EPA 600/R-16/220 | November 2016 | www.epa. United States Environmental Protection Agency SEPA Characterization of Emissions from Open Burning of Meals Ready-to-Eat and their Paperboard Packaging Office of Research and Development ------- Characterization of Emissions from Open Burning of Meals Ready-to-Eat and their Paperboard Packaging Johanna Aurell1, Brian Gullett2* University of Dayton Research Institute 2U.S. Environmental Protection Agency, Office of Research and Development August 17, 2016 ------- Acknowledgments The authors appreciate the technical sampling assistance provided by Captain Thomas Dominguez, USAF, Air Force Institute of Technology, and his advisor, Lt. Col. Dirk Yamamoto. Paul Freeman, currently at Calvin College, Grand Rapids Ml, provided critical volunteer assistance during the burns. Technical support was provided by Steve Terll, ARCADIS U.S., Inc. Analyses were significantly aided by the contribution of Dennis Tabor, US EPA. Disclaimer The views expressed in this report are those of the authors and do not necessarily represent the views or policies of the U.S. Environmental Protection Agency. i ------- Executive Summary Emissions from burning current and candidate Meals Ready-to-Eat (MRE) packaging and shipping containers were characterized in an effort to assuage concerns that combustive disposal of waste at forward operating bases could pose an environmental or inhalation threat. Four types of container 5 materials, both box and liners, including the currently used fiberboard, new corrugated fiberboard with Spectra-kote polymer, new fiberboard without Spectra-kote polymer, and the current fiberboard without wet strength were burned in an open burn test facility that simulated the burn pit disposal methods in Iraq and Afghanistan. MREs, including both current and proposed packaging materials, were added to a single container type to examine their effect on emissions. One quarter of the food was left 10 in the packaging to represent unused meal components. The proposed packaging, consisting of a nano- composite polymer, was added in 25 % increments compared to traditional MRE packaging to create a range of usage levels. Emission factors, mass of pollutant per mass of burned material, were increased over the emission factors of the package containers themselves by the addition of the multi-component MREs, with the exception of Volatile Organic Compounds (VOCs). In general, little distinction was 15 observed when comparing emission factors from the four container materials and when comparing the four MRE compositions. The majority of Particulate Matter (PM) emissions were of particles that were below 1.0 pirn in aerodynamic diameter for the fiberboard tests; PM2.sand PMio emissions increased five-sixfold when MREs were added to fiberboard packaging. Emission factors, particularly VOCs, were negatively correlated to modified combustion efficiency. As combustion quality improved, VOCs and, 20 less notably, polychlorinated dibenzodioxins/polychlorinated dibenzofurans (PCDDs/PCDFs) declined. ------- .. 1 .. 1 .. 1 .. 2 .. 2 .. 2 .. 2 .. 5 .. 6 .. 7 .. 8 10 10 11 11 12 12 13 13 13 14 15 16 16 16 18 19 20 20 22 I Table of Contents 1. Introduction 1.1 Background 1.2 Objectives 2 Materials and Methods 2.1 Test Materials 2.1.1 Fiberboard 2.1.2 Meal Ready-to-Eat 2.2 Open Burn Test Facility 2.3 Test Procedure 2.3.1 Test Matrix 2.3.2 E mission Sampling System 2.4 Emission Sampling and Analytical Methods 2.4.1 SVOCs 2.4.2 VOCs 2.4.3 PM 2.4.4 C02 2.4.5 CO 2.5 Calculations 2.5.1 Emission factors 2.5.2 PCDD/PCDF Toxic Equivalent Calculations 2.5.3 Modified Combustion Efficiency 2.6 Data Precision 3 Results and Discussion 3.1 PM 3.1.1 Fiberboard packaging 3.1.2 MRE pouches 3.2 Metals and Other Trace Elements 3.3 VOCs 3.3.1 Fiberboard packaging 3.3.2 MRE pouches ------- 3.4 PAHs 23 3.4.1 Paperboard packaging 23 3.4.2 MRE pouches 25 55 3.5 PCDD/PCDF 27 3.5.1 Fiberboard packaging 27 3.5.2 MRE pouches 30 4 Quality of Data and Data Limitations 32 5 Conclusions 33 60 6 References 34 II ------- List of Figures Figure 2-1. A) MRE menu "Spicy penne pasta vegetarian" was used as the base for each waste 65 category burned. Heater not used due to safety concerns (release of H2 gas). B) New nanocomposite packaging 3 Figure 2-2. Schematic of open burn test facility. Not to scale 6 Figure 2-3. The paperboard test material (corrugated Spectra-kote Polymer Fiberboard box and liner) atop aluminum foil (left) on 1 m x 1 m (3.2 ft x 3.2 ft) steel pan. Combustion of same (right).. 6 70 Figure 2-4. MRE (100 % OLD material or 0 % NEW) on 3.2 x 3.2 foot steel pan, before (left) and after (right) burn 7 Figure 2-5. Flyer sampling instruments 9 Figure 2-6. Monitoring of CEMs, SVOC flow rate, temperature, and SUMMA canister pressure during a burn 9 75 Figure 3-1. Typical traces of PM, CO, and CO2 throughout each of the fiberboard type burnburns...,16 Figure 3-2. PM2.5 and PM10 emission factors and modified combustion efficiency (MCE) for each replicate 17 Figure 3-3. PM2.5 and PM10 emission factors from open burning of fiberboard. Error bars represent 1 STDV 17 80 Figure 3-4. PM emission factors from open burning of MREs. Error bars represent 1 STDV 18 Figure 3-5. PM2.5 and PM10 emission factors and modified combustion efficiency (MCE) for each replicate 19 Figure 3-6. Major metal and trace /element emission factors from open burning ofMRE's 19 Figure 3-7. Select VOCs and their emission factors for the different fiberboard types. * = on EPA's 85 list of hazardous air pollutants 20 Figure 3-8. Select VOCs versus modified combustion efficiency (MCE) 21 Figure 3-9. VOC emission factors from open burning of MREs. * = on EPA's list of Hazardous Air Pollutants (HAPs) 22 Figure 3-10. Select VOC emission factors versus modified combustion efficiency (MCE) 23 90 Figure 3-11. Benzene and acrolein vs. MCE for all MRE waste compositions and fiberboard types burns 23 Figure 3-12. PAH emission factors from open burning of fiberboard packaging. Error bars represent 1 standard deviation 24 Figure 3-13. PAH emission factors from open burning of MREs. Error bars represent 1 standard 95 deviation 26 Figure 3-14. PCDD/PCDF emission factors from open burning of fiberboard packaging. Error bars represent 1 standard deviation 28 III ------- Figure 3-15. Fiberboard PCDD/PCDF emission factors versus modified combustion efficiency (MCE) 29 100 Figure 3-16. PCDD/PCDF emission factors from open burning of MREs. Error bars represent 1 standard deviation 30 Figure 3-17. MRE PCDD/PCDF emission factors versus modified combustion efficiency (MCE) 32 IV ------- 105 List of Tables Table 2-1. Ultimate proximate analysis for the seven fiberboard materials 2 Table 2-2. Weight percentage of material in each waste category.3 4 Table 2-3. Carbon fraction of each waste material and category.3 5 Table 2-4. Fiberboard test matrix.ฎ 7 110 Table 2-5. MRE test matrix.a 8 Table 2-6. Collected samples for each test category 8 Table 2-7. Flyer emission sampling 9 Table 2-8. PCDD/PCDF Toxic Equivalency Factors for mammals/humans [12] 14 Table 2-9. PAH Toxic Equivalency Factors for humans [17] 14 115 Table 3-1. PM emission factors 18 Table 3-2. Major metal and trace /element emissions from open burning of MRE pouches.3 20 Table 3-3. VOC emission factors 21 Table 3-4. VOC emission factors from open burning of MREs 22 Table 3-5. PAH emission factors from open burning of fiberboard in mg/kg fiberboard 24 120 Table 3-6. PAH TEQ emission factors from open burning of fiberboard in mg B[a]P TEQ/kg fiberboard.ฎ 25 Table 3-7. PAH emission factors from open burning of MRE pouches in mg/kg MRE 26 Table 3-8. PAH TEQ emission factors from open burning of MRE pouches in mg B[a]P TEQ/kg MRE.a 27 125 Table 3-9. PCDD/PCDF TEQ emission factors 28 Table 3-10. PCDD/PCDF Total emission factors 29 Table 3-11. PCDD/PCDF TEQ emission factors 31 Table 3-12. PCDD/PCDF Total emission factors 31 130 V ------- List of Appendices Appendix A: Data for each sample collected from Open Burning of Fiberboard. Appendix B: Data for each sample collected from OB of MRE pouches. 135 VI ------- List of Acronyms AN OVA Analysis of variance BTU British thermal unit CB Current fiberboard box CEM Continuous emission monitor CH4 Methane CL Current fiberboard liner CO Carbon monoxide CO2 Carbon dioxide DoD U.S. Department of Defense EPA U. S. Environmental Protection Agency ESTCP Environmental Security Technology Certification Program FID Flame ionization detector GC Gas chromatography HRGC High Resolution Gas Chromatography HRMS High Resolution Mass Spectrometry IARC International Agency for Research on Cancer IR Infrared LOD Limit of Detection MCE Modified combustion efficiency MLS Montmorillonite-layered silicates MRE Meal, Ready-to-Eat ND Not detected NDIR Non-dispersive infrared NSB No Spectra-kote box NSL No Spectra-kote liner NSRDEC Natick Soldier Research, Development and Engineering Center NWS Current fiberboard box - no wet strength OBTF Open Burning Testing Facility PAHs Polycyclic aromatic hydrocarbons PCDDs Polychlorinated dibenzo-p-dioxin PCDFs Polychlorinated dibenzofurans PCF photometric calibration factor PM Particulate matter PMi Particulate matter of 1 micrometers or less PM10 Particulate matter of 10 micrometers or less PM2.5 Particulate matter of 2.5 micrometers or less PM4 Particulate matter of 4 micrometers or less PUF Polyurethane foam RPD Relative percent difference VII ------- RSD Relative standard deviation SB Corrugated Spectra-kote polymer fiberboard box SL Corrugated Spectra-kote polymer fiberboard liner STDV Standard deviation SVOC Semivolatile organic compounds TEF Toxic equivalency factors TEQ Toxic equivalency VOC Volatile organic compound WHO World Health Organization XAD-2 Brand name of sorbent polymeric resin (crosslinked polystyrene copolymer) VIII ------- 140 1. Introduction 1.1 Background Approximately 4000 tons of MRE (Meal, Ready-to-Eat) solid fiberboard packaging waste is generated every year [1], This amount of waste, coupled with rising disposal costs and hazards encountered with open pit burning in contingency base operations, has dramatically increased the need to investigate 145 alternative materials and designs for combat ration fiberboard packaging applications. This project is a follow-up of a study sponsored by the U.S. Department of Defense (DoD), performed by the Natick Soldier Research, Development and Engineering Center (NSRDEC) to research and develop novel lightweight fiberboard structures to replace the existing military fiberboard containers, with the ultimate goal to reduce the amount of solid waste for the military. This demonstration/validation 150 project, "Lightweight and Compostable Packaging for the Military", is sponsored through a U.S. Army- operated Environmental Security Technology Certification Program (ESTCP), funded by DoD for examining the replacement of solid fiberboard with coated corrugated containers for MRE rations. Each fiberboard box and liner contains 12 MREs. Additional research by NSRDEC is ongoing for the potential replacement of MRE aluminum-based pouches with pouches that are multi-layer, nanocomposite-based 155 polymer materials that can potentially provide greater barrier and mechanical properties [2], The combined effect of these packaging and MRE material changes has uncertain effects on emissions from combustion disposal. 1.2 Objectives The objectives of this work were to determine and compare air emissions from open burning of: 160 Current and newly-developed MRE fiberboard packaging options; and Current MRE aluminum-based pouches and newly-developed nanocomposite-based pouches. Emissions that were characterized included health-related compounds: PM2.sand PMio (particulate matter with aerodynamic diameter equal to and less than 2.5 pim in diameter and particulate matter with aerodynamic diameter equal to and less than 10 pim in diameter), elements/metals in PM, 165 polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDDs/PCDFs), polycyclic aromatic hydrocarbons (PAHs), carbon monoxide (CO), carbon dioxide (C02), and volatile organic compounds (VOCs). PM2.5 is a criteria pollutant regulated by the U.S. EPA since these particles can enter the lungs when inhaled and potentially carry metals and other toxic pollutants, which can cause adverse health effects. PCDDs/PCDFs are persistent in the environment and are of interest due to their health 170 effects including immunotoxicity, carcinogenicity, and teratogenicity. Many VOCs are on the U.S. EPA's list of hazardous air pollutants with properties that are toxic and carcinogenic for humans. Some PAHs are classified as possible human carcinogens. 1 ------- 175 2 Materials and Methods 2.1 Test Materials 2.1.1 Fiberboard Seven fiberboard materials were studied for their emissions when combusted in an open burn scenario: Current solid fiberboard box (CB); 180 Current solid fiberboard liner (CL); New corrugated fiberboard box with Spectra-kote polymer (SB) (Spectra-kote Corp., Gettysburg, PA, USA); New corrugated fiberboard liner with Spectra-kote polymer (SL); New fiberboard box with no Spectra-kote polymer (NSB); 185 New fiberboard liner with no Spectra-kote polymer (NSL); and Current solid fiberboard box without wet strength (NWS) polymer. Analyses of these materials (Galbraith Laboratories, Inc., Knoxville, TN, USA) are reported in Table 2-1. Differences in the Spectra-kote boxes/liners are noted, particularly for loss on drying, chlorine, and sulfur. 190 Table 2-1. Ultimate proximate analysis for the seven fiberboard materials. Current Current Fiberboard Fiberboard Solid Box Liner Corrugated Corrugated Spectra- Spectra- kote kote Polymer Polymer Fiberboard Fiberboard No Spectra- Box Liner kote Box No Spectra- kote Liner Current Fiberboard Box - No Wet Strength Code CB CL SB SL NSB NSL NWS Heat of combustion (BTU*/lb)1 Loss on drying (%)2 Carbon (%)3 Chlorine (ppm)4 Hydrogen (%)5 Nitrogen (%)6 Sulfur (%)7 8121 7.45 46.3 188 6.08 <0.5 0.234 7955 7.49 46.19 185 6.16 <0.5 0.243 7537 9.45 44.99 297 6.13 <0.5 0.162 7166 9.13 45.44 251 6.02 <0.5 0.155 7598 9.48 45.36 97 6.29 <0.5 0.149 7979 8.51 45.85 57 6.20 <0.5 0.140 8145 10.24 46.56 139 6.03 <0.5 0.236 * British thermal unit(s). Galbraith procedures: 1S-231; 2S-200; 3ME-14; 4ME-4A; 5ME-14; 6ME-14; 7E16-2. 2.1.2 Meal Ready-to-Eat 195 MRE packaging consists of a new nanocomposite material and old aluminum-based material. Research conducted by NSRDEC is developing a new potential replacement for the aluminum-based pouches. The new packaging consists of a multi-layer, nanocomposite-based polymer material that can potentially provide greater barrier and mechanical properties [2], The novel materials disperse modified montmorillonite-layered silicates (MLSs) into thermoplastic in a layered molecular structure that 2 ------- 200 increases the path length of diffusing gases (i.e., oxygen and moisture) and improves the shelf life of the MRE contents. MRE menu number 14, Spicy penne pasta vegetarian, was used as the base food for the testing and number of packages and sizes to assure a good reproducibility. Four different MRE packaging categories were studied, comprising different percentages of new nanocomposite and old aluminum-based 205 material: 0 % NEW (only old material), 32 % NEW (32 % new material and 68 % old material), 66 % NEW (66 % new material and 34 % old material), and 100 % NEW (only new material) (Table 2-2). The total carbon fraction of each waste material in the four waste categories was calculated using carbon fractions from Liu and Liptak [3], as well as sugar (0.42) and carbohydrates (0.44, as starch) (Table 2-3) For all MRE tests, the current fiberboard packing was used as a substrate (CB/CL, Table 2-1). 210 A NEW OLD NEW material Heater Figure 2-1. A) MRE menu "Spicy penne pasta vegetarian" was used as the base for each waste category burned. Heater not used due to safety concerns (release of H2 gas). B) New nanocomposite packaging. 215 3 ------- Table 2-2. Weight percentage of material in each waste category.3 Waste Material 0% NEW 32% NEW 66% NEW % 100% NEW Old Al-based material 11 5.7 3.6 NA New nanocomposite Material NA 3.6 7.0 11 Plastic 17 18 16 17 Cardboard 29 30 28 29 Paper 1.6 1.6 1.5 1.6 Al-bag 1.7 1.7 6.6 1.7 Matches 1.0 1.0 0.92 1.0 Adsorbent package 0.47 0.48 0.45 0.47 Food waste: Penne pasta 16 17 16 16 Beef stick 2.8 2.8 2.6 2.8 Toaster pastry 4.1 4.2 3.9 4.1 Crackers 2.8 2.8 2.6 2.8 Pretzels 2.6 2.7 2.5 2.7 Cappuccino powder 2.1 2.1 2.0 2.1 Salt 0.65 0.66 0.62 0.65 Seasoning 0.26 0.27 0.25 0.27 Iced tea powder 5.0 5.1 4.8 5.0 Chewing gum 0.82 0.84 0.78 0.83 a Each waste category comprised of different percentages of new nanocomposite and old aluminum-based material, e.g., 32 % NEW = 32 % new nanocomposite material and 68 % old Al-based material of the total waste. 220 ------- Table 2-3. Carbon fraction of each waste material and category.3 Waste Material Carbon Fraction in Material 0 % 32 % 66 % 100 % NEW NEW NEW NEW Carbon fraction from each waste category13 Old materia 0.37 4.2E-02 2.1E-02 1.3E-02 NA New Material 0.74 NA 2.7E-02 5.2E-02 8.2E-02 Plastic 0.74c 1.3E-01 1.3E-01 1.2E-01 1.3E-01 Cardboard 0.46 1.4E-01 1.4E-01 1.3E-01 1.4E-01 Paper 0.44c 7.0E-03 7.1E-03 6.6E-03 7.0E-03 Al-bag 0.0076c 1.3E-04 1.3E-04 5.0E-04 1.3E-04 Matches 0.50 4.9E-03 5.0E-03 4.7E-03 4.9E-03 Adsorbent package 0.0076c 3.6E-05 3.7E-05 3.4E-05 3.6E-05 Food waste: Penne pasta 0.092 1.5E-02 1.5E-02 1.4E-02 1.5E-02 Beef stick 0.28 7.7E-03 7.8E-03 7.3E-03 7.7E-03 Toaster pastry 0.43 1.8E-02 1.8E-02 1.7E-02 1.8E-02 Crackers 0.51 1.4E-02 1.4E-02 1.3E-02 1.4E-02 Pretzels 0.39 1.0E-02 1.1E-02 9.9E-03 1.0E-02 Cappuccino 0.45 9.4E-03 9.6E-03 8.9E-03 9.4E-03 Salt 0.0076 4.9E-05 5.0E-05 4.7E-05 4.9E-05 Seasoning 0.49 1.3E-03 1.3E-03 1.2E-03 1.3E-03 Iced tea 0.49 2.4E-02 2.5E-02 2.3E-02 2.4E-02 Chewing gum 0.49 4.0E-03 4.1E-03 3.8E-03 4.0E-03 Total NA 0.42 0.44 0.43 0.46 a Each waste category comprised of different percentages of new nanocomposite and old aluminum-based material, e.g., 32 % NEW = 32 % new nanocomposite material and 68 % old Al-based material of the total waste.b Data from Liu and Liptak [3],c Carbon fraction in material x waste fraction in recipe. 225 2.2 Open Burn Test Facility This work was conducted in the U.S. EPA's Open Burning Testing Facility (OBTF) located at EPA's Research Triangle Park, NC, campus (Figure 2-2). The open burn test facility consists of a 12.8 x 12.8 x 15 230 feet (3.9 x 3.9 x 4.6 m) structure constructed with sheetrock wallboard that is covered with stainless steel for ease of cleaning. High volume air handlers provide dilution air into the test facility to help ensure that open burn conditions (minimal depletion of oxygen concentration) are maintained within the facility during the tests. Measurements of the emissions exiting from the enclosed facility, together with the dilution rate of incoming combustion air, allow for calculation of emission factors in terms of 235 pollutant mass per mass of material burned. The facility flowrate results in approximately one air volume change every 90 sec. The dilution air and combustion emissions exit the test facility through an 8-inch diameter (20.3 cm) transfer duct. 5 ------- Air outlet PAH Flyer 1 Flyer 2 sampler Air inlet Paperboard CO CEM Figure 2-2. Schematic of open burn test facility. Not to scale. 2.3 Test Procedure The fiberboard/MRE sample was placed randomly on aluminum foil atop a sand-filled 3.2 x 3.2 foot (1 m x 1 m) steel plate (Figure 2-3, Figure 2-4). The average fiberboard weight for each burn was 4.7 lb (2.1 245 kg), 5.6 lb (2.6 kg), 5.5 lb (2.5 kg) and 5.7 lb (2.6 kg) for CB/CL, SB/SL, NSB/NSL and NWS, respectively. Six MRE bags and half of a CB/CL fiberboard box was used for each MRE burn (based on 12 MRE bags in one fiberboard box); only 25 % of the food was included, simulating food not eaten. Each burn was started with the use of a propane torch. Semivolatile organic compounds (SVOCs) and particulate matter (PM) collection started at ignition while Volatile Organic Compound (VOC) (SUMMA 250 canister) sampling was started with a trigger when the C02 concentration had reached 800 ppm (this delay avoided the SUMMA canister opening prematurely during the ignition while the operator was still within the OBTF). VOC sampling was stopped when the C02 concentration diminished to 800 ppm. The SVOC and PM collection were stopped when the C02 concentration had reached the background concentration of approximately 400-500 ppm C02. 255 Figure 2-3. The paperboard test material (corrugated Spectra-kote Polymer Fiberboard box and liner) atop aluminum foil (left) onlmxlm (3.2 ft x 3.2 ft) steel pan. Combustion of same (right). 6 ------- 260 Figure 2-4. MRE (100 % OLD material or 0 % NEW] on 3.2 x 3.2 foot steel pan, before (left) and after (right) burn. 2.3,1 Test Matrix The fiberboard tests and the MRE tests were conducted at separate times, November 2014 and July 265 2015, respectively. The tests were performed in random order (Table 2-4 and Table 2-5).To receive detectable levels of PCDD/PCDF, two to six separate burns had to be composited into one sample (one test). Table 2-6 shows the number of collected samples for each fiberboard and MRE category. A background sample was collected for each of the two test periods. 270 Table 2-4. Fiberboard test matrix.3 Fiberboard Type Code Test order No. of Tests Ash Samples NA- OBTF Blank BS P re-Test 1 NA Current Fiberboard Container and CB/CL 3, 5, 7, 8 4 1 (composite) Current Fiberboard Liner New Polymer Coated Fiberboard Container and New Polymer Coated Fiberboard Liner SB/SL 6, 9, 10, 11 4 1 (composite) New Non-Polymer Fiberboard Container and New Non-Polymer Fiberboard Liner NSB/NSL 4, 14, 15, 16 4 1 (composite) Current Fiberboard, No Wet Strength NWS 1,2, 12, 13 4 1 NA - OBTF Blank BS Post-Test 1 NA a NA - not applicable. 7 ------- Table 2-5. MRE test matrix.3 Test Material Code Test order No. of Tests MRE Menu No. 11, 100 % New Material 100 % NEW 1,4, 9 3 MRE Menu No. 11, 66 % New Material 66 % NEW 11,12, 13 3 MRE Menu No. 11, 32 % New Material 32 % NEW 7, 8,10 3 MRE Menu No. 11,0% New Material 0 % NEW 2, 3, 5 3 (100 % Old material) (100 % OLD) Baseline: Current Fiberboard Container CB/CL 6 1 and Current Fiberboard Liner NA - OBTF Blank BS Post-Test 1 a NA - not applicable. Table 2-6. Collected samples for each test category. VOCs Test Category SUMMA Canisters PM2.5 PM10 PAH PCDD/PCDF CB/CL 5 10 10 5 5 SB/SL 4 7 7 4 4 NSB/NSL 4 8 8 4 4 NWS 4 10 10 3 4 100% NEW 3 6 6 3 3 66 % NEW 2 6 6 3 3 32 % NEW 3 6 6 3 3 0% NEW (100% OLD) 3 6 6 3 3 Background 2 2 2 2 3 Total 30 61 61 30 32 2.3.2 Emission Sampling System Emission sampling was conducted using the "Flyer", which is a remotely controlled sampling system 280 (Figure 2-5) described more fully elsewhere [4; 5], The Flyer includes an on-board computer, control software, and wireless transmitters which allow sampling to be monitored and controlled from a distance. Sampling periods are controlled using "triggers" and software to operate multiple on/off valves. Interchangeable sampling instruments allow for continuous C02, CO, temperature, and PM measurements as well as batch sampling of VOCs, SVOCs, PMio and PM2.5. The on-board computer and 285 wireless data transfer also allow the operator to monitor C02 concentration, battery life, and pressure drop across a filter in real time. All sensor data and flow rates are logged to the on-board computer. A smaller version of the flyer was used to sample PAHs. To quantify the designated target analytes, the Flyer was comprised of the instruments indicated in Figure 2-6 shows monitoring of the Flyer samplers. 8 ------- Dioxins Dioxins 290 Figure 2-5. Flyer sampling instruments. Table 2-7. Flyer emission sampling. Pollutant lnstrument/Method(s) Duration Analytical Laboratory PIVhsand PM10 SKC impactors, 47 mm Teflon filters, PM by mass Batch Chester LabNet PCDD/PCDF, PAH Modified U.S. EPA Method TO-9A [6], U.S. EPA Method 23 [7J/HRGC-HRMS, U.S. EPA Method 8270D [8J/HRGC- LRMS Batch EPA/ORD VOCs SUMMA Canister/U.S. EPA Method TO- 15 [9], including CO2, CO, CH4/U.S. EPA Method 25C [10] Integrated run, 12 min samples ALS Simi Valley Metals Teflon filters/gravimetric and X-ray fluorescence (XRF) [11] Batch Chester LabNet PM mass arid size DustTrak DRX (PM1, PM25, PM4, PM10 and Total PM) Continuous EPA/ORD C02 LI-COR 820, Non-dispersive Infrared (NDIR) Continuous EPA/ORD CO Electrochemical cell, e2V EC4-500-CO Continuous EPA/ORD 1066756?'--'- 14.9-5- 17.4 "w- n Figure 2-6. Monitoring of CEMs, SVOC flow rate, temperature, and SUMMA canister pressure during a burn. 9 ------- 2.4 Emission Sampling and Analytical Methods 2.4.1 SVOCs 300 PCDDs/PCDFs and PAHs were sampled using a low voltage Windjammer and MINIjammer brushless direct current blower (AMETEK Inc., Berwyn, PA, USA), respectively. The blowers were started via wireless control at the start of the burn. The flow rate was measured by a 0-622 Pa pressure differential transducer (Setra, Model 265, Boxborough, MA, USA) across Herschel Standard Venturi tubes. The Venturi tubes were designed at EPA to meet the desired sampling rate for the target compound. The 305 Venturi tubes were mounted on the outlet of the Windjammer and MINIjammer blowers. The voltage equivalent to this pressure differential was recorded on the onboard PC using the FlyerDAQ program or ARDUINO-based computer, which was calibrated with a Roots meter (Model 5M, Dresser Measurement, Addison, TX, USA) in the U.S. EPA Metrology Laboratory before sampling effort. A temperature thermistor was used to measure the air temperature exiting the Venturi. 310 PCDD/PCDFPCDDs/PCDFs were sampled via modified U.S. EPA Method TO-9A [6] using a polyurethane foam (PUF) sorbent preceded by a quartz microfibermicrofiber filter (20.3 x 25.4 cm) with a nominal sampling rate of 0.85 m3/min (Windjammer). PAHs were also sampled via modified U.S. EPA Method TO- 9A [6] using a PUF/XAD-2 (polymer resin, Supelco Inc., Bellefonte, PA, USA)/PUF sorbent behind a quartz microfibermicrofiber filter (70 mm in diameter) with a nominal sampling rate of 0.18 m3/min 315 (MINIjammer). The PUF (Tisch Scientific, North Bend, OH, USA) was cleaned before use by solvent extraction with dichloromethane and dried with flowing helium to minimize contamination of the media with the target analytes and remove unreacted monomer from the sorbent. The PUF and PUF/XAD/PUF sorbents were mounted in a glass cartridges (Tisch Scientific) and inserted in a cartridge holder mounted on the Windjammer and MINIjammer blowers. The samples was extracted and cleaned up according to 320 U.S. EPA Method 23 [7] and analyzed using high resolution gas chromatography/high resolution mass spectrometry (HRGC/HRMS). Blanks were collected and analyzed. 2.4.1.1 PCDD/PCDF Analysis of tetra- through octa-CDDs/CDFs was performed according to modified U.S. EPA Method 23 [7], Identification and quantification of the PCDD/PCDF congeners made use of a mixture of standards 325 (Cambridge Isotope Laboratories, Tewksbury, MA, USA) containing tetra-to octa-CDD/CDF native and 13C-labeled congeners as per modified U.S. EPA Method 23 [7], The PCDD/PCDF calibration solutions were prepared in house and contained native PCDD/PCDF congeners at concentration from 0.25 to 40 ng/mL. The 2005 World Health Organization (WHO) 2005 toxic equivalency factors (TEFs) [12] were used to 330 determine the PCDD/PCDF toxic equivalency (TEQ) emission factors (see Chapter 2.5 for calculations). Not all TEF-weighted PCDD/PCDF congeners were detected in all samples. The congeners that were not detected (ND) were set to zero in the text although Appendix A and B show the PCDD/PCDF values both at ND = 0 and ND = limit of detection (LOD)). All surrogate standard recoveries were between 63 % and 110 % for the fiberboard burn samples, which was within the standard method criteria (25-130 %). Some 335 of the surrogate standard recoveries were outside the standard method criteria (25-130 %) for the MRE 10 ------- burn samples due to interference from significant amounts of other compounds in the 13C channels causing a low response for the compound pre-analysis. 2.4.1.2 PAHs Internal standards (Cambridge Isotope Laboratories, Tewksbury, MA, USA) were added to the sorbent 340 before the sample was collected. The surrogate recoveries were measured relative to the internal standards and are a measure of the PUF/XAD/PUF/filter collection efficiency. Adeuterated recovery standard, DIO-pyrene, was added before mass analysis. Samples were analyzed on a Thermo Tracel310/ISQ GC/MS (Thermo Electron North America LLC, West Palm Beach, FL, USA) utilizing full- scan mode. All surrogate standard recoveries were between 48 and 110 percent, which was within the 345 standard method criteria (25 and 130 %). 2.4.2 VOCs Volatile organic compounds were sampled via U.S. EPA Method TO-15 [9], Sampling for VOCs was accomplished using laboratory-supplied 6-L SUMMA canisters (ALS, Simi Valley, CA, USA). Each SUMMA canister was equipped with a manual valve, metal filter (frit), pressure gauge, pressure transducer, and 350 an electronic solenoid valve. Pre-sampling tests showed canister fill times of 12 min. The SUMMA valves were checked for leakage before sample collection by ensuring that the pressure gauge was not showing decreased vacuum with time. The SUMMA had its electronic solenoid valve controlled by the Flyer data acquisition (FlyerDAQ) program. The pressure transducer and electronic solenoid valve were connected to the Flyer, and the manual valve was opened. The electronic solenoid 355 valve sampling system was opened and closed based on C02 concentration set points using the FlyerDAQ program. When the LI-820 measures elevated levels of C02, the Flyer DAQ enables the solid state relay, opening the SUMMA's solenoid valve to start sampling at the chosen frit filter sampling rate. The pressure transducer provided information on the status of the SUMMA (i.e., empty, filling, or full) to the FlyerDAQ interface. Following the end of sampling, the manual valve was closed, the SUMMA 360 dismounted from the Flyer, the solenoid valve removed, and the canister was returned to its shipping container. SUMMA canisters were shipped to and from the field in boxes as per (ALS Environmental) instructions. The VOCs were analyzed by ALS Laboratories (Simi Valley, CA) using U.S. EPA Method TO-15 [9] using full scan mode gas chromatography-low resolution mass spectrometry (GC/LRMS). The SUMMA canisters 365 were also analyzed for C02, CO, and CH4 by a GC/ flame ionization detector (FID) according to modified U.S. EPA Method 25C [10] by ALS Laboratories (Simi Valley, CA). 2.4.3 PM 2.4.3.1 PM batch sampling PM2.5 and PM10 were sampled with SKC impactors using 47 mm tared Teflon filters with a pore size of 2.0 370 pirn via a Leland Legacy sample pump (SKC Inc., Pittsburgh, PA, USA) with a constant airflow of 10 L/min. PM was measured gravimetrically following the procedures described in 40 CFR Part 50 [13]. Particles larger than 10 pim in the PM10 impactor (or larger than 2.5 pim in the PM2.5 impactor) were collected on 11 ------- an oiled 37 mm impaction disc. The Leland Legacy Sample pump was calibrated with a Gilibrator Air Flow Calibration System (Sensidyne LP, St. Petersburg, PA, USA). 