United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park. NC 27711
EPA - 454/R-99-041b
August 1999
Air
Integrated Iron and Steel Industry Final Repor
Manual Testing
Volume II of III
Youngstown Sinter Company
Youngstown, Ohio
-------
Integrated Iron and Steel Industry
Final Report
Volume II of III
Appendices
Contract No. 68-1)7-0068
Work Assignment 2-13
Youngstown Sinter Company
Youngstown, Ohio
Prepared for:
Michael K. Ciolek
Emission Measurement Center
Emission, Monitoring, and Analysis Division
Office of Air Quality Planning and Standards
U.S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
August 1999
*ERG
EASTERN
RESEARCH GROUP, I N C
-------
Table of Contents
Appendix A D/F Laboratory Analysis Data
Appendix B PAH Laboratory Analysis Data
-------
Appendix A
D/F Laboratory Analysis Data
-------
SAMPLE
DATA
I
{
I
Triangle Laboratories, Inc.
801 Capitola Drive P.O. Box 13485
Durham, NC27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax #919-544-5491
-------
TRIANGLE LABORATORIES OF RTP, INC. Page 1
Sample Result Summary for Project 42930A 09/08/97
Method 23X Full Screen Analyses (DB-5)
Data File S975665 S975666 S9756S7 S975S«
Sample ID TLX M23 Blank RUN 1 RUN 2 RUN 2
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
ng
08/25/97
09/05/97
S
XAD
Soxhlet
ng
08/25/97
09/05/97
S
M2 3TRAIN
Soxhlet
ng
08/25/97
09/05/97
S
M2 3TRAIN
Soxhlet
ng
08/25/97
09/05/97
S
M23TRAIN
Soxhlet
Analytes
2378-TCDD
(0.01)
0.62
0
24
0 .44
12378-PeCDD
(0 .03)
1.7
0
62
0.95
123478-HxCDD
(0 .03)
0 .38
0
15
0 .19
123 67 8-HxCDD
(0.02)
3.8
1
4
1. 6
123789-HxCDD
(0.02)
1.6
PR
0
57
PR
0 .71
1234678-HpCDD
(0.03)
1.8
0
68
0 .85
OCDD
(0 .07)
0 .96
0
37
0 .47
2378-TCDF
(0.01)
50.2
19
1
41. 0
12378-PeCDF
(0.02)
6.7
2
4
3.5
23478-PeCDF
(0.02)
6.9
2
4
3.2
123478-HxCDF
(0.02)
3.9
PR
1
2
PR
1.5
123678-HxCDF
(0.01)
1.4
0
42
0.53
234678-HxCDF
(0.01)
0.88
PR
{0
25}
PR
0.35
123789-HxCDF
(0.02)
0.10
0
03
(0.2)
1234678-HpCDF
(0 .02)
0.88
{0
30}
0 .3 S
1234789-HpCDF
(0.03)
(0.2)
(0
2)
(0.4)
OCDF
(0.05)
(0.4)
(0
3)
(0.6)
TOTAL TCDD
(0.01)
15.1
5
7
Q
10 .6
TOTAL PeCDD
(0.03)
13 .8
6
0
7.0
TOTAL HxCDD
(0.02)
33 .9
12
3
15.2
TOTAL HpCDD
(0.03)
5.5
2
1
2. 6
TOTAL TCDF
(0.01)
413
155
381
TOTAL PeCDF
(0.02)
100
35
.5
53 .2
TOTAL HxCDF
(0.01)
16.1
4
6
5.8
TOTAL HpCDF
(0.02)
1.2
0
.18
0.38
Other Standards Percent Recovery Summary (% Rec)
37C1-TCDD 98.4 100 92.0 89.5
13C12-PeCDF 234 92.9 81.8 87.1 70.1
13C12-HxCDF 478 92.2 105 102 85.1
13C12-HxCDD 478 88.4 103 97.7 95.3
13C12-HpCDF 789 89.2 100 99.3 68.8 V
Other Standards Percent Recovery Summary (% Rec)
13012-HxCDF 789 93.2 97.9 98.7 106
13C12-HxCDF 234 96.2 100 106 106
Internal Standards
Percent
Recovery Summary (% Rec)
13C12-2378-TCDF
88 .3
92.9
96.6
92.0
13C12-2378-TCDD
77 .7
85.1
91.9
86.4
13C12-PeCDF 123
75.5
59.7
67.0
60 .2
13C12-PeCDD 123
68.1
49 .4
58.5
47.4
13C12-HXCDF 678
101
111
108
112
13C12-HxCDD 678
87 .4
95.4
95.5
94 .6
13C12-HpCDF 678
80 .8
65.0
63 .7
65.0
13C12-HpCDD 678
80.7
68.9
70 .1
69 .5
13C12-OCDD
58.8
52.0
55.0
52.4
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:32 09/08/97
-------
TRIANGLE LABORATORIES OF RTP, INC.
Sample Result Summary for Project 42930A
Method 23X Full Screen Analyses (DB-5)
Page 2
09/08/97
Data File
S975669
S975670
S975671
S975672
Sample ID
FB 1
RB 1
RUN 4
RUN 5
Units
ng
ng
ng
ng
Extraction Date
08/25/97
08/25/97
08/25/97
08/25/97
Analysis Date
09/05/97
09/05/97
09/05/97
09/05/97
Instrument
S
S
S
S
Matrix
M2 3TRAIN
M2 3TRAIN
M23TRAIN
M23TRAIN
Extraction Type
Soxhiet
Soxhiet
Soxhiet
Soxhiet
Analytes
2378-TCDD
(0 .
01)
(0.
01)
0 .54
0 .43
12378-PeCDD
(0.
02)
(0.
02)
1.1
1.2
123478-HxCDD
(0.
02)
(0.
02)
0 .14
{0.14}
123678-HxCDD
(0.
01)
(0.
01)
1.7
1.8
123789-HxCDD
(0 .
01)
(0.
01)
0.67 ?R
0.73 PR
1234 67 8-HpCDD
(0.
02)
(0.
02)
0 .81
0 .77
OCDD
{0.
07}
(0 .
04)
{1.6}
0 .33
2378-TCDF
{0.
05}
(0.
008)
43 .3
37 . 8
12378-PeCDF
(0.
01)
(0.
01)
4.7
4 . 0
23478-PeCDF
(0.
01)
(0.
01)
4.2
3.8
12347 8-HxCDF
(0.
01)
(0.
01)
1.7 PR
1.6 PR
123678-HxCDF
(0.
007)
(0.
009)
O.ol
0 . 58
23467 8-HxCDF
(0.
01)
(0.
01)
0.32 ?R
0.32 PR
1237 89-HxCDF
(0.
01)
(0.
01)
0 . 04
0 .06
123 4 678-HpCDF
(0.
01)
(0.
01)
0 .38
0 .34
1234789-HpCDF
(0.
02)
(0.
02)
(0.2)
(0.2)
OCDF
(0 .
03 )
(0.
03)
0.17
(0.4)
TOTAL TCDD
(0.
01)
(0 .
01)
11.4
10 .7
TOTAL PeCDD
(0.
02)
(0.
02)
11. 6
11.3
TOTAL HxCDD
{0.
02}
(0.
02)
16 .1
17 .4
TOTAL HpCDD
{0.
04}
(0.
02)
2.5
2.3
TOTAL TCDF
0 .
02
(0.
008)
349
335 Q
TOTAL PeCDF
{0.
02}
(0.
01)
70.5
59 .7
TOTAL HxCDF
(0.
009)
(0 .
01)
6.9
6.5
TOTAL HpCDF
(0.
01)
(0.
02)
0 .47
0.34
Other Standards
Per
cent
Recovery
Summary
(% Rec)
37C1-TCDD
98
. 5
98
. 1
103
94 .3
13C12-PeCDF 234
84
.1
96
.8
79.5
88.8
13C12-HxCDF 478
85
.9
94
.8
108
109
13C12-HxCDD 478
90
.3
89
.2
104
102
13C12-HpCDF 789
75
.5
96
.4
98.5
93 . 5
Other Standards
Percent
Recovery
Summary
(% Rec)
13C12-HxCDF 789
82
. 6
73
.4
106
109
13C12-HxCDF 234
90
.4
77
.7
109
111
Internal Standards
Percent Recovery Summary (% Rec)
13C12-2378-TCDF
79
.4
76
.1
97 .0
100.0
13C12-2378-TCDD
76
.6
66
.7
85.7
88 .1
13C12-PeCDF 123
71
.9
59
.7
67 .3
59.5
13C12-PeCDD 123
69
.5
63
.0
48 .1
42.1
13C12-HxCDF 678
94
. 1
74
.2
120
119
13C12-HxCDD 678
86
;.8
75
. 9
94 .4
98 .3
13C12-HpCDF 678
77
.8
66
; .8
56.1
60.6
13C12-HpCDD 678
80
.7
75
.0
59.0
59 .9
13C12-OCDD
54
.0
57
.2
36.4
44 .4
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:32 09/08/97
-------
TRIANGLE LABORATORIES OF RTP, INC. Page 3
Sample Result Summary for Project 42930A 09/08/97
Method 23X Full Screen Analyses (DB-5)
Data File S975673
Sample ID FB 2
Units ng
Extraction Date 08/25/97
Analysis Date 09/05/97
Instrument S
Matrix M23TRAIN
Extraction Type Soxhlet
Analytes
2378-TCDD
(0.02)
12378-PeCDD
{0.03)
123478-HxCDD
(0.02)
123678-HxCDD
(0.02)
123789-HxCDD
(0.02)
1234678-HpCDD
(0.03)
OCDD
{0.21}
2378-TCDF
(0.01)
12378-PeCDF
(0.02)
23478-PeCDF
(0.02)
123478-HxCDF
(0.01)
123678-HxCDF
(0.01)
234678-HxCDF
(0.01)
123789-HxCDF
(0 .02)
1234678-HoCDF
(0.02)
1234789-KpCDF
(0.02)
OCDF
(0.08)
TOTAL TCDD
(0.02)
TOTAL PeCDD
(0.03)
TOTAL HxCDD
(0.02)
TOTAL HpCDD
(0.03)
TOTAL TCDF
(0.01)
TOTAL PeCDF
(0.02)
TOTAL HxCDF
(0.01)
TOTAL HdCDF
(0.02)
Other Standards Percent Recovery Summary (% Rec)
37C1-TCDD 97.0
13C12-PeCDF 234 86.3
13C12-HXCDF 478 92.9
13C12-HxCOD 478 91.9
13C12-HpCDF 789 70.3
Other Standards Percent Recovery Summary {% Rec}
13C12-HXCDF 789 68.3
13C12-HXCDF 234 84.9
Internal Standards
Percent Recovery Summary (% Rec)
13C12-2378-TCDF
82.3
13C12-2378-TCDD
67 .9
13C12-PeCDF 123
60.8
13C12-PeCDD 123
51.7
13C12-HxCBF 678
107
13C12-HxCDD 678
99 .4
13C12-HpCDF 678
87 .0
13C12-HpCDD 678
79.8
13C12-OCDD
35.0
{Estimated Maximum Possible Concentration), {Detection Limit).
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitoia Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:32 09/08/97
-------
TRIANGLE LABORATORIES OF RTP, INC.
Sample Result Summary for Project 42930A
Method 23X (DB-225)
Page 1
09/08/97
Data File
Sample ID
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
X973013
RUN 1
ng
08/25/97
09/06/97
X
M23TRAIN
Soxhlet
X973014
RUN 2
ng
08/25/97
09/06/97
X
M23TRAIN
Soxhlet
X973015
RUN 3
ng
08/25/97
09/06/97
X
M23TRAIN
Soxhlet
X973016
FB 1
ng
08/25/97
09/06/97
X
M23TRAIN
Soxhlet
Analytes
2378-TCDF 15.4 5.9 11.5 0.02
Internal Standards Percent Recovery Summary (% Rec)
13C12-2378-TCDF 80.6 85.1 82.3 68.3
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 18:08 09/08/97
-------
TRIANGLE LABORATORIES OF RTP, INC.
Sample Result Summary for Project 4293OA
Method 23X (DB-225)
Page 2
09/08/97
5 = = = =:=: =
Data File
Sample ID
X973017
RUN 4
X973018
RUN 5
Units
Extraction Date
Analysis Date
Instrument
Matrix
Extraction Type
ng
08/25/97
09/06/97
X
M23TRAIN
Soxhlet
ng
08/25/97
09/07/97
X
M23TRAIN
Soxhlet
Analytes
2378-TCDF
12.8
11.2
Internal Standards Percent Recovery Summary (% Rec)
13C12-237 8-TCDF 84.5 77.9
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 18:08 09/08/97
-------
TLI Project: 42930A Method 23 PCDD/PCDF Analysis (a)
Client Sample: TLI M23 Blank Analysis File: S975665
Client Project:
Iron & Steel-Youngstowri
Sample Matrix:
XAD
Date Received: / /
Spike File:
SPX23704
TLI ID:
TLI Blank
Date Extracted: 08/25/97
ICal:
SF56117
-
Date Analyzed: 09/05/97
ConCal:
S975664
Sample Size:
1.000
Dilution Factor: n/a
% Moisture:
n/a
Dry Weight:
n/a
Blank File:
S975665
% Lipid:
n/a
GC Column:
DB-5
Analyst:
HLM
% Solids:
n/a
Analytes
Amt. (ng} DL
EMPC
Ratio
RT Flags
2,3,7,8-TCDD
ND 0.01
1,2,3,7.8-PeCDD
ND 0.03
1,2,3,4,7,8-HxCDD
ND 0.03
1.2,3,6,7.8-HxCDD
ND 0.02
1,2,3,7,8,i)-HxCDD
ND 0.02
1,2,3,4,6,7.8-HpCDD
ND 0.03
1.2,3,4,6.7.8,9-OCDD
ND 0.07
—
2,3,7,8-TCDF
ND 0.01
1,2.3,7,8-PeCDF
ND 0.02
2.3.4,7.8-PeCDF
ND 0.02
1,2,3,4,7,8-HxCDF
ND 0.02
1,2,3,6.7,8-HxCDF
ND 0.01
2.3,4.6.7.8-HxCDF
ND 0.01
1,2.3.7.8,9-HxCDF
ND 0.02
1,2,3,4,6,7,8-HpCDF
ND 0.02
1.2,3.4,7.8,9-HpCDF
ND 0.03
1,2,3,4,6,7,8,9-0 CDF
ND 0.05
Totals
Amt (ng) Number
DL EMPC
Flags
Total TCDD
ND
0.01
Total PeCDD
ND
0.03
Total HxCDD
ND
0.02
Total HpCDD
ND
0.03
—
Total TCDF
ND
0.01
Total PeCDF
ND
0.02
Total HxCDF
ND
0.01
Total HpCDF
ND
0.02
Page 1 of 2 X237„PSR vZOO, LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:30 09/08/97
-------
TLI Project: 42930A Method 23 PCDD/PCDF Analysis (a)
Client Sample: TLI M23 Blank Analysis File: S975665
internal Standards
Amt(ng)
% Recovery
QC Limits
Ratio
RT
Flags
i3Ci:-2,3,7,8-TCDF
3.5
88.3
40%-130%
0.75
20:44
i}C,:-2,3,7,8-TCDD
3.1
77.7
40%-130%
0.84
21:31
13C,:-1,2,3,7,8-PeCDF
3.0
75.5
40%-130%
1.63
24:56
l3C, 2-1,2,3.7,8-PeCDD
2.7
68.1
40%-130%
1.47
26:03
l3Ci2-l,2,3,6,7,8-HxCDF
4.0
101
40%-130%
0.50
28:37
l3Cia- 1,2,3,6,7,8-HxCDD
3.5
87.4
40%-130%
1.23
29:19
13C:;-1,2,3.4.6.7,8-HpCDF
3.2
80.8
25%-130%
0.43
31:17
,3C13-1.2,3,4,6,7,8-HpCDD
3.2
80.7
25%-130%
1.00
32:08
nCn-1,2,3.4,6.7,8,9-OCDD
4.7
58.8
25%-130%
0.90
34:35
—
| Surrogate Standards (Type A)
Amt. (fig)
% Recovery
QC Limits
Ratio
RT
Flags
i7CL-2,3,7,8-TCDD
3.9
98.4
70%-140%
21:32
,}C, 2-2.3,4,7,8-PeCDF
3.7
92.9
70%-140%
1.65
25:42
1 }Ci2-1,2,3,4,7,8-HxCDF
3.7
92.2
70%-140%
0.50
28:31
13C,2-1,2,3,4,7,8-HxCDD
3.5
88.4
70%-140%
1.23
29:15
i3C,2-1,2,3,4,7,8,9-HpCDF
3.6
89.2
70%-140%
0.42
32:29
—
Amt. (ng)
QC Limits
Ratio
RT ;
Flags
,3Cirl. 2,3.7,8,9-HxCDF
3.7
93.2
40%-130%
0.51
29:50
l3C,2-2,3,4,6,7.8-HxCDF
3.8
96.2
40%-130%
0.54
29:08
—
13Ci2-l,2,3,4-TCDD
0.82
21:18
l3Ci2-l,2,3,7,8.9-HxCX>D
1.14
29:37
Data Reviewer »¦ -/ 09/08/97
Page 2 of 2 jottjwr »2.oo. lars e.io.w
Triangle Laboratories, Inc.®
801 Cap'rtola Drive* Durham, North Carolina 27713
Phone: (919) 544-5729 ~ Fax: (919) 544-5491
Printed: 15:30 09/08/97
-------
Initial
...Oat*...
Data Review By:
3-/Sb%2 Calculated Noise
Ar»a:
1.3?
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page Ho.
1
Listing of S9756658.dbf
09/05/97
Matched
GC Peaks /
Ratio / Ret. Time
Confound/
H_Z QC.Log Omit Why
. .RT.
OK
Ratio Total
.Area—
Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name..
ID.
TCDF
0.
65-0.89
0.827-1.099
304-306
DC
HI,
0:00
RO
1.21
0.25
0.000
DC
SN
18:02
0.78
0.71
0.870
DC
SN
18:29
RO
2.33
0.53
0.891
DC
SN
20:47
RO
0.38
2.11
1.002 2378-TCDF
AN
DC
SH
22:27
RO
1.33
0.64
1.083
DC
SN
22:44
RO
1.07
1.54
1.096
304-306
0
Peaks
0.00
13C12-TCDF
0.
.65-0.89
0.952-1,048
316-318
DC
Ht
0:00
RO
1.08
0.21
0.000
DC
SN
19:53
0.84
3.39
0.959
20:44
0.75
1,100.09
472.50 627.59 1.000 13C12-2378-TCDF
ISO
DC
m
22:35
RO
2.03
0.64
1.089
316-318
i
Peak
1,100.09
Flags,
Above: TCDF / TCDD Follows
TCDD
320-322
320-322
DC
ML
0:00
0.85
0.24
0.000
DC
SH
18:36 RO
1.41
0.39
0.864
DC
SN
18:42 RO
0.46
0,60
0.869
DC
SN
18s48 RO
3.38
0.42
0.874
DC
SN
18:54 RO
0.26
0.32
0.878
DC
SN
19:15 RO
0.42
0.94
0.895
DC
SN
19:37 RO
1.54
0.23
0.912
DC
SN
19:44 RO
1.42
0.46
0.917
DC
SN
19:49
0.68
0.74
0.921
DC
SN
20:04 RO
1.86
1.26
0.933
DC
SN
20:23 RO
2.47
0.27
0.947
DC
SN
20:27 RO
3.31
0.28
0,950
DC
SN
21:01 RO
2.13
0.55
0.977
DC
SN
21:21 RO
0.30
0.39
0.992
DC
SN
22:00 RO
0.28
0.55
1.022
DC
SN
22:06 RO
0.60
1.08
1.027
DC
SN
22:16 RO
1.37
0.73
1.035
DC
SN
22:26
0.81
1.65
1.043
DC
HH
22:59 RO
0.03
,0.0S
1.068
0
Peaks
0.00
37C1-TCDD
328
DC
NL
0:00
DC
W,
18:36
DC
WL
18:46
0.13
0.91
0.51
0.907-1.093
0.000
0.864
0.872
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 06:47 09/05/97_
-------
Page Ho. 2 lasting of S975665B.db£
09/05/97 Matched GC Peaks / ftatio / Ret. Tin*
Compound/
M_z QC.Log Omit Why . .RT. OX Ratio Total-Area... Area.Pea*.1.. JWrea.Peak.2.. Rel.RT Ccnuound.Naine.. ID.. Flags.
DC
ML
19:02
1.25
0.885
DC
WL
19:22
0.45
0.900
DC
SN
19:31
0.34
0.907
DC
SN
19:39
1.01
0.913
DC
SN
19:49
0.39
0.921
20:01
4.42
4.42
0.930
DC
SN
20:32
0.68
0.954
DC
SN
20:43
0.71
0.963
DC
SN
20:57
0.22
0.S74
DC
SN
21:07
0.76
0.981
DC
SN
21:19
0.24
0.991
21:32
649.63
649.63
1.001
DC
SN
21:49
1.15
1.014
DC
SN
21:53
1.13
1.017
DC
SN
22:06
0.95
1.027
DC
SN
22:09
0.54
1.029
DC
SN
22:20
1.23
1.038
DC
SN
22:32
0.76
1.047
DC
SN
22:38
1.00
1.052
DC
SN
22:45
1.45
1.057
DC
SN
23:03
1.06
1.071
DC
SN
23:11
0.38
1.077
2
Paaks
654.05
13C12-TCDD 0.65-0.89 0,907-1.093
332-334 DC NL 0:00 RO 9.87 0.27 0.000
332-334
0.
65-0.89
DC
NL
0:00
RO
9.87
0.27
20:14
RO
1.50
4.12
DC
SN
20:37
RO
1.51
2.00
21:18
0.82
945.63
21:31
0.84
783.11
21:52
0.86
17.19
22:06
RO
1.90
3.13
DC
SH
22:24
RO
1.35
2.78
DC
SN
22:35
RO
7.95
0.69
DC
SN
22:35
RO
5.28
0.71
5
Peaks
1,753.18
3.49 2.33 0.940
0.9S8
426.86 518.77 0.990 13C12-1234-TCDD RSI
358.54 424.57 1.000 13C12-2378-TCDD IS1
7.94 9.25 1.016
3.37 1.77 1.027
1.041
1.050
1.050
Above: TCDD / PeCBF Follows
PeCOP
340-342
1.
32-1.78
0.910-1.076
DC
NL
0:00
RO
1.23
0.26
0.000
DC
SN
22:52
RO
4.67
0.38
0.917
DC
SN
23:29
RO
0.10
0.07
0.942
DC
SN
24:08
RO
0.04
0.07
0.968
DC
SN
24:18
RO
0.27
0.66
0.975
DC
SN
24:53
RO
0.34
0.46
1.001 12378'
DC
SN
25:09
RO
0.09
0.16
1.009
DC
SN
25:14
RO
3.00
0.36
1.012
DC
SN
25:45
SO
0.02
0.08
1.033
DC
SN
25:55
RO
0.37
0.43
1.039
DC
SN
26:08
1.52
1.36
1.048
DC
SN
26:20
RO
0.21
0.69
1.056
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capftola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 06:47 09/05/97,
-------
Page Ho. 3
09/05/97
Listing of S975665B.dbf
Hatched CC Peaks / Ratio / Ret. Time
Compound/
H_Z.... QC.Log Omit Why
..RT. OK
Ratio Total
.Area...
Area.Peak.1.. Area.
.Peak.2.. Rel.RT Compound.Namo..
DC
SN
26:33 RO
0.19
1.10
1.065
DC
WH
26;57 RO
4.14
0.54
1.081
340-342
0
Peaks
0.00
13C12-PeCDF
1.
32-1.78
0.840-1.160
352-354
DC
NL
0:00 RO
1.15
0.25
0.000
DC
SN
24:03
1.59
3.06
0.965
24:33 BO
0.94
5.89
3.58
3.79 0.985
24:56
1.63
808.46
501.25
307.21 1.000 13C12-PeCDF 123
25:16 RO
1.09
7.52
4.57
4.19 1.013
25:22 RO
0.87
2.94
1.79
2.05 1.017
DC
SN
25:33
1.43
2.48
1.025
25:42
1.65
728.58
453.23
275.35 1.031 13C12-PeCDP 234
DC
SN
25:56 RO
3.76
2.37
1.040
DC
SN
26:05 RO
0.64
1.48
1.046
DC
SN
26:38 RO
1.85
2.27
1.068
DC
SN
26:48 RO
2.65
0.43
1.075
DC
SN
26:54 RO
0.23
0.49
1.079
DC
SN
27:14 RO
1.03
0.59
1.092
352-354
5
Peaks
1,553.39
FeCDF /
Jrv^ULf ruliuvra — — — — ¦
PeCOO
1.
32-1.78
0.923-1.025
356-358
DC
NL
0:00 RO
0.93
0.21
0.000
DC
SN
24:06 RO
0.60
1.20
0.925
DC
SN
24:38 RO
13.57
0.18
0.946
DC
SN
24:46 RO
2.19
0.94
0.951
DC
SN
25:05 RO
3.48
0.69
0.963
DC
SN
25:11 RO
1.02
0.90
0.967
DC
SN
25:41
1.44
2.42
0.986
DC
SN
25:52 RO
0.69
0.84
0.993
DC
SN
26:13 RO
3.00
0.66
1.006
DC
SN
26:30 RO
4.15
0.33
1.017
DC
WH
26:50 RO
18.20
0.13
1.030
DC
WH
26:59 RO
6.00
0.28
1.036
356-358
0
Peaks
0.00
13C12-P«CDD
1.
,32-1.78
0.847-1.153
368-370
DC
NIi
0:00 RO
1.00
0.23
0.000
DC
SN
24:14 RO
7.08
0.31
0.930
DC
SN
24:34 RO
2.75
0.41
0.943
DC
SN
24:51 RO
2.84
0.97
0.954
DC
SN
24:55 RO
1.13
1.43
0.956
DC
SN
25:38 RO
0.37
0.43
0.984
DC
SN
25:45 RO
0.40
0.67
0.988
26:03
1.47
408.64
242.87
165.77 1.000 13C12-PeCDD 123
26s11 RO
1.82
42.43
30.27
16.64 1.005
DC
SM
26:38 RO
1.07
0.26
1.022
DC
SN
26:48
1.68
1.34
1.029
368-370
2
Peaks
451.07
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 06:47 09/05/97
-------
Pago No. 4
09/05/97
Listing of S975665B.db£
Matched GC Peaks / Ratio / Rat. Tina
Compound/
M_2 QC.Log Omit Why . .RT. OK Ratio Total.Araa... Araa.Peak.1.. Araa.Peak.2.. Ral.RT Confound. Nana.. ID.. Flags.
HxCDF
374-376
374-376
13C12-HXCOF
384-386
384-386
PaCDD I \
HxCDF Follows
1.
05-1.43
0.957-1.051
DC
0:00 RO
O
O
0.22
0.000
DC
SH
27:43 RO
2.35
0.76
0.969
DC
SN
27:50 RO
0.97
0.54
0.973
DC
SH
27:53 RO
0.82
0.25
0.974
DC
SH
28:05 RO
2.41
0.38
0.981
DC
SN
28:25 RO
0.52
0.25
0.993
DC
SH
28:27
1.19
1.64
0.994
DC
SH
28:35 RO
0.61
0.34
0.999 123678-HxCDF
MM
DC
SN
28:39 RO
2.09
0.76
1.001
DC
SN
28:46 RO
0.96
0.85
1.005
DC
SH
28:50 RO
0.61
0.20
1.008
DC
SH
28:57 RO
2.00
0.85
1.012
DC
SN
29:02
1.34
1.66
1.015
DC
SH
29:09
1.38
1.14
1.019 234678-HxCDF
AN
DC
SN
29:22 RO
2.17
0.52
1.026
DC
SH
29:31 RO
2.16
0.72
1.031
DC
SH
29:37 RO
1.50
0.99
1.035
DC
SN
29:43 RO
2.24
0.74
1.038
DC
SH
29:50 RO
1.52
0.56
1.043 123789-HxCSF
AH
DC
SN
29:54
1.36
0.33
1.045
DC
SH
29:56 RO
2.89
0.40
1.046
DC
WH
30:13 RO
0.65
0.78
1.056
DC
WH
30:25 RO
2.13
0.36
1.063
0
Faaks
0.00
0.
43-0.59
0.860-1.140
DC
NL
0:00 RO
0.31
1.07
0.000
DC
SH
27:45 RO
0.93
0.41
0.970
DC
SN
27:51 RO
1.47
0.48
0.973
28:31
0.50
665.47
222.20
443.27
0.997 13C12-HXC0F 478
SOK3
28:37
0.50
752.25
249.87
502.38
1.000 13C12-HXCIJF 678
IS4
28:50 RO
0.67
4.82
2.13
3.19
1.008
29:08
0.54
664.05
231.67
432.38
1.018 13C12-HXCBF 234
ALT2
DC
SH
29:18 RO
1.27
1.99
1.024
DC
SN
29:31 RO
0.23
0.68
1.031
DC
SH
29:36 RO
0.21
1.30
1.034
29:50
0.51
559.48
189.24
370.24
1.043 13C12-HXCUF 789
ALT1
DC
SN
29:59
0.47
4.72
1.048
DC
SH
30:04 RO
0.20
1.04
1.051
DC
SN
30:14 RO
0.21
0.71
1.056
5
Paaks
2,646.07
: HxCDF /
HxCDD Follows
HxCDD
1.
05-1.43
0.952-1.015
390-392
DC
HI.
0:00
1.20
0.22
0.000
DC
SN
28:05
RO
0.04
0.04
0.958
DC
SN
28:23
RO
0.41
0.29
0.968
DC
SN
28:27
RO
0.27
0.20
0.970
Triangle Laboratories, Inc.® Analytical Services Division
801 Capttola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 06:47 09/05/97
-------
Pago No. 5 Listing o£ S975665B.db£ ""
09/05/97 KaCcbvd OC Peaks / Ratio / R«t. Tin*
Compound/
M_Z QC.Log Omie Mby ..RT. OK Raeio Total.Area... Area.Peak.l, . Ar»a.Paak.2.. Rel.RT Compound.Naae.. ID.. Flags.
DC
SN
28:42
RO
0.95
0.67
0.979
DC
SN
28:45
1.20
0,33
0.981
DC
SN
28:49
RO
2.33
0.27
0.983
DC
SN
28:56
RO
0.49
0.61
0.987
DC
SH
29:07
RO
2.15
1.77
0.993
DC
SH
29:14
1.43
0.68
0.997
123478-HxCDD
AN
DC
SN
29:21
RO
-0.70
0.89
1.001
123678-HxCDD
AN
DC
SN
29:27
RO
6.09
0.25
1.005
DC
SN
29:37
RO
3.26
1.03
1.010
123789-HxCDD
AN
DC
WH
0
30:01
Peaks
RO
0.20
0.40
0.00
1.024
13C12-HXCDD
402-404
402-404
1.
05-1.43
0.966-1.034
DC
m
0:00
1.07
0.31
0.000
DC
ML
28:03
RO
3.57
0.78
0.957
DC
ML
28:07
RO
0.90
0.83
0.9S9
DC
SN
28:23
RO
3.46
0.29
0.968
DC
SN
28:29
RO
0.33
0.27
0.972
DC
SH
28:32
SO
2.00
0,43
0.973
DC
SN
28:42
SO
1.86
1.46
0.979
DC
SN
28:46
RO
0.46
0.61
0.981
DC
SN
28:50
RO
2.17
0.81
0.984
DC
SN
28:55
RO
0.92
0.40
0.986
DC
SN
29:02
RO
0.33
0.43
0.990
DC
SN
29:08
1.25
1.19
0.994
29:15
1.23
463.41
255.54
207.87
0.998
13C12-HXC0D
29:19
1.23
538.53
296.86
241.67
1.000
13C12-HXCDD
29:37
1.14
619.42
329.57
289.85
1.010
13C12-HXCDD
DC
SN
29:46
RO
1.46
3.79
1.015
DC
SN
3
30:08
Peaks
RO
0.35
0.72
1,621.36
1.028
ES2
Above: HxCDD / HpCDP Follows
HpCDF 0.88-1.20 0.995-1.044
408-410 DC NL 0:00 1.09 0.23 0.000
DC SN 31:51 RO 0.78 1.14 1.018
DC WH 32:47 RO 0.71 0.94 1.048
408-410 0 Peaks 0.00
13C12-HPC0F
0.
37-0.51
418-420
DC
NL
0:00
RO
1.18
0.16
31:17
0.43
443.79
132.62
DC
SN
32:19
RO
3.81
0.62
32:29
0.42
305.19
90.61
DC
SN
32:53
0.48
1.24
418-420
2
Peaks
748.98
HpCDP /
HpCDD Follows
HpCDD
0.
.88-1.20
424-426
OC
NL
0:00
1.00
0.24
0.936-1.128
0.000
311.17 1.000 13C12-HpCBF 678 IS6
1.033
214.58 1.038 13C12-HpCBP 789 STO5
1.051
0.977-1.006
0.000
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 06:47 09/05/97
-------
Page Ho, 6
09/05/97
Listing of S975665B.dbf
Matched GC Peaks / Ratio / Ret. Tin*
compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.l.. Area.Peak.2.. Rel.ST Ccmpound.Name.. ID.. Flags.
DC
SN
31:32
RO
2.46
0.80
0.981
DC
SH
31:38
RO
0.53
0.20
0.984
DC
SH
31:59
RO
2.25
0.49
0.995
DC
WH
32:28
RO
9.67
0.24
1.010
0
Peaks
0.00
13C12-HPCDD
0.
88-1.20
436-438
DC
NL
0:00
1.15
0.28
DC
SH
31:36
RO
2.28
0.37
32:08
1.00
407.59
DC
SH
32:25
RO
1.79
2.04
436-438
1
Peak
407.59
203.54
0.969-1.031
0,000
0.983
204.05 1.000 13C12-HpCDD 678 XS7
1.009
Above: HpCDD / Octa-CDD and CDF Follows
ocdf
442-444
442-444
0.
76-1.02
0.884-1.116
DC
NL
0:00
RO
0.15
0.30
0.000
DC
SH
31:14
0.85
0.72
0.903
DC
SH
31:47
RO
3.05
0.79
0.919
DC
SH
32:06
RO
0.38
0.70
0.928
DC
SN
33:01
SO
0.28
0.83
0.955
DC
SH
33:11
RO
1.16
1.15
0.960
DC
SH
33:19
RO
0.54
0.66
0.963
DC
SN
33:58
RO
0.46
0.76
0.982
DC
SN
34:20
RO
0.16
0.45
0.993
DC
SH
34:45
RO
0.30
1.23
1.005 OCDF
DC
SH
35:31
RO
0.36
1.15
1.027
DC
SH
35:36
RO
1.24
0.70
1.029
DC
SH
35:46
RO
0.61
1.02
1.034
0
Peaks
0.00
AH
OCDD
458-460
458-460
0.76-1.02
DC
DC
DC
DC
NL
SB
SH
SN
0:00
34:26 SO
34:35 RO
34:52
0 Peaks
0.92
1.69
0.29
0.92
0.23
1.23
1.72
0.46
0.00
0.884-1.116
0.000
0.996
1.000 OCDD
1.008
AH
13C12-OCDD
0
76-1.02
0.996-1.006
470-472
DC
HL
0
00
0
92
0.25
0,000
DC
SH
34
28
0
85
1.00
0.997
34
35
0
90
378.26
179.56
198.70 1.000 13C12-OCDD
DC
WH
35
06
RO
1
84
2.12
1.015
470-472
1
Peak
378.26
Triangle Laboratories, Inc.® Analytical Services Division
801 Capttola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 06:47 09/05/97
-------
Page No. 7 Listing of S97S665B.dbf
09/05/97 Matched GC Peaks / Ratio / Ret. Time
Canpound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
Column Description.
"Why* Code Description QC Log Desc.
H_Z -Nominal Ion Hass(esS
. .RT. -Retention Time (nn:ss)
Rat. 1 -Ratio of H/M+2 Ions
OK -RQ=Ratio Outside Limits
Rel. RT-Relative Retention Time
*** End of Report ***
WL-Below Retention Time window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
Fi.le-.S975665 #1-867 Acq:S-SEP-97 05:34:37 EI* Voltage SIR 70S Noise: 84
303.9016 F:2 BSTTB(256, 30, -3. 0) PKD(9, 5 ,5, 0. 05%, 336.0 ,1. 00%,F, T) Exp:EPCOS
TRIANGLE LABS Text:TLI H23 BLANK TLI*42930A INJ. TIME - 05:35
100%
l "i 1 i 1—i—r' 111 ' ' 1——*T
18:00 19:00 20:00 21:00
File:S975665 #1-867 Acq:5-SEP-97 05:34:37 EI* Voltage SIR 70S Noise: 68
305.8987 F:2 BSUB(256, 30,-3\0 ) PKB(9, 5, 5, 0. 05%,272. 0,1.00%,F, T) Exp:EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLI#42930A INJ. TIME - 05:35
100'.
18:00 19:00 20:00 21:00
File: S975665 #1-867 Acq:5-SEP-97 05:34:37 EI* Voltage SIR 70S Noise: 67
315.9419 F:2 BSTJB(256, 30,-3 . 0 ) PKD(9, 5 ,5 , 0. 05%, 268.0 , 1. 00%, F, T) Exp-.EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLI#42930A INJ. TIME = 05:35
1003, A4 . J2E6
80A
603
40j
3.7E3
A2.11E4 Ag^1BE3
A4.85E3
3.0E3
AS. 86
2.2E3
A7.02E3
A1.14E4
3.53E3
1.5E3
7.5E2
0.0 EO
22:00
23:00
2.2E4
1.7E4
1.3E4
A2.31E4
8. 7E3
A2.00E4
A2.30E4
Al.53E4
4.3E3
A1.31
A4.0 5
4.23E3
, 84E
22:00
20j
Oj
18:00 19:00 20:00 21:00 22:00
File: S975665 #1-867 Acq:5-SEP-97 05:34:37 EI* Voltage SIR 70S Noise: 60
317.9389 F:2 BSOB( 256, 30 , -3.0 ) FKD(9 , 5,5, 0. 05%, 240. 0,1.00%,F ,T) Exp-.EPCUS
TRIANGLE LABS Texts2X1 M23 BIANK TLI442930A INJ. TIME = 05:35
100S
80J
soj
40j
2oq
OJ
A6.28E6
18:00 19:00 20:00 21:00
File:S975665 #1-867 Acq:5-SEP-9? 05:34:37 EI* Voltage SIR 70S
330.9792 F:2 Exp-.EPCUS
TRIANGLE LABS Texts Til M23 BLANK TLI#42930A
100.
I '
22:00
INJ. TIME
18:00 19:00 20:00 21:00
File:S975665 #1-867 Acq:5-SEP-97 05:34:37 EI* Voltage SIR 70S
375.8364 F:2 Exp:EPCUS
22:00
TRIANGLE LABS
1001
Text:TLX M23 BLANK TLH42930A
17:56
I 18:h2
JUL^a AJW.
19:01
—Ax—
19:
20:15
20:0
INJ. TIME
20:48
05:35
-Q.QEO
2300 Time
.1 • 1E6
L9.1E5
.6.8E5
.4.5ES
'-2.3ES
.0.0E0
23 : 00
Time
1.6E6
1.3E6
9.4E5
6.3E5
3.1E5
¦.0.0E0
23:00 Time
05:35
1.3E7
1.1E7
7.9E6
5.3E6
2.6E6
10.0E0
23": 00 Time
18100
19:00
20:00
21:00
2. 7E4
2.2E4
1.6E4
1.1E4
22:34
5.4E3
0.0E0
21:12
22:00
23:00
Tuae
-------
File:S975665 #1-867 Acq; S-SEP-97 05:34:37 EI* Voltage SIX 70S Noise: 57
319.8965 F:2 BSUB(256, 30,-3 . 0) PKD( 7, 5, 3, 0 . 05\, 223.0,1.00\, T, T) ExpsEPCUS
TRIANGLE LABS Text.-3X1 M23 BLANK TZI*42930A IN J. TIME = 05:35
19:00 20:00 21:00 22:00
File:S975665 #1-367 Avq:5-SEP-97 05:34:37 EI* Voltage SIR 70S Noise: 64
321,8936 F:2 BSUB(256, 30,-3~.0) PKD(7, 5,3,0.05%, 256.0,1.00%,F, T) Exp-.EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLI442930A INJ. TIME = 05:35
lOOi
A3.59E6
19:00 20:00 21:00 22:00
File:S975665 01-867 Acq:5-SEP-97 05:34:37 EI+ Voltage SIS 70S Noise: 74
333.9338 F:2 BSVB(256, 30, -3.0) PKD ( 7, 5, 3 , 0. 05%, 296. 0,1. 00%, F, T) Exp-.EPCUS
TRIANGLE LABS Text: TLI M23 BLANK TLI04293OA INJ. TIME = 05:35
1003,
80,
60.
40.
20.
AS.19E6
A4.25E6
—
__
J-
-.00
19:00 20:00 21:00 22:
File:S975665 01-867 Acq:5-SEP-97 05:34:37 EI* Voltage SIS 70S Noise: 65
327.8847 F:2 BSUB(256, 30, -3.0) PXD( 7, 5,3, 0. 05%, 260.0,1.00%, F, T) Exp-.EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLI04293OA INJ. TIME = 05:35
1003,
aoj
scj
40j
202
0J
A6..
19:00 20:00 21:00
Flle:S97566S 01-867 Acq.-5-SEP-97 05:34:37 EI* Voltage SIS 70S
330.9792 F:2 Exp;EPCUS
22:00
TRIANGLE LABS
100:
Text: TLI M23 BLANK TLI04293OA
INJ. TIME = 05:35
23:00
19:00 20:00 21:00 22:00
File: S975665 $1-867 Acq: 5-SEP-97 05:34:37 EI* Voltage SIS 70S Noise: 740
331.9368 F:2 BSUB(256,30,-3.0) PKD( 7, 5, 3, 0.05%, 2960.0,1. 00%, F, T) Exp-.EPCUS
TRIANGLE LABS Text: TLI M23 BLANK TLI04293OA INJ. TIME = 05:35
1001
aoj
SOj
ioo:
A8.10E3
38E3
2.66E3
A5.35E3
A3. 74E
74E4
A1. 71E3
A6.60E3 I A9.11E3
23:00
A1.21E4 A8.61E3 A9-°3E3
A1.24E4
4 . 05E3
E3 .A J.93E3lt I\A3.66E3
23:00
23:00
23: 00
¦ 5E6
,2E6
. 8E5
¦ 9E5
.9E5
¦ 0E0
Time
.7E6
. 4E6
. 0E6
.3E5
.4E5
. 0E0
Time
19:00
20:00
21:00
22:00
23:00
-------
File: S975665 01-86 7 Acq:5-SEP-97 05:34:37 EI+ Voltage SIS 70S Noise:81
339.8597 F:2 BSUB( 256, 30,-3. 0 ) PKD( 7, 5 , 3 , 0. 05%, 324 . 0 , 1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:IXJ M23 BLANK TLI*42930A INJ~. TIME - 05:35
1003,
23:00 24:00 25:00 26:00
File:S975665 *1-867 Acq:5-SEP-97 05:34:37 EI+ Voltage SIS 70S Noise:67
341.8567 F:2 BSUB(256, 30, -3~. 0) PKD(7, 5,3,0.05%, 268.0,1.00%, F,T) Exp:EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLI*42930A JNJ". TIME = 05:35
23:00 24:00 25:00 26:00
File: S975665 *1-867 Acq:5-SEP-97 05:34:37 EI+ Voltage SIS 70S Noise: 75
351.9000 F:2 BSUB(256, 30, -3 . 0) PKD( 7, 5, 3, 0 . 05%, 300. 0, 1. 00%,F, T) Exp:EPCUS
TRIANGLE LABS Text: TLI M23 BLANK TLI#42930A IN J. TIME = 05:35
9.3E3
p.7.4E3
A8. 74E3
A4.48E3
3.7E3
A4.25E3
A3.9S
A4.28E3
A1L22E3
A9.26E3
A6.66E3
2.64E3
1.9E3
5. 68E3II '. . .
0.0E0
27:00
1.7E4
1003
A2.11E4
A1.17E4
L. 1. 0E4
A2.00E4
A3. 61E4
S.7E3
A1.11E4
A1.04E4
A6.28E3
A1.4 6E4
3.3E3
tO.OEO
27: 00
1001
80.
60.
40.
20.
0.
AS.
Q1E6
A4.53E6
L
23:00 24:00 25:00 26:00
File:S975665 *1-867 Acq:5-SEP-97 05:34:37 EI+ Voltage SIR 70S Noise: 64
353.8970 F:2 BSUB(256, 30,-3 . 0) PKD(7, 5,3,0 . 05%,256. 0, 1. 00%,F, T) Exp:EPCUS
TRIANGLE LABS Text: TLI M23 BLANK TLI *4293 OA IN J. TIME = 05:35
27: 00
I. 5E6
LI.2E6
f.9.1E5
t
6.0E5
^.3 . 0E5
J.0.0E0
Time
1001
80.
60.
40.
20.
0.
A3.Q7E6
A2. 75E6
23:00 24:00 25:00
File:S975665 #1-867 Acq:5-SEP-97 05:34:37 EI+ Voltage SIR 70S
330.9792 F:2 Exp:EPCOS
TRIANGLE LABS Text: TLI M23 BLANK TLI*42930A INJ. TIME
1001 25:21
80!
60.
401
201
0.
26: 00
27: 00
9.1E5
7.3E5
3.6E5
1.8E5
0.0E0
05:35
26:00 26:17
25:36
25:05
24:22 24:42
23:59
23:26
23:05
23:00 24:00 25:00
File:S975665 *1-867 Acq:5-SEP-97 05:34:37 EI+ Voltage SIR 70S
409.7974 F:2 Exp:EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLI*4293OA
1003,
24:20
26:00
27:00
80.
601
40.
20.
INJ. TIME =
25:30
23:18
24 s m
25:00
22:50
24:36
2300
rta.
05:35
26:08
26:31
24:00
25:00
26:00
27:01
27:00
1.9E7
1. 5E7
1.1E7
7.4E6
3. 7E6
0.0E0
Time
.1. 6E4
.1. 3E4
.9.4E3
.6.3E3
.3. 1E3
.0.0E0
Time
-------
Fxle:S9?5S65
-------
File:S975665 #1-425 Acq:5-SEP-97 05:34:37 EI+ Voltage SIR 70S Noise:61
373.8208 F: 3 BSUB( 256 , 30 , -3 .0 ) PKD( 7, 5, 3, 0. 05%, 244. 0, 1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLI04293OA IN J. TIME » 05:35
1001,
80.
60.
40.
201
A8.88E3
ifowr A>*
A7.64E3 A6.32E3
8.8E4
7.0E4
5.3E4
3.5E4
II. 8E4
A7.40E3
i*W| tOA, pi«i fy? iT> i I1"1! i fli
A5.54E3
c* i
O.OEO
i i i i | t hi i | i"i 'i^ if f i ^ i .'i i iWriTi 'Pi I PV i'tK [ i i i i i | * i i i i ; i i i i i I i i j i i | i i i i i | i i i i i | i i i ; i . i i i i i |
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 Time
File:S975665 #1-425 Acq:5-SEP-97 05:34:37 EI+ Voltage SIR 70S Noise:62
375.8178 F:3 BSUB(256, 30, -3~. 0) PKD( 7, 5, 3, 0. 05%, 248. 0, 1. 00%, F, T) Exp-.EPCCS
TRIANGLE LABS Text: TLI M23 BLANK TLI04293OA IN J. TIME = 05:35
100% r.2.1E5
801
601
401
201
i i i I i i i i i I i ^ i i i i'v i ^ i r ¦ i i ri i | i 1 i*i i , i i 'i i i i i i i 'i 1 *i ¦) P i i p i1 i i i i i'| i i i t i | i i f ^ r | f i i i i | i i ¦! i i | i i i i
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
L1. 6E5
'.1.2E5
L8.2E4
L4.1E4
O.OEO
Time
File:S975665 #1-425 Acq:5-SEP-97 05:34:37 EI+ Voltage SIR 70S Noiae:178
383.8639 F:3 BSUB(256, 30 , -3 . 0 ) PKD( 7, 5,3, 0. 05%, 712. 0, 1. 00%, F, T) Exp:EPCVS
TRIANGLE LABS
1004
801
601
Text: TLI M23 BLANK
40.
20.
TLI*42930A
A2.50E6
IN J. TIME =
A2.32E6
05:35
A1.89E6
.9. 4E5
.7.5E5
.5.6E5
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
I.
8E5
9E5
OEO
Time
File: S975665 #1-425 Acq: 5-SEP-97 05:34:37 EI+ Voltage SIR 70S Noise:592
385.8610 F: 3 BSUB(256 , 30 , -3 . 0 ) PKD( 7, 5 , 3, 0. 05%, 2368. 0 , 1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS
100%
80.
Text: TLI M23 BLANK
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
File:S975665 #1-425 Acq:5-SEP-97 05:34:37 EI+ Voltage SIR 70S
392.9760 F:3 Exp:EPCUS
TRIANGLE LABS Text: TLI M23 BLANK TLI #4293 OA IN J. TIME ' 05:35
100%
60.
40.
20.
0.
TLI #4293 OA
A5.Q2E6
' ' I ' '
-r
INJ. TIME
A4.32E6
05:35
A3.70E6
. 7E6
. 4E6
.0E6
. 9E5
. 5E5
.OEO
Time
30:2
29:47 29:58
29:10
28:03
28:22
28:41
27:43
I ' 1 ' ' ' I 1 1 1 ' 1 I ' 1 1 ' 1 I ' 1 ' ' ' I ' 1 1 ' ' I ' 1 ' 1 1 I I ' i ' ' ' I 1 i ' ' 1 I i ' ' ' 1 I ' 1 ' i ' I 1 ' ' ' 1 I 1 1 ' ' ' I i ' ' ' ' I
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
File:S975665 #1-425 Acq:5-SEP-97 05:34:37 EI+ Voltage SIR 70S
445.7555 F-.3 Exp:EPCUS
TRIANGLE LABS Text: TLI M23 BLANK TLI§4293OA
100%
INJ. TIME =
05:35
80.
601
401
201
01
29:05
28:23
28:37
28:59
27:50 28:02
27:3
29:26 29:44 30:01 -3
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
. 6E4
. 3E4
. 7E3
. 5E3
.2E3
.OEO
Time
-------
File:S975SS5 41-425 Acq:5-SEP-97 05:34:37 EI* Voltage SIS 70S Noise: 58
389. 8156 F:3 BSUB(256, 30,-3.0} PKD( 7, 5, 3, 0. 05%, 232. 0,1.00%,F,T) EXpsEPCUS
TRIANGLE LASS Text: TLX M23 BLANK TLX #4293OA IKT. TIME = 05:35
ioo:|
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48
File:S975665 #1-425 Acq: 5-SEP-97 05:34:37 Eli- Voltage SIX 70S Noise: 52
391.8127 F: 3 BSUB(256,30, -3.0) PKD( 7, 5, 3, 0 . 05\, 208 . 0,1. 00%, F, T) Exp:EPCUS
A1.50E4
1.2E4
9.9E3
7.4E3
A9.59E3
A1. 70E4
A6.85E3
4.9E3
A3.42E3
.27E
2.5E3
30:00
TRIANGLE LABS
iooa
Text:TLI M23 BLANK
TLM42930A
A5,OOE3
INJ-. TIME
05:35
6.9E3
5. 5E3
A7.93E3
AS.10E3
A7.65E3
4.1E3
A4.07E3
A1.17E4
A6.89E3
A1.4 7E3
2.8E3
A7.04E3
A4.93E3
A3.1
A2i 81E
1.4E3
O.OEO
30:00
Txme
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:
File: S975665 #1-425 Acq:5-SEP-97 05:34:37 EI+ Voltage SIR 70S Noise: 81
401.8558 F:3 BSUB( 256, 30, -3 . 0 ) PKS(7, 5,3,0. 05%, 324 .0,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text: TLX M23 BLANK TLI#42930A INJ. TIME «
1003,
80J
A2.97E6
A3.
203
05:35
30E6
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36
File: S97S665 *1-425 Acq:5-SEP-97 05:34:37 EI+ Voltage SIR 70S Noise: 74
403.8529 F:3 BSUB( 256, 30,-3. 0 ) PKZ>( 7, 5 , 3 , 0. 05%,296. 0 , 1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLI04293OA INJ. TIME = 05:35
29:48
30:00
100%
80.
60.
40.
20.
A2.90E6
A2.42E6
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24
File:S975665 #1-425 Acq:5-SEP-97 05:34:37 EI+ Voltage SIS 70S
392.9760 F:3 Exp:EPCBS
TRIANGLE LABS Text:TLI M23 BLANK TLIH42930A INJ. TIME
100%
80.
601
40.
20.
29:36 29:48
05:35
30:00
29:58
.1.2E6
.9.5E5
.7.1E5
.4.8E5
.2.4E5
.O.OEO
Time
.1. 0E6
.8.3E5
.6.2E5
.4.1E5
.2.1E5
.O.OEO
Time
.8.9E6
.7.1E6
.5. 3E6
13. 5E6
11.8E6
28:00
28:12 28:24 28:36 28:48 29:00
29:12
29:24
29:36 29:48
30:00
.O.OEO
Time
-------
File :S9 75665 *1-391 Acq:5-SEP-97 05:34:3 7 EI+ Voltage SIR 70S Noiae:58
407.7818 F:4 BSUB(256, 30,-3 . 0 ) PKD( 7,5,3,0. 05%,232. 0 , 1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text: 2X1 M23 BLANK TLI*42930A IN J. TIME ' 05:35
1003,
A1.S4E4
A1.04E4
1.34E4
A4.75E3
A1.18E4
A7.56E3
A9.70E3 A5.08E3
, i i i *"i i i i i ^ i" f ' i >*'~r r i 'T' ' >'T|f
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
File:S975665 #1-391 Acq:5-SEP-97 05:34:37 EI+ Voltage SIX 70S Noiae:54
409.7789 F:4 BSUB(256, 30, -3~. 0) PKD( 7, 5, 3, 0. 05%,216. 0, 1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLI*42930A INJ. TIME = 05:35
100%
32:48
33:00
A7. 75E3
A7.43E3
A4.25E3
A7.18E3
A3.88E3 A3.29E3
A2.94E3
i i i i i i
31:36
32:48
33:00
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
File:S975665 #1-391 Acq:5-SEP-97 05:34:37 EH- Voltage SIR 70S Noise:67
417.8253 F:4 BSUB( 256, 30 , -3.0) PKD(7, 5, 3, 0 . 05%, 268. 0, 1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLIS42930A INJ. TIME = 05:35
1003
801
60.
40.
201
Oj
A1.33E6
A9.06E5
31:12 31:24 31:36 31:48 32:00 32:12 32':24 32:36
File:S975665 #1-391 Acq:5-SEP-97 05:34:37 EH- Voltage SIR 70S Noise:56
419.8220 F:4 BSUB(256, 30,-3. 0) PKD(7, 5, 3, 0. 05%, 224 . 0, 1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text-.TLI M23 BLANK TLI#42930A INJ. TIME = 05:35
.3.
.2.
-1.
.9.
±0.
32:48
1003,
80.
601
4ol
201
A3.11E6
A2.15E6
31:12 31:24 31:36 31:48 32:00 32:12
File:S975665 #1-391 Acq:5-SEP-97 05:34:37 EI+ Voltage SIR 70S
430.9729 F:4 Exp: EPCDS
TRIANGLE LABS Text:TLI M23 BLANK TLI#42930A INJ.
~r
33:00
1
:.9
Ls
_4
L 2
32:24
TIME
100%
80.
601
401
201
0.
31: 59
32:36
05:35
32:36
32:48
33:00
6.
-4.
-3.
-2.
L i.
x
rr
"T
32:24
31:12 31:24 31:36 31:48 32:00 32:12
File:S975665 #1-391 Acq:5-SEP-97 05:34:37 EI+ Voltage SIR 70S
479.7165 F:4 Exp:EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLI#42930A INJ. TIME
32:36
05:35
32:48
~r
.0.
1003
80.
601
401
201
01
31:51
31:22
31:35
31:47
[aAA.
32:25
32:08
33:00
r-8.
.7.
.5.
8E5
8E5
9E5
¦ 9E5
6E4
¦ 0E0
Time
. 1E6
. 1E5
. 9E5
. 6E5
. 3E5
. 0E0
Time
1E6
9E6
7E6
4E6
2E6
0E0
Time
.3
il
1—i—'—'—1—>—I—i—
31:12 31:24
31:36
31:48
-1—I—r~
32: 00
32:12
32:24
32:36
32:48
• I
33:00
7E3
0E3
.2E3
. 5E3
. 7E3
.0E0
Timel
-------
Fxle:s975655 41-391 Acq:5-SEP-97 05:34:37 EX* Voltage SIR 70s Noise: 61
423.7766 F-.4 BSUB (256, 30, -3, 0 ) PKD( 7, 5, 3, 0. 05%, 244. 0, 1, 00%, F, T) ExpsEPCOS
TRIANGLE LABS Text:TLI M23 BLANK TLI§42930A
1003, A9.S3E3
05:35
lit J. TIME »
7.0E3
A1.16E4
80:
5.6E3
6o:
4.2E3
40:
31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30 32:36
File:S9756S5 *1-391 Acq:5-SEP-97 05:34:37 E1+ Voltage SIX 70S Noise: 58
425.7737 F:4 BSUB(256 , 30,-3.0) PKD(7, 5,3, 0 . 05%, 232. 0, 1. 00%, F, T) ExptEPCOS
. - - - - XXT. TIME =
TSIAJTGLE LABS Text:TLX M23 BLANK TLI#42930A
A2.40E3
05:35
1003
80:
A9.72E3
I A9.17E3
601
11. 9E3
A2.29.
201
A1.93E3
9.5E2
Time
File: S975665 #1-391 Acq:5-SEP-97 05:34:37 EI+ Voltage SIB 70S Noise: 74
435.8169 F:4 BSOB(256, 30,-3 . 0 ) PKD(7, 5,3,0.05%, 296.0, 1.00%, F, T) Exp-.EPCVS
TRIANGLE LABS TextsIXJ M23 BLANK TLI04293OA INJ. TIME = 05:35
1003. A2.04E6
7.7E5
so:
6.1E5
601
4.6E5
401
201
12. 5E5
6.7E5
,5. 0E5
401
3.4E5
11. 7E5
IO.OEO
31:30 31:36 31:42 31:48 31:54 32:00 32:06 32.-12 32:18 32:24 32:30 32:36
-------
File: S975665 #1-391 Acq: 5-SEP-97 05:34:37 EI+ Voltage SIR 70S Noise: 69
441.7429 F: 4 BSUB( 256, 30,-3 . 0 ) PKV(7, 5,3,0.05%, 276.0,1.00%, F,T) Exp:EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLI#42930A INJ. TIME =* 05:35
1001
90.
80.
70.
601
sol
401
30.
20.
10.
0.
32:00 33:00 34:00
File:S9 75665 #1-391 Acq: 5-SEP-97 05:34:37 EI+ Voltage SIR 70S Noi3e:459
443.7399 F:4 BSOB(256, 30,-3 . 0) PKD( 7, 5, 3, 0 . 05%, 1836. 0,1. 00%, F, T) Exp:EPCUS
A6.00E3
08E3
1.07E4
A5.39E3
2.3E4
.2.1E4
1.8E4
.1. 6E4
.1.4E4
L1.1E4
9.2E3
6.9E3
.4.6E3
12.3E3
O.OEO
36:00 Time
TRIANGLE LABS
100%
Text:TLI M23 BLANK TLI04293OA
INJ. TIME
05:35
1.4E4
1.2E4
A1.75E4
9.1E3
A1.40E4
A7.61E3
_7. 6E3
A1.91E4
A1.49 E4
6.1E3
A8.62E3
A7.90E3
4.6E3
7. 80E3
3.0E3
_1. 5E3
O.OEO
32:00 33:00
File:S975665 #1-391 Acq:5-SEP-97 05:34:37 EI+ Voltage SIR
430.9729 F:4 Exp: EPCVS
TRIANGLE LABS Text:TLI M23 BLANK TLI04293OA
35: 00
36:00 Time
INJ. TIME =
05:35
100i
901
801
31:41 31l59 32:19 32'3ttM
33:02
34 : 01 34j23
35:01
35j30, 35.-51,
-6.5E6
-5.9E6
5.2E6
701
4.6E6
601
.3. 9E6
501
3. 3E6
40.
-2.6E6
301
12.0E6
201
-1.3E6
101
.6.5E5
0
» 1 ' 1 ' 1 1 | \ ' ' |
O.OEO
32:00 33:00 34:00 35:00
File: S975665 #1-391 Acq: 5-SEP-97 05:34:37 EI+ Voltage SIR 70S
513.6775 F:4 Exp:EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLI#42930A INJ. TIME = 05:35
32;26 34:53
31:17
2:09
34:41
33 : 08
32:55
14 : 04
34:29
ULj
35:10 35:37
36:00 Time
1.2E4
1.1E4
9.9E3
8.7E3
7.4E3
6.2E3
L 5.0E3
L 3. 7E3
.2.5E3
1.2E3
32:00
33:00
34 : 00
35:00
O.OEO
36:00 Time
-------
File:S975665 *1-391 Acq:5-SEP-97 05:34:37 voltage sir 70s Noise,55
457.7377 F:4 BSX7B(256, 30,-3.0) PKD(7, 5,3, 0. 05%,220. 0 ,1.00%,F,T) Exp: EPCUS
TRIANGLE LABS Text: TLI M23 BLANK TLI04293OA INJ. TIME = 05:35
1004 A8.J.4E3
801
60:
401
201
3.8E3
3.1E3
-2.3E3
A3.14EJ-1_5£3
2.22E3
7.7E2
O.OEO
Tune
34:30 34:36 34:42 34:43 34:54 35:00
File:S975665 #1-391 Acq:5-SEP-97 05:34:37 EI+ Voltage SIR 70S Noise:60
459 . 734 8 F:4 BSUB(256, 30, -3.0) PKD(7, 5, 3, 0. 05%, 240. 0,1. 00%,F, T) Exp:EPCUS
TRIANGLE LABS Text: TLI M23 BLANK TLI#42930A INJ. TIME » 05:35
3S: 06
100$
80.
60.
40.
201
A2.7SE4
Al.22E4
A2.41E3
34:30 34:36 34:42 34:48 34:54 35:00
File:S975665 01-391 Acq:5-SEP-97 05:34:37 EI+ Voltage SIS 70S Noise; 60
469.7779 F:4 BSUB(256, 30,-3.0) PKD(7, 5 , 3 , 0.05%, 240. 0,1.00%,F, T) Exp: EPCUS
TRIANGLE LABS Text:TLI M23 BLANK TLI*42930A INT. TIME = 05:35
lOOi
ao:
60J
40Z
20.
34:30 34:36 34:42 34:48 34:54 35:00
File:S975665 #1-391 Acq:5-SEP-97 05:34:37 EI+ Voltage SIR 70S Noise: 66
471.7750 F: 4 BSCS (256, 30, -3.0) PKD( 7 , 5 , 3 , 0. 05\, 264 . 0,1. 00%, F, T) Exp: EPCUS
TRIANGLE LABS Text: TLI M23 BLANK TLXH2930A INJ. TIME = 05:35
1001
80.
6o:
40J
20L
99E6
34:30 34:36 34': 42 34:48 34:54
File:S975665 §1-391 Acq-. 5-SEP-97 05:34:37 EI* Voltage SIR 70S
430.9729 F:4 Exp:EPCUS
TRIANGLE LABS Text: TLI M23 BLANK TLI*4293 OA INJ. TIME
100% 34:31 3ti37 34:51
80.
60:
40.
201
0.
35:00
05:35
35x01
35: 06
.1.5E4
.1. 2E4
.9. 1E3
.6.1E3
.3. 0E3
.0.0E0
Time
5.SE5
4.4E5
3.3E5
12.2E5
1.1E5
35:06
.0.0E0
Time
6.2E5
15.0E5
3.7E5
2.5E5
L1.2E5
35:06
35:06
10.0E0
Time
r.6.4E6
5.1E6
13.8E6
2.SE6
11.3E6
34:30
34:36
34:42
34:48
34:54
35:00
35:06
.0.0E0
Time
-------
58
58
i
1
1
J
L
r
111
mmBE
Channel I 338.9792 Peak top
Height 3.25 volts Spar 290 pea
Systea file nae
Data file rate
Resolution
Group nuaber
Ionization node
Switching
Ref. «asses 292.9825,
ft 293 J 331
B 384
C 386
D 316
E 318
F 328
6 322
H 328
I 331
K 332
L 334
« 348
N 342
0 352
P 354
Q 356
R 358
EPOJS2
18688
2
EI*
VOLM
416.9768
S 368
T 378
U 376
V 418
Ref. tass 416.9768 Peak top
Height .96 wits Span 289 ppi
-------
TLI Project: 42930A Method 23 PCDD/PCDF Analysis (a)
Client Sample: RUN1 Analysis File: S975666
Client Project:
Iron & Steel-Youngstown
Sample Matrix:
M23TRAIN
Date Received: 08/19/97
Spike File:
SPX23704
TLI ID:
179-98-1A-D
Date Extracted: 08/25/97
ICal:
SF56117
-
Date Analyzed: 09/05/97
ConCal:
S975664
Sample Size:
1.000
Dilution Factor: n/a
% Moisture
: n/a
Dry Weight:
n/a
Blank File: S975665
% Lipid:
n/a
GC Column:
DB-5
Analyst: HLM
% Solids:
n/a
Analytes
Amt. (tig) DL EMPC
Ratio
RT
Flags
2,3,7,8-TCDD
0.62
0.87
21:48
1,2,3,7,8-PeCDD
1.7
1.42
26:13
1,2,3.4,7,8-HxCDD
0.38
1.13
29:21
1,2,3.6,7.8-HxCDD
3.8
1.20
29:26
1.2,3,7.8,9-HxCDD
1.6
1.17
29:44
PR_
1,2,3,4.6,7,8-HpCDD
1.8
1.01
32:12
1,2,3,4,6,7,8,9-OCDD
0.96
0.86
34:40
2,3,7,8-TCDF
50.2
0.85
21:04
1.2,3,7,8-PeCDF
6.7
1.47
25:08
2,3,4,7,8-PeCDF
6.9
1.47
25:52
1,2,3,4,7,8-HxCDF
3.9
1.30
28:37
PR_
1,2,3,6.7,8-HxCDF
1.4
1.16
28:44
2,3,4.6,7.8-HxCDF
0.88
1.17
29:14
PR_
1.2.3.7.8,9-HxCDF
0.10
1.30
29:56
1,2,3,4,6,7,8-HpCDF
0.88
1.01
31:22
—_
1,2,3,4,7,8,9-HpCDF
ND 0.2
1,2,3,4,6,7,8,9-OCDF
ND 0.4
Total TCDD
15.1 12 15.3
Total PeCDD
13.8 6 20.3
Total HxCDD
33.9 6 34.4
Total HpCDD
5.5 2
—
Total TCDF
413 14 426
Total PeCDF
100 13 102
Total HxCDF
16.1 13
Total HpCDF
1.2 2 1.4
Page 1 of 2 X237.PSR viOO, LARS 6.loot
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
-------
TLI Project: 42930A Method 23 PCDD/PCDF Analysis (a)
Client Sample: RUN1 Analysis File: S975666
Internal Standards
Amt {ng)
% Recovery
QC Limits
Ratio
RT
Flags
3Cn-2.3,7,8-TCDF
3.7
92.9
40%-130%
0.74
21:02
3Cir2,3,7,8-TCDD
3.4
85.1
40%-130%
0.83
21:47
3Ci:-l,2.3.7,8-PeCDF
2.4
59.7
40%-130%
1.75
25:07
3C,:-1.2.3,7,8-PeCDD
2.0
49,4
40%-130%
1.49
26:13
5C;:-1,2.3.6,7,8-HxCDF
4.4
111
40%-130%
0.52
28:44
3Ci;-l,2.3,6,7,8-HxCDD
3.8
95.4
40%-130%
1.26
29:25
3Cn-1.2.3.4.6.7,8-HpCDF
2.6
65.0
25%-130%
0.42
31:22
JCi2-1.2,3,4,6,7,8-HpCDD
2.8
68.9
25%-130%
0.98
32:12
3C)2-1,2,3,4,6,7,8.9-OCDD
4.2
52.0
25%-130%
0.91
34:39
—
Surrogate Standards {Type A)
Amt. (ng)
% Recovery
QC Limits
Ratio
RT
Flags
i7CL-2,3,7,8-TCDD
4.0
100
70%-140%
21:48
13C, 2-2,3,4.7,8-PeCDF
3.3
81.8
70%-140%
1.55
25:51
,3C,;-1.2.3,4,7.8-HxCDF
4.2
105
70%-140%
0.49
28:37
,3Cu-1,2.3.4,7,8-HxCDD
4.1
103
70%-140%
1.12
29:21
l3Ctrl,2,3,4,7,8»9-HpCDF
4.0
100
70%-140%
0.42
32:33
—
Alternate Standards (Type A)
Amt. (ng)
% Recovery
QC Limits
Ratio
RT
Flags
13Ci2-l,2.3,7,8.9-HxCDF
3.9
97.9
40%-130%
0.53
29:56
l3Ci2-2,3,4,6,7,8-HxCDF
4.0
100
40%-130%
0.51
29:13
—
Recovery Standards
Ratio
RT
Flags
l3Ci2-l,2,3,4-TCDD
0.81
21:35
13Ci2-l,2,3,7,8,9-HxCDD
1.21
29:43
Data Reviewer SLi -Lxoa 09/08/97
Page 2 of 2 jcot.psr vioo. lars s.io.m
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:31 09/08/97
-------
Initial .... Date...
Data Review 3y: Calculated Noise Area: 4. 62
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
09/08/97
Listing of S975666B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit
Why
. .RT.
OK
Ratio Total.Area...
Area.Peak.1..
Area.Peak.2..
Rel.RT Compound.
TCDF
0.
65-0.89
0.327-1.099
304-306 DC
NL
0
00
RO
0.36
14.16
0.000
A
17
45
0.34
7,040.00
3,220.00
3,820.00
0.844
18
13
SO
0.91
5,588.74
2.875.45
3,157.48
0.866
18
29
0.85
3.434.59
1,582.27
1,852.32
0.879
18
54
0.84
35.372.20
16,176.90
19.195.30
0.399
19
11
0.34
23,969.40
10,962.00
13,007.40
0,912
19
39
0.86
21,279.35
9,808,65
11,471,20
0.934
19
57
0.84
16,837.37
7,687,04
9,150.33
0.943
20
15
0.85
15,210.15
6,995,27
8,214.38
0.963
20
24
0.84
7,512.73
3.435.39
4,076,34
0.970
20
37
0.85
13,607.09
6,265.33
7,341.26
0.980
20
52
0.33
9,127.91
4,153.41
4.974.50
0.992
21
04
0.35
23.333.70
10,709.50
12 .624 .20
1.002 2378-TCDF
21
30
0.84
9,310.34
4,258.11
5,052.23
1. 022
21
42
0.83
5.218.73
2.365.96
2,352.32
1.032
21
57
RO
1.03
732.02
426.57
413,57
1.044
22
16
RO
1.36
52.92
55. 50
29.90
1.059
22
50
0.83
574.70
260.74
313.96
1. 036
DC
WH
23
08
RO
0.54
24.30
1.100
304-306
17
PeaKs
198,202.49
13C12-TCDF
0
65-0.89
0.
952-1.043
316-313 DC
MX,
0
00
RO
11.99
5.42
0.000
21
02
0.74
1,486.37
630.14
856.73
1.000 13C12-237
ID.. Flags.
AN
316-313
1 Peak
1.486.37
Above: TCDF / TCDD Follows
TCDD
320-322
DC NX.
0.
65-0.89
0.861-1.053
0: 00
RO
7.79
12.39
0.000
19:07
0.76
554.76
239.43
315.28
0.378
19: 31
0.70
344.95
142.05
202.90
0.896
19:49
0.78
333.63
146.27
187.36
0.910
20: 33
0.81
939.89
419.73
520.16
0.943
20:46
0.78
730.00
319.00
411.00
0. 953
21:15
0.86
317.67
147.01
170.66
0.976
21: 32
0.78
412.98
180.58
232.40
0.989
21:41
0.87
413.14
194.47
223.67
0.995
21:48
0.87
203.46
94.54
108.92
1.001 2378-TCDD
21:57
0.77
158.63
69.22
89.41
1.008
22:08
0.78
385.23
168.48
216.75
1.016
22:21
RO
0.96
88.50
47.80
50.00
1.026
22:49
0.68
141.74
57.22
84,52
1.047
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:32 09/08/97
-------
Page No.
09/08/97
Listing of S975666B.dbf
Matched GC Peaks / Hacio / Ret. Time
Compound/
M_2.... QC.Log Omit
why
. .RT.
OK
Ratio Total
.Area...
Area.Peak.1.. Area.
Peak.2. .
Rel.ST Compound.Name..
320-322
13
Peaks
5.029.58
37C1-TCDD
0.907-1.093
323 DC
NL
0: 00
2.44
0. 000
DC
WL
18: 32
76.30
0.851
DC
•WL
18:45
2.31
0.861
DC
WL
18:51
-
5.81
0.365
DC
ML
19:05
3 .96
0.876
DC
ML
19:21
2.20
0.888
DC
WL
19: 31
7.16
0.396
20:19
288.08
288.08
0.933
20: 33
11.91
11 .91
0.943
20:44
3.07
3 . 07
0.952
20: 55
2.96
2.96
0. 960
21:17
4.86
4.86
0.977
DC
SN
21: 32
2.47
0.989
21:48
929.31
929.31
1.001 37C1-TCDD
21:58
5.36
5. 36
1. 008
22:13
1,098.66
1,098.66
1.020
DC
SN
22:27
2.08
1,031
22: 35
4.21
4.21
1 . 037
22:44
7.75
7.75
1.044
22:55
20.03
20, 03
1.052
23:10
7.10
7 .10
1. 064
328
12
Peaks
2,383.30
13C12-TCDD
0.
65-0.39
0.907-1.093
332-334 DC
NL
0:00
HO
18.94
0,30
0.000
DC
WL
19:02
RO
11 ."9
1.12
0. 374
DC
SN
20:55
RO
3.99
3.04
0.960
DC
SN
21:15
RO
1. 93
2.80
0.976
21:35
0. 31
1,214.38
542.32
572.06
0.991 13C12-1234-TCDD
21:47
0.33
1,101,99
500.13
601.36
1.000 13C12-2378-TCDD
21:57
RO
1.10
10.11
6.28
5.71
1.008
22:09
RO
1 . 53
17.47
16.10
9.37
1. 017
22:19
RO
0.50
6.05
2.63
4.36
1.024
22:42
RO
0. S3
10.14
4.41
6.95
1.042
22:54
RO
1.59
5.73
5. 14
3.24
1.051
DC
SN
23:03
RO
1.01
4.14
1.058
332-334
7
Peaks
2,365.87
PeCDF Follows -
PeCDF
1.
.32-1.78
0.910-1.076
340-342 DC
NL
0:00
RO
0.16
0.31
0.000
22:52
RO
0. 59
156.59
95.18
161,29
0.910
23:07
1.48
2.773.32
1,656.62
1,116.70
0.920
23:22
RO
0.88
34.52
20. 98
23.89
0.930
23:50
RO
1.23
72.12
43.84
35.54
0.949
24:07
1. SO
1,280.38
768.20
512.63
0.960
24:16
1. 53
7,410.65
4,477.93
2,932.72
0.966
24:26
1.44
1,206.94
711.53
495.41
0.973
SUF.l
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive » Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:32 09/08/97
*
-------
Page No. 3
09/08/97
Listing of S975666B.db£
Matched GC Peaks / Ratio / Sett. Time
Compound/
M_Z .... QC. Log Cir.it Why
¦ RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rei.RT Compound.Name.. ID.. Flags.
A
24:
38
1.47
507.00
302.00
205.00
0,981
24.
53
1.47
2,067.83
1,231.18
836.65
0.991
A
25:
02
1.57
674.00
412.00
262.00
0.997
M
25
08
1.47
1,529.00
911.00
618.00
1.001 12378
25
17
1. 53
964.67
582.90
381.77
1 . 007
25
25
1.46
1,443.93
857.14
586.79
1. 012
25
52
• 1 .47
1,587.90
943.79
644.11
1.030 23478-
26
00
1.47
1.330.46
791,04
539.42
1.035
26
18
RO
1.15
97.20
59.08
51.45
1.047
26
49
1.51
143.51
39.45
59.06
1. 063
340-342
17
Peaks
23,285.52
13C12-PeCDF
1.
32-1.78
0.840-1.160
352-354
DC
NL
0
00
RO
4. 53
0.33
0. 000
DC
SN
22
49
RO
0.59
2.53
0 . 903
DC
SN
23
02
RO
11.74
1.84
0.917
DC
SN
23
44
RO
2.13
2.17
0.945
DC
SN
23
56
RO
4.85
3.67
0. 953
DC
SN
24
17
RO
4.86
3.11
0.967
DC
SN
24
47
RO
2. 59
4,34
0.937
25
07
1.75
321.82
523.50
298.32
1.000 13C12
25
27
RO
3.17
24.45
30. 38
9.59
1. 013
25
51
1.5S
651.34
396.47
255.37
1.029 13C12
DC
SN
26
07
RO
0.51
2.47
1. 040
DC
SN
26
43
1.40
5.63
1.064
26
48
RO
0.72
6.02
3,66
5.09
1. 067
DC
SN
26
59
RO
0.76
3.77
1.074
352-354
4
Peaks
1,504.13
DafTM? /
!
PeCDD r oilows ——¦
PeCDD
1
32-1.78
0.
323-1.025
356-353
DC
NL
0
00
RO
1.93
2.40
0 . 000
24
25
RO
1.31
535.93
325.76
249.37
0 . 931
24
54
1.66
105.35
65.72
39.63
0. 9 50
25
08
1. 66
484.32
302.28
132.04
0. 959
25
15
1 .67
235.60
147.23
88.32
0. 963
25
27
1.63
238.15
147.67
90,48
0.971
25
42
1.46
374.31
222.03
152.23
0.980
25
54
RO
1.04
41.67
25.33
24.35
0.988
26
02
RO
0.22
21.03
12.78
59.05
0. 993
26
13
1.42
209.32
122.71
86.61
1,000 12378
26
21
RO
1.13
90.15
54.80
48.53
1.005
26
43
RO
1.27
88.38
53.72
42.43
1.019
356-358
11
Peaks
2,424.21
13C12-?eCDD
1
32-1.78
0.
347-1.153
363-370
DC
NL
0
00
1.33
0.35
0.000
DC
SN
24
20
RO
2.88
2.09
0.928
DC
SN
24
SO
RO
2.95
2.65
0. 947
DC
SN
25
27
RO
4.72
2.01
0.971
DC
SN
25
55
RO
6. 80
1.38
0.989
AH
AN
•PeCDF 234 SGR2
AM
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 1^09/08/97
-------
Page No. 4
09/03/97
Listing of 3975666B.db£
Hatched GC Peaks / Ratio / Ret. Time
Compound/
QC.Log Omit Why
.RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
368-370
DC
DC
SN
SN
26: 13
1.49
381.09
228.04
153.05
1 . 000
26:20
1.43
42.71
25. 11
17.60
1. 004
26:38
RO
1.18
3.65
1 .016
K>
-J
O
o
RO
0. 50
2.62
1.030
Peaks
423.80
Above: PeCDD / HXCDF Follows
HxCDF
1.
05-1.43
0.957-1.051
374-376
DC
NL
0:00
1.25
7.00
0.000
27:40
1.28
208.50
116.93
91 .57
0.963
27:49
1.25
713.45
395.81
317.64
0.963
27:58
1.26
56.52
31.47
25.05
0.973
28:06
1.29
74.39
41.95
32.44
0.973
28:16
1.36
92.94
53.56
39.38
0.984
DC
SN
28:22
1.27
3.40
0. 987
DC
SN
28:27
RO
0.82
2.73
0.990
28:37
1.30
499.32
282.26
217.06
0.996 123473-HxCDF
AM
28:44
1.16
233.25
125.46
107.79
1.000 123678-HxCDF
AN
28: 51
1.07
36.36
18.78
17.58
1. 004
29:02
1. 36
79.95
46.13
33.32
1.010
A
29:11
1.25
42.10
23 .40
18.70
1.016
M
29:14
1.17
115.70
62 . 30
53.40
1.017 234673-HxCDF
AN
AN
29:56
1. 30
11.99
6.77
5.22
1.042 123789-HxCDF
AN
M
30: 00
1 .25
31.00
17.20
13.30
1.044
374-376
13
Peaks
2
195.47
13C12-HxCDF
0
43-0.59
0.860-1.140
384-386
DC
NL
0:00
RO
0.75
3.82
0.000
DC
SN
27:34
RO
4.33
0.65
0.959
DC
SN
28:30
RO
0.70
0.97
0.992
28:37
0.49
425.64
140.73
284.91
0.996 13C12-HXCDF 478
SUR3
28:44
0.52
423.47
145.54
277,93
1.000 13C12-HXCDF 678
XS4
DC
SN
29:03
RO
2.15
1.21
1.011
29: 13
0. 51
354,48
119.39
235.09
1.017 13C12-HXCDF 234
ALT2
DC
SN
29:23
RO
1.17
2.07
1.023
DC
SN
29:32
0.52
4.31
1.028
29:56
0.53
300.55
103.93
196.62
1.042 13C12-HXCDF 789
ALT1
DC
SN
30:07
RO
1.48
1.24
1.043
DC
SN
30:12
0.59
2.41
1.051
DC
SN
30:17
RO
2.54
1.68
1.054
DC
SN
30:20
RO
1.76
0.74
1.056
384-386
4
Peaks
1
,504.14
PR
PR
Above: HXCDF / HxCDD Follows
HxCDD
1.05-1.43
0.
952-1.015
390-392 DC
NL
0:00
1.31
3.97
0.000
28:11
1.22
464.15
254.92
209.23
0.958
DC
SN
28:19
1.40
2.11
0.963
DC
SN
28:25
RO 1. 88
1.43
0.966
28:38
1.29
123.36
69.52
53.84
0.973
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:32 09/08/9]
-------
Page No. 5
09/08/97
Listing of S975666B.db£
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log
Omit
Why
. -RT.
OK
Ratio Total
.Area... Area
Peak.1.. Area
Peak.2..
Rel.RT
Compound.Name. .
ID. .
28: 51
1.21
1.654.72
904.43
750.29
0. 981
28:59
RO
0.95
35.61
19 .71
20.75
0.985
AN
29:21
1.13
26.90
14.30
12 .60
0.998
123473-HXCDD
AM
M
29 = 26
1.20
324.00
177.00
147.00
1.001
123678-HxCDD
AN
29:44
1.17
128.03
69.01
59.02
1. 011
123739-HxCDD
AN
DC
SN
29:50
RO
0.92
2.19
1 . 014
390-392
7
Peaks
-
2,756.77
13C12-HxCDD
1
05-1.43
0.966-1.034
402-404
DC
NL
0:00
RO
0. 11
0.40
0. 000
DC
WL
28:01
RO
0.42
0.76
0.952
DC
ML
28:17
RO
1.87
1.01
0. 961
DC
SN
28:46
RO
0.36
1.48
0.978
DC
SN
28:50
RO
0.73
1.90
0.980
DC
SN
28:55
RO
0.41
1.41
0,983
29:21
1.12
301.02
153.81
142.21
0.998
13C12-HXCDD 478
STO4
29:25
1.26
300.70
167.56
133 .14
1.000
13C12-HXCDD 678
ISS
29:43
1.21
316.78
173.22
143.56
1. 010
13C12-HXCDD 789
SS2
DC
SN
30:02
1.24
2.02
1.021
DC
SN
30:08
RO
2.23
1.38
1.024
402-404
3
Peaks
918.50
Flags-
PR
Above: HxCDD / HpCDF Follows
HpCDF
0
88-1.20
403-410
DC
NL
0
00
RO
2. 39
M
31
22
1. 01
M
31
35
RO
1.61
M
31
43
1 . 07
D
DC
SN
32
32
1.16
DC
WH
33
02
RO
2.23
408-410
3
Peaks
1.96
62.20
8.45
21.70
6.37
0.90
92.35
31,20
6.68
11.20
0.995-1.044
0.000
31.00 1.000 1234678-HpCDF AN
4.14 1.007
10.50 1.011
1.037 1234739-HpCDF AN
1.053
13C12-HpCDF
418-420
418-420
DC NL
DC SN
0.37-0.51
0 .
936-1.128
0:00
RO 0.96
1.67
0. 000
31:22
0.42
182.62
54.09
128.53
1.000 13C12-HOCDF
578
IS6
31:50
RO 1,32
1.05
1.015
32: 33
0.42
140.94
41. 53
99.41
1.038 13C12-HpCDF
789
SUB 5
Peaks
323.56
HpCDD
Above: HpCDF / HpCDD Follows
0.88-1.20
0.977-1.006
424-426
DC
NL
0:00
RO
7.82
0.22
0.000
31: 37
1.02
175.93
88.87
87.06 0.982
32:12
1.01
83.75
41.98
41.77 1.000 1234678
DC
SN
32:23
RO
0.30
0.59
1.006
424-426
2
Peaks
259.68
13C12-HpCDD
0
0
rs
H
1
CO
CO
0.969-1.031
436-438
DC
NL
0:00
RO
1.21
0.29
0.000
DC
SN
31:53
RO
7.62
0.43
0.990
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:32 09/0°'
-------
Page No.
09/08/97
Listing of S975666B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omit Why .-RT, OK Ratio Total.Area.
Area.Peak.1.. Area. Peak.2.. Rel.RT Compound,Name.. ID.. Flags.
436-438
32:12 0.98
DC SN 32:30 RO 1.67
DC SN 32:39 RO 3.76
1 Peak
177.80
1.12
0.59
177.80
38.15
89.65 1.000 13C12-HpCDD 678 IS7
1.009
1. 014
Above: HpCDD / Octa-CDD and CDF Follows
OCDF
0.
76-1.02
0.884-1.116
442-444
DC
NL
0:00
RO
0. 15
0.21
0.000
DC
SN
31:28
RO
0.60
0.53
0.908
DC
SN
31:28
RO
0.48
0.28
0.908
DC
SN
31:39
RO
1.70
1.30
0,913
DC
SN
32:00
RO
0. 58
1.27
0,924
DC
SN
32:07
RO
0.62
0.89
0.927
DC
SN
32: 32
RO
1.18
1.97
0.939
DC
SN
33:24
RO
4.00
0.57
0.964
DC
SN
33:42
RO
0.31
1.42
0.973
DC
SN
33:51
RO
0.51
1.17
0. 977
DC
SN
34:10
RO
1.38
1.46
0. 986
DC
SN
34:32
RO
2.54
0,49
0. 997
DC
SN
34: 35
0.90
1.37
0.998
D
DC
SN
34:49
1 . 02
7.45
1.005 OCDF
DC
SN
35:03
RO
11.45
0.21
1, 014
DC
SN
35: 34
RO
0.46
1.40
1 .026
DC
SN
35:43
RO
0.28
0 .74
1.031
DC
SN
35:57
0.95
2.60
1.033
442-444
0
Peaks
0.00
OCDD
0.
.76-1.02
0.834-1.116
453-460
DC
NL
0:00
RO
1.17
0.23
0.000
34:40
0.36
22.65
10.46
12.19 1.000 OCDD
453-460
1
Peak
22,65
13C12-OCDD
0
.76-1.02
0.996-1.006
470-472
DC
NL
0:00
1.00
0.24
0.000
34: 39
0.91
170.87
81.58
89.29 1.000 13C12
470-472
i
Peak
170.87
AN
AH
:ss
Column Description.
"Why" Code Description QC Log Desc.
M.
Z -Nominal Ion Mass(es!
. .RT. -Retention Time {mm:ss)
Rat. 1 -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Tin® Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
801
LI. 9E6
-1.4E6
.9. 7E5
14.8E5
A4.94E5
O.OEO
18:00
File:S975666 #1-867 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
330.9792 7:2 Exp-.EPCUS
TRIANGLE LABS Text:RUN 1 TLI#42930A
100S, 17:25
Time
19:00
21:00
20: 00
22:00
23:00
06:14
21jl9 21:44
INJ. TIME
18:10
22
22:50
J1.8E7
19:44
18:43
JtO:21
1.4E7
801
601
-1.1E7
13.5E6
801
-2.1E4
22:38
601
11. 6E4
11:38
401
-1. 0E4
17:45
18:58
20:25
20:5:
19:48
18:25
201
19:2
18:12.
od.
O.OEO
18: 00
19:00
20:00
21: 00
22:00
23 : 00
-------
Tile-. S975666 01-867 Acq:5-SEP-97 06:12:18 EX* Voltage SIS 70S Noise:27267
319.8965 F:2 BSUB(256, 30, -3. 0) PKD(7, 5,3,0 . 05%, 109068. 0 , 1.00%, F, T) Exp:EPCVS
19:00 20:00 21:00 22:00
File:S975666 #1-867 Acq:5-S£P-97 06:12:18 EI+ Voltage SIX 70S Noise:3502
321.8936 t:2 BSUB(256,30, -3.0) PKD( 7, 5,3, 0. 05%, 14008. 0,1. 00%, F,T) Exp:EPCVS
TRIANGLE LABS
1003
Text: SON 1 TLI042930A
A2.39E6
A4 .120E6
INJ. TIME
06:14
A1.42E6
A1.46E6
A1.94E6
A1.18E6
A1.47E6
A1.68E6
6.92E3
A5.72E5
23:00
.1.1E6
.8.9E5
.6.6E5
.4.4E5
-2.2E5
.O.OEO
Time
TRIANGLE LABS
1001
Text:RON 1 TLI04293OA
IN*7. TIME
06:14
A3.15E6
A2.03E6
3.97E6
A2.24E6 A2.17E6
18.94E.
4 .95E5
/\ ,
19:00 20:00 21:00 22:00
File:S975666 #1-867 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S Noise: 1612
331.9368 F:2 BSUB(256, 30,-3 .0) PKD( 7,5,3,0.05%, 6448.0,1. 00%, F,T) Exp-.EPCUS
TRIANGLE LABS Text:RON 1 TLI#4293OA INJ. TIME » 06:14
A8.45E5
1001
80J
60A
40-
20J
A5.42E6
fiAS.OOES
LXL
. " l " f I i i * " I I "l * ' 'I I 1 i
19:00 20:00 21:00 22:00
File: S975666 01-867 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S Noise: 87
333.9338 F:2 BSUB(256, 30,-3.0 ) PKD(7, 5 , 3 , 0.05%, 348. 0 , 1.00%,F,T) Exp-.EPCUS
TRIANGLE LABS Text .-RUN 1 TLI04293OA INJ. TIME •
06:14
1001
80A
50j
403
20J
A6.02E6
rr
-r
r-
19:00 20:00 21:00 22:00
File:S975666 01-867 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S Noise: 1221
327.8847 F-.2 BSUB(256, 30,-3. 0) PKD(7, 5,3,0.05%, 4884. 0,1. 00%, F,T) Exp:EPCVS
TRIANGLE LABS Text:RON 1 TLI04293OA INJ. TIME « 06:14
1001
A1.10E7
A9.29E6
A2.88E6
A ,
/ v
19:00
20:00
21:00
22:00
1.3E6
1.0E6
7.8E5
5.2E5
23:00
rl. 4E6
Li.iE6
p.5. 7E5
L2.9E5
¦ I E " trn
23:00 Time
.1.8E6
11. 5E6
'.1.1E6
.7.4E5
13. 7E5
-0.0E0
Time
23 s 00
_3.6E6
'.2.9E6
.2.2E6
'.1.5E6
.7.3E5
19:00 20:00 21:00 22:00
File:S975666 #1-867 Acq:5-SEP-97 06:12:18 EI+ Voltage SIS 70S
330.9792 F-.2 Exp-.EPCUS
TRIANGLE LABS Text:SON 1 TLI042930A INJ. TIME = 06:14
1001
.O.OEO
23 i- 00 Time
1.8E7
1.4E7
1.1E7
7.1E6
3.5E6
.0.0E0
23:00 Time
-------
23:00
File:S975666 #1-867 Acq:5-
351.9000 F:2 BSUB(256,30,¦
TRIANGLE LABS Text:RUN 1
1004
80J
50j
4ol
2o\
"J .
File:S975666 #1-867 Acq:5-
339.8597 F:2 BSUB(256,30,¦
TRIANGLE LABS TextzRUN 1
1004
80.
60.
4 0.
2 OS.
SEP-97 06:12:18 EI+ Voltage SIR 70S Noise:93
3.0) PKD(7,5,3,0.05%,372.0,1.00%,F,T) Exp:EPCUS
TLI»42930A . INJ. TIME = 06:14
A4.48E7
A1.66E7
23: 00
File: S975666 *1-867 Acq:5-
341.8567 F:2 BSUB(256,30,¦
TRIANGLE LABS Text:RON 1
1004
7.12E6
A1.30E7
A1.2JE7
A9.44E6
9.9E6
L 7.9E6
15.9E6
.4 . 0E6
12. 0E6
801
601
4 0.
201
24:00 25:00 26:00
SEP-97 06:12:18 EI+ Voltage SIR 70S Noise: 606
3'.0) PKD(7, 5,3, 0. 05%,2424 . 0,1. 00%, F, T) Exp:EPCUS
TLI#42930A INJ. TIME = 06:14
A2.93E7
27: 00
O.OEO
Time
A1.12E7
M
.4 .95E6
A8.74E6
A8.37E6
A6.44E6
K'AAAA a a
24:00 25:00 26:00
SEP-97 06:12:18 EI+ Voltage SIR 70S Noise:338
3.0) PKD(7, 5,3,0.05%, 1352. 0, 1. 00%, F, T) Exp:EPCUS
TLI#42930A INJ. TIME = 06:14
A5.?3E6
A3.96E6
-4-
27:00
6.4E6
5.1E6
3.9E6
2.6E6
1.3E6
O.OEO
11
1.5E6
-1.2E6
\.9.0E5
6.0E5
L 3 . 0E5
23:00
File: S9756 66 *1-867 Acq:5-
353.8970 F:2 BSUB(256,30,¦
TRIANGLE LABS Text:RUN 1
1003.
80.
601
40.
20.
0.
24:00 25:00 26:00
SEP-97 06:12:18 EI+ Voltage SIR 70S Noise: 77
¦3.0) PKD(7, 5,3,0.05%,308.0,1.00%, F,T) Exp:EPCUS
TLI#42930A INJ. TIME = 06:14
A2.?8E6 A2.55E6
27:00
.O.OEO
Time
i
23: 00
File:S975666 #1-867 Acq:5-
330.9792 F:2 Exp: EPCUS
TRIANGLE LASS Text.-RUN 1
24:00 25:00
SEP-97 06:12:18 EI+ Voltage SIR 70S
26:00
27:00
8.9E5
7.1E5
5.4E5
3.6E5
1.8E5
O.OEO
1004:
23:10 23:26
TLI#42930A
24: 01
24:37
25:01
INJ. TIME = 06:14
25:29 25:46 26:01 26:21
22:50
1.9E7
1.5E7
1.1E7
7.4E6
3.7E6
23 : 00
File:S975666 *1-867 Acq:5
409.7974 F:2 ExpzEPCUS
TRIANGLE LABS Text:RON 1
1004
24:00 25:00
¦SEP-97 06:12:18 EI+ Voltage SIR 70S
26: 00
27:00
O.OEO
Time
TLI#42930A
INJ. TIME = 06:14
24 34
25:01
_2.0E4
23:30
1.6E4
26:59
23 : 09
25:52
22:56
8.0E3
k
24:5
26:18 26
4.0E3
25:34
O.OEO
23:00
24: 00
25:00
26:00
27:00
-------
File:S975666 *1-967 Acq:S-SEP-97 06:12:18 £1* Voltage SIR 70S Noi.se:90J
355.8546 F:2 BSUB(256, 30,-3 . 0) PKD( 7, 5 ,3 ,0 ,05%,3612. 0 ,1. 00%, F,T) Exp:EPCUS
TRIANGLE LABS TextsRUN 1 TLI04293QA INJ. TIME « 06:14
ioo:
25:00 26:00
File: S975666 #1-867 Acq:5-SEP-97 06:12:18 SI* Voltage SIR 70S Noise: 4 71
357.8516 T-.2 BSUB(256, 30, -3.0 ) PKD(7,5 ,3 , 0.05%, 1884. 0 ,1.00%,F, T) Exp:EPCVS
TRIANGLE LASS Text:RUN 1 TLI04293OA INJ. TIME = 06:14
T- —| 1— •— 1 —f —J—
25:00 26:00
File: S975666 01-867 Acq: 5-SEP-97 06:12:18 EI+ Voltage SIR 70S Noiae: 101
367.8949 F:2 BSUS{256, 30,-3.0 ) PKD( 7, 5, 3, 0 . 05%, 4 04 . 0, 1. 00%, F, T) Exp-.EPCUS
TRIANGLE LABS Text:RVN 1 TLI*4293QA INJ. TIME = 06:14
100X A2.?8E6
80.
9.7E5
A3 * 26JE6
7. 7E5
5.8E5
A1.48E6
A1.23E6
A2.22E6
3.9E5
A5.37E5
A6.57E5
5.48E5
1.9E5
A2. 53E5
100S
so:
601
40.
20.
A2.49E6
A1.82E6
A3.96E5
%8.83E5
A9.05E5 A1.52E6
A2.22E5
JX-
A8.66E5
A5.90E5
4.8SE5
A2.43E5/
A4.24E5
0.0E0
27:00 Time
6.3E5
5.1E5
3.8E5
12.5E5
1.3E5
.0.0E0
60.
40.
20.
A2.51E5
27:00 Time
.6.4E5
.5.1E5
3.9ES
.2. 6E5
.1. 3E5
25:00 26:00
File:S97S666 #1-867 Acq:5-SEP-97 06:12:18 EI* Voltage SIR 70S Noiae: 76
369.8919 F:2 BSUB(256, 30,-3. 0 ) PKE(7 , 5,3,0.05%,304.0,1.00%,F, T) Exp:EPCVS
TRIANGLE LABS Text:RUN 1 TLI04293OA INJ. TIME - 06:14
-P-
.0. OEO
100S
801
60.
40.
20Z
A1.53E6
1. 76E5
27:00 Time
4.6E5
13. 7E5
12.7E5
1.8E5
9.2E4
25:00 26:00
File:S975666 t1-867 Acq:5-SEP-97 06:12:18 EI* Voltage SIR 70S
330.9792 F:2 Exp:EFCUS
TRIANGLE LABS Text.-SUN 1 TLX *4293OA INJ. TIME =
100X 24:10 24:37 24:49 25:01 25:17 25:29 25:46
.0. OEO
27:00 Time
06:14
1.9E7
1.5E7
1.1E7
7.4E6
-3.7ES
25:00
26:00
0.0E0
27:00 Time
-------
File:S975666 #1-425 Acq:5-SEP-97 06:12:13 El* Voltage SIR 70S Noise: 1946
373.8208 P:3 BSUB( 256, 30,-3. 0 ) PKD( 7, 5, 3, 0. 05%, 7784.0,1. 00%,F, T) Exp-.EPCUS
TRIANGLE LABS Text:RUN 1 TLI04293OA
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29': 12 29:24 29:36
File: S975666 *1-425 Acq:5-SEP-97 06:12:18 EI* Voltage SIR 70S Noise: 1553
375.8178 F: 3 BSUB( 256, 30, -T. 0 ) PKD (7, 5 , 3 , 0 .05%, 6212.0,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:RUN 1 TLI#42930A INJ. TIME = 06:14
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 Time
File:S975666 #1-425 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S Noise: 948
383.8639 F:3 BSUB(256,30, -3.0) PKD(7, 5, 3 , 0 .05%, 3792. 0 , 1. 00%, F,T) Exp-.EPCVS
INT. TIME
06:14
100:
A3.96E6
Al ¦ 17Et
A2.82E6
11.2525
A5.36ES
¦f
A8.S4E5
wry
29:48 30:00 30:12 30:
_1.5E6
'.1.2E6
I8.8E5
.5.9E5
L2.9E5
|_0.0£0
24 Time
1003
80l
60.
40.
20:
o.
A9.16E
8E6
A2.17E6
A3.94E5
A7.17E5
A3.38E5
Al.96E5
, ! I I
L.1E6
t-8.9E5
6.7E5
4 . 5E5
2.2E5
O.OEO
TRIANGLE LABS
100%
802
Text: RON 1 TLX442930A
60.
40.
20.
A1.46E6
INJ'. TIME
A1.19E6
06:14
5.6E5
4.5E5
Al.04E6
27:24 27:36 27:48 28:00 28:12 28:24
File:S975666 #1-425 Acq:5-SEP-97 06:12
385.8610 F:3 BSUB(256, 30,-3 . 0 ) PKD(7,5
TRIANGLE LABS Text-.RUN 1 TLI04293OA
100$
80.
28:36 28:48 29": 00 29:12 29:24 29:36 29:48 30:00
18 EI* Voltage SIR 70S Noise: 1266
¦ 3, 0.05%, 5064. 0,1. 00%, F,T) Exp:EFCUS
INJ. TIME = 06:14
1 I 'I '"I PI T I
30:12 30:24
2.2E5
1.1ES
Time
60.
40J
20.
A2. 7BE6
I I') I 1 11 1 '1"' I I I » I I
27:24 27:36 27:48 28:00 28:12 28:24
A2.35E6
A1.97E6
.1. 1E6
.8.9ES
L6.6E5
.4.4E5
.2.2E5
.O.OEO
i fffi t-f ;¦ t I | prff i j i i n rn1
28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 Time
File:S975666 #1-425 Acq:5-SEP-97 06:12:18 EI* Voltage SIR 70S
392.9760 F:3 Exp:EPCUS
TRIANGLE LABS Text:RON 1 TLX*4293OA
lOOi
INJ. TIME = 06:14
9. 9E6
28:10
27:45
28:23
28:46
7.9E6
5.9E6
4.0E6
2.0E6
O.OEO
24 27:36 27:48 28:00 28:12 28:24
S975666 *1-425 Acq:5-SEP-97 06:12
445.7555 F-.3 Exp:EPCUS
TRIANGLE LABS Text:RUN 1 TLX *4293 OA
100%
28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 Time
18 EI* Voltage SIR 70S
INJ. TIME
06:14
1.7E4
1.4E4
1.0E4
6.9E3
3.5E3
-.24 27:36 27:48 28:00 28:12 28:24
28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00
O.OEO
30:12 30:24 Time
-------
Fil'eis§?5SS6 41-425 Acg:5-SEP-9? 06:12,16 £1+ Voltage SIR 70s Nox3e:112S—"
389.8156 F:3 BSOB(256, 30,-3.0) PKD(7, 5,3,0. 05%, 4500.0,1.00%, F, T) Exp:EPCUS
TRIANGLE LABS
1003
80.
60:
28:00 28:12 28:24 28:36 28:48 29-00 29:12 29:24 29:36 29:48 30:00 Tims
File:S975666 #1-425 Acq:5-SEP-97 06:12:18 EI+ Voltage SIS 70S Noise:860
391.8127 F: 3 BSOB(256, 30, -3 .0 } PKD(7, 5,3,0. 05%, 3440.0,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:RUIf 1
1003,
80.
601
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36
File:S975666 *1-425 Acq:5-SEP-97 06:12:18 EI* Voltage SIS 70S Noise: 108
401.8558 F-.3 BSO~B { 256, 3 0, -3.0 ) PKD(7, 5, 3 , 0.05%, 432. 0,1. 00%, F, T) Exp : EPCUS
Text:RUN 1 TLI04293 OA
IN J. TIKE =
06:14
A9.04E6
40:
20:
o:
A2.55E6
A6.95E5
A1.93E6
A6.90E5
_3.0E6
-2.4E6
.1.8E6
L1.2E6
.5.9E5
.O.OEO
TLI #4293 OA
INT. TIME = 06:14
40.
20.
A7.50E6
A2.09E6
A5.38E5
. />>" ¦
A1.62E6
A5.90E5
29:48
30:00
TRIANGLE LABS
1001
80.
Text:RUN 1 TLI #4293OA
60.
40.
20.
INT. TIME =
A1.59E6
06:14
A1. 73E6
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36
File: S975666 01-425 Acq:5-SEP-97 06:12:18 EH- Voltage SIR 70S Noise: 990
403.8529 F:3 BSUB(256,30, -3.0) PKD( 7, 5, 3 , 0.05%, 3960. 0,1.00%, F, T) Exp: EPCUS
29:48
30:00
TRIANGLE LABS
looa
80.
Text:SUN 1 TLI #4293OA
60.
401
20.
IMJ. TIME
A1.42E6
' ¦ "l1 i' i
28:00
•r i l ' '
28:12 28:24 28:36 28:48 29:00 29:12
File:S975666 #1-425 Acq:5-SB>-97 06:12:18 EI+ Voltage SIR 70S
392.9760 F:3 Exp:EPCUS
TRIANGLE LABS Text:RUN 1 TLI442930A INJ.
100S 28:01 28:10 28:23 28:37 28:46 ¦>«.« ->a.ne 29-17
28:48
06:14
TIME =
29:51
29:33 29:41
801
60.
40.
20.
0.
06:14
A1.44E6
29:36
29:24
28:00
„2.5E6
2.0E6
11.5E6
1.0E6
5.0E5
30:00
O.OEO
Time
.6.4E5
.5. 1E5
.3.8E5
.2. 6E5
.1.3E5
.O.OEO
Time
.5.7E5
.4.6E5
.3. 4ES
.2.3E5
.1. 1E5
.O.OEO
Time
9.7E6
.7.8E6
15.8E6
13.9E6
'.1.9E6
'28112 ' '28:24 ' "28:36 ' '28:48 ' '2s\6o ' '29 s 12 ' '29:24 ' '29:36 ' '29:48 ' '30:66
.O.OEO
Time
-------
File: S975666 #1-390 Acq:5-SEP-97 06:12:18 EI+ Voltage SIS 70S Noise: 1144
407.7818 F:4 BSUB(256, 30, -3 . 0) PKD( 7, 5, 3, 0. 05%, 4576. 0, 1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS TextiRUN 1 TLI#42930A INJ. TIME = 06:14
1001 A3.J2E5
801
601
4 01
201
0.
