EPA 600/R-16/220 | November 2016 | www.epa.
United States
Environmental Protection
Agency
SEPA
Characterization of Emissions from Open Burning of
Meals Ready-to-Eat and their Paperboard Packaging
Office of Research and Development

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Characterization of Emissions from Open
Burning of Meals Ready-to-Eat and their
Paperboard Packaging
Johanna Aurell1, Brian Gullett2*
University of Dayton Research Institute
2U.S. Environmental Protection Agency, Office of Research and
Development
August 17, 2016

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Acknowledgments
The authors appreciate the technical sampling assistance provided by Captain Thomas Dominguez,
USAF, Air Force Institute of Technology, and his advisor, Lt. Col. Dirk Yamamoto. Paul Freeman, currently
at Calvin College, Grand Rapids Ml, provided critical volunteer assistance during the burns. Technical
support was provided by Steve Terll, ARCADIS U.S., Inc. Analyses were significantly aided by the
contribution of Dennis Tabor, US EPA.
Disclaimer
The views expressed in this report are those of the authors and do not necessarily represent the views
or policies of the U.S. Environmental Protection Agency.
i

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Executive Summary
Emissions from burning current and candidate Meals Ready-to-Eat (MRE) packaging and shipping
containers were characterized in an effort to assuage concerns that combustive disposal of waste at
forward operating bases could pose an environmental or inhalation threat. Four types of container
5 materials, both box and liners, including the currently used fiberboard, new corrugated fiberboard with
Spectra-kote polymer, new fiberboard without Spectra-kote polymer, and the current fiberboard
without wet strength were burned in an open burn test facility that simulated the burn pit disposal
methods in Iraq and Afghanistan. MREs, including both current and proposed packaging materials, were
added to a single container type to examine their effect on emissions. One quarter of the food was left
10 in the packaging to represent unused meal components. The proposed packaging, consisting of a nano-
composite polymer, was added in 25 % increments compared to traditional MRE packaging to create a
range of usage levels. Emission factors, mass of pollutant per mass of burned material, were increased
over the emission factors of the package containers themselves by the addition of the multi-component
MREs, with the exception of Volatile Organic Compounds (VOCs). In general, little distinction was
15 observed when comparing emission factors from the four container materials and when comparing the
four MRE compositions. The majority of Particulate Matter (PM) emissions were of particles that were
below 1.0 pirn in aerodynamic diameter for the fiberboard tests; PM2.sand PMio emissions increased
five-sixfold when MREs were added to fiberboard packaging. Emission factors, particularly VOCs, were
negatively correlated to modified combustion efficiency. As combustion quality improved, VOCs and,
20 less notably, polychlorinated dibenzodioxins/polychlorinated dibenzofurans (PCDDs/PCDFs) declined.

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I
Table of Contents
1. Introduction	
1.1	Background	
1.2	Objectives	
2	Materials and Methods	
2.1	Test Materials	
2.1.1	Fiberboard	
2.1.2	Meal Ready-to-Eat	
2.2	Open Burn Test Facility	
2.3	Test Procedure	
2.3.1	Test Matrix	
2.3.2	E mission Sampling System	
2.4	Emission Sampling and Analytical Methods	
2.4.1	SVOCs	
2.4.2	VOCs	
2.4.3	PM	
2.4.4	C02	
2.4.5	CO	
2.5	Calculations	
2.5.1	Emission factors	
2.5.2	PCDD/PCDF Toxic Equivalent Calculations
2.5.3	Modified Combustion Efficiency	
2.6	Data Precision	
3	Results and Discussion	
3.1	PM	
3.1.1	Fiberboard packaging	
3.1.2	MRE pouches	
3.2	Metals and Other Trace Elements	
3.3	VOCs	
3.3.1	Fiberboard packaging	
3.3.2	MRE pouches	

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3.4 PAHs	23
3.4.1	Paperboard packaging	23
3.4.2	MRE pouches	25
55 3.5 PCDD/PCDF	27
3.5.1	Fiberboard packaging	27
3.5.2	MRE pouches	30
4	Quality of Data and Data Limitations	32
5	Conclusions	33
60 6 References	34
II

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List of Figures
Figure 2-1. A) MRE menu "Spicy penne pasta vegetarian" was used as the base for each waste
65 category burned. Heater not used due to safety concerns (release of H2 gas). B) New nanocomposite
packaging	3
Figure 2-2. Schematic of open burn test facility. Not to scale	6
Figure 2-3. The paperboard test material (corrugated Spectra-kote Polymer Fiberboard box and
liner) atop aluminum foil (left) on 1 m x 1 m (3.2 ft x 3.2 ft) steel pan. Combustion of same (right).. 6
70 Figure 2-4. MRE (100 % OLD material or 0 % NEW) on 3.2 x 3.2 foot steel pan, before (left) and
after (right) burn	7
Figure 2-5. Flyer sampling instruments	9
Figure 2-6. Monitoring of CEMs, SVOC flow rate, temperature, and SUMMA canister pressure during
a burn	9
75 Figure 3-1. Typical traces of PM, CO, and CO2 throughout each of the fiberboard type burnburns...,16
Figure 3-2. PM2.5 and PM10 emission factors and modified combustion efficiency (MCE) for each
replicate	17
Figure 3-3. PM2.5 and PM10 emission factors from open burning of fiberboard. Error bars represent 1
STDV	17
80 Figure 3-4. PM emission factors from open burning of MREs. Error bars represent 1 STDV	18
Figure 3-5. PM2.5 and PM10 emission factors and modified combustion efficiency (MCE) for each
replicate	19
Figure 3-6. Major metal and trace /element emission factors from open burning ofMRE's	19
Figure 3-7. Select VOCs and their emission factors for the different fiberboard types. * = on EPA's
85 list of hazardous air pollutants	20
Figure 3-8. Select VOCs versus modified combustion efficiency (MCE)	21
Figure 3-9. VOC emission factors from open burning of MREs. * = on EPA's list of Hazardous Air
Pollutants (HAPs)	22
Figure 3-10. Select VOC emission factors versus modified combustion efficiency (MCE)	23
90 Figure 3-11. Benzene and acrolein vs. MCE for all MRE waste compositions and fiberboard types
burns	23
Figure 3-12. PAH emission factors from open burning of fiberboard packaging. Error bars represent
1 standard deviation	24
Figure 3-13. PAH emission factors from open burning of MREs. Error bars represent 1 standard
95 deviation	26
Figure 3-14. PCDD/PCDF emission factors from open burning of fiberboard packaging. Error bars
represent 1 standard deviation	28
III

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Figure 3-15. Fiberboard PCDD/PCDF emission factors versus modified combustion efficiency
(MCE)	29
100 Figure 3-16. PCDD/PCDF emission factors from open burning of MREs. Error bars represent 1
standard deviation	30
Figure 3-17. MRE PCDD/PCDF emission factors versus modified combustion efficiency (MCE)	32
IV

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105 List of Tables
Table 2-1. Ultimate proximate analysis for the seven fiberboard materials	2
Table 2-2. Weight percentage of material in each waste category.3	4
Table 2-3. Carbon fraction of each waste material and category.3	5
Table 2-4. Fiberboard test matrix.ฎ	7
110 Table 2-5. MRE test matrix.a	8
Table 2-6. Collected samples for each test category	8
Table 2-7. Flyer emission sampling	9
Table 2-8. PCDD/PCDF Toxic Equivalency Factors for mammals/humans [12]	14
Table 2-9. PAH Toxic Equivalency Factors for humans [17]	14
115 Table 3-1. PM emission factors	18
Table 3-2. Major metal and trace /element emissions from open burning of MRE pouches.3	20
Table 3-3. VOC emission factors	21
Table 3-4. VOC emission factors from open burning of MREs	22
Table 3-5. PAH emission factors from open burning of fiberboard in mg/kg fiberboard	24
120 Table 3-6. PAH TEQ emission factors from open burning of fiberboard in mg B[a]P TEQ/kg
fiberboard.ฎ	25
Table 3-7. PAH emission factors from open burning of MRE pouches in mg/kg MRE	26
Table 3-8. PAH TEQ emission factors from open burning of MRE pouches in mg B[a]P TEQ/kg MRE.a
	27
125 Table 3-9. PCDD/PCDF TEQ emission factors	28
Table 3-10. PCDD/PCDF Total emission factors	29
Table 3-11. PCDD/PCDF TEQ emission factors	31
Table 3-12. PCDD/PCDF Total emission factors	31
130
V

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List of Appendices
Appendix A: Data for each sample collected from Open Burning of Fiberboard.
Appendix B: Data for each sample collected from OB of MRE pouches.
135
VI

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List of Acronyms
AN OVA	Analysis of variance
BTU	British thermal unit
CB	Current fiberboard box
CEM	Continuous emission monitor
CH4	Methane
CL	Current fiberboard liner
CO	Carbon monoxide
CO2	Carbon dioxide
DoD	U.S. Department of Defense
EPA	U. S. Environmental Protection Agency
ESTCP	Environmental Security Technology Certification Program
FID	Flame ionization detector
GC	Gas chromatography
HRGC	High Resolution Gas Chromatography
HRMS	High Resolution Mass Spectrometry
IARC	International Agency for Research on Cancer
IR	Infrared
LOD	Limit of Detection
MCE	Modified combustion efficiency
MLS	Montmorillonite-layered silicates
MRE	Meal, Ready-to-Eat
ND	Not detected
NDIR	Non-dispersive infrared
NSB	No Spectra-kote box
NSL	No Spectra-kote liner
NSRDEC	Natick Soldier Research, Development and Engineering Center
NWS	Current fiberboard box - no wet strength
OBTF	Open Burning Testing Facility
PAHs	Polycyclic aromatic hydrocarbons
PCDDs	Polychlorinated dibenzo-p-dioxin
PCDFs	Polychlorinated dibenzofurans
PCF	photometric calibration factor
PM	Particulate matter
PMi	Particulate matter of 1 micrometers or less
PM10	Particulate matter of 10 micrometers or less
PM2.5	Particulate matter of 2.5 micrometers or less
PM4	Particulate matter of 4 micrometers or less
PUF	Polyurethane foam
RPD	Relative percent difference
VII

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RSD
Relative standard deviation
SB
Corrugated Spectra-kote polymer fiberboard box
SL
Corrugated Spectra-kote polymer fiberboard liner
STDV
Standard deviation
SVOC
Semivolatile organic compounds
TEF
Toxic equivalency factors
TEQ
Toxic equivalency
VOC
Volatile organic compound
WHO
World Health Organization
XAD-2
Brand name of sorbent polymeric resin (crosslinked polystyrene copolymer)
VIII

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140 1. Introduction
1.1	Background
Approximately 4000 tons of MRE (Meal, Ready-to-Eat) solid fiberboard packaging waste is generated
every year [1], This amount of waste, coupled with rising disposal costs and hazards encountered with
open pit burning in contingency base operations, has dramatically increased the need to investigate
145 alternative materials and designs for combat ration fiberboard packaging applications. This project is a
follow-up of a study sponsored by the U.S. Department of Defense (DoD), performed by the Natick
Soldier Research, Development and Engineering Center (NSRDEC) to research and develop novel
lightweight fiberboard structures to replace the existing military fiberboard containers, with the
ultimate goal to reduce the amount of solid waste for the military. This demonstration/validation
150 project, "Lightweight and Compostable Packaging for the Military", is sponsored through a U.S. Army-
operated Environmental Security Technology Certification Program (ESTCP), funded by DoD for
examining the replacement of solid fiberboard with coated corrugated containers for MRE rations. Each
fiberboard box and liner contains 12 MREs. Additional research by NSRDEC is ongoing for the potential
replacement of MRE aluminum-based pouches with pouches that are multi-layer, nanocomposite-based
155 polymer materials that can potentially provide greater barrier and mechanical properties [2], The
combined effect of these packaging and MRE material changes has uncertain effects on emissions from
combustion disposal.
1.2	Objectives
The objectives of this work were to determine and compare air emissions from open burning of:
160	• Current and newly-developed MRE fiberboard packaging options; and
• Current MRE aluminum-based pouches and newly-developed nanocomposite-based pouches.
Emissions that were characterized included health-related compounds: PM2.sand PMio (particulate
matter with aerodynamic diameter equal to and less than 2.5 pim in diameter and particulate matter
with aerodynamic diameter equal to and less than 10 pim in diameter), elements/metals in PM,
165 polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDDs/PCDFs), polycyclic
aromatic hydrocarbons (PAHs), carbon monoxide (CO), carbon dioxide (C02), and volatile organic
compounds (VOCs). PM2.5 is a criteria pollutant regulated by the U.S. EPA since these particles can enter
the lungs when inhaled and potentially carry metals and other toxic pollutants, which can cause adverse
health effects. PCDDs/PCDFs are persistent in the environment and are of interest due to their health
170 effects including immunotoxicity, carcinogenicity, and teratogenicity. Many VOCs are on the U.S. EPA's
list of hazardous air pollutants with properties that are toxic and carcinogenic for humans. Some PAHs
are classified as possible human carcinogens.
1

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175 2 Materials and Methods
2.1 Test Materials
2.1.1 Fiberboard
Seven fiberboard materials were studied for their emissions when combusted in an open burn scenario:
•	Current solid fiberboard box (CB);
180	• Current solid fiberboard liner (CL);
•	New corrugated fiberboard box with Spectra-kote polymer (SB) (Spectra-kote Corp., Gettysburg,
PA, USA);
•	New corrugated fiberboard liner with Spectra-kote polymer (SL);
•	New fiberboard box with no Spectra-kote polymer (NSB);
185	• New fiberboard liner with no Spectra-kote polymer (NSL); and
•	Current solid fiberboard box without wet strength (NWS) polymer.
Analyses of these materials (Galbraith Laboratories, Inc., Knoxville, TN, USA) are reported in Table 2-1.
Differences in the Spectra-kote boxes/liners are noted, particularly for loss on drying, chlorine, and
sulfur.
190
Table 2-1. Ultimate proximate analysis for the seven fiberboard materials.
Current Current
Fiberboard Fiberboard
Solid Box Liner
Corrugated	Corrugated
Spectra-	Spectra-
kote	kote
Polymer	Polymer
Fiberboard	Fiberboard No Spectra-
Box	Liner kote Box
No Spectra-
kote Liner
Current
Fiberboard
Box - No
Wet
Strength
Code
CB
CL
SB
SL
NSB
NSL
NWS
Heat of combustion
(BTU*/lb)1
Loss on drying (%)2
Carbon (%)3
Chlorine (ppm)4
Hydrogen (%)5
Nitrogen (%)6
Sulfur (%)7
8121
7.45
46.3
188
6.08
<0.5
0.234
7955
7.49
46.19
185
6.16
<0.5
0.243
7537
9.45
44.99
297
6.13
<0.5
0.162
7166
9.13
45.44
251
6.02
<0.5
0.155
7598
9.48
45.36
97
6.29
<0.5
0.149
7979
8.51
45.85
57
6.20
<0.5
0.140
8145
10.24
46.56
139
6.03
<0.5
0.236
* British thermal unit(s). Galbraith procedures: 1S-231; 2S-200; 3ME-14; 4ME-4A; 5ME-14; 6ME-14; 7E16-2.
2.1.2 Meal Ready-to-Eat
195 MRE packaging consists of a new nanocomposite material and old aluminum-based material. Research
conducted by NSRDEC is developing a new potential replacement for the aluminum-based pouches. The
new packaging consists of a multi-layer, nanocomposite-based polymer material that can potentially
provide greater barrier and mechanical properties [2], The novel materials disperse modified
montmorillonite-layered silicates (MLSs) into thermoplastic in a layered molecular structure that
2

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200 increases the path length of diffusing gases (i.e., oxygen and moisture) and improves the shelf life of the
MRE contents.
MRE menu number 14, Spicy penne pasta vegetarian, was used as the base food for the testing and
number of packages and sizes to assure a good reproducibility. Four different MRE packaging categories
were studied, comprising different percentages of new nanocomposite and old aluminum-based
205 material: 0 % NEW (only old material), 32 % NEW (32 % new material and 68 % old material), 66 % NEW
(66 % new material and 34 % old material), and 100 % NEW (only new material) (Table 2-2). The total
carbon fraction of each waste material in the four waste categories was calculated using carbon
fractions from Liu and Liptak [3], as well as sugar (0.42) and carbohydrates (0.44, as starch) (Table 2-3)
For all MRE tests, the current fiberboard packing was used as a substrate (CB/CL, Table 2-1).
210
A NEW	OLD
NEW
material
Heater
Figure 2-1. A) MRE menu "Spicy penne pasta vegetarian" was used as the base for each waste
category burned. Heater not used due to safety concerns (release of H2 gas). B) New nanocomposite
packaging.
215
3

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Table 2-2. Weight percentage of material in each waste category.3
Waste Material
0%
NEW
32%
NEW
66%
NEW
%
100%
NEW
Old Al-based material
11
5.7
3.6
NA
New nanocomposite Material
NA
3.6
7.0
11
Plastic
17
18
16
17
Cardboard
29
30
28
29
Paper
1.6
1.6
1.5
1.6
Al-bag
1.7
1.7
6.6
1.7
Matches
1.0
1.0
0.92
1.0
Adsorbent package
0.47
0.48
0.45
0.47
Food waste: Penne pasta
16
17
16
16
Beef stick
2.8
2.8
2.6
2.8
Toaster pastry
4.1
4.2
3.9
4.1
Crackers
2.8
2.8
2.6
2.8
Pretzels
2.6
2.7
2.5
2.7
Cappuccino powder
2.1
2.1
2.0
2.1
Salt
0.65
0.66
0.62
0.65
Seasoning
0.26
0.27
0.25
0.27
Iced tea powder
5.0
5.1
4.8
5.0
Chewing gum
0.82
0.84
0.78
0.83
a Each waste category comprised of different percentages of new nanocomposite and old
aluminum-based material, e.g., 32 % NEW = 32 % new nanocomposite material and 68 %
old Al-based material of the total waste.
220

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Table 2-3. Carbon fraction of each waste material and category.3
Waste Material
Carbon Fraction
in Material
0 % 32 % 66 % 100 %
NEW NEW NEW NEW
Carbon fraction from each waste category13
Old materia

0.37
4.2E-02
2.1E-02
1.3E-02
NA
New Material
0.74
NA
2.7E-02
5.2E-02
8.2E-02
Plastic

0.74c
1.3E-01
1.3E-01
1.2E-01
1.3E-01
Cardboard

0.46
1.4E-01
1.4E-01
1.3E-01
1.4E-01
Paper

0.44c
7.0E-03
7.1E-03
6.6E-03
7.0E-03
Al-bag

0.0076c
1.3E-04
1.3E-04
5.0E-04
1.3E-04
Matches

0.50
4.9E-03
5.0E-03
4.7E-03
4.9E-03
Adsorbent package
0.0076c
3.6E-05
3.7E-05
3.4E-05
3.6E-05
Food waste:
Penne pasta
0.092
1.5E-02
1.5E-02
1.4E-02
1.5E-02

Beef stick
0.28
7.7E-03
7.8E-03
7.3E-03
7.7E-03

Toaster pastry
0.43
1.8E-02
1.8E-02
1.7E-02
1.8E-02

Crackers
0.51
1.4E-02
1.4E-02
1.3E-02
1.4E-02

Pretzels
0.39
1.0E-02
1.1E-02
9.9E-03
1.0E-02

Cappuccino
0.45
9.4E-03
9.6E-03
8.9E-03
9.4E-03

Salt
0.0076
4.9E-05
5.0E-05
4.7E-05
4.9E-05

Seasoning
0.49
1.3E-03
1.3E-03
1.2E-03
1.3E-03

Iced tea
0.49
2.4E-02
2.5E-02
2.3E-02
2.4E-02

Chewing gum
0.49
4.0E-03
4.1E-03
3.8E-03
4.0E-03
Total

NA
0.42
0.44
0.43
0.46
a Each waste category comprised of different percentages of new nanocomposite and old aluminum-based
material, e.g., 32 % NEW = 32 % new nanocomposite material and 68 % old Al-based material of the total
waste.b Data from Liu and Liptak [3],c Carbon fraction in material x waste fraction in recipe.
225
2.2 Open Burn Test Facility
This work was conducted in the U.S. EPA's Open Burning Testing Facility (OBTF) located at EPA's
Research Triangle Park, NC, campus (Figure 2-2). The open burn test facility consists of a 12.8 x 12.8 x 15
230 feet (3.9 x 3.9 x 4.6 m) structure constructed with sheetrock wallboard that is covered with stainless
steel for ease of cleaning. High volume air handlers provide dilution air into the test facility to help
ensure that open burn conditions (minimal depletion of oxygen concentration) are maintained within
the facility during the tests. Measurements of the emissions exiting from the enclosed facility, together
with the dilution rate of incoming combustion air, allow for calculation of emission factors in terms of
235 pollutant mass per mass of material burned. The facility flowrate results in approximately one air
volume change every 90 sec. The dilution air and combustion emissions exit the test facility through an
8-inch diameter (20.3 cm) transfer duct.
5

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Air outlet

PAH Flyer 1 Flyer 2
sampler
Air inlet
Paperboard
CO CEM
Figure 2-2. Schematic of open burn test facility. Not to scale.
2.3 Test Procedure
The fiberboard/MRE sample was placed randomly on aluminum foil atop a sand-filled 3.2 x 3.2 foot (1 m
x 1 m) steel plate (Figure 2-3, Figure 2-4). The average fiberboard weight for each burn was 4.7 lb (2.1
245 kg), 5.6 lb (2.6 kg), 5.5 lb (2.5 kg) and 5.7 lb (2.6 kg) for CB/CL, SB/SL, NSB/NSL and NWS, respectively. Six
MRE bags and half of a CB/CL fiberboard box was used for each MRE burn (based on 12 MRE bags in one
fiberboard box); only 25 % of the food was included, simulating food not eaten.
Each burn was started with the use of a propane torch. Semivolatile organic compounds (SVOCs) and
particulate matter (PM) collection started at ignition while Volatile Organic Compound (VOC) (SUMMA
250 canister) sampling was started with a trigger when the C02 concentration had reached 800 ppm (this
delay avoided the SUMMA canister opening prematurely during the ignition while the operator was still
within the OBTF). VOC sampling was stopped when the C02 concentration diminished to 800 ppm. The
SVOC and PM collection were stopped when the C02 concentration had reached the background
concentration of approximately 400-500 ppm C02.
255
Figure 2-3. The paperboard test material (corrugated Spectra-kote Polymer Fiberboard box and
liner) atop aluminum foil (left) onlmxlm (3.2 ft x 3.2 ft) steel pan. Combustion of same (right).
6

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260 Figure 2-4. MRE (100 % OLD material or 0 % NEW] on 3.2 x 3.2 foot steel pan, before (left) and
after (right) burn.
2.3,1 Test Matrix
The fiberboard tests and the MRE tests were conducted at separate times, November 2014 and July
265 2015, respectively. The tests were performed in random order (Table 2-4 and Table 2-5).To receive
detectable levels of PCDD/PCDF, two to six separate burns had to be composited into one sample (one
test). Table 2-6 shows the number of collected samples for each fiberboard and MRE category. A
background sample was collected for each of the two test periods.
270 Table 2-4. Fiberboard test matrix.3
Fiberboard Type
Code
Test order
No. of Tests
Ash Samples
NA- OBTF Blank
BS
P re-Test
1
NA
Current Fiberboard Container and
CB/CL
3, 5, 7, 8
4
1 (composite)
Current Fiberboard Liner




New Polymer Coated Fiberboard
Container and New Polymer Coated
Fiberboard Liner
SB/SL
6, 9, 10, 11
4
1 (composite)
New Non-Polymer Fiberboard
Container and New Non-Polymer
Fiberboard Liner
NSB/NSL
4, 14, 15, 16
4
1 (composite)
Current Fiberboard, No Wet
Strength
NWS
1,2, 12, 13
4
1
NA - OBTF Blank
BS
Post-Test
1
NA
a NA - not applicable.
7

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Table 2-5. MRE test matrix.3
Test Material
Code
Test order
No. of Tests
MRE Menu No. 11, 100 % New Material
100 % NEW
1,4, 9
3
MRE Menu No. 11, 66 % New Material
66 % NEW
11,12, 13
3
MRE Menu No. 11, 32 % New Material
32 % NEW
7, 8,10
3
MRE Menu No. 11,0% New Material
0 % NEW
2, 3, 5
3
(100 % Old material)
(100 % OLD)


Baseline: Current Fiberboard Container
CB/CL
6
1
and Current Fiberboard Liner



NA - OBTF Blank
BS
Post-Test
1
a NA - not applicable.



Table 2-6. Collected samples for each test category.


VOCs



Test Category SUMMA Canisters PM2.5
PM10 PAH
PCDD/PCDF
CB/CL 5
10
10 5
5
SB/SL 4
7
7 4
4
NSB/NSL 4
8
8 4
4
NWS 4
10
10 3
4
100% NEW 3
6
6 3
3
66 % NEW 2
6
6 3
3
32 % NEW 3
6
6 3
3
0% NEW (100% OLD) 3
6
6 3
3
Background 2
2
2 2
3
Total 30
61
61 30
32
2.3.2 Emission Sampling System
Emission sampling was conducted using the "Flyer", which is a remotely controlled sampling system
280 (Figure 2-5) described more fully elsewhere [4; 5], The Flyer includes an on-board computer, control
software, and wireless transmitters which allow sampling to be monitored and controlled from a
distance. Sampling periods are controlled using "triggers" and software to operate multiple on/off
valves. Interchangeable sampling instruments allow for continuous C02, CO, temperature, and PM
measurements as well as batch sampling of VOCs, SVOCs, PMio and PM2.5. The on-board computer and
285 wireless data transfer also allow the operator to monitor C02 concentration, battery life, and pressure
drop across a filter in real time. All sensor data and flow rates are logged to the on-board computer. A
smaller version of the flyer was used to sample PAHs. To quantify the designated target analytes, the
Flyer was comprised of the instruments indicated in Figure 2-6 shows monitoring of the Flyer samplers.
8

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Dioxins
Dioxins
290
Figure 2-5. Flyer sampling instruments.
Table 2-7. Flyer emission sampling.
Pollutant
lnstrument/Method(s)
Duration
Analytical
Laboratory
PIVhsand PM10
SKC impactors, 47 mm Teflon filters, PM
by mass
Batch
Chester LabNet
PCDD/PCDF, PAH
Modified U.S. EPA Method TO-9A [6],
U.S. EPA Method 23 [7J/HRGC-HRMS,
U.S. EPA Method 8270D [8J/HRGC-
LRMS
Batch
EPA/ORD
VOCs
SUMMA Canister/U.S. EPA Method TO-
15 [9], including CO2, CO, CH4/U.S. EPA
Method 25C [10]
Integrated run,
12 min samples
ALS Simi Valley
Metals
Teflon filters/gravimetric and X-ray
fluorescence (XRF) [11]
Batch
Chester LabNet
PM mass arid size
DustTrak DRX (PM1, PM25, PM4, PM10
and Total PM)
Continuous
EPA/ORD
C02
LI-COR 820, Non-dispersive Infrared
(NDIR)
Continuous
EPA/ORD
CO
Electrochemical cell, e2V EC4-500-CO
Continuous
EPA/ORD
1066756?'--'-
14.9-5-
17.4 "w-
— n
Figure 2-6. Monitoring of CEMs, SVOC flow rate, temperature, and SUMMA canister pressure during
a burn.
9

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2.4 Emission Sampling and Analytical Methods
2.4.1 SVOCs
300 PCDDs/PCDFs and PAHs were sampled using a low voltage Windjammer and MINIjammer brushless
direct current blower (AMETEK Inc., Berwyn, PA, USA), respectively. The blowers were started via
wireless control at the start of the burn. The flow rate was measured by a 0-622 Pa pressure differential
transducer (Setra, Model 265, Boxborough, MA, USA) across Herschel Standard Venturi tubes. The
Venturi tubes were designed at EPA to meet the desired sampling rate for the target compound. The
305 Venturi tubes were mounted on the outlet of the Windjammer and MINIjammer blowers. The voltage
equivalent to this pressure differential was recorded on the onboard PC using the FlyerDAQ program or
ARDUINO-based computer, which was calibrated with a Roots meter (Model 5M, Dresser Measurement,
Addison, TX, USA) in the U.S. EPA Metrology Laboratory before sampling effort. A temperature
thermistor was used to measure the air temperature exiting the Venturi.
310 PCDD/PCDFPCDDs/PCDFs were sampled via modified U.S. EPA Method TO-9A [6] using a polyurethane
foam (PUF) sorbent preceded by a quartz microfibermicrofiber filter (20.3 x 25.4 cm) with a nominal
sampling rate of 0.85 m3/min (Windjammer). PAHs were also sampled via modified U.S. EPA Method TO-
9A [6] using a PUF/XAD-2 (polymer resin, Supelco Inc., Bellefonte, PA, USA)/PUF sorbent behind a quartz
microfibermicrofiber filter (70 mm in diameter) with a nominal sampling rate of 0.18 m3/min
315 (MINIjammer). The PUF (Tisch Scientific, North Bend, OH, USA) was cleaned before use by solvent
extraction with dichloromethane and dried with flowing helium to minimize contamination of the media
with the target analytes and remove unreacted monomer from the sorbent. The PUF and PUF/XAD/PUF
sorbents were mounted in a glass cartridges (Tisch Scientific) and inserted in a cartridge holder mounted
on the Windjammer and MINIjammer blowers. The samples was extracted and cleaned up according to
320 U.S. EPA Method 23 [7] and analyzed using high resolution gas chromatography/high resolution mass
spectrometry (HRGC/HRMS). Blanks were collected and analyzed.
2.4.1.1 PCDD/PCDF
Analysis of tetra- through octa-CDDs/CDFs was performed according to modified U.S. EPA Method 23
[7], Identification and quantification of the PCDD/PCDF congeners made use of a mixture of standards
325 (Cambridge Isotope Laboratories, Tewksbury, MA, USA) containing tetra-to octa-CDD/CDF native and
13C-labeled congeners as per modified U.S. EPA Method 23 [7], The PCDD/PCDF calibration solutions
were prepared in house and contained native PCDD/PCDF congeners at concentration from 0.25 to 40
ng/mL.
The 2005 World Health Organization (WHO) 2005 toxic equivalency factors (TEFs) [12] were used to
330 determine the PCDD/PCDF toxic equivalency (TEQ) emission factors (see Chapter 2.5 for calculations).
Not all TEF-weighted PCDD/PCDF congeners were detected in all samples. The congeners that were not
detected (ND) were set to zero in the text although Appendix A and B show the PCDD/PCDF values both
at ND = 0 and ND = limit of detection (LOD)). All surrogate standard recoveries were between 63 % and
110 % for the fiberboard burn samples, which was within the standard method criteria (25-130 %). Some
335 of the surrogate standard recoveries were outside the standard method criteria (25-130 %) for the MRE
10

-------
burn samples due to interference from significant amounts of other compounds in the 13C channels
causing a low response for the compound pre-analysis.
2.4.1.2 PAHs
Internal standards (Cambridge Isotope Laboratories, Tewksbury, MA, USA) were added to the sorbent
340 before the sample was collected. The surrogate recoveries were measured relative to the internal
standards and are a measure of the PUF/XAD/PUF/filter collection efficiency. Adeuterated recovery
standard, DIO-pyrene, was added before mass analysis. Samples were analyzed on a Thermo
Tracel310/ISQ GC/MS (Thermo Electron North America LLC, West Palm Beach, FL, USA) utilizing full-
scan mode. All surrogate standard recoveries were between 48 and 110 percent, which was within the
345 standard method criteria (25 and 130 %).
2.4.2 VOCs
Volatile organic compounds were sampled via U.S. EPA Method TO-15 [9], Sampling for VOCs was
accomplished using laboratory-supplied 6-L SUMMA canisters (ALS, Simi Valley, CA, USA). Each SUMMA
canister was equipped with a manual valve, metal filter (frit), pressure gauge, pressure transducer, and
350 an electronic solenoid valve. Pre-sampling tests showed canister fill times of 12 min.
The SUMMA valves were checked for leakage before sample collection by ensuring that the pressure
gauge was not showing decreased vacuum with time. The SUMMA had its electronic solenoid valve
controlled by the Flyer data acquisition (FlyerDAQ) program. The pressure transducer and electronic
solenoid valve were connected to the Flyer, and the manual valve was opened. The electronic solenoid
355 valve sampling system was opened and closed based on C02 concentration set points using the
FlyerDAQ program. When the LI-820 measures elevated levels of C02, the Flyer DAQ enables the solid
state relay, opening the SUMMA's solenoid valve to start sampling at the chosen frit filter sampling rate.
The pressure transducer provided information on the status of the SUMMA (i.e., empty, filling, or full) to
the FlyerDAQ interface. Following the end of sampling, the manual valve was closed, the SUMMA
360 dismounted from the Flyer, the solenoid valve removed, and the canister was returned to its shipping
container. SUMMA canisters were shipped to and from the field in boxes as per (ALS Environmental)
instructions.
The VOCs were analyzed by ALS Laboratories (Simi Valley, CA) using U.S. EPA Method TO-15 [9] using full
scan mode gas chromatography-low resolution mass spectrometry (GC/LRMS). The SUMMA canisters
365 were also analyzed for C02, CO, and CH4 by a GC/ flame ionization detector (FID) according to modified
U.S. EPA Method 25C [10] by ALS Laboratories (Simi Valley, CA).
2.4.3 PM
2.4.3.1 PM batch sampling
PM2.5 and PM10 were sampled with SKC impactors using 47 mm tared Teflon filters with a pore size of 2.0
370 pirn via a Leland Legacy sample pump (SKC Inc., Pittsburgh, PA, USA) with a constant airflow of 10 L/min.
PM was measured gravimetrically following the procedures described in 40 CFR Part 50 [13]. Particles
larger than 10 pim in the PM10 impactor (or larger than 2.5 pim in the PM2.5 impactor) were collected on
11

-------
an oiled 37 mm impaction disc. The Leland Legacy Sample pump was calibrated with a Gilibrator Air
Flow Calibration System (Sensidyne LP, St. Petersburg, PA, USA).
375 2.4.3.2 PM continuous sampling
The TSI DustTrak DRX Model 8533 (TSI, Inc., Knoxville, TN, USA) was used to measure time-resolved
particle size distributions. The DustTrak DRX measures light scattering by aerosols as they intercept a
laser diode and has the capability of simultaneous real time measurement (every second) of PMi, PM2.5,
Respirable (PM4), PM10 and Total PM (up to 15 pim). The aerosol concentration range for the DustTrak
380 DRX was 0.001-150 mg/m3 with a resolution of ฑ0.1% of the reading. The flow accuracy is ฑ5 % of
internal flow as controlled. The DustTrak DRX was factory-calibrated yearly to the respirable fraction
(PM4), with a photometric calibration factor (PCF) value of 1.00. A custom PCF was conducted as per
manufacturer's recommendations for PM2.5 and PM10 using the simultaneously sampled PM2.5 and PM10
by filter impactor concentrations (averaged continuous PM2.5 (or PM10) concentration divided by PM2.5
385 (or PM 10) by filter mass concentration). This factor was applied to scale the real time data. A zero
calibration was performed before each day using a zero filter which comes with the DustTrak DRX.
Similarly, a daily flow calibration was performed with a Gilibrator flowmeter following procedures in
Operation and Service Manual Model 8533/8534 (P/N 6001898, Revision F, January 2011). The DustTrak
inlet was cleaned after each day with a cotton swab.
390 2.4.4 CO2
C02 was continuously measured using an NDIR instrument (LI-COR 820 model, LI-COR Biosciences,
Lincoln, NE, USA). This unit was configured with a 14 cm optical bench, giving it an analytical range of 0-
20,000 ppm with an accuracy specification of less than 3 % of reading. The LICOR was calibrated in
accordance with U.S. EPA Method 3A [14] with three-point zero and calibration drift test. The LI-COR
395 820 C02 concentration was recorded every second on the onboard computer using the FlyerDAQ
program. The calibration error for all test days was between 0.001 % and 0.559 %, and the system drift
was between 0.015 % and 0.319 %, below the error and drift acceptance criteria of 5% and 3%,
respectively, as stated by the U.S. EPA Method 3A [14].
2.4.5 CO
400 A Horiba Model VIA510 CO monitor (Horiba Instruments, Inc, Chicago III) was used on the side of the
Flyer's C02 inlet during the paperboard tests (November 2014 test period). The analyzer operates by
directing identical infrared (IR) beams through an optical sample cell and a sealed optical reference cell.
A detector, located at the opposite end of the cells, continuously measures the difference in the amount
of infrared energy absorbed within each cell. This difference is a measure of the concentration of the
405 component of interest in the sample. The CO analyzer adheres to U.S. EPA Method 10 [15]. Calibration
and post drift tests were performed each test day. The calibration error for all test days was between
0.01 % and 1.10 %, and the system drift was between 0.66 % and 1.57 %, below the error and drift
acceptance criteria of 5% and 3%, respectively, as stated by the U.S. EPA Method 3A [14].
410
12

-------
An electrochemical gas sensor (e2V EC4-500-CO, SGX Sensortech, Buckinghamshire, United Kingdom)
was used for the MRE tests. This sensor measures CO concentration by means of an electrochemical cell
through CO oxidation and changing impedance. The E2v CO sensor has a CO detection range of 1-500
ppm with resolution of 1 ppm and sensitivity of 55-85 nA/ppm. The response time is less than 30
415 seconds. The CO sensor was calibrated and tested for post-drift on a daily basis in accordance with U.S.
EPA Method 3A. The system drift was between 0.168 % and 4.993 % (for one test day only, otherwise
below 3 %), which was both above and below the 3 % acceptance criterion as stated by the U.S. EPA
Method 3A [14], respectively. For the test day where the drift was 4.993 %, the calibration curve was
used for the first half of the tests and the post-drift curve was used for the second half of the tests.
420 2.5 Calculations
2.5.1	Emission factors
The emission factor for each species was calculated from the ratio of pollutant concentrations to
background-corrected carbon concentration as calculated from C02 and CO measurements (AC02, ACO
and ACH4 for VOCs). Emission factors were calculated using these concentrations and the fraction of C in
425 fiberboard/MRE material, following the carbon balance method [16]. This approach assumes that all
carbon in the combusted material is emitted as C02, CO, and CH4.
Pollutant (—งฆ)
Emission Factor (g Pollutant/g Material) = Fcx	.	Equation 2-1
I Carbon @)
where: Fc = carbon fraction in the fiberboard/MRE material, Carbon = amount of carbon sampled
430 derived from AC02, and ACO (and ACH4 for VOCs) concentration in the plume.
2.5.2	PCDD/PCDF Toxic Equivalent Calculations
PCDDs and PCDFs include 75 and 135 congeners, respectively. Of these 210 congeners, 17 are toxic and
have been assigned TEF values [12] (Table 2-8). The TEQ value is obtained by multiplying the
435 concentration of a PCDD/PCDF congener by its TEF-value and summarizing the result for all 17 toxic
congeners. The U.S. EPA has listed 16 priority PAHs. Some of these PAHs are probably carcinogenic to
humans according to U.S. EPA.
Table 2-9 lists these 16 PAHs and their TEFs for humans.
13

-------
440 Table 2-8. PCDD/PCDF Toxic Equivalency Factors for mammals/humans [12].
PCDDs
TEF
PCDFs
TEF
2,3,7,8 - TCDD
1
2,3,7,8-TCDF
0.1
1,2,3,7,8 - PeCDD
1
1,2,3,7,8 - PeCDF
0.03
1,2,3,4,7,8 - HxCDD
0.1
2,3,4,7,8 - PeCDF
0.3
1,2,3,6,7,8 - HxCDD
0.1
1,2,3,4,7,8 - HxCDF
0.1
1,2,3,7,8,9 - HxCDD
0.1
1,2,3,6,7,8 - HxCDF
0.1
1,2,3,4,6,7,8 - HpCDD
0.01
1,2,3,7,8,9 - HxCDF
0.1
1,2,3,4,6,7,8,9 -OCDD
0.0003
2,3,4,6,7,8 - HxCDF
0.1


1,2,3,4,6,7,8 - HpCDF
0.01


1,2,3,4,7,8,9 - HpCDF
0.01


1,2,3,4,6,7,8,9 -OCDF
0.0003
Table 2-9. PAH Toxic Equivalency Factors for humans [17].
Compound
TEF
Compound
TEF
Naphthalene
0
Benzo(a)anthracenea,b
0.005
Acenaphthylene
0
Chrysenea,d
0.03
Acenaphthene
0
Benzo(b)fluoranthenea
0.1
Fluorenec,d
0
Benzo(k)fluoranthenea,b
0.05
Phenanthrenec,d
0.0005
Benzo(a)pyrenea,b
1.0
Anthracenecd
0.0005
lndeno(l,2,3-cd)pyreneab
0.1
Fluoranthenec,d
0.05
Dibenz(a,h)anthracenea
1.1
Pyrenecd
0.001
Benzo(ghi)perylenecd
0.02
a Probably carcinogenic to humans according to US EPA.b Probably and possibly carcinogenic to humans according to
International Agency for Research on Cancer (IARC).c Not classifiable as carcinogenic to humans according to US EPA.
445 d Not classifiable as carcinogenic to humans according to IARC.
2.5.3 Modified Combustion Efficiency
The modified combustion efficiency (MCE) (Equation 2-2) is a measure of combustion behavior or how
450 well the fuel is being burned where MCE = 1.0 is complete combustion. The MCE can be categorized as
MCE > 0.95, indicating flaming conditions (good combustion) and MCE < 0.90, indicating smoldering
conditions (poor combustion).
A C02
MCE =	 Equation 2-2
AC02 + ACO H
455
14

-------
2.6 Data Precision
The data precision was checked by calculating:
•	Relative percent difference (RPD) for any pair of duplicates
460
Q-B
RPD = 100x—			Equation 2-3
Q + B
where: Q = results from one sample, B = results from replicate samples
465
•	Standard deviation (STDV) if more than duplicate measurements were conducted
STDV =
1 N
(=1
Equation 2-4
470
Wherewhere: n = average results from all samples, x, = results from one sample
N = number of samples
Or expressed as Relative Standard Deviation (RSD)
STDV
RSD = 100X	 Equation 2-5
Average
475 Single factor one-way analysis of variance (ANOVA) with alpha of 0.05 (level of significance) was used to
determine any differences between the four fiberboards types and between the four MRE waste
compositions types. To establish significant difference the ANOVA returned p value (significant value)
has to be less than the alpha value (0.05) and the F-distribution value (F/Fcrrt) has to be greater than 1.0.
15

-------
480 3 Results and Discussion
Results from each collected sample are presented in Appendix A and B.
3.1 PM
3.1.1 Fiberboard packaging
Typical traces of PM, CO, and C02 throughout each of the fiberboard burns are shown in Figure 3-1 A-D,
485 below. In general, concentrations of CO and C02 mimic the increase in particle concentration. Peak
particle concentrations range from 10-20 mg/m3, although one packaging type, NWS, exceeded 50
mg/m3. The similarity of the PMi to Total PM traces (Figure 3-1) indicates that the majority of the
particles are small, < 1 pim, and therefore respirable. Figure 3-2 examines PM emission factors with time
over the replicates and also plots MCE to see if there is any relationship between PM emissions and
490 combustion quality. While most of the runs have consistent, packaging-specific emission factors, the
variance in a few runs illustrates the effect of random waste orientation on emissions. Also, while there
are suggestions from limited tests that poor combustion quality (low MCE) increases PM emissions
(NSB/NSL R2 of 0.81 and SB/SL R2 of 0.55, figure not shown), the correlations seem inconsistent (CB/CL
R2 of 0.056 and NWS R2 of 0.056, figure not shown). Single factor ANOVA showed no statistical
495 difference between the PM emission factors for the different fiberboard types (F = 0.24, p = 0.56).
CB/CL
PM10
12000
NWS
10000
PM10
12:29 12:32 12:35 12:39 12:42 12:45 12:49
Time (hh:mm)
Figure 3-1. Typical traces of PM, CO, and CO2 throughout each of the fiberboard type burns.
NSB/NSL
pmio
Total PM
PM10
8000 -|
7000 -
6000 -
a 5000 -
2.
~ 4000 -
3000 -
2000 -
1000 -
0 -
9:28 9:30 9:32 9:34 9:36 9:38 9:40 9:42 9:44 9:46
Time (hh:mm)
8000
7000
_ 6000
I. 5000
Q.
J 4000
J 3000
2000
1000
10:42 10:44 10:47 10:50 10:52 10:55 10:58 11:00
Time (hh:mm)
16

-------
9.0
f 8.0
0	7.0
si
1	6'ฐ
m 5.0
3 4.0
Ll_
5 3'ฐ
2.0
1.0
0.0
5.0 n
4.0 -
3.0 -
2.0 -
1.0 -
] PM2.5
IPM10
MCE
NSB/NSL
0.0
] PM2.5
IPM10
MCE
4 5
Replicates
SB/SL
3 4 5
Replicates
r 1-000
-	0.990
-	0.980
-	0.970 ,
i
-	0.960 '
-	0.950
-	0.940
-	0.930
r 1.000
-	0.990
-	0.980
-	0.970 L
(.
-	0.960 "
-	0.950
-	0.940
-	0.930
6.0 i
~o
15 5.0
0
jQ
1	4-ฐ
tao
<	3.0 -
tap
LI-
5 2.0
Q_
1.0 -
0.0 -
4.0
tT 3.5 -
ro
J 3.0
0)
5 2.5
tlO
<	2.0 -
bp
1.5 -
i 1.0 -
0.5 -
0.0 -
] PM2.5
IPM10
MCE
NWS
ni1
] PM2.5
IPM10
MCE
ft n
4 5 6
Replicates
CB/CL
nl~l
4 5
Replicates
500 Figure 3-2. PM2.5 and PM10 emission factors and modified combustion efficiency (MCE] for each
replicate.
PM2.5
PM10
8.0
5.0
CO 05
3.0
2.0
NSB/NSL NWS
SB/SL CB/CL
505
Figure 3-3. I'M2.5 and PM10 emission factors from open burning of fiberboard. Error bars represent 1
STDV.
17

-------
510
Table 3-1. PM emission factors.

PM2.5
PM10


mg/kg Paperboard
mg/kg Paperboard
Paperboard
Average STDV
Average
STDV
NSB/NSL
3.4 1.95
3.4
1.66
NWS
3.4 0.72
3.6
0.72
SB/SL
2.8 0.86
2.7
0.89
CB/CL
2.9 0.63
2.9
0.70
3.1.2 MRE pouches
PM emission factors are shown in
Figure 3-4 for the MRE waste compositions and the baseline CB/CL. As with fiberboard packaging,
515 addition of any MRE composition to the baseline CB/CL fiberboard increases the emission factor by
approximately 3-4 times. The effect of composition changes on PM emission factors, however, is
indiscernible (single factor ANOVA F = 0.24, p = 0.53). The PMio is nearly the same as PM2.5, indicating
that the vast majority of the PM is 2.5 micrometers in size or less. The PM emission factors did not
correlate with the MCE (Figure 3-5), r2 = 0.0011-0.34 (scatter plot not shown).
520
PM2.5
PM10
18.0 -
16.0 -
14.0 -
10.0 -
100%
Baseline
CB/CL
NEW
Figure 3-4. PM emission factors from open burning of MREs. Error bars represent 1 STDV.
18

-------
100% NEW Material
525
16.0 -
PM2.5
PM10
-a 14.0 -
ฃ 12.0 -
10.0 -
6.0 -
4.0 -
14.0 i
"E 12.0 -
tX3
o
m lo.o -
.a
w> 8.0 -
- 6.0 -
LU
| 4.0	-
2.0 -
0.0	-
Figure 3-5.
replicate.
2 3 4 5
Replicates
]PM2jTj 32o/o NEW Material
IPM10
MCE
2 3 4
Replicates
r 1.000

16.0 -i

T3
14.0 -
- 0.980
03


-Q
12.0 -

OJ

- 0.960

10.0 -

bo

u

8.0 -

bp

- 0.940
Ll_
LU
6.0 -




Q_
4.0 -
- 0.920




2.0 -
- 0.900

0.0 -
] PM2.5
IPM10
66% NE
JV Material

r	0.970
-	0.960
-	0.950
-	0.940 ,
-	0.930
-	0.920
-	0.910
-	0.900
3 4
Replicates
r 0.960


20.0


T3

- 0.950

tX3



O
-Q
15.0 -




- 0.940

CD
-Q









- 0.930
MCE

10.0 -


Ll_

- 0.920





Q_
5.0 -
- 0.910



- 0.900


0.0 -
IpM2.5 | 0% NEW Materiair ฐ"95ฐ
IPM10
MCE
- 0.940
/
- 0.930
- 0.920 y.
- 0.910
- 0.900
0.890
3 4
Replicates
PM2.5 and PM10 emission factors and modified combustion efficiency (MCE) for each
3.2 Metals and Other Trace Elements
Emission factors for metals and other trace elements are shown in Figure 3-6 and Table 3-2 for the MRE
530 waste composition. No effect on the emission factors was found for the different MRE waste
compositions. Chlorine (CI), Sulfur (S), Potassium (K) were the most abundant elements observed. The Al
emission factors were very similar for the four MRE waste compositions, 2.3-2.8 mg/kg MRE.
535
HI	40 1
1	3.5 -
tUD	„ „
^	3.0 -
tUJ
ฃ	2.5 -
to
o	2.0 -
S	15 -
LL_	ฑ"J
|	1.0 -
'to
ฆ|	0.5 -
m	0.0 -
~	100% N EW ฆ 66% N EW
~	32% NEW ~ 0% NEW
M
H
...

fib
Al
Fe
Cr Pb Cu
Elements
Zn
Br
cu
5
M
100 1
80 -
60 -
40 -
20 -
0 -

Si
ci
~	100% N EW ฆ 66% N EW
~	32% NEW ~ 0% NEW
niffi
ififi
Elements
Figure 3-6. Major metal and trace /element emission factors from open burning of MRE's.
I
19

-------
Table 3-2. Major metal and trace /element emissions from open burning of MRE pouches.3




l\
EW




100 %

66%


32%
0%

Element
mg/kg
STDV
mg/kg
STDV
mg/kg
STDV
mg/kg
STDV
Al
2.3
0.43
2.8
0.75
2.3
0.30
2.7
0.78
Fe
0.30
0.030
0.51
0.45
0.31
0.11
0.29
0.046
Cr
0.059
0.027
0.15
0.19
0.027
0.0058b
0.040
0.025
Pb
0.056
0.044
0.086
0.033
0.045
0.016
0.071
0.012
Cu
0.21
0.075
0.23
0.079
0.17
0.057
0.17
0.062
Zn
0.97
0.18
0.91
0.31
0.74
0.15
0.78
0.24
Br
2.0
0.33
2.2
0.59
2.1
0.18
2.3
0.36
Si
5.7
0.56
9.0
3.8
5.6
1.1
5.4
0.6
CI
60
23
54
18
59
25
68
18
P
10
1.3
11
3.2
10
2.0
10
2.5
S
26
2.9
25
5.3
26
5.2
26
3.3
K
21
2.2
17
3.1
20
2.8
17
0.91
540
3 The metals and trace elements here were selected based on the number of samples where the material was detected more than
three times the uncertainty level of the analysis. Full list of all XRF elements analytes are shown in Appendix B, Table B19.b Relative
difference.
3.3 VOCs
3.3.1 Fiberboard packaging
Results for select VOC emission factors for the MRE fiberboard packaging burns are shown in Figure 3-7
and Table 3-3 . For the four packaging types, benzene is the most prevalent VOC at approximately 80 to
545 150 mg/kg of fiberboard material. For three of the four materials, acrolein is the next most prevalent.
Typical combustion-related aromatic pollutants (benzene, toluene, acrolein, and xylenes) are linearly
related to the MCE value (Figure 3-8). A more complete set of emission factors by packaging type is
shown in Appendix A, Tables A26-29.
300
0	250
-Q
q3
ฃ 200
O)
1	150
w 100
o
o
> 50

1L
~	Benzene* ~ Acrolein*
~	Styrene* BToluene*
~	Ethylbenzene* Bm.p-Xylenes*
De
i
IL
llni-
CB/CL
SB/SL
NSB/NSL
NWS
550 Figure 3-7. Select VOCs and their emission factors for the different fiberboard types. * = on EPA's
list of hazardous air pollutants.
20

-------
o CO
" s
jo -e
r- 0
,lฃ
J?
E "5)
lu E
300 i
250 -
200 -
150 -
100 -
50 -
Benzene
R2 = 0.8586
0
0.960
•	CB/CL
•	SB/SL
•	NSB/NSL
o NWS
o
0.970 0.980
MCE
0.990
o CO
" s
jo -e
r- 0
,lฃ
.ซ i?
E "5)
lu e
120 i
100 -
80 -
60 -
40 -
20 -
Toluene
R2 = 0.8356
•	CB/CL
•	SB/SL
•	NSB/NSL
o NWS
0
0.960
o
o
•i
0.970 0.980
MCE
0.990
T3
o lo
" S
CO -g
c 0
.ซj?
E "5)
lu e
160
140
120
100
80
60
40
20
0
0.
Acrolein
*
R2 = 0.6626
•	CB/CL
•	SB/SL
•	NSB/NSL
o NWS

960 0.970 0.980 0.990
MCE
25 n
20 -
^ "O
o ro
u ฃ
03 -0
^ _Q
.2 4=
f/5 05
^ 10
15 -
E "5)
lu e
5 -
0
0.960
Xylene
R2 = 0.8623
•	CB/CL
•	SB/SL
•	NSB/NSL
o NWS
n ฆฆฆ ฐ
0.970 0.980
MCE
0.990
Figure 3-8. Select VOCs versus modified combustion efficiency (MCE).
Table 3-3. VOC emission factors.
Compound
CB/CL
Average STDV
mg/kg mg/kg
SB/SL
Average
mg/kg
STDV
mg/kg
NSB/NSL
Average STDV
mg/kg mg/kg
NWS
Average
mg/kg
STDV
mg/kg
Benzene3
79
75
153
102
91
49
111
16
Propene
38
42
118
94
84
57
51
9.4
Vinyl Acetate3
33
13
98
70
50
NA
48
CD
Acrolein3
9.4
4.8
81
64
76
60
36
5.9
Toluene3
19
19
57
44
28
16
26
4.6
1,3-Butadiene3
19
22
44
43
34
23
24
5.3
Styrene3
5.6
2.5
60
64
13
7.5
13
1.6
2-Butanone (MEK)
9.3
11
23
19
24
16
10
3.0
Ethyl benzene3
2.4
2.2
15
13
4.6
2.9
4.1
0.60
Methylene Chloride
5.5
5.3
2.2
2.1b
3.1
3.4
6.7
5.3
/rj-,p-Xylenes3
1.9
1.7
6.9
6.1
5.5
3.5
3.7
0.82
o-Xylene3
0.74
0.58
2.9
2.6
2.2
1.4
1.5
0.32
Acetonitrile
1.2
1.1
3.0
2.0
1.6
0.84
0.62
0.10
Cumene3
0.33
NA
1.5
1.4
0.29
0.12
0.20
0.027
555 3 Included in the EPA list of hazardous air pollutants.b Relative difference. NA = not applicable. The VOCs shown here were selected based on
the number of samples where the compound was detectable above three times the detection limit with relevance to the EPA's list of hazardous
air pollutants. Full list of the 88 VOCs analyzed and their emission factors are presented in Appendix A, Tables A26-29.
21

-------
560
565
3.3.2 MRE pouches
Select VOC data for the MRE packaging are shown in Figure 3-9, and values for the full data set are in
Table 3-4. As with the fiberboard packaging, benzene is the most common compound followed by
acrolein. All VOC concentrations are higher with the presence of MREs than the CB Baseline. No
concentration trend with changing amounts of NEW material is noted. As for the fiberboard, the
selected VOCs showed a linear relationship with MCE (increased emission factors with decreased MCE),
Figure 3-10. Although the R2 of 0.39-0.78 was lower for open burning of MRE than for only combusting
fiberboard (R2 of 0.66-0.86), these differences can be due to the overall better MCE occurring during the
fiberboard burns, Figure 3-11.
0
H—'
CO
E
O)
E
LL
LU
O
o
>
350 -i
300 -
250 -
200
150
100
50
M
100%
i
66% | 32%
NEW Material
~	Benzene*
~	Acrolein*
ฆ Toluene*
~	1,3-Butadiene*
i
o%

CB
Baseline
570
Figure 3-9. VOC emission factors from open burning of MREs.
* = on EPA's list of Hazardous Air Pollutants (HAPs).
Table 3-4. VOC emission factors from open burning of MREs.

