001



0.001

0.001
0.001


0.001

0.001
0.001
0.003

0.001
0.003
0.001
0.001
0.001


0.001
• •• :. Qtt*U. lamit •
/ .' ' *%. -

0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05

0.05
                         NA- Not Applicable; Det Limit Detection Limit; Quan. Limit Quantitation Limit
    IS: Internal Standard; U: Undetected; B: Prevent In Blank; ]: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • rax- (919) 544-5491
                                       Savar v3 5
                            Printed: Zl:47 07/25/1997
                                                                                                    131
-------
• :: ': P^cB^mnmeatal^mi.- -: 	 ;;: /: : ";*•:- : :
Project Number 42284
Sample File: HS355
Client Projecfc S4Q7-003
III ID: 17$46-6A,B -
Sample ID:
Date Received: 06/30/97
Date Analysed; 07/06/97 ,
Method 8240A VOST
VOST-2 SET 1 TUBEA/B T/TC
Response
Filet ICALH7QS


Analyte • ' ' .'" •./ *::.-^ '•'

2-Butanone
1 ,1 . 1-Trichloroe thane
Carbon tetrachloridc
Benzene
Trichloroethene
1 ,2-Dichloropropane
Ethyl acrylate
Methyl methacrylate
Bromodichloromethane
cis-1 ,3-Dichloropropene
trans-1 ,3-Dichloropropene
1 , 1 ,2-Trichloroethane
Dibromochloromethane
Ethylene dibromide
Bromoform
ChJorobenzenc-d
4-Methyl-2-pentanone
Toluene
Tetrachloroethene
2-Hexanone
Chlorobenzene
Ethylbenzene
m-/p-Xylenc
o-Xylene
Styrene
1 ,1 ,2,2-Tetrachloroethane
.i;. Amount-./ fiAG':::::.. "Rf: '-.'• :-
. ' • :. . °* x'' .»••• •V'-"-:'::/ - 'i /:=••.
0.016 ] 4.41
U
U
1.743 BE 5.14
U
U
U
0.087 6.50
U
U
U
U
U
U
U
IS 3 9-80
U
0.506 B 7.61
U
U
0.004 ] 9.85
0.104 10.14
0.147 10.37
0.080 11.08
0.281 11.13
U
': Defettedt>F !.:
tig.-.r:T-:'

0.001
0.001

0.001
0.001
0.001

0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001

0.001
0.001





0.00 1
•**•* ' %y^fflrt~ jwHtttv*
• v* • / ' *4KJ ' .'. \*
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.10
0.05
0.05
0.05
NA- Not Applicable; Oct. Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank;]: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
             Savar v3.5
Printed: 21:47 07/25/1997
                                                                                                                    182
-------
Project Number: 42284
Sample File: HS355
                                                                 Method 8240A VOST
                                          Sample ID: VOST-2 SET 1TUBEA/B T/TC


Cumene
                        0.006 J
                           11.85
0.05

1 ,2-DichloroethanG-d
Benzcne-d
6
Toluene-d
I!;S|lllMii^p3Hlllii
0.282
0.308
0.294

5.12
5.10
7.52

1
2
3

113
123
118
Reviewed by.
-7U3
Date
                         NA- Not Applicable; Det. Limit: Detection Limit; Quan. Limit: Qmnritatlon Limit
    IS: Internal Standard; U: Undetected! B: Present In Blank; J; Ettimated- Below Quanritation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fsuc (919) 544-5491
                                                                                  Savar v3.5
                                                                      Printed: 21:47 07/25/1997
-------
                                  Pacific Environmental Services
Project Number: 42284
Sample File:     HS355
Method 8240A
Sample ID:
VOST-2 SET 1 TUBEA/B T/TC
Client Project
TLIID:

S407-003


Dilution Factor:
Date Received:
Date Analyzed:
1.00
06/30/97
07/08/97

                             Tentatively Identified Compounds
1 Name
Unknown
Methylbutane Isomer
Sulfer Dioxide
C4H8 Isomer
C5H8 Isomer
Pentane
Methyl Propane Isomer
C7H16 Isomer
Tetrahydrodimethyl Pyranone Isomer
Hexamethylcydotrisiloxane
.RIV--
0.721
1.630
0.891
1.011
2.200
1.950
0.881
5.571
4.120
8.711
"""-"- Area
35993156
24938344
15086964
14169553
12617491
11730563
9653451
5770273
5525091
11788115
1SRT
4511
4511
4511
4511
4511
4.511
4511
4.511
4.511
9.811
IS Area
5465039
5465039
5465039
5465039
5465039
5465039
5465039
5465039
5465039
12259760
Amount.ua j
1.647
1.141
0.690
0.648
0.577
0537
0.442
0.264
0253
0240
Triangle Laboratories, Inc.
801 Capitoia Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 » Fax: (919) 544-5491
                      Printed:   10:26  07/25/97
-------
                                                                                       ID
                                                                                       oo
07-R8-97  23:53          Triangle Laboratories of RTF, Inc.
    ln: UQST-2 SET 1 TUBEfi/B  T/TC  173-46-6A/B  TLIH42284
(919) 544-5729
  Instrument H
HS355
iy0i

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ia£ i?


/
M
M
f





,
f\
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\\
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? V



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                                                                                    0)
                                                                                    or
                                                                                    o
                                                                                    u
                                                                                   Q
-------
WAN ' 08 '.  H335S


No. MAT FOR REV De'. t~.a
   LAG-BASE  QUAN
Area P.Flags
RT
QM Name
i
2
3
4
5
6
8
9
1O
11
12
13
14
15
16
17
18
19
20
21
22

25
26
28
29
30
31
T /-N
\*J J~
33
-, ^
35
36
37
TO
-Q
— ' ^
40
41
42
43
44
45
46
47
A ^

49
50
100
1OO
100
•46
98
1OO
100
59

100
90
32
0
92
0
0
100
71
0
100
0

100
0
C f
0
0
0
100
-y ~r
ww
90
-T .",
0
100
0
--1 /•
'Id

100
0
0
0
0
0
0
0
-y ,"\

100
0
39
88
93
16
79
88
1 1
86
47
^
60
50
39
0
54
0
0
80
45
0
84
0
T
98
0
0
0
0
70


72
i— ,
0
93
0
1 A
io
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86
0
0
0
O
0
0
0
-rs's

95
0
9S
96
97
59
BO
99
94
49
— ^
100
96
48
0
95
0
0
99
73
0
95
0

100
0
CT C
0
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0
93
y x^
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77
>* r*.
0
99
0

•3S 	
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95
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0
0
0
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99
0
0
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" Z
2
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1
°o
2
0

0
1
26
0
0
0
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1
0

0
0
0
0
0
1
*-*!(".
A-1— '
2

0
0
0
1 —r
rf

0
0
0
0
0
o
0
0


1
0
401552
248.1656
30896SO
12 195 2O
3539OS2
4125010
2038678
734OOO
w-^^J
1 r- 1 T •- c o

76316
19156
0
343544
0
0
4244972
123661
0
3999896
0

6114050
0
0
0
0
983916
Af~f\ r ft c-i-r
M t-i X — ' 1 f r
6496
*~^ "7O / A
0
21924080
0
A A**"
A -i -r r ^
T .A. W — '.*-
209160
0
0
0
0
0
0
0


4627468
0
bb
bb
bv
bv
bv
bv
vv
vv
i- 1-
j \ ** i *i ^

• i
bb
i i

bb


bv
vb

bv


vv




bv
h- *

A
uu

bv

A
A

bb









bv

4
5
9
5
5
7
1 ^
12
0

1 W
-L
i
i
0
i
0
0
2
2
0
2
0

3
0
O
0
0
5
—T
w
4
^
0
5
0
s
s
**-*
6
0
0
0
0
0
0
0
—r

7
0
.51
. 67
. SO
.12
.10
.52
.09
.93


* ~J *^
.43
.80
.00
.84
.00
.OO
.51
.58
.00
.98
.00

.57
.00
.OO
.00
.OO
.30
r- ~~y
m -~S t
.41
-7 ^
.00
.14
.OO
-*,-,
^ ,
" -*-1*-'
.50
.00
.00
.00
.00
.00
.00
.00


.61
.00
123
114
117
65
84
98
/-,<->
95
50
62
Lot*
| » V ^f .-r f^f

94
64
106
1O1
96
142
76
43
76
84
96
K:-T
•~S-*J
57
63
96
83
62
57
y| ~f
H O
72
OT
7 i
117
78
130
63
W-M?
69
83
75
75
97
129
107
173
43
92
164
13 r o m o c h '•. o r o m e t h a n e
1 , 4-Dif I uorobenzene
Chi o r o be n z e ne - d 5
.1. , 2-D i. chioroet!iane-ci4
Benzane-d6
Toluene-cl8 x--v\0
4-Bromof 1 uorobenzene
Chloromethane -\
Vinyl Chloride/^W-)
1 , 3— Butadien^^y^xP
Bromomethane
Chloroethane
Vinyl bromide
Trichlorof luorome thane
1 , 1-Dichloroethene
lodomethane
Carbon disulfide
Acetone
Allyl chloride
Methylene chloride
trans-l,2-Dichloroethene
tert~Butyl rnsdthyl ether
A^f^wl f~ini1t"r*T 1 £>/££Xi^O
M w l ^J.i«illj.l.l ^x vSI \i 7 \ »»^
n-Hexane
1,1-Dichloroethane
cis-1 , 2-Dichloroethena
Chloroform
1,2-Di chloroethane
Isooctane x—xiT}
Vinyl acetate(^/^^
2-Butanone r-
111 T r- "T f~* H 1 f^i r*- r^ o *t* hi a n di'YVn*
Carbon tetrachloride
Benzene
Trichloroethene
1,2 DichloropropaNn^pf)
Ethyl acrylate J(S^VW^
Methyl methacrylate
Bromodi chloromethane
cis-1, 3-D ichloropropene
trans-l,3-Dichloropropen
1, 1,2-Trichloroethane
Dibromochloromethane
Ethylene dibromide
Bromoform
4-Methyl-2-pentanone(r^J
Tol uene
Tetrachloroethene
                     Data Review:
                     Date:
                                                                       186
-------
No,  MAT FOR  REV Delta
                         Ar^a P
-.a«s
                    RT
                QM Name

52
53
54
[~ r-
™'O
56
w JP

45
100
10O
100
100
A.V--

15
91
36
81
92
r~
w

53
'99
O£
87
96

„
1
1
0
1
1
w

51
65"?
1155
605
3506
-1

360
024
324
448
764


bb
bv
vv
bV
bv
' *

o
10
1O
11
11

~» r-
.35
.14
. 37
.OS
,13 .
, — 'A

112
106
106
106
104


.:. rt«>.a HOI 1C-? (^VJ/1 »^
Chlorcbenzene
E thy Ibenzane
m~/p-Xyiene
o-Xylane
Styrers
,i,2,z Tetrachloroe C
53  69  38  75
149512  vv
                 11.85
               1O5 Cumene
                                 187
-------
                                                                                      oo
                                                                                      oo
J7-88-97  23:53          Triangle Laboratories of RTF, Inc.
Janple: U0ST-2 SET  1  IUBEA/B  T/IC  173-46-6A/B  TLIM2284
                                                                  (919) 544-5729
                                                                    Instrument H
      93 (0.93B)
         64

XFS
      48
                                                                          757760
       50
                 10e
            158
            238
            258
            308
                                                                            356
H8355'93 (8.931)   REFINE
      50
XFS-
  0
     49
        52
                                                                           71680
M/
      58
108
15B
200
250
                                                                 3B8
350
NT2CAA 9 C0.93B)   Chloronethane
      58
XFS-
  0 t. , (, l
-------
                                                                                        en
                                                                                        oo
08-Ju1-97 23:53          Triangle Laboratories of  RTF,  Inc.
Sample: UOST-2 SET  1  TUBEA/B   T/TC   173-4&-&A/B   TLI842284
(919) 544-5729
  Instrument H
HS355 109 (1.090)
1001

zFS-
0
M/Z
3



9 66560
5

, ,1
4

1 .
50 ' 100 ' 150 ' 200 ' 250 ' 380 ' 358
HS35V109 (1.091) REFINE
1001

XFS
0-
M/Z
5
53

4 45056


50 ' 100 ' 150 ' 208 ' 250 ' 300 ' 350
PIASTER 11 (1.440) 1,3-Butadiene FIND
100
XFS
8
M/Z
3


9
5
50
\
5G
100
4


1 ' 108 ' 150 ' 208 ' ' 25B , ^^ » ^
-------
                                                                                      o
                                                                                      CD
07-88-97  23:53
Sample: UQST-2 SET 1
   Triangle Laboratories of RIP, Inc.
TUBEA/B  T/TC  173-46-6A/B  TLI«42284
(919) 544-5729
  Instrunent H
143 (1.438)
180-
XFS '
8-
M/Z
44 27392
34
48 fid 93
Ij^s o -t
I ifi •
, . , t , l 1 1J. .1

59 180 158 200 25O 300 350
HS355M43 (1.431) REFINE
188-
XFS-
fl-
M/Z
9-
93
tl1 .1
i 12992


5B 10e ISO 200 250 308 358
12 (1.428) BroMonethane FIND
180-
XFS-
M/Z
9\
93
"'•
4)076 8i j
t 100


58 180 158 200 258 308 350
-------
870097  23:53         Triangle Laboratories of RfP,
Sample: WST-2 SET 1 TUBEA/B  T/TC  173-46-6A/B  TLI»42284
(919) 544-R729
  Instrument H
188 (1.8BB)
IflSn

XFS -
Ji~
181 18176
44 183
48 6
53
jJ-fiU-
se
4
,lll, B,? j
188 158 288 258 380 358
HS3B5'i8B (l.BBl) REFINE
100-

XFS
8-
M/Z
33 6
44

4 388


50 188 158 288 258 388 358
NT2CAA 13 (1.548) Chloroe thane FIND
1B0!
XFS -

0-
M/Z
6

f63
4B..li ,;;
4 108
66


59 168 150 288 258 380 358
-------
                                                                                      CM
B7-08-9T  23:53          Triangle Laboratories of RTF, Inc.
Sanple: VGST-2 SET  1 TUBEA/B  T/TC  173-46-&A/B  TLIM2284
(919) 544-5729
  Instrument H
184 (1,846)
1001 A<

XFS -

0-
42
55
ii 7B
^iiUpi,. Jii^ss
11 45056
103

105
,*•*
l
58 188 158 200 250 388 350
HS355'184 (1.841) REFINE
1C

0-
H/Z

4i! 6f 8,?
>1 41472
163
117
58 10e 158 200 250 388 350
NT2CAA 15 (1.848) frichlorof luoronethane FIND
100-1

XFS -
0-
H/Z
1C


35
47 6.6 82
n 100
163

105
i H.7
50 18O 158 208 250 380 350
-------
                                                                                      CO
                                                                                      en
£17-08-97  23:53          Triangle  Laboratories of  IIP,  Inc.
Sample: UOST-2 SET I 1UBEA/B   T/TC   173-46-6A/B  TLIM2284
(919) 544-5729
  Instrument H
HS3i:
iee-
XFS-
0.

14 O Tf
180
XFS-
8
HS/Z
HI2C
180-
0.
H/Z
fb 251 (2.!
7

44
» 1 53 fe,?
58
i5J251 (2.!
7

44
.a.5.347
58
;AA 18 (2.1
7
44
, 1
56
518)
6 782336

78
168 150 238 250 308 358
511) REFIHE
6 770848

78
»-*
1@3 150 200 253 300 350
MB) Carbon disulf ide FIND
6 100
78
1@8 150 200 250 300 350
-------
07-88-97  23:53         Triangle Laboratories of RfP, Inc.
Sanple: UGST-Z  SET 1 TUBEA/B  I/TC  173-46-6A/B  TLIIW2284
                                                                  (919)  544-5729
                                                                    Instrument H
      258 (2,588)
 SFS-
  8-
    Jl
        58
         64
          U.
              78
                    108
                                                                           14080
                              158
                                         288
                                    258
                                    308
                                   350
HS35F258  (Z.581)   REFINE
    43
        58
  0-
M/Z
                                                                            6480
      50
108
150
200
25O
300
356
       19  (2,578)   Acetone
    43
  0
m/s
      44
                                                                            FIND
                                                                             180
      50
100
150
200
250
300
350
-------
                                                                                      in
87-68-97  23:53          Triangle  Laboratories of RTF,  Inc.
Sample: MOST-2 SET 1 TUBEA/B   T/TC   173-46-6A/B  TL1U42284
(919)  544-5729
  Instrument  H
HS355 298 (2.988)
189

X.FS J
0-
K/Z
4


II
9 1163264
84
51
1 55
1 •- 70
I...I.... - 	 L .

88
.i.
59 100 158 200 250 300 350
HS355'298 (2.981) REFINE
•j QQ -

KFS -
e
H.-'S
4


Jj
5
9 1146880
84
51
I 55

88
@ IBB 159 230 250 300 350
HT2CRA 21 (2.978) Methylene chloride FIND
d
1801

XFS
S-
H/Z


47
9 100
84
51
83

80
j
59 100 159 260 250 300 350
-------
                                                                                       CO
'67-88-97  23:53
Triangle Laboratories of RIP, Inc.
Sanvle: UOST-Z SET 1 TUBEA/B  T/TC  173-46-6A/B  TLW42Z84
(919) 544-5729
  Instrument H
357 (3.578)
108-

XFS-
B-
H/Z
5
41



56
'•
55
7 811808


**_&..*?
59 188 150 288 258 388 358
HS355'357 (3.571) REFINE
180T

XFS -

8-
M/Z
5
41



56
55
\
7 753664


58 B6
;"'..,. ?.r .. L
58 lee 158 200 250 388 358
25 (3.570) n-Hexane FIND
188-
X.FS-
8-
W/E
5
43


56
55
7 108

71 8j&
58 188 158 200 250 300 350
-------
Ol
   80 37  23;53         Triangle Laboratories of RTF,  Inc.
Sample: WST-2 SET 1 TUBEA/B   T/TC  173-46-&A/B  TLIH42284
(919) 544-5729
  Instrument H
HS355 538 (5. 381)
lee:
54FS-

8
H/Z
5
56
| 55
..1ili,i ,-(»ii
7 88864

5878
/ £«J '••. Kjl
i i j 9 9
50 188 158 2O0 258 388 358
(5.381) REFINE
180
XFS -
8
H/Z
5
f
7 58112

50 180 150 280 258 380 350
31 (5.291) Isooctane FIHD
188 1

0
H/Z
5
56
4155
ll, ,>,
V 108

58
,-' 1Q^3
i |
53 183 156 169 258 380 350
-------
                                                                                      oo
07-88-97  23:53          Triangle Laboratories of  RIP,  Inc.
Sanple: UOST-2 SET 1 IUBEA/B  T/IC  173-4&-6A/B  TLIM2Z84
                                                                  (919) 544-5729
                                                                    Instrument H
      441 (4.411)
100- 43
      44
        1
                                                                           5248
  0
H/Z
-T-
58
                  100
            158
            280
            258
            388
           350
HS355T41 (4.411)  REFINE
           72
1QB-
  0-
H/Z
     43
                                                                            860
        57
      44
      5B
183
158
230
258
308
                                                                      356
N12CAA 33  (4.388)   2-Butanone
100- 43
                                                                           FIND
                                                                            180
X.FS-
  0
M/Z
        57
      50
100
158
280
250
388
                                                                      350
-------
                                                                                      CT5
                                                                                      CD
07-08-97  23:53         Triangle Laboratories of RIP,  Inc.
      : UOST-2 SET 1 TUBEA/B  T/TC  173-46-6A/B  TLIIW2284
(919) 544-5729
  Instrument H
HS355 514 (5.141)
7
y.FSj 77
] 5,1 74 x
eU-.l-.-^A'
e

79
-t"
L.L
M/Z 59 ie0 158
H8355J514 (5.141) REFINE
7
,-FJ
I if 74
eij 4 ^ >v
3

79
M/S 58 ' 100 ' 158
MTZCfiA 36 (5,131) Benzene
188 -. 7
52
e ,,i Jl 6.3 ,r
8
79
M/Z 59 1@8 150

2867200



288 256 388 358

2783360


380 258 30B 358
FIND
100

288 250 380 358
-------
                                                                                       c
                                                                                       c:
07-88-97  23:53          Triangle Laboratories of RTF,  Inc.
Sanple: WST-2 SET  1 TUBEA/B  T/IC  173-46-6A/B  TLI842284
(919) 544-5729
  Instrument H
658 (6.581)
108-
XFS-
8-
M/Z
4

J
11 33792
6
55
1.. , Jf ii.1 , 1*
9
/ 81 190
L , i l..j -i. li
58 100 158 200 25O 300 350
HS355'658 (6.501) REFINE
100

0-
H/Z
NTZC
180-

•/.FS-
8-
H/Z
4


i 25856
6
42 5g
9
O ^v i
€,? TU? I
m 108 150 200 250 3O0 350
:A
4


A 48 (6.491) Methyl Methacrylate FIND
i 100
69
«5,
- ^^ CJ "-t I
|ji ^f j!
56 100 150 200 250 300 350
-------
                                                                                     o
                                                                                     CM
07-88-97  23:53         triangle Laboratories of RIP, Inc.
Sanple: WST-2 SET 1 TUBEA/B  f/TC  173-46-6A/B  ?LI«42284
(919) 544-5729
  Instrument H
761 (7,611)
IBB-i 9

' 39
r si es 89
J I «J X . |
a...,,. ,..,|,..,.|LM. ,i. •«,,.,,,.,„,.„,.„•.
1
92
93
»/z 58 lee 158 268 250
HS355'761 (7.611)
i0Bi 9

r'si *5 8?
0i.,,ir , ,. j,. ,»I.|, ..,„. ,r. i
1
92
93
-rif.ii.j.r. .,..,.,..,,,,,,..,,...,,,,.,..,,,,.,.,,
M/z 58 180 158 288 258
H12CAA 49 (7.6B1) Toluene
188-j 9

""I ,39,1 ,5 89
Q,,l- -,."/. .L| r r\
1
92
93
MS* 58 188 158 288 258

1836288


388 358

942088


388 358
FIND
133


388 358
-------
                                                                                      CM
                                                                                      O
                                                                                      CM
87-88-97  23:53          Triangle Laboratories of RTF, Inc.
Sanple: VOST-2 SET 1 TUBEA/B  T/IC  173-46-&A/B  TLIft42284
(919) 544-5729
  Instrunent H
985 (9.851)
ise
9-
M/Z
117 147456
82
m " 55 lift
H? il . 7ftll , n
58 100 150 200 250 380 350
HS355'985 (9.851) REFINE
100-
X.FS
8-
M/Z
1:
77
108
_.v , , 	 ,. i , ii,.
2 5504
114
f
131
50 108 150 200 250 300 350
NT2CAA 52 (9.841) Oilorobenzene FIND
,80

X.FS:

H/Z
1:
77

51 74
«i,.. ,5.6.. \,8p
t2 100

114
|"

58 160 150 200 250 300 350
-------
B7 80 07  23:53
                        Triangle Laboratories of RTF, Inc.
Sample: UQSI-2 SET 1 TUBEA/B  T/TC  173-4&-&A/B  TLIM2284
(919) 544-5729
  Instrument H
HS355 1014 (19,141)
lee-
X.FS-
»•'?"
9
5,1 65 77
1
186
\ , ,1,., . .Jf . , | -, j , ,„ i, , ( , . , . j . , , , ( , , .. ..
59 160 15B
H8355-1B14 (18,141) REFINE
100

8
9

5.1 65 77
| J, ,j ||r ,
1

186
, J/187 _ _. _.
58 iee i5B
53 (18.131) Ethyl benzene
tea-, 'I
i
XFS -
8-
W/'E
¥ fP 7i?

106
Tie?
I J:''
58 10S 150

259072

200 258 380 350

223232


23® 25@ 300 350
FIND
1MB


280 250 300 350
-------
                                                                                      CM
87-68-97 23:53         Triangle Laboratories of RTF, Inc.
Sawle:  WST-2  SET 1 TUBEft/B  T/TC  173-46-6A/B  TLIM2284
(919) 544-S729
  Instrument H
1037 (18,371)
IBB-
XFS -
.B-
9
39
( 51 65 77
1 274432
11
92
...•.,,.1
36
107
50 130 150 200 250 300 350
HS355'1837 (18.371) REFINE
100-
XFS-
0-
HT2C
IBB:
XFS -
B-
9

JL ., . ts ... j.|, u... ,.!«,,. ,„,
1 236544
106
92
107
58 100 150 250 360 350
;AA 54 (IB. 371
9
39 f-a
t> .7 Tl
••• \ fr
) w-/p-Xylene
1 180
11
92
i .(
m
50 ie0 150 2O0 250 300 350
-------
                                                                                 10
                                                                                 O
                                                                                 CM
97  23:53         Triangle Laboratories of RIP,  Inc.
:  UOST-2 SET 1 TUBEA/B  T/TC  173-4&-&A/B  IL1142284
(919) 544-5729
  Instrument H
HS355 1188 (11.881)
180-

XFS •
0
M/2
5

51 73
I 79
1 63 /
-i!j!j.j T 1*,!,, JJ,|.».irJ]i ,,„,„!
1 147456
164
106
92
'. 	 1:1 	 . ..
50 100 158 200 250 300 350
HS355'1118 (11.881) REFINE
IBB:
XFS -
e
M/Z
9


1 124928
186
92 TIB?
50 188 150 260 250 300 350
HT2CAA 55 (11.871) o-Xylene FIND
180n
XFE -
Q,
H/Z
?
39 51
11 If5".
1 100
J?- 1 107
.iBt
38 109 150 260 258 308 ' 350
-------
                                                                                        CO
                                                                                        o
                                                                                        CJ
97-08-97  23:53          Triangle Laboratories of RIP,  Inc.
Sample: UOST-2 SET 1 TUBEA/B  T/TC   173-4&-&A/B  TLIJJ42284
(919) 544-5729
  Instrument H
1113 (11.131)
180-

vFQ-
j **- *>

8-
it
103
78
51
1 76
| I 6,3 \


	 !t...

34 421888



105
«*

B/Z 58 188 158 288 258 380 350
HSSSEPlllS (11.131) REFINE
180

%FS -



0-
11
103
7
51
i „,„ _
j S3 \
...I. . ..I!.. .,J._ ..Ip
3

102

.....89 . ,. ;
. , , . i . . | , . . . t
M 372736



1@5


• • • i • •---• . -( .... i .-. - i .-.-,.-•* i - '. - i -.•-]•••• i • - - • i
M/Z 50 168 158 200 250 380 350
NT2CAA 56 (11.121) Styrene FIND
188:

/.FS .
0-
IE
1B3
51 ?fiV
J. 1 *? ^
B 102
, 85 .j
!4 100

105
-"
. 1 j 1 I 1 j ...,,..,, ,.,,,,....,.... | .... | ..,.,....,..,., 1 ... | :...,
M/Z 50 168 158 208 258 388 358
-------
                                                                                      o
                                                                                      CM
8r-88-97  23'53          Triangle  Laboratories  of  RTF,  Inc.
      : UOST-2 SET i TUBEA/B   T/TC  173-46-6A/B  TLIft42284
(919) 544-57Z9
  liistrunent H
HS355 1185 (11,851)
185 14848
169

•/.FS -|


41 57
69 „„
ll , ,Si:L .Jl Jjlfl l.lll I



123
iin L.
"•/"z 58 100 150 200 250 300 350
!IS355'1185 (11.851) REFINE
iee-
XFS


It

*i7
MVr.^7,'. .',«,
^5 11136

120
Tl22
I. . . I.:'"
H/S 58 100 150 280 256 306 356
HT2CAA 58 (11.851) Cunene FIND
180-
XFS


0-
1C

?? 103

; . j £.3 J.| I
*5 100

129
1

• • f . 1 .,...," .1 • i . i . | .... | .... | .. i . 1 .... | .... | .... | .... | ....,
M/E 50 108 150 200 250 300 350
-------
                      oo
                      o
                      CM
08-Jul-97 23:53          Triangle Laboratories of RTF, Inc.
Sample: UOSf-2 SET 1 TUBEA/B  T/TC  173-46-6A/B  TL1*42284
(919) E44-5729
  Instrument H
HS3!
100;
XFS
0-
55 72 (8.728)
60 2555984
41
JH 	
w^z 50 ' 100 ' 150 •-•••• 2ge • 2£0 • 300 ' 350
HS3E
100
XFS
0.
ill
100
X.FS
0,
#2
100
X.FS
0.
*3
100
X.FS
0
5'72 (8.721) REFINE HBS 49 Hits : 49 Searched
68 2621448
38 41?3 62
,V(tr 	 / as.
FI428 12997
«. *
1315 2627
FJ399 618:3-
3S
F:392 689:2-
3S
!./ .il
M/Z 28 4
:2-PROPENE-l,l-DIOL, 2-METH¥l,-, DI ACETATE
42 ?0 255
68 69 71
, .,.,.. r*!^/ . ., 14.2 l.f.8 . ...
-BUTENOIC ACID
14]L 255
-42 «.--fill 7? 0.5 86
%* v" 3l • O IB m. *• • *• Cr ** x
*ll **\ 1 1 f \ii %f s \
-BUTENOIC ACID, -
»41 255
j§*% — __ Q /*
X *•* "*"T ** ** jf "^ *O %*
,, , \ /, 1^', \r87
0 60 88 180 128 148 168 180
-------
                 O3
                 O
                 CM
            23:53         Triangle  Laboratories  of  IIP,  Inc.
Sample: MOSf-2 SET  1  TOBIA/B   T/fC  173-46-bA/B ILIM2284
(919) 544-5729
 Instruneiit" H
! 18355 163 (1.
IBB] **
*?*-= 1
— re-- J-- !
'* ** «.? •*. i
n . _. Jj
^« .,,,-,,,
hi/ E
HS355fl63 (i,
18H- 4
oq i
MFS "\
ra 1 .11
ill F*. 841 S
ie-3 ail
*-£*! i
«rs. -|
M ' , l.i
:?'.3 F:7-16 i
1 titl T ^
vsrs] 27 29
• ia j.ii. . i,s
«3 F:"33 6
i.B|
XFS-] 39
n__ ;1
M/S
638)
3
555f
\j __^ 7,3
5S iee 158 200
631) KIFINE
•3
5r
,i ?,?•
0^3 : UVDROXVLflHINE, O- (a-METHVLPItOFi'L)-
3
55 -71
44|i5B /3'
;i / ;' t-s *,
,, 	 III. .l-J d . 1
42? ; PENT ft ME. 2 , 4-»IMETH¥L-
3
57
55 1 58 RS
.. ...:':l' 	 T. j. ,,J.., 	
531: HEPTANE, 4-fiSIDO-
3
*>7
44 / ?fl
r' J f 8.4 98
5§ 188 158 288
HBS
765952
25O 388 358
NBS 242 Hits : 242 Searched
696328
C4H110M 255
355
C7H16
• i ' '" - - t • • ' • i * ' ' • i • • • • i • • • • i
255
C7H15N3
250 360 350
-------
                                                                                         o
                                                                                         *H
                                                                                         
-------
BB-Jul-97 23^53          Triangle Laboratories of RIP,  Inc.
Sample: UOSf-2 SIf  1  IUBEA/B  T/TC  173-46-6A/B  TLItt42284
                                                                   (919) 544-5729
                                                                     Instrument H
       181 (1.818)
100-
XFS-
   0
      43
     i
     .I,JL .I...J... L .
                                                                           458752
                   100
                              150
HS355J181  (1.811)   REFINE

100-
XFS
  0
 41
                                       38^39
                                                        NBS  64  Hits


                                                           56
                                                      515
                                                                     64 Searched
                                                                          528384
 #1  F:718  78J2-BUTENI,  CZ>-
                                            41
   0-
                                        3839
                                        . \. I .
                                                                             255
                                              42
                                                           56
                                                             57
 #2   F:?15  76',2-BUTENE,

100

Y.W$i

  0
 #3   F:682  79I1-PROPENE, 2-METHVL-
                                                                             255
                                              /42
                                                                              255
XFS-

  0
M/Z

                                              42
                                              /
                                                       515356
                                                     5JB/.
             10
                      20
                                 30
48
58
60
70
-------
                                                                                  •  (M
                                                                                    v-\
                                                                                    CM
07/88/97    23:53         Triangle Laboratories of RTF,  Inc.
Sample: UOST-2 SET  1  TUBEA/B   T/TC   173-46-6A/B  TLII42Z84
(919) 544-5729
 Instrument: I!
{ 1-=' if-f-
1 S=J JU33
1B01
sFSi
^

IT
XFS-
8.
ta F-
180-j
y-L
S-3 F
-s*T'€~ -
«~3 '•

228 (2.26
=i j- 5
37 51
6
•3
65
NBS
7 147456
81
.. ..l. 101 . __ 	 .
56 150 250
220 (2.20
5
792 182
2, 27 ?9
^; .in r
757 186
39
2 ft 27 /
754 175
5
*3Q
^IJ .
1)
6
3
:l.
53
54
:i,:
536
:2-'
6
h
KEF1HE NBS 44 Hits : 44 Searched
7 138240
69
3~BUT«I)IENE, 2-METHVL-
fi7 C5H8 255
69
3 - PENT ft £• I ENE , C E > -
7 255
,
69
PEHTVNE
8 255
C5H8
69
50 150 200 250 380 356
-------
                                                                                  CO
                                                                                  _H

                                                                                  C4
6W80/97    23S3        Triangle Laboratories of KfP, Inc.
Karwle: UOST-2 SET 1          I/IC  I73-4&-&A/B  TLII42284
544-5729
IHS3S5 195 (1,958)
.sf-nt
= rzu-« =^*
H ,_ . i
is ! J,
«_?7 Y2
'-*••'* 50 ie0 158 288
iHS355f195 (1,951)
-,-.-, 43
A toil ~ 1
xFS i 39
3 ": - t 'j' -'i
57 72
•••- ... j 	 i.
»l F:V35 8tt9:HyD»OXYLAMINE, O-C2-MET HVLPROPVL>-
A^3
IJ"lf~l ,, jm m ^f-i-f
L-l Lri ^ fj t
KFSl 39N
ra 1 I
«3 F;725 1
4
MFS-i 39
1 '7 '"'
P < f..f, .j.i
44||58 '511
(, 	 i< jr.72 .
298:ACEIIC ACID, 2-PROPI3M¥L ESTES
3
„ l— r-j
4*1 - '
/ ilVbl __ _ 	 _ ..
f-3 F:?17 653i:HEPlAHE, ' 4-ftSIl>O- '

XFS-j 39-
57
44 / 7o
/ J T 8/1 98 .
.'-• • • " ' i • • • • i • • • - i ' • • " "i '• - •••• ' 	 i 	 " 	 ' ' i-"- '•-'• • r •• 	 •" •• • i • -• •
H/as 56 188 158 288
MBS
3 6 45 44


258 300 359
NBS 83 Hits : 03 Searched
333S6S

C4H110N 255


255
C5H802

111111
235

258 36S 358
-------
                                                                                          CM
88-Jul-97 23:53         Triangle Laboratories of RIP/ Inc.
Sample: UOSf-2 SET 1 TUBEA/B  T/TC  173-46-6A/B  TLI842284
                                                                  (919) 544-5729
                                                                    Instrument H
HS355 88 (8.880)
         64
100

XFS-
  0
W/2
      48
                                                                          913403
       58
                  100
             200
                 250
fiS355J88 (8.881)  1EF1ME
                                                      NBS  83 Hits  :  83 Searched
                                                                         405504
XFS-
  0
 #1  F:630  652!2-PENTftNONE
100-j                   ^3
XFS-
                                     58
  0
          2,7 /
                   3.9 1,
                                                                            255
    55 /.
                           [m
T
262728 31 39
ik, ( 3,7 ill


5
57
8
59
( ?A
 *2  F:621  674:OXIRftNE,  TRIMETHVL-
                     _ .  JK**
100-

XFS-

  0
 tt3

100

XFS


M/z 20
                                                                            255
            1642:HVDKOXVLftMINE,
                       43

                                                                            255
                         44
                                 X 56
                               53Nl/r58
            30
                    40
50
60
                                             70
80
90
100
-------
                      in
                      »H
                      CM
88-Jul-97 23:53         Triangle Laboratories of RTP, Inc.

Sample: MOST-2 SET 1 TUBEA/B  T/TC  173-46-6A/B  TLI»42284
(919) 544-5729
  Instrument H
557 (5.571)
100i ¥ 17B176
XFS 5i7 7±
B ti ,.j 	 r 	 , T
M/Z 50 ' 100 ' 150 ' 200 ' 258 ' 300 ' 350
HS355'557 (5.571) REFINE
1881 4
XFSJ 41
o i , 3.9 Ji
ttl F:851 809 5 HYDROXYLftM
1001 41
X.FS 39
0 ' 'i 1 i ' '
tt2 F:827 1642:HYDROXVLfil
1801 4
XFSJ \
01 i 1 1 1
«£*% *"» M A 4 A 4 ^| -
,43 255
44 ^l5!6 58 70 J1
f'4,6 ,,5,3,)) /M ."llr??,
1INE, 0-<3-MEIHYLBUTVI.>-
3 255
44 55V 56 70 71
/, 53,X|/n ,^1,
-HETHYL-
3 255
_- ?e 71
44 55 5,6 \ /
/ 	 >, I 	 1 1 - . . 85 100
M/z '20 30 ' 40 ' 50 ' 60 ' 70 80 ' 90 ' 100 '
-------
                                                                                  CD
                                                                                  *H
                                                                                  CM
87/08/97     23*53        Triangle Laboratories of IIP,  hie,
&inpJe: VOST-2 SET 1 TUBEA/B  T/TC  173-46-6A/B  TLI«42284
(919) 544-5729
           ;  H
412 (4.12*
les-i 5
4155
XFS-j **^
»1 J,l. ...
i)
6
69
	 L ..!?
H/Z 58 ' 180 ' 150
HS355J412 (4.121
IBCh 5
vrfTfij 4155
L) REFINE
6
65
	 	 I. .m
111 F;831 4261:2H-PVRAN-2-ONE, TEfRflH¥!>RO-3
d-p
IBBi *" 55
v.FS 37 , -43J57 69
3 '. b / 64
q J - L . :' , ,. i *-, —
: 1 - OCT , 7 - MET H V L~
6 69
57 /
/ | 7a 83
Jf-W;f 98111126
' ' ' • I • • ' • i - • • • ! ' ' ' 1 ' • ' • 1 ' ' • ' 1 • • ' • 1 ' ' '•'
M/Z 50 100 150
NBS
106496
280 250 300 350
MBS 66 Hits : 66 Searclied
91136
»6~BIMEIH¥]b-
C7H1202 255
»€-3C«IMElH¥L-» TRANS-
255
C7H1202
-, i . I4i •' J- i - • -lt •' •' i * * ' • i Jl ;* i
255
C9H18
• i • "• ' • i ' • • • i • • • • • i ' ' • * i * •• 	 ' '••)""' 	 ~i 	 - 	 ' — i
200 250 360 359
-------
                                                                            CM
                  Triangle Laboratories of P,TP,
i;OSi-2 SET  i  TUBEA/B  I/TC  173-46-66/8  TLI842284
O19) 544-5729
 Instrument: H
HS355 871 (8,711)
IQflrj ~'
x.FSj ng 177
1 - < '-i a £ — ,. fio •*•'. 1 H i
I-, j ^1 f ^ .' :?."-• . 1 o ^? •••. -1 ? -«•
rj ' . i . • . | • T^ ," • '!• r> j"'! l"1 1" ?"•) r'!' .••!• 1 , .•'] . r | . l"-l . ("1 1 •!» M ! i
H- s 5@ lee 158 209
HS3B5f871 (8.711) EEFIHE
100" 2<
'tS i77 191
«i F: V96 22431 rCVCLOITlIS I LOXAME, HEXAHETHVL-
ia«-, 2I
Jir7 ""^O fiQl'^^E f °7 *? 1 9 •
r-* 4 .- -_l ~ | i J. 7 J- -Y •»> J. f I •*• -f —
ffv F!735 30l5tilAR¥]BEMSEHE
I9q, l|12 ESTER
'7Bfl C9H7.703Ri3rtsJ"
37 255
268 C12H22S12
222
\ T-
250 369 358
-------
; ; ; Pacific Environmental Services .:•....
Project Number 42284
Sample File: HS365
Client Project: S4Q7-00&
ITJ ID: 173-46-7A,B
<
Method 8240A VOST

Sample ID:
Gate Received: 06/30/97

Date Analyzed :

07/09/97
VOST-2 SET 2 TUBEA/B T/TC
Response


Fiie:ICALH7Q8




Aital^fr • ' .'.:••'..• : :'""•'• &m.«w*- '• !F£AG- ' \&£ .•] '•'.. IJefcttuMtlt; ". Q&aa,IaojJt
Bromochloromethane
Chloromethane
Vinyl Chloride
1,3- Butadiene
Bromomethane
Chloroe thane
Vinyl bromide
Trichlorofluoromethane
1,1-Didiloroethene
lodomethane
Carbon disulfide
Acetone
Ally! chloride
Methylene chloride
trans- 1 ,2-Dtchloroethcne
tert-Butyl methyl ether
Acrylonitrile
n-Hexane
1 , 1 -Dichlo roe thane
1 ,2-Epoxyburane
cis-1 ,2-Dichloroethene
Chloroform
1 ,2-Dichloroe thane
[soocune
1 ,4-Difluorobenrene
Vinyl acetate
ISl
0.093
U
0.143
0.019 J
0.004 J
U
0.053
U
U
0.490
0.082 B
U
0.349 B
U
U
U
0.210
U
U
U
U
U
U
IS 2
U
4.49
0.93

1.08
1.42
1.54

1.82


2.49
2.55

2.96



3.55






5.64


0.001



0.001

0.001
0.001


0.001

0.001
0.001
0.003

0.001
0.003
0.001
0.001
0.001
0.001

0.001
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05

0.05
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit Quantitation Limit
IS: Internal Standard; U: Undetected; B:
Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
              Savar v3.5
Printed: 15:02 07/22/1997
-------
 Project Number: 42284
 Sample File: HS365
                       Method 8240A VOST
Sample ID: VOST-2 SET 2 TUBEA/B T/TC

2-Butanone
1,1,1 -Trichloroethanc
Carbon tetrachloride
Benzene
Trichloroethenc
1 ,2-Dichloropropane
Ethyl acrylmte
Mechyl mediacrylate
Bromodichloromcihane
cis-1 ,3-Dichloropropene
trans-1 ,3-Dichloropropene
1 ,1 ,2-TrkhIorocdmnc
Dibromochloromethane
Ethykne dibromide
Bromofbrm
CMorobcnzenc-d
4-Methyl-2-pentanone
Toluene
Tetrachloroethene
2-Hexanone
Chlorobenzene
Ethylbenzenc
m-/p-Xylene
o-Xylcne
Styrene
.1 ,2,2-Tetrachforoethane


0.013


0.959



0.027









0.433
0.001

0.005
0.066
0.145
0.063
0.273
0.015
t"3iW^£i!*:^^:^^--'^--Oi^:t-;-^
MsP^i^lSiSSiSilSiSilll
J
U
U
B
U
U
U
J
u
u
u
u
u
u
u
IS 3
U
B
J
U
J




J
4.37


5.11



6.47







9.76

7.58
8.38

9.81
10.10
10.33
11.03
11.08
12.52


0.001
0.001

0.001
0.001
0.001

0.001
0.001
0.001
0.001
0.001
0.001
0.001

0.001


0.001







0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05

0.05
0.05
0.05
0.05
0.05
0.05
0.10
0.05
0.05
0.05
                        NA- Not Applicable; D«t Limit Detection Limit; Quasi. Limit: Quantilation Limit
    IS; Internal Standard; U: Undttectot; 8; Pr»*nt In Blink; |: EttinuMd- Below Qiuuititation Limit; B Estimated- Above Calibration Hinge
Triangle Laboratories of RTF, Inc.
801 Capitols Drive « Durham, North Carolina 27713
Phone; (919) 544-5729 » Pax: (919) 544-5491
                                      SavarvS-S
                           Printed: 15:02 07/22/1997
                                                                                                  219
-------
Project Number 42284
Sample File: HS365
                                                                                     Method 8240A VOST
                                                              Sample ID: VOST-2 SET 2 TUBEA/B T/TC
                                           Dale Received: 06/30/97
                                                                                Response Pile: IGALH7Q8
Cumcne
0.007  J
                                                                11.81
                                                                                                       0.05
• I":! -*' .**•'•?••••'
: s\ \'-V- •/, •
1 ,2-Dichloroethane-d
Benzene-d
6
Tolucnc-d
_,. -.•V^'-J. " ". V .•".*".,•/• s '* 	
%1> ;X:*^ "•" "'%^**>:* *• ••vJ'faGnLOOjtrt^ \%-j^- !-^A sf-.y*^ i- ^A\.
•i\f^3P-i4:> .™^^'-" <
0.231
0.250
0.281
:;*S:
5.09
5-07
7.49
#33N&;
1
2
3
il|=^!;;
92
100
112
Reviewed bv
                                     Date
                        NA- Not Applicable; Del. Limit: Detection Limit; Qtun. Limit: Qiuntitation Limit
    IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Qnanrltation Limit; t Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
801 Capitola Drive • Durham. North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                                                                     Savar v3.5
                                                                                          Printed: 15:02 07/22/1997
                                                                                                     220
-------
Project Number:  42284
Sample File:      HS365
           Method 8240A
           Sample ID:         VOST-2 SET 2 TUBEA/ B T/TC
Client Project
TUID:

S407-003
173-46-7A,B


Dilution Factor:
Date Received:
Date Analyzed:
1.00
06/30/97
07/09/97

                                Tentatively Identified Compounds

                                                                                            tg
   Unknown
   C5H8 Isomer
   Pentane
   C4H8 isomer
   Methylbutane Isomer
   C6H12 Isomer
   Hexamethylcyclotrisiloxane
   Methyl Propane Isomer
   Alkerte
   C13H28 Isomer
 0.721
 2.190
 1.940
 1.011
 1.620
 3.451
 8.671
 0.861
 9.161
10.631
20117332
9295418
8571261
8112055
7793199
4524458
8042815
3896776
5809888
5241712
4.491
4.491
4.491
4.491
4.491
4.491
9.761
4.491
9.761
9.761
5090038
5090038
5090038
5090038
5090038
5090038
10274056
5090038
10274056
10274(56
0.988
0.457
0.421
0398
0383
0222
0.196
0.191
0.141
0.128
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 * Fax: (919) 544-5491
                                 Printed:  10:41   07/25/97
                                                                                         221
-------
                                                                                 C4
97  13:18         Triangle Laboratories of RIP,  Inc.
:  WOST-2 SET 2 TUBEfi/B  T/TC  173~4&-7A/B  TLIU4ZZ84
(919) 544-5729
  Instrument H
188]

XF3 -


A
A/C
A
J^Jt




a,
X
i
i
A
Min




,
'i
if
Iv





4
3X
l-J






r -
U-/MJ
4.8
5.^i




i 4
lv,J




5.
.—-J
4614625
TIC
•1
/
7.

t/
I* T
^8
11 88
-------
I."JAW • DrS  :  HS365
No. MAT FOR  REV Delta
              QUAN
Area P.t-iaqs
RT
QM Name
1
o
4
5
6
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
^_O
25
26
28
29
30

33
34
35
36
37

40
41

44
45
46

49
50
100
100
100
54
99
100
.100
100
0
100
94
26
0
90
0
0
100
81
0
100
0

31
100
0
0
0
0

94
0
0
10O
0

1OO
O

O
o
o

100
34
39
91
96
20
78
38
87
79
0
76
58
29
0
54
0
0
83
48
0
79
0
— Jw
98
0
0
0
O

76
0
0
94
0

78
0
1 n

0
0
0

95
11
09
97
98
66
3O
99
94
86
0
100
95
40
0
94
0
0
99
82
0
94
0
->,
10O
0
0
0
0

76
0
0
99
0

90
0
C -7
C —
0
0
0

99
44
0
„ i
1
0
1
0
0
-1
1
26
0
-1
0
0
0
-1
0
0
0

0
0
0
0
0

1
0
o
o
0
•*-
0
0
X-N
0
0
0
s
1
0
356S76
2146296
2745368
388664
2482108
35G2316
1651744
279424
0
61260
0
215780
0
0
4410940
153088
0
980668
0

1404672
0
0
O
0

4532
0
0
10433720
O

55316
0
c rr -? o
/ r -T f
0
0
0

3520328
4176
bb
bv
bv
bv
bV
vv
vv
.•S3"7| $\4
bb
-a- ~7 113
bb
bv
bb
bv

D v
bv

U .
bb
bv
^
vb
^
4.49
5 . 64
9 . 76
5 .. 09
5 . 0 7
7.49
^~ -re
12.
0.
0.
1.
0.
1.
0.
0.
2 .
0.
2.
0.
-r
3.
0.
0.
0.
0.
^
4.
0.
0.
5.
0.
w -
O4
93
OO
Oik<
42
9^9-1.
OO
82
00
00
49
55
00
96
00
-Z 7
55
00
00
00
00
r 4

37
00
00
11
00

6.47
0.00
-! 1C
A <•> /~>i


bv
A
0.00
0.00
0.00
"7 ^O
7.58
8.38
128
114
117
65
84
98
98
95
5O
62
:>§- 39
94
,SM 64
106
101
96
142
76
43
76
84
96
73
57
63
42
96
83
62
^7

72
97
117
78
130
/: T;

69
83
75
75
97
129
107
173
43
92
164
8 r o m o c h l o r o m e t n a n e
1 , 4-D.i F 1 ucrobenzene
Ciiloroberizene-d5
:L .,'2-0 i. c h 1 o r o e i: h a n e - - i 4
Benzene— d6 ->.
Toi ue ne— d8 /^»^TT>_)
4-Bromof 1 uorobenzene
Chi orome thane
Vinyl Chloride •>
1 . o Butadl 6i iti \3(YlVl LfiJ
Bromomethane
C h 1 o r o e t h a ru.^TJTTxJ
Vinyl bromide
Trichlorof luorometharu
1,1-Oichloroethene
lodomethane
Carbon disulfide
Acetone
Ally! chloride
Methylene chloride
trans-l,2-Dichloroeth<
Ac r y 1 o n i t r i 1 eJt^f\»J
n-Hexane
1 ,1-Dichloroethane — ^
cIs-.l,2-Dichloroethen<
Chloroform
1,2-Dichloroethane
Vinyl acerate ^TTV/-'
2-Butanone
1,1,1-Trichlo roe thane
Carbon tetrachloride
Benzene
Trichloroethene
1 ,2-Dichloropropan\gxr|
Ethyl acrylate -^-^
Methyl methacrylate
Bromodichloromethane
cis-.l , 3-D ichlorop rope
trans-l,3-Dichloropro
1,1,2-Trichloroethane
Dibromochloromethane
Ethylene dibromide
STT^j/l ]
xlx .
Toluene
Tetrachloroethene
2ne
2P
5
a
•w
&£
&a
                           Data Review:
                           Date:
                                                                          OO
-------
MAT FOR REV Delta
'~ea  ?. Flags
RT

52
C T-
._. '-V-'
54
55
56
57
58

51
1OO
1OO
100
100
53
78

..L /'
90
87
81
93
17
47
r- f"
67
09
9.-1
86
97
70
81
-V
1
1
0
1
1
1
1

56524
370676
1O14884
42OO12
3O17696
42O42
158576

ob
::>\'
v'V
DV
ov
VfV
ov
^
9
1O
1O
11
11
12
11
-,..
,81
, 1O
.33
.03
,08
. 32
.81
-,
112
106
106
106
104
83
105
o
Chiorooen
Ethylban.2
m-/p-Xy le
o-Xy lene
S tyrene
1,1,2,2-T
Cumene
^fVAp


                                                              224
-------
in
04
O4
07-09-97 13:18 friable Laboratories of RTF, Inc. (919) 544-5729
Sample: WST-2 SET 2 TUBEA/B T/fC 173-46-7A/B ILItt42284 Instrument H
93 (8.930)
iea

XFS -
0-
M/Z
5
44
^JUflJ
5
e 56328

52
0 108 158 288 258 388 358
HS36S!93 (8.931) REFINE
180-
XFS -
0-
H/Z
5

49
1,1
§ 47616
52

5B 1O8 158 288 258 388 358
HT2CAA 9 (B.93B) Chloronetliane FIND
ie«i
XFS -
0-
»/z
5

44
.. , Ld
@ 188
52

50 188 158 288 258 380 358










-------
                                                                                       CO
                                                                                       CM
                                                                                       CM
09-Ju1-97 13:18          Triangle Laboratories of RIP,  Inc.
      : UQST-2 SET 2  TUBEA/B  T/TC  173-46-7A/B  TLIH42284
(919) 544-B729
  Instrunent  H
HS365 108 (1.080)
100-
XFS-
0
«/z
3

al
9
5
50
»ii I
90112
4

hL .
50 ' 188 ' ISO ' 208 150 ' 308 ' 358
HS365'108 (1.081) REFINE
1001 54 70656

XFS
0-
«/z
53
\
50
\



50 100 150 200 258 300 350
PIASTER 11 (1.440) 1,3-Butadiene FIND
100
XFS-
0
M/Z
3

9 100
54
50
\
, 1

50 ' 100 ' 15fl ' 200 ' 250 ' 300 ' 350
-------
                                                                                        CM
                                                                                        CM
87-89-97  13:18
Sample: MOSI-2
     Triangle Laboratories of RIP,  Inc.
2 IUBEA/B  T/TC  173-46-7A/B  TLI#42284
(919) 544-5729
  Instrument H
HS365
180-

XFS H
8-
H/S
4


^_
HS365'
100-
XFS-
H/Z




142 (1.428)
4 17664
94

93
*— H™ G 'I
e t O1 -*.-.-
"i , >r. *


58 158 200 258 388 350
142 (1.421) REFIHE
9-
93
7,9 ]
11 ,1
f 9856


50 100 150 280 250 300 350
NT2CAA 12 (1.42B) BroMonethane FIND
188-
XFS-
8-
H/Z


4,8

9<
93
^ %l J
1 180


59 1@@ 150 200 250 308 350
-------
                                                                                       oo
                                                                                       (M
                                                                                       CM
89-Ju1-97 13:IB         Triangle  Laboratories  of  RTF,  Inc.
Sample: UOST-2 SET2TUBEA/B   T/fC   173-46-7A/B   TLIft42284
(919) S44-5729
  Instrument H
HS365 154 (1.54B)
IBB
WI/Z
44 14912
55
•1 ,-li,
. 1
50 100 150 200 250 300 350
HS365'154 (1.541) REFINE
100
XFS
0
IH/2
6

4 1440
66
50 ' 100 ' ISO ' 200 ' 250 ' 300 ' 350
MASTER 13 (2. §20) Chloroethane FIND
100
XFS
0-
M/Z
6

49
4 100
66
(
50 ' 100 ' 150 ' 200 ' 250 ' 360 ' 350
-------
                                                                                      0)
07-09-97  13:18         Triangle Laboratories of RTP, Inc.
Sanple: VGST-2 SET 2 TOBEA/B  T/fC  173-46-7A/B  TL!i4Z284
(919) 544-5729
  Instrument H
182 (1.82B)
100-
XFS -
0-
11
42
55
i 78
! I
11 SSS I!!i:j. . t'W^lt * *
11 27392
163
y

185
f 117
!'***! '' "v 1' *^ "I""'*! * * * * 1 " " ' * I «-.-|«-« • I'-' -|-- ,.j. .,.,.. .. |
HS365'182 (1.821) REFINE
1B0-

X.FS-
8-
1C


I7 6|f 84
11 25856
183

185
53 180 158 108 258 308 358
HT2CAA 15 (1.840) Trichlorof luoronethane FIND
leei L*\
\

XFS -
8-
H/Z


35
47 
-------
                     c
                     01
tJ7-iJy-y7  13:18          Triangle Laboratories of IIP, Inc.
Sample: MQST-2 SET 2           T/IC  173-46-7A/B  TLlt42284
(919) 544-5729
  Instrument H
:HS365 249 (2.49B)
iBin
XFS-

7

44
6 827392

78
H/Z 58 160 150 200 250 3B8 350
HS365'249 (2.491) HEFINE
100-
xFS-

e-
7

44
1 5,3 67
S B15I04

78
.L
r I I , l"'l -, ..,.,..,.,,,,,.....,,...,....,....,....,....,.... ! ....,
M^Z 5B 158 280 250 308 350
18 C2.5BB) Carbon disulf ide FIND
1801 7

XFSJ



44
6 100


78
Vf • • - t • • • • ........ , 	 , ,,,,,.,..,....,....,..,.,....,..,.,,...,,. .. ,. ,. ,
m/'s 58 180 150 200 250 380 350
-------
                                                                                       CO
                                                                                       CM
97-09-97  13:18         Triangle Laboratories of  RIP,  Inc.
Sawple: WST-2 SET 2 IUBEA/B  T/TC   173-46-7A/B  TLIM2284
                                                             (919)  544-5729
                                                               Instrument H
      255 (2.558)
     43
    Jji
        5ft
        ""*
          £. "J
              78
M/K
50
ie@
150
280
                                                      258
360
358
!iS3&5J255 (2.551)  REFINE
IBS- 43
=/.rs-
  B
        58
                    If 8
i*/ z   59
                              158
                                    280
                                     250
                                    300
                                   350
       19 (2.578)  Acetone
     41
liei
  B
MS
                                                                      FIND
                                                                       100
56
lee
158
200
                                                      250
300
353
-------
                    
-------
                                                                                       CO
                                                                                       CO
67-69-9?  13:18         Triangle Laboratories of RIP, Inc.
Sample:  UOSf-2  SET 2 TUBEA/B  T/TC  173-4&-7A/B  ILIM2284
(919) 544-5729
  Instrument H
355 (3.550)
180-
XFS-
8-
M/Z
4


5
1
56

55
7 182272

?°JJ- *f
5@ 100 150 200 250 300 350
HS365'355 (3.551) REFINE
100-
XFS-
0-
pt/S
5
4

-3
56
44
7 167936

fn *!>
58 108 150 200 250 300 350
25 (3.570) n-Hexane FIND
1 HP 5i? 100

v
0-
43


56%
55


v T
58 ' 1OO ' 150 ' 200 ' 250 " 300 ~" 350
-------
                                                                                       00
89-Jul-9? 13HB         Triangle  Laboratories of RIP,  Inc.
Sample: MOST-2 SET 2 TUBEfl/B   T/TC   173-46-7A/B  TL1H42284
                                                                  (919) 544-5729
                                                                    Instrument H
HS365 436 (4.360)
100
    , 43
                                                                            4096
      44
        u.
M/Z   58
                  100
            150
            200
            250
            300
           350
HS365M36  (4.361)   REFINE

100- 43
XFS
  0J^
                                                                            3440
M/Z   50
                  100
            150
            200
            250
            300
           350
MASTER 35 (5.158)  2-Butanone
100- 43
                                                                            FIND
                                                                             100
X.FS
        5?
    ,....111. t..i^-
           1
M/z
       50
100
150
200
250
300
350
-------
                                                                                        IT
87-09-97  13:18         Triangle Laboratories of RTF,  Inc.
Sample:  MOST-2 SET 2 TUBEA/B  T/TC  173-46-7A/B  TLIW2284
(919) 544-5729
  Instrument H
511
100
XFS
8-
H/Z


,1,. 1
58
HSSbB-'Sli
180-
HFS-
g.
H/Z

5J
58
36
100-
xFS-

0-
w/z


52
.,! J.
58
(5.111)
7
77
65
8

84
H...I.. ....
108 150
(5.111) REFINE
7
77
74
\
8
79
i'.
180 158
(5.131) Benzene
7

77
6.3
8

79
i
j i i i . ..,,..,.,.,,,,..,.
lee 150

1589248


280 258 366 350

1523712

200 250 300 358
FIND
lee



200 250 300 350
-------
07-89-97 13:18 Triangle Laboratories of RIP, Inc. (919) B44-5729
Sample: UOST-2 SET 2 TUBEiVB T/TC 173-46-7A/B IL1JW2284 Instrunent H
!IS3t
XFS -
B
f4/Z
iee-
8
M/Z
HT2C
IBB
XFS-
M/Z
Jb
4
Jfl
4
jjj
tt
4
,
b47 (6.471)
:J.. 13768
§9
4235 .-•• oi
/ i ' 81 100
It, iliju i i li i 1 1 1 1 |i ll
58 100 158 200 258 388 350
H&l? (6.471) REFINE
1 9280
69
r ^ /%5 T
58 160 150 200 250 300 358
B 48 (6,491) Hethyl wethacrylate FIND
i 100
65
42 5g 70 i
-------
87-89-97  13:18         Triangle Laboratories of IIP, Inc.
Sample: UQST-2  SET 2 TUBEA/B  T/TC  173-4&-7A/B  TL1M2284
(919) 544-5729
  Instrument H
758 (7.581)
108-1 9

' 19
• /si &5 B9
8,, I „..!. ..!l 	 ,|I.| 	 	 	 ,-,,.,.?,
1
92
93
..-•
i_......
yl» ]W| ( ,.«.!* || 1, i-.jii t,i,,«i.r ., . , 4 ,,.„,,,.,,,».
«/z 58 180 150
HS365J758 (7,581) REFINE
1861 9

KFS-
' "19
r si 
-------
                                                                                        a
                                                                                        cr
                                                                                        <\
07-69-97  la:18         Triangle Laboratories of IIP,  Inc.

