EPA-454/R-00-038e
SOURCE CHARACTERIZATION FOR SEWAGE SLUDGE INCINERATORS
FINAL EMISSIONS REPORT, VOLUME II OF III, APPENDIX A - APPENDIX J
METROPOLITAN SEWER DISTRICT (MSD)
MILL CREEK WASTER WATER TREATMENT PLANT
CINCINNATI. OHIO
Prepared for:
Clyde E. Riley(MD-19)
Emissions, Monitoring and Analysis Division
Office of Air Quality Planning and Standards
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
U.S. ENVIRONMENTAL PROTECTION AGENCY
Office of Air and Radiation
Office of Air Quality Planning and Standards
Research Triangle Park, North Carolina 27711
September 2000
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GENERAL DISCLAIMER
This document may have problems that one or more of the following disclaimer
statements refer to:
* This document has been reproduced from the best copy furnished by the
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* This document may contain data which exceeds the sheet parameters. It
was furnished in this condition by the sponsoring agency and is the best
copy available.
• This document may contain tone-on-tone or color graphs, charts and/or
pictures which have been reproduced in black and white.
• The document is paginated as submitted by the original source.
• Portions of this document are not fully legible due to the historical nature
of some of the material. However, it is the best reproduction available
from the original submission.
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TABLE OF CONTENTS
ACKNOWLEDGMENTS , iii
1.0 INTRODUCTION . 1-1
1.1 Summary of Test Program 1-1
1.2 Test Program Organization .' 1-3
1.3 Quality Assurance/Quality Control (QA/QC) Procedures . .1-6
1.4 Description of Report Sections 1*6
2.0 SUMMARY AND DISCUSSION OF TEST RESULTS 2-1
2.1 Objectives and Test Matrix 2-1
2,2 Site-Specific Test Plan Changes and Sample Collection Problems 2-1
2.2.1 Air Emissions 2-2
2,2.2 Scrubber Water 2-4
2,2.3 Sewage Sludge 2-4
2.3 Air Organic Emissions Summary and Discussion 2-4
2.3.1 Toxic PCB Results 2-7
2,3.2 Dioxins, Furans (D/F) Results 2-12
2.3.3 PAH Results - 2-16
2.4 Continuous Emissions Monitoring Summary and Discussion 2-19
2.5 Process Sample Measurements Summary and Discussion , . 2-21
2,5,1 Scrubber Water Organic Results 2-21
2.5.1.1 Toxic PCB Comparison of Scrubber Water In Versus
Scrubber Water Out 2-21
2.5.1.2 Toxic PCB Results for Scrubber Water In . . . . . 2-21
2.5,1.3 Toxic PCB Results for Scrubber Water Out . . . 2-24
2.5,1.4 Dioxin/Furan Results for Scrubber Water 2-24
2.5.2 Sewage Sludge Organic Results . 2-24
2.5.3 Scrubber Water and Sewage Sludge Inorganic Results 2-31
3,0 SAMPLING LOCATION DESCRIPTIONS 3-1
3.1 Flue Gas Sampling Location -. 3-1
3.1.1 Sampling Point Determination - EPA Method 1 3-1
3.1.2 Volumetric Measurements - EPA Method 2 3-5
3.1.3 Molecular Weight Determination - EPA Method 3A 3-5
3.1.4 Flue Gas Moisture Content - EPA Method 4 3-5
3.2 Process Sampling Locations 3-6
3.2.1 Scrubber Water 3-6
3.2.1.1 Inlet Sampling Location 3-6
3.2.1.2 Outlet Sampling Location 3-6
3.2.* bluage Feed 3-7
IV
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TABLE OF CONTENTS
(Continued)
Page
4.0 PROCESS DESCRIPTION AND OPERATION 4-1
4.1 Process Description , 4-1
4.1.1 General .. ,,..,, 4-1
4.1.2 PreliminaryTreatment 4-1
4.1.3 Primary Treatment ......,, 4-1
4.1.4 Secondary Treatment 4-3
4.1.5 Tertiary Treatment , , , , . 4-3
4.1.6 Sewage Sludge Thickening System 4-3
4.1.7 Sewage Sludge Digestion .- ........... 4-4
4.1.8 Dewatering System , , , . 4-4
4.1.9 Incinerator Ash . 4-5
4.2 Description of Incinerators , . , , . 4-5
4.3 Description of Emissions Monitoring, Control and Emergency Equipment , , . 4-6
4.3.1 Emissions Control Equipment 4-6
4.3.2 Emissions Monitoring Equipment ,,,,,,. 4-6
4.3.3 Emergency Equipment , , . 4-6
4.4 Process Operation Summary ,,..., 4-7
5.0 SAMPLING AND ANALYTICAL PROCEDURES , 5-1
5.1 Air Emissions , 5-1
5.1.1 Air Emission Sampling . . 5-1
5.1.1.1 Modified Method i Sampling , . . . . 5-1
5.1.1.2 Continuous Emission Monitoring for CO, 02, and CO2 ..... . . . . . 5-9
5.1.1.3 Total Hydrocarbon Monitoring 5-13
5.1.2 Air Emission Sample Analysis 5-13
5.1.2.1 MM5 Sample Extraction 5-13
5.1,2.2 PCB Extract Cleanup and Analysis 5-16
5.1.2.3 D/F Extract Cleanup and Analysis , .,,,., 5-16
5.1.2.4 PAH Extract Cleanup and Analysis , . , , 5-20
5.2 Process Scrubber Water ..,,., 5-2C
5.2.1 Scrubber Water Sampling 5-20
5.2.2 Scrubber Water Analysis .,,,,., 5-23
5.2.2.1 PCB Analysis 5-23
5.2.2.2 D/F Analysis 5-24
5.2.2.3 Chlorine Analysis ........,, 5-25
5.2.2.4 pH/Temperature Determination 5-2B
5.3 Process Sludge Feed ,,.,,.' 5-25
5.3.1 Sludge Feed Sampling ....,....„.,,. .5-2$
b.i.ii Sludge Feed Analysis . 5-oC
5.3.2.1 PCB Analysis 5-30
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TABLE OF CONTENTS
(Continued)
Page
5.3.2.2 D/F Analysis , 5-30
5.3.2.3 Chlorine Analysis 5-33
5.3.2.4 Percent Solids Analysis 5-34
5.3.2.5 Ultimate/Proximate Analysis 5-34
6.0 INTERNAL QA/QC ACTIVITIES 6-1
6.1 QA/QC Checks and Issues 6-1
6.1.1 Field Sampling , 6-1
6.1.1.1 MM5 Emission Sampling 6-1
6.1.1.2 Continuous Emission Monitoring 6-3
6.1.2 Sample Handling 6-7
6.1.3 Laboratory Analysis 6-7
6,1.3.1 Emission Samples 6-8
6.1.3.2 Sewage Scrubber Water Samples . 6-48
6.1.3.3 Sewage Sludge Feed Samples 6-66
6.2 QA Performance Audits 6-75
6.2.1 Field Sampling Audits 6-75
6.2.1.1 Dry Gas Meter 6-75
6.2.1.2 Pitot Tube 6-75
6.2.1.3 Thermocouples 6-76
6.2.1.4 Analytical Balance 6-76
6.2.1.5 Total Hydrocarbon Analyzer 6-77
6.2.1.6 CEM Systems Audit 6-78
6.2.2 Laboratory Analysis Audit 6-78
6.3 QA/QC Performance Review 6-80
6.3.1 Program Performance Targets and Results 6-80
6.3.2 Method Specific Performance Targets and Results 6-81
6.3.2.1 Air Emissions 6-81
6.3.2.2 Scrubber Water Samples 6-85
6.3.2.3 Sludge Feed Samples 6-86
VI
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LIST OF APPENDICES
Appendix A - Field Test Results
Appendix B - Raw Field Data
B-1 Stack Sampling Data
B-1-1 Methods 1 & 2 Preliminary Stack Traverse Data
B-1-2 MM-5 Sampling Raw Field Data
B-2 MM-5 Sample Recovery Field Data
B-3 Percent Isokinetic Field Calculation Form
B-4 Process Samples Field Data
Appendix C - Calibration Data for Field Equipment
C-1 Summary of Field Equipment Used During Field Program
C-2 Equipment Calibration Forms
C-2-1 Dry Gas Meter, Pitot Tube Calibrations
C-2-2 Post Test Meter Box Field Audit
C-2-3 Cylinder Gas Audits Summary Sheets
C-2-4 Cylinder Gas Audits
Appendix D - Sampling Logs and Chain-of-Custody Records
D-1 Daily Sampling Logs
D-1-1 ETS Field Sampling Log
D-2 Chain-of-Custody Records
D-3 Process Sampling Logs
D-4 Laboratory Record Book Sample Log In
D-5 Field Test Log
Appendix E - PCB Analytical Lab Raw Data Results
E-1 PCB Analytical Summaries
E-1-1 Air Samples
E-2 PCB Lab Raw Data Sheets
E-2-1 Air Samples
E-2-2 Sewage Sludge Fractions
E-2-3 Scrubber Water Inlet Fractions
E-2-4 Scrubber Water Outlet Fractions
E-3 PCB Blanks Lab Raw Data
E-3-1 Air Sampling Train
E-3-2 Sewage Sludge Blank Fractions
E-3-3 Scrubber Water Fractions
Appendix F - Dioxin/Furan Analytical Lab Raw Data Results
F-1 D/F Results Summary
F-1-1 Air Sample Fractions
F-1-2 D/F EPA Audit Sample
VII
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TABLE OF CONTENTS
(Continued)
F-2 D/F Lab Raw Data Sheets
F-2-1 Air Emission Runs
F-2-2 EPA Audit Sample
F-2-3 Sewage Sludge
F-2-4 Scrubber Water Inlet
F-2-5 Scrubber Water Outlet
F-3 D/F Blank Lab Raw Data Sheets
F-3-1 Air Sampling Train & Proof Blanks, Lab Spikes, and Spike Dups
F-3-2 Sewage Sludge Blank Fractions
F-3-3 Scrubber Water Fractions
Appendix G - PAH Analytical Lab Raw Data Results
G-1 PAH Results Summary
G-2 PAH Blank Lab Summaries
G-3 PAH Lab Raw Data Sheets
G-4 PAH Blank Lab Raw Data Sheets
Appendix H - Chlorine Analytical Lab Raw Data Results
H-1 Chlorine Sewage Sludge Results
H-2 Chlorine Scrubber Water Inlet Results
H-3 Chlorine Scrubber Water Outlet Results
H-4 Chlorine Lab Sludge Blank Results
H-5 Chlorine Lab Water Blank Results
H-6 Chlorine Field Water Blank Results
H-7 Chlorine Lab Raw Data Sheets
Appendix I - Percent Solids Analytical Lab Raw Data Results
I-1 Total Percent Solids Results Summary
I-2 Lab Raw Data Sheets
Appendix J - Ultimate/Proximate Analytical Results'
J-1 Analytical Summary
J-2 Lab Raw Data Sheets
Appendix K - Equations and Guidelines Used for Calculating Results
K-1 Stack Sampling Reference Methods 2-5 Example Calculations
K-2 Example Calculations for PCB Analysis
K-3 Relative Standard Deviation Calculation Worksheet
K-4 Gas Concentration Correction to 7% 02 Worksheet
Appendix L - Continuous Emissions Monitoring (CEM) Data
L-1 CEM Test Data Summary
L-2 1-Min Data Printouts
viii
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TABLE OF CONTENTS
(Continued)
L-3 CEM Response Time Determinations
L-4 C-4 CEM Calibration Records
L-5 CEM Calibration Gas Certifications
Appendix M • Process Field Data Sheets
M-1 Daily Process Data Summary Tables
M-2 Daily Process Data Sheets from MSD
Appendix N - Sampling and Analytical Protocols
N-1 PCB Protocols (Battelle)
N-1-1 Draft Air Emissions Method
N-1-2 Draft Sewage Sludge Method
N-1-3 Draft Scrubber Water Method
N-2 Battelle SOPs for D/F Analysis
N-3 PAH Protocols (Modified CARB Method 429)
N-4 Chlorine Protocol (Wastewater Method 4500 G, Modified ASTM D5233)
N-5 Percent Solids IWastewater Method 2540 B!
N-6 Proximate/Ultimate Protocols (ASTM D3172, D4239, and others)
N-7 pH and Temperature (Wastewater Method 4500 H)
N-8 CO Protocol<40 CFR 60, Appendix A, Method 10A)
N-9 C02 and 02 Protocols (40 CFR 60, Appendix A, Method 3A)
N-10 Composite Sampling
Appendix O - List of Project Participants with Titles
0-1 MSD
0-2 USEPA
0-3 Battelle
0-4 ETS
0-5 Pacific Environmental
0-6 T&E Lab
0-7 Quanterra Lab
Appendix P - Post Test Summary
P-1 Post Test Summary Report
P-2 QAPP Amendment Records
P-3 SSTP Amendment Records
P-4 Corrective Action Reports
P-5 QA Officer Site Visit Checklist
IX
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LIST OF TABLES
Page
Table 1-1. Test Matrix 1-2
Table 2-1. Toxic PCB Results - Stack Gas Concentrations (ng/dscm, as measured) . 2-8
Table 2-2. Toxic Results - Stack Gas Concentrations (ng/dscm, adjusted
To 7% 02) 2-9
Table 2-3. Toxic PCB Results - WHO Toxic Equivalent Stack Gas'
Concentrations (ng/dscm, adjusted to 7% 02) 2-10
Table 2-4. World Health Organization Toxic Equivalent Factors (TEFs) for
Determining Coplanar PCB TEQs 2-11
Table 2-5. D/F Results - Stack Gas Concentrations (ng/dscm, as measured) 2-13
Table 2-6. D/F Results - Stack Gas Concentrations (ng/dscm, adjusted to
7% Oj) . . 2-14
Table 2-7. D/F Results - TEQ Stack Gas Concentrations (ng/dscm, adjusted
to 7% 02) 2-15
Table 2-8. PAH Results - Stack Gas Concentrations (ng/dscm, as measured) .... 2-17
Table 2-9. PAH Results - Stack Gas Concentrations (ng/dscm, adjusted to
7% 02 2-18
Table 2-10. CEM Daily Results 2-19
Table 2-11. Run 2, Run 3, and Run 4 Toxic PCB Results - Comparison of
Inlet Versus Outlet Scrubber Water 2-22
Table 2-12. Toxic PCB Results - Inlet Scrubber Water . 2-23
Table 2-13. Toxic PCB Results - Outlet Scrubber Water . . 2-25
Table 2-14. D/F Results - Comparison of Inlet Versus Outlet Scrubber Water 2-26
Table 2-15. D/F Results for Inlet Scrubber Water 2-27
Table 2-16. D/F Results for Outlet Scrubber Water 2-28
Table 2-17. Toxic PCB Results for Sewage Sludge 2-29
Table 2-18. D/F Results for Sewage Sludge 2-30
Table 2-19. Chlorine, Percent Solids, Temperature, and pH Results - Comparison
of Inlet Versus Outlet Scrubber Water . 2-31
Table 2-20. Chlorine and Percent Solids Results for Sewage Sludge . 2-32
Table 2-21. Ultimate Analysis Results for Sewage Sludge 2-32
Table 2-22. Proximate Analysis Results for Sewage Sludge 2-32
Table 4-1. Summary of Data from Mill Creek WWTP Control Room
Process Monitors 4-8
Table 5-1. Pre-Field Surrogate Standards 5-5
Table 5-2. Laboratory Internal Standards 5-17
Table 5-3. Standards for Laboratory Control Spike Samples 5-18
Table 5-4. Gas Chromatographic Operating Conditions for PAH Analysis . 5-21
Table 6-1. Gas Stratification Check Results 6-2
Table 6-2. CEM Calibration and Linearity Check Data 6-4
i aoie o-o. Bias and Instrument Drift Check Data 6-5
Table 6-4. Response Time Check . 6-4
Table 6-5. Sample Transfer Schedule 6-7
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LIST OF TABLES
(Continued)
Pat
Table 6-6. Summary of PCB Results and Standard Recoveries for Front Half
Air Samples 6-v.
Table 6-7a. Summary of PCB Results and Standard Recoveries for Back Half
Air Samples - 6-10
Table 6-7b, Back Half Air Data Corrected for Pre-sampling Surrogate Recovery ... 6-12
Table 6-8a. Summary of PCB Results and Standard Recoveries for Front Half
Lab Control Spike and Spike Duplicate Samples 6-14
Table 6-8b. Summary of PCB Results and Standard Recoveries for Back Half
Lab Control Spike and Spike Duplicate Samples , . . , , 6-15
Table 6-9. Summary of PCB Results and Standard Recoveries for
Background and Method Blank Samples , , 6-16
Table 6-10. Summary of PCB Results and Standard Recoveries for Field Blank
and Proof Blank Front Half Air Samples 6-1?
Table 6-11. Summary of PCB Standard Recoveries for Field and Proof Blank
Back Half Air Samples 6-18
Table 6-12. Summary of Dioxin/Furan Results and Standard Recoveries for
Front Half Air Samples ,..,.,. 6-20
Table 6-13, Summary of Dioxin/Furan Results and Standard Recoveries for
; Back Half Air Samples 6-22
Table 6-14a. Summary of Dioxin/Furan Results and Standard Recoveries for
Front Half Lab Control Spike and Spike Duplicate Samples 6-25
Table 6-14b. Summary of Dioxin/Furan Results and Standard Recoveries for
Back Half Lab Control Spike and Spike Duplicate Samples ......... 6-27
Table 6-15. Summary of Dioxin/Furan Results and Standard Recoveries for
Lab and Method Blank Samples , , , , 6-30
Table 6-16. Summary of Dioxin/Furan Results and Standard Recoveries for
Field Blank and Proof Blank Front Half Air Samples ,,.... 6-3?
Table 6-17. Summary of Dioxin/Furan Results and Standard Recoveries for
Field Blenk and Proof Blank Back Half Air Samples . 6-34
Table 6-18, Summary ef PAH Results and Standard Recoveries for Front Half
Air Samples 6-3"?
Table 6-19. Summary of PAH Results and Standard Recoveries for Back Half
Air Samples . . , 6-3f
Table 6-20a. Summary of PAH Results and Standard Recoveries for Front Half
Lab Control Spike and Spike Duplicate Samples ......... 6-4?
Table 6-20b. Summary of PAH Results and Standard Recoveries for Back Half
Lab Control Spike and Spike Duplicate Samples ,,,,., 6-44
Table 6-21. Summary of PAH Results and Standard Recoveries for Lab and
Method Blank Samples 8 46
Table 6-22. Summary of PAH Results,and Standard Recoveries for Field and
Proof .Blank Front Half Air Samples '. . . 6-43
XI
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LIST OF TABLES
(Continued)
Page
Table 6-23. Summary of PAH Standard Recoveries for Field and Proof Blank
Back Half Air Samples 6-51
Table 6-24. Summary of PCB Results and Standard Recoveries for Scrubber
Water Inlet Samples . 6-53
Table 6-25. Summary of PCB Results and Standard Recoveries for Scrubber
Water Outlet Samples 6-54
Table 6-26. Summary of PCB Results and Standard Recoveries for Lab Control
Spike and Spike Duplicate Scrubber Water Samples 6-56
Table 6-27. Summary of PCB Results and Standard Recoveries for Lab Blank
Scrubber Water Samples 6-58
Table 6-28. Summary of Dioxin/Furan Results end Standard Recoveries for
Scrubber Water Inlet Samples . 6-59
Table 6-29. Summary of Dioxin/Furan Results end Standard Recoveries for
Scrubber Water Outlet Samples . 6-61
Table 6-30, Summary of Dioxin/Furan Results and Standard Recoveries for Lab
Control Spike, Spike Duplicate, and Lab Blank Scrubber Water Samples 6-64
Table 6-31. Intercomparison of Total Chlorine Analyses 6-66
Table 6-32. Summary of PCB Results and Standard Recoveries for Sewage
Sludge Samples 6-67
Table 6-33. Summary of PCB Standard Recoveries for Matrix Spike, Spike
Duplicate, and Lab Blank Sewage Sludge Samples 6-69
Table 6-34. Summary of Dioxin/Furan Results and Standard Recoveries for
Sewage Sludge Samples 6-71
Tab'e 6-35. Summary of Dioxin/Furan Results and Standard Recoveries for Matrix
Spike, Spike Duplicate, and Background Sewage Sludge Samples .... 6-73
Teble 6-36, QA Results for Dry Gas Meter 6-76
Table 6-37. Total Hydrocarbon Analyzer Audit Results 6-77
Teble 6-38. Results of the CEM Audit 6-78
Table 6-39. Results of the Lab Dioxin/Furan Audit 6-79
Table 6-40. Overall Program QA/QC Results 6-80
Table 6-41. Data Quality Objectives for Precision, Accuracy, and Completeness
for Field Measurements 6-81
Table 6-42. Draft PCB Emission Method Performance Target Criteria and Results . . 6-82
Table 6-43. D/F Emission Analysis Performance Target Criteria and Results 6-83
Teble 6-44. PAH Emission Performance Target Criteria and Results 6-84
Table 6-45. Draft PCB Scrubber Water Method Performance Criteria 6-85
Table 6-46. D/F Scrubber Water Analysis Performance Target Criteria and Results . 6-86
Table 6-47. Draft PCB Sewage Sludge Method Performance Criteria 6-87
Table 6-48. D/F Sewage Sludge Feed Analysis Performance Target Criteria and
Results . t. , . 6-87
XI!
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LIST OF FIGURES
Figure 1-1, Program Organization 1-4
Figure 2-1, CO end THC Daily Test Results - Run 2 2-20
Figure 2-2. CO end THC Daily Test Results - Run 3 2-20
Figure 2-3. CO and THC Daily Test Results - Run 4 2-20
Figure 3-1. Plant Process Sampling Locations . 3-2
Figure 3-2. Schematic of Sampling Location Exhaust Stack for Incinerator No. 6 ... 3-3
Figure 3-3. Sampling and Traverse Points for Incinerator Stack 3-4
Figure 4-1. Schematic Diagram of Mill Creek Wastewater Treatment
Plant Process 4-2
Figure 5-1. Sampling Train for EPA Modified Method 5 5-2
Figure 5-2. Flow Chart for Emission Sample Recovery 5-8
Figure 5-3. Continuous Sampling System for Instrumental Methods
(EPA Methods 3A and 10) 5-11
Figure 5-4. Flow Chart for Extraction of MM5 Sampling Train Front Half ........ 5-14
Figure 5-5. Flow Chart for Extraction of MM5 Sampling Train Back Half ........ 5-15
Figure 5-6. Flow Chart for Scrubber Water Sampling 5-22
Figure 5-7. Flow Diagram for Preparation and Extraction of Scrubber
Water Samples for PCB Analysis 5-26
Figure 5-8. Flow Diagram for Preparation and Extraction of Scrubber
Water Samples for D/F Analysis 5-27
Figure 5-9. Flow Chart for Sludge Feed Sampling 5-29
Figure 5-10. Flow Diagram for Sample Preparation and Extraction of Sludge
Feed Samples for PCB Analysis 5-31
Figure 5-11. Flow Diagram for Preparation and Extraction of "Sludge Feed
Samples for D/F Analysis 5-32
Kill
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APPENDIX A
Field Test Results
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Table A-l
Field Results Summary
A-1
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Table A-l
Field Test Results Summary
Run ID
Sample Date
Clock Time Started
Clock Time Ended
Total Sampling Minutes
Run 2
MSD-MM5-R2
7-20-99
15:00
21:30
360
Run3
MSD-MM5-R3
7-21-99
10:15
16:35
360
Run 4 Avei
MSD-MM5-R4
7-22-99
08:15
14:35'
360 350
Average Stack Conditions
Volumetric Flow
acfm
dscfrn
dscmm
Percent Moisture (%)
Avg Stack Temperature (°F)
Stack Gas Concentration
CO (ppmdv)
THC (ppmdv)
CO, Cone. (%dV)
O, Cone, (%dV)
MM-5 Field Sampling Results
Sampled Volume
(dscf)
(dscm)
Percent Isokinetic
17980
15520
439
4.65
116
1380
70.6
5.16
13.7
207
5.85
91.7
18130
15780
447
4.26
115
1170
54.2
5.50
13.0
220
6.22
95.9
19450
16790
475
4.76
117
1130
37.5
5.07
13.4
237
6.70
97.1
18520
16030
454
4.56
116
1230
54.1
5.24
13.4
221
6.26
94.9
Process Sample Field Results
Scrubber Water In
pH ' 7.37
Temperature (°F) 87
Scrubber Water Out
pH 6.49
Temperature (°F) 116
7.48
87
6.57
120
7.43
87
6.51
123
7.43
87,
6.52
120
Footnotes
1. Process data logged by Pacific Environmental. (THC analyzer data provided by MSD)
2. CO, CO2, and O2 analyzer data is the arithmetic mean of corrected 1-minute averages collected during
nprirvt campled. THC analyzer data is arithmetic mean of corrected hourly reported values collected
during the sampling period (8 data points per run). , ;
3. Process scrubber water data is the arithmetic mean of the 6 grab samples collected during each
sampling ran.
A-2
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Table A-2
Modified Method 5 Field Test Results Summary
A-3
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Table A-2
MM-5 Field Test Results Summary
Run?
Rim ID
Sample Date
Time Started
Time Ended
Sampling Parameters MM-5
Total Sampling Time (min.)
Number Traverse Points
Corrected Barometric Press (In. Hg)29,55
Sampled Volume (dcf) -
Avg. Meter Press (in. H20)
Avg, Meter Ternp (°F)
Total Moisture Collected (g)
Dry Gas Meter Calibration Factor
Nozzle Inside Dia. (in.)
Pilot Tube Constant
Outlet Stack Parameters
Stack Static Press, (in. H2O)
Absolute Stack Press, (in. Eg)
Stack Area (sq. in)
Avg Stack Temperature (°F)
Avg. AP (v')
CO, Cone. (%dV)
02 Cone. (%dV)
MM-S Sample Results
Sampled Volume
(dscf)
(dscm)
Stack Moisture
Volume Collected (scf)
Percent Moisture (%)
Mole Fraction
Stack Gas Molecular Wt.
Wet Basis
Dry Basis
Stack Gas Velocity
ft/min
m/sec
Stack Gas Volumetric Flow
acfm
dscfrn
dscmm
Percent Isokir.etic
Percent Excess Air
Run3
Run 4
MSD-MM5-R2
7-20-99
15:00
21:30
360
72
)29,55
221,71
1.18
99
213.7
0.9968
0.254
0.836
-0.16
29.54
1256.6
116
0.35
5.16
13.7
207
5.85
10.1
4.65
0.0465
28.86
29.38
2061
10.47
17980
15520
439
91.7
182
MSD-MM5-R3
7-21-99
10:15
16:35
360
72
29.64
237.29
1.36
105
207.5
0.9968
0,254
0.836
-0.16
29.63
1256.6
115
0.35
5.50
13.0
220
6.22
9.77
4,26
0.0426
28.91
29.40
2078
10.56
18130
15780
447
95.9
153
MSD-MM5-R4
7-22-9P
08:15
14:35'
360
72
29.63
256.12
1.57
106
251.0
0.9968
0.254
0.836
-0.19
29.62
1256.6
117
0.40
5.07
13.4
237
6.70
11.8
4.76
0.0476
28.81
29.35
2228 '
11.32
19450
16790
4/5
97.1
165
360
72
29.61
238.37
1.37
103.3
224.1
0.9968
0.254
0.836
-0.17
29.60
1256.6
116
0.37
5.24
13.4
221
6.26
10.5
4.56
0.0456
28.86
29,38
2122
10.78
18520
16030
454
94.9
167
A-4
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Table A-3
CEM CO Daily Test Run Averages
A-6
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Table A-3
Field Test CO Results Summary
Run ID
Sample Date
Clock Time Started
Clock Time Ended
Averaging Intervals
Run 2
MSD-MM5-R2
7-20-99
15:00
21:30
1 minute
Run 3
MSD-MM5-R3
7-21-99
10:15
16:35
1 minute
Run 4
MSD-MM5-R4
7-22-99
08:15
14:35
1 minute
Sampling Parameters CEMs
CO Daily Low (ppmdv) 1248
CO Daily High (ppmdv) 1607
CO Mean Average (ppmdv) 1379
Standard Deviation (%) 4.3
918
2137
1170
16.9
1023
1372
1126
5.6
1063
1705
1225
8.9
Footnotes
1. Daily low and high values are uncorrected 1-minute averages during period sampled.
2. Mean and standard deviation were calculated from corrected 1-minute averages during the period
sampled.
A-7
-------
Table A-4
CEM THC Daily Test Run Averages
A-B
-------
Table A-4
Field Test THC Results Summary
Run ED
Sample Date
Clock Time Started
Clock Time Ended
Averaging Intervals
Run 2
MSD-MM5-R2
7-20-99
15:00
21:30
hour
Run 3
MSD-MM5-R3
7-21-99
10:15
16:35
hour
Run 4
MSD-MM5-R4
7-22-99
08:15 '
14:35
hour
Sampling Parameters CEMs
THC Dafly Low (ppmdv) 63.2
THC Daily High (ppmdv) 78.2
THC Mean Average (ppmdv) 70.6
Standard Deviation (%) 4.84
31.3
73.3
54.2
22.9
30.6
57.3
37.5
8.50
41.7
69.6
54.1
12.1
Footnotes
1. THC analyzer values are calibration corrected and calculated from hourly reported values during the
sampling period (8 data points per run).
2. THC analyzer data collected by Pacific Environmental. (THC analyzer data provided by MSD)
A-9
-------
Table A-5
CEM CO2 and O2 Daily Test Run Averages
A-10
-------
Table A-5
Field Test CO2 Results Summary
Run ID
Sample Date
Clock Tune Started
Clock Time Ended
Averaging Intervals
Run!
MSD-MM5-R2
7-20-99
15:00
21:30
I minute
Run 3
MSB-MMS-R3
7-21-99
10:15
16:35
1 minute
Run 4
Average
MSD-MM5-R4
7-22-99
08:15
14:35
1 minute
Sampling Parameters CEMs
CO2 Daily Low (%dv)
CO2 Daily High (%dv)
CO2 Mean Average (%dv)
Standard Deviation (%)
4.54
5.70
5.16
5.23
4.18
8.26
5.50
12.5
4.34
5.56
5.07
4.93
4.35
6.51
5,24
7.55
Footnotes
1. Carbon dioxide analyzer data is calibration corrected 1 -minute averages during the sampling period.
A-11
-------
Table A-6
Field Test O2 Results Summary
Run ID
Sample Date
Clock Time Started
Clock Time Ended
Averaging Intervals
Run2
MSD-MM5-R2
7-20-99
15:00
21:30
1 minute
Run 3
MSD-MMS-R3
7-21-99
10:15
16:35
1 minute
Run4
MSD-MM5-R4
7-22-99
08:15
14:35
1 minute
Sampling Parameters OEMs
O2 Daily Low (%dv) 12.9
O2 Daily High (%dv) 14.6
O2 Mean Average (%dv) 13.7
Standard Deviation (%) 2.77
9.49
15.0
13.0
7.21
12.1
14.6
13.4
4.77
11.5
14.7
13.4
4.92
Footnotes
1. Oxygen analyzer data is calibration corrected 1-minute averages during the sampling period.
A-12
-------
APPENDIX B
Raw Field Data
-------
B-l
Stack Sampling Data
B-1
-------
Table B-l-1 - Methods 1 and 2 Preliminary Stack Traverse Data
Stratification Test Results
Cincinnati MSD Incinerator Stack
SAMPLING
POINT
Al
A2
A3
A4
A5
A6
Bl
B2
B3
B4
B5
B6
AVI7
TIM
E
1545
1549
1553
1557
1601
1605
1610
1614
1618
1622
1626
1630
02
(%dv)
15.26
14.85
14.73
'14.94
15.09
14.86
15.15
14.73
14.38
13.88
13.87
14.03
i4tfi«;
%DIFF.
FROM
MEAN
4.2
1.4
0.5
2,0
3.0
1.4
3.4
0.5
-1.8
-5.3
-5.3
-4.2
C02
(%dv)
4.31
4.27
4.35
4.16
4.29
4.44
4.15
4.45
4.76
5.21
5.28
"5.15
4
-------
METROPOLITAN SEWER DISTRICT
SEWAGE SLUDGE INCINERATOR
STRATIFICATION CHECK
JULY 19, 1999
Starting
07-19-99
Time
15:43
15:44
15:45
15:46
15:47
15:48
15:49
15:50
15:51
15:52
15:53
15:54
15:55
15:56
15:57
15:58
15:59
16:00
16:01
16:02
16:03
16:04
16:05
16:06
16:07
16:08
16:09
16:10
16:11
16 : 12
16:13
16:14
16:15
16:16
16:17
16:18
16:19
16:20
16:21
16:22
16:23
16:24
16:25
16:26
16:27 .
16:28
16:29
16:30
02
%dv
11.76R
14.18R
15.26P
14.93R
14.96R
14.87R
14.85P
14.95R
14.89R
14.71R
14.73P
14.79R
14.80R
14.87R
14.94P
14.S3R
15.14R
15.14R
15.09P
15.07R
15.02R
14.88R
14.86P
14.89R
16.69R
15.25R
15.22R
15.15P
14.99R
14.90R
14.79R
14.73P
14.43R
14.46R
14.44R
14.38P
14.22R
14.21R
13.87R
13.88P
13.98R
14.03R
13.S6R
13.87P
13.98R
14.01R
14.051
14.03P
C02 CO
%dv ppntdv
3.07R 2849. OOR
4.33R 1978. OOR
4.31P 956. OOP
4.18R 847. OOR
4.16R 833. OOR
4-24R 836. OOR
4.27P 858. OOP
4.18R 883. OOR
4.21R 890. OOR
4.38R 926. OOR
4.35P 947. OOP
4.30R 961. OOR
4.28R 983. .OOR
4.23R 1000. OOR
4.16P 995. OOP
4.17R 1012. OOR
4.19R 102 5. OOR
4.24R 1044. OOR
4.29P 1060. OOP
4.28R 1099. OOR
4.31R 1130. OOR
4.44R 1171. OOR
4.44P 1156. OOP
4.41R 1159. OOR
2.96R 1088. OOR
4.06R 917. OOR
4.09R 1197. OOR
4.15P 1216. OOP
4.28R 1225. OOR
4.32R 1221. OOR
4.42R 1212. OOR
4.45P 1203. OOP
4.68R 1181. OOR
4.661 1203. OOR
4.69R 1205. OOR
4.76P 1209. OOP
4.87R 1213. OOR
4.87R 1195. OOR
5.18R— 1245.00R
3.21P 1294. DO*
5.13R 1319. OOR
5.11R 1279. OOR
5.181 1241. OOR
5.28P 1218. OOP
5.181 1213.001
5.161 1206.001
5.15R 1175. OOR
^ 5.15P 1152. OOP
-------
B-l-2
MM-5 Sampling Raw Field Data
B-5
-------
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Revision 1
03/16/94
CYCLONIC FLOW CHECK
40 CFR 60, APPENDIX A, METHOD 1, SECTION 2.4
Location:
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J3
A
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Point No.
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-------
B-2
MM-5 Sample Recovery Field Data
i-18
-------
FIELD SAMPLE LOG
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FIELD SAMPLE LOG
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RUN I.D.
SAMPLE
TYPE
TOTAL
SAMPLE
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ALIQUOT
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DATE
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-------
B-3
Percent Isokinetic Field Calculation Form
B-27
-------
APPENDIX B-1-1
STACK SAMPLING FIELD DATA
ISOKINETIC CALCULATIONS delta H=K*deltaP 0.5 0.16
0.52 0.16
NOZZLE SI2ER • Put in 35 and 55 ACFH to determine nozzle size range. 0.54 0.17
Desired 0.56 0.26
Sample Volume 35 ACFH 0.54 0.25
Stack Temp. 106 degrees F Suggested 0.48 0.25
Moisture % 1 %H2O Nozzle size 0.154697 0.49 0.21
Average delta P l.85in.H20 0.49 0.23
0.45 0.26
Choose a nozzle from inside the range and put the actual 0.42 0.28
K-FACTOR CALCULATOR size in the K-factor calculator below. 0.34 0.27
0.3 0.28
delta Ha 1.68611 in. H2O Update the Kfactor for temperature changes of >5 0.469167 0.231667
Meter Temp. 50 degrees F degrees F for meterbox temperature and 15 degrees F 0.64
Barometric 28.6 In, Hg stack temperature. KFactor= 0.592544 0.37
Static Pressure 0 in, H2O 0.5
Nozzle Diameter 0.16 inches k*dP. = dH 1.096206 0.61
Moisture % 1 % Need to average a dH of 1 or highei 0.74
Stack Temp. 100 degrees F to pull 30 dscf/hour. 0.82
0.86
0.531958
MOISTURE SATURATION CALCULATOR/STEAM TABLES
Stack Temp. 70 degrees F
Barometric 30.06 in. Hg Maximum % Saturations 2.459186
Static Pressure 0.18 in, H2O
B-28
-------
SIZING NPZ2L1S FOR ISOKINETIC SAMPLING
The Method 5 sampling train is intended to operate at a
sampling rate of 0.75 scfm. In order to operate at a variety of
different sampling velocities while maintaining the same nominal
sampling rate of 0.75 cfm, different sizes of nozzle openings are
used on the sampling probe. The higher the gas velocity, the
smaller the nozzle diameter needed to maintain an isokinetic
rate, and vice versa. The equation to calculate an appropriate
nozzle diameter is:
where
P.
• avg
= nozzle diameter, inches
= volumetric flow rate through meter, cfm
- absolute pressure at meter, in. Hg
« PB + 0.10
s= absolute pressure at stack, in. Hg
PB + P.t.tic/13-6
- anticipated average temperature at
meter, °F
= average temperature in stack, °F
= pitot tube calibration coefficient (0.84
for type S)
= water vapor in stack gas, volume
fraction
= molecular weight of stack gas, wet basis
MjMl-B^) + 18*BW,
average velocity head of stack gas, in. W.C.
For most situations, this equation can be simplified by •
making several assumptions. If Qw = 0.75 cfm, Pm = PB » 29.92 in.
Hg., Me = 29.0, Cp = 0.84, then:
= 0.97
If specific total sample volume limits or sampling rates
other than 45 dcf and 0.75 cfm, respectively, are required, be
sure to use the full equation. For instance, if a test requires
that no more than 120 dscf be collected in three hours, then use
-"-":"'ve rf 0,67 (120/180) for Qm in the lull equation.
Once D. is calculated, an actual nozzle is selected from
those available -closest to the calculated Dn
It should be
remembered that a nozzle larger than the calculated Dn will
require sampling at a higher £H than normally required, while
using a nozzle smaller than the calculated Dn will result in a
lower AH, and consequently, a lower sample volume.
B-29
-------
K-FACTOR APPROACH FOR ISOKINETIC SAMPLING
Isokinetic sampling is performed using 3 basic steps:
1) Measure the velocity of the gas stream using a pitot tube,
2) Calculate a sampling AH based on the velocity of the gas
stream.
3) Adjust the sampling rate of the Method 5 meter box to the
calculated AH,
Nomographs or calculator programs are often used to calculate the
AH required for isokinetic sampling. However, it is usually just
as easy and convenient to use the K-factor approach to calculate
AH. In this approach, a constant, K, is determined based on the
preliminary traverse data. AH is then determined for each AP by
simple multiplication. All that is required for this procedure
is a simple calculator with one memory register. Although a
calculator with programmable ability is useful, it is not
necessary for this approach.
Isokinetic Rate Equation; The isokinetic rate equation can be
written as follows;
846.72 £>K AIL CJ (l-B^J2
M. (2V-460) P.
M
AP
Note that this equation reduces toi
AH = K * AF
where
K = 846.72 D AJ?e
(rM+460)
M
• The equation for K can be simplified in most cases by
assuming that the ratios M^/M, and ?,/£„ are equal • to one. This
is normally justified' in non-combustion source stacks with low
static pressures ' (< 3"W.C.) and combustion sources with moisture
contents less than 6%.
B-30
-------
NOMENCLATURE
BWB= Assumed volume fraction of H2O in stack•
Cp « pitot tube coefficient (0.84 for Type S)
Dn = nozzle diameter (in.)
AH = pressure difference of orifice meter required to sample
isokinetically (in. H20)
AH»= orifice meter coefficient, AH for 0.75 cfm at STP
(in. H20)
M, = assumed stack gas molecular weight
= Md*(l-Bra) + 18*BWS (Ib/lb-mole)
Ma = dry gas molecular weight (29 'for dry air) (lb/lb-moie)
PB » absolute stack pressure (in. Hg)-PB + P,t,tlc/13.6 •
PB = meter absolute pressure (in. Hg)*PB +6.10
&P = individual pressure difference of pitot tube for
traverse point (in. H2O)
Tro = average anticipated meter temperature, °F (use
ambient + 10° for most cases)
TB = average stack temperature from preliminary traverse, °F
B-31
-------
RUN NUMBER
MSD-MM5-R1
Date
Start Time
End Time
Stack Diam.
Nozzle I.D.
Meter Box Gamma
Meter Box dH@
Barometric
Cp
TesI Duration
METHOD 1-4 RESULTS
Mete red Volume
Volume @ Std.Cond,
% Water
% Isokinetics
Velocity
Actual Flow
Std. Flow
Dry Std. Flow
STACK
TEMP STATIC
POINT (DegF) (in.WC)
1 115 -0.16
2 115
3 115
4 115
5 116
6 115
7 115
8 115
9 116
10 116
11 115
12 115
13 115
14 115
15 114
16 114
17 114
18 114
18 113
20 114
21 113
22 113
23 115
24 114
25 114
26 114
27 114
2B 113
29 113
X 113
31 . 113
32 113
33 113
34 113
35 113
36 113
AV6, 114 -0.16
07/20/99
09:30
12:30
40
0.254
0.9968
1.6953
29.25
0.84
180
109.822
101.725
4.66
91.1
34.31
17964
16143
15392
DP
(in.WC)
0.26
0.25
0.25
0.26
0.26
0.26
0.26
0.28
0.27
0.29
0.30
0.32
0.31
0.35
0.35
0.36
0.40
0.40
0.41
0.43
0.44
0.40
0.39
0.41
0.38
0.43
0.42
0.41
0.40
0.37
0.34
0.35
0.35
OJ29
0.30
0.32
0.34
METHOD 4 DATA
inches
Inches
In.Hg
minutes
dcf
dscf
IMP.1
IMPJ
IMP.3
IMP.4
IMP.S
IMP.6
XAD
TOTAL
S.G.
(NIT.
(ml)
0.0
100.0
100.0
0.0.
360.0
560.0
200.0
FINAL
ftnft
80.0
101,0
103.0
2.0
370.5
656.5
209.0
NET
(ml)
80.0
1,0
3.0
2.0
0.0
0.0
10,5
96.5
9.0
% METHOD 3 DATA
%
ft/sec
acfrn
scfrn
dscfm
DH
(in.WC)
0.86
0.83
0.83
0.86
0.86
0.86
0.86
0.92
0.89
0.96
0.99
1.10
1.00
1.20
1.20
1.30
1.32
1.32
1.40
140
1.50
1.32
1.30
1.40
1.30
1.40
1.40
1.40
1.30
1.20
1.10
1.20
1.20
0.96
0.99
1.10
1.14
B-32
%02
%C02
%CO
%N2
O2+C02
METER
VOLUME
(dcf)
156.859
266.681
-«••*-
109.822
13.1
5.4
0.0
81.5
18.5
Md
Ms
Ps
Fo
%EA
29.38
28.85
29.24
1.451
156
METER TEMPERATURE
INLET
{DegF)
89
94
96
99
101
101
102
98
98
98
99
98
102
102
99
102
103
102
103
105
105
105
107
107
105
106
104
102
100
, 133
102
102
102
103
103
102
OUTLET
(DegF)
85
85
87
88
•as
89
92
89
90
90
91
89
91
• 91
91
91
92
92
92
94
94
94
96
97
96
97
96
94
94
97
95
95
94
95
96
96
87
-------
RUN NUMBER
NSD-MMS-R2
Date
Stal Time
End Time
Stack Diam.
Nozzle LD.
Meter Box Gamma
Meter Bo* dH@
Barometric
Cp
Test Duration
METHOD 1-4 RESULTS
Metered Volume
Volume C StdCond.
% Water
KItokirwtict
Velocity
Actual Flow
Sid. Flo*
Dry Sid. Flow
STACK
TEMP STATIC
POINT (DeoF) (in.WC)
1 116 -0.16
2 116 -0.16
3 116
4 118
5 ite
6 116
7 116
e lie
9 118
10 118
11 118
12 117
13 116
14 119
15 116
16 116
17 117
16 116
1C 116
20 117
21 116
22 116
23 116
24 116
25 116
26 115
27 115
26 115
23 115
30 116
31 115
32 115
33 115
34 115
35 115
36 115
37 116
36 116
35 116
40 115
41 117
42 115
43 117
44 118
4J 117
46 116
47 116
48 116
49 118
50 116
51 116
52 116
53 115
54 116
55 116
56 116
57 116
SB 115
59 114
60 114
61 113
62 113
63 113
64 114
65 113
66 113
67 113
68 113
69 113
.70 112
71 112
72 112
WG. 116 -0.16
07/20/99
1&OC
21:30
40 Inche*
0254 Inches
0.9968
1.6953
29.55 frvHg
0.836
360 minutes
221.709 aa
206.517 fecf
4.65 %
81.7 %
34.35 fUiec
17963 acrni
16274 acfm
1SS18d*efm
DP DH
(in.WC) fnWC)
027 0.86
025 0.80
026 0.83
025 0.80
026 0.83
025 0.80
026 0.83
027 0.86
029 0.93
0.31 1.00
0.31 1.00
0.31 1.00
0.32 1.00
0.35 1.10
0.35 1.10
0.34 1.10
0.35 1.10
0.36 1.10
0.38 120
0.38 120
0.36 120
0.38 120
0.39 1.30
040 1.30
0.40 1.30
0.40 1.30
0.39 1.30
0.38 120
0.40 1.30
0.40 1.30
0.37 1.30
0.35 120
0.37 1.30
0.31 1.10
029 1.00
029 ' 1.00
0.33 120
0.33 120
0.34 120
0.34 120
0.35 120
0.3S 120
0.34 120
0.34 120
0.35 120
0.34 120
0.33 120
0,33 120
0.34 120
033 120
0.32 1.10
035 120
035 120
0.36 1.30
0.41 1.40
0.41 1.40
0.41 1.40
0,40 1.40
0.40 1.40
0.41 1.40
0.41 1.40
0.42 1.50
0,40 1.40
0.38 1.40
0.38 1.40
0.39 1.40
0.34 120
0.34 120
0.33 120
027 0.97
025 0.90
026 0.90
0.35 1.18-
B-33
METHOD 4 DATA
MP1
MP2
MP.3
MP.4
MP.S
MP.6
XAD
TOTAL
S.G.
wrr.
(ml)
0.0
100.0
100.0
0.0
347.0
S47.0
872.5
FINAL
(ml)
174.0
mo
73.0
0.0
353.0
709.0
8242
NET
(mn
V74.0
9.0
•27.0
0.0
C.O
0.0
6.0
162.0
S1.7
METHOD S DATA
%02
KCO2
%CO
%N2
02+C02
METER
VOLUME
(del)
267.659
328.301
331.382
378.663
380.000
491.786
.
~M1.70»
13.8
52
0.0
81.0
19.0
Md
Ml
P»
Fo
KEA
26.38
28.86
2S.S4
1.365
182
METER TEMPERATURE
INLET
(DeoF)
86
101
89
103
103
103
103
104
107
105
106
104
107
106
106
103
105
106
105
105
105
102
105
106
112
109
106
106
107
107
107
105
105
106
109
108
88
101
103
102
103
103
103
102
102
101
102
98
103
102
102
102
101
103
102
103
102
101
88
"*^S
95
as
as
as
as
95
95
as
as
95
86
as
OUTLET
(DeoF)
86
86
86
88
86
86
85
86
88
86
87
101
101
101
102
89
100
102
101
102
102
86
88
88
101
100
102
101
102
88
89
88
86
88
102
101
85
85
84
84
86
84
88
86
86
84
84
84
95
95
as
86
83
84
as
as
83
92
82
P1
88
88
: 87
88
88
88
87
87
88
88
87
87
99
-------
RUN NUMBER
MSO-MMMU
D*u
SWttn*
End Tim*
SlKkDiKI.
NozztoLO.
M*ter BCB Gamma
Motor Box dHO
BarenxMe
Cp
T»»i Duration
METHOD 1-4 RESULTS
IMargdVekm*
WtteM 6 SW-Cond,
KWM*
%IftakfcHiBI
MtodtF
Actual Flow
SU. Ftow
Dry SM. Flow
STACK
TEMP STATIC
POINT (OesF) (HWC)
1 116 41.16
2 115 -0.16
3 115
4 114
6 115
6 114
7 112
8 113
9 113
10 114
11 113
12 11S
13 113
14 113
15 113
16 113
17 1«
IB 113
19 112
20 112
21 114
22 114
23 114
24 11$
25 113
26 113
27 114
28 113
29 113
30 113
31 114
32 113
33 113
34 114
35 113
36 112
37 118
38 118
99 116
40 117
41 118
42 117
43 118
44 117
45 118
46 116
47 118
48 116
49 116
50 117
91 116
52 116
S3 117
54 1W
SB 11T
56 118
57 118
SB 11C
59 116
60 116
61 116
62 118
83 116
64 117
65 116
66 117
87 116
86 117
69 116
70 I'M
'71 116
T2 116
AVG. 115 -0.16
07/21)99
10:15
16:35
40 incur
i
0254 inch**
0.9968
1.6953
28.64 in-Hg
0,8355
360 miM
237295 del
219.6S2 dx*
428*
95.9 *
34.63 (Vice
Wt33*cftn
16487 KtRl
•s
METHOD'
MP.1
MPJZ
MP.3
MP.4
WP.5
MP.6
XAD
TOTAL
E.G
IDATA
wrr.
%
IDO'O
100.0
0,0
342.0
S42.0
872J
FMAL
fiS
171.0
106,0
99.0
1,0
347.5-
729.5
BSGL5
NET
imo
6.0
-1.0
1.0
0.0
0.0
6.5
187.5
.20.0
METHOD 3 DATA
15785 dtqfm
DP OH
fnVWC) (r
031
QJO
0.30
0.30
0.30
0.32
as?
039
0.39
0.34
0.31
033
033
0.34
0.34
0.36
036
0.37
0.43
0.44
0.49
0.46
0.37
0.39
0.40
0.3S
0.38
0.36
0.37
0.38
0.30
0.31
0.32
024
QJ4
024
tL2S
028
OJO
0.30
0.31
029
0.30
o.x
0.31
0.33
0.30
0.31
QJS
OJ7
CJ6
0.40
040
0.40
0,45
0.42
0.41
0.42
0.41
0.41
0.«2
0^41
0.43
0.41
0.44
0.42
0.36
0.38
0.3$
CM
025
025
035
B
120
1.10
1,10
1.10
1.10
120
1.40
1,50
1.50
1.30
120
1.30
1.30
1.30
1.30
1.40
1.40
1.40
1.60
1.70
1.90
1.70
1.40
1.50
1.50
1.30
1.40
1.40
1.40
1.40
1,10
120
120
0.91
0.91
O.B1
1.10
1.10
120
120
120
1.10
120
120
120
1.30
120
120
1,40
1,40
1.40
UB
1.60
1.60
1.80
140
1.60
1.80
1.60
1.60
l.taO
180
1.70
140
1.70
1.60
1.40
1.50
1.50
1.10
0.98
0.98
1.36
•34
%O2
KCQ2
%CO
%K2
02«CO2
METER
VOLUME
«**!
494,149
611,099
B12.500
732.845
237295
13.0
5.5
0.0
81.5
18.5
Md
Ml
Pi
Fo
KEA
29.40
28.91
29.63
1.436
1S3
METER TEMPERATURE
INLET
(OteF)
85
96
102
101
101
102
102
104
103
103
103
104
105
105
105
105
105
- 106
106
108
107
107
110
107
110
110
111
111
108
110
112
109
106
112
111
111
105
106
111
112
113
109
112
112
108
112
112
112
113
114
114
115
115
115
115
114
113
112
109
MiMirn
1lj
113
11$
114
114
114
113
113
113
114
114
113
OUTLET
(D*cF)
92
92
92
92
93
93
•2
82
93
92
93
93
94
94
95
as
95
•6
96
96
W
87
100
97
101
101
102
im
101
101
101
102
102
102
101
101
102
102
102
102
103
103
103
104
' 103
104
104
104
105
105
MS
105
106
106
108
108
106
105
105
106
1U&
105
105
107
106
105
105
105
105
105
105
105
105
-------
RUN NUMBER
MSD-MMMU
Dale
Start Time
EndTme
Stack Diam.
Nozzle I.D.
Meter Box Gamma
Mater Box dH@
Barometric
Cp
Te*t Duration
METHOD 1-4 RESULTS
Metered Volume
Volume C StdCond.
* Water
KboWnatfca
Velocity
Actual Flow
Stfl Flow
Dry Sid. Flow
STACK
TEMP STATIC
POINT (DegF) («vV\C)
1 114 -0.21
2 114 -0.16
3 114
4 115
S 114
6 114
7 114
8 114
9 115
10 115
11 115
12 115
13 115
14 115
15 '114
16 115
17 114
18 115
19 115
20 114
21 115
22 114
23 115
24 115
25 115
26 115
27 115
28 115
29 116
30 116
31 116
32 115
33 115
34 115
35 116
36 116
37 117
38 116
39 117
40 117
41 117
42 117
43 117
44 116
45 117
46 117
47 119
48 119
49 121
SO 121
51 119
52 121
S3 119
54 120
55 118
56 118
57 118
58 119
59 118
60 118
61 118
62 118
63 118
64 118
65 118
66 118
67 118
68 118
69 119
70 119
'71 119
72 119
AVG. 117 .0.19
07/22/99
08:15
14:35
40inchef
0.254 inche>
0.9968
1.6953
29.63 I\Hg
0.6355
360 rnnutei
256.119 act
236.604 decf
4.76 %
97.1 *
37.14 rVaec
19447 adm
17629 aefm
16790 dacftn
DP DH
(«vWC) (in.V\C)
0.32 1.30
0.30 1.20
0.31 1.20
0.30 1.20
0.34' 130
0.32 1.30
0.32 1.30
0.35 1.40
0.36 1.40
0.37 1.40
0.37 1.40
0.36 1.40
0.42 1.60
0.42 1.60
0.43 1.60
0.48 150
0.49 1.80
0.49 1.80
0.48 1.80
0.4S 1.80
0.46 1.80
0.46 1.80
0.46 1.80
0.48 1.80
0.47 1.80
0.46 1.80
0.47 1.80
0-46 1.80
0.47 1JO
0.47 1.80
0.41 1.60
0.42 1.60
0.42 1.60
0.28 1.10
027 1.10
0-27 1.10
0.39 1.50
0.40 1.60
0.40 1.60
0.39 1.50
0.40 1.60
0.39 1.50
0.39 1.50
0.40 1.60
0.38 1.50
0.38 1*3
0.37 1.40
0.37 1.40
0.38 1.40
0.38 1.40
0.37 1.40
0.41 1.60
0.41 1-BO
0.41 1.60
0.47 1»
0.48 1.80
0.48 1.80
0.46 1.80
0.46 1.80
0.47 1.80
0.46 1.80
0.45 1»
0.45 1.80
0.45 1.80
0.44 1.70
0.44 1.70
0.43 1.70
0.42 1*0
0.42 1.60
O26 1.00
O27 1.10
O27 1.10
0.40 1.57
B-35
METHOD 4 DATA
MP.1
IMP.2
MP.3
MP.4
MP.5
MP.6
XAD
TOTAL
S.G.
mrr.
(mD
0.0
100.0
100.0
0.0
351.0
551.0
791.5
FINAL
(mi)
187.0
100.0
101.0
0.0
355.5
743.5
850.0
NET
(jnO
197.0
0.0
1.0
0.0
0.0
0.0
4.5
192.5
58.5
METHOD 3 DATA
«O2
%C02
%CO
*N2
02+CO2
METER
VOLUME
(ocf)
735.000
661.355
862.051
991.815
^56.119
13.4
5.1
0.0
81.5
18.5
Md
Ma
Pa
Fd
MEA
29.35
28.81
29.62
1.471
165
METER TEMPERATURE
MLET
(DaoFl
89
85
101
102
102
103
104
105
105
105
105
105
106
107
108
108
112
112
112
113
113
113
114
109
113
113
115
113
113
113
114
113
114
112
112
113
104
111
. 113
114
109
113
114
114
114
113
114
115
115
115
114
114
115
115
114
116
116
115
116
•****446
116
117
117
118
117
117
116
118
118
118
116
117
OUTLET
(DeoF)
as
66
87
89
89
80
82
82
82
83
84
84
85
85
85
85
86
96
96
86
86
102
100
100
101
101
101
102
101
102
102
103
102
101
102
101
101
102
102
103
103
103
102
102
1O2
103
103
104
104
105
104
104
104
104
104
104
105
105
105
105
106
107
106
106
106
106
107
107
111
111
110
110
106
-------
B-4
Process Samples Field Data
B-36
-------
' Scrubber Solution Sample Collection
Plant;
Data;
Samplt CollectlQnPo1nt:_
Sarapl er;
Volume Collected:M±£Liii
COMMENTS:
SAMPLE NUHBER
iM JL- JL.'
UJT
A^.
W J
- r
J=_z_
UJ
TIME OF
SAMPLE
COLLECTION
VIJL
u
ROOM
, TEMPERATURE
pH
?d
ZL
y/Dc
£.-&**
^JL
a_L
?-.-$$
B-37
-------
' Scrubber Solution Sample'Collection
Plant:_£H2L
Date: 7-*t
Sample Collection Point:
Sampl eri_ Brig*
Volume
COMMENTS :
IOOO»L ue>-
SAMPLE NUMBER
VJO
J&«^^^u
-LIT
LJO
I- 1
UL
7-
3-
TIME OF
SAMPLE
COLLECTION
n i
4li
: Pi
1 •
J-L
ROOM
.TEMPERATURE
pH
B-38
-------
Scrubber Solution Sample'Collection
Plant:
Date:_
Sample Collection Point:
Sampl er;
Volume Cc 11 ortod• im«i uf.
COMMENTS:
1
SAMPLE NUHSEJ?
f-JL
ILL
1L5L
±JL
TIME OF
SAMPLE
COLLECTION
£12.
"- 17
11
iLiU
ROOH
- TEMPERATURE
pH
«
3/°C
5Y
. p
7.
B-39
-------
APPENDIX C
Calibration Data for Field Equipment
-------
e-i
Summary of Field Equipment Used During Field Program
C-1
-------
Table 9-2. Field Equipment List
Item
Comment
No.
ETS/
Battelle
Technician
Initials
PM/QAC
Initials
Air Sampling Equipment
MM5 Hardware
Meter Boxes (Consoles
and Pumps)
Umbilicals
Impinger Anns
Water Recirculation
Pumps
Impinger Caddies
Heater Boxes
Method 23 Towers
4-ft Effective Probes
Heating Jackets
Pitot Tips
Glass Liners
5/8 Teflon Unions
Glass Nozzle Kits
Thomas Pump for Pitot
Back Purge
Must have recent
calibrations
25 foot
Large
Nutech w/Large
Clamp
New Style
New Style
New - With Recent
Cals
Fit 4-ft Probe - New
New
Complete
Small
3
3
3
3
3
3
2
2
4
2
3
3
2
2
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
MM5 Glassware/Reagents/Recovery
Threaded Filter
Kt-,— • — ,.
-o1"
Double L's
Condensers
Teflon Frits, Extra
Caps and Rings
3
31' '
3
ETS
ETS
ETS
" ' 1
C-2
-------
Table 9-2. (Continued)
Item
XAD Traps
2-L Screw Impingers
1-L Ball Impingers
1-L Ball Impingers
Screw to Ball Adapter
Filters - Binder Free
Water
Silica Gel
Acetone
Methylene Chloride
Toluene
Hexane-Rinsed
Aluminum Foil
Teflon Tape
Teflon Probe Brush
Teflon Rinse Bottle
Glass Funnel
Meiai bpamia
Metal Tweezers
Ring Stands
Comment
Spiked, Prepped
Modified Stems
O-Ring - Standard
Stems
O Ring - Modified
Stems
Adapt 1 st Impinger to
Balljoint
Quartz - Cleaned
4-L Jug - HPLC Grade
Bulk
4-L Jug - Highest
Grade
4-L Jug - Highest
Grade
4-L Jug - Highest
Grade
Thick
1-in.Width
6-ft Length (clean
and in foil)
125 mL
In Foil
In Foil
In Foil
No.
10
3
3
9
3
12
1
4+
kg
4
4
4
10ft
6
rolls
2
4
4
j.
2
4
ETS/
Battelle
ETS/
Battelle
ETS
ETS
ETS
ETS
ETS/
Battelle
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
-»"^*0fl-,
£T»
ETS
ETS
Technician
Initials
PM/QAC
Initials
C-3
-------
Table 9-2. (Continued)
Item
Waste Jug
5/8-in. x 5/8-in. x 1/4-
in. 3 -way Stopcocks
Timer/Stopwatch
1 -L Erlenmeyer Flasks
250-mL Graduated
Cylinders
1000-mL Graduated
Cylinders
Petri Dishes + Lids
(Container 1)
Front-Half Rinse Catch
Bottle (Container 2)
Front-Half Rinse Catch
Bottle (Container 3)
Back-Half Rinse Catch
Bottles (Container 4)
Back-Half Rinse Catch
Bottle (Container 5)
Impinger Liquid Catch
Bottles (Container 7)
Impinger Rinse Catch
Bottle (Container 8)
Silica Gel Containers
(Container 9)
Triple Beam Balance
«^ « fri rray^ +f\ *•
Comment
4L
Soak Configuration
Clean Glass
Clean Glass
Clean Glass
Clean glass
500-rnL Amber Glass -
Teflon-lined Cap
250-mL Amber Glass -
Teflon-lined Cap
1000-mL Amber Glass
- Teflon-lined Cap
1000-mL Amber Glass
- Teflon-lined Cap
1 000-mL Amber glass
- Teflon-lined Cap
250-mL Amber Glass -
Teflon-lned cap
500-rnL Nalgene
Bottles
No.
2-3
3
2
2
tf
2
12
12
12
24
12
24
12
12
2
1.
ETS/
Battelle
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
^TS
Technician
Initials
PM/QAC
Initials
i
--— - -- -i
i
|
i
i i
... _|
T ~ "~-~1
L - - J
C-4
-------
Table 9-2. (Continued)
Item
Comment
No.
ETS/
Battelk
Technician
Initials
PM/QAC
Initials
Methods 3A/10 Hardware
CO Analyzers
O2 Analyzers
CO2 Analyzers
3-4 ft CEM Probes
CEM Probe Heaters
CEM Filter Assemblies
CEM Heaters
Silicon Heat Strips
3-4 ft Heated CEM
Jumpers
Condensers
Peristaltic Pumps
200-ft Dry Sample
Lines
Propane CGA Low Gas
Propane CGA Mid Gas
O2/CO2 Mid Cal Gas
(yCOa High Cal Gas
CO 3000 ppm span
JZero Nitrogen
Spare CEM Filters
I Spare Masterflex
Tubing
10,000 ppm Span
3-4 ft
Heated 3/8-in. Teflon
Variable Speed or
Steady-Rate
60-90 ppms 800+ psi
124.6 ppni, 800+ psi
10-15% OW-12%CO2
20-25% O2/I6-20%CO2
30% - -900 ppm
60% -~1 800 ppm
100%- ~3000ppm
1000+ psi
2
2
2
2
3
2
3
2
3
3
2
2
1
1
1
1
1
each
1
5
10'
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ITS
KS-.
ETS
ETS
C-5
-------
Table 9-2. (Continued)
Item
ETS Fittings Box
Tubing Box
GEMS Computer
Comment
Stocked
Stocked
CARS Loaded
No.
1
1
1
ETS/
Battelle
ETS
ETS
ETS
Technician
Initials
PM/QAC
Initials
Scaffolding
Four 5-ft Bucks
Safety Rails, Running
Boards, Toe Boards,
Ladder
Must form 4x8 "L"
with Two Sections
As Needed
ETS
ETS
|
Miscellaneous Hardware and Equipment
Rope
Duct Tape
2x6x8 Lumber
2x4x8 Lumber
Nails
C Clamps
Hand Track
Extension Cords
Extension Cords
Power Strips
Stove Switch
3-Way Plugs
.Jbol Boxes
Ice-Oaly Coolers
Radios and Chargers
8-inch
100ft
25ft
With Saw and
Hammer
50ft
4
rolls
2
4
4
1
5
2
6
3
2
2
3
4
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
ETS
£35
ETS
ETS
J
I
i
__ -.,.„, . i
— .._„, ._ ^
i
C-6
-------
Table 9-2, (Continued)
Item
Data Computers
Printer
Sample Labels
Comment
Paper, Cable, and
Spare Cartridge
Both Air and Process
Samples
No.
2
1
ETS/
Battelle
ETS
ETS
ETS
Technician
Initials
PM/QAC
Initials
Process Sampling/ Analysis
Large Cookie Sheets
Teflon Scoop
Large Separatory
Funnel
Ring Stand For Large
Funnel
Scrubber Water Sample
Jars (Subsamples)
Scrubber Water Sample
Jars (Composites)
Scrubber Water Sample
Jars (Composites)
Sludge Sample Jars
Sludge Sample Jars
pH Meter
New Coolers for
•"Samples
Blue Ic*
Gallon Zip-Loc Bags
Aluminum, Hexane
Rinsed
Capacity
2L
250-mL Amber Glass -
Teflon-lined Cap
1000-mL Amber Glass
- Teflon-lined Cap
250-mL Amber Glass -
Teflon-lined Cap
1000-mL Amber Glass
- Teflon-lined Cap
250-mL Amber Glass -
Teflon-lined Cap
Calibration Standards
Packs
Boxes of 100
4
3
2
1
120
24
24
12
12
2
12
36
3
Battelle
Battelle
Battelle
Battelle
ETS
ETS
ETS
ETS
ETS
ETS
Battelle
Battelle
Battelle
C-7
-------
Table 9-2. (Continued)
Item
Thermometers for
Coolers
Comment
No.
12
ETS/ •
Battelle
Battelle
Technician
Initials
PM/QAC
Initials
C-8
-------
C-2
Equipment Calibration Forms
0-9
-------
ITS, INC.
MET1R CONSOLS CALIBRATION FORM
Contract No. 9S-4B7w2
Job I.D.
Meter Box No.: 12
Delta Hi 1.3953
Qamma: 0.9968
Analyst:
CaliferSCTon/D&tei 07/14/99
Test Meter No. 9548
Barometric Presaure 29.02
Print Date 07/14/99
QA/QC Check:
Previous Calibration Dates 03/04/99
Previous Gamma: 0.9792
Temp Check
Ice H20
degrees F
^_
Boiling H2O d>/3 degrees F
Run
P1
2
3
4
5
.
f
Orf(lnitial) Final (Volume |lnit|Finl| Test (Initial
Setj Teat Teat j Test j Temp | Temp j Temp j Box
I J I ! 1 1
1 1 ! 1 1 1
0.5(644.054 654.557) 10.503 | 76 .0 | 76. 0| 76 .00) 88.678
1 1 III!
1
1.0(654.956
1
I
1.5)665.632
1
1
2.0)677.242
J
1
2.5)688.435
, 1
1
3,05698,803
1
1 III 1
665.408) 10. 452(76. 0)76. 0(76. 00| 99.603
1 1 1 L 1
| i III 1
677v 052 1 11 . 420 | 76 . 0 | 77 . 0 ( 76 . 50 | 110 . 350
1 1 1 I 1
1 1 1 1 1
688,220) 10. 97S| 76. 0)76. 0)76. 00 (122.108
1 1 I.I 1
i 1 1 I 1
698. 494 j 10. 059 (76. 0(76. 0(76. 00 (133. 495
1 1 1 1 1
1 fill
709.236! 10. 433 | 76, 0 I 76. 0| 76. 00 j 144. 186
. i ._.!... 1 if
Final (Volume (I-I |I-O
Box I Box JTempj Temp
1 II
1 1 1
99.208| 10.530(78.0(78.0
1 II
1 1 1
110.123) 10.520(81.0(79.0
I II
1 1 i
121. 916 | 11.566(85.0(81.0
1 1 1
1 1 1
133.390) 11, 282'|88. 0)82.0
1 1 1
1 1 1
143.764) 10.269(89.0)83.0
1 1 1
1 1 1
154.750) 10.564(90.0(84.0
1 1 i
F-I |F-O (Temp (Time (Delta H| Gamma
TempJTempj j j j
II 1 .. 1 1
1 1 1 1 1
78.0(81. 0(78. 75)25. 0 | 1 . 65017 | 1 . 00128
1 III 1
•II II 1
81.0)85. 0(81. 50 (17. §(1.62469 1 1,00119
1 1 II 1
1 1 1 1 1
82. 0(88,0 1 84. 00) 16. 0)1.70177 (0.99739
1 1 1 1 1
1 1 1 1 1
84. 0(90. 0(86. 00 (13. 5 (1.73840 JO. 98621
II II i
11 II 1
84. 0(91.0 [86. 75) 11. 0(1. 71600 (0.99291
1 1 1 1 1
1 1 1 1 1
8 5 . 0 | 92 . 0 | 87 . 75 1 10 . 5 ( 1 . 74097 1 1 . 00164
(III 1
-------
C-2-1
Dry Gas Meter, Pitot Tube Calibrations
(MM5 Field Train)
-------
E.7,8. IMC.
HE7ES CONSOLE- CSLIBftfiTIfe' FORH
HK7i CAL-K
1
2
3
4
S.
6
7
i
5
10
11
Reference The
»pm.u»
35
181
282
3iH
A3?
5C5
we
788
S62
912
•raocQUj*}* 1
$
35
133
2IS
3i5
•^82
51?
SiS
?84
BB2
215
l*ifffff«?
s.eee
B.886
-8.357
-8.453
-8.3S4
-8.233
••i.ESS
-S.E&3
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C-12
-------
E.T.S. INC.
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C-13
-------
E.l.S. IHC.
CBLIBfcATIC*
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C-14
-------
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C-15
-------
E.T.S. INC.
METER CONSOLE CftLIBftPTICN FORK
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C-16
-------
£.7.S. IE.
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C-17
-------
t.T.S. INC.
KSTtF; C3HSOIE CfiLIffirtTION FORK
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C-18
-------
P1TOT TUBE CfiLIBRfiuGM WSKSHEZT
Oc.ts; 85/21/95
Pitot Tubs Idsr.tificaiion *:
Calibrated By: J.KcKenr.a
SIDE "3" CSLIESSTION
dilka D sic. delta P
RUN NO. (in. Water! (in. itetar) Cp (s) Cpis) -
fivg. Cp for Side A - Cp(fih C.S365
SIDE "B" CftLIBRflTIffi
delta P std. deite P is) DE'JIftTION
Rtfi NO. ' tin. yattr) (in. Mater; Co (s; Cpisi - Cp«E)
i 8.41 E.57 3.S25& OS'S
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fivj. &»v. 5ioE "ft"; 3."8I£-i" ifiilawable Liiit =•!
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Cpim-Cp(6): i.BvlH (SUowtl* LUi: =(
Cp'for Pitot t £23: 0.3355
CciitnU:
C-19
-------
C-2-2
Raw Field Data Sheets - Post Test Meter Box Field Audit
C-20
-------
TABLE C-1 - Post-Test Calibration
.Alternative Method 5 Sampling Train - Dry Gas Meter Box
Cincinnati MSD Incinerator Test Program
METER BOX ID ETS-12
Meter Box dH@ 1.6953 in W.C.
Meter Box Gamma 0.9968
Avg. Cal. Check (Yqa) 1.0391
Percent Error 4.23 %
RUN NUMBER AUDIT-RUN 1
Barometric 29.63 in Hg
Sample Run Time 20 min
Metered Volume 15,888 dcf
Avg. Meter Temp. 113 F
572.9 R
Average dH 1.9 in W.C.
Average Sqrt (dH) - 1.38
Dry Molecular Wt. (Md) 28.84 ib/lb-mole
Cal Check (Yqa) 1.0470
RUN NUMBER AUDIT-RUN 2
Barometric 29.63 in Hg
Sample Run Time 20 min
Metered Volume 12.878 del
Avg. Meter Temp. 116 F
575.6 R
Average dH 1.3 in W.C.
Average Sqrt (dH) . 1.14
Dry Molecular Wt. (Md) 28.84 Ib/lb-moie
Cal Check (Yqa) 1.0718
RUN NUMBER AUDIT-RUN 3
Barometric 29.63 In Hg
Sample Run Time 20 min
Metered Volume 10.936 dcf
Avg. Meter Temp. 110 F
570.4 R
Average dH 0.82 in W.C.
Average Sqrt (dH) 0.9T*
Dry Molecular Wt. (l*",Cj 2E.34 IL/Ib
Cal Check (Yqa) 0.9985
C-21
-------
EF-A MODIFIED METHOD tUftO tSaglHETIC S*HPUH6 PATft SHEFT
Ao0,f —
PAGE J _ OF _2i_
FACILITY; £
START TIMEs
TEST LOCATION:
DATE:
POLLUTANT:
Rim I.O.: Qj/A - H - R I
POINT
SAMPLE
TIHE
TIME
STATIC
STACK
TEHP.
STACK
aP
METER
VOLUME
ft3
DGH TEW.
IHLET
BCW TEW.
OUTLET
XAD
EXIT
PROSE
TEHP
IMP
EXIT
FILTER
TEMP.
VAC
r
^7/5
If
CHAIN Of.CUSTCCY:
CONTAINER
\
J,
f
SAMPLE l.D.
\ /
\ /
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/ XJ
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VACUUM
RATE
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IMPINGER CONTENTS:
IMPINGER
V
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«
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INITIAL
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A-
/ X
C-22 •
FINAL
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NOZZLE *
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BOX l.D.
GAHHA y
c Ha
FILTER
TECH.
MA
-------
F05T- rS>T
EPA HQPIFIED METHOD 0010
SAMPLING DATA SHFFT
PAGE "^- Of 3
FACILITY:
TEST LOCATION:
DATE:
END TIKE:
POLLUTANT:
RUN I.D.: t>CA\ • H
PO!MT
SAMPLE
TIME
o
5
10
^
W
TIME
^l4
Tfej 1 «"
STATIC
<^5"
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TEHP.
STACI:
iP
KETER
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^7
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TEMP
.
IMP
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LEAK CHECK:
CONT.MUER
\
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,
/
S.AWPLE I.D.
/
/
FT /
\ /
A
^ \
"Y
\
DESCRIPTION
./t
/
*
"
1 VACUUM
RATE
IHPIMGER CONTEXTS:
IMP1NGER
*"^X,
#2
«3
. -•*/
'^
*6
INITIAL
S
V
/ \
C-23 •
FINAL
*
^
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NOZZLE 0
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BOX I.D.
GAMMA
FILTER
TECH.
WA
IZ
VJfl,
-------
EPA MODIFIED METHOD 0010 IgorittFMC .SAHPIHIC DATA SHEET
PAGE
FACILITY:
TEST LOCATION:
DATE:
END TIME:
: (O
POLLUTANT:
RUN I.D.:
- M - R
POINT
C?
5
10
tf
3fl
SAMPLE
tJME
JSSID
t^to
^
t
TIME
STATIC
STACK
TEMP.
•
STACK
aP
*
HETER
eH
n
i.-?
i,^
t>j
/o
DGK VOLUME
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OiO.3^
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OUTLET
l/^
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//^
1',?'
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TIMP
.
IMP
EXIT
FILTER
TEMP.
VAC
CNAIN OF CUSTODY:
LEAK CHECK!
CONTAINER SAMPLE I.D.
DESCRIPTION
(VACUUM
M7E
IMPINGE! CONTENTS:
IMP I USER
fl
#2
95
(K
•5
*6
INITIAL
C-24
FINAL
•
,
NOZZLE C
mar f
BOX I.D.
GAMMA y
era
FILTER
TEC«.
-------
C-2-3
Cylinder Gas Audits Summary Sheets
- O2, CO2, CO
-THC
C-25
-------
TABLE C-l - Cylinder Gas Audit Results
Reference Method Analyzers
CEMS Information
Analyzer Type
Manufacturer
Model Number
Serial Number
Span Value/Range
Cylinder Gas
Information
Certified Audit Value
«y
Cylinder ID. Number
Type of Certification
Certification Date
Audit Results
Testl
Test 2
Test3
Average Response
(CJ
Accuracy (A)*
Oxygen
Teledyne
320A
102469
25% dv
Audit Point 1
14.2 %dv
AAL9476
Protocol 1 -
04/07/99
July 22, 1999
(%dv) Time
14.10 07:18
13.94 07:26
14.25 07:32
14.10 %dv
-0.7 %
Carbon Dioxide
Horiba
PIR-2000
91-20-15
20% dv
Audit Point I
5.93 %dv
AAL9476
Protocol 1
04/07/99
July 22, 1999
(% dv) Time
5.93 07:18
5.94 07:26
5.90 07:32
5.92 %dv
-3.5 %
Carbon Monoxide
TECO
48H
48-25815-222
6000 ppmdv
Audit Point 1
467.0 ppmdv
ALM008858
Protocol 1
02/08/99
July 22, 1999
(ppm) Time
443,8 07:22
444,4 07:30
444.8 07:36
444,3 ppm
-4.9 %
C-26
-------
TABLE C-l - Cylinder Gas Audit Results
Hydrocarbon Analyzer
CEMS Information
Analyzer Type
Manufacturere
Model Number
Serial Number
Span Value/Range
Cylinder Gas
Information
Certified Audit Value
(Q
Cylinder I.D. Number
Type of Certification
Certification Date
Audit Results
Testl
Test 2
TestS
Average Response
(CJ
Accuracy (A)*
PRE-TEST AUDIT
Total Hydrocarbon
Horiba
MPA-510
57034007
300 ppmwv
Audit Point 1
86,6 ppm
CC90980
Protocol 1
04/22/98
My 19, 1999
(ppm) Time
85,9 1152
85.9 11:28
85.9 11:37
85.9 ppm
-0.8 %
Audit Point 2
124.6 ppm
CC94773
Protocol 1
10/05/98
July 19, 1999
(ppm) Time
124.1 11:17
•124.1 11:24
124.1 11:33
124.1 ppm
-0.4 %
POST-TEST AUDIT
Total Hydrocarbon
Horiba
MPA-510
57034007
300 ppmwv
Audit Point 1
86,6 ppm
CC90980
Protocol 1
04/22/98
July 22, 1999
(ppm) Time
82.8 14:47
81.0 14:57
78.1 15:11
80.6 ppm
-6.9 %
Audit Point 2
124.6 ppm
CC94773
Protocol 1
10/05/98
July 22, 1999
(ppm) Time
120.3 14:43
1-19.1 14:57
114.6 15:03
11 8.0 ppm
-5.3 %
C-27
-------
Month
TABLE C-1 - Battelle Calibration Gas Cylinder Audit
Reference Method Analyzers
Raw CARS data for calibration gas cylinder audit
Cincinnati MSD Incinerator Test Program
Day
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
7
Year
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
22
'22
22
22
22
22 .
22
22
22
22
22
22
22
22
22
Time
99
93
98
99
99
99
99
99
99
99
99
99
99 .
99
99
99
99
99
99
99
m
99
99
99
99
99
99
99
99
99
C02
%dv
711
712
713
714
715
716
717
718
719
720
721
722
723 .
724
725
726
727
728
729
730
731
732'
733
734
735
736
737
738
739
740
0.15
0.13
0.13
0.13
0.12 Z
0.14
5.27
5.93 C'
5.78
0.53
0.15
0.13
0.12
222
5.88
5.94 C
5.33
0.34
0.15
0.13
424
5.90 C
5.94
1.35
0.16
0.13
0.12
0.12
0.13
0.14
CO
ppmdv
1820.00
590.00
8.05
6.32
5.87 Z
6.21
520
-621
-6.04
162.60
441,60
443.80 C
44420
430.30
96.30
-2.52
-5.59
206.00
441.80
444.40 C
35020
18.73
-5.48
106.40
428.70
444.80 C
445.10
446.00
445.60
445.40
02
%dv
0.05
0.04
0.04
0.03
0.03 Z
0.19
12.94
14.10 C
12.95
0.69
0.07
0,04
0.03
5.62
13.74
13.94 C
11.97
0.37
0.07
0.05
10.98
14.25 C
14.14
2.30
0.10
0.05
0.04
0.03
0.12
0.86
Z
C
zero calibration gas
cylinder gas audit
C-28
-------
C-2-4
Raw Field Data Sheets - Cylinder Gas Audits
- O2, CO2, CO
- THC
C-2i
-------
Marker Description Display Average
A . Data was Absent from original raw data file. /
C CYLINDER GAS AUDIT / /
D DELAY FOR SAMPLING TRAIN TROUBLESHOOTING /
H HIGH CALIBRATION GAS • /
L LOW CALIBRATION GAS ' /
M MID CALIBRATION GAS /
P SAMPLING POINT / /
R RESPONSE TIME , /
Z 2ERO CALIBRATION GAS /
* Data was not used in calculated parameter averages.
C-30
-------
METROPOLITAN SEWER DISTRICT
SEWAGE SLUDGE INCINERATOR
CALIBRATION GAS CYLINDER AUDIT
JULY 22, 1999
Starting
07-22-99
Time '
07:11
07:12
07:13
07:14
07:15
07:16
07:17
07:18
07:19
07:20
07:21
07:22
07:23
07:24
07:25
07:26
07:27
07:28
07:29
07:30
07:31
07:32
07:33
07:34
07:35
07:35
07:37
07:38
07:39
07:40
02
%dv
0.05
0.04
0.04
0.03
0.03Z
0,19
12.94
14. IOC
12.95
0.69
0,07
0.04
0.03
5.62
13.74
13.94C
11.97
0.37
0.07
0.05
10.98
14.25C
14.14
2.30
0.10
0.05
0.04
0.03
0.12
0.86
C02
%dv
0.15
0.13
0.13
0.13
0.12Z
0.14
S.27
S.93C
5.78
0.53
0.15
0.13
0.12
2.22
5.88
5.94C
5.33.
0.34
0.15
0.13
4.24
5.90C
5.93
1.35
0.16
0.13
0.12
0.12
0.13
0.14
CO
pptndv
1820.00
590.00
8.05
6.32
5.87Z
6.20
5.20
-6.20
-6.04
162.60
441.60
443. 80C
444.20
430.30
96.30
-2.52
-5.59
206.00
441.80
444. 40C
350.20
18.73
-5.48
106.40
428.70
444. 80C
445.10
446.00
445.60
44i,40
C-31
-------
CYLINDER GAS AUDIT (CGA)
DATA FORM
Date of Audit.
-FACILITY INFORMATION
Facility Name:
Address:
Source ID:
CIMS INFORMATION
Analyzer Type
Sampte Location:
7
Manufacturer. J.
Model No.:
Serial No: [^E> II
SpanVWue:
Range: .
CYLINDER GAS INFORMATION
Audit Point 1 fanfcrt 2 (units)
CertifiedAudHValue(CJ: /V.)_ ( %/i^ __^ (
CyGnder ID No.:
Type of Certification:
Certification Cite (f..f I/ ^ f
AUDIT RESULTS
Audit Point:
T«t1: /¥.
Test2 /?•
Testa . / 7. »5 | 76 ^ V I • $**•_ ( _.:.. 1
Average Response (CJ: iH'fa I %*"* { |
Accuracy (A): ' CP. /V( % } ( %
Equation 1-1 from 40 CFR 60 Appendix F. "Cafcutotfw* for GEMS Daft Aeairtcf
,f =<£*££•.)„ 100
OEMS must meet either of the following, %»Wchever is greater
1} +/-15 percent of the average audit value
2)*/-5ppm " C-3k
-------
CYLINDER GAS AUDIT (CGA)
DATA FORM
Date of Audit 7 A> / *? '
FACILITY INFORMATION ; I_I
Facility Name: C /x>-c.>\
Address:
Source ID:
GEMS INFORMATION
do.
Analyzer Type: _
Sample Locatioa*
Manufacturer
Mode! No.: Pit- MO*
Serial No:
Span Value:
Range:
CYLINDER GAS INFORMATION
Auefit Point 1 (untA 2 tonftrt
Certified Audit Value (C J:
Cylinder ID No.:
Type of Certification:
Certification Date:
AUDIT RESULTS
Audit Point . 1 lunK& Sim
Testl: GQl f%/0 47: If
TestZ *T Qf
Testa y,^..<>
Average Response(CJ: 5~fl)*. (?*
Accuracy (A): ">-?T f % ^ ^^^ LJL
Equation 1 -1 from 40 CFR 60 Appendix F, "CateufeSons Ibr OEMS Data Accuracy
CEMS must meet either of the following, whichever is greater:
I)*/- 15 percent of the average audit value - . .
2) */- S ppm C-i o
-------
CYLINDER GAS AUDIT (CGA)
DATAFORM
Date of Audit.
EACILTIT INFORMATION • '
Facffity Name: {. ( *
TestS: .Hlilsjf lff*J*\ D~l - 3J ( I :
Average Response (CJ: HH.*?- 3 (/h^f^
Acasacv
-------
FACILITY INFORMATION
CYLINDER GAS AUDIT (CCA)
DATA FORM
Date of Audit "7
/'9/ra.