, . ¦ 1 1 I I !' I I I T"| T TI T | , I
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
File:S975666 #1-390 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S Noise:481
409.7789 F:4 BSUB( 256, 30, -S. 0 ) PKD( 7, 5 , 3 , 0. 05%, 1924 . 0 ,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text-.RUN 1 TLI#42930A INJ. TIME - 06:14
A1.42E5
1.2E5
Ll. 0E5
L 7.5E4
15.0E4
L 2.5E4
A3. 42E4
A2.19E4
1003
A3.28E5
80
A
60
40_
20
J \
0
. s3 V
1 1
31:12 31:24
A1.24E5
A3.97E4
^ I i "i
32:12
<1 r
32:24
A2. 95E4
/^\ -
32:36
31:36 31:48 32:00
File: S975666 #1-390 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S Noise:556
417.8253 F:4 BSUB( 256, 30,-3 . 0 ) PKD( 7, 5, 3, 0 . 05%, 2224 . 0, 1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text-.RUN 1 TLI*42930A INJ. TIME = 06:14
100%
801
601
401
20.
0.
32:48
| rr T
32:48
31:12
A9.94E5
~r
T
31:24 31:36 31:48 32:00 32:12
File:S975666 #1-390 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
430.9729 F:4 EzptEPCUS
TRIANGLE LABS Text:RUN 1 TLI#42930A INJ. TIME = 06:14
100% 31:16 31:29 31:40 31:54 32:06 32:15 —~ 32:28 32:36
~r
32:24
32:36
801
601
401
201
0.
' i ¦ ¦
32:48
32:49
T
31:12 31:24 31:36 31:48 32:00 32:12
File:S975666 #1-390 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
4 79.7165 F:4 Exp:EPCUS
TLI442930A
32:24
TRIANGLE LABS
1001
80.
601
40.
201
0.
Text: RUN 1
31:25
INJ. TIME =
32:36
06:14
32:48
31:12
31:24
31:36
31:48
~'—I—•—
32:00
32:12
32:24
""—I—'—
32:36
32:48
10.0E0
32:48 33:00 Time
1.1E5
8.9E4
6. 7E4
C4.5E4
2.2E4
!L0. 0E0
33: 00
1.7E5
1.4E5
1.0E5
6.9E4
3.5E4
.O.OEO
33: 00 Time
4.3E5
L 3.5E5
L 2.6E5
L1. 7E5
L 8.7E4
O.OEO
33:00 Time
6.2E6
'.4.9E6
L 3. 7E6
L2.5E6
'.1.2E6
32:05
31:39
32:20
32:29
32:16
| .O.OEO
33: 00 Time
1. 5E4
¦-1.2E4
'¦.9.0E3
L6.0E3
i 3. 0E3
LO.OEO
33:00 Time
-------
File:SS75S66 41-390 Acq:5-s£p-97 0eiI2:19 £t+ Voltage siR 7/Ts'Noime:432
423.7766 F:4 BSUB(256, 30, -3 .0) PKD< 7, 5,3, 0. 05%, 1728.0,1.00%,F,T) Exp .-EPCUS
TRIANGLE LABS Text:RUN 1 TLI#42930A INJ. TIME - 06:14
100%
801
60i
401
2oi
t ! "f I *
31:30
A4.20E5
1 i I1 m | i i
Jll-36 31:42 31:48 31:54 32:00 32:06 32:12 32:18
File:S97S666 #1-390 Acq:S-S£P-97 06:12:18 EI+ Voltage SIR 70S Noiae:57
425.7737 F:4 BSOB(256, 30,-3.0) PKD( 7,5,3, 0. 05%, 228 . 0,1. 00%, F, T) Exp : EPCUS
TRIANGLE LABS Text.:SUN 1 TLI04293OA ZNJ. TIME = 06:14
100*
T^»r
80.
60.
40i
20i
32:24 ' 32:30 32:36
A4.18E5
31:30 31': 36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30
File; S975666 #1-390 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S Noise: 85
435.8169 F:4 BSUB(256,30,-3.0) PKB(7, 5 ,3 , 0.05%, 340.0 ,1.00%, F,T) Exp: EPC'JS
TRIANGLE LABS Text-.RUN 1 TLI*4293 OA INJ. TIME » 06:14
32:36
1 i | i i"i
31:48
I I I I I ! 1 I | I 1-1 I PI I I I [ I I 1 ITT
31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18
File: S975666 §1-390 Acq:5-SEP-97 06:12:18 SI* Voltage SIM 70S Noise: 69
437.8140 F:4 BSUB(256, 30, -3 .0) PKD( 7 , S , 3 , 0 . 05%, 276. 0 ,1.00%, F, T) Exp:EPCOS
TRIANGLE LABS Text:RUN 1 TLI*42930A INJ. TIME » 06
1003s
so:
60i
401
201
A8.81E5
-fr-
100%
801
601
40:
201
A8.96ES
rr
31:30 31:36 31:42 31:48 31:54 32:00 32:06
File: S975666 #1-390 Acq: 5-SEP-97 06:12:18 EI* Voltage SIR
430.9729 F:4 Exp:EPCUS
TRIANGLE LABS Text:RUN 1 TLI04293OA
100% 31:29 31:34
801
601
40.
20.
0.
32:12
f r*i !* i i i i
32:18 32:24
INJ. TIME
32:15
06:14
32:28
32:36
32:24 32:30 32:36
14
' ' T' T < ' 1 I 1 1
32:30 32:36
.3. 1E5
.2.SE5
.1. 9E5
.1.2E5
.6.2E4
.0. 0E0
Tiae
.3. 4E5
.2. 7E5
.2.0E5
.1.3E5
.6.7E4
.0. 0E0
Tiae
.3.3E5
.2.6E5
.2.0E5
.1.3E5
.6.6E4
.0. 0E0
Time
.3.2E5
.2.6E5
.1. 9E5
.1.3E5
.6.5E4
.0.0E0
Time
6.2E6
4.9E6
13.7E6
2.5E6
1.2E6
31 s 30
i i I 1 1
31:36
31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30 32:36
.0. 0E0
Time
-------
File: S975666 fl-390 Acq: 5-SEP-97 06:12:18 EI+ Voltage SIR 70S Noiae:52
441.7428 F:4 BSUB(256, 30, -3. 0 ) PKD(7,5,3,0.0S%f208.0,1.00%,F,T) Exp:EPCUS
32:00 33:00 34:00 35:00
File:S975666 #1-390 Acq:S-SEP-97 06:12:18 Elf Voltage SIB 70S Noise:324
443.7399 F:4 BSUB ( 256, 30, -3 . 0 ) PKD(7, 5 ,3 , 0 . 05%, 1296. 0 ,1. 00%, F, T) Exp:EPCDS
TRIANGLE LABS Text:RON 1 TLI 04293OA INJ. TIME = 06:14
100% A2.
TRIANGLE LABS
ioo:
TextsSON 1 TLI04293OA
INJ-. TIME
06:14
2.3E4
2.1E4
1.9E4
1.6E4
1.4E4
A3. 77E4
1.2E4
A9.94E3
A2.19E4
A1.23E4
9.3E3
7.0E3
A2.43E4
A4.17E3
A1.18E4
4.6E3
A1.17E4
2T3E3
O.OEO
Time
2.1E4
z.1. 9E4
LI. 7E4
-1.5E4
z.1. 3E4
A1. 72E4
A1.98E4
A3 . 68E4
1.1E4
8.6E3
A6.84E3 AU.23E4
A1.04M4
A1.17E4
A3.00E3 1 A8.43E3
-6.4E3
A1.42B4
1.26E4
-4 . 3E3
2.1E3
O.OEO
32:00 33:00 34:00
File:S975666 #1-390 Acq:5-SEP-97 06:12:18 EI+ Voltage SIS 70S
430.9729 F:4 Exp:EPCUS
TRIANGLE LABS Text:RON 1 TLI*42930A INT. TIME
¦1003, _ __ .J3;03 33:21 ,, „ 34:16
90
35:00
6.3E6
35:23
5. 7E6
5.1E6
4.4E6
3.8E6
3.2E6
2.5E6
1.9E6
1.3E6
6.3E5
O.OEO
32:00 33:00 34:00
File: S975666 01-390 Acq:5-SEP-97 06:12:18 EI* Voltage SIR 70S
513.6775 F:4 Exp:EPCBS
35:00
TRIANGLE LABS
1003
902
803
70s
60j
soj
4o\
301
Text-.RXTN 1 TLI04293OA
31:14
203
102
31:52
32:09
I 31:43
uUW^waLJlJ
INJ-. TIME = 06:
34:33
33:17
32:00
1.1E4
1.0E4
8.9E3
7.8E3
6.7E3
35:32
5.6E3
4.4E3
34:19
32:32
3.3E3
2.2E3
4:55
1.1E3
35:24
O.OEO
33:00
34:00
35:00
-------
File:S975SSS #1-390 Acq:5-SEP-9? 06:12:18 EI+ Voltage SlR 70S Noxse:70
457.7377 T:4 BSUB(256,30,-3.0) PKD(7, 5,3,0.05%, 280.0,1.00%, F,T) Exp:EPCUS
TRIANGLE LABS Text: RUN 1 TLI442930A INJ\ TIME = 06:14
100% AljJ>5E5
r""si—1—1—1——r
34:30 34:36 34:42 34:48 34:54 35:00
File:S975666 #1-390 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S Noise: 62
459.7348 F:4 BSUB(256, 30, -3 .0 ) PKD(7, 5, 3 , 0. 05%, 248. 0 , 1. 00%,F,T) Exp:EPCUS
TRIANGLE LABS Text:RUN 1 TLI#42930A INJ~. TIME = 06:14
1004 A1.22E5
34:30 34:36 34:42 34:48 34:54 35:00
File:S9 75666 #1-390 Acq: 5-SEP-97 06:12:18 EI+ Voltage SIR 70S Noise:62
469.7779 F:4 BSUB( 256 , 30, -3 . 0 ) PKD(7, 5 , 3 , 0 . 05%, 248 . 0, 1.00%,F,T) Exp:EPCUS
TRIANGLE LABS Text:RON 1 TLI#42930A INJ~. TIME = 06:14
A1.52E4
-r-r/S,
35:06
.2.2E4
.1. 8E4
.1. 3E4
.9. 0E3
.4.5E3
.0.0E0
Tine
3.9E4
_ 3. 1E4
2. 3E4
_1. 6E4
_ 7. 8E3
A8.13E3
A2. 76E3
0.0E0
35: 06
1003
801
601
401
201
A8.16E5
T
"r
T
T
35:00
34:30 34:36 34:42 34:48 34:54
File: S975666 #1-390 Acq: 5-SEP-97 06:12:18 EI+ Voltage SIR 70s Noise: 61
471.7750 F:4 BSUB(256, 30, -3 .0 ) PKD( 7, 5, 3, 0. 05%,244. 0, 1. 00%,F, T) Exp:EPCUS
TRIANGLE LABS Text:RVN 1 TLI442930A INJ~. TIME » 06:14
1004
35: 06
Time
.2. 7E5
.2.1E5
.1. 6E5
11. 1E5
.5.3E4
.O.OEO
Time
_2.7E5
-2.2E5
_1. 6E5
_1. 1E5
5.5E4
.O.OEO
I ' I ....
34:30 34:36 34:42 34:48 34:54
File:S975666 *1-390 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
430.9729 F:4 Exp:EPCOS
TRIANGLE LABS Text:RUN 1 TLI§42930A INJ~. TIME =
35:00
06:14
1001
801
601
401
201
0.
34:29
34:40
34 j 51
34 :58
35:06
35:06
34:30
-1 1—i-
34:36
34:42
34:48
~' 1 r"
34:54
1 1
35:00
35: 06
_6.1E6
4.9E6
3.7E6
.2.5E6
.1. 2E6
O.OEO
Time
73
-------
I
I
I
I
I
I
Channel I 338.3732
Peak top
Height 3.25 wits Span
286 oca
liW nil
Systa file nm
EPCUS2
Data fits nase
fi=S985S71
Resolution
16080
nuber
2
Ionization tode
EI*
Switching
mm
Rtf. lasses 238.9825,
R 293 J 331
418.3788
S 368
B 384 K 332
T 378
C 3i L 334
U 378
0 316 i m
V 418
E 318 H 342
F 321 0 352
6 322 P 354
H 328 9 31
I 331 R 358
Rtf. ass 416,9788
Peak top
W .98 tfb fcn
cm ppi
-------
File:S975666 #1-867 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
303.9016 F:2 Exp:EPCUS
Sample Text: RUN 1 TLI#42930A ^ IN J , TIME = 06:14 File Text: RUN 1
100%
80.;
601
40
20 j
Oi
1—i—i—i—|—i—I—I—I—I | I I—I—I—I—I T~~i ri p-1—i—i—i—i—i—I—I—I—rH—i—pr—i—i—i—I—|—r=T"T—i—r—|—i—i—i—i—rn—i—i—i—r T ]—I—rr
16:48 17:00 17:12 17:24 17:36 17:48 18:00 18:12 18:24 18:36
File:S975666 #1-867 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
305,8987 F:2 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A _ J. TIME = 06 : 14 File Text:RUN 1
100% —i—i—r~|—r—t 1 > 'r i—r—i—i—t ~T~H~ ?—i—i—i—t ¦ F"77!—i—i—r
16:48 17:00 17:12 17:24 17:36 17:48 18:00 18:12 18:24 18:36
File:S975666 #1-867 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
315.9419 F:2 Exp:EPCUS
Sample Text:RUN 1 TLI#42 930A INJ. TIME
100% 16;57
06:14 File Text:RUN 1
TLI#42»
-1.3E7
.1.0E7
L7.5E6
5.0E6
L2.5E6
0.0E0
Time
TLI#42»
-1.5E7
.1.2E7
.9.0E6
.6 . 0E6
.3 . 0E6
.0,0E0
Time
TLI#42»
1. 8E5
17 : 54
1.5E5
18:04
17 :48
1. 1E5
17 :12
7 . 3E4
16:45
18:25
3 . 7E4
-i—i—i—i—|—i—i—i—i—i—j—i—i—i—i—i—|—i—i—r~~i—!—|—i—i—j—i—i—|—i—i i r—i—|—r—i—r~r
t—t i t—r-^1—r—!—r i—i—r—j~
16:48 17:00 17:12 17:24 17:36 17:48 18:00 18:12 18:24 18:36
.0 , 0E0
Time
in
-------
File: S975666 #1-867 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
319.8965 F:2 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A INJ. TIME = 06:14 File Text:RUN 1 TLI#42»
100%
80i
60 J
40 J
20.
0.
n
n
18
18
V
W
w
: 1C
_l 1 , , , 1 , , , , , 1 , , , , , 1 , , , 1 , 1-
T
23 :3
w
:*4|
: 2 5
~i i r*
1 ,—,—i
i 1—t ( 1 —« 1 1 r~
.3 . 9E4
.3 . 1E4
.2 . 4E4
.1.6E4
.7 . 8E3
.0 . 0E0
16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 24:00 25:00 Time
File:S97 5666 #1-867 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
321.893 6 F:2 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A INJ. TIME = 06:14 File Text:RUN 1 TLI#42»
m
3.9E4(J
4 :25
100%
4 18:5 L
16 :3
3 . 1E4
l2.3E4
17 :16
il.6E4
7 . 8E3
w
20:00
21:00 22:00 23:00 24:00
17:00 18:00 19:00
16 :00
0.0E0
25:00 Time
File:S975666 #1-867 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
331.9368 F:2 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A INJ. TIME = 06:14 File Text:RUN 1 TLI#42»
24 24
100%
80i
60J
40j
20 J
17 :13
6 :22
18:44 19:33
7:47
20 : 55
20 :32
w
3 . 1E4
l2.5E4
23 : 14
il.8E4
! 22:54
:_1 .2E4
16 . 1E3
^0.0E0
~i 1—i 1 1—|—i—i—i—i—t—|—i—i—i—i—i—|—i—i—i 1—i 1—i—i—i—i—r—|—i 1 1—r—i— p- - T--- r- !—,— r—-j ,—,——j—,—j—r—, ,—, [-
16 00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 24:00 25i00 Time
-------
File:S975666 #1-867 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70s"
319.8965 F:2 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A INJ. TIME
100% A • (1
06:14 File Text:RUN 1
TLI#42»
.5 . 0E5
4 . 0E5
Ch3 . 19E6J
2 . 0E5
78E5 .>
9.9E4
19100 20:00 21:00 22:00
File:S975666 #1-867 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
321.8936 F:2 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A INJ. TIME =
i ~^**T r1 1 »
23 :00
06:14 File Text:RUN 1
100%
80j
60i
40 J
20i
0:
/
19
.00
JiO . 0E0
Time
TLI#42»
5 . 5E5
4 . 4E5
3 . 3E5
l2.2E5
1.1E5
20:00 21:00 22:00
File:S975666 #1-867 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
331.9368 F:2 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A INJ. TIME =
21:35
23 :00
06:14 File Text:RUN 1
100%
80 J
60i
40 j
20i
0 :
19
•00
20:00
21:00
22:00
r"i1"1 r " ^
-r^' nj' ¦" f"
23 : 00
-0 .0E0
Time
TLI#42»
.1.4E6
.1.1E6
.8 . 6E5
-5 . 7E5
-2.9E5
.0.0E0
Time
-4
tJ
-------
File: S97 5666 #1-867 Acq: 5-SEP--97 06:12:18 EI+ Voltage SIR 7 0S""
339.8597 F:2 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A
100%
INJ. TT.ME_.ii. 06 : 14 File Text:RUN 1
£&?. 11E6>
TLI#42»
2 .7E6
2 . 2E6
1, 6E6
<^A4 . 12E6 1
1. 1E6
CA3.02E6)
5 . 4E5
~i—I—i—i—i—i—i—I—r-T—I—i—I—I—I—I—i—i—I—|—r—i—i—i—i—|—i—i—r-T—r—|—>—i—i—ri—|—I—i—I—rl—|—r—i—i—<—<—)—i—i—r—i— i—[—i—i—i—i—<—|—i—i—i—i—r-
24 :24 24:30 24:36 24:42 24:48 24:54 25:00 25:06 25:12 25:18 25:24 25
File:S975666 #1-867 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
341.8567 F:2 Exp:EPCUS
0.0E0
30 Time
Sample Text:RUN 1 TLI#42930A
100%
INJ. TIME .= 06:14 File Text:RUN 1
CA6 .18E6
cA2.62E6
INJ. TIME = 06:14 File Text:RUN 1
25 : 07
—i—|—i—i—i—i—i j fl ) i—i—|—i—i—i—i—i—j i*i i—i—i—|—i—i—i—i—i—|—i—| VfY |—r—i—i—r-h—|—i—i—i—i—i i i—i—i—i—]—i—i—i—i—i—|—i—r . . .
24:24 24:30 24:36 24:42 24:48 24:54 25:00 25:06 25:12 25:18 25:24 25
File:S975666 #1-867 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
351.9000 F:2 Exp:EPCUS
Sample Text:RUN 1 TLI#4293 0A
1004
80i
60i
40i
20i
ol
T*j—r—> \ 'i »
-i—!—i—|—i—i—i—i—i—|—— i | I ! i
24:24 24:30 24 i 36 24 i42 24148 24:54 25:00 25:06^ 25:12 25:18 25:24 25
TLI#42»
_1.9E6
_1.5E6
-1.1E6
.7 . 6E5
_3 , 8E5
.0.0E0
30 Time
TLI#42»
_1.5E6
1.2E6
9.0E5
L6.0E5
_3 . 0E5
.0.0E0
30 Time
«s|
•00
-------
File:S975666 #1-425 Acq:S-SEP-97 06:12:18 EI+
373.8208 F:3 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A
100% 29j 14
Voltage SIR 70S
INJ. TIME
06:14 File Text:RUN 1 TLI#42»
2 , 0E5
1. 6E5
1.2E5
29:02
8.2E4
30:00
28:51
4 . 1E4
29:5
29:38
' 1 t I t I 1 "j"l I 1 I I | » I I—I 1 | « j ..... | | , ,
28:48 28:54 29:00 29:06 29:12 29:18 29:24
File:S975666 #1-425 Acq:5-SEP-97 06:12:18 EI+
375.8178 F:3 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A
100% 29 l14
29:30 29:36 29:42
Voltage SIR 70S
INJ. TIME =
29:02
28:51
r-r-n-r. ,,,,,,, T r-0 •0E0
29:48 29:54 30:00 30:06 Time
06:14 File Text:RUN 1 TLI#42»
.1, 9E5
1.5E5
L1.1E5
7.6E4
L3.8E4
30:00
28:48 28:54 29:00 29i06 29il2 29il8 29i24
File:S975666 #1-425 Acq:5-SEP-97 06:12:18 EI+
383.8639 F:3 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A
100%, 29; 13
80.
60.
40 j
20.
29 :30
29:30 29:36 29:42
Voltage SIR 70S
INJ. TIME =
t l"Tri
.0 . 0E0
29:48 29:54 30:00 30106 Time
06:14 File Text:RUN 1 TLI#42»
.4 . 6E5
29:56
r rn | p iO-r "f*"| f r—rnit )•¦! t-i T^~T~T~T~r^~|- i-t
28:48 28:54 29:00 29:06 29:12 29:18 29:24
n-ri'ifn-tT
29:30 29:36 29 :42
i3.7E5
.2 . 8E5
-1.8E5
.9. 2E4
.0 . 0E0
29i 48 29:54 30~! 00 30 1 06 Time
,-4
CO
-------
File:S975666 #1-425 AcqTB-SEP-97 06:12:18 EI+ Voltage SIR 70S"
373.8208 F:3 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A
100%
INJ. TIME =
06:14 File Text:RUN 1 TLI#42»
2 . 0E5
1. 6E5
1.2E5
/fa
8 . 2E4
4 . 1E4
-0.0E0
t—i—i—i—i—r~i—i—i—i—i—i—i—i—r—i—i | T i—i—i—i—f~i—i—i—i—i—i—i—i—i—t"Ti—r"T" r i"i—r"!—i—i—i—r—j—r~T—j—i—i ~PT T f"l ~T™"i "i—i—i—t—i—i—i—1~ t~i i i—i—i i T p
28:48 28:54 29:00 29:06 29:12 29:18 29:24 29:30 29:36 29:42 29:48 29:54 30:00 30:06 Time
File:S975666 #1-425 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
375.8178 F:3 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A
100%
INJ. TIME =
06:14 File Text:RUN 1 TLI#42»
1. 9E5
1. 5E5
ll.1E5
i7,6E4
3 .8E4
-j—I—i—i—i—I—|—I—I—r—i—i—|—i—?—j—i—iTT (—j—l I 11 i—i—i—i—i—pT—i—i—t 1 I T i—i—r~i—P"T TT f T i rT i i -r
28:48 28:54 29:00 29:06 29:12 29:18 29:24 29:30 29:36 29 i 42
File:S975666 #1-425 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
383.8639 F:3 Exp:EPCUS
Sample Text;RUN 1 TLI#42930A INJ. TIME =
100% 29;13
80
60 j
40
20 j
28 1 48 ' 28!54 '29!Oo"29 S06^29!12 '29!18 '29!24 29:30 29 i 3 6 29i42
0 0K0
1 'rTr i—i—r^i—j—t—i—i—i—i—i—i—i—I—r~i—r-^— ' XJC-'yj
29:48 29:54 30:00 30:06 Time
06:14 File Text:RUN 1 TLI#42»
4 . 6E5
29:56
3 . 7E5
l2.8E5
1.8E5
9.2E4
0.0E0
29:48 29:54 3 0!00 30!06 Time
O
-------
File:S975666 #1-425 Acq:5-SEP~97 06:12:18EI+ Voltage SIR 70S
373.8208 F:3 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A
100% A6 3E5
80
INJ. TIME = 06:14 File Text:RUN 1 TLI#42»
,_2 . 0E5
lI.6E5
ll.2E5
8 . 2E4
l4.1E4
28:48 28:54 29:00 29:06 29:12 29:18 29:24
l I l | l i l l T~ p 0 •
29:30 29:36 29:42 29:48 29:54 30:00 30:06 Time
File:S975666 #1-425 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
37 5.817 8 F:3 Exp:EPCUS
Sample Text:RUN 1 TLI#42 93 0A _
100% (*A5 . 34E5
INJ. TIME = 06:14 File Text:RUN 1 TLI#42»
_1.9E5
1.5E5
L1.1E5
l7.6E4
l3.8E4
I > I I I ' 1' ' | ' I I I 'V ' V | I I I I I1 j it f i i | > i i i i | r i I I I |
28:48 28:54 29:00 29:06 29:12 29:18 29:24
| i-i i i i | i ' i i i | r i i i i [ i i i i i I '
29:30 29:36 29:42 29:48 29:54 30:00 30:06 Time
File:S975666 #1-425 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
3 83.8639 F:3 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A
100% 29:13
80j
60J
40 J
20j
INJ. TIME = 06:14 File Text:RUN 1 TLI#42»
_4.6E5
29 : 56
I if, ,v .f.p,... j , [ ! . p iO i r | i r—i i i | i i i i i |T~n i i (' i 'i
28:48 28:54 29:00 29:06 29:12 29:18 29:24
l3.7E5
l2.8E5
1. 8E5
i9.2E4
L0.0E0
T~T r-pi n-r"fj PT it I—P' 1~I~1—I I I I I I—I—r y i—i—i—i—i—|—i—i—i i i |
29:30 29:36 29:42 29:48 29:54 30:00 30:06 Time
99
-------
File:S975666 #1-425 Aeq:5-SEP-97 06:12:18 EI+~ Voltage SIR 70S
373.8208 F:3 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A INJ. TIME
100%
80i
60
40
20J
06:14 File Text:RUN 1
A6.77E|
-i—i 1—i 1 1 1—i 1 1—i 1 1—i 1 1—i—i 1—i r 1—i i 1 1 1 1 1—i 1 r—| 1 1 1 r \—i 1 1 f 1 1 1 1 1 1 r~
29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48
File:S975666 #1-425 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
375.8178 F:3 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A INJ. TIME = 06:14 File Text:RUN 1
IOOSl
TLI#42»
_7 . 0E4
.5 .6E4
.4. 2E4
.2 . 8E4
.1.4E4
0 . 0E0
Time
TLI#42»
6.3E4
5.0E4
3 . 8E4
2.5E4
1 .3E4
~i—i—!—i—i 1 1—e—|—i—i—i—i—i—|—i—
29:24 29:36 29:4
~t 1 i r "i 1 1 1 r 'i i f—"i 1—r—\ 5 1 r~—r—i r™
30:00 30:12 30:24 30:36 30!41
File:S975666 #1-425 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
383.8639 F:3 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A INJ. TIME
100% 29; 56
80
60j
40i
20
0
06:14 File Text:RUN 1
29 :24
29:36
29:48 ' 30:00
jiT—
1 1 p r-p , .. , | - . | -p p, , j p~-^1 y ^
30:12 30:24 30:36 30:48
0 .0E0
Time
TLI#42»
.3 . 6E5
^2 . 9E5
.2 . 2E5
.1. 5E5
.7 . 3E4
-0.0E0
Time
m
to
-------
File:S975666 #1-425 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 7US
373.8208 F:3 Exp:EPCUS
Sample Text: RUN 1 TLI#4293 0A INJ. TIME = 06:14 File Text: RUN 1
(^1"'72eT)
TLI#42»
7 . 0E4
100%
. 6E4
l4.2E4
L2.8E4
1 . 4E4
29 00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36
30:48
File:S975666 #1-425 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
375.8178 F:3 Exp:EPCUS
Sample Text: RUN 1 TLI#4293 0A _ INJ. TIME = 06:14 File Text: RUN 1
lOOfcin
_0 . 0E0
Time
TLI#42»
6 . 3E4
£A1. 3 8E5...
5.0E4
3 . 8E4
2 . 5E4
1.3E4
I i I I I I I I I I I I I I J I I I I JJ
29:24 29:36 29:48 30:00
I 1 '
30 :12
|—i—i—i—i—i—|—i—i—r~
30:24 30:36
t—i—|—i—i—i—i—r~
30:48
29:00 29:12
File:S975666 #1-425 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
383.8639 F:3 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A INJ. TIME = 06:14 File Text:RUN 1
100% A 29;56
80 J
60 J
40 J
20
0j
¦*Wy
29 00 29:12
-T'-i "i—r"
29 :24
"•i- i |
29 :48
i i—i—i—i—|—i—r*
30:00
30 : 12
¦ |'"r ,,"i
3 0:24
¦ ¦f* r r p i ,ji—i—i—i—p-i—i—r*r
3 0:36 30:48
.0 . 0E0
Time
TLI#42»
_3 . 6E5
_2 . 9E5
.2 . 2E5
.1 . 5E5
.7 . 3E4
_0.0E0
Time
CO
-------
File:S975666 #1-425 Acq:5-SEP-9T 06:12:18 EI+ Voltage SIR 70S
389.8156 F:3 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A INJ, TIME =
100% f~\ (11 29 j 44
06:14 File Text:RUN 1
TIj I # 4 2 »
.1.7E5
1
1.4E5
1.0E5
6.8E4
3 , 4E4
28:00
28:00 29:00
File:S975666 #1-425 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
391.8127 F:3 Exp:EPCUS
30 :00
Sample Text:RUN 1 TLI#42930A
100%
INJ. TIME
06:14 File Text:RUN 1
0 . 0E0
Time
TLI#42»
.1.7E5
29: 44
1.3E5
9.9E4
6.6E4
29 ::>1
29:00
3 . 3E4
27 :50
28:00 29:00 30:00
File:S975666 #1-425 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 7 0S
401.8558 F:3 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A INJ. TIME = 06:14 File Text:RUN 1
100% ^9:25 29,43
80 4 '' ^
60 j
40
20.
0.
28:00
29 :00
30 :00
0 . 0E0
Time
TLI#42»
_6 . 2E5
5 . 0E5
3 . 7E5
^2 . 5E5
.1. 2E5
-0.0E0
Time
1 OO
4b
-------
File:S975666 #1-425 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
389.8156 F:3 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A INJ. TIME =
100% I 29i 44
06:14 File Text:RUN 1
TLI#42»
_1.7E5
1.4E5
1.0E5
6 . 8E4
29:13
~i—i—i—i—i "j i —T r tTTS—i—i rf | ~t—I—I—I—rn—I—I—I—I—i—r-r-1—i—i—i—|—r~T" i—i i |—i—i—t t""i" | i—i—i—i {"*" r t i^T \—i—i—PT" i r* i' | »
29:00 29:06 29:12 29:18 29:24 29:30 29:36 29:42 29:48 29:54 30:00 30:06
iTiTft
30:12
File:S975666 #1-425 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
391.8127 F:3 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A INJ. TIME
29:44
06:14 File Text:RUN 1
.0 . 0E0
Time
TLI#42»
1.7E5
1.3E5
9 . 9E4
6.6E4
29:21
3 . 3E4
9:03
t—i—i—i—i rTTTT n—i—i r i—i—i—i—j—i—i—r—i—r~i—i—i—i—r—i—i—i—i—i r i it—m—i—\—r—r~i r -1—i i "t—r~*i—j i r~ i *T~"r i—rfin i—1—
29 00 29:06 29:12 29:18 29:24 29:30 29:36 29:42 29:48 29:54 30:00 30:06
File:S975666 #1-425 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
401.8558 F : 3 Exp*. EPCUS
••"t i
30:12
Sample Text:RUN 1 TLI#42930A
100% a
INJ. TIME =
29:43
06:14 File Text:RUN 1
I "I I—I—|—I—l—T—I I | I )—! "( T |—i—I—i—i—r
¦'I tTT* ! i | 'i i I i—i—t—i—i—i—i—i—|T i '"i "T" i ) i i i'11—i—|—r~r~i—i—i—rr~ir
00 29:06 29i12 29:18 29:24 29:30 29:36 29:42 29:48 29:54 30:00 30:06
tit |—i—r
30 : 12
0.0E0
Time
TLI#42»
.6.2E5
.5.0E5
_3 . 7E5
.2 . 5E5
.1.2E5
.0.OEO
Time
» OO
-------
File:S975666 #1-425 Acq:5-SEP-97 06:12718 EI+ Voltage SIR 70S
389.8156 F:3 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A INJ. TIME =
100%
06:14 File Text:RUN 1
TLI#42»
1.7E5
il,4E5
1 , 0E5
6.8E4
A1.43E5
3 . 4E4
00 29:06 29:12 29:18 29:24 29:30 29:36 29:42 29:48 29:54 30:00 30:06 30:12
File:S975666 #1-425 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
391.8127 F:3 Exp:EPCUS
Sample Text: RUN 1 TLI#42930A INJ, TIME = 06:14 File Text: RUN 1
100%
.O.OEO
Time
TLI#42»
.1. 7E5
1.3E5
9 . 9E4
<^r.26E6 3
6.6E4
3 . 3E4
30:12
i—i—i—t "i" r r*T i i—r—i—i iT j—i { i i ij.npn.j—.—,—,—,—,—j—.—j—i—i—i—i y i i—t—i—t—i—i—i—i—i—i—j—i—r-*i—i—r~i—f7"7?" i—i—i—i—i—i—t—r—i—i—i—r~
29 00 29:06 29:12 29:18 29:24 29:30 29:36 29:42 29:48 29:54 30:00 30:06
File;S975666 #1-425 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
401.8558 F:3 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A
1°0^ ^ 29:25
80
60
40
20j
0J
29
TT-I—I | I I
I | I I T I1 T j i—r—r
INJ. TIME
29 :43
06:14 File Text:RUN 1
i—j—i—i—i—i—i | rr iini i j-1
n—|—1„ rT.
00 29:06 29:12 29:18 29:24 29:30 29:36 29:42 29:48 29:54 30:00 30:06
|—I—r
30:12
0.0E0
Time
TLI#42»
.6 .2E5
3.0E5
3 . 7E5
.2 . 5E5
-1.2E5
.0 . 0E0
Time
i
OO
-------
File:S975666 #1-425 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
389,8156 F:3 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A
100%
80i
60i
40
20
0,
INJ. TIME
06:14 File Text:RUN 1
—i—i—r—i—i—i—r'f""|1 i v
29136 29:42 29:48
29:06 29:12 29:18 29:24 29:30
File:S975666 #1-425 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
391.8127 F:3 Exp:EPCUS
'i'" i "i l l—i "7 "1 I ") ) i I i i i—r
29:54 30:00 30:06
i_r_j—|^
30:12
Sample Text:RUN 1
100%
80
60
40 j
20
0
TLI#42930A
~ i' 1111
29:06
i i r"i "T
29:12
i '"I r
29:18
INJ. TIME
06:14 File Text:RUN 1
A1.26E
r-i—I—i—i—i—i—i |~i r~t i i I T"n i—i—|—~i—i—i—rTTTT r~r*i*nf r i—i—i—r
29:24 29:30 29:36 29:42 29:48 29:54 30
File:S975666 #1-425 Aeq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
401.8558 F:3 Exp:EPCUS
f—i—n—i i | i i
: 00 30:06
t—r—r~|~i—
30 :12
Sample Text:RUN 1
100%
80 J
60i
40i
20i
0.
TLI#42930A
29:21
*1—i—i | i—i—r
29:06
rrrrrrr
29:12 29
INJ .
29 :43
TIME = 06:14 File Text:RUN 1
-1 1 1 1 T"
~i—i—i—i—r-
18 29:24 29:30
t I I k
29:36
i—i—i—i—r~
29:42 29:48
T11 l,r
29
'i f i i—r—|—i t t"i"i i i I-
54 30:00 30:06
r i t i—i—r
30 :12
TLI#42»
_ 6.6E5
I.5.3E5
14.0E5
•12 .7E5
II.3E5
lO.OEO
Time
TLI#42»
5.6E5
4 . 5E5
.3.4E5
_2 . 2E5
.1.1E5
.0.0E0
Time
TLI#42»
.6. 4E5
.5.1E5
.3 . 8E5
.2 . 6E5
.1.3E5
0.0E0
Time
-------
File:S975666 #1-390 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR TOS*
407,7 818 F:4 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A INJ. TIME
100% n
06:14 File Text:RUN 1
TLI# 4 2 »
.3 . 7E4
2 , 9E4
2 . 2E4
33:04 33:19
32:43 I ' li 33:36
1 . 5E4
34 :05
7*. 4E3
ac~3"Z"\ 2 0
2:06
31 00 32:00 33:00 34:00
File:S975666 #1-390 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
409.7789 F:4 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A INJ. TIME = 06:14 File Text:RUN 1
.0 .0E0
Time
TLI#42»
.3 . 6E4
31:42
100%
2.9E4
31:35
2 . 2E4
33 : 50
1. 4E4
32:34
32:04 32:24
34 :10
7 . 2E3
32:59 3 3 : 14 3 3:31
^VaJ\/w\o
34 :00
31 00 32:00 33:00
File:S975666 #1-390 Acq;5-SEP-97 06:12:18 EI+ Voltage SIR 70S
417.8253 F:4 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A INJ. TIME
32:33
06:14 File Text:RUN 1
31:57
33 :38
31:32
34 : 07
31:00
32 : 00
33 :00
34:00
£U0E0
Time
TLI# 4 2 »
. 1.5E5
.1.2E5
-8.9E4
_5 . 9E4
.3 . 0E4
.0 . 0E0
Time
no
oo
-------
File:S975666 #1-390 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
407.7818 F:4 Exp:EPCUS
Sample Text:RUN 1 TLI#42 93 0A INJ. TIME -
100% 31;22
80 J
60 J
40 J
20J
oJ
06:14 File Text:RUN 1
31:35
31:21
33 :04
1:48 32 :02
32 :43
34:05 34:23
34:00
32:00 33:00
File:S975666 #1-390 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
409.7789 F:4 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A INJ. TIME = 06:14 File Text:RUN 1
100% 31:22
TLI#42»
1.2E5
Ll.0E5
17.5E4
15.0E4
l2.5E4
0 . 0E0
Time
TLI#42»
1.1E5
8.9E4
6.7E4
4 . 5E4
31:42
2 . 2E4
33:50 34:1034:23
32:00 33:00
File:S975666 #1-390 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
417.8253 F:4 Exp:EPCUS
34 :00
Sample Text:RUN 1 TLI#42 93 0A
100% 31 22
INJ. TIME = 06:14 File Text:RUN 1
32:33
31: 57
34:15
33:38
32 : 00
33 : 00
34 : 00
0 . 0E0
Time
TLI#42»
_1.7E5
.1.4E5
.1.0E5
.6 . 9E4
.3 . 5E4
0 . 0E0
Time
-------
File:S975666 #1-390 Acq:5-SEP-97 06:12:18 EI+ Voltage"SIR TOS
407.7818 F:4 Exp:EPCUS
Sample Tey t:RUN 1 TLI#42930A INJ. TIME =
100% 7i2E5 )
06:14 File Text:RUN 1
TLI#42»
_1.2E5
1.0E5
7.5E4
5 . 0E4
2 . 5E4
32:00 33:00
File:S975666 #1-390 Aeq:5-SEP-97 06:12:18 EI + Voltage SIR 70S
409.7789 F:4 Exp:EPCUS
Sample T^xfc-tEJjftr 1 TLI#42 93 0A INJ. TIME =
100%, /^A3 .10E? >
80.
60.
40.
20.
0.
32100 33:00
File:S97 5666 #1-390 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
417.8253 F:4 Exp:EPCUS
34:00
06:14 File Text:RUN 1
Sample Text:RUN 1 TLI#42930A
INJ. TIME
34:00
06:14 File Text:RUN 1
100*
80
60
40
20
31
¦A-/.
22
32 :33
¦——
31:57
AA /%—
—
33 :38
s —AA--_^
34 :15
0.0E0
Time
TLI#42»
.1. 1E5
.8.9E4
.6. 7E4
A . 5E4
.2 . 2E4
.0 . 0E0
Time
TLI#42»
7E5
1
1
.1
32 :00
33:00
34 :00
4E5
0E5
9E4
5E4
0E0
Time
•O
-------
File:S975666 #1-390 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
407.7818 F:4 Exp:EPCUS
Sample Text:RUN 1 TLI#4291DA INJ. TIME =
CA1•12E5>
06:14 File Text:RUN 1 TLI#42»
3 . 7E4
~2 . 9E4
i2.2E4
1.5E4
i7.4E3
~i—i—i—|—i—i—i—i—i—1—i—i—i—i—i—|—i—i—i—i—i—|—i—i—i—i—i—j—i—i—i—i—i—|—i—i—i—i—i—[—i—i—i—i—i—|—i—i—i—i—i—|—i—>—i—i—i—|—r
31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 3 2:30 Time
File:S975666 #1-390 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
409.7789 F:4 Exp:EPCUS
Sample Text: RUN 1 TLI#42 21QA^ INJ. TIME = 06:14 File Text : RUN 1 TLI#42»
100%. f~Al .'Q5E5 _3 . 6E4
i2.9E4
(^aTUeTj
i2.2E4
Ll.4E4
¦1 . 2E3
"0.0E0
n—i—i—|—i—i—i—i—i—|—i—i—i—i—i—j—i—i—i—i—i—|—i—i—I—i—i—|—i—i—i—i—i—|—i—i—i—i—i—j—i—i—i—i—i—-j—i—i—i—i—i—j—i—i—i—i—i—|—i—i—i—r
31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32 i 30 Time
File:S97 5666 #1-390 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
417.8253 F:4 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A INJ. TIME = 06:14 File Text:RUN 1 TLI#42»
100% _1.6E4
80j
60 j
40 J
20 J
0.
31:32
31: 57
il.3E4
.9 . 8E3
.6 . 5E3
.3 . 3E3
.0 . 0E0
1—i—i—i—j—i—i—i—i—i—|—i—i—i—i—i—j—i—i—i—i—i—[—i—I—I—I—I—|—I—i—i—i—i—|—t—i—i—i—i—j—i—i—i—i—i—[•—i—i—i—r—i—|—r—i—r —i—i—j—i—r—i—i—r
31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 3 2!3 0 Time
-------
File:S975666 #1-390 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
441.7428 F:4 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A INJ. TIME = 06:14 File Text:RUN 1
100%.
TLI#42»
1.2E4
1. 0E4
35:01
32 :32
7 . 5E3
35:47
32 :20
33 :07
31:39 32:00
L5.0E3
33:35
4:22
l2.5E3
35 : 00
32:00
33:00 34:00
File:S975666 #1-390 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
443.7399 F:4 Exp:EPCUS
Sample Text: RUN 1 TLI#42930A INJ. TIME = 06.: 14 File Text: RUN 1
100%, 3 5; 03
0 . 0E0
00 Time
TLI#42»
1.2E4
3:22
l9.6E3
32 :40
17.2E3
33 : 45
35:48
32 :00
34:13 34:3!)
33 :24
4.8E3
i2.4E3
32:00 33:00 34:00 35:00
File:S975666 #1-390 Acq:5-SEP-97 06:12:18 EI+ Voltage SIR 70S
469.7779 F:4 Exp:EPCUS
Sample Text:RUN 1 TLI#42930A INJ. TIME = 06:14 File Text:RUN 1
100%
80j
60
40j
20.:
0
34:39
32:01
+-
32 :00
-I—T ¦*-] —I
33 :00
--—'
.0 . 0E0
00 Time
TLI#42»
_2.7E5
l2.1E5
1. 6E5
1 . 1E5
L5 . 3E4
-r—
34 :00
35 : 00
36
_0.0E0
00 Time
-------
TLI Project:
Client Sample:
42930A Method 23 TCDD/TCDF Analysis (DB-225)
RUN1 Analysis File: X973013
Client Project:
Sample Matrix:
TLI ID:
Iron & Steel-Youngstown
M23TRAIN Date Received:
179-98-1A-D Date Extracted:
Date Analyzed:
08/19/97
08/25/97
09/06/97
Spike File: SPC2NF04
ICal: XF24087
ConCal: X973009
Sample Size:
Dry Weight:
GC Column:
1.000 Dilution Factor:
n/a Blank File:
DB-225 Analyst:
n/a
S975665
ML
% Moisture: n/a
% Lipid: n/a
% Solids: n/a
Analytes
Amt (ng) DL
EMPC
Ratio RT
Flags
2,3,7,8-TCDF
15.4
0.79 23:01
—
Internal Standard
Amt. (ng) % Recovery QC Limits
Ratio RT
Flags
•5C,;-2.3,7,8-TCDF
3.2 80.6
40%-130%
0.76 23:00
—
Recovery Standard
Ratio RT
Flags
I3Cn- 1,2,3,4-TCDD
0.84 21:59
Data Reviewer %u 09/08/97
Page 1 Of 1 C2NF.PSRv200. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:5^0^08/97
-------
Initial
Data Review By:
....Date...
Calculated Noise Area: n/a
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No. 1 Listing of X973013B.db£
09/03/97 Batched GC Peaks / Ratio / Set. Time
Compound/
M_Z.... QC.Log Omit Why .,RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
0.
65-0.89
0.798-1.102
304-306 DC
NL
0:00
RO
1.24
16,62
0.000
DC
WL
18: 21
RO
10.83
676.16
0.798
18:43
RO
1.56
1.737.86
1,528.43
981.34
0 . 314
18: 50
RO
1.01
16,428.15
9,370.33
9,231.44
0.319
19:03
0.68
223.69
90.59
133.10
0.828
19: 13
0.73
168,95
71.57
97.38
0.836
19: 17
0.75
343.57
147.27
196.30
0.333
19:43
0.76
28.385.80
12,291.90
16.093.90
0.357
19: 50
0.79
15,746.00
6,946.36
3.799.14
0.362
19: 58
0.79
25,243.20
11,168.00
14.075.20
0.363
20: 07
0.74
15,666.82
6,679.80
3,937.02
0.375
20:22
0.75
12,505.60
5.374.51
7,131.09
0.386
20:30
0.76
22.883,23
9,888.13
12.995.10
0. 391
20:39
0.78
10.107.81
4.413.65
5,694.16
0. 393
20:48
0.76
42,151.50
18.195.60
23.955.90
0 . 904
20: 56
0.75
8.746.49
3,749.43
4,997.01
0.910
21:17
0.77
40,395.70
17,573.30
22,322.40
0.925
21:44
0.72
25.255.00
10.555.40
14,699.60
0.945
21:56
0.76
15,089.70
6,536.91
8.552.79
0.954
22:09
0.74
16,431.67
7,009,23
9.422.39
0.963
22:21
0.75
1.233.04
548.21
734.83
0.972
22: 30
0 .79
11,368.03
5,002.55
6,365.48
0.973
22:53
0.81
9.452.67
4,226,25
5,226.42
0.995
23:01
0.79
10,437.15
4,602.62
5,834.53
1.001 2378-
23:13
0.76
9,144.02
3,954.29
5,189.73
1.009
23: 30
0.77
3,562.46
3,722.29
4,340.17
1.022
23: 37
0.76
14,871.63
6,398.83
3,472.30
1.027
24: 24
0 .75
6,944.07
2,967.22
3,976.35
1.061
25:08
0.81
859.96
385.92
474.04
1.093
304-306
27
Peaks
370,433.77
13C12-TCDF
0
65-0.89
0.956-1.044
316-313 DC
NL
0: 00
RO
1.37
19.82
0.000
DC
WL
18:25
RO
6.08
18,37
0.801
DC
WL
18:42
0.71
446,62
0.313
DC
WL
19:03
RO
2.38
9.27
0.828
DC
ML
21:56
RO
0.62
38.46
0.954
23:00
0.76
2,807.68
1.215.33
1,592.35
1.000 13C12
DC
WH
24:28
RO
1. 60
9.89
1.064
DC
WH
25:26
RO
1.18
30.90
1.106
316-318
1
Peak
2,807.68
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:55 09/08/97
94 -
-------
Page No,
09/03/97
Listing of X973013B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.i.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
Above: TCDF / TCDD Follows
13C12-TCDD
332-334
332-334
0.
65-0.39
0.
907-1.093
DC
NL
0:00
RO
2.43
5.42
0.000
DC
WL
19:11
RO
1.58
4.71
0.883
DC
SN
20:34
RO
1.08
7.59
0.947
DC
SN
21:26
RO
- 0.48
3.10
0.987
21:43
0.79
2,139.99
942.68
1,197.31
1.000 13C12-2378-TCDD
21: 59
0.84
2,503.59
1,144.33
1,353.76
1.012 13C12-1234-TCDD
DC
SN
22:16
RO
3.13
4.74
1.025
DC
SN
22:22
RO
1.78
6.69
1.030
DC
SN
22:55
RO
0.61
6.11
1.055
DC
SN
22:57
RO
0.52
6.51
1. 057
DC
SN
23:02
SO
3.03
1.27
1.061
DC
SN
23:13
RO
0.54
1.72
1.069
DC
SN
23:19
RO
2.43
6.57
1.074
DC
SN
23:27
RO
1. 97
2.73
1.080
DC
SN
23:31
0.79
5.92
1.083
DC
SN
23:34
RO
1.61
2.67
1.085
DC
SN
23:38
0.76
4.44
1.083
DC
SN
23:44
RO
0.41
3.26
1.093
DC
SN
23:44
0.65
6.77
1.093
DC
WH
2
23:51
Peaks
RO
2.34
3.13
4,643.58
1. 098
Column Description.
"Why" Code Description QC Log Desc.
M_2 -Nominal Ion Mass(es)
. .RT. -Retention Time (diss!
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
Pilot 1573013 *1-1285 Xcqt S-SSP-1997 31x09x20 QC SI* Voltage SIS. XuboSpmc
303.9016 Bxp:XCONP_TT
Saavl* TmxtxXOBl TLX04293OJI film Tmxtx TKULOOZX LABS
101a
95.
90!
as.
801
7Si
70.
65!
sol
SSl
sol
4Sl
40l
3Sl
30l
2Sl
20l
ISl
101
Si
0.
20:48
19:43
_4.5E7
.4.3X7
3.8E7
.J • © tsz
.3.4X7
3.2X7
2.7X7
19:58
2.5X7
2.3X7
20x30
2. 0X7
1.8X7
20x07
1 • © tsz
1.4X7
1.1X7
9.0X6
6.8X6
4.5X6
2.3X6
19x43
i i i S*
19:00 19x12 19x24 19x36 19x48 20x00 20x12 20x24
Pil»xZ973013 01-1285 Acqx S-3XP-1997 21x09x20 OC XX* Voltage SIR AutoSpac
305.8987 XxpxXCOSP_TT
Sample TextiKUNl TLI04293OA Vila Tojctt TXIANBLX LABS
ion
95l
90l
85!
801
75.
701
651
601
551
SO.
45.
40.
35-
30l
25.
20-
IS.
101
s!
20x36
20t48
.0.0X0
tOO Tim*
19:00
19:12
' i I i '
19x24
19x36
19158
20x30
19x49
20x07
20x39
20x22
19x48
20x00
20x12
20x24
20x36
48
.5.9X7
.5.6X7
.5.3X7
.5.0X7
.4.7X7
.4,4X7
.4.2X7
.3.9X7
.3.6X7
.3.3X7
3.0X7
2.7X7
2.4X7
.2.1X7
1.8X7
1.5X7
20x56
1.2X7
J\
.8.9X6
f\
5.9X6
\
3.0X6
V
0. 0X0
48 21
00 Time
96-
-------
\fllmsX973013 #1-1385 Acq. 5-3*9-1997 21x09x30 X BX* VoXtmgm SIM XuboSpme SoimmxSSlS
303.9016 BSm(256,30,-3.0) FXD(5,3,1,0.10%, 23264.0,0.00%,F,F) XxpxXCOBF_TT
Sasfilm TrnxtsMOKl TLX04293OA Film Tmxtx TRZJU90LK LASS
lOOk Al.f2X8
19 s 00 20 s 00 21'sOO 22,00 23x00 24x00 25x00
FilmxZ973013 01-1285 Mags 6-3KP-1997 21x09120 OC XX* Voltmgm SXX AutoSpma Salami*697
30S. 8987 BSUB(2S6, 30,-3.0) FED (S,3,1,0.10%, 18788.0,0. 00%, F, F) XxpxXCaHF_Tr
Saaplm TmxtxXONl TLX04293OA Film Tmxtt TKXABBXJS LAW
loo*
20x00 21x00 22s00 23x00 24x00
FilmxX973013 01-1285 Acqs 6-SXF-1S97 21x09x20 OC XX* Voltaym SIR AutoSpma Hoimms7683
31S.9419 BSm(25€,30,-3.0) FKD(5,3,1,0.10%.30732.0,0.00%,F.F) ExpsXCQNF_TT
Saaplm tmxtxltOSl TLX04293OA Film T«rt* TXZAHBLX LABS
_4.5X7
.3. SX7
A1.23XB
A1.06X8
L2.7X7
A9.37X7
A3.89X7
68X7
1.8X7
7.01X7
A6.40X7
AS.00X7
A4.2
_9.0X6
A2.97X7
'0. 0X0
Timm
5.9X7
4.7X7
A1.61X8
A3.28X8
3.6X7
A3.28X7
A1.30X8
.99X7
8.55X7
2.4X7
A8.47X7
At. 3 7X7
AS.2
1.2X7
A3.98X7
19x00
25x00
loom
80.
60.
40,
20.
A1.22X7
A1.86X6
III fi/\*
II
I' I 'I' I '*!' f
.0. 0X0
Timm
3.0X6
2.4X6
1.8X6
1.2X6
6.1X5
t£.O.OXO
19x00 20s00 21x00 22x00 23s00 24x00
FilmsZ973013 01-1285 Acqs 6-SXF-1997 21x09x20 OC XX* Voltagm SXX AutoSpma Balmmx560l
317.9389 BSUB(256,30,-3.0) VXD (5,3,1, 0.10%, 22404.0, 0.00%, F,F) BxpxXCOBP_TT
Saaplm frxtxXUm TLX04293OA Film Taxes TBXASOLX IMS
25x00
loo*
80i
60.
40.
20.
A1.59X7
A2.61X6
mj^m
I "I rl '"I 'I" "I 1 1
19x00
A1.78X6
rimm
3.8X6
3.1X6
12.3X6
.1.5X6
.7.6X5
' I I I * 1 1 I I 1' I 1 !¦ V*l I I I I 1*1 '"I" 'I
20x00 21x00 22x00 23x00 24x00
FilmxX973013 01-1285 Acqs 6-SXF-1997 21x09x20 OC XX* Voltmgm SIR AutoSpma
375.8364 X*9xZCONF_TT
Smaplm rmxtsMDm TLX04293OA Film Tmxtx TXXAmLX LABS
100*
1 * f I f
0.0X0
25s00
Timm
1.1X5
.9.1X4
-6.8X4
18x47
18x29
.4.6X4
12.3X4
13x00
20x00
21x00
22x00
23x00
24x00
25x00
.0.0X0
Timm
97 |
-------
\Pilm:U73013 §1-12B5 Acgx 6-SBP-1997 21:09:20 OC SI* Voltagm SIR XukoSpmc Boiam:lC24
319.8965 BSUB(256,30.-3.0) PKD(5,3,1. 0.10%, 6496. 0, 0. OOH.F.P) Xxp:XCONF_TT
Staple TmxttKOHl TLI04293OA Film TUt: TRIANBLB LIBS
100k
I 1^1 "i ¦ tr | 'i" ? ^ i ¦ | i—* ¦' | ' P" ¦ '-I
20:00 21:00 22:00 23:00 24:00
Fllm:X973013 01-1285 Acq: 6-SSP-1997 21:09:20 OC XI* Voltagm SIR AutoSpmc Noism:64S5
321.8936 BSOB(256,30,-3.0) PKD(S,3.1.0.10%. 25820.0,0.00%. P.P) Xxp:ICOSP_TT
Saaplm TmxtiKUNl TLI04293OA Film Tmxt: TRIABOLX UBS
AS.49X6
A4.42X6
A3.99E6
A3.22X6
A4.70B6
A4.52S
1.93X6
8.37B5
A1.1SS
A8.3SXS
.56X5
A1.21B6
, A
ioia
so:
60•:
40.
20.
0.
A6.34B6
mf | A
A6.20S6
A3.86S6
A4.82X6
A6.76X6
A5.55X
A3.89X6
lr
A1.05X6
I -r" A
20:00 21:00 22:00 23:00 24:00
Pilm:Z973013 01-1285 Acq: 6-SXP-1997 21:09:20 OC XI* Voltmgm 3111 AutoSpmc Nolam:3142
327.8847 BSUB(256,30,-3.0) PKD(S,3,1, 0.10%, 12568.0, 0.00%,P,P) Sxp:XCOSP_TT
Saaplm Tmxt:K0N1 TLI04293OA Film Tmxt: TRIANBLX LABS
100H A1.?6E7
A1.25X7
801
601
40.
20:
A1.59X6
-A*.
AS.19X6
A3.98X6
WVh.M i—A!
A1.46X7
A1.91X6
v-A-
I * I " I 1 I I I 1 "l T" I I I I t I
20:00 21:00 22:00 23:00 24:00
Film:X973013 01-1285 Acq: 6-SXP-1997 21:09:20 OC XI* Voltagm SIR AutoSpmc Noimm:3715
331.9368 BSUB(256, 30,-3.0) PKD (5,3,1, 0.10%, 14860.0, 0.00%,P,P) Sxp:XCOSP_TT
Saaplm TmxtiRONl TLI04293OA Film Tmxt: TRIANBLX LABS
100>t
80.
60.
40.
20.
A1.14X7
A9.43X6
1 ^ I I I ' | ~ I ¦! 1 I 1 I I I 1 I ¦ I 1 I 1' I | 1 ' I " I' I ^ I 1 1 —I ¦ I ' ¦ I I I
20:00 21:00 22:00 23:00
Pilm:X973013 01-1285 Acq: 6-3XP-1997 21:09:20 OC XI* Voltagm SIR AutoSpmc NOimm:1529
333.9338 BSUB(256,30,-3.0) PKD(5,3,1, 0.10%, 6116.0,0.OOH.F.P) BxptZCONP_TT
Saaplm TajctiRUNl TLI04293OA Film Tmxt: TRIANBLX '¦»'
¦ I '
24:00
ion
ao:
6o:
40.
20.
0.
A1.36X7
A1.20X7
20:00
i r '
21:00
•U=~*
2.3X6
.1.9X6
.1.4X6
.9,4X5
.4.7X5
.0.0X0
Tiam
.5.0X6
.4.0X6
.3.0X6
2.0X6
.1.0X6
0. 0X0
Tiam
_2.9X6
2.4X6
.1.8X6
.1.2X6
.5.9X5
0.0X0
Tiam
3.6X6
2.9X6
.2.2X6
.1.5X6
.7.3X5
22:00
23:00
24:00
0.0X0
Tiam
98-
-------
film1X973013 *1-1295 Ac«* 6-SSP-1997 21109J20 OG XI* Volt*?* SIR AutoSpmc
303.9016 SxpiZCOSP_TT
Smaplm Tmxt,MUNI TLI04293OA Film Tmxtt TRZASaLX LABS
4.5X7
iooa
'3.6X7
-.2.7X7
20t30
0t07
1.8X7
23l3 7
23 tOl
9.0X6
24124
A
0.0X0
-r-r
19100
20,00 21tOO 22iob 23 * 00 24t00
FilmtX973013 #1-1285 Acqs 6-3X2-1997 21s09,20 OC XI* Voltmgm SIX AutoSpme
3IS. 9419 sxptxcamr_Tt
Saapl# TmxttXOSl TLI04293OA Film Tmxt, TSIASOLB LABS
20n 23f00
80:
60.
2St00
to:
20.
21t43
19t00 20,00 21,00 22,00 23,00 24,00
rll;X973013 §1-1285 Aeqt 6-SXP-1997 21,09$20 OC XI* Voltmgm SIX AutoSpmc
331.9368 XxptXCOMF_TT
Smaplm fnttHSm TLI04293OA Film Tmxtt TXIAXBLX LABS
lOOSj 211 $9
80.
60.
40.
20.
0.
18:42
r y i ~™ 'p'"!"1 T ¦7"1 r | ¦ i y i "i 1 i t i 'i" 'in i ¦ i )• i if "i1 ¦ii,ii
19t00 20,00 21tOO 22:00 23x00
Film,X973013 §1-1285 Aeqt 6-SXP-1997 21t09t20 OC XI* Voltmgm SIR AutoSpmc
319.8965 SxptXCOW TT
Smaplm Tmxt,Smi TLH42930A Film Tmxtt TRIASBLX LABS
i" "1 11111" l 'I I"1)1 p " i
24,00 25,00
19t31
loon
20,41
20t03
22,39
22t02
2114
19 tit
i- ) ii~i~ nil*
23,22
25,00
| I H
I | I
u
L
¦l" I'T I"
19,00 20,00 21'tOO 22)00 23,00 24,00
Film,X973013 *1-1285 Acq, 6-SXF-1997 21t09t20 OC MI* Voltmgm SIX AutoSpmc
292.9825 SxptZCONP TT
Sanplm Tmxt tXXm TLI*42930A Film Tmxtt TRLUOLB LABS
1* >°0 19,33 20,05 20t37
25 tOO
100H
80.
60:
40:
20:
o.
"^\/WjVvy\/\wvVV^
t~t
"T~
_
-r
T
19,00 20,00 21tOO 22,00 23,00 24,00
Fllm,Z973013 §1-1285 Aoft 6-SXP-1997 21,09,20 OC XI* Voltmgm SIX AutoSpmc
330.9792 SsbsXCQSF TT
Smaplm Tmxt,SITO TLI*42930A Film Tmxtt TXXAaOLX LABS
25 tOO
Tlmm
100S
80:
60:
40.
20C
0:
18t30 18t59
19t31 20,00
21t21
221 SI 23t41 24116
ii '"m11** y upm yyi "
'T I Y"
19 s 00
ho too
21100
22,00
23 tOO
i I '
24 tOO
.6.6X7
.5.3X7
.3.9X7
•-2.6X7
.1.3X7
.0.0X0
25 tOO
TiMm
99
-------
Volts
0.4449
Volts
0.6255
PPM
200
Volts
0.5898
PPM
200
PPM
200
380.93795 380.97604 381.01414
330.94615 330.97925 331.01235
292.95315 292.98245 293.01175
O
» O
-------
I
TLI Project: 42930A
Client Sample: RUN2
Client Project:
Iron & Steel-Youngstown
Sample Matrix:
M23TRAIN
Date Received:
08/19/97
Spike File:
SPX23704
TLI ID:
179-98-2A-D Date Extracted:
08/25/97
ICal:
SF56117
Date Analyzed:
09/05/97
ConCal:
S975664
Sample Size:
1.000
Dilution Factor:
n/a
% Moisture: n/a
Dry Weight:
n/a
Blank File:
S975665
% Lipid:
n/a
GC Column:
DB-5
Analyst:
HLM
% Solids:
n/a
Analytes
Amt. (ng} DL
EMPC
Ratio
RT
Flags
2,3,7,8-TCDD
0.24
0.76
21:44
1,2,3,7.8-PeCDD
0.62
1.61
26:11
1,2,3,4,7,8-HxCDD
0.15
1.15
29:20
1.2,3,6.7.8-HxCDD
1.4
1.19
29:25
1,2,3,7,8,9-HxCDD
0.57
1.29
29:43
PR_
1,2,3.4,6,7,8-HpCDD
0.68
0.93
32:12
1,2,3,4.6,7,8,9-OCDD
0.37
0.97
34:38
—
2,3,7,8-TCDF
19.1
0.83
20:59
1,2,3,7,8-PeCDF
2.4
1.49
25:05
2,3,4,7,8-PeCDF
2.4
1.46
25:49
1,2,3,4,7,8-HxCDF
1.2
1.23
28:36
PR_
1,2,3,6,7,8-HxCDF
0.42
1.24
28:43
2,3.4,6,7.8-HxCDF
EMPC
0.25
PR
1,2,3.7,8,9-HxCDF
0.03
1.10
29:55
1,2,3,4,6,7,8-HpCDF
EMPC
0.30
1,2,3,4.7,8,9-HpCDF
ND 0.2
1.2,3,4.6.7.8.9-OCDF
ND 0.3
Totals
Ami. (ng): Number DL
EMPC
Flags
Total TCDD
5.7 14
Total PeCDD
6.0 9
7.8
Total HxCDD
12.3 7
Total HpCDD
2.1 2
—
Total TCDF
155 14
156
Total PeCDF
35.5 14
35.7
Total HxCDF
4.6 12
4.8
Total HpCDF
0.18 1
0.47
Method 23 PCDD/PCDF Analysis (a) I
Analysis File: S975667
1
I
I
I
1
I
I
I
I
I
I
I
I
I
I
Printed: 15:33 09/08/97 ¦
101* 1
Page 1 of 2
X237.PSR v2-00, LARS 6.10.01
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
-------
I
Eastern Research Group
| TLI Project:
Client Sample:
I
I
I
|
I
I
I
I
I
I
I
I
I
I
I
I
I
42930A
RUN2
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975667
1 internal Standards
Amt (ng)
% Recovery
GC Limits
Ratio
RT
Flags
l3C ,2-2,3,7,8-TCDF
3.9
96.6
40%-130%
0.74
20:57
l3C;;-2.3,7,8-TCDD
3.7
91.9
40%-130%
0.83
21:43
13C, 2-1,2.3,7,8-PeCDF
2.7
67.0
40%-130%
1.54
25:04
13Ci2-l,2,3,7,8-PeCDD
2.3
58.5
40%-130%
1.44
26:10
l3Ci:-l,2,3,6,7,8-HxCDF
4.3
108
40%-130%
0.52
28:42
,3C--1,2.3.6.7,8-HxCDD
3.8
95.5
40%-130%
1.20
29:24
»C l2-l,2,3,4.6,7,8-HpCDF
2.5
63.7
25%-130%
0.40
31:21
l3Ci;-1,2,3.4,6,7,8-HpCDD
2.8
70.1
25%-130%
0.98
32:12
;3C:;-1.2.3.4.6,7,8.9-OCDD
4.4
55.0
25%-130%
0.91
34:38
—
| Surrogate Standards {Type A)
Amt. (ng)
% Recovery
QC Urmts
Ratio
RT
Flags
57CL-2.3.7,8-TCDD
3.7
92.0
70%-140%
21:44
13C,;-2,3,4,7,8-PeCDF
3.5
87.1
70%-140%
1.69
25:49
,3C;2-1.2,3,4,7,8-HxCDF
4.1
102
70%-140%
0.49
28:36
' 3C:;-1,2,3.4,7.8-HxCDD
3.9
97.7
70%-140%
1.20
29:20
rJCi2-l,2,3,4,7,8,9-HpCDF
4.0
99.3
70%-140%
0.39
32:32
—
| Alternate Standards (Type A)
Amt. (ng)
% Recovery
QC Limits
Ratio
RT
Flags
13Ci;-l,2,3,7,8.9-HxCDF
3.9
98.7
40%-130%
0.50
29:55
I3Ci2-2,3,4,6,7,8-HxCDF
4.3
106
40%-130%
0.50
29:12
j Recovery Standards
Ratio
RT
Flags
l3Ci;-l,2,3,4-TCDD
0.83
21:31
13Cn-l,2,3,7,8,9-HxCDD
1.20
29:42
Data Reviewer: SH „ -I
Page 2 of 2
09/08/97
X237.FSR vltSO, LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:33 09/08/97
102
-------
Data Review By:
Initial
....Date...
Calculated Noise Area: 5.95
The Total Area for
each
peak with
an ion
abundance ratio
outside
ratio limits has been recalculated according to method requirements.
Page No. 1
Listing
of S975667B.dbf
09/08/97
Matched
GC Peaks
/ Ratio I Ret.
Time
CompoundI
M_Z QC.Log Omit Why
..RT. OK
Ratio Total.Area... Area.Peak.1.. Area
Peak.2..
Rel,RT Compound.Name..
TCDF
0.
65-0.89
0.827-1.099
304-306 DC
NL
0:00 RO
1. 34
13.26
0. 000
A
17: 38
0.83
3,750.00
1,700.00
2,050.00
0.842
18:06
0.38
2,870.76
1,341.30
1,529.46
0.364
18:22
0.82
1,798.35
808.78
989.57
0.377
18:47
0.83
17,049.50
7,756.46
9,293.04
0.397
19: 09
0. 34
10.948.36
4,994.51
5,954.35
0.914
A
19:31
0.85
10,180.00
4,680.00
5,500.00
0.932
19:50
0.84
8,322.63
3,792.47
4,530.16
0.947
20:10
0.84
11,230.21
5,126.72
6,103.49
0.963
20:31
0.33
6,964.81
3.158.07
3,306.74
0.979
20:47
0. 32
4,625.44
2.083.91
2,536.53
0.992
20: 59
0.33
11.999.78
5,451. 35
6,548.43
1.002 2378-TCDF
21:25
0.31
4,364.85
2,132.62
2,682.23
1.022
21:38
0 . 32
2,554.94
1,154.04
1,400.90
1.033
21:52
0.34
449.36
204.95
244.91
1. 044
22:13 RO
1 .90
38.82
41. 57
21.93
1.060
22:46 RO
0 . 93
262.90
137.49
143.53
1. 087
DC
WH
23:05 RO
1.08
26.30
i . 102
304-306
16
Peaks
97,911.71
13C12-TCDF
0
65-0.89
0.
952-1.048
316-318 DC
NL
0:00 RO
5.79
3.96
0.000
DC
WL
17:40 RO
5.75
16.57
0,843
20:57
0.74
2,008.04
856.77
1.151.27
1.000 13C12-2378-TCDF
DC
WH
23:07
0.59
35.39
1.103
316-313
1
Peak
2,008.04
AN
ISO
Above: TCDF / TCDD Follows
TCDD
320-322
0.65-0.89
0. 861-1.058
DC NIi
0:00 RO
4.91
9.43
0
000
19:02
0.35
265.49
121.60
143.39
0
376
19:26
0 . 73
179.16
75.74
103.42
0
395
Q
19:44
0.73
176.84
74.52
102.32
0
909
20:29
0.73
496.06
217.04
279.02
0
943
Q
20:41
0.-5
295.00
126.00
169.00
0
952
20:52
0.75
89.02
38.06
50.96
0
961
Q
21:10
0.77
170.61
74.27
96.34
0
975
21:27
0.82
215.25
96.76
113.49
0
983
21: 37
0.37
219.38
101.82
117.56
0
995
21:44
0.76
109.07
47.04
62.03
1
001 2378-TCDD
AN
21:53
0. 32
76.21
34.27
41.94
1
008
22:05
0.80
188,65
83.98
104.67
1
017
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713 Printed: 15:34 09/08/97
Phone: (919) 544-5729 • Fax: (919) 544-5491
103
-------
Page No.
09/03/97
2
Listing of S975667B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
320-322
37C1-TCDD
328
323
13C12-TCDD
332-334
332-334
Dmit
Why
. .RT.
OK
Ratio Total
.Area... Area.Peak.1.. Area.
.Peak.2.. Rel.RT Compound.Name..
22: 17
0.^6
50.34 21.70
28.64 1.026
22:46
0.34
75.68 34.64
41.04 1.048
14
Peaks
2,606.76
0.907-1.093
DC
NL
0:00
1 .03
0 . 000
DC
WL
13: 36
1.34
0.356
DC
WL
13 : 43
3 .46
0.862
DC
WL
19: 02
3 .27
0.376
DC
WL
19 : 16
13 .24
0. 887
DC
WL
19:26
13.32
0. 895
DC
WL
19: 35
0.93
0. 902
19 : 44
4.20 4.20
0. 909
DC
SN
19:53
1.10
0.919
20:13
1,553.98 1,553.98
0 . 931
20: 31
7.97 7.97
0.945
20: 52
3.49 3.49
0.961
21: 10
2.77 2.77
0.975
21:44
1,198.78 1,198.78
1.001 37C1-TCDD
DC
SN
21: 58
2.16
1 . 012
22:09
604.77 604.77
1. 020
22:41
5.42 5.42
1.045
22: 52
6.48 6.48
1. 053
DC
SN
23:02
1.23
1.061
9
Peaks
3,387.36
0.
65-0.39
0.907-1.093
DC
NL
0: 00
RO
14 . 00
0. 34
0. 000
DC
WL
18: 54
RO
1 . 61
1.19
0.370
DC
WL
19: 13
RO
1.07
2.35
0. 339
DC
SN
19: 50
RO
7.53
2.19
0. 913
DC
SN
20: 13
RO
0 . 30
1.84
0. 931
20:29
RO
2 . 36
6.39 8.51
3.61 0.943
DC
SN
20: 50
RO
4 ."7
1.91
0.959
21: 31
0 . 33
1,577.08 713.01
864.07 0.991 13C12-1234-TCDD
21:43
0 . 33
1,545.33 702.83
842.50 1.000 13C12-2 378-TCDD
22: 02
RO
1.30
23.01 16.94
13.00 1.015
DC
SN
22: 53
RO
1.39
1.81
1.054
4
Peaks
3,151.81
ID.. Flags.
Above: TCDD / PeCDF Follows
PeCDF
340-342
DC
DC
NL
WL
1.
32-1.78
0.
910-1.0'
0:00
RO
0.21
0.26
0.000
22:43
RO
0.57
83.94
0. 906
23:04
1 .44
1,416.56
834.98
581.58
0.920
23:20
RO
0 . 54
17.98
10.93
20.29
0.931
23:46
1 .40
41.00
23.90
17.10
0.948
24:04
1.55
685.83
416.35
269.48
0.960
24: 13
1.51
3,761.21
2,260.74
1,500.47
0.9 66
24:23
1 .44
650.12
383.94
266.18
0.973
24: 37
1. 56
241.33
147.06
94.27
0.982
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:34 09/08/97
104 *
-------
Page No. 3
09/08/97
Listing of S975667B.dbf
Matched SC Peaks / Ratio / Ret. Time
Compound/
M_Z. . .. QC.Log Omit
Why
. .RT.
OK
Ratio
Total-Area... Area
Peak.1.. Area
Peak.2. .
Rel.RT
Compound.Name. .
ID. .
24:49
1.46
1,117.90
663.28
454.62
0.990
A
24: 59
1. 53
339.00
205.00
134.00
0.997
M
25:05
1.49
789.00
472.00
317.00
1.001
12378-PeCDF
AN
25:14
1.38
507.78
294.07
213.71
1.007
25:22
1.46
733.15
435.14
298.01
1.012
25:49
1.46
810.61
481.39
329.22
1.030
23478-PeCDF
AN
25:57
-1.40
663.33
386.90
276.43
1.035
26:15
SO
1.21
57.04
34.67
28.54
1.047
26:47
1. 37
71.77
41.50
30.27
1.068
DC
WH
27:11
RO
2.16
2.55
1.084
340-342
16
Peaks
11,903.61
13C12-PeCDF
1
32-1.78
0.340-1.160
352-354 DC
NL
0:00
RO
0.88
0.23
0.000
DC
SN
22:48
1.40
2.66
0.910
DC
SN
24:13
RO
2.07
3.14
0.966
DC
SN
24:28
RO
0.34
0.67
0.976
DC
SN
24:43
RO
0.81
2.91
0.936
25: 04
1.54
1,198.01
726.96
471.05
1. ooo
13C12-?eCDF 123
IS2
25:25
RO
2.29
26.52
23 .77
10.40
1.014
25:38
RO
2.40
9.41
8.37
3.69
1.023
25:49
1.59
1.011.80
635.43
376.37
1 .030
13C12-?eCDF 234
SUR2
DC
SN
26:46
RO
0. 37
3.34
1.063
27:00
RO
1.05
5.22
3.17
3.02
1.077
352-354
5
Peaks
2,250.96
Above: PeCDF / PeCDD Follows
PeCDD
1.
32-1.78
0.923-1.025
356-358
DC
NL
0: 00
RO
2 . 38
1.61
0.000
DC
WL
24:05
RO
0. 33
3.16
0.920
A
24:20
RO
0.40
302.71
184.00
456.00 0.930
24: 51
1.45
77.00
45.52
31.48 0.950
25:05
1.58
278.07
170.29
107.78 0.959
25:12
1.S0
139.30
83. 6S
55.65 0.963
25:23
1.39
141.10
82.15
58.95 0.970
M
25:40
1.55
217.30
132.00
85.30 0.981
25: 52
1.76
30.48
19.42
11.06 0.989
25: 59
RO
0.29
15.60
9.48
33.03 0.993
26:11
1.61
114.44
70.66
43.78 1.001 12378
26:19
1.58
53.04
32.49
20.55 1.006
DC
SN
26:29
RO
2.22
2.73
1.012
26:41
1.57
55.68
33.98
21.70 1.020
356-358
11
Peaks
1,424.72
13C12-PeCDD
1.
32-1.78
0.347-1.153
368-370
DC
NL
0:00
RO
0.31
0.21
0.000
DC
SN
24:49
RO
0.86
2.11
0.948
DC
SN
25:05
RO
2.15
2.88
0.959
DC
SN
25:22
RO
0.61
2.98
0.969
DC
SN
25: 32
1.58
2.35
0.976
DC
SN
25:49
RO
1.11
2.91
0.987
AN
Triangle Laboratories, inc.® Analytical Services Division
801 Capita la Drive • Durham, North Carolina 27713 Printed: 15:34 09/08/97
Phone: (919) 544-5729 • Fax: (919) 544-5491 105
-------
Page No. 4
09/03/97
Listing of S975667B.db£
Matched GC Peaks / Ratio I Rec. Time
Compound/
QC.Log Omit Why . .RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
368-370
DC SN
26
26
26
Peaks
10 1.44
18 1.64
48 RO 5.75
585.44
60.41
1.96
645.85
345.28
37.57
240.16 1.000 13C12-PeCDD 123
22.34 1.005
1 .024
IS3
Above: PeCDD / HxCDF Follows
HxCOF
374-376
1.05-1.43
0.957-1.051
A
M
AN
M
DC NL
DC WH
374-376
0
00
RO
0.92
4
82
0. 000
27
38
1.24
103
56
57 .26
46.30
0.963
27
46
1.28
345
10
194.02
151.08
0.967
27
56
1.15
22
76
12.16
10.60
0.973
28
04
1.10
36
15
18.91
17.24
0.978
28
15
1 .21
54
11
29. S8
24.43
0.984
28
36
1.23
258
22
142.50
115.72
0.997
123473-HxCDF
AN
28
43
1.24
117
51
55.03
52.48
1. 001
123673-HxCDF
AN
28
49
1. 30
18
39
10. 39
3.00
1.004
29
01
1.11
48
16
25.29
22.37
1.011
29
09
1 . 13
16
36
3.95
7.91
i.016
29
13
RO
1.47
53
76
35.30
24.00
1.013
234673-HxCDF
AN
29
55
1 . 10
6
73
3. 52
3.21
1. 042
1237 89-HxCDF
AN
29
53
1.16
17
02
9.13
7.39
1 .044
30
17
RO
0. 57
1
01
1. 055
Peaks
1.098
33
PR
PR
13C12-HxCDF
0
43-0.59
384-336 DC
NL
0
00
RO
0.78
3.58
DC
SN
28
28
RO
0.42
1.39
28
36
0.49
685.33
28
42
0. 52
703.61
28
49
RO
0.31
4.36
DC
SN
28
59
RO
1.19
2.11
29
12
0. 50
639.92
DC
SN
29
22
RO
0. 16
2.66
29
55
0. 50
516.17
384-386
5
Peaks
2,549.89
224.72
239.29
2.62
214.38
172.89
0.860
0
0
0
1
1
460.61
464.32
3.22
425.54
343.28
1. 140
000
992
997 13C12-HxCDF 478 SUR3
000 13C12-HxCD? 678 IS4
004
1.010
1.017 13C12-HXCDF 234 ALT2
1.023
1.042 13C12-HXCDF 739 ALT1
Above! HxCDF / HxCDD Follows
HxCDD
390-392
AN
M
DC
DC
DC
DC
DC
NL
1
05-1.43
0.952-
1.015
0
00
RO
0.70
2.15
0
000
28
00
RO
0.41
1.57
0
952
28
09
1.20
280.18
152.87
127.31
0
9 57
28
23
RO
2 . 38
1.75
0
965
28
36
1.12
75.13
39.74
35.39
0
973
28
49
1.26
1,003.92
559.35
444.57
0
980
28
53
1.16
28.05
15.06
12.99
0
985
29
04
RO
2.24
0.92
0
989
29
08
RO
1.53
0.85
0
991
29
20
1. 15
18.37
9.81
8.56
0
998 123478-HXCDD
AN
29
25
1. 19
197.00
107.00
90.00
1
001 123678-HxCDD
AN
29
43
1.29
79.78
44.91
34.37
1
011 123789-HxCDD
AN
PR
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713 ' Printed: 15:34 09/08/97
Phone: (919) 544-5729 • Fax: (919) 544-5491
106
-------
Page No. 5
09/03/97
Listing of S975667B.dbf
Matched GC Peaks / Ratio / Ret, Tims
Compound/
M_Z.... QC.Log
Omit
Why
, .ST.
OK
Ratio Total
.Area... Area.Peak.1.. Area.Peak.2. .
Rel.RT
Compound.Name..
ID. .
DC
WH
29: 54
RO
0.21
0.65
1.017
390-392
7
Peaks
1.682,43
13C12-HXCDD
1 .
05-1.43
0.:
966-1.034
402-404
DC
NL
0:00
SO
0.55
1.46
0.000
DC
WL
27: 53
RO
1.03
1.10
0. 948
DC
WL
27: 59
HO
- 1. 55
2.42
0.952
DC
WL
28:11
RO
0.12
0.36
0.959
DC
SN
23:29
RO
0.39
0.47
0.969
DC
SN
28:47
RO
2.75
1.79
0.979
DC
SN
28:53
RO
8.38
0.36
0.982
29:20
1.20
437.39 265.90 221.49
0.998
13C12-HXCDD 478
SUR4
29:24
1.20
512.74 279.60 233.14
1.000
13C12-HXCDD 673
IS5
29:42
1.20
539.60 294.71 244.89
1.010
13C12-HXCDD 789
RS2
DC
SN
29:58
RO
1. 69
0.78
1.019
DC
SN
30:01
RO
0.65
0.87
1.021
DC
SN
30:08
RO
0,73
1.70
1.025
402-404
3
Peaks
1.539.73
Above: HxCDD / HpCDF Follows
20.90
9,69
HpCDF
0.
o
CO
00
403-410
DC
NL
0:00
RO
1.43
3 .30
M
31:22
RO
1. 22
34.88
31:41
1.12
18.31
DC
SN
32:39
RO
0.45
1.86
DC
SN
32:44
RO
0.56
1.65
403-410
2
Peaks
53.19
13C12-HpCDF
0.
37-0.51
413-420
DC
NL
0:00
RO
1.14
1.74
31:21
0.40
304.71
32:32
0.39
233.35
DC
SN
32:51
RO
0.77
3 .21
413-420
2
Peaks
538.06
HpCDF /
HpCDD
0
38-1.20
424-426
DC
NL
0:00
RO
0.21
0.26
31:37
1.10
119.90
32:12
0.93
55.69
DC
WH
32:31
RO
2.24
0.92
DC
WH
32:40
RO
2.76
0.59
424-426
2
Peaks
175.59
13C12-HpCDD
0
88-1.20
435-438
DC
NL
0:00
RO
6,64
0.29
DC
SN
31:53
RO
0.48
0.94
32:12
0.98
308.21
436-438
1
Peak
308.21
87.51
65.83
HpCDD Follows
62.78
26.90
0.
995-1.044
0.000
17.10
1.001 1234673-HpCDF
AN
3 . 62
1.011
1.041
1. 044
0.
936-1.128
0.000
217.20
1.000 13C12-HpCDF 673
IS6
157.52
1.038 13C12-HpCDF 789
SUR5
1.048
152.52
0.977-1.006
0.000
57.12 0.982
28.79 1.000 1234678-HpCDD AN
1.010
1.014
0.969-1.031
0,000
0.990
155.69 1.000 13C12-HpCDD 678 IS7
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive * Durham, North Carolina 27713 Printed: 15:34 09/08/97
Phone: (919) 544-5729 • Fax: (919) 544-5491
107
-------
Page No.
09/08/97
Listing of S975667B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
HJZ....
QC,Log
Omit
Why
. .RT.
OK
Ratio Total
Area...
Area.Peak.1.. Area.Peak.2. . Rel.RT Compound.Name
U^rTiTl /
rtp<—uu /
Octa-CDD and CDF Follows -- ———-----
OCDF
0
76-1.02
0.884-1.116
442-444
DC
NL
0
00
HO
0.61
2.19
0. 000
DC
SN
31
53
HO
3.26
0.43
0. 921
DC
SN
32
03
RO
0.43
2.17
0.925
DC
SN
32
23
RO
-0.43
1.19
0.937
DC
SN
32
37
RO
1.22
4.16
0. 942
DC
SN
33
18
RO
0. 58
2.14
0.962
DC
SN
33
31
RO
2.56
1.89
0. 963
DC
SN
33
39
RO
0.75
1.76
0. 972
DC
SN
33
43
RO
0. 64
3.44
0. 976
DC
SN
34
24
RO
1.14
0.96
0. 993
DC
SN
34
48
RO
1.55
3.29
1.005 OCDF
DC
SN
35
11
RO
1.64
1.40
1.016
DC
SN
35
21
RO
1.45
2.02
1.021
DC
SN
35
28
RO
0.42
1.32
1.024
442-444
0
Peaks
0.00
OCDD
0
76-1.02
0.384-1.116
453-460
DC
NL
0
00
HO
1.13
1.27
0 . 000
M
34
38
0.97
15. 55
7.64 7.91 1.000 OCDD
DC
SN
35
06
RO
0.65
1.78
1. 013
458-460
1
Peak
15.55
13C12-OCDD
0
76-1.02
0.996-1.006
470-472
DC
NL
0
: 00
0.93
0.29
0.000
34
•38
0.91
307.36
146.38 161.43 1.000 13C12-OCDD
470-472
1
Peak
307.86
AN
AN
I So
Column Description,
"Why" Code Description QC Log Desc.,
M_Z -Nominal Ion Mass(es)
. .RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
File:S975667 #1-86 7 Acq:5-SEP-97 06:51:42 EI* Voltage SIS 70S Noise: 5014
303.9016 F:2 BSUB(256,30. -3.0) PU3{9, 5, 5 , 0.05%,20056.0, 1. 00\,F,T) Exp-.EPCUS
TRIANGLE LABS
100:
18:00 19:00 20:00 21:00
File: S975667 #1-867 Acq: 5-SEP-97 06:51:42 EI* Voltage SIX 70S Noise:3745
305.8987 F:2 BSU3(2S6,30, -3.0) PKD(9, 5,5,0.05%, 14980.0,1.00%, T, T) Exp:EPCUS
TRIANGLE LABS
100i
aoj
sod
40I
20J
ej
Text:SUN 2
TLI#42930A
A7.76E7
INJ. TIME
06:54
1.7E7
1.3E7
A5.45E7
1.0E7
A3I16E7
A3. 79E7
A2.18E7
6.7E6
A5.13E7
3.3E6
A1.34E7
J
22:00
Text:RUN 2
TLI#42930A
A9.29E7
INJ. TIME
06:54
A1.53E7
A A
A6.55E7
A4.S3E7
A3.81E7
A6.10E7
f\i\A
AZ.68E7
22: 00
18:00 19:00 20:00 21:00
File: S975667 #1-867 Acq:5-SEP-97 06:51:42 EI* Voltage SIS JOS Noise: 6484
315.9419 F:2 BSUB(256,30,-3.0) PKD(9,5,S, 0. 05%,25936. 0, 1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text: RUN 2 TLI*42930A IN J. TIME - 06:54
100% A8.ji7E6
80*
60J
40I
201
I i T^iini mutf— *T— j 1 | —|~ | j , | I ^ , ^ ^ ^ j i in 1 in I * 1 1
18:00 19:00 20:00 21:00 ' 22-00
File: S975667 #1-867 Acq:5-SEP-97 06:51:42 EI* Voltage SIR 70S Noise: 1122
317.9389 F:2 BSZTB(256, 30,-3 . 0) PKD(9, 5, 5, 0 . 05%, 4488. 0, 1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:RUN 2 TLI#42930A INJ. TIME = 06:54
1003s
80j
60J
401
203
0J
A1.1SE7
II
10.0E0
231- 00 Time
-2.0E7
L1.6E7
L 1.2E7
.7.9E6
.4.0E6
.0.0E0
23': 00 Time
-2.4E6
L1.9E6
11.4E6
IS -4E5
'¦.4.7E5
23:00
tO.OEO
Time
,_3. 0E6
1.2.4E6
.1. 8E6
.1.2E6
¦-6.0ES
18:00 19:00 20:00 21:00 22:00
File: S9 75667 #1-867 Acq: 5-SEP-97 06:51:42 EI* Voltage SIR 70S
330.9792 F:2 Exp:EPCUS
TRIANGLE LABS Text-.RUN 2 TL1#42930A INJ. TIME = 06:54
100% 17:48 18:15 m- IS 1
-------
File:S9 75667 01-867 Acq: 5-SEP-97 06:51:42 EI+ Voltage SIS 70S Noise: 13091
319.8965 F:2 BSUB(256, 30,-3 . 0} PKB( 7,5,3,0. 05%, 52364 .0,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:BON 2 TLI04293OA INJ. TIME = 06:54
loo:
19:00 20:00 21:00 22:00
File: S975667 #1-867 Acq:5-SEP-97 06:51:42 EI+ Voltage SIS 70S Noise: 2665
321.8936 F: 2 BSVB(256y30,-3.0) PKD( 7, 5, 3, 0. 05%, 10660 . 0,1. 00%, F, T) Exp:EPCVS
TRIANGLE LABS Text:RON 2 TLIM2930A INJ. TIME = 06:54
19:00 20:00 21:00 22:00
File:S975667 #1-867 Acq:5-SEP-97 06:51:42 EI+ Voltage SIS 70S Noise:1332
331.9368 F:2 BSUB<256, 30,-3. 0) PKD( 7, 5, 3, 0. 05%, 5328. 0,1. 00%, F, T) Exp:EPCVS
TRIANGLE LABS Text:RUN 2 TLI04293 OA INJ. TIME = 06:54
1004 A7.Q3E6
801
601
401
20.
A1.22E6
A7.S7E5
A7.45E5
A7.43E5
Al . 02E6
A8.40E5
43EI
A fV^5
A3.46E5
A
.5,
-.4
L 3.
12.
ii.
23:00
4E5
3E5
2E5
1E5
. 1E5
. 0E0
Time
1003
aoj
sod
201
A2.79E6
Al.03E6
Al.44E6
iinii^inMO^.
J
Al.02E6
A9.63E5 A1.18E6 ai„05E6
A5.10E5
\4.19E:
A4.10E5
A2.86E5
J\
i ' 1 1 1 1 ' 1 1 1 1 1
19:00 20:00 21:00 22:00
File:S975667 01-867 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S Noise:96
333.9338 F:2 BSUB( 256, 30, -3. 0 ) PKD(7, 5 , 3 , 0. 05%, 384 . 0 , 1. 00%, F, T) Exp-.EPCVS
TRIANGLE LABS Text:RUN 2 TLI04 293OA INJ\ TIME " 06:54
1003
801
601
401
201
01
A8.43E6
19:00 20:00 21:00 22:00
File:S975667 01-867 Acq:5-SEP-97 06:51:42 EI+ Voltage SIS 70S Noise:513
327.8847 F:2 BSUB(256,30,-3.0) PKD( 7, 5, 3, 0. 05%, 2052. 0,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS
iooa
801
601
Text:RUN 2
401
20.
01
TLI042 93 OA
A1.55E7
INJ. TIME =
A1.20E7
06:54
±
A6. 05E6
19:00 20:00 21:00
File: S975667 01-867 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
330.9792 F:2 Exp:EPCOS
22:00
TRIANGLE LABS Text:RUN 2 TLI04293OA
ioo:
INJ. TIME
21:39
A
.6.
-5.
'.3.
12.
11.
23:00
23:00
23:00
23:00
3E5
0E5
8E5
5E5
. 3E5
. 0E0
Time
0E6
6E6
2E6
8E5
. 9E5
¦ 0E0
Time
4E6
9E6
4E6
6E5
. 8E5
¦ 0E0
Time
3E6
¦ 6E6
,0E6
.3E6
, 6E5
, 0E0
Time
06:54
22:16
21:10
19:32 19:50
20:42
19:10
19:00
20:00
21:00
22:00
23:00
110
-------
rile:S97S667 01-867 Acq:5-SEP-97 06:51:42 SI* Voltage SIR 70S Noise: 81
339.8597 T-.2 BSUB(256, 30, -3 .0 } PKD( 7,5,3,0.05%, 3 24.0,1.00%,r, T) Exp:EPCUS
TRIANGLE LABS Text:RON 2 TZI04293OA INJ. TIME =¦ 06:54
23:00 ; 24:00 25:00 26:00
rile:S975667 *1-867 Acq:5-S£P-97 06:51:42 EI* Voltage SIS 70S Noise:390
341.8567 T: 2 BS(JB(256, 30,-3 . 0 ) PKS(7, 5, 3, 0. 05%, 1560 . 0 , 1. 00%, F, T) Exp-.EPCDS
TRIANGLE LABS Text:RVN 2 TLI*42930A INJ. TIME - 06:54
23:00 24:00 25:00 26:00
File:S975667 *1-867 Acq:5-SEP-97 06:51:42 El* Voltage SIS 70S Noise:68
351.9000 T: 2 BSUB(256,30, -3.0) PKD( 7,5,3,0.05%,272.0,1.00%,F, T) Exp:EPCVS
TSI ANCLE LABS Text. :RON 2 TLI04293OA INJ. TIME " 06:54
100% • A7.27E6
100%
aoJ
60 j
4o\
20j
oj
A2.26E7
A8.35E6
M
A3.84E6
A „
A4.71E6
A6.6$E6
A4.81E6
A.
1001
A1.50E7
A5.82E6
12.66E6
A4.55E6
A4.55E6
A3.29E6
ZL
80J
tfOJ
401
20J
oj
A6.35E6
I
IX
, 1 , 1 , , , , , , , , (I > - ¦-r>
23:00 24:00 25:00 26:00
File:S9 75667 *1-867 Acq: 5-SEP-97 06:51:42 EI* Voltage SIS 70S Noise: 82
353.8970 F:2 BSUB (256 , 30, -3.0) PKD( 7, 5, 3, 0. 05%,328. 0, 1. 00%,F, T) Exp:EPCVS
TRIANGLE LABS Text:SUN 2 TLI*42930A INJ. TIME = 06:54
A4 . 71E6
100S,
80J
6oi
4ol
203
ci_
A3 . 76E6
23:00 24:00 25:00
rile:S975667 #1-867 Acq:S-SEP-97 06:51:42 El* Voltage SIS 70S
330.9792 F:2 Exp: EPCUS
TRIANGLE LABS Text:RUN 2 TLI*42930A INJ.
100% o-i. ne 3d ¦ n* 24:32 25:03
26:00
27:00
.5.5E6
.4.4E6
¦-3.3E6
L 2.2E6
:.1. 1E6
L 0.0E0
Time
27:00
.3. 8E6
13. 0E6
12.3E6
i1.5E6
.7.6E5
.O.OEO
Time
.2.3E6
.1. 8E6
H.4E6
L9.1E5
'U4.SE5
27:00
27:00
.O.OEO
Time
.1. 4E6
il.2E6
IS. 7E5
L5.8E5
L2.9E5
L O.OEO
Time
06:54
25:40
25:58
26:25
1.7E7
1.4E7
1.0E7
6.9E6
3.4E6
LO.OEO
23:00 24:00 25:00
File: S975667 *1-867 Acq:5-SEP-97 06:51:42 EI* Voltage SIR 70S
409.7974 F:2 Exp:EPCUS
TRIANGLE LABS Text:RDN 2 TLI04293OA INJ. TIME
1001,
26:00
27:00
06:54
2.2E4
26:37
1.8E4
S0A22:51
1.3E4
26: 02
24:04
26:27
26:58
9.0E3
4.5E3
O.OEO
23:00
24 : 00
25:00
26: 00
27:00
111
-------
File:s9756S7 41-867 Acq:5-SEP-57 06:S1:4J EI* Voltage SIS 70s Moiae: 748
3S5.8546 F:2 BSUB(256,30, -3.0) PKD( 7, 5, 3, 0. 05%, 2992.0,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:SUN 2 TLH42930A
1004 A1.84E6 A1.70E6
06:54
IKJ-. TIME
5.4E5
4.3E5
60:
3.3E5
A7.07ES
A7.50ES
A4.S5E5
40.
2.2E5
A3.40E5
202
11.1E5
A1.94E5
.9.48E4
:o.oeo
i 25:00
FilezS975667 #1-867 Acq:S-SEf-97 06:51:42 El* Voltage SIR 70S Noise: 316
357.8516 F:2 BSUB( 256 , 30,-3 . 0 ) PKD( 7, 5, 3, 0 . 05%, 1264 . 0,1 . 00\, F, T) Exp:EPCUS
TRIANGLE LABS Text: HON 2 TLI§42930A IN J. TIME =
1003. A4.56E6
26: 00
27:00
06:54
9. 5E5
801
7.6E5
5.755
ill, 69E6
40:
13.8E5
A1.08E6
>5. 57£5
201
11.9E5
A3.15E5
A4.38E5
~ A A""
1O.OEO
25:00
File:S975667 #1-867 Acq:5-SEP-97 06:51:42 EI*- Voltage SIS 70S
33 0.9792 F:2 ExpsSPCUS
TRIANGLE LABS Text:S(M 2 TLI04293QA
10 0t
27:00
26:00
INJ. TIME « OS: 54
25:58 26:12 26:25
,_1. 7E7
25:29 25:40
2432
25:03
'-1.4E7
80.
II.0E7
60.
40.
-6.9E6
20.
13.4E6
25:00
26:00
27:00
Time
11.2
-------
Wile:S975667 #1-425 Acq:5-SEP-97 06:51:42 SI* Voltage SIR 70S Noise:1335
373.8208 F: 3 BSUB(256,30,-3.0> PKD(7, 5,3, 0. 05%, 5340. 0,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:RUN 2 TLI»42930A IMT. TIKE = 06:54
100S
80J
soj
40J
20J
A1.94E6
Oi^
A1.42E6
A5. 73E5
A2.97E5
A4.48E5
A2.53E5
A1.40E5
i yT¥fsr
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
File:S975667 §1-425 Acq;5-SEP-97 06:51:42 EI* Voltage SIS 70S Noise: 1447
375.8178 F:3 BSUB(256, 30,-J. 0) PKS( 7, 5, 3, 0.05%, 5788.0,1. 00\, F, T) Exp:EPCOS
TRIANGLE LABS Text:BON 2 TLI04293OA IKJ. TIME = 06:54
T
30:24
100%
sod
601
4o\
20J
A1.51E6
A1.16E6
A4 . 63E.
A2.44E5
A1,72E5 A
A .
"T*l"
-.3
12
A2.29E5
A3.31E5
A1.14E5
-—'S.
28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
27:24 27:36 27:48 28:00
File :S975667 §1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIS 70S Noise: 928
383.8639 F: 3 BSUB (256, 30,-3.0) PKD(7, 5,3, 0.05%, 3712. 0,1. 00%,F, T) Exp-.EPCOS
~r
. 1E5
. 7E5
. 3E5
. 9E5
.4E5
. 0E0
Time
.4E5
¦ 4E5
¦ 3ES
.2E5
.1E5
. 0E0
Time
TRIANGLE LABS
1003
soJ
60J
40J
201
Text:RUN 2 TLI#42930A
INJ. TIME
06:54
A2.39E6
A2.14E6
A1. 73E6
_
E"'
I4
r
i-2
lo.
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
File:S975667 #1-425 Acq:S-SEP-97 06:51:42 EI* Voltage SIR 70S Noise: 1185
385.8610 F:3 BSUB( 256 , 30, -3 .0) PKD( 7, 5 ,3 , 0. 05%, 4740, 0,1. 00%, F,T) Exp:EPCUS
0E6
¦ 2E5
1E5
,1E5
,0E5
0E0
Time
Text:RON 2 TLI#42930A
IMT. TIME =
06:54
A4.26E6
A3.43E6
TRIANGLE LABS
100$, A4.§4E6
801
60-
40.
20.
*MVri 1 1 ; 1 1 1 1 11 1 '"I '11)1 j"l"l 1 1" ) I 1 1 1 t l I 1 1 1 I 1 '1 1 I >I"|"||| 1 ) 1 I 1 I'l 1'*| I 1 >""l t 1 |'"|"| 1 I 1 1 i 1 I 1 1 1 i»'"[ 11)111
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
File:S975667 §1-425 Acq:5-SEP-97 06:51:42 EI* Voltage SIS 70S
392.9760 F: 3 Exp:EPCUS
TRIANGLE LABS Text-.RON 2 TLI*42930A INJ. TIME = 06:54
1003» . 27:43 27:57 28j09 28:2328:33 28:55 ZSjL19 29:33 29:50 30:10
. 9E6
.5 E6
.2E6
. 7E5
. 8E5
. 0E0
Time
801
sol
40l
20l
0:
27:24 27:36' 27:48 ' 28:00' 28:12 28:24 ' 28:36 ' 28:48 ' 29: 00' 29:12' 29:24 ' 29:36' 29:48 ' 30: 00 ' 30:12 30:24
0E6
2E6
4E6
6E6
8E6
OEO
Time
File:S975667 #1-425 Acq:S-SEP-97 06:51:42 EI* Voltage SIR 70S
445.7555 F:3 Exp:EPCUS
TMIANGZE LABS TextsSON 2 TLI04293OA
100:
IN.7. TIME
06:54
29:42
28:31
30:03
28:57
28:08
28:1
30:2
27:43 ,27:?4
28:4
.4E3
27:24 27:36 27:48 28^00 ' 2812 '28-24 "28s 36 28 • 48 ' 291- 00 ' 29': 12 29': 24 29:36 29:48 30-00 30:12 30:24
113
-------
File:SS756S7 *1-425 Acq: S-SEP-SJ-'O'g: 51 -• 42 "Ti* Vol tage SIR -7lTs"' Noise: 533
389.8156 F:3 BSUB(256,30,-3.0} PKD( 7, 5, 3, 0 . 05\, 2372.0,1. 00\, F, T) Exp:EPCUS
TRIANGLE LABS
1004
80.
so:
Text:RUN 2 TLX #4293OA
INJ. Tim
06:54
9E6
40:
20:
hi.53E6
—r
28:00
A3.97E5
A1.19E6
•fTy1 i i
29: 00
A4.49E5
28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36
File:S975667 *1-425 Acq:5-SEP-97 06:51:42 EX+ Voltage SIS 70S Noise: 856
391.8127 F:3 BSUB(256, 30,-3.0) PKD{7, 5, 3, 0. 05 %, 3424 . 0,1. 00%, F, T) Exp: EPCVS
I
29:48
TRIANGLE LABS Text:RON 2 TLI*42930A
1003
INJ. TIME
06:54
80.
60.
40.
20.
0.
A4.45E6
A1.27E6
A3.54E5
A1.01E6
A3.49E5
TRIANGLE LABS
100i
80.
Text:SXJN 2 TLI*42930A
60.
40.
20.
INJ. TIME
A2.80E6
06:54
A2.95E6
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36
File:S975667 *1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIS 70S Noise: 740
403.8529 r:3 BSOB(256,30,-3. 0) PKD(7, 5, 3 , 0. 05%, 2960. 0 ,1. 00%, F,T) Exp:EPCUS
TRIANGLE LABS Text:RON 2 TLI04293OA INJ. TIME
1001 A2.J3E6
80,
29:48
60.
40.
20.
06:54
A2.4SE6
29:48 30:00
'' pi »•' ' 1 i' 1 j ' 1 ' i ¦•< '• ¦ '¦"¦i i >
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36
File: S975667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
392.9760 F:3 Exp:EPCOS
TRIANGLE LABS Text;SUN 2 TLI04293OA INJ. TIKE = 06:54
1004 28i09 28:23 2^33 28:46 28jJS 29:10 JSJL19 29:33 29:42^9i5° 29:57
803
603
403
203
03
.1. 8E6
.1. 5E6
.1.1E6
.7.4E5
.3.7E5
.0. 0E0
30:00
Time
.1.6E6
.1.3E6
.9.4ES
.6.3E5
.3.1E5
.O.OEO
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00
File:S975667 #1-425 Acq:5-SEP-97 06:51:42 EI* Voltage SIS 70S Noise:405
401.8558 F:3 BSUB{ 256, 30,-3. 0 ) PKD(7, 5,3,0.05%, 1620.0,1.00%, F, T) Exp:EPCUS
Tune
.1.2E6
.9.4E5
.7,1E5
A.7E5
.2.4E5
.O.OEO
30:00
Time
.3.5E5
17. 6E5
.5. 7E5
.3. 8E5
1.9E5
.0.0E0
Tiae
'28:00 ' '28:12 ' '28:24 ' '28:36 ' 28:48 ' '29:00 ' '29:12 ' '29:24 ' ' 29': 36 ' '29:48 ' 30:00
.9.0E6
.7.2E6
.5.4E6
.3. 6E6
.1. 8E6
.0.0E0
Time
114
-------
F±le:S975667 01-390 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S Noise:1154
407.7Q1Q F:4 BSUB( 256, 30 ,-3. 0 ) PKD( 7, 5, 3 , 0.05%, 4616. 0 , 1. 00%, F,T) Exp:EPCUS
TRIANGLE LABS Text:RUN 2 TLI#42930A INJ. TIME = 06:54
A2.29E5
1001
Q.5E4
6.8E4
5.1E4
A9. 69E4
3.4E4
1.7E4
A3. 02E4
AS.36E3
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
File:S975667 *1-390 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S Noise:811
409.7789 F:4 BSUB(256, 30,-3~. 0) PKD(7, 5,3,0.05%, 3244 . 0,1. 00%, F, T) ExpiEPCUS
TRIANGLE LABS Text;SOW 2 TLI#42930A INJ. TIME = 06:54
10 OS) A1.73E5
32:48
0. 0E0
33:00 Tijue
6.6E4
15. 3E4
4.0E4
A8.62E4
2. 7E4
A3.15E4
A2.12E4
.0.0E0
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
File:S975667 #1-390 Acq:5-SEP-97 06:51:42 EI+ Voltage SIS 70S Noise:691
417.8253 F:4 BSUB( 256, 30, -3. 0 ) PKD( 7, 5, 3, 0 . 05%, 2764 . 0,1. 00%, F, T) Exp-.EPCUS
TSIANGLE LABS Text .-J? ON 2 TLI#42930A INJ. TIME = 06:54
32:48
1003
aol
603,
40.