Sample: UQST-2 SET 2 TUBEA/B   I/fC   173-46-7A/B  ILIM2Z84
(9193 544-5729

  Instilment H
IHS.%5 838 (8,381)
109"
XFS -
Q-
H/Z
4

i
I .j
..'
i »!i
5
7 69

5376

jfi 84 9
ihil fllll h

HS3fa5'838 (8,381)
160-)

•XKS-
8
H/Z

4
<
13
58
58 (8,411)
ipn-s
,

XFS-
0-
H/Z

<
47 i
, , li
39 8?
5 a
*£t
5 M2 ^
r 1
^6
188 158 289 250 38B 350
REFINE
U
i'
J
1
a

6 1888
168

150 288 258 3B0 350
Tetrachlorocthene FIND
1^6 180
129

>4



133
'

168
'
170
i
168 15B 288 258 300 350
-------
en
en
CM
87-09-97 13:18 Triangle Laboratories of RTF, Inc. (919) 544-5729
Sample: VOST-2 SET 2 TUBEA/B T/TC 173-46-7A/B TLII42284 Instrument H
HS3I
180-
XFS-
iB 981 (9, BID
117 115712
82
54 >19
f ,l,f..^,,/3 "S,,
M/Z 58 ' 168 ' 150 ' 20e ' 2g0 ' 30e ' 3g0
HS3f
100
XFS-
8-
*5J901 (9.811) REF
1J
7?
1NE
.2 6080
114
«^z 56 ' ' 150 ' 200 ' 250 ' 300 ' 350
MT2C
XFS-
8-
%M 52 (9.841) Chi
l:
77
51 7.4
.... ,5.6.. J,.e5
orobenzene FIND
.2 100
114
1
«^z 50 ' 189 ' 150 ' 200 ' 250 ' 300 ' 350

-------
                                                                                        o
                                                                                        *^
                                                                                        CVJ
B7-89-9V  13:18         Triangle  Laboratories  of  RIP,  Inc.
Sanple: MOST-Z SET 2           I/1C   173-46-7A/B
(919) 544-5729
  Inslrunent H
HS365 1810 Cie.lBl)
IBSi 9
XFS -
51 65 77
y ..l.i. .p,.,.. .i.l....,.,.!.!!.,,.,..
1
106
, 	 1. . ..
M^z 5B ' 100 ' 150 ' 200
HS365J1B18 (li.lBl)
1601 9
XFS -
5.1 65 7V
(J »l|- •{'•• -'•'• , i-j ll'i "L.IJ
1
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[107
i 	 k
w^z SB ' iee ' 150 ' 200
NT2CAA 53 f1fl,l3l) Ethyl benzene
1B8l
HI £ 1 "»n
-jj. bp f /
p 1 ..ir . , ... . . II.
1
las
JJL07
i .Jr'
n/z 58 160 150 200

140288

250 300 350

119808

250 389 350
FIND
100

250 300 350
-------
                                                                                       Cl
§7-89-97  13:18          Triangle Laboratories of RIP, Inc.
Sanple: VQST-2 SEI 2 TUBEA/B  T/TC  173-46-7A/B  TLIf42284
(919) 544-5729
  Instrument H
1833 (IB. 331)
1001 91
1
XFS-
B-
H/Z
39
L V, f ,5 71?

186
?2 107
i. 	 iK 	
58 108 158
H5365'1B33 (10.331) REFINE
100-
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9
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/* 69, 77
56
1
186
92
188 158

245760


288 258 308 358

211968

280 258 380 358
FIND
100


280 258 308 350
-------
07-89-97  13:18          Triangle  Laboratories of  IIP,  Inc.
Sample: WST-2 SET 2  TUBEA/B   f/TC  173-46-7A/B  fL!tf42284
(919) 544-5729
  Instrument H
HS365 1103 (11.831)
IBS

e-
9

1 63?6 ?f
.,,«, |L, i[i.,.,rj|! (...,.,
1 99328
164
186
Hi
58 108 158 268 258 380 358
HS365M183 (11.831) REFINE
188-
0-
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1 82944
92
i. . ... .... .
56 168 150 260 258 388 358
m?£m 55 (11.871) o-Xylcnc FIND
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92 |i07
59 108 158 288 258 308 358
-------
                                                                                     CO
                                                                                     ^
                                                                                     C4
07-89-97  13:18         Triangle Laboratories of RTF, Inc.
Sample: WST-2 SET 2 TUBEA/B  T/IC  173-46-7A/B  TLIM2284
(919) B44-5729
  Instrunent H
1188 (11.881)
180
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J9-

7
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56
U
183
8
34 364544
185
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108 158 208 258 388 350
H83&S'ilB8 (11.881) REFINE
188-
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NT2C
100-
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N/Z

7
¥
1 *i3
58
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50
11
103
8
102
-------
                                                                                       
-------
                                                                                        u
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H7-89-9?  13:18
Sanple:
'if-'?
          Triangle  Laboratories of IIP, Inc.
SET 2  TUBEA/B   T/TC   173-46-7A/B  TLIIW2284
(919) 544-5729
  Instrument H
1181 (11,811)
188-
8-
H/Z
11
41 g?
.1 , ,,47I,^,
35 15296
128
!,,, 1.
SB 158 258 388 358
HS365'Ii81 (11.811) REFINE
ig- if 5 11968
~ ]
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39 5,7 6g 183
eJ
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186
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58 180 158 288 258 388 358
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15 1G8
128
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50 138 159 288 258 388 358
-------
                 CO
                 «3«
                 CM
89-Jul-97 13:18          Triangle  Laboratories of  BTP,  Inc.
Sanple: MOST-2 SET 2  IUBEA/B  I/TC  173-46-7A/B  ILIH42284
(919) 544-5729
  Instrument H
72 (8.728)
i nn 68
100-
XFS
0:

41
jj.ji( , 	
M/Z 50 100
HS365'72 (8.721) REFINE

1835008



150 260 250 300 350
NBS 49 Hits : 49 Searched
, __ aa 180224B
100-
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1001
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70 255
{ 60 69 71
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-------
9fV89/y7     13:18        Triangle Laboratories of RTF, Inc.
Sarnie: MOST-2 SET 2 TUBEA/B  T/TC  173-4&-7A/B  ILI»42284
(919) 544-5729
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219 (2,lyij
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l:l/'J7 13:10 Triangle Laboratories of BfP, Iw. (919) 544-5729
».le: MOST- 2 SET 2 luBEA/B T/TC 173-46-7A/B Instrument: !!
ib 194 (1.948)
43
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358
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43 214816
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F;V56 ll?8:nCETIC AC!!>, 2-FROFEKYL ESTER
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                                                                                  CD
                                                                                  TP
                                                                                  CJ
09-Jul-9?  13:18         Triangle Laboratories of RfP, Inc.
Sample:  UOST-2 SET 2 TUBEA/B  T/fC  173-4&-7A/B  TL1*42284
(919) 544-5729
  Instrument H
HS3£
100
XFS
0-
»5 181 (1.818)
|43
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J,L..,jL . .
413696
M/Z 58 ' 100 ' i^a ' 288 ' 258 ' 380 ' 350
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100
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100:
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NBS 87 Hits : 87 Searched
481488
565?
56 255
,5,3,^ / "?(!-
56 255
55/6
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68 78 88
-------
                                                                                     o
                                                                                     in
Sample:  UOSf-2 SIT
                           Triaiwle Laboratories of KTP,  Inc.

                                f/IC   173^4b-?ft/B  TLIM2284
IISJ6G  162 (1.620)
                                        R44-R729

                                        	i; _H

                                            NBSl
                                         218544
                         168
jM3365J'ih2 (iTbZl)   REFINE

             43
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                                            358
                                                       HBS  242 Hits  : 242  Searched

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                      in
09-Ju1-97 13:18         Triangle Laboratories of RTP, Inc.
Sample: UOST-2 SET 2 TUBEft/B  T/TC  173-4&-7A/B  TLIB42284
(919) 544-5729
  Instrument H
HS36
100
XFS
>5 345 (c
|43
II 6
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HS36
100-
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1.458)
114688
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100 ' 150 ' 200 ' 250 ' 300 ' 350
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42
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100-j 5
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HBS 61 Hits : 61 Searched
6 74752
67 *9 84
^NE, TEfRAH¥»RO-3,6-DIMETH¥L-
255
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6 ' * 255
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M/Z 20 ' 38 ' 40 ' 50 ' 60 ' 70 '80 '90 ' 100 ' lli ' 120 ' 130
-------
                                                                                    CM
                                                                                    in
                                                                                    CM
             13:18         Triangle Laboratories of  RTF,  !ne,
Konph;: UOST-2 SET Z TIIBWB  f/TC  173-4b-7f1/B   TLIJ142284
(919)
 Instrument.' H
HoJbh 8b7 (8,671)
?s
1 C?t3 -5 *• '
'•:!>'*;•: | 1 9 i'f-f
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i? 255
268
DFHEHOXV -, ACETATE
17 255
\. .^223
H/2: ' 50 190 ' 150 ' 288 ' 250 ' 380 ' 3"jtl
-------
                CO
                in
89-Ju 1-97  13:18         triangle Laboratories of RtP, Inc.
Sample:  MQST-2 SET 2 TUBEA/B  T/fC  173-46-7A/B  TL1842284
(919) 544-5729
  Instrument H
HS3f
180-
XFS
0-
»5 86 (8.86B)
43
44
ill 	
w/z 50 ' 100
HS36
188-
XFS-
8.
*1
188
XFS
0.
#2
100
XFS-
0.
#3
100-
XFS
0.
£'86 (8.861) REFINE
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FI647 1642:HYDROXYLI
4
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4
29 41
2,7 / 39^,
F:623 1643.-HYDROXYLI
4
« 41
38 h
1 1 1 1
M/Z 20 30 48
181248
150 ' 200 ' 250 ' 300 ' 350
NBS 44 Hits : 44 Searched
3 177152
, , 5,7
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3 255
44 5\ 56 70 71
/ 5,3V, r58 ,v)l.
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50 60 70 80 90 100
-------
                                                                                 in
                                                                                 CM
H7/09/97    13:18         Triangle Laboratories of IIP, inc
S'anple: MOST-2 SET 2           T/TC  173-46-7A/B  TL1842284
(9191 544-5729
 Instrument *  H
U8365 916 (9,
""i! 	 L!
M/T.
HS3G5'9i& (9.
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39 166 158 209 238 386 35B
1G1) HDS 156 Hits : 156 Searched
3 less 44
Ji. ..., 8«f i?6
3?S= i-HEPIENE, HJ-HETH'sL-
1155 7Q C8H16 2ab
.,.1 , ./ (-84
,-. ,j!., ,l...|, . i j i . » » ^ »..lt.,.j...vj.«--j>'.»^-..-j-...j
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55r56 78 ,% _4 255
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50 168 158 289 258 360 358
-------
07/09/97 13:18 Triangle Laboratories of RTF. Inc.
:{a«w!e: UQttl-Z SET 2 TUBKA/B f/TC 173-46-7A/B TLIIH2284
1863 (18,631)
i»0j 43 5?
7.FS- 39 |
JH/S 5« 108 15W 250
(18,631) MBS 137
liBi "* 57
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y.FSJ 39 ""j 44 5i [?2 / 5 97 112
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XFSJ ^MJB/'f ,_, 18T
H/Z ' 50 ' 100 ' 158 ' 209 ' 250
(919) 544-5729
Instrument ' II
NilS
73728

Hits : 137 Searched
49152
' ' t ' "• ' ' 1 ' ' * - I * ' " ' I
C13H20 255
255
C19H4B
, 4 ,.,,,,.. 1 ,,.-.,.,
255
C13H28
380 350
in
in
CM







-------
;i.:-:* .' • / .-"."'.":•-:• • - ".•:• xx •:••;• ••- x :•:.-.. .'• •-•.-:.:•.-:-••-:-.
•:•:••. .• -•;•.. ,x •:•-:•.:• :••: 	 :-.::-..-•.-•.-.•:•..-.•.•:•::••.• .••.•: •.:•...•.•:•.•::.:•.•::.:.•-•.-•>..•.
Project Number 42284
Sample File: HS366
Client Project: 5487*003
TDID:173-46-8A,B

Sample
Date Reoaved: 06/30/97
Date Analyzed : 07/09/9?
pi!;! |||ipiiii:li|p;i|
iSllilSPIiillpi^H;:
... . — . . .,. . ....... ... --_- -• ••••
Method 8240A VOST
ID: VOST-2 SET 3 TUBEAyB T/TC
Response
Pile: ICALH7Q8


Analyte
/" ^ "" •. f ^ V
Bromochloromcthane
Chloromethane
Vinyl Chloride
1,3-Butadicnc
Bromomethane
Chloroe thane
Vinyl bromide
Trichlorofluoromechane
1,1-Dichloroethene
[odomethane
Carboa disulfide
Acetone
Allyl chloride
Methylene chloride
trans- 1 ,2-Dichlorocthene
tert-Butyl methyl ether
Acrylonitrilc
n-Hexane
1 ,1 -Dichloroethane
,2-Epoxybutane
cis-1 ,2-Dichloroethene
Chloroform
1 ,2-Dichloroetharie
Isooctane
1 ,4-Difluorobenzene
Vinyl acetate
• • • •• Ambatti" ' FLAG ' : RT" ;:
/ , \,;,- , Bg<- „-;;; • :.rr •;;;_"• ;;: := ^
IS 1 4.48
0.099 0.92
U
0.114 1.07
0.013 J 1.40
U
U
0.044 J 1.81
U
U
0.396 2.47
0.068 B 2.54
U
0.206 B 2.94
U
U
U
0.119 3.54
U
U
U
U
U
U
IS 2 5.63
U
Dcfclamit
* ' *• -•
« . »••:.


0.001


0.001
0.001

0.001
0.001


0.001

0.001
0.001
0.003

0.001
0.003
0.001
0.001
0.001
0.001

0.001
Quan. Luuit
-. •.!••.'!• H-O1
...... "9 *

0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05

0.05
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E Estimated- Above Calibration Range
Triangle Laboratories of RTP, Inc.
801 Capitula Drive • Durham, North Carolina 27713
Phone: (919) 544-3729 • Fax: (919) 544-5491
              Savar v3.5
Printed: 15:02 07/22/1997
-------
                                                            lelllcisi
Project Number 42284
Sample File: HS366
                      Method 8240A VOST
Sample ID: VOST-2 SET 3 TUBEA/B T/TC
_•,., ...:....;.....-. ^.. ' :'- v ::: ':':V:',;: •;'":- ":'::::':;": :•:;"; :V-T:: i'^'VtV^'^V:^^-:-^;^:^:':'.^"':"^"-:-1^^''.'"
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' A "»']i'jiiii",j^:' ':'.''•"'''.':-*' ^'--' -'-"-•" •--•': -":::-r- "':'':;"::::':': ::: ;-:•;-;-;•:•: :-t '••'•i*;";-;'?;V:':';'-"--:¥:'-':';::';''v!$;;-;-:
./::.\:-;^:;-|4'?>vr.;v:.';:i.;. .|i .••.>;:•:; ^;.;::A-.;>;;,vX -^^Ajjiytytv;; >:• ; V •vS!:!:!vX$i$:v!v;:xVi1;'-'XtvX:.'
2-Butanone
1 ,1 , 1-Trichloroechine
Carbon tetrachloridc
Benzene
Trichloroethene
1 ,2-DichIoropropane
Ethyl acrykte
Methyl methacrylate
BromodicMorotnethane
cis-1 ,3-Dichloropropene
trans-1 ,3-Dichloropropene
1,1 ,2-Trichloroethane
DibromocUoromediane
Ethylene dibromide
Bromoform
Chlorobenzenc-d
4-Mcthyl-2-pentanone
Toluene
Tetrachloroethene
2-Hexanone
Chlorobenzene
Ethylbenzcnc
m-/p-Xylene
o-Xylene
Sryrene
1 »1 ,2,2-Tetrachloroetrtane



liliiiii
u
u
u
0.948 B 5.11
U
U
U
0.077 6.46
U
U
U
U
U
U
U
IS 3 9.75
U
0.314 B 7.57
U
U
0.003 J 9.80
0.050 10.09
0.114 10.32
0.048 J 11.03
0.239 1 1 .08
U




0.006
0.001
0.001

0.001
0.001
0.001

0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001

0.001
0.001





0.001




0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0,05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.10
0.05
0.05
0.05
                        NA- Not Applicable; Det Limit Detection Limit; O.uan. Limit Qiuntitation Limit
    IS: Internal Standard; U: Undetected; B; Present In Blank; J; Estimated- Below Quanritarion Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive » Durham, North Carolina 27713
Phone: (919) S44-5729 • Fax: (919) 544-5491
                                       Savarv3.5
                           Printed: 15:02 07/22/1997
                                       257
-------

Project Number: 42284
Sample File: HS366
iiMiliyi^il^illllll^
JViiSiKi :-.-;!.:; 3f|i.a«s:5S S-SS s-^x»:::< -.::::i :«««•:••.<•«:«:>
Kj:;c:;;:y:::::::o:.o:;:;oj:;5;:::::^

Sample ID:
|J|||fl||||WI|;:^^
Method 8240A VOST
VOST-2 SET 3 TUBEA/B T/TC



li^SSssiilS.'^?^^-!^^^!^-? §»?Kr-SPfl?t:;:K::?°h
Cumcnc
i5^i.is:jS5::'£Si(?:SX.S:'!dS:^SM^:'SS;sfe¥s;;sSS^s
S^y;;;:;:§5:j|J#»|«sSii8^!i:lSV;?l SPy *SfS
1 ,2-Dichloroethanc-d
4
Bcnzcne-d
Tolucne-d

0,004 J

0,232
0.265
0.292
3ft«yp8MiifrK:
11.80

5.08
5.06
7.48

0.05

1 93
2 106
3 117
Reviewed by
                            NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit Quantitation Limit
     IS: Internal Standard; U; Undetected; B: Tresent In Blank; J; Estimated- Below Quantitaiion Limit fc Estimated- Abovt Calibration Range
Triangle Laboratory* of RIP, Inc
801 Capitola Drive * Durham, North Carolina 27713
Phone (919) 544-5729 « Fax; (919) 544-5491
             SavarvS.5
Printed: 15:02 07/22/1997
                                                                                                                     258
-------
                                  PaclfSc Environmental Services
Project Number. 42284
Sample File:     HS366
Method 8240A
Sample ID:
VOST-2 SET 3 TUBE A/B T/TC
Client Project:
TLIID:

S407-003
173-46-8A,B


Dilution Factor:
Date Received:
Date Analyzed:
1.00
06/30/97
07/09/97

                             Tentatively Identified Compounds

Unknown
C4H8 isomer
Pentane
C5H8 Isomer
Methyl Propane Isomer
Methylbutane Isomer
Hexamethylcyclotrisiloxane
C6H12 Isomer
Alkene
C13H28 Isomer

0.711
1.001
1.920
2.180
0.851
1.600
8.661
3.441
9.151
10.621

17568126
7835286
6105392
5837587
4073988
4001037
8895099
3207264
5438555
4097470
:J30f$iil
4.481
4.481
4.481
4.481
4.481
4.481
9.751
4.481
9.751
9.751
llsiSift^iiill
4480785
4480785
4480785
4480785
4480785
4480785
10025194
4480785
10025194
10025194
ii^iiiiiBiisl
0.980
0.437
0.341
0.326
0.227
0.223
0.222
0.179
0.136
0.102
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 * Fax: (919) 544-5491
                     Printed:   11:29  07/25/97
                                                                                    259
-------
                                                                                       o
                                                                                       CO
                                                                                       CM
          13:45         Triangle Laboratories of IIP. Inc.
        MOST-2 SET 3 TUBEA/B  f/TC  173-4&-8A/B  TLIM2284
                                (919J 544-5729
                                  Iiistnment H
H83GG
MFS -
  9
                  5-10
                     5.^3
4.8
                       6.8
                                :&
8.8
                                                                              #1
                                                                        15.92
16.0
                                                                                     r-
                                                                                     cr
                                                 "gr
                                                 cz
                                                 O fl)
                                                  B
                                                  Q
-------
JAN  06 .:  HC366

•Jo..  MAT FOP REV  Delta
Area P.Flag
Qh Name
1
2
o
4
5
6
-,

3
9
10
1 1
JL-L
12
13
14
15
16
17
18
19
20
21
22
23
25
26
28
29
30
-ft

•~r-r
O W
34
35
36
37
-r^
— OC3
TO
^ ,-
40
41
42
43
44
45
46
47

49
50
100
100
100
56
1OO
1OO
1 — *

100
99
0
i nn
JLUU
86
0
0
86
0
0
100
84
0
100
0
0
100
0
0
0
0

~7 O


0
0
100
0
^>r»

A £
\ c
100
0
0
0
0
0
0
0
C "7
100
0
91
92
96
21
81
90


88
76
0
"7 A
t H
46
0
0
53
0
0
85
53
0
77
O
0
98
0
0
0
O

TO


0
0
93
0
1 *

"6

90
0
0
0
0
0
0
0
K
94
0
99
97
98
68
82
9'?
-r f-.

94
83
0
1 nr\
JUJW
93
0
0
92
0
0
99
81
0
94
0
0
-r-r
100
o
r p
0
0
0
t~ /•
^


0
0
100
0
~7 S
w \-^
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96
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99
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— 3
1
0
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2
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0
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-1
0
0
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0
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0
w 1
0
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v_. 1
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0
0
0
/
00


0
0
J_
0
T
w
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. —
0
0
0
0
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0
0
0
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1
0
3c2816
2098516
2713820
90S5O4
25717O8
360O388
i ^i 1 ^ /-

1746OO3
300848
0
x< /i - .- 1 r-,'-.
41056
0
0
1S542S
0
0
3622600
129626
0
590356
0
O
1 TO n ->
807072
0
0
0
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0
0
10079710
0
-y — ' ^
N_/ / ^_
O yf T"7 ^
— 1 -w r C-
156404
0
0
0
0
0
0
0
6 ~ 5 -1 -1
2523916
0
bb
bb
bv
bv
bv
bv
^

vv
vv

^\ i . j I O f O
bb


bb


bv
bv

bv

Sh
bb










bv

U I*
oo 	
/y

bb







A
bv

4
5
9
5
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1 -^

12
O
0

1
0
0
1
0
0
2
2
0
2
0
0
3
0
0
0
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r-
-i-


0
0
5
0
,'
w
£
^
6
0
0
0
0
0
0
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7
0
.4R
. 63
. 7 5
. OS
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.03
.. 92
.00
OCI.CT7
.40
.00
.00
.31
.00
.00
.47
.54
.00
.94
.00
.00
.54
.00
.00
.00
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—r r*
*"
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.00
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.00
no

°1

.46
.00
.00
.00
.00
.00
.00
.00
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.57
.00
1 '? 8
1L4
117
65
8-4
98
98
95
5O
62
•7TQ
\J 7
94
64
106
101
96
142
76
43
76
84
96
73
57
63
A^>
M .£
96
83
62


- 72
97
117
78
130
63
55
69
83
75
75
97
129
107
173
A-Z,
M \J
92
164
B i'onioc h 1 or ome t ha r\v
1 ., 4-D i. f 1 uorobenzene
Chi c.) r- o h e n z e n e — d 5
1 , 2-D.ichloroe thane-d--i
Benzen2-d6
Toluene-d3 — -v
o-Xy 1 e ne-dlO (^A^
4-8fornof 1 uoroberiiiane
Chlororne thane
Vinyl Chloride -^
1 "" — Ri t-arli pn^rf^ffiV^
Bromornethane
Chloroethane
Vinyl bromide
Trichlorofl uor ome thane
1 ,1-Dichloroethene
lodomethane
Carbon disulfide
Acetone
Allyl chloride
Methylsne chloride





















trans-l,2-Dichloroethene
tert-Butyl methyl ethe
n-Hexane
1,1-Oichloroethane -^
10 «.C^ r\(~»\x \y k> i 1 1" a n d/^^jrlf\ \~J
i £. cipoxyD u ua n ^pp^/\u^*^
cis-l,2-Dichloroethene
Chloroform
1, 2-D i chl or oe thane
T ^- ^^v +•
j.ooocuane v ^^
2-Butanone /
1,1,1-Trichloroe thane
Carbon tetrachloride
Benzene
Trichloroetherie
1,2-Dichloropropan^/^fc
Ethyl acrylate /t^"
Methyl methacrylate
Bromodichloromethane
r












•D
^^^


cis-1 ,3-Dichloropropene
trans-1, 3-0 i chl orop r open
1,1,2-Tr i chl o roe thane
Dibromochlorome thane
Ethylene dibromide
Bromof orm
,-l™lv{tfa*t~K\yl "7 	 r>c^i-i1~arn-~ii-^ c/^*/5
Tol uene
Tetrachloroethene




vT
3u

                        Data Review:
                        Date:
                                                                       261
-------
No. MAT FOR REV Delta
                    RT
                           C3M  Name

52
53
54
55
.r>6

47
10O
100
95
10O

.16
89
87
75
94

63
99
9 a
00
98

1
1
0
2
2

37108
278736
791480
320640
262030S

'Ob
bV
vv
by
bv

9
1C
10
11
11

. SO
. O9
. 32
,03
, OB

112
106
-06
1O6
104
*? Hfx 3i 10 nt^nfw*
C h i o r obe nze rie
Ethylbenzene
m~/D-Xylone
o-Xylene
Styrans
1 1 1 ?—Tcai-l-a<-hl ,", rr,o
  38  70  41
95144 bV
11,30
-------
en
CO
CM
07-09-97 13:45 Triangle Laboratories of RIP, Inc. (919) 544-5729
Sanple: WST-2 SET 3 TUBEA/B T/TC 173-46-8A/B TLIW42284 Instrument H
92 (B.928)
188-
XFS -
8-
5
4-4

•-j
5
8 59392
52
j 65
8 150 200 256 308 350
iSliiS6"92 (8.921) REFINE
100-
XFS -
B
M/Z
5
"^
49
8 50432
52
50 100 150 200 250 380 350
HT2CAA 9 (0.938) Ch loronetliane FIND
180-
XFS -
B-
M/S
5

44
B 180
52

58 lee 150 200 250 300 350









-------
                                                                                       CD
                                                                                       Cl
89-Ju1-97 13'.45         Triangle Laboratories of RIP, Inc.
Sample: VOST-2 SET 3 TUBEA/B  T/1C  173-46-8A/B  TLW42284
(919) 544-5729
  Instrument H
HS366 107 (1.070)
108-
X.FS-
0-
w/z
3

ol
9 83968
54

ilj . .IILr .
50 ' 108 150 ' 200 ' 258 ' 300 350
HS366'107 (1.071) REFINE
108
0-
tt/Z
5
53
\
5&
4 63744

50 ' 100 ' 150 ' 280 ' 258 ' 380 350
MASTER 11 (1.440) 1,3-Butadiene FIND
100
8-
n/z
3

9
5
58
108
4

50 ' 188 ' 150 ' 288 ' 250 ' 380 ' 358
-------
                    10
                    CD
oV-My-97  13:45         Triangle Laboratories of IIP, Inc.
  ««ie: WST-Z SET 3 TUBEA/B  T/TC  173-46-8A/B  TLII42284
(919) 544-5729
  Instrument H
148 (1.480)
1JV,_ 44 28224
1
XFS-
0
H/"Z
*
79 93
t, , it J
1
56 103 150 200 250 300 350
HS366Ji4i (1.4U1) REFINE
1B8-
X.FS-;
0.
9
93
79 --
4.1 if ,
4 6848


50 100 150 208 250 300 350
NfZCAA 12 (1.420) Brononethane FIND
IBB:
X.FS -
0-
H/Z
9-
93
4,8 /6 fi1 j
4 100


50 108 150 230 250 300 350
-------
                                                                                        CD
                                                                                        CD
                                                                                        CM
i7-lfj-597  13=45          Triangle Laboratories of RIP,  Inc.
Sanple:        SET 3           T/IC  173-46-8A/B
(919) 544-5729
  Instrument H
U=-='JtxC 1Q1 M D1H»
rltjsjoo JLoJ. \i,olD/
109-
V.FK-
9-
1C
T
a"
' ce. Ta
! Dt3- 13
11 24328
183

105
i
58 15O 200 250 380 358
HS36fa'18i (1.811) REFINE
100-
0-
11
47 S6
L 1, 8,?
U 22272
193
105
56 158 280 25© 368 35®
15 (1,840) Irichlorof luoronethane FIND
i P=l-, A3 <*3
11 100
1S3
105
58 188 15O 200 250 388 350
-------
                                                                                     CD
H7--09-97  13:45          Triangle Laboratories of RIP,  Inc.
     e: WST-2 SET 3 fUBErt/B  T/TC  173-4&-8A/B  TLIIH2284
(919) 544-5729
  Instrument H
247 (2.478)
7
XFS -
: 44
g'. 	 ir.514,Z
6

78
I, .... . . ..
H'Z 58 ' 108 ' 158 ' 208
H3366'247 (2.471) REFINE
1B01 7
X.FS-
: €4
«,,..!„ 5,3 4. 7
6

78
1 ... ....
M/Z 58 ' 100 ' 15B ' 200
IB (2.508) Carbon disulf ide
180] ?S
J
i
XFS 1
BS.4'4


78
M/Z 58 109 150 200

659456


250 300 350

647168


250 380 350
FIND
lee



150 308 350
-------
oo
CD
CM
Q7-R9-'J7 13:45 Triangle Laboratories of RIP, Inc. (919) 544-5729
Sample: U03I 2 SET 3 TUBEA/B I/ 1C 173-4G-8A/B IIJtt42284 Instrument H
254 (2.540)
76 19712
1001 *°
43
1
%FS-j

S Hf,
44

58 78
, i 6,7 (
H/Z 5O 188 158 208 250 300 350
HS36faJ254 (2.541) REFINE
iSS^
•/.FS-

;
3 12868

58

H/Z 58 ' 168 ' ISO ^^ ~" 208 ' 258 ' 3BB ' 358
NT2CAA I1? (2.578) Acetone FIND
. „„ 41 iee
1801
i
i
•l
***]

r.





53
44
H/S 56 109 158 200 258 3BB 358

























-------
CTJ
CO
c-i
13:45 Triangle Laboratories of RIP., Inc. (919) 544-5729
Sanple: UOST-2 SE1 3 IUBEA/B T/TG 173-46-8A/B TLIft42284 Instrument H
294 (2.94B)
dQ 158720
108-

XFS-


rt
,*




I

84
51
' 55
/ 71
l ..!,, , .ll.

88

.1
H/Z 50 100 150 200 250 308 350
HS366'294 (2.941) REFINE
n* 158720
109i

«jjF*J-



0-



47

,


84
51

' 55
?e
«. i i


88


••11,......, , . , , . . , .... , . . , . , . . , . . . , ....,..,, j . . , . , . . .... . . . , . . . . ,
H/Z 58 180 150 268 250 300 350
21 (2.978) Methyl ene chloride FIND
1BB|
XFS-

g '


47
- "V"*
84
51
1 83
j X

88
i
H/Z 50 ' 1@9 ' 150 ' 208 ' 250 ' 300 ' 350

























-------
                                                                                      o
                                                                                      is.
                                                                                      CM
67-69-57  13:45          friangle Laboratories of  RIP,  Inc.
Sample: WST-2 SET 3           I/TC  173-46-8A/B  TLIf42204
(919) 544-5729
  Instrument H
354 (3.548)
108-

B-
H/Z
_!-,-*-•»»„,.»
HU3t
180-
xrs-
B-
f*/'Z
5
d*

I
1"
4-
56
55
7 103424

IV *?
53 109 153 200 258 300 350
'354 (3.541) REFINE
5
4
4
3
"56
44
!--"
7 95232

/87,1 8|&
SB 188 158 200 250 309 356
HT2CM 25 (3.570) n-Hexane FIND
1WH1
y;FS-
0-
5


56
35
7 180

?! ¥
50 188 15i 280 250 300 350
-------
                                                                                     CM
87-09-97  13:45          Triangle Laboratories of IIP,  Inc.
Sanple: WST-2 SET  3 IUBEA/B  1/TC  173-4&-8A/B  TLI842284
(919) 544-5729
  Instrument H
511 (5.111)
188i ?
Xil? S " TT
: si 7\
g:j 	 |r. ,$£_,
8
84
M^K "SB ' ' iee ''•''' j^g '
HS36b"5il (5.111) REFIHE
r» ?
"FS: 5jf_7^
8
79
i.
w^z 50 100 158
36 (5,131) Benzene
1801 7
52 "-•
g „ .1. 6..3 .,,
8
79
.'
*J * - " ! ' ' ' ' 1 • • • • i ' • ' ' ' I • • " • 1 • '
»/s 58 100 150

1474560

200 250 360 350

1409024

200 250 300 350
FIND
100


200 250 300 350
-------
                                                                                     CM
87-89-97  13:45         Triangle Laboratories of RIP,  Inc.
Sawple: MOSf-2 SEI 3 TUBEA/B   T/TC  173-46-OA/B  TLIi4Z284
(919) 544-5729
  Instrument H
646 (6.461)
tea-

XFS -
_e-
4


J
LL 26880
b.9

*„ !-ll«I .1,

L .Ti1, ,lf
58 188 150 208 25G 368 358
HS366'646 (6.461) REFINE
19^
J'.FS -
,0-
4

.

1 21760
b
«
Q
7O 100
58 166 158 208 259 388 35(3
NT2CM 48 (6.491) Methyl met haery late FIND
1B9-J

0-
;M/2
4

-i
t 188
b
42 59
3
;08|5 1f8
59 188 158 200 258 388 350
-------
                                                                                      CO
87-09-97  13:45          Triangle Laboratories of RTF, Inc.
Sanple: WST-2 SEf  3 fUBEA/B  T/TC  173-4&-8A/B  TLIM2284
(9193 544-5729
  Instrunent H
757 (7.571)
100-

XFS-
R-
l«/z
9


39
/ si 65 «x
,,i!..-.f. ..li^t™ ji!,l,,..j .'i-jf. n »|^, 1,
1
92

93
58 150 288 250 388
H8366'757 (7.571) REFINE
188-

M/Z
f

39
1
92
93
58 100 158 288 258 388
HT2CAA 49 (7.681) Toluene
18ii

HFS-
e-
!*S/Z
9


39
f' 5.1 |5 &9-,
1
92

93
SB 180 158 288 258 388

565248



• i • i • • i
358

512880


"' '! "' 	 ' ' ' "'1
358
FIND
108



358
-------
89-Ju1-97 13:45         triangle Laboratories of RTF,  Inc.
Sample: UOST-2 SET 3 TUBEA/B  T/TC  173-46-BA/B  TLUW2284
(919)  544-5729
  Instrument H
HS366 979 (9.791)
100-1

XFS-
8
M/Z


A n
Tin
5

1
82
5,4
u 	 ,M,
0

j.7 181248

119
.1 1 .
100 ' 150 ' 200 ' 250 ' 300 ' 350
HS366'979 (9.791) KEFINE
100*
XFS-
e
M/Z


7

7

	 i •
50
i:

2 4096
114
'
100 ' 150 ' 200 ' 250 ' 300 ' 350
RASTER 58 (18.950) Cli lorobenzene FIND
1001

y.FS-
0
M/Z

5
AB i

77
L74:-,

i ," i ^ . , . . , .
50
1:

i- _«
2 100

114
100 ' 158 ' 200 ' 250 ' 300 ' 358
-------
                                                                                     in
87-09-97  13:45          Triangle Laboratories of  BTP,  Inc.
Sample: WST-2 SET  3 TUBEA/B  T/TC  173-46-8A/B  TLIM2284
(919) 544-5729
  Instrument H
1889 (18, §91)
188-1 9
>;FS i

51 65 77
o ..Li., jl. ,,- .i|..T Tllt.... ,
1

186
T
... ,i..

w/z 5B 10® 158 208
HS366MB89 (10=191) REFIHE
188-j f
XFS -

51 65 77
a ,.). . i, .. ,4.. !l,, , .
i

106
T


H/Z 58 160 150 200
NfZCAA 53 (10.131) Ethylbenzene
imi 9
^FS-
Si 65 77
g 1 .1. . ^. .4 . .(.l|, _„
i
106
|107
1 .*if;
»/z 58 ' 160 ' 158 ' " 288

188544





258 388 358

93184




• -.•!•---!•-•-!•-- i • - - • |
250 380 350
FIND
100



258 300 358
-------
                                                                                       .CD
CO—l-i
7-69-97  13:45
Triangle Laboratories of RIP, Inc.
Sample: UQST-2 SET 3  TUBEA/B  T/TC  173-46-8A/B  TLItt42284
(019) 544-577,9
  Instalment H
1B32 (18.321)
«»l 196464
1881
XFS-





OQ
^ ^ '(if
., .!. . .lit.... J.I 	 lil 	 ,

IBS
1
?2 i 10?
i 	 illt....
	 < r—j 	 , 	 -,—, , 	 j , ,— _T 	 r-—^ 	 , 	 . 	 r—t 	 ^, 	 __, 	 ,, 	 j 	 1 	 *~ -' 	 ' 	 * 	 ...J.-T 	 . «— T— j -= -. r ,— | -*— , — T- r ,--, ---T- ,I.,,.|.-.-(»-.-|
M/S ^y 188 150 200 250 360 350
HS366'1032 (IB. 321) REFINE
,__ Q1 163840
1801
>'FS:

0-


39 51
•"•' -''" fi 7,7
	 L . l|" ...... In,,.. ITlf

186
92 Jie7
B ••'
i . . .ill;.

M^Z 58 1O0 150 200 250 300 350
54 (10.371) m-/p-Mylene FIND
9
~J" j
xFS-i „
*^ c. Q
i ••' " •-. 7 r
j *»Q . ': 1.

. ... •-"». .11.. 1 ...!i, .,
1 100

186
92

.1! . . . . -
— *~— *. p~» - — • T-^ • * ' 	 j 	 1 	 • — ' 	 ' — I 	 ' 	 ' 	 ^ 	 ' — | 	 * — • 	 < — ' 	 1 — • T-* *—i ' • * •— y— • - ' • j ^ •-- -- • -f 	 •- - ^ * i - ---- • j • - - ' i
»/z 58 160 158 288 250 308 350
-------
07-09-97  13:45          Triangle Laboratories of RIP, Inc.
Sample: UOST-2 SET 3 fUBEA/B  I/TC  173-46-8A/B  TLIM2284
(919) 544-5729
  Instrument H
1183 (11.831)
100-

XFS-
8-
M/*Z
1£
91
v 78
i tf *7Q
1 63*" *
.1... .1..,.. l|...r,,,i|'i I,...,..,
i
92
( 1
14 107520

166

50 100 150 200 250 300 350
HS366'1183 (11.831) REFINE
100-
XFS -
,0-
9


1 65536
K
92
i .
36
107
/
5B 188 158 200 250 300 350
55 (11.871) o-Xylene FIND
100-
XFS-
0-
y
39 51
•-"" ••••' ts 77
j i j o3
.,if..l |h, ,1.1. ... h _, ,
~*
1B6
92 |107
r ,!!/
50 1O3 150 200 250 300 350
-------
                                                                                        oc
                                                                                        r-
                                                                                        CN
87-69-97  13:45          Triangle Laboratories of RTF,  Inc.
     e: WST-2 SET 3  TUBEA/B  T/TC  173-46-8A/B  TLIIT42284
(919) 544-5729
  Jnstruwent H
1198 (11.BB1)
100-


>.rf b



1<
103
78
51

i 63
...I..- .1 	 A, 	 !,;


i^ |
___ j 	
34 307268



105

,
M/Z 50 100 150 200 250 300 350
HS366J118y 111. BUD REFINE
x ~« I *
1E8-

XFf»-


8-

103
7
51

•!.. . .!.. ,.>\. 	 lii
8

102
,. -.£.9 . "i
}4 270336




185
i . .
H/Z 50 ' 188 ' 150 ' ' ' ' 200 " 250 ' ' ' 300 ' 350
56 (11.121) Styreno FIND
tew.

y.FS-

Q
11
103

5ii 76?
1 I i '''i
~ 182
89
14 108


IBS

w^z SO 100 ' 150 ' 200 ' 250 ' 388 350
-------
07 89-9?  13:45          Triangle Laboratories of RIP, Inc.
Sanple: UQST-2 SET  3 TUBEA/B  T/TC  173-4&-8A/B  TL1M2284
(919) 544-5729
  Instrument H
1180 (11.881)
100-
X.FS -
9-
M/Z
11
41 57
i 6979
III 91
35 9152
120
Iiii 1
59 100 150 zee zse 300 350
HS366'1188 (11.881) REFINE
188-
X.FS -
8-
H/Z
li

S3 „.-, 85
58 \S9 ** / 98
u.i ffj I..A. . ,,i fi i
15 7046

186
/ 120
• • ill! .1 .1 , 	 . i 1 • i i « ( < • " ' I ' ...(.-.. | . • . • ] . . . • | .- • • • ] ......... |
58 108 158 250 300 350
58 (11.851) Cunene FIND
160-
XFS -
0-
K/Z
11

77 103S
i. Jr ..&.? .,|.| I
15 100

120
se lee 153 zee 250 300 350
-------
               o
               oo
               CM
09-Jui-97 13:45         friable Laboratories of RIP,  Inc.
Sample: MOSI-2 SET 3 TUBEA/B  T/TC  173-46-8A/B  TLW42284
(919) 544-5729
  Instrument H
HS366 71
18B]«
XFS'I
2-jm^-r-,
w/z 50
HS3&6J71
1001
XFSJ
01
tfl F;50
1001
XFSJ
01,., 	 „,, 	 ,,.
412 F:48
1001
XFS-I3 |4
#3 F:46
100-
0 :_,-,„„„ 	 	
(8.718)
60 659456
100 ' 150 ' 200 ' 258 ' 380 ' 350
(8.711) REFINE UBS 68 Hits : 68 Searched
60 753664
38^r3 ,« «r
1 618:3-1
39
6 12997:2
39 '
M^EJI •
5 609:2-1
39
HJTENOIC ACID
.4J. 255
f42 5557 60 ._ 72 85 /'
l4i ,\ !| /. b»?.,/' M
t-PROPENE-l^-DIOL, 2-METHYL-, DI ACETATE
12 7a 255
T 45 78
/ 60 69 71
, ..... r6iV<. . , .. 14-2 , 130 ...
1 ••]'-' * .... 1 . 4 ,, ... 1 ,, J . 1 , ... 1 , 1 . 1 .,. t .. | .................. 1 ,...,,.
HJTENOIC ACID, (2)-
41 255
42 *z<* tisGflftS?! nJ86
X 3p%f %J%>y « * o D
tl . .. ^ {. .. \ i I'l N "87
„ ,,,...,.-..,..,. ... ( .... | ... . . . . ( . , .,...., ..... ... ,., 	 ..., ,...,,...,,,..,....,,,..,....,,
M/Z 20 40 60 80 100 120 140 160 180
-------
                                                                                  oo
                                                                                  Cvl
89-Ju 1-97 13:45         Triangle Laboratories of RTP, Inc.
Sample:  UOST-2 SET 3 TUBEA/B  T/TC  173-46-8A/B  ILI842284
                                                                  (919) 544-5729
                                                                    Instrument H
      108 (1.080)

XFS
  0
                                                                          397312
      58
                  180
  150
             200
       250
          3O0
            350
HS3&&'1BB (1.801)  REFINE
XFS-
  0
                        37 3?
 41
 ft
                                                      NBS 58 Hits  : 58  Searched
                                                                         385024
 #1  F:719   552:i-PENTENE, 4-METHVL

180-                           *3
XFS

  0
    44        5,6
    "   m. ,||.5,8
                                     t"-p'l"
                                                                            255
, ,¥, 	 2
.728 39 T.
1- . t i., ., ... , . i 1 t-1 	
44
T"
84
     F:715   71<3:l-BUTftNAMINE,  2-HETHVL-
100
XFS^
  0
                        37
                                                                             255
   / ...

                                              8
     F:710   809:HVDROXVLAMINE, O-(2-MEfH¥LPROPVL>-
1001
XFS
  0
M/Z
•1
                           3? i i
                                                                             255
                                 44
                                          g55758
                          70, ,72
                                               -r
          20
                   30
40
         50
60
70
80
90
-------
                OJ
                00
                CM
97    O;4rt        Triangle  1 -iteratories of IIP,  Inc.
: WSf-2 SET 3 TUBEtl/B  T/IC  173-46-8A/B  TL!lt4Z284
(919) 544-5729
 I list-runeni^ II
ipjp-i^r S €J-"7 f4
i0a-j 4
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3 i1
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if 5? ¥"* : *^ 51 ft 1
l"na, " " " 4
A TJ =.f 1
Q ^ ^-i- ••"•*
tt3 lr;724 6
niei 4
-------
                                                                                  en
                                                                                  oo
                                                                                  CM
0V/W97    13:45        Triangle Laboratories of RfP,  Inc.

&mrie:  UOST-2 SET 3 TUBEA/B  T/TC  173-46-8A/B  TLI«t4Z284
(919) 544-5729

 Instrument *  H
2
180-
XFS
« J 	
M/Z
1= 3j"a-~t.~ ," ? •""
i-1>=rfm-» /•
1 	 -
XFS-
13 J
M. | i:1 »
ar,-. !"• :
>;FS -
0._
108
il •
If 3 F:
18Bl
XFS-I
ql__
:m (2.188)
"' 53
37 ,5 A 65
.'ilBli. ..!!-.! ....It
/ Q '
'.. 0 -i-
NBS
181376
	 '' i • "' 	 '"" ' { • ' ' '"' ' i • •' 	 ' ''"I •"•* 	 ' 	 ' I1 • "'«• - ' | • * •' ' | ' ' ' ' ( • • ' ' | • ' • - i ' - ' • 1 ' ' ' ' 1 • •"" • •••'"•• 1
5g 108 153 200 150
:te (2.18D '
1™.
39 53
37 J51 65
._, ^M >t. ».
*!i 9 O i s ^ - 1 « t
? JL«J JL C £; • 1. f
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If" i= 1" -•** er •«
fit? / :' -Jl
9S7 174:1,
-6
^__ 39 ^3
"ft:f i j"4,
NBS 33 Hits : 33 Searched
7 983O4
1
|69
3-BUIftDlEHE, 2-HETHVL-
;67 C5H8
X
3 - PETIT A L*I EHE, C Z) -
7 CiH8
9 93 178:1,4- PEMT A D I ENE
27 39 53b'1 C5H«
2^l ll .1 F9
• • i - • - • i
255
255
.,..,.,. .--,
255
50 1436 150 200 250 308 350
-------
                                                                                  oo
89-JuF9? 13:45         Triangle Laboratories of RTF, Inc.
Sanple: MOSI-2 SET 3 TUBEA/B  T/TC  173-46-8A/B  fLI«42284
                                                                  (919) 544-5729
                                                                    Instrument H
HS36& 85 (0.858)
     4.3
188:
      44
                                                                          183296
M/Z   50
                  180
                              ISO
                200
         250
              300
                                                                            358
HS366'85  (8.851)  REFINE
                     II
                                                    NBS 148 Hits :  148 Searched
                                                                        17920e
  0-
 #1
188:
XFS^
  0
                              57
            1612:HVDROXVLAMINE,  - O-METHVLBUTYD-
                                     771
                                                                            255
                   '•r*-»-"	r1
             4J
     FI624  4351:PENTftNE, 1-C2-PROPENVLOX«)-
100
y.F$l
  0
 #3
1001
XFSJ
  01	
«/z   20
                   4.1
                      -43
                               58
                                                                            255
     FI621  652:2-PENTANONE
                     43
                                 59   6? J8
                                 /     Nrl.
                                                                            255
             38
                   40
50
                                60
>1'|
-------
in
00
13:45 Triangle Laboratories of RfP, Inc. (919) 544-5729
Sample: MOSf-2 SET 3 T/TC 173-46-8A/B ILIH42284 Instrunent: H
HS3&S 168 (1
18°1 .-J
xFSJ J<,
fJ I
NBS
,3 111616
ET ="3!
55' "
••--., 7 •?_
^ * •""""" '""' 	 1 ••''•,'•••• 1 .... j .... , . . . i j . ...... . , . . ...- . , . , , 	 , | ., i . ( .. ,.,....,....,. 	 	 	 , t
M/Z 50 1OB 158 288 258 388 358
!!33bvib0 (1
1 BH'j '
..™1 39 j
^P^l \j
10W-1 4l1
X.FS-i 3\
91.
- - • i • • '
»2 F:?42 1
>;FS -j
»1 I,
f3 F=739 1
iP«T 4
.*_ «J 5-? •
XFS: 27 29 _
8 j.ii, . j,l
MBS 242 Hits : 242 Searched
3 106352
E7t
D i"
,. ,.,J. 7,2
09 :t!¥l>KOXYLflHINE, O-C2-HETHYLPROPVD-
3 ^ C4H110N 255
44h58 "M
L..J;: .|r?2
62O: PROPANE f 2-HETHVL-l-HITRO-
L 255
5?
42
j
429 ; 2 , 4-DIMETHVL-
3 255
= *\n C7H16
H/S ' 5O ' J.6S ' 150 ' ' " 298 " ' 258 ' ' 366 ' 356

-------
CD
CO
CJ
157/05/07 13:45 Triangle laboratories of RTF, Inc. (919) 544-5729
xam>le: UOST-2 SET 3 T/TC 173-48-80/1 TL 1 1142284 instrument: If
1 OiSi
1
,J 06 J"ll\ 133 \ 1^1
H --""-'• Ht* 1 QO

HS366'866 (0,661) 1EFIME
NBS
?7 311206
£63
130 288 25Q 366 350
21
177
33 -, 191
«l F:032 22491 : CVCLOIRIS t LOXflNE, HEXAMETHyL-
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33 . 1?1
#3 F: 568 22 1-23 : 1 , S-HI.S CTP.IMETHVLSILVDBEHZiJiE
•-iFS-i 43 ^-_a '|Vl ?8 131
is-* -" ->• "^^S I r*f3t
!«•••• -j 3-s5 Xvie?
HBS 24 Hits : 24 Searched
37 173176
-t ijitj
£* Wtj
97 C6HI803S13 255
208
I LVD ES'l'EP,
r? 255
C9H2703Si3fis
288
-- > us=i

158 ' 283 ' 25« ' 3B8 ' 3HS
-------
                                                                                          oo
                                                                                          CM
89-Ju1-97 13:45          Triangle  Laboratories of  RTF,  Inc.
Sample: MOST-2 SET 3 TUBEA/B   T/TC   173-46-8A/B  TL1842284
                                                                   (919) 544-5729
                                                                     Instrument H
HS366 344 (3.448)
        56
      43
1.00

XFS1

  0
                                                                            83968

                  100
HS366I344 (3.441)  REFINE
               38X   44
                                                       HBS 61 Hits  : 61 Searched
  0
                \
                    I/

                 6769
                  .\.l.
                       84
                        1.
 #1  FI876  426l:2H-P¥RftN-2-ONE, IITRftHVJ>RO-3,S~»IMElHyL-
100T            39 4|^ 43     55
    I          37 "l IK   51 5
                                                                             255
  0-

100:
X.FS
  0
     FJ827  4288!2H-P¥RftN-2-ONE, TIXRflHVDRO-5,6-WHETHVL-,  TRftNS-
                  41        "
                                                                             255
100
  0-
     F:822  559:CVCLOHEXftNE

                            56
                                                                             255
                                               84
                              57
'M""l't»»
   70
"*	*	t	••Hlf
80
    20
           30
40
50
60
90
100    110   120    130
-------
                 00

                 QC
f    i3*4i>          Triangle Laboratories of  IIP., !nc

 UGST--2 SET 3           I/fC   173-46-8A/B   iLIS42284
>n
£.-.*
IT*~H ft i
\JJLJ1


 Instr-iuieiit ;  H
1 CJO -, 4
t r~ -8 i hlTVC1
lolJ nai
H/Z 50 iee 158 200 250 see sse
H53GGJ915 (9.
i^FSl "}
-;-„-,, 4.
iB>5j| »»^ ?Q f
-•-•"• i ai f *-«-',
X £.• ?^ i » f.--' t
151) REFINE HBS 156 Hits : 15C Searclred
3 98384
=M5 : 1-OCTENE, 3 , 7-MMETHVL-
.55 56 76 C18H2H 255
{57 j"71 ft3
ff>; F:821 H37S:l-HEPTENE, 5-METHVL-
iml _ ^ifl5l/L,ni C8H1&
..s-i^ i £,«..-[ »«i« 71 IIJ
•'-v '" i \i*
ct i ,il, J,ll. .„! .,..1 . Jr94
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7941 : I-TETRADECENE
L41 55 255
57/9e:4 9S 11± C14H2«
. .J. J. ..1 . lif98;:' 125 .. - 196
^y's ' 58 ' 108 ' 158' ' ' '288 ' 250 ' " ' '
-------
                 cr>
                 oo
                 ci
B9-Jul-97  13:45         Triangle Laboratories of RTF,  Inc.
Sanple:  MOSf-2  SII 3 TUBEA/B  T/TC  173-46-8A/B  TL1*42284
(919) 544-5729
  Instrument H
HS366 18f
10eiT 5
XFS- 1
0; 4, J
»2 (IB. 621)
i?
i 71 8.5
. ...JiL 	 ii. ...i.. .....
W • ' ' 1 ' • • ' I '• • 	 I ' • •"'
n/z 50 100
HS366' 1B£
1001 A
XFS 39
8 iM
#1 F:83
1001 4
XFS- 39
^
#2 F:82
1001 4J
KFS 39
e: \i
tt3 F:82
1001 4JL4
XFS- 39 x
o: \i

' 150 ' 200
»2 (IB. 621) REFINE
>3
57
56 n. oc;
,. ,.rj|, ,7jf i 9.7 141
5 15627 :DECfiNE, 2,4,6-TRIMETHVL-
13
57
44 58 ||728|386 98
/ .,,,/ .,.,!,!/ .!,!/ ./ . i??
3 15625 IDECANE
Lao
'**& t~ n « ^Lf I
__ 3o If jjc
, 2,6,8-TRINETHVL-
98 99
\/ 113 ,.
1 29829 : HEPIftDECANE, 2,6-DIMET HVL-
13 5i7
44 58 (7283 97 99
I/ .hi/ ..,.!/ "I \/ U2 	
U . , . . . . | 1 . . . , . , T • | I • • I | .... | . . . .
M/Z 40 60 80
1 . . . . , . ...,.,.. | , . , . ( .... | .... | . . . . ,,.,.,.
100 120 140 160
56832
250 300 350
NBS 193 Hits : 193 Searched
37120
255
255
,..j.l..|... .j,'.,!^!. .Jj.Jl.|. ,,,|...,|i ..t|,
255
180 200 220 240 260
-------
                                                llili^^
Project Number 42284
Sample File: HS367


Sample ID
iiillll^
:.-S^:C?v':H;*^aii&^
.... ,.;. .;.:.. .. ;,....... .- .... fc^& r*l'tl**' :'it::-"A:l
$4|.g vy-f: :|.-?^3?|^^^?wl^?^r^WSl?
^::.5.^>:'5j-;:<;g:Vj^^:?4;^

VOST
JT/TC
iWi


Bromochloromethane
Chloromethanc
Vinyl Chloride
1 ,3-Butadienc
Brornomethane
Chloroethane
Vinyl bromide
Trichlorofiuoromethane
1 , 1 -Dichlorocthcne
lodornethane
Carbon disulfidc
Acetone
Ally! chloride
Mechylene chloride
trans-1 ,2-Didilorocthcnc
tert-Butyl methyl ether
Aciyionitrile
n-Hcxane
1 , 1 - Dichlorocthane
1 ,2- Epoxyfautane
cis-l,2-Dich!oroethcnc
Chloroform
1 ,2-DichIorocthane
Ijooctane
1 ,4-Difluorobeniene
Vinyl acetate
^KlSS^SSS^^^^^i^tertS^fellsll
IS1
0.152
U
0.124
0.018 J
0.004 J
U
0.051
U
U
0.742
0.097 B
U
0.232 B
U
U
0.025 J
0.161
U
U
U
U
U
U
IS 2
U