Facility Name:
Address:
Source ID:
GEMS INFORMATION
Analyzer Type:
Sample Location:
Manufacturer:
Model No,:
Serial No:
Span Value:
Range:
CYLINDER GAS INFORMATION
'
Audit Point
Certified Audit Value (C J:
Cylinder ID No,:
Type of Certification:
Certification Date:
AUDIT RESULTS
1 (units}
/ /
Audit Point
Testl:
Testi
Test3:
Average Response (CJ:
AccuracjL(A):
1 ((/nfel fimo
2 footed tfrrw
t
»»
( %
Equation 1 -1 from 4Q CFR 60 Appendix F, 'Csteufafions ftv GEMS Data Accuracy
CEMS must meet either of the following, whichever Is greater:
1)*f-15 percent of the average audit value
-------
FOST- />
CYLINDER GAS AUDIT (CGA)
DATA FORM
Date of Audit ^
FACIUTY INFORMATION
FaeSBy Name:
Address:
Source ID:
CEMS INFORMATION
/C*GO
JFTT
Anaiyzer Type:
Sample Location: /
'\
Manufacturer:
Model No.:
Serial No:
Span Value:
Range: ;
r-}o«i
Co I
CYLINDER GAS INFORMATION
Audit Point
Certified Audit Value (C J:
Cylinder 10 No.:
Type of Certification:
Certification Date:
Auorr RESULTS
fi/nfet
(units)
g
Audit Point
TesM:
Test 2
Testa:
Average Response (C_):
AccuragyJA):
ffme
2 fonfttf
111.1 ,*>n\
TS.O
-IT/
,y 5- -
Equation 1-1 from 40 CFR 60 Appendix F. 'Calculations far C£MS Data Accuracy
CEWS must meet either of the following, yrhichevief is greater
1)+/-1Spercentoftheaverageauditvalue
-------
APPENDIX D
Sampling Logs and Chain-of-Custody Records
-------
-------
D-l
Daily Sampling Logs
D-1
-------
Rovblonl
03/17/94
Client:
ETS Contract N x:
ETS, Inc.
FJELD LOG
NASh
Date
Client Contact:
Acknowledgement:
Task
-Start
Time
End
Time
Hours
On
Scope?
Reason
JOtCp
*_
-£
Ffaa.
1*0
lOOti
to titijae
IPtOO
II1C9O
Uft
H'-CO
3-S
-------
Client:„ &=£ /'
ETS Contract No.:
ETS, Inc.
FIELD LOG
03M7/94
Client Con tact:
Acknowledgement:
/bl-f^t
I"7'.OO
-ser.jp
|-r:oc>
so too
3L
A**r.
O7«!>O
0*30
Z-5
«?HBC< ,
2-S
-------
Revision 1
03/17/94
f
Client:.
ETS ContractNc.:
ETS, Inc.
FJELD LOG
Client Contact:
Acknowledgement:
Date
Task
Start
Time
End
Time
Hours
On
Scope?
Reason
r
y
FPC
27:00
V
X
KI so— /*»"»
-------
ETS, Inc.
FJELD LOG
03/17/94
Client: ET»=g\ j\
ETS Contract No
Client Contact:
Acknowledgemenl:
17 '!€
tpfl-'S"
'•7s
3_
E-rs
T
1 0. 1
Ib5r~
icons
Y
V
-------
D-2
Chain-of-Custody Records
D-6
-------
'/£>/£>
.'*'•*' " '
CONTRACT NO: _2! )-4e»7-wz.
JOB I.D.:
FIELD SAMPLE LOG
ETS. INC.
TEST METHOD: ^A< C*F»«D
SAMPLE
NO.
CONTAINER
NO.
OTHER
I.D.
TEST
LOCATION
RUN I.D.
SAMPLE
TYPE
TOTAL
SAMPLE
VOLUME
ALIQUOT
VOLUME
INITIALS
DATE
COMMENTS
S-Rl- lol
M-3O-MH
D
•M
T-R.I —
CMUC.
xt/V "^ '»
CHAIN
OF
CUSTODY
Collects 3 by:
Relinqui jhed
Rehnqu'shed by:
uate/l
£
-eT5
Received by:
Received by:
Datemma
Received by:
Daten"ime
Date/Time
Date/Time
-------
FIELD SAMPLE LOG
ETS. INC.
CONTRACT
JOB I.D.:
TEST METHOD:
SAMPLE
NO.
CONTAINER
NO.
OTHER
I.D.
TEST
LOCATION
RUN I.D.
SAMPLE
TYPE
TOTAL
SAMPLE
VOLUME
ALIQUOT
VOLUME
INITIALS
DATE
COMMENTS
—.-K.Z- —ae<»\
JbJ*L
-tew i
*
Collecte by:
j CHAIN
0F
JCUSTODY
Relinqu shed
Relinqu shed
Relinqu shed by:
Date/Time
Received by:
Received by:
Received by:
Date/Time
Date/Time
-------
FIELD SAMPLE LOG
ETS. INC.
CONTRACT ;>'0:_2 -
JOB I.D.: ....... __<^r>r»gM*» *f
TEST METHCD:_£jc
MS
J
SAMPLE
NO.
CONTAfMER
NO.
OTHER
I.D.
TEST
LOCATION
RUN I.D.
SAMPLE
TYPE
TOTAL
SAMPLE
VOLUME
ALIQUOT
VOLUME
INITIALS
DATE
COMMENTS
— IM.*vS
*/*'/«?)
V
ft
tf
•70
u
.y—
ColleGtedby: 444
CHAIN
OF
CUSTODY
Relinquished by?
Relinquished
Relinquished by:
Date/Time
Received by: ^
Date/Time
Received by: .
Date/Time
Datemme
Received by:
Datemme
-------
FIELD SAMPLE LOG
CONTRACT riO: 3 )*- 4G7- wz.
JOBI.D.: <
*"""" - **s^<*"«T'^
-m==J1,fP" CW**. '^"•1P™I I I *-^|._.r*
ETS. INC.
- •
TEST METHOD: N *>,*,*» rf^r
c
c
j
, '
SAMPLE
NO.
fs^ED-rs^m
,*«'-•
M?b-A>VH
,
f*ifloi»vk- T*^ * 4o£{
>W5| - /«OS
s-**i - i>
Date/Time 7/^.»/,. ^jj/
Date/Time '
TOTAL
SAMPLE
VOLUME
KIX\
IS^cal-)
"
1 25/^.1
^K>A-)
'•f^' f
^*5t>^5^)
MA
4eaA/l
'
2CS*J
^
ALIQUOT
VOLUME
INITIALS
-A.-\, --.-
/n^-
A-UV-,
M \#-
A*S\
4/trt
AVV
xwt^t
1
Received by: d&,£*iz* jff&£? «L
Received by: *£}&+& n.&i*ri
Received by:
DATE
T/ez/^q
1
•>/*c/9».
'
T/W'W
.
T/»*A>.
-T/^Z^q,
l/ttfft.
•vhzfa
lj"*^h^-
'
COMMENTS
Date/Time 7- *F^ >^e>
Date/Tlme iM^-f f /J|£;
Date/Time
-------
FIELD SAMPLE LOG
ETS. INC.
CONTRACT NO:
JOB.I.D.:
TEST METHOD: Mca.iw H5
SAMPLE
NO,
*»3B-Avn
fiat*-***
•W*C>i*w>y
*w«t>w*A,3
"'^SO-MrfftS
m.wo*"" *fo*\ "5*"
*
v
CHAIN
. Qjr
CUSTODY
CONTAINER
NO.
. ^_ dOfci**' i <&o 1
^•- fClMn^ fcdC*^3C»
-W-fctxs
-fsll~l«xl
_*at -*>os
«%\ ^jcMoa
i *>p
OTHER
I.D.
TEST
LOCATION
vn~ &
\.^.
sf
v «
• „ *
•X.V
' ,
IColIected by; /^.A. V-Wj.
Relinquiahed byK^i^r^--/^ OrS"
Relinquished byLi1 [jC^CJ^f^yf^/
(Relinquished by: i
RUN I.D.
***&£*
*"
v^
«r
".
'/
•
SAMPLE
TYPE
Flense
^^^
U^-^rrC^
AceroHE
^siss^
t»u«^e.
•>.
Date/Time?/*^ i^uo
Date/Time -w^i/^-iotQb
Date/Time-^/?*/ 5 ^ /j*
Datemme
TOTAL
SAMPLE
VOLUME
NA
MA
<*-
^=_^
VA—
44A-
,4^ /
(W^T^**
Xli pjr^™
1 A/Mh
Received by:\^]^PJSk/mJJri]
Received by: VJLA. Jwt'jt U
Received by:
DATE
"7/'?J^9
~?-/«^99
•7/1^ ay
tfofai
-I/9/&
-r/\
-------
'V-ieL-o ~E^CAM ^ I FIELD SAMPLE 1
ETS.INC.
CONTRAC
JOBI.D.:£
i
TNO: J^4e7-uaz
_IMC«MAM rl f*-VSl!^
TEST METHOD: n^rt«to M«s
SAMPLE
NO.
MSC>~I^A
fMtp^AV
1^4^!^ ™iM»
»««&-.>
J^_ %.
l-vio .. JM
f^or,^
/VU»t>-AA
i
• >
.
r~™ ~~~*~~~i
L^ CHAIN
OF
USTODY
CONTAINER
NO.
VS— FQt- «30|
is-ffei- iva
^T-PBI-I3«SS
k«K«i-f«l "ISOii
Ats-c&i-rses
^C-H^-l^dg,
-,5-fTa,- i^&7
n6-nsi-\-ic=e
!*•
.
-
OTHER
I.D.
TEST
LOCATION
L*A/T~ Co
/A-ClMSWfttfZ.
NV
NV
*>
**'
^ •.'
^
(
.
*
Collected by: 44-|-fe,-t As>'M *****&
Relinquished by:/'^^/^_^r5
Relinquished by:
Relinquished by:
RUN I.D.
l™*"l^5L»O
(^iy^/sjig
"
"
•'> "
*
»r
^
SAMPLE
TYPE
PlUTQt.
#££*££**
"T^rfjitffcj^
fl/^ilHf t VftC-P
BTsyi^r
XXt,«S^
oT^i^c
CEr^Pi*jCe<.
^^"l
f
Date/lime ~\]u]Q
Date/Time 4fti^t^o^
DatefTime '
Date/Tlme
LOG
4
•.
V
TOTAL
SAMPLE
VOLUME
KJA
aoB^foj1)
//O f«5*)
0QD(«5l-)
4co ^j^
KiA
ZffC^J
ZGC»J
ALIQUOT
VOLUME
INITIALS
/U\
A44-
/\Ajf
^vtt-
AA-V-
AArt
M4-
A^rt-
Received by: |^i^/_Vifc/dk
Received by: s£i>Lf >**v— -
Received by:
DATE
7/i.M
-*/*•'&)
7/ZI/9J
7fel*»
-l/Xjkft
ifa/99
-'A 1/9*
COMMENTS
>.
Date/Time ^ ,»"^J «4/Li*l ItL
Date/Time ^ii-'u* /t/iMj^
DateATime
-------
FIELD SAMPLE LOG
ETS. INC,
CONTRACT
JOB I.D.:
TEST METHOD:_£V
SAMPLE
NO.
CONTAINER
NO.
OTHER
I.D.
TEST
LOCATION
RUN I.D.
SAMPLE
TYPE
TOTAL
SAMPLE
VOLUME
ALIQUOT
VOLUME
INITIALS
DATE
COMMENTS
MO. I
11J f
torn
ft
it
200 J
w
ll
CHAIN
OF
CUSTODY
CoIlecteaDy:/
Relinqu shed
Relinqu shed
Received
Relinqirshed by:
Received by
Date/Time
Received by
Date/Time
Date/Tim©
-------
FIELD SAMPLE LOG
ETS. INC.
CONTRACT MO:J25
JOB I.D^
TEST METHOD: M.
SAMPLE
NO.
CONTAINER
NO.
OTHER
I.D.
TEST
LOCATION
RUN I.D.
SAMPLE
TYPE
TOTAL
SAMPLE
VOLUME
ALIQUOT
VOLUME
INITIALS
DATE
COMMENTS
NA
*•**£»-
— izoz.
**
TL
121
-paz. —
H
2LQ0+J
il
Collected
CHAIN |Relinqui!;hed
OF ||Relinquibhed
Dae/Time ~>l
Date/Time >//^
Received by
Received
CUSTODY Relinquii ;hed byr
Date/Time
Received by
-------
Columbus Dillon
505 .ong Avem, I
Columbus, Ohl > 43201-2693
(614) 42-M247
PCDD/PCDF/PCR
HUUU/HUDh/PUB
CHAIN OF CUSTODY RECORD
Client:
Project Description:
Client ID
Number
Date
Sampled
TJirte
Sampled
Location
No. Containers
Remarks/Condition Upon Receipt
U"
7/2
-2. »
\5
9
o
*»•*/>*
-------
Columbus DM ion
SSLKK
(6H) 4J-M2-7
Cllenl:
CHAIN OF CUSTODY RECORD
Pro|er.| Description
S Bie
Client ID
Number
Dale
Sampled
Time
Sampled
Location
No. Container!
Remarks/Condition Upon Receipt
t&oo .c. c
«c_
CC
O) .
Relinquished by (Signature)
Date
?/a/??
Time
Received by (Signature)
Date
Time
Relinquished by (Signature)
Date
Time
(Printed)
(Prfntari)
(Printed)
Date Time
Samples Disposed of by:
Dale Analyses Requested:
Method ol Disposal:
WhHa-Wilh Simptos. Yellow-Ltbofalofy. Plnk-FMd
-------
Columbus Divis £n
S£WS£ , «oi,M,
(614) 42*4247
PCDD/PCOF/PCB
rULHJ/HULJh/PUB
CH AIN OF CUSTODY RECORD
Client:
Project Description:
5
(Ufffr
Client ID
Number
Dale
Sampled
Time
Sampled
Location
No, Containers
Remarkj/Condlllon Upon Receipt
Relinquished by (SJgnalure)
Dale
Time
Received by (Signature)
Dale
Time
Relinquished by (Signature)
Date
Time
(Printed)
(Printed)
(Printed)
Received tor Laboratory by (Signature)
Date
Time
(Prlnled)
Samples Disposed of by:
Date
Analyses Requested:
Method of Disposal:
-------
Columbus DM ton
L.MM
«M| 4K-4M7
Cttent:
PCDD/PCDF/PCB
HL-UUfPODF/PCB
CHAIN OF CUSTODY RECORD
N5 000280
Project Description:
Client ID
Number
Date
Sampled
Time
Sampled
Location
No. Cqntalnen
Remarks/Condition Upon Receipt
fyterf &Mt
a.
fat***
±
Relinquished by (Signature)
Date
Time
Received by (Signature)
Date
Time
Relinquished by (Signature)
Date
Time
(Printed)
(Printed)
(Printed)
bv (Signature)
ate
Time
Samplet Disposed of by:
Date
Analyses Requested:
Method of Disposal:
-------
Columbus DM- ^n
Xa£= „««
(614) 421-42-17
PCDD/PCDF/PCB
PUUU/K'lAJf-/PUB
CHAIN OF CUSTODY RECORD
N8 000280
Client:
Project Description;
Client ID
Number
Date
Sampled
Time
Sampled
Location
No. Containers
Remarks/Condition Upon Receipt
7-
fit chi
ve
r>O at id
f*»
£**»/>
Relinquished by (Signature)
Date
Time
Received by (Signature)
Dele Time
Relinquished by (Signature)
Date
Time
(Printed)
(Printed)
(Printed)
Received to Laboratory L>y (Signature)
Date
Time
(Printed)
Samples Disposed of by;
Date
Analyses Requested:
Method of Disposal:
-------
Baffell-2
Columbus Division
,
(614)4244147
2M3
PCDD/PCDF/PCB
PUUU/PL,U|-/PUB
CHAIN OF CUSTODY RECORD
N? 000280
Client
Profecl Description:
Client ID
Number
~qrrr
Dili
Sampled
Tlnn
Sampled
location
No. Containers
Remarks/Condition Upon Receipt
W/S
I
Relinquished by (Signature)
Dili
Time
Received by (Signature)
Date
Time
Relinquished by (Signature)
Date
Time
(Pflnled)
(Printed)
(Printed)
Recejwd lor Laboralory t / (Slgniture)
Time
(Printed)
^
Samptea Disposed of by:
Data
Analyses Requested:
Method of Disposal:
-------
Co:
-------
Coiiml j§ Oi*i3im
Cchindi n, Ohio *JW1 -JMJ
(CM) 42* 4747
PCDD/PCOF/PCB
CHAW OP CUSTODY RECORD
rnjict DlK/lpnPki
cumtio
MmbM
Tim*
MMMihlJCmlttM Upon Rwtipl
03
an
o
*
Kl
OS
cfe-
041
Lt-S
AM
JO
Art
JL
WNM-WMk Swnftoi, VtlM-Ubamtoiy, PM-FMI
-------
Columbui 3MUan
iUS King Aw nuc
liilimbui, «
(4!« 42*424
PCDD/PCDF/PCB
CHAIN OF CUSTODY RECORD
Profwt Dtttrtptlon:
CBintlD
HunAv
Dito
Tim
Rtinria/OoiKliten Upon Rwtipl
fK ^wn* J
.OH
fil
ca
f*
-08
frf
I_CJ
Frf
Thru
BM
TfeM
AtftiqvMwdbyffflgntlun)
Tim
ThM
0*
WMM-WM St*>M, y«fcw-L«lmi«y, M*-FMI
-------
D-3
Process Sampling Logs
D-24
-------
" Scnjbber Solution Sample'Collection
Plant-
Oatt:
g.
Sample Collection Po1nt:_J_
Sanpl er? . fsr/-'f'1«j p
Volume
k/X ="
I/a
If ~
I
SAMPLE NUHBER
uj
-& i-
- r
J^.
J^L
TDK OF
SAMPLE
'COLLECTIOH
**•)?
/'^?
MM.
^^o
ROOM
.TEMPERATURE
. UH
.id
HZJL
S^
Ul
D-25
-------
" Scrubber Solution Sample' Collection
Date:
Sample Collection Point:
Sanpl §r: - Kfia^
Volume
COmEHTS:.
UP-
1
SAMPLE NlfffeSS
k/T
UO
Jed—x
Ir-'f . T-
TIME OF
SAMPLE
COU.ECTIQH
10L
ML
/) '.
n *.
J »-: 3JL
a:
ROW!
.TEMPERATURE
pH
30*'_ *
0-26
-------
' Scrubber Solution Sample' Collection
Dati: Z:
Sample Collection Point:
Saopl er;. Rfiasi £a/>T£!/'h(jf*
Volume Collected: JZSLai—kiu
COmSNTSj
Pott
SAMPLE
if-
f-JL
V-JL
¥-1
-
wx
w
TIME OF
SAHPLE
COLLECTION
//) ;
II1. ¥5^"
// - f /
!/ :
) -r/
ROOM
•TEMPERATURE
pH
r/'c
30*"6 X?. 3?
7.
^
' 7V/
D-27
-------
D-4
Laboratory Record Book
Sample Log In
D-28
-------
72
LABORATORY RECORD BOOK NO. 47904
TT
D-29
-------
LABORATORY RECORD BOOK NO.
73
I I 9 I I I I IP I I t I IS I I
20 I I
25
30
Work Performed by:
Project
Date of Work: 3 )
TiHe or Purpose:
) ")
Continued from:
- fvts-Aa-'jt,ii
an
65
a<*fSL
6?
oJr
1ST
13—L
- idol
?
Si/
s
ift'L
SU
lick
Mc'rV»
»y
110
it
3B_
«*•-.*,
.»< i «>» \r:
« r i i * i i i i *» i r
i i i *\
Date: a
Continued to: —
Performances of this work observed by:
Disclosed to and understood by ne:
Date:
Date:
t*.
Date:
Date:
D-30
-------
74'
• s-lU*fiiff-ELLE LABORATORY BOOK NO. 47904
110
Jfi.
2P
_5L
_2L
Work Performed
Project
Date of Work: Q.1
Title or Purpoifc
t«..TV
Continued from:-
c
-1)14
. -. A
aeftef
A fict
OH
_3J
i>u:
_!!'//!
i
i
it
V
/a
A,
^o> fP
K
30
a?
«5_
vf
r
/rj^tU'L.
* »*?"*'*
» I I I I * I
i
III!
Intfrerf
Dati; Qj
Eontoed tn:
Performances of this work observed by:
Disclosed to and understood by me:
Date;
Date:
D-31
-------
I'OCtAftELLE LABORATORY RECORD BOOK NO. 4*2904
75
T 1 I I » i I I I ilo f f T^ I 1J5 I I I I zb l l l i 2ji | T
30
Work Perform»d by: D4vfP
Project No.
Data of Werki^S
( *? f?
Title or Purpose: (/(//$ ~~
Continued frems
Performances of this work oiuervtd by:
Bitt:
-'--D-3S
Disclosed to mil understood by me:
Bate:
-------
78
LABORATORY RECORD BOOK NO. 47904
IT I I » I I I I Ho I
JL
Work Performed by:
Presject
of Work
: *&//"
Titb or Purpose:
Continued from:
-0*1
D
>, fiua
Chain of
o
rl
i .
r r*E
it: |7
Continuid to:
Disclosed to and understood by me:
*y/
9-
-isz»*
-------
D-5
Field Test Log
D-34
-------
Table D-1. Field Test Log -- Cincinnati MSD (July 1i9i)
Test Location
GEMS
Outlet
Outlet Stack
Inlet
Outlet Stack
Outlet Stack
Sample
Recovery
Laboratory
Sample
Recovery
Laboratory
Stack Outlet
Stack Outlet
Stack Outlet
Stack Outlet
Scrubber
Water Inlet
Scrubber
Water Outlet
Sample
Recovery
Laboratory
Activity
Pre-Test Cylinder Gas
Audit
Cyclonic Flow
Check/Preliminary
Flowrate
RM Response Time
Stratification Check
Reagent Blanks
Proof Blank #1
MSD-MM5-R11"
(invalidated)
MSD-CEMS-R1
MSD-MM5-R2
MSD-CEMS-R2
MSD- Process-R2
MSD- Process-R2
MSD-Process-R2
(Sludge!
Test Parameter(s)
Total Hydrocarbons
Flowrate
CO/C02/02
CO/C02/02
PCBs
D/Fs
PAHs
PCBs
D/Fs
PAHs
PCBs
D/Fs
PAHs
CO/C02/02
PCBs
D/Fs
PAHs
CO/C02/02
pH, Temperature
pH, Temperature
Chlorine, % Solids,
Ultimate/Proximate
Date
7/19/99
7/20/99
Start
Time
1100
1430
143S
1540
1530
1700
0930
0930
1iOO
1500
1500
1500
1500
End
Time
1130
1530
1545
1630
1700
2000
1230
1230
2130
2130
2130
2130
2130
D-35
-------
Table D-1. (Continued)
Test Location
Sample
Recovery
Laboratory
Stack Outlet
Stack Outlet
Stack Outlet
Scrubber
Water Inlet
Scrubber
Water Outlet
Sample
Recovery
Laboratory
Mobile
Laboratory
Stack Outlet
Stack Outlet
Scrubber
Water Inlet
Scrubber
Water Outlet
Sample
Recovery
Laboratory
CEMS
m*M*r-
Stack Outlet
Activity
Proof Blank f 2
MSD-MM5-R3
MSD-CEMS-R3
Field Blank #1
MSD-Process-R3
MSD-Process-R3
MSD-Process-R3
(Sludge!
Reference Method
CEMS Gas Audit
MSD-MM5-R4
MSD-CEMS-R4
MSD-Process-R4
MSD-Process-R4
MSD-Process-R4
{Sludge)
Post-Test Cylinder Gas
Audit
Post-Test Meter Box
Audit
Test Parameter(s)
PCBs
D/Fs
PAHs
PCBs
D/Fs
PAHs
CO/COj/02
PCBs
D/Fs
PAHs
pH, Temperature
pH, Temperature
Chlorine, % Solids,
Ultimate/Proximate
CO/C02/02
PCBs
D/Fs
PAHs
CO/C02/02
pH, Temperature
pH, Temperature
Chlorine, % Solids,
Ultimate/Proximate
Total Hydrocarbons
Critical Orifice
Date
7/21/99
7/22/99
Start
Time
0700
1015
1015
1015
1015
1015
1015
0710
0815
0815
0815
0815
0815
1430
1500
End
Time
0900
1635
1635
1430
1635
1635
1635
0740
1435
1435
1435
1435
1435
1515
1610
R1, R2, R3, R4 = Run 1, 2, 3, 4, respectively.
D-36
-------
APPENDIX E
PCB Analytical Lab Raw Data Results
-------
E-l
PCB Analytical Summaries
E-1
-------
Table E-1T Run 2 PCB Results - Stack Gas Concentrations (ng/dscm, as measured}
PCB Congener
3,3',4,4'-tetrachlorobipheny! (TCB) (PCB-77)
2,3,3',4,4'-pentachlorobiphenyl (PeCB) (PCB-1O5)
2,3,4,4', 5-pentaehiorobiprienyI (PeCB> (PCB-114J
2,3',4,4',5-pentaehtorobiphenyI (PeCB) (PCB-118)
2',3,4,4',5-pemachlorobiphenyl (PeCB) (PCB-123)
3,3',4,4',5-pentachIorobiphenyl (PeCB) (PCB-12§)
2,3,3',4,4',5-hexachlorobiphenyi (HxCBI (PCB-1i6)
2,3,3',4,4',5'-hexachloroblpheny! (HxCB) (PCB-157J
a.S'^^'.S.S'-hexaehlorobipheny! (HxCB) (PCB-167)
3,3',4,4',5,5'-hexachiorobiphenyl.(HxCB) (PCB-169)
2,2',3,3",4,41,5-heptachlorobiphenyl (HpCB) (PCB-170)
2,2',3,4,4',5,5'-hept3chiorobiphenyI (HpCB) (PCB-180)
2,3,3',4,4',5,5'-heptachIorobiphenyI (HpCB) (PCB-189)
Concentration (ng/dscm, as measured)*
FH
0.129
0.107 B
0.016 B
0.222 B
0.007 B
0.006 B
0.022 B
0.006 B
0.01 1 B
0.010 B
0.025 B
0.052 B
0.003 B
BH
15.5"
2.56
0.373
5.50
0.114
0.694
0.623
0.215
0.377
0.549
1.06
2.64
0.092
Total
15.6
2.67
0.389
5.72
0.121
0.700
0.645
0.221
0.388
0.559
1.08
2.68
0.095
* ng/dscm; nanogram per dry standard cubic meter.
Standard conditions: temperature - 20°C; pressure - 1 atm (760 mm Hg).
" extract was diluted with additional internal standard and re-analyzed to bring PCB-77 concentration within
calibration range. Concentration has been corrected for original extract PCB-77 recovery.
Note: (Below Detection Limit) values listed in parentheses and {EMPC} values listed in brackets.
E - value above calibration range.
B = congener found in blank at greater than 20% of the concentration found In the samples.
E-2
-------
Table E-2T Run 3 PCB Results - Stack Gas Concentrations (ng/dscm, as measured)
PCB Congener
3,3',4,4'-tetrachlorobiphenyl (TCB) (PCB-77)
2,3,3',4,4'-pentachlorobiphenyl (PeCB) (PCB-105)
2,3,4,4',5-pentachlorobiphenyl (PeCB) (PCB-114)
2,3',4,4',5-pentachlorobiphenyl (PeCB) (PCB-118)
2',3,4,4',5-pentachlorobiphenyl (PeCB) (PCB-123)
3,3',4,4',5-pentachlorobiphenyl (PeCB) (PCB-126)
2,3,3',4,4',5-hexachlorobiphenyl (HxCB) (PCB-156)
2,3,3',4,4',5'-hexachlorobiphenyl (HxCB) (PCB-157)
2,3',4,4',5,5'-hexachIorobiphenyl (HxCB) (PCB-167)
3,3',4,4',5,5'-hexachlorobiphenyl (HxCB) (PCB-169)
2,2',3,3',4,4',5-heptachlorobiphenyl (HpCB) (PCB-170)
2,2',3,4,4',5,5l-heptachlorobiphenyl (HpCB) (PCB-180)
2,3,3',4,4',5,5'-heptachlorobiphenyl (HpCB) (PCB-189)
Concentration (ng/dscm, as measured)'
FH
0.104
0.094 B
0.012 B
0.203 B
0.006 B
0.004 B
0.018 B
0.005 B
0.009 B
0.005 B
0.017 B
0.038 B
0.002 B
BH
10.6"
2.36
0.328
5.07
0.105
0.580
0.547
0.174
0.328
0.462
0.949
2.34
0.074
Total
10.7
2.45
0.340
5.27
0.111
0.584
0.565
0.179
0.337
0.467
0.966
2.37
0.076
' ng/dscm; nanogram per dry standard cubic meter.
Standard conditions: temperature - 20°C; pressure - 1 atm (760 mm Hg).
b extract was diluted with additional internal standard and re-analyzed to bring PCB-77 concentration within
calibration range. Concentration has been corrected for original extract PCB-77 recovery.
Note: (Below Detection Limit) values listed in parentheses and {EMPC} values listed in brackets.
E = value above calibration range.
B = congener found in blank at greater than 20% of the concentration found in the samples.
E-3
-------
Table E-3T Run 4 PCS Results - Stack Gas Concentrations (ng/dscm, as measured)
PCB Congener
3,3',4,4'-tetracriIorobiphenyl (TCB) (PCB-77)
2r3,31,4,41-pentachtoroWphenyl (PeCB) (PCB-105)
2,3,4,4' ,5-pentachlorobiphenyt (PeCBJ (PCB-1 1 4)
2,3',4,4',5-pentaehlorobtphenyl (PeCBI (PCB-1 18)
2',3,4,4',5-pentachlorobiphenyi (PeCB) (PCB-123)
3,3',4,4',5-pentachlorobiphenyl (PeCB} (PCB-126)
2,3,3',4,4'»5-bexachlorobIphenyi (HxCB) (PCB-1S6)
2,3,3',4,4',5'-hBxachlorobiphenyI (HxCB} (PCB-1 §7)
l.S'.^'.B.B'-hexachlorobiphenyl (HxCB) (PCB-167)
3,3',4,4',5,5'-hexachlorobiphenyl (HxCB) (PCB-1 69)
2,2',3,3',4,4',5-heptachlorobiphenyl (HpCBI (PCB-170)
2,2', 3,4,4', 5,5'-heptachlorobiphenyf (HpCB) (PCB-180)
2,3,3',4,4',5,5'-hcptachlorobiphenyl (HpCB) fPCB-189)
Concentration (ng/dscm, as measured}'
FH
0.083
0,078 B
0.009 B
0.168 B
0.004 B
0.003 B
0.016 B
0.004 B
0.008 B
0.006 B
0.01 7 B
0.038 B
0.003 B
BH
4.19"
0.867
0.128
2.04
0.034
0.207
0.197
0.074
0.128
0.135
0.420
0.818
0.041
Total
4.27
0.945
0.137
2.21
0.038
0.210
0.213
0.078
0.136
0.141
0.437
0.856
0.044
* ng/dscm; nanogram per dry standard cubic meter.
Standard conditions: temperature - 20°C; pressure - 1 aim (760 mm Hg).
b extract was diluted with additional internal standard and re-analyzed to bring PCB-77 concentration within
calibration range. Concentration has been corrected for original extract PCB-77 recovery.
Note: (Below Defection Limit) values listed in parentheses and {EMPC} values listed in brackets.
E = value above calibration range.
B B congener found in blank at greater than 20% of the concentration found in the samples.
C-A
-------
E-2
PCB Lab Raw Data Sheets
E-5
-------
E-2-1
Air Samples
E-6
-------
OPUS'jiian 28 AWO-1999
Page 7
Pag« 7 of 9
Method 1668 PCS Data 8b«*t
Irttb HOBM: '.ATTELLS
Matrix: All
Beapl* R«c .ipt Data i 07-21-99
Ext. D»t«: 08-01-99
An«ly«l» D«t*l 21-ADQ-99 Xia*i 06:49:31
Extract Voluro* (uL) : 20
Injection Velua* (ul.) t 1
Dilution Factor t wows >"
Concentration Onitti pg/dae
AHALTTB
PCB-77
PCB-123
PCB-118
PCB-114
PCB-105
PCB-126
SCB-167
PCS-156
SCB-157
PCB-169
PCB-180
PC3B-170
PCB-189
COHC.
FOUND
129,20
6.56
222.15
15.67
106.79
6.07
11.26
12.72
12.72
10.57
52.42
25.37
2.97
DETECTION
LIMIT
0.00
0.88
•0.64
1.14
1.16
0.50
0.99
0.80
• 0.80
0.46
0.92
0,41
0.66
L»b B»rapl« IP: 48190-11-02 FH-R2-PCB
Sampl* Ht/Vol: 2.9240 q or ML: M3
Initial Calibration Dat*: 08-22-99
Inatrumont ID: AutoBp«c
GC Column ID: 30m SPB
Sampl. Data Fil«n«m»: 4807*89*
Blank Data Ml«naia*i 4807889A fl
Cal. V»r. Data rllanwM! 4807889 »3
IOH
RATIO
0.75
1.39
1.51
1.66
1.55
1.34
1.19
1.2S
1.28
1.33
1.01
1.07
Concentration Onlta (pg)
IABEI£D COHPOUKDS
13C-PCB-77
13C-eCB-118
13C-ECB-105
13C-PCB-126
13C-PCB-167
130-5CB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-1B9
13C-PCB-209
SPIKB
COHC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
SPIKB
COHC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
COMC.
FOUND
1332
917
955
1142
911
934
934
1086
1180
1173
1428
*{%»
67
46
48
57
46
47
47
54
59
59
36
IOH
RATIO
0.75
1.58
1.S2
1.55
1.26
1.25
1.2S
1.23
1.04
1.04
1.20
0.94
CLEANUP STANDARD
13C-PCB-81
13C-PCB-1X1
1000
5000
646
2844
65
57
-------
m
CO
Lab Name: BATTELLE
Matrix: Air
rasa*
Sample Receipt Date: 07-21 99
Ext. Date: 08-01-99
Analysis Date: 21-AUG-99 Time: 06:49:31
Extract Volume (uL):20
Injection Volume (uL): 1
Dilution Factor None
Concentration Units: pg/sample
Analyte Cone. Found
PCB-77
PCB-123
PCB-118 1
PCB-114
PCB-105
PCB-126
PCB-167
PCi-156
PCB-157
PCB-169
PCB-180
PCB-170
PCB-189
749.71
38.36
,299.13
91.64
624.51
35.50
65.85
74.39
74.39
61.81
306.55
148.38
17.37
Detection Limit
0.00
5.15
3.74
6.67
6.78
2.92
5.79
4.68
4.68
2.69
5.38
2.40
3.86
1 668 PCB Data Sheet
Lab Sample ID: 48190-11-02 FH-R2-PCB
Sample Wt/Vol: 1.00
Initial Calabratlon Date: 08-22-99
Instrument ID: AutoSpec
GG Column ID: 30m SPB
Sample Data Filename: 4807889A
Blank Data Filename: 4807889A #1
Cal. Ver. Data Filename: 4807889 #3
Concentration units
-------
npUSrpmn 2 '-JUJ0-1999
Pag* 7
Pag* 7 of 18
Method 1668 VCB Data Sheet
Lab Hame: BATTELLB
Matrix: A 31
Sample Receipt Data: 07-21-99
Ext. Oat*: 08-01-99
Analyaia Date: 25-AQQ-99 HIM: 02:06:17
Extract Volume (uL): 20
Injection Voluae (nL|i 1
Dilution Factor: NOUS '*
Concentration Onitai pg/Amcm
Lab Sample ID: 48190-11-02 FH-R2-PCB
Sample Wt/VoI: 2.9240 g or mL: M3
Initial Calibration Date: 08-24-99
Instrument ID: RutoSpec
GC Column ID: 30m DB1
S»mpl» Data Filename: 4B07892
Blank Data Filename: 4807892 |7
Cal. Ver, Data Filename: 4807892 |4
Concentration Unit* (pg)
MMUtn •
SCB-77
PCB-123
PCB-118
tCB-114
PCB-10S i
PCB-126 1
BCB-167
PCB-156
BCB-1S7
PCB-169
PCB-180
tCB-170
PCB-189
CONC.
FOUHD
*
*
*
*
*
*
ii.sa
22.43
6.44
8.19
*
*
*
DETECTION I OH
LIMIT RATIO LABBLBD COMPOUHD9
13C-PCB-77
13C-PCB-118
13C-PCD-105
13C-PCB-126
13C-PCB-1S7
13C-PCB-156
2.53 1.15 13C-PCB-157
2.58 1.26 13C-PCB-W9
2.49 1.19 13C-PCB-180
1.13 1.22 13C-PCB-189
* * 13C-PCB-209
* *
* *
SPIKE
CONC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
CONC.
room
*
*
*
*
1392
1548
1378
1901
»
*
*
*W
*
*
*
A
78
77
£9
95
*
*
*
ION
RATIO
*
•
*
*
1,25
1.25
1.2S
1.26
*
*
*
CLRANUP STANDARD
13C-PCB-81
13C-fCB-lll
1000
5000
-------
m
Lab Name: BATTELLE
Matrix: Air
Sample Receipt D.«e: 07-21 SB
Ext. Date: 06-01 S3
Analysis Date: 25- AUG-99 rime: 02:06
Extract Volume (uL):20.
Injection Volume (uL): 1
Dilution Factor: Nona
Concentration Units: pg/sample
Analyie Cone. Found
PCB-77
PCB-123
PCS-US
PCB-114
PCB-105
PCB-128
PCB-167 67.37
PCB-156 131.17
PCB-157 -37.66
PCB-169 47.90
PCB-180
PCB-170
PCB-1B9
Method 1668 PCB Data Sheet
Lab Sample ID: 48190-1 1-02 FH-R2-PCB
Sample Wt/Vol: 1.00
Initial Calabration Date: 08-24-99
Instrument ID: AutoSpec
17 GC Column ID: 30m DB1
Sample Data Filename: 4807889A
Blank Data Filename: 4807892 #7
Cat. Ver. Data Filename: 4807892
-------
OPUStjvan 26 -AUG-1999
Page S
P»g« 8 of 9
Method 1668 PCS Data Sheet
Matrix: hi I
Seiepl* Reoipt D»t«: 07-21-99
Ext. Dftt*: 08-01-99
Analy»i» D»t«: 21-AHQ-99 lint! 07:53:24
extract Voluro* (uL) t 20
Injection Voltuw (uL): 1
Dilution factor« HOHS ?
Concentration Onltai pg/daoo
COHC.
AMALYTR
PCB-77
PCS- 123
PCB-114
PCB-105
PCS- 12 6
PCB-167
PCB-156
PCB-1S7
PCB-169
PCB-1BO
PCB-170
PCB-189
104.45
6.23
202.84
11.72
94.03
3.97
9.43
10.48
10.48
4.91
39.02
17.10
2.00
DKTBCTIOH
LIMIT
0.00
1.02
' 0.74
1.30
1.32
0.57
1.07
0.88
' 0.88
0.50
0.98
0.44
0.67
Lib Sample IDs 48190-11-03 FH-R3-PCB
Sarepl. W;/Vcl: 3.1100 9 or mL: H3
Initial Calibration Data: 08-22-99
InatnuMnt ID: AutoSpac
GC Column ID: 30m SPB
Banpl* Data FllenaiMt 4807889A
Blank Data Fllenaim: 4807889A fl
Cal. V«r. Data Fll«nam»: 4807889 13
ION
RXIIO
0.75
1.45
1.57
1.62
1.61
1,74
1.14
1.33
1.33
1.12
0.95
0.98
1.15
Concentration Units (pg)
UBSLSD COMPOUHDS
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-1S9
13C-PCB-180
13C-PCB-189
13C-PCB-209
SPTKR
COHC,
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
CLKMTOP STANDARD
13C-PCB-81
13C-PCB-111
SPTKR
COHC,
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
cone.
FOUND
1101
695
73<
886
723
763
7i3
•75
962
1013
1571
*(*)
55
35
37
44
36
38
38
44
48
51
39
IOH
RATIO
0.77
1.60
1.54
1.56
1.25
1.24
1.24
1.26
1.02
1.03
1.19
1000
5000
526
2043
S3
41
-------
Is*
Method 1668 PCB Data Sheet
Lab Name: BATTELLE Lab Sample ID: 481 90-1 1 -03 FH-R3-PCB
Matrix: Air Sample VWVoi: 1.00
Sample Receipt Date; 07-2- BB Initial Calabration Date: 08-22-99
Ext. Date: 08-01-99 Instrument ID: AutoSpec
Analysis Date: 21-AUO-93 Time: 07:§3:24 GO Column ID: 3Cm SPB
Extract Volume (uU): 20 Sample Data Filename: 4807889A
Injection Volume (uL): 1 Blank Data Filename: 4807889A #1
Dilution Factor: NONE Cal. Ver. Data Filename: 4807889 #3
Concentration Units: pg/sample
Analyta
PCB-77
PCB-123
PCB-118
PCB-114
PCB-105
PCB-126
PCB-167
PCB-156
PCB-157
PCB-169
PCB-180
PCB-170
PCB-189
Cone. Found
649.68
3875
1,261 36
72.30
584 37
2439
5835
6519
6519
30 54
236.48
10636
12.44
Detection Limit
0.00
6.34
4.60
8.09
8.21
3.55
6.89
5.47
5.47
3.11
6.10
2.74
4.17
Ion Ratio
0.75
1.45
1.57
1.62
1.61
1.74
1.14
1,33
1.33
1.12
0.95
0.98
1.15
Concentration units (pg)
Labeled Compounds
13C-PCB-77
13c-PCB-118
13C-PCB-105
13C-PCB-126
13c-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
Cleanup Stds
13c-PCB-81
13C-PCB-111
Spike Cone,
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
8000
2000
10000
Cone. Found
2202
1390
1472
1772
1446
1526
1526
1750
1924
2028
3142
1052
4086
R(%)
55
35
37
44
36
38
38
44
48
51
39
53
41
Ion Ratio
0.77
1.6
1.54
1.56
1.25
1.24
1.24
1.26
1.02
1.03
1.19
-------
OPUPquar. 2 '-XOCJ-1999
Page 8
Method 1668 PCB Data Sheet
Lib Uaoe: BATTBLLS
tfxttlx; K CR
Barople Re :eipt Datei 07-21-99
Ext. Data: 08-01-99
Analyelo Datet 25-AOO-99 Time: 02:52:33
Extract Volume (uL)« 20
Injection Voluae (wt>) i 1
Dilution Fact or i MONi '*
Concentration Unit*: pg/dacn
tab Simple IBs 48190-11-03 FH-R3-PCB
Bangle Wt/Volf 3.1100 g or mil! M3
Initial Calibration Date: 08-24-99
Instrument ID: AutoSpoc
GC Column ID: 30m DBl
Sample Data Filename: 4807892
Blank Data Filename: 48O7892 §7
Cal. Ver. Data Filenamei 4807892 M
Concentration Unit* (pg)
CLEANUP STANDARD
13C-PCB-91
13C-PC1-111
1000
SOOO
Page 8 of 18
CONC. DETECTION ION
JtHMiTTB FOOHD LIMIT RATIO LABELED COMPOUNDS
fCB-71 ' . 13C-tCB-17
fC»-123 13C-PCB-118
PCB-118 • 13C-PCB-10S
»Ca-lH 13C-PCB-128
PCB-105 I 13C-PCB-167
PCB-12S I * 13C-PCB-1SS
PCB-1S7 *.36 2.89 1.41 13C-5CB-157
PCB-15« 18.00 2.99 1.22 13C-PCB-169
fCS-157 4.57 2.76 ' 1.20 13C-fCB-180
PCB-169 * 1.31 * 13C-PCB-189
PCB-180 * * * 13C-PCB-209
PCB-170 * * *.
PCB-189 * * *
BPnOK
CONC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
CONC.
FOUND
*
*
*
*
1082
1202
1103
1483
*
*
*
*<»>
*
*
*
*
54
60
ss
74
*
*
*
ION
RATIO
*
*
*
*
1.28
1.27
1.27
1.26
*
*
*
-------
Method
Lab Name: Batten*
Matrix: Air
Sample Receipt Date- 37-2 -99
Ext Date: 08-01 M
Analysis Date: 25- AUS-99 Time: 02:52:33
Extract Volume (uL): 20
Injection Volume (uL); 1
Dflutton Factor: None
Concentration Units: pg/sample
Analyte Cone. Found Detection Limit
PCB-77
PCB-123
PCB-118
PCB-114 *
PCB-105
PCB-126 *
PCB-167 58.22 17.98
PCB-156 111.98 18.60
PCB-157 28.48 17.17
PCB-169 -..*" 8.15
PCB-180 « *
PCB-170 » '
PCB-189 * *
1 668 PCB Data Sheet
Lab Sample ID: 48190-11-03 FH-R3-PCB
Sample Wt/Vol: 1.00
Initial Calabration Date: 08-24-99
Instrument ID: AutoSpec
GC Column ID: 30m DB1
Sample Data Filename: 4807892
Blank Data Filename: 4807B92 #7
Cal, Ver. Date Rename: 4807892 #4
Concentration units (pg)
Ion Ratio Labeled Compounds
13c-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-158
1.41 13C-PCB-157
1.22 13C-PCB-169
1.2 13C-PCB-180
* 13oPCB-189
13C-PCB-209
*
#
Cleanup Stds
13C-PCB-81
13C-PCB-111
Spike Cone. Cone. Found R(%)
4000 *
4000
4000 * *
4000 * *
4000 2184 54
4000 2404 60
4000 2208 55
4000 2968 74
4000
4000
BOOO
2000 * *
10000
Ion Ratio
*
*
*
•
1.28
1.27
1.27
1.26
«
*
*
-------
OPUScpiau 28 AUG-199J
Page 9
Pag* 9 of 9
Method 1668 PCB Data Sheet
Lab Nam*i >A7TKLLE
Matrix: AT I
Sample Roc ilpt D.t«: 07-23-99'
Exfc. D»t«: 08-01-99
An«ly«i« D»toi 21-AOQ-99 Tlflw: 08:57:14
Extract V«lunM (uL) : 20
Injection Voluma (uL): l
Dilution F»cton MOMS r
Conc«ntration Onltsi pg/d«cn
Lab B.mple IDs 48190-11-04 FH-R4-PCB
Sample Kt/Vol: 3.3500 g or ml,: H3
Initial Calibration Data; 08-22-99
Instrument ID: AutoSpec
OC Column ID: 30« 3PB
Sampl« Data Filename: 4807899A
Blank Data Filename i 4807889A fl
Cal. Ver. Data Filcnaiw; 4807889 13
Concentration Onit« (pg)
rn
<
01
AHAi/rrs
.PCB-77
PCB- 123
PCB-118
PCB- 11 4
PCB- 3.05
PCB-126
PCB-167
PCB-156
PCB- 157
PCB-1S9
pca-iso
PCB-170
PCB-189
COKC.
room
82.91
4.25
167.95
9.32
78.18
3.46
7.75
8.78
8.78
5.72
38.30
16.79
2.95
DBTKCTIOH
LIMIT
0.00
1.08
0.79
1.46
1.48
0.61
1.24
1.03
• 1.03
0.54
1.13
0.51
0.7»
ION
RATIO
0.75
1.54
1.56
1.71
1.56
1.48
1.29
1.33
1.33
1.39
0.91
1.10
0.98
LABELED COMPOUNDS
13C-PCB-77
13C-PCB-11B
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-1«9
13C-PCB-180
13C-PCB-H9
13C-PCB-209
BPIKB
COKC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
COHC.
room
1106
727
722
909
732
75«
75«
951
931
978
1590
*W
55
36
36
45
37
38
38
48
47
49
40
ION
RATIO
0.78
1.56
1.59
1.55
1.26
1.25
1.25
1.25
1.03
1.03
1.19
CLEAHUP STANDARD
13C-PCB-81
13C-PCB-111
1000
5000
575
2425
58
48
-------
O)
Method 1668 PCS Data Sheet
Lab Name: Battelle Lab Sample ID: 48190-11-04 FH-R4-PCB
Matrix: Air Sample Wt/Vol: 1 .00
Sample Raceipt Dels: 07-23 99 Initial Calabratton Date: 08-22-99
Ext. Date; 08-01 -96 Instrument ID: AutoSpec
Analysis Date: 21-AUG-99 rim«: 08:57:14 OC Column ID: 30m SPB
Extract Volume (uL): 20 Sample Data Filename: 4B07889A
Injection Volume {uL): 1 Blank Data Filename: 4807889A #1
Dilution Factor: None Cal. Ver. Data Filename: 4807889 #3
Concentration Units: pg/sample
Analyte
PCB-77
PCB-123
PCB-118
PCB-114
PCB-105
PCB-126
PCB-1«7
PCB-158
PCB-157
PCB-169.
PCB-180
PCB-170
PCB-189
Cone. Found
555.50
28.48
1,125.?7
82.44
523.81
23.18
51.93
58.93
58.83
38.32
256.81
112.49
19.77
Detection Limit
0.00
7.24
S.29
9.78
9.92
4.09
8.31
6.90
8.90
3.62
7.71
3.42
5.23
ion Ratio
0.75
1.54
1.56
1.71
1.56
1.48
1.29
1.33
1.33
1.39
0.91
.1.1
0.98
Concentration units (pg)
Labeled Compounds
13C-PCB-77
13o-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
Cleanup Stds
13c-PCB-81
13C-PCB-111
Spike Cone.
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
8000
2000
10000
Cone. Found
2212
1454
1444
1818
1464
1512
1512
1902
1862
1956
3180
11BO
4850
R(%)
55
38
36
45
37
38
38
48
47
49
40
58
48
Ion Ratio
0.78
1.56
1.59
1.55
1.26
1.25
1.25
1.25
1.03
1.03
1.19
-------
OPOScrj.in 2< -AOC-1999
P»g« 9
Pag* 9 of 18
Motbod 1668 PCB Data Sheet
lato Hum: BATTELLB
HateiX! A R
S«uqpl» R«> «ipt Data! 07-23-99
Ext. Oat*: 08-01-99
Analy«ia Dat*t 25-JUKI-99 Tlnw: 03:38:55
Extract Volume (UL) : 20
Injection VolHM (uL) i 1
Dilution Fact or i HONE ''
Concentration Bnitai pg/dacai
I,ab Sample ID: 48190-11-04 FH-R4-PCB
Sample Ht/Vol: 3.3500 g or BL: M3
Initial Calibration Data: 08-24-99
XnMtrumant iD: BntoSpec
OC Column ID: 30r« DB1
8a«f>l* Data Pil»n«ra«: 4807892
Blank Data Fil«nam»: 4807892 |7
cal. v«r. Data ril«nam*> 4807892 |4
Concentration Unit* (pg)
ANALTTB
tCB-7?
PCB-123
PCS-118
PCB-114
PCB-10S i
PCB-126 |
PCB-167
PCB-158
tCB-157
tCB-169
PCB-180
PCB-170
PCB- 189
COHC, DBTSCTIOH I OH
PO0HD LIMIT RATIO LABKLED COMPOUHO8
* 13C-5CB-77
13C-PCB-1H
13C-PCB-105
13C-FCB-12*
13C-PCB-1S7
13C-PCB-15S
' T.7t 3.94 1.07 13C-PCB-157
15.92 4.29 1.27 13C-PCB-169
4.11 3.99 1.21 13C-PCB-190
2.40 1.87 1.38 13C-PCB-189
* • * 13C-PCB-209
* * *
* * *
CLEANUP STANDARD
13C-PCB-81
13C-PCB-111
8PIKK
CONC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
1000
5000
COHC.
FOUND
*
*
*
*
973
1011
897
12*3
*
*
*
*
*
*(*»
*
*
*
*
49
51
49
64
*
*
*
*
. *
ION
RATIO
*
*
*
*
1.25
1.26
1.25
1.26
*
*
*
-------
m
oo
Method
Lab Nairn: Battelle
Matrix: Air
Sample Receipt Dele; 07-23 99
Ext. Date: 08-01 -CC
Analysis Date: 25-AUG-99 Ime: 03:38:55
Extract Volume (ul): 20
Injection Volume (uL): 1
Dilution Factor: None
Concentration Units: po/sample
Analyte Cone, Found Detection Limit
PCB-77 *
PCB-123 • *
PCB-118
PCB-114 * •
PCB-105
PCB-126 * *
PCB-167 52. 3 26.40
PCB-156 106.H6 26.74
PCB-157 27.! 4 26.73
PCB-189 16.!)8 12.53
PCB-180 *
PCB-170
PCB-189 *
1668 PCB Date Sheet
Lab Sample ID: 48190-11-04 FH-R4-PCB
Sample VWVol: 1.00
Initial Calabf ation Date: 0824-99
Instrument ID: AutoSpec
GC Column ID: 30m DB1
Sample Data Filename: 4807892
Blank Data Filename: 4807892 »7
Cal. Ver. Data Filename: 4807892 #3
Concentration units (pg)
Ion Ratio Labeled Compounds
13C-PCB-77
13c-PCB-118
13C-PCB-105
13C-PCB-128
13C-PCB-167
13C-PCB-158
1.07 13C-PCB-157
1.27 13C-PCB-169
1,21 13C-PCB-180
1.38 13C-PCB-189
13C-PCB-209
*
*
Cleanup Stds
13C-PCB-81
13C-PCB-111
Spike Cone. Cone, Found R(%)
4000
4000
4000 *
4000 * *
4000 1048 49
4000 2022 51
4000 1794 45
4000 2563 64
4000 * *
4000 " *
8000 *
2000
10000
Ion Ratio
*
*
*
*
1.25
1.26
1.25
1.26
*
*
*
-------
OPWqwan 21 -AUG-1999
Pago 7
Fag* 7 of 9
Method 1668 PCS Data Shaat
tab Hnm»: 3AITELLB
Matrix: JP *
Biunpla Receipt Dmtms 07-21-99
Ext. Data: 07-26-99
Knalyaia Data: 23-AUQ-99 'Tina: 20:10:44
Extract Volmna (uL) ; 20
Injection Valma (ut.) t 1
Dilation factorI 1:2 ?
Concentration Unitai pq/dmcm
ANKLYTB
PCB-77
" PCB-123
KB-118
PCB-1H
SC8-105 I
PCB-126 I
tCB-167 *
PCB-156
PCB-157
PCB-169
PCS-ISO
PCB-170
PCB-169
Lab Samplo ID: 48190-D9-02 BH-R2-FCB
Sanpl* Ht/Vol: 2.9240 g or mL: M3
Initial Calibration Data: 08-22-99
Instrument ID: AutoSpac
GC Column ID: 30m 8PB
San^le Data filenama; 4807(91
Blank Data PU*naaia; 4807891 13
Cal. V*c. Data Filanaaa: 4807891 I2
Concantxation Dnita (jxj)
CONC . DETECTION
FOUND
25001.11^
113.76
$498,35
372.94
2562.06
694.07
377.09
107.39
407.39
549.01
2637.74
1055.27
92.03
LIMIT
0.00
2.28
1.66
4.06
1.92
1.30
0.81
1.54
1.54
0.65
1.71
1.08
0.89
ION
RA3IO
0.77
1.43
1.54
1.60
1.70
1.52
1.24
1.24
1.24
1.27
1.02
1.01
0.98
IABKLED COWOONDS
13C-PC»-77
13C-PCB-118
13C-FCB-105
13C-PCB-126
13C-PCB-167
13C-5CB-156
13C-PCB-157
13C-pe»-169
13C-PCB-180
13C-PCB-169
13C-PCB-209
BPnot
COHC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
CONC.
FOUMD
12S7
1180
1241
981
1269
1264
12S4
1061
1083
1201
240C
1
R<%) 1
S3 I
59 ]
62
49
S3
S3
63
53
S«
60
60
[OH
IATIO
1.79
L.60
,59
. «3
.2S
,27
.27
.28
.03
.02
.19
13C-PCB-B1
13C-PCB-111
1000
sooo
537
2618
54
52
-------
Method 1668 PCS Data Sheet " ' """ " ' "
Lab Name; Battelle Lab Sample ID: 481 90-09-02 BH-R2-PCB
Matrix: Air Sample WIA/ol: 1 .00
Sample Receipt Date- 07-2 99 Initial CalabraMon Date: 08-22-99
Ext. Date: 07-28 99 Instrument ID: AutoSpec
Analysis Date: 23 AUG-99 Time: 20:10:44 GC Column ID: 30m SPB
Extract Volume
-------
OPOSquan 2S -AOQ-1999
Bag* 1
fmg» 16 of 18
Mathod 1668 PCS Data Shaat
Lib HUM: 3ATTBIO4I
Matclz: AJil
Saapl* Receipt fiat*: 07-21-99
Bxt. Datai 07-28-99
Analyal* Date: 2S-3WO-99 f i»»! 10:35:47
Extract Volume (UL) i 20
Injection Volute (uL) : 1
Dilation Factor! Ii2
Lab Sunpl* ID: 48190-09-02 BH-R2-PCB
Sampl* Vt/Vol: 2.9240 g or •!.: M3
Initial Calibration Data: 08-24-99
Xnatnmwftt ID: Auto«p«c
OC Column ID: 30m DB1
Sarapl* Data Fllanaaw: 4807892
Blank Data Fil«nan»: 4807892 17
cal. V«r. Data rilmanwi 4807092 H
Concentration Unit*:
AKAliITK
BCB-77
PCB-123
PCB-118
PCB-114
BCB-10S
PCB-126
PCB-1S7
FC8-15*
fCB-157
PCB-169
PCB-180
K»-170
PCB-189
C0HC.
FOUND
DBTBCIIOH
LIMII
JOM
RATIO
332.53
S23.12
214.38
520.72
*
*
*
7.39
7.44
C.23
4.01
*
*
1.28
1.25
1.18
1.27
*
Concentration Onita (pg)
LABELED COMPOUNDS
13C-PCB-77
13C-PCB-118
13C-ECB-10S
13C-PCB-12«
13C-PCB-167
13C-BCB-1SS
13C-PCB-157
13C-FCB-1S9
13C-PCB-180
13C-tCB-189
13C-FCB-209
COHC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
CONC.
FOVHD
*
*
*
*
1489
1645
1679
1674
*
*
*
*
74
82
84
•4
*
*
XOM
RATIO
*
*
*
*
1.2«
1.27
1.25
1.24
*
*
*
CLSAHUP STANDARD
13C-PCB-81
13C-*CB-lli
1000
5000
-------
m
fo
W
Method
Lab Name: Battella
Matrix: Air
Sampte Receipt Date: 07-2 -99
Ext Dale: 07-28-P9
Analysis Date: 25-AUG-99 Time: 10:35:47
Extract Volume (uL): 20
Injection Volume (uL): 1
Dilution Factor: 1:2
Concentration Units: pg/sampte
Analyte Cone. Found Detection Limit
PCB-77
PC8-123
PCB-11B '
PCB-114 »
PCB-105 *
PCB-126 *
PCB-187 1,944.64 43.22
PCB-156 3,544.01 43.51
PCB-157 1,254.86 36.43
PCB-189 3,045.17 . 23.45
PCB-180 »
PCB-170
PCB-189
1668 PCS Data Sheet
Lab Sample ID: 48190-09-02 BH-R2-PCB
Sample WtfVol: 1.00
Initial Calabralran Data: 08-24-99
Instrument ID: AuloSpec
GC Column ID: 30m DB1
Sample Data Filename: 4807892
Blank Data Filename: 4807892 #7
Cal. Ver, Data Filename: 4807892 #3
Concentration units (pg)
Ion Ratio Labeled Compounds
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-128
13C-PCB-167
13C-PCB-156
1.28 13C-PCB-157
1.25 13C-PCB-169
1.18 13C-PCB-180
1.27 13C-PCB-189
13C-PCB-209
*
*
Pre-Sampling Surrogate Stds
13C-PCB-81
13c-PCB-111
Spike Cone. Cone. Pound R(%)
4000 ' *
4000
4000
4000
4000 2978 74
4000 3290 82
4000 3358 84
4000 3348 84
4000
4000 * *
8000
2000
10000
Ion Ratio
*
*
*
*
1.26
1.27
1.25
1.24
*
*
*
-------
OPUSqua- 22-f JP-1999
Page 1
Page 11 of 13
Method 1668 PCS Data Sheet
Lab Ham: Bf FTRLLB
Matrix: AIR
BaiapJe Receipt Data: 07-21-99
Bxt, Datet 07-28-99
ftnalyal. Data: 20-8EP-99 Tina: 23:04i27
Extract volume (uL): 20
Injection Volune (uL) i 1
Dilution Factori Ii25
Concentration Cnltai pg/daca
AHAI.TTB
PCB-77
CONC.
room)
9761.28
DETSCTIOM
LIMIT
0.00
Lab Sample ID: 48190-09-02 BH-R2-PCB
Sanple Wt/Vol: 2.9240 g or nL: M3
Initial Calibration Date: 08-22-99
Instrument ID: Auto9pec
GC Colunm ID) 3Ore SPB
Sample Data Filename: 4807897
Blank Data Filename: 4807891 13
Cal. Ver. Data Filename: 4807891 «2
ION
RATIO
0.79
Concentration Unit* (pg)
LABELED COMPOUNDS
70776
52015
510C7
48706
44034
4390
434(13
7944
41967
35817
53535
3C-PCB
3C-PCB
3C-PCB
3C-PCB
3C-PCB
3C-PCB
3C-PCB
3C-PCB
-------
Method 1668 PCS Data Sheet
Lab Sample ID: 48190-09-02 BH-R2-PCB
Sample VWVol: 1.00
Initial Calibration Date: 08-22-99
Instrument ID: AutoSpec
GO Column ID: 30m SPB
Sample Data Filename: 4807897
Blank Data Filename: 4807891 #3
Cal. Ver. Data Filename: 4807891 #2
Lab Name: Battelle
Matrix: Air
Sample Receipt Data: 07-21 99
Ext. Data; 07-28-M
Analysis Date: 20-SEP-99 "hue: 23:04:27
Extract Volume (uL): 20
njecOon Vohme (uL): 1
Dilution Factor. 1:25
Concentration Units: pg/sarnple
Analyte Cone. Found Detection Limit Ion Ratio
PCB-77 57,083.97 0.00 0.79
PCB-123
PCB-118
PCB-114
PCB-105
PCB-126
PCB-167
PCB-156
PCB-157
PCB-169
PCB-180
PCB-170
PCB-189
'This Is a sample rerun at a hlflher dilution factor to bring PCB-77
into range.
Concentration units (pg)
Labeled Compounds
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-158
13C-PCB-157
13C-PCB-169
13C-PCB-180
13c-PCB-fBi
13C-PCB-209
Pre-Sampling Surrogate Slds
13C-PCB-81
13C-PCB-111
Spike Cone.
Cone. Found
ton Ratio
-------
OFOSouan 26- AUC-1999
Page 8
Fag* 8 of 9
Method 1668 PCD Data Sheet
Lsl Nfc.iwi ? AI1ELLB
Matrix: AD.
Banipl* Rec< ipt Datei 07-21-99
Kxt. Data: 07-28-99
Analy.ia Datet SS-AWJ-99 flaw; 21:14:32
Kztzact Volum* {Uli) : 20
Injection Volum* (uL)i 1
Dilation Factor! ItZ '
Concentration Onita: pg/dacm
HKJX.YTK .
PCB-77
PCB-123
PCB-118
* PCB-114
PCB-105 I
PCB-126 I
SCB-167
SCB-156
PCB-157
PCB-169
PCB-180
PCB-170
PCB-189
Lab S«mpl« 1C: 48190-C9-03 BH-R3-PCB
8 amp IB Wt/Vol: 3. HOC g or mb: M3
Initial Calibration Dates 08-22-99
Instrument ID: AutoSpec
8C Column ID: 30m SPB
SampIB Data Filename: 4807891
Blank Data Filename: 4807891 |3
Cal. V»r. Data Fllenam*; 4807891 «2
Concantratlon Dntt* (pg)
CONG.
FOUND
21S92.74'/
105.48
506S.39
32*. 35
2361.00
579.93
327. 8«
351.51
351.51
461.97
2336.41
949.30
73. S7
DETECTION
LIMIT
0.00
1.77
•1.28
3.06
1.44
0.91
0.64
1.22
1.22
0.54
1.38
0.88
0.73
ion
RATIO
0.77
1.48
1.S4
1.60
1.6*
l.SS
1.26
1.25
1..23
1.30
1.03
1.04
1.01
LABELED COMPOUNDS
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-5CB-126
13C-5GB-167
13C-FCB-15I!
13C-PCB-157
13C-PCB-169
13C-PCB-18Q
13C-PCB-189
13C-PCB-209
BPIKB
CONC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
cone.
FOUND
1391
1226
1323
1136
1274
1289
1289
1019
1182
1289
2572
R(*»
70
61
66
57
64
64
£4
51
59
64
64
IOH
RATIO
0.79
1.57
1.58
1.59
1.28
1.27
1.27
1.24
1.03
1.02
1.20
STANDARD
13C-PCB-81
13C-PCB-111
1000
5000
CO 6
2546
61
.51
-------
in
fb
0>
Lab Name: Battello
Matrix: Air
Sample Receipt Cite:
Ext. Date: 07-28 -«9
Method
1 668 PCB Data Sheet
lab Sample ID: 48190-094)3 BH-R3-PCB
07-2'; 99
Sample WtA/ol: 1.00
Initial Calabraiion Date: 08-22-99
Instrument ID: AutoSpec
Analysis Date: 23-AU3-99 Time: 21:14:32
Extract Volume (uL): 20
Injection Volume (uL):
Dilution Factor: 1:2
Concentration Units:
1
OC Column ID: 30m
SPB
Sample Data Filename: 4807891
Blank Data Fitename
: 4807891 #3
Cat. Ver. Data Filename: 4807881 «
pg/sample
Anatyte Cone. Found
PCB-77
PCB-123
PCB-118
PCB-114
PCB-105
PCB-128
PCB-167
PCB-156
PCB-157
PCB-189
PCB-180
PCB-170
PCB-189
126,274.34
616.85
29,622.40
1,921.36
1 3.807. t3
3,391.43
1,917.33
2,055.63
2,055.63
2,701.80
13,663.33
5.551.51
430.24
Detection Limit
0.00
10.35
7.49
17.89
8.42
5.32
3J4
7.13
7.13
3.16
8.07
5.15
4.27
Ion Ratio
0.77
1.48
1.54
1.6
1.68
1.56
1.26
1.25
1.25
1.3
1.03
1.04
1.01
Concentration units (pg)
Labeled Compounds
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-1S6
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-2Q9
Pre-Sampling Surrogate Slds
13C-PCB-81
13C-PCB-111
Spike Cone.
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
8000
2000
10000
Cone. Found
2782
2452
2648
2272
2548
2578
2578
2038
2364
2578
5144
1212
5092
R(%)
70
61
66
57
64
64
64
51
59
64
64
61
51
Ion Ratio
0.79
1.57
1.58
1.59
1.28
1.27
1.27
1.24
1.03
1.02
1.20
-------
OFOSqumn 29 ROG-1999
P«g» 1
Method 1668 PCB Data She.t
Lab Mann: . ATTKLLE
Matrix? AE;
Sanpl* R«c iipt Data: 07-21-99
Ext. Dat*t 07-28-99
Analyaia Data: 25-AW3-99 Tim: 11:22:08
Extract Voluow (uL)t 20
Injection Volu»« (UL)s 1
Dilution Factort Ii2
Concentration Unitei pg/daoa
Lab Sampl* ID: 48190-09-03 BH-R3-PCB
Stmpls Wt/Vol: 3.1100 g or mL: M3
Initial Calibration Dat*: 08-24-99
Instrument ID! Autoapac
GC Column ID: 30m DS1
Sanpl* Data Pll*naiM: 4807892
Blank Data Fil«nara«: 4807*92 17
Cal. V*r. Data ril«nan»: 4807892 |4
Concentration Dnita (pg)
CLEAHOT? STANDARD
13C-PCB-81
13C-PCS-111
1000
5000
Pag. 17 of 18
AHALTTB
. PCB-77
PCB-123
, PCB-118
PCB-114
PCB-105 I
PCB- 12 6 |
PCB-167
PCB- 15 6
fCB-157
PCB-169
PCB-180
PCB-170
PCB-189
COHC. DETKCTIOK ION
FOUND LIMIT RATIO T.magfjtn COMPOUKDB
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-12S
13C-FCB-167
13C-PCB-15S
295.40 6.72 1.24 13C-PCB-157
547.35 6. 57 1.21 13C-PCB-1S9
174.03 S.29 1.22 13C-PCB-180
453.14 3,90 1.34 13C-PCB-189
« * * 13C-PCB-209
* * *
* * *
arm
COHC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
COHC.
room)
*
*
*
*
1434
1633
1666
1553
*
*
*
*(*)
*
*
*
*
72
82
83
78
*
*
*
ION
RATIO
*
*
*
*
1.24
1.26
1.23
1.22
*
*
*
-------
m
i
M
m
Lab Nsme: Battelle
Matrix: Air
Method 1668 PCB Data Sheet
Lab Sample ID: 48190-08-03 BH-R3-PCB
Sample Receipt O-ite: 07-21 -99
Ext, Date: 07-28-99
Sample VWVol: 1.00
Initial Catenation Date: 08-24-99
Instrument ID: AutoSpec
Analysis Date: 25-AUG-99 Time: 1 1
Extract Volume (uL):
20
Injection Volume (uL): 1 '
Dilution Factor: 1:2
Concentration Units:
Analyte
PCB-77
PCB-123
PCB-118
PCB-114
PCB-105
PCB-126
PCB-167
PCB-156
PCB-157
PCB-168
PCB-180
PCB-170
PCB-189
22:08 GC Column ID: 30m DB1
SampJe Data Filename: 4807892
Blank Data Filename
: 4807882 #7
Ca!, Ver. Data Filename: 4807892 #4
pg/sample
Cone. Found
*
*
•
*
It
*
1,837.39
3,404.52
1,082.47
2,822.88
*
'*
*
Detection Limit Ion Ratio
*
%
*
*
*
«
41.80 1.24
40.87 1.21
32,90 1.22
24.26 1.34
* *
* *
* *
Concentration units (pg)
Labeled Compounds
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
Pre-Sampling Surrogate Stds
13C-PCB-81
13C-PCB-111
Spike Cone. Cone. Found R(%)
4000 * *
4000
4000 * *
4000 *
4000 • 2888 72
4000 3266 82
4000 3332 83
4000 3110 78
4000
4000
8000
2000
10000 * *
Ion Ratio
*
*
#
*
1,24
1.6
1,23
1.22
*
*
*
-------
22-f 2P-1999
P»g»
Method 1CC8 PCB Data Sheet
Iiab Han»i K I7EU2
Hatrr-xs MR
Sample Receipt Pate: 07-21-99
Ext. »»t«! 07-28-99
Analyaia Datei 21-SEP-99 TIM*I 00:00:21
Bxtraot Volume (ul,) : 20
Injection Volume (ul>) i 1
Dilation Facto* i £rf) \ \
Concentration Onlt»t pg/dao*
WJH.TTB
CONG.
FOUND
DKTRCTIOH
LIMIT
Lab Sample ID: 49190-09-03 BH-R3-PCB
Sample Ht/Vol: 3.1100 g or mL: M3
Initial Calibration Data: 08-22-99
Tnarrumont 10: XutoSpec
OC Column ID: 30m SPB
Sample Data Fllsname: 4807897
Blank Data rilenarae: 4807891 |3
Cal. V*r. Data Filename: 4807891 12
IOM
RATIO
2036.43
132.19
943.89
191.20
PCB-1
?CB-105
PCB-126
?CB-167
PCB-156
?CB-157
1.
181.17
167.20
1172.96
377.31
U *
Concentration Onits
~m, '"
183
123
119
112
93
J^
•^ 90
76
90
73
54
^
1000
sooo
Fag» 12 of 13
-------
m
OJ
o
i
OPUSquan 28 -AOO-1999
f
L.-xb Kan*: 3ATXELLC
Matrix: All
Baaipl* Ka>c»ipt Date I
Ext. Data: 07-28-99
Pag*
9
Pag* 9 of 9
Method 1668 FCB Data Sb«*t .
07-23-99
Analyai* Dat*l 23-MKJ-99 Tim*! 22 : 18 1 22
Extract Voluma (uL) :
Injection Voluna fal>}
Dilation Factor i Ii2
Concentration Dnita:
AKALYTB
PCB-77
PCB-123
PCS- 118
PCB-i.14
PCB-105 i
PCB-126 i
PCB-167 *
PCB-156
PCB-157
PCB-169
PCB-180
PCB-170
PCB-189
J
20
I 1
?
pg/dioi
COHC. DKTBCIIOH
FOOHD LIMIT
705*. 71* 0.00
34.16 1.57
2042. £3 1.14
127.58 2.72
866.79 1.28
207.19 0.90
128 .05 0 . 61
134.36 1.12
134.36 1.12
134. £0 0.40
817.78 1.33
420.28 0.85
40. £5 0.71
»«r*
Ltb Barupl* ID: 48199-09-04 BH-R4-PCB
Saibpl* Wt/Vol: 3.3500 «j or •!,: M3
Initial calibration Data: 08-22-99
Inatzunent XDl AutoSp«c
GO Column ID: 30m SPB
Saipl* Data Filmaim: 4807*91
Blank Data Fil*nanw; 4*07891 13
Cal. v»r. Data filcnama; 4807891 f2
Concentration Dnita (pg)
ZON
RATIO LABELED COMPODHD8
0.78 13C-PCB-77
1.43 13C-PCB-118
1.55 13C-PCB-105
l.fiS 13C-PCB-126
1 . 63 13C-PCB-167
1.54 13C-PCB-156
.27 13C-2CB-157
.23 13C-PCB-169
.23 13C-PCB-180
.31 13C-PCB-H9
.04 13C-PCB-209
.17
.07
^f C. " S&^pV*^*^ VWf 0ej»AX»
'ClEAHUP STANDARD
13C-PCB-81
13C-PCB-111
SPIKK
COHC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
1000
5000
COHC. IOM
FOUND R(%) RAIIO
1039 52 0.79
1304 £5 1.57
1456 73 1.56
1100 55 1.59
1311 66 1.29
1352 £8 1.27
1352 68 1,27
1328 66 1.25
1173 59 1.00
1251 £3 1.02
2691 67 1.19
207 21
1381 28
-------
•71
CO
Lab Name; Battelle
Matrix: Air
Sample Receipt Date: 0721 99
Ext. Date: 07-28-99
Analysis Date: 21-SEP-99 Time: 00:08:21
Extract Volume fuL): 20
njectfon Volume (uL): 1
Dilution Factor: 1:25
Concentration Units: pg/sample
ivieinoa IDDO ri^a uaia jjneer
Lab Sample ID: 48190-09-03 BH-R3-PCB
Sample WtA/ol: 1.00
Initial Calabration Date: 08-22-99
Instrument ID: AutoSpec
GC Column ID: 30m SPB
Sample Data Filename: 4807897
Blank Data Filename: 4807891 #3
Cat. Ver. Data Filename: 4807891 #2
Analyte
PCB-77
PCB-123
PCB-118
'CB-114
PCB-105
PCB-126
PCB-167
PCB-156
PCB-157
PCB-169
PCB-1BO
'CB-170
PCB-18i
Cone. Found
46,055.37
Detection Limit
0.00
Ion Ratio
0.78
'This is a sample rerun at a higher dilution factor to bring PCB-77
into range
Concentration units (pg)
Labeled Compounds
13c-PCB-77
13c-PCB-118
13C-PCB-105
I3C-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
Pre-Sampling Surrogate Stds
13c-PCB-81
13C-PCB-111 •
Spike Cone.
Cone, Found
Ion Ratio
-------
Method 1668 PCB Data Sheet
Lab Name: Battedo Lab Sample ID: 481 90-09-04 BH-R4-PCB
Matrix: Air Sample Wt/Vol: 1 .00
Sample Receipt Date: 07-23 99 Initial Celebration Date: 08-22-99
ExL Date: 07-28-99 Instrument ID: AutoSpec
Analysis Date: 23-AUO-99 rime: 22:1 8:22 GC Column ID: 30m SPB
Extract Volume {uLJ: 20 Sample Data Filename; 4807891
Injection Volume (uL): 1 Blank Data Filename: 4807891 #3
Dilution Factor: 1:2 Cal. Ver. Data Filename: 4807891 #2
Concentration Units: pp/sample
Analyte
PCB'77
PCB-123
PCB-118
PCB-114
PCB-105
PCB-126
PCB-167
PCB-156
PCB-157
PCB-169
PCB-180
PCB-170
PCB-189
Cone. Found
47,360.38
228.87
13,685.62
854.79
5,807.49
1,388.17
857.94
900.21
900.21
901.82
. 5,479.13
2,815.88
272.36
Detection Limit
0.00
10.52
7.64
18.22
8.58
8.03
4.09
7.50
7.50
2.68
8.91
5.70
4.76
Ion Ratio
0.78
1.43
1.55
1.66
1.63
1.54
1,27
1.23
1.23
1,31
1.04
1.17
1.07
Concentration units (pg}
Labeled Compounds
13C-PCB-77
13C-PCB-118
13C-PCB-105
13c-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13c-PCB-180
13C-PCB-189
13C-PCB-209
Pre-Sampling Surrogate Stds
13C-PCB-81
13C-PCB-111
Spike Cone.
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
8000
2000
10000
Cone. Found
2078
2608
2912
2200
2622
2704
2704
2656
2346
2502
5382
414
2762
R{%)
52
65
73
55
66
68
68
66
59
63
67
21
28
Ion Ratio
0.79
1.57
1.56
1.59
1.29
1.27
1.27
1.25
1
1.02
1.19
-------
OPUSq-j«n 29 -AOO-1999
' f
tab Name: lATTEIAB
Matrix: aix
S«rapl« R.caipt Dat*s 07-23-99
Kit. Data: 07-28-99
Analytic Date: 25-AUG-99 Jismt
•attract Volua* (oi) t 20
Injection VolOM (ul.) i 1
Dilution Factor i 1:2
Concentration Unit*: pg/dacta
CONC.
WttliFDI rOOHD
tCB-77 *
FCB-123 *
FCB-11B *
VCB-114- *
PCB-105 I *
PCB-12S I *
PCB-1S7 109.38
PCB-1SS 196,50
FCB-157 74.42
PCB-169 130. €3
PCB-180 *
BCB-170 *
PCB-169 *
Fag* 1
Method 1668 FOB Data Sheet
Lab Sample ID: 48190-09-04 BH-R4-PCB
Sainpl* Wt/Vcl: 3.3500 g or mL; M3
Initial Calibration Data; 08-24-99
Instrument ID: Autospvc
12:08:28 oc Column ID: 30ra DB1
S«atpl« Data FilenaM: 4807892
Blank Data FilanaBM: 4807892 17
Cal. V.r. Data Fil*naraai 4807892 14
Concentration Unit* (pg)
DKTBCTIOH ION
tlHir RATIO LJtBELBD COMPOUHDS
* 13C-PCB-77
* 13C-PCB-118
* 13C-PC8-105
* 13C-PC8-126
* 13C-PCB-167
* 13C-PC8-15S
5.22 1.20 13C-PCB-157
5.40 1.25 13C-PCB-169
4,77 1.22 13C-PCB-180
2.43 1.25 13C-PCB-189
* * 13C-PCB-209
* *
* *
CLKANOT STAHDARD
UC-tCB-81
13C-PCB-111
Bag* 18 of 18
ffPIKK COHC. ION
CONC. FOUWD R<%) RATIO
2000 * * • *
2000 * * *
2000 * * *
2000 * * *
2000 1537 77 1.25
2OOO 1C7S S4 1.28
2000 1S48 82 1.23
2000 2019 101 1.24
2000 • * *
2000 * * *
4000 * * *
1000 * *
5000 * *
-------
10
Method 1668 PCB Data Sheet '
Lab Name: Battefle Lab Sample ID; 48190-09-04 BH-R4-PCB
Matrix: Air Sample WWVol: 1.00
Sample Receipt Dr.te: 07-23 99 Initial Calabration Date: 08-24-89
Ext. Data: 07-28-^0 Instrument ID: AutoSpec
Analysis Date: 25-Aug-99 ' ime: 12:08:28 GC Column ID: 30m DB1
Extract Volume (ut.): 20 Sample Data Filename: 4807892
Injection Volume (uL): 1 Blank Data Filename: 4807892 #7
Dilution Factor; 1:2 Cal. Ver. Data Filename: 4807892 #4
Concentration Units: pg/sample Concentration unite (pg>
Analyta Cone. Found Detection Limit
PCB-77 * *
PCB-123 *
PCB-118
PCB-114 * *
PCB-105 * *
PCB-126 *
PCB-167 732.85 34.97
PCB-156 1,316.35 36.18
PCB-157 498.61 31.96
PCB-189 875.22 18.28
PCB-180
PCB-170 *
PCB-189 *
ton Ratio Labeled Compounds
* 13C-PCB-77
13C-PCB-118
13c-PCB-105
* 13C-PCB-126
13C-PCB-167
* 13C-PCB-156
1.2 13c-PCB-157
1.25 13C-PCB-169
1.22 13C-PCB-180
1.25 13&PCB-189
13C-PCB-209
*
*
Pre-Sampling Surrogate Stds
13C-PCB-81
13C-PCB-111
Spike Cone. Cone. Found R(%)
4000 * *
4000
4000 * *
4000 * *
4000 3074 77
4000 3352 84
4000 3298 82
4000 4038 101
4000 * *
4000 * *
8000
2000
10000
Ion Ratio
*
*
*
*
1.25
1.28
1.23
1.24
*
*
*
-------
Lab Name: Battet'e
Matrix: Air
Sample Receipt Dale: 07-2 i-99
Ext. Date: 07-2&-T9
Analysis Date: 21-SEP-99 Time: 01:12:18
Extract Volume (uL): 20
injection Volume (uL): 1
Dilution Factor: i ;25
Concentration Units: pg/sample
Method 1668 PCB Data Sheet
Lab Sample ID: 48091-09-04 BH-R4-PCi
Sample WtA/ol: 1.00
Initial Catabration Date: 08-22-99
Instrument ID: AutoSpec
GC Column ID: 30m SPB
Sample Data Filename: 4807897
Blank Data Filename: 4807891 #3
Cal. Ver, Data Filename: 4808971 #2
Analyte
PCB-77
PCB-123
PCB-118
PCB-114
PCB-105
PCB-126
PCB-167
'CB-156
CB-157
PCB-169
PCB-180
PCB-170
PCB-189
Cone. Found
14,606.13
Detection Limit
0.00
Ion Ratio
0.78
'This is a sample rerun at a higher dilution factor to bring PCB-77
into range
Concentration units (pg)
Labeled Compounds
13C-PCB-77
13c-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
Pre-Sampling Surrogate Stds
13C-PCB-81
13C-PCB-111
Spike Cone.
Cone, Found
Ion Ratb
-------
OPOBquan 22-8 '.F-1999
Pag* 1
CO
0>
Pag* 13 of 13
' H*thod 1(68 FOB Data fih**t
Lab Maraet BA !
Matrix) AIR
Sample Reeel>t Datet 07-23-99
Bxt. Datei 07-28-99
Analytic Dat*t 21-I0-99 Xla»i 01112:18
Extract Volume (nL)t 20
Injection Volume (uL)t 1
Dilution Factor)
Concentration Onltai pg/d*c
AHAIiTTB
PCB-7T
Lab 8wnpl« IDi 48190-09-04 BH-R4-FCB
Sample Wt/Vol: 3.3500 g or mL: M3
Initial Calibration Date! 08-22-99
Instrument ID: AutoSpec
OC Column ID: 3On SPB
Banple Data Filename) 4807897
Blank Data Filenamei 4807891 §3
Cal. Ver. Data Filenamet 4807891 t2
Concentration Onita (pg)
DETECTION
LIMIT
LABELED COMPOUNDS
52623
5051C
4C083
41120
3946
4
32889
36906
29028
42871
13C-PCB-12
13C-PCB-1S7
13C-PCB-15S
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
105
CB-126
-167
8-156
IB-157
IB-169
3-180
CB-170
STANDARD
C-PCB-81
13C-PCB-111
-------
E-2-2
Sewage Sludge Fractions
E-37
-------
ITi
CO
CO
OPOBcfuin 29- a.OQ-1999
Pag.
12
Pag* 12 of 16
' Method 1668 PCB Data Bhe«t
Lab Nan*: 1 ATWUJI
Matrix: 8L DOS
Banpla Receipt batni
Ext. Data: 08-08-99
07-21-99
Analyai* Dflt»i 22-AOG-99 Tims:
Extract Volum* luL) i
ISO
20:44:31
Injection VoluM (uL) : 1
Dilution Fact on HOWE ''
Conc«ntrat on Unltn
py/g dry
CONG. DETECTION
ANALTTE
PCB-77
PCB-123 ...
PCB-118
PCB-114
PCB-103 i
PCB-126 I
PCB-167
PCB-156
PCB-157
PCB-169
POB-180
fOB-170 '
PCB-189
rOOND
40898.90
231.41
12250.28
691.47
7014.72
1118.20
•78.21
1122.17
1122.17
452. SS
6002.29
2526.24
180.52
LIMIT
0.00
105.45
76.64
132.38
101.16
89.61
81.94
65.77
65.77
50.47
68.61
82.90
45.13
L«i) Sanpl* ID! 48190-15-08 3-R2-213B
0aoq>l* Ht/Vols 0.1561 g or HLt g
Initial Calibration Dat«: 08-22-99
In»t rumsnt ID i Auto8{MC
GC Column IDi 30m SPB
S«npl« Data ril«nan»: 4807890
Blank Data Pil»nam«! 4807890 |7
Cal. V.r. Data fllmaiM; 4807890 |3
Concentration Unit* (pg)
ION 8PIKR CONG .