0 % NEW
32 % NEW
66 % NEW
100 % NEW

Average
STDV
Average
STDV
Average
RPD
Average
STDV
Compound
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
Benzene3
268
83
329
16
253
1.3%
286
75
Propene
211
89
266
10
182
6.7%
225
36
Vinyl Acetate3
101
41
111
24
93
17%
109
27
Acrolein3
125
40
145
16
126
10%
126
27
Toluene3
63
36
79
37
52
22%
58
18
1,3-Butadiene3
103
38
126
12
82
2.8%
94
55
Styrene3
206
192
283
198
210
10%
120
79
2-Butanone (MEK)
23
6.9
26
3.8
25
19%
24
7.8
Ethyl benzene3
16
12
24
14
18
1.8%
15
6.0
Methylene Chloride
5.4
0.66
6.0
0.93
4.8
15%
5.7
1.4
/rj-,p-Xylenes3
2.7
0.36
3.2
0.56
2.6
15%
3.1
0.72
o-Xylene3
7.6
2.5
12
1.3
8.8
22%
13
1.9
Acetonitrile
0.95
0.69
1.5
0.89
1.2
5.1%
0.82
0.33
Cumene3
268
83
329
16
253
1.3%
286
75
3 Included in the EPA list ofHAPs. The VOCs shown here were selected based on the number of compounds detectable above three times the
detection limit and their relevance to the EPA's list of HAPs. Full list of the 88 VOCs analyzed and their emission factors are presented in
Appendix B, Tables B20-24.
22

-------
-2 LU
ฐ rv
CO
375
300
225
0	D>
 o> 60 -
E
m 40 -
20 -
0
Toluene
R2 = 0.3142
•	100% NEW
•	66% NEW
•	32% NEW
o0% NEW
0.97	0.975	0.98
MCE
0.985
-2 LU
ฐ rv
ro U-
200 1
160 -
120 -
o
u)
ฆ| E 80 H
LU """
40 -
Acrolein
o
R2 = 0.5936

•	100% NEW
•	66% NEW
•	32% NEW
O0% NEW

0.97	0.975	0.98
MCE
0.985
-2 LU
ฐ fV
CO th
o
u)

0.96	0.97	0.98
MCE
0.99
200 n
g 160 \
ro € 120 H
lu
OH
E 5
m # 40 H
D)
E
0
Acrolein
•	MRE pouches
•	Fiberboard
* .
R2 = 0.5936
• •
R2 = 0.6626
0.96	0.97	0.98
MCE
0.99
Figure 3-11. Benzene and acrolein vs. MCE for all MRE waste compositions and fiberboard types
burns.
580 3.4 PAHs
3.4.1 Paperboard packaging
23

-------
585
Fiberboard burns resulted in PAH emission factors as shown for sums (Figure 3-12), individual PAHs
(Table 3-5), and TEF-weighted PAHs (Table 3-6). No difference was seen between the fiberboard types
(Figure 3-12) (single factor ANOVA, F = 0.51, p = 0.20); PAH emissions are the same no matter what
fiberboard type.
CD ^3
x" E
Q- .Q
—i
—1
CO
O)
E
140 -i
120 -
100 -
80 -
60
40
20
0
•Average
CB/CL Replicates
NSB/NSL Replicates
•	NWS Replicates
•	SB/SL Replicates
PAHs
I
I :
} :
CB/CL
NSB/NSL NWS
SB/SL
Figure 3-12. PAH emission factors from open burning of fiberboard packaging. Error bars represent
1 standard deviation.
590 Table 3-5. PAH emission factors from open burning of fiberboard in mg/kg fiberboard.

NWS

CB/CL

NSB/NSL
SB/SL

Average
STDV
Average
STDV
Average
STDV
Average
STDV
Compound
mg/kg Fiberboard
mg/kg Fiberboard
mg/kg Fiberboard
mg/kg Fiberboard
Naphthalene
28
21
14
15
21
9.9
15
6.7
Acenaphthylene
13
9.3
5.5
5.2
6.9
2.7
4.8
2.2
Acenaphthene
0.68
0.45
0.24
0.18
0.43
0.19
0.35
0.20
Fluorene
3.0
1.6
1.1
0.86
1.4
0.56
1.8
0.79
Phenanthrene
10
4.7
4.3
3.0
4.4
1.3
6.8
3.0
Anthracene
2.4
1.3
0.89
0.64
0.99
0.33
1.7
0.87
Fluoranthene
4.9
2.7
2.0
0.93
1.8
0.29
2.7
1.2
Pyrene
4.5
2.5
1.8
0.80
1.7
0.24
2.4
1.1
Benzo(a)anthracene
1.2
0.65
0.44
0.27
0.44
0.13
0.75
0.35
Chrysene
1.1
0.57
0.43
0.28
0.41
0.11
0.72
0.34
Benzo(b)fluoranthene
0.62
0.32
0.24
0.14
0.23
0.068
0.33
0.16
Benzo(k)fluoranthene
0.91
0.45
0.31
0.18
0.27
0.055
0.40
0.17
Benzo(a)pyrene
1.0
0.55
0.34
0.22
0.31
0.067
0.46
0.22
lndeno(1,2,3-cd)pyrene
0.66
0.33
0.22
0.13
0.20
0.035
0.28
0.13
Dibenz(a,h)anthracene
0.11
0.067
0.041
0.030
0.037
0.011
0.067
0.038
Benzo(ghi)perylene
0.73
0.37
0.26
0.18
0.21
0.035
0.27
0.11
SUM 16-EPA PAH
74
40
32
28
41
16
38
16
24

-------
Table 3-6. PAH TEQ emission factors from open burning of fiberboard in mg B[a]P TEQ/kg
fiberboard.a
Compound
NWS
Average
STDV
CB/CL
Average STDV
mg B[a]P TEQ/kc
NSB/NSL
Average STDV
Fiberboard
SB/SL
Average STDV
Naphthalene
NA
NA
NA
NA
NA
NA
NA
NA
Acenaphthylene
NA
NA
NA
NA
NA
NA
NA
NA
Acenaphthene
NA
NA
NA
NA
NA
NA
NA
NA
Fluorene
NA
NA
NA
NA
NA
NA
NA
NA
Phenanthrene
5.1E-03
2.4E-03
2.1E-03
1.5E-03
2.2E-03
6.4E-04
3.4E-03
1.5E-03
Anthracene
1.2E-03
6.3E-04
4.4E-04
3.2E-04
5.0E-04
1.6E-04
8.4E-04
4.3E-04
Fluoranthene
2.5E-01
1.3E-01
9.8E-02
4.6E-02
8.8E-02
1.4E-02
1.3E-01
5.9E-02
Pyrene
4.5E-03
2.5E-03
1.8E-03
8.0E-04
1.7E-03
2.4E-04
2.4E-03
1.1E-03
Benzo(a)anthracene
5.9E-03
3.3E-03
2.2E-03
1.4E-03
2.2E-03
6.3E-04
3.7E-03
1.7E-03
Chrysene
3.2E-02
1.7E-02
1.3E-02
8.4E-03
1.2E-02
3.3E-03
2.2E-02
1.0E-02
Benzo(b)fluoranthene
6.2E-02
3.2E-02
2.4E-02
1.4E-02
2.3E-02
6.8E-03
3.3E-02
1.6E-02
Benzo(k)fluoranthene
4.5E-02
2.3E-02
1.5E-02
9.2E-03
1.3E-02
2.7E-03
2.0E-02
8.3E-03
Benzo(a)pyrene
1.0E+00
5.5E-01
3.4E-01
2.2E-01
3.1E-01
6.7E-02
4.6E-01
2.2E-01
lndeno(1,2,3-cd)pyrene
6.6E-02
3.3E-02
2.2E-02
1.3E-02
2.0E-02
3.5E-03
2.8E-02
1.3E-02
Dibenz(a,h)anthracene
6.2E-02
7.3E-02
2.5E-02
1.8E-02
3.4E-02
2.4E-02
6.4E-02
5.5E-02
Benzo(ghi)perylene
1.5E-02
7.3E-03
5.3E-03
3.5E-03
4.2E-03
7.0E-04
5.4E-03
2.3E-03
SUM 16-EPA PAH
1.6E+00
8.2E-01
5.4E-01
3.1E-01
5.1 E-01
1.2E-01
7.7E-01
3.8E-01
a NA - not applicable (no TEF value).
595 3.4.2 MRE pouches
MRE burns resulted in PAH emission factors as shown for sums (Figure 3-13), individual PAHs
(Table 3-7), and TEF-weighted PAHs (
Table 3-8). Single factor ANOVA (F = 0.24, p = 0.44) showed no difference in PAH emissions among the
different MRE waste categories (Figure 3-13). However, a weak difference was seen between the
600 different MRE waste categories and CB/CL fiberboard type (F = 1.04, p = 0.045). Higher PAH emissions
resulted from burning MREs and CB/CL together. No difference was seen between the MRE types
(Figure 3-13); PAH emissions are the same no matter what MRE waste category.

-------
250
200
150
g E 100
50
0
PAHs
~Average
>100% NEW Replicates
66% NEW Replicates
32% NEW Replicates
>0% NEW Replicates
i : t
	1	1	1	1
100% NEW 66% NEW 32% NEW 0% NEW
Figure 3-13. PAH emission factors from open burning of MREs. Error bars represent 1 standard
deviation.
Table 3-7. PAH emission factors from open burning of MRE pouches in mg/kg MRE.

0% New
32% New
66% New
100% New

Average
STDV
Average
STDV
Average
STDV
Average
STDV
Compound
mg/kg MRE
mg/kg MRE
mg/kg MRE
mg/kg MRE
Naphthalene
46
15
40
8.7
31
3.3
65
39
Acenaphthylene
15
5.7
12
2.1
11
1.3
19
9.8
Acenaphthene
0.69
0.25
0.58
0.14
0.57
0.011
0.87
0.57
Fluorene
4.5
1.9
3.2
0.47
3.5
0.68
4.8
2.6
Phenanthrene
16
7.0
11
1.95
14
3.3
16
7.3
Anthracene
2.5
1.0
2.0
0.38
2.3
0.36
2.9
1.5
Fluoranthene
3.2
1.4
2.4
0.37
2.9
0.029
3.7
1.4
Pyrene
2.2
1.0
1.9
0.39
2.1
0.18
2.9
1.3
Benzo(a)anthracene
1.3
0.65
0.82
0.20
1.09
0.023
1.4
0.69
Chrysene
1.5
0.79
0.99
0.22
1.37
0.021
1.5
0.75
Benzo(b)fluoranthene
0.91
0.45
0.57
0.14
0.77
0.016
0.85
0.45
Benzo(k)fluoranthene
0.83
0.47
0.60
0.11
0.72
0.104
0.89
0.36
Benzo(a)pyrene
0.79
0.43
0.56
0.14
0.65
0.079
0.86
0.44
lndeno(1,2,3-cd)pyrene
0.57
0.30
0.36
0.088
0.43
0.072
0.59
0.27
Dibenz(a,h)anthracene
0.21
0.110
0.115
0.031
0.138
0.0048
0.19
0.10
Benzo(ghi)perylene
0.50
0.25
0.37
0.10
0.37
0.111
0.58
0.27
SUM 16-EPA PAH
96
37
77
15
73
1.8
122
67

-------
610 Table 3-8. PAH TEQ emission factors from open burning of MRE pouches in mg B[a]P TEQ/kg MRE.a

0% NEW
32% NEW
66% NEW
100% NEW

Average
STDV
Average
STDV
Average
STDV
Average
STDV
Compound



mg B[a]P TEQ/kg MRE



Naphthalene
NA
NA
NA
NA
NA
NA
NA
NA
Acenaphthylene
NA
NA
NA
NA
NA
NA
NA
NA
Acenaphthene
NA
NA
NA
NA
NA
NA
NA
NA
Fluorene
NA
NA
NA
NA
NA
NA
NA
NA
Phenanthrene
7.9E-03
3.5E-03
5.6E-03
9.8E-04
6.9E-03
1.6E-03
8.2E-03
3.7E-03
Anthracene
1.3E-03
5.1E-04
9.9E-04
1.9E-04
1.2E-03
1.8E-04
1.5E-03
7.6E-04
Fluoranthene
1.6E-01
7.2E-02
1.2E-01
1.8E-02
1.5E-01
1.4E-03
1.8E-01
7.1E-02
Pyrene
2.2E-03
9.7E-04
1.9E-03
3.9E-04
2.1E-03
1.8E-04
2.9E-03
1.3E-03
Benzo(a)anthracene
6.3E-03
3.2E-03
4.1E-03
1.0E-03
5.5E-03
1.2E-04
6.8E-03
3.4E-03
Chrysene
4.5E-02
2.4E-02
3.0E-02
6.5E-03
4.1E-02
6.2E-04
4.6E-02
2.3E-02
Benzo(b)fluoranthene
9.1E-02
4.5E-02
5.7E-02
1.4E-02
7.7E-02
1.6E-03
8.5E-02
4.5E-02
Benzo(k)fluoranthene
4.1E-02
2.4E-02
3.0E-02
5.3E-03
3.6E-02
5.2E-03
4.4E-02
1.8E-02
Benzo(a)pyrene
7.9E-01
4.3E-01
5.6E-01
1.4E-01
6.5E-01
7.9E-02
8.6E-01
4.4E-01
lndeno(1,2,3-cd)pyrene
5.7E-02
3.0E-02
3.6E-02
8.8E-03
4.3E-02
7.2E-03
5.9E-02
2.7E-02
Dibenz(a,h)anthracene
2.3E-01
1.2E-01
1.3E-01
3.4E-02
1.5E-01
5.2E-03
2.1E-01
1.1E-01
Benzo(ghi)perylene
1.0E-02
4.9E-03
7.5E-03
2.1E-03
7.5E-03
2.2E-03
1.2E-02
5.5E-03
SUM 16-EPA PAH
1.4E+00
7.6E-01
9.8E-01
2.2E-01
1.2E+00
9.3E-02
1.5E+00
7.5E-01
a NA - not applicable (no TEF value).
3.5 PCDD/PCDF
3.5.1 Fiberboard packaging
615 Emission values for the MRE shipping containers (Figure 3-14) show PCDD/PCDF emission factors that
are low compared to the cellulosic biomass [18]. One emission factor value, however, that of SB/SL,
stands out from the other fiberboard types as being distinctively high. Paired single factor ANOVA
analyses showed a significant difference between SB/SL and the other fiberboard types (F = 1.43, 1.02,
2.61 and p = 0.026, 0.048, 0.0065). The same high value for SB/SL results when examining the
620 PCDD/PCDF total value (Table 3-10), consisting of the sum of all of the homolog concentrations. The
results are internally consistent in that the 1,2,3,7,8 - PeCDD congener and the 2,3,4,7,8 - PeCDF
congener consistently contribute the most to their respective TEQ values (Table 3-9). A number of
compositional factors (Table 2-1) may have resulted in this comparatively higher PCDD/PCDF value,
including lower calorific value, higher loss on drying, higher chloride, and lower sulfur. In general, better
625 combustion (processes with higher fuel calorific value and lower moisture content) results in lower
PCDD/PCDF formation due to the diminished availability of organic precursors. Higher chloride values
and lower sulfur values have generally been associated with increased formation of PCDD/PCDF, the
former acting as a chlorination promotor, and the latter acting to suppress PCDD/PCDF formation.
27

-------
CD
o
Ll_ -Q
8
CL 5
^ H—
o w)
Q <
u re
Q_ Jr!
CUD
0.45
0.40
0.35
0.30
0.25
0.20
0.15
0.10
0.05
0.00
O Average
CB/CL Replicates
•	NSB/NSL Replicates
•	NWS Replicates
•	SB/SL Replicates
I
o
CB/CL NSB/NSL NWS SB/SL
630 Figure 3-14. PCDD/PCDF emission factors from open burning of fiberboard packaging. Error bars
represent 1 standard deviation.
Table 3-9. PCDD/PCDF TEQ emission factors.

CB/CL
NSB/NSL
NWS
SB/SL
Isomer.
Average
STDV
Average
STDV
Average
STDV
Average
STDV




ng TEQ/kc
fiberboard



2,3,7,8 - TCDD
3.20E-03
1.51E-03
1.25E-02
2.17E-03
6.05E-03
2.11 E-03
2.76E-02
1.78E-02
1,2,3,7,8- PeCDD
1.26E-02
3.95E-03
5.17E-02
2.36E-02
1.63E-02
7.55E-03
1.18E-01
8.06E-02
1,2,3,4,7,8- HxCDD
8.22E-04
3.42E-04
2.78E-03
9.28E-04
1.06E-03
4.28E-04
6.70E-03
4.21 E-03
1,2,3,6,7,8- HxCDD
1.68E-03
4.09E-04
9.23E-03
3.54E-03
1.72E-03
7.64E-04
2.07E-02
1.25E-02
1,2,3,7,8,9- HxCDD
1.40E-03
4.57E-04
6.74E-03
2.60E-03
1.52E-03
4.28E-04
1.54E-02
9.77E-03
1,2,3,4,6,7,8- HpCDD
1.75E-03
4.93E-04
1.20E-02
3.91 E-03
1.65E-03
4.17E-04
2.52E-02
1.19E-02
1,2,3,4,6,7,8,9 - OCDD
1.44E-04
3.82E-05
1.01 E-03
2.52E-04
1.26E-04
4.01 E-05
2.05E-03
7.88E-04
2,3,7,8 - TCDF
9.26E-03
6.22E-03
7.09E-03
1.13E-03
8.71 E-03
4.93E-03
2.38E-02
4.96E-03
1,2,3,7,8- PeCDF
9.13E-04
3.74E-04
5.70E-04
3.88E-04
1.38E-03
1.16E-03
2.03E-03
2.47E-04
2,3,4,7,8- PeCDF
9.76E-03
3.25E-03
7.40E-03
5.07E-03
1.97E-02
1.30E-02
2.56E-02
2.47E-03
1,2,3,4,7,8- HxCDF
2.72E-03
1.30E-03
2.63E-03
5.45E-04
5.66E-03
3.38E-03
4.52E-03
8.73E-04
1,2,3,6,7,8- HxCDF
2.42E-03
1.26E-03
2.05E-03
6.52E-04
5.02E-03
3.58E-03
3.51 E-03
2.94E-04
1,2,3,7,8,9- HxCDF
1.30E-03
8.81 E-04
7.22E-04
7.79E-05
2.26E-03
1.21 E-03
1.39E-03
1.68E-04
2,3,4,6,7,8 - HxCDF
3.52E-03
2.73E-03
2.18E-03
4.74E-04
5.79E-03
2.59E-03
4.58E-03
6.47E-04
1,2,3,4,6,7,8- HpCDF
8.86E-04
8.01 E-04
6.68E-04
1.17E-04
1.23E-03
5.72E-04
1.23E-03
2.30E-04
1,2,3,4,7,8,9- HpCDF
1.60E-04
1.43E-04
1.31 E-04
3.58E-05
2.33E-04
1.66E-04
2.23E-04
7.03E-05
1,2,3,4,6,7,8,9-OCDF
1.67E-05
1.46E-05
2.48E-05
5.44E-06
2.27E-05
1.23E-05
4.86E-05
9.76E-06
PCDD TEQ Total
2.09E-02
6.50E-03
7.92E-02
4.94E-02
2.54E-02
1.11 E-02
2.16E-01
1.37E-01
PCDF TEQ Total
3.09E-02
1.36E-02
2.27E-02
5.70E-03
5.00E-02
2.95E-02
6.70E-02
6.04E-03
PCDD/PCDF TEQ Total
5.19E-02
1.97E-02
1.02E-01
5.50 E-02
7.54E-02
4.05E-02
2.83E-01
1.36E-01
28

-------
Table 3-10. PCDD/PCDF Total emission factors.

CB/CL

NSB/NSL
NWS

SB/SL

Homologue
Average
STDV
Average
STDV
Average
STDV
Average
STDV




ng/kg fiberboard



TeCDD
0.35
0.089
0.39
0.13
0.39
0.12
0.84
0.40
PeCDD
0.18
0.040
0.31
0.17
0.20
0.033
0.80
0.47
HxCDD
0.19
0.060
0.67
0.30
0.19
0.016
1.7
1.0
HpCDD
0.31
0.10
1.9
0.65
0.29
0.071
4.0
1.9
OCDD
0.48
0.13
3.4
0.84
0.42
0.13
6.8
2.6
TeCDF
1.29
0.73
0.93
0.15
1.55
1.09
2.6
0.36
PeCDF
0.37
0.083
0.30
0.14
0.67
0.52
0.84
0.11
HxCDF
0.24
0.14
0.19
0.05
0.47
0.28
0.36
0.024
HpCDF
0.17
0.15
0.17
0.03
0.24
0.12
0.34
0.074
OCDF
0.069
0.043
0.086
0.023
0.076
0.041
0.16
0.033
PCDD Total
1.5
0.37
6.7
2.0
1.5
0.34
14
6.3
PCDF Total
2.1
0.84
1.7
0.30
3.0
2.0
4.3
0.48
PCDD/PCDF Total
3.6
1.2
8.3
2.2
4.5
2.2
19
6.6
635
640
0
u
CL
o"
Q
U
Q.
TO
o
-Q
L_
(U
-Q

ClD
CB/CL ซ NSB/NSL • NWS • SB/SL
Figure 3-15 compares the PCDD/PCDF TEQ values versus MCE, indicating a moderate, negatively
correlating relationship. Formation of PCDD/PCDF has historically been tied to marginal combustion,
likely due to the presence of surviving organic structures providing the template for chlorination and
ring formation.
0.45
0.40
0.35
0.30
0.25
0.20
0.15
0.10
0.05
0.00





R = 0.5678








•

•




•

•
•
	



Figure 3
(MCE).
0.965 0.970 0.975 0.980 0.985 0.990
MCE
ฆ15. Fiberboard PCDD/PCDF emission factors versus modified combustion efficiency
29

-------
645 3.5.2 MRE pouches
PCDD/PCDF values are presented for the four compositions of MRE rations tested in Figure 3-16. There
is considerable overlap in the ฑ 1 Std Dev range, although "0 % NEW" is the highest value. No statistical
difference among the MRE waste compositions was found (single factor ANOVA F = 0.77, p = 0.087). The
emission factors up to 2 ng TEQ/kg MRE are several times higher than the emission factors from the
650 packing material alone (Figure 3-16), likely reflecting the more difficult combustion scenario (higher
moisture, heterogeneity of packaging morphology) and the likely higher CI content (food salts). The
congener- and homolog-specific data are presented in Table 3-11 and Table 3-12, respectively. Figure
3-17 compares the PCDD/PCDF TEQ values versus MCE, indicating a weak negatively correlated
relationship. Noticeable is that the MCE for the MRE tests are less than 0.960 while for fiberboard tests
655 the MCE values are greater than 0.965.
0
U
CL
0
0
U
CL
cc
CUD
CUD
c
3.50	-i
3.00	-
2.50	-
2.00	-
1.50	-
1.00	-
0.50	-
0.00	-
O Average
•	100% NEW Replicates
66% NEW Replicates
•	32% NEW Replicates
•	0% NEW Replicates
o
o
t

100% NEW 66% NEW 32% NEW 0% NEW
Figure 3-16. PCDD/PCDF emission factors from open burning of MREs. Error bars represent 1 standard
deviation.
660
665
670
30

-------
Table 3-11. PCDD/PCDF TEQ emission factors.

0% New
32% New
66% New
100% New
Isomer.
Average
STDV
Average
STDV
Average
STDV
Average
STDV




ng TEQ/kg MRE



2,3,7,8 - TCDD
2.9E-01
2.4E-01
6.4E-02
3.5E-02
3.3E-02
2.1E-02
6.5E-02
4.2E-02
1,2,3,7,8- PeCDD
1.3E-01
2.2E-02
8.8E-02
2.3E-02
3.6E-02
1.6E-02
8.6E-02
3.4E-02
1,2,3,4,7,8- HxCDD
5.4E-03
2.1E-03
3.3E-03
1.1E-03
2.2E-03
4.1E-04
3.3E-03
1.3E-03
1,2,3,6,7,8- HxCDD
7.2E-03
6.3E-03
7.8E-03
1.2E-03
6.4E-03
1.1E-03
8.0E-03
1.2E-03
1,2,3,7,8,9- HxCDD
6.0E-03
5.3E-03
7.2E-03
2.0E-03
5.9E-03
8.6E-04
6.3E-03
5.4E-04
1,2,3,4,6,7,8- HpCDD
1.2E-02
5.1E-04
8.8E-03
4.8E-04
9.0E-03
4.3E-04
9.8E-03
7.2E-04
1,2,3,4,6,7,8,9 - OCDD
9.9E-04
9.1E-05
7.5E-04
3.6E-05
8.1E-04
3.0E-05
8.7E-04
1.0E-04
2,3,7,8 - TCDF
7.1E-01
4.3E-01
3.4E-01
1.4E-01
9.7E-02
5.8E-02
3.3E-01
2.4E-01
1,2,3,7,8- PeCDF
4.5E-02
2.4E-02
2.6E-02
7.8E-03
7.4E-03
4.7E-03
2.6E-02
1.7E-02
2,3,4,7,8- PeCDF
4.8E-01
2.9E-01
2.6E-01
7.4E-02
7.5E-02
4.7E-02
2.5E-01
1.7E-01
1,2,3,4,7,8- HxCDF
3.6E-02
9.2E-03
2.7E-02
8.4E-03
9.1E-03
3.0E-03
2.8E-02
1.2E-02
1,2,3,6,7,8- HxCDF
3.2E-02
1.1E-02
2.7E-02
5.4E-03
8.6E-03
3.0E-03
2.4E-02
1.0E-02
1,2,3,7,8,9- HxCDF
1.1E-02
1.0E-02
1.3E-02
5.5E-03
4.2E-03
1.9E-03
1.1E-02
4.2E-03
2,3,4,6,7,8 - HxCDF
2.7E-02
8.9E-03
2.4E-02
6.3E-03
8.6E-03
3.8E-03
2.1E-02
8.8E-03
1,2,3,4,6,7,8- HpCDF
3.2E-03
1.3E-04
2.6E-03
6.2E-04
1.5E-03
2.5E-04
2.8E-03
8.6E-04
1,2,3,4,7,8,9- HpCDF
3.9E-04
3.8E-04
7.4E-04
2.7E-04
2.5E-04
7.3E-05
6.4E-04
2.2E-04
1,2,3,4,6,7,8,9-OCDF
7.1E-05
7.2E-06
6.3E-05
1.4E-05
4.8E-05
9.1E-06
6.0E-05
2.3E-05
PCDD TEQ Total
4.6E-01
2.6E-01
1.8E-01
5.0E-02
9.1E-02
2.9E-02
1.8E-01
7.5E-02
PCDF TEQ Total
1.3E+00
7.9E-01
7.2E-01
2.4E-01
2.1E-01
1.2E-01
7.0E-01
4.6E-01
PCDD/PCDF TEQ Total
1.8E+00
1.0E+00
9.0E-01
2.9E-01
3.0E-01
1.4E-01
8.8E-01
5.3E-01
Table 3-12. PCDD/PCDF Total emission factors.

0 % New

32 % New
66 % New
100 % New
Homologue
Average
STDV
Average
STDV
Average
STDV
Average
STDV




ng/kg
MRE



TeCDD
2.1
0.75
0.95
0.30
0.70
0.14
1.8
0.78
PeCDD
0.96
0.13
0.64
0.18
0.37
0.12
0.92
0.48
HxCDD
1.1
0.16
0.83
0.11
0.64
0.10
0.95
0.23
HpCDD
2.1
0.095
1.5
0.080
1.5
0.095
1.7
0.12
OCDD
3.31
0.30
2.48
0.12
2.71
0.10
2.90
0.34
TeCDF
92
48
57
15
26
8.0
59
25
PeCDF
14
6.5
9.0
2.2
2.4
1.2
8.6
5.3
HxCDF
2.4
0.85
2.0
0.43
0.66
0.25
1.9
0.75
HpCDF
0.49
0.16
0.50
0.14
0.25
0.017
0.44
0.069
OCDF
0.25
0.042
0.22
0.032
0.16
0.030
0.22
0.083
PCDD Total
9.6
0.96
6.4
0.51
5.9
0.52
8.2
1.6
PCDF Total
109
56
69
17
29
9.3
70
31
PCDD/PCDF Total
118
56
75
18
35
9.3
78
32
31

-------
Q	^
a!
Q
LJ	|jj
u	h-
CL	no
c
3.50
3.00
2.50
2.00
1.50
1.00
0.50
0.00

•
•	100% NEW ซ 66% NEW
•	32% NEW • 0% NEW






R = 0.1921




	

•



	
		
•



•
•
	
	 _



•
•
•

0.910 0.920 0.930 0.940 0.950 0.960
MCE
675 Figure 3-17. MRE PCDD/PCDF emission factors versus modified combustion efficiency (MCE).
4 Quality of Data and Data Limitations
For PCDD/PCDF analyses all surrogate standard recoveries were between 63% and 110% for the
fiberboard burn samples, which was within the standard method criteria (25-130%). Some of
680 the surrogate standard recoveries were outside the standard method criteria (25-130%) for the
MRE burn samples due to interference from significant amounts of other compounds in the 13C
channels causing a low response for the compound pre-analysis. For the PAHs all surrogate
standard recoveries for method blanks and samples were between 48 and 110 percent, which
was within the standard method criteria (25% and 130%). Two method blanks for the VOCs
685 returned all non-detects. All surrogate standard recoveries for method blanks and samples
were between 95% and 107%, within the acceptance limits of the method (70-130%). Precision
data on the XRF analyses for six elements had less than 3.5% error. The accuracy data on nine
standard reference materials ranged from 90.7% to 106.8%. The precision for the gravimetric
data is ฑ 10 |ag. The CO2 calibration error for all test days was between 0.001% and 0.559%, and
690 the system drift was between 0.015 % and 0.319 %, below the error and drift acceptance
criteria of 5% and 3%, respectively, in U.S. EPA Method 3A [14]. CO calibration and post drift
tests were performed each test day. The calibration error for all test days was between 0.01 %
and 1.10 %, and the system drift was between 0.66% and 1.57%, below the error and drift
acceptance criteria of 5% and 3%, respectively, in U.S. EPA Method 3A [14].
695 As emission factors are often dependent on the type of material being burned and the method
of burning, changes in composition and burn efficiency may change the emission factors
determined herein.
32

-------
5 Conclusions
Emissions from open burning of four MRE waste compositions and four MRE fiberboard packaging
700 containers were quantified for a range of emission types. MRE food packaging included current and
prospective packing material (a nanocomposite polymer). Fiberboard packaging containers for 12 MREs
consisted of current and prospective container material (cardboard and polymer-coated for wet
strength).
All fiberboard packaging had low PCDD/PCDF emission factors, consistent with values for a range of
705 biomass types. The highest value, approximately three times higher than the other packaging types, was
from the polymer-coated fiberboard packaging potentially due to minor changes in loss on drying,
chloride, and sulfur content. A weak negative correlation with combustion efficiency was noted.
PCDD/PCDF results from tests of four levels of old and new MRE packaging mixed in with the current
fiberboard MRE containers increased levels up to six-fold from the containers alone. As well, emission
710 factors amongst the MRE compositions varied six-fold with no obvious relation to composition.
Average PAH results from the fiberboard containers varied between 30 and 75 mg/kg fiberboard.
Addition of the MRE compositions to the baseline fiberboard more than doubled these values.
VOCs from burning fiberboard containers showed dominant benzene, acrolein, and toluene. The
containers with the polymer coating had two of the highest VOC concentrations but this was related to
715 low MCE values; all of the VOC emission factors were negatively correlated with MCE and two polymer
coated containers showed low VOC emissions at high MCE. Addition of MREs to the baseline packaging
fiberboard showed little change in emission factors from those of the packaging alone.
PM emissions were 90 % less than 1 pim for fiberboard tests and tended to follow the combustion
process and release of CO and C02. Little distinction was noted between the PM emission factors for the
720 four packaging types; no obvious relationship with MCE was observed. Addition of MRE pouches to the
baseline fiberboard significantly increased the PM emission factors - approximately five- to six-fold.
In general, emissions tended to follow MCE - higher values of MCE associated with greater combustion
efficiency led to lower emission factor values across all compositions tested. This suggests for this work
that attention to promoting improved combustion, rather than efforts to alter waste composition, was a
725 more effective means of lowering emissions.
33

-------
6
References
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compostable fiberboard for the military. Natick/TR-12/023. 2012.
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using X-Ray Fluorescence (XRF) Spectroscopy. 1999.
760	http://www.epa.gov/ttnamtil/files/ambient/inorganic/mthd-3-3.pdf Accessed May 5, 2014
12	Van den Berg, M.; Birnbaum, L.S.; Denison, M.; De Vito, M.; Farland, W.; Feeley, M.; Fiedler, H.;
Hakansson, H.; Hanberg, A.; Haws, L.; Rose, M.; Safe, S.; Schrenk, D.; Tohyama, C.; Tritscher, A.;
Tuomisto, J.; Tysklind, M.; Walker, N.; Peterson, R.E. The 2005 World Health Organization
reevaluation of human and mammalian toxic equivalency factors for dioxins and dioxin-like
765	compounds. Toxicol Sci. 93:223-241; 2006
13	40 CFR Part 50, Appendix L. Reference method for the determination of particulate matter as
PM2.5 in the Atmosphere, App. L. 1987.
34

-------
14	U.S. EPA Method 3A. Determination of oxygen and carbon dioxide concentrations in emissions
from stationary sources (instrumental analyzer procedure). 1989.
770	http://www.epa.gov/ttn/emc/promgate/m-03a.pdf Accessed May 5, 2014
15	U.S. EPA Method 10A. Determination of carbon monoxide emissions from stationary sources.
https://www.epa.gov/ttnemc01/promgate/m-10a.pdf Accessed May 11, 2016
16	Burling, I.R.; Yokelson, R.J.; Griffith, D.W.T.; Johnson, T.J.; Veres, P.; Roberts, J.M.; Warneke, C.;
Urbanski, S.P.; Reardon, J.; Weise, D.R.; Hao, W.M.; de Gouw, J. Laboratory measurements of
775	trace gas emissions from biomass burning of fuel types from the southeastern and southwestern
United States. Atmos Chem Phys. 10:11115-11130; 2010
17	Larsen, J.C.L., P.B. Chemical carcinogens. In: Air pollution and health. Cambridge, UK: The Royal
Society of Chemistry:33-56; 1998
18	Black, R.R.; Meyer, C.P.; Touati, A.; Gullett, B.K.; Fiedler, H.; Mueller, J.F. Emission Factors for
780 PCDD/PCDF and dl-PCB from Open Burning of Biomass. Environ Int. 38:62-66; 2012
35

-------
785
Appendices

-------
790 Appendix A: Data for each sample collected from Open Burning of Fiberboard.
Table A-l. PCDD/PCDF data for CB/CL 1.
PCDD/PCDF	Page 1 (2)
Sample ID	PS-PCDD-CB-SVOC-111814-02 MCE 0.982
Sampling volume (m3)	76.5
Carbon sampled (g)	64.1
Carbon sampled (mg/m3)	837.4
Carbon fraction	0.46245



TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total
LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ng/sample
ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 -TCDD
2.22E-04

2.22E-04
2.22E-04
2.90E-06
2.90E-06
2.90E-06
1,2,3,7,8 -PeCDD
2.00E-03

2.00E-03
2.00E-03
2.61 E-05
2.61 E-05
2.61 E-05
1,2,3,4,7,8 -HxCDD
1.78E-03

1.78E-04
1.78E-04
2.32E-05
2.32E-06
2.32E-06
1,2,3,6,7,8 -HxCDD
3.11E-03

3.11E-04
3.11E-04
4.07E-05
4.07E-06
4.07E-06
1,2,3,7,8,9-HxCDD
2.67E-03

2.67E-04
2.67E-04
3.49E-05
3.49E-06
3.49E-06
1,2,3,4,6,7,8- HpCDD
3.00E-02

3.00E-04
3.00E-04
3.92E-04
3.92E-06
3.92E-06
1,2,3,4,6,7,8,9 - OCDD
7.24E-02

2.17E-05
2.17E-05
9.47E-04
2.84E-07
2.84E-07
2,3,7,8 -TCDF
1.02E-02

1.02E-03
1.02E-03
1.34E-04
1.34E-05
1.34E-05
1,2,3,7,8-PeCDF
3.78E-03

1.13E-04
1.13E-04
4.94E-05
1.48E-06
1.48E-06
2,3,4,7,8 - PeCDF
6.22E-03

1.87E-03
1.87E-03
8.13E-05
2.44E-05
2.44E-05
1,2,3,4,7,8-HxCDF
6.67E-03

6.67E-04
6.67E-04
8.71 E-05
8.71 E-06
8.71 E-06
1,2,3,6,7,8-HxCDF
6.00E-03

6.00E-04
6.00E-04
7.84E-05
7.84E-06
7.84E-06
1,2,3,7,8,9-HxCDF
3.56E-03

3.56E-04
3.56E-04
4.65E-05
4.65E-06
4.65E-06
2,3,4,6,7,8 - HxCDF
1.13E-02

1.13E-03
1.13E-03
1.48E-04
1.48E-05
1.48E-05
1,2,3,4,6,7,8- HpCDF
3.16E-02

3.16E-04
3.16E-04
4.12E-04
4.12E-06
4.12E-06
1,2,3,4,7,8,9- HpCDF
4.89E-03

4.89E-05
4.89E-05
6.39E-05
6.39E-07
6.39E-07
1,2,3,4,6,7,8,9-OCDF
1.84E-02

5.53E-06
5.53E-06
2.41 E-04
7.23E-08
7.23E-08
TeCDD Total
4.51 E-02



5.90E-04


PeCDD Total
2.74E-02



3.58E-04


HxCDD Total
2.78E-02



3.63E-04


HpCDD Total
5.21 E-02



6.81 E-04


OCDD
7.24E-02



9.46E-04


TeCDF Total
1.58E-01



2.07E-03


PeCDF Total
6.39E-02



8.35E-04


HxCDF Total
6.50E-02



8.49E-04


HpCDF Total
5.87E-02



7.67E-04


OCDF
1.85E-02



2.41 E-04


PCDD Total
2.25E-01



2.94E-03


PCDF Total
3.64E-01



4.76E-03


PCDD/PCDF Total
5.89E-01



7.70E-03


PCDD TEQ Total


3.30E-03
3.30E-03

4.31 E-05
4.31 E-05
PCDF TEQ Total


6.13E-03
6.13E-03

8.01 E-05
8.01 E-05
PCDD/PCDF TEQ Total


9.43E-03
9.43E-03

1.23E-04
1.23E-04
1-A

-------
Sample ID
PS-PCDD-CB-SVOC-111814-02
Page 2 (2)

EF
EF
EF
EF
EF
EF

Total
TEQ
TEQ
Total
TEQ
TEQ
Isomer.

ng/g Carbon


ng/kg fiberboard



ND=0
ND=LOD

ND=0
ND=LOD
2,3,7,8 - TCDD
3.47E-06
3.47E-06
3.47E-06
1.60E-03
1.60E-03
1.60E-03
1,2,3,7,8 - PeCDD
3.12E-05
3.12E-05
3.12E-05
1.44E-02
1.44E-02
1.44E-02
1,2,3,4,7,8 - HxCDD
2.77E-05
2.77E-06
2.77E-06
1.28E-02
1.28E-03
1.28E-03
1,2,3,6,7,8 - HxCDD
4.86E-05
4.86E-06
4.86E-06
2.25E-02
2.25E-03
2.25E-03
1,2,3,7,8,9 - HxCDD
4.16E-05
4.16E-06
4.16E-06
1.92E-02
1.92E-03
1.92E-03
1,2,3,4,6,7,8 - HpCDD
4.68E-04
4.68E-06
4.68E-06
2.17E-01
2.17E-03
2.17E-03
1,2,3,4,6,7,8,9 - OCDD
1.13E-03
3.39E-07
3.39E-07
5.23E-01
1.57E-04
1.57E-04
2,3,7,8 - TCDF
1.60E-04
1.60E-05
1.60E-05
7.38E-02
7.38E-03
7.38E-03
1,2,3,7,8 - PeCDF
5.90E-05
1.77E-06
1.77E-06
2.73E-02
8.18E-04
8.18E-04
2,3,4,7,8 - PeCDF
9.71 E-05
2.91 E-05
2.91 E-05
4.49E-02
1.35E-02
1.35E-02
1,2,3,4,7,8 - HxCDF
1.04E-04
1.04E-05
1.04E-05
4.81 E-02
4.81 E-03
4.81 E-03
1,2,3,6,7,8 - HxCDF
9.36E-05
9.36E-06
9.36E-06
4.33E-02
4.33E-03
4.33E-03
1,2,3,7,8,9 - HxCDF
5.55E-05
5.55E-06
5.55E-06
2.57E-02
2.57E-03
2.57E-03
2,3,4,6,7,8 - HxCDF
1.77E-04
1.77E-05
1.77E-05
8.18E-02
8.18E-03
8.18E-03
1,2,3,4,6,7,8 - HpCDF
4.92E-04
4.92E-06
4.92E-06
2.28E-01
2.28E-03
2.28E-03
1,2,3,4,7,8,9 - HpCDF
7.63E-05
7.63E-07
7.63E-07
3.53E-02
3.53E-04
3.53E-04
1,2,3,4,6,7,8,9 - OCDF
2.88E-04
8.64E-08
8.64E-08
1.33E-01
3.99E-05
3.99E-05
TeCDD Total
7.04E-04


3.26E-01


PeCDD Total
4.27E-04


1.97E-01


HxCDD Total
4.34E-04


2.00E-01


HpCDD Total
8.13E-04


3.76E-01


OCDD
1.13E-03


5.23E-01


TeCDF Total
2.47E-03


1.14E+00


PeCDF Total
9.97E-04


4.61 E-01


HxCDF Total
1.01 E-03


4.69E-01


HpCDF Total
9.16E-04


4.23E-01


OCDF
2.88E-04


1.33E-01


PCDD Total
3.51 E-03


1.62E+00


PCDF Total
5.69E-03


2.63E+00


PCDD/PCDF Total
9.20E-03


4.25E+00


PCDD TEQ Total

5.15E-05
5.15E-05

2.38E-02
2.38E-02
PCDF TEQ Total

9.56E-05
9.56E-05

4.42E-02
4.42E-02
PCDD/PCDF TEQ Total

1.47E-04
1.47E-04

6.80E-02
6.80E-02
2-A

-------
Table A-2. PCDD/PCDF
data for CB/CL 2.
Page 1 (2)
PCDD/PCDF
Sample ID	PS-PCDD-CB2-SVOC-111914-02	MCE 0.984
Sampling volume (m3)	62.8
Carbon sampled (g)	73.1
Carbon sampled (mg/m3)	1164.9
Carbon fraction	0.4625


TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total
LOD ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ng/sample ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
4.44E-04
4.44E-04
4.44E-04
7.08E-06
7.08E-06
7.08E-06
1,2,3,7,8- PeCDD
1.11E-03
1.11E-03
1.11E-03
1.77E-05
1.77E-05
1.77E-05
1,2,3,4,7,8- HxCDD
6.67E-04
6.67E-05
6.67E-05
1.06E-05
1.06E-06
1.06E-06
1,2,3,6,7,8- HxCDD
1.78E-03
1.78E-04
1.78E-04
2.83E-05
2.83E-06
2.83E-06
1,2,3,7,8,9- HxCDD
1.78E-03
1.78E-04
1.78E-04
2.83E-05
2.83E-06
2.83E-06
1,2,3,4,6,7,8- HpCDD
2.22E-02
2.22E-04
2.22E-04
3.54E-04
3.54E-06
3.54E-06
1,2,3,4,6,7,8,9 - OCDD
5.96E-02
1.79E-05
1.79E-05
9.49E-04
2.85E-07
2.85E-07
2,3,7,8 - TCDF
1.00E-02
1.00E-03
1.00E-03
1.59E-04
1.59E-05
1.59E-05
1,2,3,7,8- PeCDF
3.33E-03
1.00E-04
1.00E-04
5.31 E-05
1.59E-06
1.59E-06
2,3,4,7,8- PeCDF
3.11E-03
9.33E-04
9.33E-04
4.96E-05
1.49E-05
1.49E-05
1,2,3,4,7,8- HxCDF
2.22E-03
2.22E-04
2.22E-04
3.54E-05
3.54E-06
3.54E-06
1,2,3,6,7,8- HxCDF
1.56E-03
1.56E-04
1.56E-04
2.48E-05
2.48E-06
2.48E-06
1,2,3,7,8,9- HxCDF
6.67E-04
6.67E-05
6.67E-05
1.06E-05
1.06E-06
1.06E-06
2,3,4,6,7,8 - HxCDF
2.22E-03
2.22E-04
2.22E-04
3.54E-05
3.54E-06
3.54E-06
1,2,3,4,6,7,8- HpCDF
5.11E-03
5.11E-05
5.11E-05
8.14E-05
8.14E-07
8.14E-07
1,2,3,4,7,8,9- HpCDF
6.67E-04
6.67E-06
6.67E-06
1.06E-05
1.06E-07
1.06E-07
1,2,3,4,6,7,8,9-OCDF
6.00E-03
1.80E-06
1.80E-06
9.56E-05
2.87E-08
2.87E-08
TeCDD Total
4.00E-02


6.37E-04


PeCDD Total
1.93E-02


3.07E-04


HxCDD Total
2.10E-02


3.34E-04


HpCDD Total
3.63E-02


5.79E-04


OCDD
5.96E-02


9.50E-04


TeCDF Total
1.29E-01


2.06E-03


PeCDF Total
3.96E-02


6.31 E-04


HxCDF Total
1.38E-02


2.20E-04


HpCDF Total
1.14E-02


1.82E-04


OCDF
6.04E-03


9.63E-05


PCDD Total
1.76E-01


2.81 E-03


PCDF Total
2.00E-01


3.19E-03


PCDD/PCDF Total
3.76E-01


6.00E-03


PCDD TEQ Total

2.22E-03
2.22E-03

3.53E-05
3.53E-05
PCDF TEQ Total

2.76E-03
2.76E-03

4.40 E-05
4.40E-05
PCDD/PCDF TEQ Total

4.98E-03
4.98E-03

7.93E-05
7.93E-05

-------
795
Sample ID
PS-PCDD-CB2-SV0C-111914-02
Page 2 (2)

EF
EF
EF
EF
EF
EF

Total
TEQ
TEQ
Total
TEQ
TEQ
Isomer.

ng/g Carbon


ng/kg fiberboard



ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8-TCDD
6.08E-06
6.08E-06
6.08E-06
2.81 E-03
2.81 E-03
2.81 E-03
1,2,3,7,8 -PeCDD
1.52E-05
1.52E-05
1.52E-05
7.03E-03
7.03E-03
7.03E-03
1,2,3,4,7,8-HxCDD
9.12E-06
9.12E-07
9.12E-07
4.22E-03
4.22E-04
4.22E-04
1,2,3,6,7,8 -HxCDD
2.43E-05
2.43E-06
2.43E-06
1.12E-02
1.12E-03
1.12E-03
1,2,3,7,8,9-HxCDD
2.43E-05
2.43E-06
2.43E-06
1.12E-02
1.12E-03
1.12E-03
1,2,3,4,6,7,8- HpCDD
3.04E-04
3.04E-06
3.04E-06
1.41 E-01
1.41 E-03
1.41 E-03
1,2,3,4,6,7,8,9 - OCDD
8.15E-04
2.44E-07
2.44E-07
3.77E-01
1.13E-04
1.13E-04
2,3,7,8 -TCDF
1.37E-04
1.37E-05
1.37E-05
6.32E-02
6.32E-03
6.32E-03
1,2,3,7,8-PeCDF
4.56E-05
1.37E-06
1.37E-06
2.11E-02
6.32E-04
6.32E-04
2,3,4,7,8 - PeCDF
4.26E-05
1.28E-05
1.28E-05
1.97E-02
5.90E-03
5.90E-03
1,2,3,4,7,8-HxCDF
3.04E-05
3.04E-06
3.04E-06
1.41 E-02
1.41 E-03
1.41 E-03
1,2,3,6,7,8-HxCDF
2.13E-05
2.13E-06
2.13E-06
9.84E-03
9.84E-04
9.84E-04
1,2,3,7,8,9-HxCDF
9.12E-06
9.12E-07
9.12E-07
4.22E-03
4.22E-04
4.22E-04
2,3,4,6,7,8 - HxCDF
3.04E-05
3.04E-06
3.04E-06
1.41 E-02
1.41 E-03
1.41 E-03
1,2,3,4,6,7,8- HpCDF
6.99E-05
6.99E-07
6.99E-07
3.23E-02
3.23E-04
3.23E-04
1,2,3,4,7,8,9- HpCDF
9.12E-06
9.12E-08
9.12E-08
4.22E-03
4.22E-05
4.22E-05
1,2,3,4,6,7,8,9-OCDF
8.21 E-05
2.46E-08
2.46E-08
3.79E-02
1.14E-05
1.14E-05
TeCDD Total
5.46E-04