4.47
0.91

1.06
1.39
1.51

1.79


2.46
154

2.94


323
3.53






5-63

|^i^ft|il||l|t|i|i^i


0.001



0.001

0.001
0.001


! 0.002

0.001
0.001


0.001
0.004
0.001
0.001
0.001
0.001

0.001
§11

0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05

0.05
NA- Not Applicable; Det. Limit: Detection Limit; Quan. Limit: Qqantitation Limit
IS: Internal Standard; U:
Undetected; B: Present In Blank; J: Estimated' Below Quantilation Limit;
& Estimated- Above Calibration
Range
Triangle Laboratories of RTF, Inc.
801 Capitoia Drive * Durham, North Carolina 27713
Phone (919) 344-5729 « Fax: (919) 544-5491
            Savarv3.S
Printed: 1623 07/22/1997
                                                                                                         290
-------
                                                                Semcies?
Project Number 42284
Sample File: HS367
                        Method 8240A VOST
Sample ID: VOST-2 SET 4 TUBEA/B T/TC
Client Project S4Q7-003
TO IE>: 173-46-9A3
Date Received: 06/30/97 Response EOe ICALH7Q8
Date Analyzed : 07/09/97


^*» ; ; ; * . •; . ^r^f^i :p ;&;£!*%:• Gf"^'
2-Butanone
1 ,1 ,1-Trichloroethane
Carbon tetrachloride
Benzene
Trichloroethene
1 ,2-Dichloropropane
Ethyl acrylate
Methyl mcthacrylate
BromodichJoromcthane
cis-1 ,3-Dichloropropene
trans-1 ,3-Dichloropropcne
1 ,1 ,2-Trichloroethane
Dibromochloromcthanc
Ethylene dibromidc
Bromoform
Chlorobenzene-d
4-Methyl-2-penianone
Toluene
Tetrachloroethene
2-Hexanonc
Chlorobenzenc
Ethylbenzene
m-/p-Xylene
o-Xylene
Scyrcne
1 ,1 ,2,2-Tetrachloroe thane
0.013 J
U
U
1.246 BE
U
U
U
0.249
U
U
U
U
U
U
U
IS 3
U
0.438 B
0.006 J
U
0.005 J
0.068
0.166
0.065
0.313
U
4.36
0.001
0.001
5.10
0.001
0.001
0.001
6.45
0.001
0.001
0.001
0.001
0.001
0.001
0.001
9.75
0.001
7.56
8.37
0.001
9.79
10.08
10.31
11.02
11.07
0.001
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.10
0.05
005
0.05
                         NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
    IS: Internal Standard; U: Undetected; B: Present In Blank;): Estimated- Below Quantitation Limit; E- Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544^5729 • Fax- (919) 544-5491
                                         Savar v3.5
                             Printed: 16:23 07/22/1997
                                                                                                      291
-------
                                                                Services  ~
Project Number 42284
Sample File: HS367
                        Method 8240A VOST
Sample ID: VOST-2 SET 4 TUBEA/B T/TC
                                                            !:• feiS S iffi-s ^ffiKSilS iiSlll: • ffSymA
                                                            IMititM-'tMtMZ'SZ&l Sg?;'; is;- ;|: p: s
Cumene
                                              0.006  J
  11.80
0.05

1 ,2-Dichloroethane-d
Bcnzene-d
6
Toluene-d

0.235
0.260
0.289

5.08
5.06
7.47



1
2
3
iiif


94
104
116
Reviewed by.
                         NA- Not Applicable; DeL Limit Detection Limit; Quan. Limit: Qmantitation Limit
    IS: Internal Standard; U: Undetected; B: Present In Blank; I: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
801 Capitola Ehive • Durham. North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                        Savar v3.5
                             Printed: 16-23 07/22/1997
                                                                                                     292
-------
                                   Pacific Environmental Sendees
Project Number:  42284
Sample File:      HS367
Method 8240A
Sample ID:
VOST-2 SET 4 TUBEA/B T/TC
Client Project:
TLIID:

S407-003
173-46-9A,B


Dilution Factor:
Date Received:
Date Analyzed:
1.00
06/30/97
07/09/97

                              Tentatively Identified Compounds
[ Name
Unknown
C4H8 isomer
C5H8 Isomer
C6H12 Isomer
Pentane
Methylbutane Isomer
Alkene
Methyl Propane Isomer
C13H28 Isomer
Hexamethylcyclotrisiloxane
RT
0.711
0.991
2.160
3.430
1.910
1.600
9.151
0.841
10.621
8.661
Area
21802560
8017970
7194486
7189997
6959172
4581469
7505355
3491404
5099787
4285737
tsm
4.471
4.471
4.471
4.471
4.471
4.471
9.751
4.471
9.751
9.751
IS Area
4353547
4353547
4353547
4353547
4353547
4353547
8215840
4353547
8215840
8215840
Amount uq !
1252
0.460
0.413
0.413
0.400
OJZ63
0228
OJZOO
0.155
0.130
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 * Fax: (919) 544-5491
                      Printed:   10:49  07/25/97
-------
                    CM
87-89-97  14:12         Triangle Laboratories of BfP, Inc.
Sanple: UOST-Z SET 4 IUBEA/B  T/IC   173-46-9A/B  TLIJ42284
(919) 544-5729
  Instrument H
HS367
1901
1
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                -------
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                                                               -09-97
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                                                       81' ornoc h 1 o r ome't t la ne
                                                       1,4-0ifluorobenzene
                                                       C i i i o robenze ne—cIS
                                                       1,2-Dlchloraethane-cK'
                                                       Benzene—d6
                                                       Toluena~clS   xTT>n \
                                                       o-Xy lene-dlO @?"^
                                                       4-Bromof 1 uorofoenzerie
                                                       C hIo romet ha ne
                                                    62 Vinyl Chloride
                                                       Bromomethane
                                                       ChloroethaneQ2l5
                                                       Vinyl bromide
                                                       Trichiorof luorotnethane
                                                       1 ,l-0ichloroethene
                                                       lodomethane
                                                       Carbon dlsulficle
                                                       Acetone
                                                       Allyl chloride
                                                       Methylene  chloride
                                                       trans-1,2-Oichloroetherie
                                                       tert-Butyl methyl ether
                                                       Acrylonitrile
                                                       n-Hexane
                                                       1,1-Dlchloroethane
                                                       1,2-Epoxybuta ne(J^
                                                       cis-l,2-Dichloroethene
                                                       Chloroform
                                                       1,2-Dichloroethane
                                                       Isooctane
                                                       Vinyl acetate^
                                                       2-Butanone
                                                       1,1,1-Trichloroethane
                                                       Carbon tetrachloride
                                                       Benzene
                                                       Trlchloroethene
                                                       1,2-Dichloropropaf
                                                       Ethyl acrylate
                                                       Methyl methacrylate
                                                       Bromodichloromethane
                                                       cis-l,3-Dichloropropene
                                                       trans-1,3-Oichlcropropen
                                                       1,1,2-Trichloroethane
                                                       Dibromochloromethane
                                                       Ethylene dibromide
                                                       Bromoform
                                                       4-Methyl-2-pentanone(
                                                       Toluene
                                                       Tetrachloroethene
                        Data Review:
                        Date:
                                  -9 7
                                                                      295
-------
Ho: MAT FOR KfiV Delta      Area P.F.iaqs        RT    QM Name

                                                       2-Hex:.:; none
                                                       Chloroben^ene
                                                   1O6 Ethylbenzene
                                                   1O6 m-/p-Xyisne
                                                   1O6 o-Xylene
                                                       Styrene
                                                       1,1,2,,2-Teti-ach
     64  35  70     1    1O4012 bv         11,80   105 Cumene
-

C •';>
^ -7
54
55
56
r, 7

-'-...-
4B
.100
100
1OO
100
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16
87
87
78
93
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6,3
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94
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_™ •-'
42
304
923
346
?75O
T


430
255
376
Rft4
-------
                                                                                      CD
                                                                                      CM
87-89-97  14:12          Triangle Laboratories of RTF, Inc.
Sappje: UQST-2 SET 4 TUBEft/B  T/TC  173-46-9ft/B  TLIM2284
HS367"9l"(0'.9i0)
ISQ-
H/Z
                  1OO
150
            250
                                                                  (919) 544-5729
                                                                    Instrument H
                                                                           72704
            300
           358
!!S367J9i CO = 911)  REFINE
188i
  0
     49
                             150
                                          288
                        258
                                                                          63232
                        360
                       356
       9 (0.93B)   Chloronethane
180!
     44
      50
                  100
158
288
256
                                                                            FIND
                                                                             188
300
358
-------
                     00
                     CD
                     CM
89-Jul-97 14:12          Triangle  Laboratories of RTF,  Inc.
Sanple: VOST-2 SET 4 TUBEA/B   T/TC   173-4&-9A/B  TLIH42284
(919) 544-5729
  Instrument H
HS367 106 (1.868)
100
XFS
0
n/z
3
al
9 57600
54
II II
JH-4
51
57
JL .
> 100 150 200 250 300 350
HS36?'106 (1.861) REFINE
1001
XFS
0
M/Z
5
50
\
r J
4 41984


50 100 150 200 250 300 350
MASTER 11 (1.448) 1,3-Butadiene FIND
100
XFS
e
n/z
3

9
5
50
1
100
4

50 100 150 200 250 300 350
-------
                   03
                   CD
                   CM
07-09-97   14:12         Triangle Laboratories of RTF, Inc.
Sanple: UOSI-2 SET 4 TUBEA/B  T/fC  173~46-9A/B  TLI842284
(919) 544-5729
  Instrument H
iiojbi'
1B8-]
1
j
XFS-
84_+
M/S
HS367
188-j
j
I
i *
139
44



59
* 139

14
58
NT2CAA 12
188]
KFS-


46
0 4r t
M/3
58
(1.398)
29696


9
4
108 150 200 250 388 350
(1.391) REFINE
9
93
81 "'
4 7616

180 150 200 250 308 350
(1.428) BroMOMetliane FIND
9
93
81
4 100


100 150 200 250 308 350
-------
0g-,IuI-97 14:12          Triangle Laboratories of  RIP,  hie.
Sanple: UOST-2 SET 4 TUBEft/B   T/TC  173-46-9ft/B  TLItt42284
(919) S44-5729
  Instrument H
HS367 151 (1.510)
100"
XFS-
0-
M/Z
44 24064

55
50 ' 100 ' 150 ' 200 ' 250 ' 380 ' 350
HS367'151 (1.511) REFINE
100
XFS"
0
M/2
6
49
4 1136
66
50 ' 100 ' 158 ' 200 ' 250 ' 300 ' 350
MASTER 13 (2.820) Chloroetiiane FIND
100-
XFS
0
M/Z
6

49
4 100
66

58 100 ' 150 ' 200 ' 250 ' 300 ' 353
-------
                                                                                       O
87-09 97  14:12          Triangle Laboratories of RTF, Inc.
Sample: MOST-Z SET 4  TOBEA/B  T/IC  173-4&-9A/B  TLItt42284
(919) 544-5729
  IiistruFient H
179 (1.798)
100
8-
K/Z
111
44
j 55
ii ?10
,,l!f, I...- . kj »^
»1 28592
IBS
105
50 IBS 158 200 258 388 350
HS367'179 (1.791) REFINE
189-
XFS-
8-
1<

47 ft. -6
11 19200
103

185
50 180 15B 288 250 388 358
MTZCftA 15 (1.848) frichlorof luopanethane FIND
160;
XFS -

e
H/S
1C

35

61 100
1O3

105
11,7
SB 1©0 ' 158 ' 200 ' 250 ' 388 ' 350
-------
                                                                                       CM
87-99-97  14-12          Triangle Laboratories of BTP, hie.
Sample: WSI-2 SIT 4 TUJBEA/B   T/IC  173-4&-WB  TLW42284
019) 544-5729
  Instrument H
HS36? 246 (2.4&B)
isa-
XFS-
.M/T.
7
„
„ 	 S3., 67
fi 974848
7B
i. ........
58 168 158 288 250 388 358
ffS367J2'!fa (2.461)
1601

.¥"-*-

0-
M/S
7


-4
,„.!... ^.3 r.6?
6 958464


78
£
58 188 158 269 256 380 358
IB (2.588) Cdpban disulfide FIND
7
IBS']
I
| €4
M/Z
6 108
78
58 188 158 288 25@ 38B 358
-------
                                                                                      CO
                                                                                      o
                                                                                      en
67-69-97  14:12         Triangle Laboratories of RTF, Inc.
Sanple: UQST-2  SET 4 TUBEA/B  T/TC  173-4&-9A/B  fLIi42284
                                                                  (919) 544-5729
                                                                    Instmnent H
      254 (2.548)
IBBi 43
 CFS
        58
              78
                                                                           17152
H/ S
                 160
150
200
258
338
350
HS367T254 (2,541)  REFINE
     43
188-j
XFS
  0
H/Z
        58
                                                                           13446
                             150
            238
            259
            300
           358
HT2CAA 19 (2.578)   Acetone
     ^•i
180-
                                                                            FIND
                                                                             100

      44'
      58
                             150
            209
            250
            300
           350
-------
                                                                                        o
                                                                                        en
07-09-97  14;12          Triangle Laboratories of RTF, Inc.
     le: MOSI-2 SEI 4  TUBEA/B  T/TC  173-46-9A/B  TLIf42284
                                                                    (919) 544-5729
                                                                      Instrument  H
IHS367 294 (2.948)
L««_   4.9
     43 ! 51
      ,f!f55
    i.iy r'
                 88
!«/S
i»
       56
                   189
            15B
            288
            250
                                                                           142336
             38
           3bW
!!!S;J67T294 CZ.S41)  REFINE
       49
iee-
x.FS -
        51

         55
               84
                 88
                                                                           140268
M/S
       58
188
15B
209
258
300
                                                                              358
HT2CAA  21  (2.978)  Methijlene chloride

•ft r»i"» —  ~al 5?
    f
               84
!4FS -
H/Z
       59
188
150
260
258
                                                                             FIND
                                                                              100

47
51

.4,1 It ;

83
i

88
.f
308
                                                                              358
-------
in
cr>
Pi?-B9-y? 14:12 Triangle Laboratories of IIP, Inc. (919) 544-5729
Sample: WST-2 SET 4 TUBEA/B f/TC 173-46-9A/B TLIM2284 Instrument H
323 (3.238)
ise?

XFS '
Q-
HS3C
i@o-

XFS -
0-
M/Z
57 22528
41 i
?3!
ill A 6.Y Bfr
• t '•• - i •-••(•"''• J "''' * - 1 < '''•!'• 	 ' • ' '• 1 ' • ' ' i ' ' ' - i • • • • i • • • ' i • • • J i • ' • • i
58 100 150 288 250 358
»7'323 (3.231) REFINE
5,3 1536
52
38
i
71
86

58 10e 150 2O0 250 300 350
NT2CAA 24 (3.27B) Aery Ion itr He FIND
100 53 100

XFS-

H-
M/Z
51

38
,,i, .1, . ,i


5%3
. 9.6
58 l@e 150 203 250 300 350













-------
                                                                                      C£>
                                                                                      O
8?-0'j-37  14:12          Triangle Laboratories of IIP., hie.
Sample: MOST-2 SET 4           i/TC  173-46-9A/B
(919) 544-5729
  Instrument H
•HS3f
XF8':
o1

Hglf
= u W- i_r i-
IBS]
KFS-

8.
rt/Z
ftf/C
188-
•X.FS-

w/s
>7
4
,

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jbi
t56
L,"
i ",
58
J353
5
I?
j

56
ft 25
13
56
i
• I '
58
( i'j 1:001
i \ -JJ t i^!-_3^J f
7 109568

!.( 	 (I. ,^l.
16S 158 200 250 380 350
1 ('J.b3D HEFINE
7 10S352

58^. B6
i'' 7^ [
189 150 200 250 300 350
; C3.5VB) n-llexane FIND
160

. v e,6
188 158 200 25O 300 350
-------
                                                                  CD
09-Jul-97 14:12
Sample: UQST-2 SET 4
   Triangle Laboratories of RTF, Inc.
TUBEA/B  T/TC  173-46-9A/B  TLI»42284
(919) 544-5729
  Instrument H
HS367 435 (4.351)
A
XFS-
3
44
M/Z 50 ' 100 ' 150
HS367'435 (4.351) BEFINE
4
XFS
0
3
5|7 ?
w/z 50 ' 100 ' 150
MASTER 35 (5.15B) 2-Butanone
1001 4
XFS

3

57 ?f
1. 	 1. J.
M/Z 50 ' 100 ' 150

3872

' ' " ' ' „,!.,•. • • " i * • " ' i ' • " • i - - - • i - • • • t > - • - i
200 250 300 350

3168

200 250 300 350
FIND
100


200 ' 250 ' 300 ' 350
-------
                                                                                      00
                                                                                      o
8,' 80-97  14:17.          Triangle Laboratories of RTF,  Inc.
Sample:        SET 4           T/fC  173-46-WB
(319) 544-5729
  Instrument H
HS367 510 (5,181)
188-
>;FS"
0
M/ Z
7
77
,8

50 JOO ISO
HSB&T^Bie (5.101) REFINE
100
Q-
M/'S
7
VV
¥ 71
8
79
i -
50 160 150
NT2CAA 36 (5.131) Benzene
180-
XFS-
8
M/Z
7
77
1 f 63 "
al , '*' ,»»>.... -y
8

79
53 100 150

1605632

200 250 360 350

1523712

280 258 380 353
FIND
103


200 250 308 358
-------
                                                                                       en
BYH3y-9/  14:12          Triangle Laboratories of RIP, Inc.
Sample: UQST-2 SEf 4 fUBEA/I  f/TC  173-46-9A/B  TLIi42284
(919) 544-5729
  Instrument H
645 (6,451)
100-

XFS-
8-
M/Z
4i 86816



69
I

55
;l,, ....LL „,

70 180
' . J3,5 1
50 1C© 159 280 258 308 350
HS367J645 (6.451) REFINE
108-

8-
M/Z
4


1 74752
6
42
5«1
L. . .i...r
9
70 100
i. . i II,
*'' . | ••••••-( 4 .. i , , , — i . | i , 	 , r ,..,.,,... | ,...,.... | .. , ,,....,....,...•!
50 180 158 288 258 3G8 350
48 (6.491) Methyl methacrylate FIND
100-
8-
4

1 188
6
dL~?
Tit* cr o
i,.. ,,lt.,i
9
58 130 150 200 250 300 358
-------
                    o
                    *-<
                    en
R7-R9-97  14:17:          Triangle Laboratories of RIP,  Inc.

R-fwIe: U03T-2 SET 4  TUBEA/B  T/TC  173-46-WB  TL1142284
<919) 544-5729

  Instrument H
Itejt
"H**-

•/.FS-

0
.V Vb6 (7,561)
91


f4 „ eg
i 51 **P
. I...,."|C... ,4..., .T..,,,.,,4
92
.*

93

56 10Q 156 208

626688




258 3i9 358
HS3br?b6 (7.561) HEFINE
109-1

xFS "
.
NT2C
9


'7"3> cs; 89
I 5.1 €f \
1
92
!
|93
59 100 158 20Q
lAA 49 (7,681) toluene
lOBi 9

KFS -
e
K/Z


,1-,,'T j. ,f, ,.\
1
92

93
50 15B 208
565248



256 3i9 358
FIND
188



258 38B 358
-------
07-89-97  14:12          Triangle Laboratories of RIP, Inc.
     e: WST-2 SEf 4 TUBEA/B  T/TC  173-4&-9A/B  TLIf42284
(919) 544-5729
  Instrument H
HS367
IBB/

XFS -
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|
1




837 (8.371)
1 5:
43

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6
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109 158 208 250 308 358
(8.371) REFIHE


15
9,4
l^a,


9 16

133
4 2528
168
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150 288 259 308 358
(8.411) Tetrachloroethene FIND

dr

It
129
9
82
. h. .
4
133
I
(, 100
168
178
i.
10O 150 200 250 300 350
-------
                                                                                      CO
H/-09-9/  14:12         Triangle Laboratories of RTF, Inc.
Sample; HQST-Z SET 4 TUBEA/B  T/TC  173-46-9A/B  TLI8422Q4
(919)  R44-5729
  Instrument H
JH8367 979 (9.791)
i fi£'i_
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H/S S 8
117 116736
83 116
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169 158 288 258 380 358
}!S367'979 (9.791) REFINE
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1 51
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l:



93
2 4488

114
!

leg 158 268 258 388 356
HT2C?lii 52 (9.841) Chlorobenzene FIND
180-1
i 77
KFS -]
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1:



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114
j
188 158 288 258 388 356
-------
                                                                                     CO
07-09-97  14:12         Triangle Laboratories of RIP, Inc.
Sarnie:  MOSf-2 SET 4 TUBEA/B  T/TC  173-4&-WB  TLI842284
(919) 544-5729
  Instrument H
(li.881)
IBBl 9
51. €=p 77
1
186
,s.- ...li ...
M/Z 50 188 158 288
HS367'1888 (10.B81) 1EFINE
9
XFSJ
| . 5/ 65 7?
1
186
, .1.
i*/z 58 188 150 288
53 (10.131
1-901 9
MFS -
Q- f 51 tp 77
) Ethyl benzene
i
186
Tie?
M/S 56 160 150 200

116736

250 30B 350

99328


250 308 350
FIND
108

250 303 350
-------
                                                                                     cn
w?-@9-y?  14'12         Triarcgle Laboratories of EfP, Inc.
Sanple: MOST-2 SET 4 fUBEA/B  f/TC  173-4&-9A/B  TL1842284
(919) 544-5729
  Instrument H
HS3&7 1831 (18.311)

100:
•
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;
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7 "5.1. £,s 77



106
92 107
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250 388 350
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. Jis.t
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91

79 «? 77
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58 iee 150 200
188416





25@ 300 350
FIND
100




250 300 350
-------
                                                                                    in
87-89-97  14:12         Triangle Laboratories of RIP, Inc.
Sanple: VOST-2 SET 4 IUBEfi/B  T/TC  173-46-9A/B  TLIft42284
(919) 544-5729
  Instpunent H
1102 (11.821)
108-
>;FS -
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H/Z

^
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58
9
8
LI--II. I
I11
92 l|
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14 92160
186
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100 158 208 250 300 350
HS3fa7JllB2 (11.821) REFINE
198-
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55 (11.
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8-
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If
92
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16
IB?
188 150 200 258 308 358
071) o-Xylene FIND
91 100

?

18S
J2 197
i .1 1;"
103 150 200 250 300 35O
-------
                                                                                    CO
07-09-97  14:12         Triangle Laboratories of RTF, Inc.
Sample: UGST-2 SEI i TOBEA/B  I/TC  173-46-WB  IL!i42284
(919) 544-5729
  Instrument H
HS367 1187 (11,871)
iOSi *'
163
xFS-j ^ ?8
•a Li 	 i 	 j? 	 >,: , 	 jl.. i
34
185
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a/2 58 108 158 288 25O
l!S3b7J1187 (11.871)
1001 14
183
.MP*--- 70
" ~:- " ,3 la2-
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REFINE
p4
105
H/Z 50 100 150 200 250
HT2CAA 56 (11.121)
.001 1C
ies
*m~- 51 7678 le^
fi ^" J*
o -I. , *iT" ; 1 ( P.-^" J
Styrene
J4
i
M/Z 5" 180 150 200 250
327680
308 35S
286720
380 358
FIND
lee
see 350
-------
                     CO
07-B9-9/  14:12          Triangle Laboratories of IIP,  Inc.
Sanple: WST-2 SET 4 IUBEA/B  T/TC  173-46-9A/B  TLIM2284
(919) 544-5729
  Instrument H
1188 (11,881)
100-

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M/Z
11
41 57
69 79 ±
I )j,i ,|iji i;i!^ iiii,
45 8832

128
SB 108 15B 288 258 300 358
1IS367'1188 (11.881) REFINE
iSB
XFS -

8
M/E
1^

51&g x03
M-l | •!'' i ii- IH^? • i 1
15 6656

106
i . I?0
5i ' 180 ' 15B ' 200 ' 250 ' 380 350
W2CAA 58 (11.851) Cunene FIND
1B9
0-
It
7? ±&3
P 188
120
. . f ,...,,.-., .,,,..,. | ,.,,,,..,,....,....,...,,...,...,....!
58 189 158 288 258 388 358
-------
                                                                                   oo
                                                                                   «H
                                                                                   CO
09-Jul-97 14:12          Triangle Laboratories of RTF,  Inc.
Sample: MOSf-2 SET 4  TUBIA/B  f/IC  173-46-9A/B  ILIH42284
(919) 544-5729
  Instrument H
HS367 71 (0.718)
AH
100
XFS


44
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1001
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2228224



100 ' 150 ' 200 ' 250 ' 300 ' 350
REFINE NBS 49 Hits : 49 Searched
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«/z 20 40 60 80 10B 120 140 160 188
-------
09-Jul-97  14:12         Triangle Laboratories of KTP, Inc.
Sample:  UQST-2 SET 4 TUBEA/B  T/TC  173-46-9A/B  TLIH42284
(919) 544-5729
  Instrument H
HS3(
100-
XFS
0-
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41
|43
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w/z 50 100 ' 150
HS36
100
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0.
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100
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100-
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0-
»7'99 (B.991) REFINE
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FI699 657IOXETANE, 3,3-DIHETHVL
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F:649 545:C¥CLOPROPflNE, <1-HEIH
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39|
37 42
31 \. , /, ..
M/Z10 ' 20 ' 30 ' 40 ' 50
401408
208 250 308 350
NBS 24 Hits : 24 Searched
393216
56
56 255
55^ 57
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-------
              o
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    14:lZ         Triangle LtlMKratories of RTF, Inc.
UOST-2 SET 4  IIJBEA/B  T/TC  173-46-9A/M  TL
(919) 544-K7Z9
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HSJb
1001
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-------
                                                                                    C4
                                                                                    CD
OVVTO/9Y    1.4'. 1Z         iriangle  Laboratories of RIP, hie.
Kanplc:  UOST-2 SEI 4  TUBEfi/B   f/TC  173-4&-9A/B  TLItt42284
(919) 544-5729
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118367 343 (3.43i
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168 150 208 258 388 358
L) REFINE NBS 61 Hits : 61 Searched
6 81928
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: 2H-PVRAN-2-QHE, TETRAHVDRO-3 , 6-DIHETHVL-
5 C7H1202 255
5? 69
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-------
                                                                                    ct
                                                                                    ct
rffV1ri--'"y"/     14*12        triangle Laboratories of fifP, Iiic,
8,«-M'le: UySf-2  SET 4 IUBEA/B  T/TC  173HKHIA/B  TL1*42234
(919) 544-5729
 Instrument: H
• ,\j ' «,-" r? * r» •« <•• 4
!l-5-_>bf A3A 11 .
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3
57 72
2U8:flCETIC fiCI», 2-PSOPEfWJ
3
44 57
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531: HEPTANE, 4-6311)0-
sv
44 / 7o
rlJ . I ».4 98 	 	 .
«^r. 58 168 158
HBS
258 3O0 358
HBS 83 Hits : 83 Searched
183296
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^ ESTE1
H55
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C7H1&H3
283 25Q 366 359
-------
87/89/97    14:12        Triangle Laboratories of RfP.,  Inc.
Sanpfe:  UflRT-2 SET 4 UJBEA/B  T/TC  173-4&-9A/B  TLIM2284
(919) 544-5729
 Instrument: If
160 (1,680)
« «.-}, . 43
j.»3j
- i ^9
X* a j \
„ i j,
57
55
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M/Z 58 1G6 158 200
(1.681)
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»K-O] 39 I
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44 J58 P
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55 58 85
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133128



258 368 358
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121856





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255
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258 380 358
-------
                                                                                 cn
07/09/97    14:12        Triaiwle Laboratories of HIT, Inc.
Sanple; U08T-2 SET 4          T/TC  173-4G-9A/B  TLW42204
(919) 544-5729
 Instrument:  H
US%? 915 '9
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3 134144
55 7,0
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lSf> tr ~ 7O -- ^i "•'SS
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r-^OJ POLHr
i 56 71 83 ^oHTh
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1,,5^ 255
jrbv^ep 96^ U1
58 lee 150 209 258 368 350
-------
                 in
                 CM
89-Ju 1-97  14:12         Triangle Laboratories of RIP, Inc.
Sanple: UOST-2 SET 4 TUBEA/B  T/TC  173-46-9A/B  TLI&42284
(919) 544-5729
  Instrument H
84 (0.840)
1001 4|344
XFS- |
M/2 50 ' ' 100 '
HS367'84 (0.841) REFINE
1001 41 ^P
XFS- 38 ^
e V M

150 200 250
NBS 144
.57
#1 F:816 97: PROPANE, 2-METHVL-
1081 42?
XFS __ 29 39 \ 44
ff f J \ 1 I /* H"*"i
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1801 ^j3
XFS- 39 44
Q T-V • -r't'i I
2-PROPENVL ESTER
57 58
V*L
#3 F:679 4489:2/4-OXA20LIDINEDIONE, 5, 5-DIMEf HVL-
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0 45, 2.7/. \fl,, /r« , .. \r 7.0
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60 80 100
183296
300 356
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178176
i*' "i'"*'i* I""
255
255
255
129
120 140
-------
                                                                                    CO
                                                                                    OJ
                                                                                    CO
fi7/i¥i/9?     1.4:12
                          Triangle Laboratories of IfP,  Inc.
Sanple: UOST-2  SET 4 TUBBVB  I/fC   173-46-9A/B  ILIM2284
            :m
            43
(919) 544-5729
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59 186 159 289
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256 308 358
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                                                                                  CJ
                                                                                  CO
            14:12        Triable Laboratories of IIP,  Inc.
SariPJe:  UOSf-2 SET 4 fUBEA/B  T/TC  173-4&-9A/B  TLIf42284
(919) 544-5729
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866 (8,661)
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Project Number: 42284
Sample File: HS368
Client Project: S407-Q03

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Method 8240A VOST

Dale Received:
Date Analyzed
Sample ID:
06/30/9?
: 07/09/97
VOST-3 SET 1
TUBEA/B T/TC
Response KI«R:ICALH708




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Bromochloromcthanc
Chloromethane
Vinyl Chloride
1,3-Butadiene
Bromomcthane
Chloroc thane
Vinyl bromide
TricMorofluoromcthanc
1,1-Dichloroethene
lodomethane
Carbon disulfide
Acetone
Allyl chloride
Mcthylene chloride
trans- 1 ,2-Dichloroethene
ten-Butyl methyl ether
Acrylonilrilc
n-Hexane
1 , 1 -Dichioroethane
1 ,2-Epoxybutane
cis- ! ,2-Dichlorocthene
Chloroform
1 ,2- Dichioroethane
Isooctane
1 ,4-Difluorobcnzcnc
Vinyl acetate


]&\
0.161
U
0.182
0.028 J
U
U
0.125
U
U
0.434
0.127 B
U
3.024 BE
U
U
0,525
1.755 E
U
U
U
U
U
0.077
IS 2
U
lllliiiili
.^S'^VMi-iS.-i: i:S^Bi:§fefi-
4.44
0.88

1.01
1.34


1.74


2.41
2.48

2.88


3.18
3.48





5.24
5.61





0.001


0.001
0.00 1

0.001
0.00 1


0.00!

0.00 1
0.001


0.001
0.003
0.001
0.00 1
0.001


0.001
SlpSISilii


0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05

0.05
N A- Hot Applicable; Det Limit: Detection Limit Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected;
B: Present In Blank; J: Estimated- Below Quantitarion Limit E: Estimated- Above Calibration Range
Triangle Ijboratorits df RTF, Inc
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Pax: (919) 544-5491
             Savar v3.5
Printed; 15:03 07/22/1997
         328
-------
: ; Pacific Environmental Services
Project Number 42284
Sample File: HS368
Oient Project: 5407*003
tilt ID! 173-46-16A,B -' >
Method 8240A VOST
Sample ID: VOST-3 SET 1 TUBEA/B T/TC
Date Received:
Date Analyzed
0&3Q/97
1 07/09/97
Response
HIerlCALHTOS


to^x;:.:.,:H;
2-Bucanone
1,1,1 -Trichloroethane
Carbon tetrachloride
Benzene
Trichloroethene
1 ,2-Dichloropropane
Ethyl acrylate
Methyl methacrylate
Bromodichloromethane
cjs-1 ,3-Dichloropropene
trans-1 ,3-Dichloropropene
1 ,1 ,2-Trichloroethane
Dibromochloromethane
Ethylene dibromide
Bromoform
Chlorobenzene-d
4-Methyl-2-penunone
Toluene
Terrachloroethene
2-Hexanone
Chlorobenzene
Ethylbenzcne
m-/p-Xylene
o-Xylene
Styrene
1 , 1 ,2,2-Terrachloroe thane
.- ::' Amouirt .. :.EL^C T.!.'
0.019 J
0.005 J
0.011 J
0.772 B
U
U
U
0.011 J
U
U
U
U
U
U
U
IS 3
U
0.343 B
U
U
0.011 J
0.043 J
0.135
0.046 J
0.106
U
•"" KTjv •
4.32
4.68
4.86
5.07



6.44







9-74
7.55


9-79
10.08
10.31
11.01
11.06

'• :D?vf/-..




0.001
0.001
0.001

0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001

0.001
0.001





0.001
Qbattv limit
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.10
0.05
0.05
0.05
NA- Not Applicable; Det. Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax (919) 544-5491
            Savar v3.5
Printed; 15:03 07/22/1997
                                                                                                          329
-------

Project Number: 42284
Sample File: HS368
                                                              Method 8240A VOST
                                       Sample ID: VOST-3 SET 1TUBEA/B T/TC
                                          :l3iii
                                     SlStoi^il

Cumene
                      0.004  J
                           11.79
0.05
1,2-Didilorocthanc-d
                 4
Benzene-u^
Toluene-d
                      0.246
                      0.277
                      0.296
                           5.05
                           5.03
                           7.46
 98
 111
 118
Reviewed by.
-TLO
Date
                        NA- Not Applicable; Deb Limit: Detection Limit; Quan, Limit: Quantitation Limit
    IS: Internal SLandird; U: Undttected; B: Present In Blank; J; Estimated- Below Qiuntitation Limit; £: Esrimated- Above Calibration Range
Triangle Laboratories at RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 * Fax: (919) 544-5491
                                                                              Savarv3.S
                                                                   Printed: 15:03 07/22/1997
                                                                                              330
-------
Project Number:  42284
Sample File:      HS368
                                                Method 8240A
                                                Sample ID:
                                   VOST-3 SET 1 TUBEA/B T/TC
Client Project
TLIID:

S407-003
173-46-10A,B


Dilution Factor:
Date Received:
Date Analyzed:
1,00
06/30/97
07/09/97

Tentatively identified Compounds

   Methylbutane Isorner                 1.530      41272228      4.451      4899559
   Unknown                          0.701      29335470      4.451      4899559
   Hexamethykyclotrisiloxane           8,651      21759164      9.741      10471731
   Halogenated Hydrocarbon            2.070      9109668       4.451      4899559
   C5H8 Isomer                       0.951      8700915       4.451      4899559
   Pentane                            1.850      $230038       4.451      4899559
   Methyl Propane Isomer               0.821      7240241       4.451      4899559
   Tetrahydrodimethyl Pyranone Isomer   4.050      6209437       4.451      4899559
   C8H16isomer                       7.781      5914977       9.741      10471731
   C13H28 Isomer                      10.611      5162709       9.741      10471731
                                                          2.106
                                                          1.497
                                                          0.519
                                                          0.465
                                                          0.444
                                                          0.420
                                                          0369
                                                          0317
                                                          0.141
                                                          0.123
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 * Fax: (919) 544-5491
                                       Printed:   22:30  07/25/97
                                                           331
-------
                                                                                        cvj

                                                                                        CO

                                                                                        CO
H7-89-97  14:39          Triangle Laboratories of RfP, Inc.

   ple: UOST-3 SET 1  TUBEA/B  T/TC  173-46-18A/B  ILItt42284
(919) 544-5729

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                                              Bromoch i o rom«tha ne
                                              1,4-Dlf1uorooenzene
                                              Chiorobenzene-dS
                                              1,2-OIchloroathane-d4
                                              Benzene~"d6
                                              Toi uene—d8
                                              o-Xylene-dlO
                                              4-Bromof 1 uoroTSenzane
                                              Chloromethane
                                              Vinyl Chloride
                                              1,3-Butadiane
                                              Bromomethane
                                              Chloroethane
                                              Vinyl bromide
                                              Tricolorofluoromethane
                                              1,1-Oichloroethene
                                              lodomethane
                                              Carbon disulfide
                                              Acetone
                                              Allyl
                                              Methylene chlorTde
                                              trans-1,2-Dichloroethene
                                              tert-Butyl methyj _etlie
                                              ftcrylonitrll
                                              n-Hexane
                                              1,,1-Oichloroethane'^N
                                              1,2-Epoxybutane^fT^
                                              cis-l,2-Dichloroethene
                                              Chloroform
                                              1,2-Oichloroethane
                                              Isooctane
                                              Vinyl acetate
                                              2-8utanone
                                              1,1,1-Trichloroethane
                                              Carbon tatrachlorlde
                                              Benzene
                                              Trichloroethene^
                                              1,2-Oichloroprof:
                                              Ethyl acrylate
                                              Methyl methacryl'ats
                                              BromodlChloromethane
                                              cis-l,3-Dichloropropene
                                              trans-1,3-Dichloropropen
                                              1,1,2-Trichloroethane
                                              Dibromochloromethane
                                              Ethylene dibromide
                                              Bromoform
                                              Toluene
                                              Tetrachloroethene
                 Data Review:
                 Date; -
                                                             333
-------
Dt?lta
RT
                                QH Name
,
52
C, T
54
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56
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58

C'3
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                    334
-------
If)
en
CO
67-69-97 14:39 Triangle Laboratories of RIP, Inc. (919) 544-5729
Sanple: UOSI-3 SET 1 TUBEA/B T/TC 173-46- 18A/B TLIM2284 Instrument H
08 (8.888)
189] 5
1 44
IX.FSI
1 i
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	 j|,i
0 100352

52
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58 ' ' ' 168 •••••• ^g ' 2^0 ' ' 2^0 ' 3^0 ' 35^
(0.881) REFINE
5

XFS-
m-

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5
@ 82944

52
3 103 150 288 258 388 350
NT2CAA 9 (0.93B) Chloronethane FIND
168-
XFS-
0-
H/Z
5

44
.. . 1. i,!
8 180
52

59 160 158 208 258 388 350











-------
                                                                                       CO
                                                                                       CO
                                                                                       CO
0g-Jul-97 14=39          Triangle  Laboratories of RTF,  Inc.
Sample: UOST-3 SET 1 TUBEA/B   T/TC   173-46-18A/B   TLI842284
(919) 544-5729
  Instrument H
HS368 101 (1.010)
iee 3,9 134144

XFS

0-



,i
5
50
\

4


1,1,..,
w/z 50 ' 108 ' 150 ' 200 ' 250 ' 308 ' 350
HS368'101 (1.011) REFINE
1001


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5
53
\



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50
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4 105472





, .
*•"• • '1 • • • • f • 	 ' • ' 1 • • • -1" • 	 • ' • 1 ' 	 • • 1 •• • • I'" • I • f • I •'"! 	 ¥ 	 • 	 » t- • '» <* 	 	 1 	 « . • 1 1 • . - . | - . ««f 	 * 	 1
M/Z 5« JL00 158 200 250 300 350
MASTER 11 (1.440) 1,3-Butadiene FIND
100
XFS

0,
3



9
50
\
I

100
4




-------
                                                                                     CO
07-69-97  14:39         Triangle Laboratories of RTF, Inc.
Sample: UOST-3 SET 1 IUBEA/B  f/TC  173-4&-18A/B  TLIS4Z2G4
(919) 544-5729
  Instrument H
HS368
188-
XF8 '

0
H/Z
4




HsiKiF
10Q-
XFS -
O-
H/Z




134 (1.348)
4 28672
9
93
73 '•
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ii
58 106 150 200 250 300 358
134 (1.341) PEFIME
9
93
1,1 M
4 14144


58 100 158 208 250 308 350
INfZCAA 12 (1.42B) Branonethane FIND
-f J3|"3> —
XFS:
0-
H/Z


48

9'
93
?6 81 j
;. , , i-i. iJ
* 100


58 106 158 2O0 250 308 350
-------
                   CO
                   CO
                   en
-W'J-yv  14:39         Triangle Laboratories of  RIP,  Inc.
    :         SET 1          T/TC   173-4G-18A/B
(919) 544-5729
  Instrument H
174 (1=748)
1 QQ-i •*•
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185
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15 (1.848) Triclilopof luorowethane
180-j -11
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H
183

185
I 147
»/z 58 ' 108 ' ' 150 ' " 200 ' ' " * ' 250 " '


380 359

60928


300 350
FIND
100


30B 350
-------
                                                                                      0}
                                                                                      CO
67-W9-97  14:39         Triangle Laboratories of IIP,  Inc.
     e: UQST-3 SET I TUBEA/B  T/fC  173-46-18A/B  TLI142284
(9193 544-5729
  Instrument H
241 (2.418)
- c*n 7
v;FS -
: 44
S

78
M/Z 50 ' 100 •-.--- 1^jJ • 2£0
HS360'241 (2.411) REFINE
108-1 7
• 44
a ..i... 1,.. 5.3 ,J>.7
6
78
1 . . . . ...... ....
H/Z 58 1O0 ' 150 ' 200
18 (2.58B) Carbon disulfide
ir ?
XFS -
g ' L i ,; , ,
6

78
w/z 58 100 150 200

729088


250 300 350

716800

250 300 350
FIND
100


250 300 35O
-------
o
CO
87-09-97 14:39 Triangle Laboratories of RfP, Inc. (919) 544-5729
Sample: UOS1-3 SET 1 TUBEA/B T/TC l?3-46.-10ft/B TL I Instrument H
240 (2.488)
ise-
XFS"
9-
M/Z
4

.HI-;
3 2432S
76
j 58
5\ w 78
58 108 150 200 250 300 350
H83bOJ248 (2.481) REFINE
ISO]

XFS-
6
M/Z
4

	 „.
3 15936

58
50 100 150 200 250 300 350
19 C2.S7B) Acetone FIND
J. 08"
XFS-
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F"
4


3 180

53
44
58 168 150 200 256 300 350










-------
87-89-97  14:39         Triangle Laboratories of IIP,  Inc.
Sanple: MOSf-3  SET 1 IOBWB  f/TC  173-46-18A/B   TLII42284
(919) 544-5729
  histratsient H
288
188-

KFS-
a-
M/Z
4


42
JM
5
9 2277376
84
51
55
,.^-i" -

88
X
a lee 150 200 250 388 350
H3368J288 (2.881) REFINE
1801

XFS -
fl-
H/Z
N12C
188l

XFS-
8-
H/S
4


,Ii
9 2211840
84
51
55
./. 	 !« .

88
/
„•"
.1.
50 IflO 158 288 250 388 350
:«rt
4
21 (2.978) Netliylene chloride FIND
9 180
84
47
.«!,
51
83
88
5@ lee 158 2Q0 258 388 35O
-------
                   CM

                   CO
87-69-97  14-'39          Triangle Laboratories of RTF, Inc.
Sanple: MOSf-3 SET  1  TUillA/B  T/TC  173-46-1BA/B  TLW42284
(919) 544-5729
  Instrnnent H
HS3b'B
188

XFS -
e-

318 (3.18B)
K:
41

!
I1S36Q
1B0T

G-
H/S
4
,


L
51

1
7 88664


58
;'" .^,1 86
ISO 156 260 250 389 358
'318 (3.181)
57 768O8
53
1 "•
J 1

I.I

58
50 166 150 200 250 300 350
HT2CAA 5
186] ^
e-
M/S
38
i

!4 (3.278) ftcrylonitrile FIND
3 100
9*63
5§ 188 150 268 250 368 358
-------
                                                                                      00
                                                                                      «3«
                                                                                      CO
87-ftl-9?  14:39         Triangle Laboratories of RTF,  Inc.
     e: UOST-3 SET i fUBEA/B  T/TC  173-46-1BA/B   TLIft42284
(919) 544-5729
  Instrument H
348 (3.488)
100-
XFS-
M/Z
5
4

56
55
7 1572864

!jJL ^
58 160 150 200 250 300 356
(3.481) REFINE
? 14417*2

XFS-
S-
4


1
~56
"•


55 58 i>ft
Nl/ 71 Bib
i L • f— I
58 15B 258 300 358
25 (3.578) n-liexane FIND

•

XFS -

0J
H/Z
4,3



\
56

55
- ...,i
7 180



71 8r6

59 188 158 200 250 300 350
-------
                                                                                      en
07-09-97  14:39         Triangle Laboratopies of RTF,  Inc
ianple: VOST-3 SET 1 TUBEA/B   1/TC   173-46-10A/B  TUft42284
(919) 544-5729
  Instrument H
524 (5.241)
160-
Q-
5
41,. ""*
.ill.. .p
7 173056
58 84
m 100 ISB i«8 250 300 350
(5.241)
J.00-
xrs:
I*/Z
5
-•_
,j.I }\
7 126976

?,9
5B 180 158 260 250 360 350
31 (5=291) Isooctane FIND
5

>:FSJ
M/Z-
56

58
7 168


58
| f |
160 150 2B8 258 3B0 350
-------
                                                                                    in
                                                                                    «&
                                                                                    CO
67-89-97  14:39          Triangle Laboratories of RIP,  Inc.

Sample: WST-3 SET  1 TUBEA/B  T/TC  173-4&-10A/B  TLItt42284
(919) 544-5729

  Instrument H
432 (4. 328)
4
XFS -
R-JU
3

?4?4 72
1, I
«/z 50 1©8 158
(4.321) REFINE
1001 4
1
XFS'j
0 ' 	 	 i
3

7E
-T,7 "1
w/z 50 188 158
33 (4.388) 2-lutanone
1801 4
XFS-
3
72
r
H/Z 50 100 ' 150

5696


208 258 388 350

4544


2O0 250 300 35O
FIND
100

200 250 300 350
-------


8V- 00






97
Sample: MO
HS3G8 468

1 88-;

XFS-

9-
,i
~


i

rt/>;




14:39
3T-3
CD
CO
Triangle Laboratories of RIP, Inc. (919) 544-5729
SET 1 TUBEA/B T/TC 173-4&-1BA/B TL I 142284 Instalment H
(4.681)
56
t

- 1
S5
42
1
"Ij i

5

«
fjj

s




; j


468

160-

XFS'

6.;






8832

84
78
"if '!
slMJi-jj


4LLi

"Ct *jf


11 7
•"-Tl*
- , , ,- , - , 	 r--| 	 ,— , 	 . 	 , 	 1 	 . 	 , 	 • 	 , 	 1 	 . • 	 • 	 1 	 1 	 . 	 1 	 ' 	 ] 	 . 	 • 	 1 	 • 	 1 • 	 • 	 . 	 • 	 1 • r—r- ,-,--. . • -r .-"( . . . . — ,
160 150 268 23« 3S8 358
(4,681)
7fl


53
38

-r- —








<•,

1
58
HfZCflft 34

IB8^








i ??
\
' *
U-, « P"






3264

97




99

169 150 200 256 388 350
(4.751) 1,1,1-Trichloroethane FIND




9? 180

j 6,1
~ rfr*£ -j
'•- - L,
1
8-



sr
47
' ' 'i




60



63






.8,8 ,

M/Z 50

S


117
. , , , , -^ , -, r- r i r, ,TT, j ^ . r , | .. . -. ] . --- . | - - - - ( -..,.|..-r-.-jT.- , - -. ,
158 20S 258 388 358
























-------
                                                                                       CO
87-09-9?  1439          Triangle Laboratories of IIP, Inc.
Sample: UOST-3 SET 1 fu'BWB  1/fC  173-46-10A/B  TLIM2284
(919) 544-5729
  Instrument H
486 (4.861)
188] ¥ 5
, 1

X.FS -


0-
!
j
| 35

i
i |
, >!l! 1,1,!,
, 11264
j
11
I PK
65 sp
, nil! ,|J

7
121


.....,J....j, ...,....,..,.,....,...-, .-.-..!..
Wz 58 188 158 208 258 300 358
(4.861)
1001 5

XFS-
0


Y
XiJllH
6 5888
U

... 78
6!4 ' 7
-------
                                                                                      CO
                                                                                      ^

                                                                                      en
          H:39         Irianff!e Laboratories of iTP. Inc.

Sanule: MOSf-3 SET 1 TUBEA/B  f/TC  173-46-ieA/B  TLIf42284
(919) 544-5729

  Instrument H
HS3bO 587
10B-
]
XFS-
,S~

,..,1,.
58
IIS36875e7
±80:
X.FS
g
M/Z

51
.„, 4
53
HT2CAA 36
1B8-
XFS-.
^_g-


52
-I .11

(5,871)
7
77
6S
3

84
1 ''' I ••••_!_ ^ ••• 1 	 ' '" 1 ' 	 	 I • ' 	 • ' 1 • ' ' 1 • • • • "I ••-•!•
(5.071) REFINE
7
77
74 '"
,„!„ 	 ,,,i|!
8
79
i .
100 158 288 258
(5.131) Benzene
7
77
S3 j
3

79
ie0 158 200 250

1196832


3i8 358

1138496

300 358
FIND
106


308 350
-------
                                                                                       0-3
87-89-97  14:39         Triangle Laboratories of  RTF,  I«c,
Sample: MOST 3 SET 1 IUBEA/B  T/TC   173-46-18A/B   TLIII42284
(919) 544-5729
  Instrument H
644 (6.441)
100-
XFS-
6-
HSrr
.- ft
I4
1
tl §816
53 §
ET *7
fill "f *
1 \."
ll !«[_ .
9
81 100
36'
III h
58 100 158 208 258 308 350
HS368'644 (6.441) HEFINE
i 00- 4.1 2896

XFS-
«...
H/S


6
42
/ 57
9
71 1«B
("Jf I
5B 150 288 258 388 358
48 (6.491) Methyl wethaerylate FIND
188-

XFS"
H'Z
4


!
1 180
69

42 gg
i 	 ,. I

;8e? T
*. » i i.
50 100 150 269 258 300 358
-------
                                                                                      CD
                                                                                      IT5
                                                                                      CO
07-09-9/                 Triangle Laboratories of RIP, Inc.
Sanple:        SET  1           f/IC  173-46-18A/B
(919) 544-5729
           l H
755 (7.551)
.168-] 9

•XFS -j
: /351 65 g3
(4 '..a,.,.,,!?!!..,.. ,i!r|.— , -j 	 ,-'i
w/z 58
HS3G8'755 (7.551)
1001

XFS •
39
-'A5/ IP ^
w/z 50
49 (7.601)
Q
1 gra-i J
j_ « j
i
j
XFS-j ^
J/V f , 8*.
H/Z 59

1
92

93
10O 158 200 258
REFINE
I
92

93
108 158 208 258
Toluene
1
^ £*
E
93
ICO 158 208 258

598016



380 350

540672



300 358
FIND
180



300 350
-------
                                                                                      in
                                                                                      en
          14:39         Triangle Laboratories of RIP,  hie,
Sample: UOST-3 SET 1 IUBEA/B  f/IC  173-4&-18A/B  TLII42284
(919) 544-5729
  Instrument H
979 (9.791)
108-

X.FS-
8-
M/Z
117 90112
82
llf
5\777 112
48 / ^7 \

58 1430 150 208 250 308 350
HS368J979 (9.791) REFINE
188-
XFS -
8-
w/z
1:

9.3 t
2 12168
114
j
58 158 200 258 308 350
52 (9.841) Chlorobenzene FIND
180-

XFS-

H-
H/Z
1:
*!«"*
• f

51 "4
„... J5.6.. :i,.85
.2 100

114
'

58 108 150 200 250 388 350
-------
                                                                                     ID
07-89-97  14:39         Triangle Laboratories of RTF, Inc.
Sample:        SET 1          I/IC  1Y3-46-1BA/B  TLIM2284
(919) 544-5729
  Instrument H
1688 (IB. 881)
100-
"FS-
8-
H/Z
a
"*

51 65 77
•V |l..|.. ,d.u. 	 111,... ,,
1
106
, I
5S ie-8 158
ClB.eei) REFINE
100
8-
M/E
9
51 S5 77
J- - -• 	 ...Hi,, i.
1
IBfr
... . .ill.
59 ie@ 150
53 (18.131) Ethtjlbenzene
188-
XFS-
m/z
9

51 65 ?)7
1

I IB?
5B 108 158

89088


200 258 388 358

74752

236 253 380 358
FIND
168


230 258 303 353
-------
                   PO
                   ID
                   CO
87-89-97  14:39         Triangle Laboratories of RIP,  Inc.
SaRpIe:  UOSf-3 SET 1 TUBEA/B  T/TC  173-46-18A/B  TLIH42284
(919) 544-5729
  Instrument H
1B31 (li.311)
108
yFf-
B-
P./S
9

39
r ¥ §5 7i7
j.i... J.I.|,.. j.[,...t..,tjn,...,.. ,
1 21913i
186
92 he?
S J/
< 1 1 1 4 1 I | I 1 . , , . , ... ,.,,.,,..,,,...,,...,....,....,....,....!.... |
50 100 150 260 250 300 350
HS368'1831 (18,311) REFINE
1.68-
>;FS •
s-
M/Z
9

t) 1 £ *; • 7
1 ' Y
1 187392
166
92 107
i .1 !L ..
58 ISO 150 289 250 300 350
MT2CAA 54 (IB. 371) M~/p-Xylene FIND
100-
"FS-
0J
w/z
9

"--•J
i v%f } i 1 i[
.It.. f" i -If" ' T "t i "
1 100
186
92
58 10e ' 150 ' 200 ' 250 ' 300 ' 350
-------
                                                                                       in
                                                                                       CD
67-09-97   14:3'J          Triangle Laboratories of RIP,  Inc.
Sanj'lts: MOST 3 SET  1  TUBEA/B  T/IC  173-46-10A/B  TLI»42284
(919) 544-5729
  Instrument H
1181 (11.811)
108-
HFS -
8
H/Z
9
51 78
I 1 63
.,1-1. l'.|. J-Uv*. , 	
1 74752
104
n
( 	 llll
58 180 15G 280 250 308 358
HS368'1181 (11.811)
"*" 1
I
i
8-

I 62976

f2 107
5y ISS 158 280 258 388 358
bb (11.B71) o-Kyiene FIND
108-
KFS -
8-
M/Z
9
3*» 51
A 5 77
1 198
106
?2 10?
i .1 ;'
se iee ISB 200 259 see 350
-------
                                                                                     in
                                                                                     CO
87-09-97  14:39          Triangle Laboratories of RfP, Inc.
Sanple: WST-3 SET  1  fUBEA/B  T/TC  173-46-10A/B  TL1*42284
(919) 544-5729
  Instrument H
ne& (11.B&D
100-

__
%FS "


B-



li
103
7 8
51

ij
.... J
_ — . — _ — ^

63
,,,. J., 	 !.


91
1
,,„.,_. L. 	
94 132096



105

I...
' " " ' !--. . , . - , .j,. ,.§. ...,..,- ( ... , j , -.»!-. , . j , . , . ( , . . . (
w^z 58 158 288 250 388 358
(11.0&1) REFINE
a x~t ri
1.B01
1


XFSJ r.
j *•;

«.i
-In -
j»- ,—_ j-
164 115712


103
78
]_
, ,76
fi "1 %
•jf i_* *,
!„. i!,, 	 ,ii

182

^J9.4







i i . i , . . .,....,....,,...,,...,....,..,.,,...,...,,...,
»^z 59 158 208 250 388 350
56 (11.121) Styrene FIND
100-1
i

X.FS-

8-


g
J, .!