20.
0.
A8.75E5
A6.58E5
33:00 Time
.4.0E5
¦.3.2E5
-2.4E5
L1. 6E5
.8. 0E4
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
File:S975667 *1-390 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S Noise: 607
419.8220 F:4 BSUB(256, 30, -3 . 0 ) PKD(7, 5,3,0.05%, 2428. 0,1. 00%, F, T) Exp:EPCUS
TSIANGLE LABS Text:RUN 2 TLIH42930A INJ. TIME = 06:54
•' I
32:48
r " n m
33:00 Time
1003
80.
60.
40.
20.
A2.17E6
A1.68E6
8.1E5
6.4E5
4.8E5
3.2E5
1.6E5
32:36
i ' <—i—i—i—r™1—^T—1—1 i i 1—r~'—t—1—1—1—1—1—i—^
31:12 31:24 31:36 31:48 32:00 32:12 32:24
File:S975667 #1-390 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
430.9729 F:4 Exp-.EPCUS
TRIANGLE LABS Text:RUN 2 TLI#42930A INJ. TIME ' 06:54
1003* 31:14 31:28 31:41 _ 3iil5 _ 32J.0a . _ 32:20 32-^29 32:37
801
601
401
201
0.
32:48
32:48 32:
.O.OEO
33:00 Time
5.9E6
4.7E6
3.5E6
2.4E6
1.2E6
~r
~r
unr
32:24
31:12 31:24 31:36 31:48 32:00
File:S975667 #1-390 Acq:5-SEP-97 06:51:42 EH- Voltage SIR 70S
479.7165 F:4 ExpsEPCUS
TRIANGLE LABS Text:RUN 2 TLI*42930A INJ. TIME
1003,
32:36
06:54
32:48
171
801
601
401
201
0.
31:16
31:29
31:47
32:28
I
O.OEO
00 Time
r.1 ¦ 7E4
1.4E4
1.0E4
7.0E3
.3. 5E3
31:12
31:24
31:36
31:48
32:00
32:12
32:24
32*: 36
—i—|—r—i
32:48
O.OEO
33:00 Time
115
-------
File":'s97BSS7 #1-390 Acq:S-SEP-97 05:51:42 EI* Voltage SIS 70s Noise: 67
423.7766 F:4 BSUB(256, 30,-3 . 0 ) PKD( 7,5,3,0.05%, 268.0,1.00%,F, T) Exp:EPCUS
TRIANGLE LABS Text:RUN 2 TLI442930A
100% A6.28E5
06:54
INJ. TIME
-2.2E5
11. 7E5
80.
60.
A2.69E5
40.
L4.3E4
.1. BE5
bo:
.1. 3E5
601
A2.88E5
40i
8.9E4
4.4E4
4.7E5
80.
13. 5E5
2.3E5
40.
11.2E5
201
14. 9E5
so:
13. 7ES
12.5E5
10.0E0
31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30 32:36
File :S975667 #1-390 Acq: 5-SEP-97 06:51:42 EI* Voltage SIR 70S
430.9729 F-.4 Exp:EPCUS
TRIANGLE LABS Text:R CW 2 TLI#4293QA
10°J| 31:28 31:41 31:46 _ 31x5-5 . 3M08
06:54
ISX. TIME
32:29
32:37 _5. 8E6
32:20
14. 7E6
so:
.3.5E6
eo:
40.
20:
31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30 32:36
11-
-------
File:S975667 01-390 Acq: 5-SEP-97 06:51:42 EI+ Voltage SIS 70S Noiae:51S
441.7428 F:4 BSUB(256,30, -3.0) PXD(7, 5,3,0.05 \, 2060.0,1. 00\, F, T} Exp:EPCUS
TRIANGLE LABS TextsStm 2 TLI04293QA XKT. TIME = 06:54
100%
2.3E4
2.1E4
1.9E4
1.6E4
1.4E4
1,2E4
A1.67E4
A2.70E4
A3.47E4
A1.56E
9.3E3
A1.21E4
A5.01E3
A2.93E4
24E3
7.0E3
A2.56E4
A1.77E4
4.7E3
2.3E3
O.OEO
32:00 33:00 34:00
File: S9 7566 7 01-390 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S Noise: 852
443.7399 F:4 BSUB(256, 30,-3.0) PKB(7, 5,3 ,0. 05%, 340B .0,1. 00%,F,TI Exp-.EPCUS
TRIANGLE LABS Text:RON 2 TLI04293OA INJ. TIME * 06:54
100% A2.55E4
35:00
1.7E4
1.5E4
1.3E4
1.2E4
A1.49E4
9.9E3
A1.53E4
8.3E3
A1 . 74E>
. 73E4
6.6E3
A2.57E4
A1.16E4
00E4
5.0E3
3.3E3
1. 7E3
O.OEO
Time
32:00 33:00 34:00
File:S975667 *1-390 Acq:5-SEP-97 06:51:42 EI+ Voltage SIS 70S
430.9729 F:4 Exp:EPCVS
TRIANGLE LABS Text:RON 2 TLI04293OA INJ. TIME = 06:54
100& 31:55 32:29 32:55 33:36 34:06 34:33
504
80.
70.
60.
50.
40.
302
20.
101
0.
35:00
35:18 35:38
32:00 33:00 34:00
File:S975667 01-390 Acq:S-SEP-97 06:51:42 EI+ Voltage SIS 70S
513.6775 F:4 Exp:EPCOS
35:00
TRIANGLE LABS Text:RDS 2 TLI04293OA
100%
901
801
70.
601
50.
40.
30.
20.
10.
0.
31:41
32:06
33:08
31:23
33:4
mr. time =
34 : 09
06:54
32: 00
33:00
34:00
I 34:.
JUJUft.
35:33
35:03
4:43
.5.9E6
S.3E6
.4.7E6
.4.2E6
.3.6E6
.3. 0E6
.2.4E6
.1. 8E6
.1.2E6
.5.SE5
.0. OEO
Time
1.4E4
1.3E4
1.1E4
1.0E4
8.5E3
7.1E3
S.7E3
4.3E3
2.8E3
1.4E3
35:00
O.OEO
Time
117. |
-------
File: S975667 H1-3S0 Acq:5-SEP-S7 SW:51:42 EI* voltage sis 70s Noise: 362
457.7377 F-.4 BSUB( 25 6, 30, -3.0) PKD( 7, 5, 3, 0. 05%, 1528. 0,1. 00%,F, T) Exp:EPCVS
TRIANGLE LABS Text:SON 2 TLI*42930A INJ. TIME = 06:54
100% A9.±3E4
so:
so:
34:30 34:36 34:42 34:48 34:54 35:00
File:S975667 #1-390 Acq:5-SEP-97 06:51:42 EI* Voltage SIX 70S Noise:336
459.7348 F:4 BSUB(256,30, -3.0) PKD(7 , 5 , 3 , 0.05%, 1344. 0 ,1.00%, F,T) Exp:EPCUS
TRIANGLE LABS Text:MON 2 TLI04293OA INJ. TIME - 06:54
100%
34:30 34:36 34:42 34:48 34:54 35:00
File:S975667 #1-390 Acq:5-SEP-97 06:51:42 EI* Voltage SIS 70S Noise:70
469.7779 F:4 BSUB( 256 , 30, -3 . 0 ) PKV(7 , 5 , 3 , 0 . 05%, 280 . 0 , 1.00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:RUN 2 TLI»42930A INJ. TIME = 06:54
40Z
20:
A6.97E3
1001
so:
so:
40.
20.
A1.46E6
34:30 34:36 34:42 34:48 34:54 35:00
File:S975667 #1-390 Acq: 5-SEP-9 7 06:51:42 EI* Voltage SIX 70S Noise: 76
471.7750 F:4 BSUB(256,30, -3.0) PKD(7, 5,3,0.05%, 3 04.0,1.00%, F, T) Exp-.EPCUS
TRIANGLE LABS Text:SON 2 TLI#42930A INJ. TIME = 06:54
100%
80.
60.
40:
20.
T
T
34:30 34:36 34:42 34:48 34:54
File:S97S667 #1-390 Acq:5-SEP-97 06:51:42 EI* Voltage SIM 70S
430.9729 F:4 ExptEPCUS
TRIANGLE LABS Text:SON 2 TLI04293OA INJ. TIME
100% __ 34:33 _ 34 L50
80.
60.
T—r"
35:00
06:54
40.
20.
ft
2.6E4
2.1E4
1.6E4
1.1E4
5.3E3
A8.45E
O.OEO
35:06
A8.62E4
2. 7E4
2.2E4
11.6E4
1.1E4
5.5E3
A7.00E3
A8.61E3
A1.30E4-
A8.79E3
O.OEO
35:06
35:06
.5.2E5
.4.1E5
.3. 1E5
.2.1E5
.1.0E5
.O.OEO
Time
5.2E5
14.2E5
3.1E5
12.1E5
1.0E5
35:06
.O.OEO
Time
34130
34:36
34:42
34:48
34 : 54
35:00
35:06
5.9E6
4.7E6
13.5E6
2.4E6
1.2E6
1 O.OEO
Time
118
-------
Channel I 338.9792 Peak top
Height 3,25 volts Span 296 ppa
Systea file nae
Data file nase
Resolution
Group nmter
Ionization aode
Switching
Ref. iasses 282.3825,
ft 293 J 331
K 332
L 334
B 384
0 318
E 318
K 346
N 342
0 352
P 354
8 356
R 358
EPCUS2
fl:S985971
10696
2
EI*
VOLTRGE
416.9766
S 368
T 376
U 376
V 416
Ref. aass 416.9768 Peak top
Height .96 volts Span 208 ppa
-------
File:S975667 #1-867 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
303.9016 F:2 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A TIME
100% ( A1. 70E7
80_
60i
40j
2 0
0J
06:54 File Text:RUN 2
—i—|—i—i—|—i—j—-j—¦—i—]—i—i—i—i—i—I—i—i—i—i—i—|—i—i—i—i 'i j Pi—i—i—i—|—i—i—i—i—r—|—i—r*i—i—i—|—i—i—i i i "fi—i i i i | i—i—i—i—i—|—v'i—i—i—i—pi—r
16:24 16:36 16:48 17:00 17:12 17:24 17:36 17:48 18:00 18:12 18:24 18:36
File:S975667 #1-867 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
305.8987 F:2 Exp:EPCUS
Sample Text : RUN 2 TLI#42930A ...... .. INJ.^ TIME
100% Cj^2•05E7 i
80,
60
40j
20j
06:54 File Text:RUN 2
t—i—|—i i i—i—r-i—i—I—i—i—r—i—i—i—i—i—r—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—j—r
16:24 16:36 16:48 17:00 17:12 17:24 17:36 17:48 18:00 18:12 18^24 18136
File:S975667 #1-867 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
315.9419 F:2 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME = 06:54 File Text:RUN 2
100% 16:50 17,40 18-02
~i—1—I—I—|—I—I—I—1—f—|—I—r*~r—i—i—j—i—i—i—i—< "pi—i—i—i—) | t ~r""» i—r"i—f~~"l I I—r
TLI#42»
.7 . 1E6
.5. 7E6
.4.3E6
.2 . 9E6
-1.4E6
0.0E0
Time
TLI#4 2»
..8 . 7E6
16.9E6
.5.2E6
i3.5E6
-1.7E6
lO.OEO
Time
TLI#42»
80j
60i
40
20 j
0
17 :33
17 :04
17 : 1
16 :29
16:20 1 a « 16:42
^—(—l—f—(——|—|—i—j—i—j—j—i—»—i—t i—(—i—i—i—i—j—i—i—i—i—i—|—i—i—r—i—i—|—r -r—i—i—r~p'T—i— t—i—r—]—i—r—r ~i —r " j—r—t—i—i—r~i—r—r—t—r~i—j—i—i—r—t—i—i—i—r
16:24 16:36 16:48 17:00 17:12 17:24 17:36 17:48 18:00 18:12 18:24 18:36
6
6E4
Ls
3E4
i4
0E4
i2
7E4
vl
3E4
: 0
0E0
Time
ro
1 o
-------
File:S975667 #1-867 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
303.9016 F:2 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME =
100%
06:54 File Text:RUN 2 TLI#42»
_8.6E6
(PA . 68E7.V
6 . 9E6
5 . 1E6
l3.4E6
1 .7E6
0 .0E0
19:00 19:12 19:24 19:36 19:48 20:00 20:12
20:24 20:36 20:48
Time
File:S975667 #1-867 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
305.8987 F:2 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A
100%
80i
60 J
40J
20J
INJ. TIME =
0.
06:54 File Text:RUN 2 TLI#42»
1 .1E7
5.50E7)
T—i—i—i—[—i—i—i—i—i—l—T I I I I I—I—I—i—i—I—| I l I i—i—i—i—i—i—r^T—[—n—i—i—i—i—j—i—i—r
19:00 19:12 19:24 19:36 19:48 20:00 20:12
File:S975667 #1-867 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
315.9419 F:2 Exp:EPCUS
Sample Text:RUN 2 TLI#42 930A INJ. TIME =
1004
8 . 5E6
l6.4E6
i4.2E6
~_2 . 1E6
0 . 0E0
20:24 20:36 20:48
Time
06:54 File Text:RUN 2 TLI#42»
9 . 1E4
l7.3E4
l5.5E4
l3.6E4
19:16 i
1. 8E4
19:40
20 :31
20 : 44
19:52 20:04
20:23
19 :06
9:35
n—i—r~"r—i—i—i—i—i—| r*" i—i—r—i—i—i—i—i—?—i—|—i—i—i—i—i—|—i—i—i—i i |—i—i—i—t—i—|—i—i—r
19:00 19:12 19:24 19:36 19:48 20:00 20:12
t—i | r i i—i—i—|—i—i ~i i—i—| t i—t~® • 0E0
20:24 20:36 20:48 Time
-------
0.
16
16:31
—T f i
• I I *'
20:. .9
20
W
02
17
File :S975667 #1-867 Acq: 5-SEP-97 06 FBI: 42~'£l+ Voltage SIR TDS
319.8965 F:2 Exp:EPCUS
Sample Text;RUN 2 TLI#42930A INJ. TIME = 06:54 File Text:RUN 2
ioii i6:W in i n n fi nni p
80
60 j
40
20s
24:22
t r—i—r—r—| r 1 ?—*i --y—i 1—r "i r~j—r—r—i 1—i—
20;00 21:00 22:00 23:00 24:00 25
16:00 17:00 18:00 19:00
File:S975667 #1-867 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
321.8936 F:2 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME = 06:54 File Text:RUN 2
2, 19
TLI#4 2»
_6.5E4
5 . 2E4
:3,9E4
-2.6E4
_1.3E4
_0.0E0
00 Time
1004
80i
60i
4Qj
20i
(ii
16
o
o
17:59
18 :4
16:41
y
u
Iai
n—i i—i—j—i—i 1—i 1—|—i r~
20:00 21:00 22:00
VA/I I
24 :22
23:0623:
TLI#42»
.6 . 7E4 (.
5.3E4
4.0E4
2.7E4
1.3E4
0-. 0E0
2 3:00 ' ' 24:00 ' 25:00 Time
17:00 18:00 19:00
File:S975667 #1-867 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
331.9368 F:2 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME = 06:54 File Text:RUN 2 TLI#42»
16:31
19:50
20 :29
17:57
18:31
2 .3 E4
23 :48
1.9E4
21: 1C
1.4E4
19:04
9.3E3
7 :08
14 , 7 E3
i t t—i r—l—r—i—i—t—i—r— ~i—t 1—i—t~—|—i r—r~T 1 1—j—\~"i—t—i—| 1 1— r~ i—i—-j—i—
16 00 17:00 18:00 19:00 20:00 21:00 22:00
23 : Oo"T ' ' 24l 00~
0.0E0
25 : 00 Time
S'L-
»ro
-------
File:S975667 #1-867 Acq:5-SEP-97 06:51:42 EI+
319.8965 F:2 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A
100%
Voltage SIR 70S
INJ. TIME
06:54 File Text:RUN 2
TLI#42»
_2,6E5
i2.1E5
(^jj26E6
1.6E5
1.0E5
i5.2E4
19:00 20:00 21:00
File:S975667 #1-867 Acq:5-SEP-97 06:51:42 EI
321.8936 F:2 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A
100%
22 :00
Voltage SIR 70S
INJ. TIME
23 :00
06:54 File Text:RUN 2
0 .0E0
Time
TLI#42»
.2.9E5
i2.3E5
A1.69
11.8E5
11.2E5
15.9E4
19:00 20:00
File:S975667 #1-867 Acq:!
331.9368 F:2 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A
21 :00
SEP-97 06:51:42 EI+
100%
80 J
60i
40i
20_
0 :
19
00
22 : 00
Voltage SIR 70S
INJ. TIME
21.43
23:00
06:54 File Text:RUN 2
20:00
-! [ r
21:00
22:00
23 :00
0.0E0
Time
TLI#42»
_2 . 0E6
.1. 6E6
.1.2E6
7 . 8E5
:.3 . 9E5
0.0E0
Time
-------
File:S975667 #1-867 Acq:5-SEP-97 06751:42 EI+ Voltage SIR 70S
339,8597 F:2 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME
100%
06:54 File Text:RUN 2
TLI#42»
_1.5E6
1 .2E6
8 , 9E5
(£,2 . 05 E6
5.9E5
3 . 0E5
i—i—i—1—i—i—i—j—i—i—i—i—i—i—i—|—i—i—i—i—i—|—i—i—i—i—i—j"i >* "I—i—r-j—i—r~i—i—i—|—i -1 ¦ t—i—i—|—?—i—i—i—I—|—i—i—r—i—i—i—i—i—i—j i i t 1"f'T i—f®
24:30 24:36 24:42 24:48 24:54 25:00 25:06 25:12 25:18 25:24 25:30 25:36 25:42
File:S975667 #1-867 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
341.8567 F:2 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME = 06:54 File Text:RUN 2
100%
0.0E0
Time
TLI#42»
.9 . 8E5
7 . 8E5
5 . 9E5
3.9E5
2 . 0E5
i—I—I—I—i—i—i—i—i—j—t—i—i—*—i—i i—r~i—it—|—r—i—\ 7 TT" 1 tI i*"T"t ¦ 'I "t"
24:30 24136 24:42 24:48 24:54 25:00 25:06 25:12 25:18 25:24 25:30 25:36 25142
File:S975667 #1-867 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
3 51.9000 F:2 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME = 06:54 File Text:RUN 2
100% 25;04
80s
60s
40 J
20
0.
i r'T | i" i i i i | i i t i i ¦ | r i i t i f »
I j I I J I I
~j—i—r j i i j i til—i—p-1—rr;fi—|—i—i—fiiti—i i i r i "1 T r* i i i—i—r
24:30 24:36 24142 24:48 24 154 25:00 25:06 25:12 25:18 25:24 25:30 25:36 25:42
.0 . 0E0
Time
TLI#42»
.2.3E6
-1.8E6
.1.4E6
-9.2E5
A . 6E5
-0 . 0E0
Time
ro
-------
File:S975667 #1-867 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S"
339.8597 F:2 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A
100%
, PJJ . TIME
72E6 J
06:54 File Text:RUN 2
TLI#42»
1.5E6
l1 . 2E6
18.9E5
L5.9E5
i3.0E5
24 00 24:12 24:24 24:36 24:48 25:00 25:12 25:24 25:36 25:48 26
File:S975667 #1-867 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
341.8567 F:2 Exp:EPCUS
Sample Text: RUN 2 TLI#42930A _ IN J. TIME = 06:54 File Text : RUN 2
100% / \ CA3 . J7e6 )
80J
lO.OEO
00 Time
TLI#42»
9.8E5
l7,9E5
5 . 9E5
3 . 9E5
2 . 0E5
—i—t—i—r—I—I—i—I—i—I—I—i—f*=i—i—I—I—i i—t—I—i—j—i—I—i—i—i—I < I r' 'I—j—i—I—i—i—r—-i—I—1 T"~F"' f I1 J l^r »—j—i—n—r—t—i-
24-00 24:12 24:24 24:36 24:48 25:00 25:12 25:24 25:36 25:48 26
File:S975667 #1-867 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
3 51.9000 F:2 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME
100% 25;04
80j
60i
40i
20j
0—1—,—,—,—,—I ¦— I—I—I—I—I—j—I—I—I—I—I—I—I—I—1—1—I—[—I—i—i—I—I—f2—i—i—i—i i j1 'l ' ¦—I—f " i T r I i—i—i—rT f -1—I—r-*-i—]—I—T—T—T-" 'I"
24 00 24:12 24:24 24:36 24:48 25:00 25:12 25:24 25:36 25:48 26
06:54 File Text: RUN 2
25:49
0.0E0
00 Time
TLI#42»
-2.3E6
.1.8E6
H1.4E6
9 . 2E5
4 , 6E5
-0.0E0
00 Time
-------
File:S97 5667 #1-867 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 7HS
355.8546 F:2 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME
100% 24:21
06:54 File Text:RUN 2
TLI#42»
5 . 4E5
- 4.4E5
_3.3E5
25 ; 23
25:40
24 : 51
l2.2E5
26 :41
il.1E5
23 00 24:00 25:00 26:00
File:S97 5667 #1-867 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
357.8516 F:2 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME =
06:54 File Text:RUN
0 . 0E0
Time
2 TLI#42»
_3.5E5
25:05
100%
:2.8E5
12.1E5
25 :24
24:51
il.4E5
26 :41
1.7 .0E4
25:51
JX
23:00 24:00 25:00 26
File:S975667 #1-867 Aeq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
367.8949 F:2 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME
100%
80.:
60i
40i
20
0j
26
06:54
10
File Text:RUN 2
23 :00
24 :00
25 :00
26 !00
yV
27 : 00
0.0E0
Time
TLI#42»
_1.0E6
8 . 2E5
^6.1E5
.4.1E5
.2 . 0E5
0 .0E0
Time
ro
-------
File:S975667 #1-867 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
3 55.8546 F:2 Exp:EPCUS
Sample Text;RUN 2 TLI#42930A INJ. _TIME.
06:54 File Text:RUN 2 TLI#42»
.2E5
1001
'1.8E5
.1. 3E5
l8.9E4
4 . 5E4
i i—i—i—i—r ? - i—r—i—r
25:00 25:06 25:12
-i—i—i—i—i—i—i—j—i—|—i—i—r
25:18 25:24
r I 1 j I t -r , r -r - , J—
25:30 25:36 25:42
File:S975667 #1-867 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 7 0S
357 . 8516 F:2 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME
* 3E5"'
i—r'i • •[—-i—i—i—i—i—|—t—i—i—i—i—|—i—!*"¦ ® • 0^0
25:48 25:54 26:00 Time
06:54 File Text:RUN 2 TLI#42»
1.4E5
100%
1.1E5
18.2E4
5.5E4
l2,7E4
25 :00 25:06 25 :12 25118 25:24 25 :30 25 i 36 25:42
File:S975667 #1-867 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
367.8949 F:2 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME =
100%, A k 25:42
80 J
60
40
20 j
—i—i—i—i—r*
25:00 25:06
j~~i—i—i—i—>—j—i—i—i—i—i—I—i—
25:48 25:54 26:00
.0 . 0E0
Time
_i—!—.—,—,—,—,—,—|—,—f—i—i—i—|—i—|-
25:12 25:18 25:24
~l—I—|—I—I—I—I—l—|—l—I—I—l—i—|—l—r-
25:30 25:36 25:42
06:54 File Text:RUN 2 TLI#42»
1. 0E4
l8.1E3
6 . 1E3
14.1E3
2 . 0E3
0 ,0E0
25:48 25:54 26i00' Time
t—r—i—|—i—t—i—i—r—j—r—i—i—i—r—|—r
• ro
-------
File:S975667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
373.8208 F:3 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME
100%
80 J
60 J
40
20j
0j
7:29
\J
06:54 File Text:RUN 2 TLI#42»
1 . 3E5
T T*
28 :15
1.0E5
28:04
l7.7E4
29:01
27:56
15.1E4
29 : 58
2 . 6E4
30:24 30-41
29:30
28:00 29:00 30:00
File:S975667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
375.8178 F:3 Exp:EPCUS
Sample Text .-RUN 2 TLI#42930A INJ. TIME = 06:54
100%
80
60
40 j
20
Oj
28 :04
27 :56
3:20
JlAlkJ
29,13
29:00
28:49
29 : 59
0 . 0E0
Time
File Text:RUN 2 TLI#42»
8 . 5E4
..6.8E4
:5.1E4
3 . 4E4
l1.7E4
30:47
' 28:00 "" 29:00 30:00
File:S975667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
383.8639 F:3 Exp-.EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME = 06:54
100%
80
60j
40J
20
0
29
12
29 : 55
_1 (
28 : 00
J-r
^'i ¦
.0.0E0
Time
File Text:RUN 2 TLI#42»
,_7 . 9E5
6 . 3E5
t_4 . 8E5
3 . 2E5
L1.6E5
29:00
30 : 00
L0.0E0
Time
1 h-t
ro
-------
File:S975667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
373.82 08 F:3 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME =
100%
06:54 File Text:RUN 2
TLI#42»
_1.3E5
1. 0E5
17.7E4
5 . 1E4
A8.9
i2.6E4
A3 . 52
, , , , , 1 1 f-=—r
28:48 29:00
30 : 00
30 :12
29:12 29:24 29:36 29:48
File:S97 5667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
375.8178 F:3 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME = 06:54 File Text:RUN 2
100%
0 . 0E0
Time
TLI#42»
8 . 5E4
6.8E4
5 . 1E4
A7 .9
3 . 4E4
1.7E4
30:00
30 : 12
28:48 29:00 29:12 29:24 29:36 29:48
File:S975667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
383.8639 F:3 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME = 06:54 File Text:RUN 2
100% 2 9 l12
80 z
60J
40 J
20j
oJ
I 1 1
28 :48
P.-!" I"*"
29 :00
29 : 55
29 :12
-r—I—l_
29 :24
» t i—| ¦ r i "i
29:36
—'—I—r-=r
29:48
-1 1 -1 r- 1 1 r—I r-
30:00 30:12
0 . 0E0
Time
TLI#42»
.7 . 9E5
.6 . 3E5
.4 . 8E5
.3 . 2E5
.1.6E5
.0.0E0
Time
-------
File:S975667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
373.8208 F:3 Exp:EPCUS
Sample Text: RUN 2 TLI#42 930Av__^^
100% <^ft3753EV
INJ. TIME = 06:54 File Text:RUN 2
TLI#42»
^1.3E5
i1.0E5
7 . 7E4
5.1E4
2 . 6E4
A3 . 52
28:48
1 1 1 1 1 1 1 1 r
29 :00
29:12
INJ. TIME = 06:54 File Text:RUN 2
t 1 1 1 1 1 1 r—i 1—^ t 1 n—r-—i p
29:24 29:36 29:48 30:00 30:12
File:S975667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
3 7 5.817 8 F:3 Exp:EPCUS
Sample Text:RUN 2 TLI#4293 0A
100% >
80
60j
40J
20j
0_:
0 . 0E0
Time
TLI#42»
.8 . 5E4
6 . 8E4
5 . 1E4
3 . 4E4
A3 .2
1.7E4
30 : 12
28:48 29:00 29:12 29:24 29:36 29:48
File:S975667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
30 :00
383.863 9 F:3 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A
100% 29:12
80j
60i
40j
20j
0
28:48
1" rr'
29 :00
29:12
INJ. TIME = 06:54 File Text:RUN 2
29 : 55
I n | I " I ' I 1 I | I1
29:24 29:36
—|' 1" 1 * —r 1 r
29 : 48
30:00
li"T=—i r
30 : 12
.0 . 0E0
Time
TLI#42»
J . 9E5
-6 . 3E5
A . 8E5
.3 .2E5
_1.6E5
.0 . 0E0
Time
' CO
o
-------
File:S975667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
373.8208 F:3 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME =
100%
80J
60J
40
20 j
0
06:54 File Text:RUN 2
TLI#42»
.4 . 1E4
l3.3E4
l2.5E4
A3 .52
Ll.6E4
- 8.2E3
29 :24
29 :36
29 :48
30 :00
30 : 12
30 :24
30:36
30:48
/\v\a°VAA^
File:S975667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
375.8178 F:3 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME = 06:54 File Text:RUN 2
100%
0 . 0E0
Time
TLI#42»
.3 . 8E4
i3.0E4
2 . 3E4
1.5E4
7 . 6E3
29:36
29:48
30 :00
30 :12
30 :24
30:36
30 :48
29:24
File:S975667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
383.8639 F:3 Exp:EPCUS
Sample Text:RUN 2 TLI#4293 0A INJ. TIME = 06:54 File Text:RUN 2
100% 29:55
80j
60j
40
20
0
—=r—=—I 1 1—I 1 1 1 r 1 "I I I | r"=n 1 1 1 jT^T' T**1—T—-] 1—=r™l f" I ¦f - I—
29:24 29:36 29:48 30:00 30:12 30:24
-i—i—| i'"i—r i f |—r—r1" i
3 0:36 30:48
0 .0E0
Time
TLI#42»
.7 . 3E5
.5.8E5
.4 . 4E5
.2 . 9E5
.1.5E5
.0.0E0
Time
' I—4
¦¦CO
-------
File: S975667 #1-425 Acq:"5-SEP-97 06:51:42 EI+ Voltage SIR 70S
373.8208 F:3 Exp:EPCUS
INJ. TIME
Sample
100%
f
80j
60j
40.;
20j
0;
06:54 File Text:RUN 2
TLI#42»
_ 4.1E4
3 . 3E4
2.5E4
1.6E4
8 . 2E3
T 1 J 1 T~
-j—i—i—i—r—T" i—r—r i—r-
06:54 File Text:RUN 2
29 00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48
File:S975667 #1-425 Aeq;5-SEP-97 06:51:42 EI+ Voltage SIR 70S
375.8178 F:3 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME
100%
80J
60s
40j
20 J
Ol
29
(A7.89E4)
i ¦ •;—i—i—i—|—i—i—i—i—i—[—i—r—i r I 1—r—I—r—i—i—j—I—*—I—I—i—|—i—i—i—i—i—|—1—i—»—i—r—j—i—i—i—r—i—i—i—i—i—i—i—-j—i—r—I—i—r~
00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48
File:S975667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
383.8639 F:3 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME
100% f\ 29; 55
80s
60
40
20 j
0
06:54 File Text:RUN 2
r**i i "T i—I—i—iT^i—i~"*i—i i i i i [ r i '"'"i "i r—| i ¦ i—r—>—i r" i—r°-]—i *i i riM i ir|—i—i—i—i—i—pT—, t-t r i—r—r
29.00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48
O.OEO
Time
TLI#42»
_3 . 8E4
.3.0E4
.2.3E4
.1.5E4
,7 . 6E3
-0.0E0
Time
TLI#42»
7 .3E5
-5.8E5
.4 . 4E5
.2 . 9E5
.1.5E5
.0.0E0
Time
I CO
.*\3
-------
File:S975667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
389.8156 F:3 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME =
100%, n (11 n 29; 43
06:54 File Text:RUN 2 TLI#42»
.1.3E5
1.0E5
l7.6E4
>8:58
5 . 1E4
2 . 5E4
30:08
28 :23
30:31 30:49
27 :50
0 .0E0
29:00
28:00
3 0:00 Time
File:S975667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
391.8127 F:3 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME = 06:54 File Text:RUN 2 TLI#42»
100%
80
60j
40 J
20i
0
27:58
29 : 43
28:58
29 : ::o
30:02 30:21
30 : 50
9 . 7E4
i_7 . 8E4
L5.8E4
i_3.9E4
Ll.9E4
0 .0E0
Time
28:00 29:00 30:00
File:S975667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
401.8558 F:3 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME = 06:54 File Text:RUN 2 TLI#42»
100% 29: 2it) 29 42
80 J
60
40j
20J
0
'i i • •] 1 *i
28:00
U I
29:00
30:00
1.1E6
18.6E5
-6.4E5
l4.3E5
l2.1E5
.0 .0E0
Time
t
CO
-------
i—i—|—i—i—i—i—i—j—i—i—i—i—i—j—i—i—i—r—i—r—r"i—I—ri—r—r—i—I I—J—j—I i i—ri—|—r i t it—t i t t t—i—i—i—r~ t~x j—i—ri—t~i t t—r
28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48
File:S975667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
391.8127 F:3 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME = 06:54 File Text:RUN 2
100% 1 29:43
File: S975667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR T0S~
389.8156 F:3 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A
100% I 1
29:43
INJ. TIME = 06:54 File Text:RUN 2
28:58
29:2 )
30:08
30:49
30:31
TLI#42»
. 1.3E5
1. 0E5
.7 , 6E4
_ 5.1E4
.2 . 5E4
0.0E0
Time
TLI# 4 2 »
9 . 7E4
7 . 8E4
28:58
5 . 8E4
29 :2
3 . 9E4
1.9E4
30:21 30:31
30:40 30:50
i—i—|—i—i—i—i—i—j—\ f"i im—i—i—i—i—r~~i—|—f—i—i—r^i—j—r—i—i—i—i—|—i—i—i—i—i—|—i—j—i—r—i—[—i—i—i—»—i—i—i—i—»—i—i—i—s—i—i—rn—pi ,,Ti—r
28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48
File:S975667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
401.8558 F:3 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A
100% 29:2
INJ. TIME
06:54 File Text:RUN 2
80^
60 J
40i
20i
0 i
29:42
-1—i i ¦ I ~i—i" i i—i—i" P r-"I—i—i—|—r r i—i—i—r i rrn—|—r~i—i—i—r^-rr r r l—|—i—I—i—m—i—i—i—i—r—1—i—r—i—i—I—i—i—l—I—i—i—I—i—i—I—i—r-
28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48
0 . 0E0
Time
TLI#42»
-1.1E6
.8 . 6E5
.6 . 4E5
.4 .3 E5
.2 . 1E5
_0 .0E0
Time
*
-------
File:S975667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
389.8156 F:3 Exp:EPCUS
Sample Text:RUN 2 TLI#4293 0A INJ. TIME =
100%
06:54 File Text:RUN 2 TLI#42»
1 .3E5
Ll.0E5
-1 . 6E4
l5.1E4
81 24
l2.5E4
0 . 0E0
-i—I—i—i—i—i—i—|—i—i—f—i—i—i—r~T—i—i—i—|—i—i—i—i—i—|—i—i—i—i—i——i—i—i i j—T-T—i—i—r-*j—r"-i—n—r""]—i——i—| ' '—i—'—'—| i '—i—r=T
28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 Time
File:S975667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
391.8127 F:3 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME = 06:54 File Text:RUN 2 TLI#42»
9 . 7E4
j
l\ I
A ^8756
E4"
\ 1
: aJV
1 1
i i i i i i i i Yi ri i i i i i i
1 1
iii i liiiiiijiiiiii T7*^i i i iT*i i i i i i i i i i i i i i i i i i r*
.1. 9E4
.0 . 0E0
28:48 29:00 29 i12 29 i 24 29136 2 9 i 48 30:00 30:12 30 i 24 3 013 6 30 i 48 ' Time
File:S975667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
401.8558 F:3 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME = 06:54 File Text:RUN 2 TLI#42»
100% 29: 2CV\ 29i42 .-1.1E6
80J A I \ L8.6E5
60J Ml -6•4E5
40J 1 I I 1 i-4 .3E5
20.: J V \ / \ ~2' 1E5
0 — ¦ I I m. ,¦ I ^ —i-'l P1 I ¦ I '"I ¦ I ¦ r— r I 1 1 1 f l" *T~* I* "I 1 I r - T ¦ I ¦Vv1 I"11 I1 f* r 7 I - I * I "I"1 I "I I" I" I T*' I 1 I I ¦! I I 1 I 1' ^ I 1 I mt I 1-1 ^ • 0 E 0
-r-1—i ¦ | ™i—r i n—i—[Til—i—i—|—r*T i—i—i—j—« T T r I j—r-1—i—i—i1 y r r r r 1 |—i—i—i—I—I—j—i—rn—i ni |——r—i—i—| i i i i i |—i i i—i—r
28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 Time
i
-------
File:S975667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
389.8156 F:3 Exp:EPCUS
Sample Text: RUN 2 TLI#42930A_. ^
100% (Rl^)7E6)
80j
60i
40
20
0
INJ. TIME = 06:54 File Text:RUN 2
A9 .81E;
f 'i"¦ r t r r-~i—T*
29:00 29:12
File:S975667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
391.8127 F:3 Exp:EPCUS
Sample Text: RUN 2 TLI#42930A_. INJ. TIME =
100%, fA9\00E5>
A8.56
29:00
29 :12
v 1 i T ["• r—i—i—i—f—~t—r—|—i—r—i—i i "i 1—i—r—r—i 1-11 ~i
29124 29:36 29:48 30:00 30:12 30:24
06:54 File Text:RUN 2
80j
60 J
40 J
20i
0.
29 :20
—i—i—| r~ i—i—i—i—|—i—
29:00 29:12
29:42
T—t 1 1 r
29 :24
29 :36
29:48
-r 1—i—|—i—i 1—r—i—|—i—
30:00 30:12
—i | r-
30 :24
29:24 29:36 29148 30:00 30:12 30:24
File:S975667 #1-425 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
401.8558 F:3 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME = 06:54 File Text:RUN 2
100%. 29; 24
TLI#42»
_4.2E5
:3 . 3E5
2 . 5E5
:1.7E5
_8.3E4
.0.0E0
Time
TLI#42»
-3 . 9E5
_3 . 1E5
.2 . 4E5
.1.6E5
.7 . 9E4
.0 .0E0
Time
TLI#42»
.1.2E6
_9.4E5
.7 . 1E5
A .7E5
.2 . 4E5
.0 .0E0
Time
' CO
CT)
-------
File:S975667 #1-390 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
407,7818 F:4 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME
100% 31;22
06:54 File Text:RUN 2 TLI#42»
8.5E4
6.8E4
5.1E4
31:41
3.4E4
1.7E4
33 :07
32:25
33:22
33 :53
32 :44
32:00 33:00
File:S975667 #1-390 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
409.7789 F:4 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME
100% 31:22
34 :00
0.0E0
Time
06:54 File Text:RUN 2 TLI#42»
6.6E4
5 . 3E4
4.0E4
12.7E4
31:14
1,3E4
34:01
32:37
33 :50
33 :04
33 :20
32:00 33:00
File:S975667 #1-390 Acq:5-SEP-97 06:51: 42 EI+ Voltage SIR 70S
417.8253 F:4 Exp:EPCUS
34 : 00
.0.0E0
Time
Sample Text:RUN 2 TLI#42930A
100%, 31:21
80
60j
40i
20
INJ. TIME
Oj
32:32
L
06:54 File Text:RUN 2 TLI#42»
A . 0E5
.3 . 2E5
.2 . 4E5
.1.6E5
-8.0E4
32 : 00
~f=--
33 :00
34 : 00
-0.0E0
Time
¦*5
-------
File:S975667 #1-390 Acq: 5-SEP-97 06:51:42 EI+ Voltage SIR TCJS-
407.7818 F:4 Exp:EPCUS
Sample Text:RUN 2 TLI#42 93 0A INJ. TIME
100%, (A2 . 99E5-J
31:12 31118 31:24 31:30 31i36 31142 31:48 31154
File:S975667 #1-390 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
409.7789 F:4 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME
100% I I 1 I I 1 I I I
¦—1—1—1—1—[*-i—1—1—1—1—|—1—1—1—1—1—p»—0 • 0E0
32:00 32:06 32:12 32:18 Time
06:54 File Text:RUN 2 TLI#42»
A . 0E5
.3 . 2E5
.2 . 4E5
.1.6E5
.8 . 0E4
1 f 1 1 , (! j.
1 *n—1—r"T —1—1 "1 I 1—f
rT^"l' TrT I
-1—I > 1 r 1 i"~ t" 1 1—1—f—r
L0.0E0
31:12 31:18 31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 Time
1 CO
OO
-------
File:S975667 #1-390 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
457.73 77 F:4 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A
100%.
INJ. TIME =
d_A7 ! 64 E J)
06:54 File Text:RUN 2
TLI#42»
2 . 6E4
2 . 1E4
L1.6E4
il.lE4
5 . 3E3
34:00 35:00
File:S975667 #1-390 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
459.7348 F:4 Exp:EPCUS
Sample Text: RUN 2 TLI#42930A _INJ . TIME
06:54 File Text:RUN 2
0.0E0
Time
TLI#42»
^2 .7E4
i2.2E4
-1.6E4
"1.1E4
i5.5E3
34:00 35:00
File:S975667 #1-390 Acq:5-SEP-97 06:51:42 EI+ Voltage SIR 70S
469.7779 F:4 Exp:EPCUS
Sample Text:RUN 2 TLI#42930A INJ. TIME
100% 34 ; 38
80
60j
40j
20j
0
06:54 File Text:RUN 2
34 :00
35 :00
0 .0E0
Time
TLI#42»
.5 . 2E5
i4.1E5
:.3 . 1E5
2 . 1E5
1.0E5
l0.0E0
Time
to
-------
I
Eastern Research Group
| TLI Project: 42930A
¦ Client Sample: RUN2
I
I
Method 23 TCDD/TCDF Analysis (DB-225)
Analysis File: X973014
Client Project:
Sample Matrix:
TLI ID:
Iron & Steel-Youngstown
M23TRAIN Date Received:
179-98-2A-D Date Extracted:
Date Analyzed:
08/19/97
08/25/97
09/06/97
Spike File:
ICal:
ConCal:
SFC2NF04
XF24087
X973009
Sample Size:
Dry Weight:
GC Column:
1.000
n/a
DB-225
Dilution Factor:
Blank File:
Analyst:
n/a
S975665
ML
% Moisture
% Lipid:
% Solids:
n/a
n/a
n/a
i Anatytes
Amt. (ng) Dt
EMPC
Ratio
RT
Flags
2,3,7,8-TCDF
5.9
0.79
23:01
—
Internal Standard
Amt. (ng) % Recovery QC Limits
Ratio
RT
Flags
l3C,:-2,3J,8-TCDF
3.4 85.1
40%-130%
0.79
23:00
—
I
I
Ratio
RT Flags
I
1
I
I
1
I
I
I
I
l3Ci2- 1,2,3,4-TCDD
0.83 22:01
Data Reviewer.
'• >-3
09/08/97
Page 1 of 1
CZNF.PSR v200. LARS 6.10,04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:55 09/08/97
14-0
-------
Initial ....Dace...
Data Review By: ±jxm Calculated Noise Area: n/a
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No. 1
09/03/97
Listing of X973014B.db£
Matched GC Peaks / Ratio / Ret. Time
Confound/
M_Z.... QC.Log Omit Why
,RT. OK 'Ratio Total.Area,.. Area.Peak.1., Area.Peak.2.. Rel.KT Compound.Name.. ID.. Flags.
TCDF
304-306
304-306
13C12-TCDF
316-318
0.
65-0.89
0.798-1.102
DC
NL
0: 00
RO
1.30
14.69
0.000
18:23
RO
6.35
512.29
1.981.38
289.43
0.799
18: 52
RO
1.02
14.410.95
3,286.31
3.141.78
0. 820
19:06
RO
0.44
72.68
31.62
72.18
0.830
19:15
RO
0.61
113.95
49. 57
81. 32
0. 337
19:19
RO
0.41
98.13
42.69
103.72
0.340
19:45
0.76
23.260.70
10,013.70
13,247.00
0. 359
19:52
0.78
13,088.96
5.751.67
7,337.29
0.864
20: 01
0.32
18.513.62
8,342.92
10,175.70
0.370
20:09
0.78
12.966.36
5,670.97
7,295.39
0.376
20:26
0.31
10,421.10
4.663.45
5.757.65
0.383
20:33
0.78
19,571.07
8.567.57
11,003.50
0.893
20:41
0.77
8,370.95
3, 645.50
4,725.45
0.399
20: 50
0.77
36,226.10
15.733.30
20.492.30
0.906
20: 53
0.78
7.453.51
3,277.42
4,131.19
0.912
21:20
RO
0.49
21,194.60
9,220.25
18,773.40
0.928
21: 31
0.85
95.81
44.14
51.67
0.936
21:45
0.78
21,621.14
9,452.74
12,168.40
0.946
21: 53
0.77
12,816.98
5,537.11
7.229.87
0. 955
22: 11
0.77
13,720.60
5,970.33
7,750.27
0.964
22:22
RO
0.91
1,010,88
522.16
571.12
0.972
22:31
0.81
9,611.90
4,238.32
5,323.53
0. 979
22: 54
0. 30
7,734,35
3,428.55
4.305.80
0.996
23:01
0.79
8,954.54
3,939.72
5,014.82
1,001 23"8-TCDF
23:14
0.79
7,650.91
3,369.61
4,281.30
1.010
23:30
0.77
6,537.00
2,842.95
3,694.05
1.022
23: 33
0.77
12.386.68
5,375.87
7,010.81
1.028
24:25
0.76
5,525.22
2,381.57
3,143.65
1.062
25:09
0.74
643.95
274.40
369.55
1.093
28
Peaks
294,595.03
0
65-0.89
0.
556-1.044
DC
NL
0: 00
RO
1.83
18.62
0. 000
DC
WL
18:26
RO
1.55
36.36
0.801
DC
WL
18:44
0.83
239.37
0.814
DC
WL
19:22
RO
2.03
14.23
0.842
DC
WL
21:23
RO
2.23
4.46
0.933
DC
WL
21:45
0.73
31.37
0.946
23:00
0.79
6,316.71
2,790.26
3,526.45
1,000 13C12-2378
23:19
0.69
73.67
30.20
43.47
1.014
DC
SM
24:01
0.71
10.47
1.044
DC
WH
25:01
0. 66
49.89
1.088
DC
WH
25:26
RO
0.33
16.11
1.106
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:56 09/08/97
141-
-------
Page No. 2 Listing of X973014B.dbf
09/08/97 Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.I.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
316-313 2 Peaks 6,390.33
Above: TCDF / TCDD Follows
13C12-TCDD
332-334
332-334
DC
NL
o
o
o
RO
1 .07
7.24
0.000
DC
WL
19: 39
RO ¦
¦ 3 . 34
4.09
0.903
DC
SN
20: 25
RO
0.39
3.03
0.939
20: 41
RO
1 .02
26.51
15.22
14.98
0.951
DC
SN
21:31
0.30
12.06
0 . 989
DC
SN
21: 36
RO
0.60
4.92
0 . 993
21:45
0.79
4,472.45
1,969.22
2,
503 .23
1 . 000
22: 01
0.33
5,331.35
2,411.62
2,
919.73
1 . 012
22: 10
RO
1 .21
12.81
8.73
7.24
1.019
DC
SN
22: 17
RO
1 . 00
6.73
1 . 025
22:40
RO
0. 58
65.38
28.44
43.71
1. 042
DC
SN
22:48
RO
2 . 17
2.37
1. 048
DC
SN
22: 51
RO
2 . 60
3.49
1 . 051
DC
SN
22:57
RO
0.95
5.26
1. 055
DC
SN
23: 11
RO
5.46
4.11
1. 066
DC
SN
23:17
RO
2.29
5.43
1 . 070
DC
SN
23: 33
RO
0.49
10.69
1 . 083
DC
SN
23: 39
RO
0. 37
7 .40
1 . 087
DC
SN
23:44
RO
2 . 16
4.02
1 . 091
DC
SN
23:46
RO
1 .04
8.20
1 . 093
DC
WH
23: 54
RO
1. 55
5.72
1 . 099
DC
WH
24:20
RO
0.52
8.99
1 . 119
DC
WH
5
24: 37
Peaks
RO
0.94
4.83
9,908.50
1 . 132
13C12-12 34-TCDD RSI
Column Description.
"Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
\?ilmtXS730U leg, i-3SP-3JS'> UltbOi2$ X MI* Volkmgm 3XA XucoSpmc
303.3016 sxptzcoar_rr
saapl* Tmxttiana *LX**2930A. WiZm Tmxtt TRUUfOUt UBS
100*
-4.5X7
4.0B7
3.8X7
3.627
3.1S7
2.9X7
-2.7X7
¦2. SB7
20x01
¦2.2X7
2.0X7
20: OS
1.82 7
1.6X7
19152
1.3X7
30*41
1.1X7
9.0X6
6.716
4.5X6
2.2X6
20x24
19tOO 19tl2 19*24 19x36 19't48 20x00 20x12
Pil»:XS73014 01-1285 Acq, 6-3BP-1997 21tS0t2S OC XI* Voltmam SIX XUtaSpme
305.8987 SxptXCOBFJTT
Saaplm TmxtxXOta TLX942930X Film Tmxtt TSXJUK3LX LASS
10 OX
o.oxo
00 Time
5. 787
-5.4X7
S.2X7
4.9X7
4.3X7
'.4.0X7
3.7X7
19t45
3.4X7
3.2X7
2.9X7
20t01
20109
2.3X7
2.0X7
1.7X7
20125
1.4X7
1.1X7
LB • OJSf
-.5.7X6
-2.9X6
r I I
19i00 19x12
¦0.0X0
19i48
20:00
20t24
20i48
21 tOO Timm
-------
PUatV73014 *1-1285 Icqi S-3BP-1997 21t50i25 OC ZT+ Volbagm SIR XutoSpac Bola»t537B
303.9016 BSOB(256,30,-3.0) PXD(5,3,1, 0.10%, 21312.0, 0. 00*. V,t) BXftXCOSBJtT
Saapl* TaxtiK0N2 TLH42930X film Tmxtt TRIWOLB LABS
10 A A1.57S8
so:
so:
A9.45K7
X8.29S7
1.BB7
to:
I.5.97X7
20:
A2.38E7
O.OSO
Tim*
aotoo
21 too
23 too
24100
ao:
7.7S6
so:
5. BE6
so:
10.0B0
19 tOO
21 tOO
Timm
144
-------
PilmtX971014 §1-1385 Aeqi S-SSP-XSS7 21x50,35 X XT* Volkmgm SIR AmkoSpmaHolmmiUOBi"'
319. 8965 BSOB(2S6,3Q,-3.0) PXB(5,3,1.0.10*, 17632.0, 0. 00*,P.F) XxptXCOaPJtT
Sanvlm Tmxtt Rata TLX04293OA Film Tmxtt TXXANOLX IABS
iom
so:
60.
40:
so•:
A4.62S6
AS.31X6
Al.OSXi
^
A4.00X6
Y
*3.76X6
A4.43X6
A3.48X6
Jil.96X6
8.43X5 !
I
6.42X5
AS.17X5
f—f
23 >00
-A-
11" ""'I * 1" I1 "T ) *" I '" I1
20i00 31't00 22s 00
FilmtZ973014 81-1285 Acqt 6-SXP-1997 21t50i35 QC XX* Volfgm SIR AutoSpmc mimmt6Q70
321.8936 3Sm(256,30, -3.0} FKD(5,3,1,0.1 0*,24280. 0,0.00*, F,F) XxptXCONF_Tr
Saaplm TmxttW0B2 TLX04293OA Film Tmxtt TRXAHOLX LABS
i r* i' i
34 >00
A1.15X6
.1.8X6
.1.4X6
11.1X6
.7.1X5
13.6X5
:o.oxo
Time
loan
AS.59X6
_2.4X6
2.0X6
A4.87X6
.1.5X6
A4.05X6
AS. 57X6
A4.97X6
A 4.13X6
-9.8X5
A3.11X6
.4.3X5
AS.47X5
8.83X5
A9.76X5
I" 11 1 i1 'I i I11
20't00 21:00 22t00 33tOQ 34i00
PilmtX973014 01-1385 Aeqt 6-SXP-1997 2it50t25 OC XX* Volt*gm SIR AutoSpmc mimmtl425
327.8847 aSBB(256,30, -3.0) PXD(5,3,l,0.10*,5700.0,0.00*eF,P) ExptXCONP^TT
Smaplm TmxtiKOS3 TLX04393OA Film Tmxtt TSXAmLX LABS
20£*
80.
6o:
40.
20.
0.
20t00 2U00 22100 23 tOO 34t00
FilmtX973014 81-1285 Aeqt 6-SXP-1997 21:50t25 OC XX* Voltagm SIR AutoSpmc SaimmtSiai
331.S368 BSUB(356,30, -3.0) PX33(5,3,1,0.10*, 8734.0,0.00*,F,F) XxptXCQNFJTT
Sewpla Tmxtt«OS3 TLX04293OA Film Tmxtt TSXASK3LX MBS
A1.07S7
AS.88X6
. A4.74X6
M ^ ^ Aa f\
A2.84X6
A-
Aj
A1.25X7
-r.
100*
80.
60.
40.
20.
A2.41M7
A1.97X7
r~~r>
20t00
T.
-i 1 f \ ^ i i r—¦*
31x00 33tOO 23tOO
FilmtZ973014 01-1285 Aeqt 6-SEP-1997 21tS0t35 OC XX* Voltmgm SIR AutoSpma Bolmmt2043
333.9338 BSUB(256,30, -3.0) PXO(5,3,1,0.10*, 8173.0, 0.00*,F,P) XMptXCOHF_TT
Sanplm Tmxt tRDB2 TLX04393OA Film Tmxtt TRXABBLX LIBS
i—J r
24100
100*
80.
60.
404
20.
0.
A3.93X7
A3.50X7
20100
31 tOO
22i00
23 tOO
' ""| r
24t00
Timm
,-1.3X7
1.0X7
.7. 7X6
,5.1X6
2.6X6
:o.oxo
Timm
^7.3X6
15.9X6
.4.4X6
12.9X6
.1,5X6
.0.0X0
Tima
9.0X6
.7.2X6
5.4X6
.3.6X6
.1.8X6
0.0X0
Timm
145
-------
Pilm:X973014 01-1285 Acq: 6-3SP-1997 21:50:25 OC XI* Voltagm SIR AutoSpmc
303.9016 Xxp:XCOHF_TT
Samplm Tmxt:KON2 TLI04293OA Film Tmxt: TRIAHOLX LABS
ion
801
601
401
201
I f |' ' f". ' >¦ f | 1 * .—i1 I | i
25<00 20t00 21x00 22t00 23:00 24i00
Film:X973014 01-1285 Acq: 6-SXP-1997 21i50t25 OC XI* Voltmgm SIR AutoSpmc
315.9419 XxptXCOSFJTT
Stapla T*JCtlRUN2 TLI04293OA Film Tmxt: TRIABOLX LABS
19:00 20:00 21:00 22:00 23:00 24:00 25:00
Film:X973014 01-1285 Acq: 6-SXP-1997 21:50:25 OC XI* Voltmgm SIS AutoSpmc
319.8965 Xxp:XCONP_TT
Samplm TUtiSmn TLH42930A Film Tmxt: TRIANBLX LABS
Oj
20:50
18:52
19:45
20:33
21:20^1:45
22:11
23:01 23i2S
M a/A
24:25
-A-,
25:00
100S
801
601
401
201
OJ
23:00
" O m | i r r
i I i i i
19:00 20:00 21:00 22:00 23:00 24:00
Film:X973014 01-1285 Acq: 6-SBP-1997 21:50:25 OC SI* Vol tag* SIS AutoSpmc
331.9368 Xxp:XCOHF_TT
Sample Tmxt:ROH2 TLI04293OA Film Tmxt: TRIAHOLB LABS
10t» 22:01
21:45
25:00
i I 1 1
19:00
T
i
T
4.5S7
3.6X7
2.7X7
1.8X7
9.0X6
0.0X0
Tiam
7.6X6
6.0X6
4.5X6
,3.0X6
.1.5X6
.0. 0X0
Timm
1.8X6
100*
20:42
1.4X6
1.1X6
20:06
22:04
7.2X5
22:41
3.6X5
19: IS
23:22
_7.4X6
5.9X6
4.4X6
J2.9X6
L1.5X6
20:00 21:00 22:00 23:00 24:00 25:00
Film:X973014 01-1285 Acq: 6-SXP-1997 21:50:25 OC XI* Voltmgm SIR AutoSpmc
292.9825 Xxp:XCOSF_TT
Samplm Tmxt :BOB2 TLX04293OA Film Tmxt: TRIANBLX LABS
lOCSt
0.0X0
Timm
4.8X7
19:08 19:38 20:06 20:38
24:0524.30 'A 25:13
21:05 21:35
22:08
23:29
22:50
3.8X7
2.9X7
.1.9X7
.9.5X6
0.0X0
1—i—i—i—i—i—i—i—i—i—i i | i i—¦—i—i—|—¦—i—i—i—i—| i i—> i i |
19:00 20:00 21:00 22:00 23:00 24:00
Film:X973014 01-1285 Acq: 6-SXP-1997 21:50:25 OC XI* Voltmgm SIR AutoSpmc
330.9792 Xxp:XCOSF_TT
Samplm Tmxt:XnN2 TLI04293OA Film Tmxt: TRIASBLX LABS
25:00
100H
18:40 19:08 19:40
iSam
25:02
_5.7X7
0:10
20:52 21:22
22:01
4.6X7
0.0X0
19:00
20:00
21:00
22:00
23:00
24:00
25:00
146
-------
Volts
0.4499
Volts
0.5087
Volts
0.3712
PPM
200
PPM
200
PPM
200
330.94615 330.97925 331.01235
292.95315 292.98245 293.01175
380.93795 380.97604 381.01414
-------
TLI Project:
42930A
Method 23 PCDD/PCDF Analysis (a)
Client Sample:
RUN3
Analysis File:
S975668
Client Project:
Iron & Steel-Youngstown
Sample Matrix:
M23TRAIN Date Received:
08/19/97
Spike File:
SPX23704
TLI ID:
179-98-3A-D Date Extracted:
08/25/97
ICal:
SF56117
Date Analyzed:
09/05/97
ConCal:
S975664
Sample Size:
1.000 Dilution Factor:
n/a
% Moisture: n/a
Dry Weight:
n/a Blank File:
S975665
% Lipid:
n/a
GC Column:
DB-5 Analyst:
HLM
% Solids:
n/a
Analytes
Amt. (ng)
DL
EMPC
Ratio
RT
Flags
2,3.7,8-TCDD
0.44
0.73
21:52
1,2,3,7,8-PeCDD
0.95
1.39
26:14
1,2,3,4,7,8-HxCDD
0.19
1.31
29:22
1,2,3,6,7,8-HxCDD
1.6
1.30
29:27
1,2,3,7,8,9-HxCDD
0.71
L.13
29:45
PR_
1,2,3,4,6,7,8-HpCDD
0.85
0.95
32:12
1,2,3,4,6,7,8,9-OCDD
0.47
0.78
34:40
—
2,3,7,8-TCDF
41.0
0.85
21:09
1,2,3,7,8-PeCDF
3.5
1.41
25:09
2,3,4,7,8-PeCDF
3.2
1.46
25:53
1,2,3,4,7,8-HxCDF
1.5
1.34
28:38
PR_
1,2,3,6,7,8-HxCDF
0.53
1.25
28:45
2,3,4,6,7.8-HxCDF
0.35
1.19
29:14
PR_
1,2,3,7,8,9-HxCDF
ND
0.2
1,2,3,4,6,7,8-HpCDF
0.38
0.95
31:23
1,2,3.4.7,8,9-HpCDF
ND
0.4
1,2,3,4,6,7,8,9-OCDF
ND
0.6
Totals Ami (ng) Number Dt EMPC Flags
Total TCDD
10.6
12
11.3
Total PeCDD
7.0
6
11.4
Total HxCDD
15.2
7
Total HpCDD
2.6
2
Total TCDF
381
15
393
Total PeCDF
53.2
13
54.9
Total HxCDF
5.8
9
6.2
Total HpCDF
0.38
1
Page 1 of 2 X237.PSR vioo. LARS 6.10 04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 16:39 09/08/97
148
-------
I
TLI Project: 42930A
Client Sample: RUN3
Method 23 PCDD/PCDF Analysis (a) |
Analysis File: S975668
internal Standards
Amt {ng)
% Recovery
QC Limits
Ratio
RT
Flags |
l3C 12-2,3,7,8-TCDF
3.7
92.0
40%-130%
0.75
21:07
i3Ci2-2,3,7,8-TCDD
3.5
86.4
40%-130%
0.88
21:51
l3Ci2-l,2,3,7,8-PeCDF
2.4
60.2
40%-130%
1.69
25:09
13C.:-1,2,3.7,8-PeCDD
1.9
47.4
40%-130%
1.43
26:14
l3Cn-l,2,3,6,7,8-HxCDF
4.5
112
40%-130%
0.48
28:45
1JCi2-1,2,3,6,7,8-HxCDD
3.8
94.6
40%-130%
1.24
29:26
13C)3-1,2,3,4,6,7,8-HpCDF
2.6
65.0
25%-130%
0.44
31:22
13Ci3- 1,2,3,4.6,7,8-HpCDD
2.8
69.5
25%-130%
1.03
32:12
!3C;2-1,2,3,4,6,7.8.9-OCDD
4.2
52.4
25%-130%
0.87
34:39
—
Surrogate Standards (Type A)
Amt. (og)
% Recovery
QC Limits
Ratio
RT
Flags |
57CU-2,3,7,8-TCDD
3.6
89.5
70%-140%
21:52
13Ci:-2,3,4,7,8-PeCDF
2.8
70.1
70%-140%
1.59
25:52
13C! 2-1,2,3,4,7,8-HxCDF
3.4
85.1
70%-140%
0.49
28:39
l3Gr 1,2,3,4,7,8-HxCDD
3.8
95.3
70%-140%
1.23
29:21
l3C-,r 1,2,3,4,7,8,9-HpCDF
2.8
68.8
70%-140%
0.42
32:33
v
Alternate Standards (Type A>
Amt (ng)
% Recovery
QC Limits
Ratio
RT
Flags J
13Ci2-l,2,3,7,8,9-HxCDF
4.2
106
40%-130%
0.49
29:57
1!C::-2.3,4,6,7,8-HxCDF
4.2
106
40%-130%
0.48
29:14
—
13Ci2-l,2,3,4-TCDD
0.82
21:39
l3Ci2-l,2,3,7,8,9-HxCDD
1.15
29:44
I
I
I
I
I
I
1
I
I
I
I
I
I
I
I
I
I
Data Reviewer,
Si.J.
11} o
09/08/97
Page 2 of2
X237 PSR *200. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capita la Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 16:39 09/08/97
149
-------
Data Review By:
Initial ....Date...
Calculated Noise Area: 5.36
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
09/03/97
Listing of S975668B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK "Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID. . Flags.
TCDF
304-306
DC NL
304-306
0.
65-0.89
0.327-1.0!
0: 00
0. 34
10.29
0.000
17: 51
0.84
5.520.00
2,520.00
3,000.00
0.845
13:20
RO
0.92
3,997.44
2,066.61
2,258.44
0.368
18:36
0. 31
2,375.04
1,065.13
1.309.36
0. 381
19:01
0. 33
24,320.50
11,053.30
13,266.70
0.901
19: 13
0.84
15,855.86
7,220.34
8,635.02
0 .914
19:44
0.83
14,399.33
6,518.73
7,880.55
0.934
20: 01
0.32
10,846.08
4,381.90
5,964.18
0.948
20: 19
0 . 34
15,280.00
6,970.00
8,310.00
0. 962
20:41
0. 83
3,646.87
3,919.65
4,727.22
0 . 979
20:55
0.37
5,601.33
2,603.04
2,993.29
0.991
21:09
0. 35
13,442.25
6,164.35
7,277.90
1.002
21:34
0. 84
5,022.92
2,292.53
2,730.39
1. 021
21:46
0.86
2,866.30
1,325.09
1 , 541.21
1. 031
22:00
0.-7
496.57
216.17
230.40
1. 042
22:11
0.75
23 .49
10.07
13 .42
1 . 051
22:20
RO
1. 08
55.88
34. 10
31.57
1. 053
22:53
0. 31
308.25
138.38
169.87
1. 084
Peaks
129,058.11
-TCDF
AN
13C12-TCDF
316-313
316-318
0.65-0.89
DC NL 0:00 RO 10.92
DC WL 17:18 RO 18.88
21:07 0.75
1 Peak
3.82
3.45
049.28
049.28
450.42
0.952-1.048
0.000
0 . 319
593.36 1.000 13C12-237 8-TCDF ISO
Above: TCDF / TCDD Follows
TCDD
320-322
0.
65-0.89
0.1
361-1.058
0:00
RO
8.34
9.54
0.000
19:13
0.79
321.69
142.36
179.33
0.379
19:37
0.71
199.51
32.55
116.96
0. 398
19:55
0. 65
184.09
72.60
111.49
0.912
20:37
0.74
542.74
230.79
311.95
0.944
20: 55
0. 80
390.00
173.00
217 .00
0.957
21:19
0.75
169.38
72.60
96.78
0.976
21:36
0.32
191.16
86.33
104.83
0.989
21:45
0.76
220.76
95.12
125.64
0.995
21:52
0.73
103.40
43.73
59.67
1.001 2378-TCDD
21: 59
0. 68
78.09
31.60
46.49
1.006
22: 13
RO
0.92
169.48
88.04
95.75
1. 017
22:25
0.88
50.90
23.80
27 .10
1.026
22: 52
0. 81
64.60
29 .00
35.60
1.047
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 16:40 09/08/97
150
-------
Page No. 2
09/08/97
Listing of S975663S.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
320-322
37C1-TCDD
3 23
328
13C12-TCDD
332-334
332-334
imit
Why
. .RT.
OK
Ratio Total
.Area... Area
Peak,1.. Area.Peak.2..
Rel,RT Compound.Name,.
13
Peaks
2.S85.80
0.907-1.093
DC
NL
0
00
2.74
0.000
DC
WL
18
39
13.97
0.854
DC
WL
18
52
0.57
0.863
DC
WL
18
56
4.16
'0 .867
DC
WL
19
12
1.97
0. 879
DC
WL
19
16
2.65
0.882
DC
WL
19
21
1.39
0. 886
DC
WL
19
30
2.24
0.392
DC
WL
19
37
5.44
0. 898
19
53
3.10
3.10
0.910
DC
SN
20
00
0.53
0.915
DC
SN
20
02
1,04
0.917
20
22
316.32
316.32
0.932
20
37
4.99
4.99
0.944
20:42
1.90
1.90
0.947
20
50
2.01
2.01
0.953
DC
SN
20
55
1.21
0.957
DC
SN
21
08
0.97
0.967
21
13
. 3.39
3 . 39
0. 975
21
28
1.65
1.65
0.982
DC
SN
21
: 32
0.78
0.986
21
: 52
600.62
600.62
1.001 37C1-TCDD
22
: 16
674.44
674.44
1. 019
22
: 24
2.26
2.26
1.025
22
: 45
2.57
2.57
1. 041
22
; 59
8.11
8.11
1.052
DC
SN
23
: 06
1.41
1.057
12
Peaks
1,621.86
0
65-0.89
0.907-1.093
DC
NL
0
: 00
RO
19.50
0.35
0. 000
DC
WL
18
: 47
RO
16.62
0.51
0.860
DC
WL
19
: 05
RO
3.01
1.3S
0.873
DC
WL
19
:15
RO
5.77
1.45
0.881
DC
WL
19
: 33
RO
1.78'
1.79
0.895
DC
SN
21
: 12
RO
6.18
1.59
0. 970
21
: 39
0. 82
865.00
390.08 474.92
0.991 13C12-123 4-TCDD
21
: 51
0.88
796.23
371.62 424.61
1.000 13C12-2378-TCDD
22
:12
RO
1.04
14.43
8.45 8.15
1.016
DC
SN
22
: 21
RO
1.91
1.13
1.023
DC
SN
22
: 31
RO
3.95
0.67
1.031
3
Peaks
1,675.66
S0R1
Above: TCDD / PeCDF Follows
PeCDF
340-342
1.32-1.78
DC NL 0:00 RO 0.15 0.30
DC WL 22:40 RO 0.59 31.88
23:10 1.45 1,199.36
710.41
0.910-1.076
0.000
0.901
488.95 0.921
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 16:40 09/08/97
151 "
-------
Page No.
09/08/97
3
Listing of S975663B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z....
QC.Log Omit
Why
. . RT-
OK
Ratio Total
¦Area...
Area.Peak.1.. Area
Peak. 2, .
Rel.RT Compound.Name..
23:
16
1.53
22.32
13 .49
3.33
0.925
23
25
RO
0.78
15.42
9 .37
12.01
0.931
23
52
RO
1.31
33 .38
23 .72
13.09
0.949
24
10
1. 53
542.46
327.63
214.33
0.961
24
17
1 . 51
2.951.16
1,773.59
1,177.57
0.966
24.
28
1.40
516.48
301.42
215.06
0, 973
24:
42
RO
-1.22
132.56
110.97
90.30
0.982
24:
53
1.47
307.04
480.43
326.61
0. 989
A
25:
03
1. 51
249.20
150.00
99.20
0.996
M
25:
09
1.41
577.00
338.00
239.00
1.000 12378-PeCDF
25:
19
1.45
353.44
209.45
143.99
1.007
25.
26
1.42
519.33
304.80
215.03
1.011
25
53
1.46
527.26
313.19
214,07
1.029 23473-PeCDF
26
01
1.47
415.76
247.48
163.23
1.034
26
19
SO
1 .22
40.54
24. 64
20.24
1.046
26
41
SO
1. 28
6.25
3.80
2.96
1.061
26
49
1.75
49.72
31 . 65
18.07
1. 066
340-342
18
Peaks
9.009.18
13C12-PeCDF
1
32-1.78
0.340-1,160
352-354
DC
NL
0
00
RO
0. SO
0.20
0.000
DC
SN
22
48
RO
0.55
1.83
0.907
DC
SN
23
57
RO
5.42
1.76
0.952
24
17
1.43
10.59
6.32
4.27
0.966
DC
SN
24
37
1.41
2.00
0. 979
25
09
1.69
589.76
370.28
219.43
1.000 13C12-PeCDF 123
25
52
1, 59
400.92
246.36
154.56
1.023 13C12-PeCDF 234
DC
SN
26
16
RO
0.17
0.86
1. 044
26
49
RO
0.47
4.10
2 . 49
5.33
1. 066
DC
SN
26
58
RO
3 .70
1.86
1.072
DC
SN
27
10
RO
1.15
2.58
1.030
352-354
4
Peaks
1,005.37
PeCDF /
PeCDD Follows
PeCDD
1
32-1.78
0.923-1.025
356-358
DC
NL
0
00
RO
0.30
2.42
0. 000
24
25
RO
1.21
211.29
128.43
105.89
0. 931
D DC
SN
24
39
RO
0.09
3.44
0. 940
24
55
1.34
52.61
30.10
22.51
0.950
25
09
1. 61
198.52
122.38
76.14
0.959
25
17
1.42
80.77
47.33
33 .44
0. 964
25
27
RO
1.29
78.69
47.83
36.95
0.970
M
25
43
1.40
139.00
81.00
53.00
0.980
25
56
1.35
19.14
10.93
8.16
0. 989
26
03
RO
0.27
11.68
7.10
26.50
0.993
26
14
1.39
77.93
45.31
32.62
1.000 12378-PeCDD
26
22
RO
1.22
29.60
17.99
14.30
1.005
26
44
RO
1.20
31.27
19.01
15.73
1.019
D DC
SN
26
49
RO
1.02
2.93
1.022
356-358
11
Peaks
930.50
ID. . Flags.
AH
AN
IS2
SUR2
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 16:40 09/08/97
O
15°
-------
Page No. 4
09/03/97
Listing of S975668B,dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log
Omit
Why
. -RT.
OK
Ratio Total.Area... Area.Peak.1.. Area.Peak.2. .
Rel.RT
13C12-?eCDD
1 .
32-1.78
0.:
847-1,11
368-370
DC
NL
0:00
RO
0.84
0.26
0.000
DC
SN
24:07
SO
3.S5
1.48
0. 919
DC
SN
25:09
RO
0.41
2.48
0.959
DC
SN
25: 14
RO
0. 37
0.54
0.962
DC
SN
25:31
1.47
1.78
0.973
26:14
• 1.43
260.10 152.91 107.19
1.000
26:22
1.70
24.43 15.37 9.06
1.005
DC
SN
26: 34
RO
0.26
1.65
1.013
368-370
2
Peaks
234,53
ID.. Flags -
I S3
Above: PeCDD / HxCDF Follows
HXCDF
l.
05-1.43
0.957-1.051
374-376
DC
ML
0:00
RO
0.74
3.90
0.000
27:41
1.25
60.23
33 .41
26.32
0.966
27: 50
1.26
193.86
107.99
85.37
0.971
27:58
RO
1.02
15.70
3.69
8.49
0.976
28:08
1.40
23.48
13.71
9.77
0.982
28:17
1. 36
30.72
17 . 68
13.04
0.987
N
28:38
1.34
136.98
78.52
53.46
0.999 12 3 47 8-HxCDF
AN
N
28:45
1.25
63.34
35.20
28.14
1.003 123678-HxCDF
AN
28: 52
RO
1.49
11.60
7.74
5.13
1.008
29:03
1.25
21.01
11.69
9.32
1.014
A
29: 12
RO
1.47
13.15
8.60
5.37
1.015
NM
29:14
1. 19
32.90
17.90
15.00
1.020 234673-HxCDF
AN
DC
SN
29:27
1.37
1.28
1. 023
DC
SN
29: 30
RO
3.19
0.69
1.Q30
DC
SN
29:44
RO
0.31
1.10
1.038
DC
SN
29:47
RO
2. 54
1.37
1.040
N
DC
SN
29:53
RO
1.54
1.59
1.043
M
30:01
1.26
11.16
6.22
4.94
1.048
DC
WH
30:11
RO
0.39
1.14
1.054
DC
WH
30: 19
RO
0.53
0.90
1.058
374-376
12
Peaks
614.13
13C12-HXCDF
0
43-0.59
0.860-1.140
384-386
DC
NL
0:00
RO
0.92
2.55
0,000
DC
SN
27:47
RO
0.18
0.50
0.970
N
28:39
0.49
249.21
82.39
166.32
1.000 13C12-HxCDF 478
stm3
N
28:45
0.48
305.48
99.33
206.15
1.003 13C12-HXC0F 678
IS4
28:53
RO
0.83
2.97
1.63
1.97
1.008
N
29:14
0.48
267.IS
86.59
180.57
1.020 13C12-HXCDF 234
ALT2
DC
SN
29:20
RO
0.35
3.97
1.024
DC
SN
29:29
RO
1.69
0.83
1.029
DC
SN
29: 31
0.45
2.12
1.030
DC
SN
29:42
0.52
2.39
1.037
DC
SN
29:47
RO
0.32
0.74
1.040
N
29:57
0.49
232.64
76.66
155.98
1.045 13C12-HxCDF 789
ALT1
DC
SN
30:08
0.S8
2.69
1.052
DC
SN
30:20
RO
1. 14
1.57
1.059
384-386
5
Peaks
1,057.46
PR
PR
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive * Durham, North Carolina 27713 Printed: 16:40 09/08/97
Phone: (919) 544-5729 • Fax: (919) 544-5491 . _ „
15 J
-------
Page No. 5 Listing of S975668B.db£
09/03/97 Matched GC Peaks / Ratio / Ret. Time
Compound/
X_2... . QC.Log Omit Why ..RT. OK Ratio Total.Area.., Area.Peak. 1. . Area.Peak.2., Rel.RT Compound.Name.. ID. . Flags.
HxCDF /
HxCDD
Follows
HxCDD
1.
05-1.43
0.952-1.015
390-392
DC
NL
0:00
RO
1 .01
2.28
0.000
DC
SN
28:01
RO
0.39
1. 34
0.955
28:12
1 .22
152.33
33 . 61
68.72
0.961
DC
SN
28:22
RO
. 0. 52
0.79
0.966
DC
SN
28:29
RO
2.SI
0.58
0.970
28:39
1.14
43.73
23.28
20.50
0.976
28:51
1 .25
505.01
230.87
224.14
0.983
29:00
1 .11
17.08
9.00
8.08
0.933
an
29:22
1.31
9.73
5.51
4.22
0.998 123473-HxCDD
AN
m
29:27
1, 30
98.50
55.70
42.30
1.003 123678-HxCDD
AS
DC
SN
29:35
RO
0.58
1.66
1.008
K
29:45
1.13
41.47
21.99
19.48
1.014 123739-HxCDD
AN
DC
WH
29:59
RO
3.64
1.68
1. 022
DC
m
30:03
RO
0.1S
0.31
1. 024
DC
WH
30: 04
RO
0. 17
0.27
1,024
DC
WH
30:09
RO
2,25
2.06
1.027
390-392
7
Peaks
867.90
13C12-HxCDD
1.
05-1.43
0.
966-1.034
402-404
DC
NL
0: 00
RO
0. 92
2.17
0. 300
DC
WL
27:57
RO
0.32
1.21
0.952
DC
SN
28:51
1. 42
1.55
0. 933
DC
SN
29:02
1.43
1.02
0. 989
DC
SN
29:11
RO
0. 39
1.37
0. 994
N
29:21
1.23
198.27
109.42
83.85
1.000 13C12-HxCDD 473
SUR4
N
29:26
1.24
213.84
113.21
95.63
1,003 13C12-HXCDD 673
IS5
N
29:44
1.15
227.12
121.61
105.51
1.013 13C12-HxCDD 739
RS2
DC
SN
29:52
RO
2.11
1.95
1 , 013
DC
SN
30:04
RO
2.91
1.55
1.024
402-404
3
Peaks
639.23
Uv(* Fifi /
UrMTVt?
MX— UU /
jipc ut
rOiiows.
HpCDF
0
83-1.20
0.
995-1.044
408-41C
DC
NL
0:00
RO
1.90
2.14
0.000
M
31:23
0.95
19.29
9.41
9 .88
1.001 1234678-HpCDF
AN
D
DC
SN
31:43
RO
1.75
6.22
1.011
DC
SN
31:53
RO
3 . 00
0.96
1.016
DC
SN
32:20
RO
0.10
0.26
1.031
DC
SN
32:22
RO
0.72
1.79
1.032
408-410
1
Peak
19.29
13C12~HpCDF
0
37-0.51
0,
936-1.128
413-420
DC
NL
0:00
RO
2,59
0.94
0.000
31:22
0.44
130.87
40. 00
90.87
1.000 13C12-HpCDF 678
IS6
DC
SN
31:39
0.50
2.11
1.009
DC
SN
32:10
RO
1.57
2.20
1.026
32:16
RO
1.48
2.32
2.39
1.61
1 .029
32:33
0.42
69.44
20.62
48.82
1.038 13C12-HpCDF 789
SCR5
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713 Printed: 16:40 09/08/97
Phone: (919) 544-5729 • Fax: (919) 544-5491 -
154
-------
Page No. S
09/08/97
Listing of S97S668B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omi t
Why
. ,RT.
OK
Ratio Total
Area...
Area.Peak.1. .
418-420
3
Peaks
202.63
Above:
HpCDF /
HpCDD Follows
HpCDD
0
88-1.20
424-426 DC
NL
0
00
1.07
1.72
DC
WL
31
26
RO
•0.50
1.00
31
38
1 .07
59.60
30.83
DC
SN
31
55
SO
0.46
2.22
32
12
0.95
29.08
14.17
424-426
2
Peaks
88.68
0,977-1,006
0.000
0.976
28.77 0.982
0.991
14.91 1.000 1234678-HpCDD
AN
13C12-HpCDD
436-438
436-438
DC E 0
32
SN 32
DC
0.88-1.20
:00 RO 6.00
:12 1.03
:26 RO 1.58
1 Peak
0.24
128.66
1.47
128.66
65.36
0.969-1.031
0.000
63.30 1.000 13C12-HpCDD 678 IS7
1.007
Above: HpCDD / Octa-CDD and CDF Follows
OCDF
0.
76-1.02
0.884-1.116
442-444
DC
NL
0:00
RO
0.75
1.95
0.000
DC
SN
31:25
RO
0. 59
2.87
0,907
DC
SN
31:39
RO
1.S1
2.46
0. 913
DC
SN
31: 57
RO
0. 43
1.93
0.922
DC
SN
32:31
RO
2.23
1.40
0.938
DC
SN
32:38
RO
0.19
0.93
0.942
32:59
RO
0.41
3.67
1.73
4.23 0.952
DC
SN
33: 14
RO
0.40
2.51
0.959
DC
SN
33:38
RO
1,63
1.68
0.971
34:04
RO
0.66
4.84
2.28
3.45 0.983
DC
SN
34:13
0. 82
2.66
0.987
DC
SN
34:22
RO
1.74
2.51
0.992
DC
SN
34: 33
RO
0.73
2.21
0.997
DC
SN
35: 01
RO
0.37
1.49
1.011
DC
SN
35:05
RO
0. 60
1.04
1.013
35:22
RO
0. 66
6.65
3.13
4.74 1.021
DC
SN
35:39
RO
0.23
1.3S
1.029
442-444
3
Peaks
15.16
QCDD
0.
.76-1.02
0.884-1.116
458-460
DC
NL
0:00
RO
1,55
1.13
0.000
M
34:40
0.78
8.10
3,55
4.55 1.000 OCDO
DC
SN
35:12
RO
0.54
1.55
1.016
458-460
1
Peak
8.10
13C12-OCDD
0
.76-1.02
0.996-1.006
470-472
DC
NL
0:00
RO
7.10
0.19
0.000
34:39
0.87
123.56
57.36
66.20 1.000 13Ci:
470-472
1
Peak
123.56
AN
ISS
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713 Printed: 16:40 09/08/97
Phone: (919) 544-5729 • Fax: (919) 544-5491
155
-------
Page No. ~ Listing of S9"?5663B. dbf
09/08/97 Matched GC Peaks / Ratio / Ret. Time
Compound/
H_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak. 1. . Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
Column Description..... "Why" Code Description QC Log Desc.
H_Z -Nominal Ion Hassles)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
File : S975668 #1-867 Acq:5-SEP-97 07:31:00 EI* Voltage SIS 70S Noise:2345
303.9016 F-.2 BSUBf256,30,-3.0) PKD(9, 5, S, 0 . 0S\, 9380 . 0, 1. 00%, F, T) Exp-.EPCUS
TRIANGLE LABS
100*
80z
60.
40.
20.
0.
;18': 00 19:00 20:00 21:00
File:S975668 41.-867 Acq:5~SEP-97 07:31:00 SI* Voltage SIS 70S Noise:2802'
305.898 7 F: 2 BSUB(256, 30, -3.0) PKD(9, 5,5,0
TRIANGLE LABS Text-.RON 3 TLX04293OA
Text:RON 3
TLX04293 OA
A1.11E8
IKJ. TIME
07:33
A2.07E7
AA1.07E7
i _ i |
A6.16E7
A4,88E7 A3.92E7
A6.94E7
A2.29E7
22:00
1003
80A
A1.33E8
0S%,11208.0,1.00%,F,T) Exp:EPCDS
¦ INJ. TIKE - ' 07:33
A7.28E7
A7.88E7 A4.73E7
18:00 19:00 20:00 21:00
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 EI* Voltage SIM 70s Noise: 11797
315.9419 F:2 BSOB( 256, 30 ,-3 . 0 ) PKD(9 , S, 5 , 0.05%, 47188 . 0, 1. 00%, F,T) Exp-.EPCUS
TRIANGLE LABS Text:RON 3 TLI04293OA INJ. TIME « 07:33
1005 A4.f0E6
22:00
A7.24E5
18:00 19:00 20:00 21:00
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 SI* Voltage SIR 70s Noise: 1081
317.9389 F:2 BSUB(256 , 30, -3 .0 ) PKD(9, 5, 5, 0.05%, 4324. 0,1.00%, F,T) Exp:EPCUS
TRIANGLE LABS Text:RUN 3 TLI04293OA INJ". TIME = 07:
1004 A5.99E6
803
6 OA
40J
20J
0J
22:00
33
A4,52E5
T
18:00 19:00 20:00 21:00
File:S975668 01-867 Acq:5-SEP-97 07:31:00 El* Voltage SIR 70S
330.9792 F:2 Exp:EPCUS
TRIANGLE LABS Text:SUN 3 TLI04293OA INJ, TIME
10 01
22:00
.2. 5E7
.2.0E7
L1.5E7
-9.8E6
.4.9E6
.0.0E0
23': 00 Time
A2. 73E7
A2.26E7
A
3.0E7
2.4E7
1.8E7
1.2E7
6.0E6
.0.0E0
23:00 Time
-1.1E6
.9.1E5
'.6.8E5
.4.5E5
L2.3E5
.0.0E0
'23 • 00 Time
.1. 6E6
il.3E6
Is, 8E5
.6.6E5
13.3E5
.O.OEO
Ui 00
Time
1.5E7
JL,2E7
9.1E6
6.0E6
3.0E6
O.OEO
18:00 19:00 20:00 21:00
Fxle:S975668 01-867 Acq:5-SEP-97 07:31:00 EI* Voltage SIS 70S
375.8364 F:2 Exp:EPCUS
TRIANGLE LABS Text:RUN 3 TLI04293OA INJ. TIME
1003,
22:00
23 : 00
Time
2.3E4
1.8E4
21:30
1.4E4
19:57
22:36
21:16
9.2E3
18:04
19:39
20:42
4.6E3
O.OEO
18:00
19:00
20:00
21:00
22:00
23:00
157
-------
File:S975668 *1-867 Acq: 5-SEP-9 7 07:31:00 EI* Voltage SIR 70S N02.se: 224 78
319.8965 F:2 BSOS(256, 30,-3.0 ) PKD( 7, 5, 3 ,0. 05%, 89912.0, 1.00%, F,T) Exp:EPCUS
TRIANGLE LABS
1001
'¦ Illlf i' S " »"11' ' ¦! ¦ >
19:00 20:00 21:00 22:00
File:S975668 »1-867 Acq:5-SEP-97 07:31:00 EI* Voltage SIR 70S Noise:2693
321.8936 F-.2 BSU3(256, 30', -3.0) PKD(7, 5 ,3 , 0 .05%, 10772.0, 1.00%, S,T) Exp:EPCUS
TRIANGLE LABS
loo:
19:00 20:00 21:00 22:00
File: S97S668 #1-867 Acq: 5-SEP-97 07:31:00 EI* Voltage SIX 70S Noise: 1950
331.9368 F:2 BSUB( 256, 30,-3 . 0 ) PKD( 7, 5, 3, 0. 05%, 7800. 0 , 1.00%, F, T) Exp-.EPCOS
TRIANGLE LASS Text:RUN 3 TLI442930A INJ. TIME = 07:33
Text:RON 3 TLI*42930A
INJ. TIME
42E6
A 8\25E5
A7.26E5
A9.51E5
A1.68E6 A7.26E5
07:33
A8.80E5
16.
JL.
r
23:00
0E5
0E5
0E5
0E5
0E5
. OEO
Time
Text.-MOW 3 TLI#42930A
INJ. TIME
07:33
A1. 79E6 a J.. 17E6
A1.26E6
A1.11E6
A9.68E5
A9.57E5
7.75E5
\A2.88E5 A
23: 00
1004
80l
60J
4 0l
20.
A3.
%56
72E6
19:00 20:00 21:00 22:00
File:S975668 §1-867 Acq:S-SEP-97 07:31:00 EH- Voltage SIX 70S Noise: 101
333.9338 F:2 BSUB( 256, 30,-3 .0 ) PKD( 7, 5, 3, 0. 05%, 404 . 0, 1. 00%,F, T> Exp:EPCUS
TRIANGLE LABS Text;RON 3 TZH42930A INJ. TIME =
23:00
07:33
100%
801
sod
401
204
A4. 7SE6
hA4.25E6
19:00 20:00 21:00 22:00
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 EI* Voltage SIX 70S Noise: 1369
327.8847 F:2 BSXTB(256, 30,-3 .0 ) PKD(7, 5 , 3 , 0.05%, 5476. 0 ,1. 00%, F,T) Exp:EPCUS
TRIANGLE LABS Text:XON 3 TLI#42930A INJ. TIME = 07:33
23 : 00
1004
Sflj
601
40J
201
A6.01E6
A6.74E6
A3.16E6
19:00 20:00 21:00 22:00
File: S975668 #1-867 Acq:~5-SEP~97 07:31:00 EI* Voltage SIR 70S
330.9792 F:2 Exp:EPCtJS
TXIANGLE LABS Text:RON 3 TLH42930A INJ. TIME = 07:33
100% 18:42 19:09 19:26 20:02 20:22 21:05 21:23 21:57
23 i 00
1ES
8E5
6E5
4E5
2E5
OEO
Time
3E6
1E6
9E5
3E5
6E5
OEO
Time
2E6
8E6
3E6
0E5
5E5
.OEO
Time
22:33
801
60J
40J
203
01
IS: 00 '
20:00
21:00
22:00
23:00
5E7
2E7
1E6
0E6
0E6
OEO
Time
158
-------
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 El* Voltage SIS 70S Noise:89
339.8597 F:2 BStJB( 256, 30, -3. 0 ) PKJ>( 7,5,3,0.05%, 356.0,1.00%, F, T) Exp:EPCVS
TRIANGLE LABS Text:RUN 3 TLI04293OA INJ. TIME = 07:33
23:00 24:00 2£:00 26:00
File:S975668 *1-867 Acq:5-SEP-97 07:31:00 EI* Voltage SIS 70S Noise:595
341.8567 F: 2 BSUB(256,30, -3.0) PKD(7, 5,3, 0.05%, 2389. 0,1. 00%, F, T) Exp-.EPCUS
TRIANGLE LABS Text:SON 3 TLI442930A \ INJ. TIME * 07:33
1002
«0J
SOj
20j
7E7
A7.10E6
3. 01E6
A4.76E6
A3.13E6
/j\ /A AA- , A A
1001
SOJ
S0J
40J
20J
A1. 18E7
A4.89E6
A2.15E6
A3.30E6
A2.14E6
/V aA A/\ Aa
23:00 24:00 25:00 26)00
File:S975668 *1-867 Acq:5-SEP-97 07:31:00 EI* Voltage SIS 70S Noise:SO
351.9000 F: 2 BSUB(256, 30,-3. 0 ) PKD( 7,5,3,0.05%, 24 0.0,1.00%, F,T) Exp-.EPCUS
TRIANGLE LAMS Text-.RON 3 TLI04293OA INJ. TIME = 07:33
1001
eoj
soj
4oj
2flj
A3.70E6
A
A2.4 6E6
1.
23:00 24:00 25:00 26:00
File:S975668 *1-867 Acq:5-SEP-97 07:31:00 EI* Voltage SIS 70S Noise: 90
353.8970 F:2 BSUBf256, 30, -3. 0 ) PKD(7, 5 , 3 , 0.05%, 392.0,1. 00%,F,T) Exp:EPCDS
TRIANGLE LABS Text-.SON 3 TLI04293OA INJ. TIME = 07:33
1001
80A
sol
401
20j
A2.19E6
A1.55E6
11
23:00 24:00 25:00 26:00
File:S975668 01-867 Acq:5-SEP-97 07:31:00 EI* Voltage SIS 70S
330.9792 F:2 ExpiEPCUS
TRIANGLE LABS Text:SON 3 TLI»42930A INJ. TIME = 07:33
1001 -jtj.u oj.cj 24:14 24:43 25:00 25:19 25:56
27:00
.4.5ES
:.3. 6ES
12.7E6
L 1. 8E6
L9.1E5
'¦.O.OEO
Time
27: 00
27:00
.2.9E6
-2.3E6
.1. 7E6
Li. 1E6
-.5. 7E5
'.O.OEO
Time
.1. 1E6
.8.5E5
L6.4E5
.4.3E5
-2.1E5
'¦.O.OEO
Time
.6.5E5
15.2E5
L 3. 9E5
¦.2.6E5
Li.3E5
27:00
.0.0E0
Time
26:29 26:46
1.6E7
1.3E7
9.7E6
6.5ES
3.2E6
O.OEO
23:00 24:00 25:00
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 EI* Voltage SIS 70S
409.7974 F:2 Exp:EPCUS
TLI*42930A INJ. TIME
26:00
27:00
Time
TRIANGLE LABS
10
Text:SON 3
07:33
1.4E4
1.1E4
24:36
8. BE3
26:58
24:07
5.7£3
23:17
2:55
24:56 25 ¦12
23:36
2.9E3
O.OEO
23:00
24:00
26:00
27:00
25:00
159
-------
File:SS7566& *1-867 Acq:5-SEP-97 07:31:00 EI* Voltage SIX 70s Noise: 737
355.8546 F:2 BSUB(256,30, -3.0) PKD( 7, 5, 3, 0. 05%, 2948. 0,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:RUN 3 TLIH42930A INJ. TIME = 07:33
1003
ao:
so:
40:
20:
Al.22E6
A1.2BE6
A3.01E5
*4. 73ES
A8.01ES
25:00 26:00
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 El* Voltage SIX 70S Noise:916
357.8516 F-.2 BStTBf 256, 30, -3.0} PKD( 7,5,3,0. 05%, 3664.0,1.00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:RUN 3
25:00 26:00
File: S975668 #1-867 Aeq:5-SEP-97 07:31:00 EI* Voltage SIR 70S Noise: 80
367.8949 F:2 BSUB (256, 30, -3. 0 ) PKD( 7 , 5 , 3, 0 . 05%, 320. 0 , 1.00%, F, T) Exp:EPCUS
TRIANGLE LABS Text: RUN 3 TLI442930A INJ. TIME = 07:33
100% Al.pE6
so:
A4.53E5
A1.10E5
1.80E5
I
A1190E5
A
.4.2E5
.3.4E5
.2.5E5
.1. 7E5
.8.4E4
.0.0E0
' f 1
27:00 Time
1003,
Al. 06E6
TLI04293OA
A7.61E5
INJ. TIME
07:33
2.5E5
2.0E5
1.5E5
&3.34E5
A3.69E5 AJ-f5E5 A2.6SES
A2.25E5
1.0E5
1.48E5
A2.23E5
Al.58E5
5.0E4
A8.16E
60.
40.
20:
1.54E5
0. 0E0
27:00 Time
4.7ES
3.8E5
2.8E5
1.9E5
19.5E4
25:00 26:00
File: S975668 #1-867 Acq: 5-SEP-97 07:31:00 EI* Voltage SIR 70S Noise: 96
369.8919 F: 2 BSUB(256, 30,-3. 0} PKD( 7, 5,3, 0. 05%, 384. 0,1. 00%,F, T) Exp:EPCUS
TRIANGLE LABS Text:SON 3 TL1K42930A INJ. TIME = 07:33
.O.OEO
1001
801
60.
40.
201
A1.07E6
m
27:00 Time
4.1E5
3.3E5
2.4E5
1.6E5
18.1E4
lO.OEO
25': 00 26:00
File: S975668 #1-867 Acq:S-SEP-97 07:31:00 EI* Voltage SIR 70S
330.9792 F:2 Exp:EPCUS
TRIANGLE LABS Text:SON 3 TLIH42930A INJ. TIME
100* 24:14 24:30 _2ii43 25:00 25:19 25:56
80.
60.
40¦'
20.
0.
26:46
27:00 Time
.1. 6E7
.1.3E7
.9. 7E6
.6.5E6
.3.2E6
.O.OEO
25; 00
26:00
27:00 Tiae
160
-------
File:S975668 01-425 AcqsS-SEP-97 07-.31:00 EI* Voltage SIS 70S Noiae:1000
373.8208 F:3 BSUB(256, 30,-3 . 0 ) PKD(7, 5, 3 , 0.05%, 4320 . 0,1. 00%, F, T) Exp:EPCVS
TRIANGLE LABS Text:RON 3 TZI04293OA
IXJ-. TIME
07:33
1001
8\¦ i" I*ri "> i" i i"'i*i ftyyPN. r i'it".
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 Time
.4.2ES
.3.4E5
L 2.5E5
11. 7E5
.8.5E4
¦.O.OEO
Fxle:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI* Voltage SIS 70S Hoise:1463
375.8178 F:3 BSUB(256, 30,-3, 0 ) PKD(7, 5, 3, 0.05%, 5852.0,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:RUN 3 TLI04293OA
INJ. TIME
07:33
1001
80*
601
40:
20:
A8.59E5
A2.68ES
A5.85E5
Al.30E5
A2.UE5
A9.32E4
.3.2E5
L2.6E5
1.9E5
1.3E5
-6.5E4
A8.14E4
T.V i p ¦; "|« i | im
29:24 29:36
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12
File: S975668 01-425 Acq:5-SEP-97 07:31:00 EH- Voltage SIS 70S Noise: 773
383.8639 F:3 BSUB( 256, 30, -3.0) PKD(7, 5,3,0.05%, 3092.0,1.00%, F, T) Exp:EPCUS
rr
29:48 30:00
I I I f I1! ^¦ l"
30:12 30:24
O.OEO
Time
TRIANGLE LABS
1001
80i
Text:RUN 3 TLI442930A
603
40:
20i
ol
INJ. TIME
A8.66E5
07:33
A7.67E5
.4.0ES
-3.2E5
L 2.4E5
L1. 6E5
-7.9E4
.O.OEO
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 Time
File:S97S668 #1-425 Acq:5-SEP-97 07:31:00 EI* Voltage SIR 70S Noise: 843
385.8610 F:3 BSUB(256, 30 ,-3. 0 ) PKD (7, 5,3 , 0. 05%, 3372.0,1. 00%, F,T) Exp:EPCUS
TRIANGLE LABS
1001
80J
Text:RUN 3 TLI*42930A
Q6E6
60J
403
20j
OJ
T!
~r
INJ. TIME
A1.81E6
07:33
Al.56E6
.8.0E5
.6.4E5
.4.8E5
¦.3.2ES
¦-1.6E5
¦.O.OEO
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 Time
File:S975668 #1-425 Acq:S-SEP-97 07:31:00 EI* Voltage SIS 70S
392.9760 F:3 Exp:EPCUS
TRIANGLE LASS Text .-SDN 3 TLI04293OA IMT. TIME = 07:33
1001 27:32 27:45 28:10 28:24 28:38 28:54 29:20 oq. 29:55 30:11
8.5E6
6.8E6
5.1E6
3.4E6
1.7E6
27:24 27:36 27:48 ' 28:00 ' 28:12 ' 28': 24' 28:36" 28:48 29: 00 "29:12 29:24 ' 29:36' 29:48' 30-00 30:12
File:S975668 #1-425 Acq:5-SEP-97 07.-J1.-00 EI* Voltage SIR 70S
445.7555 F:3 Exp-.EPCOS
TRIANGLE LABS
100127:29
801
60:
40:
20:
ol
Text-.RXJN 3 TLI04293OA
INJ. TIME
07:33
W<
28:36
27:58
29:29
30:01
28:22
28:56
29:39
28:49
29:lt
29:551
,30:15k
O.OEO
30:24 Time
.2.4E4
i1.9E4
'.1.4E4
15. 7E3
-.4.8E3
27-24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
.0.OEO
30:24 Time
161
-------
fxle: S975668 *1-425 Acq:5-SEP-97 07:31:00 EH- Vol tape SIR 70S Noise: 629
389.8156 F:3 BSUB ( 256, 30 , -3 . 0 ) PKD(7, 5 , 3 , 0 . 05%, 2516. 0 , 1. 00%, F, T) Exp:EPCUS
' ' 1"' 1 1 ........
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S Noise: 601
401.8558 F:3 BSUB(256, 30,-3 . 0) PKD(7, 5 , 3 , 0 .05%,2404 . 0 , 1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS
1003,
801
60i
Text:RON 3 TLI#42930A
INS. TIME
07:33
A2.81E6
401
201
A8.36E5
rr
A2.33E5
, ,/v
A6.33E5
A2.20E5
~r
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S Noise:626
391.8127 F: 3 BSUB( 256, 30, -3 . 0 ) PKD( 7,5,3,0.05%,2504.0,1.00%,F,T) Exp:EPCUS
29:48
30:00
TRIANGLE LABS
100%
80.
Text:RUN 3 TLI#42930A
INS. TIME =
07:33
60.
401
20.
A6.87E5
A2.05E5
s\
A4.86E5
A1.95E5
29:48
30:00
TRIANGLE LABS
1003,
80^
Text:RUN 3 TLI#42930A
601
401
201
INS. TIME
A1.Q9E6
07:33
A1.22E6
i "I | I I
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S Noise:656
403.8529 F: 3 BSUB( 256, 30,-3. 0 ) PKD( 7,5,3,0. 05%,2624 . 0 ,1. 00%, F, T) Exp:EPCVS
H ln f I I ¦ I I "I [T F
28:36 28:48
29:48
30:00
TRIANGLE LABS
1003,
80.
Text:RUN 3 TLI#42930A
INS.
601
401
201
A9.56E5
f*\ "| T
r t n i f i
"i i ^ i i p i
29: 00
07:33
. i I i i i . riTi'fi fii i ¦ |T
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
392.9760 F:3 Exp:EPCUS
TRIANGLE LABS Text-.RUN 3 TLI#42930A INS. TIME =
1003,
80.
601
40.
201
0.
29:36
29:48
30:00
07:33
pi' in 'i i1"1!*. i
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00
.9.0E5
. 7.2E5
.5.4E5
.3. 6E5
.1. 8E5
.O.OEO
Time
.6. 8E5
.5.5E5
.4.1E5
.2. 7E5
.1. 4E5
.O.OEO
Time
.4.7E5
.3.7E5
.2. 8E5
.1. 9E5
.9.4E4
.O.OEO
Time
.3 . 8E5
.3 . 1E5
.2.3E5
.1. 5E5
.7. 7E4
.O.OEO
Time
8.5E6
6.8E6
5.1E6
3.4E6
1. 7E6
O.OEO
Time
162
-------
File: S9 75668 *1-390 Acq:5-SEP-97 07:31:00 EI+ Voltage SIS 70S Noise: 993
407.7818 F:4 BSOB(2S6,30, -3.0) PKD(7, 5 ,3, 0.05%, 3972.0 ,1.00%, F, T) Exp:EPCUS
TRIANGLE LASS Text::SON 3 TLI04293OA ZKT. TIME - 07:33
100% A1-19E5
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
File:S975668 #1-390 Acq:S-SEP-97 07:31:00 EI+ Voltage SIS 70S Noise:527
409.7789 F:4 BSITB(256, 30, -1.0) PKD(7 , 5 , 3 , 0 .05%, 2108. 0 , 1. 00%, F, T) Exp: EP CVS
TRIANGLE LASS Text:SON 3 TLI*42930A INJ. TIME = 07:33
100i A1.Q9E5
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
Tile :S975668 #1-390 AcqsS-SEP-97 07:31:00 EI+ Voltage SIS 70S Noise: 8 75
417.8253 F-.4 BSUB(256,30, -3.0) PKD(7, 5 ,3, 0. 05%, 3500.0 ,1.00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:SON 3 TLI#42930A INJ. TIME » 07:33
3.6E4
2.9E4
2.2E4
A5.33E4
1.5E4
AS.06E3
A4.96E4
A3.64E4
7.3E3
A8.07E3
1.41E4
32:48
32:48
100a
80J
602
40Z
20J
A4.Q0E5
A2.06E5
A2.61E4
A2.39E4
T
T
¦
32:36
31:12 31:24 31:36 31:48 32:00 32:12 32:24
File:S97S66S #1-390 Acq:5-SEP-97 07:31:00 EI+ Voltage SIS 70S Noise: 325
419.8220 F:4 BSUB(256,30,-3.0) PKD(7 , 5, 3 , 0. 05%, 1300.0 ,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text .-SON 3 TLI04293OA INJ". TIME = 07:33
"l I"
32:48
1003
803
60J
403
20J
J
A9.Q9E5
A4.8SES
f==p
31:12 31:24 31:36 31:48 32:00 32:12
File: S975668 #1-390 Acq: 5-SEP-97 07:31:00 EI+ Voltage SIS 70S
430.9729 F:4 Exp:EPCUS
32:24
TRIANGLE LABS
100% 31:13
Text:SON 3
31:28
TLI&42930A
31:41
INJ. TIME
32:36
07:33
I ""*¦
32:48
.O.OEO
33:00 Time
A3.05E4
A1.27E4
9.07E3
.O.OEO
33:00 Time
-1.5E5
.1.2E5
.9. 1E4
.6.0E4
'.3. 0E4
'.O.OEO
33:00 Time
.3.4E5
L 2. 7E5
:.2.0E5
L1.3E5
16.7E4
.O.OEO
33:00 Time
32:00
5.6E6
32:4
4.4E6
3.3E6
2.2E6
1.1E6
31:12 31:24 31:36 31:48 32:00 32:12
File:S975668 *1-390 Acq:S-SEP-97 07:31:00 EI* Voltage SIS 70S
479.7165 F:4 Exp:EPCUS
32:24
TRIANGLE LABS
100!
Text:SON 3 TLH42930A
INJ-. TIME
32:36
07:33
32:48
( .O.OEO
33:00 Time
31:58
31:22
32:12
JLMJL
32:44
31:12
31:24
31:36
31:48
32:00
32:12
32:24
32:36
2. 8E4
2.2E4
1.7E4
1.1E4
5.6E3
O.OEO
32:48
33:00 Time
163 - I
-------
File :S9 756 6 8 #1-390 Acq:5-SEP-97 07:31:00 EH- Vol Cage SIR 70S Noise: 447
423.7766 F:4 BSUB(256,30,-3 . 0) PKD(7, 5,3,0.05%, 1788.0,1.00%,F,T) Exp-.EPCVS
TRIANGLE LABS Text:SVN 3 TLI*42930A INJ. TIME = 07:33
1004
SOI
601
40:
20L
31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24
File:S975668 #1-390 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S Noi3e:416
425. 7737 F:4 BSOB( 256, 30 , -3 . 0 ) PKD( 7, 5,3, 0. 05%, 1664 . 0, 1. 00%, F, T) Exp:EPCUS
-1.2E5
_S. 7E4
.7.3E4
A1.42E5
-2.4E4
A2.01E4
32:30 32:36
Time
TBI ANGLE LABS
1004
80.
601
40.
20.