2.53E-01


PeCDD Total
2.64E-04


1.22E-01


HxCDD Total
2.87E-04


1.33E-01


HpCDD Total
4.97E-04


2.30E-01


OCDD
8.15E-04


3.77E-01


TeCDF Total
1.77E-03


8.18E-01


PeCDF Total
5.42E-04


2.51 E-01


HxCDF Total
1.89E-04


8.74E-02


HpCDF Total
1.57E-04


7.24E-02


OCDF
8.27E-05


3.82E-02


PCDD Total
2.41 E-03


1.11 E+00


PCDF Total
2.74E-03


1.27E+00


PCDD/PCDF Total
5.15E-03


2.38E+00


PCDD TEQ Total

3.03E-05
3.03E-05

1.40E-02
1.40E-02
PCDF TEQ Total

3.77E-05
3.77E-05

1.75E-02
1.75E-02
PCDD/PCDF TEQ Total

6.81 E-05
6.81 E-05

3.15E-02
3.15E-02
4-A

-------
Table A-3. PCDD/PCDF data for CB/CL 3.
PCDD/PCDF	Page 1 (2)
Sample ID	PS-PCDD-CB3-SV0C-112014-02 MCE 0.985
Sampling volume (m3)	60.5
Carbon sampled (g)	65.0
Carbon sampled (mg/m3)	1074.5
Carbon fraction	0.4625


TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total
LOD ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ng/sample ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8-TCDD
4.44E-04
4.44E-04
4.44E-04
7.34E-06
7.34E-06
7.34E-06
1,2,3,7,8- PeCDD
2.00E-03
2.00E-03
2.00E-03
3.30E-05
3.30E-05
3.30E-05
1,2,3,4,7,8- HxCDD
8.89E-04
8.89E-05
8.89E-05
1.47E-05
1.47E-06
1.47E-06
1,2,3,6,7,8- HxCDD
2.22E-03
2.22E-04
2.22E-04
3.67E-05
3.67E-06
3.67E-06
1,2,3,7,8,9- HxCDD
1.78E-03
1.78E-04
1.78E-04
2.94E-05
2.94E-06
2.94E-06
1,2,3,4,6,7,8- HpCDD
1.93E-02
1.93E-04
1.93E-04
3.19E-04
3.19E-06
3.19E-06
1,2,3,4,6,7,8,9 - OCDD
5.82E-02
1.75E-05
1.75E-05
9.62E-04
2.89E-07
2.89E-07
2,3,7,8 - TCDF
1.02E-02
1.02E-03
1.02E-03
1.69E-04
1.69E-05
1.69E-05
1,2,3,7,8- PeCDF
3.78E-03
1.13E-04
1.13E-04
6.24E-05
1.87E-06
1.87E-06
2,3,4,7,8- PeCDF
4.44E-03
1.33E-03
1.33E-03
7.34E-05
2.20E-05
2.20E-05
1,2,3,4,7,8- HxCDF
3.33E-03
3.33E-04
3.33E-04
5.51 E-05
5.51 E-06
5.51 E-06
1,2,3,6,7,8- HxCDF
2.67E-03
2.67E-04
2.67E-04
4.41 E-05
4.41 E-06
4.41 E-06
1,2,3,7,8,9- HxCDF
1.11E-03
1.11E-04
1.11E-04
1.84E-05
1.84E-06
1.84E-06
2,3,4,6,7,8 - HxCDF
2.89E-03
2.89E-04
2.89E-04
4.77E-05
4.77E-06
4.77E-06
1,2,3,4,6,7,8- HpCDF
6.67E-03
6.67E-05
6.67E-05
1.10E-04
1.10E-06
1.10E-06
1,2,3,4,7,8,9- HpCDF
8.89E-04
8.89E-06
8.89E-06
1.47E-05
1.47E-07
1.47E-07
1,2,3,4,6,7,8,9-OCDF
7.11E-03
2.13E-06
2.13E-06
1.17E-04
3.52E-08
3.52E-08
TeCDD Total
5.61 E-02


9.27E-04


PeCDD Total
3.18E-02


5.25E-04


HxCDD Total
2.64E-02


4.36E-04


HpCDD Total
3.58E-02


5.92E-04


OCDD
5.81 E-02


9.60E-04


TeCDF Total
1.57E-01


2.59E-03


PeCDF Total
6.09E-02


1.01E-03


HxCDF Total
2.64E-02


4.37E-04


HpCDF Total
1.39E-02


2.29E-04


OCDF
7.00E-03


1.16E-04


PCDD Total
2.08E-01


3.44E-03


PCDF Total
2.65E-01


4.38E-03


PCDD/PCDF Total
4.73E-01


7.82E-03


PCDD TEQ Total

3.14E-03
3.14E-03

5.19E-05
5.19E-05
PCDF TEQ Total

3.55E-03
3.55E-03

5.86E-05
5.86E-05
PCDD/PCDF TEQ Total

6.69E-03
6.69E-03

1.11E-04
1.11E-04
5-A

-------
Sample ID
PS-PCDD-CB3-SV0C-112014-02
Page 2 (2)

EF
EF
EF
EF
EF
EF

Total
TEQ
TEQ
Total
TEQ
TEQ
Isomer.
ng/g Carbon
ng/g Carbon
ng/g Carbon
ng/kg fiberboard


ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8-TCDD
6.83E-06
6.83E-06
6.83E-06
3.16E-03
3.16E-03
3.16E-03
1,2,3,7,8-PeCDD
3.08E-05
3.08E-05
3.08E-05
1.42E-02
1.42E-02
1.42E-02
1,2,3,4,7,8-HxCDD
1.37E-05
1.37E-06
1.37E-06
6.32E-03
6.32E-04
6.32E-04
1,2,3,6,7,8 -HxCDD
3.42E-05
3.42E-06
3.42E-06
1.58E-02
1.58E-03
1.58E-03
1,2,3,7,8,9-HxCDD
2.73E-05
2.73E-06
2.73E-06
1.26E-02
1.26E-03
1.26E-03
1,2,3,4,6,7,8- HpCDD
2.97E-04
2.97E-06
2.97E-06
1.37E-01
1.37E-03
1.37E-03
1,2,3,4,6,7,8,9 - OCDD
8.95E-04
2.69E-07
2.69E-07
4.14E-01
1.24E-04
1.24E-04
2,3,7,8 -TCDF
1.57E-04
1.57E-05
1.57E-05
7.27E-02
7.27E-03
7.27E-03
1,2,3,7,8-PeCDF
5.81 E-05
1.74E-06
1.74E-06
2.69E-02
8.06E-04
8.06E-04
2,3,4,7,8 - PeCDF
6.83E-05
2.05E-05
2.05E-05
3.16E-02
9.48E-03
9.48E-03
1,2,3,4,7,8-HxCDF
5.13E-05
5.13E-06
5.13E-06
2.37E-02
2.37E-03
2.37E-03
1,2,3,6,7,8-HxCDF
4.10E-05
4.10E-06
4.10E-06
1.90E-02
1.90E-03
1.90E-03
1,2,3,7,8,9-HxCDF
1.71 E-05
1.71E-06
1.71 E-06
7.90E-03
7.90E-04
7.90E-04
2,3,4,6,7,8 - HxCDF
4.44E-05
4.44E-06
4.44E-06
2.05E-02
2.05E-03
2.05E-03
1,2,3,4,6,7,8- HpCDF
1.03E-04
1.03E-06
1.03E-06
4.74E-02
4.74E-04
4.74E-04
1,2,3,4,7,8,9- HpCDF
1.37E-05
1.37E-07
1.37E-07
6.32E-03
6.32E-05
6.32E-05
1,2,3,4,6,7,8,9-OCDF
1.09E-04
3.28E-08
3.28E-08
5.06E-02
1.52E-05
1.52E-05
TeCDD Total
8.63E-04


3.99E-01


PeCDD Total
4.89E-04


2.26E-01


HxCDD Total
4.06E-04


1.88E-01


HpCDD Total
5.51 E-04


2.55E-01


OCDD
8.94E-04


4.13E-01


TeCDF Total
2.41 E-03


1.12E+00


PeCDF Total
9.36E-04


4.33E-01


HxCDF Total
4.06E-04


1.88E-01


HpCDF Total
2.13E-04


9.86E-02


OCDF
1.08E-04


4.98E-02


PCDD Total
3.20E-03


1.48E+00


PCDF Total
4.08E-03


1.88E+00


PCDD/PCDF Total
7.28E-03


3.37E+00


PCDD TEQ Total

4.83E-05
4.83E-05

2.24E-02
2.24E-02
PCDF TEQ Total

5.45E-05
5.45E-05

2.52E-02
2.52E-02
PCDD/PCDF TEQ Total

1.03E-04
1.03E-04

4.76E-02
4.76E-02
Table A-4. PCDD/PCDF data for CB/CL 4.
6-A

-------
PCDD/PCDF	Page 1 (2)
Sample ID	PS-PCDD-CB4-SV0C-112114-01 MCE 0.986
Sampling volume (m3)	60.5
Carbon sampled (g)	70.9
Carbon sampled (mg/m3)	1172.0
Carbon fraction	0.4625


TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total
LOD ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ng/sample ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 -TCDD
ND
7.56E-04 0.00E+00
7.56E-04
ND
0.00E+00
1.25E-05
1,2,3,7,8 -PeCDD
1.56E-03
1.56E-03
1.56E-03
2.57E-05
2.57E-05
2.57E-05
1,2,3,4,7,8 -HxCDD
1.11E-03
1.11E-04
1.11E-04
1.84E-05
1.84E-06
1.84E-06
1,2,3,6,7,8 -HxCDD
2.44E-03
2.44E-04
2.44E-04
4.04E-05
4.04E-06
4.04E-06
1,2,3,7,8,9-HxCDD
1.33E-03
1.33E-04
1.33E-04
2.20E-05
2.20E-06
2.20E-06
1,2,3,4,6,7,8- HpCDD
2.18E-02
2.18E-04
2.18E-04
3.60E-04
3.60E-06
3.60E-06
1,2,3,4,6,7,8,9 - OCDD
6.13E-02
1.84E-05
1.84E-05
1.01E-03
3.04E-07
3.04E-07
2,3,7,8 -TCDF
7.78E-03
7.78E-04
7.78E-04
1.29E-04
1.29E-05
1.29E-05
1,2,3,7,8-PeCDF
3.78E-03
1.13E-04
1.13E-04
6.24E-05
1.87E-06
1.87E-06
2,3,4,7,8 - PeCDF
3.78E-03
1.13E-03
1.13E-03
6.24E-05
1.87E-05
1.87E-05
1,2,3,4,7,8-HxCDF
3.11E-03
3.11E-04
3.11E-04
5.14E-05
5.14E-06
5.14E-06
1,2,3,6,7,8- HxCDF
3.11E-03
3.11E-04
3.11E-04
5.14E-05
5.14E-06
5.14E-06
1,2,3,7,8,9-HxCDF
1.33E-03
1.33E-04
1.33E-04
2.20E-05
2.20E-06
2.20E-06
2,3,4,6,7,8 - HxCDF
3.56E-03
3.56E-04
3.56E-04
5.88E-05
5.88E-06
5.88E-06
1,2,3,4,6,7,8- HpCDF
7.78E-03
7.78E-05
7.78E-05
1.29E-04
1.29E-06
1.29E-06
1,2,3,4,7,8,9- HpCDF
ND
9.11E-04 0.00E+00
9.11E-06
ND
0.00E+00
1.51E-07
1,2,3,4,6,7,8,9-OCDF
8.67E-03
2.60E-06
2.60E-06
1.43E-04
4.30E-08
4.30E-08
TeCDD Total
4.63E-02


7.65E-04


PeCDD Total
3.15E-02


5.21 E-04


HxCDD Total
2.46E-02


4.07E-04


HpCDD Total
3.87E-02


6.40E-04


OCDD
6.14E-02


1.01 E-03


TeCDF Total
1.22E-01


2.02E-03


PeCDF Total
5.53E-02


9.13E-04


HxCDF Total
2.65E-02


4.37E-04


HpCDF Total
1.36E-02


2.24E-04


OCDF
8.56E-03


1.41 E-04


PCDD Total
2.03E-01


3.35E-03


PCDF Total
2.26E-01


3.74E-03


PCDD/PCDF Total
4.29E-01


7.09E-03


PCDD TEQ Total

2.28E-03
3.04E-03

3.77E-05
5.02E-05
PCDF TEQ Total

3.22E-03
3.23E-03

5.31 E-05
5.33E-05
PCDD/PCDF TEQ Total

5.50E-03
6.26E-03

9.08E-05
1.03E-04
7-A

-------
Sample ID
PS-PCDD-CB4-SV0C-112114-01
Page 2 (2)

EF
EF
EF
EF
EF
EF

Total
TEQ
TEQ
Total
TEQ
TEQ
Isomer.

ng/g Carbon


ng/kg fiberboard



ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
ND
0.00E+00
1.07E-05
ND
0.00E+00
4.93E-03
1,2,3,7,8- PeCDD
2.19E-05
2.19E-05
2.19E-05
1.01E-02
1.01 E-02
1.01 E-02
1,2,3,4,7,8- HxCDD
1.57E-05
1.57E-06
1.57E-06
7.25E-03
7.25E-04
7.25E-04
1,2,3,6,7,8- HxCDD
3.45E-05
3.45E-06
3.45E-06
1.59E-02
1.59E-03
1.59E-03
1,2,3,7,8,9- HxCDD
1.88E-05
1.88E-06
1.88E-06
8.69E-03
8.69E-04
8.69E-04
1,2,3,4,6,7,8- HpCDD
3.07E-04
3.07E-06
3.07E-06
1.42E-01
1.42E-03
1.42E-03
1,2,3,4,6,7,8,9 - OCDD
8.65E-04
2.59E-07
2.59E-07
4.00E-01
1.20E-04
1.20E-04
2,3,7,8 - TCDF
1.10E-04
1.10E-05
1.10E-05
5.07E-02
5.07E-03
5.07E-03
1,2,3,7,8- PeCDF
5.33E-05
1.60E-06
1.60E-06
2.46E-02
7.39E-04
7.39E-04
2,3,4,7,8- PeCDF
5.33E-05
1.60E-05
1.60E-05
2.46E-02
7.39E-03
7.39E-03
1,2,3,4,7,8- HxCDF
4.39E-05
4.39E-06
4.39E-06
2.03E-02
2.03E-03
2.03E-03
1,2,3,6,7,8- HxCDF
4.39E-05
4.39E-06
4.39E-06
2.03E-02
2.03E-03
2.03E-03
1,2,3,7,8,9- HxCDF
1.88E-05
1.88E-06
1.88E-06
8.69E-03
8.69E-04
8.69E-04
2,3,4,6,7,8 - HxCDF
5.01 E-05
5.01 E-06
5.01 E-06
2.32E-02
2.32E-03
2.32E-03
1,2,3,4,6,7,8- HpCDF
1.10E-04
1.10E-06
1.10E-06
5.07E-02
5.07E-04
5.07E-04
1,2,3,4,7,8,9- HpCDF
ND
0.00E+00
1.28E-07
ND
0.00E+00
5.94E-05
1,2,3,4,6,7,8,9-OCDF
1.22E-04
3.67E-08
3.67E-08
5.65E-02
1.70E-05
1.70E-05
TeCDD Total
6.53E-04


3.02E-01


PeCDD Total
4.45E-04


2.06E-01


HxCDD Total
3.47E-04


1.61E-01


HpCDD Total
5.46E-04


2.52E-01


OCDD
8.66E-04


4.00E-01


TeCDF Total
1.73E-03


7.98E-01


PeCDF Total
7.79E-04


3.60E-01


HxCDF Total
3.73E-04


1.73E-01


HpCDF Total
1.91 E-04


8.84E-02


OCDF
1.21 E-04


5.58E-02


PCDD Total
2.86E-03


1.32E+00


PCDF Total
3.19E-03


1.47E+00


PCDD/PCDF Total
6.05E-03


2.80E+00


PCDD TEQ Total

3.22E-05
4.28E-05

1.49E-02
1.98E-02
PCDF TEQ Total

4.53E-05
4.55E-05

2.10E-02
2.10E-02
PCDD/PCDF TEQ Total

7.75E-05
8.83E-05

3.58E-02
4.08E-02
800 Table A-5. PCDD/PCDF data for NSB/NSL 1.
8-A

-------
PCDD/PCDF	Page 1 (2)
Sample ID	PS-PCDD-NSB-SVOC-111914-02 MCE 0.984
Sampling volume (m3)	45.3
Carbon sampled (g)	65.2
Carbon sampled (mg/m3)	1438.8
Carbon fraction	0.4561



TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total
LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ng/sample
ND =0
ND = LOD

ND = 0
ND = LOD
2,3,7,8-TCDD
ND
2.58E-03
0.00E+00
2.58E-03
ND
0.00E+00
5.69E-05
1,2,3,7,8-PeCDD
ND
5.18E-03
0.00E+00
5.18E-03
ND
0.00E+00
1.14E-04
1,2,3,4,7,8 -HxCDD
ND
4.29E-03
0.00E+00
4.29E-04
ND
0.00E+00
9.46E-06
1,2,3,6,7,8 -HxCDD
8.67E-03

8.67E-04
8.67E-04
1.91E-04
1.91 E-05
1.91 E-05
1,2,3,7,8,9-HxCDD
6.44E-03

6.44E-04
6.44E-04
1.42E-04
1.42E-05
1.42E-05
1,2,3,4,6,7,8- HpCDD
1.20E-01

1.20E-03
1.20E-03
2.64E-03
2.64E-05
2.64E-05
1,2,3,4,6,7,8,9 - OCDD
3.96E-01

1.19E-04
1.19E-04
8.74E-03
2.62E-06
2.62E-06
2,3,7,8 -TCDF
1.20E-02

1.20E-03
1.20E-03
2.65E-04
2.65E-05
2.65E-05
1,2,3,7,8-PeCDF
ND
5.07E-03
0.00E+00
1.52E-04
ND
0.00E+00
3.35E-06
2,3,4,7,8 - PeCDF
ND
4.82E-03
0.00E+00
1.45E-03
ND
0.00E+00
3.19E-05
1,2,3,4,7,8-HxCDF
4.67E-03

4.67E-04
4.67E-04
1.03E-04
1.03E-05
1.03E-05
1,2,3,6,7,8-HxCDF
4.22E-03

4.22E-04
4.22E-04
9.31 E-05
9.31 E-06
9.31 E-06
1,2,3,7,8,9-HxCDF
ND
4.36E-03
0.00E+00
4.36E-04
ND
0.00E+00
9.61 E-06
2,3,4,6,7,8 - HxCDF
ND
4.84E-03
0.00E+00
4.84E-04
ND
0.00E+00
1.07E-05
1,2,3,4,6,7,8- HpCDF
1.09E-02

1.09E-04
1.09E-04
2.40E-04
2.40E-06
2.40E-06
1,2,3,4,7,8,9- HpCDF
ND
4.62E-03
0.00E+00
4.62E-05
ND
0.00E+00
1.02E-06
1,2,3,4,6,7,8,9-OCDF
1.47E-02

4.40E-06
4.40E-06
3.24E-04
9.71 E-08
9.71 E-08
TeCDD Total
3.07E-02



6.77E-04


PeCDD Total
1.14E-02



2.51 E-04


HxCDD Total
4.62E-02



1.02E-03


HpCDD Total
1.87E-01



4.12E-03


OCDD
3.96E-01



8.75E-03


TeCDF Total
1.08E-01



2.39E-03


PeCDF Total
1.63E-02



3.60E-04


HxCDF Total
1.81E-02



3.99E-04


HpCDF Total
2.65E-02



5.84E-04


OCDF
1.63E-02



3.60E-04


PCDD Total
6.72E-01



1.48E-02


PCDF Total
1.86E-01



4.10E-03


PCDD/PCDF Total
8.57E-01



1.89E-02


PCDD TEQ Total


2.83E-03
1.10E-02

6.24E-05
2.43E-04
PCDF TEQ Total


2.20E-03
4.77E-03

4.86E-05
1.05E-04
PCDD/PCDF TEQ Total


5.03E-03
1.58E-02

1.11 E-04
3.48E-04
Sample ID	PS-PCDD-NSB-SVOC-111914-02	Page 2 (2)
9-A

-------

EF
EF
EF
EF
EF
EF

Total
TEQ
TEQ
Total
TEQ
TEQ
Isomer.

ng/g Carbon


ng/kg fiberboard



ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
ND
0.00E+00
3.95E-05
ND
0.00E+00
1.80E-02
1,2,3,7,8- PeCDD
ND
0.00E+00
7.94E-05
ND
0.00E+00
3.62E-02
1,2,3,4,7,8- HxCDD
ND
0.00E+00
6.58E-06
ND
0.00E+00
3.00E-03
1,2,3,6,7,8- HxCDD
1.33E-04
1.33E-05
1.33E-05
6.06E-02
6.06E-03
6.06E-03
1,2,3,7,8,9- HxCDD
9.88E-05
9.88E-06
9.88E-06
4.51 E-02
4.51 E-03
4.51 E-03
1,2,3,4,6,7,8- HpCDD
1.84E-03
1.84E-05
1.84E-05
8.37E-01
8.37E-03
8.37E-03
1,2,3,4,6,7,8,9 - OCDD
6.08E-03
1.82E-06
1.82E-06
2.77E+00
8.32E-04
8.32E-04
2,3,7,8 - TCDF
1.84E-04
1.84E-05
1.84E-05
8.39E-02
8.39E-03
8.39E-03
1,2,3,7,8- PeCDF
ND
0.00E+00
2.33E-06
ND
0.00E+00
1.06E-03
2,3,4,7,8- PeCDF
ND
0.00E+00
2.22E-05
ND
0.00E+00
1.01 E-02
1,2,3,4,7,8- HxCDF
7.15E-05
7.15E-06
7.15E-06
3.26E-02
3.26E-03
3.26E-03
1,2,3,6,7,8- HxCDF
6.47E-05
6.47E-06
6.47E-06
2.95E-02
2.95E-03
2.95E-03
1,2,3,7,8,9- HxCDF
ND
0.00E+00
6.68E-06
ND
0.00E+00
3.05E-03
2,3,4,6,7,8 - HxCDF
ND
0.00E+00
7.43E-06
ND
0.00E+00
3.39E-03
1,2,3,4,6,7,8- HpCDF
1.67E-04
1.67E-06
1.67E-06
7.61 E-02
7.61 E-04
7.61 E-04
1,2,3,4,7,8,9- HpCDF
ND
0.00E+00
7.09E-07
ND
0.00E+00
3.23E-04
1,2,3,4,6,7,8,9-OCDF
2.25E-04
6.75E-08
6.75E-08
1.03E-01
3.08E-05
3.08E-05
TeCDD Total
4.71 E-04


2.15E-01


PeCDD Total
1.75E-04


7.97E-02


HxCDD Total
7.08E-04


3.23E-01


HpCDD Total
2.86E-03


1.31E+00


OCDD
6.08E-03


2.77E+00


TeCDF Total
1.66E-03


7.58E-01


PeCDF Total
2.50E-04


1.14E-01


HxCDF Total
2.77E-04


1.26E-01


HpCDF Total
4.06E-04


1.85E-01


OCDF
2.50E-04


1.14E-01


PCDD Total
1.03E-02


4.70E+00


PCDF Total
2.85E-03


1.30E+00


PCDD/PCDF Total
1.31 E-02


5.99E+00


PCDD TEQ Total

4.34E-05
1.69E-04

1.98E-02
7.70E-02
PCDF TEQ Total

3.38E-05
7.31 E-05

1.54E-02
3.33E-02
PCDD/PCDF TEQ Total

7.71 E-05
2.42E-04

3.52E-02
1.10E-01
Table A-6. PCDD/PCDF data for NSB/NSL 2.
PCDD/PCDF	Page 1 (2)
10-A

-------
Sample ID	PS-PCDD-NSB2-SVOC-121114-01	MCE 0.971
Sampling volume (m3)	95.0
Carbon sampled (g)	75.2
Carbon sampled (mg/m3)	791.8
Carbon fraction	0.45605



TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total
LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ng/sample
ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 -TCDD
2.44E-03

2.44E-03
2.44E-03
2.57E-05
2.57E-05
2.57E-05
1,2,3,7,8- PeCDD
1.27E-02

1.27E-02
1.27E-02
1.33E-04
1.33E-04
1.33E-04
1,2,3,4,7,8 -HxCDD
6.22E-03

6.22E-04
6.22E-04
6.55E-05
6.55E-06
6.55E-06
1,2,3,6,7,8 -HxCDD
2.33E-02

2.33E-03
2.33E-03
2.46E-04
2.46E-05
2.46E-05
1,2,3,7,8,9-HxCDD
1.71E-02

1.71E-03
1.71 E-03
1.80E-04
1.80E-05
1.80E-05
1,2,3,4,6,7,8- HpCDD
2.88E-01

2.88E-03
2.88E-03
3.04E-03
3.04E-05
3.04E-05
1,2,3,4,6,7,8,9 - OCDD
7.55E-01

2.26E-04
2.26E-04
7.94E-03
2.38E-06
2.38E-06
2,3,7,8 -TCDF
1.18E-02

1.18E-03
1.18E-03
1.24E-04
1.24E-05
1.24E-05
1,2,3,7,8-PeCDF
4.00E-03

1.20E-04
1.20E-04
4.21 E-05
1.26E-06
1.26E-06
2,3,4,7,8 - PeCDF
6.22E-03

1.87E-03
1.87E-03
6.55E-05
1.96E-05
1.96E-05
1,2,3,4,7,8-HxCDF
4.44E-03

4.44E-04
4.44E-04
4.68E-05
4.68E-06
4.68E-06
1,2,3,6,7,8-HxCDF
3.33E-03

3.33E-04
3.33E-04
3.51 E-05
3.51 E-06
3.51 E-06
1,2,3,7,8,9-HxCDF
1.33E-03

1.33E-04
1.33E-04
1.40E-05
1.40E-06
1.40E-06
2,3,4,6,7,8 - HxCDF
4.44E-03

4.44E-04
4.44E-04
4.68E-05
4.68E-06
4.68E-06
1,2,3,4,6,7,8- HpCDF
1.27E-02

1.27E-04
1.27E-04
1.33E-04
1.33E-06
1.33E-06
1,2,3,4,7,8,9- HpCDF
2.67E-03

2.67E-05
2.67E-05
2.81 E-05
2.81 E-07
2.81 E-07
1,2,3,4,6,7,8,9-OCDF
1.53E-02

4.60E-06
4.60E-06
1.61 E-04
4.84E-08
4.84E-08
TeCDD Total
8.09E-02



8.51 E-04


PeCDD Total
7.56E-02



7.96E-04


HxCDD Total
1.73E-01



1.82E-03


HpCDD Total
4.65E-01



4.90E-03


OCDD
7.55E-01



7.94E-03


TeCDF Total
1.58E-01



1.67E-03


PeCDF Total
5.80E-02



6.10E-04


HxCDF Total
3.45E-02



3.63E-04


HpCDF Total
3.34E-02



3.51 E-04


OCDF
1.52E-02



1.60E-04


PCDD Total
1.55E+00



1.63E-02


PCDF Total
2.99E-01



3.15E-03


PCDD/PCDF Total
1.85E+00



1.95E-02


PCDD TEQ Total


2.29E-02
2.29E-02

2.41 E-04
2.41 E-04
PCDF TEQ Total


4.68E-03
4.68E-03

4.92E-05
4.92E-05
PCDD/PCDF TEQ Total


2.76E-02
2.76E-02

2.90E-04
2.90E-04
Sam pie ID	PS-PCDD-NSB2-SVOC-121114-01	Page 2(2)
11-A

-------

EF
EF
EF
EF
EF
EF

Total
TEQ
TEQ
Total
TEQ
TEQ
Isomer.

ng/g Carbon


ng/kg fiberboard



ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
3.25E-05
3.25E-05
3.25E-05
1.48E-02
1.48E-02
1.48E-02
1,2,3,7,8- PeCDD
1.68E-04
1.68E-04
1.68E-04
7.68E-02
7.68E-02
7.68E-02
1,2,3,4,7,8- HxCDD
8.27E-05
8.27E-06
8.27E-06
3.77E-02
3.77E-03
3.77E-03
1,2,3,6,7,8- HxCDD
3.10E-04
3.10E-05
3.10E-05
1.41 E-01
1.41 E-02
1.41 E-02
1,2,3,7,8,9- HxCDD
2.27E-04
2.27E-05
2.27E-05
1.04E-01
1.04E-02
1.04E-02
1,2,3,4,6,7,8- HpCDD
3.83E-03
3.83E-05
3.83E-05
1.75E+00
1.75E-02
1.75E-02
1,2,3,4,6,7,8,9 - OCDD
1.00E-02
3.01 E-06
3.01 E-06
4.57E+00
1.37E-03
1.37E-03
2,3,7,8 - TCDF
1.57E-04
1.57E-05
1.57E-05
7.14E-02
7.14E-03
7.14E-03
1,2,3,7,8- PeCDF
5.32E-05
1.59E-06
1.59E-06
2.42E-02
7.27E-04
7.27E-04
2,3,4,7,8- PeCDF
8.27E-05
2.48E-05
2.48E-05
3.77E-02
1.13E-02
1.13E-02
1,2,3,4,7,8- HxCDF
5.91 E-05
5.91 E-06
5.91 E-06
2.69E-02
2.69E-03
2.69E-03
1,2,3,6,7,8- HxCDF
4.43E-05
4.43E-06
4.43E-06
2.02E-02
2.02E-03
2.02E-03
1,2,3,7,8,9- HxCDF
177E-05
1.77E-06
1.77E-06
8.08E-03
8.08E-04
8.08E-04
2,3,4,6,7,8 - HxCDF
5.91 E-05
5.91 E-06
5.91 E-06
2.69E-02
2.69E-03
2.69E-03
1,2,3,4,6,7,8- HpCDF
1.68E-04
1.68E-06
1.68E-06
7.68E-02
7.68E-04
7.68E-04
1,2,3,4,7,8,9- HpCDF
3.54E-05
3.54E-07
3.54E-07
1.62E-02
1.62E-04
1.62E-04
1,2,3,4,6,7,8,9-OCDF
2.04E-04
6.11E-08
6.11E-08
9.29E-02
2.79E-05
2.79E-05
TeCDD Total
1.07E-03


4.90E-01


PeCDD Total
1.01E-03


4.58E-01


HxCDD Total
2.30E-03


1.05E+00


HpCDD Total
6.18E-03


2.82E+00


OCDD
1.00E-02


4.57E+00


TeCDF Total
2.11 E-03


9.60E-01


PeCDF Total
7.70E-04


3.51 E-01


HxCDF Total
4.59E-04


2.09E-01


HpCDF Total
4.43E-04


2.02E-01


OCDF
2.02E-04


9.23E-02


PCDD Total
2.06E-02


9.39E+00


PCDF Total
3.98E-03


1.82E+00


PCDD/PCDF Total
2.46E-02


1.12E+01


PCDD TEQ Total

3.04E-04
3.04E-04

1.39E-01
1.39E-01
PCDF TEQ Total

6.22E-05
6.22E-05

2.84E-02
2.84E-02
PCDD/PCDF TEQ Total

3.66E-04
3.66E-04

1.67E-01
1.67E-01
Table A-7. PCDD/PCDF data for NSB/NSL 3.
PCDD/PCDF	Page
12-A

-------
Sample ID	PS-PCDD-NSB3-SVOC-121714-01	MCE 0.978
Sampling volume (m3)	58.8
Carbon sampled (g)	57.7
Carbon sampled (mg/m3)	980.8
Carbon fraction	0.4561



TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total
LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ng/sample
ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 -TCDD
1.56E-03

1.56E-03
1.56E-03
2.65E-05
2.65E-05
2.65E-05
1,2,3,7,8 -PeCDD
3.78E-03

3.78E-03
3.78E-03
6.43E-05
6.43E-05
6.43E-05
1,2,3,4,7,8 -HxCDD
2.44E-03

2.44E-04
2.44E-04
4.16E-05
4.16E-06
4.16E-06
1,2,3,6,7,8 -HxCDD
9.33E-03

9.33E-04
9.33E-04
1.59E-04
1.59E-05
1.59E-05
1,2,3,7,8,9-HxCDD
6.67E-03

6.67E-04
6.67E-04
1.13E-04
1.13E-05
1.13E-05
1,2,3,4,6,7,8- HpCDD
1.32E-01

1.32E-03
1.32E-03
2.25E-03
2.25E-05
2.25E-05
1,2,3,4,6,7,8,9 - OCDD
3.58E-01

1.07E-04
1.07E-04
6.09E-03
1.83E-06
1.83E-06
2,3,7,8 -TCDF
7.11E-03

7.11E-04
7.11E-04
1.21E-04
1.21 E-05
1.21 E-05
1,2,3,7,8-PeCDF
2.89E-03

8.67E-05
8.67E-05
4.91 E-05
1.47E-06
1.47E-06
2,3,4,7,8 - PeCDF
3.56E-03

1.07E-03
1.07E-03
6.05E-05
1.81 E-05
1.81 E-05
1,2,3,4,7,8-HxCDF
2.44E-03

2.44E-04
2.44E-04
4.16E-05
4.16E-06
4.16E-06
1,2,3,6,7,8-HxCDF
1.78E-03

1.78E-04
1.78E-04
3.02E-05
3.02E-06
3.02E-06
1,2,3,7,8,9-HxCDF
8.89E-04

8.89E-05
8.89E-05
1.51 E-05
1.51 E-06
1.51 E-06
2,3,4,6,7,8 - HxCDF
2.22E-03

2.22E-04
2.22E-04
3.78E-05
3.78E-06
3.78E-06
1,2,3,4,6,7,8- HpCDF
6.67E-03

6.67E-05
6.67E-05
1.13E-04
1.13E-06
1.13E-06
1,2,3,4,7,8,9- HpCDF
1.78E-03

1.78E-05
1.78E-05
3.02E-05
3.02E-07
3.02E-07
1,2,3,4,6,7,8,9-OCDF
8.00E-03

2.40E-06
2.40E-06
1.36E-04
4.08E-08
4.08E-08
TeCDD Total
4.51 E-02



7.67E-04


PeCDD Total
3.84E-02



6.53E-04


HxCDD Total
7.48E-02



1.27E-03


HpCDD Total
2.11E-01



3.59E-03


OCDD
3.58E-01



6.09E-03


TeCDF Total
1.14E-01



1.94E-03


PeCDF Total
4.00E-02



6.80E-04


HxCDF Total
2.21 E-02



3.76E-04


HpCDF Total
1.68E-02



2.87E-04


OCDF
8.02E-03



1.36E-04


PCDD Total
7.27E-01



1.24E-02


PCDF Total
2.01 E-01



3.41 E-03


PCDD/PCDF Total
9.28E-01



1.58E-02


PCDD TEQ Total


8.61 E-03
8.61 E-03

1.46E-04
1.46E-04
PCDF TEQ Total


2.68E-03
2.68E-03

4.57E-05
4.57E-05
PCDD/PCDF TEQ Total


1.13E-02
1.13E-02

1.92E-04
1.92E-04
805
Sample ID	PS-PCDD-NSB3-SVOC-121714-01	Page 2 (2)
13-A

-------

EF
EF
EF
EF
EF
EF

Total
TEQ
TEQ
Total
TEQ
TEQ
Isomer.

ng/g Carbon

ng/kg fiberboard


ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
2.70E-05
2.70E-05
2.70E-05
1.23E-02
1.23E-02
1.23E-02
1,2,3,7,8- PeCDD
6.55E-05
6.55E-05
6.55E-05
2.99E-02
2.99E-02
2.99E-02
1,2,3,4,7,8- HxCDD
4.24E-05
4.24E-06
4.24E-06
1.93E-02
1.93E-03
1.93E-03
1,2,3,6,7,8- HxCDD
1.62E-04
1.62E-05
1.62E-05
7.38E-02
7.38E-03
7.38E-03
1,2,3,7,8,9- HxCDD
1.16E-04
1.16E-05
1.16E-05
5.27E-02
5.27E-03
5.27E-03
1,2,3,4,6,7,8- HpCDD
2.29E-03
2.29E-05
2.29E-05
1.04E+00
1.04E-02
1.04E-02
1,2,3,4,6,7,8,9 - OCDD
6.21 E-03
1.86E-06
1.86E-06
2.83E+00
8.50E-04
8.50E-04
2,3,7,8 - TCDF
1.23E-04
1.23E-05
1.23E-05
5.62E-02
5.62E-03
5.62E-03
1,2,3,7,8- PeCDF
5.01 E-05
1.50E-06
1.50E-06
2.29E-02
6.86E-04
6.86E-04
2,3,4,7,8- PeCDF
6.17E-05
1.85E-05
1.85E-05
2.81 E-02
8.44E-03
8.44E-03
1,2,3,4,7,8- HxCDF
4.24E-05
4.24E-06
4.24E-06
1.93E-02
1.93E-03
1.93E-03
1,2,3,6,7,8- HxCDF
3.08E-05
3.08E-06
3.08E-06
1.41 E-02
1.41 E-03
1.41 E-03
1,2,3,7,8,9- HxCDF
1.54E-05
1.54E-06
1.54E-06
7.03E-03
7.03E-04
7.03E-04
2,3,4,6,7,8 - HxCDF
3.85E-05
3.85E-06
3.85E-06
1.76E-02
1.76E-03
1.76E-03
1,2,3,4,6,7,8- HpCDF
1.16E-04
1.16E-06
1.16E-06
5.27E-02
5.27E-04
5.27E-04
1,2,3,4,7,8,9- HpCDF
3.08E-05
3.08E-07
3.08E-07
1.41 E-02
1.41 E-04
1.41 E-04
1,2,3,4,6,7,8,9-OCDF
1.39E-04
4.16E-08
4.16E-08
6.33E-02
1.90E-05
1.90E-05
TeCDD Total
7.82E-04


3.56E-01


PeCDD Total
6.66E-04


3.04E-01


HxCDD Total
1.30E-03


5.91 E-01


HpCDD Total
3.66E-03


1.67E+00


OCDD
6.21 E-03


2.83E+00


TeCDF Total
1.97E-03


9.00E-01


PeCDF Total
6.93E-04


3.16E-01


HxCDF Total
3.83E-04


1.75E-01


HpCDF Total
2.92E-04


1.33E-01


OCDF
1.39E-04


6.35E-02


PCDD Total
1.26E-02


5.75E+00


PCDF Total
3.48E-03


1.59E+00


PCDD/PCDF Total
1.61 E-02


7.34E+00


PCDD TEQ Total

1.49E-04
1.49E-04

6.81 E-02
6.81 E-02
PCDF TEQ Total

4.66E-05
4.66E-05

2.12E-02
2.12E-02
PCDD/PCDF TEQ Total

1.96E-04
1.96E-04

8.93E-02
8.93E-02
Table A-8. PCDD/PCDF data for NSB/NSL 4.
PCDD/PCDF	Page 1 (2)
14-A

-------
Sample ID	PS-PCDD-NSB4-SVOC-121714-02	MCE 0.981
Sampling volume (m3)	63.7
Carbon sampled (g)	77.2
Carbon sampled (mg/m3)	1212.2
Carbon fraction	0.4561



TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total
LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ng/sample
ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 -TCDD
1.78E-03

1.78E-03
1.78E-03
2.79E-05
2.79E-05
2.79E-05
1,2,3,7,8 -PeCDD
8.22E-03

8.22E-03
8.22E-03
1.29E-04
1.29E-04
1.29E-04
1,2,3,4,7,8 -HxCDD
4.44E-03

4.44E-04
4.44E-04
6.98E-05
6.98E-06
6.98E-06
1,2,3,6,7,8 -HxCDD
1.58E-02

1.58E-03
1.58E-03
2.48E-04
2.48E-05
2.48E-05
1,2,3,7,8,9-HxCDD
1.16E-02

1.16E-03
1.16E-03
1.81 E-04
1.81E-05
1.81 E-05
1,2,3,4,6,7,8- HpCDD
1.95E-01

1.95E-03
1.95E-03
3.07E-03
3.07E-05
3.07E-05
1,2,3,4,6,7,8,9 - OCDD
5.51 E-01

1.65E-04
1.65E-04
8.65E-03
2.59E-06
2.59E-06
2,3,7,8 -TCDF
1.22E-02

1.22E-03
1.22E-03
1.92E-04
1.92E-05
1.92E-05
1,2,3,7,8-PeCDF
4.89E-03

1.47E-04
1.47E-04
7.67E-05
2.30E-06
2.30E-06
2,3,4,7,8 - PeCDF
5.56E-03

1.67E-03
1.67E-03
8.72E-05
2.62E-05
2.62E-05
1,2,3,4,7,8-HxCDF
4.44E-03

4.44E-04
4.44E-04
6.98E-05
6.98E-06
6.98E-06
1,2,3,6,7,8-HxCDF
3.11E-03

3.11E-04
3.11E-04
4.88E-05
4.88E-06
4.88E-06
1,2,3,7,8,9-HxCDF
1.11E-03

1.11E-04
1.11E-04
1.74E-05
1.74E-06
1.74E-06
2,3,4,6,7,8 - HxCDF
3.56E-03

3.56E-04
3.56E-04
5.58E-05
5.58E-06
5.58E-06
1,2,3,4,6,7,8- HpCDF
1.04E-02

1.04E-04
1.04E-04
1.64E-04
1.64E-06
1.64E-06
1,2,3,4,7,8,9- HpCDF
1.56E-03

1.56E-05
1.56E-05
2.44E-05
2.44E-07
2.44E-07
1,2,3,4,6,7,8,9-OCDF
1.22E-02

3.67E-06
3.67E-06
1.92E-04
5.75E-08
5.75E-08
TeCDD Total
8.37E-02



1.31 E-03


PeCDD Total
6.83E-02



1.07E-03


HxCDD Total
1.23E-01



1.93E-03


HpCDD Total
3.22E-01



5.05E-03


OCDD
5.51 E-01



8.65E-03


TeCDF Total
1.88E-01



2.95E-03


PeCDF Total
7.37E-02



1.16E-03


HxCDF Total
3.96E-02



6.21 E-04


HpCDF Total
2.58E-02



4.05E-04


OCDF
1.23E-02



1.93E-04


PCDD Total
1.15E+00



1.80E-02


PCDF Total
3.39E-01



5.33E-03


PCDD/PCDF Total
1.49E+00



2.33E-02


PCDD TEQ Total


1.53E-02
1.53E-02

2.40E-04
2.40E-04
PCDF TEQ Total


4.38E-03
4.38E-03

6.88E-05
6.88E-05
PCDD/PCDF TEQ Total


1.97E-02
1.97E-02

3.09E-04
3.09E-04
Sample ID	PS-PCDD-NSB4-SVOC-121714-02	Page 2 (2)
15-A

-------

EF
EF
EF
EF
EF
EF

Total
TEQ
TEQ
Total
TEQ
TEQ
Isomer.

ng/g Carbon


ng/kg fiberboard



ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
2.30E-05
2.30E-05
2.30E-05
1.05E-02
1.05E-02
1.05E-02
1,2,3,7,8- PeCDD
1.06E-04
1.06E-04
1.06E-04
4.85E-02
4.85E-02
4.85E-02
1,2,3,4,7,8- HxCDD
5.75E-05
5.75E-06
5.75E-06
2.62E-02
2.62E-03
2.62E-03
1,2,3,6,7,8- HxCDD
2.04E-04
2.04E-05
2.04E-05
9.32E-02
9.32E-03
9.32E-03
1,2,3,7,8,9- HxCDD
1.50E-04
1.50E-05
1.50E-05
6.82E-02
6.82E-03
6.82E-03
1,2,3,4,6,7,8- HpCDD
2.53E-03
2.53E-05
2.53E-05
1.15E+00
1.15E-02
1.15E-02
1,2,3,4,6,7,8,9 - OCDD
7.14E-03
2.14E-06
2.14E-06
3.25E+00
9.76E-04
9.76E-04
2,3,7,8 - TCDF
1.58E-04
1.58E-05
1.58E-05
7.22E-02
7.22E-03
7.22E-03
1,2,3,7,8- PeCDF
6.33E-05
1.90E-06
1.90E-06
2.89E-02
8.66E-04
8.66E-04
2,3,4,7,8- PeCDF
7.19E-05
2.16E-05
2.16E-05
3.28E-02
9.84E-03
9.84E-03
1,2,3,4,7,8- HxCDF
5.75E-05
5.75E-06
5.75E-06
2.62E-02
2.62E-03
2.62E-03
1,2,3,6,7,8- HxCDF
4.03E-05
4.03E-06
4.03E-06
1.84E-02
1.84E-03
1.84E-03
1,2,3,7,8,9- HxCDF
1.44E-05
1.44E-06
1.44E-06
6.56E-03
6.56E-04
6.56E-04
2,3,4,6,7,8 - HxCDF
4.60E-05
4.60E-06
4.60E-06
2.10E-02
2.10E-03
2.10E-03
1,2,3,4,6,7,8- HpCDF
1.35E-04
1.35E-06
1.35E-06
6.17E-02
6.17E-04
6.17E-04
1,2,3,4,7,8,9- HpCDF
2.01 E-05
2.01 E-07
2.01 E-07
9.18E-03
9.18E-05
9.18E-05
1,2,3,4,6,7,8,9-OCDF
1.58E-04
4.75E-08
4.75E-08
7.22E-02
2.17E-05
2.17E-05
TeCDD Total
1.08E-03


4.94E-01


PeCDD Total
8.84E-04


4.03E-01


HxCDD Total
1.59E-03


7.25E-01


HpCDD Total
4.16E-03


1.90E+00


OCDD
7.13E-03


3.25E+00


TeCDF Total
2.43E-03


1.11E+00


PeCDF Total
9.55E-04


4.35E-01


HxCDF Total
5.12E-04


2.34E-01


HpCDF Total
3.34E-04


1.52E-01


OCDF
1.59E-04


7.24E-02


PCDD Total
1.49E-02


6.77E+00


PCDF Total
4.39E-03


2.00E+00


PCDD/PCDF Total
1.92E-02


8.78E+00


PCDD TEQ Total

1.98E-04
1.98E-04

9.03E-02
9.03E-02
PCDF TEQ Total

5.67E-05
5.67E-05

2.59E-02
2.59E-02
PCDD/PCDF TEQ Total

2.55E-04
2.55E-04

1.16E-01
1.16E-01
Table A-9. PCDD/PCDF data for NWS 1.
PCDD/PCDF	Page 1 (2)
16-A

-------
Sample ID	PS-PCDD-NWS-SVOC-111714-01	MCE 0.974
Sampling volume (m3)	85.4
Carbon sampled (g)	46.8
Carbon sampled (mg/m3)	547.9
Carbon fraction	0.4656



TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total
LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ng/sample
ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
ND
9.78E-04
0.00E+00
9.78E-04
ND
0.00E+00
1.15E-05
1,2,3,7,8- PeCDD
2.00E-03

2.00E-03
2.00E-03
2.34E-05
2.34E-05
2.34E-05
1,2,3,4,7,8- HxCDD
1.33E-03

1.33E-04
1.33E-04
1.56E-05
1.56E-06
1.56E-06
1,2,3,6,7,8- HxCDD
2.67E-03

2.67E-04
2.67E-04
3.12E-05
3.12E-06
3.12E-06
1,2,3,7,8,9- HxCDD
2.00E-03

2.00E-04
2.00E-04
2.34E-05
2.34E-06
2.34E-06
1,2,3,4,6,7,8- HpCDD
2.11E-02

2.11E-04
2.11E-04
2.47E-04
2.47E-06
2.47E-06
1,2,3,4,6,7,8,9 - OCDD
5.47E-02

1.64E-05
1.64E-05
6.40E-04
1.92E-07
1.92E-07
2,3,7,8 -TCDF
1.29E-02

1.29E-03
1.29E-03
1.51E-04
1.51 E-05
1.51 E-05
1,2,3,7,8- PeCDF
4.67E-03

1.40E-04
1.40E-04
5.47E-05
1.64E-06
1.64E-06
2,3,4,7,8- PeCDF
6.00E-03

1.80E-03
1.80E-03
7.03E-05
2.11 E-05
2.11 E-05
1,2,3,4,7,8- HxCDF
6.00E-03

6.00E-04
6.00E-04
7.03E-05
7.03E-06
7.03E-06
1,2,3,6,7,8- HxCDF
5.11E-03

5.11E-04
5.11E-04
5.99E-05
5.99E-06
5.99E-06
1,2,3,7,8,9- HxCDF
3.33E-03

3.33E-04
3.33E-04
3.91 E-05
3.91 E-06
3.91 E-06
2,3,4,6,7,8 - HxCDF
7.11E-03

7.11E-04
7.11E-04
8.33E-05
8.33E-06
8.33E-06
1,2,3,4,6,7,8- HpCDF
1.60E-02

1.60E-04
1.60E-04
1.87E-04
1.87E-06
1.87E-06
1,2,3,4,7,8,9- HpCDF
2.67E-03

2.67E-05
2.67E-05
3.12E-05
3.12E-07
3.12E-07
1,2,3,4,6,7,8,9-OCDF
9.11E-03

2.73E-06
2.73E-06
1.07E-04
3.20E-08
3.20E-08
TeCDD Total
5.67E-02



6.64E-04


PeCDD Total
2.49E-02



2.92E-04


HxCDD Total
1.89E-02



2.21 E-04


HpCDD Total
3.74E-02



4.38E-04


OCDD
5.48E-02



6.42E-04


TeCDF Total
1.65E-01



1.93E-03


PeCDF Total
5.84E-02



6.84E-04


HxCDF Total
5.28E-02



6.19E-04


HpCDF Total
3.14E-02



3.67E-04


OCDF
9.18E-03



1.08E-04


PCDD Total
1.93E-01



2.26E-03


PCDF Total
3.17E-01



3.71 E-03


PCDD/PCDF Total
5.09E-01



5.97E-03


PCDD TEQ Total


2.83E-03
3.81 E-03

3.31 E-05
4.46E-05
PCDF TEQ Total


5.57E-03
5.57E-03

6.53E-05
6.53E-05
PCDD/PCDF TEQ Total


8.40E-03
9.38E-03

9.84E-05
1.10E-04
Sam pie ID	PS-PCDD-NWS-SVOC-111714-01	Page 2 (2)
17-A

-------

EF
EF
EF
EF
EF
EF

Total
TEQ
TEQ
Total
TEQ
TEQ
Isomer.

ng/g Carbon


ng/kg fiberboard


ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
ND
0.00E+00
2.09E-05
ND
0.00E+00
9.74E-03
1,2,3,7,8- PeCDD
4.28E-05
4.28E-05
4.28E-05
1.99E-02
1.99E-02
1.99E-02
1,2,3,4,7,8- HxCDD
2.85E-05
2.85E-06
2.85E-06
1.33E-02
1.33E-03
1.33E-03
1,2,3,6,7,8- HxCDD
5.70E-05
5.70E-06
5.70E-06
2.66E-02
2.66E-03
2.66E-03
1,2,3,7,8,9- HxCDD
4.28E-05
4.28E-06
4.28E-06
1.99E-02
1.99E-03
1.99E-03
1,2,3,4,6,7,8- HpCDD
4.51 E-04
4.51 E-06
4.51 E-06
2.10E-01
2.10E-03
2.10E-03
1,2,3,4,6,7,8,9 - OCDD
1.17E-03
3.51 E-07
3.51 E-07
5.44E-01
1.63E-04
1.63E-04
2,3,7,8 - TCDF
2.76E-04
2.76E-05
2.76E-05
1.28E-01
1.28E-02
1.28E-02
1,2,3,7,8- PeCDF
9.98E-05
2.99E-06
2.99E-06
4.65E-02
1.39E-03
1.39E-03
2,3,4,7,8- PeCDF
1.28E-04
3.85E-05
3.85E-05
5.97E-02
1.79E-02
1.79E-02
1,2,3,4,7,8- HxCDF
1.28E-04
1.28E-05
1.28E-05
5.97E-02
5.97E-03
5.97E-03
1,2,3,6,7,8- HxCDF
1.09E-04
1.09E-05
1.09E-05
5.09E-02
5.09E-03
5.09E-03
1,2,3,7,8,9- HxCDF
7.13E-05
7.13E-06
7.13E-06
3.32E-02
3.32E-03
3.32E-03
2,3,4,6,7,8 - HxCDF
1.52E-04
1.52E-05
1.52E-05
7.08E-02
7.08E-03
7.08E-03
1,2,3,4,6,7,8- HpCDF
3.42E-04
3.42E-06
3.42E-06
1.59E-01
1.59 E-03
1.59E-03
1,2,3,4,7,8,9- HpCDF
5.70E-05
5.70E-07
5.70E-07
2.66E-02
2.66E-04
2.66E-04
1,2,3,4,6,7,8,9-OCDF
1.95E-04
5.84E-08
5.84E-08
9.07E-02
2.72E-05
2.72E-05
TeCDD Total
1.21 E-03