375 2.4.3.2 PM continuous sampling The TSI DustTrak DRX Model 8533 (TSI, Inc., Knoxville, TN, USA) was used to measure time-resolved particle size distributions. The DustTrak DRX measures light scattering by aerosols as they intercept a laser diode and has the capability of simultaneous real time measurement (every second) of PMi, PM2.5, Respirable (PM4), PM10 and Total PM (up to 15 pim). The aerosol concentration range for the DustTrak 380 DRX was 0.001-150 mg/m3 with a resolution of ฑ0.1% of the reading. The flow accuracy is ฑ5 % of internal flow as controlled. The DustTrak DRX was factory-calibrated yearly to the respirable fraction (PM4), with a photometric calibration factor (PCF) value of 1.00. A custom PCF was conducted as per manufacturer's recommendations for PM2.5 and PM10 using the simultaneously sampled PM2.5 and PM10 by filter impactor concentrations (averaged continuous PM2.5 (or PM10) concentration divided by PM2.5 385 (or PM 10) by filter mass concentration). This factor was applied to scale the real time data. A zero calibration was performed before each day using a zero filter which comes with the DustTrak DRX. Similarly, a daily flow calibration was performed with a Gilibrator flowmeter following procedures in Operation and Service Manual Model 8533/8534 (P/N 6001898, Revision F, January 2011). The DustTrak inlet was cleaned after each day with a cotton swab. 390 2.4.4 CO2 C02 was continuously measured using an NDIR instrument (LI-COR 820 model, LI-COR Biosciences, Lincoln, NE, USA). This unit was configured with a 14 cm optical bench, giving it an analytical range of 0- 20,000 ppm with an accuracy specification of less than 3 % of reading. The LICOR was calibrated in accordance with U.S. EPA Method 3A [14] with three-point zero and calibration drift test. The LI-COR 395 820 C02 concentration was recorded every second on the onboard computer using the FlyerDAQ program. The calibration error for all test days was between 0.001 % and 0.559 %, and the system drift was between 0.015 % and 0.319 %, below the error and drift acceptance criteria of 5% and 3%, respectively, as stated by the U.S. EPA Method 3A [14]. 2.4.5 CO 400 A Horiba Model VIA510 CO monitor (Horiba Instruments, Inc, Chicago III) was used on the side of the Flyer's C02 inlet during the paperboard tests (November 2014 test period). The analyzer operates by directing identical infrared (IR) beams through an optical sample cell and a sealed optical reference cell. A detector, located at the opposite end of the cells, continuously measures the difference in the amount of infrared energy absorbed within each cell. This difference is a measure of the concentration of the 405 component of interest in the sample. The CO analyzer adheres to U.S. EPA Method 10 [15]. Calibration and post drift tests were performed each test day. The calibration error for all test days was between 0.01 % and 1.10 %, and the system drift was between 0.66 % and 1.57 %, below the error and drift acceptance criteria of 5% and 3%, respectively, as stated by the U.S. EPA Method 3A [14]. 410 12 ------- An electrochemical gas sensor (e2V EC4-500-CO, SGX Sensortech, Buckinghamshire, United Kingdom) was used for the MRE tests. This sensor measures CO concentration by means of an electrochemical cell through CO oxidation and changing impedance. The E2v CO sensor has a CO detection range of 1-500 ppm with resolution of 1 ppm and sensitivity of 55-85 nA/ppm. The response time is less than 30 415 seconds. The CO sensor was calibrated and tested for post-drift on a daily basis in accordance with U.S. EPA Method 3A. The system drift was between 0.168 % and 4.993 % (for one test day only, otherwise below 3 %), which was both above and below the 3 % acceptance criterion as stated by the U.S. EPA Method 3A [14], respectively. For the test day where the drift was 4.993 %, the calibration curve was used for the first half of the tests and the post-drift curve was used for the second half of the tests. 420 2.5 Calculations 2.5.1 Emission factors The emission factor for each species was calculated from the ratio of pollutant concentrations to background-corrected carbon concentration as calculated from C02 and CO measurements (AC02, ACO and ACH4 for VOCs). Emission factors were calculated using these concentrations and the fraction of C in 425 fiberboard/MRE material, following the carbon balance method [16]. This approach assumes that all carbon in the combusted material is emitted as C02, CO, and CH4. Pollutant (งฆ) Emission Factor (g Pollutant/g Material) = Fcx . Equation 2-1 I Carbon @) where: Fc = carbon fraction in the fiberboard/MRE material, Carbon = amount of carbon sampled 430 derived from AC02, and ACO (and ACH4 for VOCs) concentration in the plume. 2.5.2 PCDD/PCDF Toxic Equivalent Calculations PCDDs and PCDFs include 75 and 135 congeners, respectively. Of these 210 congeners, 17 are toxic and have been assigned TEF values [12] (Table 2-8). The TEQ value is obtained by multiplying the 435 concentration of a PCDD/PCDF congener by its TEF-value and summarizing the result for all 17 toxic congeners. The U.S. EPA has listed 16 priority PAHs. Some of these PAHs are probably carcinogenic to humans according to U.S. EPA. Table 2-9 lists these 16 PAHs and their TEFs for humans. 13 ------- 440 Table 2-8. PCDD/PCDF Toxic Equivalency Factors for mammals/humans [12]. PCDDs TEF PCDFs TEF 2,3,7,8 - TCDD 1 2,3,7,8-TCDF 0.1 1,2,3,7,8 - PeCDD 1 1,2,3,7,8 - PeCDF 0.03 1,2,3,4,7,8 - HxCDD 0.1 2,3,4,7,8 - PeCDF 0.3 1,2,3,6,7,8 - HxCDD 0.1 1,2,3,4,7,8 - HxCDF 0.1 1,2,3,7,8,9 - HxCDD 0.1 1,2,3,6,7,8 - HxCDF 0.1 1,2,3,4,6,7,8 - HpCDD 0.01 1,2,3,7,8,9 - HxCDF 0.1 1,2,3,4,6,7,8,9 -OCDD 0.0003 2,3,4,6,7,8 - HxCDF 0.1 1,2,3,4,6,7,8 - HpCDF 0.01 1,2,3,4,7,8,9 - HpCDF 0.01 1,2,3,4,6,7,8,9 -OCDF 0.0003 Table 2-9. PAH Toxic Equivalency Factors for humans [17]. Compound TEF Compound TEF Naphthalene 0 Benzo(a)anthracenea,b 0.005 Acenaphthylene 0 Chrysenea,d 0.03 Acenaphthene 0 Benzo(b)fluoranthenea 0.1 Fluorenec,d 0 Benzo(k)fluoranthenea,b 0.05 Phenanthrenec,d 0.0005 Benzo(a)pyrenea,b 1.0 Anthracenecd 0.0005 lndeno(l,2,3-cd)pyreneab 0.1 Fluoranthenec,d 0.05 Dibenz(a,h)anthracenea 1.1 Pyrenecd 0.001 Benzo(ghi)perylenecd 0.02 a Probably carcinogenic to humans according to US EPA.b Probably and possibly carcinogenic to humans according to International Agency for Research on Cancer (IARC).c Not classifiable as carcinogenic to humans according to US EPA. 445 d Not classifiable as carcinogenic to humans according to IARC. 2.5.3 Modified Combustion Efficiency The modified combustion efficiency (MCE) (Equation 2-2) is a measure of combustion behavior or how 450 well the fuel is being burned where MCE = 1.0 is complete combustion. The MCE can be categorized as MCE > 0.95, indicating flaming conditions (good combustion) and MCE < 0.90, indicating smoldering conditions (poor combustion). A C02 MCE = Equation 2-2 AC02 + ACO H 455 14 ------- 2.6 Data Precision The data precision was checked by calculating: Relative percent difference (RPD) for any pair of duplicates 460 Q-B RPD = 100x Equation 2-3 Q + B where: Q = results from one sample, B = results from replicate samples 465 Standard deviation (STDV) if more than duplicate measurements were conducted STDV = 1 N (=1 Equation 2-4 470 Wherewhere: n = average results from all samples, x, = results from one sample N = number of samples Or expressed as Relative Standard Deviation (RSD) STDV RSD = 100X Equation 2-5 Average 475 Single factor one-way analysis of variance (ANOVA) with alpha of 0.05 (level of significance) was used to determine any differences between the four fiberboards types and between the four MRE waste compositions types. To establish significant difference the ANOVA returned p value (significant value) has to be less than the alpha value (0.05) and the F-distribution value (F/Fcrrt) has to be greater than 1.0. 15 ------- 480 3 Results and Discussion Results from each collected sample are presented in Appendix A and B. 3.1 PM 3.1.1 Fiberboard packaging Typical traces of PM, CO, and C02 throughout each of the fiberboard burns are shown in Figure 3-1 A-D, 485 below. In general, concentrations of CO and C02 mimic the increase in particle concentration. Peak particle concentrations range from 10-20 mg/m3, although one packaging type, NWS, exceeded 50 mg/m3. The similarity of the PMi to Total PM traces (Figure 3-1) indicates that the majority of the particles are small, < 1 pim, and therefore respirable. Figure 3-2 examines PM emission factors with time over the replicates and also plots MCE to see if there is any relationship between PM emissions and 490 combustion quality. While most of the runs have consistent, packaging-specific emission factors, the variance in a few runs illustrates the effect of random waste orientation on emissions. Also, while there are suggestions from limited tests that poor combustion quality (low MCE) increases PM emissions (NSB/NSL R2 of 0.81 and SB/SL R2 of 0.55, figure not shown), the correlations seem inconsistent (CB/CL R2 of 0.056 and NWS R2 of 0.056, figure not shown). Single factor ANOVA showed no statistical 495 difference between the PM emission factors for the different fiberboard types (F = 0.24, p = 0.56). CB/CL PM10 12000 NWS 10000 PM10 12:29 12:32 12:35 12:39 12:42 12:45 12:49 Time (hh:mm) Figure 3-1. Typical traces of PM, CO, and CO2 throughout each of the fiberboard type burns. NSB/NSL pmio Total PM PM10 8000 -| 7000 - 6000 - a 5000 - 2. ~ 4000 - 3000 - 2000 - 1000 - 0 - 9:28 9:30 9:32 9:34 9:36 9:38 9:40 9:42 9:44 9:46 Time (hh:mm) 8000 7000 _ 6000 I. 5000 Q. J 4000 J 3000 2000 1000 10:42 10:44 10:47 10:50 10:52 10:55 10:58 11:00 Time (hh:mm) 16 ------- 9.0 f 8.0 0 7.0 si 1 6'ฐ m 5.0 3 4.0 Ll_ 5 3'ฐ 2.0 1.0 0.0 5.0 n 4.0 - 3.0 - 2.0 - 1.0 - ] PM2.5 IPM10 MCE NSB/NSL 0.0 ] PM2.5 IPM10 MCE 4 5 Replicates SB/SL 3 4 5 Replicates r 1-000 - 0.990 - 0.980 - 0.970 , i - 0.960 ' - 0.950 - 0.940 - 0.930 r 1.000 - 0.990 - 0.980 - 0.970 L (. - 0.960 " - 0.950 - 0.940 - 0.930 6.0 i ~o 15 5.0 0 jQ 1 4-ฐ tao < 3.0 - tap LI- 5 2.0 Q_ 1.0 - 0.0 - 4.0 tT 3.5 - ro J 3.0 0) 5 2.5 tlO < 2.0 - bp 1.5 - i 1.0 - 0.5 - 0.0 - ] PM2.5 IPM10 MCE NWS ni1 ] PM2.5 IPM10 MCE ft n 4 5 6 Replicates CB/CL nl~l 4 5 Replicates 500 Figure 3-2. PM2.5 and PM10 emission factors and modified combustion efficiency (MCE] for each replicate. PM2.5 PM10 8.0 5.0 CO 05 3.0 2.0 NSB/NSL NWS SB/SL CB/CL 505 Figure 3-3. I'M2.5 and PM10 emission factors from open burning of fiberboard. Error bars represent 1 STDV. 17 ------- 510 Table 3-1. PM emission factors. PM2.5 PM10 mg/kg Paperboard mg/kg Paperboard Paperboard Average STDV Average STDV NSB/NSL 3.4 1.95 3.4 1.66 NWS 3.4 0.72 3.6 0.72 SB/SL 2.8 0.86 2.7 0.89 CB/CL 2.9 0.63 2.9 0.70 3.1.2 MRE pouches PM emission factors are shown in Figure 3-4 for the MRE waste compositions and the baseline CB/CL. As with fiberboard packaging, 515 addition of any MRE composition to the baseline CB/CL fiberboard increases the emission factor by approximately 3-4 times. The effect of composition changes on PM emission factors, however, is indiscernible (single factor ANOVA F = 0.24, p = 0.53). The PMio is nearly the same as PM2.5, indicating that the vast majority of the PM is 2.5 micrometers in size or less. The PM emission factors did not correlate with the MCE (Figure 3-5), r2 = 0.0011-0.34 (scatter plot not shown). 520 PM2.5 PM10 18.0 - 16.0 - 14.0 - 10.0 - 100% Baseline CB/CL NEW Figure 3-4. PM emission factors from open burning of MREs. Error bars represent 1 STDV. 18 ------- 100% NEW Material 525 16.0 - PM2.5 PM10 -a 14.0 - ฃ 12.0 - 10.0 - 6.0 - 4.0 - 14.0 i "E 12.0 - tX3 o m lo.o - .a w> 8.0 - - 6.0 - LU | 4.0 - 2.0 - 0.0 - Figure 3-5. replicate. 2 3 4 5 Replicates ]PM2jTj 32o/o NEW Material IPM10 MCE 2 3 4 Replicates r 1.000 16.0 -i T3 14.0 - - 0.980 03 -Q 12.0 - OJ - 0.960 10.0 - bo u 8.0 - bp - 0.940 Ll_ LU 6.0 - Q_ 4.0 - - 0.920 2.0 - - 0.900 0.0 - ] PM2.5 IPM10 66% NE JV Material r 0.970 - 0.960 - 0.950 - 0.940 , - 0.930 - 0.920 - 0.910 - 0.900 3 4 Replicates r 0.960 20.0 T3 - 0.950 tX3 O -Q 15.0 - - 0.940 CD -Q - 0.930 MCE 10.0 - Ll_ - 0.920 Q_ 5.0 - - 0.910 - 0.900 0.0 - IpM2.5 | 0% NEW Materiair ฐ"95ฐ IPM10 MCE - 0.940 / - 0.930 - 0.920 y. - 0.910 - 0.900 0.890 3 4 Replicates PM2.5 and PM10 emission factors and modified combustion efficiency (MCE) for each 3.2 Metals and Other Trace Elements Emission factors for metals and other trace elements are shown in Figure 3-6 and Table 3-2 for the MRE 530 waste composition. No effect on the emission factors was found for the different MRE waste compositions. Chlorine (CI), Sulfur (S), Potassium (K) were the most abundant elements observed. The Al emission factors were very similar for the four MRE waste compositions, 2.3-2.8 mg/kg MRE. 535 HI 40 1 1 3.5 - tUD ^ 3.0 - tUJ ฃ 2.5 - to o 2.0 - S 15 - LL_ ฑ"J | 1.0 - 'to ฆ| 0.5 - m 0.0 - ~ 100% N EW ฆ 66% N EW ~ 32% NEW ~ 0% NEW M H ... fib Al Fe Cr Pb Cu Elements Zn Br cu 5 M 100 1 80 - 60 - 40 - 20 - 0 - Si ci ~ 100% N EW ฆ 66% N EW ~ 32% NEW ~ 0% NEW niffi ififi Elements Figure 3-6. Major metal and trace /element emission factors from open burning of MRE's. I 19 ------- Table 3-2. Major metal and trace /element emissions from open burning of MRE pouches.3 l\ EW 100 % 66% 32% 0% Element mg/kg STDV mg/kg STDV mg/kg STDV mg/kg STDV Al 2.3 0.43 2.8 0.75 2.3 0.30 2.7 0.78 Fe 0.30 0.030 0.51 0.45 0.31 0.11 0.29 0.046 Cr 0.059 0.027 0.15 0.19 0.027 0.0058b 0.040 0.025 Pb 0.056 0.044 0.086 0.033 0.045 0.016 0.071 0.012 Cu 0.21 0.075 0.23 0.079 0.17 0.057 0.17 0.062 Zn 0.97 0.18 0.91 0.31 0.74 0.15 0.78 0.24 Br 2.0 0.33 2.2 0.59 2.1 0.18 2.3 0.36 Si 5.7 0.56 9.0 3.8 5.6 1.1 5.4 0.6 CI 60 23 54 18 59 25 68 18 P 10 1.3 11 3.2 10 2.0 10 2.5 S 26 2.9 25 5.3 26 5.2 26 3.3 K 21 2.2 17 3.1 20 2.8 17 0.91 540 3 The metals and trace elements here were selected based on the number of samples where the material was detected more than three times the uncertainty level of the analysis. Full list of all XRF elements analytes are shown in Appendix B, Table B19.b Relative difference. 3.3 VOCs 3.3.1 Fiberboard packaging Results for select VOC emission factors for the MRE fiberboard packaging burns are shown in Figure 3-7 and Table 3-3 . For the four packaging types, benzene is the most prevalent VOC at approximately 80 to 545 150 mg/kg of fiberboard material. For three of the four materials, acrolein is the next most prevalent. Typical combustion-related aromatic pollutants (benzene, toluene, acrolein, and xylenes) are linearly related to the MCE value (Figure 3-8). A more complete set of emission factors by packaging type is shown in Appendix A, Tables A26-29. 300 0 250 -Q q3 ฃ 200 O) 1 150 w 100 o o > 50 1L ~ Benzene* ~ Acrolein* ~ Styrene* BToluene* ~ Ethylbenzene* Bm.p-Xylenes* De i IL llni- CB/CL SB/SL NSB/NSL NWS 550 Figure 3-7. Select VOCs and their emission factors for the different fiberboard types. * = on EPA's list of hazardous air pollutants. 20 ------- o CO " s jo -e r- 0 ,lฃ J? E "5) lu E 300 i 250 - 200 - 150 - 100 - 50 - Benzene R2 = 0.8586 0 0.960 CB/CL SB/SL NSB/NSL o NWS o 0.970 0.980 MCE 0.990 o CO " s jo -e r- 0 ,lฃ .ซ i? E "5) lu e 120 i 100 - 80 - 60 - 40 - 20 - Toluene R2 = 0.8356 CB/CL SB/SL NSB/NSL o NWS 0 0.960 o o i 0.970 0.980 MCE 0.990 T3 o lo " S CO -g c 0 .ซj? E "5) lu e 160 140 120 100 80 60 40 20 0 0. Acrolein * R2 = 0.6626 CB/CL SB/SL NSB/NSL o NWS 960 0.970 0.980 0.990 MCE 25 n 20 - ^ "O o ro u ฃ 03 -0 ^ _Q .2 4= f/5 05 ^ 10 15 - E "5) lu e 5 - 0 0.960 Xylene R2 = 0.8623 CB/CL SB/SL NSB/NSL o NWS n ฆฆฆ ฐ 0.970 0.980 MCE 0.990 Figure 3-8. Select VOCs versus modified combustion efficiency (MCE). Table 3-3. VOC emission factors. Compound CB/CL Average STDV mg/kg mg/kg SB/SL Average mg/kg STDV mg/kg NSB/NSL Average STDV mg/kg mg/kg NWS Average mg/kg STDV mg/kg Benzene3 79 75 153 102 91 49 111 16 Propene 38 42 118 94 84 57 51 9.4 Vinyl Acetate3 33 13 98 70 50 NA 48 CD Acrolein3 9.4 4.8 81 64 76 60 36 5.9 Toluene3 19 19 57 44 28 16 26 4.6 1,3-Butadiene3 19 22 44 43 34 23 24 5.3 Styrene3 5.6 2.5 60 64 13 7.5 13 1.6 2-Butanone (MEK) 9.3 11 23 19 24 16 10 3.0 Ethyl benzene3 2.4 2.2 15 13 4.6 2.9 4.1 0.60 Methylene Chloride 5.5 5.3 2.2 2.1b 3.1 3.4 6.7 5.3 /rj-,p-Xylenes3 1.9 1.7 6.9 6.1 5.5 3.5 3.7 0.82 o-Xylene3 0.74 0.58 2.9 2.6 2.2 1.4 1.5 0.32 Acetonitrile 1.2 1.1 3.0 2.0 1.6 0.84 0.62 0.10 Cumene3 0.33 NA 1.5 1.4 0.29 0.12 0.20 0.027 555 3 Included in the EPA list of hazardous air pollutants.b Relative difference. NA = not applicable. The VOCs shown here were selected based on the number of samples where the compound was detectable above three times the detection limit with relevance to the EPA's list of hazardous air pollutants. Full list of the 88 VOCs analyzed and their emission factors are presented in Appendix A, Tables A26-29. 21 ------- 560 565 3.3.2 MRE pouches Select VOC data for the MRE packaging are shown in Figure 3-9, and values for the full data set are in Table 3-4. As with the fiberboard packaging, benzene is the most common compound followed by acrolein. All VOC concentrations are higher with the presence of MREs than the CB Baseline. No concentration trend with changing amounts of NEW material is noted. As for the fiberboard, the selected VOCs showed a linear relationship with MCE (increased emission factors with decreased MCE), Figure 3-10. Although the R2 of 0.39-0.78 was lower for open burning of MRE than for only combusting fiberboard (R2 of 0.66-0.86), these differences can be due to the overall better MCE occurring during the fiberboard burns, Figure 3-11. 0 H' CO E O) E LL LU O o > 350 -i 300 - 250 - 200 150 100 50 M 100% i 66% | 32% NEW Material ~ Benzene* ~ Acrolein* ฆ Toluene* ~ 1,3-Butadiene* i o% CB Baseline 570 Figure 3-9. VOC emission factors from open burning of MREs. * = on EPA's list of Hazardous Air Pollutants (HAPs). Table 3-4. VOC emission factors from open burning of MREs. 0 % NEW 32 % NEW 66 % NEW 100 % NEW Average STDV Average STDV Average RPD Average STDV Compound mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg Benzene3 268 83 329 16 253 1.3% 286 75 Propene 211 89 266 10 182 6.7% 225 36 Vinyl Acetate3 101 41 111 24 93 17% 109 27 Acrolein3 125 40 145 16 126 10% 126 27 Toluene3 63 36 79 37 52 22% 58 18 1,3-Butadiene3 103 38 126 12 82 2.8% 94 55 Styrene3 206 192 283 198 210 10% 120 79 2-Butanone (MEK) 23 6.9 26 3.8 25 19% 24 7.8 Ethyl benzene3 16 12 24 14 18 1.8% 15 6.0 Methylene Chloride 5.4 0.66 6.0 0.93 4.8 15% 5.7 1.4 /rj-,p-Xylenes3 2.7 0.36 3.2 0.56 2.6 15% 3.1 0.72 o-Xylene3 7.6 2.5 12 1.3 8.8 22% 13 1.9 Acetonitrile 0.95 0.69 1.5 0.89 1.2 5.1% 0.82 0.33 Cumene3 268 83 329 16 253 1.3% 286 75 3 Included in the EPA list ofHAPs. The VOCs shown here were selected based on the number of compounds detectable above three times the detection limit and their relevance to the EPA's list of HAPs. Full list of the 88 VOCs analyzed and their emission factors are presented in Appendix B, Tables B20-24. 22 ------- -2 LU ฐ rv CO 375 300 225 0 D> o> 60 - E m 40 - 20 - 0 Toluene R2 = 0.3142 100% NEW 66% NEW 32% NEW o0% NEW 0.97 0.975 0.98 MCE 0.985 -2 LU ฐ rv ro U- 200 1 160 - 120 - o u) ฆ| E 80 H LU """ 40 - Acrolein o R2 = 0.5936 100% NEW 66% NEW 32% NEW O0% NEW 0.97 0.975 0.98 MCE 0.985 -2 LU ฐ fV CO th o u) 0.96 0.97 0.98 MCE 0.99 200 n g 160 \ ro 120 H lu OH E 5 m # 40 H D) E 0 Acrolein MRE pouches Fiberboard * . R2 = 0.5936 R2 = 0.6626 0.96 0.97 0.98 MCE 0.99 Figure 3-11. Benzene and acrolein vs. MCE for all MRE waste compositions and fiberboard types burns. 580 3.4 PAHs 3.4.1 Paperboard packaging 23 ------- 585 Fiberboard burns resulted in PAH emission factors as shown for sums (Figure 3-12), individual PAHs (Table 3-5), and TEF-weighted PAHs (Table 3-6). No difference was seen between the fiberboard types (Figure 3-12) (single factor ANOVA, F = 0.51, p = 0.20); PAH emissions are the same no matter what fiberboard type. CD ^3 x" E Q- .Q i 1 CO O) E 140 -i 120 - 100 - 80 - 60 40 20 0 Average CB/CL Replicates NSB/NSL Replicates NWS Replicates SB/SL Replicates PAHs I I : } : CB/CL NSB/NSL NWS SB/SL Figure 3-12. PAH emission factors from open burning of fiberboard packaging. Error bars represent 1 standard deviation. 590 Table 3-5. PAH emission factors from open burning of fiberboard in mg/kg fiberboard. NWS CB/CL NSB/NSL SB/SL Average STDV Average STDV Average STDV Average STDV Compound mg/kg Fiberboard mg/kg Fiberboard mg/kg Fiberboard mg/kg Fiberboard Naphthalene 28 21 14 15 21 9.9 15 6.7 Acenaphthylene 13 9.3 5.5 5.2 6.9 2.7 4.8 2.2 Acenaphthene 0.68 0.45 0.24 0.18 0.43 0.19 0.35 0.20 Fluorene 3.0 1.6 1.1 0.86 1.4 0.56 1.8 0.79 Phenanthrene 10 4.7 4.3 3.0 4.4 1.3 6.8 3.0 Anthracene 2.4 1.3 0.89 0.64 0.99 0.33 1.7 0.87 Fluoranthene 4.9 2.7 2.0 0.93 1.8 0.29 2.7 1.2 Pyrene 4.5 2.5 1.8 0.80 1.7 0.24 2.4 1.1 Benzo(a)anthracene 1.2 0.65 0.44 0.27 0.44 0.13 0.75 0.35 Chrysene 1.1 0.57 0.43 0.28 0.41 0.11 0.72 0.34 Benzo(b)fluoranthene 0.62 0.32 0.24 0.14 0.23 0.068 0.33 0.16 Benzo(k)fluoranthene 0.91 0.45 0.31 0.18 0.27 0.055 0.40 0.17 Benzo(a)pyrene 1.0 0.55 0.34 0.22 0.31 0.067 0.46 0.22 lndeno(1,2,3-cd)pyrene 0.66 0.33 0.22 0.13 0.20 0.035 0.28 0.13 Dibenz(a,h)anthracene 0.11 0.067 0.041 0.030 0.037 0.011 0.067 0.038 Benzo(ghi)perylene 0.73 0.37 0.26 0.18 0.21 0.035 0.27 0.11 SUM 16-EPA PAH 74 40 32 28 41 16 38 16 24 ------- Table 3-6. PAH TEQ emission factors from open burning of fiberboard in mg B[a]P TEQ/kg fiberboard.a Compound NWS Average STDV CB/CL Average STDV mg B[a]P TEQ/kc NSB/NSL Average STDV Fiberboard SB/SL Average STDV Naphthalene NA NA NA NA NA NA NA NA Acenaphthylene NA NA NA NA NA NA NA NA Acenaphthene NA NA NA NA NA NA NA NA Fluorene NA NA NA NA NA NA NA NA Phenanthrene 5.1E-03 2.4E-03 2.1E-03 1.5E-03 2.2E-03 6.4E-04 3.4E-03 1.5E-03 Anthracene 1.2E-03 6.3E-04 4.4E-04 3.2E-04 5.0E-04 1.6E-04 8.4E-04 4.3E-04 Fluoranthene 2.5E-01 1.3E-01 9.8E-02 4.6E-02 8.8E-02 1.4E-02 1.3E-01 5.9E-02 Pyrene 4.5E-03 2.5E-03 1.8E-03 8.0E-04 1.7E-03 2.4E-04 2.4E-03 1.1E-03 Benzo(a)anthracene 5.9E-03 3.3E-03 2.2E-03 1.4E-03 2.2E-03 6.3E-04 3.7E-03 1.7E-03 Chrysene 3.2E-02 1.7E-02 1.3E-02 8.4E-03 1.2E-02 3.3E-03 2.2E-02 1.0E-02 Benzo(b)fluoranthene 6.2E-02 3.2E-02 2.4E-02 1.4E-02 2.3E-02 6.8E-03 3.3E-02 1.6E-02 Benzo(k)fluoranthene 4.5E-02 2.3E-02 1.5E-02 9.2E-03 1.3E-02 2.7E-03 2.0E-02 8.3E-03 Benzo(a)pyrene 1.0E+00 5.5E-01 3.4E-01 2.2E-01 3.1E-01 6.7E-02 4.6E-01 2.2E-01 lndeno(1,2,3-cd)pyrene 6.6E-02 3.3E-02 2.2E-02 1.3E-02 2.0E-02 3.5E-03 2.8E-02 1.3E-02 Dibenz(a,h)anthracene 6.2E-02 7.3E-02 2.5E-02 1.8E-02 3.4E-02 2.4E-02 6.4E-02 5.5E-02 Benzo(ghi)perylene 1.5E-02 7.3E-03 5.3E-03 3.5E-03 4.2E-03 7.0E-04 5.4E-03 2.3E-03 SUM 16-EPA PAH 1.6E+00 8.2E-01 5.4E-01 3.1E-01 5.1 E-01 1.2E-01 7.7E-01 3.8E-01 a NA - not applicable (no TEF value). 595 3.4.2 MRE pouches MRE burns resulted in PAH emission factors as shown for sums (Figure 3-13), individual PAHs (Table 3-7), and TEF-weighted PAHs ( Table 3-8). Single factor ANOVA (F = 0.24, p = 0.44) showed no difference in PAH emissions among the different MRE waste categories (Figure 3-13). However, a weak difference was seen between the 600 different MRE waste categories and CB/CL fiberboard type (F = 1.04, p = 0.045). Higher PAH emissions resulted from burning MREs and CB/CL together. No difference was seen between the MRE types (Figure 3-13); PAH emissions are the same no matter what MRE waste category. ------- 250 200 150 g E 100 50 0 PAHs ~Average >100% NEW Replicates 66% NEW Replicates 32% NEW Replicates >0% NEW Replicates i : t 1 1 1 1 100% NEW 66% NEW 32% NEW 0% NEW Figure 3-13. PAH emission factors from open burning of MREs. Error bars represent 1 standard deviation. Table 3-7. PAH emission factors from open burning of MRE pouches in mg/kg MRE. 0% New 32% New 66% New 100% New Average STDV Average STDV Average STDV Average STDV Compound mg/kg MRE mg/kg MRE mg/kg MRE mg/kg MRE Naphthalene 46 15 40 8.7 31 3.3 65 39 Acenaphthylene 15 5.7 12 2.1 11 1.3 19 9.8 Acenaphthene 0.69 0.25 0.58 0.14 0.57 0.011 0.87 0.57 Fluorene 4.5 1.9 3.2 0.47 3.5 0.68 4.8 2.6 Phenanthrene 16 7.0 11 1.95 14 3.3 16 7.3 Anthracene 2.5 1.0 2.0 0.38 2.3 0.36 2.9 1.5 Fluoranthene 3.2 1.4 2.4 0.37 2.9 0.029 3.7 1.4 Pyrene 2.2 1.0 1.9 0.39 2.1 0.18 2.9 1.3 Benzo(a)anthracene 1.3 0.65 0.82 0.20 1.09 0.023 1.4 0.69 Chrysene 1.5 0.79 0.99 0.22 1.37 0.021 1.5 0.75 Benzo(b)fluoranthene 0.91 0.45 0.57 0.14 0.77 0.016 0.85 0.45 Benzo(k)fluoranthene 0.83 0.47 0.60 0.11 0.72 0.104 0.89 0.36 Benzo(a)pyrene 0.79 0.43 0.56 0.14 0.65 0.079 0.86 0.44 lndeno(1,2,3-cd)pyrene 0.57 0.30 0.36 0.088 0.43 0.072 0.59 0.27 Dibenz(a,h)anthracene 0.21 0.110 0.115 0.031 0.138 0.0048 0.19 0.10 Benzo(ghi)perylene 0.50 0.25 0.37 0.10 0.37 0.111 0.58 0.27 SUM 16-EPA PAH 96 37 77 15 73 1.8 122 67 ------- 610 Table 3-8. PAH TEQ emission factors from open burning of MRE pouches in mg B[a]P TEQ/kg MRE.a 0% NEW 32% NEW 66% NEW 100% NEW Average STDV Average STDV Average STDV Average STDV Compound mg B[a]P TEQ/kg MRE Naphthalene NA NA NA NA NA NA NA NA Acenaphthylene NA NA NA NA NA NA NA NA Acenaphthene NA NA NA NA NA NA NA NA Fluorene NA NA NA NA NA NA NA NA Phenanthrene 7.9E-03 3.5E-03 5.6E-03 9.8E-04 6.9E-03 1.6E-03 8.2E-03 3.7E-03 Anthracene 1.3E-03 5.1E-04 9.9E-04 1.9E-04 1.2E-03 1.8E-04 1.5E-03 7.6E-04 Fluoranthene 1.6E-01 7.2E-02 1.2E-01 1.8E-02 1.5E-01 1.4E-03 1.8E-01 7.1E-02 Pyrene 2.2E-03 9.7E-04 1.9E-03 3.9E-04 2.1E-03 1.8E-04 2.9E-03 1.3E-03 Benzo(a)anthracene 6.3E-03 3.2E-03 4.1E-03 1.0E-03 5.5E-03 1.2E-04 6.8E-03 3.4E-03 Chrysene 4.5E-02 2.4E-02 3.0E-02 6.5E-03 4.1E-02 6.2E-04 4.6E-02 2.3E-02 Benzo(b)fluoranthene 9.1E-02 4.5E-02 5.7E-02 1.4E-02 7.7E-02 1.6E-03 8.5E-02 4.5E-02 Benzo(k)fluoranthene 4.1E-02 2.4E-02 3.0E-02 5.3E-03 3.6E-02 5.2E-03 4.4E-02 1.8E-02 Benzo(a)pyrene 7.9E-01 4.3E-01 5.6E-01 1.4E-01 6.5E-01 7.9E-02 8.6E-01 4.4E-01 lndeno(1,2,3-cd)pyrene 5.7E-02 3.0E-02 3.6E-02 8.8E-03 4.3E-02 7.2E-03 5.9E-02 2.7E-02 Dibenz(a,h)anthracene 2.3E-01 1.2E-01 1.3E-01 3.4E-02 1.5E-01 5.2E-03 2.1E-01 1.1E-01 Benzo(ghi)perylene 1.0E-02 4.9E-03 7.5E-03 2.1E-03 7.5E-03 2.2E-03 1.2E-02 5.5E-03 SUM 16-EPA PAH 1.4E+00 7.6E-01 9.8E-01 2.2E-01 1.2E+00 9.3E-02 1.5E+00 7.5E-01 a NA - not applicable (no TEF value). 3.5 PCDD/PCDF 3.5.1 Fiberboard packaging 615 Emission values for the MRE shipping containers (Figure 3-14) show PCDD/PCDF emission factors that are low compared to the cellulosic biomass [18]. One emission factor value, however, that of SB/SL, stands out from the other fiberboard types as being distinctively high. Paired single factor ANOVA analyses showed a significant difference between SB/SL and the other fiberboard types (F = 1.43, 1.02, 2.61 and p = 0.026, 0.048, 0.0065). The same high value for SB/SL results when examining the 620 PCDD/PCDF total value (Table 3-10), consisting of the sum of all of the homolog concentrations. The results are internally consistent in that the 1,2,3,7,8 - PeCDD congener and the 2,3,4,7,8 - PeCDF congener consistently contribute the most to their respective TEQ values (Table 3-9). A number of compositional factors (Table 2-1) may have resulted in this comparatively higher PCDD/PCDF value, including lower calorific value, higher loss on drying, higher chloride, and lower sulfur. In general, better 625 combustion (processes with higher fuel calorific value and lower moisture content) results in lower PCDD/PCDF formation due to the diminished availability of organic precursors. Higher chloride values and lower sulfur values have generally been associated with increased formation of PCDD/PCDF, the former acting as a chlorination promotor, and the latter acting to suppress PCDD/PCDF formation. 27 ------- CD o Ll_ -Q 8 CL 5 ^ H o w) Q < u re Q_ Jr! CUD 0.45 0.40 0.35 0.30 0.25 0.20 0.15 0.10 0.05 0.00 O Average CB/CL Replicates NSB/NSL Replicates NWS Replicates SB/SL Replicates I o CB/CL NSB/NSL NWS SB/SL 630 Figure 3-14. PCDD/PCDF emission factors from open burning of fiberboard packaging. Error bars represent 1 standard deviation. Table 3-9. PCDD/PCDF TEQ emission factors. CB/CL NSB/NSL NWS SB/SL Isomer. Average STDV Average STDV Average STDV Average STDV ng TEQ/kc fiberboard 2,3,7,8 - TCDD 3.20E-03 1.51E-03 1.25E-02 2.17E-03 6.05E-03 2.11 E-03 2.76E-02 1.78E-02 1,2,3,7,8- PeCDD 1.26E-02 3.95E-03 5.17E-02 2.36E-02 1.63E-02 7.55E-03 1.18E-01 8.06E-02 1,2,3,4,7,8- HxCDD 8.22E-04 3.42E-04 2.78E-03 9.28E-04 1.06E-03 4.28E-04 6.70E-03 4.21 E-03 1,2,3,6,7,8- HxCDD 1.68E-03 4.09E-04 9.23E-03 3.54E-03 1.72E-03 7.64E-04 2.07E-02 1.25E-02 1,2,3,7,8,9- HxCDD 1.40E-03 4.57E-04 6.74E-03 2.60E-03 1.52E-03 4.28E-04 1.54E-02 9.77E-03 1,2,3,4,6,7,8- HpCDD 1.75E-03 4.93E-04 1.20E-02 3.91 E-03 1.65E-03 4.17E-04 2.52E-02 1.19E-02 1,2,3,4,6,7,8,9 - OCDD 1.44E-04 3.82E-05 1.01 E-03 2.52E-04 1.26E-04 4.01 E-05 2.05E-03 7.88E-04 2,3,7,8 - TCDF 9.26E-03 6.22E-03 7.09E-03 1.13E-03 8.71 E-03 4.93E-03 2.38E-02 4.96E-03 1,2,3,7,8- PeCDF 9.13E-04 3.74E-04 5.70E-04 3.88E-04 1.38E-03 1.16E-03 2.03E-03 2.47E-04 2,3,4,7,8- PeCDF 9.76E-03 3.25E-03 7.40E-03 5.07E-03 1.97E-02 1.30E-02 2.56E-02 2.47E-03 1,2,3,4,7,8- HxCDF 2.72E-03 1.30E-03 2.63E-03 5.45E-04 5.66E-03 3.38E-03 4.52E-03 8.73E-04 1,2,3,6,7,8- HxCDF 2.42E-03 1.26E-03 2.05E-03 6.52E-04 5.02E-03 3.58E-03 3.51 E-03 2.94E-04 1,2,3,7,8,9- HxCDF 1.30E-03 8.81 E-04 7.22E-04 7.79E-05 2.26E-03 1.21 E-03 1.39E-03 1.68E-04 2,3,4,6,7,8 - HxCDF 3.52E-03 2.73E-03 2.18E-03 4.74E-04 5.79E-03 2.59E-03 4.58E-03 6.47E-04 1,2,3,4,6,7,8- HpCDF 8.86E-04 8.01 E-04 6.68E-04 1.17E-04 1.23E-03 5.72E-04 1.23E-03 2.30E-04 1,2,3,4,7,8,9- HpCDF 1.60E-04 1.43E-04 1.31 E-04 3.58E-05 2.33E-04 1.66E-04 2.23E-04 7.03E-05 1,2,3,4,6,7,8,9-OCDF 1.67E-05 1.46E-05 2.48E-05 5.44E-06 2.27E-05 1.23E-05 4.86E-05 9.76E-06 PCDD TEQ Total 2.09E-02 6.50E-03 7.92E-02 4.94E-02 2.54E-02 1.11 E-02 2.16E-01 1.37E-01 PCDF TEQ Total 3.09E-02 1.36E-02 2.27E-02 5.70E-03 5.00E-02 2.95E-02 6.70E-02 6.04E-03 PCDD/PCDF TEQ Total 5.19E-02 1.97E-02 1.02E-01 5.50 E-02 7.54E-02 4.05E-02 2.83E-01 1.36E-01 28 ------- Table 3-10. PCDD/PCDF Total emission factors. CB/CL NSB/NSL NWS SB/SL Homologue Average STDV Average STDV Average STDV Average STDV ng/kg fiberboard TeCDD 0.35 0.089 0.39 0.13 0.39 0.12 0.84 0.40 PeCDD 0.18 0.040 0.31 0.17 0.20 0.033 0.80 0.47 HxCDD 0.19 0.060 0.67 0.30 0.19 0.016 1.7 1.0 HpCDD 0.31 0.10 1.9 0.65 0.29 0.071 4.0 1.9 OCDD 0.48 0.13 3.4 0.84 0.42 0.13 6.8 2.6 TeCDF 1.29 0.73 0.93 0.15 1.55 1.09 2.6 0.36 PeCDF 0.37 0.083 0.30 0.14 0.67 0.52 0.84 0.11 HxCDF 0.24 0.14 0.19 0.05 0.47 0.28 0.36 0.024 HpCDF 0.17 0.15 0.17 0.03 0.24 0.12 0.34 0.074 OCDF 0.069 0.043 0.086 0.023 0.076 0.041 0.16 0.033 PCDD Total 1.5 0.37 6.7 2.0 1.5 0.34 14 6.3 PCDF Total 2.1 0.84 1.7 0.30 3.0 2.0 4.3 0.48 PCDD/PCDF Total 3.6 1.2 8.3 2.2 4.5 2.2 19 6.6 635 640 0 u CL o" Q U Q. TO o -Q L_ (U -Q ClD CB/CL ซ NSB/NSL NWS SB/SL Figure 3-15 compares the PCDD/PCDF TEQ values versus MCE, indicating a moderate, negatively correlating relationship. Formation of PCDD/PCDF has historically been tied to marginal combustion, likely due to the presence of surviving organic structures providing the template for chlorination and ring formation. 0.45 0.40 0.35 0.30 0.25 0.20 0.15 0.10 0.05 0.00 R = 0.5678 Figure 3 (MCE). 