TextzRUN 3
A2.88E5
TLI442930A
INJ. TIME
07: 33
¦>i , r>
A1.49E5
A2.45E4
A
.1.1E5
.8.8E4
L 6.6E4
4.4E4
2.2E4
I ! I I I I I ! I . 1 ! j I ! I ! I | . I I . I ; "I
31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18
File: S975668 #1-390 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S Noise:360
435.8169 F:4 BSUB( 256, 30, -3 . 0 ) PKD( 7, 5, 3 , 0 . 05%, 1440 . 0 , 1. 00%, F,T) Exp:EPCUS
TRIANGLE LABS Text-.RUN 3 TLI442930A INJ. TIME = 07:33
100%
80.
60L
40:
20:
O.OEO
32:24 32:30 32:36
.2.4E5
'.1. 9E5
-1.4E5
.9.6E4
.4.8E4
-f-T-|-l-T-r T !¦ | '1 1 1~l i | I'T I I i | i , I i i | i l l i ~l . r i i | i i i iT | TTM~! . , . T. ' , . .
31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30 32:36
File: S975668 #1-390 Acq: 5-SEP-97 07:31:00 EI+ Voltage SIR 70S Noi3e:62
437.8140 F:4 BSUB( 256, 30,-3 . 0 ) PKD (7, 5, 3 , 0 . 05%, 248 .0 , 1. 00%,F,T) Exp-.EPCVS
TRIANGLE LABS Text.RVN 3 TLI#42930A INJ. TIME = 07:33
1003,
801
601
40:
20:
A3.16E4
' ' V |"I ......
31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12
File: S975668 #1-390 Acq: 5-SEP-97 07:31:00 El-h Voltage SIR 70S
430.9729 F:4 Exp: EPCUS
TRIANGLE LABS TextzRUN 3 TLI442930A INJ.
100% 31:28 31:41 31:53 32^00 32:11
¦&T
T
' ¦' I ¦»-'
31:54
Pi I ; T I
32:00
801
601
40:
20:
0.
32:18 32:24 32:30
TIME = 07:33
32:22
32:36
'31:30 ' ' '31:42 ' 31:48 ' '31:54 ' 32:66 ' '32:06 ' '32:12 ' J2:is ' '32:24 ' J2.* jb ' '32:36
. 0.OEO
Tine
2.5E5
2.0E5
1.5E5
1. 0E5
5. 0E4
O.OEO
Time
.5. 5E6
.4.4E6
.3.3E6
.2.2E6
.1.1E6
.O.OEO
Time
164
-------
File:S975668 #1-390 Acq:5-SEP-97 07:31:00 EI* Voltage SIR 70S Hoiae:460
441.7428 F:4 BSOB(256,30, -3.0) PKD(7, 5,3 , 0. 05%, 1840.0, 1. 00%, F,T) Exp-.EPCOS
TRIANGLE LABS Text:RUN 3 TLIH42930A XJKJ. TIME ¦ 07:33
100%
2.4E4
2.1E4
1.9E4
1.7E4
1.4E4
A2.31E4
1.2E4
A2.91E4
1.04E4
A2.35E4
9.4E3
A1.4SE4
A2.31E4
3.13E4
7.1E3
4.7E3
2.4E3
32:00 33:00 34:00
File: S975668 #1-390 Acq: 5-SEP-97 07:31:00 EI+ Voltage SIS 70S Noise: 615
443.7399 F:4 BSUB< 256, 30, -3.0 ) PKD( 7, 5, 3, 0. 05%r2460. 0,1.00%,F, T) Exp:EPCUS
TRIANGLE LABS Text:RON 3 TLH42930A INS. TIME = 07:
100% A4 ,23E4
35:00
1.7E4
32:00 33:00 34:00
File:S975668 01-390 Acq:5-SEP-97 07:31:00 EI* Voltage SIS 70S
430.9729 T:4 Exp-.EPCOS
TLI44293OA INS. TIME
TRIANGLE LABS
100¦.
.36E4
1.4E4
1.2E4
A2.97E4
. 74E4
1.0E4
A2.28E4
A3 . 3 2£4
A2.21E4A1
8.5E3
A1.42E4
A2.30E4
1 .\3uE4
6.8E3
. 33E4
A2.29E4
A2. 70E4
5.1E3
A1.00
3.4E3
1.7E3
O.OEO
35:00
90.
801
70.
60.
50.
40.
30.
201
10.
Text.-RUN 3
31:41 32:00 32:22 32'iSn
07:33
33:3233:48 31.0734:23 34:48 35:06
35:31
35:50
32:00 33:00 34:00
File:S975668 #1-390 Acq:5-SEP-97 07:31:00 El-h Voltage SIR 70S
513.6775 F:4 Exp:EPCXJS
35:00
.5.8E6
.5. 2E6
4.6E6
.4.1E6
.3.5E6
.2.9E6
.2.3E6
.1. 7E6
.1.2E6
.5.8E5
10.0E0
Time
TRIANGLE LABS Text:RON 3 TLI442930A
100%
INS. TIME
07:33
8.5E3
5:47
7.7E3
33:15
34:29
6.8E3
6.0E3
31:50 32:07 32:25
33:50
5.1E3
4.3E3
2:55
35:09
3:3 ?
3.4E3
31:14
2.6E3
34:51
1.7E3
A
8.5E2
O.OEO
35:00
32:00
33:00
34:00
165
-------
File:S97566B *1-390 Acq: 5-SEP-97 07:31:00 EH- Voltage SIR 70S Woi.se.-464
457.7377 F:4 BSUB(256,30,-3.0) PKD( 7, 5, 3, 0. 05%, 1856. 0, 1. 00%, F, T) Exp-.EPCUS
TRIANGLE LABS
lOOi
Text;3
TLX #4 293 OA
A5.QLE4
IN J. TIME =
07:33
1.2E4
9. 7E3
A3.81E3
7. 3E3
-4.9E3
A9.06E3
_2.4E3
A4 . 86E3
34:30 34:36 34:42 34:48 34:54 35:00
File:S975668 #1-390 Acq:5-SEP-97 07:31:00 EH- Voltage SIR 70S Noiae:300
459.7348 F:4 BSUB(256, 30,-3 . 0 ) PKD( 7, 5 , 3 , 0. 05%, 1200 . 0,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text-.RUN 3 TLIH42930A INJ. TIME = 07:33
100% A5.76E4
35:06
2.2E4
1.8E4
1.3E4
8.9E3
4.5E3
A9.16E3
O.OEO
34:30 34:36 34:42 34:48 34:54 35:00
File:S975668 #1-390 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S Noise:353
469.7779 F:4 BSUB(256, 30, -3 . 0) PKD( 7, 5, 3, 0 . 05%, 1412. 0,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:RUN 3 TLIH42930A INJ. TIME = 07:33
10 Oi A5.J4E5
35:06
I 1 I > I'l l 1 1 1 1 1 1 ' I ' i t •, i i I ¦ " — ' 1 r>
34:30 34:36 34:42 34:48 34:54 35:00
File:S975668 #1-390 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S No±se:51
471.7750 F:4 BSUB( 256, 30, -3 . 0 ) PKD(7, 5 , 3 , 0. 05%, 204 . 0 ,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:RUN 3 TLH42930A INJ. TIME = 07:33
1004
35:06
.1. 8E5
.1. 4E5
.1. 1E5
7.1E4
3.5E4
.O.OEO
Time
1.8E5
1.4E5
7.2E4
3.6E4
O.OEO
I 1 1—1 1 1 i—1—1—1—'—1—i—1—1—1'—r"1——1 f •*"*
34:30 34:36 34:42 34:48 34:54
File:S975668 #1-390 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
430.9729 F:4 Exp:EPCUS
TRIANGLE LABS Text:RUN 3 TLI#42930A INJ. TIME =
35:00
07:33
100i
801
60.
40;
20;
0.
34:48
34:54
34:57
35:06
35:06
34 : 30
34:36
34:42
34:48
34 : 54
35:00
35:06
_5.6E6
4.5E6
13.4E6
-2.2E6
-1.1E6
O.OEO
Time
166
-------
58
58
i
r
1
J
IL
Channel I 338.3792
Height 3.25 volts Span
Peak top
296 ppt
Systsa file nae
EFCUS2
Data file naie
A:S905971
Resolution
18000
Group nmber
2
Ionization aode
EI*
Switching
VOGE
Ref. lasses 292.3825,
416.9768
B 293 J 331
S 368
B 384 K 332
T 370
C 386 L 334
U 376
0 316 H 348
V 410
E 318 H 342
F 320 0 352
6 322 P 354
H 328 9 356
I 331 R 358
Ref, lass 416.9760
Height .96 wits Span
Peak top
Mb*
167
-------
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
3 03.9016 F:2 Exp:EPCUS
Sample Text: RUN 3 TLI#4293 0A mj—T.XME = 07:33 File Text: RUN 3
100% <^A2.52E7)
80j
60 J
40
20j
oJ
| i i i I i | i—i"nt |—i i—p—i—l—|—i—i—i—i—rprrrrrp—i—i "T i | T i i—i—i—|—i—i—i—i—r,,|' i—i—r*i—i—|—i—i—rTTTi^r't—i—i—t—i—i—i—r~i—i—i—i i j111 11 r
16:12 16:24 16:36 16:48 17:00 17:12 17:24 17:36 17:48 18:00 18:12 18:24 18:36 18:48
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
305.8987 F:2 Exp:EPCUS
Sample Text:RUN 3 TLI#4293 0A INJ. TIME = 07:33 File Text:RUN 3
100% (^A3'.yOE7;>
80
60j
40J
20J
Oj
ti i i
| > i i i i | i i i i i |~~i i i i i j i i i i i | i i—i i i [t—i—i—i—i ¦ i—i—i—i—i—j—r~i—i i i | T i—i—i—i—j i*t i ~i—i—|—i—i Trrp—t*t
16:12 16:24 16:36 16:48 17:00 17:12 17:24 17:36 17:48 18:00 18:12 18:24 18:36 18:48
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
315.9419 F:2 Exp:EPCUS
Sample Text:RUN 3 TLI#4293 0A INJ. TIME = 07:33 File Text:RUN 3
100%. 17^01
17:54
18 : 17
18 : 40
17 : 34
18 :31
i i i i r
•j—i—i—i—i—i—|-r~i—i—i—i—["i—i—i—i—i—|—i—i—i—i—i—|—i—i—i—i—i—j—i—i—i—i—i—j—i—i—i—r-7-|"r i—r~j—i—c-1 f—'1—r""P"' i—i—i—I—i—i—i-" i*•-j--1—i -1—i—i—(~j-
16:12 16:24 16:36 16:48 17:00 17:12 17:24 17:36 17:48 18:00 18:12 18:24 18:36 18:4
TLI# 4 2 »
.1 . 0E7
_8 . 0E6
.6 . 0E6
A . 0E6
.2 . 0E6
0.0E0
Time
TLI#42»
.1.2E7
9 . 5E6
.7 . 1E6
-4.7E6
_2 . 4E6
-0.0E0
Time
TLI#42»
.1.1E5
.8 . 7E4
.6.6E4
.4 . 4E4
.2 . 2E4
.0 . 0E0
Time
• oo
-------
File:S975668 #1-867 Acq:5-SEP-97 07:31
303.9016 F:2 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A
100%
WEI+ Voltage SIR 70S
INJ. TIME
(aJ'.97E^
i—i—i—i—i—|—i—i—i—r^r11—i—i—i—i—i—I—"1
19:12 19:24 19:36 19:48
File:S975668 #1-867 Acq:5-SEP-97 07:31;
305.8987 F:2 Exp:EPCUS
Sample Text:RUN 3 TLI#4293 0A
100%
i—i—|—r—i—t—i i r |—i—i—i—i—i—i—t—i
20:00 20:12 20:24
00 EI+ Voltage SIR 70S
INJ. TIME =
07:33 File Text:RUN 3 TLI#42»
.9 . 9E6
L8.0E6
'6.0E6
.4 . 0E6
.2 . 0E6
0 . 0E0
£A8 . 31E7)
-j—j—i—i—"j—i ,,MiJ" i i i—i—r~
19:12 19:24 19:36
t—r*
19148
2 0:3 6T 1-120 ! 4 8 ' 21:00 Time
07:33 File Text:RUN 3 TLI#42»
.1.2E7
9.6E6
i7.2E6
i4.8E6
2 . 4E6
File:S975668 #1-867 Acq:5-SEP-97 07:31
315,9419 F:2 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A
100%
80 j
60
40i
20 i
0
_i—f—.—,—,—» i""" i "j—i—j—i—i—i—j—i—r
20:00 20:12 20:24
00 EI+ Voltage SIR 70S
INJ. TIME =
.0 . 0E0
19:28 19:38
f*—i—j—i—i—i—r~i—p-1 i—r-'f i—1"
19:12 19:24 19:36
19:51
f * j , , r
19 :48
20:27
20 :12
"i—i—j—i—r"n—f—i—*y—r
20:00 20:12 20:24
~i—i—|—i—i—i—s—i—|—i—j—i—i—r
20:36 20:48 21i00 Time
07:33 File Text:RUN 3 TLI#42»
1. 1E5
9 . 1E4
6.8E4
.4 . 5E4
i2 . 3E4
20:56
10 . 0E0
20136 20:48 21i00 Time
20:39
» CT)
-------
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
319.8965 F:2 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A
INJ. TIME = 07:33 File Text:RUN 3
100%
80_:
60J
40J
20J
0 ;
4
16
00
VI
w
20 :2
\4/
V
29
2:24
23
w
>9
r—| 1 1 1 1 1 j 1 1 1 1 1 1 1 1—t 1 r
24 :00
25
TLI# 4 2 »
6 . 0E4
i4.8E4
3 . 6E4
2 . 4E4
til .2E4
_ 0.0E0
00 Time
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
321.893 6 F:2 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A INJ. TIME = 07:33 File Text:RUN 3
2-26
100%
18:16
19 : C
16:53
vM>mvW
ft
4:25
1 1 1 1 1 1 J 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1—^ 1 1 1 1 J 1 1 f 1 1 j 1 1 1 1 1 j 1 1 1 J 1 J 1 1 1 1 1
16 00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 24:00 25
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
331.9368 F:2 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A INJ. TIME = 07:33 File Text:RUN 3
100%
80J
60j
40
20J
0
18:25
22 : 52
23
t—i—i 1 1—|—i—i 1—i—i—|—i—i 1—i—i—j—i 1—i 1—i 1—i—r~
16 00 17:00 18:00 19:00 20:00
—i 1 1 r—i 1—r—j 1 1 r—i i—j—i 1 1 r r—| 1 1 1—i—r—
21:00 22:00 23:00 24:00 25
TLI# 4 2 »
_7 . 2E4 (
l5.8E4
l4.3E4
l2.9E4
Ll.4E4
.0.0E0
00 Time
TLI# 4 2 »
^1.4E4
Ll.1E4
18 . 3E3
:_5 . 5E3
12.8E3
_0.0E0
00 Time
IIJ
Vu-
o
-------
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
319.8965 F : 2 Exp.-EPCUS
Sample Text:RUN 3 TLI#42930A INJ. TIME =
100%
80j
60i
40 J
20J
0.
A
kJ
21:45
07:33 File Text:RUN 3 TLI#42»
2 . 9E5
19:37
n
^ '
19:55
20l55 21:19
19:00 20:00 21:00 22:00
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
321.893 6 F:2 Exp:EPCUS
Sample Text:RUN 3 TLI#4293 0A INJ. TIME =
i H 21 45
1.2 . 3E5
22 : 13
ll.7E5
L1.2 E5
22 :52
i5.8E4
23 :00
0 . 0E0
Time
07:33 File Text:RUN 3 TLI#42»
^3.6E5
100%
i2.9E5
21 : 19
22 : 12
l2.1E5
20:50
il.4E5
22 : 52
-7 . 1E4
23 : 00
19:00 20:00 21:00 22:00
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
331.9368 F:2 Exp:EPCUS
Sample Text:RUN 3 TLI#4293 0A INJ. TIME =
100% 21;39
80J
60i
40J
20J
0.
19 00
20:00
21:00
—T
0 . 0E0
Time
07:33 File Text:RUN 3 TLI#42»
.1. 1E6
.8 . 8E5
\l6 . 6E5
4 . 4E5
i2 . 2E5
22 :00
1 " *^T rl r 1 I1'
23 : 00
tO.0E0
Time
-------
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
319.8965 F:2 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A
INJ. TIME = 07:33 File Text:RUN 3
TLI# 4 2 »
2.9E5
100%
i2.3E5
73E6 >
Ll.7E5
1 .2E5
5.8E4
19 00 20:00 21:00 22:00
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
321.8936 F:2 Exp:EPCUS
23 :00
Sample Text:RUN 3
100%
TLI#42930A
INJ. TIME = 07:33 File Text:RUN 3
.0 . 0E0
Time
TLI# 4 2 »
.3 . 6E5
2 . 9E5
&2.17E6. }
12.1E5
11.4E5
l7.1E4
19:00 20:00 21:00 22:00
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
331.9368 F:2 Exp:EPCUS
Sample Text:RUN 3 TLI#4293 0A INJ. TIME
100%, 21; 39
80
60j
40 j
20j
23 : 00
07:33 File Text:RUN 3
0.
19 00
-f [—n
20:00
L0.0E0
Time
TLI#42»
.1.1E6
i.8 . 8E5
l6 . 6E5
4.4E5
l2 . 2E5
L.
21:00
22 :00
T
23 : 00
.0 . 0E0
Time
• -sJ
ro
-------
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
319.8965 F:2 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A JNJ. TIME
c A2 . ?0E5~">
07:33 File Text:RUN 3 TLI#42»
1.0E5
100%
l8 . 3E4
16.2E4
l4.2E4
"2.1E4
—i—i—i—*—i—[—i r i i—p—j—r~i—i—i—i j—i—i—t—t—i—|—i—i—i—i—i—|—i—i—i—r—r-*j—i—i—i—i—i—i—i—i—i—i—i—r—i—» t- i—r
21:48 22:00 22:12 22:24 22:36 22:48 23:00 23:12 23:24 23:36 23i48 Time
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
321.8936 F:2 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A . INJ. TIME
100%1 A \ .""' A3 .5.6E5 )
07:33 File Text:RUN 3 TLI#42»
1 .1E5
i9.2E4
A2 .7 IE
6 . 9E4
4 . 6E4
i2.3E4
0.0E0
21 :48 22 :00 22il2 22 :24 22 :36 22 |48 23 : 00 23 : 12 23 :24 23 :36 23 :48 Time
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
331.9368 F:2 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A INJ. TIME
100%
23:25
80
60 j
40
20j
oJ
07:33 File Text:RUN 3 TLI#42»
23 37 _1.5E4
22:52
22:39
t—|—I—r-"T—i—i—I-1 i i—"i—i—i—|—r~
~i—i—r—i—i—i—r~
]—i—i—j—r—t—|—f—i—r~ "i—i—j—i "i—i—t—i—|—i—i—t—i—t—j—i—r—i—i—i—p
.1 .2E4
_9 .2E3
6 . 2E3
.3 . 1E3
0.0E0
21:48 22:00 22:12 22:24 22:36 22:48 23:00 23:12 23:24 23:36 23:48 Time
-------
File : S975668 #1-867 Acq; 5^SEP-97 07 : 31TUfi~ET^oltage""SIir"7U3~
339.8597 F:2 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A INJ. TIME
100%
07:33 File Text;RUN 3
T fi 3—r~]—i » i—i •»- j • i "i—r-1—\—| ) \—r i i ""| i i—i—i t^j i 1—M—i—j—r~ ?—r~i—i—|—i—\—i' TT [ f r ' S"* i1 I '"j r-r~i i " i ~j~ir ttTTJT i—r—i T | I T T*l T,r"j "i'i'I t"i
24:00 24:12 24:24 24:36 24:48 25:00 25:12 25:24 25:36 25:48 26:00 26:12 26:24 26:36
File:S 9 7 5 6 6 8 #1-867 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
341.8567 F:2 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A INJ. TIME
100%
07:33 File Text:RUN 3
TLI#42»
.1.1E6
.8 . 7E5
.6.5E5
.4.3E5
.2 . 2E5
_0 .0E0
Time
TLI#42»
.7 . 3E5
5 . 9E5
4 . 4E5
2 . 9E5
1.5E5
) TI I I I I I I I ) I I I I I I" I IT i r"i I ¦I'll' I I I i' i i [ I I I I I [ I i -I T**Tr:|^T=T"1 T r^j i I i r-1 I i i fTT] T t~i—{"jl"T|,rT*'1 1 I i •T~jT~r y'
24:00 24:12 24:24 24:36 24:48 25:00 25:12 25:24 25:36 25:48 26:00 26:12 26:24 26:36
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
3 51.9000 F:2 Exp:EPCUS
Sample Text:RUN 3 TLI#4293 0A INJ. TIME
100% 25;09
07:33 File Text:RUN 3
80 j
60
40j
20j
0 j
T-n I l"| .| i—r1 ,-) I I |-| I p I I" I I I" I I-I-T [ r
25:52
r "i i i ¦[ r i r i rr ¦¦[¦¦¦ t i--i i -i
24:00 24:12 24:24 24:36 24:48 25:00 25:12 25:24 25:36 25:48 26:00 26:12 26:24 26:36
0.0E0
Time
TLI#42»
.1.1E6
.8 . 5E5
.6.4E5
.4 . 3E5
-2 . 1E5
-0.0E0
Time
» <1
-------
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
339.8597 F:2 Exp:EPCUS
Sample Text: RUN 3 TLI#42930A INJ . TIME =
.3~8l?)
07:33 File Text:RUN 3 TLI#42»
1.1E6
100%
l8.7E5
l6.5E5
"4.3E5
i2.2E5
-n i i i [ i i i i i | i i—i—i—i—|—i—i i i i | i i—i r—iw"j i i t i I |""*i i f i i | i i i r i | I i i i "j—i—i—r i—j—j—i—i—i ^ F ir" | r i—i 7 T l T1 n lni| 11"!1
24:00 24:12 24:24 24:36 24:48 25:00 25:12 25:24 25:36 25:48 26:00 26:12 26:24 26:36
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
341.8567 F:2 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A i INJ. TIME =
CA2?3 9e£>
07:33 File Text:RUN 3
Time
TLI#42»
.7.3 E5
100%
5.9E5
4 . 4E5
2 . 9E5
1.5E5
24:00 24:12 24:24 24:36 24:48 25:00 25:12 25:24 25:36 25:48 26:00 26il2 26i24 26:36
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
3 51.9000 F:2 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A INJ. TIME = 07:33 File Text:RUN 3
100% 2 5;09
80j
60
40
20 j
0.
Tl 1
25 : 52
I i r"i t i '| i i ii i | i in i i in r i t i | —i—i—|—nr~ f i i" f T i—i ~r i i i r r i i r i—1—1^1 t") i t irti i i i i i i i r i r i i i—i r i
24:00 24:12 24:24 24:36 24:48 25:00 25:12 25:24 25:36 25:48 26:00 26:12 26:24 26:36
.0 . 0E0
Time
TLI#42»
.1.1E6
.8 . 5E5
.6 . 4E5
.4 . 3E5
.2 . 1E5
.0 . 0E0
Time
-------
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR TUW
355.8546 F:2 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A INJ. TIME
ioo% .
07:33 File Text:RUN 3
TLI#42»
.1. 5E5
1.2E5
9 , 3E4
6 . 2E4
3 . 1E4
-i—i—i—i—i—i—r
25:24
25:36 25:48 26:00 26:12 26:24 26:36
File:S975668 #1-867 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
3 57.8516 F:2 Exp:EPCUS
t—r—i—i—=1—r—r—i i'i—J—i—r—r-^T—r~
26:48 27:00 27:12
Sample Text:RUN 3 TLI#42930A
100%
INJ. TIME
07:33 File Text:RUN 3
.0 . 0E0
Time
TLI#42»
.1 .2E5
9.9E4
7 . 4E4
5 . 0E4
2 . 5E4
25:24 25:36 25J48 26i00 26:12 26:24 26:36
File:S975668 #1-867 Acq:5-SEP»97 07:31:00 EI+ Voltage SIR 70S
3 67.8949 F:2 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A INJ. TIME
100% 26j14
80j
60j
40j
20J
Oi
26:48 27:00 27:12
07:33 File Text:RUN 3
t "7 T 1 f "T » i
25:24
T-=r
I ' 1 '
25:36
t* I T "t"~—I I "1^1 'I 1 'T"T
25:48 26:00
26:22
t—i—i—i—i—i—f—T—?—r=T—P-p t "I"" r i—r
26:12 26:24 26:36 26148
r-'VT 1—i—r—r
27 :00
"i—i—i—r
27 : 12
.0.0E0
Time
TLI#42»
_4 . 7E5
.3 . 8E5
.2 . 8E5
-1. 9E5
-9 . 5E4
.0 . 0E0
Time
an
-------
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70s
373,8208 F:3 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A INJ. TIME = 07:33 File Text:RUN 3
100%
80
60
40j
20j
ol
29:14
28:08
29:03
30:01
28 :29
28:5
3 0:29 30:41 30:'54:
TLI#42»
_6.lE4
4 . 9E4
3 , 7E4
L2.4E4
1.2E4
28:00 29:00 30:00
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
375.8178 F:3 Exp:EPCUS
.0. 0E0
Time
Sample Text:RUN 3 TLI#42930A
INJ. TIME = 07:33 File Text:RUN 3
100%,
80.
60.
40.
20.
0.
28:17
28:08
29:15
29 :04
8:51
30:00
30:11
30:28
29:29
29:4229:5
0:40.
30:46
28:00 29:00 30:00
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
383.8639 F:3 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A INJ. TIME =
29:14 29:57
07:33 File Text:RUN 3
100%
80
60
40j
20 J
0.
28 i 00
TLI#42»
3.1E4
.4 . 1E4
.3 . 1E4
.2 . 0E4
.1. 0E4
.0 . 0E0
Time
TLI# 4 2 »
.3 . 2E5
28:3
2 . 5E5
1.9E5
1.3E5
6.4E4
29:00
30:00
0.0E0
Time
l-sl
-------
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
373.8208 F:3 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A INJ. TIME =
100%
07:33 File Text:RUN 3 TLI#42»
6 . 1E4
l4.9E4
3 . 7E4
8 . (>0E
i2.4E4
-1.2E4
29 :00
29 :12
29 :24
29:36
1 I | T" "I-
29 :48
^ 1 To :00
n 1 , p
30:12
.0.0E0
Time
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
375.8178 F:3 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A INJ. TIME =
100%
07:33 File Text:RUN 3 TLI#42»
5 .1E4
4 . 1E4
3 . 1E4
l2.0E4
z.1. 0E4
i r ^ 1 ' ' i
29:36 29:48
29:00
29:12
29 :24
30:00
30 :12
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
383.8639 F:3 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A
100% 29:14
80.:
60 J
40
20 j
0
INJ. TIME =
-r—r—t—]¦
29:00
f-T
29 :24
0 . 0E0
Time
07:33 File Text:RUN 3 TLI#42»
29;57 _3.2E5
~J2 . 5E5
1. 9E5
tl.3E5
6 . 4E4
T P i i
29:45
29:12
29:36
n r~
29:48
30 :00
" i^ i | t~" "r1 ¦ \*
30 : 12
.0 . 0E0
Time
• OO
-------
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
373.8208 F:3 Exp:EPCUS
Sample Text:RUN 3 TLI#4293QA ^ INJ. TIME =
^r?7 9E.5^
100%
80j
60 J
40
20J
07:33 File Text:RUN 3
n—i—i—i—i—|-
^(( ( (j 1 , 1 , 1 , , , , 1 1— 1 1 , , 1 , , 1 , r~
T
_i 1 1 r-
30:00
T
30 :12
29:00 29:12 29:24 29:36 29:48
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
375.8178 F:3 Exp:EPCUS
Sample Text: RUN 3 TLI#42 930A ^ INJ. TIME = 07:33 File Text: RUN 3
100% <
-------
File:S975668 #1-425 Acq:5^SEP-97 07:31:00 EI+ Voltage SIR 70S
INJ . TIME
373.8208 F:3 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A
100%
80
60
40 j
20
0j
29:14
29:03
30:01
29 :30
30 :11
07:33 File Text:RUN 3 TLI#42»
6 . 1E4
14.9E4
L3.7E4
2 . 4E4
1.2E4
30:29 30:41 30:^4
i—i—i—i—r~i—|—i—i—i—i—i—f—i—i—i—r-1—j—l—i—i—i—i—p-h—r-
29:00 29:12 29:24 29:36 29:48
28 :48
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI +
375.8178 F:3 Exp:EPCUS
Sample Text:RUN 3 TLI#42 930A
100% 29:15
t—I—|—-j—r--,—i—t—r—j—r —i—
30:00 30:12
Voltage SIR 70S
INJ. TIME
3 0 [24 30:36 30:48
0 .0E0
Time
07:33 File Text:RUN 3 TLI#42»
_5.1E4
l4.1E4
i3.1E4
29:04
:_2 . 0E4
30 :00
30 :11
30:46
l1.0E4
30 : 56
28:48' ' 29:00
n—i—i—|—i—i—i—i—i—|—i—i—i—i—i—|—i—r
29:12 29:24 29:36
1 1 l
29 :48
l 1 1 1 1 1 l 1 1 '
30:00 30:12
"i—i—J* i—i—i—r n—|—r—i—i—i—i—j—i—i—i—i—r~
30:24 30:36 30:48
.0 . 0E0
Time
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
383.8639 F:3 Exp:EPCUS
Sample Text:RUN 3 TLI#42 930A
100% 29:14 29;57
INJ. TIME =
29 :45
07:33 File Text:RUN 3 TLI#42»
.3 . 2E5
l2.5E5
1. 9E5
L1.3E5
L6.4E4
28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
•f-^pr—i—r-~i i—p°f~r-rr-rM—On—t^t-t
30:24 30:36 30:48
.0 . 0E0
Time
' OO
O
-------
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
373.8208 F:3 Exp:EPCUS
Sample Text: RUN 3 TLI#42930A _ INJ. TIME = 07:33 File Text: RUN 3
>2E4 3
TLI#42»
_3.2E4
100%
2 . 5E4
ll.9E4
1.3E4
16.3E3
-j—i—|—i—i—i—i—i—|—i—i—i—i—i—|—r~i—i—i—i—|—i—i—i—i—i—j—i—i—i—i—i—|—i—i—i—i—i—i—i—i—i—i—r~]—i—i—r—i—i—|—i—i—i—i—i—|—i—r n—r~-i—i—i—i—i—i—i—i—i—i—i—i—i—i—r—i—r~
29:24 29:30 29:36 29:42 29:48 29:54 30:00 30:06 30:12 30:18 30:24 30:30 30:36
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
375.8178 F:3 Exp:EPCUS
Sample Text : RUN 3 TLI#42930A v INJ. TIME = 07:33 File Text : RUN 3
100%, fA4.94E4^
0.0E0
Time
TLI#42»
1 . 8E4
. 5E4
ll.1E4
i7.3E3
l3.6E3
~i—i—|—i—I—i—i—i—|—i—i—i—i—i—j—j—i—i—i—i—j—i—i—i—i—i—|—i—I—I—i—i—|—i—i—i—i—i—j—i—i—i—i—i—j—i—i—i—i—i-1—i—i—i—i-1—j—i—i—i—i—r ~j—i—i—i—i—i—j—i—i—i—i—i—|—i—r~r~
29:24 29:30 29:36 29:42 29:48 29:54 30:00 30:06 30:12 30:18 30:24 30:30 30:36
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
383.8639 F:3 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A
100%
INJ. TIME = 07:33 File Text:RUN 3
80
60 j
40
20 j
0
29:57
29 :45
rn p~r i i i^| i i i i i1"! rY^1 ir~r~pr
~i i i | i i f t * i | i i i i i | i TTTTf r-T-r-P r P" i r r i i r—j T' r"
29:24 29:30 29:36 29:42 29:48 29:54 30:00 30:06 30:12 30:18 30:24 30:30 30:36
0 . 0E0
Time
TLI#42»
3 . 2E5
l2.5E5
1. 9E5
t-1 . 3E5
6 . 4E4
_0.0E0
Time
00
-------
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
3 89.8156 F:3 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A INJ. TIME
/II n 29:45
i9:00
29 ::»2
28:17
07:33 File Text:RUN 3 TLI#42»
.6.5E4
.5 . 2E4
.3 . 9E4
.2 . 6E4
.1.3E4
29:59 30:30 30;47
28:00 29:00
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
391.8127 F:3 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A INJ. TIME
n
.0 . 0E0
Time
100%
80
60
40
20.
1a 27:45 28101 )
0 ¦'
wu
29 :45
07:33 File Text:RUN 3 TLI#42»
5.2E4
28:00 29:00
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
401.8558 F:3 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A INJ. TIME
100% hi 29 44
80
60
40
20
0
4 . 1E4
3 . 1E4
2 . 1E4
30 : 12
1.0E4
30:30 30:47
29:00
30:00
0.0E0
Time
"i ^"" "T *
07:33 File Text:RUN 3 TLI#42»
4 . 3E5
.3 . 4E5
t_2 . 6E5
1.7E5
8.6E4
I """TT"— ,
—Hk-
OO
. ro
28 :00
29:00
30:00
0. GEO
Time
-------
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
389.8156 F:3 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A INJ. TIME
100% \ n 29:45
29:00
29:22
2 3:31
29:59 30:09
07:33 File Text:RUN 3 TLI#42»
.6.5E4
.5 . 2E4
.3 . 9E4
i2.6E4
Ll.3E4
L0 , 0E0
30*30 30:47
JU.JU 30.42
-i—i—i—i—i—i—>—j—in-i—j—i—h—i—i—i—|—i—i—i—i—i—|—f—»—i—i—i—I—i—i—i—i—i—i—i—t—i—i—i—i—i—i—i—i—i—|—i—i—i—i—i—j—f—r—i—i—i—r—i—i—i—r
29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48 Time
29:45
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
391.8127 F:3 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A INJ. TIME
100% \
80j
60
40.
20j
0 i
29:00
07 : 33 File Text:RUN 3 TLI#42»
5.2E4
^4 . 1E4
i3.1E4
2 . 1E4
1.0E4
30:12
29:35 J ^ A h h l\ 30:22 30:47
~ 0 . 0E0
29 : 00 29:12 29:24 ' 29 ! 36 ' 29 548' '30:00 ' 3 0 ! 12 30 5 24' ' 30 ! 36 ' '30 1 48' ' ' Time
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
401.8558 F:3 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A
100%
80j
60j
40j
20
0J
INJ. TIME
29:44
07:33 File Text:RUN 3 TLI#42»
_4.3E5
.3 . 4E5
.2 . 6E5
.1. 7E5
8.6E4
—r=i|—p "T"T--| T I ~| l'"1—p-1-T'^-(-T-ri—i—r"T i-
0.0E0
v r.„l; I-,, ,.lfl —III!—I—|—I—I—r
29:00 29:12 29:24 29i36 29:48 3 0 i 00 30112 30^24 30i36 30^48 Time
QO
co
-------
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
389,8156 F:3 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A
INJ. TIME
07:33 File Text:RUN 3
60.
40.
L tfsTi
1 1
1 ! 1 1 1 1 f , | j t*"1
¦ j i"
i iij i i i i i iii i
29:00 29:12 29.24 29:36 29:48 30:00 30:12 30:24 30:36 30:48
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
391.8127 F:3 Exp:EPCUS
Sample Text:RUN 3 TLI#4293 0A INJ. TIME = 07:33 File Text:RUN 3
100% \
80J
60 J
40
20 J
\A^ZJT
07:33 File Text:RUN 3
i—i—i—i—|—i—j—i—i—i—|—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—i j r i -i—i—i—|—i—i—i—i—t—r i—r—j—i—i—j—i—i—i—i—i—i—i—i—i—i—i—r—r
29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:41
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
401.8558 F:3 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A INJ. TIME
100% h (i 29; 44
80j
60i
40
20 j
0
^1 I " I I—I—f
^*™r*=T-®[=^r=P£i—rH—|—i—r i ~ i i i—r i "T -p-p-r- i—i—f—T r-1 i
29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48
TLI#42»
.6.5E4
.5 . 2E4
.3 . 9E4
.2 . 6E4
.1.3E4
.0 .0E0
Time
TLI#42»
-5.2E4
.4.1E4
.3 . 1E4
_2.1E4
-1.0E4
_0.0E0
Time
TLI#42»
A . 3E5
.3 . 4E5
.2 . 6E5
.1.7E5
.8 . 6E4
-0.0E0
Time
. OO
-------
File:S975668 #1-425 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
389.8156 F:3 Exp:EPCUS
Sample Text: RUN 3 TLI#4^3IiA INJ. TIME = 07:33 File Text: RUN 3
100%
-------
File:S975668 #1-390 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 703"
407.7818 F:4 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A INJ. TIME
100% A9.41E4
80
60
40.
20 j
0
07:33 File Text:RUN 3
i - i I " I I—I—r—i—i i i—s—i—r—i—t r i—i—i—i—i—i—i—i—i—i—i—|—i—i—i—i—i—|—i—i—i—i—i—e—i—e—i—i—i—j—r—r~i—ri—i i i i—»—i—j—r—r—i—i—i—i—r- r-rn—i—i—i—t—i~t—i—i—i—i—i—r
31:12 31:18 31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24
File:S97 5668 #1-390 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
409,7789 F:4 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A INJ. TIME = 07:33 File Text:RUN 3
100% A9.88E4
80 j
60i
40i
20i
t l i l t 111 i | I t I f I i > i » I i f f i f I I | I i i » t | i t i i i | i i i i i i t i > i i | i i ) v t ill)—i—i—i--i i -i r r i t
31:12 31: 18 31:24 31:30 31:36 31:42 31:48 31 :54 32 : 00 32:06 32:12 32 : 18 32^24
TLI#42»
.3 . 6E4
-2.9E4
.2 . 2E4
.1.5E4
.7 . 3E3
.0.0E0
Time
TLI# 4 2 »
.3.8E4
.3 . 0E4
.2 . 3E4
.1.5E4
.7.6E3
. 0.0E0
Time
File:S975668 #1-390 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
417.8253 F:4 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A
100% 31;22
INJ. TIME
07:33 File Text:RUN 3 TLI#42»
31 :53
32 : 16
31:12 31:18 31:24 31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24
1
5E5
Li
2E5
i9
1E4
1,6
0E4
:„3
0E4
Lo
0E0
Time
-------
File:S975668 #1-390 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
457.7377 F:4 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A INJ. TIME = 07:33 File Text:RUN 3
100%, 33*39 34; 40
32:24
* 2:43
(1 33:15
r p—
32 100
File:S975668 #1-390 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 7 0S
459.7348 F:4 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A
100%
31:29
31:16
TLI#42»
1.2E4
9 . 7E3
34:08 34.30
7 .3E3
35:34
4.9E3
2 . 4E3
35:00
INJ. TIME = 07 : 33 File Text:RUN 3
34:39
0.0E0
Time
TLI#42»
_2.2E4
1.8E4
1.3E4
33 :37
8.9E3
34:11
31:40 31:59
33 :05
35:13
32:24
4.5E3
33 :00
32:00
t 1 *—r* 1——i 1 1 1 r~
34:00 35:00
File:S975668 #1-390 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
469.7779 F:4 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A INJ. TIME = 07:33 File Text:RUN 3
100% 34 ; 39
80 j
60i
40J
20 J
0
32 :24
33:37
35:39
32:00
33 :00
34:00
35 : 00
.0.0E0
Time
TLI#42»
-1.8E5
.1.4E5
.1.1E5
.7 . 1E4
,3 . 5E4
0.0E0
Time
» OO
CD
-------
File:S975668 #1-390 Aeq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
457.7377 F:4 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A INJ. TIME =
Text:RUN 3
TLI#42»
.1.2E4
Q7.:33 File
5E4 )
100%
9.7E3
7 .3 E3
4 . 9E3
2 . 4E3
1 1 1——-r-
32:00 33:00 34:00
File:S975668 #1-390 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
459.7348 F:4 Exp:EPCUS
Sample Text :RUN 3 TLI#42930A INJ. TIME
35:00
07:33 File Text:RUN 3
.0 . 0E0
Time
TLI# 4 2 »
_2.2 E4
A4.55E4 ;
100%
1.8E4
1 ,3E4
8.9E3
4 . 5E3
0 . 0E0
Time
32100 33:00 34:00 35100
File:S975668 #1-390 Acq:5-SEP-97 07:31:00 EI+ Voltage SIR 70S
469.7779 F;4 Exp:EPCUS
Sample Text:RUN 3 TLI#42930A INJ. TIME = 07:33 File Text:RUN 3
100% 34; 39
80i
60i
40
20
32 :00
32:24
~iii f ^ •—
33:37
^ ^ A — r
33:00
34 :00
35T00
35:39
~4_
TLI#42»
.1. 8E5
^1. 4E5
-1. 1E5
.7 . 1E4
.3 . 5E4
^0.0E0
Time
QO
-4
-------
EastemResearch Group
I
TLI Project: 42930A
Client Sample: RUN3
Method 23 TCDD/TCDF Analysis (DB-225) I
Analysis File: X973015
Client Project:
Sample Matrix:
TLI ID:
Iron & Steel-Youngstown
M23TRAIN Date Received:
179-98-3A-D Date Extracted:
Date Analyzed:
08/19/97
08/25/97
09/06/97
Spike File:
ICal:
ConCal:
SPC2NF04
XF24087
X973009
Sample Size:
1.000
Dilution Factor:
n/a
% Moisture:
n/a
Dry Weight:
n/a
Blank File:
S975665
% Lipid:
n/a
GC Column:
DB-225
Analyst:
ML
% Solids:
n/a
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Analytes
Anrt. (ng)
Dt EMPC
Ratio
RT
Flags
2,3.7,8-TCDF
11.5
0.77
23:03
—
Internal Standard
Amt. (ng)
% Recovery QC Limits
Ratio
RT
Flags
uCtr2,3,7,8-TCDF
3.3
82.3 40%-130%
0.78
23:02
—
Recovery Standard
Ratio
RT
Flags
l3Ci:-1,2,3,4-TCDD
0.81
22:02
Data Reviewer S£j ,
09/08/97
Page 1 of 1
C2NF.PSR v2.00, LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:56 0a/Q8/;
-------
Initial ....Date...
Data Review By: Calculated Noise Area: n/a
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
09/03/97
Listing of X973015B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z... . QC.Log Omit Why
.RT. OK "Ratio Total.Area.. . Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
304-306
13C12-TCDF
316-318
0 .
65-0.89
0.793-1.102
DC
NL
0: 00
RO
1.58
12.30
0 . 000
DC
WL
18: 15
0.36
55.11
0.792
18:23
RO
6. 30
738.13
2,629.14
417.02
0.802
18: 49
RO
4.18
578.47
1,366.92
326.32
0.317
18: 56
RO
1.03
14,658.13
8,497.06
8,281.43
0.822
19:09
RO
0 . 97
213.09
117.35
120.39
0.331
19:22
RO
0 . 47
194.10
34 . 44
180.32
0.841
19:27
0. 66
179.51
71.48
108.03
0. 344
19:48
0.77
22,046.53
9,605.98
12,440.60
0.360
19: 55
0.78
12,587.33
5,533.31
7,053.52
0. 365
20:04
0. 35
14,573.10
6,637 . 34
7,385.76
0.371
20:11
0.77
13,191.94
5,748.34
7,443.60
0. 376
20: 23
0. 30
10,624.40
4,725.70
5,398.70
0. 339
20: 35
0.79
19.235.91
8,471.71
10,754.20
0. 394
20:43
0 . 77
8.076.35
3,522.32
4,554.03
0 . 399
20: 51
0.78
33.419.60
14,607.50
13,312.10
0.905
20: 59
0.78
6,797.20
2,970.00
3,327.20
0.911
21:21
0.77
30,450.20
13,230.10
17 , 170.10
0.927
DC
SN
21: 33
RO
2. 16
9.50
0.936
21:46
0.87
17,733.67
3,250.96
9,482.71
0 . 945
22:00
0.78
10,527.78
4,607.06
5,920.72
0.955
22: 12
0.76
12,250.41
5,273.50
6,976.91
0 . 964
22:23
0.89
979 .52
461.78
517.74
0 . 972
22: 32
0.80
7,859.78
3,503.08
4,356.70
0 . 978
22: 56
0 . 31
6.267.39
2,812.59
3,454.80
0.996
23 03
0.77
7,228.64
3,135.29
4,093.35
1.001 237
23:16
0.79
6,211.19
2,736.19
3,475.00
1.010
23:31
0.78
5,469.61
2,392.68
3,076.93
1.021
23:39
0.76
9,462.27
4,094.35
5,367.42
1.027
23: 50
RO
4 . 49
20.02
50.76
11.31
1.035
24:26
0.75
4,211.56
1,807.62
2,403.94
1.061
25:09
0 . 76
486.88
210.44
276.44
1.092
29
Peaks
276,273.26
0
65-0.89
0.
956-1.044
DC
NL
0 : 00
0.76
24.47
0.000
DC
WL
18:15
RO
2.90
14.97
0.792
DC
WL
18:32
RO
3.24
33 .72
0. 305
DC
WL
18:46
0. 67
316.03
0.815
DC
WL
18:55
RO
2. 39
19.05
0.821
DC
WL
19: 34
RO
3.85
11.29
0. 849
DC
WL
21:59
RO
1.32
25.74
0.954
DC
SN
22:03
RO
0. 62
7.38
0.957
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:56 09/08/97
189
-------
Page No.
09/03/97
Listing of X973015B.db£
Matched GC Peaks / Ratio / Ret, Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area,,. Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
316-313
23:02 0.78 2,605,05
DC WH 24:11 RO 0,02 6,02
CC WH 24:13 RO 1.94 8.28
1 Peak 2,605.05
1,144.35 1,460.20 1.000 13C12-2378-TCDF ISO
1.050
1.055
Above: TCDF / TCDD Follows
13C12-TCDD
332-334
0.65-0.89
0.907-1.093
332-334
DC
ML
o
o
o
RO
1. 91
7.59
0.000
DC
SU
20:07
RO
2.26
2.35
0,923
DC
SN
20:43
RO
0.58
6.46
0. 951
DC
SN
20: 52
RO
2.42
6.78
0. 958
DC
m
21: 14
RO
1, 06
5.06
0.975
21:47
0.80
1,932.39
857.29
1,075.10
1.000
22: 02
0.31
2,273.88
1,014.12
1,259.76
1.011
22:41
RO
0.58
31.63
13.76
23.84
1.041
DC
SN
23:08
RO
1.23
5.54
1.062
DC
SN
23: 12
RO
0.98
6.31
1.065
DC
SN
23:20
RO
4.38
3.56
1.071
DC
SN
23:26
0.39
7.IS
1.076
DC
SN
3
23: 34
Peaks
RO
0.43
10.85
4,237.90
1. 082
Column Description.
"Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
..RT. -Retention Time (mm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.ST-Relative Retention Time
End of Report
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
\Pil»iJB7TBI5 *1-1285 Acg; S-3SP-1S97 23,33,10 X SI* Volbmgm SIR luboSpme
303.9016 Expixcaarjn
Sampl* rrniKbtWam TLI04293OA Film Tmxt: TRXABBLX ZJLBS
lOCSf
95.
SO.
85s
80L
7 Si
70s
65s
60s
55s
.2.1X7
SOs
40s
,1.5X7
35s
30s
1.2X7
25.
.9.7X6
20s
15.
10.
3.9X6
,1.9X6
'.Q.QBQ
21 s 00 Tima
19:00 19i12 19x24 19:36
*1103X973015 #1-1285 Acq: 6-SXP-1S97 22:32:10 OC SI* Vol tag* •SXJfc
305.8987 BxpsXCONFJTT
Saapl• T*xt:R0I13 TLX04293OA Film Tmxt: TRXABBLX LABS
100H
20:36
20:51
-5.0B7
95s
4.8X7
.4.5X7
85s
.4.3X7
80s
4. 0X7
75s
.3.8X7
70s
,3.5X7
65.
60.
3.0B7
55.
2.8X7
.2.3X7
35s
30s
,1.5X7
,1.3X7
20s
15s
10s
^-.-.0,0X0
21:00 Tim*
19:12
19
-------
\9ilmxXS7301S il-13»S Aog« S-SBP-19S7 22i32xl0 X IT
303.9016 BSUB(256,30, -3.0) PXD(S, 3,1.0.10*,22028. 0, 0
Saaplm TaxtxXOm TLX§42930A HI* Taxtx TBXABOLX LABS
100%
bo:
so:
*o:
19:00 20x00 21tOO 22tOO 23x00 2*t00 25>00
PilmxX973015 §1-1295 Aeqx 6-3XP-1997 22x32x10 QC MX* Voltmga 3X11 AutoSpme Soi»mx3475
30S.8987 BSBB(2SS,30,-3.0) MO(3,3,1,0.10\, 13900.0,0. 00%,P,P) XxpiZCOBP_TT
Sawpl* TrnxbiKUm TLX*42930* film Taxtx TSXAHOLX LABS *
100ft
i"l i *w s ^ i i* i' 'I 'i*t* ( r '"n 11' "'i' ' i 1 I' I ^ I * m M'
19tOO 20>00 21t00 22t00 23>00 24>00
Plla>Z973015 §1-1285 Acqx 6-SXP-1997 22>32tl0 QC EX* Vol tag# SXR AutoSpme HK>ia*tS292
315.9419 SSOB (256, 30, -3. 0) Pm(5,3,l,0.10%,21168.0,0.00%,P,P) XxpxXCOm_TT
sawlm TrnxtiMXjm TLX§42930A Film Taxtx TRXAMLX LABS
Volkaga SIM luto3pae Hoia;5507
00%,P,f) ttp»XCQHF_T*
6X8
AS. 50X7
201
•U
M
L
AS. 61X7
A8.25X7
AS.27X7
A3.SOS7 A4.09X7
A1.81M7
A
_3.8X7
13.1X7
12.3X7
11.5X7
17.7X6
10.0X0
Tim*
S.0X7
4.0X7
A1.24X8
3.0X7
A9.48X7
A8.28X7
.44X7
AS. 98X7
2.0X7
AS.37X7
A4.36X7
A3.4
1.0X7
A2.40X7
0.0X0
25t00
100*
80.
60.
40.
20.
A1.14X7
AX.27X6
AiAi
.3.1X6
12.5X6
1.8X6
.1.2X6
,6.2X5
I I 11 'l'1"
Hp
T.
iM,r i" i t | i i
25*00 20>00 21x00 22x00 23x00 24x00
PilmtZ973015 §1-1285 Aoqx 6-3XP-1997 22x32x10 OC MX* Vol tag* SIR AatoSpmc Solaa>6943
317.9389 BSVB(256,30, -3.0) PSD(5,3,1,0.10%,27772.0, 0. 00%,P,P) JB*p»ICCMF_W,
SanplB Tmxt xKOm TLX04293OA Film Ttoctx TXXAmLX LABS
25x00
.0.0X0
Tima
100*
ao:
60.
40.
2C0
0.
A1
46X7
A1.89X6
A'7\
f" I ¦ I I"1 I
20 too
19i00 20x00 21x00 22>00 23x00 24x00
PllaxX973015 §1-1285 Acqt 6-3XP-1997 22x32x10 OC XX* Voltmga SIX AatoSpaa
375.8364 Xsp>XC0BF_n
Sample TmxtxJtum TLX842930A Pila Tmxtx TXXASOLX LABS
10<* 22t41
^panl|B
A1.74X6
3.7X6
3.0X6
2.2X6
.1.5X6
17.5X5
I 'I
1 "i
i"" r* i i
25x00
.0.0X0
Tima
6.7X4
5 .4X4
24x09
4.0X4
23x15
20 >08
2.7X4
1.3X4
0.0X0
-1—1—I—I-
19 tOO
20i00
21x00
22 >00
23x00
24x00
192-
I
-------
Pilm,X97mS #1-1385' leg, S-3BP-1997 23,32,10 X MI* VoXbmgm SIS XuboSpmc Holm;3076
319.8965 BSUB(256,30, -3.0) PKB{5,3,1, 0.10%, 12280.0, 0.00%,F,F) XXptXCONF^TT
Sma^lm Tmxt,Sam TLX*42930A Film Tmxt, TXXAM&X LABS
100S
80C
60.
to:
20.
I P*m I >
20,00 21tOO 22,00 23,00 24,00
Pllm,1973015 *1-128$ Acq, 6-SSP-1997 22,32,10 QC XX* Voltmgm SIR AutoSpmc Soimm,15820
321.8936 BSUB(256,30, -3.0} FKD(5,3,1. 0.10%, 63280.0, 0.00%,F,F) Xxp,ZCOSF_TT
Sam>l» Tmxt,RONS TLX*4293OA Film Tmxt, TSXAHOLX LABS
100m A4.02X6
20,00 21,00 22,00 23,00 24,00
Film,X973015 *1-1285 Acq, 6-SBP-1997 22,32,10 OC XX* Voltagm SIR AutoSpmc Noimm,3085
327.8847 BSVB(256,30,-3.0) FED(5,3,1,0.10*, 12340.0,0.00%,F,F) Xxp,ZCQNF_TT
Samplm Tmxt,RON3 TLX842930A Film Tmxt, TRXANBLX LASS
100m
A4.09*6
(L,
A1.09S.;
.jy] i
A4.04X6
A3.56X6
A2.88X6
8.10X5
A3.22X6
AX,60X6 A ft
A1.88X6
4.09X5
AS.04X5
Jx
A8.19X5
i
.1.4X6
.1.1X6
.8.5X5
.5. 7X5
.2.8X5
.0. 0X0
Timm
1.4X6
1.1X6
A2.94X6
A2.93X6
8.5X5
A4.37X6
A3.68S
A2.24B6
5.7X5
12.8X5
A4.29X5
AA.94X5
^.
6.01X5
0.0X0
•I i " i™ i' '"i i * 1—r" f1 'r i i " i i * ir i^"| ¦ i '"i" i i1 11 I
20,00 21,00 22,00 23,00
Film,X973015 *1-1285 Acq, 6-SXF-1997 22,32,10 OC XX* Voltmgm SIR AutoSpmc Soi»m,4099
331.9368 BSVB(256,30, -3.0) PKD(5,3,1, 0.10%, 16396.0, 0. 00%,F,F) Xzp,XCaBF_TT
Sample TmxtsRXna TLX842930A Film Tmxt, TRIASOXM LABS
iom
80.
6o:
40.
20.
Al.01X7
A8.57X6
-4
—.
i" 'i'
20,00 21,00 22,00 23,00 ' 24,00
Film,1973015 #1-1285 Acq, 6-SXP-1997 22,32,10 OC XX* Voltmgm SXR AutoSpma Soimm,2146
333.9338 BSOB(256,30,-3.0) FXD(5,3,1,0.10%,8584.0,0.00%,F,F) S*p»XCOSr_5T
Samplm Tmxt,ROSS TLX04293OA Film Tmxt, TSXASOLX LABS
101a
801
eo.:
40.
20.
0.
A1.26X7
A1.08X7
20,00
U
21,00
22,00
23,00
'' l '
24,00
Timm
Al. 71X7
4.9X6
A1.09X7
_3.9X6
3.0X6
A1.12X7
A6.64X6
'2.0X6
A3.85X6
A3.00X6
A3.60X6
19.9X5
24,00
.0.0X0
Timm
,3.1X6
.2.4X6
.1.8X6
11.2X6
L6.1X5
.0.0X0
Timm
3.9X6
13.1X6
12.3X6
1.6X6
7.8X5
10. 0X0
Tlma
193
-------
Film: X373015 *1-1285 Acq, 6-SSP-IS97 22>32:10 QC EX* Voltagm SIR AutoSpmc
303.8016 KxpiXCQ8P_TT
Smaplm TmxttX0B3 &X§42930A Film Tmxt, TKZUBLB LXBS
20)51
18,56 19>*S
loan
80.
60.
40:
20.
oj
i ' if ' i i—
19 too 20,00 21 too 22x00 23x00 2it00 25t00
Pllm,Z973015 91-1285 Acqt 6-SXP-1997 22i32tl0 OC XI* Voltmgm SIX AutoSpme
315.9*19 XxptXCOSFJTT
smm'!• TmxttMOm TLI§42930A Film Tmxt, TRXADSLX LABS
18,28
,J\. P..
21,2131'*6
K
22112
23103 .
Ma A.
23,39
24 >26
~/\ i'
19,00 20't00 21,00 22,00 23,00 24,00
FilmtZ973015 §1-1285 Acq, 6-SXP-1997 22,32,10 OC BX* Voltmgm SIR AutOSpme
319.8965 Bxp,XeONP_TT
Smapl* Tmxt tKU!T3 TLX942930A Film Tmxt, TXXAHOLX LABS
19,35
19,00 20,00 21i00 22,00 23,00 24>00
Film,X97301S §1-1285 Acq, 6-SBP-1S97 22t32t10 OC BX* Voltmgm SIR AutoSpmo
331.9368 BxpiXCOBPJTT
Saaplm Tmxt,XOS3 TLX942930A Film Tmxt, TRXABBLX ZABS
10m 22,02
3 21,47\
SOU
60d
4ol
2o|
oi
f i i "r111 i i i1 "i" i i' i f 'iwi >r i i i "i-
19,00 20,00 21,00 22,00 23,00
Pllm,X$73015 §1-1285 Acq, 6-SXP-1S97 22,32,10 OC MX* Voltmgm SIR AutoSpmo
292.9825 XxptXCOSF TT
Smaplm Tmxt, Rtm3 TLI942930A Film Tmxt, TSXASOLX ZABS
10
-------
Peak Locate Examination: 6-SEP-1997:22:31 File:X973015
Experiment:XCONF_TT Function;! Reference:PFK
Volts
0.3358
Volts
0.5055
PPM
200
Volts
0.4318
PPM
200
PPM
200
n.u.ai ifti i u 1 llfiii
292.95315 292.98245 293.01175
380.93795 380.97604 381.01414
330.94615 330.97925 331.01235
» CO
U1
-------
I
TLI Project: 42930A
Client Sample: FBI
Client Project:
Iron & Steel-Youngstown
Sample Matrix:
M23TRAIN
Date Received:
08/19/97
Spike File:
SPX23704
TLI ID:
179-98-4A-D
Date Extracted:
08/25/97
ICal:
SF56117
Date Analyzed:
09/05/97
ConCal:
S975664
Sample Size:
1.000
Dilution Factor:
n/a
% Moisture:
n/a
Dry Weight:
n/a
Blank File:
S975665
% Lipid:
n/a
GC Column:
DB-5
Analyst:
HLM
% Solids:
n/a
Method 23 PCDD/PCDF Analysis (a) |
Analysis File: S975669 "
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Analytes
Amt. (ng)
DL 1
Ratio RT Flags |
2,3,7,8-TCDD
ND
0.01
1,2,3.7.8-PeCDD
ND
0.02
1,2,3,4,7,8-HxCDD
ND
0.02
1,2,3,6,7,8-HxCDD
HD
0.01
1,2.3,7,8,9-HxCDD
ND
0.01
1.2,3,4.6,7.8-HpCDD
ND
0.02
1,2,3,4,6,7,8,9-OCDD
EMPC
0.07
—
2,3,7,8-TCDF
EMPC
0.05
1,2,3,7,8-PeCDF
ND
0.01
2,3,4,7,8-PeCDF
ND
0.01
1,2.3,4,7,8-HxCDF
ND
0.01
1,2,3,6,7,8-HxCDF
ND
0.007
2,3.4.6,7,8-HxCDF
ND
0.01
1.2,3,7.8,9-HxCDF
ND
0.01
1,2,3,4,6,7,8-HpCDF
ND
0.01
1,2,3,4,7,8,9-HpCDF
ND
0.02
1,2,3,4,6,7,8,9-OCDF
ND
0.03
Total TCDD
ND
0.01
Total PeCDD
ND
0.02
Total HxCDD
EMPC
0.02
Total HpCDD
EMPC
0.04
Total TCDF
0.02
1
0.31
Total PeCDF
EMPC
0.02
Total HxCDF
ND
0.009
Total HpCDF
ND
0.01
Page 1 of 2
X237JPSR v200, LARS & 10.04
Triangle Laboratories, Inc.®
801 Caprtola Drive • Durham,
North Carolina 27713
Printed: 16:28 09/08/97
Phone: (919) 544-5729 • Fax: (919) 544-5491
196-
-------
TLI Project: 42930A Method 23 PCDD/PCDF Analysis (a)
Client Sample: FBI Analysis File: S975669
1 internal Standards
Amt {ng}
% Recovery
QC Limits
Ratio
RT
Flags
,3C,2-2,3,7.8-TCDF
3.2
79.4
40%-130%
0.76
20:44
l3Ci2-2,3,7,8-TCDD
3.1
76.6
40%-130%
0.83
21:32
13Ci;-l,2.3,7,8-PeCDF
2.9
71.9
40%-130%
1.64
24:58
,3C,2-1,2.3,7,8-PeCDD
2.8
69.5
40%-130%
1.43
26:04
13C!2-1,2,3,6,7,8-HxCDF
3.8
94.1
40%-130%
0.51
28:38
13Ci2-l,2,3,6,7,8-HxCDD
3.5
86.8
40%-130%
1.21
29:21
13Ci2-l,2,3,4,6,7,8-HpCDF
3.1
77.8
25%-130%
0.42
31:19
13Ci2- 1,2,3,4,6,7,8-HpCDD
3.2
80.7
25%-130%
1.03
32:09
,3Ci;-l,2,3,4,6,7,8.9-OCDD
4.3
54.0
25%-130%
0.96
34:37
—
| Surrogate Standards {Type A)
AmL (ng)
% Recovery
QC Limits
Ratio
RT
Flags
"CL-2,3,7,8-TCDD
3.9
98.5
70%-140%
21:32
l3Ci2-2,3,4,7,8-PeCDF
3.4
84.1
70%-140%
1.75
25:42
13Ci2-l,2,3,4,7,8-HxCDF
3.4
85.9
70%-140%
0.50
28:32
l3Ci:-l,2,3,4,7,8-HxCDD
3.6
90.3
70%-140%
1.22
29:16
l3Ci2-l,2,3,4,7,8,9-HpCDF
3.0
75.5
70%-140%
0.40
32:30
—
| Alternate Standards (Type A)
Amt (ng)
% Recovery
QC Limits
Ratio
RT
Flags
13Ci2-l,2,3,7,8,9-HxCDF
3.3
82.6
40%-130%
0.50
29:51
13Ci2-2,3,4,6,7,8-HxCDF
3.6
90.4
40%-130%
0.50
29:08
—
| Recovery Standards
Ratio
RT
Flags
l3Ci2-l,2,3,4-TCDD
0.81
21:19
I3Ci2-l,2,3,7,8,9-HxCDD
1.25
29:39
Data Reviewer 09/08/97
Page 2 of 2 X237J>SR vlOO. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive* Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 16:28 09/08/97
197
-------
Initial ....Date...
Data Review By: Calculated Noise Area: 1.19
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method retirements.
Page No.
09/03/97
Listing of S97S669B.dbf
Matched GC peaks / Ratio / Ret. Time
Compound/
K_Z. . . . QC
TCDF
304-306
MK
A
304-306
13C12-TCDF
316-313
316-313
Omit
Why
. .RT.
OK
¦Ratio Total
.Area... Area
Peak.1.. Area
Peak. 2. .
Rel.RT Compound.Name..
0.
65-0.89
0.827-1,099
DC
NL
0
00
RO
1.21
0.25
0,000
DC
SN
17
17
RO
1.12
8.41
0.834
DC
SN
18
04
RO
1.18
3.52
0.871
13
28
RO
1.02
27.13
15.63
15.33
0.891
18
50
¦RO
1.01
16.09
9.20
9 .09
0.908
19
16
RO
0.93
3.12
4.25
4.59
0. 929
19
35
RO
0.93
11.75
6.17
6.S4
0. 945
DC
SN
19
55
RO
1.18
7.01
0.961
DC
SN
20
04
RO
0.54
6.37
0.968
20
16
ao
0. 92
11.45
5.93
6.47
0.977
20
33
RO
0. 56
7.47
3.25
5.81
0.991
20
46
RO
0.53
13.85
3.20
13 .06
1.002 2373-TCDF
21
12
0.?3
3.03
3.39
4.64
1.023
DC
SN
22
37
RO
0.S4
2.44
1. 091
8
Peaks
108.39
0
65-0.89
0.
952-1.048
DC
NL
0
00
RO
0.93
0.27
0. 000
DC
ML
18
59
RO
1.1S
2.51
0. 916
DC
WL
19
27
RO
0.17
0.67
0.938
DC
SN
19
53
RO
0.35
2.00
0. 959
DC
SN
20
07
RO
0.17
0.69
0.970
20
44
0.76
1,137.70
492.16
645.54
1.000 13C12-2373-TCDF
DC
SN
21
32
RO
0. 62
2.60
1.039
DC
WH
21
45
RO
0.16
0.78
1 .049
DC
WH
22
20
RO
2.19
0.76
1.077
DC
WH
22
50
SO
1. 51
1.68
1.101
1
Peak
1.137.70
ID.. Flags.
AN
ISO
Above: TCDF / TCDD Follows
TCDD
320-322
0.
65-0.89
0.861-1.058
DC
NL
0
00
RO
0. 92
0.21
0. 000
DC
SN
19
35
0.76
0.37
0.909
DC
SN
19
45
RO
1.53
1.29
0.917
DC
SN
20
12
RO
3.83
0.64
0.938
DC
SN
20
27
RO
0.54
0.46
0.950
DC
SN
20
39
RO
1. 39
0.55
0.959
DC
SN
20
54
RO
0.27
0.28
0.971
DC
SN
20
57
0.77
1.17
0.973
DC
SN
21
06
RO
3.00
0.23
0.980
DC
SN
21
12
RO
0. 41
0.32
0.985
DC
SN
21
31
RO
0.90
3.61
0.999 2378-TCDD
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capiioia Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 16:29 09/08/97
198"
-------
Page No. 2
09/08/97
Listing of S975669B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log
Omit
Why
. . RT.
OK
Ratio Total
.Area... Area.
.Peak.1.. Area.Peak.2..
Rel.RT Compound.Name..
DC
SN
21: 57
0.76
1.46
1 . 019
DC
WH
22: 53
RO
1. 84
0 .44
1.063
320-322
0
Peaks
0.00
37C1-TCDD
0.
907-1.093
328
DC
NL
0: 00
0.13
0.000
DC
WL
19:02
0.90
0.384
DC
WL
19:07
1 . 54
0 . 883
20: 00
33 .70
33 .70
0.929
DC
SN
20:27
0.41
0.950
DC
SN
20:31
0.61
0.953
DC
SN
20: 50
1.01
0. 967
DC
SN
20: 59
0.71
0 . 974
21:32
737 .20
737.20
1.000 37C1-TCDD
DC
SN
21: 59
2.01
1 . 021
DC
SN
22:24
0.57
1.040
DC
SN
22:29
1.11
1 . 044
DC
SN
22: 36
1.78
1.050
DC
SN
22:46
0 . 87
1.057
DC
SN
23:01
0.67
1. 069
323
2
Peaks
770.90
13C12-TCDD
0.
55-0.39
0 .
907-1.093
332-334
DC
NL
0:00
RO
9 . 86
0.25
0. 000
DC
WL
18: 50
RO
14 . 09
0.19
0. 375
DC
SN
19: 36
RO
3 . 07
1.54
0. 910
20: 16
RO
0.94
7.36
3.93 4.16
0. 941
DC
SN
20: 37
RO
1.70
2 .60
0. 957
21:19
0.31
1,087.83
483.20 599.63
0.990 13C12-1234-TCDD
21:32
0.33
887.75
403.92 483.33
1.000 13C12-2 378-TCDD
21:54
RO
1.04
16.43
9.65 9.28
1.017
DC
SN
22: 34
RO
15 . 67
0.32
1.043
DC
SN
22:53
RO
1 . 17
2.80
1.063
332-334
4
Peaks
1,999.37
Flags.
Above: TCDD / PeCDF Follows
PeCDF
340-342
1.
32-1.78
0.910-1.076
DC
NL
0:00
RO
1 . 00
0.21
0.000
DC
SN
23:05
RO
0.28
0.67
0. 925
DC
SN
23:26
RO
0.45
0.84
0.939
DC
SN
23:41
RO
0.37
0.53
0.949
DC
SN
23:48
RO
0.47
0.67
0.953
DC
SN
23:55
RO
0.26
0.44
0.958
24:04
RO
0.94
4.64
2.32
3.00 0.964
DC
SN
24: 12
RO
1.01
1.84
0 . 969
DC
SN
24:37
RO
0.70
1.99
0 . 986
DC
SN
24: 51
RO
1 . 31
1.74
0.995
DC
SN
24: 58
RO
1.01
1.96
1.000 12378-PeCDF
DC
SN
25: 16
RO
0.54
1.40
1 . 012
DC
SN
25:20
1.49
1.17
1.015
DC
SN
25:23
RO
4.10
0.51
1.017
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713 Printed: 16:29 09/08/97
Phone: (919) 544-5729 • Fax: (919) 544-5491 199 -
-------
Page No. 3
09/08/9?
Listing of 5975669B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z,,.. QC.Log Omit Why -.RT.
OK Ratio Total.Area.
Area.Peak.1.. Area.Peak.2.. Rel.RT Compound,Name.. ID.. Flags.
340-342
DC
SN
25
42
RO
1 .04
2.45
1.029
DC
SN
25
55
RO
0. 56
2.29
1.038
DC
SN
26
11
1. 36
1.75
1.049
DC
SN
26
26
RO
Q . 60
0.89
1.059
DC
SN
26
34
RO
0.78
0.63
1.064
DC
SN
26
42
RO
0.03
0.05
1.069
DC
SN
26
52
RO
0.71
0.49
1.076
DC
WH
26
58
SO
0.50
0.59
1.080
DC
WH
27
07
1.37
2,18
1.086
1
Peak
4.64
AN
13C12-PeCDF
1 .
32-1.78
0.840-1.160
352-354
DC
NL
0
00
RO
1 . 08
0.21
0.000
DC
SN
24
04
SO
1.03
5.07
0.964
24
58
1. 64
886.73
551.39
335.34 1.000 13C12-PeCDF
DC
SN
25
06
RO
1.32
7.38
1.005
25
15
1.75
10.05
6.40
3,65 1.011
DC
SN
25
27
RO
2.95
1.02
1.019
25
42
1.75
723.65
460.23
263.42 1.029 L3C12-?eCDF
DC
3N
26
00
RO
2 .44
2.88
1.041
DC
SN
26
52
RO
1 . 90
0.51
1.076
DC
SN
27
10
RO
2.74
0.59
1.033
352-354
3
Peaks
1,620.43
PofTYC / Dornn
Follows ———
PeCDD
I
32-1.78
0.923-1.025
356-358
DC
NL
0
00
RO
1.08
0.23
0.000
DC
ML
24
00
1. 39
1.34
0.921
DC
SN
24
25
RO
0.37
1.18
0. 937
DC
SN
24
45
RO
18. SO
0.10
0. 949
DC
SN
24
48
RO
0. 98
0.92
0.951
DC
SN
24
57
RO
2.42
1.50
0.957
DC
SN
25
09
RO
10.10
0.54
0.965
DC
SN
25
56
1.42
1.38
0.995
DC
SN
26
06
RO
0 . 97
1.91
1.001 12378-PeCDD
DC
SN
26
13
RO
1.97
0.74
1.006
DC
SN
26
28
RO
0.77
0.38
1.015
DC
SN
26
33
RO
4.35
0.51
1.019
DC
WH
26
47
RO
0.28
0.21
1.027
DC
WH
26
52
RO
5.15
0.66
1.031
356-358
0
Peaks
0.00
13C12-PeCDD
1
32-1.78
0.847-1.153
368-370
DC
NL
0
: 00
RO
1 . 00
0.21
0.000
DC
SN
25
: 05
RO
2.78
1.15
0.962
DC
SN
25
: 13
RO
0.30
0.58
0.967
DC
SN
25
: 21
RO
1.00
0.79
0.973
DC
SN
25
: 29
RO
2.33
0,99
0.978
26
: 04
1.43
480.00
282.50
197.50 1.000 13C12-PeCDD
26
: 12
RO
2.04
49.60
39.75
19.45 1.005
DC
SN
26
: 3 3
1.66
0.85
1.019
AN
IS3
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 16:29 09/08/97
200
-------
Page No. 4
09/03/97
Listing of S975669B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log
Omie
Why
. .RT.
OK
Ratio Total
.Area. . .
Area.Peak. 1. . Area
Peak.2.. Rel.RT Compound.Name..
ID. .
DC
SN
26
58
RO
7.24
0.54
1 .035
363-370
2
Peaks
529.60
Darnn /
rev-yu /
rtx^ut roiiows — —— —.
HxCDF
1
05-1.43
0.957-1.051
374-376
DC
NL
0
00
RO
-7.39
0.20
0.000
DC
SN
27
34
RO
4.42
0. 54
0.963
DC
SN
27
57
RO
1 . 57
1.19
0.976
DC
SN
28
03
1.21
0.62
0.980
DC
SN
28
10
RO
2.74
0.43
0.984
DC
SN
28
20
1.16
2.16
0.990
DC
SN
28
32
RO
2.03
2.15
0.997 123473-HxCDF
AN
DC
SN
28
38
RO
1.75
1.50
1.000 123678-HxCDF
AN
DC
SN
28
56
RO
0.72
1.39
1 .010
DC
SN
29
03
RO
0 . 44
0.42
1,015
DC
SN
29
09
RO
1. 33
3.34
1.013 234673-HxCDF
AN
DC
SN
29
16
RO
0.46
0.29
1.022
DC
SN
29
20
RO
1. 56
1.16
1. 024
DC
SN
29
27
RO
1. 52
0.65
1.029
DC
SN
29
39
RO
2.23
0.37
1.036
DC
SN
29
48
RO
1.00
1.12
1.041
DC
SN
30
02
RO
2.29
0.78
1.049
DC
SN
30
06
RO
3 .13
0.38
1,051
DC
WH
30
11
RO
1.00
0.65
1.054
DC
MH
30
15
RO
0.26
0.49
1.056
DC
WH
30
28
RO
1.88
1.93
1.064
374-376
0
Peaks
0.00
13C12-HXCDF
0
43-0.59
0.860-1.140
334-386
DC
NL
0
00
RO
1.07
2.67
0. 000
28
32
0. 50
365.18
289.63
575.50 0.991 13C12-HXCDF 478
SUR3
28
38
0. 51
1.049.66
356.52
693.14 I.000 13C12-HxCDF 673
IS4
DC
SN
28
51
RO
1.32
3.44
1.008
29
08
0. 50
933.73
311.76
621.97 1.017 13C12-HxCDF 234
ALT 2
DC
SN
29
26
0. 59
2.39
1 .028
DC
SN
29
36
RO
1.60
0.33
1 .034
DC
SN
29
41
RO
0.38
0.98
1 .037
29
51
0. 50
741.37
248.70
493.17 1.042 13C12-HXCDF 789
ALT1
DC
SN
30
04
RO
1. 32
3.02
1.050
DC
SN
30
10
RO
1.32
1.12
1.054
384-386
4
Peaks
3,590.44
Above: HxCDF / HxCDD Follows
HxCDD
1
05-1.43
0.952-1.015
390-392
DC
NL
0:00
RO
2.27
1
01
0.000
K
28:05
RO
0.94
4
19
2.32
2.46 0.957
DC
SN
28:08
1.09
0
90
0. 959
DC
SN
28:16
1.20
0
90
0.963
DC
SN
28:23
1.38
0
69
0.967
DC
SN
28:33
RO
1.51
2
80
0.973
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713 Printed: 16:29 09/08/97
Phone: (919) 544-5729 • Fax: (919) 544-5491 201*
-------
Page No. 5
09/08/97
Listing of S975669B.dbf
Macched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC
390-392
13C12-HXCD0
402-404
402-404
Dmic
Why
. .RT.
OK
Ratio Total
.Area... Area.Peak. 1.. Area.Peak.2..
Re I. RT
Compound.Name..
ID. .
DC
SN
28
36
1.08
2.06
0.974
DC
SN
28
46
1.14
6.73
0.980
DC
SN
28
51
RO
0.59
1.21
0.983
DC
SN
29
05
SO
1.95
0.43
0.991
DC
SN
29
08
SO
2.80
1.14
0.993
DC
SN
29
11
RO
0. 80
1.01
0.994
DC
SN
29
17
- 1.17
2.13
0.993
123478-HxCDD
m
DC
SN
29
22
RO
0.79
2.13
1.001
123678-HxCDD
AN
DC
SN
29
38
RO
0.56
1.34
1.010
123789-HxCDD
AN
DC
SN
29
46
RO
0. 56
0.45
1. 014
1
Peak
4.19
1
05-1.43
0.966-1.034
DC
NL
0
00
RO
0.64
1.05
0.000
DC
WL
27
57
RO
2.00
0.47
0.952
DC
WL
28
13
RO
0.66
0.94
0.961
DC
ML
28
19
RO
0. 59
1.05
0.965
DC
SN
28
29
RO
1.84
1.39
0.970
DC
SN
28
31
1.09
1.19
0,972
DC
SN
28
36
1.29
1.10
0. 974
DC
SN
28
45
RO
0. 57
2.94
0.980
DC
SN
28
49
RO
1.46
0.33
0.982
DC
SN
29
07
1.33
2.24
0.992
29
16
1.22
703.66 386.18 317.48
0.997
13C12-HXCDD 478
SOR4
29
21
1.21
800.63 437.98 362.65
1.000
13C12-HXCDD 678
IS5
29
39
1.25
926.56 514.08 412.48
1.010
13C12-HXCDD 789
RS2
DC
SN
29
52
RO
2.25
4.26
1.018
DC
SN
30
01
RO
0.83
1.88
1.023
DC
SN
30
06
RO
0. 68
3.18
1. 026
3
Peaks
2.430.85
Ahove: HxCOD / HpCDF Follows
HpCDF
0.88-1.20
0.995-
.044
408-410
DC
NL
0:00
RO
1.24
1.94
0.000
DC
SN
31:16
RO
2.66
4.86
0.998
DC
SN
31:30
RO
3.69
0.80
1.006
DC
SN
32:16
RO
4.70
0.75
1.030
408-410
0
Peaks
0.00
13C12-HpCDF
418-420
413-420
0.
37-0.51
0.!
936-1.128
DC
NL
0:00
RO
1.97
1.28
0.000
31:19
0.42
639.61
188.22
451.39
1.000
13C12-HpCDF
678
IS6
DC
SN
31:31
RO
0. 33
3.14
1,006
DC
SN
32:09
RO
1.35
1.44
1.027
DC
SN
32:19
RO
1.00
0.75
1.032
DC
SN
32:24
SO
1.45
0.95
1.035
32:30
0.40
372,53
106.28
266.25
1.038
13C12-HpCDF
789
S0R5
2
Peaks
1,012.14
Above: HpCDF / HpCDD Follows
Triangle Laboratories, Inc.® Analytical Services Division
801 Capita la Drive * Durham, North Carolina 27713 Printed: 16:29 09/08/97
Phone: (919) 544-5729 • Fax: (919) 544-5491 _ 0 -
2U<-
-------
Page No. 6
09/03/97
Listing of S975669B.dbf
Matched GC Peaks / Ratio i Ret. Time
Compound/
QC.Log
Omit
Why
. .?,T.
OK
Ratio Total
Area...
Area.Peak. 1. . Area.Peak. 2. . Rel.RT C erttpound. Name. . ID.
HpCDD
0
88-1.20
0.977-1.006
424-426
DC
ML
0:00
RO
0.21
0.27
0.000
K
31:35
RO
1.76
6.22
5.36 3.05 0.982
DC
SN
31:40
RO
0.65
0.73
0.985
DC
SN
31:47
RO
0.S5
1.31
0.939
DC
SN
31:59
RO
0. 18
0.41
0. 995
DC
SN
32: 10
RO
- 1 . 46
4.77
1.001 1234678-HpCDD AN
424-426
1
Peak
6.22
13C12-HpCDD
0
88-1.20
0.969-1.031
436-433
DC
NL
0:00
RO
0.67
1.65
0.000
32: 09
1. 03
609.07
309.24 299.83 1.000 13C12-HpCDD 678 IS7
436-433
DC SN 32
38 RO 0.71
1 Peak
1.77
609.07
1. 015
Above: HpCDD / Octa-CDD and CDF Follows
OCDF
442-444
442-444
0
76-1.02
0 . 334-1.116
DC
NL
0
00
RO
0 . 38
1.32
0.000
DC
SN
31
47
0.83
4.90
0.918
DC
SN
32
03
RO
3.65
0.98
0. 926
DC
SN
32
17
RO
1.56
1.95
0.933
DC
SN
33
30
RO
1.97
1.66
0.963
DC
SN
33
35
RO
0.40
2.44
0.970
DC
SN
34
04
RO
1 .71
0.79
0. 984
DC
SN
34
26
RO
2.93
1.66
0. 995
DC
SN
34
34
RO
1. 60
1.78
0.999
DC
SN
35
47
0. 87
0.97
1.034
DC
SN
35
59
RO
0. 37
1.34
1.039
0
Peaks
0.00
CCDD
4S8-460
458-460
DC NL
DC
DC
SN
SN
0.7S-1.02
0.384-1.116
0:00
RO
3. 36
0.21
0.000
34:38
RO
1.28
4,82
3.26
2.55 1.000
34:43
RO
1.91
0.64
1 . 005
35:13
RO
1.51
2.70
1 . 017
Peak
4.32
AN
13C12-OCDD
470-472
470-472
0.76-1.02
DC NL 0:00 RO 1.09 0.21
34:37 0.96 519.12
1 Peak 519.12
254.22
0. 996-1.006
0.000
264.90 1.000 13C12-OCDD
XS3
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive ~ Durham, North Carolina 27713 Printed: 16:29 09/08/97
Phone: (919) 544-5729 ~ Fax: (919) 544-5491 2 0 3' ~
-------
Page No. 7 Listing of S9?5669B.db£
09/08/97 Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.X.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
Column Description.
"Why" Code Description QC Log Desc.
M_Z -Nominal Ion Hassles)
..RT. -Retention Time (nxn:ss)
Rae.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
File:S975669 »1-867 Acq: 5-SEP-97 08:10:18 EI+ Voltage SIR 70S Noise: 84
303,9016 F:2 B$UB(256,30, -3.0) PKD{ 9 , 5 ,5 ,0.05%, 336.0 , 1.00%, F,T) Exp-.EPCUS
TRIANGLE LABS TextiFBl TLIM42930A INJ. TIME = 08:
100S, A1.S6E5
18:00 19:00
File:S975669 #1-867 Acq:S-SEP-97 08:10
305.8987 F:2 BSU3(256,30,-3.0) PKD(9,5
TRIANGLE LABS Text:FBI TLI*42930A
ioo:
18:00 19:00
File:S975669 #1-867 Acq:5-SEP-97 08:10
315.9419 F:2 BSUB(256,30,-3.0) PKD(9,S
TRIANGLE LABS Text:FBI TLI442930A
ioo:
80A
601
2.3E4
A5.93E4 A8.20E4
1.8E4
A6.17E4
1.4E4
9.1E3
A3.39E4
A3.26E4
A1.06E4
4.6E3
A7.50E3
O.OEO
20:00 21:00
18 EI+ Voltage SIR 70S Noise: 71
5,0.05%,284.0,1.00%,F,T) Exp:EPCUS
INJ. TIME = 08:
A1.31E5
22: 00
23 : 00
12
A1 . 53 E5
A1.OSES
A5.81E',
A4 .64E4
A6.64E4
A
A1. 74E4
20:00 21:00
18 EI+ Voltage SIR 70S Noise: 70
5, 0 . 05%, 280 .0,1. 00%, F, T) Exp-.EPCUS
INJ. TIME = 08:
A4.92E6
3.7E4
L.2.2E4
1.5E4
7.4E3
22:00
23:00
OEO
Time
12
40q
20J
18:00 19:00
File:S975669 #1-867 Acq:5-SEP-97 08:10:
317.9389 F:2 BSUB(256,30, -3 . 0) PKD(9,5,
TRIANGLE LABS TextiFBl TLH42930A
100%
80.
60,
40:
20.
20:00 21": 00
18 EI+ Voltage SIR 70S Noise: 74
5, 0.05%, 296. 0,1. 00%, F,T) Exp:EPCCS
INJ. TIKE = 08
A6.46E6
22:00
: 12
-1.2E6
.9. 9E5
.7.5E5
'.S.OES
'-2.5E5
| .O.OEO
23': 00 Time
1.7E6
1.3E6
1.0E6
6.7ES
3.4ES
O.OEO
18:00 19:00
File:S97S669 *1-867 Acq:5-SEP-97 08:10
330.9792 F:2 Exp-.EPCUS
TRIANGLE LABS Text:FBI TLI04293OA
ioo:
20:00 21:00
18 EI+ Voltage SIR 70S
22:00
23:00
Time
INJ. TIME = 08:
22:31
9.1E6
16 19:40
7.2E6
5.4E6
3.6E6
1.8E6
O.OEO
18:00 19:00
File:S975669 #1-867 Acq:5-SEP-97 08:10
375.8364 F:2 Exp-.EPCUS
TRIANGLE LABS Text:FBI TLI442930A
100.
20:00 21:00
18 EI+ Voltage SIR 70S
INJ. TIME
22:00
23:00
22:00
1.3E4
1.0E4
18:22
7.SE3
22:31
5.0E3
19:04
20:10
21:06
2.5E3
20:30.
O.OEO
18:00
19:00
20:00
21:00
22:00
23:00
205
-------
File:S975669 #1-867 Acq:5-SEP-97 03:10:13 EI+ Voltage SIS 70S Noise:55
319.8965 F:2 BSUB(256,30,-3.0) PKD( 7, 5, 3, 0. 05%, 220. 0,1.00%,F,T) Exp:EPCUS
TRIANGLE LABS Text::FBI TLT#42930A IJKT. TIME = 08:12
100% A1.38E4
-------
File:S975669 *1-867 Acq:5-SEP-97 03:10
339.8597 F:2 BSUB(256,30, -3.0) PKD(7,5
TRIANGLE LABS Text::Ml TLI04293OA
100% A2.82E4
23:00 24:00
File:S975669 #1-867 Acq:5-SEP-97 08:10
341.S567 F:2 BSUB(256,30, -3.0) PKO(7,5
TRIANGLE LABS Text:FBI TLI#42930A
100% A1.45E4
A3.00E4
80.
23:00 24:00
File: S975669 §1-867 Acq:5-SEF-97 08:10;
351.9000 F-.2 BSUB(256,30,-3.0) PKD(7,5,
TRIANGLE LABS Text:FBI TLIH42930A
100%
80j
i
603
18 EI* Voltage SIS 70S Noise: 66
3,0 .05%, 264 .0,1. 00%, F, T) Exp:EPCVS
INJ. TIME - 08:12
A1.39E4
A1.06E4
A1.21E4
A8.46E3
A2
81E3
A4.13E3
A1.01E4
25:00 26:00
18 EI* Voltage SIR 70S Noise:66
3, 0.05%, 264 . 0,1. 00%, F, T) Exp : EPCUS
IN J. TIME = 08:12
27:00
A1.13E4
A1.74E4 A1.57E4
+A8.06E3
A1.09E4
A9.0
1.43
4,92B3
AF.37E3
25:00 26:00
18 EI* Voltage SIR 70S Noise:63
3,0. 05%, 252.0,1. 00%, F, T) Exp: EPCUS
INJ. TIME = 08:12
A5.51E6
A4.60E6
27:00
403
20J
_1_
23: 00 24 : 00
File:S975669 #1-867 Acq:5-SEP-97 08:10
353.8970 F:2 BStJB( 256, 30, -3 . 0 ) PKD(7,5.
TRIANGLE LABS Text:FBI TLI#42930A
1001
803
603
403
203
25:00 26:00
18 EI* Voltage SIR JOS Noise: 62
3, 0.05%, 248. 0,1. 00%, F,T) Exp-.EPCUS
INJ". TIME = 08:12
A3.35E6
A2.63E6
27:00
23:00 24:00
File:S975669 #1-867 Acq:5-SEP-97 08:10
330.9792 F:2 Exp: EPCUS
TRIANGLE LABS Text:FBI TLI04293OA
100:
Jx
25:00
18 EI* Voltage SIR 70S
26: 00
27:00
1E6
1E5
8E5
6E5
. 3E5
¦ OEO
Time
INJ. TIME
25:22
08:12
26:16
23:00 24': 00
File:S975669 01-867 Acq:5-SEP-97 08:10
409.7974 F:2 Exp: EPCUS
TRIANGLE LABS Text:FBI TLI04293OA
ioo:
25:00
18 EI* Voltage SIS 70S
26:00
27:00
INJ. TIME = 08:12
24:12
23:41
26:26
23:21
27:00
23:59
Time
23:00
24 : 00
25:00
26: 00
27:00
207
-------
Fxle:S9/5669 01-667 Acq:5-SEP-97 08:10:13 EI* Voltage SIS 70S Noise: 71
355.8546 F-.2 BSUB(256,30, -3.0) PKD( 7 , 5 , 3, 0. 05\, 284 .0 , 1. 00\,F, T) Exp-.EPCUS
TRIANGLE LABS Text:FBI TLI04293OA IHJ. TIME - 08:12
A6.99E3
A8.34E3
25:00 26:00
File:S975669 §1-867 Acq:5-SEP-97 08:10:18 EH- Voltage SIS 70S Noise: 64
357.8516 F:2 BSUBf256, 30, -3.0) PKD( 7, 5, 3, 0.05%,256. 0,1. 00%, F, T) Exp-.EPCUS
TRIANGLE LABS
lOOi A5.03E4
so:
601
40.
1001
A1.16
A2. 01E4
A1.43E4
A5.56E3
h/h.jyV
A7.38E3
A1.34E4
A8.14E3 *5.65E3
A8.67E3
27:00
. OEO
Time
Text: FBI TLI#42930A
IN J. TIME
08:12
A1.96E4
Ix
\Ljl
A1.28E4
A1.20E4
A5. 74E3
A1.05E4
h11"k L.. LajJ
25:00 26:00
File:S975669 #1-867 Acq:5-SEP-97 08:10:18 EI* Voltage SIX 70S Noise-.64
367.8949 F:2 BSXJB(256, 30,-3. 0 ) PKD( 7, 5,3,0. 05%,256. 0, 1. 00%,F, T) Exp:EPCUS
TRIANGLE LABS Tex tiFBl TLI§42930A IN J. TIME = 08:12
100$ A2.$3E6
80.
60.
40.
20.
d—, , , , , , , , , , L
A3.02E3 A4.61E3
i .A A*j —l\jy^AJ
i.
i.
7.
13.
0.
3.97E5
27:00
25:00 26:00
File:S975669 #1-857 Acq: 5-SEP-97 08:10:18 EI* Voltage SIS 70S Noise: 64
369.8919 F: 2 BSUB (256, 30,-3 . 0 > PKD(7, 5,3,0 .05%, 256.0,1. 00%,F,T) Exp:EPCUS
TSIANGLE LABS Texts FBI TLH42930A INS. TIME = 08:12
27:00
10 Oi
80.
60.
40:
20.
0.
A1.97E6
1.95E5
25:00 26:00
File:S975669 *1-867 Acq:5-SEP-97 08:10:18 EI* Voltage SIS 70S
330.9792 F:2 Exp-.EPCUS
TRIANGLE LABS Text:FBI TLI*42930A INS. TIME
1003> 25} 22
80:
60.
40.
20.
0.
27:00
08:12
26:16
24:17
24:54 25
24:28
25:00
26: 00
27:00
8E4
5E4
1E4
3E3
7E3
OEO
Time
0E6
OES
0E5
OES
OES
¦ OEO
Time
9E5
5E5
1E5
8E5
4E5
OEO
Tiae
5E7
2E7
7E6
8E6
9E6
OEO
Tiae
208
-------
File :S975669 *1-425 Acq: S-SEP-97 08:10:18 EI* Voltage SIS 70S Noise: 354
373.8208 F: 3 BSUB(256,30,-3.0) PKD( 7, 5 , 3 , 0. 05%, 1416. 0 , 1.00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:FBI TLI04293OA INJ. TIME = 08:12
100%
80.
60.
tim "PTf r»f f 1'vr " 'i ¦ i * ¦> V i i"i n . i T"i "i""i i r i" i i»i r i i n"i i'e i •pi f i '"r'l i'"i i r i « i r i1 i v i' i | <"i i i "I "
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
File: S975669 #1-42 5 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S Noise: 948
383.8639 F:3 BSUB( 256,30, -3 . 0 ) PKD(7, 5,3 , 0.05%, 3 792. 0,1.00%, F, T) Exp:EPCUS
40.
20.
Q.
A2.32E4
A1.06E4 h A71.B7E3
A1.16E4
A2. 72E4
A1.17E4 A7.69E3
j A A8.14E3 AS.37E3
7.1E4
5. 7E4
4.3E4
2.8E4
24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
S975669 #1-425 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S Noise:45
375.8178 F:3 BSUB(2S6,30, -3.0) PKD{7, 5, 3 , 0. 05%, 180 . 0, 1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:FBI TLI#42930A INJ. TIME = 08:12
Time
100S
80l
60l
401
20.
o-
.1. 9E5
11.5E5
11.2E5
.7. 7E4
13. 9E4
. 0E0
Time
TRIANGLE LABS
100%
i
80,
Text: FBI TLI#42930A
INJ, TIME
08:12
7E6
60.
i
40J
20.
T f T-'T"! 1 t I > I 1 I I
27:24 27:36 27:48
X
A3.12E6
A2.49E6
T
rr
.1. 3ES
'.1. 0E6
.7.7E5
•-5.2E5
-2.6E5
.0.0E0
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 Time
File:S97S669 #1-425 Acq: 5-SEF-97 08:10:18 EI+ Voltage SIR 70S Noise: 886
385.8610 F: 3 BSUB( 256,30, -3 . 0 ) PKDf 7, 5,3, 0. 05%, 3544.0 ,1.00%, F, T) Exp:EPCUS
TRIANGLE LABS
100S
8 ft]
40J
20J
Text: FBI TLI04293OA
TTT"
INJ.
A6.22E6
TIME
08:12
93E6
f l | i i i ; i
rr
.2.5E6
'.2.0E6
11-S£S
L9.9E5
.5.0E5
10. 0E0
Time
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
File:S975669 #1-425 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S
392.9760 F: 3 Exp:EPCUS
TRIANGLE LABS Text:FBI TLI#42930A INJ. TIME « 08:12
1003, 27:56 ,, „„ _ 29:13 29^27 30:08 30:21^.7.0E6
5.6E6
4.2E6
2.8E6
1.4E6
, . . , . , , i 0 ¦0E0
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48' 29 • 00 ' 29:12' 29:24' 29:36' 29:48 30:00 ' '30:12' 30:24 Time
File:S975669 #1-425 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S
445.7555 F:3 Exp:EPCUS
TRIANGLE LABS Text:FBI TLI#42930A INJ. TIME - 08:12
100%
1.8E4
1.4E4
29:44
1.1E4
29:08
28:32
29:28
7.0E3
28:11
3.5E3
29: Q1
2F:37
0.0 EO
27:24 27:36 271-48 ' 28:bb' 28:12 28:24' 28:36' 28:48' 29:o6' 2<9:12 29:24' 29': 36 ' 28:46 ' '30:00 ' 30:24 Time
209
-------
File:£975t>6S "*1-425 Acq:5-stP-97 03:10:18 EI+ Voltage its 70s Noise: i>08
389.8156 F:3 BSUB(2S6, 30, -3.0) PKS(7, 5,3 ,0 .05%, 2032. 0,1. 00%, F, X) Zxp:EPCVS
TRIANGLE LABS Text.:FBI TLX04293OA INT. TIME = 03:12
1003,
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36
File:S975669 #1-425 Acq:5-SEP-97 08:10:18 EI* Voltage SIX 70S Noise .224
391.8127 F:3 BSUB(256,30,-3.0) PKD(7, 5 , 3 , 0.05%, 896. 0 ,1.00%,F, T) Exp:EPCVS
TRIANGLE LABS Text:FBI TLI*42930A INJ. TIME = 08:12
100% A2.46E4
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36
File:S975669 01-425 Acq:5-SEP-97 08:10:18 EI* Voltage SIS 70S Noise:290
401.8558 F: 3 BSUB<256, 30,-3.0) PKD( 7,5,3,0.05%,116 0.0,1.00%,F,T) Exp:EPCOS
TRIANGLE LABS Text:FBI TLH42930A XK7. TIME = 08:12
100& A5.14E6
A3.58E4
1.5E4
1.2E4
A2.32E4
9.1E3
Al.43E4
A1.15E4
Al.89E4
6.1E3
A3.60E3
2.64E3
3.0E3
O.OEO
29:48 30:00
80.
60.
40.
20.
0.
A3.15E4
A1.25E4
A4 . 06E3
2.93
~r
~r
X
A6.98E3
1..13E4 A1.87E3
AAt
Al. 49E4
A1.32E4
154EJ A9.14E3
~r
-r
29:48
30:00
80.
60.
40.
20.
A4 .38E6
I i '
28:00
< '1
28:12
l t f ¦, »—r-r"
28:24 28:36 28:40 29:00 29:12 29:24 29:36
File;S97S669 §1-425 Acq:5-SEP-97 08:10:18 EI* Voltage SIS 70S Noise: 448
403.8529 F:3 BSUB(256,30,-3. 0) PKD( 7, 5, 3, 0.05%, 1792. 0,1.00%,F,T) Exp:EPCOS
TRIANGLE LABS Text:FBI TLIH42930A INJ. TIME = 08:12
100%
29:48
30:00
80.
60.
40.
20.
0.
A3.17E6
' "l j I I ! 1 I I—T I
28:48 29:00
) i ""["" l ' II l1 'I i i 1 f ¦! 'I I "'I 111;—i i i—i—i T*"|—i—i1' "i i—r'I
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24
File:S975669 #1-425 Acq:5-SEP-97 08:10:18 EI* Voltage SIR 70S
392.9760 F:3 ExpzEPCUS
TRIANGLE LABS Text:FBI TL2*42930A INJ. TIME
29:36
r •¦»¦"'¦•
29:48
08:12
100S
so:
60.
40.
20.
29:13
29:27
29:48
30:00
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36
' ' | 1 ' 1 1 ' ) 1 1
29:48 30:00
I. 6E4
.1.2E4
.9. 4E3
.6.2E3
.3. 1E3
.O.OEO
Time
.1.9E6
.1. 5E6
.1.1E6
.7.6E5
.3.8ES
.O.OEO
Time
.1. 5E6
.1.2E6
.9.2E5
.6.1E5
.3.1E5
.O.OEO
Time
.7.0E6
.5.6E6
14.2E6
12.8E6
II. 4E6
10.0E0
Time
210
-------
File:S975669 #1-390 Acq:5-SEP-97 08:10:18 EI+ Voltage SIX 70S Noise:589
407. 7818 F:4 BSOB( 256, 30, -3 .0) PKD(7, 5,3, 0. 05%, 2356.0,1.00%, F, T) Exp;EPCUS
TRIANGLE LABS Text-.FBI TLI#42930A IN J". TIME = 08:12
lOOi A6.32E4
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
File: S975669 §1-390 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S Noise: 4 77
409.7789 F: 4 BSUB(256, 30, -3. 0) PKD( 7, 5,3, 0. 05%, 1908. 0,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:FBI TLI»42930A INJ. TIME = 08:12
100% A1.45E4
A2. 38E4
80J
2.0E4
1.6E4
1.2E4
7.8E3
A1.44E4
A1. 74E4
A1.20E4
3.9E3
32:48
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
File:S975669 §1-390 Acq: 5-SEP-97 08:10:18 EI+ Voltage SIR 70S Noise: 874
417.8253 F:4 BSVB( 256, 30,-3.0) PKD(7, 5,3,0.05%, 3496.0,1.00%, F, T) Exp:EPCUS
TRIANGLE LABS Text: FBI TLI#42930A INJ. TIME = 08:12
1003
80J
60.
40.
20.
32:48
A1.06E6
31:12 31:24 31:36 31:48 32:00 32:12 32:24
File:S9 75669 §1-390 Acq: 5-SEP-97 08:10:18 EI+ Voltage SIR 70S Noise: 447
419.8220 F:4 BSUB( 256 , 30 ,-3 . 0 ) PKD ( 7, 5, 3, 0 . 05%, 1788. 0 ,1. 00%, F, T) Exp-.EPCUS
TRIANGLE LABS Text: FBI TLI»42930A INJ. TIME = 08:12
32:36
32:48
1004
80j
601
40J
•2oJ
A4.
A2.66E6
_
32:24
31:12 31:24 31:36 31:48 32:00 32:12
File:S975669 §1-390 Acq:S-SEP-97 08:10:18 EI+ Voltage SIR 70S
430.9729 F:4 Exp-.EPCUS
TRIANGLE LABS Text:FBI TLI«42930A INJ". TIME
1°0% ,, ;S5 33JtS2 32:09
32:36
32:48
.O.OEO
33:00 Time
9.6E3
7. 7E3
A1.14E4
5.8E3
A2.95E3
A1.28E4
3.8E3
A7.27E3
1.9E3
Al\70E
O.OEO
33:00 Time
.7.5E5
.6.0E5
.4.5E5
L3. 0E5
.1. 5E5
_O.OEO
33:00 Time
.1.8E6
'.1. 5E6
LI. 1E6
.7.3E5
:3.6E5
^ .0.0E0
33 : 00 Time
08:12
5.0E6
32:36
32:26
31:45
31:33
4.0E6
3.0E6
2.0E6
9.9E5
31:12 31:24 31:36 31:48 32:00 32:12
File: S975669 #1-390 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S
479.7165 F:4 Exp:EPCUS
TRIANGLE LABS Text:FBI TLIS42930A INJ.
1003,
32:24
TIME
32:36
08:12
32:48
.O.OEO
33:00 Time
1.3E4
1.1E4
32:46
8.0E3
31:13
31: 54
32:11
5.3E3
2.7E3
31:12
31:24
31:36
31:48
32:00
32:12
32:24
32:36
32:48
:o.oeo
33:00 Time
211
-------
File:S9/4669 41-330 Acq:5-SEP-§7 OS: 10: IB EI* Voltage SiR 70s Noiae: SB
423.7766 F:4 BSOB(256,30,-3.0) PKD(7, 5,3,0.05%, 2 72.0,1.00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:FBI TLI442930A IKT. TIME - 08i 12
100% A5.J6E4
31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18
File: S975669 §1-390 Acq: 5-SEP-97 08:10:18 EI* Voltage SIS 70S Noise: 341
425.7737 F:4 BSUB(256, 30,-3. 0) PKD(7, 5,3,0.05%, 1364. 0 ,1. 00%, F,T) Exp:EPCVS
TRIANGLE LABS Text:FBI TLI442930A INT. TIME = 08:12
1003) A3.Q5E4
1.5E4
A3.41E4
1.2E4
8. 7E3
5.8E3
A1.99E4
3.67E3 A6-f9f
2.9E3
A3.90E3
O.OEO
32:24 32:30 32:36
1.4E4
A1. 72E4
1.2E4
8.7E3
A2.29E4
5.8E3
2.9E3
A4 . 73E3
0. OEO
31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18
File:S975669 *1-390 Acq:S-SEP-97 08:10:18 EI* Voltage SIR 70S Noise: 418
435.8169 F:4 BSUB( 256, 30, -3 .0 ) FKD(7 , 5 , 3 , 0.05%, 1672.0,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:FBI TLI04293OA INT. TIME = 08:12
100%
802
6CJ
40J
20J
32:24 32:30 32:36
¦ i I ' i
31:30
31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18
File:S975669 01-390 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S Noise: 632
437.8140 F:4 BSUB(256, 30, -3.0 ) PKD(7, 5,3, 0. 05%,2528. 0,1. 00%,F, T) Exp:EPCUS
TRIANGLE LABS Text:FBI TLI442930A IKJ. TIME = 08:12
100%
80.
32:24 32:30 32:36
60.
40.
20.
' ' ' 1 l ' 1
31:30
i i ] i i t i i | i f
31:36 31:42 31:48 31:54 32:00 32:06 32:12
File:S975669 #1-390 Acq:5-SEP-97 08:10:18 EI* Voltage SIR 70S
430.9729 F:4 Exp:EPCHS
TRIANGLE LABS Text:FBI TLI#42930A INT. TIME «
100% 32:02 ,,
31:33 31:45 31:55 3iL09 . 32:15
80.
60.
40.
20.
0.
08:12
32:36
32:26
32:18 32:24 32:30 32:36
3lHo3nJI^~7inj^~7ll4F~r^3l7sP~l2ToT^~727oI^~72nJ~r^327IT^~l2n4^32r3o'
'32:36
.1.2E6
.1. 0E6
.7.5E5
.5. 0E5
.2.5E5
.O.OEO
Time
.1.2E6
.9.5E5
.7.1E5
.4. 8E5
.2.4E5
.O.OEO
Time
5.0E6
4.0E6
3.0E6
2.0E6
9.9E5
O.OEO
Time
2:
-------
File:S975669 *1-390 Acq:5-SEP-97 08:10:18 EI* Voltage SIR 70S Noises 311
441.7428 F:4 BSUB(256,30, -3.0) PKD(7, 5,3,0.05%, 1244 .0,1. 00%, F, T) Exp:EPCVS
TRIANGLE LABS Text: FBI TLIH42930A INJ". TIME = 08:12
lOOi
A1.16
A2.32E4
A1.90E4
J A1.61E4
2.4E4
2.1E4
1.9E4
1.6E4
1.4E4
1.2E4
Al.S0E4
9.4E3
. 41E4
7.1E3
A1.34
4.7E3
2.4E3
O.OEO
32:00 • 33:00 34:00
File:S975669 $1-390 Acq:5-SEP-97 08:10:18 EI* Voltage SIR 70S Noise: 814
443.7399 F:4 BSOB(256, 30, -3.0 ) PKD( 7,5,3,0.05%, 3256.0,1. 00%, F, T) Exp: EPCCS
TRIANGLE LABS Text:FBI TLI*4293QA
1003, A2.63E4
INJ. TIME
08:12
1.9E4
1.7E4
A2. 73E4
1.SE4
1.3E4
A2. 88E4
1.1E4
9.4E3
A2.1SE4
1.40E4
A1.03E4
7.SE3
Al.99E
AS.17E3
S.6E3
A4.21E
A5.01E3
3.8E3
1.9E3
O.OEO
32:00 33:00
File-.5975669 *1-390 Acq:5-SEP-97 08:10:18 EI
430.9729 F:4 Exp:EPCUS
TRIANGLE LABS Text:FBI TLI#42930A
100%
34:00
Voltage SIR 70S
08:12
INJ. TIME
34:08
5.2E6
34:53
35:22
32:02
35:41
4.SES
31: 45
4.1E6
3.6E6
3.1E6
2.6E6
2.1E6
1.SE6
1.0E6
5.2E5
O.OEO
32:00 33:00 34:00
File: S975669 #1-390 Acq: 5-SEP-97 08:10:18 EI* Voltage SIS 70S
513.6775 F:4 Exp:EPCOS
TRIANGLE LABS Text:FBI TLI04293OA INJ.