5.64E-01


PeCDD Total
5.33E-04


2.48E-01


HxCDD Total
4.04E-04


1.88E-01


HpCDD Total
7.99E-04


3.72E-01


OCDD
1.17E-03


5.45E-01


TeCDF Total
3.52E-03


1.64E+00


PeCDF Total
1.25E-03


5.82E-01


HxCDF Total
1.13E-03


5.26E-01


HpCDF Total
6.70E-04


3.12E-01


OCDF
1.96E-04


9.14E-02


PCDD Total
4.12E-03


1.92E+00


PCDF Total
6.77E-03


3.15E+00


PCDD/PCDF Total
1.09E-02


5.07E+00


PCDD TEQ Total

6.05E-05
8.14E-05

2.82E-02
3.79E-02
PCDF TEQ Total

1.19E-04
1.19E-04

5.55E-02
5.55E-02
PCDD/PCDF TEQ Total

1.80E-04
2.01 E-04

8.36E-02
9.34E-02
810 Table A-10. PCDD/PCDF data for NWS 2.
PCDD/PCDF	Page 1 (2)
18-A

-------
Sample ID	PS-PCDD-NWS2-SV0C-11182104-01	MCE 0.989
Sampling volume (m3)	55.6
Carbon sampled (g)	37.0
Carbon sampled (mg/m3)	665.6
Carbon fraction	0.4656



TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total
LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ng/sample
ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
6.00E-04

6.00E-04
6.00E-04
1.08E-05
1.08E-05
1.08E-05
1,2,3,7,8- PeCDD
2.00E-03

2.00E-03
2.00E-03
3.60E-05
3.60E-05
3.60E-05
1,2,3,4,7,8- HxCDD
1.20E-03

1.20E-04
1.20E-04
2.16E-05
2.16E-06
2.16E-06
1,2,3,6,7,8- HxCDD
1.40E-03

1.40E-04
1.40E-04
2.52E-05
2.52E-06
2.52E-06
1,2,3,7,8,9- HxCDD
1.40E-03

1.40E-04
1.40E-04
2.52E-05
2.52E-06
2.52E-06
1,2,3,4,6,7,8- HpCDD
1.44E-02

1.44E-04
1.44E-04
2.59E-04
2.59E-06
2.59E-06
1,2,3,4,6,7,8,9 - OCDD
4.00E-02

1.20E-05
1.20E-05
7.19E-04
2.16E-07
2.16E-07
2,3,7,8 - TCDF
1.04E-02

1.04E-03
1.04E-03
1.87E-04
1.87E-05
1.87E-05
1,2,3,7,8- PeCDF
8.00E-03

2.40E-04
2.40E-04
1.44E-04
4.32E-06
4.32E-06
2,3,4,7,8- PeCDF
1.02E-02

3.06E-03
3.06E-03
1.83E-04
5.50E-05
5.50E-05
1,2,3,4,7,8- HxCDF
8.20E-03

8.20E-04
8.20E-04
1.47E-04
1.47E-05
1.47E-05
1,2,3,6,7,8- HxCDF
8.00E-03

8.00E-04
8.00E-04
1.44E-04
1.44E-05
1.44E-05
1,2,3,7,8,9- HxCDF
2.60E-03

2.60E-04
2.60E-04
4.68E-05
4.68E-06
4.68E-06
2,3,4,6,7,8 - HxCDF
7.00E-03

7.00E-04
7.00E-04
1.26E-04
1.26E-05
1.26E-05
1,2,3,4,6,7,8- HpCDF
1.46E-02

1.46E-04
1.46E-04
2.63E-04
2.63E-06
2.63E-06
1,2,3,4,7,8,9- HpCDF
3.60E-03

3.60E-05
3.60E-05
6.47E-05
6.47E-07
6.47E-07
1,2,3,4,6,7,8,9-OCDF
1.00E-02

3.00E-06
3.00E-06
1.80E-04
5.39E-08
5.39E-08
TeCDD Total
2.97E-02



5.33E-04


PeCDD Total
1.36E-02



2.45E-04


HxCDD Total
1.62E-02



2.92E-04


HpCDD Total
2.55E-02



4.58E-04


OCDD
4.00E-02



7.19E-04


TeCDF Total
2.44E-01



4.38E-03


PeCDF Total
1.14E-01



2.05E-03


HxCDF Total
6.70E-02



1.21 E-03


HpCDF Total
3.07E-02



5.51 E-04


OCDF
9.92E-03



1.78E-04


PCDD Total
1.25E-01



2.25E-03


PCDF Total
4.65E-01



8.36E-03


PCDD/PCDF Total
5.90E-01



1.06E-02


PCDD TEQ Total


3.16E-03
3.16E-03

5.68E-05
5.68E-05
PCDF TEQ Total


7.11 E-03
7.11 E-03

1.28E-04
1.28E-04
PCDD/PCDF TEQ Total


1.03E-02
1.03E-02

1.85E-04
1.85E-04
Sample ID	PS-PCDD-NWS2-SVOC-11182104-01	Page 2 (2)
19-A

-------

EF
EF
EF
EF
EF
EF

Total
TEQ
TEQ
Total
TEQ
TEQ
Isomer.

ng/g Carbon

ng/kg fiberboard


ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
1.62E-05
1.62E-05
1.62E-05
7.55E-03
7.55E-03
7.55E-03
1,2,3,7,8- PeCDD
5.40E-05
5.40E-05
5.40E-05
2.52E-02
2.52E-02
2.52E-02
1,2,3,4,7,8- HxCDD
3.24E-05
3.24E-06
3.24E-06
1.51 E-02
1.51 E-03
1.51 E-03
1,2,3,6,7,8- HxCDD
3.78E-05
3.78E-06
3.78E-06
1.76E-02
1.76E-03
1.76E-03
1,2,3,7,8,9- HxCDD
3.78E-05
3.78E-06
3.78E-06
1.76E-02
1.76E-03
1.76E-03
1,2,3,4,6,7,8- HpCDD
3.89E-04
3.89E-06
3.89E-06
1.81 E-01
1.81 E-03
1.81 E-03
1,2,3,4,6,7,8,9 - OCDD
1.08E-03
3.24E-07
3.24E-07
5.03E-01
1.51 E-04
1.51 E-04
2,3,7,8 - TCDF
2.81 E-04
2.81 E-05
2.81 E-05
1.31 E-01
1.31 E-02
1.31 E-02
1,2,3,7,8- PeCDF
2.16E-04
6.48E-06
6.48E-06
1.01 E-01
3.02E-03
3.02E-03
2,3,4,7,8- PeCDF
2.76E-04
8.27E-05
8.27E-05
1.28E-01
3.85E-02
3.85E-02
1,2,3,4,7,8- HxCDF
2.22E-04
2.22E-05
2.22E-05
1.03E-01
1.03E-02
1.03E-02
1,2,3,6,7,8- HxCDF
2.16E-04
2.16E-05
2.16E-05
1.01 E-01
1.01 E-02
1.01 E-02
1,2,3,7,8,9- HxCDF
7.02E-05
7.02E-06
7.02E-06
3.27E-02
3.27E-03
3.27E-03
2,3,4,6,7,8 - HxCDF
1.89E-04
1.89E-05
1.89E-05
8.81 E-02
8.81 E-03
8.81 E-03
1,2,3,4,6,7,8- HpCDF
3.94E-04
3.94E-06
3.94E-06
1.84E-01
1.84E-03
1.84E-03
1,2,3,4,7,8,9- HpCDF
9.73E-05
9.73E-07
9.73E-07
4.53E-02
4.53E-04
4.53E-04
1,2,3,4,6,7,8,9-OCDF
2.70E-04
8.10E-08
8.10E-08
1.26E-01
3.77E-05
3.77E-05
TeCDD Total
8.01 E-04


3.73E-01


PeCDD Total
3.68E-04


1.71 E-01


HxCDD Total
4.39E-04


2.04E-01


HpCDD Total
6.88E-04


3.21 E-01


OCDD
1.08E-03


5.03E-01


TeCDF Total
6.58E-03


3.06E+00


PeCDF Total
3.08E-03


1.43E+00


HxCDF Total
1.81 E-03


8.43E-01


HpCDF Total
8.28E-04


3.86E-01


OCDF
2.68E-04


1.25E-01


PCDD Total
3.38E-03


1.57E+00


PCDF Total
1.26E-02


5.85E+00


PCDD/PCDF Total
1.59E-02


7.42E+00


PCDD TEQ Total

8.53E-05
8.53E-05

3.97E-02
3.97E-02
PCDF TEQ Total

1.92E-04
1.92E-04

8.94E-02
8.94E-02
PCDD/PCDF TEQ Total

2.77E-04
2.77E-04

1.29E-01
1.29E-01
Table A-ll. PCDD/PCDF data for NWS 3.
PCDD/PCDF	Page 1 (2)
20-A

-------
Sample ID	PS-PCDD-NWS3-SV0C-120814-01	MCE 0.982
Sampling volume (m3)	95.7
Carbon sampled (g)	68.1
Carbon sampled (mg/m3)	711.2
Carbon fraction	0.4656



TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total
LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ng/sample
ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
6.67E-04

6.67E-04
6.67E-04
6.96E-06
6.96E-06
6.96E-06
1,2,3,7,8- PeCDD
1.33E-03

1.33E-03
1.33E-03
1.39E-05
1.39E-05
1.39E-05
1,2,3,4,7,8- HxCDD
1.11E-03

1.11E-04
1.11E-04
1.16E-05
1.16E-06
1.16E-06
1,2,3,6,7,8- HxCDD
2.44E-03

2.44E-04
2.44E-04
2.55E-05
2.55E-06
2.55E-06
1,2,3,7,8,9- HxCDD
1.78E-03

1.78E-04
1.78E-04
1.86E-05
1.86E-06
1.86E-06
1,2,3,4,6,7,8- HpCDD
2.29E-02

2.29E-04
2.29E-04
2.39E-04
2.39E-06
2.39E-06
1,2,3,4,6,7,8,9 - OCDD
5.64E-02

1.69E-05
1.69E-05
5.90E-04
1.77E-07
1.77E-07
2,3,7,8 - TCDF
7.56E-03

7.56E-04
7.56E-04
7.89E-05
7.89E-06
7.89E-06
1,2,3,7,8- PeCDF
2.67E-03

8.00E-05
8.00E-05
2.79E-05
8.36E-07
8.36E-07
2,3,4,7,8- PeCDF
6.00E-03

1.80E-03
1.80E-03
6.27E-05
1.88E-05
1.88E-05
1,2,3,4,7,8- HxCDF
4.44E-03

4.44E-04
4.44E-04
4.64E-05
4.64E-06
4.64E-06
1,2,3,6,7,8- HxCDF
3.78E-03

3.78E-04
3.78E-04
3.95E-05
3.95E-06
3.95E-06
1,2,3,7,8,9- HxCDF
2.22E-03

2.22E-04
2.22E-04
2.32E-05
2.32E-06
2.32E-06
2,3,4,6,7,8 - HxCDF
5.33E-03

5.33E-04
5.33E-04
5.57E-05
5.57E-06
5.57E-06
1,2,3,4,6,7,8- HpCDF
1.16E-02

1.16E-04
1.16E-04
1.21 E-04
1.21 E-06
1.21 E-06
1,2,3,4,7,8,9- HpCDF
2.00E-03

2.00E-05
2.00E-05
2.09E-05
2.09E-07
2.09E-07
1,2,3,4,6,7,8,9-OCDF
7.78E-03

2.33E-06
2.33E-06
8.13E-05
2.44E-08
2.44E-08
TeCDD Total
4.03E-02



4.21 E-04


PeCDD Total
2.98E-02



3.11 E-04


HxCDD Total
2.73E-02



2.85E-04


HpCDD Total
3.99E-02



4.17E-04


OCDD
5.64E-02



5.89E-04


TeCDF Total
1.08E-01



1.12E-03


PeCDF Total
4.52E-02



4.72E-04


HxCDF Total
3.85E-02



4.03E-04


HpCDF Total
2.24E-02



2.34E-04


OCDF
7.80E-03



8.15E-05


PCDD Total
1.94E-01



2.02E-03


PCDF Total
2.22E-01



2.32E-03


PCDD/PCDF Total
4.15E-01



4.34E-03


PCDD TEQ Total


2.78E-03
2.78E-03

2.90E-05
2.90E-05
PCDF TEQ Total


4.35E-03
4.35E-03

4.55E-05
4.55E-05
PCDD/PCDF TEQ Total


7.13E-03
7.13E-03

7.45E-05
7.45E-05
Sample ID	PS-PCDD-NWS3-SVOC-120814-01	Page 2 (2)
21-A

-------

EF
EF
EF
EF
EF
EF

Total
TEQ
TEQ
Total
TEQ
TEQ
Isomer.

ng/g Carbon

ng/kg fiberboard


ND=0
ND=LOD

ND=0
ND=LOD
2,3,7,8 - TCDD
9.79E-06
9.79E-06
9.79E-06
4.56E-03
4.56E-03
4.56E-03
1,2,3,7,8- PeCDD
1.96E-05
1.96E-05
1.96E-05
9.12E-03
9.12E-03
9.12E-03
1,2,3,4,7,8- HxCDD
1.63E-05
1.63E-06
1.63E-06
7.60E-03
7.60E-04
7.60E-04
1,2,3,6,7,8- HxCDD
3.59E-05
3.59E-06
3.59E-06
1.67E-02
1.67E-03
1.67E-03
1,2,3,7,8,9- HxCDD
2.61 E-05
2.61 E-06
2.61 E-06
1.22E-02
1.22E-03
1.22E-03
1,2,3,4,6,7,8- HpCDD
3.36E-04
3.36E-06
3.36E-06
1.57E-01
1.57E-03
1.57E-03
1,2,3,4,6,7,8,9 - OCDD
8.29E-04
2.49E-07
2.49E-07
3.86E-01
1.16E-04
1.16E-04
2,3,7,8 - TCDF
1.11E-04
1.11 E-05
1.11 E-05
5.17E-02
5.17E-03
5.17E-03
1,2,3,7,8- PeCDF
3.92E-05
1.18E-06
1.18E-06
1.82E-02
5.47E-04
5.47E-04
2,3,4,7,8- PeCDF
8.81 E-05
2.64E-05
2.64E-05
4.10E-02
1.23E-02
1.23E-02
1,2,3,4,7,8- HxCDF
6.53E-05
6.53E-06
6.53E-06
3.04E-02
3.04E-03
3.04E-03
1,2,3,6,7,8- HxCDF
5.55E-05
5.55E-06
5.55E-06
2.58E-02
2.58E-03
2.58E-03
1,2,3,7,8,9- HxCDF
3.26E-05
3.26E-06
3.26E-06
1.52E-02
1.52E-03
1.52E-03
2,3,4,6,7,8 - HxCDF
7.83E-05
7.83E-06
7.83E-06
3.65E-02
3.65E-03
3.65E-03
1,2,3,4,6,7,8- HpCDF
1.70E-04
1.70E-06
1.70E-06
7.90E-02
7.90E-04
7.90E-04
1,2,3,4,7,8,9- HpCDF
2.94E-05
2.94E-07
2.94E-07
1.37E-02
1.37E-04
1.37E-04
1,2,3,4,6,7,8,9-OCDF
1.14E-04
3.43E-08
3.43E-08
5.32E-02
1.60E-05
1.60E-05
TeCDD Total
5.92E-04


2.76E-01


PeCDD Total
4.37E-04


2.04E-01


HxCDD Total
4.01 E-04


1.86E-01


HpCDD Total
5.86E-04


2.73E-01


OCDD
8.28E-04


3.86E-01


TeCDF Total
1.58E-03


7.36E-01


PeCDF Total
6.64E-04


3.09E-01


HxCDF Total
5.66E-04


2.64E-01


HpCDF Total
3.30E-04


1.53E-01


OCDF
1.15E-04


5.33E-02


PCDD Total
2.84E-03


1.32E+00


PCDF Total
3.26E-03


1.52E+00


PCDD/PCDF Total
6.10E-03


2.84E+00


PCDD TEQ Total

4.08E-05
4.08E-05

1.90E-02
1.90E-02
PCDF TEQ Total

6.39E-05
6.39E-05

2.98E-02
2.98E-02
PCDD/PCDF TEQ Total

1.05E-04
1.05E-04

4.88E-02
4.88E-02
Table A-12. PCDD/PCDF data for NWS 4.
PCDD/PCDF	Page 1 (2)
22-A

-------
Sample ID	PS-PCDD-NWS4-SVOC-121014-01	MCE 0.986
Sampling volume (m3)	52.3
Carbon sampled (g)	65.8
Carbon sampled (mg/m3)	1257.7
Carbon fraction	0.4656



TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total
LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3




ND =




ng/sample
ng/sample
ND = 0
LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
ND
5.56E-04
0.00E+00
5.56E-04
ND
0.00E+00
1.06E-05
1,2,3,7,8- PeCDD
1.56E-03

1.56E-03
1.56E-03
2.97E-05
2.97E-05
2.97E-05
1,2,3,4,7,8- HxCDD
8.89E-04

8.89E-05
8.89E-05
1.70E-05
1.70E-06
1.70E-06
1,2,3,6,7,8- HxCDD
1.11E-03

1.11E-04
1.11E-04
2.12E-05
2.12E-06
2.12E-06
1,2,3,7,8,9- HxCDD
1.56E-03

1.56E-04
1.56E-04
2.97E-05
2.97E-06
2.97E-06
1,2,3,4,6,7,8- HpCDD
1.58E-02

1.58E-04
1.58E-04
3.01 E-04
3.01 E-06
3.01 E-06
1,2,3,4,6,7,8,9 - OCDD
3.49E-02

1.05E-05
1.05E-05
6.67E-04
2.00E-07
2.00E-07
2,3,7,8 - TCDF
5.33E-03

5.33E-04
5.33E-04
1.02E-04
1.02E-05
1.02E-05
1,2,3,7,8- PeCDF
2.67E-03

8.00E-05
8.00E-05
5.09E-05
1.53E-06
1.53E-06
2,3,4,7,8- PeCDF
4.67E-03

1.40E-03
1.40E-03
8.92E-05
2.67E-05
2.67E-05
1,2,3,4,7,8- HxCDF
4.67E-03

4.67E-04
4.67E-04
8.92E-05
8.92E-06
8.92E-06
1,2,3,6,7,8- HxCDF
3.33E-03

3.33E-04
3.33E-04
6.37E-05
6.37E-06
6.37E-06
1,2,3,7,8,9- HxCDF
1.33E-03

1.33E-04
1.33E-04
2.55E-05
2.55E-06
2.55E-06
2,3,4,6,7,8 - HxCDF
5.11E-03

5.11E-04
5.11E-04
9.77E-05
9.77E-06
9.77E-06
1,2,3,4,6,7,8- HpCDF
9.78E-03

9.78E-05
9.78E-05
1.87E-04
1.87E-06
1.87E-06
1,2,3,4,7,8,9- HpCDF
1.11E-03

1.11E-05
1.11E-05
2.12E-05
2.12E-07
2.12E-07
1,2,3,4,6,7,8,9-OCDF
4.67E-03

1.40E-06
1.40E-06
8.92E-05
2.67E-08
2.67E-08
TeCDD Total
4.77E-02



9.11 E-04


PeCDD Total
2.65E-02



5.06E-04


HxCDD Total
2.34E-02



4.46E-04


HpCDD Total
2.89E-02



5.53E-04


OCDD
3.48E-02



6.65E-04


TeCDF Total
1.08E-01



2.07E-03


PeCDF Total
4.90E-02



9.36E-04


HxCDF Total
3.48E-02



6.64E-04


HpCDF Total
1.79E-02



3.42E-04


OCDF
4.69E-03



8.96E-05


PCDD Total
1.61 E-01



3.08E-03


PCDF Total
2.15E-01



4.10E-03


PCDD/PCDF Total
3.76E-01



7.18E-03


PCDD TEQ Total


2.08E-03
2.63E-03

3.97E-05
5.03E-05
PCDF TEQ Total


3.57E-03
3.57E-03

6.82E-05
6.82E-05
PCDD/PCDF TEQ Total


5.65E-03
6.20E-03

1.08E-04
1.19E-04
815
Sample ID	PS-PCDD-NWS4-SVOC-121014-01	Page 2(2)
23-A

-------

EF
EF
EF
EF
EF
EF

Total
TEQ
TEQ
Total
TEQ
TEQ
Isomer.

ng/g Carbon

ng/kg fiberboard


ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8-TCDD
ND
0.00E+00
8.44E-06
ND
0.00E+00
3.93E-03
1,2,3,7,8-PeCDD
2.36E-05
2.36E-05
2.36E-05
1.10E-02
1.10E-02
1.10E-02
1,2,3,4,7,8-HxCDD
1.35E-05
1.35E-06
1.35E-06
6.29E-03
6.29E-04
6.29E-04
1,2,3,6,7,8 -HxCDD
1.69E-05
1.69E-06
1.69E-06
7.86E-03
7.86E-04
7.86E-04
1,2,3,7,8,9-HxCDD
2.36E-05
2.36E-06
2.36E-06
1.10E-02
1.10E-03
1.10E-03
1,2,3,4,6,7,8- HpCDD
2.40E-04
2.40E-06
2.40E-06
1.12E-01
1.12E-03
1.12E-03
1,2,3,4,6,7,8,9 - OCDD
5.30E-04
1.59E-07
1.59E-07
2.47E-01
7.40E-05
7.40E-05
2,3,7,8 -TCDF
8.10E-05
8.10E-06
8.10E-06
3.77E-02
3.77E-03
3.77E-03
1,2,3,7,8-PeCDF
4.05E-05
1.22E-06
1.22E-06
1.89E-02
5.66E-04
5.66E-04
2,3,4,7,8 - PeCDF
7.09E-05
2.13E-05
2.13E-05
3.30E-02
9.90E-03
9.90E-03
1,2,3,4,7,8-HxCDF
7.09E-05
7.09E-06
7.09E-06
3.30E-02
3.30E-03
3.30E-03
1,2,3,6,7,8- HxCDF
5.06E-05
5.06E-06
5.06E-06
2.36E-02
2.36E-03
2.36E-03
1,2,3,7,8,9-HxCDF
2.03E-05
2.03E-06
2.03E-06
9.43E-03
9.43E-04
9.43E-04
2,3,4,6,7,8 - HxCDF
7.76E-05
7.76E-06
7.76E-06
3.62E-02
3.62E-03
3.62E-03
1,2,3,4,6,7,8- HpCDF
1.49E-04
1.49E-06
1.49E-06
6.92E-02
6.92E-04
6.92E-04
1,2,3,4,7,8,9- HpCDF
1.69E-05
1.69E-07
1.69E-07
7.86E-03
7.86E-05
7.86E-05
1,2,3,4,6,7,8,9-OCDF
7.09E-05
2.13E-08
2.13E-08
3.30E-02
9.90E-06
9.90E-06
TeCDD Total
7.24E-04


3.37E-01


PeCDD Total
4.02E-04


1.87E-01


HxCDD Total
3.55E-04


1.65E-01


HpCDD Total
4.40E-04


2.05E-01


OCDD
5.29E-04


2.46E-01


TeCDF Total
1.65E-03


7.67E-01


PeCDF Total
7.44E-04


3.46E-01


HxCDF Total
5.28E-04


2.46E-01


HpCDF Total
2.72E-04


1.27E-01


OCDF
7.12E-05


3.32E-02


PCDD Total
2.45E-03


1.14E+00


PCDF Total
3.26E-03


1.52E+00


PCDD/PCDF Total
5.71 E-03


2.66E+00


PCDD TEQ Total

3.16E-05
4.00E-05

1.47E-02
1.86E-02
PCDF TEQ Total

5.42E-05
5.42E-05

2.52E-02
2.52E-02
PCDD/PCDF TEQ Total

8.58E-05
9.42E-05

3.99E-02
4.39E-02
Table A-13. PCDD/PCDF data for SB/SL 1.
PCDD/PCDF	Page 1 (2)
24-A

-------
Sample ID	PS-PCDD-SB-SVOC-112014-01 MCE 0.980
Sampling volume (m3)	60.2
Carbon sampled (g)	68.1
Carbon sampled (mg/m3)	1129.9
Carbon fraction	0.45215



TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total
LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ng/sample
ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
1.56E-03

1.56E-03
1.56E-03
2.58E-05
2.58E-05
2.58E-05
1,2,3,7,8- PeCDD
7.33E-03

7.33E-03
7.33E-03
1.22E-04
1.22E-04
1.22E-04
1,2,3,4,7,8- HxCDD
4.89E-03

4.89E-04
4.89E-04
8.11E-05
8.11E-06
8.11 E-06
1,2,3,6,7,8- HxCDD
1.49E-02

1.49E-03
1.49E-03
2.47E-04
2.47E-05
2.47E-05
1,2,3,7,8,9- HxCDD
1.09E-02

1.09E-03
1.09E-03
1.81 E-04
1.81E-05
1.81 E-05
1,2,3,4,6,7,8- HpCDD
2.44E-01

2.44E-03
2.44E-03
4.05E-03
4.05E-05
4.05E-05
1,2,3,4,6,7,8,9 - OCDD
7.46E-01

2.24E-04
2.24E-04
1.24E-02
3.71 E-06
3.71 E-06
2,3,7,8 - TCDF
2.64E-02

2.64E-03
2.64E-03
4.39E-04
4.39E-05
4.39E-05
1,2,3,7,8- PeCDF
8.67E-03

2.60E-04
2.60E-04
1.44E-04
4.32E-06
4.32E-06
2,3,4,7,8- PeCDF
1.27E-02

3.80E-03
3.80E-03
2.10E-04
6.31 E-05
6.31 E-05
1,2,3,4,7,8- HxCDF
7.78E-03

7.78E-04
7.78E-04
1.29E-04
1.29E-05
1.29E-05
1,2,3,6,7,8- HxCDF
5.11E-03

5.11E-04
5.11E-04
8.48E-05
8.48E-06
8.48E-06
1,2,3,7,8,9- HxCDF
2.44E-03

2.44E-04
2.44E-04
4.06E-05
4.06E-06
4.06E-06
2,3,4,6,7,8 - HxCDF
7.78E-03

7.78E-04
7.78E-04
1.29E-04
1.29E-05
1.29E-05
1,2,3,4,6,7,8- HpCDF
1.69E-02

1.69E-04
1.69E-04
2.80E-04
2.80E-06
2.80E-06
1,2,3,4,7,8,9- HpCDF
2.89E-03

2.89E-05
2.89E-05
4.79E-05
4.79E-07
4.79E-07
1,2,3,4,6,7,8,9-OCDF
2.09E-02

6.27E-06
6.27E-06
3.47E-04
1.04E-07
1.04E-07
TeCDD Total
7.68E-02



1.28E-03


PeCDD Total
5.64E-02



9.36E-04


HxCDD Total
1.25E-01



2.08E-03


HpCDD Total
3.87E-01



6.43E-03


OCDD
7.46E-01



1.24E-02


TeCDF Total
3.20E-01



5.31 E-03


PeCDF Total
1.08E-01



1.80E-03


HxCDF Total
5.62E-02



9.32E-04


HpCDF Total
4.23E-02



7.02E-04


OCDF
2.08E-02



3.46E-04


PCDD Total
1.39E+00



2.31 E-02


PCDF Total
5.47E-01



9.09E-03


PCDD/PCDF Total
1.94E+00



3.22E-02


PCDD TEQ Total


1.46E-02
1.46E-02

2.43E-04
2.43E-04
PCDF TEQ Total


9.22E-03
9.22E-03

1.53E-04
1.53E-04
PCDD/PCDF TEQ Total


2.38E-02
2.38E-02

3.96E-04
3.96E-04
Sam pie ID	PS-PCDD-SB-SVOC-112014-01	Page 2 (2)
25-A

-------

EF
EF
EF
EF
EF
EF

Total
TEQ
TEQ
Total
TEQ
TEQ
Isomer.

ng/g Carbon


ng/kg fiberboard


ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
2.29E-05
2.29E-05
2.29E-05
1.03E-02
1.03E-02
1.03E-02
1,2,3,7,8- PeCDD
1.08E-04
1.08E-04
1.08E-04
4.87E-02
4.87E-02
4.87E-02
1,2,3,4,7,8- HxCDD
7.18E-05
7.18E-06
7.18E-06
3.25E-02
3.25E-03
3.25E-03
1,2,3,6,7,8- HxCDD
2.19E-04
2.19E-05
2.19E-05
9.89E-02
9.89E-03
9.89E-03
1,2,3,7,8,9- HxCDD
1.60E-04
1.60E-05
1.60E-05
7.23E-02
7.23E-03
7.23E-03
1,2,3,4,6,7,8- HpCDD
3.58E-03
3.58E-05
3.58E-05
1.62E+00
1.62E-02
1.62E-02
1,2,3,4,6,7,8,9 - OCDD
1.10E-02
3.29E-06
3.29E-06
4.95E+00
1.49E-03
1.49E-03
2,3,7,8 - TCDF
3.88E-04
3.88E-05
3.88E-05
1.76E-01
1.76E-02
1.76E-02
1,2,3,7,8- PeCDF
1.27E-04
3.82E-06
3.82E-06
5.76E-02
1.73E-03
1.73E-03
2,3,4,7,8- PeCDF
1.86E-04
5.58E-05
5.58E-05
8.41 E-02
2.52E-02
2.52E-02
1,2,3,4,7,8- HxCDF
1.14E-04
1.14E-05
1.14E-05
5.17E-02
5.17E-03
5.17E-03
1,2,3,6,7,8- HxCDF
7.51 E-05
7.51 E-06
7.51 E-06
3.39E-02
3.39E-03
3.39E-03
1,2,3,7,8,9- HxCDF
3.59E-05
3.59E-06
3.59E-06
1.62E-02
1.62E-03
1.62E-03
2,3,4,6,7,8 - HxCDF
1.14E-04
1.14E-05
1.14E-05
5.17E-02
5.17E-03
5.17E-03
1,2,3,4,6,7,8- HpCDF
2.48E-04
2.48E-06
2.48E-06
1.12E-01
1.12E-03
1.12E-03
1,2,3,4,7,8,9- HpCDF
4.24E-05
4.24E-07
4.24E-07
1.92E-02
1.92E-04
1.92E-04
1,2,3,4,6,7,8,9-OCDF
3.07E-04
9.21 E-08
9.21 E-08
1.39E-01
4.16E-05
4.16E-05
TeCDD Total
1.13E-03


5.10E-01


PeCDD Total
8.29E-04


3.75E-01


HxCDD Total
1.84E-03


8.32E-01


HpCDD Total
5.69E-03


2.57E+00


OCDD
1.10E-02


4.95E+00


TeCDF Total
4.70E-03


2.12E+00


PeCDF Total
1.59E-03


7.20E-01


HxCDF Total
8.25E-04


3.73E-01


HpCDF Total
6.21 E-04


2.81 E-01


OCDF
3.06E-04


1.38E-01


PCDD Total
2.04E-02


9.24E+00


PCDF Total
8.04E-03


3.64E+00


PCDD/PCDF Total
2.85E-02


1.29E+01


PCDD TEQ Total

2.15E-04
2.15E-04

9.71 E-02
9.71 E-02
PCDF TEQ Total

1.35E-04
1.35E-04

6.12E-02
6.12E-02
PCDD/PCDF TEQ Total

3.50E-04
3.50E-04

1.58E-01
1.58E-01
Table A-14. PCDD/PCDF data for SB/SL 2.
PCDD/PCDF	Page 1 (2)
26-A

-------
Sample ID	PS-PCDD-SB2-SV0C-11212014-02	MCE 0.982
Sampling volume (m3)	56.4
Carbon sampled (g)	63.4
Carbon sampled (mg/m3)	1123.4
Carbon fraction	0.452



TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total
LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ng/sample
ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
2.00E-03

2.00E-03
2.00E-03
3.54E-05
3.54E-05
3.54E-05
1,2,3,7,8- PeCDD
6.89E-03

6.89E-03
6.89E-03
1.22E-04
1.22E-04
1.22E-04
1,2,3,4,7,8- HxCDD
4.22E-03

4.22E-04
4.22E-04
7.48E-05
7.48E-06
7.48E-06
1,2,3,6,7,8- HxCDD
1.44E-02

1.44E-03
1.44E-03
2.56E-04
2.56E-05
2.56E-05
1,2,3,7,8,9- HxCDD
1.00E-02

1.00E-03
1.00E-03
1.77E-04
1.77E-05
1.77E-05
1,2,3,4,6,7,8- HpCDD
2.14E-01

2.14E-03
2.14E-03
3.79E-03
3.79E-05
3.79E-05
1,2,3,4,6,7,8,9 - OCDD
6.48E-01

1.94E-04
1.94E-04
1.15E-02
3.45E-06
3.45E-06
2,3,7,8 - TCDF
4.16E-02

4.16E-03
4.16E-03
7.37E-04
7.37E-05
7.37E-05
1,2,3,7,8- PeCDF
1.09E-02

3.27E-04
3.27E-04
1.93E-04
5.79E-06
5.79E-06
2,3,4,7,8- PeCDF
1.36E-02

4.07E-03
4.07E-03
2.40E-04
7.21 E-05
7.21 E-05
1,2,3,4,7,8- HxCDF
6.67E-03

6.67E-04
6.67E-04
1.18E-04
1.18E-05
1.18E-05
1,2,3,6,7,8- HxCDF
4.44E-03

4.44E-04
4.44E-04
7.88E-05
7.88E-06
7.88E-06
1,2,3,7,8,9- HxCDF
1.78E-03

1.78E-04
1.78E-04
3.15E-05
3.15E-06
3.15E-06
2,3,4,6,7,8 - HxCDF
5.33E-03

5.33E-04
5.33E-04
9.45E-05
9.45E-06
9.45E-06
1,2,3,4,6,7,8- HpCDF
1.38E-02

1.38E-04
1.38E-04
2.44E-04
2.44E-06
2.44E-06
1,2,3,4,7,8,9- HpCDF
2.00E-03

2.00E-05
2.00E-05
3.54E-05
3.54E-07
3.54E-07
1,2,3,4,6,7,8,9-OCDF
1.84E-02

5.53E-06
5.53E-06
3.27E-04
9.81 E-08
9.81 E-08
TeCDD Total
6.59E-02



1.17E-03


PeCDD Total
5.67E-02



1.00E-03


HxCDD Total
1.15E-01



2.05E-03


HpCDD Total
3.40E-01



6.03E-03


OCDD
6.48E-01



1.15E-02


TeCDF Total
3.86E-01



6.84E-03


PeCDF Total
1.39E-01



2.47E-03


HxCDF Total
4.55E-02



8.06E-04


HpCDF Total
3.82E-02



6.78E-04


OCDF
1.84E-02



3.26E-04


PCDD Total
1.23E+00



2.17E-02


PCDF Total
6.27E-01



1.11 E-02


PCDD/PCDF Total
1.85E+00



3.28E-02


PCDD TEQ Total


1.41 E-02
1.41 E-02

2.50E-04
2.50E-04
PCDF TEQ Total


1.05E-02
1.05E-02

1.87E-04
1.87E-04
PCDD/PCDF TEQ Total


2.46E-02
2.46E-02

4.36E-04
4.36E-04
Sample ID	PS-PCDD-SB2-SVOC-11212014-02	Page 2 (2)
27-A

-------

EF
EF
EF
EF
EF
EF

Total
TEQ
TEQ
Total
TEQ
TEQ
Isomer.

ng/g Carbon


ng/kg fiberboard



ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
3.16E-05
3.16E-05
3.16E-05
1.43E-02
1.43E-02
1.43E-02
1,2,3,7,8- PeCDD
1.09E-04
1.09E-04
1.09E-04
4.91 E-02
4.91 E-02
4.91 E-02
1,2,3,4,7,8- HxCDD
6.66E-05
6.66E-06
6.66E-06
3.01 E-02
3.01 E-03
3.01 E-03
1,2,3,6,7,8- HxCDD
2.28E-04
2.28E-05
2.28E-05
1.03E-01
1.03E-02
1.03E-02
1,2,3,7,8,9- HxCDD
1.58E-04
1.58E-05
1.58E-05
7.13E-02
7.13E-03
7.13E-03
1,2,3,4,6,7,8- HpCDD
3.37E-03
3.37E-05
3.37E-05
1.52E+00
1.52E-02
1.52E-02
1,2,3,4,6,7,8,9 - OCDD
1.02E-02
3.07E-06
3.07E-06
4.62E+00
1.39E-03
1.39E-03
2,3,7,8 - TCDF
6.56E-04
6.56E-05
6.56E-05
2.96E-01
2.96E-02
2.96E-02
1,2,3,7,8- PeCDF
1.72E-04
5.15E-06
5.15E-06
7.77E-02
2.33E-03
2.33E-03
2,3,4,7,8- PeCDF
2.14E-04
6.42E-05
6.42E-05
9.67E-02
2.90E-02
2.90E-02
1,2,3,4,7,8- HxCDF
1.05E-04
1.05E-05
1.05E-05
4.76E-02
4.76E-03
4.76E-03
1,2,3,6,7,8- HxCDF
7.01 E-05
7.01 E-06
7.01 E-06
3.17E-02
3.17E-03
3.17E-03
1,2,3,7,8,9- HxCDF
2.80E-05
2.80E-06
2.80E-06
1.27E-02
1.27E-03
1.27E-03
2,3,4,6,7,8 - HxCDF
8.41 E-05
8.41 E-06
8.41 E-06
3.80E-02
3.80E-03
3.80E-03
1,2,3,4,6,7,8- HpCDF
2.17E-04
2.17E-06
2.17E-06
9.83E-02
9.83E-04
9.83E-04
1,2,3,4,7,8,9- HpCDF
3.16E-05
3.16E-07
3.16E-07
1.43E-02
1.43E-04
1.43E-04
1,2,3,4,6,7,8,9-OCDF
2.91 E-04
8.73E-08
8.73E-08
1.32E-01
3.95E-05
3.95E-05
TeCDD Total
1.04E-03


4.70E-01


PeCDD Total
8.94E-04


4.04E-01


HxCDD Total
1.82E-03


8.24E-01


HpCDD Total
5.37E-03


2.43E+00


OCDD
1.02E-02


4.62E+00


TeCDF Total
6.09E-03


2.75E+00


PeCDF Total
2.19E-03


9.92E-01


HxCDF Total
7.18E-04


3.24E-01


HpCDF Total
6.03E-04


2.73E-01


OCDF
2.90E-04


1.31 E-01


PCDD Total
1.93E-02


8.75E+00


PCDF Total
9.90E-03


4.47E+00


PCDD/PCDF Total
2.92E-02


1.32E+01


PCDD TEQ Total

2.22E-04
2.22E-04

1.00E-01
1.00E-01
PCDF TEQ Total

1.66E-04
1.66E-04

7.51 E-02
7.51 E-02
PCDD/PCDF TEQ Total

3.88E-04
3.88E-04

1.76E-01
1.76E-01
820
Table A-15. PCDD/PCDF data for SB/SL 3.
PCDD/PCDF	Page 1 (2)
Sample ID	PS-PCDD-SB3-SVOC-120314-01	MCE 0.969
28-A

-------
Sampling volume (m3)	73.1
Carbon sampled (g)	49.7
Carbon sampled (mg/m3)	679.5
Carbon fraction	0.4522



TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total
LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ng/sample
ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
4.89E-03

4.89E-03
4.89E-03
6.69E-05
6.69E-05
6.69E-05
1,2,3,7,8- PeCDD
2.22E-02

2.22E-02
2.22E-02
3.04E-04
3.04E-04
3.04E-04
1,2,3,4,7,8- HxCDD
1.24E-02

1.24E-03
1.24E-03
1.70E-04
1.70E-05
1.70E-05
1,2,3,6,7,8- HxCDD
3.80E-02

3.80E-03
3.80E-03
5.20E-04
5.20E-05
5.20E-05
1,2,3,7,8,9- HxCDD
2.89E-02

2.89E-03
2.89E-03
3.95E-04
3.95E-05
3.95E-05
1,2,3,4,6,7,8- HpCDD
4.43E-01

4.43E-03
4.43E-03
6.06E-03
6.06E-05
6.06E-05
1,2,3,4,6,7,8,9 - OCDD
1.13E+00

3.38E-04
3.38E-04
1.54E-02
4.62E-06
4.62E-06
2,3,7,8 - TCDF
2.58E-02

2.58E-03
2.58E-03
3.53E-04
3.53E-05
3.53E-05
1,2,3,7,8- PeCDF
7.33E-03

2.20E-04
2.20E-04
1.00E-04
3.01 E-06
3.01 E-06
2,3,4,7,8- PeCDF
8.44E-03

2.53E-03
2.53E-03
1.15E-04
3.46E-05
3.46E-05
1,2,3,4,7,8- HxCDF
3.56E-03

3.56E-04
3.56E-04
4.86E-05
4.86E-06
4.86E-06
1,2,3,6,7,8- HxCDF
4.22E-03

4.22E-04
4.22E-04
5.77E-05
5.77E-06
5.77E-06
1,2,3,7,8,9- HxCDF
1.56E-03

1.56E-04
1.56E-04
2.13E-05
2.13E-06
2.13E-06
2,3,4,6,7,8 - HxCDF
5.56E-03

5.56E-04
5.56E-04
7.60E-05
7.60E-06
7.60E-06
1,2,3,4,6,7,8- HpCDF
1.67E-02

1.67E-04
1.67E-04
2.28E-04
2.28E-06
2.28E-06
1,2,3,4,7,8,9- HpCDF
3.33E-03

3.33E-05
3.33E-05
4.56E-05
4.56E-07
4.56E-07
1,2,3,4,6,7,8,9-OCDF
2.20E-02

6.60E-06
6.60E-06
3.01 E-04
9.03E-08
9.03E-08
TeCDD Total
1.26E-01



1.73E-03


PeCDD Total
1.36E-01



1.86E-03


HxCDD Total
3.09E-01



4.22E-03


HpCDD Total
7.06E-01



9.65E-03


OCDD
1.13E+00



1.54E-02


TeCDF Total
2.98E-01



4.08E-03


PeCDF Total
8.80E-02



1.20E-03


HxCDF Total
4.13E-02



5.65E-04


HpCDF Total
4.74E-02



6.48E-04


OCDF
2.20E-02



3.01 E-04


PCDD Total
2.40E+00



3.29E-02


PCDF Total
4.97E-01



6.80E-03


PCDD/PCDF Total
2.90E+00



3.97E-02


PCDD TEQ Total


3.98E-02
3.98E-02

5.44E-04
5.44E-04
PCDF TEQ Total


7.03E-03
7.03E-03

9.61 E-05
9.61 E-05
PCDD/PCDF TEQ Total


4.68E-02
4.68E-02

6.41 E-04
6.41 E-04
Sam pie ID	PS-PCDD-SB3-SVOC-120314-01	Page 2 (2)
29-A

-------

EF
EF
EF
EF
EF
EF

Total
TEQ
TEQ
Total
TEQ
TEQ
Isomer.

ng/g Carbon

ng/kg fiberboard


ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
9.84E-05
9.84E-05
9.84E-05
4.45E-02
4.45E-02
4.45E-02
1,2,3,7,8- PeCDD
4.47E-04
4.47E-04
4.47E-04
2.02E-01
2.02E-01
2.02E-01
1,2,3,4,7,8- HxCDD
2.50E-04
2.50E-05
2.50E-05
1.13E-01
1.13E-02
1.13E-02
1,2,3,6,7,8- HxCDD
7.65E-04
7.65E-05
7.65E-05
3.46E-01
3.46E-02
3.46E-02
1,2,3,7,8,9- HxCDD
5.81 E-04
5.81 E-05
5.81 E-05
2.63E-01
2.63E-02
2.63E-02
1,2,3,4,6,7,8- HpCDD
8.91 E-03
8.91 E-05
8.91 E-05
4.03E+00
4.03E-02
4.03E-02
1,2,3,4,6,7,8,9 - OCDD
2.27E-02
6.81 E-06
6.81 E-06
1.03E+01
3.08E-03
3.08E-03
2,3,7,8 - TCDF
5.19E-04
5.19E-05
5.19E-05
2.35E-01
2.35E-02
2.35E-02
1,2,3,7,8- PeCDF
1.48E-04
4.43E-06
4.43E-06
6.67E-02
2.00E-03
2.00E-03
2,3,4,7,8- PeCDF
1.70E-04
5.10E-05
5.10E-05
7.68E-02
2.31 E-02
2.31 E-02
1,2,3,4,7,8- HxCDF
7.16E-05
7.16E-06
7.16E-06
3.24E-02
3.24E-03
3.24E-03
1,2,3,6,7,8- HxCDF
8.50E-05
8.50E-06
8.50E-06
3.84E-02
3.84E-03
3.84E-03
1,2,3,7,8,9- HxCDF
3.13E-05
3.13E-06
3.13E-06
1.42E-02
1.42E-03
1.42E-03
2,3,4,6,7,8 - HxCDF
1.12E-04
1.12E-05
1.12E-05
5.06E-02
5.06E-03
5.06E-03
1,2,3,4,6,7,8- HpCDF
3.35E-04
3.35E-06
3.35E-06
1.52E-01
1.52E-03
1.52E-03
1,2,3,4,7,8,9- HpCDF
6.71 E-05
6.71 E-07
6.71 E-07
3.03E-02
3.03E-04
3.03E-04
1,2,3,4,6,7,8,9-OCDF
4.43E-04
1.33E-07
1.33E-07
2.00E-01
6.01 E-05
6.01 E-05
TeCDD Total
2.54E-03


1.15E+00


PeCDD Total
2.73E-03


1.24E+00


HxCDD Total
6.21 E-03


2.81 E+00


HpCDD Total
1.42E-02


6.42E+00


OCDD
2.27E-02


1.03E+01


TeCDF Total
6.01 E-03


2.72E+00


PeCDF Total
1.77E-03


8.01 E-01


HxCDF Total
8.31 E-04


3.76E-01


HpCDF Total
9.54E-04


4.31 E-01


OCDF
4.43E-04


2.00E-01


PCDD Total
4.84E-02


2.19E+01


PCDF Total
1.00E-02


4.52E+00


PCDD/PCDF Total
5.84E-02


2.64E+01


PCDD TEQ Total

8.01 E-04
8.01 E-04

3.62E-01
3.62E-01
PCDF TEQ Total

1.41 E-04
1.41 E-04

6.39E-02
6.39E-02
PCDD/PCDF TEQ Total

9.43E-04
9.43E-04

4.26E-01
4.26E-01
825 Table A-16. PCDD/PCDF data for SB/SL 4.
PCDD/PCDF	Page 1 (2)
Sample ID	PS-PCDD-SB4-SV0C-120414-01	MCE 0.971
30-A

-------
Sampling volume (m3)	96.4
Carbon sampled (g)	63.3
Carbon sampled (mg/m3)	656.4
Carbon fraction	0.4522



TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total
LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ng/sample
ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
5.78E-03

5.78E-03
5.78E-03
5.99E-05
5.99E-05
5.99E-05
1,2,3,7,8- PeCDD
2.40E-02

2.40E-02
2.40E-02
2.49E-04
2.49E-04
2.49E-04
1,2,3,4,7,8- HxCDD
1.29E-02

1.29E-03
1.29E-03
1.34E-04
1.34E-05
1.34E-05
1,2,3,6,7,8- HxCDD
3.93E-02

3.93E-03
3.93E-03
4.08E-04
4.08E-05
4.08E-05
1,2,3,7,8,9- HxCDD
2.96E-02

2.96E-03
2.96E-03
3.07E-04
3.07E-05
3.07E-05
1,2,3,4,6,7,8- HpCDD
4.08E-01

4.08E-03
4.08E-03
4.23E-03
4.23E-05
4.23E-05
1,2,3,4,6,7,8,9 - OCDD
1.06E+00

3.17E-04
3.17E-04
1.10E-02
3.29E-06
3.29E-06
2,3,7,8 -TCDF
3.44E-02

3.44E-03
3.44E-03
3.57E-04
3.57E-05
3.57E-05
1,2,3,7,8- PeCDF
9.56E-03

2.87E-04
2.87E-04
9.91 E-05
2.97E-06
2.97E-06
2,3,4,7,8- PeCDF
1.18E-02

3.53E-03
3.53E-03
1.22E-04
3.67E-05
3.67E-05
1,2,3,4,7,8- HxCDF
6.89E-03

6.89E-04
6.89E-04
7.15E-05
7.15E-06
7.15E-06
1,2,3,6,7,8- HxCDF
5.11E-03

5.11E-04
5.11E-04
5.30E-05
5.30E-06
5.30E-06
1,2,3,7,8,9- HxCDF
1.78E-03

1.78E-04
1.78E-04
1.84E-05
1.84E-06
1.84E-06
2,3,4,6,7,8 - HxCDF
6.00E-03

6.00E-04
6.00E-04
6.22E-05
6.22E-06
6.22E-06
1,2,3,4,6,7,8- HpCDF
1.80E-02

1.80E-04
1.80E-04
1.87E-04
1.87E-06
1.87E-06
1,2,3,4,7,8,9- HpCDF
3.56E-03

3.56E-05
3.56E-05
3.69E-05
3.69E-07
3.69E-07
1,2,3,4,6,7,8,9-OCDF
2.49E-02

7.47E-06
7.47E-06
2.58E-04
7.75E-08
7.75E-08
TeCDD Total
1.71 E-01



1.78E-03


PeCDD Total
1.66E-01



1.72E-03


HxCDD Total
3.13E-01



3.25E-03


HpCDD Total
6.63E-01



6.88E-03


OCDD
1.06E+00



1.10E-02


TeCDF Total
4.17E-01



4.32E-03


PeCDF Total
1.17E-01



1.22E-03


HxCDF Total
5.09E-02



5.28E-04


HpCDF Total
4.99E-02



5.18E-04


OCDF
2.49E-02



2.59E-04


PCDD Total
2.37E+00



2.46E-02


PCDF Total
6.60E-01



6.84E-03


PCDD/PCDF Total
3.03E+00



3.14E-02


PCDD TEQ Total


4.24E-02
4.24E-02

4.39E-04
4.39E-04
PCDF TEQ Total


9.47E-03
9.47E-03

9.82E-05
9.82E-05
PCDD/PCDF TEQ Total


5.18E-02
5.18E-02

5.38E-04
5.38E-04
Sample ID	PS-PCDD-SB4-SVOC-120414-01	Page 2 (2)
EFEFEFEFEFEF
31-A

-------

Total
TEQ
TEQ
Total
TEQ
TEQ
Isomer.

ng/g Carbon

ng/kg fiberboard



ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8-TCDD
9.13E-05
9.13E-05
9.13E-05
4.13E-02
4.13E-02
4.13E-02
1,2,3,7,8 -PeCDD
3.79E-04
3.79E-04
3.79E-04
1.72E-01
1.72E-01
1.72E-01
1,2,3,4,7,8 -HxCDD
2.04E-04
2.04E-05
2.04E-05
9.21 E-02
9.21 E-03
9.21 E-03
1,2,3,6,7,8 -HxCDD
6.22E-04
6.22E-05
6.22E-05
2.81 E-01
2.81 E-02
2.81 E-02
1,2,3,7,8,9-HxCDD
4.67E-04
4.67E-05
4.67E-05
2.11E-01
2.11 E-02
2.11 E-02
1,2,3,4,6,7,8- HpCDD
6.44E-03
6.44E-05
6.44E-05
2.91 E+00
2.91 E-02
2.91 E-02
1,2,3,4,6,7,8,9 - OCDD
1.67E-02
5.02E-06
5.02E-06
7.56E+00
2.27E-03
2.27E-03
2,3,7,8 -TCDF
5.44E-04
5.44E-05
5.44E-05
2.46E-01
2.46E-02
2.46E-02
1,2,3,7,8-PeCDF
1.51E-04
4.53E-06
4.53E-06
6.83E-02
2.05E-03
2.05E-03
2,3,4,7,8 - PeCDF
1.86E-04
5.58E-05
5.58E-05
8.42E-02
2.52E-02
2.52E-02
1,2,3,4,7,8-HxCDF
1.09E-04
1.09E-05
1.09E-05
4.92E-02
4.92E-03
4.92E-03
1,2,3,6,7,8-HxCDF
8.08E-05
8.08E-06
8.08E-06
3.65E-02
3.65E-03
3.65E-03
1,2,3,7,8,9- HxCDF
2.81 E-05
2.81 E-06
2.81 E-06
1.27E-02
1.27E-03
1.27E-03
2,3,4,6,7,8 - HxCDF
9.48E-05
9.48E-06
9.48E-06
4.29E-02
4.29E-03
4.29E-03
1,2,3,4,6,7,8- HpCDF
2.84E-04
2.84E-06
2.84E-06
1.29E-01
1.29E-03
1.29E-03
1,2,3,4,7,8,9- HpCDF
5.62E-05
5.62E-07
5.62E-07
2.54E-02
2.54E-04
2.54E-04
1,2,3,4,6,7,8,9-OCDF
3.93E-04
1.18E-07
1.18E-07
1.78E-01
5.34E-05
5.34E-05
TeCDD Total
2.70E-03


1.22E+00


PeCDD Total
2.62E-03


1.18E+00


HxCDD Total
4.95E-03


2.24E+00


HpCDD Total
1.05E-02


4.74E+00


OCDD
1.67E-02


7.56E+00


TeCDF Total
6.59E-03


2.98E+00


PeCDF Total
1.85E-03


8.37E-01


HxCDF Total
8.05E-04


3.64E-01


HpCDF Total
7.88E-04


3.56E-01


OCDF
3.94E-04


1.78E-01


PCDD Total
3.75E-02


1.69E+01


PCDF Total
1.04E-02


4.71 E+00


PCDD/PCDF Total
4.79E-02


2.17E+01


PCDD TEQ Total

6.69E-04
6.69E-04

3.03E-01
3.03E-01
PCDF TEQ Total

1.50E-04
1.50E-04

6.76E-02
6.76E-02
PCDD/PCDF TEQ Total

8.19E-04
8.19E-04

3.70E-01
3.70E-01
830 Table A-16. Pre-test background PCDD/PCDF concentrations.
PCDD/PCDF - Ambient/Background concentrations	Page 1 (1)
Sample ID	BS-PCDD-SVOC-111414
Sampling volume (m3)	279.5
32-A

-------



TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total
LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ng/sample
ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8-TCDD
2.22E-04

2.22E-04
2.22E-04
7.95E-07
7.95E-07
7.95E-07
1,2,3,7,8-PeCDD
8.89E-04

8.89E-04
8.89E-04
3.18E-06
3.18E-06
3.18E-06
1,2,3,4,7,8-HxCDD
6.67E-04

6.67E-05
6.67E-05
2.38E-06
2.38E-07
2.38E-07
1,2,3,6,7,8 -HxCDD
1.33E-03

1.33E-04
1.33E-04
4.77E-06
4.77E-07
4.77E-07
1,2,3,7,8,9-HxCDD
1.33E-03

1.33E-04
1.33E-04
4.77E-06
4.77E-07
4.77E-07
1,2,3,4,6,7,8- HpCDD
1.76E-02

1.76E-04
1.76E-04
6.28E-05
6.28E-07
6.28E-07
1,2,3,4,6,7,8,9 - OCDD
4.96E-02

1.49E-05
1.49E-05
1.77E-04
5.32E-08
5.32E-08
2,3,7,8 -TCDF
6.67E-04

6.67E-05
6.67E-05
2.38E-06
2.38E-07
2.38E-07
1,2,3,7,8-PeCDF
8.89E-04

2.67E-05
2.67E-05
3.18E-06
9.54E-08
9.54E-08
2,3,4,7,8 - PeCDF
6.67E-04

2.00E-04
2.00E-04
2.38E-06
7.15E-07
7.15E-07
1,2,3,4,7,8-HxCDF
8.89E-04

8.89E-05
8.89E-05
3.18E-06
3.18E-07
3.18E-07
1,2,3,6,7,8-HxCDF
8.89E-04

8.89E-05
8.89E-05
3.18E-06
3.18E-07
3.18E-07
1,2,3,7,8,9-HxCDF
4.44E-04

4.44E-05
4.44E-05
1.59E-06
1.59E-07
1.59E-07
2,3,4,6,7,8 - HxCDF
1.33E-03

1.33E-04
1.33E-04
4.77E-06
4.77E-07
4.77E-07
1,2,3,4,6,7,8- HpCDF
4.44E-03

4.44E-05
4.44E-05
1.59E-05
1.59E-07
1.59E-07
1,2,3,4,7,8,9- HpCDF
6.67E-04

6.67E-06
6.67E-06
2.38E-06
2.38E-08
2.38E-08
1,2,3,4,6,7,8,9-OCDF
4.22E-03

1.27E-06
1.27E-06
1.51 E-05
4.53E-09
4.53E-09
TeCDD Total
1.17E-02



4.19E-05


PeCDD Total
1.01 E-02



3.63E-05


HxCDD Total
1.66E-02



5.95E-05


HpCDD Total
3.85E-02



1.38E-04


OCDD
4.94E-02



1.77E-04


TeCDF Total
2.84E-02



1.02E-04


PeCDF Total
1.30E-02



4.66E-05


HxCDF Total
6.78E-03



2.42E-05


HpCDF Total
8.16E-03



2.92E-05


OCDF
4.53E-03



1.62E-05


PCDD Total
1.26E-01



4.52E-04


PCDF Total
6.09E-02



2.18E-04


PCDD/PCDF Total
1.87E-01



6.70E-04


PCDD TEQ Total


1.63E-03
1.63E-03

5.85E-06
5.85E-06
PCDF TEQ Total


7.01 E-04
7.01 E-04

2.51 E-06
2.51 E-06
PCDD/PCDF TEQ Total


2.34E-03
2.34E-03

8.36E-06
8.36E-06
Table A-17. PAH emission factors for NWS.