0.965 0.970 0.975 0.980 0.985 0.990 MCE ฆ15. Fiberboard PCDD/PCDF emission factors versus modified combustion efficiency 29 ------- 645 3.5.2 MRE pouches PCDD/PCDF values are presented for the four compositions of MRE rations tested in Figure 3-16. There is considerable overlap in the ฑ 1 Std Dev range, although "0 % NEW" is the highest value. No statistical difference among the MRE waste compositions was found (single factor ANOVA F = 0.77, p = 0.087). The emission factors up to 2 ng TEQ/kg MRE are several times higher than the emission factors from the 650 packing material alone (Figure 3-16), likely reflecting the more difficult combustion scenario (higher moisture, heterogeneity of packaging morphology) and the likely higher CI content (food salts). The congener- and homolog-specific data are presented in Table 3-11 and Table 3-12, respectively. Figure 3-17 compares the PCDD/PCDF TEQ values versus MCE, indicating a weak negatively correlated relationship. Noticeable is that the MCE for the MRE tests are less than 0.960 while for fiberboard tests 655 the MCE values are greater than 0.965. 0 U CL 0 0 U CL cc CUD CUD c 3.50 -i 3.00 - 2.50 - 2.00 - 1.50 - 1.00 - 0.50 - 0.00 - O Average 100% NEW Replicates 66% NEW Replicates 32% NEW Replicates 0% NEW Replicates o o t 100% NEW 66% NEW 32% NEW 0% NEW Figure 3-16. PCDD/PCDF emission factors from open burning of MREs. Error bars represent 1 standard deviation. 660 665 670 30 ------- Table 3-11. PCDD/PCDF TEQ emission factors. 0% New 32% New 66% New 100% New Isomer. Average STDV Average STDV Average STDV Average STDV ng TEQ/kg MRE 2,3,7,8 - TCDD 2.9E-01 2.4E-01 6.4E-02 3.5E-02 3.3E-02 2.1E-02 6.5E-02 4.2E-02 1,2,3,7,8- PeCDD 1.3E-01 2.2E-02 8.8E-02 2.3E-02 3.6E-02 1.6E-02 8.6E-02 3.4E-02 1,2,3,4,7,8- HxCDD 5.4E-03 2.1E-03 3.3E-03 1.1E-03 2.2E-03 4.1E-04 3.3E-03 1.3E-03 1,2,3,6,7,8- HxCDD 7.2E-03 6.3E-03 7.8E-03 1.2E-03 6.4E-03 1.1E-03 8.0E-03 1.2E-03 1,2,3,7,8,9- HxCDD 6.0E-03 5.3E-03 7.2E-03 2.0E-03 5.9E-03 8.6E-04 6.3E-03 5.4E-04 1,2,3,4,6,7,8- HpCDD 1.2E-02 5.1E-04 8.8E-03 4.8E-04 9.0E-03 4.3E-04 9.8E-03 7.2E-04 1,2,3,4,6,7,8,9 - OCDD 9.9E-04 9.1E-05 7.5E-04 3.6E-05 8.1E-04 3.0E-05 8.7E-04 1.0E-04 2,3,7,8 - TCDF 7.1E-01 4.3E-01 3.4E-01 1.4E-01 9.7E-02 5.8E-02 3.3E-01 2.4E-01 1,2,3,7,8- PeCDF 4.5E-02 2.4E-02 2.6E-02 7.8E-03 7.4E-03 4.7E-03 2.6E-02 1.7E-02 2,3,4,7,8- PeCDF 4.8E-01 2.9E-01 2.6E-01 7.4E-02 7.5E-02 4.7E-02 2.5E-01 1.7E-01 1,2,3,4,7,8- HxCDF 3.6E-02 9.2E-03 2.7E-02 8.4E-03 9.1E-03 3.0E-03 2.8E-02 1.2E-02 1,2,3,6,7,8- HxCDF 3.2E-02 1.1E-02 2.7E-02 5.4E-03 8.6E-03 3.0E-03 2.4E-02 1.0E-02 1,2,3,7,8,9- HxCDF 1.1E-02 1.0E-02 1.3E-02 5.5E-03 4.2E-03 1.9E-03 1.1E-02 4.2E-03 2,3,4,6,7,8 - HxCDF 2.7E-02 8.9E-03 2.4E-02 6.3E-03 8.6E-03 3.8E-03 2.1E-02 8.8E-03 1,2,3,4,6,7,8- HpCDF 3.2E-03 1.3E-04 2.6E-03 6.2E-04 1.5E-03 2.5E-04 2.8E-03 8.6E-04 1,2,3,4,7,8,9- HpCDF 3.9E-04 3.8E-04 7.4E-04 2.7E-04 2.5E-04 7.3E-05 6.4E-04 2.2E-04 1,2,3,4,6,7,8,9-OCDF 7.1E-05 7.2E-06 6.3E-05 1.4E-05 4.8E-05 9.1E-06 6.0E-05 2.3E-05 PCDD TEQ Total 4.6E-01 2.6E-01 1.8E-01 5.0E-02 9.1E-02 2.9E-02 1.8E-01 7.5E-02 PCDF TEQ Total 1.3E+00 7.9E-01 7.2E-01 2.4E-01 2.1E-01 1.2E-01 7.0E-01 4.6E-01 PCDD/PCDF TEQ Total 1.8E+00 1.0E+00 9.0E-01 2.9E-01 3.0E-01 1.4E-01 8.8E-01 5.3E-01 Table 3-12. PCDD/PCDF Total emission factors. 0 % New 32 % New 66 % New 100 % New Homologue Average STDV Average STDV Average STDV Average STDV ng/kg MRE TeCDD 2.1 0.75 0.95 0.30 0.70 0.14 1.8 0.78 PeCDD 0.96 0.13 0.64 0.18 0.37 0.12 0.92 0.48 HxCDD 1.1 0.16 0.83 0.11 0.64 0.10 0.95 0.23 HpCDD 2.1 0.095 1.5 0.080 1.5 0.095 1.7 0.12 OCDD 3.31 0.30 2.48 0.12 2.71 0.10 2.90 0.34 TeCDF 92 48 57 15 26 8.0 59 25 PeCDF 14 6.5 9.0 2.2 2.4 1.2 8.6 5.3 HxCDF 2.4 0.85 2.0 0.43 0.66 0.25 1.9 0.75 HpCDF 0.49 0.16 0.50 0.14 0.25 0.017 0.44 0.069 OCDF 0.25 0.042 0.22 0.032 0.16 0.030 0.22 0.083 PCDD Total 9.6 0.96 6.4 0.51 5.9 0.52 8.2 1.6 PCDF Total 109 56 69 17 29 9.3 70 31 PCDD/PCDF Total 118 56 75 18 35 9.3 78 32 31 ------- Q ^ a! Q LJ |jj u h- CL no c 3.50 3.00 2.50 2.00 1.50 1.00 0.50 0.00 100% NEW ซ 66% NEW 32% NEW 0% NEW R = 0.1921 _ 0.910 0.920 0.930 0.940 0.950 0.960 MCE 675 Figure 3-17. MRE PCDD/PCDF emission factors versus modified combustion efficiency (MCE). 4 Quality of Data and Data Limitations For PCDD/PCDF analyses all surrogate standard recoveries were between 63% and 110% for the fiberboard burn samples, which was within the standard method criteria (25-130%). Some of 680 the surrogate standard recoveries were outside the standard method criteria (25-130%) for the MRE burn samples due to interference from significant amounts of other compounds in the 13C channels causing a low response for the compound pre-analysis. For the PAHs all surrogate standard recoveries for method blanks and samples were between 48 and 110 percent, which was within the standard method criteria (25% and 130%). Two method blanks for the VOCs 685 returned all non-detects. All surrogate standard recoveries for method blanks and samples were between 95% and 107%, within the acceptance limits of the method (70-130%). Precision data on the XRF analyses for six elements had less than 3.5% error. The accuracy data on nine standard reference materials ranged from 90.7% to 106.8%. The precision for the gravimetric data is ฑ 10 |ag. The CO2 calibration error for all test days was between 0.001% and 0.559%, and 690 the system drift was between 0.015 % and 0.319 %, below the error and drift acceptance criteria of 5% and 3%, respectively, in U.S. EPA Method 3A [14]. CO calibration and post drift tests were performed each test day. The calibration error for all test days was between 0.01 % and 1.10 %, and the system drift was between 0.66% and 1.57%, below the error and drift acceptance criteria of 5% and 3%, respectively, in U.S. EPA Method 3A [14]. 695 As emission factors are often dependent on the type of material being burned and the method of burning, changes in composition and burn efficiency may change the emission factors determined herein. 32 ------- 5 Conclusions Emissions from open burning of four MRE waste compositions and four MRE fiberboard packaging 700 containers were quantified for a range of emission types. MRE food packaging included current and prospective packing material (a nanocomposite polymer). Fiberboard packaging containers for 12 MREs consisted of current and prospective container material (cardboard and polymer-coated for wet strength). All fiberboard packaging had low PCDD/PCDF emission factors, consistent with values for a range of 705 biomass types. The highest value, approximately three times higher than the other packaging types, was from the polymer-coated fiberboard packaging potentially due to minor changes in loss on drying, chloride, and sulfur content. A weak negative correlation with combustion efficiency was noted. PCDD/PCDF results from tests of four levels of old and new MRE packaging mixed in with the current fiberboard MRE containers increased levels up to six-fold from the containers alone. As well, emission 710 factors amongst the MRE compositions varied six-fold with no obvious relation to composition. Average PAH results from the fiberboard containers varied between 30 and 75 mg/kg fiberboard. Addition of the MRE compositions to the baseline fiberboard more than doubled these values. VOCs from burning fiberboard containers showed dominant benzene, acrolein, and toluene. The containers with the polymer coating had two of the highest VOC concentrations but this was related to 715 low MCE values; all of the VOC emission factors were negatively correlated with MCE and two polymer coated containers showed low VOC emissions at high MCE. Addition of MREs to the baseline packaging fiberboard showed little change in emission factors from those of the packaging alone. PM emissions were 90 % less than 1 pim for fiberboard tests and tended to follow the combustion process and release of CO and C02. Little distinction was noted between the PM emission factors for the 720 four packaging types; no obvious relationship with MCE was observed. Addition of MRE pouches to the baseline fiberboard significantly increased the PM emission factors - approximately five- to six-fold. In general, emissions tended to follow MCE - higher values of MCE associated with greater combustion efficiency led to lower emission factor values across all compositions tested. This suggests for this work that attention to promoting improved combustion, rather than efforts to alter waste composition, was a 725 more effective means of lowering emissions. 33 ------- 6 References I Ratto, J.A.; D'Souza, S.; Dagnon, K.; Sun, S.; Neidzwiecki, J.; Jeanne, L. Lightweight and compostable fiberboard for the military. Natick/TR-12/023. 2012. 730 2 Ratto, J., Lucciarini J., Wright, A., Niedzwiecki, J., Lee, C., Favreau, N; Altmeyer, R., U.S. Army Natick Soldier Research, Development and Engineering Center, Environmental Security Technology Certification Program Final Report, Nanotechnology for the Solid Waste Reduction of Military Food Packaging, WP-200816- February, 2015. https://serdp-estcp.org/Program- Areas/Weapons-Systems-and-Platforms/Waste-Reduction-and-Treatment-in-DoD- 735 Operations/WP-200816/WP-200816/(language)/eng-US. Accessed August 23, 2016. 3 Liu, D.H.F.; Liptak, B.G. 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Emission Factors for 780 PCDD/PCDF and dl-PCB from Open Burning of Biomass. Environ Int. 38:62-66; 2012 35 ------- 785 Appendices ------- 790 Appendix A: Data for each sample collected from Open Burning of Fiberboard. Table A-l. PCDD/PCDF data for CB/CL 1. PCDD/PCDF Page 1 (2) Sample ID PS-PCDD-CB-SVOC-111814-02 MCE 0.982 Sampling volume (m3) 76.5 Carbon sampled (g) 64.1 Carbon sampled (mg/m3) 837.4 Carbon fraction 0.46245 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 -TCDD 2.22E-04 2.22E-04 2.22E-04 2.90E-06 2.90E-06 2.90E-06 1,2,3,7,8 -PeCDD 2.00E-03 2.00E-03 2.00E-03 2.61 E-05 2.61 E-05 2.61 E-05 1,2,3,4,7,8 -HxCDD 1.78E-03 1.78E-04 1.78E-04 2.32E-05 2.32E-06 2.32E-06 1,2,3,6,7,8 -HxCDD 3.11E-03 3.11E-04 3.11E-04 4.07E-05 4.07E-06 4.07E-06 1,2,3,7,8,9-HxCDD 2.67E-03 2.67E-04 2.67E-04 3.49E-05 3.49E-06 3.49E-06 1,2,3,4,6,7,8- HpCDD 3.00E-02 3.00E-04 3.00E-04 3.92E-04 3.92E-06 3.92E-06 1,2,3,4,6,7,8,9 - OCDD 7.24E-02 2.17E-05 2.17E-05 9.47E-04 2.84E-07 2.84E-07 2,3,7,8 -TCDF 1.02E-02 1.02E-03 1.02E-03 1.34E-04 1.34E-05 1.34E-05 1,2,3,7,8-PeCDF 3.78E-03 1.13E-04 1.13E-04 4.94E-05 1.48E-06 1.48E-06 2,3,4,7,8 - PeCDF 6.22E-03 1.87E-03 1.87E-03 8.13E-05 2.44E-05 2.44E-05 1,2,3,4,7,8-HxCDF 6.67E-03 6.67E-04 6.67E-04 8.71 E-05 8.71 E-06 8.71 E-06 1,2,3,6,7,8-HxCDF 6.00E-03 6.00E-04 6.00E-04 7.84E-05 7.84E-06 7.84E-06 1,2,3,7,8,9-HxCDF 3.56E-03 3.56E-04 3.56E-04 4.65E-05 4.65E-06 4.65E-06 2,3,4,6,7,8 - HxCDF 1.13E-02 1.13E-03 1.13E-03 1.48E-04 1.48E-05 1.48E-05 1,2,3,4,6,7,8- HpCDF 3.16E-02 3.16E-04 3.16E-04 4.12E-04 4.12E-06 4.12E-06 1,2,3,4,7,8,9- HpCDF 4.89E-03 4.89E-05 4.89E-05 6.39E-05 6.39E-07 6.39E-07 1,2,3,4,6,7,8,9-OCDF 1.84E-02 5.53E-06 5.53E-06 2.41 E-04 7.23E-08 7.23E-08 TeCDD Total 4.51 E-02 5.90E-04 PeCDD Total 2.74E-02 3.58E-04 HxCDD Total 2.78E-02 3.63E-04 HpCDD Total 5.21 E-02 6.81 E-04 OCDD 7.24E-02 9.46E-04 TeCDF Total 1.58E-01 2.07E-03 PeCDF Total 6.39E-02 8.35E-04 HxCDF Total 6.50E-02 8.49E-04 HpCDF Total 5.87E-02 7.67E-04 OCDF 1.85E-02 2.41 E-04 PCDD Total 2.25E-01 2.94E-03 PCDF Total 3.64E-01 4.76E-03 PCDD/PCDF Total 5.89E-01 7.70E-03 PCDD TEQ Total 3.30E-03 3.30E-03 4.31 E-05 4.31 E-05 PCDF TEQ Total 6.13E-03 6.13E-03 8.01 E-05 8.01 E-05 PCDD/PCDF TEQ Total 9.43E-03 9.43E-03 1.23E-04 1.23E-04 1-A ------- Sample ID PS-PCDD-CB-SVOC-111814-02 Page 2 (2) EF EF EF EF EF EF Total TEQ TEQ Total TEQ TEQ Isomer. ng/g Carbon ng/kg fiberboard ND=0 ND=LOD ND=0 ND=LOD 2,3,7,8 - TCDD 3.47E-06 3.47E-06 3.47E-06 1.60E-03 1.60E-03 1.60E-03 1,2,3,7,8 - PeCDD 3.12E-05 3.12E-05 3.12E-05 1.44E-02 1.44E-02 1.44E-02 1,2,3,4,7,8 - HxCDD 2.77E-05 2.77E-06 2.77E-06 1.28E-02 1.28E-03 1.28E-03 1,2,3,6,7,8 - HxCDD 4.86E-05 4.86E-06 4.86E-06 2.25E-02 2.25E-03 2.25E-03 1,2,3,7,8,9 - HxCDD 4.16E-05 4.16E-06 4.16E-06 1.92E-02 1.92E-03 1.92E-03 1,2,3,4,6,7,8 - HpCDD 4.68E-04 4.68E-06 4.68E-06 2.17E-01 2.17E-03 2.17E-03 1,2,3,4,6,7,8,9 - OCDD 1.13E-03 3.39E-07 3.39E-07 5.23E-01 1.57E-04 1.57E-04 2,3,7,8 - TCDF 1.60E-04 1.60E-05 1.60E-05 7.38E-02 7.38E-03 7.38E-03 1,2,3,7,8 - PeCDF 5.90E-05 1.77E-06 1.77E-06 2.73E-02 8.18E-04 8.18E-04 2,3,4,7,8 - PeCDF 9.71 E-05 2.91 E-05 2.91 E-05 4.49E-02 1.35E-02 1.35E-02 1,2,3,4,7,8 - HxCDF 1.04E-04 1.04E-05 1.04E-05 4.81 E-02 4.81 E-03 4.81 E-03 1,2,3,6,7,8 - HxCDF 9.36E-05 9.36E-06 9.36E-06 4.33E-02 4.33E-03 4.33E-03 1,2,3,7,8,9 - HxCDF 5.55E-05 5.55E-06 5.55E-06 2.57E-02 2.57E-03 2.57E-03 2,3,4,6,7,8 - HxCDF 1.77E-04 1.77E-05 1.77E-05 8.18E-02 8.18E-03 8.18E-03 1,2,3,4,6,7,8 - HpCDF 4.92E-04 4.92E-06 4.92E-06 2.28E-01 2.28E-03 2.28E-03 1,2,3,4,7,8,9 - HpCDF 7.63E-05 7.63E-07 7.63E-07 3.53E-02 3.53E-04 3.53E-04 1,2,3,4,6,7,8,9 - OCDF 2.88E-04 8.64E-08 8.64E-08 1.33E-01 3.99E-05 3.99E-05 TeCDD Total 7.04E-04 3.26E-01 PeCDD Total 4.27E-04 1.97E-01 HxCDD Total 4.34E-04 2.00E-01 HpCDD Total 8.13E-04 3.76E-01 OCDD 1.13E-03 5.23E-01 TeCDF Total 2.47E-03 1.14E+00 PeCDF Total 9.97E-04 4.61 E-01 HxCDF Total 1.01 E-03 4.69E-01 HpCDF Total 9.16E-04 4.23E-01 OCDF 2.88E-04 1.33E-01 PCDD Total 3.51 E-03 1.62E+00 PCDF Total 5.69E-03 2.63E+00 PCDD/PCDF Total 9.20E-03 4.25E+00 PCDD TEQ Total 5.15E-05 5.15E-05 2.38E-02 2.38E-02 PCDF TEQ Total 9.56E-05 9.56E-05 4.42E-02 4.42E-02 PCDD/PCDF TEQ Total 1.47E-04 1.47E-04 6.80E-02 6.80E-02 2-A ------- Table A-2. PCDD/PCDF data for CB/CL 2. Page 1 (2) PCDD/PCDF Sample ID PS-PCDD-CB2-SVOC-111914-02 MCE 0.984 Sampling volume (m3) 62.8 Carbon sampled (g) 73.1 Carbon sampled (mg/m3) 1164.9 Carbon fraction 0.4625 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 4.44E-04 4.44E-04 4.44E-04 7.08E-06 7.08E-06 7.08E-06 1,2,3,7,8- PeCDD 1.11E-03 1.11E-03 1.11E-03 1.77E-05 1.77E-05 1.77E-05 1,2,3,4,7,8- HxCDD 6.67E-04 6.67E-05 6.67E-05 1.06E-05 1.06E-06 1.06E-06 1,2,3,6,7,8- HxCDD 1.78E-03 1.78E-04 1.78E-04 2.83E-05 2.83E-06 2.83E-06 1,2,3,7,8,9- HxCDD 1.78E-03 1.78E-04 1.78E-04 2.83E-05 2.83E-06 2.83E-06 1,2,3,4,6,7,8- HpCDD 2.22E-02 2.22E-04 2.22E-04 3.54E-04 3.54E-06 3.54E-06 1,2,3,4,6,7,8,9 - OCDD 5.96E-02 1.79E-05 1.79E-05 9.49E-04 2.85E-07 2.85E-07 2,3,7,8 - TCDF 1.00E-02 1.00E-03 1.00E-03 1.59E-04 1.59E-05 1.59E-05 1,2,3,7,8- PeCDF 3.33E-03 1.00E-04 1.00E-04 5.31 E-05 1.59E-06 1.59E-06 2,3,4,7,8- PeCDF 3.11E-03 9.33E-04 9.33E-04 4.96E-05 1.49E-05 1.49E-05 1,2,3,4,7,8- HxCDF 2.22E-03 2.22E-04 2.22E-04 3.54E-05 3.54E-06 3.54E-06 1,2,3,6,7,8- HxCDF 1.56E-03 1.56E-04 1.56E-04 2.48E-05 2.48E-06 2.48E-06 1,2,3,7,8,9- HxCDF 6.67E-04 6.67E-05 6.67E-05 1.06E-05 1.06E-06 1.06E-06 2,3,4,6,7,8 - HxCDF 2.22E-03 2.22E-04 2.22E-04 3.54E-05 3.54E-06 3.54E-06 1,2,3,4,6,7,8- HpCDF 5.11E-03 5.11E-05 5.11E-05 8.14E-05 8.14E-07 8.14E-07 1,2,3,4,7,8,9- HpCDF 6.67E-04 6.67E-06 6.67E-06 1.06E-05 1.06E-07 1.06E-07 1,2,3,4,6,7,8,9-OCDF 6.00E-03 1.80E-06 1.80E-06 9.56E-05 2.87E-08 2.87E-08 TeCDD Total 4.00E-02 6.37E-04 PeCDD Total 1.93E-02 3.07E-04 HxCDD Total 2.10E-02 3.34E-04 HpCDD Total 3.63E-02 5.79E-04 OCDD 5.96E-02 9.50E-04 TeCDF Total 1.29E-01 2.06E-03 PeCDF Total 3.96E-02 6.31 E-04 HxCDF Total 1.38E-02 2.20E-04 HpCDF Total 1.14E-02 1.82E-04 OCDF 6.04E-03 9.63E-05 PCDD Total 1.76E-01 2.81 E-03 PCDF Total 2.00E-01 3.19E-03 PCDD/PCDF Total 3.76E-01 6.00E-03 PCDD TEQ Total 2.22E-03 2.22E-03 3.53E-05 3.53E-05 PCDF TEQ Total 2.76E-03 2.76E-03 4.40 E-05 4.40E-05 PCDD/PCDF TEQ Total 4.98E-03 4.98E-03 7.93E-05 7.93E-05 ------- 795 Sample ID PS-PCDD-CB2-SV0C-111914-02 Page 2 (2) EF EF EF EF EF EF Total TEQ TEQ Total TEQ TEQ Isomer. ng/g Carbon ng/kg fiberboard ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8-TCDD 6.08E-06 6.08E-06 6.08E-06 2.81 E-03 2.81 E-03 2.81 E-03 1,2,3,7,8 -PeCDD 1.52E-05 1.52E-05 1.52E-05 7.03E-03 7.03E-03 7.03E-03 1,2,3,4,7,8-HxCDD 9.12E-06 9.12E-07 9.12E-07 4.22E-03 4.22E-04 4.22E-04 1,2,3,6,7,8 -HxCDD 2.43E-05 2.43E-06 2.43E-06 1.12E-02 1.12E-03 1.12E-03 1,2,3,7,8,9-HxCDD 2.43E-05 2.43E-06 2.43E-06 1.12E-02 1.12E-03 1.12E-03 1,2,3,4,6,7,8- HpCDD 3.04E-04 3.04E-06 3.04E-06 1.41 E-01 1.41 E-03 1.41 E-03 1,2,3,4,6,7,8,9 - OCDD 8.15E-04 2.44E-07 2.44E-07 3.77E-01 1.13E-04 1.13E-04 2,3,7,8 -TCDF 1.37E-04 1.37E-05 1.37E-05 6.32E-02 6.32E-03 6.32E-03 1,2,3,7,8-PeCDF 4.56E-05 1.37E-06 1.37E-06 2.11E-02 6.32E-04 6.32E-04 2,3,4,7,8 - PeCDF 4.26E-05 1.28E-05 1.28E-05 1.97E-02 5.90E-03 5.90E-03 1,2,3,4,7,8-HxCDF 3.04E-05 3.04E-06 3.04E-06 1.41 E-02 1.41 E-03 1.41 E-03 1,2,3,6,7,8-HxCDF 2.13E-05 2.13E-06 2.13E-06 9.84E-03 9.84E-04 9.84E-04 1,2,3,7,8,9-HxCDF 9.12E-06 9.12E-07 9.12E-07 4.22E-03 4.22E-04 4.22E-04 2,3,4,6,7,8 - HxCDF 3.04E-05 3.04E-06 3.04E-06 1.41 E-02 1.41 E-03 1.41 E-03 1,2,3,4,6,7,8- HpCDF 6.99E-05 6.99E-07 6.99E-07 3.23E-02 3.23E-04 3.23E-04 1,2,3,4,7,8,9- HpCDF 9.12E-06 9.12E-08 9.12E-08 4.22E-03 4.22E-05 4.22E-05 1,2,3,4,6,7,8,9-OCDF 8.21 E-05 2.46E-08 2.46E-08 3.79E-02 1.14E-05 1.14E-05 TeCDD Total 5.46E-04 2.53E-01 PeCDD Total 2.64E-04 1.22E-01 HxCDD Total 2.87E-04 1.33E-01 HpCDD Total 4.97E-04 2.30E-01 OCDD 8.15E-04 3.77E-01 TeCDF Total 1.77E-03 8.18E-01 PeCDF Total 5.42E-04 2.51 E-01 HxCDF Total 1.89E-04 8.74E-02 HpCDF Total 1.57E-04 7.24E-02 OCDF 8.27E-05 3.82E-02 PCDD Total 2.41 E-03 1.11 E+00 PCDF Total 2.74E-03 1.27E+00 PCDD/PCDF Total 5.15E-03 2.38E+00 PCDD TEQ Total 3.03E-05 3.03E-05 1.40E-02 1.40E-02 PCDF TEQ Total 3.77E-05 3.77E-05 1.75E-02 1.75E-02 PCDD/PCDF TEQ Total 6.81 E-05 6.81 E-05 3.15E-02 3.15E-02 4-A ------- Table A-3. PCDD/PCDF data for CB/CL 3. PCDD/PCDF Page 1 (2) Sample ID PS-PCDD-CB3-SV0C-112014-02 MCE 0.985 Sampling volume (m3) 60.5 Carbon sampled (g) 65.0 Carbon sampled (mg/m3) 1074.5 Carbon fraction 0.4625 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8-TCDD 4.44E-04 4.44E-04 4.44E-04 7.34E-06 7.34E-06 7.34E-06 1,2,3,7,8- PeCDD 2.00E-03 2.00E-03 2.00E-03 3.30E-05 3.30E-05 3.30E-05 1,2,3,4,7,8- HxCDD 8.89E-04 8.89E-05 8.89E-05 1.47E-05 1.47E-06 1.47E-06 1,2,3,6,7,8- HxCDD 2.22E-03 2.22E-04 2.22E-04 3.67E-05 3.67E-06 3.67E-06 1,2,3,7,8,9- HxCDD 1.78E-03 1.78E-04 1.78E-04 2.94E-05 2.94E-06 2.94E-06 1,2,3,4,6,7,8- HpCDD 1.93E-02 1.93E-04 1.93E-04 3.19E-04 3.19E-06 3.19E-06 1,2,3,4,6,7,8,9 - OCDD 5.82E-02 1.75E-05 1.75E-05 9.62E-04 2.89E-07 2.89E-07 2,3,7,8 - TCDF 1.02E-02 1.02E-03 1.02E-03 1.69E-04 1.69E-05 1.69E-05 1,2,3,7,8- PeCDF 3.78E-03 1.13E-04 1.13E-04 6.24E-05 1.87E-06 1.87E-06 2,3,4,7,8- PeCDF 4.44E-03 1.33E-03 1.33E-03 7.34E-05 2.20E-05 2.20E-05 1,2,3,4,7,8- HxCDF 3.33E-03 3.33E-04 3.33E-04 5.51 E-05 5.51 E-06 5.51 E-06 1,2,3,6,7,8- HxCDF 2.67E-03 2.67E-04 2.67E-04 4.41 E-05 4.41 E-06 4.41 E-06 1,2,3,7,8,9- HxCDF 1.11E-03 1.11E-04 1.11E-04 1.84E-05 1.84E-06 1.84E-06 2,3,4,6,7,8 - HxCDF 2.89E-03 2.89E-04 2.89E-04 4.77E-05 4.77E-06 4.77E-06 1,2,3,4,6,7,8- HpCDF 6.67E-03 6.67E-05 6.67E-05 1.10E-04 1.10E-06 1.10E-06 1,2,3,4,7,8,9- HpCDF 8.89E-04 8.89E-06 8.89E-06 1.47E-05 1.47E-07 1.47E-07 1,2,3,4,6,7,8,9-OCDF 7.11E-03 2.13E-06 2.13E-06 1.17E-04 3.52E-08 3.52E-08 TeCDD Total 5.61 E-02 9.27E-04 PeCDD Total 3.18E-02 5.25E-04 HxCDD Total 2.64E-02 4.36E-04 HpCDD Total 3.58E-02 5.92E-04 OCDD 5.81 E-02 9.60E-04 TeCDF Total 1.57E-01 2.59E-03 PeCDF Total 6.09E-02 1.01E-03 HxCDF Total 2.64E-02 4.37E-04 HpCDF Total 1.39E-02 2.29E-04 OCDF 7.00E-03 1.16E-04 PCDD Total 2.08E-01 3.44E-03 PCDF Total 2.65E-01 4.38E-03 PCDD/PCDF Total 4.73E-01 7.82E-03 PCDD TEQ Total 3.14E-03 3.14E-03 5.19E-05 5.19E-05 PCDF TEQ Total 3.55E-03 3.55E-03 5.86E-05 5.86E-05 PCDD/PCDF TEQ Total 6.69E-03 6.69E-03 1.11E-04 1.11E-04 5-A ------- Sample ID PS-PCDD-CB3-SV0C-112014-02 Page 2 (2) EF EF EF EF EF EF Total TEQ TEQ Total TEQ TEQ Isomer. ng/g Carbon ng/g Carbon ng/g Carbon ng/kg fiberboard ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8-TCDD 6.83E-06 6.83E-06 6.83E-06 3.16E-03 3.16E-03 3.16E-03 1,2,3,7,8-PeCDD 3.08E-05 3.08E-05 3.08E-05 1.42E-02 1.42E-02 1.42E-02 1,2,3,4,7,8-HxCDD 1.37E-05 1.37E-06 1.37E-06 6.32E-03 6.32E-04 6.32E-04 1,2,3,6,7,8 -HxCDD 3.42E-05 3.42E-06 3.42E-06 1.58E-02 1.58E-03 1.58E-03 1,2,3,7,8,9-HxCDD 2.73E-05 2.73E-06 2.73E-06 1.26E-02 1.26E-03 1.26E-03 1,2,3,4,6,7,8- HpCDD 2.97E-04 2.97E-06 2.97E-06 1.37E-01 1.37E-03 1.37E-03 1,2,3,4,6,7,8,9 - OCDD 8.95E-04 2.69E-07 2.69E-07 4.14E-01 1.24E-04 1.24E-04 2,3,7,8 -TCDF 1.57E-04 1.57E-05 1.57E-05 7.27E-02 7.27E-03 7.27E-03 1,2,3,7,8-PeCDF 5.81 E-05 1.74E-06 1.74E-06 2.69E-02 8.06E-04 8.06E-04 2,3,4,7,8 - PeCDF 6.83E-05 2.05E-05 2.05E-05 3.16E-02 9.48E-03 9.48E-03 1,2,3,4,7,8-HxCDF 5.13E-05 5.13E-06 5.13E-06 2.37E-02 2.37E-03 2.37E-03 1,2,3,6,7,8-HxCDF 4.10E-05 4.10E-06 4.10E-06 1.90E-02 1.90E-03 1.90E-03 1,2,3,7,8,9-HxCDF 1.71 E-05 1.71E-06 1.71 E-06 7.90E-03 7.90E-04 7.90E-04 2,3,4,6,7,8 - HxCDF 4.44E-05 4.44E-06 4.44E-06 2.05E-02 2.05E-03 2.05E-03 1,2,3,4,6,7,8- HpCDF 1.03E-04 1.03E-06 1.03E-06 4.74E-02 4.74E-04 4.74E-04 1,2,3,4,7,8,9- HpCDF 1.37E-05 1.37E-07 1.37E-07 6.32E-03 6.32E-05 6.32E-05 1,2,3,4,6,7,8,9-OCDF 1.09E-04 3.28E-08 3.28E-08 5.06E-02 1.52E-05 1.52E-05 TeCDD Total 8.63E-04 3.99E-01 PeCDD Total 4.89E-04 2.26E-01 HxCDD Total 4.06E-04 1.88E-01 HpCDD Total 5.51 E-04 2.55E-01 OCDD 8.94E-04 4.13E-01 TeCDF Total 2.41 E-03 1.12E+00 PeCDF Total 9.36E-04 4.33E-01 HxCDF Total 4.06E-04 1.88E-01 HpCDF Total 2.13E-04 9.86E-02 OCDF 1.08E-04 4.98E-02 PCDD Total 3.20E-03 1.48E+00 PCDF Total 4.08E-03 1.88E+00 PCDD/PCDF Total 7.28E-03 3.37E+00 PCDD TEQ Total 4.83E-05 4.83E-05 2.24E-02 2.24E-02 PCDF TEQ Total 5.45E-05 5.45E-05 2.52E-02 2.52E-02 PCDD/PCDF TEQ Total 1.03E-04 1.03E-04 4.76E-02 4.76E-02 Table A-4. PCDD/PCDF data for CB/CL 4. 6-A ------- PCDD/PCDF Page 1 (2) Sample ID PS-PCDD-CB4-SV0C-112114-01 MCE 0.986 Sampling volume (m3) 60.5 Carbon sampled (g) 70.9 Carbon sampled (mg/m3) 1172.0 Carbon fraction 0.4625 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 -TCDD ND 7.56E-04 0.00E+00 7.56E-04 ND 0.00E+00 1.25E-05 1,2,3,7,8 -PeCDD 1.56E-03 1.56E-03 1.56E-03 2.57E-05 2.57E-05 2.57E-05 1,2,3,4,7,8 -HxCDD 1.11E-03 1.11E-04 1.11E-04 1.84E-05 1.84E-06 1.84E-06 1,2,3,6,7,8 -HxCDD 2.44E-03 2.44E-04 2.44E-04 4.04E-05 4.04E-06 4.04E-06 1,2,3,7,8,9-HxCDD 1.33E-03 1.33E-04 1.33E-04 2.20E-05 2.20E-06 2.20E-06 1,2,3,4,6,7,8- HpCDD 2.18E-02 2.18E-04 2.18E-04 3.60E-04 3.60E-06 3.60E-06 1,2,3,4,6,7,8,9 - OCDD 6.13E-02 1.84E-05 1.84E-05 1.01E-03 3.04E-07 3.04E-07 2,3,7,8 -TCDF 7.78E-03 7.78E-04 7.78E-04 1.29E-04 1.29E-05 1.29E-05 1,2,3,7,8-PeCDF 3.78E-03 1.13E-04 1.13E-04 6.24E-05 1.87E-06 1.87E-06 2,3,4,7,8 - PeCDF 3.78E-03 1.13E-03 1.13E-03 6.24E-05 1.87E-05 1.87E-05 1,2,3,4,7,8-HxCDF 3.11E-03 3.11E-04 3.11E-04 5.14E-05 5.14E-06 5.14E-06 1,2,3,6,7,8- HxCDF 3.11E-03 3.11E-04 3.11E-04 5.14E-05 5.14E-06 5.14E-06 1,2,3,7,8,9-HxCDF 1.33E-03 1.33E-04 1.33E-04 2.20E-05 2.20E-06 2.20E-06 2,3,4,6,7,8 - HxCDF 3.56E-03 3.56E-04 3.56E-04 5.88E-05 5.88E-06 5.88E-06 1,2,3,4,6,7,8- HpCDF 7.78E-03 7.78E-05 7.78E-05 1.29E-04 1.29E-06 1.29E-06 1,2,3,4,7,8,9- HpCDF ND 9.11E-04 0.00E+00 9.11E-06 ND 0.00E+00 1.51E-07 1,2,3,4,6,7,8,9-OCDF 8.67E-03 2.60E-06 2.60E-06 1.43E-04 4.30E-08 4.30E-08 TeCDD Total 4.63E-02 7.65E-04 PeCDD Total 3.15E-02 5.21 E-04 HxCDD Total 2.46E-02 4.07E-04 HpCDD Total 3.87E-02 6.40E-04 OCDD 6.14E-02 1.01 E-03 TeCDF Total 1.22E-01 2.02E-03 PeCDF Total 5.53E-02 9.13E-04 HxCDF Total 2.65E-02 4.37E-04 HpCDF Total 1.36E-02 2.24E-04 OCDF 8.56E-03 1.41 E-04 PCDD Total 2.03E-01 3.35E-03 PCDF Total 2.26E-01 3.74E-03 PCDD/PCDF Total 4.29E-01 7.09E-03 PCDD TEQ Total 2.28E-03 3.04E-03 3.77E-05 5.02E-05 PCDF TEQ Total 3.22E-03 3.23E-03 5.31 E-05 5.33E-05 PCDD/PCDF TEQ Total 5.50E-03 6.26E-03 9.08E-05 1.03E-04 7-A ------- Sample ID PS-PCDD-CB4-SV0C-112114-01 Page 2 (2) EF EF EF EF EF EF Total TEQ TEQ Total TEQ TEQ Isomer. ng/g Carbon ng/kg fiberboard ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD ND 0.00E+00 1.07E-05 ND 0.00E+00 4.93E-03 1,2,3,7,8- PeCDD 2.19E-05 2.19E-05 2.19E-05 1.01E-02 1.01 E-02 1.01 E-02 1,2,3,4,7,8- HxCDD 1.57E-05 1.57E-06 1.57E-06 7.25E-03 7.25E-04 7.25E-04 1,2,3,6,7,8- HxCDD 3.45E-05 3.45E-06 3.45E-06 1.59E-02 1.59E-03 1.59E-03 1,2,3,7,8,9- HxCDD 1.88E-05 1.88E-06 1.88E-06 8.69E-03 8.69E-04 8.69E-04 1,2,3,4,6,7,8- HpCDD 3.07E-04 3.07E-06 3.07E-06 1.42E-01 1.42E-03 1.42E-03 1,2,3,4,6,7,8,9 - OCDD 8.65E-04 2.59E-07 2.59E-07 4.00E-01 1.20E-04 1.20E-04 2,3,7,8 - TCDF 1.10E-04 1.10E-05 1.10E-05 5.07E-02 5.07E-03 5.07E-03 1,2,3,7,8- PeCDF 5.33E-05 1.60E-06 1.60E-06 2.46E-02 7.39E-04 7.39E-04 2,3,4,7,8- PeCDF 5.33E-05 1.60E-05 1.60E-05 2.46E-02 7.39E-03 7.39E-03 1,2,3,4,7,8- HxCDF 4.39E-05 4.39E-06 4.39E-06 2.03E-02 2.03E-03 2.03E-03 1,2,3,6,7,8- HxCDF 4.39E-05 4.39E-06 4.39E-06 2.03E-02 2.03E-03 2.03E-03 1,2,3,7,8,9- HxCDF 1.88E-05 1.88E-06 1.88E-06 8.69E-03 8.69E-04 8.69E-04 2,3,4,6,7,8 - HxCDF 5.01 E-05 5.01 E-06 5.01 E-06 2.32E-02 2.32E-03 2.32E-03 1,2,3,4,6,7,8- HpCDF 1.10E-04 1.10E-06 1.10E-06 5.07E-02 5.07E-04 5.07E-04 1,2,3,4,7,8,9- HpCDF ND 0.00E+00 1.28E-07 ND 0.00E+00 5.94E-05 1,2,3,4,6,7,8,9-OCDF 1.22E-04 3.67E-08 3.67E-08 5.65E-02 1.70E-05 1.70E-05 TeCDD Total 6.53E-04 3.02E-01 PeCDD Total 4.45E-04 2.06E-01 HxCDD Total 3.47E-04 1.61E-01 HpCDD Total 5.46E-04 2.52E-01 OCDD 8.66E-04 4.00E-01 TeCDF Total 1.73E-03 7.98E-01 PeCDF Total 7.79E-04 3.60E-01 HxCDF Total 3.73E-04 1.73E-01 HpCDF Total 1.91 E-04 8.84E-02 OCDF 1.21 E-04 5.58E-02 PCDD Total 2.86E-03 1.32E+00 PCDF Total 3.19E-03 1.47E+00 PCDD/PCDF Total 6.05E-03 2.80E+00 PCDD TEQ Total 3.22E-05 4.28E-05 1.49E-02 1.98E-02 PCDF TEQ Total 4.53E-05 4.55E-05 2.10E-02 2.10E-02 PCDD/PCDF TEQ Total 7.75E-05 8.83E-05 3.58E-02 4.08E-02 800 Table A-5. PCDD/PCDF data for NSB/NSL 1. 8-A ------- PCDD/PCDF Page 1 (2) Sample ID PS-PCDD-NSB-SVOC-111914-02 MCE 0.984 Sampling volume (m3) 45.3 Carbon sampled (g) 65.2 Carbon sampled (mg/m3) 1438.8 Carbon fraction 0.4561 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ng/sample ND =0 ND = LOD ND = 0 ND = LOD 2,3,7,8-TCDD ND 2.58E-03 0.00E+00 2.58E-03 ND 0.00E+00 5.69E-05 1,2,3,7,8-PeCDD ND 5.18E-03 0.00E+00 5.18E-03 ND 0.00E+00 1.14E-04 1,2,3,4,7,8 -HxCDD ND 4.29E-03 0.00E+00 4.29E-04 ND 0.00E+00 9.46E-06 1,2,3,6,7,8 -HxCDD 8.67E-03 8.67E-04 8.67E-04 1.91E-04 1.91 E-05 1.91 E-05 1,2,3,7,8,9-HxCDD 6.44E-03 6.44E-04 6.44E-04 1.42E-04 1.42E-05 1.42E-05 1,2,3,4,6,7,8- HpCDD 1.20E-01 1.20E-03 1.20E-03 2.64E-03 2.64E-05 2.64E-05 1,2,3,4,6,7,8,9 - OCDD 3.96E-01 1.19E-04 1.19E-04 8.74E-03 2.62E-06 2.62E-06 2,3,7,8 -TCDF 1.20E-02 1.20E-03 1.20E-03 2.65E-04 2.65E-05 2.65E-05 1,2,3,7,8-PeCDF ND 5.07E-03 0.00E+00 1.52E-04 ND 0.00E+00 3.35E-06 2,3,4,7,8 - PeCDF ND 4.82E-03 0.00E+00 1.45E-03 ND 0.00E+00 3.19E-05 1,2,3,4,7,8-HxCDF 4.67E-03 4.67E-04 4.67E-04 1.03E-04 1.03E-05 1.03E-05 1,2,3,6,7,8-HxCDF 4.22E-03 4.22E-04 4.22E-04 9.31 E-05 9.31 E-06 9.31 E-06 1,2,3,7,8,9-HxCDF ND 4.36E-03 0.00E+00 4.36E-04 ND 0.00E+00 9.61 E-06 2,3,4,6,7,8 - HxCDF ND 4.84E-03 0.00E+00 4.84E-04 ND 0.00E+00 1.07E-05 1,2,3,4,6,7,8- HpCDF 1.09E-02 1.09E-04 1.09E-04 2.40E-04 2.40E-06 2.40E-06 1,2,3,4,7,8,9- HpCDF ND 4.62E-03 0.00E+00 4.62E-05 ND 0.00E+00 1.02E-06 1,2,3,4,6,7,8,9-OCDF 1.47E-02 4.40E-06 4.40E-06 3.24E-04 9.71 E-08 9.71 E-08 TeCDD Total 3.07E-02 6.77E-04 PeCDD Total 1.14E-02 2.51 E-04 HxCDD Total 4.62E-02 1.02E-03 HpCDD Total 1.87E-01 4.12E-03 OCDD 3.96E-01 8.75E-03 TeCDF Total 1.08E-01 2.39E-03 PeCDF Total 1.63E-02 3.60E-04 HxCDF Total 1.81E-02 3.99E-04 HpCDF Total 2.65E-02 5.84E-04 OCDF 1.63E-02 3.60E-04 PCDD Total 6.72E-01 1.48E-02 PCDF Total 1.86E-01 4.10E-03 PCDD/PCDF Total 8.57E-01 1.89E-02 PCDD TEQ Total 2.83E-03 1.10E-02 6.24E-05 2.43E-04 PCDF TEQ Total 2.20E-03 4.77E-03 4.86E-05 1.05E-04 PCDD/PCDF TEQ Total 5.03E-03 1.58E-02 1.11 E-04 3.48E-04 Sample ID PS-PCDD-NSB-SVOC-111914-02 Page 2 (2) 9-A ------- EF EF EF EF EF EF Total TEQ TEQ Total TEQ TEQ Isomer. ng/g Carbon ng/kg fiberboard ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD ND 0.00E+00 3.95E-05 ND 0.00E+00 1.80E-02 1,2,3,7,8- PeCDD ND 0.00E+00 7.94E-05 ND 0.00E+00 3.62E-02 1,2,3,4,7,8- HxCDD ND 0.00E+00 6.58E-06 ND 0.00E+00 3.00E-03 1,2,3,6,7,8- HxCDD 1.33E-04 1.33E-05 1.33E-05 6.06E-02 6.06E-03 6.06E-03 1,2,3,7,8,9- HxCDD 9.88E-05 9.88E-06 9.88E-06 4.51 E-02 4.51 E-03 4.51 E-03 1,2,3,4,6,7,8- HpCDD 1.84E-03 1.84E-05 1.84E-05 8.37E-01 8.37E-03 8.37E-03 1,2,3,4,6,7,8,9 - OCDD 6.08E-03 1.82E-06 1.82E-06 2.77E+00 8.32E-04 8.32E-04 2,3,7,8 - TCDF 1.84E-04 1.84E-05 1.84E-05 8.39E-02 8.39E-03 8.39E-03 1,2,3,7,8- PeCDF ND 0.00E+00 2.33E-06 ND 0.00E+00 1.06E-03 2,3,4,7,8- PeCDF ND 0.00E+00 2.22E-05 ND 0.00E+00 1.01 E-02 1,2,3,4,7,8- HxCDF 7.15E-05 7.15E-06 7.15E-06 3.26E-02 3.26E-03 3.26E-03 1,2,3,6,7,8- HxCDF 6.47E-05 6.47E-06 6.47E-06 2.95E-02 2.95E-03 2.95E-03 1,2,3,7,8,9- HxCDF ND 0.00E+00 6.68E-06 ND 0.00E+00 3.05E-03 2,3,4,6,7,8 - HxCDF ND 0.00E+00 7.43E-06 ND 0.00E+00 3.39E-03 1,2,3,4,6,7,8- HpCDF 1.67E-04 1.67E-06 1.67E-06 7.61 E-02 7.61 E-04 7.61 E-04 1,2,3,4,7,8,9- HpCDF ND 0.00E+00 7.09E-07 ND 0.00E+00 3.23E-04 1,2,3,4,6,7,8,9-OCDF 2.25E-04 6.75E-08 6.75E-08 1.03E-01 3.08E-05 3.08E-05 TeCDD Total 4.71 E-04 2.15E-01 PeCDD Total 1.75E-04 7.97E-02 HxCDD Total 7.08E-04 3.23E-01 HpCDD Total 2.86E-03 1.31E+00 OCDD 6.08E-03 2.77E+00 TeCDF Total 1.66E-03 7.58E-01 PeCDF Total 2.50E-04 1.14E-01 HxCDF Total 2.77E-04 1.26E-01 HpCDF Total 4.06E-04 1.85E-01 OCDF 2.50E-04 1.14E-01 PCDD Total 1.03E-02 4.70E+00 PCDF Total 2.85E-03 1.30E+00 PCDD/PCDF Total 1.31 E-02 5.99E+00 PCDD TEQ Total 4.34E-05 1.69E-04 1.98E-02 7.70E-02 PCDF TEQ Total 3.38E-05 7.31 E-05 1.54E-02 3.33E-02 PCDD/PCDF TEQ Total 7.71 E-05 2.42E-04 3.52E-02 1.10E-01 Table A-6. PCDD/PCDF data for NSB/NSL 2. PCDD/PCDF Page 1 (2) 10-A ------- Sample ID PS-PCDD-NSB2-SVOC-121114-01 MCE 0.971 Sampling volume (m3) 95.0 Carbon sampled (g) 75.2 Carbon sampled (mg/m3) 791.8 Carbon fraction 0.45605 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 -TCDD 2.44E-03 2.44E-03 2.44E-03 2.57E-05 2.57E-05 2.57E-05 1,2,3,7,8- PeCDD 1.27E-02 1.27E-02 1.27E-02 1.33E-04 1.33E-04 1.33E-04 1,2,3,4,7,8 -HxCDD 6.22E-03 6.22E-04 6.22E-04 6.55E-05 6.55E-06 6.55E-06 1,2,3,6,7,8 -HxCDD 2.33E-02 2.33E-03 2.33E-03 2.46E-04 2.46E-05 2.46E-05 1,2,3,7,8,9-HxCDD 1.71E-02 1.71E-03 1.71 E-03 1.80E-04 1.80E-05 1.80E-05 1,2,3,4,6,7,8- HpCDD 2.88E-01 2.88E-03 2.88E-03 3.04E-03 3.04E-05 3.04E-05 1,2,3,4,6,7,8,9 - OCDD 7.55E-01 2.26E-04 2.26E-04 7.94E-03 2.38E-06 2.38E-06 2,3,7,8 -TCDF 1.18E-02 1.18E-03 1.18E-03 1.24E-04 1.24E-05 1.24E-05 1,2,3,7,8-PeCDF 4.00E-03 1.20E-04 1.20E-04 4.21 E-05 1.26E-06 1.26E-06 2,3,4,7,8 - PeCDF 6.22E-03 1.87E-03 1.87E-03 6.55E-05 1.96E-05 1.96E-05 1,2,3,4,7,8-HxCDF 4.44E-03 4.44E-04 4.44E-04 4.68E-05 4.68E-06 4.68E-06 1,2,3,6,7,8-HxCDF 3.33E-03 3.33E-04 3.33E-04 3.51 E-05 3.51 E-06 3.51 E-06 1,2,3,7,8,9-HxCDF 1.33E-03 1.33E-04 1.33E-04 1.40E-05 1.40E-06 1.40E-06 2,3,4,6,7,8 - HxCDF 4.44E-03 4.44E-04 4.44E-04 4.68E-05 4.68E-06 4.68E-06 1,2,3,4,6,7,8- HpCDF 1.27E-02 1.27E-04 1.27E-04 1.33E-04 1.33E-06 1.33E-06 1,2,3,4,7,8,9- HpCDF 2.67E-03 2.67E-05 2.67E-05 2.81 E-05 2.81 E-07 2.81 E-07 1,2,3,4,6,7,8,9-OCDF 1.53E-02 4.60E-06 4.60E-06 1.61 E-04 4.84E-08 4.84E-08 TeCDD Total 8.09E-02 8.51 E-04 PeCDD Total 7.56E-02 7.96E-04 HxCDD Total 1.73E-01 1.82E-03 HpCDD Total 4.65E-01 4.90E-03 OCDD 7.55E-01 7.94E-03 TeCDF Total 1.58E-01 1.67E-03 PeCDF Total 5.80E-02 6.10E-04 HxCDF Total 3.45E-02 3.63E-04 HpCDF Total 3.34E-02 3.51 E-04 OCDF 1.52E-02 1.60E-04 PCDD Total 1.55E+00 1.63E-02 PCDF Total 2.99E-01 3.15E-03 PCDD/PCDF Total 1.85E+00 1.95E-02 PCDD TEQ Total 2.29E-02 2.29E-02 