TIME
08:12
lOOi
901
801
70.
601
50.
40.
301
201
10.
0.
33:02
31:43
31:16
"f09 W
^ luAlV
32:00
1.9E4
1.7E4
1.5E4
1.3E4
1.1E4
9.3E3
35:17
7.4E3
35:49
33:55
5.6E3
34:50
3.7E3
33133
1.9E3
O.OEO
32:42
33:00
34 : 00
213
-------
F£le:S975SS9 *1-390 Acq:5-SEP-97 08.-lg.-ia £1* Voltage sX R 70s Noise: 459
457.7377 F:4 BSOB(256, 30, -3.0) PKD( 7, S, 3, 0 . 05%, 1836. 0, 1. 00%, F,T) ExpzEPCUS
TRIANGLE LABS Text:FBI TLI*42930A XKT. TIME » 08:12
100A A5-17E4
2.0E4
1.6E4
1.2E4
7.9E3
A1.59E4
AX. 39E4
4.0E3
A6.49E3
0.0E0
34:30 34:36 34:42 34:48 34:54 35:00
File:S975669 #1-390 Acq:5-SEP-97 08:10:18 EI* Voltags SIR 70S Noise:54
459. 7348 F-.4 BSUB(256, 30, -3.0) PKD( 7, 5,3 , 0. 05%, 216.0,1.00%, F, T) Exp:EFCUS
TRIANGLE LASS Text: FBI TLI#42930A IN J. TIME » 08:12
100S A3.98E4
35:00
34:30 34:36 34:42 34:48 34:54
File:S975669 *1-390 Acq:5-SEP-97 08:10:18 EI* Voltage SIS 70S Noise: 61
469.7779 F:4 BSUB(256,30, -3.0) PKD(7, 5,3, 0.05%,244. 0,1. 00%,F, T) Exp:EPCUS
TRIANGLE LABS Text:FBI TZI*42930A IJKJ, TIME = 08:12
100%
801
35:00
i "I- 'i—i m i |—i—i—i i i i i T I i i t" 111 i i i i ¦' i i
34:30 34:36 34:42 34:48 34:54
File:S97S669 01-390 Acq:5-SEP-97 08:10:18 EI* Voltage SIR 70S Noise: 55
471.7750 T: 4 BSUB( 256, 30,-3 . 0 ) PKD(7, 5,3,0.05%, 220 .0,1.00%, F,T) Exp:EPCUS
TRIANGLE LABS Text:FBI TLI*42930A IJKT. TIME = 08:12
100%
80-
60.
401
201
601
40:
201
<—"i—' ¦"< ¦ —'—I—>—1—I—I—I—I ~ I—I—I I I—I—1—f
34:30 34:36 34:42 34:48 34:54
File:S975669 §1-390 Acq:5-SEP-97 08:10:18 EI* Voltage SIR 70S
430.9729 F:4 EipsEPCOS
TRIANGLE LABS
100S
80.
60.
40.
20.
Text:FBI
34:34
TLI#42930A
34:41
IN J. TIME -
34±53 34:56
35:00
08:12
35:06
1.4E4
1.1E4
8.4E3
15.6E3
A3.37E3
AS.15E3
2.8E3
10.0E0
35:06
7. 7E5
6.1E5
4.6E5
3.1E5
11.5E5
35:06
L 0.0E0
Time
-8.6E5
.6.9E5
15.2E5
13.4E5
.1. 7E5
35:06
.0.0E0
rime
35:04
S.1E6
14.0E6
3.0E6
2.0E6
1.0E6
34:30
34:36
34:42
34:48
34:54
35:00
35: 06
.O.OEO
Time
214
-------
Chanel I 338.9732 Peak top
Height 3.25 volts Spa 288 ppt
___ _
Data flit na* fi=338537i
Resolution 16888
Group nwber 2
Ionization aode EI*
Switching VOLTRGE
Ref, lasses 232.3885, 418.9768
fl 233 J 331 S 388
K 332 T 378
L 334 U 376
I 348 V 418
N 342
0 352
? 354
9 358
I 331 R 358
Ref.iasi 418,3788 P^c top
|L2 jikl iuti L m Cfmrntt dflfi ma
nsupit i% votes spsn off ppi
D 318
E 318
f 328
-------
File:S975669 #1-867 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S " ~
303.9016 F:2 Exp:EPCUS
Sample Text:FBI TLI#42930A INJ. TIME = 08:12 File Text
100%, 18:28
:FBI TLI#4293»
2 . 3E4
17 : 17
1. 9E4
19:35
" 1.4E4
9.3E3
21:05
17 :50
23 : 52
23 :35
24 :41
22 : 37
21; 59 I I
4 . 7E3
80 j
60
40
20-| 16:37
u ' ¦ ¦ i i—i—j 1—»—i 1—i—j——r^—i 1—t—j—n—i—i—i 1—j 1—i—i—i 1 1 1 1 1 1 1 1 i 1—i 1—i—|—i 1 1 1—i 1 r
17:00 18:00 19:00 20:00 21:00 22:00 23:00 24:00
File:S975669 #1-867 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S
305.8987 F:2 Exp:EPCUS
Sample Text:FBI TLI#42930A INJ. TIME = 08:12 File Text
100% 20,47
T 1 1 1-
0 . 0E0
2 5:00 Time
FBI TLI#4293»
_3.7E4
3 . 0E4
18 :29
2 . 2E4
19:13
^1.5E4
17 :19
1: 2521:58
3:13
l7.5E3
24 : 0
17:00 18:00 19:00 20:00 21:00 22:00 23:00 24:00
File:S975669 #1-867 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S
315.9419 F:2 Exp:EPCUS
Sample Text:FBI TLI#42930A INJ. TIME = 08:12 File Text:
100% 20,44
80 j
60 J
40J
20j
0
.r . 0 . PRO
2 5:00 Time
FBI TLI#4293»
1 . 2E6
l9.9E5
17.5E5
L5.0E5
2 . 5E5
t—i—i—i—i—|—i—i—i—i—i—|—i—i—i—i—i—|—i—i—i—i—i—|—i—t—i—"i—t3—|—i1" i • i—i i |—r—i—i—i—i—|—i—i—r-
17:00 18:00 19:00 20:00 21:00 22:00 23:00 24:00
.0 . 0E0
2 5:00 Time
ro
» H*
-------
File: S975669 #1-867 Acq:5-SEP-97 08:10:18 EI+ Voltage SIRTOST
303.9016 F:2 Exp:EPCUS
Sample Text:FBI TLI#4293 0A INJ. TIME
100% ^
A9 .20E4>
08:12 File Text:FBI
VwWN /V
TV\Aa A
TLI#4293»
2 ,3E4
17 00 18:00 19:00
File:S975669 #1-867 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S
305.8987 F:2 Exp:EPCUS
Sample Text;FBI TLI#42930A INJ. TIME =
11.9E4
"1.4E4
9.3E3
4 . 7E3
08:12 File Text:FBI
100%
80i
60i
40i
20 J
0:
17
00
0.0E0
20:00 Time
TLI#4293»
_3.7E4
;.3 . 0E4
"2 . 2E4
09E4
18:00
315.9419 F:2 Exp:EPCUS
Sample Text:FBI TLI#42930A
100%
80.:
60i
40i
20j
19 :00
INJ. TIME
08:12 File Text:FBI
10.0E0
20:00 Time
TLI#4293»
1.2E6
_9.9E5
l7.5E5
5. 0E5
9 K pc
# v l. l
0.
17 :00
18:00
19 :00
.0 . 0E0
20:00 Time
• 12
-------
File:S975669 #1-867 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S
303.9016 F:2 Exp:EPCUS
Sample Text:FBI TLI#42930A
100%
INJ, TIME
08:12 File Text:FBI TLI#4293»
2 . 3E4
1.9E4
1.4E4
9.3E3
4.7E3
0 QEO
....... ," | i t—i i t ttti—r~T I i i i—i | i—i i i i | i i j i i | -n—i—rnr~j—i—i—i—i i r~i—i—t—i—i i f t rinr-i—i—nn—i | i i i i i—i—r~?—i—i—?—p4™ *
17:36 17:48 18:00 18:12 18:24 18:36 18:48 19:00 19:12 19:24 19:36 19:48 20:00 20:12 Time
File:S975669 #1-867 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S
305.8987 F:2 Exp:EPCUS
Sample Text:FBI TLI#42 930A
100%
80j
60 J
40i
20
0.
INJ. TIME = 08:12 File Text:FBI TLI#4293»
2.6E4
2 . 0E4
111. 5E4
1.0E4
5 . 1E3
Lo.oeo
i r i i i i—ill i t—i—i i i—j—i—i—r—i—i—j—j—i ii—i | i—i t i i |—i—i—i i i i i i i—i—i—i—i—i—i—i—i—i—i—i—i—i—i—j—r—i—i—i" i »—r~i—r i i 1—i—i i i—i—i—n—i—r
17:36 17:48 18:00 18:12 18:24 18:36 18:48 19:00 19:12 19:24 19:36 19:48 20:00 20il2 Time
File:S97 5669 #1-867 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S
315.9419 F:2 Exp:EPCUS
Sample Text:FBI TLI#42930A INJ. TIME = 08:12 File Text:FBI TLI#4293»
100% 18 04 _6.6E3
5.3E3
19:35
19:53 20:07
L4.0E3
18 : 59
18:21
17 :49
1.2 . 7E3
19 :27
1.3E3
i i—r r | • "i—i i i—1—1-
0.0E0
17:36 17:48 18:00 18:12 18:24 18:36 18:48 19:00 19:12 19:24 19:36 19:48 20:00 20:12 Time
ro
/VI
-------
File:S975669 #1-867 Acq:5-SEP~97 08:10:18 EI+ Voltage SIR 70S
303.9016 F:2 Exp:EPCUS
Sample Text:FBI TLI#42930A INJ. TIME =
100% . c^7.05E4)
08:12 File Text:FBI
19:00 20:00 21:00 22:00
File:S975669 #1-867 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S
305.8987 F:2 Exp:EPCUS
Sample Text: FBI TLI#42930A _ INJ. TIME = 08:12 File Text: FBI
100%.
00 20:00 21:00 22:00
File:S975669 #1-867 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S
315.9419 F:2 Exp:EPCUS
Sample Text:FBI TLI#42930A INJ. TIME = 08:12 File Text:FBI
100% 20 44
80
60 j
40
20J
TLI# 4 2 9 3 »
1.9E4
1.2E4
7 . 8E3
i3.9E3
L0.0E0
Time
TLI#4293»
3 . 7E4
2 .2E4
-1.5E4
0.
T
~i r—m 1 r-
.0.0E0
Time
TLI#4293»
1.2E6
.9. 9E5
.7 . 5E5
.5 . 0E5
t_2 , 5E5
19:00
ro
20:00
21:00
(n
22 : 00
0.0E0
Time
CO
-------
File:S975669 #1-867 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S
319.8965 F:2 Exp:EPCUS
Sample Text:FBI TLI#42930A INJ. TIME
10 Oil
80
60
40j
20i
0
16:47
18:05
:WuIJIUUa
17 :26
JllJuiuui/
18 :42
19
:4?
0
MA, iftJ
UJ
12
21:31
20 : 57
22 :42
1 1 1 I ! 1 1 1 1— t—j 1 1 1—T"
-i—i—j—i—i—r—t—t—i—r
r
"i—p—i—I—r—r
08:12 File Text:FBI TLI#4293»
.1, 1E4
24:09 , 7e3
.6.5E3
.4 . 3E3
.2 . 2E3
0 . 0E0
23 :38
2:09
I
17:00 18:00 19:00 20:00 21:00 22:00 23:00 24:00 25:00 Time
File:S975669 #1-867 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S
321.8936 F:2 Exp:EPCUS
Sample Text:FBI TLI#42930A INJ. TIME = 08:12 File Text:FBI TLI#4293» s , ,
100%. 24 58 (,Hpl.4E4 I
20:19
21:53
19 :28
16:26
20:59
7:12
18:42
18:07
22:38
23 ; 15 23 : 54
n—i—n—i—i—j—i—i—i—i—i—i—r—i—»—i—j—[¦
17 : 00 18100 19 : 00 20 ! 00 ' ' '21! 00' ' "22 1 00' ' 2 3 loO^' ' 24 [ 00 * ' ' 25 ! 00^
1. 1E4
8 . 2E3
l5.5E3
l2.7E3
; 0 . 0 EO
Time
File:S975669 #1-867 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S
331.9368 F:2 Exp:EPCUS
Sample Text:FBI TLI#42930A INJ. TIME
100% 21;19
80i
60
40j
20i
0
i—i ¦ r i""t ¦ |¦ t 'i*' r¦ "T" i1 • j* ¦; "f -<—>—i—j—ti 'i"i—i—[¦
i " i • i T i' r—r* i
y
T" r-1 • i—i • t r i | i i * t—3—1—p-n—r
17:00 18:00 19:00 20:00 21:00 22:00 23:00 24:00
08:12 File Text:FBI TLI#4293»
.1. 3E6
1I.OE6
l7.8E5
l5.2E5
2 . 6E5
L0.0E0
Time
r,T,,i'nl
25:00
to
lro
-------
File: S975669 #1-867 Acq:5-SEP-97 08":10:18 EI+ Voltage SIR 70S"
339.8597 F:2 Exp:EPCUS
Sample Text:FBI TLI#42930A INJ. TIME
100% 22:53 24 04
22x21
21:34 22:12
21:07
20:44
23 :26
24:51
08:12 File Text:FBI TLI#4293»
.9 . 7E3
25:55
25:42
25:16
M
26:27 27:07
—'—1—I—r
21:00
-i 1—-j r -
' j 5
24 :00
22:00 23:00
File:S975669 #1-867 Acq:5-SEP~97 08:10:18 EI+ Voltage SIR 70S
341.8567 F;2 Exp:EPCUS
Sample Text:FBI TLI#42930A INJ. TIME
100% 23 05
- r r , 1 , , p— T—
25:00 26:00
l7:~00"
t-7 .8E3
.5.8E3
".3 . 9E3
Ll.9E3
L0.0E0
Time
08:12 File Text:FBI TLI#4293»
26:27 1.4E4
ll.1E4
l8.2E3
27 :03
22 :44
23 :40
5.5E3
24 :38
1:10
22:09
:.2 . 7E3
2UT35
0 . 0E0
23 :00
24:00
21:00
22 :00
25:00
File:S975669 #1-867 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S
3 51.9000 F:2 Exp:EPCUS
Sample Text:FBI TLI#42930A INJ. TIME =
100% 24 58
80.:
60 i
40i
20j
Oi
^ 1 J 1 1 T-—r 1 1 1 r 1 f~
26:00 27:00
Time
08:12 File Text:FBI TLI#4293»
1.8E6
25 : 42
1 1 1 1 T~
21:00
-i 1 j r-—r 1 1 — i j 1 1 1 r 1 r~—i r~
22:00 23:00 24:00
I V
i " r r*-—j i i r
25:00
L
r—r
26100
-r r I
27:00
1.4E6
1.1E6
l7.0E5
3 . 5E5
L0 . 0E0
Time
,ro
ro
-------
File:S975669 #1-425 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S
389.8156 F:3 Exp:EPCUS
Sample Text:FBI TLI#42 93 0A INJ. TIME
08:12 File Text:FBI TLI#4293»
1. 5E4
100%
l1.2E4
28:05
30:48
19.1E3
29:0
29:51
28:33
9:22 .
27:40
- 6.1E3
30 :27
i3.0E3
'0.0E0
28:00
29:00
30:00
Time
File:S975669 #1-425 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S
391.8127 F:3 Exp:EPCUS
Sample Text:FBI TLI#4293 0A INJ. TIME
28:05
08:12 File Text:FBI TLI#4293»
1.6E4
100%
11.3E4
.28; 47
9. 4E3
27:37
29:38
29:22
L6.3E3
29:04
i3.1E3
0 .0E0
28 :00
29:00 30:00
File:S975669 #1-425 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S
401.8558 F:3 Exp:EPCUS
Time
Sample Text:FBI TLI#4293 0A
100%
80J
60i
40
20j
ol
INJ. TIME
29,39
29:21
28 :00
29 :00
30 ! 00
08:12 File Text:FBI TLI#4293»
.1. 9E6
1.5E6
L1.1E6
7 . 6E5
3 . 8E5
0.0E0
Time
-------
File: S975669 #1-390 Acq:5-SEP-97 08:10:18 EI+"~Voltage SIR 70S
423.7766 F:4 Exp:EPCUS
Sample Text:FBI TLI#42930A INJ. TIME
08:12 File Text:FBI TLI#4293»
100%
1.5E4
32 :10
31:19
1.2E4
9.0E3
32 :31
:6.0E3
33 :42
33 :08
34:38
3 . 0E3
32:00 33:00 34
File:S975669 #1-390 Acq;5-SEP-97 08:10:18 EI+ Voltage SIR 70S
425.7737 F:4 Exp:EPCUS
Sample Text:FBI TLI#42930A INJ. TIME =
100% 31;3 5
35:00
::0 . 0E0
Time
08:12 File Text:FBI TLI#4293:
34:40
32:26
31:19
33:36
34 : IS
32 :10
33 :02
32 :4
_1
4E4
Li
2E4
L 8
7E3
Ls
8E3
1.2
9E3
1 0
0E0
32:00 33:00 34
File:S975669 #1-390 Acq;5-SEP-97 08:10:18 EI+ Voltage SIR 70S
435.8169 F:4 Exp:EPCUS
Sample Text:FBI TLI#42930A INJ. TIME =
100% 32;09
80J
60 J
40i
20 J
0
35:00
Time
08:12 File Text:FBI TLI#4293»
.1 .2E6
1 . 0E6
.7 . 5E5
.5 . 0E5
:.2 . 5E5
32 :00
L
33 :00
34:00
34:37
./y
35 : 00
.0.0E0
Time
, ro
ro
CO
-------
File:S975669 #1-390 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S
457.7377 F:4 Exp:EPCUS
Sample Text:FBI TLI#42930A INJ. TIME = 08:12 File Text:FBI TLI#4293»
100% 34 ; 38
32 :31
31:44
31:23 1
WW^M/^jivW
32:14
i
33 :03
32:54
33:30 33:
UmaJI,
35:13
35:32
4:11
34:00
35:00
80
60j
40j
20i
0
32100 33:00
File:S975669 #1-390 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S
459.7348 F:4 Exp:EPCUS
Sample Text:FBI TLI#42930A INJ. TIME = 08:12 File Text:FBI TLI#4293»
100%, 34 ; 38
2 . 0E4
1.6E4
ll.2E4
l7.9E3
4 . 0E3
lO.OEO
Time
_1.5E4
1.2E4
i8.7E3
32:12
33 :4
32 : 56
31:33
34 :25
15.8E3
5:19
35 :41
./vWli
30 :30
l2.9E3
:0 . QEQ
35:00
32:00 33:00 34:00
File:S975669 #1-390 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S
469.7779 F:4 Exp:EPCUS
Sample Text:FBI TLI#42 93 0A INJ. TIME
100%
80 J
60i
40J
20i
0.
Time
08:12 File Text:FBI TLI#4293»
34:37 _7.7E5
6.1E5
4.6E5
3 . 1E5
1.5E5
I ' 1 1 1 1——1 1
32 :00
_1 1 1 I T" 1 I
33 :00
-I 1 T
1 "I I r r-
34 :00
^—I ^—r
35 :00
0.0E0
Time
ro
lro
-------
File;S975669 #1-390 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S
457.7377 F:4 Exp:EPCUS
Sample Text:FBI TLI#42930A _... _ INJ. TIME
100% q A3 2 6E4'~>
80
60
40
20J
08:12 File Text:FBI TLI#4293»
.2 . 0E4
-1. 6E4
.1.2E4
-i 1 r 1 1 r 1 1 1 1 1 1
34:00 35:00
File:S975669 #1-390 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S
459.7348 F:4 Exp:EPCUS
Sample Text:FBI TLI#42930A —. INJ. TIME
1.00%, C.A2.55E^
80.
60.
40.
20 j
0
08:12 File Text:FBI
34:00 35:00
File:S975669 #1-390 Acq:5-SEP-97 08:10:18 EI+ Voltage SIR 70S
469.7779 F:4 Exp:EPCUS
Sample Text:FBI TLI#42930A
100%
80j
60.
40.
20.
0.
INJ. TIME = 08:12 File Text:FBI
34 :00
35 :00
ro
, ro
en
.7 . 9E3
.4 . 0E3
0.0E0
Time
TLI#4293»
1. 5E4
1.2E4
"8.7E3
5 . 8E3
2.9E3
- 0.0E0
Time
TLI#4293»
.7 . 7E5
.6 . 1E5
.4 . 6E5
13.1E5
.1. 5E5
.0 . 0E0
Time
-------
I
TLI Project: 42930A
Client Sample: FBI
Method 23 TCDD/TCDF Analysis (DB-225) 1
Analysis File: X973016
I
I
Client Project:
Sample Matrix:
TLI ID:
Iron & Steel-Youngstown
M23TRAIN Date Received:
179-98-4A-D Date Extracted:
Date Analyzed:
08/19/97
08/25/97
09/06/97
Spike File:
ICal:
ConCal:
SPC2NF04
XF24087
X973009
Sample Size:
Dry Weight:
GC Column:
1.000
n/a
DB-225
Dilution Factor:
Blank File:
Analyst:
n/a
S975665
ML
% Moisture
% Lipid:
% Solids:
n/a
n/a
n/a
Analytes
Amt. (ng} Dt
EMPC
Ratio
RT Flags
2,3,7,8-TCDF
0.02
0.84
22:50
Interna* Standard
Amt. (ng) % Recovery QC Limits
Ratio
RT Flags
13C 12-2,3,7,8-TCDF
2.7 68.3
40%-130%
0.79
22:50
I
I
I
I
Recovery Standard
Ratio
RT
Flags
i3Ci:-l,2,3,4-TCDD
0.79
21:47
Data Reviewer.
09/08/97
Page 1 of 1
C2NF.PSR *2.00. LARS6.10.W
I
I
I
(
I
I
I
I
I
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:57 09/08/97 A
226
-------
Data Review By:
Initial
_%L_
.... Date...
Calculated Noise Area: n/a
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No. 1
Listing
of X973016B
. dbf
09/08/97
Matched
GC Peaks /
Ratio / Ret.
Time
Compound/
M_Z.... QC.Log
Omit
Why
. . RT. OK
¦Ratio Total
.Area... Area
.Peak.1.. Area.
Peak.2..
Re 1. RT Compound. Najne
TCDF
0.
65-0.89
o.:
'98-1.102
304-306
DC
NL
0:00 RO
1 . 39
5.06
0.000
18:21 RO
0.92
75.99
39 .49
42.93
0.304
DC
SN
18:40 RO
1. 38
1.27
0. 313
DC
SN
18:50 RO
3 .13
2.30
0. 325
19:22
0.73
112.92
47 .78
65.14
0. 343
19:29
0.75
72.16
30.88
41 .23
0.353
19:37
0.89
106.67
50.35
56.32
0. 359
19:47
0.78
64.7 3
28.29
36 .44
0.866
20:04
0.79
39.05
17.19
21.36
0.379
20: 14
0.68
87.92
35. 57
52.35
0 . 386
20:21 RO
0.99
37.61
20. 99
21.25
0.391
20:32 RO
0. 57
120.29
52.33
91 .36
0 . 399
20:43 RO
0.38
24.35
10.31
28 .23
0 . 907
21 : 04
88.49
38 . 57
49 . 32
0 . 923
21:07 RO
0. 57
62.39
27. 14
47 .92
0.925
DC
SN
21 : 14
0.67
4.37
0.930
21:31 RO
0. 60
98.71
42. 94
71.46
0 . 942
21:43 RO
0.59
67.05
29. 17
49 . 11
0.951
21:57 RO
0. 58
52.32
22.98
39 .54
0. 961
DC
SN
22:11 RO
0. 32
7.24
0.972
22: 20
0.89
56.12
26.48
29.64
0.978
DC
SN
22:29
0.82
4.83
0 . 985
DC
SN
22: 32
0 . 63
3.67
0.987
22:42 RO
1.19
39.58
26. 68
22.36
0.994
M
22: 50
0.84
66.00
30.20
35.80
1.000 2378-TCDF
23:02
0.69
36.48
14.91
21.57
1 . 009
DC
SN
23: 14
0.65
8.34
1 . 013
23:21
0 .77
46. 33
20.18
26.15
1.023
23:29
0.74
69.98
29.75
40.23
1.028
DC
SN
23:42 RO
0.55
4.97
1.038
DC
SN
24:25 RO
1 .37
2.48
1. 069
25:00
0.87
15.75
7.34
8.41
1.095
DC
SN
25:09 RO
0.05
0.32
1.101
DC
WH
25:21 RO
1.37
3 .22
1. 110
304-306
22
Peaks
1,441.89
13C12-TCDF
0
.65-0.89
0.
956-1.044
316-318
DC
NL
0: 00
0.73
14.83
0 . 000
DC
WL
21:02
0.82
17.76
0.921
DC
WL
21:19 RO
0 . 64
9.33
0.934
DC
WL
21:30
0. 84
66.06
0.942
DC
WL
21:42
0.88
26.15
0. 950
DC
SN
22:27 RO
2.18
4.07
0.983
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive ~ Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:57 09/08/97
227 ~
-------
Page No.
Listing of X973016B.db£
09/08/97
Matched
QC Peaks / Ratio / Ret. Time
Compound/
M_Z QC. Log Omit
Why
. .RT.
OK
Ratio
Total.Area. . .
Area.Peak.1. .
Area.Peak.2. .
Rel.RT Compound.Name.. ID.
22:50
0.79
13,051.06
5,763.63
7,287.43
1.000 13C12-2378-TCDF ISO
DC
SN
23:08
RO
4.03
4.76
1.013
23:24
0.71
41.03
16.98
24.05
1.025
DC
m
23:51
RO
3.54
11.74
1.045
DC
24:01
RO
1.60
18.78
1 .052
DC
m
24:51
0.82
215.22
1 .088
316-318
2
Peaks
13,092.09
Above: TCDF / TCDD Follows
13C12-TCDD
332-334
DC NL
DC WH
332-334
0.65
0:00 RO
20:23 RO
21:31
21:47
22:27
24:08 EO
Peaks
0.89
2.83
1.16
0.30
0.79
0.31
0.33
0.907-1.093
2.09 0.000
50.78 33.31 28.69 0.947
10,860.16 4.819.78 6,040.38 1.000 13C12-2378-TCDD IS1
13.736.36 6,062.19 7,674.17 1 . 012 13C12-1234-TCDD RSI
134.96 60.60 74.36 1.043
18.46 1.122
24,782.26
Column Description.
"Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
. .R7. -Retention Time (nsn:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below signal to Noise Level
-------
*ilmxXS730lS 91-1285 leqx S-3BP-1997 23xT2x29 SCSI* Volbmgm 3XS AutoSpma
303.mis 8xp$XCOSP_Tr
Smaplm TmxtxFBl TLX04293OJL Pilm fmxtx 9MXMSOZE LABS
ion
95.
90.
85.
80.
75.
70.
65.
eoi
55.
50.
45.
40.
35.
30.
25.
20.
IS.
10.
5.
0.
19f32
19147
19t29
19t09
19156
20x14
20t21
20x04
20x43
20:52
T
"T"
1 I 1 1 !
19*22
19:00 19i12 19x24 19x36 19x48 20:00 20:12 20x24
PilotX973016 01-1285 Jkeqx 6-SBP-1997 23x12x29 QC BI+ Volbmgm SIR AatoSpme
305.0987 BxpxXCONPJTT
Saaplm Tmxt xWBl TLZ04293OA Film Tvctx TRXJUKKB LMB3
loan
95:
90:
85.
80:
75:
70:
65:
SO:
55.
50,
45.
40.
35.
30:
25:
20:
IS.
10.
5:
i » i i—i j i i—i i i
20t36 20x48
20x31
19x38
19x29
20x13
20x03
19x47
20x42
1.8S5
1.7B5
il.sss
11.5X5
1.4B5
1.3BS
1.2B5
Z.1.1B5
1.1B5
9.6B4
8.8E4
.7.9B4
7.0B4
6.1S4
S.3B4
4.4S4
3.5B4
12.6X4
1.8B4
8.8S3
211
O.OBO
00 Tlma
19x00
19x12
19x24
' | '
19x36
->—|—'—>
19x48
2.3S5
2.2B5
12.IBS
L2.OSS
1.9B5
1. 725
1.6S5
1.5BS
1.4B5
U.3B5
L1.2B5
1.0B5
9.3B4
8.1B4
17.0B4
L 5.8S4
'.4.7B4
3.5B4
12.3B4
1.2X4
20x00
20x12
I I ! » f 'T'B
20x24
20x36
20x48
21 x
O.OBO
00 Timm
229
-------
PilmtX37301S §1-1385 Aeq, t-3SP-1997 23ti2t39 X SI* Volbmv 31R XuboSpmc Sol»mtl9*7
303*3016 3SUB(256, 30,-3. 0) PKD(5,3,1, 0.10%. 7348. 0, 0. 00%,W, V) XxptXCOSFjrt
Smmplm TmxttFBI TLX04233OA Film Tmxtt TXXAHOLX LABS
13 tOO 20100 21100 22tOO 23t00 24t00
FilmtX973016 *1-128S Aeqt 6-SXF-1397 23112123 OC MX* Voltmgm SIX AutoSpme Soi»mtl432
305.8987 BSUB(256,30,-3.0) 003(5,3,1.0.10%,5728. 0,0.00%,F,F) XxptXC08F_TT
Saaplm TmxttFBI TLX04233OA Ml* Tmxtt TXXABBLX LABS
100* A3.J.3XS A7. ISMS
loom
JUS.23X5
A4.29M5
A3.67X5
A4.78M5
A2.30M5
A2.65SS
i
.35M4
_1.SM5
.1.3M5
.9.6X4
.2X4
I A2.38X5 .6.4X4
J1.4JJT5 tl
23*00 ' ' ' '24t00 ' ' ' 25t00 Tiam
^2.2X5
A6.51S5
1.8X5
A4.98X5
.36X5
1.3M5
A5.23MS
A3.39X5 A4.02X5
A2.96M5
8.8X4
A1.72X5
4.4X4
, | , , ,, | ,yw-T T, r 00 20x00 21 tOO 22t00 23:00 24'tOO 25'tOO
FllmtX373016 01-1285 Aeqt 6-SMF-1337 23tl2t23 OC XX* Voltmgm SIR AutoSpme Soift3120
315.9413 BSVB(256,30,-3.0) PXD(5,3,1,0.10%,12480.0,0.00%,F.F) XxptXCOBF_TT
Sampi* TmxtiFBl TLX04293OA Film Tmxtt TSXASOLX LABS
,0X0
Tim*
iom
so:
60.
40.
20.
i i 'i 1 i i i 1 I i i1 | "I1 * r i 'i I i i T i i j i i i i' t*'i" 1 i—i "i 1 'p't i > I
I9t00 20t00 21tOO 22tOO 23t00 24t00
rll»tX973016 01-1285 Aeqt 6-SXF-1397 23,12)29 OC MX* Yoltmgm SIM AtatoSpme Holm*>42S3
317.3389 BSim(256,30,-3.0) KtD(5,3,1,0.10%, 17172.0,0.00%,F.W) XxptXeaiF_TT
Sanpl* TmxtiFBl TLI04233OA Film Tmxtt TXZABOLX LABS
AS.76X7
^1.5X7
1.2X7
18.7X6
5.8X6
.2.9X6
-P—I—r—r
25 tOO
0.0X0
Tiam
loan
80.
60.
40.:
20.
A7.29X7
J
) i i I r l i i i | i i i i r | i i ¦! i i | i i
13100 20t00 21 tOO 22 tOO 23'tOO 24t00
PilmtX373016 §1-1285 Aeqt 6-SMF-1337 23tl2t29 OC XX* Voltmgm SIR AntaSpmc
375.8364 XxptXCOBF_TT
Saspl* Tmxtt FBI TLX04293OA Film Tmxtt TSXASOUt IMS
25t00
.1.8X7
.1.4X7
.1.1X7
.7.1X6
.3.6X6
.0.0X0
Tiam
100% 18 f 2 7
801
60.
401
20:
0.
•<**/
I3t05,
20:17
20t40
21tl3
22t08
22 >50
23*29
23*57
24t37
IStOO
" I I I » »
20t00
21 tOO
22 tOO
'23t00
< | 1
24 tOO
.1.8X5
.1.5X5
11.1X5
7.3X4
3.7X4
25tOO
.0.0X0
Timm
230
-------
PilmtXS73016 §1-1295lcq» W-3MP-1397 23il2t33 OC ST* Volfew 3ZM luboSpma SoimmtSBO
319.8965 33X33(256,30,-3.0) PXB<5,3,1, 0.10*, 2320. 0, 0. 00*, F,F) SxpiICOSF_TT
Smmplm Tmxtt FBI TLI§42930A Film Tmxtt TRIABBLX LABS
100* A3.95X4 A1.?3X5
20ioo 21100 22 too 23 too 24too
FilmtZ973016 §1-1285 Aeqt 6-SEV-1997 23tl2t29 QC SI* Voltmgm SIR AutoSpmc Solsmt*82
321.8936 B3tm(256,30,-3.0) PXB(5,3,1,0.10*, 1928.0,0.00*,*,*) XxptXCOSF_TT
Smaplm Tmxtt FBI TLI04293OA Film Trnxtt TRXASOLX LABS
A3.82X4
AS. 36X4
A3.43X4
A6.94X4
A4.26X4
16.34X4
14.59X4
A3.13X4
100k
A3.12X5
A6.18X4
A3.60S4 A7.81B4
A4.88E4
AS.27X4
A3.88X4 "-02X4
A4.83X4
A5.52X4
A2.82X4
1.35S4
64M4
20)00 21i 00 HtOO 23)00 24t00
FllmiX973016 §1-1285 Aoqt 6-SXF-1997 23tl2t29 OC XI* Voltmgm SIX AutoSpmc Noie;S3S
327.8847 BSUB(2S6,30,-3.0) PXD (5, 3,1,0.10*, 2144.0,0.00*, F, F) SxptXCOHF_TT
Saaplm Trnxtt FBI TZX04293OA Film Trnxtt TXXAStZM LABS
100S
80.
60.
40,
201
A9.60X7
•20*00'
n~
1 1 1
23 tOO
21tOO 22t00
FilmtZ9730l6 §1-1285 Aeqt 6-3XP-1997 23tl2t29 <2C XX* Voltmgm SIS *uto^>ac Soiamtl672
331.9368 BSm(256,30, -3.0) PXD (5, 3,1,0.10*, 6688.0,0.00*,F, F) XxptZCOHP_TT
Saaplm TmxttFBl TLX§42930A Film Tmxtt TRIASOLX LABS
1—1 p-
24t00
1 1 " 1 1*1 »™r" 1' i" 1 ¦ 1 *1 1 1 1 1 1 1 1 1 1
20<00 21t00 22i00 33i00
FilmtX973016 §1-1385 Aeqt 6-SXF-1997 23il2t29 OC MI* Voltmgm SIR AutoSpmc Hoimmt588
333.9338 BSUB(256,30, -3.0} PSD(S,3,1, 0.10*,23S2.0, 0.00*,F,F) Sbgj»«*!KP_lT
Smaplm Tmxtt ml TLI§42930A Film Tmxtt TRIAlfSLX LABS
lOOSf
80.
60.
401
20.
A6.06X7
A4.82X7
A_,
1 r
24 tOO
100If
80.
60.
40.
20.
0.
A7.67X7
A6.04X7
30 tOO
31 tOO
22100
33 tOO
1 1 'I11
34 tOO
_5.2*7
1.7X7
,1.3X7
8.4X6
,4.2X6
0.0X0
Timm
231:
-------
FilmtX973016 01-1285 Aaqt 6-SMF-1997 23,12,29 OC XX* Voltmgm SXX AutoSpme
303.90ie meptxcaarjTT
Smaplm TexttFBI TLX04293OA Film Tmxt, TXXAXLX LABS
tornI 19f22
21104 21t31
20i14 | J | 22i42
21tS7 L
25*00 20)00 21'tOO 22,00 23i00 24,00
FilmtZ973016 *1-1295 Acqt 6-SKP-1997 23il2t29 CtC XX* Voltmgm SXX AutoSpme
315.9419 SxptXCOSFJTT
Smaplm TmxttFBI TLX04293OA Film 7Ut> TXXASBLX LABS
100H 22f50
80.
60.
40.
20.
mJL
1 I I t I I I 1 1 I V 1 1 I I 1 » "I 'I 1 1 l""l 1 I ' < ^ ! 1 I I I
19>00 20,00 21>00 22tOO 23>00
Film>1973016 01-1285 Aeqt 6-SXF-1997 23,12t29 OC XX* Voltmgm SIX AutoSpme
319.8965 XxptXCOSFJFT
Saaplm TmxttFBl TLX04293OA Film Tmxt, TXXASma LABS
100If 21f31
22t30
80J 20 tOO
20t26
60:
9t47
0t43
18150
1.8*5
1.4M5
L1.1XS
7.0X4
3.5X4
0.0X0
25 tOO
TiMB
'' I 'I
24:00
' TJ
25 tOO
40:
26:
01
24t49
\ I i i 11 i i i i i i i r i" i "i—i i11 i i i i—ii i i 11 i i i
19t00 20,00 21 too 22 too 23,00 24,00
Fllm,X973016 01-1285 Aoqt 6-SXF-1997 23,12t29 OC XX* Voltmgm SIX AutoSpme
331.9368 Bxp,XCOHF_rT
Smwplm TmxttFBl TLX04293OA Film Tmxtt TRXASOLB LABS
21,47
i i1—r-
25 tOO
iom
80.
60.
40.
20.
0.
21131
i i i 'I i i i i i I i i i i i I i i '» *r i' 'i' 'i i 'i i i 'i" i i»'i ii i
19:00 20,00 21,00 22,00 23,00 24,00
FllmtX973016 01-1285 Aoqt 6-SMF-1997 23tl2t29 OC XX* Voltmgm SXX AutoSpme
292.9825 XXBtXCOSF TT
Smaplm tmxttFBI TLX04293OA Film Tmxtt TBXABBLX LABS
25,00
.1.5X7
.1.2X7
.8.7X6
.5.8X6
.2.9X6
.0.0X0
7im»
.5.2X4
,4.2X4
.3.1X4
'¦.2.1X4
.1,0X4
.0. 0X0
Timm
1.8X7
1.4X7
1.1X7
,7.1X6
.3.5X6
.0.0X0
TiMm
iom
80S
60.
40.
20.
0.
1 18,33 Hi}1 A** 1*1 20,20 2a'*6 21,28 23,05 23*22 23,59 24,37 25,09 c3'
__
T
—
19,00 20i00 21:00 22'tOO 23:00 24t00
FilmtX973016 01-1285 Acqt 6-SXP-1997 23,12,29 OC XX* Voltmgm SXX AutoSpme
330.9792 BxptXCGBFJTT
Smaplm TmxttFBl TLZ04293OA Film Tmxtt TRIANBLX LABS
100H _ „ 191*5. 20220 20:58 21,36 22,29 3*>°*
601
40.
202
0.
' l' t
25,00
25,01
.3.5X7
8X7
12.2*7
.1.4X7
'.7.0X6
-.0.0X0
rimm
4.5X7
-.3.6X7
12.7X7
1.8X7
-.9.1X6
I ! I 11 f 1 f 1 111
19,00 20,00
-i—| »1111
21 tOO
22,00
23,00
24 tOO
25,00
0.0X0
Tiam
23
-------
-------
File:X973016 #1-1285 Acq: 6-SEP-1997 23:12:29 GC EI+ Voltage SIR AutoSpec
303.9016 Exp:XCONF_TT
Sample Text:FBI TLI#42930A FileJText: TRIANGLE LABS
100%, (Tp3V92E5^
80j
60 j
40j
20.:
0
1 1 1 1 1 1 1 1 1 1 1 J 1 1 1
22:00 23:00 24:00
File:X973016 #1-1285 Acq: 6-SEP-1997 23:12:29 GC EI + Voltage SIR AutoSpec
305.8987 Exp:XCONF_TT
Sample Text:FBI TLI#42 930A File Text: TRIANGLE LABS
100%
80j
60j
40 J
20j
0
1 1 1 1 1 1 1 1 1 1 1 1 1 j 1
22:00 23:00 24:00
File:X973016 #1-1285 Acq: 6-SEP-1997 23:12:29 GC EI + Voltage SIR AutoSpec
315.9419 Exp:XCONF_TT
Sample Text:FBI TLI#42930A File Text: TRIANGLE LABS
100% 22;50
80 J
60i
40 J
20 J
0
22 : 00
23 :00
-1 1
24:00
.1 .2E5
.1. 0E5
.7 . 5E4
.5 . 0E4
.2 . 5E4
.0 . 0E0
Time
.1.5E5
.1.2E5
.8 . 8E4
.5 . 9E4
.2 . 9E4
.0 . 0E0
Time
.1.5E7
_1. 2E7
.8 . 7E6
.5 . 8E6
.2 . 9E6
.0 . 0E0
Time
ro
» CO
-------
I
| TLI Project:
Client Sample:
I
I
42930A
RBI
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975670
Client Projeci:
Iron & Steel-Youngstown
Sample Matrix:
M23TRAIN
Date Received: 08/19/97
Spike File:
SPX23704
TLI ID:
179-98-5A-E
Date Extracted: 08/25/97
ICal:
SF56117
.
Date Analyzed: 09/05/97
ConCal:
S975664
Sample Size:
1.000
Dilution Factor: n/a
% Moisture:
n/a
Dry Weight:
n/a
Blank File: S975665
% Lipid:
n/a
GC Column:
DB-5
Analyst:
HLM
% Solids:
n/a
j Analytes
AmL (ng)
DL EMPC
Ratio
RT Flags
2,3,7,8-TCDD
ND
0.01
1,2,3,7,8-PeCDD
ND
0.02
1,2,3,4,7,8-HxCDD
ND
0.02
1,2,3,6,7,8-HxCDD
ND
0.01
1,2,3,7,8,9-HxCDD
ND
0.01
1.2,3.4.6,7.8-HpCDD
ND
0.02
1,2,3,4.6,7.8,9-OCDD
ND
0.04
—
2,3,7,8-TCDF
ND
0.008
1,2,3,7,8-PeCDF
ND
0.01
2,3,4,7,8-PeCDF
ND
0.01
1,2,3,4,7,8-HxCDF
ND
0.01
1,2,3,6,7,8-HxCDF
ND
0.009
2,3,4,6,7,8-HxCDF
ND
0.01
1,2,3,7.8,9-HxCDF
ND
0.01
1.2,3.4,6,7.8-HpCDF
ND
0.01
1,2,3,4,7,8,9-HpCDF
ND
0.02
1,2.3,4,6,7.8.9-OCDF
ND
0.03
| Totals
Ami (ng) Number Dt. EMPC
Flags
Total TCDD
ND
0.01
Total PeCDD
ND
0.02
Total HxCDD
ND
0.02
Total HpCDD
ND
0.02
—
Total TCDF
ND
0.008
Total PeCDF
ND
0.01
Total HxCDF
ND
0.01
Total HpCDF
ND
0.02
I
I
I
I
I
I
I
I
I
I
I
I
I
Page 1 of 2
X237.PSR V2.0Q, LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 16:29 09/0&B* j-
-------
Eastern Research Group
TLI Project: 42930A Method 23 PCDD/PCDF Analysis (a)
Client Sample: RBI Analysis File: S975670
internal Standards
Amt {ng)
% Recovery
QC Limits
Ratio
RT
Flags
ir>C;;-2,3,7.8-TCDF
3.0
76.1
40%-130%
0.73
20:44
'3C;:-2.3,7.8-TCDD
2.7
66.7
40%-130%
0.82
21:32
13C12-l,2,3,7,8-PeCDF
2.4
59.7
40%-130%
1.61
24:57
i3Cn-1,2,3,7.8-PeCDD
2.5
63.0
40%-130%
1.50
26:04
nC;;-1,2,3.6,7,8-HxCDF
3.0
74.2
40%-130%
0.51
28:38
l3Cn-l,2,3,6,7,8-HxCDD
3.0
75.9
40%-130%
1.19
29:21
:3C,;-1.2.3,4.6,7.8-HpCDF
2.7
66.8
25%-130%
0,43
31:18
"Ci;- 1.2.3,4.6,7,8-HpCDD
3.0
75.0
25%-130%
1.08
32:09
,3Ci:-1,2.3,4.6.7.8.9-OCDD
4.6
57.2
25%-130%
0.88
34:37
—
i Surrogate Standards (Type A)
Amt. (ng)
% Recovery
. QC Limits
Ratio
RT
Flags
17CL-2.3.7,8-TCDD
3.9
98.1
70%-140%
21:32
13Cir 2,3,4,7,8-PeCDF
3.9
96.8
70%-140%
1.70
25:42
13C a-1,2,3,4,7,8-HxCDF
3.8
94.8
70%-140%
0.50
28:32
l3Ci;- 1,2,3,4,7,8-HxCDD
3.6
89.2
70%-140%
1.19
29:16
l3Ci2-l,2,3,4,7,8,9-HpCDF
3.9
96,4
70%-140%
0.39
32:30
—
Alternate Standards (Typ© A)
Amt. (ng)
% Recovery
QC Limits
Ratio
RT
Flags
13Ci2-l,2,3,7,8,9-HxCDF
2.9
73.4
40%-130%
0.53
29:51
13C,2-2,3,4,6,7,8-HxCDF
3.1
77.7
40%-130%
0.51
29:08
—
l3Ci2- 1,2,3,4-TCDD
0.84
21:19
13Cir 1,2,3,7,8,9-HxCDD
1.18
29:38
Data Reviewer Si Lt,, w> 09/08/97
Page 2 of 2 xu? _psr vioo. lars 6.iom
Triangle Laboratories, Inc.®
801 Capita la Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 16:29 09/08/97
'
-------
Initial ....Date...
Data Review By: Calculated Noise Area: 1.09
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No. 1
Listing
of S975670B.dbf
09/08/97
Matched
GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log
Omit
Why
. .RT.
OK
•Ratio Total. Area. . .
Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.
TCDF
0.
65-0.89
0.827-1.099
304-306
DC
NL
0:00
RO
1.00 0.25
0 . 000
DC
SN
17:48
RO
2.30 0.27
0.359
D
DC
SN
20:44
RO
1.15 3.73
1.000 2378-TCDF AN
DC
SN
21:19
0.77 1.13
1 . 023
304-306
0
Peaks
0.00
13C12-TCDF
0,
,65-0.89
0.952-1.048
316-318
DC
NL
0: 00
RO
1.00 0.23
0.000
DC
WL
18:26
RO
1.07 1.35
0.389
DC
WL
18:53
RO
0.37 0.92
0.911
20:44
0.73 1,039.88
438.20 601.68 1.000 13C12-2373-TCDF ISO
21: 32
0.31 2.79
1.25 1.54 1.039
DC
WH
21:58
0.72 2.61
1 . 059
DC
WH
23: 00
RO
0.63 1.77
1 . 109
316-318
2
Peaks
1,042.67
nvnn i i _ _
iiwjju roilows —
TCDD
0.
.65-0.39
0.361-1.053
320-322
DC
NL
0:00
RO
0.92 0.21
0 . 000
DC
SN
18:51
RO
3.92 0.21
0.375
DC
SN
19:05
RO
2.50 0.21
0.386
DC
SN
19: 19
RO
0.15 0.25
0. 397
DC
SN
20: 00
RO
1.65 0.30
0.929
DC
SN
20:44
0.72 0.81
0 . 963
DC
SN
21:23
RO
1.24 0.37
0.993
DC
SN
21: 32
RO
0.12 0.39
1.000 2378-TCDD AN
DC
SN
21:40
RO
0.60 0.34
1 . 006
DC
SN
22: 36
RO
0.06 0.07
1 . 050
DC
WH
22:59
RO
1.18 0.30
1.067
320-322
0
Peaks
0.00
37C1-TCDD
0.907-1.093
328
DC
NL
o
o
o
0.15
0.000
DC
WL
18:43
0.56
0. 869
DC
WL
18:51
0.20
0.87 5
DC
WL
19:09
0.53
0.389
DC
SN
19:46
0.50
0.913
-------
Page No. 2
09/08/97
Listing of S975670B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound /
H_Z QC.Log
Omit
•Why
. .RT.
OK
Ratio Total
.Area...
Area.Peak.1. . Area
Peak.2..
Re1.RT Compound.Name..
DC
SK
22:
16
0.25
1.034
22:
35
1.74
1.74
1.049
DC
SN
22:
57
0.58
1.066
SN
23:
02
0.24
1.070
DC
SN
23:
08
0,63
1.074
328
5
Peaks
620.97
13C12-TCDD
0.
65-0.89
0.907-1.093
332-334
DC
NL
0:
00
RO
7.93
0.27
0.000
DC
WL
19:
04
RO
2.18
1.47
0.385
19:
34
RO
1.26
2.23
1.59
1.26
0.909
DC
SN
20:
23
RO
3.22
1.06
0.947
DC
SN
21:
05
RO
2.25
0.64
0.979
21:
19
0.84
1.036.76
472.86
563.90
0.990 13C12-1234-TCDD
21:
32
0.82
736.93
331.26
405.67
1.000 13C12-2378-TCDD
21:
43
RO
0. 94
3. 32
2.04
2.16
1.009
21:
54
RO
1.08
13.10
8.01
7 .40
1.017
DC
SN
22:
13
RO
3. 18
0.99
1.032
DC
SN
22:
37
RO
3.16
1.19
1.050
332-334
5
Peaks
1.792.34
: icuu /
PeCDr rollows ————
PeCDF
1
32-1.78
0.910-1.076
340-342
DC
NL
0:
00
RO
1. 00
0,21
0. 000
DC
WL
22:
37
RO
0.80
0.58
0.906
DC
SN
23:
10
RO
0.40
0.41
0.929
DC
SN
23:
33
RO
0.23
0.36
0.944
DC
SN
23:
38
RO
0. 16
0.20
0.947
DC
SN
23:
57
RO
2.96
0.59
0.960
DC
SN
24:
14
1.41
0.41
0.971
DC
SN
25:
07
RO
0.26
0.41
1.007
DC
SN
25:
29
RO
0. 17
0.41
1. 021
DC
SN
25:
32
RO
2 . 83
0.46
1.023
DC
SN
25-
43
RO
0.37
0.63
1.031 23478-PeCDF
DC
3N
26-
00
RO
0.08
0.07
1.042
DC
SN
26
15
RO
2.78
0.69
1.052
DC
SN
26
48
RO
1 .90
0.79
1.074
DC
WH
26
54
RO
0.58
0.46
1.078
340-342
0
Peaks
0.00
13C12-PeCDF
1
32-1.78
0.840-1.160
352-354
DC
NL
0
00
SO
1.25
0.25
0.000
DC
SN
23
15
RO
0.63
0.58
0.932
DC
SN
24
03
RO
3.36
0.92
0.964
DC
SN
24
11
RO
0.48
0.31
0.969
24
57
1.61
700.82
432 . 64
268.18
1.000 13C12-PeCDF 123
25
16
RO
2 . 08
4.95
4.03
1.94
1.013
25
21
RO
0.27
1.79
1.09
4.01
1.016
25
42
1.70
657.75
414.45
243.30
1.030 13C12-PeCDF 234
26
00
1.35
2.66
1.53
1.13
1.042
DC
SN
26
05
RO
1.97
0.77
1.045
ID,. Flags.
IS1
AN
S0R2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive * Durham, North Carolina 27713 Printed: 16:30 09/08/97
Phone: (919) 544-5729 • Fax: (919) 544-5491 237
-------
Page No. 3
09/03/97
Listing of S975670B.db£
Matched GC Peaks / Ratio / Bet. Time
Corapound/
M„Z.... QC.Log
Omit
why
. -RT.
OK
Ratio Total
.Area...
26:
40
1. 34
3.07
DC
SN
26:
47
RO
3 .48
0.64
352-354
6
Peaks
1,371.04
PeCDF /
PeCDD
1
-32-1.78
356-358
DC
NL
0
00
RO
1. 00
0.20
DC
SN
24
18
RO
1. 08
0.64
ry~
SN
24
37
RO
1. 00
0.39
DC
SN
25
35
RO
0.83
0.08
DC
SN
25
50
RO
0. 63
0.77
DC
SN
26
08
1.52
0.68
DC
SN
26
15
RO
0.88
0.49
DC
SN
26
30
RO
1.83
0.39
DC
WH
26
48
1. 47
1.48
356-358
0
Peaks
0.00
13C12-PeCDD
1
32-1.78
363-370
DC
NL
0
00
RO
0. 92
0.20
DC
SN
24
10
RO
1 .06
0.59
DC
SN
24
38
RO
1.06
0.32
DC
SN
24
50
RO
2.52
0.64
DC
SN
24
58
RO
1. 00
1.09
DC
SN
25
28
RO
4.08
0.64
DC
SN
25
39
1.52
0.58
DC
SN
25
53
RO
0.61
0.33
26
04
1 . 50
414.73
26
12
RO
1 .23
37.74
DC
SN
26
34
RO
5.65
0.59
DC
SN
26
40
RO
3.14
0.74
DC
SN
26
52
RO
0.77
0.61
368-370
2
Peaks
452.47
~ LJJmJ /
HxCDF
1
05-1.43
374-376
DC
ML
0
00
RO
1. 00
0.20
DC
SN
27
35
RO
2 . 60
0.22
DC
SN
27
39
RO
1. 64
0.25
DC
SN
27
44
RO
8.14
0.16
DC
SN
27
52
RO
2 . 00
0.63
DC
SN
28
02
RO
2.67
0.81
DC
SN
28
15
RO
0. 59
0.43
DC
SN
28
31
RO
2.10
0.69
DC
SN
28
39
RO
4.00
0.29
DC
SN
28
52
1.16
0.41
DC
SN
28
58
RO
2.24
0.47
DC
SN
29
03
RO
0.40
0.38
DC
SN
29
08
RO
0.62
1.77
DC
SN
29
22
RO
0.79
0.94
DC
SN
29
30
RO
0 . 56
1.08
Area.Peak.1.. Area.Peak.2.. ReX.RT Compound.Name.
ID.
Flags.
1.76
1.31 1.069
1.073
0.923-1.025
0.000
0, 932
0.944
0.981
0.991
1.003
1.007
1.017
1.028
0.347-1.153
0.000
0.927
0.945
0.953
0.953
0.977
0. 984
0.993
243.68
22.94
166.05
18. 64
000
005
019
023
13C12-?eCDD 123 IS3
1.031
.957-1.051
0.000
0.963
0.966
0.969
0.973
0.979
0.987
0.996 123478-HxCDF
1.001 123 673-HxCDF
1.008
1.012
1.015
1.017 234678-HxCDF
1.026
1.030
AN
AN
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive ~ Durham, North Carolina 27713 Printed: 16:30 09/08/97
Phone: (919) 544-5729 • Fax: (919) 544-5491 2 3 g
-------
Page No, 4
09/08/97
Listing of S975670B.dbf
Matched GC Peaks / Ratio / Ret, Time
Compound/
M_Z.... QC,Log
Omit
Why
, .RT.
OK
Ratio Total
.Area...
Area.Peak.1.. Area
Peak.2.. Rel.RT Compound.Name..
ID. .
DC
SN
29:
44
RO
5.30
0.22
1.038
DC
SN
29:
52
RO
0.50
0.40
1.043 123789-HxCDF
AN
DC
SN
30:
02
RO
0.82
0.56
1.049
DC
WH
30:
11
EO
1.83
1.08
1.054
DC
WH
30:
15
RO
3.72
0.40
1.056
DC
"WH
30:
25
RO
4.29
0.16
1.062
374-376
0
Peaks
0.00
13C12-HXCDF
0 .
43-0.59
0.360-1.140
384-386
DC
NL
0
00
RO
0.41
1.45
0.000
DC
SN
28
01
RO
2.79
0.21
0. 978
28
32
0. 50
728.41
243.62
484.79 0.997 13C12-HXCDF 473
SUE 3
28
38
0 . 51
801.17
271.81
529.36 1.000 13C12-HXCDF 678
XS4
28
50
0.58
5.46
2.00
3.46 1.007
DC
SN
28
58
RO
0.63
2.31
1.012
29
08
0. 51
776.34
263.03
513.31 1.017 13C12-HXCDF 234
ALT 2
DC
SN
29
18
RO
0.39
2.19
1.023
29
20
RO
1 .20
2.85
2.27
1.89 1.024
DC
SN
29
31
RO
0. 86
1.12
1.031
29
51
0. 53
638.25
220.51
417,74 1.042 13C12-HXCDF 789
ALT1
30
01
RO
1. 06
3.11
2.19
2.06 1.048
30
06
RO
1.38
1.71
1.56
1.13 1.051
DC
SN
30
18
RO
1.38
1.01
1.058
30
22
RO
1.09
1.89
1. 36
1.25 1.061
384-386
9
Peaks
2,959.69
Abov
Uv»r*nv /
ove.
nXv.uu r onows
HxCDD
1.
05-1.43
0.952-1.015
390-392
DC
NL
0
00
RO
0.83
0.18
0.000
DC
SN
28
01
RO
0.74
0.89
0.955
DC
SN
28
22
RO
0. 84
0.65
0.966
DC
SN
28
38
RO
8. 69
0.29
0. 976
DC
SN
28
42
RO
0.35
0.45
0.978
DC
SN
28
52
RO
0.28
0.14
0.984
DC
SN
28
57
RO
4.00
0.11
0.986
DC
SN
29
02
1.41
0.41
0.989
DC
SN
29
08
RO
1.96
1.05
0.993
DC
SN
29
15
RO
1.00
0.69
0.997 123478-HxCDD
AN
DC
SN
29
26
RO
0.21
0.34
1.003
DC
SN
29
48
RO
0.16
0.16
1.015
DC
WH
29
51
RO
0.91
0.87
1.017
DC
WH
29
57
RO
2.29
0.31
1.020
DC
WH
30
03
RO
3.08
0.58
1.024
390-392
0
Peaks
0.00
13C12-HxCDD
1
05-1.43
0.966-1.034
402-404
DC
NL
0
: 00
1.36
0.26
0.000
DC
WL
27
: 57
1.16
1.06
0.952
DC
WL
28
: 14
RO
1.97
0.76
0.962
DC
SN
28
: 37
RO
0.36
0.49
0.975
29
: 16
1.19
588.14
319.40
268.74 0.997 13C12-HXCDD 478
S0R4
Flags.
Triangle Laboratories, Inc.® Analytical Services Division
801 Capita la Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 16:30 09/08/97
239
-------
Page No. 5 Listing of S975670B.db£
09/08/97 Matched GC Peaks / Ratio / Ret. Time
Compound/
QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
29:21
1.19
677.46
367.47
309.99
1.000
13C12-HXCDD
673
IS5
29: 38
1. 18
896.78
485.91
410.37
1.010
13C12-HXCDD
789
RS2
29:47
RO
1. 44
8.36
5.36
3.73
1.015
DC
SN
29: 54
RO
2.22
1.10
1. 019
DC
SN
30:00
RO
1.37
1.23
1.022
DC
SN
4
30: 05
Peaks
1. 13
1.90
2,170.74
1.025
Above: HxCDD / HpCDF Follows
HpCDF
0.
38-1.20
0.995-1.044
408-410
DC
ML
0
00
RO
1.36
0.22
0 . 000
D
DC
SN
31
18
0.98
2.99
1.000 1234678-HpCDF
DC
SN
31
31
0.90
0.55
1 .007
DC
SN
31
42
RO
0.30
0.26
1.013
DC
SN
32
09
RO
2.11
1.94
1.027
DC
SN
32
31
RO
3 .08
0.82
1.039 1234789-HpCDF
DC
SN
32
34
RO
4 .43
0.36
1. 040
TY~
|A>
WH
32
58
RO
2. 03
0.69
1.053
408-410
0
Peaks
0.00
13C12 -HpCDF
0
37-0.51
0.
936-1.123
413-420
DC
NL
0:00
RO
12. 09
0.16
0.000
31:18
0.43
531.63
159.34
272.29
1.000 13C12-HpCDF
678
IS6
32:30
0.39
394,99
111.45
233.54
1.033 13C12-HpCDF
789
3UR5
DC
SN
32:51
RO
0. 56
2.58
1.050
33: 01
RO
1. 11
1.77
1.37
1 .23
1. 055
413-420
3
Peaks
928.39
Above: HpCDF / HpCDD Follows
HpCDD
424-426
424-426
0.88-1.20
0.977-1.006
DC
NL
0
00
RO
0.85
0.22
0
000
DC
SB
32
00
RO
3. 50
0.53
0
995
DC
SN
32
09
RO
0.79
0.34
1
000
DC
WH
32
31
1.09
2.95
1
011
DC
WH
32
43
RO
0.49
0.82
1
018
0
Peaks
0.00
AN
13C12-HpCDD
436-433
436-438
0
88-1.20
0.969-1.031
DC
NL
0:00
RO
6.36
0.29
0.000
DC
SN
31:33
RO
3 . 88
0.67
0.981
DC
SN
31:55
RO
1. 63
0.49
0.993
32:09
1.08
547.82
284.57
263.25 1.000 13C12
DC
SN
32:24
RO
0.74
1.94
1.008
1
Peak
547.82
Above: HpCDD / Octa-CDD and CDF Follows
OCDF 0.7S-1.02 0.884-1.116
442-444 DC NL 0:00 RO 0.66 1.00 0.000
31:41 0.95 2.48 1.21 1.27 0.915
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 16:30 09/08/97
240 "
-------
Page No.
Listing of S975670B.db£
09/08/97
Matched
GC Peaks /
Ratio / Ret,
Time
Compound/
M_2.... QC.Log
Omit
Why
. .RT.
OK
Ratio Total
.Area... Area.Peak.1.. Area.Peak.2..
Re1.RT Compound.Name
DC
SN
31: 57
RO
1. S6
1.21
0.923
DC
SN
32:09
RO
1. 46
1.68
0.929
DC
SN
32:17
RO
1.48
0.59
0.933
DC
SN
32:26
RO
0.58
0.98
0. 937
DC
SN
32:38
RO
0. 39
0.53
0.943
DC
SN
32: 38
RO
0.44
0.98
0.943
DC
SN
33:02
RO
. 0.34
0.85
0.954
DC
SN
33:39
RO
0.64
0.53
0.972
DC
SN
33:45
RO
3.08
1.19
0.975
DC
SN
34:01
RO
2.02
1.91
0.983
DC
SN
34:43
RO
0.58
1.81
1.003 OCDF
34:58
RO
1.09
2.97
1.71 1.57
1. 010
DC
SN
35:19
RO
1.51
1.40
1.020
35:32
RO
1.62
2.29
1.9S 1.21
1.026
DC
SN
35:44
RO
1.58
1 .80
1 .032
DC
SN
35:53
RO
2.29
0.93
1.037
442-444
3
Peaks
7.74
OCDD
0.
.76-1.02
0.
384-1.115
453-460
DC
NL
0:00
1 .00
0.24
0. 000
DC
SN
34:26
RO
1.60
1.00
0. 995
D
DC
SN
34:37
0.82
5.38
1.000 OCDD
DC
SN
34:56
RO
0.28
0.51
1.009
458-460
0
Peaks
0.00
I3C12-OCDD
0
.76-1.02
0 .
996-1.006
470-472
DC
NL
0:00
0.91
0.21
0.000
34:37
0.88
532.44
249.52 282.92
1.000 13C12-OCDD
DC
WH
35:04
RO
3.05
0.76
1. 013
470-472
1
Peak
532.44
ID.. Flags.
m
m
I S3
Column Description.
"Why" Code Description......... QC Log Desc.
M_Z -Nominal Ion Mass(es)
..ST. -Retention Time imm:ss)
Rat.1 -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report ***
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
File:S975670 01-867 Acq:5-SEP-97 08:49
303.9016 F:2 BSUB(256, 30, -3.0) PKD(9,S
TRIANGLE LABS Text:SB1 TLI04293OA
100:
AS. 69E3
18:00 19:00
File:S975670 #1-867 Acq:5-SEP-97 08:49
305.8987 F:2 BSXTB(256, 30, -3.0) PKD(9,5
TRIANGLE LABS Text:SB 1 TLI04293OA
ioo:
18:00 19:00
File:S975670 #1-867 Acq:5-SEP-97 08:49
315.9419 F:2 BSOB(256,30, -3. 0) PKD(9,5
TRIANGLE LABS Text:RBI TLI*42930A
ioo:
80j
sol
4 OA
201
01
¦37 EI+ Voltage SIR 70S Noise: 72
5, 0.05%, 288.0,1.00%, F, T) Exp:EPCUS
INJ. TIME = 08:52
A2.43E4
4.71E3 .A3.01E.
A1. 75E4
20:00 21:00 22:00
¦37 EI+ Voltage SIR 70S Noise: 72
5, 0.05%, 288. 0,1. 00%, F, T) Exp:EPCUS
INJ. TIME = 08: 52
23:00
A1. 03E4
A1 A01E4
A2.10E4
A3.66E3
A2.11E4
A1. 03E4
A1.14E4
A1.36E4
A8.98BJ
20:00 21:00
37 EI+ Voltage SIR 70S Noise: 66
5,0.05%, 264 .0,1. 00%, F,T) Exp-.EPCUS
INJ. TIME = 08: 52
A4.38E6
22:00
23:00
lx.
18:00 19:00
File:S975670 #1-867 Acq:5-SEP-97 08:49:
317.9389 F:2 BSOB(256,30, -3. 0) PKD(9, 5,
TRIANGLE LABS Text:RBI TLI#42930A
1001
801
20:00 21:00 22:00
37 EI+ Voltage SIS 70S Noise: 64
5, 0.05%, 256. 0,1. 00%, F, T) Exp:EPCOS
INJ. TIME = 08:52
A6.02E6
23:00
601
40J
204
18:00 19:00
File: S9 756 70 *1-867 Acq:5-SEP-97 08.-49
330.9792 F-.2 Exp-.EPCOS
TRIANGLE LABS Text:RBI TLI#42930A
100.
20:00 21:00
-.37 EI* Voltage SIR 70S
INJ. TIME
22: 00
08:52
21;52 22s33
23:00
0E6
4E5
3E5
2E5
1E5
OEO
Time
5E6
2E6
9E5
9E5
0E5
OEO
Time
18:00 19:00
File:S975670 #1-867 Acq:5-SEP-97 08:49
375.8364 F-.2 Exp-.EPCUS
TRIANGLE LABS Text:RBI TLH42930A
1001
20:00 21:00
37 EI* Voltage SIR 70S
22:00
23:00
.OEO
Time
19:52
21:0
21:00
INJ. TIME = 08:52
21; 12
22:13
22:00
18:00
19:00
20:00
22:00
23 : 00
242
-------
File:S975670 §1-367 Acq: 5-S3SP-97 08:49:37 EI* Voltage SIR 70S Noise: 56
319.8965 F:2 BSUB{256,30, -3.0} PKD(7, 5 , 3, 0.05%,224.0,1.00%, F,T} Exp-.EPCOS
TRIANGLE LASS
1003
Text :RBl TLI442930A
INJ. TIME
08:52
A4. 77E3
A4.44E3
A1.08E3
A2.38
I A4fE3A3.44E3
-------
File:S975670 #1-867 Acq:5-SEP-97 08:49.-37 EI+ Voltage SIR 70S Noiae:67
339.8597 F:2 BSVB( 256 , 30,-3 .0 ) PKD(7, 5 , 3 , 0. 05%,268. 0 , 1. 00%, F, T) Exp-.EPCUS
TRIANGLE LABS Text:RBI TLI04293OA INJ. TIME - 08:52
100%
80J
601
401
201
23:00 24:00 25-00 26:00
File :S9 75670 01-867 Acq:5-SEP-97 08:49:37 EI* Voltage SIR 70S Noise: 65
341.8567 F-.2 BSUB(256 , 30, -3\0) PKD(7, 5, 3 , 0.05%, 260 . 0,1. 00%,F, T) Exp:EPCUS
TRIANGLE LABS Text:RBI TLI04293OA INJ. TIME = 08:52
100%
A8.70E3 A 8.01E3
A3.39E3
A6.78E3
k i" ~ A7.45E3 AS.89E3
27:00
1.6E4
1.3E4
9. 7E3
6.5E3
3.2E3
O.OEO
Time
1.5E4
1.2E4
9.0E3
A9.68E3
A8.90E3
A1.43E4
A7.39E3
6.0E3
AS.62E3
Al.03E
14E4
3.0E3
A2. 7
A6.00E3
23:00 24:00 25:00 26:00
File:S975670 #1-867 Acq-.5-SEP-97 08:49:37 EI+ Voltage SIR 70S Noise: 74
351.9000 F:2 BSTJB( 256, 30,-3. 0) PKD(7, 5,3, 0. 05%, 296. 0,1. 00%, F, T) Exp-.EPCUS
TRIANGLE LABS Text:RBI TLI04293OA INJ. TIME = 08:52
27:00
1001
801
601
401
204
A4.
33E6
A4.14E6
±
JL O.OEO
Time
.1. 4E6
'.1.1E6
.8.3E5
¦-5.6E5
'-2.8E5
23:00 24:00 25:00 26:00
File:S975670 01-867 Acq: 5-SEP-97 08:49:37 EI* Voltage SIM 70S Noise: 62
353.8970 F:2 BSUB(256,30,-3. 0) PKD( 7, 5,3, 0. 0S%,248. 0,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:RBI TLI04293OA INJ. TIME =
27:00
08:52
1001
SOJ
60J
40\
201
0J_
A2.68E6
n
A2.43E6
L
1
1,
23:00 24:00 25:00
File: S975670 01-867 Acq-.5-SEP-97 08:49:37 EI+ Voltage SIR 70S
330.9792 F:2 Exp-.EPCUS
TRIANGLE LABS Text-.RBI TLI04293OA INJ. TIME =
100% 25,-22
sol
60.
40'
20.
26: 00
27: 00
08:52
23:19 23:37 23:53
24:17
23:00 24:00 25:00
File: S975670 #1-867 Acq:5-SEP-97 08:49:37 EI* Voltage SIR 70S
409.7974 F:2 Exp: EPCUS
26:00
TRIANGLE LABS
100:
Text: RBI TLI*42930A
23:44
INJ. TIME = 08:52
23:00
24:00
25:00
26:00
.O.OEO
Time
.8.1E5
.6.5E5
.4.9E5
.3.3E5
11. 6E5
.O.OEO
Time
1.4E7
1.1E7
26:15
25:42 26:02 ^ 26:32
26:56
24:56 25:1
8.2E6
5.5E6
2. 7E6
27:00
.O.OEO
Time
8.7E3
7.0E3
25:23
5.2E3
25:42
24:19
3.5E3
26:10
24:09
26:57
1.7E3
O.OEO
27:00
244
-------
File:S975670 *1-86/ Acq:5-SEP-97 08:49:37 EI* Voltage: SIS 70S NoxseibJ
355.8546 F:2 BSUB(256, 30, -3.0 ) PKD(7, 5,3,0.05 \, 248.0,1.00 \, F,T! ExptEPCDS
TRIANGLE LABS Text:SB 1 TLI04293OA INJ. TIME - 08:52
1003,
A1.08E4
A3.98E3
A3.93E3
A5.4SE3
25:00 26:00
Files S975670 01-867 Acq:S-SEP-97 08:49:37 El* Voltage SIS 70S Noise:59
357. 8516 T:2 BSTTB(256, 30, -3.0 ) PKD( 7, 5, 3, 0. 05%, 236. 0,1. 00\,F, T) Exp:EPCUS
TRIANGLE LABS
100%
5.6E3
4.4E3
A6.43E3
13. 3E3
A3.15E3
A8.82E3
2.2E3
4.26E3
A2.97E3
A4.68E3
A3.19BI
1.1E3
Text:SBl TLI$42930A
INJ. TIME
08:52
402
20.
A6.36E3
¦a »f"*» i ii
A4.59E3
A4.X1E3
A,^V=^e.«
| A3.41E3
\rVuw V\—/Vfr—A
A5.95E3
O.OEO
00 Time
2.5E4
.2.0E4
.1. 5E4
.1.0E4
.5. 0E3
-A wA-
25:00 26:00
File:S97S670 *1-867 Acq:5-SEP-97 08:49:37 EI* Voltage SIS 70S Noise: 59
367.8949 F:2 BSUB(256,30, -3.0) PKD( 7, 5,3 , 0.05%, 236.0, 1.00%, F,T) Exp:EPCUS
TRIANGLE LABS Text:SBl 72,104293OA INJ. TIME = 08:52
1003,
80_
60.
40:
20.
A-~a\A/y-
.O.OEO
2.29E5
27:00 Time
9.1E5
7.3E5
5.5E5
3. 6E5
11. 8E 5
.O.OEO
25:00 26:00
rile:S975670 01-867 Acq:5-SEP-97 08:49:37 EI* Voltage SIS 70S Noise: 67
369.8919 F:2 BSUB(256, 30,-3. 0) PKD(7, 5,3,0.05%,268.0,1.00\,F,T) Exp-.EPCUS
TRIANGLE LABS Text-.SBl TLI04293OA INJ. TIME = 08:52
100$
80.
60.
40.
20.
A1.66E6
hi.86E5
XA
25:00 26:00
File:S975670 01-867 Acq: 5-SEP-97 08:49:37 EI* Voltage SIB 70S
330.9792 F:2 Exp-.EPCUS
TRIANGLE LABS Text:RBI TLI04293OA INJ. TIME
1003, 25122
80.
60.
40.
20.
0.
27:00 Time
5.1E5
14.1E5
13.1ES
12.1E5
1.0E5
LO.OEO
08:52
26:15
25:12
24:17
27:00 Time
.1. 4E7
.1.1E7
18.2E6
15.SE6
-2.7E6
26:56
25:00
.O.OEO
26:00
27:00 Time
245
-------
File:S975670 #1-425 Acq:5-SEP-97 08:49:37 EI+ Voltage SIR 70S Noise:56
373.3208 F:3 BSUB( 256, 30, -3 .0 ) PKD(7, 5 , 3 , 0 . 05%, 224 . 0 , 1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:RBI TLI04293OA INT. TIME = 08:52
1003,
80.
60.
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
File:S975670 #1-425 Acq:5-SEP-97 08:49:37 EI+ Voltage SIR 70S Noise:53
375.8178 F: 3 BSUB( 256 , 30, -3~.0 ) PKD( 7, 5, 3, 0. 05%, 212. 0, 1. 00%, F, T) Exp-.EPCUS
TRIANGLE LABS Text:RBl TLI04293OA INS. TIME = 08:52
27
File
383.8639 F:3 BSUB( 256 , 30, -3 . 0 ) P1CD(7, 5,3,0.05%,984.0,1.00%,F,T) Exp:EPCUS
401
201
01
A9.64E3
-r-r
4
A6. 72E3
A1.09E4 A5.33E3
A8.79E3
_6.1E4
4.9E4
-3.7E4
¦-2.4E4
-1.2E4
T
"inW it1? ifoo-i-fp
O.OEO
Time
1003
801
601
40.
20.
2.0E5
il.6E5
il.2E5
-7.9E4
¦.4.0E4
' 11 i T'i i '*i '' 1 i*1 i 1 <¦*' i ' 11*11 ' 1 i * ¦ 11'n| i i i' ¦ 1 f1 1 ''1 1 f1 |,ri i r1 1,1 111 i
24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
S975670 #1-425 Acq:5-SEP-97 08:49:37 EI+ Voltage SIR 70S Noise.246
O.OEO
Time
TRIANGLE LABS
1003,
80.
Text: RBI TLI#42930A
60.
401
201
IN J. TIME =
A2.63E6
08:52
A2.21E6
9. 7E5
L 7. 8E5
-.5.8E5
'.3.9E5
L 1.9E5
27:24 27':36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
File:S975670 #1-425 Acq:5-SEP-97 08:49:37 EI + Voltage SIR 70S Noiae:598
385.8610 F:3 BSUB(256, 30, -3 . 0) PKD( 7, 5, 3, 0. 05%, 2392. 0, 1. 00%, F, T) Exp:EPCUS
.O.OEO
30:24 Time
TRIANGLE LABS
1003,
801
Text :RB1 TLI#42930A
601
401
201
01
A5.29E6
A5.
~r
~r
time =
08:52
A4.18E6
T"
2.0E6
1.6E6
-.1.2E6
L8.0E5
14. 0E5
y
O.OEO
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
File: S975670 #1-425 Acq: 5-SEP-97 08:49:37 EI+ Voltage SIR 70S
392.9760 F:3 Exp:EPCDS
TRIANGLE LABS Text:RB1 TLI#42930A INT. TIME = 08:52
Time
1003
_6.5r6
29: 57
27:57
29:38
29:13
28:5129:01
28:21
8:08
5.2E6
3. 9E6
2.6E6
_1. 3E6
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
File:S975670 #1-425 Acq:5-SEP-97 08:49:37 EI+ Voltage SIR 70S
445.7555 F:3 Exp:EPCUS
TRIANGLE LABS
1003,
801
Text: RBI TLI#42930A
INS. TIME =
08:52
601
401
201
29:07
28:32
29:51
29:33
30:05
29:21
O.OEO
30:24 Time
r-1 ¦ 7E4
1.4E4
.1. 0E4
7.0E3
.3. 5E3
O.OEO
27:24 27:36 ' 27:48 28:00 ' '28:12' 20- 24 28:36 ' '28:48 ' 29:00 ' 29:12 29': 24 29:36' 29:48 30:00 30:12' 30:24 Time
2 46
-------
File:s975S70 #1-435 Acq>5-sl&"97 08:49:3? EI* Voltage SIR" 70s Noise:50
389.8156 F:3 BSUB(256,30, -3.0) PXD( 7,5,3,0. 05%, 200,0,1.00%,F,T) Exp-.EPCUS
TRIANGLE LABS Text:SBl TLI*42930A HOT. TIME = 08:52
100%
7.6E3
A1.13E4
6.1E3
4.6E3
A9.16E3
A3.82E3
A4.95E3
3.0E3
A3.14E3
A3.21E3
. 52E3
821.
A4.02E3
1.5E3
28:00 28:12 28,24 28:36 28:48 29:00 29:12 29:24 29:36
nie:S975670 #1-425 Acq:5-SEP-97 08.-49:37 EI* Voltage SIS 70S Noise: 58
391.8127 F:3 BSUB(256,30, -3.0) PKD(7 , 5,3,0.05%, 232.0,1.00%,F, T) Exp-.EPCUS
TRIANGLE LABS Text:XBl TLI#42930A IM7. TIME = 08:52
100%
29:48
30:00
O.OEO
Time
28:00 28:12 28:24 28:3S 28:48 29:00 29:12 29:24 29:36 29:48
File:S975670 #1-425 Acq:5-SEP-97 08:49:37 EI* Voltage SIS 70S Noise: 73
401.8558 F:3 BSUB( 255, 30, -3. 0 ) PKD( 7,5,3,0.05%, 292.0,1.00%, F, T) Exp-.EPCUS
TRIANGLE LABS Text:RBI TLH42930A INJ. TIME = 08:52
1001
6.2E3
A5.57E3
A6.55E3
5.0E3
A7.17E3
A2.93E3
AB.99E3
3. 7E3
2.5E3
74E3 A5. 02
A1.9IE
A2.42E3
1.2E3
O.OEO
30:00
80:
60.
401
20.
A3.67E6
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36
File:S975670 #1-425 Acq:5-SEP-97 08:49:37 El* Voltage SIR 70S Noise:53
403.8529 F:3 BSUB( 256, 30, -3 .0 ) PKD(7, 5 , 3 , 0. 05%, 212. 0 , 1. 00%,F, T) Exp:EPCUS
TRIANGLE LABS Text:SBl TLI*42930A INJ. TIME « 08:52
29:48
30: 00
1003k
so:
60:
40.
20.
A4.11E6
A3.10E6
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24
File:S975670 *1-425 Acq:S-SEP-97 08:49:37 EI* Voltage SIR 70S
392.9760 F:3 Exp-.EPCUS
TRIANGLE LABS Text:RBI TLI04293OA INJ. TIME
lOOSi 29:26
I T | T I
28:24
i i |—r-r
28:36
28:48
""'Ml I ' i
29:00
29:36
29:48 30:00
08:52
29:5 7
29:13
29:38
29:50
28:432S:J1
28:08
28:21
SOJ
40J
20j
28:00
I [ T T
28:12
.1. 8E6
.1.5E6
.1.1E6
.7.3ES
.3.7E5
.0.0E0
Time
.1.5E6
.1.2E6
.9.1ES
.6.1ES
.3. 0E5
.0.0E0
Time
.6.5E6
.S.2E6
-3.9E6
.2.6E6
-1.3E6
28:24
28:36
28:48
29:00 29:12
29:24
29:36 29:48
30:00
.0.0E0
Time
247
-------
File: S975670 *1-390 Acq:5-SEP-97 08:49:37 EI+ Voltage SIX 70S Hoiae:76
407. 7818 F:4 BSOB(256, 30, -3.0) PKD( 7, 5, 3, 0. 05%, 304 . 0, 1. 00%,F, T) Exp:EPCUS
TRIANGLE LABS Text-.RBl TLI04293OA INJ. TIME = 08:52
1004 A1.48E4
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
File:S975670 #1-390 Acq: 5-SEP-97 08:49:37 EI+ Voltage SIR 70S Hoiae:57
409.7789 F: 4 BSOB( 256, 30, - 3~. 0) PKD( 7 , 5 , 3, 0. 05%, 228. 0 , 1. 00%,F, T) Exp:EPCUS
TRIANGLE LABS Text:RBl TLI04293OA INJ. TIME = 08:52
1001
7.9E3
6.4E3
A1.23E4
A5. 09E3
4.8E3
A2.00E4
A5.52E3
3.2E3
1.6E3
32:48
Z.O.OEO
33:00 Time
7. 1E3
A8.08E3
5.6E3
A1.34E4
4.2E3
A4.38E3
A3.23E3
2. 8E3
A4.24E3
A7.20E3
A4 . 05E3
1.4E3
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
File:S975670 01-390 Acq:5-SEP-97 08:49:37 EI+ Voltage SIR 70S Hoise:666
417.8253 F:4 BSUB( 256 , 30 , -3 . 0 ) PKD( 7, 5 , 3 , 0. 05%, 2664 . 0,1. 00%, F, T) Ezp:EPCUS
TRIANGLE LABS Text:RBI TLI442930A INJ. TIME = 08:52
32:48
.O.OEO
33:00 Time
1004
80l
60.
40.
20.
A1.S9E6
~r
A1.11E6
T
rr
5.8E5
6E5
3.5E5
c.
2.3E5
C.1 • 2E5
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
File:S975670 #1-390 Acq:5-SEP-97 08:49:37 EI+ Voltage SIR 70S tfoise:56
419.8220 F:4 BSUB( 256 , 30 ,-3 . 0 ) PKD(7, 5 , 3 , 0. 05%, 224 . 0 , 1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:RBl TLI#42930A INJ. TIME = 08:52
1004
32:48
LO.OEO
33:00 Time
80J.
6ol
401
20l
A2.84E6
31:12 31:24 31:36 31:48 32:00 32:12
File: S975670 #1-390 Acq:5-SEP-97 08:49:37 EI* Voltage SIR 70S
430.9729 F:4 Exp: EPCUS
32:24
1.4E6
1.1E6
8.3E5
Z5.5E5
.2. 8E5
TRIANGLE LABS Text:RBl TLH42930A
1004
INJ. TIME =
32:36
08:52
32:48
.0.0E0
33:00 Time
32:01
5.1E6
4.1E6
3.1E6
2.1E6
1.0E6
31:12 31:24 31:36 31:48 32:00 32:12 32:24
File: S975670 #1-390 Acq:5-SEP-97 08:49:37 EI+ Voltage SIR 70S
479.7165 F:4 Exp:EPCUS
32:36
32:48
TRIANGLE LABS
1004
801
60l
401
20.
Text: RBI TLI#42930A
INJ. TIME =
08:52
32:37
32:46
31:47
31:28
32:13
32:56
.O.OEO
33:00 Time
_1. 3E4
1.0E4
7. 7E3
.5. 1E3
12.6E3
31:12
3 ll: 2 4
31: 36
31:48
' I '
32:00
32:12
32':24
32:36
-i—|—i—i—i—i—i—|
32:48 33,
O.OEO
00 Time
248
-------
File: S975670 91-390 Acq:$-4£p-#7 03:45:37 EH- Voltage six 704 Noise:56
423.7766 F:4 BSUB(2S6,30,-3.0} PXD( 7, 5,3, 0. 05%, 224. 0,1. 00\,F, T) Exp:EPCUS
TRIANGLE LASS Text:RBI TZI042S3OA XWT. TIME = 08:52
lOOi
A1.S4E4
7.0E3
5.6E3
4.2E3
A3.32E3
A1.69E3
2. BE3
A9.07E3
A4.83E3
1W69B
A7.24E
A2.64
1.4E3
31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18
File:S975670 #1-390 Acq:5-SEP-97 08:49:37 SI* Voltage SIR 70S Noise:63
425.7737 T:4 BSUB(2S6, 30, -3.0) PKD( 7, 5,3,0.05%, 252. Q, 1. 00%,F,T) Exp-.EPCVS
32:24
'! l t i' r*
32:30 32:36
TRIANGLE LABS
lOOi
Text:: RSI TLX#42930A
1NJ-. TIME
08:52
31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24
File:S975670 #1-390 Acq:5-SEP-97 08:49:37 EH- Voltage SIR 70S Noise:446
435.8169 F:4 BSUS(256 , 30,-3 . 0) PKD(7, 5,3 , 0. 05%, 1784. 0,1. 00%,F,T) Exp-.EPCVS
TRIANGLE LABS Text:RBI TLI#42930A INJ. TIME = 08:52
lOOi
80.
60S
40.
20.
If—T-
32:18
31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12
File:S975670 #1-390 Acq:5-SEP-97 08:49:37 EX* Voltage SIR 70S Noise:69
437.8140 F:4 BSUB( 256, 30,-3.0 ) PKD(7, 5, 3, 0.05%, 276.0 ,1. 00%,F,T) Exp:EPCUS
TRIANGLE LABS Text:SSl TLX#4293 OA IKT. TIME = 08:52
100%
801
60.
40.
201
0.
A2.63E6
31:30 31:36 ' '31:42 ' 31:48 ' 31:54 ' '32:66 ' '32I06 ' '32:12 ? 32-ifJ ' '32:24 ' '32:30 ' 32:36
32:18
31s 47
32:07
31:31 31:36
File-. S975670 41-390 Acq:5-SEP-97 08:49:37 EX* Voltage SIS 70S
430.9729 F:4 ExpsEPCVS
TRIANGLE LASS Text-.RBl TLX#4293OA INJ. TIME
100^ 32i01
11.^7
801
60.
401
20.
0.
08:52
32:31 32:36
'.0.0E0
Time
6.6E3
A1.27E4
5.3E3
H6.13E3
4. 0E3
A1.41E4
A4.31E3
1.02E4
2.6E3
A1.95E3
1.3E3
32:30 32:36
-1.1E6
32:24 32:30 32:36
9.0E5
6. 7E5
4.5E5
2.2E5
O.OEO
.9. 7E5
.7.7E5
15.8E5
.3.9E5
11. 9E5
_0.0E0
Time
5.1E6
14.1E6
3.1E6
2.1E6
-1.0E6
O.OEO
'31:30 ' '31:36 ' '31:42 ' '31:48 ' '31:54 ' '32:66 ' '32:06 ' 32:ii ' 32:18 ' 32:24 ' 32:30 ' 32:36 Time
249
-------
file :S9 755 70 #1-390 Acq: S-SEP-97 08:49:37 EI* Voltage SIS 70S Noise: 236
441.7428 F:4 BSUB(2S5, 30, -3.0} PKD(7, 5,3,0.05%, 944. 0,1, 00%,F,T) Exp-.EPCUS
TRIANGLE LABS TextiMBl TLI*42930A INJ. TIME - 08:52
1004
2.4E4
2.1E4
1.9E4
1.7E4
1.4E4
A1.53E4
1.2E4
A1. 71E4
A7.4HE3I A6.50E3
9.5E3
A1.85E4
7.1E3
A1.94E4
~ t I A M *¦!!» # 5
-------
File:6575670 41-390"Acq: S-sep-97 0i:49:37 M* voltage SIR 7Qs mxseTYS"
457.7377 F:4 BSUB(256,30, -3.0) PKD( 7, 5,3,0.05%, 236.0,1. 00%, F, T) Exp:EPCOS
TRIANGLE LABS
1003
so:
SOJ
TZI*42930A
INJ. TIME
40:
201
\
Text: RBI
A1.32E3
OB: 52
A1.63E4
A2.38E3
35:00
34:30 34:36 34:42 34:48 34:54
File: S9 756 70 #1-390 Acq:5-SEP-97 08:49:37 EI+ Voltage SIS 70S Noise: 58
459.7348 F:4 BSOB( 256, 30, -3.0 ) PKD( 7, 5 , 3, 0. 05%, 232. 0 ,1. 00%,F, T) Exp:EPCUS
TRIANGLE LABS Text:RBl TLI04293OA INJ". TIME = 08:52
100% A2.95E4
34:30 34:36 34:42 34:48 34:54
File:S975670 #1-390 Acq:5-SEP-97 08:49:37 EI+ Voltage SIS 70S Noise:48
469.7779 F:4 BSUB(256,30, -3.0) PKD( 7,5,3,0.05%, 192.0,1.00%, F, T) Exp:EPCUS
TRIANGLE LABS Text: RBI TLI#42930A IN J. TIME = 08:52
100i
801
60.
40.
201
35:06
35:06
34:30 34:36 34:42 34:48 34:54 35:00
File: S9 75670 §1-390 Acq:5-SEP-97 08:49:37 EI* Voltage SIR 70S Noise: 54
471.7750 F:4 BSUB(256, 30,-3. 0) PKD(7, 5,3, 0. 05%,216. 0,1. 00%,F, T) Exp:EPCUS
TRIANGLE LABS Text:SB 1 TLI#42930A IN.7. TIME = 08:52
100%
80.
60.
40.
20:
A2.83E6
_f_l—
35:06
34:30 34:36 34:42 34:48 34:54
File:S975670 #1-390 Acq:5-SEP-97 08:49:37 Eli- Voltage SIR 70S
430.9729 F:4 Exp:EPCUS
TRIANGLE LABS Text'.RBl TLI#42930A INJ. TIME
1003
801
601
401
20:
o:_
35:00
08:52
34:30
34:36
34:42
34:48
34:54
35:06
35:00
35:06
251
-------
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Chanel I 338.9782
Height 3.25 volts Spai
Peak top
mm
Systei fill naie
mm
Data file naae
fi:S985971
Resolution
18886
Group muter
2
Ionization node
ib
Syltchuig
mm
tef. lasses 238.3825,
416.9768
» 293 J 331
S 368
8 m K 332
T 378
C 386 L 334
U 376
D 316 i m
V 418
i 318 H 342
F 321 0 352
6 322 P 354
H 328 Q 356
I 331 R 358
fef.iass 418.9768
Height .96 Melts Span
Peak top
280 m
-------
File:S975670 #1-867 Acq:5-SEP-97 08:49:37 EI+ Voltage SIR 70s"
319.8965 F:2 Exp:EPCUS
Sample Text:RBI TLI#42930A
100%,
INJ. TIME
08 : 52 File Text:RBI TLI#4293»
X 8 . 7 E3 C
6.9E3
21:52
5.2E3
20:44
20:29
23 :40
3 . 5E3
17:30
22:29
1:18
l?,? °3 18:51
19 :47
L.7E3
0.0E0
Time
t—I 1 i 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 j r 1 1—i 1 1 1 1—t—i—-i 1 1 1 tt—j 1 i 1 1 r
17:00 18:00 19:00 20:00 21:00 22:00 23:00 24!00
File:S975670 #1-867 Acq:5-SEP-97 08:49:37 EI+ Voltage SIR 70S
321.8936 F:2 Exp:EPCUS
Sample Text:RBI TLI#42930A INJ. TIME = 08:52 File Text:RBI TLI#4293»
1004, 24;18 „1.0E4
80,
60.
40j
20i
0
17:15
18:04
118:4
19:35
21:
21:14
30
22 :25
JWAvA/Aj inlu klihk
23:11
kkMilllLd
n 5 1 1 p*~i 1 1 1 r-—{ 1 1 1 1 i" ¦ i"" i 1 1—t 1 1—"i— t 1 —i 1 1 1 1 1 i 1 j— r—
17:00 18:00 19:00 20:00 21:00 22:00
File:S97 5670 #1-867 Acq:5-SEP-97 08:49:37 EI+ Voltage SIR 70S
331.9368 F:2 Exp:EPCUS
Sample Text:RBI TLI#42930A INJ. TIME =
100% 21;19
80i
60
40.
20
—j « r—i 1—i 1 1—i 1 1 1 r
23:00 24:00
8.0E3
6 . 0E3
4.0E3
2 . 0E3
to. 0E0
Time
XL
08:52 File Text:RBI TLI#4293»
.1.3E6
.1.0E6
,7 . 8E5
.5 . 2E5
.2 . 6E5
X
i **i—i—r—|—i—i—i—i—i | > 'i "i—i—i—I—i—i—i—i—i—|—i—i—i—i—i—|—< T —r=—|—i"i • t"*"i—i—i—r—i—i—i—i—-i—i •¦¦-r--1—i—r
17:00 18:00 19:00 20:00 21:00 22:00 23:00 24:00
0 . 0E0
Time
A):
•0^
ro
» en
ca
-------
File:S97 5670 #1-390 Acq:5-SEP-97 08:49:37 EI+ Voltage SIR 70S
407.7818 F:4 Exp:EPCUS
Sample Text:RBI TLI#42930A
100%
INJ. TIME
33 :04
32:31
32:49
31:48 32:09
33 :21
31:28
08:52 File Text:RBI TLI#4293»
8E3
34:11
33:31 33:50 :.7 . 0E3
5.3E3
:.3 . 5E3
1. 8E3
33 :00
34:00
0.0E0
Time
32 :00
File:S975670 #1-390 Acq:5-SEP-97 08:49:37 EI+ Voltage SIR 70S
409.7789 F:4 Exp:EPCUS
Sample Text:RBI TLI#42930A INJ. TIME = 08:52 File Text:RBI TLI#4293»
100%
31:19
32:14 33 :121
80
60j
40 J
0_
34:17
2"Jj
31:41
32:36 32:54
33 :
f|
33 :
hrJ
32:00 33:00
File:S975670 #1-390 Acq:5-SEP-97 08:49:37 EI+ Voltage SIR 70S
417.8253 F:4 Exp:EPCUS
, n
34:00
.8 . 7E3
.7.0E3
-5.2E3
.3 . 5E3
1 .7E3
0 . 0E0
Time
Sample Text:RBI TLI#42930A
100%. 31 18
80
60 j
40
20
0
INJ. TIME =
32:30
1"—
32 :00
08:52 File Text:RBI TLI#4293»
.5 . 8E5
.4 . 6E5
.3 . 5E5
.2 . 3E5
Ll.2E5
33 :00
r f r * i r " 'i
34 : 00
.0 . 0E0
Time
, fS3
CJ1
-------
File:S975670 #1-390 Acq:5-SEP-97 08:49:37 EI+ Voltage SIR 70S"
457,7377 F:4 Exp;EPCUS
Sample Text:RBI TLI#42930A
100%
INJ. TIME
34 08
08:52 File Text:RBI TLI#4293
34:32
»
35:03
35 :47
33 :55
33 :01
31:16
33 :26
32:01
32 :43
53:45
33 :00
34:00
35 :00
_1
2E4
E.9
5E3
17
1E3
L4
7E3
L2
4E3
:-0
0E0
32 :00
File:S975670 #1-390 Acq:5-SEP-97 08:49:37 EI+ Voltage SIR 70S
459.7348 F:4 Exp:EPCUS
Sample Text:RBI TLI#42930A INJ. TIME
100% 34,-03
08:52 File Text:RBI
34 :37
Time
TLI# 4 2 9 3 »
.8.1E3
.6.5E3
33 :08
35:08
4 . 9E3
35:43
35:31
3 . 2E3
32 :46
33 :4
31:55
.1.6E3
34 : 00
32 :00
33 :00
35:00
File:S975670 #1-390 Acq:5-SEP-97 08:49:37 EI+ Voltage SIR 70S
469.7779 F:4 Exp:EPCUS
Sample Text:RBl TLI#4293 0A INJ. TIME = 08:52 File Text:RBI
100% 34;37
80 J
60j
40
20
0
0.0E0
Time
TLI#4293»
.9 . 0E5
.7 . 2E5
i5.4E5
3 . 6E5
1.8E5
"¦ 1 1 '
32:00
-i 1 r— i"
33!0 0'
34 :00
"I 1 1 T"
f 1 ,
35 :00
tO.OEO
Time
to
* cn
cn
-------
I
Eastern Research Group
¦ TLI Project:
™ Client Sample:
I
42930A
RUN4
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975671
Client Project:
Iron & Steel-Youngstown
Sample Matrix:
M23TRAIN
Date Received:
08/19/97
Spike File:
SPX23704
TLI ID:
179-98-6A-D Date Extracted:
08/25/97
ICal:
SF56117
Date Analyzed:
09/05/97
ConCal:
S975664
Sample Size:
1.000
Dilution Factor:
n/a
% Moisture: n/a
Dry Weight:
n/a
Blank File:
S975665
% Lipid:
n/a
GC Column:
DB-5
Analyst:
HLM
% Solids:
n/a
| Analytes
Amt. (ng) DL
EMPC
Ratio
RT
Flags
2,3,7,8-TCDD
0.54
0.76
21:40
1,2,3,7,8-PeCDD
1.1
147
26:08
1,2,3,4,7,8-HxCDD
0.14
1.11
29:20
1,2,3,6.7,8-HxCDD
1.7
1.31
29:23
1,2,3,7,8,9-HxCDD
0.67
1.26
29:41
PR_
1,2,3.4,6.7.8-HpCDD
0.81
1.08
32:11
1.2,3,4.6,7,8.9-OCDD
EMPC
1.6
—
2,3,7,8-TCDF
43.3
0,83
20:55
1,2,3.7,8-PeCDF
4.7
1.52
25:03
2,3,4,7,8-PeCDF
4.2
1.52
25:47
1,2,3,4,7,8-HxCDF
1.7
1.20
28:35
PR_
1,2,3,6.7,8-HxCDF
0.61
1.25
28:41
2,3,4,6,7,8-HxCDF
0.32
1.30
29:11
PR_
1,2,3,7,8,9-HxCDF
0.04
1.14
29:53
1,2,3,4,6,7,8-HpCDF
0.38
0.90
31:20
1,2,3,4,7,8,9-HpCDF
ND 0.2
1,2.3.4.6,7,8.9-OCDF
0.17
0.97
34:45
j Totals
Arot (ng) Number DL
EMPC
Flags
Total TCDD
11.4 15
Total PeCDD
11.6 9
15.3
Total HxCDD
16.1 7
Total HpCDD
2.5 2
—
Total TCDF
349 14
359
Total PeCDF
70.5 16
70.8
Total HxCDF
6.9 13
Total HpCDF
0.47 2
0.66
I
I
I
I
I
I
I
I
I
I
I
Page 1 of2
X237.PSR *200, LARS
Triangle Laboratories, Inc.©
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:13 09/08/97
256
-------
TLI Project: 42930A Method 23 PCDD/PCDF Analysis (a)
Client Sample: RUN4 Analysis File: S975671
| Internal Standards
Amt (ng}
% Recovery
QC Limits
Ratio
RT
Flags
13Cn-2,3,7,8-TCDF
3.9
97.0
40%-130%
0.75
20:53
"Ci2-2,3,7,8-TCDD
3.4
85.7
40%-130%
0.82
21:39
13Ci;-l,2,3,7,8-PeCDF
2.7
67.3
40%-130%
1.73
25:02
! 3C,2-1.2,3,7,8-PeCDD
1.9
48.1
40%-130%
1.44
26:08
13Ci2-l,2,3,6,7,8-HxCDF
4.8
120
40%-130%
0.51
28:40
,3C,2-1,2,3,6.7,8-HxCDD
3.8
94.4
40%-130%
1.25
29:22
l3Ci2-1,2.3,4,6,7,8-HpCDF
2.2
56.1
25%-130%
0.41
31:19
l3Ci:-L2,3,4,6,7,8-HpCDD
2.4
59.0
25%-130%
1.01
32:09
l3C,:-1,2.3,4,6,7,8,9-OCDD
2.9
36.4
25%-130%
0.90
34:37
Surrogate Standards (Type A) :
Amt. (ng)
% Recovery
QC Limits
Ratio
RT
"CL-2,3,7,S-TCDD
4.1
103
70%-140%
21:40
l3Ci2-2,3,4,7,8-PeCDF
3.2
79.5
70%-140%
1.67
25:46
!3C,2-1,2,3,4,7,8-HxCDF
4.3
108
70%-140%
0.50
28:34
13C,2-1,2.3,4,7,8-HxCDD
4.2
104
70%-140%
1.22
29:18
»C.r 1,2,3,4,7,8,9-HpCDF
3.9
98.5
70%-140%
0.42
32:31
Alternate Standards (Type A) Amt. (ng} % Recovery QC Limits Ratio RT Flags
13C,2-1,2,3,7,8,9-HxCDF
:3Ci;-2,3,4,6,7,8-HxCDF
4.2
4.4
106
109
40%-130%
40%-130%
0.53
29:52
0.52
29:10
¦—
Ratio RT Flags
0.84
21:26
1.19
29:40
13Ci2-l,2,3,4-TCDD
13Ci2-1,2,3,7,8,9-HxCDD
Data Reviewer ^,4 Ltl^ 09/08/97
|
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713 Printed: 17:13 09/08/97 ¦
Phone: (919) 544-5729-Fax: (919) 544-5491 - |
£57
-------
Initial ....Date...
Data Review By: 3-/31/33: Calculated Noise Area: 6.31
The Totai Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
09/08/97
Listing of S975671B.dbf
Matched GC Peaks / Ratio / Ret.
Time
Compound/
M_2.... QC.Log Omit Why ..RT. OK .Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name.. ID.. Flags.
TCDF
304-306
DC NL
304-306
0 .
65-0.89
0.327-1.099
0:00
RO
1 . 34
9 .10
0 . 000
17:32
0 . 83
3,980.00
4,080.00
4,900.00
0. 340
17:59
RO
0.91
8,074.56
4,145.91
4,561.90
0.861
13:16
0.32
5,114.64
2,308.77
2,805.37
0.375
18:42
0.84
54,474.10
24,892.70
29,531.40
0. 395
19: 01
0.85
35.744.20
16,395.10
19,349.10
0.911
19:27
0.85
30,513.90
13,990.90
16,528.00
0.931
19:46
0.85
24,525.80
11,250.00
13.275.30
0.947
20:05
0.83
35,272.50
16,033.10
19.234.40
0.962
20:26
0.35
19,307.45
9,081.95
10,725.50
0. 973
20:41
0.84
13,567.98
6,190.12
7,377.36
0.990
in
in
o
CN
0.33
35,708.80
16,162.10
19,546.70
1.002 2373-TCDF
21:21
0.34
14.177.08
6,473.74
7,703.34
1. 022
21: 34
0. 84
7,650.36
3,488.62
4,161.74
1.033
21:49
0.37
1,243.99
579.38
664.61
1.045
22:09
RO
1.95
67.67
74. 33
33 . 23
1.061
22:42
0 . 30
831.93
370.59
461 . 34
1.037
Peaks
295.759.96
AN
13C12-TCDF
316-313
316-313
0.65-0.39
NL 0:00 RO 15.86 5.31
20:53 0.75 2,635.88
1 Peak 2,635.38
1,126.96
0.952-1.048
0.000
1,503.92 1.000 13C12-2378-7CDF ISO
Above: TCDF / TCDD Follows
TCDD
320-322
DC NL
A
A
0.65-0.89
0:00
RO 5.54
23 .77
13: 55
0.80
742.03
19:20
0.72
504.04
19: 38
0.77
410.29
20:24
0.78
1,376.84
20: 37
0.75
400.88
20:42
0.78
298.66
20:48
0. 82
232.58
21:06
0.33
397.43
21:24
0.83
501.17
21:32
0.80
534.77
21:40
0.76
303.67
21:49
0.84
188.72
22:00
0.30
463.31
22:14
0.81
12.10
22:42
0.81
17.17
0.361-1.053
0. 000
330.84
411.19
0.874
210.35
293.19
0. 893
177.88
232.41
0.907
604.15
772.69
0.942
171.71
229.17
0.952
131.03
167.63
0.956
104.88
127.70
0.961
179.97
217.46
0.975
227.61
273.56
0 . 988
237.39
297.38
0. 995
131.08
172.59
1.001 2378-TCDD
85.39
102.83
1.008
208.79
259.52
1 .016
5.40
6.70
1.027
7 . 69
9.48
1.048
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:14 09/08/97
258 '
-------
Page No. 2
09/03/9?
Listing of S97S67lB.db£
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log
Omit
why
. .RT.
OK
Ratio Total
.Area...
Area.Peak.1.. Area
peak.2..
Rel. RT Compound. Name. .