11

103

1 7
63 j,
102
, 9.9 ."i
14 100



105

" J •• • « • i «• . - .... . .... | * .,,£.... j,., ...,...,,.,,. ,...,
PS/'Z 58 188 150 280 250 3B8 350
-------
97-69-97 14 :39
Sanpio: TOST-3 SET 1
1173 (11,791)
1091 lc
• 'M' 37
X.FSJ ii .„
; |l _ °9?9
J I  150 209 258 368 350
Aiwene FIND
, "f
f 158 260 258 300 338
CO
CO






-------


oy/H'3/y? 3
V:,fi,tfp' ||nOf_
- «*.**'«!-- .• l.~ * v >/ 1> 1

jiiAjoH 153 Ci
H
1 n < ...i
\n/z ' ^^ ' ' '
(I
i js.
j""3 ')]
is j a,- s =•=.-* t O
•'I .f. r « or-lJL o
199- 4l1
n (I
fix F:749 1
t8«| 4
'^qi^ ..IX^i
If--? F;737 1
.l»8i 4f
A';i ._J,



.4:3
-3 S

, b3t
.3

• i ' -
50
E"-~»4
b-ju
f i
55
@9i
3
44 1
•-"
429
3
5
cT CT
620
I
f
50


!9 Triangle Laboratories of «TP, Inc. (919) S44-S729
:JET 1 TUBEA/B T/TC 173-46- 10A/B IL!if42284 Instrument: H

I) NBS
1212416
..,.7.2
180 156 2@Q 258 358
L) NBS 242 Hits : 242 Searched
1081344
•3-p
IIVDROXYLAMINEj O-C2-METHYLPROP¥L>-
C4H110H 255
p&
: PENT ANE, 2 , 4- D I NETII YL-
255
7 C7H16
58 gp
:PROPANEf 2-METHVL-1-N1TRO-
7 C4H902H

188 150 206 25© 366 356
in
CO

















-------
                                                                                   Of)
                                                                                   in
                                                                                   en
09-Jul-9? 14:39         Triangle Laboratories of RIP, Inc.
Sample: WST-3 SET 1 TUBEA/B   I/TC   173-46-10A/B  TLW42284
(919) 544-5729
  Instrument H
70 (0.700)
I00i 60
XFS 44
Q : ,-..,«,-..,. 	 , ., 	 , . .
M/Z 50 ' 100
2424832
150 200 250 300 358
HS368'70 (0.701) REFINE
1001 6
XFS 39 43
0 1 , L 4 , | , (1 f , , , , ,
HI F.649 2898 : PENT A NOIC ACID/ 3-METH
100i 6
XFS- 39 -, 43 55 56
o ;\Ch ,, , VIM
4t2 FI512 751:BUTANOIC ACID
1001 6
v ire * O-C^*" .** ** 3 9 ^***
jSOl-jjQ 3 8 y / ^5
0 ]1 i 1 1 1 • l^i 1 1 1 ' '
*3~ F.501 1538; BUI ANOIC'
1001 ,q 39
V.FS 2627 7 38
0 f5f,8 \ j,)^ ,\
ACID, 3-MIlH¥
/41
h5 55\i
M.I.. _,,,•«! ,
NBS 348 Hits : 348 Searched
3 2375680
85 8?
VL-
i 255
61
HI ..jf,, -j .JI I | , ... | . , .1 |.I j f | . , « M | t .1 -J- -"-|-- --| - - ' l | '•*'!
0 255
f ™-
0 255
/ .69 ^1. . 8i7
w/z 10 ' 20 ' 30 ' 40 ' 50 ' 60 ' 70 ' 80 ' 98 ' 100 ' 110 ' 120
-------
                                                                                    in
                                                                                    en
87/09/9?    14:3y        Triangle Laboratories of  KfP,  Inc.
Marble:  MOST-3 SET 1 fUIIEA/B  T/TC   173-46-18A/B  fLItt422B4
(919) 544-5729
 Instruneirt: H
865 (8,651)
IftWi 2I
XFS j «s§ 115t «- , i?? 19i
H/Z ' 58 ' ' ' ' ' i^0 ••'.-•- ^^ - . 2^Q
!£>%!)' 865 (8.651) REFINE
iee, m
..,-- *
91 F;854 22491 : CVCLOTRIS £LOk'flNE, HEXAHETHVL-
ie«i 2<
xKS-j
al 1*» - ... 9i6. 1.19133 .. .. 177l?l
«>: F:715 38155 :ARSENOUS flCI»t TRISCTRIMETHVLS
?l
Ii0i £3
'""ql 44 73 IR5 133 . Ifl
f? F:54B 2262a:A,2-BIS(TKINETHyLSILVL>BENZENE
n^. 191 2C
xFfij 43 45 7^. ft8 131

H/Z ' SO 1 106 ' 158 208
NBS
17 745472
258 356
NBS 24 Hits : 24 Searched.
r? 417792
208
I ' * "f""* f '" I * * I1 1Ll
17 C6H1803S13 255
268
/
ILVL> ESTER
17 255
C9H2703Si3As
268
ir2i>9 .
• • » t . . L . , .... , . - ... | -.,-..,,,. (
*7 255
208 ClZHZZSiZ
^ 222
258 368 350
-------
                                                                                        o
                                                                                        CO
             14:39         Triangle Laboratories of IfP., Inc.
jwmple; ypSf-3 SET 1           f/TC  173-46-18A/B
                                                                      (919) 544-5729
                                                                       Instrument:  II
m:m  20? (2.070)
                                                                                 NBS
                                                                             28GV28
          3!) 4.5
                       83

                                     158

                                                           258
                                                        30S
                                 358
!fl?UC>0'207 (2.671)  REFINE
                     8.1
                       83
    ,       __45  6.1 79 •
   ai.
 411  t:S67   2?88:£THANE,  1„2-DICHLORQ-i-FLUO!O~
                 *,  ei
    i
                                                         NBS  93 Hits : 93 Searched
                                                                             262144
                 ftl^Cis
xrs i     _  43
  Q '!     Hfr. ... \L.t. L Li"  11  96  1ii6
  |..| ^, „, ... -,. _..T^ yC^.x..tiJ. ^ li /, y.MfcU^.^.dBi.,. I.L	j.	*.*|	1.3	,	lAj •-.,._,.	..i....kli|_.p- ,-,—_
                        E,  i,2-J>ICHl.ORO-2-FLUORO-
188
                     81
                       83
                                                                     C2H3C12F   255
                                                                     C3H5C12F
                                                                                    I
        27  33 ?55
        ,  ^ /..,.;,,. ..Li/.,...|tL ....
 11-3  Fr 4«I   125§7 ; PHOSPHOKODIflMIBOUS FLUORIDE,
1.8111                 3ii
                                                    I-' -blHETHOXY-N, W -MMETHYL-
                                                                     C4H1Z02M2FP
59
                         ie@
                                    156
200
256
356
-------
09-Jul-97  14:39         Triangle Laboratories of RTF, Inc.
Sample:  MOST-3 SEI 1 TUBIA/B  T/TC  173-46-liA/B  TLIH42284
(919)  544-5729
  Instrument H
HS3(
100-
XFS
0-
)8 95 (8.950)
41 438271
1 5f
... ! 1 	 ,.^.11.1.. . .
w/i 58 ' 180 ••••••• 15g ••-,-- 288 ' 250 ' 388 " " ' 358
HS3£
100-
XFS
0.
#1
100
XFS
0.
«2
180
7.FS
0.
tt3
100
XFS
0-
>8'95 (0.951) REFINE
41
39
?,7 i i
'FI733 '809:HVDROXyLAMl'NE
T
"h
Fl 724 '552 1 1-PINTENE, *4-
4
>ff 2|7'8 ,39]l
F:708 1642:HVDROXVLAMIN
4
41
3,9 1 ,
MBS 58 Hits : 58 Searched
425984
44 56 58
( 5A | 1 , N ,
, O-(2-METHyLPROPVL)-
,43 255
44 55vf|* 58 78 J1
ft6, ,,5.^l n, Mlr7R
1 | 1 C . . | 1 . 1 1 | 1 ll|..,,|...l|IIIIJ,,.,(1ll,I,.,l,,..,(...i1.ll.(....
MITHVL-
3 255
A- 55
/ sail 6,9 «,4
1 1 ' ' " ' 1 • • *• ' |l!l.,llli|ll««|l-.I|-lll|lllI|I. ..,,...,....,.,..,.,..
E, 0-(3-METHVLBUfVD-
3 255
44 55X 56 78 J1
/. 53V.. \\.
M/zifl ' 20 ' 30 40 ' 58 ' 68 ' ?0 ' 88 '90 ' 100 '
-------
                                                                                    CM
                                                                                    CD
                                                                                    CO
            14-39         IP!angle Laboratories of  IIP.  Inc.
Sanplc: UOST-3 SIT  1           T/TC  173-46-I0A/B
O19) 544-S7Z9
          t *  I!
ilS3&8 185 (1.
i»«l ^
K/Z- ~~I
us3&u'iub d =
ige-j 4i4
KFg1 J
«.l F;73b o
VFC] 39""i
" "1 'i i
• «a F:?a3 i
i ea i 4
i
«~3 "f £ (F j r
#3 F:V2B fe
_ .-t
«SJ 39^
H/Z
856) NBS
3 2334V2
f» 7 "7 - J
,, ,...5J. ...,.!/'
5«3 i»e 15S 288 3O6 35H
8bl) MEF1NE NBS 03 Hits : 83 Searclied
3 217088
89 J HVDROXVLAMINE, O-t2-METH¥LPROPVL>-
3 ^ C4H110N 255
4 If 5 3 ?^
2 9d I ACETIC flCID, 2-FROPENVL
H 255
— j_| !_ y. -^
i-brtdU/-
44 57 f
331:»!EFTnHE, 4-i13I3)O-
44 ?7« C7H15N3
f 1 fB «-1 9JB .
58 160 158 208 250 366 358
-------
                                                                                     CD
                                                                                     CT3
89-Jul-97  14:39         Triangle Laboratories of RIP,  Inc.
Sample:  MOST-3 SET 1 TUBEA/B  T/TC  173-46-18A/B  TLI842284
(919) 544-5729
  Instrument H
HS3e
100
XFS
0-
}8 82 (8.828)
43 376832
|45
...lit.... 	 	 	
M/Z 50 ' 100 ' 150 ' 200 250 300 350
HS36
100
XFS
0.
ttl
100
XFS
0.
*2
100
XFS
0.
*3
100
XFS
0-
>8J82 (8.821) REFI
A
41
NE NBS 38 Hits : 38 Searched
[3 389120
44
/ ...57.
FJ819 97; PROPANE, 2-MEIHVL-
43 255
42 I
o-»29 39 \ 44
.fif/ ,-,;,!! I/- 	 5.7..
F:736 1298:ACETI<
4
39s
F:?33 4521:ISOXfl:
42
39
w/z 20 40
: ACID, 2-PROPENVL ESTER
[3 255
44 57 58
/ ^ f r61
-------
UV/BS/gy 14:39 Triangle Laboratories of IIP, Inc. (919) 514-5729
&mu!e: UOST-3 SET i TUBEA/B T/TC 173-^t6-18A/B Instrument: H
485 (4.858
1 fM-j, Sjl
KFK-? Y25'
g I , ill. ...J
«
-------
in
en
07/Ui)/W 14:39 Triangle Laboratories of IIP, Inc. (919) 544-5729
Sanple: UOST-3 SEI 1 fUtiEA/B T/TC 173-46- 10A/B TL I 842284 Instrument: H
778 (7.781)
198j 41 5i5
vFSJ || |5
M/Z 58
;= is't ' irf-" f"\ ? 1™i--ff~i f=~f ""Si™* -3 "*
^ !=;>dci8 f f d < 7 = 78 1 J
.1.80-j 41 'JJ
a i- - t U - ..* t"
1 88 -3 S5-.'5
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3} 1 ,.f, '
12 F:i*52 2362;
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108} ^ ?J5p
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... .8|? .3.7 *|2
168 150 288 258 300 350
NBS 112 Hits : 112 Searched
37888
78
••» i
8i? H2
CYCLOPROPANE, PENTVL-
69 oq
7 !i7j_ ^
,.,1-^ 4 9.7 H2
1-OCTENE
255
69 C8H16
7 j)71 «3
1-HEPTENE, 5-METHYL-
70 255
6 71 83 C8H16
* •*• /
168 158 208 250 368 358

-------
                                                                                    to
                                                                                    CO
RVV09/97     14:39         Triangle Laboratories of RIP, Inc.       (919) 544-5729

?jam>Ie: UOST-3 SET  1 TUIlEA/B  T/TC  173-46-18A/B  TLHt422B4         1
HS3f
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57
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. . - , i . . i | . , . . i . i ! . . - - j * i i - i •) . f . . j
255
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255
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203 253 330 35@
-------
Pacific Environmental Services : '"<-
Project Number 42284
Sample File: HS369
Client Project: .8407-603


Sample ID:
Date Received: 06/30/97 • :
. Date Analyzed:: 07/69/97
Method 8240A VOST
VOST-3 SET 2 TUBEA/B T/TC
; Response Bile: ICALH708
•;••'" ""•• ;•'


Analyte • :- •• '. ; •• -•
Bromochloromechane
Chloromethane
Vinyl Chloride
1,3-Butadienc
Bromomethane
Chloroe thane
Vinyl bromide
Trichlorofluoromethane
1,1-Dichloroethene
lodomethane
Carbon disulfide
Acetone
AUyl chloride
Methylene chloride
trans-1 ,2-Dichloroethene
tcrt-Butyl methyl ether
Acrylonitrile
n-Hexane
1 ,1-Dichloroethane
1 ,2-Epoxybutanc
cis-1 ,2-Dichloroethene
Chloroform
1 ,2-Dichloroethane
Isooctane
1 ,4-Difluorobenzene
Vinyl acetate
• • v _i i f-_ i r j, y r"r"'. .. • KJ s '. A /*"* * UT
Amount rirAVK: :.•;• . IV iv •:•
IS 1 4.48
0.232 0.93
U
0.195 1.08
0.015 J 1.41
0.013 J 1-53
U
0.048 J 1.82
U
U
0.446 2.48
0.095 B 2.56
U
0.979 B 2.95
U
U
0.665 3.24
0.492 ' 3.54
U
U
U
U
U
0.021 J 5.27
IS 2 5.63
U
' Defc Until '~.~^.\,-:f ;Quao, limit
0.05
0.001 0.05
0.05
0.05
0.05
0.001 0.05
0.05
0.001 0.05
0.001 0.05
0.05
0.05
0.001 0.05
0.05
0.001 0.05
0.001 0.05
0.05
0.05
0.001 0.05
0.003 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.05

0.001 0.05
NA- Not Applicable; Det Limit Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B:
Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax; (919) 544-5491
             Savar v35
Printed: 22:11 07/25/1997
                                                                                                              367
-------
                                     Pacific Environmental Services
Project Number: 42284
Sample File: HS369
                       Method 8240A VOST
Sample ID: VOST-3 SET 2 TUBEA/B T/TC
fiflfjllfll^


Aualyte ; ( ,J" ] ....
2-Bucanone
1.1 ,1-Trichloroc thane
Carbon tctrachloride
Benzene
Trichioroethene
1 ,2-Dichloropropane
Ethyl acrylare
MecHyl mechacrylatc
Bromodichloromethane
cis-1 ,3-Dichloropropcnc
trans-1 ,3-Dichloropropene
1 ,1 ,2-Trichlorocchanc
Dibromochloromethane
Ethylcne dibromidc
Bromnform
Chlorobcnzcnc-d
4-Methyl-2-pentanone
Toluene
Tetrachloroethene
2-Hcxanonc
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylcnc
Styrene
1 . 1 ,2.2-Tecrachlorocthanc
x:-:--x:x::-:-:ix:v-:---K-::-:^-x^^^>x-::i:':i:-:.i':-.-:-:-x:-: •:^:-:v:-:-x:-:-:-:-'-:v!-:-:i: :•::•••:• :•*: •:'.<••:••
:•.:.-•:-.•:-: :-:v:v>: :•>••>.-:•::-: Xv:- •:•:•:•: :*•:*•:•::::::•:•:•"• vx-: x:-:-' :• -:v vvx : ::•::•••:•:•"•:•: x- •:••
^sms^^M^i^se^^mim^
.. •,•.•,;.•,:.-.•. .•. .:-:.:/.v.v XT^y'Tv -™-,v -.-. . . . . . . . .; ;^E:^;; ,.; :;!::::;:-,;: ;.T.v... -•-•,: v..-:-T .:••-•.•.: .:.•:•:.;:•.


- -ag ' .: • • :; : ;;: ',-
0.014 J 4.36
U
0.003 J 4.89
0.637 B 5-10
U
U
U
U
U
U
U
U
U
U
U
IS 3 9.75
U
0.269 B 7.56
U
U
0.008 J 9.79
0.043 J 10.08
0.137 10.31
0.043 J 11.02
0.103 11.07
U



;'•', "-; t
-------
                                      Pacific Environmental Services
Project Number 42284                                                              Method 8240A VOST
Sample File: HS369                                         Sample ID: VOST-3 SET 2 TUBEA/B T/TC
Client Project:. S4Q7-003
TLIID:173-46-llA,B
Dale Received: 06/30/97
•'•: Date Anailyzedi 07/09/97
Response File: rCALHTQS


Anaiyte . :
Cumene
Surrogate SiiaH»aoy ~ ,
1 ,2-Dichloroethane-d
4
Benzene-d
6
Toluene-d
•.... '*•'*•-. . • '•'• '
•: •.: . ADttGJJDtfc .FLAG •
0.003 J
.<'."•.. ', .• ff -.-.<•. ^ •.-.-. * t .. * -. j
j-jtHVcmiit %
0.239
0.267
0.277
•:•. ';M :"-
11.79
•.:!!. '.•:'.'. . •••.••
5.08
5.06
7.47
^^•:^^^^\
0.05
• • •".•.••"•••'' " -T •
-{•--> :::--.-''^..:.;--.;
1 96
2 107
3 111
Reviewed by.
                         NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
     IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range

Triangle Laboratories of RTF, Inc                                                                              Savar v3.5
801 Capitola Drive • Durham. North Carolina 27713                                                      Printed; 22:11 07/25/1997
Phone: (919) 544-5729 • Fax; (919) 544-5491
                                                                                                     369
-------
                                    Pacific pjvironmental Services
Project Number: 42284                       Method 8240A
Sample File:     HS369                      Sample ID:         VOST-3 SET 2 TUBEA/B T/TC
Client Project
TLJID:

S407-003


Dilution Factor:
Date Received:
Date Analyzed:
1.00
06/30/97
07/09/97

                               Tentatively Identified Compounds
  	Name	KT...::	Atga	JSHT	IS Area		

   Unknown                         0.711      41822764       4.491     8847156           1.182
   Methylbutane Isomer                1.620      15802291       4.491     8847156           0.447
   C4H8 isomer                       1.021      10609605       4.491     8847156           0300
   Hexamethylcyclotrisiloxane           8.651      12783530       9.751     11001446           0.290
   Pentane                           1.930      8181850        4.491     8847156           0.231
   C6H12 Isomer                      3.451      7696993        4.491     8847156           0.217
   C9H18 isomer                     10.481      7726296        9.751     11001446           0.176
   Octane                            7.791      6865834        9.751     11001446           0.156
   C5H8 Isomer                       2.170      5091624        4.491     8847156           0.144
   Methyl Propane Isomer              0.861      5027924        4.491     8847156           0.142
Triangle Laboratories, Inc.
801 Capitola Drive* Durham, K?oith Carolina 27713                            Printed:  10:26   07/25/97
Phone: (919) 544-5729 » Fax: (919) 544-5491
                                                                                          370
-------
                                                                                     CQ
          15:87         Triangle Laboratories of BTP,  Inc.
Sanple:  MOST-3 SET 2 TUBEA/B  T/IC  173-46-11A/B   ILIS42284
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achioroe/i
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                                                                  373
-------
07-0g-97  15:07         Triangle Uhnvatories of IIP, Inc.
SanpJe: VOST-3 SET 2 TUBEA/B  f/TC  173-46-ilA/B  fLIft42284
(919) 544-5723
  Instrument H
93 (0.930)
1001 s8
*,'iTC -\
""&J 44
15 ....,, J|.ill
52
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(0.931)
1881 5
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1 49
8
52

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5
XFB]
. 44
0
52

w/z 58 ' 190 ' ' 158

141312

260 256 38B 350

128808


288 256 388 358
FIND
188


288 258 36fl 359
-------
                                                                                       in
                                                                                       r^
                                                                                       CO
89-Jul-97 1S:B7         Triangle Laboratories of RTF,  Inc.
Sample: UOST-3 SET 2 TUBEA/B  I/TC  173-46-ilA/BTLI842284
(919) 544-5729
  Instrument H
HS369 188 (1.088)
100
XFS
0
H/Z
3

Jl
9
5
50
\
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138240
4

64
HI. i.
»"• • i • • • i • • • • i • • • • | . . • • j . . • - , . . . . , . . . . , . . . . , , , . .,,,,.. ..... , . . . . , . . . . ,
50 100 150 200 350 300 350
HS3&9'188 (1.881) REFINE
100
XFS-
0
W/Z
5
53
50
\
4 109568


50 ' 100 ' 150 ' 200 ' 250 ' 300 ' 350
MASTER 11 (1.440) 1,3-Butadiene FIND
100
XFS
0-
M/Z
3

9
5
50
\
i
100
4

50 ' 100 ' 150 ' 200 ' 250 ' 300 ' 350
-------
                                                                                      CO
                                                                                      r-
                                                                                      co
07-Qy-gy  15:07         Triangle Laboratories of RIP, Inc.

SantMe: VOST-3 SBT 2 fUBEA/B   T/TC  173-46-11A/B  fLItt42284
(919) S44-5729

  Instntnent H
HS369 141
108
6-
44
45
53
141
188-
XFS -
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58
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JL l*f iH **f
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59
(1.41B)
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9
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1
168 158 200 258 3§3 358
(1.411)
9
93
81 '-j
i! ,!
4 7936


188 158 200 256 3B8 359
(1.428) Branonethane FIND
9

93
81
1,1, H
4 108



ie@ 150 268 250 380 353
-------
                                                                                     cn
R7-89-97  15:87          Triangle Laboratories of  BIP,  Inc.
Sanple: WST-3 SET  2 TUBEA/B  I/TC  173-4&-11A/B   TL1M2284
(919) 544-5729
  Instrument H
153 (1.538)
4d 15872
188-] '
1
;if'K-j - 55 .
~] !! fc/3
__0-
III 1,
i Jil j.sl!l.
78
50 100 150 200 250 300 350
HS369'153 (1.531) REFINE
100-
vf-e-
0-
H/Z
6

49
4 5184
66

50 100 150 208 250 380 350
NT2CAA 13 (1.540) Cliloroe thane FIND
180-
XFS -
8-
H/Z
6
»3.O[
.-i . .; i ,j*
4 100
66
58 168 150 20O 250 308 350
-------
                                                                                  CO
-y7  35; 97         Triangle Laboratories of RfP, I«n.
e^ VQST-3 SET 2 TUBWB  T/TC  173-46-11A/B  TL!«42284
(919) 544-5729
  Instrument H
102 (1.820)
4' 1 C
^ ncH ~*
| 55
XFS '
8-
K/S
44 73
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U 27392
183
1S5

56 150 36-8 35O
113369' 102 (1.821) REFINE
iei

9-
M/ 2.
ie

4,7 6|6 8,2
LI 25344
163
105
f
58 108 150 200 250 300 350
NT2CAA 1U (1.04B) Trichlnrnf luoronethane FIND
inq-, A1?

.,-c-
0-
My* 3
^7 M „
M- I * 1 * - '"^l
11 100
103
105
36 169 150 268 258 368 350
-------
                                                                                      en
87-89-9?  15»8"f          Triangle Laboratories of IIP,  Inc.
Sample; UOST-3 SET 2          T/TC  173-46-ilA/B  IL1842284
(919) 544-5729
  Instrument H
248
* r--*n "*

XFS-
_0-


,M53 6,?
6


78
58 188 150 20e 250
(2.481)
100
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8
7


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6

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pf
50 108 150 200 250
18 (2.500) Carbon disulfide
ley
XFS-
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H/E
7

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6

78
59 183 150 209 250

786432



308 358

774144



308 35O
FIND
130


300 350
-------
07-89-97 15:8? Triangle Laboratories of RIP, Inc. (919) 544 5729
Sample: MOST-3 SET 2 T/TC 173-46-11A/B TL If 42284 Instrument H
XFS -
3 '

256 (2.568)
3 22528
58 76
57 1 78
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w/z ' '59 ' ' " iee ' 158 ' 268 ' as» ' ' ' see ' 350
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XFS -
9-
M/Z
»9'
4
,'Hf
256 (2.561) REFINE
3 17928
ije
5Q IBS 158 288 250 389 358
! 10 (?.57R) Acetone FIND
3 186
44 58
58 188 158 280 258 3O8 356
O
00
en
-------


R7-F|q.
00
CO
-97 15:07 Triangle Laboratories of RTF, Inc. (919) 544-5729
Sample: UOST-3 SET 2 TUBEA/B T/TC 173-46-11A/B ILIft42284 Instrument H
HS369

10@~]
1

XFS -

Q


295 (2.956)
49 839688
i



42
,,Ali
M/Z
HS369
188-

XFS -

r»




84
51
55
I -.! 	 -I 	

88
. .1.
50 188 158 288 258 3B8 358
'295 (2.951) HEFINE
4


42
i

pt/S
,ii
9 827392
84
51
f55
!. ..I. - ....... 1. .

88
.i.
58 188 158 288 258 388 358
HI (2.978) Hethylene chloride FIND

180-

XFS -

e'



49 108



47
41 1
.— »-
W/E

84
51
83


88
/
50 188 150 288 258 308 358
























-------
C!
OD
cn
07-89-97 15:67 Triangle Laboratories of RIP, Inc. (919) 544-5729
Sanple: MOST-3 SEf 2 1/fC 173-46-11A/B fLI«42284 Instrunent H
HS3&9 324 (3=240)
5

%FS- 41

glii-Lj
3 68668
57
i
58
„ \\f' 74- 86
Hilt. .- j .f~, , nf.1^ -i.,vvv=iu^v in----- _ _- _ ,::::, 	 -j. :..:.. _- r .- . I . j. . .min. mm n m.i _ I 	 , v; 1 _ J 	 ^w 1 .VI _ ..... 1 1 L 1 ~ 1 	 T-H -<-X — •— ,-- . ............... 	 1 -. ~n j iirnniini n .
*^ ^*~**-T( • • • ' I f • i » I • 	 • « 	 • 	 1 	 •— ' 	 « ""•'"'" '!-" * ' • •'"• "t '""'• """"'' " '( ' f --.--« -1 • *• "* » L| -i -- i * t -- 1 T- . - - --, "-V-V j i ^ - j — r |
H/Z 50 106 150 20O 250 380 350
HS369*324 (3.241) REFINE
,nn, 53 65024
1001 i
1

y.FS -i ts *,
j-31 %
ej,l ,J
57
r

: [
| 158
j*-j-^-ft, :* i - -* . — • — (- '•""• — i — ' 	 i1" 	 • — ' — • — ' — i — •— — ' — • — | — ' — • — i — • — r"1 — • — '" * 	 i — • — *~~* — *""~1 — * — ' — ' — ' — 1 — ' — • • - — I""1 ' "*""' V" ' •'* ' * I
w'z 5H 180 150 260 250 300 359
NT2C6A 24 (3,278) Acrylonitrile FIND
IBS ^ 16S
51
XFS -
HB
i

I34fi5t
o ,/,,. .il" ./ " . 96 ,
m/T, 58 150 200 256 308 350






















-------
                                                                                       CT3
                                                                                       00
                        Triangle Laboratories of RIP,  Inc.
Sample: MOST-3 SET 2 IUBER/B  T/fC  173-46-11A/B   TLIi42Z84
(919) 544-5729
  Iiistrunent H
354 (3.548)
100-
KFS-
M/Z
4


5
1
56

55
7 454656

f871 86
58 160 150 208 250 388 358
HS369'354 (3.541) REFINE
108-

XFS-
0-
5
4.3

4

44
*50
7 417792


5* 8ft
l@e 150 280 250 388 358
25 (3.578) n-Hexane FIND
100-
XFS -
0-
H/S
5
4,3

I
56
55
. ,...)
7 188

71 8.6
58 130 150 200 250 380 358
-------
                                                                                      oo
                                                                                      01
67-09-97  15:87          Triangle Laboratories of  BTP,  Inc.
Sample: UGST-3 SIT 2           T/TC  173-46-11A/B   TLIU42284
(919) 544-5729
  Instruneiit H
HS3G9 527 (5.271)
1881
y.FS-
.0-
5
56
Y -%"
,.Jji»i| 	 .('ill
58
7 47616
58 84
100 IbB 288 258 388 358
(5.271)
leui
•.*• ET5?
H/rZ
5
56
43 "-•
|
? 33024

9,9
53 1B8 150 208 258 3BB 358
31 (5,291) Isaoctane FIND
i raiii
8-
H/Z
56
4155
,1.1 >
7 168
50
' . . 9,9
59 188 158 200 258 308 350
-------
in
00
CO
15:87 Triangle Laboratories of RIP, Inc. (919) 544-5729
Sample: UOST-3 SEf 2 TUBEA/B T/TC 173-46-11A/B ILIM2284 Instrument H
436 (4.368)
118-
xFS -
0-
H/Z
4

Jl
54 4928
55
, .,[57 72 84
HI ( \ i
58 188 158 288 258 388 358
HS369'436 (4,361) REFINE
100-
XFS "
0-
4

If
3 3536

72
50 188 158 280 258 388 358
33 (4.388) 2-Butanone FIND
108-
XFS '
0-
M/Z
4


3 188

72
57 |
58 188 158 288 258 388 358










-------
                                                                                       CO
                                                                                       oo
H7-09-97  15:07         Triangle Laboratories of RTF,  Inc.
Sample: WST-3 SET 2 TUBEA/B   T/TC   173-46-11A/B  TLIM2284
(919) 544-5729
  Instrument H
118369 489 C4.891)
100-1 i
•
XFS -
S' .
H/S
M- 56
i
| iJ1 "ij i
t
iili , ii,
50
11840


,9 85 M7
= i q Hi
150 268 250 368 350
(4=891) BEFINE
iesi
j
XFS-j •
4
_0ii
NtZCf
I63i
4
XE'S-
8' i
rt/3


1V bb
58
IJ
31
71
! 84
ill !
7 1872


168 156 260 258 368 358
m 35 (4.911) Carbon tetracliloride FIND



47
58
lf.7 100


T
i
121
123
1@0 . 150 200 250 30B 350
-------
                    co
                    en
97  lb:07          Triangle Laboratories of RfP, Inc.

:  WST-3 SET 2  fUBEA/B  T/TC  173-4&-11A/B  TLItt42284
(919) 544-5729
  Instrument H
51B (5,1
*„«-. 7
J.KM3 ^
KF8: ^ 7?
5 JL
Bl)
8
T
L.tL
w/z 59 188 ' ' 150 ' 280
(5.181)
188] 7
XFS- 77
: ¥ 74V
Q -'» , .'[ 1,,, -,rt, ,,.|i|'
8
79
L.. .. . . . .
H/Z 50 100 150 200
36 (5.131) Benzene
188] 7
XFS: ?7
52
^ ' „! |. &3
8

79
;•'
H/Z 50 100 150 208
1687616

250 see 350

958464

250 see 350
FIND
100



250 300 350
-------
                                                                                      Of)
                                                                                      CO
                                                                                      01
87-83-3?  ib:B7          triangle  Laboratories  of  IIP,  Inc.
Sample: WST-3 SEI 2 IUBEA/B   T/IC   173-4&-11A/B   TLItt42284
(919) 544-5723
  Instrument H
756 C7.B61)
IBS] 9

XFS--
/9S1 65 89
w/z 53
(7.561)
9

xt s -
' 39
51 65 89
e-...U-r .-»-! -, 	 r-
M/Z 58
49 (7.681)
*e*^ 9

: 39
/ H1 65 89
p ..I,.., i j. ... r\
H/S 58

1
32

93
199 158 200
REFiriE
1
92
93
180 159 209
TollltJiltJ
1
92
93
150 260

512030



250 308 350
462848


250 300 356
FIND
130


250 300 350
-------


07-09-97 15:07
cx>
en
Triangle Laboratories of RTF.. Inc. (919) 544-5729
Sample: UOST-3 SET 2 TUBEA/B T/TC 173-46-11A/B TLIJJ42284 Instrument H
979 (9.791)
1801 1J
XFS-
0-
H/Z
82
54
f! Jx«?£..*3, \>
56

.7 138240
119

150 200 250 300 350
(9.791)
* pp* A:

XFS-
0-
rt/Z
77
51
6,5 9.3, .
2 9408


114
^-
X

5B 133

150 200 250 300 350
NT2CAA 52 (9.841) Chlorobenzene FIND
1001 1J

x.FS ;
0-
H/Z
77
5,1 74
.2 100


114
„••
f
5i
150 20O 250 300 35O











-------
                    o
                    C73
er-Hy-gy  ib;e7
                  Triangle Laboratories of RTPj  Inc.
:  UOST-3 SET 2 TUBEA/B  T/TC  173-46-11A/B  TLW42284
(919) 544-5729
  Jristrtinewt H
HS369 1B88 (18,081)
„ 9

>;FS -
.8-
•Sr*-?;


,, ¥ 6,5 7|
1 99328

166

5e 108 158 268 258 380 358
HS369'1BBB (IB. 081) REFINE
100-
XFS-
e-1
H/S
9

51 65 77
I 84992
1P6

58 158 28® 258 3SS 358
53 (10,131) Ethyibensene FIND
iea-
XFS -
e-
M/Z
9

51 6,5 77
| J J |j
58
1 188
106
Tl©7
' •••!« 4 i , . .
100 158 288 250 300 350
-------
                   cn
B/-89-97  15:07          Triangle Laboratories of RTF,  Inc.
Sanple: WST-3 SET  2 TUBEA/1  T/TC  173-46-11A/B  TLI»42284
(919) 544-5729
  Instrument H
Hs3i
100-
i
XFS-
0
sn/s
H3JC
100
XFS-
0^
M/3!
NT2C
100-
v.FS
p.
39 1831 (18.31
9
1
39
' 5,1 65 7,7
.. J- t .111.),- .Il-i..,. - ..111....... .
1)
1 241664
186
(?2 P7
I.,,., .Jill,. ..
59 lee 158 200 250 300 350
i9J1031 (18.31
9
39
51 65 77
,,!. Ju .jf .,|.'M ,.,..,
1) REFINE
1 207872
106
/2 ^87
50 ' iee • j^^g • 2|^0 - 2!£0 • 3^0 • 35£
:AA 54 (10.371
9
39 £41
b ? «j -^
.'...50. .iu _.!M. ..
) *i-/p-Xylene FIND
i lee
186
92
( J
w^z 58 lee 150 208 250 300 350
-------


87-69-97 15:67
Xanpie: UOST-3 SET 2
HS3G9 1182 (11.021)
*88^ 3i
j
xFS-
0-
M/Z
T«3 T?9
,!,L. .|l|. J.!....,.,!!,!!!,.^..
1C
i... .1
CD
CO
Triangle Laboratories of RTF, Inc. (919) 544-5729
TiJDEA/B T/TC 173-46-11A/B TLIM2284 Instrument H

73728
%-l
1
50 100 150 200 250 300 350
HS3&9J11DZ (11.B21)
138-
XFS
H/S-
9

"i::. . ,.
1
nEFIHE
61952
1R&
92
i .

187
3 159 238 253 3G8 358
NT2CAH 55 (11.071) o-Xylene FIND
ies-i 9
j
XFS-
r%/S
OA ^1
' / .«r 77
,i,.i i. ii .,.!„ .
L

1
92
1W3

187
|jx
58 100 150 268 258 386 356










-------
                                                                                      00
                                                                                      CO
                                                                                      en
87-89-97  15:87         Irianfle Laboratories of IIP, Inc.
Sanple: WST-3  SET 2 IUBEA/B  I/TC  173-4&-11A/B  IUt42284
(919) 544-5729
  Instrument H
lie? cii.871)
180-
..K-C-
0-
H/Z
i!
103
78
I I 63?1'l
Y
,.. ,....! 	 !
H4 141312

105
i 	
58 lee 150 200 250 300 350
HS369!1187 (11.071) REFINE
108-

e
IH/Z
ii
103
78 \
, T j\
102
	 	 i
14 123904


5i ' 168 •••'"'' j_^0 ••••-•• 2
-------
                                                                                      en
                                                                                      CO
1Q-
11;-a?
,?,-<-? * f.J I
                         Tr-i angle Lafenratorics of RTF*  Inc.
Sample; WST-3 SET 2           T/TC  173-46-11A/B
(919)
  Instrument H
Ii

- '•« . 41
x.FS: i
•
j
el ih j'

H/S Sl
!HS3o9rlJ
ies-
XFS- ^
1 T
nl h f

w/z 5*
rlTZCftft F
IBB]
1
XFS i
1
f
I 5

,_. f _,. £7 £
JFI/" £; ^1 :
7g (11 ?gl)
1C
57
69 ^«
79
j j 91
ii ,;,!ll i|li!t lit i

j let
.79 (11,791)
1C
183
"j f -f 7
,!,[i hi , Ii, .i| ^i i

3 1SS
IB (11.851) s
it.



1B3
Leo ^i"^
.- ^»?* J.! i
3 LB'i.

J5 7232



12©

•' 158 256 see 350
REFINE
15 5584
128
T
1 ' ' I i ,
. . i i ....,..,. i .,,,,...,..,.,.... j ..,,,....,,,,. (
« 150 268 258 368 356
"HWROR FIND
J5 106



126

i j
1 150 2©0 258 388
-------
                                                                                    in
                                                                                    CD
                                                                                    cn
09-Jul-97  15:07         Triangle Laboratories of RTF, Inc.
Sample:  UOST-3 SET 2 1UBEA/B  T/TC  173-46-11A/B  TLI*42284
(919) 544-5729
  Instrument H
HS3f
100
XFS
0-
i9 71 (B.71B)
68 2949120
M/Z 58 ' 188 ' 158 ' 200 ' 250 ' 300 ' 35£
HS36
100
XFS
0.
ftl
100
XFS
0.
#2
100
8-
>9'71 (8.711) REFINE
6
3V/43
,,il|fii , •
F!638 2898:PENTANOIC flCIP, 3-METH
6
3941 j?3 55X;6
- | i i M (fill M, . |llll
F:514 751:BUTANOIC ACID
6
2627 38 39^|»
^ 1 1.. .NI. (LI .,
m F:468 1538:BUTANOIC ACID, 3-METHV
1001 39 41 6
'^FSJ 2627 /9 38 I /|45 555,6
01 JLSfS \ ,|^J, l\\i ,1,],, |I(I(N|!| ,
«/z 10 28 ' 38 ' 48 58 ' 6
NBS 258 Hits : 258 Searched
8 2981888
62
1 1 1 1 L J »
VL-
8 255
61
8 255
61 73
L-
0 255
/ ,6I^1Nill , ,71, ,,
0 78 88 98 188 118 128
-------


W/m/'ff 15:07
to
en
Ipiaiigle Laboratories of RTF, Inc. (919) 544-5729
S*«i)le: VGST-3 SEI 2 T/TC 173-46^11A/B IL!i42284 Instrument: H
mjfti 162 (1 = 628)

: ^Q
y.ts- -\
o ' J.

Sffj'

H/S 58
MS¥i9'162 C 1.621)
4.3
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487424

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186 159 200 250 aee 350
N^ 242 Hits : 242 Searched
446464




~ -"•
£ &
k1 MS , 0- ( 2 - NET H V LPJtOPV L ) -
C4H110N 255
°/72
'_• i * *___ ' ' 1 ' ' ' ' ' ' I ' ' • ' ! i * ' ' "I • • • -i • • • • ! ' • --,•--• | - • • • , • • • • ,-*..,
if ii'fcJ'S* u ff = |i * O i^B 	 : T\ f INI'lj**!* 1 j !.,'¥'« 	
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166 ' 159 ' 208 ' 250 ' 360 ' 358


























-------
89-Jul-97 15:87          Triangle  Laboratories  of RIP,  Inc.
Sample: UQST-3 SEI  2 IUBEA/B  f/IC  173-46-ilA/B   TU842284
(919) 544-5729
  Instrument H
HS3*
108
0-
i9 102 (1.020)
41
1 ¥
Jl L. .....11.1.. . . ,
M/Z 50 ' 100
HS3G
100:
XFS-
B;
ttl
100
XFS
0.
82
100-
X.FS
0.
1*3
100-
XFS
0:
^ 182 (1.821) REFINE
4
37 39
F:728 809:HYDROXYLAMII
4
39
491520
150 200 250 300 350
NBS 58 Hits : 58 Searched
1 512000
44 56 58
*E, O-CZ-METHVLPROPyD-
,.43 255
f 44 55Cf 58 70 Jl
1 ^4,6 ..sail /. ^fr?2
• • - • i • " " * 1 • - • • i • - - • i • • ' • 1 • • • 1 • -i * • * • r "*• ' • • i • * • i • * * • t • • • 'i ' • • • i • • • • i • • • • i '•"*• • '"• "i « • • • | • • • • | . . . . | . f . •
F:721 552J1-PENTENE, 4-METHVL-
4,3 255
41]
2728 39 44 5M &9
F:689 1642:HYDROXYLAM
41
N
INEJ 0-<3-MEf HVLBUf «D- •'''•'•
43 255
44 55X 56 70 J1
/ K2q / x !
« .1 ___ »*,%«_ AJ»_* ,11, .
I''''!'''1!''-'!''''!'-''!'-' 1 •!••••! 	 ,,.,.,....,..,,,,,,.,,..,,...,,....,.. .,,..,.,..,.
M/Z10 20 30 40 50 60 70 80 90 100
-------
                                                                                        00
                                                                                        en
                                                                                        en
OV/H'V'*?     15:07
                           Triangle Laboratories of Elf,  l«r..

                       TUBEA/B  T/TC   173-46- 11A/B  IL1942284
                                               (919) 544-5729

                                                Instrument: H
       8fab (8.651)
SM/'Z
f --j-
!= =•
Ri^ibTW&S (8.651)
2i
96 1A\ 133 1?\ If 1
iee is-3 sea
NBS
i? 417792
sea
_..•
H-
250 358
                                                          NBS 35 Hits  :  35 Searched
                            119
                                                   jzet

                                                  -A.. .,
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     F: -S3I   224VJ.: CVCLOTRISI LOXRNfc, KEXflHETHVL-
                              119193       A??1?1
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                                                                      bs i IcJUoo 1 -j
                                                    288
             33155 .-nESEHOUS ACID, TRIS(TKIMETH¥LSIL¥L>  ESTER
                                                    268
             fH, . .  ?.?

             36433 ; 3 Jz-l
!>l ISOFRopOXV-i .1,1,5,5. 5-HEXAMKlHVLTRl SILOXftNE

                          287

                     .^133
                     131 I
                    7.3

                         iS«
                                     158
     263
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                                        267
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                                                          35S
-------
                                                                                         CD
                                                                                         CTJ
                                                                                         00
            1S:07         Triangle Laboratories of  KfP, Inc.
               SET 2           T/TC   173-46-ilA/B   TL1842284
                                                                       (919)  544-5729
                                                                               nient." H
      103 (1.930)
            43
          39
            '•   : «
             y|  SJ- 'fc*
             I ...... si .„
              56
                          189
                       150
            289
           250
   see
    356
HS:JK>'193 (1,931)
            43
                                                          MBS 83 Hits  : 83 Searched
                                                                               2048G0
          41
                   72
                 , f- .-.	f£r. ,-
I If 1  F:759  1298;ACEIIC ftCIB,  2-PROPENVL ESTER
"««»..        «
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          39
                                                                      C5H802
              44 5
     _^	2.7, _:iit[
     F: "m  6531: HEPTANE, ' 4-nZIIK>-
            43
          3*}
              44 /
                 57
                                                                      C7H15N3
                                                                                 255
             ^.-aTr&U^
 til  1:729  8@9:flV]>ItOXVLAflINE,  O (2-METHYLPROFYL>

LBQl      41?
 ,,,.       33 '
'iw,^-!!
50
                   •-*"t--
                         180
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-------
                                                                                    o
                                                                                    o
89-Ju1-97 15:8?         Triangle Laboratories of RIP, Inc.
Sample: UQSI-3 SEI 2 TUBEA/B  T/TC  173-46-iiA/B  TLIU42284
(919) 544-5729
  Instrument H
HS369 345
100T4]1 5,6
XFS- .I
e ...1,11. .(4
M/2 50
HS369* 345
1001
XFSJ
0v- .
Ml 1? * QH£
if A I! « oil C
1001
XFS|
0'
(3.458)
205824
100 150 200 250 300 350
(3.451) REFINE
39 41 S
 ...,....,,.. j . . . , i ,..,,.,. ,,,..,.,.. i ......... , ....,...,, ,, .. i .,.,,.,,. i ,,
4261 : 2H-PVRftN-2-ONE, TEIRAHVDRO-3, 6-0IHETHyL-
41 -^ 255
3\ > I / 3 53 ll 5?
" I" ••• J -••!•••• | • • 	 • | • • - • i -T ,•••, ,,.,., |
44O IT* Q ^J ^ AOOQ » ^> U«.VU OAIhl_ O _ /
W£ f . o & 3 *xfiif o . <£rt 2 ]L4$Hn £ I
1001 41 5
0] N I IkS 50.!.
tt3 F:819
100'
XFS-
0 ' < i '
H/Z 20
559:CVCLOHEXANE
5
„„ „„ 41 55
2*J ^ *r "f"" j(^* Kfl \
•HE,' TE'lRAH«bRb-5',6-0iMEiHVL-/ TRANS-
& 255
( 6??9 ?l4 ,
6 255
84
/ 6?N69 83N /5
30 ' 40 50 60 ' 70 ' 80 ' 90 ' 100 ' 110 ' 120 ' 130
-------
                                                                                       o
H7/W97     15:07         Triangle Laboratories of KIP, Inc.
Sanple: MOST-3 SET 2           T/TC  173-46-11A/B  TL 1*42284
                                                                     (919) 544-5729
                                                                      Iwstrunent'  H
            (18.401)
                                                                                 r-
-------
a9-Jul-97 15:0?         Triangle Laboratories of RIP, Inc.
Sample: UOSI-3 SET 2 TUBEA/B  T/TC  173-46-11A/B  TLI«42284
(919)  544-5729
  Instrument H
HS36
100-
XFS
M/2
HS36
I00i
0J
1001
XFSJ
0]
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100-
XFS-
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5
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F : 866 ' 2361 : CYCLOPROPANE,'
43 554
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F:854 2362! JL-C
4
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5.3,
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91136
208 250 300 356
MBS 112 Hits : 112 Searched
61696
9
71 33
/ i
1 1 ..,..,., 1 1 1 1 1 1 ... | .,..,....,.,..,.... | . 1 1 j , — , , .
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(ji 8283
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255
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0 255
50 ' 60 ' 70 ' 80 90 ' 108 ' lie ' 128
-------
:87
                         Triangle Laboratories of RIP, Inc.
&j.w!es  VOST-3 SKI 2          T/TC  173-46-11A/K  ILIM2204
(919) 544-5729
          t: H
217 (2.170)
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REFINE NBS 41 Hits : 41 Searclied
7 48640
BOTVflE, 3-METIIYL-
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3-PUTABIENE, 2-METHYL-
67
69
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? 255
C5H8
69
iee 158 258
-------
09-Ju1-97 15:87         Triangle Laboratories of RTF, Inc.
Sample: MOSI-3 SET 2 TUBEA/B  f/TC  173-46-11A/B  TLIH42284
(919) 544-5729
  Instrument H
HS369 86 (B.
100-j ^j3
XFS- I44
M/Z 50
HS369'86 (8.
100-
XFSJ
0
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100-
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100 150 200 250
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43
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97: PROPANE,' 2 -NET H¥L- '
T
39 ,44
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39 44 57 58
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39 4453 56 70 J1
\ | 1 X 1»'"'*/ \|
40 60 80 100 120 140
323584
300 350
27 Hits : 27 Searched
315392
255
255
255
160 ISO 200
-------
Project Number: 42284
Sample File: HS370
                       Method 8240A VOST
Sample ID: VOST-3 SET 3 TUBEA/B T/TC
(te^SiS^S^^SIiiWIllttiSiSI^^^Sfeli

}(;i::SKSt*f;S«®Ri? ^.^K^Mf^^^Xf^^^^£^^^^iKaiaii^-X'-
:-';~::*":":'-::^"<:->»^^^
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w|||;i|:^gft!p;i||ll Ilii||l|||;||;?:M



0.001


0.001
0.001

0.001
0.001


0.001

0.001
0.001


0.001
0.003
0.001
0.001
0.001
0.001

0.001
HI
;.;:£:t:V:;Y:x:;:-
x::'?:;;x::«!Si:;

0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05

0.05
                         NA- Not Applicable; Dtt. Limit: Detection Limit; Quan. Limit: Quantitation Limit
    IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; t Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                        Savar v3.5
                            Printed: 15:03 07/22/1997
                                      405
-------

:;-:;.>•< .;..;:.:.;. •' ..;:•;::..;; '. •:;:::;?:;:.::::;:•:::::;;:;;:::::;::"::::::;
Project Number 42284
Sample File: HS370
Qient Project S4fl7-OD3
TLl ID: 173-46-12A,& - J .


:;;: 3:«i:£ ::': .: S! :.:::±.: :a: :ii;::;;:Jx;:: :: ::;:..x»?

Date Received:
Date Analyzed
•:-:-;-:S;.fS:.:.::V .*•:•:::••:••;•!:;

Sample ID:
06/30/97
: 07/09/97,
::::"-::::".""::"::::::f:'.:' :'::'::: "- ' :'•": •:.::::::••;•:
||pllli;|l|*fillli
illilllll:
Method 8240A VOST
VOST-3 SET 3 TUBEA/B T/TC
Response Kle:
sv „ , ^,, „..;:
ICA1H708
< ,*


Amlyfe . , .

2-Bucanone
1,1, 1-Trichloroethane
Carbon tctrachloridc
Benzene
Trichlcroethene
1 ,2-Dichloropropane
Ethyl acrylate
Methyl mcthacrylatc
Bromodichloromethane
cis-1 ,3-Dichloropropene
trans-1 ,3-Dichloropropene
1 , 1 ,2-Trichlorocthanc
Dibromochloromethane
Ethylene dibromide
Bromoform
Chlorobcnzcne-d
4-Methyl-2-pentanone
Toluene
Tetrachloroethene
2-Hcxanone
Chlorobenzene
Ethyibcnzene
m-/p-Xylene
o-Xylene
Styrene
1 ,1 ,2,2-Tetrachloroethane
. ••- Amoturt "\ HA.;£- •
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.10
0.05
0.05
0.05
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B:
Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive « Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
             Savarv3.5
Printed: 15HX5 07/22/1997
           406
-------
                                     Pacific Environmental Services
Project Number 42284                                                            Method 8240A VOST
Sample File: HS370                                        Sample ID: VOST-3 SET 3 TUBEA/B T/TC
Client Project S4Q7-003
HI ID: 173-46-12A,B


Analyte .• . • '/;7"
Cumene
Surrogate Summary ,.....-.
x • , .
1 ,2-Dichloroethane-d
4
Bcnzenc-d
Toluene-d
>
'::-- Date Received:
Date Analyzed


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tfflf* ** * • * . • . •.• /
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0.229
0.261
0.279
06/30/9? . :
i 07/09/97


;^: '
11.78
••.•»: :

5.08
5.06
7.47
...'. Response File: ICA1H708
,„ ,„


0et limit • - Qtt«n> limit
• -: :- • yg-: ::•'•••• ' ; tig
0.05
• 15 Re* -'.\. ':;•,' -%R2C "-' ;

1 92
2 104
3 112
 Reviewed by.
                         NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
     IS; Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc                                                                            Savar v3.5
801 Capitola Drive • Durham, North Carolina 27713                                                     Printed: 15:03 07/22/1997
Phone: (919) 544-5729 • Fax: (919) 544-5491

                                                                                                    407
-------
Project Number: 42284
Sample File;     HS370
           Method 8240A
           Sample ID:
                   VOST-3 SET 3 TUBEA/B T/TC
Client Project
TUID:

S407-003
173-46-12A3


Dilution Factor:
Date Received:
Date Analyzed:
1.00
06/30/97
07/09/97

                               Tentatively Identified Compounds
         •Name
            Area
   Unknown
   Sulfer Dioxide
   C6H12 Isomer
   Methyl Propane Isomer
   C4H8 Isomer
   C9H18 isomer
   Methylbutane Isomer
   C8H16 Isomer
   C5H8 Isomer
   Pentane
 0.711
 0.881
 3.450
 0.851
 1,021
10,481
 1.620
 7.791
 1180
 1.930
48937188
14595666
14231927
13586102
12358183
6929598
9845091
6227923
9095175
6880450
5.631
5.631
5.631
5.631
5,631
9.741
5.631
9.741
5.631
5.631
16044722
16044722
16044722
16044722
16044722
10896565
16044722
10896565
16044722
16044722
0.763
0.227
0.222
0.212
0.193
0.159
0.153
0,143
0.142
0.107
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 * Fax: (919) 544-5491
                                  Printed:   11:41  07/25/97
                                                                                      408
-------
07-89-97  15:32          Triangle Laboratories of RTF, Inc.
Sa«p]e: UQST-3 SET 3 lUBEA/B  f/TC  173-46-12A/B  TLIf42284
(919) 544-5729
  Instrument H
                                                                                       cr
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-------
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11
12
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15
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21
22
24
25
26
28
29
30
71


33
34
35
36

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40
41
42
43
44
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46
47
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100
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86
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Vinyl acetate&£/\^
2-Butanone
1,1,1- rrichloroetrharte
Carbon tetrachlorlde
Benzene
Tr ichloroethens\ ' N
Ethyl acrylate /&y
Methyl methacrylate
Bromodichloromethane
cis-1 , 3— Oichloropropene
trans-l,3-0ichloropropen
1,1,2-Trichloroethane
Oibromochloromethane
Ethylene dibromide
Bromoform '
Toluene ^-^
Tetrachloroethene
                     410
-------
-•!o .
„ .
52
53
54
55
56
58
MAT
.__
60
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100
96
100
61
FOR
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86
85
74
95
31
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76
98
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106
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Name
'?-Hexj;i iione(ry
Cnlorobenzene
E thylbenzene
m-/p-Xy iene
o— Xy lene
Sty rene
Cumene
                                      : h 1 o r
Data Review.-Tto
Date: -i
                                        411
-------
                                                                                        OJ
Ry-Bl-t-'jy  1G:32          Triangle Laboratories of RTF, Inc.
Sanple:        SET 3           T/TC  173-46-12A/B
                                                                   (919) 544-5729
                                                                     Instrunenl H
          (0.921
          64
                                                                           598016
Kf'S"
      48
       SS
                  IRQ
158
289
256
388
308
HS37QJ92
      5.8
            .921)
                                                                            49152
        8
                  180
150
209
258
388
3g0

     m 9 f8.93B)  Chiorosotliano
      59
                                                                             FIND
     44
        52
IH/S
       58
                  188
158
268
250
3O8
356
-------
                    en
M7-09-9V  15:32         Triangle Laboratories of RTPj,  Inc.
Sapipie: VOST-3 SET 3 TUBEA/B  T/TC  173-46-12A/B   TLI«42284
(919) 544-5729
  Instrument H
HS3VH 100 (i.BBfl)
188-
* * ~ f - ~
AT -»
g_


4
3 348160
5.4
5B
i
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5C
&4
1 108 150 200 250 350
(1.881) REFINE
; 1 letlsf "1
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MI2C

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""'";
aJ
H/Z

_,
53
59
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4 294912
i


se iee ise 200 250 see 350
:AH 11 (1.898) 1,3-Butadiene FIND
3*^ 100


5,4
58 1
I
55
58 108 15B 200 250 388 350
-------
fly-89-37  15«:

                 Triangle  Laboratories of  RIP,  Inc.
y08I-3 SET 3 TUB1A/B   T/TC   173-46-12A/B  IL!tt42284
(919) 544-5729
  I nstrtinent H
1HS370
188-
= _
8-
4

_M
141 (1,418)
4

4S 64
23552
ifj jrti
l9^

199 156 20» 256 388 350
(1.411)
1.88-

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,A





mzair

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4 11712


1 !.
*Jii*
188 15H 260 258 368
i 12 (1.420) Brononethane FIND

46
58
9,
,3
i lee
i
IBM 158 260 258 363 350
-------
                                                                                    in
67-09-97  15:32         Triangle Laboratories of KIP, Inc.
Sample: UQ8T-3  SET 3 TUBEA/B  T/IC  173-46-12A/B  ILltt42284
(919) 544-5729
  Instrument H

180-
KFS -

i -i
IK/SE
fM5rl"
iwe-
y-FS -




108"
>;FS -
S,
H/S
;8 182 (1.82B)
42
I !
! 55 M
! 64 ?«
1
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58 10
J8'182 (1.R21) I
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58 10
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1T

35
47 fe^ g2
58 18

23808
li
105
j
S 156 200 250 350
DEFINE
ii ifieeo
163

IBS
j 147
8 ISO 200 250 380 356
> ich lorof iuorofflethane FIND
si 100
103

105
\ 117
0 150 280 250 380 350
-------
                    CO
87 09-9?  1S:::i7;          Triangle Laboratories of RIP, Inc.
   Pie: "OS 1-3 SET 3  TUBEft/B  I/TC  173-46-IZrt/B  TLIMZ284
<919) 544-CT29
  Instrument H
HH:^
?0 2-ia (2,488)
IBM] 7
XFS-
: Q-

XFS -
0-
H/Z


6 2768896

78
,!. 	 ....
58 10y 15§ 238 388 358
1T248 C2,^
7

44
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6 2736128

78
58 1@« 158 209 258 3B0 350
18 C2,b6M) Carbon disulfide FIHD
t^CStJ-
m. X"
r^;* JLI
7
44
• I
6 100
78
58 108 158 260 258 388 350
-------
89-Jul~97 15:32         Triangle Laboratories of  RIP,  Inc.

Sample: UOST-3 SET 3 TUBEA/B  T/TC  173-46-12A/B   TLHH2284
                                                                 (919) 544-5729
                                                                   Instrument H
HS378 256 (2.560)
            *»£
100
XFS
  0
M/Z
         5.8
                                                                          32768
                 100
            150
            288
            250
            388
           350
HS378'256 (2.561)   REFINE
     >1O
100
XFS-
  0
                                                                           9280
       50
                 100
            150
            200
            250
            300
           350
MASTER 20  (3.378)  Acetone

100- 43
XFS
  0
M/Z
        58
      50
100
150
200
250
                                                                          FIND
                                                                           100
300
350
-------
                                                                                      oo
07-89-97  15:3Z         Triage Laboratories of RIP, Inc.
Sanple: UOSf-3 SET 3          T/TC  173-46-12A/B
<919) 544-5729
  Instrument H
295 (2.9bB)
Lr,, 49 679936
j
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8
51
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4
88
i
59 186 15Q 200 25G 3S8 358
(2.951)
4

e-
H/Z
HT2C
I8Qi

v-FS-


47
3 667648
84
51
55
88
58 lee 150 200 250 300 350
-flft
4


4?
4,1 1
2-1 (2.978) Hethylene chloride FIND
9 100
8
51
63
4

83
.i
s/z 58 ' ' 158 ' 208 ' 258 ' 388 ' 350
-------
07-09-y7  15*3Z          triangle Laboratories of IIP, Inc.
Sanple: U05I-3 SET 3 IUBEA/B  f/IC  173-46-12A/B  ILIt42284
                                                                  (919) 544-5729
                                                                    Instrument H
      324 (3,248)
100"
XFS
                                                                          356352
  eUw-p,
                 lee
                              ISB
            288
            250
            300
           350
HS370 324 (3.241)  REFINE
       5.3
         57
                                                                          339968
  9-
M/ Z
      50
                  1G0
158
203
250
308
350
       24 (3.270)  Hcrylonitrile

1801   " f

     SI
                                                                            FIND
                                                                             100
XFS
     38
    ,i, .1. .
M
      58
                .9.6 .
                 ies
158
208
250
308
350
-------
                                                                                      o
                                                                                      CM
87-09-97  15:32         Triangle Laboratories of RTF, Inc.
Sanple: UOSf-3 SET 3          T/TC  173-46-12A/B
(919) 544-5729
  Instrument H
3b4 (3.S4B)
IfKh 5>7 234496
" i .^ i
v-FS"
-vS"
*** 1
56
J55
f^^.|
58
58 86
«-B J CcP %«
188 15B 200 258 388 356
HS378'354 (3.541) REFINE
108
XFS-
8-
5
3
1
J

»»™*«jiii^;
58
7 216864

. ?! 8f
1WB 158 288 158 368 358
Hf2Cnfl 25 (3.578) n-Hexane FIND
| OO-! ^
"'"1 f,3
, .—._.
8-


56
55
- ,."(
7 1G8

71 «f
50 18S 158 289 258 388 358
-------
                                                                                     Cl
OV-89-yy  15:32         Triangle Laboratories of IIP, Inc.