2.41 E-04 2.41 E-04 PCDF TEQ Total 4.68E-03 4.68E-03 4.92E-05 4.92E-05 PCDD/PCDF TEQ Total 2.76E-02 2.76E-02 2.90E-04 2.90E-04 Sam pie ID PS-PCDD-NSB2-SVOC-121114-01 Page 2(2) 11-A ------- EF EF EF EF EF EF Total TEQ TEQ Total TEQ TEQ Isomer. ng/g Carbon ng/kg fiberboard ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 3.25E-05 3.25E-05 3.25E-05 1.48E-02 1.48E-02 1.48E-02 1,2,3,7,8- PeCDD 1.68E-04 1.68E-04 1.68E-04 7.68E-02 7.68E-02 7.68E-02 1,2,3,4,7,8- HxCDD 8.27E-05 8.27E-06 8.27E-06 3.77E-02 3.77E-03 3.77E-03 1,2,3,6,7,8- HxCDD 3.10E-04 3.10E-05 3.10E-05 1.41 E-01 1.41 E-02 1.41 E-02 1,2,3,7,8,9- HxCDD 2.27E-04 2.27E-05 2.27E-05 1.04E-01 1.04E-02 1.04E-02 1,2,3,4,6,7,8- HpCDD 3.83E-03 3.83E-05 3.83E-05 1.75E+00 1.75E-02 1.75E-02 1,2,3,4,6,7,8,9 - OCDD 1.00E-02 3.01 E-06 3.01 E-06 4.57E+00 1.37E-03 1.37E-03 2,3,7,8 - TCDF 1.57E-04 1.57E-05 1.57E-05 7.14E-02 7.14E-03 7.14E-03 1,2,3,7,8- PeCDF 5.32E-05 1.59E-06 1.59E-06 2.42E-02 7.27E-04 7.27E-04 2,3,4,7,8- PeCDF 8.27E-05 2.48E-05 2.48E-05 3.77E-02 1.13E-02 1.13E-02 1,2,3,4,7,8- HxCDF 5.91 E-05 5.91 E-06 5.91 E-06 2.69E-02 2.69E-03 2.69E-03 1,2,3,6,7,8- HxCDF 4.43E-05 4.43E-06 4.43E-06 2.02E-02 2.02E-03 2.02E-03 1,2,3,7,8,9- HxCDF 177E-05 1.77E-06 1.77E-06 8.08E-03 8.08E-04 8.08E-04 2,3,4,6,7,8 - HxCDF 5.91 E-05 5.91 E-06 5.91 E-06 2.69E-02 2.69E-03 2.69E-03 1,2,3,4,6,7,8- HpCDF 1.68E-04 1.68E-06 1.68E-06 7.68E-02 7.68E-04 7.68E-04 1,2,3,4,7,8,9- HpCDF 3.54E-05 3.54E-07 3.54E-07 1.62E-02 1.62E-04 1.62E-04 1,2,3,4,6,7,8,9-OCDF 2.04E-04 6.11E-08 6.11E-08 9.29E-02 2.79E-05 2.79E-05 TeCDD Total 1.07E-03 4.90E-01 PeCDD Total 1.01E-03 4.58E-01 HxCDD Total 2.30E-03 1.05E+00 HpCDD Total 6.18E-03 2.82E+00 OCDD 1.00E-02 4.57E+00 TeCDF Total 2.11 E-03 9.60E-01 PeCDF Total 7.70E-04 3.51 E-01 HxCDF Total 4.59E-04 2.09E-01 HpCDF Total 4.43E-04 2.02E-01 OCDF 2.02E-04 9.23E-02 PCDD Total 2.06E-02 9.39E+00 PCDF Total 3.98E-03 1.82E+00 PCDD/PCDF Total 2.46E-02 1.12E+01 PCDD TEQ Total 3.04E-04 3.04E-04 1.39E-01 1.39E-01 PCDF TEQ Total 6.22E-05 6.22E-05 2.84E-02 2.84E-02 PCDD/PCDF TEQ Total 3.66E-04 3.66E-04 1.67E-01 1.67E-01 Table A-7. PCDD/PCDF data for NSB/NSL 3. PCDD/PCDF Page 12-A ------- Sample ID PS-PCDD-NSB3-SVOC-121714-01 MCE 0.978 Sampling volume (m3) 58.8 Carbon sampled (g) 57.7 Carbon sampled (mg/m3) 980.8 Carbon fraction 0.4561 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 -TCDD 1.56E-03 1.56E-03 1.56E-03 2.65E-05 2.65E-05 2.65E-05 1,2,3,7,8 -PeCDD 3.78E-03 3.78E-03 3.78E-03 6.43E-05 6.43E-05 6.43E-05 1,2,3,4,7,8 -HxCDD 2.44E-03 2.44E-04 2.44E-04 4.16E-05 4.16E-06 4.16E-06 1,2,3,6,7,8 -HxCDD 9.33E-03 9.33E-04 9.33E-04 1.59E-04 1.59E-05 1.59E-05 1,2,3,7,8,9-HxCDD 6.67E-03 6.67E-04 6.67E-04 1.13E-04 1.13E-05 1.13E-05 1,2,3,4,6,7,8- HpCDD 1.32E-01 1.32E-03 1.32E-03 2.25E-03 2.25E-05 2.25E-05 1,2,3,4,6,7,8,9 - OCDD 3.58E-01 1.07E-04 1.07E-04 6.09E-03 1.83E-06 1.83E-06 2,3,7,8 -TCDF 7.11E-03 7.11E-04 7.11E-04 1.21E-04 1.21 E-05 1.21 E-05 1,2,3,7,8-PeCDF 2.89E-03 8.67E-05 8.67E-05 4.91 E-05 1.47E-06 1.47E-06 2,3,4,7,8 - PeCDF 3.56E-03 1.07E-03 1.07E-03 6.05E-05 1.81 E-05 1.81 E-05 1,2,3,4,7,8-HxCDF 2.44E-03 2.44E-04 2.44E-04 4.16E-05 4.16E-06 4.16E-06 1,2,3,6,7,8-HxCDF 1.78E-03 1.78E-04 1.78E-04 3.02E-05 3.02E-06 3.02E-06 1,2,3,7,8,9-HxCDF 8.89E-04 8.89E-05 8.89E-05 1.51 E-05 1.51 E-06 1.51 E-06 2,3,4,6,7,8 - HxCDF 2.22E-03 2.22E-04 2.22E-04 3.78E-05 3.78E-06 3.78E-06 1,2,3,4,6,7,8- HpCDF 6.67E-03 6.67E-05 6.67E-05 1.13E-04 1.13E-06 1.13E-06 1,2,3,4,7,8,9- HpCDF 1.78E-03 1.78E-05 1.78E-05 3.02E-05 3.02E-07 3.02E-07 1,2,3,4,6,7,8,9-OCDF 8.00E-03 2.40E-06 2.40E-06 1.36E-04 4.08E-08 4.08E-08 TeCDD Total 4.51 E-02 7.67E-04 PeCDD Total 3.84E-02 6.53E-04 HxCDD Total 7.48E-02 1.27E-03 HpCDD Total 2.11E-01 3.59E-03 OCDD 3.58E-01 6.09E-03 TeCDF Total 1.14E-01 1.94E-03 PeCDF Total 4.00E-02 6.80E-04 HxCDF Total 2.21 E-02 3.76E-04 HpCDF Total 1.68E-02 2.87E-04 OCDF 8.02E-03 1.36E-04 PCDD Total 7.27E-01 1.24E-02 PCDF Total 2.01 E-01 3.41 E-03 PCDD/PCDF Total 9.28E-01 1.58E-02 PCDD TEQ Total 8.61 E-03 8.61 E-03 1.46E-04 1.46E-04 PCDF TEQ Total 2.68E-03 2.68E-03 4.57E-05 4.57E-05 PCDD/PCDF TEQ Total 1.13E-02 1.13E-02 1.92E-04 1.92E-04 805 Sample ID PS-PCDD-NSB3-SVOC-121714-01 Page 2 (2) 13-A ------- EF EF EF EF EF EF Total TEQ TEQ Total TEQ TEQ Isomer. ng/g Carbon ng/kg fiberboard ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 2.70E-05 2.70E-05 2.70E-05 1.23E-02 1.23E-02 1.23E-02 1,2,3,7,8- PeCDD 6.55E-05 6.55E-05 6.55E-05 2.99E-02 2.99E-02 2.99E-02 1,2,3,4,7,8- HxCDD 4.24E-05 4.24E-06 4.24E-06 1.93E-02 1.93E-03 1.93E-03 1,2,3,6,7,8- HxCDD 1.62E-04 1.62E-05 1.62E-05 7.38E-02 7.38E-03 7.38E-03 1,2,3,7,8,9- HxCDD 1.16E-04 1.16E-05 1.16E-05 5.27E-02 5.27E-03 5.27E-03 1,2,3,4,6,7,8- HpCDD 2.29E-03 2.29E-05 2.29E-05 1.04E+00 1.04E-02 1.04E-02 1,2,3,4,6,7,8,9 - OCDD 6.21 E-03 1.86E-06 1.86E-06 2.83E+00 8.50E-04 8.50E-04 2,3,7,8 - TCDF 1.23E-04 1.23E-05 1.23E-05 5.62E-02 5.62E-03 5.62E-03 1,2,3,7,8- PeCDF 5.01 E-05 1.50E-06 1.50E-06 2.29E-02 6.86E-04 6.86E-04 2,3,4,7,8- PeCDF 6.17E-05 1.85E-05 1.85E-05 2.81 E-02 8.44E-03 8.44E-03 1,2,3,4,7,8- HxCDF 4.24E-05 4.24E-06 4.24E-06 1.93E-02 1.93E-03 1.93E-03 1,2,3,6,7,8- HxCDF 3.08E-05 3.08E-06 3.08E-06 1.41 E-02 1.41 E-03 1.41 E-03 1,2,3,7,8,9- HxCDF 1.54E-05 1.54E-06 1.54E-06 7.03E-03 7.03E-04 7.03E-04 2,3,4,6,7,8 - HxCDF 3.85E-05 3.85E-06 3.85E-06 1.76E-02 1.76E-03 1.76E-03 1,2,3,4,6,7,8- HpCDF 1.16E-04 1.16E-06 1.16E-06 5.27E-02 5.27E-04 5.27E-04 1,2,3,4,7,8,9- HpCDF 3.08E-05 3.08E-07 3.08E-07 1.41 E-02 1.41 E-04 1.41 E-04 1,2,3,4,6,7,8,9-OCDF 1.39E-04 4.16E-08 4.16E-08 6.33E-02 1.90E-05 1.90E-05 TeCDD Total 7.82E-04 3.56E-01 PeCDD Total 6.66E-04 3.04E-01 HxCDD Total 1.30E-03 5.91 E-01 HpCDD Total 3.66E-03 1.67E+00 OCDD 6.21 E-03 2.83E+00 TeCDF Total 1.97E-03 9.00E-01 PeCDF Total 6.93E-04 3.16E-01 HxCDF Total 3.83E-04 1.75E-01 HpCDF Total 2.92E-04 1.33E-01 OCDF 1.39E-04 6.35E-02 PCDD Total 1.26E-02 5.75E+00 PCDF Total 3.48E-03 1.59E+00 PCDD/PCDF Total 1.61 E-02 7.34E+00 PCDD TEQ Total 1.49E-04 1.49E-04 6.81 E-02 6.81 E-02 PCDF TEQ Total 4.66E-05 4.66E-05 2.12E-02 2.12E-02 PCDD/PCDF TEQ Total 1.96E-04 1.96E-04 8.93E-02 8.93E-02 Table A-8. PCDD/PCDF data for NSB/NSL 4. PCDD/PCDF Page 1 (2) 14-A ------- Sample ID PS-PCDD-NSB4-SVOC-121714-02 MCE 0.981 Sampling volume (m3) 63.7 Carbon sampled (g) 77.2 Carbon sampled (mg/m3) 1212.2 Carbon fraction 0.4561 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 -TCDD 1.78E-03 1.78E-03 1.78E-03 2.79E-05 2.79E-05 2.79E-05 1,2,3,7,8 -PeCDD 8.22E-03 8.22E-03 8.22E-03 1.29E-04 1.29E-04 1.29E-04 1,2,3,4,7,8 -HxCDD 4.44E-03 4.44E-04 4.44E-04 6.98E-05 6.98E-06 6.98E-06 1,2,3,6,7,8 -HxCDD 1.58E-02 1.58E-03 1.58E-03 2.48E-04 2.48E-05 2.48E-05 1,2,3,7,8,9-HxCDD 1.16E-02 1.16E-03 1.16E-03 1.81 E-04 1.81E-05 1.81 E-05 1,2,3,4,6,7,8- HpCDD 1.95E-01 1.95E-03 1.95E-03 3.07E-03 3.07E-05 3.07E-05 1,2,3,4,6,7,8,9 - OCDD 5.51 E-01 1.65E-04 1.65E-04 8.65E-03 2.59E-06 2.59E-06 2,3,7,8 -TCDF 1.22E-02 1.22E-03 1.22E-03 1.92E-04 1.92E-05 1.92E-05 1,2,3,7,8-PeCDF 4.89E-03 1.47E-04 1.47E-04 7.67E-05 2.30E-06 2.30E-06 2,3,4,7,8 - PeCDF 5.56E-03 1.67E-03 1.67E-03 8.72E-05 2.62E-05 2.62E-05 1,2,3,4,7,8-HxCDF 4.44E-03 4.44E-04 4.44E-04 6.98E-05 6.98E-06 6.98E-06 1,2,3,6,7,8-HxCDF 3.11E-03 3.11E-04 3.11E-04 4.88E-05 4.88E-06 4.88E-06 1,2,3,7,8,9-HxCDF 1.11E-03 1.11E-04 1.11E-04 1.74E-05 1.74E-06 1.74E-06 2,3,4,6,7,8 - HxCDF 3.56E-03 3.56E-04 3.56E-04 5.58E-05 5.58E-06 5.58E-06 1,2,3,4,6,7,8- HpCDF 1.04E-02 1.04E-04 1.04E-04 1.64E-04 1.64E-06 1.64E-06 1,2,3,4,7,8,9- HpCDF 1.56E-03 1.56E-05 1.56E-05 2.44E-05 2.44E-07 2.44E-07 1,2,3,4,6,7,8,9-OCDF 1.22E-02 3.67E-06 3.67E-06 1.92E-04 5.75E-08 5.75E-08 TeCDD Total 8.37E-02 1.31 E-03 PeCDD Total 6.83E-02 1.07E-03 HxCDD Total 1.23E-01 1.93E-03 HpCDD Total 3.22E-01 5.05E-03 OCDD 5.51 E-01 8.65E-03 TeCDF Total 1.88E-01 2.95E-03 PeCDF Total 7.37E-02 1.16E-03 HxCDF Total 3.96E-02 6.21 E-04 HpCDF Total 2.58E-02 4.05E-04 OCDF 1.23E-02 1.93E-04 PCDD Total 1.15E+00 1.80E-02 PCDF Total 3.39E-01 5.33E-03 PCDD/PCDF Total 1.49E+00 2.33E-02 PCDD TEQ Total 1.53E-02 1.53E-02 2.40E-04 2.40E-04 PCDF TEQ Total 4.38E-03 4.38E-03 6.88E-05 6.88E-05 PCDD/PCDF TEQ Total 1.97E-02 1.97E-02 3.09E-04 3.09E-04 Sample ID PS-PCDD-NSB4-SVOC-121714-02 Page 2 (2) 15-A ------- EF EF EF EF EF EF Total TEQ TEQ Total TEQ TEQ Isomer. ng/g Carbon ng/kg fiberboard ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 2.30E-05 2.30E-05 2.30E-05 1.05E-02 1.05E-02 1.05E-02 1,2,3,7,8- PeCDD 1.06E-04 1.06E-04 1.06E-04 4.85E-02 4.85E-02 4.85E-02 1,2,3,4,7,8- HxCDD 5.75E-05 5.75E-06 5.75E-06 2.62E-02 2.62E-03 2.62E-03 1,2,3,6,7,8- HxCDD 2.04E-04 2.04E-05 2.04E-05 9.32E-02 9.32E-03 9.32E-03 1,2,3,7,8,9- HxCDD 1.50E-04 1.50E-05 1.50E-05 6.82E-02 6.82E-03 6.82E-03 1,2,3,4,6,7,8- HpCDD 2.53E-03 2.53E-05 2.53E-05 1.15E+00 1.15E-02 1.15E-02 1,2,3,4,6,7,8,9 - OCDD 7.14E-03 2.14E-06 2.14E-06 3.25E+00 9.76E-04 9.76E-04 2,3,7,8 - TCDF 1.58E-04 1.58E-05 1.58E-05 7.22E-02 7.22E-03 7.22E-03 1,2,3,7,8- PeCDF 6.33E-05 1.90E-06 1.90E-06 2.89E-02 8.66E-04 8.66E-04 2,3,4,7,8- PeCDF 7.19E-05 2.16E-05 2.16E-05 3.28E-02 9.84E-03 9.84E-03 1,2,3,4,7,8- HxCDF 5.75E-05 5.75E-06 5.75E-06 2.62E-02 2.62E-03 2.62E-03 1,2,3,6,7,8- HxCDF 4.03E-05 4.03E-06 4.03E-06 1.84E-02 1.84E-03 1.84E-03 1,2,3,7,8,9- HxCDF 1.44E-05 1.44E-06 1.44E-06 6.56E-03 6.56E-04 6.56E-04 2,3,4,6,7,8 - HxCDF 4.60E-05 4.60E-06 4.60E-06 2.10E-02 2.10E-03 2.10E-03 1,2,3,4,6,7,8- HpCDF 1.35E-04 1.35E-06 1.35E-06 6.17E-02 6.17E-04 6.17E-04 1,2,3,4,7,8,9- HpCDF 2.01 E-05 2.01 E-07 2.01 E-07 9.18E-03 9.18E-05 9.18E-05 1,2,3,4,6,7,8,9-OCDF 1.58E-04 4.75E-08 4.75E-08 7.22E-02 2.17E-05 2.17E-05 TeCDD Total 1.08E-03 4.94E-01 PeCDD Total 8.84E-04 4.03E-01 HxCDD Total 1.59E-03 7.25E-01 HpCDD Total 4.16E-03 1.90E+00 OCDD 7.13E-03 3.25E+00 TeCDF Total 2.43E-03 1.11E+00 PeCDF Total 9.55E-04 4.35E-01 HxCDF Total 5.12E-04 2.34E-01 HpCDF Total 3.34E-04 1.52E-01 OCDF 1.59E-04 7.24E-02 PCDD Total 1.49E-02 6.77E+00 PCDF Total 4.39E-03 2.00E+00 PCDD/PCDF Total 1.92E-02 8.78E+00 PCDD TEQ Total 1.98E-04 1.98E-04 9.03E-02 9.03E-02 PCDF TEQ Total 5.67E-05 5.67E-05 2.59E-02 2.59E-02 PCDD/PCDF TEQ Total 2.55E-04 2.55E-04 1.16E-01 1.16E-01 Table A-9. PCDD/PCDF data for NWS 1. PCDD/PCDF Page 1 (2) 16-A ------- Sample ID PS-PCDD-NWS-SVOC-111714-01 MCE 0.974 Sampling volume (m3) 85.4 Carbon sampled (g) 46.8 Carbon sampled (mg/m3) 547.9 Carbon fraction 0.4656 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD ND 9.78E-04 0.00E+00 9.78E-04 ND 0.00E+00 1.15E-05 1,2,3,7,8- PeCDD 2.00E-03 2.00E-03 2.00E-03 2.34E-05 2.34E-05 2.34E-05 1,2,3,4,7,8- HxCDD 1.33E-03 1.33E-04 1.33E-04 1.56E-05 1.56E-06 1.56E-06 1,2,3,6,7,8- HxCDD 2.67E-03 2.67E-04 2.67E-04 3.12E-05 3.12E-06 3.12E-06 1,2,3,7,8,9- HxCDD 2.00E-03 2.00E-04 2.00E-04 2.34E-05 2.34E-06 2.34E-06 1,2,3,4,6,7,8- HpCDD 2.11E-02 2.11E-04 2.11E-04 2.47E-04 2.47E-06 2.47E-06 1,2,3,4,6,7,8,9 - OCDD 5.47E-02 1.64E-05 1.64E-05 6.40E-04 1.92E-07 1.92E-07 2,3,7,8 -TCDF 1.29E-02 1.29E-03 1.29E-03 1.51E-04 1.51 E-05 1.51 E-05 1,2,3,7,8- PeCDF 4.67E-03 1.40E-04 1.40E-04 5.47E-05 1.64E-06 1.64E-06 2,3,4,7,8- PeCDF 6.00E-03 1.80E-03 1.80E-03 7.03E-05 2.11 E-05 2.11 E-05 1,2,3,4,7,8- HxCDF 6.00E-03 6.00E-04 6.00E-04 7.03E-05 7.03E-06 7.03E-06 1,2,3,6,7,8- HxCDF 5.11E-03 5.11E-04 5.11E-04 5.99E-05 5.99E-06 5.99E-06 1,2,3,7,8,9- HxCDF 3.33E-03 3.33E-04 3.33E-04 3.91 E-05 3.91 E-06 3.91 E-06 2,3,4,6,7,8 - HxCDF 7.11E-03 7.11E-04 7.11E-04 8.33E-05 8.33E-06 8.33E-06 1,2,3,4,6,7,8- HpCDF 1.60E-02 1.60E-04 1.60E-04 1.87E-04 1.87E-06 1.87E-06 1,2,3,4,7,8,9- HpCDF 2.67E-03 2.67E-05 2.67E-05 3.12E-05 3.12E-07 3.12E-07 1,2,3,4,6,7,8,9-OCDF 9.11E-03 2.73E-06 2.73E-06 1.07E-04 3.20E-08 3.20E-08 TeCDD Total 5.67E-02 6.64E-04 PeCDD Total 2.49E-02 2.92E-04 HxCDD Total 1.89E-02 2.21 E-04 HpCDD Total 3.74E-02 4.38E-04 OCDD 5.48E-02 6.42E-04 TeCDF Total 1.65E-01 1.93E-03 PeCDF Total 5.84E-02 6.84E-04 HxCDF Total 5.28E-02 6.19E-04 HpCDF Total 3.14E-02 3.67E-04 OCDF 9.18E-03 1.08E-04 PCDD Total 1.93E-01 2.26E-03 PCDF Total 3.17E-01 3.71 E-03 PCDD/PCDF Total 5.09E-01 5.97E-03 PCDD TEQ Total 2.83E-03 3.81 E-03 3.31 E-05 4.46E-05 PCDF TEQ Total 5.57E-03 5.57E-03 6.53E-05 6.53E-05 PCDD/PCDF TEQ Total 8.40E-03 9.38E-03 9.84E-05 1.10E-04 Sam pie ID PS-PCDD-NWS-SVOC-111714-01 Page 2 (2) 17-A ------- EF EF EF EF EF EF Total TEQ TEQ Total TEQ TEQ Isomer. ng/g Carbon ng/kg fiberboard ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD ND 0.00E+00 2.09E-05 ND 0.00E+00 9.74E-03 1,2,3,7,8- PeCDD 4.28E-05 4.28E-05 4.28E-05 1.99E-02 1.99E-02 1.99E-02 1,2,3,4,7,8- HxCDD 2.85E-05 2.85E-06 2.85E-06 1.33E-02 1.33E-03 1.33E-03 1,2,3,6,7,8- HxCDD 5.70E-05 5.70E-06 5.70E-06 2.66E-02 2.66E-03 2.66E-03 1,2,3,7,8,9- HxCDD 4.28E-05 4.28E-06 4.28E-06 1.99E-02 1.99E-03 1.99E-03 1,2,3,4,6,7,8- HpCDD 4.51 E-04 4.51 E-06 4.51 E-06 2.10E-01 2.10E-03 2.10E-03 1,2,3,4,6,7,8,9 - OCDD 1.17E-03 3.51 E-07 3.51 E-07 5.44E-01 1.63E-04 1.63E-04 2,3,7,8 - TCDF 2.76E-04 2.76E-05 2.76E-05 1.28E-01 1.28E-02 1.28E-02 1,2,3,7,8- PeCDF 9.98E-05 2.99E-06 2.99E-06 4.65E-02 1.39E-03 1.39E-03 2,3,4,7,8- PeCDF 1.28E-04 3.85E-05 3.85E-05 5.97E-02 1.79E-02 1.79E-02 1,2,3,4,7,8- HxCDF 1.28E-04 1.28E-05 1.28E-05 5.97E-02 5.97E-03 5.97E-03 1,2,3,6,7,8- HxCDF 1.09E-04 1.09E-05 1.09E-05 5.09E-02 5.09E-03 5.09E-03 1,2,3,7,8,9- HxCDF 7.13E-05 7.13E-06 7.13E-06 3.32E-02 3.32E-03 3.32E-03 2,3,4,6,7,8 - HxCDF 1.52E-04 1.52E-05 1.52E-05 7.08E-02 7.08E-03 7.08E-03 1,2,3,4,6,7,8- HpCDF 3.42E-04 3.42E-06 3.42E-06 1.59E-01 1.59 E-03 1.59E-03 1,2,3,4,7,8,9- HpCDF 5.70E-05 5.70E-07 5.70E-07 2.66E-02 2.66E-04 2.66E-04 1,2,3,4,6,7,8,9-OCDF 1.95E-04 5.84E-08 5.84E-08 9.07E-02 2.72E-05 2.72E-05 TeCDD Total 1.21 E-03 5.64E-01 PeCDD Total 5.33E-04 2.48E-01 HxCDD Total 4.04E-04 1.88E-01 HpCDD Total 7.99E-04 3.72E-01 OCDD 1.17E-03 5.45E-01 TeCDF Total 3.52E-03 1.64E+00 PeCDF Total 1.25E-03 5.82E-01 HxCDF Total 1.13E-03 5.26E-01 HpCDF Total 6.70E-04 3.12E-01 OCDF 1.96E-04 9.14E-02 PCDD Total 4.12E-03 1.92E+00 PCDF Total 6.77E-03 3.15E+00 PCDD/PCDF Total 1.09E-02 5.07E+00 PCDD TEQ Total 6.05E-05 8.14E-05 2.82E-02 3.79E-02 PCDF TEQ Total 1.19E-04 1.19E-04 5.55E-02 5.55E-02 PCDD/PCDF TEQ Total 1.80E-04 2.01 E-04 8.36E-02 9.34E-02 810 Table A-10. PCDD/PCDF data for NWS 2. PCDD/PCDF Page 1 (2) 18-A ------- Sample ID PS-PCDD-NWS2-SV0C-11182104-01 MCE 0.989 Sampling volume (m3) 55.6 Carbon sampled (g) 37.0 Carbon sampled (mg/m3) 665.6 Carbon fraction 0.4656 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 6.00E-04 6.00E-04 6.00E-04 1.08E-05 1.08E-05 1.08E-05 1,2,3,7,8- PeCDD 2.00E-03 2.00E-03 2.00E-03 3.60E-05 3.60E-05 3.60E-05 1,2,3,4,7,8- HxCDD 1.20E-03 1.20E-04 1.20E-04 2.16E-05 2.16E-06 2.16E-06 1,2,3,6,7,8- HxCDD 1.40E-03 1.40E-04 1.40E-04 2.52E-05 2.52E-06 2.52E-06 1,2,3,7,8,9- HxCDD 1.40E-03 1.40E-04 1.40E-04 2.52E-05 2.52E-06 2.52E-06 1,2,3,4,6,7,8- HpCDD 1.44E-02 1.44E-04 1.44E-04 2.59E-04 2.59E-06 2.59E-06 1,2,3,4,6,7,8,9 - OCDD 4.00E-02 1.20E-05 1.20E-05 7.19E-04 2.16E-07 2.16E-07 2,3,7,8 - TCDF 1.04E-02 1.04E-03 1.04E-03 1.87E-04 1.87E-05 1.87E-05 1,2,3,7,8- PeCDF 8.00E-03 2.40E-04 2.40E-04 1.44E-04 4.32E-06 4.32E-06 2,3,4,7,8- PeCDF 1.02E-02 3.06E-03 3.06E-03 1.83E-04 5.50E-05 5.50E-05 1,2,3,4,7,8- HxCDF 8.20E-03 8.20E-04 8.20E-04 1.47E-04 1.47E-05 1.47E-05 1,2,3,6,7,8- HxCDF 8.00E-03 8.00E-04 8.00E-04 1.44E-04 1.44E-05 1.44E-05 1,2,3,7,8,9- HxCDF 2.60E-03 2.60E-04 2.60E-04 4.68E-05 4.68E-06 4.68E-06 2,3,4,6,7,8 - HxCDF 7.00E-03 7.00E-04 7.00E-04 1.26E-04 1.26E-05 1.26E-05 1,2,3,4,6,7,8- HpCDF 1.46E-02 1.46E-04 1.46E-04 2.63E-04 2.63E-06 2.63E-06 1,2,3,4,7,8,9- HpCDF 3.60E-03 3.60E-05 3.60E-05 6.47E-05 6.47E-07 6.47E-07 1,2,3,4,6,7,8,9-OCDF 1.00E-02 3.00E-06 3.00E-06 1.80E-04 5.39E-08 5.39E-08 TeCDD Total 2.97E-02 5.33E-04 PeCDD Total 1.36E-02 2.45E-04 HxCDD Total 1.62E-02 2.92E-04 HpCDD Total 2.55E-02 4.58E-04 OCDD 4.00E-02 7.19E-04 TeCDF Total 2.44E-01 4.38E-03 PeCDF Total 1.14E-01 2.05E-03 HxCDF Total 6.70E-02 1.21 E-03 HpCDF Total 3.07E-02 5.51 E-04 OCDF 9.92E-03 1.78E-04 PCDD Total 1.25E-01 2.25E-03 PCDF Total 4.65E-01 8.36E-03 PCDD/PCDF Total 5.90E-01 1.06E-02 PCDD TEQ Total 3.16E-03 3.16E-03 5.68E-05 5.68E-05 PCDF TEQ Total 7.11 E-03 7.11 E-03 1.28E-04 1.28E-04 PCDD/PCDF TEQ Total 1.03E-02 1.03E-02 1.85E-04 1.85E-04 Sample ID PS-PCDD-NWS2-SVOC-11182104-01 Page 2 (2) 19-A ------- EF EF EF EF EF EF Total TEQ TEQ Total TEQ TEQ Isomer. ng/g Carbon ng/kg fiberboard ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 1.62E-05 1.62E-05 1.62E-05 7.55E-03 7.55E-03 7.55E-03 1,2,3,7,8- PeCDD 5.40E-05 5.40E-05 5.40E-05 2.52E-02 2.52E-02 2.52E-02 1,2,3,4,7,8- HxCDD 3.24E-05 3.24E-06 3.24E-06 1.51 E-02 1.51 E-03 1.51 E-03 1,2,3,6,7,8- HxCDD 3.78E-05 3.78E-06 3.78E-06 1.76E-02 1.76E-03 1.76E-03 1,2,3,7,8,9- HxCDD 3.78E-05 3.78E-06 3.78E-06 1.76E-02 1.76E-03 1.76E-03 1,2,3,4,6,7,8- HpCDD 3.89E-04 3.89E-06 3.89E-06 1.81 E-01 1.81 E-03 1.81 E-03 1,2,3,4,6,7,8,9 - OCDD 1.08E-03 3.24E-07 3.24E-07 5.03E-01 1.51 E-04 1.51 E-04 2,3,7,8 - TCDF 2.81 E-04 2.81 E-05 2.81 E-05 1.31 E-01 1.31 E-02 1.31 E-02 1,2,3,7,8- PeCDF 2.16E-04 6.48E-06 6.48E-06 1.01 E-01 3.02E-03 3.02E-03 2,3,4,7,8- PeCDF 2.76E-04 8.27E-05 8.27E-05 1.28E-01 3.85E-02 3.85E-02 1,2,3,4,7,8- HxCDF 2.22E-04 2.22E-05 2.22E-05 1.03E-01 1.03E-02 1.03E-02 1,2,3,6,7,8- HxCDF 2.16E-04 2.16E-05 2.16E-05 1.01 E-01 1.01 E-02 1.01 E-02 1,2,3,7,8,9- HxCDF 7.02E-05 7.02E-06 7.02E-06 3.27E-02 3.27E-03 3.27E-03 2,3,4,6,7,8 - HxCDF 1.89E-04 1.89E-05 1.89E-05 8.81 E-02 8.81 E-03 8.81 E-03 1,2,3,4,6,7,8- HpCDF 3.94E-04 3.94E-06 3.94E-06 1.84E-01 1.84E-03 1.84E-03 1,2,3,4,7,8,9- HpCDF 9.73E-05 9.73E-07 9.73E-07 4.53E-02 4.53E-04 4.53E-04 1,2,3,4,6,7,8,9-OCDF 2.70E-04 8.10E-08 8.10E-08 1.26E-01 3.77E-05 3.77E-05 TeCDD Total 8.01 E-04 3.73E-01 PeCDD Total 3.68E-04 1.71 E-01 HxCDD Total 4.39E-04 2.04E-01 HpCDD Total 6.88E-04 3.21 E-01 OCDD 1.08E-03 5.03E-01 TeCDF Total 6.58E-03 3.06E+00 PeCDF Total 3.08E-03 1.43E+00 HxCDF Total 1.81 E-03 8.43E-01 HpCDF Total 8.28E-04 3.86E-01 OCDF 2.68E-04 1.25E-01 PCDD Total 3.38E-03 1.57E+00 PCDF Total 1.26E-02 5.85E+00 PCDD/PCDF Total 1.59E-02 7.42E+00 PCDD TEQ Total 8.53E-05 8.53E-05 3.97E-02 3.97E-02 PCDF TEQ Total 1.92E-04 1.92E-04 8.94E-02 8.94E-02 PCDD/PCDF TEQ Total 2.77E-04 2.77E-04 1.29E-01 1.29E-01 Table A-ll. PCDD/PCDF data for NWS 3. PCDD/PCDF Page 1 (2) 20-A ------- Sample ID PS-PCDD-NWS3-SV0C-120814-01 MCE 0.982 Sampling volume (m3) 95.7 Carbon sampled (g) 68.1 Carbon sampled (mg/m3) 711.2 Carbon fraction 0.4656 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 6.67E-04 6.67E-04 6.67E-04 6.96E-06 6.96E-06 6.96E-06 1,2,3,7,8- PeCDD 1.33E-03 1.33E-03 1.33E-03 1.39E-05 1.39E-05 1.39E-05 1,2,3,4,7,8- HxCDD 1.11E-03 1.11E-04 1.11E-04 1.16E-05 1.16E-06 1.16E-06 1,2,3,6,7,8- HxCDD 2.44E-03 2.44E-04 2.44E-04 2.55E-05 2.55E-06 2.55E-06 1,2,3,7,8,9- HxCDD 1.78E-03 1.78E-04 1.78E-04 1.86E-05 1.86E-06 1.86E-06 1,2,3,4,6,7,8- HpCDD 2.29E-02 2.29E-04 2.29E-04 2.39E-04 2.39E-06 2.39E-06 1,2,3,4,6,7,8,9 - OCDD 5.64E-02 1.69E-05 1.69E-05 5.90E-04 1.77E-07 1.77E-07 2,3,7,8 - TCDF 7.56E-03 7.56E-04 7.56E-04 7.89E-05 7.89E-06 7.89E-06 1,2,3,7,8- PeCDF 2.67E-03 8.00E-05 8.00E-05 2.79E-05 8.36E-07 8.36E-07 2,3,4,7,8- PeCDF 6.00E-03 1.80E-03 1.80E-03 6.27E-05 1.88E-05 1.88E-05 1,2,3,4,7,8- HxCDF 4.44E-03 4.44E-04 4.44E-04 4.64E-05 4.64E-06 4.64E-06 1,2,3,6,7,8- HxCDF 3.78E-03 3.78E-04 3.78E-04 3.95E-05 3.95E-06 3.95E-06 1,2,3,7,8,9- HxCDF 2.22E-03 2.22E-04 2.22E-04 2.32E-05 2.32E-06 2.32E-06 2,3,4,6,7,8 - HxCDF 5.33E-03 5.33E-04 5.33E-04 5.57E-05 5.57E-06 5.57E-06 1,2,3,4,6,7,8- HpCDF 1.16E-02 1.16E-04 1.16E-04 1.21 E-04 1.21 E-06 1.21 E-06 1,2,3,4,7,8,9- HpCDF 2.00E-03 2.00E-05 2.00E-05 2.09E-05 2.09E-07 2.09E-07 1,2,3,4,6,7,8,9-OCDF 7.78E-03 2.33E-06 2.33E-06 8.13E-05 2.44E-08 2.44E-08 TeCDD Total 4.03E-02 4.21 E-04 PeCDD Total 2.98E-02 3.11 E-04 HxCDD Total 2.73E-02 2.85E-04 HpCDD Total 3.99E-02 4.17E-04 OCDD 5.64E-02 5.89E-04 TeCDF Total 1.08E-01 1.12E-03 PeCDF Total 4.52E-02 4.72E-04 HxCDF Total 3.85E-02 4.03E-04 HpCDF Total 2.24E-02 2.34E-04 OCDF 7.80E-03 8.15E-05 PCDD Total 1.94E-01 2.02E-03 PCDF Total 2.22E-01 2.32E-03 PCDD/PCDF Total 4.15E-01 4.34E-03 PCDD TEQ Total 2.78E-03 2.78E-03 2.90E-05 2.90E-05 PCDF TEQ Total 4.35E-03 4.35E-03 4.55E-05 4.55E-05 PCDD/PCDF TEQ Total 7.13E-03 7.13E-03 7.45E-05 7.45E-05 Sample ID PS-PCDD-NWS3-SVOC-120814-01 Page 2 (2) 21-A ------- EF EF EF EF EF EF Total TEQ TEQ Total TEQ TEQ Isomer. ng/g Carbon ng/kg fiberboard ND=0 ND=LOD ND=0 ND=LOD 2,3,7,8 - TCDD 9.79E-06 9.79E-06 9.79E-06 4.56E-03 4.56E-03 4.56E-03 1,2,3,7,8- PeCDD 1.96E-05 1.96E-05 1.96E-05 9.12E-03 9.12E-03 9.12E-03 1,2,3,4,7,8- HxCDD 1.63E-05 1.63E-06 1.63E-06 7.60E-03 7.60E-04 7.60E-04 1,2,3,6,7,8- HxCDD 3.59E-05 3.59E-06 3.59E-06 1.67E-02 1.67E-03 1.67E-03 1,2,3,7,8,9- HxCDD 2.61 E-05 2.61 E-06 2.61 E-06 1.22E-02 1.22E-03 1.22E-03 1,2,3,4,6,7,8- HpCDD 3.36E-04 3.36E-06 3.36E-06 1.57E-01 1.57E-03 1.57E-03 1,2,3,4,6,7,8,9 - OCDD 8.29E-04 2.49E-07 2.49E-07 3.86E-01 1.16E-04 1.16E-04 2,3,7,8 - TCDF 1.11E-04 1.11 E-05 1.11 E-05 5.17E-02 5.17E-03 5.17E-03 1,2,3,7,8- PeCDF 3.92E-05 1.18E-06 1.18E-06 1.82E-02 5.47E-04 5.47E-04 2,3,4,7,8- PeCDF 8.81 E-05 2.64E-05 2.64E-05 4.10E-02 1.23E-02 1.23E-02 1,2,3,4,7,8- HxCDF 6.53E-05 6.53E-06 6.53E-06 3.04E-02 3.04E-03 3.04E-03 1,2,3,6,7,8- HxCDF 5.55E-05 5.55E-06 5.55E-06 2.58E-02 2.58E-03 2.58E-03 1,2,3,7,8,9- HxCDF 3.26E-05 3.26E-06 3.26E-06 1.52E-02 1.52E-03 1.52E-03 2,3,4,6,7,8 - HxCDF 7.83E-05 7.83E-06 7.83E-06 3.65E-02 3.65E-03 3.65E-03 1,2,3,4,6,7,8- HpCDF 1.70E-04 1.70E-06 1.70E-06 7.90E-02 7.90E-04 7.90E-04 1,2,3,4,7,8,9- HpCDF 2.94E-05 2.94E-07 2.94E-07 1.37E-02 1.37E-04 1.37E-04 1,2,3,4,6,7,8,9-OCDF 1.14E-04 3.43E-08 3.43E-08 5.32E-02 1.60E-05 1.60E-05 TeCDD Total 5.92E-04 2.76E-01 PeCDD Total 4.37E-04 2.04E-01 HxCDD Total 4.01 E-04 1.86E-01 HpCDD Total 5.86E-04 2.73E-01 OCDD 8.28E-04 3.86E-01 TeCDF Total 1.58E-03 7.36E-01 PeCDF Total 6.64E-04 3.09E-01 HxCDF Total 5.66E-04 2.64E-01 HpCDF Total 3.30E-04 1.53E-01 OCDF 1.15E-04 5.33E-02 PCDD Total 2.84E-03 1.32E+00 PCDF Total 3.26E-03 1.52E+00 PCDD/PCDF Total 6.10E-03 2.84E+00 PCDD TEQ Total 4.08E-05 4.08E-05 1.90E-02 1.90E-02 PCDF TEQ Total 6.39E-05 6.39E-05 2.98E-02 2.98E-02 PCDD/PCDF TEQ Total 1.05E-04 1.05E-04 4.88E-02 4.88E-02 Table A-12. PCDD/PCDF data for NWS 4. PCDD/PCDF Page 1 (2) 22-A ------- Sample ID PS-PCDD-NWS4-SVOC-121014-01 MCE 0.986 Sampling volume (m3) 52.3 Carbon sampled (g) 65.8 Carbon sampled (mg/m3) 1257.7 Carbon fraction 0.4656 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ND = ng/sample ng/sample ND = 0 LOD ND = 0 ND = LOD 2,3,7,8 - TCDD ND 5.56E-04 0.00E+00 5.56E-04 ND 0.00E+00 1.06E-05 1,2,3,7,8- PeCDD 1.56E-03 1.56E-03 1.56E-03 2.97E-05 2.97E-05 2.97E-05 1,2,3,4,7,8- HxCDD 8.89E-04 8.89E-05 8.89E-05 1.70E-05 1.70E-06 1.70E-06 1,2,3,6,7,8- HxCDD 1.11E-03 1.11E-04 1.11E-04 2.12E-05 2.12E-06 2.12E-06 1,2,3,7,8,9- HxCDD 1.56E-03 1.56E-04 1.56E-04 2.97E-05 2.97E-06 2.97E-06 1,2,3,4,6,7,8- HpCDD 1.58E-02 1.58E-04 1.58E-04 3.01 E-04 3.01 E-06 3.01 E-06 1,2,3,4,6,7,8,9 - OCDD 3.49E-02 1.05E-05 1.05E-05 6.67E-04 2.00E-07 2.00E-07 2,3,7,8 - TCDF 5.33E-03 5.33E-04 5.33E-04 1.02E-04 1.02E-05 1.02E-05 1,2,3,7,8- PeCDF 2.67E-03 8.00E-05 8.00E-05 5.09E-05 1.53E-06 1.53E-06 2,3,4,7,8- PeCDF 4.67E-03 1.40E-03 1.40E-03 8.92E-05 2.67E-05 2.67E-05 1,2,3,4,7,8- HxCDF 4.67E-03 4.67E-04 4.67E-04 8.92E-05 8.92E-06 8.92E-06 1,2,3,6,7,8- HxCDF 3.33E-03 3.33E-04 3.33E-04 6.37E-05 6.37E-06 6.37E-06 1,2,3,7,8,9- HxCDF 1.33E-03 1.33E-04 1.33E-04 2.55E-05 2.55E-06 2.55E-06 2,3,4,6,7,8 - HxCDF 5.11E-03 5.11E-04 5.11E-04 9.77E-05 9.77E-06 9.77E-06 1,2,3,4,6,7,8- HpCDF 9.78E-03 9.78E-05 9.78E-05 1.87E-04 1.87E-06 1.87E-06 1,2,3,4,7,8,9- HpCDF 1.11E-03 1.11E-05 1.11E-05 2.12E-05 2.12E-07 2.12E-07 1,2,3,4,6,7,8,9-OCDF 4.67E-03 1.40E-06 1.40E-06 8.92E-05 2.67E-08 2.67E-08 TeCDD Total 4.77E-02 9.11 E-04 PeCDD Total 2.65E-02 5.06E-04 HxCDD Total 2.34E-02 4.46E-04 HpCDD Total 2.89E-02 5.53E-04 OCDD 3.48E-02 6.65E-04 TeCDF Total 1.08E-01 2.07E-03 PeCDF Total 4.90E-02 9.36E-04 HxCDF Total 3.48E-02 6.64E-04 HpCDF Total 1.79E-02 3.42E-04 OCDF 4.69E-03 8.96E-05 PCDD Total 1.61 E-01 3.08E-03 PCDF Total 2.15E-01 4.10E-03 PCDD/PCDF Total 3.76E-01 7.18E-03 PCDD TEQ Total 2.08E-03 2.63E-03 3.97E-05 5.03E-05 PCDF TEQ Total 3.57E-03 3.57E-03 6.82E-05 6.82E-05 PCDD/PCDF TEQ Total 5.65E-03 6.20E-03 1.08E-04 1.19E-04 815 Sample ID PS-PCDD-NWS4-SVOC-121014-01 Page 2(2) 23-A ------- EF EF EF EF EF EF Total TEQ TEQ Total TEQ TEQ Isomer. ng/g Carbon ng/kg fiberboard ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8-TCDD ND 0.00E+00 8.44E-06 ND 0.00E+00 3.93E-03 1,2,3,7,8-PeCDD 2.36E-05 2.36E-05 2.36E-05 1.10E-02 1.10E-02 1.10E-02 1,2,3,4,7,8-HxCDD 1.35E-05 1.35E-06 1.35E-06 6.29E-03 6.29E-04 6.29E-04 1,2,3,6,7,8 -HxCDD 1.69E-05 1.69E-06 1.69E-06 7.86E-03 7.86E-04 7.86E-04 1,2,3,7,8,9-HxCDD 2.36E-05 2.36E-06 2.36E-06 1.10E-02 1.10E-03 1.10E-03 1,2,3,4,6,7,8- HpCDD 2.40E-04 2.40E-06 2.40E-06 1.12E-01 1.12E-03 1.12E-03 1,2,3,4,6,7,8,9 - OCDD 5.30E-04 1.59E-07 1.59E-07 2.47E-01 7.40E-05 7.40E-05 2,3,7,8 -TCDF 8.10E-05 8.10E-06 8.10E-06 3.77E-02 3.77E-03 3.77E-03 1,2,3,7,8-PeCDF 4.05E-05 1.22E-06 1.22E-06 1.89E-02 5.66E-04 5.66E-04 2,3,4,7,8 - PeCDF 7.09E-05 2.13E-05 2.13E-05 3.30E-02 9.90E-03 9.90E-03 1,2,3,4,7,8-HxCDF 7.09E-05 7.09E-06 7.09E-06 3.30E-02 3.30E-03 3.30E-03 1,2,3,6,7,8- HxCDF 5.06E-05 5.06E-06 5.06E-06 2.36E-02 2.36E-03 2.36E-03 1,2,3,7,8,9-HxCDF 2.03E-05 2.03E-06 2.03E-06 9.43E-03 9.43E-04 9.43E-04 2,3,4,6,7,8 - HxCDF 7.76E-05 7.76E-06 7.76E-06 3.62E-02 3.62E-03 3.62E-03 1,2,3,4,6,7,8- HpCDF 1.49E-04 1.49E-06 1.49E-06 6.92E-02 6.92E-04 6.92E-04 1,2,3,4,7,8,9- HpCDF 1.69E-05 1.69E-07 1.69E-07 7.86E-03 7.86E-05 7.86E-05 1,2,3,4,6,7,8,9-OCDF 7.09E-05 2.13E-08 2.13E-08 3.30E-02 9.90E-06 9.90E-06 TeCDD Total 7.24E-04 3.37E-01 PeCDD Total 4.02E-04 1.87E-01 HxCDD Total 3.55E-04 1.65E-01 HpCDD Total 4.40E-04 2.05E-01 OCDD 5.29E-04 2.46E-01 TeCDF Total 1.65E-03 7.67E-01 PeCDF Total 7.44E-04 3.46E-01 HxCDF Total 5.28E-04 2.46E-01 HpCDF Total 2.72E-04 1.27E-01 OCDF 7.12E-05 3.32E-02 PCDD Total 2.45E-03 1.14E+00 PCDF Total 3.26E-03 1.52E+00 PCDD/PCDF Total 5.71 E-03 2.66E+00 PCDD TEQ Total 3.16E-05 4.00E-05 1.47E-02 1.86E-02 PCDF TEQ Total 5.42E-05 5.42E-05 2.52E-02 2.52E-02 PCDD/PCDF TEQ Total 8.58E-05 9.42E-05 3.99E-02 4.39E-02 Table A-13. PCDD/PCDF data for SB/SL 1. PCDD/PCDF Page 1 (2) 24-A ------- Sample ID PS-PCDD-SB-SVOC-112014-01 MCE 0.980 Sampling volume (m3) 60.2 Carbon sampled (g) 68.1 Carbon sampled (mg/m3) 1129.9 Carbon fraction 0.45215 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 1.56E-03 1.56E-03 1.56E-03 2.58E-05 2.58E-05 2.58E-05 1,2,3,7,8- PeCDD 7.33E-03 7.33E-03 7.33E-03 1.22E-04 1.22E-04 1.22E-04 1,2,3,4,7,8- HxCDD 4.89E-03 4.89E-04 4.89E-04 8.11E-05 8.11E-06 8.11 E-06 1,2,3,6,7,8- HxCDD 1.49E-02 1.49E-03 1.49E-03 2.47E-04 2.47E-05 2.47E-05 1,2,3,7,8,9- HxCDD 1.09E-02 1.09E-03 1.09E-03 1.81 E-04 1.81E-05 1.81 E-05 1,2,3,4,6,7,8- HpCDD 2.44E-01 2.44E-03 2.44E-03 4.05E-03 4.05E-05 4.05E-05 1,2,3,4,6,7,8,9 - OCDD 7.46E-01 2.24E-04 2.24E-04 1.24E-02 3.71 E-06 3.71 E-06 2,3,7,8 - TCDF 2.64E-02 2.64E-03 2.64E-03 4.39E-04 4.39E-05 4.39E-05 1,2,3,7,8- PeCDF 8.67E-03 2.60E-04 2.60E-04 1.44E-04 4.32E-06 4.32E-06 2,3,4,7,8- PeCDF 1.27E-02 3.80E-03 3.80E-03 2.10E-04 6.31 E-05 6.31 E-05 1,2,3,4,7,8- HxCDF 7.78E-03 7.78E-04 7.78E-04 1.29E-04 1.29E-05 1.29E-05 1,2,3,6,7,8- HxCDF 5.11E-03 5.11E-04 5.11E-04 8.48E-05 8.48E-06 8.48E-06 1,2,3,7,8,9- HxCDF 2.44E-03 2.44E-04 2.44E-04 4.06E-05 4.06E-06 4.06E-06 2,3,4,6,7,8 - HxCDF 7.78E-03 7.78E-04 7.78E-04 1.29E-04 1.29E-05 1.29E-05 1,2,3,4,6,7,8- HpCDF 1.69E-02 1.69E-04 1.69E-04 2.80E-04 2.80E-06 2.80E-06 1,2,3,4,7,8,9- HpCDF 2.89E-03 2.89E-05 2.89E-05 4.79E-05 4.79E-07 4.79E-07 1,2,3,4,6,7,8,9-OCDF 2.09E-02 6.27E-06 6.27E-06 3.47E-04 1.04E-07 1.04E-07 TeCDD Total 7.68E-02 1.28E-03 PeCDD Total 5.64E-02 9.36E-04 HxCDD Total 1.25E-01 2.08E-03 HpCDD Total 3.87E-01 6.43E-03 OCDD 7.46E-01 1.24E-02 TeCDF Total 3.20E-01 5.31 E-03 PeCDF Total 1.08E-01 1.80E-03 HxCDF Total 5.62E-02 9.32E-04 HpCDF Total 4.23E-02 7.02E-04 OCDF 2.08E-02 3.46E-04 PCDD Total 1.39E+00 2.31 E-02 PCDF Total 5.47E-01 9.09E-03 PCDD/PCDF Total 1.94E+00 3.22E-02 PCDD TEQ Total 1.46E-02 1.46E-02 2.43E-04 2.43E-04 PCDF TEQ Total 9.22E-03 9.22E-03 1.53E-04 1.53E-04 PCDD/PCDF TEQ Total 2.38E-02 2.38E-02 3.96E-04 3.96E-04 Sam pie ID PS-PCDD-SB-SVOC-112014-01 Page 2 (2) 25-A ------- EF EF EF EF EF EF Total TEQ TEQ Total TEQ TEQ Isomer. ng/g Carbon ng/kg fiberboard ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 2.29E-05 2.29E-05 2.29E-05 1.03E-02 1.03E-02 1.03E-02 1,2,3,7,8- PeCDD 1.08E-04 1.08E-04 1.08E-04 4.87E-02 4.87E-02 4.87E-02 1,2,3,4,7,8- HxCDD 7.18E-05 7.18E-06 7.18E-06 3.25E-02 3.25E-03 3.25E-03 1,2,3,6,7,8- HxCDD 2.19E-04 2.19E-05 2.19E-05 9.89E-02 9.89E-03 9.89E-03 1,2,3,7,8,9- HxCDD 1.60E-04 1.60E-05 1.60E-05 7.23E-02 7.23E-03 7.23E-03 1,2,3,4,6,7,8- HpCDD 3.58E-03 3.58E-05 3.58E-05 1.62E+00 1.62E-02 1.62E-02 1,2,3,4,6,7,8,9 - OCDD 1.10E-02 3.29E-06 3.29E-06 4.95E+00 1.49E-03 1.49E-03 2,3,7,8 - TCDF 3.88E-04 3.88E-05 3.88E-05 1.76E-01 1.76E-02 1.76E-02 1,2,3,7,8- PeCDF 1.27E-04 3.82E-06 3.82E-06 5.76E-02 1.73E-03 1.73E-03 2,3,4,7,8- PeCDF 1.86E-04 5.58E-05 5.58E-05 8.41 E-02 2.52E-02 2.52E-02 1,2,3,4,7,8- HxCDF 1.14E-04 1.14E-05 1.14E-05 5.17E-02 5.17E-03 5.17E-03 1,2,3,6,7,8- HxCDF 7.51 E-05 7.51 E-06 7.51 E-06 3.39E-02 3.39E-03 3.39E-03 1,2,3,7,8,9- HxCDF 3.59E-05 3.59E-06 3.59E-06 1.62E-02 1.62E-03 1.62E-03 2,3,4,6,7,8 - HxCDF 1.14E-04 1.14E-05 1.14E-05 5.17E-02 5.17E-03 5.17E-03 1,2,3,4,6,7,8- HpCDF 2.48E-04 2.48E-06 2.48E-06 1.12E-01 1.12E-03 1.12E-03 1,2,3,4,7,8,9- HpCDF 4.24E-05 4.24E-07 4.24E-07 1.92E-02 1.92E-04 1.92E-04 1,2,3,4,6,7,8,9-OCDF 3.07E-04 9.21 E-08 9.21 E-08 1.39E-01 4.16E-05 4.16E-05 TeCDD Total 1.13E-03 5.10E-01 PeCDD Total 8.29E-04 3.75E-01 HxCDD Total 1.84E-03 8.32E-01 HpCDD Total 5.69E-03 2.57E+00 OCDD 1.10E-02 4.95E+00 TeCDF Total 4.70E-03 2.12E+00 PeCDF Total 1.59E-03 7.20E-01 HxCDF Total 8.25E-04 3.73E-01 HpCDF Total 6.21 E-04 2.81 E-01 OCDF 3.06E-04 1.38E-01 PCDD Total 2.04E-02 9.24E+00 PCDF Total 8.04E-03 3.64E+00 PCDD/PCDF Total 2.85E-02 1.29E+01 PCDD TEQ Total 2.15E-04 2.15E-04 9.71 E-02 9.71 E-02 PCDF TEQ Total 1.35E-04 1.35E-04 6.12E-02 6.12E-02 PCDD/PCDF TEQ Total 3.50E-04 3.50E-04 1.58E-01 1.58E-01 Table A-14. PCDD/PCDF data for SB/SL 2. PCDD/PCDF Page 1 (2) 26-A ------- Sample ID PS-PCDD-SB2-SV0C-11212014-02 MCE 0.982 Sampling volume (m3) 56.4 Carbon sampled (g) 63.4 Carbon sampled (mg/m3) 1123.4 Carbon fraction 0.452 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 2.00E-03 2.00E-03 2.00E-03 3.54E-05 3.54E-05 3.54E-05 1,2,3,7,8- PeCDD 6.89E-03 6.89E-03 6.89E-03 1.22E-04 1.22E-04 1.22E-04 1,2,3,4,7,8- HxCDD 4.22E-03 4.22E-04 4.22E-04 7.48E-05 7.48E-06 7.48E-06 1,2,3,6,7,8- HxCDD 1.44E-02 1.44E-03 1.44E-03 2.56E-04 2.56E-05 2.56E-05 1,2,3,7,8,9- HxCDD 1.00E-02 1.00E-03 1.00E-03 1.77E-04 1.77E-05 1.77E-05 1,2,3,4,6,7,8- HpCDD 2.14E-01 2.14E-03 2.14E-03 3.79E-03 3.79E-05 3.79E-05 1,2,3,4,6,7,8,9 - OCDD 6.48E-01 1.94E-04 1.94E-04 1.15E-02 3.45E-06 3.45E-06 2,3,7,8 - TCDF 4.16E-02 4.16E-03 4.16E-03 7.37E-04 7.37E-05 7.37E-05 1,2,3,7,8- PeCDF 1.09E-02 3.27E-04 3.27E-04 1.93E-04 5.79E-06 5.79E-06 2,3,4,7,8- PeCDF 1.36E-02 4.07E-03 4.07E-03 2.40E-04 7.21 E-05 7.21 E-05 1,2,3,4,7,8- HxCDF 6.67E-03 6.67E-04 6.67E-04 1.18E-04 1.18E-05 1.18E-05 1,2,3,6,7,8- HxCDF 4.44E-03 4.44E-04 4.44E-04 7.88E-05 7.88E-06 7.88E-06 