NWS1 NWS3 NWS4
PAH
mg/kg Fiberboard
Naphthalene
11.48 51.89 21.57
33-A

-------
Acenaphthylene
7.95
24.09
8.17

Acenaphthene
0.44
1.20
0.40

Fluorene
2.75
4.70
1.49

Phenanthrene
12.25
13.38
4.72

Anthracene
3.22
3.05
0.97

Fluoranthene
6.48
6.45
1.83

Pyrene
6.10
5.87
1.64

Benzo(a)anthracene
1.63
1.47
0.43

Chrysene
1.47
1.35
0.43

Benzo(b)fluoranthene
0.86
0.74
0.26

Benzo(k)fluoranthene
1.16
1.18
0.38

Benzo(a)pyrene
1.34
1.32
0.38

lndeno(1,2,3-cd)pyrene
0.87
0.82
0.27

Dibenz(a,h)anthracene
0.17
0.13
0.04

Benzo(ghi)perylene
0.91
0.96
0.30

SUM 16-EPA PAH
59.09
118.61
43.29

Table A-18. PAH emission factors for CB/CL.



CB1/CL1
CB2/CL2
CB3/CL3 CB4/CL4
PAH

mg/kg Fiberboard

Naphthalene
10.77
6.97
5.50
5.36
Acenaphthylene
5.35
3.03
2.35
2.37
Acenaphthene
0.30
0.14
0.12
0.11
Fluorene
1.21
0.66
0.55
0.54
Phenanthrene
4.30
2.81
2.47
2.34
Anthracene
0.91
0.57
0.50
0.46
Fluoranthene
2.46
1.52
1.27
1.22
Pyrene
2.42
1.46
1.20
1.20
Benzo(a)anthracene
0.53
0.28
0.24
0.25
Chrysene
0.48
0.28
0.24
0.25
Benzo(b)fluoranthene
0.28
0.17
0.14
0.13
Benzo(k)fluoranthene
0.36
0.20
0.19
0.19
Benzo(a)pyrene
0.39
0.21
0.19
0.20
lndeno(1,2,3-cd)pyrene
0.24
0.15
0.13
0.14
Dibenz(a,h)anthracene
0.046
0.027
0.020
0.020
Benzo(ghi)perylene
0.29
0.18
0.14
0.15
SUM 16-EPA PAH
30.31
18.66
15.25
14.93
Table A-19. PAH emission factors for NSB/NSL.

NSB1/NSL1
NSB2/NSL2 NSB3/NSL3
NSB4/NSL4
PAH

mg/kg Fiberboard

Naphthalene
6.58
29.31 24.36
23.72
34-A

-------
Acenaphthylene
2.91

8.81
8.02
7.89
Acenaphthene
0.15

0.60
0.49
0.46
Fluorene
0.66

2.00
1.55
1.49
Phenanthrene
2.60

5.61
4.81
4.64
Anthracene
0.54

1.32
1.05
1.05
Fluoranthene
1.35

1.98
1.84
1.91
Pyrene
1.31

1.86
1.68
1.77
Benzo(a)anthracene
0.28

0.59
0.45
0.43
Chrysene
0.27

0.54
0.43
0.41
Benzo(b)fluoranthene
0.16

0.32
0.22
0.21
Benzo(k)fluoranthene
0.19

0.28
0.31
0.29
Benzo(a)pyrene
0.21

0.37
0.34
0.33
lndeno(1,2,3-cd)pyrene
0.14

0.22
0.22
0.21
Dibenz(a,h)anthracene
0.026

0.050
0.043
0.031
Benzo(ghi)perylene
0.16

0.24
0.23
0.21
SUM 16-EPA PAH
17.55

54.10
46.04
45.05
Table A-20. PAH emission factors for SB/SL.



SB1/SL1 SB2/SL2
SB3/SL3
SB4/SL4

PAH
mg/kg Fiberboard


Naphthalene
10.61
11.12
12.13
24.58

Acenaphthylene
3.44
3.33
4.60
7.99

Acenaphthene
0.22
0.20
0.34
0.64

Fluorene
1.16
1.09
2.04
2.74

Phenanthrene
4.21
4.23
9.31
9.55

Anthracene
0.94
0.93
2.32
2.54

Fluoranthene
1.70
1.65
3.70
3.75

Pyrene
1.56
1.47
3.29
3.48

Benzo(a)anthracene
0.45
0.45
0.98
1.11

Chrysene
0.43
0.43
0.98
1.04

Benzo(b)fluoranthene
0.21
0.19
0.44
0.50

Benzo(k)fluoranthene
0.27
0.25
0.49
0.59

Benzo(a)pyrene
0.28
0.26
0.58
0.69

lndeno(1,2,3-cd)pyrene
0.17
0.16
0.36
0.41

Dibenz(a,h)anthracene
0.036
0.034
0.091
0.11

Benzo(ghi)perylene
0.19
0.16
0.33
0.40

SUM 16-EPA PAH
25.88
25.96
41.98
60.12

Table A-21. TEQ PAH emission factors for NWS.

NWS1 NWS3 NWS4
PAH
mg B[a]P TEQ/kg Fiberboard
Naphthalene
NA NA NA
35-A

-------
Acenaphthylene
NA
NA
NA


Acenaphthene
NA
NA
NA


Fluorene
NA
NA
NA


Phenanthrene
6.13E-03
6.69E-03
2.36E-03


Anthracene
1.61E-03
1.52E-03
4.86E-04


Fluoranthene
3.24E-01
3.22E-01
9.17E-02


Pyrene
6.10E-03
5.87E-03
1.64E-03


Benzo(a)anthracene
8.17E-03
7.36E-03
2.17E-03


Chrysene
4.40E-02
4.05E-02
1.28E-02


Benzo(b)fluoranthene
8.64E-02
7.37E-02
2.58E-02


Benzo(k)fluoranthene
5.78E-02
5.92E-02
1.92E-02


Benzo(a)pyrene
1.34E+00
1.32E+00
3.85E-01


lndeno(1,2,3-cd)pyrene
8.75E-02
8.22E-02
2.70E-02


Dibenz(a,h)anthracene
0.00E+00
1.42E-01
4.34E-02


Benzo(ghi)perylene
1.83E-02
1.93E-02
6.08E-03


SUM 16-EPA PAH
1.98E+00
2.08E+00
6.17E-01


Table A-22. TEQ PAH emission factors for CB/CL.




CB1/CL1
CB2/CL2
CB3/CL3
CB4/CL4
PAH
mg B[a]P TEQ/kg Fiberboard
Naphthalene
NA
NA
NA

NA
Acenaphthylene
NA
NA
NA

NA
Acenaphthene
NA
NA
NA

NA
Fluorene
NA
NA
NA

NA
Phenanthrene
2.15E-03
1.41E-03
1.24E-03

.17E-03
Anthracene
4.57E-04
2.84E-04
2.50E-04
2.31 E-04
Fluoranthene
1.23E-01
7.62E-02
6.35E-02
6.10E-02
Pyrene
2.42E-03
1.46E-03
1.20E-03
1.20E-03
Benzo(a)anthracene
2.63E-03
1.40E-03
1.22E-03
1.25E-03
Chrysene
1.44E-02
8.42E-03
7.14E-03
7.49E-03
Benzo(b)fluoranthene
2.78E-02
1.70E-02
1.38E-02
1.33E-02
Benzo(k)fluoranthene
1.80E-02
9.76E-03
9.33E-03
9.41 E-03
Benzo(a)pyrene
3.87E-01
2.12E-01
1.87E-01
1.95E-01
lndeno(1,2,3-cd)pyrene
2.37E-02
1.53E-02
1.26E-02
1.36E-02
Dibenz(a,h)anthracene
5.08E-02
3.01 E-02
2.21 E-02
2.25E-02
Benzo(ghi)perylene
5.77E-03
3.52E-03
2.90E-03
3.01 E-03
SUM 16-EPA PAH
6.58E-01
3.77E-01
3.22E-01
3.30E-01
Table A-23. TEQ PAH emission factors for NSB/NSL.

NSB1/NSL1 NSB2/NSL2 NSB3/NSL3 NSB4/NSL4
PAH
mg B[a]P TEQ/kg Fiberboard
Naphthalene
NA NA NA NA
36-A

-------
Acenaphthylene
NA
NA
NA
NA
Acenaphthene
NA
NA
NA
NA
Fluorene
NA
NA
NA
NA
Phenanthrene
1.30E-03
2.81 E-03
2.40E-03
2.32E-03
Anthracene
2.70E-04
6.60E-04
5.25E-04
5.27E-04
Fluoranthene
6.73E-02
9.88E-02
9.19E-02
9.55E-02
Pyrene
1.31E-03
1.86E-03
1.68E-03
1.77E-03
Benzo(a)anthracene
1.40E-03
2.95E-03
2.26E-03
2.14E-03
Chrysene
8.12E-03
1.61E-02
1.29E-02
1.22E-02
Benzo(b)fluoranthene
1.57E-02
3.22E-02
2.25E-02
2.13E-02
Benzo(k)fluoranthene
9.31 E-03
1.38E-02
1.56E-02
1.43E-02
Benzo(a)pyrene
2.14E-01
3.67E-01
3.36E-01
3.31 E-01
lndeno(1,2,3-cd)pyrene
1.44E-02
2.18E-02
2.15E-02
2.08E-02
Dibenz(a,h)anthracene
0.00E+00
5.48E-02
4.71 E-02
3.39E-02
Benzo(ghi)perylene
3.27E-03
4.83E-03
4.65E-03
4.14E-03
SUM 16-EPA PAH
3.37E-01
6.18E-01
5.59E-01
5.40E-01
Table A-24. TEQ PAH emission factors for SB/SL.

SB1/SL1
SB2/SL2
SB3/SL3
SB4/SL4
PAH
mg B[a]P TEQ/kg Fiberboard
Naphthalene
NA
NA
NA
NA
Acenaphthylene
NA
NA
NA
NA
Acenaphthene
NA
NA
NA
NA
Fluorene
NA
NA
NA
NA
Phenanthrene
2.11 E-03
2.11 E-03
4.65E-03
4.77E-03
Anthracene
4.71 E-04
4.66E-04
1.16E-03
1.27E-03
Fluoranthene
8.49E-02
8.26E-02
1.85E-01
1.88E-01
Pyrene
1.56E-03
1.47E-03
3.29E-03
3.48E-03
Benzo(a)anthracene
2.25E-03
2.25E-03
4.90E-03
5.54E-03
Chrysene
1.28E-02
1.30E-02
2.93E-02
3.13E-02
Benzo(b)fluoranthene
2.10E-02
1.89E-02
4.37E-02
4.98E-02
Benzo(k)fluoranthene
1.35E-02
1.24E-02
2.45E-02
2.94E-02
Benzo(a)pyrene
2.79E-01
2.62E-01
5.85E-01
6.94E-01
lndeno(1,2,3-cd)pyrene
1.71 E-02
1.63E-02
3.62E-02
4.10E-02
Dibenz(a,h)anthracene
0.00E+00
3.78E-02
9.97E-02
1.18E-01
Benzo(ghi)perylene
3.72E-03
3.29E-03
6.63E-03
8.02E-03
SUM 16-EPA PAH
4.39E-01
4.53E-01
1.02E+00
1.17E+00
Table A-25: PM Emission Factors.




EF PM2.5
EF PM10


Date Matrix
g/kg Fiberboard


11/19/2014 NSB/NSL
2.8
2.9


37-A

-------
11/19/2014
NSB/NSL
2.7
2.8
12/11/2014
NSB/NSL
2.5
2.5
12/11/2014
NSB/NSL
8.3
7.5
12/17/2014
NSB/NSL
3.0
3.0
12/17/2014
NSB/NSL
2.7
2.8
12/17/2014
NSB/NSL
2.6
2.7
12/17/2014
NSB/NSL
2.9
3.0
11/17/2014
NWS
2.6
2.7
11/17/2014
NWS
3.5
3.9
11/17/2014
NWS
3.5
3.4
11/18/2014
NWS
3.4
3.5
11/18/2014
NWS
3.4
3.2
12/08/2014
NWS
5.1
5.1
12/09/2014
NWS
3.3
3.7
12/09/2014
NWS
2.9
3.3
12/10/2014
NWS
2.6
2.7
12/10/2014
NWS
4.1
4.2
11/20/2014
SB/SL
2.4
2.3
11/20/2014
SB/SL
2.0
1.9
11/21/2014
SB/SL
2.9
2.4
11/21/2014
SB/SL
1.9
2.0
12/03/2014
SB/SL
4.4
4.5
12/04/2014
SB/SL
2.9
2.9
12/04/2014
SB/SL
3.2
3.0
11/18/2014
CB/CL
3.1
3.1
11/18/2014
CB/CL
3.0
3.0
11/19/2014
CB/CL
3.4
3.5
11/19/2014
CB/CL
3.3
3.4
11/20/2014
CB/CL
2.7
2.7
11/20/2014
CB/CL
3.1
3.4
11/21/2014
CB/CL
3.1
3.1
11/21/2014
CB/CL
1.4
1.3
Table A-26. VOC emission factors from current fiberboard Solid Boxes and Liners (CB/CL).
Current Fiberboard Solid Box and Liner (CB/CL)
12	3	4
38-A

-------


Method
detection
limit

Method
detection
limit

Method
detection
limit

Method
detection
limit
Compound
EF
EF
EF
EF
EF
EF
EF
EF

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
Propene
100.64
0.18
19.63
0.11
16.20
0.09
16.70
0.06
Dichlorodifluoromethane (CFC-12)
ND
0.22
ND
0.13
ND
0.11
ND
0.08
Chloromethane
4.49
0.19
2.76
0.11
1.31
0.09
1.45
0.07
1,2-Dichloro-1,1,2,2-
tetrafluoroethane (CFC 114)
ND
0.24
ND
0.14
ND
0.12
ND
0.09
Vinyl Chloride
0.22
0.22
ND
0.13
ND
0.11
ND
0.08
1,3-Butadiene
52.33
0.28
10.10
0.17
8.10
0.14
5.77
0.10
Bromomethane
ND
0.24
ND
0.14
ND
0.12
ND
0.09
Chloroethane
ND
0.22
ND
0.13
ND
0.11
ND
0.08
Ethanol
5.94
1.01
1.10
0.61
1.02
0.51
0.38
0.36
Aceto nit rile
2.82
0.23
0.78
0.14
0.58
0.11
0.56
0.08
Acrolein
3.02
0.22
8.37
0.13
12.72
0.11
13.51
0.08
Acetone
83.43
1.00
13.25
0.58
ND
0.49
8.34
0.35
Trichlorofluoromethane
ND
0.22
ND
0.13
ND
0.11
ND
0.08
2-Propanol (Isopropyl Alcohol)
ND
0.54
ND
0.32
ND
0.25
ND
0.18
Acrylonitrile
1.31
0.22
0.35
0.13
0.28
0.11
0.24
0.08
1,1-Dichloroethene
ND
0.22
ND
0.13
ND
0.11
ND
0.08
Methylene Chloride
11.78
0.22
7.71
0.13
2.24
0.11
0.14
0.08
3-Chloro-1 -propene (Allyl Chloride)
ND
0.20
ND
0.12
ND
0.10
ND
0.07
Trichlorotrifluoroethane
0.01
0.22
ND
0.13
ND
0.11
ND
0.08
Carbon Disulfide
2.42
0.19
0.84
0.11
1.25
0.09
1.21
0.07
trans-1,2-Dichloroethene
ND
0.24
ND
0.14
ND
0.12
ND
0.09
1,1-Dichloroethane
ND
0.20
ND
0.12
ND
0.10
ND
0.07
Methyl tert-Butyl Ether
ND
0.22
ND
0.13
ND
0.11
ND
0.08
Vinyl Acetate
41.26
0.84
46.18
0.49
21.29
0.42
22.77
0.29
2-Butanone (MEK)
26.07
0.27
5.17
0.16
2.98
0.13
2.87
0.09
cis-1,2-Dichloroethene
ND
0.20
ND
0.12
ND
0.10
ND
0.07
Ethyl Acetate
ND
0.45
ND
0.27
ND
0.22
0.09
0.15
n-Hexane
0.26
0.19
0.05
0.11
0.04
0.09
0.07
0.07
Chloroform
ND
0.22
ND
0.13
ND
0.11
ND
0.08
Tetrahydrofuran (THF)
1.11
0.26
ND
0.15
ND
0.12
0.10
0.09
1,2-Dichloroethane
ND
0.20
ND
0.12
ND
0.10
ND
0.07
1,1,1-Trichloroethane
ND
0.22
ND
0.13
ND
0.11
ND
0.08
Benzene
190.89
2.01
51.86
0.12
41.57
0.10
33.35
0.07
Carbon Tetrachloride
0.02
0.19
0.01
0.11
0.01
0.09
0.01
0.07
Cyclohexane
ND
0.37
ND
0.22
ND
0.18
ND
0.13
1,2-Dichloropropane
ND
0.20
ND
0.12
ND
0.10
ND
0.07
Bromodichloromethane
ND
0.19
ND
0.11
ND
0.09
ND
0.07
39-A

-------
Trichloroethene
ND
0.18
ND
0.11
ND
0.09
ND
0.06
1,4-Dioxane
ND
0.20
ND
0.12
ND
0.10
ND
0.07
Methyl Methacrylate
ND
0.40
ND
0.23
ND
0.19
ND
0.14
n-Heptane
ND
0.22
ND
0.13
ND
0.11
ND
0.08
cis-1,3-Dichloropropene
ND
0.18
ND
0.11
ND
0.09
ND
0.06
4-Methyl-2-pentanone
ND
0.20
ND
0.12
ND
0.10
ND
0.07
trans-1,3-Dichloropropene
ND
0.20
ND
0.12
ND
0.10
ND
0.07
1,1,2-Trichloroethane
ND
0.20
ND
0.12
ND
0.10
ND
0.07
Toluene
47.77
0.22
10.81
0.13
9.36
0.11
7.21
0.08
2-Hexanone
0.37
0.20
0.14
0.12
ND
0.10
0.08
0.07
Dibromochloromethane
ND
0.20
ND
0.12
ND
0.10
ND
0.07
1,2-Dibromoethane
ND
0.20
ND
0.12
ND
0.10
ND
0.07
n-Butyl Acetate
ND
0.20
ND
0.12
ND
0.10
ND
0.07
n- Octane
ND
0.23
ND
0.14
ND
0.11
ND
0.08
Tetrachloroethene
ND
0.18
ND
0.11
ND
0.09
ND
0.06
Chlorobenzene
ND
0.20
ND
0.12
ND
0.10
ND
0.07
Ethyl benzene
5.74
0.20
1.53
0.12
1.34
0.10
1.02
0.07
m-,,p-Xylenes
4.43
0.38
1.33
0.23
1.11
0.19
0.88
0.13
Bromoform
ND
0.19
ND
0.11
ND
0.09
ND
0.07
Styrene
9.16
0.19
5.48
0.11
4.40
0.09
3.49
0.07
o-Xylene
1.61
0.19
0.52
0.11
0.46
0.09
0.36
0.07
n-Nonane
ND
0.19
ND
0.11
ND
0.09
ND
0.07
1,1,2,2-Tetrachloroethane
ND
0.19
ND
0.11
ND
0.09
ND
0.07
Cumene
0.33
0.19
ND
0.11
ND
0.09
ND
0.07
alpha-Pinene
0.51
0.18
0.21
0.11
0.28
0.09
0.08
0.06
n-Propylbenzene
ND
0.20
ND
0.12
ND
0.10
ND
0.07
4-Ethyltoluene
ND
0.20
0.12
0.12
0.10
0.10
0.09
0.07
1,3,5-Trimethyl benzene
ND
0.20
ND
0.12
ND
0.10
ND
0.07
1,2,4-Trimethyl benzene
ND
0.19
0.16
0.11
0.14
0.09
0.12
0.07
Benzyl Chloride
ND
0.14
ND
0.08
ND
0.07
ND
0.05
1,3-Dichlorobenzene
ND
0.19
ND
0.11
ND
0.09
ND
0.07
1,4-Dichlorobenzene
ND
0.18
ND
0.11
ND
0.09
ND
0.06
1,2-Dichlorobenzene
ND
0.19
ND
0.11
ND
0.09
ND
0.07
d-Limonene
ND
0.18
0.18
0.11
0.14
0.09
0.10
0.06
1,2-Dibromo-3-chloropropane
ND
0.13
ND
0.08
ND
0.06
ND
0.04
1,2,4-Trichlorobenzene
ND
0.20
ND
0.12
ND
0.10
ND
0.07
Naphthalene
0.42
0.23
12.99
0.14
10.64
0.11
11.39
0.08
Hexachlorobutadiene
ND
0.18
ND
0.11
ND
0.09
ND
0.06
g/kg cardboard








Carbon Monoxide
27.72

15.57

14.07

14.29

Methane
0.20

0.17

0.20

0.13

40-A

-------
Carbon Dioxide
1651.55
1670.72
1673.00
1672.84
MCE
0.974
0.986
0.987
0.987
850
855
860
865
870
875 Table A-27. VOC emission factors from corrugated Spectra-kote polymer fiberboard box and liner
(SB/SL).
|	|	Corrugated Spectra-kote Polymer Fiberboard box and liner (SB/SL)
41-A

-------


1

2

3

4


Method
detection
limit

Method
detection
limit

Method
detection
limit

Method
detection
limit
Compound
EF
EF
EF
EF
EF
EF
EF
EF

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
Propene
38.07
0.11
47.18
0.11
152.04
0.40
236.40
0.42
Dichlorodifluoromethane (CFC-
12)
ND
0.13
ND
0.14
ND
0.46
ND
0.53
Chloromethane
2.47
0.11
2.99
0.12
10.49
0.43
6.55
0.46
1,2-Dichloro-1,1,2,2-
tetrafluoroethane (CFC 114)
ND
0.14
ND
0.15
ND
0.52
ND
0.56
Vinyl Chloride
ND
0.13
ND
0.14
ND
0.46
ND
0.53
1,3-Butadiene
5.87
0.16
10.67
0.17
65.98
0.60
95.26
0.67
Bromomethane
ND
0.14
ND
0.15
ND
0.52
ND
0.56
Chloroethane
ND
0.13
ND
0.14
ND
0.46
ND
0.53
Ethanol
ND
0.60
0.37
0.64
6.20
2.21
ND
2.43
Acetonitrile
1.16
0.14
1.42
0.14
4.02
0.49
5.29
0.56
Acrolein
25.38
0.13
26.67
0.14
134.83
0.46
137.60
0.53
Acetone
ND
0.59
ND
0.62
ND
2.12
ND
2.36
Trichlorofluoromethane
ND
0.13
ND
0.14
ND
0.46
ND
0.53
2-Propanol (Isopropyl Alcohol)
ND
0.32
ND
0.33
ND
1.18
ND
1.27
Acrylonitrile
0.57
0.13
0.64
0.14
2.15
0.46
2.61
0.53
1,1-Dichloroethene
ND
0.13
ND
0.14
ND
0.46
ND
0.53
Methylene Chloride
4.24
0.13
0.08
0.14
ND
0.46
ND
0.53
3-Chloro-1 -propene (Allyl Chloride)
ND
0.12
ND
0.13
ND
0.43
ND
0.49
Trichlorotrifluoroethane
ND
0.13
ND
0.14
ND
0.46
ND
0.53
Carbon Disulfide
0.35
0.11
0.35
0.12
2.29
0.43
1.48
0.46
trans-1,2-Dichloroethene
ND
0.14
ND
0.15
ND
0.52
ND
0.56
1,1-Dichloroethane
ND
0.12
ND
0.13
ND
0.43
ND
0.49
Methyl tert-Butyl Ether
ND
0.13
ND
0.14
ND
0.46
ND
0.53
Vinyl Acetate
36.48
0.49
51.29
0.51
189.34
1.81
116.43
1.98
2-Butanone (MEK)
5.38
0.16
7.36
0.17
36.98
0.57
41.95
0.64
cis-1,2-Dichloroethene
ND
0.12
ND
0.13
ND
0.43
ND
0.49
Ethyl Acetate
ND
0.27
0.57
0.29
ND
0.98
ND
1.06
n-Hexane
0.16
0.11
0.23
0.12
0.36
0.43
ND
0.46
Chloroform
ND
0.13
ND
0.14
ND
0.46
ND
0.53
Tetrahydrofuran (THF)
0.19
0.15
0.16
0.16
1.35
0.55
1.09
0.60
1,2-Dichloroethane
ND
0.12
ND
0.13
ND
0.43
ND
0.49
1,1,1-Trichloroethane
ND
0.13
ND
0.14
ND
0.46
ND
0.53
Benzene
60.23
0.12
71.73
0.13
220.80
0.43
260.98
0.49
Carbon Tetrachloride
ND
0.11
ND
0.12
ND
0.43
ND
0.46
Cyclohexane
ND
0.22
ND
0.23
ND
0.80
ND
0.88
1,2-Dichloropropane
ND
0.12
ND
0.13
ND
0.43
ND
0.49
42-A

-------
Bromodichloromethane
ND
0.11
ND
0.12
ND
0.43
ND
0.46
Trichloroethene
ND
0.11
ND
0.11
ND
0.40
ND
0.42
1,4-Dioxane
ND
0.12
ND
0.13
ND
0.43
ND
0.49
Methyl Methacrylate
4.92
0.24
6.77
0.25
31.56
0.86
23.99
0.95
n-Heptane
ND
0.13
0.18
0.14
ND
0.46
ND
0.53
cis-1,3-Dichloropropene
ND
0.11
ND
0.11
ND
0.40
ND
0.42
4-Methyl-2-pentanone
ND
0.12
ND
0.13
ND
0.43
ND
0.49
trans-1,3-Dichloropropene
ND
0.12
ND
0.13
ND
0.43
ND
0.49
1,1,2-Trichloroethane
ND
0.12
ND
0.13
ND
0.43
ND
0.49
Toluene
17.36
0.13
22.46
0.14
77.30
0.46
109.19
0.53
2-Hexanone
ND
0.12
0.18
0.13
0.72
0.43
0.64
0.49
Dibromochloromethane
ND
0.12
ND
0.13
ND
0.43
ND
0.49
1,2-Dibromoethane
ND
0.12
ND
0.13
ND
0.43
ND
0.49
n-Butyl Acetate
ND
0.12
ND
0.13
ND
0.43
ND
0.49
n-Octane
ND
0.14
ND
0.14
ND
0.49
ND
0.56
Tetrachloroethene
ND
0.11
ND
0.11
0.66
0.40
ND
0.42
Chlorobenzene
ND
0.12
ND
0.13
ND
0.43
ND
0.49
Ethyl benzene
3.49
0.12
4.72
0.13
21.23
0.43
30.34
0.49
/rj-,,p-Xylenes
1.90
0.22
2.46
0.25
8.61
0.83
14.82
0.92
Bromoform
ND
0.11
ND
0.12
ND
0.43
ND
0.46
Styrene
19.04
0.11
30.77
0.12
34.42
0.43
155.25
0.46
o-Xylene
0.81
0.11
1.07
0.12
3.44
0.43
6.35
0.46
n-Nonane
ND
0.11
ND
0.12
ND
0.43
ND
0.46
1,1,2,2-Tetrachloroethane
ND
0.11
ND
0.12
ND
0.43
ND
0.46
Cumene
0.33
0.11
0.45
0.12
2.12
0.43
3.25
0.46
alpha-Pinene
0.22
0.11
0.11
0.11
0.48
0.40
0.49
0.42
n-Propylbenzene
0.17
0.12
0.23
0.13
0.89
0.43
1.55
0.49
4-Ethyltoluene
0.15
0.12
0.19
0.13
0.55
0.43
1.23
0.49
1,3,5-Trimethyl benzene
ND
0.12
0.14
0.13
ND
0.43
0.88
0.49
1,2,4-Trimethyl benzene
0.24
0.11
0.35
0.12
0.55
0.43
2.26
0.46
Benzyl Chloride
ND
0.08
ND
0.09
ND
0.32
ND
0.34
1,3-Dichlorobenzene
ND
0.11
ND
0.12
ND
0.43
ND
0.46
1,4-Dichlorobenzene
ND
0.11
ND
0.11
ND
0.40
ND
0.42
1,2-Dichlorobenzene
ND
0.11
ND
0.12
ND
0.43
ND
0.46
d-Limonene
ND
0.11
ND
0.11
ND
0.40
0.42
0.42
1,2-Dibromo-3-chloropropane
ND
0.07
ND
0.08
ND
0.28
ND
0.30
1,2,4-Trichlorobenzene
ND
0.12
ND
0.13
ND
0.43
ND
0.49
Naphthalene
20.62
0.14
22.57
0.14
1.29
0.49
56.45
0.56
Hexachlorobutadiene
ND
0.11
ND
0.11
ND
0.40
ND
0.42
g/kg paperboard
Carbon Monoxide
15.11

16.24

29.30

36.04

Methane
0.28

0.34

1.09

1.55

43-A

-------
Carbon Dioxide
1633.37
1631.43
1608.84
1596.99
MCE
0.986
0.985
0.972
0.966
880
885
890
895
900
Table A-28. VOC emission factors from No-Spectra-kote fiberboard box and liner (NSB/NSL).
No-Spectra-kote box and liner (NSB/NSL)
12	3	4
44-A

-------


Method
detection
limit

Method
detection
limit

Method
detection
limit

Method
detection
limit
Compound
EF
EF
EF
EF
EF
EF
EF
EF

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
Propene
19.06
0.07
113.86
0.19
56.54
0.13
146.60
0.31
Dichlorodifluoromethane (CFC 12)
ND
0.08
0.05
0.24
0.03
0.16
ND
0.35
Chloromethane
0.97
0.07
2.21
0.21
1.50
0.14
2.53
0.33
1,2-Dichloro-1,1,2,2-
tetrafluoroethane (CFC 114)
ND
0.09
ND
0.26
ND
0.19
ND
0.39
Vinyl Chloride
ND
0.08
ND
0.24
ND
0.16
ND
0.35
1,3-Butadiene
8.85
0.10
42.37
0.32
23.98
0.21
61.26
0.46
Bromomethane
ND
0.09
ND
0.26
ND
0.19
ND
0.39
Chloroethane
ND
0.08
ND
0.24
ND
0.16
ND
0.35
Ethanol
1.02
0.37
8.10
1.11
ND
0.75
5.82
1.68
Aceto nit rile
0.53
0.08
2.12
0.25
1.32
0.17
2.41
0.37
Acrolein
1.36
0.08
116.51
0.24
54.82
0.16
131.28
0.35
Acetone
ND
0.35
ND
1.06
ND
0.74
127.98
1.62
Trichlorofluoromethane
ND
0.08
0.03
0.24
ND
0.16
ND
0.35
2-Propanol (Isopropyl Alcohol)
ND
0.19
ND
0.58
ND
0.39
ND
0.90
Acrylonitrile
0.19
0.08
0.64
0.24
0.46
0.16
0.90
0.35
1,1-Dichloroethene
ND
0.08
ND
0.24
ND
0.16
ND
0.35
Methylene Chloride
0.23
0.08
4.16
0.24
7.49
0.16
0.48
0.35
3-Chloro-1 -propene (Allyl Chloride)
ND
0.07
ND
0.22
ND
0.15
ND
0.33
Trichlorotrifluoroethane
ND
0.08
ND
0.24
ND
0.16
ND
0.35
Carbon Disulfide
0.29
0.07
0.42
0.21
2.91
0.14
0.66
0.33
trans-1,2-Dichloroethene
ND
0.09
ND
0.26
ND
0.19
ND
0.39
1,1-Dichloroethane
ND
0.07
ND
0.22
ND
0.15
ND
0.33
Methyl tert-Butyl Ether
ND
0.08
ND
0.24
ND
0.16
ND
0.35
Vinyl Acetate
50.37
0.30
ND
0.90
ND
0.62
ND
1.38
2-Butanone (MEK)
6.25
0.10
34.13
0.29
16.09
0.21
41.33
0.44
cis-1,2-Dichloroethene
ND
0.07
ND
0.22
ND
0.15
ND
0.33
Ethyl Acetate
ND
0.16
2.30
0.48
ND
0.33
ND
0.74
n-Hexane
0.04
0.07
1.97
0.21
0.32
0.14
0.38
0.33
Chloroform
ND
0.08
ND
0.24
ND
0.16
ND
0.35
Tetrahydrofuran (THF)
0.12
0.09
1.14
0.26
0.38
0.19
1.20
0.42
1,2-Dichloroethane
ND
0.07
ND
0.22
ND
0.15
ND
0.33
1,1,1-Trichloroethane
ND
0.08
ND
0.24
ND
0.16
ND
0.35
Benzene
33.99
0.07
100.53
0.22
78.75
0.15
150.90
0.33
Carbon Tetrachloride
ND
0.07
ND
0.21
ND
0.14
ND
0.33
Cyclohexane
ND
0.13
ND
0.40
ND
0.27
ND
0.61
1,2-Dichloropropane
ND
0.07
ND
0.22
ND
0.15
ND
0.33
Bromodichloromethane
ND
0.07
ND
0.21
ND
0.14
ND
0.33
45-A

-------
Trichloroethene
ND
0.07
ND
0.19
ND
0.13
ND
0.31
1,4-Dioxane
ND
0.07
ND
0.22
ND
0.15
ND
0.33
Methyl Methacrylate
ND
0.15
0.50
0.42
ND
0.29
ND
0.66
n-Heptane
ND
0.08
0.64
0.24
ND
0.16
ND
0.35
cis-1,3-Dichloropropene
ND
0.07
ND
0.19
ND
0.13
ND
0.31
4-Methyl-2-pentanone
ND
0.07
0.34
0.22
ND
0.15
ND
0.33
trans-1,3-Dichloropropene
ND
0.07
ND
0.22
ND
0.15
ND
0.33
1,1,2-Trichloroethane
ND
0.07
ND
0.22
ND
0.15
ND
0.33
Toluene
8.37
0.08
36.93
0.24
22.18
0.16
45.83
0.35
2-Hexanone
0.10
0.07
0.42
0.22
0.33
0.15
0.59
0.33
Dibromochloromethane
ND
0.07
ND
0.22
ND
0.15
ND
0.33
1,2-Dibromoethane
ND
0.07
ND
0.22
ND
0.15
ND
0.33
n-Butyl Acetate
ND
0.07
ND
0.22
ND
0.15
ND
0.33
n-Octane
ND
0.08
0.45
0.25
ND
0.17
ND
0.37
Tetrachloroethene
ND
0.07
ND
0.19
ND
0.13
ND
0.31
Chlorobenzene
ND
0.07
ND
0.22
ND
0.15
ND
0.33
Ethyl benzene
1.24
0.07
5.83
0.22
3.43
0.15
7.88
0.33
/rj-,,p-Xylenes
1.24
0.14
7.68
0.42
4.28
0.29
8.97
0.63
Bromoform
ND
0.07
ND
0.21
ND
0.14
ND
0.33
Styrene
4.22
0.07
15.36
0.21
10.11
0.14
21.88
0.33
o-Xylene
0.52
0.07
2.91
0.21
1.71
0.14
3.72
0.33
n-Nonane
ND
0.07
ND
0.21
ND
0.14
ND
0.33
1,1,2,2-Tetrachloroethane
ND
0.07
ND
0.21
ND
0.14
ND
0.33
Cumene
ND
0.07
0.29
0.21
0.17
0.14
0.42
0.33
alpha-Pinene
0.15
0.07
0.37
0.19
0.39
0.13
0.57
0.31
n-Propylbenzene
ND
0.07
0.34
0.22
0.21
0.15
0.39
0.33
4-Ethyltoluene
0.12
0.07
0.69
0.22
0.36
0.15
0.79
0.33
1,3,5-Trimethyl benzene
ND
0.07
0.40
0.22
0.22
0.15
0.44
0.33
1,2,4-Trimethyl benzene
0.18
0.07
1.30
0.21
0.74
0.14
1.40
0.33
Benzyl Chloride
ND
0.05
ND
0.15
ND
0.10
ND
0.24
1,3-Dichlorobenzene
ND
0.07
ND
0.21
ND
0.14
ND
0.33
1,4-Dichlorobenzene
ND
0.07
ND
0.19
ND
0.13
ND
0.31
1,2-Dichlorobenzene
ND
0.07
ND
0.21
ND
0.14
ND
0.33
d-Limonene
0.13
0.07
0.48
0.19
0.27
0.13
0.33
0.31
1,2-Dibromo-3-chloropropane
ND
0.05
ND
0.14
ND
0.09
ND
0.21
1,2,4-Trichlorobenzene
ND
0.07
ND
0.22
ND
0.15
ND
0.33
Naphthalene
9.80
0.08
14.56
0.25
18.85
0.17
37.20
0.37
Hexachlorobutadiene
ND
0.07
ND
0.19
ND
0.13
ND
0.31
g/kg paperboard
Carbon Monoxide
15.62

26.44

19.27

30.13

Methane
0.17

0.87

0.53

1.16

46-A

-------
Carbon Dioxide
1647.17
1628.25
1640.46
1621.64
MCE
0.985
0.975
0.982
0.972
905
910
915
920
925
Table A-29. VOC emission factors from current fiberboard box, no wet strength (NWS).
Current Fiberboard box, no wet strength (NWS)
12	3	4
47-A

-------


Method
detection
limit

Method
detection
limit

Method
detection
limit

Method
detection
limit

EF
EF
EF
EF
EF
EF
EF
EF

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
Propene
62.97
0.18
44.62
0.18
52.42
0.17
42.07
0.13
Dichlorodifluoromethane (CFC-
12)
ND
0.22
ND
0.22
0.02
0.21
ND
0.16
Chloromethane
0.71
0.20
0.73
0.20
0.51
0.19
0.55
0.14
1,2-Dichloro-1,1,2,2-
tetrafluoroethane (CFC 114)
ND
0.25
ND
0.25
ND
0.24
ND
0.18
Vinyl Chloride
ND
0.22
ND
0.22
ND
0.21
ND
0.16
1,3-Butadiene
31.48
0.29
21.72
0.29
23.83
0.29
19.28
0.21
Bromomethane
ND
0.25
ND
0.25
ND
0.24
ND
0.18
Chloroethane
ND
0.22
ND
0.22
ND
0.21
ND
0.16
Ethanol
2.76
1.07
ND
1.04
ND
1.00
ND
0.77
Acetonitrile
0.73
0.24
0.68
0.24
0.52
0.22
0.56
0.17
Acrolein
31.97
0.22
44.62
0.22
33.36
0.21
33.31
0.16
Acetone
41.12
1.02
ND
1.01
ND
0.95
ND
0.74
Trichlorofluoromethane
ND
0.22
ND
0.22
0.02
0.21
ND
0.16
2-Propanol (Isopropyl Alcohol)
ND
0.53
ND
0.54
ND
0.52
ND
0.40
Acrylonitrile
ND
0.22
0.36
0.22
0.24
0.21
0.23
0.16
1,1-Dichloroethene
ND
0.22
ND
0.22
ND
0.21
ND
0.16
Methylene Chloride
12.93
0.22
7.94
0.22
0.24
0.21
5.56
0.16
3-Chloro-1 -propene (Allyl Chloride)
ND
0.21
ND
0.21
ND
0.20
ND
0.15
T richlorotrifluoroethane
ND
0.22
ND
0.22
ND
0.21
ND
0.16
Carbon Disulfide
2.66
0.20
1.99
0.20
1.41
0.19
0.96
0.14
trans-1,2-Dichloroethene
ND
0.25
ND
0.25
ND
0.24
ND
0.18
1,1-Dichloroethane
ND
0.21
ND
0.21
ND
0.20
ND
0.15
Methyl tert-Butyl Ether
ND
0.22
ND
0.22
ND
0.21
ND
0.16
Vinyl Acetate
58.13
0.87
38.67
0.83
ND
0.81
ND
0.63
2-Butanone (MEK)
14.00
0.28
8.89
0.27
7.36
0.26
8.05
0.21
cis-1,2-Dichloroethene
ND
0.21
ND
0.21
ND
0.20
ND
0.15
Ethyl Acetate
ND
0.46
ND
0.45
1.00
0.43
ND
0.33
n-Hexane
0.22
0.20
0.14
0.20
0.61
0.19
0.43
0.14
Chloroform
ND
0.22
ND
0.22
ND
0.21
ND
0.16
Tetrahydrofuran (THF)
0.73
0.26
0.42
0.26
0.33
0.24
0.30
0.19
1,2-Dichloroethane
ND
0.21
ND
0.21
ND
0.20
ND
0.15
1,1,1-Trichloroethane
ND
0.22
ND
0.22
ND
0.21
ND
0.16
Benzene
125.78
0.21
121.87
0.21
102.37
0.20
92.86
0.15
Carbon Tetrachloride
0.01
0.20
ND
0.20
ND
0.19
ND
0.14
Cyclohexane
ND
0.38
ND
0.39
ND
0.36
ND
0.28
1,2-Dichloropropane
ND
0.21
ND
0.21
ND
0.20
ND
0.15
Bromodichloromethane
ND
0.20
ND
0.20
ND
0.19
ND
0.14
48-A

-------
Trichloroethene
ND
0.18
ND
0.18
ND
0.17
ND
0.13
1,4-Dioxane
ND
0.21
ND
0.21
ND
0.20
ND
0.15
Methyl Methacrylate
ND
0.41
ND
0.42
ND
0.38
ND
0.30
n-Heptane
ND
0.22
ND
0.22
ND
0.21
ND
0.16
cis-1,3-Dichloropropene
ND
0.18
ND
0.18
ND
0.17
ND
0.13
4-Methyl-2-pentanone
ND
0.21
ND
0.21
ND
0.20
ND
0.15
trans-1,3-Dichloropropene
ND
0.21
ND
0.21
ND
0.20
ND
0.15
1,1,2-Trichloroethane
ND
0.21
ND
0.21
ND
0.20
ND
0.15
Toluene
32.19
0.22
26.32
0.22
26.08
0.21
20.94
0.16
2-Hexanone
0.31
0.21
0.23
0.21
ND
0.20
ND
0.15
Dibromochloromethane
ND
0.21
ND
0.21
ND
0.20
ND
0.15
1,2-Dibromoethane
ND
0.21
ND
0.21
ND
0.20
ND
0.15
n-Butyl Acetate
ND
0.21
ND
0.21
ND
0.20
ND
0.15
n- Octane
ND
0.24
ND
0.24
ND
0.22
ND
0.17
Tetrachloroethene
ND
0.18
ND
0.18
ND
0.17
ND
0.13
Chlorobenzene
ND
0.21
ND
0.21
ND
0.20
ND
0.15
Ethyl benzene
4.75
0.21
3.87
0.21
4.29
0.20
3.33
0.15
m-, p-Xylenes
4.84
0.39
3.27
0.39
3.81
0.38
2.98
0.28
Bromoform
ND
0.20
ND
0.20
ND
0.19
ND
0.14
Styrene
15.02
0.20
13.09
0.20
13.34
0.19
11.04
0.14
o-Xylene
1.94
0.20
1.34
0.20
1.52
0.19
1.21
0.14
n-Nonane
ND
0.20
ND
0.20
ND
0.19
ND
0.14
1,1,2,2-Tetrachloroethane
ND
0.20
ND
0.20
ND
0.19
ND
0.14
Cumene
0.23
0.20
0.21
0.20
0.19
0.19
0.17
0.14
alpha-Pinene
2.42
0.18
0.38
0.18
0.15
0.17
0.40
0.13
n-Propylbenzene
ND
0.21
ND
0.21
ND
0.20
ND
0.15
4-Ethyltoluene
0.46
0.21
0.33
0.21
0.38
0.20
0.26
0.15
1,3,5-Trimethyl benzene
0.23
0.21
ND
0.21
ND
0.20
ND
0.15
1,2,4-Trimethyl benzene
0.73
0.20
0.42
0.20
0.57
0.19
0.40
0.14
Benzyl Chloride
ND
0.15
ND
0.14
ND
0.14
ND
0.11
1,3-Dichlorobenzene
ND
0.20
ND
0.20
ND
0.19
ND
0.14
1,4-Dichlorobenzene
ND
0.18
ND
0.18
ND
0.17
ND
0.13
1,2-Dichlorobenzene
ND
0.20
ND
0.20
ND
0.19
ND
0.14
d-Limonene
2.13
0.18
0.39
0.18
0.33
0.17
0.30
0.13
1,2-Dibromo-3-chloropropane
ND
0.13
ND
0.13
ND
0.12
ND
0.09
1,2,4-Trichlorobenzene
ND
0.21
ND
0.21
ND
0.20
ND
0.15
Naphthalene
36.33
0.24
35.70
0.24
30.97
0.22
31.56
0.17
Hexachlorobutadiene
ND
0.18
ND
0.18
ND
0.17
ND
0.13
g/kg paperboard
Carbon Monoxide
23.90

23.90

16.68

17.50

Methane
0.48

0.47

0.39

0.38

49-A

-------
Carbon Dioxide
1668.33
1668.36
1679.92
1678.65
MCE
0.978
0.978
0.985
0.984
930
50-A

-------
Appendix B: Data for each sample collected from OB of MRE pouches.
Table B-l. PCDD/PCDF data for 0 % NEW 01.
Sample ID	PS-1000LD-073015-01 MCE	0.941667	Page 1 (2)
Sampling volume (m3)	122.3
Carbon sampled (g)	68.4
Carbon sampled (mg/m3)	559.6
Carbon fraction	0.4



TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total
LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ng/sample
ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
1.02E-02

1.02E-02
1.02E-02
8.34E-05
8.34E-05
8.34E-05
1,2,3,7,8- PeCDD
1.92E-02

1.92E-02
1.92E-02
1.57E-04
1.57E-04
1.57E-04
1,2,3,4,7,8- HxCDD
1.26E-02

1.26E-03
1.26E-03
1.03E-04
1.03E-05
1.03E-05
1,2,3,6,7,8- HxCDD
ND
1.37E-02
0.00E+00
1.37E-03
ND
0.00E+00
1.12E-05
1,2,3,7,8,9- HxCDD
ND
1.45E-02
0.00E+00
1.45E-03
ND
0.00E+00
1.18E-05
1,2,3,4,6,7,8- HpCDD
1.95E-01

1.95E-03
1.95E-03
1.59E-03
1.59E-05
1.59E-05
1,2,3,4,6,7,8,9 - OCDD
5.48E-01

1.64E-04
1.64E-04
4.48E-03
1.34E-06
1.34E-06
2,3,7,8 - TCDF
6.10E-01

6.10E-02
6.10E-02
4.98E-03
4.98E-04
4.98E-04
1,2,3,7,8- PeCDF
1.52E-01

4.55E-03
4.55E-03
1.24E-03
3.72E-05
3.72E-05
2,3,4,7,8- PeCDF
1.48E-01

4.45E-02
4.45E-02
1.21 E-03
3.64E-04
3.64E-04
1,2,3,4,7,8- HxCDF
5.28E-02

5.28E-03
5.28E-03
4.32E-04
4.32E-05
4.32E-05
1,2,3,6,7,8- HxCDF
4.20E-02

4.20E-03
4.20E-03
3.43E-04
3.43E-05
3.43E-05
1,2,3,7,8,9- HxCDF
ND
1.66E-02
0.00E+00
1.66E-03
ND
0.00E+00
1.36E-05
2,3,4,6,7,8 - HxCDF
3.44E-02