Sarnie: V08I-3 SET 3 TUBEA/B  T/fC  173-46-12A/B  TL!t42284
                                                                  (919) 544-5729

                                                                    Instninent H
 HOTja
 =>-3 f O
         55
           1
                                                                            4288
                  ISO
                              ise
238
 »58
see
    356
HS37HM36 (4.361)   REFINE
     ,10
180
           72
  0
K/Z
                              ise
200
258
                                                                            3168
388
\ '   r' \

    350
NT2CAA 33 (4.380)   2-Butanone


180
XFS
        57
           72
                                                                            FIND
                                                                             180
                  1Q0
                              158
288
258
388
    358
-------
                                                                                    CM
                                                                                    CM
87-09-97  15:3>*         Triangle laboratories of RIP,  Inc.
Sample: UOST-3 SET 3          ~T/TC  173-46-12A/B  TLIU42284
(919) 544-5729
  Instrument H
llfti'i^n «~ 4 J s t~- * 4 4 «k
hliiJiO bll la .111,"
180-
XFS -
e
H/Z
7
77
8 1572864
84
5B lew 150 280 250 388 358
MS37B'511 (5.111) REFINE
1R0
XFS-
M/Z
7
77
.,« I .7V
fl 1490944

79
58 189 158 200 250 3Si 358
36 (5,131) Benzene FIND
IO0-
*.*£-•&• _
,-=!• 5r
W/S
7
77
s iee
79
53 109 150 2©0 250 300 350
-------
                                                                                      CO
                                                                                      CM
117-89-9?  15:32         Triangle Laboratories of IIP,  Inc.
Sanple: W8I-3 SET 3 TUBEA/B  I/TC  173-46-12A/B  TLIJt42284
(919) 544-5729
  Instrument H
646 (6,461)
103-
XFS-
.e
4

J
[I 9344
55 6
57
58
9 81
i 1 i l,| . ! !J
1C6 150 280 250 308 350
HS378J&46 (6.461) REFINE
160
XFS-
0
M/Z
NT2C
188^

XFS-
8-
H/Z
6
4,1^5,9
	
rss-
4


^i.
•.Li
9 2864
J0
1 8,8 1
58 108 158 200 258 388 350
A 4B (6.491) Methyl nethacrylate FIND
1 100
§9

?2 59

;'l 1 1 li.
58 136 158 200 25O 308 350
-------
                                                                                      CI
                        frianyle Laboratories of RTF,  Inc.
Sample:        SE1 3           T/TC   173-46-12A/B  TL!tt42284
(919) 544-5729
  Instrument H
IIS37Q 756 (7,561)
IBS] 9

XFS-
' 39
: f 51 *5 8\
1
92
93
W/K 58 ' 188 ' 150 ' 208
HS378'75& (7.561) BEFIHE
108i , 9

-39 -, 0
1
92
S3
w/z 58 IGS ' ' 158 ' ' 208
49 (7.681) Toluene
188-j 9
j
X.FS -
j ( 5,1 ^p 83X
1
92

93
w/z 59 186 158 100

659456


250 368 358

598016


258 38B 359
FIND
180



258 388 358
-------
                                                                                      in
                                                                                      CJ
87-09-97  15:32         Triangle Laboratories of RfP, Inc.
Sample: WST-3 SET 3 TUBEA/B  T/TC  173-46-12A/B  TLIB42284
(919) 544-5729
  Instrument H
979
J.B9

XFS-
0-
H/Z


(9.791)

117 115712
8,2
4.0 "
4
5777
56
H8378J97
1001

H/Z



9


5
119
160 150 200 250 300 350
(9,791) REFINE

77
8

. - . , , , — | ~r
58
NT2CAA 52
188-

X.FS-





51
Q '
H/Z
,i- -. .N
k
1.1

Cl ^J
T* *
2 10304

114
100 150 200 250 300 350
(9.841) CMorobenzene FIND

77

74
\


f
58
1.



J5
.2 100

114
i
i
160 150 200 250 380 358
-------
                                                                                      (JD
                                                                                      CJ
07 m-97  If.:37,          Triangle Laboratories of RTF, Inc.
Sample: UOST-3 SET 3  TUBEA/B  T/TC  173-46-12A/B  ILIf
(919) 544-5729
  Instrument H
HS378 1888 (18.881)
189 1 9
XFS^
n ]..!>.. '11. .,Jl....ffZ.......
i
106
t. 	 j 	
-* - • ! ' • • • 1 • • ' 1 - ' ' • 1 ' ' ' • t • ' ' ' 1 ' ' ' ' 1 ' ' ' ' 1 ' ' ' ' 1 ' ' ' ' 1 '
H/s 58 158 2©6 25©
(18.681) HEF1NE
ic"ii 9f1
..-JP-.-J
j
V.FSJ
H/Z 5O
HT2CAA 53 (18.131
188 1 y
1
n. ( 51 6p ??



L,. .J., ... 4 	 4 . 4 ^ , (
180 158 266 256
) Etl»y I benzene
l

186
|187
»--'s '50 ' ' ' ' lee •••••• j^g ••••••• 2(|e • • 2^@

112640


368 358

96256




389 358
FIND
160


308 350
-------
                                                                                       C-J
07-89-97  15:32         Triangle Laboratories of IIP,  Inc.
Sanple: MOST-3 SEI 3          T/TC  173-46-12A/B   ILItt42284
(919) 544-5729
  Instrument H
1831 (ie,311)
iqg-, 91
i
xFS-
0-


J.L., .i!%,|... ,u",..r.Tli!r..t.r(

106
f2 107
i 	 illi'.. ..
58 100 158 288 250
HS37B'1B31 (10.311)
100-
X.FS -
8-
NT2C
100:
•/-FS-
0-
H/Z
9
39
f 5L f i5 ?ll
1
106
32 J107
i 	 * -
• " * • ** '* • i ' * - • i • ' • • i • . . j .... | . , , . i . . . . , , . , , , , . , . , .
50 100 150 2O0 250
:AA 54 (10.371
9

t> "~f ITf =rj
If_5£ ,,:i TII(I n
) M-/p-Xylene
1
106
*21
50 150 200 250

250880



308 350

216064

388 350
FINB
100


300 350
-------
                                                                                    CO
07-09-97  15:32         Triangle Laboratories of RIP,  Inc.
Sawrle: UOST-3 SET 3 TUBEA/B   f/IC   173-46-12A/B   TL1842284
(919) 544-5729
  Instrument M
1181 (11.811)
1 £ifi-
y.FS -
1R4 114688
T
91
78
51
1 fi-> 79
,L 1, 7U.M '.,..
1 f 06
ji
fl
59 las i5i aee ase 358
HS37Q!liei (11. BID REFINE
108!
HFS-
e
vt/z
«/?•
9


1 65536
196
f2 107
I.. i'
58 188 158 288 258 388 358
;fift 55 (11.871
Q
"
39 51
,- rw «•*
i"' if 65 ' f
.,U 1.,, j.|. T« .
) o-Xylene FIND
1 180
186
92 is?
i .t I/
58 158 288 256 388 356
-------
07-09-97  15:32         Triangle Laboratories of RIP,  Inc.
Sample: UQST-3  SET 3 fiJBEA/B  T/TC  173-46-12A/B  TLIM2284
(919) 544-5729
  Instrument H
1186 (11,861)
188-