1,2,3,7,8,9- HxCDF 1.78E-03 1.78E-04 1.78E-04 3.15E-05 3.15E-06 3.15E-06 2,3,4,6,7,8 - HxCDF 5.33E-03 5.33E-04 5.33E-04 9.45E-05 9.45E-06 9.45E-06 1,2,3,4,6,7,8- HpCDF 1.38E-02 1.38E-04 1.38E-04 2.44E-04 2.44E-06 2.44E-06 1,2,3,4,7,8,9- HpCDF 2.00E-03 2.00E-05 2.00E-05 3.54E-05 3.54E-07 3.54E-07 1,2,3,4,6,7,8,9-OCDF 1.84E-02 5.53E-06 5.53E-06 3.27E-04 9.81 E-08 9.81 E-08 TeCDD Total 6.59E-02 1.17E-03 PeCDD Total 5.67E-02 1.00E-03 HxCDD Total 1.15E-01 2.05E-03 HpCDD Total 3.40E-01 6.03E-03 OCDD 6.48E-01 1.15E-02 TeCDF Total 3.86E-01 6.84E-03 PeCDF Total 1.39E-01 2.47E-03 HxCDF Total 4.55E-02 8.06E-04 HpCDF Total 3.82E-02 6.78E-04 OCDF 1.84E-02 3.26E-04 PCDD Total 1.23E+00 2.17E-02 PCDF Total 6.27E-01 1.11 E-02 PCDD/PCDF Total 1.85E+00 3.28E-02 PCDD TEQ Total 1.41 E-02 1.41 E-02 2.50E-04 2.50E-04 PCDF TEQ Total 1.05E-02 1.05E-02 1.87E-04 1.87E-04 PCDD/PCDF TEQ Total 2.46E-02 2.46E-02 4.36E-04 4.36E-04 Sample ID PS-PCDD-SB2-SVOC-11212014-02 Page 2 (2) 27-A ------- EF EF EF EF EF EF Total TEQ TEQ Total TEQ TEQ Isomer. ng/g Carbon ng/kg fiberboard ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 3.16E-05 3.16E-05 3.16E-05 1.43E-02 1.43E-02 1.43E-02 1,2,3,7,8- PeCDD 1.09E-04 1.09E-04 1.09E-04 4.91 E-02 4.91 E-02 4.91 E-02 1,2,3,4,7,8- HxCDD 6.66E-05 6.66E-06 6.66E-06 3.01 E-02 3.01 E-03 3.01 E-03 1,2,3,6,7,8- HxCDD 2.28E-04 2.28E-05 2.28E-05 1.03E-01 1.03E-02 1.03E-02 1,2,3,7,8,9- HxCDD 1.58E-04 1.58E-05 1.58E-05 7.13E-02 7.13E-03 7.13E-03 1,2,3,4,6,7,8- HpCDD 3.37E-03 3.37E-05 3.37E-05 1.52E+00 1.52E-02 1.52E-02 1,2,3,4,6,7,8,9 - OCDD 1.02E-02 3.07E-06 3.07E-06 4.62E+00 1.39E-03 1.39E-03 2,3,7,8 - TCDF 6.56E-04 6.56E-05 6.56E-05 2.96E-01 2.96E-02 2.96E-02 1,2,3,7,8- PeCDF 1.72E-04 5.15E-06 5.15E-06 7.77E-02 2.33E-03 2.33E-03 2,3,4,7,8- PeCDF 2.14E-04 6.42E-05 6.42E-05 9.67E-02 2.90E-02 2.90E-02 1,2,3,4,7,8- HxCDF 1.05E-04 1.05E-05 1.05E-05 4.76E-02 4.76E-03 4.76E-03 1,2,3,6,7,8- HxCDF 7.01 E-05 7.01 E-06 7.01 E-06 3.17E-02 3.17E-03 3.17E-03 1,2,3,7,8,9- HxCDF 2.80E-05 2.80E-06 2.80E-06 1.27E-02 1.27E-03 1.27E-03 2,3,4,6,7,8 - HxCDF 8.41 E-05 8.41 E-06 8.41 E-06 3.80E-02 3.80E-03 3.80E-03 1,2,3,4,6,7,8- HpCDF 2.17E-04 2.17E-06 2.17E-06 9.83E-02 9.83E-04 9.83E-04 1,2,3,4,7,8,9- HpCDF 3.16E-05 3.16E-07 3.16E-07 1.43E-02 1.43E-04 1.43E-04 1,2,3,4,6,7,8,9-OCDF 2.91 E-04 8.73E-08 8.73E-08 1.32E-01 3.95E-05 3.95E-05 TeCDD Total 1.04E-03 4.70E-01 PeCDD Total 8.94E-04 4.04E-01 HxCDD Total 1.82E-03 8.24E-01 HpCDD Total 5.37E-03 2.43E+00 OCDD 1.02E-02 4.62E+00 TeCDF Total 6.09E-03 2.75E+00 PeCDF Total 2.19E-03 9.92E-01 HxCDF Total 7.18E-04 3.24E-01 HpCDF Total 6.03E-04 2.73E-01 OCDF 2.90E-04 1.31 E-01 PCDD Total 1.93E-02 8.75E+00 PCDF Total 9.90E-03 4.47E+00 PCDD/PCDF Total 2.92E-02 1.32E+01 PCDD TEQ Total 2.22E-04 2.22E-04 1.00E-01 1.00E-01 PCDF TEQ Total 1.66E-04 1.66E-04 7.51 E-02 7.51 E-02 PCDD/PCDF TEQ Total 3.88E-04 3.88E-04 1.76E-01 1.76E-01 820 Table A-15. PCDD/PCDF data for SB/SL 3. PCDD/PCDF Page 1 (2) Sample ID PS-PCDD-SB3-SVOC-120314-01 MCE 0.969 28-A ------- Sampling volume (m3) 73.1 Carbon sampled (g) 49.7 Carbon sampled (mg/m3) 679.5 Carbon fraction 0.4522 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 4.89E-03 4.89E-03 4.89E-03 6.69E-05 6.69E-05 6.69E-05 1,2,3,7,8- PeCDD 2.22E-02 2.22E-02 2.22E-02 3.04E-04 3.04E-04 3.04E-04 1,2,3,4,7,8- HxCDD 1.24E-02 1.24E-03 1.24E-03 1.70E-04 1.70E-05 1.70E-05 1,2,3,6,7,8- HxCDD 3.80E-02 3.80E-03 3.80E-03 5.20E-04 5.20E-05 5.20E-05 1,2,3,7,8,9- HxCDD 2.89E-02 2.89E-03 2.89E-03 3.95E-04 3.95E-05 3.95E-05 1,2,3,4,6,7,8- HpCDD 4.43E-01 4.43E-03 4.43E-03 6.06E-03 6.06E-05 6.06E-05 1,2,3,4,6,7,8,9 - OCDD 1.13E+00 3.38E-04 3.38E-04 1.54E-02 4.62E-06 4.62E-06 2,3,7,8 - TCDF 2.58E-02 2.58E-03 2.58E-03 3.53E-04 3.53E-05 3.53E-05 1,2,3,7,8- PeCDF 7.33E-03 2.20E-04 2.20E-04 1.00E-04 3.01 E-06 3.01 E-06 2,3,4,7,8- PeCDF 8.44E-03 2.53E-03 2.53E-03 1.15E-04 3.46E-05 3.46E-05 1,2,3,4,7,8- HxCDF 3.56E-03 3.56E-04 3.56E-04 4.86E-05 4.86E-06 4.86E-06 1,2,3,6,7,8- HxCDF 4.22E-03 4.22E-04 4.22E-04 5.77E-05 5.77E-06 5.77E-06 1,2,3,7,8,9- HxCDF 1.56E-03 1.56E-04 1.56E-04 2.13E-05 2.13E-06 2.13E-06 2,3,4,6,7,8 - HxCDF 5.56E-03 5.56E-04 5.56E-04 7.60E-05 7.60E-06 7.60E-06 1,2,3,4,6,7,8- HpCDF 1.67E-02 1.67E-04 1.67E-04 2.28E-04 2.28E-06 2.28E-06 1,2,3,4,7,8,9- HpCDF 3.33E-03 3.33E-05 3.33E-05 4.56E-05 4.56E-07 4.56E-07 1,2,3,4,6,7,8,9-OCDF 2.20E-02 6.60E-06 6.60E-06 3.01 E-04 9.03E-08 9.03E-08 TeCDD Total 1.26E-01 1.73E-03 PeCDD Total 1.36E-01 1.86E-03 HxCDD Total 3.09E-01 4.22E-03 HpCDD Total 7.06E-01 9.65E-03 OCDD 1.13E+00 1.54E-02 TeCDF Total 2.98E-01 4.08E-03 PeCDF Total 8.80E-02 1.20E-03 HxCDF Total 4.13E-02 5.65E-04 HpCDF Total 4.74E-02 6.48E-04 OCDF 2.20E-02 3.01 E-04 PCDD Total 2.40E+00 3.29E-02 PCDF Total 4.97E-01 6.80E-03 PCDD/PCDF Total 2.90E+00 3.97E-02 PCDD TEQ Total 3.98E-02 3.98E-02 5.44E-04 5.44E-04 PCDF TEQ Total 7.03E-03 7.03E-03 9.61 E-05 9.61 E-05 PCDD/PCDF TEQ Total 4.68E-02 4.68E-02 6.41 E-04 6.41 E-04 Sam pie ID PS-PCDD-SB3-SVOC-120314-01 Page 2 (2) 29-A ------- EF EF EF EF EF EF Total TEQ TEQ Total TEQ TEQ Isomer. ng/g Carbon ng/kg fiberboard ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 9.84E-05 9.84E-05 9.84E-05 4.45E-02 4.45E-02 4.45E-02 1,2,3,7,8- PeCDD 4.47E-04 4.47E-04 4.47E-04 2.02E-01 2.02E-01 2.02E-01 1,2,3,4,7,8- HxCDD 2.50E-04 2.50E-05 2.50E-05 1.13E-01 1.13E-02 1.13E-02 1,2,3,6,7,8- HxCDD 7.65E-04 7.65E-05 7.65E-05 3.46E-01 3.46E-02 3.46E-02 1,2,3,7,8,9- HxCDD 5.81 E-04 5.81 E-05 5.81 E-05 2.63E-01 2.63E-02 2.63E-02 1,2,3,4,6,7,8- HpCDD 8.91 E-03 8.91 E-05 8.91 E-05 4.03E+00 4.03E-02 4.03E-02 1,2,3,4,6,7,8,9 - OCDD 2.27E-02 6.81 E-06 6.81 E-06 1.03E+01 3.08E-03 3.08E-03 2,3,7,8 - TCDF 5.19E-04 5.19E-05 5.19E-05 2.35E-01 2.35E-02 2.35E-02 1,2,3,7,8- PeCDF 1.48E-04 4.43E-06 4.43E-06 6.67E-02 2.00E-03 2.00E-03 2,3,4,7,8- PeCDF 1.70E-04 5.10E-05 5.10E-05 7.68E-02 2.31 E-02 2.31 E-02 1,2,3,4,7,8- HxCDF 7.16E-05 7.16E-06 7.16E-06 3.24E-02 3.24E-03 3.24E-03 1,2,3,6,7,8- HxCDF 8.50E-05 8.50E-06 8.50E-06 3.84E-02 3.84E-03 3.84E-03 1,2,3,7,8,9- HxCDF 3.13E-05 3.13E-06 3.13E-06 1.42E-02 1.42E-03 1.42E-03 2,3,4,6,7,8 - HxCDF 1.12E-04 1.12E-05 1.12E-05 5.06E-02 5.06E-03 5.06E-03 1,2,3,4,6,7,8- HpCDF 3.35E-04 3.35E-06 3.35E-06 1.52E-01 1.52E-03 1.52E-03 1,2,3,4,7,8,9- HpCDF 6.71 E-05 6.71 E-07 6.71 E-07 3.03E-02 3.03E-04 3.03E-04 1,2,3,4,6,7,8,9-OCDF 4.43E-04 1.33E-07 1.33E-07 2.00E-01 6.01 E-05 6.01 E-05 TeCDD Total 2.54E-03 1.15E+00 PeCDD Total 2.73E-03 1.24E+00 HxCDD Total 6.21 E-03 2.81 E+00 HpCDD Total 1.42E-02 6.42E+00 OCDD 2.27E-02 1.03E+01 TeCDF Total 6.01 E-03 2.72E+00 PeCDF Total 1.77E-03 8.01 E-01 HxCDF Total 8.31 E-04 3.76E-01 HpCDF Total 9.54E-04 4.31 E-01 OCDF 4.43E-04 2.00E-01 PCDD Total 4.84E-02 2.19E+01 PCDF Total 1.00E-02 4.52E+00 PCDD/PCDF Total 5.84E-02 2.64E+01 PCDD TEQ Total 8.01 E-04 8.01 E-04 3.62E-01 3.62E-01 PCDF TEQ Total 1.41 E-04 1.41 E-04 6.39E-02 6.39E-02 PCDD/PCDF TEQ Total 9.43E-04 9.43E-04 4.26E-01 4.26E-01 825 Table A-16. PCDD/PCDF data for SB/SL 4. PCDD/PCDF Page 1 (2) Sample ID PS-PCDD-SB4-SV0C-120414-01 MCE 0.971 30-A ------- Sampling volume (m3) 96.4 Carbon sampled (g) 63.3 Carbon sampled (mg/m3) 656.4 Carbon fraction 0.4522 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 5.78E-03 5.78E-03 5.78E-03 5.99E-05 5.99E-05 5.99E-05 1,2,3,7,8- PeCDD 2.40E-02 2.40E-02 2.40E-02 2.49E-04 2.49E-04 2.49E-04 1,2,3,4,7,8- HxCDD 1.29E-02 1.29E-03 1.29E-03 1.34E-04 1.34E-05 1.34E-05 1,2,3,6,7,8- HxCDD 3.93E-02 3.93E-03 3.93E-03 4.08E-04 4.08E-05 4.08E-05 1,2,3,7,8,9- HxCDD 2.96E-02 2.96E-03 2.96E-03 3.07E-04 3.07E-05 3.07E-05 1,2,3,4,6,7,8- HpCDD 4.08E-01 4.08E-03 4.08E-03 4.23E-03 4.23E-05 4.23E-05 1,2,3,4,6,7,8,9 - OCDD 1.06E+00 3.17E-04 3.17E-04 1.10E-02 3.29E-06 3.29E-06 2,3,7,8 -TCDF 3.44E-02 3.44E-03 3.44E-03 3.57E-04 3.57E-05 3.57E-05 1,2,3,7,8- PeCDF 9.56E-03 2.87E-04 2.87E-04 9.91 E-05 2.97E-06 2.97E-06 2,3,4,7,8- PeCDF 1.18E-02 3.53E-03 3.53E-03 1.22E-04 3.67E-05 3.67E-05 1,2,3,4,7,8- HxCDF 6.89E-03 6.89E-04 6.89E-04 7.15E-05 7.15E-06 7.15E-06 1,2,3,6,7,8- HxCDF 5.11E-03 5.11E-04 5.11E-04 5.30E-05 5.30E-06 5.30E-06 1,2,3,7,8,9- HxCDF 1.78E-03 1.78E-04 1.78E-04 1.84E-05 1.84E-06 1.84E-06 2,3,4,6,7,8 - HxCDF 6.00E-03 6.00E-04 6.00E-04 6.22E-05 6.22E-06 6.22E-06 1,2,3,4,6,7,8- HpCDF 1.80E-02 1.80E-04 1.80E-04 1.87E-04 1.87E-06 1.87E-06 1,2,3,4,7,8,9- HpCDF 3.56E-03 3.56E-05 3.56E-05 3.69E-05 3.69E-07 3.69E-07 1,2,3,4,6,7,8,9-OCDF 2.49E-02 7.47E-06 7.47E-06 2.58E-04 7.75E-08 7.75E-08 TeCDD Total 1.71 E-01 1.78E-03 PeCDD Total 1.66E-01 1.72E-03 HxCDD Total 3.13E-01 3.25E-03 HpCDD Total 6.63E-01 6.88E-03 OCDD 1.06E+00 1.10E-02 TeCDF Total 4.17E-01 4.32E-03 PeCDF Total 1.17E-01 1.22E-03 HxCDF Total 5.09E-02 5.28E-04 HpCDF Total 4.99E-02 5.18E-04 OCDF 2.49E-02 2.59E-04 PCDD Total 2.37E+00 2.46E-02 PCDF Total 6.60E-01 6.84E-03 PCDD/PCDF Total 3.03E+00 3.14E-02 PCDD TEQ Total 4.24E-02 4.24E-02 4.39E-04 4.39E-04 PCDF TEQ Total 9.47E-03 9.47E-03 9.82E-05 9.82E-05 PCDD/PCDF TEQ Total 5.18E-02 5.18E-02 5.38E-04 5.38E-04 Sample ID PS-PCDD-SB4-SVOC-120414-01 Page 2 (2) EFEFEFEFEFEF 31-A ------- Total TEQ TEQ Total TEQ TEQ Isomer. ng/g Carbon ng/kg fiberboard ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8-TCDD 9.13E-05 9.13E-05 9.13E-05 4.13E-02 4.13E-02 4.13E-02 1,2,3,7,8 -PeCDD 3.79E-04 3.79E-04 3.79E-04 1.72E-01 1.72E-01 1.72E-01 1,2,3,4,7,8 -HxCDD 2.04E-04 2.04E-05 2.04E-05 9.21 E-02 9.21 E-03 9.21 E-03 1,2,3,6,7,8 -HxCDD 6.22E-04 6.22E-05 6.22E-05 2.81 E-01 2.81 E-02 2.81 E-02 1,2,3,7,8,9-HxCDD 4.67E-04 4.67E-05 4.67E-05 2.11E-01 2.11 E-02 2.11 E-02 1,2,3,4,6,7,8- HpCDD 6.44E-03 6.44E-05 6.44E-05 2.91 E+00 2.91 E-02 2.91 E-02 1,2,3,4,6,7,8,9 - OCDD 1.67E-02 5.02E-06 5.02E-06 7.56E+00 2.27E-03 2.27E-03 2,3,7,8 -TCDF 5.44E-04 5.44E-05 5.44E-05 2.46E-01 2.46E-02 2.46E-02 1,2,3,7,8-PeCDF 1.51E-04 4.53E-06 4.53E-06 6.83E-02 2.05E-03 2.05E-03 2,3,4,7,8 - PeCDF 1.86E-04 5.58E-05 5.58E-05 8.42E-02 2.52E-02 2.52E-02 1,2,3,4,7,8-HxCDF 1.09E-04 1.09E-05 1.09E-05 4.92E-02 4.92E-03 4.92E-03 1,2,3,6,7,8-HxCDF 8.08E-05 8.08E-06 8.08E-06 3.65E-02 3.65E-03 3.65E-03 1,2,3,7,8,9- HxCDF 2.81 E-05 2.81 E-06 2.81 E-06 1.27E-02 1.27E-03 1.27E-03 2,3,4,6,7,8 - HxCDF 9.48E-05 9.48E-06 9.48E-06 4.29E-02 4.29E-03 4.29E-03 1,2,3,4,6,7,8- HpCDF 2.84E-04 2.84E-06 2.84E-06 1.29E-01 1.29E-03 1.29E-03 1,2,3,4,7,8,9- HpCDF 5.62E-05 5.62E-07 5.62E-07 2.54E-02 2.54E-04 2.54E-04 1,2,3,4,6,7,8,9-OCDF 3.93E-04 1.18E-07 1.18E-07 1.78E-01 5.34E-05 5.34E-05 TeCDD Total 2.70E-03 1.22E+00 PeCDD Total 2.62E-03 1.18E+00 HxCDD Total 4.95E-03 2.24E+00 HpCDD Total 1.05E-02 4.74E+00 OCDD 1.67E-02 7.56E+00 TeCDF Total 6.59E-03 2.98E+00 PeCDF Total 1.85E-03 8.37E-01 HxCDF Total 8.05E-04 3.64E-01 HpCDF Total 7.88E-04 3.56E-01 OCDF 3.94E-04 1.78E-01 PCDD Total 3.75E-02 1.69E+01 PCDF Total 1.04E-02 4.71 E+00 PCDD/PCDF Total 4.79E-02 2.17E+01 PCDD TEQ Total 6.69E-04 6.69E-04 3.03E-01 3.03E-01 PCDF TEQ Total 1.50E-04 1.50E-04 6.76E-02 6.76E-02 PCDD/PCDF TEQ Total 8.19E-04 8.19E-04 3.70E-01 3.70E-01 830 Table A-16. Pre-test background PCDD/PCDF concentrations. PCDD/PCDF - Ambient/Background concentrations Page 1 (1) Sample ID BS-PCDD-SVOC-111414 Sampling volume (m3) 279.5 32-A ------- TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8-TCDD 2.22E-04 2.22E-04 2.22E-04 7.95E-07 7.95E-07 7.95E-07 1,2,3,7,8-PeCDD 8.89E-04 8.89E-04 8.89E-04 3.18E-06 3.18E-06 3.18E-06 1,2,3,4,7,8-HxCDD 6.67E-04 6.67E-05 6.67E-05 2.38E-06 2.38E-07 2.38E-07 1,2,3,6,7,8 -HxCDD 1.33E-03 1.33E-04 1.33E-04 4.77E-06 4.77E-07 4.77E-07 1,2,3,7,8,9-HxCDD 1.33E-03 1.33E-04 1.33E-04 4.77E-06 4.77E-07 4.77E-07 1,2,3,4,6,7,8- HpCDD 1.76E-02 1.76E-04 1.76E-04 6.28E-05 6.28E-07 6.28E-07 1,2,3,4,6,7,8,9 - OCDD 4.96E-02 1.49E-05 1.49E-05 1.77E-04 5.32E-08 5.32E-08 2,3,7,8 -TCDF 6.67E-04 6.67E-05 6.67E-05 2.38E-06 2.38E-07 2.38E-07 1,2,3,7,8-PeCDF 8.89E-04 2.67E-05 2.67E-05 3.18E-06 9.54E-08 9.54E-08 2,3,4,7,8 - PeCDF 6.67E-04 2.00E-04 2.00E-04 2.38E-06 7.15E-07 7.15E-07 1,2,3,4,7,8-HxCDF 8.89E-04 8.89E-05 8.89E-05 3.18E-06 3.18E-07 3.18E-07 1,2,3,6,7,8-HxCDF 8.89E-04 8.89E-05 8.89E-05 3.18E-06 3.18E-07 3.18E-07 1,2,3,7,8,9-HxCDF 4.44E-04 4.44E-05 4.44E-05 1.59E-06 1.59E-07 1.59E-07 2,3,4,6,7,8 - HxCDF 1.33E-03 1.33E-04 1.33E-04 4.77E-06 4.77E-07 4.77E-07 1,2,3,4,6,7,8- HpCDF 4.44E-03 4.44E-05 4.44E-05 1.59E-05 1.59E-07 1.59E-07 1,2,3,4,7,8,9- HpCDF 6.67E-04 6.67E-06 6.67E-06 2.38E-06 2.38E-08 2.38E-08 1,2,3,4,6,7,8,9-OCDF 4.22E-03 1.27E-06 1.27E-06 1.51 E-05 4.53E-09 4.53E-09 TeCDD Total 1.17E-02 4.19E-05 PeCDD Total 1.01 E-02 3.63E-05 HxCDD Total 1.66E-02 5.95E-05 HpCDD Total 3.85E-02 1.38E-04 OCDD 4.94E-02 1.77E-04 TeCDF Total 2.84E-02 1.02E-04 PeCDF Total 1.30E-02 4.66E-05 HxCDF Total 6.78E-03 2.42E-05 HpCDF Total 8.16E-03 2.92E-05 OCDF 4.53E-03 1.62E-05 PCDD Total 1.26E-01 4.52E-04 PCDF Total 6.09E-02 2.18E-04 PCDD/PCDF Total 1.87E-01 6.70E-04 PCDD TEQ Total 1.63E-03 1.63E-03 5.85E-06 5.85E-06 PCDF TEQ Total 7.01 E-04 7.01 E-04 2.51 E-06 2.51 E-06 PCDD/PCDF TEQ Total 2.34E-03 2.34E-03 8.36E-06 8.36E-06 Table A-17. PAH emission factors for NWS. NWS1 NWS3 NWS4 PAH mg/kg Fiberboard Naphthalene 11.48 51.89 21.57 33-A ------- Acenaphthylene 7.95 24.09 8.17 Acenaphthene 0.44 1.20 0.40 Fluorene 2.75 4.70 1.49 Phenanthrene 12.25 13.38 4.72 Anthracene 3.22 3.05 0.97 Fluoranthene 6.48 6.45 1.83 Pyrene 6.10 5.87 1.64 Benzo(a)anthracene 1.63 1.47 0.43 Chrysene 1.47 1.35 0.43 Benzo(b)fluoranthene 0.86 0.74 0.26 Benzo(k)fluoranthene 1.16 1.18 0.38 Benzo(a)pyrene 1.34 1.32 0.38 lndeno(1,2,3-cd)pyrene 0.87 0.82 0.27 Dibenz(a,h)anthracene 0.17 0.13 0.04 Benzo(ghi)perylene 0.91 0.96 0.30 SUM 16-EPA PAH 59.09 118.61 43.29 Table A-18. PAH emission factors for CB/CL. CB1/CL1 CB2/CL2 CB3/CL3 CB4/CL4 PAH mg/kg Fiberboard Naphthalene 10.77 6.97 5.50 5.36 Acenaphthylene 5.35 3.03 2.35 2.37 Acenaphthene 0.30 0.14 0.12 0.11 Fluorene 1.21 0.66 0.55 0.54 Phenanthrene 4.30 2.81 2.47 2.34 Anthracene 0.91 0.57 0.50 0.46 Fluoranthene 2.46 1.52 1.27 1.22 Pyrene 2.42 1.46 1.20 1.20 Benzo(a)anthracene 0.53 0.28 0.24 0.25 Chrysene 0.48 0.28 0.24 0.25 Benzo(b)fluoranthene 0.28 0.17 0.14 0.13 Benzo(k)fluoranthene 0.36 0.20 0.19 0.19 Benzo(a)pyrene 0.39 0.21 0.19 0.20 lndeno(1,2,3-cd)pyrene 0.24 0.15 0.13 0.14 Dibenz(a,h)anthracene 0.046 0.027 0.020 0.020 Benzo(ghi)perylene 0.29 0.18 0.14 0.15 SUM 16-EPA PAH 30.31 18.66 15.25 14.93 Table A-19. PAH emission factors for NSB/NSL. NSB1/NSL1 NSB2/NSL2 NSB3/NSL3 NSB4/NSL4 PAH mg/kg Fiberboard Naphthalene 6.58 29.31 24.36 23.72 34-A ------- Acenaphthylene 2.91 8.81 8.02 7.89 Acenaphthene 0.15 0.60 0.49 0.46 Fluorene 0.66 2.00 1.55 1.49 Phenanthrene 2.60 5.61 4.81 4.64 Anthracene 0.54 1.32 1.05 1.05 Fluoranthene 1.35 1.98 1.84 1.91 Pyrene 1.31 1.86 1.68 1.77 Benzo(a)anthracene 0.28 0.59 0.45 0.43 Chrysene 0.27 0.54 0.43 0.41 Benzo(b)fluoranthene 0.16 0.32 0.22 0.21 Benzo(k)fluoranthene 0.19 0.28 0.31 0.29 Benzo(a)pyrene 0.21 0.37 0.34 0.33 lndeno(1,2,3-cd)pyrene 0.14 0.22 0.22 0.21 Dibenz(a,h)anthracene 0.026 0.050 0.043 0.031 Benzo(ghi)perylene 0.16 0.24 0.23 0.21 SUM 16-EPA PAH 17.55 54.10 46.04 45.05 Table A-20. PAH emission factors for SB/SL. SB1/SL1 SB2/SL2 SB3/SL3 SB4/SL4 PAH mg/kg Fiberboard Naphthalene 10.61 11.12 12.13 24.58 Acenaphthylene 3.44 3.33 4.60 7.99 Acenaphthene 0.22 0.20 0.34 0.64 Fluorene 1.16 1.09 2.04 2.74 Phenanthrene 4.21 4.23 9.31 9.55 Anthracene 0.94 0.93 2.32 2.54 Fluoranthene 1.70 1.65 3.70 3.75 Pyrene 1.56 1.47 3.29 3.48 Benzo(a)anthracene 0.45 0.45 0.98 1.11 Chrysene 0.43 0.43 0.98 1.04 Benzo(b)fluoranthene 0.21 0.19 0.44 0.50 Benzo(k)fluoranthene 0.27 0.25 0.49 0.59 Benzo(a)pyrene 0.28 0.26 0.58 0.69 lndeno(1,2,3-cd)pyrene 0.17 0.16 0.36 0.41 Dibenz(a,h)anthracene 0.036 0.034 0.091 0.11 Benzo(ghi)perylene 0.19 0.16 0.33 0.40 SUM 16-EPA PAH 25.88 25.96 41.98 60.12 Table A-21. TEQ PAH emission factors for NWS. NWS1 NWS3 NWS4 PAH mg B[a]P TEQ/kg Fiberboard Naphthalene NA NA NA 35-A ------- Acenaphthylene NA NA NA Acenaphthene NA NA NA Fluorene NA NA NA Phenanthrene 6.13E-03 6.69E-03 2.36E-03 Anthracene 1.61E-03 1.52E-03 4.86E-04 Fluoranthene 3.24E-01 3.22E-01 9.17E-02 Pyrene 6.10E-03 5.87E-03 1.64E-03 Benzo(a)anthracene 8.17E-03 7.36E-03 2.17E-03 Chrysene 4.40E-02 4.05E-02 1.28E-02 Benzo(b)fluoranthene 8.64E-02 7.37E-02 2.58E-02 Benzo(k)fluoranthene 5.78E-02 5.92E-02 1.92E-02 Benzo(a)pyrene 1.34E+00 1.32E+00 3.85E-01 lndeno(1,2,3-cd)pyrene 8.75E-02 8.22E-02 2.70E-02 Dibenz(a,h)anthracene 0.00E+00 1.42E-01 4.34E-02 Benzo(ghi)perylene 1.83E-02 1.93E-02 6.08E-03 SUM 16-EPA PAH 1.98E+00 2.08E+00 6.17E-01 Table A-22. TEQ PAH emission factors for CB/CL. CB1/CL1 CB2/CL2 CB3/CL3 CB4/CL4 PAH mg B[a]P TEQ/kg Fiberboard Naphthalene NA NA NA NA Acenaphthylene NA NA NA NA Acenaphthene NA NA NA NA Fluorene NA NA NA NA Phenanthrene 2.15E-03 1.41E-03 1.24E-03 .17E-03 Anthracene 4.57E-04 2.84E-04 2.50E-04 2.31 E-04 Fluoranthene 1.23E-01 7.62E-02 6.35E-02 6.10E-02 Pyrene 2.42E-03 1.46E-03 1.20E-03 1.20E-03 Benzo(a)anthracene 2.63E-03 1.40E-03 1.22E-03 1.25E-03 Chrysene 1.44E-02 8.42E-03 7.14E-03 7.49E-03 Benzo(b)fluoranthene 2.78E-02 1.70E-02 1.38E-02 1.33E-02 Benzo(k)fluoranthene 1.80E-02 9.76E-03 9.33E-03 9.41 E-03 Benzo(a)pyrene 3.87E-01 2.12E-01 1.87E-01 1.95E-01 lndeno(1,2,3-cd)pyrene 2.37E-02 1.53E-02 1.26E-02 1.36E-02 Dibenz(a,h)anthracene 5.08E-02 3.01 E-02 2.21 E-02 2.25E-02 Benzo(ghi)perylene 5.77E-03 3.52E-03 2.90E-03 3.01 E-03 SUM 16-EPA PAH 6.58E-01 3.77E-01 3.22E-01 3.30E-01 Table A-23. TEQ PAH emission factors for NSB/NSL. NSB1/NSL1 NSB2/NSL2 NSB3/NSL3 NSB4/NSL4 PAH mg B[a]P TEQ/kg Fiberboard Naphthalene NA NA NA NA 36-A ------- Acenaphthylene NA NA NA NA Acenaphthene NA NA NA NA Fluorene NA NA NA NA Phenanthrene 1.30E-03 2.81 E-03 2.40E-03 2.32E-03 Anthracene 2.70E-04 6.60E-04 5.25E-04 5.27E-04 Fluoranthene 6.73E-02 9.88E-02 9.19E-02 9.55E-02 Pyrene 1.31E-03 1.86E-03 1.68E-03 1.77E-03 Benzo(a)anthracene 1.40E-03 2.95E-03 2.26E-03 2.14E-03 Chrysene 8.12E-03 1.61E-02 1.29E-02 1.22E-02 Benzo(b)fluoranthene 1.57E-02 3.22E-02 2.25E-02 2.13E-02 Benzo(k)fluoranthene 9.31 E-03 1.38E-02 1.56E-02 1.43E-02 Benzo(a)pyrene 2.14E-01 3.67E-01 3.36E-01 3.31 E-01 lndeno(1,2,3-cd)pyrene 1.44E-02 2.18E-02 2.15E-02 2.08E-02 Dibenz(a,h)anthracene 0.00E+00 5.48E-02 4.71 E-02 3.39E-02 Benzo(ghi)perylene 3.27E-03 4.83E-03 4.65E-03 4.14E-03 SUM 16-EPA PAH 3.37E-01 6.18E-01 5.59E-01 5.40E-01 Table A-24. TEQ PAH emission factors for SB/SL. SB1/SL1 SB2/SL2 SB3/SL3 SB4/SL4 PAH mg B[a]P TEQ/kg Fiberboard Naphthalene NA NA NA NA Acenaphthylene NA NA NA NA Acenaphthene NA NA NA NA Fluorene NA NA NA NA Phenanthrene 2.11 E-03 2.11 E-03 4.65E-03 4.77E-03 Anthracene 4.71 E-04 4.66E-04 1.16E-03 1.27E-03 Fluoranthene 8.49E-02 8.26E-02 1.85E-01 1.88E-01 Pyrene 1.56E-03 1.47E-03 3.29E-03 3.48E-03 Benzo(a)anthracene 2.25E-03 2.25E-03 4.90E-03 5.54E-03 Chrysene 1.28E-02 1.30E-02 2.93E-02 3.13E-02 Benzo(b)fluoranthene 2.10E-02 1.89E-02 4.37E-02 4.98E-02 Benzo(k)fluoranthene 1.35E-02 1.24E-02 2.45E-02 2.94E-02 Benzo(a)pyrene 2.79E-01 2.62E-01 5.85E-01 6.94E-01 lndeno(1,2,3-cd)pyrene 1.71 E-02 1.63E-02 3.62E-02 4.10E-02 Dibenz(a,h)anthracene 0.00E+00 3.78E-02 9.97E-02 1.18E-01 Benzo(ghi)perylene 3.72E-03 3.29E-03 6.63E-03 8.02E-03 SUM 16-EPA PAH 4.39E-01 4.53E-01 1.02E+00 1.17E+00 Table A-25: PM Emission Factors. EF PM2.5 EF PM10 Date Matrix g/kg Fiberboard 11/19/2014 NSB/NSL 2.8 2.9 37-A ------- 11/19/2014 NSB/NSL 2.7 2.8 12/11/2014 NSB/NSL 2.5 2.5 12/11/2014 NSB/NSL 8.3 7.5 12/17/2014 NSB/NSL 3.0 3.0 12/17/2014 NSB/NSL 2.7 2.8 12/17/2014 NSB/NSL 2.6 2.7 12/17/2014 NSB/NSL 2.9 3.0 11/17/2014 NWS 2.6 2.7 11/17/2014 NWS 3.5 3.9 11/17/2014 NWS 3.5 3.4 11/18/2014 NWS 3.4 3.5 11/18/2014 NWS 3.4 3.2 12/08/2014 NWS 5.1 5.1 12/09/2014 NWS 3.3 3.7 12/09/2014 NWS 2.9 3.3 12/10/2014 NWS 2.6 2.7 12/10/2014 NWS 4.1 4.2 11/20/2014 SB/SL 2.4 2.3 11/20/2014 SB/SL 2.0 1.9 11/21/2014 SB/SL 2.9 2.4 11/21/2014 SB/SL 1.9 2.0 12/03/2014 SB/SL 4.4 4.5 12/04/2014 SB/SL 2.9 2.9 12/04/2014 SB/SL 3.2 3.0 11/18/2014 CB/CL 3.1 3.1 11/18/2014 CB/CL 3.0 3.0 11/19/2014 CB/CL 3.4 3.5 11/19/2014 CB/CL 3.3 3.4 11/20/2014 CB/CL 2.7 2.7 11/20/2014 CB/CL 3.1 3.4 11/21/2014 CB/CL 3.1 3.1 11/21/2014 CB/CL 1.4 1.3 Table A-26. VOC emission factors from current fiberboard Solid Boxes and Liners (CB/CL). Current Fiberboard Solid Box and Liner (CB/CL) 12 3 4 38-A ------- Method detection limit Method detection limit Method detection limit Method detection limit Compound EF EF EF EF EF EF EF EF mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg Propene 100.64 0.18 19.63 0.11 16.20 0.09 16.70 0.06 Dichlorodifluoromethane (CFC-12) ND 0.22 ND 0.13 ND 0.11 ND 0.08 Chloromethane 4.49 0.19 2.76 0.11 1.31 0.09 1.45 0.07 1,2-Dichloro-1,1,2,2- tetrafluoroethane (CFC 114) ND 0.24 ND 0.14 ND 0.12 ND 0.09 Vinyl Chloride 0.22 0.22 ND 0.13 ND 0.11 ND 0.08 1,3-Butadiene 52.33 0.28 10.10 0.17 8.10 0.14 5.77 0.10 Bromomethane ND 0.24 ND 0.14 ND 0.12 ND 0.09 Chloroethane ND 0.22 ND 0.13 ND 0.11 ND 0.08 Ethanol 5.94 1.01 1.10 0.61 1.02 0.51 0.38 0.36 Aceto nit rile 2.82 0.23 0.78 0.14 0.58 0.11 0.56 0.08 Acrolein 3.02 0.22 8.37 0.13 12.72 0.11 13.51 0.08 Acetone 83.43 1.00 13.25 0.58 ND 0.49 8.34 0.35 Trichlorofluoromethane ND 0.22 ND 0.13 ND 0.11 ND 0.08 2-Propanol (Isopropyl Alcohol) ND 0.54 ND 0.32 ND 0.25 ND 0.18 Acrylonitrile 1.31 0.22 0.35 0.13 0.28 0.11 0.24 0.08 1,1-Dichloroethene ND 0.22 ND 0.13 ND 0.11 ND 0.08 Methylene Chloride 11.78 0.22 7.71 0.13 2.24 0.11 0.14 0.08 3-Chloro-1 -propene (Allyl Chloride) ND 0.20 ND 0.12 ND 0.10 ND 0.07 Trichlorotrifluoroethane 0.01 0.22 ND 0.13 ND 0.11 ND 0.08 Carbon Disulfide 2.42 0.19 0.84 0.11 1.25 0.09 1.21 0.07 trans-1,2-Dichloroethene ND 0.24 ND 0.14 ND 0.12 ND 0.09 1,1-Dichloroethane ND 0.20 ND 0.12 ND 0.10 ND 0.07 Methyl tert-Butyl Ether ND 0.22 ND 0.13 ND 0.11 ND 0.08 Vinyl Acetate 41.26 0.84 46.18 0.49 21.29 0.42 22.77 0.29 2-Butanone (MEK) 26.07 0.27 5.17 0.16 2.98 0.13 2.87 0.09 cis-1,2-Dichloroethene ND 0.20 ND 0.12 ND 0.10 ND 0.07 Ethyl Acetate ND 0.45 ND 0.27 ND 0.22 0.09 0.15 n-Hexane 0.26 0.19 0.05 0.11 0.04 0.09 0.07 0.07 Chloroform ND 0.22 ND 0.13 ND 0.11 ND 0.08 Tetrahydrofuran (THF) 1.11 0.26 ND 0.15 ND 0.12 0.10 0.09 1,2-Dichloroethane ND 0.20 ND 0.12 ND 0.10 ND 0.07 1,1,1-Trichloroethane ND 0.22 ND 0.13 ND 0.11 ND 0.08 Benzene 190.89 2.01 51.86 0.12 41.57 0.10 33.35 0.07 Carbon Tetrachloride 0.02 0.19 0.01 0.11 0.01 0.09 0.01 0.07 Cyclohexane ND 0.37 ND 0.22 ND 0.18 ND 0.13 1,2-Dichloropropane ND 0.20 ND 0.12 ND 0.10 ND 0.07 Bromodichloromethane ND 0.19 ND 0.11 ND 0.09 ND 0.07 39-A ------- Trichloroethene ND 0.18 ND 0.11 ND 0.09 ND 0.06 1,4-Dioxane ND 0.20 ND 0.12 ND 0.10 ND 0.07 Methyl Methacrylate ND 0.40 ND 0.23 ND 0.19 ND 0.14 n-Heptane ND 0.22 ND 0.13 ND 0.11 ND 0.08 cis-1,3-Dichloropropene ND 0.18 ND 0.11 ND 0.09 ND 0.06 4-Methyl-2-pentanone ND 0.20 ND 0.12 ND 0.10 ND 0.07 trans-1,3-Dichloropropene ND 0.20 ND 0.12 ND 0.10 ND 0.07 1,1,2-Trichloroethane ND 0.20 ND 0.12 ND 0.10 ND 0.07 Toluene 47.77 0.22 10.81 0.13 9.36 0.11 7.21 0.08 2-Hexanone 0.37 0.20 0.14 0.12 ND 0.10 0.08 0.07 Dibromochloromethane ND 0.20 ND 0.12 ND 0.10 ND 0.07 1,2-Dibromoethane ND 0.20 ND 0.12 ND 0.10 ND 0.07 n-Butyl Acetate ND 0.20 ND 0.12 ND 0.10 ND 0.07 n- Octane ND 0.23 ND 0.14 ND 0.11 ND 0.08 Tetrachloroethene ND 0.18 ND 0.11 ND 0.09 ND 0.06 Chlorobenzene ND 0.20 ND 0.12 ND 0.10 ND 0.07 Ethyl benzene 5.74 0.20 1.53 0.12 1.34 0.10 1.02 0.07 m-,,p-Xylenes 4.43 0.38 1.33 0.23 1.11 0.19 0.88 0.13 Bromoform ND 0.19 ND 0.11 ND 0.09 ND 0.07 Styrene 9.16 0.19 5.48 0.11 4.40 0.09 3.49 0.07 o-Xylene 1.61 0.19 0.52 0.11 0.46 0.09 0.36 0.07 n-Nonane ND 0.19 ND 0.11 ND 0.09 ND 0.07 1,1,2,2-Tetrachloroethane ND 0.19 ND 0.11 ND 0.09 ND 0.07 Cumene 0.33 0.19 ND 0.11 ND 0.09 ND 0.07 alpha-Pinene 0.51 0.18 0.21 0.11 0.28 0.09 0.08 0.06 n-Propylbenzene ND 0.20 ND 0.12 ND 0.10 ND 0.07 4-Ethyltoluene ND 0.20 0.12 0.12 0.10 0.10 0.09 0.07 1,3,5-Trimethyl benzene ND 0.20 ND 0.12 ND 0.10 ND 0.07 1,2,4-Trimethyl benzene ND 0.19 0.16 0.11 0.14 0.09 0.12 0.07 Benzyl Chloride ND 0.14 ND 0.08 ND 0.07 ND 0.05 1,3-Dichlorobenzene ND 0.19 ND 0.11 ND 0.09 ND 0.07 1,4-Dichlorobenzene ND 0.18 ND 0.11 ND 0.09 ND 0.06 1,2-Dichlorobenzene ND 0.19 ND 0.11 ND 0.09 ND 0.07 d-Limonene ND 0.18 0.18 0.11 0.14 0.09 0.10 0.06 1,2-Dibromo-3-chloropropane ND 0.13 ND 0.08 ND 0.06 ND 0.04 1,2,4-Trichlorobenzene ND 0.20 ND 0.12 ND 0.10 ND 0.07 Naphthalene 0.42 0.23 12.99 0.14 10.64 0.11 11.39 0.08 Hexachlorobutadiene ND 0.18 ND 0.11 ND 0.09 ND 0.06 g/kg cardboard Carbon Monoxide 27.72 15.57 14.07 14.29 Methane 0.20 0.17 0.20 0.13 40-A ------- Carbon Dioxide 1651.55 1670.72 1673.00 1672.84 MCE 0.974 0.986 0.987 0.987 850 855 860 865 870 875 Table A-27. VOC emission factors from corrugated Spectra-kote polymer fiberboard box and liner (SB/SL). | | Corrugated Spectra-kote Polymer Fiberboard box and liner (SB/SL) 41-A ------- 1 2 3 4 Method detection limit Method detection limit Method detection limit Method detection limit Compound EF EF EF EF EF EF EF EF mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg Propene 38.07 0.11 47.18 0.11 152.04 0.40 236.40 0.42 Dichlorodifluoromethane (CFC- 12) ND 0.13 ND 0.14 ND 0.46 ND 0.53 Chloromethane 2.47 0.11 2.99 0.12 10.49 0.43 6.55 0.46 1,2-Dichloro-1,1,2,2- tetrafluoroethane (CFC 114) ND 0.14 ND 0.15 ND 0.52 ND 0.56 Vinyl Chloride ND 0.13 ND 0.14 ND 0.46 ND 0.53 1,3-Butadiene 5.87 0.16 10.67 0.17 65.98 0.60 95.26 0.67 Bromomethane ND 0.14 ND 0.15 ND 0.52 ND 0.56 Chloroethane ND 0.13 ND 0.14 ND 0.46 ND 0.53 Ethanol ND 0.60 0.37 0.64 6.20 2.21 ND 2.43 Acetonitrile 1.16 0.14 1.42 0.14 4.02 0.49 5.29 0.56 Acrolein 25.38 0.13 26.67 0.14 134.83 0.46 137.60 0.53 Acetone ND 0.59 ND 0.62 ND 2.12 ND 2.36 Trichlorofluoromethane ND 0.13 ND 0.14 ND 0.46 ND 0.53 2-Propanol (Isopropyl Alcohol) ND 0.32 ND 0.33 ND 1.18 ND 1.27 Acrylonitrile 0.57 0.13 0.64 0.14 2.15 0.46 2.61 0.53 1,1-Dichloroethene ND 0.13 ND 0.14 ND 0.46 ND 0.53 Methylene Chloride 4.24 0.13 0.08 0.14 ND 0.46 ND 0.53 3-Chloro-1 -propene (Allyl Chloride) ND 0.12 ND 0.13 ND 0.43 ND 0.49 Trichlorotrifluoroethane ND 0.13 ND 0.14 ND 0.46 ND 0.53 Carbon Disulfide 0.35 0.11 0.35 0.12 2.29 0.43 1.48 0.46 trans-1,2-Dichloroethene ND 0.14 ND 0.15 ND 0.52 ND 0.56 1,1-Dichloroethane ND 0.12 ND 0.13 ND 0.43 ND 0.49 Methyl tert-Butyl Ether ND 0.13 ND 0.14 ND 0.46 ND 0.53 Vinyl Acetate 36.48 0.49 51.29 0.51 189.34 1.81 116.43 1.98 2-Butanone (MEK) 5.38 0.16 7.36 0.17 36.98 0.57 41.95 0.64 cis-1,2-Dichloroethene ND 0.12 ND 0.13 ND 0.43 ND 0.49 Ethyl Acetate ND 0.27 0.57 0.29 ND 0.98 ND 1.06 n-Hexane 0.16 0.11 0.23 0.12 0.36 0.43 ND 0.46 Chloroform ND 0.13 ND 0.14 ND 0.46 ND 0.53 Tetrahydrofuran (THF) 0.19 0.15 0.16 0.16 1.35 0.55 1.09 0.60 1,2-Dichloroethane ND 0.12 ND 0.13 ND 0.43 ND 0.49 1,1,1-Trichloroethane ND 0.13 ND 0.14 ND 0.46 ND 0.53 Benzene 60.23 0.12 71.73 0.13 220.80 0.43 260.98 0.49 Carbon Tetrachloride ND 0.11 ND 0.12 ND 0.43 ND 0.46 Cyclohexane ND 0.22 ND 0.23 ND 0.80 ND 0.88 1,2-Dichloropropane ND 0.12 ND 0.13 ND 0.43 ND 0.49 42-A ------- Bromodichloromethane ND 0.11 ND 0.12 ND 0.43 ND 0.46 Trichloroethene ND 0.11 ND 0.11 ND 0.40 ND 0.42 1,4-Dioxane ND 0.12 ND 0.13 ND 0.43 ND 0.49 Methyl Methacrylate 4.92 0.24 6.77 0.25 31.56 0.86 23.99 0.95 n-Heptane ND 0.13 0.18 0.14 ND 0.46 ND 0.53 cis-1,3-Dichloropropene ND 0.11 ND 0.11 ND 0.40 ND 0.42 4-Methyl-2-pentanone ND 0.12 ND 0.13 ND 0.43 ND 0.49 trans-1,3-Dichloropropene ND 0.12 ND 0.13 ND 0.43 ND 0.49 1,1,2-Trichloroethane ND 0.12 ND 0.13 ND 0.43 ND 0.49 Toluene 17.36 0.13 22.46 0.14 77.30 0.46 109.19 0.53 2-Hexanone ND 0.12 0.18 0.13 0.72 0.43 0.64 0.49 Dibromochloromethane ND 0.12 ND 0.13 ND 0.43 ND 0.49 1,2-Dibromoethane ND 0.12 ND 0.13 ND 0.43 ND 0.49 n-Butyl Acetate ND 0.12 ND 0.13 ND 0.43 ND 0.49 n-Octane ND 0.14 ND 0.14 ND 0.49 ND 0.56 Tetrachloroethene ND 0.11 ND 0.11 0.66 0.40 ND 0.42 Chlorobenzene ND 0.12 ND 0.13 ND 0.43 ND 0.49 Ethyl benzene 3.49 0.12 4.72 0.13 21.23 0.43 30.34 0.49 /rj-,,p-Xylenes 1.90 0.22 2.46 0.25 8.61 0.83 14.82 0.92 Bromoform ND 0.11 ND 0.12 ND 0.43 ND 0.46 Styrene 19.04 0.11 30.77 0.12 34.42 0.43 155.25 0.46 o-Xylene 0.81 0.11 1.07 0.12 3.44 0.43 6.35 0.46 n-Nonane ND 0.11 ND 0.12 ND 0.43 ND 0.46 1,1,2,2-Tetrachloroethane ND 0.11 ND 0.12 ND 0.43 ND 0.46 Cumene 0.33 0.11 0.45 0.12 2.12 0.43 3.25 0.46 alpha-Pinene 0.22 0.11 0.11 0.11 0.48 0.40 0.49 0.42 n-Propylbenzene 0.17 0.12 0.23 0.13 0.89 0.43 1.55 0.49 4-Ethyltoluene 0.15 0.12 0.19 0.13 0.55 0.43 1.23 0.49 1,3,5-Trimethyl benzene ND 0.12 0.14 0.13 ND 0.43 0.88 0.49 1,2,4-Trimethyl benzene 0.24 0.11 0.35 0.12 0.55 0.43 2.26 0.46 Benzyl Chloride ND 0.08 ND 0.09 ND 0.32 ND 0.34 1,3-Dichlorobenzene ND 0.11 ND 0.12 ND 0.43 ND 0.46 1,4-Dichlorobenzene ND 0.11 ND 0.11 ND 0.40 ND 0.42 1,2-Dichlorobenzene ND 0.11 ND 0.12 ND 0.43 ND 0.46 d-Limonene ND 0.11 ND 0.11 ND 0.40 0.42 0.42 1,2-Dibromo-3-chloropropane ND 0.07 ND 0.08 ND 0.28 ND 0.30 1,2,4-Trichlorobenzene ND 0.12 ND 0.13 ND 0.43 ND 0.49 Naphthalene 20.62 0.14 22.57 0.14 1.29 0.49 56.45 0.56 Hexachlorobutadiene ND 0.11 ND 0.11 ND 0.40 ND 0.42 g/kg paperboard Carbon Monoxide 15.11 16.24 29.30 36.04 Methane 0.28 0.34 1.09 1.55 43-A ------- Carbon Dioxide 1633.37 1631.43 1608.84 1596.99 MCE 0.986 0.985 0.972 0.966 880 885 890 895 900 Table A-28. VOC emission factors from No-Spectra-kote fiberboard box and liner (NSB/NSL). No-Spectra-kote box and liner (NSB/NSL) 12 3 4 44-A ------- Method detection limit Method detection limit Method detection limit Method detection limit Compound EF EF EF EF EF EF EF EF mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg Propene 19.06 0.07 113.86 0.19 56.54 0.13 146.60 0.31 Dichlorodifluoromethane (CFC 12) ND 0.08 0.05 0.24 0.03 0.16 ND 0.35 Chloromethane 0.97 0.07 2.21 0.21 1.50 0.14 2.53 0.33 1,2-Dichloro-1,1,2,2- tetrafluoroethane (CFC 114) ND 0.09 ND 0.26 ND 0.19 ND 0.39 Vinyl Chloride ND 0.08 ND 0.24 ND 0.16 ND 0.35 1,3-Butadiene 8.85 0.10 42.37 0.32 23.98 0.21 61.26 0.46 Bromomethane ND 0.09 ND 0.26 ND 0.19 ND 0.39 Chloroethane ND 0.08 ND 0.24 ND 0.16 ND 0.35 Ethanol 1.02 0.37 8.10 1.11 ND 0.75 5.82 1.68 Aceto nit rile 0.53 0.08 2.12 0.25 1.32 0.17 2.41 0.37 Acrolein 1.36 0.08 116.51 0.24 54.82 0.16 131.28 0.35 Acetone ND 0.35 ND 1.06 ND 0.74 127.98 1.62 Trichlorofluoromethane ND 0.08 0.03 0.24 ND 0.16 ND 0.35 2-Propanol (Isopropyl Alcohol) ND 0.19 ND 0.58 ND 0.39 ND 0.90 Acrylonitrile 0.19 0.08 0.64 0.24 0.46 0.16 0.90 0.35 1,1-Dichloroethene ND 0.08 ND 0.24 ND 0.16 ND 0.35 Methylene Chloride 0.23 0.08 4.16 0.24 7.49 0.16 0.48 0.35 3-Chloro-1 -propene (Allyl Chloride) ND 0.07 ND 0.22 ND 0.15 ND 0.33 Trichlorotrifluoroethane ND 0.08 ND 0.24 ND 0.16 ND 0.35 Carbon Disulfide 0.29 0.07 0.42 0.21 2.91 0.14 0.66 0.33 trans-1,2-Dichloroethene ND 0.09 ND 0.26 ND 0.19 ND 0.39 1,1-Dichloroethane ND 0.07 ND 0.22 ND 0.15 ND 0.33 Methyl tert-Butyl Ether ND 0.08 ND 0.24 ND 0.16 ND 0.35 Vinyl Acetate 50.37 0.30 ND 0.90 ND 0.62 ND 1.38 2-Butanone (MEK) 6.25 0.10 34.13 0.29 16.09 0.21 41.33 0.44 cis-1,2-Dichloroethene ND 0.07 ND 0.22 ND 0.15 ND 0.33 Ethyl Acetate ND 0.16 2.30 0.48 ND 0.33 ND 0.74 n-Hexane 0.04 0.07 1.97 0.21 0.32 0.14 0.38 0.33 Chloroform ND 0.08 ND 0.24 ND 0.16 ND 0.35 Tetrahydrofuran (THF) 0.12 0.09 1.14 0.26 0.38 0.19 1.20 0.42 1,2-Dichloroethane ND 0.07 ND 0.22 ND 0.15 ND 0.33 1,1,1-Trichloroethane ND 0.08 ND 0.24 ND 0.16 ND 0.35 Benzene 33.99 0.07 100.53 0.22 78.75 0.15 150.90 0.33 Carbon Tetrachloride ND 0.07 ND 0.21 ND 0.14 ND 0.33 Cyclohexane ND 0.13 ND 0.40 ND 0.27 ND 0.61 1,2-Dichloropropane ND 0.07 ND 0.22 ND 0.15 ND 0.33 