RATIO LABELED COMPOUNDS COHC. FOUND
0.77 13C-PCB-77 . J«OOT\ 7330
1.45 13C-PCB-11B 20 Off 1 6921
1.5S 13C-PCB-10S 2006 I ^ rtfi 7085
1.63 13C-PCB-12* 20MJ >l*| 599*
1.69 13C-PCB-167 20AO [ |> 66K
1.57 13C-FCB-15S ZOWO 1 6527
.18 13C-fCB-157 2POO 1 6527
.24 13C-PCB-169 3000 1 5256
,24 13C-SCB-180 £000^ 7419
.18 13C-FCB-189 SOW -, 7181
.05 13C-PCB-209 40S8-30," 126S3
.04
.09
CLEANUP STANDARD \gtffi
13C-PCB-81 MWT" ' jjfl 2371
13C-PCB-111 SOW jjj 13937
ION
R(%) RATIO
49 0.76
46 1.S6
47 1.54
40 1.55
44 1.26
44 1.24
44 1.24
35 1.23
49 1.02
48 1,03
42 1.20
40
46
-------
OPUSrn>an 29 AO3-1999
Fag* 12
Method 1668 PCB Omtm ab**t
Lab NaiM: iATTELLB
Matrix! SI iDQB
Baicplc Rcolpt Data: 07-21-99
Ext. Cat*I 08-08-99
Jtnalyal* Dat«i 2C-ADQ-99 Ti»a: 02:41:34
Extract Voltatt (UL)i 150
Injection Volm* (uL) t 1
Dilation Factors HODS *'
Concentration Onitai pg/g dry
Lab Sampl» IDs 48190-15-08 S-R2-213B
Sanpl* Kt/Vol: 0.1561 g or inL: g
Initial Calibration Data: 08-24-99
Inatrument ID: AutoSpoc
GC Colimn ID: 30B DB1
Sanpl* Data Filenanw! 4807893
Blank Data Filanama: 4807893 13
Cal. V«r. Data Fil«nan»: 4807893 12
Concentration Unit* (pg)
AHM.1TB
PCB-77
PCB-123
PCB-118
tCB-114
PCB-105 I
PCB-126 1
PCB-1S7
PCB-15S
PCB-157
PCB-169
PCB-180
PCB-170
fCB-189
CONG.
room
912.01
1772.41
472.44
1
t
«
t
DBTBCTK
LIMIT
'
I 134.0:
t 179. S3
I 168.7:
' 155. 5!
> t
i i
i t
IH ION
RAT;
1 1.3(
! 1.24
1 1.2!
> t
t t
t t
1 • t
10 LABELED COM
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-JPCB-126
13C-PCB-167
13C-PCB-15S
) 13C-PCB-157
1 13C-PCB-169
! 13C -PCB-180
» 13C-PCB-189
t 13C-PCB-209
t
t
CUBWTOP BTXHDARD
13C-PCB-81
1000
5000
Pag* 12 of 16
8PIKK
CONG.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
CONG.
FOUND
*
*
*
*
8666
933S
9191
8977
*
*
*
R(%)
* -
*
*
*
SB
«2
61
60
*
*
*
IOM
RATIO
*
*
*
*
1.26
1.27
1.27
1.2C
*
*
*
-------
OPOSqujn 29- iUO-1999
P»ge 13
m
Pag* 13 of 16
Method 16«8 PCB .Data Sheet
tat Nanwt B kfZBUJt
Matrix: ttJUO MM
•ample Receipt Pate: 07-21-99
Ext. Datei 08-08-99
Analyala Datei 22-AOO-99 Tlnei 21:48:16
Extract Volume (to.) i ISO
Injection VolttM (UL) I 1
Dilution ractort Mom "
Concentration Dnitai py/g dry
AHAX.R8
fCB-77
KS-123
PCB-118
PCB-114 .
PCB-105 i
PCB-126 I
ECB-167 *
PCB-1SS
PCB-157
PCB-169
rCB-180
PCB-170
PCB-189
Lab Sample IDi 48190-15-09 8-R2-313B
Sanpl* Nt/Voli 0.1307 9 or nLi 9
Initial calibration Data: 08-22-99
Instrument XDf AutoSpec
CC Column IPI 30m SPB
Saopl* Data filanaM : 4807890
Blank Data Fll*nanwi 4807890 |7
Cal. Var. Data Filenana: 4807890 13
Concentration Onlt* (pg)
cove.
FOOHD
11095.68
276.46
13496.60
674.09
7389.05
1213.53
967.83
1186.88
1186.88
600.79
6780.09
2572.23
197.98
DBTBCTIOH
LIMIT
0.00
138.12
100.38
169.24
129.33
115.30
104.01
82.78
82.78
67.43
85.40
103.18
56.43
ION
RATIO
0.79
1.50
1.57
1.66
1,72
1.46
1.27
1.18
1.18
1.28
1.01
1.03
1.00
LABEUD COMPOUNDS
13C-JCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-KS-189
13C-PCB-209
BTDOI
COMC.
COMC.
«(*>
46
48
49
41
44
44
44
34
50
48
45
ION
RAX SO
0.74
1.57
1.5S
1.54
1.25
1.23
1.25
1.25
.04
.03
1.
1.
1.19
CLEANUP STANDARD
13C-PCB-81
3»l
2179
13279
36
44
-------
OPQSquan 29- AOG-1999 tag*
13
Page 13 of 16
', Method 1668 PCB Data Sheet
Lab H»JW»: 1 A.TTBLLK
Mateis : SL. DOB
Sample R«c«.ipt Data: 07-21-99
Ext. D*t»: 08-08-99
JUialyalc Dat»l 26-AW3-99 Tij»»! 03127:52
Extract Voliuaa (uL) t 150
Injection Volume (uL) ! 1
Dilution Fact on HONB
Concentration Dnitat pg/g dry
COHC. DETKCTIOH
ANALTTB FOUKD LIMIT
PCi-77
PCB-123
PCB-11S
pca-114
PCT-105 I
PCB-126 i
PCB-167 9*3.93 159.12
PCB-156 1882.59 209. 09
PCB- 137 564.33 204.51
FCB-169 * 181.32
PCB-180 * *
PCB-170 * *
PC3S-189 * *
Lab S»mpl* IDi 48190-15-O9 S-E3-313B
S»mpl« Wt/Vol: 0.1307 g or tnL: g
Initial Calibration Data: 08-24-99
Instrument ID : AutoSpao
GC Column ID: 30m DB1
Sample Data Fllanana: 4B07893
Blank Data Filename! 4807893 13
Cal. Ver. Data Filename: 4607893 12
Concentration Unit*, (pg)
IOH
RATIO LABELED COtCOOHDS
13C-JC8-77
13C-fC8-ll«
13C-FCB-105
13C-PCB-126
13C-PCB-1S7
13C-PCB-1SS
1.3C 13C-PCB-1B7
l.SO 13C-fC8-l«9
1,13 13C-fCS-l«0
* 13C-PC8-189
* 13C-PCB-209
*
*
ClMXKm BTAMDRRD
13C-PCB-81
13C-PCB-111
SPIKB CONG. IOU
CONC. 7OOHD R(%) RATIO
2000 * * *
2000 * * *
2000 * * *
2000 * * *
2000 8039 54 1.27
2000 8863 59 1.27
2000 8542 97 1.23
2000 840* 56 1.26
2000 * * *
2000 * * *
4000 * * *
1000 * *
5000 * *
-------
M
OPDSquan 29- MHJ-1999
t
Lab Name I I ATTELI£
Matrix! 0V DOS
Bajiple Rer- ipt Ditei
Bxt. Date i 09-08-99
Page
14
Page 14 of 16
Method 1668 PCB Data Sheet
07-23-99
Analyai* Datei 22-AOO-99 MJMI
Rxtract Volume (uL) t
150
22:52:03
Injection volune (ttL) : 1
Dilution Fact or i NOB
Concentration Units I
ANALTTB
SCB-77
PCB-123 -
PCB-11B
PCB-114
PCB-105 t
PCB-126 1
PCB-167
PCB-156
PCB-157
PCB-169
PCB-180
pcB-no
PCB-189
• ''
99/9 **V
COHC.
FOUND
45385.81
241.49
12836.01
737.80
7288.98
1479,39
959.36
1177.55
1177.53
655.78
6711.30
2776.46
217.61
DETECTION
LIMIT
0.00
131.19
95.35
162.43
124.13
112.41
100.59
81.09
81.09
64.95
•6.79
104.86
56.30
Lab Sample IDi 48190-15-10 S-R4-413B
Sample Kt/Voli 0.1425 g or mL: g
Initial Calibration Date: 08-22-99
Inatrament IDt AutoSpec
GC Column ID > 3 OB SPB
Sample Data Filename! 4107890
Blank Data Filename: 4807890 |7
Cal. Ver. Data Filename: 4807890 |3
Concentration Unit a (pg)
ION SPIKB COHC. ION
RATIO LABBLKD COMPOUNDS CONC. FOOND R(%) RATIO
0.79 13C-PCB-77 «9««?i 7298 49 0.74
1.61 13C-PCB-118 2000/1 ,«8 7384 49 1.57
1.53 13C-PCB-10S ZOOfflpI1^ 7536 50 1.57
1.70 13C-PCB-126 200*7 6233 42 1.54
1.6S 13C-PCB-167 20CTO 7221 48 1.25
1.69 13C-PCB-156 2OOO 7140 48 1.26
1.22 13C-PCB-157 2BOO 7140 48 1.26
1.33 13C-PCB-169 afOOO 5493 37 1.23
1.33 13C-PCB-180 SBOOJ 7964 53 1.04
1.23 13C-PCB-189 *ttnlt> jj 7685 51 1.03
1.06 13C-PCB-209 4«»0 >yj fr 14559 49 1.20
1.08
1.01
CLEANUP STANDARD . ..ftO
13C-PCB-81 *««r «^ 2413 40
13C-PCB-111 5«0tl 2ffP* 13926 46
-------
OPUSqutn 2! -AUQ-1999 p»g«
14
Pag* 14 of 1«
* Method 1661 PCS Data Sheet
Lah MUM! IMTTKUB
Mat-rixi SIJDOE
flan-pi* Receipt Data: 07-23-9$
Ext. Cat*: OB-03-99
Analyai* Dat*i 26-AUO-99 Ti»e: 04:14:11
Extract Volura* (ttL) t 150
Injection Volume (ul) : 1
Dilution Factor i moot "
Concentration Onitai pg/g dry
COHC. DKTBCTIOH
AHA1TTB FOUND LIMIT
fCB-77 *
PCB-123
tCB-118
PCB-1H
fCS-105 1
PCB-126 I
PCB-167 971.88 140.68
PCB-156 1875.97 193.19
PCB-157 336.21 181.24
PCB-169 546.B1 168.28
PCB-180 * *
PCB-170 * *
PCB-189 * *
Lab 3nmpl« ID: 48190-15-10 S-R4-413B
Bampla wt/Vol: 0.1425 g or mL: g
Initial Calibration Date: 08-24-99
InBtmment ID: AutoSpoc
GC Coliunn ID: 30m DB1
Banpl* Data Fllanaim: 4807893
Blank Data rilvnami 4807893 *3
Cal. V»r. Data rilmana: 4807893 |2
Concentration Dnita (pg)
ION
RATIO LABELED COMPOUNDS
13C-PCB-77
13C-PCB-118
13C-PCB-10S
13C-PCB-126
13C-PCT-1S7
13C- PCB-156
1.27 13C-PCB-157
1,23 13C-PCB-159
1.16 13C-PCB-180
1.32 13C-PCB-189
* 13C-PCB-209
*
*
CLEANUP STANDARD
13C-PCB-81
13C-BCB-111
BPUCB CONC. ION
COMC. FO01ID R|t) RJHIO
2000 * * • *
2000 * * *
2000 * * *
2000 * * . *
2000 8407 56 1.29
2000 8997 CO 1.29
2000 8801 59 1.2S
2000 8490 97 1.28
2000 * * *
2000 * * *
4000 * * *
1000 * *
5000 * *
-------
E-2-3
Scrubber Water Inlet Fractions
E-44
-------
m
A
01
OPOSab Earapl* ID: 48200-56-03 WT-R2-211B
Samplo Wt/Vol: 0.4950 g or ml,: L
Initial Calibration Data: 08-22-99
In»trum»nt ID: Auto>p«c
GC Column ID: 3On SPB
Bmeplf Data Filename: 4807(90
Blank Data rilanama: 4807890 |7
Cat. v»c. Data Fil*nan*t 4807890 13
Concantration Onlt» (pg)
COHC.
FOUND
158.49
177.42
1200.85
233.78
689.92
23.98
1*5.96
197.55
197.55
26.76
338.28
105.22
29.03
DETECTION
LIMIT
0.00
5.95
4.32
6.84
5.23
3.42
3.49
2.75
2.75
1.49
2.87
3.46
1.71
ION
RATIO
0.80
1.52
1.55
1.72
1.54
1.74
1.24
1.25
1.25
1.13
1.G1
1.07
1.04
LABELED COWOUHD9
13C-PCB-77
13C-PCB-118
13C-FCB-105
13C-PCB-126
13C-*CB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
SPIKE
COHC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
COHC.
row
RATIO
952
910
996
1149
1057
108€
1066
1207
1180
1268
2533
48
45
50
57
S3
54
54
60
59
63
63
0.77
1.60
1.55
1.56
1.25
1.23
1.23
1.23
1.02
1.03
1.20
CUUHOP STANDARD
13C-PCB-81
13C-FCB-111
1000
sooo
585
2715
58
$4
-------
OPUBquan 29- MW-1999
fag* 4
Pag* 4 of 16
Method 1668 PCB Data Sh««t
t»b NMM*! 1
Matrix: WA SR
Srapl* .Itoe-.Ipt Data! 07-21-99
Ext. Date; 07-28-9!
An»ly»i« Data: 25~i03-9» TliMi 19:44:18
Kzfcract Voluma (ttL) i 20
InjactloD VoluM (uL)s 1
Dilution Factor! WOM
Lab Sanf>l* IDt 48200-56-03 WI-«2-211B
8»mpl» Ht/Vol: 0.4950 g or mL: I
Initial C«ltbt»tion D»t«: 08-24-99
In«trument ID: Autospec
OC Coliran XD: 30m DBl
8a*pla D«t» Fllanuna: 4807893
Blank Data riUnam*: 4807893 |3
Cal, V«r. Data Pilanaow: 4007893 |2
Concantcatlon Dnltn
Concentration Dnit»
m
o>
AHALTTg
FCB-77
PCB-123
. PCB-118 .
PCB-114
PCB- 103 1
PCB-126 5
tCB-187
PCB-156
KZB-157
PCB-169
PCB-180 _
PCB-170
PCS-IB*
COMd.
room
•
191.1!
242. 9(
168.6!
22.73
t
•
<
DETECTION I0«
LIMIT RAJ:
*
* •
*
*
*
*
1 5.34 1.2<
1 €.13 1.2!
i 6.2i 1.23
1 0.00 1.22
i * t
< * t
t t
tO 1ABEL1D COMPOUNDS
13C-PCB-77
13C-PCB-118
13C-PCB-10S
13C-PCB-126
13C-PCB-1«7
13C-PCB-156
> 13C-SCB-157
> 13C-PCB-169
! 13O-PCB-180
1 13C-PCB-189
' 13C-PCB-209
>
r
nxrx,
sane.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
COKC.
FOUMD
*
*
*
*
1180
130 <
1323
1«75
*
*
A
RW
*
*
*
*
59
65
fit
84
*
*
*
ION
KUXO
*
*
*
*
1.28
1.27
1.27
1.2S
*
*
*
CI.RANUP STANDARD
13C-PCB-81
13C-PCB-111
1000
SOOO
-------
OPUSqunn 29-MJG-1999
Pag* 5
Pmgm S at 16
Method 1666 PCS Data Stm«t
Lab Mama i I MTE1AB
Matrix: UK SR
Sample Receipt Datei 07-21-99
Bxt. Dates 07-28-99
Analyaia Data: 22-10O-99 Tine: 11:10:12
Extract Velum fuZ.) : 20
Injection Volune (uL)i 1
Dilation Fact or i HOOT "*
Concentration ttaitat P9/X*
MJALYTE
PCB-77
PCB-123
PCB-118
' PCB-114
fCB-105 |
PCB-126 i
PCB-167 '
PCB-15S
PCB-157
PCB-169
PCB-180
PCB-170
PCB-189
L«b Bangle IDi 48200-56-05 KI-R3-311B
Sample Kt/Vol: 0.49SO g ox aLs I>
Initial Calibration Date: 08-22-99
Inatrumsnt ID: Jlntoapec
OC Column ID: 30m SEE
Simple Data Filename: 4807(90
Blank Data Fllenjune: 4807*90 |7
Cal. v.r. Data Filenamet 4807890 |3
Concentration Unit* (pg)
CONC.
FOUHD
166,40
31.SS
1064,73
67.98
490,59
6.91
44.38
55.81
55.81
5.81
189.56
79.88
9.14
DETECTION
LIMIT 1
0,00 1
6.21
•4.52
7.76
5.93 :
3.66
4.05
3.28
3.28
1.73
3.23
3.91
2.12 1
[ON
WHO
J.79
L.S2
1.56
1.59
L.58
.47
.31
.30
.30
.28
.00
.07
L.ll
LABKLED COMPOUNDS
13C-PCB-77
13C-PCB-118
13C-PCB-105
130-PCB-126
13C-PCB-167
13C-?CB-156
13C-PCB-157
13C-PCB-169
13C-PCB-190
13C-PCB-189
13C-PCB-209
SPIKE
CONG.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
cone.
FOUND
1234
1174
1183
1427
1251
1226
1226
1404
1511
1511
3014
R(*»
62 •
59
59
71
63
61
61
70
76
76
75
XOH
RATIO
0.76
1.58
1.58
1.56
1.26
1,25
1.25
1.25
1.02
1.03
1.20
CLEANOT STMTOARD
13C-fCD-81
13C-PCB-111
1000
5000
735
3382
74
•a
-------
OPDSquan 29- \OQ-1939
Fag* «
Pag« £ of IS
Hathod 1CC8 PCS Data 3ho«t
Name: UTTELIi
Matrix i WA-.2F.
Sanpl* R«c* Ipt Cat*! 07-21-99
Bxt. D«t*t 07-28-99
Analyala Data: 25-AUQ-9* TUat: 21:17101
Extract VbloM (oL)I 20
Injection Volune (uL) i 1
Dilation Factor! HOn
Concentration Dnitai pgr/t
Lab Sample ID: 48200-56-05 WI-R3-311B
Sample Wt/Vol: 0.4950 g or B&I L
Initial Calibration Date: 08-24-99
Instrument ID: AutoBpec
QC Column ID: 30a DB1
Sample Data fll*naa»i 4807893
Blank Data Filen««ai 4807B93 »3
Cal. Ver. Data Pilana»e: 4807893 |2
AMAI.TTI
FCB-77
FCB-123
PCS-118
FCB-114
PCB-105
PCB-126
PCB-167
PCB-156
PCB-157
PCB-169
PCB-180
PCB-170
CCB-189
COHO.
room
42.1*
89.2S
28.49
*
*
*
*
MTSCTIOM
LIMIT
*
*
*
*
*
*
c.oc
8.10
0.00
S.29
*
*
*
ION
RATIO
1.35
1.21
1.09
*
*
*
*
Concentration Unit* (pg)
IAB3LED COMPOUNDS
13O-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-1S7
13C-PCB-156
13C-PCB-157
13C-PCB-1S9
13C-PCB-180
13C-PCB-189
13C-PCB-209
SPHOt
COKC.
2000
2000
2000
2000
2000
2000
.2000
2000
2000
2000
4000
COMC.
FOUHD
*
*
*
*
1444
1571
14SC
2081
*
*
*
*C»)
*
*
*
*
72
79
73
104
TOM
RATIO
*
*
*
1.29
1.25
1.21
1.26
*
*
*
CLEAKtTP STANDARD
13C-PCB-81
13C-PCB-111
1000
SOOO
-------
OPUBqcan 21 SEP-1999
^ P»g« 1
Pag* 19 of 19
Method 1668 ECB D*t» 8b««t
Lab Ham*: ItTTBLLE
Itetrix: MUTER
Uamplr. Receipt Date: 07-23-99
Ext. Date: 07-28-99
Analyaia Date: 20-SKP-99 Time: 22:00:33
Extract Volume (tiL) i 20
Injection Volune (UL): 1
Dilution Pactori MOVB
Concentration Onit*i pg/L
Lab Simple ID: 48200-56-07 HI-R4-411B
Sample Ht/Vol: 0.4950 g or inL: L
Initial Calibration Cat*: 08-22-99
Instrument ID: ButoSpec
OC Column ID: 3On SPB
Sample Data Filename: 4807897
Blank Data Filename: 4807890 17
Cal. Ver. Data Filename: 4807890 §3
Concentration Unita (pg)
m
^
CO
AHALYTB
ECB-77
PCB-123
FCB-118
PCB-1H
ECB-105
PCB-126
PCB-167
PCB-156
BCB-157
PCB-169
FOB- 180
PCB-170
PCB-1B9
COHC.
POUND
138.01
17.76
10S9.00
45.12
504.35
3.6<
36.08
47.76
47. 7€
1.97
176.56
78.25
5.12-1
DETECTION
LIMIT
0.00
5.07
3.68
C.55
5.01
3.18
3.86
3.13
3.13
1.84
3.12
3.7*
tPlPtr2.03
I OM
RATIO
0.77
1.75
1.58
1.55
l.SS
1.58
1.19
1.20
1.20
1.1S
1.00
1.01
1.04
LABELED COMPOUNDS
13C-8CB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-1CB-157
13C-PCB-169
13C-PCB-180
13C-TCB-189
13C-PCB-209
SPIKB
COMC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
COHC.
FOOND
1662
1187
1174
1347
114*
1122
1122
1178
1104
1074
1670
M%»
83
59
59
67
57
5$
56
59
55
54
42
ION
RATIO
0.74
1.56
1.S6
1.56
1.23
1.23
1.23
1.23
1.01
1.03
1.19
CLEAHTJP 8IAKDARD
13C-PCB-81
13C-PCB-111
1000
5000
1071
4236
Ofl*
-------
22- 1EP-1999
P«g« 19 of 19
I F VTTBLLH
S«rapl« Mo*Lpt Data; 01-23-99
But. Data: 07-28-99
Analyai* Dtt»: 21-8EP-9* Tlmat 18:38:0*
•Xtraet Voluma (tt!,) i 20
Injection Vein** (ul.) i 1
Dilation Fact or i
Machod 1668 PCB Data Shmt
Lab aanpl* ID: 48200-55-07 WT-R4-411B
Sample Wt/Vol; 0.4950 g or raL: I>
Initial Calibration Data: 08-24-99
Inatrtonant ID: Autospac
OC Column ID: 30» DB1
Sanpl* Data Pilanan-i 4807I97A
Blank Data rilanaowi 4007093 «3
Cal. Var. Data ril*n«Mi 4807893 12
Concentration Dnltai pq/I.
Concentration Onita (pg)
Itl
01
O
AHALTTK
P08-77
PCB-123 -
PCB-118
PCB-114
twn i &tt »
PCB-12* |
PCB-167
PCB-156
PCB-1S7
PCB-169
PCB-180
PCB-170
PCB-189
CO»C. DETBCTIOH IOH
VOVHD LIMIT RATIO LABBLKD COMPOUNDS
* 13C-PCB-77
13C-PC»-11«
13C-PCB-105
13C-PCB-12S
13C3— PCB— 1 67
13C-PCB-158
— • 93 .89 t.73 It-**- tP 13C-PC3B-137
•0,47 ».00 1,30 13C-P«a-169
19. 9< 9.27 1.19 13C-PCB-180
*a * "> T 3 fi 1 T T n 1 1f* f*ff1 - 1 R t
» * * , 13C-PCM-209
* * *
* * *
. CLEANOP STANDARD
jL. jwweM-"*-*^^ 13C-PCB-81
Q5 ^"^ T* 130-PCB-tll
BPHCB
COKC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
1000
3000
COHC.
FOOHD
*
*
*
*
13CJ
1334
1299
*
*
*
*
*
IOH
R(%) RATIO
*
*
*
*
liC t TB_ CD
67 1.29
65 1.28
— n rr*s — .&
* ' *
* *
* *
*
*
-------
I
I
I
I
I
I
I
I
I
1 E-2-4
Scrubber Water Outlet Fractions
i
i
i
i
i
i
i
i
E-51
-------
m
01
ovmquan 29 -Ana-lags
I
Lit Nam»i VATTSUUB
Matclx; mrSR '
Sample lUolpt Dat«t 07-21-99
4
Ext. D»t«: 07-21-99
Analyii* Dat*t 22-MKJ-99 Haw:
Extract 7olua* (uL) t 20
Injection Volu»» (m.) i 1
Dilution r motor I MOMS "
ConoantratioD Onitvt P9/L
AHALTTB
BCB-77
PCB-123
PCB-116
' PCB-114
PCB-105 i
PCB-126 i
PCB-167 •
PCB-156
PCB-1S7
PCB-169
PCB-180
PCB-170
ECB-189
COHC,
ffJUMD
4163.23
85.79
1«75.B2
136,38
945.62
134.52
158.39
179.21
179.21
113.49
€85.99
264.31
30.12
tmgm
4
Mabhod 1«68 PCB Date Sb*«t
L«i> Sampl* ID! 48200-56-04 WO-R2-212B
Sunpl* Wt/Voli 0.5000 9 or ml,! L
Initial Calibration D&t*i 08-22-99
Instrument IDi Auto*p«c
10:06:28 OC Colvmn IDi 3 On SPB
Sanpl* Data Fil.nan*! 4807890
Blank Data Filanamai 4807890 17
C»l. V»r. Data FllanuM: 4807890 |3
Conc«ntr«tlon Dnlta (pg)
DKXECTIOH
LIMIT
0.00
4.46
* 3.26
5.30
4.09
2.58
2.78
2.09
2.09
1.21
2.38
2.S8
1.35
ION
RATIO
0.78
1.59
1.54
1.62
1.61
1.54
1.24
1.24
1.24
1.39
1.02
1.02
1.07
LABELKD COMPOUNDS
13C-PCB-77
13C-PCB-1H
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-FC8-157
13C-PCB-1C9
• 13C-PCB-180
13C-PCB-189
13C-PCB-209
CTLEAHUP STAMDARD
13C-PCB-81
13C-PCB-111
BVZKB
cone.
2000
2000
2000
2000
2000
2000
,2000
2000
2000
2000
4000
1000
SOOO
cove.
FOUND
1336
1139
1222
1419
1285 .
1349
1349
1428
139C
1S01
2928
662
2635
*<*»
67
S7
61
71
64
«7
67
71
68
75
73
66
53
P«g« 4 of 16
ION
RATIO
0.77
1.S9
1.56
1.95
,. 1.23
1.2S
1.25
1.23
1.03
1.03
1.21
-------
m
01
CO
OPIJEqiian > 9-WN3-1999
.', 'f
Lab Mama BATTEUJC
Hatttxj VAXBR
Sanple fu oipt Date: 07-21-99
Ext. Data: 07-28-99
Analycii Dat*t 25-AOO-99 Time
Extract Volume (uL) r 20
Injection Volume (uL) : 1
Dilution ractori HOUR
Concentration Dnlt»i pg/L
COHC.
ANALTTE FOUMD
PCB-77 *
PCB-123
PCB-118
PCB-114
PCB-105 k
PCB-126 ]
PCB-167 148.74
PCB-156 249,32
fCB-157 119.44
PCB-1S9 110.28
PCB-180 *
PCB-170 *
PCB-189 *
Page S
Mfthod 1668 PCD Tata Sheet
Lab Sample ID: 48200-56-04 WO-R2-212B
Sample Wt/Vol: D.500O g or mL: 1,
Initial Calibration Dat«r: 08-24-99
Instrument ID: AutoSpec
20:30:40 GO Column ID: 3 On DB1
Sample Data Filename: 4807893
Blank Data Filename: 4807893 §3
Cal. Ver. Data Filename i 4807893 12
Concentration Unit* (pg)
DETECTION IOM
LIMIT RATIO LABELED COMPOUNDS
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-15S
4.78 1.28 13C-PCB-157
5.87 1.32 13C-FCB-169
S.S6 1,23 13C-PCB-180
4.01 1.40 13C-PCB-189
* * 13C-ECB-209
* *
* *
CLSAHtJP STANDARD
13C-PCB-81
13C-PCH-111
SPIKK
COMC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
1000
5000
Page 5 of 16
COMC. ION
fOOHD R(%> RATIO
* * *
* * *
* * *
* * «
1397 6* 1.26
1514 76 1.26
1920 76 1.27
1974 99 1.24
• * -*
* » *
* * *
* *
* ' *
-------
Ol
OPU8qu»n 21-sSF-1999
P*9* 18 of 19
Method 1668 PCS Data Sh«at
Lab Mane I BT. RSUJt
Mat i IX i WATHt
fl«mp]» R.cslpt Oat* I 07-31-9*
Bxt. Dat*t 07-28-99
lutimlytlf D«t«i 20-BBF-99 VilMt 20:SCt43
Extract Volume (ui( t 20
In J«ctlon Volwm (uL) i 1
Dilution raoton Horn
Concvntratlon Onltai
UULTT1
PCB-77
PCB-123
PCB-118
PCB-114
PCB-105
PCB-126
FCB-167
PCB-15S
PCB-157
PCB-169
PCS-ISO
PCB-170
PCB-189
Lab Sanpl* IDl 48200-5«-O« HO-R3-312B
Sanpl* m/Volt 0.497S g or mLi L
Initial Calibration Dat«! 08-22-99
ZnatrniBant ID: AutoSpac
OC Colutm IDl 30m 9PB
Saipl* Data ril«n«jn«! 4*07*97
Blank Data VUraaawt 4807890 *7
Cal. V«r. Data FilvnaMi 4*07890 13
Concentration Unit* (pg)
COKC.
room
304,14
63.13
3923. 87
154.91
1873.63
118.21
164.00
239.38
239.3*
80,69
1000.0*
411.95
29.82
DETECTION
LIMIT
0.00
4.96
3.60
6.15
4.70
3.24
3.9*
3.11
3.11
1.8*
3.30
3.99
2.13
IOM
RATIO
0.7*
1.56
1.54
1.73
1.60
1.54
1.23
1.27
1.27
1.33
1.02
0.99
0.97
UBStBD COM
13C-PCB-77
13C-PCB-118
13OPCB-105
13C-PCB-126
130-PCB-1S7
13C-PCB-136
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
BPHOI
COKC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
20OO
4000
cone.
FOUND
1441
1132
1172
1253
10*3
10*3
1083
1099
101C
1004
1519
M*I
72
57
5*
S3
54
54
54
55
51
50
38
ION
RATIO
0.75
1.56
1.58
1.57
1.23
1.24
1.24
1.23
1.01
1.03
1.20
CLEAHUP 8TAHDAPJ>
13C-PCB-81
13C-PCB-111
1000
sooo
•45
3666
*«*
-------
OPOSguin 22- 1EP-1999
Pag* 1
M*thod 1668 PCB Data Sh*at
Lab Mama: f \TTBLUC
Matrix: IBM «R
Sainpla R*c*lpt Dat*: 07-21-99
S*t. Dat*i 37-28-99
Analyaia Data: 21-S1P-99 Xian: 17:51:50
Extract Volujp* (m.) t 20
Injection Voltnna (uL) i 1
Dilution Factori HONE
concentration Onitat
AHALTTE
.PCB-77
PCB-123
PCB-118
8CB-114
PCB-10S ,
PCB-126 I
PCB-1S7
SCB-157
PCB-169
PCB-180
VC8-170
PCB-189
tab Sanpl* IDt 48200-56-06 WO-R3-312B
Sanpl* we/Volt 0.4975 g or MLi L
Initial Calibration Dat*: 08-24-99
Inubrmmnt IDi XutoSpac
QC Column ID: 30m DB1
Barapl* Data FilanaiMi 4B07897A
Blank Data FilanaBWi 4807893 13
Cal. V*r. Data Fil*nam: 4807893 12
Concantratlon Onita (per)
CONC . DETECTION
rOtlUB LIMIT
*
*
*
i*
*
* .
' 17t rtl IF. 2! "
109. flS 10.24
- » *
* *
IOH
RAT]
TTZ1
1.11
1.3J
i
[O LABBLBD COW
13C-PCB-77
13C-PCB-118
13C-PCB-10S
13C-PCB-126
13C-PCB-1S7
... 13OPCB-156
J"*'' 13C-PCB-157
13C-PCB-180
» 13C-PCB-209
k
CUUMOP STANDARD
130-fCB-Bl
130-fCB-lll
1000
5000
Pag* 18 of 19
UtfltJt
COHC.
2000
2000
2000
2000
2000
2000
2000
2000
4000
CONC.
FODUD
*
*
*
*
1364
1302
*
, * '
*
*f*»
*
*
*
*
68
65
*
*
*
ION
RATIO
*
*
*
*
1.29
1,27
* .
*
*
(P
-------
1
m
O)
o>
OPUSqvmn 29 -HJO-1999
f
Lab Nam*: SATTELI^
Matrix: IB n»
Saaipla Racaipt Data!
•act. Datat 07-28-99
07-23-99
Analyaia Data! 22-ADO-99 Viaai
Extract VolUBB (uL) I
Injection VoloaB (uli)
20
I 1
Dilation Factor: MODS ''
Concantrat ion tfnitai
ANALTTB
PCB-77
PCB-123
PCB-118 -
PCB-114.
PCB-105 t
PCB-126 1
SCB-167 '
PCB-156
PCB-157
PCB-169
PCB-180
SCfl-170
PCB-189
pg/Xi
COMC.
FOtnro
2520.01
50,24
1621.37
123.94
854.45
98.28
124.62
157.11
157.11
97.65
653.05
2»7.77
44.40
P.9. 6
Hathod 1668 PCB Data Bbe*t
L*b Sampl* ID: 48200-56-08 WO-R4-412B
B ample Wt/Voli 0.4975 g or aLi I.
Inttiil Calibration Data) 08-22-99
Inatnmwit TDt JUitoapae
14:21l3S eC Column IDi 30ra SPB
Suapl* Data rilanaiMt 4807890
Blank Data ril*nanat 4807890 §7
Cal. V»r. Data rilanama: 4807890 13
Coneantration 0nita (pg)
DB-ncncnt ION
LIMIT RATIO LABELED COHPOOND3
0.00 0.78 13C-PCB-77
6.18 1.56 13C-PCB-11*
• 4.49 1.57 13C-PCB-105
7.2S 1.53 13C-PCB-126
3.54 1.59 13C-PCB-167
3.54 1.55 13C-PCB-156
4. Of 1.17 13C-PCT-157
3.03 1.26 13C-PCB-169
3. OS 1.26 13C-PCB-180
1.71 1.30 13C-PCB-189
3.27 1.04 13C-PCB-209
3.96 1.03
2.00 1.03
CUtlNDP STANDARD
13C-PCB-81
13C-PCB-111
8PHCR
cone.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
1000
5000
Pag* 8 of 16
COMC. ION
FOUHD R(%) RATIO
1110 33 0.76
1011 51 1.56
1106 55 1.57
1303 65 1.54
1100 55 1.25
1139 57 1.25
1139 37 1.25
1255 63 1.24
1251 63 1.03
1300 65 1.02
2279 57 1.20
684 «»
3077 62
-------
OPOSquan 29 -AUO-1999
Page 9
Hethod 1668 PCB Cat* Sheet
I,Jh Nan*: aATTELLK
Matrix: N7TER
Baitple Receipt Datei 07-23-99
Bxt. Date: 07-28-99
Analy.i. Datel 25-AW3-99 Time: 23:36:05
Extract Volvone (uL) i 20
Injection VoltHte (uL) : 1
Dilution Factpn ROMS
Concentration Unit*; pg/L
Lab Sample ID: 48200-56-09 WO-R4-412B
Sample Wt/Vol: 0.4975 g or «Li I<
Initial Calibration Date: 08-24-99
In»trumont ID: Aiit oSpec
OC Column ID: 30m DBl
Sample Data Filename: 4807893
Blank Data Filename: 4807893 il
Cal. Ver. Data Filename: 4807893 12
concentration Unite (pg)
CLEANUP STANDARD
13C-PCB-81
13C-fCB-lll
1000
5000
Pag* 9 of 16
m
en
•sj
AHAiYTK
PCB-77
PCB-123
FCB-118
PCB-114
PCB-105 |
PCB- 12 6 1
PCB-167
PCB-156
PCB-157
PCB-169
PCB-180
PCT-170
PCB-189
cone. vm*
POOND 1
115.7*
235.47
•3.33
94.54
*
*
*
fBCIlOW I0H
jIMII RATIO
*
*
*
*
*
*
6. 1C 1.37
•,09 1.23
7.71 1.30
5.15 1.33
* *
* *
* *
LABBLED COMPOUNDS
13C-PCB-77
13C-SCB-118
13C-PCB-105
13C-»C8-12*
13C-PCB-167
13C-tCB-15«
13C-1CB-157
13C-tCB-l«9
13C-PCB-180
13C-tCB-189
13C-PCB-209
BPTKS
cove.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
COHC.
FOTHD
*
*
*
*
127T
1387
13C9
1920
*
*
*
R(t)
*
*
*
A
«4
69
68
96
*
*
*
low
RATIO
*
*
• *
»
1.28
1.25
1.27
1.24
*
*
*
-------
E-3
PCB Blanks Lab Raw Data
E-58
-------
E-3-1
Air Sampling Train
E-59
-------
OPUSqv&n 2P -AUO-1999
Page 2
Page 2 of 9
Method 1668 PCS Data Sheet
Lab Name: 3ATTBLLB
Matrix: A:a
3»nipl« Receipt Date: 07-21-99
Ext. Date.:. 08-01-99
Analyaie Date: 21-AOO-99 lime: 01:30:34
Extract Volume (uL): 20
Injection Volume (uL): 1
Dilution Factort NONB ~
Concentration Unite: pg/daca
AHALYTB
PCB-77
PCB-123
PCB-118
PCB-114
PCB-105 1
PCB-126 i
PCB-167 -
PCB-156
PCB-157
PCB-169
PCB-180
PCB-170
PCB-189
Lab Sample IO: 48190-11-07 FR-FB1-PCB
Sample Ht/Vol: 3.1280 g or ml>: M3
Initial Calibration Date: 08-22-99
Instrument IDs AutoSpec
GC Column ID: 30m SPB
Sample Data Filename: 4B07889A
Blank Data Filename: 4B07889A *1
Cal. Ver. Data Filename: 4807889 13
Concentration Onita (pg)
CONG.
FOUND
10.84
5.36
232.78
9. BO
104.72
0.72
6.01
8.01
8.01
*
26.02
10.74
*
DETECTION
LIMIT
0.00
0.57
• 0.41
0.71
0.73
0.35
0.65
0.55
0.55
0.34
0.68
0.31
0.55
ION
RATIO
0.74
1.55
1.53
1.65
1.52
1.50
1.18
1.23
1.23
*
1.02
1.03
*
LABELED COMPOUNDS
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-1S6
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
SPIK8
CONG.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
COMC.
FOUND
1289
961
1029
1134
961
973
973
1032
1104
1013
965
3
R(%) 1
64 <
48
51
57
48
49
49
52
55 J
51 :
24*^ 1
EON
ULTIO
).75
.57
.SB
.58
.25
.25
.25
.25
L.03
L.04
L.20
CLEANUP STANDARD
13C-PCB-81
13C-PCB-111
1000
5000
C84
2940
68
59
-------
Method 1668 PCB Data Sheet
Lab Name: BATTELLE Lab Sample ID: 48190-1 1-07 FH-FB1-PCB
Matrix: Air Sample Wt/Vol: 1.00
Sample Receipt Date: 07-21 39 Initial Caiabralion Date: 08-22-99
Ext. Date: 08-01-98 Instrument ID: AutoSpec
Analysis Date: 21 -AUG-99 T tie: 01 :30:34 GC Col' imn ID: 30m SPB
Extract Volume o
37 .'iO
50. 1
50. i1
•
162.V8
87/i
*
Detection Limit
0.00
3.57
2.56
4.-14
4.57
2.19
4.07
3.44
3.44
2.13
4.25
1.94
3.44
Ion Ratio
0.74
1.55
1.53
1.65
1.52
1.50
1.18
1.23
1.23
*
1.02
1.03
* .
Concentration units (pg)
Labeled Compounds
13c-PCB-77
13c-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13c-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
Cleanup Stds
13C-PCB-81
13C-PCB-111
Spike Cone.
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
8000
2000
10000
Cone. Found
2578
1922
2058
2268
1922
1946
1946
2064
2208
2026
1930
1368
5880
R(%)
64
48
51
57
48
49
4!)
52
55
51
24
68
59
Ion Ratio
0.75
1.57
1.58
1.58
1.25
1.25
.25
.25
.03
.04
.20
-------
OPOSquan 2 -AUC-1999
Page 2
Page 2 of 18
Matbod 1668 PCB Data 8ha*t
Lob MaMei BATTBIiE
Matrix: ft It
Sample Receipt Date: 07-21-99
Bxt. Datei 08-01-99
Analy«i« Date: 24-ADO-99 Tijoe: 22:14:46
Extract Volume (uL) : 20
Injection Volume (uL)i 1
Dilution Pactori MOKH
Concentration Cnit«i pg/d*e*
Lab S«impl« ID: 48190-11-01 FH-FB1-PCB
8«mpl« Wt/Vol: 3.1260 g or mL: M3
Initial Calibration Data: 08-24-99
Inatrumant ID: AutoSfwc
GC Column ID: 30n DB1
saapl* Data ril«naiH! 4807692
Blank Data Filananm: 4807892 #7
Cal. V«r. Data Fil«naiw>: 4807192 f4
Concentration Onit* (pg)
AHALYTH
PCB- 77
PCB- 123
PCB-118
PCB-114
PCB- 105 i
FCB-126 i
PCB-lfi7
PCB-156
PCB-157
PCB- 16 9
PCB-180
PCB-170
PCB- IS 9
CONC. DKTBCTIOW ION
VtXmD LIMIT RATIO
*
*
*
*
*
• *
6.09 3.29 1.16
13.70 3.64 1.17
2.84 0.00 1.20
* 1.63 *
* * *
* « *
* * *
LABELED COMPOUNDS
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-12S
13C-PCB-167
13C-?CB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
CLEANUP STANDARD
13C-PCB-81
13C-PCB-111
ffPIKS
COHC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
1000
5000
COHC,
FOUKD
*
*
*
*
1371
1429
1346
1730
*
*
*
*
*
R(t|
*
*
*
*
69
71
«7
87
*
*
*
*
*
ION
RATIO
*
*
*
*
1.25
1.25
1.24
1.25
*
*-
*
-------
n
r»
o
Lab Name: BATTELLE
Matrix: Air
Sample Receipt Dsie: 07-21 99
Ext. Data: 08-01 -PS
Analysis Data: 24-AUG-99 1 ime: 22
Extract Volume (uL): 20
Injection Volume (uL): 1
Dilution Factor None
Concentration Units: pg/sample
Analyte Cone. Found
PCB-77
PCB-123
PCB-118
PCB-114
PCB-105
PCB-126
PCB-167 ;»8.10
PCB-156 8571
PCB-157 ' 17.77
PCB-169 "
PCB-180 *
PCB-170
PCB-189 *
Method 1668 PCB Data Sheet
Lab Sample ID: 48190-11-07 FH-FB1-PCB
Sample VWVol: 1.00
Initial Calabration Data; 08-24-99
Instrument ID: AutoSpec
14:48 GC Column ID: 30m DB 1
Sample Data Filename: 4807892
Blank Data Filename: 4807892 #7
Cat. Ver. Data Filename: 4807892 M
Concentration units (pg)
Detection Limit Ion Ratio Labeled Compounds
130-PCB-77
13C-PCB-118
13c-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
20.58 1.16 13C-PCB-157
22.77 1.17 13C-PCB-169
10.20 1.20 13C-PCB-180
* * 13C-PCB-189
13C-PCB-209
» *
* 4
Cleanup Stds
13C-PCB-81
13c-PCB-111
Spike Cone. Cone. Found R(%)
4000 * «
4000
4000
4000
4000 2742 69
4000 2858 71
4000 2692 67
4000 3500 87
4000 * *
4000
8000 *
2000
10000 * *
Ion Ratio
*
*
*
*
1.25
1.25
1.24
1.25
*
*
*
-------
OPUEquan 28 -ADa-1999
P«g« 3
tmgm 3 of 9
Method 1669 PCB Dlta Sbnt
l/at> tmoa: JAITBLUB
Matrixj All
Sample Rflolpt Date: 07-21-99
Ext. Date: 08-01-99
Analyala Data: 21-AW3-99 Tim: 02:31:25
Extract Volume (uL) : 20
Injection Volume (vl>) t 1
Dilution Factor.! MORB "
Concentration Cnita: pg/dac
FCB-77
PCB-123
PCB-118
PCB-114
PCB-105
PCB-126
PCB-167
J-CB-156
BCB-157
PCB-K9
PCB-180
PCB-170
PCB-189
CONC.
FOOHD
12.40
4.86
210.11
8.56
94.16
0.99
6.54
7.J4
7.84
*
29.78
11.63
0.7»
DKTBCTIOW
LIMIT
0.00
O.S7
•0.49
0.83
0.85
0.40
0.74
0.61
0.61
0.37
0.75
0.34
O.S7
Lab S»mpl« ID; 48190-11-05 FH-PB1-PCB
s»mpl« Ift/vol: 3,1280 g or mL: M3
Initial Callbcation Data: 08-22-99
Instrument ID: AutoSpec
GC Column ID: 30m SPB
Sample Data Filename! 4807889*
Blank Data Filanajna: 4807889k II
Cal. Ver. Data Filename: 4807889 »3
IOK
RATIO
0.68
1.44
1.S3
1.S7
1.58
1.62
1.18
1.2*
1.28
*
1.02
0.97
1.09
Concentration nnita (pg)
LABBLKD COMPODNDS
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-KSB-126
13C-FCB-167
13C-PCB-15«
13C-SCB-157
13C-BCB-169
liC-KCB-180
13C-FCB-189
13C-PCB-209
SfOSX
COMC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
efjxa
COMC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
COHC.
room
1222
841
912
1027
847
885
885
965
984
963
1466
R<*»
61
42
46
SI
42
44
44
48
49
48
37
IOH
RATIO
0.77
1.58
1.59
1.54
1.25
1.24
1.24
1.25
1.03
1.03
1.19
CLRAKUP STANDARD
13C-fCB-81
13C-PGB-111
1000
5000
621
2581
62
-52
-------
Method 1668 PCB Data Sheet
f Jib Name: BATTELLE Lab Sample ID: 48190-1 1-05 FH-PB1-PCB
Matrix: Air Sample Wt/Vol: 1.00
Sample Receipt Date: 07-2' -98 Initial Calabration Date: 08-22-99
Ext. Date: 08-01 -99 Instrument ID: AutoSpcc
Analysis Date: 21 -AUG-99 rime: 02:34:25 GC Column tD: 30m SPB
Extract Volume (uL): 20 Sample Data Filename: 4807B89A
Injection Volume (uL): 1 Blank Data Filename: 4807889A #1
Dilution Factor: Nona Cat. Ver. Data Filename: 4807889 #3
Concentration Units: pg/sample
Anatyfe
PCB-77
PC8-123
PCi-118
PCB-114
PCB-105
PCB-128
PCB-167
PCB-158
PCB-157
PCB-168
PCB-180
PCB-170
PCB-189
Cone. Found
77.57
30,40
1,314.45
53.55
589.06
6.19
40.91
49.05
49.05
*
186.30
72.76
4.88
Detection Limit
0.00
4,19
3.07
5.19
5.32
2.50
4.63
3.82
3.32
2.31
4.69
2.13
3.57
Ion Ratio
0.68
1.44
1.53
1.57
1,58
1.62
1.18
1.28
1.28
*
1.02
0.97
. 1.09
Concentration units (pg)
Labeled Compounds
13c-PCB-77
13c-PCB-118
13c-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13oPCB-189
13C-PCB-209
Cleanup Stds
13c-PCB-81
13c-PCB-111
Spike Cone.
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
8000
2000
10000
Cone. Found
2444
1682
1824
2054
1694
1770
1770
1930
1968
1926
2932
1242
5162
R(%)
61
42
48
51
42
44
44
48
49
48
37
62
52
Ion Ratio
0,77
1.58
.59
.54
.25
.24
.24
.25
.03
.03
.19
-------
WOPqu»n
"9-JWO-1999
Pag* 3
Method 1668 PCB D»t» 6b**t
Lab Wane BMTBLUB
Watrlxt OR
Sampl* Rie«ipt Dat«: 07-21-99
Ext. Datai 08-01-99
Analyaia Dat*i 24-ADO-99 Tin*; 23l01>09
Kxtract TolOMB (uL)i 20
Injection Volua» (uL)t 1
Dilution tactori MOHB '
Concentration Dnitat pg/dac*
Lab 3ampl« ID; 48190-11-05 FH-PB1-PCB
Sample Wt/Vol: 3.1280 g or aiL: M3
Initial Calibration Bate: 08-24-99
In«tniH>»nt ID: AutoSpec
GC Column ID: 30» DB1
Sample Data Fil*nam«; 4807892
Blank Data Filename: 4807892 17
Cal. V»r. Data Fil«nam*i 4807892 M
Concentration Dnita (pg)
C1KJUJOP 8TAHDARD
13C-PCB-81
13C-fCS-lll
1000
5000
rag* 3 at 18
m
O)
o>
iKALTTB
PCB-77
PCB-123
PCB-118
PCB-114
PCB-10S t
PCB-126 1
PCB-167
PCB-156
»C»-157
PCB-169
PCB-180
PCB-170
PCB-189
CORC . DKTKCTIOM IOH
FOOMD LIMIT RAIIO LABELED COMPOUHD8
13C-PCB-77
13C-PCB-118
13C-f CB-105
13C-PCTI-126
13C-PCB-167
13C-PCB-1S6
5.92 3.55 1.27 13C-PCB-157
13.68 3.79 1.40 13C-ECB-169
2.80 0.00 1.17 13G-PCB-180
* l.SO * 13C-PCS-189
« * * 13C-SCB-209
* * *
* . * *
StXKB
CQHC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
COHC.
jfOIMD
*
*
*
*
1244
1321
1288
1713
*
*
*
»(%)
*
*
*
*
62
. 66
64
86
*
*
*
IOK
RATIO
*
*
*
*
1.27
1.23
1.23
1.26
*
*
• • *
-------
m
O)
•sj
Lab Name; BATTELLE
Matrix: Air
Sample Receipt D Me- 07-2 -99
Ext. Date: 08-01-99
Analysis Date: 24-AUG 99 " ime: 23:01
Extract Volume (uL): 20
Injection Volume (uL): 1
Dilution Factor None
Concentration Units: pg/sample
Anaryte Cone. Found
PCB-7?
PCB-123
PCB-118
PCi-114
PC8-105
PCB-126
PCB-167 37 04
PCB-156 85 58
PCB-157 . 17 52
PCB-169
PCB-180
PCB-170 *
PCB-189
Method 1668 PCB Data Sheet
Lab Sample ID: 48190-1 1-05 FH-PB1-PCB
Sample VWVol: 1.00
Initial Catabration Date: 08-24-99
Instrument ID: AutoSpec
09 GC Column ID: 30m DB1
Sample Data Filename: 4807892
Blank Data Filename: 48078i2 #7
Cal. Ver. Data Filename: 4807892 #4
Concentration units (pg)
Detection Limit Ion Ratio Labeled Compounds
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
22.21 1.27 13c-PCB-157
23.71 1.40 13C-PCB-169
10.01 1.17 13C-PCB-180
13C-PCB-189
13C-PCB-209
• *
* *
Cleanup Stds
13c-PCB-81
13&-PCB-111
Spike Cone. Cone, Found R{%)
4000 * *
4000
4000 * *
4000
4000 2488 62
4000 2642 66
4000 257B 64
4000 3426 86
4000 *
4000 *
8000 * *
2000
10000
Ion Ratio
*
*
*
»
1.27
1.23
1.23
1.26
*
4
*
-------
OPUStf-l&n 28- MK3-1999
Pag* 4 of 9
Method 1668 PCB Data Sheet
Lab NaiM: 1 .
Matrix: AH
Sample Receipt Date: 07-21-99
Ext. Date: 08-01-99
Analysis Data; 21-AUQ-99 Time: 03:38:10
Extract Volume (uL): 20
Injection Volume (uL): 1
Dilation Factors NORB f1
Concentration Onit»; pg/daaa
ANALYTE
PCB-77
PCB-123
FCB-118
PCB-114
PCB-105
PCB-126
PCB-167
PCB-156
PCB-157
PCB-169
PCB-180
PCB-170
PCD-189
Lab Sample ID: 48190-11-06 FH-PB2-PCB
Sanpl» Kt/Vol: 3,1280 g or ml,: M3
Initial Calibcation Data: 08-22-99
Instrument ID: AntoSpac
QC Column ID: 30m SPB
Sample Data Filename: 4807889A
Blank Data Filename: 48078B9A fl
Cal. Vnr. Data Filename: 4807889 |3
Concentration t)nlt« (pg)
CONC.
POUND
29.75
32.86
870.98
51.37
420.87
2.09
33.30
41.06
41.06
2.12
88.79
32.57
2.92
DETECTION
LIMIT
0.00
1.36
•0.98
1.69
1.71
0.66
1.39
1.14
1.14
0.59
1.27
0.57
0.91
ION
RATIO
0.80
1.52
1.52
1.50
1.54
1.41
1.09
1.25
1.2S
1.32
1.02
0.95
1.11
UIBEUKD COMPOUNDS
13C-PCB-77
13C-PCB-118
13C-PCB-105
13G-PCB-126
13C-PCB-167
13C-PCB-156
13G-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
BPIKK
CONG.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
CONC.
POUND
912
546
590
784
372
590
590
764
756
764
1008
R<%)
46
27'"*''
29»<*
39
29*"/"'
30
30
38
38
38
25 -"
ION
RATIO
0.77
1.58
1.5?
1.55
1.23
1.25
1.25
1.26
1.03
1.03
1.20
CLEAHOT STANDARD
130-ECB-81
13C-PCB-111
1000
5000
465
1735
46
35
-------
m
6>
(O
Method
Lab Name: BATTELLE
Matrix: Air
Sample Receipt D?ie: 07-21 99
Ext. Data: 08-21-S&
1668 PCB Data Sheet
Lab Sample ID: 48190-1 1-06 FH-PB2-PCB
Sample VWVol: 1.00
Initial Calabration Date: 08-22-99
Instrument ID: AutoSpec
Analysis Dale: 21-AUG-99 T ms: 03:38:10
Extract Volume (uL):
20
GC Column ID: 30m
SPB
Sample Data Filename: 4807889A
Injection Volume (uL): 1
Dilution Factor: None
Concentration Units:
Analyte
PCB-77
PCB-123
PCB-118
PCB-114
PCB-105
PCB-128
PCB-167
PCB-156
PCB-157
PCB-169
PCB-180
PCB-170
PCB-189
Blank Data Filename
: 4807B89A #1
Cal. Ver. Data Filename: 4807889 #3
pg/sample
Cone. Found
186.12
205.57
5,448.85
321.37
2,632.96
13.08
208.32
^56.37
256.87
13.28
555.47
203.76
18.27
Detection Limit
0.00
8.51
6.13
10.57
10.70
4.13
8.70
7.13
7.13
3.69
7.95
3.57
5.69
Ion Ratio
0.80
1.52
1.52
1.50
1.54
1.41
1.09
1.25
1.25
1.32
1.02
0.95
1.11
Concentration units (pg)
Labeled Compounds
13c-PCB-77
13C-PCB-118
13C-PCB-105
13e-PCi-126
13C-PCB-167
13C-PCB-158
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-2Q9
Cleanup Stds
13C-PCB-81
13e-PCB-111
Spike Cone.
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
8000
2000
10000
Cone. Found
1824
1092
1180
1568
1144
1180
1180
1528
1512
1528
2016
930
3470
R(%)
46
27
29
39
29
30
30
38
38
38
25
46
35
Ion Ratio
0.77
1.58
1.57
1.55
1.23
1.25
1.25
1.26
1.03
1.03
1.20
-------
OPOSquau 29-AU3-1999
Page 4
Page 4 of IS
Method 1668 PCB Data Sheet
Lab Name: BATTELLE
Matrix: AIR
Bangle Receipt Data: 07-21-99
Ext, Data: 08-01-99
An»ly»i* Data: 24-JWM-99 Tina! 23:47:26
Extract Volume (uL)t 20
Injection Volume (uL): 1
Dilution Factor: NONE ''
concentration Dnit»i pg/decm
Lab Sample ID: 48190-11-06 FH-PB2-PCB
Sampl* Wt/Volt 3.1280 g or mL: M3
Initial Calibration Date: 08-24-99
Instrument ID t AutoSpec
GG Column ID: 30m DBl
Sample Data Filename: 4807892
Blank Data Filename: 4807892 f?
Cal. Vac. Data Filename: 4807892 M
Concentration Dnit»
ANALTTE
tCB-77
PCB-123
PCB-118
PCB-114
PCB-105 *
PCB- 12 6 I
PCB-167
PCB-156
PCB-157
PCB-1BO
PCB-170
KB-189
CONG , DETECTION ION
FOtTHD LIMIT RATIO LABELED COMPOUNDS
* * 13C-PCB-77
* 13C-ECB-118
* 13C-PCB-105
« 13C-fCB-126
* 13C-PCB-1S7
* 13C-PCB-156
34.49 4.34 1.24 13C-PCB-157
62.88 4.01 1.34 13C-PCB-169
24.62 0.00 1.29 13C-PCB-180
* 1.55 * 13C-PCB-189
* * * 13C-PCB-209
* * *
* * *
tXEAHUP STAHDARD
13C-PCB-81
13C-PCB-111
SPZKB
COMC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
1000
5000
CONG.
FOUND R(%)
* «
* *
» *
* *
848 42
1025 51
915 46
1443 72
* *
* *
* *
* *
* *
ION
RATIO
*
*
*
*
1.25
1.27
1.25
1.26
*
*
*
-------
Method
Lab Name: BATTELLE
Matrix: Air
Sample Receipt Date; 07-21-99
Ext. Date: 08-01-99
Analysis Date: 24-AUG-99 Time: 23:47:26
Extract Volume (uL): 20
injection Volume (uL): 1
Dilution Factor: None
Concentration Units: pg/sample
Analyte Cone. Found Detection Limit
PCB-77
PCB-123 ' *
PCB-118 * «
PCB-1 14
PCB-105
PCB-1 26
PCB-167 215.77 27.15
PCB-1 56 - 393.38 25.09
PCB-157 154.02 9.70
PCB-1 69
PCB-1 80
PCB-1 70
PCB-189 * *
1 668 PCB Data Sheet
Lab Sample ID: 48190-11-06 FH-PB2-PCB
Sample WtA/ol: 1.00
Initial Calabration Date; 08-24-99
Instrument ID: AutoSpec
GC Column ID: 30m DB1
Sample Data Filename; 4807892
Blank Data Filename: 4807892 #7
Cal. Ver. Data Filename: 4807892 #4
Concentration units (pg)
Ion Ratio Labeled Compounds
13c-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
* 13C-PCB-156
1.24 13C-PCB-157
1.34 13C-PCB-169
1.29 13C-PCB-180
13C-PCB-189
13C-PCB-209
*
*
Cleanup Stds
13c-PCB-81
13C-PCB-111
Spike Cone. ' Cone. Found R(%)
4000
4000 •
4000
4000
4000 . 1696 42
4000 2050 51
4000 1830 46
4000 2886 72
4000 - * .. *
4000
8000
2000 * *
10000
Ion Ratio
*
A
*
*
1.25
1.27
1.25
1.26
*
*
*
-------
OPUSquan 28-AOG-1999
Page 1
Pago 1 of 9
Method 1668 PCS Data Sheet
Lab Name: BA.TTELLE
Matrix: AIR
Sample Receipt Date: 08-01-99
Ext. Date: 08-01-99
Analy«l« Date: 21-A0S-99 Time: 00:26:44
Extract Volume (uL): 20
Injection Volume (uL) : 1
Dilation Factor: HOME p
Concentration Unite: pg/docra
WHALYTB
tCB-77
PCS-123
PCB-118
PCB-114
fCB-105 J
PCB-126 5
SCB-167
PCB-156
PCB-157
PCB-1S9
PCB-180
FCB-170
PCB-189
L«b Sample ID: 48190-11-10 PH-tB-PCB
Sample Wt/Vol: 3.1280 g or mL: M3
Initial Calibration Date: 08-22-99
Instrument ID: AutoSpec
SC Column ID: 30m SPB
Sample Data Filename: 4807889A
Blank Data Filename: 48078B9A fl
Cal. Ver. Data Filauaroa: 4807889 13
Concentration Onlta (pg)
COHC.
FOOUD
11. 45
91,18
321.27
122.59
224.40
' 5.11
74.48
76.57
76.57
5.89
59.58
19.56
8.49
DEHCtlOM
LIMIT
0.00
4.27
3.11
5.03
5.11
1.17
3.22
2.47
2.47
0.80
1.83
0.82
1.63
ION
RATIO
0.66
1.S4
1.50
1.66
1.49
1.59
1.21
1.24
1.24
1.21
1.00
1.02
1.21
LABELED COMPOUNDS
13C-PCB-77
13C-PCB-118
13C-ECB-105.
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
CLEANUP SXAHDARD
13C-PCB-B1
13C-PCB-111
SPIKE.
COHC .
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
COHC.
FOUND
582
176
199
455
218
245
2*5
SOS
469
371
849
R<*>
29-""
9-^
10*-"~
23-'
II1-"
12 «--'
12 -^
25 1-^"
23-^
19^"
21'^'
IOM
RATIO
0.78
1,61
1.60
1.55
1.26
1.24
1.24
1.23
1.04
1.03
1.19
1000
5000
286
797
-------
rn
NJ
CO
Lab Name: BATTELLE
Matrix: Air
Sample Receipt Date: 08-01-99
Ext, Date: 08-01-99
Analysis Date: 21-AUG-99 Time: 00:26:44
Extract Volume (uL): 20
Injection Volume (uL): 1
Dilution Factor: None
Concentration Units: pg/sample
Analyte Cone. Found
PCB-77 71.63
PCB-123 570.42
PCB-118 2,009.87
PCB-114 766.92
PCB-105 1,403.85
PCB-126 -.. 31.97
PCB-167 465.95
PCB-156 479.02
PCB-157 479.02
PCB-169 36.85
PCB-180 372.73
PCB-170 122.37
PCB-189 53.11
-
Method
1668 PCS Data Sheet
Lab Sample ID: 48190-11-10 FH-LB-PCB
Sample WtA/oI: 1.00
Initial Calabration Date: 08-22-99
Instrument ID: AutoSpec
GC Column ID: 30m
SPB
Sample Data Filename: 4807889A
Blank Data Filename
: 4807889A #1
Cal. Ver. Data Filename: 4807889 #3
Detection Limit
0.00
26.71
19,46
31.47
31.97
7.32
20.14
15.45
15.45
5.00
11.45
5.13
10.20
Ion Ratio
0.66 ,
1.54
1.50
1.66
1.49
1.59
1.21
1.24
1.24
1.21
. 1.00
1.02
1.21
Concentration units (pg)
Labeled Compounds
13c-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
Cleanup Stds
13C-PCB-81
13C-PCB-111
Spike Cone.
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
8000
2000
10000
Cone. Found
1164
352
398
910
436
490
490
1012
938
742
1698
572
1594
R(%) Ion Ratio
29 0.78
9 1.61
10 1.60
23 1.55
11 1.26
12 1.24
12 1.24
25 1.23
23 1.04
19 1.03
21 1.19
29
16
-------
OPBSquan 29-&03-1999
f
Lab Kama: BATTELLB
Matrix: AIR
Sample Eacaipt Data: 08-01-99
Ext. Data: 08-01-99
Analysis Data: 24-MKJ-99 Time
Extract Volume (uL) : 20
Injection Volume (uL) : 1
Dilution Factor: HONK '
Concantrmtion Onita: pg/d»cm
COHC .
ANALYTE FOUND
PCB-77 *
PCB-123 *
PCB-118 *
PCB-114 *
PCB-1QS | *
PCB-126 3 *
PCB-167 * 77.32
PCB-156 94.74
PCB-157 78.18
ECB-169 6.86
BCB-1BO *
PCB-170 *
ECB-1B9 *
Page 1
Method 1668 PCB Data Sheet
Lab Sample ID: 48190-11-10 FH-LB-PCB
Sample Wt/Vol: 3.1260 g or ml.: H3
Initial Calibration Datai 08-24-99
Instrument ID : AotoSpec
: 21:28:26 GC Column ID: 30m DEI
Sample Data Filename: 4807892
Blank Data Filename: 4807892 tl
Cal. Var. Data Filename: 4807892 14
Concentration Onita (pg>
DETECTION ION
LIMIT RATIO LABELED COMPOUNDS
* 13C-PCB-77
* 13C-PCB-118
* 13C-PCB-105
* 13C-PCB-12S
* 13C-PCB-167
* 13C-PCB-1S6
13.25 1.29 13C-PCB-157
14.16 1.31 13C-ECB-169
11.39 1.22 13C-PCB-180
0.00 1.30 13C-ECB-189
« * 13C-PCB-209
* *
* *
CLEANUP STANDARD
13C-PCB-81
13C-PCB-111
SPIKE
COHC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
1000
5000
Page 1 of 18
COHC . ION
FOOND R(%) RATIO
* * *
* * *
* * ift
* * *
316 16 1.28
338 17"C i-28
341 17 "^ 1.25
733 37 1.26
« * *
* * *
* * *
* *
* *
*V
-------
Method
Lab Name: BATTELLE
Matrix: Air
Sample Receipt Date: 08-01-99
Ext. Data: 08-01-99
Analysis Date: 24-AUG-99 Time: 21:28:99
Extract Volume (uL): 20
Injection Volume (uL): 1
Dilution Factor: None
Concentration Units: pg/sample
Analyte Cone. Found Detection Limit
PCB-77
PCB-123 ' *
PCB-118
PCB-114
PCB-105
PCi-126
PCB-!6T 483.71 82.89
PCB-156 • 592.69 88.58
PCB-157 489.09 71.26
PCB-169 42.92 0.00
PCB-180
PCB-170
PCB-189
1 668 PCB Data Sheet
Lab Sample ID: 48190-11-10 FH-LB-PCB
Sample Wt/Vol: 1.00
Initial Calabrafion Date: 08-24-99
Instrument ID: AutoSpec
GC Column ID: 30m DB1
Sample Data Filename: 4807892
Blank Data Filename: 4807892 #7
Cal. Ver. Data Filename: 4807892 #4
Concentration units (pg)
Ion Ratio Labeled Compounds
13C-PCB-77
* 13C-PCB-118
13C-PCB-105
* 13C-PCB-126
13C-PCB-167
13C-PCB-156
1.29 13C-PCB-157
1.31 13C-PCB-169
1.22 13c-PCB-180
1.3 13C-PCB-189
13C-PCB-209
*
*
Cleanup Stds
13C-PCB-81
13C-PCB-111
Spike Cone. Cone. Found R(%)
4000 * *
4000 -
4000
4000
4000 .632 16
4000 676 17
4000 682 17
4000 1466 37
4000 • ' . *
4000
8000
2000
10000 * *
Ion Ratio
*
«
*
- *
1.28
1.28
1.25
1.26
*
*
*
-------
OPUSquan 28-AUG-1999
Page 5
Method 1668 PCB Data Shaet
Lab Name : BATTELLE
Matrix: AIR
Sample Receipt Date: 08-01-99
Ext. Date: 08-01-99
Analysis Date: 21-AUC-99 Time: 04:42:00
Extract Volume (uL) : 20
Injection Volume (uL): 1
Dilution Factor: HONE '"
Concentration Units: pg/dscm
ANALYTE
PCB-77
PCB-123
PCB-118
PCB-114
PCB-105
PCB-126
PCB-167
PCB-156
PCB-157
PCB-169
PCB-180
PCB-170
PCB-189
Lab Sample ID: 48190-11-08 FH-LCS-PCB
Sample Ht/Vol: 3.1280 g or mL: M3
Initial Calibration Date: 08-22-99
Instrument ID: AutoSpec
GC Column ID: 30m SPB
Sample Data Filename: 4807889A
Blank Data Filename: 4807889A *1
cal. Ver. Data Filename: 4807889 43
Concentration Units (pg)
COHC.
FOUND
171.83
7261.84
5616.17
9451.86
7385.38
752.14
7309.17
7452.76
7452.76
1277.04
7262.23
1598.52
1378.66
DETECTION
LIMIT
0.00
1.17
0.85
1.45
1.48
0.63
1.19
0.99
0.99
0.53
1.16
0.52
0.75
ION
RATIO
0.76
1.52
1.51
1.51
1.51
1.54
1.24
1.23
1.23
1.23
0.99
1.00
1.01
LABELED COMPOUNDS
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-12S
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-1«9
13C-PCB-180
13C-PCB-189
13C-PCB-209
CLEANUP STANDARD
13C-PCB-81
13C-PCB-111
1000
5000
629
2078
63
42
Page 5 of 9
SPIKE
CONC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
COHC.
FOUND
1180
654
711
869
670
702
702
853
844
926
1434
R(%)
59
33
36
43
33
35
35
43
42
46
36
ION
RATIO
0.74
1.60
1.56
1.57
1.25
1.23
1.23
1.25
1.02
1.04
1.19
-------
m
4j
-d
Method
Lab Name: BATTELLE
Matrix: Air
Sample Receipt Date:
Ext. Date: 08-01-99
08-01-99
1 668 PCB Data Sheet
Lab Sample ID:
Sample VWVol:
48190-11-08 FH-LCS-PCB
1.00
Initial Calabratton Date: 08-22-99
Instrument ID: AutoSpec
Analysis Date: 2 1 -AUG-99 Time: 04:42:00
Extract Volume (uL): 20
Injection Volume (uL):
Dilution Factor: None
Concentration Units:
1
GC Column ID:
30m SPB
Sample Data Filename: 4B07889A
Blank Data Filename: 4807889A #1
Cal. Ver. Data Filename: 4807889 #3
pg/sampte
Analyte Cone. Found
PCB-77
PCB-123
PCB-118
PCB-114
PCB-105
PCB-126
PCB-167
PCB-158
PCB-157
PCB-169
PCB-180
PCB-170
PCB-189
-
1,074.97
45,430.07
35,134,76
59,130.84
46,202,94
4,705,39
45,726.17
46,624.47
46,624.47
7,989.16
45,432.51
10,000.34
8,624,90
Detection Limit
0.00
7.32
5.32
9.07
9.26
3.94
7.44
6.19
6.19
3.32
7.26
3.25
4.69
Ion Ratio
0.76
1.52
1.51
1.51
1.51
1.54
1.24
1,23
1,23
1.23
1.99
1.00
1.01
Concentration units (pg)
Labeled Compounds
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PC8-180
13C-PCB-189
13C-PCB-209
Cleanup Stds
13C-PCB-81
13C-PC8-111
Spike Cone,
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
8000
2000
10000
Cone. Found
2360
1308
1422
1738
1340
1404
1404
1706
1688
1852
2868
1258
4156
R(%)
59
33
36
43
33
35
35
43
42
46
36
63
42
-------
OPOSquan 29-AW3-1999
!
Lab Mama: BATTELLE
Matrix: MR
Sanf>la Receipt Date: 08-01-99
Kxt. Data: 08-01-99
Xnalyai* Data: 25-AO3-99 Time
Extract: Voluma (uL) t 20
Injection Voluo* (til.) : 1
Dilution {-actor: NONE
Concentration Onita; pg/d»cm
CCWC.
, JUMLXTS . IOTHD
KS-77
FCB-123
FCB-118
BCB-114
Pd-105 ,
PCB-12C 2
BCB-161 * 7629.33
PCB-156 8134.13
SCB-157 7840.98
PCB-169 1368.82
PCB-1BO *
PCB-170 *
PCB-189 *
Pag« 5
. Hsthod 1668 FCB Data Shset
Lab Sampl« 10; 48190-11-08 FH-LCS-PCB
Satnpl* Ht/Vol: 3.1280 9 or mL: M3
Initial Calibration Date: 08-24-99
Xnatrumsnt ID : Autospec
00:33:43 3C Column ID: 30m DB1
Saropla Data Filenaaa : 4807892
Blank Data Filename: 4807892 «7
Cal. Ver. Data Filename: 4807892 |4
Concentration Dnlta (pg)
DETECTION ION
LIMIT RATIO LAB1EED COHPODHDS
* * 13C-1CB-77
« * 13C-SCB-118
* * 13C-FCB-10S
* * 13C-5CB-126
* * 13C-BCB-1S7
« » 13C-fCB-15«
• 3.11 1.24 13C-PCB-157
3.36 1.26 13C-PCB-169
2.97 1.24 13C-PCB-180
0.00 1.25 13C-PCB-189
* * 13C-PCB-209
* *
* *
CLEANUP STANDARD
13C-PC8-81
13C-PCB-111
8PIKS COHC.
COHC. FOOND R(%J
2000 " * « .
2000 * *
2000 * *
2000 * *
2000 1004 30
2000 1061 " 53
2000 999 50
2000 1355 68
2000 * *
2000 * *
4000 * *'
1000 * *
5000 * *
Page S of 18
ION
RATIO
*
*
*
*
1.27
1.27
1.28
1.27
*
*
*
-------
m
•si
29.09
PCB-156 51,199.92
PCB-1 57 49,053.17
PCB-1 69 8,563.34
PCB-180
PCB-170
PCB-189 *
Method 1668 PCB Data Sheet
Lab Sample ID: 48190-11-08 FH-LCS-PCB
Sample VWVol: 1.00
Initial Calabration Date: 08-24-99
Instrument ID: AutoSpec
GC Column ID: 30m DB1
Sample Data Filename: 4807892
Blank Data Filename: 4807892 #7
Cal. Ver. Data Filename: 4807892 #4
Concentration units (pg)
Detection Limit Ion Ratio Labeled Compounds
13C-PCB-77
* * 13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
19,46 1.24 13C-PCB-157
21.02 1.26 13C-PCB-169
18.58 1.24 13C-PCB-180
0.00 1.25 13C-PCB-189
13C-PCB-209
* *
* *
Cleanup Sfds
13C-PCB-81
13C-PCB-111
Spike Cone.
4000
4000 •
4000
4000
4000
4000
4000
4000
4000
4000
8000
2000
10000
Cone. Found R(%)
* #
* *
* *
* *
2008 50
2122 53
1998 50
2710 68
* *
* *
* *
* *
* *
-------
OPDSquan 28-100-1999
Page G
Method 1668 PCS Data Sheet
tab Name: BATTELLE
Matrix: AIR
Sample Receipt Data: 08-01-99
Ext, Data: 08-01-99
Analysis Date: 21-A0G-99 Time: 05:45:46
Extract Volume (uL); 20
Injection Volume (uL): 1
Dilution Factor: NONE '"
Concentration Unit*: pg/d»cm
AMALTTB
tCB-77
PCB-123
PCB-118
PCB-114
PCB-105
PCB-126
PCB-1K7
PCB-156
FCB-157
PCB-169
PCB-1BO
FCB-170
PCB-189
Lab Sample ID: 48190-11-09 FH-LCSDOF-PCB
Sample Wt/Vol: 3.1280 g or mL: M3
Initial Calibration Data: 08-22-99
Instrument ID: AutoSpac
GC Column ID: 30m SFB
Sample Data Filename : 4807889A
Blank Data Filename: 4807889A 11
Cal. Ver. Data Filename: 4807889 13
Concentration Unit a (pg)
COHC.
FOOND
165.73
7191.69
SS49.73
9439.68
7300.30
733.39
7298.48
7329.92
7329.92
1272.48
7169.97
1501.77
1385.25
DE1ECIIOH
LIMIT
0.00
1.10
• 0.80
1.41
1.43
0.57
1.10
0,87
0.87
0.51
l.OS
0.48
0.73
ION
Rano
0.75
1.50
1.51
1.51
1.S1
1.52
1.24
1.24
1.24
1.2S
1.01
1.01
1.01
IABEUED COMPOUNDS
13C-PCB-77
13C-PCB-11B
13C-FCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-1B9
13C-PCB-209
CLEANUP STANDARD
13C-PCB-81
13C-PCB-111
1000
5000
611
2230
61
45
Page 6 of 9
SPiRJJ
CONG.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
COHC.
FOTOD
1105
668
704
915
732
780
780
883
912
958
1526
IOM
R(%) BA5IO
55
33
35
46
37
39
39
44
46
. 48
38'
0
1
1
1
1
1
1
1
1
1
1
.76
.57
,61
.54
.25
.24
.24
.25
.03
,03
.19
-------
rn
00
-1
Method
Lab Name: BATTELLE
Matrix: Air
Sample Receipt Date
Ext. Date: 08-01 -99
: 08-01-99
1668 PCB Data Sheet
Lab Sample ID: 48190-11-09 FH-LCSDUP-PCB
Sample Wt/Vol: 1.00
Initial Calabration Date: 08-22-99
instrument ID: AutoSpec
Analysis Date: 21-AUG-99 Time: 05:45:46
Extract Volume (uL): 20
Injection Volume (uL]
Dilution Factor: None
Concentration Units:
Analyte
PCB-77
PCB-123
PCB-118
PCB-114
PCB-105
PCB-126
PCB-167
PCB-156
PCB-157
PCB-169
PCB-180
PCB-170
PCB-189
: 1
GC Column ID: 30m
SPB
Sample Data Filename: 4807889A
Blank Data Filename
: 4807889A #1
Cai. Ver. Data Filename: 4807889 m
pg/sample
Cone. Found
1,036.81
44.991.21
35,344.71
59,054.64
45,670.68
4,588.09
45,659.29
45,855.98
45,855.98
7,960.63
44,855.33
9,395.08
8,666.12
-
Detection Limit
0.00
6.88
5.00
8.82
8.95
3.57
6.88
5.44
5.44
3.19
6.63
3.00
4.57
Ion Ratio
0.75
1.50
1.51
1.51
1.51
' ' 1.52
1.24
1.24
1,24
1.25
1.01
1.01
1.01
Concentration units (pg)
Labeled Compounds
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167 .
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
Cleanup Stds
13c-PCB-81
13C-PCB-111
Spike Cone.
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
8000
2000
10000
Cone. Found
2210
1336
1408
1830
1464
1560
1560
1766
1824
1916
3052
1222
4460
R(%)-
55
33
35
46
37
39
39
44
46
48
38
61
45
-------
OPOTquan 29-JWS-1999
Pag* €
m
CO
ro
Page 6 of 18
Method 1668 PCB Data Sheet
Lab Mama: BATTELUB
Matrix: AIR
Sample Receipt Data: 03-01-99
Ext. Oat*: 08-01-99
Analysis Data: 25-AOG-99 Time: 01:20:00
Extract Volume (uL) > 20
Injection Volume (uL): 1
Dilution factor: HONE
Concentration Unit*: pg/dson
Lab Sample IDi 48190-11-09 FH-LCSDBP-PCB
Sample Ht/Vol: 3.1280 g or mLi K3
Initial Calibration Date: 08-24-99
Instrument ID: AutoSpec
GC Column ID: 3On DB1
Sample Data Filename: 4807892
Blank Data Filename: 4807892 f7
Cal. Ver. D«t« Filename; 4807892 H
Concentration Uniti (pg)
junurnr
fCB-77
PCS- 123
PCS- 11 8
PCS- 11 4
PCB-105 i
PCB-126 |
PCB-1«7
1CB-1SS
ECB-157
BCB-169
SCB-liO
FCB-170
PCB-189
COHC. DETECT IOH IOH
vovm LHHI RATIO
* *
*
*
*
*
*
7734. B7 3.29 1.24
8204.13 3.31 1.24
7847.80 2.83 1.24
1341.57 0.00 1.25
* * *
* * *
* * *
1ABELED COMPOUNDS
13C-PCB-77
13C-1CB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-1CB-156
13C-PCB-1S7
13C-BCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
CLEANUP STANDARD
13C-PCB-81
13C-1CB-111
SPD08
COMC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
1000
SOOO
COMC.
fOTOB
*
*
*
*
1093
1242
1192
1664
*
*
*
*
*
m<%)
*
*
*
*
55
£2
GO
83
*
_*
*
*
*
ION
RATIO
*
*
*
*
1.28
l,2fi
1.28
1.27
*
A
A
-------
m
CO
u
Method 1 668 PCB Data Sheet
Lab Name: iATTELLE
Matrix: Air
Sample Receipt Date: 08-01-99
Ext. Date: 08-01-99
Analysis Date: 25-AUG-99 Time: 01:20:00
Extract Volume (uL): 20
Injection Volume (uL): 1
Dilution Factor: None
Concentration Units: pg/sample
Analyte Cone, Found
PCB-77
PCB-123
PC8-11B *
PCB-114
PCB-105
PCB- 126
PCB-167 48,389.35
PCB-156 51,325.04
PCB-157 49,095.84
PCB-169 8,392.86
PCB-180
PCB- 170
PCB- 189
Lab Sample ID: 48190-11-09 FH-LCSDUP-PCB
Sample Wt/Vol: 1.00
Initial Calabration Date: 08-24-99
Instrument ID:
GC Column ID
AutoSpec
. 30m DB1
Sample Data Filename: 4807892
Blank Data Filename: 4807892 #7
Cat. Ver. Data
Detection Limit Ion Ratio
* *
* *
* *
* *
* *
* *
20,58 1,24
20.71 1,24
17.70 ' 1,24
0.00 1.25
* *
* *
* *
Filename: 4807892 #4
Concentration units (pg)
Labeled Compounds
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13G-PCB-180
13C-PCB-189
13c-PCB-209
Cleanup Sids
13C-PCB-81
13C-PCB-111
Spike Cone,
4000
4000'
4000
4000
4000
4000
4000
4000
4000
4000
8000
2000
10000
Cone. Found R(%)
it *
* *
* *
* *
2186 55
2484 62
2384 60
3328 S3
* *
It *
* *
* *
* ' *
-------
opoa
-------
m
O3
01
Method
Lab Name: BATTELLE
Matrix: Air
Sample Receipt Date:
Ext. Date: 07-28-99
07-21-99
1 868 PCB Data Sheet
Lab Sample ID:
Sample Wt/Vol:
48190-09-07 BH-FB1-PCB
1.00
Initial Calabration Date: 08-22-99
Instrument ID: AutoSpec
Analysis Date: 23-AUG-99 Time: 14:51:23
Extract Volume (uL): 20
Injection Volume (uL):
Dilution Factor: None
Concentration Units:
1
GC Column ID:
30m SPB
Sample Data Filename: 4807891
Blank Data Filename: 4807891 f3
Cal. Ver. Data Filename: 4807891 #2
pg/sample
Analyte Cone. Found
PCB-77
PCB-123
PCB-118
PCB-114
PCB-105
PCB-126
PCB-167
PCB-156
PCB-157
PCS- 169
PCS- 180
PCB-170
PCB-189
177.98
72.01
1,779.77
129.69
872.71
. 16.20
92.71
109.17
109.17
7.51
284.96
116.30
10.13
-
Detection Limit
0.00
7.44
5.38
12.95
6.13
2.94
2.69
5.07
5.07
1.69
5.51
3.50
3.07
Ion Ratio
0.78 .
1.55
.57
.74
.58
.42
.19
.26
.26
.12
. 1.04
1.07
1.07
Concentration units (pg)
Labeled Compounds
13c-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
.13c-PCB-189
13c-PCB-209
Pro-Sampling Surrogate Stds
13c-PCB-81
13C-PCB-111
Spike Cone.
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
8000
2000
10000
Cone. Found
3144
1982
2120
2366
2284
2414
2414
2508
2200
2254
5168
1438
4918
R(%)
79
50
53
59
57
60
60
63
55
56
65
72
49
Ion Ratio
0.77
1.52
1.57
1.56
1.27
1.26
1.26
1.26
1.02
1.00
1.20
-------
00
O)
OEDSquan 29-AUQ-1999
1
Lab Kane: BATTELLK
Matrix: AIR
Sample Receipt Date: 07-21-99
Bxt. Data: 07-28-99
Analyai* Dat*i 25-ADG-99 Time
Extract Volume (ul.) i 20
Injection Volume (uL) : 1
Dilution Factori NONB •'
Concentration Onitt: pg/dacm
COHC.