vir<;-
~~~ ~


8-
1*
103
78
51

i | 63 '6\


102

B4 446464



185
/
£, __ 	 |ii: 	 	 J|l^ „ . .
LjllM*A(^^Ft»!lV^J«i;«"Mljr{|" _,_ . , , 	 ; ___T „ ^_ r_J _,_ . 	 T ,__ ,_ .... , ,__ _,_,._, . j , . r r._. J-^— - - - j ^— - - , . | , - . - j - ... | . - . r . --j
H/Z 58 108 158 280 258 300 350
H837e?118b (11,861) REFINE
188-1

"FS "
*


8-
11
103
7.8
51

63
lilt
-•*ff -t -f '-it * *iil»«n*i, ..*ll

102
\
.-..8-9 	 i
94 393216



185
/

" ' "* ' r 4 I ' ' ' * f " " l ' 1 r * 	 1 •''-!' • • • | • • • • ) • • • • ] • • • • | • • - - | • • • '( ' • - • 1
M/Z 58 180 158 280 258 388 358
NT2CAA 56 (11.121) Styrene FIND
. „_ i B4 108
108i

KFS -

8-

183
\
51 7
f 6
I 6i3 >;
102
, 33 . j



IBS


M/Z 50 150 280 258 388 350
-------
                                                                                    o
                                                                                    cr>
89-97  15:32          Triangle Laboratories of RTF, Inc.

  e: UOST-3 SET 3  TUBEA/B   f/TC  173-4&-12A/B  TL1942284
    544-5729

liistrunent H
HS370 1178 (11.781)
i&.-i^ 185 8864
~-t
9-
s/z
r 5,7
ii ,
,!] 69 „
|!», ,|«'ik 'M , I'!'! J'llia', I

! !ii i ii u '? rl
58 168 158 260 258 300 358
Hb'370JllV8 111,781) JtEFINK
188-
8-
M/Z
Nfl?
IBQ-
XFS -
H/S
11
j 56 / 79
J.I. j., ii il,ll.r ..l.u| I II 1
»5 5952
12O
.. .Ii 1
se iee ise zee 258 :HHI sse
:AA SB cn.fisn cunRnR FIND
it

5-1 63 !l? \
f ..., *-( ,t . -t* i i , | ;
is iee

j
1
5B ie0 158 260 258 388 35©
-------
               en
09-Jul-97  15:32         Triangle Laboratories of  RIP,  Inc.
Sample: MOST-3  SEI 3 IUBEA/B  I/IC  173-46-12A/B   ILW42284
(919)  544-5729
  Instrument H
HS3;
100-
XFS
Q
f8 71 (8.718)
68
41 62
M/2 50
3227648
100 ' 158 ' 288 ' 258 ' 388 ' 358
HS37BJ71 (0.711) REFINE
100T 6
XFSJ 39\41 43
0] ... 1 1 1 I ..
Ill
100
X.FS
e.
#2
100
X.FS-
0.
#3
100
XFS
8.
F:608 2898:PENTfiNOIC AC!
6
F:508 751:BUTANOIC ACID
6
Mil 9Q -wO y* X 4.^1
M 1 1 , , >i 1 1 , ' •
F:482 4521: I
4
Y
'• • • i • • • • • • • • i • * *~ • i
«/z 38 48
NBS 258 Hits : 258 Searched
8 3145728
V, s'-HETHVL- ' '
0 255
61
1 1 . , , 1 . . , , . . 1 1 | . . - . , , . . 1 | . 1 . 1 , . . . 1 | . . I . | ...... . . 1 | ..,.,, .-» ,,..,,, 4 1 ..,....,
3 255
61 7,3
SOXftZOLIDINE, 4-ETHyL-2f5-»IMEfHyL-, CIS-
2,- 255
r43
^4 53 55 68
If45 (1\ [,,, , ,8,8 129
58 ' 68 ' 78 ' 88 ' 98 ' 188 ' lie ' 128 ' 130 '
-------
                                                                                   OJ
                                                                                   en
B9-Jul-97 15:32         Triangle Laboratories of RTF, Inc.
Sample: MOSI-3 SET 3 TUBEA/B  T/TC  173-46-12A/B  TLI*42284
(919)  544-5729
  Instrument H
HS31
100
XFS
8-
'B 88 (
6
48
	 !J. 	 	
0.880)
»4 1425408
M/Z 53 ' 100 ' 158 ' 200 ' 258 ' 3OO ' 350
HS37
lee
XFS-
0.
#1
100
KFS
0,
#2
100
X.FS
8
'0'88 (0.881) REFINi
6
48
^1
FI823 146! SULFUR D
6
>6 V f?°
: NBS 48 Hits : 48 Searched
4 524288
66
I OXIDE
4 255
66
/
F:3S(S' 33i4:METHAHESULFONVL AZIDE
79 255
45*>48 63%/478w80 m
*3 FJ316
1001 28^
XFSJ
Q j, ,
17965:1, 2-HV
29 4,8 6
r30
r32 1 .
DRAZINEDISULFONYL DI FLUORIDE
4 113 255
67
1,1 ¥
w/z 20 ' 40 ' ' " 68 ' "' 80 ' 100 ' 12B ' 140 ' 168 ' 180 ' 200
-------
                                                                                    00
                                                                                    CO
iff/m/'f?    15:3>i         Triangle Laboratories of RTF.  Inc.
Sfermic;  UOST-3 SET 3  TUBEA/B   T/TC  173-4fa-~12A/B  TLII42284
(919) 544-5729
 I list rune nt* H
Tib--!-"
• !0-:> s
XFS-
u
/
HS31
109
XFS -
n.
Si"
1.PH-
.""« C -3
O -
£1 .
Kl'S :
M/TS
fO 345 (3.450)
41 «
39 "
j 1 6:3 84
50 168 150
'0f345 (3.451)
41 56
43 1
1 ..-' P £Q t>4
in J ,.J;..T
F;f9i 4261:2t!-P¥RAN-2-ONE. TETRAHVDRO-3
42 55
37x| Jf'ff*vp
F;844 4288:2H-PVRAH-2-ONE, f ETRAHV»K>-5
42 "tf
3? 1,43 57
J 1,^6.7 8?, . .
F ; 815 559 :
41 ^a84
58 160 150
NBS
250 388 358
NBS 61 Hits : 61 Searched
1239O4
,,...*,.. ..,.».. ,!.«.,.. ..,....,
,6-DIMETHVl,-
C7H1202 255
,i-»IMETH¥L-, TRANS-
255
C7H1202
255
C6H12
209 250 388 356
-------
               CO
09-Ju1-97 15:32          Triangle  Laboratories of RTF,  Inc.
Sample: MOSf-3 SEI 3  1UBEA/B   f/fC   173-46-12A/B   TL1842284
(919) 544-5729
  Instrument H
HS378 85
I00i
HFS 48
0: Jjll^^^.
M/Z 50
HS370J85
0 ll-.-r-nTT.r-
#1 F:69
1001
XFSJ
0i
#2 F:58
100
X.FS
(0.850)
64 1196032
100 ' 150 ' 200 250 ' 300 ' 350
(0.851) RE1
4\1
i |
7 S597;l-PJ
4
41
39 x
4 97 : PROPAH
4
#3 F:544 11153:1,3
100i 3g41
xFSi 2?293i \
Q\ YU32I.I,
H/2
^INE NBS 397 Hits : 397 Searched
3 397312
64
4850 66
tOPANESULFONVL CHLORIDE
3 255
^48 6,4 797 l 107
IE, 2-METHVL-
3 255
44
/ ,.,.,., 5,.?.,
,2~DIOXATHIOLANEl 4,4,5,5-f ETRflHETHVL-,' 2-OXIDE '
57 64 255
1 / .... ll . 1 / \(.\ I0e {
20 ' 40 60 80 ' 100 ' 120 " 148 ' 160 '
-------
                 in
                 o
89-Jul-97  15:2          Triangle Laboratories of RTF,  Inc.
Sample: UQSI-3 SIT 3 TUBEA/B  T/TC  173-46-12A/B  TLW42284
(919) 544-5729
  Instrument H
HS370 102 (LCei)'
100T4!1
XFS
n.
il ¥ f4
11,,, i, /
M/z 50 100 ' 150
HS378'102 (1.821.) REFINE
1001 V.

xFS-
43
37 39 44
	 V L , ../...
*i F!722 1152 : C VCLOBUTftNONE1, 3,3-bifr
1001
XFS-
8-
39143
i 1 ii

614400


200 250 300 350
NBS 58 Hits : 58 Searched
626688

1 ?«8, ,
IETHVL-
56 255
55N |7 70 83 m

*2 F;7i9 809:HV DROXyLflMINE/ O-ck-HETHyLPROPVL)-'
1.001
XFS-
41 ^3
3lHl /446
«3 FI710 552:1- PENIENE/ 4-HETH«L-
i no ^3
XFS
0
15 2!?28 39II 44
255
5535^6/|« 7*?fa
i -,-,'!' i , ,.,.,.,.,....,
255
g35|5 69 84
w/ z 10 28 30 40 ' 50 ' 60 ' 70 ' 80 ' 90 ' 100
-------
                                                                                      CO
                                                                                      CO
07/03/9?    15^32        fs-iangle Laboratories of IIP,  Inc.

Kdrwte: MOST-3  SET 3          1/fC   173-46^12A/B  TL!tt42Z84
xFS-



H./Z
(919) 544-5729

 I ttstrunsYit« H
i iOO'jq '
i !=}-_» f E,|



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1848 (10.*
59
' .1040 ( 10 , *
43 5
39 !|
jj
F:9@5 24Q5
'II .43
.3 *?""}!
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a? « c^  Ca !
„> r? ,
_j]
- 1 - - 1 . . , '
Ft Jl El ET -"5n~^T~
» =-! -J J -5 7 * (
415
il5*
59
181) MBS
<- 63232
Ffc
61? fl^
. .4 ¥ *i? ..... 126
leS 158 289 258 380
181) REFINE HBS 83 Hits : 83 Searched
K 41728
69
1 ,1 Bl? 9i7
:I-HEPfENE, 6-M1THVL-
FLs6 ^9 COII16 255
157 ;'..
r l[70?3/'ii2

: 1 - OCT EME , 7 - MET If ¥ L-
6-0 " 255
^7 ?9 coma
j,/**^ "q8111126
SCyC.ioOHErTAflOME, 4-HEIHVL-, t»>-
S 255
r.fi 69 82_ Q7 C8H140
1P» 15Q 200 250 368 356
-------
                                                                                  r-
                                                                                  co
67/09/9?     15:32        triangle Laboratories of RTF, Inc.

    le: MOST-3 SET 3 IUBEA/B  T/TC  173-46-12A/B  ILIf42284
(919) 544-5729

 Instrument *  H
IIO'V3Q -1£n f 1
ilOJfTj lh& tl
4
_ : 39
ri/a
iio-n-jiv i£-3 /• -f
no-dro xoi, \l
^
"T'l"!j ^Q 1
XFS^ w\j
pi - ^__li
1*1 F:S34 8
r^flj 11
fa F:746 J,
XFSJ 27 29
ft 3 F:734 I
lilfl, «
r,J 39
ei 	 , 	 , T.l

.620) NB3
.3 286720
1 57
5^l
5O 108 158 258 368 358
=621) NBS 242 Hits : 242 Searched
.3 262144
89 ; H'f NE, 0- < 2-METHVLPROPtf L> -
3 ^^ ^ 255
44JI53 / x
429 : FENTANE. 2 , 4-IMHET HVL-
3 255
57 C7H16
r»5 5fl gg
2-METHVL-i-NITRO-
1 r 255
d?5' C4H902N
' ' 11
5S iee ise 258 see 350
-------
iiv .-"HO /Cj v i r~ = -7
•-.-? f •" ?_f -/-' -/ i JLO - -_i
triple: UOST-3 S
HS370 77^ (7,79:
5
, " ]
«
-------
CO
ff,'/fn/^7 IS: 32 Triangle Laboratories of RTF, Inc.
&u-*He: MOSf-3 SET 3 TUIJEA/B T/TC 173-46- 12A/B TLIJW2284
21B (2,188)
Mia . =,, 6
XFS-J 37 1.51 65
i a\ . . 	 , ';iu.i...4
7
81
,. ..i. iai
»'z 58 ie« 159 280 250
liS37«'218 (2.181)
lvs-«j otj 53
XFS| 37 [51 65
a - ^";i!i. ..jiJ. , . -j
if F:9il 182 :lf:
1.9H- 53
..^J ?^39 ^
;"=M 26 f" j-' 54
is>i F:9«3 178:1,'
''^~l\ ,,/«7 39 5,3 '"
IM i!;9t|l 174:1,;
JC £-5- »' -J «™ _, fjp
.?. ^r? «r • -T ^]| ^_f ^jf
NBS 33
7
69
3-BUTADIENE, 2-HETH¥L-
-6?
€3
4-PENTAMENE
.68
69
3-PBITAIJIEME, <2>-
=-j
f
69
H/3 ' ' ' 50' ' ' ' ! ' ' ' ie» •••'••" j_^e •--.-•- 290 ....... ^^ .
(919) 544-5729
1 TistruPteivfc " H
NBS
141312
360 358
Hits : 33 Searched
134144
C5H8 255
C5II8
• I • • •••• i ' ' ' 	 !'" ' 	 ' " • 1
255
C5H8
see ase
-------
             1B:32
                          Triangle Laboratories of  RTF,  Inc.
gamble: UQST-3  SET 3 TUBEfl/B  f/TC  173-46-12f»/B   1111142284
j^mi  193 (1,930)
            43
                     (919) 544-^729
                     _!jistrunejitj H
                               NB3
r:i
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. , • .', '• V- ;.v'-:' P4ciiicBtiviisa«iientalSetvic«s _•; '• ,- •••.•• .. .;••" ': . -;, '/
Project Number 42284
Sample File: HS371
Client Project: S487-G03
TU ID: 173-46-13A>iB
Method 8240A VOST
Sample ID: VOST-3 SET 4 TUBEA/B T/TC
Dale Received: 96/30/97
: Dale Analyzed :07/<»/$7
. Response
HIerlCALHTQS



Anaiyfe* ' '•" *:; •' '•/•:. "••'•'• T*:
Bromochloromcthane
Chloromcthane
Vinyl Chloride
1,3-Butadiene
Bromomcthane
Chloroe thane
Vinyl bromide
Trichlorofluoromethane
1,1-Dichloroethene
lodomcthane
Carbon disulfide
Acetone
Allyl chloride
Methylenc chloride
trans-1 ,2-Dichloroethene
ten-Butyl methyl ether
Acrylonitrile
n-Hexane
1 , 1 -Dichloroethane
1 ,2-Epoxybutane
cis-1 ,2-Dichloroethene
Chloroform
1 ,2-Dichlorocthane
Isooctane
1 ,4-Difluorobenzene
Vinyl acetate
••• oa ' • "•":" !:".:r ./.•

IS1
0.287
U
0.714
0.020 J
0.137
U
0.031 J
U
U
1.107 E
0.136 B
U
1.275 BE
U
U
6.424 E
0.517
U
U
U
U
U
U
IS 2
U
: '— ! ^
4.48
0.92

1.08
1.41
1.53

1.82


2.48
2.55

2.95


3-25
3.54






5.63

:ff^ -•


0.001



0.001

0.001
0.001


0.001

0.001
0.001


0.001
0.003
0.001
0.001
0.001
0.001

0.001
'•::•'•'• . .-' ttg.

0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05

0.05
                            NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit Quantitation Limit
     IS: Internal Standard; U; Undetected; B; Present In Blank; J: Estimated- Below Qoantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
              Savar v3.5
Printed: 15:03 07/22/1997
             441
-------
Project Number 42284
Sample File: HS371
                       Method 8240A VOST
Sample ID: VOST-3 SET 4 TUBEA/B T/TC
Qtent Project S487-003
TO ID: 173-46-13 A,B
. ••.: -~\ - ' ,


Analytc . :. • T -: • ' • •
2-Butanone
1,1,1 -Trichloroethane
Carbon retrachloride
Benzene
Trichlorocthenc
1 ,2-Dichloropropane
Ethyl acrylate
Methyl methacrylate
Bromodichloromethanc
cis-1 ,3-Dichloropropene
trans-1 ,3-Dichloropropene
1 , 1 ,2-Trichloroethane
Dibromochloromethane
Ethylene dibromidc
Bromoform
Chlorobenzene-d
5
4-Methyl-2-pentanone
Toluene
Terrachlorocthene
2-Hcxanonc
Chlorohenzene
Ethylbenzenc
m-/p-Xy!ene
o-Xylene
Sty rent
1 ,1 ,2,2-Tctrachloroe thane
Date Received: 06/30/97 1

- Date Analyzed : 07/d$$77


.•"^] }***':,.. **v:
0.019 J 4.35
U
U
1.838 BE 5.10
U
U
U
0.103 6.45
U
U
U
U
U
U
U
IS 3 9.74

U
1.099 BE 7.56
U
U
0.012 J 9.79
0.175 10.08
0.252 10.31
0.092 11.03
1.987 F. 11. OR
U
I* ^Response File:
*..*.*:



!t^.V?:'.;';

0.001
0.001

0.001
0.001
0.001

0.001
0.001
0.001
0.001
0.001
0.001
0.001


0.001

0.001
0.001





0.00 1
KSALH7QS

'•"' "T "• ?~"


Qtiin. lomit
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05


0.05
0.05
0.05
0.05
0.05
0.05
0.10
0.05
0.05
0.05
                         NA- Not Applicable; Drt. Limit Detection Limit; Quan. Limit: Qiuntitation Limit
    IS: Internal Standard; U: Undetected; B: Present In Blank;): Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle I jboratorle« of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Photic (919) 544-5729 • Fax: (919) 544-5491
                                        Savarv3.5
                            Printed: 15:03 07/22/1997
                                                                                                       442
-------
                                      Pacific Environmental Services
Project Number. 42284                                                               Method 8240A VOST
Sample File: HS371                                          Sample ID: VOST-3 SET 4 TUBEA/B T/TC
Client Project: S4Q7-003
TO ID: 173-46-13A/B
.Date Received: 06/30/97
Date Analyzed: 07/09/97
Response File: ICALH708


Amlyte .: / - ." "..-. .' ''': ••••• •'•'•
Cumene
Snrrogate Summary J;-, : ... •.. ...'.:. .:;>,
1 ,2-Dichlorocthane-d
Benzene-d
6
Toluene-d
f^S^': '*••'
0.006 J 11.79
^^il,",!,.^:.
0.217 5.08
0.255 5.06
0.281 7.47
„, ,. , «tg „„ , . , a&: •
0.05
, js»e£ „! /•••\;,;-:%IOEC:":'..:
1 87
2 102
3 112
Reviewed by	J <-«-)	  Date	^
                         NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
    IS: Internal Standard; U; Undetected; B: Present In Blank; J; Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range

Triangle Laboratories of RTF/ Inc.                                                                               Savar v3.5
801 Capitola Drive • Durham, North Carolina 27713                                                      Printed: 15:03 07/22/1997
Phone: (919) 544-5729 • Fax: (919) 544-5491

                                                                                                      443
-------
Project Number: 42284                        Method 8240A
Sample File:     HS371                       Sample ID:         VOST-3 SET4TUBEA/BT/TC
Client Project:
TLIID:

S407-003
173-46-13A,B


Dilution Factor:
Date Received:
Date Analyzed:
1.00
06/30/97
07/09/97

                               Tentatively Identified Compounds

   Unknown                          0.711      46039136       9.741     12110536           0.950
   Hexamethylcyclotrisiloxane            8.651      28698900       9.741     12110536           0592
   C6H12Isome"r                       3.450      28282712       9.741     12110536           0584
   C4H8 Isomer                        1.011      24188248       9.741     12110536           0.499
   Sulfur Dioxide                       0.891      24188248       9.741     12110536           0.499
   C7H14Isomer                       5.421      21905056       9.741     12110536           0.452
   C8H16Isomer                       7.791      16296904       9.741     12110536           0336
   Methylbutane Isomer                 1.620      15291239       9.741     12110536           0316
   C5H8 Isomer                        2.180      13215533       9.741     12110536           0273
   C9H18 Isomer                      10.481      10799890       9.741     12110536           0223
Triangle Laboratories, Inc.
801 Capitola Drive* Durham, North Carolina 27713                            Printed:   2230  07/25/97
Phone: (919) 544-5729 * Fax: (919) 544-5491
                                                                                          444
-------
                                                                                       in
          15:56          Triangle Laboratories of RTF, Inc.
ianple: VOST-3 SEI 4  IUBEA/B  f/TC  173-4&-13A/B  TLIft42284
(919) 544-5729
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1,4- C i i" 1 1 j o r c b e ~ z a n a
C h i o r • o be n z e n e - c 5
1 , 2--D Lehiorcsthane-o4
Den-:sne-d6
Toluene— oS ^aiy» ~")
4-Bfomof 1 uorooen^ene
C ii 1 o r omet ha ne
Vinyl Chlorida
1,3-B Jtadiene
Sromomethane
Chlorcethane
Vinyl bromide
Tr Ichlorof 1 uoromethane
1 ,1-0 ichloroethene
lodome-hane
Carbor disulfide
Acetone - — ,^_ ~\
Allyl c h 1 o r i deCFj^T 1 {***'
Methylene chloride
trans-1, 2-0 Ichloroethene
tert-Butyl methyl ethe^J
Acryloni trile
n-Hexane
l,l-0ichloroethane*~x
1 ., 2-Eooxybutane f^^'-'
cis-1, 2-0 ichloroethene
Chloroform
1,2-Olchloroethane
T -^ ^x«-**^4~ »« t^j-* ^ """ 	 'S
i j^ooc ua n© ^ ^~ \
2-Butanone
1,1,1-Trichloroe thane
Carbon tetrachloride
Benzene
Trichloroethene "^\
Ethyl acrylate /!>*^
Methyl methacrylate
Bromodichloromethane
cis-1, 3-Olchloropropene
trans-1 » 3-D i c hi or op r open
1,1,2-Trichloroe thane
Dlbromochlorome thane
Ethylene dibromide
Bromoform ^^
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Mecny l— 2-pentanonefyw^u
Tol uene
Tetrachloroethene
Data Review: -r?i ^





Date: -j
* \*r\^/




                                                                           446
-------
No. MAT FOR REV Dslt:a
A:-aa P,.Flags
QM Name

— > -u
52
53
5
-------
9/-U9-9Y  15:56
(HS371  92 IB:920)
188-
                      Triangle Laboratories of KTP, Inc.
                   f IJBEA/B   T/TC  173-46~13ft/B  TL1»42284
9
                100
                               150
            200
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                                     (919) 544-5729
                                       Instrument H
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                                                                        16S1344
                                                                             358
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                            150
                                           100
                        256
                        368
                                                                         134144
                       358
        9  (e=938)
       59
      52
                                                                           FIND
    58
                  100
153
200
258
                                                                 380
350
-------
                    CT5
          15:56         Triangle Laboratories of RIP,  Inc.
Sample: UQST-3 SET 4 TUBWB  T/TC  173-4&-13A/B   fLItt42284
(919) 544-5729
  Instrument H
188
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58
1

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5i 188 150 288 25e 388 358
-------
                                                                             o
                                                                             in
07-09-yV  15:5b
                Triangle Laboratories of RTF,  hie.
UuSf-3 SET 4 1UBEA/B  f/K  173-46-13A/B  TLIS42284
(919)  544-5729

  Instrument H
141 (1.418)
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M^Z 56 160 150 186 256 366 358
-------
                     in
                        Triangle Laboratories of RTF,  Inc.
Sanple:  W8T-3  SET 4 TiJBEA/B  T/TC  173-46-13A/B   TLIIf42284
(919) 544-5729
  Instrument H
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(1.531) REFINE
6 5824
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108 150 208 250 388 350
(1.540) Chloroethane FIND
6
.3

\
4 1O8
66
lee 158 288 258 380 358
-------
                                                                                      in
87 &} 97
                        Triangle Laboratories of RIP,  hie.
Sanple: WST-3 SET 4           I/TO   173-46-13A/B   fL 1*42284
(919)  544-5729
  Instrunent H
HS371 182 (1,828)
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49152

250 3MM 358

16384

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258 388 350
-------
                                                                                      in
07-09-97  15;56         Triangle Laboratories of IIP, Inc.
Sample: WHT-3 SET 4 TUBEA/B  T/TC  173-4&-13A/B  TL1*42284
(919) 544-5729
             H
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2815232




1982464



258 388 350
FIND
188


250 388 350
-------
                                                                                      in
                                                                                      «•*«
117-89-97  15:56          Triangle Laboratories of ETP, Inc.
Sanple; v»ST-3 SET 4                 173-46-13ft/B  Tiltt42204
"H8371  255  (2.558)
 ,««»,         76
         58
      !!45 !
              VO
                                                                         544-5729
                                                                     Instrument H
                                                                           34816
                  188
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                               156
            289
            250
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           358
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                               150
                                                                           23296
                                               33O
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      44
        59
58
                  188
15B
288
258
368
                                                                             FIND
                                                                              180
                                                                             358
-------
                                                                                       in
07-89-9?  15:56          Triangle  Laboratories of  RIP,  Inc.
Sample: UGST-3 SET 4 TUBEA/B   f/TC   173-46-13A/B   ILIM2284
           rv QC:J
(919) 544-5729
  Instrument H

1
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49 1881344

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84
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58 108 150 208 258 388 358
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4

88
-.„- vp^M:-!!,-^ -^ -, 	 « ,—j .— » 	 ,.., 	 -; 	 . .., 	 f 	 , . , ,, j ...^ 	 , 	 , T_, , 	 , • T - ^— , -r— , , ,.-^....-I- ... j , . . . -j . . . . ,--.-. . [ . . , 	 , ,--- „ -.- . j
M/Z 58 150 288 258 388 358
NT2CAA 21 (2.970) Methylene chloride FIND
49 188
1901

XFS -


8



47
TE B
411,

84
51
/"
83
i '"':


88
.("'
M/Z 59 1G8 15i 208 258 388 358
-------
                                                                            <£>
15
                  Triangle Lahoratopics of  RTF.  Inc.
:  UOST-3 SET 4 TUPEA/B  T/TC   173-4&-13A/B
(913) S44-5729
  Ins'trunent H
.i-tviMvi 'f?n
= S-,3»J i 1- ^Jf£j»J
IBU-i 5
v;t:<.-j 51
I 58
< i
re ^-, 4
"'"~ 5i
3

5
l,L
3
j
HS371'325
1001 ""'
j- ~ i
S.ii,, . I
3
54
H/Z 58
HTZCfiA 24
i pa 5,3
51
-38 !

54
P ' -i -tr , A ! ' ,
%-T " j
H/Z 50
(3.258)
724992

«~i
«
"" 1 | • '' '• • | • • "•• ' -j - 	 • "•"! 	 •- 1' 	 	 	 | 	 	 • ' | '!• 1 '1 '• ' j • ... | ....,....,....,.-..,
ifM?= i^g H08 25@ 3SS 358
(3.251)
788608

160 ' ' 158 ' ' 288 ' 258 ' 389 ' 356
(3.270) Acrglonitrilc FIN!)
180

63
96
100 158 2130 250 380 350
-------
                                                                                      Is-
                                                                                      m
W'r-89-97  15;5fa         Triangle Laboratories of  BTP,  Inc.
SnnpJe: VOST-3 SET 4 fUBEA/B  T/IC   173-46-13A/B   TLI&42284
(919) 544-5729
  Instrument \\
354 (3.546)
1188
i
8-
w/s
f
IN
f '
i 	
S 	 j
7 475136

i -^ij o a.
r-» j C? CJ
5§ 188 15B 288 258 360 358
(3.541)
188-
XFS -
0-
5
£
13
56
7 438272
58 86
50 103 158 288 258 386 358
25 (3.578) n-Hexane FIND
im] 43 5
:
V'FK -

8-
M/S




56

55
\
. ,,J
7 160



71 |
59 188 150 288 258 388 358
-------
                   GO
                   in
G'J Ji
           LBihh          Triangle Laboratories of RIP.  inc.
Sariple: WRT-3 SET  4          T/TC  173-4&-13A/B  ILI»42284
(910) 544-S729
  Instrument H
435 14.358)
188! €


3
3,4
;
; cr tr
5e tee 150 200
HS371T435 (4,351)
4
»t-
3
57 ?|2
. i 1
58 100 158 209
33 (4.388) 2-Butanone
4
rt/Z
-j
72
57 |
58 108 150 200

5631


259 308 350

4672

259 30i 350
FIND
180

250 see 350
-------
                                                                                       05
                                                                                       in
07-m-97  15:56         Triangle Laboratories of  RIP,  Inc.
Sample: U08I-3  SET 4 TUBEA/B  T/TC  173~46-13A/B   TLIft4Z284
(919) 544-5729
  Instrument H
518 (5,181)
iee1 7
XFS-j 7?
51 74
3
7-9
M/Z 58 100 150
HS371'51B (5.101) REFINE
ie0i 7
XFS- 7?
• 5jf 71
8

79
i.
H/E SB 100 ' ' 150
36 (5.131) iensene
188] 7
XFS1 „ 77.
P ' ,,i .I:. **,••* .1,,
8
79
«/z 58 188 150

2783368

200 250 308 350

2572288


200 250 380 35O
FIND
168

280 250 388 350
-------
                                                                                        o
                                                                                        CO
ij?-@(j---.*37   |5:5(j         Triangle  Laboratories of R?F% Jwe,

Sample: WST-3  SET 4 TUBEA/B   T/TC  173-46-13A/B  TLIU42284
(919) 544-5729
  Instrument H
IHS371 645 (6.451)
„,-„ -41 35328
let?
= ,--•-- ,

8-




i
6
4255
li; .J'llI,! . ,.h
9
81 188
i, ..i.l i .... i
' I '' ' ' ' 1 ' ' ' ' i ' ' '• ' "I " ' ' - ) '•' ' 	 , .... | ...,,.., , 	 , ,-,.,,,,,.,,...,..., |
«/z 58 106 150 26R 256 38M 358
HS37ir645 (6,451) REFINE
188] 6
l
•
XFS-

rj 1
41


...

43 5y
„, 1
3 16896


lew

;:...! __ 	 .. . .......
• "5 ' 	 ' '"" ' 1 	 " ' 	 ' '• 1 ' ' ' ' 1 ' ' ' ' 1 ' ' ' ' 1 ' ' • "" | 1 • 1 • | • ' • - • | .... | "."• . • . • '-[ . . . . | 4 ... |
•^/z se iee 150 200 250 see 350
48 (6.491) Methyl wethacrylate FIHD
» -r 4
J
.*¥?«- J
/"ji- -J- j
||
1 100
63


/a 59


J88,5 ife
H./s 58 ' 18S ' 150 ' ' " 208 ' ' ' 258 ' ' 388 ' " 358
-------
07-tiy-y?  15:56          Triangle Laboratories of KfP, Inc.
Sample: UQST-3 SEI  4 TUBEA/B  T/IC  173-46-13fl/B  TLI»42Z84
(919) 544-5729
  Instrimewt H
!J€T"JT ! *7Cf
riu-J i i ( tie
100:

XFS^
•— JT
i 51
0 ..lr-,..-|l,.r_

H/z 59
HS371' 756
108:

"3D
• /? ^
p '..J, ...."x

H/'Z 58
49
ieei


XFS-
: 39
: f' si
8.ti..,i j
-T^-. I [ .
M/Z 59
(7.561)
9


65 8?

.if !„ 	 j
1
92

93

t ..^.
I 1 I I I I . . , . . , . , . . , , , .4 , » | , . . . | .........
iee ise 200
(7.561) REFINE
9


65 89
,4 .., 	 ^
1
92

93


188 158 288
(7.661) Toluene
91




65 89
J. ... ,.\
92
..*


93

10O 158 200

2146364






250 308 358

1949696




E'"""i"" ' " i ' ' " "1 - » . i •
250 388 350
FIND
180






250 3G8 350
-------
                                                                                      CD
H? 09 !37  15:S&         Triangle  Laboratories  of  RIP,  Inc.
Sanple: M08T~3 SET 4           T/IC   173-46-13A/B   ILIJM2284
C919)  544-5723
  Instrument H
IIS371 979 (9,791)
100T A47 119808
j 8,2
.8
54 77 112
4g ,itfi s? )ii:i
119
L . .
58 186 I5Q 288 256 388 358
(9,791)
i ass-i

xFS-
n/J
1:
77
5-3
105
.2 14406

114
1 . . . •_._.. .___ ..
58 158 208 256 3§0 359
MT2CAH S2 (9.841) Clilnrnbenzcne FIND
IS0-] --
'

Q-

31 74
,,... J56._ ^,.8^5
.2 168
114
'

5S 188 15i 288 258 388 358
-------
                                                                                     oo
                                                                                     CD
          15:56         Triangle Laboratories of BIP, Inc.
Sample:  MOST-3  SET 4 TUBEA/B  T/TC  173-46-13A/B  TLIM2284
(919) 544-5729
  Instrument H
1BB8 (IB. 881)

1801
XFS-


a-



5i 6,5 77
I • i i i I *-r


106
I
i 	 ,.!, 	
• • - i i •• "T| .1*1. i1"1 ,.'.'i ,|,j) "i *" l 	
M'XZ 50 iea i5B
HS37F1BBB (IB, 081) REFINE
180-
XFS-

P-
3


,, 51 W !? .. .
1

186
107
M/Z 58 ' 186 ' 15Q
53 (10.131) Ethyl benzene
91
" ~~" •
XFS-

ra


51 65 ??
..!„ . ,. ,.!.._. .J.I1, , .,

IBS
10?
1 wJ:

M/Z 58 160 150

393216





tliiii^i^i-ift*!*!^**"!**'1!-1.*! ." 	 • i' * ;
288 250

335S72



208 258 360 358
FIND
100




• 1 • ••• !••• •!• ...(.... ,»,,.|. .,.,....,
208 250 300 350
-------
                                                                                      CO
87-89-97  1.5:b&         Triangle Laboratories of BTP,  Inc.
Sample: MOST-3 SET 4 1UBEA/B   1/TC   173-46-13A/B   TLII42284
(919)  544-5729
  Instnment II
1831 (18.311)
180"
XFS-
|
«
9



1 446464
186
92 J187
i 	 lit. 	
h--'£ f.'e ' 1TO ' 158 "•'••• gee '••'••• 2£0 " ' ' 3J|a ' 35£
HS37I'1831 (18,311)
188-
>;FS-

9


qi,ii , 	 f., ,:r 	 i,, 	
1 • 385824
Iflfr
92 , 107
	 t{ ;'. .
n^'z 50 ' 100 ' 158 ' 266 ' 250 ' 3BB ' 358
N12CAA 54 (18.371) M-/p-Xyleiifl FIND
lee-j 9
t
i
V« j,' -31 I
b-y ??
ai jf.. 5.e .H..I ...1,1,
i iee

1Rfc



i*^z 50 ' 160 ' ' ' ' 150 ' " ' " 288 ' ' 258 ' ' " ' " ' 3gB " ' " 350
-------
09-Jul-97 15:56
Sample: UOST-3 SET
HScfi
M/'Z;
HSJ37
i&&-
X.FS;-
gj.
WiSl
1CI0-
XFS;
re
fl 1102 (11.02J
i
78
51
jXu-J-3
50
T11B2 (11.021
91
i
50
:EB 6i (12.198]
9J
39 51
50
ID
CD
Triangle Laboratories of RTF, Inc. (919) 544-5729
4 TUBEA/B T/TC 173-46-13A/B TLHH2284 Instrument H
.)
104 757760
®\
105
/
,... i L.,. . j , - ,-- i- - - , - i --i
100 150 280 250 300 350
L) REFINE
111616
106
100 150 200 250 300 350
) o-Xylene FIND
108
106
4 M'1 1
108 ' 150 ' 200 ' 250 ' 300 ' 3g£

-------


C0
CD
07-89-97 15:56 Triangle Laboratories of HIP, Inc. (919) 544-577,9
Sdnple: U OS 1-3
SET 4 TIJBEA/B T/1C 1V3-46-13A/B TLII42284 Instrument H
IHS371 1188 (11.881)
i
:
VF*J -
JT1M. i?



n
7
51
T ?fi ,
, | 63 \
..,! 	 i= 	 i 	 -.ill
H/S 58
184 2621440
163
a

182
•J q
. ...rr J^,. '



185
/

158 200 25Q 308 350
HS371'1iee Cll.eei) REFINE
I83n


*""F^ "
~ D ~*


8-


1B4 2293760
183
S
73 1
51


1 | j ,

H/Z 59
56 (11.

—*•"• \


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182

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105
X
1 	 . ... __ ..
1 "'* 	 ' — ' " ! • — ' — ' — ' — 1 — •— -1 — ' — ' — 1 — ' — ' — • — • — 1 — ' — • — • • — I • • • • — r— •—»— •- 	 • |--- •- •- i —• • • - i • -- - i - - -- • i
160 15B 200 256 360 35@
121) Stijrene FIND
1R4 100


103

8 JiW
. 85 . J




ieu


108 158 260 258 308 350




























-------
                                                                                     CD
R7-fl9-97                Triangle Laboratories of RIP, Inc.
Sarcple:  UQST-3 SET 4 fUBEA/B  I/TC  173-4&-13A/B  TLIH42284
(919) 544-5729
  Instrument H
1 !_!*-' ;V
189-

-F£v-
fl
M/S
HS3i
100
XFS
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M/S
MI2C

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XFS -

p.

'1 1179 (11.791)
11
4.1
| 5?
J! i jlii , ifjiiji jji]i!l| Ijjul .
SB IOC
'i'Ii?9 (11.791)
11

41 5? 77 J-83V
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53 1§£
:fttt GO (11.851) 1
11



103
. 5A §3 "i
53 iee

35 15808


120
i 150 200 250 300 350
REFINE
45 12352

1^0
i 150 200 250 380 350
Dunene FIND
15 100



120
i J
> 150 200 250 300 350
-------
                oo
                CD
09-Ju1-97 15:56          Triangle  Laboratories of RIP,  Inc.
Sample: UOST-3 SET 4 TUBEA/B   T/TC   173-46-13A/B   TLIH42284
(919) 544-5729
  Instrument H
HS371 71 (
1001 6
i 4144
y.FS: ,"/
M/Z 50
;8.718)
0 2834432
100 ' 150 ' 200 ' 250 ' 300 ' 350
HS3711?! (0.711) REFINE NBS 49 Hits : 49 Searched
100i 60 2818048
XF!j 38^43 62
#1 F:490
1001
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618:3-
3?
2,?/1,!
#2 F:466 12997:
1001 39 '
— ,«, i to. |l M| /. 6,9./ N|.
2-PR6PENE-l,l-DIOL, 21METHyL-J' DI ACETATE
32 7CI 255
45 fv
/ 6069x 71
BUTENOIC ACID, -
>4i 255
>I*i O£
/ 53 55§06,®71 83
'.•1. ..S /. X IL^, N r87
M/Z ' 28 ' 40 ' 60 80 100 120 ' 140 ' 160 ' 180
-------
                C0
09-Ju 1-97 15:56         Triangle Laboratories of RTF, Inc.
Sample:  MOST-3 SET 4 TUBEA/B  T/TC  173-46-13A/B  TLI842284
(919) 544-5729
  Instrument H
HS371 868 (8.681)
1001 2f
XFS- 2«W
0 -,.-,,-,...,-, 	 - 	 	 	 , 	 	 	 __ .... 	 	 L
M/Z 50
100 ISO 200
HS371J8&8 (8.681) REFINE
0 |il. ...ill. J 1 r?A 1 1,.IM3. IfJ-l^fi 16,6180 .212
#1 F:415
€ inn-m ^***J
1001 41 /
XFS 29 155X
0; II,, -
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58 72 93 105 __ .
/.•„>_ 	 k ./, . . 2?4
*2 F:392 38439 .'BENZENE, O-OCTVLUNDECVL)-
1001 'j2
XFS 39 |r4l|^57 69 8j5 93 104
#3 'F!392 39637 I BENZENE,' El COSVL- '
1801 41 911J2
XFS 39 If43 J 765 77 93 104
Q Ml 4 /.,, /... k ^ia6 133 .
M/Z ' 50
100 150 200
839680
250 30B 35O
NBS 329 Hits : 329 Searched
8000
255
255
,253
255
358
250 ' 300 ' 350
-------
V-.^n, in ' IIA"T
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tut]
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01 ,. ,.., T..^s*,,J,
IR:S& Triangle Laboratories of RIP, Inc. (919) 544-b729
-3 SET 4 TUBEA/B T/TC 173-46- 13A/B fL 11142284 Insti>uneiit: H
.458) ' MBS
1 rjfi 376832
! 69 84
50 166 158 208 258 388 3501
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t 5ft 237568
43 |
1 ...1 V ai4
^ 1^ - • J ' 1 ' "" *_ ' 1 ' ' "" ' 	 ' 	 '"' - ,...-,..-,-..-, . . , , . i i , , . . v J , i ........ t
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-------
09-Ju 1-97  15:56         Triangle Laboratories of RIP, Inc.
Sample:  UQST-3 SET 4 TUBEft/B  I/TC  173-46-13A/B  TLI842284
(919) 544-5729
  Instrument H
HS37
100
'1 181 (1.818)
T
. 56
JJL. 	 L,64
0.
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M/7 *%Q 1 £IQ
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150
HS371J181 (1.811) REFINE
1001 4|1
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„ j . N 1 . 1 , I . . . . 1
ttl
100
XFS
0.,
100-
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100
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1359872
200 250 300 350
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6
5.8
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& 255
57 70
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i g? 255
42 55
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1 5
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/ 7^
60 ' 70 ' 80' 90 ' 100 '
-------
89-Jul-97 15:56
Sample: MOST-3 SET 4
   Triangle Laboratories of RIPj  Inc.
1UBEA/B  T/TC  173-46-13A/B  TLIH42284
(919) 544-5729
  Instrument H
HS37
180
X.FS-
0.
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64
48
,..,...,,....,..,.,...
M/Z 50 183
HS37
100-
XFS
0.
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100
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100
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0-
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F 3, t- *
:
4
66
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2146304
150 ' 200 ' 250 ' 300 ' 350
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1933312
I OXIDE
4 255
66
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F!346 3314:NETHAN£SULFOH
7
.., 64
4S*|*t48 63 X 78
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VL AZIDE
9 255
SO
/. 121
DRAZINEDISULFONYL D I FLUORIDE
4 113 255
67
1,1 *P 196
n/x 20 ' 40 ' 60 ' 80 ' 100 ' 128 ' 140 ' 160 ' ISO ' 200
-------
07/19/97     15:56        Triangle Laboratories of  KfP,  hie.
Kawle:         SET 4          f/IC  173H6-13A/R  TLItt4Z284
(919) 544-5729
 Instruneut*  H
HS3/1 542 (5.42:
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L)
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M-'Z 50 106 150 200
Hi>J?i'5-12. (5.421
XFSj "X 54
ttl F:8§8 1187
1 * s rj i 5 fl
'^L-^K
i!x F!ff32 1195
" ~ ~ 1 •? 7 2 9 "
ql .11. J-C.J
f3 FJ83W 1225
I83i - 55
al -1,5 ij .1.1 ^ ,.„
I) REFINE
6
70
...J .§.3 9,8
: CVCLOPEtfT ANE, 1 , 2-1)1 MEIHYL-
'56
F7""?! f3QJt
:CYCI.OIIEPTANE
r56 70
: CYCLOPENTANE, 1 , 2-1)1 METHYL- f TRfiTO-
••of-
69
S?|j?1 83 9g
1 ..,.k" .,,1 _.! ... ...... ...
H^Z 58 188 158 290
NBS
191488
250 300 350
NBS 56 Hits : 56 Searched
C7H14 355
'"' 	 - •• i --..,•••• t ..--•• i •• - • t
255
C7H14
C7H14
250 see 350
-------
9V"     lo>56        Ti'ian!ile Laboratories of RIP.
:  WlST-3  SET 4           T/TC  173-46-13A/B  TLIH42284
(919) 544-5729
 I iistriineiit * H
f-fci37.l 779 (7.79.
i»3^ *1 5
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-------
                                                                                 in
H7/OT/97    15:56        Triangle Laboratories of RIP,  Inc.
K?wrle:  MOST 3 SET 4 TUBEA/B  T/TC  173-46-13fVB  TLItt42284
(919) S44-S729
 Instrument'  II
3371 IS'? (i
,*-vJ » -?_ JtL\~i rsj* ^s, JL a

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tSj *"\ll

/T;
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a \ 1!

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44 1
-•'' ,1 7.2
5«3 108 150 250
621) REFINE NBS 242
3
57
••". .,.,! ...7^

O9 : KYDROXYLAHINE, O - <2-WETIIYLPROPYL>-
3 ^__
ij^e-p 71
V"|J -J" .•••
,; 	 ik J-72 .
- !-,.,.,...|...,t..,-j....|.4..|l,.,ll|,.,tJ,l
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57
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€26: PROPANE, ?,-METHYL-l-NITRO-
L
57
_^? f> i


50 166 150 200 250
NBS
471040



gee 350
Hits : 242 Searched
434176




255





255
C7H16





255



30© 358
-------
                                                                                      CO
                                                                                      r-
i-s-~5 ss.ii i >E*V
f s •• .•• f_! ?.- 3? f
             15'56         Triangle Laboratories of  BIPj  Inc.

Hanplo: UOST-3 SET 4 TUBEA/B  T/TC  173-46-13A/B   TLI942284
(919) 544-5729

 Instranent* H
UO-J'J'i J>iSl f"? IPQ^
• *•_*-. » 1 -i. i iO -, i. , ±CW J
"FSJ 3? ,31 fib
ni :; It4L .::•,
7
O f
,. _"|L 18i ___. . _ _
H/Z ' 58 ' 168 ' 159
m-t/rZiB (2.101)
a -I , ^ '';iii. jii . .."i
fl-J F:fl@ 182:1,
IB81 „ 3, ,^
>iFS ; sfi f * -•" S4
..• ""-..'•• |i \?
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:PC}~] 67-
__ ? 27 39 53
X.2S-J Jjlt j j

413 rise! i?4:i,
f? 3 , '>JV . Jl*. .. :"', ...ji
REFINE
69
3-BUIflDiEME, a-METHYL-
67
69
4-VENTA&IENE
169
I/
3-FEHTADIEME, -
=1
69
H/S 5S* It4fl 1 Fid
_ - MBS
2QO 256 308 356
NBS 33 Hits : 33 Searched
•" • "" !"• ' " '"' i • - • • i • • • • i ' ' • • • , • • • • i • • • • |
C5H8 255
255
C5HO
- • I • • • • 1 • • • • 1 • • • • ! " • • • 1 • • • ' 1 ' • - !
255
C5H3
saa ?sa ^te^Q ^SQ
-------
89-Ju1-97 15:56         Triangle Laboratories of RTF, Inc.
Sanplel  MOST-3 SET 4 TUBEA/B  T/TC  173-46-13A/B  TLIU42284
(919) 544-5729
  Instrument H
HS3i
100-
XFS-
0
'I1 184
43 5
H/Z 50
HS37
100
xFS-
0.
ttl
100
XFS
0.
#2
100
XFS
0.
100
XFS
0
18 (10.481) REFINE
6 81920

I1 1848 (1
39
100 ' 150 ' 200 ' 250 ' 300 ' 350
8.481) RI
43 5
54
\
F:900 2405:l-HEP'
4143 55\5
39\ j 53
|M
F:888 4
41 '
B3i:l-OCTE
« 55x=
F:868 3977:CyCLOH
51
II B? f T^l
1 1 v JL <1^^*
M/Z 30
40
IFINE NBS 83 Hits : 83 Searched
6 81920
57 67 69 ?1
( \\\f , ,,,?3, , , ?i7., ,. . -126
ENE, 6-METHVL-
6 255
57 69
6\J[i \/ 9(7 1^.2
NE, 7-METHyL-
6 255
57 69
67 L70
EFT A NONE, 4-METHVL-, 
-------

Project Number: 42284
Sample File: HS349

|"?:S-- : :- X: ?S:3pl; fl\;Hif wlS;S§


-;";*"•: V; Vv!i"v •!':-.•:•. V vl';"'!^. .;!X-"-? -?••:;!•:-:-: ;::::--
Method 8240A VOST
Sample
!:S:lfP:§|illS
•Xi^:A::::i;:;-::v;:
^^ff^^-^Ji^^^^^^^^l^^^KSn
ID: VOST FB

iiSitlf Hill
2 TUBEA/B T/TC
iiBiiiiiS
?::S|S|l;||Spp|:;;isi- -;i Si|p:



||fl§;I§illl;ii^'ill5;i;i^ftf^iSI
Bromochloromethane
Chloromethane
Vinyi Chloride
1 ,3-Butadienc
Bromomethane
Chloroediane
Vinyl bromide
Trichlorofluoromethane
1 , 1 -Dichiorocthene
lodomcthane
Carbon disulfide
Acetone
Allyl chloride
Methylene chloride
trans- 1 ,2- Dichiorocthene
cert-Butyl methyl ether
Acrylonitrik
n-Hexane
1 ,1-Dichlorocthane
1 ,2-Epoxybutane
cis-1 ,2-Dichloroethene
Chloroform
,2-DichIoroe thane
Isooctane
1 ,4-Diftuoroben7£ne
Vinyl acetate
lili^i^^sililiKliiiiiiiiii

IS 1 4.51
0.005 J 0.94
U
U
0.004 J 1.42
U
U
0.014 J 1.84
U
U
U
0.045 BJ 2.57
U
1.547 BE 2.97
U
U
U
0.950 3.57
U
U
U
0.001 J 4.66
U
0.042 J 5.29
IS 2 5.66
U




0.001
0.001

0.001
0.001

0.001
0.001
0.001

0.001

0.001
0.001
0.003

0.001
0.003
0.001

0.001


0.001
ilifSlpfiliiil'
^illSSiii|liil
: £ fr- •- . ;.->:-•.;: .::.*•• '-< % --:v™«R •--•--.; - •---:•-- '••• '••-

0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05

0.05
NA- Not Applicable; Dct Limit: Detection Limit; Quan. Limit: QuantiUiion Limit
IS: Internal Standard; U; Undetected;
B: Present In Blank;]: Estimated- Below Quanlitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
SOI Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 * Fax: (919) 544-5491
             Savar v3.5
Printed: 15:01 07/22/1997
                                                                                                                   473
-------
Project Number 42284
Sample File: HS349
                   Method 8240A VOST
Sample ID: VOST FB 2 TUBEA/B T/TC
Tmmmmsm&m
•^-::^: ^;:S::^^''^:v'-':i::^S^:KSv:v; !v^:vi$:^SxlS::i&^;::^SsS
$&^^:W';:i;:::-S i<'::::£v.::vS^
2-Butanone
1,1,1 -Trichloroediane
Carbon retrachloride
Benzene
Trichloroethene
1 ,2-Dichloropnopane
Ethyl acrylate
Methyl methacrylatc
Bromodichloroinethane
cis-1 ,3-Dichloropropene
trans-1 ,3-Dichloropropene
1 ,1 ,2-Trichloroethane
Dibromochloromethane
Ethylcnc dibromidc
Bromoform
Chlorobenzcne-d
4-Mcthyl-2-pentanonc
Toluene
Tetrachloroethene
2-Hexanone
Chlorobenzene
Ethylbenzenc
nWp-Xylene
o-Xylene
Styrene
1 ,1 ,2,2-Tetrachlorocthane
•^•^M^yi^:i^^^f-M^:^i!;t^'^^^^^'^i^^:^:^^^-'-i-.
ia»^^Sffl^?»ilffi^?K*:*^™'S¥?^^:^iP^^^^S&
U
u
0.003 ] 4.91
0.042 BJ 5.14
U
U
u
u
u
u
u
u
u
u
u
IS 3 9.79
U
0.051 B 7.60
U
U
u
0.002 J 10.13
0.004 J 10.36
0.002 J 11.07
0.003 J 11.12
U
1
1
0.005
0.001


0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001

0.001

0.001
0.001
0.001




0.001
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05

0.05
0.05
0.05
0.05
0.05
0.05
0.10
0.05
0.05
0.05
                        NA- Not Applicable; Dct Limit: Detection Limit; Quan. Limit: Quantisation Limit
    IS: Internal Standard; U; Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                  Savar v3.5
                       Printed-15:01 07/22/1997
                                                                                                 479
-------
Project Number: 42284
Sample File; HS349
                                            Method 8240A VOST
                      Sample ID: VOST FB 2 TUBEA/B T/TC

                                                                                 m
                                                                •::;;:V.^V;-;--:-;feii:;:::::,'i'::^-^-:':r-:':.<:::-::: :>>•:<•:• "vX.-:-:-^v:;::-:x v:>>;:w;.vr:;v/..«.y.>-^vv::::.;;;:;v;;
Ciuncne
0.001   J
11.84
0.05

1 ,2-Dichloroethane-d
4
Bcnicnc-d
6
Toluene-d
..::::-:v:;^^^|i;:-KS!|gp*P^^f®::^:K«.&-:.;
0.289
0.286
0.288

5.11
5.09
7.51
-yv¥iS";*^iS£SS';';:S:S»s
•-KjiSiarsafirjSsjIjiJjtes;.*
1
2
3

116
114
115
Reviewed by,
                          NA- Not Applicable; Oct. Limit: Detection Limit; Quan, Limit: Quantiution Limit
    IS: Internal Slandand; U: Undetected; B: Present In Blank; JsEstimated- Below Quantiution Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                                             Swat v3.5
                                                 Printed: 15:01 07/22/1997
                                                               480
-------
Project Number: 42284
Sample File:     HS349
Method 8240A
Sample ID:
VOST FB 2 TUBEA/B T/TC
Client Project:
TLIID:

5407-003
173-46-14A3


Dilution Factor:
Date Received:
Date Analyzed:
1.00
06/30/97
07/08/97

                               Tentatively Identified Compounds
   Methylbutane Isomer                 1.630      27735310      4.511     3221199
   Halogenated Hydrocarbon            2.160      5619273       4.511     3221199
   Methyl Propane Isomer                036      4951311       4.511     3221199
   Tetrahydrodimethyl Pyranone Isomer   4.120      2873874       4.511     3221199
   Pentane                            1.940      1721163       4511     3221199
   Alkane                            3.250      1466024       4.511     3221199
   Alkane                            2.420      1084714       4.511     3221199
   C4H8 Isomer                       1.011       921672       4.511     3221199
                                          2.153
                                          0.436
                                          0384
                                          0.223
                                          0.134
                                          0.114
                                          0.084
                                          0.072
Triangle Laboratories, Inc.
801 Capitoia Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 ' Fax: (919) 544-5491
                        Printed:   22:41   07/25/97
                                                                                           481
-------
                                                                                     
-------
UAM -DB .: H3349




No. MAT FOR REV Delta
   LAB-BASE   QUAN
Area P.Flags
                                                            07-08-97
                           21:3.5
RT
QM Name
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15

16
17

JLU
19
20
21
22
/"NT

25
26
~ *" /-s -i
*~ i
28
29
fs\
31
•y XA
o-e:
33
~~* -^
35
36
-r -i
38
39
40
41
42
43
44
45
46
47

49
r n
100
100
100
75
1OO
100
o
100
22
0
0
58
0
0
84

27
0
-r r-

81
0
100
0
*7O>
°n
100
0
r* T
•^ Srf*
0
51
oo
100
T C
0

~
96
9O
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0
0
0
o
o
0
o
o
o
0
r- x->
100

97
95
98
37
82
93
0
88
17
0
0
11
0
0
42

J. '-T
0
1 7

64
0
85
0
c c
X
99
0


0
19

88
^ A
0

JLU
64
55
/-5/->
0
o
0
0
0
0
0
0
o
0

91

99
97
98
85
83
99
0
93
18
0
0
81
0
0
94
!_ 	
^JO
0
-rr-!

66
0
95
O
tr —f
">->
100
0
r- -r
Ww>
0
64
T X
96
T7
O
-*• y-
89
93
r 1
0
0
0
0
0
0
0
0
0
0
SA
98
^^
0
0
-1
1
0
1
0
1
1
0
0
0
0
0
0
.— . —
•Z.w
0
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0
0
0
0
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0
o
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^
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-- 1
0
1
0
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0
1
1
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o
0
0
0
0
0
0
0
0
/•)
1
Q
358608
2283036
2790100
1116032
301S588
3652564
O
1797144
13724
0
0
11452
0
0
59392


0
i ^>-y-7o

84168
0
4370152
0


6374104
0
± •£•«£{") 4
C,^T V*'^
0
3556
f~> /• y* C O
973516
c rs^l
0

13832
482677
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0
0
0
0
0
0
o
0
0
0
OO
UJ





trans-l,2-Dichloroethene
tert— Butyl inethyrv^jsfcijsi
Aery loni t ri le AQi< v^
n-Hexane
1 , 1-Dichloroethane N.
-1 ,2-Epoxybutane(^J^^
cis-l,2-Dichlopoethene
Chloroform ^-sv
1 2~0ichlopoethane (R^'J'
Isooctane -^
Vinyl acetate ^^ )
2-Butanone
i i 1 	 Tr*iohl or*Of>'t"h.'inf^' \
Carbon tetrachloride
Benzene
T r ichloroethenrf^rY9Tl>-'
1,2-Dichloropropane
Ethyl acpylate
Methyl methacrylate
Bromodichloromethane
p
1




X
u)


, 	 Tl
£?>
kCx






cis-l,3-0ichlopopropene
trans-l,3-0ichlopopropen
1,1,2-Trichlopoethane
Oibromochloromethane
Ethylene dibromide
Bromof orm
.^~^
4 — Methyl — 2 — pentano rvSpj
Tol uene
Tetrachloroethene /^?Vn



— .

\
J
                              Data Review:
                                                                        483
-------
No.


	 r
->J -i-
53
54
55
56
57
58
MAT
„_
£. \_/
~, ,-.
O 7
88
100
88
93
0
81
FOR
•— /-x
O 4^.

t?
69
34
72
75
0
65
REV
— —
*-> i£.
r- .-
»J*"T
76
84
72
7S
0
75
Del ta



±
1
0
1
1
0
2
Area
^-7 ^0

1 1 " ' "* 1
J_ J. . Ci1 t
10&96
28044
11656
28176
0
20076
P. Flags
U l~
^v.'
t~l-

bb
bb
A
bb

A

<_}
•-•
r~>

10
10
11
11
0
11
RT
o <;>
• '
Qyj

.13
.36
.07
.12
.00
.84
QM
43
112
1O6
1O6
IO6
1O4
83
105
Name
2-Hexanone ~\^L
Chlorobenzene ' vJ
Ethylbenzene
m-/p-Xylene
o-Xylsne
Styrene

5VTLO
ryj \s\-^




1,1 ,2,2- Tetrachloroethan
Cumene

434
-------
                                                                                      tn
                                                                                      en
B7-08-97  21:82         Triangle Laboratories of RTP, Inc
Sample: MOST FB 2 fUBEA/B  T/TC  173-46-14A/B  TLIM2284
(919) 544-5729
  Instrument H
94 (0,948)
100
XFS-
8-
M/Z
44

,.,50
58 lee 158 280 250 380
HS349'94 (0.941) REFINE
180-
M/Z
5

e
52
50 iee ise 200 250 30e
9 (0,930) Chlorowethane
163
XFS-
0-
H/S
5

44
e
52

50 ieS 150 2O0 250 300

96256


350

1696

358
FIND
100


i • * - ' i
-------
                    CO
                    CO
87-88-97  21:02         Triangle Laboratories of KTP,  Inc
Sanple: MOST FB 2 TUBEA/B   T/TC  173-46-14A/B  TLIf42284
(919) 544-5729
  Instrument H
HS349 142 (1.428)
100-
0
4
4 39936
51 188 159 2O8 258 308 350
H8349*142 (1.421) REFINE
IBB:
0-
9
4
4 93
6,5 T i
4 2168

50 ICQ 150 200 250 388 350
12 (1.428) Browomethane FIND
IBB
XFS-
0
M/Z
9
93
46 R 1 "'i
40 / **I* 1
4 100

.
50 100 150 208 250 300 358
-------
                                                                                      r-
                                                                                      oo
87-88-97  21:02         Triangle Laboratories of RTF, Inc.
Sample: WST FB 2 fUBEA/B  T/TC  173-46-14A/B  TLIft42284
(919) 544-5729
  Instrument H
184 C1.84B)
iee
XFS -
0-
M/Z
44 19288
181
47
J105
i
58 188 150 288 258 388 358
HS349'184 (1.841) REFINE
100-

XFS
8-
H/Z
li


€,7 ¥ n?
, . 1 1. a<2
il 7184
183
_.-•*

105
\
58 1©8 158 288 258 300 358
MT2CAA 15 (1.84B) Trichlorof luoronethane FIND
108-
XFS:
0-
ft/Z
1(

35
47 €"(6 8^
11 188
183

105
I 117
50 188 150 288 258 388 358
-------
                                                                                      oo
                                                                                      oo
07^fl«-97  21:02         Triangle Laboratories of R?P, Inc.

Sample: MOST FB 2 fUBEA/B  T/TC  173-46-14A/B  TLItt422«4
                                                                  (919)  544-5729

                                                                    Instrument H
HS349 257 C2.57B)
     AA
100
XFS-
        58
  e-U4
H/35
                                                                           11072
                  iee
                              153
                        230
                        250
                        3BB
                       356
H8349J257  (2.571)  MEFIME
                                                                            7360
       50
                  100
            15B
            208
            250
            300
                                                                            350
HT2CAA 19 (2.570)  Acetone
    jt**
IBBi
XFS
  0
M/Z
      44
      58
100
158
2O0
250
                                                                            FIND
                                                                             100
                                                                 300
350
-------
                                                                                       en
                                                                                       oo
87-88-97  21:02         Triangle Laboratories of RTF,  Inc
Sample: MOST FB 2 TUBEA/B  T/TC  173-4&-14A/B   TLIft42284
                                                                   (919) 544-5729
                                                                     Instrument H
      297 (2.970)
      
-------
                                                                                     o
                                                                                     en
07-88-97  2i:92         Triangle Laboratories of RIP, Inc
Sample: MOST FB 2 fUBEA/B   f/TC  173-4&-14A/B  TL1M2284
(919) 544-5729
  Instrument H
HS349 357 (3.578)
108i 5
141

XFS-
0-
w/z.


r-f
56

55
u-^J
? 851968


58 nf
«J i M t>
1
50 1C6 158 280 250 388 350
HS349'357 (3.571) REFINE
100 57 794624


0-
41

J
56
55
\


58 86
50 100 150 280 250 300 350
Nf2CAA 25 (3.570) n-Hexane FIND
IBB


XFS-
0
5
43

.
56
	 .1
V 108


VA "l6
50 ' 100 ' 150 ' 200 ' 250 ' 388 ' 358
-------
                                                                                    en
§7-88-9?  21:02         Triangle Laboratories of RTF, Inc
Sample:  UOST FB 2 TUBEA/B  T/TC  173-4&-14A/B  ILIM2284
(919) 544-5729
  Instrument H
466 (4.661)
100-
XFS-
e-
H/Z
7
44

49
I
50
5 3872

8
3
168 158 2OO 258 388 356
HS349J466 (4.661) REFINE
1801

yjs
0
M/Z
4

J.
5 892
B,
7
5O
5
3

10e 150 200 250 300 350
HT2CAA 29 (4.661) Cliloroforn FIND
1001

XFS
0
M/Z
e


Yse
,< • Ibj" i
3 lee
85

87
\
58 iee 150 2ee 250 300 350
-------
                                                                                      cn
-00-97
          7.1 :R2         Triangle Laboratories of  RTF,  Inc,
Sample: MOST FD 2 IUBEA/B   f/TC  173-4&-14A/B  TLI842284
(919) 544-5729
  Instrument H
HS349 529 (5.291)
lee-
vps-
M/Z
5
56
41 x
7 94288

58
78 99
50 180 158 288 250 388 353
HS349'529 (5.291) REFINE
1801
XFS-
0-
5
5S
,|l^,
7 71688

99
50 180 158 280 250 388 358
MT2CAA 31 (5.291) Isooctane FIND
1001

XFS-
a/r
5
56

41 55
7 100


5«
58 100 158 280 250 380 358
-------
                                                                                      en
87-88-97  21:82          Triangle Laboratories of IIP, Inc
      :  MOST FB  2 TUBEA/B  T/TC  173-46-14A/B  TLIB42284
(919) 544-5729
  Instrument H
491 (4.911)
100

XFS
0-
M/Z
1J
4
J
4
47
49 82
ff ll
7 1968

121
50 100 150 200 250 380 350
HS349M91 (4.911) REFINE
I00i

XFS
0-
M/Z
i



17 82 A
49

, . . • i i i • • i | • • i
5fl 100
21 692


150 200 250 300 350
NT2CAA 35 (4.911) Carbon tetrachloride FIND
leei
%FS:
8-
H/Z
1

*
i, ./i, ,
17 «2
7 100
121
123
5B 100 150 200 250 300 35O
-------
                                                                                     CD
87-08-9?  21:82          Triangle Laboratories of  BTP,  Inc
     e: WST FB 2  IUBEA/B  T/IC  173-46-14A/B  TLIf42284
(919) 544-5729
  Instrument H
HS349 514 (5.141)
180-

XFS-
,0-
84 117760
6578
\
51
42 ,i
,,I,.L ..,( rfj. r.!(J .,,,!

,.ir5l(P
50 100 150 200 250 300 350
118349*514 (5.141) REFINE
100
XFS-
0-
7
39 7"?
73 "
8 537i0

79
50 180 150 200 250 300 350
NT2CAA 36 (5.131) Benzene FIND
tee
XFS-
0
H/Z
7
77
¥
„ f 6.3 ,,.
8 100

79
i
58 100 150 200 250 300 350
-------
                   in
                   CD
07-§8-97  21:82         Triangle Laboratories of RIP,  Inc
      :  VOST FB 2 TUBEA/B  T/TC  173-46-14A/B  TLIM2284
(919) 544-5729
  Instrument H
HS349 760
1801

X.FS
39
M/Z 58
HS349'760
IBil

{ 39
: I 5,1
q J. ,. J. .
M/Z 50
HI2CAA 49
1B01

" : 39
o: f 5A
M/Z 50
(7.681)
91
92
65 89 98
100 150 200
(7.681) REFINE
91
92
65 89 93
Jj ..,. ,Ji /
1O0 150 200
(7.681) Toluene
91
92
65 89 93
1 1 **"
100 150 200

93184


25O 300 350

83968


250 300 350
FIND
100


250 300 350
-------
                                                                                       CD
                                                                                       CD
87-08-97  21:02          Triangle Laboratories of RTF,  Inc,
Sample: WST FB 2 IUBEA/B   1/TC  173-4&-14A/B   TL 1*42284
(919) 544-5729
  Instrument H
HS349 1B13 (18.131)
1001 9
XFS-
49 ^ 65 77
0 • Tj I |!i | H I
1
106
IM7
M/Z 58 ' 160 ' 158 ' 208 ' 258
HS349Jiei3 (ie.isi) REFINE
9
>:FS '
5,i 65 77
g I . |l ! II
1

166
i*/z 58 180 150 280 250
HfZCAH 53 (18.131
1001 9
XFS-
51 65 ??
Q ..!r , .j.. .tj. . Tlt, „
) Ethyl benzene
1
106
10?
I .^j:'
M/Z 50 180 150 200 250

4224


380 350

3680


300 350
FIND
100

308 350
-------
                                                                                     CT>
07-88-97  21:02         Triangle Laboratories of BfP,  Inc.
Sanpie: UOS1 FB 2 TUBEA/B  T/TC  173-46-14A/B  TLIM2284
(919) 544-5729
  Instrument H
1836 (18.361)
100-
XFS-
0-
M/Z
9
39
(, sf «3 7f
i 6784
106
92 Jl07
" ,1
» "4 *• • ' " > i ' ••'(•'ii|'
-------
                                                                                      00
                                                                                      en
87-88-97  21:82         Triangle Laboratories of RTF,  Inc
Sawle: MOST FB 2 IUBEA/B  T/IC  173-4&-14A/B  TLIB42284
(919) 544-5729
  Instrument H
H8349 11B7 (11.071)
190-
XFS-
9-
M/Z
9
51 77
l| 1 f|5 1
1 2784
i«
II
50 180 150 108 258 380 358
H8349'liB? (11.B71) HEFINE
iee-
-
0-
M/Z
HT2(
100
XFS -
8
M/Z
9

65
44 7?
1 776
185

58 180 ' 150 - • • • 2^0 • 2g0 • 3^0 • 350
:AA BF (11.071
9
39 51
.'».. !, , J.|. .j.lll ,
) o-Xylene FIND
i 100
186
r2!187
58 188 158 288 258 300 358
-------
                                                                                      O5
                                                                                      cn
87-08-97  2i:02         Triangle Laboratories of RTF, Inc.
Sample: MOST FB 2 TUBEA/B  T/TC  173-46-14A/B  TLItt42284
(919) 544-5729
  Instrument H
1112 (11.121)
100-
XFS-
8-
M/Z
11
51 7
40 52
i/ ;' 63
I|i i 1 1
8 103
T'
m 3392
105
50 188 150 288 258 308 358
HS349J1112 (11.121) KEFINE
180-

•/.FS
0
If
183
7
1 1 ? l%
8

14 2912


105
58 ' 188 ' 158 ' 208 ' 258 ' 300 ' 358
HT2CAA 56 (11.121) Styrene FIND
180

0
M/Z
1(
103
¥ , 76?,
..ir f ^ >rl
8 182
, 85 ."'i
4 100

185

-------
                                                                                     o
                                                                                     o
07-00-97  Z1:R2         Triable Laboratories of RTF, Inc.
Sample: MOST FB 2 TUBEA/B  T/fC  173-46- 1WB  TLlt42284
(919)  544-5729
  Instrument H
! 18349 1184 (11.841)
100-
XFS-
0
M/Z






11

44 77
|l li
58
15 2224

120
138 150 280 250 300 350
HS349J1184 (11.841) BEFINE
100
XFS •
0
K/Z



7-
3§


NTZCftfi 58 (11.
1B0-
0
M/'Z





50
7
li

120 624
15

1@0 150 200 250 300 350
851) CuMene FIND
li
7 103_
15 100
120
100 150 200 250 300 353
-------
                                                                                 o
                                                                                 in
07/08/97   21:82        Triangle Laboratories of RIP, Inc.

      :  MOSI FB  2 TUBEA/B  f/IC  173-4&-14A/B  ILItt422B4
(919) 544-5729
           r  H
163 (1
i«»i «
j "SO
XFS1 "'
nl Jt
=638)
l«5r
j 7-?
i;. 	 ,1. 	 f.t*
«-• • • ' i • • : • t ' ' ' • 1 ' • ' • i '• ' ' • ' 1 ' ' ' ' ! ' ' ' ' 1 ' ' ' ' 1 ' ' '
H/Z 58 lee 159 268
HS349'163 (1
1801 4
XFS: *\\
Q* , ,. ,-J,!
SI F:S4i 8
180T 41^
: qo
XFSJ \
0 i 1,
#2 F;745 1
A
180T
XFS: 2729(
i^ : j.if, . j.S
13 F:735 6
188i 4
xFS-i 39
fj i
631)
-*Ti
57
72
09 IHVDROXVLAMINE, O-t2-HEIHyLPlOPVL>-
3
55 71
44||58 /-1
;:;ry< _^72 .
429:PENTftNE, 2, 4-l>INETIIVL-
3
57
55 58 ns
8^
S3l:HEFfANE, 4-AZIDO-
3
57
44 / 70
{ , i 84 98 .
w/z SO 180 158 200
NBS
835584
25S 3S8
NBS 242 Hits : 242 Searched
765952
•I-'--I--ITI----I---'|''''I
C4H110N 255
li''""i'"'1il""4)"l""l' '"i
255
C7H16
255
C7H15N3
256 300 350
-------



07/88/97 2i:82
CJ
CD
in
Triangle Laboratories of RTPj Inc. (919) 544-5729
Sanple: FB 2 T/TC 173-46- 14A/B TL!i42284 Instruneirt: H
216 (2.168)
MBS
, 03,, 81 242S88
j
V.Fi^ 45 si gg
fa i 3.3,4...,. . ,!.( . t
l^z - _ 5fl
8-3



:/ 1*1
108 150 268 258 386 350 «
(2.161) NBS 63 Hits : 63 Searcted
jag S.1 229166
1
>;F!l 35 £ 6/

83
/
i . . r , i . . k -.,.... , .,..,.... ( i . i , ,.-,.,,..., .,.,,...,,
#1 F;578 2788: ETHANE, 1, 2-MCHLQR0-1-FLU0BO-
] 0*3-1 ftf "
XFSJ ^ 43 ?560 69
jl .) Gtp 5 [. ^,i j

31 C2H3C12F 255
83
1 ^v y
'' * • • r • • "v" i • • • i • ' * • i • • • • i • • • • • i • • • i - - • ' i - f • • i • • • -i • • - - i
«2 F:4I0 125S7:PHOSPHOR01>IAMII>OUS FLUOEIDE, N,N' -»IMETHOXV-N,N* -WMETHVL-
. „_. pi 255
ie0i r ^
** -^ ^Aty j~ f^
xF'S"! 28 ">£..- few
3 j U?8I I , 1,69
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vfc»J -47 63
nl |i 
-------
                                                                                      en
                                                                                      o
                                                                                      in
08-Ju 1-97  2i:B2         Triangle Laboratories of RTF,  Inc.

Sample:  UOST  FB 2 TUBEA/B  T/IC  173-46-14A/B  !LItt42284
(919) 544-5729
  Instrument H
HS34
100-
XFS:
0;.
M/Z
9 86 (0.860)
f
45
1, 88
.l,l|....r,...( 	 t
50 180
HS349J86 (0.86
1001 41 l
XFSJ 38 X
01 . . .Yi.
ttl
100
XFS
0:.
#2
1001
xFSJ
0JL
#3
100:
XFS
0
FI691 45
4
39
\
i,
F:666 45
4
39
FI642 45
4,
39
\
,1) REFINE
13
i|...., .. ,5,?,
198464
*
158 288 258 388 358
NBS 74 Hits : 74 Searched
188416
8e»2
21: ISOXA20LIDINE, 4-Ef HVL-2,5-DIMETHVL-, CIS-
2 255
4A C7H150H
:455\5,5,60
19: ISOXAZOLI]
2
,43
,44 5B,52 f
1 1 I'M1''
»INE, 4-ETH¥L-2,5-DIMETH¥L-, TRANS- ~,,14r-/vki
C7H150H 255
68
/
69 88 i?9
aSlISOXflZOLIDINE, 5-ETHyL-2,4-DIHETH«L-» CIS-
2 C7H150H 255
^43 55 56 68
r44 58 1L ' 6.9 88 i?9
M/z 30 ' 48 ' 58 ' 68 ' 78 ' 88 ' 98 ' 108 'lie ' 128 ' 138
-------
                                                                                 LO
M7/§8/y7    21:02         Triangle Laboratories of RIP.. Inc.
Sanple: MOST FB 2 TUBEA/B  f/TC  173-46-14A/B  TL«42284
(919) 544-5729
 Instrument:  H
IIS349
-si^-j
XFS j
01^,
w/z
H3349'
1001
XFS 1
9 •
£=, * 1^
!RS»1
« J
H i. - , .
»2 F
-f
fli-^.
83 F
1 3£*n
"""I
>:FS1
U?^.? ....
412 (4.12«
"Jig g
J) HBS
6 101376
56 100 150 280 250 30O 35O
412 (4.12J
4155
J p'
:340 4261
42 5
(3^i ^,4!
;83l 55U:
5
41
39 f'51^
2.7 x-| " !
:823 4288
. ^.t Jl , r.
I) 1EFIME NBS 61 Hits : 61 Searched
6 90112
69
.J .84
1 2H-PyRflH-2-OHE, lETRftHy»RO-3,6-DIMETHVL-
5 C7H1202 255 !
;' ..i. ^
CVCLOHEXANE
6 255
,«.«4 C6H12
577" IBS
:2H-PVRAN~2-OME. TETBflH¥DRO-5, 6-DIHETIIVL-. TRANS-
6 255
s? C7H1202
59 158 260 250 360 358
-------
07/08/97                 Triangle Laboratories of IIP,  Inc.
Sanple:       FB 2 TUBEA/B  T/TC  173-4&-14A/B  TLIt42284
(919) 544-5729
 Instrument: H
«l
q i ,
H/Z
HS349'
180-j
KFS^
P^
Hi F
liSi
if "3 |T
13ft-
V«j
. „*. V. 2
=1 i
II*1* W5
.1.801
KFS:
g -.. 	 	
14/2-
194 (i.
4
39 ,
I,
948)
3
44
57
, .u.
• ' i • ' • • i • • •
50
191 (1.
4
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• . i • • i
; 726 8
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4
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3
89 : H'f
55
44|j5fi
£r ,.ik"
298: A
44 57
/ ,1-6
824= f
1 	 L.
se
72
100 158 200 250
1EFINE NBS 83
BROXtfLAHINE, O-C2-HETHVLP«OP¥L>-
1 J^
CETIC ACID, 2-PJ»PEH¥L ESTER
1
-PROPftNAHIHE, N, 2-BIMETHVL-M-NITROSO-
68
1S0 150 200 250
NBS
52224
3OO 350
Hits : 83 Searched
49152
C4H110N 255
255
C5H802
255
C5H120N2
300 350
-------
                                                                                  CD
                                                                                  O
                                                                                  10
07/68/W    2i:«2         Triangle Laboratories of KIP,  Inc.
Sanple:      FB 2           T/fC  173-4&-14A/B  ILif42284
(OO) 544-5729
 Instrument *  H
HS31
108
P-

HS3-4
168 |
XFS-
Q-
ftl
XFS-
p •
if 2
•.-ire- :
•** *3?
I.OS"
=""•"' -' "
ft
H/S
;4 325 (3.258)
57
41
OQ i «-.-
-. 33
59 166 156 209
L9'325 (3,251) DEFINE
v T
55
til. r:t 7,1 86
F:873 6373 : HEXAHE, 2, 2, 5, 5-TETRAHETHk'L-
57
41 71
33 .- 5g f1
iti ^i/..',.-.i -»-5 	 AS"?,
F:«i? 4464:HEXAHEJ, 2, 2, 3-TRIMETHVL-
2? ?9 ~ sft 71
¥ Jt ./^j7
F; 885 4435 : PEHTANE, 3-ETHYL-2 , 2-DIHETH'tL-
5?
- ^ 2^ 41
"t / / 58 ?S
'IL Jl. ,.,, /..,4 ..,.., 	
58 108 158 260

250 300
HBS 25 Hits : 25
1 | 1 4 1 4 | ........ 4 , 1 .
C18H22
• ]••-'!*-- , t , * » | . .
C9H/.0
C9H28
250 360
NBS
40960
358
Searclied
35872
255
255
255
350
-------
                                                                                 in
            21:02        Triangle Laboratories of RIP, Inc.
Sample:  MOST FB 2 IUBEA/B  T/TC  173-46-14A/B  TLJi42284
(919) 544-5729
 Instrument:  H
HS34
109-
XFS '
Q '
t9 242 (2.
4
41
u
428)
14
i T •
NBS
12224
1
M/Z ' 50 100 ••••••- A^0 ---,.- ^^ , ^^^ , 3^0 , 3g^
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118-
XFS-
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XFS :
a.
113
180;
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9' 242 (2,
4
39
421
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41
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4
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4
27 29
438
3 5
55
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433
5
44
.)
7
7
58
i
REFINE NBS 84 Hits : 84 Searched
5568
1
72
: HEXANE. 2 , 2, 5, 5-TETRAMETHVL~
7 255
71
58 /
/_,..). ...8.5 	 127.
:HE
7
Y
58
• '• T
:HE
7
58
! ' ' 	 ,.,.,,...,,..., | .,..,,..,,....,.... | ...,,....,
PIANE, 3,3-DIHEfKVL-
255
i
72 98 99
f
'• •-. '3,
XflNE, 2,4,4-TRIMETHVL-
255
1
1* v . 	 __ .._
w/s 58 108 150 288 250 368
-------
                                                                                       oo
                                                                                       o
08-Ju1-97 21:02          Triangle  Laboratories of RIP,  Inc.
Sample: MOST FB 2 TUBEA/B   I/TC   173-46-14A/B   TLIH42284
(919)  544-5729

  Instrument  H
HS34
100
XFS
0
19 101 (1.010)
44
M/Z 50 ' 100 ' 150 ' 200 '
HS34
100-
'/,FS :
0:
#1
180
XFS
180-
XFS-
0,
100-
XFS
0
9' 101 (1.011) REFINE
3

250 300
4
9
FI733 78I2-BUTENE, CZ>-
4
26s 27/ f29 38 3i9
F:730 76I2-BUTENE, (E)-
4
26 a?/ f2g 38 39
, , , i i i I r , ^, A
F:699 79H-PROPENE, 2-NETHVL-
»!«; S.27/OQ
. . ^P . .Nil r2.9
»/z 5 10 15 20 25 30 35
4
9
NBS 64 Hits : 64
i
50 |5x5
1
55
51531
42, , Sp/, /t 1
i C4H8
55
5153|
4,2, , SBf, { , 1
C4H8
l
31531
42 5,B/. /, !
40 45 50 55
79872
350
Searched
17152
&
56 255
5,7,
/
5,7,
255
56
60
-------
                                    Pacific Environmental Services"
Project Number 42284
Sample File: HS350
                                                                                  Method 8240A VOST
                                                                Sample ID: VOST FB 3 TUBEA/B T/TC
Client Project 54077003
TLI ID: 173-46-15A,B

Date Received: 06/30/97 -

Date Alnalyzed:: 07/0&97rf™ l[
Response


File ICALH7Q&

' T


Ahalyie • . . . :. ••'. ' • • ": ' : ' .;" ; .;';.'• A
':: •'•.-•• . \ • '•••:. .:
Bromochloromethane
Chloromethane
Vinyl Chloride
1 ,3-Butadiene
Bromomethane
Chloroethane
Vinyl bromide
TrichJorofluoromethane
1 , 1 -Dichloroethene
lodomethane
Carbon disulfide
Acetone
AUyl chloride
Methylene chloride
trans-1 ,2- Dichloroethene
tcrt-Butyl methyl ether
Acrylonitrile
n-Hexane
1 , 1 -Dichloroethane
1 ,2-Epoxybutane
cis-1 ,2-Dichloroethene
Chloroform
1 ,2-Dichloroethane
Isooctane
1 ,4-Difluorobenzene
Vinyl acetate
4»ottttf:;v- .: H.A
-------
Project Number. 42284
Sample File: HS350
                   Method 8240A VOST
Sample ID: VOST FB 3 TUBEA/B T/TC
^ientii^i^iiiiiiolsifi
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2-Butanone
1 ,1 ,1-Trichloroe thane
Carbon tetrachloridc
Benzene
TricJiloroethene
1 ,2-Dichioropropane
Ethyl aoylace
Methyl methacrykte
Bromodichlorornethane
cis-1 ,3-Dichloropropenc
trans-1 ,3-Dichloropropenc
1 , 1 ,2-Trichloroedianc
Dibrornochioromethanc
Ethyienc dibrornide
Bromoform
Chlorobenzcnc-d
4-Methyi-2-pentanone
Toluene
Tetrachlorocthene
2-HexaiioflC
Chlorobcnzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrenc
1 ,1 ,2,2-Tetrachloroerlitne

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0.001
0.001
0.001
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0.001
0.001
0.001
0.001
0.001
0.001
0.001
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0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05

0.05
0.05
0.05
0.05
0.05
0,05
0.10
0.05
0.05
0.05
                        NA- Not Applicable; Del. Limit Detection Unit; Quan. Limit: Quantttation Limit
    IS: Internal Standard; lit Undetected; B: Present In Blank; J: Estimated- Btlow QuantiUtion Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
801 Capitola Drive * Durham, North Carolina 27713
Phone: <919» 544-5729 • Fax: (919) 544-5491
                                    Savarv3.5
                        Printed: 22:48 07/25/1997
                                                                                                    510
-------
Project Number: 42284                                                               Method 8240A VOST
Sample File: HS350                                               Sample ID: VOST FB 3 TUBEA/B T/TC
Cumenc                                              U                               0.001                  005
1,2-Didilorocthane-d                             0.291                  5-11                  1                   116
Benzene-d4                                      0.288                  5.09                  2                   115
Toluene-d                                       0,285                  7.51                  3                   114
Reviewed by	f  (A )	  Date /  le
                          NA- Not Applicable; DeL Limit: Detection Limit Quan, Omit: Quantitation Limit
     IS: Internal Standard; U: Undetected;B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated-Above Calibration Range
Triangle Laboratories of RTF, Inc.                                                                               Savar v35
801 Capitoia Drive » Durham, North Carolina 27713                                                       Printed: 22:48 07/25/1997
Phone: (919) 544-5729 « Fax (919) 544-5491                                                                           'ill
-------
Project Number: 42284                     Method 8240A
Sample File:     HS350                    Sample ID:       VOSTFB3TUBEA/BT/TC
Client Project
TLJID:

S407-003
173-46-15A,B


Dilution Factor:
Date Received:
Date Analyzed:
1.00
06/30/97