Bromodichloromethane ND 0.07 ND 0.21 ND 0.14 ND 0.33 45-A ------- Trichloroethene ND 0.07 ND 0.19 ND 0.13 ND 0.31 1,4-Dioxane ND 0.07 ND 0.22 ND 0.15 ND 0.33 Methyl Methacrylate ND 0.15 0.50 0.42 ND 0.29 ND 0.66 n-Heptane ND 0.08 0.64 0.24 ND 0.16 ND 0.35 cis-1,3-Dichloropropene ND 0.07 ND 0.19 ND 0.13 ND 0.31 4-Methyl-2-pentanone ND 0.07 0.34 0.22 ND 0.15 ND 0.33 trans-1,3-Dichloropropene ND 0.07 ND 0.22 ND 0.15 ND 0.33 1,1,2-Trichloroethane ND 0.07 ND 0.22 ND 0.15 ND 0.33 Toluene 8.37 0.08 36.93 0.24 22.18 0.16 45.83 0.35 2-Hexanone 0.10 0.07 0.42 0.22 0.33 0.15 0.59 0.33 Dibromochloromethane ND 0.07 ND 0.22 ND 0.15 ND 0.33 1,2-Dibromoethane ND 0.07 ND 0.22 ND 0.15 ND 0.33 n-Butyl Acetate ND 0.07 ND 0.22 ND 0.15 ND 0.33 n-Octane ND 0.08 0.45 0.25 ND 0.17 ND 0.37 Tetrachloroethene ND 0.07 ND 0.19 ND 0.13 ND 0.31 Chlorobenzene ND 0.07 ND 0.22 ND 0.15 ND 0.33 Ethyl benzene 1.24 0.07 5.83 0.22 3.43 0.15 7.88 0.33 /rj-,,p-Xylenes 1.24 0.14 7.68 0.42 4.28 0.29 8.97 0.63 Bromoform ND 0.07 ND 0.21 ND 0.14 ND 0.33 Styrene 4.22 0.07 15.36 0.21 10.11 0.14 21.88 0.33 o-Xylene 0.52 0.07 2.91 0.21 1.71 0.14 3.72 0.33 n-Nonane ND 0.07 ND 0.21 ND 0.14 ND 0.33 1,1,2,2-Tetrachloroethane ND 0.07 ND 0.21 ND 0.14 ND 0.33 Cumene ND 0.07 0.29 0.21 0.17 0.14 0.42 0.33 alpha-Pinene 0.15 0.07 0.37 0.19 0.39 0.13 0.57 0.31 n-Propylbenzene ND 0.07 0.34 0.22 0.21 0.15 0.39 0.33 4-Ethyltoluene 0.12 0.07 0.69 0.22 0.36 0.15 0.79 0.33 1,3,5-Trimethyl benzene ND 0.07 0.40 0.22 0.22 0.15 0.44 0.33 1,2,4-Trimethyl benzene 0.18 0.07 1.30 0.21 0.74 0.14 1.40 0.33 Benzyl Chloride ND 0.05 ND 0.15 ND 0.10 ND 0.24 1,3-Dichlorobenzene ND 0.07 ND 0.21 ND 0.14 ND 0.33 1,4-Dichlorobenzene ND 0.07 ND 0.19 ND 0.13 ND 0.31 1,2-Dichlorobenzene ND 0.07 ND 0.21 ND 0.14 ND 0.33 d-Limonene 0.13 0.07 0.48 0.19 0.27 0.13 0.33 0.31 1,2-Dibromo-3-chloropropane ND 0.05 ND 0.14 ND 0.09 ND 0.21 1,2,4-Trichlorobenzene ND 0.07 ND 0.22 ND 0.15 ND 0.33 Naphthalene 9.80 0.08 14.56 0.25 18.85 0.17 37.20 0.37 Hexachlorobutadiene ND 0.07 ND 0.19 ND 0.13 ND 0.31 g/kg paperboard Carbon Monoxide 15.62 26.44 19.27 30.13 Methane 0.17 0.87 0.53 1.16 46-A ------- Carbon Dioxide 1647.17 1628.25 1640.46 1621.64 MCE 0.985 0.975 0.982 0.972 905 910 915 920 925 Table A-29. VOC emission factors from current fiberboard box, no wet strength (NWS). Current Fiberboard box, no wet strength (NWS) 12 3 4 47-A ------- Method detection limit Method detection limit Method detection limit Method detection limit EF EF EF EF EF EF EF EF mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg Propene 62.97 0.18 44.62 0.18 52.42 0.17 42.07 0.13 Dichlorodifluoromethane (CFC- 12) ND 0.22 ND 0.22 0.02 0.21 ND 0.16 Chloromethane 0.71 0.20 0.73 0.20 0.51 0.19 0.55 0.14 1,2-Dichloro-1,1,2,2- tetrafluoroethane (CFC 114) ND 0.25 ND 0.25 ND 0.24 ND 0.18 Vinyl Chloride ND 0.22 ND 0.22 ND 0.21 ND 0.16 1,3-Butadiene 31.48 0.29 21.72 0.29 23.83 0.29 19.28 0.21 Bromomethane ND 0.25 ND 0.25 ND 0.24 ND 0.18 Chloroethane ND 0.22 ND 0.22 ND 0.21 ND 0.16 Ethanol 2.76 1.07 ND 1.04 ND 1.00 ND 0.77 Acetonitrile 0.73 0.24 0.68 0.24 0.52 0.22 0.56 0.17 Acrolein 31.97 0.22 44.62 0.22 33.36 0.21 33.31 0.16 Acetone 41.12 1.02 ND 1.01 ND 0.95 ND 0.74 Trichlorofluoromethane ND 0.22 ND 0.22 0.02 0.21 ND 0.16 2-Propanol (Isopropyl Alcohol) ND 0.53 ND 0.54 ND 0.52 ND 0.40 Acrylonitrile ND 0.22 0.36 0.22 0.24 0.21 0.23 0.16 1,1-Dichloroethene ND 0.22 ND 0.22 ND 0.21 ND 0.16 Methylene Chloride 12.93 0.22 7.94 0.22 0.24 0.21 5.56 0.16 3-Chloro-1 -propene (Allyl Chloride) ND 0.21 ND 0.21 ND 0.20 ND 0.15 T richlorotrifluoroethane ND 0.22 ND 0.22 ND 0.21 ND 0.16 Carbon Disulfide 2.66 0.20 1.99 0.20 1.41 0.19 0.96 0.14 trans-1,2-Dichloroethene ND 0.25 ND 0.25 ND 0.24 ND 0.18 1,1-Dichloroethane ND 0.21 ND 0.21 ND 0.20 ND 0.15 Methyl tert-Butyl Ether ND 0.22 ND 0.22 ND 0.21 ND 0.16 Vinyl Acetate 58.13 0.87 38.67 0.83 ND 0.81 ND 0.63 2-Butanone (MEK) 14.00 0.28 8.89 0.27 7.36 0.26 8.05 0.21 cis-1,2-Dichloroethene ND 0.21 ND 0.21 ND 0.20 ND 0.15 Ethyl Acetate ND 0.46 ND 0.45 1.00 0.43 ND 0.33 n-Hexane 0.22 0.20 0.14 0.20 0.61 0.19 0.43 0.14 Chloroform ND 0.22 ND 0.22 ND 0.21 ND 0.16 Tetrahydrofuran (THF) 0.73 0.26 0.42 0.26 0.33 0.24 0.30 0.19 1,2-Dichloroethane ND 0.21 ND 0.21 ND 0.20 ND 0.15 1,1,1-Trichloroethane ND 0.22 ND 0.22 ND 0.21 ND 0.16 Benzene 125.78 0.21 121.87 0.21 102.37 0.20 92.86 0.15 Carbon Tetrachloride 0.01 0.20 ND 0.20 ND 0.19 ND 0.14 Cyclohexane ND 0.38 ND 0.39 ND 0.36 ND 0.28 1,2-Dichloropropane ND 0.21 ND 0.21 ND 0.20 ND 0.15 Bromodichloromethane ND 0.20 ND 0.20 ND 0.19 ND 0.14 48-A ------- Trichloroethene ND 0.18 ND 0.18 ND 0.17 ND 0.13 1,4-Dioxane ND 0.21 ND 0.21 ND 0.20 ND 0.15 Methyl Methacrylate ND 0.41 ND 0.42 ND 0.38 ND 0.30 n-Heptane ND 0.22 ND 0.22 ND 0.21 ND 0.16 cis-1,3-Dichloropropene ND 0.18 ND 0.18 ND 0.17 ND 0.13 4-Methyl-2-pentanone ND 0.21 ND 0.21 ND 0.20 ND 0.15 trans-1,3-Dichloropropene ND 0.21 ND 0.21 ND 0.20 ND 0.15 1,1,2-Trichloroethane ND 0.21 ND 0.21 ND 0.20 ND 0.15 Toluene 32.19 0.22 26.32 0.22 26.08 0.21 20.94 0.16 2-Hexanone 0.31 0.21 0.23 0.21 ND 0.20 ND 0.15 Dibromochloromethane ND 0.21 ND 0.21 ND 0.20 ND 0.15 1,2-Dibromoethane ND 0.21 ND 0.21 ND 0.20 ND 0.15 n-Butyl Acetate ND 0.21 ND 0.21 ND 0.20 ND 0.15 n- Octane ND 0.24 ND 0.24 ND 0.22 ND 0.17 Tetrachloroethene ND 0.18 ND 0.18 ND 0.17 ND 0.13 Chlorobenzene ND 0.21 ND 0.21 ND 0.20 ND 0.15 Ethyl benzene 4.75 0.21 3.87 0.21 4.29 0.20 3.33 0.15 m-, p-Xylenes 4.84 0.39 3.27 0.39 3.81 0.38 2.98 0.28 Bromoform ND 0.20 ND 0.20 ND 0.19 ND 0.14 Styrene 15.02 0.20 13.09 0.20 13.34 0.19 11.04 0.14 o-Xylene 1.94 0.20 1.34 0.20 1.52 0.19 1.21 0.14 n-Nonane ND 0.20 ND 0.20 ND 0.19 ND 0.14 1,1,2,2-Tetrachloroethane ND 0.20 ND 0.20 ND 0.19 ND 0.14 Cumene 0.23 0.20 0.21 0.20 0.19 0.19 0.17 0.14 alpha-Pinene 2.42 0.18 0.38 0.18 0.15 0.17 0.40 0.13 n-Propylbenzene ND 0.21 ND 0.21 ND 0.20 ND 0.15 4-Ethyltoluene 0.46 0.21 0.33 0.21 0.38 0.20 0.26 0.15 1,3,5-Trimethyl benzene 0.23 0.21 ND 0.21 ND 0.20 ND 0.15 1,2,4-Trimethyl benzene 0.73 0.20 0.42 0.20 0.57 0.19 0.40 0.14 Benzyl Chloride ND 0.15 ND 0.14 ND 0.14 ND 0.11 1,3-Dichlorobenzene ND 0.20 ND 0.20 ND 0.19 ND 0.14 1,4-Dichlorobenzene ND 0.18 ND 0.18 ND 0.17 ND 0.13 1,2-Dichlorobenzene ND 0.20 ND 0.20 ND 0.19 ND 0.14 d-Limonene 2.13 0.18 0.39 0.18 0.33 0.17 0.30 0.13 1,2-Dibromo-3-chloropropane ND 0.13 ND 0.13 ND 0.12 ND 0.09 1,2,4-Trichlorobenzene ND 0.21 ND 0.21 ND 0.20 ND 0.15 Naphthalene 36.33 0.24 35.70 0.24 30.97 0.22 31.56 0.17 Hexachlorobutadiene ND 0.18 ND 0.18 ND 0.17 ND 0.13 g/kg paperboard Carbon Monoxide 23.90 23.90 16.68 17.50 Methane 0.48 0.47 0.39 0.38 49-A ------- Carbon Dioxide 1668.33 1668.36 1679.92 1678.65 MCE 0.978 0.978 0.985 0.984 930 50-A ------- Appendix B: Data for each sample collected from OB of MRE pouches. Table B-l. PCDD/PCDF data for 0 % NEW 01. Sample ID PS-1000LD-073015-01 MCE 0.941667 Page 1 (2) Sampling volume (m3) 122.3 Carbon sampled (g) 68.4 Carbon sampled (mg/m3) 559.6 Carbon fraction 0.4 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 1.02E-02 1.02E-02 1.02E-02 8.34E-05 8.34E-05 8.34E-05 1,2,3,7,8- PeCDD 1.92E-02 1.92E-02 1.92E-02 1.57E-04 1.57E-04 1.57E-04 1,2,3,4,7,8- HxCDD 1.26E-02 1.26E-03 1.26E-03 1.03E-04 1.03E-05 1.03E-05 1,2,3,6,7,8- HxCDD ND 1.37E-02 0.00E+00 1.37E-03 ND 0.00E+00 1.12E-05 1,2,3,7,8,9- HxCDD ND 1.45E-02 0.00E+00 1.45E-03 ND 0.00E+00 1.18E-05 1,2,3,4,6,7,8- HpCDD 1.95E-01 1.95E-03 1.95E-03 1.59E-03 1.59E-05 1.59E-05 1,2,3,4,6,7,8,9 - OCDD 5.48E-01 1.64E-04 1.64E-04 4.48E-03 1.34E-06 1.34E-06 2,3,7,8 - TCDF 6.10E-01 6.10E-02 6.10E-02 4.98E-03 4.98E-04 4.98E-04 1,2,3,7,8- PeCDF 1.52E-01 4.55E-03 4.55E-03 1.24E-03 3.72E-05 3.72E-05 2,3,4,7,8- PeCDF 1.48E-01 4.45E-02 4.45E-02 1.21 E-03 3.64E-04 3.64E-04 1,2,3,4,7,8- HxCDF 5.28E-02 5.28E-03 5.28E-03 4.32E-04 4.32E-05 4.32E-05 1,2,3,6,7,8- HxCDF 4.20E-02 4.20E-03 4.20E-03 3.43E-04 3.43E-05 3.43E-05 1,2,3,7,8,9- HxCDF ND 1.66E-02 0.00E+00 1.66E-03 ND 0.00E+00 1.36E-05 2,3,4,6,7,8 - HxCDF 3.44E-02 3.44E-03 3.44E-03 2.81 E-04 2.81 E-05 2.81 E-05 1,2,3,4,6,7,8- HpCDF 5.26E-02 5.26E-04 5.26E-04 4.30E-04 4.30E-06 4.30E-06 1,2,3,4,7,8,9- HpCDF ND 2.27E-02 0.00E+00 2.27E-04 ND 0.00E+00 1.86E-06 1,2,3,4,6,7,8,9-OCDF 4.28E-02 1.28E-05 1.28E-05 3.50E-04 1.05E-07 1.05E-07 TeCDD Total 2.10E-01 1.72E-03 PeCDD Total 1.39E-01 1.14E-03 HxCDD Total 1.56E-01 1.27E-03 HpCDD Total 3.46E-01 2.83E-03 OCDD 5.48E-01 4.48E-03 TeCDF Total 8.34E+00 6.82E-02 PeCDF Total 1.37E+00 1.12E-02 HxCDF Total 2.73E-01 2.23E-03 HpCDF Total 5.26E-02 4.30E-04 OCDF 4.78E-02 3.91 E-04 PCDD Total 1.40E+00 1.14E-02 PCDF Total 1.01 E+01 8.24E-02 PCDD/PCDF Total 1.15E+01 9.39E-02 PCDD TEQ Total 3.28E-02 3.56E-02 2.68E-04 2.91 E-04 PCDF TEQ Total 1.23E-01 1.25E-01 1.01 E-03 1.03E-03 PCDD/PCDF TEQ Total 1.56E-01 1.61 E-01 1.28E-03 1.32E-03 Sample ID PS-100QLD-073015-01 Page 2 (2) 1-B ------- EF EF EF EF EF EF Total TEQ TEQ Total TEQ TEQ Isomer. ng/g Carbon ng/kg fuel ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 1.49E-04 1.49E-04 1.49E-04 6.27E-02 6.27E-02 6.27E-02 1,2,3,7,8- PeCDD 2.81 E-04 2.81 E-04 2.81 E-04 1.18E-01 1.18E-01 1.18E-01 1,2,3,4,7,8- HxCDD 1.84E-04 1.84E-05 1.84E-05 7.75E-02 7.75E-03 7.75E-03 1,2,3,6,7,8- HxCDD ND 0.00E+00 2.00E-05 ND 0.00E+00 8.43E-03 1,2,3,7,8,9- HxCDD ND 0.00E+00 2.11 E-05 ND 0.00E+00 8.89E-03 1,2,3,4,6,7,8- HpCDD 2.85E-03 2.85E-05 2.85E-05 1.20E+00 1.20E-02 1.20E-02 1,2,3,4,6,7,8,9 - OCDD 8.01 E-03 2.40E-06 2.40E-06 3.37E+00 1.01 E-03 1.01 E-03 2,3,7,8 - TCDF 8.91 E-03 8.91 E-04 8.91 E-04 3.75E+00 3.75E-01 3.75E-01 1,2,3,7,8- PeCDF 2.22E-03 6.65E-05 6.65E-05 9.32E-01 2.80E-02 2.80E-02 2,3,4,7,8- PeCDF 2.17E-03 6.50E-04 6.50E-04 9.13E-01 2.74E-01 2.74E-01 1,2,3,4,7,8- HxCDF 7.71 E-04 7.71 E-05 7.71 E-05 3.25E-01 3.25E-02 3.25E-02 1,2,3,6,7,8- HxCDF 6.14E-04 6.14E-05 6.14E-05 2.58E-01 2.58E-02 2.58E-02 1,2,3,7,8,9- HxCDF ND 0.00E+00 2.43E-05 ND 0.00E+00 1.02E-02 2,3,4,6,7,8 - HxCDF 5.03E-04 5.03E-05 5.03E-05 2.12E-01 2.12E-02 2.12E-02 1,2,3,4,6,7,8- HpCDF 7.69E-04 7.69E-06 7.69E-06 3.24E-01 3.24E-03 3.24E-03 1,2,3,4,7,8,9- HpCDF ND 0.00E+00 3.32E-06 ND 0.00E+00 1.40E-03 1,2,3,4,6,7,8,9-OCDF 6.25E-04 1.88E-07 1.88E-07 2.63E-01 7.90E-05 7.90E-05 TeCDD Total 3.07E-03 1.29E+00 PeCDD Total 2.03E-03 8.56E-01 HxCDD Total 2.27E-03 9.57E-01 HpCDD Total 5.06E-03 2.13E+00 OCDD 8.01 E-03 3.37E+00 TeCDF Total 1.22E-01 5.13E+01 PeCDF Total 2.00E-02 8.43E+00 HxCDF Total 3.99E-03 1.68E+00 HpCDF Total 7.69E-04 3.24E-01 OCDF 6.98E-04 2.94E-01 PCDD Total 2.04E-02 8.61 E+00 PCDF Total 1.47E-01 6.20E+01 PCDD/PCDF Total 1.68E-01 7.06E+01 PCDD TEQ Total 4.79E-04 5.20E-04 2.02E-01 2.19E-01 PCDF TEQ Total 1.80E-03 1.83E-03 7.59E-01 7.71 E-01 PCDD/PCDF TEQ Total 2.28E-03 2.35E-03 9.61 E-01 9.90E-01 935 940 Table B-2. PCDD/PCDF data for 0 % NEW 02. 2-B ------- Sample ID PS-1000LD2-073015-02 MCE 0.943944 Page 1 (2) Sampling volume (m3) 101.2 Carbon sampled (g) 58.8 Carbon sampled (mg/m3) 581.2 Carbon fraction 0.4 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 3.94E-02 3.94E-02 3.94E-02 3.90E-04 3.90E-04 3.90E-04 1,2,3,7,8- PeCDD 1.66E-02 1.66E-02 1.66E-02 1.64E-04 1.64E-04 1.64E-04 1,2,3,4,7,8- HxCDD 5.40E-03 5.40E-04 5.40E-04 5.34E-05 5.34E-06 5.34E-06 1,2,3,6,7,8- HxCDD 1.62E-02 1.62E-03 1.62E-03 1.60E-04 1.60E-05 1.60E-05 1,2,3,7,8,9- HxCDD 1.38E-02 1.38E-03 1.38E-03 1.36E-04 1.36E-05 1.36E-05 1,2,3,4,6,7,8- HpCDD 1.69E-01 1.69E-03 1.69E-03 1.67E-03 1.67E-05 1.67E-05 1,2,3,4,6,7,8,9 - OCDD 4.99E-01 1.50E-04 1.50E-04 4.94E-03 1.48E-06 1.48E-06 2,3,7,8 - TCDF 7.86E-01 7.86E-02 7.86E-02 7.77E-03 7.77E-04 7.77E-04 1,2,3,7,8- PeCDF 1.63E-01 4.90E-03 4.90E-03 1.62E-03 4.85E-05 4.85E-05 2,3,4,7,8- PeCDF 1.63E-01 4.88E-02 4.88E-02 1.61 E-03 4.82E-04 4.82E-04 1,2,3,4,7,8- HxCDF 4.00E-02 4.00E-03 4.00E-03 3.95E-04 3.95E-05 3.95E-05 1,2,3,6,7,8- HxCDF 3.56E-02 3.56E-03 3.56E-03 3.52E-04 3.52E-05 3.52E-05 1,2,3,7,8,9- HxCDF 1.62E-02 1.62E-03 1.62E-03 1.60E-04 1.60E-05 1.60E-05 2,3,4,6,7,8 - HxCDF 3.28E-02 3.28E-03 3.28E-03 3.24E-04 3.24E-05 3.24E-05 1,2,3,4,6,7,8- HpCDF 4.24E-02 4.24E-04 4.24E-04 4.19E-04 4.19E-06 4.19E-06 1,2,3,4,7,8,9- HpCDF 5.80E-03 5.80E-05 5.80E-05 5.73E-05 5.73E-07 5.73E-07 1,2,3,4,6,7,8,9-OCDF 3.12E-02 9.36E-06 9.36E-06 3.08E-04 9.25E-08 9.25E-08 TeCDD Total 3.36E-01 3.33E-03 PeCDD Total 1.55E-01 1.53E-03 HxCDD Total 1.79E-01 1.77E-03 HpCDD Total 2.99E-01 2.96E-03 OCDD 4.99E-01 4.94E-03 TeCDF Total 1.12E+01 1.10E-01 PeCDF Total 1.62E+00 1.60E-02 HxCDF Total 2.96E-01 2.92E-03 HpCDF Total 6.72E-02 6.64E-04 OCDF 3.12E-02 3.08E-04 PCDD Total 1.47E+00 1.45E-02 PCDF Total 1.32E+01 1.30E-01 PCDD/PCDF Total 1.46E+01 1.45E-01 PCDD TEQ Total 6.14E-02 6.14E-02 6.07E-04 6.07E-04 PCDF TEQ Total 1.45E-01 1.45E-01 1.44E-03 1.44E-03 PCDD/PCDF TEQ Total 2.07E-01 2.07E-01 2.04E-03 2.04E-03 Sample ID PS-1000LD2-073015-02 Page 2 (2) 3-B ------- EF EF EF EF EF EF Total TEQ TEQ Total TEQ TEQ Isomer. ng/g Carbon ng/kg fuel ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 6.70E-04 6.70E-04 6.70E-04 2.82E-01 2.82E-01 2.82E-01 1,2,3,7,8- PeCDD 2.82E-04 2.82E-04 2.82E-04 1.19E-01 1.19E-01 1.19E-01 1,2,3,4,7,8- HxCDD 9.19E-05 9.19E-06 9.19E-06 3.87E-02 3.87E-03 3.87E-03 1,2,3,6,7,8- HxCDD 2.76E-04 2.76E-05 2.76E-05 1.16E-01 1.16E-02 1.16E-02 1,2,3,7,8,9- HxCDD 2.35E-04 2.35E-05 2.35E-05 9.88E-02 9.88E-03 9.88E-03 1,2,3,4,6,7,8- HpCDD 2.87E-03 2.87E-05 2.87E-05 1.21E+00 1.21E-02 1.21 E-02 1,2,3,4,6,7,8,9 - OCDD 8.50E-03 2.55E-06 2.55E-06 3.58E+00 1.07E-03 1.07E-03 2,3,7,8 - TCDF 1.34E-02 1.34E-03 1.34E-03 5.63E+00 5.63E-01 5.63E-01 1,2,3,7,8- PeCDF 2.78E-03 8.34E-05 8.34E-05 1.17E+00 3.51 E-02 3.51 E-02 2,3,4,7,8- PeCDF 2.77E-03 8.30E-04 8.30E-04 1.16E+00 3.49E-01 3.49E-01 1,2,3,4,7,8- HxCDF 6.80E-04 6.80E-05 6.80E-05 2.86E-01 2.86E-02 2.86E-02 1,2,3,6,7,8- HxCDF 6.06E-04 6.06E-05 6.06E-05 2.55E-01 2.55E-02 2.55E-02 1,2,3,7,8,9- HxCDF 2.76E-04 2.76E-05 2.76E-05 1.16E-01 1.16E-02 1.16E-02 2,3,4,6,7,8 - HxCDF 5.58E-04 5.58E-05 5.58E-05 2.35E-01 2.35E-02 2.35E-02 1,2,3,4,6,7,8- HpCDF 7.21 E-04 7.21 E-06 7.21 E-06 3.04E-01 3.04E-03 3.04E-03 1,2,3,4,7,8,9- HpCDF 9.87E-05 9.87E-07 9.87E-07 4.15E-02 4.15E-04 4.15E-04 1,2,3,4,6,7,8,9-OCDF 5.31 E-04 1.59E-07 1.59E-07 2.23E-01 6.70E-05 6.70E-05 TeCDD Total 5.72E-03 2.41 E+00 PeCDD Total 2.63E-03 1.11 E+00 HxCDD Total 3.04E-03 1.28E+00 HpCDD Total 5.09E-03 2.14E+00 OCDD 8.50E-03 3.58E+00 TeCDF Total 1.90E-01 7.99E+01 PeCDF Total 2.76E-02 1.16E+01 HxCDF Total 5.03E-03 2.12E+00 HpCDF Total 1.14E-03 4.81 E-01 OCDF 5.31 E-04 2.23E-01 PCDD Total 2.50E-02 1.05E+01 PCDF Total 2.24E-01 9.43E+01 PCDD/PCDF Total 2.49E-01 1.05E+02 PCDD TEQ Total 1.04E-03 1.04E-03 4.39E-01 4.39E-01 PCDF TEQ Total 2.47E-03 2.47E-03 1.04E+00 1.04E+00 PCDD/PCDF TEQ Total 3.51 E-03 3.51 E-03 1.48E+00 1.48E+00 945 Table B-3. PCDD/PCDF data for 0 % NEW 03. 4-B ------- Sample ID PS-1000LD3-073115-02 MCE 0.920669 Page 1 (2) Sampling volume (m3) 118.2 Carbon sampled (g) 63.9 Carbon sampled (mg/m3) 540.5 Carbon fraction 0.4 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 8.12E-02 8.12E-02 8.12E-02 6.87E-04 6.87E-04 6.87E-04 1,2,3,7,8- PeCDD 2.38E-02 2.38E-02 2.38E-02 2.01 E-04 2.01 E-04 2.01 E-04 1,2,3,4,7,8- HxCDD 6.80E-03 6.80E-04 6.80E-04 5.75E-05 5.75E-06 5.75E-06 1,2,3,6,7,8- HxCDD 1.52E-02 1.52E-03 1.52E-03 1.29E-04 1.29E-05 1.29E-05 1,2,3,7,8,9- HxCDD 1.24E-02 1.24E-03 1.24E-03 1.05E-04 1.05E-05 1.05E-05 1,2,3,4,6,7,8- HpCDD 1.69E-01 1.69E-03 1.69E-03 1.43E-03 1.43E-05 1.43E-05 1,2,3,4,6,7,8,9 - OCDD 4.52E-01 1.36E-04 1.36E-04 3.82E-03 1.15E-06 1.15E-06 2,3,7,8 - TCDF 1.82E+00 1.82E-01 1.82E-01 1.54E-02 1.54E-03 1.54E-03 1,2,3,7,8- PeCDF 3.70E-01 1.11E-02 1.11E-02 3.13E-03 9.38E-05 9.38E-05 2,3,4,7,8- PeCDF 4.12E-01 1.24E-01 1.24E-01 3.49E-03 1.05E-03 1.05E-03 1,2,3,4,7,8- HxCDF 7.00E-02 7.00E-03 7.00E-03 5.92E-04 5.92E-05 5.92E-05 1,2,3,6,7,8- HxCDF 6.74E-02 6.74E-03 6.74E-03 5.70E-04 5.70E-05 5.70E-05 1,2,3,7,8,9- HxCDF 3.14E-02 3.14E-03 3.14E-03 2.66E-04 2.66E-05 2.66E-05 2,3,4,6,7,8 - HxCDF 5.72E-02 5.72E-03 5.72E-03 4.84E-04 4.84E-05 4.84E-05 1,2,3,4,6,7,8- HpCDF 5.00E-02 5.00E-04 5.00E-04 4.23E-04 4.23E-06 4.23E-06 1,2,3,4,7,8,9- HpCDF 1.14E-02 1.14E-04 1.14E-04 9.64E-05 9.64E-07 9.64E-07 1,2,3,4,6,7,8,9-OCDF 3.34E-02 1.00E-05 1.00E-05 2.82E-04 8.47E-08 8.47E-08 TeCDD Total 4.12E-01 3.48E-03 PeCDD Total 1.38E-01 1.17E-03 HxCDD Total 1.74E-01 1.47E-03 HpCDD Total 2.99E-01 2.53E-03 OCDD 4.52E-01 3.82E-03 TeCDF Total 2.20E+01 1.86E-01 PeCDF Total 3.18E+00 2.69E-02 HxCDF Total 5.04E-01 4.26E-03 HpCDF Total 9.92E-02 8.39E-04 OCDF 3.34E-02 2.82E-04 PCDD Total 1.48E+00 1.25E-02 PCDF Total 2.59E+01 2.19E-01 PCDD/PCDF Total 2.73E+01 2.31 E-01 PCDD TEQ Total 1.10E-01 1.10E-01 9.33E-04 9.33E-04 PCDF TEQ Total 3.40E-01 3.40E-01 2.87E-03 2.87E-03 PCDD/PCDF TEQ Total 4.50E-01 4.50E-01 3.81 E-03 3.81 E-03 Sample ID PS-1000LD3-073115-02 Page 2 (2) 5-B ------- EF EF EF EF EF EF Total TEQ TEQ Total TEQ TEQ Isomer. ng/g Carbon ng/kg fuel ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 1.27E-03 1.27E-03 1.27E-03 5.35E-01 5.35E-01 5.35E-01 1,2,3,7,8- PeCDD 3.72E-04 3.72E-04 3.72E-04 1.57E-01 1.57E-01 1.57E-01 1,2,3,4,7,8- HxCDD 1.06E-04 1.06E-05 1.06E-05 4.48E-02 4.48E-03 4.48E-03 1,2,3,6,7,8- HxCDD 2.38E-04 2.38E-05 2.38E-05 1.00E-01 1.00E-02 1.00E-02 1,2,3,7,8,9- HxCDD 1.94E-04 1.94E-05 1.94E-05 8.17E-02 8.17E-03 8.17E-03 1,2,3,4,6,7,8- HpCDD 2.65E-03 2.65E-05 2.65E-05 1.11E+00 1.11 E-02 1.11 E-02 1,2,3,4,6,7,8,9 - OCDD 7.07E-03 2.12E-06 2.12E-06 2.98E+00 8.93E-04 8.93E-04 2,3,7,8 - TCDF 2.85E-02 2.85E-03 2.85E-03 1.20E+01 1.20E+00 1.20E+00 1,2,3,7,8- PeCDF 5.79E-03 1.74E-04 1.74E-04 2.44E+00 7.31 E-02 7.31 E-02 2,3,4,7,8- PeCDF 6.45E-03 1.93E-03 1.93E-03 2.71 E+00 8.14E-01 8.14E-01 1,2,3,4,7,8- HxCDF 1.10E-03 1.10E-04 1.10E-04 4.61 E-01 4.61 E-02 4.61 E-02 1,2,3,6,7,8- HxCDF 1.05E-03 1.05E-04 1.05E-04 4.44E-01 4.44E-02 4.44E-02 1,2,3,7,8,9- HxCDF 4.91 E-04 4.91 E-05 4.91 E-05 2.07E-01 2.07E-02 2.07E-02 2,3,4,6,7,8 - HxCDF 8.95E-04 8.95E-05 8.95E-05 3.77E-01 3.77E-02 3.77E-02 1,2,3,4,6,7,8- HpCDF 7.82E-04 7.82E-06 7.82E-06 3.29E-01 3.29E-03 3.29E-03 1,2,3,4,7,8,9- HpCDF 1.78E-04 1.78E-06 1.78E-06 7.51 E-02 7.51 E-04 7.51 E-04 1,2,3,4,6,7,8,9-OCDF 5.23E-04 1.57E-07 1.57E-07 2.20E-01 6.60E-05 6.60E-05 TeCDD Total 6.44E-03 2.71 E+00 PeCDD Total 2.16E-03 9.10E-01 HxCDD Total 2.73E-03 1.15E+00 HpCDD Total 4.68E-03 1.97E+00 OCDD 7.07E-03 2.98E+00 TeCDF Total 3.45E-01 1.45E+02 PeCDF Total 4.98E-02 2.10E+01 HxCDF Total 7.89E-03 3.32E+00 HpCDF Total 1.55E-03 6.53E-01 OCDF 5.23E-04 2.20E-01 PCDD Total 2.31 E-02 9.72E+00 PCDF Total 4.05E-01 1.70E+02 PCDD/PCDF Total 4.28E-01 1.80E+02 PCDD TEQ Total 1.73E-03 1.73E-03 7.26E-01 7.26E-01 PCDF TEQ Total 5.32E-03 5.32E-03 2.24E+00 2.24E+00 PCDD/PCDF TEQ Total 7.04E-03 7.04E-03 2.97E+00 2.97E+00 950 Table B-4. PCDD/PCDF data for 32 % NEW 01. Sample ID PS-32NEW-080315-02 MCE 0.935541 Page 1 (2) 6-B ------- Sampling volume (m3) 105.5 Carbon sampled (g) 58.4 Carbon sampled (mg/m3) 554.0 Carbon fraction 0.4 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 9.40E-03 9.40E-03 9.40E-03 8.91 E-05 8.91 E-05 8.91 E-05 1,2,3,7,8- PeCDD 1.20E-02 1.20E-02 1.20E-02 1.14E-04 1.14E-04 1.14E-04 1,2,3,4,7,8- HxCDD 4.60E-03 4.60E-04 4.60E-04 4.36E-05 4.36E-06 4.36E-06 1,2,3,6,7,8- HxCDD 1.22E-02 1.22E-03 1.22E-03 1.16E-04 1.16E-05 1.16E-05 1,2,3,7,8,9- HxCDD 1.22E-02 1.22E-03 1.22E-03 1.16E-04 1.16E-05 1.16E-05 1,2,3,4,6,7,8- HpCDD 1.21E-01 1.21 E-03 1.21 E-03 1.15E-03 1.15E-05 1.15E-05 1,2,3,4,6,7,8,9 - OCDD 3.18E-01 9.53E-05 9.53E-05 3.01 E-03 9.04E-07 9.04E-07 2,3,7,8 - TCDF 4.37E-01 4.37E-02 4.37E-02 4.14E-03 4.14E-04 4.14E-04 1,2,3,7,8- PeCDF 1.25E-01 3.75E-03 3.75E-03 1.19E-03 3.56E-05 3.56E-05 2,3,4,7,8- PeCDF 1.35E-01 4.04E-02 4.04E-02 1.28E-03 3.83E-04 3.83E-04 1,2,3,4,7,8- HxCDF 4.48E-02 4.48E-03 4.48E-03 4.25E-04 4.25E-05 4.25E-05 1,2,3,6,7,8- HxCDF 4.14E-02 4.14E-03 4.14E-03 3.93E-04 3.93E-05 3.93E-05 1,2,3,7,8,9- HxCDF 2.42E-02 2.42E-03 2.42E-03 2.29E-04 2.29E-05 2.29E-05 2,3,4,6,7,8 - HxCDF 3.96E-02 3.96E-03 3.96E-03 3.75E-04 3.75E-05 3.75E-05 1,2,3,4,6,7,8- HpCDF 4.20E-02 4.20E-04 4.20E-04 3.98E-04 3.98E-06 3.98E-06 1,2,3,4,7,8,9- HpCDF 1.40E-02 1.40E-04 1.40E-04 1.33E-04 1.33E-06 1.33E-06 1,2,3,4,6,7,8,9-OCDF 2.16E-02 6.48E-06 6.48E-06 2.05E-04 6.14E-08 6.14E-08 TeCDD Total 1.54E-01 1.46E-03 PeCDD Total 9.86E-02 9.35E-04 HxCDD Total 1.25E-01 1.18E-03 HpCDD Total 2.01 E-01 1.91 E-03 OCDD 3.18E-01 3.01 E-03 TeCDF Total 7.04E+00 6.67E-02 PeCDF Total 1.28E+00 1.21 E-02 HxCDF Total 3.20E-01 3.03E-03 HpCDF Total 8.78E-02 8.32E-04 OCDF 2.50E-02 2.37E-04 PCDD Total 8.96E-01 8.50E-03 PCDF Total 8.74E+00 8.29E-02 PCDD/PCDF Total 9.64E+00 9.14E-02 PCDD TEQ Total 2.56E-02 2.56E-02 2.43E-04 2.43E-04 PCDF TEQ Total 1.03E-01 1.03E-01 9.80E-04 9.80E-04 PCDD/PCDF TEQ Total 1.29E-01 1.29E-01 1.22E-03 1.22E-03 Sample ID PS-32NEW-080315-02 Page 2 (2) 7-B ------- EF EF EF EF EF EF Total TEQ TEQ Total TEQ TEQ Isomer. ng/g Carbon ng/kg fuel ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 1.61 E-04 1.61 E-04 1.61 E-04 7.00E-02 7.00E-02 7.00E-02 1,2,3,7,8- PeCDD 2.05E-04 2.05E-04 2.05E-04 8.94E-02 8.94E-02 8.94E-02 1,2,3,4,7,8- HxCDD 7.87E-05 7.87E-06 7.87E-06 3.43E-02 3.43E-03 3.43E-03 1,2,3,6,7,8- HxCDD 2.09E-04 2.09E-05 2.09E-05 9.08E-02 9.08E-03 9.08E-03 1,2,3,7,8,9- HxCDD 2.09E-04 2.09E-05 2.09E-05 9.08E-02 9.08E-03 9.08E-03 1,2,3,4,6,7,8- HpCDD 2.07E-03 2.07E-05 2.07E-05 9.01 E-01 9.01 E-03 9.01 E-03 1,2,3,4,6,7,8,9 - OCDD 5.44E-03 1.63E-06 1.63E-06 2.37E+00 7.10E-04 7.10E-04 2,3,7,8 - TCDF 7.48E-03 7.48E-04 7.48E-04 3.25E+00 3.25E-01 3.25E-01 1,2,3,7,8- PeCDF 2.14E-03 6.42E-05 6.42E-05 9.31 E-01 2.79E-02 2.79E-02 2,3,4,7,8- PeCDF 2.30E-03 6.91 E-04 6.91 E-04 1.00E+00 3.01 E-01 3.01 E-01 1,2,3,4,7,8- HxCDF 7.67E-04 7.67E-05 7.67E-05 3.34E-01 3.34E-02 3.34E-02 1,2,3,6,7,8- HxCDF 7.08E-04 7.08E-05 7.08E-05 3.08E-01 3.08E-02 3.08E-02 1,2,3,7,8,9- HxCDF 4.14E-04 4.14E-05 4.14E-05 1.80E-01 1.80E-02 1.80E-02 2,3,4,6,7,8 - HxCDF 6.78E-04 6.78E-05 6.78E-05 2.95E-01 2.95E-02 2.95E-02 1,2,3,4,6,7,8- HpCDF 7.19E-04 7.19E-06 7.19E-06 3.13E-01 3.13E-03 3.13E-03 1,2,3,4,7,8,9- HpCDF 2.40E-04 2.40E-06 2.40E-06 1.04E-01 1.04E-03 1.04E-03 1,2,3,4,6,7,8,9-OCDF 3.70E-04 1.11E-07 1.11E-07 1.61 E-01 4.83E-05 4.83E-05 TeCDD Total 2.63E-03 1.15E+00 PeCDD Total 1.69E-03 7.34E-01 HxCDD Total 2.14E-03 9.29E-01 HpCDD Total 3.44E-03 1.50E+00 OCDD 5.44E-03 2.37E+00 TeCDF Total 1.20E-01 5.24E+01 PeCDF Total 2.18E-02 9.50E+00 HxCDF Total 5.47E-03 2.38E+00 HpCDF Total 1.50E-03 6.54E-01 OCDF 4.28E-04 1.86E-01 PCDD Total 1.53E-02 6.67E+00 PCDF Total 1.50E-01 6.51 E+01 PCDD/PCDF Total 1.65E-01 7.18E+01 PCDD TEQ Total 4.38E-04 4.38E-04 1.91 E-01 1.91 E-01 PCDF TEQ Total 1.77E-03 1.77E-03 7.70E-01 7.70E-01 PCDD/PCDF TEQ Total 2.21 E-03 2.21 E-03 9.61 E-01 9.61 E-01 955 Table B-5. PCDD/PCDF data for 32 % NEW 02. Sample ID PS-32NEW2-080415-01 MCE 0.932435 Page 1 (2) Sampling volume (m3) 127.8 8-B ------- Carbon sampled (g) 75.6 Carbon sampled (mg/m3) 591.4 Carbon fraction 0.4 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 1.54E-02 1.54E-02 1.54E-02 1.21E-04 1.21 E-04 1.21 E-04 1,2,3,7,8- PeCDD 1.92E-02 1.92E-02 1.92E-02 1.50E-04 1.50E-04 1.50E-04 1,2,3,4,7,8- HxCDD 7.40E-03 7.40E-04 7.40E-04 5.79E-05 5.79E-06 5.79E-06 1,2,3,6,7,8- HxCDD 1.26E-02 1.26E-03 1.26E-03 9.86E-05 9.86E-06 9.86E-06 1,2,3,7,8,9- HxCDD 1.30E-02 1.30E-03 1.30E-03 1.02E-04 1.02E-05 1.02E-05 1,2,3,4,6,7,8- HpCDD 1.44E-01 1.44E-03 1.44E-03 1.13E-03 1.13E-05 1.13E-05 1,2,3,4,6,7,8,9 - OCDD 4.53E-01 1.36E-04 1.36E-04 3.54E-03 1.06E-06 1.06E-06 2,3,7,8 - TCDF 8.45E-01 8.45E-02 8.45E-02 6.62E-03 6.62E-04 6.62E-04 1,2,3,7,8- PeCDF 1.89E-01 5.67E-03 5.67E-03 1.48E-03 4.44E-05 4.44E-05 2,3,4,7,8- PeCDF 1.82E-01 5.47E-02 5.47E-02 1.43E-03 4.28E-04 4.28E-04 1,2,3,4,7,8- HxCDF 5.14E-02 5.14E-03 5.14E-03 4.02E-04 4.02E-05 4.02E-05 1,2,3,6,7,8- HxCDF 4.96E-02 4.96E-03 4.96E-03 3.88E-04 3.88E-05 3.88E-05 1,2,3,7,8,9- HxCDF 2.56E-02 2.56E-03 2.56E-03 2.00E-04 2.00E-05 2.00E-05 2,3,4,6,7,8 - HxCDF 4.30E-02 4.30E-03 4.30E-03 3.36E-04 3.36E-05 3.36E-05 1,2,3,4,6,7,8- HpCDF 4.64E-02 4.64E-04 4.64E-04 3.63E-04 3.63E-06 3.63E-06 1,2,3,4,7,8,9- HpCDF 1.18E-02 1.18E-04 1.18E-04 9.23E-05 9.23E-07 9.23E-07 1,2,3,4,6,7,8,9-OCDF 4.36E-02 1.31 E-05 1.31 E-05 3.41 E-04 1.02E-07 1.02E-07 TeCDD Total 1.89E-01 1.48E-03 PeCDD Total 1.31E-01 1.03E-03 HxCDD Total 1.47E-01 1.15E-03 HpCDD Total 2.53E-01 1.98E-03 OCDD 4.53E-01 3.54E-03 TeCDF Total 1.28E+01 1.00E-01 PeCDF Total 1.91E+00 1.49E-02 HxCDF Total 3.45E-01 2.70E-03 HpCDF Total 8.08E-02 6.32E-04 OCDF 4.36E-02 3.41 E-04 PCDD Total 1.17E+00 9.18E-03 PCDF Total 1.52E+01 1.19E-01 PCDD/PCDF Total 1.64E+01 1.28E-01 PCDD TEQ Total 3.95E-02 3.95E-02 3.09E-04 3.09E-04 PCDF TEQ Total 1.62E-01 1.62E-01 1.27E-03 1.27E-03 PCDD/PCDF TEQ Total 2.02E-01 2.02E-01 1.58E-03 1.58E-03 Sample ID PS-32NEW2-080415-01 Page 2 (2) 9-B ------- EF EF EF EF EF EF Total TEQ TEQ Total TEQ TEQ Isomer. ng/g Carbon ng/kg fuel ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 2.04E-04 2.04E-04 2.04E-04 8.87E-02 8.87E-02 8.87E-02 1,2,3,7,8- PeCDD 2.54E-04 2.54E-04 2.54E-04 1.11 E-01 1.11 E-01 1.11 E-01 1,2,3,4,7,8- HxCDD 9.79E-05 9.79E-06 9.79E-06 4.26E-02 4.26E-03 4.26E-03 1,2,3,6,7,8- HxCDD 1.67E-04 1.67E-05 1.67E-05 7.26E-02 7.26E-03 7.26E-03 1,2,3,7,8,9- HxCDD 1.72E-04 1.72E-05 1.72E-05 7.49E-02 7.49E-03 7.49E-03 1,2,3,4,6,7,8- HpCDD 1.91 E-03 1.91E-05 1.91 E-05 8.30E-01 8.30E-03 8.30E-03 1,2,3,4,6,7,8,9 - OCDD 5.99E-03 1.80E-06 1.80E-06 2.61 E+00 7.82E-04 7.82E-04 2,3,7,8 - TCDF 1.12E-02 1.12E-03 1.12E-03 4.87E+00 4.87E-01 4.87E-01 1,2,3,7,8- PeCDF 2.50E-03 7.50E-05 7.50E-05 1.09E+00 3.26E-02 3.26E-02 2,3,4,7,8- PeCDF 2.41 E-03 7.23E-04 7.23E-04 1.05E+00 3.15E-01 3.15E-01 1,2,3,4,7,8- HxCDF 6.80E-04 6.80E-05 6.80E-05 2.96E-01 2.96E-02 2.96E-02 1,2,3,6,7,8- HxCDF 6.56E-04 6.56E-05 6.56E-05 2.86E-01 2.86E-02 2.86E-02 1,2,3,7,8,9- HxCDF 3.39E-04 3.39E-05 3.39E-05 1.47E-01 1.47E-02 1.47E-02 2,3,4,6,7,8 - HxCDF 5.69E-04 5.69E-05 5.69E-05 2.48E-01 2.48E-02 2.48E-02 1,2,3,4,6,7,8- HpCDF 6.14E-04 6.14E-06 6.14E-06 2.67E-01 2.67E-03 2.67E-03 1,2,3,4,7,8,9- HpCDF 1.56E-04 1.56E-06 1.56E-06 6.79E-02 6.79E-04 6.79E-04 1,2,3,4,6,7,8,9-OCDF 5.77E-04 1.73E-07 1.73E-07 2.51 E-01 7.53E-05 7.53E-05 TeCDD Total 2.51 E-03 1.09E+00 PeCDD Total 1.74E-03 7.55E-01 HxCDD Total 1.95E-03 8.46E-01 HpCDD Total 3.35E-03 1.46E+00 OCDD 5.99E-03 2.61 E+00 TeCDF Total 1.70E-01 7.38E+01 PeCDF Total 2.52E-02 1.10E+01 HxCDF Total 4.57E-03 1.99E+00 HpCDF Total 1.07E-03 4.65E-01 OCDF 5.77E-04 2.51 E-01 PCDD Total 1.55E-02 6.76E+00 PCDF Total 2.01 E-01 8.74E+01 PCDD/PCDF Total 2.16E-01 9.42E+01 PCDD TEQ Total 5.22E-04 5.22E-04 2.27E-01 2.27E-01 PCDF TEQ Total 2.15E-03 2.15E-03 9.35E-01 9.35E-01 PCDD/PCDF TEQ Total 2.67E-03 2.67E-03 1.16E+00 1.16E+00 960 Table B-6. PCDD/PCDF data for 32 % NEW 03. Sample ID PS-32NEW3-080615 MCE 0.934109 Page 1 (2) Sampling volume (m3) 129.6 10-B ------- Carbon sampled (g) 87.9 Carbon sampled (mg/m3) 678.1 Carbon fraction 0.435 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 8.00E-03 8.00E-03 8.00E-03 6.17E-05 6.17E-05 6.17E-05 1,2,3,7,8- PeCDD 1.30E-02 1.30E-02 1.30E-02 1.00E-04 1.00E-04 1.00E-04 1,2,3,4,7,8- HxCDD 4.20E-03 4.20E-04 4.20E-04 3.24E-05 3.24E-06 3.24E-06 1,2,3,6,7,8- HxCDD 1.40E-02 1.40E-03 1.40E-03 1.08E-04 1.08E-05 1.08E-05 1,2,3,7,8,9- HxCDD 1.02E-02 1.02E-03 1.02E-03 7.87E-05 7.87E-06 7.87E-06 1,2,3,4,6,7,8- HpCDD 1.86E-01 1.86E-03 1.86E-03 1.44E-03 1.44E-05 1.44E-05 1,2,3,4,6,7,8,9 - OCDD 5.00E-01 1.50E-04 1.50E-04 3.86E-03 1.16E-06 1.16E-06 2,3,7,8 - TCDF 4.04E-01 4.04E-02 4.04E-02 3.12E-03 3.12E-04 3.12E-04 1,2,3,7,8- PeCDF 1.17E-01 3.50E-03 3.50E-03 9.00E-04 2.70E-05 2.70E-05 2,3,4,7,8- PeCDF 1.21E-01 3.62E-02 3.62E-02 9.32E-04 2.80E-04 2.80E-04 1,2,3,4,7,8- HxCDF 3.48E-02 3.48E-03 3.48E-03 2.69E-04 2.69E-05 2.69E-05 1,2,3,6,7,8- HxCDF 4.14E-02 4.14E-03 4.14E-03 3.20E-04 3.20E-05 3.20E-05 1,2,3,7,8,9- HxCDF 1.48E-02 1.48E-03 1.48E-03 1.14E-04 1.14E-05 1.14E-05 2,3,4,6,7,8 - HxCDF 3.44E-02 3.44E-03 3.44E-03 2.65E-04 2.65E-05 2.65E-05 1,2,3,4,6,7,8- HpCDF 3.84E-02 3.84E-04 3.84E-04 2.96E-04 2.96E-06 2.96E-06 1,2,3,4,7,8,9- HpCDF 1.02E-02 1.02E-04 1.02E-04 7.87E-05 7.87E-07 7.87E-07 1,2,3,4,6,7,8,9-OCDF 4.42E-02 1.33E-05 1.33E-05 3.41 E-04 1.02E-07 1.02E-07 TeCDD Total 1.21E-01 9.35E-04 PeCDD Total 8.76E-02 6.76E-04 HxCDD Total 1.43E-01 1.10E-03 HpCDD Total 3.25E-01 2.51 E-03 OCDD 5.00E-01 3.86E-03 TeCDF Total 9.04E+00 6.98E-02 PeCDF Total 1.35E+00 1.04E-02 HxCDF Total 3.06E-01 2.36E-03 HpCDF Total 7.86E-02 6.07E-04 OCDF 4.42E-02 3.41 E-04 PCDD Total 1.18E+00 9.09E-03 PCDF Total 1.08E+01 8.35E-02 PCDD/PCDF Total 1.20E+01 9.26E-02 PCDD TEQ Total 2.59E-02 2.59E-02 2.00E-04 2.00E-04 PCDF TEQ Total 9.32E-02 9.32E-02 7.19E-04 7.19E-04 PCDD/PCDF TEQ Total 1.19E-01 1.19E-01 9.19E-04 9.19E-04 Sample ID PS-32NEW3-080615 Page 2 (2) LL LU LL LU EF I EF EF EF I 11-B ------- Total TEQ TEQ Total TEQ TEQ Isomer. ng/g Carbon ng/kg fuel ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 9.11E-05 9.11E-05 9.11 E-05 3.96E-02 3.96E-02 3.96E-02 1,2,3,7,8- PeCDD 1.48E-04 1.48E-04 1.48E-04 6.44E-02 6.44E-02 6.44E-02 1,2,3,4,7,8- HxCDD 4.78E-05 4.78E-06 4.78E-06 2.08E-02 2.08E-03 2.08E-03 1,2,3,6,7,8- HxCDD 1.59E-04 1.59E-05 1.59E-05 6.93E-02 6.93E-03 6.93E-03 1,2,3,7,8,9- HxCDD 1.16E-04 1.16E-05 1.16E-05 5.05E-02 5.05E-03 5.05E-03 1,2,3,4,6,7,8- HpCDD 2.12E-03 2.12E-05 2.12E-05 9.21 E-01 9.21 E-03 9.21 E-03 1,2,3,4,6,7,8,9 - OCDD 5.69E-03 1.71 E-06 1.71 E-06 2.48E+00 7.43E-04 7.43E-04 2,3,7,8 - TCDF 4.60E-03 4.60E-04 4.60E-04 2.00E+00 2.00E-01 2.00E-01 1,2,3,7,8- PeCDF 1.33E-03 3.98E-05 3.98E-05 5.77E-01 1.73E-02 1.73E-02 2,3,4,7,8- PeCDF 1.37E-03 4.12E-04 4.12E-04 5.98E-01 1.79E-01 1.79E-01 1,2,3,4,7,8- HxCDF 3.96E-04 3.96E-05 3.96E-05 1.72E-01 1.72E-02 1.72E-02 1,2,3,6,7,8- HxCDF 4.71 E-04 4.71 E-05 4.71 E-05 2.05E-01 2.05E-02 2.05E-02 1,2,3,7,8,9- HxCDF 1.68E-04 1.68E-05 1.68E-05 7.33E-02 7.33E-03 7.33E-03 2,3,4,6,7,8 - HxCDF 3.92E-04 3.92E-05 3.92E-05 1.70E-01 1.70E-02 1.70E-02 1,2,3,4,6,7,8- HpCDF 4.37E-04 4.37E-06 4.37E-06 1.90E-01 1.90E-03 1.90E-03 1,2,3,4,7,8,9- HpCDF 1.16E-04 1.16E-06 1.16E-06 5.05E-02 5.05E-04 5.05E-04 1,2,3,4,6,7,8,9-OCDF 5.03E-04 1.51 E-07 1.51 E-07 2.19E-01 6.57E-05 6.57E-05 TeCDD Total 1.38E-03 6.00E-01 PeCDD Total 9.97E-04 4.34E-01 HxCDD Total 1.63E-03 7.08E-01 HpCDD Total 3.70E-03 1.61 E+00 OCDD 5.69E-03 2.48E+00 TeCDF Total 1.03E-01 4.48E+01 PeCDF Total 1.53E-02 6.67E+00 HxCDF Total 3.49E-03 1.52E+00 HpCDF Total 8.95E-04 3.89E-01 OCDF 5.03E-04 2.19E-01 PCDD Total 1.34E-02 5.83E+00 PCDF Total 1.23E-01 5.36E+01 PCDD/PCDF Total 1.37E-01 5.94E+01 PCDD TEQ Total 2.94E-04 2.94E-04 1.28E-01 1.28E-01 PCDF TEQ Total 1.06E-03 1.06E-03 4.61 E-01 4.61 E-01 PCDD/PCDF TEQ Total 1.35E-03 1.35E-03 5.89E-01 5.89E-01 965 Table B-7. PCDD/PCDF data for 66 % NEW 01. Sample ID PS-66NEW-081215 MCE 0.934443 Page 1 (2) Sampling volume (m3) 99.5 Carbon sampled (g) 61.6 12-B ------- Carbon sampled (mg/m3) Carbon fraction 619.1 0.426 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 2.40E-03 2.40E-03 2.40E-03 2.41 E-05 2.41 E-05 2.41 E-05 1,2,3,7,8- PeCDD 6.20E-03 6.20E-03 6.20E-03 6.23E-05 6.23E-05 6.23E-05 1,2,3,4,7,8- HxCDD 4.00E-03 4.00E-04 4.00E-04 4.02E-05 4.02E-06 4.02E-06 1,2,3,6,7,8- HxCDD 1.02E-02 1.02E-03 1.02E-03 1.02E-04 1.02E-05 1.02E-05 1,2,3,7,8,9- HxCDD 9.40E-03 9.40E-04 9.40E-04 9.45E-05 9.45E-06 9.45E-06 1,2,3,4,6,7,8- HpCDD 1.33E-01 1.33E-03 1.33E-03 1.33E-03 1.33E-05 1.33E-05 1,2,3,4,6,7,8,9 - OCDD 4.04E-01 1.21E-04 