ANALYTB FOOND
PC8-77 *
PCB-123 *
PGB-118 *
PGB-114 *
PCB-126 I *
PCB-167 14.80
PCB-156 24.73
PCB-157 9.84
PCS-169 *
PCB-180 *
PCB-170 *
PCB-189 *
Page 11
Method 1668 PCB Data Sheet
Lab Sample ID: 48190-09-07 BH-FB1-PCB
Sample Ht/Vol: 3.1280 q or mL: M3
Initial Calibration Date: 08-24-99
Instrument ID: AutoSpec
: 06:44:08 DC Column ID; 30m DB1
Sample Data Filename: 4807892
Blank Data Filename: 4807892 »7
Cal. Ver. Data FilenaniB: 4807892 #4
Concentration Dtilt* (pg)
DKTKCTIOH ION
LIMIT RATIO LABELED COMPOOHDS
13C-PCB-77
13C-PCB-118'
13C-PCB-105
130-PCB-126
13C-PCB-167
13C-PCB-156
3.46 1.19 13C-PCB-157
3.89 1.2S 13C-PCB-169
0.00 1.22 13C-PCB-180
1.72 * 13C-PCB-189
* * 13C-PCB-209
* *
* *
CLEANUP STANDARD
13C-PCB-81
13C-PCB-111
Page 11 of 18
rona COHC. ION
COWC. FODKD R(%) RATIO
2000 * * *
2000 * * *
2000 * * *
2000 * * *
2000 1383 $9 1.26
2000 1451 73 1.26
2000 1409 70 1.24
2000 1777 89 1.2S
2000 * * *
2000 * ,* *
4000 * * *
1000 * *
5000 * *
-------
Lab Name: BATTELLE
Matrix: Air
Sample Receipt Date: 07-21-99
Ext. Date: 07-28-99
Analysis Date: 25-AUG-99 Time: 06:44:08
Extract Volume (uL): 20
Injection Volume (uL): 1
Dilution Factor: None
Concentration Units: pg/sample
Analyte Cone. Found
PCB-77
PCB-123
PCB-118 *
PCB-114
PCB-105
PCB-126
PCB-167 - 92.59
PCB-156 • 154.71
PCB-157 61.56
PCB-169
PCB-180
PCB-170
PCB-189
Method 1668 PCB Data Sheet
Lab Sample ID: 481 90-09-07 BH-FB1-PCB
Sample WtA/ol: 1.00
Initial Galabratlon Date: 08-24-99
Instrument ID: AutoSpec
GC Column ID: 30m DB1
Sample Data Filename: 4807892
Blank Data Filename: 4807892 #1
Cat. Ver. Data Filename: 4807892 #4
Concentration units (pg)
Detection Limit Ion Ratio Labeled Compounds
13c-PCB-77
13C-PCB-118
13C-PCB-105
* 13C-PCB-126
13C-PCB-167
* 13C-PCB-156
21.65 1.19 13C-PCB-157
24.34 1.26 13C-PCB-169
10.76 1.22 13c-PCB-180
13C-PCB-189
13c-PCB-209
* ' *
* *
Pre-Sampling Surrogate Stds
13c-PCB-81
13C-PCB-111
Spike Cone. Cone. Found R(%)
4000
4000 •
4000
4000
4000 2766 69
4000 2902 73
4000 2818 70
4000 3554 89
4000 * *
4000
8000
2000 * * •
10000
Ion Ratio
*
*
*
*
1.26
1.26
1.24
1.25
*
*
*
-------
OPDSquan 28-AOS-1999
Page 3
Pago 3 of 9
Mathod 1668 PCB Data Sheet
Lab Kama: BATTELIJS
Matrix: AIR
Biaaplm Receipt Data: 07-21-99
Ract. Data: 07-28-99
JLnalysii Date: 23-AW3-99 Time: 15:55:17
Extract Volume (uL)s 20
Injection Volisaa (uL) t 1
Dilution Factor: NONE "
Concentration Onita: pg/d»cm
ANAI.TTB
PCB-77
PCB-123
TCB-118
PCB-114
tCB-105 i
PCB-126 j
PCB-167 •
PCB-1S6 "• '
PCB-157
FCB-169
PCB-180
PCB-170
PCB-IB9
Lab Sample ID: 48190-09-05 BH-FB1-PCB
Sarapla Wt/Vol: 3.1280 g or ml,: M3
Initial Calibration Data: 08-22-99
Instrument ID: AutoSpoc
GC coltmrn IB: 30ra 3PB
Sample Data Filename: 4807891
Blank Data rilaname: 4807891 f3
Cal. Vac, Data Filanama; 4807891 $2
Concentration Dnita (pg)
COHC.
FOTOD
29.08
5.13
278.45
12.35
133.46
1.90
8.86
12.02
12.02
O\Vt> *•
41.30
19.32
1,11
DETECTION
LIMIT
0.00
0.93
0.67
1.67
0.79
0.34
0.32
0.60
0.60
mft o.is
0.64
0.40
0.33
IOH
RATIO
0.75
1.48
1.56
1.67
1.56
1.73
1.29
1.23
1.23
* \.1t\
1.03
1.02
0.93
LABELED COMPOUNDS
13C-PCB-77
13C-PCB-11B
13C-5CB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
SPIKE
COHC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
COHC.
FOUND
1368
932
971
1217
1030
1082
1002
1250
1011
1102
2394
R(%J
£8
47
49
61
52
54
54
62
51
55
60
IOH
RATIO
0.78
1.54
1,50
1.54
1.24
1.26
1.26
1.2S
1.03
1.02
1.19
-euuoiw.
13C-FCB-81
13C-PCB-111
1000
5000
6S3
2306
65
46
-------
m
CO
CD
Method
Lab Name: BATTELLE
Matrix: Air
Sample Receipt Date: 07-21-99
Ext. Date; 07-28-99
1668 PCB Data Sheet
Lab Sample ID
Sample Wt/Vol
48190-09-05 BH-PB1-PCB
1.00
Initial Calabration Date: 08-22-99
Instrument ID: AutoSpec
Analysis Date: 23-AUG-99 Time: 15:55:17
Extract Volume (uL):
20
GC Column ID:
30m SPB
Sample Data Filename: 448047891
Injection Volume (uL): 1
Dilution Factor: None
Concentration Units:
Analyte
PCB-77
PCB-123
PCB-118
PCB-114
PCB-105
PCB-126
PCB-167
PCB-156
PCB-157
PCB-169
PCB-180
PCB-170
PCB-189
Blank Data Filename: 4807891 #3
Cal. Ver. Data Filename: 4807891 #2
pg/sample
Cone. Found
181.92
32.09
1,741.98
77.26
834.93
11.89
55.43
75.20
75.20
1.44 EMPC
258.37
120.87
6.94
-
Detection Limit
0.00
5.82
4.19
10.45
4.94
2,13
2.00
3.7.5
3.75
1.13
4.00
2.50
2.06
Ion Ratio
0.75 .
1.48
1.56
1.67
1.56
1.73
1.29
1.23
1.23
1.24
1.03
1.02
0.93
Concentration units (pg)
Labeled Compounds
13c-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
13c-PCB-157
13C-PCB-169
13C-PCB-180
. 13C-PCB-189
13c-PCB-209
Pre-Samp!ing Surrogate Stds
13C-PCB-81
13c-PCB-111
Spike Cone.
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
8000
2000
10000
Cone. Found R(%)
2736 68
1864 47
1942 49
2434 61
2060 52
2164 54
2164 54
2500 62
2022 51
2204 55
4788 60
1306 65
4612 46
Ion Ratio
0.78
1.54
1.50
1.54
1.24
1.26
1.26
1.25
1.03
1.02
1.19
-------
OPUSqu«n 29-AUCJ-1999
Pag* 12
Method 1668 PCB Data Sheet
Lab Kama: B&TTELLB
Matrix: AIR
B«mp:« R«c«lpt Dat«: 07-21-99
Bxt. Dat.01 07-28-99
An»ly»i» Data: 25-AOQ-99 Time: 07:30:26
Extract Voluma (uL): 20
Injection Volume (ul) i 1
Dilution Factors HOHK
coneantratlon Unita: pg/dacm
Lab Sample ID: 48190-09-05 BH-PB1-PCB
Sample Wt/Vol: 3.1280 g or ml,: H3
Initial Calibration Dat«: 08-24-99
Instrtunent ID: AutoSpac
GC Column ID: 30m DBl
Sample Data Filename: 4807892
Black Data Filen«me: 4807892 §7
Cal. Ver. Data Filename: 4807892 f4
Concentration Unit* (pg)
CLEANUP STANDARD
13C-PCB-111
1000
5000
Page 12 of 18
m
CO
o
, AHALTTK
SCB-7?
PCB-123
PCB-118
PCB-114
ECB-105 t
PCB-126 I
PCB-167
PCB-156
ECB-157
PCB-169
FCB-180
PCB-170
PCB-189
COHC.
FOUND
8.53
19.70
4.59
*
*
*
*
DETECTION
LIMIT
*
*
*
*
*
*
2.28
0.00
2.07
1.02
*
*
*
ion
RATIO
*
*
*
*
*
*
1,20
1.29
1.36
*
*
*
*
LABELED COMPOUNDS
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-1BO
13C-PCB-189
13C-PCB-209
SPIKE
CONC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
COHC.
FOUND
*
*
*
*
1274
1382
1363
1870
*
*
*
R(%)
*
*
*
*
64
69
68
93
*
*
*
IOH
RATIO
*
*
*
*
1.25
1.25
1.28
1.2C
*
*
*
-------
Method
Lab Name: BATTELLE
Matrix: Air
Sample Receipt Date: 07-21-99
Ext. Date: 07-28-99
Analysis Date: 25-AUG-99 Time: 07:30:26
Extract Volume (uL): 20
Injection Volume
-------
OPUSquan 28-AOQ-1999
P»ga 4
Method 1669 PCS Data Sheet
Lab Name: BA1TELLE
Matrix: AIR
Sample Receipt Date: 07-21-99
Ext. Data: 07-28-99
An*lyni» Date: 23-JKJS-99 lima: 16:59:11
Extract Volume (uLJ : 20
Injection Volume (uL) : 1
Dilution Factors HONK ?
Concentration nnlta
MUUiXXE
PCB-77
PCB-123
fCB-118
PCB-114
PCB-105
PCB-126
PCB-167
PCB-156
PCB-157
PCB-169
PCB-180
PCB-170
PCB-189
pg/dacm
COMC.
FOOTD
73.94
26,71
1281.02
51,76
539.15
1.99
21.56
28.84
28.84
0.49
85.68
31.91
0.98
DETECTION
LXHIT
0.00
1,19
0.86
2.05
0.97
0.44
0.41
0.74
0.74
0.23
0.74
0.47
0.37
ION
RR3IO
0.7S
1.56
1.54
1.45
1.55
1.69
1.20
1.31
1.31
1.24
1.02
1.06
1.19
Lab Sample ID: 48190-09-06 BH-PB2-PCB
Sample Wt/Vol: 3,1280 g or mLt M3
Initial Calibration Date: 08-22-99
Xnfttrtiment XD: AutoSpec
GC Column ID: 30a SPB
Sauple Data Filenames 4B07891
Blank Data Filename : 4807891 13
Cal. Ver. Data Filename: 4807891 |2
Concentration Units (pg)
UffiELED COMPOUNDS
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
'•GHMSBP. STANDARD
13C-PCB-B1
13C-PCB-111
1000
5000
482
2093
48
42
Page 4 of 9
BtTKS
COMC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
COMC.
FOUND
1073
887
979
1154
951
1049
1049
1148
1045
1194
2473
R<%)
54
44
49
58
48
52
52
57
52
•60
62
IOH
RATIO
0.76
1.62
1,57
1.55
1.25
1.27
1.27
1.23
1.02
1.02
1.19
-------
m
i
co
OJ
Method
Lab Name: BATTELLE
Matrix: Air
1 668 PCB Data Sheet
Lab Sample ID: 48190-09-06 BH-PB2-PCB
Sample VWVoI: 1.00
Sample Receipt Date: 07-21-99
Ext. Date: 07-28-99
Analysis Date: 23-AUG-99 Time: 16:59:1 1
Extract Volume (uL):
20
Initial Galabration Date: 08-22-99
Instrument ID:
GC Column ID
AutoSpec
• 30m SPB
Sample Data Filename: 4807891
Injection Volume (uL): 1
Dilution Factor None
Concentration Units:
Analyte
PCB-77
PCB-123
PC8-118
PCB-114
PCB-105
PCB-126
PCB-167
PCB-158
PCB-157
PCB-169
PCS- 180
PCB-170
PCB-189
pg/sample
Cone. Found
462.57
167.10
8,014.08
323,81
3,372.92
12.45
134.88
180.42
180.42
3.07
536.01
199.63
6.13
-
Detection Limit
0.00
7.44
5,38
12.82
6.07
2.75
2.56
4.63
4.63
1,44
4.63
2.94
2.31
Blank Data Filename: 4807891 #3
Cal. Ver. Data
Ion Ratio
0.76 .
1.58
1.54
1.45
1.55
1.69
1.20
1.31
1.31
1.24
1.02
1.06
1.19
Filename: 4807891 #2
Concentration units (pg)
Labeled Compounds
13c-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13c-PCB-167
13C-PCB-156
13C-PCB-157
130-PCB-169
13C-PCB-180
,13c-PCB-189
13C-PCB-209
Pre-Sampllng Surrogate Stds
13c-PCB-81
13c-PCB-111
Spike Cone.
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
8000
2000
10000
Cone. Found R(%)
2146 54
1774 44
1958 49
2308 58
1902 48
2098 52
2098 52
2296 57
2090 52
2388 60
4946 62
954 48
4186 42
Ion Ratio
0.76
1.62
1.57
1.55
1.25
1.27
1.27
1.23
1.02
1.02
1.19
-------
OPDSquan 29-AOG-1999
Pag« 13
Pag« 13 of 18
Method 1668 PCB Data Sheet
Lab Ham*: BATTBLLE
Matrlzi AIR
Sampl* Receipt Dat*: 07-21-99
Ext. Dat»! 07-28-99
Analyiln Data: 25-A0Q-99 Tina: 08:16:44
Extract Voluro* (uL): 20
Injactlon Volume (nL) : 1
Dilution Factors HONB ''
Concentration Unit*: pg/decm
ANALTTE
PCB-77
PCB-123
fCB-118
PCB-114
PCB-105
PCB-126
PCB-167
PCB-156
PCB-157
PCB-169
PCB-180
PGB-170
PCB-189
Lab Sample ID: 48190-09-06 BH-PB2-PCB
Sample Wt/Vol: 3.1280 g or mL: M3
Initial Calibration Data: 06-24-99
GC Column ID: 30m DD1
SaB3>l« Data Filensma: 4807892
Blank Data Fil*nanm: 4807892 f7
Cal. Ver. Data Fil»nam«: 4807892 #4
Concentration Dnite (pg)
CONC
,
FOOND
20
SO
9
*
*
*
*
*
*
.65
.48
.50
*
*
*
*
DETECTION TOM
LIMIT RATIO LABELED COMPOUNDS
13C-PCB-77
13C-PCB-118
13C-PCB-1QS
13C-PCB-126
13C-PCB-167
* 13C-FCB-156
• 3.24 1.22 13C-PCB-157
0.00 1.23 13G-POB-169
2. S3 1.20 13C-PCB-180
1.35 « 13C-PCB-189
* « 13C-PCB-209
* *
* *
CLEANUP STANDARD
13C-PCB-81
13C-PCB-111
SPIKK
CONC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
CONC.
FOtnro
*
*
*
*
1211
1368
1405
1837
*
* *
*
R<*>
*
*
*
*
61
68
70
92
*
*
*'
ION
RATIO
*
*
*
*
1.26
1.24
1.25
1.26
*
*
*
1000
5000
-------
m
to
en
Method
Lab Name: BATTELLE
Matrix: Air
Sample Receipt Date: 07-21-99
Ext. Data: 07-28-99
Analysis Date: 25-AUG-99 Time: 08:16:44
Extract Volume (uL): 20
Injection Volume (uL): 1
Dilution Factor: None
Concentration Units: pg/sample
Analyte Cone. Found Detection Limit
PCB-77 ' *
PCB-123
PCB-118
PCB-114
PCB-105
PCS-126
PCB-167 129.19 20.27
PCB-156 315.80 16.77
PCB-157 59.43 8.45
PCB-169
PCB-180
PCB-170 * '
PCB-189
1 668 PCB Data Sheet
Lab Sample ID: 48190-09-06 BH-PB2-PCB
Sample Wt/Vol; 1.00
Initial Calabration Date: 08-24-99
Instrument ID: AutoSpec
GC Column ID: 30m DB1
Sample Data Filename: 4807892
Blank Data Filename: 4807892 #7
Cal. Ver. Data Filename: 4807892 #4
Concentration units (pg)
Ion Ratio Labeled Compounds
13c-PCB-77
* 13C-PCB-118
* 13C-PCB-105
13C-PCB-126
13C-PCB-167
13c-PCB-156
1.22 13C-PCB-157
1.23 13C-PCB-169
1 1.20 13C-PCB-180
13C-PCB-189
13C-PCB-209
*
*
Pre-Sampling Surrogate Stds
13C-PCB-81
13C-PCB-111
Spike Cone. Cone. Found R(%)
4000
4000 •
4000 * *
4000
4000 2422 61
4000 2736 68
4000 2810 70
4000 3674 92
4000 • * *
4000
8000 ' *
2000
10000
Ion Ratio
*
*
*
*
1.26
1.24
1.25
1.26
*
*
*
-------
OPUSquan 28-AO8-1999
Page 1
Method 1668 fCB Data Sheet
Lab Name: BAT-TELLS
Matrix: AIR
Sample Receipt Data: 07-28-99
Ext. Data: 07-28-99
Analyain Dat«: 23-AOS-99 Tlmt 13:47:33
Extract Volume (uL): 20
Injection Volume (ul): 1
Dilution Factor: NODE •'
Lab Sampl* ID: 48190-09-11 BH-1B-PCB
Sample Wt/Vol: 3.1280 g or mt,: M3
Initial Calibration Date: 08-22-99
Instrument ID: AutoSpec
SC Colmm IDs 30m SPB
Sample Data Filename: 4807891
Blank Data Filansma: 4807891 13
Cal. Vac. Data Filename: 4807891 *2
Page 1 of 9
Concentration Onit«: pg/daem
Concentration Dnitn (pg)
SCB-77
PC8-123
»OB-118
PCS-114
POB-105
PCB-126
PCS-167
PCB-156
PCB-157
PCB-169
PCB-180
PCB-170
tOB-189
CONG.
POUND
8.00
6.44
197.27
13.06
91.52
0.68
8.05
11.13
11.13
0.72
28.93
U,¥2> -*"'
0.96
DETECTION
LIMIT
0,00
1,52
•1.10
2.66
1.26
0.62
0.56
1.08
1.08
0.37
1.13
© 0.72
0.65
IOH
RATIO
0.70
1.40
1.52
1.76
1.62
1.32
1.38
1.22
1.22
1.19
1.01
*
1.08
LABELED COMPOOTTDS
13C-PCB-77
13C-PCB-118
13C-FCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
SPIKE
CQMC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
CONG.
FOUND
1153
736
788
861
841
867
S67
842
782
783
1959
R(%]
58
37
39
43
42
43
43
42
39
39.
49
ION
RATIO
0.77
1.60
1.55
1.58
1.26
1.25
1.25
1.25
1.04
1.03
1.19
13C-PCB-81
13C-PCB-111
1000
5000
*o
-------
m
-------
OPCSquin 29-AWQ-1999
f
tab HUM; BATTELLH
Matrix! AIR
6ampl« Receipt Date: 07-28-99
Ext. Dates 07-28-99
Analyaia Datei 25-AUQ-99 Time
Extract Volume (uL) : 20
Injection Volume (uL) : 1
Dilation Factors HONK '"
Concentration Dnita: pg/d»cm
OOHC.
• ANALYTH FOUND
PCB-77 *
PCB-123 *
PCB-118 *
PCB-114 *
PCS- 105 i *
PCS- 12 6 1 *
PCB-W7 6.92
rcB-156 15,28
PCB-1S7 5 . IS
PCB-169 *
PCB-180 *
PCB-170 *
SCB-189 *
Pag« 10
Method 1669 PCS Data Shnet
Lab SanplB ID: 48190-09-11 BH-IB-PCB
Sampl« Ht/Vol: 3,1280 g or ml,: M3
initial Calibration Data: 08-24-99
Instrument ID: AutoSpac
: 05:57:50 GC Column ID: 30m DB1
Samplo Data Filename: 4807892
Blank Data Filanama: 4807892 «7
Cal. Ver. Data Filename: 4807892 |4
Concentration Onita (pg)
DBTBCTIOH ZOM
LIMIT RATIO LABELED COMPOUNDS
* * 13C-PCB-77
* * 13C-PCB-118
* * 13C-PCB-105
* * 13C-PCB-126
* * 13C-PCB-167
* * 13C-PCB-156
5.68 1.12 13C-PCB-157
6.23 1.2S 13C-PCB-169
0.00 1.32 13C-PCB-180
2,89 * 13C-PCB-189
* * 13C-PCB-209 .
* *
* *
CTLEAHtn? STMTOARJO
13C-PCB-81
13C-PCB-111
Page 10 of IB
SPIES CONC. ION
COHC. FOOKD R(%) RATIO
2000 * * *
2000 * * *
2000 * * *
2000 * * *
2000 1040 52 1.25
2000 1109 55 1.25
2000 1078 54 1.25
2000 1252 €3 1.25
2000 * * *
2000 * * • *
4000 * *' *
1000 * *
5000 * * ,
-------
Method
Lab Name: BATTELLE
Matrix: Air
Sample Receipt Date: 07-28-99
Ext. Date: 07-28-99
Analysis Date: 25-AUG-99 Time: 05:57:50
Extract Volume (uL): 20
Injection Volume (uL): 1
Dilution Factor: None
Concentration UnWs: pg/sample
Analyte Cone. Found Detection Limit
PCB-77
PCB-123
PCB-118
PCB-114 *
PCB-105
PCB-126.
PCB-167 43.29 35.53
PCB-156 95.59 38.97
PCB-157 32.28 18.08
PCB-169 * *
PCB-180 *
PCB-170 * *
PCB-189
1668 PCB Data Sheet
Lab Sample ID: 48190-09-11 BH-LB-PCB
Sample Wt/Vol: 1.00
Initial Calabration Date: 08-24-99
Instrument ID: AutoSpec
GC Column ID: 30m DB1
Sample Data Filename: 4807892
Blank Data Filename: 4807892 #7
Cal. Ver. Data Filename: 4807892 #4
Concentration units (pg)
Ion Ratio Labeled Compounds
13C-PCB-77
13c-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
1.12 13C-PCB-157
. 1.26 13C-PCB-169
1.32 13C-PCB-180
13C-PCB-189
13C-PCB-209
*
*
Pre-Sampling Surrogate Stds
13c-PCB-81
13C-PCB-111
Spike Cone. Cone. Found R(%)
4000
4000 *
4000 * *
4000 *
4000 2080 52
4000 2218 55
4000 2156 54
4000 2504 63
4000
. 4000
8000
2000
10000
Ion Ratio
*
•
*
*
1.25
1.25
1.25
1.25
*•
*
*
-------
OPUSquan 28-AUG-1999
Page 5
Page 5 of 9
Method 1668 PCB Data Sheet
Lab Name: BATTELLB
Matrix: AIR
Sample Receipt Date: 07-28-99
Ext. Data: 07-28-99
Analysis Dato: 23-ABG-99 Time: 18:03:05
Extract Volume (uL): 20
Injection Volume (uL): 1
Dilution Factor: NONE r
Concentration Units: pg/dacm
ANALTTE
PCB-77
PCB-123
PCB-118
PCB-114
PCB-105
PCB-126
PCB-167
PCB-156
PCB-157
PCB-169
PCB-180
PCB-170
PCB-189
Lab Sample ID: 48190-09-09 BH-LCS-PCB
Sample Wt/Vol: 3.1280 g or rnL-i M3
Initial Calibration Dato : 08-22-99
Instrument ID: AutoSpec
GC Column ID: 30m SPB
Sample Data Filename: 4807891
Blank Data Filename: 4807891 13
Cal. Ver. Data Filename: 4807891 #2
Concentration Units (pg)
CONC . DETECTION
FOUND
170.32
7192. ISV'
5669.69
9877. 87*^
7537 . 10 I/
748.67
7179.14
7326.28
7326.28
1257.97
7037.52
1540.53
1336.36
LIMIT
0.00
1.35
0.98
2.28
1.08
0.52
0.50
0.90
0.90
0.30
1.05
0.67
0.54
ION
RATIO
0.76
1.S3
1.55
1.55
1.54
1.56
1.24
1.24
1.24
1.25
1.02
1.02
1.02
LABELED COMPOUNDS
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
SPIKE
CONG.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
CONG.
FOUND
800
682
762
832
821
880
880
915
758
830
1731
R{%)
40
34
38
42
41
44
44
46
38
41.
43
ION
RATIO
0.77
1.55
1.56
1.56
1.26
1.25
1.25
1.24
1.01
1.02
1.19
-CUUUtOT STANDARD
13C-PCB-81
13C-PCB-111
1000
5000
fftUA-
-------
m
o
Lab Name: BATTELLE
Matrix: Air
Sample Receipt Date: 07-28-99
Ext. Date: 07-28-99
Analysis Data: 23-AUG-89 Time:
Extract Volume (uL): 20
injection Volume (uL): 1
Dilution Factor None
Concentration Units: pg/sample
Analyte Cone. Found
PCB-77 1,065.52
PCB-123 44,994.09
PCB-118 35,469.58
PCB-114 61,795.95
PCB-105 47,152.10
PCB-126 - 4,683.68
PCB-167 44,912.70
PCB-156 45,833.21
PCB-157 45,833.21
PCB-16i 7,869.86
PCB-180 44,026.73
PCB-170 9,637.56
PCB-189 8,360.27
-
Method
1668 PCB Data Sheet
Lab Sample ID: 48190-09-09 BH-LCS-PCB
Sample VWVol: 1.00
Initial Calabration Date; 08-22-99
Instrument ID: AutoSpec
GC Column ID: 30m
SPB
Sample Data Filename: 4807891
Blank Data Filename
: 4807891 #3
Cat. Ver. Data Filename: 4807891 #2
Detection Limit
0.00
8.45
6.13
14.26
6.76
3.25
3.13
5.63
5.83
1.88
6.57
4.19
3.38
t
Ion Ratio
0.76
1.53
1.55 ,
1.55
1.54
1.56
1.24
1.24
1.24
1.25
1.02
1.02
1.02
Concentration units (pg)
Labeled Compounds
13C-PCB-77
13c-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167 .
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
Pre-Sampling Surrogate Stds
13C-PCB-81
13c-PCB-111
Spike Cone.
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
8000
2000
10000
Cone. Found
1600
1364
1524
1664
1642
1760
1760
1830
1516
1660
3462
*
*
R{%)
40
34
38
42
41
44
44
46
38
41
43
*
*
-------
OPUSqu»n 29-AU5-1999
f
Lab Kama: BATTELLE
Matrix: AIR
B«s$>l« Raeaipt D»t«s 07-28-99
Ext. Data: 07-28-99
Analytic Date: 25-JWJS-99 Ttma
Extract Volume (xil.) : 20
Injection Volurae (uL) t 1
Dilution Factor: MODE •
Concentration Onit«: pg/d«aa
CONC .
. JUttLYTB FOUHD
PC8-77
PCB-123
PCB-118
PCB-114
PCS- 105
PCB-126 t
PCB-167 ' 7373. 62
PCB-156 7577.08
PCB-157 7303.61
PCB-169 1259.71
PCS-ISO *
PCB-170 *
PCB-189 *
Pag* 14
Method 1668 FCB Data Ehaat
Lab Sample IDs 48190-09-09 BH-IiCS-PCB
Bangle St/Vols 3.1280 g or aLs M3
Initial Calibration Dates 08-24-99
Inatcument ID: Autonp«c
I 09:03:05 GC Coliamn ID: 30« DB1
Sample Data Filename: 4807892
Blank Data Filename: 4807892 f?
Cal. Ver. Data Filename: 4807892 «4
Concentration Unit* (pg)
DSTECIIOH IC3H
LIMIT RATIO LABELED COMPOUNDS
* * 13C-PCB-77
* * 13C-PCB-118
* * 13C-PCB-105
* * 13C-PCB-12S
* * 13C-PCB-167
* * 13C-PCB-15S
2.83 1.24 13C-PCB-157
2.92 1.25 13C-PCB-169
2.30 1.25 13C-PCB-180
0.00 1.25 13C-PCB-189
* * 13C-PCB-209 .
* *
* *
CLEANUP STANDARD
13C-PCB-81
13C-PCB-111
Page 14 of 18
SPXKK COHC. ION
COHC. FOUND R(%) RATIO
2000 ' * * *
2000 * * *
2000 * * *
2000 * * *
2000 1088 54 1.27
2000 1245 62 1.26
2000 1264 S3 1.27
2000 1682 84 1.24
2000 * * *
2000 * * . *
4000 * * *
1000 * *
5000 * *
\f
-------
m
o
CO
Lab Name: BATTELLE
Matrix: Air
Sample Receipt Date: 07-28-99
Ext, Date: 07-28-99
Analysis Data: 25-AUG-99 Time: 09:03:05
Extract Voluma (uL)r 20
Injection Volume (uL): 1
Dilution Factor. None
Concentration Units: pg/sampie
Analyta Cone. Found
PCB-77
PCB-123
PCB-118
PCB-114
PCB-105
PCB-126
PCB-167 46,129.37
PCB-156 47,402.21
PCB-157 45,691.57
PCB-169 7,880.75
PCB-180 * .
PCB-170
PCB-189
Method 1668 PCB Data Sheet
Lab Sample ID: 48190-09-09 BH-LCS-PCB
Sample Wt/Vol: 1.00
Initial Calabration Date: 08-24-99
Instrument ID: AutoSpec
GC Column ID: 30m DB1
Sample Data Filename: 4807892
Blank Data Filename: 4807892 #7
Cal. Ver. Data Filename: 4807892 #4
Concentration units (pg)
Detection Limit ton Ratio Labeled Compounds
. 13C-PCB-77
13C-PCB-118
* * 13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
17.70 1.24 13C-PCB-157
18.27 1.25 13c-PCB-169
14.39 1.25 13c-PCB-180
0.00 1.25 13C-PCB-189
13C-PCB-209
* *
* *
Pre-Sampling Surrogate Stds
13c-PCB-81
13c-PCB-111
Spike Cone.
4000
4000 '
4000
4000
4000
4000
4000
4000
4000
4000
8000
2000
10000
Cone. Found R(%)
* *
* *
* *
* *
2176 54
2490 62
2528 63
3364 84
* . *
* *
* *
* *
* *
-------
OPU3qu»n 28-AOO-1999
Page 6
rn
—A
o
Page £ of 9
Method 166B PCB Date sheet
Lab Name: BATTEIAE
Matrix: AIR
Sample Receipt Date: 07-28-99
Ext, Date: 07-28-99
Analyai* Data; 23-AOQ-99 Tina: 19:06:49
Extract Volume (uL); 20
Injection Volum« (uL): 1
Dilution Factor: HONK ?
Concentration Unitei pg/d*ca
ANALTTE
PGB-77
PCB-123
PCB-11B
PCB-114
KS-105
PC8-126
PCB-167
PCB-156
PCB-157
PCB-169
PCB-180
?CB-170
PCB-189
Lab Sample ID: 48190-09-10 BH-IXTSDW-PCB
Sample Ht/Vol: 3.1280 g or mL: M3
Initial Calibration Date: 08-22-99
Instrument ID: AutoSpec
GC Column ID: 30m 8PB
S«n:plo Data Filename: 4807891
Blank Data Filename: 4807891 13
Cal. Var. Data Filename: 4807891 12
Concentration Unit* (pg)
CONG,
FOOHO
179. «0
7504. 49/
5843.53
10712.94*'
7713, S9»/
759,16
7587.49
7587.64
7587.64
1293.36
7445.01
1534.49
1386,97
DBIECIJOH
MHIT
1.49
2.05
• 1.49
3,51
1.66
0.80
0.76
1.41
1.41
0.48
1.49
0.94
0.82
ION
RATIO
0.77
1.S5
1.54
1.53
1.54
1.54
1.24
1.24
1.24
1.25
1.02
1.00
1.02
LABELED COMPOUNDS
13C-PCB-77
13C-fCB-118
13C-SCB-105
13C-ECB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-FCB-180
13C-PCB-189
13G-PCB-209
J^
CffiMTOF STANDARD
13C-BCB-81
13C-SCB-111
•PIKE
COMC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
CONG,
FOUND
2276
993
1090
1205
990
1047
1047
1053
936
966
1909
R(%)U.
IOH
RATIO
1000
5000
-------
m
i
o
an
Method
Lab Name: BATTELLE
Matrix; Air
Sample Receipt Date; 07-28-99
Ext. Date: 07-28-99
1668 PCB Data Sheet
Lab Sample ID: 48190-09-10 BH-LCSDUP-PCB
Sample Wt/Vol: 1.00
Initial Calabration Date: 08-22-99
Instrument ID: AutoSpec
Analysis Date: 23-AUG-9.9 Time: 19:06:49
Extract Volume (uL): 20
Injection Volume (ul_]
Dilution Factor: None
Concentration Units:
Analyte
PCB-77
PCB-123
PCB-118
PCB-114
PCB-105
PCB-126
PCB-167
PCB-156
PCB-157
PCB-169
PCB-180
PCB-170
PCB-189
.1
GC Column ID: 30m
SPB
Sample Data Filename: 4807891
Blank Data Filename
: 4807891 #3
Cal, Ver. Data Filename: 4807891 #2
pg/sample
Cone. Found
1123.58
48948.09
36557.12
67020.15
48256.22
4749.30
47457.34
47468.28
47468.28
8091.26
46575.98
9599.77
8676.88
~
Detection Limit
9.32
12.82
9.32
21.96
10.38
5.00
4.75
8.82
8.82
3.00
9.32
5.88
5.13
Ion Ratio
0.77
1.55
1.54
1.53
1.54
1.54
1.24
1.24
1.24
1.25
1.02
1.00
. 1.02
Concentration units (pg)
Labeled Compounds
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13G-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
Pre-Sampling Surrogate Stds
13C-PCB-81
13C-PCB-111
Spike Cone.
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
8000
2000
10000
Cone. Found R(%)
4552 114
1986 50
2180 54
2410 60
1980 50
2094 52
2094 52
2106 53
1872 47
1932 48
3818 43
* *
* *
Ion Ratio
0.74
1.55
1.57
1.53
1.24
1.26
1.26
1.23
1.03
1.03
1.19
-------
o
0>
OPOSquan 29-AOG-1999
f
Lab HUM: BATTSL1B
Matrix; AIR
Sample Receipt Date: 07-28-99
Ext. Bates 07-28-99
Analy»i» Dat*: 25-AOO-99 Tin*:
Extract Volume (uL) : 20
Injection Volumo (uL) : 1
Dilution Faction HONE -
Concentration Unit*: pg/d«cm
COHC.
ANALYTB FOUND
EGB-77 *
SCB-123
PCB-118
PCB-114
PCB-105 ,
PCB-126 I
PCB-167 7472.86
PCB-156 7938.92
PCS-1S7 7S34.87
PCB-169 1287.13
SCB-180 *
PCB-170 *
PGB-189 *
Pag* IS
Method 1668 PCB Data Sheat
Page 15 of 18
Lab Sample ID: 18190-09-10 BH-LCSDUF-EC1
Bangle Wt/Vol: 3.1280 g or mL: H3
Initial Calibration Date: 08-24-99
Instrument ID: AutoSpac
09:49:26 SC Column ID: 30m DB1
Sample Data Filename: 4807892
Blank Data Filename: 4807892 |7
Cal. Ver. Data Filename: 4807892 14
Concentration unit* (pg)
DETECTION ION
LIMIT RATIO IJIBELED COMPOnHDS
* 13C-PCB-77
* 13C-8CB-118
* 13C-PCB-105
* 13C-BCB-126
* . 13C-PCB-167
* 13C-fC»-lS«
3.85 1.24 13C-PCB-157
4. OS 1.24 13C-PCB-169
3.29 1.24 13C-SCB-180
0,00 1.24 13C-PCB-189
* * 13C-PCB-209 •
* *
* *
CLEANUP STANDARD
13C-PCB-81
13O-PCB-111
SPZKB CONC . XOK
CONC. FOOHD R(%) RATIO
2000 * * *
2000 * * • *
2000 * * *
2000 * * *
2000 1337 67 1.25
2000 1438 72 1.25
2000 1435 72 1.24
2000 1701 85 1.25
2000 * * . ' *
2000 * * *
4000 * * *
1000 * * .
5000 * *
Jh
-------
71
«i
o
vl
Lab Name: BATTELLE
Matrix: Air
Sample Receipt Dale: 07-28-99
Ext, Date: 07-28-99
Analysis Date: 25-AUG-99 Time: 09:49:26
Extract Volume (uL): 20 '
Injection Volume (uL): 1
Dilution Factor: None
Concentration Units: pg/sample
Analyte Cone. Found
PCB-77
PCB-123
PCB-118
PCB-114
PCB-105
PCB-126
PCB-167 46750.21
PCB-156 49665.88
PCB-157 47138.15
PCB-169 • 8054,16
PCB-180
PCB-170
PCB-189
Method 1668 PCB Data Sheet
Lab Sample ID: 48190-09-10 BH-LCSDUP-PCB
Sample Wt/Vol: 1.00
Initial Calabratfan Date: 08-24-99
Instrument ID: AutoSpec
GC Column ID: 30m DB1
Sample Data Filename: 4807892
Blank Data Filename: 4807892 #7
Cal. Ver. Data Filename: 4807892 #4
Concentration units (pg)
Detection Limit Ion Ratio Labeled Compounds
13c-PCB-77
13c-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13c-PCB-15S
24.09 1.24 13C-PCB-157
25.40 1.24 13C-PCB-169
20.58 1.24 13C-PCB-180
0.00 1.24 13c-PCB-189
* ' 13C-PCB-209
* *
* *
Pre-Sampling Surrogate Stds
13C-PCB-81
13c-PCB-111
Spike Cone. Cone. Found R(%)
4000 * *
4000
4000 . *
4000
4000 2674 67
4000 2876 72
4000 2870 72
4000 3402 85
4000
4000
8000
2000
10000
Ion Ratio
«
*
•
*
1.25
1.25
1.24
1.25
*
*
»
-------
OPCSquan H-JUL-1999
tag* 1
Pag« 1 of 1
Method 1668 PCS Data Sb««t
tab Vmamt BX1TELLB
Matrixt SOLVENT .
Sample Receipt Date: 07-10-99
Kit. Dab* t 07-10-99
*n«ly«i« D«t*i H-JTJt-99 XliMi 13:52:03
Extract VolttBM (ul) i 20
Xnjaction Voluro* (uL) : 1
Dilution Fact or i HOBS
.tab Sample IDi 48200-51-03 METHOD BLAHK
8anpl« Wt/Vol« 1.0000 g or M.I ••
Initial Calibration Datei 06-23-99
nutriment XOi AotoSpeo
OC Column XDi 50m ET8
Bmrapl* Data Fil«nam«i 480786fiB
Blank. Data ril*nam*t 48078I6B |2
C«l. V«r. Data Fil«naa«t 490786KB fl
Cooc*ntr*tion Unltai pg/aanpl«
BOT-77
PCB-123
PCB-118
PCB-1H
5CB-105
fCB-126
PCB-156
PCB-1S7
ECB-169
5CB-180
PCB-170
PCB-189
CONG.
FOUHD
4.92
*
134.02
5,09
66.96
*
4.73
11.42
2.86
0.59
21.58
OSZXCXIOH
IOH
RATIO
0.53
16.95
3. 37
4,88
4.03
2.32
2.36
2.13
2.10.
1.28
2.89
11.96
11. S2
0.77
*
1.B1
1.46
1.47
*
1,16
1.33
1.27
1.12
1.00
A
*
Concentration Unit* (pg)
LABELED COMPOUNDS
13C-SCB-77 .
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-BCB-167 ,
13OPCB-1S6
13C-PCT-1S7
13C-BCB-169
13C-PCB-1BO
13C-PCB-189
13C-PCB-209
8S3X*
COIIC.
2000
2000
3000
2000
2000
2000
2000
2000
2000
2000
4000
CONG.
room
3S6S
1777
1603
2214
196S
1720
1619
1717
1292
1385
3614
RW
89
80
111
98
86
81
86
65
90
RATIO
0.78
1.62
1.61
1.57
1.2*
1.2C
1.27
1.25
1.04
1.04
1.20
CLEANUP STANDARD
13C-ICB-81
13C-K3-111
1000
, 5000
-------
m
o
CD
Lab Name: BATTELLE
Matrix: Solvent
Method
1668 PCB Data Sheet
Lab Sample ID: 48200-51-03 METHOD BLANK
Sample Receipt Date: 07-10-99
Ext. Date: 07-10-99
Sample VWVol: 1.00
Initial Calabratlon Date: 06-23-99
Instrument ID: AutoSpec
Analysis Date: 14-JUL-99 Time: 13:52:03
Extract Volume (uL): 20
Injection Volume (uL): 1
Dilution Factor: None
GC Column ID: 50m
HT8
Sample Data Filename: 4807866B
Blank Data Filename
• 4807866B #2
Cai. Ver. Data Filename: 4807866B #1
Concentration Units: pg/sample
Analyte ' Cone, Found
PCB-77
PCB-123
4.92
PCB-118 134.02
PCB-114
PCB-105
PCB-126
PCB-167
PCB-156
PCB-157
PCB-189
PCB-180
PCB-170
PCB-189
5.09
66.96
4.73
11,42
2.86
0.59
21.58
Detection Limit
0.53
16.95
3.57
4.88
4.03
2.32
2.36
2.13
2.10
1.28
2.89
11.96
11.52
Ion Ratio
0.77
*
1.51
1.46
1.47
*
1.16
1.33
1.27
1.12
1.00
*
*
Concentration units (pg)
Labeled Compounds
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
130-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
Cleanup Stds
13C-PCB-81
13C-PCB-111
Spike Cone. Cone, Found R(%)
4000 3565 89.1
4000 1777 44.4
4000 1603 40
4000 2214 55.3
4000 1965 49.1
4000 1720 43
4000 1619 40.5
4000 1717 42.9
4000 1292 32.3
4000 1385 34.6
8000 3614 45.2
2000
10000 * *
Ion Ratio
0.78
1.62
1.61
1.57
1.29
1.26 •
1.27
1.25
1.04
1.04
1.20
-------
OPOSrju»n 14-JUL-1999
Page 1
Fag* 2 of 2
Method 1668 PCS Dab* Sh««t
Lab Name: BATTSLLK
Matrix. ZU>
Sample Receipt Datei 07-10-99
Kit. Date: 07-10-99
Analyaii Date: 14-JUL-99 Time! 14i!7;16
Brtract Volume (ul.) i 20
Injection Volume (ulj) t 1
Dilation Factori HOKK
Lab Sample IDt 48200-51-02 XM) BXQD
Sample Wt/7oli 1.0000 g or nLi ea
Initial Calibration Datei 06-23-99
Instrument ID: AutoSpec
OC Column IDi 5 Oa BIB
Sample Data Filename. 4807866B
Blank Data Filenamei 4807866B |2
cal. Ver. Data Filename i 48078€6B fl
Concentration Unitat pg/aample
Concantration tmita (pg)
m
•^
o
JOIHTTH
tCB-77
BCB-123
fCB-118
fCB-114
PCS-105
PCB-126
PCB-167
PCB-136
PCB-157
PCB-169
PCB-180
PCS- no
PCB-189
X3HC.
'ODKD
12.98
, *
301. OS
*
138.58
*
12.14
27. CS
*
.*
213.49
115.31
*
DKTBCTIOH
I.IMII
0.59
19.70
4. IS
C.02
4.97
3.09
3.07
2.73
2.77
1.67
3.58
14.78
15.05
IOH
RA1IO ,
0.88
*
1.S4 •'
*
1.49
*
1.41
1.30
*
*
1.03
1.01
* '
*-• TJlffifiTIIE COME
: 13C-PCB-77
13C-PCB-118
13C-PCB-10S
13C-PCB-128
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-2D*
BPIKB
cone. ; .,
2000
2000
2,000 v
2000
2000
2000
2000
2000
2000
2000
4000
COHC.
TOUHD
2813
178S
1940
2005
1930
1753
1«10
1721
1472
1539
37(1
KM
141
09
77
100
97
88
80
8fi
74
7.7
94
IOH
RitIO
0.75
1.61
1.50
1.58
1.27
1.28
1.27
1.23
. 1.02
1.04
1.20
Cl^lNUP STiHDARD
13O-PCB-81
13C-PCB-111
1000
9000
-------
m
Lab Name: BATTELLE
Matrix: XAD
Sample Receipt Date: 07-10-99
ExI. Date: 07-10-99
Analysis Date: 14-JUL-99Time: 14:57
Extract Volume (uL): 20 '
Injection Volume (uL): 1
Dilution Factor None
Concentration Units: pg/sample
Analyte
PCB-77
PCB-123
PCB-118
PCB-114
PCBrlOS
PCB-126
PCB-167
PC8-156
PCB-157
PCB-169
PCB-180
PCB-170
PCB-189
Cone. Found
12.96
*
301.06
•
138,58
*
12.14
27.65
*
f
213.49
115.31
*
Method 1 668 PCB Data Sheet
Lab Sample ID: 48200-51 -02 XAD BKGD
Sample Wt/Vol: 1.00
Initial Calabration'Date: 06-23-99
Instalment ID: AutoSpec
:16 GC Column ID: 50m HT8
Sample Data Filename: 4807866B
Blank Data Filename: 4807866B #2
Cal. Ver. Data Filename: 4807866B #1
Concentration units (pg)
Detection Limit
0.69
19.70
4.15
6.02
4.97
3.09
3.07
2.73
2.77
1.67
3.58
14.78
15.05
Ion Ratio
0.88
»
1.54
*
1.49
*
1.41
1.30
*
*
1.03
1.01
*
Labeled Compounds
13c-PCB-77
13c-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13c-PCB-209
Cleanup Stds
13C-PCB-81
13C-PCB-111
Spike Cone.
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
8000
2000
10000
Cone. Found
2815
1785
1540
2005
1930
1753
1610
1721
1472
1539
3761
*
*
R{%)
70.4
44.6
38.5
50.1
48.2
43.8
40.2
43
36.8
38.5
47
*
*
Ion Ratio
0.75
1.61
1.58
1.58
1.27
1.2B
1.27
1.23
1.02
1.04
1.20
-------
E-3-2 '
Sewage Sludge Blank Fractions
E-112
-------
OPOSquan 29-31013-1999
P»g» 11
m
_»
«*
00
Page 11 of
Method 1668 PCS Data Sheet
Lab Nan*: BMTBLLB
Matrix: SLUDGH
Sample Receipt Data: 08-08-99
Ext. Data: 08-08-99
Analy.ia Oat*: 22-JUK3-99 Time: 19:40:45
Extract Volume (uL)< 150
Injection Volume (ul>) t 1
Dilution Factors HOKB '"'
Concentration Unit*: P9/9 dry
Lab Sample ID; 48190-15-15 LB-PCB
Sample wt/Vol; 0.1445 g or nL: 9
Initial Calibration Dat*: 08-22-99
Inatrumant ID: AutoEpec
GC Column ID: 30m 8PB
3aaipl« Data Filenama: 4607890
Blank Data Filename: 4807890 f7
Cal. Var. Data Filename: 4807890 13
Concentration Onitc (pg)
fCB-77
PCB-123
PCB-118
PCB-114
fCB-105
PCB-126
PCB-167
PCS-156
FCB-157
PCB-169
PCS-180
PCB-170
fCB-189
COHC
DETECTION
voum
237
121
4695
252
2131
308
260
260
724
319
91
.70
.90.
.96
.94
.98
*
.77
.56
.56
*
.16
.46
.88
LIMIT
250.
395.
287.
73
03
09
437.48
334.
176.
190.
143.
143.
§7.
127.
154.
68.
33
11
31
82
82
89
90
53
60
IOH
RATIO
0.
1.
1.
1.
1,
1.
1.
1.
1.
1.
1.
75
53
48
06
42
*
34
26
26
*
05
04
11
LABELED COMPOUNDS'
13C-SCB-77
13C-PCT-118
13C-PCB-105
13C-PGB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-FCB-189
13C-PCB-209
BPXKB
COHC.
COHC.
FOCTNO
14"'
15 ~"
22
21
22
22
29
28
33 ,
35
ION
RATIO
0.77
1.58
1.59
1.58
1.27
1.25
1.25
1.24
1.01
1.01
1.20
CLEANUP STANDARD
13C-PCB-81
13C-PCB-1H
872
3978
-------
OPUSquan 29-ADG-1999
!
Lab Hum: BATTEKLE
Matrix i SLUDGE
Sample Rucaipt Data: 08-08-99
Bxt, Data: 08-08-99
Analyal* Data: 26-ATO-99 Time:
Extract Volume (uL) : ISO
Injection Volume (uL) ; 1
Dilution Factors MOMS ''
cone»ntration Onlti: pg/g dry
Pago 11
Method 1668 Pen Data sha«t
Lab Sample ID: 48190-15-15 IB-PCS
Sampl« Wt/Vol: 0.1445 g or mL: g
Initial Calibration Data: 08-24-99
Instrument ID: AutoSpac
01:55:08 GC Column ID: 30ra DB1
Bample Data Filename: 4807893
Blank Data Filename: 4807893 *3
Cal. Ver. Data Filename: 4807893 |2
Concentration Uniti (pg)
COHC , DBfECIION IOM
ANALYTB FOUND
pcB-77 *
PCB-123 *
PCB-118 *
PCB-114 *
FCB-105 | *
PCB-126 f *
PCB-167 276.02
PCB-156 295,70
PCB-157 89.49
tCB-169 *
tCB-180 *
fCB-170 *
PCB-189 *
LKIIT RATIO LABELED COMPOUHD3
* * 13C-PCB-77
* * 13C-PCB-118
* * ' 13C-PCB-105
* * 13C-FCB-126
* * 13C-PCJS-1S7
* * 13C-PCB-156
310.20 1.11 13C-PC8-157
382.67 1.3S 13C-PCB-169
400.49 1.15 13C-PCB-180
233.77 * 13C-PCB-189
* * 13C-PCB-209
* *
* *
CLEANUP STANDARD
13C-PCB-81
13C-PCB-111
SPIKR
COHC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
1000
5000
Page 11 of 16
CONC. IOH
FODHD R(%) RATIO
* * *
* * *
* * *
* * *
3804 25 1.26
4355 29 1.25
4032 27 1.27
£186 41 1.26
* * *
* * *
* * *
* *
* *
-------
OPUSquan 29-AUQ-1999
Page 15
Pag* 15 of 16
Method 1668 PCS Data sheet
Lab Hamas BATTBLLE
Matrix: SLUDGE
Sample Receipt Date: 07-23-99
Ext. Data: 08-08-99
Analysis Cat*: 22-AOO-99 Time: 23:55:48
Extract Volume (UL): ISO
Injection Volume (uL): 1
Dilution Factori HOSB '*
Concentration Dnlt»: pg/g dry
iKALYTB
PCB-77
PCS-123
PCB-118
PCB-11i
PCB-105 I
PCB-126 1
PCB-167
PCB-156
FCB-157
PCB-169
PCB-180
PCB-170
PCB-189
Lab Sample ID; 48190-15-11 S-R4-413B MS
Sample Wt/Vol: 0.1425 g or mL: g
Initial Calibration Date: 08-22-99
Instrument IDi AutoSpec
GC column ID: 30m SFB
Sample Data Filename: 4807890
Blank Data Filename: 4807890 |7
Cal. Ver. Data Filename: 4807890 13
Concentration Dnita (pg)
COHC.
FOUND
130297.35
100088.12
102574.29
135315.50
116551.92
11043.47
98448.43
100861.18
100861.18
16753.08
112451.92
23615.32
18821.24
DETECTIOK
LIMIT
0.00
123.65
89.87
157.09
120.05
116.03
92.57
74.85
74.85
64.06
79.58
96.16
52.80
ION
HAJIO
0.77
1.56
1.54
1.54
1.S5
1.46
1.24
1.23
1.23
1.27
1.01
1.00
l.OS
LABELED COMPOUNDS
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C--PCB-126
13C-PCB-1S7
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
SPIKE COHC.
COHC. FOUND
s, .
•vsGGj
2009
ZQOP
2000
2000
7467
7874
rfp 7899
ft| 6154
7772
2BOO / 7683
2*00 ( 7683
WOO \ 5555
F2000 J 7958
•ae*° <«ft 7531
•4fltTO -a,^ 14469
R(%)
50
52
53
41
52
51
51
37
53
50
48
IOM
RATIO
0.74
1.57
1.57
1.52
1.26
1.23
1.23
1.22
1.04
1.02
1.19
CLEANUP STAKDAFD
13C-PCB-81
13C-PCB-111
2499
14992
42
50
-------
OPUSquan 29-AUO-1999
Fag* 15
Method 1668 PCS Data Sheet
Lab Name: BATTELLH
Matrix: SLUDOB
Sample Receipt Date: 07-23-99
Ext. Data: 08-08-99
Analysis Data: 26-1103-99 Time: 05:00:29
Extract Volume (uL) : ISO
Injection Volvuna (uL) : 1
Dilution Factori MONK
Concentration Unit*: pg/g dry
tab Sarapla ID: 48190-15-11 S-R4-413B MS
Sample Wt/Vol: 0.1425 g or mL: g
Initial Calibration Data: 08-24-99
Instrument XD s AijtoSpec
QC Column IDi 30m OBI
Sample Data Filename: 4807893
Blank Data Filename: 4807893 13
Cal. V«r. Data Filename: 4807893 12
Concentration Dnita (pg)
CLEANUP STANDARD
13C-PCB-81
13C-PCB-111
1000
5000
Page 15 of IS
ANALTTK
PCB-77
PCB-123
ECB-1H
PCB-114
PCB-105 i
PCB-126 I
PCB-167
ECB-156
PCB-157
PCB-169
PCB-180
PGB-170
PCB-189
COMC.
FOOHD
i
100180.8!
109534. 41
100062. 8(
17108.8!
i
1
i
DBIBCIIOH IOM
LIMIT PATIO LABELED COMPOUNDS
* 13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
» 13C-PCB-156
5 122.35 1.23 13C-PCB-157
) 166.34 1.26 13C-PCB-169
) 153.79 1.23 13C-PCB-180
1 0.00 1.21 13C-PCB-189
> * * 13C-PCB-209
k * *
( * *
SPIKE
COMC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
COMC.
FOUND
*
*
*
*
9051
9628
9596
•471
*
*
*
R(%)
*
*
*
*
60
64
64
56
*
*
*
IOM
RATIO
*
*
*
*
1.26
1.25
1.27
1.26
*
*
*
-------
OPOSquan 29-AU3-1999
E«ge IS
m
vj
Page 16 of 16
Method 1668 PCB Data Sheet
Lab Namet BATTBUJB
Matrix: SLODGE
Sample Receipt Datei 07-23-99
Ext. Data: 08-08-99
An«ly«i« Datat 23-MHJ-99 Tinwi 00:59:35
Extract Volume (uL)t ISO
Injection Volume (uL.) ! 1
Dilution Factors UONB r
Concentration Dnltat pg/g dry
ANALYTB
FCB-77
PCB-123
PCB-118
FOB-114
PCB-105
PCB-126
SCB-1S7-
PCB-156
PCB-157
ECB-169
PCB-180
PCB-170
PCB-189
L«b Sa»pl» IDs 48190-15-12 S-R4-413B HSD
Sampl* Kt/Vol; 0.1426 g or BL: g
Initial Calibration Data: 08-22-99
In»tirumont IDi Auto Spec
QC Column ID: 30m SPB
Sample Data Filename: 4807B90
Blank Data ?ll*naiM! 4B07B90 #7
cal. V*r. Data Filename t 4807890 |3
Concentration Dnita (pg)
COHC.
FOtJKD
114960.08
99390.50
88027.30
132840.75
107742 . 15
10421.38
99020.74
101280.29
101280.29
17059.59
107589.07
21557.10
13116.21
DETECTION
LIMIT
0.00
126.98
92.28
152.99
11C. 91
107.59
93,97
73.63
73.63
60.43
77.33
93.43
54.31
IOM
RMIO
0.77
1.52
1.57
1.55
1.58
1.59
1.24
1.23
1.23
1.22
1.01
1.01
1.04
LABKLED COMPOOHDS
13C-PCB-77
13C-PCB-11B
13C-PCB-10S
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
SFIKB
COHC.
CONG.
FOtTND
4OOO
52
53
55
44
50
50
SO
38
54
50
50
CLEANUP STANDARD
13C-PCB-81
13C-PCB-111
I/MKT
gfl 2399
>F 15759
40
53
ION
RATIO
0.77
1.53
1.54
1.54
1.23
1.23
1.23
1.26
1.01
1.03
1.19
-------
OPnSquan 29-ABO-1999
Page 16
Method 1668 PCB Data Shoot
Lab Mama; BA7TELLB
Matrix; SLOCGR
Sample Receipt Date: 07-23-99
Ext. Datei 08-08-99
Analysis Data: 26-&UQ-99 Time: 05:46:51
Extract Volume (uL)i ISO
Injection Volume (uL): 1
Dilution Factors HOME ''
Lab Sarapl. ID; 46190-15-12 B-R4-413B USD
Sample Ht/Vol: 0.1426 g or nl>: g
Initial Calibration Date: 08-24-99
Instrument ID: JtatoSpec
QC Column ID: 30m DB1
Sample Data Filename: 4807893
Blank Data Filename: 4807893 §3
Cal. Ver. Data Filenames 4807893 12
Fag* 16 of
Concentration Unite pg/g dry
Concentration Unit* (p
*
60
65
63
59
*
*
*
IOH
RATIO
*
*
*
*
1.2£
1.25
1.26
1.25
*
*
*
CLEANUP STANDARD
13C-ICB-81
13C-PCB-111
1000
5000
-------
1-3-3
Scrubber Water Fractions
E-119
-------
OPUggnan 29-MIG-199J
Pago 2
Fag* 2 of 16
Method 1668 POT Data Shoot
Lab Hame: BATTELLE
Matrix! HATER
S»mple Receipt Data: 07-28-99
Bxt. Dat«! 07-28-99
analy«i» Date: 22-ADS-99 Tima: 07:58:52
Extract 7oliuiM (uL) : 20
Injaction Volume (uL): 1
Dilution Factori NOME "
Concentration Onltn
JtNALYTB
PCS-77
PCB-123
PCB-116
PCB-114
fCB-105
PCB-126
PCB-167
SCB-156
PCB-157
PCB-169
BCB-180
SCB-170
PCB-189
Lab Sample ID: 48200-S6-11 1B-FCB
Sample Wt/Vol: 0.5000 g or mL: L
Initial Calibration Data: 08-22-99
Instrument ID: Autospec
GC Colimn ID; 30m 8PB
Sample Data Filename: 4807890
Blank Data Filanaraa: 4*07890 |7
Cal, Var. Data Fil.nami: 4807890 *3
Coneantratlon Unita
CONC.
FOOND
38.75
83.01
984.75
151.39
480.37
8.25
93.00
92.99
92.99
8.97
172.70
CO. 54
13.74
DETECTION
LIMIT
0.00
11.56
8.40
14.89
11.38
5.98
7.26
5.54
5.54
2,64
4.94
5.97
3.08
IOH
RATIO
0.88
1.62
1.58
1.69
1.58
1.77
1.39
1.22
1.22
1.25
1.02
0.90
1.13
LABELED COMPOUNDS
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-1S7
13C-PCB-169
13C-SCB-180
13C-PCB-189
13C-PCB-209
CLEA1JCTP STAKDARD
13C-PCB-81
13C-PCB-111
BPIKS
cove.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
CONC.
FO0HD
•21
628
617
878
712
743
743
972
940
973
2220
R(%>
41
31
31
44
36
37
37
•49
47
49
56
ION
RATIO
0.73
1.58
1.56
1.5S
1.24
1,25
1.25
1.25
1.O2
1.04
1.19
1000
5000
540
2240
54
45
-------
OCOSquan 29-ADQ-1999
E»go 1
m
P»g« 1 of 16
Method 1668 FOB Data Sheet
Lab Hams: BA7TBLLB
Matrix: WATER
Sampl* R*c*ipt D«t«: 07-28-99
Kxt. Dat«: 07-28-99
Analy»I« Pat*; 25-A0S-99 Xlaa: 17:25:13
Extract Volume (uL): 20
Injection Volunw (ill*) t 1
Dilution Factori KOHS "
Lab Sample ID: 48200-56-11 LB-PCB
Sample Wt/Vol: 0.5000 g or ml.: L
Initial Calibration Data: 08-24-99
Inotmnwnt ZDi JkutoSpac
ac Column ID: 30m DB1
Sample Data Pilanan*; 4807893
Blank Data Filonaraa: 4807893 *3
Cal. V«r. Data Filenama: 4807893 42
Concentration Onltag
Concentration 0nlt> (pgl
ANALYTE
FCB-77
fCB-123
PCB-118
PCB-1K
FCB-105
fCB-12«
PCB-167
COHC«
FOUND
DETBCTIOW
LIMIT
ION
RATIO
ECB-1S7
PCB-169
PCB-180
PCB-170
PCB-189
89,25
123,93
70.60
9.84
12.27
0,00
7.12
*
*
*
1.28
1.24
1.39
*
LABELED COMPOUNDS
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-5CB-167
13C-SCB-156
13C-SCB-157
13C-BCB-1S9
13C-fCB-180
13C-PCB-189
13C-PCB-209
CLEAHOF STANDARD
13C-PCS-81
13C-PCB-111
SPIKB
COWC .
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
1000
5000
CONC.
FOUND
' *
*
*
*
829
919
800
1348
*
*
*
*
*
R(*>
*
*
*
*
41
46
40
67
*
*
* •
*
*
IOH
RATIO
*
*
*
*
1.28
1.23
1.26
1.25
*
*
*
-------
OPUSquan 29-AOG-1999
P»g« 9
Page 9 of 16
f
Method 1668 ECB Data Sheet
Lab Name: BATTELLB
Matrix:'WATER
Sample Receipt Date: 07-28-99
Ext. Date: 07-28-99
Analyal* Date: 22-AUG-99 Time: 15:25:29
Extract Volume (uL): 20
Injection Volume (uL): 1
Dilution Factor: NONE ''
concentration Unite pg/L
ANALTTE
PCB-77
PCS-123.
PCB-118
PCB-114
PCB-105
PCB-126
PCB-167
PCS-156
PCS-157
PCB-169
PCB-180
PCB-170
PCB-189
Lab Sample ID: 48200-56-09 LCS-PCB
Sample Ht/Vol: 0.5000 g or mL: L
Initial Calibration Date: 09-22-99
Instrument ID: Autospec
GC Column ID: 30m SPB
Sample Data Filename: 4807890
Blank Data Filename: 4807890 »7
cal. Ver. Data Filename: 4807890 #3
Concentration Unita (pg)
CONC.
FOUND
1365.34
31814.49.
40739.29*^
56625.84V
36456.35
2772.58
27630.92
27231.08
27231.08
4423.48
27897.85
6382.57
4677.54
DETECTION
LIMIT
0.00
262.89
191.06
320.05
244.59
126.04
234.17
160.38
160.39
69.11
150.46
181.79
115.71
ION
RATIO
0.78
1.48
1.54
1.56
1.57
1.48
1.23
1.26
1.26
1.18
1.04
1.04
1.13
LABELED COMPOUNDS
13C-PCB-77
13C-PCB-11B
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
CLEANUP STANDARD
13C-PCB-81
13C-PCB-111
SPIKE
CONC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
1000
5000
CONC.
FOUND
53
32
35
50
29
31
31
46
39
31
58
475
1928
48
39
ION
RATIO
0.77
1.50
1.60
1.59
1.24
1.20
1.20
1.15
0.98
1.09
1.16
-------
OPUSquan 29-AOQ-1999
Fag* 2
Method 1668 PCB Data Sheat
Lab Hanw: BATTELLK
Matrix: WATER
Sarapl* Receipt Dat*: 07-28-99
Ext. Date: 07-28-99
Xnaly«i« Dat*t 25-AUG-99 Tima: 18:11:35
Extract Voluma (uL) : 20
Injection Volvnn* (ul<} : .1
Dilution Factor: MOHK
Concentration Unit*: pg/L
Lab Sampla ID: 48200-56-09 LC3-PCB
Sample Ht/Vol: 0.5000 g or mL: L
Initial Calibration Data: 08-24-99
Instrument ID: JuitoSp«c
GC Column ID: 30m DB1
8ampl» Data Filanaraa: 4807893
Blank Data Filename: 4807893 #3
Gal. Vac. Data Filename: 4807893 12
Concentration Unite (pg)
CUUVMOP STANDARD
13C-PCB-81
13C-PCB-111
1000
5000
Pag« 2 of 16
I
NJ
CO
ANALTTR
PCB-77
PCB-123
, PCB-118
?CB-114
PCS- 10$ I
ECB-126 5
ECB-167 .
PCB-156
PCB-157
PCB-1C9
FCB-180
PCB-170
PCB-189
COHG.
FOUND
*
33544.28
30289.71
27741.84
*
*
*
*
DETECTION
LIMII
*
*
*
*
*
*
266.83
354.29
403. C3
*
*
*
*
ion
RATIO
*
1.23
1.25
1.29
1.31
*
*
A
LABELED COMPOUNDS
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13G-1CB-167
13C-fCB-156
13C-PCB-1S7
13C-tCS-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
SPIES
COHC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
COHC.
roiffiD
*
*
*
*
32
41
37
*
*
*
*
R(%)
*
*
*
*
2 s-
2 /
2 *S
*
*
*
* "
IOH
RATIO
*
*
*
*
1,19
1.38
1.15
*
*
*
*
-------
OPOSquan 29-MJO-1999
Page 10
f Method 16S8 PCS Data Sheet
l^b Mao*! WaymMM I^ib Sample ID: 48200-56-10 LCSDOP-PCB
Matrix: WATER Sample Wt/Vol: 0.5000 g or OL: L
Sample Receipt Dates 07-28-99 Initial Calibration Date: 08-22-99
Ext. Date i 07-28-99 Instrument ID: Autoepec
Analy»i« Date: 22- Ana- 9 9 Time: 16:29:17 SC Column ID: 30m SPB
Extract Volume (uL) : 20 Sample Data Filaname: 4607890
Injection Volume (uL) : 1 Blank Data Filename: 4807890 |7
Dilution Factor: VOWS r Cal. Var. Data filename: 4807890 <3
concentration tlnit»: pg/L
ANALIT2
SCB-77
1CB-123
PCB-118
PCB-114
PCB-105 i
PCS- 12 6 2
PCB-167
PCB-156
PCB-157
1CB-169
PCB-180
SCB-170
PCB-189
cowc.
FOUND
853.05
31444.11
25972.56 ,
48740.48V
33082.28
3266.07
28320.22
27930.75
27930.75
4694.26
24662.56
4784.90
4300.75
.•$• ^
t .'r' J*y
DETECTION
LIMIT
0.00
9.35
6.80
11.91
9.10
5.51
6.97
5.40
5.40
2.90
5.11
6.17
3.33
**
^
IOH
RATIO
0.77
1.53
1.53
1.53
1.54
1.54
1.24
1.24
1.24
1.26
1.01
1.01
0.99
Page 10 of 16
Concentration Units (pg)
LABELED COMPOUNDS
13C-PCB-77
13C-PCB-118
13C-PCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-1S6
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
CLEANUP STANDARD
13C-PCB-81
13C-PCB-111
SPIKE
CONC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
1000
5000
COMC.
FOUND
10S7
657
650
809
572
587
587
677
727
726
1243
743
2820
R(*>
53
33
33
40 L
29-f
29M'
294-
34
36
36 • '
31
74
56
ION
RATIO
0.77
1.61
1.60
1.53
1.26
1.22
1.22
1.25
1.02
1.04
1.19
y.
Jtr Q"
NLi§ #w^a
-------
OPUSquan 29-ADQ-1999
Pag* 3
NJ
U1
Bags 3 of 16
Method 1668 fCB Data Sheet
Lab Nana: BATTBLLB
. Matrix: WLIER
Sainpl* R«c»ipt Dat«: 07-26-99
Ext, Dat«: 07-28-99
*naly«i« Dates 2S-MJB-99 3ln»: 18:57t57
Extract Volum (uL): 20
Injection Volume (uL)t 1
Dilution Factor: NONB
Concentration Unit*:
AHALYTK
FCB-77
PCB-123
PCB-118
PCB-1H
PCB-105
PCB-126
tCB-167
pea-ise
PCB-157
PCB-16B
PCB-180
PCB-170
PCB-189
Lab 8«qpl* ID: 48200-56-10 LCSDUP-PCB
Sample Wt/Vol: 0.5000 g or mL: L
Initial Calibration D«t«: 08-24-99
InctEument ID: ftutosp«c
GO Column XD: 30m DB1
6ampl« Data Filename: 4807893
Blank Data rilanaraa: 4807893 #3
Cal. V»r. Data Filonamai 4807893 12
CONC.
FOUND
29525.51
30463.5:
28562.5]
4772. 91
i
i
DETECT K
I.ZMXI
> 9.2:
1 11.4!
1 12 . 0(
) O.OC
k •
> 4
DH ION
. »MI
*
*
*
ft
*
I 1,24
) 1.24
; 1.24
> 1.21
r *
* *
Concentration Units (pg)
LABELED COMPOUNDS"
13C-PCB-77
13C-PCB-118
13C-PCB-10S
13C-PCB-126
13C-PCB-167
13C-PCB-1S6
13C-PCB-1S7
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-PCB-209
SPIKE
CONC,
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
CLEANUP STANDARD
13C-PCB-81
13C-FCB-111
SPIKE
CONC,
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
CONC.
FOUND
*
*
*
*
725
835
752
1082
*
*
*
R<%>
*
*
«
*
36
42
38
54
*
* .
-------
OPOSqu«n 21-SEF-1999
Fage 1
page 17 of 19
Method 1668 PCB Data Sheet
Lab Hanm: BAT7BLLE
Mat r ix: WATER
Sample Receipt Date: 07-28-99
B.tt. Dates 07-28-99
Analyol. Date: 20-8EP-99 Time: 19:52:45
Extract Volume (uL): 20
Injection Volume (uL)i 1
Dilution Factor; HONK
Concentration Unit*: pg/L
AHALTTE
BCB-77
ECB-123
fCB-118
PCB-114
BCB-10S j
JfCB-126 \
PCB-167
eCB-156
FCB-157
PCB-169
PCB-180
PCB-189
lab Sample ID: 48200-56-11 LAB BLANK
Sample Ift/Vol: 0.5000 g or mL: L
Initial Calibration Date: 08-22-99
Instrument ID: AutoSpae
GC Column ID; 30m SPB
Sample Data Filename: 4807897
Blank Data Filename: 4807890 tl
Cal. Vet. Data Filename: 4807890 »3
Concentration Unltn (pg)
ccwc.
FOUND
26.85
41.04
857.61
91.34
396.21
4.19
45.45
54.39
54.39
5.14
131.23
46.13
10.43
DEIBCIIOH
LIMIT
0.00
10.14
7.37
14.09
10.77
3" 4.82
7.07
6.23
6.23
2.83
4.51
5.45
3.60
IOH
RATIO
0.79
1.70
1.60
1.45
1.54
1.52
1.10
1.29
1.29
1.41
1.07
1.19
1.17
LABELED COWOOHDS
13C-PCB-77
13C-POB-118
13C-tCB-105
13C-PCB-126
13C-PCB-167
13C-PCB-156
13C-PCB-157
13C-PCB-169
13C-PCB-180
13C-PCB-189
13C-SCS-209
CLEANUP STANDARD
13C-PCB-81
13C-SCB-111
SPIKB
COHC.
2000
2000
2000
2000
2000
2000
2000
2000
2000
2000
4000
CCTTC.
FOUND
1290
729
659
1084
749
674
674
912
859
684
1140
ION
R(%) RATIO
65
36
33
54
37
34
34
46
43
34
29
0
1
1
1
1
1
1
1
1
1
1
.76
.60
.59
,57
.25
.23
.23
.23
.03
.04
.19
1000
5000
843
3357
•var
-------
OPtJSquan 22-SEP-1999
f
Lab Name: BATTELLB
Matrix: WATER
Bangle Receipt Cat*: 07-28-99
Ext. Dat«: 07-28-99
Analysis Date: 21-SBP-99 lima:
Extract Volume (TIL) : 20
Injection Volum* (uL) : 1
Dilution Factor: NONE
Concentration Units: pg/L
COHC .
ANALYTK rODHD
JfCB-77 *
SCB-123 *
PCB-1H *
JGB-114 *
POB-IOS I *
PCB-126 1 *
PCB-167 4 • ^
2000 890 44 1.25
2000 720 36 1.27
20PO * * • *
2000 * * • ' *
4000 * * *
1000 * *
5000 * *
-------
WA1« Front Half Ate
LCSn.CS Duplicate Ratuttm
m
«i
00
ANAtYTC
PCB-77
PCB-123
PCB-118
PCB-114
PCB-105
PCB-12B
PCB-187
PCB-156*
PCM 57*
PCS 199
PCB-180
PCB-170
PCB-189
LCSSplk*
Cone.
(poAhcm)
127,88
8303,84
6393.88
8383.88
8393.88
63038
6393.86
6393.88
6383.88
1278.77
6393.88
1278.77
127877
48190-11-10
l«b Blink
Cone.
(pg/dtcm)
11.45
91 18
321.27
122. SB
224.40
5.11
74.48
M.74
78.18
5.89
58.58
10,58
849
. 48190-11-08
LCSCone.
Found
171.83
7281.84
5818.17
0451.88
7385.38
7S2.14
7309.17
8184.13
7B40.B8
1277.04
7282.23
1598.52
1378.86
Racovary
(*}
125
112
83
148 S.
112
117
113
127
121
eg
113
123
107
LCSDuftSpika
Cone.
(PO'dfcm)
127,88
' 8393.86
8383.88
8393.88
8303.88
639.38
839388
8393.88
8393.88
1278.77
8313.88
1278.77
1278.77
48100-11-10
L.b Blink
Cone.
(pg/*tcm)
11.45
91.16
321.27
122.59
224.40
5.11
74.48
94.74
78.18
5.89
5S.S8
18.58
8.49
48190-1 1-OB
LCS Dup Cone.
Found
(POldtcm;
185.73
7191.69
5849.73
9439.69
7300.30
733.88
7208.48
8204,13
7647.80
1272.48
7189.07
1501.77
1385.25
Racovary
w
121
111
83
148 S
111
114
113
127
122
89
111
118
108
Racovary
RPD
C*)
30
1.0
0.6
0.1
1.2
2.S
0.1
0.2
0.1
0.4
13
8.3
05
R«covery to cilculitad »( (cone, found-blink cone
& =ouWd«DQO 0(70-1 30%
* * vulus Irom DB1 confirmation.
cofK.;*100
-------
WAUS Back Half AJn
pg/diem
LCSfl.CS Duplicate Results
m
— » .
Ni
co
ANAIYTE
PCB-77
PCB-123
PCB-118
PCB-114
PCS-IDS
PC&126
PCB-167
PCB.156S
PC6-157*
PCB-169
PCB-180
PCB-170
PCB-189
LCS Spike
Cono.
(pg/dscm)
127,88
6383.86
6383.88
6393.86
638386
639.39
0393 M
6M386
6393.66
1278.77
8393 88
1278,77
1278.77
48190-09-11
Lab Blank
Cone.
(Pfl/dscm)
800
6.44
197.27
13.06
9152
'0.88
8.05
15.28
5.16
0.72
29.93
12.33
0.96
4819009-09
LCSConc.
Found
(pgfascm)
170.32
7192.15
5669.69
9877.87
7537.10
748.87
717914
7577.08
7303.64
1257,97
7037.52
1640.53
1336.36
Recovery
(%)
127
112
88
154 &
116
117
112
118
114
98
110
120
104
LCS Dup Splkt
Cone.
(pOWscm)
1S.88
6393.88
6393,86
6393.86
S393.86
639.39
S393.86
6393.38
8393.88
1278.77
6393.86
1278.77
1278.77
48190-09-11
lab Blank
Cone.
(pgftftem)
9.00
6.44
187 2!
13.08
91.52
068
8.0S
15.28
5.16
0.72
28.93
12.33
0.98
481904)9-10 '
LCS Dup. Cone.
Found
(pa/dscm)
179.60
7504.43
9843.53
1071194
7713.59
758.16
7587.49
7938.92
7534.87
1283.38
7445.01
1534.48
1388.87
Recovery
(%)
134 8
117
60
167 &
119
119
119
124
118
101
116
119
103
Recovery
RPO
(%)
56
4.3
3.1
8.1
2.3
1.4
5.5
4.7
3.1
2.8
5.6
0.4
3.7
Recovery It calculated ac( (cone, found-blink cnnc j/tpika cone )'100
& toutektoDQOonO-130%
t f vsliw from OB 1 contlnmtkm.
-------
W
o
WM-OSWMm
pgA.
LCSfl.CS DuptaM R*«ull»
ANALYTC
PCB-77
PCB-12S
PCB-11B
PC8-114
PC B- 103
PCS-1M
PC B- 187
PCB-IMff
PCS- 157*
pea-ma
PC B- ISO
PC&.1TO
PCB-1B3
LCSBpk.
Cone.
(P9A.)
80000
40000,00
40000,00
40000.00
40000.09
4000.00
4dQQO.QQ
40000.90
40000.90
900000
40000.00
Sdoooo
j 800000
48200-58-11
Uk Blink
Cone,
(Pflt)
M.7S
(3.01
984.7S
151.SS
4S037
873
•3.00
123.83
7080
807
172.TO
, 6054
13.74
4B200-S6-09
ICSConc.
Found
(M*.)
136534
318M.48
40739.2ft
5662S64
36456.15
2772.M
27(30.92
3O7S471
I7741.M
442348
27SS7SS
S3SZST
4877.94
Rceowfy
(*)
1G6 1
79
99
141
90
M
M
7«
«g
65
8»
Ti
58
LCS D'Jp Soft*
Cone.
(Pflfl-)
80000
4000000
40000.00
40000.00
40000.00
4000,00
40000.00
40000.00
40000.00
800000
40000.00
800000
8000.00
4(200-86-11
Lib Blink
Cone.
(PC/1)
3875
•301
BM.7S
1S1.W
4*0,37
8,15
S3 00
123,91
7080
887
1T2.70
8054
13.74
48 200- 5S- 10
LCS Dup. Cone.
Found
(nan.)
153.09
31444.11
2M72.M
48740.48
33M2.2S
3Ht.07
2*320.22
90403.W
2IBGB1
4«84.2«
54*63.5*
47M.M
4300,75
Rwcovtry
{%)
102
7*
87
121
(2
11
71
76
71
W
11
W
54
Rtemwy
RPO
{%)
48
1
48
18
10
11
2
1
3
«
12
39
*
RKxmiy h afculiM »>( (cone, found-blink conc.yip!k* conc.)*10Q
t •ouMkMDOOlIf 40-160%
t * vilut fram DB1 copfirmitton.
-------
t Q •- _k « -.—.—._ O —
JI3 N-s«---"««--«
**SS'*^^''^*">'*
t'rti«JO*N*-o™Soi2r*w
—. Jlliilll^lli
»g - -
||g| ^s|s. s^s^s"?. 2s
55 - "
| . | ft ft ft 5 5 S 5 5 ft R ft. R R
c
3*,? S»a8Sft5??8?SS
ic
5s
81
ii
5i
a:
*t |? ^
<2 §i
It Sc6
E-131
-------
APPENDIX F
Dioxin/Furan Analytical Lab Raw Data Results
-------
F-l
D/F Results Summary
F-1
-------
F-l-1
Air Sample Fractions
F-2
-------
Table F-1T. Run 2 Dioxin/Furan Results • Stack Gas Concentrations (ng/dscm, as
measured)
Congener
Concentration (ng/dscm, as measured)'
FH
BH
TOTAL
Dioxins
2,3,7,8-TCDD t
Total TCDD
1,2,3,7,8-PCDD
Total PCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
Total HxCDD
1,2,3,4,6,7,8-HpCDD
Total HpCDD
Octa CDD
Total CDD
0,001
0.055
ND<0.0026
0.012
0.001
0.002
0.004
0.041
0.035
0.074
0.118
0.300
0.097
2,969
0.017
0.694
0.014
0.036
{0.035}
0.565
0.169
0.385
0.199
4.813
0.098
3.024
0.017
0.706
0.015
0.038
0.039
0,606
0.204
0.459
0.317
5,113
Furans
2,3,7.8-TCDF #
Total TCDF
1,2,3,7,8-PCDF
2,3,4,7,8-PCDF
Total PCOF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
Total HxCDF
1.2,3.4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
Total HpCDF
Octa CDF
Total CDF
Total CDD + CDF
0,019
0,119
0.004
0.014
0.107
(0.013)
0.005
0.013
ND<0.001
0.062
0.027
0.004
0.042
0.022
0.351
0.651
1.564
5,488
0.191
0.375
4.826
• 0.213
0.076
0.113
ND< 0.001
1.064
0.197
0.019
0,287
0,068
11.733
16.545"
1.583
5.607
0.195
0.389
4.933
0.226
0.081
0.126
ND< 0.001
1.126
0.224
0.023
0,329
0.090
1 2.084
17.196
* ng/dscm; nanogram per dry standard cubic meter.
Standard conditions, pressure and.temperature defined as 1 atm (760 mm Hgl and 20°C.
Note: (Below Detection Limit) values listed in parentheses and {EMPC} values listed in brackets.
ND < B Non Detect, value is detection limit.
S <= value from confirmation column.
Non Detect and {EMPC} value! not included in totals.
Numbers rounded before summing, totals may vary from report table in Section 2.
F-3
-------
Table F-2T. Run 3 Dioxin/Furan Results - Stack Gas Concentrations (ng/dscm, as measured)
Congener
Concentration (ng/dscm, as measured!'
FH
BH
TOTAL
Dioxins
2,3,7,8-TCDD *
Total TCDD
1,2,3,7,8-PCDD
Total PCDD
1,2,3,4,7.8-HxCOD
1,2,3,6,7,8-HxCDO
1,2,3,7,8,9-HxCDD
Total HxCDD
1,2,3,4,6,7,8-HpCDD
Total HpCDD
Octa ODD
Total CDD
ND<0.0005
0.029
ND<0.0024
0.003
ND< 0.0008
0.002
ND<0.0005
0.023
0.022
0.050
0.069
0.174
0.067
3.505
0.013
' 0.655
0.015
0.038
0.035
0.561
0.180
1.402
0.234
6.357
Furans
2,3,7,8-TCDF #
Total TCDF
1,2,3,7,8-PCDF
2,3,4,7,8-PCDF
Total PCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7, 8-HxCDF
1,2,3,7,8,9-HxCDF
Total HxCDF
1, 2,3,4,6,7, 8-HpCDF
1,2,3,4,7,8,9-HpCDF
Total HpCDF
Octa CDF
Total CDF
Total CDD + CDF
0.010
0.064
0.002
0.006
0.042
{0.005}
0.003
0.006
ND< 0.001
0.022
0.014
'(0.001)
0.015
0.016
0.159
0.333
1.227
4.815
0.148
0277
3.624
0.172
0,064
0.091
ND<0.002
0.858
0,171
0.016
0.246
0.066
9.610
1 5.S66
0.067
3. 634
0,013
0.658
0.015
0.04C
0.035
0.584
0,202
1.452
0.303
6,531
1.237
4.879
0.150
0.283
3.666
0,17?
0.067
0.097
NO < 0.003
0, 880
0,185
0.017
0.261
0,08?
3,765
16.23S
" ng/dscm; nanogram per dry standard cubic meter. .
Standard conditions, pressure and temperature defined as 1 atm (760 mm Hg! and 20°C,
Note: (Below Detection Limit! values listed in parentheses and (EMPC) values listed in brackets
ND< = Non Detect, value is detection limit.
# = value from confirmation column.
Non Detect and {EMPC} values not included in totals.
Numbers rounded before summing, totals may vary from report table in Section 2.
F-4
-------
Table F-3T. Run 4 Dioxin/Furan Results - Stack Gas Concentrations (ng/dscm, as measured)
Congener
Concentration (ng/dscm, as measured)*
FH
BH
TOTAL
Dioxins
2,3,7, 8-TCDD #
Total TCDD
1,2,3,7,8-PCDD
Total PCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1 ,2,3,7,8,9-HxCDD
Total HxCDD
1, 2,3,4,6, 7,8-HpCDD
Total HpCDD
Octa CDD
Total CDD
ND<0.0007
0.021
ND< 0.0027
0.002
ND< 0.0008
0.002
0.002
0.027
0.019
0.044
0,060
0.155
0.034
0.698
(0.005)
0.185
0.006 '
0.011
0.016
• 0.297
0.074
0.193
0.080
1.453
0.034
0.719
(0.005)
0.187
0.006
0.013
0.018
0.324
0.093
0.237
0.140
1.608
Furan*
2,3,7,8-TCDF f
Total TCDF
1.2,3.7,8-PCDF
2,3,4,7,8-PCDF
Total PCDF
1, 2,3,4,7, 8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
Total HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
Total HpCDF
Octa CDF
Total CDF
total CDD -f CDF
0.013
0.089
{0,003}
0.007
0.057
{0.006}
0.003
0.006
ND<0.001
0.029
0.014
{0.002}
0.015
0,012
0.201
0.356
0.520
2.482
0.065
0.116
1.479
0.086
0.032
0.045
ND< 0.002
0.381
0.089
0.007
0.122
0.029
4.494
5.947
0.533
2.571
0.068
0.123
1.536
0.092
0.035
0.051
ND< 0.003
0.410
0.103
0.009
0.137
0.041
4.696
6.303
* ng/dscm; nanogram per dry standard cubic meter,
Standard conditions, pressure and temperature defined as 1 atm (760 mm Hg) and 20°C.
Note: (Below Detection Limit] values listed in parentheses and {EMPC} values listed in brackets.
ND< = Non Detect, value is detection limit.
f - value from confirmation column.
Non Detect and (EMPC} values not included in totals.
Numbers rounded before summing, totals may vary from report table in Section 2.
F-5
-------
F-l-2
D/F EPA Audit Sample
F-6
-------
D/F Laboratory Air Results Sample Table F-3
D/F Audit Sample ng/Sample (X4)
Battalia ID
Audit Sample No.