320-322
15
Peaks
6,388.66
37C1-TCDD
0.907-1.093
328
DC
NL
0
00
2.95
0.000
DC
WL
18
32
2.08
0.856
DC
WL
18
39
5.74
0.361
DC
WL
18
52
0.52
0.871
DC
WL
19
11
6.69
0.386
DC
WL
19
20
10.63
0.393
DC
WL
19
35
3.84
0.905
DC
SN
19
42
2.74
0.910
20
09
812.05
812.05
0.931
20
23
14.98
14.98
0.941
DC
3N
20
37
2.44
0.952
DC
SN
20
48
4.55
0.961
DC
SN
21
OS
4.54
0.975
DC
SN
21
24
3.88
0.988
21
40
1,637.04
1,637.04
1.001 37C1-TCDD
22
05
1,622.65
1,622.65
1.020
DC
SN
22
20
3.73
1.032
22
27
9.08
9.08
1.037
22
38
11.14
11. 14
1.045
22
49
19.63
19.63
1.054
23
08
23.54
23. 54
1.069
323
8
Peaks
4,150.11
13C12-TCDD
0.
65-0,39
0.907-1.093
332-334
DC
NL
0
00
RO
15.39
0.32
0.000
DC
WL
18
42
RO
2.71
1.47
0.364
DC
WL
19
18
RO
5.96
1.61
0.391
DC
SN
20
03
RO
2.38
1.72
0.926
20
24
RO
1.13
9.56
6.09
5.40
0.942
DC
SN
21
05
RO
1.97
3.13
0.974
21
26
0.84
2,060.83
943.82
1.117.01
0.990 13C12-1234-TCDD
21
39
0.82
1,881.81
850.50
1,031.31
1.000 13C12-2378-TCDD
22
00
RO
1.02
26.43
15.16
14.93
1.016
DC
SN
22
07
RO
1.01
4.43
1.022
22
33
RO
1.24
9.43
6.60
5.33
1.042
DC
SN
22
48
RO
3.61
2.11
1.053
DC
SN
23
01
RO
3.40
1.91
1.063
DC
SN
23
09
RO
1.59
4.23
1.069
332-334
5
Peaks
3,988.06
srHH-Ut rOXiOWS
PeCDF
1
32-1.78
0.
910-1.076
340-342
DC
NL
0
: 00
RO
0.22
0.30
0.000
DC
WL
22
: 43
RO
0.49
215.25
0.907
23
: 00
1.43
4,112.27
2,422.43
1,689.84
0.919
23
: 10
1.65
41.34
25.73
15.61
0.925
23
: 17
RO
0.88
32.99
20.05
22.75
0.930
23
= 44
RO
1.07
60.57
36.82
34.53
0.948
SUFI
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitoia Drive • Durham, North Carolina 27713 Printed: 17:14 09/08/97
Phone: (919) 544-5729 • Fax: (919) 544-5491 _ _ _
259
-------
Page No. 3
09/03/97
Listing of S975671B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z....
QC.Log
Omit
Why
. .RT.
OK
Ratio Total
.Area...
Area.Peak.1. . Area.Peak.2..
Rel.RT Compound.Name..
24:02
1.55
1,319.17
1,106.74 712.43
0. 960
24: 10
1.51
9,311.49
5.907.70 3,903.79
0.965
24: 21
1. 49
1,344.15
1,104.33 739.32
0.973
A
24: 36
1 .43
678.00
399.00 279.00
0. 983
24: 50
1.49
2,796.34
1.673.27 1,123.07
0. 992
A
24: 57
1. 51
901.00
542.00 359.00
0 . 997
M
25: 03
. 1. 52
2,055.00
1.240.00 315.00
1.001 12378-PeCDF
25: 12
1.52
1,269.33
765.55 503.78
1 . 007
25:20
1 . 52
1,317.25
1,095.83 721.42
1. 012
25:47
1. 52
1,360.12
1,121.98 738.14
1.030 23478-PeCDF
25: 55
1. 51
1,514.11
911.12 602.99
1. 035
26:08
1. 57
16.33
9.98 6.35
1.044
26: 13
1.38
130.41
75.68 54.73
1 . 047
26: 35
RO
0.63
9.02
5.48 3.70
1.062
26: 44
1.41
153.51
89.94 63.57
1. 068
340-342
19
Peaks
30,922.40
13C12-PeCDF
1 .
32-1.78
o.;
340-1.160
352-354
DC
NL
0: 00
RO
0 . 36
0.30
0 . 000
DC
SN
22:46
RO
3 . 39
1.81
0 . 909
DC
SN
23:00
RO
1.79
5.13
0. 919
DC
SN
23:46
RO
3.43
4.69
0.949
DC
3N
24:43
RO
1.14
7.96
0 . 987
25: 02
1.73
1,570.21
994.20 576.01
1.000 13C12-PeCDF 123
25:23
RO
3 .01
24.45
28.83 9.59
1 .014
DC
SN
25: 36
RO
2.79
10 . 02
1.023
25:46
1.67
1.210.36
756.54 453.32
1.029 13C12-PeCDF 234
DC
SN
26:04
1 . 53
3.02
1. 041
DC
SN
26: 12
RO
0. 61
2.35
1 . 047
DC
SN
26: 22
RO
0.77
1.18
1 . 053
DC
SN
26:44
RO
0.95
6.42
1. 068
DC
SN
27:06
RO
0.90
3 . 55
1.033
3 52-354
3
Peaks
2,305.02
Above
DarfiT? /
rcL, jjr /
rei^uu POilows —————————————
PeCDD
\ (
.32-1.73
0.'
923-1.025
356-353
DC
NL
0: 00
RO
1. 81
3.57
0.000
24:19
RO
1.05
694.72
422.28 401.93
0.930
24: 51
1.49
120.34
72.07 48.27
0.951
25: 02
1.60
694.76
427.27 267.49
0. 958
25:10
1.56
287.71
175.43 112.28
0.963
25: 21
1.48
277.70
165.78 111.92
0.970
M
25:36
1.52
419.00
253.00 166.00
0.980
25:49
1. 34
56.91
32.57 24.34
0. 983
25: 57
RO
0.27
31.26
19.00 71.13
0. 993
26: 08
1 .47
223.06
132.68 90.38
1.000 12378-PeCDD
26: 16
1.58
100.98
61.88 39.10
1.005
DC
SN
26: 29
RO
1.07
7.01
1.013
26: 38
1.53
114.95
69.51 45.44
1.019
DC
SN
26:47
RO
4. 37
0.69
1.025
DC
WH
26: 59
RO
3 . 32
2.07
1.033
AN
IS2
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713 Printed: 17:14 09/08/97
Phone: (919) 544-5729 • Fax: (919) 544-5491 2 6 0 '
-------
Page So, 4
09/03/97
Listing of S97567iB.dbf
Matched GC Peaks / Ratio / Ret, Time
Compound/
M_Z... . QC.Log Omit Why ..RT, OK Ratio Total.Area... Area.Peak.1,, Area.Peak.2.. Rel.RT Compound.Name., ID.. Flags.
356-353
11 Peaks
3,021.39
13C12-PeCDD
368-370
368-370
1. 32-1.78
0.347-1.153
DC
NL
0:00
RO
1.07
0.26
0. 000
DC
SN
25:07
RO
1.07
2.63
0.961
DC
SN
25:18
RO
3.63
1.66
0.963
DC
SN
25:34
RO .
.0.63
3.14
0. 973
DC
SN
25:39
1.42
2.73
0.982
26:08
1 .44
629.37
371.76
257.61
1.000
26:15
1.41
66.91
39.15
27 .76
1.004
DC
SN
26:25
1.71
4.98
1.011
DC
SN
2
26:47
Peaks
RO
1.10
3.65
696.28
1.025
13C12-PeCDD 123 IS3
Above: PeCDD / HxCDF Follows
HxCDF
374-376
DC NL
A
M
K
374-376
13C12-HXCDF
334-386
334-336
HxCDD
390-392
DC SN
DC
DC
DC
DC
SN
13
NL
SN
SN
DC SN
DC SN
DC
DC
NL
SN
1.
05-1.43
0
00
1.09
5.67
27
36
1.23
177.63
27
45
1.25
650.64
27
54
1.13
47.68
28
02
1.31
66.44
28
12
1. 39
87.59
28
22
RO
13.15
0.58
28
3S
1.20
441.13
28
41
1.25
208.80
28
47
1.42
29.76
28
59
1. 34
64.78
29
08
1.39
24.16
29
11
1.30
37.70
29
53
1.14
8.88
29
56
1.24
26.98
30
04
RO
1.63
0.92
Peaks
1,922.22
0
43-0.59
0
00
RO
0.92
3.53
27
44
RO
1.47
0.88
28
03
RO
3 .68
0.71
28
34
0.50
898.43
28
40
0.51
867.15
29
10
0.52
729.94
29
44
RO
0.26
2.46
29
52
0. 53
617.46
30
15
0. 55
1.02
Peaks
3,112.98
HxCDF /
1
05-1.43
0
: 00
RO
1.04
2.58
27
: 57
RO
0.98
4.50
0.957-1.051
98.01
360.94
25. 33
37.70
50.98
240.69
116.10
17.46
37.06
14.06
49.60
4.74
14. 93
299.63
291.08
248.58
213.30
HxCDD Follows
0. 000
79.62
0.963
289.70
0.968
22. 35
0.973
28.74
0.978
36.51
0. 984
0.990
200.49
0.997
123478-HxCDF
AN
92.70
1. 001
123678-HxCDF
AN
12.20
1.004
27.72
1.011
10.10
1.016
38.10
1. 018
234678-HXCDF
AN
4.14
1.042
123789-HXCDF
AN
12.05
1.044
1.049
PR
PR
0.860-1.140
0.000
0.967
0. 978
598.80 0.997 13C12-HxCDF 478 SUR3
576.07 1.000 13C12-HXCDF 678 IS4
481.36 1.017 13C12-HXCDF 234 AL72
1.037
404.16 1.042 13C12-HxCDF 789 ALT1
1.055
0.952-1.015
0.000
0.952
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive ~ Durham, North Carolina 27713 Printed: 17:14 09/08/97
Phone: (919) 544-5729 • Fax: (919) 544-5491 261
-------
Page No. 5
09/03/97
Listing ot S97567lB.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log
Omit
Why
. .RT.
OK
Ratio Total
.Area...
Area.Peak.1.. Area.
.Peak.2..
Rel.RT Compound.Name..
ID. .
28:08
1.23
413.56
230.60
137.96
0.958
DC
SN
28:15
RO
2 .00
1.01
0.962
28: 35
1 .25
115.41
64.14
51.27
0.973
28:47
1 .21
1,465.70
802.71
662.99
0.980
28: 56
1 .12
35.69
18. 88
16.31
0. 985
DC
SN
29: 04
RO
0. 36
0.98
0 . 990
DC
SN
29 : 13
.1.23
0.96
0.995
AN
29:20
1 .11
19.39
10.20
9.19
0.999 123478-HxCDD
AN
M
29:23
1 .31
272.00
154.00
118.00
1.001 123 67 3-HxCDD
AN
DC
SN
29:29
RO
1 .65
3.16
1 . 004
29:41
1 .26
103.39
57. 66
45.73
1.011 123789-HxCDD
AN
DC
WH
30: 08
RO
1 . 59
3.11
1.026
390-392
7
Peaks
2,430.14
13C12-HXCDD
1 .
05-1.43
0 . '
966-1.034
402-404
DC
NL
0: 00
RO
0.27
1.14
0 . 000
DC
WL
27:59
RO
0 . 57
1.12
0.953
DC
WL
28:09
RO
1 . 50
1.25
0.959
DC
SN
28: 38
RO
0.13
0.56
0.97 5
DC
SN
28:47
RO
2.53
2.55
0 . 930
DC
SN
28:57
RO
0.71
1.93
0.986
DC
SN
29:05
RO
3 .22
1.10
0.990
29: 18
1 .22
570.67
314.05
256.52
0.993 13C12-HXCDD 478
SUR4
29:22
1.25
565.10
314.08
251.02
1.000 13C12-HxCDD 673
TS5
29:40
1 . 19
601.44
327.02
274.42
1.010 13C12-HxCDD 739
RS2
DC
SN
29:58
1 .34
1.73
1 . 020
DC
SN
30: 05
RO
0.56
2.06
1.024
402-404
3
Peaks
1,737.21
Above
Ur-ifTlT? !?/¦>, 1 1 _ „
nxLuu i
npL fr roiiows
HpCD?
0.
.88-1.20
0.
995-1.044
408-410
DC
NL
0: 00
RO
13.08
0.24
0.000
M
31:20
0.90
44.30
21.00
23.30
1.001 1234673-HpCDF
AN
K
31:32
1 .10
8.59
4. 50
4.09
1.007
31:41
RO
1.54
19.52
14.70
9.57
1.012
DC
SN
31: 59
RO
4 . 16
0.63
1.021
DC
SN
32:16
RO
4.45
1.04
1.030
DC
SN
32: 33
RO
0 . 74
6.41
1.039
DC
WH
32: 59
RO
1 .47
2.59
1.053
DC
WH
33:03
RO
0. 65
1.04
1.055
408-410
3
Peaks
72.41
13C12-HpCDF
0.
37-0.51
0.
936-1.128
413-420
DC
NL
0: 00
RO
9.54
0.16
0.000
31:19
0.41
299.25
87.36
211.39
1.000 13C12-HpCDF 678
IS6
DC
SN
31:31
RO
1.25
2.94
1.006
DC
SN
32:03
RO
0.61
1.83
1.023
DC
SN
32: 18
RO
0.13
0 .46
1.031
32: 31
0.42
227.31
67.22
160.09
1.038 13C12-HpCDF 789
SUR5
DC
SN
32:56
RO
0. 92
2.35
1.052
413-420
2
Peaks
526.56
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713 Printed: 17:14 09/08/97
Phone: (919) 544-5729 • Fax: (919) 544-5491 _
262
-------
Page No. 6
09/03/97
Listing of S97S671B.dbf
Hatched GC Peaks / Ratio / Ret. Time
Confound/
QC.Log Omit "Why ..RT. OK Ratio Total, Area.. . Area. Peak. 1. . Area. Peak. 2. . Rel.RT Compound. Name. . ID.. Flags.
Above: HpCDF / HpCDD Follows
HpCDD
424-425
424-426
0.88-1.20
DC E 0:00 RO 5.58 0.24
31:35 0.95 132.09
32:11 1.08 62.35
DC WH 32:21 SO . 0,60 0.32
DC WH 32:30 RO 2.43 1.51
2 Peaks 194.94
64.51
32. S3
0.977-1.006
0.000
67.58 0.982
30.22 1.001 1234678-HpCDD
1. 006
1.011
AN
13C12-HpCDD
436-438
436-438
0.88-1.20
DC
DC
NIi
SN
DC SN
00
53 RO
09
34 RO
1.17
0.30
1.01
2.43
1 Peak
0.26
0.27
239.43
0.82
289.43
145.39
0.969-1.031
0.000
0.992
144.04 1.000 13C12-HpCDD 673 IS7
1.013
Above: HpCDD i Octa-CDD and CDF Follows
OCDF
0.
76-1.02
0. 384-1.116
442-444
DC
NL
0:00
RO
1.09
0.21
0.000
DC
SN
31 : 14
RO
0.26
0.32
0. 902
DC
SN
31:39
RO
1.21
1.25
0. 914
DC
SN
31:50
0,96
0.51
0. 920
DC
SN
31:56
RO
2.16
1 . 51
0. 922
DC
SN
32:13
RO
0.16
0.64
0.931
DC
SN
32:41
RO
0. 65
0.96
0.944
DC
SN
32:52
0.34
0.81
0.949
DC
SN
33:01
SO
0.30
0.74
0.954
DC
SN
33:53
0.90
1.58
0.979
DC
SN
34:14
RO
0. 53
0.87
0.939
DC
SN
34:26
RO
2.89
1.78
0.995
K
34:45
0.97
7.33
3.60
3.73 1.004 OCDF
DC
SN
35:05
RO
0.58
1.66
1.013
DC
SN
35:25
RO
3.06
1.17
1. 023
442-444
1
Peak
7.33
OCDD
0
76-1.02
0.834-1.116
458-460
DC
NL
0:00
0.92
0.25
0.000
34:38
RO
0.73
50.46
23.76
32.59 1.000 OCDD
458-460
1
Peak
50.46
13C12-OCDD
0
76-1.02
0.996-1.006
470-472
DC
NL
0:00
0.33
0.22
0.000
34: 37
0.90
227.30
107.64
119.66 1.000 13Ci;
DC
WH
34:53
RO
0.41
0.93
1.008
DC
WH
34:59
RO
3.42
1.17
1. 011
470-472
1
Peak
227.30
AN
AN
I S3
Triangle Laboratories, inc.© Analytical Services Division
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:14 09/08/97
263'
-------
Page No. 7 Listing of S975671B.dbf
09/08/97 Matched GC Peaks I Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name., ID,. Flags.
Column Description "Why" Code Description.
QC Log Desc.
M_Z -Nominal Ion Mass(es)
. .RT. -Retention Time lmm:ss)
Rat.l -Ratio of M/M+2 Ions
OK -R0=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
File:S975671 #1-867 Acq:5-SEP-97 09:28:57 EI*- Voltage SIS 70S Noise: 4 738
303.9016 F:2 BSUB(2 5 6,30, -3.0} PKD(9,S,S,
TRIANGLE LABS Text:RON 4 TLZ442930A
100S
sod
601
'I1"""''"—I r~^ 1 1 T r—I f—fc] 1 V* I ""1 1 •»-»-+—¦' 'f 1
18:00 19:00 20:00 21:00 22:00
File: S975671 #1-857 Acq:5-SEP-97 09:28:57 EX+ Voltage SIM 70S Noise: 2570
305.898 7 F:2 BSU3(256, 30,-J. 0) PKD( 9 , 5 ,5, 0.05%, 10280. 0, 1. 00\,F,T) Exp:EPCUS
TRIANGLE LABS Text:SDN 4 TLI04293OA litj, TIME - 09:31
1003) A2.96E8
18:00 19:00 20:00 21:00
File :S975671 01-867 Acq:5-SEP-97 09:28:57 EI* Voltage SIR 70S Noise: 23795
315.9419 F:2 BSUB(256, 30, -3 . 0) PKD(9, 5,5,0. 05%, 95180.0,1.00%, F, T) Exp:EPCUS
TRIANGLE LABS Text .-RON 4 TLI44293 OA INJ. TIME • 09:31
100% A1.13E7
. 05%, 18952.0, 1. 00%,F,T) Bxp:EPCVS
INJ. TIME - 09:31
40j
202
A4.15E7
A.
A1.64E8
Al.62E8
A9.08E7
A1.12E8
Al. 60E8
A6.19E
A6.47E7
A.
j_5.2E7
Z.4.1E7
P-J.IS7
C
(12.IE7
|l.0JT7
JlO.OEC
23:00
Time
6.1E7
4.9E7
A1.95E8
Al. 0 7E8
3.6E7
Al,33E8
A7.70E7
Al.93E8
Al.92E8
7.38E
A4.56E7
A
1.2E7
0.0E0
22:00
23: 00
Time
1. 3E6
1.2E6
5.9E5
A1.53E6
O.OEO
22: 00
23:00
3. 0E6
r2.4E6
18:00 19:00 20:00 21:00
File: S975671 #1-867 Acq: 5-SEP-97 09:28:57 EI* Voltage SIR 70S Noise: ISO 0
317.9389 F:2 BSUB(256, 30,-3.0) PKD(9, 5,5,0.05%, 6000.0,1.00%, F,T) Exp:EPCUS
TRIANGLE LABS Text:RUN 4 TLI04293OA INJ. TIME - 09:31
lOOi Al. $1E7
80J
6 0J
4oq
20J
Oj
18:00 19:00 20:00 21:00 22:00
File: S975671 #1-867 Acq:5-SEP-97 09:28:57 EI* Voltage SIR 70S
330.9792 F:2 Exp:EPCUS
TRIANGLE LABS Text: RON 4 OX J §4293 OA INJ. TIME « 09:31
1001
.4.1E6
13.3E6
'¦.2.5E6
Ll. 7E6
-.8.3E5
LO.OEO
23': 00 Time
1.3E7
1.0E7
7.8E6
5.2E6
2.6E6
18:00 19:00 20:00 21:00
File:S975671 #1-867 Acq:5-SEP-97 09.-28.-57 EI* Voltage SIR 70S
375.8364 F:2 Exp: EPCUS
TRIANGLE LABS Text:RUN 4 TLI*42930A INJ. TIME
100%
80.
22:00
O.OEO
23:00 Time
09:31
21:40
2.2E4
1.8E4
22:21
21: 00
1.3E4
19:10
22:06
20:35
8.9E3
18:34
4.5E3
O.OEO
18:00
19:00
20:00
21: 00
22:00
23:00
I
I
i
i
i
1
i
i
i
t
i
i
i
i
i
i
i
265 -1
-------
File: S9 75671 #1-867 Acq: 5-SEP-97 09:28:57 EI+ Voltage SIS 70S Noise: 37192
319.8965 F:2 BSUB(256,30,-3.0) PKD{ 7, 5 ,3 , 0 ,05%, 148768.0, 1. 00%, f ,T) Exp:EPCDS
TRIANGLE LABS Text:SOW 4 TLI04293OA INJ. TIME = 09:31
1001
80j
tftfj
A6.04E6
A3.31E6 A2.11E6
A1.78E6
A2.37E6 /3Gsv-
Al.aors a A2.09E6
8.59E3\
A / V /v A
19:00 20:00 21:00 22:00
File: S975671 #1-867 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S Noise: 6717
321.8936 F: 2 BSUB(256, 30,-T. 0 ) PKD(7 , 5,3,0. 05%, 26868.0,1.00 %, F,T) Exp:EPCUS
.1. 7E6
.1.4E6
Li . 0E6
7.0E5
'.3.5E5
.O.OEO
23:00 Time
TRIANGLE LABS
10 OS
Text:RON 4 TLI04293OA
A7. J3E6
A4.11E6 A2.93E6
A2.32E6
INJ. TIME
A2.97E6
09:31
2.29E6
A A2.60E6
/VW/T/V-.
76E5
A,
A9.61E5
A
19:00 20:00 21:00 22:00
File:S975671 #1-867 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S Noise: 1430
331.9368 F: 2 BSUB(256, 30,-3.0 ) PKD(7, 5,3,0.05%, 5720.0 ,1.00%, F ,T) Exp:EPCUS
TRIANGLE LABS Text-.RUN 4 TLI042930A INJ. TIME = 09:31
23: 00
2.1E6
1.7E6
1.2E6
8.3E5
4.1E5
0.0E0
Time
1003,
80j
60J
40J
20J
A9.
A8.S1E6
2.5E6
2.0E6
1.5E6
1.0E6
15. 0E5
, , r
19:00 20:00 21:00 22:00
File:S975671 #1-867 Acq: 5-SEP-97 09:28:57 EI* Voltage SIR 70S Noise: 91
333.9338 F:2 BSUB( 256, 30, -3 . 0 ) PKD( 7, 5 , 3 , 0. 05%, 364.0 , 1. 00%, F, T) Exp:£PCUS
TRIANGLE LABS Text:RON 4 TLI#4293OA INJ. TIME = 09:31
23: 00
.O.OEO
Time
2E7
1003,
80j
60 i
40 i
202
19:00 20:00 21:00 22:00
File:S975671 #1-867 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S Noise: 14 76
327.8847 F:2 BStTB ( 256,30, -3.0) PXD( 7, 5 ,3 , 0. 05%, 5904 . 0,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:RON 4 TLI*42930A INJ. TIME » 09:31
100& A1.62E7
.2.9E6
.2.3E6
L1.8E6
¦.1.2E6
15.9E5
•.0.0E0
23:00
Time
Al.64E7
ft
A8.12E6
30J
60J
403
203
0j ,
' 19:00 20:00 21:00
File:S975671 #1-867 Acq:5-SEP-97 09:28:57 EI* Voltage SIS 70s
330.9792 F:2 Exp:EPCUS
TRIANGLE LABS Text:RON 4 TLI#42930A INJ. TIME
100!
Li
22:00
_S.3E6
-4.3E6
.3.2E6
:.2.1E6
.1.1E6
-0. 0E0
23': 00 Time
09:31
1.3E7
1.0E7
7.8E6
5.2E6
2.6E6
O.OEO
19:00
20:00
21:00
22:00
23:00
Time
266
-------
File :S9 756 71 #1-867 Acq:5-SEP-97 09:28:57 EI* Voltage SIS 70S Noise: 90
339.859 7 F:2 BSWB(256, 30,-3. 0) PKS(7, 5,3 , 0. 0S%, 360. 0,1.00%, F, 1) Exp:EPCUS
TRIANGLE LABS Text:SON 4 TL104293OA INT. TIME ¦ 09:31
23:00 24:00 25:00 26:00
File:S975671 #1-867 Acq:S-SEP-97 09:28:57 EI+ Voltage SIR 70S Noiae:417
341.8567 T-.2 BSUB(256, 30, -3\ 0 ) PKD( 7, 5, 3, 0. 05%, 1668. 0,1. 00%, F, T) Exp:EPCVS
ioo:
A2.42E7
AS,
M
1.10E7
[A1.76E7
A1 . 617E7 A
A1.12E7
'KaAAA A A
TRIANGLE LABS
1003
Text:SUN 4
A1.69E7
TLI04293OA
A3.90E7
IN,T. TIME
09:31
7.40E6
A1.17E7
A1.12E7 A
A7.38E6
7m ^ a a
23:00 24:00 25:00 26:00
File:S975671 01-86 7 Acq:5-SEP-97 09:28:57 EI* Voltage SIR 70S Noise: 89
351.9000 F:2 BSXTB(256, 30,-3. 0 ) PKD(7, 5,3,0. 05%, 356.0,1.00%,F,T) EipsEPCUS
TRIANGLE LABS Tezf.RUN 4 TLI04293OA INJT. TIME = 09:31
1003> A9.94E6
802
60J
20Z
A7.57E6
J
r_, , , , r r__( , , , , ^^
23:00 24:00 25:00 26:00
File:S975671 #1-867 Acq:5-SEP-97 09:28:57 EI* Voltage SIR 70S Noise: 104
353.8970 T:2 BSUB(256,30, -3.0) PKD(7, 5,3,0.05%, 416.0,1.00%, E, T) Exp:EPCUS
TRIANGLE LABS Text:RUN 4 TLI04293OA INJ. TIME - 09:31
1001
aol
6ol
40J
2fU
oj
A 5.
76E6
A4.54E6
-r
26:00
23:00 24:00 25:00
File:S975671 01-867 Acq:5-SEP-97 09:28:57 EI* Voltage SIS 70S
330.9792 F:2 Exp:EPCUS
TRIANGLE LABS Text:SON 4 TLI04293OA INS. TIME = 09:31
100* 23:26 23:48 24:19 •"> - "> 25:01 25:22 25:53
27:00
27:00
27:00
27:00
.1. 4E7
.1.1E7
.8.2E6
LS.4E6
.2.7E6
.O.OEO
Time
-9.1E6
.7.3E6
.5.4E6
13.6E6
L1.8E6
.O.OEO
Time
.3.2E6
i 2.6E6
11.9E6
'-1.3E6
'.6.4E5
.O.OEO
Time
-1.9E6
Li.5E6
11.1E6
.7.5E5
13.8ES
.O.OEO
Time
24:19
26:28 26:44 27jJ)3^1.4E7
1.1Z7
8.4E6
5.6E6
2.8E6
23:00 24:00 25:0026:00
File:S975671 §1-867 Acq:S-SEP-97 09:28:57 EI+ Voltage SIR 70S
409.7974 F:2 ExpsEPCUS
TRIANGLE LABS Text:RUN 4 TLI04293OA INJ. TIME = 09:31
100%
27:00
iO.OEO
Time
1.7E4
1.4E4
4:53
26:49
25:57
23:51
26:34
1.0E4
23:27
7.0E3
25:45
25:32
25:10
3.5E3
23:00
24 : 00
25:00
26:00
'.O.OEO
27:00 Time
267
I
-------
File:S975671 41-867 Acq:5-SEP-!J7 09:28:5/ EH- Voltage SIR 70S Noise:1^64
355.8546 F:2 BSUB(256, 30, -3 .0 ) PKD(7, 5, 3 , 0.05%, 5056.0 ,1. 00%, F,T) Exp:EPCUS
TRIANGLE LABS Text: RON 4 TLI#42930A IS J. TIME = 09:31
1003
801
60S
401
201
A4.22E6
A4.27E6
1. 75E6
A1.66E6
A1.33E6
A2.54E6
6.19E5
A3.26E5
1.4E6
ii.ie6
A7.21E5
A6.95E5
25:00 26:00
File: S975671 #1-867 Acq: 5-SEP-97 09:28:57 EI+ Voltage SIS 70S Noise: 700
357.8516 F:2 BSXJB(256, 30, -3.0) PKD( 7, 5, 3, 0. 05%, 2800. 0, 1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:RXJN 4 TLI#42930A INJ. TIME = 09:31
100%
-A
18
15
12
.0
27': 00
. 5E5
, 7E5
, 8E5
. OEO
Time
A4.02E6
1.12E6
A1.12E6
A9.04E5
A4.83E5
A9.84E5
A7.11E5
A5.26E5
A4.54E5
A3.91E5
A2.43E5
25:00 26:00
File:S975671 #1-867 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S Noise:82
367.8949 F:2 BSOB(256, 30, -3. 0) PKD( 7, 5, 3, 0. 05%, 328. 0, 1. 00%, F, T) Exp-.EPCUS
TRIANGLE LABS Text:RXJN 4 TLI#42930A INJ. TIME = 09:31
100A
30.
60.
40.
20.
A3 .72E6
3 .92E5
27: 00
1.
18.
15,
14
12.
10,
25:00 26:00
File:S975671 #1-867 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S Noise:73
369.8919 F:2 BSXJB (256, 30 ,-3 .0 ) PKD(7, 5 , 3 , 0. 05%, 292. 0, 1. 00%, F,T) Exp:EPCUS
TRIANGLE LABS Text:RUN 4 TLI#42930A INJ. TIME = 09:31
100%
801
60S
401
20:
25:00 26:00
File:S975671 #1-867 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
330.9792 F-.2 Exp:EPCUS
TLI#42930A
25:01 25:22 25:37
2. 78E5
27:00
7.
15.
14.
12
II,
0.
TRIANGLE LABS Text-.RUN 4
1003, 24:19 24:33
80S
60.
4 OS
20S
0.
INJ. TIME
25: 53
25:00
26: 00
27:00
09:31
26:28 26:44 26:55 1.
27:00
1E6
5E5
4E5
3E5
1E5
OEO
Time
3E5
8E5
4E5
9E5
5E5
OEO
Time
4E7
,1E7
. 3E6
,5E6
,8E6
.OEO
Time
268
-------
File:S975671 §1-425 AcqsS-SEP-97 09:28:57 EI+ Voltage SIR 70S Hoi set 1481
373.8208 F:3 BSTJB(256, 30,-3. 0) PKD(7, 5, 3, 0 . 05%, 5924 . 0,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:RDN 4 TLI04293OA INJ. TIME » 09:31
100% A3 . 61E6
80J
601
40j
20j
0±L.
A2.41E6
A9.S0E5I
_A
A5.10E5
f-p
A6.94E5
I i "[»"i O]
27.-24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00
File:S975671 41-425 Acq:5-SEP-97 09:28:57 EI+ Voltage SIM 70S Noise: 1354
375.8178 F: 3 BSUB(256,30, -3.0) PKD( 7,5,3,0.05%, 5416.0,1. 00%, F, T) Exp:EPCUS
.1. 4ES
il.lES
.8.4E5
-5.6E5
¦-2.8E5
.O.OEO
30)12 30:24 riffle
TRIANGLE LABS Text:SDN 4 TLH42930A
ioo:
INJ. TIME
09:31
A2.90E6
1.1E6
9.1E5
6.9ES
A2.00E6
4.6E5
9.27E5
A7.96E5
2.3E5
A3.66E5
A4.90E5
, , (N ii I j ¦
27.-24 27:36 27:48 28:00 28': 12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00
File: S975671 #1-425 Acq:5-SEP-97 09:28:57 EI*- Voltage SIR 70S Noise: 1080
383.8639 F:3 BSVB(256,30, -3.0) PKD(7, 5,3,0.05%, 4320. 0,1. 00%, F,T) Exp-.EPCUS
TRIANGLE LABS
1003,
80.
Text:RON 4 TLI04293OA
IK7. TIME
09:31
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29.-00 29:12 29:24 29:36 29:48 30:00
File:S975671 #1-425 Acq:S-SEP-97 09:28:57 EI* Voltage SIR 70S Noise: 1172
385.8610 F:3 BSUB(2S6,30, -3.0) PKD( 7, 5,3, 0. 05%, 4688. 0,1. 00%, F, T) Exp-.EPCVS
TRIANGLE LABS
1003,
801
60J
40.
20,
Oil
File:S975671 #1-425 Acq:5-SEP-97 09:28:57 EI* Voltage SIR 70S
392.9760 F:3 ExpiEPCUS
TRIANGLE LABS Text:RUN 4 TL1#42930A INJ. TIME =
100% . 27:40 „ 28:16 28-15 . . 29:15
60,
40.
20.
A3.
A2.49E6
A2.13E6
O.OEO
30:12' 30:24 Time
.1. 1E6
L9.0E5
.6.7E5
14.5E5
-2.2E5
' 1 "I ' i i"' M
30:12 30:24
O.OEO
Time
Text:RUN 4 TLH42930A
INJ. TIME
09:31
A4.81E6
A4.04E6
2.3E6
1.9E6
1.4E6
9.3E5
4.7E5
'I 1 1 ' '' I ' ' ' ' ¦ I 1 ' ''""I ' i i i ' | ' ¦ i"1*' ) |'' I I TT|"l I 1 I I") I'llt |>V I I i | i i i i i | 1 1 1 ' 1 I
27.-24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00
> 1 I" t I I I 1 I
30:12 30:24
O.OEO
Time
09:31
7.4E6
0530:15
5.9E6
4.4ES
2.9E6
1.5E6
0.OEO
27:24 27:36 27-48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 Time
File:S97S671 #1-425 Acq:5-SEP-97 09:28:57 EI+ Voltage SIS 70S
445.7555 F.-3 Exp: EPCUS
TRIANGLE LABS
ioo:
Text:RUN 4 TLI04293OA
INJ. TIME = 09:31
1.7E4
1.3E4
27:39
1.0E4
29 j 11
28:31
27: 50
6.7E3
28:51
3.4E3
| O. OEO
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 Time
269
-------
File:S975571 41-425 Acq:5-SEP-97 09:23:57 EI* voltage SIR 70s Noise: 715"
389. 8156 F: 3 BSUB(2SS, 30, -3. 0 ) PKPf 7, 5,3,0. 05%, 2860. 0,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS
1001
80J
eo:
40:
20:
Text:SUH 4
TLI04293OA
A8.03E6
I1KT. TIME
09:31
A2.31E6
0_
A1.63E6
A6.41E5
¦ XX
A5.77E5
28': 00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36
File:S97S671 #1-425 Acq:5-SEP-97 09:28:57 EI* Voltage SIR 70S Noise:684
391.8127 F:3 BSUB( 256, 30, -3 .0 ) PXD( 7, 5, 3, 0. 05%,2736. 0,1. 00%, F, T) Exp:EPCVS
29:48
TRIANGLE LABS Text :RUN 4
1004
40.
20.
TLI§42930A
A6.63E6
inj. time
09:31
A1.88E6
A5.13E5
A1.19B6
A4.57E5
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36
File:S975671 #1-425 Acq:5-SEP-97 09:28:57 EI* Voltage SIR 70S Noise: 1161
403.8529 F:3 BSUB{256,30, -3.0) PKD(7, 5,3, 0.05%, 4644.0,1. 00%, F, T) Exp:EPCDS
TRIANGLE LABS Text:RUN 4 TLI #4293 OA 1NJ. TIME
100% A2.57E6
i ""!111 [ i1 i" i i i | i i i—i i i—r
28:36 28:48 29:00
A3.27E6
28:00 28:12 28:24 28:36 23:48 29:00 29:12 29:24 29:36
File:S9 75671 §1-425 Acq:5-SEF-97 09:28:57 EI* Voltage SIR 70S Noises 317
401.8558 F: 3 BSUB(256, 30, -3.0) PKD ( 7, 5 , 3 , 0. 05%, 1268. 0 , 1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:RON 4 TLI442930A INJ. TIME = 09:31
1003, A3.14E6
80j
60.
40.
201
29:48
801
601
40.
20.
' '' I
28:00
y
28:12 28:24 28:36 28:48 29:00 29:12 29:24
File:S975671 #1-425 Acq:5-SEP-97 09:28:57 EI* Voltage SIR 70S
392,9760 F:3 Exp:EFCVS
TRIANGLE LABS Text:Rm 4 TLI04293OA INJ. TIME
09:31
A2. 74E6
29:36
09:31
100%
80.
60:
40.
201
0.
28:16
28:27t
29:17
29:50
'ia-oo' ' '28112 ' '28:24 ' '28:36 ' '28:48 ' '29:6o' ' '29:12 ' '29:24 ' ' 29': 36
_ 2.9E6
12.3E6
11. 7E6
11. 1E6
15. 7E5
.0.0E0
30:00
Time
.2.3E6
.1. 9E6
11.4E6
.9.4E5
.4.7E5
.O.OEO
30:00
Time
.1. 4E6
.1.1E6
18.4E5
.5. 6E5
.2. 8E5
29:48 30:00
"'"T ' ' I j ''
29:48 30:00
.O.OEO
Time
.1.1E6
"-8.5E5
.6.4E5
.4.3E5
.2.1E5
.0.0E0
Time
29:48 30:00
.7.2E6
.5.7E6
.4.3E6
.2.9E6
.1. 4E6
.0.0E0
Time
-------
File :S975671 *1-390 Acqs 5-SEP-97 09-.2S-.57 El* Voltage SIS 70S Noiae:784
407.7818 F:4 BSUB(256, 30,-3 . 0) PKB(7, 5,3,0. 05%, 3136. 0,1 . 00%, F, T) Exp:EPCUS
TSIANGLE LABS TextiSUN 4 TLI04293OA TKT. TIME » 09:31
1003, A2.f2E5
A1.47E5
I I i1 p i*" i fi
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
File:S975671 *1-390 Acq:5-SEP-97 09:28:57 EI* Voltage SIS 70S Noise: 59
409.7789 F:4 BSU2(256, 30, -T. 0} PKD(7, 5,3, 0.05%, 236. 0,1. Q0\,T,T) Exp:EPCUS
TRIANGLE LABS Text:SON 4 TLM42930A INT. TIME » 09:31
A4.50E4
A1.81E4 A1.29E4
A2.27E4
^
A3.27E4
8.1E4
S.4E4
4.8E4
3.2E4
1.6E4
32:48
0.0E0
33:00 Time
1003
SOJ
60j
4oq
20A
7E5
A9.S7E4
A4.09E4
A1.12E4
» ,..A,
A4.40E4
32:36
31:12 31:24 31:36 31:48 32:00 32:12 32:24
File:S975671 #1-390 Acq:5-SEP-97 09:28:57 EI* Voltage SIS 70S Noise: 528
417.8253 F:4 BSUB( 256, 30, -3.0 ) PKD( 7,5,3,0.05%, 2112. 0 ,1. 00%, F, T) Exp-.EPCUS
TSIANGLE LABS Text:SON 4 TLI*42930A INJ. TIME = 09:31
32:48
1. 0E5
8.3E4
6.3E4
4.2E4
2.1E4
rwfvCN | - r o • oeo
33:00 Time
1003s
SOJ
60j
4 03
2ol
A8. J4E5
AS. 72E5
11 ¦ i ;
31:12 31:24 31:36 31:48 32:00 32:12 32:24
File: S975671 #1-390 Acq:5-SEP-97 09:28:5 7 EI* Voltage SIS 70S Noise: 56
419.8220 F:4 BSUB(256,30, -3. 0) PKD(7, 5,3,0. 05%,224 . 0,1. 00%, F, T) Exp:EPCCS
TSIANGLE LABS Text-.SVN 4 TLI04293OA INT. TIME - 09:31
"T i '
32:00
f-—
32:36
32:48
3.7E5
3. 0E5
2.2E5
1.5E5
7.5E4
.0.0E0
33:00 Time
100s
A2.12E6
60E6
' I
32:12
32:24
31:12 31:24 31:36 31:48 32:00
File:S975671 *1-390 Acq:5-SEP-97 09:28:57 EI* Voltage SIS 70S
430.9729 F.-4 Exp:EPCUS
TSIANGLE LABS Text:SON 4 TLI*42930A INJ. TIME
1003, 31:13 311
32:36
09:31
32:48
8.5E5
6.8E5
5.1E5
3.4E5
1.7E5
.0.0E0
33:00 Time
4.4E6
3. 5E6
2.6E6
1.8E6
8.8E5
31:12 31:24 31:36 31:48 32:00 32:12
File:S975671 *1-390 Acq:5-SEP-97 09:28:57 EI* Voltage SIS 70S
479.7165 F:4 Exp: EPCUS
32:24
TSIANGLE LABS
ioo:
Text:StJN 4 TLI*42930A
31:33
INJ. TIME
32:36
09:31
32:48
.O.QEO
33:00 Time
1.0E4
8.0E3
32:20
6.0E3
32:34
4.0E3
31:50
31:16
jJ^XLRj
32:27
2.0E3
32:24
32:36
31:12
31:24
31:36
31:48
32:00
32:12
32:48
10. OEO
33:00 Time
27i|
-------
Flle:S975671 01-350 Acq:S-S£P-97 59:28:5? Elf Voltage SIR 70S Noise: J J/
423.7766 F:4 BSUB(256, 30, -3.0) PXD( 7, 5, 3, 0. 05\, 1348. 0,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Texts SON 4 TLI*42930A IMS. Tim = 09:31
100%
a a:
601
401
¦ I n I I f| 'I I i I T> I I fi r
31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18
File:S975671 #1-390 Acg:5-SEP-97 09:28:57 EI+ Voltage SIR 7OS Noise: 59
425.7737 F:4 BSUB(256, 30,-3. 0) PKD(7, 5,3,0.05%, 236.0,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:SUN 4 TLI04293OA INJ. TIKE = 09:31
100%
80.
so:
4 a:
20.
203
A3.26E5
32:24 32:30
A3.02E5
31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30 32:36
File-.5975671 #1-390 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S Noise: 70
435.8169 F: 4 BSUB (256, 30, -3.0 ) PKD( 7, 5 , 3 , 0. 05%, 280. 0 , 1.00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:RUN 4 TLH42930A INJ. TIME = 09:31
100\
80.
60.
40.
20,
—
31': 54
-^T
32: 06
T-
I I I I
31: 30
31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18
File:SS75571 #1-390 Acq:5-SEP-97 09:28:57 E1+ Voltage SIX 70S Noise: 60
437.8140 F: 4 BSUB ( 256 , 3 0,-3 . 0 ) PKD( 7, 5 , 3, 0. 05%, 240 .0, 1.00%,F,T) Exp:EPCUS
TRIANGLE LABS Text:RUN 4 TLI442930A INJ. TIME = 09:31
loos
801
60.
40.
20.
A1.44E6
i i i ! • i i > • | ' '
31:30 31:36
31:42 31:48 31:54 32:00 32:06 32:12
File: S975671 #1-390 Acq:5-SEP-97 09:28:5 7 £I+ Voltage SIM 70S
430.9729 F:4 Exp:EPCUS
TRIANGLE LABS Text:RUN 4 TLI442930A INJ. TIKE =
iooa>
-2.BES
-2.3E5
11. 7E5
.1.1ES
15.7E4
.O.OEO
32:36 Time
2.7E5
12.2E5
.1. 6E5
.1. 1E5
.5.5 E4
.0.0E0
Time
.6.1E5
.4.9E5
.3. 6E5
.2.4E5
11.2E5
32:24 32:30 32:36
.0.0E0
Time
.5.4E5
.4.3E5
3.2E5
12.2E5
L1.1E5
32:18
801
601
40.
20.
0.
32:24
32:30 32:36
09:31
32:28
1O.OEO
Time
4.4E6
.3. 5E6
.2.6E6
.1, 8E6
18.8ES
O.OEO
'31:30 ' "31:36 " 31:42 ' 31:48 ' 31:54 ' '32:00 ' 32:06 ' 32': 12 ' 32*is ' 32:24 ' 32:30 ' 32;is Time
272
-------
TIIe7sW5W7r~gT^J¥0~Acq75
441.7428 F: 4 BSUB(256,30,
TRIANGLE LABS Text:RON 4
100a
32:00
File: S975671 #1-390 Acq:5
443.7399 F:4 BSX3B(256, 30,
TRIANGLE LABS Text:SUN 4
1001
SEP-97 09:28:57 EX* Voltage SIS 70S Noise: 60
•3.0) PKD(7,5,3,0.05%,240.0,1.00%,F,T) Exp:EPCUS
TLX 04293 OA INJ. TIME = 09:31
2.3E4
2.0E4
1.8E4
1.6E4
1.4E4
A3.60E4
A2.23E4
1.1E4
9.1E3
A1. 73E4
A7.97E3
A2.39E4
6.8E3
A2. 72E4
4.5E3
A7.83E3
2.3E3
33:00 34:00
¦SEP-97 09:28:57 EI* Voltage SIS 70S Noise: 55
¦3.0) PKD{7, 5, 3, Q.05%,220. 0,1. 00%, F,T) Exp:EPCUS
TLX 04293OA INJ. TIME = 09:31
35:00
32:00
Fxle:S975671 #1-390 Acq:5
430.9729 F:4 Exp: EPCUS
TRIANGLE LABS Text:SON 4
100:
33:00 34:00
SEP-97 09:28:57 EX* Voltage SIM 70S
35:00
TLXt4293OA
32:34
INS. TIME = 09:31
34:34
35:29
32:00
File:S975671 §1-390 Acq: 5
513.6775 F:4 ExpsEPCOS
TRIANGLE LABS Text-.RON 4
100%
33:00 34:00
¦SEP-97 09:28:57 EI* Voltage SIS 70S
35:00
TLX *4293 OA
IN J". TIME « 09:31
2:52
32:21
31:25
3 2:4
33:33
34:0 7
33:54
lu
10.0E0
Time
1.5E4
1.3E4
A3. 73E4
1.2E4
1.0E4
8.9E3
A1.65E4
7.4E3
A3.18E4 * 05E4
A1.53E4
6.0E3
A1.17E4
A7.99E3
4.5E3
A9.40E3
74E3
A4. 77E3
3.0E3
1.5E3
O.OEO
4.6E6
33:55 34:15
33:07
4.2E6
3. 7E6
3.2E6
2. BE6
2.3E6
1.9E6
1.4E6
9.3E5
4.6E5
O.OEO
32:00
33:00
34:00
9.7E3
8.7E3
7.8E3
6.8E3
5.8E3
35:44
4.9E3
3.9E3
2.9E3
1.9E3
9.7E2
O.OEO
35:00
273
-------
F±le:S97SS71 *1-390 Acq:5-SEP-97 05:28:57 ET+ voltage sis 70s Noise: S3
457.7377 F:4 BSUS(256 , 30, -3.0 ) PKD(7 f 5,3, 0.05%, 248. 0,1,00%,F, T) Exp-.EPCUS
TRIANGLE LABS Text:SUN 4 TLX*4293OA IK7. TIME = 09:31
1001, A2.38E5
80.
601
40.
20.
A
34:30 34:36 34:42 34:48 34': 54
File:S975671 #1-390 Acq:5-SEP-97 09:28:57 EI* Voltage SIR 70s Noise:64
459.7348 F:4 BSU8(256,30, -3.0) PKD( 7, 5, 3, 0. 05%, 256. 0, 1 .00%, F, T) Exp-.EPCUS
TRIANGLE LABS Text:SON 4 TLIM2930A mj. TIME =
35: 00
09:31
1001
so:
60.
40.
20.
26ES
=?-
35:00
34:30 34:36 34:42 34:48 34:54
File:S975671 #1-390 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S Noise:51
469.7779 F:4 BSUS(256, 30, -3.0) PKD( 7, 5 ,3 , 0. 05%, 204. 0, 1. 00%,F,T) Exp-.EPCUS
TRIANGLE LABS Text:SUN 4 TLI#42930A JJKJ. TIME = 09:31
1003s
80.
601
40.
20.
34-30 34:36 34:42 34:48 34:54 35:00
File;SS75671 §1-390 Acq:5-SEP-97 09.-28:57 EI* Voltage SIR 70S Noise: 61
471.7750 F:4 BSUB(256, 30, -3. 0 ) PKD{ 7, 5 , 3 ,0,0S%,244. 0, 1.00%,F,T) Exp:EPCUS
TRIANGLE LABS Text:RDN 4 TLI#42930A INJ. TIME = 09:31
lOOSk
803
603
403
203
[ i IT* | i i I l i 1 r-
34:30 34:36 34:42 34:48 34:54
File: S975671 #1-390 Acq:5-SEP-97 09:28:57 EX+ Voltage SIS 70S
430.9729 F-.4 ExpsSPCUS
TRIANGLE LABS
1003,
801
601
40.
20.
01
TexZ.-RON 4
TLI#42930A
34:41
INJ. TIME
34:56
35:00
09:31
34:30
34:36
34 • 42
-i=
35:06
7.4E4
5.9E4
4.4E4
2.9E4
1.5E4
O.OEO
35:06
.1.2E5
.9. 5E4
.7.1E4
.4.8E4
.2.4E4
.O.OEO
Time
35:06
.3. 8E5
.3.0E5
.2.3E5
.1. 5E5
. 7.5E4
.0.0E0
Time
4.1E5
3.3E5
12.5E5
1. 6E5
8.2E4
~ -
35:06
35:06
.O.OEO
Time
4. 6E6
3.7E6
12.7E6
1.8E6
19.2E5
34:48
34:54
35:00
35:06
10.OE0
Time
274
-------
Channel I 339,9798 Pa* top
Hel^t 3,25 volts Span 288 ppt
Systa file naie
Oata file mt
Resolution
Grotp nmtef
Ionization lode
Syitchlng
Ref, tasses 292.9885,
A 293 J 331
K 332
L 334
1 340
H m
9 352
f 354
8 35S
331 R 358
M, uss 418.9768 Peak top
Hiigtt .96 wits Span 298 ppi
0 318
E 318
F 328
fi;S985971
11668
2
11*
VOLTAGE
418.9766
S 368
T 378
U 378
V 418
I
I
I
I
I
I
I
I
I
I
I
I
1
I
1
I
I
I
27-51
-------
File:S975671 #1-867 Acq:5-SEP~97 09:28:57 EI+ Voltage SIR 7~0S
303.9016 F:2 Exp:EPCUS
Sample Text: RUN 4 TLI#42930A JNJ TIME = 09:31 File Text: RUN 4
100%, ^A4.08E7>
80
60s
40i
20 J
16:12 16:24 16:36 16:48 17 iOO 17 :12 17:24 17 :36
File:S975671 #1-867 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
305.8987 F:2 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A INJ TIME = 09:31 File Text:RUN 4
100%
T I I r
—i—i—i—i—i—r
17:12 17:24
TLI#42»
1.5E7
1.2E7
17 148 ' 18:00
_!—j—p-,—f—j-
18 :12
«"T"'1
18 :24
80
60
40 j
20
0
<^A4 !90E7l
1—I—I—I—I—I—I—]—i—I—I—i—I—I—i—I—I—I—i—I—i—I—I—I—i—I—I—I—i—I—i—I—i—i—i—i—i—I—r—i—i—i—r"l—i—i—i—i—I—]—I—i—r—r~i—j—i—i i—,—r~r-
16:12 16:24 16:36 16:48 17:00 17:12 17:24 17:36 17:48 18:00 18:12
1 1 1
18:24
File:S975671 #1-867 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
315.9419 F:2 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A INJ. TIME = 09:31 File Text:RUN 4
100% 16;53
_0.0E0
Time
TLI#42»
.1. 8E7
.1.4E7
.1.1E7
7 . 2E6
.3 . 6E6
.0 . 0E0
Time
TLI#42»
.2 . 8E5
2 . 2E5
17 :56
17 :41
1.7E5
1. 1E5
16:33 16:
16:13
-t—i—i—i—i—i—|—i—i—i—i—i—|—i—j—r—r~i—|—i i I I—i—j—i—r r i i—pi—i—i—r~i—r—t—i—i—i—i—i—>—i—t—i—i—j—i—i—i—i—i—i—i t
16:12 16:24 16:36 16:48 17:00 17:12 17:24 17:36 17:48 18:00 18il2
1—I—|-
18 :24
0.0E0
Time
ro
Kl
cn>
-------
File:S975671 #1-867 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
319.8965 F:2 Exp:EPCUS
Sample Text: RUN 4 TLI#42930A INJ. TIME
100^
80 j
60d
40 j
20i
0:
16
1
00
ill
20:01
—i—i—i—i—i—j—i—i—i—i—i—r—i—i—i—r~
U
w
2 :.p0
23 :22
ill
09:31 File Text:RUN 4 TLI#42»
84,19If! nif 4 . 1E4
l3.3E4
l2.4E4
1.6E4
h.8 . 1E3
0.0E0
!
-f—i—j—i—r—i—i—i—|—i—r • "i r—r-
File:S975671 #1-867 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
321.8936 F:2 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A INJ. TIME
H
100%
17:18
18 :4
16:37
3120:0
3 :
2:2
yw
23 : 02 . tj
| M J • Jj
124
20
f]
i—-r—i—i—n—r—t—i—i—i—i—j—i—i—i—i—i—|—i—i—i—i—i—i—i—i—i—i—x—j—i—r—i—i—i—j—i—i—i—r i - i—t—i—i—i—i—i—i—i—i—i—r~
0 17:00 18:00 19:00 20:00 21:00 22:00 23:00 24:00 2!
File:S975671 #1-867 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
331.9368 F:2 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A INJ. TIME = 09:31 File Text:RUN 4
16:55
100%
80i
60J
40i
20-i
0 ( ! ! , 1 j—, , , , , 1 r—| 1 , , 1 1 1—| , 1 1 1 1—,—, , j , 1 1 , 1—j , ,—, , 1 1 1—, 1 ,—,—| 1 , 1 ,—r
16:00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 24:00
22 :33
21:05
23 :56
18:22
TLI#42»
8 . 0E4 («l
L6.4E4
i4.8E4
i3 . 2E4
^i»h>
11.6E4
:- 0 . 0E0
: 00 Time
TLI# 4 2 »
2 . 2E4
Ll.7E4
11.3E4
18.7E3
l4.4E3
: 0,0E0
:00 Time
-------
File:S975671 #1-867 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
319.8965 F:2 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A _mj. TIME
10041 A I 1 CA7.69E5^
09:31 File Text:RUN 4
TLI#42»
.2 . 3E5
1.9E5
A5.40E5)
9 . 3E4
4 . 7E4
~i—J—I—|—I—I—r^r—i—|—i—i—i—i—i—|—i—i—i—i—i—r
21:48 22:00 22:12 22:24
t—r—| r i—r—r—i—r—i—i—i—t r
23:12 23:24 23
22:36 22:48 23:00
File:S975671 #1-867 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
321,8936 F:2 Exp:EPCUS
Sample Text: RUN 4 TLI#42930A —JENJ. TIME = 09:31 File Text: RUN 4
100%1 I \ ( A9.48E5 >
23 :00
23 :12
23 :24
.0 .0E0
36 Time
TLI#42»
.2 . 7E5
1.6E5
1. 1E5
5 . 4E4
21:48 22:00 22:12 22:24 22:36 22:4?
File:S975671 #1-867 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
331,9368 F:2 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A INJ. TIME = 09:31 File Text:RUN 4
100S, I h 23 11
0.0E0
36 Time
TLI#42»
3 . 6E4
23:29
2 . 9E4
2 . 2E4
22 :33
22 :4
23 :07
7.3E3
-i—i—i—I—i—r—i—i—r"|—r—r—i—r—f—j—t—r—i—r~-i—i—i—i—i—i—i—j——i—r~i—r—i—i—r~t™t—i—i—i—i—i—i—i—r—i—i—r~i—i—r—i—i—i—i—f
21:48 22:00 22:12 22:24 22:36 22:48 23:00 23:12 23:24 23:
0 .0E0
3 6 Time
r\3
«-s|
00
-------
File:£975671 #1-867 Acq:5-SEP-97 09:28:57 EI+
339.8597 F:2 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A
100%,
80 j
60j
40j
20 J
01
24:21
25.03
t
25:20
24:50
Voltage SIR 70S
INJ. TIME
47
09:31 File Text:RUN 4
25:00
File:S975671 #1-867 Acq:5-SEP-97 09:28:57 EI+
341.8567 F:2 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A
100% 25:03
8 oJ2 4•21 M 25:20
60i
40j
20
26 :13
26 :44
...A
26:00
Voltage SIR 70S
INJ. TIME
24 :50
25:00
File:S975671 #1-867 Acq:5-SEP-97 09:28:57 EI+
351.9000 F:2 Exp:EPCUS
Sample Text:RUN 4 TLI#4293 0A
100% 25:02
80
60
40.
20J
26 :12
26 :44
- A.,
26:00
Voltage SIR 70S
INJ. TIME
27 :00
09:31 File Text:RUN 4
Oj
27:00
09:31 File Text:RUN 4
TLI#42»
.4 . 1E6
l3.3E6
2 . 4E6
1.6E6
l8.1E5
_0.0E0
Time
TLI#42»
.2 . 7E6
12.1E6
Ll.6E6
Ll.1E6
l5,3E5
25:00
26:00
27 :00
0.0E0
Time
TLI#42»
-3 . 2E6
J2 . 6E6
_1.9E6
-1 .3E6
.6 . 4E5
.0.0E0
Time
ro
Kl
-------
File: S975671 #1-867 Aeq:5-SEP-97 09:28:57 EI+ Voltage SIR "70S
339.8597 F:2 Exp;EPCUS
Sample Text:RUN 4 TLI#42930A
100%
INJ. TIME = „ 09:31 File Text
(Al. 24E7
RUN 4 TLI#42»
4.1E6
3 . 3E6
2 .4E6
CK1.69ETL id
.1 .6E6
"A3 .~99e5>
8 . 1E5
~i—i—i—i—r—i—r
24:18 24:24
t—i—3—j—i—i—i—i—i 'r i—i—i—i—i—j—I—i—i r i—|—t—j—r—i—i—i—i—r—i—i—i—r~i—r~
24:48 24:54 25:00 25:06 25:12 25:18
24:30 24:36 24
File:S975671 #1-867 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
341.8567 F:2 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A
100%
i—i—i—j—i—r
25 :24
.0 .0E0
Time
INJ. TIME = 09:31 File Text
5E6
RUN 4 TLI#42»
2.7E6
2.1E6
1. 6E6
:.l. 1E6
<&2,79E6>
5.3E5
¦*i—i—I—i—i—i—i—i—|—r i i—I—i—|—I—r
24:18 24:24 24:30
-i—i t "i" i
24136 24
1—p—I—p~l—I—I—1—I p I—I—I—I—I—|—I—I—1—I—I—| 'i T i—r~t—|—i—i—i—i—i—|—i—r
24:48 24:54 25:00 25:06 25:12 25:18
t—r i—| T~i
25 :24
.O.OEO
Time
File:S975671 #1-867 Aeq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
351.9000 F:2 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A
100%
80.
60.
40.
20.
INJ. TIME = 09:31 File Text
25:02
i i I i i—i i i | i < i i i t i i"" i i i | i i i1 i 11
24:18 24:24 24:30 24:36 24
j-T-r
: 42
~i—|—i—i—i—r~i—j—i—i—i—r' e j—i—i—i—i—i—j—i—rT"' I i [ r~"i—i—i i T ' i
24:48 24:54 25:00 25:06 25:12 25:18
RUN 4 TLI # 4 2 »
3 .2E6
2.6E6
1.9E6
1.3E6
L6.4E5
.0 . 0E0
Time
T 1 1—j V ' I
25 :24
O
-------
File: S975671 #1-867 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 7(JS"
355.8546 F:2 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A
100% 24;19
INJ. TIME
09:31 File Text:RUN
80
60j
40i
20 J
0
25 :02
1-
25:21
24:51
26 :08
25:49
? '"I —¦—I""*' "f"—-r-~—T"—r~sa—( —1 "t—*—*i ** i" i :w*;i ,v.
24:00 25:00 26:00
File:S975671 #1-867 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
357.8516 F:2 Exp:EPCUS
26:38
J\-
Sample
100%
80j
60i
40i
20i
0:
INJ. TIME
27 :00
09:31 File Text:RUN
24:19
r —*~i
25:21
24 :51
^ _ 26:08
25:37 25:59A
A A JvJX
26:38
27:00
24:00 25:00 26:00
File:S975671 #1-867 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
367.8949 F:2 Exp:EPCUS
Sample Text: RUN 4 TLI#42930A INJ. TIME = 09:31 File Text: RUN
100% 26.08
80j
60
40j
20j
oJ
,— r-
24 :00
1 1 T"
25 :00
1 r^
26 :00
K-
-r————|— r-
27 :00
4 TLI#42»
,_1. 4E6
1.1E6
18.5E5
L5.7E5
2.8E5
Lo.oeo
Time
4 TLI#42»
8 . 9E5
7 . 1E5
t_5 . 4E5
3 . 6E5
L1.8E5
, 0.0E0
Time
4 TLI#42»
_1.1E6
8 . 5E5
6.4E5
t-4 . 3E5
2 . 1E5
O.OEO
Time
TO
-------
File:S975671 #1-867 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
355,8546 F:2 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A INJ. TIME
/¦ATT'pWBi
100%
09:31 File Text:RUN 4 TLI#42»
3 . 8E5
3 . 0E5
2 , 3E5
1.5E5
7 . 5E4
n—i—i—i—|—i—i—i—i—i—jt—i—i—i—i—|—i—i—r
25 00 25:06 25:12 25:18
-i—|—i—f—i—r—i—|—i—«—i—i—i—|—r
25:24 25:30 25:36
t—i—i—|—i—i—r
25 :42
^0 . 0E0
25:48 25:54 26:00 Time
-i—I"-j—i—i "i—i i"—i—r—r—t—i | 1 l ' i1
File:S975671 #1-867 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
3 57.8516 F:2 Exp:EPCUS
Sample Text: RUN 4 TLI#42930A „ JNJ . TIME =
E6 ' ;
09:31 File Text:RUN 4 TLI#42»
2 . 4E5
1.9E5
1.4E5
9.6E4
4.8E4
25:00 25:06 25:12 25:18 25:24 25:30 25:36 25:42
File:S975671 #1-867 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
367,8949 F:2 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A INJ. TIME =
_1 (, j 1 r
25:18 25:24
100%
25:39
25:07
25:00
25:06 25:12
"i—i—I—r
25:18
~1—I—1—i—i—r
25:24
25 :30
t—r—i—r -i—-j—i t
25:36 25:42
t 0 • 0 E0
25:48 25:54 26:00 Time
09:31 File Text:RUN 4 TLI#42»
-9.6E3
.7 . 7E3
.5. 8E3
.3.8E3
1.9E3
. - —J—l—1—t—r—T—[—l—l—l—I—i—I—t—i—r - ^ • 0E0
25:48 25:54 26:00 Time
, 00
r-o
-------
File:S975671 #1-425 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
373.8208 F:3 Exp:EPCUS
sample Text:RUN 4 TLI#42930A INJ. TIME
29:11
09:31 File Text:RUN 4
TLI#42»
_1.8E5
100%
1.4E5
1.1E5
28:59
7 , 0E4
8:47
29:56
3 . 5E4
28:00 29:00 30:00
File:S975671 #1-425 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
375.8178 F:3 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A INJ. TIME =
100% 28;12
09:31 File Text;RUN 4
0.0E0
Time
TLI#42»
1.5E5
1.2E5
8.8E4
28:59
5.9E4
29:57
;!8:48
2.9E4
29:25
0.0E0
Time
28 00 29:00 30:00
File:S975671 #1-425 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
383.8639 F:3 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A
100%
80i
60i
40j
20i
0:
28
00
29:10
h
INJ. TIME
29 : 52
09:31 File Text:RUN 4
J-
-> r™
29:00
T r
30:00
TLI#42»
.9.5E5
.7 , 6E5
.5.7E5
.3 . 8E5
.1. 9E5
-0.0E0
Time
»ro
-------
File:S975671 #1-425 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
373.8208 F:3 Exp:EPCUS
Sample
100%
—
80i
60i
40i
20i
0;
28:22
n
w
INJ. TIME
29:56
09:31 File Text:RUN 4
30:21
30:47 '
28:00 29:00 30:00
File:S975671 #1-425 Acq: 5--SEP-97 09:28:57 EI+ Voltage SIR 70S
375 . 8178 F:3 Exp:EPCUS
H2930A INJ. TIME =
29:57
Sample
100%
80.:
60 J
40j
20i
0;
Ay
\ 2S:
29:25
30:50
JL
V
INJ. TIME
29 52
28 00 29:00 30:00
File;S975671 #1-425 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
383.8639 F:3 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A
100%, n
80J
60i
40
201
0 j
09:31 File Text:RUN 4
28:00
29:00
L
09:31 File Text:RUN 4
30-00
TLI#42»
.. 5 . 7E4
L4.6E4
L3.4E4
2 . 3E4
L1.1E4
0.0E0
Time
TLI#42»
. 5.2E4
.4.2E4
.3.1E4
.2 . 1E4
.1.0E4
.0.0E0
Time
TLI#42»
-8.3E5
.6.6E5
_5.0E5
.3 . 3E5
.1.7E5
-0.0E0
Time
OO
-------
File: £>975671 #1-425 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S"
373.8208 F:3 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A _ x INJ . TIME
100% rT—i—j T i—i—i—i—I—*—i—r—i' i '"j* »—i—i——J—i—I——I—p-'r
i7.6E5
i5.7E5
3 . 8E5
1.9E5
L0 . 0E0
28:48 28:54 29:00 29:06 29:12 29:18 29:24 29:30 29:36 29:42 29:48 Time
» ro
-------
File:S975671 #1-425 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S"
389.8156 F:3 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A IN J. TIME = 09:31 File Text:RUN 4
n
100%,
80
60
40j
20i
ol
27:48
i
u
!8:56
29
41
28:00 29:00 30:00
File:S975671 #1-425 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
391.8127 F:3 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A INJ. TIME
100%
—
09:31 File Text:RUN 4
TLI#42»
.1.7E5
-1.4E5
-1.0E5
.6 .8E4
.3 . 4E4
.0 . 0E0
Time
TLI#42»
.1. 4E5
29:40
1.1E5
8 . 1E4
28:56
5.4E4
2.7E4
30:32 30:48
4 27:48
0
28:2
30:09
28:00
29:00 30:00
File:S975671 #1-425 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
401.8558 F:3 Exp:EPCUS
Sample Text:RUN 4 TLI#4293 0A
100%
80i
60
40j
20_:
0
, j
28:00
INJ. TIME
29 :40
09:31 File Text:RUN 4
J-
29:00
30:00
0.0E0
Time
TLI#42»
1. 3E6
1.0E6
.7.5E5
.5.0E5
.2 . 5E5
.0.0E0
Time
Kd
OO
-------
File:S975671 #1-425 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S"
389.8156 F:3 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A INJ. TIME
100% fl
09:31 File Text:RUN 4
TLI#42»
.1. 7E5
1.4E5
1.0E5
6.8E4
l3.4E4
0J.
28136 28:48 29:00 29:12 29124 29:36 29:48 30:00 30:12
File:S975671 #1-425 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
391.8127 F:3 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A INJ. TIME
100%/1
30:24 30:36 30:48
09:31 File Text:RUN 4
.0. 0E0
Time
TLI#42»
1.4E5
1.1E5
8.1E4
5.4 E4
A9.1S
2.7E4
28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12
File:S975671 #1-425 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
401,8558 F:3 Exp:EPCUS
30:24
I I
30 :36
30 : 48
Sample Text:RUN 4 TLI#42930A
100%
80j
60
40j
20 j
0
INJ. TIME
09:31 File Text:RUN 4
29:40
-i—|—i—rr—i r \—? i i i '» i—i—i—m—i—f
28:36 28:48 29:00 29:12
T-I I > I- 1 T"l"l 'T ¦! r i r
29124
1 rr | 1 r i—r~i—r-1—n—n—r ""i"" i- i i—t ]""i i—r—r-i—i—r—i—i—i—r—i—i—i—i—i—r
29:36 29:48 30:00 30:12 30:24 30:36 30:48
.0 . 0E0
Time
TLI#42»
.1. 3E6
1.0E6
7 5F5
. ' » *Zl J
-5.0E5
.2 . 5E5
.0.0E0
Time
CO
« OO
-
-------
File:S975671 #1-425 Acq:5-SEP-97 09:28:57
389.8156 F:3 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A_C
1002^
80j
601
40.
20j
Al .02
EI+ Voltage SIR 70S
INJ. TIME
r^r
r I1" i I r r | i *r i f -i "i r~t r
29:00 29:06 29:12 29:18 29:24 29:30
09:31 File Text:RUN 4 TLI#42»
6.4E5
.5 . 1E5
.3 . 8E5
L2.6E5
1.3E5
*r*i—r*]" i—i—!—i—(—| Pi "l ' I "I |—i—r
29:36 29:42 29:48
L0.0E0
i ) r I1" i i t i-i I ( n i -f—[tt-t i i -i
29:54 30:00 30:06 30:12 Time
INJ. TIME =
File:S975671 #1-425 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
391.8127 F:3 Exp:EPCUS
Sample Text:RUN 4 TLI#42 93QA._.-—^
100% CaI-|8E6>
80.
60 j
40
20.
0
-"fi") ,"i iii-ii | , i
29:00 29:06
29 :12
A9 .
18 29:24
SEP-97 09
File:S975 671 #1-425 Acq
401.8558 F:3 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A
100* 29^1829;22
80i
60i
40i
20i
29:30
28:57
09:31 File Text:RUN 4 TLI#42»
.4.9E5
;_3 . 9E5
3 . 0E5
12.0E5
L9.9E4
"I—1—!~T r—i—i—i—i—| -ir^—I I '""I ""T I—r
29:36 29:42 29:48
EI+ Voltage SIR 7 0S
L0.0E0
J' I i j—i—I—1—I—I—. -t T f' T I ;
29:54 30:00 30:06 30 i12 Time
INJ. TIME =
0
29:40
t—r-1—i -i | i—I—I ""I I—|—r-r=r—i—i—i—i—i—i—i—r—i—i I I I i i i >
29:00 29:06 29:12 29:18 29:24 29:30
09:31 File Text:RUN 4 TLI#42»
1.4E6
Ll.1E6
8.4E5
i5.6E5
L2.8E5
1—I I l l "1—I r i—I IfT-i \ | 1 H1
29:36 29:42 29:48
.0 . 0E0
~ri—[—i—i—i—i—i—|—i—% -i i—i—j—r~i—i—i—i—r
29:54 30:00 30:06 30:12 Time
»*\3
1 00
00
-------
File:S975671 #1-390 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
407.7818 F:4 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A INJ. TIME
100% 31 20
09:31 File Text:RUN 4
80 j
60
40 j
20
0
31:41
31:32
31:59 32:16
32 : 59
32:29
33:23 33:35 33:48 34-04
A__
34 :00
32:00 33100
File:S975671 #1-390 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
409.7789 F:4 Exp:EPCUS
Sample Text: RUN 4 TLI#42930A INJ. TIME = 09:31 File Text: RUN 4
100% 31;20
80i
60
40 j
20
31:40
31:32
33 :25
33:48 34:03
32:00 33:00 34 :00
File:S975671 #1-390 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
417.8253 F:4 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A INJ. TIME = 09:31 File Text:RUN 4
100% 31:19
80j
60 J
40
20 J
oJ
32 :31
-r^—"—r
32 :00
32:32
31:53
32 : 58
~l|l .IT..P 1 ^ <1 1 «l A'jUITP
33 :00
1 r" —r"
¦
1 T-
34 :00
TLI#42»
.8.1E4
.6 . 4E4
.4 . 8E4
l3 .2E4
Ll.6E4
-0.0E0
Time
TLI#42»
.1.0E5
.8 . 4E4
.6. 3E4
.4 . 2E4
.2 . 1E4
0.0E0
Time
TLI#42»
.3 . 7E5
.3 . 0E5
.2 . 2E5
.1.5E5
J . 5E4
.0.0E0
Time
1 OO
-------
File:S975671 #1-390 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S-
407.7 818 P:4 Exp:EPCUS
Sample TQxtr -RLJN 4 TLI#42930A INJ. TIME
100% ^J2"40E5,
80i
60s
40
20
32:00 33:00
File:S975671 #1-390 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
409.7789 F:4 Exp:EPCUS
Sample Tgxfc^tPN 4 TLI#42930A INJ. TIME
100%
09:31 File Text:RUN 4 TLI#42»
8.1E4
L6.4E4
i4.8E4
3 . 2E4
1. 6E4
34 :00
Lo.oeo
Time
09:31 File Text:RUN 4 TLI#42»
^l.OES
l8.4E4
id.3E4
"_4 . 2E4
2 . 1E4
32:00 33:00
File:S975671 #1-390 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
417.8253 F:4 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A INJ. TIME
100%
34:00
_0 . 0E0
Time
80
60
40j
20i
0s
31:19
32 :31
32 :00
09:31 File Text:RUN 4 TLI#42»
3 . 7E5
:..3 . 0E5
2 . 2E5
1. 5E5
L7.5E4
33 : 00
34 : 00
L0.0E0
Time
fO
'CO
O
-------
File:S975671 #1-390 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
441.7428 F:4 Exp:EPCUS
Sample Text: RUN 4 TLI#42930A INJ. TIME = 09:31 File Te : RUN 4 TLI#42»
100% 34 45 35
80s
60 J
40J
20
0J
33 :06
33 :34
32 :38
i 1 1 r
T
r~
35:25
xh
1 . 3E4
ll.0E4
7 . 8E3
l5.2E3
-2 . 6E3
0 .0E0
Time
33:00 34:00 35:00
File:S975671 #1-390 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
443.7399 F:4 Exp:EPCUS
Sample Text:RUN 4 TLI#4293 0A INJ. TIME = 09:31 File Text:RUN 4 TLI#42»
100%, 34:45 _1.2E4
34:07 I
35:31
80j
60J
40J
20J
0j
33 :24
3 : 52
2:49
34:35
35 : 50
35 :19
1 1 r
33 :00
"¦ 1 1
34 : 00
_1
i9.9E3
l7.4E3
4.9E3
l2.5E3
L0.0E0
3 5:00 Time
File:S975671 #1-390 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
469.7779 F:4 Exp:EPCUS
Sample Text:RUN 4 TLI#42930A INJ. TIME = 09:31 File Text:RUN 4 TLI#42»
100% 3 4; 3 7 _3.8E5
80j
60
40j
20J
0J
-r— 1 r
33 :00
, 1
34 :00
y.—
35:00
:.3 . 0E5
12.3E5
Ll.5E5
l7 . 5E4
.0.0E0
Time
•X)
» O
-------
File:S975671 #1-390 Acq:5-SEP-97 09:28:57 EI+ Voltage SIR TOS^
457.7377 F:4 Exp:EPCUS
Sample Text: RUN 4 TLI#4293 0A INJ. TIME
100% C"A2 .'17E5>
09:31 File Text:RUN 4 TLI#42»
7 . 4E4
5 . 9E4
4 . 4E4
3 . 0E4
1. 5E4
j=p-r>-i"T.T'ri—|—i
-t—r—t—|—r
34:48
i—r~r~
35 :00
33148 34:00 34:12 34:24 34:36
File:S975671 #1-390 Aeq:5-SEP-97 09:28:57 EI+ Voltage SIR 70S
459.7348 F:4 Exp:EPCUS
Sample Text: RUN 4 TLI#42930A INJ. TIME
100% ^ ^ —i—| T i—r—^ [ j i i—**
•\3
» Co
<*o
-------
Eastern Research Group
TLI Project: 42930A
Client Sample: RUN4
Client Project:
Sample Matrix:
TLI ID:
Iron & Steel-Youngstown
M23TRAIN Date Received:
179-98-6A-D Date Extracted:
Date Analyzed:
08/19/97
08/25/97
09/06/97
Spike File:
ICal:
ConCal:
SPC2NF04
XF24087
X973009
Sample Size:
Dry Weight:
GC Column:
1.000
it/a
DB-225
Dilution Factor:
Blank File:
Analyst:
n/a
S975665
ML
% Moisture:
% Lipid:
% Solids:
n/a
n/a
n/a
Amt. (n
BlllliiilP
RT Flags
2,3,7,8-TCDF
12.8
0.76
23:00
internal Standard
Amt. (ng) % Recovery QC Limits
Ratio
RT Ffags
'3C!2-2,3,7,8-TCDF
3.4
84.5
40%-130%
0.76
22:59
Method 23 TCDD/TCDF Analysis (DB-225) I
Analysis File: X973017
I
I
I
I
I
I
I
I
I
I
I
I
1
I
I
I
Recovery Standard
Ratio
RT
Flags
>3Ci2-U,3,4-TCDD
0.80 21:58
Data Reviewer,
09/08/97
Page 1 of 1
C2NFJ>SR vlOft LARS 6.10.0*
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:58 09/08/97
293
-------
Data Review By:
Initial
.... Date...
Calculated Noise Area; n/a
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
09/03/97
Listing of X973017B.db£
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z. . . . QC.Log Omit Why
TCDF
304-306
DC
DC
NL
WL
304-306
. -RT.
OK
Ratio
Total.Area. . .
Area.Peak.1..
Area.Peak.2. .
Rel.RT
0
65-0.89
0.798-1.1
0
00
RO
1.34
22.25
0. 000
18
14
RO
7.32
2,574.52
0.793
18
38
RO
4.18
I,086.09
2.564.75
613.51
0.811
18
45
RO
0.96
39,385.53
21,529.70
22,534.20
0.316
18
57
RO
1.20
202.49
137.19
114.40
0. 325
19
07
0.76
315.34
136.45
179.39
0.832
19
11
RO
1.43
103.07
83.21
53.23
0.835
19
41
0.~6
74.860.80
32,303.20
42.557.50
0.356
19
46
0.76
47,670.70
20.653.30
27,017,40
0.360
19
54
0.76
75,143.60
32,466.70
42 .676.90
0.366
20
03
0.76
43.441.60
13,736.90
24,704.70
0. 372
20
21
0.7"
35,158.00
15,271.70
19.386.30
0.835
20
28
0.76
65.910.40
28,562.20
37,343.20
0.891
20
37
o.-s
28,711.60
12,313.00
16,398.50
0. 397
20
45
0.74
122,015.50
51.996.20
70,019.30
0. 903
20
54
0.76
25.433.00
10,944.40
14.438.50
0.909
21
14
RO
0.48
72.360.56
31,696.40
65.948.30
0. 924
21
41
0.76
73.972.10
31.924.70
42,047.40
0 . 943
21
55
0.76
43,933.90
13,999.10
24,934.30
0.954
22
07
0.74
48,069.00
20,497.20
27.571.80
0.962
22
19
0.32
4,199.58
1.388.07
2,311.51
0. 971
22
28
0.78
33,141.40
14,499.60
18,641.80
0.978
22
52
0.78
29,328.30
12,324.30
16.504.50
0.995
23
00
0.76
30,315.50
13,064.60
17.250.90
1.001
23
12
0.76
27,633.70
11,968.40
15,665.30
1.009
23
29
0.31
25.007.50
11,157.60
13,849 .90
1.022
23
36
0.73
42,264.70
17,773.90
24,490.30
1. 027
24
23
0.76
19,155.49
3,282.29
10.873.20
1.061
25
08
0.68
2,236.79
907.21
1,329.58
1.094
Peaks
1,012,057.24
. Rel.RT Compound. Nair.e. . ID.. Flags.
m
13C12-TCDF
316-313
316-318
0
65-0.89
0.956-1.044
DC
NL
0:00
RO
2.07
26
35
0.000
DC
WL
18: 18
RO
3.19
70
80
0.796
DC
WL
18: 31
RO
3.38
57
37
0.806
DC
WL
18:35
0.55
308
40
0.809
DC
WL
13: 56
RO
1.34
21
34
0. 824
DC
WL
19:13
RO
1.43
31
95
0.836
DC
WL
19:24
RO
2.33
31
21
0. 844
22:59
0.76
9,801
45
4,236.12
5,565.33 1.000 13C12
DC
WH
25:02
RO
0. 98
88
15
1.089
1
Peak
9,801
45
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:58 09/08/97
294
-------
Page No.
09/08/97
Listing of X973017B.db£
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z .... QC.Log
Omit
Why
. .RT.
OK
Ratio
Total.Area.. .
Area.
. Peak.1..
Above: TCDF /
TCDD
Follows ¦
13C12-TCDD
0.
65-0.as
332-334
DC
NL
0:00
RO
3.85
2.69
DC
WL
19:16
RO
3.96
2.96
DC
WL
19:36
RO
1.71
8.94
DC
SN
19:48
RO
• 2.19
4.50
DC
SN
19:53
RO
1. 37
9.31
DC
SN
20:31
RO
11.48
1.91
20: 38
RO
1.14
39.35
25.37
DC
SN
20:44
RO
2.21
7.40
21:41
0.79
6,975.52
3,088.3 5
21:58
0.30
3,336.86
3,700.29
22:37
RO
0.92
94.37
49.53
23:33
RO
1.09
14.30
3.33
DC
WH
24: 05
RO
1.08
12.21
DC
WH
24:34
RO
1.64
4.76
332-334
5
Peaks
15,460.90
0.907-1.093
0.000
0,389
0.904
0.913
0. 917
0.946
22.23 0.952
0.956
3,387.17 1.000 13C12-2378-TCDD IS1
4,636.57 1.013 13C12-1234-TCDD RSI
53.60 1.043
8.08 1.086
1.111
1. 133
Column Description "Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
. .F.T. -Retention Time !tmzss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
End of Report
vfiL-3eiow Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
\Pilm:X973Q17 $1-I2BS Acq: S-3BP-1997 23,54:03 X SI* Volbmgm MIS Auf63p»
-------
PilmtO73017 il-JLSSS Acqt 6-SSP-1997 23ti4t03 OC SI* Voltmgm SIR XutoSpme SolmmtMU
303.9016 BSOB(256,30,-3.0) PXD(5,3,1, 0.10%, 33696.0, 0. 00%,*,*) SSp*,KMSF_f*
Smwplm nurttltCS* TLX§42930A Film Tmxtt TXXAMLX LABS
IOC* JUS.? 0X9
sac
so:
40:
20c
A3.35MB
A3.ISMS
dX
A3.19M8
A2.05M8
A1.45X8
A1.31X8
.7 SMS
AS.38X7
I. ,1 l| [| »|..| l| I,> ! * I t y l"l' l» '! I'l ' I " I 'I' I1 I' I I
IStOO 30t00 SltOO 33tOO 23<00 24>00 25>00
*ilm>X973017 01-1285 Actjt 6-SMP-1997 23t54t03 OC SI* Voltmgm SIX AutoSpme Bolmmi S285
305.8987 BSUX (256, 30,-3.0) *KD(5,3,1,0.10%,25140.0.0.00%,*,*) XzptXCOSXjrT
Saoplm Tmxt :X0N4 TLI§42930A *ilm Tmxtt TXXAMLX UBS
100k
.1.2M8
.9.2X7
.6.9X7
.4.6X7
.2.3X7
.0.0X0
Timm
19'tOO 20t00 21 too 22 >00 23 >00 24>00 25t00
*ilm>X973017 §1-1285 Aeqt 6-SXP-1997 23>54t03 OC XX* Voltage SIX AutaSpmc Xoimrnt15706
315.9419 BSOB(256,30, -3.0) PKD(5,3,1, 0.10%, 62824.0,0. 00%,*,*) XxptXCON*_Tr
Smaplm TrnxttSm4 TLX142930A Film Tmxtt TBXABOLX UBS
iom
so:
60L
40.
20.
19s00 20t00 21>00 22>00 23>00 »4t00
*ilmsX973017 §1-1285 Aaqi 6-3XP-1S97 23t54t03 OC XI* Voltmgm SIX AutoSpme Soimm>7584
317.9389 BSOB(256,30, -3.0) *XD (5,3,1,0.10%, 30336. 0, 0.00%, *, *) XxptXCOSXJTT
Smmlm TmxttX0S4 TLX§42930A *ilm tmxtt TXXAXOLX LABS
1.5E8
1.2X8
A4.27X8
A4.20X8
9.2X7
A2.76XS
A2.25X8
6.1X7
A2.45X8
A1.86X8
A1.6
3.1X7
A1.09X8
A4.24X7
fllQi •{*">¦
0.0X0
Timm
9.7X6
,7. 7X6
.5.8X6
.3.9X6
.1.9X6
IX
i p'"
25 tOO
.0,0X0
fimm
100*
80.
60.
401
20.
0.
AS.57X7
-!-=V
TTT
"T"
f I" 1
-4-
.1.2X7
.9.9X6
.7.5X6
.5.0X6
L2.5X6
19 too 20>00 21i00 22t00 23:00 24t00
XilmtX973017 §1-1285 Aoqt 6-SXT-1997 23t54t03 OC XX* Voltmgm SIR AntoSpmc
375.8364 XxptXCOB* TT
Smmplm Tmxttmm4 TLX§42930A *ilm Tmxt> TBXABOLX LABS
r ' ¦
25 tOO
.0.0X0
Timm
2001
80'1
601
4o:
20.
18t40
20:45
i—| • i
19t00
20t00
i i r
2UOO
i i ' i '¦
22100
.3.3X5
12.7X5
12.0X5
1.3X5
6.7X4
,0.0X0
23 tOO
24 tOO
25t00
I
I
I
I
I
I
297 |
-------
Pllm:Z973017 *1-12B5 Acq* S-3SP-1397 S3*bit03 X SI* Volbagm SIR XukoSpec Nolmm:2737
319. 8965 BSUB(256.30.-3.0) PKD (5,3,1, 0.10*, 10948. 0, 0. 00*,P,P) Xxp:XCORF_rT
Sample Trnjct:RUS4 TLX04293OA Film Text: TBIANBLX LABS
1001 XI. 1X7
20:00 22x00 22:00 23:00 24:00
Pllm:X973017 01-1285 Acq: 6-SXP-1997 23iS4t03 QC XX* Voltage SX11 AutoSpmc Sol Bet 18270
321.8936 BSOB(256,30,-3.0) PKD(5,3,1, 0.10*, 73080.0, 0. 00*,P,P) BxptXCOBP_TT
3amp la TextlRUN4 TLI04293OA Pile Text: TRIANQLX LABS
20:00 21:00 22:00 23:00 24:00
Pilm:X973017 01-1285 Aaj: 6-SXP-1997 23:54:03 OC PI* Voltagm SIR AutoSpeC Holme:1706
327.8847 BSUB(256,30,-3.0) PKD(5,3,1, 0.10*, 6824. 0, 0.00*,P,P) Sxp:ZCOSP_TT
Sample Text:RUN4 T.LI*4293OA Pile Text: TRXANQLX LABS
80L
401
20.
A1.41S7
A1.24B7
A9.98X6
A7.85X6
A6.19X6
14.54X6
A1.76X6
A
A2.87X6
4.
.3.
:J2.
u.
18.
. K .F.
.0X6
.2X6
.4X6
.6X6
.0X5
.0X0
Time
ion
80i
601
40.
20.
0.
A1.62X7
A1.73X7
I
A1.12X7
ft
, J JI
A1.28X7
A1.74X7
A1.40S7,
A1.02X7
6. 74X6
A2.82S6
.29X6
A2.40X6
100.*
80.
601
401
20.
A6.61X7
A1.10E7
AS. 17X6
/AATa
AS.19X6
A4.07X7
A1.99X7
T
I
~r
7X7
4X7
20:00 21:00 22:00 23:00 24:00
Pllm:X973017 01-1285 Acq: 6-SXP-1997 23:54:03 OC XX* Voltagm SIR AutoSpec Holme:2926
331.9368 BSUB(256,30,-3.0) PSD(5,3.1.0.10*. 11704.0,0.00*.P,P) Xxp:XCC8P_TT
Sample Tmxt:RVS4 TLX04293OA Film Text: TRXANQLB LABS
100*
1.0X7
7.0X6
3.5X6
0.0X0
Time
9.7X6
A3.09X7
7.8X6
.5.8X6
.3.9X6
1.9X6
I i i i 'i i | i i i ' i I1 i i i *i i |
20:00 21:00 22:00 23:00 '
Pile:XS73017 01-1285 Acq: 6-3XP-1997 23:54:03 OC XX* Voltagm SIX AutoSpmc Nolmm:758
333.9338 BSVB(256,30, -3.0) PKD(5,3,1, 0.10*, 3032. 0, 0. 00*,P,P) Sxp:XCOSP_TT
Sample Tmxt:KOS4 TLX04293OA Film Text: TRIAEQLX LABS
24:00
lOOi
801
60:
40.
2C0
0.
A4.64X7
A3.89X7
,.1.2X7
9.6X6
7.2X6
.4.8X6
12.4X6
20:00
21:00
22:00
23:00
' I '
24:00
.0. 0X0
Tlmm
9Q£
-------
Pllm:XS73Q17 *1-1285 Acq: 6-SSP-1S97 23:54:03 OC EI* Voltag* SIR AutaSp«c
303.9016 XxptXCOSF IT
Saxplm Tmxt tSmi TLX*42930A Film Tmxt: TXXAtKJLX LABS
20x45
-1.2X8
9,3X7
19:54
21114 211 ml
6.9X7
22 >07
18t45
4.6X7
23:00 A
mA
12.3X7
- 0.030
19:00 20:00 21:00 22:00 23'tOO 24:00
FilmtX973017 *1-1285 Aaqt 6-SBF-1997 23t54t03 OC MX* Voltmffm SIS AatoSpma
31S.9419 Exp:XCOBP_TT
Saxplm TmxtsXtm4 TLX*42930A FIX* Tmxtt TXXAmLS LABS
100Ij 22,39
80.
60.
40.
2«4
J-
19s00 20':00 ' ' 21:00 22x00 23:00 24:00 25'tOO
FilmtX373017 *1-1285 Aoqt 6-SBF-1997 23:54:03 OC EX* Voltagm SIR AatoSpmc
319.8965 Bxp:XCONF_TT
Smsplm TmxttXm4 TLX*42930A Film Tmxtt TXXAmLS LABS
100* 20:38
19:28
25 tOO
"O 1 i | i" i" i
I I I 1 I" I I
Timm
.9.7X6
.7.7X6
.5.8X6
.3.9X6
.1.9X6
.0.0X0
Time
4.0X6
3.2X6
20t00
2.4X6
22 s 01
1.6X6
8.1X5
24t22
JL 24,54
23 s 22
18135
ikL
19il0
0.0X0
19s00 20:00 21:00 22:00 23i00 24s00
FilmsX973017 *1-1285 Aaqt 6-SXP-1997 23t54t03 OC XX* Voltagm SIR AutoSpme
331.9368 SxpxXCOKF_TT
Samplm fmxttsm4 TLX*42930A Film Tmxtt TBXABBLB LABS
25x00
200
80A
60i
4C
20i
21:58
21x41
J
u
Timm
9.7X6
7.8X6
5.8X6
3.9X6
1.9X6
-r—1—r-
23x00
i i lit i i i 1 i "i I i i" i "r i | i I "i ' i w i' I i i ¦!
19x00 20x00 21x00 22:00
FllmtX973Q17 *1-1285 Acqx 6-SBP-1997 23t54x03 OC XX* Voltagm SIX AatoSpmc
292.9825 XxpxXC08P_TT
Samplm TmxttXm4 TLX*42930A Film Tmxtt TXXUBU LABS
100K 18129 18:56 19x28 19t54
i i i | 1 i
24x00
' 'I
0. 0X0
25x00
Tism
_3.2S7
6S7
1.9X7
T
19:00 20x00 21x00 22x00 23:00 24x00
FllmtX973017 *1-1285 Acqs 6-SXP-1997 23x54:03 OC XX* Voltagm SIX AmtoSpma
330.9792 XxptXXXMFJTT
Saaplm TmxttBXOI4 TLX*42930A Film Tmxtt TXXAmLS LABS
-r
25:00
-1.3X7
L 6.4X6
0.0X0
Timm
loon
23x39 24x17
22x31
3102
18:26 28*55
—4.QX7
3.2X7
.2,4X7
¦ 0X0
19x00
20x00
21x00
22 tOO
23x00
24t00
25x00
Timm
9
-------
Volts
0.3448
Volts
0.3744
Volts
0.2786
PPM
200
PPM
200
PPM
200
—> .a m r %*L
380.93795 380.97604 381.01414
292.95315 292.98245 293.01175
330.94615 330.97925 331.01235
I
-------
TLI Project: 42930A Method 23 PCDD/PCDF Analysis (a)
Client Sample: RUN5 Analysis File: S975672
Client Project:
Iron & Steel-Youngstown
Sample Matrix:
M23TRAIN
Date Received:
08/19/97
Spike File:
SPX23704
TLI ID:
179-98-7A-D
Date Extracted:
08/25/97
ICal:
SF56117
.
Date Analyzed:
09/05/97
ConCal:
S975664
Sample Size:
1.000
Dilution Factor:
n/a
% Moisture:
n/a
Dry Weight:
n/a
Blank File:
S975665
% Lipid:
n/a
GC Column:
DB-5
Analyst:
HLM
% Solids:
n/a
01-, ' EMPC . Ratio RT Flags
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1.2.3.6.7.8-HxCDD
1.2.3.7.8.9-HxCDD
1,2.3,4,6,7,8-HpCDD
1,2,3,4,6,7,8,9-OCDD
2,3,7,8-TCDF
1,2,3,7.8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2.3.4.6.7.8-HxCDF
1.2.3.7.8.9-HxCDF
1.2.3.4.6.7.8-HpCDF
1.2.3.4.7.8.9-HpCDF
1.2,3,4,6,7,8.9-OCDF
Total TCDD
Total PeCDD
Total HxCDD
Total HpCDD
Total TCDF
Total PeCDF
Total HxCDF
Total HpCDF
I
X237JPSR vZOO. LARS 6.1005
Printed: 17:14 09/08/97 m
301 - 1
0.43 0.70 21:46
1.2 1.54 26:11
EMPC 0.14
1.8 1.26 29:24
0.73 1.12 29:42 ffL
0.77 0.94 32:11
0.33 0.78 34:39
37.8 0.84 21:02
4.0 1.50 25:07
3.8 1.48 25:50
1.6 1.31 28:37 PR_
0.58 1.26 28:44
0.32 1.32 29:13 PR_
0.06 1.29 29:55
0.34 1.03 31:21
ND 0.2
ND 0.4
10.7
13
10.9
11.3
10
14.5
17.4
6
17.6
2.3
2
335
14
345
59.7
14
60.0
6.5
12
6.8
0.34
1
I
I
I
Page 1 of 2
Triangle Laboratories, Inc.®
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
-------
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Eastern Research Group
TLI Project:
Client Sample:
42930A
RUNS
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975672
| internal Standards
Amt {ng}
% Recovery
QC Limits
Ratio
RT
Flags
13Ci2-2,3,7,8-TCDF
4.0
100.0
40%-130%
0.74
20:59
13C',i-2,3,7.8-TCDD
3.5
88.1
40%-130%
0.83
21:45
I3C,2-1,2.3,7,8-PeCDF
2.4
59.5
40%-130%
1.75
25:05
,3C,2-1,2.3,7,8-PeCDD
1.7
42.1
40%-130%
1.39
26:11
*3C,:-1,2.3,6.7,8-HxCDF
4.8
119
40%-130%
0.52
28:42
:3C.;-1.2.3.6.7.8-HxCDD
3.9
98.3
40%-130%
1.16
29:24
!3C,r 1.2,3.4,6.7.8-HpCDF
2.4
60.6
25%-130%
0.42
31:21
;3C-.;-1,2,3,4.6.7,8-HpCDD
2.4
59.9
25%-130%
1.07
32:11
13C,r 1,2.3.4,6.7,8,9-OCDD
3.6
44.4
25%-130%
0.95
34:38
—
1 Surrogate Standards (Type A)
Amt. (ng)
% Recovery
QC Limits
Ratio
RT
Flags
CL7 . ,8-TCDD
3.8
94,3
70%-140%
21:46
1!Ci:-2,3.4.7.8-PeCDF
3.6
88.8
70%-140%
1.58
25:49
:3C,2-l,2.3.4,7.8-HxCDF
4,3
109
70%-140%
0.50
28:37
¦3C;;-1,2,3,4,7,8-HxCDD
4.1
102
70%-140%
1.28
29:20
l3Ci;-l,2,3,4,7,8,9-HpCDF
3.7
93.5
70%-140%
0.37
32:31
—
1 Alternate Standards (Type A)
Amt. (ng)
% Recovery
QC Limits
Ratio
RT
Flags
13Cn-l,2,3,7,8,9-HxCDF
4.4
109
40%-130%
0.50
29:54
13C;;-2,3,4,6,7,8-HxCDF
4.4
111
40%-130%
0.51
29:12
—
1 Recovery Standards
Ratio
RT
Flags
13C,2-1,2,3,4-TCDD
0.86
21:32
13C,2-1,2.3.7,8,9-HxCDD
1.22
29:42
Data Reviewer ^ a. -L>, >
-2jQ_
09/08/97
Page 2 of 2
X23T.PSR vlOO. LARS 6.10.01
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:14^^08^97
-------
Initial
..,Dace...
Data Review By:
X'S./i?
Calculated Noise Area;
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
4.64
Page No.
09/03/97
Listing of S975672B.dbf
Matched 3C Peaks / Ratio / Ret. Time
Cottpound/
QC.Log Omit Why . .RT. OK .Ratio Total.Area.
Area.Peak.1.. Area.Peak.2.. Re1. RT Compound.Name. . ID.. Flags.
TCDF
304-306
0.65-0.89
0.327-1.099
DC NL
304-306
0:00
0
77
11.25
0.000
17:41
0
82
8,480.00
3,810.00
4,670.00
0.843
18:10
RO
0
92
6,114.18
3.170.67
3.454.34
0.366
18:25
0
38
3,593.16
1,678.53
1,914.63
0.873
18:51
0
32
37,399.00
16,905.50
20,493.50
0.398
19:12
0
35
24,112.70
11.110.30
13,002.40
0.915
19:35
0
85
21,699.71
9,960.91
11,738.80
0.933
19:53
0
83
16,955.72
7,675.55
9.280.17
0.948
20:12
0
83
23,850.30
10.342.90
13.007.40
0.963
20:33
0
33
13,724.42
6,234.16
7,490.26
0.979
20:49
0
36
9,036.59
4.177.09
4.859.50
0.992
21: 02
0
34
22,087.90
10,102.80
11.985.10
1.002 2373-TCDF
21:27
0
34
8,498.13
3,380.15
4.617.98
1. 022
21:40
0
84
4,626.50
2,114.42
2,512.03
1.033
21:54
0
37
801.41
373.91
427.50
1.044
22:15
RO
1
28
55.67
40.16
31.45
1.060
22:47
0
80
488.97
217.40
271.57
1.036
Peaks
201.524.36
AN
13C12-TCDF
316-313
316-313
DC
DC
NL
VJL
0
18
20
0.65-0.89
:00 RO 25.93
:02 RO 35.07
59 0.74
1 Peak
2.99
5.36
.866.68
,866.68
796.51
0.952-1.043
0.000
0.859
1,070.07 1.000 13C12-2378-TCDF ISO
Above: TCDF I TCDD Follows
TCDD
320-322
DC NL
0.
65-0.89
0.861-1.058
0:00
RO
6.75
15.31
0.000
19:05
0.32
500.78
225.21
275.57
0.877
19:28
0.73
321.35
135.66
185.69
0.895
19:46
0.78
289.55
126.69
162.86
0.909
20:31
0. 31
864.82
386.90
477.92
0.943
20:43
0.76
467.00
201.00
266.00
0.952
20:54
0.31
140.25
62. 53
77.67
0.961
21:12
0.73
280.93
118.75
162.18
0.975
21:29
0.80
331.22
146.93
184.29
0.988
21:33
0.30
345.57
153.09
192.48
0.995
21:46
0.70
168.39
69.40
98.99
1,001 2378-TCDD
21:55
0.79
129.79
57.15
72,64
1.008
22:06
0,75
306.98
132.04
174.94
1.016
22:19
0.81
77.90
34.90
43.00
1.026
22:46
RO
0.95
96.43
51.50
54.48
1.047
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:15 09/08/97
-------
Page No.
09/03/97
Listing of S97S672B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
320-322
37C1-TCDD
328
328
13C12-TCDD
332-334
332-334
3mit
Why
. ,RT.
OK
Ratio Total
.Area... Area
Peak.1., Area
Peak.2..
ReX.RT Compound.Name..
14
Peaks
4. 320.96
0.907-1.093
DC
ML
0
00
1.82
0. 000
DC
WL
18
29
91.69
0. 350
DC
ML
18
37
1.87
0. 356
DC
WL
18
49
4.11
0.365
DC
WL
19
01
2.66
0.374
DC
WL
19
17
3.22
0.337
DC
WL
19
26
11.96
0. 393
19
45
3.95
3.95
0. 903
DC
SN
19
55
1.76
0.916
20
15
874.46
874.46
0.931
20
31
10.66
10. 66
0. 943
DC
SN
20
37
1.37
0.943
DC
SN
20
46
1.69
0.955
20
53
4.31
4.31
0.960
DC
SN
21
01
2.54
0. 966
DC
SN
21
04
0.57
0.969
21
21
4.07
4.07
0.974
DC
SH
21
25
1.85
0.935
DC
SN
21
29
1.78
0. 933
DC
SN
21
30
1.17
0 . 939
21
46
1,057.81
1.057.31
1.001 37C1-TCDD
DC
SN
21
58
2.53
1 . 010
22
T_ 1_
1,066.03
1,066.03
1. 020
22
35
3.06
3.06
1.033
22
41
3.46
8.46
1.043
22
53
11.68
11.68
1.052
23
08
9 .04
9.04
1. 064
11
Peaks
3 ,053,53
0
65-0.39
0.907-1.093
DC
ML
0
00
RO
13 .77
0.39
0. 000
DC
WL
18
38
RO
1.02
2 . 53
0.357
DC
WL
18
48
RO
3 .08
1.52
0.364
DC
WL
19
38
RO
2 .47
2.11
0.903
DC
SN
19
51
RO
6.57
0.83
0.913
DC
SN
19
55
RO
2.60
1.19
0.916
DC
SN
20
17
RO
2.41
1.33
0.933
20
32
RO
1.25
11.38
8.02
6.43
0. 944
DC
SN
20
52
RO
1.62
4.73
0. 959
21
32
0.86
1.416.89
654.49
762.40
0.990 13C12-1234-TCDD
21
45
0.83
1,330.72
604.22
726.50
1.000 13C12-2373-TCDD
22
05
RO
0.96
21.19
11.48
11.97
1.015
DC
SN
22
36
RO
3 .46
4.67
1.039
23
04
RO
2.44
5.15
7.09
2.91
1. 061
S
Peaks
2,785.33
SUR1
Above: TCDD / PeCDF Follows
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:15 09/08/97
304 -
-------
Page No. 3 Listing of S9756723.db£
09/08/97 Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log Omi t
Why
. ,RT.
OK
Ratio Total.Area,.. Area
Peak.1.. Area
Peak.2..
Rel.RT Compound.Name. .
PeCDF
1.
32-1.78
0.910-1.076
340-342 DC
NL
0: 00
RO
0.12
0.21
0.000
DC
WL
22:49
RO
0.52
156.31
0.910
23:06
1.47
2.276.24
1,353.41
922.33
0.921
23:51
1. 52
60.79
37.59
23.20
0.951
24:06
1.51
1,004.40
604.81
399.59
0.961
24:15
-1.53
5,061.11
3,063.49
1,997.62
0.967
24:25
1.41
928.77
543,14
385.63
0.973
A
24:37
1. 58
341.00
209.00
132.00
0.981
A
24: 53
1.44
1,253.00
740.00
513.00
0.992
A
25:01
1.60
475.00
292.00
183.00
0.997
a
25:07
1.50
1.059.00
636.00
423.00
1.001 12378-PeCDF
25:16
1.42
609.34
357.48
251.36
1. 007
25:23
1.50
937.49
561.89
375.60
1.012
25:50
1.48
1,019.30
608.50
410.80
1.030 23473-PeCD?
25: 59
1.45
768.69
455.57
313 .12
1. 036
26:16
1.37
31.65
47.26
34.39
1.047
26:48
RO
1.26
75.74
46. 04
36.45
1. 068
DC
SN
26: 57
RO
1. 31
3.32
1.074
340-342
15
Peaks
15,951.52
13C12-PeCDF
1
32-1.78
0.
340-1.160
352-354 DC
NL
0:00
RO
0.65
0.25
0,000
DC
SN
23:26
RO
4. 34
2.01
0.934
DC
SN
24:17
RO
4.80
2.09
0.963
DC
SN
24:50
RO
1.96
5.13
0.990
25:05
1.75
955.91
608.39
347.02
1.000 13C12-?eCDr 123
25:25
RO
2.87
22.36
25.18
3.77
1.013
25:38
1.74
14.18
9 .00
5.13
1.022
25:49
1.58
823.34
504.53
313.76
1.029 13C12-PeCDF 234
DC
SN
26:25
RO
0.54
2.24
1.053
DC
SN
26: 55
RO
2.30
1.76
1.073
352-354
4
Peaks
1,315.79
ID.. Flags.
AN
AN
Above: PeCDF / PeCDD Follows
PeCDD
356-358
A
A
DC NL
DC SN
DC HH
1.