1.21 E-04 4.06E-03 1.22E-06 1.22E-06 2,3,7,8 - TCDF 7.90E-02 7.90E-03 7.90E-03 7.94E-04 7.94E-05 7.94E-05 1,2,3,7,8- PeCDF 2.04E-02 6.12E-04 6.12E-04 2.05E-04 6.15E-06 6.15E-06 2,3,4,7,8- PeCDF 2.20E-02 6.60E-03 6.60E-03 2.21 E-04 6.63E-05 6.63E-05 1,2,3,4,7,8- HxCDF 1.28E-02 1.28E-03 1.28E-03 1.29E-04 1.29E-05 1.29E-05 1,2,3,6,7,8- HxCDF 1.00E-02 1.00E-03 1.00E-03 1.00E-04 1.00E-05 1.00E-05 1,2,3,7,8,9- HxCDF 5.20E-03 5.20E-04 5.20E-04 5.23E-05 5.23E-06 5.23E-06 2,3,4,6,7,8 - HxCDF 1.12E-02 1.12E-03 1.12E-03 1.13E-04 1.13E-05 1.13E-05 1,2,3,4,6,7,8- HpCDF 2.38E-02 2.38E-04 2.38E-04 2.39E-04 2.39E-06 2.39E-06 1,2,3,4,7,8,9- HpCDF 4.40E-03 4.40E-05 4.40E-05 4.42E-05 4.42E-07 4.42E-07 1,2,3,4,6,7,8,9-OCDF 2.82E-02 8.46E-06 8.46E-06 2.83E-04 8.50E-08 8.50E-08 TeCDD Total 1.20E-01 1.21E-03 PeCDD Total 7.30E-02 7.34E-04 HxCDD Total 1.03E-01 1.04E-03 HpCDD Total 2.16E-01 2.17E-03 OCDD 4.04E-01 4.06E-03 TeCDF Total 2.66E+00 2.67E-02 PeCDF Total 2.50E-01 2.51 E-03 HxCDF Total 9.08E-02 9.12E-04 HpCDF Total 3.48E-02 3.50E-04 OCDF 2.82E-02 2.83E-04 PCDD Total 9.17E-01 9.21 E-03 PCDF Total 3.06E+00 3.08E-02 PCDD/PCDF Total 3.98E+00 4.00E-02 PCDD TEQ Total 1.24E-02 1.24E-02 1.25E-04 1.25E-04 PCDF TEQ Total 1.93E-02 1.93E-02 1.94E-04 1.94E-04 PCDD/PCDF TEQ Total 3.17E-02 3.17E-02 3.19E-04 3.19E-04 Sample ID P S-66 N EW-081215 Page 2 (2) EF EF EF I EF EF EF 13-B ------- Total TEQ TEQ Total TEQ TEQ Isomer. ng/g Carbon ng/kg fuel ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 3.90E-05 3.90E-05 3.90E-05 1.66E-02 1.66E-02 1.66E-02 1,2,3,7,8- PeCDD 1.01E-04 1.01 E-04 1.01 E-04 4.29E-02 4.29E-02 4.29E-02 1,2,3,4,7,8- HxCDD 6.49E-05 6.49E-06 6.49E-06 2.77E-02 2.77E-03 2.77E-03 1,2,3,6,7,8- HxCDD 1.66E-04 1.66E-05 1.66E-05 7.05E-02 7.05E-03 7.05E-03 1,2,3,7,8,9- HxCDD 1.53E-04 1.53E-05 1.53E-05 6.50E-02 6.50E-03 6.50E-03 1,2,3,4,6,7,8- HpCDD 2.15E-03 2.15E-05 2.15E-05 9.17E-01 9.17E-03 9.17E-03 1,2,3,4,6,7,8,9 - OCDD 6.56E-03 1.97E-06 1.97E-06 2.79E+00 8.38E-04 8.38E-04 2,3,7,8 - TCDF 1.28E-03 1.28E-04 1.28E-04 5.46E-01 5.46E-02 5.46E-02 1,2,3,7,8- PeCDF 3.31 E-04 9.93E-06 9.93E-06 1.41 E-01 4.23E-03 4.23E-03 2,3,4,7,8- PeCDF 3.57E-04 1.07E-04 1.07E-04 1.52E-01 4.56E-02 4.56E-02 1,2,3,4,7,8- HxCDF 2.08E-04 2.08E-05 2.08E-05 8.85E-02 8.85E-03 8.85E-03 1,2,3,6,7,8- HxCDF 1.62E-04 1.62E-05 1.62E-05 6.91 E-02 6.91 E-03 6.91 E-03 1,2,3,7,8,9- HxCDF 8.44E-05 8.44E-06 8.44E-06 3.59E-02 3.59E-03 3.59E-03 2,3,4,6,7,8 - HxCDF 1.82E-04 1.82E-05 1.82E-05 7.74E-02 7.74E-03 7.74E-03 1,2,3,4,6,7,8- HpCDF 3.86E-04 3.86E-06 3.86E-06 1.65E-01 1.65E-03 1.65E-03 1,2,3,4,7,8,9- HpCDF 7.14E-05 7.14E-07 7.14E-07 3.04E-02 3.04E-04 3.04E-04 1,2,3,4,6,7,8,9-OCDF 4.58E-04 1.37E-07 1.37E-07 1.95E-01 5.85E-05 5.85E-05 TeCDD Total 1.95E-03 8.31 E-01 PeCDD Total 1.18E-03 5.05E-01 HxCDD Total 1.67E-03 7.12E-01 HpCDD Total 3.51 E-03 1.49E+00 OCDD 6.56E-03 2.79E+00 TeCDF Total 4.31 E-02 1.84E+01 PeCDF Total 4.05E-03 1.73E+00 HxCDF Total 1.47E-03 6.28E-01 HpCDF Total 5.65E-04 2.41 E-01 OCDF 4.58E-04 1.95E-01 PCDD Total 1.49E-02 6.34E+00 PCDF Total 4.97E-02 2.12E+01 PCDD/PCDF Total 6.46E-02 2.75E+01 PCDD TEQ Total 2.01 E-04 2.01 E-04 8.58E-02 8.58E-02 PCDF TEQ Total 3.14E-04 3.14E-04 1.34E-01 1.34E-01 PCDD/PCDF TEQ Total 5.15E-04 5.15E-04 2.19E-01 2.19E-01 970 Table B-8. PCDD/PCDF data for 66 % NEW 02. Sample ID PS-66NEW2-081315-01 Sampling volume (m3) 91.1 Carbon sampled (g) 67.8 Page 1 (2) MCE 0.945527 14-B ------- Carbon sampled (mg/m3) 744.6 Carbon fraction 0.4 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 3.00E-03 3.00E-03 3.00E-03 3.29E-05 3.29E-05 3.29E-05 1,2,3,7,8- PeCDD 4.00E-03 4.00E-03 4.00E-03 4.39E-05 4.39E-05 4.39E-05 1,2,3,4,7,8- HxCDD 3.00E-03 3.00E-04 3.00E-04 3.29E-05 3.29E-06 3.29E-06 1,2,3,6,7,8- HxCDD 8.20E-03 8.20E-04 8.20E-04 9.00E-05 9.00E-06 9.00E-06 1,2,3,7,8,9- HxCDD 7.80E-03 7.80E-04 7.80E-04 8.56E-05 8.56E-06 8.56E-06 1,2,3,4,6,7,8- HpCDD 1.35E-01 1.35E-03 1.35E-03 1.48E-03 1.48E-05 1.48E-05 1,2,3,4,6,7,8,9 - OCDD 4.14E-01 1.24E-04 1.24E-04 4.55E-03 1.36E-06 1.36E-06 2,3,7,8 - TCDF 1.16E-01 1.16E-02 1.16E-02 1.28E-03 1.28E-04 1.28 E-04 1,2,3,7,8- PeCDF 2.72E-02 8.16E-04 8.16E-04 2.99E-04 8.96E-06 8.96E-06 2,3,4,7,8- PeCDF 2.62E-02 7.86E-03 7.86E-03 2.88E-04 8.63E-05 8.63E-05 1,2,3,4,7,8- HxCDF 1.00E-02 1.00E-03 1.00E-03 1.10E-04 1.10E-05 1.10E-05 1,2,3,6,7,8- HxCDF 1.10E-02 1.10E-03 1.10E-03 1.21 E-04 1.21 E-05 1.21 E-05 1,2,3,7,8,9- HxCDF 4.60E-03 4.60E-04 4.60E-04 5.05E-05 5.05E-06 5.05E-06 2,3,4,6,7,8 - HxCDF 9.40E-03 9.40E-04 9.40E-04 1.03E-04 1.03E-05 1.03E-05 1,2,3,4,6,7,8- HpCDF 1.86E-02 1.86E-04 1.86E-04 2.04E-04 2.04E-06 2.04E-06 1,2,3,4,7,8,9- HpCDF 3.20E-03 3.20E-05 3.20E-05 3.51 E-05 3.51 E-07 3.51 E-07 1,2,3,4,6,7,8,9-OCDF 2.28E-02 6.84E-06 6.84E-06 2.50E-04 7.51 E-08 7.51 E-08 TeCDD Total 8.66E-02 9.51 E-04 PeCDD Total 4.18E-02 4.59E-04 HxCDD Total 8.42E-02 9.24E-04 HpCDD Total 2.21 E-01 2.43E-03 OCDD 4.14E-01 4.55E-03 TeCDF Total 3.91 E+00 4.29E-02 PeCDF Total 2.76E-01 3.03E-03 HxCDF Total 6.66E-02 7.31 E-04 HpCDF Total 3.92E-02 4.30E-04 OCDF 2.28E-02 2.50E-04 PCDD Total 8.48E-01 9.31 E-03 PCDF Total 4.32E+00 4.74E-02 PCDD/PCDF Total 5.16E+00 5.67E-02 PCDD TEQ Total 1.04E-02 1.04E-02 1.14E-04 1.14E-04 PCDF TEQ Total 2.40E-02 2.40E-02 2.64E-04 2.64E-04 PCDD/PCDF TEQ Total 3.44E-02 3.44E-02 3.78E-04 3.78E-04 Sample ID PS-66NEW2-081315-01 Page 2 (2) EF EF EF EF EF EF 15-B ------- Total TEQ TEQ Total TEQ TEQ Isomer. ng/g Carbon ng/kg fuel ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 4.42E-05 4.42E-05 4.42E-05 1.88E-02 1.88E-02 1.88E-02 1,2,3,7,8- PeCDD 5.90E-05 5.90E-05 5.90E-05 2.51 E-02 2.51 E-02 2.51 E-02 1,2,3,4,7,8- HxCDD 4.42E-05 4.42E-06 4.42E-06 1.88E-02 1.88E-03 1.88E-03 1,2,3,6,7,8- HxCDD 1.21 E-04 1.21E-05 1.21 E-05 5.15E-02 5.15E-03 5.15E-03 1,2,3,7,8,9- HxCDD 1.15E-04 1.15E-05 1.15E-05 4.90E-02 4.90E-03 4.90E-03 1,2,3,4,6,7,8- HpCDD 1.98E-03 1.98E-05 1.98E-05 8.45E-01 8.45E-03 8.45E-03 1,2,3,4,6,7,8,9 - OCDD 6.11E-03 1.83E-06 1.83E-06 2.60E+00 7.80E-04 7.80E-04 2,3,7,8 - TCDF 1.71 E-03 1.71 E-04 1.71 E-04 7.30E-01 7.30E-02 7.30E-02 1,2,3,7,8- PeCDF 4.01 E-04 1.20E-05 1.20E-05 1.71E-01 5.13E-03 5.13E-03 2,3,4,7,8- PeCDF 3.86E-04 1.16E-04 1.16E-04 1.65E-01 4.94E-02 4.94E-02 1,2,3,4,7,8- HxCDF 1.47E-04 1.47E-05 1.47E-05 6.28E-02 6.28E-03 6.28E-03 1,2,3,6,7,8- HxCDF 1.62E-04 1.62E-05 1.62E-05 6.91 E-02 6.91 E-03 6.91 E-03 1,2,3,7,8,9- HxCDF 6.78E-05 6.78E-06 6.78E-06 2.89E-02 2.89E-03 2.89E-03 2,3,4,6,7,8 - HxCDF 1.39E-04 1.39E-05 1.39E-05 5.90E-02 5.90E-03 5.90E-03 1,2,3,4,6,7,8- HpCDF 2.74E-04 2.74E-06 2.74E-06 1.17E-01 1.17E-03 1.17E-03 1,2,3,4,7,8,9- HpCDF 4.72E-05 4.72E-07 4.72E-07 2.01 E-02 2.01 E-04 2.01 E-04 1,2,3,4,6,7,8,9-OCDF 3.36E-04 1.01E-07 1.01 E-07 1.43E-01 4.30E-05 4.30E-05 TeCDD Total 1.28E-03 5.44E-01 PeCDD Total 6.16E-04 2.63E-01 HxCDD Total 1.24E-03 5.29E-01 HpCDD Total 3.26E-03 1.39E+00 OCDD 6.11 E-03 2.60E+00 TeCDF Total 5.77E-02 2.46E+01 PeCDF Total 4.06E-03 1.73E+00 HxCDF Total 9.82E-04 4.18E-01 HpCDF Total 5.78E-04 2.46E-01 OCDF 3.36E-04 1.43E-01 PCDD Total 1.25E-02 5.32E+00 PCDF Total 6.36E-02 2.71 E+01 PCDD/PCDF Total 7.61 E-02 3.24E+01 PCDD TEQ Total 1.53E-04 1.53E-04 6.51 E-02 6.51 E-02 PCDF TEQ Total 3.54E-04 3.54E-04 1.51 E-01 1.51 E-01 PCDD/PCDF TEQ Total 5.07E-04 5.07E-04 2.16E-01 2.16E-01 975 Table B-9. PCDD/PCDF data for 66 % NEW 03. Sample ID PS-66NEW3-081315-02 Sampling volume (m3) 82.8 Carbon sampled (g) 58.7 Carbon sampled (mg/m3) 709.3 MCE 0.957416 Page 1 (2) 16-B ------- Carbon fraction 0.4 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 6.60E-03 6.60E-03 6.60E-03 7.97E-05 7.97E-05 7.97E-05 1,2,3,7,8- PeCDD 6.60E-03 6.60E-03 6.60E-03 7.97E-05 7.97E-05 7.97E-05 1,2,3,4,7,8- HxCDD 3.40E-03 3.40E-04 3.40E-04 4.11E-05 4.11E-06 4.11E-06 1,2,3,6,7,8- HxCDD 9.80E-03 9.80E-04 9.80E-04 1.18E-04 1.18E-05 1.18E-05 1,2,3,7,8,9- HxCDD 8.60E-03 8.60E-04 8.60E-04 1.04E-04 1.04E-05 1.04E-05 1,2,3,4,6,7,8- HpCDD 1.27E-01 1.27E-03 1.27E-03 1.54E-03 1.54E-05 1.54E-05 1,2,3,4,6,7,8,9 - OCDD 3.78E-01 1.13E-04 1.13E-04 4.57E-03 1.37E-06 1.37E-06 2,3,7,8 - TCDF 2.24E-01 2.24E-02 2.24E-02 2.71 E-03 2.71 E-04 2.71 E-04 1,2,3,7,8- PeCDF 5.84E-02 1.75E-03 1.75E-03 7.05E-04 2.12E-05 2.12E-05 2,3,4,7,8- PeCDF 5.92E-02 1.78E-02 1.78E-02 7.15E-04 2.15E-04 2.15E-04 1,2,3,4,7,8- HxCDF 1.68E-02 1.68E-03 1.68E-03 2.03E-04 2.03E-05 2.03E-05 1,2,3,6,7,8- HxCDF 1.66E-02 1.66E-03 1.66E-03 2.01 E-04 2.01 E-05 2.01 E-05 1,2,3,7,8,9- HxCDF 7.60E-03 7.60E-04 7.60E-04 9.18E-05 9.18E-06 9.18E-06 2,3,4,6,7,8 - HxCDF 1.56E-02 1.56E-03 1.56E-03 1.88E-04 1.88E-05 1.88E-05 1,2,3,4,6,7,8- HpCDF 2.12E-02 2.12E-04 2.12E-04 2.56E-04 2.56E-06 2.56E-06 1,2,3,4,7,8,9- HpCDF 4.20E-03 4.20E-05 4.20E-05 5.07E-05 5.07E-07 5.07E-07 1,2,3,4,6,7,8,9-OCDF 1.96E-02 5.88E-06 5.88E-06 2.37E-04 7.10E-08 7.10E-08 TeCDD Total 9.96E-02 1.20E-03 PeCDD Total 4.64E-02 5.60E-04 HxCDD Total 9.50E-02 1.15E-03 HpCDD Total 2.17E-01 2.63E-03 OCDD 3.78E-01 4.57E-03 TeCDF Total 4.73E+00 5.72E-02 PeCDF Total 5.28E-01 6.38E-03 HxCDF Total 1.27E-01 1.53E-03 HpCDF Total 3.76E-02 4.54E-04 OCDF 1.96E-02 2.37E-04 PCDD Total 8.37E-01 1.01 E-02 PCDF Total 5.44E+00 6.58E-02 PCDD/PCDF Total 6.28E+00 7.59E-02 PCDD TEQ Total 1.68E-02 1.68E-02 2.03E-04 2.03E-04 PCDF TEQ Total 4.79E-02 4.79E-02 5.78E-04 5.78E-04 PCDD/PCDF TEQ Total 6.46E-02 6.46E-02 7.81 E-04 7.81 E-04 Sample ID PS-66NEW3-081315-02 Page 2 (2) EF EF EF EF EF EF Total TEQ TEQ Total TEQ TEQ 17-B ------- Isomer. ng/g Carbon ng/kg fuel ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 1.12E-04 1.12E-04 1.12E-04 4.79E-02 4.79E-02 4.79E-02 1,2,3,7,8- PeCDD 1.12E-04 1.12E-04 1.12E-04 4.79E-02 4.79E-02 4.79E-02 1,2,3,4,7,8- HxCDD 5.79E-05 5.79E-06 5.79E-06 2.47E-02 2.47E-03 2.47E-03 1,2,3,6,7,8- HxCDD 1.67E-04 1.67E-05 1.67E-05 7.11E-02 7.11 E-03 7.11 E-03 1,2,3,7,8,9- HxCDD 1.46E-04 1.46E-05 1.46E-05 6.24E-02 6.24E-03 6.24E-03 1,2,3,4,6,7,8- HpCDD 2.17E-03 2.17E-05 2.17E-05 9.24E-01 9.24E-03 9.24E-03 1,2,3,4,6,7,8,9 - OCDD 6.44E-03 1.93E-06 1.93E-06 2.74E+00 8.23E-04 8.23E-04 2,3,7,8 - TCDF 3.82E-03 3.82E-04 3.82E-04 1.63E+00 1.63E-01 1.63E-01 1,2,3,7,8- PeCDF 9.94E-04 2.98E-05 2.98E-05 4.24E-01 1.27E-02 1.27E-02 2,3,4,7,8- PeCDF 1.01 E-03 3.02E-04 3.02E-04 4.29E-01 1.29E-01 1.29E-01 1,2,3,4,7,8- HxCDF 2.86E-04 2.86E-05 2.86E-05 1.22E-01 1.22E-02 1.22E-02 1,2,3,6,7,8- HxCDF 2.83E-04 2.83E-05 2.83E-05 1.20E-01 1.20E-02 1.20E-02 1,2,3,7,8,9- HxCDF 1.29E-04 1.29E-05 1.29E-05 5.51 E-02 5.51 E-03 5.51 E-03 2,3,4,6,7,8 - HxCDF 2.66E-04 2.66E-05 2.66E-05 1.13E-01 1.13E-02 1.13E-02 1,2,3,4,6,7,8- HpCDF 3.61 E-04 3.61 E-06 3.61 E-06 1.54E-01 1.54E-03 1.54E-03 1,2,3,4,7,8,9- HpCDF 7.15E-05 7.15E-07 7.15E-07 3.05E-02 3.05E-04 3.05E-04 1,2,3,4,6,7,8,9-OCDF 3.34E-04 1.00E-07 1.00E-07 1.42E-01 4.26E-05 4.26E-05 TeCDD Total 1.70E-03 7.22E-01 PeCDD Total 7.90E-04 3.37E-01 HxCDD Total 1.62E-03 6.89E-01 HpCDD Total 3.70E-03 1.58E+00 OCDD 6.44E-03 2.74E+00 TeCDF Total 8.06E-02 3.43E+01 PeCDF Total 8.99E-03 3.83E+00 HxCDF Total 2.16E-03 9.20E-01 HpCDF Total 6.40E-04 2.73E-01 OCDF 3.34E-04 1.42E-01 PCDD Total 1.42E-02 6.07E+00 PCDF Total 9.27E-02 3.95E+01 PCDD/PCDF Total 1.07E-01 4.56E+01 PCDD TEQ Total 2.86E-04 2.86E-04 1.22E-01 1.22E-01 PCDF TEQ Total 8.15E-04 8.15E-04 3.47E-01 3.47E-01 PCDD/PCDF TEQ Total 1.10E-03 1.10E-03 4.69E-01 4.69E-01 980 Table B-10. PCDD/PCDF data for 100 % NEW 01. Page 1 (2) Sample ID PS-100NEW-072915-01 MCE 0.944463 Sampling volume (m3) 129.1 Carbon sampled (g) 74.3 Carbon sampled (mg/m3) 575.6 18-B ------- Carbon fraction 0.462 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 1.14E-02 1.14E-02 1.14E-02 8.83E-05 8.83E-05 8.83E-05 1,2,3,7,8- PeCDD 1.72E-02 1.72E-02 1.72E-02 1.33E-04 1.33E-04 1.33E-04 1,2,3,4,7,8- HxCDD 7.80E-03 7.80E-04 7.80E-04 6.04E-05 6.04E-06 6.04E-06 1,2,3,6,7,8- HxCDD 1.50E-02 1.50E-03 1.50E-03 1.16E-04 1.16E-05 1.16E-05 1,2,3,7,8,9- HxCDD 1.08E-02 1.08E-03 1.08E-03 8.37E-05 8.37E-06 8.37E-06 1,2,3,4,6,7,8- HpCDD 1.68E-01 1.68E-03 1.68E-03 1.30E-03 1.30E-05 1.30E-05 1,2,3,4,6,7,8,9 - OCDD 5.04E-01 1.51 E-04 1.51E-04 3.90E-03 1.17E-06 1.17E-06 2,3,7,8 - TCDF 5.17E-01 5.17E-02 5.17E-02 4.00E-03 4.00E-04 4.00E-04 1,2,3,7,8- PeCDF 1.29E-01 3.88E-03 3.88E-03 1.00E-03 3.01 E-05 3.01 E-05 2,3,4,7,8- PeCDF 1.22E-01 3.67E-02 3.67E-02 9.47E-04 2.84E-04 2.84E-04 1,2,3,4,7,8- HxCDF 4.28E-02 4.28E-03 4.28E-03 3.32E-04 3.32E-05 3.32E-05 1,2,3,6,7,8- HxCDF 3.62E-02 3.62E-03 3.62E-03 2.80E-04 2.80E-05 2.80E-05 1,2,3,7,8,9- HxCDF 1.82E-02 1.82E-03 1.82E-03 1.41 E-04 1.41 E-05 1.41 E-05 2,3,4,6,7,8 - HxCDF 3.96E-02 3.96E-03 3.96E-03 3.07E-04 3.07E-05 3.07E-05 1,2,3,4,6,7,8- HpCDF 5.72E-02 5.72E-04 5.72E-04 4.43E-04 4.43E-06 4.43E-06 1,2,3,4,7,8,9- HpCDF 1.24E-02 1.24E-04 1.24E-04 9.61 E-05 9.61 E-07 9.61 E-07 1,2,3,4,6,7,8,9-OCDF 4.52E-02 1.36E-05 1.36E-05 3.50E-04 1.05E-07 1.05E-07 TeCDD Total 3.87E-01 3.00E-03 PeCDD Total 2.33E-01 1.80E-03 HxCDD Total 1.96E-01 1.52E-03 HpCDD Total 2.91 E-01 2.26E-03 OCDD 5.04E-01 3.90E-03 TeCDF Total 9.30E+00 7.20E-02 PeCDF Total 1.36E+00 1.06E-02 HxCDF Total 3.08E-01 2.39E-03 HpCDF Total 6.96E-02 5.39E-04 OCDF 5.04E-02 3.90E-04 PCDD Total 1.61 E+00 1.25E-02 PCDF Total 1.11 E+01 8.59E-02 PCDD/PCDF Total 1.27E+01 9.84E-02 PCDD TEQ Total 3.38E-02 3.38E-02 2.62E-04 2.62E-04 PCDF TEQ Total 1.07E-01 1.07E-01 8.26E-04 8.26E-04 PCDD/PCDF TEQ Total 1.40E-01 1.40E-01 1.09E-03 1.09E-03 Sample ID PS-100NEW-072915-01 Page 2 (2) EF EF EF EF EF EF Total TEQ TEQ Total TEQ TEQ 19-B ------- Isomer. ng/g Carbon ng/kg fuel ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 1.53E-04 1.53E-04 1.53E-04 7.08E-02 7.08E-02 7.08E-02 1,2,3,7,8- PeCDD 2.31 E-04 2.31 E-04 2.31 E-04 1.07E-01 1.07E-01 1.07E-01 1,2,3,4,7,8- HxCDD 1.05E-04 1.05E-05 1.05E-05 4.85E-02 4.85E-03 4.85E-03 1,2,3,6,7,8- HxCDD 2.02E-04 2.02E-05 2.02E-05 9.32E-02 9.32E-03 9.32E-03 1,2,3,7,8,9- HxCDD 1.45E-04 1.45E-05 1.45E-05 6.71 E-02 6.71 E-03 6.71 E-03 1,2,3,4,6,7,8- HpCDD 2.26E-03 2.26E-05 2.26E-05 1.04E+00 1.04E-02 1.04E-02 1,2,3,4,6,7,8,9 - OCDD 6.78E-03 2.03E-06 2.03E-06 3.13E+00 9.39E-04 9.39E-04 2,3,7,8 - TCDF 6.95E-03 6.95E-04 6.95E-04 3.21 E+00 3.21 E-01 3.21 E-01 1,2,3,7,8- PeCDF 1.74E-03 5.22E-05 5.22E-05 8.04E-01 2.41 E-02 2.41 E-02 2,3,4,7,8- PeCDF 1.64E-03 4.93E-04 4.93E-04 7.59E-01 2.28E-01 2.28E-01 1,2,3,4,7,8- HxCDF 5.76E-04 5.76E-05 5.76E-05 2.66E-01 2.66E-02 2.66E-02 1,2,3,6,7,8- HxCDF 4.87E-04 4.87E-05 4.87E-05 2.25E-01 2.25E-02 2.25E-02 1,2,3,7,8,9- HxCDF 2.45E-04 2.45E-05 2.45E-05 1.13E-01 1.13E-02 1.13E-02 2,3,4,6,7,8 - HxCDF 5.33E-04 5.33E-05 5.33E-05 2.46E-01 2.46E-02 2.46E-02 1,2,3,4,6,7,8- HpCDF 7.70E-04 7.70E-06 7.70E-06 3.55E-01 3.55E-03 3.55E-03 1,2,3,4,7,8,9- HpCDF 1.67E-04 1.67E-06 1.67E-06 7.71 E-02 7.71 E-04 7.71 E-04 1,2,3,4,6,7,8,9-OCDF 6.08E-04 1.82E-07 1.82E-07 2.81 E-01 8.43E-05 8.43E-05 TeCDD Total 5.21 E-03 2.41 E+00 PeCDD Total 3.14E-03 1.45E+00 HxCDD Total 2.64E-03 1.22E+00 HpCDD Total 3.92E-03 1.81 E+00 OCDD 6.78E-03 3.13E+00 TeCDF Total 1.25E-01 5.78E+01 PeCDF Total 1.83E-02 8.47E+00 HxCDF Total 4.15E-03 1.91 E+00 HpCDF Total 9.37E-04 4.33E-01 OCDF 6.78E-04 3.13E-01 PCDD Total 2.17E-02 1.00E+01 PCDF Total 1.49E-01 6.89E+01 PCDD/PCDF Total 1.71 E-01 7.89E+01 PCDD TEQ Total 4.55E-04 4.55E-04 2.10E-01 2.10E-01 PCDF TEQ Total 1.43E-03 1.43E-03 6.62E-01 6.62E-01 PCDD/PCDF TEQ Total 1.89E-03 1.89E-03 8.72E-01 8.72E-01 Table B-ll. PCDD/PCDF data for 100 % NEW 02. Page 1 (2) Sample ID PS-100NEW2-073115-01 MCE 0.953685 Sampling volume (m3) 116.8 Carbon sampled (g) 63.5 Carbon sampled (mg/m3) 543.6 20-B ------- Carbon fraction 0.5 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 1.44E-02 1.44E-02 1.44E-02 1.23E-04 1.23E-04 1.23E-04 1,2,3,7,8- PeCDD 1.44E-02 1.44E-02 1.44E-02 1.23E-04 1.23E-04 1.23E-04 1,2,3,4,7,8- HxCDD 3.40E-03 3.40E-04 3.40E-04 2.91 E-05 2.91 E-06 2.91 E-06 1,2,3,6,7,8- HxCDD 1.08E-02 1.08E-03 1.08E-03 9.25E-05 9.25E-06 9.25E-06 1,2,3,7,8,9- HxCDD 9.00E-03 9.00E-04 9.00E-04 7.71 E-05 7.71 E-06 7.71 E-06 1,2,3,4,6,7,8- HpCDD 1.24E-01 1.24E-03 1.24E-03 1.06E-03 1.06E-05 1.06E-05 1,2,3,4,6,7,8,9 - OCDD 3.46E-01 1.04E-04 1.04E-04 2.96E-03 8.89E-07 8.89E-07 2,3,7,8 - TCDF 7.90E-01 7.90E-02 7.90E-02 6.76E-03 6.76E-04 6.76E-04 1,2,3,7,8- PeCDF 2.03E-01 6.10E-03 6.10E-03 1.74E-03 5.22E-05 5.22E-05 2,3,4,7,8- PeCDF 1.96E-01 5.89E-02 5.89E-02 1.68E-03 5.04E-04 5.04E-04 1,2,3,4,7,8- HxCDF 5.54E-02 5.54E-03 5.54E-03 4.74E-04 4.74E-05 4.74E-05 1,2,3,6,7,8- HxCDF 4.86E-02 4.86E-03 4.86E-03 4.16E-04 4.16E-05 4.16E-05 1,2,3,7,8,9- HxCDF 2.12E-02 2.12E-03 2.12E-03 1.81E-04 1.81 E-05 1.81 E-05 2,3,4,6,7,8 - HxCDF 3.78E-02 3.78E-03 3.78E-03 3.24E-04 3.24E-05 3.24E-05 1,2,3,4,6,7,8- HpCDF 4.14E-02 4.14E-04 4.14E-04 3.54E-04 3.54E-06 3.54E-06 1,2,3,4,7,8,9- HpCDF 1.04E-02 1.04E-04 1.04E-04 8.90E-05 8.90E-07 8.90E-07 1,2,3,4,6,7,8,9-OCDF 2.60E-02 7.80E-06 7.80E-06 2.23E-04 6.68E-08 6.68E-08 TeCDD Total 2.70E-01 2.31 E-03 PeCDD Total 1.07E-01 9.13E-04 HxCDD Total 1.20E-01 1.03E-03 HpCDD Total 2.16E-01 1.85E-03 OCDD 3.46E-01 2.96E-03 TeCDF Total 1.17E+01 9.98E-02 PeCDF Total 1.92E+00 1.64E-02 HxCDF Total 3.55E-01 3.04E-03 HpCDF Total 7.08E-02 6.06E-04 OCDF 2.60E-02 2.23E-04 PCDD Total 1.06E+00 9.07E-03 PCDF Total 1.40E+01 1.20E-01 PCDD/PCDF Total 1.51 E+01 1.29E-01 PCDD TEQ Total 3.25E-02 3.25E-02 2.78E-04 2.78E-04 PCDF TEQ Total 1.61 E-01 1.61 E-01 1.38E-03 1.38E-03 PCDD/PCDF TEQ Total 1.93E-01 1.93E-01 1.65E-03 1.65E-03 Sample ID PS-100NEW2-073115-01 Page 2 (2) EF EF EF EF EF EF Total TEQ TEQ Total TEQ TEQ 21-B ------- Isomer. ng/g Carbon ng/kg fuel ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 2.27E-04 2.27E-04 2.27E-04 1.05E-01 1.05E-01 1.05E-01 1,2,3,7,8- PeCDD 2.27E-04 2.27E-04 2.27E-04 1.05E-01 1.05E-01 1.05E-01 1,2,3,4,7,8- HxCDD 5.35E-05 5.35E-06 5.35E-06 2.47E-02 2.47E-03 2.47E-03 1,2,3,6,7,8- HxCDD 1.70E-04 1.70E-05 1.70E-05 7.85E-02 7.85E-03 7.85E-03 1,2,3,7,8,9- HxCDD 1.42E-04 1.42E-05 1.42E-05 6.55E-02 6.55E-03 6.55E-03 1,2,3,4,6,7,8- HpCDD 1.96E-03 1.96E-05 1.96E-05 9.03E-01 9.03E-03 9.03E-03 1,2,3,4,6,7,8,9 - OCDD 5.45E-03 1.64E-06 1.64E-06 2.52E+00 7.55E-04 7.55E-04 2,3,7,8 - TCDF 1.24E-02 1.24E-03 1.24E-03 5.74E+00 5.74E-01 5.74E-01 1,2,3,7,8- PeCDF 3.20E-03 9.61 E-05 9.61 E-05 1.48E+00 4.44E-02 4.44E-02 2,3,4,7,8- PeCDF 3.09E-03 9.28E-04 9.28E-04 1.43E+00 4.29E-01 4.29E-01 1,2,3,4,7,8- HxCDF 8.73E-04 8.73E-05 8.73E-05 4.03E-01 4.03E-02 4.03E-02 1,2,3,6,7,8- HxCDF 7.65E-04 7.65E-05 7.65E-05 3.53E-01 3.53E-02 3.53E-02 1,2,3,7,8,9- HxCDF 3.34E-04 3.34E-05 3.34E-05 1.54E-01 1.54E-02 1.54E-02 2,3,4,6,7,8 - HxCDF 5.95E-04 5.95E-05 5.95E-05 2.75E-01 2.75E-02 2.75E-02 1,2,3,4,6,7,8- HpCDF 6.52E-04 6.52E-06 6.52E-06 3.01 E-01 3.01 E-03 3.01 E-03 1,2,3,4,7,8,9- HpCDF 1.64E-04 1.64E-06 1.64E-06 7.56E-02 7.56E-04 7.56E-04 1,2,3,4,6,7,8,9-OCDF 4.09E-04 1.23E-07 1.23E-07 1.89E-01 5.67E-05 5.67E-05 TeCDD Total 4.26E-03 1.97E+00 PeCDD Total 1.68E-03 7.75E-01 HxCDD Total 1.89E-03 8.74E-01 HpCDD Total 3.40E-03 1.57E+00 OCDD 5.45E-03 2.52E+00 TeCDF Total 1.84E-01 8.48E+01 PeCDF Total 3.03E-02 1.40E+01 HxCDF Total 5.58E-03 2.58E+00 HpCDF Total 1.12E-03 5.15E-01 OCDF 4.09E-04 1.89E-01 PCDD Total 1.67E-02 7.70E+00 PCDF Total 2.21 E-01 1.02E+02 PCDD/PCDF Total 2.38E-01 1.10E+02 PCDD TEQ Total 5.11E-04 5.11E-04 2.36E-01 2.36E-01 PCDF TEQ Total 2.53E-03 2.53E-03 1.17E+00 1.17E+00 PCDD/PCDF TEQ Total 3.04E-03 3.04E-03 1.41 E+00 1.41 E+00 Table B-12. PCDD/PCDF data for 100 % NEW 03. Page 1 (2) Sample ID PS-100NEW3-080515-01 MCE 0.936171 Sampling volume (m3) 107.0 Carbon sampled (g) 66.3 Carbon sampled (mg/m3) 619.9 22-B ------- Carbon fraction 0.46 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 3.00E-03 3.00E-03 3.00E-03 2.80E-05 2.80E-05 2.80E-05 1,2,3,7,8- PeCDD 6.80E-03 6.80E-03 6.80E-03 6.35E-05 6.35E-05 6.35E-05 1,2,3,4,7,8- HxCDD 3.80E-03 3.80E-04 3.80E-04 3.55E-05 3.55E-06 3.55E-06 1,2,3,6,7,8- HxCDD 1.00E-02 1.00E-03 1.00E-03 9.34E-05 9.34E-06 9.34E-06 1,2,3,7,8,9- HxCDD 8.20E-03 8.20E-04 8.20E-04 7.66E-05 7.66E-06 7.66E-06 1,2,3,4,6,7,8- HpCDD 1.43E-01 1.43E-03 1.43E-03 1.34E-03 1.34E-05 1.34E-05 1,2,3,4,6,7,8,9 - OCDD 4.40E-01 1.32E-04 1.32E-04 4.11E-03 1.23E-06 1.23E-06 2,3,7,8 - TCDF 1.45E-01 1.45E-02 1.45E-02 1.35E-03 1.35E-04 1.35E-04 1,2,3,7,8- PeCDF 4.88E-02 1.46E-03 1.46E-03 4.56E-04 1.37E-05 1.37E-05 2,3,4,7,8- PeCDF 4.52E-02 1.36E-02 1.36E-02 4.22E-04 1.27E-04 1.27E-04 1,2,3,4,7,8- HxCDF 2.38E-02 2.38E-03 2.38E-03 2.22E-04 2.22E-05 2.22E-05 1,2,3,6,7,8- HxCDF 2.22E-02 2.22E-03 2.22E-03 2.07E-04 2.07E-05 2.07E-05 1,2,3,7,8,9- HxCDF 1.00E-02 1.00E-03 1.00E-03 9.34E-05 9.34E-06 9.34E-06 2,3,4,6,7,8 - HxCDF 1.58E-02 1.58E-03 1.58E-03 1.48E-04 1.48E-05 1.48E-05 1,2,3,4,6,7,8- HpCDF 2.68E-02 2.68E-04 2.68E-04 2.50E-04 2.50E-06 2.50E-06 1,2,3,4,7,8,9- HpCDF 5.60E-03 5.60E-05 5.60E-05 5.23E-05 5.23E-07 5.23E-07 1,2,3,4,6,7,8,9-OCDF 1.86E-02 5.58E-06 5.58E-06 1.74E-04 5.21 E-08 5.21 E-08 TeCDD Total 1.28E-01 1.19E-03 PeCDD Total 7.60E-02 7.10E-04 HxCDD Total 1.10E-01 1.03E-03 HpCDD Total 2.40E-01 2.24E-03 OCDD 4.40E-01 4.11E-03 TeCDF Total 4.96E+00 4.64E-02 PeCDF Total 4.80E-01 4.48E-03 HxCDF Total 1.55E-01 1.45E-03 HpCDF Total 5.44E-02 5.08E-04 OCDF 2.22E-02 2.07E-04 PCDD Total 9.94E-01 9.29E-03 PCDF Total 5.67E+00 5.30E-02 PCDD/PCDF Total 6.67E+00 6.23E-02 PCDD TEQ Total 1.36E-02 1.36E-02 1.27E-04 1.27E-04 PCDF TEQ Total 3.70E-02 3.70E-02 3.46E-04 3.46E-04 PCDD/PCDF TEQ Total 5.06E-02 5.06E-02 4.73E-04 4.73E-04 Page 2 Sample ID PS-100NEW3-080515-01 (2) EF EF EF EF EF EF Total TEQ TEQ Total TEQ TEQ 23-B ------- Isomer. ng/g Carbon ND = 0 ND = LOD ng/kg fuel ND = 0 ND = LOD 2,3,7,8 - TCDD 4.52E-05 4.52E-05 4.52E-05 2.09E-02 2.09E-02 2.09E-02 1,2,3,7,8- PeCDD 1.02E-04 1.02E-04 1.02E-04 4.73E-02 4.73E-02 4.73E-02 1,2,3,4,7,8- HxCDD 5.73E-05 5.73E-06 5.73E-06 2.64E-02 2.64E-03 2.64E-03 1,2,3,6,7,8- HxCDD 1.51E-04 1.51E-05 1.51 E-05 6.96E-02 6.96E-03 6.96E-03 1,2,3,7,8,9- HxCDD 1.24E-04 1.24E-05 1.24E-05 5.71 E-02 5.71 E-03 5.71 E-03 1,2,3,4,6,7,8- HpCDD 2.16E-03 2.16E-05 2.16E-05 9.97E-01 9.97E-03 9.97E-03 1,2,3,4,6,7,8,9 - OCDD 6.63E-03 1.99E-06 1.99E-06 3.06E+00 9.19E-04 9.19E-04 2,3,7,8 - TCDF 2.18E-03 2.18E-04 2.18E-04 1.01 E+00 1.01 E-01 1.01 E-01 1,2,3,7,8- PeCDF 7.36E-04 2.21 E-05 2.21 E-05 3.40E-01 1.02E-02 1.02E-02 2,3,4,7,8- PeCDF 6.81 E-04 2.04E-04 2.04E-04 3.15E-01 9.44E-02 9.44E-02 1,2,3,4,7,8- HxCDF 3.59E-04 3.59E-05 3.59E-05 1.66E-01 1.66E-02 1.66E-02 1,2,3,6,7,8- HxCDF 3.35E-04 3.35E-05 3.35E-05 1.55E-01 1.55E-02 1.55E-02 1,2,3,7,8,9- HxCDF 1.51 E-04 1.51 E-05 1.51 E-05 6.96E-02 6.96E-03 6.96E-03 2,3,4,6,7,8 - HxCDF 2.38E-04 2.38E-05 2.38E-05 1.10E-01 1.10E-02 1.10E-02 1,2,3,4,6,7,8- HpCDF 4.04E-04 4.04E-06 4.04E-06 1.87E-01 1.87E-03 1.87E-03 1,2,3,4,7,8,9- HpCDF 8.44E-05 8.44E-07 8.44E-07 3.90E-02 3.90E-04 3.90E-04 1,2,3,4,6,7,8,9-OCDF 2.80E-04 8.41 E-08 8.41 E-08 1.29E-01 3.88E-05 3.88E-05 TeCDD Total 1.92E-03 8.88E-01 PeCDD Total 1.15E-03 5.29E-01 HxCDD Total 1.66E-03 7.67E-01 HpCDD Total 3.62E-03 1.67E+00 OCDD 6.63E-03 3.06E+00 TeCDF Total 7.48E-02 3.45E+01 PeCDF Total 7.23E-03 3.34E+00 HxCDF Total 2.34E-03 1.08E+00 HpCDF Total 8.20E-04 3.79E-01 OCDF 3.35E-04 1.55E-01 PCDD Total 1.50E-02 6.92E+00 PCDF Total 8.55E-02 3.95E+01 PCDD/PCDF Total 1.01 E-01 4.64E+01 PCDD TEQ Total 2.04E-04 2.04E-04 9.44E-02 9.44E-02 PCDF TEQ Total 5.58E-04 5.58E-04 2.58E-01 2.58E-01 PCDD/PCDF TEQ Total 7.62E-04 7.62E-04 3.52E-01 3.52E-01 990 Table B-13. PCDD/PCDF data for Baseline CB/CL 05. Sample ID PS-CB-080315-01 MCE 0.949349 Page 1 (2) Sampling volume (m3) 69.2 Carbon sampled (g) 70.7 24-B ------- Carbon sampled (mg/m3) 1021.1 Carbon fraction 0.46245 TEQ TEQ Total TEQ TEQ Isomer. Total LOD ng/sample ng/sample ng/m3 ng/m3 ng/m3 ng/sample ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 8.00E-04 8.00E-04 8.00E-04 1.16E-05 1.16E-05 1.16E-05 1,2,3,7,8- PeCDD 2.60E-03 2.60E-03 2.60E-03 3.75E-05 3.75E-05 3.75E-05 1,2,3,4,7,8- HxCDD 1.60E-03 1.60E-04 1.60E-04 2.31 E-05 2.31 E-06 2.31 E-06 1,2,3,6,7,8- HxCDD 2.80E-03 2.80E-04 2.80E-04 4.04E-05 4.04E-06 4.04E-06 1,2,3,7,8,9- HxCDD 2.80E-03 2.80E-04 2.80E-04 4.04E-05 4.04E-06 4.04E-06 1,2,3,4,6,7,8- HpCDD 3.68E-02 3.68E-04 3.68E-04 5.31 E-04 5.31 E-06 5.31 E-06 1,2,3,4,6,7,8,9 - OCDD 1.05E-01 3.14E-05 3.14E-05 1.51E-03 4.53E-07 4.53E-07 2,3,7,8 - TCDF 3.10E-02 3.10E-03 3.10E-03 4.48E-04 4.48E-05 4.48E-05 1,2,3,7,8- PeCDF 8.00E-03 2.40E-04 2.40E-04 1.16E-04 3.47E-06 3.47E-06 2,3,4,7,8- PeCDF 6.40E-03 1.92E-03 1.92E-03 9.24E-05 2.77E-05 2.77E-05 1,2,3,4,7,8- HxCDF 4.60E-03 4.60E-04 4.60E-04 6.64E-05 6.64E-06 6.64E-06 1,2,3,6,7,8- HxCDF 4.40E-03 4.40E-04 4.40E-04 6.35E-05 6.35E-06 6.35E-06 1,2,3,7,8,9- HxCDF 2.80E-03 2.80E-04 2.80E-04 4.04E-05 4.04E-06 4.04E-06 2,3,4,6,7,8 - HxCDF 5.60E-03 5.60E-04 5.60E-04 8.09E-05 8.09E-06 8.09E-06 1,2,3,4,6,7,8- HpCDF 1.30E-02 1.30E-04 1.30E-04 1.88E-04 1.88E-06 1.88E-06 1,2,3,4,7,8,9- HpCDF 2.80E-03 2.80E-05 2.80E-05 4.04E-05 4.04E-07 4.04E-07 1,2,3,4,6,7,8,9-OCDF ND 7.70E-03 0.00E+00 2.31 E-06 ND 0.00E+00 3.34E-08 TeCDD Total 7.34E-02 1.06E-03 PeCDD Total 2.66E-02 3.84E-04 HxCDD Total 4.44E-02 6.41 E-04 HpCDD Total 7.04E-02 1.02E-03 OCDD 1.05E-01 1.51 E-03 TeCDF Total 3.90E-01 5.63E-03 PeCDF Total 5.20E-02 7.51 E-04 HxCDF Total 3.96E-02 5.72E-04 HpCDF Total 2.24E-02 3.23E-04 OCDF ND ND PCDD Total 3.19E-01 4.61 E-03 PCDF Total 5.04E-01 7.28E-03 PCDD/PCDF Total 8.24E-01 1.19E-02 PCDD TEQ Total 4.52E-03 4.52E-03 6.53E-05 6.53E-05 PCDF TEQ Total 7.16E-03 7.16E-03 1.03E-04 1.03E-04 PCDD/PCDF TEQ Total 1.17E-02 1.17E-02 1.69E-04 1.69E-04 Sample ID PS-CB-080315-01 Page 2 (2) EF EF EF EF EF EF Total TEQ TEQ Total TEQ TEQ 25-B ------- Isomer. ng/g Carbon ng/kg fuel ND = 0 ND = LOD ND = 0 ND = LOD 2,3,7,8 - TCDD 1.13E-05 1.13E-05 1.13E-05 5.23E-03 5.23E-03 5.23E-03 1,2,3,7,8- PeCDD 3.68E-05 3.68E-05 3.68E-05 1.70E-02 1.70E-02 1.70E-02 1,2,3,4,7,8- HxCDD 2.26E-05 2.26E-06 2.26E-06 1.05E-02 1.05E-03 1.05E-03 1,2,3,6,7,8- HxCDD 3.96E-05 3.96E-06 3.96E-06 1.83E-02 1.83E-03 1.83E-03 1,2,3,7,8,9- HxCDD 3.96E-05 3.96E-06 3.96E-06 1.83E-02 1.83E-03 1.83E-03 1,2,3,4,6,7,8- HpCDD 5.20E-04 5.20E-06 5.20E-06 2.41 E-01 2.41 E-03 2.41 E-03 1,2,3,4,6,7,8,9 - OCDD 1.48E-03 4.44E-07 4.44E-07 6.84E-01 2.05E-04 2.05E-04 2,3,7,8 - TCDF 4.38E-04 4.38E-05 4.38E-05 2.03E-01 2.03E-02 2.03E-02 1,2,3,7,8- PeCDF 1.13E-04 3.39E-06 3.39E-06 5.23E-02 1.57E-03 1.57E-03 2,3,4,7,8- PeCDF 9.05E-05 2.72E-05 2.72E-05 4.19E-02 1.26E-02 1.26E-02 1,2,3,4,7,8- HxCDF 6.51 E-05 6.51 E-06 6.51 E-06 3.01 E-02 3.01 E-03 3.01 E-03 1,2,3,6,7,8- HxCDF 6.22E-05 6.22E-06 6.22E-06 2.88E-02 2.88E-03 2.88E-03 1,2,3,7,8,9- HxCDF 3.96E-05 3.96E-06 3.96E-06 1.83E-02 1.83E-03 1.83E-03 2,3,4,6,7,8 - HxCDF 7.92E-05 7.92E-06 7.92E-06 3.66E-02 3.66E-03 3.66E-03 1,2,3,4,6,7,8- HpCDF 1.84E-04 1.84E-06 1.84E-06 8.50E-02 8.50E-04 8.50E-04 1,2,3,4,7,8,9- HpCDF 3.96E-05 3.96E-07 3.96E-07 1.83E-02 1.83E-04 1.83E-04 1,2,3,4,6,7,8,9-OCDF ND 0.00E+00 3.27E-08 ND 0.00E+00 1.51 E-05 TeCDD Total 1.04E-03 4.80E-01 PeCDD Total 3.76E-04 1.74E-01 HxCDD Total 6.28E-04 2.90E-01 HpCDD Total 9.96E-04 4.60E-01 OCDD 1.48E-03 6.84E-01 TeCDF Total 5.52E-03 2.55E+00 PeCDF Total 7.35E-04 3.40E-01 HxCDF Total 5.60E-04 2.59E-01 HpCDF Total 3.17E-04 1.46E-01 OCDF ND ND PCDD Total 4.52E-03 2.09E+00 PCDF Total 7.13E-03 3.30E+00 PCDD/PCDF Total 1.16E-02 5.39E+00 PCDD TEQ Total 6.39E-05 6.39E-05 2.96E-02 2.96E-02 PCDF TEQ Total 1.01 E-04 1.01 E-04 4.68E-02 4.68E-02 PCDD/PCDF TEQ Total 1.65E-04 1.65E-04 7.64E-02 7.64E-02 995 Table B-14. PAH emission factors for 0 % NEW and 32 % NEW. 0% 0% 0% 32 % 32 % 32 % NEW NEW NEW NEW NEW NEW Compound mg/kg MRE mg/kg MRE Naphthalene 30.7 61.6 45.4 47.9 30.6 40.5 Acenaphthylene 8.4 19.2 17.0 14.3 10.3 11.2 26-B ------- Acenaphthene(CCC) 0.41 0.90 0.76 0.70 0.43 0.61 Fluorene 2.34 5.78 5.33 3.52 2.63 3.35 Phenanthrene 8.07 21.6 17.9 12.4 8.89 12.12 Anthracene 1.37 3.22 3.03 2.23 1.53 2.16 Fluoranthene(CCC) 1.63 4.43 3.61 2.82 2.13 2.25 Pyrene 1.09 2.93 2.57 2.34 1.59 1.78 Benzo(a)anthracene 0.55 1.81 1.42 0.97 0.60 0.90 Chrysene 0.66 2.22 1.63 1.15 0.75 1.08 Benzo(b)fluoranthene 0.38 1.19 1.15 0.70 0.43 0.57 Benzo(k)fluoranthene 0.31 1.22 0.95 0.66 0.48 0.66 Benzo(a)pyrene(CCC) 0.30 1.15 0.91 0.69 0.41 0.58 lndeno(1,2,3-cd)pyrene 0.23 0.80 0.67 0.44 0.26 0.38 Dibenz(a,h)anthracene 0.09 0.30 0.24 0.13 0.08 0.14 Benzo(ghi)perylene 0.23 0.70 0.59 0.47 0.26 0.39 SUM 16-EPA PAH 57 129 103 91 61 79 Table B-15. PAH emission factors for 66 % NEW, 100 % NEW and baseline (CB/CL 05). 