Analysis date
Congener
2378-TCDD
1 2378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
1 2378-PeCDF
23478-PeCDF
123478-HxCDF
1 23678-HxCDF
123789-HxCDF
234678-HxCDF
1 234678-HpCDF
1 234789 HpCDF
OCDF
Total TEQ
Total Tatra-Furans
Total Tatra -Dioxins
Audit Sample
BH
48190-09-08
M23-031
8-16-99
Concen.
/%Raoov.
0.50428
0.48120
0.46556
0.53732
0.56408
1.1332
1.30096
0.66164
0.58612
0.56784
0.588S2
0.62472
0.52908
0.60404
1.19208
0.95272
0.61492
1.67676
1.2134
Q
tt
TEQ
0.5042744
0.2405988
0.0465564
0.0537308
0.0564100
0.0113320
0.001 3008
0.0165409
0.0293060
0.2838184
0,0588512
0.0824732
0.0529072
0.0604040
0.0119208
0.0095272
0.0006148
1.5472232
Detection
Limit
0.00752
0.01656
0,006
0.0056
0.00368
0.00488
0.0028
0.001 37
0.00816
0.00684
0.0071,6
0.00824
0.0072
0.00898
0.00268
0.01 1 38
0.01956
0.00944
0.01304
-------
D/F Laboratory Air ResuftS"Sample Table F-3
D/F Audit Sample ng/Sample (X4)
Total Panta-Furans
Total P«nta-Dioxlns
Total Hexa-Furans
Total Hexs-Dioxins
Total Hapta-Furans
Total Hepta-Dioxins
1 3C-2378TCDF
13C-12371-PeCDF
1 3C-1 23678-HxCDF
13C-1234678-HPCDF
1 3C-2378-TCDD
13C-12378-PeCDD
13C-123678-HxCDD
13C-1234678-HpCDD
13C-OCDD
37CI-2378-TCDD
13C-123478-HXCDD
13C-23478-P8CDF
1 3C-1 23478-HxCDF
1 3C-1 234783-HpCDF
8H-AUDIT
2.21468
1.77212
3.62032
2.63392
2.1448
1 .75472
65
75
60
71
65
81
67
7$
75
NA
NA
NA
NA
NA
It
0.01386
0.01 880
0.01368
0.00904
0.00316
0.02212
1 '
NA = Not applicable,
# = value from confirmation column.
-------
F-2 •
D/F Lab Raw Data Sheets
F-9
-------
F-2-1
Air Emission Runs
F-10
-------
OPUSquan 27-AUG-1999
Page 5
PCDD/PCDF ANALYSIS DATA SHEET
Lab Name: BATTELLE Lab Sample ID: 48190-11-02 FH-R2-DIOX
Matrix: AIR Sample Wt/Vol: 1.4620 unita: M3
Sample Receipt Date: 08-07-99 Initial Calibration Date: 04-22-99
Ext. Date: 08-07-99 Instrument ID: Autospec
Analysis Date: 16-AUG-99 Time: 00:09:13 GC Column ID: 60m DBS
Extract Volume (uL) : 20 Sample Data Filename: 4807886A
Injection Volume (uL) : 1 Blank Data Filename: 4807886A *1
Dilution Factor: NONE Cal. Ver. Data Filename: 4807886 12
CONC.
FOUND
ANALYTE pg/dacm
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23479-reCDF
123478-HxCDF-fnvPC
123678-HxCDF
123789-HxCDF
234678-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furans
Total Tetra-Dioxina
Total Penta-Furana
Total Penta-Dioxina
Total Hexa-Furana
• Total Hexa-Dioxins
Total Hepta-Furana
Total Hepta-Dioxins
Total TEQ
2.52
*
0.93
2.35
4.26
35.02
117.85
27.00
4.00
13.53
13.01
5.06
*
12.89
26.71
3.52
22.00
119.39
55.44
106.72
11.95
61.54
40.91
41.69
73.76
DETECTION
LIMIT
pg/dscm
1.31
2.57
0.88
0.81
0.54
0.71
0.41
0.78
1.31
1.10
i.07
0.94
1.08
1.04
0.38
1.66
2.86
1.58
2.26
2.23
2.92 ;
2.05
1.32
0.46
3.25
TEQ
2.5167
*
0.0932
0.2351
0.4264
0,3502
0.1178
2.7003
0.1998
6.7674
1.3006
0.5058
*
1.2694
0.2671
0.0352
0.0220
16.8269
LABELED COMPOUNDS
13C-2378-TCDF
13C-12378-PeCDF
13C-123678-HXCDF
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HXCDD
13C-1234678-HpCDD
13C-OCDD
PRE-FIELD SURROGATES
37C1-2378-TCDD
13C-123478-HXCDD
13C-23478-PeCDF
13C-123478-HXCDF
13C-1234789-HpCDF
SPIKE
CONC.
(pg)
2000
2000
2000
2000
2000
2000
2000
2000
4000
JlOOO '"LOO
2boo\.
20OO \ ilj
20M ) "
200 nial
^PI\><
CONC.
FOtJND
(pg)
1379
1690
1310
1584
1448
1909
1495
1664
3242
203
*
*
k
*
(Jt\ *
Page 5 of 20
RECOVERY
(%)
69
84
65
79
72
95
75
83
81
CL W
102'— CjulQjn~<-»4-> W^'
*
*
*
*
-------
OPUSquan 30-MG-1999
Lab Name: BATTELLE
Matrix; AXR
Sample Receipt Date: 07-21-99
Sxt. Dates 08-01-99
Analyala Date: 18-ACG-99 lime
Extract Volume (uL) : 20
Injection Volume (uL) ; 1
Dilution factor; HOME
COHC.
FO0HD
ANALYTE pg/d«cm
2378-TCDD 1.04
12378-feCDD *
123478-HXCDD *
123678-HxCDD *
123789-HxCDD *
1234678-HpCDD *
OCDD *
2378-ICDB1 18.54
"P 12378-F*CDP *
-* 23«78-PeCDF *
10 123478-HxCDF *
123«78-HJcCDF *
123789-HxCDF *
234678-HxCDF *
1234678-HpCDF *
1234789-HpCDF *
OCDF *
Total Tetra-Furana 117.25
Total TetJM-Dloxln» 55.66
Total Penta-Furana *
Total Penta-Dloxint *
Total Hexa-Furana *
• Total Bex»-Dioxina *
Total Bepta-Fnrana *
Total nepta-Dioxins *
Total TEQ
Page 6
PCDD/PCDF ANALYSIS DATA 6HEET
Page 6 of 11
Lab Sample ID: 48190-11-02 FH-R2-DIOX
Sample Wt/Vol: 1.4620
Initial Calibration Date:
Instrument ID: AutoSpac
: 09:28:21 QC Column ID: 30mD8225
units: M3
04-22-99
Sample Data Filename: 4807887
Blank Data Filename: 4807887 f!3
Cal. Ver. Data Filename;
DETECflON
LIMIT ZEQ
pg/dacm LABELED COMPOUNDS
0.53 1.0444 13C-2378-TCDI-
* * 13C-12378-PeCDF
* * 13C-123678-HJCCDF
* * 13C-1234678-HpCDF
* * 13C-2378-TCDD
* * 13C-12378-PeCDD
* * 13C-123678-HXCDD
0,90 1.8536 13C-1234«78-HpCDD
* * 13C-OCDD
*
*
*
*
*
*
*
*
1.31 PRE-FIELD SURROGATES
5.58
* 37C1-2378-TCDD
* 13C-123478-BXCDD
* 13C-23478-PeCDF
* 13C-123478-H3CCDF
* 13C-1234789-HpCDt
*
2.8980
4807887 |12
SPIKB COHC.
COHC. FOUND RECOVERY
-------
-n
CO
Lab Name: Battelle
Matrix: Air
Sample Receipt Date 08/07/99
Ext. Date: 08/07/99
Analysis Date: 16-Aug-99 Time:
Extract Volume (uL): 20
Injection Volume (uL): 1
Dilution Factor: None
Analyte
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
123789-HxCDF
234678-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furans
Total Tetra-Dioxins
Total Penta-Furans
Total Penta-Dioxins
Total Hexa-Furans
Total Mexa-Dioxins
Total Hepta-Furans
Total Hepta-Dioxins
Total TEQ
Cone.
Found
pg/sample
14.74
*
5.44
13.74
24.91
... 204.80
689.19
157.90
23.39
79.12
76.08
29.59
*
75.38
156.20
20.58
128.66
698.19
324.21
624.10
69.88
359.89
239.24
243.80
431.35
12:09: 13 AM
Detection
Limit
pg/sample
7.66
15.03
5.15
4.74
3.16
4.15
2.40
4.56
7.66
6.43
6.26
5.50
6.32
6.08
2.22
9.71
16.73
9.24
13.22
13.04
17.08
11.99
7.72
2.69
19.01
PCDD/PCDF ANALYSIS DATA SHEET
Lab Sample ID: 48190-11-02 FH-R2-DIOX
Sample Wt/Vol: 1 units:
Initial Calibration Date: 04/22/99
Instrument ID: AutoSpec
GC Column ID: 60m DB5
Sample Data Filename: 4807886A
Blank Data Filename: 4807886A #1
Cal. Ver. Data Filename: 4807886 #2
TEQ
pg/sample
14.72
*
0.55
1.37
2.49
2.05
0.69
15.79
1.17
39.58
7.61
2.96
*
7.54
1.56
0.21
0.13
98.40
Labeled Compounds
13C-2378-TCDF
13C-12378-PeCDF
13C-1 23678
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HxCDD
13C-1234678-HpCDD
13C-OCDD
Cleanup Stds
37CI-2378-TCDD
13C-123478HxCDD
13C-23478-PeCDF
13C-123478-HxCDF
13C-1234789-HpCDF
Spike
Cone.
(pg)
8000
8000
8000
8000
8000
8000
8000
8000
16000
800
NA
NA
NA
NA
Cone.
Found
(pg)
5516
6760
5240
6336
5792
7636
5980
6656
12968
812
*
•
*
*
Recovery
69
84
65
79
72
95
75
83
81
102
*
•
•
*
-------
PCDD/PCDF ANALYSIS DATA SHEET
Lab Name:
Matrix:
Sample Receipt Date:
Ext. Date:
Analysis Date:
Extract Volume (uL):
Injection Volume (uL):
Dilution Factor:
Analyte
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234S78-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
123789-HxCDF
234678-HxCDF
1234878-HpCDF
1234789-HpCDF
OCDF
Total Tefra-Furans
Total Tetra-Dioxins
Total Penta-Furans
Total Penta-Dioxins
Total Hexa-Furans
Total Hexa-Dioxins
Total Hepta-Furans
Total Hepta-Dioxins
Total TEQ
Battolle
Air
0.03367
08/01/99
18-Aug-99 Time: 9:28:21 AM
20
1
None
Cone. Detection
Found Limit TEQ
pg/sample pg/sample pg/sample
6,08 3.10 6.11
* * *
* * *
* * *
ft * •
* * *
* * *
108.42 • 5.26 10.84
* * *
* * *
* - * *
* * * •
* * *
» * *
* * *
* * *
* * . *
685.88 ?<66
325.50 32.63
* *
9 *
* - *
t* *
* • *
* *
16.95
Lab Sample ID:
Sample Wt/Vol:
Initial Calibration Date:
Instrument ID:
GC Column ID:
Sample Data Filename:
Blank Data Filename:
Cal. Ver. Data Filename:
Labeled Compounds
13C-2378-TCDF
13C-12378-PeCDF
13C-1 23678
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
1X-123678-HxCDD
13C-1234678-HpCDD
13C-OCDD
Cleanup Stds
37CI-2378-TCDD
13C-123478HXCDD
13C-23478-PeCDF
13C-123478-HxCDF
13C-1234789-HpCDF
48190-11-02 FH-R2-DIOX
1 units:
04/22/99
AutoSpec
30M DB225
4807887
4807887 #13
4807887*12
Spike Cone.
Cone. Found
(PS) (pg)
8000 5168
8000
8000
8000
8000 5580
8000
8000
8000
16000
800 820
NA
NA
NA *
NA
Recovery
(%)
65
*
*
* _
70
*
*
*
*
103
*
*
*
*
-------
OPDSquan 27-AOO-1999
Page 6
fCDD/PCDF ABAtiYSIS DATA SHEET
Lab Name: BATTELLE l,ab Sample ID: 48190-11-03 FH-R3-DIOX
Matrix: AIR Sample Wt/Vol: 1.5550 units: M3
Sample Receipt Date: 08-07-99 Initial Calibration Date: 04-22-99
Ext. Data: 08-07-99 Instrument ID: tetospee
Analysis Date: 16-ACTG-99 Time: 01:15:15 GC column ID: 60n DBS
Extract Volume (uL) : 20 Sample Data Filename: 4807886A
Injection Volume (uL) : 1 Blank Data Filename; 4807886A #1
Dilution Factor: HONE Cal. Ver. Data Filename: 4807886 §2
ANALYTE
2378-TCDD
12378-PeCDD
123478-HXCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-P«CDF
23478-PBCDF
123478-HJtCDF •— &W-K
123678-BxCDF
123789-HxCDF
234678-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
CONC.
FOOMD
pg/daon
*
*
*
1.54
*
22.16
68.90
13.67
2.28
5.49
5.19
2,58
*
5,96
13.49
1.23
16.38
Total Tetra-Furan« -I»«.R.63.47
Total Tetra-Dioxlna
Total Penta-Furans
Total P«nta-Diexin»
Total Baxft-Furan*
Total Hexa-Dioxins
Total Hepta-FuranB
Total Bepta-Dioxin»
Total TEQ '
29.15
42.24
3.42
21.88
22.50
14.71
50.42
DETECTION
LIMIT
pg/dscm
1.21
2.44
0.82
0.16
0.50
0.68
0.35
0.74
1.25
1.05
1.00
0.87
1.01
0.97
0.36
3 1.57
2.70
1.50
2.10
2.13
2,77
1.91
1.23
0.44
3.08
TEQ
*
*
*
0.1536
*
0.2216
0.0689
1.3669
0.1142
2.7431
0.5192
0.2581
*
0.5957
0.1348
0.0123
0,0164
6.2047
1ABELED COMPOUNDS
13C-2378-TCDF
13C-12378-PeCDF
13C-123678-HXCDF
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HXCDD
13C-1234678-HpCDD
13C-OCDD
PRE-FIEI.D SURROGATES
37C1-2378-TCDD
130-123478-HxOBO
13C-23478-PeCDF
13C-123478 -HxCDF
1301234789-HpCDF
SPIKE
COHC.
(pg)
2000
2OOO
2OOO
2000
2000
2000
2000
2000
4000
§OO
|A^-
ut
Vi>^
Page 6 of 20
COHC,
FOOND RECOVER!
(P3> (*>
1413 71
1731 87
13SO 67
1621 81
1531 77
1967 98
1512 76
1713 86
3S56 91
^
203 101. -CJJ^*-1"1 "''•-£' OTP"
* *
* «
* *
* *
1
/
4H
-------
o>
OPDSquan 30-AB0-1999
Lab Names BATTELLE
Matrix: AIR
sample Receipt Data: 07-21-99
Ext. Date: 08-01-99
Analysis Data: 18-A0B-99 Time
Extract. Volume (uL) : 20
Injection Volume (uL> : 1
Dilution Factor; NONE
CONG .
FOUND
ANALYZE pg/dson
2378-TCDD *
12378-PeCDD *
123478-HxCDD *
123678-HXCDD *
123789-HJtCDD
1234678-HpCDD
OCDD
2378-TCDF 9.5
12378-P«CDF
234">8-FeCDF
123478-HxCDF
123678-HrCDF
123789-HxCDF
234678-H3CCIM?
1234678-HpCDF
1234789-BpCDF
OCDF
Total Tatra-Fnrana 48.79
Total tetra-Dioxinn 27.20
Total Penta-Furina *
Total Ponta-Dioxln* *
Total Hexa-Furana *
Total Hexa-Bioxlna *
Total Hepta-Furana *
Total Hepta-Dioxlns *
Total 1EQ
Page 7
PCDD/PCDF
Page 7 of 11
ANALYSIS DATA SHEET
Lab Sample ID: 48190-11-03 FH-R3-DIOX
; 10:16:23
Sample Jft/Vol: 1.5550
Initial Calibration Data;
Instrument ID: AutoSpac
OC Column ID: 30mDB225
units: M3
04-22-99
Sample Data Filename: 4807887
Blank Data Filename: 4807887 113
DETECTION
LIMIT TBQ
pg/dscro
0.51
*
*
*
*
*
*
0.88 9.
*
* •
*
*
*
*
*
* •
*
1.28
5.35
*
*
*
*
*
*
0.
*
*
it
it
*
*
*
9499
*
*
*
*
*
*
*
*
*
9499
Cal, Vet. Data Filename:
LABELED COMPOUNDS
13C-2378-TCDF
13C-12378-FeCDF
13C-123678-HXCDF
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HXCDD
13C-1234678-HpCDD
13C-OCDD
PKE-FIELD SORROGATES
37C1-2378-TCDD
13C-123478-HXCDD
13C-23478-PeCDF
13C-123478-HXCDF
13C-1234789-HpCDF
4807887 112
8V IKE CONG.
CONC. FQOHD RECOVBRy
(pgt) (pgj (%)
2000 1384 69
2000 * *
2000 * *
2000 * *
2000 1503 75
2000 * *
2000 * *
2000 * *
4000 * *
/} ftWL>
f0® 201 100 '<- ^Jl&CO^""''"''^
* *\
1 1 * *\ KiA
Kir' * * /
A ID 1 I/ *
WA^^^Q V
-------
Tl
vj
Lab Name:
Matrix:
Sample Receipt Date
Ext. Date:
Analysis Date:
Extract Volume (uL):
Injection Volume (uL):
Dilution Factor:
Analyte
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
123789-HxCDF
234678-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furans
Total Tetra-Dioxins
Total Penta-Furans
Total Penta-Dioxins
Total Hexa-Furans
Total Hexa-Dioxins
Total Hepta-Furans
Total Hepta-Dioxins
Total TEQ
Battelle
Air
08/07/99
08/07/99
20
1
None
Cone.
Found
pg/sample
*
*
*
9.58
*
137.84
428.56
85.03
14.18
34.15
32.28
16.05
*
37.07
83.85
7.65 J
101.88
394.78
181.31
262.73
21.27
136.09
139.95
91.50
313.61
1:15:15 AM
Detection
Limit
pg/sample
7.53
15.18
5.10
4.73
3.11
4.23
2.18
4.60
7.78
6.53
6.22
5.41
6.28
6.03
2.24
9.77
16.79 •
9.33
13.06
13.25
17.23
11.88
7.65
2.74
19.16
PCDD/PCDF ANALYSIS
TEQ
pg/sample
*
*
*
0.24
*
0.34
0.11
2.13
0.18
4.27
0.81
0.40
*
0.93
0.21
0.02
0.03
38.59
> DATA SHEET
Lab Sample ID:
Sample Wt/Vol:
Initial Calibration Date:
Instrument ID:
GC Column ID:
Sample Data Filename:
Blank Data Filename:
Cal. Ver. Data Filename:
Labeled Compounds
13C-2378-TCDF
13C-12378-PeCDF
13C- 123678
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HxCDD
13C-1234678-HpCDD
13C-OCDD
Cleanup Stds
37CI-2378-TCDD
13C-123478HxCDD
13C-23478-PeCDF
13C-123478-HXCDF
13C-1234789-HpCDF
48190-11-03
1
04/22/99
Autospec
60m DBS
4807886A
4807886A #1
4807886 #2
Spike
Cone.
(P9)
8000
8000
8000
8000
8000
8000
8000
8000
16000
800
NA
NA
NA
NA
FH-R3-DIOX
units:
Cone.
Found
(pg)
5652
6924
5400
6484
6124
7868
6048
6852
14624
812
*
*
•
•
Recovery
(%)
71
87
67
81
77
98
76
86
91
101
*
*
*
*
-------
Lab Name:
Matrix:
Sample Receipt Data
Exl. Date:
Analysis Date:
Extract Volume (uL);
injection Volume (uL):
Dilution Factor:
Anatyte
2378-TCDD
12378-PeCDD
123478-HxCDD
1238T8-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
123789-HxCDF
234878-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furans
Total Tetra-Dtoxins
Total Penta-Furans.
Total Penta-Dtoxins
Total Hexa-Furans
Total Hexa-Dioxins
Total Hepta-Furans
Total Hepta-Dioxins
Total TEQ
Batlelle
Air
07/21/99
08/01/99
18-Aug-99 Time: 10:1 6:23 AM
20
1
None
Cone, Detection
Found Limit
pg/sample pg/sample
2,98
* *
* *
* *
* *
* *
* *
55,56 . 5,15
* *
* *
* *
• *
* *
* *
* *
* *
* t
285.32 7,49
159.07 31,29
* *
* *
* *
* *
* - *
» »
PCDD/PCDF ANALYSIS DATA SHEET
Lab Sample ID:
Sample Wt/Vol;
Initial Calibration Date:
Instrument ID:
GC Column ID:
Sample Data Filename:
Blank Data Filename:
Cal. Ver. Data Filename:
TEQ
pg/sample , Labeled Compounds
13C-2378-TCDF
13C-12378-PeCDF
13C-1 23678
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HxCDD
5.56 13C-1234678-HpCDD
13C-OCDD
*
*
*
*
*
*
t
*
Cleanup Stds
37CI-2378-TCDD
13C-123478HxCDD
13C-23478-PeCDF
13C-123478-HxGDF
13C-12347-89-HpCDF
5..S6
48190-11-03 FH-R3-DIOX
1 units:
04/22/99
AutoSpec
30M DB225
4807887
4807887 #13
4807887 #12
Spike Cone.
Cone. Found
(P9) (P9)
8000 5536
8000 *
8000
8000
8000 6012
8000
8000
8000
16000
a. ft
*Q u
^00 ^01
* «
* *
* *
* *
Recovery
(%)
69
*
*
4
75
0
*
*
*
100
*
*
-------
CD
OPOSquan 27-ADS-1999
Page 7
Page 7 of 20
PCDD/PCDF ANAliTSIS DATA SHEET
lab Kama: BATTELLB tab Sample ID: 48190-11-04 FH-R4-DIOX
Matrix: AIR Sample Ht/Vol: 1.6750 unite: M3
Sample Receipt Date: 08-07-99 Initial Calibration Data: 04-22-99
Ext. Date: 08-07-99 Instrument ID: Autoapec
Analysis Date: 16-AUG-99 Time: 02:21:17 GC Column ID: 60m DBS
Extract Volume (ML) : 20 Sample Data Filename : 4 807 8 8 6A
injection Volume (uL) : 1 Blank Data Filename: 4807886A fl
Dilution Factor: NONE Cal. Vet. Data Filename; 4807886 *2
COHC.
FOUND
ANAXiYTB pg/dscm
2378-TCDD
12378-PeCDD
123478-HJtCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
237B-TCDF
12378-PeCDF -£fflFC-
23478-reCDF
123478-BxCDF -tfm At
123678-HxCDF
123789-HxCDF
234678-HxCDF
1234678-HpCDF
123478 9-HpCDF - S 01 fit
OCDF
Total Tetra-Furans
Total Tetra-Dioxina
Total Penta-Furans
Total Pehta-Dioxina
Total H«jta-Furana
Total Hftxa-Dioxlna
Total Hepta-Furans
Total Hepta-Dioxina
Total TEQ
*
*
*
1.54
2.38
18.93
60.23
19.04
2.50
7.04
6.12
2.68
*
6.01
13.50
1.55.
12.26"
88.63
21.24
56.66
2.38
28.99
27.23
14.70
44.16
DETECTION
LIMIT
pg/dscm
1.48
2.66
0.82
0.77
0.50
0.65
0.33
0.88
1.42
1.1S
1.06
0.92
1.07
1.03
0.37
3 1.64
2.83
1.80
2.57
2.41
3.02
2.02
1.24
0.46
2.94
TEQ
*
*
*
0.1536
0.2381
0.1893
0.0602
1.9042
0.1250
3 . P2?*)
0.6121
0.2678
*
0,6011
0.1350
0.015S
0.0123
7.8362
1ABEI£D COMPOUNDS
13C-2378-TCDF
13C-12378-PeCDF
13C-123678-HXCDF
1301234678-HpCDF
13C-2378-TCDD
13c-12378-PeCDD
13C- 123 678 -HJCCDD
1301234678-HpCDD
13C-OCDD
_
PRE-FIELD SURROGATES
37C1-2378-TCDD
130123478-HxCDD
13023478-PeCDF
13C-123478 -H JtCDF
1301234789-HpCDF
SPIKB COHC .
COHC . FOUKD RECOVER?
(P9> ?P9) (*)
2000 1149 57
2000 1427 71
2000 1268 63
2000 1593 80
2000 . 1152 58
2000 1696 85
2000 1515 76
2000 1793. 90
4000 3884 97
i(\ *"i\cV.
^QOO *^O 198 99 -CJUUXyx-^-V3
2\004 * *
20BO\ ii * *
200P / ^ * *
2001 • * *
i^Ai^
-------
OPUSquan 30-AUQ-1999
Page
Page 8 of 11
PCDD/PCDF ANALYSIS DATA SHEET
Lab Maine i BATTELLE
Matrix: AIR
Sample Receipt Data: 07-23-99
lact. Date: 08-01-99
Analysis Date: 18-AUS-99 Time: 11:04:22
Extract Velum* (uL) : 20
Injection Volume (ul.) ; 1
Dilution Factor: HONE
tab Sample ID: 48190-11-04 FH-R4-DIOX
Sample Ht/Vol: 1.6750 units: H3
Initial Calibration Date: 04-22-99
Instrument 10! AutoEpec
GC Column ID: 30mOB225
Sample Data Filename; 4807887
Blank Data Filename; 4807887 |13
Cal. Vet. Data Filename: 4807887 |12
M
o
AHALYTB
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-ttxCDD
123789-HxCDD
1234678-BpCDD
OCDD
2378-TCDF
12378-BeCDF
23478-PeCDF
123478-HxCDF
123678-HXCDF
12378 9-HXCDF
234678-HxCDF
1234678-HpCDF
123478 9-HpCDf
OCDF
Total Tetra-Furan*
Total Tetra-Dioxina
Total P«nta-Furana
Total Penta-Dioxine
Total Rexa-Fucana
Total Hexa-Dioxinn
Total Hepta-Furana
Total Repta-Dioxlna
COHC.
FOUHD
pq/d»ca
*
*
*
*
*
*
*
12,81
*
*
*
*
*
*
*
*
*
79.18
23.11
*
*
it
it
*
*
DETECTION
LIMIT
pg/d«cm
0.67
*
*
*
*
*
*
1.07
*
*
*
*
*
*
*
*
*
1.56
6.99
*
*
*
*
*
*
TEQ
SPIKE
COHC.
COHC.
FOOHD
1.2813
LABELED COMPOUNDS
13C-2378-TCDF
13C-12378-FBCW
13C-123678-HXCDF
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-P«CDD
13C-123678-BXCDD
13C-1234678-HPCDD
13C-OCDD
PRE-FIELD SOPJROGATES
37C1-2378-TCDD
13C-123478-HXCDD
13C-23478-teCDP
13C-123478-HxCDF
13G-1234789-BpCDF
2000
2000
2000
2000
2000
2000
2000
2000
4000
1074
*
*
*
1128
RBCOVERT
W
54
5
199
ion -
Total TBQ
1.2813
-------
Lab Name:
Matrix:
Sample Receipt Date
Ext, Date:
Analysis Date:
Extract Volume (uL):
Injection Volume (uL)
Dilution Factor;
Analyte
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
t2378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
123789-HxCDF
234878-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furans
Total Tetra-Dfoxins
Total Penta-Furans
Total Penta-Dioxins
Total Hexa-Furans
Total Hexa-Dioxins
Total Hepta-Furans
Total Hepta-Dioxins
Total TEQ
Battelle
Air
08/07/99
08/07/99
16-Aug-99 Time:
20
1
None
Cone.
Found
pg/sample
*
*
*
10.32
15.95
126.83
403.54
127.57
16.75
47.17
41.00
17.96
*
40.27
90.45
10.39 J
82.14
593.82
142.31
379.62
15.95
.194.23
182.44
98.49
295.87
2:21:17 AM
Detection
Limit
pg/sample
9.92
17.82
5.49
5.16
3.35
4.36
2.21
5.90
9.51
7.97
7.10
6.16
7.17
6.90
2.48
10.99
18.96
12.06
17.22
16.15
20.23
13.53
8.31
3.08
19.70
PCDD/PCDF ANALYSIS DATA SHEET
Lab Sample ID: 481 90-1 1 -04 FH-R4-DIOX
Sample Wt/Vol: 1 units:
Initial Calibration Date: 04/22/99
Instrument ID: Autospec
GC Column ID: 60m DBS
Sample Data Filename: 4807886A
Blank Data Filename: 4807886A #1
Cal. Ver. Data Filename: 4807886 #2
TEQ
pg/sample
*
•
*
1.03
1.60
1.27
0.40
12.76
0.84
23.60
4.10
1.79
*
4.03
0.90
0.10
0.08
•• 52.50
Spike
Cone.
Labeled Compounds (pg)
13C-2378-TCDF 8000
13C-12378-PeCDF 8000
13C-123678 8000
13C-1234678-HpCDF 8000
13C-2378-TCDD 8000
13C-12378-PeCDD 8000
13C-123678-HxCDD 8000
13C-1234678-HpCDD 8000
13C-OCDD 16000
Cleanup Stds
37CI-2378-TCDD 800
13C-123478HxCDD
13C-23478-PeCDF
13C-123478-HxCDF *
13C-1234789-HpCDF
Cone.
Found
(pg)
4596
5708
5072
6372
4608
6784
6060
7164
15536
792
*
*
*
*
Recovery
(%)
57
71
63
80
58
85
76
90
97
99
*
«
«
•
-------
"fl
fo
KJ
Lab Name:
Matrix:
Sample Receipt Date:
Ext, Date:
Analysis Date:
Extract Volume (uL):
injection Volume (uL):
Dilution Factor;
Analyte
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234878-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
123788-HxCDF
234678-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furans
Total Tetra-Dioxins
Total Penta-Furans
Total Penta-Dtoxins
Total Hexa-Furans
Total Hexa-Dioxins
Total Hepta-Furans
Total Hepta-Dtoxins
Total TEQ
Battelle
Air
07/23/99
08/01/99
1 8-Aug-99 Time: 1 1 :04:22 AM
20
1
None
Cone. Detection
Found Limit
pgfsample pg/sample
4,49
ft , *
* *
* *
* *
* *
« ' *
, 85.83 7.17
"* *
* *
* *
* *
* *
* *
* . *
* *
„ * *
530.51 . 10.45
154.84 46.83
* *
* . ' *
* *
* *
* *
*- *
PCDD/PCDF ANALYSIS DATA SHEET
Lab Sample ID:
Sample Wt/Vol:
Initial Calibration Date:
Instrument ID:
GC Column ID:
Sample Data Filename:
Blank Data Filename:
Cal. Ver, Data Filename:
TEQ
pg/sample Labeled Compounds
13C-2378-TCDF
13C-12378-PeCDF
13C-1 23678
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HxCDD
8.58 13C-1234678-HpCDD
13C-OCDD
*
*
* <
*
*
*
*
*
Cleanup Stds
37CI-2378-TCDD
13C-123478HxCDD
13C-23478-PeCDF
13C-123478-HxCDF
13C-1234789-HpCDF
8.58
48190-11-04 FH-R4-DIOX
1 units:
04/22/99
AutoSpec
30MDB225
4807887
4807887 #13
4807887 #12
Spike Cone.
Cone. Found
(pg)
-------
CO
OPtlSquan 27-AUC3-1999
Page
17
PCDD/PCDF ANALYSIS DATA SHEET
tah Name: BATTELLE Lab Sample ID: 48190-09-02 BH-R2-DIOX
Matrix: AIR Sample Ht/Vol: 1.4620 unltfl: M3
Sample Receipt Date: 08-07-9S Initial Calibration Date: 04-22-99
Ext. Datat 08-07-99 Instrument ID: Autospee
Analysis Date: 16-AUG-99 Time: 15:34:29 GC Column ID: 60m DBS
Extract Volume (uL) : 20 Sample Data Filename; 4807886A
' Injection Volume (UL) : 1 Blank Data Filename; 4807886A 11
Dilution Factor: 1:2 Cal, Ver . Data Filename: 4807886 |2
ANALTTE
2378-TCDD
12378-PeCDD
123478-BxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PaCDF
123478-HxCDF
123678-HxCDF
123789-HacCDF
234678-HxCDF
1234678-HpCDF
1234789-BpCDF
OCDI"
Total Tetra-Furana
Total Tetra-Dioxinn
Total Pcnta-Furana
Total Penta-Dioxino
Total Hexa-Furana
• Total Hexa-Dioxlns
Total Kept a-Fur BUB
Total Hepta-Dioxihs
Total TEQ
CONC.
FOUND
pg/dscm
*
16.74
13.94
35.69
DETECTION
LIMIT
pg/dscm
2.71
6.02
1.73
1.61
34.796iWPc. 1.06
169.42
198.99
1749.93
190.64
375.10
212.82
76.39
*
113.04
196.52
18.57
67.93
5487.98
2969.39
4825.95
693 , 93
1064,33
565.11
286.67
385.09
1.37
0,68
2,01
2.98
2,50
'2.08
1.81
2.09
2.02
0.73
3.21
5.54
4.10
4.70
5.06
6.84
3.97
2.61
0.89
6.25
TEQ
*
8,3677
1.3939
3.5689
3.4785
1.6942
0.1990
174.9932
9.5320
167,5498
21.2817
7 . 6392
*
11.3044
1 . 9652
0,1857
0,0679
433,2212
LABELED COMPOUNDS
13C-2378-TCDF
13C-12378-PeCDF
13C-123678-EKCDF
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-BXODD
13C- 123 4 678-HpCDD
13C-OCDD
PRE -FIELD SURROGATES
37C1-2378-TCDD
13C-123478-HXCDD
13C-23478-P«CDF
13C-123478-HxCDF
13C-1234789-HpCDF
SPIKE
CONC.
(pg)
2000
2000
2000
2000
2000
2000
2000
2000
4000
2000
2000
2000
2000
2000
CONC.
FOUND
(pg)
996
1400
1221
1432
1289
1547
1377
1493
3527
1992
2079
1939
1959
1514
Page 17 of 20
RECOVERY
(%)
50
70
61
72 •
64
77
69
75
88
100
104
97
98
76
-------
OPOSqunn 30-AUG-1999
Page 9
PCDD/PCDF ANALYSIS DATA SHEE1
Lab HUM! BRTTELLB
Matrix: AIR
Sample E*c*lpt Data: 07-21-99
Ext; Data: 07-26-99
Analysis D»t»: 18-AUG-99 limn: 11:52:19
Extract Volume (uL) : 20
injection Volume (uL) : 1
Dilation Factor: 1:2
Lab Samp IB ID; 48190-09-02 BH-R2-DIOX
Sampl« Wt/Vol: 1.4620 units: M3
Initial Calibration Data: 04-22-99
Instrument ID: AutoSpec
GC Column ID: 30nDB22S
Sample Data Filename: 4807887
Blank Data Filename: 4807887 113
Cal. Ver. Data Filename: 4807887 #12
Page 9 of 11
ANALYTE
2378-TCDB
12378-F«CDD
123478-HxCDD
123678-HXCDD
123789-HxCBD
1234676-HpCDD
OCDD
2378-fCM'
12378-F«CDF
123478-HxCDF
123678-HXCDF
123789-ExCDF
234678-HxCDF
1234678-BpCDF
123478 9-I^iCDF
OCDF
COHC. DETECTIOH
FOOND LIMIT
pg/dscra pq/dscrn
96.69
1564.11
Total
Total
Total
Total
Total
Total
Total
Total
T«tra-Fur*n»
Tetxa-Dloxina
Penta-Furane
Penta-Dioxlns
H*xa-Furana
Hexa-Dioxin*
Hepta-Fucana
Hepta-Diozins
5643. 8S
2970,83
1.2£
2,53
3.«9
13.18
TEQ
96.6893
A
*
*
*
156.4114
LABELED COMPOUNDS
13C-2378-TCDF
13C-12378-PeCDF
13C-123 67 B-HxCDF
13C-1234678-HpCBF
13C-2378-TCDD
13C-12378-P«CDD
13C-123678-HXCDD
13C-1234678-HpCDD
13C-OCDD
PRE-FI8tD SORROGATE5
37C1-237B-TCDD
13C-123478-HXCDD
13C-2347B-PBCDF
13C-123478-HXCDF
13C-1234789-BpCDF
SPIKE
CONC.
(pg)
2000
2000
2000
2000
2000
2000
2000
2000
4000
COHC,
FOOHD
(pg>
961
*
*
*
1241
*
*
*
*
RECOVERY
<%>
48
*
*
*
62
*
*
*
*
Total TEQ
253.1008
-------
Lab Name:
Matrix:
Sample Receipt Date
Ext. Date:
Analysis Date:
Extract Volume (uL):
Injection Volume (uL>
Dilution Factor:
Analyte
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234878-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
123789-HxCDF
234678-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furans
Total Tatra-Dioxins
Total Penta-Furans
Total Penta-Dloxins
Total Hexa-Furans
Total Hexa-Dioxins
Total Hepta-Furans
Total Hepta-Dioxins
Total TEQ
Battelle
Air
08/07/99
08/07/99
16-Aug-99 Time:
20
1
1:2
Cone.
Found
pg/sample
»
97.90
81.52
208.72
203.45 EMPC
990.77
1163.69
10233.59
1114.86
2193.58
1244.57
446.73
«
661.06
1149.25
108.60
397.25
32093.71
17364.99
28222.16
4058.10
6224.20
3304.76
1676.45
2251.83
3:34:29 PM
Detection
Limit
pg/sample
15.85
35.20
10.12
9.42
6.20
8.01
3.98
11.75
17.43
14.62
12.16
10.58
12.22
11.81
4.27
18.77
32.40
23.98
27.49
29.59
40.00
23.22
15.26
5.20
36.55
PCDD/PCDF ANALYSIS DATA SHEET
Lab Sample ID:
Sample Wt/Vol:
Initial Calibration Date:
Instrument ID:
GC Column ID:
Sample Data Filename:
Blank Data Filename:
Cat. Ver. Data Filename:
TEQ
pg/sample
*
48.93
8.15
20.87
20.34
9.91
1.16
1023.36
55.74
1096.79
124.46
44.67
•*
66.11
11.49
1.09
0.40
2533.48
Labeled Compounds
13C-2378-TCDF
13C-12378-PeCDF
13C-1 23678
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HXCDD
13C-1234678-HpCDD
13C-OCDD
Pre-Field Surrogates Stds
37C1-2378-TCDD
13C-123478HxCDD
13C-23478-PeCDF
13C-123478-HxCDF
13C-1234789-HpCDF
48190-09-02 BH-R2-DIOX
1 units:
04/22/99
AutoSpeo
60m DBS
4807886A
4807886A #1
4807886 #2
Spike
Cone.
(pg)
8000
8000
8000
8000
8000
8000
8000
8000
16000
8000
8000
8000
8000
8000
Cone.
Found
(P9)
3984
5600
4884
5728
5156
6188
5508
5972
14108
7968
8316
7756
7836
6056
Recovery
(%)
50
70
61
72
64
77
69
75
88
100
104
97
98
76
-------
Lab Name:
Matrix:
Sample Receipt Date
Ext, Date:
Analysis Date:
Extract Volume (uL):
Injection Volume (uL):
Dilution Factor:
Analyte
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCOD
2378-TCOF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123i78-HxCOF
123789-HxCDF
234678-HxCDF
1234678-HpCDF
1234789-HpCOF
OCDF
Total Tetra-Furans
Total Tetra-Dioxins
Total Penta-Furans
Total Penta-Dioxlns
Total Hexa-Furans
Total Hexa-Dtoxins
Total Hepta-Furans
Total Hepta-Dioxins
Total TEQ
Battelle
Air
07/21/99
07/28/99
18-Aug-99 Time: 11:52: 19 AM
20
1
1:2
Cone. Detection
Found Limit
pg/sample pg/sample
565.44 7.37
* *
* - *
* *
* *
*• *
* ' *
9146.92 14,80
* *
* *
*- »
* * •
* *
* *
* *
* *
* *
33005,23 21.58
17373.41 77,08
* *
* *
* . *
* *
* *
* • *
PCDD/PCDF ANALYSIS DATA SHEET
Lab Sample ID:
Sample VWVol:
Initial Calibration Date:
Insltunwnt ID:
GC Column ID:
Sample Data Filename:
Blank Data Filename:
Cal. Ver, Data Filename:
TEQ
pg/sample Labeled Compounds
565.44 13C-2378-TCDF
13C-12378-PBCDF
13C-1 23678
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
130-123678-HxCDD
914,69 13C-1234678-HpCDD
13C-OCDD
*
*
*
*
*
*
*
*
Pro-Field Surrogates Stds
37CI-2378-TCDD
13C-123478HxCDD
13C-23478-PeCDF
13C-123478-HxCDF
13C-1234789-HpCDF
370,03
48190-09-02 BH-R2-DIOX
1 units:
04/22/99
AutoSpec
30m DB225
4807887
4807887 #13
48078887*12
Spike Cone.
Cone. Found
(pg) (pg)
8000 3844
8000 *
8000
8000
8000 4984
8000
8000
8000
16000
8000 8444
8000
8000
8000
8000
Recovery
(%)
48
*
*
*
62
*
*
*
*
106
*
*
*
*
-------
71
•vl
1
OPUSquan 27-AUG-1999
Page
18
Page 18 of 20
PCDD/PCDF ANALYSIS DATA SHEET
Lab Name: BATTELLE
Matrix: AIR
Sample Receipt Date: 08-07-99
Ext. Date: 08-07-99
Analysis Date: 16-AUG-99 Time
Extract Volume (uL) : 20
Injection Volume (uL) : 1
Dilution Factor: 1:2
CONC.
FOUND
ANALYTE pg/decm
2378-TCDD *
12378-PeCDD 12 . 60
123478-HxCDD 14.48
123678-HxCDD 37.85
123789-HxCDD 34 . 92
1234678-HpCDD 180.41
OCDD 234.40
2378-TCDF 1366.89
12378-PeCDF 147.96
23478-p»CDF 276.59
123478-HXCDF 172.43
123678-HxCDF 63.69
123789-HXCDF *
234678-HxCDF 90.51
1234678-HpCDF 170.86
1234789-HpCDF 16.05
OCDF 66.25
Total Tetra-Furans 4815.43
Total Tetra-Dioxins 3504.47
Total Penta-Furans 3623.92
Total Penta-Dioxins 654.90
Total Hexa-Furana 857.48
Total HexarDioxins 560.61
Total Bepta-Furans ' 246.41
Total Repta-Dioxins 402.30
Total TEQ
Lab Sample ID: 48190-09-03 BH-R3-DIOX
16:40:39
sample Wt/Vol: 1.5550
Initial Calibration Date
Instrument ID: Autospec
GC Column ID: 60m DBS
units: M3
04-22-99
Sample Data Filename: 4807886A
Blank Data Filename: 4807886A fl
DETECTION
LIMIT
pg/dsem
3.16
5.91
1.87
1.74
1.14
1.50
0.73
1.99
2.83
2.37
2.25
1.96
2.27
2.18
0.80
3.52
6.06
4.05
5.47
4.81
6.71
4.30
2.81
0.98
6.85
TEQ
*
6.3006
1.4476
3.7848
3.4922
1.8041
0.2344
136.6886
7.3981
138.2949
17.2429
6.3689
*
9.0515
1.7086
0.1605
0.0662
334.0438
Cal. Ver. Data Filename:
LABELED COMPOONDS
13C-2378-TCDF
13C-12378-PeCDF
13C-123678-HXCDF
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HXCDD
13C-1234678-HpCDD
13C-OCDD
EKE-FIELD SURROGATES
37C1-2378-TCDD
13C-123478-HXCDD
13C-23478-PeCDF
13C-123478-HXCDF
13C-1234789-HpCDF
4807886 »2
SPIKE CONC.
CONC . FOUND RECOVERY
(pg) (pg) (*)
2000 997 50
2000 1432 72
2000 1344 67
2000 1562 78
2000 1096 55
2000 1554 78
2000 1454 73
2000 1645 82
4000 3786 95
2000 2125 'l06'
2000 2432 122
2000 2123 106
2000 2132 107
2000 1903 95
-------
OFUSquan 30-AOG-1999
Page 10
T
to
PCDD/PCDF ANALYSIS DATA SHEET
tab Name: BATTELLE
Matrix: AIR
Sample Receipt Date: 07-21-99
Ext. >Date: 07-28-99
Analyaia Date: 18-AUG-99 Time: 12:40:16
Extract Volume (uL): 20
Injection Volume (uL): 1
Dilution Factor: 1:2
AHALTTE
2378-TCDD
12378-JeCDD
12347B-HXCDD
123678-H3CCDD
123789-HxCDD
1234678-HpCtJD
OCDD
2378-TCDF
12378-PeCDF
COHC. DBTECIIOH
FOOHD LIMIT
pg/dacm pg/dacm
67.21
1.36
TEQ
67.2091
1226.67
2.53
123478-HjcCDF
123678-HxOW
123789-HXCDF
234678-BxCDF
1234678-HpCDF
1234789-HpCDF
OCOF
122.6669
*
*
*
*
*
Total
Total
Total
Total
Total
Total
Total
Total
letra-Farajna
Tetra-Dloxina
Penta-Furana
Penta-Dioxin*
Bexa-Furans
Hexa-Oioxina
Hnpta-Furana
Bapta-Dioxins
5163.92
3421.42
3.69
14.23
Total IEQ
189,8760
Lab Sarapla IDt 48190-09-03 BH-R3-P1OX
Sample Mt/Vol: 1.5550 unit!: H3
Initial Calibration Date: 04-22-99
Instrumsnt ID t AutoEpec
BC Column ID: 30mDB225
Sample Data Filename: 4807887
Blank Data Filename; 4B07887 f!3
Cal. Ver. Data Filename: 4807887 |12
LABEljED COMPOUNDS
13C-2378-TCDF
13C-12378-P»CDF
13C-123678-HXC0F
13G-1234678-HpCDF
13C-2378-TCDD
13C-12378-P«CDD
13C-123678-H3CCDD
13C-1234 678-HpCDD
13C-OCDD
PRE-FIBtD SURROSATBS
37C1-2378-ICDD
13C-123478-H»3DD
13C-23478-PeCDF
13C-123478-HXCDF
13C-123478 9-HpCDF
2000
2000
2000
2000
2000
Page 10 of 11
SPIKE
CONG,
47
*
*
*
55
*
*
*
*
2184
-------
-------
Lab Name:
Matrix:
Sample Receipt Date
Ext. Data-
Analysis Date:
Extract Volume (uL):
Injection Volume (uL):
Dilution Factor:
Analyte
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123878-HxCDF
123789-HxCDF
234878-HxCOF
1234678-HpCDF
1234?89-HpCDF
OCDF
Total Tetra-Furans
Total Tetra-Dioxins
Total Penta-Furans
Total Penta-Dioxins
Total Hexa-Furans
Total Hexa-Dioxins
Total Hepta-Furans
Total Hepla-Dioxms
total TEQ
Dattelle
Air
07/21/99
07/28/99
18-Aug-99 Time: 12:40:1 6PM
20
1
1:2
Cone. Detection
Found Limit
pg'sampio pg/sample
418.05 8.46
* *
* *
* *
* *
* *
* *
7629.89 15.74
» • *
* *
* *
It It
* *
* *
*• *
* *
* *
32119.58 22.95
21281,23 88.51
* *
* *
* *
* *
* *
* *
*
PCDD/PCDF ANALYSIS DATA SHEET
Lab Sample ID:
Sample Wt/Vol:
Initial Calibration Date:
Instrument ID:
GC Column ID:
Sample Data Filename:
Blank Data Filename:
Cal. Ver. Data Filename:
TEQ
pg/sample • Labeled Compounds
418.04 13C-2378-TCDF
13C-12378-PeCDF
13C-1 23678
13C-1234678-HpCDF
13C-2378-TCDD
* 13C-12378-PeCDD
13C-123678-HXCDD
762.99 13C-1234678-HpCDD
13C-OCDD
*
*
4
*
*
*
4
*
Pre-Field Surrogates Stds
37CI-2378-TCDD
13C-123478HxCDD
13C-23478-PeCDF
13C-123478-HxCDF
13C-1234789-HpCDF
1181.03
48190-09-03 BH-R3-DIOX
1 units:
04/22/99
AutoSpec
30M DB225
4807887
4807887 #13
4807887 #12
Spike Cone.
Cone. Found
-------
OPOSquan 27-JWJG-1999
Lab Maim: BATTELLE
Matrix: AIR
Sample Receipt Date: 08-07-99
Ext. Date: 08-07-99
Analysis Date; 16-AOG-99 Time
Extract Volume (uL) : 20
Injection Volume (UL) : 1
Dilution Factor: 1:2
ANALYTE
2378-TCDD
12378-EeCDD
123478-HxCDD
123678-HJECDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-EeCDF
23478-PoCOP
123478-HxCDF
123678-HxCDF
123789-HxCDF
234678-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furanc
Total Tetra-Dioxins
Total Penta-Furana
Total Penta-Dioxin*
Total H»jca-Furans
Total Hexa-Dioxina
Total Hepta-Furans
Total nepta-Dioxina
Total TEQ
COMC.
POTTO
pg/dscm
*
4.95
5.73
11.36
15.81
74.05
79.68
617.81
64.58
115 . 66
85.80
31.79
*
45.18
88.48
6.93
29,38
2482.36
698.07
1479.33
185.23
380.84
296.88
121 . 65
193 . 03
Page
19
PCDD/PCDF ANALYSIS DATA SHEET
Lab Sample IDs 48190-09-04 BH-R4-DIOX
Sample Mt/Vol: 1.6750 units: M3
Initial calibration Date: 04-22-99
Instrument ID: Autospec
: 17:46:53 GC Column ID: 60m DBS
Sample Data Filename: 4807886A
Blank Data Filename: 4807886A fl
Cal. Ver. Data Filename: 4807886 12
DETECTION
LIMIT
pg/dscm
3.03
6.09
1.97
1.83
1.20
1.52
0.78
1.89
3.04
2.55
2.33
2.02
2.34
2.26
0.64
3.73
6.42
3.86
5.26
5.16
6.92
4.44
2.97
1.03
6.93
TEQ
*
2.4743
0.5727
1.1359
1.5812
0.7405
0.0797
61.7808
3.2290
57.8300
8,5799
3 .1788
*
4.5181
0.8848
0 . 0693
0.0294
146.6845
LABELED COMPOUNDS
13C-2378-TCDF
13C-12378-PeCDF
13C-123678-H3CCDF
13C-123467B-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HXCDD
13C-1234678-HpCDD
13C-OCDD
PRE-FIKLD SURROGATES
37C1-2378-TCDD
13C-12347B-HXCDD
13C-23478-P6CDF
13C-123478-H3CCDF
13C-1234789-HpCDF
SPIKE
COHC.
(pg)
2000
2000
2000
2000
2000
2000
2000
2000
4000
2000
2000
2000
2000
2000
COHC.
FOTOB
-------
OPOSquan 3O-MJO-1999
Lab Hame: BATTELLE
Matrix: AIR
Sample Receipt Date: 07-23-99
Ext. Date: 07-28-99
Analysis Date: 18-ATO-99 Tina
Extract Volume (uL) : 20
Injection Volume (uL) : 1
Dilution Factors 1:2
COIK.
FO0HD
ANALTTS pg/dscm
2378-TCDD 33.53
12378-PeCDD *
123478-BxCDD *
123678-HxCDD *
1237«»-HxCDD *
1234678-HpCDD *
OCDD .*
2378-TCDF S20.40
12378-teCDF *
23478-PeCDF *
123478-HKH5F *
123878-ttcCDF *
123789-HxCDF *
234S78-HxCDF *
1234678-HpCDF *
1234789-HpCDF *
OCDF *
Total Tetra-Futan* 2595 . 62
Total Tetta-Diojcina 713.44
Total Penta-Fucan* *
Total Panta-Dioxin* *
Total Heaca-Furana *
Total Hejc«-Diojcin» *
Total Hepta-Furana *
Total Bepta-Dioxins *
Sag* 11 .
Page 11 of 11
PCDD/PCDF ANALYSIS DATA SHEET
lab Sample IDs 48190-09-04 BH-R4-DIOX
13:28:15
Sample Wt/Vol: 1.6750
Initial calibration Date:
Instrument ID: AutoSpac
GC Column ID: 30mDB225
units: H3
04-22-99
Sample Data Filename: 4807887
Blank Data Filename: 4807887 f!3
DETECTIOS
LIMIT
pg/dscm
1.27
*
*
*
*
*
*
2.22
*
*
*
it
*
*
*
*
*
3,23
13.33
*
A
*
*
*
*
TEQ
33.5295
*
*
*
*
*
*
52.0396
*
*
*
*
*
*
' *
*
*
Cal. Ver. Data Filename:
UBB1£D COHPOtlKDS
13C-2378-TCDF
13C-12378-PeCDF
13C-123878-HXC0F
13C-1234«78-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HXCOD
13C-1234678-HpCDD
13C-OCDD
PRE-FIELD SOKROGATE3
37C1-2378-TCDD
13C-123478-HXCDD
13C-23478-PeCDF
13C-123478-H3CCDF
13C-1234789-HpCDF
4807887 |12
SPIKE COHC,
COHC . FOUND RECOVERY
(P0 \ fHJt'"'y"*^i o
2000 959 •«« *iOt Jy^ ^gpl*^
2000 * *'t^l9(cis
2000 * *
2000 * *
2000 * *
Total TEQ
85,5691
-------
-fl
u
CO
Lab Name:
Matrix:
Sample Receipt Date
Ext. Date:
Analysis Date:
Extract Volume (uL):
Injection Volume
-------
"71
t
co
•fc.
Lab Name:
Matrix:
Sample Receipt Date
Ext Date:
Analysts Date:
Extract Volume (uL):
Injection Volume (uL):
Dilution Factor;
Analyle
2378-TCDD
12378-PeCDD
123478-HxCDD
123878-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
123789-HxCDF
234678-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tatra-Furans
Total Tetra-Dtoxins
Total Penta-Furans
Total Penta-Dioxins
Total Hexa-Furans
Total Hexa-Dloxlns
Total Hepta-Fyrans
Total Hepta-Dloxins
Total TEQ
Battelle
Air
07/23/99
07/28/9§
18-Aug-99 Time:
20
1
1:2
Cone.
Found
pg/sample
224.65
• •
*
*
*
*
*
. 3486.68
*
«
*
*
*
*
* -
*
-*.
17390.65
4780.05
*
•
*
*
*
* ~
PCDD/PCDF ANALYSIS DATA SHEET
Lab Sample ID:
Sample VWVol:
Initial Calibration Date:
Instrument ID:
1:28:1 5PM GC Column ID:
Sample Data Filename:
Blank Data Filename:
Cal. Ver. Data Filename:
Detection
Limit TEQ
pg/sample pg/sample Labeled Compounds
8.51 224.65 13C-2378-TCDF
13C-12378-PeCDF
13C-1 23678
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
* * 13C-123678-HxCDD
14.87 348.67 13C-1234678-HpCDD
* ' 13C-OCDD
* *
* *
* '*
* *
* *
* *
* *
* *
21.64 Pre-Fleld Surrogates SWs
89.31
* 37CI-2378-TCDD
13C-123478HXCDD
* 13023478-PeCDF
13C~123478-HxCDF
* 13C-1234r89-HpCDF
*
573.31
48190-09-04 BH-R4-DIOX
1 units:
04/22/99
AutoSpec
30m DB225
4807887
4807887 #13
4807887 #12
Spike Cone.
Cone. Found
(PS) (P9)
8000 3972
8000
8000
8000
8000 4464
8000
8000
8000
16000
8000 3836
8000
8000
8000
8000
Recovery
(%)
50
*
*
*
56
*
*
*
*
48
*
*
*
*
-------
F-2-2
EPA Audit Sample
F-35
-------
CO
o>
OPUSquan 27-ADO-1999
Page
14
Page 14 of 20
PCDD/PCBF ANALYSIS DATA. SHEET
Lab Name: BATTELLB Lab Sample ID: 48190-09-08 BH-AUDIT-DIOX
Matrix: AIR Sample Wt/Voli -1.0000 units: M3
3ans>l« Receipt Dat*: 08-07-99 Initial Calibration Date: 04-22-99
Ext. Date: 08-07-99 • Instrument IDs Autospec
Analyaia Date: 16-AUG-99 Tina; 12:16:07 GC Column ID: 60m DBS
Extract Volume (uL) : 20 Sample Data Filename: 4807886A
' Injection Volume |uL) : 1 Blank Data Filename: 4807886& 11
Dilution Factor: HOME Cal. Ver, Data Filename: 48078(6 »2
CONC. DETECTION SPIKE CONC.
FOOND LIMIT TEQ CONC, FOOND RECOVER*
ANALYTE pg/samplo pg/aampla
2378-TCDD
12378-P«CDD
123478-HxCDD
123678-HXCBD
123789-B3CCDD — CWiPC,
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-RxCDF
123678-HxCDF
123789-HJtCDF
234678-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furana
total Tetra-Dioxin*
total Penta-Furans
Total Pflnta-Dioxins
Total Hexa-Furana
total Hexa-Dioxins
total Bapta-Furana
Total Hapta-Dioxins
Total TBQ
126
120
116
134
141
283
325
158
146
141
147
156
132
151
298
238
153
419
303
553
443
905
658
536
438
.07
.30
.39
.33
.02
.30
,24
.00
.53
.91
.13
.18
.27
.01
.02
.18
.73
,19
.35
.67
.03
.08
.48
.20
.66
1
4
1
3.
0
1
0
1
2
1
1
1
1
1
0
2
4
2
3
3
4
3
2
0
s
.88
.14
.50
.40
.92
.22
.70
.16
.04
,71
.79
,56
.80
.74
.64
.84
.89
.36
,26
.47
.70
.42
.26
.79
.53
126
60
11
13
14
2
0
15
7
70
14
15
13
15
2
2
0
386
.0686
.1497
.6391
.4327
,1025
.8330
.3252
.7995
.3265
. 9543
,7128
.6183
.2268
.1010
.9802
,3818
.1537
.8058
LABELED COMPOUNDS
13C-2378-TCD11
13C-12378-PeCDF
13C-123678-HXCDF
13C-1234 678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123 678 -HxCDD
13C-1234678-Hj)CDD
13C-OCDD
PRE-FIELO SBRRO6MES
37C1-2378-TCDD
13C-123478-HXCDD
13C-23478-PeCDF
13C-123478-BXCDF
13C-1234789-HpCDF
(pg)
2000
2000
2000
2000
2000
2000
2000
2000
4000
200O
2000
2000
2000
2000
{pg> (*>
1303 65
1490 75
1193 60
1424 71
1371 69
1617 81
1335 67
1527 76
3005 t5
'\ .
2 0\ \(*$C< \.
* * | fr^*"^ j«JiJ^^
* * / /AJ^'^
* * / j^~^
*/
-------
CO
OPOSquan 30-AUQ-1999
Page 5
PCDD/PCDF ANALYSIS DATA SHEET
Lab Kama: BA.TTELLS * Lab Sample ID: 48190-09-08 BH-ACTDIT-DIOX
Matrix: AIR Sample Kt/Vol: 1.0000 units: ea
Sample Receipt Date: 07-09-99 Initial Calibration Date: 04-22-99
Ext. Date: 07-28-99 Instrument ID: AutoSpec
Analyais Date: 18-ATO3-99 Time: 08:40:23 GC Column ID: 30mDB225
Extract Volume (uL) : 20 Sample Data Filename: 4807887
Injection Volume (uL) : 1 Blank Data Filename: 4807887 113
Dilution Factor: HOME Cal. V«r. Data Filename: 4807887 |12
A1IALYTE
237S-TCDD
12378-PeCDD
123478-RXCDD
123678-HxCDD
12378 9-HxCDD
1234«78-HpCDD
OCDD
2378-3CDF
12378-feCDF
23478-FeCDF
123478-HKCDF
123678-HxCDF
12378 9-HxCDF
234678-HXCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furan»
Total Tetra-Dioxins
Total Penta-Furane
Total Penta-Dioxina
Total Bexa-Furana
Total Hexa-Dioxins
Total H«pta-Furan»
Total B*pta-Dioxin»
Total TEQ
CCWC.
FQOHD
pg/sampls
121. «7
*
*
*
*
*
A
185.41
*
*
*
*
*
*
*
*
*
169.20
305.15
*
*
*
*
*
*
DETECTIOH
LIMIT
pg/sample
0.81
*
*
*
*
*
*
1.37
*
*
*
*
*
*
*
*
*
2.00
8.48
*
TEQ
121.6737
*
*
*
. *
*
*
16.5409
it
*
*
*
*
*
*
*
*
138.2146
LABELED COMPOUNDS
13C-2378-TCDF
13C-12378-PeCDF
130-123678-HxCDF
13G-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HxCDD
13C-1234678-HpCDD
13C-OCDD
PRE-FXELD SURROGATES
37C1-2378-TCDD
13C-123478-HXODD
13C-23478-PBCDF
13C-123478-HXGDF
13C-123 4 78 9-HpCDF
SPIKE
COMC.
(P9)
2000
2000
2000
2000
2000
2000
2000
2000
4000
2000
2000
2000
2000
2000
COMC.
FOOMD
-------
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
? RESEARCH TRIANGLE PARK, NC 27711
1999
OFFICE OF
AIR QUALITY PLANNING
AND STANDARDS
MEMORANDUM
SUBJECT; Results from Method 23 Audit Sample - #23-03 1
FROM: Gary D. McAlister Ct &
Emission Measurement Center (MD- 19)
TO-. Clyde E. Riley
Emission Measurement Center (MD-19)
This letter represents EPA's official evaluation of the Method 23 audit results which were
submitted by Ms. Karen Lesniak of Battelle Memorial Institute Laboratories, Columbus, Ohio,
*The audit sample was originally received by Mr. Tony Wisbith of Battelle on July 9, 1999 and
^analyzed by Battelle August 16, 1999.
In summary, for the reported data, 9 of 1 1 dibenzodioxins are within the 90 percent
confidence limit including the,2378-TCDD isomer . For the dibenzofurans, 1 1 of 14
dibenzofurans are within the 90 percent confidence limit. Battelle documented that confirmation
analysis was performed for the 2378-TCDF isomer. The reported data meet the acceptable
performance limits for the target analytes. For additional information, please see the enclosed
USEPA Dioxin/Furan Audit Form. If you have any questions, please contact me at (919)
541-1062.
Attachment
F-38
Internet Addnsss (URL)« HBp:/Awww.apa.gov
R*cycl*d/R«cycl*bl* • Printed with Vegetable OB Based Inks on Recycled Paper (Minimum 25% Pos
-------
US EPA DIOXIN/FURAN AUDIT FORM
Auditor:
Agency;
Agency Address:
Agency Phone #:
Audit Sample #:
Date Analyzed;
Clyde E (Gene) Riley
EMAD, OAQPS, EPA
MD19
RTF, NC 27711
(919)541-5239
M23-031
8/16/99
Auditee Company;
Auditee's Name:
Auditee Address:
Date Audit Sam Rec'd:
Confirmation Analysis Used;
Battelle Memorial Institute
Karen Lesniak
505 King Ave
Columbus, OH 43201-2693
7/9/99
Yes
Compound
2378-TCOD
Other TCDD
12378-PeCDD
Other PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
Other HxCDD
1234678-HpCDD
Other HpCDD
OCDD
Auditee Result
(ng/sample)
0.504
7.09
0.481
1.291
,_ 0.466
0.537
0.564
1.067
1.133
0.622
1.301
Compound
2378-TCDF
Other TCDF
12378-PCDF
23478-PCDF
Other PCDF
123478-HxCDF
123678-HxCDF
123789-HxCDF
234678-HxCDF
Other HxCDF
1234678-HpCDF
1234789-HpCDF
Other HpCDF
OCDF
Auditee Result
(ng/sample)
0.662
1.015
0.586
0.568
1.061
0.589
0.625
0.529
0.604
1.274
1.192
O.i53
0
0.615
The results of the above performance audit sample will be calculated as follows:
Results of the Polychlorinated Dibenzodioxins (CDD):
9 of the 11 different CDD are within the 90% confidence
10 of the 11 different CDD are within the 50% of the 90% confidence
Results of the Polychlorinated Dibenzofurans (CDF):
11 of the 14 different CDF are within the 90% confidence
13 of the 14 different CDF are within the 50% of the 90% confidence
F-39
-------
F-2-3
Sewage Sludge
F-40
-------
This page intentionally blank
F-41
-------
OPUSquan 27-AUS-1999
Lab (lain*: BATTBLLE
Matrix! WATER
Sample Receipt Date: 07-21-99
Ext. Date: 08-08-99
Analyaia Datei 15-AUO-99 Timei
Extract Volume (uL) i 20
Injection Volume (uL) i 1
Dilution Factor: NONE
Concentration Unite: pg/g dry
UNALYTE
2378-ICDD
12378-**CDD
123478-HxCDD
123678-BSCDD - ' .
123789-BXCDD
1234678-HpGBD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
12S678-HJCCDF
123789-HxCDF
234678-HxCDF
1234678-HpCDF
1234789-BpCDF
OCDE
total Tetra-Furana
total Tetra-Dioxina
Total P«nta-Furan«
Total Penta-Dioxina
Total Hexa-Furana
Total B«xa-Dioxin«
Total Bepta-Furana
Total Hepta-Dioxina
Total 1EQ
COMC,
FOUND
*
*
? *
15.034
27.278
229.242
2510. 045
27.«72
*
8.089
13.703
*
*
6.211
134.485
*
313.466
76.483
67,723
90.162
30.287
97.680
128.323
238. 639
430.793
Page
10
PCDD/FCDF ANALYSIS DATA SHEET
Lab Sample ID: 48190-15-02 S-R2-213A
Sample Wt/Vol: 0,2665 unit*! L
Initial Calibration Date: 02-08-99
Instrument ID : AutoSpee
05 131:45 QC Column ID: 60m DBS
Sample Data Filenames 4S07885&
Blank Data Filename: 4807885A fl
Cal. Ver. Data Filename: 480788S fl
Concentration Onita (pg)
DETECIIOM
•LIMIT
4.853
15.018
4.714
5.292
4.935
10.539
6.195
4.346
7.751
3.545
5.2«?
5.043
5.878
5.089
2.890
11.665
14.915
10.260
11.039
13.411
25.172
19.543
11.179
3.476
31.677
ION
RATIO
*
*
*
1.16
1.06
1.02
0.85
0.80
*
1.51
1.24
*
*
1.23
0.98
*
0.90
0.72
0.80
1.58
1.30
1.36
1.12
0.98
0.99
TEQ
*
*
A
1.5034
2.7278
2.2924
2,5100
2.7672
*
4,0444
1.3703
*
*
0.6211
1.3449
*
0.3135
19.49»
LABELED COMPOUNDS
13C-2378-TCDD
13C-12378-P«CDD
13C-123478-HXCDD
13C-123678-BXGDD
1,301234678-BpCDD
13C-OCDD
13C-2378-TCDF
13C-12378-PeCDF
13C-23478-P«CDF
13C-123478-HXCDF
13C- 123 £7 B-H»,CDr
13C-123789-BXCD*
13C-234678-BXCDF
13C-1234678-HpCDF
13C-1234789-HpCDF
CLEANUP STANDARD
37C1-2378-TCDD '
SPIKB
CONG.
2000
2000
2000
2000
2000
4000
2000
2000
2000
2000
2000 •
2000
2000
2000
2000
200
COMC.
FOUHD
1469
1596
14C7
1550
1374
2468
1271
1517
1443
1414
1457
1361
1489
1332
1202
121
Page
R<%)
73
80
73
77
69
62
i4
76
72
71
73
68
74
67
60
61
10 of 15
3OH
RATIO
0.78
1.55
1.24
1.25
1.03
0.88
0.76
1.55
1.53
0.52
0.50
0.51
0.52
0.44
0.44
-------
OPDSquan 27-AWO-1999
Page 11
Page 11 of 15
PCDD/PCDF ANALYSIS DATA SHEET
Lab Nairn: BATTBLLB
Matrix: WATER
Sample Receipt Data: 07-21-99
Ext. Data: 08-08-99
Analyaia Datai 15-AUG-99 Time: 06:37:49
Extract Volume (ul<) : 20
Injection Volume (uL): 1
Dilution Factor: NONE
Concentration Unit*: pg/g dry
ANALrtB
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-taCDD * '
123789-HXCDD
1234678-HpCDD
OCDD
2378-TCDP
12378-PeCDF
23478-PeCDF
123478-HscCDF
123678-HxGDF
123789-BxCDF
234678-BxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furana
Total Tetra-Dioxina
Total Penta-Furana
Total Penta-Dioxina
Total Hexa-Furana
Total Bexa-Dioxina
Total Bepta-Furana
Total Bepta-Dioxina
CONG.
FOUND
*
*
? *
17.940
24.345
281.146
2687.554
29.950
*
9.207
19.302
7.512
*
8.433
159.218
*
339.723
95.881
82.584
95.195
23.349
117.436
134.831
283.917
520.175
DETECTION
LIMIT
5.392
17.029
5.402
5.971
5.618
11.927
6.779
4.661
8.480
3.752
5.855
5.565
6.644
5.781
3.222
12.624
16.322
11.004
12.264
14.442
28.544
21.896
12.726
3.812
35.849
ION
RATIO
*
*
*
1.30
1.19
1.03
0.89
0.70
*
1.40
1.2?
1.31
* <
1.24
1.02
*
0.88
0.71
0.80
1.51
1.53
1.08
1.23
1.02
0.93
TKQ
*
*
*
1.7940
2.4345
2.8115
2.6876
2.9950
*
4.6035
1.9302
0.7512
*
0.8433
1.5922
*
0.3397
Total TBQ
Lab Sample ID: 48190-15-03 S-R3-313A
Sample Wt/Vol: 0.2316 unita: L
Initial Calibration Date: 02-08-99
Instrument ID: AutoSpec
GC Column ID: 60m DBS
Sample Data Filename: 4807885A
Blank Data Filename: 4807885A #1
Cal. Ver. Data Filename: 4807885 41
Concentration Units (pg)
LABELED COMPOUNDS
13C-2378-TCDD
13C-12376-PeCDD
13C-123478-HXCDD
13C-123678-HXCDD
13C-1234678-HpCDD
13C-OCDD
13C-2378-TCDF
13C-12378-PeCDF
13C-23478-POCDF
13C-123478-HXCDF
13C-123678-HXCDF
130-123789-HxCDF
13C-234678-HXCDF
13C-1234£78-BpCDF
13C-1234789-HpCDF
CLEANUP STANDARD
37C1-2378-TCDD
22.78»
SPIKE
CONC.
2000
2000
2000
2000
2000
4000
2000
2000
2000
2000
2000
2000
2000
2000
2000
CONC.
FOUND
1623
1742
1589
1577
1435
2716
1447
1675
1635
1512
1543
1440
1535
1415
1257
R(%)
81
87
79
79
72
68
72
84
82
76
77
72
77
71
63
ION
RATIO
0.77
1.54
1.25
1.25
1.02
0.88
0.76
1.55
1.55
0.51
0.51
0.51
0.51
0.44
0.45
200
131
65
y
-------
OPOSqunn 27-AUQ-1999
P«g» 12
Page 12 of 15
PCDD/PCDF ANALYSIS DATA SHEET
Lab Naawi BMTELLB
Matrix: MUTER
Sanpl* Receipt Data: 07-23-99
EKt. Data: 08-08-99
An«lyfll« Dat«: 1S-A0Q-99 Time: 07:43:55
Extract Volume (uL) : 20
Injection Volume (uL): 1
Dilution Factor: NOHB
Concentration Unite pg/g dry
AHAMTTK
2378-TCDD
12378-PsCDD
123478-HxCDD
123678-H3CCDD * '
123789-HxCDD
1234678-HpCBD
OCDD
2378-IOBF
12378-PeCDF
23478-SeCDF
123478-HrCDF
12367t-HXCDF
123789-RXCDF
234678-BxCDF
123467«-HpCDF
1234789-HpCDF
OCDF
Total T«tra-Furan«
Total Tatra-Dioxina
Total P«nta-Fur«n«
Total fenta-Dioatina
Total B«3ta-ruran»
Total B«xa-Dioxina
I Total Rnpt*-Fur«n»
| Total Hepta-Dioxins
COHC.
FOUND
*
*
'8.237
30.717
39,949
383.542
3689.092
38.620
12.749
13.427
29.630
10.008
*
13.309
222.0S£
*
441.203
120,041
95.069
162.687
29.574
170.701
203.750
376.603
701.939
DETECTION
LIMIT
5.327
17.356
5.420
6.167
5.715
11.915
6.465
4.995
8.562
4.078
5.758
5.681
6.993
5.611
3.279
13.024
15.567
11,791
12,117
15.096
29.091
22.004
12 . 945
3,910
35.813
IOH
RATIO
*
*
1.19
1.40
1.09
1.11
0.87
0.75
1.45
1.38
1.32
1.26 >
*
1.24
1.02
*
0.88
0.69
0.81
1.46
1.58
1.27
1.15
1,02
1,12
TEQ
*
*
0.8237
3.0717
3,9949
3 . 8354
3,6691
3.8620
0.6375
6.7136
2.9S30
1.0008
*
1.3309
2.2209
*
0.4412
Lab Sample ID: 48190-15-04 S-R4-413A
Sample Ht/Vol: 0,2326 unit*: L
Initial Calibration Data: 02-08-99
Instrument ID: AutoSpec
GC Column ID: 60m DBS
Sample Data Filename: 4807885A
Blank Data Filename: 4807885A II
Cal. Vet. Data ?ilonanra: 4807885 fl
Concentration Units (jxj)
LABELED COMPOUNDS
13O-2378-TGDD
13C-12378-t«CDD
13C-123478-HXCDD
13C-123678-HXCDD
13C-1234678-HpCDD
13C-OCDD
13C-2378-ICDF
13C-1237B-S«CDP
13C-23 478-P«CDF
130-123478-HxCDF
13S-123S78-HXCDF
13C-1237B9-HxCDF
13C-234678-HxCa)F
13C-123467B-HpCDF
13C-1234789-HpCDF
CLEANUP STAKDARD
37C1-2378-TODD
SPIKE
CONC.
2000
2000
2000
2000
2000
4000
2000
2000
2000
2000
2000
2000
2000
2000
2000
COKC.
FOUND
1642
1698
1571
1646
1474
2900
1351
1669
1531
1562
1589
1449
1609
1440
12B9
R(%)
82
85
79
82
74
72
68
83
77
78
79
72
80
72
64
IOM
RATIO
0.77
1.54
1.22
1.23
1.04
0.87
0.76
1.55
1.55
0.53
0.51
0.50
0.52
0.45
0.44
200
134
67
lotal TEQ
34,56»
-------
OPOSqu*n 30-AU3-1999
Page 5
01
2CDD/PCDF ANALYSIS DATA SHEET
Lab Name: BATTBLL8
Matrix: SLUDSS
Sample Receipt Dates 07-21-99
Bxt. Date: 08-08-99
Analyaia Date: 18-A0O-99 Tine: 00:40:37
Extract Volume (uL): 20
Injection Volume («L): 1
Dilution Factor: NONE
Concentration Unites pg/g dry
Lab Sample ID: 48190-15-02 S-R2-213A
Sample Ht/Vol: 0.2665 unit.: g
Initial Calibration Data: 02-08-99
Inatrtunant ID: Autoapec
GC Column ID: 30mDB225
Sample Data Filename: 4807887
Blank Data Filename: 4807887 *3
Cal. V«r. Data Filename: 4807887 |2
Concentration Dnita (pg)
Total TEQ
4.8058
Page 5 of 7
AHALriE
2378-TCDD
12378-P«CDD
123478-HXCBD
123678-axCDD
12378 9-HXCDD
1234678-HpCDD
OCDD
2378-TCBF
12378-teCDF
23478-PaCDF
12S47«-H*GDF
12367«-HxCDF
12378 9-HzCDF
234678-BxCDF
1234678-HpCDF
1234789-BpCDF
OCDF
Total Tetra-Furana
Total Tetra-Dioiina
Total P«nta-Furan»
Total Penta-Dioxina
Total Haxa-Furana
Total H«ra-Dioxin«
Total Hepta-Furana
Total Hepta-Dioxina
COHC .
FOUND
2.751
*
*
*
*
*
*
20.553
it
*
*
4
*
*
*
.*
• *
61.246
67.476
DETECTION
LIMIT
14.556
*
*
*
*
#
*
3.309
*
*
*
*
*
*
*
*
*
10.403
2920.794
*
*
*
*
*
*
ION
RATIO
0.68
*
*
*
*
*
*
0.76
*
*
*
*
*
*
*
*
*
0.74
0.78
*
*
*
*
*
*
TEQ
2.7506
*
*
*
*
*
*
2.0553
*
*
*
*
*
*
*
*
*
LABELED COMPOUNDS
13C-2378-TCDD
13C-12378-PeCDD
13C- 123 4 78 -HxCDD
13C-123 678-HxCDD
13C- 123 467 8-HpCDD
13C-OCDD
13C-2378-TCDF
13C-12378-PeCDF
130-23478-PeCBF
13C-123478-HXCDF
13C-123S78-H3CCDF
13C-123789-HXCDF
13C-234678-BXCDF
13C-123467fi-BpCDF
13C-1234789-HpCDF
CLEANUP STANDARD
37C1-2378-TCDD
SPIKE
CONC.
2000
2000
2000
2000
2000
4000
2000
2000
2000
2000
2000
2000
2000
2000
2000
200
cone.
FOUND R
1469 7:
*
*
*
*
*
1392 7
*
*
*
*
*
*
*
*
124 6S
ION
%) RATIO
> 0.80
*
*
*
A
*
0.80
*
«
*
*
*
*
*
*
-------
OPOBquan 30-AUQ-1999
Page *
Pag* 6 of 7
PCDD/PCDF ANALYSIS DATA SHEET
Lab HUM: BATTELLB
Matrix! SLO1X3B
Sample Receipt Date; 07-21-99
Brt. Date: 08-08-99
Analyai* Date; 18-AOQ-99 Tiros: 01:28:3$
Extract Volume (uL): 20
Injection Volume (uL) t 1
Dilution factori HOME
Concentration Units; pg/g dry
Lab Sample ID: 48190-15-03 S-R3-313A
Sample Ht/Vol: 0.2316 unit*: g
Initial calibration Date: 02-08-99
Inatrumsnt ID: jkutoapac
GC Column ID: 30mDB225
Sample Data Filename: 4807887
Blank Data Filename: 4807887 13
Cal. V.IT. Data Filenames 4807887 12
Concentration Unit* (pg)
T1
0>
UtUiTTB
. 2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCTD
1234678-BpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478^BxCDr
129C78-HXCDF
123789-BxCDF
234678-HrCDF
1234678-HpCDF
1234789-HpCDF
OCDV
Total Tetra-Furana
Total Tetra-Dioxin»
Total tenta-Furana
Total Venta-Dioxin*
Total H«xa-Furan»
Total Hexa-Dioxina
Total Bepta-Furan*
Total Hepta-Dioxlna
CONG.
Fomro
2.871
24.0«4
*
*
*
60,282
80.217
*
*
*
*
*
*
DETECTION
LIMIT
15.580
*
*
*
*
*
*
3.475
*
*
» -
*
*
*
*
*
* *
10.924
3126.236
ICM
RATIO
0.72
*
*
*
*
*
*
0.77
*
*
*
*
*
*
*
*
*
0.67 .
0.82
*
*
*
• *
*
*
TEQ
2.8705
*
*
*
*
*
*
2.4064
*
*
*
*
*
*
*
• *
*
LABELED COMPOUNDS
13C-2378-TCDD
13C-12378-FeCDD
13C-123478-HXCDO
13C-123678-BZCDD
1301234678-HpCDD
13C-OCDD
13C-2378-TO3F
13C-12378-teCTF
13C-23478-PBCDF
13G-123478-B3CCBF
13O-123678-HXCDF
130-123789-HxCD?
13C-234678-HZCDF
13C-1234 678-HpCDF
13C-1234789-HpCOF
CLEAHtJP STANDARD
37C1-2378-TCDD
SPIKB COHC.
CONG. FOOMD R(%)
2000 1S89 79
2000
2000
2000
2000
4000
2000 1S4
2000
2000
2000
2000
2000
2000
2000
*
*
*
*
*
77
*
*
*
*
*
*
*
2000 *
200 133 67
IOM
RATIO
0.79
*
*
0.79
Total TBQ
5.2759
-------
OP08quan 30-AUC3-1999
P«g« 7
PCDD/PCDF ANALYSIS DA1A SHEK7
Lab Mama: BATTELLB
Matrix: SLtTDCK
Simple Receipt Data: 07-23-99
Ext, Date: 08-08-99
Analy«i« Date: 18-AUQ-99 Tine: 02:16:37
Extract Volume (uL): 20
Injection Volume (uL.) : 1
Dilution Factor: NONE
Concentration Onits: pg/g dry
Lab Sample ID: 48190-15-04 S-R4-413H
Sample Wt/Vol: 0.2326 unit*: g
Initial Calibration Data: 02-08-99
Instrument ID: Antoapec
GC Column ID: 30nDB225
Sample Data Filename: 4807867
Blank Data Filename: 4807887 |3
Cal. Vfsr. Data. Filename: 4807887 |2
Concentration Bnits (pgr)
Total TSQ
8.6443
Page 7 of 7
AKALYTE
2378-TCDD
12378-PeCDD
123478-HXCDD
123678-HxCDD
123789-HxCDD
1234678-BpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-BxCDF
123678-HzCDF
123789-HxCDF
234678-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF" ...
Total Tetra-Furana
Total Tatra-Dioxini
Total Panta-Fucaoa
Total Penta-Dioxin*
Total Hexa-Furana
Total Bexa-Dioxina
Total Hepta-Furan«
Total Hepta-Dioxin*
CONC.
FOUND
5.139
*
*
*
*
*
*
35.056
*
*
*
*
*
*
*
*
*
109,289
30.725
*
*
*
*
*
*
DETECTION
LIMIT
14.492
*
*
*
*
*
*
3,564
*
*
*
*
*
*
*
*
*
11.205
2908.012
*
*
*
*
*
*
ION
RATIO
0,74
*
*
*
*
*
(*
0.72
*
*
*
*
*
*
*
*
*
0.75
0.82
TEQ
5.1387
*
*
*
*
*
*
3,5056
*
*
*
*
*
*
*
*
*
LABELED COMPOUNDS
13C-2378-TCDD
13C-12378-P«ODD
13C-123478-H3CCDD
13C-12367i-HxCDD
13C-1234678-HpCDD
13O-OCDD
13C-2378-TCDF
130-12378 -faCDF
13C-23478-P«CDF
19C-123478-HJCCDF
13G-123f78-tttCDF
13C-123789-HJCCDF
13C-23 467 8-HXCDF
13C-1234678-HpCDF
13C-1234789-BpCDF
CLEANUP STANDARD
37C1-2378-TCDD
9PIKS CONC.
CONC. POUND R(%)
2000 1604 80
2000
2000
2000
2000
4000
2000 141
2000
2000
2000
2000
2000
2000
2000
*
*
*
*
*
71
*
*
*
*
*
*
*
2000 *
200 137 68
IOH
RATIO
0.79
*
*
*
*
*
0.78
*
*
*
*
*
*
*
*
-------
F-2-4
Scrubber Water Inlet
F-48
-------
OPDSquan 27-ABO-1999
Page 15
PCDD/PCDF ANALYSIS DATA SHEET
Lab Mane: BATTELLE ' Lab Sample ID: 48200-57-02 WI-R2-211A
Matrix! MATER Sample Wt/Vol; 1.0000 units: L
Sample Receipt Date: 07-21-99 Initial Calibration Date: 02-08-99
Ext. Dat*: 07-29-99 Inatrument ID: AutoSpec
Analyai* Date: 15-A.US-99 Tine: 13:50:51 <3C Column ID: 60m DBS
Extract Volume (uL) : 20 Sample Data Filename: 4807885B
Injection Volume (UL) : 1 Blank Data Filename: 4807 8 B5A fl
Dilution Factor: 1:5 Cal. Ver. Data Filename: 4807885 fl
Concentration Unit*: pg/L
AHALTTE
2378-TCDD
12378-teCDD
123478-BxCDB
123678-HxCDD * '
123789-HxCDD
1234678-BpCDD
OCDD
2378-TCDF
12378-PeCOF
23478-PeCDF
123478-HxCDF
123678-HxGDF
123789-HxCDF
234678-BxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furan»
Total Xetra-Dioxlna
Total Penta-Furan*
Total Panta-Dioxin*
Total B*za,-Purana
Total B*xa-Dioxln>
Total Hepta-Furana
Total Bepta-Dioxlna
Total TEQ
COMC.