3.44E-03
3.44E-03
2.81 E-04
2.81 E-05
2.81 E-05
1,2,3,4,6,7,8- HpCDF
5.26E-02

5.26E-04
5.26E-04
4.30E-04
4.30E-06
4.30E-06
1,2,3,4,7,8,9- HpCDF
ND
2.27E-02
0.00E+00
2.27E-04
ND
0.00E+00
1.86E-06
1,2,3,4,6,7,8,9-OCDF
4.28E-02

1.28E-05
1.28E-05
3.50E-04
1.05E-07
1.05E-07
TeCDD Total
2.10E-01



1.72E-03


PeCDD Total
1.39E-01



1.14E-03


HxCDD Total
1.56E-01



1.27E-03


HpCDD Total
3.46E-01



2.83E-03


OCDD
5.48E-01



4.48E-03


TeCDF Total
8.34E+00



6.82E-02


PeCDF Total
1.37E+00



1.12E-02


HxCDF Total
2.73E-01



2.23E-03


HpCDF Total
5.26E-02



4.30E-04


OCDF
4.78E-02



3.91 E-04


PCDD Total
1.40E+00



1.14E-02


PCDF Total
1.01 E+01



8.24E-02


PCDD/PCDF Total
1.15E+01



9.39E-02


PCDD TEQ Total


3.28E-02
3.56E-02

2.68E-04
2.91 E-04
PCDF TEQ Total


1.23E-01
1.25E-01

1.01 E-03
1.03E-03
PCDD/PCDF TEQ Total


1.56E-01
1.61 E-01

1.28E-03
1.32E-03
Sample ID	PS-100QLD-073015-01	Page 2 (2)
1-B

-------

EF
EF
EF
EF
EF
EF

Total
TEQ
TEQ
Total
TEQ
TEQ
Isomer.

ng/g Carbon


ng/kg fuel



ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
1.49E-04
1.49E-04
1.49E-04
6.27E-02
6.27E-02
6.27E-02
1,2,3,7,8- PeCDD
2.81 E-04
2.81 E-04
2.81 E-04
1.18E-01
1.18E-01
1.18E-01
1,2,3,4,7,8- HxCDD
1.84E-04
1.84E-05
1.84E-05
7.75E-02
7.75E-03
7.75E-03
1,2,3,6,7,8- HxCDD
ND
0.00E+00
2.00E-05
ND
0.00E+00
8.43E-03
1,2,3,7,8,9- HxCDD
ND
0.00E+00
2.11 E-05
ND
0.00E+00
8.89E-03
1,2,3,4,6,7,8- HpCDD
2.85E-03
2.85E-05
2.85E-05
1.20E+00
1.20E-02
1.20E-02
1,2,3,4,6,7,8,9 - OCDD
8.01 E-03
2.40E-06
2.40E-06
3.37E+00
1.01 E-03
1.01 E-03
2,3,7,8 - TCDF
8.91 E-03
8.91 E-04
8.91 E-04
3.75E+00
3.75E-01
3.75E-01
1,2,3,7,8- PeCDF
2.22E-03
6.65E-05
6.65E-05
9.32E-01
2.80E-02
2.80E-02
2,3,4,7,8- PeCDF
2.17E-03
6.50E-04
6.50E-04
9.13E-01
2.74E-01
2.74E-01
1,2,3,4,7,8- HxCDF
7.71 E-04
7.71 E-05
7.71 E-05
3.25E-01
3.25E-02
3.25E-02
1,2,3,6,7,8- HxCDF
6.14E-04
6.14E-05
6.14E-05
2.58E-01
2.58E-02
2.58E-02
1,2,3,7,8,9- HxCDF
ND
0.00E+00
2.43E-05
ND
0.00E+00
1.02E-02
2,3,4,6,7,8 - HxCDF
5.03E-04
5.03E-05
5.03E-05
2.12E-01
2.12E-02
2.12E-02
1,2,3,4,6,7,8- HpCDF
7.69E-04
7.69E-06
7.69E-06
3.24E-01
3.24E-03
3.24E-03
1,2,3,4,7,8,9- HpCDF
ND
0.00E+00
3.32E-06
ND
0.00E+00
1.40E-03
1,2,3,4,6,7,8,9-OCDF
6.25E-04
1.88E-07
1.88E-07
2.63E-01
7.90E-05
7.90E-05
TeCDD Total
3.07E-03


1.29E+00


PeCDD Total
2.03E-03


8.56E-01


HxCDD Total
2.27E-03


9.57E-01


HpCDD Total
5.06E-03


2.13E+00


OCDD
8.01 E-03


3.37E+00


TeCDF Total
1.22E-01


5.13E+01


PeCDF Total
2.00E-02


8.43E+00


HxCDF Total
3.99E-03


1.68E+00


HpCDF Total
7.69E-04


3.24E-01


OCDF
6.98E-04


2.94E-01


PCDD Total
2.04E-02


8.61 E+00


PCDF Total
1.47E-01


6.20E+01


PCDD/PCDF Total
1.68E-01


7.06E+01


PCDD TEQ Total

4.79E-04
5.20E-04

2.02E-01
2.19E-01
PCDF TEQ Total

1.80E-03
1.83E-03

7.59E-01
7.71 E-01
PCDD/PCDF TEQ Total

2.28E-03
2.35E-03

9.61 E-01
9.90E-01
935
940
Table B-2. PCDD/PCDF data for 0 % NEW 02.
2-B

-------
Sample ID	PS-1000LD2-073015-02 MCE	0.943944	Page 1 (2)
Sampling volume (m3)	101.2
Carbon sampled (g)	58.8
Carbon sampled (mg/m3)	581.2
Carbon fraction	0.4



TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total
LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ng/sample
ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
3.94E-02

3.94E-02
3.94E-02
3.90E-04
3.90E-04
3.90E-04
1,2,3,7,8- PeCDD
1.66E-02

1.66E-02
1.66E-02
1.64E-04
1.64E-04
1.64E-04
1,2,3,4,7,8- HxCDD
5.40E-03

5.40E-04
5.40E-04
5.34E-05
5.34E-06
5.34E-06
1,2,3,6,7,8- HxCDD
1.62E-02

1.62E-03
1.62E-03
1.60E-04
1.60E-05
1.60E-05
1,2,3,7,8,9- HxCDD
1.38E-02

1.38E-03
1.38E-03
1.36E-04
1.36E-05
1.36E-05
1,2,3,4,6,7,8- HpCDD
1.69E-01

1.69E-03
1.69E-03
1.67E-03
1.67E-05
1.67E-05
1,2,3,4,6,7,8,9 - OCDD
4.99E-01

1.50E-04
1.50E-04
4.94E-03
1.48E-06
1.48E-06
2,3,7,8 - TCDF
7.86E-01

7.86E-02
7.86E-02
7.77E-03
7.77E-04
7.77E-04
1,2,3,7,8- PeCDF
1.63E-01

4.90E-03
4.90E-03
1.62E-03
4.85E-05
4.85E-05
2,3,4,7,8- PeCDF
1.63E-01

4.88E-02
4.88E-02
1.61 E-03
4.82E-04
4.82E-04
1,2,3,4,7,8- HxCDF
4.00E-02

4.00E-03
4.00E-03
3.95E-04
3.95E-05
3.95E-05
1,2,3,6,7,8- HxCDF
3.56E-02

3.56E-03
3.56E-03
3.52E-04
3.52E-05
3.52E-05
1,2,3,7,8,9- HxCDF
1.62E-02

1.62E-03
1.62E-03
1.60E-04
1.60E-05
1.60E-05
2,3,4,6,7,8 - HxCDF
3.28E-02

3.28E-03
3.28E-03
3.24E-04
3.24E-05
3.24E-05
1,2,3,4,6,7,8- HpCDF
4.24E-02

4.24E-04
4.24E-04
4.19E-04
4.19E-06
4.19E-06
1,2,3,4,7,8,9- HpCDF
5.80E-03

5.80E-05
5.80E-05
5.73E-05
5.73E-07
5.73E-07
1,2,3,4,6,7,8,9-OCDF
3.12E-02

9.36E-06
9.36E-06
3.08E-04
9.25E-08
9.25E-08
TeCDD Total
3.36E-01



3.33E-03


PeCDD Total
1.55E-01



1.53E-03


HxCDD Total
1.79E-01



1.77E-03


HpCDD Total
2.99E-01



2.96E-03


OCDD
4.99E-01



4.94E-03


TeCDF Total
1.12E+01



1.10E-01


PeCDF Total
1.62E+00



1.60E-02


HxCDF Total
2.96E-01



2.92E-03


HpCDF Total
6.72E-02



6.64E-04


OCDF
3.12E-02



3.08E-04


PCDD Total
1.47E+00



1.45E-02


PCDF Total
1.32E+01



1.30E-01


PCDD/PCDF Total
1.46E+01



1.45E-01


PCDD TEQ Total


6.14E-02
6.14E-02

6.07E-04
6.07E-04
PCDF TEQ Total


1.45E-01
1.45E-01

1.44E-03
1.44E-03
PCDD/PCDF TEQ Total


2.07E-01
2.07E-01

2.04E-03
2.04E-03
Sample ID	PS-1000LD2-073015-02	Page 2 (2)
3-B

-------

EF
EF
EF
EF
EF
EF

Total
TEQ
TEQ
Total
TEQ
TEQ
Isomer.

ng/g Carbon


ng/kg fuel



ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
6.70E-04
6.70E-04
6.70E-04
2.82E-01
2.82E-01
2.82E-01
1,2,3,7,8- PeCDD
2.82E-04
2.82E-04
2.82E-04
1.19E-01
1.19E-01
1.19E-01
1,2,3,4,7,8- HxCDD
9.19E-05
9.19E-06
9.19E-06
3.87E-02
3.87E-03
3.87E-03
1,2,3,6,7,8- HxCDD
2.76E-04
2.76E-05
2.76E-05
1.16E-01
1.16E-02
1.16E-02
1,2,3,7,8,9- HxCDD
2.35E-04
2.35E-05
2.35E-05
9.88E-02
9.88E-03
9.88E-03
1,2,3,4,6,7,8- HpCDD
2.87E-03
2.87E-05
2.87E-05
1.21E+00
1.21E-02
1.21 E-02
1,2,3,4,6,7,8,9 - OCDD
8.50E-03
2.55E-06
2.55E-06
3.58E+00
1.07E-03
1.07E-03
2,3,7,8 - TCDF
1.34E-02
1.34E-03
1.34E-03
5.63E+00
5.63E-01
5.63E-01
1,2,3,7,8- PeCDF
2.78E-03
8.34E-05
8.34E-05
1.17E+00
3.51 E-02
3.51 E-02
2,3,4,7,8- PeCDF
2.77E-03
8.30E-04
8.30E-04
1.16E+00
3.49E-01
3.49E-01
1,2,3,4,7,8- HxCDF
6.80E-04
6.80E-05
6.80E-05
2.86E-01
2.86E-02
2.86E-02
1,2,3,6,7,8- HxCDF
6.06E-04
6.06E-05
6.06E-05
2.55E-01
2.55E-02
2.55E-02
1,2,3,7,8,9- HxCDF
2.76E-04
2.76E-05
2.76E-05
1.16E-01
1.16E-02
1.16E-02
2,3,4,6,7,8 - HxCDF
5.58E-04
5.58E-05
5.58E-05
2.35E-01
2.35E-02
2.35E-02
1,2,3,4,6,7,8- HpCDF
7.21 E-04
7.21 E-06
7.21 E-06
3.04E-01
3.04E-03
3.04E-03
1,2,3,4,7,8,9- HpCDF
9.87E-05
9.87E-07
9.87E-07
4.15E-02
4.15E-04
4.15E-04
1,2,3,4,6,7,8,9-OCDF
5.31 E-04
1.59E-07
1.59E-07
2.23E-01
6.70E-05
6.70E-05
TeCDD Total
5.72E-03


2.41 E+00


PeCDD Total
2.63E-03


1.11 E+00


HxCDD Total
3.04E-03


1.28E+00


HpCDD Total
5.09E-03


2.14E+00


OCDD
8.50E-03


3.58E+00


TeCDF Total
1.90E-01


7.99E+01


PeCDF Total
2.76E-02


1.16E+01


HxCDF Total
5.03E-03


2.12E+00


HpCDF Total
1.14E-03


4.81 E-01


OCDF
5.31 E-04


2.23E-01


PCDD Total
2.50E-02


1.05E+01


PCDF Total
2.24E-01


9.43E+01


PCDD/PCDF Total
2.49E-01


1.05E+02


PCDD TEQ Total

1.04E-03
1.04E-03

4.39E-01
4.39E-01
PCDF TEQ Total

2.47E-03
2.47E-03

1.04E+00
1.04E+00
PCDD/PCDF TEQ Total

3.51 E-03
3.51 E-03

1.48E+00
1.48E+00
945
Table B-3. PCDD/PCDF data for 0 % NEW 03.
4-B

-------
Sample ID	PS-1000LD3-073115-02 MCE	0.920669	Page 1 (2)
Sampling volume (m3)	118.2
Carbon sampled (g)	63.9
Carbon sampled (mg/m3)	540.5
Carbon fraction	0.4


TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
8.12E-02
8.12E-02
8.12E-02
6.87E-04
6.87E-04
6.87E-04
1,2,3,7,8- PeCDD
2.38E-02
2.38E-02
2.38E-02
2.01 E-04
2.01 E-04
2.01 E-04
1,2,3,4,7,8- HxCDD
6.80E-03
6.80E-04
6.80E-04
5.75E-05
5.75E-06
5.75E-06
1,2,3,6,7,8- HxCDD
1.52E-02
1.52E-03
1.52E-03
1.29E-04
1.29E-05
1.29E-05
1,2,3,7,8,9- HxCDD
1.24E-02
1.24E-03
1.24E-03
1.05E-04
1.05E-05
1.05E-05
1,2,3,4,6,7,8- HpCDD
1.69E-01
1.69E-03
1.69E-03
1.43E-03
1.43E-05
1.43E-05
1,2,3,4,6,7,8,9 - OCDD
4.52E-01
1.36E-04
1.36E-04
3.82E-03
1.15E-06
1.15E-06
2,3,7,8 - TCDF
1.82E+00
1.82E-01
1.82E-01
1.54E-02
1.54E-03
1.54E-03
1,2,3,7,8- PeCDF
3.70E-01
1.11E-02
1.11E-02
3.13E-03
9.38E-05
9.38E-05
2,3,4,7,8- PeCDF
4.12E-01
1.24E-01
1.24E-01
3.49E-03
1.05E-03
1.05E-03
1,2,3,4,7,8- HxCDF
7.00E-02
7.00E-03
7.00E-03
5.92E-04
5.92E-05
5.92E-05
1,2,3,6,7,8- HxCDF
6.74E-02
6.74E-03
6.74E-03
5.70E-04
5.70E-05
5.70E-05
1,2,3,7,8,9- HxCDF
3.14E-02
3.14E-03
3.14E-03
2.66E-04
2.66E-05
2.66E-05
2,3,4,6,7,8 - HxCDF
5.72E-02
5.72E-03
5.72E-03
4.84E-04
4.84E-05
4.84E-05
1,2,3,4,6,7,8- HpCDF
5.00E-02
5.00E-04
5.00E-04
4.23E-04
4.23E-06
4.23E-06
1,2,3,4,7,8,9- HpCDF
1.14E-02
1.14E-04
1.14E-04
9.64E-05
9.64E-07
9.64E-07
1,2,3,4,6,7,8,9-OCDF
3.34E-02
1.00E-05
1.00E-05
2.82E-04
8.47E-08
8.47E-08
TeCDD Total
4.12E-01


3.48E-03


PeCDD Total
1.38E-01


1.17E-03


HxCDD Total
1.74E-01


1.47E-03


HpCDD Total
2.99E-01


2.53E-03


OCDD
4.52E-01


3.82E-03


TeCDF Total
2.20E+01


1.86E-01


PeCDF Total
3.18E+00


2.69E-02


HxCDF Total
5.04E-01


4.26E-03


HpCDF Total
9.92E-02


8.39E-04


OCDF
3.34E-02


2.82E-04


PCDD Total
1.48E+00


1.25E-02


PCDF Total
2.59E+01


2.19E-01


PCDD/PCDF Total
2.73E+01


2.31 E-01


PCDD TEQ Total

1.10E-01
1.10E-01

9.33E-04
9.33E-04
PCDF TEQ Total

3.40E-01
3.40E-01

2.87E-03
2.87E-03
PCDD/PCDF TEQ Total

4.50E-01
4.50E-01

3.81 E-03
3.81 E-03
Sample ID	PS-1000LD3-073115-02	Page 2 (2)
5-B

-------

EF
EF
EF
EF
EF
EF

Total
TEQ
TEQ
Total
TEQ
TEQ
Isomer.

ng/g Carbon


ng/kg fuel



ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
1.27E-03
1.27E-03
1.27E-03
5.35E-01
5.35E-01
5.35E-01
1,2,3,7,8- PeCDD
3.72E-04
3.72E-04
3.72E-04
1.57E-01
1.57E-01
1.57E-01
1,2,3,4,7,8- HxCDD
1.06E-04
1.06E-05
1.06E-05
4.48E-02
4.48E-03
4.48E-03
1,2,3,6,7,8- HxCDD
2.38E-04
2.38E-05
2.38E-05
1.00E-01
1.00E-02
1.00E-02
1,2,3,7,8,9- HxCDD
1.94E-04
1.94E-05
1.94E-05
8.17E-02
8.17E-03
8.17E-03
1,2,3,4,6,7,8- HpCDD
2.65E-03
2.65E-05
2.65E-05
1.11E+00
1.11 E-02
1.11 E-02
1,2,3,4,6,7,8,9 - OCDD
7.07E-03
2.12E-06
2.12E-06
2.98E+00
8.93E-04
8.93E-04
2,3,7,8 - TCDF
2.85E-02
2.85E-03
2.85E-03
1.20E+01
1.20E+00
1.20E+00
1,2,3,7,8- PeCDF
5.79E-03
1.74E-04
1.74E-04
2.44E+00
7.31 E-02
7.31 E-02
2,3,4,7,8- PeCDF
6.45E-03
1.93E-03
1.93E-03
2.71 E+00
8.14E-01
8.14E-01
1,2,3,4,7,8- HxCDF
1.10E-03
1.10E-04
1.10E-04
4.61 E-01
4.61 E-02
4.61 E-02
1,2,3,6,7,8- HxCDF
1.05E-03
1.05E-04
1.05E-04
4.44E-01
4.44E-02
4.44E-02
1,2,3,7,8,9- HxCDF
4.91 E-04
4.91 E-05
4.91 E-05
2.07E-01
2.07E-02
2.07E-02
2,3,4,6,7,8 - HxCDF
8.95E-04
8.95E-05
8.95E-05
3.77E-01
3.77E-02
3.77E-02
1,2,3,4,6,7,8- HpCDF
7.82E-04
7.82E-06
7.82E-06
3.29E-01
3.29E-03
3.29E-03
1,2,3,4,7,8,9- HpCDF
1.78E-04
1.78E-06
1.78E-06
7.51 E-02
7.51 E-04
7.51 E-04
1,2,3,4,6,7,8,9-OCDF
5.23E-04
1.57E-07
1.57E-07
2.20E-01
6.60E-05
6.60E-05
TeCDD Total
6.44E-03


2.71 E+00


PeCDD Total
2.16E-03


9.10E-01


HxCDD Total
2.73E-03


1.15E+00


HpCDD Total
4.68E-03


1.97E+00


OCDD
7.07E-03


2.98E+00


TeCDF Total
3.45E-01


1.45E+02


PeCDF Total
4.98E-02


2.10E+01


HxCDF Total
7.89E-03


3.32E+00


HpCDF Total
1.55E-03


6.53E-01


OCDF
5.23E-04


2.20E-01


PCDD Total
2.31 E-02


9.72E+00


PCDF Total
4.05E-01


1.70E+02


PCDD/PCDF Total
4.28E-01


1.80E+02


PCDD TEQ Total

1.73E-03
1.73E-03

7.26E-01
7.26E-01
PCDF TEQ Total

5.32E-03
5.32E-03

2.24E+00
2.24E+00
PCDD/PCDF TEQ Total

7.04E-03
7.04E-03

2.97E+00
2.97E+00
950
Table B-4. PCDD/PCDF data for 32 % NEW 01.
Sample ID	PS-32NEW-080315-02	MCE	0.935541	Page 1 (2)
6-B

-------
Sampling volume (m3)	105.5
Carbon sampled (g)	58.4
Carbon sampled (mg/m3)	554.0
Carbon fraction	0.4


TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
9.40E-03
9.40E-03
9.40E-03
8.91 E-05
8.91 E-05
8.91 E-05
1,2,3,7,8- PeCDD
1.20E-02
1.20E-02
1.20E-02
1.14E-04
1.14E-04
1.14E-04
1,2,3,4,7,8- HxCDD
4.60E-03
4.60E-04
4.60E-04
4.36E-05
4.36E-06
4.36E-06
1,2,3,6,7,8- HxCDD
1.22E-02
1.22E-03
1.22E-03
1.16E-04
1.16E-05
1.16E-05
1,2,3,7,8,9- HxCDD
1.22E-02
1.22E-03
1.22E-03
1.16E-04
1.16E-05
1.16E-05
1,2,3,4,6,7,8- HpCDD
1.21E-01
1.21 E-03
1.21 E-03
1.15E-03
1.15E-05
1.15E-05
1,2,3,4,6,7,8,9 - OCDD
3.18E-01
9.53E-05
9.53E-05
3.01 E-03
9.04E-07
9.04E-07
2,3,7,8 - TCDF
4.37E-01
4.37E-02
4.37E-02
4.14E-03
4.14E-04
4.14E-04
1,2,3,7,8- PeCDF
1.25E-01
3.75E-03
3.75E-03
1.19E-03
3.56E-05
3.56E-05
2,3,4,7,8- PeCDF
1.35E-01
4.04E-02
4.04E-02
1.28E-03
3.83E-04
3.83E-04
1,2,3,4,7,8- HxCDF
4.48E-02
4.48E-03
4.48E-03
4.25E-04
4.25E-05
4.25E-05
1,2,3,6,7,8- HxCDF
4.14E-02
4.14E-03
4.14E-03
3.93E-04
3.93E-05
3.93E-05
1,2,3,7,8,9- HxCDF
2.42E-02
2.42E-03
2.42E-03
2.29E-04
2.29E-05
2.29E-05
2,3,4,6,7,8 - HxCDF
3.96E-02
3.96E-03
3.96E-03
3.75E-04
3.75E-05
3.75E-05
1,2,3,4,6,7,8- HpCDF
4.20E-02
4.20E-04
4.20E-04
3.98E-04
3.98E-06
3.98E-06
1,2,3,4,7,8,9- HpCDF
1.40E-02
1.40E-04
1.40E-04
1.33E-04
1.33E-06
1.33E-06
1,2,3,4,6,7,8,9-OCDF
2.16E-02
6.48E-06
6.48E-06
2.05E-04
6.14E-08
6.14E-08
TeCDD Total
1.54E-01


1.46E-03


PeCDD Total
9.86E-02


9.35E-04


HxCDD Total
1.25E-01


1.18E-03


HpCDD Total
2.01 E-01


1.91 E-03


OCDD
3.18E-01


3.01 E-03


TeCDF Total
7.04E+00


6.67E-02


PeCDF Total
1.28E+00


1.21 E-02


HxCDF Total
3.20E-01


3.03E-03


HpCDF Total
8.78E-02


8.32E-04


OCDF
2.50E-02


2.37E-04


PCDD Total
8.96E-01


8.50E-03


PCDF Total
8.74E+00


8.29E-02


PCDD/PCDF Total
9.64E+00


9.14E-02


PCDD TEQ Total

2.56E-02
2.56E-02

2.43E-04
2.43E-04
PCDF TEQ Total

1.03E-01
1.03E-01

9.80E-04
9.80E-04
PCDD/PCDF TEQ Total

1.29E-01
1.29E-01

1.22E-03
1.22E-03
Sample ID	PS-32NEW-080315-02	Page 2 (2)
7-B

-------

EF
EF
EF
EF
EF
EF

Total
TEQ
TEQ
Total
TEQ
TEQ
Isomer.

ng/g Carbon


ng/kg fuel



ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
1.61 E-04
1.61 E-04
1.61 E-04
7.00E-02
7.00E-02
7.00E-02
1,2,3,7,8- PeCDD
2.05E-04
2.05E-04
2.05E-04
8.94E-02
8.94E-02
8.94E-02
1,2,3,4,7,8- HxCDD
7.87E-05
7.87E-06
7.87E-06
3.43E-02
3.43E-03
3.43E-03
1,2,3,6,7,8- HxCDD
2.09E-04
2.09E-05
2.09E-05
9.08E-02
9.08E-03
9.08E-03
1,2,3,7,8,9- HxCDD
2.09E-04
2.09E-05
2.09E-05
9.08E-02
9.08E-03
9.08E-03
1,2,3,4,6,7,8- HpCDD
2.07E-03
2.07E-05
2.07E-05
9.01 E-01
9.01 E-03
9.01 E-03
1,2,3,4,6,7,8,9 - OCDD
5.44E-03
1.63E-06
1.63E-06
2.37E+00
7.10E-04
7.10E-04
2,3,7,8 - TCDF
7.48E-03
7.48E-04
7.48E-04
3.25E+00
3.25E-01
3.25E-01
1,2,3,7,8- PeCDF
2.14E-03
6.42E-05
6.42E-05
9.31 E-01
2.79E-02
2.79E-02
2,3,4,7,8- PeCDF
2.30E-03
6.91 E-04
6.91 E-04
1.00E+00
3.01 E-01
3.01 E-01
1,2,3,4,7,8- HxCDF
7.67E-04
7.67E-05
7.67E-05
3.34E-01
3.34E-02
3.34E-02
1,2,3,6,7,8- HxCDF
7.08E-04
7.08E-05
7.08E-05
3.08E-01
3.08E-02
3.08E-02
1,2,3,7,8,9- HxCDF
4.14E-04
4.14E-05
4.14E-05
1.80E-01
1.80E-02
1.80E-02
2,3,4,6,7,8 - HxCDF
6.78E-04
6.78E-05
6.78E-05
2.95E-01
2.95E-02
2.95E-02
1,2,3,4,6,7,8- HpCDF
7.19E-04
7.19E-06
7.19E-06
3.13E-01
3.13E-03
3.13E-03
1,2,3,4,7,8,9- HpCDF
2.40E-04
2.40E-06
2.40E-06
1.04E-01
1.04E-03
1.04E-03
1,2,3,4,6,7,8,9-OCDF
3.70E-04
1.11E-07
1.11E-07
1.61 E-01
4.83E-05
4.83E-05
TeCDD Total
2.63E-03


1.15E+00


PeCDD Total
1.69E-03


7.34E-01


HxCDD Total
2.14E-03


9.29E-01


HpCDD Total
3.44E-03


1.50E+00


OCDD
5.44E-03


2.37E+00


TeCDF Total
1.20E-01


5.24E+01


PeCDF Total
2.18E-02


9.50E+00


HxCDF Total
5.47E-03


2.38E+00


HpCDF Total
1.50E-03


6.54E-01


OCDF
4.28E-04


1.86E-01


PCDD Total
1.53E-02


6.67E+00


PCDF Total
1.50E-01


6.51 E+01


PCDD/PCDF Total
1.65E-01


7.18E+01


PCDD TEQ Total

4.38E-04
4.38E-04

1.91 E-01
1.91 E-01
PCDF TEQ Total

1.77E-03
1.77E-03

7.70E-01
7.70E-01
PCDD/PCDF TEQ Total

2.21 E-03
2.21 E-03

9.61 E-01
9.61 E-01
955
Table B-5. PCDD/PCDF data for 32 % NEW 02.
Sample ID	PS-32NEW2-080415-01	MCE	0.932435	Page 1 (2)
Sampling volume (m3)	127.8
8-B

-------
Carbon sampled (g)	75.6
Carbon sampled
(mg/m3)	591.4
Carbon fraction	0.4


TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
1.54E-02
1.54E-02
1.54E-02
1.21E-04
1.21 E-04
1.21 E-04
1,2,3,7,8- PeCDD
1.92E-02
1.92E-02
1.92E-02
1.50E-04
1.50E-04
1.50E-04
1,2,3,4,7,8- HxCDD
7.40E-03
7.40E-04
7.40E-04
5.79E-05
5.79E-06
5.79E-06
1,2,3,6,7,8- HxCDD
1.26E-02
1.26E-03
1.26E-03
9.86E-05
9.86E-06
9.86E-06
1,2,3,7,8,9- HxCDD
1.30E-02
1.30E-03
1.30E-03
1.02E-04
1.02E-05
1.02E-05
1,2,3,4,6,7,8- HpCDD
1.44E-01
1.44E-03
1.44E-03
1.13E-03
1.13E-05
1.13E-05
1,2,3,4,6,7,8,9 - OCDD
4.53E-01
1.36E-04
1.36E-04
3.54E-03
1.06E-06
1.06E-06
2,3,7,8 - TCDF
8.45E-01
8.45E-02
8.45E-02
6.62E-03
6.62E-04
6.62E-04
1,2,3,7,8- PeCDF
1.89E-01
5.67E-03
5.67E-03
1.48E-03
4.44E-05
4.44E-05
2,3,4,7,8- PeCDF
1.82E-01
5.47E-02
5.47E-02
1.43E-03
4.28E-04
4.28E-04
1,2,3,4,7,8- HxCDF
5.14E-02
5.14E-03
5.14E-03
4.02E-04
4.02E-05
4.02E-05
1,2,3,6,7,8- HxCDF
4.96E-02
4.96E-03
4.96E-03
3.88E-04
3.88E-05
3.88E-05
1,2,3,7,8,9- HxCDF
2.56E-02
2.56E-03
2.56E-03
2.00E-04
2.00E-05
2.00E-05
2,3,4,6,7,8 - HxCDF
4.30E-02
4.30E-03
4.30E-03
3.36E-04
3.36E-05
3.36E-05
1,2,3,4,6,7,8- HpCDF
4.64E-02
4.64E-04
4.64E-04
3.63E-04
3.63E-06
3.63E-06
1,2,3,4,7,8,9- HpCDF
1.18E-02
1.18E-04
1.18E-04
9.23E-05
9.23E-07
9.23E-07
1,2,3,4,6,7,8,9-OCDF
4.36E-02
1.31 E-05
1.31 E-05
3.41 E-04
1.02E-07
1.02E-07
TeCDD Total
1.89E-01


1.48E-03


PeCDD Total
1.31E-01


1.03E-03


HxCDD Total
1.47E-01


1.15E-03


HpCDD Total
2.53E-01


1.98E-03


OCDD
4.53E-01


3.54E-03


TeCDF Total
1.28E+01


1.00E-01


PeCDF Total
1.91E+00


1.49E-02


HxCDF Total
3.45E-01


2.70E-03


HpCDF Total
8.08E-02


6.32E-04


OCDF
4.36E-02


3.41 E-04


PCDD Total
1.17E+00


9.18E-03


PCDF Total
1.52E+01


1.19E-01


PCDD/PCDF Total
1.64E+01


1.28E-01


PCDD TEQ Total

3.95E-02
3.95E-02

3.09E-04
3.09E-04
PCDF TEQ Total

1.62E-01
1.62E-01

1.27E-03
1.27E-03
PCDD/PCDF TEQ Total

2.02E-01
2.02E-01

1.58E-03
1.58E-03
Sample ID	PS-32NEW2-080415-01	Page 2 (2)
9-B

-------

EF
EF
EF
EF
EF
EF

Total
TEQ
TEQ
Total
TEQ
TEQ
Isomer.

ng/g Carbon


ng/kg fuel



ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
2.04E-04
2.04E-04
2.04E-04
8.87E-02
8.87E-02
8.87E-02
1,2,3,7,8- PeCDD
2.54E-04
2.54E-04
2.54E-04
1.11 E-01
1.11 E-01
1.11 E-01
1,2,3,4,7,8- HxCDD
9.79E-05
9.79E-06
9.79E-06
4.26E-02
4.26E-03
4.26E-03
1,2,3,6,7,8- HxCDD
1.67E-04
1.67E-05
1.67E-05
7.26E-02
7.26E-03
7.26E-03
1,2,3,7,8,9- HxCDD
1.72E-04
1.72E-05
1.72E-05
7.49E-02
7.49E-03
7.49E-03
1,2,3,4,6,7,8- HpCDD
1.91 E-03
1.91E-05
1.91 E-05
8.30E-01
8.30E-03
8.30E-03
1,2,3,4,6,7,8,9 - OCDD
5.99E-03
1.80E-06
1.80E-06
2.61 E+00
7.82E-04
7.82E-04
2,3,7,8 - TCDF
1.12E-02
1.12E-03
1.12E-03
4.87E+00
4.87E-01
4.87E-01
1,2,3,7,8- PeCDF
2.50E-03
7.50E-05
7.50E-05
1.09E+00
3.26E-02
3.26E-02
2,3,4,7,8- PeCDF
2.41 E-03
7.23E-04
7.23E-04
1.05E+00
3.15E-01
3.15E-01
1,2,3,4,7,8- HxCDF
6.80E-04
6.80E-05
6.80E-05
2.96E-01
2.96E-02
2.96E-02
1,2,3,6,7,8- HxCDF
6.56E-04
6.56E-05
6.56E-05
2.86E-01
2.86E-02
2.86E-02
1,2,3,7,8,9- HxCDF
3.39E-04
3.39E-05
3.39E-05
1.47E-01
1.47E-02
1.47E-02
2,3,4,6,7,8 - HxCDF
5.69E-04
5.69E-05
5.69E-05
2.48E-01
2.48E-02
2.48E-02
1,2,3,4,6,7,8- HpCDF
6.14E-04
6.14E-06
6.14E-06
2.67E-01
2.67E-03
2.67E-03
1,2,3,4,7,8,9- HpCDF
1.56E-04
1.56E-06
1.56E-06
6.79E-02
6.79E-04
6.79E-04
1,2,3,4,6,7,8,9-OCDF
5.77E-04
1.73E-07
1.73E-07
2.51 E-01
7.53E-05
7.53E-05
TeCDD Total
2.51 E-03


1.09E+00


PeCDD Total
1.74E-03


7.55E-01


HxCDD Total
1.95E-03


8.46E-01


HpCDD Total
3.35E-03


1.46E+00


OCDD
5.99E-03


2.61 E+00


TeCDF Total
1.70E-01


7.38E+01


PeCDF Total
2.52E-02


1.10E+01


HxCDF Total
4.57E-03


1.99E+00


HpCDF Total
1.07E-03


4.65E-01


OCDF
5.77E-04


2.51 E-01


PCDD Total
1.55E-02


6.76E+00


PCDF Total
2.01 E-01


8.74E+01


PCDD/PCDF Total
2.16E-01


9.42E+01


PCDD TEQ Total

5.22E-04
5.22E-04

2.27E-01
2.27E-01
PCDF TEQ Total

2.15E-03
2.15E-03

9.35E-01
9.35E-01
PCDD/PCDF TEQ Total

2.67E-03
2.67E-03

1.16E+00
1.16E+00
960
Table B-6. PCDD/PCDF data for 32 % NEW 03.
Sample ID	PS-32NEW3-080615	MCE	0.934109	Page 1 (2)
Sampling volume (m3)	129.6
10-B

-------
Carbon sampled (g)	87.9
Carbon sampled (mg/m3)	678.1
Carbon fraction	0.435


TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
8.00E-03
8.00E-03
8.00E-03
6.17E-05
6.17E-05
6.17E-05
1,2,3,7,8- PeCDD
1.30E-02
1.30E-02
1.30E-02
1.00E-04
1.00E-04
1.00E-04
1,2,3,4,7,8- HxCDD
4.20E-03
4.20E-04
4.20E-04
3.24E-05
3.24E-06
3.24E-06
1,2,3,6,7,8- HxCDD
1.40E-02
1.40E-03
1.40E-03
1.08E-04
1.08E-05
1.08E-05
1,2,3,7,8,9- HxCDD
1.02E-02
1.02E-03
1.02E-03
7.87E-05
7.87E-06
7.87E-06
1,2,3,4,6,7,8- HpCDD
1.86E-01
1.86E-03
1.86E-03
1.44E-03
1.44E-05
1.44E-05
1,2,3,4,6,7,8,9 - OCDD
5.00E-01
1.50E-04
1.50E-04
3.86E-03
1.16E-06
1.16E-06
2,3,7,8 - TCDF
4.04E-01
4.04E-02
4.04E-02
3.12E-03
3.12E-04
3.12E-04
1,2,3,7,8- PeCDF
1.17E-01
3.50E-03
3.50E-03
9.00E-04
2.70E-05
2.70E-05
2,3,4,7,8- PeCDF
1.21E-01
3.62E-02
3.62E-02
9.32E-04
2.80E-04
2.80E-04
1,2,3,4,7,8- HxCDF
3.48E-02
3.48E-03
3.48E-03
2.69E-04
2.69E-05
2.69E-05
1,2,3,6,7,8- HxCDF
4.14E-02
4.14E-03
4.14E-03
3.20E-04
3.20E-05
3.20E-05
1,2,3,7,8,9- HxCDF
1.48E-02
1.48E-03
1.48E-03
1.14E-04
1.14E-05
1.14E-05
2,3,4,6,7,8 - HxCDF
3.44E-02
3.44E-03
3.44E-03
2.65E-04
2.65E-05
2.65E-05
1,2,3,4,6,7,8- HpCDF
3.84E-02
3.84E-04
3.84E-04
2.96E-04
2.96E-06
2.96E-06
1,2,3,4,7,8,9- HpCDF
1.02E-02
1.02E-04
1.02E-04
7.87E-05
7.87E-07
7.87E-07
1,2,3,4,6,7,8,9-OCDF
4.42E-02
1.33E-05
1.33E-05
3.41 E-04
1.02E-07
1.02E-07
TeCDD Total
1.21E-01


9.35E-04


PeCDD Total
8.76E-02


6.76E-04


HxCDD Total
1.43E-01


1.10E-03


HpCDD Total
3.25E-01


2.51 E-03


OCDD
5.00E-01


3.86E-03


TeCDF Total
9.04E+00


6.98E-02


PeCDF Total
1.35E+00


1.04E-02


HxCDF Total
3.06E-01


2.36E-03


HpCDF Total
7.86E-02


6.07E-04


OCDF
4.42E-02


3.41 E-04


PCDD Total
1.18E+00


9.09E-03


PCDF Total
1.08E+01


8.35E-02


PCDD/PCDF Total
1.20E+01


9.26E-02


PCDD TEQ Total

2.59E-02
2.59E-02

2.00E-04
2.00E-04
PCDF TEQ Total

9.32E-02
9.32E-02

7.19E-04
7.19E-04
PCDD/PCDF TEQ Total

1.19E-01
1.19E-01

9.19E-04
9.19E-04
Sample ID
PS-32NEW3-080615



Page 2 (2)

LL
LU
LL
LU
EF
I EF
EF

EF I
11-B

-------

Total
TEQ
TEQ
Total
TEQ
TEQ
Isomer.

ng/g Carbon


ng/kg fuel



ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
9.11E-05
9.11E-05
9.11 E-05
3.96E-02
3.96E-02
3.96E-02
1,2,3,7,8- PeCDD
1.48E-04
1.48E-04
1.48E-04
6.44E-02
6.44E-02
6.44E-02
1,2,3,4,7,8- HxCDD
4.78E-05
4.78E-06
4.78E-06
2.08E-02
2.08E-03
2.08E-03
1,2,3,6,7,8- HxCDD
1.59E-04
1.59E-05
1.59E-05
6.93E-02
6.93E-03
6.93E-03
1,2,3,7,8,9- HxCDD
1.16E-04
1.16E-05
1.16E-05
5.05E-02
5.05E-03
5.05E-03
1,2,3,4,6,7,8- HpCDD
2.12E-03
2.12E-05
2.12E-05
9.21 E-01
9.21 E-03
9.21 E-03
1,2,3,4,6,7,8,9 - OCDD
5.69E-03
1.71 E-06
1.71 E-06
2.48E+00
7.43E-04
7.43E-04
2,3,7,8 - TCDF
4.60E-03
4.60E-04
4.60E-04
2.00E+00
2.00E-01
2.00E-01
1,2,3,7,8- PeCDF
1.33E-03
3.98E-05
3.98E-05
5.77E-01
1.73E-02
1.73E-02
2,3,4,7,8- PeCDF
1.37E-03
4.12E-04
4.12E-04
5.98E-01
1.79E-01
1.79E-01
1,2,3,4,7,8- HxCDF
3.96E-04
3.96E-05
3.96E-05
1.72E-01
1.72E-02
1.72E-02
1,2,3,6,7,8- HxCDF
4.71 E-04
4.71 E-05
4.71 E-05
2.05E-01
2.05E-02
2.05E-02
1,2,3,7,8,9- HxCDF
1.68E-04
1.68E-05
1.68E-05
7.33E-02
7.33E-03
7.33E-03
2,3,4,6,7,8 - HxCDF
3.92E-04
3.92E-05
3.92E-05
1.70E-01
1.70E-02
1.70E-02
1,2,3,4,6,7,8- HpCDF
4.37E-04
4.37E-06
4.37E-06
1.90E-01
1.90E-03
1.90E-03
1,2,3,4,7,8,9- HpCDF
1.16E-04
1.16E-06
1.16E-06
5.05E-02
5.05E-04
5.05E-04
1,2,3,4,6,7,8,9-OCDF
5.03E-04
1.51 E-07
1.51 E-07
2.19E-01
6.57E-05
6.57E-05
TeCDD Total
1.38E-03


6.00E-01


PeCDD Total
9.97E-04


4.34E-01


HxCDD Total
1.63E-03


7.08E-01


HpCDD Total
3.70E-03


1.61 E+00


OCDD
5.69E-03


2.48E+00


TeCDF Total
1.03E-01


4.48E+01


PeCDF Total
1.53E-02


6.67E+00


HxCDF Total
3.49E-03


1.52E+00


HpCDF Total
8.95E-04


3.89E-01


OCDF
5.03E-04


2.19E-01


PCDD Total
1.34E-02


5.83E+00


PCDF Total
1.23E-01


5.36E+01


PCDD/PCDF Total
1.37E-01


5.94E+01


PCDD TEQ Total

2.94E-04
2.94E-04

1.28E-01
1.28E-01
PCDF TEQ Total

1.06E-03
1.06E-03

4.61 E-01
4.61 E-01
PCDD/PCDF TEQ Total

1.35E-03
1.35E-03

5.89E-01
5.89E-01
965
Table B-7. PCDD/PCDF data for 66 % NEW 01.
Sample ID	PS-66NEW-081215	MCE	0.934443	Page 1 (2)
Sampling volume (m3)	99.5
Carbon sampled (g)	61.6
12-B

-------
Carbon sampled (mg/m3)
Carbon fraction
619.1
0.426


TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
2.40E-03
2.40E-03
2.40E-03
2.41 E-05
2.41 E-05
2.41 E-05
1,2,3,7,8- PeCDD
6.20E-03
6.20E-03
6.20E-03
6.23E-05
6.23E-05
6.23E-05
1,2,3,4,7,8- HxCDD
4.00E-03
4.00E-04
4.00E-04
4.02E-05
4.02E-06
4.02E-06
1,2,3,6,7,8- HxCDD
1.02E-02
1.02E-03
1.02E-03
1.02E-04
1.02E-05
1.02E-05
1,2,3,7,8,9- HxCDD
9.40E-03
9.40E-04
9.40E-04
9.45E-05
9.45E-06
9.45E-06
1,2,3,4,6,7,8- HpCDD
1.33E-01
1.33E-03
1.33E-03
1.33E-03
1.33E-05
1.33E-05
1,2,3,4,6,7,8,9 - OCDD
4.04E-01
1.21E-04
1.21 E-04
4.06E-03
1.22E-06
1.22E-06
2,3,7,8 - TCDF
7.90E-02
7.90E-03
7.90E-03
7.94E-04
7.94E-05
7.94E-05
1,2,3,7,8- PeCDF
2.04E-02
6.12E-04
6.12E-04
2.05E-04
6.15E-06
6.15E-06
2,3,4,7,8- PeCDF
2.20E-02
6.60E-03
6.60E-03
2.21 E-04
6.63E-05
6.63E-05
1,2,3,4,7,8- HxCDF
1.28E-02
1.28E-03
1.28E-03
1.29E-04
1.29E-05
1.29E-05
1,2,3,6,7,8- HxCDF
1.00E-02
1.00E-03
1.00E-03
1.00E-04
1.00E-05
1.00E-05
1,2,3,7,8,9- HxCDF
5.20E-03
5.20E-04
5.20E-04
5.23E-05
5.23E-06
5.23E-06
2,3,4,6,7,8 - HxCDF
1.12E-02
1.12E-03
1.12E-03
1.13E-04
1.13E-05
1.13E-05
1,2,3,4,6,7,8- HpCDF
2.38E-02
2.38E-04
2.38E-04
2.39E-04
2.39E-06
2.39E-06
1,2,3,4,7,8,9- HpCDF
4.40E-03
4.40E-05
4.40E-05
4.42E-05
4.42E-07
4.42E-07
1,2,3,4,6,7,8,9-OCDF
2.82E-02
8.46E-06
8.46E-06
2.83E-04
8.50E-08
8.50E-08
TeCDD Total
1.20E-01


1.21E-03


PeCDD Total
7.30E-02


7.34E-04


HxCDD Total
1.03E-01


1.04E-03


HpCDD Total
2.16E-01


2.17E-03


OCDD
4.04E-01


4.06E-03


TeCDF Total
2.66E+00


2.67E-02


PeCDF Total
2.50E-01


2.51 E-03


HxCDF Total
9.08E-02


9.12E-04


HpCDF Total
3.48E-02


3.50E-04


OCDF
2.82E-02


2.83E-04


PCDD Total
9.17E-01


9.21 E-03


PCDF Total
3.06E+00


3.08E-02


PCDD/PCDF Total
3.98E+00


4.00E-02


PCDD TEQ Total

1.24E-02
1.24E-02

1.25E-04
1.25E-04
PCDF TEQ Total

1.93E-02
1.93E-02

1.94E-04
1.94E-04
PCDD/PCDF TEQ Total

3.17E-02
3.17E-02

3.19E-04
3.19E-04
Sample ID
P S-66 N EW-081215




Page 2 (2)

EF EF
EF
I EF

EF
EF
13-B

-------

Total
TEQ
TEQ
Total
TEQ
TEQ
Isomer.

ng/g Carbon


ng/kg fuel



ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
3.90E-05
3.90E-05
3.90E-05
1.66E-02
1.66E-02
1.66E-02
1,2,3,7,8- PeCDD
1.01E-04
1.01 E-04
1.01 E-04
4.29E-02
4.29E-02
4.29E-02
1,2,3,4,7,8- HxCDD
6.49E-05
6.49E-06
6.49E-06
2.77E-02
2.77E-03
2.77E-03
1,2,3,6,7,8- HxCDD
1.66E-04
1.66E-05
1.66E-05
7.05E-02
7.05E-03
7.05E-03
1,2,3,7,8,9- HxCDD
1.53E-04
1.53E-05
1.53E-05
6.50E-02
6.50E-03
6.50E-03
1,2,3,4,6,7,8- HpCDD
2.15E-03
2.15E-05
2.15E-05
9.17E-01
9.17E-03
9.17E-03
1,2,3,4,6,7,8,9 - OCDD
6.56E-03
1.97E-06
1.97E-06
2.79E+00
8.38E-04
8.38E-04
2,3,7,8 - TCDF
1.28E-03
1.28E-04
1.28E-04
5.46E-01
5.46E-02
5.46E-02
1,2,3,7,8- PeCDF
3.31 E-04
9.93E-06
9.93E-06
1.41 E-01
4.23E-03
4.23E-03
2,3,4,7,8- PeCDF
3.57E-04
1.07E-04
1.07E-04
1.52E-01
4.56E-02
4.56E-02
1,2,3,4,7,8- HxCDF
2.08E-04
2.08E-05
2.08E-05
8.85E-02
8.85E-03
8.85E-03
1,2,3,6,7,8- HxCDF
1.62E-04
1.62E-05
1.62E-05
6.91 E-02
6.91 E-03
6.91 E-03
1,2,3,7,8,9- HxCDF
8.44E-05
8.44E-06
8.44E-06
3.59E-02
3.59E-03
3.59E-03
2,3,4,6,7,8 - HxCDF
1.82E-04
1.82E-05
1.82E-05
7.74E-02
7.74E-03
7.74E-03
1,2,3,4,6,7,8- HpCDF
3.86E-04
3.86E-06
3.86E-06
1.65E-01
1.65E-03
1.65E-03
1,2,3,4,7,8,9- HpCDF
7.14E-05
7.14E-07
7.14E-07
3.04E-02
3.04E-04
3.04E-04
1,2,3,4,6,7,8,9-OCDF
4.58E-04
1.37E-07
1.37E-07
1.95E-01
5.85E-05
5.85E-05
TeCDD Total
1.95E-03


8.31 E-01


PeCDD Total
1.18E-03


5.05E-01


HxCDD Total
1.67E-03


7.12E-01


HpCDD Total
3.51 E-03


1.49E+00


OCDD
6.56E-03


2.79E+00


TeCDF Total
4.31 E-02


1.84E+01


PeCDF Total
4.05E-03


1.73E+00


HxCDF Total
1.47E-03


6.28E-01


HpCDF Total
5.65E-04


2.41 E-01


OCDF
4.58E-04


1.95E-01


PCDD Total
1.49E-02


6.34E+00


PCDF Total
4.97E-02


2.12E+01


PCDD/PCDF Total
6.46E-02


2.75E+01


PCDD TEQ Total

2.01 E-04
2.01 E-04

8.58E-02
8.58E-02
PCDF TEQ Total

3.14E-04
3.14E-04

1.34E-01
1.34E-01
PCDD/PCDF TEQ Total

5.15E-04
5.15E-04

2.19E-01
2.19E-01
970
Table B-8. PCDD/PCDF data for 66 % NEW 02.
Sample ID	PS-66NEW2-081315-01
Sampling volume (m3)	91.1
Carbon sampled (g)	67.8
Page 1 (2)
MCE	0.945527
14-B

-------
Carbon sampled (mg/m3)	744.6
Carbon fraction	0.4



TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total
LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ng/sample
ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
3.00E-03

3.00E-03
3.00E-03
3.29E-05
3.29E-05
3.29E-05
1,2,3,7,8- PeCDD
4.00E-03

4.00E-03
4.00E-03
4.39E-05
4.39E-05
4.39E-05
1,2,3,4,7,8- HxCDD
3.00E-03

3.00E-04
3.00E-04
3.29E-05
3.29E-06
3.29E-06
1,2,3,6,7,8- HxCDD
8.20E-03

8.20E-04
8.20E-04
9.00E-05
9.00E-06
9.00E-06
1,2,3,7,8,9- HxCDD
7.80E-03

7.80E-04
7.80E-04
8.56E-05
8.56E-06
8.56E-06
1,2,3,4,6,7,8- HpCDD
1.35E-01

1.35E-03
1.35E-03
1.48E-03
1.48E-05
1.48E-05
1,2,3,4,6,7,8,9 - OCDD
4.14E-01

1.24E-04
1.24E-04
4.55E-03
1.36E-06
1.36E-06
2,3,7,8 - TCDF
1.16E-01

1.16E-02
1.16E-02
1.28E-03
1.28E-04
1.28 E-04
1,2,3,7,8- PeCDF
2.72E-02

8.16E-04
8.16E-04
2.99E-04
8.96E-06
8.96E-06
2,3,4,7,8- PeCDF
2.62E-02

7.86E-03
7.86E-03
2.88E-04
8.63E-05
8.63E-05
1,2,3,4,7,8- HxCDF
1.00E-02

1.00E-03
1.00E-03
1.10E-04
1.10E-05
1.10E-05
1,2,3,6,7,8- HxCDF
1.10E-02

1.10E-03
1.10E-03
1.21 E-04
1.21 E-05
1.21 E-05
1,2,3,7,8,9- HxCDF
4.60E-03

4.60E-04
4.60E-04
5.05E-05
5.05E-06
5.05E-06
2,3,4,6,7,8 - HxCDF
9.40E-03

9.40E-04
9.40E-04
1.03E-04
1.03E-05
1.03E-05
1,2,3,4,6,7,8- HpCDF
1.86E-02

1.86E-04
1.86E-04
2.04E-04
2.04E-06
2.04E-06
1,2,3,4,7,8,9- HpCDF
3.20E-03

3.20E-05
3.20E-05
3.51 E-05
3.51 E-07
3.51 E-07
1,2,3,4,6,7,8,9-OCDF
2.28E-02

6.84E-06
6.84E-06
2.50E-04
7.51 E-08
7.51 E-08
TeCDD Total
8.66E-02



9.51 E-04


PeCDD Total
4.18E-02



4.59E-04


HxCDD Total
8.42E-02



9.24E-04


HpCDD Total
2.21 E-01



2.43E-03


OCDD
4.14E-01



4.55E-03


TeCDF Total
3.91 E+00



4.29E-02


PeCDF Total
2.76E-01



3.03E-03


HxCDF Total
6.66E-02



7.31 E-04


HpCDF Total
3.92E-02



4.30E-04


OCDF
2.28E-02



2.50E-04


PCDD Total
8.48E-01



9.31 E-03


PCDF Total
4.32E+00



4.74E-02


PCDD/PCDF Total
5.16E+00



5.67E-02


PCDD TEQ Total


1.04E-02
1.04E-02

1.14E-04
1.14E-04
PCDF TEQ Total


2.40E-02
2.40E-02

2.64E-04
2.64E-04
PCDD/PCDF TEQ Total


3.44E-02
3.44E-02

3.78E-04
3.78E-04
Sample ID	PS-66NEW2-081315-01	Page 2 (2)
EF	EF	EF	EF	EF	EF
15-B