66 % 66 % 66 % 100 % 100 % 100 % CB/CL NEW NEW NEW NEW NEW NEW 05 Compound mg/kg MRE mg/kg MRE Naphthalene 30.5 34.3 27.6 47.7 36.8 109.1 40.9 Acenaphthylene 11.7 12.1 9.63 14.3 12.2 30.1 14.5 Acenaphthene(CCC) 0.58 0.56 0.56 0.60 0.48 1.53 0.52 Fluorene 3.25 3.03 4.29 3.10 3.41 7.75 2.56 Phenanthrene 12.0 11.6 17.5 12.1 12.1 24.8 9.54 Anthracene 2.16 2.07 2.73 2.14 1.99 4.68 1.98 Fluoranthene(CCC) 2.95 2.90 2.90 2.80 2.89 5.32 3.37 Pyrene 2.17 2.17 1.86 2.33 2.02 4.41 2.97 Benzo(a)anthracene 1.11 1.07 1.10 0.99 0.92 2.15 0.88 Chrysene 1.35 1.39 1.39 1.13 1.07 2.41 0.90 Benzo(b)fluoranthene 0.75 0.77 0.78 0.54 0.65 1.38 0.46 Benzo(k)fluoranthene 0.75 0.81 0.61 0.71 0.65 1.31 0.61 Benzo(a)pyrene(CCC) 0.69 0.70 0.56 0.71 0.50 1.35 0.70 lndeno(1,2,3-cd)pyrene 0.47 0.47 0.35 0.47 0.41 0.90 0.43 Dibenz(a,h)anthracene 0.14 0.14 0.13 0.15 0.12 0.31 0.09 Benzo(ghi)perylene 0.45 0.42 0.25 0.50 0.36 0.88 0.56 SUM 16-EPA PAH 71 75 72 90 77 198 81 Table B-16. PAH TEQ emission factors for 0 % NEW and 32 % NEW. 0 % 0 % 32 % 32 % 32 % 0 % NEW NEW NEW NEW NEW NEW Compound mg B[a]P TEQ/kg MRE mg B[a]P TEQ/kg MRE Phenanthrene 4.04E-03 1.08E-02 8.97E-03 6.21 E-03 4.45E-03 6.06E-03 Anthracene 6.83E-04 1.61E-03 1.51 E-03 1.11 E-03 7.65E-04 1.08E-03 Fluoranthene(CCC) 8.15E-02 2.21 E-01 1.81 E-01 1.41 E-01 1.06E-01 1.12E-01 27-B ------- Pyrene 1.09E-03 2.93E-03 2.57E-03 2.34E-03 1.59E-03 1.78E-03 Benzo(a)anthracene 2.74E-03 9.07E-03 7.10E-03 4.87E-03 2.99E-03 4.49E-03 Chrysene 1.99E-02 6.66E-02 4.89E-02 3.46E-02 2.25E-02 3.25E-02 Benzo(b)fluoranthene 3.83E-02 1.19E-01 1.15E-01 7.01 E-02 4.31 E-02 5.71 E-02 Benzo(k)fluoranthene 1.53E-02 6.10E-02 4.75E-02 3.32E-02 2.38E-02 3.28E-02 Benzo(a)pyrene(CCC) 3.05E-01 1.15E+00 9.12E-01 6.86E-01 4.14E-01 5.75E-01 lndeno(1,2,3-cd)pyrene 2.33E-02 8.00E-02 6.67E-02 4.38E-02 2.65E-02 3.75E-02 Dibenz(a,h)anthracene 9.48E-02 3.31 E-01 2.61 E-01 1.38E-01 8.77E-02 1.54E-01 Benzo(ghi)perylene 4.57E-03 1.40E-02 1.17E-02 9.37E-03 5.28E-03 7.78E-03 SUM 16-EPA PAH 5.91 E-01 2.06E+00 1.66E+00 1.17E+00 7.39E-01 1.02E+00 1000 Table B-17. PAH TEQ emission factors for 66 % NEW, 100 % NEW and baseline (CB/CL 05). Compound 66% 66 % NEW 66 % NEW NEW mg B[a]P TEQ/kg MRE 100 % NEW 100 % 100% NEW NEW mg B[a]P TEQ/kg MRE CB/CL 05 Phenanthrene 6.01 E-03 5.82E-03 8.74E-03 6.05E-03 6.07E-03 1.24E-02 4.77E-03 Anthracene 1.08E-03 1.04E-03 1.36E-03 1.07E-03 9.93E-04 2.34E-03 9.92E-04 Fluoranthene(CCC) 1.48E-01 1.45E-01 1.45E-01 1.40E-01 1.45E-01 2.66E-01 1.69E-01 Pyrene 2.17E-03 2.17E-03 1.86E-03 2.33E-03 2.02E-03 4.41 E-03 2.97E-03 Benzo(a)anthracene 5.57E-03 5.34E-03 5.49E-03 4.94E-03 4.62E-03 1.07E-02 4.40E-03 Chrysene 4.05E-02 4.16E-02 4.16E-02 3.40E-02 3.22E-02 7.23E-02 2.69E-02 Benzo(b)fluoranthene 7.51 E-02 770E-02 7.82E-02 5.37E-02 6.52E-02 1.38E-01 4.64E-02 Benzo(k)fluoranthene 3.77E-02 4.05E-02 3.04E-02 3.57E-02 3.24E-02 6.54E-02 3.05E-02 Benzo(a)pyrene(CCC) 6.87E-01 7.01 E-01 5.58E-01 7.11 E-01 5.01 E-01 1.35E+00 6.96E-01 lndeno(1,2,3-cd)pyrene 4.74E-02 4.72E-02 3.48E-02 4.73E-02 4.11 E-02 8.99E-02 4.33E-02 Dibenz(a,h)anthracene 1.58E-01 1.49E-01 1.48E-01 1.62E-01 1.30E-01 3.37E-01 1.00E-01 Benzo(ghi)perylene 9.09E-03 8.35E-03 4.92E-03 9.91 E-03 7.16E-03 1.77E-02 1.13E-02 SUM 16-EPA PAH 1.22E+00 1.22E+00 1.06E+00 1.21 E+00 9.67E-01 2.37E+00 1.14E+00 1005 Table B-18. PIVh.sand PMio emission factors for MRE tests. EF PM2.5 EF PM10 Date Matrix g/kg MRE 7/30/2015 0 % NEW 11.2 13.9 7/30/2015 0 % NEW 6.9 9.8 7/30/2015 0 % NEW 12.3 15.5 7/30/2015 0 % NEW 19.0 15.3 28-B ------- 7/31/2015 0 % NEW 10.1 10.7 7/31/2015 0 % NEW 14.3 16.2 8/3/2015 32 % NEW 10.1 9.9 8/3/2015 32 % NEW 9.4 9.9 8/4/2015 32 % NEW 12.6 12.8 8/4/2015 32 % NEW 9.6 9.8 8/6/2015 32 % NEW 11.6 12.8 8/6/2015 32 % NEW 9.9 10.6 8/12/2015 66 % NEW 8.2 8.0 8/12/2015 66 % NEW 8.6 8.1 8/13/2015 66 % NEW 7.7 8.9 8/13/2015 66 % NEW 14.2 11.0 8/13/2015 66 % NEW 10.5 9.2 8/13/2015 66 % NEW 12.9 11.8 100 % 7/29/2015 NEW 8.7 10.9 100 % 7/29/2015 NEW 13.5 14.1 100 % 7/31/2015 NEW 14.3 13.9 100 % 7/31/2015 NEW 10.1 11.2 100 % 8/5/2015 NEW 12.6 12.8 100 % 8/5/2015 NEW 12.2 12.5 8/3/2015 Baseline 3.0 3.5 8/3/2015 Baseline 3.3 3.4 1010 29-B ------- Table B-19. Metal emission factors for MRE tests analyzed from PM2.5 batch filter.3 Al Si P S CI K Fe Cu Zn Al Unc. Si Unc. P Unc. S Unc. CI Unc. K Unc. Fe Unc. Cu Unc. Zn Unc. Date Test mg/kg MRE 7/30/2015 0 % NEW 3.33 0.32 5.98 0.36 11.14 0.63 29.59 1.61 83.28 4.44 16.79 0.87 0.331 0.037 0.167 0.026 0.832 0.045 7/30/2015 0 % NEW 2.45 0.23 5.03 0.30 9.29 0.52 23.09 1.24 58.57 3.09 17.03 0.88 0.257 0.027 0.130 0.021 0.517 0.030 7/30/2015 0 % NEW 2.98 0.34 4.91 0.31 8.95 0.51 30.89 1.69 94.26 5.05 16.68 0.87 0.353 0.040 0.175 0.031 0.528 0.031 7/30/2015 0 % NEW 3.73 0.39 6.31 0.37 9.90 0.55 25.25 1.34 67.32 3.53 17.07 0.88 0.287 0.051 0.287 0.039 0.719 0.045 7/31/2015 0 % NEW 1.93 0.22 5.02 0.32 7.46 0.44 23.42 1.30 57.01 3.10 19.04 1.00 0.256 0.025 0.129 0.018 1.029 0.053 7/31/2015 0 % NEW 1.78 0.26 5.11 0.40 14.61 1.03 24.45 1.59 44.90 2.54 17.93 0.96 0.237 0.023 0.119 0.016 1.069 0.055 8/3/2015 32 % NEW 2.19 0.22 4.97 0.34 11.68 0.71 25.85 1.48 63.96 3.54 22.33 1.18 0.146 0.017 0.146 0.013 0.731 0.036 8/3/2015 32 % NEW 2.67 0.30 5.54 0.33 10.58 0.59 18.89 1.04 34.81 1.82 18.07 0.92 0.308 0.040 0.205 0.031 0.821 0.045 8/4/2015 32 % NEW 2.34 0.27 4.68 0.35 6.40 0.42 32.32 1.93 82.45 4.75 20.92 1.14 0.469 0.028 0.140 0.013 0.625 0.032 8/4/2015 32 % NEW 1.77 0.20 5.31 0.36 11.25 0.69 21.87 1.26 34.79 1.95 17.08 0.91 0.312 0.021 0.105 0.012 0.834 0.043 8/6/2015 32 % NEW 2.43 0.28 5.20 0.32 10.93 0.62 30.70 1.68 93.13 4.99 18.21 0.95 0.346 0.036 0.173 0.025 0.519 0.029 8/6/2015 32 % NEW 2.24 0.24 7.65 0.47 11.61 0.66 24.01 1.31 42.60 2.29 24.27 1.26 0.265 0.030 0.265 0.024 0.924 0.048 8/12/2015 66 % NEW 3.16 0.31 6.78 0.39 15.37 0.85 16.38 0.89 39.32 2.05 21.13 1.08 0.228 0.040 0.228 0.031 0.565 0.035 8/12/2015 66 % NEW 1.62 0.20 6.14 0.37 5.81 0.33 20.67 1.12 37.55 1.99 15.50 0.80 0.216 0.026 0.216 0.020 1.076 0.055 8/13/2015 66 % NEW 3.50 0.33 12.02 0.74 11.57 0.66 29.07 1.60 45.96 2.47 18.27 0.95 1.370 0.076 0.151 0.025 1.067 0.054 8/13/2015 66 % NEW 3.31 0.30 15.43 0.95 9.51 0.55 27.55 1.52 52.48 2.84 14.33 0.75 0.551 0.036 0.276 0.024 1.378 0.070 8/13/2015 66 % NEW 3.13 0.31 6.43 0.38 12.86 0.71 29.70 1.60 84.93 4.50 20.84 1.08 0.176 0.037 0.347 0.033 0.694 0.037 8/13/2015 66 % NEW 2.16 0.23 7.17 0.46 10.95 0.64 24.20 1.35 65.56 3.57 14.60 0.77 0.542 0.034 0.135 0.018 0.677 0.036 100% 7/29/2015 NEW 2.07 0.20 6.22 0.39 8.49 0.49 23.89 1.32 22.80 1.24 19.14 1.00 0.296 0.023 0.198 0.017 1.185 0.060 100% 7/29/2015 NEW 1.92 0.26 4.72 0.30 11.95 0.70 25.67 1.43 60.17 3.27 25.23 1.32 0.294 0.033 0.147 0.023 1.031 0.053 100% 7/31/2015 NEW 3.12 0.34 6.24 0.39 8.70 0.50 27.10 1.49 82.95 4.44 21.19 1.10 0.330 0.038 0.165 0.030 1.152 0.059 100% 7/31/2015 NEW 2.17 0.23 5.50 0.35 10.28 0.60 25.19 1.40 66.45 3.62 19.40 1.02 0.289 0.026 0.144 0.018 0.868 0.044 100% 8/5/2015 NEW 2.52 0.28 5.71 0.36 10.41 0.60 29.90 1.65 81.82 4.42 19.99 1.05 0.335 0.035 0.335 0.028 0.840 0.045 100% 8/5/2015 NEW 2.27 0.28 5.68 0.35 10.10 0.57 21.33 1.16 48.33 2.58 20.70 1.07 0.253 0.035 0.253 0.027 0.756 0.043 a Unc = Uncertainty. ND = not detected. b Less than three times the uncertainty. 30-B ------- 1015 Continuation of Table B-19 Br Na Ca Ti Cr Mn Br Unc. Na Unc. Mg Na Ca Unc. Ti Unc. V V Unc. Cr Unc. Mn Unc. Date Test mg/kg MRE 7/30/2015 0 % NEW 2.33 0.12 8.79b 3.20 0.33b 0.81 0.525 0.045 0.331 0.030 0.026b 0.018 0.053b 0.030 0.026b 0.026 7/30/2015 0 % NEW 2.19 0.11 3.83b 2.29 0.64b 0.61 0.512 0.036 0.103 0.021 ND 0.015 0.012b 0.024 0.012b 0.021 7/30/2015 0 % NEW 1.76 0.09 7.13b 4.05 0.11b 1.02 ND 0.036 0.018b 0.031 0.031b 0.022 ND 0.036 ND 0.031 7/30/2015 0 % NEW 2.87 0.15 6.58b 3.96 0.72b 1.10 0.218 0.045 0.146 0.039 ND 0.028 0.056b 0.045 0.056b 0.039 7/31/2015 0 % NEW 2.32 0.12 7.11b 2.73 ND 0.63 0.032b 0.020 0.386 0.025 ND 0.013 ND 0.020 0.032b 0.018 7/31/2015 0 % NEW 2.37 0.12 2.10b 3.92 0.36b 0.83 ND 0.018 0.119 0.016 ND 0.011 ND 0.018 0.059 0.016 8/3/2015 32 % NEW 2.34 0.12 6.28b 2.72 0.44b 0.56 ND 0.015 0.437 0.025 ND 0.010 ND 0.015 0.038b 0.013 8/3/2015 32 % NEW 1.95 0.10 6.41b 3.07 ND 0.87 0.008b 0.036 0.080b 0.031 ND 0.022 ND 0.036 ND 0.031 8/4/2015 32 % NEW 2.19 0.11 1.75b 3.35 0.31b 0.67 ND 0.015 0.140 0.015 0.030 0.009 ND 0.015 ND 0.013 8/4/2015 32 % NEW 1.87 0.09 6.12b 2.63 ND 0.53 ND 0.014 0.312 0.019 0.032 0.009 0.022b 0.014 ND 0.012 8/6/2015 32 % NEW 2.08 0.10 6.25b 3.19 ND 0.81 0.476 0.040 0.105 0.025 ND 0.018 0.033b 0.029 0.033b 0.025 8/6/2015 32 % NEW 2.24 0.11 12.25 2.98 0.79b 0.68 0.083 0.024 0.117 0.021 ND 0.015 ND 0.024 0.049b 0.021 8/12/2015 66 % NEW 2.37 0.12 2.46b 2.81 0.34b 0.82 ND 0.035 0.022b 0.031 0.059b 0.022 0.051b 0.035 0.070b 0.031 8/12/2015 66 % NEW 1.29 0.07 12.85 2.68 0.64b 0.62 ND 0.023 0.064 0.020 0.058 0.014 0.058b 0.023 0.015b 0.020 8/13/2015 66 % NEW 2.13 0.11 17.78 3.80 1.52b 0.83 0.175 0.029 0.151 0.025 0.054 0.018 0.529 0.036 0.087 0.025 8/13/2015 66 % NEW 2.34 0.12 4.96b 2.89 0.14b 0.71 0.146 0.024 0.082 0.021 ND 0.015 0.045b 0.024 0.045b 0.021 8/13/2015 66 % NEW 3.13 0.16 5.32b 3.09 0.35b 0.84 0.271 0.037 0.139 0.029 0.054b 0.020 0.067b 0.033 0.013b 0.029 8/13/2015 66 % NEW 2.03 0.10 4.37b 2.75 0.68b 0.66 0.015b 0.021 0.135 0.018 0.015b 0.013 0.127 0.021 ND 0.018 100% 7/29/2015 NEW 1.88 0.09 10.37 2.38 0.20b 0.51 ND 0.017 0.098 0.015 ND 0.011 0.098 0.017 ND 0.015 100% 7/29/2015 NEW 1.92 0.10 9.74b 3.65 ND 0.83 ND 0.027 0.591 0.037 0.011b 0.017 0.036b 0.027 0.011b 0.023 100% 7/31/2015 NEW 2.30 0.12 5.19b 3.80 0.82b 0.97 ND 0.034 0.081b 0.030 0.047b 0.021 ND 0.034 0.015b 0.030 100% 7/31/2015 NEW 2.32 0.12 5.71b 2.70 0.054b 0.64 ND 0.021 0.144 0.018 ND 0.013 0.050b 0.021 0.020b 0.018 100% 8/5/2015 NEW 2.35 0.12 5.73b 3.35 ND 0.83 0.106 0.028 0.167 0.024 ND 0.017 0.053b 0.028 0.022b 0.024 100% 8/5/2015 NEW 1.52 0.08 11.62 3.49 0.74b 0.86 0.090b 0.031 0.253 0.027 0.018b 0.019 ND 0.031 0.018b 0.027 a Unc = Uncertainty. ND = not detected. b Less than three times the uncertainty. 31-B ------- Continuation of Table B-19 Co Ni Ga Ge As Se Rb Sr Co Unc. Ni Unc. Ga Unc. Ge Unc. As Unc. Se Unc. Rb Unc Sr Unc. Date Test 7/30/2015 0 % NEW 0.012b 0.018 ND 0.015 0.012b 0.015 0.012b 0.015 ND 0.018 0.012b 0.011 ND 0.008 ND 0.022 7/30/2015 0 % NEW ND 0.015 ND 0.012 0.012b 0.012 0.026b 0.012 ND 0.015 0.012b 0.009 ND 0.006 ND 0.018 7/30/2015 0 % NEW ND 0.022 ND 0.018 ND 0.018 0.047b 0.018 0.047b 0.022 ND 0.013 0.031b 0.013 0.031b 0.027 7/30/2015 0 % NEW 0.021b 0.028 0.034b 0.022 0.021b 0.022 0.034b 0.022 0.043b 0.028 ND 0.017 ND 0.011 ND 0.034 7/31/2015 0 % NEW ND 0.013 0.010b 0.010 0.010b 0.010 0.010b 0.010 ND 0.013 0.010b 0.008 ND 0.005 ND 0.015 7/31/2015 0 % NEW ND 0.011 ND 0.009 0.011b 0.009 0.011b 0.009 ND 0.011 ND 0.007 ND 0.005 ND 0.014 8/3/2015 32 % NEW ND 0.010 0.013b 0.008 0.013b 0.008 0.013b 0.008 ND 0.010 ND 0.006 ND 0.004 0.025b 0.012 8/3/2015 32 % NEW 0.029b 0.022 0.020b 0.018 0.049b 0.018 ND 0.018 0.029b 0.022 0.008b 0.013 ND 0.009 ND 0.027 8/4/2015 32 % NEW 0.014b 0.009 ND 0.007 ND 0.007 ND 0.007 0.014b 0.009 0.014b 0.006 ND 0.004 0.014b 0.011 8/4/2015 32 % NEW 0.011b 0.009 ND 0.007 0.022 0.007 0.032 0.007 ND 0.009 0.011b 0.005 0.032 0.005 ND 0.011 8/6/2015 32 % NEW 0.016b 0.018 ND 0.014 0.046 0.014 0.046 0.014 0.033b 0.018 0.046 0.011 ND 0.007 0.046b 0.022 8/6/2015 32 % NEW ND 0.015 ND 0.012 0.034b 0.012 0.015b 0.012 0.015b 0.015 0.034 0.009 ND 0.006 0.068 0.021 8/12/2015 66 % NEW ND 0.022 0.031b 0.017 0.019b 0.017 0.012b 0.017 ND 0.022 0.031b 0.013 0.051 0.013 0.012b 0.026 8/12/2015 66 % NEW ND 0.014 0.027b 0.012 ND 0.012 0.058 0.012 ND 0.014 0.069 0.009 0.042 0.009 0.027b 0.018 8/13/2015 66 % NEW ND 0.018 0.158 0.018 ND 0.014 0.033b 0.014 0.033b 0.018 0.017b 0.011 0.087 0.011 0.054b 0.022 8/13/2015 66 % NEW ND 0.015 0.058 0.012 0.029b 0.012 0.029b 0.012 ND 0.015 0.016b 0.009 0.016b 0.009 0.016b 0.018 8/13/2015 66 % NEW ND 0.020 ND 0.016 ND 0.016 0.041b 0.016 ND 0.020 0.013b 0.012 0.041 0.012 ND 0.025 8/13/2015 66 % NEW ND 0.013 0.048 0.010 0.030b 0.010 0.015b 0.010 ND 0.013 ND 0.008 0.078 0.008 0.015b 0.016 100% 7/29/2015 NEW ND 0.011 0.019b 0.008 0.011b 0.008 0.019b 0.008 ND 0.011 0.041 0.006 0.041 0.006 ND 0.013 100% 7/29/2015 NEW 0.025b 0.017 0.011b 0.013 ND 0.013 0.025b 0.013 0.049b 0.017 ND 0.010 0.060 0.010 0.011b 0.020 100% 7/31/2015 NEW ND 0.021 0.031b 0.017 0.031b 0.017 0.047b 0.017 ND 0.021 0.031b 0.013 ND 0.009 0.031b 0.025 100% 7/31/2015 NEW ND 0.013 0.011b 0.010 0.020b 0.010 ND 0.010 0.031b 0.013 ND 0.008 ND 0.005 ND 0.016 100% 8/5/2015 NEW ND 0.017 ND 0.014 ND 0.014 0.022b 0.014 ND 0.017 0.022b 0.010 ND 0.007 ND 0.021 100% 8/5/2015 NEW ND 0.019 0.018b 0.016 ND 0.016 0.008b 0.016 0.022b 0.019 0.004b 0.012 0.018b 0.012 0.004b 0.023 a Unc = Uncertainty. ND = not detected. b less than three times the uncertainty. 32-B ------- Continuation of Table B-19 Zr Mo Pd Ag Cd In Sn Sb Zr Unc. Mo Unc. Pd Unc. Ag Unc. Cd Unc. In Unc. Sn Unc. Sb Unc. Date Test mg/kg MRE 7/30/2015 0 % NEW ND 0.045 ND 0.078 ND 0.078 0.117b 0.078 0.132b 0.078 0.261b 0.119 ND 0.137 ND 0.241 7/30/2015 0 % NEW ND 0.036 0.026b 0.062 0.026b 0.062 ND 0.062 0.129b 0.062 ND 0.095 0.184b 0.115 ND 0.192 7/30/2015 0 % NEW 0.063b 0.054 0.153b 0.094 0.063b 0.094 0.016b 0.094 0.066b 0.094 0.309b 0.143 0.309b 0.165 0.614b 0.295 7/30/2015 0 % NEW ND 0.068 0.056b 0.118 ND 0.118 ND 0.118 0.043b 0.163 0.218b 0.180 ND 0.208 ND 0.365 7/31/2015 0 % NEW 0.042b 0.031 ND 0.053 0.063b 0.053 0.021b 0.053 0.107b 0.053 0.107b 0.081 0.095b 0.099 0.190b 0.173 7/31/2015 0 % NEW 0.070b 0.027 ND 0.048 0.118b 0.048 0.036b 0.048 0.059b 0.048 0.107b 0.073 0.237b 0.084 0.130b 0.151 8/3/2015 32 % NEW ND 0.023 ND 0.040 ND 0.040 ND 0.040 ND 0.056 ND 0.061 0.094b 0.071 0.259b 0.138 8/3/2015 32 % NEW 0.029b 0.054 ND 0.094 ND 0.094 0.057b 0.094 0.029b 0.094 ND 0.143 0.078b 0.165 ND 0.290 8/4/2015 32 % NEW ND 0.022 ND 0.039 0.074b 0.039 ND 0.039 ND 0.054 ND 0.060 0.012b 0.071 0.464 0.125 8/4/2015 32 % NEW 0.032b 0.021 ND 0.037 ND 0.037 ND 0.037 ND 0.051 ND 0.057 ND 0.066 0.288b 0.121 8/6/2015 32 % NEW ND 0.043 ND 0.076 ND 0.076 ND 0.076 0.159b 0.105 ND 0.116 0.235b 0.133 0.331b 0.238 8/6/2015 32 % NEW 0.165b 0.036 ND 0.063 0.034b 0.063 ND 0.063 ND 0.087 ND 0.096 ND 0.111 0.658 0.199 8/12/2015 66 % NEW ND 0.053 ND 0.092 0.101b 0.092 ND 0.092 ND 0.127 0.202b 0.140 ND 0.162 0.202b 0.285 8/12/2015 66 % NEW 0.042b 0.035 ND 0.061 ND 0.061 0.058b 0.061 ND 0.085 ND 0.093 0.427 0.108 1.767 0.195 8/13/2015 66 % NEW ND 0.043 ND 0.076 ND 0.076 ND 0.076 0.175b 0.105 0.158b 0.115 ND 0.133 1.394 0.241 8/13/2015 66 % NEW ND 0.036 ND 0.064 0.016b 0.064 ND 0.064 ND 0.064 ND 0.097 0.380 0.121 1.035 0.200 8/13/2015 66 % NEW ND 0.049 ND 0.086 0.067b 0.086 0.041b 0.086 0.108b 0.118 ND 0.131 1.899 0.192 0.542b 0.269 8/13/2015 66 % NEW ND 0.031 0.093b 0.055 ND 0.055 0.030b 0.055 ND 0.076 ND 0.083 ND 0.096 1.019 0.177 100% 7/29/2015 NEW ND 0.026 ND 0.045 ND 0.045 0.019b 0.045 ND 0.062 ND 0.068 0.045b 0.083 0.918 0.143 100% 7/29/2015 NEW ND 0.040 ND 0.070 ND 0.070 ND 0.070 ND 0.097 ND 0.107 0.172b 0.123 ND 0.217 100% 7/31/2015 NEW ND 0.051 0.151b 0.089 0.015b 0.089 ND 0.089 ND 0.123 0.151b 0.136 0.104b 0.157 0.743 0.229 100% 7/31/2015 NEW 0.020b 0.031 ND 0.054 0.020b 0.054 ND 0.054 ND 0.075 0.040b 0.083 ND 0.095 0.733 0.201 100% 8/5/2015 NEW 0.022b 0.042 ND 0.073 0.086b 0.073 0.106b 0.073 0.106b 0.101 ND 0.112 ND 0.129 0.516b 0.230 8/5/2015 100% NEW 0.014b 0.047 ND 0.082 ND 0.082 0.018b 0.082 ND 0.113 ND 0.125 ND 0.144 0.199b 0.257 1020 a Unc = Uncertainty. ND = not detected. b lessL than three times the uncertainty. 33-B ------- Continuation of Table B-19 Ba La Hg Pb Ba Unc. La Unc. Hg Unc. Pb Unc. Y YUnc. Date Test mg/kg MRE 7/30/2015 0 % NEW ND 0.108 ND 0.056 0.091 0.022 0.065 0.015 0.026b 0.034 7/30/2015 0 % NEW ND 0.086 ND 0.044 0.012b 0.018 0.076 0.012 ND 0.027 7/30/2015 0 % NEW 0.461 0.134 0.137b 0.072 0.031b 0.027 0.078 0.018 ND 0.040 7/30/2015 0 % NEW ND 0.163 ND 0.085 ND 0.034 0.086 0.022 ND 0.051 7/31/2015 0 % NEW ND 0.074 ND 0.038 0.032b 0.015 0.053 0.010 0.010b 0.023 7/31/2015 0 % NEW ND 0.066 ND 0.034 ND 0.014 0.070 0.009 0.011b 0.021 8/3/2015 32 % NEW ND 0.056 ND 0.029 ND 0.012 ND 0.008 0.013b 0.017 8/3/2015 32 % NEW ND 0.130 ND 0.067 ND 0.027 0.037b 0.018 ND 0.040 8/4/2015 32 % NEW ND 0.054 0.030b 0.028 ND 0.011 ND 0.007 ND 0.017 8/4/2015 32 % NEW ND 0.051 ND 0.027 ND 0.011 0.063 0.007 ND 0.016 8/6/2015 32 % NEW ND 0.105 0.079b 0.058 0.096b 0.022 ND 0.014 ND 0.033 8/6/2015 32 % NEW ND 0.087 ND 0.045 0.015b 0.018 0.034b 0.012 0.034b 0.027 8/12/2015 66 % NEW ND 0.127 ND 0.066 ND 0.026 0.101 0.017 ND 0.040 8/12/2015 66 % NEW ND 0.085 0.115b 0.047 0.015b 0.018 0.100 0.012 ND 0.026 8/13/2015 66 % NEW ND 0.105 0.071b 0.054 ND 0.022 0.104 0.014 ND 0.033 8/13/2015 66 % NEW ND 0.088 ND 0.046 0.016b 0.018 0.117 0.012 ND 0.027 8/13/2015 66 % NEW ND 0.118 0.108b 0.065 ND 0.025 0.029b 0.016 ND 0.037 8/13/2015 66 % NEW ND 0.076 ND 0.039 ND 0.016 0.063 0.010 ND 0.024 100% 7/29/2015 NEW ND 0.062 ND 0.032 ND 0.013 0.041 0.008 ND 0.019 100% 7/29/2015 NEW ND 0.097 ND 0.050 ND 0.020 ND 0.013 0.011b 0.030 100% 7/31/2015 NEW ND 0.123 0.031b 0.064 ND 0.025 0.120 0.017 0.047b 0.038 100% 7/31/2015 NEW ND 0.075 0.011b 0.039 ND 0.016 0.020b 0.010 ND 0.023 100% 8/5/2015 NEW ND 0.101 0.031b 0.052 ND 0.021 0.042 0.014 ND 0.031 100% 8/5/2015 NEW ND 0.113 ND 0.059 ND 0.023 ND 0.016 0.014b 0.035 a Unc = Uncertainty. ND = not detected. bLess than three times the uncertainty. 34-B ------- Table B-20. VOC emission factor from open burning of 100 % NEW composite MRE material. 1 100 % NEW 2 3 EF Method Detection Limit EF Method Detection Limit EF Method Detection Limit Compound mg/kg MRE Propene 222.76 0.40 266.94 1.08 368.20 0.83 Dichlorodifluoromethane (CFC-12) 0.07 0.48 ND 0.13 ND 0.10 Chloromethane 3.56 0.44 2.87 0.12 2.79 0.09 1,2-Dichloro-1,1,2,2- tetrafluoroethane (CFC-114) ND 0.55 ND 0.15 ND 0.11 Vinyl Chloride ND 0.48 0.53 0.13 0.52 0.10 1,3-Butadiene 88.00 0.62 42.25 0.17 150.85 1.31 Bromomethane ND 0.55 0.48 0.15 0.29 0.11 Chloroethane ND 0.48 0.26 0.13 0.31 0.10 Ethanol 4.40 2.31 ND 0.63 5.95 0.48 Acetonitrile 11.60 0.51 11.78 0.14 14.94 0.11 Acrolein 95.11 0.48 136.69 1.31 146.64 0.99 Acetone ND 2.24 ND 0.63 114.73 0.44 Trichlorofluoromethane ND 0.48 ND 0.13 ND 0.10 2-Propanol (Isopropyl Alcohol) 1.98 1.21 ND 0.33 ND 0.25 Acrylonitrile 6.97 0.48 8.56 0.13 9.53 0.10 1,1-Dichloroethene ND 0.48 ND 0.13 ND 0.10 Methylene Chloride 31.72 0.48 2.97 0.13 ND 0.10 3-Chloro-1 -propene (Allyl Chloride) ND 0.48 ND 0.13 ND 0.10 Trichlorotrifluoroethane ND 0.48 ND 0.13 ND 0.10 Carbon Disulfide ND 0.44 ND 0.12 ND 0.09 trans-1,2-Dichloroethene ND 0.55 0.20 0.15 ND 0.11 1,1-Dichloroethane ND 0.48 ND 0.13 ND 0.10 Methyl tert-Butyl Ether ND 0.48 ND 0.13 ND 0.10 Vinyl Acetate 77.00 1.87 125.62 0.51 123.07 0.39 2-Butanone (MEK) 15.14 0.62 27.58 0.17 29.50 0.12 cis-1,2-Dichloroethene ND 0.48 0.31 0.13 ND 0.10 Ethyl Acetate 9.53 1.03 ND 0.27 ND 0.21 n-Hexane 6.70 0.44 9.30 0.12 15.59 0.09 Chloroform ND 0.48 0.29 0.13 ND 0.10 Tetrahydrofuran (THF) 1.69 0.59 2.97 0.15 3.22 0.12 1,2-Dichloroethane ND 0.48 ND 0.13 ND 0.10 1,1,1-Trichloroethane ND 0.48 ND 0.13 ND 0.10 Benzene 197.88 0.48 211.07 1.26 265.84 0.95 Carbon Tetrachloride ND 0.44 0.03 0.12 0.01 0.09 Cyclohexane ND 0.84 ND 0.23 0.48 0.17 1,2-Dichloropropane ND 0.48 0.21 0.13 ND 0.10 35-B ------- Bromodichloromethane ND 0.44 ND 0.12 ND 0.09 Trichloroethene ND 0.40 ND 0.11 ND 0.08 1,4-Dioxane ND 0.48 ND 0.13 ND 0.10 Methyl Methacrylate ND 0.88 ND 0.24 ND 0.18 n-Heptane 8.07 0.48 8.56 0.13 13.89 0.10 cis-1,3-Dichloropropene ND 0.40 ND 0.11 ND 0.08 4-Methyl-2-pentanone 0.88 0.48 1.20 0.13 1.95 0.10 trans-1,3-Dichloropropene ND 0.48 ND 0.13 ND 0.10 1,1,2-Trichloroethane ND 0.48 ND 0.13 ND 0.10 Toluene 76.85 0.48 41.45 0.13 55.42 0.10 2-Hexanone 4.40 0.48 5.02 0.13 6.35 0.10 Dibromochloromethane ND 0.48 ND 0.13 ND 0.10 1,2-Dibromoethane ND 0.48 ND 0.13 ND 0.10 n-Butyl Acetate ND 0.48 ND 0.13 ND 0.10 n-Octane 5.50 0.51 6.85 0.14 10.72 0.11 Tetrachloroethene ND 0.40 ND 0.11 ND 0.08 Chlorobenzene ND 0.48 0.23 0.13 0.13 0.10 Ethyl benzene 20.53 0.48 8.56 0.13 14.69 0.10 m-,p-Xylenes 5.50 0.88 4.45 0.23 7.15 0.18 Bromoform ND 0.44 ND 0.12 ND 0.09 Styrene 194.34 0.44 37.69 0.12 127.04 0.87 o-Xylene 3.08 0.44 2.34 0.12 3.77 0.09 n-Nonane 4.03 0.44 5.60 0.12 8.73 0.09 1,1,2,2-Tetrachloroethane ND 0.44 ND 0.12 ND 0.09 Cumene 1.10 0.44 0.46 0.12 0.91 0.09 alpha-Pinene 0.55 0.40 ND 0.11 0.87 0.08 n-Propylbenzene 1.72 0.48 1.03 0.13 1.71 0.10 4-Ethyltoluene 0.62 0.48 0.57 0.13 0.91 0.10 1,3,5-Trimethyl benzene ND 0.48 0.33 0.13 0.67 0.10 1,2,4-Trimethyl benzene 0.70 0.44 0.69 0.12 1.79 0.09 Benzyl Chloride ND 0.32 0.18 0.09 ND 0.06 1,3-Dichlorobenzene ND 0.44 ND 0.12 ND 0.09 1,4-Dichlorobenzene ND 0.40 ND 0.11 ND 0.08 1,2-Dichlorobenzene ND 0.44 ND 0.12 ND 0.09 d-Limonene 0.77 0.40 0.86 0.11 1.19 0.08 1,2-Dibromo-3-chloropropane ND 0.29 ND 0.08 ND 0.06 1,2,4-Trichlorobenzene ND 0.48 ND 0.13 ND 0.10 Naphthalene 44.00 0.51 34.26 0.14 35.33 0.11 Hexachlorobutadiene ND 0.40 ND 0.11 ND 0.08 g/kg MRE g/kg MRE g/kg MRE Carbon Monoxide 19.78 21.62 23.69 Methane 0.89 0.52 0.83 36-B ------- Carbon Dioxide 1659.67 1657.77 1653.67 MCE ratio 0.980 0.979 0.977 1025 37-B ------- Table B-21. VOC emission factor from open burning of 66 % NEW composite MRE material. 66 % NEW 1 2 EF Method Detection Limit EF Method Detection Limit Compound mg/kg MRE Propene 249.59 1.51 256.14 1.56 Dichlorodifluoromethane (CFC 12) ND 0.09 ND 0.38 Chloromethane 1,2-Dichloro-1,1,2,2- tetrafluoroethane (CFC 114) 1.96 ND 0.08 0.10 4.52 ND 0.33 0.42 Vinyl Chloride 0.37 0.09 0.46 0.38 1,3-Butadiene 84.73 2.36 80.11 0.51 Bromomethane 0.22 0.10 ND 0.42 Chloroethane 0.23 0.09 ND 0.38 Ethanol 5.53 0.44 ND 1.77 Acetonitrile 6.86 0.10 10.81 0.40 Acrolein 113.98 1.81 138.88 0.38 Acetone ND 0.41 88.12 1.73 Trichlorofluoromethane ND 0.09 ND 0.38 2-Propanol (Isopropyl Alcohol) ND 0.22 ND 0.93 Acrylonitrile 4.05 0.09 6.32 0.38 1,1-Dichloroethene ND 0.09 ND 0.38 Methylene Chloride ND 0.09 ND 0.38 3-Chloro-1 -propene (Allyl Chloride) ND 0.08 ND 0.35 Trichlorotrifluoroethane ND 0.09 ND 0.38 Carbon Disulfide ND 0.08 ND 0.33 trans-1,2-Dichloroethene ND 0.10 ND 0.42 1,1-Dichloroethane ND 0.08 ND 0.35 Methyl tert-Butyl Ether ND 0.09 ND 0.38 Vinyl Acetate 77.36 0.35 109.62 1.43 2-Butanone (MEK) 20.00 0.11 29.64 0.46 cis-1,2-Dichloroethene ND 0.08 ND 0.35 Ethyl Acetate ND 0.19 ND 0.76 n-Hexane 8.21 0.08 9.82 0.33 Chloroform 0.29 0.09 ND 0.38 Tetrahydrofuran (THF) 2.51 0.11 3.04 0.46 1,2-Dichloroethane ND 0.08 ND 0.35 1,1,1-Trichloroethane ND 0.09 ND 0.38 Benzene 169.34 1.69 193.80 0.35 Carbon Tetrachloride 0.06 0.08 ND 0.33 Cyclohexane ND 0.15 ND 0.63 1,2-Dichloropropane ND 0.08 ND 0.35 38-B ------- Bromodichloromethane ND 0.08 ND 0.33 Trichloroethene ND 0.07 ND 0.31 1,4-Dioxane ND 0.08 ND 0.35 Methyl Methacrylate ND 0.17 ND 0.67 n-Heptane 7.74 0.09 12.65 0.38 cis-1,3-Dichloropropene ND 0.07 ND 0.31 4-Methyl-2-pentanone ND 0.08 0.67 0.35 trans-1,3-Dichloropropene ND 0.08 ND 0.35 1,1,2-Trichloroethane ND 0.08 ND 0.35 Toluene 40.37 0.09 63.07 0.38 2-Hexanone 3.68 0.08 6.32 0.35 Dibromochloromethane ND 0.08 ND 0.35 1,2-Dibromoethane ND 0.08 ND 0.35 n-Butyl Acetate ND 0.08 ND 0.35 n-Octane 5.89 0.10 8.85 0.40 Tetrachloroethene ND 0.07 ND 0.31 Chlorobenzene ND 0.08 ND 0.35 Ethyl benzene 18.79 0.08 18.13 0.35 m-,p-Xylenes 4.05 0.16 5.48 0.67 Bromoform ND 0.08 ND 0.33 Styrene 187.88 1.62 231.90 0.33 o-Xylene 2.25 0.08 3.04 0.33 n-Nonane 5.16 0.08 7.17 0.33 1,1,2,2-Tetrachloroethane ND 0.08 ND 0.33 Cumene 1.14 0.08 1.26 0.33 alpha-Pinene 0.74 0.07 1.01 0.31 n-Propylbenzene 1.14 0.08 1.90 0.35 4-Ethyltoluene 0.48 0.08 0.63 0.35 1,3,5-Trimethyl benzene 0.25 0.08 ND 0.35 1,2,4-Trimethyl benzene 0.70 0.08 1.01 0.33 Benzyl Chloride 0.17 0.06 ND 0.24 1,3-Dichlorobenzene ND 0.08 ND 0.33 1,4-Dichlorobenzene ND 0.07 ND 0.31 1,2-Dichlorobenzene ND 0.08 ND 0.33 d-Limonene 0.66 0.07 1.26 0.31 1,2-Dibromo-3-chloropropane ND 0.05 ND 0.22 1,2,4-Trichlorobenzene ND 0.08 ND 0.35 Naphthalene 23.58 0.10 46.38 0.40 Hexachlorobutadiene ND 0.07 ND 0.31 g/kg biomass g/kg biomass Carbon Monoxide 16.49 20.32 39-B ------- Methane 0.46 0.58 Carbon Dioxide 1534.60 1528.24 MCE ratio 0.983 0.979 40-B ------- Table B-22. VOC emission factor from open burning of 32 % NEW composite MRE material. 32 % NEW 1 2 3 EF Method Detection Limit EF Method Detection Limit EF Method Detection Limit Compound mg/kg MRE Propene 311.64 0.90 341.65 1.07 335.09 0.78 Dichlorodifluoromethane (CFC 12) ND 0.11 ND 0.13 ND 0.09 Chloromethane 2.39 0.09 2.48 0.11 2.00 0.08 1,2-Dichloro-1,1,2,2- tetrafluoroethane (CFC 114) ND 0.12 ND 0.14 ND 0.11 Vinyl Chloride 0.55 0.11 0.64 0.13 0.59 0.09 1,3-Butadiene 121.14 1.37 139.34 1.66 117.23 1.21 Bromomethane 0.25 0.12 0.46 0.14 0.27 0.11 Chloroethane 0.29 0.11 0.23 0.13 0.22 0.09 Ethanol ND 0.51 ND 0.59 1.64 0.43 Acetonitrile 11.58 0.11 11.06 0.14 13.53 0.10 Acrolein 128.71 1.06 160.44 1.29 144.35 0.94 Acetone ND 0.47 101.29 0.59 105.12 0.43 Trichlorofluoromethane ND 0.11 ND 0.13 ND 0.09 2-Propanol (Isopropyl Alcohol) ND 0.27 ND 0.32 ND 0.23 Acrylonitrile 6.64 0.11 7.50 0.13 7.03 0.09 1,1-Dichloroethene ND 0.11 ND 0.13 ND 0.09 Methylene Chloride ND 0.11 ND 0.13 ND 0.09 3-Chloro-1 -propene (Allyl Chloride) ND 0.10 ND 0.12 ND 0.09 Trichlorotrifluoroethane ND 0.11 ND 0.13 ND 0.09 Carbon Disulfide ND 0.09 ND 0.11 0.59 0.08 trans-1,2-Dichloroethene 0.23 0.12 0.29 0.14 ND 0.11 1,1-Dichloroethane ND 0.10 ND 0.12 ND 0.09 Methyl tert-Butyl Ether ND 0.11 ND 0.13 ND 0.09 Vinyl Acetate 85.97 0.39 133.98 0.49 113.33 0.36 2-Butanone (MEK) 22.00 0.13 28.03 0.16 29.03 0.12 cis-1,2-Dichloroethene ND 0.10 ND 0.12 ND 0.09 Ethyl Acetate ND 0.22 ND 0.27 ND 0.20 n-Hexane 11.44 0.09 11.94 0.11 13.79 0.08 Chloroform 0.25 0.11 ND 0.13 ND 0.09 Tetrahydrofuran (THF) 2.54 0.13 2.89 0.15 2.77 0.11 1,2-Dichloroethane ND 0.10 ND 0.12 ND 0.09 1,1,1-Trichloroethane ND 0.11 ND 0.13 ND 0.09 Benzene 257.78 1.02 262.41 1.23 277.31 0.90 Carbon Tetrachloride 0.02 0.09 0.02 0.11 0.01 0.08 Cyclohexane ND 0.18 ND 0.22 0.51 0.16 41-B ------- 1,2-Dichloropropane ND 0.10 0.28 0.12 ND 0.09 Bromodichloromethane ND 0.09 ND 0.11 ND 0.08 Trichloroethene ND 0.09 ND 0.11 ND 0.08 1,4-Dioxane 0.25 0.10 ND 0.12 ND 0.09 Methyl Methacrylate ND 0.20 ND 0.24 ND 0.17 n-Heptane 11.33 0.11 12.33 0.13 13.29 0.09 cis-1,3-Dichloropropene ND 0.09 ND 0.11 ND 0.08 4-Methyl-2-pentanone ND 0.10 ND 0.12 1.29 0.09 trans-1,3-Dichloropropene ND 0.10 ND 0.12 ND 0.09 1,1,2-Trichloroethane 0.13 0.10 ND 0.12 ND 0.09 Toluene 62.36 0.11 52.30 0.13 120.98 0.94 2-Hexanone 4.69 0.10 5.90 0.12 6.25 0.09 Dibromochloromethane ND 0.10 ND 0.12 ND 0.09 1,2-Dibromoethane ND 0.10 ND 0.12 ND 0.09 n-Butyl Acetate 0.28 0.10 0.18 0.12 ND 0.09 n- Octane 8.99 0.11 9.11 0.14 10.16 0.10 Tetrachloroethene ND 0.09 ND 0.11 ND 0.08 Chlorobenzene ND 0.10 0.28 0.12 0.19 0.09 Ethyl benzene 20.32 0.10 12.33 0.12 39.08 0.09 m-,p-Xylenes 5.86 0.19 5.20 0.23 7.03 0.17 Bromoform ND 0.09 ND 0.11 ND 0.08 Styrene 207.11 0.94 133.98 1.13 508.01 0.82 o-Xylene 3.17 0.09 2.68 0.11 3.79 0.08 n-Nonane 7.42 0.09 7.50 0.11 8.60 0.08 1,1,2,2-Tetrachloroethane ND 0.09 0.13 0.11 ND 0.08 Cumene 1.37 0.09 0.70 0.11 2.46 0.08 alpha-Pinene ND 0.09 0.91 0.11 0.70 0.08 n-Propylbenzene 1.76 0.10 1.23 0.12 2.27 0.09 4-Ethyltoluene 0.70 0.10 0.64 0.12 0.98 0.09 1,3,5-Trimethyl benzene 0.32 0.10 0.31 0.12 0.74 0.09 1,2,4-Trimethyl benzene 0.86 0.09 0.75 0.11 1.91 0.08 Benzyl Chloride 0.16 0.07 0.12 0.09 ND 0.06 1,3-Dichlorobenzene ND 0.09 ND 0.11 ND 0.08 1,4-Dichlorobenzene ND 0.09 ND 0.11 ND 0.08 1,2-Dichlorobenzene ND 0.09 ND 0.11 ND 0.08 d-Limonene 0.70 0.09 1.07 0.11 1.17 0.08 1,2-Dibromo-3-chloropropane ND 0.06 ND 0.08 ND 0.05 1,2,4-Trichlorobenzene ND 0.10 ND 0.12 ND 0.09 Naphthalene 38.69 0.11 33.23 0.14 33.22 0.10 Hexachlorobutadiene ND 0.09 ND 0.11 ND 0.08 g/kg biomass g/kg biomass g/kg biomass Carbon Monoxide 22.87 23.98 22.87 42-B ------- Methane 0.82 0.70 0.82 Carbon Dioxide 1557.34 1555.91 1557.34 MCE ratio 0.976 0.975 0.976 1030 43-B ------- Table B-23. VOC emission factor from open burning of 0 % NEW composite MRE material. 0 % NEW 1 2 3 EF Method Detection Limit EF Method Detection Limit EF Method Detection Limit Compound mg/kg MRE Propene 200.93 0.42 242.02 0.69 361.04 0.83 Dichlorodifluoromethane (CFC 12) 0.10 0.49 ND 0.08 ND 0.10 Chloromethane 5.12 0.45 1.42 0.08 3.06 0.09 1,2-Dichloro-1,1,2,2- tetrafluoroethane (CFC 114) ND 0.56 ND 0.09 ND 0.11 Vinyl Chloride ND 0.49 0.36 0.08 0.74 0.10 1,3-Butadiene 69.59 0.63 94.27 1.09 143.98 1.27 Bromomethane ND 0.56 0.21 0.09 0.70 0.11 Chloroethane ND 0.49 0.09 0.08 0.24 0.10 Ethanol 3.20 2.33 4.35 0.40 1.83 0.48 Acetonitrile 7.87 0.52 4.94 0.09 9.87 0.10 Acrolein 111.12 0.49 94.04 0.83 169.89 1.00 Acetone ND 2.26 ND 0.40 126.09 0.44 Trichlorofluoromethane ND 0.49 ND 0.08 ND 0.10 2-Propanol (Isopropyl Alcohol) ND 1.22 ND 0.21 ND 0.24 Acrylonitrile 4.52 0.49 4.35 0.08 7.85 0.10 1,1-Dichloroethene ND 0.49 ND 0.08 ND 0.10 Methylene Chloride ND 0.49 ND 0.08 8.51 0.10 3-Chloro-1 -propene (Allyl Chloride) ND 0.45 ND 0.08 ND 0.09 Trichlorotrifluoroethane ND 0.49 ND 0.08 ND 0.10 Carbon Disulfide ND 0.45 31.54 0.08 ND 0.09 trans-1,2-Dichloroethene ND 0.56 0.19 0.09 ND 0.11 1,1-Dichloroethane ND 0.45 ND 0.08 ND 0.09 Methyl tert-Butyl Ether ND 0.49 ND 0.08 ND 0.10 Vinyl Acetate 83.50 1.91 72.51 0.33 148.34 0.38 2-Butanone (MEK) 18.55 0.63 20.05 0.11 31.11 0.12 cis-1,2-Dichloroethene ND 0.45 ND 0.08 ND 0.09 Ethyl Acetate ND 1.01 ND 0.17 ND 0.21 n-Hexane 8.10 0.45 8.80 0.08 13.65 0.09 Chloroform ND 0.49 ND 0.08 ND 0.10 Tetrahydrofuran (THF) 2.09 0.59 2.18 0.10 3.18 0.12 1,2-Dichloroethane ND 0.45 ND 0.08 ND 0.09 1,1,1-Trichloroethane ND 0.49 ND 0.08 ND 0.10 Benzene 135.57 0.45 188.41 0.80 309.62 0.92 Carbon Tetrachloride ND 0.45 0.02 0.08 0.03 0.09 Cyclohexane ND 0.84 0.30 0.15 ND 0.17 44-B ------- 1,2-Dichloropropane ND 0.45 0.22 0.08 ND 0.09 Bromodichloromethane ND 0.45 ND 0.08 ND 0.09 Trichloroethene ND 0.42 ND 0.07 ND 0.08 1,4-Dioxane ND 0.45 0.11 0.08 ND 0.09 Methyl Methacrylate ND 0.90 ND 0.16 ND 0.18 n-Heptane 8.00 0.49 9.43 0.08 13.96 0.10 cis-1,3-Dichloropropene ND 0.42 ND 0.07 ND 0.08 4-Methyl-2-pentanone 0.63 0.45 0.65 0.08 1.09 0.09 trans-1,3-Dichloropropene ND 0.45 ND 0.08 ND 0.09 1,1,2-Trichloroethane ND 0.45 ND 0.08 0.09 0.09 Toluene 45.09 0.49 39.73 0.08 104.53 1.00 2-Hexanone 4.18 0.45 4.35 0.08 6.11 0.09 Dibromochloromethane ND 0.45 ND 0.08 ND 0.09 1,2-Dibromoethane ND 0.45 ND 0.08 ND 0.09 n-Butyl Acetate ND 0.45 0.15 0.08 ND 0.09 n-Octane 6.26 0.52 6.89 0.09 10.03 0.10 Tetrachloroethene ND 0.42 ND 0.07 ND 0.08 Chlorobenzene ND 0.45 0.21 0.08 0.20 0.09 Ethyl benzene 10.09 0.45 9.06 0.08 30.10 0.09 m-,p-Xylenes 4.87 0.87 5.08 0.15 6.11 0.17 Bromoform ND 0.45 ND 0.08 ND 0.09 Styrene 100.90 0.45 90.64 0.76 427.57 0.87 o-Xylene 2.57 0.45 2.36 0.08 3.05 0.09 n-Nonane 4.87 0.45 5.44 0.08 8.29 0.09 1,1,2,2-Tetrachloroethane ND 0.45 ND 0.08 ND 0.09 Cumene 0.59 0.45 0.51 0.08 1.75 0.09 alpha-Pinene 1.15 0.42 0.54 0.07 ND 0.08 n-Propylbenzene 1.18 0.45 0.94 0.08 1.53 0.09 4-Ethyltoluene 0.59 0.45 0.54 0.08 0.74 0.09 1,3,5-Trimethyl benzene ND 0.45 0.40 0.08 0.43 0.09 1,2,4-Trimethyl benzene 0.77 0.45 0.73 0.08 0.87 0.09 Benzyl Chloride ND 0.32 0.14 0.05 0.24 0.07 1,3-Dichlorobenzene ND 0.45 ND 0.08 ND 0.09 1,4-Dichlorobenzene ND 0.42 ND 0.07 ND 0.08 1,2-Dichlorobenzene ND 0.45 ND 0.08 ND 0.09 d-Limonene ND 0.42 0.94 0.07 1.09 0.08 1,2-Dibromo-3-chloropropane ND 0.29 ND 0.05 ND 0.06 1,2,4-Trichlorobenzene ND 0.45 ND 0.08 ND 0.09 Naphthalene 32.36 0.52 30.09 0.09 43.63 0.10 Hexachlorobutadiene ND 0.42 ND 0.07 ND 0.08 g/kg biomass g/kg biomass g/kg biomass Carbon Monoxide 18.77 19.97 24.53 45-B ------- Methane 0.66 0.62 0.77 Carbon Dioxide 1512.10 1510.32 1502.73 MCE ratio 0.980 0.979 0.974 46-B ------- 1035 Table B-24. VOC emission factor from open burning of baseline (CB/CL). Compound CB/CL - baseline 1 Method Detection EF Limit mq/kq fiberboard Propene 16.70 0.06 Dichlorodifluoromethane (CFC-12) ND 0.08 Chloromethane 1.45 0.07 1,2-Dichloro-1,1,2,2- tetrafluoroethane (CFC-114) ND 0.09 Vinyl Chloride ND 0.08 1,3-Butadiene 5.77 0.10 Bromomethane ND 0.09 Chloroethane ND 0.08 Ethanol 0.38 0.36 Acetonitrile 0.56 0.08 Acrolein 13.51 0.08 Acetone 8.34 0.35 Trichlorofluoromethane ND 0.08 2-Propanol (Isopropyl Alcohol) ND 0.18 Acrylonitrile 0.24 0.08 1,1-Dichloroethene ND 0.08 Methylene Chloride 0.14 0.08 3-Chloro-1 -propene (Allyl Chloride) ND 0.07 Trichlorotrifluoroethane ND 0.08 Carbon Disulfide 1.21 0.07 trans-1,2-Dichloroethene ND 0.09 1,1-Dichloroethane ND 0.07 Methyl tert-Butyl Ether ND 0.08 Vinyl Acetate 22.77 0.29 2-Butanone (MEK) 2.87 0.09 cis-1,2-Dichloroethene ND 0.07 Ethyl Acetate 0.09 0.15 n-Hexane 0.07 0.07 Chloroform ND 0.08 Tetrahydrofuran (THF) 0.10 0.09 1,2-Dichloroethane 1,1,1-Trichloroethane Benzene Carbon Tetrachloride Cyclohexane 1,2-Dichloropropane ND ND 33.35 0.01 ND ND 0.07 0.08 0.07 0.07 0.13 0.07 47-B ------- Bromodichloromethane ND 0.07 Trichloroethene ND 0.06 1,4-Dioxane ND 0.07 Methyl Methacrylate ND 0.14 n-Heptane ND 0.08 cis-1,3-Dichloropropene ND 0.06 4-Methyl-2-pentanone ND 0.07 trans-1,3-Dichloropropene ND 0.07 1,1,2-Trichloroethane ND 0.07 Toluene 7.21 0.08 2-Hexanone 0.08 0.07 Dibromochloromethane ND 0.07 1,2-Dibromoethane ND 0.07 n-Butyl Acetate ND 0.07 n-Octane ND 0.08 Tetrachloroethene ND 0.06 Chlorobenzene ND 0.07 Ethyl benzene 1.02 0.07 m-,p-Xylenes 0.88 0.13 Bromoform ND 0.07 Styrene 3.49 0.07 o-Xylene 0.36 0.07 n-Nonane ND 0.07 1,1,2,2-Tetrachloroethane ND 0.07 Cumene ND 0.07 alpha-Pinene 0.08 0.06 n-Propylbenzene ND 0.07 4-Ethyltoluene 0.09 0.07 1,3,5-Trimethyl benzene ND 0.07 1,2,4-Trimethyl benzene 0.12 0.07 Benzyl Chloride ND 0.05 1,3-Dichlorobenzene ND 0.07 1,4-Dichlorobenzene ND 0.06 1,2-Dichlorobenzene ND 0.07 d-Limonene 0.10 0.06 1,2-Dibromo-3-chloropropane ND 0.04 1,2,4-Trichlorobenzene ND 0.07 Naphthalene 11.39 0.08 Hexachlorobutadiene ND 0.06 g/kg fiber board Carbon Monoxide 14.29 Methane 0.13 48-B ------- Carbon Dioxide 1672.84 MCE ratio 0.987 49-B ------- SEPA United States Environmental Protection Agency Office of Research and Development (8101R) Washington, DC 20460 Official Business Penalty for Private Use $300 Printed on 100% recycled/recyclable paper a with a minimum 50% post-consumer fiber using vegetable-based ink. PRESORTED STANDARD POSTAGE & FEES PAID EPA PERMIT NO. G-35 ------- |