FOUND
*
*
! *
*
: *
*
40.146
*
*
*
*
*
*
*
*
*
*
91.7SO
*
*
*
*
*
*
*
DETECTION
LIMIT
12. 603
27.354
12.703
13.459
12.893
32.831
19.376
9.492
11 , 656
11.090
14.409
12. £98
17.486
14.150
9.313
35,004
46.654
22.408
28 . 667
35.495
45.850
53.368
29.20*
79.065
98.682
ION
RATIO
*
*
*
*
*
*
0.79
*
*
*
*
*
* •
*
*
*
*
0.8S
*
*
*
*
*
*
*
Pag* 15 of 15
Concentration On it* (pg)
TEQ
*
*
*
*
A
#
0.0401
*
*
*
*
*
*
*
*
*
*
0.0401
LABELED COMPOUNDS
13C-2378-TCDD
13C-12378-P*CDD
13C-12347B-HXCDD
13C-12367B-HXCDD
13C-1234678-HJ1CDD
13C-OCDD
13C-2378-TCDF
13C-1237B-POCDF
13C-23478-P*CDF
13C-123478-HXCDF
13C-123678-BXCDF
13C-123789-ffitCDF
13C-234678-HXCDF
13C-1234678-B|»CDF
13C-1234789-BpCDF
CLEANUP STANDARD
37C1-2378-TCDD
SPIKE
CONC.
2000
2000
2000
2000
2000
4000
2000
2000
2000
2000
2000
2000
2000
2000
2000
200
COHC.
FOUND
1176
1483
1068
1160
860
1538
1222
1197
959
1007
1095
91S
1029
818
763
121
R(%)
59
74
53
58
43
SBv^
61
60
48
50
55
46
51
41
3B\T
60
IOH
RATIO
0.78
1.58
1.35
1.13
1.03
0.89
0.79
1,50
1.56
0.52
0.53
0.52
0.50
0.44
0.43
-------
opostjuan 27-AOO-1999
P»g« 3
at-'
a
Pag« 3 of 15
PCDD/PCDF ANALYSTS DATA SHEET
Lab Mama; BATTELLB
Matrix: WATER
Sample Receipt Date: 07-21-99
Ext. Date: 07-29-99
Analyaia Date: H-AUO-99 Time: 20:43:21
Extract Volume (uL) : 20
Injection Volume (nL): 1
Dilution Factor: MONS
Concentration Units: pg/L
ANALYTE
2378-TCDD
12378-PeCDD
123478-BxCDD
123678-HxCDD * '
123789-HXCDD
1234678-BpCDD
OCDD
2378-ICW
12378-FeCDF
23478-EeCDF
123478-BxCDF
123678-HxCDS'
123789-HxCDF
234678-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total T«tra-Furan«
Total T»tra-Dloxina
Total. Fenta-Furana
Total Penta-Dioxin*
Total Hexa-rurana
Total Hexa-Dioxlna
Total Hepta-Farana
Total Hopta-Dioaeina
CONC.
FOUND
*
*
T *
*
*
*
11.713
*.
*
*
*
*
*
*
1.365
*
*
1.191
1.723
• *
*
*
*
3.708
*
DETE
LI
2
7
2
2
2
4
2
2
3
1
' 2
2
2
2
1
4
5
4
5
£
11
2
4
10
12
CJIOM
MIT
.587
.055
.060
.216
.105
.315
.439
.067
.788
.581
.294
.251
.503
.257
.210
.723
.872
.879
.885
.272
.824
.259
.767
.453
.971
IOH
RATIO
*
*
*
* •
• *
*
0.79
*
*
*
*
*
*
*
0.91
*
*
0.82
0.74
*
TEQ.
*
*
*
*
*
*
0.0117
*
*
*
*
*
*
*
0.0136
*
*
Lab Sample ID: 48200-57-04 WI-R3-311A
Sample Ht/Vol: 1,0000 unite: L
Initial calibration Data: 02-08-99
Inetrumant ID: Auto«pec
SC Column ID: 60m DBS
Sample Data Filename; 4807885A
Blank Data Filename: 4807885A fl
Cal. vac. Data Filename: 480788S fl
Concentration Unite (pg)
LABELED COMBOTTHDS
13C-2378-TCDD
13C-123 7 8-»eCDD
13C-123478-HXCBD
13C-123678-H3ICDD
13C-1234678-HpCDD
13C-OCDD
13C-2378-IC3>F
13C-12378-PeCDF
13C-23478-teCDF
13C-123478-HXCDF
13C-123S78-HXCDF
13C-12378 9-ExCDl1
13C-234678 - RicCDF
1301234678-HpGDF
13C-1234789-BpCDF
CLRANUP STANDARD
37C1-2378-TCDD
SPIKE
CONC.
2000
2000
2000
20OO
2000
4000
2000
2000
2000
2000
2000
2000
2000
2000
2000
CO»C.
FODKD
S70
792
£98
797
725
1312
633
720
7S«
£90
717
703
713
£80
£23
R(%»
33S
40
35 v
40
36^-
33 •
32**
3£v*
38^
35V
3fi^
35^
36 rf"
34^<
31 -"
IOH
RATIO
0.79
1.53
1.22
1.24
1.05
0.88
0.77
l.Sfi
1.55
0.51
0.51
0.51
0.51
0.45
0.43
200
132
£6
Total TKO
0.0254
-------
Ol
OPnEqu.n 27-AUQ-1999
Page 5
PCDD/PCDF ANALYSIS DATA SHEET
Lab Name: BATTELLE Lab Sample ID: 48200-57-06 WT-R4-411A
Matrix ; MUTER Samp la Ht/vol: 1.0000 unit*: L
Sample Receipt Date: 07-23-99 Initial Calibration Date: 02-08-99
Ext. Date: 07-29-99 Instrument ID: Autoopec
Analysis Date: H- ADO- 9 9 Tine: 22:55:25 GC Column ID: 60m DBS
Extract Volume (uL) : 20 Sample Data Filename: 4807885&.
Injection Volume (uL) : 1 Blank Data Filename: 48078S5A fl
Dilution Factor: HONE Cal. Var. Data Filename: 4807885 fl
Concentration Units: pg/L
ANALTtTE
2378-TCDD
12378-J«CDD
123478-BxCDD
123678-HxCDD ' '
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCD?
23478-PeCOT
123478-HxCDF
123618-HxCDF
123789-HxCDF
234678-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tetra-FTiran«
Total Tetra-Dioxins
Total Penta-Furana
Total Penta-DioKin*
Total Hex»-rur»n«
total Dexa-Dioxlna
Total Hepta-Fnrana
Total Bepta-Dloaina
Total TEQ
COHC.
pomro
*
ft
* ft
ft
ft
ft
15 . 696
*
*
ft
*
*
it
*
*
*
*
*
#
*
*
*
*
2.928
*
DETECT ION
LIMIT
7.658
23,154
6.093
6.488
6.186
12.210
6.562
£.334
11.434
5.023
6.419
6.172
7,697
6.771
3.354
13.514
15,799
14.952
17 . 420
19,408
38,810
24.782
14,012
29.426
36.699
IOH
RATIO
*
*
ft
*
*
*
0.78
ft
*
*
*
*
*
ft
ft
*
*
*
*
*
*
*
ft
*
ft
Concentration Units (pg)
TEQ LABELED COMPOUNDS
* 13C-2378-TCDD
* 13C-12378-P«CDD
* 13C-123478-HXCDD
130123678-HxCDD
13C-1234 678-HpCDD
13C-OCDD
0.015 13C-2378-TCD1'
130-12378-PeCDF
130-23476-PeCDF
13C-123478-H3tCDF
13C-123678-HXCDF
13C-123789-HXCDF
13C-234678-HXCD!1
13C-123 4678 -npCD?
* 13C-1234789-HpCDF
*
*
CLEANUP STANDARD
37C1-237B-TCDD
0.0157
8PZXE
COHC.
2000
2000
2000
2000
2000
4000
2000
2000
2000
2000
2000
2000
2000
2000
2000
200
Page 5 of 15
COHC.
FOUHD R(%)
714 36^
802 40
773 39 *"
902 45
830 41
1581 40
666 33 *-
761 38«^
753 38 •
788 39^
862 42
76i 38 S
793 40
798 40
725 36 •
140 70
TOM
RATIO
0,80
1.56
1.25
1.27
1.05
0.87
0.75
1.56
1.56
0.50
0.53
0.49
0.50
0.41
0.45
-------
F-2-5
Scrubber Water Outlet
F-52
-------
OPUStjuan 27-AOG-1999
Page 2
Vmg» 2 of 15
PCDD/PCDF ANALYSIS DATA SHEET
Lab Hums: BATTELLK
Matrix: HATER
Sample Receipt Oat*: 07-21-99
Ext. Data: 07-29-99
Analyaia Data: 14-AUG-99 Time: 19:37:14
Extract Volume (uL): 20
Injection Volume (uL) : 1
Dilution Factor: HOME
Concentration Units: pg/L
ANALYTB
2378-TCDD
12378-F«CDD
123478-HxCDD
123678-HxCOD * '
123789-HXCDD
1234678-BpCDD
OCDD
2378-TCDF
12378-P«CDJF
23478-F«CDF
123478-HxCDP
123678-HxCDF '
123789-BBtCDF
234678-HacCDF
' 1234678-BpCDF
1234789-HpCDF
OCDF " •..
Total Tetra-Furana
Total T»tra~Dioxin»
Total Penta-Furans
Total Penta-Dioxin»
Total H»xa-Furane
Total Heaca-Dioxlna
Total Hepta-Furana
Total Hepta-Dioxin»
COHC.
FOOMB
*
*
•"J..477
2.823
2.781
11.004
29.490
209.868
14.289
29.413
11 .458
4.558
*
6.229
12.400
*
6.194
824.161
475.310
317.554
46.427
48.103
29.479
17.305
27.438
DETECTION
LIMIT
1.746
4.937
1.468
1.674
1.550
3.085
1.699
1.374
2.599
1.117
1.'640
1.591
1.765
1.591
0.884
3.244
4.091
3.244
3.972
4.366
8.276
6.088
1.537
1.019
9.274
IOH
RASIO
*
*
1.30
1.38
1.17
1.00
0.8«
0.77
1.59
1.58
1.22
1.28
»
1.24
1.02
*
0.89
0.72
0.77
1.56
1.54
1.19
1.30
1.02
0.9C
TBQ
*
*
0.1477
0.2823
0.2781
0.1100
0.0295
20.98*
0.7144
14.70*
1.1458
0.4558
*
0.6229
0.1240
*
0 . 0062
Total TEQ
Lab Sample ID: 48200-57-03 WO-R2-212A
Sample Wt/Vol: 1.0000 unit»: I,
Initial Calibration Date: 02-08-99
Instrument: ID: Auto spec
GC Column ID: 60m DBS
Sample Data Filename: 4807885A
Blank Data Filename: 4807B85& fl
Cal. Ver. Data Filename: 4B078B5 |1
Concentration Units (pg)
LABELED COMPOUNDS
13C-2378-TCDD
13C-12378-F»CDD
13C-123478-HJCCDD
13C-123678-HXCDD
13C-1234678-HpCDD
13C-OCDD
13C-2378-ICDF
13C-12378-E«CDF
13C-23478-P*CBF
13C-123478-H3CCDF
13C-123678-HSCDF
13C-123l89-ttcCDF
13C-234 678-HXCDF
13C-123467B-HpCDF
13C-1234789-HpCDF
CLEANUP STANDARD
37C1-2378-TCDD 200
39.61*
SPIKE
COHC.
2000
2000
2OOO
2000
2000
4000
2000
2000
2000
2000
2000
2000
2OOO
2000
2000
COHC.
FOUND
1016
1216
1103
11O7
1064
2044
981
1104
1122
1017
1059
1071
1051
1013
976
R(%)
51
61
55
55
53
51
49
55
56
51
53
54
53
51
49
IOH
RATIO
0.80
1.S5
1.25
1.24
1.04
0.88
0.77
1.53
1.57
0.52
0.51
0.52
0.52
0.45
0.44
127
63
IV
-------
Tl
OTOSquan 27-AOO-1999
Lab Ham*: BATTSLLK
Matrix: WATER
Sample Receipt Data: 07-21-99
Ixt. Dat«! 07-29-99
Analyaia Date: 14 -ADO- 9 9 Tina:
Extract Voluroe (til,) i 20
Injection Volume (uL) : 1
Dilution Factor: HONE
Concentration Onit«: pg/L
AMAIiTXS
2378-TCDD
12378-EeCDD
123478-HxCDD
123678-HXCDD * '
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
t23478-BxCDF
123678-HxCDF
12378 9-HxCDF
234678-HxCDF
1234678-HpCDF
1234789-BpCDF
OCDF
Total Tetra-Furani
Total T*tra-Dioxin*
Total Penta-Furana
Total Panta-Dioxina
Total Bexa-Furana
Total Baxa-Dioxini
Total Hapta-Fnran*
Total Hepta-Dioxin*
Total TBQ
GCWe.
F00ND
f
24,567
58.692
272.660
24.494
45.403
16.429
£.655
*
12.829
19.642
*
10.396
1120.036
820.823
493.077
57.2(4
80.161
53.507
28.854
52.930
Pago
4
PCDD/PCDF ANALYSIS DATA SHEET
Lab Saiti>le ID: 48200-S7-05 WO-R3-312A
Sareplo Wt/Vol: 1.0000 unit*: L
Initial calibration Data: 02-08-99
Instrument ID : Autoapnc
21:49:22 SC Column ID: 60m DBS
Sample Data Filename: 4807885A,
Blank: Data Filename ; 4807885A fl
Cal. Ver. Data Filename: 4807885 *1
Concentration Dnita (pg)
DETECTION
LIMIT
4.378
13 . 130
3.896
4 . 022
3.893
7.548
4.312
3.199
6.817
2.925
4.201
4.107
4.827
4.257
2.285
8.331
10.381
7.552
9.958
11.440
22.008
16.021
8.818
2.623
22.687
ION
RATIO
*
*
*
*
*
0.99
1.00
0.73
1.41
1.61
1.22
1.10
*
1.34
1.13
*
0.98
0.66
0.77
1.41
1.57
1.30
1.06
1.13
*
TEO
0.2457
0.0587
27.26»
1.2247
22.70.
1.6429
0.6655
*
1.2829
0.1964
*
0.0104
55.29»
LABELED COMPOUNDS
13C-2378-TCDD
13C-12378-P»CDD
130-123478-HxCDD
13C-123678-HXCDD
13C-123467»-BpCDD
13C-OCDD
13C-2378-TCDF
13C-12378-P«CDF
13C-23478-P«CDF
13C-123478-HXCDF
13C-123678-BXCDF
13C-123789-HXCDF
13C-234678-HXCDF
13C-123467B-Hj>enF
13C-1234789-HpCDF
CLEANUP STANDARD
37C1-2378-JCDD
DfiKlS
CONC.
2000
2000
2OOO
2000
2000
4000
2000
2000
2000
2000
2000 •
• 2000
2000
2000
2000
200
CONC.
FOUND
396
457
404
466
449
813
402
408
423
408
425
412
418
403
382
131
Fag* 4 of 15
R(*>
20^
23^
20X
23**
22^
20^
20."
20^-
21«'"
20 S
?.l f.
21 •
21 ^
20 *
19 /•
65
IOH
RATIO
0.80
1.57
1.23
1.24
1.02
0.88
0.77
1.55
1.58
0.51
0.51
0.49
0.50
0.44
0.43
r\\
-------
OPOSquan 27-AOQ-1999
Lab Name: BATTELLE
Matrix: HATER
Sample Receipt Date: 07-23-99
Ext. Date: 07-29-99
Analyaia Date: 15-AUG-99 Time:
, Extract Volume (uL) : 20
Injection Volume (UL) : 1
Dilution Factor: NONE
Concentration Units: pg/L
ANALYTK
2378-ICDD
12378-PeCDD
123478-BxCDD
123678-BxCDD *
123789-BxCDD
1234678-BpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-FeCDF
123478-HxCDE
123678-HxCDF
12378 9-BxCDF
234678-HxCDF
1234678-HpCDF
1234789-BpCDF
OCDF
Total Tetra-Furana
Total Tetra-Dloxlna
Total Penta-Furana
Total Penta-Dioxlna
Total Bexa-Furana
Total Hexa-Dioxina
Total Bepta-Furana
Total Bepta-Dioxlna
Total TEQ
CONC.
FODND
*
*
•*2 . 613
6.070
5.734
31.894
46.961
266.408
25.395
53.099
24.890
10.727
*
16.528
24.999
*
8.158
865.770
276.622
495.070
65 . 606
113.274
102.339
35.343
73.558
Page
6
PCDD/PCDF ANALYSIS DATA SHEET
Lab Sample ID: 48200-57-07 KO-R4-412A
Sample Wt/Vol: 1.0000 unita : L
Initial Calibration Date: 02-08-99
Instrument ID: Autospec
00:01:27 GC Column ID: 60m DBS
Sample Data Filename: 4807885A
Blank Data Filename: 4807885A «1
Cal. Ver. Data Filename: 4807885 fl
Concentration Units (pg)
DETECTION
LIMIT
1.364
4.121
1.335
1.497
1.396
3.124
1.886
1.039
2.179
0.974
1.481
1.435
1.682
1.446
0.866
3.335
4.540
2.454
3.103
3.730
6.907
5.556
3.161
1.019
9.391
ION
RATIO
*
*
1.19
1.37
1.39
0.95
0.87
0.77
1.44
1.57
1.17
1.21
* •
1.18
0.96
*
0.77
0.84
0.75
1.55
1.54
1.09
1.34
0.96
1.11
TEQ
*
*
0.2613
0.6070
0.5734
0.3189
0.0470
26.64*
1.2698
26.54*
2.4890
1.0727
*
1.6528
0.2500
*
0.0082
61.74»
LABELED COMPOUNDS
13C-2378-TCDD
13C-12378-PeCDD
13C-123478-RxCDD
13C-123678-HXCDD
13C-1234678-BpCDD
13C-OCDD
13C-2378-TCDF
13C-12378-PeCDF
13C-23478-PeCDF
13C-123478-HXCDF
13C-123S79-HXCDF
13C-123789-HXCDF
130-234678-HxCDF
13C-1234678-HpCDF
13C-1234789-HpCDF
CLEANUP STANDARD
37C1-2378-TCDD
SPIKE
CONC.
2000
2000
2000
2000
2000
4000
2000
2000
2000
2000
2000
2000
2000
2000
2000
200
CONC.
FOUND
1312
1423
1224
1344
1129
1965
1249
1300
1297
1197
1214
1158
1246
1078
988
139
Page 6 of 15
R(%)
66
71
61
67
56
49
62
65
65
60
61
58
62
54
49
69
ION
RATIO
0.79
1.56
1.21
1.24
1.05
0.87
0.77
1.53
1.52
0.51
0.51
0.51
0.51
0.44
0.43
-------
OPOSquan 30-AUQ-1999
Fag* 2
PCDD/PCDF ANALYSIS DATA SHEET'
Lab MUM: BATTBLLB
Matrix: WATER
Sampl* Receipt Dat*: 07-21-99
Bxt. Data! 07-28-99
Analysis Data: 17-ATO-99 Tln»: 22:16:40
Extract Volum* (uL): 20
Injection Voluraw (ul): 1
Dilution Factor: NONE
Concontration Onlt»: pg/L
Lab Sarapl* ID: 48200-57-03 WO-R2-212A
Sampl* St/Volt 1.0000 onita: Xi
Initial Calibration Dat*: 02-08-99
Instrument ID: Autospec
GC Column ID: 30mDB225
Sample Data Filename,: 4807887
Blank Data Filanana: 4807887 13
Cal. Var. Data Filename: 4807887 §2
Concentration Onlta (pg)
Page 2 of 7
AN ALT
nt
2378-TCDD
12378-P«CDD
123478-HxCDD
123678-HxCDD
12378 9-BxCDD
1234678-BpCBD
OCDD
2378-TCDF
1237B-PBCDF
23478-P.CDF
123478-BxCDF
COHC. DETECTION
FOOHD LIMIT
9 . 056 5 . 821
* *
* *
* *
* *
* *
* *
180.942 1.258
* *
* *
*
123678-BxCDF *
1237«9-H*CDF *
234«78-HxCDF
123471
OCDF
Total
total
Total
Total
Total
Total
Total
Total
78-HpCDF
19-HpCDF
T«tra-Furan«
T*tra-Dioxina
Penta-Fnran*
t*nta-Dioxin*
B«xa-Furana
Hwxa-nioxina
H«pta-Furan«
B*pta-Diojcin»
*
*
*
*
811.076 3.956
476,367 11«7.960
ION
RATIO
0.73
*
*
*
*
*
' *
0.75
*
*
*
*
*
*
*
*
*
0.78
0.72
*
*
*
*
*
*
TEQ
9.0S61
*
*
*
*
*
*
18.09»
*
*
*
*
*
*
*
*
*
LABELED COMPOtTHDS
13C-2378-TCDD
13C-12378-F«CD0
13C-123478-BXCDD
13C-123678-BXCDD
13C-1234678-HpCDD
13C-OCDD
13C-2378-TCDF
13C-12378-F«CDF
13C-23 4 7 8 -SeCDF
13C-123478-HXCDF
13C-123678-HxCDF
13C-123789-IUtf:nF
13C-234 678-HxCDF
13C-1234678-HpCDF
13C-123478*-HpCDF
CLKAKUP STANDARD
37C1-2378-TCDD
SEIKB CONC.
ION
COHC. FOUND R(%) RATIO
2000 1009 SO 0.79
2000 *
2000 *
2000 *
2000 *
4000 *
2000 1018 5
2000
2000
2000
2000
*
*
*
*
*
0,78
*
*
*
*
2000 * *
2000 * *
2000 * *
2000 * *
200 130 65
Total TEQ
27,15»
-------
OPOSquari 30-AUO-1999
Lab Warns: BATTELLB
Matrix: WATER
Sample Receipt Date: 07-21-99
Ext. Date: 07-28-99
Analyaia Date: 17-AO3-99 Time
Extract Volume (uL) ; 20
Injection' Volume (UL) ; 1
Dilation Factor: NONE
Concentration Dnita: pg/1.
AHALXTE
2378-TCDD
12378-PeCDD
123478-HxCDD
123578-HxCDD
123789-HxCDD
1234678-BpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-BxCDF
123«78-B*CBF
123789-BxCDF
23467B-HXCBF
123478 9-HpCDF
OCDF
Total Tetra-Furan*
Total Tetra-Dioxina
Total Penta-Furana
Total Penta-Dioxina
Total Hexa-Fnran»
Total Hexa-Dioxina
Total Bepta-Ftiran*
Total Hepta-Dioxin»
Total TEQ
CONC.
FODHD
13.328
*
«
#
*
*
*
222 . 024
*
*
«
*
*
*
*
. *
*
1228.479
859.881
*
«
*
*
ft
*
Fage
3
PCDD/PCDF ANALYSIS DATA SHEET
lab Sample ID: 48200-57-05 WO-R3-312A
Sample Kt/Vol: 1.0000 unita: 1>
Initial Calibration Date: 02-08-99
Instrument ID: Autoepec
: 23:04:38 GC Column ID: 30mDB225
Sample Data Filename: 4807887
Blank Data Filename: 4807887 |3
Cal. Ver. Data Filename: 4807887 12
Concentration Onit» (pg)
DETECTIOM
LIMH
13.640
ft
*
*
*
*
ft
2.940
*
*
*
*
ft
*
*
*
*
9.243
2736.931
*
*
*
*
*
*
ION
RATIO
0.70
*
*
*
*
*
*
0.74
*
*
*
ft
*
*
*
*
*
0.85
0.84
*
*
*
ft
ft
* .
TEO
13.32*
*
*
*
*
*
*
22 . 20»
ft
*
*
*
*
*
*
ft
*
35.53»
LABELED COMPOUNDS
13C-2378-TCDD
13C-12378-P«CDD
13C-12347B-BXCDD
13C-123S78-HXCDD
13C-1234 678-HpCDD
13C-OCDD
13C-2378-1CDF
lJC-12378-FeCDF
13C-23478-P»CDF
13C-123478-HXCDF
13C-123 678-HxCDF
13C- 12378 9-HxCDP
13C-234678-HXCDF
13C-1234678-HpCDF
13C-1234789-HpCDF
CLEANUP STANDARD
37C1-2378-TCDD
SPIKB
COHC.
2000
2000
2000
2000
2000
4000
2000
2000
2000
2000
2000
2000
2000
200Q
2000
200
'
Page 3 of 7
COHC . IOH
FOUND R(%) RATIO
384 i9iS* 0.80
ft ft ft
* * ft
« ft *
* ft ft
* * ft
40S 20 • 0.80
* ft *
ft * ft
* * ft
ft * *
* * -ft
* * ft
* ' * *
* . * ft
136 68
-------
OPUSqu»n 30-AUO-1999
P«g» 4
PCDD/PCDF ANALYSIS DATA SHEET
Lab Naott! BATXBLLB
Matrix: WATER
Sainpl* H*c*ipt Dat*; 07-23-99
Ext. Data: 07-28-99
Analyiia Dat*! 17-JUJO-99 Tin*! 23:52:36
Extract Volume (uL)i 20
Injection Volvnna (uL) : 1
Dilution Factors NONB
Concentration Cnita: pD
123478-ElKCt>D
123678-HlCDD
123789-&JCCDD
1234«78-HpCCD
OCDD
2378-ICCF
12378-P«CDF
23478-PeCDF
123478-HxCDF
123678-HxCDT
123789-HxCDF
23467»-HrCT»
1234678-HpCDF
123478 9-BpCDr
OCDF
Total T«tra-Furan«
Total T«tra-Dioxin«
Total P«nt»-Ftiran«
Total P«nta-Dioxin«
Total B«xa-rnran«
fatal H«xa-Dioxina
Total B»pta-Fur«n«
Total Bvpta-Dioxina
COHC.
FOOHD
13.517
*
*
*
*
*
*
255.880
*
*
*
*
*
*
*
*
*
994.114
275.177
*
DETECTION
LIMIT
3.909
*
*
*
•*
*
*
0.865
*
*
* •
*
*
•*
*
*
* •
2.721
784. 4«7
*
*
*
*
*
*
ION
RATIO
0.68
*
*
*
*
• *
*
0.75
*
*
*
*
*
*
*
*
*
0.69 .
0.87
*
*
*
• *
*
*
T1Q
13.51>
*
*
*
*
*
*
25.58*
*
*
*
*
*
*
*
' *
*
LABELED COMPOUHD3
13C-2378-TCDD
13C-12378-*«CDD
13C-123478-HXCDD
13C-123678-HJCCDD
13C-1234678-HpCDD
13C-OCDD
13C-2378-TCDF
13C-1237*-B*CDf
13C-23478-PeCDF
13C-123478-HxCDF
13C-123678-HXCDF
13C-123789-HxCDr
13C-234678-HXCDF
13C-123467B-BpCDF
1301234789-HpCDF
CLEAKUP STAKDARD
37C1-2378-TCDD
SEIKS
COHC.
2000
2000
2000
2000
2000
4000
2000
2000
2000
2000
2000
2000
2000
2000
2000
200
COHC.
FOOHD
1324
*
*
*
*
*
1310
*
*
*
*
*
*
*
*
142
RW
66
*
*
*
*
*
65
*
*
*
*
* .
*
*
*
71
IOH
RATIO
0.79
0.7
*
*
«
*
total TEQ
39.10*
-------
F-3
D/F Blank Lab Raw Data Sheets
F-59
-------
F-3-1
Air Sampling Train and Proof Blanks, Lab Spikes, and
Spike Dups
F-60
-------
Tl
OPOSquan 27-JKK3-1999
Page 1
PCDD/PCDF ANALYSIS DATA SHEET
Lab Name: BAfTELtE L«b Sample ID: 48190-11-10 FH-LB-DIOX
Matrix: AIR Sample Wt/Vol: 1.5640 nnltai M3
Sample Receipt Date: 08-07-99 Initial Calibration Date: 04-22-99
Ext. Date: 08-07-99 Instrument ID: Autospoc
Analysis Date: 15-AUG-99 Time: 19:44:50 GO Column ID: 60m DBS
Extract Volume (uL) : 20 Sample Data Filename: 4807886JL
Injection Volume (uL) : 1 Blank Data Filename; 4807886JI fl
Dilution Factor; NOME Cal. Ver. Data Filename: 4807886 |2
ANMiYTE
2378-SCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HltCDD
1234678-HpCDD
OCDD
2378-3CDF
12378-teCDF
23478-FeCDir
123478-HxCDF
12367R-BXCDF
123789-HxCDF
234678-RxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furana
Total f«tra-Dioxin»
Total Penta-FuranB
Total Ponta-DioxitiB
Total Hexa-Furana
Total H«xa-Dioxin*
Total Hepta-Furana
Total Repta-Dioxina
Total IEQ
CONC.
FOUND
pg/dscm
*
*
*
*
*
*
5.10
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
DETECTION
LIMIT
pg/ds
1
2
0
0
0
0
0
0
1
1
1
1
1
1
0
1
3
1
2
2
3
2
1
3
3
cm
.38
.82
.95
.88
.58
.79
.42
.84
,39
.16
.18
.03
.19
.14
.42
.87
.23
.71
,39
.36
.21
.25
.43
.43
.59
TEQ
*
*
*
*
' *
*
0.0051
*
*
*
*
*
*
*
*
*
*
0.0051
LABELED COMPOUNDS
13C-2378-TCDF
13C-12378-PeCDF
13C-12367B-HXCDF
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123 67 8-HXCDD
13C-1234678-HpCDD
13C-OCDD
FKE-FXELD SURROGATES
37C1-2378-TCDD
13C-123478-HXCDD
13C-23478-PeCDF
13C-123478-HXCDF
13C-123478 9-HpCDF
BPIKB CONC.
CONC . FOUND
(Mi
-------
OJ
NJ
OPUSquan 30-AUQ-1999
Page 1
Page 1 of 11
PCDD/PCDF ANALYSIS DATA SHEET
Lab Name: BATTBLLE
Matrix: AIR
Sample Receipt Date: 08-01-99
Ext. Dates 08-01-99
Analyai* Date: 18-AW3-99 Tine
Extract Volume (iiL) : 20
Injection Volume (uL) : 1
Dilution Factors NONE
CONC.
fOBHO
AHALTTE pg/daon
2378-TCDD *
12378-?«C0D *
123478-HxCDD *
123678-HxCDD *
123789-HxCDD *
1234678-HpCDB *
OCDD *
2378-1CDF *
12378-PeCDF *
23478-PeCDF *
123478-HxCM1 *
123S78-HXCDF *
123789-HxCDF *
234678-HxCDF *
1234678-HpCDF *
1234789-HpCDF *
OCDF *
Total Tetra-Furana 0.06
Total Tetra-Dioxins 0.36
Total P«nta-Furan»
Total yenfca-Diojeina
Total Hexa-Furana
Total RexA-Dloxlna
Total Bepta-Furana
Total Repta-Dioxina
Total TEQ
i 05:28:28
Lab Sample ID: 48190-11-10
Sample Ht/Vol: 1,5640
Initial Calibration Date:
Instrument ID: AutoSpoc
GC Column ID: 30mDB22S
FB-LB-DIOX
units: M3
04-22-99
Sample Data Filename: 4607687
Blank Data Filename: 4807887 §13
Cal. Ver. Data Filename: 4807BB7 112
DETECTION
LIMIT TEQ
pg/dacra
0.60 *
* *
* *
* *
* ' »
* *
* *
0.98 *
* *
* " *
* «
* *
* *
* *
* • *
* *
* *
1.43
6.31
*
*
*
*
*
*
0.0000
LABELED COMPOUNDS
13C-2378-TCDF
13C-12378-B0CDF
13C-12367 8 -H3CCOF
13C-1234678-HpCDF
13C-2378-TCDD
13C-1237 8 -BeCDD
13C-123S78-HXCDD
13C-1 23 4 67 B-HpCDD
13C-OCDD
JRS-FIZU) SURROGATES
37C1-2378-ICDD
13C-123478-HXCDD
13C-23478-PeCBF
13C-123478-HXCDF
13C-1234789-HpCDF
SPIKE CONC.
COMC . EOTOD RECOVERY
(P9) » .
* *
ttfll^l
-------
Lab Name:
Matrix:
Sample Receipt Date
Ext. Date:
Analysis Date:
Extract Volume (uL):
Injection Volume (uL):
Dilution Factor:
Analyte
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
123789-HxCDF
234678-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furans
"otal Tetra-Dioxins
Total Penta-Furans
Total Penta-Dioxins
Total Hexa-Furans
Total Hexa-Dioxins
Total Hepta-Furans
Total Hepta-Dioxins
Total TEQ
PCDD/PCDF ANALYSIS DATA SHEET
Battelle
Air
08/07/99
08/07/99
15-Aug-99 Time:
20
1
None
Cone.
Found
pg/sample
*
*
*
*
*
31.91
*
*
*
*
*
*
*
*"
*
*
*
*
*
*
1
*
•
*
7:44:50 PM
Detection
Limit TEQ
pg/sample pg/sample
8.63
17.64
5.94
5.51
3.63
4.94
2.63 0.0319
5.26
8.70
7.26
7.38
6.44
7.44
7.13
2.63
11.70
20.21
10.70
14.95
14.76
20.08
14.08
8.95
21.46
22.46
0.0319
Lab Sample ID:
Sample Wt/Vol:
Initial Calibration Date:
Instrument ID:
GC Column ID:
Sample Data Filename:
Blank Data Filename:
Cal. Ver. Data Filename:
Labeled Compounds
13C-2378-TCDF
13C-1237B-PeCDF
13C- 123678
13C-123467B-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HXCDD
13C-1234678-HpCDD
13C-OCDD
Cleanup Stds
37CI-2378-TCDD
13C-123478HxCDD
13C-23478-PeCDF
13C-123478-HxCDF
13C-1234789-HpCDF
48190-11-10
FH-LB-DIOX
1 units-
04/22/99
AutoSpec
60m DBS
4807886A
4807886A #1
4807886 #2
Spike
Cone.
(P9)
8000
8000
8000
8000
8000
8000
8000
8000
16000
800
NA
NA
NA
NA
Cone.
Found
(pg)
5096
6012
5144
5992
5168
6968
5820
6504
13768
812 .
*
•
*
*
Recovery
64
75
64
75
65
87
73
81
86
102
•
•
*
*
-------
CT>
PCDD/PCDF ANALYSIS DATA SHEET
Lab Name:
Matrix:
Sample Receipt Date
Ext, Date:
Analysis Date:
Extract Volume (uL):
Injection Volume (uL):
Dilution Factor:
Analyte
2378-TCDD
12378-PeCDD
123478-HxCDD
123878-HxCDD
123789-HxCDD
1234578-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
123789-HxCDF
234878-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furans
Total Tetra-Dioxlns
Total Ptnte-Furans
Total Penta-Dioxins
Total Hexa-Furans
Total Hexa-Dloxins
Tola! Hepta-Furans
Total Hepta-Dioxins
Total TEQ
Battelle
Air
08/01/99
08/01/99
18-Aug-99 Time: 5:28:28 AM
20
1
None
Cone. Detection
Found Limit
pg/sample pg/sample
3.75
* *
* *
* *
* *
* *
* - - *
6.13
* ", *
* *
* *
* *
* *
* •
* *
* *
» " »
0.38 . 8.95
2.25 39.48
* *
# *
* ft
* *
* *
J> *
Lab Sample ID:
Sample VWVol:
Initial Calibration Date:
Instrument ID:
GC Column ID:
Sample Data Filename:
Blank Data Filename:
Cal. Ver. Date Filename:
TEQ
pg/sample Labeled Compounds
13C-2378-TCDF
13C-12378-PeCDF
13C-1 23678
13C-1234878-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HxCDD
13C-1234678-HpCDO
13C-OCDD
«
*
* ,
*
*
*
*
*
Cleanup Stds
37CI-2378-TCDD
13C-123478HxCDD
13C-23478-PeCDF
13C-123478-HxCDF
13C-12347B9-HpCDF
0.00
48190-11-10 FH-LB-DIOX
1 units:
04/22/99
AutoSpec
30m DB225
4807887
4807887 #13
4807887 #12
Spike Cone.
Cone. Found
(P9) (P9)
8000 4932
8000
8000
8000
8000 5108
8000
8000
8000
18000
800 808
NA
NA
NA
NA
Recovery
(%)
62
, *
*
*
64
*
*
*
*
101
*
*
*
*
-------
"n
I
OJ
en
j
OPtJStjuan 27-ADS-1999
Page 9
I
Page 9 of 20
PCDD/FCDF AHALYSIS DAIA SHEET
Lab Name: BATTRLLE
Matrix: AIR
Sample Receipt Date: 08-07-99
Ext. Date: 08-07-99
Analysis Date; 16-AUG-99
Extract Volume (uL) : 20
Injection Volume (uL) : 1
Dilution Factor: HONE
COKC
Time:
07:51:39
Lab Sample ID: 48190-09-11
Sample Wt/Vol: 1.5640
Initial Calibration Date:
Instrument ID: Auto spec
GC Column ID: 60m DBS
BH-IiB-DIOX
units: M3
04-22-99
Sample Data Filename; 4807886A
Blank Data Filename: 4807886A ti
Cal. Var. Data Filename: 4807886 42
FOOHD
AKMiYTB pg/dseni
2378-TCDD
12378-P«CDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD 0
OCDD 3
2378-ICDF 0
12378-B«CDF
23478-PeGDF
123478-HxCDF .
123678-BxCDF
123789-HJtCDF
234678-HxCDF
1234678-HpCBF 0
1234789-HpCBF
OCDF 1
Total Tetra-Furana 0
Total T«tr*-Dioxin» 1
Total Ponta-FuranB
Total Eenta-Dioxin*
Total Hexa-Furans 0
Total Hexa-Dioxina
Total Eepta-Furana 1
Total Hepta-Dioxins 3
Total TEQ
*
*
*
*
*
.51^
.91
.71
*
*
*
*
»
*
.54
*
DETECTION
LIMIT TBQ
pg/docm
0.73
1.61
0.51
0.47
jfjJL 0.31
0.41 p. 0051
0.20 0,0039
0.45 0.0714
0,80 *
0.67 *
'0.65 *
0.56 *
0.65 *
0 . 63 *
0.21 0.0054
0.92 *
LABEljED COMPOTODS
13C-2378-TCDP
13C-12378-PeCDF
13C-123678-BXCDF
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HXCDD
13C-1234678-HpCDD
13C-OCDD
SPIKE COHC.
COHC . FOOHD RECOVERY
(pg) (pg) W
2000 1227 61
2000 1392 70
2000 1102 55
2000 1452 73
2000 1238 62
2000 1567 78
200O 1277 64
2000 1512 76
4000 3517 88
'
.223 1.59 0.0012
,71
.98
*
*
.48
*
.36
.55$
0.91
1.26
1,35
1,83
1.24
0.77
j£> 1<69
P 1.84
0.0870
ERB-FIELD SURROGATES
37C1-2378-TCDD
13C-123478-HXCDD
13C-23478-PeCDF
13C-123478-H3B3DF
13C-1234789-HpCDF
&?*
I'T*
lEOOCS'1^^® 2 0\
aoool * * \ Vi A
2fl||pO\ j^U * * /
2o\p ) r>^ * * / (kjfj^ O-d>AJki^S
20<^J -tiCfi * *
\i$*
-------
OPUSquan 30-AUC-1999
Page 2
O)
tn
Page 2 of 11
f CDD/PCDF ANALYSIS DATA SHEET
Lab Nanw.: BATTELLB
Matrix: AIR
Sample Receipt Date: 07-28-99
EJCt. Date: 07-28-99
Analysis Data: 18-AOO-99 Time: 06:16:26
Extract Volume (uLJ: 20
Injection Volume (11X1) : 1
Dilution Factor: MONK
AHALTTB
2378-TCDD
12378-PeCDD
123478-HXCDD
123678-HxCDD
12378 9-BxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-FeCDF
23478-PeCDF
123478-HXCDF
123678-HxCDF
12378 9-HxCDP
234678-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furana
Total Tetra-Dioxina
Total Penta-Furana
Total Penta-Dioxina
Total Hexa-Furan»
Total Hejta-Dioxina
Total Hapta-Furana
Total Bepta-Dioxlna
COUC.
F00HD
pg/dncan
0.24
*
*
*
*
*
*
0.82
*
*
*
*
*
*
*
*
*
0.15
0.76
*
*
*
*
*
*
DBTECTIO1
LIMIT
pg/dacm
0.29
*
*
*
*
*
*
0.46
*
*
*
*
*
*
*
*
*
0.67
2.99
*
*
*
*
*
*
TEO
0.2440
*
0.0815
Lab Sanrpl* ID: 48190-09-11 BH-I.B-DIOX
Sample Ht/Vol: 1.5640 units: M3
Initial Calibration Date; 04-22-99
Instrument ID t AutoSpec
GC Column ID: 30raDB22S
Sample Data Filename: 4807887
Blank Data Filename: 4807887 113
Cal. Ver. Data Filename: 4807887 112
LABELED COMPOUNDS
13C-2378-TCDF
13C-12378-PeCDF
13C-123«78-HxCDF
13C-1234678-HpCDF
13C-2378-TCDD
13C-1237 8-PeCDD
13C-123678-H3CCD0
13C-1234678-HpCDD
13C-OCDD
PRB-FIELD SURROGATES
37C1-2378-TCDD
13C-123478-HXCDD
13C-23478-PeCDF
13C-123478-HXCDF
13C-1234789-HpCDF
SPIKE
COMC.
-------
0>
PCDD/PCDF ANALYSIS DATA SHEET
Lab Name:
Matrix:
Sample Receipt Date
Ext. Date:
Analysis Date:
Extract Volume (uL):
Injection Volume (uL):
Dilutbn Factor:
Analyte
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
123789-HxCDF
234678-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furans
Total Tetra-Dioxins
Total Penta-Furans
Total Penta-Dtoxins
Total Hexa-Furans
Total Hexa-Dioxins
Total Hepta-Furans
Total Hepta-Dioxins
Total TEQ
Baltelle
Air
08/07/99
08/07/99
16-Aug-99 Time:
20
1
None
Cone.
Found
pg/sample
*
*
*
*
*
3.19056 EMPC
24.46096
4.44176
*
*
•
*
*
*
3.37824
*
7.63232 J
4,44176
12.38688
*
*
3.00288
*
8.50816
22.2088 EMPC
7:51:39 AM
Detection
Limit
pg/sample
4.56688
10.07216
3.19056
2.94032
1.93936
2.56498
1.2512
2.8152
5.0048
4.19152
4.0664
3.50336
4.0664
3.94128
1.31376
5.75552
9.94704
5.69296
7.88256
8.4456
11.44348
7,75744
4,81712
10.57264
11.51104
Lab Sample ID:
Sample VWVol:
Initial Calibration Date:
Instrument ID:
GC Column ID:
Sample Data Filename:
Blank Data Filename:
Cal. Ver. Data Filename:
TEQ
pg/sample Labeled Compounds
13C-2378-TCDF
13C-12378-PeCDF
13C-1 23678
13C-1234678-HpCDF
13C-2378-TCDD
0.0319 13C-12378-PeCDD
0.0244 13C-123678-HxCDD
0.4467 13C-1234678-HpCDD
13C-OCDD
*
*
*
*
*
0.0338
*_
0.0075
Pre^Field Surrogate
37CI-2378-TCDD
13C-123478HxCDD
13C-23478-PeCDF
13C-123478-HXCDF
13C-1234789-HpCDF
0.5443
48190-09-1 1
BH-LB-DIOX
1 units:
04/22/99
AutoSpec
60m DBS
4807886A
4807886A#1
4807886 #2
Spike
Cone.
(pg)
8000
8000
8000
8000
8000
8000
8000
8000
16000
800
NA
NA
NA
NA
Cone.
Found
(P9)
4908
5568
4408
5808
4952
6268
5108
6048
14068
8
*
*
*
*
Recovery
(%)
61
70
55
73
62
78
64
76
88
0
*
*
*
*
-------
PCDD/PCDF ANALYSIS DATA SHEET
Lab Name:
Matrix;
Sample Receipt Date
Ext Date:
Analysis Date:
Extract Volume (uLJ:
injection Volume (uL):
Dilution Factor:
Analyte
2378-TCDD
12378-PeCDD
1234?S-HxCDD
123878-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123878-HxCDF
123789-HxCDF
234678-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furans
Total Tetra-Dioxlns
Total Penta-Furans
Total Penta-Dioxins
Total Haxa-Furans
Total Haxa-Dioxins
Total Hepta-Furans
Total Hepta-Dioxins
Total T6Q
Baltelle
Air
07/28/99
07/28/99
18-Aug-99 Time: 6:16:26 AM
20
1
None
Cone. Detection
Found Limit
pg/samplc pg/sample
1.50 1.81
* *
* „ *
* *
* *
» *
* *
5.13 2.88
* *
* * ft
«L #
* *
* *
* *
* *
* *
* ' *
0.94 4.19
4.75 18.71
* *
* *
* *
* *
tr ' *
* *
Lab Sample ID:
Sample Wt/Vol:
Initial Calibration Date:
InstrumentJD:
GC Column ID:
Sample Data Filename:
Blank Data Filename:
Cal. Ver. Data Filename:
Ion
Ratio Labeled Compounds
0.38 13C-2378-TCDF
13C-12378-PeCDF
13C-1 23678
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HxCDD
0,13 13C-1234678-HOCDD
13C-OCDD
*
*
*
*
*
*
*
*
Pre-Field Surrogate Stds
37C1-2378-TCDD
13C-123478HxCDD
13C-23478-PeCDF
13C-12347B-HxCDF
13C-1234789-HpCDF
2.04
481 90-09-1 1BH-LB-DIOX
1 units:
04/22/99
AutoSpec
30m DB225
4807887
4807887 #13
4807887 #12
Spike Cone.
Cone. Found
(pa) (pa)
8000 4664
8000
8000 *
8000
8000 4908
8000
8000 *
8000
16000
800 4
NA
NA
NA
NA
Recovery
(%)
58
*
*
*
61
*
*
*
*
1
#
*
*
*
-------
Tl
O)
CO
1
OPUSquan 27-ACTG-1999
Lab Name: BATTELLE
Matrix: AIR
Sample Receipt Date: 08-07-99
Ext. Data: 08-07-99
Analysis Date; 15-AOGJ-99 Time
Extract volume (ul>) : 20
Injection Volume (uL) : 1
Dilution Factors NONE
COHC.
FOWNB
AHALYTE pg/dacra
2378-TCDD *
12378-PeCDD *
123478-RicCDD *
123678-HxCDD *
123789-aatCDD *
1234678-HpCDD *
OCDD 3 . 72
2378-TCDt *
12378 -PeCDF *
23478-PaCDF *
123478-HxGDF *
123678-HatCDF *
123789-lJtCDF *
234678-HXCDF *
1234678-HpCDF *
1234789-BpCDF *
OCDF *
Total Tetra-Furana *
Total Tetra-Dioxina *
Total P»nt*-Fnsan« *
Total Penta-Dioxin* *
Total Bex»-Furan« *
Total Hexa-Dioxin* . *
Total H*j»ta-Furan« *
Total Hepta-Dioxina *
Total TEQ
Page 4
PCDD/PCDF
ANALYSIS DATA SHEET
Page 4 of 20
Lab Sample ID: 48190-11-07 FH-FB1-DIOX
23:03:03
Sample Mt/Vol: 1.5640
Initial Calibration Date
Instrument XD : Atitospec
GC Column ID : 60m DB5
units: M3
04-22-99
Sample Data Filename: 4807886A
Blank Data Filename: 4807886A fl
DETECTION
LIMIT TEQ
pg/dscm
1.69
3.12
0.97
0.91
0.60
0,73
0.38 0.
1.06
1.75
1.47
1.25
1.09
1.26
1.21
0.41
1.79
3.09
2.16
2.94
2.97
3.55
2.38
1.47
0.50
3.33
0.
Cal. Ver. Data Filename:
LABELED COMPOUNDS
* 13C-2378-TCDF
* 13C-12378-PeCDF
* 13C-123678-HXCDF
* 13C-1234678-HpCDF
* 13C-2378-TCDD
* 13C-12378-PeCDD
0037 13C-123678-HXCDD
* 13C-1234678-HpCDD
* 13C-OCDD
*
*
*
*
*
*
*
*
PRE-FIBLD SURROGATES
37C1-2378-TCDD
13C-123478-HxCDD
13C-23478-PeCDF
13C-123478-HXCDF
13C-1234789-HpCDF
0037
4807886 |2
SPIKE COHC .
CONG . FOUND RECOVER*
(P9) (P9) (*)
2000 1070 53
2000 1297 65
2000 11«1 57
2000 1508 75
2000 1096 55
2000 1610 81
2000 1371 69
2000 1S72 84
4000 3554 89
Vooo W» 201 loi -c5JLCwA-Uuf> Q& •
WJOOV. * *
jXpo\|^ * *
20\0 / * *
2<* ^ * *
^
-------
PCDD/PCDF ANALYSIS DATA SHEET
Lab Name:
Matrix:
Sample Receipt Date
Ext Date:
Analysis Date:
Extract Volume (uL):
Injection Volume (uL):
Dilution Factor:
Analyte
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234878-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
123789-HxCDF
234678-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furans
Total Tetra-Dioxins
Total Penta-Furans
Total Penta-Dioxins
Total Hexa-Furans
total Hexa-Dioxins
Total Hepta-Furarts
Total Hepta-Dtexins
Total TEQ
Battelle
Air
08/07/99
08/07/99
15-Aug-99 Time:
20
1
None
Cone,
Found
pg/sample
*
*
» . -
*
*
*
23,27
ft
* '
*
*
*
*
* '
*
*
.*
*
*
*
*
*
*
«
*
11:03:03PM
Detection
Limit TEQ
pg/sample pg/sample
10.57
19.52
6,07
5.69
375
4.57
2.38 0.0231
6.63
10,95
9.20
7.82
6.82
7.88
7.57
2.56
11.20
19,33
. 13.51
18.39
18.58
22.21
14.89
9.20
3.13
20,83
0.0231
Lab Sample ID:
Sample Wt/Vol:
Initial Calibration Date:
Instrument ID:
GC Column ID:
Sample Data Filename:
Blank Data Filename:
Cal. Ver, Data Filename:
Labeled Compounds
13C-2378-TCDF
13C-12378-PeCDF
13C-123678
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HxCDD
13C-1234678-HpCDD
13C-OCDD
Cleanup Stds
37CI-2378-TCDD
13C-123478HxCDD
13C-23478-PeCDF
13C-123478-HXCDF
13C-1234789-HpCDF
48190-11-07 FH-FB1-DIOX
1 units:
04/22/99
AutoSpec
60m DBS
4807886A
4807886A#1
4307886 #2
Spike
Cone.
(pg)
8000
8000
8000
8000
8000
8000
8000
8000
16000
800
NA
NA
NA
NA
Cone.
Found
(P9)
4280
5188
4564
6032
4384
6440
5484
6688
14216
804
*
*
*
*
Recovery
(%)
53
65
57
75
55
81
69
84
89
101
*
*
*
*
-------
OPOSquan 27-AOS-1999
Lab Name: BATTELLE
Matrix: AIR
Sample Receipt Date: 08-07-99
Ext. Date: 08-07-99
Analysis Date: 15-AUG-99 Time
Extract Volume (uL) : 20
Injection Volume (uL) : 1
Dilution Factor: HOWE
AHJttYTE
2378-TCDD
12378-P*CDD
123478-HJCCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-P«CDF
23478-P»CDF
123478-HxCDF
123678-HxCDF
123789-HjtCDF
234S78-HXCDF
1231678-HpCDF
123«789rHpCDF
OCDF
Total Tatra-Furans
Total Tatra-Dioxins
Total Penta-Furana
Total Penta-Dioxinp
Total Hexa-Fnrang
Total Hnxa-Dioxins
Total Bepta-Furan*
Total Hepta-Dioxin»
Total TEQ
COMC.
PODHD
pg/dacsn
*
it
*
*
it
it
3.43
*
*
*
*
*
*
*
0.60
*
*
2.37
*
*
*
*
*
0.60
0,81
Page 2
PCDD/PCDF ANALYSIS DAfA SHEET
tab Sample ID: 46190-11-05 FH-PB1-DIOX
Sample Wt/Vol: 1.5640 units s M3
Initial Calibration Date: 04-22-99
Instrument ID : Autospec
: 20:50:56 GC Column ID: 60m DBS
Sample Data Filename: 4807886A
Blank Data Filename: 4807886A #1
Cal. Ver. Data Filename: 4807886 §2
DETECTION
LIMIT
pg/dscm
1.02
1,75
0.63
0.59
0.39
0.48
0.25
0.63
1.00
.0.84
0.80
0.69
0.80
0.77
0.27
1.21
2.09
1.29
1.77
1.69
1.99
1.52
0.95
2.22
2.20
IEQ
*
*
*
*
*
*
0.0034
*
*
*
*
*
*
*
0 . 0060
*
*
0.0094
LABELED COMPODNDS
13C-237B-TCDF
13C-12378-PeCDF
13C-123678-HXCDF
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-P«CDD
13C-123678-HXCDD
13C-1234 678 -HpCDD
13C-OCDD
PRE-FIELD SURROGATES
37C1-2378-TCDD
13C-123 4 7 8-HxCDD
13C-23478-teCDF
13C-123 47 8-BxCDF
13C-1234789-HpCDF
SPIKE
COMC.
(pg)
2000
2000
2000
2000
2000
2000
2000
2000
4000
§:O
tlK
^c.
^\W
Page 2 of 20
COHC.
FOOMD RECOVEH¥
(pg) (%)
1280 64
1583 79
1322 66
1673 84
1345 67
1905 95
1538 77
1841 92
3944 99
. _ Q-WJI.
192 96 •" vJJtiOA-*-*-^ v*xl's'
* *
* *
* *
£_ * *
-------
S3
PCDD/PCDF ANALYSIS DATA SHEET
Lab Name; Battelle
Matrtx: Air
Sample Receipt Date 08/07/99
Ext. Date: 08/07/99
Analysis Date: 15-Aug-99 Time:
Extract Volume (uL): 20
Injection Volume (uL): 1
Dilution Factor: None
Cone.
Found
Analyte pg/sample
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD , *
OCDD 21.46
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
123789-HxCDF
234678-HxCDF
1234678-HpCDF 3.75
1234789-HpCDF
OCDF
Total Tetra-Furans 14.83
Total Tetra-Dioxins *
Total Penta-Furans
Total Penta-Dioxins *
Total Hexa-Furans *
Total Hexa-Oioxins *
Total Hepta-Furans 3.75
Total Hepta-Dioxirts 5.07
Total TEQ
*
8:50:56 PM
Detection
Limit
pg/sample
6.33
10.95
3.94
3.69
2.44
3.00
1.56
3.94
6.26
5.26
5.00
4.32
5.00
4.82
1.69
7.57
13.08
8,07
11.07
10.57
12.45
9.51
5.94
13.89
13.76
Lab Sample ID:
Sample Wt/Vol:
Initial Calibration Date:
Instrument ID:
GC Column ID:
Sample Data Filename:
Blank Date Filename:
Cal. Ver. Data Filename:
TEQ
pg/sample Labeled Compounds
13C-2378-TCDF
13C-12378-PeCDF
13C-1 23678
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
0.0213 13C-123678-HxCDD
13C-1234678-HpCDD
13C-OCDD
*
* *
.
*
*
0.0375
*
*
Cleanup Stds
37CI-2378-TCDD
13C-123478HxCDD
13C-23478-PeCDF
13C-123478-HxCDF
13C-1234789-HpCDF
0.0588
48190-11-05 FH-PB1-DIOX
1 units:
04/22/89
AutoSpec
60m DBS
4807886A
4807886A#1
4807886 #2
Spike
Cone.
(P9)
8000
8000
8000
8000
8000
8000
8000
8000
16000
800
NA
NA
NA
NA
Cone.
Found
(P9>
5120
6332
5288
6692
5380
7620
6152
7364
15776
768
*
*
*
*
Recovery
(%)
64
79
66
84
67
95
77
92
99
96
-------
Tl
CO
OPUSquan 27-AUG-1999
Lab Name: BATTELLE
Matrix: AIR
Sample Receipt Date: 08-07-99
Ext. Date: 08-07-99
Analysis Date : 15-AUG-99 Time
j, Extract Volume (uL) : 20
Injection Volume (uL) : 1
Dilution Factor: NONE
ANALYTE
2378-TCDD
12378-PeCDD
123478-HXCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDP
123678rHxCDF
123789-HxCDF
234678-HXCDF
1234678-HpCDF
123478 9-HpCDF
OCDP
Total Tetra-Furans
Total Tetra-Dioxins
Total Penta-Furans
Total Penta-Dioxins
Total Hexa-Furans
Total Hexa-Dioxins
Total Hepta-Furana
Total Hepta-Dioxina
Total TEQ
CONC.
FOUND
pg/dscm
*
*
*
*
*
*
3.21
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
Page 3
Page 3 of 20
PCDD/PCDF ANALYSIS DATA SHEET
Lab Sample ID: 48190-11-06 FH-EB2-DIOX
Sample Wt/Vol: 1.5640 unita: M3
Initial Calibration Date: 04-22-99
Instrument ID: Autospec
: 21:56:57 GC Column ID: 60m DBS
Sample Data Filename: 4807886A
Blank Data Filename: 4807886A fl
Cal. Ver. Data Filename: 4807886 12
DETECTION
LIMIT
pg/dscm
2.02
3.02
0.85
0.79
0.52
0.65
0.34
1.18
1.63
1.36
1.14
0.99
1.15
1.11
0.37
1.62
2.78
2.40
3.50
2.76
3.43
2.18
1.28
2.96
2.97
TEQ
*
*
*
*
•*
*
0.0032
*
*
*
*
*
*
*
*
*
*
0.0032
LABELED COMPOUNDS
13C-2378-TCDF
13C-12378-PeCDF
13C-123678-HxCDF
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HXCDD
13C-1234678-HpCDD
13C-OCDD
PRE-FIELD SURROGATES
37C1-2378-TCDD
13C-123478-HXCDD
13C-23478-PeCDF
13C-123478-HXCDF
13C-1234789-HpCDF
SPIKE COWC.
CONC . FOUND RECOVERY
(w) (*)
2000 793 40
2000 1112 56
2000 1068 53
2000 1424 71
2000 . 797 40
2000 1363 68
2000 1288 64
2000 1588 79
4000 3397 85
WH^03 198 gg'-CUc-'O-o^5'1^
2000 * *
2000 k^^. * *
20M * *
20 oifl>^ * *
W
-------
PCDD/PCDF ANALYSIS DATA SHEET
Lab Name:
Matrix:
Sample Receipt Date
Ext Date:
Analysis Date:
Extract Volume (uL):
Injection Volume (uL):
Dilution Factor:
Analyte
2378-TCDD
12378-PeCDD
123478-HxCDD
123878-HxCDD
123789-HxCDD
123467fl-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
123789-HxCDF
234678-HxCDF
1234878-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furans
Total Tetra-Oioxins
Total Penta-Furans
Total Penta-Dtoxins
Total Hexa-Furans
Total Hexa-Dioxins
Total Hepta-Furans -
Total Hepta-Dioxins
Total TEQ
Battelle
Air
08/07/99
08/07/99
15-Aug-99 Time:
20
1
None
Cone.
Found
pg/sampte
*
*
* •
*
*
•
20.08
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
- *
*
*
9:58:57 PM
Detection
Limit TEQ
pg/sarnple pgfeample
12.64
18.89
5.32
4.94
3.25
4.07
. 2.13 0.023147
7.38
10.20
8.51
7.13
6.19
7.19
6.94
2.31
10.13
17.39
15.01
21.90
17,27
21.46
13.64
8.01
18.52
18.58
0.020019
Lab Sample ID:
Sample Wt/Vol:
Initial Calibration Date:
instrument! D:
GO Column ID:
Sample Data Filename:
Blank Data Filename:
Cal. Ver. Data Filename:
Labeled Compounds
13C-2378-TCDF
13C-12378-PeCDF
13C-1 23678
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HxCDD
13C-1234678-HpCDD
13C-OCDD
Cleanup Stds
37CI-2378-TCDD
13C-123478HxCDD
13C-23478-PeCDF
13C-123478-HxCDF
13C-1234789-HpCDF
48190-1 1-06 FH-PB2-DIOX
1 units:
04/22/99
AutoSpec
60m DBS
4807886A
480788BA #1
4807886 #2
Spike
Cone.
(PS)
8000
8000
8000
8000
8000
8000
8000
8000
16000
800
NA
NA
NA
NA
Cone,
Found
(pg>
3172
4448
4272
5696
3188
5452
5152
6352
13588
792
*
*
*
*
Recovery
(%)
40
56
53
71
40
68
64
79
85
99
*
*
*
*
-------
-n
i
vl
en
i
OPUSquan 27-AUG-1999
Page
8
Page 8 of 20
PCDD/PCDF ANALYSIS DATA SHEET
Lab Name: BATTELLE
Matrix: AIR
Sample Receipt Date: 08-07-99
Ext. Date: 08-07-99
Analysis Date: 16-AUS-99 Time
Extract Volume (uL) : 20
Injection Volume (uL) : 1
Dilution Factor: NONE
CONC .
FOUND
ANALYTE pg/dscm
2378-TCDD 148.66
12378-PeCDD 661.86
123478-HxCDD 617.29
123678-HxCDD 655.28
12378 9-HxCDD 682.75
1234678-HpCDD 649.49
OCDD 1325.11
2378-TCDF 149.12
12378-PeCDF 711.76
23478-P6C?F 760.17
123478-HxCDP 750.39
123678-HxCDP 723.70
123789-HxCDF 866.07
234678-HxCDF 885.27
1234678-HpCDF 672.78
1234789-HpCDF 735.13
OCDF 1640.82
Total Tetra-Furans 149.12
Total Tetra-Dioxins 148.66
Total Penta-Furana 1471.94
Total Penta-Dioxins 661.86
Total Hexa-Furans 3225.43
Total Hexa-Dioxins • 1955.32
Total Hepta-Furana 1407,91
Total Hepta-Dioxins 649.49
Total TEQ
: 03:27:22
Lab Sample ID: 48190-11-08
Sample Wt/Vol: 1.5640
Initial Calibration Date:
Instrument ID: Autospec
GC Column ID: 60m DBS
FH-LCS-DIOX
units: M3
04-22-99
Sample Data Filename: 4807886A
Blank Data Filename: 4807886A fl
Cal. Ver. Data Filename: 4807886 *2
DETECTION
LIMIT
pg/dscm
1.44
2.11
0.71
0.66
0.43
0.54
0.28
0.95
1.30
1.09
0.92
0.80
0.93
0.89
0.30
1.31
2.25
0.95
1.44
1.32
2.11
0.99
0.67
0.36
0.54
TEQ
148.6565
330.9298
61.7291
65.5276
69.2754
6.4949
1.3251
14.9116
35.5881
380.0865
75.0387
72.3696
86.6071
88.5272
6.7278
7.3513
1.6408
1451.7874
LABELED COMPOUNDS
13C-2378-TCDF
13C-12378-PeCDF
13C-123678-HXCDF
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HXCDD
13C-1234678-HpCDD
13C-OCDD
PRE-FIELD SURROGATES
37C1-2378-TCDD
13C-123478-HXCDD
13C-23478-PeCDP
130-123478-HxCDF
13C-1234789-HpCDF
SP IKE CONC .
CONC . FOUND RECOVERY
(pg) (pg) (%)
2000 995 50
2000 1377 69
2000 1213 61
2000 1594 80
2000 1067 53
2000 1811 91
2000 1458 73
2000 1762 88
4000 3819 95
f&> 205 102 - CSUUX.0~U.-p SAC*-
* *
tAJ>- * *
p> * «
Q$f\ * *
\$
a
-------
PCDD/PCDF ANALYSIS DATA SHEET
Lab Name: Battelle
Matrix: Air
Sample Receipt Date: 08/07/99
Ext. Date: 08/07/99
Analysis Date: 16-Aug-99 Time: 3:27:22 AM
Extract Volume (uL): 20
Injection Volume (uL): 1
Dilution Factor: None
Analyte
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD.
1234878-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123878-HxCDF
123789-HxCDF
234878-HxCDF
1234878-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furans
Total Tetra-Dloxins
Total Panta-Furans
Total Penta-Dioxins
Total Hexa-Furans
Total Hexa-Dioxins
Total Hepta-Furans
Total Hepta-Dioxins
Total TEQ
Cone.
Found
, pg/sample
930.02
4140.60
3861,77
4099.43
4271.28
4063.21
8289.89
932.89
4452.77
4755.62
4694.44
4527.47
5418.13
5538.25
4208.91
4598.97
-., "10264.97
932.89
930.02
9208.46
4140.60
.20178.29
12232.48
8807.88
- 4063.21
Detection
Limit
pgteample
9.01
13.20
4.44
4.13
2.69
3.38
1.75
5.94
8.13
6.82
. 5.76
s.oo
5.82
5.57
1.88
8.20
14.08
5.94
9.01
8.26
13.20
6.19
4.19
2.25
3.38
TEQ
pg/sample
930.00
2070.30
386.18
409.94
427.13
40.63
8.29
93.29
222.64
2377.82
469.44
452.74
541.81
553.83
42.09
45.99
10.26
9082.38
Lab Sample ID:
Sample Wt/Vol:
Initial Calibration Date:
Instrument ID:
GC Column ID:
Sample Data Filename:
Blank Data Filename:
Cal. Ver. Data Filename
Labeled Compounds
13C-2378-TCDF
13C-12378-PeCDF
13C-1 23678
13C-1234678-HpCDF
. 13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HXCDD
1 3C-1 234678-HpCDD
13C-OCDD
Cleanup Stds
37CI-2378-TCDD
13C-123478HxCDD
13C-23478-PeCDF
13C-123478-HXCDF
13C-1234789-HpCDF
48190-11-08 FH-LCS-DIOX
1 units:
04/22/99
AutoSpec
60m DBS
4807886A
4807886A #1
4807886 #2
Spike
Cone.
(Pi)
8000
8000
8000
8000
8000
8000
"8000
8000
16000
800
NA
NA
NA
NA
Cone.
Found
(P9)
3980
5508
4852
6376
4268
7244
5832
7048
15276
820
*
*
*
ft
Recovery
(%)
50
69
61
80
53
91
73
88
95
102
*
*
*
*
-------
OPOSquan 27-AUC3-1999
Page
20
PCDD/PCDF ANALYSIS DATA SHEET
l»al» Ham*: BAfTELLS Lab Sample ID: 48190-11-09 FH-LCSDOP-DIOX
Matrix: AIR Sample Wt/Vol: 1.5640 unite: H3
Sample Receipt Date: 08-07-99 Initial Calibration Date: 04-22-99
Ext. Date: 08-07-99 Instrument ID: Autoapec
Analysis Date: 16-AOS-99 Time: 21:13:15 GC Column ID: 60m DBS
Extract Volum* (uL) : 20 Sample Data Filename: 4807886B
Injection Volume (uL) : 1 Blank Data Filename: 4807886A #1
Dilution Factor: 1:5 Cal. Ver. Data Filename: 4807886 *2
COHC. DETECTION " SPIKE CONC.
FOUND LIMIT TEQ COHC. FOUHD
AHALYTE
2378-TCDB
12378-PeCDD
123478-HxCDD
123678-HKCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-P«CDF
23478-PeCDF
123478-HxCBF
123678-HxCDF
123789-HxCDP
234678-HxCDF
1234678-BpCDF
1234789-HpCDF
OCDF
Total Tetra-Furana
Total Tetra-Dioxins
Total Penta-Furans
Total Penta-Dioxlna
Total Hexa-Furan*
Total Hexa-Dioxlna
Total Hepta-Furans
Total Repta-Dioxiria
Total TEQ
pc?/dacra pg/dscni
127
630
612
657
633
622
1258
136
687
506
752
716
902
882
665
818
1734
136
127
1194
630
3254
1903
1483
622
.20
.01
.87
.57
.53
.93
.71
.06
.84
.88
.33
.46
.67
.98
.01
.02
.90
.06
.20
.72
.01
.43
.96
.03
.93
3
5
1
1
1
1
0
2
2
•2
2
2
2
2
0
3
5
2
3
3
5
2
1
0
1
.92
.00
.84
.71
.12
.42
.75
.84
.97
.49
.47
.15
.49
.40
.78
.44
.93
.84
.92
.02
.00
.67
.74
.96
.42
127
315
61
65
63
is
1
13
34
253
75
71
90
88
6
8
1
1283
.2035
.0026
.2868
.7568
.3526
.2293
.2587
.6064
.3919
.4395
.2330
.6458
,2669
.2976
.6501
.1802
.7349
.5366
LABELED COMPOUNDS
13C-2378-TCDF
13C-12378-PeCDF
13C-123678-HXCDF
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HXCDD
13C-1234678-HpCDD
13C-OCDD
PRE-FIBLD SDRROGATES
37C1-2378-TCDD
13C-123478-HXCDD
13C-23478-EeCDF
13C-123478-HXCDF
13C-1234789-HpCDF
-------
09
PCDD/PCDF ANALYSIS DATA SHEET
Lab Name: Battalia
Matrix: Air
Sample Receipt Date: 08/07/99
Ext Date: 08/07/89
Analysis Date: 16-Aug-99 Time: 9: 13: 15PM
Extract Volume (uL): 20
Injection Volume (uL): 1
Dilution Factor: 1:5
Analyte
2378-TCDD
12378-PeCDD
123478-HxCDD
123878-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
123789-HxCDF
234678-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furans
Total Tetra-Dioxins
Total Penta-Furans
Total Penta-Dioxins
Total Hexa-Furans
Total Hexa-Dioxins
Total Hepla-Furans
Total Hepla-Dioxhis
Total TEQ
Cone.
Found
pg/sample
795.78
3941.34
3834.11
4113.76
3963.36
3887.05
7874.49
851.19
4303.13
3171.04
4706.58
4482.17
5647.10
5S23.92
4160.30
5117.53
10853.53
851.19
795.76
7474.17
3941.34
20359.71
11911.17
9277.84
3897.05
Detection
Limit
pg/sample
24.52
31.28
11.51
10.70
7.01
8.88
4.69
17.77
18.58
15.58
15.45
13.45
15.58
15.01
4.88
21.52
37.10
17.77
24.52
18.89
31.28
16.70
10.89
6.01
8.88
TEQ
pg/sample
795.79
1970.66
383.41
411.37
396.33
38.97
7,87
85.12
215.16
1585.52
470.66
448.22
564.71
552.39
41.60
51.18
10.85
8029.80
Lab Sample ID:
Sample VWVol;
Initial Calibration Date:
Instrument ID:
GC Column ID:
Sample Data Filename:
Blank Data Filename:
Cal. Ver, Data Filename:
Labeled Compounds
13C-2378-TCDF
13C-12378-PeCDF
13C-1 23678
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HXCDD
13C-1234678-HpCDD
13C-OCDD
Pre-Field Surrogate Stds
37CI-2378-TCDD
13C-123478HXCDD
13C-23478-PeCDF
13C-123478-HXCDF
13C-1234789-HpCDF
48190-11-09 FH-LCSDUP-DIOX
1 units:
04/22/99
AutoSpec
60m DBS
4807886B
4807886A#1
4807886 #2
Spike
Cone.
(pg)
8000
8000
8000
8000
8000
8000
8000
8000
16000
8000
8000
8000
8000
8000
Cone.
Found
(pg)
5040
5904
4940
6708
5912
7068
5976
7568
16940
660
*
*
*
*
Recovery
(%)
63
74
62
84
74
88
75
95
106
8
*
*
*
*
-------
~n
to
OPOSapian 27-A0O-1999
Page 10
PCBD/SCDF ANALYSIS DATA SHEET
Lab Name: BATTEL1E ' Lab Sample ID: 48190-09-05 BH-PB1-DIOX
Matrix: AIR Sample Wt/Vols 1.5640 unit»: H3
Sample Receipt Date: 08-07-99 Initial Calibration Date: 04-22-99
Ext, Data: 08-07-99
Analy«i« Date: 16-WJS-99 Tim«: 08 s 57: 48
Extract Volume (uL) : 20
Injection Volume
Dilution Factor:
AHALTTE
2378-TCDD
12378-PeCOD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-P«CDF
23478-58CBF
123478-HjfCDF
123678-BxCDF
123789-HxCDF
234678-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furana
Total Tetra-Dioxina
Total Penta-Furans
Total tenta-Dioxln*
Total Bexa-Fucana
Zotal Bexa-Dioxino
Total Hepta-Furan*
Total Hepta-DioxiriB
Total TEQ
(ill.) : 1
KOHB
COHC.
FOOHD
pg/docm
*
*
*
*
*
2.29
11.77
1.06
*
*
*
*
*
*
1.78
*
2.24
1.06
*
*
*
*
0.95
3.14
3.97
Page 10 of 20
Instrument ID: Autospec
GC Column ID: 60m DBS
Sample Data Filename:
Blank Data Filename:
4807886A
4807886A 11
Cal. Vac. Data Filename: 4807886 12
DETECTION
LIHXX
pg/dscjn
1.11
2.62
0.85
0.79
0.52
0.69
0,35
0.73
1.30
1,09
1.06
0.92
1.06
1.02
0.38
1,68
3" 2.89
y -i.so
1,93
2.21
2.98
2.02
T 1.28
0.47
0.69
IEQ
LABELED COMPOUNDS
13C-2378-ICDF
13C-12378-PeCDf
13C-123678-HXCDF
1301234678-HpCDF
13C-2378-TCDD
0.0229 13C-12378-PeCDD
0,0118 13C-123678-HXCDD
0.1058 13C-1234678-HpCDD
* 13C-OCDD
*
*
*
*
*
0,0178
4
0.0022
PRE-FIELD SURROGATES
37C1-2378-TCDD
13C-123478-HXCDD
13C-23478-PeCDF
130123478-BXCBF
13C-1234789-fipCDF
0.1606
SPIKE
COHC.
(pg)
2000
2000
2000
2000
2000
2000
2000
2000
4000
2000
2000
2000
2000
2000
CONG.
FO0HD
12S1
1413
1219
1361
1348
1583
1346
1507
3358
2250
2543
2535
2360
2513
RECOVERY
(*>
63
71
61
68
67
79
67
75
84
112
127
127
118
126
r
-------
OPUSquan 30-AUO-1999
Pag* 3
PCDD/PCDP ANALYSIS DATA SHEET "
Lab Name BATTELLE
Matrix: AIR
Sample Receipt Data: 07-21-99
Ext, Data: 07-28-99
Analysis Dkte: 18-AOS-99 Time: 07:04:26
Extract Volume (uL): 20
Injection Volume (uLJ : 1
Dilution Factor: NONE
ftHALYTE
CONG. DETECTION
FO0HD LIMIT
pg/dscra pg/dacra
TEQ
Tl
CO
o
2378-SCBD
12378-PeCDD
12347B-HXCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-ICDF
12378-PaCDr
23478-PaCD?
123478-H3CCDF
123678-HxCDF
123789-HxCDF
234678-BKCD7
1234678-HpCDF
1234789-HpCDF .
OCDF
Total Tetra-Forana
Total Tetra-Dioxins
Total Penta-Fur«n«
Total Panta-Dioxina
Total Hexa-Furan»
Total Baxa-Dioxina
Total Hepta-Furana
Total Hepta-Dioxina
*
*
*
*
«
*
*
0.6S 0"
*
*
*
*
*
*
«
*
*
2,38
1.32
*
0,47
*
'*
*
*
*
*
0,78
*
*
*
*
*
*
*
*
*
1.14
4.98
0.065
Total TEQ
0.06S1
Lab Sample ID: 48190-09-05 BH-PB1-DIOX
sample Wt/Vol: 1.5640 units: M3
Initial Calibration Date: 04-22-99
Instrument ID: AutoSpec
GC Column ID: 30mDB225
Sample Data Filename: 4807887
Blank Data Filename: 4807887 113
Cal. Ver. Data Filename: 4807887 fl2
I.ABF.T.ED COMPOUNDS
13C-2378-TCDF
13C-12378-PeCDF
13C-123678-BXCOT'
13C-1234678-BpCDF
13C-2378-TCDD
*3c-12378-PeCDD
13C-123678-HXCDD
13C-1234678-HpCDD
13C-OCDD
PRE-FIBLD SURROGATES
37C1-2378-TCDD
13C-123478-HXCDD
13C-23478-PeCDF
13C-123478-HJCCDF
13C-1234789-HpCDr
Page 3 of 11
SPIKE
CONC.
(pg>
2000
2000
2000
2000
2000
2000
2000
2000
4000
CONC.
FOUND
(P9)
1210
*
*
*
1292
*
it
*
*
RECOVERY
(%>
SI
*
*
*
65
*
*
*
*
2265
-------
CO
PCDD/PCDF ANALYSIS DATA SHEET
Lab Name:
Matrix:
Sample Receipt Date
Ext, Date:
Analysis Date:
Extract Volume (uL):
Injection Volume (uL):
Dilulton Factor:
Analyte
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
123789-HxCDF
234678-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tefra-Furans
Total Tetra-DIoxins
Total Penta-Furans
Total Penta-Dtoxins
Total Hexa-Furans
Total Hexa-Dioxins
Total Hepta-Furans
Total Hepta-Dioxins
Total TEQ
Battetle
Air
07/21/99
07/28/99
18-Aug-99 Time: 7:04:28 AM
20
1
None
Cone. Detection
Found Limit
pg/sample pg/sample
* ' ' 2.94
* *
* . *
* *
* *
* - *
* *
4.07 4,88
-* *
* *
* *
* *
* ' <*
* *
* *
* *
* *
14.89 7,13
8.26 31.15
* *
* *
* *
* ..' *
« «
» *
Lab Sample ID:
Sample VWVoI:
Initial Calibration Date:
Instrument ID:
GC Column ID:
Sample Data Filename:
Blank Data Filename:
Cal. Ver, Data Filename:
TEQ
pg/sample Labeled Compounds
13C-2378-TCDF
13C-12378-PeCDF
13C-123678
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HxCDD
0.4072656 13C-1234678-HpCDD
1 3C-OCDD
*
*
*
*
*
*
*
*
Pre-Field Surrogates Stds
37CI-2378-TCDD
13C-123478HxCDD
13C-23478-PeCDF
13C-123478-HxCDF
13C-1234789-HpCDF
0.4072656
48190-09-05 BH-PB1-DIOX
1 units:
04/22/99
AutoSpec
30m DB225
4807887
4807887 #13
4807887*12
Spike Cone.
Cone. Found
(P9) (P9)
8000 4340
8000
8000
8000
8000 5168
8000
8000
8000
16000
8000 9060
8000
8000
8000
8000
Recovery
(%)
61
*
*
*
65
*
*
*
*
113
*
*
*
*
-------
00
ro
OPUSquan 27-A06-1999
Fag* 11
FCDD/FCDF ANALYSIS DATA SHEET
Lab Name: BATTELLE , Lab Sample ID: 48190-09-06 BH-PB2-DIOX
Matrix: AIR Sample Ht/Voli 1.5640 unita: M3
Sanqple Receipt Date: 08-07-99 Initial Calibration Dates 04-22-99
Ext.' Date: 08-07-99 Instrument ID: Auto spec
Analysis Date: 16-AUQ-99 Tine: 10:03:56 GC Column ID: €0m DBS
Extract Volume (uL) : 20 Sample Data Filename : 4807886A
Injection Volume (uL) : 1 Blank Data filename: 480788 6A |1
Dilution Factor: KOBE
AHALYTE
2378-TCDD
12378-PeCDD
123479-HxCDD
123678-HXCDD
12378 9-HxCDD .
1234678-HpCBD
OCDD
2378-TCDF
12378-PeCDF
SS^IS-PoCPT
123478-HxCDF
123678-HXCDF
123789-BxCDF
234678-HXCDF
1234678-HpCDF
1234789-BpCDF
OCDF
Total Tatra-Purana
Total Totra-Dioxina
Total Penta-Furans
Total Penta-Dioxine
Total Bexa-Fnrana
Total Hexa-Diojcina
Total HBpta-Fur»n»
Total Hepta-Dioxina
Total TEQ
COHC.
FOUND
pg/dacm
*
*
*
*
*
1.09
5.44
3.25
#
*
*
*
• *
*
0.92
*
1.53
11.82
6.58
2.35
0.77
1.02
*
2.29
2.37
DETECIIOH
LIMIT
pg/dacm
1.07
2.59
0.83
0.78
0.51
i-'fflft- 0.70
gmPc, 0.35
0.71
1.30
1.Q9
1..06
0.93
1.07
1.03
0.39
1.72
S 2.97
1.45
1.8C
2.21
3 2.94
T 2.03
1.26
0.48
3.18
Eage 11 of 20
Cal. Ver. Data Filename: 4807886 *2
TEQ
LABELED COMPOUNDS
* 13C-2378-TCDF
* 13C-12378-P*CDF
* 13C-123678-H31CDF
* 1301234678-HpCDF
* 13C-2378-TCDD
0.0109 13C-12378-I»eea3D
0.0054 13C-123678-HXCDD
0.3247 13C-1234678-HpCDD
13C-OCDD
0.0092
*
0.0015
SHE-FIELD SBRROGATES
37C1-2378-TCDD
13C-123478-HXCDD
13C-23478-PBCDF
13C-123478-HXCDF
13C-1234789-HpCDF
0.3518
SPIKE
COHC.
2000
2000
2000
2000
2000
2000
2000
2000
4000
2000
2000
2000
2000
2000
CONC.
FOOTD
(pg)
1298
1442
1281
1400
1420
1668
1502
1557
3476
2208
2259
2500
2310
2414
RECOVERY
(*»
es
72
64
70
71
83
75
78
87
110
113
125
115
121
-------
00
CO
OPUSquan 30-AUG-1999
Lab Name: BATTELLE
Matrix: AIR
Sample Receipt Date: 07-21-99
Ext. Date: 07-28-99
Analysis Date: 18-AOG-99 Time
Extract Volume (uL) : 20
Injection Volume (uL) : 1
Page 4
PCDD/PCDF ANALYSIS DATA SHEET
Lab Sample ID: 48190-09-06 BH-PB2-DIOX
Sample Wt/Vol: 1.5640 units: M3
Initial Calibration Date: 04-22-99
Instrument ID: AutoSpec
: 07:52:24 GC Column ID: 30mDB225
Sample Data Filename: 4807887
Blank Data Filename: 4807887 #13
Dilution Factor: NONE
ANALYTE
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-RxCDF
123678-HXCDF
123789-HxCDF
234678-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furana
Total Tetra-Dioxins
Total Penta-Furans
Total Penta-Dioxins
Total Hexa-Furans
Total Hexa-Dioxin»
Total Hepta-Furans
Total Hepta-Dioxins
Total TEQ
CONC.
FOtFND
pg/dscm
*
A
A
A
A
*
A
2.28
A
*
*
A
*
*
*
A
*
12.64
9.93
A
A
*
*
A
A
DETECTION
LIMIT
pg/dscm
0.44
A
*
A
A
A
*
0.74
A
*
*
A
*
A
*
A
*
1.08
4.58
*
A
A
*
A
A
TEQ
A
*
*
*
A
*
*
0.2278
*
*
*
A
*
*
*
*
*
0.2278
Page 4 of 11
Cal. Ver. Data Filename: 4807887 *12
LABELED COMPOUNDS
13C-2378-TCDF
13C-12378-PeCDF
13C-123C78-HXCDF
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HXCDD
13C-1234678-HpCDD
13C-OCDD
PRE-FIELD SURROGATES
37C1-2378-TCDD
13C-123478-HXCDD
13C-23478-PeCDF
13C-123478-HXCDF
13C-1234789-HpCDF
SPIKE
CONC.
(pg)
2000
2000
2000
2000
2000
2000
2000
2000
4000
2000
COOO
ZQOO
20\0
ulPlV^1
CONC.
FOOND RECOVERY
-------
co
PCDD/PCDF ANALYSIS DATA SHEET
Lab Name:
Matrix:
Sample Receipt Date
Ext. Date:
Analysis Date:
Extract Volume (uL):
Injection Volume (uL):
Dilution Factor:
Analyte
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF;
123789-HxCDF
234878-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furans
Total Tetra-Dioxins
Total Penta-Furans
Total Penta-Dioxins
Total Hexa-Furans
Total Hexa-Dioxins
Total Hepta-Furans
Total Hepta-Dioxins
Total TEQ
Battelle
Air
07/21/99
07/28/99
18-Aug-99 Time: 7:52:24 AM
20
1
None
Cone. Detection
Found Limit
pg/sample pg/sample
2.75
* *
* *
* «
* *
* *
* *
14.26 4.63
* *
* *
* *
* *
* *
* *
* *
* *
* *
79.08 6.76
62.12 28.65
* *
* *
* *
* *
* *
* *
Lab Sample ID:
Sample Wt/Vol:
Initial Calibration Date:
Instrument ID:
GC Column ID:
Sample Data Filename:
Blank Data Filename:
Cal. Ver. Data Filename:
TEQ
pg/sample Labeled Compounds
13C-2378-TCDF
* 13C-12378-P6CDF
13C-1 23678
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HxCDD
1 .43 1 3C-1 234678-HpCOD
* 13C-OCDD
*
*
*
*
*
«
*
*
Pre-Field Surrogates Stds
37CI-2378-TCDD
13C-123478HxCDD
13C-23478-PeCDF
13C-123478-HXCDF
13C-1234789-HpCDF
1.43
48190-09-06 BH-PB2-DIOX
1 units:
04/22/89
AutoSpec
30m DB225
4807887
4807887 #13
4807887 #12
Spike Cone.
Cone. Found
(pg) (pg)
8000 4864
8000
8000 *
8000
8000 5300
8000
8000 *
8000
16000
•
8000 8928
NA
NA
NA
NA
Recovery
(%)
61
*
*
*
66
*
*
*
*
112
-------
-T1
do
01
i .