32-1.73
0.923-1.025
0:00
RO
0.66
2.04
0.000
24:22
RO
1.18
353.65
218.00
185.00
0.931
24: 38
RO
0.01
0.84
0.941
24:55
1.32
53.30
30,30
23.00
0.952
25:07
1.55
438.28
266.59
171.69
0.959
25:14
1.40
151.40
88.37
63,03
0,964
2S: 25
1.62
167,34
103.88
63.96
0.971
25:35
1.64
106.44
66.13
40.31
0.977
25:40
1.66
133.63
83,46
50.22
0.980
25:53
1.43
34.37
20.52
14.35
0. 989
26:01
RO
0.30
19.79
12.03
39.45
0.994
26:11
1.54
141.21
85.52
55.69
1,000 1237 8-PeCDD
26:20
1.51
58.76
35.33
23.43
1.006
26:42
1.60
61.91
38.13
23.78
1. 020
26:56
RO
1.07
2.35
1.029
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:15 09/08/97
305 '
-------
Page No. 4
09/03/97
Listing of 3975672B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why ..RT. OK Ratio Total.Area... Area.Peak.1. . Area.Peak.2.. Rel.RT Compound.Name. . ID.. Flags.
356-358
12 Peaks
1,726.13
13C12-PeCDD
363-370
1.32-1.78
0.847-1.153
363-370
DC
NX.
0:00
RO
0 . 94
0.28
0.000
DC
SN
24:36
RO
0 . 96
0.81
0.940
DC
SN
24: 37
RO
2 . 96
0.61
0. 940
DC
SN
24:46
RO
- 0. 10
0.18
0.946
DC
SN
25:23
RO
3 . 04
1.71
0 . 969
DC
SN
25:47
RO
0.89
2.86
0.935
DC
SN
25:53
RO
0.13
0.94
0. 989
26: 11
1.39
379.09
220.48
158.61
1.000
26:19
1.46
54.91
32.55
22.36
1.005
DC
SN
2
26:44
Peaks
1.72
5.66
434.00
1.021
Above: PeCDD / HxCDF Follows
HxCDF
374-376
A
M
MK
374-376
13C12-HXCDF
384-336
1.
05-1.43
0.957-1.051
DC
NL
0:00
1.06
5.64
0. 000
27 : 39
1 . 32
105.00
59.77
45 .23
0. 963
27:43
1 .31
347.39
196.75
150.64
0.969
27:56
1.14
29.30
15.60
13 .70
0. 973
28:05
1.19
37.56
20.42
17 .14
0. 979
28:15
RO
1.46
49.IS
31.98
21.94
0.984
28:37
1.31
232.22
131.53
100.54
0.997 123473-HxCDF
AN
28:44
1.26
• 109.36
61,07
43.29
1.001 123673-HxCDF
AN
28:49
1 . 27
16.49
9. 22
7.27
1.004
29:01
1. 29
39.06
21 .99
1" .07
1.011
29: 10
1.13
13.52
7.31
6.21
1.016
29:13
1. 32
47.10
26.80
20.30
1.013 234673-KxCDF
AN
29:55
1.29
7.91
4.45
3 .46
1.042 123789-HXCDF
AN
29:59
1.26
15.23
3. 50
6.73
1.045
DC
WH
30:27
RO
1. 04
2.11
1.061
13
Peaks
1,049.29
0.
43-0.59
0.360-1.140
DC
NL
0:00
RO
0.67
2.46
0.000
DC
SN
27:47
RO
0.82
1.01
0.968
DC
SN
28:22
RO
0.85
1.18
0.988
28:37
0. 50
498.52
166.06
332.46
0.997 13C12-HXCDF 478
SUR3
28:42
0. 52
478.34
162.64
315.70
1.000 13C12-HXCOF 678
IS4
DC
SN
28:48
RO
1.06
3.02
1.003
DC
SN
28:56
0. 58
2.63
1.003
DC
SN
29:01
RO
1.39
0.82
1.011
DC
SN
29: 03
RO
0.89
1.15
1.012
29:12
0. 51
412.87
139.73
273.14
1.017 13C12-HXCDF 234
ALT2
DC
SN
29:20
RO
0. 39
4.32
1.022
DC
SN
29:31
RO
0.77
1.06
1.028
DC
SN
29:37
RO
1.57
1.37
1.032
DC
SN
29:44
RO
1.65
1.45
1.036
29:54
0, 50
352.82
117.59
235.23
1.042 13C12-HXCDF 789
ALT1
DC
SN
30:01
RO
0.95
3.46
1.046
PR
PR
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713 Printed; 17:15 09/08/97
Phone: (919) 544-5729 • Fax: (919) 544-5491
306
-------
Page No. 5
09/03/97
Listing of S975672B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compoundi
M_Z.
QC.Log Omit Why ..RT. OK Raeio Total.Area... Area.Peak.1.. Area,Peak.2,. Rel.RT Compound.Name.. ID,. Flags.
334-336
DC SN 30:06 RO 0. SO 1.57
DC SN 30:17 RO 2.51 1.37
4 Peaks 1,742.55
1.049
1. 055
Above: HxCDF / HxCDD Follows
HxCDD
390-392
AN
M
DC NL
DC SN
DC SN
390-392
1
J35-1.43
0.952-1.015
0:00
RO
1.90
2.31
0.000
28: 10
1.27
253.34
141.73
111.56
0.958
23:30
RO
2.16
1.55
0.969
23:37
1.25
61.69
34.24
27.45
0.973
23:49
i.:2
952.03
523.19
428.84
0.980
28:58
1.15
19.40
10.37
9.03
0.985
29:12
RO
2.50
1.08
0.993
29:22
RO
0.75
10.39
S.03
8.03
0.999
123478-HxCDD
AN
29:24
1.26
170.90
95.40
75.50
1.000
123678-HxCDD
AN
29:42
1.12
64.82
34.30
30.52
1.010
123789-HxCDD
AN
Peaks
1,533.07
n
13C12-HXCDD
402-404
1.05-1.43
0.966-1.034
402-404
DC
NL
0:00
RO
0.59
1.39
0.000
DC
WL
27:54
RO
1.71
0.78
0.949
DC
WL
23:02
RO
0.93
0.74
0 . 954
DC
WL
28:08
RO
0. "7?
2.40
0.957
DC
SN
23:38
RO
0.93
1.50
0.974
DC
SN
28:55
RO
0.29
0.98
0. 984
DC
SN
29:05
1.09
2.01
0.989
DC
SN
29:10
RO
1.53
0.85
0.992
29:20
1.28
324.75
182,14
142.51
0.998
13C12-HXCDD
478
29:24
1.16
326.87
175.57
151.30
1 .000
13C12-HXCDD
673
29:42
1.22
334.22
133.62
150.60
1.010
13C12-HXCDD
739
DC
SN
29:49
RO
0,34
2.15
1.014
DC
SN
3
29:53
Peaks
RO
0.61
1.79
985.84
1.019
Above: HxCDD / HpCDF Follows
HpCDF
0.38-1.20
0.995-1.044
403-410
DC
NL
0:00
RO
2.26
1,57
0.000
M
31:21
1.03
23.60
12.00
11.60 1.000 1234678-HpCDF AN
D
DC
SN
31:34
0.93
6.31
1.007
D
DC
SN
31:41
0.94
13.85
1.011
DC
SN
32:06
RO
2.59
1.51
1.024
DC
SN
32:12
RO
2.91
0.90
1.027
DC
SN
32:34
RO
2.20
2.51
1.039 1234789-HpCDF AN
408-410
1
Peak
23 .60
13C12-HpCDF
0.
37-0.51
0.936-1.128
418-420
DC
NL
0:00
RO
1.22
1.24
0.000
31:21
0.42
179.57
52.94
126.63 1.000 13C12-HpCDF 678 IS6
DC
SN
31:46
RO
2.80
0.58
1.013
DC
SN
32:20
RO
0. S3
1.09
1. 031
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:15 09/08/97
30? -
-------
Page No. 5
09/03/97
Listing of S975672B.dbfi
Hatched GC Peaks 1 Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit
Why
. ,RT.
OK
Ratio Total
Area... Area.Peak.1.. Area.Peak.2..
Rel. RT
Compound.Name..
ID. .
32:31
0. 37
129.41 35.09 94.32
1.037
13C12-HpCDF 789
SDR 5
DC
SN
32:42
RO
0.69
3.60
1.043
DC
SN
32:52
RO
1.9S
1.63
1.048
DC
SN
32:59
RO
0.57
1.67
1 .052
413-420
2
Peaks
308.98
Flags.
Above: HpCDF / HpCDD Follows
HpCDD
424-426
424-426
DC NL
DC SN
DC m
0
88-1.20
0.
977-1.006
O
o
o
1. 07
0
31
0. 000
31:36
0.95
66
32
32.38
33 .94
0.982
31:42 RO
1.S4
1
41
0.985
32:11
0.94
33
57
16.27
17 .30
1.000 1234678
32:28
1.05
1
35
1.009
Peaks
99
89
AN
13C12-HpCDD
0
88-1.20
0.969-1.031
436-433
DC
NL
0: 00
1.08
0
27
0.000
DC
SN
31: 38
RO
0.35
0
83
0.983
DC
SN
31:47
RO
0.63
0
92
0.988
32: 11
1.07
163
23
34.32
78.96 1.000 13C12
DC
SN
32:29
RO
1.81
1
96
1.009
DC
SN
32: 36
RO
6.44
0
33
1.013
436-433
X
Peak
163
28
Z12-HpCDD 678 IS7
Above; HpCDD / Octa-CDD and CDF Follows
OCDF
442-444
442-444
OCDD
458-460
0.
76-1.02
0.884-1.116
DC
NL
0
00
RO
1 .25
0.23
0.000
DC
SN
31
16
RO
1.68
1.46
0.903
DC
SN
31
23
0.95
2.36
0.906
DC
SN
31
48
RO
0.64
1.23
0.918
DC
SN
32
09
RO
1.96
0.85
0.928
DC
SN
32
21
RO
0.13
0.38
0.934
DC
SN
32
28
RO
1.08
2.34
0.937
DC
SN
32
48
RO
0.65
3.86
0.947
DC
SN
33
30
RO
0.62
1.91
0.967
DC
SN
33
46
RO
1.18
3.95
0.97S
DC
SN
34
00
RO
4.10
0.79
0.982
DC
SN
34
11
0. 80
4.03
0.987
DC
SN
34
20
0. 98
2.41
0. 991
DC
SN
34
36
RO
0 . 54
2.31
0.999
DC
SN
34
45
0. 92
5.00
1.003 OCDF
DC
SN
34
57
RO
4.76
0.93
1.009
DC
SN
35
13
0. 98
1,05
1.017
DC
SN
35
30
RO
2.81
0.49
1.025
DC
SN
35
37
0.99
2.37
1.028
DC
SN
35
52
RO
0.46
0.59
1.036
0
Peaks
0.00
0
76-1.02
0.884-1.116
DC
NL
0
00
RO
1 .08
0.23
0.000
AN
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:15 09/08/97
308 *
-------
Page No.
09/03/97
Listing of S975672B.dbf
Matched GC Peaks / Ratio / See, Time
Compound/
M_Z QC
453-460
Omit
Why
. .RT.
OK
Ratio Total
Area... Area.. Peak. 1. . Area. Peak ,2. .
Rel. RT
Compound.Name.
ID
DC
SN
34:29
RO
1.30
0.19
0.996
34:39
0.78
7.01 3.07 3.94
1.000
OCDD
AN
DC
SN
34:58
RO
1.41
0.83
1.010
DC
SN
35:05
RO
0. 38
0.51
1.013
1
Peak
7,01
Flags.
13C12-OCDD
0
-76-1.02
0.996-1.006
470-472
DC
NL
0:00
RO
1.15
0.25
0.000
34:38
0.95
154.14
75.25
78.39 1.000 13C12-OCDD
IS8
DC
WH
34:55
RO
0.41
1.76
1.008
470-472
1
Peak
154.14
Column Description.
"Why" Code Description QC Log Desc.
M_2 -Nominal Ion Mass(es)
..RT. -Retention Time (iran:ss)
Rat.l -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Sel.RT-Relative Retention Time
End of Report ***
HL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
File:S975672 #1-867 Acq:5-SEP-97 10:08:14 EI + Voltage SIR 70S Noise:2446
303.9016 F:2 BSUB( 256, 30, -3 . 0 ) PKD(9 , 5,5,0.05%, 9784 . 0 ,1.00%, F, T) Exp:EPCUS
TRIANGLE LABS
100%
18:00 19:00 20:00 21:00
File :S975672 #1-867 Acq: 5-SEP-97 10:08:14 EI+ Voltage SIR 70S Nbise:3182
305.8987 F: 2 BSUB(256, 30 , -3.0 ) PKD(9 , 5, 5 , 0. 05%, 12728. 0 ,1.00%, F,T) Exp:EPCUS
TRIANGLE LABS Text:RUN 5 TLIH42930A INS^ TIME = 10:10
77:00
File:S975672 #1-867 Acq:5-
315.9419 F:2 BSUB(256, 30, ¦
TRIANGLE LABS Text:RUN 5
100%
80S
Text:RUN 5
TLI04293OA
A1. 69E8
IN J. TIME =
10:10
2.4E7
A1 . 01E8
A6K23E7
A7.68E7
A1.08E8
1.6E7
A1.11E8
A3.88E7
8.1E6
A3.17E7
A
22:00
1003,
80.
60.
4 0.
20.
0.
A2.05E8
A3.45E7
Aa1.91E7
A7.49E7
A1.30E8 A9.28E7
A1.30E8
L.21C./ /
A A
A1.20E8
A4.62E7
O.OEO
23': 00 Time
5. 0E7
'.4.0E7
¦.3.0E7
.2.0E7
ll.0E7
60S
401
20.
19:00 20:00 21:00
SEP-97 10:08:14 EI+ Voltage SIR 70S Noise:21913
3.0) PKD(9, 5,5,0.05%, 87652. 0,1. 00%,F,T) Exp:EPCUS
TLIH42930A INJ". TIME = 10:10
A7.97E6
22: 00
23:00
O.OEO
Time
A1.20E6
.2.1E6
i.1. 7E6
.1.3E6
.8.4E5
\_4.2E5
18:00
File:S975672 #1-867 Acq:5
317.9389 F-.2 BSUB(256,30,
TRIANGLE LABS Text:RUN 5
100%
80.
~r
-L
l:
60.
40.
201
19:00 20:00 21:00
¦SEP-97 10:08:14 EI+ Voltage SIR 70S Noise:847
¦3.0) PKD(9, 5, 5, 0. 05%, 3388. 0,1. 00%, F, T) Exp:EPCUS
TLI#42930A INS. TIME = 10:10
A1.07E7
22: 00
23:00
OEO
Time
18:00
File: S975672 #1-867 Acq:5-
330.9792 F:2 Exp:EPCUS
TRIANGLE LABS Text:RUN 5
100$ 17:20 18:17
19:00 20:00 21:00
SEP-97 10:08:14 EI+ Voltage SIR 70S
22: 00
23:00
C2.8E6
[.2.2E6
L1. 7E6
. 1.1E6
L5.5E5
.O.OEO
Time
TLI #4293 OA
18:54
19:30 79--S7
INS. TIME =
20:39 21:07
22:16_
J?2.i49_r_±^2E7
».9. 9E6
7.4E6
5.0E6
2.5E6
O.OEO
18:00
File:S975672 #1-867 Acq:5
375.8364 F:2 Exp:EPCUS
TRIANGLE LABS Text:RUN 5
lOOi
80.
601
19:00 20:00 21:00
¦SEP-97 10:08:14 EI+ Voltage SIR 70S
22:00
23: 00
TLI#42930A
401
20.
0.
INS. TIME = 10:10
21:21
20:30
20:09
21:07
\17:56
18:00
18:54 ild; 16 19:46
20:56
Wo"
22:05
19:00
20:00
21:00
_2.2E4
1.7E4
_1.3E4
-8.7E3
-4.3E3
O.OEO
22:00
23: 00
310
-------
File: S975672 *1-867 Acq:5-SEP-97 10:08:14 EX# Voltage SIS 70S Noise:29186
319.8965 F: 2 3SUB(256,30, -3. 0) PKD( 7,5,3,0.05%,116744.0,1.00%,F,T) Exp-.EPCUS
TRIANGLE LAMS
1003
19.-00 20:00 1 21:00 22:00
File:S975672 #1-867 Acq:5-SEP-97 10:08:14 EI* Voltage SIS 70S Noise:4325
321.8936 F: 2 BSGB(256,30, -3.0) PKD(7, 5 ,3, 0. 05%, 17300.0,1. 00%,F,T) Exp: EPCZJS
TRIANGLE LABS
lOOi
80J
19:00 20:00 21:00 22:00
File:S975672 #1-367 Acq:5-SEP-97 10:08:14 EI* Voltage SIS 70S Noise: 1516
331.9368 F:2 BStJBf256,30, -3.0) PKD(7,5 , 3 , 0.05%, 6064.0,1. 00%, F,T) Exp:EPCUS
TRIANGLE LABS Text: RUN 5 TLI#42930A IN J. TIME = 10:10
Text:SUN 5 TLI*42930A
A3187E6
IN J. TIME = 10:10
A2.25E6 A1.36E6
A A1.27E6
A
A1.53E6
A
A1.32E6
5.72E.
-/V
A5.15E5
- fA
23:00
.1.2X6
ll. 0E6
.7.SE5
15.0E5
L2.5E5
.O.OEO
Time
Text:SUN 5 TLI04293OA
INJ. TIME » 10:10
A4.78E6
60j
40j
20-
OA
A2.76E6
Al.86E6
A1.63X6
A
A1.92E6
Al.62E6
A Al. 75E6
/V\a7a"/V'-a"5
AS.
04E6
A7-m6.27E6
Al.06E7
A3. 74E6
801
60A
40j,
20i
19:00 20:00 21:00
File:S975672 #1-867 Acq:5-SEP-97 10:08:14 EI* Voltage SIM 70S
330.9792 F:2 EzpsEPCOS
TRIANGLE LABS Text:SVN 5 TLI44293OA INJ.
1003, 18:54 19:30 19:48 20, 07 20:23 20:39 21:07 21
22:00
10:10
A5.45E5
__A-
1.5E6
1.2E6
3. 8E5
5.9E5
2.9E5
23:00
.O.OEO
Time
100%
80A
sod
401
20\
OJ j , 1 r- 1 1 1 1 1 1 1 1 1" 1 << W—\ [-
19:00 20:00 21:00 22:00
File:S975672 #1-857 Acq:S-SEP-97 10:08:14 XI* Voltage SIR 70S Noise: 111
333.9338 F:2 BSUB(256,30, -3.0) PKD( 7, S, 3, 0. 05%, 444 . 0, 1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:RUN 5 TLI04293OA INJ. TIME - 10:10
100%
80A
sod
40l
2oi
—,—, , , . ,
19:00 20:00 21:00 22:00 23:00
File:S975672 #1-867 Acq:5-SEP-97 10:08:14 EI* Voltage SIR 70S Noise: 908
327.8847 F-.2 BSUB(256,30, -3.0) PXDf 7, 5, 3 , 0. 05 %, 3632. 0,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS TextsRUN 5 TLI»42930A INJ. TIME » 10:10
100%
1.8E6
1.4E6
1.1ES
7. 0E5
3.5E5
.O.OEO
23': 00 Tine
2.0E6
1.6E6
1.2E6
7.8E5
3.9E5
O.OEO
Time
-3.4E6
:.2. 7E6
L2.0E6
Ll. 4E6
.6.8E5
.O.OEO
23:00
Time
22:49
1.2E7
9.9E6
7.4E6
5.0E6
2.5E6
O.OEO
19:00
20:00
21:00
22:00
23:00
311
-------
File:S975672 #1-867 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S Noiae:67
339.8597 F:2 BSUB( 256, 30, -3 . 0 ) PKD(7, 5,3 , 0. 05%, 268. 0 , 1. 00%,F,T) Exp:EPCUS
TRIANGLE LABS Text-.RUN 5 TLI#42930A IN J. TIME = 10:10
1001
801
601
401
201
Oj
A3.06E7
A1.35E7
5.43E6
A9.12E6
A7.25E6
A6.09E6
AA Aa
23:00 24:00 25:00 26:00
File:S975672 #1-867 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S Noise:550
341.8567 F: 2 BSUB(256, 30,-3 . 0 ) PKD(7, 5 , 3 , 0.05%, 2200. 0 ,1. 00%, F,T) Exp-.EPCUS
TRIANGLE LABS Text: RUN 5 TLI#42930A IN J. TIME = 10:10
100.
A9.23E6
3.86E6
A6. 02E6
A5. 08E6j\
A4.11E6
r\N\
AA Aa
23 : 00 24 : 00
File:S975672 #1-867 Acq:5-SEP-97 10:08:
351.9000 F:2 BSUB(256, 30,-3 . 0) PKD(7,5,
TRIANGLE LABS Text:RUN 5 TLI»42930A
100%
801
601
25:00 26:00
14 EI+ Voltage SIR 70S Noise: 76
3,0.05%, 304 .0,1. 00%, F, T) Exp-.EPCUS
IN J. TIME = 10:10
401
201
A6.
Q9E6
A5.05E6
23: 00
File:S975672 #1-867 Acq:5-
353.8970 F-.2 BSUB(256, 30, -
TRIANGLE LABS Text:SUN 5
1001
801
601
401
201
24: 00
SEP-97 10:08:
3.0) PKD(7, 5 ,
TLI442930A
25:00 26:00
14 EI+ Voltage SIR 70S Noise:116
3,0.05%, 464 .0,1. 00%, F,T) Exp: EPCUS
IN J. TIME = 10:10
A3.4 7E6
A3.19E6
23: 00
File:S975672 #1-867 Acq:5-
330.9792 F:2 Exp-.EPCUS
TRIANGLE LABS Text:RUN 5
100S
24: 00
SEP-97 10:08:
TLI #4 293 OA
23 -.52 24: 14
25:00
14 EI+ Voltage SIR 70S
26:00
INJ. TIME = 10:10
25:35 25:53 26:08 26:24
.6. 6E6
.5.3E6
.4.0E6
12. 7E6
p . 3E6
27: 00
0.0E0
Time
4.3E6
L3.4E6
L2. 6E6
Ll. 7E6
¦_8.5E5
27: 00
10.0E0
Time
.1. 7E6
1.4E6
1. 0E6
6.9E5
3.4E5
27:00
27:00
0.0E0
Time
.1.1E6
.8.6E5
.6.5E5
.4.3E5
.2.2E5
.0.0E0
Time
26:46
1.3E7
24:36
23:35
23: 05
1. 0E7
-7.7E6
_5. 2E6
_2.6E6
0.0E0
23:00
File:S975672 #1-867 Acq:5
409.7974 F-.2 Exp-.EPCUS
TRIANGLE LABS Text-.RUN 5
100%
801
601
401
201
24 -. 00
¦SEP-97 10:08
TLI #4293 OA
24: 04
25:00
14 EI+ Voltage SIR 70S
26:00
27:00
INJ. TIME = 10:10
23: 05
23:37
22:52
Afj\hf
23:16
fi
24 :19
25:12
26:01
5:45
27:03
6:17
23 : 00
24 : 00
25: 00
26:00
27:00
2.2E4
1.8E4
1.3E4
8.8E3
.4. 4E3
0.0E0
Time
312 ~
-------
File:SS?5S72 il-867 Acq:S-SEP-S? 13:dB:14 EI* Voltage SIM 7Ss Noise:622
355.8546 T:2 BSUB(256,30, -3.0) PKD(7, 5 , 3, 0 . Q5\, 2488. 0,1 . 00%, F, T) Exp-.EPCUS
TRIANGLE LABS Text."ROW 5 TZI04293OA INJ. TIME » 10:10
¦ i i ; ¦* i'1 »vr >"l
25:00 26:00
File:S975672 §1-867 Acq:5-SEP-97 10:08:14 EI* Voltage SIS 70S noise: 940
357.8516 F: 2 BSOB(256,30, -3.0) PKD( 7,5,3, 0 . 05%, 3760. 0,1.00%, F,T) Exp-.EPCUS
TRIANGLE LABS Text:RVN 5 TLI04293OA INJ. TIME = 10:10
1003,
25:00 26:00
File:S975672 #1-867 Acq:5-SEP-97 10:08:14 EI* Voltage SIR 70S Noise:85
367.8949 F:2 BSOB(256, 30, -3.0) PKD(7, 5,3,0.05%, 340. 0,1. 00%,F, T) Exp:EPCVS
TRIANGLE LABS Text:RON 5 TLI*42930A INJ. TIME = 10:10
lOOi
801
60:
40L
201
A2.67E6
A2.27E6
Jl8.84E5
A3.27E5
A6.61E5
A8.55ES
A2.05E5
3.53E5
A3.81E5
80.
60:
401
20.
A1. 72E6
A9.89E5
A
16.30E5
A6.40E5
A5.02E5
A1.43E5,
A5.57E5
55
A2.38E5
100$
80.
60.
40.
20.
A2.20E6
. 25E5
25:00 26:00
File:S975672 01-867 Acq:5-SEP-97 10:08:14 EI* Voltage SIS 70S Noise: 91
369.8919 F:2 BSCB( 256, 30,-3 . 0 ) PKJ}( 7, 5 ,3 , 0 . 05\, 364 . 0 , 1. 00%, F, T) Exp: EPCVS
TRIANGLE LABS Text:SON 5 TLI04293OA INJ. TIME = 10:10
IOCS
803
603
403
20J
A1.59E6
2.24E5
80.
60.
40.
20.
25:00
26': 00
.8.4E5
'.6.7E5
.5.0E5
'.3.4E5
.1. 7ES
.0.0E0
27:00 Time
— 6.3E5
5.0E5
13. 8E5
2.5E5
11.3E5
O.OEO
27:00 Time
6.3E5
15.0E5
3.8E5
12.5E5
1.3E5
.O.OEO
27:00 Time
_4.2E5
3.4E5
2.5E5
1. 7E5
8.5E4
—i ¦ ¦ - i " ¦¦ i ¦ i ¦' t " i | ; 1 - "i
25:00 26:00
File:S975672 $1-867 Acqs5-SEP-97 10:08:14 EI* Voltage SIS 70S
330.9792 F:2 Exp:EPCUS
TRIANGLE LABS Text:SUN 5 TLI04293OA INJ. TIME = 10:10
100% 24:36 25 • 02 25: 13 25:35 25:53 26:08 26 ^24 26:35 26:46 _
1O.OEO
27:00 Time
1.3E7
1.0E7
17.7E6
15.2E6
2.6E6
.O.OEO
—r
27:00 Time
313 -
-------
File:S975672 01-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S Noise:1448
373.8208 F: 3 BSUB(256, 30,-3 . 0 ) PKD(7, 5, 3, 0 . 05%, 5792. 0 ,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:RON 5 TLI#42930A INJ~. TIME = 10:
1003k
80.
60.
40.
20.
29:36 29:48 30:00 30:12 30:24
File: S975672 #1-425 Acq:5-SEP-9 7 10:08:14 EI+ Voltage SIR 70S Noise:1369
375.8178 F: 3 BSUB(256, 30,-3 .0 ) PKD(7, 5, 3 , 0. 05%, 5476. 0 , 1. 00%,F,T) Exp:EPCUS
TRIANGLE LABS Text:RUN 5 TLI#42930A INJ. TIME = 10.
10
A5.9BE
A1.32E6
16.11E5
A3.20E5
¦A, A
it if ' 'T ¦ i | f i i ( i | ' T. ' ^vi i i«-i | i-»i i i'i | i'i ¦
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24
A3.37E5
TT'O'-i . i
1:10
1001
801
60.
401
20l
01
A1-51E6
A4.52E5
A1.01E6
\4 .83E5
A2.19E5
¦A, A,..
A2.67E5
¦rTN.
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36
File: S975672 #1-425 Acq:5-SEP-9 7 10:08:14 EI+ Voltage SIR 70S Noise: 546
383.8639 F:3 BSUB( 256 , 30, -3 . 0 ) PKD( 7, 5 , 3 , 0 . 05%, 2184 . 0, 1. 00%, F, T) Exp:EPCUS
A6. 73E4
i "TV i i i
i ' ' 1 1 1 • 1 ' 1 ' r
29:48 30:00 30:12 30:24
TRIANGLE LABS
1004
80.
Text:RUN 5 TLX #42930A
60.
40.
20.
27
File
A1.66E6
]
r 1 I ' 1 1 .......
24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36
S975672 #1-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S Noise:814
INJ-. TIME =
4 0E6
10:10
¦p-r-f
28:48
A1.18E6
29:48 30:00 30:12 30:24
385.8610 F:3 BSUB( 256 , 30,-3. 0 ) PKD(7, 5 , 3 , 0. 05%, 3256. 0 ,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS
100%
801
Text:RUN 5 TLI*42930A
INJ~. TIME =
10:10
60.
40.
201
A3.32E6
27
File
A2. 73E6
A2.35E6
24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36
29:48 30:00 30:12 30:24
.3E5
.9E5
• 4E5
.9E5
. 5E5
. 0E0
Time
8E5
7E5
5E5
3E5
2E5
.OEO
Tine
5E5
2E5
9E5
6E5
3E5
.OEO
Time
.2E6
. 9E5
. 5E5
.OE5
. 5E5
.OEO
Time
S975672 #1-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
392.9760 F:3 Exp:EPCUS
TRIANGLE LABS Text:RON 5 TLI#42930A
100% 27:30 27:43 28:00 „„ 28:37 28:56
IN J. TIME =
29:4fl' 30:00 30:12 30:24
S975672 #1-425 Acq: 5-SEP-97 10:08:14 EH- Voltage SIR 70S
445.7555 F:3 Exp:EPCUS
TRIANGLE LABS Text:RON 5 TLI442930A
100%
INJ~. TIME =
28:32
80.
601
401
201
(1
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36
27:38
28: 09
29: 09
29:30
30:04 30:16
28:57
29:48' 30.-00 ' '30:12' 30:24
314
-------
File:S375672 #1-425 Acq;5-ll£P-§7 10:08:14 eT+ Voltage slA 70s Noise:98^!
389.8156 F-.3 BSUB(256, 3 0,-3 . 0 ) PKD(7, 5,3,0.05%, 3928.0,1. 00%, F, Tj £xp:EPCUS
TRIANGLE LAMS
1003,
28-00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00
File: S975672 #1-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIM 70S Noise: 515
391.8127 F:3 BSUB(256, 30,-3.0) PKJ>( 7,5,3,0.05%, 2060.0 ,1. 00%, F, T) Exp.-EPCUS
TRIANGLE LABS
lOOi
80.
Text.IRON 5 TLI04293OA
IMJ. TIME " 10:10
_i.9E6
.1. 5E6
l .1E6
A1.42E6
A1.04E6
A3.42E5
zx
TextsXVN 5 TLI04293OA
IN J. TIME = 10:10
60.
401
20.
A1.12E6
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00
File:S975672 #1-425 Acq:S-SEP-97 10:08:14 EI+ Voltage SIS 70S Noise: 385
401.8558 F:3 BSUB(256, 30,-3. 0) PKD(7, 5 , 3 , 0. 05%, 1540 . 0,1.00%, T,T) Exp:EPCCS
A2.74E5
A 7. 77E5
A3.OSES
TRIANGLE LABS
1004
80.
Text:SUN 5 TLI§4293OA
601
401
201
INJ. TIME
A1.82E6
y
rr
__
10:10
A1.84E6
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36
File:S975672 #1-425 Acq:5-SEP-97 10:08:14 EH- Voltage SIX 70S Noise: 652
403.8529 F: 3 BSUB(256, 3 0,-3 . 0) PKD(7, 5,3,0.05%, 2608.0,1.00%, F, T} Exp-.EPCUS
TRIANGLE LABS Text:SON 5 TLI442930A INJ. TIME = 10:10
29:48
100S,
so:
60.
40.
20.
A1.51E6
A1.51E6
30:00
i I I I 'i I W I I -1 I" I i |"'I '"I"1!" I" I *t*i I I rpi Ini 'I i "I" I I I I i" I f [ I i I ¦ 1 i "i" I ,*r I i I~¥"r
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00
File:S975672 §1-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIB 70S
392.9760 F:3 Exp-.EPCUS
TRIANGLE LABS Text:SUN 5 TLI»42930A INJ. TIME = 10:10
100* 28:00 . ,o 28:37 28:56 „„ 29jl7 ,, _ _ 29:52
_ . 28:18 /v ) V^f8i46^ XV 29:04 29133 29-.4J /V a 30:03
soj
60.
40.
20.
0.
'28:00' ' 28':12
'28': 24
28': 36
28:48
1 I ' '
29:00
'29:12 ' 29:24 ' '29:36 ' '29:48
30:00
I
I
I
I
I
I
I
315
I
-------
File: S975672 01-390 Acq:5-SEP-97 10:08:14 EI+ Voltage SIS 70S Noise:871
407.7818 F:4 BSUB( 256, 30, -3 . 0 ) PKD(7, 5 , 3 , 0. 05%, 3484. 0 , 1.00%,F,T) Exp:EPCUS
TRIANGLE LABS Text.: RUN 5 1X1*4293 OA IN J. TIME * 10:10
1001 A1.J5E5
31:12 31:24 31:36 31:48 32:00 32:12 32:24
File:S975672 #1-390 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S Noi3e:383
409.7789 F:4 BSUB( 256, 30, -3. 0 ) PKD(7, 5 , 3 , 0. 05%, 1532. 0 ,1. 00%, F,T) Exp:EPCUS
A6. 72E4
A3.04E4
A1.44E4
A2. 70E4
A1.28E4
32:36
32:48
33: 00
TRIANGLE LABS Text:RUN 5 TLI#42930A
1003, A1.18E5
INJ. TIME
10:10
A7.13E4
A3.27E4
A1.23E4
A7.59E3
A1.21E4
~ ~ ^
32:36
31:12 31:24 31:36 31:48 32:00 32:12 32:24
File: S975672 #1-390 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S Noise:526
417.8253 F:4 BSVB( 256 , 30, -3 . 0 ) PKD( 7, 5, 3, 0 . 05%, 2104 . 0, 1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:RUN 5 TLI#42930A INJ. TIME = 10:10
1001
32:48
80J
601
40l
20l
T
A3.51E5
A2.05E4
-i
T
33: 00
1
1
7
r-p"
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
File: S975672 #1-390 Acq:5-SEP-97 10:08:14 EH- Voltage SIR 70S Noise:429
419.8220 F:4 BSOB(256,30,-3.0) PKD( 7, 5, 3, 0 . 05%, 1716 . 0,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:RUN 5 TLI#42930A INJ\ TIME = 10:10
32:48
1003
SOl
601
40l
20J
A1.
A9.43E5
31:12 31:24 31:36 31:48 32:00 32:12
File: S975672 #1-390 Acq:5-SEP-97 10:08:14 EI + Voltage SIR 70S
430.9729 F:4 Exp:EPCUS
TRIANGLE LABS Text:RUN 5 TLI#42930A INJ.
100% 31:14 31:23 11:34 31:41 31:53 32:05 32:18
80d
60l
40l
20.
32:24
jJToo
5.
-4.
1 3.
12.
L1.
32:36
10:10
32:48
-J-O.
33: 00
-2
.1
31:12 31:24 31:36 31:48 32:00 32:12
File:S975672 #1-390 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
479.7165 F: 4 Exp:EPCUS
TRIANGLE LABS Text.-RDJf 5 TLI#42930A INJ.
1001 31;41
80l
60l
401
20l
0.
32:24
TIME =
32:36
10:10
32:48
33:00
0E5
6E5
2E5
9E4
, 0E4
0E0
Time
1E5
1E5
.1E5
. 0E5
.0E5
. 0E0
Time
. 3E6
. 5E6
. 6E6
. 7E6
.7E5
. 0E0
Time
32:12
32:0
32:28
32:53I
32:43
31:12
~'—I—1—
31:24
31:36
31:48
32:00
32:12
32:24
32:36
32:48
.1.
.9.
.7.
t
33:00
2E4
6E3
2E3
8E3
4E3
. 0E0
Time
316
-------
Flle:S975672 W1-J90 Acq:5-SEP-97 10:03:14 Et+ Voltage siii 70s Noise: 80
423.7766 F:4 BSUB( 256 , 30, -3 . 0 ) PKD(7, 5, 3, 0. 05%, 320. 0, 1. 00%,F, T) Exp:EPCUS
TRIANGLE LABS Text:BUN 5 TLI04293OA INJ~. TIME - 10:10
1004
801
601
40i
201
A1. 63E5
¦i i1^ r|t i i
1.1E5
.9. 2E4
.6.9E4
.4.6E4
-2.3E4
T
31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30 32:36
File:S975672 #1-390 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S Noise:75
425.7737 F:4 BSUB(256, 30, -3. 0 ) PTD(7, 5 , 3 , 0. 05%, 300.0 , 1. 00%,F,T) Exp-.EPCUS
TRIANGLE LABS Text: RON 5 TLI#42930A IN J. TIME = 10:10
100i
801
601
40.
O.OEO
Time
20.
A1. 73E5
31:30 31:36 31:42 31:48 31:54 32:00 32': 06 32:12 32:18
File:S975672 #1-390 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S Noise:70
435.8169 F:4 BSUB( 256, 30, -3. 0 ) PKD(7, 5 , 3 , 0. 05%, 280. 0 , 1. 00%, F,T) Exp-.EPCUS
TRIANGLE LABS Text:RUN 5 TLI#42930A IN J. TIME = 10:10
1004
.1.1E5
.9. 0E4
.6. 7E4
.4.5E4
12.2E4
32:24
801
60.
401
20.
I I I i i I
32:30
O.OEO
32:36
Time
1 1 T 1 1 1 1 1 I 1 1
31:30 31:36
1 1 I
31:42
3.4E5
2. 7E5
2.0E5
1.3E5
6. 7E4
~iT 1 1
32:18
31:48 31:54 32:00 32:06 32:12
File:S975672 #1-390 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S Noise: 67
437.8140 F:4 BSUB(256, 30,-3. 0) PKD( 7, 5,3, 0. 05%, 268 . 0,1. 00%,F, T) Exp-.EPCUS
TRIANGLE LABS Text: RUN 5 TLI#42930A IN J. TIME = 10:10
1003,
801
• ' I ' 1 1 |fr*l ' ' 'T ' '¦
32:24 32:30 32:36
O.OEO
Time
60.
40.
20.
I I I | I I I I I | l*l»l 1 11 | I ! I l I | I I I I I I I [ I I l | l | I | | ,
31:30 31:36 31:42 31:48 31:54 32:00 32:06
File:S975672 #1-390 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR
430.9729 F:4 Exp:EPCUS
TRIANGLE LABS Text:RUN 5 TLI04293OA
32:12
70S
1003,
80.
601
40.
201
0.
31: 34
31:41
31:53
32: 05
32:18
TIME
32:18
i i | M
32:24
t I I
32:30
32:36
10:10
32:27
31:30 31:36 31:42 31:48
' 1 I i '
31:54
32:00 32:06 32:12 32:18 32:24 32:30 32:36
3.1E5
2.5E5
.1. 9E5
1.2E5
.6.2E4
O.OEO
Time
.4.3E6
.3.4E6
.2.6E6
.1. 7E6
.8.5E5
.O.OEO
Time
317
-------
File: S975S72 01-390 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S Noiae:74
441.7428 F-.4 BSUB(256, 30, -3 . 0 ) PKD(7, 5, 3 , 0. 05%, 296.0 , 1. 00%, F, T) Exp-.EPCUS
32:00 33:00 34:00 35:00
File: S975672 §1-390 Acq:5-SEP-97 10:08:14 EI* Voltage SIX 70S Noise: 61
443.7399 Fs4 BSUB(256,30, -3.0} PKB( 7, 5, 3, 0. 05%,244. 0, 1. 00%,F, T) Exp-.EPCUS
TRIANGLE LABS Text:EtJN 5 TLI142930A INT. TIME = 10:10
lOOSk
A2 . 60E4
A2.82E4
TRIANGLE LASS
100i
90j
Text:RON 5 TLI#42930A
IN.7. TIME
Al. 79E4
10:10
A2.34E4
A1.15E4 A5.79E3lA2-°4.Z4
" ' A1.34E4
A1.82E4 A8.66E3
IA8.97E3
| i j IA8.97E-
^mndAAhLkA
A2.4 0E4
A2.33E4
A5.18E3 Al .18
Time
Al. 72E-
A2.46E4
A1.46E4
A1.19E4
A1.64E4
A2.01E4
A1.40E4
A9.70E3
A2.24
A2.81
A2.09E4
A4.18
A5..32E3
A5.15E3
32:00 33:00 34:00
File:S975672 #1-390 Acq:5-SEP-97 10:03:14 EI* Voltage SIR 70S
430.9729 F:4 Exp-.EPCUS
TRIANGLE LABS Text:SON 5 TLI#42930A INJ. TIME
35:00
10:10
100%
90.
80.
701
60.
50.
40.
30.
20.
10.
32:00 33:00 34:00
File:S975672 #1-390 Acq:5-SEP-97 10:08:14 EI* Voltage SIR 70S
513.6775 Tt4 ExpsEPCUS
TRIANGLE LABS TextsRVN 5 TL104293OA INJ. TIME
33:02
33:3333149 34:10
34:36
35:16
35:46
31:41
32:18
35:00
.6E6
. 1E6
. 7E6
.2E6
. 7E6
. 3E6
. 8E6
.4E6
. 1E5
. 6E5
. OEO
Time
10:10
IOCS
33:34
34:07
31:31
34:48
34:31
33:53
32:00
33:00
34 : 00
35:00
318
-------
File: S975b72 *1-390 Acq: i -SEP-9 7 10:08114 EI* Voltage SIR 70S J»oi«e.-66
457.7377 T:4 BSUB(256,30, -3.0) PXD( 7, 5, 3, 0 . 05%, 264 . 0,1. 00%, F, T) Exp-.EPCVS
TRIANGLE LABS
100%
34:30 34:36 34:42 34:48 34:54
File:S975672 §1-390 Acq:S-SEP-97 10:08:14 EI* Voltage SIB 70S Noise:60
459 . 734 8 F:4 BSUB(256,30,-3.0) PKD( 7,5,3,0.05%, 240.0,1.00%, F, T) Exp:EPCUS
TRIANGLE LABS
100%
34:30 34:36 34:42 34:48 34:54 35:00
File:S975672 #1-390 Acq:5-SEP-97 10:08:14 EI* Voltage SIS 70S Noise:75
469.7779 F:4 BSUB(256, 30,-3 . 0 ) PKD( 7, 5,3, 0. 05%, 300. 0,1. 00%, F, T) Exp:EPCCS
TRIANGLE LABS Text-.RUN 5 TLI#42930A INJ. TIME = 10:10
100s
rext.-SCW 5 TZI04293OA
A4.S8E4
INT. TIME =
10:10
1.2E4
.9.5E3
7.1E3
4.8E3
A6.21E3
-2.4E3
2.41E3
O.OEO
35:00
35:06
Text:RON 5 TLI*42930A
A5.14E4
INT. TIME =
10:10
1.2E4
9.5E3
7.1E3
4.7E3
A6.39E3
A4.39E3
2.4E3
A7. 77E3
O.OEO
35:06
.2.3E5
_1. 8E5
1.4E5
9.1E4
4.6E4
O.OEO
34:30 34:36 34:42 34:48 34:54 35:00
F±le:S975672 #1-390 Acq:5-SEP-97 10:08:14 EI* Voltage SIS 70S Noise: 63
471.7750 F:4 BSUB ( 256, 30,-3.0) PKD( 7, 5 ,3 , 0. 05%, 252. 0 , 1. 00%,F ,T) Exp:EPCUS
TRIANGLE LABS Text:RUN 5 TLX04293OA INT. TIME = 10:10
35:06
1001
so:
60.
40.
20.
A7.89E5
~'i i r i • i i r» i i
34:30 34:36 34:42 34:48 34:54
File:S975672 #1-390 Acq:5-SEP-97 10:08:14 EI* Voltage SIR 70S
430.9729 F:4 Exp:EPCUS
TRIANGLE LASS T&Ct:REN 5 TLI04293OA INT. TIME
100% 34jl36 34:51
35:00
10:10
35:06
.2.6E5
.2.1E5
.1.5E5
.1. 0E5
.5.1E4
1O.OEO
Time
34:46
80J
602
40J
20J
OJ
4.5E6
3.6E6
12.7E6
1.8E6
19.1E5
34:30
s 1 r-
34 : 36
34:42
,—|—
34:48
34:54
35:00
35:06
IO.OEO
Time
319
-------
File:S975672 #1-390 Acq:5-SEP~97 10:08:14 EI+ Voltage SIR 70S
407.7818 F:4 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A INJ. TIME =
100% 34 37
10:10 File Text:RUN 5
TLI# 4 2»
_1.7E4
1. 5E4
1 . 4E4
33:40
32 : 51
1. 2E4
34 : 12
1 . 0E4
35 : 07
8 . 5E3
35 : 39
32: 34
6 . 8E3
33 : 16
32 : 0(.
5 . 1E3
3i5 : 23
3 . 4E3
1. 7E3
0 . 0E0
34 : 00
32:00
33 : 00
35:00
File:S975672 #1-390 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
409.7789 F:4 Exp:EPCUS /,
Sample Text: RUN 5 TLI#42930A INJ- TIME = 10:10 File Text: RUN 5
34:37
33:09
Time
TLI# 4 2»
.9 . 0E3
fj' •**"
32:11 32:32
8 . 1E3
7 . 2E3
3 5 : 4 C
6 . 3E3
33:29 33:48
35 : 27
34 : 56
5 . 4E3
35 : 19
34 : 08
4 . 5E3
:_3 . 6E3
3-2-^6
2 . 7E3
1. 8E3
9 . 0E2
0 . 0E0
33 : 00
34 : 00
35 : 00
Time
lOi
32:00
CO
«\3
o
-------
File:S975672 #1-867 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
303.9016 F:2 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A INJ. TIME
100% (^A3'.91E7)
80
60j
40i
20
Oj
1 1 1 1 1 1 1 1 1 1 P' I 1 1 1 1 1 1 1 | f 1 1 1 1 r-
17:00 17:12 17:24 17:36 17:48
18:00 ' " 18 : .12
10:10 File Text:RUN 5 TLI#42»
1.5E7
Ll.2E7
8.8E6
5.9E6
_2.9E6
Lo.oeo
Time
t-^t r -j—i—i—I T"11—I—I 1—i
18:24 18:36
File:S97 5672 #1-867 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
305.8987 F:2 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A ,, INJ. TIME
100%
-------
File:S975672 #1-867 Acq:S-SEP-97 10:08:14 EI+~Voltage SIR 70S
319.8965 F:2 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A INJ. TIME
100%
80i
60i
40.
20j
Oi
T"
20:08
10:10 File Text:RUN 5
4:23
22
23 :
19
~i 1 1 r~
~i—i r-—i—i—r~
t*—1—i 1—i—i—i—i 1 1 1—| 1 1 1 1 1 1 r—i 1 1 « 1—i e—i 1 1—|
16:00 17:00 18:00 19:00 20:00 21:00 22': 00 23:00 24 i 00 25
t:
TLI#42»
3 . 1E4
.2,5E4
LI.9E4
.1 .2E4
6 . 2E3
0 . 0E0
00 Time
File:S975672 #1-867 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
321.8936 F:2 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A INJ. TIME
10:10 File Text:RUN 5
54:23
100%
16:49
3 : 00
17 :3
TLI#42»
_3 . 3 E4 ( •
:.2 . 6E4
_2.0E4
l1.3E4
6 . 5E3
.0.0E0
00 Time
v 1—i—i—i—i—i—i—i—i—f—r-n—i—i—i—i—i—i—i—i—i—i—i—i—i—i—r—i—i—i—i—i—i—t—i—~i—i - ~t—i—r—i—j—p—i 1 »—i—i—i—i—i—r—\—
16 00 17:00 18:00 19:00 20:00 21:00 22:00 23:00 24:00 25
File:S975672 #1-867 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
331.9368 F:2 Exp:EPCUS
Sample Text:RUN 5 TLI#4293 0A INJ. TIME
100M
80j
60i
1
b
40J
20i
1
0;.
16 :
00
17 :02
6:30
17 :48
18:57
19 :33
20:32
,20:0?
1: 2
10:10 File Text:RUN 5
24 21
, j , , j , , , , , 1 1 1—i j 1 p
TLI# 4 2 »
.2 . 3E4
22:53 23:1
1.8E4
1. 4E4
23 :26
9 . 0E3
i4.5E3
*~"T ' \ T f !»- -T 1 1 J T-T- - , — r , - T r
22:00 23:00 24:00 25
.0.0E0
00 Time
iv
'CO
AO
-------
File:S975672 #1-867 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
319.8965 F:2 Exp:EPCUS
Sample Text .-RUN 5 TLI#42930A INJ. TIME = 10:10 File Text: RUN 5
100%
80 J
60
40 j
20
0J
TLI#42»
.3 . 8E5
»l ^ Ml
. 01E6
A3.49E5
23 :00
20:00 21:00 22:00
File:S975672 #1-867 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
321.893 6 F:2 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A INJ. TIME = 10:10 File Text:RUN 5
1001
-0.0E0
Time
TLI#42»
5.7E5
2,66E6J
2 .3E5
A4 .30E5
1.1E5
20:00 21:00 22:00
File:S975672 #1-867 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
331.9368 F:2 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A INJ. TIME =
100^ 21^32
21:45
80j
60i
40
20 J
23 :00
10:10 File Text:RUN 5
20:00
21:00
22 : 00
23 : 00
.0 .0E0
Time
TLI#42»
-1.8E6
.1.4E6
.1.1E6
J . 0E5
.3 . 5E5
O.OEO
Time
CO
lfO
-------
File:S975672 #1-867 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S "
339.8597 F:2 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A INJ. TIME = 10:10 File_I^xt:RUN 5
1.00%
5 . 3E5
2.6E5
A1.32E6 )
10:10 File Text:RUN 5
25 l05
24:24 24:30 24:36 24:42 24:48 24:54 25:00 25:06 25 : 12
File:S975672 #1-867 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
351.9000 F:2 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A INJ. TIME
100%
80
60
40
20 j
0
—i—|—r i i—|—i—i—i—i—i—|—i—i—i—i—i—|—i—i—r—i—i | i=f—r—i—i—j—i—i—i—i—i—|—i—-r—, | ,¦-
24:24 24:30 24:36 24:42 24:48 24:54 25:00 25:06 25:12
CO
45-
0.0E0
Time
TLI#42»
.1. 7E6
1.4E6
.1.0E6
-6.9E5
,3 . 4E5
.0 .0E0
Time
-------
File:S975672 #1-867 Acq:5-SEP-97 10
355.8546 F:2 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A
100%
80J
60
40
20J
08:14 EI+ Voltage SIR 70S
INJ. TIME = 10:10
A2.18E6>
0J
71 I'V
-rvT-r-r
» I I I I
24 :00
A3.03E5
File Text:RUN 5 TLI#42»
_8 . 4E5
6 . 7E5
l5.0E5
l3.4E5
1.7E5
23:12 23:24 23:36 23:48
File:S975672 #1-867 Acq:5-SEP-97 10:
357.8516 F:2 Exp:EPCUS
Sample Text:RUN 5 TLI#42 93 0A
100%
80 J
60i
40j
20J
"F"i—i | "iii i—i—|—i r rMi—i—|—I—r~?—i—i—|—i——i T [
24:12 24:24 24:36 24:48 25:00
08:14 EI+ Voltage SIR 70S
INJ. TIME = 10:10
.0.0E0
0J
T1 ^
23 :12
TT
rTT*i i i—i"T"i' pi T
23:24 23:36 23:48 24:00
File:S975672 #1-867 Acq:5-SEP-97 10:
367.8949 F:2 Exp:EPCUS
Sample Text:RUN 5 TLI#4293 0A
100%
C^Al /. 35E6y
(A2.30E5)
A_
i 1
T
25:12 25:24 25136 Time
File Text:RUN 5 TLI#42»
_6 . 4E5
5.1E5
t_3 . 8E5
.2 . 6E5
1.3E5
.0 .0E0
24:12 24:24 24:36 24:48 25:00
08:14 EI+ Voltage SIR 70S
INJ. TIME = 10:10
80j
60J
40J
20J
24 28
23 :36
24:12
23 : 52
24 : 50
4 : 40
25:12 25:24 25:36 Time
File Text:RUN 5 TLI#42»
.1. 5E4
ll.2E4
i_8.9E3
l5.9E3
l3.0E3
25 :12
25 :23
i—i—i—i—i—i—|—i—i—i—i—i—j—i—i—I—i—i—j—i—i—i—i—i—|—i—r
23:12 23:24 23:36 23:48 24:00
t—i—I—j—I—I—i—\—i—j—i—i—i—i—i—|—i—i—i—i—i—|—i—r—i—i—i—j i r"i"
24:12 24:24 24:36 24:48 25:00
L0.0E0
i—i—j—i—r~i—i—i—[—i—i—i—r~T—|
25:12 25:24 25:36 Time
to
-------
File:S975672 #1-425 Acq:5-SEP-97 10
373.8208 F:3 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A
100%
08:14 EI+ Voltage SIR 70S
8:49
28 :26
29:2.7
INJ. TIME = 10:10 File Text:RUN 5 TLI#42»
29 ; 59 r._3 . 9E4
3 . 1E4
t.2 .3E4
1. 5E4
- 7 .7E3
30:13 30:27 39.39 30:54,
~i r~
28:00 29:00
File:S975672 #1-425 Acq:5-SEP-97 10
375.8178 F:3 Exp:EPCUS
Sample Text:RUN 5 TLI#4293 0A
30:00
08:14 EI+ Voltage SIR 70S
INJ. TIME =
29:58
L0 .0E0
Time
10:10 File Text:RUN 5 TLI#42»
_3 . 2E4
100%
J2 . 6E4
ll.9E4
il.3E4
30:26
30:16 30:38
28:2
16.4E3
10..0E0
28:00 29:00
File:S975672 #1-425 Acq:5-SEP-97 10:08
383.8639 F:3 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A
100%
80j
60i
40i
20i
0:
28
00
n
A
30:00
14 EI+ Voltage SIR 70S
INJ. TIME =
29:54
Time
10:10 File Text:RUN 5 TLI#42»
4 . 2E5
l3 . 4E5
2 . 5E5
ll.7E5
18.4E4
29 :00
30:00
~l—~°—r
^ ¦¦ „ - -
Lo.oeo
Time
CO
i ro
CD
-------
File:S975672 #1-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
373 . 8208 F:3 Exp:EPCUS
Sample Text;RUN 5 TLI#42930A INJ. TIME
100%
10:10 File Text:RUN 5 TLI#42»
1.0E5
- 8.3E4
l6.2E4
i4.1E4
12.1E4
*"i—I—I—I—i—I—I—r-T—i—i—I—1~i—I—i—i—i—i—t | r I I i
28:48 28:54 29:00 29:06 29:12 29:18 29:24
File:S975672 #1-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
375.8178 F:3 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A INJ. TIME =
100%
> ti -0 . 0E0
29:30 29:36 29:42 Time
10:10 File Text:RUN 5 TLI#42»
7 . 2E4
5 . 8E4
4.3E4
12,914
ll ,4E4
*-f—i—i—i—r
28:48
_i—,—|—,—j—,—,—|—|—i—i—i—r—i—r—i—i—r~~i—j—|—i—r
28:54 29:00 29:06 29:12
1 t—r-
29:18
" l' ¦ I"1
29124
File:S975 672 #1-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
383.8639 F:3 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A INJ. TIME
100% 29;12
80i
60i
40i
20i
0
' 1 f=-T=-
28 :48
i t* i "¦ | "i 1 r1' i i r t r* i
28:54 29:00
T 1 1 ' ] T~*T
29:06
-•i—i—|—r—r
29 : 12
29 : 18
29 :24
0.0E0
"i—r—i—r—f—r—r—r~i—p'T—r " —i—r
29:30 29:36 29:42 Time
10:10 File Text:RUN 5 TLI#42»
4 . 8E5
i3.8E5
12.9E5
1.9E5
9.6E4
V- ¦ . , rri-r^-t-T-r^O . 0E0
29:30 29:36 29:42 Time
CO
-------
File:S975672 #1-425 Acq:5-SEP-97 10:08:14 EI+"Voltage SIR 70S
373.8208 F:3 Exp:EPCUS
Sample Text;RUN 5 TLI#42930A
100%
APR)
INJ. TIME
10:10 File Text
RUN 5 TLI#42»
.1.0E5
18.3E4
16.2E4
A7 .31
:4.1E4
2 . 1E4
h—i—|—i—i—i—i—i—|—r—i—i—i—i—r—i—r—i—i—f—i—ir" I ' i "1'' *1' | i » i55"55*!—i—|—i—i—i—i—i—|—i—nr
28:48 28:54 29:00 29:06 29:12 29:18 29:24
File:S975672 #1-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
375.8178 F:3 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A ... INJ. TIME =
100% c'A2.03E5N)
i—5—I—j—,—rh—i—|—r—r
29:30 29:36
10:10 File Text
, , tO.OEO
29:42 Time
RUN 5 TLI#42»
7 . 2E4
_5.8E4
l4.3 E4
:.2 . 9E4
•1.4E4
n—i—i—i—i—i—i—r—|—i—i—i—i—J—|—i—«—r—i—i—!—i—i—i—r
28:48 28:54 29:00 29:06 29:12
29 : 18 23\'M~~r~r29\io* 29 : 36
File:S975672 #1-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
383.8639 F:3 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A INJ. TIME
100% 29;12
80-i
60_i
40
20
10:10 File Text
0.
—i pTT I T* I I—I" T" I—I I" "[• I**' I T° I " r I r-1"1!'" I—I—I—I—I—r—i 7i" I T -f"-!—f~i—I—I—| 'T~ i—i—r
28:48 28:54 29:00 29:06 29:12 29:18 29:24 29:30 29:36
JlO.OEO
29:42 Time
RUN 5 TLI#42»
4.8E5
"3.8E5
i2,9E5
Ll.9E5
9.6E4
.tO.OEO
29:42 Time
. CO
OO
-------
File:S975672 #1-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
373.8208 F:3 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A INJ. TIME = 10:10 File Text:RUN 5 TLI#42»
100% A. ill I . _3.9E4
80j
60 J
40J
20j
0.
£A^45pb
~j—i—i—i—i—i—|—i—i—i—i—i—j—i—r—i—i—i—j—i—i—i—i—i—1
13.1E4
i_2 . 3E4
1.5E4
t-7 .7E3
.0 . 0E0
-i—i—i—i—i—|—i—i—i—i—i—|—i—i—i—i—i—j—i—i—i—i—i—|—i—i—i—i—i—j—r—i—i—i—i—|—i—i—i—i—i—|—r
29 00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 3 0:36 3 0 i 48 Time
File: S97 5672 #1-425 Acq:5-SEP-97 10:08:14 EI+- Voltage SIR 70S
375.8178 F:3 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A INJ. TIME = 10:10 File Text:RUN 5 TLI#42»
100%~\
3 . 2E4
1.2 . 6E4
A3 .46
1. 9E4
1.3E4
1.6 . 4E3
lO . 0E0
29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48
Time
File:S975672 #1-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
383.863 9 F:3 Exp:EPCUS
Sample Text:RUN 5 TLI#4293 0A INJ. TIME = 10:10 File Text:RUN 5 TLI#42»
100% A 29:54 4.2E5
80J 1 \ 13.4E5
60j I M l2 . 5E5
40J I \ Ll.7E5
20J \ \ L8.4E4
0_
1 I 'T'l "lr I
1 p r i *i "'i ¦ r" |-~i" i" r*'T i "| r i—i—i T| —f
—i—i—*i—|^-i i—i—r^i i-^i—r
.0 .0E0
29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48
Time
-------
File:S975672 #1-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
373.8208 F:3 Exp:EPCUS
Sample Text: RUN 5 TLI#42930A IN J. TIME = 10:10 File Text
100% 29;13
RUN 5 TLI#42»
_1.0E5
8.3E4
l6 . 2E4
29 :01
4 . 1E4
28:49
2 . 1E4
29:27
28:54 29:00 29:06 29:12 29:18 29:24
29:30 29:36
28:48
29 : 42
File:S975672 #1-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
375.8178 F:3 Exp:EPCUS
Sample Text: RUN 5 TLI#42930A INJ. TIME = 10:10 File Text
100%. 29; 13
L0.0E0
Time
RUN 5 TLI#42»
_7.2E4
5 . 8E4
29:01
i4.3E4
28:50
i2.9E4
11.4E4
29 :20
29:31
28 :48
28:54
29:00
29 :06
29 :12
29 :18
29 :24
29 :30
29 : 36
File:S975672 #1-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
383.8639 F:3 ExprEPCUS
Sample Text:RUN 5 TLI#42930A INJ. TIME = 10:10 File Text
100% 29;12
80 J
60 J
40 J
20j
0
t—i | 'i r i "i" i | i i1 i—i—i k i
28:48 28:54 29:00
I I | * "I —i 1—|—i —r
29:06 29:12
]—i i—i1" i t i i *1 i i 11 11 *i~"f i i "r" | r i
29:18 29:24 29:30 29:36
0.0E0
29 : 42 Time
RUN 5 TLI#42»
4 . 8E5
l3.8E5
l2.9E5
11.9E5
l9.6E4
0 . 0E0
Time
i "r i ¦ [
29 : 42
CO
1 CO
Q
-------
File:S975672 #1-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
389.8156 F:3 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A INJ. TIME
29 :42
10:10 File Text:RUN 5
100%
58:58
28:3
28:00
30:09
30:39
TLI#42»
.9.2E4
.7 . 4E4
L5.5E4
3 . 7E4
il.8E4
28:00 29:00 30:00
File:S975672 #1-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
391.8127 F:3 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A INJ. TIME = 10:10 File Text:RUN 5
30 : 53
a,^a-_ 0 . 0E0
Time
TLI#42»
9.7E4
29:42
100%
7 , 7E4
~5.8E4
28:58
il.9E4
30:42
27 :48
29:55 30:10
28:24
28:00 29:00 30:00
File:S975672 #1-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
401.8558 F:3 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A INJ. TIME = 10:10 File Text:RUN 5
29,42
100%
80
60
40.:
ft
r° r r
28:00
I /
L0.0E0
Time
TLI#42»
6 . 9E5
15.5E5
4.1E5
L2.8E5
:1.4E5
L.
29 :00
30:00
.0.0E0
Time
t
CO
-------
File:S975672 #1-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
3 89.8156 F:3 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A
100%
INJ. TIME = 10:10 File Text:RUN 5
TLI#42»
.9 . 2E4
29 :42
7 . 4E4
5 . 5E4
28:58
3 . 7E4
1.8E4
29:52
29:12
30:39
30:09
30:53
I 1 1
29:00
T 1 1 1 1 1 1 1 1 1 1 1 j 1 1 1 1 1 1 1 1 1 [ 1 1 1 1 1 [~
29:12 29:24 29:36 29:48 30:00 30:12
28 :48
File:S975672 #1-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
391.8127 F:3 Exp:EPCUS
Sample Text:RUN 5 TLI#4293 0A INJ. TIME
29:42
f~-|—i——r-j—j—i—r~i—i—» |i—i—j—j-
30:24 30:36 30:48
10:10 File Text:RUN 5
.0 . 0E0
Time
TLI#42»
.9 . 7E4
100%
7 . 7E4
5 . 8E4
3 . 9E4
1 . 9E4
30 :42
30 : 10
-i—|—i—i—i—i—i—j—i—i—i——r-"T—i—i—i—i—|—i—i—t—>—i—j—i—i—i—i—i—p~i—i—i—i—i—j—i—i—i—r i |—j—i—i—r—i—[—>—i—i—i—i—j—i—i—i—i—i |
28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48
File:S975672 #1-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
401.8558 F:3 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A
100%
80 J
60
40j
20j
0.
INJ. TIME = 10:10 File Text:RUN 5
-I—i—i—I—f—1—r
29:42
28:48 29:00 29:12
1 l 1
29:24
j ' i ir i ~i—i—|—i—r
29:36 29:48 30:00
i
i
30:12 30:24 30:36
=t—r"=,|—i—r
30 :48
0 . 0E0
Time
TLI# 4 2 »
-6 . 9E5
-5.5E5
.4 . 1E5
.2 . 8E5
.1. 4E5
_0 . 0E0
Time
'CO
CO
/\->
-------
File:S975672 #1-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
389.8156 F:3 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A
100%
INJ. TIME
10:10 File Text:RUN 5
TLI#42»
_9.2E4
"7.4E4
5.5E4
i3.7E4
l1.8E4
-j—i—i—i—i—i—i—j—i—r*~i——|—1" f i—i—r—|—r~i—r i t—|—i—i—i—i—i—pi—i—r—i—> • j T" i—i—i—i—pn—r-n—i—i | *1——r^-i—i—i—~i i—i Tr T i
28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24 30:36 30:48
File:S975672 #1-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
391.8127 F:3 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A INJ. TIME
100%
10:10 File Text:RUN 5
0.0E0
Time
TLI#42»
.9. 7E4
7 . 7E4
5.8E4
3 . 9E4
<
-------
File:S975672 #1-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
389.8156 F:3 Exp:EPCUS
Sample Text: RUN 5 TLI#429i2jQA INJ. TIME
100%, (5£_54E5)
10:10 File Text:RUN 5
-r^i—I pTT1 r i 1 nfp" I P f I
i" r P r i f " i 1 '|—r=*r
30:12 30:24
29:00 29:12 29:24 29:36 29:48 30:00
File:S975672 #1-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
391.8127 F:3 Exp:EPCUS
-i—f—i—|——i—i—r=—[—r—f-r
30:36
30:48
Sample Text:RUN 5 TLI#42g3JQA
100% ^7 55E5)
80
60j
40.:
20
INJ. TIME
10:10 File Text:RUN 5
•r-i—r
29100
¦ I '*?r
r t"| "i i—i—! T~p,'Trrn—r*j—ttt** ]—r~i r~~i—i—[ t-t -~i—r~p-i *7'^ n—|—r'V'iT
29:12 29:24 29:36 29:48 30:00 30:12 30:24
File:S97 5672 #1-425 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
401.8558 F:3 Exp:EPCUS
30:36
30:48
Sample Text:RUN 5 TLI#42930A
100%, . 29 ; 20
80
60j
40i
20
0J
INJ. TIME
10:10 File Text:RUN 5
' ' ' I 1 1
29:00
29:42
i r | i—f—»—«—i—i—t-
29:12 29:24
—i—i—i—r-j—I—i-**r*f i I—i—i—i—i—i—F—>—i—i—r—i—|—i—i—i—I — r'*'i—i—i—r~i—i-1*]—I—i—r-
29:36 29:48 30:00 30:12 30:24 30:36 30:48
TLI#42»
_4.1E5
i.3 . 3E5
.2 . 5E5
il.7E5
l8.3E4
_0.0E0
Time
TLI#42»
_3 .2E5
.2 . 6E5
.1.9E5
-1.3E5
.6.5E4
-0.0E0
Time
TLI#42»
.7 . 7E5
.6. 2E5
-4.6E5
.3 . 1E5
.1.5E5
.0 .0E0
Time
CO
if*
-------
File:S975672 #1-390 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
407.7818 F:4 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A INJ. TIME
100% 31 ;21
10:10 File Text:RUN 5
TLI#42»
_4.6E4
i3.7E4
l2.7E4
31 :41
"1.8E4
3:54 34:12
i9 . 2E3
32:00 33:00 34:00
File:S97 5672 #1-390 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
409.7789 F:4 Exp:EPCUS
Sample Text:RUN 5 TLI#4293 0A INJ. TIME = 10:10 File Text:RUN 5
100% 31; 21
80j
60 j
40j
20J
0i
31:41
33:09
| | | I I I I I I
32:00 33:00
File:S975672 #1-390 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
417.8253 F:4 Exp:EPCUS
"¦ 1 r
34 :00
Sample Text:RUN 5 TLI#42930A
INJ. TIME = 10:10 File Text:RUN 5
100%
80 J
60
40
20 j
0
31:21
32 :31
L.
32 :02
a -1 —
32 : 00
33 :00
33 : 58
34 :00
.0 .0E0
Time
TLI#42»
_5.4E4
_4.3E4
_3 . 2E4
_2 . 2E4
Ll.1E4
-0.0E0
Time
TLI#42»
.2 . 0E5
.1 . 6E5
.1.2E5
.7 . 9E4
.4 . 0E4
.0 .0E0
Time
, Co
-------
File:S975672 #1-390 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
407.7818 F:4 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A INJ. TIME
100% A1.20E5
10:10 File Text:RUN 5
TLI#42»
4 . 6E4
:3 . 7E4
_2.7E4
1. 8E4
9 . 2E3
32:00 33:00
File:S975672 #1-390 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
409.7789 F:4 Exp:EPCUS
Sample Text:RUN 5 TLI#42 930A INJ. TIME
100% A1.16E5
34 :00
10:10 File Text:RUN 5
0 ,0E0
Time
TLI#42»
.5 . 4E4
i4.3E4
3 . 2E4
2 . 2E4
il.1E4
32:00 33:00
File:S975672 #1-390 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
417.8253 F:4 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A
100% 31;21
INJ. TIME
34 :00
10:10 File Text:RUN 5
32:31
32 :00
33 :00
33 : 58
-¦A.-p
34 :00
.0 .0E0
Time
TLI#42»
_2 . 0E5
_1. 6E5
.1.2E5
L7.9E4
i4.0E4
:o.oeo
Time
» Co
Co
O)
-------
File:S975672 #1-390 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
457.7377 F:4 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A INJ. TIME
100%
10:10 File Text:RUN 5
TLI#42»
.1.7E4
il.4E4
A3!07 E4J
11.0E4
l6.8E3
l3.4E3
34:00 35:00
File:S975672 #1-390 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
459.7348 F:4 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A INJ. TIME =
A3.94E4 )
10:10 File Text:RUN
0 . 0E0
Time
TLI#42»
1.3E4
100%
1. 1E4
1.7 . 9E3
5.3E3
-2.6E3
34:00 35:00
File:S97 5672 #1-390 Acq:5-SEP-97 10:08:14 EI+ Voltage SIR 70S
469.7779 F:4 Exp:EPCUS
Sample Text:RUN 5 TLI#42930A
100%
80j
60
40j
20J
INJ. TIME
10:10 File Text:RUN 5
OJ
34:38
— -
34:00
-="=1-
1
0.0E0
Time
TLI#42»
,2 . 3E5
-1.8E5
11,4E5
9.1E4
4.6E4
r* —-r
35:00
-i "r
0.0E0
Time
Co
CO
.-vj
-------
J-;''Groiipl
TLI Project:
Client Sample:
42930A Method 23 TCDD/TCDF Analysis (DB-225)
RUN5 Analysis File: X973018
Client Project:
Sample Matrix:
TLI ID:
Iron & Steel-Youngstown
M23TRAIN Date Received:
179-98-7A-D Date Extracted:
Date Analyzed:
08/19/97
08/25/97
09/07/97
Spike File: SPC2NF04
ICal: XF24087
ConCal: X973009
Sample Size:
Dry Weight:
GC Column:
1.000 Dilution Factor:
n/a Blank File:
DB-225 Analyst:
n/a
S975665
ML
% Moisture: n/a
% Lipid: n/a
% Solids: n/a
| Analytes
Amt (ng) DL.
EMPC
Ratio RT
Flags
2,3,7,8-TCDF
11.2
0.77 23:01
—
1 Internal Standard
Amt. (ng} % Recovery QC Limits
Ratio RT
Flags
!3Ci;-2,3,7,8-TCDF
3.1 77.9
40%-130%
0.76 23:00
—
1 Recovery Standard
Ratio RT
Flags
I3C.:-1,2,3,4-TCDD
0.78 21:58
Data Reviewer _ 09/08/97
Page 1 of 1 CZNF.PSR V2.00. LARS 6 10 W
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
338
Printed: 17:58 09/08/97
-------
Initial ...-Dace...
Daea Review By: Calculated Noise Area: n/a
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No.
09/03/97
Listing of X973018B.db£
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.... QC.Log Omit Why
. RT. OK .Ratio Total .Area. . . Area. Peak. 1. . Area. Peak. 2. . Rel. RT Compound. Name. . ID.. Flags.
TCDF
304-306
304-306
13C12-TCDF
316-318
316-318
0.
65-0.89
0.79
8-1.102
DC
NL
0: 00
RO
2.09
10.27
0.000
DC
ML
18: 18
RO
6.71
1.663.70
0.796
18:33
RO
0.46
23 .98
10.43
22.91
0. 807
18:48
RO
1.12
19,463.45
12,300.50
10,996.30
0.817
19:00
0.83
194.18
88.20
105.98
0.326
19:42
0.76
25.111.60
10,842.40
14,269.20
0.857
19:49
0.76
14,709.76
6,370.39
8,339.37
0.862
19:56
0.79
20,816.33
9,212.23
11,604.60
0.367
20:06
0.77
13,940.03
6,065.67
7,374.36
0.374
20:21
0 . 77
10,630.19
4,624.96
6,005.23
0.335
20:29
0.77
20,229.28
3,316.98
11,412.30
0.391
20: 39
0.75
8.980.02
3.859.44
5,120.58
0.898
20:47
0.77
37,415.20
16.244.70
21,170.50
0.904
20:56
0.75
7,520.28
3.231.55
4,283.73
0.910
21:16
RO
1.23
22.173.35
15.363.30
12.527.60
0.925
21: 34
RO
0.49
45.17
19.65
39 .72
0. 938
21:42
0.78
21,432.75
9,363.25
12,064.50
0. 943
21: 56
0.76
11,804.02
5,092.77
6,711.25
0.954
22:09
0.75
13,686.96
5,858.82
7,828.14
0.963
22:21
0.85
1,174.95
533,61
636.34
0.972
22:30
0.81
8,922.40
3,992.00
4,930.40
0.973
22: 53
0.80
7,262,38
3,222,65
4,039.73
0.995
23:01
0.77
7,435.92
3,235,33
4,200.54
1.001 2373-TCDF
23:13
0.79
6,919.91
3.064.41
3,355.50
1 . 009
23:30
0.78
5,645.41
2,470.15
3,175.26
1. 022
23:37
0.78
10,758.34
4,710.38
6,047.46
1.027
24:24
0.79
5,106.30
2,251.90
2,354.40
1.061
25:08
0.80
572.58
253.96
318.62
1.093
26
Peaks
301,975.74
0
65-0.89
0.956-1.044
DC
NL
0:00
RO
1.34
22.89
0.000
DC
WL
18:23
RO
4.17
45.28
0.799
DC
WL
18:33
RO
3.27
55.63
0.807
DC
WL
18:41
RO
1.10
199,55
0.312
DC
WL
19:08
RO
1.84
13 .54
0.832
DC
WL
19:17
RO
2.12
30.55
0.838
DC
WL
19:29
RO
2.21
28.50
0.347
23:00
0.76
2,747.45
1,190.49
1,556.96
1.000 13C12-2378
1
Peak
2,747.45
AN
Above: TCDF / TCDD Follows
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 17:59 09/08/97
339
-------
Page No.
09/03/97
Listing of X973018B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z.. . . QC.Log Omit
Why
. .RT.
OK
Ratio Total
.Area... Area.Peak.1.. Area.Peak.2..
Rel.RT Compound.Name..
13C12-TCDD
0
65-0.89
0.
907-1.093
332-334 DC
NL
0:00
RO
1.70
8.28
0.000
DC
WL
19: 19
RO
2.63
5.01
0.389
20:37
0.74
19.75 8.40 11.35
0. 949
DC
SN
20:55
RO
2.40
2.92
0.963
21:43
0 . 78
2,110.70 922.42 1.188.28
1.000 13C12-2378-TCDD
21:58
- 0.78
2,533.49 1,108.09 1,425.40
1.012 13C12-12 34-TCDD
22: 36
0.76
46.21. 20.01 26.20
1. 041
DC
SN
22: 59
RO
1 . 09
1.73
1.058
DC
SN
23:24
RO
1.31
4.96
1 . 073
DC
SN
23: 31
RO
1.70
6. 16
1. 083
DC
SN
23:40
RO
0 . 96
10.05
1. 090
DC
WH
24: 06
0 . 69
10.77
1.110
DC
WH
24: 16
RO
2.33
4.73
1.117
DC
WH
24:24
RO
3.76
4.19
1.124
DC
WH
24:42
RO
0.93
10.66
1 . 137
332-334
4
Peaks
4,710.15
ID.. Flags.
Column Description.
"Why" Code Description QC Log Desc.
M_Z -Nominal Ion Mass(es)
. .RT. -Retention Time (mm:ss)
Rat
OK
Rel
. 1 -Ratio of M/M+2 Ions
-RO=Ratio Outside Limits
.RT-Relative Retention Time
End of Report
WL-Selow Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
Plla!JCS73018 tl-12B5 Xcq> 7-SSP-1S97 OOlUtll X ST* Volbmffm 3IR luto£pac
303.9016 XxptXCOaPJTT
Smaplm Tmxt>RUNS TLX04293OJL Film Tmxti TRULDOLX mm
1001
55j
90l
as.
80.
75.
70.
ffS:
60.
55.
SO.
45.
40.
35s
30l
25l
20l
lSl
101
Sj
Ol
19t00 19i12 19:24 19'i36 19>48 20x00 20>12 20t24
Film>1373018 §1-1285 Xcqi 7-SEP-1997 00t44tl2 <3C SI+ Voltaa* SIX Autosome
305.8987 BxptZCONP_TT
Sanplm Tmxt>RUNS TLI142930JL Film Tmxtt TRZJkSOLX umr
100*
19 >42
-.3.0X7
2.8X7
2.6X7
2.4X7
19t56
.2.2X7
-2.0X7
19149
.1.8X7
20i06
1.7X7
1.5X7
1.3X7
20t39
1.1X7
9.2X6
h7. 4SS
S.5X6
3.7X6
.8X6
20t36
20 >48
21>00 Timm
20 >47
.4.9X7
4.6X7
4.4X7
4.1X7
19:42
3.9X7
3.7X7
3.4X7
3.2X7
J. 9X7
19 >56
19 >49
2.4X7
20t0S
2.2X7
1.9X7
.1.7X7
1.5X7
20t21
_9.7X6
.7.3X6
.4.9X6
0.0X0
x—I
20t48
19 >00
19>12
19 >48
20 tOO
20>12
00 Time
341
-------
\FilmtlS7301B H-12B5 Ictji 7-3SP-1997OOtUtil X SI* Volkmgm 3IS Xako3pmc Soi*mtS073
303.9016 BSBB(256,30,-3.0) PXD(5,3.1,0.10*,24292.0,0. 00%,F,F) **p»ZCCMF_W
Smaplm TmxtIRONS TLI04293OA Film Tmxtt fRXASOLX LABS
200S
so:
so:
40:
201
0.
20:00 21 too 22'tOO 23>00 24t00
FilmtX973018 §1-1285 Acgt 7-3*9-1997 00t44>12 OC XX* Voltmgm SXR AuteSpmc Soimm>2901
305. S987 BSm(256, 30,-3. 0) PXD (5, 3,1,0.10*, 11604.0,0. 00%, F,F) XxptlCCMPJtt
3 nop Is TmxtiRUNS TLX04293OX Film Tmxtt TRIADBLE LABS
10m *2.12*8
A1.62E8
At.08*8
A1.23S8
AS. 82*:
a
X.
"P
19100
I1
07*7
ill
At.54X8
15.86X7
A3.99*7
A4.71X7
A2.25B7
T
A
> i ^
25100
.3.737
13.027
12.2*7
11.5*7
.7.4*6
10.0*0
Timm
4.9S7
A1.43X8
3.9*7
A1.25S8
2.9*7
A7.83B7
A4.93B7
1.9*7
A6.Q5B7
86S7
9.7X6
A2.8SE7
A
25t00
sol
603
Al.
10S8
402.
202
I
o\-
'
25*00 '
22 tOO
23100
24 >00
20tOO 21tOO
FilmtX973018 01-1285 Acq; 7-3SF-1997 00>44>t2 OC XZ* Voltmgm SIS AutoSpmc Naimmt8687
315.9419 BSZtB(256,30,-3.0) PXD (5,3.1. 0.10\, 34748.0, 0. 00\, F, F) ExptXCmPJlT
Smavlm TmxttRUNS TLX04293OA Film fttti TRXANBL* LABS
100% At. 19*7
80.
60.
40.
20.
0.
Al.03*6
aAn
A3.66X5
¦pn A A I
ni" i1 i •r ) •'i ¦" i [ )• i i i t
.0.0*0
?ia«
3.0*6
2.4*6
,1.8*6
1.2X6
.6.0*5
19i00 20i00 2li00 22>00 23t00 24t00
FilmtX973018 01-1285 Aagt 7-8XF-1997 00>44>13 OC SX* Voltmgm SXR AntaSpme Balmm>6467
317.9389 amm(2§6,30,-3.0) PXD{5,3.1,0.10*,25868.0,0.OOH.F.F} *xptXCCm_TT
Smaplm TmxetRm5 TLX04293OA Film tmxtt TRIANBLE LABS
20A A1.S6X7
80.
60.
4o:
20£
0.
25 tOO
to. mo
tilam
A1.13E6
3.9*6
13.2*6
J. 4*6
.1,6*6
.7.9X5
AS.25X5
19'tOO 20t00 21t00 22 tOO 23 >00 24 >00
Pilm>Z973018 01-1285 Aeq> 7-SEP-IS97 00>44t12 OC SX* Voltmgm SIR AntoSpmc
375.8364 Bxp>XCOXF_rr
Smml* Tmxt>Rm5 TLX04293OA Film Tmxt> TMXAmLX LABS
21,26
i r1'1"
25 >00
LO. 0X0
TSMm
1 OOH
6.6S4
5.3*4
22 >2j
23114
22 >56
20t07
.3.9X4
18 >32
24>42
19t48
2.6*4
.1.3*4
24t00
19 >00
20 >00
21 >00
22 >00
23 tOO
->—i—i—j-
25 tOO
.0.0*0
Timm
342
-------
PUm,Z97301B *1-1385 Xeq, 7-MMP-1997 00,44,13 X SI* Volbrngm SIR AutaSp*c Soimm,3333
3X3*8965 3SUB(256,30, -3.0) PKD(5,3,1, 0.10%, 13328.0.0. 00*,F,F) *xp,XOXF_TT
So*l( Tmxt,XBH5 TLX842930A Film Tmxt, TXXAmL* LABS
IOCS
so:
60C
40C
20:
A4.64S6
1
X1.3SSI
J13.41*6
A4.26S6
A4.06*6
6,83X3
A1.90X6
\ll.24S6
,4.06*5 H «.A A4.98S5
, A,
M
mfjhtlm
T
20,00 21:00 22,00 23,00 24,00
Film,2373018 §1-1283 Aeg* 7-SXF-1997 00,44,13 OC XX* Voltmgm SIX AutoSpmc Sbi»m,7341
331.8936 BSUB(256,30,-3.0) PKD(5,3,1,0.10*,29364.0, 0.00%,F,F) SxptXCOSF.TT
Stuplm TmxttXnBS TLX842930A Film Tmxti TRZANOL* LABS
lom A4.$7*6
A6.93X5
I
.1.5*6
.1.2*6
.9.1*5
.6.1*5
13.0*5
.0.0*0
80.
60.
40.
20.
f"l ' ["'| "V |' 1 I ' > I|l"*''l ! I1* l""> T11 I I'l ¦ M
20,00 21,00 22,00 23,00 24,00
Film:Z973018 §1-1285 Acq, 7-SSF-1997 00,44,12 OC SX* Vol tag* SIX Au6oStp*c Hoimmt3215
327.8847 BSOB(256,30,-3.0) PMD(5,3,1,0.10*,12860.0,0.00*,F,F) *xp,XCOHF_TT
Saaplm TmxttXtmS TLX*42930A Film Tmxt, TXIAHOLX LASS
100*A1.44E7 A1.97S7
80.
__
/uui nf\/A: A/V f\l \
30,00 21:00 22,00 23,00
Film,X973018 §1-1285 Aeq, 7-SSP-1S97 00,44,12 OC SX* Voltmgm SIX AutoSpma Sola;3976
331.9368 Bsm(256,30,-3.0) FXB{5,3,1,0.10*. 15904.0,0.00*,F,F) SxptXCOHFJlT
Samplm Tmxt :BmS TLX§43930A Film Tmxt, TXXANBLB LABS
A 4.34*6
A3.45*6
A3.09*6
114.45*6
A2.42B6
A1.63S6
6.33*5
AS.02*5
A6.13S6
A4.16*6 A3.88*6
A1.07B7
A1.16S7
r
24,00
IOCS
801
so:
40.
20.
01*.
A1.11X7
A3.22*6
•A
Jh.
f r
20,00 21,00 22,00 23,00 <¦' 24,00
Film,Z973018 §1-1285 Aeq: 7-SEF-1997 00,44,12 OC XX* Voltmgm SZX AutoSpma Soitm,2341
333.9338 BSSm{256,30,-3.0) FKD(5, 3,1,0.10%,9364. 0,0. 00*,F,F) XxpiXCOSFJIT
Samplm TmxttMXmS TLX§42930A Film Tmxt, TXXAmL* LABS
100*
80.
60.
40.
30.
0.
A1.43*7
A1.19X7
-f
-r-
20,00
21,00
a
22,00
r | i 111 1 r i" i I "i1111 i
23,00 24,00
Timm
1.9*6
1.5*6
,1.1*6
.7.6*5
3.8*5
AS.62*5
0. 0*0
Timm
-.5.4*6
-4.4*6
3.3*6
2.2*6
1.1*6
0. 0*0
Timm
-2.9*6
L2.3JTS
.1.8*6
1.2*6
L5.8S5
rn.ttw/i
Timm
,_3.8*6
3.0*6
'J. 3*6
11.5*6
.7.5*5
0.0*0
Timm
343 -|
-------
FilaxX973018 #1-1285 Acq: 7-SXP-1997 00t*4ll2 OC XI* Voltmgm SIR JLUtoajp«c
303.9016 Xxp:XCOSF_TT
Staaplm futt HUN5 TLX04293OA Film Tmxti TRZAHOLX LABS
1009
80:
60.
I i '<
19 tOO
18i33
A A/v 25,17
ITT; I fil iV) i
20:00 21:00 22:00 23t00 24:00 25:00
Film:X973018 $1-1285 Acq: 7-SXP-1997 00:44:12 OC SI* Voltmgm SIR AutoSpmc
315.9419 Sxp:XCONF_TT
Sax&lm Tmxt:ROBS TLX04293OA Film Tmxt: TKLUK3LB LABS
20® 23f00
80:
60:
40.
20.
Oj
¦*»
f "i" 'I1111 t —i i
23:00
—i—J—r—
24:00
19:00 20:00 21:00 22:00
FilmtX973Q18 #1-1285 Acq: 7-SXP-1997 00x44:13 OC XI* Voltmgm SIR AutoSpmc
330.9792 Xxp:XCOBP_TT
Smaplm Tmxt::SmS TLI142930A Film Tmxt: TRXABQLX LABS
101* 18:5019:15 M,17 21:15 oi.ma it.in
25:00
.0. 0X0
Tima
3.6X7
12.8X7
-2.1X7
1.4X7
7.1X6
19:00
20:00
21:00
22:00
23:00
24:00
25:00
£.0.0X0
Tima
344
-------
Peak Locate Examination: 7-SEP-1997:00:43 File:X973018
Experiment:XCONF_TT Function:1 Reference:PFK
PPM
200
Volts
0.2871
jl
292.95315 292.98245 293.01175
PPM
200
Volts
0.3234
330.94615 330.97925 331.01235
PPM
200
Volts
0.2154
380.93795 380.97604 381.01414
1 CO
-------
I
ITLI Project:
Client Sample:
I
I
I
I
I
I
I
I
I
I
I
I
I
I
1
I
42930A
FB2
Method 23 PCDD/PCDF Analysis (a)
Analysis File: S975673
Client Project:
Iron & Steel-Youngstown
Sample Matrix:
M23TRAIN
Date Received: 08/19/97
Spike File:
SPX23704
TLI ID:
179-98-8A-D
Date Extracted: 08/25/97
ICal:
SF56117
.
Date Analyzed: 09/05/97
ConCal:
S975664
Sample Size:
1.000
Dilution Factor: n/a
% Moisture:
n/a
Dry Weight:
n/a
Blank File:
S975665
% Lipid:
n/a
GC Column:
DB-5
Analyst:
HLM
% Solids:
n/a
Analytes
Amt. (ng)
DL
EMPC
Ratio
RT Flags
2,3,7,8-TCDD
ND
0.02
1,2,3.7,8-PeCDD
ND
0.03
1,2,3,4,7,8-HxCDD
ND
0.02
1,2,3,6.7,8-HxCDD
ND
0.02
1,2.3,7,8.9-HxCDD
ND
0.02
1,2,3.4.6.7.8-HpCDD
ND
0.03
1.2.3.4,6.7.S.9-OCDD
EMPC
0.21
—
2,3,7,8-TCDF
ND
0.01
1,2,3,7,8-PeCDF
ND
0.02
2,3,4,7,8-PeCDF
ND
0.02
1,2,3,4,7,8-HxCDF
ND
0.01
1,2,3,6,7,8-HxCDF
ND
0.01
2,3,4,6,7,8-HxCDF
ND
0.01
1,2,3,7,8,9-HxCDF
ND
0.02
1,2.3.4.6,7,8-HpCDF
ND
0.02
1,2.3,4,7,8,9-HpCDF
ND
0.02
1.2.3.4.6,7.8.9-OCDF
ND
0.08
Total TCDD
ND
0.02
Total PeCDD
ND
0.03
Total HxCDD
ND
0.02
TotaJ HpCDD
ND
0.03
Total TCDF
ND
0.01
Total PeCDF
ND
0.02
Total HxCDF
ND
0.01
Total HpCDF
ND
0.02
Page 1 of 2
X237.PSR v20Q, LAJRS (5.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 16:31 09/08/^ 0
-------
TLI Project: 42930A Method 23 PCDD/PCDF Analysis (a)
Client Sample: FB2 Analysis File: S975673
interna} Standards
Amt (ng)
% Recovery
QC Limits
Ratio
RT
Flags |
l3C,;-2,3,7,8-TCDF
3.3
82.3
40%-130%
0.73
20:44
i3C;;-2,3,7,8-TCDD
2.7
67.9
40%-130%
0.89
21:31
13Ci2-l,2,3,7.8-PeCDF
2.4
60.8
40%-130%
1.48
24:57
>3C,2-1,2.3,7,8-PeCDD
2.1
51.7
40%-130%
1.44
26:04
uCi2-l,2,3,6,7,8-HxCDF
4.3
107
40%-130%
0.48
28:38
»C,;-l,2,3,6J,8-HxCDD
4.0
99.4
40%-130%
1.20
29:20
"Ci2-l,2,3,4,6,7,8-HpCDF
3.5
87.0
25%-130%
0.45
31:18
13Ci:- 1,2,3,4,6,7.8-HpCDD
3.2
79.8
25%-130%
1.04
32:09
l3Ci:-l,2,3,4,6.7,8,9-OCDD
2.8
35.0
25%-130%
0.93
34:37
Surrogate Standards {Type A)
Amt. (ng)
% Recovery
QC Limits
Ratio
RT
Flags |
37CL-2,3,7,8-TCDD
3.9
97.0
70%-140%
21:32
13Cii-2,3,4»7,8-PeCDF
3.5
86.3
70%-140%
1,76
25:42
,3Ci2- 1,2,3,4,7,8-HxCDF
3.7
92.9
70%-140%
0.53
28:32
13Ci2-l,2,3,4,7,8-HxCDD
3.7
91.9
70%-140%
1.20
29:16
IJCi2-l,2,3,4,7,8,9-HpCDF
2.8
70.3
70%-140%
0.42
32:30
—
| Alternate Standards {Type A)
Amt. (ng)
% Recovery
QC Limits
Ratio
RT
Flags j
,3Ci 2-1,2,3,7.8,9-HxCDF
2.7
68.3
40%-130%
0.50
29:51
13C 12-2,3,4,6,7,8-HxCDF
3.4
84.9
40%-130%
0.51
29:08
l3Cia-l,2,3,4-TCDD
0.82
21:19
1JCi;-l,2,3.7,8,9-HxCDD
1.26
29:38
Data Reviewer. Skj 09/08/97
Page 2 of2 X237.PSR vZOO. LARS 6.10.04
Triangle Laboratories, Inc.®
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 16:31 09/08/97
347
-------
Initial ....Date,..
Data Review By: Calculated Noise Area: 0.94
The Total Area for each peak with an ion abundance ratio outside
ratio limits has been recalculated according to method requirements.
Page No. 1
Listing
of S975673B
.dbf
09/03/97
Matched
GC Peaks /
Ratio / Ret. Time
Compound/
M_Z.... QC.Log
Omit
Why
. ,RT.
OK
.Ratio Total
.Area... Area.Peak.1.. Area.Peak.2.. Rel.RT Compound.Name..
TCDF
0
65-0.89
0.327-1.099
304-306
DC
NL
0:00
RO
1.23
0.23 0.000
D
DC
SN
17: 14
0.35
4.53 0.331
DC
SN
21:14
RO
0.61
2.53 1.024
DC
SN
22:07
RO
2 . 07
0.73 1.067
304-306
0
Peaks
0.00
13C12-TCDF
0
65-0.89
0.952-1.048
316-313
DC
NL
0:00
RO
0.93
0.25 0.000
20:44
0.73
739.58 334.36 455.22 1.000 13C12-2378-TCDF
DC
WH
22:13
0.75
1.85 1.072
DC
WH
22:53
RO
0.44
1.38 1,104
316-313
1
Peak
739.58
Above: TCDF / TCDD Follows
TCDD
320-322
320-322
0.
65-0.89
0.361-1.058
DC
NL
0: 00
RO
1.13
0.19
0.000
DC
SN
18.-36
RO
0.30
0.25
0.364
DC
SN
18:47
RO
2. 15
0.48
0.373
DC
SN
19:02
RO
2.80
0.13
0.335
DC
SN
19: 18
RO
0.24
0.21
0. 397
DC
SN
19:44
RO
2.11
0.48
0.917
DC
SN
20:44
RO
1,49
1.26
0.964
DC
SN
21:19
RO
1.05
1.35
0.991
DC
SN
21:32
RO
0.33
0.51
1.001 2373
DC
SN
21:51
RO
1.13
0.57
1.015
DC
SN
21:55
RO
0.62
0.30
1.019
DC
SN
22: 10
0.37
1.01
1.030
DC
SN
22:24
RO
4.19
0.28
1.041
DC
WH
22: 53
RO
0. 50
0.53
1.064
0
Peaks
0.00
AN
37C1-TCDD
328
0.907-1.093
DC
NL
0
00
0.12
0.000
DC
WL
18
32
0.19
0.861
DC
WL
13
33
0.15
0.866
DC
WL
13
41
0.19
0.868
DC
WL
13
54
0.44
0.878
DC
WL
19
00
0.42
0.883
DC
WL
19
30
0.77
0.906
DC
SN
19
47
0.51
0.919
DC
SN
19
55
0.63
0.926
20
02
8.50 8.50
0.931
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 16:32 09/08/97
348
-------
Page No. 2
09/08/97
Listing of S975673B.db£
Matched GC Peaks / Ratio / Set. Time
Cotnpound/
M_Z. . . . QC
328
13C12-TCDD
332-334
332-334
PeCDF
340-342
Omit
Why
. . RT.
OK
Ratio Total
.Area... Area
Peak.1.. Area.Peak. 2. . Rel.RT Compound.Name. .
DC
SN
20:
12
0.44
0.939
DC
SN
20:
21
0.67
0.946
DC
SN
20:
28
0.81
0. 951
DC
SN
20:
35
0.33
0.957
DC
SN
20:
40
0.29
0.960
DC
SN
20:
55
0.54
0.972
DC
SN
21:
15
.
1.20
0.988
DC
SN
21:
23
0.22
0.994
21:
32
431.06
431.06 1.001 37C1-TCDD
21 :
51
3.57
3.57 1.015
22:
02
1.77
1.77 1.024
DC
SN
22:
11
0.16
1.031
DC
SN
22:
20
0.1$
1.038
DC
SN
22:
31
1.04
1.046
DC
SN
22:
37
0.44
1.051
DC
SN
22:
42
0.40
1.055
DC
SN
23:
02
1.07
i.070
4
Peaks
444.90
0
65-0.39
0.907-1.093
DC
NL
0
00
RO
7.86
0.25
0.000
DC
WL
18
42
RO
0.09
0.16
0.369
DC
WL
19
07
RO
2 . 48
0.74
0.888
DC
SN
19
36
SO
2 . 32
0.60
0.911
DC
SN
19
53
SO
1.22
1.12
0.924
DC
SN
20
05
RO
1 . 67
1.47
0.93 3
DC
SN
20
16
RO
2. 37
1.93
0.942
21
19
0. 32
727.78
328.83 393.95 0.991 13C12-1234-TCDD
21
31
0.89
526.99
247.99 279.00 1.000 13C12-2373-TCDD
21
53
0. 30
9.69
4.31 5.38 1.017
DC
SN
22
26
RO
0.98
1.63
1.043
DC
SN
22
43
RO
1.37
1.77
1. 056
DC
SN
22
53
RO
2.04
0.90
1.064
DC
SN
23
08
RO
2.22
0.57
1.075
3
Peaks
1,264.46
ID.. Flags.
]
SUR1
Above: TCDD / PeCDF Follows
1.
32-1.78
0,910-1.G*
DC
NL
0
00
RO
0.93
0.21
0.000
DC
SN
23
20
RO
1.28
0.38
0.935
DC
SN
23
41
RO
0.70
1.25
0.949
DC
SN
23
48
RO
0.54
0.53
0.954
DC
SN
24
01
RO
1.88
1.71
0.963
DC
SN
24
12
RO
3.35
0.59
0.970
DC
SN
24
35
RO
0.41
0.46
0.985
DC
SN
24
41
RO
2.09
0.59
0.989
DC
SN
25
06
RO
2.33
0.99
1.006
DC
SN
25
13
1.35
1.08
1 .011
DC
SN
25
51
RO
1.10
0.90
1.036
DC
SN
26
15
SO
0.20
0.02
1.052
DC
SN
26
21
1. 36
0.59
1.056
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713 Printed: 16:32 09/08/97
Phone: (919) 544-5729 • Fax: (919) 544-5491 349 *
-------
Page No. 3
09/08/97
Listing of S975673B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_Z QC.Log Omit
Why ..ST. OK Ratio Total.Area... Area.Peak.1.. Area.Peak.2. . Rel.RT Compound.Name.. ID., Flags.
340-342
13C12-PeCDF
352-354
352-354
PeCDD
356-358
356-358
13C12-PeCDD
368-370
368-370
DC
SN
26:
30
RO
0.49
0.46
DC
WH
27:
06
RO
0, 53
0.49
0
Peaks
0.00
1 .
32-1.78
DC
HL
0:
00
RO
0.75
0.20
DC
SN
22:
42
RO
_ 1.25
0.58
DC
SN
24:
03
RO
1,90
2.75
DC
SN
24:
34
RO
3.01
1.76
24:
57
1.48
501.21
25:
11
RO
1.38
5.23
25:
42
1.76
419.75
25:
59
RO
1 .79
4.23
DC
SN
26:
11
RO
0. 91
0.95
DC
SN
26:
23
RO
2.42
0.61
DC
SN
26:
33
RO
0, 55
0.67
DC
SN
26:
49
RO
0."
0.82
DC
SN
26:
55
RO
0. ?8
0.69
DC
SN
27
11
RO
4.00
0.51
4
Peaks
930.42
PeCDF /
1 .
32-1.78
DC
NL
0
00
RO
0.92
0.18
DC
SN
24
21
RO
0 , 54
0.30
DC
SN
24
28
RO
0.48
0.77
DC
SN
24
53
RO
1.15
2.04
DC
SN
25
34
RO
1. 17
0.23
DC
SN
25
51
RO
1 .79
0.36
DC
SN
26
04
RO
0. 59
0.21
DC
SN
26
11
RO
3 . 96
0.69
DC
SN
26
23
RO
1 11
0.16
DC
SN
26
33
RO
0. 22
0.33
DC
WH
27
01
RO
6.22
0.46
0
Peaks
0.00
1
32-1.78
DC
NX.
0
00
RO
0.35
0.18
DC
SN
24
03
1. 39
1.27
DC
SN
24
39
1.45
0.93
DC
SN
24
50
RO
4.29
0.18
DC
SN
24
56
RO
19.00
0.15
DC
SN
25
22
RO
1 . 90
1.30
DC
SN
25
30
RO
0. 33
0.33
26
04
1.44
238.94
26
11
RO
1.25
28.26
DC
SN
26
26
RO
7.00
0.54
2
Peaks
267.20
299.14
3.35
267.76
2.97
1. 062
1. 086
0.840-1.160
0.000
0.910
0.964
0.985
202.07 1.000 13C12-PeCDF 123 IS2
2.05 1.009
151.99 1.030 13C12-PeCDF 234 S0R2
1.66 1.041
1.049
1.057
1. 064
1 . 075
1. 079
1 . 090
AK
141.08
17.18
97.86
13.79
.923-1.025
0.000
0.934
0.939
0.955
0. 981
0. 992
1.000 12373-PeCDD
1. 004
1.012
1.019
1.036
0.347-1.153
0.000
0.926
0. 946
0.953
0.957
0.973
0.978
1.000 13C12-PeCDD 123 IS3
1.004
1.014
Above: PeCDD / HxCDF Follows
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive * Durham, North Carolina 27713 Printed: 16:32 09/08/97
Phone: ,919) 544-5729 • Fax: (919) 544-5491 350 "
-------
Page No. 4
09/08/97
Listing of S975673B.db£
Matched GC Peaks / Ratio / Ret, Time
Compound/
HxCDF
374-376
374-376
13C12-HXCDF
334-336
384-386
HxCDD
Dmit
why
. .RT.
OK
Ratio Total
Area... Area
Peak.1.. Area.Peak.2..
Eel.RT Compound,Name,.
1.
05-1.43
0.957-1.051
DC
NL
0: 00
1.18
0.24
0. 000
DC
SN
27:42
RO
0.57
1.08
0.967
DC
SN
27: 50
RO
2.05
0.49
0. 972
DC
SN
27: 59
RO
2. 07
0.67
0. 977
DC
SN
28:15
RO
1.88
0.74
0.987
DC
SN
28:23
RO
.2.20
0.45
0.991
DC
SN
28: 37
RO
5.80
0.22
0.999 123673-HxCDF
DC
SN
28:42
RO
6 . 33
0.20
1.002
DC
SN
28:46
RO
0.42
0.20
1.005
DC
SN
28:51
RO
1.58
0.27
1,003
DC
SN
28:54
1. 05
0.76
1. 009
DC
SN
29: 07
RO
0. 36
0.70
1.017
DC
SN
29:10
RO
0.34
0.58
1.019 234673-HxCDF
DC
SN
29:22
1.08
0.54
1.026
DC
SN
29:33
RO
2.08
0.56
1.032
DC
SN
29:46
RO
0.56
0.42
1.040
DC
WH
30: 08
RO
7.56
0.36
1.052
DC
WH
30:15
RO
0.62
0.56
1.056
DC
WH
30:24
RO
7. 69
0.36
1.062
0
Peaks
0.00
0
43-0.59
0.360-1,140
DC
NL
0:00
RO
0.33
0.30
0.000
DC
SN
27:42
RO
0.79
1.36
0.967
DC
SN
27: 53
RO
0. 11
0.21
0,977
DC
SN
28: 02
RO
1.33
0.23
0. 979
28: 32
0. 53
480.53
167.45 313.08
0.997 13C12-HXCDF 478
28:38
0. 48
539.17
175.51 363.66
1.000 13C12-HXCDF 678
DC
SN
28: 50
RO
1.40
1.54
1. 007
28: 54
RO
0.31
2.60
1.39 1.72
1.009
29:03
0. 51
394.94
132,83 262,06
1.017 13C12-HXCDF 234
29:16
0.54
8.41
2.96 5.45
1.022
DC
SN
29:20
RO
0. 68
2.39
1.024
DC
SN
29:28
RO
0.17
0.83
1.029
DC
SN
29:34
RO
0.24
0.38
1.033
DC
SN
29: 38
RO
2.59
0.26
1.035
DC
SN
29:43
RO
1.88
0.48
1.033
29:51
0. 50
276.16
92.19 183.97
1.042 13C12-HxCDF 789
30:01
RO
0.79
2.63
1.37 1.74
1.048
DC
SN
30:05
0.44
3.52
1.051
DC
SN
30: 14
RO
1.11
1.69
1.056
DC
SN
30:19
0.46
1.30
1.059
DC
SN
30:27
RO
1.17
0.44
1.063
7
Peaks
1.704.44
ID.
"lags.
AN
AN
Above: HxCDF / HxCDD Follows
1.05-1.43
0.952-1.015
390-392
DC
NL
0:00
1.20
0.22
0.000
DC
SN
27:59
1.32
0.44
0.954
DC
SN
28:15 RO
4,20
0.22
0.963
Triangle Laboratories, Inc.® Analytical Services Division
801 Cap'rtola Drive* Durham, North Carolina27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 16:32 09/08/97
QC1"
oOi
-------
Page No. 5
09/08/97
Listing of S975673B.dbf
Matched GC Peaks / Ratio / Ret. Time
Compound/
M_2.... QC.Log
Omit
Why
. .RT.
OK
Ratio Total.Area. . .
Area.Peak.1.. Area.
.Peak.2.. Rel.RT Compound.Name..
DC
SN
28:21
RO
1.81 0.36
0.966
DC
SN
28: 34
RO
5.55 0.49
0.974
DC
SN
28: 38
RO
2.13 1.01
0.976
DC
SN
28:44
RO
0.64 0.92
0.980
DC
SN
28:47
RO
0.57 0.47
0. 981
DC
SN
29 : 07
RO
2.41 0.33
0.993
DC
SN
29:11
RO
.0.43 0.45
0.995
DC
SN
29:20
RO
0.58 1.07
1.000 12 3 678-HxCDD
DC
SN
29:24
RO
0.28 0.52
1. 002
DC
SN
29: 35
RO
0.59 0.31
1 . 009
DC
SN
29:41
RO
0.79 0.69
1.012 123739-HxCDD
DC
WH
29: 50
RO
1.77 0.69
1 . 017
DC
WH
29:57
RO
1.57 0.47
1.021
390-392
0
Peaks
0.00
13C12-HxCDD
1 .