-------

Total
TEQ
TEQ
Total
TEQ
TEQ
Isomer.

ng/g Carbon


ng/kg fuel



ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
4.42E-05
4.42E-05
4.42E-05
1.88E-02
1.88E-02
1.88E-02
1,2,3,7,8- PeCDD
5.90E-05
5.90E-05
5.90E-05
2.51 E-02
2.51 E-02
2.51 E-02
1,2,3,4,7,8- HxCDD
4.42E-05
4.42E-06
4.42E-06
1.88E-02
1.88E-03
1.88E-03
1,2,3,6,7,8- HxCDD
1.21 E-04
1.21E-05
1.21 E-05
5.15E-02
5.15E-03
5.15E-03
1,2,3,7,8,9- HxCDD
1.15E-04
1.15E-05
1.15E-05
4.90E-02
4.90E-03
4.90E-03
1,2,3,4,6,7,8- HpCDD
1.98E-03
1.98E-05
1.98E-05
8.45E-01
8.45E-03
8.45E-03
1,2,3,4,6,7,8,9 - OCDD
6.11E-03
1.83E-06
1.83E-06
2.60E+00
7.80E-04
7.80E-04
2,3,7,8 - TCDF
1.71 E-03
1.71 E-04
1.71 E-04
7.30E-01
7.30E-02
7.30E-02
1,2,3,7,8- PeCDF
4.01 E-04
1.20E-05
1.20E-05
1.71E-01
5.13E-03
5.13E-03
2,3,4,7,8- PeCDF
3.86E-04
1.16E-04
1.16E-04
1.65E-01
4.94E-02
4.94E-02
1,2,3,4,7,8- HxCDF
1.47E-04
1.47E-05
1.47E-05
6.28E-02
6.28E-03
6.28E-03
1,2,3,6,7,8- HxCDF
1.62E-04
1.62E-05
1.62E-05
6.91 E-02
6.91 E-03
6.91 E-03
1,2,3,7,8,9- HxCDF
6.78E-05
6.78E-06
6.78E-06
2.89E-02
2.89E-03
2.89E-03
2,3,4,6,7,8 - HxCDF
1.39E-04
1.39E-05
1.39E-05
5.90E-02
5.90E-03
5.90E-03
1,2,3,4,6,7,8- HpCDF
2.74E-04
2.74E-06
2.74E-06
1.17E-01
1.17E-03
1.17E-03
1,2,3,4,7,8,9- HpCDF
4.72E-05
4.72E-07
4.72E-07
2.01 E-02
2.01 E-04
2.01 E-04
1,2,3,4,6,7,8,9-OCDF
3.36E-04
1.01E-07
1.01 E-07
1.43E-01
4.30E-05
4.30E-05
TeCDD Total
1.28E-03


5.44E-01


PeCDD Total
6.16E-04


2.63E-01


HxCDD Total
1.24E-03


5.29E-01


HpCDD Total
3.26E-03


1.39E+00


OCDD
6.11 E-03


2.60E+00


TeCDF Total
5.77E-02


2.46E+01


PeCDF Total
4.06E-03


1.73E+00


HxCDF Total
9.82E-04


4.18E-01


HpCDF Total
5.78E-04


2.46E-01


OCDF
3.36E-04


1.43E-01


PCDD Total
1.25E-02


5.32E+00


PCDF Total
6.36E-02


2.71 E+01


PCDD/PCDF Total
7.61 E-02


3.24E+01


PCDD TEQ Total

1.53E-04
1.53E-04

6.51 E-02
6.51 E-02
PCDF TEQ Total

3.54E-04
3.54E-04

1.51 E-01
1.51 E-01
PCDD/PCDF TEQ Total

5.07E-04
5.07E-04

2.16E-01
2.16E-01
975
Table B-9. PCDD/PCDF data for 66 % NEW 03.
Sample ID	PS-66NEW3-081315-02
Sampling volume (m3)	82.8
Carbon sampled (g)	58.7
Carbon sampled (mg/m3)	709.3
MCE
0.957416
Page 1 (2)
16-B

-------
Carbon fraction
0.4


TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
6.60E-03
6.60E-03
6.60E-03
7.97E-05
7.97E-05
7.97E-05
1,2,3,7,8- PeCDD
6.60E-03
6.60E-03
6.60E-03
7.97E-05
7.97E-05
7.97E-05
1,2,3,4,7,8- HxCDD
3.40E-03
3.40E-04
3.40E-04
4.11E-05
4.11E-06
4.11E-06
1,2,3,6,7,8- HxCDD
9.80E-03
9.80E-04
9.80E-04
1.18E-04
1.18E-05
1.18E-05
1,2,3,7,8,9- HxCDD
8.60E-03
8.60E-04
8.60E-04
1.04E-04
1.04E-05
1.04E-05
1,2,3,4,6,7,8- HpCDD
1.27E-01
1.27E-03
1.27E-03
1.54E-03
1.54E-05
1.54E-05
1,2,3,4,6,7,8,9 - OCDD
3.78E-01
1.13E-04
1.13E-04
4.57E-03
1.37E-06
1.37E-06
2,3,7,8 - TCDF
2.24E-01
2.24E-02
2.24E-02
2.71 E-03
2.71 E-04
2.71 E-04
1,2,3,7,8- PeCDF
5.84E-02
1.75E-03
1.75E-03
7.05E-04
2.12E-05
2.12E-05
2,3,4,7,8- PeCDF
5.92E-02
1.78E-02
1.78E-02
7.15E-04
2.15E-04
2.15E-04
1,2,3,4,7,8- HxCDF
1.68E-02
1.68E-03
1.68E-03
2.03E-04
2.03E-05
2.03E-05
1,2,3,6,7,8- HxCDF
1.66E-02
1.66E-03
1.66E-03
2.01 E-04
2.01 E-05
2.01 E-05
1,2,3,7,8,9- HxCDF
7.60E-03
7.60E-04
7.60E-04
9.18E-05
9.18E-06
9.18E-06
2,3,4,6,7,8 - HxCDF
1.56E-02
1.56E-03
1.56E-03
1.88E-04
1.88E-05
1.88E-05
1,2,3,4,6,7,8- HpCDF
2.12E-02
2.12E-04
2.12E-04
2.56E-04
2.56E-06
2.56E-06
1,2,3,4,7,8,9- HpCDF
4.20E-03
4.20E-05
4.20E-05
5.07E-05
5.07E-07
5.07E-07
1,2,3,4,6,7,8,9-OCDF
1.96E-02
5.88E-06
5.88E-06
2.37E-04
7.10E-08
7.10E-08
TeCDD Total
9.96E-02


1.20E-03


PeCDD Total
4.64E-02


5.60E-04


HxCDD Total
9.50E-02


1.15E-03


HpCDD Total
2.17E-01


2.63E-03


OCDD
3.78E-01


4.57E-03


TeCDF Total
4.73E+00


5.72E-02


PeCDF Total
5.28E-01


6.38E-03


HxCDF Total
1.27E-01


1.53E-03


HpCDF Total
3.76E-02


4.54E-04


OCDF
1.96E-02


2.37E-04


PCDD Total
8.37E-01


1.01 E-02


PCDF Total
5.44E+00


6.58E-02


PCDD/PCDF Total
6.28E+00


7.59E-02


PCDD TEQ Total

1.68E-02
1.68E-02

2.03E-04
2.03E-04
PCDF TEQ Total

4.79E-02
4.79E-02

5.78E-04
5.78E-04
PCDD/PCDF TEQ Total

6.46E-02
6.46E-02

7.81 E-04
7.81 E-04
Sample ID
PS-66NEW3-081315-02



Page 2 (2)
EF
EF
EF
EF
EF
EF
Total
TEQ
TEQ
Total
TEQ
TEQ
17-B

-------
Isomer.

ng/g Carbon


ng/kg fuel



ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
1.12E-04
1.12E-04
1.12E-04
4.79E-02
4.79E-02
4.79E-02
1,2,3,7,8- PeCDD
1.12E-04
1.12E-04
1.12E-04
4.79E-02
4.79E-02
4.79E-02
1,2,3,4,7,8- HxCDD
5.79E-05
5.79E-06
5.79E-06
2.47E-02
2.47E-03
2.47E-03
1,2,3,6,7,8- HxCDD
1.67E-04
1.67E-05
1.67E-05
7.11E-02
7.11 E-03
7.11 E-03
1,2,3,7,8,9- HxCDD
1.46E-04
1.46E-05
1.46E-05
6.24E-02
6.24E-03
6.24E-03
1,2,3,4,6,7,8- HpCDD
2.17E-03
2.17E-05
2.17E-05
9.24E-01
9.24E-03
9.24E-03
1,2,3,4,6,7,8,9 - OCDD
6.44E-03
1.93E-06
1.93E-06
2.74E+00
8.23E-04
8.23E-04
2,3,7,8 - TCDF
3.82E-03
3.82E-04
3.82E-04
1.63E+00
1.63E-01
1.63E-01
1,2,3,7,8- PeCDF
9.94E-04
2.98E-05
2.98E-05
4.24E-01
1.27E-02
1.27E-02
2,3,4,7,8- PeCDF
1.01 E-03
3.02E-04
3.02E-04
4.29E-01
1.29E-01
1.29E-01
1,2,3,4,7,8- HxCDF
2.86E-04
2.86E-05
2.86E-05
1.22E-01
1.22E-02
1.22E-02
1,2,3,6,7,8- HxCDF
2.83E-04
2.83E-05
2.83E-05
1.20E-01
1.20E-02
1.20E-02
1,2,3,7,8,9- HxCDF
1.29E-04
1.29E-05
1.29E-05
5.51 E-02
5.51 E-03
5.51 E-03
2,3,4,6,7,8 - HxCDF
2.66E-04
2.66E-05
2.66E-05
1.13E-01
1.13E-02
1.13E-02
1,2,3,4,6,7,8- HpCDF
3.61 E-04
3.61 E-06
3.61 E-06
1.54E-01
1.54E-03
1.54E-03
1,2,3,4,7,8,9- HpCDF
7.15E-05
7.15E-07
7.15E-07
3.05E-02
3.05E-04
3.05E-04
1,2,3,4,6,7,8,9-OCDF
3.34E-04
1.00E-07
1.00E-07
1.42E-01
4.26E-05
4.26E-05
TeCDD Total
1.70E-03


7.22E-01


PeCDD Total
7.90E-04


3.37E-01


HxCDD Total
1.62E-03


6.89E-01


HpCDD Total
3.70E-03


1.58E+00


OCDD
6.44E-03


2.74E+00


TeCDF Total
8.06E-02


3.43E+01


PeCDF Total
8.99E-03


3.83E+00


HxCDF Total
2.16E-03


9.20E-01


HpCDF Total
6.40E-04


2.73E-01


OCDF
3.34E-04


1.42E-01


PCDD Total
1.42E-02


6.07E+00


PCDF Total
9.27E-02


3.95E+01


PCDD/PCDF Total
1.07E-01


4.56E+01


PCDD TEQ Total

2.86E-04
2.86E-04

1.22E-01
1.22E-01
PCDF TEQ Total

8.15E-04
8.15E-04

3.47E-01
3.47E-01
PCDD/PCDF TEQ Total

1.10E-03
1.10E-03

4.69E-01
4.69E-01
980 Table B-10. PCDD/PCDF data for 100 % NEW 01.
Page 1 (2)
Sample ID	PS-100NEW-072915-01	MCE	0.944463
Sampling volume (m3)	129.1
Carbon sampled (g)	74.3
Carbon sampled (mg/m3)	575.6
18-B

-------
Carbon fraction
0.462



TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total
LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ng/sample
ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
1.14E-02

1.14E-02
1.14E-02
8.83E-05
8.83E-05
8.83E-05
1,2,3,7,8- PeCDD
1.72E-02

1.72E-02
1.72E-02
1.33E-04
1.33E-04
1.33E-04
1,2,3,4,7,8- HxCDD
7.80E-03

7.80E-04
7.80E-04
6.04E-05
6.04E-06
6.04E-06
1,2,3,6,7,8- HxCDD
1.50E-02

1.50E-03
1.50E-03
1.16E-04
1.16E-05
1.16E-05
1,2,3,7,8,9- HxCDD
1.08E-02

1.08E-03
1.08E-03
8.37E-05
8.37E-06
8.37E-06
1,2,3,4,6,7,8- HpCDD
1.68E-01

1.68E-03
1.68E-03
1.30E-03
1.30E-05
1.30E-05
1,2,3,4,6,7,8,9 - OCDD
5.04E-01

1.51 E-04
1.51E-04
3.90E-03
1.17E-06
1.17E-06
2,3,7,8 - TCDF
5.17E-01

5.17E-02
5.17E-02
4.00E-03
4.00E-04
4.00E-04
1,2,3,7,8- PeCDF
1.29E-01

3.88E-03
3.88E-03
1.00E-03
3.01 E-05
3.01 E-05
2,3,4,7,8- PeCDF
1.22E-01

3.67E-02
3.67E-02
9.47E-04
2.84E-04
2.84E-04
1,2,3,4,7,8- HxCDF
4.28E-02

4.28E-03
4.28E-03
3.32E-04
3.32E-05
3.32E-05
1,2,3,6,7,8- HxCDF
3.62E-02

3.62E-03
3.62E-03
2.80E-04
2.80E-05
2.80E-05
1,2,3,7,8,9- HxCDF
1.82E-02

1.82E-03
1.82E-03
1.41 E-04
1.41 E-05
1.41 E-05
2,3,4,6,7,8 - HxCDF
3.96E-02

3.96E-03
3.96E-03
3.07E-04
3.07E-05
3.07E-05
1,2,3,4,6,7,8- HpCDF
5.72E-02

5.72E-04
5.72E-04
4.43E-04
4.43E-06
4.43E-06
1,2,3,4,7,8,9- HpCDF
1.24E-02

1.24E-04
1.24E-04
9.61 E-05
9.61 E-07
9.61 E-07
1,2,3,4,6,7,8,9-OCDF
4.52E-02

1.36E-05
1.36E-05
3.50E-04
1.05E-07
1.05E-07
TeCDD Total
3.87E-01



3.00E-03


PeCDD Total
2.33E-01



1.80E-03


HxCDD Total
1.96E-01



1.52E-03


HpCDD Total
2.91 E-01



2.26E-03


OCDD
5.04E-01



3.90E-03


TeCDF Total
9.30E+00



7.20E-02


PeCDF Total
1.36E+00



1.06E-02


HxCDF Total
3.08E-01



2.39E-03


HpCDF Total
6.96E-02



5.39E-04


OCDF
5.04E-02



3.90E-04


PCDD Total
1.61 E+00



1.25E-02


PCDF Total
1.11 E+01



8.59E-02


PCDD/PCDF Total
1.27E+01



9.84E-02


PCDD TEQ Total


3.38E-02
3.38E-02

2.62E-04
2.62E-04
PCDF TEQ Total


1.07E-01
1.07E-01

8.26E-04
8.26E-04
PCDD/PCDF TEQ Total


1.40E-01
1.40E-01

1.09E-03
1.09E-03
Sample ID	PS-100NEW-072915-01	Page 2 (2)
EF
EF
EF
EF
EF
EF
Total
TEQ
TEQ
Total
TEQ
TEQ
19-B

-------
Isomer.

ng/g Carbon


ng/kg fuel



ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
1.53E-04
1.53E-04
1.53E-04
7.08E-02
7.08E-02
7.08E-02
1,2,3,7,8- PeCDD
2.31 E-04
2.31 E-04
2.31 E-04
1.07E-01
1.07E-01
1.07E-01
1,2,3,4,7,8- HxCDD
1.05E-04
1.05E-05
1.05E-05
4.85E-02
4.85E-03
4.85E-03
1,2,3,6,7,8- HxCDD
2.02E-04
2.02E-05
2.02E-05
9.32E-02
9.32E-03
9.32E-03
1,2,3,7,8,9- HxCDD
1.45E-04
1.45E-05
1.45E-05
6.71 E-02
6.71 E-03
6.71 E-03
1,2,3,4,6,7,8- HpCDD
2.26E-03
2.26E-05
2.26E-05
1.04E+00
1.04E-02
1.04E-02
1,2,3,4,6,7,8,9 - OCDD
6.78E-03
2.03E-06
2.03E-06
3.13E+00
9.39E-04
9.39E-04
2,3,7,8 - TCDF
6.95E-03
6.95E-04
6.95E-04
3.21 E+00
3.21 E-01
3.21 E-01
1,2,3,7,8- PeCDF
1.74E-03
5.22E-05
5.22E-05
8.04E-01
2.41 E-02
2.41 E-02
2,3,4,7,8- PeCDF
1.64E-03
4.93E-04
4.93E-04
7.59E-01
2.28E-01
2.28E-01
1,2,3,4,7,8- HxCDF
5.76E-04
5.76E-05
5.76E-05
2.66E-01
2.66E-02
2.66E-02
1,2,3,6,7,8- HxCDF
4.87E-04
4.87E-05
4.87E-05
2.25E-01
2.25E-02
2.25E-02
1,2,3,7,8,9- HxCDF
2.45E-04
2.45E-05
2.45E-05
1.13E-01
1.13E-02
1.13E-02
2,3,4,6,7,8 - HxCDF
5.33E-04
5.33E-05
5.33E-05
2.46E-01
2.46E-02
2.46E-02
1,2,3,4,6,7,8- HpCDF
7.70E-04
7.70E-06
7.70E-06
3.55E-01
3.55E-03
3.55E-03
1,2,3,4,7,8,9- HpCDF
1.67E-04
1.67E-06
1.67E-06
7.71 E-02
7.71 E-04
7.71 E-04
1,2,3,4,6,7,8,9-OCDF
6.08E-04
1.82E-07
1.82E-07
2.81 E-01
8.43E-05
8.43E-05
TeCDD Total
5.21 E-03


2.41 E+00


PeCDD Total
3.14E-03


1.45E+00


HxCDD Total
2.64E-03


1.22E+00


HpCDD Total
3.92E-03


1.81 E+00


OCDD
6.78E-03


3.13E+00


TeCDF Total
1.25E-01


5.78E+01


PeCDF Total
1.83E-02


8.47E+00


HxCDF Total
4.15E-03


1.91 E+00


HpCDF Total
9.37E-04


4.33E-01


OCDF
6.78E-04


3.13E-01


PCDD Total
2.17E-02


1.00E+01


PCDF Total
1.49E-01


6.89E+01


PCDD/PCDF Total
1.71 E-01


7.89E+01


PCDD TEQ Total

4.55E-04
4.55E-04

2.10E-01
2.10E-01
PCDF TEQ Total

1.43E-03
1.43E-03

6.62E-01
6.62E-01
PCDD/PCDF TEQ Total

1.89E-03
1.89E-03

8.72E-01
8.72E-01
Table B-ll. PCDD/PCDF data for 100 % NEW 02.
Page 1 (2)
Sample ID	PS-100NEW2-073115-01	MCE	0.953685
Sampling volume (m3)	116.8
Carbon sampled (g)	63.5
Carbon sampled (mg/m3)	543.6
20-B

-------
Carbon fraction
0.5


TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
1.44E-02
1.44E-02
1.44E-02
1.23E-04
1.23E-04
1.23E-04
1,2,3,7,8- PeCDD
1.44E-02
1.44E-02
1.44E-02
1.23E-04
1.23E-04
1.23E-04
1,2,3,4,7,8- HxCDD
3.40E-03
3.40E-04
3.40E-04
2.91 E-05
2.91 E-06
2.91 E-06
1,2,3,6,7,8- HxCDD
1.08E-02
1.08E-03
1.08E-03
9.25E-05
9.25E-06
9.25E-06
1,2,3,7,8,9- HxCDD
9.00E-03
9.00E-04
9.00E-04
7.71 E-05
7.71 E-06
7.71 E-06
1,2,3,4,6,7,8- HpCDD
1.24E-01
1.24E-03
1.24E-03
1.06E-03
1.06E-05
1.06E-05
1,2,3,4,6,7,8,9 - OCDD
3.46E-01
1.04E-04
1.04E-04
2.96E-03
8.89E-07
8.89E-07
2,3,7,8 - TCDF
7.90E-01
7.90E-02
7.90E-02
6.76E-03
6.76E-04
6.76E-04
1,2,3,7,8- PeCDF
2.03E-01
6.10E-03
6.10E-03
1.74E-03
5.22E-05
5.22E-05
2,3,4,7,8- PeCDF
1.96E-01
5.89E-02
5.89E-02
1.68E-03
5.04E-04
5.04E-04
1,2,3,4,7,8- HxCDF
5.54E-02
5.54E-03
5.54E-03
4.74E-04
4.74E-05
4.74E-05
1,2,3,6,7,8- HxCDF
4.86E-02
4.86E-03
4.86E-03
4.16E-04
4.16E-05
4.16E-05
1,2,3,7,8,9- HxCDF
2.12E-02
2.12E-03
2.12E-03
1.81E-04
1.81 E-05
1.81 E-05
2,3,4,6,7,8 - HxCDF
3.78E-02
3.78E-03
3.78E-03
3.24E-04
3.24E-05
3.24E-05
1,2,3,4,6,7,8- HpCDF
4.14E-02
4.14E-04
4.14E-04
3.54E-04
3.54E-06
3.54E-06
1,2,3,4,7,8,9- HpCDF
1.04E-02
1.04E-04
1.04E-04
8.90E-05
8.90E-07
8.90E-07
1,2,3,4,6,7,8,9-OCDF
2.60E-02
7.80E-06
7.80E-06
2.23E-04
6.68E-08
6.68E-08
TeCDD Total
2.70E-01


2.31 E-03


PeCDD Total
1.07E-01


9.13E-04


HxCDD Total
1.20E-01


1.03E-03


HpCDD Total
2.16E-01


1.85E-03


OCDD
3.46E-01


2.96E-03


TeCDF Total
1.17E+01


9.98E-02


PeCDF Total
1.92E+00


1.64E-02


HxCDF Total
3.55E-01


3.04E-03


HpCDF Total
7.08E-02


6.06E-04


OCDF
2.60E-02


2.23E-04


PCDD Total
1.06E+00


9.07E-03


PCDF Total
1.40E+01


1.20E-01


PCDD/PCDF Total
1.51 E+01


1.29E-01


PCDD TEQ Total

3.25E-02
3.25E-02

2.78E-04
2.78E-04
PCDF TEQ Total

1.61 E-01
1.61 E-01

1.38E-03
1.38E-03
PCDD/PCDF TEQ Total

1.93E-01
1.93E-01

1.65E-03
1.65E-03
Sample ID
PS-100NEW2-073115-01



Page 2 (2)
EF
EF
EF
EF
EF
EF
Total
TEQ
TEQ
Total
TEQ
TEQ
21-B

-------
Isomer.

ng/g Carbon


ng/kg fuel



ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
2.27E-04
2.27E-04
2.27E-04
1.05E-01
1.05E-01
1.05E-01
1,2,3,7,8- PeCDD
2.27E-04
2.27E-04
2.27E-04
1.05E-01
1.05E-01
1.05E-01
1,2,3,4,7,8- HxCDD
5.35E-05
5.35E-06
5.35E-06
2.47E-02
2.47E-03
2.47E-03
1,2,3,6,7,8- HxCDD
1.70E-04
1.70E-05
1.70E-05
7.85E-02
7.85E-03
7.85E-03
1,2,3,7,8,9- HxCDD
1.42E-04
1.42E-05
1.42E-05
6.55E-02
6.55E-03
6.55E-03
1,2,3,4,6,7,8- HpCDD
1.96E-03
1.96E-05
1.96E-05
9.03E-01
9.03E-03
9.03E-03
1,2,3,4,6,7,8,9 - OCDD
5.45E-03
1.64E-06
1.64E-06
2.52E+00
7.55E-04
7.55E-04
2,3,7,8 - TCDF
1.24E-02
1.24E-03
1.24E-03
5.74E+00
5.74E-01
5.74E-01
1,2,3,7,8- PeCDF
3.20E-03
9.61 E-05
9.61 E-05
1.48E+00
4.44E-02
4.44E-02
2,3,4,7,8- PeCDF
3.09E-03
9.28E-04
9.28E-04
1.43E+00
4.29E-01
4.29E-01
1,2,3,4,7,8- HxCDF
8.73E-04
8.73E-05
8.73E-05
4.03E-01
4.03E-02
4.03E-02
1,2,3,6,7,8- HxCDF
7.65E-04
7.65E-05
7.65E-05
3.53E-01
3.53E-02
3.53E-02
1,2,3,7,8,9- HxCDF
3.34E-04
3.34E-05
3.34E-05
1.54E-01
1.54E-02
1.54E-02
2,3,4,6,7,8 - HxCDF
5.95E-04
5.95E-05
5.95E-05
2.75E-01
2.75E-02
2.75E-02
1,2,3,4,6,7,8- HpCDF
6.52E-04
6.52E-06
6.52E-06
3.01 E-01
3.01 E-03
3.01 E-03
1,2,3,4,7,8,9- HpCDF
1.64E-04
1.64E-06
1.64E-06
7.56E-02
7.56E-04
7.56E-04
1,2,3,4,6,7,8,9-OCDF
4.09E-04
1.23E-07
1.23E-07
1.89E-01
5.67E-05
5.67E-05
TeCDD Total
4.26E-03


1.97E+00


PeCDD Total
1.68E-03


7.75E-01


HxCDD Total
1.89E-03


8.74E-01


HpCDD Total
3.40E-03


1.57E+00


OCDD
5.45E-03


2.52E+00


TeCDF Total
1.84E-01


8.48E+01


PeCDF Total
3.03E-02


1.40E+01


HxCDF Total
5.58E-03


2.58E+00


HpCDF Total
1.12E-03


5.15E-01


OCDF
4.09E-04


1.89E-01


PCDD Total
1.67E-02


7.70E+00


PCDF Total
2.21 E-01


1.02E+02


PCDD/PCDF Total
2.38E-01


1.10E+02


PCDD TEQ Total

5.11E-04
5.11E-04

2.36E-01
2.36E-01
PCDF TEQ Total

2.53E-03
2.53E-03

1.17E+00
1.17E+00
PCDD/PCDF TEQ Total

3.04E-03
3.04E-03

1.41 E+00
1.41 E+00
Table B-12. PCDD/PCDF data for 100 % NEW 03.
Page 1 (2)
Sample ID	PS-100NEW3-080515-01	MCE	0.936171
Sampling volume (m3)	107.0
Carbon sampled (g)	66.3
Carbon sampled (mg/m3)	619.9
22-B

-------
Carbon fraction
0.46



TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total
LOD
ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample
ng/sample
ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
3.00E-03

3.00E-03
3.00E-03
2.80E-05
2.80E-05
2.80E-05
1,2,3,7,8- PeCDD
6.80E-03

6.80E-03
6.80E-03
6.35E-05
6.35E-05
6.35E-05
1,2,3,4,7,8- HxCDD
3.80E-03

3.80E-04
3.80E-04
3.55E-05
3.55E-06
3.55E-06
1,2,3,6,7,8- HxCDD
1.00E-02

1.00E-03
1.00E-03
9.34E-05
9.34E-06
9.34E-06
1,2,3,7,8,9- HxCDD
8.20E-03

8.20E-04
8.20E-04
7.66E-05
7.66E-06
7.66E-06
1,2,3,4,6,7,8- HpCDD
1.43E-01

1.43E-03
1.43E-03
1.34E-03
1.34E-05
1.34E-05
1,2,3,4,6,7,8,9 - OCDD
4.40E-01

1.32E-04
1.32E-04
4.11E-03
1.23E-06
1.23E-06
2,3,7,8 - TCDF
1.45E-01

1.45E-02
1.45E-02
1.35E-03
1.35E-04
1.35E-04
1,2,3,7,8- PeCDF
4.88E-02

1.46E-03
1.46E-03
4.56E-04
1.37E-05
1.37E-05
2,3,4,7,8- PeCDF
4.52E-02

1.36E-02
1.36E-02
4.22E-04
1.27E-04
1.27E-04
1,2,3,4,7,8- HxCDF
2.38E-02

2.38E-03
2.38E-03
2.22E-04
2.22E-05
2.22E-05
1,2,3,6,7,8- HxCDF
2.22E-02

2.22E-03
2.22E-03
2.07E-04
2.07E-05
2.07E-05
1,2,3,7,8,9- HxCDF
1.00E-02

1.00E-03
1.00E-03
9.34E-05
9.34E-06
9.34E-06
2,3,4,6,7,8 - HxCDF
1.58E-02

1.58E-03
1.58E-03
1.48E-04
1.48E-05
1.48E-05
1,2,3,4,6,7,8- HpCDF
2.68E-02

2.68E-04
2.68E-04
2.50E-04
2.50E-06
2.50E-06
1,2,3,4,7,8,9- HpCDF
5.60E-03

5.60E-05
5.60E-05
5.23E-05
5.23E-07
5.23E-07
1,2,3,4,6,7,8,9-OCDF
1.86E-02

5.58E-06
5.58E-06
1.74E-04
5.21 E-08
5.21 E-08
TeCDD Total
1.28E-01



1.19E-03


PeCDD Total
7.60E-02



7.10E-04


HxCDD Total
1.10E-01



1.03E-03


HpCDD Total
2.40E-01



2.24E-03


OCDD
4.40E-01



4.11E-03


TeCDF Total
4.96E+00



4.64E-02


PeCDF Total
4.80E-01



4.48E-03


HxCDF Total
1.55E-01



1.45E-03


HpCDF Total
5.44E-02



5.08E-04


OCDF
2.22E-02



2.07E-04


PCDD Total
9.94E-01



9.29E-03


PCDF Total
5.67E+00



5.30E-02


PCDD/PCDF Total
6.67E+00



6.23E-02


PCDD TEQ Total


1.36E-02
1.36E-02

1.27E-04
1.27E-04
PCDF TEQ Total


3.70E-02
3.70E-02

3.46E-04
3.46E-04
PCDD/PCDF TEQ Total


5.06E-02
5.06E-02

4.73E-04
4.73E-04
Page 2
Sample ID	PS-100NEW3-080515-01	(2)
EF
EF
EF
EF
EF
EF
Total
TEQ
TEQ
Total
TEQ
TEQ
23-B

-------
Isomer.

ng/g Carbon
ND = 0
ND = LOD

ng/kg fuel
ND = 0
ND =
LOD
2,3,7,8 - TCDD
4.52E-05
4.52E-05
4.52E-05
2.09E-02
2.09E-02
2.09E-02
1,2,3,7,8- PeCDD
1.02E-04
1.02E-04
1.02E-04
4.73E-02
4.73E-02
4.73E-02
1,2,3,4,7,8- HxCDD
5.73E-05
5.73E-06
5.73E-06
2.64E-02
2.64E-03
2.64E-03
1,2,3,6,7,8- HxCDD
1.51E-04
1.51E-05
1.51 E-05
6.96E-02
6.96E-03
6.96E-03
1,2,3,7,8,9- HxCDD
1.24E-04
1.24E-05
1.24E-05
5.71 E-02
5.71 E-03
5.71 E-03
1,2,3,4,6,7,8- HpCDD
2.16E-03
2.16E-05
2.16E-05
9.97E-01
9.97E-03
9.97E-03
1,2,3,4,6,7,8,9 - OCDD
6.63E-03
1.99E-06
1.99E-06
3.06E+00
9.19E-04
9.19E-04
2,3,7,8 - TCDF
2.18E-03
2.18E-04
2.18E-04
1.01 E+00
1.01 E-01
1.01 E-01
1,2,3,7,8- PeCDF
7.36E-04
2.21 E-05
2.21 E-05
3.40E-01
1.02E-02
1.02E-02
2,3,4,7,8- PeCDF
6.81 E-04
2.04E-04
2.04E-04
3.15E-01
9.44E-02
9.44E-02
1,2,3,4,7,8- HxCDF
3.59E-04
3.59E-05
3.59E-05
1.66E-01
1.66E-02
1.66E-02
1,2,3,6,7,8- HxCDF
3.35E-04
3.35E-05
3.35E-05
1.55E-01
1.55E-02
1.55E-02
1,2,3,7,8,9- HxCDF
1.51 E-04
1.51 E-05
1.51 E-05
6.96E-02
6.96E-03
6.96E-03
2,3,4,6,7,8 - HxCDF
2.38E-04
2.38E-05
2.38E-05
1.10E-01
1.10E-02
1.10E-02
1,2,3,4,6,7,8- HpCDF
4.04E-04
4.04E-06
4.04E-06
1.87E-01
1.87E-03
1.87E-03
1,2,3,4,7,8,9- HpCDF
8.44E-05
8.44E-07
8.44E-07
3.90E-02
3.90E-04
3.90E-04
1,2,3,4,6,7,8,9-OCDF
2.80E-04
8.41 E-08
8.41 E-08
1.29E-01
3.88E-05
3.88E-05
TeCDD Total
1.92E-03


8.88E-01


PeCDD Total
1.15E-03


5.29E-01


HxCDD Total
1.66E-03


7.67E-01


HpCDD Total
3.62E-03


1.67E+00


OCDD
6.63E-03


3.06E+00


TeCDF Total
7.48E-02


3.45E+01


PeCDF Total
7.23E-03


3.34E+00


HxCDF Total
2.34E-03


1.08E+00


HpCDF Total
8.20E-04


3.79E-01


OCDF
3.35E-04


1.55E-01


PCDD Total
1.50E-02


6.92E+00


PCDF Total
8.55E-02


3.95E+01


PCDD/PCDF Total
1.01 E-01


4.64E+01


PCDD TEQ Total

2.04E-04
2.04E-04

9.44E-02
9.44E-02
PCDF TEQ Total

5.58E-04
5.58E-04

2.58E-01
2.58E-01
PCDD/PCDF TEQ Total

7.62E-04
7.62E-04

3.52E-01
3.52E-01
990
Table B-13. PCDD/PCDF data for Baseline CB/CL 05.
Sample ID	PS-CB-080315-01	MCE	0.949349	Page 1 (2)
Sampling volume (m3)	69.2
Carbon sampled (g)	70.7
24-B

-------
Carbon sampled (mg/m3)	1021.1
Carbon fraction	0.46245


TEQ
TEQ
Total
TEQ
TEQ
Isomer.
Total
LOD ng/sample
ng/sample
ng/m3
ng/m3
ng/m3

ng/sample ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
8.00E-04
8.00E-04
8.00E-04
1.16E-05
1.16E-05
1.16E-05
1,2,3,7,8- PeCDD
2.60E-03
2.60E-03
2.60E-03
3.75E-05
3.75E-05
3.75E-05
1,2,3,4,7,8- HxCDD
1.60E-03
1.60E-04
1.60E-04
2.31 E-05
2.31 E-06
2.31 E-06
1,2,3,6,7,8- HxCDD
2.80E-03
2.80E-04
2.80E-04
4.04E-05
4.04E-06
4.04E-06
1,2,3,7,8,9- HxCDD
2.80E-03
2.80E-04
2.80E-04
4.04E-05
4.04E-06
4.04E-06
1,2,3,4,6,7,8- HpCDD
3.68E-02
3.68E-04
3.68E-04
5.31 E-04
5.31 E-06
5.31 E-06
1,2,3,4,6,7,8,9 - OCDD
1.05E-01
3.14E-05
3.14E-05
1.51E-03
4.53E-07
4.53E-07
2,3,7,8 - TCDF
3.10E-02
3.10E-03
3.10E-03
4.48E-04
4.48E-05
4.48E-05
1,2,3,7,8- PeCDF
8.00E-03
2.40E-04
2.40E-04
1.16E-04
3.47E-06
3.47E-06
2,3,4,7,8- PeCDF
6.40E-03
1.92E-03
1.92E-03
9.24E-05
2.77E-05
2.77E-05
1,2,3,4,7,8- HxCDF
4.60E-03
4.60E-04
4.60E-04
6.64E-05
6.64E-06
6.64E-06
1,2,3,6,7,8- HxCDF
4.40E-03
4.40E-04
4.40E-04
6.35E-05
6.35E-06
6.35E-06
1,2,3,7,8,9- HxCDF
2.80E-03
2.80E-04
2.80E-04
4.04E-05
4.04E-06
4.04E-06
2,3,4,6,7,8 - HxCDF
5.60E-03
5.60E-04
5.60E-04
8.09E-05
8.09E-06
8.09E-06
1,2,3,4,6,7,8- HpCDF
1.30E-02
1.30E-04
1.30E-04
1.88E-04
1.88E-06
1.88E-06
1,2,3,4,7,8,9- HpCDF
2.80E-03
2.80E-05
2.80E-05
4.04E-05
4.04E-07
4.04E-07
1,2,3,4,6,7,8,9-OCDF
ND
7.70E-03 0.00E+00
2.31 E-06
ND
0.00E+00
3.34E-08
TeCDD Total
7.34E-02


1.06E-03


PeCDD Total
2.66E-02


3.84E-04


HxCDD Total
4.44E-02


6.41 E-04


HpCDD Total
7.04E-02


1.02E-03


OCDD
1.05E-01


1.51 E-03


TeCDF Total
3.90E-01


5.63E-03


PeCDF Total
5.20E-02


7.51 E-04


HxCDF Total
3.96E-02


5.72E-04


HpCDF Total
2.24E-02


3.23E-04


OCDF
ND


ND


PCDD Total
3.19E-01


4.61 E-03


PCDF Total
5.04E-01


7.28E-03


PCDD/PCDF Total
8.24E-01


1.19E-02


PCDD TEQ Total

4.52E-03
4.52E-03

6.53E-05
6.53E-05
PCDF TEQ Total

7.16E-03
7.16E-03

1.03E-04
1.03E-04
PCDD/PCDF TEQ Total

1.17E-02
1.17E-02

1.69E-04
1.69E-04
Sample ID	PS-CB-080315-01	Page 2 (2)
EF
EF
EF
EF
EF
EF
Total
TEQ
TEQ
Total
TEQ
TEQ
25-B

-------
Isomer.

ng/g Carbon


ng/kg fuel



ND = 0
ND = LOD

ND = 0
ND = LOD
2,3,7,8 - TCDD
1.13E-05
1.13E-05
1.13E-05
5.23E-03
5.23E-03
5.23E-03
1,2,3,7,8- PeCDD
3.68E-05
3.68E-05
3.68E-05
1.70E-02
1.70E-02
1.70E-02
1,2,3,4,7,8- HxCDD
2.26E-05
2.26E-06
2.26E-06
1.05E-02
1.05E-03
1.05E-03
1,2,3,6,7,8- HxCDD
3.96E-05
3.96E-06
3.96E-06
1.83E-02
1.83E-03
1.83E-03
1,2,3,7,8,9- HxCDD
3.96E-05
3.96E-06
3.96E-06
1.83E-02
1.83E-03
1.83E-03
1,2,3,4,6,7,8- HpCDD
5.20E-04
5.20E-06
5.20E-06
2.41 E-01
2.41 E-03
2.41 E-03
1,2,3,4,6,7,8,9 - OCDD
1.48E-03
4.44E-07
4.44E-07
6.84E-01
2.05E-04
2.05E-04
2,3,7,8 - TCDF
4.38E-04
4.38E-05
4.38E-05
2.03E-01
2.03E-02
2.03E-02
1,2,3,7,8- PeCDF
1.13E-04
3.39E-06
3.39E-06
5.23E-02
1.57E-03
1.57E-03
2,3,4,7,8- PeCDF
9.05E-05
2.72E-05
2.72E-05
4.19E-02
1.26E-02
1.26E-02
1,2,3,4,7,8- HxCDF
6.51 E-05
6.51 E-06
6.51 E-06
3.01 E-02
3.01 E-03
3.01 E-03
1,2,3,6,7,8- HxCDF
6.22E-05
6.22E-06
6.22E-06
2.88E-02
2.88E-03
2.88E-03
1,2,3,7,8,9- HxCDF
3.96E-05
3.96E-06
3.96E-06
1.83E-02
1.83E-03
1.83E-03
2,3,4,6,7,8 - HxCDF
7.92E-05
7.92E-06
7.92E-06
3.66E-02
3.66E-03
3.66E-03
1,2,3,4,6,7,8- HpCDF
1.84E-04
1.84E-06
1.84E-06
8.50E-02
8.50E-04
8.50E-04
1,2,3,4,7,8,9- HpCDF
3.96E-05
3.96E-07
3.96E-07
1.83E-02
1.83E-04
1.83E-04
1,2,3,4,6,7,8,9-OCDF
ND
0.00E+00
3.27E-08
ND
0.00E+00
1.51 E-05
TeCDD Total
1.04E-03


4.80E-01


PeCDD Total
3.76E-04


1.74E-01


HxCDD Total
6.28E-04


2.90E-01


HpCDD Total
9.96E-04


4.60E-01


OCDD
1.48E-03


6.84E-01


TeCDF Total
5.52E-03


2.55E+00


PeCDF Total
7.35E-04


3.40E-01


HxCDF Total
5.60E-04


2.59E-01


HpCDF Total
3.17E-04


1.46E-01


OCDF
ND


ND


PCDD Total
4.52E-03


2.09E+00


PCDF Total
7.13E-03


3.30E+00


PCDD/PCDF Total
1.16E-02


5.39E+00


PCDD TEQ Total

6.39E-05
6.39E-05

2.96E-02
2.96E-02
PCDF TEQ Total

1.01 E-04
1.01 E-04

4.68E-02
4.68E-02
PCDD/PCDF TEQ Total

1.65E-04
1.65E-04

7.64E-02
7.64E-02
995
Table B-14. PAH emission factors for 0 % NEW and 32 % NEW.

0%
0%
0%
32 %
32 %
32 %

NEW
NEW
NEW
NEW
NEW
NEW
Compound

mg/kg MRE


mg/kg MRE

Naphthalene
30.7
61.6
45.4
47.9
30.6
40.5
Acenaphthylene
8.4
19.2
17.0
14.3
10.3
11.2
26-B

-------
Acenaphthene(CCC)
0.41
0.90
0.76
0.70
0.43
0.61

Fluorene
2.34
5.78
5.33
3.52
2.63
3.35

Phenanthrene
8.07
21.6
17.9
12.4
8.89
12.12

Anthracene
1.37
3.22
3.03
2.23
1.53
2.16

Fluoranthene(CCC)
1.63
4.43
3.61
2.82
2.13
2.25

Pyrene
1.09
2.93
2.57
2.34
1.59
1.78

Benzo(a)anthracene
0.55
1.81
1.42
0.97
0.60
0.90

Chrysene
0.66
2.22
1.63
1.15
0.75
1.08

Benzo(b)fluoranthene
0.38
1.19
1.15
0.70
0.43
0.57

Benzo(k)fluoranthene
0.31
1.22
0.95
0.66
0.48
0.66

Benzo(a)pyrene(CCC)
0.30
1.15
0.91
0.69
0.41
0.58

lndeno(1,2,3-cd)pyrene
0.23
0.80
0.67
0.44
0.26
0.38

Dibenz(a,h)anthracene
0.09
0.30
0.24
0.13
0.08
0.14

Benzo(ghi)perylene
0.23
0.70
0.59
0.47
0.26
0.39

SUM 16-EPA PAH
57
129
103
91
61
79

Table B-15. PAH emission factors for 66 % NEW, 100 % NEW and baseline (CB/CL 05).



66 %
66 %
66 %
100 %
100 %
100 %
CB/CL

NEW
NEW
NEW
NEW
NEW
NEW
05
Compound

mg/kg MRE


mg/kg MRE

Naphthalene
30.5
34.3
27.6
47.7
36.8
109.1
40.9
Acenaphthylene
11.7
12.1
9.63
14.3
12.2
30.1
14.5
Acenaphthene(CCC)
0.58
0.56
0.56
0.60
0.48
1.53
0.52
Fluorene
3.25
3.03
4.29
3.10
3.41
7.75
2.56
Phenanthrene
12.0
11.6
17.5
12.1
12.1
24.8
9.54
Anthracene
2.16
2.07
2.73
2.14
1.99
4.68
1.98
Fluoranthene(CCC)
2.95
2.90
2.90
2.80
2.89
5.32
3.37
Pyrene
2.17
2.17
1.86
2.33
2.02
4.41
2.97
Benzo(a)anthracene
1.11
1.07
1.10
0.99
0.92
2.15
0.88
Chrysene
1.35
1.39
1.39
1.13
1.07
2.41
0.90
Benzo(b)fluoranthene
0.75
0.77
0.78
0.54
0.65
1.38
0.46
Benzo(k)fluoranthene
0.75
0.81
0.61
0.71
0.65
1.31
0.61
Benzo(a)pyrene(CCC)
0.69
0.70
0.56
0.71
0.50
1.35
0.70
lndeno(1,2,3-cd)pyrene
0.47
0.47
0.35
0.47
0.41
0.90
0.43
Dibenz(a,h)anthracene
0.14
0.14
0.13
0.15
0.12
0.31
0.09
Benzo(ghi)perylene
0.45
0.42
0.25
0.50
0.36
0.88
0.56
SUM 16-EPA PAH
71
75
72
90
77
198
81
Table B-16. PAH TEQ emission factors for 0 % NEW and 32 % NEW.


0 %
0 %
32 %
32 %
32 %

0 % NEW
NEW
NEW
NEW
NEW
NEW
Compound
mg B[a]P TEQ/kg MRE
mg B[a]P TEQ/kg MRE
Phenanthrene
4.04E-03
1.08E-02
8.97E-03
6.21 E-03
4.45E-03
6.06E-03
Anthracene
6.83E-04
1.61E-03
1.51 E-03
1.11 E-03
7.65E-04
1.08E-03
Fluoranthene(CCC)
8.15E-02
2.21 E-01
1.81 E-01
1.41 E-01
1.06E-01
1.12E-01
27-B

-------
Pyrene
1.09E-03
2.93E-03
2.57E-03
2.34E-03
1.59E-03
1.78E-03
Benzo(a)anthracene
2.74E-03
9.07E-03
7.10E-03
4.87E-03
2.99E-03
4.49E-03
Chrysene
1.99E-02
6.66E-02
4.89E-02
3.46E-02
2.25E-02
3.25E-02
Benzo(b)fluoranthene
3.83E-02
1.19E-01
1.15E-01
7.01 E-02
4.31 E-02
5.71 E-02
Benzo(k)fluoranthene
1.53E-02
6.10E-02
4.75E-02
3.32E-02
2.38E-02
3.28E-02
Benzo(a)pyrene(CCC)
3.05E-01
1.15E+00
9.12E-01
6.86E-01
4.14E-01
5.75E-01
lndeno(1,2,3-cd)pyrene
2.33E-02
8.00E-02
6.67E-02
4.38E-02
2.65E-02
3.75E-02
Dibenz(a,h)anthracene
9.48E-02
3.31 E-01
2.61 E-01
1.38E-01
8.77E-02
1.54E-01
Benzo(ghi)perylene
4.57E-03
1.40E-02
1.17E-02
9.37E-03
5.28E-03
7.78E-03
SUM 16-EPA PAH
5.91 E-01
2.06E+00
1.66E+00
1.17E+00
7.39E-01
1.02E+00
1000
Table B-17. PAH TEQ emission factors for 66 % NEW, 100 % NEW and baseline (CB/CL 05).
Compound
66%
66 % NEW 66 % NEW NEW
mg B[a]P TEQ/kg MRE
100 %
NEW
100 %
100% NEW NEW
mg B[a]P TEQ/kg MRE
CB/CL
05
Phenanthrene
6.01 E-03
5.82E-03
8.74E-03
6.05E-03
6.07E-03
1.24E-02
4.77E-03
Anthracene
1.08E-03
1.04E-03
1.36E-03
1.07E-03
9.93E-04
2.34E-03
9.92E-04
Fluoranthene(CCC)
1.48E-01
1.45E-01
1.45E-01
1.40E-01
1.45E-01
2.66E-01
1.69E-01
Pyrene
2.17E-03
2.17E-03
1.86E-03
2.33E-03
2.02E-03
4.41 E-03
2.97E-03
Benzo(a)anthracene
5.57E-03
5.34E-03
5.49E-03
4.94E-03
4.62E-03
1.07E-02
4.40E-03
Chrysene
4.05E-02
4.16E-02
4.16E-02
3.40E-02
3.22E-02
7.23E-02
2.69E-02
Benzo(b)fluoranthene
7.51 E-02
770E-02
7.82E-02
5.37E-02
6.52E-02
1.38E-01
4.64E-02
Benzo(k)fluoranthene
3.77E-02
4.05E-02
3.04E-02
3.57E-02
3.24E-02
6.54E-02
3.05E-02
Benzo(a)pyrene(CCC)
6.87E-01
7.01 E-01
5.58E-01
7.11 E-01
5.01 E-01
1.35E+00
6.96E-01
lndeno(1,2,3-cd)pyrene
4.74E-02
4.72E-02
3.48E-02
4.73E-02
4.11 E-02
8.99E-02
4.33E-02
Dibenz(a,h)anthracene
1.58E-01
1.49E-01
1.48E-01
1.62E-01
1.30E-01
3.37E-01
1.00E-01
Benzo(ghi)perylene
9.09E-03
8.35E-03
4.92E-03
9.91 E-03
7.16E-03
1.77E-02
1.13E-02
SUM 16-EPA PAH
1.22E+00
1.22E+00
1.06E+00
1.21 E+00
9.67E-01
2.37E+00
1.14E+00
1005
Table B-18. PIVh.sand PMio emission factors for MRE tests.