OPUSepjan 27-AOG-1999
Pag« 12
Page 12 o£ 20
PCDB/PCDF ANALYSIS DATA SHEET
Lab Name: BATIELLE
Mate is: AER
Sample Receipt Date :
Ext. Date: 08-07-99
Lab Sample ID: 48190-09-07 BH-FB1-DIOX
08-07-99
Analysis Date: 16-AOG-99 Time: 11
Extract Volume (uL) :
Injection Volun** |uL)
20
: 1
:10:01
Sample Bt/Voli 1,5640
Initial Calibration Date
Instrument ID : Autoapec
GC Column ID : 60m BB5
units: M3
04-22-99
Sample Data Filename: 4807886A
Blank Data Filename: 4807886A *1
Dilution Factor; HOME
Cal. Ver. Data Filename!
COHC. DETECTION
FOUND LIMIT XBQ
ANALYTB pg/dpcro pg/d»an
2378-TCDD
12378-BeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-lJCCDF
123789-HxCDF
234678-HxCDF
1234678-BpCDF
1234789-BpCDF
OCDF
Total Tetra-Furans
Total T»tra-Dioxins
Total Penta-Furarve
Total Fenta-Dioxina
Total H«x»-Furans
Total Hexa-Dioxine
Total Hepta-Furana
Total H»pta-Dioxins
Total TBQ
*
*
*
*
*
i.so&mPC,
8,63
0,75
*
*
*
*
*
*
1.56
*
*
0.75 3"
*
*
*
0.87 J
*
3.15 3
1.90 y
1.08 »
2.55 *
0,88 *
0.82 *
0.54 *
0.75 0.0190
0.39 0.0086
0.71 0,0748
1.29 *
1.08 *
0.99 *
0.86 *
1.00 . *
0.96 *
0.40 0.0156
1,76 *
3.03 *
1.44
1.88
2.18
2.90
1.89
1.33
0.49
3.39
0.1180
LABELED COMPOUNDS
13C-2378-TCDF
13C-12378-PeCDF
13C-123678-HzCDF
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C- 123 678-HxCDD
13C-1234678-HpCDD
13C-OCDD
i
PRE-FIELD SURROGATES
37C1-2378-TCDD
13C-123478-HXCDD
13C-23478-PeCDF
13C-123478-HXCDF
13C-1234789-HpCDF
4807886 *2
SPIKE CONC.
COMC . FOOHD RECOVSRT
(P«) lPV) W
2000 1395 70
2000 1554 78
2000 1422 71
2000 1453 73
2000 1496 75
2000 1775 89
2000 1516 76
2000 1554 78
4000 3406 85
2000 2064 103
2000 2244 112
2000 2339 117
2000 2021 101
2000 1816 91
-------
-fl
1
CO
O)
PCDD/PCDF ANALYSIS DATA SHEET
Lab Name:
Matrix:
Sample Receipt Date
Ext. Date:
Analysis Date:
Extract Volume (ul.f.
Injection Volume (uL):
Dilution Factor:
Analyte
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
123789-HxCDF
234878-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tefra-Furans
Total Tetra-Dioxins
Total Penta-Furans
Total Penta-Dioxlns
Total Hsxa-Furans
Total Haxa-Dioxins
Total Hepta-Furans .
Total Hepta-Dioxins
Total TEQ
Battelle
Air
08/07/99
08/07/99
16-Aug-99 Time:
20
1
None
Cone,
Found
pg/sample
*
*
*
*
*
11,89
53.99
4.69
*
' *
*-
*
*
*
2,44
*
*
1.17
*
*
*
1.36
(*
4.93
2.97
11:10:01 AM
Detection
Limit
pg/sample
6.76
15.95
5.51
5.13
3.38
4.69
2.44
4.44
8.07
6.76
6.19
5,38
6.26
6.01
2.50
11.01
18.96
9.01
11.76
13.64
18.14
11.82
8.32
3.07
21.21
Lab Sample ID:
Sample Wt/VoI:
Initial Calibration Data:
Instrument ID:
GC Column ID:
Sample Data Filename:
Blank Data Filename:
Cat. Ver. Data Filename:
TEQ
pg/sample Labeled Compounds
13C-2378-TCDF
13C-12378-P6CDF
13C-123678
* 13C-1234678-HpCDF
13C-2378-TCDD
0.12 13C-12378-PeCDD
0.05 13C-123678-HxCDD
0.47 13C-1234678-HpCDD
* 13C-OCDD
*
*
* •
*
*
0.10
*
*
Pre-Field Surrogates
37CI-2378-TCDD
13C-123478HxCDD
13C-23478-PeCDF
13C-123478-HXCDF
13C-1234789-HpCDF
0.74
48190-09-07 BH-FB1-DIOX
1 units:
04/22/99
AutoSpec
60m DB5
4807886A
4807886A#1
4807886 #2
Spike
Cone.
(pg)
8000
8000
8000
8000
8000
8000
8000
8000
16000
8000
8000
8000
8000
8000
Cone.
Found
(P9)
5580
6216
5688
5812
5984
7100
6064
6216
13624
8256
8976
9356
8084
7264
Recovery
(%)
70
78
71
73
75
89
76
78
85
103
.112
117
101
91
-------
OPOSquan 27-AOG-1999
Lab Hama: BATTELLE
Matrix: AUS.
Sample Receipt Dates 08-07-99
Ext. Date: 08-07-99
RnalysiH Date: 16-AW3-99 Time
Extract Volume (uL) : 20
Injection Volum* (uH : 1
Dilution Factor: HONE
AHALYTE
2378-TCDD
12378-PeCBD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCOD
2378-TCDF
12378-PeCDF
23478-PeCW
123478-HxCDE'
123678-HxCDI1
123789-fficCDF
234678-HxCDf
1234678-HpCDF
1234789-HpCDF
OC0P
Total Tetra-Furane
Total Tetra-Dioxins
Total Penta-Furan*
Total Pent»-Dioxins
Total tlexa-Fuzana
Total Hexa-Dioxins
Total Hapta-Furans
Total Bapta-Dioxin»
Total *BQ
CONC .
FOOND
pg/dflcm
13 4 . 17
646.51
615.85
618.61
650.60
625.52
1262.44
138.04
666.93
662.49
728.03
£93 . 85
831.11
816.63
626.00
734.06
1536.19
141.35
134.17
1329.42
646.51
3069.62
1885.07
1360.06
€25.52
Page
15
PCDD/PCOF ANALYSIS DATA SHEET
Lab Sample ID: 48190-09-09 BH-LCS-DIOX
sample Ht/Vol: 1.5640 units: M3
Initial Calibration Date: 04-22-99
Instrument ID : Autospec
: 13:22:18 . OC Column ID; 60m DBS
Sample Data Filename: 4807886A
Blank Data Filename: 4807886A fl
Cal. Ver. Data Filename: 4807886 f2
DETECTION
LIMIT
pg/dacm
1.18
1.46
0.48
• 0.45
0.29
0.36
0.18
0,79
0.76
0.64
0.60
0.52
0.60
0.58
0.20
0,87
1.50
1.61
1.18
0.78
1.46
0.65
0.46
0.24
0.36
TEQ
134.1735
323.2569
61.5853
61.8612
65.0600
6.2552
1.2624
13.8036
33.3466
331.2429
72.8031
69.3849
83.1108
81.6633
6.2600
7.3406
1.5362
1353.9466
LABELED COMPOUNDS
13C-2378-TCDP
13C-12378-5eCDl'
13C-123678-HXCDF
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PcCDD
13C-123678-BXCDD
13C-1234678-HpCDD
13C-OCDD
PRE-FIBLD SOHROGJOTSS
37C1-2378-TCDD
13C-123478-HXCDD
13C-23478-PeCDS'
13C-123478-HXCDF
13C-1234789-HpCDF
SPIKE
COHC.
(pg)
2000
2000
2000
2000
2000
2000
2000
2000
4000
2000
2000
2000
2000
2000
COHC.
FOOHD
(pg)
1316
1581
1221
1627
1431
1888
1430
1774
4246
*
*
*
*
*
Paga 15 of 20
RECOVERY
(*)
66
79
61
81
72
94
71
89
106
\
\ l/*^Ls \
> W^A>J"~'"
/ Ar^
/ fy^
/
-------
Tt
II
00
00
PCDD/PCDF ANALYSIS DATA SHEET
Lab Name:
Matrix:
Sample Receipt Date
Ext. Date:
Analysis Date:
Extract Volume (uL):
Injection Volume (uL):
Dilution Factor:
Analyte
2378-TCDD
12378-PeCDD
123478-HxCDD
123878-HxCDD
123789-HxCDD
1234878-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
123789-HxCDF
234878-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total Tetra^Furans
Total Tetra-Dioxins
Total Penta-Furans
Total Penta-Dioxins
Totel Hexa-Furans
Total Hexa-Dioxlns
Total Hepta-Furans
Total Hepta-Dioxins
Total TEQ;
Battelle
Air
08/07/99
08/07/99
16-Aug-99 Time:
20
1
None
Cone.
Found
pg/sample
839.37
4044.57
3852.76
3870.02
4070.15
3913.25
7897.82
863.58
4172.31
4144.54
4554,66
4340.73
5199.42
5108.84
3916.26
4592,28
' 9610.40
884.29
839.37
8316.85
4044.57
19203.54
11793.00
8508.54
- 3913.25
1:22:1 8PM
Detection
Limit
pg/sample
7.38
9.13
3.00
2.82
1.81
2.25
1.13
4.94
4.75
4.00
3.75
3.25
3,75
3.63
1.25
5.44
9.38
10.07
7.38
4.88
9.13
4.07
2.88
1.50
2.25
TEQ
pg/sample
839.39
2022.30
385.28
387.00
407.02
39.13
7.90
86.36
209.18
2072.26
455.46
434,07
519.94
510.89
39.16
45.92
9.61
8470.29
Lab Sample ID:
Sample WtA/ol:
Initial Calibration Date:
Instrument ID:
GC Column ID:
Sample Data Filename:
Blank Data Filename:
Cal. Ver. Data Filename:
Labeled Compounds
13C-2378-TCDF
13C-12378-PeCDF
13C-1 23678
13C-1234678-HpCDF
13C-23T8-TCDD
13C-12378-PeCDD
13C-123678-HxCDD
13C-1234678-HpCDD
13C-OCDD
Pro-Field Surrogates Stds
37CI-2378-TCDD
13C-123478HxCDD
13C-23478-PeCDF
13C-123478-HxCDF
13C-1234789-HpCDF
48190-09-09 BH-LCS-DIOX
1 units:
04/22/99
AutoSpec
QOm DBS
4807886A
4807886A #1
4807886 #2
Spike Cone.
Cone, Found
(P9) (P9)
8000 5284
8000 6324
8000 4884
8000 6508
8000 5724
8000 7552
8000 5720
8000 7096
16000 16992
8000
8000
8000
8000 *
8000
Recovery
(%)
66
79
61
81
72
94
71
89
106
*
*
*
*
*
-------
Tl
CO
CD
1
OFOSqumn 27-AUG-1999
Paqe
16
Pag* 16 of 20
PCDD/FCDF ANALYSIS DATA SHEET
Lab Name: BRTTELLF,
Matrix: AIR
Sample Receipt Data: 08-07-99
Ext. Dat»s 08-07-99
Analysis Date: 16-AOG-99 Time
Extract Volume (uL) : 20
Injection Volume (uL) : 1
Dilution Factor: HOHE
CONC.
FOUND
ANALYTK pg/dscm
2378-ICDD 138.95
12378-PeCDD 667.93
123 47 8-HxCDD 62 € . IS
123678-HxCDD 6S9.2S
123789-BxCDD 654.83
1234678-HpCDD 654 . 31
OCDD 1319,82
2378-1CDF 144.84
12378-PeCDF 708. €2
23478-PeCDF 723.47
123478-HXGDF 774.36
123678-HxGDF 72S.OO
123789-HxCDF 938.61
234678-HxGDF 855.57
1234678-HpCDF 670.11
1234789-HpCDF 737 . 40
OCDF 1833.52
Total Tetra-Furana 144.84
lotal Ietra-Dioxin» 138.95
Total Panta-Fiirano 1432.09
Total *entm-Dtoxin» 667,93
Total Hexa-Furana 3294.54
Total H«xa-Dio3Clns 1950.23
Total Hepta-Furans 1407.51
Total Hepta-Dioxins 654.31
Total TEQ
Lab Sample ID: 46190-09-10 BH-LCSDUP-DIOX
• 14:28:23
Sample Ht/Vol; 1,5640
Initial Calibration Date
Instrument XJ>: Autospec
GC Column ID: 60m DBS
units : M3
04-22-99
Sampl» Data Filenamn: 4807886ft
Blank Data Filename: 4807886A #1
DETECTION
LIMIT
p
-------
PCDD/PCDF ANALYSIS DATA SHEET
Lab Name:
Matrix:
Sample Receipt Date
Ext. Date:
Analysis Date:
Extract Volume (uL):
Injection Volume (uL):
Dilution Factor:
Analyte
2378-TCDD
12378-PeCDD
123478-HxCDD
123878-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCOF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
123789-HxCDF
234678-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
Total T»tra-Furans
Total Tetra-Dtexins
Total Penta-Furans
Total Penta-Dioxins
Total Hexa-Furans
Total Hexa-Dloxins
Total Hepta-Furans
Total Hepta-Dioxins
Total TEQ
Battelle
Air
08/07/99
08/07/99
16-Aug-99 Time; 2:28:23 PM
20
1
None
Cone.
Found
pg/sample
669.27
4178.57
3917.19
4186.89
4096.62
4093.36
8256.79
906.12
4433.13
4526.03
4844.40
4541.88
5671.94
5352.45
4192.21
4613.17
11470.50
806.12
869.27
8959.16
4178.57
20610.64
12200.64
8805.38
4093.36
Detection
Limit
pg/sample
7.19
13.95
4,25
4.00
2.63
3.25
1.56
4.63
7.19
6.07
5.44
4.75
5.44
5.26
1.75
7.76
13,39
4.63
7.19
7.32
13.95
5.88
4.07
2.13
3.25
TEQ
pg/sample
869.29
2089.30
391.72
418,69
409.66
40.93
8.26
90.61
221.66
2263.00
484.44
454,19
587.20
535.24
41.92
46.13
11,47
8963.71
Lab Sample ID:
Sample YWVol:
Initial Calibration Date:
Instalment ID:
GC Column ID:
Sample Data Filename:
Blank Data Filename:
Cal. Ver. Data Filename:
Labeled Compounds
13C-2378-TCDF
13C-12378-PeCDF
13C-1 23678
13C-1234678-HpCDF
13C-2378-TCDD
13C-12378-PeCDD
13C-123678-HxCDD
13C-1234678-HpCDD
13C-OCDD
Pro-Field Surrogate Stds
37CI-2378-TCDD
13C-123478HxCDD
13C-23478-PeCDF
13C-123478-HxCDF
13C-1234789-HpCDF
48190-09-10 BH-LCSDUP-OIOX
1 units:
04/22/99
AutoSpec
60m DBS
4807886A
4807886A#1
4807886 #2
Spike
Cone.
(pg>
8000
8000
8000
8000
8000
8000
8000
8000
18000
8000
8000
8000
8000
8000
Cone.
Found
(Pfl)
4960
5596
4720
6396
5364
6816
5592
7124
16804
*
*
*
*
*
Recovery
(%)
82
70
59
80
67
85
70
89
105
*
*
*
*
*
-------
OFUSquan 14-JUL-1999
Pag* 1
Page 1 of 1
PCDD/PCDF ANALYSIS DATA SHEET
Lab Nam*; BATTELLE
Matrix: SOLVENT
Sample Receipt Date: 07-10-99
Ext. Date: 07-10-99
Analyai* Date: 13-JUL-99 Time: 21:06:24
Extract Volume (uli) : 20
Injection Volume (uL): 1
Dilution Factor: NONE
Concentration Unit*: pg/aample
ANALTTB
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HXCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
1,2378-PeCDF
1'3478-PeCDF
123478-DxCDF
123678-HxCDF
123789-HXCDF
234478-HxCDF
1234678-HpCDF
1234789-HpCDF f-
OCDF
Total letra-Furan*
Total Tetra-Dloxln*
Total Penta-Furan*
Total Penta-Dioxins
Total Beza-Furan*
Total Bexa-Dioxin*
Total Bepta-Furan*
Total Bepta-Dioxin*
CONC.
FOUND
*
*
*
*
*
*
3.38
*
*
*
*
*
*
*
*
*
*
5.22
0.13
*
*
0.60
*
*
0.64
DETECTION
LIMIT
1.74
4.60
2.35
2.71
3.25
l.*8
3.21
2.58
1.53.
2.62
1.80
1.77
1.55
1.96
1.53
2.74
7.56
11.00
4.38
3.24
47.10
3.98
3.84
4.94
5.68
ION
RATIO
*
*
*
*
*
*
0.76
*
*
*
*
*
* '
.*
*
*
*
0.67
0.76
*
*
1.23
*
*
1.16
Lab Sample ID: 48200-51-03 METHOD BLAHK
Sample Wt/Vol: 1.0000 unit*: ea
Initial Calibration Date: 02-08-99
Instrument ID: AutoSpec
GC Column ID: 60m DBS
Sample Data Filename: 4807866A
Blank Data Filename! 4807866A »2
Cal. Ver. Data Filename: 4807866X fl
Concentration Unit* (pg)
LABELED COMPOUNDS
13C-2378-TCDD
13C-12378-PeCDD
13C-123478-BXCDD
13C-123678-BXCDD
;13C-1234 678-HpCDD
'13C-OCDD
13C-2378-TCDF
13C-12378-PeCDF
13C-23478-PeCDF
13C-123478-HXCDF
13C-123678-HXCDF
13C-123789-HXCDF
13C-234678-HXCDF
13e-U34<78-BpOBr
13C-1234789-HpCDF
CLEANUP STANDARD
37C1-2378-TCDD
SPIKE
CONC.
2000
2000
2000
2000
2000
4000
2000
2000
2000
2000
2000
2000
2000
2000
2000
CONC.
FOUND
1681
2121
1592
1600
1545
2376
1769
1920
2291
1741
1671
1545
1807
1OO
1247
R(%)
84
106
80
80
77
64
88
96
113
87
94
77
90
• 1
62
ION
RATIO
0.80
1.53
1.26
1.26
1.05
0.90
0.79
1.53
1.58
0.52
0.52
0.52
0.51
0.45
0.44
200
-------
PCDD/PCDF ANALYSIS DATA SHEET
Lab Name: Battelle
Matrix: Solvent
Sample Receipt Date 07/10/99
Ext. Date: 07/10/99
Analysis Date: '. 13-Jul-9i Time: 8:08:24 PM
Extract Volume (uL): 20
Injection Volume (uL): 1
Dilution Factor: None
Concentration Units: pg/sample
• Cone.
Found
Analyte pg/sample
2378-TCDD
12378-PeCDD
123478-HxCDD *
123678-HxCDD
123789-HxCDD *
1234878-HpCDD
OCDD 3.38
2378-TCDF
12378-PeCDF l
23478-PeCDF
123478-HxCDF
123678-HxCDF
123789-HxCDF
234678-HxCDF *
1234878-HpCDF
1234789-HpCDF
OCDF
Total Tetra-Furans 5.22
Total Tetra-Dtoxins 0. 1 3
Total Penta-Furans *
Total Penta-Dtoxins ' *
Total Hexa-Furans 0.60
Total Hexa-DIoxins *
Total Hepta-Furans *
Total Hepta-Dbxlns 0.64
Detection
Limit
pg/sample
1.74
4.60
2.35
2.71
3.25
1.68
3.21
2.58
1.53
2.82
1.80
- 1.77
1.55
1.86
1.53
2.74
7.56
11.00
4.38
3.24
47.10
3.98
3.84
4.94
5.68
Lab Sample ID: 48200-51-03 METHOD BLANK
Sample WtA/ol: 1 units: M3
Initial Calibration Date: 02/08/99
Instrument tD: AutoSpec
GC Column ID: 60rn DBS
Sample Data Filename: 4807866A
Blank Data Filename: 4807866A #2
Cal. Ver. Data Filename: 4807866A#1
TEQ
pg/sample Labeled Compounds
13C-2378-TCDD
* 13C-12378-PeCDD
13C-123478-HxCDD
* 13C-123678-HxCDD
13C-1234678-HpCDD
13C-OCDD
0.76 13C-2378-TCDF
13C-12378-PeCDF
13C-23478-PeCDF
13C-123478-HXCDF
13C-123678-HXCDF
13C-123789-HXCDF
13C-234678-HXCDF
' 13C-1234678-HDCDF
13C-1234789-HpCDF
*
*
0.67 Cleanup Slds
0.76
37CI-2378-TCDD
*
1.23
*
*
1.16
Spike
Cone.
-------
OPOSquan 14-JUL-1999
Pag* 1
Pago 1 of 1
10
CO
PCDD/PCDP ANALYSIS DATA SHEET
Lab Hum: BATTELI.E
Mat r ix! SOLVENT
Saiipla Receipt Data: 07-10-99
Ixt. Data! 01-10-99
Analyais Data: 13-JOL-99 Time: 22:12:38
Extract Voluma (ul.) : 20
Injection Volume (uL) : 1
Dilution Factor: HONE
Concentration Dnit«: pg/aanpla
2378-TCDD
12378-PaCDD
123478-HxCDD
123678-BxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCOT
12378-P«CDP
123478-HxCDF
123678-ffitCW
123789-HxCBF
234678-HxCDP
1234678-HpCDF
1234789-BpCCF
OCDF
lotal
Total
Total
Total
Total
Total
Total
Total
T*tra-Furana
T*tra-Dioxlna
Fanta-Furana
P«nt»-Dioxin»
Hoxa-Furari*
Hexa-Dioxln*
Bapta-Furana
H«pta-Dioxin«
COHC
DETBCSIOH
FOTOD
1
3
0
0
0
0
0
1
*
*
*
*
*
.42
,09
*
.95
.31
.24
*
.17
*
.49
.52
LrmT
2
1
2
3
4
1
3
3
2
3
•>
2
1
2
1
3
8
14
£
4
19
4
4
5
4
.46
.80
.93
.30
.01
.91
.66
.49 .
.08,
.61
.25
.20
.79
.43
.77
.05
.62
.87
.20
.46
.92
.87
.73
.60
.98
ION
RATIO
*
*
*
*
*
1.19
o.aa
*
*
*
*
*
*
*
*
*
*
0.73
0.80
l.SS
*
1.14
*
0.98
1.19
Lab Samplo ID: 48200-51-02 XAD BKCD
Sample Wt/Vol: 1,0000 units: ea
Initial Calibration Date: 02-08-99
Xtiatrument ID: AutoSpac
GC Column IDs 60m DBS
Sample Data Filename: 4807866A
Blank Data FilanaRw: 480T866A «2
Cal. Ver. Data Fllanana: 4B07866A #1
Concentration Unit* (pg)
LABELED COMPOUNDS
13C-2378-TCDD
13C-12378-EaCDD
13C-123478-HXCDD
13C-123678-HXCDD
13C-123 4 678-HpCDD
•'13C-OCDD
13C-2378-TCDF
13C-12378-FaCDF
13C-2347B-»aCDB'
13C-123478-HxCDf
130-123678-HxCDF
13C-123789-HXCDF
13C-234678-H3CCDF
13C-1234678-HpCDF
13C-1234789-HpCDF
CLKADUI" STANDARD
37C1-2378-TCDD
rones
COHC.
2000
2000
2000
2000
2000
4000
2000
2000
2000
2000
3000
2000
2000
2000
2000
cone.
FOOHD
1729
2023
1*57
1626
1717
2988
1820
2081
2298
17S7
17S4
1707
1864
1826
1400
RW
86
101
83
81
86
75
91
104
115
88
87
85
93
91
70
IOH
RATIO
0.80
1.56
1.24
1.26
1.06
0.90
0.8O
1.S6
1.59
0.52
0.33
0.51
0.52
0.45
0.44
200
-------
PCDD/PCDF ANALYSIS DATA SHEET
Lab Name: Baltelte
Matrix: Solvent
Sample Receipt Date 07/10/99
Ext. Date: 07/10/99
Analysis Date: 13-Jul-99 Time; 10:1 2:38 PM
Extract Volume (uL): 20
Injection Volume (uL): 1
Dilution Factor: None
Concentration Units: pg/sample
Cone.
Found
Analyte pg/sample
2378-TCDD
12378-PeCDO
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD 1,42
OCDD 3.09
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123878-HxCDF
123788-HxCDF
234678-HxCDF
1234878-HpCDF .
1234788-HpCDF
OCDF
Total Tetra-Furans . 0.95
Total Tetra-Dtoxins 0.31
Total Penta-Furans 0.24
Total Penta-Dioxins
Total Hexa-Furans 0.17
Total Hexa-Dioxtns -*
Total Hepta-Furans 0.49
Total Hapta-Dioxins 1.52
Detection
Limit
pg/sample
2.46
7.8
2.93
3.3
4.01
1.91
3.66
3.49
2.08
3.61
2.25
2.2
1.79
2.43
1.77
3.05
8.62
14.87
6.2
4.46
79.92
4.87
4,73
5.6
4,98
Lab Sample ID:
Sample Wt/Vol:
Initial Calibration Date:
Instrument ID:
GC Column ID:
Sample Data Filename:
Blank Data Filename:
Cal. Ver. Data Filename:
Ion
Ratio Labeled Compounds
13C-2378-TCDD
* 13C-12378-P6CDD
13C-123478-HxCDD
13C-123678-HxCDD
13C-1234678-HpCDD
1.19 13C-OCDD
0.88 13C-2378-TCDF
13C-12378-PeCDF
13C-23478-PeCDF
13C-123478-HxCDF
13C-123678-HXCDF
13C-1237S9-HxCDF
13C-234678-HxCDF
13C-1234678-HpCDF
13C-1234789-HpCDF
0.73 Pre-Field Surrogate Stds
0.8
1.56 37CI-2378-TCDD
it
1.14
«
0.98
1.19
48200-51-02 XADBKGD
1 units: M3
02/08/99
AutoSpec
60m DBS
48078B6A
48078B6A#2
4807866A#1
Spike
Cone.
(P9)
8000
8000
8000
8000
8000
16000
8000
8000
8000
8000
8000
8000
8000
8000
8000
800
Cone.
Found
6916
8092
6628
6504
6868
11952
7280
8324
9192
7068
6936
6828
7456
7304
5800
*
Recovery
(%)
86
101
83
81
86
75
91
104
115
88
87
85
93
91
70
*
Ion
Ratio
0.8
1.56
1.24
1.26
1.06
0.9
0.8
1.56
1.59
0.52
0.53
0.51
0.52
0,45
0.44
-------
F-3-2
Sewage Sludge Blank Fractions
F-95
-------
OPUSquan 27-AOS-1999
P»g« 9
PCD0/PCDF ANALYSIS DATA SHEEf
Lafa Nun: BATTBLLE
Matrix: merm.
Sarapl. R«c«ipt Data; 07-29-99
Ext. Data I 08-08-99
Analyaia Data: lS-AOa-99 Time: 04:25:44
Extract Volume (ut): 20
Injection Volura* (uL): 1
Dilution Factor: HOME
Concentration Onita: pg/g dry
Lab Sampl* ID: 48190-15-14 LAB BLANK
Sampl« Kt/Vol: 0,2409 unit*: 1,
Initial Calibration Data: 02-08-99
Inatruimnt IDi Autospee
GC Column IDi 60m DBS
Sample Data Filename: 480788SA
Blank Data Filename: 480788SA II
Cal. V«r. Data Filename: 4807885 tl
Concentration Onita
Fag* 9 of 15
Tl
-------
OPUSquan 30-AUQ-1999
Fag* 1
PCDD/PCBF AKALYSIS DATA SHEET
Lab Name: BATTKLLB
Matrix: SLUDGE
Sample Receipt Date: 08-08-99
Ext. Data: 08-08-99
Analytic Date: 17-AWZ-99 Time: 21:28:38
Extract Volume (uL): 20
Injection Volume (uL): 1
Dilution Factor: HONE
Concentration Unit*: pg/g dry
Lab Sample ID: 48190-15-14 LAB BLANK
Sample Ht/Vol: 0.2409 unit*: g
Initial Calibration Date: 02-08-99
Instrument ID: Autoapec
GC Column ID: 30mDB225
Sample Data Filename: 4807887
Blank Data Filename: 4807887 13
Cal, Vet. Data Filename: 4807887 *2
Concentration Dnita (pg)
ANALYTE
CONC.
FQOHD
DETECTION
LIMIT
ION
RATIO
TEQ
»
Tl
CO
"•4
i -
2378-TCDD
12378-PeCDD
123478-HXCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-FeCDF
23478-PeOJF
123478-HxGDF
123678-HxCDF
123789-BxCDF
234678-HxCDF
1234678-B^iCDF
1234789-BpCDF
OCDF
Total Tetra-Fuxan*,
Total Tetra-Dioxin*
Total Penta-Furana
Total Penta-Dloxlna-
Total Hexa-Fnran»
Total H»ia-Dioxin«
total Hepta-Furans
Total Hepta-Dloxine
*
*
*
*
*
*
*
*
*
*
*
•
*
*
*
*
*
4.437
*
*
*
*
*
*
*
2E.2S7
*
*
*
*
*
*
5.106
*
*
*
»
*
*
*
*
*
16.051
5270.759
*
*
*
*
*
*
*
*
*
*
*
*
* •
*
*
*
*
0.67
*
*
*
*
*
*
*
LABELED COMPOUNDS
13C-237B-TCDD
13C-12378-P»CDD
13C-123478-HXCDD
13C-123678-HXCDD
13C-1234678-HpCDD
13C-OCDD
13C-2378-TCDF
13C-12378-PeCDF
13C-23478-PeCDF
13C-123478-HXCDF
13C-123678-HXCDF
13C-123789-BxCDF
13C-234«78-HxCDF
13C-1234678-BpCBF
13C-1234789-HpCDF
ClrRMrUP STANDARD
37C1-2378-TCDD
200
Total TSO
0.0000
Page I of 7
EPIKB
CONC.
2000
2000
2000
2000
2000
4000
2000
2000
2000
2000
2000
2OOO
2000
2000
2000
COMC.
FOOTO
1171
*
*
*
*
*
1342
*
*
*
*
*
*
*
*
m<%»
59
*
*
*
*
*
67
*
*
*
*
*
*
*
*
ION
RATIO
0.77
*
*
*
*
*
0.80
*
*
*
*
ft
*
*
*
99
50
-------
OPUSquan 27-ABQ-1999
P»g« 13
P»g« 13 of 15
PCDD/ECDP ANALYSIS DATA SHEET
Lib Nam*: BMTELLE
Matrix: WATER
sanpl* R«c«ipt D»t«: 07-23-99
Ext. Dat*: 08-08-99
Analyst* Dat*; 15-JMJG-99 lima: 08:50:01
Extract Volume (uL): 20
Injection Velum* (uL) : 1
Dilution Factor: HONK
Concentrut ion 0nit>; pg/g dry
™n
CO
CM
,
ANALYTB
2378-ICDD
12378-POCDD
123478-BxCDD
123678-BxCDD * ' .
123789-HxCDD
1234678-HpCDD
OCDD
2378-ICDF
12378-P«CDF
2347»-*»CDF
123478-HTCDt
123678-EtxCOH'
123789-HxCDF
234C78-8XCDV
1234C78-SpCDF
1234783-HpCDF
OCDF
Total T«tra-ruran«
Total Tdtra-Dioxin*
Total P«nta-Furan»
Total P«nt«-Dioxin»
Total H«xa-Furan«
Total Hexa-Dio3tin«
Total Hept»-Furan»
Total R«pta-Dioxin*
COSC.
FOOND
897.929
4217.885
34t2.67S
4215.993
4217.715
4460. 8S5
1066S.425
827.726
4323.959
4105.178
4207.435
4162.805
4024.493
4423.698
4431.840
4231.286
7S37.168
864.700
967.392
8429.137
4217.885
16818.432
11907.384
8765.309
4670.553
DETECTION
LIMIT
5.695
17.566
5.573
6.246
5.838
11.954
6.513
4.857
8.758
4.069
6.2S1
6.016
6.778
6.062
3.442
12.863
15 . 683
11.465
5.695
8.688
17.566
6.590
5.788
3.992
35 . 930
ION
RATIO
0.74
1.55
1.22
1.26 .
1.26
1.03
0.86
0,75
1.57
1.55
1.23
1.24
1.23
1.22
1.04
1.02
0.88
0.72
0.74
1.57
1.55
1.23
1.22
1.04
1.03
TZQ
897.9»
2108. »
347. 2»
421.6*
421.7,
44.60»
10.66»
82.77»
216. 1»
2052. »
420 . 7»
416 . 2»
402. 4»
442. 3»
44.31»
42.31»
7.5372
liab Sampl* ID: 48190-15-05 S-R4-413A M3
Sampla Wt/Vol: 0.2326 unit*: L
Initial Calibration Datai 02-08-99
Instrument ID: AutoSpec
SO Column ID: 60m PBS
Sarapl* Data Filenanw: 4807885A.
Blank Data Filename: 4807885& fl
Cal. Ver, Data Filenamo: 480788S fl
Concentration Onits (pg)
LABF.LED COMPOUNDS
13O-2378-ICDD
13C-12378-E«CDD
13C-123478-H3tCOD
13C-123678-H3CCDD
13C-1234678-HpCDD
13C-OCDD
13C-2378-TCDF
13C-12378-*»ca»l
13C-23478-P«CDF
13C-123478-H«CI)P
13C-123678-HXCDF
13C-123789-H3tt3)F
13C-234S78-HXCDF
13C-1234«78-HpCDF
CLEANUP STANDARD
37C1-2378-TCDD
SPIKE
CONC.
2000
2000
2000
2000
2000
4000
2000
2000
2000
2000
2000
2000
2000
2000
2000
CONC.
FOUND
1571
1681
1492
1465
1421
2763
1391
1592
1536
1392
1428
1366
1410
1309
1209
R{*>
79
84
75
73
71
69
70
80
77
70
71
68
71
65
SO
ION
RATIO
0.79
1.51
1.23
1.23
1.02
0.88
0.78
1.56
1.54
0.51
a. si
0.50
0.51
0.44
0.43
200
132
66
Jotsl TEQ
8380.»
-------
OPUSquan 27-AOS-1999
14
Page 14 of 15
PCDD/PCDF AHftLTtSIS DATA SHEET
Lab Name: BATTELLE
Matrix: HATER
sainple Receipt Date; 07-23-99
Ext. Date: 08-08-99
Analyaia Dat«: 15-AOS-99 Tiroo : 09:56s03
Extract Volume (uL): 20
Injection Volume (uL) : 1
Dilution Factors HOME
Concentration Unlt»: pg/g dry
ANALYTE
2378-TCDD
12378-PeCDD
123478-HXCDD
123678-HxCDD * '
123789-BuCDD
1234678-HpCDD
OCDD
2378-TCDf
12378-PeCDF
23478-?«CDF
123478-HxCDF
123678-HxCDF
12378 9-HXCW
234678-HXGDF
1234678-HpCDF
1234789-BpCDF
OCDF
Total Tetra-Furana
Total Tetra-Dioxina
Total P«nt»-Furana
Total P«nta-Dioxina
Total Hexa-Fur«n»
Total Baxa-Dioxina
Total H«pta'-Fur«n«
Total Hepta-Dioxina
CONG,
FOIJMD
922.180
4265.763
3756.664
4045.160
4003.540
4453.906
10804.678
862.242
4321.081
4138.867
4256. £19
4211.970
4073.521
4407.371
4441.289
4306.817
7568.202
883.971
984.523
84S9.949
4265.763
16949.481
11805.364
8853.513
4664.607
DETECTION
LIMIT
5.556
16.618
5.338
5.998
5.590
12.045
6.578
4,481
8.588
3.818
6.08-;
3.734
6.979
5.841
3.303
12.885
15.839
10.578
12.639
8.340
16 . 618
6.443
5.542
3.906
36.204
ION
RATIO
0.76
1.59
1.23
1.23
1.24
1.03
0.88
0.78
1.56
1,52
1.23
1.22
1.22
1.22
1,03
1.04
0.90
0,67
0.81
1,56
1.59
1.23
1.23
1.03
1.00
TEQ
922.1*
2132, »
375. 6»
404.5*
400.3*
44.53»
10.80*
86.22*
216.0*
2069.*
425 . 6*
421. 1>
407.3*
440. 7»
44.41»
43.06*
7.5682
total B2Q
Lab Sample ID: 48190-15-06 SR4413A USD
Sample Wt/Vol: 0.2323 unit*: I>
Initial Calibration Data: 02-08-99
Instrument ID: AutoSpec
GC Column ID: 60m DBS
Sample Data Filanune: 4807885A
Blank Data Filename: 4807885A tl
Cal, Ver. Data Filename: 4807885 fl
Concentration Unitn (pg)
LABELED COMPOUNDS
13C-2378-TCDD
13C-12378-J?«CBB
130123478-HxCDD
13C-123678-HXCDD
13C-1234678-HpCDD
13C-OCDD
13C-2378-TCDF
13C-12378-BeCDF
13C-23478-PeCDF
13C-123478-BXCBF
13C-123678-HXCDF
13C-123789-HXCDF
13C-S34678-BxCDF
13C-1234678-HpCDF
13C-1234789-HpCDF
CLEANUP STANDARD
37C1-2378-TCDO
8452. »
8FXKB
COHC.
2000
2000
2000
2000
2000
4000
2000
2000
2000
2000
2000
2000
2000
2000
2000
CONG.
FOUND
1610
1741
1526
1619
1448
2846
1497
1631
1628
1440
1464
1364
1511
1369
1234
R<*l
80
87
76
81
72
71
75
82
81
72
73
68
7«
68
62
IOH
RATIO
0.79
1.55
1.23
1.24
1.03
0.87
0.76
1.53
1.S4
0.50
0.50
0.50
0.51
0.44
0.44
200
141
70
-------
F-3-3
Scrubber Water Fractions
F-100
-------
o
OPUSguan 27-AUO-1999
Lab Nama: BATTZL.LB
Matrix: WATER
Sample Receipt Data: 07-29-99
Ext. Dat*: 07-29-99
Analysis Data: 14-AUO-99 Tim*:
Extract Volume (uL) : 20
Injection Volume (ul») : 1
'Dilution Factor: KOHE
Concentration Units: pg/L
ANALYTE
2378-TCBD
12378-PeCDD
123478-HxCDD
123678-HXCDD *
123789-HxCDD
1234678-HpCDD
OCDB
2378-TCDF
12378-PeCDF
23478-EeCDF
12S478-H-WJDF
123678-HXCDF
123789-HxCDF
234678-HxCDF
1234678-HpCDF
1234789-HpCDF
OCOF
Total Tetea-Furaa*
Total Tetra-Dioxin*
Total Penta-Fur»ns
Total Fanta-Diexina
Total Hexa-Furan*
Total Hoxa-Dioxins
Total Hept»-Furan«
Total H«pta~Dioxl*»
Total TEfl
COHC.
FOUND
*
*
r *
*
*
. *
S.304
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
Page
1
PCDD/SCDF ANALYSIS DATA SHEET
Lab Sample ID: 48200-57-28 LAB BLANK
Sample Wt/Vol: 1.0000 units: L
Initial Calibration Date: 02-08-99
Instrument ID: Jlutospac
17:25:11 GC Column ID: 60m DBS
Sample Data Filename: 4807385*
Blank Data Filename: 4807885K fl
cal. Ver. Data Filename: 4807885 fl
Concentration Units (pgl
DETECTION
LIMIT
1.522
3.959
1.115
1.216
1,149
2.083
1.106
1.093
2.057
0.828
i:22C
1.214
1.252
1.159
0.620
2.121
2.664
2.580
3.463
3.345
£.635
4.497
2.602
5.0S2
6.262
IOH
RATIO
*
*
*
*
*
*
o.ei
*
*
*
*
* -
*
*
*
*
*
*
*
*
*
*
*
*
*
TEQ LABELED COMPOUNDS
* 13C-2378-TCDD
* 13C-12378-P«CDD
* 13C-12347B-HJCCDD
* 13C-123678-HXCDD
* 13C-1234678-HpCDD
* 13C-OCDD
O.OOS3 i3c-2378-»en>r
* 13C-12378-P*CDF
* 13C-23478-PeCDF
* 13C-123478-BXCDF
* 330123678-HxCDF
* 13C-123789-HXCDF
* 13C-234678-HXCDF
* 13C-12346"?8-HpCDF
* 13C-1234789-HpCDF
*
*
CLEANUP STANDARD
37C1-2378-1CDD
0.0053
SPIKE
COHC.
2000
2000
2000
2000
2000
4000
2000
2000
2000
2000
2000
2000
2000
2000
2000
200
CONC.
FODND
1063
1363
1202
1385
1390
2772
1144
1259
1393
1222
1228
1342
1318
1263
1291
117
Paqe 1 of 15
R(%)
53
68
64
69
70
69
ST
S3
70
61
61
67
66
63
65
59
IOH
RATIO
0.79
1.56
1.22
1.24
1.03
0.88
0,7»
1.54
1.56
0.52
0.52
0.52
0.52
0.44
0.44
-------
OEUSquan 27~ftna-1999
Page 7
Paga 7 of IS
ECDD/ECDF ANALYSIS DATA SHEET
Lab Kama: BATTELLE
Matrix: WATER
Sample Receipt Date: 07-29-99
Zxt. Data: 07-29-99
Analysis Date: 15-ADS-99 Tina: 01:07:28
Extract Volume (uL) : 20
Injection Volume (uL.) : 1
Dilution Factor: NONE
Concentration Onita: pg/L
.
Tl'
_a
O '
KJ
i
ANALYTS
2378-TCDD
12378-PeCDD
12347»-HxCDD
123C78-HXCDO ' '
123789-BxCDD
1234€78-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-BxCDF
123678-HxCDF
1237S9-fficCDF
234678-BxCDF
' 1234«78-EpCDF
1234789-HpCDF
OCDF
Total Tetra-Puran*
Total Tetra-Dioxini
Total P«nta-ITuran»
Total. P«nta-Dioxin«
Total Hexa-Furana
Total H«xa-Diorlna
Total H«pta-Furan»
Total Hapta-Diostin*
COMG.
FOOHD
222.918
1046.610
9O.957
1015.200
984,797
1018.390
2027.844
206.749
1093.386
1093.502
1043.670
1052.468
1020.109
1108.978
1075.949
1063.871
1944. C71
210.389
222.918
2186.889
1046. €10
4225.226
2963.934
2139.820
1018.390
DETEC2I0H
LIMIT
1.57S
3.506
1.1E3
1.2S3
1.187
2.319
1,288
1.154
1.981
1.377
1.219
1.219
1.271
1.161
0.659
2.443
3.101
2.724
1.S75
2.351
3.506
1.284
1.176
0.766
2.319
IOH
RATIO
0.76
1.58
1.24
1.25
1.23
1.06
0.87
0.74
1.56
1.56
1.23
1.25
1.25
1.22
1.03
1.02
0.89
0.85
0.76
1.56
1.58
1.23
1.24
1.03
1.06
TS!Q
222. 9>
523. 3>
»S.3B»
101. S»
98.47»
10.18»
2.027B
20.£7»
54.66»
546. 7»
104.3*.
105.2*
102. Oil
110 . 8»
10.75»
10.63»
1.9447
Lab Sample ID: 48200-57-08 LCS
Sampla Wt/Vol: 1.0000 unit*:
Initial Calibration Data; 02-08-99
Instrument ID: Autcepac
6C Column ID: 60ra DBS
Sanpltt Data Filenames 4807385A
Blank Data Filename: 4807885%. »1
Cal. Ver. Data Filename: 4807885 fl
Concentration Unit* (pg)
LABELED COMPOUNDS
13C-237B-ICDD
13C-12378-PeCDD
13C-123479-HXCDD
13C-123 678-BxCDD
13C-1234678-HpCDD
13C-OCDD
13C-2378-TCDF
13C-12378-PeCTF
13C-23478-P«CDF
13C-123478-HXCDF
13C-123 678-HxCDF
13C-123789-BaCDF
13C-234 678-HxCD?
13C-123 4 678-HpCDF
13C-1234789-HpCDF
CLKANOT STANDAflD
37C1-2378-3CDD
SPIKE
COHC.
2000
2000
2000
2000
2000
4000
2000
2000
2000
2000
2000
2000
2000
2000
2000
COHC.
Fotnm
1188
1481
13(0
1442
1363
2556
1269
1342
932
1309
1280
1374
1416
1253
1262
R(%)
59
74
C8
72
£8
£4
63
67
47
65
64
69
71
63
63
ION
KAIIO
0.80
1.55
1.22
1.22
1.03
0.88
0.75
1.53
1.58
0.52
0.52
0.51
0.52
0.44
0.44
200
127
64
Total TBQ
2122.»
-------
OPUSquan 27-AUG-1999
Lab Haute; BATXZLLE
Matrix: HATER
Sample Receipt Date; 07-29-99
Mxt. Dates 07-29-99
Analysis Date: 15-AU3-99 Time:
Extract Volume (uL) : 20
Injection Volume (uL) : 1
Dilution Factor: HOME
Concentration Dnits: pg/L
ANAMTTE
2378-1CDD
12378-PeCDD
123478-BxCDD
123678-HJtCBD * '
123789-HxCDD
1234678-BpCDD
OCDD
2378-ICDF
12378-EeCDF
23478-PeCDF
123478-HxCbr
123678-EJBCDF
123789-BbtCDF
234678-HxCDF
1234678-BpCDF
1234789-HpCDF
OCDF
Total Tetra-Furana
Total Tetra~Dioxin»
Total Penta-Furan»
Total Penta-Dioxin*
Total Haxa-Furam
Total Hexa-Dioxina
Total Hepta-Furans
Total Hepta-Dioxins
Total TEQ
COKC.
FO0ND
210.478
1032 . 118
889.180
996.409
973.892
981.497
1931.914
197.060
1061.499
1014.366
1014.343
1029.222
960.692
1055.456
103S.S21
1013.004
1083.742
197,060
210.478
2075.865
1032.118
4059.713
2859.481
2052.524
981.497
Page
8
FCDD/ECDF ANALYSIS DATA SHEET
Lab Sample IDt 48200-57-09 LCS DOT
Sample Wt/Vol: 1.0000 units: L
Initial Calibration Date: 02-08-99
Instrument ID ; Autospec
02! 13: 34 GC Column ID: 60m DBS
Sample Data Filename: 4807885A
Blank Data Filename: 4807885A fl
Cal. Ver. Data Filename: 4807885 fl
Concentration Unit* (pg)
DETECT ION
LIMIT
1.761
4.573
1.247
1.379
1.296
2.589
1.656
1,225
2.346
0.922
1.406
1.351
1.501
1.270
0.750
3.028
3.987
1.22S
1.761
2.143
i,573
1.451
1.285
0.897
2.589
ION
RATIO
0.75
1.55
1.21
1.24
1.23
1.05
0.87
0.76
1.58
1.53
1.24
1.23
1.24
1.22
1.03
1.05
0.90
0.76
0.75
1.58
1.55
1.24
1.21
1.03.
1.05
TEQ
210.4*
516. 0»
88. tl»
99.64*
97.38»
9.8150
1.9319
19.70»
53.07»
507.1*
101. 4»
102.9;.
96.06»
105.5*
10,39»
10.13*
1.0837
2031. »
LABELED COMPODNDS
13C-2378-ICDD
13C-12378-5eCDD
13C-123478-HXCDD
13C-123678-BXCBD
13C-123467 8 -HpCDD
13C-OCDD
13C-2378-TCDF
13C-12378-teCDF
13C-23478-PeCDF
13C-123478-HXCDF
13C-123 678-HxCDF
13C-123789-HXCDF
13C-234 678-HXCDF
13C-1234678-HpCDP
13C-1234769-HpCDF
CLBAKUP STANDARD
37C1-2378-ICDD
BE IKE
COKC.
2000
2000
2000
2000
2000
4000
2000
2000
2000
2000
2000
2000
2000
2000
2000
200
CONG,
FOUND
1090
1364
1332
1383
1310
2173
1173
1264
1429
1267
1278
1262
1374
1239
1050
125
Page 8 of 15
R(%)
54
68
67
69
66
54
59
63
71
63
P4
63
69
62
53
62
IOH
RATIO
0.80
1.51
1.31
1.19
1.02
0.88
0.76
1.55
1.S3
0.51
0.51
0.51
0.51
0.45
0.44
-------
WAZ-OIFranlHaHAIrs
LCSA.CS Duplicate Results
ANALVTE
2378-TCOD
12378-PeCDD •
123478-HxCDD
I2387B-H»CDD
123789-HxCDD
f234S78-HpCOD
OCDO
2378-TCOF
12378-PeCDF
23478-PeCDF
12347B-HxCDF
123678-KxCDF
1237B9-HKCDF
234678-tttCDF
1234678-HpCDF
1234769-HpCDF -
OCDF
Rseoveiy Is calculated as( (cone
LCS Spike'
Cone.
(sa/dfcm)
128
639
839
639
639
639
1,279
126
638
639
639
639
539
639
639
S39
1279
found-background cone
48190-11-10
Lab Blank
Cone.
0.00
0.00
0.00
0.00
0.00
0.00
• S.10
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
•Vtfttn eonc.)*1flO
48190-114)8
LCS Cone.
Found
(pg/dscm)
148.66
861.86
617.28
65538
682.75
649.49
132S.11
14912
711.76
760.17
750.39
723.7
866.07
aas.27
672.76
735.13
1640.82
Recovery
116
104
97
103
107
102
103
117
111
119
117
113
135
138 S
105
115
12B
LCS Dup Spike
Cone.
(pg/dsem;
128
638
639
839
639
639
1279
128
639
839
839
639
639
639
639
639
1279
48190-11-10
Field Blank
Cone.
(pg/dscm^
0.00
0.00
0.00
0.00
0.00
0.00
S.10
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
O.OG
0.00
48190-11-09
LCS Dup, Cone.
Found
127.20
630.01
612.87
657,57
633.53
622.93
1258.71
136.06
687.64
506.88
753,33
718.46
902.67
882.98
665.01
81 8.02
1734.90
Recovery
99
99
96
103
99
97
n
106
108
79
118
112
141 &
138 &
104
128
136 4
Recovery
RPD
15.6
4.9
0.7
0.3
7.5
4.2
5.2
9.2
3.4
40.0 *
0.4
1,0
4.1
0.3
1.2
10.7
5.6
& * outside QC
-------
WA2-01 Back Half Airs
pg/dscm
LCS/LCS Duplicate Results
ANALYTE
2378-TCDD
12378-PeCDD
123478-HxCDD
123678-HxCDD
123789-HxCDD
1234678-HpCDD
OCDD
2378-TCDF
12378-PeCDF
23478-PeCDF
123478-HxCDF
123678-HxCDF
123789-HxCDF
234678-HxCDF
1234678-HpCDF
1234789-HpCDF
OCDF
LCS Spike
Cone.
(pg/dscm)
128
639
639
839
639
639
1278
128
639
639
839
639
639
639
639
839
1278
48190-09-11
Lab Blank
Cone.
(pg/Oscm)
0
0
0
0
0
0
0.51
3.91
0.71
0
0
0
0
0
054
0
1.22
46190-09-09
LCS Cone.
Found
(pg/dscm)
134.17
646.51
615.85
618.61
650.6
625.52
1262.44
138.04
666.93
662.49
726.03
663.65
831.11
816.63
626
734.06
1536.19
Recovery
(%)
105
101
96
97
102
98
99
105
104
104
114
109
130
128
98
115
120
LCS Djp Spke
Cone.
(pg/dscm)
128
639
639
639
639
639
1279
128
639
639
639
839
639
639
639
639
1279
48190-09-11
Field Blank
Cone.
(pg/dscm)
0
0
0
0
0
0
051
3.81
0.71
0
0
0
0
0
0.54
0
1.22
48190-09-10
LCS Dup. Cone.
Found
(pg/dscm)
138.95
667.93
626.15
669.26
654.83
65431
131962
144.84
706.62
723.47
774.36
726.00
938.61
855.57
670.11
737.40
1833.52
Recovery
(%)
109
104
98
105
102
102
103
110
111
113
121
114
147 S
134
105
115
143 S
Recovery
RPD
(%)
4
3
2
8
1
4
4
5
6
9
6
5
12
5
7
0
16
Recovery is calculated as( (cone, found-background conc.ysplke conc.poo
& « outside QC range.
-------
71
o
e»
WM -OS Waters
pan.
LCSA.CS Duplicate Rtsutte
ANALYTE .
2378-TCDD
12378-PiCDD
t234?S-HlCDO
imn-MxCOO
1 23789 HxCDD
IZMSfB-HpCDD
OCDD
23T8-TCDF -..
12378-PeCDF
23478-PeCDF
123478-H*CDF
1236?8-H»CDF . -
123789-HnCDF
234678-H*GDF
1234678-MpCDF
1234788-HpCOF
OCDF
LCS Spike
Cone.
(pgflj
200
looo
1000
1000
1000
1000
2000
200
1000
1000
1000
1000
1000
1000
1000
1000
2000
4820Q-5T-28
Lab Blank
Cone.
(PtfL>
0.00
0,00
0.00
0,00
0.00
0.00
o.oo
5.30
0.00
0.00
0.00
0.00
0.00
o.oo
0.00
0.00
0.00
48200-87-08
LCS Cone,
Found
-------
WA1-O5 Sludge
PO'gdry
MS/MS Duplicate Results
S-R4-413B
ANALYTE
2378-TCDD If
12378.PeCDD
123478-HxCDD
123676-HxCDD
123789-HxCDD
1234878-HpCDD
OCDD
237B-TCDF *
12378-PeCDF
23476-PeCDF
123478-HxCDF
123678-H«CDF
123789-HKCDF
234678-HxCDF
1234878-HpCDF
1234789-HpCDF
OCDF
MS Spike
Cone.
(pg/g dty)
1403.51
7017.54
7017.64
7017.84
7017.54
7017.54
14035.09
1403.61
7017.54
7017.54
7017.54
701754
7017.54
7017.54
7017.64
7017.54
14035.09
48190-15-04
Background
Cone.
(pg/g dry)
5.14
0.00
8.24
3072
39.95
383.54
3689.09
35.08
1275
13.43
29.63
1001
0.00
1331
222.09
0.00
441.20
48190-15-05
MS Cone.
Found
(pg/g dry)
89793
4217.89
3472.68
4218.69
4217.72
4460.87
10865.43
827.73
4323.96
4105.18
4207.44 '
4162.81
4024.48
4423.70
4431.84
4231.20
7537.17
Recovery
(%)
84
60
49
80
60
58
50
58
61
58
60
59
57
63
60
60
51
MS Dup Spike
Cone.
(pg/g dry)
140252
7012.62
7012.82
7012.62
7012.62
7012.82
14025.25
1402.52
7012.62
701262
7012.62
7012.62
701262
7012.62
7012.82
7012.82
14025.25
48190-15-04
Background
Cone.
(pg/9 dry)
514
0.00
8.24
30.72
39.95
383.54
363900
35.08
12.75
13.43
29.63
10.01
000
1331
222.09
0.00
441.20
48190-16-06
MS Dup. Cone.
Found
(pg/g dry)
922 18
4285.78
3768.68
404S.18
4003.64
4453.01
10804.68
' 882.24
4321.08
4138.87
4256.62
. 4211.97
4073.62
4407.37
4441.29
4308.82
7588.20
Recovery
(*)
85
81
53
87
57
58
51
59
81
59
60
60
58
83
80
81
51
Recovery
RPD
(%)
3
1
8
4
5
0
2
4
0
1
1
1
1
0
0
2
1
Recovery Is calculated as( (cone, found-background conc.yspika conc.)MOO
• » values from second column confirmation.
-------
APPENDIX G
PAH Analytical Lab Raw Data Results
-------
G-l
PAH Results Summary
G-1
-------
Table G-1T Run 2 PAH Results - Stack Gas Concentrations (ng/sample, as measured)
Acenaphthene
<20
160
160
Acenaphthylene
<20
1700D,J
1700 D,J
Anthracene
<20
210 J
210 J
Benzo{a)anthracene
53
83
136
Benzo(b)fluoranthene
350
860
1210
Benzo(k)fluoranthene
270
840
1110
Benzo(g,h,i)perylene
Benzo(a)pyrene
210
130
110
(20)
340
110
Benzo
-------
Table G-2T Run 3 PAH Results - Stack Gas Concentrations (ng/sample, as measured)
^ . f^fe.-
PAH Congener - ^*jww&*'&gi££
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(g,h,i)perylene
Benzo(a)pyrene
Benzo(e)pyrene
Chrysene
Dibenzo(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1 ,2,3-c,d)pyrene
2-Methylnaphthafene
Naphthalene
Perylene
Pyrene
Phenanthrene
<20
<20
<20
<20
120
92
120
53
640
77
51
33
<20
170
37
530 B
<20
27
- <64
On,{ng/sample,as
1^5frliP'|^!
130
2000 E,J
82 J
390
910
470
89
NQ
540 J
2000 E
25
3600 E
1700 E
88
30000 D.E.B
380000 D.E.B
NQ
2400 E
33000 D.E.B
measured)$fci
felTotkl-Wi
130
2000 E,J
82. J
390
1030
562
209
53
1180J
2080 E
76
3630 E
•1700-E
258
30000 D.E.B
381000D.E.B
NQ
2430 E
33000 D.E.B
3 ng/sample; nanogram per sample.
Standard conditions: temperature - 20 C; pressure -1 atm (760 mm Hg).
Note: (Below Detection Limit) values listed in parentheses and {EMPC} values listed in
brackets.
E = value above calibration range
B = congener found in blank at greater than 20% of the concentration found in the
samples
D = based on dilution
NQ= d,2-benzo(a)pyrene recovery in Sample Run 4 was too low to quantify the compound.
Maximum concentration of the compound is estimated by quantitation of benzo(e)pyrene
at 270 ng.
G-3
-------
Table G-3T Run 4 PAH Results - Stack Gas Concentrations (ng/sample, as measured)
.--••-.- , . • -..sfea
V ~-r ,-- ...*"'? * ' e. ""''Wi
?PAH Congenlr '" "-.y" ;-'lP
Acenaphthene
Acenaphthylene
Anthracene
Benzola)anthracene
Benzo(b)fluoranthene
Benzo{k)fluoranthene
Benzo{g,h,i)perylene
Benzo(a)pyrene
Benzo{e)pyrene
Chrysene
Dibenzo(a,h)anthracene
Fluoranthene
Fluorene
Indenod ,2,3-c,d)pyrene
2-Methylnaphthalene
Naphthalene
Perylene
Pyrene
Phenanthrene
• *^^^^^P^trati
<20
<20
<20
<20
96
37
<20
<20
270'
43
21
23
<20
29
27
440 B
<20
<20
<20
!
•J'
26
260 J
93
82
170
120
85
NQ
120 J
440
<20
910
130 .
45
1300DJ
210000D,E,B
57 J
490
8000 E,B
26
260 J
93
82
266
157
85
NO
390 J
483
21
933
130
74
1327 I
210000 D.E.B 1
i
57 '
b/ , i
49(5 ]
8000 E,B J
* ng/sample; nanogram per sample.
Standard conditions: temperature - 20 C; pressure - 1 atm (760 mm Hg)
Note: (Below Detection Limit) values listed in parentheses and {EMPC} values isted
brackets.
E = value above calibration range
B = congener found in blank at greater than 20% of the concentration found in thr
samples
D = based on dilution
NQ = d12-benzo(a)pyrene recovery in Sample Run 4 was too low to quantify the
compound. Maximum concentration of the compound is estimated by quarttitatic
of benzo(e)pyrene at 270 ng.
G-4
-------
G-l-1
Air Sample Fractions
G-S
-------
PAH Laboratory Air Results Summary Table G-l
PAH Front Half Fractions in ng/sample
Battetta tO
Analysis date
Congener
Acenaphlhena .
Acenaphthytene
Anthracene
Banzo(a)anthracana
Benzo(b)fluoranthene
BenzolMfluoranthane
Banzolg.h.ilperylene
Benzofalpyrene
Bonzofolpyrene
Chrysen*
Dit»nzo|a,h)anthrBce
na
Fluorantharm
Ruorene
lndeno|1,2,3-
c,d)pyrene
2-Methytnaphthalene
Naphthalene
Parylene
Pyrene
j Pherwnthrone
Run 2
48190-11-02
8-16-99
Concentration
< 20
< 20
< 20
53
350
270
210
110
(2000)
2QO
85
S3
< 20
260
40
{1700)
< 20
43
130
Q
U
U
U
E
U
E
U
B
Reporting
Limit
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
100
20
70
64
Run 3
481 §0-1 1-03
8-16-99
Concentration
< 20
< 20
< 20
< 20
120
92
120
53
640
77
51
33
< 20
170
37
530
< 20
27
< 64
Q
U
U
U
U
U
U
U
Reporting
Limit
20
20
2O
2O
20
20
20
20
20
20
20
20
20
20
20
1OO
20
20
64
Run 4
48190-11-04
8-18-99
Concentration
< 20
< 20
< 20
< 20
96
37
< 20
< 20
270
43
21
23
< 20
29
27
440
< 20
< 20
< 20 •
Q
U
U
U
U
U
U
U
U
U
U
Reporting
Limit
2O
20
20
20
20
20
20 •
20
20
20
20
20
20
20
20
100
20
20
64
9
a»
-------
PAH Laboratory Air Results Summary Table G-l
PAH Front Half Fractions in ng/sample
Battalia ID
Analysis date
Internal Standard •
Acenaphthene-rf 1 0
Acenaphthylene-dS
Benzolalanthraccne d1 2
Benzo!a)pyrerw-d1 2
Benzo(b)fluor8nlher»8-d1 2
Benzo(g,h,i|pBrylBne-d12
Benzo(k)fluoranthene-d1?
Chrys«ne-d12
Dibenzo(a,hlanthracerve-d14
Fluoranthene-dIO
Fluorene-dlO
Indenod ,2,3-c,d)pyrene
Naphthalene-d8
f*erylene-«J1 2
Phenenthrene-d10
Pyrene-d10
Run 2
48190-11-02
8-16-99
% Recovery
74
56
71
17
102
74
86
97
85
94
87
84
87
32
82
90
Q
&
&
Reporting
Limit
50-150
50-150
50-150
50-150
50-1 50
50-150
50-150
50-150
50-1iO
50-150
50-150
50-150
50-1 50
50-150
50-150
50-150
Bun 3
48190-11-
03
8-16-99
% Recovery
79
50
74
22
107
83
97
102
96
102
97
93
86
18
92
96
Q
*
ft
Reporting
Limit
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-1 50
50-150
50-150
50-150
50-150
50-150
50-150
50-1 50
50-150
Run 4
48190-11-04
8-16-99
% Recovery
75
64
62
21
89
81
103
109
78
133
79
87
88
29
69
124
Q
&
&
Reporting
Limit
50-150
50-150
50-150
50-150
50-150
50-150
50150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
o
NO, U *! Not Detected, or below reporting limit.
f = value from confirmation column.
St = outside QC limits.
NA = not applicable. '
J = estimated value, below detection limit.
I) = EMPC value.
E= exceeds calibration range. ., ,
B- method blank contained the target anilyte at a reportible level
-------
PAH Laboratory Air Results Summary Table G-2
PAH Back Half Fractions in ng/sample
BatteR* ID
Analysis date
Congener
Acanaphthene
Acenaphthylene
Anthracene
Banzo(a)onthraceno
Benzolblfluoranthene
Benio{k)fluoranthene
Benzo(g,h,ilperylene
Banzo(a)pyrene
BenzoMpyrana '
ChryMiw
Dibenzo|a,hlanthracene
Fluoranthene . ..
Fluorene
Indenol 1 , 2 ,3-c.dl py rene
2-MethyloBphthalene
Naphthalene
' Peryiene
s
• "-Vi'ane
Run 2
48190-09-02
8- 16-99
Concentration
160
1700
210
83
860
840
130
< 20
7200
3300
20
3900
1500
97
32000
450000
370
2800
Q
D
J
A
E
J
A
E
E
E
D
E
B
D
£
a
j
A
'-
Reporting
Limit
20
20
20
2O
20
20
20
20
20
20
20
20
20
20
20
7.0
Run 3
48190-09-03
8-16-99
Concentration
130
2000
82
390
910
470
89
NO
9700
2000
25
3600
1700
SB
30000
380000
NO '
2400
Q
E
J
A
J
A
E
J
A
E
E
E
D
E
B
D
B
E
r
Reporting
Limit M
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
Run 4
48190-09-04
8-16-99
Concentration
26
260
93
82
170
120
85
NO
NQ
440
< 20
910
130
45
1300
210000
57
490
Q
J
A
D
B
D
E
a
,i
A
Reporting
Limit
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
9
09
-------
PAH Laboratory Air Results Summary Table G-2
PAH Back Half Fractions in ng/sample
Bundle ID
Analysis date
Intertill Standard
Acenaphthene-d 1 0
Acenaphthylene-dB
Benzo|a!anthracene-d1 2
Benzo(a)pyrene dl 2
BenzolbHIuorantheno-d 1 2
Benzo
-------
G-2
PAH Blank Lab Summaries
G-10
-------
PAH Field Air Blank Laboratory Results Summary Table G-3
PAH Field and Proof Blank Fractions ng/sample
Battelle ID
Analysis Date
Congener
Acanaphthena
Acanaphthylene
Anthracene
Benzolalanthracene
Benzolbl f luoranthe ne
BenzolMftuoranthene
Benzo(g,h,i)perylene
Benzolalpyrene
Benzo(e)pyrerw)
Chrysene
Dibenzo(a,h)anthracena
Fluorarrtrwne
Fluorene
Indenot 1 ,2,3-c,d)pyrena
2-MethvlnaphthBlene
Naphthalene
j
j Porylena
: Pyrene
'. P!vsr.anthrer.fi
Flsld Proof
Blank Initial
BH-PB1-PAH
481900905
8-21-99
Concentration
< 20
< 20
< 20
< 20
< 20
< 20
29
< 20
< 20
< 20
< 20
21
< 20
< 20
< 470
210
< 20
26
~ ''
Q
U
U
U
U
U
U
U
U
U
U
U
U
U
J
B
J
U
,_. 1
f
Reporting
Limit
20
20
20
20
20
20
20
20
20
20
20
20
20
20
120
470
20
20
120
Field Proof
Blank Final
FH-PB2-PAH
48190-11-06
8-23-99
Concentration
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
58
350
< 30
<. 20
Li*4
F
Q
U
U
U
U
U
U
U
U
U
U
U
U
U
U
B
U
U
J
Reporting
Limit
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
100
20
20
64
Field Proof
Blank Final
BH-PB2-PAH
48190-09-06
8 21-99
Concentration
< 20
< 20
< 20
< 20
< 20
< 20
69
< 20
< 20
< 20
< 20
37
< 20
< 20
< 120
< 470
< 20
58
*•- 120
O
U
U
U
U
U
U
U
U
U
U
U
U
J
J
U
J
Reporting
Limit
20
20
20
20
20
20
20
20
20
20
20
20
20
20
120
470
20
20
120
-------
PAH Field Air Blank Laboratory Results Summary Table G-3
PAH Field and Proof BFaiik'Fractions ng/sample
Battalia ID
Analysis Date
Congener
AcenaphtHene-dl 0
Acenaphtbylerta-d8
Banzd(a)anthraeene-tJ1 2
Benzo(a) pyrene-d 1 2
Benzo(b)fluoranthene-d12
Benzofg.h.ilperylene-dl 2
Benzo(k)fluoranthene-d1 2
Chrysene-d12
Dlbenzo|a,h)anthracene-d1 4
Fluoranthene-dIO
Fluomne-dlO
Indenol 1 ,2,3-e,dlpyrene-d1 2
Naphthalene-dB
Porylene-dl 2
Phenanthrene-d 1 0
Pyrene-d 10
13C6-Fluorena
Field Proof
Blank Initial
BH-PB1-PAH
48180-09-05
8-21-99
% Recovery
111
96
97
97
102
92
109
121
90
103
84
94
91
100
78
103
61
O
Reporting
Limit
50-150
50 150
80-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50 150
50 150
50-150
50-150
50-150
50-150
Field Proof
Blank Final
FH-PB2-PAH
48190-11-06
8-23-99
% Recovery
80
68
72
76
97
82
97
102
84
86
73
83
74
80
68
84
NA
Q
Reporting
Limit
50-150
50-150
50-150
5O-150
50-1 50
50-150
50-150
50-1 50
50-150
50-150
50-150
50-150
50-150
50-150
50-1 50
50-150
Fl9ld Proof
Blank Final
BH-PB2-PAH
48190-09-O6
8-21-99
% Recovery
94
89
95
98
105
85
102
116
85
86
83
89
77
95
70
86
69
Q
Reporting
Limit
50-150
50-150
50-150
50-1 50
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
9
—i
to
U - Not Detected, or below reporting limit.
9 = value from confirmation column.
& = outside QC limits.
Q - Qualifier. , ... .
D = Result reported Is analysis of a dilution,
E = Estimated result, reported concentration exceeds the calibration range.
B ** method Blank contamination of target analyte at concentration above reporting level.
J - Estimated value, below detection limit.
NA = Not applicable.
E = value ovar calibration range
-------
PAH Field Air Blank Laboratory Results Summary Table G-3
PAH Field and Proof Blank Fractions ng/sample
Battefle ID
Analysis Date
Congener
Aeenaphthene
Acenaphthylene
Anthracene
Benzofalanthracene
Benzolbjfluoranthene
Benzo(k|fluoranthena
BenzolgAOperylnne
Benzo(a)pyrene -
Benzolelpyrene
Chrysene
Dlbenzols.hlanthracenfl
Fluoranthene
Fluorena
Indenod ,2,3 e.dlpytene
2-Mathy (naphthalene
Naphthalene
Perylene
| Pyrene
i Phenanlhrunf^
Held Train
Blank
FH-FB1
48190-11-07
8-21-99
Concentration
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
36
< 20
< 20
< 20
< 100
< 20
2'
68
O
U
u
U
u
u
u
u
.u-
u
u
u
u
u
u
J
u
B
Reporting
Limit
20
20
20
20
20
20
20
20
20
20
20
20
20 .
20
20
ioo
20
20
64
Field Train
Blank
BH-FB1
48190-09-07
8-23-99
Concentration
< 20
< 20
< 20
< 20
< 20
< 20
67
< 20
25
< 20
< 20
50
< 20
< 20
< 120
< 470
< 20
55
< 120
Q
U
U
U
U
U
U
u
u
u
u
u
J
J
u
J
Reporting
Limit
20
20
20
20
20
20
20
20
20
20
20
20
20
20
120
470
20
20
120
Field Proof
Blank Initial
FH-PB1
48190-11-05
8-21-99
Concentration
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
53
440
< 20
< 20
< 64
O
U
u
u
u
u
u
u
u
u
u
u
u
u
u
B
u
u
a
Reporting
Limit
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
100
20
20
64
9.
CJ
-------
PAH Field Air Blank Laboratory Results Summary Table G-3
PAH Field and Proof Blank Fractions ng/sample
Buttntle ID
Analysis Date
Congener
Acenaphthena-d 1 0
Acenaphthylene-d8
Banzolalinthraeene-dl 2
Benzo(a)pyrene-d1 2
Benzo(b|fluoranthene-d1 2
8enzo(g,h,ilnerylene-d 1 2
Ben2o(k)fluoranthene-d1 2
Chrysene-d12
Dibenzola.hlanthracene-d 1 4
Fluoranthehe-dlO
FIuorene-d10
Indeno(1,2,3-e,d)pvrene-d12
Naphthalene d8
Perylena-d12
Phenanthreno d1 0
Pywne-dlO
1 3C6-Fluorene
Field Tram
Blank
FH-FB1
48190-11-07
8-21-99
% Recovery
96
81
78
71
110
92
103
103
87
94
78 ,
95
87
50
76
92
NA
Q
QC Reportinq
Limit
50-150 .
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-1 50
50-150
50-150
50-150
50-150
Field Train
Blank
BH-FB1
48190-09-07
823-99
% Recovery
95
86
83
88
104
110
104
111
119
99
77
114
78
91
71
95
62
Q
QC Reporting
Limit
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
Field Proof
Blank Initial
FH-PB1
48190-11-05
8-21-99
% Recovery
83
73
81
88
100
97
106
110
97
94
77
99
76
89
79
87
NA
Q
QC Reporting
Limit
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50:150
50-150
50-150
50-150
50-150
50-1 50
50-150
50-150
50-150
U = Not Detected, or below reporting limit,
it = value from confirmation column.
& = outside QC limits,
Q = Qualifier.
E = Estimated result, reported concentration exceeds the calibration range,
§ = method Blank contamination of target analyte at concentration above reporting level.
J = Estimated value, below detection limit.
-------
PAH Laboratory Air Blank Results Summary Table G-4
PAH Laboratory and Spike Blank Fractions ng/sample
Battalia ID
Analysis Date
Congener
Acenaphthene
Aoensphthylene
Anthracene
Benzo(a(anthracene
Beruo(b) f luoranthene
Barao(k) f luoranthe ne
Benzolg, h.ilperylene
Banzolalpyrene
Benzolelpyrene
Clwysana
Dibenzo(a,h)anthracene
Fluoranthene
Fluorene
lndeno|1 ,2,3-c,d)pyrene
2-Methvlnaphthalene
Naphthalene
I Peryiene
" Pyrene
; Phenarrthrnns
Lab Train
Blank
FH-LB-PAH
48190-11-10
8-21-99
Concentration
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
21
< 20
< 20
< 2C
Q
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Reporting
Limit
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
2C
L2° H
lab Train
Blank
BH-LB-PAH
48190-09-11
8-23-99
Concentration
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
< 20
25
94
< 20
< 20
75
Q
U
U
U
U
U
U
U
U
U
U
U
U
.U
U
U
U
Reporting
Limit
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
Lab Control
Spika Blank
FH-LCS-PAH
48190-11-08
8-21-99
Concentration
150 •
180
260
200
200
190
200
.190
220
200
200
220
210
170
180
250
200
210
210
Q
8
B
Reporting
Limit
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
100
20
20
64
D
mm*
01
-------
PAH Laboratory Air Blank Results Summary Table G-4
PAH Laboratory and Spike Blank Fractions ng/sample
Battalia ID
Analysis Date
Congener
Acenaphthene-d1 0
Acenaphthylene-dB
Benzolalanthracene-dl 2
Benzo(a)pyrene-d 1 2
Benzo(blfluoranthene-d1 2
Benza(g,h,t)perylene-d1 2
Benzo(k)fluoranthene d1 2
Chrysene-d 1 2
0ibenzo(a,h)anthr8cene-d14
Fluoranthena-dl 0
Floors ne-d 10
lndano(1 ,2,3-e,dipyrene-d1 2
Naphthalene -d8
Perylena-d1 2
Phenanthrene-d1 0
Pyrene-d10
Lab Train
Blank
FH-li-PAH
48190-11-10
8 21-99
% Recovery
94
91
79
76
91
83
93
109
74
94
76
80
92
78
62
96
a
QC Reporting
Limit
50-1 SO
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-1 50
50-150
50-150
SO- ISO
50-150
50-150
50-150
50-150
Lab Train
Blank
BH-LB-PAH
48190-09-11
8-23-99
% Recovery
97
97
65
79
81
86
109
135
67
130
78
79
100
86
66
123
Q
QC Reporting
Limit
50-150
50-1 50
50-150
50-1 50
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-1 50
50-150
50-150
Lab Control
Spika Blank
FH-LCS-PAH
48190-11-08
8-21-99
% Recovery
108
99
81
89
97
110
107
113
102
100
66
112
99
89
65
102
Q
QC Reporting
Limit
50-1 50
50-150
50-150
50-150
50-150
50-150
50-1 50
50-150
50-150
50-150
50-1 50
50-150
50 150
50-150
50-1 50
50-150
o
<
Ol
U = Not Delected, or below reporting limit,
f - value from confirmation column.
& = outside QC limits.
Q = Qualifier.
NA - Not applicable. . ...
B = Method Blank contamination of target analyte at concentration above the reporting level.
E = value over calibration range.
-------
PAH Laboratory Air Blank Results Summary Table G-4
PAH Laboratory and Spike Blank Fractions ng/sample
BattaR* ID
Analysis Date
Congener
Acenaphthene
Acermphthylene
Anthracene
Benzolalenthracene
Benzo(b)ftuorantrwne
Benzo(k}iluorantrmrw
Benzo(g,M)p«ryl«ne
Beniofatpyrena
Benio(e)pyrena
Chrysene
Dibanzo(a,h)anthracene
Fluoranthene
Fluorene
lndeno(1,2,3-c,d(pyrene
• Naphthatar.s
; Perylen:
• r>yrerie
' PhersHnthre^'j
Lab Control
Spike Blank
BH-LCS-PAH
48190-09-09
8-21-99
Concsntration
170
180
250
200
200
200
190
200
210
190
210
220
230
190
?1O
< 47C
200
2 ) '•' •
Q
B
"
Reporting
Limit
20
20 .
20
20
20
20 .
20
20
20
20
20
20
20
20
1 20
i_ii£ _
?0
•>:^\
•, :->o
Lab Control Splka
Blank Duplicate
FH-LCSDUP-PAH
48190-11-09
8-23-99
Concentration
170
1BO
250
190
210
200
210
200
220
210
200
210
250
200
190
?40
200
.110
flic
Q
{?
n
»^
Reporting
Limit
20
20
20
20
20
20
20
20.
20
20
20
20
20
20
20
IOC
20
20
64
Lab Control Splka
Blank Duplicate
BH-LCSDUP-PAH
48190-09-10
8-21-99
Concentration
150
170
200
190
170
200
190
190
230
180
190
200
230
170
200
< 470
190
190
710
Q
B
j
B
Reporting
Limit
20
20
20
20
20
20
20
20
20
20
20
20
20
20
120
470
[IL i
20
"li'O
-------
PAH Laboratory Air Blank Results Summary Table G-4
PAH Laboratory and Spike Blank Fractions ng/sample
Battelle ID
Analysis Date
Congener
Acenaphthene-d10
Acenaphihylene-d8
Benzotelanthraeene-dl 2
Benzo(a)pyrene-d1 2
Benzo(b)fluoranthene dl 2
Benzo(g,h,i)pery!ene-d1 2
BenzO(k|fluoranthene-d1 2
Chry»Br»-d12
Dibenzo(a,h)anthracena-d14
Fluoranthene-d1 0
Fluor ene-d 10
tndeno(1,2,3-c,dlpyrane-d12
Naphthalene-d8
Perylene-d12
Phcnanthrene-<11 0
Pyrene-dIO
Lab Control
Spike Blank
BH-LCS-PAH
48190-09-09
8-21-99
% Recovery
109
98
91
93
99
98
106
114
99
106
88
99
92
91
76
102
Q
QC Reporting
Limit
50-150
50-150
50- ISO
50-150
50-150
50-150
50-150
50-1 50
50-150
50-150
50-150
50-150
50-1 50
50-150
50-150
50-1 50
Lab Control Spike
Blank Duplicate
FH-LCSDUP-PAH
48190-11-09
8-23-99
% Recovery
97
95
89
86
97
84
98
102
79
98
70
85
86
87
67
95
Q
QC Reporting
Limit
50-150
50 150
50 150
50-150
50-150
50 150
50-150
50-1 50
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
Lab Control Spike
Blank Duplicate
BH-LCSDUP-PAH
48190-09-1O
8-21-99
% Recovery
100
89
86
81
100
87
98
111
86
102
93
89
89
76
83
98
Q
QC Reporting
Limit
50-150
^0 150
50-150
50-150
50-150
50-150
50-150
50-150
50-1 50
50-1 50
50-150
50-1 50
5O-150
50-150
50-150
50-150
o
—»
00
U = Not Detected, or below reporting limit.
» — value from confirmation column.
& = outside QC limits.
Q «= Qualifier.
B = Method Blank contamination of target analyte at concentration above the reporting level.
NA = Not applicable.
E = value over calibration range
-------
#uanferra
Quanterra Incorporated
880 Riverside Parkway
West Saenmento, Caa/bmta 95605
916 373-
9J6 372-1059 fine
September 7,1999
QUANTERRA INCORPORATED PROJECT NUMBER: G9G200205
PO/CONTRACT:
Tony WIsbith
Battelle
505 King Avenue
Room 6325
Columbus, OH 43201-2693
DearMr.Wisbith,
This report contains the analytical results for the samples received under chain of custody
Quanterra Incorporated on 7/16/99 and 8/11/99. These samples are associated with your
G469005-06 project
The case narrative is an integral part of this report.
If you have any questions, please feel free to call me at (916)374-4333.
Sincerely,
Robert Weidenfeld
Project Manager
G-19
-------
TABLE OF CONTENTS
QUANTERRA INCORPORATED PROJECT NUMBER G9G200205
Case Narrative
Quanterra's Quality Assurance Program
Sample Description Information
Chain of Custody Documentation
AIR, CARS 429 MOD, Hydrocarbons, Polycyclic
Performed at Quanterra - West Sacramento
Samples: 1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20
Sample Data Sheets
Method Blank Reports
Laboratory QC Reports
Raw Data
6-20
-------
CASE NARRATIVE
QUANTERRA INCORPORATED PROJECT NUMBER G9G200205
CARB 429 MOD, Hydrocarbons, Polycyclic
The samples were received at Quanterra as extracts ID two deliveries. These samples-
were spiked and extracted by Battelle using field surrogate .(FS), intemal standards (IS), anr!
native standards (NS) supplied by Quanterra. A spiking table -was sent by Quanterra that
noted the recommended spiking levels for each standard based on the 6/22/99 fax.
information that Quanterra would receive 25% of each sample extract A notation of spike
amount was written on the COC for the first delivery group and indicated 200ng of IS per
sample. No further notation of spiking amount, sample split, or other extraction informatio
was included. All recovery calculations were based on this Information. The first deliver
group containing two .samples was spiked with a different FS and IS mix that the other
eighteen samples. A method Blank and Laboratory control sample were generated by
Quanterra and processed with the samples through all cleanup and analysis steps perform^
at Quasterra,
The field surrogate was analyzed for in all samples but only samples 3 through 8 had the
surrogate detected.
The first shipment was received at -20 degrees C with dry ice and the second batch was
received at 20 degrees C with a blue ice pack.
The client requested that a reporting limit convention be used mat incorporates the use of
combination of the lower calibration limit (LCL) and the level found in the Lab Blanks
supplied by Battelle. The reporting limit for any analyte found in the Lab Blank at a teve
greater than one-half the LCL was rasied to SX the blank level. All other analytes used tb
LCL as the reporting limit.. Positive results in samples below this reporting limit are to CK
given the T qualifier to indicate that they are estimated. Samples 3-10 were reported usirs?
sample 11 as the blank and samples 12-19 were reported using sample 20 as the blank
Samples 1 and 2 were spiked with a different internal standard and recovery standard m
from an older calibraion curve. The relative response factor from a single-point CS-3
standard from the older curve were used to quantitate the two samples in questions Sample
1 and 2 used the method Blank generated by Quanterra for the extract and final cleanup step,
as a basis of its reporting limit No levels were found in the Method blanks so all the
reporting limits are at 20ng/sample.
Several samples had intemal standard recoveries below 50 p5t»nt The samples affected b>
these recoveries are as follows:
G-21
-------
CASE NARRATIVE
QUANTERRA INCORPORATED PROJECT NUMBER G9G200205
•3: d8-Acenaphthylene, dl2-Benzo(a)anthracene, d!2-Perylene, dl2-Benzo(ghi)perylene and
dl2-beazo(a)pyrene. .
-4: d8-Aeenaphthylene, dl2-Benzo(a)anthraeene, dl2-Perylene (no recovery-native cannot
be quantitated), dl2-benzo(a)pyrene» and d!2-Benzo(ghi)peiylene.
-5: d8-Acenaphthylene, dl2-Benzo(a)aninraeene, dl2-Perylene, d!2-Benzo(a)pyrene (no
recovery-natives cannot be quantitated for Benzo(a) or Benzo(e)pyiene),
-12: d!2-Benzo(a)pyrene and dl2-Perylene.
-13: d!2-Benzo(a)pyrene and d!2-Perylene.
-14: d!2-Benzo(a)pvreen and dl2-Perylene.
The very low recovery of the dl2-benzo(a)pyrene in sample -4 did not allow the quantitation
of Benzo(a)pyrene and the quantitation of Benzo(e)pyrene should be considered a maximum
possible concentration. The low recovery of this same internal standard would not allow for
the quantitation of Benzo(a)pyrene or Benzo(e)pyrene in sample 5. In most other cases,
sensitivity and signal-to-noise ratio were adequate to detect the native compounds associated
with the affected internal standards at their reporting limits. The exception is Perylene in
sample -4, as noted above. Re-extraction of these air train samples was not possible because
the entire extract was consumed in the initial processing.
Samples 3,4, and 5 each have one or more saturated analyte in the data from the initial
analysis. All three samples were diluted and reanalyzed for the affected compounds, which
are flagged with a "D" footnote and the reporting limit raised accordingly. Sample 3 and 4
were diluted 20X and sample 5 was diluted 1 OX.
Low level concentrations of Benzo(g,h4)perylene were detected in samples 6-8.
There were no other anomalies associated with this project
G-22
-------
Quanterra - Western Region
Quality Control Definitions
QC Batch
A set of up to 20 field samples plus associated laboratory QC
samples that are similar in composition (matrix) and that are
processed within Ac same time period with the same reagent
and standard lots.
Duplicate Control Sample
(DCS)
Consist of a pair of LCSs analyzed within die same QC batch
to monitor precision and accuracy independent of sample
matrix effects. This QC is performed only if required by
client or when insufficient sample is available to perform
MS/MSD.
Duplicate Sample (DU)
A second aliquot of an environmental sample, taken from the
same sample container when possible, mat is processed
independently with the fust sample aliquot "The results are
used to assess the effect of the. sample matrix on the precision
of the analytical process. Hie precision estimated using this
sample is not necessarily representative of the precision for
other samples in the batch.