07/08/97

                           Tentatively Identified Compounds
                                ...RE.:?:..: ...;.. ..Area ,-: .....  IS JFTT .;..   IS Aiea
  Methvlbutane Isomer              1.640      1506290      4511     3103360          0.121
Triangle Laboratories, Inc.
                                                                                 512
-------
                   on
                   ~4
                   in
-08-97  21:29         Triangle Laboratories of RfP,  Inc.
    :  UOSf  FB 3 TUBEA/B  T/TC  173-46-15A/B  TLIft42284
(919) 544-5729
  Instrument H
t,
189-



XFS-

J
V-
B
5718 1456273
| TIC
#1
I f^



*
v
4.
2.4s
~-U\J,

5.


L
>^
67



9.



,.
79 12



/ .. y i
'87



15,64
Min ' 4^0 ' 6!e e!0 ' 10.0 ' 12'. 0 ' 14.0 ' ie'.e
                 Di
                 O

-------
JUAN ' 08  ::  H3350




 No,  HAT  FOR REV Delta
   LAB-BASE   QUAN
Area P.Flags
              07-08-97
                     21:
RT
QM Name
^
2
3
4
S
6
7
8
9
10
11
12
13
14
15
16
17
,1O
19
20
21
22
23
24
25
26
•->T
28
29
30
~" 3 1"
\j*~
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
49
50
1OO
100
1OO
74
1OO
1OO
O
1OO
14
0
0
0
0
o
0
0
0
oc-
46
O
1OO
O
O
O
10O
0
Kf"*i
O
o
0
it
w ^
0
0
0
92
0
0
0
o
o
o
0
0
0
0
0
100
0
97
95
97
36
83
93
0
88
11
0
0
0
0
0
0
0
0
/"S/-S
37
0
77
0
0
0
96
0
.4 ~y
O
0
0

w,*-
0
0
0
58
0
0
0
0
o
0
0
0
0
0
0
84
0
99
97
98
84
85
99
0
93
11
0
c
0
0
0
c
0
0
*•> ct
38
0
98
0
C
C
97
0
A £
0
o
0

w*.
0
0
0
94
0
0
0
0
0
0
0
o
o
o
0
95
0
o
0
	 1
1
0
1
o
1
1
0
0
o
0
0
0
0
0
1
1
0
1
0
0
0
0
0
-7
0
o
o
r-*-J
•** f
0
o
o
1
0
0
0
0
0
0
0
0
o
o
0
2
0
3496OO
2263O16
2783444
1095100
3010816
3601 7 S2
0
1834692
62O8
0
0
O
0
0
0
0
0
o 1 OQ
67240
0
1217O4
O
O
0
83588
0
*jf\ -70
0
o
o

i ^»*fk7V
O
o
o
576595
O
0
o
0
0
0
0
0
0
0
0
86876
0
bv
bv
bv
bv
bv
bv

bv
bv








bb
bv

bv



bb

f\



bl/
•V



bv











bb

4
5
9
5
5
7
O
12
0
0
0
0
0
0
0
0
0
o
2
0
2
0
O
0
3
0
•rt
o
0
0
T
W
0
0
0
5
0
0
o
o
o
o
o
o
o
o
o
7
0
,51
.66
.79
.11
.09
51
.OO
.07
.94
.00
.OO
.OO
.00
.00
.00
.00
.00
C 1
.58
.00
.98
.OO
.00
.00
.57
.00
-1 ^">
.00
.00
.00
J. *J.
M W f
.00
.00
.00
.14
.00
.00
.00
.00
.00
.00
.00
.00
,00
.00
.00
.61
.00
128
114
117
65
84
98
98
95
50
62
39
94
64
1O6
101
96
142
-?• /
43
76
84
96
73
53
57
63
jl^
96
83
62
o /
43
72
97
117
78
130
63
55
69
83
75
75
97
129
1O7
173
A~y
MQ
92
164
Broinacnlorame thane
1 , -3-DI f 1 uoroben.zene
Chlorobenzene-d5
i. , 2-Dichloroethane-d4
Benzene-d6
Tol uene~d8
o-Xylene-dlO
4-Bromcf luorobenzene
Chloromethane
Vinyl Chloride
1,3-Butadlene
Bromome thane
Chloroethane
Vinyl bromide
Trichlorof 1 uorome thane
1,1-Dichloroethene
lodomethane s~\i\^}
Tarhon di-sulf idf» n*?sV^
WCt 1 \~r\J II M .i v> M 4, I J, VJC^ VLi^
Acetone
Allyl chloride
Methylene chloride
trans-l,2-Dichloroethene
tert-Butyl methyl ether
Acrylonitr i le
n-Hexane
1,1-Dichloroethane ~"\
i O— Prsriv\yHsii't"ia n 
-------
No. MAT FOR REV Delta       Area  P.Flags       RT    QM  Name
51
5Z
T
xJ
*~>
0

0
1 Ci
-LU
r* c"
0
C A
C "
0
•-}
^ A
0
-1-7 / Q
•^•ooo
bb
/•*
0.
O
10
00
p c
~T z
43
11^
1O6
2-Hexanone ^v
Ethvlbenzene tv^J
 -5n4	63	5S	&S	9	5O2O  A	1O.36	  1O6  m-/p-Xy lene
 55   O   O   O      O          0             O.OO    1O6  o-Xylene
 56  76  6O  67      1      12O52  A          11.14    1O4  Styrene
 57   0   O   0      0          O             O.OO     83  1,1,2,2-Ts£rachloroethan
 -56	4£	2**	56	i	1316  bb	tt.83    105  Cumene/
                                                                         515
-------
                                                                                      C0
                                                                                      »H
                                                                                      in
87-68-97  21:29         fpiangle Lakiratories of BIP, Inc
Sanple: MOST FB 3 IUBEA/B  f/TC  173-4&-15A/B  ?LIfM22«4
(919) 544-5729
  Instrument H
HS350 94 (0.940)
1601 44
XFS-
M/Z 5M 108 158 200
HS350'94 (0.941) REFINE
1001 5
XFS -
Q
0
52
M/Z 50 100 158 200
9 (0,930) Chlorowethane
5
XFS-
: 44
0 ,»,«•'
e
52

M/5 58 100 ' 158 ' 200

262144

250 380 350

1152

250 300 350
FIND
100


250 308 350
-------
                                                                                     in
87-88-9?  21:29         Triangle Laboratories of RIP, Inc

Sample: MOST FB 3 TUBEA/B  T/IC  173-46-15A/B  TLI842284
                                                                  (919) 544-5729

                                                                    Instrument H
HS350 258  C2.588)

     44
1B8-I
XFS
                                                                           28928
  0
H/Z
        58
      58
            158
            208
            250
            300
           358
HS350'258 (2.581)  REFINE

IBB- 43
                                                                            5824
XFS
  0
M/Z
      4458
      58
188
158
200
250
3B0
358
NI2CAA 19 (2.570)  Acetone
    »o
1001
                                                                            FIND

                                                                             100
XFS-
  0
      44
        58
      58
                  180
            150
            208
            250
            300
           358
-------
                                                                                       oo
                                                                                       «H
                                                                                       in
87-08-97  21:29         Triangle Laboratories of RIP, Inc
Sanple: MOST FB 3 IUBEA/B  T/fC  173-4&-15A/B  TLIJW2284
(919) 544-5729
  Instrument H
HS358 298 (2.988)
100-
XFS-
0-
H/Z
4

, t
9 39424
8
51
1 f 5 lf*\
4
88
58 100 150 200 250 300 350
(2.981) REFIHE
100
Q
H/Z
NTZf
lB8i

XFS-
0-
H/Z
4
47
9 38656
8
51
j 55 83
4
88
1
50 180 150 288 25© 300 350
:AA
4

4?
4,1 i,
21 (2.970) Hethyiene chloride FIND
9 100
8
51
83
\
1

88
.i
50 ' 180 ' 150 ' 208 ' 258 ' 300 ' 350
-------
                                                                                       03
                                                                                       *H
                                                                                       in
07-08-97  21:29         friangle Laboratories of RIP, Ine
     e: MOST FB 3 fUBEA/B  T/TC  173-4&-15A/B  TLI»42284
(919) 544-5729
  Instrument H
357 (3.578)
100-

XFS-
0-
H/Z
5




1 56
\
44
1 in
50
7 11200


,' V 8.6
* • • i • • • • < • • • • i • • • • i • • • • i • • • ' i • • - • 	 ,....,.,,.,..,.,....,
100 150 200 250 300 350
HS358'357 (3,571) REFINE
100:

0
H/Z
5
41


56
55
7 1O368

> 71 8i6
f I * 1
5e 100 150 200 258 308 350
NTZCAft 25 (3.570) n-Hexane FIND
100

XFS -
0-
H/Z
5
43



56
\
55
\
. ...A
7 100


V ¥
50 100 150 200 250 300 350
-------
                                                                                      o
                                                                                      CM
                                                                                      in
0? 80 97  21:29         Triangle  Laboratories of  RIP,  Inc,

Sample: WST FB 3 TUBEA/B   T/TC   173-4&-15A/B   TLUI42284
(919) 544-5729

  Instrument H
HS358 514 (5.141)
iee-

XFS-
e
H/Z
84 138240
65
%4 F
42 1, I
.•HI 1. ... HI, . ,.] rl., „,!

85
i/ 102
5B 189 158 288 250 308 350
(5,141)
ieei
e
M/Z
7
7?
50 ?gv
i . , N
g 65824
79
36 100 150 268 250 388 358
MT2CAA 3& (5.131) Benzene FIND
180-
XFS -

8-
w/z
7
77
52
...1, . 1 	 	 6^3 ^ ,|t
8 100

79
i
59 109 15B 280 250 308 350
-------
                                                                                       10
87-08-9?  21:29         Triangle Laboratories of RIP, Inc
Sample: MOST FB 3 TUBEA/B  T/TC  173-46-15A/B  TLIH42284
(919) 544-5729
  Instrument H
761
1801

*FS
39
g: JfJ,,."|li
M/Z 58
HS3SB'761
1001

y.FS -
39
l' 5,1
6- i '
• ' 	 ' i •
»/z 50
HI2CAA 49
180-1

X.FS-
39
O<'t'f i-
M/Z 50
(7.611)
91
92
98
65j089
4 i" \> ••
100 150 200
(7.611) REFINE
91
92
65 89 §3
180 150 208
(7.601) Toluene
91
92
65 89 93
i 1 % *f
iee i5e 200

18432


250 300 350

16896


250 300 356
FIND
108


258 308 358
-------
                                                                                  CM
                                                                                  OJ
                                                                                  in
            21:29        Triangle Laboratories of RIP.,  Inc.
Sanple: WSf FB 3 IUBEA/B  T/TC  173-4&-15A/B  TLIM2284
(919) 544-5729
 Instrument:  H
Hl>358 164 Q.G40)
1801 A
n 1 ,.!
t4
. 57 .
,-* "... j .... i .... i 	 r. -i 	 » .,.,,,,,,,, i .,.,,.... | ...
(1.641)
« .-..-* 43
~ ^""^ 1 	 5 E«,
•XFR4 3» S V
»1 Jl .1 72
ttl FJ789 8
lea-j 4 if
XF S -j 3^% I
n J jl
S3 F; 75V 1
XFSJ N
99 J HVPKOXVLAHINE, 0- C2-METHVLPROFVD-
3
44|?58 J1
C ,...kr .^72 .
62«: FHOFflNE, 2-HE1HVL-1-HITRO-
57
42
§3 F;74S 1429 : PEHTANE, 2,4-»IMET«l¥L-
. «»-4 4:1
v fc c J 2 7 H 9
is ! rti. . j.l
5?
53 33 8S
i^s 50 108 156 280
MBS
70656

258 368 356
NBS 242 Hits : 242 Searched
12688


• i »'"' • • i • •--* • i .............
C4H110N 255


255
C4H902N

255
C7H16
258 30O 358
-------
Project Number: 42284
Sample File: HS372
                        Method 8240A VOST
Sample ID: VOST-4 SET 1 TUBEA/B T/TC
x-:-: :-, ::: !-:-:-x-;-:::: :- xl£-:;:xx"-x>x''x:x- <'.'::->X:Sx" x*-:::;::*:*: : *>/. ':-':<
!±:^'*:'^':S'^^X>^^«<^-<-^t^*:;-::::->•::-. :::5;::':::X:"v.:^-ix:K-;.>S^-**>>^-

Ifli SP^s^^ls^EiSli-iliMivfit:." ".
ifi! ^^^^^^^W^^SSiSi^KS^^-'


*tt;:o:V:V:: ::':x^':::::t:Y:::x't:t-':'i: xy^xtxSx'xXvWxSxv:-
Bromochlotomethane
Chloromcthane
Vinyl Chloride
1 ,3-Butadiene
Bromomethane
Chloroetlianc
Vinyl bromide
Trichlorofluoromethane
1 , l-Dichloroethene
lodomethane
Carbon disulfide
Acetone
Allyl chloride
Methylcne chloride
trans- 1 ,2-Dichlorocthene
tcrt- Butyl methyl ether
Acrylonitrile
n-Hexane
1,1-Dichlorocthane
1 ,2-Epoxybutane
cis-1 ,2-Dichloroethene
Chloroform
1 ,2-Dichlorocthanc
Isooctanc
1 ,4-Difluorobenzene
Vinyl acetate
;i|§||^i||lii:p|^|ft|si^f|

0.250

0.324
0.032
0.070

0.030


0.419
0.050

0.356


1.732
0.333





0.006


lili««lli»;lflli
f§:®||g||§||;;ff!;I|
IS1

U

J

U
J
U
U

B
U
B
U
U
E

U
U
U
U
U
J
IS2
U

4.48
0.92

1.08
1.41
1.53

1.82


2.48
2.56

2.95


3.24
3.54





5-27
5.63




0.001



0.001

0.001
0.001


0.001

0.001
0.001


0.001
0.003
0.001
0.001
0.001


0.001


0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05

0.05
                          NA- Not Applicable; Det Limit Detection Limit; Quan. Limit: Quanritation Limit
     IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                         Savar v3.5
                             Printed: 15:03 07/22/19^7
                                           kj s* 0
-------
i^M^iiSillSnWjS^
Project Number 42284
Sample File: HS372
•:.:.-. ; -:-;:-!:>.... .;.,_, • • • •:•";,•:•:. :; •;;„•:•; \".\ •• •'• •• '••••••;•;•''•:'?*/
F^I'tdFI t': trYfUt '£&*$* ' - JC-3'H ^hlirtfi jfc.' ' '••'•*'-
%»&Att£'J| T.^:'ilT:"a ^^j'JCiv-Iv.'fjjJTF M JTrfVU ?.-.-.-.' -

i^^^^pisi^iiimi^^miii^i^iMii
lift!
Method 8240A VOST
Sample ID: VOST-4 SET I TUBEA7B T/TC

?i§li^||ii|| 1|1|||||||1 flllltfl



i**;:tr":":^:*' .":"'••' '•-•".; <•'•:-'..'. 1. 2-s, -'...-.:: * •:•<-£-/;•:•;:: >j:-Kv^Xv":::$v-
2-Butanone
1 ,1,1-Trichloroe thane
Carbon tctrachloride
Benzene
Trichlorocthene
1 ,2-Dichloropropajlc
Ethyl acrylate
Methyl methacryiaw
Bromodichloromethane
cis-1 ,3- Dichloropropene
trans-l,3-Didiloropropcnc
1 , 1 ,2-Trichloroetliane
Dibromochloromcthane
Ethylenc dibromide
Bromoform
Chlorobcnzenc-d
5
4-Methyl-2-pentanone
Toluene
Tetrachloroethene
2-Hexanone
Chiorobcnzene
Ethylbenzene
m-/p-Xykne
o-Xyfene
Siyrene
1 ,1 ,2,2-TciratJilorocthanc
NA-

0.025 J
U
U
0.890 B
0.00 1 J
U
U
0.137
U
U
U
U
U
U
U
IS 3
U
0.433 B
U
U
0.006 J
0.058
0.154
0.062
0.166
U

4.36
0.001
0.001
5.10
5-87
0.001
0.001
6.45
0.001
0.001
0.001
0.001
0.001
0.001
0.001
9.74
0.001
7.56
0.001
0.001
9.78
10.07
10.30
11.01
11.06
0.001
Hi
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.10
0.05
0.05
0.05
Not Applicable; Det. Limit: Detection Limit; Qnan. Limit QuantiUtion Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated* Bdow
Quantisation Limit; i: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone; (919)544-5729 • Fa* (919) 544-5491
             Savar v3.S
Printed 15;03 07/
-------
Project Number 42284                                                               Method 8240A VOST
Sample File: HS372                                          Sample ID: VOST-4 SET 1 TUBEA/B T/TC
Cumene                                       0.004  J             11.78                                    0.05
l,2-Dichloro«liaije-d4                            0.217                 5.08                 1                    87
Benzene-d                                     0,250                 5.06                 2                   100
Toluene-d                                     0.288                 7.47                 3                   115
         &
 Reviewed by	TU)        Date "1
                          HA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
     IS: Internal Standard; U; Undetected; B; Pre»«nt In Blank; J: Estimated- Below Quanritation LioiH; E Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc                                                                               Savar v3.S
801 Capitola Drive • Durham, North Carolina 27713                                                      Printed; 15:03 07/22/1997
Phone: (919) 344-5729 • Fax: (919) 544-5491                                                                      _ _
                                                                                                      0 *. u
-------
                                        Environmental Services
Project Number:  42284
Sample File:      HS372
Method 8240A
Sample ID:
VOST-4 SET 1 TUBEA/B T/TC
Client Project:
TUID:

S407-003
173-46-16A,B


Dilution Factor:
Date Received:
Date Analyzed:
1.00
06/30/97
07/09/97

                            Tentatively Identified Compounds
1 • fiiiiie-' ••- ' -
C6H12 Isomer
C4H8 Isomer
C8H16 Isomer
C9H18 Isomer
C5H10 Isomer
Methylbutane Isomer
C7H14 Isomer
Octane
C5H8 Isomer
Hexamethylcvdotrisiloxane
•; RT
3.450
1.010
7.791
10.471
1.870
1.620
5.421
7.931
2.180
8.661
Area
20174306
19642262
14853554
11000834
8517349
7229730
6690068
6857868
5759000
3942456
tSPTT
4.491
4.491
9.741
9.741
4.491
4.491
4.491
9.741
4.491
9.741
IS Area
10315775
10315775
10783097
10783097
10315775
10315775
10315775
10783097
10315775
10783097
Amount uq 1
0.489
0.476
0.344
0.255
0.206
0.175
0.162
0.159
0.140
0.091
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 * Fax: (919) 544-5491
                    Printed:   11:59  07/25/97
                                                                                  526
-------
                                                                                    CM
                                                                                    IP
87-89-97  16:21
Sawle: UOST-4
     Triangle  Laboratories of BTP, Inc.
1 fUBEft/B  f/TC  173-46-16A/B  TL1W42284
(919)  544-5729
  Instrument H
/
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Area
3S221&
2237296
2844308
8923.12
2588068
3724906
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106280
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.08
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.82
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.95
.OO
.24
.54
.00
.OO
.00
.00
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l~ A

.36
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.OO
.10
.87
09
f* C
- V —
.45
.OO
,OO
.00
.00
.00
.00
.00
x", -7
.56
.00

3«
... 7.' 8
:.. 1 4
117
6S
84
98
or-
95
50
39
94
i «v'3 /. ^
1 >^*3 OH
106
1O1
96
142
76
43
76
84
96
	 t O
53
57
63
96
83
62
57
j*~y

72
97
117
78
130
C C

69
83
75
75
97
129
107
173
L-/
cis-1, 2-Oichloroethene
Chloroform
1 , 2-Dichloroethane x
Isooctane )
Vinyl acetate(f^)n^-^
2-Butanone
1, 1,1— T rich lo roe thane
Carbon tetrachloride
Benzene
Trichloroethene ^
10 — »• r^ ^ /^Hl r^f^nnr^r^r^^n #2^ -— .
^ X. L** A «— . 1 1 J, W I w^/l w|~^C(i 1C? X-^gj^-ys
Ethyl acrylate Jo?'^
Methyl methacrylate
Bromodichlbromethane
cis-1 , 3-D ichlorop rope ne
trans-l,3-0ichloropropen
1,1,2-Trichloroethane
Dlbromochloromethane
Ethylene dibromide
Bromoform
x Mc^-f->"\/1 O »-x d cs -f- T *-» -^ 1^1 ^r^u^^l
^t i rci i* y -i ^. i^/cs n Lfci nu n®ii?Tj /.
Toluene —
Tetrachloroethene
Data Review: "TLG





Dote:
	 "1 ^ «"| *«^ ^
n


••> «"% *"^
528
-------
T FOR REV Delta
QM Name
.
52
.bo
3d
K( C
. 56
— ' .*
50

'•*> 3
1OO
100
100
100
JUW
S3

19
S3
,34
SO
S3
28
.._
63
<3*7
93
87
96
64

O
(j
-1
1
u.
0
„„..,-_
63O80
337950
1114592
429028
19O566-J
iij^.-j.ii,
89239

bv
bv
vv
bv
bv
vv

9
10
10
11
11
3T
11
....
. 78
. O7
.30
.01
.06
. .,-4
.78

112
106
106
1O6
1O4
105
. ^_____, ,
o-Ho.,,.-, nr~ n -(<&% VX^
Chlorobenrane
Ethvlbenzens
:n-/p— Xy lene
o-Xylene
Styrane ^.^^
,1,2,^. i e L. i ticnior cpwjiMT'
Cumene
                                                          529
-------
                                                                                      o
                                                                                      en
                                                                                      to
87 &J-y?  1b:2fl          Triangle Laboratories  of  RTP,  Inc.

Sample:        SET 1           T/TC  i?3-46~16A/B   ILIM2284
                                                                   (919) 544-S729

                                                                     instrument H
      92  (11,928)
                              150
                                          288
                        256
                        3B@
                       358
HS372'92 (8.921)
      *?«
1001
xFS-
  O.L-J1-
                  100
                              Tie
                                                                           38064
            26Q
            256
            380
356
HT2CAA 9  (R.9BB)   Chloronethane
                                                                            FIND
                                                                             160
  e-L^
       5S
                  188
15B
288
256
358
-------
CO
in
87-kfy-97 Triangle Laboratories of IIP, Inc. (919) 544^5729
Sanple: UOST-4 SET 1 TUBErt/B T/IC 173-46-16A/B ILIft422B4 Instrument H
JH5372 188 (1.080)
1 39 248832
xta-

XFS-







a Jji
54
i
58


iiil I i
Hi ^ •" — ™ |-
1
H
! 64
j I
ili 	 L
i. ,..-. | , ,, ' I " ........ A... .,.!., .....|,..Jj. 1. J|....|. ..,
n/z 5B 160 158 200 250 388 350
(1,881) REFINE
100
XFS-
P-


(
39 5
58

H/z 54
f4 210944


i ISO 150 200 250 300 350
HTZCAA 11 (1.B9B) 1,3-Butadiene FIND
.u^39 10e
.f. "~ ** ,
XFS-

Q '




5
58


4

T ~
/
M/Z '50 • • • - • iee -•-.-•• A^e ....... ^^ . . , ^^ , ^^ , ^^^






















-------
                     ro
                     in
ijy-iiy-y?  IS*28          Triangle Laboratories of  RIP,  Inc.

Sample;        SIT  I          T/TC  173-4&-16A/B   TLIft42284
(919) 544-5729

  Instrtiwent H
\lii~.-~l-, --t 4 -< -5 /4 ttlf£\
jno-jr«, .tti 11 silo J
	 . 44
I Ms 1 ~ ~ g
j
xFS1
48 64 9$.
. :..( I V I
28992
4
N/Z 58 100 ' 150 ' 208 ' 250 ' 38B 350
HS3?2'141 (1,411)
jaa-i '
|
XFS1 93
! f i "
n : , , 1,1: li
REFINE
q 17920
J»/s 5B ' IMO ' 150 ' 208 ' 258 ' 300 ' 350
12 (1,428)
iea-| y
j
y- |i V ™«
93
46 r, , '',
,-ia .- SI
p 1 W i". ( !.l. I.
BrcmcmelhanR FIND
f 100
H/2 58 1S9 158 268 256 389 358
-------
                                                                                       CO
                                                                                       en
                                                                                       in
09-Jul-97 16:20          Triangle Laboratories of RTF,  Inc.
Sample:  UQST-4 SET i TUBEA/B   T/TC  173-46-16A/B   TLIH42284
(919) 544-5729
  Instrument H
HS-172 153 (1.538)


MFS;-
H/'T.
44 16896
r;r:
JJX 6

JlLo.
4

70
50 100 150 200 250 300 350
HS3i72'153 (1.531) REFINE
i&& 64 4e96

xFS-
8-
m/'i,
60

49

66
f
50 100 150 200 250 300 350
WiSTER 13 (2.028) CMoroethane FIND
ICie-i
XFS
f)
M/'Z;
6

49
4 100
66

50 100 150 ' 200 ' 250 ' 300 ' 350
-------
                                                                                     00
                                                                                     in
GV-Hy-9?  16:28          Triangle Laboratories of IIP,  Inc.
Sanple:        SET i fUBEA/B   f/IC   173-46-l&A/B
(919) 544-5729
  Instrument H
182 C1.82B)
iS0i

XFS-

t»^?L
4:1 34384
i
55
| 44 79 *
f 6i4
i' t ' 1 1 00
ii'ill l!,!ij,, ,. .1,111,, O.V
?1
105

58 188 158 24J0 258 380 350
HS3?2'18Z (1.021)
.163-
XFS-

H:"~ 3_
U


'Y f 8-2
p ' ' ' * i
H 15616
183

105
If 119
59 1«« 153 200 258 363 350
15 Q.84B) TrichlorofluGranetfane FIND
*,^_ 1M1 160
\
XFS-]

:.f?'' Z
^i7 f^ S.2
I4S3

185
f 117
SB 1SQ 158 280 258 308 350
-------
                    in
                    CO
                    in
                        Triangle Laboratories of RIP, Inc.
Sample:  UOST-4 SEI 1 IUBEA/B  T/TC  173-46-l&A/B  TLW42284
(919) 544-5729
  InstruRent H
248 (2.488)
100-
> 1 IT'l- ~
/,_r TV
0
M/Z
?

44
1 S3 67
..ii|t.l,..-<'|,J-T'" i.tsiJl,.-..
6 782336

78
56 108 158 288 258 388 358
11372-248 (2.481) REFINE
189-
XFS -

8
?


,,f*5,3 &,7
6 778848

78

•""• ' r • • < '• r • • • • 1 • • • • 'i • 	 i • 	 i • • • • i i • • • i i • • . , t . . . | . . i . | . . i . ( . . , . ,
50 lag 158 288 258 308 356
18 Carbon disulfide FIND
188-

XFS i
a
5^ ~
7


44
1 ' ,
6 iee


78
58 1@8 158 288 258 388 358
-------
                                                                                       CO
                                                                                       CO
                                                                                       in
       y  16128          Mangle Laboratories of RTF., Inc.
Sanple: MOST-4 SIf  1           T/fC  173-46^16A/B  ILIW42284
                                                                   (919) 544-5729
                                                                     Instrument H
JH0
IIS372 2bb  (2,568)
     43
             7.6
      44
      '  5.3

      I 57
                                                                            11072
       58
                  188
158
269
250
see
35©
           (2.5G1)

i@8i
                                                                             8448
       58
                  100
158
209
258
368
358
        19  (2 = 578)
                                                                             FIND
  13-
n/z
                  IOC
                              158
            283
            256
                       350
-------
                                                                                        in
07-89-97  16:28         Triangle  Laboratories of RTF, Inc.
Sanple:  VGST-4 SET 1 TUBEA/B   T/TC  173-46-16A/B  TLIE42284
(919) 544-5729
  Instriisient H
295 (2.950)
100

•-FC
•""• £ ^


a
4


42

t i
, J; T|
9 282624
84
51

''55
{ 70
i |,


88

.i
«/z ge ISB 200 259 see 350
HS372J295 (2,951)
49 274432
1B8~
XFS '



q.


d"?
*"
, ]

8
51
.--"
err;
/" 7.8
- '! , i!i; .J 	 L .
1

88

.1
M/75 58 158 288 258 300 358
mZum 21 (2.970) Metliylene chloride FIND
AM 1 OR
IBB]

X.FS-



tj.


8,4

4?
^2 t
4i i,

51
/
83




88
/'
.1
w/z 59 160 150 208 250 300 350
-------
                                                                                       oo
                                                                                       CO
                                                                                       in
87-69-97  16:26         Triangle Latoratories of HIP,
&mple: UOST-4 SET 1 TUBEA/E   T/IC   I73-46-16A/B  TL!ft42284
(919)  544-5729
  Instrument II
[HS372 324 (3.240)
100! 5:3 178176
XFS -
H/Z
HR'17
ieo-
%F5-
H/E
51
juk^
HI
1
1 c7
u ..... . ..
J ley 158 268 258 388 353
52"3Z4 (3.241)
5.3 1S5888
H
38 j
T
*Ji

1 06
1 168 15B 200 258 306 359
24 (3.278) Aery loni.tr He FIND
53 160

XFS -


s s P
'j
o *-*
i
:,-', .!,..!

=%«! - n
?-63
00 1SS 158 208 258 388 35O
-------
                                                                                       CD
                                                                                       CO
                                                                                       in
07-89-97  lb:20         Triangle Laboratories of  RIP,  Inc.
Sanple: WST-4 SET 1          f/TC   173~46-1GA/B   ILI842284
(919) 544-5729
  InstriiRent H
354 (3,540)
5
] 41
xFs-i
8-
5:% XT.

* 155
1 ;::
7 387280


787, *?
58 108 150 288 258 388 358
(3.541)
, r-3 5
11-101
i
i
vFS-
8
H/Z
.
£

s3

7 282624

PS ee
5B 150 288 258 300 358
TtT2Cf!A Z5 (3.570) n-Hexane FIND
168-

Xfr'S "
O
M/Z
5
43



56

55
7 100


8b
7,1 1
53 188 ISO 288 250 380 350
-------



H7-89-.J7 J
Warmle' Wb
52?
««n 5.7
¥--
1 I "-" "
VFC -J • -•«-:} '•• s^
"* " j Td |-3
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i . jl i = j!fi>
s-;s 1 Mi:||J [IliljH ,

H/S 36
H-!i-Ji£. 3£.i
leS] 57
1
4
•j
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H/z 5B
HT2CAA 31 (
18@- "V
: t
I 5S

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M/S 50



&:28 Triangle laboratories of BTP, Inc. (919) 544-5729
T--4 SET 1 T/TC 173-46-1&A/B fLli42284 Instrument H
(5.271)
12632


3 S^
&? V
I-! 'i 9<»
, ail, iii hi , 3s- t , .., ,
• • 	 	 ,..,.,.,,.,.. . , .................... j ....,....,
198 138 26«* 250 388 336
[5.271)
64 9-3 536




180 15B 268 258 368 350
;5.291) Isooctane FIND
108




9 '3
• •!••-• • • , 	 	 I - • • • 1 ' 	 '' ..,.,..,,-.. | I "... j ' ... '1 | . '« 	 » l '1 . "... | . . j "J
100 158 288 258 368 356
O
•<*«
in



























-------
                                                                                         in
   09-97   16:28          Triangle Laboratories of IfP,  Inc.
   ple: MOST 4 SET 1 TUBEA/B   T/TC  173-46-16A/B  TLItt42284
                                                                    (919)  544-5729
                                                                      Instrument H
      436  (4,368)
•i sTii-t ...    J. "IE
   j 43
  0 I. ill!*, -jin.
        :=3

        56
        1	i.
                  100
                              158
            . 361 )   REF INE
1601
MFS
  64-
m/-z   5©
              84
                  189
                              150
                                                                              7616
             108
            258
            303
           -r—•--•,
           358
                                                                              4O32
            233
            258
            388
           358
       33 (4,300)  2-lutanone

n/z
      59
                  ISO
158
                                                                             FIND
208
258
388
                                                                              350
-------
                                                                              m
JB f » -r~ij"2i
SI1
         1
Tr-iangle Laboratories of ItTP, Inc.
      I/iC   1?3-4&^16A/B  TL1842284
(919) 544-5729
  Instrument H
t * i rt -T T< *~» r" -I »5 / IT -^ o -i \
noo f A 3 Its 1 5 , lol )
1B0-, ?3
j

xre-:
' -f
«U 	 1, 	 £LV
84
'I...L
H/s 58 ' leg ' 158 ' 200
(it. 181) REFINE
lean 7
1
^.r i
-r---i 77
i, h(i ~!\
a !..i! . ..II .,.1. ..i,!
3


79
i .
IH/Z 58 ' 188 ' 158 ' 298
3fa (5.131) Bensene
lee-i f
]
"1 ^ ^
«i..i I!. 6,3 .,.
0
79
H/Z 56 ' ' 15B ' 200

1441792



250 360 35W

1376256



256 388 350
FIND
lee

258 308 358
-------
                                                                                         oo
                                                                                         <3«
                                                                                         in
89-Jul~97 16:28         Triangle Laboratories of  RTF,  Inc.
Sample: UQST-4 SET 1 TUBEA/B  T/TC   173-46-16A/B   TLItt42284
(919) 544-5729
  Instrument H
HS372 585 (5.851)
180-

XFS


0-
41 5
55
\
53
\ i
II li
1 1 li li
7

8640
81

69

I
in II
n/2. 50

, ill
III,
I


96
L 132
i (III i
1.
188 ' 158 ' 288 ' 2^e • 3^Q • 3g0
HS372'505 (5.851) REFINE
.«« 57
100-
XFS
0





60
1
M/2 50



J
I
4736


9
5 132
i 1 li
100 ' 158 ' 200 ' 258 ' 300 350
MASTER 39 (6.780) Trichloroetliene FIND
100-1


XF$


0-

f a
r

4,7
.. . L,
JKF




95 130 100



62

ll
M/2 50


1

i
9?


99
/
i.i


134
/

,
188 158 288 250 300 358
-------
                                                                                        in
          lb^-9          Iriaiiyls Laboratories of EITf Inc.
Saiwta: VOST-4 SET  i           f/fC  173-4&-16A/B  TLII42284
                                                 (319) 544-5729
                                                   Instp«nent H
        55
           69

             70 81

                                                                            57344
       53
iee
150
zee
250
3UB
358
i!!S372'645 (6.451)  REPINE
    .41
     j .-
              0
               R5
       58
            15B
            260
             56
            388
                                                                            44544
           356
   Cflli  46 Cb = 491>  Methyl wethacrylate
           69
      42

                  168
            158
            268
            25@
            386
                                                           FIND
           359
-------
                                                                                      in
                                                                                      "^
                                                                                      in
?-89-9V
ample:  11081-4 SET 1
Triangle Laboratories of RIPj  Inc.
 :A/B  T/TC  173-46-16A/B   fLIf42284
(919) 544-5729
             H
756 (7,561)
188 -i 9

;-:FS -
p ...uV,S^.TJ?5
1
92

93
w/z 56 100 ' 150 ' 280 250
H5372'75b (7.561) REFINE
lea- 9

XFS1
39
1
92

93
M/S 50 168 ' 156 ' 20© ' 258
49 (7.681) Toluene
?

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93
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Sanple:  UOST-4 SET 1 IUBWB  I/TC  173-4&-16A/B  TLItt42284
(919) 544-5729
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1807 (18,871)
j.08-1 9
1



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1 123904
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M/Z 58 108 158 208 258 380 358
53 (18,131) Ethylbenzene FIND
91 100
1001

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07-89-97  ife:28          Triangle  Laboratories of  EfP,  Inc.
Ranple: MOST-4 SET 1 IUB1A/B   I/TC  173-46-16A/B   TL1M2284
(91.9) 544-5729

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-------
                                                                                      OT
                                                                                      «3«
                                                                                      ID
07-89-97  16:ZO         Triangle Laboratories of RIP,  Inc.
Sample:  UQST-4 SET i fUBEA/B  T/TC  173-46-IbA/B   ILItt42284
(919) 544-5729
  Instrument H
1181 (11.81
lOH-i 9
1
i
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1 98112

106
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1 188

186
?2 197
1»0 158 288 258 358
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                                                                                      in
87*8:3 97                 Triangle Laboratories of IIP,  Inc.

Sarwle: UOST^4 SET 1           T/TC  I73H6-1GA/B
(919) 544-5729

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113372 llflh (11.861)
*po, J^4

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2B8 259 300 359
-------
                                                                                      ID
                                                                                      in
          16:20         Triangle Laboratories of RTF,  Inc.
Sarnie:  UOST-4 SET 1 TUBEA/B  T/fC  173-46-16A/B  TLIft42284
(919) 544-5729
  Instru.Rent H
1178 (11,781)
108-^ 195 10848
] ! 55
8-
H/Z
1
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ii 'i' r ' ii
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120
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58 186 158 288 258 388 350
HS372TI78 (11.781) REFINE
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38 79 103
•^ *jf _ .„ -. O ,^1 \
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15 6656
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50 180 158 208 250 380 350
58 (11.851) Cuwene FIND
1001 1?
4
XFS-
H/3E

183
, 5^ _63 Ji '1
J5 108


128
i . 1
5@ 188 150 288 250 380 350
-------
                                                                               CM
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C7H1202 255
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W/Wj/y/    16:28         Triangle  Laboratories of RIP,  Inc.

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                                                                                     in
             ib^Zfl         fs'i.Tfxglfs Laboratories of ITPi  Inc.
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186496
200 250 380 350
NBS 83 Hits : 83 Searched
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255
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C8H140
200 250 300 356
-------
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                                                                           in
MVVWJ/47     l£.:2M         friangle Laboratories of RTF. Inn.
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ii7/!iy/yy    16:ZR         Triangle Laboratories of IIP, Inc.
Sttnp.ie:  MOST-4 SET  1  TUBWB   1/IC  173-46-l&A/B  TLIi42284
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44 __ 72
"i^a: 50 100 158
NBS
288 258 308 358
NBS 242 Hits : 242 Seapched
19456W
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C4H110N 255
C7H16
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255
C5H12
280 256 3O0 356
-------
09-Jul-97 16120         Triangle Laboratories of RTF, Inc.
Sample: UOST-4 SET 1 TUBEA/B  T/TC  173-46-16A/B  TLW42284
(919) 544-5729
  Instrument M
HS3?
100
XFS
0-
>Z 542 (5.421)
( \?779
M/Z 50 ' 100
HS37
XFS
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ttl
100-
XFS-
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tt2
100
XFS-
0-
'2' 542 (5.421) REFINE
4J
39
152576
150 ' 2eQ ' 2^0 ' 300 ' 3S0
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43 53
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6 119808
57 £o 70
< M ... 83 9,8
HVL-
6 255
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50 60 70 80 90 100
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                                                                                   in
                                                                                   in
09-Jul~97 16:20         Triangle Laboratories of RIP, Inc.

Sample:  UOST-4 SET 1 TUBEA/B  T/TC  173-46-16A/B  Ti1*42284
(919) 544-5729

  Instrument H
HS372 793 (7.931)
I00i 43

M/2 50 ' 100 ' 150 ' 200
HS372'793 (7.931) REFINE
1001 4JL ^
XFS \ 44 57 7, 85
0 -i J , --i t|'lM (lit .' f |li,l/ r,.;s, , .,.,>,(,. >}it.
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1801 T ^6 85
XFS 27N 29 39 44 55^j 69 71 84/86
0 •' j 1 1 ^ t< * t ' i t "i-i*iiiii 11-"-*' • •• --..i'- . ..iif.
#3 F:818 15627 :DE<
1001 ^j3
XFS 39 44 '
M/Z 40
r*^L BJTp *^ jft f" ._ *y TPfc Tf ^|"Kri**i 11 •• w
wHrlliif & i tit D 1 If I PII!.* HY1»"~
57
55 58 69?4. 838.5 93 99
\ / \ I «J*J \ 1 Of, \ /
4-1 «i i M-i'i'r-'2 .S|if»o t ,>,f
60 80 100
145408
250 300 350
NBS 178 Hits : 178 Searched
112640
144
•1 -'• Li •• - -i -• -J t •• •-!• • •• i
255
14.4
255
1'i** ' I -J-- | ..*i|-,,, |
255
127
120 140 160
-------
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                                                                          CO
    ih;/;ti         Triangle Laboratories of IIP. Inc.
VOST-4 SET 1  TUBEA/B   T/TC  I73-46-16A/B  1LIH42284
Instrument" H
Ms:!?? 7lfj i'2 ifM1
5
Lisa-1 39 53
XFS .1? [51 63
i '• IH
a 1 ..it, ,.ji, ,. .,..j,
7
| 31
it. ..»..
H/S 58 IBB 150 200
HS372'218 (2,181)
"*«i . [fir ")
«1 F:51w 1.82:1,
l-3«3-i ^__ 53
XFS-1 2fi ??/* 1 54
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69
3-MJTfiMENl, 2-HETIIVL-
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3-P£NTf?!>!EHE, C3>-
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69
^'* 50 100 150 288
101376
250 3OO 359
NBS 33 Hits : 33 Searched
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255
255
CbHB
255
CGI 10
259 380 330
-------
               CO
               UT3
89-Ju1-97 16:28         Triangle Laboratories of RTF,  Inc.
Sample: UOST-4 SET 1 TUBEA/B  T/TC  173-46-16A/B   TLI842284
(919)  544-5729
  Instrument H
HS37
100
XFS
0
'2 864 (8.641)
207
28
6,7 (
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HS37
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0.
tti
100
XFS-
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#3
1001
XFS-
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'2J864 (8.641) REFINE
, W ...?,6 ... ...... 13,3 16^3 _ 13.1
F:?98 22491 :CVCLOTRISILOXflNE, HEXflMETHVL-
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185472
8
258 388 350
NBS 87 Hits : 87 Searched
287 58624
208
287 255
289
/
F:645 38155 :flRSENOUS ACID, TRIS( TRI MEIHYLS ILYL) ESTER
207 255
288
44 7,3 185 133 191 K . t
F:496 22628 :i,2-BIS
-------

Project Number 42284
Sample File: HS373
                       Method 8240A VOST
Sample ID: VOST-4 SET 2 TUBEA/B T/TC

Jllillllllllililii^igl



Bromochlorornethane
Chloromethane
Vinyl Chloride
1,3-Buwdiene
Bromomethane
Chloroethanc
Vinyl bromide
Trichlofofluoromcthanc
1 » 1 -Dichloroethene
lodomethane
Carbon disulfide
Acetone
Ally! chloride
Methylene chloride
trans- 1 ,2- Dichloroethcne
art-Butyl methyl ether
Aoylonitrile
n-Hexane
1 , 1 -Dichloroethane
1 ,2-Epoxybutane
ci»-l,2-Dichbroctricnc
Chloroform
1 ,2-Dichloroethane
[sooctane
1 ,4-Difluon>beniene
Vinyl acetate

IS 1 4.47
0.300 0.92
U
0.421 1.08
0.016 J 1.41
0.053 1.53
U
0.033 J 1.81
U
U
0.744 2.47
0.053 B 2.56
U
0.358 B 2.94
U
U
2.295 E 3.24
0.281 3.53
U
U
U
U
U
U
IS 2 5.62
U



0.001



0.001

0.001
0.001


0.001

0.001
0.001


0.001
0.003
0.001
0.001
0.001
0.001

0.001


0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0,05
0.05
0.05
0.05
0.05
0.05
0.05

0.05
                        NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
    IS; Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle laboratories of 8TP, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
                                       Savtsr v35
                            Printed: 16:25 07/22/1997
                                                                                                   562
-------
Project Number 42284
Sample File: HS373
                        Method 8240A VOST
Sample ID: VOST-4 SET 2 TUBEA/B T/TC
^^^iM^WViSimiiiliSMSml
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2-Butanone
1 ,1 ,1-TrichIoroethanc
Carbon tetrachloridc
Benzene
Trichloroethene
1 ,2-Dichloropropane
Ethyl acrylate
Methyl methacrylace
Bromodichloromethane
cis-1 ,3-Diehloropropene
trans-1 ,3-Dichloropropene
1 , 1 ,2-Trichloroethane
Dibfomochloromethane
Ethylene dibromide
Bromoform
Chlorobenzcnc-d
4-Methyl-2-pentanonc
Toluene
Tetrach loroethene
2-Hexanone
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrene
1,1 ,2,2-Tetrachloroethane

0.027 J
U
U
1.519 BE
U
U
V
0.218
U
U
u
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IS 3
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0.080
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9.74

7.56


9.78
10.07
10.30
11.01
11.06



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0.001

0.001
0.001
0.001

0.001
0.001
0.001
0.001
0.001
0.001
0.001

0.001

0.001
0.001





0.001

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0.05
0.05
0.05
0,05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05

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0.05
0.05
0.05
0.05
0.05
0.10
0.05
0.05
0.05
                         NA- Not Applicable; Dct Limit Detection Limi% Quui. Limit: Quantitation Limit
    IS: Internal Standard; U: Undetected; Bt Present In Blank; J: Estimated- Below Quantisation Llmii; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax (919) 544-5491
                                        Savarv3.5
                             Printed; 16:25 07/22/1997
                                      563
-------
Project Number: 42284
Sample File: HS373
                                                Method 8240A VOST
                         Sample ID: VOST-4 SET 2 TUBEA/B T/TC


Cumene
       0.007  J
11.79
0.05

1,2-DichIoroethane-d
Benzcnc-d
Toluene-d
       OJ37
       0.276
       0.282
 5-08
 5-06
 7.47
 95
 110
 113
Reviewed by.
Date 7  l^^Cn
                         NA- Not Applicable; Det Limit: Detection Um it; Qiun. Limit Quantttation Limit
    IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Qujjrtifcttion Limit; E: Esrimated- Above Calibration Eange
Triangle laboratories of RTF, Inc.
801 Capitula Drive * Durham, North Carolina 27713
Phone (919) 544-3729 « rax; (919) 344-5491
                                                                 Savar v3,5
                                                     Prinled: 1623 07/22/1997
                                                                                                     564
-------
Project Number:  42284
Sample File:     HS373
Method 8240A
Sample ID:
VOST-4 SET 2 TUBEA/B T/TC
Client Project
TUID:

S407-003
173-46-17A3


Dilution Factor:
Date Received:
Date Analyzed:
1.00
06/30/97
07/09/97

                            Tentatively Identified Compounds
|Efe¥$:K!:;i^
Unknown
C7H14 Isomer
Sulfur Dioxide
C8H16 Isomer
C4H8 Isomer
C9H18 Isomer
C5H10 Isomer
Octane
C5H8 Isomer
C13H28 Isomer

0.711
5.421
0.841
7.791
1.011
10.471
1.860
7.931
2.170
10.611

27882954
23254314
20716460
19498870
15310318
14679076
9742207
9190736
6804485
6661280

9.741
9.741
9.741
9.741
9.741
9.741
9.741
9.741
9.741
9.741
•M^tfii&Sg^tea
10573111
10573111
10573111
10573111
10573111
10573111
10573111
10573111
10573111
10573111

0.659
OJ50
0.490
0.461
0362
0.347
0.230
0.217
0.161
0-158
Triangle Laboratories, Inc.
801 Capitals Drive * Durham, Norm Carolina 27713
Phone: (919) 544-5729 * Fax: (919) 544-5491
                     Printed:   11:02   07/25/97
                                                                                 565
-------
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                               117  Ch 1 oi~obeiizene-d5
                                   1 „ 2-DiChioroetrianc-«j<:
                                84  Senzene-d6
                                90  Toluene-dS
                                   o-Xy.lene-dl
                                   4-8romofIuorobenzsne
                                   Chioromerhcine
                                   Vinyl Ciiloride/
                                   1,3-ButadIene
                                   Bromomathane
                                   Chloroathane
                                   Vinyl bromide
                                   Trichlorof1uoromethane
                                   1,1-Dichloroathene
                                   lodomethane
                                   Carbon disulfide
                                   Acetone
                                   Allyl chloride(
                                   Methylene chloride
                                   trans-1,2-Dichloroethem
                                   tert-Butyl methyl etf
                                   Aery Ioni trile
                                   n-Hexane
                                   1,1-Dichloroethaj
                                96 cis-l,2-0ichloroethene
                                83 Chloroform
                                62 1,2-Dichloroethane
                                   Isooctane
                                   Vinyl
                                72 2-Butanone
                                97 1,1,1-Trichloroetbane
                               117 Carbon tetrachloride
                                78 Benzene
                               130 Trichloroethene
                                   1,2-Dichloropropane^
                                   Ethyl acrylate
                                69 Methyl methacrylate
                                83 Bromodichloromethane
                                75 cis-l.,3-0ichloropropene
                                75 trans-l»3-0ichloropropen
                                97 1,1,2-Trichloroethane
                               129 Oibroroochloromethane
                               107 Ethylene dibromide
                               173 Bromoform
                                   4-Methyl-2-pentanon«
                                92 Toluene
                               164 Tetrachioroethene
Data Review:T^o
Date:  -
                                                    567
-------
                    Area P.F'Ut'.
:V2  60   7-1  74
S3 1OO   83  98
5Oiie
112 Ciiioro^enz
1D 6 E t h y I l-j .=> ii ,z e
1:,) 6 i n - / p - X y I e n
lOfa o-Xyiene
.134 Scyrans
 83 l,l,2,2
105 Cumane
                                                                    568
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16:44 Triangle Laboratories of HIP, Inc. (919) 544-5729
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87 -89-9/ 16:44 Triangle Laborator ies of ETP, Inc. (919) 5-14-5729
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117-09-97  16:44
Sanple:  UOST-4 SET
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TL1BEA/B  T/TC  173-46-17A/B  TLI«42284
(919) 544-5729
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87-0*9-97 16:44 Triangle Laboratories of RIP, Inc. (919) 544-5729
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Sample: UOST-4 SEI  2           I/1C  173-46-17A/B
(919) 544-5729
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07-83-97  16:44          Triangle Laboratories of IIP, Inc.

Sanple; WST-4 SET 2 fOBEA/B  T/TC  173-46-17A/B  ILII42284
(919) 544-5729

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Sample; WSI-4 SET 2           f/IC   173-4&-17A/B   TLIf42284
(910) 544-5729
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B9-Jul-97  16:44         Triangle Laboratories of RTF,  Inc.
Sample:  UOSf-4 SET 2 TUBEA/B  f/IC  173-46-17A/B  TL1*42284
(919) 544-5729
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Sample: VOST-4 SET 2 TUBEA/B  T/TC  173-46-17A/B  TLIB42284
(919) 544-5729
  Instrument H
HS3?
100
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89-Jul-97 16:44         Triangle Laboratories of RIP, Inc.
Sanple:  UOSf-4 SEf 2 TUBIA/B  T/TC  173-46-17A/B  TLIU42284
(919) 544-5729
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B9-Jul-97 16:44 Triangle Laboratories of BTP, Inc. (919) 544-5729
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Sample: UGST-4 SET 2  TUBEA/B  T/TC   173-46-17A/B   TLIH42284
(919) 544-B729
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HS37
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Project Number: 42284
Sample File: HS374
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Bromochloromethane
Chloromethane
Vinyl Chloride
1 ,3-Butadiene
Bromomethane
Chloroe thane
Vinyl bromide
Trichlorofluoromethanc
1 ,1 -Didiloroethene
lodomethane
Carbon disulfide
Acetone
AUyl chloride
Methyiene chloride
u-ans- 1 ,2-Dichloroethene
ten-Butyl methyl ether
Acrylonitrile
n-Hcxane
1,1 -DichJoroethane
1 ,2-Epo3tybutane
cis-1 ,2-Dichlorocthene
Chloroform
1 ,2-Dichloroe thane
Isooctane
1 ,4-Difluorobenzene
Vmyl acetate

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0.192
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0.246
0.020 J
0.092
U
0.037 J
U
U
0.398
0.041 BJ
U
0.771 B
U
U
0.618
0.353
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0.91

1.06
1.40
1.52

1.80


2.46
2.53

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-------

Project Number: 42284
Sample File: HS374
f^l i c^Ti't^ lP^fTi'oy*^:'-'^*£JMivii»itfyt":':':'':':-"':'-':'"'"'
%•*•! Itw J.lli-; Jk'l vTCt«l*( -t.yvxt'4 ^Wv0 ; :' ;"::';'•
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Pacific Environmental

Services • . ' - • •
Method 8240A

VOST
Sample ID: VOST-4 SIT 3 TUBEA/B T/TC
;'; ':-':: :::::V.':i'::'ii;1^^-l:^'«I^W:.O'ji;««5^
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                                           iill^^
Project Number: 42284
Sample File; HS374
                                                                                  Method 8240A VOST
                                                            Sample ID: VOST-4 SET 3 TUBEA/B T/TC
Client Project: S4Q7-003
TO
                                          Date Received: 06/30/97

                                          Date Analyzed : 07/09/97
                                                                             Response File: ICALH7Q&
Cumene
                                           0.004  J
                                                              11,78
                                                                                                    0.05
1,2-Dichloroethane-d
Benzene-d
Toluene-d
                                           0.267
                                           0.271
                                           0.281
                                                               5.07
                                                               5-05
                                                               7.46
                                                                                                     107
                                                                                                     108
                                                                                                     112
Reviewed by
                   "TL>3
                                    Date
                                         1
                        NA- Not Applicable; Det. Limit Detection Limit; Quan. Limit: Quantiution Limit
    IS; Internal Standard; U: Undetected; 3:Tnsent In Blank; J: Estimated- Below Quantitation Limit; E Estimated- Above Calibration Range
Triangle Laboratories of KTP, Inc
801 Capitola Drive » Durham, North Carolira 27713
Phone: (919) 544-5729 • Fax (919) 544-5491
                                                                                                  Savar v3.5
                                                                                       Printed: 15:04 07/22/1997
                                                                                                   6ul
-------
Project Number: 42284
Sample File:     H5374
Method 8240A
Sample ID:
      VOST-4 SET 3 TUBEA/B T/TC
Client Project,
TLIID:

S407-003
173-46-18A,B


Dilution Factor:
Date Received:
Date Analyzed:
1.00
06/30/97
07/09/97

                             Tentatively identified Compounds
         Name
 Area
IS RT     IS Area
Amount. UQ
   Unknown
   Methyl Propane Isomer
   Methylbutane Isomer
   C4H8 Isomer
   Pentane
   C5H8 Isomer
   C8H16 Isomer
   C6H12 Isomer
   C7H14 Isomer
   Tetrahydrodimethyl Pyranone Isorner   4,080
0,711
0.821
1.600
1.001
1.910
2,160
7.781
3.431
5.411
4,080
23335034
15791845
10170422
9320503
6837718
5955569
12139416
5206325
4149131
3389451
4.471
4.471
4.471
4.471
4.471
4.471
9.731
4.471
4.471
4.471
5102518
5102518
5102518
5102518
5102518
5102518
11891588
5102518
5102518
5102518
                                      1.143
                                      0.774
                                      0.498
                                      0.457
                                      0335
                                      0292
                                      0255
                                      0.255
                                      0203
                                      0.166
Triangle Laboratories, Inc.
801 Capitok Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 * Fax: (919) 544-5491
                      Printed:   10:26  07/25/97
                                                                                     602
-------
                                                                                        en
                                                                                        o
                                                                                        CD
n7-M9-97  17=14         Triangle Laboratories of  RTF,  Inc.
SanpJe: VOST-4 SET 3 TUBEA/B   T/TC   173-46-18A/B   TL1*42284
(919) 544-5729
  Instrument H
H8374

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1
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12
13
14
15
16
17
18
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24
25
26
28
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33
34
35
36
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40
41
42
43
44
45
46
47
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49
50
100
100
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89
91
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92
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3
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5
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4
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0
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0
7
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. 0 7
. O S
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•"•,*"*
.40
,52
.OO
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.46
.53
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.93
.00
«r"HO
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,52
,OO
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1 •-.• -"-.'
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114
1 1 7
6'i
84
98
O w
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93
50

94
64
1O6
101
96
142
76
43
76
84
96
73
53
57
63
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96
83
62
57
43
72
97
117
78
13O
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69
83
75
75
97
129
_O7
173
4~z
92
164
Bromoc iiioroiiiir ri >.-, ivt-
.1 -, 4 — O '. 1 U O 1 O b W 1 1 ,- ••- ! i :"
Chlor cben.;:ene-'13
1 .. 2-D ichioi-oe'chs, i-.«- <.\4
Ocnzene-do
Toiuarid'-dS --^
4— Hroiiof 1 uor oben^ene
Chloroicethane
^iny^ L,n ur ideg^aTAA
0 r ornome thane
Chloroethancs
Vinyl bromide
Trlchlorotl uorotnetharu::
1 ., 1-Oi cnloroe thene
Iccloniethane
Carbon disulfide
Acetons S—SZ-- ~\
Allyl chlorids^^TLO
Methylsne chloride
trans-1 ,2-Oichloroetiiane
tert-Butyl methyl ef^JTL*
Acryloni tri le —
n— Hexane
1 , 1-Oichloroethane ->.
1 , 2 £poxybuta n ©/^ojy \jJ
cis-l,2-0ichloroetnene
Chloroform
1 , 2-0 le h 1 or oe thane
Isooctane \
Vinyl acetate(@TJlyO
2-Butanone
1 , 1 ,1-Tr ichloroethane
Carbcn tatrachloride
Benzene
Trichloroethene ^
1,^. C Ich loropropaneV^SVl,
Ethyl acrylate J*3-J
Methyl methacrylate
Bromodichloroms thane
cis— 1 , 3-Dichloropr opens
trans-1, 3-Dichloropropen
1 , 1 , 2- f r i c h 1 o r oe t ha ne
Qibronnochloromethane
Ethylene di bromide
Bromoform x
4 ^Mot iiy 1 ~~ ^ pe nta no ny^iAj ^/s.
Tol uene
Tetrachloroethene
Data Review: 710
Date:  7 -
                                                   604
-------
MAT FOR REV Da It.
Area  P,Flags
RT
QM Name

52
55
54
55
So
i- ~.

58

54
IOO
IOO
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56

21
85
86
81
91
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70
98
94
88
97
-i x

64
1
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0
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74224
20*5779
1019O96
419692
227OO84
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bb
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bv
bv
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11
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83
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C h 1 o f o b e n <: e r i a
Ethylb
-------
CO
o
CD
87-89-97 17:14 Triangle Laboratories of BfP, Inc. (919) 544-5729
HS31
Je; UOSI-4 SET 3 T/fC 173-46-18A/B Instrument ii
S4 91 (6,916)
i(lf, 64 ' 121856
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fl-
48

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8 .160 150 280 250 3BB 350
ti8374'91 (8,911)
1BO!
XFS-
0-
5

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0 49152
52
i
i
56 186 158 260 256 36B 356
fecrtA «J CH.93f!} CliioroMethane FIND


P,

44
er
-J*
3 160
52

0 18O 15B 288 250 380 35O











-------
                     o
                     to
89-Jul-9? 1?:14         Triangle Laboratories of BIP, Inc.
Sample: VQST-4 SET 3 TUBEft/B  T/TC  173-46-18A/B  ILItt42284
(919) 544-5729
  Instrument H
HS3I74 106 (1.868)
1OCI
xFS;

Cl-
3


4
9 5
5B
\
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159744
4


...V

M/Z 50 100 150 200 250 300 350
HS374'106 (1.061) REFINE
f,4 136192
icio-
XI 'S-
Cl
39


30






n/'z 50 100 150 200 250 300 350
HfrStER 11 (1.448) 1,3-Butadiene FIND
to 103
If 101

XF'S
W-





3
50


«*



n/'z; 50 100 150 200 250 300 350
-------
                    oo
                    to
87 89-97  17 ;M-         Ir-iangle Laboratories of  RTF,  Inc.
Sample: iJPST-4 SET  3          T/TC   173-46-18A/1I   TLIft42284
(919) 544-5729
  Instrument H
HS374 148 (1.480)
Art
1601
: 9
XFS -
j 48 64 93
J .... \5? ¥ J
M/Z 56
KS374*i48 (1.481)
« ,-s^-i _ 9
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1 ^46 p. "-
j .-* Q / €r JL
»-"s 58
18432
4
ISe 158 208 258 3i8 356
REFINE
1 9728
'
ISS 158 288 256 388 358
Broaonetiiane FIND
108 158 268 258 386 358
-------
                     CD
                     CD
!_-j?y  17:14          Ti-iajigle Laboratories of RIP, Inc.
e: UOST-i SET  3 IUBEA/B  T/TC  173-46-18A/B  TLIM2284
(919) 544-5729
  Instrument If
152 (1.526)
108"
>;FS -
Q
pt/2
44 64 15196
, 48
I '»
!«
.!S,_^J_i_

78
ill
SB 150 200 258 360 350
IHS374"2 152 (1,521) REFINE
64 5312
ibOi
j
"XFS -
„ ,?-
t GP-
^.«^l^
•
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66
5§ 1GQ 15B 200 250 308 350
ttA 13 (1.548) Chloroethane FIND
6
j* Q
^2 — f. ~*3
4 168
66
58 168 150 200 250 300 350
-------
                                                                                         o
                                                                                         »H
                                                                                         CD
U7-tf3-S*f  IV'14          triangle Laboratories of RTPj  Inc.
Sample: MOSf-4 SE1  3          T/TC  173-46-18A/B  TLIJI42284
(919) 544-5729
  Instrument H
118374 188 
-------
                                                                                      CD
87-89-97  I/:14         Triangle Laboratories of HTP, Inc.
Sanple: UQST-4  SET 3 TOBEA/B  T/TC  173~46~18A/B  TLItt42Z84
(919) 544-5729
  Instrument H
246 (2.468)
7
XFS -
H/Z

44 _
6

78
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50 168 15B 208 250 308
(2.461)
1601 '
1
B-
M/Z
44
i 53 «,*
6
78
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L . . ....
56 100 150 200 250 300
HT2CAA 18 (2.588) Carbon disulf ide
100] 7
XFS-
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, T
6

78
M/Z 58 ' IBS ' 150 ' ' ' ' " 200 ' ' 250 ' 30O

622592


350

6103G4

350
FIND
100


358
-------
                                                                                       CM
                                                                                       «H
                                                                                       CJD
07 85-97  17; 14          Triangle Laboratories of RIP,  Inc.
Sample: UQST-4 SET 3           T/TC  173-46-18ft/B
       253  (2,536)"
1.™          76
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     43
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                                                                   (919) 544-5729
                                                                     Instrument H
                                                                           15744
                        see
                       358
IHS3?4'253  (2.531)
X.FS
  8-
m/z
         58
       58
                  186
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260
 50
363
                                                                            6912
358
NT2CAA  19  (2. WO)   AcetnTO
  9-
s/s
       --53
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                  106
150
2C38
258
3Q8
                                                                            FIND
                                                                             lee
350
-------
                                                                                       CD
07-B9-97  17:14         Triangle Laboratories of ETP,  hie.         (919)  544-5729
    Ie: WST-4 SET 3 TUBEA/B  T/TC  173-46-18A/B  TLIJH2284
IS3'

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93 (2.93:
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51
55
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21 (2,97t
9

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51
83
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536576

4

88


, .1, , ( - -, ,

180 150 200 258 308 350
L)
524288

4

88
.1.

100 150 200 250 300 358
3) Methylene chloride FIND
108

i

88
.-
.1
[*•* | • < * 'I*' •l|""«"JI"»'--|ll'FJ-W..|...i|l'. "| •-.-(
189 158 20O 250 300 350
-------
                                                                                       CO
07-69-97  17:14          Triable  Laboratories of RTP,  Inc.
Sanple:                        f/IC   173-46-1BA/B
<919) 544-5729
             H
: in -•""k*"! J j-% Jfjj-fc j" -— | J-i rt|Tt 't
i!aJf4 Jii l3»2i8jl
5:1 55552
I £."= tri 1
i
1 .
n 1.,ii i ..
5V
.„?!
H/Z 58 ' 168 ' 158 ' 268 ' 258 ' 386 ' 358
41
ra ,i!i .1 ,.
S2 (3 = 221)
3 51968
i 57
i f,'
1 !. 67.
«/2 58 ' 100 ' 150 " ' " 288 ' 258 ' " 300 ' 350
=!T7(~pf.'l '
- .j - — 5
: 5A
XFS-
3R
P : = ii -!,-.<
.4 (3.278) Acrylonitrile FIND
3 ise
i
IH/S 56 ' 188 ' ' 15B ' ' ' ' ' 258 ' 38S ' 358
-------
87-69-
M374
188-j
\ &.
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H/S
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M/Z
-97 17:14 Triangle Laboratories of KIP, hie, (919) 544~5729
,: UOST-4 SET 3 I/1C 173-46-18A/B ILI»42284 Instrupient H
352 (3.520)
57 " 286720
™ _ 1
36
1
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1 •---? ! 3b Q£
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i 	 ..si.. 	 :.if ,!.
50 168 158 288 258 388 358
'352 (3.521)
57 262144
3
56
55|58?1 86
58 1B0 150 200 250 300 350
} 25 (3.578) n-Hexane FIND
57 100
56
_
"•E " '• ft f^
\ ; sr? * d= O
58 188 158 260 258 3O0 358
m
CP






-------
                     CO

                     CO
tf? 89 9r"   17 ;M         Triangle Laboratories of I? IF,  hie.
^anpie:         SET 3           T/TC  173-46-18ft/B  TLHt42284
       02& (5,261)
jiiiQ-j    5,7
!
 (919)  S44-5729
   Itistrunent H
          31232
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_
56
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58
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56
! *.?. , 99
1B8 150 288 258 338 356
t (5.261) REFINE
7 1S268
188 150 208 250 380 350
. (5.291) Teooctane FIND
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• 58
99
                                            260
256
368
-------
                                                                                       CD
09-Jul-97 17:14          Triangle Laboratories of RTF, Inc.
Sample: VOST-4 SET 3 TUBEA/B  T/TC  173-46-18A/B  TLI»42284
(919) 544-5729
  Instrument H
HS374 436
100

0
M/Z
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(4.360)


4096
55
/
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50
HS374'436
180-
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100
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50
100 ' 150
(4.361) REFINE


f 7 O n j*
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100 150
(5.150) 2-Butanone


T
100 150
200 ' 250 ' 300 ' 350

3120


200 250 300 350
FIHD
100


200 ' 250 ' 300 ' 350
-------
                   oo
                   *H
                   CD
1.7 = rt          Triangle Laboratories of KfP,  Inc.
•ST-4 SEI  3          T/TC  173-46-18ft/B  1L1142284
(919) 544-5729
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1 00 158 258 388 350
31) Benzene FlNb
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3: UOSf-4 SET 3 f/TC 173-46-18A/B ILIi42284 Instriment H
645 (6,451)
d 8512
55 69 81
,! 96 *08
li ifhlu ,1, il.i , ij
58 183 150 280 258 380 358
EM5 (6.451) REFINE
1 &9 2488
71 i?8
42 59 / 85 J
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56 10S 158 268 250 300 358
A 48 (6.491) nsttecrylate FIND
168
69
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58 189 158 280 250 388 358
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9? QJ 37 If :14 Triangle Laboratories of RIP, Inc.
Sample: UOST-4 SET 3 T/1C 173-46- 18A/B IL If 42284
un-Tj/j ntr f ri 1-1-4 \
TiiixJ I 1 i DO If, 331 i
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49 (7,601) loiwens
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(91.9) 544-5729
Instrument H

843776






359

765952






363 350
FIND
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3O8 350


























-------
                                                                                      CM
                                                                                      CD
87-09-97  17:14
Sanple: UOSI-4 SET
   Triangle Laboratories of RIP, Inc.
TUBEA/B  T/IC  173-46-18A/B  TLI*42284
(919) 544-5729
  Instrument H
HS374 978 (3,781)
ian H7 123904
XFS- 119
r - _ _. j™ .,
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48 ! 57 m 112
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114
M/Z 50 100 15B 206 258 308 350
52 (9.841) Chi
189] i-
77
51 74
orobenzene FIND
.2 100
114
w/z 50 100 ' 150 ' 200 ' 250 ' mm ' ' 358
-------



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1 167528
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95 1 187
183 156 2OQ 25S 368 350
1)
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198 158 268 258 3B3 358
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150 288 250 S69 359
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67^09-97  17:14         Triangle Laboratories of IIP,  Inc.
Saaple:  U08T-4 SET 3          T/TC  173-46-18A/B   TLK42284
(919) 544-5729
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1838 (18.38
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15B 258 388 358
-------


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9 97 17:14
]^: 1/05? T 	 4 SE

Triangle Laboratories of RIP, Inc. (919) 544-5729
F 3 TUBEA/B T/TC 173-46- 18A/B TLJ»42284 Instrument H
HS374 1108 Ui.fiBl)
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58 iee 150 200 250 300 350
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106
58 168 158 268 258 383 338








-------
                                                                               CQ
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1105 (11.851)
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108 158 280 258 388 356
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104 160
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                                                                                      CD
                                                                                      cvr
                                                                                      CD
W7-R9-97  17:14          Triangle Laboratories of  KIP,  Inc,
K^pie: UOST-4 SET 3           T/TC  173-46-18A/B
(919) S44-5729
  Instrument H
JHS374 11/8 (11.781)
lino,4,1 J£
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128
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15 186
128
1 158 268 258 38B 350
-------
                                                                                    CD
B9-Jul-97 17:14         Triangle Laboratories of RIP, Inc.