EF PM2.5
EF PM10
Date
Matrix
g/kg MRE
7/30/2015
0 % NEW
11.2
13.9
7/30/2015
0 % NEW
6.9
9.8
7/30/2015
0 % NEW
12.3
15.5
7/30/2015
0 % NEW
19.0
15.3
28-B

-------
7/31/2015
0 % NEW
10.1
10.7
7/31/2015
0 % NEW
14.3
16.2
8/3/2015
32 % NEW
10.1
9.9
8/3/2015
32 % NEW
9.4
9.9
8/4/2015
32 % NEW
12.6
12.8
8/4/2015
32 % NEW
9.6
9.8
8/6/2015
32 % NEW
11.6
12.8
8/6/2015
32 % NEW
9.9
10.6
8/12/2015
66 % NEW
8.2
8.0
8/12/2015
66 % NEW
8.6
8.1
8/13/2015
66 % NEW
7.7
8.9
8/13/2015
66 % NEW
14.2
11.0
8/13/2015
66 % NEW
10.5
9.2
8/13/2015
66 % NEW
12.9
11.8

100 %


7/29/2015
NEW
8.7
10.9

100 %


7/29/2015
NEW
13.5
14.1

100 %


7/31/2015
NEW
14.3
13.9

100 %


7/31/2015
NEW
10.1
11.2

100 %


8/5/2015
NEW
12.6
12.8

100 %


8/5/2015
NEW
12.2
12.5
8/3/2015
Baseline
3.0
3.5
8/3/2015
Baseline
3.3
3.4
1010
29-B

-------
Table B-19. Metal emission factors for MRE tests analyzed from PM2.5 batch filter.3



Al

Si

P

S

CI

K

Fe

Cu

Zn


Al
Unc.
Si
Unc.
P
Unc.
S
Unc.
CI
Unc.
K
Unc.
Fe
Unc.
Cu
Unc.
Zn
Unc.
Date
Test








mg/kg MRE








7/30/2015
0 % NEW
3.33
0.32
5.98
0.36
11.14
0.63
29.59
1.61
83.28
4.44
16.79
0.87
0.331
0.037
0.167
0.026
0.832
0.045
7/30/2015
0 % NEW
2.45
0.23
5.03
0.30
9.29
0.52
23.09
1.24
58.57
3.09
17.03
0.88
0.257
0.027
0.130
0.021
0.517
0.030
7/30/2015
0 % NEW
2.98
0.34
4.91
0.31
8.95
0.51
30.89
1.69
94.26
5.05
16.68
0.87
0.353
0.040
0.175
0.031
0.528
0.031
7/30/2015
0 % NEW
3.73
0.39
6.31
0.37
9.90
0.55
25.25
1.34
67.32
3.53
17.07
0.88
0.287
0.051
0.287
0.039
0.719
0.045
7/31/2015
0 % NEW
1.93
0.22
5.02
0.32
7.46
0.44
23.42
1.30
57.01
3.10
19.04
1.00
0.256
0.025
0.129
0.018
1.029
0.053
7/31/2015
0 % NEW
1.78
0.26
5.11
0.40
14.61
1.03
24.45
1.59
44.90
2.54
17.93
0.96
0.237
0.023
0.119
0.016
1.069
0.055
8/3/2015
32 % NEW
2.19
0.22
4.97
0.34
11.68
0.71
25.85
1.48
63.96
3.54
22.33
1.18
0.146
0.017
0.146
0.013
0.731
0.036
8/3/2015
32 % NEW
2.67
0.30
5.54
0.33
10.58
0.59
18.89
1.04
34.81
1.82
18.07
0.92
0.308
0.040
0.205
0.031
0.821
0.045
8/4/2015
32 % NEW
2.34
0.27
4.68
0.35
6.40
0.42
32.32
1.93
82.45
4.75
20.92
1.14
0.469
0.028
0.140
0.013
0.625
0.032
8/4/2015
32 % NEW
1.77
0.20
5.31
0.36
11.25
0.69
21.87
1.26
34.79
1.95
17.08
0.91
0.312
0.021
0.105
0.012
0.834
0.043
8/6/2015
32 % NEW
2.43
0.28
5.20
0.32
10.93
0.62
30.70
1.68
93.13
4.99
18.21
0.95
0.346
0.036
0.173
0.025
0.519
0.029
8/6/2015
32 % NEW
2.24
0.24
7.65
0.47
11.61
0.66
24.01
1.31
42.60
2.29
24.27
1.26
0.265
0.030
0.265
0.024
0.924
0.048
8/12/2015
66 % NEW
3.16
0.31
6.78
0.39
15.37
0.85
16.38
0.89
39.32
2.05
21.13
1.08
0.228
0.040
0.228
0.031
0.565
0.035
8/12/2015
66 % NEW
1.62
0.20
6.14
0.37
5.81
0.33
20.67
1.12
37.55
1.99
15.50
0.80
0.216
0.026
0.216
0.020
1.076
0.055
8/13/2015
66 % NEW
3.50
0.33
12.02
0.74
11.57
0.66
29.07
1.60
45.96
2.47
18.27
0.95
1.370
0.076
0.151
0.025
1.067
0.054
8/13/2015
66 % NEW
3.31
0.30
15.43
0.95
9.51
0.55
27.55
1.52
52.48
2.84
14.33
0.75
0.551
0.036
0.276
0.024
1.378
0.070
8/13/2015
66 % NEW
3.13
0.31
6.43
0.38
12.86
0.71
29.70
1.60
84.93
4.50
20.84
1.08
0.176
0.037
0.347
0.033
0.694
0.037
8/13/2015
66 % NEW
2.16
0.23
7.17
0.46
10.95
0.64
24.20
1.35
65.56
3.57
14.60
0.77
0.542
0.034
0.135
0.018
0.677
0.036

100%


















7/29/2015
NEW
2.07
0.20
6.22
0.39
8.49
0.49
23.89
1.32
22.80
1.24
19.14
1.00
0.296
0.023
0.198
0.017
1.185
0.060

100%


















7/29/2015
NEW
1.92
0.26
4.72
0.30
11.95
0.70
25.67
1.43
60.17
3.27
25.23
1.32
0.294
0.033
0.147
0.023
1.031
0.053

100%


















7/31/2015
NEW
3.12
0.34
6.24
0.39
8.70
0.50
27.10
1.49
82.95
4.44
21.19
1.10
0.330
0.038
0.165
0.030
1.152
0.059

100%


















7/31/2015
NEW
2.17
0.23
5.50
0.35
10.28
0.60
25.19
1.40
66.45
3.62
19.40
1.02
0.289
0.026
0.144
0.018
0.868
0.044

100%


















8/5/2015
NEW
2.52
0.28
5.71
0.36
10.41
0.60
29.90
1.65
81.82
4.42
19.99
1.05
0.335
0.035
0.335
0.028
0.840
0.045

100%


















8/5/2015
NEW
2.27
0.28
5.68
0.35
10.10
0.57
21.33
1.16
48.33
2.58
20.70
1.07
0.253
0.035
0.253
0.027
0.756
0.043
a Unc = Uncertainty. ND = not detected. b Less than three times the uncertainty.
30-B

-------
1015 Continuation of Table B-19



Br

Na



Ca

Ti



Cr

Mn


Br
Unc.
Na
Unc.
Mg
Na
Ca
Unc.
Ti
Unc.
V
V Unc.
Cr
Unc.
Mn
Unc.
Date
Test







mg/kg MRE







7/30/2015
0 % NEW
2.33
0.12
8.79b
3.20
0.33b
0.81
0.525
0.045
0.331
0.030
0.026b
0.018
0.053b
0.030
0.026b
0.026
7/30/2015
0 % NEW
2.19
0.11
3.83b
2.29
0.64b
0.61
0.512
0.036
0.103
0.021
ND
0.015
0.012b
0.024
0.012b
0.021
7/30/2015
0 % NEW
1.76
0.09
7.13b
4.05
0.11b
1.02
ND
0.036
0.018b
0.031
0.031b
0.022
ND
0.036
ND
0.031
7/30/2015
0 % NEW
2.87
0.15
6.58b
3.96
0.72b
1.10
0.218
0.045
0.146
0.039
ND
0.028
0.056b
0.045
0.056b
0.039
7/31/2015
0 % NEW
2.32
0.12
7.11b
2.73
ND
0.63
0.032b
0.020
0.386
0.025
ND
0.013
ND
0.020
0.032b
0.018
7/31/2015
0 % NEW
2.37
0.12
2.10b
3.92
0.36b
0.83
ND
0.018
0.119
0.016
ND
0.011
ND
0.018
0.059
0.016
8/3/2015
32 % NEW
2.34
0.12
6.28b
2.72
0.44b
0.56
ND
0.015
0.437
0.025
ND
0.010
ND
0.015
0.038b
0.013
8/3/2015
32 % NEW
1.95
0.10
6.41b
3.07
ND
0.87
0.008b
0.036
0.080b
0.031
ND
0.022
ND
0.036
ND
0.031
8/4/2015
32 % NEW
2.19
0.11
1.75b
3.35
0.31b
0.67
ND
0.015
0.140
0.015
0.030
0.009
ND
0.015
ND
0.013
8/4/2015
32 % NEW
1.87
0.09
6.12b
2.63
ND
0.53
ND
0.014
0.312
0.019
0.032
0.009
0.022b
0.014
ND
0.012
8/6/2015
32 % NEW
2.08
0.10
6.25b
3.19
ND
0.81
0.476
0.040
0.105
0.025
ND
0.018
0.033b
0.029
0.033b
0.025
8/6/2015
32 % NEW
2.24
0.11
12.25
2.98
0.79b
0.68
0.083
0.024
0.117
0.021
ND
0.015
ND
0.024
0.049b
0.021
8/12/2015
66 % NEW
2.37
0.12
2.46b
2.81
0.34b
0.82
ND
0.035
0.022b
0.031
0.059b
0.022
0.051b
0.035
0.070b
0.031
8/12/2015
66 % NEW
1.29
0.07
12.85
2.68
0.64b
0.62
ND
0.023
0.064
0.020
0.058
0.014
0.058b
0.023
0.015b
0.020
8/13/2015
66 % NEW
2.13
0.11
17.78
3.80
1.52b
0.83
0.175
0.029
0.151
0.025
0.054
0.018
0.529
0.036
0.087
0.025
8/13/2015
66 % NEW
2.34
0.12
4.96b
2.89
0.14b
0.71
0.146
0.024
0.082
0.021
ND
0.015
0.045b
0.024
0.045b
0.021
8/13/2015
66 % NEW
3.13
0.16
5.32b
3.09
0.35b
0.84
0.271
0.037
0.139
0.029
0.054b
0.020
0.067b
0.033
0.013b
0.029
8/13/2015
66 % NEW
2.03
0.10
4.37b
2.75
0.68b
0.66
0.015b
0.021
0.135
0.018
0.015b
0.013
0.127
0.021
ND
0.018

100%
















7/29/2015
NEW
1.88
0.09
10.37
2.38
0.20b
0.51
ND
0.017
0.098
0.015
ND
0.011
0.098
0.017
ND
0.015

100%
















7/29/2015
NEW
1.92
0.10
9.74b
3.65
ND
0.83
ND
0.027
0.591
0.037
0.011b
0.017
0.036b
0.027
0.011b
0.023

100%
















7/31/2015
NEW
2.30
0.12
5.19b
3.80
0.82b
0.97
ND
0.034
0.081b
0.030
0.047b
0.021
ND
0.034
0.015b
0.030

100%
















7/31/2015
NEW
2.32
0.12
5.71b
2.70
0.054b
0.64
ND
0.021
0.144
0.018
ND
0.013
0.050b
0.021
0.020b
0.018

100%
















8/5/2015
NEW
2.35
0.12
5.73b
3.35
ND
0.83
0.106
0.028
0.167
0.024
ND
0.017
0.053b
0.028
0.022b
0.024

100%
















8/5/2015
NEW
1.52
0.08
11.62
3.49
0.74b
0.86
0.090b
0.031
0.253
0.027
0.018b
0.019
ND
0.031
0.018b
0.027
a Unc = Uncertainty. ND = not detected. b Less than three times the uncertainty.
31-B

-------
Continuation of Table B-19



Co

Ni

Ga

Ge

As

Se

Rb

Sr


Co
Unc.
Ni
Unc.
Ga
Unc.
Ge
Unc.
As
Unc.
Se
Unc.
Rb
Unc
Sr
Unc.
Date
Test
















7/30/2015
0 % NEW
0.012b
0.018
ND
0.015
0.012b
0.015
0.012b
0.015
ND
0.018
0.012b
0.011
ND
0.008
ND
0.022
7/30/2015
0 % NEW
ND
0.015
ND
0.012
0.012b
0.012
0.026b
0.012
ND
0.015
0.012b
0.009
ND
0.006
ND
0.018
7/30/2015
0 % NEW
ND
0.022
ND
0.018
ND
0.018
0.047b
0.018
0.047b
0.022
ND
0.013
0.031b
0.013
0.031b
0.027
7/30/2015
0 % NEW
0.021b
0.028
0.034b
0.022
0.021b
0.022
0.034b
0.022
0.043b
0.028
ND
0.017
ND
0.011
ND
0.034
7/31/2015
0 % NEW
ND
0.013
0.010b
0.010
0.010b
0.010
0.010b
0.010
ND
0.013
0.010b
0.008
ND
0.005
ND
0.015
7/31/2015
0 % NEW
ND
0.011
ND
0.009
0.011b
0.009
0.011b
0.009
ND
0.011
ND
0.007
ND
0.005
ND
0.014
8/3/2015
32 % NEW
ND
0.010
0.013b
0.008
0.013b
0.008
0.013b
0.008
ND
0.010
ND
0.006
ND
0.004
0.025b
0.012
8/3/2015
32 % NEW
0.029b
0.022
0.020b
0.018
0.049b
0.018
ND
0.018
0.029b
0.022
0.008b
0.013
ND
0.009
ND
0.027
8/4/2015
32 % NEW
0.014b
0.009
ND
0.007
ND
0.007
ND
0.007
0.014b
0.009
0.014b
0.006
ND
0.004
0.014b
0.011
8/4/2015
32 % NEW
0.011b
0.009
ND
0.007
0.022
0.007
0.032
0.007
ND
0.009
0.011b
0.005
0.032
0.005
ND
0.011
8/6/2015
32 % NEW
0.016b
0.018
ND
0.014
0.046
0.014
0.046
0.014
0.033b
0.018
0.046
0.011
ND
0.007
0.046b
0.022
8/6/2015
32 % NEW
ND
0.015
ND
0.012
0.034b
0.012
0.015b
0.012
0.015b
0.015
0.034
0.009
ND
0.006
0.068
0.021
8/12/2015
66 % NEW
ND
0.022
0.031b
0.017
0.019b
0.017
0.012b
0.017
ND
0.022
0.031b
0.013
0.051
0.013
0.012b
0.026
8/12/2015
66 % NEW
ND
0.014
0.027b
0.012
ND
0.012
0.058
0.012
ND
0.014
0.069
0.009
0.042
0.009
0.027b
0.018
8/13/2015
66 % NEW
ND
0.018
0.158
0.018
ND
0.014
0.033b
0.014
0.033b
0.018
0.017b
0.011
0.087
0.011
0.054b
0.022
8/13/2015
66 % NEW
ND
0.015
0.058
0.012
0.029b
0.012
0.029b
0.012
ND
0.015
0.016b
0.009
0.016b
0.009
0.016b
0.018
8/13/2015
66 % NEW
ND
0.020
ND
0.016
ND
0.016
0.041b
0.016
ND
0.020
0.013b
0.012
0.041
0.012
ND
0.025
8/13/2015
66 % NEW
ND
0.013
0.048
0.010
0.030b
0.010
0.015b
0.010
ND
0.013
ND
0.008
0.078
0.008
0.015b
0.016

100%
















7/29/2015
NEW
ND
0.011
0.019b
0.008
0.011b
0.008
0.019b
0.008
ND
0.011
0.041
0.006
0.041
0.006
ND
0.013

100%
















7/29/2015
NEW
0.025b
0.017
0.011b
0.013
ND
0.013
0.025b
0.013
0.049b
0.017
ND
0.010
0.060
0.010
0.011b
0.020

100%
















7/31/2015
NEW
ND
0.021
0.031b
0.017
0.031b
0.017
0.047b
0.017
ND
0.021
0.031b
0.013
ND
0.009
0.031b
0.025

100%
















7/31/2015
NEW
ND
0.013
0.011b
0.010
0.020b
0.010
ND
0.010
0.031b
0.013
ND
0.008
ND
0.005
ND
0.016

100%
















8/5/2015
NEW
ND
0.017
ND
0.014
ND
0.014
0.022b
0.014
ND
0.017
0.022b
0.010
ND
0.007
ND
0.021

100%
















8/5/2015
NEW
ND
0.019
0.018b
0.016
ND
0.016
0.008b
0.016
0.022b
0.019
0.004b
0.012
0.018b
0.012
0.004b
0.023
a Unc = Uncertainty. ND = not detected. b less than three times the uncertainty.
32-B

-------
Continuation of Table B-19



Zr

Mo

Pd

Ag

Cd

In

Sn

Sb


Zr
Unc.
Mo
Unc.
Pd
Unc.
Ag
Unc.
Cd
Unc.
In
Unc.
Sn
Unc.
Sb
Unc.
Date
Test







mg/kg MRE







7/30/2015
0 % NEW
ND
0.045
ND
0.078
ND
0.078
0.117b
0.078
0.132b
0.078
0.261b
0.119
ND
0.137
ND
0.241
7/30/2015
0 % NEW
ND
0.036
0.026b
0.062
0.026b
0.062
ND
0.062
0.129b
0.062
ND
0.095
0.184b
0.115
ND
0.192
7/30/2015
0 % NEW
0.063b
0.054
0.153b
0.094
0.063b
0.094
0.016b
0.094
0.066b
0.094
0.309b
0.143
0.309b
0.165
0.614b
0.295
7/30/2015
0 % NEW
ND
0.068
0.056b
0.118
ND
0.118
ND
0.118
0.043b
0.163
0.218b
0.180
ND
0.208
ND
0.365
7/31/2015
0 % NEW
0.042b
0.031
ND
0.053
0.063b
0.053
0.021b
0.053
0.107b
0.053
0.107b
0.081
0.095b
0.099
0.190b
0.173
7/31/2015
0 % NEW
0.070b
0.027
ND
0.048
0.118b
0.048
0.036b
0.048
0.059b
0.048
0.107b
0.073
0.237b
0.084
0.130b
0.151
8/3/2015
32 % NEW
ND
0.023
ND
0.040
ND
0.040
ND
0.040
ND
0.056
ND
0.061
0.094b
0.071
0.259b
0.138
8/3/2015
32 % NEW
0.029b
0.054
ND
0.094
ND
0.094
0.057b
0.094
0.029b
0.094
ND
0.143
0.078b
0.165
ND
0.290
8/4/2015
32 % NEW
ND
0.022
ND
0.039
0.074b
0.039
ND
0.039
ND
0.054
ND
0.060
0.012b
0.071
0.464
0.125
8/4/2015
32 % NEW
0.032b
0.021
ND
0.037
ND
0.037
ND
0.037
ND
0.051
ND
0.057
ND
0.066
0.288b
0.121
8/6/2015
32 % NEW
ND
0.043
ND
0.076
ND
0.076
ND
0.076
0.159b
0.105
ND
0.116
0.235b
0.133
0.331b
0.238
8/6/2015
32 % NEW
0.165b
0.036
ND
0.063
0.034b
0.063
ND
0.063
ND
0.087
ND
0.096
ND
0.111
0.658
0.199
8/12/2015
66 % NEW
ND
0.053
ND
0.092
0.101b
0.092
ND
0.092
ND
0.127
0.202b
0.140
ND
0.162
0.202b
0.285
8/12/2015
66 % NEW
0.042b
0.035
ND
0.061
ND
0.061
0.058b
0.061
ND
0.085
ND
0.093
0.427
0.108
1.767
0.195
8/13/2015
66 % NEW
ND
0.043
ND
0.076
ND
0.076
ND
0.076
0.175b
0.105
0.158b
0.115
ND
0.133
1.394
0.241
8/13/2015
66 % NEW
ND
0.036
ND
0.064
0.016b
0.064
ND
0.064
ND
0.064
ND
0.097
0.380
0.121
1.035
0.200
8/13/2015
66 % NEW
ND
0.049
ND
0.086
0.067b
0.086
0.041b
0.086
0.108b
0.118
ND
0.131
1.899
0.192
0.542b
0.269
8/13/2015
66 % NEW
ND
0.031
0.093b
0.055
ND
0.055
0.030b
0.055
ND
0.076
ND
0.083
ND
0.096
1.019
0.177

100%
















7/29/2015
NEW
ND
0.026
ND
0.045
ND
0.045
0.019b
0.045
ND
0.062
ND
0.068
0.045b
0.083
0.918
0.143

100%
















7/29/2015
NEW
ND
0.040
ND
0.070
ND
0.070
ND
0.070
ND
0.097
ND
0.107
0.172b
0.123
ND
0.217

100%
















7/31/2015
NEW
ND
0.051
0.151b
0.089
0.015b
0.089
ND
0.089
ND
0.123
0.151b
0.136
0.104b
0.157
0.743
0.229

100%
















7/31/2015
NEW
0.020b
0.031
ND
0.054
0.020b
0.054
ND
0.054
ND
0.075
0.040b
0.083
ND
0.095
0.733
0.201

100%
















8/5/2015
NEW
0.022b
0.042
ND
0.073
0.086b
0.073
0.106b
0.073
0.106b
0.101
ND
0.112
ND
0.129
0.516b
0.230
8/5/2015
100% NEW
0.014b
0.047
ND
0.082
ND
0.082
0.018b
0.082
ND
0.113
ND
0.125
ND
0.144
0.199b
0.257
1020 a Unc = Uncertainty. ND = not detected. b lessL than three times the uncertainty.
33-B

-------
Continuation of Table B-19



Ba

La

Hg

Pb




Ba
Unc.
La
Unc.
Hg
Unc.
Pb
Unc.
Y
YUnc.
Date
Test




mg/kg MRE




7/30/2015
0 % NEW
ND
0.108
ND
0.056
0.091
0.022
0.065
0.015
0.026b
0.034
7/30/2015
0 % NEW
ND
0.086
ND
0.044
0.012b
0.018
0.076
0.012
ND
0.027
7/30/2015
0 % NEW
0.461
0.134
0.137b
0.072
0.031b
0.027
0.078
0.018
ND
0.040
7/30/2015
0 % NEW
ND
0.163
ND
0.085
ND
0.034
0.086
0.022
ND
0.051
7/31/2015
0 % NEW
ND
0.074
ND
0.038
0.032b
0.015
0.053
0.010
0.010b
0.023
7/31/2015
0 % NEW
ND
0.066
ND
0.034
ND
0.014
0.070
0.009
0.011b
0.021
8/3/2015
32 % NEW
ND
0.056
ND
0.029
ND
0.012
ND
0.008
0.013b
0.017
8/3/2015
32 % NEW
ND
0.130
ND
0.067
ND
0.027
0.037b
0.018
ND
0.040
8/4/2015
32 % NEW
ND
0.054
0.030b
0.028
ND
0.011
ND
0.007
ND
0.017
8/4/2015
32 % NEW
ND
0.051
ND
0.027
ND
0.011
0.063
0.007
ND
0.016
8/6/2015
32 % NEW
ND
0.105
0.079b
0.058
0.096b
0.022
ND
0.014
ND
0.033
8/6/2015
32 % NEW
ND
0.087
ND
0.045
0.015b
0.018
0.034b
0.012
0.034b
0.027
8/12/2015
66 % NEW
ND
0.127
ND
0.066
ND
0.026
0.101
0.017
ND
0.040
8/12/2015
66 % NEW
ND
0.085
0.115b
0.047
0.015b
0.018
0.100
0.012
ND
0.026
8/13/2015
66 % NEW
ND
0.105
0.071b
0.054
ND
0.022
0.104
0.014
ND
0.033
8/13/2015
66 % NEW
ND
0.088
ND
0.046
0.016b
0.018
0.117
0.012
ND
0.027
8/13/2015
66 % NEW
ND
0.118
0.108b
0.065
ND
0.025
0.029b
0.016
ND
0.037
8/13/2015
66 % NEW
ND
0.076
ND
0.039
ND
0.016
0.063
0.010
ND
0.024

100%










7/29/2015
NEW
ND
0.062
ND
0.032
ND
0.013
0.041
0.008
ND
0.019

100%










7/29/2015
NEW
ND
0.097
ND
0.050
ND
0.020
ND
0.013
0.011b
0.030

100%










7/31/2015
NEW
ND
0.123
0.031b
0.064
ND
0.025
0.120
0.017
0.047b
0.038

100%










7/31/2015
NEW
ND
0.075
0.011b
0.039
ND
0.016
0.020b
0.010
ND
0.023

100%










8/5/2015
NEW
ND
0.101
0.031b
0.052
ND
0.021
0.042
0.014
ND
0.031

100%










8/5/2015
NEW
ND
0.113
ND
0.059
ND
0.023
ND
0.016
0.014b
0.035
a Unc = Uncertainty. ND = not detected. bLess than three times the uncertainty.
34-B

-------
Table B-20. VOC emission factor from open burning of 100 % NEW composite MRE material.


1
100 % NEW
2

3

EF
Method
Detection
Limit
EF
Method
Detection
Limit
EF
Method
Detection
Limit
Compound


mg/kg MRE


Propene
222.76
0.40
266.94
1.08
368.20
0.83
Dichlorodifluoromethane (CFC-12)
0.07
0.48
ND
0.13
ND
0.10
Chloromethane
3.56
0.44
2.87
0.12
2.79
0.09
1,2-Dichloro-1,1,2,2-
tetrafluoroethane (CFC-114)
ND
0.55
ND
0.15
ND
0.11
Vinyl Chloride
ND
0.48
0.53
0.13
0.52
0.10
1,3-Butadiene
88.00
0.62
42.25
0.17
150.85
1.31
Bromomethane
ND
0.55
0.48
0.15
0.29
0.11
Chloroethane
ND
0.48
0.26
0.13
0.31
0.10
Ethanol
4.40
2.31
ND
0.63
5.95
0.48
Acetonitrile
11.60
0.51
11.78
0.14
14.94
0.11
Acrolein
95.11
0.48
136.69
1.31
146.64
0.99
Acetone
ND
2.24
ND
0.63
114.73
0.44
Trichlorofluoromethane
ND
0.48
ND
0.13
ND
0.10
2-Propanol (Isopropyl Alcohol)
1.98
1.21
ND
0.33
ND
0.25
Acrylonitrile
6.97
0.48
8.56
0.13
9.53
0.10
1,1-Dichloroethene
ND
0.48
ND
0.13
ND
0.10
Methylene Chloride
31.72
0.48
2.97
0.13
ND
0.10
3-Chloro-1 -propene (Allyl Chloride)
ND
0.48
ND
0.13
ND
0.10
Trichlorotrifluoroethane
ND
0.48
ND
0.13
ND
0.10
Carbon Disulfide
ND
0.44
ND
0.12
ND
0.09
trans-1,2-Dichloroethene
ND
0.55
0.20
0.15
ND
0.11
1,1-Dichloroethane
ND
0.48
ND
0.13
ND
0.10
Methyl tert-Butyl Ether
ND
0.48
ND
0.13
ND
0.10
Vinyl Acetate
77.00
1.87
125.62
0.51
123.07
0.39
2-Butanone (MEK)
15.14
0.62
27.58
0.17
29.50
0.12
cis-1,2-Dichloroethene
ND
0.48
0.31
0.13
ND
0.10
Ethyl Acetate
9.53
1.03
ND
0.27
ND
0.21
n-Hexane
6.70
0.44
9.30
0.12
15.59
0.09
Chloroform
ND
0.48
0.29
0.13
ND
0.10
Tetrahydrofuran (THF)
1.69
0.59
2.97
0.15
3.22
0.12
1,2-Dichloroethane
ND
0.48
ND
0.13
ND
0.10
1,1,1-Trichloroethane
ND
0.48
ND
0.13
ND
0.10
Benzene
197.88
0.48
211.07
1.26
265.84
0.95
Carbon Tetrachloride
ND
0.44
0.03
0.12
0.01
0.09
Cyclohexane
ND
0.84
ND
0.23
0.48
0.17
1,2-Dichloropropane
ND
0.48
0.21
0.13
ND
0.10
35-B

-------
Bromodichloromethane
ND
0.44
ND
0.12
ND
0.09
Trichloroethene
ND
0.40
ND
0.11
ND
0.08
1,4-Dioxane
ND
0.48
ND
0.13
ND
0.10
Methyl Methacrylate
ND
0.88
ND
0.24
ND
0.18
n-Heptane
8.07
0.48
8.56
0.13
13.89
0.10
cis-1,3-Dichloropropene
ND
0.40
ND
0.11
ND
0.08
4-Methyl-2-pentanone
0.88
0.48
1.20
0.13
1.95
0.10
trans-1,3-Dichloropropene
ND
0.48
ND
0.13
ND
0.10
1,1,2-Trichloroethane
ND
0.48
ND
0.13
ND
0.10
Toluene
76.85
0.48
41.45
0.13
55.42
0.10
2-Hexanone
4.40
0.48
5.02
0.13
6.35
0.10
Dibromochloromethane
ND
0.48
ND
0.13
ND
0.10
1,2-Dibromoethane
ND
0.48
ND
0.13
ND
0.10
n-Butyl Acetate
ND
0.48
ND
0.13
ND
0.10
n-Octane
5.50
0.51
6.85
0.14
10.72
0.11
Tetrachloroethene
ND
0.40
ND
0.11
ND
0.08
Chlorobenzene
ND
0.48
0.23
0.13
0.13
0.10
Ethyl benzene
20.53
0.48
8.56
0.13
14.69
0.10
m-,p-Xylenes
5.50
0.88
4.45
0.23
7.15
0.18
Bromoform
ND
0.44
ND
0.12
ND
0.09
Styrene
194.34
0.44
37.69
0.12
127.04
0.87
o-Xylene
3.08
0.44
2.34
0.12
3.77
0.09
n-Nonane
4.03
0.44
5.60
0.12
8.73
0.09
1,1,2,2-Tetrachloroethane
ND
0.44
ND
0.12
ND
0.09
Cumene
1.10
0.44
0.46
0.12
0.91
0.09
alpha-Pinene
0.55
0.40
ND
0.11
0.87
0.08
n-Propylbenzene
1.72
0.48
1.03
0.13
1.71
0.10
4-Ethyltoluene
0.62
0.48
0.57
0.13
0.91
0.10
1,3,5-Trimethyl benzene
ND
0.48
0.33
0.13
0.67
0.10
1,2,4-Trimethyl benzene
0.70
0.44
0.69
0.12
1.79
0.09
Benzyl Chloride
ND
0.32
0.18
0.09
ND
0.06
1,3-Dichlorobenzene
ND
0.44
ND
0.12
ND
0.09
1,4-Dichlorobenzene
ND
0.40
ND
0.11
ND
0.08
1,2-Dichlorobenzene
ND
0.44
ND
0.12
ND
0.09
d-Limonene
0.77
0.40
0.86
0.11
1.19
0.08
1,2-Dibromo-3-chloropropane
ND
0.29
ND
0.08
ND
0.06
1,2,4-Trichlorobenzene
ND
0.48
ND
0.13
ND
0.10
Naphthalene
44.00
0.51
34.26
0.14
35.33
0.11
Hexachlorobutadiene
ND
0.40
ND
0.11
ND
0.08

g/kg MRE

g/kg MRE

g/kg MRE

Carbon Monoxide
19.78

21.62

23.69

Methane
0.89

0.52

0.83

36-B

-------
Carbon Dioxide
1659.67
1657.77
1653.67
MCE ratio
0.980
0.979
0.977
1025
37-B

-------
Table B-21. VOC emission factor from open burning of 66 % NEW composite MRE material.


66 % NEW
1
2

EF
Method
Detection
Limit
EF
Method
Detection
Limit
Compound

mg/kg MRE

Propene
249.59
1.51
256.14
1.56
Dichlorodifluoromethane (CFC 12)
ND
0.09
ND
0.38
Chloromethane
1,2-Dichloro-1,1,2,2-
tetrafluoroethane (CFC 114)
1.96
ND
0.08
0.10
4.52
ND
0.33
0.42
Vinyl Chloride
0.37
0.09
0.46
0.38
1,3-Butadiene
84.73
2.36
80.11
0.51
Bromomethane
0.22
0.10
ND
0.42
Chloroethane
0.23
0.09
ND
0.38
Ethanol
5.53
0.44
ND
1.77
Acetonitrile
6.86
0.10
10.81
0.40
Acrolein
113.98
1.81
138.88
0.38
Acetone
ND
0.41
88.12
1.73
Trichlorofluoromethane
ND
0.09
ND
0.38
2-Propanol (Isopropyl Alcohol)
ND
0.22
ND
0.93
Acrylonitrile
4.05
0.09
6.32
0.38
1,1-Dichloroethene
ND
0.09
ND
0.38
Methylene Chloride
ND
0.09
ND
0.38
3-Chloro-1 -propene (Allyl Chloride)
ND
0.08
ND
0.35
Trichlorotrifluoroethane
ND
0.09
ND
0.38
Carbon Disulfide
ND
0.08
ND
0.33
trans-1,2-Dichloroethene
ND
0.10
ND
0.42
1,1-Dichloroethane
ND
0.08
ND
0.35
Methyl tert-Butyl Ether
ND
0.09
ND
0.38
Vinyl Acetate
77.36
0.35
109.62
1.43
2-Butanone (MEK)
20.00
0.11
29.64
0.46
cis-1,2-Dichloroethene
ND
0.08
ND
0.35
Ethyl Acetate
ND
0.19
ND
0.76
n-Hexane
8.21
0.08
9.82
0.33
Chloroform
0.29
0.09
ND
0.38
Tetrahydrofuran (THF)
2.51
0.11
3.04
0.46
1,2-Dichloroethane
ND
0.08
ND
0.35
1,1,1-Trichloroethane
ND
0.09
ND
0.38
Benzene
169.34
1.69
193.80
0.35
Carbon Tetrachloride
0.06
0.08
ND
0.33
Cyclohexane
ND
0.15
ND
0.63
1,2-Dichloropropane
ND
0.08
ND
0.35
38-B

-------
Bromodichloromethane
ND
0.08
ND
0.33
Trichloroethene
ND
0.07
ND
0.31
1,4-Dioxane
ND
0.08
ND
0.35
Methyl Methacrylate
ND
0.17
ND
0.67
n-Heptane
7.74
0.09
12.65
0.38
cis-1,3-Dichloropropene
ND
0.07
ND
0.31
4-Methyl-2-pentanone
ND
0.08
0.67
0.35
trans-1,3-Dichloropropene
ND
0.08
ND
0.35
1,1,2-Trichloroethane
ND
0.08
ND
0.35
Toluene
40.37
0.09
63.07
0.38
2-Hexanone
3.68
0.08
6.32
0.35
Dibromochloromethane
ND
0.08
ND
0.35
1,2-Dibromoethane
ND
0.08
ND
0.35
n-Butyl Acetate
ND
0.08
ND
0.35
n-Octane
5.89
0.10
8.85
0.40
Tetrachloroethene
ND
0.07
ND
0.31
Chlorobenzene
ND
0.08
ND
0.35
Ethyl benzene
18.79
0.08
18.13
0.35
m-,p-Xylenes
4.05
0.16
5.48
0.67
Bromoform
ND
0.08
ND
0.33
Styrene
187.88
1.62
231.90
0.33
o-Xylene
2.25
0.08
3.04
0.33
n-Nonane
5.16
0.08
7.17
0.33
1,1,2,2-Tetrachloroethane
ND
0.08
ND
0.33
Cumene
1.14
0.08
1.26
0.33
alpha-Pinene
0.74
0.07
1.01
0.31
n-Propylbenzene
1.14
0.08
1.90
0.35
4-Ethyltoluene
0.48
0.08
0.63
0.35
1,3,5-Trimethyl benzene
0.25
0.08
ND
0.35
1,2,4-Trimethyl benzene
0.70
0.08
1.01
0.33
Benzyl Chloride
0.17
0.06
ND
0.24
1,3-Dichlorobenzene
ND
0.08
ND
0.33
1,4-Dichlorobenzene
ND
0.07
ND
0.31
1,2-Dichlorobenzene
ND
0.08
ND
0.33
d-Limonene
0.66
0.07
1.26
0.31
1,2-Dibromo-3-chloropropane
ND
0.05
ND
0.22
1,2,4-Trichlorobenzene
ND
0.08
ND
0.35
Naphthalene
23.58
0.10
46.38
0.40
Hexachlorobutadiene
ND
0.07
ND
0.31

g/kg
biomass

g/kg biomass

Carbon Monoxide
16.49

20.32

39-B

-------
Methane
0.46
0.58
Carbon Dioxide
1534.60
1528.24
MCE ratio
0.983
0.979
40-B

-------
Table B-22. VOC emission factor from open burning of 32 % NEW composite MRE material.



32 % NEW




1

2

3

EF
Method
Detection
Limit
EF
Method
Detection
Limit
EF
Method
Detection
Limit
Compound


mg/kg MRE


Propene
311.64
0.90
341.65
1.07
335.09
0.78
Dichlorodifluoromethane (CFC 12)
ND
0.11
ND
0.13
ND
0.09
Chloromethane
2.39
0.09
2.48
0.11
2.00
0.08
1,2-Dichloro-1,1,2,2-
tetrafluoroethane (CFC 114)
ND
0.12
ND
0.14
ND
0.11
Vinyl Chloride
0.55
0.11
0.64
0.13
0.59
0.09
1,3-Butadiene
121.14
1.37
139.34
1.66
117.23
1.21
Bromomethane
0.25
0.12
0.46
0.14
0.27
0.11
Chloroethane
0.29
0.11
0.23
0.13
0.22
0.09
Ethanol
ND
0.51
ND
0.59
1.64
0.43
Acetonitrile
11.58
0.11
11.06
0.14
13.53
0.10
Acrolein
128.71
1.06
160.44
1.29
144.35
0.94
Acetone
ND
0.47
101.29
0.59
105.12
0.43
Trichlorofluoromethane
ND
0.11
ND
0.13
ND
0.09
2-Propanol (Isopropyl Alcohol)
ND
0.27
ND
0.32
ND
0.23
Acrylonitrile
6.64
0.11
7.50
0.13
7.03
0.09
1,1-Dichloroethene
ND
0.11
ND
0.13
ND
0.09
Methylene Chloride
ND
0.11
ND
0.13
ND
0.09
3-Chloro-1 -propene (Allyl Chloride)
ND
0.10
ND
0.12
ND
0.09
Trichlorotrifluoroethane
ND
0.11
ND
0.13
ND
0.09
Carbon Disulfide
ND
0.09
ND
0.11
0.59
0.08
trans-1,2-Dichloroethene
0.23
0.12
0.29
0.14
ND
0.11
1,1-Dichloroethane
ND
0.10
ND
0.12
ND
0.09
Methyl tert-Butyl Ether
ND
0.11
ND
0.13
ND
0.09
Vinyl Acetate
85.97
0.39
133.98
0.49
113.33
0.36
2-Butanone (MEK)
22.00
0.13
28.03
0.16
29.03
0.12
cis-1,2-Dichloroethene
ND
0.10
ND
0.12
ND
0.09
Ethyl Acetate
ND
0.22
ND
0.27
ND
0.20
n-Hexane
11.44
0.09
11.94
0.11
13.79
0.08
Chloroform
0.25
0.11
ND
0.13
ND
0.09
Tetrahydrofuran (THF)
2.54
0.13
2.89
0.15
2.77
0.11
1,2-Dichloroethane
ND
0.10
ND
0.12
ND
0.09
1,1,1-Trichloroethane
ND
0.11
ND
0.13
ND
0.09
Benzene
257.78
1.02
262.41
1.23
277.31
0.90
Carbon Tetrachloride
0.02
0.09
0.02
0.11
0.01
0.08
Cyclohexane
ND
0.18
ND
0.22
0.51
0.16
41-B

-------
1,2-Dichloropropane
ND
0.10
0.28
0.12
ND
0.09
Bromodichloromethane
ND
0.09
ND
0.11
ND
0.08
Trichloroethene
ND
0.09
ND
0.11
ND
0.08
1,4-Dioxane
0.25
0.10
ND
0.12
ND
0.09
Methyl Methacrylate
ND
0.20
ND
0.24
ND
0.17
n-Heptane
11.33
0.11
12.33
0.13
13.29
0.09
cis-1,3-Dichloropropene
ND
0.09
ND
0.11
ND
0.08
4-Methyl-2-pentanone
ND
0.10
ND
0.12
1.29
0.09
trans-1,3-Dichloropropene
ND
0.10
ND
0.12
ND
0.09
1,1,2-Trichloroethane
0.13
0.10
ND
0.12
ND
0.09
Toluene
62.36
0.11
52.30
0.13
120.98
0.94
2-Hexanone
4.69
0.10
5.90
0.12
6.25
0.09
Dibromochloromethane
ND
0.10
ND
0.12
ND
0.09
1,2-Dibromoethane
ND
0.10
ND
0.12
ND
0.09
n-Butyl Acetate
0.28
0.10
0.18
0.12
ND
0.09
n- Octane
8.99
0.11
9.11
0.14
10.16
0.10
Tetrachloroethene
ND
0.09
ND
0.11
ND
0.08
Chlorobenzene
ND
0.10
0.28
0.12
0.19
0.09
Ethyl benzene
20.32
0.10
12.33
0.12
39.08
0.09
m-,p-Xylenes
5.86
0.19
5.20
0.23
7.03
0.17
Bromoform
ND
0.09
ND
0.11
ND
0.08
Styrene
207.11
0.94
133.98
1.13
508.01
0.82
o-Xylene
3.17
0.09
2.68
0.11
3.79
0.08
n-Nonane
7.42
0.09
7.50
0.11
8.60
0.08
1,1,2,2-Tetrachloroethane
ND
0.09
0.13
0.11
ND
0.08
Cumene
1.37
0.09
0.70
0.11
2.46
0.08
alpha-Pinene
ND
0.09
0.91
0.11
0.70
0.08
n-Propylbenzene
1.76
0.10
1.23
0.12
2.27
0.09
4-Ethyltoluene
0.70
0.10
0.64
0.12
0.98
0.09
1,3,5-Trimethyl benzene
0.32
0.10
0.31
0.12
0.74
0.09
1,2,4-Trimethyl benzene
0.86
0.09
0.75
0.11
1.91
0.08
Benzyl Chloride
0.16
0.07
0.12
0.09
ND
0.06
1,3-Dichlorobenzene
ND
0.09
ND
0.11
ND
0.08
1,4-Dichlorobenzene
ND
0.09
ND
0.11
ND
0.08
1,2-Dichlorobenzene
ND
0.09
ND
0.11
ND
0.08
d-Limonene
0.70
0.09
1.07
0.11
1.17
0.08
1,2-Dibromo-3-chloropropane
ND
0.06
ND
0.08
ND
0.05
1,2,4-Trichlorobenzene
ND
0.10
ND
0.12
ND
0.09
Naphthalene
38.69
0.11
33.23
0.14
33.22
0.10
Hexachlorobutadiene
ND
0.09
ND
0.11
ND
0.08

g/kg biomass
g/kg biomass
g/kg biomass
Carbon Monoxide
22.87

23.98

22.87

42-B

-------
Methane
0.82
0.70
0.82
Carbon Dioxide
1557.34
1555.91
1557.34
MCE ratio
0.976
0.975
0.976
1030
43-B

-------
Table B-23. VOC emission factor from open burning of 0 % NEW composite MRE material.



0 % NEW




1

2

3

EF
Method
Detection
Limit
EF
Method
Detection
Limit
EF
Method
Detection
Limit
Compound


mg/kg MRE


Propene
200.93
0.42
242.02
0.69
361.04
0.83
Dichlorodifluoromethane (CFC 12)
0.10
0.49
ND
0.08
ND
0.10
Chloromethane
5.12
0.45
1.42
0.08
3.06
0.09
1,2-Dichloro-1,1,2,2-
tetrafluoroethane (CFC 114)
ND
0.56
ND
0.09
ND
0.11
Vinyl Chloride
ND
0.49
0.36
0.08
0.74
0.10
1,3-Butadiene
69.59
0.63
94.27
1.09
143.98
1.27
Bromomethane
ND
0.56
0.21
0.09
0.70
0.11
Chloroethane
ND
0.49
0.09
0.08
0.24
0.10
Ethanol
3.20
2.33
4.35
0.40
1.83
0.48
Acetonitrile
7.87
0.52
4.94
0.09
9.87
0.10
Acrolein
111.12
0.49
94.04
0.83
169.89
1.00
Acetone
ND
2.26
ND
0.40
126.09
0.44
Trichlorofluoromethane
ND
0.49
ND
0.08
ND
0.10
2-Propanol (Isopropyl Alcohol)
ND
1.22
ND
0.21
ND
0.24
Acrylonitrile
4.52
0.49
4.35
0.08
7.85
0.10
1,1-Dichloroethene
ND
0.49
ND
0.08
ND
0.10
Methylene Chloride
ND
0.49
ND
0.08
8.51
0.10
3-Chloro-1 -propene (Allyl Chloride)
ND
0.45
ND
0.08
ND
0.09
Trichlorotrifluoroethane
ND
0.49
ND
0.08
ND
0.10
Carbon Disulfide
ND
0.45
31.54
0.08
ND
0.09
trans-1,2-Dichloroethene
ND
0.56
0.19
0.09
ND
0.11
1,1-Dichloroethane
ND
0.45
ND
0.08
ND
0.09
Methyl tert-Butyl Ether
ND
0.49
ND
0.08
ND
0.10
Vinyl Acetate
83.50
1.91
72.51
0.33
148.34
0.38
2-Butanone (MEK)
18.55
0.63
20.05
0.11
31.11
0.12
cis-1,2-Dichloroethene
ND
0.45
ND
0.08
ND
0.09
Ethyl Acetate
ND
1.01
ND
0.17
ND
0.21
n-Hexane
8.10
0.45
8.80
0.08
13.65
0.09
Chloroform
ND
0.49
ND
0.08
ND
0.10
Tetrahydrofuran (THF)
2.09
0.59
2.18
0.10
3.18
0.12
1,2-Dichloroethane
ND
0.45
ND
0.08
ND
0.09
1,1,1-Trichloroethane
ND
0.49
ND
0.08
ND
0.10
Benzene
135.57
0.45
188.41
0.80
309.62
0.92
Carbon Tetrachloride
ND
0.45
0.02
0.08
0.03
0.09
Cyclohexane
ND
0.84
0.30
0.15
ND
0.17
44-B

-------
1,2-Dichloropropane
ND
0.45
0.22
0.08
ND
0.09
Bromodichloromethane
ND
0.45
ND
0.08
ND
0.09
Trichloroethene
ND
0.42
ND
0.07
ND
0.08
1,4-Dioxane
ND
0.45
0.11
0.08
ND
0.09
Methyl Methacrylate
ND
0.90
ND
0.16
ND
0.18
n-Heptane
8.00
0.49
9.43
0.08
13.96
0.10
cis-1,3-Dichloropropene
ND
0.42
ND
0.07
ND
0.08
4-Methyl-2-pentanone
0.63
0.45
0.65
0.08
1.09
0.09
trans-1,3-Dichloropropene
ND
0.45
ND
0.08
ND
0.09
1,1,2-Trichloroethane
ND
0.45
ND
0.08
0.09
0.09
Toluene
45.09
0.49
39.73
0.08
104.53
1.00
2-Hexanone
4.18
0.45
4.35
0.08
6.11
0.09
Dibromochloromethane
ND
0.45
ND
0.08
ND
0.09
1,2-Dibromoethane
ND
0.45
ND
0.08
ND
0.09
n-Butyl Acetate
ND
0.45
0.15
0.08
ND
0.09
n-Octane
6.26
0.52
6.89
0.09
10.03
0.10
Tetrachloroethene
ND
0.42
ND
0.07
ND
0.08
Chlorobenzene
ND
0.45
0.21
0.08
0.20
0.09
Ethyl benzene
10.09
0.45
9.06
0.08
30.10
0.09
m-,p-Xylenes
4.87
0.87
5.08
0.15
6.11
0.17
Bromoform
ND
0.45
ND
0.08
ND
0.09
Styrene
100.90
0.45
90.64
0.76
427.57
0.87
o-Xylene
2.57
0.45
2.36
0.08
3.05
0.09
n-Nonane
4.87
0.45
5.44
0.08
8.29
0.09
1,1,2,2-Tetrachloroethane
ND
0.45
ND
0.08
ND
0.09
Cumene
0.59
0.45
0.51
0.08
1.75
0.09
alpha-Pinene
1.15
0.42
0.54
0.07
ND
0.08
n-Propylbenzene
1.18
0.45
0.94
0.08
1.53
0.09
4-Ethyltoluene
0.59
0.45
0.54
0.08
0.74
0.09
1,3,5-Trimethyl benzene
ND
0.45
0.40
0.08
0.43
0.09
1,2,4-Trimethyl benzene
0.77
0.45
0.73
0.08
0.87
0.09
Benzyl Chloride
ND
0.32
0.14
0.05
0.24
0.07
1,3-Dichlorobenzene
ND
0.45
ND
0.08
ND
0.09
1,4-Dichlorobenzene
ND
0.42
ND
0.07
ND
0.08
1,2-Dichlorobenzene
ND
0.45
ND
0.08
ND
0.09
d-Limonene
ND
0.42
0.94
0.07
1.09
0.08
1,2-Dibromo-3-chloropropane
ND
0.29
ND
0.05
ND
0.06
1,2,4-Trichlorobenzene
ND
0.45
ND
0.08
ND
0.09
Naphthalene
32.36
0.52
30.09
0.09
43.63
0.10
Hexachlorobutadiene
ND
0.42
ND
0.07
ND
0.08

g/kg biomass

g/kg biomass

g/kg biomass

Carbon Monoxide
18.77

19.97

24.53

45-B

-------
Methane
0.66
0.62
0.77
Carbon Dioxide
1512.10
1510.32
1502.73
MCE ratio
0.980
0.979
0.974
46-B

-------
1035 Table B-24. VOC emission factor from open burning of baseline (CB/CL).
Compound
CB/CL - baseline
1
Method
Detection
EF Limit
mq/kq fiberboard
Propene
16.70
0.06
Dichlorodifluoromethane (CFC-12)
ND
0.08
Chloromethane
1.45
0.07
1,2-Dichloro-1,1,2,2-


tetrafluoroethane (CFC-114)
ND
0.09
Vinyl Chloride
ND
0.08
1,3-Butadiene
5.77
0.10
Bromomethane
ND
0.09
Chloroethane
ND
0.08
Ethanol
0.38
0.36
Acetonitrile
0.56
0.08
Acrolein
13.51
0.08
Acetone
8.34
0.35
Trichlorofluoromethane
ND
0.08
2-Propanol (Isopropyl Alcohol)
ND
0.18
Acrylonitrile
0.24
0.08
1,1-Dichloroethene
ND
0.08
Methylene Chloride
0.14
0.08
3-Chloro-1 -propene (Allyl Chloride)
ND
0.07
Trichlorotrifluoroethane
ND
0.08
Carbon Disulfide
1.21
0.07
trans-1,2-Dichloroethene
ND
0.09
1,1-Dichloroethane
ND
0.07
Methyl tert-Butyl Ether
ND
0.08
Vinyl Acetate
22.77
0.29
2-Butanone (MEK)
2.87
0.09
cis-1,2-Dichloroethene
ND
0.07
Ethyl Acetate
0.09
0.15
n-Hexane
0.07
0.07
Chloroform
ND
0.08
Tetrahydrofuran (THF)
0.10
0.09
1,2-Dichloroethane
1,1,1-Trichloroethane
Benzene
Carbon Tetrachloride
Cyclohexane
1,2-Dichloropropane
ND
ND
33.35
0.01
ND
ND
0.07
0.08
0.07
0.07
0.13
0.07
47-B

-------
Bromodichloromethane
ND
0.07
Trichloroethene
ND
0.06
1,4-Dioxane
ND
0.07
Methyl Methacrylate
ND
0.14
n-Heptane
ND
0.08
cis-1,3-Dichloropropene
ND
0.06
4-Methyl-2-pentanone
ND
0.07
trans-1,3-Dichloropropene
ND
0.07
1,1,2-Trichloroethane
ND
0.07
Toluene
7.21
0.08
2-Hexanone
0.08
0.07
Dibromochloromethane
ND
0.07
1,2-Dibromoethane
ND
0.07
n-Butyl Acetate
ND
0.07
n-Octane
ND
0.08
Tetrachloroethene
ND
0.06
Chlorobenzene
ND
0.07
Ethyl benzene
1.02
0.07
m-,p-Xylenes
0.88
0.13
Bromoform
ND
0.07
Styrene
3.49
0.07
o-Xylene
0.36
0.07
n-Nonane
ND
0.07
1,1,2,2-Tetrachloroethane
ND
0.07
Cumene
ND
0.07
alpha-Pinene
0.08
0.06
n-Propylbenzene
ND
0.07
4-Ethyltoluene
0.09
0.07
1,3,5-Trimethyl benzene
ND
0.07
1,2,4-Trimethyl benzene
0.12
0.07
Benzyl Chloride
ND
0.05
1,3-Dichlorobenzene
ND
0.07
1,4-Dichlorobenzene
ND
0.06
1,2-Dichlorobenzene
ND
0.07
d-Limonene
0.10
0.06
1,2-Dibromo-3-chloropropane
ND
0.04
1,2,4-Trichlorobenzene
ND
0.07
Naphthalene
11.39
0.08
Hexachlorobutadiene
ND
0.06

g/kg fiber board

Carbon Monoxide
14.29

Methane
0.13

48-B

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Carbon Dioxide
1672.84
MCE ratio
0.987
49-B

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SEPA
United States
Environmental Protection
Agency
Office of Research and Development (8101R)
Washington, DC 20460
Official Business
Penalty for Private Use
$300
Printed on 100% recycled/recyclable paper
a	with a minimum 50% post-consumer
fiber using vegetable-based ink.
PRESORTED STANDARD
POSTAGE & FEES PAID
EPA
PERMIT NO. G-35

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