'Laboratory Control Sample
(LCS)
Matrix Spike and Matrix Spike
Duplicate (MS/MSD)
Method Blank (MB)
Surrogate Spike
A volume of reagent water for aqueous samples or a
contaminant-free solid matrix (Ottawa sand) for soil and
sediment samples which is spiked with known amounts of
representative target analytes and required surrogates. An
LCS is carried through die entire analytical process and is
used to monitor the accuracy of die analytical process
independent of potential matrix effects.
A field sample fortified with known quantities of target
analytes that are also added to die LCS. Matrix spike
duplicate is a second matrix spike sample. MSs/MSDs are
carried through the entire analytical process and are used to
determine sample matrix effect on accuracy of die
measurement system. The accuracy and precision estimated
using MS/MSD is only representative of the precision of the
sample mat was spiked.
A sample composed of all the reagents (in the same
quantities) in reagent water carried titrough the entire
analytical process. .The method blank is used to monitor the
level of contamination introduced during sample preparation
steps.
Organic constituents not expected to be detected in
environmental media and are added to every sample and QC
at a known concentration. Sunogates are used to determine
die efficiency of the sample preparation and the analytical
process. '
Source: Quanterra® Quality Control Program, Policy QA-003, Rev, 0,1719/96.
-------
Sample Summary
G9G200205
WO# Sample #
-D09KN 1
D09KQ 2
D19W6 3
D19W8 4
D19W9 5
D19WA 6
D19WC 7
D19WD 8
D19WE 9
D19WF 10
D19WG 11
D19WH 12
D19WJ 13
D19WK 14
D19WL 15
D19WM 16
D|19WN 17
D19WP 18
D19WQ 19
D19WR 20
Client Sample ID
48200-51-02
48200-51-03
48190-09-02
48190-09-03
48190-09-04
48190-09-05
48190-09-06
48190-09-07
48190-09-09
48190-09-10
48190-09-1 1
48190-11-02
48190-11-03
48190-11-04
48190-11-05
48190-11-06
48190-11-07
48190-11-08
4819041-09
48190-11-10
XAD
tte**>a
BH 1
Bl-^k
"5t-^^
?X
BK . R3
BH
BH
BH
BH
BH
BH
PH
FH
FH
FH
FH
FH
FH
FH
FW
FH
RM
FBI
PB^IL
FBI
l_«!5
LCS P
L-b 23
RL
'1? S
K ^
FB/
P6-Z.
F8J
/.cs
tcs ?
L*!» I
Sampling Date Received Date
7/14/99 11:00 AM
7/14/99 11:00 AM
7/16/99 10:00 AM
7/16/99 10:00 AM
8/11/99 08:40 AM
8/11/99 08:40 AM
8/11/99 08:40 AM
8/11/99 08:40 AM
8/11/99 08:40 AM
8/11/99 08:40 AM
8/11/99 08:40 AM
8/11/99 08:40 AM
8/11/99 08:40 AM
8/11/99 08:40 AM
mi/99 08:40 AM
8/11/99 08:40 AM
8/11/99 08:40 AM
8/11/99 08:40 AM
8/11/99 08:40 AM
8/11/99 08:40 AM
8/11/99 08:40 AM
8/11/99 08:40 AM
Notes(s):
The analytical results of the samples listed above ire prejenU-d on the following pages.
All calculations ire performed before rounding to tvoM iMBUi-off ewors hi calculated results.
Results noted M "ND" were IKK delected «t or above the staled limit
This report must no be reproduced, except in fiill, without the written approval of the laboratory.
Results for the following parameters are never reported oa I dry weight basis: color, corroiivity, density, flashpoint, Ignltability,
layers, odor, paint filter test, pH, porosity, pressure, reactivity, rcdox potential, specific gravity, spot tests, solids, solubility,
temperature, viscosity, and weigh
G-24
-------
Osattelle
Columbui Option.
505 King *cnu«
Cohimboi, Ohto WOi-im
(61414244247
.';
.I,..'.-
PCDD/PCDF/PCB
CHAIN OF CUSTODY RECORD
Ni 000290
Cflmt:
,' r1 -. ,y/ • / Prejad Oauriptlon:.,.-_; i
CRantlD
Number
9«mpltd
HIM
3tmp»td
Location
No. Coflltlnera
RamarkB/CondHlon Upon Receipt
•o-i
.AH
05
f*
M
-------
OBaltelle PCDD/PCDF/PCB N« 000288
Columbus Dlflslon PCDU/PUUP/PUB
?5, ""? *Tsi ™« «« CHAIN OF CUSTODY RECORD
Columbus, Ohio 43WMH3
<6tt» 424-4247
Client:
U\//} - |o S
Client ID
Number
ffMo-ovoa
*/
03
«H
OS
ou
«?
o«l
10
7 ; n
Date
Sampled
Relinquished by (Signature)
"^3L^*"'^- .-"»—«-«,
f&T
— r- -r
Time
Sampled
Date
Project Description:
Location
Q\\ e^"^
OH it»"ll3
flu **« •* H
fr^r 13,^ it, OM
f<"M* <3l«.^K ^} OH
ft*\l) ^Itt^'C ' C>^
LcS
AH
LCS Ov/. ftH
L^O (3l«»^K» fSH"
Time
|f «/ft*CA
(Printed)
mrt/tK A^11i^i''«v
Recehnd for Laboratory by (Signature)
Date
Received by (Signature)
(Printed)
Jfe-
TV! n,,i
(Printed) \ tfj I j ' ' ^
No. Containers
N
\
1
1
1
1
I
f
1
Date
, Samples Disposed of by:
Time
Date
Method of Disposal:
Remarks/Condition Upon Receipt
/V3&'»H- Oc-n
RECEIVED IN r,QCD COr.'WTION
UNDER COC
Alll* ! 1 rTll
AUU I _i rj-i'J
/^b
Relinquished by (Signature) Date Time
(Printed) ,
Analyses Requested:
Wh(f»-Wtlh SaimlM. Yalow-LitNMftHV. Pbik-FMrf
-------
OBaiteiie
Cotumbuf Division
SOS King Avenue
Cokimbm, Ohio 43201-2693
(614)4244247
PCDD/PCDF/PCB
CHAIN OF CUSTODY RECORD
N? 000282
OUflt:
Project Description:
OJwrtlD
Date
Sunpted
Tim*
Sampled
No. Containers
RemirWCondKkm Upon Receipt
00
FftH fhufii/i
PAW fhulio/t in P,a»Um
a
/i,
**«% F**. '
Reflnqtrfihed by (Signature)
(Printed'
Date
Time
Received by (Signature)
Oit»
Tim*
«*rtntec«
r|rr*
Samples Disposed of by:
Rellm|til»hBd by (Slgnshire)
Date
Time
(Printed)
Date i IrwIvMt Reouested:
/i .idL
Method of Disposal:
-------
CARB 429 MOD, HjHrocarkns, Polycydic
G-28
-------
BA.TTKLLH
Hydrocarbons, Polycyclic Aromatic (HRSC/HUMS
Client Sample ID: 48200-51-02
anterra
Lot-Sample #...:
Date Sailed. . . :
Prep Bete .8
Prep Batch t...:
Dilution Factor:
G9G20C205-001
7/14/99
8/16/95
9228155
1
Work Order §...: D09KN101
Date Received..i 7/16/99
Jtnmlysii Date..: 8/25/99
Instrument.
Matrix.
i AZS
PARAMETER RESULT
Acenaphthene HD
Acenaphthy1ene HD
Anthracene HD
Benzo(a)anthracene HD
Benzo(b)fluoranthene HD
Benzo(k)fluoranthene HD
Benzo(ghi)perylene HD
Benzo(a)pyrene HD
Benzo(e)pyrene HD
Chrysene HD
Dibenz(a,h)anthracene HD
Fluoranthene HD
Fluorene - HD
Indeno(1,2,3-0d5pyrene ND
2-Methylnaphthalene ND
Naphthalene 150
terylene * HD
Pyrene j ND
Phenanthrene 2 0
PERCENT
INTERNAL STANDARDS RECOVERY
Acenaphthene-dlO 114
Aeenaphthylene-dS 96
Benzo(a)anthracene-d!2 85
Benzo(a)pyrene-d!2 101
Benzo(b)fluoranthene-dl2 100
Benzo(ghi)perylene-d!2 98
Benzo(k)fIuoranthene-dl2 ill
Chrysene-dl2 • 117
Dibenz(ah)anthracene-dl4 87
Fluoranthene-dlO ill
Fluorene d-10 88
Indeno(1,2,3-cd)pyrene-d!2 SS
Naphthalene-dS 109
Perylene-dl2 ' 86
Phenanthrene-dlO 82
Pyrene-dlO 107
HOTB31 | ' • •' . - -' '
CBiculatioBSt-fcx* p»rfor»»d b«faz« rouiwtlnsr to mvoid round-off •rrora t»iri1rrn1it>-1 r««ult«
REPORTING
LIMIT
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
CHITS
Bg
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
-ng
ng .
ng
ng
ng
ng
ng
ng
RECOVERY
LIMITS
50 -
50 '-
50 -
50 -
50 -
'SO -
50 -
50 -
50 -
50 -
SO-
SO -
50 -
50 -
SO-
SO -
150
150
150
150
150
150
150
150
150
150
150
150
150
150
ISO
ISO
•
G-29
-------
BATTZLLE
Hydrocarbon*, Polycyelic Aromatic
Client Sample IDs 48200-51-03
•uanterra
Lot -Sample f...: G9G2002Q5-002
Date Sampled...: 7/14/99
?rep Sate i 8/16/99
frep Batch f...: §221155
Dilution factor: 1
Work Order f..
Date Received.
Analysis Date.
. 1 DOSKQ101 Ha
.1 7/16/99
.1 8/26/99 t-
s nn^
* * * «3*/^
REPORTING
PARAMETER
Vcenaphthene
icenaphthylene
Anthracene
3enzo (a) anthracene
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (ghi) perylene
Benzo (a) pyrene
Benzo (e) pyrene
Chrysene
Dibenz (a, h) anthracene
Fluoranthene
Fluorene
Indeno { l , 2 , 3 -cd) pyrene
2 -Me thylnaphthal ene
Naphthalene
Perylene j
Pyrene
Phenanthrene
INTERNAL STANDARDS
Acenaphthene-dlO
Acenaphthylene- d8
Benzo (a) anthracene-dl2
Benzo (a) pyrene-dl2
Benzo (b) f luoranthene -d!2
Benzo (ghi) perylene -d!2
Benzo (k) f luoranthene -d!2
Chrysene-dl2
Dibenz (ah) anthracene -d!4
Fluoranthene -dlO
Fluorene. d-io
Indeno { l , 2 , 3 - cd) pyrene- d!2
Naphthalene -de
Perylene-dl2
pyi^j^Mnt-lrr^rm..^ n
Pyrene-dlO
MOTES i
RESULT
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
59
ND
ND
ND
PERCENT
RECOVERY
116
93
72
86
91
86
102
119
73
104
77
78
104
73
66
107
: LIMIf tJNXIS
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
J B 20
20
20
20
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
»s - .
ng
ng
^5
Off
ng
RECOVERY
LIMITS
50-150
50 - 150
50-150
SO - 150
SO - 150
50 - ISO
SO - 150
SO - 150
SO - 150
SO - 150
50 - 150
50 - ISO
50 - ISO
50 - 150
50 - ISO
50 -150
Gclml •**«>• ii» r 1 1 T| I "III '1 frtfara rrmnrtl nrr tn rnntlA rmmrt-rtff t'tntr lH"Ll>lCTlllltetd r«»il1rt
Matrix..
CxKa i
: AIR
B I «<~
i:
Method blank cent»«lmtiop. The aaaociated aetibad blank nnntetfn the target
,lewel. " ' .' - -
Eetiaeted zeeult. Remit i» im»* than the reporting li«it.
G-30
-------
BATTHIiT.E
Bydrocarbonfl, Poly cyclic Aromatic (HRiSC/HRMS)
Client Saapl* ID: 48150-11-02
Lot-Sampl* f...: G9G200205-012
Oat* Saapled. „ „ i 8/9/99
Srep Oat*. • . . » . i 8/16/99
Prep Batch i...i 9228155
Dilution Factor: 1
PARAMETER*
Acenaphthene
Acenaphthylene
Anthracene
.Benzo (a) anthracene
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (ghi) perylene
Benzo ( a ) pyrene
Benzo ( e) pyrene
Chrysene
Dibenz (a , h) anthracene
Fluoranthene
Fluorene
Indeno (1,2,3 -cd} pyrene
2-Methylnaphthalene
Naph thai ene
Perylene
Pyrene
Phenanthrene
INTERNAL STANDARDS
Acenaphthene -dl 0
Acenaphthylene-d8
Benzo (a) anthracene -dl 2
Benzo (a) pyrene- d!2
Benzo (b) £luoranthene-dl2
Benzo {ghi} perylene-dl2
Benzo (k) f luoranthene -dl 2
Chrysene-dl2
Dibenz (ah) anthracene -dl 4
Fluor an thene-dio
Fluorene d-10
Indeno (1,2,3- cd) pyrene - dl 2
Naphthalene-dS
Perylene-dl2
Phenanthrene - dl 0
Pyrene-dlO
NOTIS:
* . - Surrogate z«cov«ry ii
B " MB£^OCI bXttnlc CTwn^yit ii
RESULT
ND
ND
ND
53
350
270
210
110
2000
200
85
S3
ND
260
40
1700
ND
43
130
PERCENT
RECOVERY
74
56
71
17
102
74
86
97
85
94
87
84
87
32
82
90
Work Order #...: D19WH101
Bat* S*c*iv*d. . t 8/11/99
An*ly«i« Dat*..t 8/26/99
RE50ET1NS
LIMIT
20
20
20
20
20
20
20
20
B 20
20
20
20
20
20
20
B B 100
20
20
B 64
RECOVERY
LIMITS
SO - 150
SO - 150
50 - ISO
* 50-150
50 - 150
SO - 150
50 - ISO
50 - ISO
SO - 150
SO - 150
. 50 - 150
• 50 - 150
: SO - 150
* 50 - 150
50 - 150
50 - 150
Matrix .....: A1E
FH l?im 7.
UNITS
ng
ng •' .
ng
eg
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng' ' '
ng
ng
ng
ng
'
yt*mA&ma fcO &ve*4.il rettss^A'^aff myffAfm 49t*feBl.ewlM.£«d MftBUlfeM
i' oatsijda'at
utioo. Sh«
*t*d control li«it». '. •
Moedatad «.thod blank contain, i
th« targ«t analyta mt a r^sortabl.
B . E»tim*t»d r««ult. Maral't concentration mxammdm tb* calibration rang*.
G-31
-------
BATTBLLK
Hydrocarbons, Polycyclic Aromatic (ERGC/HRHS J^'
Client Sample ID: 48190-11-03
Lot-Sasi>le i...: G9G20020S-013 Work Order f...t' D19WJ101 tt
Date Sampled. ..: 8/9/59
f rep Batch #.,.! S228155
Dilution Factor: 1
Date Received. .
Analysis Date..
I 8/11/99
I 8/26/99
s SD5 i
" • 9** 3 1
REPORTING
PARAMETER
Acenaphthene
Acenaphthylene
Anthracene
Benzo (a) anthracene
Benzo {b} f luoranthene
Benzo (k} f luoranthene
Benzo {ghi } perylene
Benzo { a ) pyrene
Benzo (e) pyrene
Chrysene
Dibenz (a, h) anthracene
Fluoranthene
Fluorene
i Indeno (1,2,3 -cd} pyrene
| 2-Methylnaphthalene
Naphthalene
Perylene
Irene
'henanthrene . -
Q3TERNAL STANDARDS
Acenaphthene - dl 0
teenaphthylene-da
3enzo (a) anthracene -di2
Benzo {a} pyrene- dl2
Benzo (b5 f Iuoranthene-dl2
Benzo {ghi} perylene -d!2
Benzo {k) f luoranthene -dl 2
Chrysene-dl2
Dibenz (ah}anthracene-dl4
Fluoranthene - dl 0
Fluorene d-iO
Indeno {1,2, 3-cd) pyrene -d!2
Naphthalene - d8
Perylene- d!2
p^^n^n^h-riKn^-rfl n
Pyrene -dlO
NOTES: • t^
RESULT
SO
ND
ND
ND
120
92
120
53
640
77
51.
33
ND
170
37
530
ND
27
ND
PERCENT
RECOVERY
79
SO
74
22
107
83
97
102
96
102
97
S3
86
18
92
96
LIMIT UNITS
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
B 100
20
20
J ' ' 64
*
*
ng
fcg
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
RECOVERY
LIMITS
SO - 150
SO - ISO
SO - 150
SO - 150
SO - 150
50 - 150
50 - 150
" 50 - ISO
50 - 150
SO - 150
50 -ISO
50 - 150
50 - ISO
50 - ISO
50 - 150
50 - ISO
Matrix
FH
AIR
?"*. 3
mxm p*x£etB*d t*for» rounding to avoid round-off m&n JS"CTi1 T*0 yt^rt carolt*
Suzrogat* cmcavmry if oataida «t«t*d control limit*.' ,
Mithod blank contamination. Tba »»«oci*t*
-------
BATTKLLE
Hydrocarbons, Polycyclie Aromatic (HR6IC/ERMS53
Client Sample IX: 48190-11-04
iLot-Saaqsle #...: G9G2Q0205-014
'fiat* Sasi>l*d. . . s 8/9/99
Frep Data. » . „ . . s 8/16/99
Pr«p Batch f...t 9228155
Dilution factor: 1
Work Order • , .
Date Received.
A&alyiift Date,
Xactrune&t. . . .
. I D19WK101
.s 8/11/99
.» 8/30/99
l 8D5
FH fc*»» H
REPORTING
'ARAMETER.
tcenaphtaene
kcenaphthylene
knthracene
lenzo (a) anthracene
senzo (b) f luoranthene
ienzo (k) f luoranthene
ienzo (ghi) perylene
lenzo (a) pyrene
3enzo (e) pyrene
Chrys*»«
pibenz (a , h) anthracene
'luoranthene
fluorene
ndeno ( 1 , 2 , 3 - od) pyrene
* Me thy Inapht halene
Naphthalene
terylene
Pyrene
Phenanthrene
(CNTERNAL STANDARDS
Acenaphthene- dlO
kcenaphthylene -ds
penzo (a) anthracene -d!2
Benzo (a) pyrene-dl2
Enzo Eb) f Iuorantbene-dl2 •
nzo (ghL} peryiene-e3a2
nzo Ck) f luoranthene -dis
Chrysene-dlZ
bibenz (ah}.aathrmcene-dl4
IFluoranthene - dl 0
Fluorene d-10
[Indeno (1 , 2 , 3-cd) pyrene-d!2
(Naphthalene -d8 '
Perylene-dl2
.Phenanthrene-dlO
[pyrene-dlO
NOTBS:
RBSOLT
ND
ND
ND
ND
96
37
ND
ND
270
43
21
23
ND
29
27
440
ND
ND
KC
PERCENT
RECOVERY
75
64
62
21
89
81
103
109
7i
133
79
87
88
29
69
124
LIMIT
20
20
20
20
20
20
2P
20
20
20
20
20
20
20
20
B 100
20
20
J 64
*
*
"S
RECOVERY
LIMITS
50 - ISO
50 - ISO
. 50 - 150
50 - 150
50 - 150
50 - 150
- 50 - 150
50 - 150
50 - 150
50 - 'ISO
50 - 150
50 - 150
50 - 150
50 - 150
50 - 150
50 - 150
•QUITS
Of
ng
ng
ag
Of
at ' . . •"
ng
ng
ng
ng
ng
»g
ng
ng
ng
ng
ng
ng ' . .
ng
.
: -
Calculation* mem pecfosmmA b*foca rovnulinp to «vaid round-off ecros* XEPealeulatad rwmlta
Suzzosat** cecovttry i» outaid* itated control Uaita. . • - • •
Kotliod blank contjuatn»tion. tba m»«oct».ted aatbad blank contain* tba tacfat aaalyte at a xaportabl*
Xatimmtad ra«ult. Ra«ult ia ia»« than tba raporting limit.
G-33
-------
BATTKLLE
Hydrocarbon*, Polycyclie Aromatic (HRCC/HKHS
Client Saapl* ID: 48190-11-05
Lot-Sample f. ..: G9G200205-015
, Cat* Sampled...: 8/9/99
Prep Batch #...: 92281S5
Dilution Factori 1
Work Order f..
Date Received.
Analytic Date.
. S D19HI,1Q1
.8 8/11/99
.t 8/26/99
t 8D5
Hat
FN
• •«
REPORTING
PARAMETER.
Acenaphthene
Acenaphthylene
Anthracene
Benzo (a) anthracene
Benzo (b) f Itjoranthene
Benzo (k) fluoranthene
Benzo (ghi ) perylene
Benzo ( a ) pyrene
Benzo (e) pyrene
Chrysene
Dibenz (a, h) anthracene
Fluoranthene
Fluorene
Indeno (1, 2 , 3-cd) pyrene
2 -Me thylnaphthalene
Naphthalene*
Perylene j
Pyrene
Phenanthrene
INTERNAL STANDARDS
Acenaphthene - dlO
Acenaphthylene -d8
Benzo (a) anthracene -d!2
Benzo (a) pyrene -d!2
Benzo (b) f Iuoranthene-dl2
Benzo (ghi) perylene-dl2
Benzo (k) f Iuoranthene-di2
Chrysene-dl2
Dibenz (ah) anthracene-dl4
Fluoranthene - dl 0
Fluorene d-10
Indeno {!» 2, 3-cd)pyrene-dl2
Naphthalene -d8
Perylene-dl2
B^»narrt"'hT-*Ti«-Hl ft
Pyrene-dlO
NOTES r
C*leul»tionS~«*» p***oi»«d b«f or*
Jtotbod ba«nk contu
RESULT
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
53
440
ND
ND
ND
PERCENT
RECOVERY
83
73
81
88
100
•97
10S
110
97
94
77
99
76
89
79
S7
LIMIT
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
B 100
20
20
J 64
RECOVERY
LIMITS
50 - 150
50 - 150
50 - 150
50 - 150
50 - 150
50 - 150
50 - 150
50 - 150
50 - 150
50 - 150
50 - 150
SO - ISO
50 - 150
50 - 150
50 - 150
50 - 150
CHITS
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ns
rounding to avoid round-o« «nor« ia»iCTlmi'ltt«rt CMOlta
it M»4 nn T*1T
M FfKHifc fftfiy^ ••tibbCMi
frlUH^C ***
-------
BATTEXJUS
Hydrocarbons, Polycyclic Axomatie (HRGC/SBOts
Client Sasjpl« IDi 48190-11-06
ILot-Sampla #...: G9G2002C
Date Saag>l«L . . s 8/9/99
Fs«P Data s 8/1S/99
trap Batch #...: 9228155
•Dilution Factor: 1
PARAMETER.
enaphthene
Acenaphthylene
jtothracene
HIZO { ft ) anthracene
Benzo (b) f luoranthene
So (k) f luoranthene
oCghilperylene .
o{ a) pyrene
Benzo ( e ) pyrene
aftrsene
3ijpnz (a, h) anthracene
'luoranthene
'l^rene
nMno (1,2,3 -cd> pyrene
-TOthylnaphthalene
aphthalene
sifltLene ,
T^ie t
lenanthrene
T»NAL STANDARDS
enapbthene - dl 0
»rjt)hthylene-de
isjpta) anthracene-d!2
izo (a) pyrene-dl2
iz«tfb) f luoranthene-*d!2
.zHghi) perylene-dl.2
zoik) f luoranthene- d!2
ysene-d!2
K« (ah) anthracene- dl 4
D JBnthene-dl 0
>rene d-10
>.&•( l , 2 , 3 - cd ) pyrene - d!2
.tjplene-de
•lene- 8/11/99
t 8/2S/9S
RT1HS
T
RECOVERY
LIMITS
50 - 150
50 - 150
50 - 150
50 - 150
50 - 150
50 - ISO
50 - 150
50 - 150
50 - 150
50 - 150
50 - 150
50 - 150
SO - 150
50 - 150
50 - 150
50 - 150
Matrix.....: AIR
PH P^pf SI*.
. "2.
UNITS
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng '
ng
ng
*
- •
*
ax* fmxioxmmd. bvCan rounding to avoid roond-oiC «rror» 4»«cmlcul»t»d
Method blank eontaaination. tb» *«»oci«t«d nathod blank y^rt-^^a. tb« targ*t analyt* at * r«port«t>l«
Mgxartiag. limit. ~ '
.
i Catiaatad c««ult. Xamilt i* !••«
-------
Hydrocarbon!, Polycyclie Aromatic (ERGC/HRMS)
Cliant Saxnpl* ZJDs 48190-11-07
(guanterra
Lot-SaS5»l« #. ..! G9G200205-017
fiat* Saapl»d. . . : 8/9/99
Prep Batch #...: 9228155
Dilution Factor « 1
Work. Order #. .
Dat* R*e*iv*d.
Analysis Dat*.
. s D19WN101 Ka
. I 8/11/99
.1 8/26/99
t fiDS •
REPORTING
PARAMETER
teenaphthene
Hcenaphthylene
Anthracene
Benzo (a) anthracene
ienzo (b) fluoranthene
Benzo (Jc) f luoranthene
Benzo (ghi } perylene
BenzoCaJpyrene
Benzo (e)pyrene
Chrysene '
Dibenz ( a , h ) anthracene
Fluoranthene
Fltiorene
Indeno ( l , 2 , 3 - ed) pyrene
2 -Methylnaphthalene
Naphthalene
Perylene
Pyrene
Phenanthrene
INTERNAL STANDARDS
Acenaph thene - dl 0
Acenaphthylene - da
Benzo (a) anthracene- dl 2
Benzo (a) pyrene-dl2
Benzo (b) f luoranthene -dl2
Benzo {ghi ) perylene-dl2
Benzo (fc) f luoranthene -d!2
Chrysene-dl2
Dibenz (ah) anthracene -dl 4
Fluoranthene - dl 0
Fluorene d-10
Indeno (1,2 , 3-cd)pyrene-dl2
Naphthalene -de
Perylene -d!2
Phenanthrene-dlO
Pyre»e-dlO
NOTBS:
RESULT
NZ5
ND
KD
ND
ND
ND
KD
ND
ND
ND
UD
36
ND
ND
ND
ND
ND
21
€8
PERCENT
RECOVERY
96
81
78
71
110
92
103
103
87
94
75
95
87
50
76
92
LIMIT TO1TS
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
a 100
20
20
B 64
- -
»S
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ag
ng
ng
ng
ag
ng
ng
ng
RECOVERY
LIMITS
50 - 150
50 - 150
50 - 150
50 - 150
50 -.150
50 - 150
50 - 150
50 - 150
50 - 150
50 - 150
50 - 150
50 '•- 150
50 - 150 :
50 - 150
50 - 150
50 - 150
Matrix
. i AIR
Calculation* »r» pmxfogm»& b*£ox* rounding to avoid round-off •zrora flftalculmtmd
Mitbod blank eoataaiaatiea. Th« a«»oelat«l actbod blank contain! tha target analyt?
rmault. IUi«uIt i« 1mm* than tte reporting Halt.
*t
G-36
-------
BATTKl.TiK
Hydrocarbon*» Polycyclie Aromatic {HRGC/HRMS}3
Client Sanpl« IB: 48190-11-08
wanterra
Lot -Sample #...: G9G2Q020S-Q18
Dat* Sampled...: 8/9/99
Pr»p Date ...... t 8/16/99
Pr*p Batch #...» 9228155
Dilution Factors 1
Work Ordar f . .
Date R«c*iT*d.
Analysis Dat*.
Tnjitnnaant
. i D19WP101
. i 8/11/99
. i 8/26/99
j 8J35
•-• • i i ^ ^M
FH LCS
REPORTING
PARAMETER-
fccenaphthene
fcceaaphthylene
Ptathracene
Benzo (a) anthracene
Benzo (b) f luoranthene
benzo (k) f luoranthene
Benz o ( ghi ) perylene
Benzo (a) pyrene
Benzo (e) pyrene
Chrysene
Dibenz (a , h) anthracene
Fluoranthene
Fluorene-
Indeno (1,2, 3 -cd) pyrene
2 - Me t hy 1 naph thai ene
naphthalene
Perylene
Pyrene
Phenanthre'ne
INTERHAL STANDARDS
Acenaphthene-dlO ,
Acenaphthylene-d8
Benzo (a) anthracene- d!2 •
Benzo { a ) pyrene - d!2
Benzo (b) f luoranthene -dl 2
Benzo (ghi) perylene- d!2
Benzo (k) f luoranthene -dl 2
Chrysene -d!2
Dibenz (ah) anthracene -dl4
Fluoranthene - dl 0
Fluorene d-10
Indeno Cl , 2 , 3 -dd) pyrene-dl2
Naphthalene-d8
Perylene -312
Phmum threne - dlO
Pyrene-dlO
NOT3S: ___
RESULT
ISO
180
260
200
200
190
200
190
220
200
200
220
210
170
180
250
200
210
210
PERCENT
RECOVERY
108
99
81
89
97
110
107
113
102
100 .
66
112
99
89
65
102 .
LIMIT
20
20
20
20
20
. 20
20
20
20
20
20
20
20
20
20
B 100
20
20
B 64
. a
RECOVERY
LIMITS
50 - ISO
SO - 150
' SO - 150
50 - 150
50 - 150
50 - 150
50 - 150
50 - ISO
SO - ISO
50 - 150
. 50 - ISO
50 - ISO
50 - 150
50 - ISO
50 - 150
50 - 150
UNITS
ng
ag
ng
ng
ng
ag
ng
ng
ng
ng
ng - -
ng
ng
ng
ng
*S
ng - . '
ng
ng
• ' "• .'..
Calculation* *r» pwrloraad b*£e«« rounding to •veld round-o£C »rror» ia ealeolataKt rsaults
B Mathod .blank contamination. Tha aaaocl it-art aathnrt hlanJc contain* th» fcaxgat analyta at a raportabl*
' ' '
G-37
-------
• 1ATTSL1S
Hydroearbonn, Polycyclic Aromatic {HRGC/HRMS
Clisnt Saapl* ID: 48190-11-09
uanterra
Lot-Sanyl* #...:
Cat* SanjJl*d...:
Pr*p Dat*
G9G2D0205-019
8/9/99
8/16/99
Work Order i...t
Dat* R*c*iv*d..t
Aaalyaia Oat*..s
D19WQ101
8/11/99
8/26/S9
Matrix.
AIR
»rmp£hr»Pft-dl 0
Pyrene -dlO
NOTES: '^_^_
RESULT
170
180
250
ISO
210
200
210
200
220
210
200
210
250
200
ISO
240 B
200
210
210 B
PERCENT
RECOVERY
97
95
89
86
97
84
98
102
79
98
70
85
86
87
67 ' •
95
LIMIT
20
20
30
20
20
20
20
20
20
30
20
20
20
20
20
100
20
20
64
£
CHITS
ng
ag
ng
ag
ng
ag
• ng
ng
ng
ng
ng
ng
ng
ag
ng
ng
ng
ng
ag
RECOVERY
LIMITS
SO -
50 -
SO -
50 -
50 -
50 -
50 -
50 -
50 -
50 -
50 -
50 -
50 -
50 -
50 -
50 -
150
150
150
150
150
150
150
150
ISO
150
150
150
150
150
150
150
FH CCS
Calculation*, ax* p*r£o«a*d b*£or*' rounding to avoid round-off •xcoxa in c«icnl«»«d rm»ult*
blank confeaaiaatian. Tt» amoeiatwt Mtbod blank contilna th* ta£g*t wmlyf^
'
6-38
-------
B&TTE&UE
Hydrocarbons, Polycyelic Aromatic (HRGC/HRMS)
Client S«s>pl» 303s 48190-11-10
uan terra
Let-Sample*...: G9G20020S-Q20
Date Sampled... s 8/9/99
Prep Date. : 8/16/99
Prep Batch f. . . : 9228155
Dilution Factors 1
Work Order f . .
Bate Received.
Analy«i» Date.
. : D19WR101
. s 8/11/99
.1 B/2S/SS
8D5
FH t-k> Bk-a
REPORTING
ARAMETER
eenaphthene
eenaphtbylene
nthracene
enzo (a) anthracene
enzo (b) f luoranthene
enzo (k) f luoranthene
enzo {f hi} perylene
enzo (a) pyrene
«nzo(e) pyrene
hrysene
ibenz (a,h) anthracene
'luoranthene
'luorene
ndeno(l,2, 3-cd) pyrene
-Methylnaphthalene
'aphthalene
•erylene
yrene
henanthrene
MTERNAL STANDARDS
Lcenaphthene-dlO
kCenaphthylene-dS
ienzo (a) anthracene -dl 2
lenzo (a) pyrene-dl2
lenzo (b) f luoranthene -d!2
Jenzo (ghi ) perylene-dl2
ienzo (k) f luoranthene -d!2
2irysene-dl2
Jibenz (ah) anthracene - d!4
riuoranthene-dlO
^luorene d-10
Cndeno {1,2 , 3-ed} pyrene -d!2
•laphthalene-da
?erylene-dl2
?henanthiene-dlO
Pyrene -diO
NOTES s „____._
Calculation* *r* fMXfosood b*Cox*
RESOLT
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
21
ND
ND
ND' •
PERCENT
RECOVERY
94
91
79
76
91
63
93
109
74
94
76
80
92
7i
62
96
LIMIT
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
rounding to avoid round-off «rr
• -
RECOVERY
LIMITS
50 - 150
SO - 150
50 - 150
50 - 150
50 - 150
SO - 150
50 - 150
SO - 150
50 - ISO
50 - 150
50 - ISO
50 - ISO
50 - ISO
SO - 150
50 - 150
. 50 - 150
UNITS -
ng
ag
ag
ng
ng
ag
ng
ag
ng
ng
ns
ng
ng
ng
ng ' •
ng
ag
ag
ng
-
•"-,"
• '
*P
•"' ••'.' ••
'
ora in calculated remits
G-39
-------
METHOD BZANX REPORT
Client Lot #...:
MB Lot-Sans>l» is
Irep Date ;
Pr«p Batch f...j
Dilution factors
Hydrocarbon*, Folycyclic Aromatic (HRGC/ERMS)
G9G200205 Work Ordar f... s D1DLC101 Matrix
G9H160Q00155B
8/16/99 Analysis Data..: 6/25/99
9228155 Instrument..... r 8D5
1
uanterra
AIR
REPORTING
PARAMETER
keenapathene
Aeenaphttoylene
Anthracene
Benzo (a) anthracene
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (gni } perylene
Benzo (a J pyrene
Benzo (e)pyrene
Chrysene
'Dibenz (a , h) anthracene*
Fluoranthene
Fluorene
Indeno (1,2, 3 -cd! pyrene
2 -Metnylnaphthalene
Naphthalene
Perylene
Pyrene
Phenanthrene
INTERNAL STAKDARDE
Acenaphthene-dlO
Acenaphthylene-d8
Benzo (a) antnracene-d!2
Benzo (a) pyrene-dl2
! Benzo (b) f luoranthene -dl 2
Benzo (ghi ) perylene-d!2
Benzo (k) f luoranthene -dl2
Chrysene-dl2
Dibenz (ah) anthracene -dl 4
Fluoranthene - dl 0
Pluorene d-10
Indeno (1,2,3 -cd) pyrene -dl 2
Naphthalene- d8
Ferylene-dl2
Pf!fnmt;l|T*n*-^l o
Pyrene-dlO
NOTES: "*"'
Cxlculctaoiu •>• p«rf otm J , txf or» rounding
RESULT
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
, ND
ND
ND
ND
ND
ND
PERCENT
RECOVERY
102
95
73
86
84
SI
101
104
ei
98
92
86
88
91
72
98
to avoid round-off mm
LIMIT
20"
20
20
20
20
20
20
20
20
20
20
20
20
20
. 20
20
20
20
20
UNITS
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
og
ng
ng
RECOVERY
•*•
ir« la e«ien
LIMITS
50 -
SO -
SO -
SO -
50 -
50 -
50 -
50 -
50 -
SO -
SO -
so -
50 -
50 -
50 -
50 -
lat*d s*rai
150
ISO
150
150
150
150
150
150
ISO
150
150
ISO
150
150
150
150
t*
~
• • -
-
G-4Q
-------
^
Hydrocarbon*, folyeyelic Aromatic (HRGC/HRKS)
Client Lot f...:
LCS Lot-Saapla #:
Prap Data :
Prap Batch f...:
Dilution Factor:
G9G200205
G3E1S0000155C
6/16/99
9228155
1
Work Ordar I.., t D1DLC102
An*ly«i» D*ta..s 8/25/99
Xnatrmnant.....: 8D5
Matrix.
AIR
PARAMETER
Acanaphthana
Acanaphthylana
Antnracana
Banzo (a) astbraeasa
Banzo (b) iluoranthana
Banro (k) fluoraathaaa
Banzo (ghl ) parylaaa
Ban zo ( a ) pyx ana
Banzo { a ) pyrana
earyaana -
Dibanr (a,h) a&thracana
Fluoran thane
Fluor an a
Indano (1,3,3 -ed) pyxana
2 -Ma thylamphtaalana
Haphthalana
farylana '
Phananthrana
Syrana »
$
INTERNAL STANDARDS
Acenaphthene - dl 0
Acenaphthylene- da
Benzo (a) anthracene- dl 2
Benzo (b) f Iuoranthene-dl2
Benso (k) £luoranthene-dl2
Benzo (ghi)perylene-dl2
Benzo (a) pyrene-dl2
€2irysene-dl2 . •
.Dibenz (ah) anthracene -dl 4
Fluorene d-10
Fluoranthene-dlO
Indeno (1,2, 3-cd)pyrene-dl2
Naph thai ene - dB
Perylene-dl2
Phenan tbxene - dl 0
Pyre&e-dlp
KOrKS:
CaleolatiOM ax* parfaraad b*f oxa
•eld print daneta* control ji«ri»»
RESULT
150
1S8
218
194
175
207
1S4
197
204
200
215
192
225
181
193
213
200
190
204
PERCENT
RECOVERY
122
102
96
108
102
100
98
109
96
101
111
99
98
98
89
108
jPOTfTld-HiFHT ISO
tars .
SPIKE
AMOONT
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
200
•veld round-off
UNITS
B?
"nf
»S
n»
a?
ag
ag
ag
ag
OS .
ag
ag
ng
ag
ag
ng
ng
ag
ag
RECOVERY
LIMITS '
SO -
50 _ •
50 '-
50 -
SO -
50 -
50 -
50 -
SO -
50 -
SO . -
50 -
50 -
SO -
50 -
50 -
•rror in calculi
150
150
ISO
150
ISO
150
150
150
150
150
ISO
ISO
ISO
ISO
ISO
150
ktad
PERCENT
RECOVERY
7S
94
109
97
88
104
97
98
102
100
107
96
112
91
96
107
100
95
102
•
.
ravulta
RECOVERY
LIMITS
SO -
50 -
so -
50 -
50 -
10 -
50 -
SO -
50 -
SO -
50 -
50 -
SO -
50 -
50 -
50 -
50 -
50 -
50 -
150
150
150
ISO
150
150
150
150
150
158
150
150
150
150
150
150
150
ISO
150
G-41
-------
BATTELLB
Client Sample ID: 48190-09-02
Trace Level Organic Compounds
B H
Lot-Saaple i : G9G200205-003
Date Sampled...: 08/09/99
Prep Date i 08/16/99
Prep Batch *.-.: S22B155
Dilution Factor: 1
PARAMETER
Acenaphthene
Acenaphthylene
Anthracene
Benzo (a) anthracene
Benzo (b) £ luoranthene
Benzo (k) fluoranthene
Benzo (ghi ) perylene
Benzo (a) pyrene
Benzo (e) pyrene
Chrysene
Dibenz ( a , h) anthracene
Fluoranthene
Fluorene
V
Indeno (1,2, 3 -cd) pyrene
2 -MethyinaphtLhalene
naphthalene
Perylene
Pyrene
phenanthrene
INTERNAL . STANDARDS
Acenaphthene - dl 0
Acenaphthylene-dB
Benzo(a)anthracene-dl2
Benzo (a) pyrene-dl2
lenzo(b) fluoranthene-dl2
Benzo (ghi) perylene-d!2
Benzo (k) fluoranthene -d!2
Chrysene-dl2
Dibenz (ah) anthracene -d!4
Fluoranthene-dl 0
Fluorene d-10
Indeno (1,2,3 -cd) pyrene -d!2
Naphthalene -d8
Perylene-dl2
Pnenanthrene-dlO
Pyrene-dlO
SURROGATE
Work Order f . .
.Date Received.
Analysis Date.
RESULT
160
1700 D.JA
210 JA
83
860
840
130
ND
530 JA
3300 E
20
3900 E
1500 E
97
32000 D,E,B
450000 D,E,B
370 JA
2600 E
33000 D.B.B
PERCENT,
RECOVERY
76
1.5 *
42 *
6.1 *
102
47 *
68
66
58
73
93
60
91
1.9 *
124 '
64
PERCENT
RECOVERY
.; D19W6101
.: 08/11/99
.: 08/26/99
DETECTION
LIMIT
20
400
20
20
20
20
20
20
20
20
20
20
20
20
400
400
20
20
20
RECOVERY
LIMITS
(50 - ISO)
(50 - 150)
(50 - 150)
(50 - 150)
(50 - 150)
(50 - 150)
(SO - 150!
(50 - 150)
(50 - 150)
(50 - 150)
(50 - 150)
(50 - 150)
(50 - 150)
, (50 - 150}
(5.0 - 150.)
(50 - 150)
RECOVERY
LIMITS
Mati
UNITS
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
iy?
IQCT
ng
ng
ng
ng
ng
rix .
• AIR
METHOD
'CA-2
CA-2
CA-2
CA-2
CA-2
Cft-2
Cft-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-3
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CftRB
429
429
429
429
429
429
429
429
429
429
429
429
429
429
429
429
429
429
429
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
13C6-Fluorene
24 * (0.0- 0.0)
(Continued on next page)
-------
..
I IHi i u- i-.-
Client Sanple ID: 48190-09-02
Trace Level Organic Compounds __ -,
^"« c.
Lot-Sanple f...: G9G200205-003 Work Order f ...: D19W6101 Matrix ____ ..... : AIR
•OTB(S) ; _ ;
* Sum>f«tt recovery » onoide a»ttd cemtrol hmto. • . • •
D Konii w«i obttiMd frcm UK w«ty«ia of • dOotioo.
JA Hie Moityte WM pondvelr Uoufflni. bB fl* qaauinuinD ii «
att a»caitr«»o aceedi ifae cijfl>r»«ko mi««.
B H**"1 "*•* i«n»J»Ml^ Th. M^ci.gd mafand hlmlr Mcttim the nrya umlyte M . rrpnmjilf Irvgl
G-43
-------
BATTELIiB
Client Sample ID: 48190-09-03
BH
Lot-Saiqple f...: G9G200205-004 Work Order i...: D19W8101
Date Saapled. ..: "OB/09/99 Dace Keceimd..: 08/11/99
Prep Dace ,.: 08/16/99 Analysis Dace..: 08/26/99
Prep Batch i-.,: 922B1S5
Dilution Factor: 1
PARAMETER
Acenaphthene
Acenaphrhylene
Anthracene
Benzo (a) anthracene
Benzo (b) fluoranthene
Benzo (k) fluoranthene
Benzo (ghi) perylene
Benzo (e) pyrene
Chrysene
Dibenz (a, h) anthracene
Fluoranthene
Fluorene
Indeno ( l , 2 , 3 -cd) pyrene
2 -Me thy Inaphtha 1 ene
Naphthalene
Pyrene
Phf»nanrhTi»r>*»
INTERNAL STANDARDS
Acenaphthene-dlO
Acenaphthy lene -d8
Benzo (a! anthracene-d!2
Benzo(a)pyrene-dl2
Benzo (b) fluoranthene -d!2
Benzo (ghi)perylene-dl2
Benzo (k) f Iuoranthene-dl2
Chrysene-dl2
Dibenz (ah) anthracene-di4
Fluoranthene -dl 0
Fluorene d-10
Indeno (1, 2, 3-cd! pyrene-dl2
Naphthalene - d 8
Phenanthrene -dl 0
Pyrene-dlO
SDRROGATE
1 3 C6- Fluor ene
RESULT
130
2000 E,JA
82 JA
390
910
470
89
540 JA
2000 B
25
3600 B
1700 B
88
30000 D,E,B
380000 D,B,E
2400 B
33OOO D,B
PERCENT
RECOVERY
87
0.70 * ;
36 *
4.3 *
SB
47 *
86
88
63
82
90
68
89
128
70
PERCENT
RECOVERY
31 *
Matrix •
AIR
DETECTION
LIMIT
20
20
20
20
20
20
20
20
20
20
20
20
20
400
400
20
20
RECOVERY
TOITS
03
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
net
**59
METHOD
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
429
429
429
429
429
429
429
429
429
429
429
429
429
429
429
429
429
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
LIMITS
(50 -
(50 -
(50 -
(50 -
(50 -
. (50 -
- (50 -
(50 -
(50 -
(50 -
(50 -
(50 -
(50 -
(50 -
(50 -
150)
150)
150)
150)
150)
150)
150)
150)
150)
150)
150)
150)
150)
150)
150)
RECOVERY
LIMITS
(0.0-
0.0)
(Continued on next page)
G-44
-------
BATTKLUE
M.-SV - - ' - •
' II-.J _ W _ 1
Client Sample ID: 48190-09-03
Trace Iiercl Organic Coopounds «,1
Lot-Sanple f : G9G200205-004 Mork Order §...= D19W8101 . Matrix s AIR
MLrili (S) : ; _^________
* Snnogite ncamy it outride Mied comnl Hmta-
E iaonmed root Rontt OMoaoratkin oxttdf ihe odfljiBioB IK^
JA Hie aiilytt tm portivcjy xlcntiflaJ, bm flic qoxooaukKi k •> »^<'~~
D ftaim wa obttin«l &txn tbe aulytji of i dflnaosi.
B Mobod bldk conammitjotL TV MsocUad mrlbod btank coo»»im the urga miiyu 11« rtporabfc kvd.
G-4i
-------
&*"^'
BATTKLLE
Client Sanple ID: 48190-09-04
Trace level Organic Compounds
Lot-Sanple f...= G9G200205-005 Work Order f...: D19W9101
Date Saopled...: -08/09/99 Date Received. . : 08/11/99
Prep Date : 08/16/99 Analvsis Date..: 08/26/99
Prep Batch f...s 3228155
Dilution Factor: 1
PARAMETER
Ar-on Anh t- H«*nf»
Acenaphthylene
Anthracene
Benzo (a) anthracene
Benzo (b) fluoranthene
Benzo (k) fluoranthene
Benzo (ghi ) perylene
Benzo (e) pyrene
Chrysene
Dibenz (a,h) anthracene
Fluoranthene
Fluor ene
Indeno (l , 2 , 3 -cd) pyrene
2 -Methylnaph thai ene
Naphthalene
Perylene
Pyrene
Ph*»fimit-hT"»n»
INTERNAL STANDARDS
Acenaphthene-dio
Acenaphthylene-d8
Benzo (a) anthracene-dl2
Benzo (b) f Iuoranthene-dl2
Benzo (ghi )perylene-dl2
Benzo (k) f Iuoranthene-dl2
Chrysene-dl2
Dibenz (ah) anthracene -dl4
Fluoranthene - dl 0
Fluorene d-10
Indeno (l, 2, 3-cd)pyrene-dl2
Naphthalene -d8
Perylene-dl2
Phenanthrene-dlQ
pyrene -dlO
SURROGATE'
1 3 C6- Fluor ene
— _ _
RESULT
26
260 JA
93
82
170
120
85
120 JA
440
ND
910
130
45 '
1300 D.B
210000 D.B, B
57 OA
490
8000 I
PERCENT
RECOVERY
73
1.2 *
38 *
86
67
74
73
63
82
108
68
77
1.8 *
125
74
PERCENT
RECOVERY
13 *
Matrix-, . , ::
AIR
DETECTION
LIMIT
20
20
20
20
20
20
20
20
20
20
20
20
20
200
200
20
20
20
RECOVERY
UNITS
ng
™'".J
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
no
"3J
METHOD
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CA-2
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
429
429
429
429
429
429
429
429
429
4.23
429
429
429
429
429
429
429
429
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
LIMITS
(50 -
(50 -
(50 -
(50 -
(50 -
(50 -
(50 -
(50 -
(50 -
(50 -
(50 -
(50 -
(50 -
(50 -
(50 -
150)
150!
150)
150)
150)
1503
150)
150)
1505
150)
150)
150)
150)
150)
150)
, RECOVERY
LIMITS
(0.0-
0.0)
(Continued on next page)
G-46
-------
.$, '* *V*T M *^ f"? f
fv: .'.'./ - .-. • •
Client Sample IDs 48190-09-04 ' "">' - ^ — - /
Trace Level Organic Oonfwunds -o^ . » U
Lot -Sample #...: G9G200205- 005 Box*: Order f. .. s D19W91 01 Matrijt ____ ,.,..: AIR
HOTB(S) : _ .
* SmcgMe recovery n oomac aBd control bnuc.
IA Tbt BuO)^ WM porttvefy ktaBiOrt b« IlK ija«aianon » • caiMtn.
D SaoliviidtalDedlhntteaulxsBof tditafion.
B Mabodbten* amummmoii. Ike •wdneA method bliok conttni die Btyct «ujye m rcfwrabk level
E Eimmtaj mat gamk eoBceoiKitiB exseoto tte caia>rmtiDo naft.
G-47
-------
BATTKLLE
Client Sample ID: 48190-09-05
Trace Level Organic Compounds
BH - P'
Lot-Saaple t,..: G9G200205-006 Work Order. f...: D19WA101
Date Saafjled. . . : OB/09/99 Date Received..: 08/11/99
Prep Date : OB/16/59 Jtoalvsis Date..: 08/26/99
Prep Batch t...: 9228155
Dilution Factor: 1
' PARAMETER
Acenaphthene
Acenaphthy 1 ene
Anthracene
Benzo (a) anthracene
Benzo (b) f luoranthene
Benzo (Jc) f luoranthene
Benzo {ghi} perylene
Benzo (a) pyrene
Benzo (e) pyrene
Chrysene
Dibenz (a,h) anthracene
Fluoranthene
Fluorene
Indeno (1,2,3 -cd) pyrene •
2-Methylnaphthalene
Naphthalene
Perylene
Pyrene
Phenanthrene
INTERNAL STANDARDS
Acenaphthene - dl 0
Acenaphthylene-d8
Benzo (a) anthracene-d!2
Benzo (a) pyrene -d!2
Benzo (b) fluoranthene-d!2
Benzo (ghi) perylene-d!2
Benzo (k) f Iuoranthene-dl2
Chrysene-di2
Dibenz (ah) anthracene-d!4
Fluor anthene-dlO
Fluorene d-10
Indeno(l,2, 3-cd)pyrene-dl2
Naphthalene -d8
Perylene-dl2
Phenanthrene - dl 0
Pyrene-dlO
SURROGATE
13C6- Fluorene
RESULT
ND
ND
ND
ND
ND '
ND
29
ND
ND
ND
ND
21
ND
ND
ND
ND
ND
28
ND J
PERCENT
RECOVERY •
111
96
97
97
102
92
109
121
90
103
84
94
91
100
78
103
PERCENT
RECOVERY
61 *
Matrix. ......'. , •
AIR
DETECTION
LIMIT
20
20
20
20
20
20
20
20
20
20
20
20
20
20
120
470
20
20
120
ON ITS
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
METHOD
CA-
2
CA-2
GA-
GA-
CA-
CA-
Cft-
CA-
CA-
CA-
CA--
GA-
GA-
CA-
CA-
CA-
CA-
CA-
CA
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARB
CARE
CARB
CARE
CARB
CARB
CARE
CARB
CARB
CARE
CARB
CAR?
429
429
429
429
429
429
429
429
429
429
429
429
429
425
429
429
429
429
42S
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
.RECOVERY
LIMITS
(50 -
(50 -
(50 -
. (50 -
(50 -
(SO -
(50 -
(50 -
(50 -
(SO -
(50 -
(50 -
(50 -
(50 -
(SO -
(50 -
150)
150)
150)
150)
150)
150)
150)
1503
150)
150)
150)
150)
150)
150)
ISO)
150)
RECOVERY
LIMITS
(0.0-
0.0)
(Continued on next page)
G-48
-------
Client Sample ID: 48190-09-05 ''*»>'' - ~ -- - '
Trace Level Organic Coojpounds ->,, _ po i
Lot-Sample*...: G9G200205-006 Work Order i...; D19MM01 Matrix.... .- AIR
HOTE(S) :
* Snrrofmic recovery n omide aued coonol liniiti.
J Enimtirf rooli. Eoutt ii io« lh« *£ reportmt HnriL
G-49
-------
BATTKIJiK
Client Sample ID: 48190-09-06
Trace Level Organic Compounds
BH • PS Z
Lot -Sample §...: G9G20Q2Q5-007 Work Order §...: D19WC101
Date Saapled. . . : 08/09/99 Date Receired. . s 08/11/99
Prep Date... s 08/16/99 Analvsis Date..: 08/26/99
.Erep Batch f...: 9228155
Dilution Factors 1
PARAMETER
Acenaphthene
Acenaphthylene
Anthracene
Benzo (a) anthracene
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo ( gni ) pery lene
Benzo (a) pyrene
Benzo (e)pyrene
Chrysene
Dibenz (a,h) anthracene -
Fluoranthene
Fluor ene
Indeno f 1 , 2 , 3 -cd) pyrene
2-Methylnaphthalene
Naphthalene
Perylene
Pyrene
Phenanthrene
INTERNAL STANDARDS
Acenaphthene - dl 0
Acenaphthylene-d8
Benzo (a) anthracene -d!2 .
Benzo (a) pyrene -d!2
Benzo (b) f luoranthene -dl2
Benzo (ghi) perylene-dl2
Benzo (k) fluoranthene-d!2
Chrysene-dl2
Dibenz (ah) anthracene -dl4
Pluoranthene - dl 0
Fluorene d-10
Indeno (1 , 2 , 3 -cd) pyrene-dl2
Naphthalene-dB
Perylene-dl2
Phenanthrene - dl 0
Pyrene-dlQ : .
SURROGATE
13C6- Fluorene
\
RESULT
ND
HD
ND
ND
ND
ND
69
ND
ND
ND
ND
37
ND
ND
ND J
ND J
ND
58
ND J
PERCENT-
RECOVERY .
94
89
95
98
105
85
102
116
85
86
83
89
77
95
70
86
PERCENT
RECOVERY
69 *
Matrix. - , . . ;
AIR
DIIUCTIQN
LIMIT
20
20
20
20
20
20
20
20
20
20
20
20
20
, 20
120
470
20
20
120
UNITS
ng
ng
ng
ng
ng
ng
ng
ng-
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
METHOD
CA-
CA-
CA-
2
2
2
CA-2
CA-
CA-
2
2
ca-2
CA-
2
CA-2
CA-
CA--
Cft~
CA-
CA-
'CA-
CA-
CA-
CA~
- CA-
2
2
2
2
2
2
2
2
2
'2
CARB
CARE
CARE
CARB
CARE
CARE
CARB
CARB
CARB
CARE
CARE
CARB
CARB
CARB
CARE
CARE
CARE
CARB
-"ARF:
429
€29
429
429
429
429
429
429
429
429
429
429
429
429
429
425
423
429
4? 9
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
RECOVERY
LIMITS
(50 -
(50 -
(50 -
(50 -
(50 -
(50 -
(50 -
(10 -
(50 -
(50 -
(50 -
(50 -
(50 -
(50 -
(50 -
(50 -
150)
150)
150)
150)
150)
150)
150)
150)
150)
150)
150)
150)
150)
ISO)
150)
ISO)'
RECOVERY
LIMITS
(0.0-
0.0)
(Continued on next page)
G-50
-------
Client Sample 3D: 48190-09-06 '" " w '
Trace lierrel Organic Coopounds "2^ - "pB "i.
Lot-Sanple §,..; G9G20020S-007 Work Order t ...: D19WC101 • Matrix ......... : AIR
•OTB(S): _ .............. T,. , ; ............. _.., .................... _..
* SmnfiB retOTcry a oooilc mied coitrcl IkmD.
I FlUmMHl matt. Rqnll » tog am flit iqportng tmriL
G-51
-------
BATTKLLB
Client Sanple ID: 48190-09-07
Trace Level Organic Compounds
BH FB
Lot -Sample *.,.: G9G200205-008 Work Order f.,.: D19WD101
Date Sailed...: 08/09/99 Date Received. .: 08/11/99
Prep Date : 08/16/99 Analvsis Date. .: 08/26/99
Brep Batch f. .. r 9228155
Dilution Factor: 1
PARAMETER
Acenaphthene
Acenaphthylene
Anthracene
Benzo (a) anthracene
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo ( ghi } perylene
Benzo (a) pyrene
Benzo (e) pyrene
Chrysene '
Dibenz { a , h ) anthracene
Fluoranthene
Fluorene
Indeno { 1 , 2 , 3 -cd) pyrene
2-Methylnaphthalene
Naphthalene
Perylene
Pyrene
Phenanthrene
INTERNAL STANDARDS
Acenaphthene -dl 0
Acenaphthylene -d8
Benzo (a) anthracene -d!2
Benzo(a)pyrene-dl2
Benzo (b) f luoranthene -d!2
Benzo (ghi ) perylene -d!2
Benzo (h) f Iuoranthene-dl2
Chrysene -d!2
Dibenz(ah) anthracene -dl4
Fluoranthene-dlO
Fluorene d-io
Indeno (1 , 2 » 3 -cd) pyrene-d!2
Naphthalene -de
Perylene-dl2
Phenanthrene-dlO
Pyrene -dlO
SURROGATE
RESULT
ND
ND
ND ,
ND
ND
ND
S7
ND
25
ND
ND
50
ND
ND
ND J
ND J
ND
55
ND J •
PERCENT
RECOVERY
95 •
86
83
88
104
110
104
111
119
99
77
114
78
91
71
95
PERCENT
RECOVERY
Matrix- . , •
AIR
DETECTION
LIMIT
20
20
20
20
20
20
20
20
20
20
20
20
20
20
120
470
20
20
120
UNITS
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
METHOD
CA-
CA-
CA-
CA~
CA-
CA-
CA
CA-
CA-
CA-
CA-
CA-
CA-
CA-
2
•2
2
2
2
2
2
2
2
7
2
2
2
2
CA-2
Cf,^
CA-
CA-
c?v
S-
2
2
";
GARB
CARE
CARB
CARE
CARS.
CARP
CARB
CARE-
CARB
CARB
CARE-
GARB
CARE
CARE
CARB
CARE
CARB.
CARB
CART
429
429
429
429
429
429
429
425
429
429
42S
429
429
429
429
429
42 9
429
42°
MOD
MOD
MOD
MOD
MOD
MOD
MOO
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
MOD
RECOVERY
LIMITS
(50 -
(50 -
(50 -
- (so -
(50 -
(50 -
(50 -
(50 -
(50 -
(50 -
(50 -
(50 -
(50 -
(50 -
, (50 -
' (50 -
150)
150)
150)
150)
150)
150)
150)
150)
150)
150)
150)
150)
150)
150.)
150)
150)
ESC0VSRY
LIMITS
13C€-Fluorene
62 * .(0.0- 0,0)
(Continued on next page)
-------
A •
BWtELLE '
"
Client Sample ED: 48190-09-07 ''
Trace Level Organic Compounds
lot-Sample f...: G9G200205-008 Pork Order §—s D19WD101 Matrix: : AIR
SOTB(S) :
* Suuogitt recovery • oMiidc mod cmml fimla,
J T^trmM«
-------
BATTEUJE
Hydrocarbon*, Polyeyclic Aromatic (HRSC/ERMS
Client Sampl« IDs 48190-09-09
jfuanterra
Lot-Sample f...: G9G200205-009
Bate Sampled. . . : 8/9/99
Frep Date......i 8/16/99
Prep Batch §...: 92281S5
Dilution Factor: 1
Work Order ff . . .
Data Received. .
JU&aly*!* Date . .
In* t X"um*n t . ....
1 D19WE101
« 8/11/99
t 8/26/99
t 8D5
* • , W+&3
Mi
B
i«<^
Rlf ORTDIG
PARAMETER.
lAcenaphthene
[Aeenaphtnylene
Anthracene
iBenzo (a) anthracene
Benzo (b) f luoranthene
Benzo (k) f luoranthene
Benzo (ghi ) perylene
Benzo {a) pyrene
Benzo ( e } pyrene
Chrysene
Dibenz ( a , h) anthracene
Fluoranthene
Fluorene
Indeno {1,2,3 -ed) pyrene
I -Methylnaphthalene
Naphthalene,
Perylene :
?yrene '
Phenanthrene
INTERNAL STANDARDS
Acenaphthene-dlO
Acenaphthylene-d8 •
Benzo (a.) anthracene-dl2
Benzo (a)pyrene-d!2
Benzo (b) f luoranthene -dl2
Benzo {ghi) perylene-dl2
Benzo (k) f luoranthene- dl2
Chrysene-dl2
Dibenz {ah) anthracene-di4
Fluoranthene -did
Fluorene d-10
Indeno (l, 2, 3-cd)pyrene-dl2
Naphthalene -dS
Perylene -dl 2
Ph^nnnf hr*nf-d1 0
Pyrene -dlO
NOTES:
Calculation* ax* p*x£ona4 b*2or* xt
RESULT
170
180
250
200
20S
200
190
200
210
190
210
220
230
190
210
HO
200
210
210
PERCENT
RECOVERY
109
98
91
93
99
98 -
106
114
99
106
88
99
92
91
76
102
LIMIT
20
20
20
20
20
20
20
20
20
20
20
20
20
20
B 120
J 470
20
20
B 120
niTMH.Kr to avoid round-off «xro;
"£
RECOVERY
LIMITS
50 - ISO
50 - 150
50 - 150
50 - 150
50 - 150
50 - 150
50 - ISO
50 - ISO
50 - ISO
50 - 150
50 - 150
50 - ISO
50 - ISO
50 - 150
50 - ISO
SO - 150
TOUTS
ag
ag
ag
ag
ng
ag
ag
ag
ag
ag
ag
ng
ag
ng .
ng
ng
ag
ag
ag
cm iwcalculatad r»«ult«
AIR
B H LC£
k»tinat»d r»«ult. Ramlt i» !••• than th* r«portinff limit.
G-54
-------
BATTKLLB
Hydrocarbon*, Polycyclic Arena tic {HRGC/SKHS
Client S«mpl« IDs 48190-09-10
uanterra
Lot-Sanpla <...
Data Samplad... i
Pr«p Bate i
G9G2G0205-010
8/S/99
8/16/S9
Work Ord« f...s D19WF101
Data R«ceivad..i 8/11/59
Jtoalyaia Bate..: 8/26/99
Matrix.
: AIR
Dilution Factor; 1
us
«
REPORTING
PARAMETER
Aeenapnthene
Acenaphthylene
Anthracene
(Benzo (a) anthracene
Benzo (b) f luoranthene
Benzo (k) f luoranthene
benzo (ghi ) perylene
Benzo (a} pyrene
Benzo («) pyrene
iChrysene
JDibenz (a , h) anthracene
Fluoranthene
Fluorene
Indeno (1,2, 3 -cd) pyrene
Methylnaphthalene
Naphthalene
Perylene
Pyrene
Phenanthrsne
INTERNAL STANDARDS
Acenaphthene-dlO
Acenaphthylene -d8
Benzo (a) anthracene -dl 2
Benzo (a)pyrene-d!2
Benzo (b) f luoranthene -dl2
Benzo (ghi) perylene -dl2
Benzo (k) f luoranthene -dl2
Chrysene-dl2
Dibenz (ah) anthracene -dl 4
Fluoranthene-dlO
Fluorene d-10
Indeno (1,2,3 -cd) pyrene -d!2
Naphthalene -de
Perylene -dl2
Phenanthrene-dlO
Pyrene -dlO
ROTES:
Calculation* ara pacfeaaad bafoea :
RESULT
150
170
200
190
170
200
190
190
230
180
190
200
230
170
200
ND
190
190
210
PERCENT '
RECOVERY
100
89
86
81
100
87
98
111
86
102
93
89
89
7fi
83
98
LIMIT
20
20
20
20
20
20
20
20
20
20
20
20
20
20
B • 120
J 470
20
20
B 120
•-
ranis
ng
ag
ng
ng
ng
ng
ng
ng
ng
ng '
ng
• ng
ng
ng
ng
ng
ng
ns .
RECOVERY
LIMITS
50 -
50 -
50 -
50 -
50 -
150
150
150
150
150
50 - -ISO
50' -'
50 -
50 -
50 -
50 -
50 -
50 -
50 -
50 -
50 -
150
150
150
150
150
150
150
150
150
150
rounding ta avoid round-off arror* ^OT calculat
• iiathod blank contamination. Tha
aaaeciatad •athnj
l&jlanlt dyntftii*ff
;ad raault«
tba taryat analyta at a raportabla
laval. - . / ,' .
latiaatad ra«ult. Raiult ia la« than tha raportiafl li»it.
G-55
-------
BATTEUJ:
Hydrocarbon*, Polycyclic Aromatic (HRGC/HRKS)
Client Sample IDi 46190-09-11
tot-Sample f. ..s G9G200205-011
Data Sampled. ..: 8/2/99
fr*p Batch 't. ..s 922815S
Dilution Factor: 1
Work Order i. .
Date R*c«iv*d.
Analysis Date.
.8 D19W61Q1
.! 8/11/99
.1 8/30/fS
S 8D5
Matrix , .
B H i
REPORTING
PARAMETER -
'Aeenaphthene
Aeenaphthylene
Anthracene
(Benzo (a) anthracene
1 Benzo (b) f luoranthene
Benzo (k) f luoranthene
• Benzo (ghi) perylene
Benzo ( a ) pyrene
' Benzo ( e ) pyrene
Chryaene .
| Dibenz (a , h) anthracene
1 Fluoranthene
Fluorene
i indeno (l, 2 , 3 -cd) pyrene
I 2-Methylnaphthalene
Naphthalene
Perylene
I Pyrene
' Phenanthrene
INTERNAL STANDARDS
Acenaphthene - dl 0
Acenaphthylene-d8
Benzo (a) anthracene-d!2
Benzo (a) pyrene-dl2
Benzo (b) f Iuoranthene-dl2
Benzo (ghi)perylene-dl2
Benzo (k) f Iuoranthen.e-dl2
Chrysene-dl2
Dibenz (ah) anthraeene-dl4
Fluoranthene - dl 0
Fluorene d-10
Indeno (1, 2, 3-ed)pyrene-dl2
Naphthalene -d8
1 Perylene -d!2
Phenanthrene - dl 0
1 Pyrene-dlO
1 Honss ^.
Calculation* ax* p«rforn»d b»£ or» xi
RESULT
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
25 . '.
94
ND
ND
25
PERCENT
RECOVERY
97
97
65
79
81
86
109
135
67
130
78
79
100
66
66
123
sunding to »
LIMIT .
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
.
-
rvoid round-off «rr
-s.
RECOVERY
LIMITS
SO - ISO
SO - 150
SO - 150
50 - 150
' so - 150
50 - 150
SO - 150
50 - 150
50 - 150
50 - 150
SO - 150
SO - ISO
50 - 150
SO - 150
50 - 150
SO - 150
UNITS
ng
hg
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ag
ng
or» j^Tealeolatad result*
AIR
G-56
-------
APPENDIX H
Chlorine Analytical Lab Raw Data Results
-------
H-l
Chlorine Sewage Sludge Results
H-1
-------
Chlorine Laboratory Sludge Results Summary Table H-l
Chlorine Sewage Sludge Results
(rag/kg)
Run 2 Run 3 Run 4
T&ESampleNo. MSD-S-R1-113D MSD-S-R3-313D/C MSD-S-R4-411C/I»
Analysis Date 7-21-99 7-22-99 7-23-99
Chlorine Sewage Sludge Results
Free Chlorine (mg/kg) 18.49 4.84 17.14
Total Chlorine (rag/kg) {0.00} 4.84 4.29
Footnotes
1. Calculated values from sludge extract volume and sludge weight; uncorrected for Blank C12 content
2. Blank sample composed of extract fluid generated from 5.01 grams of sludge mixed with 96.5 milliliters (mL)
DI water, 3.5 mL HC1 heated to 50°C for 10 minutes, cooled to ambient temp, at EPA T&E Laboratory.
{value} = reported value is less than sample specific detection limit
(value) = not detected
H-2
-------
H-2
Chlorine Scrubber Water Inlet Results
H-3
-------
Chlorine Laboratory Scrubber Water In Results Summary Table H-2
Chlorine Scrubber Water In Results
(mg/L)
Run 2 Run 3 Run 4
T & E Sample No. MSD-WI-R2-211D MSD-WI-R3-311C MSD-WI-R4-413C/D
Analysis Date 7/21/99 7/22/99 7/23/99
Chlorine Scrubber Water In Results
Free Chlorine (mg/L) 0.01 0.05 0.03
Total Chlorine (mg/L) {-0.01} 0.08 0.05
Footnotes
1. Uncorrected for Blank Free or Total C12 content
2. Total C12 results are lower than corresponding free C12 results due to possible color interference.
3. Blank sample composed of DI water prepared by EPA T&E Laboratory staff.
{value} = reported value is less than sample specific detection limit
(value) = not detected
H-4
-------
H-3
Chlorine Scrubber Water Outlet Results
H-E
-------
Chlorine Laboratory Scrubber Water Out Results Summary Table H-3
Chlorine Scrubber Water Out Results
(mg/L)
Run 2 Run 3 Run 4
T & E Sample No. MSD-WO-R2-211D MSD-WO-R3-312D MSD-WO-R4-412C/D
Analysis Date 7-21-99 7-22-99 7-23-99
Chlorine Scrubber Water Out Results
Free Chlorine (mg/L) 0.03 0.05 0.01
Total Chlorine (mg/L) 0.05 0.03 0.02
Footnotes
1. Uncorrected for Blank Free or Total C12 content
2. Votal C12 results are lower than corresponding free C12 results due to possible color interference.
3. Blank sample composed of DI water prepared by EPA T&E Laboratory staff.
{value} = reported value is less than sample specific detection limit
(value) = not detected
H-6
-------
H-4
Chlorine Lab Sludge Blank Results
H-7
-------
Chlorine Laboratory "Sludge" Blank Results Summary Table H-4
Chlorine Laboratory Blank Fractions
(mg/L)
Laboratory Laboratory
Blank Spike
T & E Sample No. Blank Extract Blank Extract N/A
Analysis Date 7/22/99 7/23/99
Chlorine Analvtes
Free Chlorine (mg/L) 0,03 0.04
Total Chlorine (mg/L) 0.01 0.03
Footnotes
1. Blank extract sample composed of extract fluid generated from 5.01 grams of sludge mixed with 96.5 milliliters
(mL) Dl water, 3.5 mL HC1 heated to 50°C for 10 minutes, cooled to ambient temp, at EPA T&E Laboratory.
{value} = reported value is less than sample specific detection limit
(value) = below detection limit
H-8
-------
H-5
Chlorine Lab Water Blank Results
H-i
-------
Chlorine Laboratory "Scrubber Water" Blank Results Summary Table H-5
Chlorine Laboratory Blank Fractions
(rog/L)
T & E Sample No.
Analysis Date
Chlorine Analvfes
Free Chlorine (mg/L)
Total Chlorine (mg/L)
Laboratory
Blanks
Blank PI
7/21/99
0.03
0.02
Blank PI
7/22/99
0.04
0.01
Blank PI
7/23/99.
0.03
0.02
Footnotes
1. Blank sample composed of DI water prepared by EPA T&l Laboratory staff.
{value} = reported value is less than sample specific detection limit
(value) = below detection limit
H-10
-------
H-6
Chlorine Field Water Blank Results
H-11
-------
Chlorine Field "Scrubber Water" Blank Results Summary Table H-6
Chlorine Field Blank Fractions
(mg/L)
Field
Blanks
T & E Sample No. GrabWI Grab WO Grab WO-DUP
Analysis Date 7/21/99 7/21/99 7/21/99
Chlorine Analvtes
Free Chlorine (mg/L) 0.05 0.04 0.04
Total Chlorine (mg/L) 0.09 (0.00) (0.00)
\
Footnotes
\
1. Uncorrected for Blank Free or Total C12 content
2. Total C12 results are lower than corresponding free C12 results due to possible color interference.
3. Field blank samples composed of DI water prepared by EPA T&E Laboratory staff.
{value} = reported value is less than sample specific detection limit
(value) = below detection limit
H-12
-------
H-7
Chlorine Lab Raw Data Sheets
H-13
-------
Battelle Project
Soil Samples
Q.CO
\ Kr To
Msa-.s-f.j-
"97
'25.39
frfto Ull
ViO
BlflMK
MSb-vil-RM-
hi
0 Ol
O.OH
O.03
O.Ol
-Q.OI
0.02
nr>)
5. 01
3LUUfr£
&.3I
«50*C
>0
ro
/ Witt ^6" o5
H-14
-------
Battelle Project
Soil Samples
If
'
H-15
-------
Table 2: BatteMe Project Sludge Sample Results
CD
7/22/99
7/22/99
7/23/99
7123199
MSD-S-R3-313D/C
BLANK EXTRACT
SD-S-R4-411C/D
BLANK EXTRACT
0.01
0.03
0.04
0.04
0.01
0.01
0.01
0.03
0.001033
0.001003
0.500
0.430
19.99
20.43
4.84
17.14
(1) Not corrected for Blank Clz readings
(2) Calculation used: (mg C\J L extract) X (L extract/ Kg Sludge) = mg C\J Kg Sludge
4.84
4.29
-------
Table 3: Battelle Project Water Sample Results
7/21/99
MSD-WO-R2-212D
0.03
0.05
0.15
7/21/99
GRABW1
0.05
0.09
7/21/99
GRAB WO
0.04
0.00
7/21/99
GRAB WO-DUP
0.04
0.00
7/21/99
BLANK D!
0.03
7/22/99
MSD-WO-R3-312D
0.05
7/22/99
MSD-WI-R3-311C
0.05
7/22/99
BLANK Dl
0.04
7/23/99
MSD-WI-R4-413C/D
0.03
0.02
0.03
0.08
0.01
0.05
0.14
0.13
0.15
7/23/99
MSD-WO-R4-412C/D
0.01
0.02
0.16
7/23/99
BLANK Di
0.03
0.02
(1) Not corrected for Blank Free CIZ or Total Clz readings
(2) Total C!2 results are lower in some cases than the corresponding free CI2 result:;
possibly due to color interference.
H-17
-------
APPENDIX I
Percent Solids Analytical Lab Raw Data Results
-------
1-1
Total Percent Solids Results Summary
1-1
-------
Total % Solids Laboratory Sludge Results Summary Table 1-1
Total % Solids Sewage Sludge Results
(% Solids)
BJULl Run 3 Run 4
T&E Sample No. MSP-S-R1-113D MSP-S-R3-313D/C MSB-S-R4-411C/D
Analysis Date 7-21-99 7-22-99 7-23-99
Total % Solids
Sewage Sludge Results
Total % Solids
AEquotA 23.53 20.04 20.39
Aliquot B 23.47 20.02 20.33
Aliquot C 23.54 19.91 20.58
Average 23.51 19.99 20.43
Other Standards Percent Recovery
N/A
Footnotes
1-2
-------
Total % Solids Laboratory Scrubber Water In Results Summary Table 1-2
Total % Solids Scrubber Water In Results
(% Solids)
T & E Sample No.
Analysis Date
Total % Solids
Scrubber Water In Results
Total % Solids
Aliquot A
Aliquot B
Aliquot C
Average
Run 2
MSD-WI-R2-211D
7/21/99
0.144
0,148
0.146
0.146
Run 3 .
MSD-WI-R3-311C
7/22/99
0.135
0.117
0.134
0.129
Run 4
MSP-WI-R4-413C/D
7/23/99
0.148
0.146
0.145
0.146
Other Standards Percent Recovery
N/A
Footnotes
-------
Total % Solids Laboratory Scrubber Water Out Results Summary Table 1-3
Total % Solids Scrubber Water Out Results
(% Solids)
T & E Sample No,
Analysis Date
Total % Solids
Scrubber Water Out Results
Total % Solids
Aliquot A
Aliquot B
Aliquot C
\
* Average
Run 2
MSD-WO-R2-212P
7-21-99
0.154
0.154
0.154
0.154
Run 3
MSP-WO-R3-3J2P
7-22-99
Ran 4
MSP-WO-R4-412C/D
7-23-99
0.142
0.141
0.142
0.142
0.159
0.157
0.158
0.158
Other Standards Percent Recovery
N/A
Footnotes
1-4
-------
1-2
Lab Raw Data Sheets
1-5
-------
Date: Time:
Initial:
Battelle Total Solids
(TCORP PN773t82-1ft
-------
Date: 7/21/9§
Initial: RR
Battclle Total Solids
IT CORP
BaltellB Study
-------
Data; 7/22/99
Initial: RR
Battelle Total Solids
09
BAT
48.2665
62.8176
51.1820
20.04
EMU
PLOW
PENGUIN
8
CAT
FOXHOUND
AARDVARK
49.3748
45.7975
' 49.8530
48,8554
55.7526
46.9767
44.5017
60.7136
65.5715
91.7174
97.0765
104.8808
95.7014
81.7426
CHICKEN 53.1790 99.6085
51.6449
49.7354
49.8097
48.9119
55.8183
47.0460
44.5685
53.2449
20.02
I) 19.91
~]| 0.135
0.117
II 0.134
| 0.142
I 0.141
J 0.142
J 19.98
J 0-129
J 0.142
1 1
-------
Battollo Total Solids
Date: 7/23/99
Initial: RR
IT CORP
Battalia Study
-------
APPENDIX J
Ultimate / Proximate Analytical Results
-------
J-l
Analytical Summary
-------
Table 2-23. Ultimate Analysis Results for Sewage Sludge
Table 2-24. Proximate Analysis Results for Sewage Sludge
Volatile Matter, %
Fixed Carbon, %
Sulphur, %
BTU Content {BTU/Ibi
J-2
-------
J-2
Lab Raw Data Sheets
J-3
-------
COMMERCIAL TESTING & ENGINEERING CO.
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August 24, 2999
BATTELLE MEMORIAL
Columbus I*boratorie8
505 Kins Avenue
ColwnbuB, OH 43201
David Davis
WOMBS *U. CWWESPQNDKNCe TO;
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teksn by - — --
O»t« aaaplafi August 5,
Data r*c«iv»d Auguct 6, 1999
ID: 47904-73-11
P.O. HO. 151530
-117,?'
Raport »o.
71-96923
Page 1 of 1
PROXIMATE AKM.YSIS
Btu/lb
% Sulfur
MAT BtU
1(29
0.32
OtTOOiTg AHALYSIS
A* Raeaivad Dry Baai«
% JJoiatuxa
% Jiih
% Volmtila
Fixed Carbon
76.22
9.10
13.88
0-gQ •
100.00
3QPOOC
38. 2«
fl.3S
'• „ 3.3?
100.00
6852
1.33
11098
Caxboo
% Sulfur
% JUh
A« Rfceaivafl Pry Bails
7S.22
s.os
1.38
1.13
0.32
9.10
100.OC
yaocxx
36.24
4.95
4.76
1.33
36.26
IOC.00
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ttu/lbi UTM E 711; Mifur: AtTN 6 OWlNKIIWd C); Cifben, l|iltHin K •ttreDvu JtSTH ft 5373; oxygent C*tcJlat«d
V»tu»
-------
COMMERCIAL TESTING & ENGINEERING CO.
cewMi. wncE& ml SOUTH HWAAND ««. sura MM. IOMMRO. uwon «n« *
twee
24, 1999
BATTELLE MEMORIAL INSTITUTE
Columbus Laboratories
505 King Avenue
Columbus, OK 43201
At tu : David Davi«
ADDRESS *U. COBWWONDENC6 70=
1CI JO MN DflUNEN HO.
SOUTH HOLLAND. *-«0*n
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takan at Battelle
t«*«tt by • — --
Oat* sanpleiJ August: 5, 1999
Date rec«iv»d August 6, 1999
ID; €7904-74-5
P.O. Ho. 151530
An«ly»i» Report Ho. 71-98924
Page 1 of I
PROXIMATE ANALYSIS
A« Seccivod
tTLTMATi: AHXLYS^p
Ptrv Baala
ETV
% »oi.t«r.
% A»h
% Volatil*
% Fixed Carbon
Btw/lb
% Sulfur
MAP Btu
7S.13
7.74
12.24
O.B?
100.00
1481
0.28
3CXXXX
37.07
S8.67
4.26
100.00
7097 % (
1.31
11278
% Moisture
% Carbon
% Bydrogan
% Hitxogma
% Sulfur
% JUb
)«ygan(di«)
79.13
7.73
1.03
0.94
0.38
7.74
3.1?
100.00
XXXXX
37.03
4.93
4.51-
1.33
37.07
%f.i|
100.00
NoiEtur*: JISTM E 949; Aths WTB E BK; Vein He: A3TH f 897f Find c»rb«i: Calculated Value; UTN D 3172
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J-5
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COMMERCIAL TESTING «t ENGINEERING CO.
ini tour* WSHUWD me, suns *io-s. iflMawn, tmoa wm » m,-
ItaMMt * ft*
August 24, 1999
BATTELLE MEMORIAL IflbTlTUTE
Columbia Laboratories
505 King Avenuo
Columbus, OH 43201
ACtn:
AODMEB8 MI. COmeSPONOENCE TO:
SOUTH HOLLANa It IM73
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Date recaivad August C, 1999
ID: 47904-75-11
P.O. HO. 151530
Analysis R«port Mo.
71-99925
i of 1
PROXIMATE AKALYSTS
TJLTntATK AKALTSZS
T>rv
A« meeeived Pry
% Moisture
% Ash
% Volatile
% Fixed carbon
BtWlb
% Sulfur
MAP Btu
71.28
7.75
13.04
100.00
1586
0.29
xxxxx
35. «8
60.03
- _ « ul»
100.00
7302 %
1.35
11353
% Holature
% Carboo
%^irJt*rfM»m
•yarofea
% Bitrogen
% Sulfur
% A*h
78.28
8.55
1.12
1.07
0.29
7.7S
100, 00
xxxxx
39.35
5. IS
4.91
1.38
35.68
JUL2&
100 , OC
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J-6
-------
TECHNICAL REPORT DATA
(Please read Instructions on reverse before completing}
I, REPORT NO.
EPA-454/R-00-038c
3, RECIPIENTS ACCESSION NO.
4. TTTLE AND SUBTITLE
Source Characterization For Sewage Sludge Incinerators
Final Emissions Report, Volume II of III, Appendix A - Appendix J
Metropolitan Sewer District (MSB) Mill Creek Wasterwater Treatment Plant
Cincinnati, Ohio
5. REPORT DATE
September 2000
6, PERFORMING ORGANIZATION CODE
7. AUTHORS)
Clyde E. Riley, USEPA
Jeffery A. Ferg, Battelle
Anthony S. Wisbith, Battelle
Dennis A. Falgout, PES
8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Battelle
505 King Avenue
Columbus, Ohio 43201-2693
10. PROGRAM ELEMENT NO,
11, CONTRACT/GRANT NO, 68-D-99-009
12. SPONSORING AGENCY NAME AND ADDRESS
Emissions, Monitoring and Analysis Division
Office of Air Quality Planning and Standards
U.S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
13. TYPE OF REPORT AND PERIOD COVERED
Final; January 99 to September 2000
M. SPONSORING AGENCY CODE
EPA/200/04
IS. SUPPLEMENTARY NOTES
16. ABSTRACT
The Clean Air Act Amendments of 1990 require the U.S. Environmental Protection Agency's (EPA) Office of Air •
Quality Planning and Standards (OAQPS) to establish standards of performance for sewage sludge incineration. These standards
are necessary to protect public health and the environment from any adverse effects of pollutant emissions from sewage sludge
incineration. The regulations will contain general regulatory requirements, pollutant characterization, and emission limits. To
assess control technologies as well as associated strategies for cost-effective standards, EPA requires data on PCS, D/F, and PAH
emissions from sewage sludge incinerators . While some emission data exist for sewage sludge incinerators, data on coplanar
polychlorinated biphenyls (PCBs) from sewage sludge incinerators are very limited.
The test report summarizes testing of a multiple hearth incinerator at the Metropolitan Sewer District (MSB) Mill Creek
Wastewater Treatment Plant in Cincinnati, Ohio in July, 1999. The emission data collected in this test program will be used by
EPA/OAQPS and EPA's Office of Water (OW) to support a decision about further data gathering efforts in support of MACT
standards for sewage sludge incinerators. During the testing, a second EPA contractor monitored and recorded the process and
emission control system operating parameters, and prepared Section 4.0, Process Description And Operation of the report. The
report consist of five documents: Executive Summary Report; Volume I-Main Report; Volume II-Appendices A-J; Volume Ill-
Appendices K-P; and a Data Quality Assessment Report.
17.
KEY WORDS AND DOCUMENT ANALYSIS
a. DESCRIPTORS
PCBs
PAHs
Dioxins/fuians
18, DISTRIBUTION STATEMENT
Release Unlimited
b. IDENTIFIERS/OPEN ENDED TERMS
Air Pollution control
19. SECURITY CLASS Report)
Unclassified
20. SECURITY CLASS (Page)
Unclassified
C. COSATI
Field/Group
21. NO. OF
PAGES
m. PRICE
ETA Form 2220-1 flier. 4-77)
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