Sample:  VOST-4 SET 3 TUBEA/B  T/TC  173-46-18A/B  TLI*42284
(919) 544-5729
  Instrument H
HS31
100-
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60 1654784
41
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39
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F:440 609:2-1
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REFINE NBS 49 Hits : 49 Searched
60 1605632
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f42 555760 72 85 /*
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09-Jul-97 17:14          Triangle  Laboratories of RIP,  Inc.
Sample: MOST-4 SET 3 TUBEA/B   T/TC  173-46-18A/B   TLI»42284
(919) 544-5729
  Instrument H
HS374 82
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81 155:l,3-C¥CLOPENTA0IENE
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4 1425408
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                                                                                   00
                                                                                   CD
89-Ju1-97 17:14          Triangle  Laboratories  of  RTF,  Inc.
Sample: UQSf-4 SEI 3 TUBEA/B   T/TC   173-46-18A/B   1LI1J42284
(919) 544-5729
  Instrument H
HS374 100 (1.080)
100T4!1
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HS374J180 (1.001) REFINE HBS 58 Hits : 58 Searched
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57
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    17:14         Triangle  Laboratories of RIP,  Inc.
UOST--4 SET 3  TUBEft/B   T/TC  173-46-18A/B  TLJM2284
(919) 544-5729
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w/WW 17:14 Triangle Laboratories of RIP, Inc. (919)
:;,^j]c: VQST-4 SET 3 T/TC 173-46- 18A/B TL I 842284 Instr
HS.f '4 770 (7,701)
I sT If?
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-------
                CO
                CD
89-Ju1-97 17:14         Triangle Laboratories of RTF,  Inc.
Sample: WST-4 SET 3 TUBEA/B   T/TC   173-46-18A/B  TLI842284
(919) 544-5729
  Instrument H
HS3<
100
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mm
180
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0
HI
100-
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tt2
1O0
XFS
0.
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1001
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0,
M/Z
'4 343 (3.438)
Vf
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150528
50 ' 100 ' 150 ' 200 ' 258 ' 300 ' 350
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F5826 4288:2H-PVRflN-2-C
39h« 5
F:821 559:CVCLOHEXANE
39 4A 55s
20 30 40
NBS 61 Hits : 61 Searched
6 83968
"s? T
. ' ' 255
T "^
NE § T ET J\H H V IrRO""5 / &~l/I N£T Hz ij"" / TJRHrlS w
6 255
57 69 „.,
t 6(7/ 8|4
6 255
84
57 67^9 83J85
' 50 ' 60 ' 70 ' 80 ' 90 ' 100 ' 110 ' 120 ' 130
-------
                                                                                   in
                                                                                   co
                                                                                   CD
09-Ju1-97 17:14         Triangle Laboratories of RfP,  Inc.
Sanple: UOST-4 SET 3 TUBEA/B  T/TC  173-46-18A/B  TL1842284
(919) 544-5729
  Instrument H
HS3i
XFS-
W/2
HS37
180"
0-
M 541 (5.411)
43 I 57?0
50 188
'4J541 (5.411) REFINE
3


4
9
i


f
97288
158 • 2g0 , ^^^ , ^^ , ^^
HBS 37 Hits : 37 Searched
42 56 ?3728
X43 54 1 57 68 70
/ Sl^llf M 83 9,8
#1 FI868 1187:CYCLOPENlftNI, 1,2-DIMEI
1 nn 4142 x
*FS 27 X29 39|yr43 53X
01 .1.1. . , 1 . I 1 1 . . , . . /S ,
#2
100-
XFS-
0;
#3
100
XFS-
0;
F:828 1195:CYCLOHEPfftNl
4\
29
27 ( 39
| » 1' V'U 1 J 1 « 1 1 1 1 1 J III!
Z
..,.,..,..,,
42 55N
43 53
I 	 SI
'F:824 i225:CYCLOPENIftNE, i,2-l)IHEl
555
^r1 x
27 19 39TJ42 „
n/z 10 28 30 48
'HYL-
16 *« C7H14 255
fty*jn
f- w% 1 **
J i lit i i iM (\ \ t t r t i 1 i t i i i i i 1 t
56 ' ' ' 'C7Hi4 '
/ 78 i55
^ 676|f| 71 8283 98
h i , ,,) \\\{ •, ,,,^ r?4 , ,,, r"
1 II | 1 1 1 I | 1 1 1 1 | • I I 1 | 1 1 1 1 | 1 1 1 | . 1 • » | 1 • . . | 1 1 1 1 | , "I 1 T | . 1
'HYL-, IBANS- T7U1A
,6 urni.1 ggg
,-, 6978
/ ^ 71 „« 98
{ 67 / 83 T
• • 1 • • • • I 	 i • * ' • 1 	 • • I • • • ' I • • • 1 • • • • 1 • ' ' • 1 • • • • | • • ' ' I • '
58 60 78 88 98 188
-------
                                                                                         CO
                                                                                         CO
                                                                                         CO
           17:14
                           Triangle Laboratories of  RTF,  Inn.
                      TIJBEjVB  T/TC   173-46 IBft/B   TL 1842284
                                  (919) nIHETHVL-, TRANS
                Sf.                                                                255
                                                                      C7H1Z02
              50
                        jeo
158
280
259
see
350 i
-------
Project Number: 42284
Sample File: HS375
                       Method 8240A VOST
Sample ID: VOST-4 SET 4 TUBEA/B T/TC


Bromochloromethane
Chloromethane
Vinyl Chloride
1,3-Butadkne
Bromomethane
Chloroethane
Vinyl bromide
Trichlorofluoromethane
1 , 1 -Dichloroethene
lodomethane
Carbon disulfide
Acetone
AUyl chloride
Methylenc chloride
trans-1 ,2- Dichloroethene
tert- Butyl methyl ether
Acrylonitrile
n-Hexane
1 , 1 -Dichloroethane
1 ,2-Epoxybutane
cb- 1 ,2- DiAloroethcne
Chloroform
1 ,2-Dichloroethanc
Isooctane
1 ,4-Difluorobenzene
Vinyl acetate


0.209

0.259
0.017
0.235

0.025


0.511
0.041

0.070


0.816
0.114









IS1

U

J

U
J
U
U

BJ
U
B
U
U


U
U
U
U
U
U
IS 2
U

4.47
0.92

1,08
1.41
1.54

1.81


2.48
2.55

2.95


3.23
3-53






5.63

iii


0.001



0.001

0.001
0.001


0.001

0.001
0.001


0.001
0.003
0.001
0.001
0.001
0.001

0.001


0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0,05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05

0.05
                         NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
    IS: Internal Standard; U: Undetected; B: Present In Blank; J; Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 « Fax- (919) 544-5491
                                        Savar v3.5
                            Printed: 15:04 07/22/1997
                                                                                                     637
-------
                                    ;-:ltelie:ift
Project Mumben 42284
Sample File: HS375
                      Method 8240A VOST
Sample ID: VOST-4 SET 4 TUBEA/B T/TC


%
•-: .•%
||l|i|||ii§p|§::|i|i|iSi


2-Butanone
1,1,1 -Trichloroethanc
Carbon tetrachloride
Benzene
Trichlorocdienc
1 ,2-DkhIoropropane
Ethyl acryktc
Methyl methacrylate
Bromodichloromcthane
cis-1 ,3-Dichloropropenc
trans- 13-Dichloropropenc
1 , 1 ,2-Trichloroethane
Dibromochloromechane
Ethykne dibromide
Bromoform
Chlorobenzene-d
5
4-M«hyl-2-penianone
Toluene
Tetrachlorocthene
2-Hexanone
Chlorobenzene
Ethylbenzene
nWp-Xylene
o-Xylenc
Styrene
1 ,1 ,Z2-Tetra£hIoroethane

0.023 J
U
U
1.205 BE
U
U
U
0.020 J
U
U
U
U
U
U
U
IS 3

U
0.428 B
U
U
0.007 J
0.061
0.149
0.062
0.199
U

4.34


5.10



6.45







9.74


7.56


9.79
10.07
10.30
11.01
11.06



0.001
0.001

0.001
0.001
0.001

0.001
0.001
0.001
0.001
0.001
0.001
0.001


0.001

0.001
0.001





0.001

0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05


0.05
0.05
0.05
0.05
0.05
0.05
0.10
0.05
0.05
0.05
                        NA- Not Applicable; Det. Limit: Detection Limit; Quan. Limit: Qiuntitation Limit
    IS: Internal Standard; U: Undetected; B; Present In Blank; I: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capital* Drive • Durham, Nor* Carolina 27713
Phone: (919) 544-5729 • FaK (919) 544-5491
                                       Savar v3.5
                           Printed: 15:04 07/22/1997
                                                                                                     638
-------
                                    Pacific Environmental Services
Project Number 42284                                                           Method 8240A VOST
Sample File: HS375                                        Sample ID: VOST-4 SET 4 TUBEA/B T/TC
Client Project S4Q7-003
JU ID: 173^6*19 A/B


&nalyfe:;:';- ^ . : 	 '. -"f^L-.^t-
Date Received: 06/30/97 Response FiksICAXHTQS
Date Analyzed; 07/09/97


"• ^ l:^:| f*0 ,< :, !;«', .P*|^ :? :?#>. W**:
Cumene                                      0.004  J            11.78                                  0.05
Surrogate Stimmary .;! ;.•; •
1 ,2-Dichloroethane-d
4
Bcnzcne-d
6
Toluene-d
V., > .Amount' ''•''>. • '
.''.*• --\::;"fagi>.r::" :
0.248
0.270
0.289
— ar-:; /;;i
5.07
5.05
7.47
Srltel- -• -
1
2
3
%KBC .1
99
108
116
 Reviewed by.
                        NA- Not Applicable; Dot Limit: Detection Limit; Quart. Limit Quantitation Limit
    IS: Internal Standard; U: Undetected; B: Present In Blank;); Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range

Triangle Laboratories of RTF, Inc                                                                           Savar v3.5
801 Capitola Drive • Durham, North Carolina 27713                                                   Printed-15:04 07/22/1997
Phone: (919) 544-5729 • Fax: (919) 544-5491

                                                                                                     639
-------
Project Number:  42284                     Method 8240A
Sample File:     HS375                     Sample ID:        VOST-4 SET4TUBEA/BT/TC
Client Project:
TLIID:

S407-003
173-46-19A3
Dilution Factor:
Date Received:
Date Analyzed:
1.00
06/30/97
07/09/97

                            Tentatively Identified Compounds
t Name ,
Unknown
Sulfur Dioxide
C4H8 Isomer
C5H10 Isomer
C6H12 Isomer
C8H16 Isomer
C5H8 Isomer
C9H18 Isomer
C7H14 Isomer
Octane
FTT '
0.711
0.841
1.011
1.870
3.441
7.791
2.180
10.471
5.421
7.941
Area
41059792
16206607
10696607
8357539
7794570
11798414
5956399
8088882
6596451
6027441
ISRT
4.481
4.481
4.481
4.481
4.481
9.741
4.481
9.741
5.631
9.741
IS Area Anwunt.ua j
6871537
6871537
6871537
6871537
6871537
11533643
6871537
11533643
10181564
11533643
1.494
0.590
0389
0304
0284
0256
0.217
0.175
0.162
0.131
Triangle Laboratories, Inc.
801 Capitola Drive * Durham, North Carolina 27713                          Printed:  10:26  07/25/97
Phone: (919) 544-5729 * Fax: (919) 544-5191
                                                                                 640
-------
                    CD
         1H;02         Triangle Laboratories of RTF,  Inc.
,nPIe:  WSI-4 SET 4 TUBEft/B 'T/TC   173-4G-19A/B   TLI#42284
(919) 544-5729
  Instrunent H
!llS3rb /

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-------
hi.'lR REV Delta
-
4
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0
3
9
:*"'
12
.13
14
IS
16
17
IS
19
21
22
23
24
25
26
28
29
3O


33
34
35
36
T~

40
41
42
43
44
45
46
47
49
c/-.
LOO
100
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100
S'C
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68
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72
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74
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55
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70
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94
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69
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29.55o££
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679844
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111684
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5002344
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212284
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545127
S27G24
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8672
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14473840
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45826
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3795340
-"""if'
°J V
!."> V
bv
bv
vv
bv

bb
A

bb


bv
bv
bv


bv
bv




rt

ft


bv
A
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bv
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5
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c
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.00
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,-?<-
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117
•'•> .'::
34
•?S
:'.t !;%
50
I-OK ;::
94
64
106
101
96
_42
76
43
84
96
73
S3
57
63
96
83
62
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72
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117
78
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69
83
75
75
97
129
107
173
92
1 <^d
;;r:.:>ir,ocli !..,;: .-. niic- 1 i io n::
_ - 4-OX i:1. ilr-f-/;.'.--!!-;:.-:; •
C 1 i Oi 'O: ;•:.:;:! '*ne— (J i
i . 2-0 i'.eh ioroetiiane -•.!••.-
menzsne-'Ju

4-Brcmof luorobs'"ze:i^
Chioromethane ^^^~ \

Brotnomethane
Chlorcethane
Vinyl, bromide
T r ieh loro" I uoronne~ri£.rie
1,1-0 i c h 1 o r oat he na
lodome^hane
Carbon dlsulflde
Acetone *-**^-\ ^
Hethylene chloride
trans -1,2-Oichl sroetrhents
tcrt-3utyl methyl ether
Aery Ijnitr rile
n-Hexsne
1.,1-Dichloroethane
cis-l»2-0ichloroethene
Chlorof orm
1,2-Oichloroe thane
Vinyl" aceta1^{Q*J/l^_J
2-Butanone
1,.1.1-Trichloroethane
Carbon tetrachloride
Benzene
\ -^»y-— ,
Frhv/acrvlat^0^-^^^
Methyl methacrylata
Brornodi chloromethane
cis-1 ,3-Oichloropropene
trans-1 ,3-Dichloroproper
1 , 1 ., 2-T i' i chlorcethane
0 i b r ornoc h 1 o r orne t ha ne
Ethylens dibromide
Bromo~orm ^r~w-^
Toluene
Tta-f*;- nr-h 1 iiro^t'hpi nr-/fc3TT"~i
               Data
                                                          642
-------
   MAT  FOR REV De.l.tr.
         QM

32 ••;,.•:!
bo 100
'54 100
55 .100
56 100

22
36
36
79
91

69
98
94
35
97

1 36
0 373
-1 11 -'!0
1 451

092 bb
381 bv
734 vv
48--" bv
1 2401667 bV


10
10
11
11

. 7"<
. O7
.. oO
.01
,. O6


1O6
1O6
106
104
R3
i
Ohio
I thy
:IV-/p
o-Xy
3 'C y r
i _ ; _

r
1
-
1
i"*


b

f-~«
n
^>TT.J
b'inz^
enzene
V i •::: i I'cJ
n e
5 T«f.rflnhl0i/^
53
           67
                  O
                       1O4289  bv
11.78   10 5  C LI i n e n e
                                                                   643
-------
                                                                                        CD
Ui'-Hj-'J?   1.9-02         Triangle  Labor-ataxies of RTPj Inc.
farwle:         SET 4 TUiEft^B   T/TC   173-46-19ft/B
]!S37h  92  (8 = 4211}
   B
    -.JJi <-
                               150
                                                        250
!!S37!3'92 (B.921I
IBM-   5B
                               150
                                           268
25O
             __
    AH 9  (8.93i)   Chi or owe thane
iae
f! ,'1
  z
  11
  5P:
                                                       258
                                                                    (919) 544-5729
                                                                      Instrunent H
            300
                                                               388
                                                                    38i
                                                                            142336
                                                                          358
                                                                             88064
350
                                                                              FIND
                                                                               1IJ0
                       358
-------
                                                                                        in
                                                                                        ^f
                                                                                        CD
89-Ju1-97 18:02         Triangle Laboratories of RIP,  Inc.
Sample: UQST-4 SET 4 TUBEA/B  T/TC  173-46-19A/B  TLItt42284
(919) 544-5729
  Instrument H
HS375 108 (1.880)
100-
XFS-
0-
tt/Z
3

9
50
,ul, ll|li
5C
212992
>4
(.I.,.!,. , L -i- i r- 1 J i 1 1- 1 I I
» ' 100 ' 150 ' 200 ' 250 ' 300 ' 350
HS375J108 (1.081) BEFINE
100
XFS-
0
W/2


4
5
39
50
\
5t
4 183296


» 100 150 200 253 300 350
MASTER 11 (1.448) 1,3-Butadiene FIND
100
XFS-
0
M/Z
3

9
5
58
\
5£
100
4

! ' 100 ' ^Q , ^^ ...,,. .^^ , ^^ , ^^
-------
                    CD
                    *3-(
                    CD
H7-89-97  18:82          irtangle Laboratories of BTP,  Inc.
Sample: MOST-4 SET 4          ^f/TC  173-46-19A/B  TLIf42284
(919) 544-5729
  Instriinent H
! it-- r
no j i
i 1 f3 g -
XFS-


i • t'. "

189-


•M jr ~
HT2C
JLBO-

v.FS-
;s -* ,<*
"lj
*^




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'Ofl


48

141 U. 4 IB)
tJt
t
43 64 93
(5.5 | 7t? J
f . , . . | t
•s.? ^f?
141 (1.411)
9-

93

12 (1.428)
9-

93
58

1632O
4


ieir 15B 200 258 369 350
REFINE
* 966S


tee 156 268 256 368 359
BroMowet haiie F I HD
i iee


S.88 158 268 25© 368 350
-------
                                                                                      CD
                       Triangle Laboratories of IIP,  Inc.
ample:  UOST-4  SET 4 TIJBEA/B  T/TC  173-46-19A/B   TL1842284
(919) 544-5729
  Instrument H
154 (1.548)
1801
..J


0-r-
44 *•
48
'55
lit !l, ri | ,
4 13952

66
i i
58 180 156 288 250 308 358
(1,541)
100-
"FS"
c - - "•• i
i
et
H/Z
iNIZCt
5 21 f"| ™
JLBB ,
XF8-
S-U:
H/Z
6

4963
i
4 5128
66
I

58 160 158 203 258 388 358
m 13 (1.548) Chloroethane FIND
6

A a
53
-3,i .!i'i
4 1@3
66
j
se iee isa 100 250 see 350
-------
                                                                                  oo
                                                                                  *c«
                                                                                  to
9-5?  !B:tJ2          Triangle Laboratories of RTF, Inc.
le: UOSf-4 SET 4  TUBEA/B  T/IC  173-46-1WB  TL1*42284
(919)  544-5729

  Instrument if
I1K375 181 (1.810)
1001 4ia
, [ Si 1<
"FS1ij|l 79
MM
' P 1 i >!| no
o li'iiiil iiu-L. .,.;'!!,. . °ff,
s^/s 50 1 ii
!1S375J181 Ci.Bli") "l
i &
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1
XFS '
j 47 6^ „
0 J. J Bf? . ,
M/-Z 58 iw
15 (1.848) 1
..,». .i.e
».%3S3
•/•ire- -.
"'"i35
J: ^ t 8i
H/25 58 16
19968
»1
165
i
S 156 206 256 368 359
1EFINE
11 13632
183
185
|
8 150 2©8 250 303 359
Vichlorof luoronethane FIND
it iee
163
105
.' It?
8 158 268 256 388 358
-------
                                                                                        CD
                                                                                        «5J«
                                                                                        CD
HV-09-97  18:62         Triangle Laboratories of  HIP,  Inc.
Sample:  WST-4 SET 4          T/TC   173-4&-1WB   TL!ft42284
(919) 544-5729
             H
|HS3Vb 248 (2.488)
IBB-
-
a.
i — ~ *•*
| ?
ji^j
6 937984
78
.L . ,. 	
58 160 158 288 258 388 350
C2.481)
ise-
X.FS-
R-
M/ Z
f

54
6 925696

78
j.. ... ..
58 108 156 288 258 300 358
HKCflft 18 C2.5BB) Carbon disulf ide FIND
1BB]
XFS"
i-
M/Z

44
, "1"
6 138

78
I
58 188 15i 280 258 308 358
-------
                                                                                       o
                                                                                       in
                                                                                       CD
07-69-97  18:82
                         Triangle Laboratories of  RIP,  Inc.
       ; UOST-4 SET 4  TUBJSA/B  T/TC  173-48- 19A/B   TLItt42284
       25B (2,550)
       59
                  100
158
269
250
                                    (919) 544-5729
                                      Instrument H
363
                                                                           15552
356
HH375
           (2. 551)
         58
                  160
                              158
            288
            25S
            see
                                                                             872
           353
1WT2CAH  19  (2.578)
 	  4:1
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                  188
                              150
            283
            250
            300
                                                                            FIND
                                                                             168
           358
-------


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150 280 258 300 356
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                                                                                           CM
                                                                                           IO
 r*_gg_37   1K:02          fr-iaiiyle Laboratories of RTF.  Inc.
5a»ple:         SET 4          ' T/TC   1Y3-4&-1WB
MS375  323 (3.238)
    14.1
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15B
289
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                                      (919) 544-5729
                                        instrument H
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280
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                                                               308
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        24 (3,278)  Acrulonitrile
1 liM-i
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-------
                                                                                      CO
                                                                                      10
                                                                                      CO
BY-M9-W                Triangle Laboratories of RfP, Inc.
Sawle:        SET 4 lUBEft/B  I/IC  173-46-19A/B  TLIM2Z84
C919) 544-5729
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isionrFr" \jt~t «*} C-~s£i i
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15B 280 258 308 358
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58?1 86
58 158 208 256 388 356
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                                                                                      in
09-Jul-97 18:82         Triangle Laboratories of RTF, Inc.
Sanple: UQST-4 SEI 4 TUBEA/B  I/IC  173-4&-19A/B  !Utt42284
                                                                 (919) 544-5729
                                                                   Instrument H
HS375 436  (4.360)
     43
1001
XFS
  0
n/z
                                                                           4992
        54
          6
               84
                  100
150
200
250
300
35B
HS375M36 (4.361)  REFINE
     /IO
100
                                                                           3264
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  0
        55
         j   F
                  180
                              ISO
            200
            250
           300
           350
MASTER 35  (5.15B)  2-Butanone
1001 43
                                                                           FIND
                                                                            100
XFS
        5.7
           1
       50
                  100
150
200
250
3QC
350
-------
                   ID
                   in
                   CO
                        Triangle Laboratories of BTP, Inc.
Sawle:  WST-4  SET 4 TUBEA/B  T/TC  173-46-1WB  TLIM2284
(919) 544-5729
  Instrument H
518 (5.181)
18B- 7
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o ' I • i'i "'"'": i
8

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2097152


250 300 350
1998848

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FIND
108




250 388 358
-------
                                                                                     CO
                                                                                    •JO
                                                                                     CO
--
                       frfangle Laboratories of MF, Inn,
   e: UOST-4 SET 4  1UMA/B  f/lC  173-46- 19A/B  TLItt42284
(919) 544-5729
  Instrument H
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                                                                             CD
W7-89--97
              Triangle Laboratories of RTF,  Inc.
ST-4 SET 4 IUBEA/B  T/TC   173-4&-1WB   TLI«42284
(919) 544-5729
  Instrument H
756 (7.561)
10-31 9
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; 39 n
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93
s*/z 58 ' 100 ' 150
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1 881 9
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IH/Z 5B ' ' 150
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843776


280 258 386 350

765952



20e 259 388 350
FIND
100



280 258 300 350
-------
                                                                                            CO
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*3~ J i ^f 1  s"j**?
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:  IJOST-4 SET  4  TUBEiVB   T/IC  173-46-19A/B   IL 1*42284
(919) 544-5729
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HSJVB 9V9 (9.791)
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          18"02         Triangle Laboratories of IIP, Inc.
Sawle: UOST-4  SET 4 fUBEA/B  T/IC  173-46-19A/B  TLI«42284
(919) 544-5729
  Instrument H
108? cie.e?!)
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100


see 359
-------
                                                                                        o
                                                                                        CO
                                                                                        CD
87-89-9
         Triangle  Labor a topics of  If P.,  Inc.
SET 4           f/IC  173-4b-19A/ti
(919) S44-5729

       i»ent H
118375 1630 (10.301)
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359
-------
CO
CD
07-09-97 Triangle Laboratories of RfP, Inc. (919) 544-5729
SarnMtj; WST--4 SET 4 TUBEA/B T/TC 173-46- 19A/B TLIB42284 Instrument H
1181 (11, BID
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(11.811)
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-------
                                                                                        CT3
                                                                                        CD
                                                                                        CD
U7--R-3-37                 Triangle  Laboratories of RTF, Inc.
Sample: M08T-4 SET 4 TOBEA/B   f/TC  173-4S-19A/B  TLIH42284
(919) 544-5729
  Instrument H
jliS^Yb 1178 111,781)
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* 150 200 250 300 350
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15 160
120
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-------
                CD
                CD
09-Ju1-97 18:02          Triangle Laboratories of RIP,  Inc.
Sample: UOST-4 SET 4  TUBEA/B   T/TC   173-46-19A/B   TL1*42284
(919)  544-5729
  Instrument H
HS375
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09-Jul-97 18:02         Triangle Laboratories of RTF,  Inc.
Sample:  UQST-4 SIT 4 TUBEA/B  T/TC  173-46-19A/B   TLW42284
                                                                   (919) 544-5729
                                                                     Instrument H
HS375 84 (0.848)
         64
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100
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M/2   50
                  100
                              150
                                          280
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                                                                                    CO
                                                                                    CO
89-Ju1-97 18:82          Triangle Laboratories of  RTF,  Inc.
Sanple: UOST-4 SET 4  TUBEA/B  T/TC  173-46-1WB   TLIH42284
                                                                  (919) 544-5729
                                                                    Instrument H
HS375  181 (1.B10)
     yn
100:

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                                                                                    CD
                                                                                    CD
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tewlei MOST--4 SET 4 f
Triangle Laboratories of  RTF.  Inc.
     T/IC  173^*6--1WB
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                03
89-Ju1-97 18:82          Triangle Laboratories of  »TP,  Inc.
Sample: UOST-4 SET 4 TUBEA/B   T/TC  173-46-19A/B   TL1*42284
(919) 544-5729
  Instrument H
HS37
100
w/z
5 344 (3.448)
41 gg 200704
1,1 , 6? 8i4
58 ' 100 ' 150 ' 200 ' 250 ' 380 ' 350
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-------
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                                                                                    CO
                                                                                    CO
fiy/W)7    18:82        Triangle Laboratories of RIP, Inc.
:kiip!e:  TOKT-4 SET 4 IUBE«/B  T/TC   173-46-19f>/B  TLI842284
(919) 544-5729
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HS371, 779 (7.791)
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255
	 i • i • • • • j • i
358
-------
                                                                             o
                                                                             IN.
                                                                             CD
    m:m         Triangle Laboratories of RTF,  Inc.
UOST-4 SET 4  fUWIfi/B  T/TC  173-46-19AXR  TL1*42284
(919) 544-l>729
 liistrunent" II
IIS.J7G 210 (2.188)
XFSj 37,5165
•* 1 iipL 1L ,..ii.
si.-'z. 58
H^i/b'/lO (2.101)
6
--L- v J -n «? I **:
-• -- ?.' .? 4 -2 J --' -V J-J --J
« 1 ""i it .'': . ,. J.
tfl F'fi4 182:1,
*-i-n ,,=l 53
>'*~SJ 2S 27 > ' J54
.„... fi
..«a-j ^^ 33 53-
it -3 F ", l#Wo 178 ; i =
IHOi f.-f-,
,_,rff. j ,^27 39 53"
M,'^ ' 59
MBS
!-•'' H 5
180 158 288 256 368 35©
NBS 26 Hits : 26 Sea*»c.lie4
7 94288
69
3-BUTASISNE, 2-HETHVL-
.67 C£H8 255
69
7 * " " ' " ' "~" *" ass
69
4-PENIADIENE
""" C5H8
168 159 289 25» 368 350
-------
                                                                            r-
                                                                            co
    1.8:0?-         Triangle Laboratories of KfP.. Inc.

UOST--4 SEf  4 TUBEA/B  T/TC  173-4G-19A/B  TL1H42Z84
(919) 544-G729

 Instrument '* H
!fi.TO U347 (10.471)
/}'.» ,_ _
liflii ij l*b
1 3*i
XT ll -
i| . ._ ._ . , IjiJL ,..i

69
1 B? 9,7
I. ...HI ...,-B. .. J 	
H/Z ' 58 ' 168 '
iK37bf184? (18,471)
« rn **-"* Sb
i«f*sj 3<, i
Vt 1* "••* ** "- i ™ i**" _ -^
Q 1 111 Ji ,1 dtf ?.7




13 &
158 200




1.36

HBS
78840


350
NBS 112 Hits : 112 Searched
55H4H




**i F:yny 
XFS: 39 i "j
Fl-..^^_^__,.-, .i,ll,__J
6 69
"^ f
I7®/ 98111

11 2 F : 8 7 7 4R2 3 : €¥ CLOPItOPA HE
180i 4l55"
1 • r- ., , II. ....
6 69
^?H/ 97
f3 F:872 9334:CVCLOPROPANE
100 41 56 69

1 l!?l F
; '|| Ji J J*- L 9(7 it_j_

Vfz 5® ies

126
	 I1 ' ' '1 • l ' • • 1 • • ' ' 1 " • '
, 1 -METHYL- 2 -PENT YL-

l|b
. l-HEPTYL-2-METHYL-


1.26

158 aee
C9H18 255

• i • ' • • i • - • • i — •• • i • • • T i" ' 	 fi" •• • i

255
C9H18

"• 	 r ' • • • i -.-••• i •••• i .... , .... ,
255
C11H22

j i • - - • i -.-..(...- i * «•• i .... i
256 366 350
-------
                                                                          C4
                                                                          fs.
                                                                          CO
                             e Laboratories of RTF* I no.
:;,^r!e: UOS'f 4 SET 4 IUMA/i!  T/IC  173-46--1WH  T
(919) 544-0729
       reijl: II
!!jji'r* '
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. JH!.. .:.ii3 	 !i. «.,>*-.- t
• ,..-.,....,.,.,.....
58 186






158 209 259 360
                                                                   _3J§
                                                HBS 56 Hits : 56
           41
K*U~^-JCL£
1187
4|53 |
J"i 4-- "'
; CVCLOFENTiiNE, 1 , 2-DH1ETHYL-
' ij.-^1 \ 98
; CVCLOKEPTAHE
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C7H14
' • i • • - t . . .
C7H14
! .— . . —j
j-\ K: sr
fi-uf^
25S
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        27  | 43(57 bi 83„„
        "     ..J
            gg"
                                                          C7H14
386
350J
-------
                                                                                     CO
                                                                                     r*
                                                                                     CD
89-Jul-97 18:02         Triangle Laboratories of KTP,  Inc.
Sample: UOSf-4 SEf 4 IUBEA/B  T/TC  173-46-19A/B   ILIfJ42284
(919)  544-5729
  Instrument H
HS31
100
>5 794
1 5,7
ill Ul
M/2 50
HS37
KFS
0.
tti
100-
XFS:
0,
412
100
X.FS
#3
4| QQ *i
.IH.1 %pyy <
X.FS
0.
'5*794
F:844
27 y>
•5,'l 1
F:836
27 29
F1822
M/Z
(7.941)
104448
71 85
100 ' 150 ' 200 ' 250 ' 300 ' 350
(7.94J
4
39 N
2712
4
39
4444
4
39
L) REFINE NBS 178 Hits : 178 Searched
3 79872
44 5? 71 8.5
( , , , i , i« il, , -M-4
; OCTANE ' ' ' • • . . . .-,....,
3 255
44 5557 ?0 J1 84 /5
/ ,.,_>, , .,.,>,[,. \l,. 14,4
: HEPTANE/ 2/4-blMETI^¥L- ••'••••'
3 255
1A 85
44 55j| 69 7i 81v,/86
15627 IDECANE,' 2,4, 6-f HI HETH¥L- ' ' ' ' '
43 255
1 57
39 44 55s 58 65 1 ?,! 83 85 93 99
40 ' 60 80 ' 100 ' 120 ' 140 ' 16'0
-------
Project Number 42284
Sample File: HS348
                Method 8240A VOST
Sample ID: VOSTBLK 070897 T/TC



pHwIS^-pl^
Bromochloromethane
Chlorometharie
Vinyl Chloride
1 ,3- Butadiene
Bromomethane
Chloroethane
Vinyl bromide
Triclno ro Auoromethanc
1,1-Dichloroethcne
lodomcthanc
Carbon disulfide
Acetone
Ailyl chloride
Methylene chloride
trans-1 ^-Dichloroethene
rert-Ruryl methyl ether
Acrylonitrile
n-Hexane
1,1-Dichloroe thane
1 ,2-F.poxybutane
cis- 1 ,2- Dichloroethene
Chloroform
1 ,2-Dichloroethane
Isooctajie
1 ,4- Difluorobenzene
Vinyl tceiate
: s liiii&'''JC:kM*jfr>rtj'Ojra'*''*'"':'/' •"'•''f'":' ':': '•;•'" ' •' :* :':':
'•'•'Kf^VKVK~x^£\rCJt T'C W"» • ;••:/-'•:••'/-/ •-•:•:•: /. :".'••".'. :'.:


I'BIjttSotgB:, OXijrfcA^^;;^;^:;!;:^;;;-^^^;;^*:; j;5y •: ;
IS 1 4.50
U
U
u
u
u
u
u
u
u
u
0.028 J 2.59
U
0.007 J 2.97
U
U
u
u
u
u
u
u
u
u
IS 2 5-66
U
plllll llRes|i|pi:;lpp|:
Slit III 1 PliiHIlli
•:-:::v::-:v: -::^;;:v::-^g ;^|:::y|:;:::fc:.-: ;®:;'::/:' : :';?vy :>:%


:•'. •--'-- •-•-•»:- -.- Cv:- •:- --•»:-: :•: :•:•••:• -:•>:•::•:;•:• •:• •*->-:--:••:•- -K-~: : i^:-.
tiil1H-5^teP'^^i:;*8S-:;:Sillv:i:i<

0.001
0.001
0.001
0.00 1
0.001
0.001
0.001
0.001
0.001
0.001

0.001

0.001
0.001
0.004
0.001
0.001
0.003
0.001
0.001
0.001
0.001

0.001
;l|i;lll|||||g




0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05

0.05
                         NA- Not Applkiblt; 0«t Limit Detection Limit; Quart. Limit: Quantisation Limit
    IS: Internal Standard; U: Undetected; B: Present In Blank; ]: Estimated- Below Quantilation Limit; E: Estimated' Above Calibration Range
Triangle Laboratories of 8TP, Inc
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 * Fax (919) 544-5491
                                 Savarv3.S
                     Printed! 15:00 07/22/1997
                              674
-------
: Pacific Environmental Services : .: ; :
Project Number 42284
Sample File: HS348
Client Project: 5407*003
ITJ ID: VOSTBUKfl70897

Method 8240A VOST
Sample
! , , „ -I, Date Received: ' / '/f ' .-•'''' • • :
'",'-
•- Date Analyzed : 07/08/97 . .
ID: VOSTBLK 070897 T/TC
Respoti$e:Fiie:

', , ,
leALHW

. - --


.• :•
Anaiyte . . -:- • 1. .' ' •.[•
••': •••'•." ;/:' " \
2-Butanone
1,1,1 -Trichloroethane
Carbon tetrachloride
Benzene
Trichloroethene
1 ,2-Dichloropropane
Ethyl acrylate
Methyl methacrylate
Bromodichloromethane
cis-1 ,3-Dichloropropene
trans-1 ,3-Dichloropropene
1 ,1 ,2-Trichloroe thane
Dibromochloromethane
Ethyiene dibromide
Bromoform
Chlorobenzene-d
4-Methyl-2-pentanone
Toluene
Tetrachloroethene
2-Hexanone
Chlorobenzene
Ethylbcnzcnc
m-/p-Xylene
o-Xylene
Styrcne
1 , 1 ,2,2-Tetrachlorocthane
NA- Not
IS: Internal Standard; U: Undetected
• : • . .*••...•
&asuttl%.v. . f£A ^-^ :?" ' '";~' y "'
U
U
U
0.026 ] 5.14
U
U
U
U
U
U
U
U
U
U
U
IS 3 9.78
U
0.008 ] 7.60
U
U
U
U
U
U
U
U

^fcXjuwit :.. :-. r:-;
,:',^V::':-:. • :•;-!; .;
0.006
0.001
0.001

0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001

0.001

0.001
0.001
0.001
0.001
0.001
0.001
0.001
0.001

Qtian.tiadt
:'': ag- >V •
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05

0.05
0.05
0.05
0.05
0.05
0.05
0.10
0.05
0.05
0.05
Applicable; Drt. Limit: Detection Limit; Qnan. Limit: Quanritation Limit
; B: Present In Blank; J: Estimated- Below Quanritation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
             Savar v35
Printed: 15:00 07/22/1997
                                                                                                                    675
-------
                                     Pacific Environmental Services
Project Number; 42284
Sample File: HS348
                                        Method 8240A VOST
                        Sample ID: VOSTBLK 070897 T/TC

Cumene
      U
                 0.001
0.05
1,2-Dichloroethane-d
Benzene-d
Tolucnc-d
0,302
0.291
0,286
5-10
5.08
7.50
 121
 116
 114
Reviewed by
                        NA- Nat Applicable; Det Limit Detection Limit Qu an. Limit: Quan tiution Limit
    IS: Internal Standard; U: Undetected; B: Present In Blank;}: Estimated- Below Quantitation Limit; E- Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc
801 Capitals Drive • Durham, North Carolina 27713
Phew: (919) 544-5729 « fee (919) 544-5491
                                                        Savar v3.5
                                             Printed: 15:00 07/22/1997
                                                           676
-------
                                                                                    CD
07-08-97 20:22         Triangle Laboratories of RTF,  hie
Sample: UOSTBLK  T/TC
(919)  544-5729
  Instrument H
188-


XFS-

•
0-
Hin
18
s5



\
4.

'to
se


4.0
$9 1270638
TIC
#1
7 1 ^ 9"




/
f?
^6




6.0




'/ I
•? 12
"?9





16



15.51
JL^
8.0 10.0 12.0 14.0 16.0
                                                                                 If
                                                                                  I '
                                                                                 o:
                                                                                 P
                                                                                 *t
                                                                                 o
                                                                                 Q
-------
3UAN
No .
L
,*->
.&.
3
4
5
6
T
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
"""A
w/V*
31
32
33
34
35
36
37
38
39
4O
41
42
43
44
45
46
47
MO
49
50
O3 :
MAT
100
100
100
73
100
100
0
100
0
0
o
o
o
0
0
0
o
0
95
0
100
o
o
0
o
o
o
0
0


0
o
o
0
0
84
0
0
0
o
o
0
0
0
0
0
0
<*~
99
O
• HS348
FOR
97
95
97
41
81
93
0
88
O
0
O
0
o
0
0
0
0
0
78
O
79
0
O
0
o
o
o
0
0


0
o
o
o
0
78
O
O
O
0
O
0
0
0
0
0
0
79
0
REV
99
97
98
87
82
99
O
93
O
O
O
0
o
0
0
0
0
0
81
0
93
0
0
0
0
0
0
0
0
f\f\
•*" ^
0
0
0
o
0
88
O
0
O
O
O
0
o
o
o
o
0
0-J-
91
O
Delta
-1
1
— "">
*~
1
-1
0
0
2
O
O
0
o
0
0
0
0
0
0
3
0
1
0
0
0
0
0
0
0
0


0
0
0
o
0
12
o
o
o
0
o
0
0
0
0
0
0
~j
2
0
LAS-BASE QUAN
Area
325396
2018632
2435024
1057132
2717936
3165524
0
1709564
0
0
0
0
0
o
0
0
0
0
47672
0
17584
0
0
0
0
0
0
0
0


0
o
0
o
o
264796
0
0
0
0
0
O
0
O
0
0
0
59732
0
P . F I ags
bb
ob
bv
ob
bb
bv

bv










bb

bb








A






ft











DO
bb

RT
4 . 50
5.66
9.78
5.10
5.08
7 . 50
o.oo
12. O6
0.00
0.00
0.00
0.00
0.00
o.oo
o.oo
o.oo
0.00
0.00
2.59
O.OO
2.97
O.OO
o.oo
o.oo
o.oo
0.00
0.00
o.oo
o.oo
J- <>•%*•*
-•' - ^£3
o.oo
o.oo
o.oo
o.oo
o.oo
5.14
0.00
o.oo
o.oo
o.oo
o.oo
o.oo
0.00
o.oo
0.00
0.00
o.oo
. D-L
7.60
0.00
QM
128
114
117
65
84
98
98
95
50
62
39
94
64
1O6
101
96
142
76
43
76
84
96
73
53
57
63
42
96
83
£ *-$

57
43
72
97
117
78
130
63
55
69
83
75
75
97
129
107
173
* T
HO
92
164
07-08-97 20:53
Name
Bromochloromethane
1 ,4-Di" 1 uorobenzene
Chlarcbenzene-d5
1 , 2-Oichloroethane-d4
8en.zene-d6
Toluene-d8
o-Xylene-dlO
4-Bromof 1 uorobenzene
Chloromethane
Vinyl Chloride
1.3-Butadiene
Bromomethane
Chloroethane
Vinyl bromide
Trichlorof luorome thane
1,1-Dichloroethene
lodomethane
Carbon disulficte
Acetone
Allyl chloride
Hethylene chloride
trans-l.,2~0ichlaroethene
tert— Butyl methyl ether
Acrylonitrlle
n-Hexane
1,1-Oichloroethane
1,2-Epoxybutane
cis-1 ,2-Oichloroethene
Chloroform ^\r^
1,2-Oichloroethane ^/v
Isooctane
Vinyl acetate
2-Butanone
1,1, 1-Trichlo roe thane
Carbon tetrachlor ide
Benzene
Trichloroethene
1,2-Dlchloropropane
Ethyl acrylate
Methyl methacrylate
Bromodichloromethane
cis-1, 3— Dichloropropene
trans-l,3-Oichloropropen
1,1 , 2 -T rich lo roe thane
Oibrornochloromethane
Ethylene dibromide ^,
Bromoform s~\/\
4 Msthy l~2~pentanon^vvA"
Toluene ^— ^
Tetrachloroethene
Data Review:
                                 GIB
-------
No.  MAT FOR REV Delta
Area P.Flagj
RT
QM Name
51
52
53
54
55
56
57
0
0
0
0
0
0
o
•' A 1 —
0
0
0
o
0
0
o
	 3-3! —
0
0
0
0
o
0
o
0
0
0
0
o
o
o
	 1 	
0
0
0
o
0
o
o
	 Tf.ftti — KK .
0
0
0
0
o
0
0
	 1_O-
.00
.00
.00
.00
.00
.00
.00
— a-6-
43
112
106
106
106
104
83
i ne;
2-Hexanone
Chlorobenzene
Ethylbenzene
m— ,/p— Xy lene
o— Xylene
Styrene
1,1 ,2,2-Tetrachloroe
Hllfncanea /j^T\ ~N






than
                                                                  679
-------



07-08-9?
O
oo
CO
2§:22 Iriaiigle Laboratories of RIP, Inc. (919) 544-5729
Sample: MOSflLK T/fC Instrument H
HS348 259
100-
XFS-
0
n/'j.
4
a
3
44
"' 5
58
259
188
X.FS -
8
M/Z
4
1_J
3
44 5
i
58
NI2CAA 19
168-
XFS-
8
M/Z
4


3

44 5
5i
(2.598)
5632
8
1O0 158 288 258 308 350
(2.591) REFINE
4928
8
108 156 2O8 258 308 358
(2.578) Acetone FIND
188

ft
10e 158 283 258 388 358








-------
                                                                                     oo
                                                                                     CD
07-88-97  20:22
Sanple: UOSTBLK  I/TC
Triangle Laboratories of RIPj Inc,
(919) 544-5729
  Instrument H
297 (2.970)
108
XFS
8-
M/Z
4


9 5376
51

4
88
i
50 180 158 200 250 300 350
HS348=297 (2.971) REFINE
100
7.FS
0
M/Z
NT2C
188l

XFS-
8
H/Z
4
47
5
;UH
4

47
9 5440
8
51
4
88
0 1O0 150 200 250 300 350
21 (2,970) Hethtjlene chloride FIND
9 100
84
51
83
88
j
50 100 150 200 250 300 350
-------




87-88-97 20:22 Iriangle Laboratories of RTF, Inc. (919) 544-5729
Sample: WSTBLK T/IC Instrument H
HS348 514 (5.141)
100


XFS-


0

65
67
U1 I
sr "4
51 | 8
42 1 1 1
... 1 1. . ,i ILL .1 M.i ,.,
w/z 50
84 86896



2
\ "^1 n-j
,\( *-"*
103 150 200 258 300 358
He348*514 (5.141) REFINE
100:

X.FS-
0-
7



' 	 : 	 ' 	 1 	 ' 	 1 	 . 	 • 	 T
M/Z 50
8 352
79


Jt, — , — . — i 	 1 — . — , — , — , — | — , — . — , — i — | . . 	 . — r— | — • ••••"« — • — | ' • • ' 1 — • — • — • — • — I — • — • • ' — 1 • • ' ' I ' ' " ' 1 ' " ' ' 1
100 150 200 250 300 350
NTZCrtrt 36 (5.131) Benzene FIND
7ft 100
100-
%rs-

8.

77
52
„, 11. 6.3 „
-. . - f ^ — .- r
t*/Z 50


73

100 150 200 25O 300 350






















-------
                                                                                       OO
                                                                                       GO
87-88-97 20:22         Triangle Laboratories of RTF,  Iwc
Sample:  UOSTBLK  T/TC
(919) 544-5729
  Instrument H
768 (7.601)
100

XFS-
0-
M/Z
9


42 54 65 J®
1 12736
98


50 100 150 200 250 300 350
HS348'76i (7.601) REFINE
1B01

y.FS
0
9


., 65 89
. S,1 l| ';
1 11712
92

93
58 100 150 200 250 300 350
NI2CAA 49 (7.681) Toluene FIND
1001

X.FS
0
H/Z
9


/951 65 89
1 100
92
r

93
50 100 150 200 250 300 350
-------
                                    Pacific Environmental Services
Project Number. 42284
Sample File: HS364
               Method 8240A VOST
Sample ID: VOSTBLK 070997 T/TC




Bromochloromcthane
ChJoromcthane
Vinyl Chloride
1,3-Butadiene
Bromomcthane
Chloroeihane
Vinyl bromide
Trichbrofluoromethane
1 ,1-Dichloroethenc
lodomethane
Carbon disulfidc
Acetone
Allyl chloride
Mediykne chloride
trans- 1 ,2-Dichloroediene
tert- Butyl methyl ether
Acrylonitrile
n-Hexane
1 ,1-Dichloroethane
1 ,2-Epoxybutane
cis- 1 ,2- Dichbroethene
Chloroform
1 ,2-Dichlorocthane
boocune
1 ,4-Difluorobenzene
Vinyl acetate
teftflpiS'^XvXX 00'!-:i-:V'.;':'"":"::"-''::;:::::'-':-::xf^feiiik-'-^i»i*iai«'i|/«iil!«:'::': /':"::/*:'''v':V:::'t:: :::-::::-::;"-:::-;
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A-/Wjf9:/:' <:::V:;:x?:::::::5^-M---:-:->H-'-i'-x-:-K::::H::^X;x:,:::^:::v:;^



IS 1 4.48
U
U
u
u
u
u
u
u
u
u
0.022 J 2.54
U
0.014 J 2.95
U
U
u
u
u
u
u
u
u
u
IS 2 5.63
U
^™:;S:t:-:;-™::^;;4-:-^:::^^-:^:: ^i&^^&lV&fJ'
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0.001
0.00 1
0.001
0.001
0.001
0.001
0.001
0.00 1
0.001
0.001

0.001

0.001
0.001
0.004
0.001
0.001
0.003
0.001
0.001
0.001
0.001

0.001
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0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05

0.05
                        NA- Not Applicable; Det. Limit: Detection Limit; Quan. Limit Quantitatran Limit
    IS: Intern*! Standard; U; Undetected; B: Present In Blank; J; Estimated- Below Quantttation Limit; E: Estimated- Above Calibration Range
Triangl* Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Pax (919) 544-5491
                               Savar v35
                    Printed 15.-01 07/22/1997
                                                                                                684
-------
* ' ""' • '• • Pacific Ettviammettlal Services > '-••'" - -V •
Project Number 42284
Sample File: HS364
Client Proj ecfa S497-003
TO IDs VOSTBOC070997


Sample
Date Received: '//

Date Analyzed s 07/09/97
Method 8240A VOST
ID: VOSTBLK 070997 T/TC
Response JPiie: ICALH7Q8

'"•"•"• :


Aiwlyte ; ." :' '* ";"': '•'"••'

2-Butanone
1,1,1 -Trichloroethane
Carbon tetrachloride
Benzene
Trichloroethene
1 ,2-Dichloropropane
Ethyl acrylate
Methyl methacrylate
Bromodichloromethane
cis-1 ,3-Dichloropropene
trans-1 ,3-Dichloropropene
1 , 1 ,2-Trichloroethane
Dibromochloromethane
Ethylene dtbromide
Bromoform
Chlorobenzene-d
5
4-Methyl-2-pentanone
Toluene
Tetrachloroethene
2-Hcxanone
Chlorobenzene
Ethylbenzene
m-/p-Xylcnc
o-Xylene
Styrene
1 ,1 ,2,2-Tetrachloroe thane
••-Vs m**^' -'m&G:-.- ' ;'RT . .;.-V -."••• D
•;•; ^»g ^' ^'' ''•.•'•• " '!• ^ •.
U
U
U
0.037 } 5.11
U
U
U
U
U
U
U
U
U
U
U
IS 3 9.76

U
0.009 ] 7.57
U
U
U
U
U
U
U
U
«fctJa*ii7 - • •- :: <2*8B& tkolt
••• •• "f *..,:
0.007 0.05
0.001 0.05
0.001 0.05
0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.001 0.05


0.001 0.05
0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.001 0.05
0.001 0.10
0.001 0.05
0.001 0.05
0.001 0.05
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected;
B: Present In Blank; ]: Estimated- Below Quantitation Limit; E: Estimated- Abovt Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Pax: (919) 544-5491
             Savar v3.5
Printed: 15:01  07/22/1997
                                                                                                            685
-------
                                      Pacific Environmental Services
Project Number: 42284                                                              Method 8240A VOST
Sample File: HS364                                                 Sample ID: VOSTBLK 070997 T/TC

Cumene                                             U                               0.001                  0.05
U-Dichlonx:tltanc-d4                           0.269                 5.08                 1                  108
Benzene-d,                                    0.268                 5,07                 2                  107
Toluenc-dj                                    0.276                 7-48                 3                  110
Reviewed by	^Date
                         NA- Not Applicable; Del Limit Detection Limit; Quan. Limit: Quantitation Limit
    IS: Internal Standard; U; Undetected; B; Prexrtt In Bluik; J; Eatunatcd- Below Quantitation Limit; E Eatiouted- Above Calibration Range
Triangle Laboratories of RTF, Inc.                                                                               Savai v3.5
801 Capjtola Drive • Durham, North Carolina 27713                                                      Printed: 15:01 07/22/1997
Phone: (919) 544-5729 • Fax: (919) 544-5491                                                                       R 8 B
-------
                                                                                         00

                                                                                         CO
87-09-97  12:46         Triangle Laboratories of RTF, Inc

Sanple: VOSTBLK  T/fC
(919) 544-5729

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Brornoc hi oronif- t'nai le
1, 4-Oi f 1 uorobenzene
Chiorobenzene-dS
1 ., 2~Dichloroethane~d4
Genzene-d6
Tol uene-dE
o-Xylene-dlO
4-Bromof 1 uorobenzene
"P"HI f™3r*r^in^*'f"K^:i n*3 K>£> Ti IA J
^.^ltj.kjl kJMICt-llCtl' C; V4*x^ \ "V**
vinyl Chloride
1,3-Butadiene
Bromornethane V^SVi"^
fHl r^*"~n#a1™' H^ r»*^ Jtf"!--1^ ' l*A*s
Vinyl bromide
Tr ichlcrof 1 uoromethane
1 ,1-Dichloroethene
lodornethane ^_^ v
r'^pHfin Hic^iil "FifHfK' N^^iftl t
WCX i l^w 11 VJJ.c>d^.l i VJC; I r |^y ilJI^
Acetone
Allyl chloride
Methylsne chloride

















N
J


trans-1 ,2-Oichloroethene
tert-Butyl methyl ether
Acrylonltrile
n-Hexane
1, 1-Oichloroethane
1 , 2-Epoxybutane
cis-1 ,2-Oichloroethene
Chloroform
l.,2-Dlchloroethan!C;S3j"
Isooctane
Vinyl acetate
2-Butanone
1,1,1-Trichloroethane
Carbon tetrachloride
Benzene
Trichloroethene
1 ,2-Oichloropropane
Ethyl acrylate
Methyl methacrylate
Bromodichloromethane






LD











cis-1, 3-Dichloropropene
trans-1 , 3-Dichloropropen
1 ,1,2-Trichloroethane
Dibromochlorome thane
Ethylene dlbromide
Bromof orm
-------
No. MAT FOR  REV Delta      Area P.Flags       RT     CM Name

—51	2D	±o	±!t!	?	-34.'.:; Lb	  8, 85     43 2-Hexanone
 52   O    O    0     O         0              O.OO    112 Chlorobenzene
         *t?	*S	SH5	C^-tu  A	-tO-^-34    1O6 EthyIbwnzene
         5-g	yg	±	Q440  ft	1O . 3"1	 1O6 rn-/p-Xylene
 55   O    O   0     O          O              O.OO    1O6 o-Xylene

                                                       33 1,1,2 ,2-Ty8^3Vm.oroethan
              -3*1	e	706-4—A	11. 80—  1O5 Cumene  y
                                                                          R89
-------
87 09-
HS3b4
1601 4
1
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HS364'1
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4
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J,,

97 12:46 Triangle Laboratories of RTF, Inc. (919) 544-5729
: MOSTBLK T/TC Instrument H
254 (2.548)
3 4672
44
58
58 100 150 200 250 303 350
254 (2.541) REFINE
3 4160
59
50 160 150 200 259 368 350
i 19 (2.57R) Acetone FIHD
3 160
50 189 150 200 250 300 350
O
CD
CO






-------
                                                                                       CD
                                                                                       CD
07-89-97  12:46         Triangle Laboratories of RTF, Inc
Sample:          f/IC
(919) 544-5729
  Instrument H
295 (2,950)
49 18496
100-

v»r^; -



H-
i


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51



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88
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•'!'•••!•"••'•••• 1 ••' ' ! ' ' ' ' 1 ' • • . i • • • • . • • • • • • • • • i • • • • i • ........ i
H/Z 58 108 150 280 258 388 350
HS364J295 (2.951) REFINE
100-

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9 18496
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88
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M/Z 5S 150 288 258 388 358
21 (2.970) Methylene chloride FIND
188-

XFS -


0
4
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-------



97_0q_f
Sample
HS364
180]
1
XFS:
• 4J
JH/Z
H8364'
108i
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J? 12:46 Triangle Laboratories of RTF, Inc. (919) 544-5729
: T/IC Instruneiit H
511 (5.111)
84 116592

65
67
51 e
. ; It! , , ,,, ^ 1 (^ itl.p
"if-Mp
5B l@e 158 203 250 308 350
511 (5.111) REFINE
7
77
73^ '
8 12288

79
50 100 150 200 250 300 350
36 (5.131) Benzene FIND
7
77
[ fia
• '- ~-f- ,,lj<
8 100
79
f
5B l@e 158 208 250 300 350











-------
                                                                                        CD
87-89-97  12:46         Triangle Laboratories of  EIP,  Inc
Sanle: U08IBLK  T/TC
(919) 544-5729
  Instrtinent H
757 (7
108-

X.FS-
42 /" 6 5
P jjim.jiu, 4
H/Z 58
HS364J757 (7
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39
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1 14144
98
180


100 150 200 250 300 350
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9
89
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1 12608
92
93
188 158 268 250 300 356
.661) Toluene FIND
9


89
1 100
92

93
108 150 200 250 300 350
-------
                                       Triangle Laboratories of 1TP, Inc.
                                         Continuing Calibration Curve
CCAL File: HS362
ICAL File: 1CALH708
Date of Analysis :07/09/97     Analyte List: 8240A
VOST Calibration.
K '• '-. '-• \ i ' • :• (• • ' ; -f&- ;•«•-?• f-w::;f: S!:ssssisi;isiraS.Ky."2M;K5l5SifS^!^ %e*w &Cfiicifl!:*ssiPS 54?
^al§*fcr;;;;yM?:lSS^
Bromochloroinetrtane I
Chioromethane P
Vinyl Chloride C
13-Butadiene
Bro mo methane
Chloroethane
Vinyl bromide
Trichlorofluorometham
1,1-Dichloroethene C
lodomethane
Carbon disulfide
Acetone
Allyl chloride
Methylene chloride
trarn-12-Dichloroethene
tert-Butyl methyl ether
Acrylonitrile
n-Hexane
1,1-Dichloroethane P
12-Epoxybutane
eis-12-Dichloroethene
Chloroform C
12-Dichloroe thane
Isooctane
1,4-Difluorobenzene £
Vinyl acetate
2-Butanone
1,1,1-Trichloroethane
Carbon tetrachloride
Benzene
Triehloroethene
12-Dichloropropane C
Ethyl aoylate
Methyl methacrylate
Bromodichloromethane
cis-13-Dichloropropene
trans-13-Dichloropiiopene
1 , 1 ,2-Trichloroethane

1.657
2.042
2.088
1.601
1.193
1.807
4255
1235
3.114
4.286
0.663
0.998
1.839
1.853
4.038
0388
3.877
4.867
0558
2.035
3.888
3.074
15.591

0.807
0.027
0548
0.454
1269
0559
0.693
0539
0265
0.963
0.866
0.697
0365

2.102
2531
2.637
2204
1396
1.499
2.874
1.642
4290
6311
1308
1.112
1.970
2.072
4.670
0.431
4.677
4.852
0.484
2.074
3.811
2.949
15.990

0.780
0.040
0541
0.443
1267
0566
0.698
0508
0242
0.903
0.881
0.724
0376


212
193
20.8
27.4
145
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48.1
24.8
27.4
32.1
493
103
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10£
135
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325
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                  *- Fifl» QC Criteria tor %D;«- Rfles* than minimum QC If;»- RF gmlcr than i
Triangle tabontori** of RTF, Ine
801 Capitola Drive * Durham, North Carolina 27713
Phone (919) 544-5729 * Pa* (919) 544-5491
                                                                         &nrsrv3.5
                                                                                                   694
-------
                                       Triangle Laboratories of RTF, Inc.
                                         Continuing Calibration Curve
CCAL File: HS362              Date of Analysis £7/09/97     Analyte List: 8240A
ICAL File: ICALH708
VOST Calibration.

i-^^^^P^\S?^?p^?^^i||^^;lSs
Dibromochloromethane
Ethylene dibromide
Bromoform
Chlorobenzene-d5
4-Methyl-2-pentanone
Toluene
Tetrachloroethene
2-Hexanone
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrene
1,1,22-Tetrachloroethane
Cumene
fill
wP


P
I

C


P
C



P


12-Dichloroethane-d4
Benzene-d6
Toluene-d8
S
s
s

l^ftftSSiKpSSte:'
0554
0505
0277

0242
0.813
0.450
0.176
1.029
0547
0.679
0.649
1.089
0233
2.110

2M7
1245
1244

sxsi:;tpp>*|;™
0590
0.494
0332

0268
0740
0.433
0249
1.021
0513
0.638
0.610
1^)08
0262
2J26

2^91
L156
L13S


6.1
-22
16.6

9.7
-9.9
-3.9
29.3
-0.8
-6.6
-6.4
-6.4
-8.0
11.1-
-4.1

0.9
-7.7
-9.6
                           "TUJ
Approved by:.	I....IAJ      Date
                  *-FaUa(^ Criteria ^ %F^ <<-Rf ItMtfamroinimum QC RF;>>-RF greater than maximum QCRF
Triangle Laboratories of RTF, Inc.                                                                            Savarv35
801 Capitola Drive • Durham, North Caroilna Z7713
Phone: (919) 544-5729-Fax: (919) 544-5491
                                                                                                   695
-------
                                       Triangle Laboratories of RTF, Inc.
                                         Continuing Calibration Curve
CCAL File: HS344
1CAL File: 1CALH708
Date of Analysis :07/08/97     Analyte List: 8240A
VOST Calibration,
Aflalyte
Bromochloromethane
Chloromethane
Vinyl Chloride
13-Butadiene
Bromo methane
Chloroethane
Vinyl bromide
Trichlorofiuorome thane
1 ,1-Dichloroethene
lodomethane
Carbon disulfide
Acetone
Allyl chloride
Methylene chloride
trans-12-Dichloroethene
tert-Butyl methyl ether
Acrylonitrile
n-Hexane
1,1-Dichloroethane
1 ,2-Epoxybutane
cis-l^-Dicnloroethene
Chloroform
1,2-Dichloroetnane
Isooctane
1,4-Kfluorobenzene
Vinyl acetate
2-Butanone
1 , 1 , 1-Tricnloroethane
Carbon tctrachloride
Benzene
TricMoroethene
12-Dichloropropane
Ethyl acrylate
Methyl methacrylate
Bromodichlorome thane
cis-13-Dichloropropene
trans- 13- Dichloropropene
1 ,1 ,2-Trichloroethane
Hag fenus
i
P 1.603
C 2.003
2.081
2.005
1.415
1.689
3.477
C 1.973
4.903
7.160
1.699
1.281
2321
2373
5340
0520
5.020
P 5240
0527
2.190
C 4.048
3348
17.971
I
0.758
0.044
0549
0.417
1378
0586
C 0.740
0567
0276
0.967
0.893
0.720
0365
EfMEAN

2.102
2.531
2.637
2.204
1396
1.499
2.874
1.642
4290
6311
1308
1.112
1.970
2.072
4.670
0.431
4.677
4.852
0.484
2.074
3.811
2.949
15.990

0.780
0.040
0541
0.443
1.267
0566
0.698
0508
0242
0.903
0.881
0.724
0376
•%*>< , •" \ ' , .-, ,,r.. 1

23,7
20.9
21.1
9.0
-1.4
-12.7
-21.0
-20.2
-14.3
-13.5
-299
-15.2
-17.8
-14.5
-143
-20.6
-73
-8.0
-8.9
-5.6
-62
-13.5
-12.4

2.8
-10.0
-15
5.9
-8.8
-3.5
-6.0
-11.6
-14.0
-7.1
-1.4
0.6
2.9
                  *- Fail* QC Criteria for %D;« - Rf le» than minimum QC RF;»- RF greater than maximum QC RF
Triangle Laboratories of RTF, Inc.
801 Capitola Drive * Durham, North Caiuiira 27713
Phone (919) 544-5729 • Fast- (919) 544-5491
                                                                          Savar v3.5
                                                                                                   696
-------
                                        Triangle Laboratories of RTF, Inc.
                                         Continuing Calibration Curve
CCAL File: HS344              Date of Analysis :07/08/97     Analyte List: 8240A
ICAL File: ICALH708
VOST Calibration.
Anaiyfe • •' •' • '.:;'•'
Dibromochloromethane
Ethylene dibromide
Bromoform
Chlorobenzene-d5
4-Methyl-2-pentanone
Toluene
Tetrachloroethene
2-Hexanone
Chlorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrene
1,122-Tetrachloroethane
Cumene
Flag

P
I
C


P
C
P

t~ «KL25:R1
i
0.553
0512
0.288

0.268
0.811
0.463
0264
1.042
0.550
0.692
0.656
1.096
0.263
2.163
'ME<f .v:
0.590
0.494
0.332

0268
0.740
0.433
0249
1.021
0513
0.638
0.610
1.008
0262
2.026
«DP-: . :/r ' :•• v z&j.x -j:^:: •
6.3
-3.6
133

0.0
-9.6
-6.9
-6.0
-2.1
-7.2
-8.5
-7.5
-8.7
-0.4
-6.8
Suttogate; - , rr -- ...J-xHigr r «%^^&*BAN-- ~ -?*O&.; Tr :k » - .. ™ S^ll '*' • /r^r. -^-,]
12-Dichloroethane-d4
Benzene-d6
Toluene-d8
S
S
S
2.880
1209
1.263
2.691
1.156
1.135
-7.0
•4.6
-11.3
^k)
 Approved by:	JJ	Date
                  *- Fails QC Criteria for %D;« - Rf leas than minimum QC RF; »• RF greater than maximum QC RF
 Triangle Laboratories of RTF, Inc                                                                               Savarv33
 801 Capitola Drive • Durham, North Carolina 27713
 Phone: (919) 544-5729 • Fax: (919) 544-5491                                                                      R 9 *7
-------
                                       Triangle Laboratories of RTF, Inc.
                                            Initial Calibration Curve
ICAL File: ICALH7Q8 Date of Analysis :07/08/97
RF0.10 HS339 RFQ25 HS343
RF0.75 HS341 RF1.00 HS342
Analyte
RF0.50
List: 8240A
HS340
VOST Calibration.

Bromochloromethane I
Chloromethane P
Vinyl Chloride C
13-Butadiene
Bromomethane
Chloroethane
Vinyl bromide
Trichlorofluoromelhane
1,1-Dichloroethene C
lodomelhane
Carbon disulfide
Acetone
Allyl chloride
Methylene chloride
trans-12-Diehloroethene
tert-Butyi methyl etfier
Acrylonitrile
n-Hexane
1,1-Dichloroethane P
12-Epoxybutane
cis-l^-Dichloroethene
Chloroform C
1,2-Dichloroethane
Isooctane
1,4-Difluorobenzene 1
Vinyl acetate
2-Butanone
1,1,1-Trichloroethane
Carbon tetrachloride
Benzene
Trichloroethene
12-Dichloropropane C
Ethyl aoyiate
Methyl methacrylate
BromodichJoromethane
cis-13-Dichloroproperte
trans-1 3-Dichloropropene
1,12-TrichIoroethane


1.922
2591
2.886
2345
1.452
1555
3.011
1.929
5.032
7388
1.619
1246
2352
2374
5.089
0541
5.146
5.132
0520
2.046
3.694
3337
20293

0.750
0.025
0506
0.434
1255
0558
0.706
0.621
0281
0.883
0.863
OJ08
0389

2.191
2.607
2586
2.408
1.413
1.447
1725
1208
3.176
4,936
1.140
0379
1523
1580
3.798
0353
4104
4.674
0.434
2.061
3372
2.422
14.411

0.759
0.048
0537
0.438
1273
0574
0746
0529
0261
0.959
0384
0747
0381

2.061
2309
2,408
1.854
1319
1.457
2.989
1.917
4.808
6.982
1.135
1230
2212
2330
5304
0.488
4.898
5.051
0518
2.126
3.944
3261
16340

0303
0.030
0527
0.416
1.168
0548
0.694
0.496
0234
0.927
0.917
0.763
0395


2.192
2517
2.656
2.103
1376
1537
2.790
1.584
4335
6312
1.106
1.147
2.101
2266
4.918
0.434
4.771
4.724
0.476
2.052
3.698
2.652
14559

0.766
0.039
0.562
0.446
1.030
0577
0.674
0.460
0221
0.857
0.865
0.692
0352


2.147
2£32
2.650
2311
1.419
1.497
2353
1575
4.100
5.935
1538
1.058
1.659
1309
4242
0340
4.468
4.679
0.471
2.087
3345
2571
13345

0.821
0.058
0574
0.480
1.111
0574
0.670
0.433
0214
0390
0377
0710
0362


2.102
2.531
2.637
2204
1396
1.499
2.874
1.642
4290
6.311
1308
1.112
1.970
2.072
4.670
0.431
4.677
4352
0.484
2.074
3311
2.949
15990

0.780
0.040
0541
0.443
1.267
0566
0.698
0508
0242
0.903
0.881
0.724
0376


5.4
5.2
6.5
103
3.6
32
43
18.1
16.9
15.1
19.1
13.5
183
17.2
13.5
20.0
8.6
4.6
7.4
1.6
2.9
20.0
16.7

4.0
33.8
5.0
53
22.6
22
4.4
14.4
11.6
44
25
4.1
4.9
                 ». Fiib QC Criteria for %RSD;« . Ef 1«a» Heal minimum QC Eft »- KF greater than nmimmn QC ttF
Triangle tabontoriea of RTF, Inc.
801 Capttola Drive * Durham, North Carolina 27713
Phone (919) 544-5729 • Pax: (919) 5*14491
    Savar v3.5
698
-------
                                     Triangle Laboratories of RTF, Inc.
                                         Initial Calibration Curve
ICAL File: ICALH708
RF0.10 HS339
RF0.75 HS341
    Date of Analysis :Q7/08/97
    RF025 HS343
    RP1.00 HS342
Analyte Ltofc 8240A
RF050 HS340
VOST Calibration.
>?:-x- vxw >v. .:;%x-$:>x^
Dibromochloromethane
Ethylene dibromide
Bromoform
Chlorobenzene-d5
4-Methyl-2-pentanone
Toluene
Tetrachloroethene
2-Hexanone
CWorobenzene
Ethylbenzene
m-/p-Xylene
o-Xylene
Styrene
1,12,2-Tetrachloroethane
Curnene

12-Dichloroethane-d4
Benzene-d6
Toluene-d8
ItH
:pw

P
I
C


P
C
P

HH!
s
s
s

0558
0590
0299

0.230
0.647
0345
0.174
1.034
0.436
0540
0.497
0.828
0236
1.671

3242
1293
0.933

0583
0.495
0336

0297
0.820
0.472
0314
1.059
0551
0.696
0.668
1.108
0318
2225

2745
1214
1254

0.622
0.469
0357

0295
0.748
0.440
0.198
1.012
0531
0.672
0.638
1.061
0293
2.079
mm
2.834
1.121
1.145

0577
0.459
0338

0272
0.749
0.454
0229
0.997
0523
0.642
0.618
1.013
0253
2.061

2295
1.047
1.188

0.607
0.460
0329

0.249
0.734
0.453
0327
1.006
0525
0,639
0.628
1.028
0.211
2.092
mii
2337
1.108
1.154
HHH
0590
0.494
0332

0268
0.740
0.433
0.249
1.021
0513
0.638
0.610
1.008
0.262
2.026
Illlfii
2.691
1.156
1.135

43
11.1
63

10.9
8.4
11.7
27.6
25
8.6
93
10.8
10.6
16.4
103

145
8.4
10.6
 Approved by:.
"7U
                *- Faila QC Criteria for %KSD;« * Rflea* than minimum QC RF;»- RF greater than maximum QC RJF
 Triangle Laboratories of RTF, Inc
 801 Capitola Drive * Durham, North Carotina 27713
 Phone (919) 544-3729 • Pax: (919) 544-5491
                                                                          Savar v35
                                                                        699
-------
TECHNICAL REPORT DATA
Please rciij instructions on the reverse before completing
1. REPORT NO.
EPA-454/R-99-032b
2.
4. TITLE AND SUBTITLE
Primary Lead Smelter, Hoc Run, Herculaneum, Missjiirl: Volume II of III


7. AUTHOR(S)
Frank J. Phoenix
9. PERFORMING ORGANIZATION NAMH AND ADDRESS
Pacific Eimtonincntal Services, Inc.
Posl Office 3nx 12077
Research Triangle Park, North Carolinft 27709-2077
12, SPONSORING AGENCY NAME AND ADDRESS
U.S. Fnvitcnmeiital Protection Agency
OK'icc of Air Quality Planning and Standards
Emissions, Monitoring and Analysis Division
Research Triangle Park, North Carolina 2771 1
3. RECIPIENT'S ACCESSION NO.
5. RHTJUT DATE
August 1999
6. PERFORMING ORGANIZATION CODE
8. PERFORMING ORGANIZATION REPORT NO
10 PROGRAM ELEMENT NO
11. CONTRACT/GRANT NO.
68-D-70069
13. TYPK 01- RHPORT AND PERIOD COVERED
Hnal
14. SPONSORING AGENCY CODE
15. SUPPLEMENTARY NOTES
16. ABSTRACT
The United States Environmental Protection Agency's (EPA) Emission Standards Division l.tSD) is investigating the primary lead smelting source
category to kfonlify and quantify organic hazardous air pollutants (HAPs) emitted fiom blast furnaces. ESD asked EPA's Emissions, Monitoring and
Analysis Division (EMAD), and the Emission Measurement Center (EMC) to conduct the required testing. EMC issued a work assignment to Pacific
Environmental Services. Inc. (PES) to plan and conduct the air emissions test program to gather emissions data as specified in the KSD test request.
The testing program was conducts^ through KPA Contract No. 6SD20I62, Wark Assignment No 4-07. The primary objective was to obtain data on the
emissions of volatile and semi-volatile organic HAPs, aldehydes, and keton.es from primary1 lead smelter blast furna:es. A secondary objective was to
obtain data on the emissions wf tai ton monoxide. The data will be used by ESD to determine whether organic HAPs are emitted at levels that would
justify regulation under the MaxiT.um Achievable Control Technology (MACT) prugiam.
The Doc Run company, which operutes a primary lead smelter in Hercxencum, Missouri was selected by the BSD as the host facility for this
project. The Doc Run facility operates three primary lead blast furnaces which smelt concentrated lead ore to produce elemental lead. During normal
operation two furnaces operate simultaneously with the third furnace down for maintenance. All three furnaces are similar in design and operation.
They are semi-hatch fed and are tapped crailinuously. Air emissions from all three furnaces along with fugitive dust form a series of hygiene ventilation
systems are exhausted to a common baghouse and stack. In thf stack several independent process air exliausts aie combined with the taghouse exhaust.
In order to quantify the furnace emissions, testing was performed in the baghouse exhaust instead of the stack
In the performance of this test program, PES used EPA Methods 1 -4 and 10, SW-816 Methods 0030 and 00 IO, teller and Industrial Furnace (UIF)
Method 001 1, and a direct interface, portable gas chroinatograph/mass spectrometer.
This volume (Volume II) is comprised of 705 pages and consists of Appendix R.I.
I7.
a. DESCRIPTIONS
Baghouse
Blast furnace
Emission Measurements
Hazardous Air Pollutants
Primary Lead
Semi-Volatile Organic Hazardous
Air Pollutants
Volatile Organic Hazardous Air
Pollutants
18. DISTRIBUTION STATEMENT
Unlirr.ited
KEY WORDS AND DOCUMENT ANALYSIS
b. IDENTIFIERS/OPEN ENDED TERMS

19. SECURITY CLASS (This Repon)
Unclassified
20, SECURITY CLASS (This page)
Unclassified
c. COASTI Field/Group

21. NO. OF PAGES
1,322
22. PRICE
EPA Form 2220-1 (Rev. 4-77)  PREVIOUS EDITION IS OBSOLETE
                                                                                 F:\U\FMeadows\TRD.Frm\WP 6 i
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