05-1 .43
0.966-1.034
402-404
DC
NL
0: 00
RO
1.00 0.25
0.000
DC
WL
27: 56
RO
0.63 0.34
0.952
DC
WL
28:02
RO
1.76 0.47
0. 956
DC
WL
28:09
RO
0.41 0.27
0 . 960
DC
WL
28: 13
1.35 1.08
0.965
DC
SN
28: 33
RO
1.33 0.52
0.976
DC
SN
28:44
RO
1.04 1.31
0 . 980
DC
SN
28: 50
RO
0.70 0.33
0. 983
DC
SN
28: 53
RO
4.32 0.25
0.935
DC
SN
28: 58
RO
0.53 0.45
0.983
29: 16
1.20 363.78
200.95
167.83 0.998 13C12-HxCDD 473
29:20
1.20 412.40
224.80
187.60 1.000 13C12-HXCDD 573
29:38
1.26 417.08
232.41
184.67 1.010 13C12-HXCDD 739
DC
SN
29:47
RO
0.39 2.15
1.015
DC
SN
29: 50
1.19 1.14
1.017
DC
SN
29: 54
RO
0.38 0.54
1.019
402-404
3
Peaks
1,198.26
npuur *oxlows — —•
HpCDF
0.
.88-1.20
0.995-1.044
408-410
DC
NL
0: 00
RO
0.85 0.22
0 . 000
DC
SN
31:25
RO
2. 11 0.39
1 . 004
DC
SN
31:31
RO
1.43 0.47
1 . 007
DC
SN
31:38
RO
0.40 0.33
1.011
DC
SN
31:43
RO
0.63 1.82
1.013
DC
SN
32:08
RO
1.98 0.96
1.027
DC
SN
32: 18
RO
1.42 0.88
1. 032
DC
SN
32: 31
RO
0.42 1.18
1.039 1234789-HpCDF
408-410
0
Peaks
0.00
13C12-HpCDF
0
.37-0.51
0.936-1.128
418-420
DC
NL
0: 00
RO
1.23 0.19
0.000
31: 13
0.45 321.81
99 .20
222.61 1.000 13C12-HpCDF 673
DC
SN
31: 37
RO
2.11 0.95
1 .010
DC
SN
31:48
RO
6.33 0.30
1.016
AN
AN
AN
Triangle Laboratories, Inc.© Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 16:32 09/08/97
352 "
-------
Page No.
09/03/97
Listing of S975673B.dbf
Hatched GC Peaks / Ratio / Ret, Time
Compound/
M_Z.... QC
413-420
Omit
Why
. .RT.
OK
Ratio Total
Area...
Area.Peak.1..
Area.Peak.2,.
Rel.RT
Compound.Name. .
ID. .
DC
SN
32:04
RO
0.84
1.31
1.024
DC
SN
32:10
RO
1.36
1.11
1.028
32:30
0.42
174.54
51.43
123.11
1.038
13C12-HpCDF 789
S0R5
DC
SN
32:46
RO
2.30
1.44
1.047
2
Peaks
496.35
Flags.
Above-. HpCDF / HpCDD Follows
HpCDD 0.88-1.20 0.977-1.006
424-426
DC
NL
O
o
o
0.92
0.23
0.000
DC
SN
31: 34
RO
0.65
1.75
0.982
DC
SN
31:48
RO
1.28
1.98
0.989
DC
SN
32:17
RO
0.50
0.59
1.004
DC
WH
32: 31
RO
2.22
1.00
1.011
424-426
0
Peaks
0.00
13C12-HpCD0 0.88-1.20 0.969-1.031
436-433 DC NL 0:00 1.00 0.28 0.000
DC SN 32:01 RO 0.41 0.61 0.996
32:09 1.04 271.41 138.52 132.39 1.000 13C12-HpCOD 678 IS7
DC SN 32:27 0.93 1.76 1.009
DC SN 32:35 1.06 1.36 1.013
436-433 1 Peak 271,41
Above: HpCDD / Octa-CDD and CDF Follows
OCDF
442-444
0.76-1.02
0.8S4-1.116
442-444
DC
NL
0
00
RO
1.15
0.25
0.000
DC
SN
31
23
RO
2.35
1.02
0.907
DC
SN
31
45
0.98
1.94
0. 917
DC
SN
32
09
RO
1.44
1.36
0.929
DC
SN
32
15
RO
1.36
0.47
0.932
DC
SN
32
59
RO
0.59
1.72
0.953
DC
SN
33
21
RO
0. 07
0.11
0.963
DC
SN
33
40
RO
0. 58
1.21
0,973
DC
SN
33
45
0.98
1.76
0.975
DC
SN
34
09
RO
0.68
1.06
0.987
DC
SN
34
17
RO
2.66
1.23
0.990
DC
SN
35
00
RO
2.63
0.96
1.011
DC
SN
35
28
RO
8.11
0.34
1.025
DC
SN
35
48
RO
2.37
0.66
1.034
DC
SN
35
53
RO
3 . 17
0.43
1.037
0
Peaks
0.00
OCDD
0
76-1.02
0.884-1.116
458-460
DC
NL
0:00
RO
1.08
0.23
0.000
M
34:38
RO
0.67
4.35
2.05 3.07 1.000 OCDD
DC
SN
35:02
RO
0.52
0.76
1.012
DC
SN
35:08
RO
2. 97
0,70
1.015
453-460
1
Peak
4.35
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 16:32 09/08/97
353 '
-------
Page No.
09/03/97
Listing of S97S673B.db£
Matched GC Peaks / Ratio / Ret. Time
Compound/
QC.Log Omit Mhy
. .RT, OK Ratio Total.Area.. . Area.Peak.1.. Area.Peak.2. . Rel.RT Compound.Name,
:D., Flags.
13C12-OCDD
470-472
470-472
DC
DC
0.76-1.02
NL 0:00 RO 1.08
34:37
WK 34:53
1 Peak
0.93
0. 87
0.23
151.60
2.67
151.60
72 .99
0.996-1.006
0.000
78.61 1.000 13C12-OCDD
1.008
IS8
Column Description.
"Why" Code Description QC Log Dese,
M_Z -Nominal Ion Mass(es)
, .RT. -Retention Time (mm: ss)
Rat.1 -Ratio of M/M+2 Ions
OK -RO=Ratio Outside Limits
Rel.RT-Relative Retention Time
** End of Report *"
WL-Below Retention Time Window
WH-Above Retention Time Window
SN-Below Signal to Noise Level
-------
Tiles S975S73 §1-867 Acq:5-SEP-97 10:47:44 EI+ Voltage SIR 70S No±ae:82
303.9016 F:2 BSUB(256, 30,-3 .0 ) PKD( 9, 5, 5, 0. 05 328 . 0, 1. 00\, F, T) Exp-.EPCUS
TRIANGLE LABS Text:FB2 TLI04293OA INJ. TIME = 10:50
1003, A3.37E4
18:00 19:00 20:00 21:00
File:S97S673 §1-867 Acq:5-SEP-97 10:47:44 EI+ Voltage SIR 70S Noiae:63
305.8987 F:2 BSUB( 256,30, -3. 0 ) PKD( 9, 5, 5, 0. 05%,252.0,1,00%,F, T) Exp:EPCVS
TRIANGLE LABS Text:FB2 TLI04293OA IN J. TIME = 10:50
lOOt A3. Q5E4
9.8E3
A2.20E4
7.8E3
5.9E3
A2.3SE4
A1.10E4
5.85E3
A1.06E4
A1.38E4
3.9E3
A8.46E3
A8.91E3
2.0E3
22:00
.O.OEO
23:00 Time
9. 7E3
L7. 7E3
S.8E3
A2.96E4
A1.86E4
9.43E3
3.9E3
A8.2
A2.01E4
80E4
1.9E3
18:00 19:00 20:00 21s00
File:S975673 *1-867 Acq:S-SEP-97 10:47:44 EI+ Voltage SIR 70S Noise: 65
315.9419 F: 2 BSUB(256, 30,-3. 0 ) PKD(9, 5 , 5, 0. 05\, 260. 0 ,1.00%,F,T) Exp:EPCUS
TRIANGLE LABS Tezt:FS2 TLH42930A INT. TIME » 10;
100%
80J
60J
40q
2oJ
22:00
50
18:00 19:00 20:00 21:00 22:00
File: S975673 01-867 Acq:S-SEP-97 10:47:44 EI* Voltage SIR 70S Noise: 69
317.9389 F:2 BSUB(256, 30, -3. 0 } PKD( 9 , 5 , 5 , 0. 0S%,276.0 ,1. 00%,F,T) Exp:EPCUS
TRIANGLE LABS Text:FB2 TLIH42930A INS. TIME = 10:50
lOOt
aoJ
6ol
40J
20Z
18:00 19 sOO 20:00 21:00
File: S97S673 #1-867 Acq:5-SEP-97 10:47:44 EI+ Voltage SIR 70S
330.9792 F:2 Exp:EPCUS
TRIANGLE LABS Text:FB2 TLI04293OA INJ. TIME
100t
A3.34E6
.O.OEO
23:00 Time
.8.1E5
.6. 5E5
.4 . 9E5
¦-3.3E5
i 1. 6E5
_£.0.0E0
23:00
TImb
A4.55E6
22:00
.1.2E6
¦-9.4E5
.7.0E5
.4. 7E5
.2.3E5
io. 0E0
23': 00 Time
10:50
22;26 22
5.8E6
4.7E6
3.5E6
2.3E6
1.2E6
18:00 19:00 20:00 21:00
File:S975673 #1-867 Acq:5-SEP-97 10:47:44 EI+ Voltage SIR 70S
375.8364 F:2 Exp-.EPCUS
TRIANGLE LABS Text:FB2 TLI442930A INJTIME
100
22100
23:00
O.OEO
Time
10:50
6.2E3
20:00
5.0E3
3.7E3
18:05
18:54
21:36
20:25
17:28
2.5E3
1.2E3
17:52
18:00
19:00
20:00
21100
22:00
.O.OEO
23:00 Time
355
I
-------
File: S975673 #1-857 Acq:5-SEP-97 10:47:44 EI* Voltage SIS 70S Noiae:66
319.8965 F:2 BSUB( 256 , 30, -3 . 0 ) PKD(7, 5,3,0.05%,264.0,1.00%,F,T) Ezp:EPCUS
TRIANGLE LABS Text:FB2 TLI*42930A IN J. TIME = 10:50
A8.29E3
19:00 20:00 21:00 22:00
File: S975673 #1-867 Acq:5-SEP-97 10:47:44 EI+ Voltage SIS 70S Noise:53
321.8936 F: 2 BSDB(256, 30,-3 . 0) PKD(7, 5 , 3 , 0. 05%, 212. 0 ,1. 00%, F,T) Exp:EPCDS
TRIANGLE LABS Text:FB2 TLI#42930A INJ. TIME - 10
lOOi A7.03E3
100%
_5. 8E3
L4.6E3
A8.02E3
A5.24E3
A5.73E3
A1.18E3
A4.72E3
A2.28E3
A4 . 73E3
10.0E0
Tune
23:00
: 50
6.2E3
5.0E3
A6.71E3
A4-flE3b_2.5E3
2.07E3
A7.10E3
A1.82E31A2.95E3
A5.4
3.82E3
A4.21E3
11\0 4
0.0E0
19:00 20:00 21:00 22:00
File: S975673 #1-867 Acq:5-SEP-97 10:47:44 EI+ Voltage SIS 70S Noise:551
331.9368 F:2 BSDB(256, 30, -3 . 0) PKD( 7, 5, 3, 0 . 05%, 2204 . 0,1. 00%, F, T) Ezp:EPCUS
TRIANGLE LABS Text:FB2 TLI*42930A INJ. TIME = 10
23:00
Time
: 50
1003,
80.
601
401
20.
A3.29E6
A2.48E6
C8.7E5
7. 0E5
.5.2E5
:.3 . 5E5
:.1. 7E5
19:00 20:00 21:00 22:00
File: S975673 #1-867 Acq:5-SEP-97 10:47:44 EI+ Voltage SIS 70S Noise:72
333.9338 F:2 BSUB( 256, 30,-3 . 0 ) PKD( 7, 5 , 3 , 0 . 05%, 288. 0 ,1. 00%,F, T) Exp:EPCUS
TRIANGLE LABS Text: FB2 TLI#42930A INJ. TIME = 10
100$
80.
: 50
60.
40.
20.
S2.79E6
.0.0E0
23:00 Time
9.4E5
L 7.6E5
L 5.7E5
L3.8E5
Ll. 9E5
19:00 20:00 21:00 22:00
File: S975673 *1-867 Acq: 5-SEP-97 10:47:44 EI+ Voltage SIS 70S Noise:60
327.8847 F:2 BSUB(256, 30,-3. 0 ) PKD(7, 5, 3 , 0. 05%,240.0 ,1. 00%,F ,T) Eip:EPCUS
TRIANGLE LABS Text:FB2 TLI#42930A INJ. TIME = 10
2J.-00
tO.OEO
Time
: 50
1001
803
A4.31E6
~r
-r~
1.2E6
L9.7E5
17.3E5
1.4.8E5
2.4E5
19:00 20:00 21:00
File:S975673 *1-867 Acq:5-SEP-97 10:47:44 EI+ Voltage SIS 70S
330.9792 F:2 Exp: EPCUS
INJ. TIME =
21:29 21:47
22:00
23: 00
O.OEO
Time
TSI ANGLE LABS
100%
801
601
40.
20.
0.
Text:FB2
19:22
22:26
20:37
20:14
21: 04
18:51
19:4
22:46
5.8E6
.4. 7E6
'.3.5E6
-2.3E6
.1.2E6
19:00
20:00
1 1
21: 00
22:00
23: 00
O.OEO
Time
356 -
-------
File:S975673 #1-867 Acq:5-SEP-97 10:47:44 EI* Voltage SIS 70S Noise: 67
339.8597 F:2 BSVB(2S6, 30,-3 .0) PKD( 7, 5, 3, 0. 05%, 268. 0, 1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:FB2 TLI#429J0A INJ. TIME - 10:50
1003, A1 .?6E4
23:00 24:00 25:00 26:00
File: S975673 *1-867 Acq:5-SEP-97 10:47:44 EI* Voltage SIR 70S Noise: 69
341.8567 F:2 BSTJB(256, 30,-S.0) PKB( 7, 5, 3, 0. 05%, 276. 0, 1 .00%, F, T) Exp:EPCUS
TRIANGLE LABS Text: FB2 TLI04293OA ZKT. TIME = 10:50
100%
23:00 24:00 25:00 26:00
File:S9 75673 01-867 Acq: 5-SEP-97 10:47:44 EI* Voltage SIR 70S Noise: 62
351.9000 F:2 BSXJB(2S6, 30, -3. 0) PKD( 7, 5, 3, 0. 05%, 243. 0, 1. 00%, F, T) Exp-.EPCUS
TRIANGLE LABS Text:FB2 TLI04293OA INJ. TIME = 10:50
4.7E3
A7.62E3
3.7E3
A9.10E3
A5.46E3
A4.82E3
2.8E3
1.9E3
A3. 71E3
9.3E2
O.OEO
looa
sol
603
4 (3d
20J
oj
A2.99E6
A2.68E6
23:00 24:00 25:00 26:00
File:S975673 *1-867 Acq:5-SEP-97 10:47:44 EI* Voltage SIR 70S Noise: 78
353.8970 F:2 BSUB(256, 30,-3. 0) PKB(7, 5, 3, 0. 05%, 312. 0,1.00%, F, T) Exp.-EPCUS
TRIANGLE LABS
100%
8(jj
soJ
40Z
2ol
oJ
Text:FB2 TLI#42930A
A2.02E6
INJ. TIME =
A1.5 2E6
10:50
23:00 24:00 25:00
File:S975673 §1-867 Acq:5-SEP-97 10:47:44 EI* Voltage SIM 70S
330.9792 F:2 Exp:EPCUS
TRIANGLE LABS Text:FB2 TLI04293OA INJ. TIME
100$ 25:21
26:00
10:50
23:00 24:00 25-00
File:S975673 01-867 Acq:5-SEP-97 10:47:44 EI* Voltage SIR 70S
409.7974 F:2 ExpsEPCBS
TRIANGLE LABS Text:FB2 TLI04293OA INJ. TIME
100« 25-27
26:00
23:38
23:0
3-.2S
24:28
24:03
23:00
25:02
25:43
24:00
25: 00
10:50
26s 04
26:25
27:00
8. 7E3
7.0E3
A1.12E4
5.2E3
A5.91E3
A6.73E3
A6.88E3
A4.60E3
3.5E3
AS.08E3
1. 7E3
O.OEO
27:00
9.5E5
7.6E5
7E5
3.8E5
1.9E5
27:00
O.OEO
Time
.5. BE5
.4.7E5
.3.5E5
'.2.3E5
'.1.2E5
27:00
:o.oeo
Time
1.2E7
9.4E6
27:01
7.1E6
24 :15
25:07
24 : 43
23:15 23:32 23:48
4.7E6
2.4E6
O.OEO
27:00
26:46
26:00
27:00
1.3E4
-.1. 0E4
7.8E3
L5.2E3
L2.6E3
0. 0E0
Time
357
-------
File-.s975S73 il-SB7 Acq:5-SEP-57 10i47YU EI* Voltage SIM 70s' 'tiSTaeSSS
355. 8546 F:2 BSCB(256, 30, -3.0) PKD(7, 5,3, 0.05%, 220. 0,1. 00%,F,T) Exp:EPCUS
TRIANGLE LABS Text;FB2 TLI#42930A
1001
25:00 26:00
File:S975673 01-867 Acq:5-SEP-97 10:47:44 EI* Voltage SIR 70S Noise: 62
357.8516 F:2 BSVB(256, 30, -3.0) PKD( 7, S, 3, 0.05%, 248. 0 , 1. 00%, F, T) Exp-.EPCVS
TRIANGLE LABS Text:FB2 TLIH42930A INJ. TIME » 10:50
1005
AS.99E3
A1.08E4
INJ. TIME
10:50
A1.78E4
A1.24E4
A1.07E4
A3. 79E3
A2.47E
U. 53E3
1.39E
. 45E3
A1.96E3 A3.82E3
A1.82E3 A5.36E3
~jWVa
27: 00
A9.81E3
A9.07E3
1.6.37E3
25:00 26:00
File:S975673 §1-867 Aeq:5-SEP-97 10:47:44 EI+ Voltage SIB 70S Noise: 5 7
367.8949 F-.2 BSUBf256,30, -3.0) PKD(7, 5,3 ,0.05%, 228. 0,1.00%,F, T) Exp: EPCVS
TRIANGLE LABS Text:FB2 TLIH42930A INJ. TIME -
A645.13
-¦ft—
27:00
10:50
1003,
80.
60.
40.
20.
0.
41E6
1. 72E5
25:00 26:00
File:S975673 #1-867 Acq:5-SEP-97 10:47:44 EI* Voltage SIS 70S Noise: 64
369.8919 F:2 BSOB(256, 30,-3 .0 ) PKD(7, 5, 3, 0. 05%,256. 0,1 . 00%,F, T) Exp:EPCUS
TRIANGLE LABS Text:FB2 TLIir4293 OA INJ. TIME = 10:50
27:00
loos
80:
60:
40:
20.
A9. 79E5
11.38E5
AA
25:00 26-00
File:S975673 #1-867 Acq:5-SEP-97 10:47:44 EI+ Voltage SIS 70S
330.9792 F:2 Exp:EPCUS
TRIANGLE LABS Text: FB2 TLI»42930A INJ. TIME = 10:50
100% 25i21
27:00
2E3
3E3
5E3 |
I
7E3 I
8E3 |
OEC j
Ti^ei
1
!
2E5
2E5
1E5
1E5
0E5
0E0
Time
3E5
6E5
0E5
3E5
5 E4
0E0
Time
24:15
25:00
26:00
27:00
358
-------
File:S975673 #1-425 Acq:5-SEP-97 10:47:44 EI+ Voltage SIR 70S Noise: 63
373.B20B F: 3 BSOB( 256 , 30,-3. 0 ) PKD( 7, 5, 3, 0. 05%,252. 0, 1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:FB2 TLI#42930A IK.T. TIME =¦ 10:50
100%
80i
601
401
201
0.
A1.21E4
A5.84E3
'Prrvi Inftri*i rvf'i i"Ati4"i fi I'l'fri I ppi PnVrl'T^'i fri'f 1 Q i i 9 CWVp-HV i | p p
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
File:S975673 #1-425 Acq:5-SEP-97 10:47:44 EI+ Voltage SIR 70S Noi3e:53
375.8178 F:3 BSVB(256, 30,-3 . 0 ) PKD(7 , 5 , 3 , 0.05%,212.0 , 1.00%,F ,T) Exp:EPCUS
TRIANGLE LABS Text:FB2 TLX#4293OA INJ. TIME = 10:50
S. 7E4
5.4E4
4.0E4
2. 7E4
1.3E4
Time
1004
tfoj
601
401
201
.1. 9E5
-.1. 5E5
°1 *1 ' ' 1 ' I ' ' ' * I 'I" <* ' ' ' | '¦ " I*1 ' I 1 1 r '1 ' ' | 1 ' | '• 1 * f 1 I ' ' ^ T I ' ' 1-1 r p ' 1 1*1*1 1' I
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:
File:S975673 #1-425 Acq:5-SEP-97 10:47:44 EI+ Voltage SIR 70S Noise:48
383.8639 F:3 BSOB(256, 30, -3. 0 ) PKD(7 , 5, 3 ,0. 05%, 192. 0 ,1.00%,F,T) Exp:EPCUS
00 30:12 30:24
TRIANGLE LABS
100%
801
601
401
Text:FB2 TLH42930A
INJ. TIME =
10:50
201
A1.33E6
A9.22E5
l
to
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
File:S975673 #1-425 Acq:5-SEP-97 10:47:44 EI+ Voltage SIR 70S Noise-.ISO
385.8610 F:3 BSUB( 256, 30, -3 . 0 ) PKD( 7, 5 , 3 ,0. 05%, 600. 0 ,1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS
1003
801
601
401
Text: FB2 TLI#42930A
INJ. TIME
10:50
201
01
A2.62E6
A1.84E6
L 0.
1 ' I 1 1 ' ' 1 I ' ' ' ' ' I ' 1 ' 1 ' I ' ' ' 1
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00 30:12 30:24
File:S975673 il-425 Acq: 5-SEP-97 10:47:44 EI+ Voltage SIR 70S
392.9760 F:3 Exp:£PCUS
TRIANGLE LABS Text:FB2 TLI*42930A INJ. TIME = 10:50
100%
801
601
401
201
01
.29:26 29:39
27:56 28:08
30: 0° 30:11
27:24 27:36' 27:48 28:00 28:12' 2A.-24 ' 28:36' 28:48' 29:00' 29-ii' 29': 24 ' 29: 36' 29:48' 30:00 ' '30:12' 30:24
6E5
JE5
0E5
6E5
3E5
0E0
Time
3E6
1E6
9E5
3E5
6E5
0E0
Time
. 8E6
. 8E6
. 9E6
. 9E6
. 5E5
. 0E0
Time
File:S975673 #1-425 Acq:5-SEP-97 10:47:44 EI* Voltage SIR 70S
445.7555 F:3 Exp:EPCUS
TRIANGLE LABS Text: FB2
1003,
TLI#42930A
INJ. TIME =
10:50
29:33
28:53 29:06
29:44
28:21
27:35
29:27
28:06
28:40
27:49
27:24 27:36 27:48 28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00
30:12 30:24
359
-------
File: S9 756 73 *1-425 Acq: 5-SEP-97 10:47:44 EI + Voltage SIR 70S No±3e:61
389.8156 F:3 BSUB( 256, 30, -3 . 0 ) PKD( 7, 5, 3, 0. 05%, 244 . 0, 1. 00%,F, T) Exp-.EPCUS
TRIANGLE LABS Text:FB2 TLI#42930A IN J. TIME = 10:50
100% A1.Q5E4
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36
File:S975673 #1-425 Acq:5-SEP-97 10:47:44 EI+ Voltage SIR 70S Noise:51
391.8127 F:3 BSUB( 256, 30, -3.0 ) PKD( 7, 5 , 3 , 0. 05%, 204 . 0 , 1. 00%, F,T) Exp:EPCUS
TRIANGLE LABS Text:FB2 TLI04293OA IN J. TIME = 10:50
1001
A9. 64E3
A8.85E3
A4.22E3
A5.95E3
A1.65E3
29:48
A5.67E3
A1.02E4
A6.81E3
A6.66E3 A8.03E3
A4.49E3
A4 . 77E3
A3.09E3
A3.59E3
A5.17E3
44E3L2
A3.69E3
OEO I
r_L.i>e|
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36
File:S975673 *1-425 Acq:5-SEP-97 10:47:44 EI+ Voltage SIR 70S Noise:72
401.8558 F: 3 BSUB(256, 30, -3 . 0) PKD( 7, 5, 3, 0 . 05%, 288. 0, 1. 00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:FB2 TLI§42930A 1NJ. TIME = 10:50
29:48
1003,
80.
601
40:
20.
A2.25E6
A2.32E6
x
T
~r
8.
.6.
14.
'.3.
11.
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48
File:S975673 *1-425 Acq:5-SEP-97 10:47:44 EI+ Voltage SIR 70S Noise:71
403.8529 F:3 BSUB( 256 , 30, -3 . 0) PKD( 7, 5 , 3 , 0. 05%, 284 . 0 , 1. 00%, F,T) Exp:EPCUS
TRIANGLE LABS Text: FB2 TLI#42930A IN J. TIME = 10:50
1001 A1.88E6 A1.85E6
801
60.
30:00
40.
20L
28:00 28:12 28:24 28:36 28:48 29:00 29:12 29:24 29:36 29:48 30:00
File:S975673 §1-425 Acq:5-SEP-97 10:47:44 EI+ Voltage SIR 70S
392.9760 F: 3 Exp:EPCUS
TRIANGLE LABS Text:FB2 TLI#42930A INJ. TIME = 10:50
29^26
29:16
28:08 28:23 28:33
rr
'¦ ' r ' 1
28:48
' ¦ I 1 1 1 1 r r 1 1
29:00 29:12
7.
15.
14.
'.2.
11.
1001
80.
60.
401
20.
29:39
30:00
29:51
28:46 28:56
'28:00 ' '28:12 ' ' 2a':24 28:36 28': 4 8 ' ' 29\66 ' 29.-12 29\24 ' 29:36 ' '29:48 3o': 00
.3
.2
.1
:.9
.0
1E5
5E5
9E5
. 3E5
. 6E5
.OEO
Time
. 0E5
. 6E5
.2E5
. 8E5
. 4E5
.OEO
Time
. 8E6
. 8E6
. 9E6
. 9E6
. 5E5
.OEO
Time
3P0
-------
Files S97S673 #1-390 Acq: 5-SEP-97 10:47:44 EI* Voltage SIR 70S Hoi set 54
407.7818 F:4 BSVB( 256 , 30,-3 .0 ) PKS( 7, 5, 3, 0. 05%,216. 0,1. 00%,F, T) Exp:EPCUS
TRIANGLE LABS Text:FB2 TLI04293OA JKJ. TIME « 10:50
1009
A3.08E4
A9.29E3
A9.12E3
A6.01E3
A2.95E
A9. 32E3
A6.13E3
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
File:S97$673 #1-390 Acq:5-SEP-97 10:47:44 EI* Voltage SIS 70S Hoise: 64
409.7789 F:4 BSUB(256,30, -3 . 0) PKD(7, 5,3, 0. 05\,256.0,1.00%, F, T) Exp:EPCUS
TRIANGLE LABS Text:FB2 TLI#42930A IN J. TIME = 10:50
iocs
32:48
33:00
A1.48E4
A2.34E3
A1.43E4
A4.72E3
A4.29E
AS.26E3
1.93E3
31:12 31:24 31:36 31:48 32:00 32:12 32:24 32:36
File:S975673 #1-390 Acq:5-SEP-97 10:47:44 EI* Voltage SIB 70S Noise: 80
417.8253 F: 4 BSUB(256, 30,-3. 0 ) PKD( 7, 5, 3, 0. 05%, 320. 0, 1. 00%,F, T) Exp:EPCUS
TRIANGLE LABS Text:FB2 TLI§42930A IHJ. TIME = 10:50
100% A9 . ?2E5
sod
sol
40J
201
od
32:48
33:00
A5.14E5
32:36
31": 12 31:24 31:36 31:48 32:00 32:12 32:24
File:S975673 01-390 Acq:5-SEP-97 10:47:44 EI* Voltage SIR 70S Hoise: 67
419.8220 F:4 BSUB( 256, 30, -3. 0 ) PKD(7, 5,3, 0. 05%, 268. 0,1.00%,F, T) Exp:EPCUS
TRIANGLE LABS Text:FB2 TLI#42930A IHJ". TIME = 10:50
1009
80l
60Z
402
20l
o3
32:48
T
A1.23E6
* I I I 'I I 1 { ¦ ! ¦ 1 1 I 1111 I 1 !
31:48 32:00 32:12
31:12 31:24 31:36
File:S975673 #1-390 Acq:5-SEP-97 10:47:44 EI* Voltage SIR 70S
430.9729 F:4 Exp:EPCUS
TRIANGLE LABS Text: FB2 TLI04293OA IHJ".
100% 32:01
_31:1431:43
80J
33:00
.8.
16,
.5.
13.
L i.
¦ 0E0
Time
32:24
!' ! I I
32:36
32:48
' I
33:00
4E5
7E5
0E5
4E5
. 7E5
.0E0
Time
TIME - 10:50
32:30 32:40
32:48
31:12 31:24 31:36 31:48 32:00 32:12
File:S975673 #1-390 Acq:5-SEP-97 10:47:44 EI* Voltage SIR 70S
479.7165 F:4 Exp:EPCUS
32:24
32:36
32:48
33:00
. 0E0
Time
TRIANGLE LABS Text:FB2 TLI04293OA
1001
INJ-. TIME
10:50
32:33
32:50
31:5
31:14
32:42
2:17
31:12
31:24
31:36
31:48
32:00
32:12
32:24
32:36
32:48
33:00
361
-------
File :S975673 il-350 Ac*: 5-SEP-97 10:47:44 EX* Voltage SIR 70s Noiae:54
423.7766 F:4 BSUB ( 256 , 30,-3 .0 ) PKD(7, 5 , 3 , 0.05%, 216.0, 1. 00%, F, T) Exp-.EPCUS
TRIANGLE LABS Text:FB2 TLI04293OA INJ. TIME = 10:50
100%
31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30 32:36
File:S9 75673 #1-390 Acq:5-SEP-97 10:47:44 EI* Voltage SIB 70S Noise: 58
425.7737 T:4 BSUB(256,30, -3.0) PKD( 7, 5, J , 0. 05%, 232.0, 1.00%, F, T) Exp: EPCVS
TRIANGLE LABS Text:FB2 TLI§42930A IMJ. TIME = 10:50
1001 A9.f9E3
5.5E3
A1. 09E4
4.4E3
A9.99E3
A8.8
3.3E3
2.2E3
1.1E3
O.OEO
Time
7.6E3
A1.49E4
6.1E3
A1.36E4
4.6E3
A1.28E4
A6.68E3
3.1E3
1.5E3
31:30 31:36 31:42 31:48 31:54 32:00 32:06 32:12 32:18
File:S975673 *1-390 Acq:5-SEP-97 10:47:44 EI+ Voltage SIR 70S Noise: 70
435.8169 F:4 BSUB(256, 30, -3.0) PKD( 7, 5 , 3, 0 . 05%, 280 . 0 ,1. 00%, F, T) Exp-.EPCUS
TRIANGLE LABS Text:FB2 TLI04293OA INJ~. TIME = 10:50
100%
80.
60.
40.
20.
32:24 32:30 32:36
-r
31:30 31:36 31': 42 31:48 31:54 32:00 32:06 32:12 32:18 32:24 32:30
File:S975673 #1-390 Acq:5-SEP-97 10:47:44 El* Voltage SIB JOS Noise:72
437.8140 F:4 BSXJB( 256, 30, -3.0) PKD(7, 5,3,0.05%, 288.0,1. 00%, F, T) Exp-.EPCUS
TRIANGLE LABS Text:FB2 TLlt42930A INJ. TIME = 10:50
100*
80.
32:36
60.
40.
20.
~r
32:18
31:30 31:36 31:42 31:48 3154 32:00 32:06 32:12
File:S975673 #1-390 Acq:5-SEP-97 10:47:44 EI* Voltage SIR 70S
430.9729 F:4 Exp:EPCVS
TRIANGLE LABS Text:FB2 TLH42930A IN J.
T™
32:24 32:30 32:36
TIME
10:50
1003)
80.
60.
40.
20.
0.
31:43
32:01
32:30
'31:30 '31:36 ' '31:42 ' 'ji-48 'ji:54 ' '.32:00 ' '32': 06 32:12 ' 32.18 ' 32:24 ' 32:30 ' 32:36
.5.1E5
.4.1E5
.3. IE5
.2.1E5
.1.0ES
.O.OEO
Time
.4.7E5
.3. 8E5
.2.8E5
.1.9E5
.9.4E4
.O.OEO
Time
.3.9E6
.3. 1E6
.2.3E6
.1. 5E6
'.7.7E5
.0.0E0
Time
PfP
I' »•
-------
Filet S97S673 #1-390 Acq; 5-SEP-97 10:47:44 EI* Vol tage SIM 70S Noise: 73
441.7428 T:4 BSUBf 256, 30, -3.0) PKDf 7, 5,3,0. 05%, 292.0, 1. Q0\, F, T) Exp: EPCUS
TRIANGLE LABS Text: FB2 TLI*4293 0A IN J. TIME = 10:50
1001
A1.27E4
A9.55E3
A8.43E3
A1.04E4
A7.33E3
u.
A1. 73E4
A2.79E3
.1.34E4
| A6.54E3
A1.4SE4
32:00 33:00 34:00
File: S975S73 »1-390 Acq: 5-SEP-97 10:47:44 EI+ Voltage SIX 70S Noise: S6
443.7399 F:4 BSTTB(256, 30, -3.0) PKD(7, 5,3,0. 05%,264 .0,1. 00%,F, T) Exp: EPCUS
35: 00
.2.3E4
.2.1E4
.1. 8E4
.1. SE4
,1. 4E4
.1. 1E4
.9. 2E3
.6.9E3
.4. SE3
.2.3E3
O.OEO
Time
TRIANGLE LABS
ioo:
Text :FB2 TLI*42930A
inj. Tim:
10:50
1.5E4
1.3E4
1.2E4
A1.89E4
1.0E4
A1.59E4
A1.3BE4
3.8E3
7.4E3
5. 9E3
A1.20E4
A1.13E4
AS.48E3
A7. 77E3
A8.86E3
A1.S0E4
4. 4E3
A9.84E3
2.9E3
A1.52E
1.5E3
m
O.OEO
32:00 33:00 34:00
File:S975673 #1-390 Acq:5-SEP-97 10:47:44 EI+ Voltage SIR 70S
430.9729 F:4 Exp:EPCUS
TRIANGLE LABS Text:FB2 TLI04293OA INJ. TIME
33:09 34:14
35:00
10:50
35; 31
4.0E6
32; 01
35:06
3.6E6
31:43
3.2E6
2.8E6
2.4ES
2.0E6
1.6E6
1.2E6
8.0E5
4.0E5
O.OEO
31:18
liUI
32:16
32137
33:44
32:00 33:00 34:00
File: S975673 #1-390 Acq:$-SEP-97 10:47:44 EI+ Voltage SIR 70S
513.6775 F:4 Exp:EPCUS
TRIANGLE LASS Text:FB2 TLI04293OA INJ. TIME - 10:50
lOOi
90.
802
70.
60.
50.
40.
301
20.
10.
0.
35: 00
31:53
32:00
33:00
6.6E3
5.9E3
5.3E3
35:00
4.SE3
3.9E3
34:04
3.3E3
35:31
2.6E3
33:33
34:45
2.0E3
33:24
1.3E3
.6.6E2
E.O.OEO
34:00
35:00
Time
363
-------
File":S$75"S73 #1-390 ASq:5-SEP-97 10:47:44 EI+ Voltage SIS 70s Noiae: $7
457. 7377 F.-4 BSUB (25 6,30,-3.0) PKX>(7, 5, 3, 0. 05%,268. 0, 1. 00%,F, T) Exp-.EPCUS
TRIANGLE LABS Text:FB2 TLI*42930A INT. TIME » 10:50
1004
1.2E4
9.5E3
7.1E3
4.8E3
A8. 71E3
2.4E3
A4.74E3
. 58E3
O.OEO
Time
34:30 34:36 34:42 34:48 34:54 35:00
File:S975673 #1-390 Acq:5-SEF-97 10:47:44 EI* Voltage SIS 70S Noise:61
459.7348 F:4 BSUB(256,30, -3.0} PKD(7, 5, 3, 0. 05%, 244. 0,1. 00%,F, T) Exp-.EPCUS
TRIANGLE LABS Text:FB2 TLI04293OA INT. TIME - 10:50
1004 A3.$0E4
35:06
1.1E4
9.0E3
6.7E3
4.5E3
A8.58E3
A6.95E3
A4.81E3
2.2E3
A3.32E3
O.OEO
35:00
34:30 34:36 34:42 34:48 34:54
File:S975673 01-390 Acq:5-SEP-97 10:47:44 EI+ Voltage SIX 70S Noise: S3
469.7779 F:4 BSVB( 256, 30, -3.0 ) PKD(7, 5 ,3 , 0.05%,252.0, 1. 00\,FrT) Exp-.EPCUS
TRIANGLE LABS Text:FB2 TLI442930A INT. TIME = 20:50
1004
80.
60.
40.
20'
35:06
I ) )
34:30
34:36 34:42 34:48 34:54 35:00
File :S975673 01-390 Acq: 5-SEP-97 10:47:44 EI+ Voltage SIS 70S Noise: 62
471.7750 F:4 BSOB(256, 30,-3 . 0 ) PKD(7, 5, 3 , 0.05%, 248. 0 , 1. 00%, F, T) ExptEPCUS
TRIANGLE LABS Text:FB2 TLI04293OA INT. TIME = 10:50
1004 A7.?6E5
35:06
.2.3ES
.1.9E5
.1. 4E5
.9.3E4
.4.7E4
.0.0E0
Time
2.4E5
1.9E5
1.4E5
9.6E4
4.8E4
O.OEO
'— ' ' '
35:00 35:06
34:54
34:30 34:36 34:42 34:48
File:S975673 #1-390 Acq:5-SEP-97 10:47:44 EI+ Voltage SIR 70S
430.9729 F:4 Exp.-EPCUS
TRIANGLE LABS Text:FB2 TLI442930A INT.
100% 34:43 34:47
sol
60J
40J
20j
TIME
10:50
35:03 35:06
34:30
3436
34:42
34': 43
34:54
35i 00
35:06
J. 9E6
.3. IBS
.2.3E6
.1. 5E6
.7.7E5
.0.0E0
Time
3G4
-------
Channel !
338.9792
Peak top
288 pp«
Height 3.25 volts Span
Systea file naie
EFCUSS
Data file use
fl;S985971
Resolution
18888
Group nurter
2
Ionization lode
EI*
Switching
VOLTAGE
Ref. tasses
292.3825,
J 331
416.9768
fl 293
S 368
B 384
K 332
T 378
C 386
L 334
U 376
D 316
A 348
V 418
E 318
N 342
F 328
0 352
6 322
F 354
H 328
9 356
I 331
R 358
Ref. tass
416.9768
Peak top
Height .96 volts Spa
see ft*
-------
File;S975673 #1-867 Aeq:5-SEP-97 10:47:44 EI+ Voltage SIR 70S
319.8965 F:2 Exp:EPCUS
Sample Text:FB2 TLI#42930A INJ. TIME = 10:50 File Text:FB2 TLI#4293»
100% _7.9E3
17 :3
20:48
18:22 18:57
17:00 ' ' ' 18:00
6.4E3
4.8E3
21:19
23 :17
22:10 22:53
3 . 2E3
19:44
1. 6E3
i0.0E0
~1 1 J 1 f T
19 :00
20:00 r ' ' 21! 00 ' ' ' 22 : 00 ' " ' 23 :00 24100 Time
File:S975673 #1-867 Acq:5-SEP-97 10:47:44 EI+ Voltage SIR 70S
321.8936 F:2 Exp:EPCUS
Sample Text:FB2 TLI#42930A INJ. TIME = 10:50 File Text:FB2 TLI#4293»
1003s, 21; 18 / KA 6 . 7E3 O
5 . 3E3
22 :43
4 . 0E3
22 :12
17 :44
18:25 19;07
2 . 7E3
20:44
16:42
23 :55
23 :3
1.3E3
» 1 1 1 r—| 1 s 1 j 1 1 1 1 1 1 1 1— 1 r
17:00 18:00 19:00
"| i i i r
20:00
, , , —r-.lt> . 0E0
21100 22:00 23:00 24:00 Time
File:S975673 #1-867 Acq:5-SEP-97 10:47:44 EI+ Voltage SIR 7 0S
331.9368 F:2 Exp:EPCUS
Sample Text:FB2 TLI#42930A INJ. TIME
100% 21; 19
80
60
40
20 j
0 J
U
S—r
10:50 File Text:FB2 TLI#4293»
.8 . 7E5
.7 . 0E5
:,5 . 2E5
i.3 . 5E5
Ll.7E5
Lo.oeo
¦r !*• i—r~i ¦ I —i—r 1 i * | *i—i 'i' i 1 i—|—i ""i ¦ i"" i" i—]—i • i ¦ i—i—i—•[—"i i —, ¦ r -i ¦ •>—r—i—i-t'-i—t—t -i—i*1 r'f
17:00 18:00 19:00 20:00 21:00 22:00 23:00 24:00 Time
' CO
-------
File:S975673 #1-390 Acq:5-SEP-97 10:47:44 EI+ Voltage SIR 70S
457.7377 F:4 Exp:EPCUS
Sample Text:FB2 TLI#42930A INJ. TIME =
100% 34
10:50 File Text:FB2 TLI#4293»
1.2E4
31:45
1.9. 8E3
34:20
34:03
31:15
l7.3E3
32 :29
33 :46—
35 :08
35:44
"4 . 9E3
-2.4E3
35:00
32:00 33:00 34:00
File:S975673 #1-390 Acq:5-SEP-97 10:47:44 EI+ Voltage SIR 7 0S
459.7348 F:4 Exp:EPCUS
Sample Text:FB2 TLI#42930A INJ. TIME
0.0E0
Time
10:50 File Text:FB2 TLI#4293»
1.5E4
100%
1 . 2E4
8 . 9E3
34 :02
35:21
5.9E3
33 :39
32:07
5:47
35:03
l3.0E3
8 31:5
32:00
33 :00
-i 1 1 1 1 1 1 r~
34 :00
File:S975673 #1-390 Acq:5-SEP-97 10:47:44 EI+ Voltage SIR 70S
469.7779 F:4 Exp:EPCUS
Sample Text:FB2 TLI#42930A INJ. TIME =
100% 34
80
60
40j
20J
35:00
.0 . 0E0
Time
0.
32 :00
-i r
33 :00
~| 1—T-
L
10:50 File Text:FB2 TLI#4293»
37 2.3E5
Ll.9E5
il.4E5
9.4E4
4 , 7E4
34 :00
35 : 00
.0 . 0E0
Time
• CO
-------
File:S975673 #1-390 Acq:5-SEP-97 10:47:44 EI+"Voltage SIR 70S
457.7377 F:4 Exp:EPCUS
Sample Text:FB2 TLI#42 930A INJ. TIME
100% ^
80.
60 j
40
20j
0
-A2.05E4 i
-A
/
VnAv..A/--KJVV\aA
34:00 35:00
File:S975673 #1-390 Acq:5-SEP-97 10:47:44 EI+ Voltage SIR 70S
459.7348 F:4 Exp:EPCUS
Sample Text:FB2 TLI#42930A _INJ. TIME =
100%. (fA3 . 97E4 )
80.:
60j
40
20j
Ol
10:50 File Text:FB2 TLI#4293»
1.2E4
L9.8E3
ll.3E3
l4.9E3
2 . 4E3
34:00 35:00
File:S975673 #1-390 Acq:5-SEP-97 10:47:44 EI+ Voltage SIR 70S
469.7779 F:4 Exp:EPCUS
l0.0E0
Time
10:50 File Text:FB2 TLI#4293»
1 .2E4
l9 . 2E3
6.9E3
L4.6E3
.2 . 3E3
.0 . 0E0
Time
AlJ\
Sample Text:FB2 TLI#42 930A
100%
80J
60 J
40
20j
0_:
INJ. TIME =
34:31
—, r-
34 :00
10:50 File Text:FB2 TLI#4293»
.2 . 3E5
l1.9E5
1.1 . 4E5
9 . 4E4
1.4.7E4
-f=-
35 : 00
.0 . 0E0
Time
• CO
T)
en
-------
CALIBRATION
DATA
Triangle Laboratories, Inc.
801 Capitola Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Pax #919-544-5491
3f>9 •
-------
Data: 09/06/97 TRIANGLE LABORATORIES, INC.
I Continuing Calibration Cor X973009
Analysis Data : 09/06/97 Method : C2HF
Operator : ML Instrument..: X
Ilnit Calibration.: XF24087 Std.Conc : 5.Q0
ICal Date 04/08/97
Analysis Time : 18:02 GC Column...: DB-22S
¦Analyte Summary ICal Delta
Name RF Ratio RT RT Ral. RT RF RF %D
162 Lo/High
12378-TCDF 0.973 0.75 18:12 22:49 1.0007 0.967 0.006 0.6%
" 25:07
TOTAL TCDF 0.973 0.75 0.967 0.006 0.6%
J2378-TCDD 1.087 0.84 19:01 21:30 1.0008 1.09S -0.008 -0.8*
24:22
|TOTAL TCDD 1.087 0.84 1.095 -0.008 -0.8%
Other Standard Suamary ICal Delta
¦ Name RF Ratio RT RT Rel. RT RF RF %D
¦ 162 Lo/High
37C1-TCDD 0.953 19:29 21:30 1.0008 1.018 -0.065 -6.4%
| 23:29
Internal Standard Susniaxy ICal Delta
¦ Name RF Ratio RT ET Rel. RT RF RF %D
162 Lo/High
13C12-2378-TCDF 1.376 0.76 21:48 22:48 1.0000 1.392 -0.Q1S -1.2%
23:48
I13C12-2378-TCDD 1.008 0.79 19:29 21:29 1.0000 1.105 -0.097 -8.8%
23:29
I
Recovery Standard Summary ICal Delta
Name RF Ratio RT RT Rel. RT RF RF %D
162 Lo/High
13C12-1234-TCDD 1.000 0.80 21:46 1.0132 1.000 0.000 0.0%
I
I
I
I
I
I
I
Page 1
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 18:43 09/06/97
370 -
-------
Dace: 09/05/97
Analysis Date
Operator
Init Calibration.
ICal Date
TRIANGLE LABORATORIES, INC.
Continuing Calibration for S975664
09/05/97 Method : M237
HLM Instrument. . : S
SFSS117 Std.Conc : SO. 00
0S/10/97
Analyte Summary
Name RF
Total MCDF 0.000
Total MCDD 0.000
Total DCDF 0.000
Total DCDD 0.000
Total TriCDF 0.000
Total TriCDD 0.000
2378-TCDF 1.352
TOTAL TCDF 1.352
2373-TCDD 1.235
TOTAL TCDD 1.235
12378-feCDF 1.195
23478-PeCDF 1.235
TOTAL PeCDF 1.215
12378-PeCDD 1.253
TOTAL PeCDD 1.253
123478-BxCDF 1.015
123 678-BxCDF 1,369
234678-HxCDF 0.942
123789-HxCDP 0.905
TOTAL HxCDF 1.057
123478-HxCDD 0.789
123678-HxCXJD 0.959
Ratio
1&2
0.86
0.86
0.83
0.83
1.59
1.53
1.56
1.50
1.50
1.31
1.27
1.32
1.32
1.30
1.23
1.20
RT RT Rel. RT
Lo/Higfa
0:44
14:44
1:32
15:32
7:44
15:44
8:32
16:32
11:44
18:44
13:32
19:32
17:09 20:46 1.0016
22:47
18:33 21:33 1.0008
22:47
22:43 24:58 1.0007
26:51
25:42 1.0301
24:03 26:04 1.0000
26:43
27:24 28:32 0.9965
30:06
28:38 1.0000
ICal Delta
IF RF
%D
29:09 1.0180
29:51 1.0425
27:55 29:16 0.9977
29:47
29:21 1.0006
2.087 -2.087 100.0%
1.625 -1.625 100.0%
0.687 -0.687 100.0%
1.326 -1.326 100.0%
1.082 -1.082 100.0%
0.933 -0.933 100.0%
1.251 0.101 8.1%
1.251 0.101 8.1%
1.191 0.044 3.7%
1.191 0.044 3.7%
1.111 0.084 7.5%
1.115 0.120 10.8%
1.113 0.102 9.2%
1.256 -0.003 -0.2%
1.256 -0.003 -0.2%
1.215 -0.200 -16.5%
1.574 -0.205 -13.0%
1.247 -0.305 -24.5%
1.105 -0.200 -18.1%
1.285 -0.228 -17.7%
0.953 -0.164 -17.2%
1.133 -0.174 -15.4%
Page
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5481
Printed: 05:44 09/05/97
371 '
-------
Dace: 09/05/97
TRIANGLE LABORATORIES, INC.
Continuing Calibration for S975664
123789-HxCDD
0.888
1.21
29:39
1.0108
1.091
-0.203
TOTAL HxCDD
0.879
1.21
1.059
-0.180
1234678-HpCDF
1.313
1.04
31:09
31:19
1.0005
1.543
-0.230
32:41
1234789-HpCDF
0.995
1.09
32:30
1.0383
1.184
-0.189
TOTAL HpCDF
1.154
1.06
1.363
-0.209
1234678-HpCDD
0.984
1.02
31:25
32:09
1.0000
1.068
-0.084
32:20
TOTAL HpCDD
0.984
1.02
1.068
-0.084
OCDF
1.723
0.91
30:36
34:44
1.0039
1.493
0.230
38:36
OCDD
1.043
0.87
30:36
34:37
1.0005
1.105
-0.062
38:36
Other Standard Stannary
ICal
Delta
Name
RF
Ratio
RT
ST
Rel. RT
RF
RF
1&2
Lo/High
37C1-TCDD
0.926
19:32
21:33
1.0008
0.843
0.083
23:32
13C12-PeCDF 234
0.992
1.65
20:57
25:42
1.0301
0.970
0.022
28:57
13C12-HxCDF 478
0.893
0.47
28:32
0.9965
0.959
-0.066
13C12-HXCDF 234
0.775
0.47
29:08
1.0175
0.926
-0.151
13C12-HXCDF 789
0.739
0.50
29:51
1.0425
0.805
-0.066
13C12-HxCDD 478
0.927
1.27
29:16
0.9977
0.973
-0.046
13C12-HpCDF 789
0.743
0.47
29:18
32:30
1.0383
0.771
-0.028
35:18
Internal Standard
Sv&nnary
ICal
Delta
Name
RF
Ratio
RT
RT
Rel. RT
RF
RF
1&2
Lo/High
13C12-2378-TCDF
1.541
0.82
19:44
20:44
1.0000
1.318
0.223
21:44
13C12-2378-TCDD
1.110
0.83
19:32
21:32
1.0000
1.066
0.044
23:32
13C12-PeCDF 123
1.082
1.70
20:57
24:57
1.0000
1.133
-0.051
28:57
13C12-PeCDD 123
0.648
1.51
22:04
26:04
1.0000
0.635
0.013
30:04
13C12-HxCDF 678
1.321
0.50
24:38
28:38
1.0000
1.204
0.117
32:38
13C12-HxCDD 678
1.045
1.17
28:20
29:20
1.0000
0.995
0.050
30:20
Page
2
-18.6%
-17.0%
-14.9%
-16.0%
-15.3%
-7.9%
-7.9%
15.4%
-5.6%
%D
9.9%
2.3%
-6.9%
-16.3%
-8.2%
-4.7%
-3.6%
%D
16.9%
4.1%
-4.5%
2.0%
9.7%
5.0%
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive ~ Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 05:44 09/05/97
372
-------
Dace: 09/05/97
13C12-HpCDF 678 0.908 0.43
13C12-HpCDD 678 0.729 0.98
13C12-OODD
0.408 0.98
Recovery Standard Suainary
Name RF Ratio
1&2
13C12-1234-TCDD 1.000 0.83
13C12-HXCDD 789 1.000 1.21
TRIAHGLE LABORATORIES, IMC.
Continuing Calibration for S975664
29:18 31:18 1.0000 0.887 0.021 2.4%
3S:18
31:09 32:09 1.0000 0.81S -0.086 -10.6%
33:09
34:28 34:36 1.0000 0.S19 -0.111 -21.4%
34:48
ST
Lo/High
ICal Delta
RT Ral. RT RF RF
%D
21:20 0.9907 1.000 0.000 0.0%
29:38 1.0102 1.000 0.000 0.0%
QC Front lad Check: 1.5470
Page 3
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 0&M.Q9/05/97
-------
TKlAAKitifi. bABUKAIVKiia, 1«U. Date: U4/iU/y /
Initial Calibration Summary for WF54107
Analysis Dace....: 04/10/97 Method : M237
Instrument : W
Analytes
RF
SD
%RSD
RT
RT/LO
RT/HI
Ratiol
Ratio2
N
Total MCDF
2.132
0.000
0%
8:34
0:21
14:21
3.117
1
Total MCDD
1.950
0.000
0%
9:02
1:10
15:10
2.720
1
Total DCDF
0.645
0.000
0%
11:01
7:21
15:21
5.555
1
Total DCDD
1.779
0.000
0%
11:32
8:10
16:10
1.426
1
Total TriCDF
1.284-
0.000
0%
14:28
11:21
18:21
0.937
1
Total TriCDD
1.194
0 .000
0%
14:31
13:10
19:10
1.069
1
2378-TCDF
1.324
0 .134
10%
20:22
16:21
24:21
0.732
5
TOTAL TCDF
1.324
0.134
10%
0.732
5
2378-TCDD
1.283
0.132
10%
21:12
17:10
25:10
0.736
5
TOTAL TCDD
1.283
0.132
10%
0 .736
5
12378-PeCDF
1.142
0.066
6%
24:40
20:40
28:40
1.466
5
23478-PeCDF
1.166
0.053
5%
25:26
1.475
5
TOTAL PeCDF
1.154
0.057
5%
1.471
5
12378-PeCDD
1.286
0.092
7%
25:48
21:47
29:47
1.553
5
TOTAL PeCDD
1.286
0.092
7%
1.553
5
123478-HxCDF
1.180
0.065
6%
28:20
24:25
32:25
1.305
5
123 678-HxCDF
1.555
0 .082
5%
28:26
1.289
5
234678-HxCDF
1.167
0.075
6%
28:56
1.257
5
123789-HxCDF
1.054
0.050
5%
29:39
1.253
5
TOTAL HxCDF
1.23 9
0.067
5%
1.277
5
123478-HxCDD
0.897
0.059
7%
29:04
25:08
33 :08
1.203
5
123 678-HxCDD
1.136
0 .048
4%
29:09
1.255
5
123789-HxCDD
1.040
0.053
5%
29:26
1.255
5
TOTAL HxCDD
1.024
0.048
5%
1.23 9
5
1234678-HpCDF
1.581
0.083
5%
31:08
27:07
35:07
1.034
5
1234789-HpCDF
1.118
0.018
2%
32:19
1.030
5
TOTAL HpCDF
1.350
0.044
3%
1.032
5
1234678-HpCDD
1.088
0.048
4%
31:58
27:58
35:58
1.024
5
TOTAL HpCDD
1.088
0.048
4%
1.024
5
OCDF
1.487
0.036
2%
34:31
30:23
38:23
0.895
5
OCDD
1.099
0 .053
5%
34:24
30:23
38:23
0.857
5
Other Standards
RF
SD
%RSD
RT
RT/LO
RT/HI
Ratiol
Ratio2
N
37C1-TCDD
0.954
0.012
.1%
21:11
19:10
23:10
5
13C12-PeCDF 234
0.983
0.011
1%
25:25
22:40
26:40
' 1.486
5
13C12-HxCDF 478
0.917
0 .037
4%
28:19
0.508
5
13C12-HxCDF 234
0.862
0 .027
3%
28:56
0.510
5
13C12-HxCDF 789
0.757
0.015
2%
29:38
0.507
5
13C12-HxCDD 478
0.881
0.049
6%
29:04
1.227
5
13C12-HpCDF 789
0.748
0.015
2%
32:18
29:07
35:07
0.434
5
Internal Standards
RF
SD
%RSD
RT
RT/LO
RT/HI
Ratiol
Ratio2
N
13C12-2378-TCDF
1.451
0.050
3%
20:21
19:21
21:21
0.743
5
13C12-2378-TCDD
1.096
0.040
4%
21:10
19:10
23:10
0.790
5
13C12-PeCDF 123
1.125
0.065
6%
24:40
20:40
28:40
1.462
5
Page
1
Triangle Laboratories, Inc.® Analytical Services Division
801 Caprtola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 15:56 04/10/97
374
-------
TRIANGLE LABORATORIES, INC. Date: 06/10/97
Initial Calibration Summary £or SF56117
Analysis Date.... : 06/10/97 Method : M237
Instrument : S
Analytes
RF
SD
%RSD
RT
RT/LO
ST/HI
Ratlol
Ratio2
N
Total MCDF
2.087
0.000
0%
8:15
0:01
13:43
2.931
1
Total MCDD
1.625
0.000
0%
8:42
0:34
14:34
2.827
1
Total DCDP
0. 687
0.000
0%
10:38
6:43
14:43
5.965
1
Total DCDD
1.326
0 .000
0%
11:09
7:34
15:34
1.609
1
Total TriCDF
1.082
0.000
0%
13:59
10:43
17:43
1.025
1
Total TriCDD
0.933
0.000
0%
14:03
12:34
18:34
1.064
1
2378-TCDF
1.251
0.116
9%
19:43
15:43
23:43
0.799
5
TOTAL TCDF
1.251
0.116
9%
0.799
5
2378-TCDD
1.191
0.231
19%
20:36
16:34
24 : 34
0.772
5
TOTAL TCDD
1.191
0.231
19%
0.772
5
12378-PeCDF
1.111
0.082
7%
24:12
20:11
28:11
1.552
5
23478-PeCDF
1.115
0.061
5%
24:59
1.470
5
TOTAL PeCDF
1.113
0.069
6%
1.509
5
12378-PeCDD
1.256
0.113
9%
25:22
21:21
29:21
1.526
5
TOTAL PeCDD
1.256
0.113
9%
1.526
5
123478-HxCDF
1.215
0.064
5%
27:55
24:01
32:01
1.247
5
123678-HxCDF
1.574
0.099
6%
28:01
1.260
5
234678-HxCDF
1.247
0.069
6%
28:32
1.243
5
123789-HxCDF
1.105
0.060
5t
29:15
1.246
5
TOTAL HxCDF
1.285
0.062
5%
1.249
5
123478-HxCDD
0.953
0.067
7%
28:41
24:45
32:45
1.265
5
123678-HxCDD
1.133
0.070
6%
28:46
1.251
5
123789-HxCDD
1.091
0.067
68
29:03
1.233
5
TOTAL HxCDD
1.059
0.067
6%
1.249
5
1234678-HpCDF
1.543
0.103
7%
30:45
26:45
34:45
1.034
5
1234789-HpCDF
1.184
0.100
8%
31:57
1.080
5
TOTAL HpCDF
1.363
0.095
7%
1.053
5
1234678-HpCDD
1.068
0.089
8%
31:37
27:36
35:36
0.993
5
TOTAL HpCDD
1.068
0.089
8%
0.993
5
OCDF
1.493
0.131
9%
34:09
30:02
38:02
0.876
5
OCDD
1.105
0.066
6%
34:03
30:02
38:02
0.902
5
Other Standards
RF
SD
%RSD
RT
RT/LO
RT/HI
Ratiol
Ratio2
N
37C1-TCDD
0.843
0.038
5%
20:36
18:34
22:34
5
13C12-PeCDF 234
0.970
0.030
3%
24:58
22:11
26:11
1.470
5
13C12-HxCDF 478
0.959
0.042
4%
27:55
0.518
5
13C12-HxCDF 234
0.926
0.021
2%
28:32
0.517
5
13C12-HxCDF 789
0.805
0.044
5%
29:15
0.519
5
13C12-HxCDD 478
0.973
0.027
3%
28:40
1.241
5
13CI2-HpCDF 789
0.771
0.049
6%
31:57
28:45
34:45
0.424
5
Internal Standards
RF
SD
%RSD
RT
RT/LO
RT/HI
Ratiol
Ratio2
N
13C12-2378-TCDF
1.318
0.065
5%
19:43
18:43
20:43
0.734
5
13C12-2378-TCDD
1.066
0.020
2%
20:34
18:34
22:34
0.802
5
13C12-PeCDF 123
1.133
0.051
5%
24:11
20:11
28:11
1.447
5
Page
1
Triangle Laboratories, inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Printed: 09:49 06/10/97
375 -
-------
TRIANGLE LABORATORIES, INC.
Date: 06/10/97
Init:
Lai Cal
ibration
Summary for :
SF56117
13C12-PeCDD 123
0. 635
0.082
13%
25:21
21:21
29:21
1.461
Z
13C12-HxCDF 678
1.204
0.073
6%
28:01
24:01
32:01
0.522
5
13C12'HxCDD 678
0.995
0.017
2%
28:45
27:45
29:45
1.240
5
13C12-HpCDF 678
0.887
0 .046
5%
30:45
28:45
34:45
0.429
5
13C12-HpCDD 678
0.815
0.077
9%
31: 36
30:36
32: 36
1.019
5
13C12-OCDD
0.519
0.080
15%
34:02
32:02
36:02
0
5
Recovery Standards
RF
SD
%RSD
RT
RT/LO
RT/HI
Ratiol Ratio2
N
13C12-1234-TCDD
1.000
0.000
0%
20:21
0.811
5
13C12-HxCDD 789
1.000
0.000
0%
29:02
1.231
5
•** End of Report ***
Page 2
Triangle Laboratories, Inc.® Analytical Services Division
801 Capitola Drive • Durham, North Carolina 27713 Printed: 09:49 06/10/97
Phone: (919) 544-5729 • Fax: (919) 544-5491
3 < O
-------
Appendix B
PAH Laboratory Analysis
-------
CASE NARRATIVE
Analysis of Samples for the Presence of
Semivolatile Analytes by
High-Resolution Gas Chromatography / Low-Resolution Mass Spectrometry
METHOD 8270A Rev. 1 (7/92)
Date:
Client ID :
TLI Project Number:
September 12, 1997
Eastern Research Group
42930B
This report should only be reproduced in full. Any partial reproduction of this report requires permission from
Triangle Laboratories, Inc.
Triangle Laboratories, Inc.
801 Capitola Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax # 919-544-5491 ^
X
-------
TRIANGLE LABORATORIES, INC.
CASE NARRATIVE
September 12,1997
42930B
Objective: Analysis of eight MM5 train samples for polycyclic aromatic hydrocarbon (PAH)
semivolatile compounds, using Method 8270.
Method:
Eight MM5 train samples were received by Triangle Laboratories, Inc. on ice at 15°C and in good
condition on August 19, 1997. The samples were stored in a cooler at 4°C prior to extraction.
Prior to extraction, the XAD, filter, and rinses were spiked with 100 ug of the surrogate standard
pyrene-djo- These portions of the MM5 trains were Soxhlet extracted with methylene chloride for
16 hours. The impinger rinses were spiked with 100 ug of the surrogate standard anthracene-dio
before being extracted with methylene chloride using a separatory funnel. The extracts were split
with 50 percent of each extract being used for the dioxin analysis. The other halves of the extracts
were combined and brought to a final volume of 1.0 mL for the semivolatile analysis. The analysis
is based on the guidelines of Method 8270A Rev. 1 (7/92). The results reported relate only to the
items tested.
The internal standards, naphthalene-dg, acenaphthene-dio, phenanthrene-dio, chrysene-dI2, and
perylene-di2, were added to the extracts such that the final internal standard concentration was 40
ug/mL immediately prior to analysis by GC/MS.
The GC/MS analysis conditions are listed below:
GC Conditions;
Column:
Program:
Carrier Gas:
J&W DB5-625, 30m x .32mm x lum
35C, ramp at 12C/min to 285C, hold for 2 min,
ramp at 8.5C/min to 315 C, hold for 6.5 min.
Helium
MS Conditions:
Instrument:
Scan:
Interface:
HP MSD, Chemsystem and Target data systems
35-550 amu at 1.67 scan/sec
Capillary, Injector: 250C, Detector: 275C
Report:
Enclosed with the case narrative are the sample identification index, project summary sheets,
client and TLI chain of custody sheets, wet laboratory extraction information sheets, GC/MS
tracking forms, and analytical run logs. The sample identification index correlates the client
sample name, TLI sample number and the analytical file name for the each sample. The project
summary sheets list the amounts of analytes detected in gray and list the estimated detection limits
in parentheses for analytes which were not detected.
The data are reported as quantitation reports, chromatograms, interim reports, and spectra of
detected target analytes. The quantitation report header lists the TLI project number, analysis
method, instrument sample file name, and client sample name. The client project number, TLI
sample number, calibration file, dilution factor, and date received, extracted, and analyzed are also
listed in the quantitation report header. The response factors used for all calculations are from the
-------
TRIANGLE LABORATORIES, INC.
CASE NARRATIVE
September 12,1997
42930B
continuing calibration listed in the header. All initial and continuing calibration data are located in
the back of the data package. The amount reported for each target analyte detected in the
samples is reported in total ug. The retention time (RT) will be listed for all internal standards
and analytes which are detected. If a target analyte is not detected, it will be flagged with a "U"
and a detection limit will be listed. Estimated detection limits are calculated using an area of
10,000 for all analytes which were not found in the samples. The estimated detection limits
reported are the average detection limits achievable over time on an instrument type. The actual
detection limit for a given compound on a given day may vary from the estimate reported. The
quantitation limit for all analytes is half of the low point of the initial calibration adjusted for
dilution when appropriate. Below this point the calibration cannot be considered to be linear.
Any amounts reported at a level below the quantitation limit will be flagged with a "J" and should
be considered estimated. If a target analyte is found at a level exceeding the upper calibration
limit, it will be flagged with an "E" and should also be considered estimated. Any analytes flagged
with a "B" on the sample topsheets were detected in the associated laboratory blank. All target
analytes are quantitated against the internal standard preceding them on the target analyte list.
Surrogate standards are quantitated against the internal standard with the matching internal
standard reference number. For example, phenol-d5 has 1 in the IS Ref column and would be
quantitated against the internal standard which has IS1 listed in the flag column. If an internal
standard area is above or below the quality control limits as defined by the continuing calibration,
it will be flagged with "High" or "Low" in the flag column.
Immediately following the quantitation report are two pages which comprise the total ion chro-
matograms. Labeled internal and surrogate standards present in the sample have their identifica-
tions and retention time printed above their peak on the chromatogram. The chromatogram is
followed by the interim report. On the interim report a $ is indicative of a surrogate standard and
a * represents an internal standard. The interim report from the instrument is followed by the
target spectra of detected compounds. Four spectral plots are included for each compound: a raw
spectrum of the peak, a background subtracted version of the same spectrum, a library spectrum
of the compound, and a plot showing the percent difference between the library spectrum and the
background subtracted spectrum. Extracted ion current profiles are plotted on the right-hand side
of the page showing the quantitation mass and one or two other prominent ions known to be
present in target compound as they appear in the sample peak.
Results:
All samples were extracted and analyzed within the Method 8270 holding times.
Please note that naphthalene was found at a level below the quantitation limit in the laboratory
blank. This analyte should not be considered truly present in the native samples unless detected at
a level at least five times the level in the blank. If the analyte level in the sample is twenty times
the level in the blank, the blank contribution can be considered statistically insignificant.
Analytes were detected in samples RUN1 through RUN5 at levels that exceeded the calibration
range. These samples were diluted in order to bring these amounts within the linear calibration
range of the instrument. Only the diluted results are reported. Please be aware that target analytes
present at lower concentrations may have been diluted out of these samples.
n
-------
TRIANGLE LABORATORIES, INC.
CASE NARRATIVE
September 12,1997
42930B
All internal standard areas were within Method 8270 quality control limits in the laboratory blank
and samples RUN2, RBI, FBI, and FB2. The internal standard areas for chrysene-dn and/or
perylene-d-,2 were outside Method 8270 quality control limits in samples RUN1, RUN3, RUN4,
and RUNS, These internal standards are flagged with "IS High" and the amounts quantitated
against them should be considered estimated. These samples were analyzed multiple times with
similar results for these internal standards, confirming the likely presence of a matrix effect.
All surrogate standard percent recoveries were within in-house quality control limits as defined by
the following 95 percent confidence intervals:
Surrogate Standards Mean 95% confidence interval
anthracene-dio 77 37.45 - 116.75
pyrene-djo 80 33.65 - 126.15
Sample Calculations:
Response Factor, RF = Area analvte x Amt Is
Area IS x Amt analyte in the ccal
Amount ug = Area analvte x Amt IS x DF
Area IS x RF
Where:
Amt IS = amount of internal standard = 40 ug
Amt analyte in the ccal = amount of analyte in the continuing calibration = 50 ug
DF = dilution factor
The data reported has been judged to be valid and in compliance with the guidelines of Method
8270A Rev. 1 (7/92) except as noted above. Should you have any questions about this project,
please feel free to contact our Project Scientist, Amy Boehm, at (919) 544-5729, ext. 268.
For Triangle Laboratories, Inc.,
Report Preparation: Quality Control:
D »
Penny A. Brock
Report Preparation Chemist
The total number of pages in this data package is
S~}Q-
ScxtolK A,
Report Preparation Chemist
,*
4
-------
TRIANGLE LABORATORIES, INC.
LIST OF CERTIFICATIONS AND ACCREDITATIONS
ENVIRONMENTAL
American Association for Laboratory Accreditation. Expires July 31, 1997. Certificate
Number 0226-01. Accreditation for technical competence in Environmental Testing.(Including
Waste Water, Sol/Haz Waste, Pulp/Paper, and Air Matrices) Parameters are AOX/TOX,
Volatiles, Pesticides, PCB's. BNA's, and Dioxin/Furan. Method 1613 for Drinking Water.
State of Alabama, Department of Environmental Management Expires December 31,
1997. Laboratory I.D. # 40950. Dioxin in drinking water.
State of Alaska, Department of Environmental Conservation. Expires December 21, 1997.
Certificate number OS-00397. Dioxin in drinking water.
State of Arizona, Department of Health Services. Expires May 26, 1998. Certificate
#AZ0423. Drinking Water for Dioxin, Dioxin in WW and S/H Waste.
State of Arkansas, Department of Pollution Control and Ecology. Expires February 18,
1998. Pulp/paper, soil, water, and Hazardous Waste for Dioxin/Furan; AOX/TOX.
State of California, Department of Health Services. Expires August 31, 1997. Certificate
#1922. Selected Metals in Waste Water; Volatiles, Semi-volatiles, and Dioxin/furan in WW and
Sol/Haz Waste. Dioxin in drinking water.
State of Connecticut, Department of Health Services. Expires September 30, 1997.
Registration # PH-0117. Dioxin in drinking water.
Delaware Health and Social Services. Expires December 31, 1997. Certificate #NC 140.
Dioxin in drinking water.
Florida Department of Health and Rehabilitative Services. Expires June 30, 1997.Dioxin in
DW. Drinking Water ID HRS# 87424. Metals, Extractable Organics (GC/MS), Pesticides/PCB's
(GC) and Volatiles (GC/MS) in Environmental Samples. Environmental water ID HRS#
E87411.
RcviMd mmr jn, Triangle Laboratories, Inc.
prim801 Capitola Drive P.O. Box 13485
Durham, NC 27713-4411 Research Triangle Park, NC 27709-3485
919-544-5729 Fax # 919-544-5491 _
J
-------
Hawaii Department of Health. Expires March 1, 1998. Dioxin in drinking water, "Accepted"
status for regulatory purposes ,
Idaho Department of Health and Welfare. Expires November 30, 1997. Dioxin in drinking
water.
State of Kansas, Department of Health and Environment. Expires January 31, 1998.
Environmentai Anaiyses/Non potable Water and Solid and Hazardous Waste. Method 1613
for drinking water. ID #'s - Drinking water and/or pollution control - E-215. Solid or Hazardous
Waste - E-1209.
Commonwealth of Kentucky, Department for Environmental Protection. Expires
December 31, 1997. ID#90060. Dioxin in drinking water.
Maryland Department of Health and Mental Hygiene. Expires September 30, 1997.
Certification #235. Drinking water by Method 1613A.
State of Michigan, Department of Public Health. Expires March 31, 1997. Drinking water by
Method 1613.
Mississippi State Department of Health. No expiration date.. Dioxin in drinking water.
Montana Department of Health and Environmental Services. Expires December 31, 1997.
Dioxin in drinking water.
State of New Jersey, Department of Environmental Protection and Energy. Extended by
state. Temporary certificate until June 30, 1997 or sooner. ID #67851. BNAs and Volatiles.
Dioxin in drinking water.
State of New Mexico, Environment Department Expires July 31, 1997. Dioxin in drinking
water.
New York State Department of Health. Expires June 30, 1997. ID #11026. Environmental
Analyses of non-potable Water, Solid and Hazardous Waste. Method 1613 in DW.
State of North Carolina, Department of Environment Health and Natural Resources
Expires December 31,1997. Certificate # 37751. Dioxin in drinking water.
State of North Carolina, Department of Environment, Health, and Natural Resources,
Division of Environmental Management. Expires December 31, 1997. Certificate # 485.
Metals, pesticides & PCBs, semi-volatiles and volatiles; TCLP.
North Dakota State Department of Health and Consolidated Laboratories. Expires
December 31,1997. Certificate # R-076. Effective October 4,1993. Dioxin in drinking water.
Revracd jm
Printed G/2&97
b
-------
Oklahoma Department of Environmental Quality. Expires October 31, 1997. Laboratory
#9612. Dioxin by 1613A, 8290 and 8280.
State of South Carolina, Department of Health and Environmental Control, Expires June
30, 1997. Certificate number #99040001 (drinking water). Expires August 31, 1997. Certificate
number #99040002 (other parameters). Dioxin/Furans, BNA, Voiatiies. and PCBs/pesticides
under Clean Water Act. 2.3,7.8-TCDD for Drinking Water, and Organic extractabies for Solid
and Hazardous Waste.
State of Tennessee. Department of Environment and Conservation. Expires February 5,
1999. iD #02992. Method 1613 Drinking water only.
U.S. Department of Agriculture Soil Permit. Expires September 30, 2002. Permit No. S-
4958. Under the authority of the Federal Plant Pest Act, permission is granted to receive
foreign soil samples for use in laboratory analysis.
U.S. Army Corps of Engineers. Expires November 30, 1997. Validated to perform methods
8280 & 8290 for Lockboume Landfill Site Investigation, Defense Distribution Depot Projects,
and assorted projects for the USACE North Pacific Division Laboratory.
U.S. EPA Region V. Expires November 14,1999. Dioxin in drinking water.
U.S. EPA Region VIII, for the State of Wyoming. Expires November 13, 1997. Dioxin in
drinking water.
State of Utah, Department of Health. Expires December 31, 1997. Certificate Number E-
166. Certification for the following parameters; Semi-Volatiles and Voiatiies under RCRA;
Voiatiies under Clean Water Act; Dioxin/furans by Method 8280; Drinking water for Dioxin by
Method 1613; Metals including Mercury and Microwave Digestion.
Commonwealth of Virginia, Department of General Services, Division of Consolidated
Laboratory Services. Expires June 30, 1998. ID # 00341. Dioxin in drinking water.
State of Washington, Department of Ecology. Expires September 11, 1997. Lab
Accreditation Number C067. Scope of Accreditation applies to water analyses for
Poiychlorinated Dibenzo-p-dioxins and Polychlorinated Dibenzofurans, BNA Extr (Semivolatile)
Organics and Purgeable (Volatile) Organics.
State of Washington, Department of Health. Expires April 30,1998. Dioxin in drinking water.
Lab I.D. 129
State of West Virginia, Department of Health. Expires December 31, 1997. Certificate No.
9923(C). Dioxin in drinking water.
Revised 6/26*97 jm
Pnnted &2mi
i
-------
State of Wisconsin, Department of Natural Resources. Expires June 30, 1997. Laboratory
ID Number 999869530. Certification for the following categories of Organics: Purgeable,
Base/Neutral, Acid, PCBs, and Dioxin. Expires November 14, 1999. Laboratory ID
999869530. Dioxin in drinking water.
PHARMACEUTICAL
Drug Enforcement Agency (DEA). Expires November 30, 1997. Registration number
RT01195835. Controlled substance registration for schedules 1,2,3,3N,4,5.
N.C. Department of Human Resources. Expires October 31, 1997. Registration number
NC-PT 0000 0031. North Carolina controlled substances registration. Application submitted for
renewal.
Food & Drug Administration (FDA) Registration. Expires July 1997. ID #'s 001500 1053481.
Annual registration of drug establishment. Annual registration of drug establishment.
OTHER
Clinical Laboratory Improvement Amendments (CLIA) Registration. Expires May 30, 1999.
ID # 34D0705123. Department of Health & Human Services, Health Care Financing
Administration.
U.S. EPA Large Quantity Hazardous Waste Generator. No expiration date. EPA ID
#NCD982156879. Permit indicates that the laboratory is a large generator of hazardous waste.
North Carolina Radioactive Materials License. Expires April 30 1998. License No. 032-
0954-1. License authorizes the licensee to receive, acquire, own, possess, transfer, import and
use such radioactive materials as designated.
North Carolina General License for Radiation Protection. No. expiration date. License No.
032-875-OG. The genera! license applies only to radioactive material contained in devices
which have been manufactured and labeled in accordance with specific requirements.
Revised 6T2&97 jm
Print*d &2S/97
8
-------
Triangle Laboratories of RTP
Sample Identification Index for Project 42930B
ClientU: TLll&i File Name:
RUNl
179-98-1AC-E
YP579
RUN2
179-98-2AC-E
YP578
RUN3
179-98-3AC-E
YP580
RUN4
179-98-6AC-E
YP581
RUN5
179-98-7AC-E
YP596
FBI
179-98-4AC-E
VG194
FB2
179-98-8AC-E
VG195
RBI
179-98-5AC-F
VG189
SBLK 082597
SBLK 082597
VG188
Triangle Laboratories of RTP, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Proj_Sum v4.0
9
-------
Client ID:
Triangle Laboratories of RTP
Project Summary for Project 42930B
RUN1 RUN2 RUN3
RUN4
RUN5
Filename:
YP579
YP578
YP580
YP581
YP596
TU Id :
179-98-1AC-E
179-98-2AC-E
179-98-3AC-E
179-98-6AC-E
179-98-7AC-E
Matrix :
MM5
MM5
MM5
MM5
MM5
Units :
"g
"g
"g
ug
ug
Naphthalene
Ilieii3023.a6 .
1395.59
292495
2632.85
2965.67
2-Methylnaphthalene
1144.50
2324,33
2201.60
2284.46
2-Chioronaphthalene
17.48
(5.99)
(5.54)
17.86
(7.50)
Acenaphthylene
214.30
90 M
189.14
¦ ' 187.38
238.95
Acenaphthene
128.95
5032
110.39
101.60
127.47
Fluorene
262.63
112.49
22220
206.64
289.91
Phenanthrene
1478.60
679.06
1476.65
1208.86
1765.05
Anthracene
264.52
11434
256.87
185.68 :
345-94
Fluoranthene
782.14
285.67
773.00
523.19
887.81
Pyrene
350.18
175.13
316.13
303.27
356.63
Benzo(a)anthracene
175.06
6834
119.35
117.73
140-32
Chrysene
283.24
112.78
176.92
228.82
209.79
Benzo(b)fluoranthene
91,76
. 34.80
46-44
53,41
57.11
Ben2o(k)fluoranthene
26.11
11.72
19.08
23.01
7.76
Benzo(e)pyrene
43.41
16.20
22.29
28.92
24.95
Benzo(a)pyrene
21-55
8J8
8.89
11.63
16.29
Perylene
5.34
(5.09)
(2.94)
(3.18)
(3.81)
Indeno(l,23-cd)pyrene
(235)
(4.06)
(2.35)
(2.54)
(2.83)
Dibenz(a,h)anthracene
(3.25)
(5.62)
(3.24)
(3.51)
(3.77)
Benzo(g,h,i )perylene
3.43
(4.49) 1
WmmM
(2.80)
(2.93)
( )-Estimated Detection Limit Page 1
Triangle Laboratories of RTP, Inc. Savar v3.5
801 Capitola Drive • Durham, North Carolina 27713 Printed: 16:01:02 09/12/97
Phone: (919) 544-5729 • Fax: (919) 544-5491
10
-------
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Client ID:
FBI
Triangle Laboratories of RTP
Project Summary for Project 42930B
FB2 RBI
SBLK 08259
7
Filename:
VG194
VG195
VG189
VG188
TLIId :
179-98-4AC-E
179-98-8AC-E
179-98-5AC-F
SBLK 082597
Matrix :
MM5
MM5
MM5
XAD/H20
Units
ug
ug
ug
ug
Naphthalene
3.72
1.74
1.16
12.39
2-Methylnaphthalene
(1-61)
(1.40)
(1.37)
(1.33)
2-Chloronaphthaiene
(1.45)
(1.30)
(1.35)
(1.32)
Acenaphthylene
(0.97)
(0.87)
(0.90)
(0.88)
Acenaphthene
(1.71)
(1.54)
(1.60)
(1.57)
Fluorene
(1.44)
(1.30)
(1.35)
(1.32)
Fhenanthrene
(1-01)
(0.88)
(0.89)
(0.84)
Anthracene
(1.05)
(0.92)
(0.93)
(0.87)
Fluoranthene
(1.18)
(1.03)
(1.04)
(0.98)
Pyrene
(1.36)
(1.19)
(1.10)
(1.01)
Benzo(a)anthracene
(1.69)
(1.48)
(1.36)
(1.26)
Chrysene
(1.94)
(1.70)
(1.56)
(1-45)
Benzo(b)£luoranthene
(1.80)
(1.61)
(1.44)
(1.35)
Benzo(k)fluoranthene
(1.85)
(1.65)
(1.47)
(1.39)
Benzo(e)pyrene
(1.86)
(1.66)
(1.48)
(1.39)
Benzo(a)pyrene
(1.99)
(1.78)
(1.58)
(1-49)
Perylene
(1.97)
(1.76)
(1.57)
(1.48)
Indeno(l,2,3-cd)pyrene
(2.12)
(1.89)
(1.68)
(1.59)
Dibenz(a,h)anthracene
(2.77)
(2.47)
(2.20)
(2-07)
Benzo(g,h,i)perylene
(2.40)
(2.15)
(1.91)
(1.80)
(
)-Eatimated Detection Limit
Pag# 2
Triangle Laboratories of RTP, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.5
Printed: 16:01:02 09/12/97
11
-------
(T-WH
r Eastern Research Group COC
C\
Younqstown Sintering Plant
CHAIN OF CUSTODY
RELINQUISHED BY =
RELINQUISHED BY =
CKAeft vf, DATE = [Q C9c(-7 receiveddate
DATE = ^ ' RECEIVED BY: 4? DATE:
SAMPLE ID
FIELD ID
SAMPLE TYPE
PRESERVATIVE
COMMENTS
ANALYSIS
YCP-63
YCP-
81297
M23-
SBOUTLET- PR-
1
METHOD 23. SBOUTLET. RUN 1
MoCI2/Ace!one Probe Rinse
D/F/PAH
YCP-64
YCP-
8)297
M23-
SBOUTLET- PRT/CRT-
1
METHOD 23, SBOUTLET. RUN 1
Toluene Probe Rinse
D/F/PAH
YCP-65
YCP-
81297
M23-
SBOUTLET- F-
1
METHOD 23. SBOUTLET. RUN 1
Filter
D/F/PAH
YCP-66
YCP-
81297
M23-
SBOUTLET- XAD-
1
METHOD 23, SBOUTLET, RUN 1
XAD Trap
D/F/PAH
YCP-67
YCP-
81297
M23-
SBOUTLET- IMP-
1
METHOD 23, SBOUTLET. RUN 1
Impingers and Rinses
D/F/PAH
YCP-68
YCP-
813S7
M23-
SBOUTLET- PR-
2
METHOD 23. SBOUTLET, RUN 2
MeCI2/Acolono Probe Rinse
D/F/PAH
YCP-09
YCP-
8i:,97
M23-
SBOUILET- PRT/CRT-
2
METHOD 23. SBOUTLET. RUN 2
Toluene Probe Rinse
D/F/PAH
YCP-70
YCP-
81397
M23-
SBOUTLET- F-
2
METHOD 23, SBOUTLET, RUN 2
Filler
D/F/PAH
YCP-71
YCP-
81397
M23-
SBOUTLET- XAO-
2
METHOD 23, SBOUTLET. RUN 2
XAD Trap
D/F/PAH
YCP-72
YCP-
81397
M23-
SBOUTLET- IMP-
2
METHOD 23, SBOUTLET. RUN 2
Impingers and Rinses
D/F/PAH
YCP-73
YCP-
81397
M23-
SBOUTLET- PR-
3
METHOD 23, SBOUTLET. RUN 3
MeCI2/Acetone Probe Rinse
D/F/PAH
YCP-74
YCP-
81397
M23-
SBOUTIET- PRT/CRT-
3
METHOD 23, SBOUTLET, RUN 3
T olueno Probo Rinse
D/F/PAH
YCP-75
YCP-
81397
M23-
SBOUTLET- F-
3
METHOD 23, SBOUTLET, RUN 3
Filter
D/F/PAH
YCP-76
YCP-
81397
M23-
SBOUTLET- XAD-
I
3
METHOD 23, SBOUTLET, RUN 3
XAD Trap
D/F/PAH
YCP-77
YCP-
81397
M23-
SBOUTLET- 1MP-
3
METHOD 23, SBOUTLET. RUN 3
impingers and Rinses
D/F/PAH
YCP-78
YCP-
81397
M23-
SBOUTtET- PR-
FB1
METHOD 23, SBOUTLET, FB 1
MoCI2/Acetone Probe Rinse
D/F/PAH
YCP-79
YCP-
81397
M23-
SBOUTLET- PRT/CRT-
FBI
METHOD 23. SBOUTLET, FB 1
Toluene Proba Rinse
D/F/PAH
YCP-80
YCP-
81397
M23-
SBOUTLET- F-
FBI
METHOD 23, SBOUTLET, FB 1
Filler
D/F/PAH
YCP-81
YCP-
81397
M23-
SBOUTIET- XAD-
FBI
METHOD 23, SBOUTLET, FB 1
XAD Trap
D/F/PAH
YCP-82
YCP-
81397
M23-
SBOUTtET- IMP-
FBI
METHOD 23, SBOUTLET, FB 1
impingers and Rinses
D/F/PAH
YCP-83
YCP-
81397
M23-
SBOUTLET- PR-
RBI
METHOD 23, SBOUTLET, RB 1
Acelone
D/F/PAH
YCP-84
YCP-
81397
M23-
SBOUTLET* PRT/CRT-
RBI
METHOD 23. SBOUTLET, RB 1
Toluene Rinse
D/F/PAH
YCP-85
YCP-
81397
M23-
SBOUTLET- F-
RB1
METHOD 23, SBOUTLET. RB 1
Filler
D/F/PAH
YCP-86
YCP-
81397
M23-
SBOUTLET- XAD-
R81
METHOD 23, SBOUTLET. RB 1
XAD Trap
D/F/PAH
YCP-8?
YCP-
81397
M23-
SBOUTLET- IMP^
R81
METHOD 23. SBOUTLET, RB 1
MeCi2
D/F/PAH
YCP-167
YCP-
81397
M23-
SBOUTLET- HPLC
RB1
METHOD 23, SBOUTLET, RB 1
HPLC WATER
D/F/PAH
Pago 1
-------
-
-------
OR I
C.
•flH in HRyctu^WS
cus
Sample Seals: Absent
Container.,.: Intact
Custody Seal : Absent
Chain of Custody : Present
Sample Tags : Absent
Sample Tag Numbers: Not Listed on Chain of Custody
mo Forms : N/A
| IU Project Number 42930 •>.-? VA'K: ,
j Client-. ER302 - Eastern Research Group :
j Date Received
-i r
| 08/19/97 j By,
-I 1
Ice Chest
ICE
Temp 15.0 C
j|TLI Number Client Sample ID Matrix] To LAB To STORAGE
||mR/IhCPM, Client COC ID » Location j Date/Init Dat
-------
m-
f* | custody Seal i Absent
' | Chain of Custody *. Present
jj Sample Tags : Absent
J Sample Tag Numbers: Not Listed on Chain of Custody
jj SMO Forms *, N/A
=TRIANGLE LABORATORIES, INC, -- LOG IN RECORD/CHAIN OF CUSTODY"
Sample Seals: Absent
Container.,,: Intact
| TLI Project Number 42930
| Client: ERG02 - Eastern Research Group
11
•UWiiBooM
| Ice Chest
ICE
Temp 15.0 0
||TLI Number Client Sample ID Matrix
||mR/H:CPM Client COC ID * Location
I i I 1 1 i I
To LAB I To STORAGE I To LAB | To STORAGE
Dnte/Init j DateVlnit | Date/Init | Date/Init
Olite
Date Received
OB/19/97
| 98 J
| Carrier and Number | JIM MCGUAGHEY
¦ '
i "i i '
To LAB I To STORAGE I To LAB | To STORAGE
Date/Init | Date/lnit | Date/Init | Date/Init
4-
DISPOSED I
Date/Init .jj
jjl79-98-3E
YCP-77
YCP-77
(RUN3)
SRUN3)
IMP/RINSE
COl
^P~Y
j|l79-98-4»
YCP-7B
YCP-78
(FBI)
(FBI}
MECL2/ACE RINSE
COl
179-98-4B
YCP-79
YCP-79
(FBI)
(FBI)
TOLUENE RINSE
COl
V.
1179-98-4C
YCP-80
YCP-80
(FBI)
(FBI)
FILTER
COl
179-98-4B
YCP-81
YCP-81
(FBI)
(FBI)
XAD
COl
m
jjl79-98-4E
YCP-82
YCP-82
(FBI)
(FBI)
IMP/RINSE
COl
|jl7t-98-SA
YCP-8S
YCP-83
(RBI)
(RBI)
ACETONE
COl
jjl79-98-5B
' YCP-84
YCP-84
(RBI)
(RBI)
TOLUENE RINSE
COl
J179-98-5C
I
II
|l79-98-5D
YCP-85
YCT-85
(RBI)
(RBI)
FILTER
COl
YCP-86
YCP-8S
(RBI)
(RBI)
XAD
COl
j|l79-98-SB
II
b
YCP-87
YGP-87
(RBI)
(RBI)
MECL2
COl
j|l79-98-5F
YCP-167
YCP-167
(RBI)
(RBI)
HPLC MATER
COl
J179-98-6A
YCP-115
YCP-115
(RUN4)
(RUN4)
MECL2/ACE RINSE
COl
V
1I179-98-6B
YCP-116
YCP-116
(RUN4)
(RUN4)
TOLUENE RINSEI
COl
Receiving Remarks! THE CUSTOMER TOOK THE COOLERS BACK.
|| Archive Remarks:
fi .III. Ill
=Form Revised 05/27/1997 -- Page 2 OF 3=
-------
Custody Seal : Absent
Chain of Custody : Present
Sample Tags : Absent
Sample Tag Numbers; Hot Listed on Chain of Custody
SMO Forms : N/A
=TRIANGLE LABORATORIES, INC. -- LOO IN RECORD/CHAIN OF CUSTODY-
Sample Seals: Absent
Container...: Intact
| TLI Project Number 42930
| Clients ERG02 - Eastern Research Group
Date Received
1 r
| 08/19/97 | B<
I
| Book H
I II
I "» II
1|
Page II
CO
Ice Chest
ICE
IH
Temp 15.0 C
| Carrier and Number | JIM MCGUAGHBY
» '
I ®8 J
X«-—f»J|
DISPOSED H
Date/Init |
||TLI Number..
HmR/MsCPH.
I 1 1 1 1 —=»™
Client Sample ID Matrix| To LAB | To STORAGE| To LAB | To STORAGE| To LAB | To STORAGE| To LAB
Client COC ID, * Location j Date/Init j Date/Irvit j Date/Init j Date/Init j Date/Init j Date/Init j Date/Init
ite/1
+
4-
To STORAGE
| Date/Init
jjl79-98-6C
YCP-117
YCP-117
(RUN4)
(RUN4)
FILTER
€01
J179-98-6D
YCP-118
YCP-118
(RUN4)
(RUN4)
XAD
C01
179-98-6B
II
YCP-119
YCP-119
(RUN4)
(RUN4)
IMP/RINSE
C01
j|X79-98-7A
II
||l79-98-7B
II
YCP-120
YCP-120
iRUNS}
(RUNS)
MECL2/ACE RINSE
C01
YCP-121
YCP-121
(RONS)
(RUNS)
TOLUENE RINSE
C01
jjl79-9B-7C
II
YCP-122
YCP-122
(RONS)
(RUNS)
FILTER
C01
||179-98-7D
YCP-123
JfCP-123
(RUNS)
(RONS)
XAD
C01
[179-98-7B
YCP-124
YCP-124
(RUMS)
(RUNS)
IMP/RINSE
C01
j|l79-98-8A
YCP-154
XCP-1S4
(FB2)
(FB2)
MECL2/ACE RINSE
COi
jjl79-98-8B
XCP-15S
YCP-1S5
(FB2)
(FB2)
TOLUENE RINSE
C01
jjl79-98-8C
XCP-156
YCP-1S6
(FB2^
(FB2)
FILTER
C01
j|179-98-8D
VCP-1S7
YCP-1S7
(FB2)
(FB2)
XAD
COI
HI-
H179-98-8B
YCP-158
YCP-158
(FB2!
(FB2)
IMP/RINSE
C01
II Receiving Remarks I THE CUSTOMER TOOK THE COOLERS BACK.
Archive Remarks:
=Form Revised 05/27/1997 -- Page 3 OF 3=
-------
I
PAGE 1 OF 1
I
| Project: 42930B
TRIANGLE LABORATORIES, IMC.
Sample Preparation Tracking & Management Form
Client: Eastern Research Group (ERG02)
I
Method:
& Solvent/Acids{1
I
«*-%, Sample Information A
Extraction Date: 52flKft X, ,,ti L-
: mk. Lot: -So <=»<
•. .... ^ v-A>^
r I
| | TLI /
I ample| SAMPLE ID /
crd | /
I
I
!8
I
| TLX Blank
I
SBLK |
i , I
J??iH
,<>0Z2Vt>zft joZZDtrtG azmciooc
fcf
L/SSL/^ , _ _
ioomM wo^j^h ^A$r,'^r
| Sample jFinal f>? t2- m*cy? ti&f? I
CLIENT |Wgt / Vol [ Volume fo? !Z< /«>1P3 /2T/t^'a?/Zr /Q-=flfcg /ZT /Tjj / /
. . i f t t' 1 ~.jf. » r . n
SAMPLE ID | g / ml | ml |
J /_
18 I 179-9S-1AC-E
bi I
|B | 179-98-2AC-E
b02 I
RUN1
RUN2
. % . >/n.
|B I 179-98-3AC-
^)03 |
179-98-4AC-S
I
| 00
I
RUN 3
FBI
^ !J//
'/V\.
179-98-SAC-F
179 - 98 - 6 AC-E
| 179-98-7AC-E
07
t„
| 172-98-8AC-E
RBI
I 1 \jj>> 1
I I I TV I
n
RUN4
i I
%>
>n\
I i I
RUNS | !
FB2
TLI LCS
09
IB I TLI LCSD
010 I
t
I
I
TLI LCS
TLI LCSD
n0
-------
HltsD A /3
MM5SDX.TXT
06/17/96
SOP#
OWL SAMPLE EXTRACTION AND CLEANUP TRACKING FORM
JOINT DIOXIN PROJECT {IMPINGER FOR ORGANICS)
STEP DESCRIPTION
~ fPrep MeCl2 presoxed glassware with 350ml MeCl2.
OWL-lil / K/D front half and back half rinses to 1 ml.
J Place filter in thimble and empty XAD into thimble.
I Add concentrated FH and BH rinses to thimble.
DSP-128 j Spike lOOOul .Spike "X" @ lOOug/ml into all samples.
DSP-128 Spike lOOOul Spike "W" ® lOOug/ml into only the LCS/LCSD samples,
! Spike lOOOul BN QC @ lOOug/ml into the LCS/LCSD samples,
Spike lOOOul A QC S lOOug/ml into the LSC/LCSD samples designated
for only 8270 analysis.
Spike 40ul USF-I @ 0. lug/ml into all samples.
Spike 4 0ul USF-MX @ O.Olug/ml into the LCS/LCSD designated for
only Dioxin analysis.
NOTE: 8270 and DIOXIN analyses have separate LCS/LCSD samples
/ consisting of 30grams of XAD. NO prespikes need to be added.
/ S.oxhlet extract for 16 hours with CH2C12.
I Rotovap. Toluene rinses to near dryness. Add boiling chips and
[ 350ml fresh clean toluene to flaskT Resox in toluene for 16 hrs.
\ Toluene extract is for only-DIOXIN analysis.
OWL-111 K/D down impinger rinses, if any.
- -- Pour impinger water in separatory funnel, measure and
record pH and volume.
, Add concentrated impinger rinses directly to the water.
DSP-128^J~Spike lOOOul Spike "W" to all samples.
NOTE: The LCS/LCSD does not have a BH (H20) fraction.:
Adjust pH of H20 to <2 and extract 3 x 60 ml CH2C12,
Adjust pH of H20 to >11 and extract 3 x 60 ml CH2C12.
Filter the impinger and XAD extracts thorough Na2S04 separatelyyf) M
K/D the extracts separately to 10 tnL. Sox ^
Divide both extracts 1:1; give 1/2 of the XAD extract 1
to high level dioxin; archive 1/2 of the water extract t 'VI rC
hinp 1 /9 rs-f Tan anH 1 Irs-F wa(-pr 1 ml.
OWL-111 ] Transfer to 1/2 dram vial with 2 X 0.5 ml MeCl2 rinses
OWL-111 J N2 to 1.0 ml final volume.
Complete paperwork. •
\ Relinquish Semi-Volatiles to GC/MS
I
I
I
I
I
I
I
I
I
.2§**
2yp,
I
I
I
I
I
I
13
I
-------
: 1 TRIANGLE LABORATORIES OF RTP, INC.
fl PROJECT COMMUNICATION TRACKING FORM page of
"1
| TLI Project Number: 43DIB
m Use this form to record all exchanges of information between production units as well as personnel
£ handling this project. Decisions, corrective actions and recommendations must also appear on this
tracking'document.
ED
eg
Name
Comment / Decision / Resolution / Action / Observation
1-2«f
VD
I
f If
I
1
i d )Z
¦
2- . % ! L
I
3 , S
1
4 i.n 12L
o uc ' 1Z-
I
1 "v
w .< a
*
1 V 1
• % •
a
% i.n • it-
*
i
1? to Oy^ L r>£ ' dvaur.fci into
¦i
Vh3. o^Cr '/ i oi-
r
" VY)s>f ffotroriinn. ¦? &>v>
-------
PROJECT COMMUNICATION TRACKING FORM
page
I
1
I
I
\
"TL1 Project Number: AZM
Use this form to record all exchanges of information between production units as well as personnel
¦ handling this project. Decisions, corrective actions and recommendations must also appear on this
tracking document
Date - Name Comment / Decision I Resolution / Action / Observation
I
fs, trvr>v^ Thjei
]
!£1
- UpA rg^,. tt^.Q lM
tfrbf-rw 7-Q
6j40
4*?r>
I5Q_
1
4/nC)
¦hMvb^Mmmhbhmhmi
4_iO.
JQ.
UOO
54a
GO
y
I
4-
ce.
JiD.
L_D__i5bv
k -.5^0
SOD
O
7- o
4^
*£ <*o
_12*_
e?
>
1
1
rir
X*i
1
r< ' Hli
X t\'#
J-$Z>
^g) p-H sCW- add r?^;tea
1
ID
W i
A
kii-~g£PtiA^O--;>g tiU>C -WE vgbift Vte-P ?gTTS.»rr4ic*,£?."g-.
LvC^.'b taawfr 5ftfa-£p jiP& LDv» ?-B-,t l IS IVC?i
"VTSt Ak%-
Trianfle Laboratories, Inc
TLI PROJECT# 03822
DATE 8/7/97 TLI BLANK
SPIKE 4.0ng USF-C & USF-S
SPIKE lOOng PAH-HRMS
SPIKER tXH
PREPARER G.L.
I
1
-------
Date: 08/25/97
Time: 15:11
Sample
It crd TLI_Number, . Customer .Sample. Id.
000 TLI Blank SBLK
001 179-98-1AC-E RUN1
00? 179-98-2AC-E RUN2
003 179-98-3AC-E RUN3
004 179-98-4AC-E FBI
005 179- 98 -SAO F RBI
006 179-98-6AC-E RUN4
007 179-98-7AC-E RUNS
006 179-99 8AC-R FB2
009 TLI LCS TLI I.CS
010 TLI LCSD TLI LCSD
End of Report "*
F. XAD
No Color,
TRIANGLE LABORATORIES, INC.
Wet Lab MM5/PUF Observations
Project: 42930-B
Filter Glass Wool PUF
Color Color Color...
0 WHITE
1 PINK WHITE
PINK WHITE
PINK WHITE
WHITE
WHITE
PINK WHITE
PINK WHITE
WHITE
0 LOT P-1000
0 LOT P-1000
NA NA NA
LT BROWN DK YELLOW NA
I,T BROWN DK YELLOW NA
LT BROWN DK YELLOW NA
WHITE WHITE NA
WHITE WHITE NA
LT BROWN DK YELLOW NA
LT BROWN DK YELLOW NA
WHITE WHITE NA
NA NA NA
NA NA NA
PRDPERC V3.19
Page: 1
Odor
NA
CHEMICAL
CHEMICAL
CHEMICAL
NONE
NONE
CHEMICAL
CHEMICAL
NONE
NA
NA
Air
Q-No.
03822
03822
03822
03822
03822
03822
03822
03822
03822
NA
NA
Entered.By.
HIIiLKT
HILLKT
HILLKT
HILLKT
HILLKT
HILLKT
HILLKT
HILLKT
HILLKT
HILLKT
HILLKT
Date.... Time..
08/25 15:08 F
08/25 15:08 F
08/25 IStOS F
08/25 15:08 F
08/25 15:08 F
08/25 15:08 F
08/25 15:08 F
08/25 15:08 F
08/25 15:08 F
08/25 15:08 F
08/25 15;08 F
«r*4
ca
-------
PAGE 1 OF 1
TRIANGLE LABORATORIES, INC.
Transfer Chain-of-Custody Form
Project 42930-B
Transfer From: OWLS5 To: OMSSV
Initials.. Date Time...
Released ¦ by: M** 0&j 3*,T1 _£: 30 M\
Accepted by:
MILES.ID.
. TLI No
Cust.Id.
42930-B
-000
TLI Blank
SBLK
42930-B
-001
179-98-1AC-E
RUN1
42930-B
-002
179-98-2AC-E
RUN2
42930-B
-003
179-98-3AC-E
RUN3
42930-B
-004
179-98-4AC-E
FBI
42930-B
-005
179-98-SAC-F
rviD x
42930-B
-006
179-98-6AC-E
RUN4
42930-B
-007
179-98-7AC-E
RUN5
42930-B
-008
179-98-8AC-E
FB2
42930-B
-009
TLI LCS
TLI LCS
42930-B
-010
TLI LCSD
TLI LCSD
+
Additional comments or instructions:
XfrCOC
(Rev 11/01/94)-
-------
| SEMIVOLATILE GC/MS TRACKING FORM
-RTP Project #: CfW£>
MATRIX: ((mmOpUF Water Soil Other
r
M
I
mA
TC
): /f8270 je
1ETHOD: ([8270 /625 CLP
kNALYTE LIST: Table 2 TCLP 625 CLP CAAVAP(w) C8/CP Cher
CAL Name: ICAL V
f Date
yippmie1;:!
Re Name
Comments
ten
V5iZ.
DFTPP
ypsio
n
£31 *1
SSTD050
Vpsij
\%6h
\~y\ ^ * 2ac-&
yps-78
f ¦
*
Ml
e^uKi i
£ *s-s i* lugb
I 1
i /
Uflx,
c's -2Ac^
€jU ^ 3
ipse#
is
2lt»
^'£
Vp5g J
15 Vlu£jV>
J V
! %> 0\ f.
Qlb'Z
crpT^P
V-Pssrc,
0163
5371
-S&lPC'SG
\-J
i ZDS
vrr^G--7^c-e
i$4*U VU^Sj
^TRIANGLE LABORATORIES OF RTP, INC.
I
SOP No. OMS130
Revision 3.0
12 January 1994
page 9 of 10
-------
SEMIV0LAT1LE GC/MS TRACKING FORM
TL-RTP Project #: AZ^^O b
MATRIX: ^MMs) PUF Water Soil Other
METHOD: 0P
"X
cQSis
%
soi^UT
/
W^j
%
0&21EPO
I
Wl<
&d(
V61S3
f
i4i o
4A6-6-
rMs-8 At-*
fez
TRIANGLE LABORATORIES OF RTP, INC.
SOP No. OMS130
Revision 3.0
12 January 1994
paga 9 of to
24
I
I
-------
Triangle Laboratories, Inc.
Run Log
JO
CM
Column Type
Column #
Analysis*
Acqulslllon
Method
OC Method'
Find DBs#
Other*
T>fcC^fe2£"
re lish ^
Standards
Internal / 8urroaate / Recovery
Internal / Surrogate / Recovery
Analyte
482dP
834- 1 »vJ3
%
Extract / Sample volume _jf£2D" mL
PP 8(- /q"7
bale"
Tlrn#**
Project
Sample#
Client ID
Filename
pit*
Operator/Date
Backup*
Proc
Comments***
%
mm
Wvoi
00 SI*>(<17
*£u U-c4
fl| bhi
o» f|»Ht
%
JW
km ek(qi
"to
«W*i
©ato
£sTd«Ht
1
^MIO
yo 9M*"*
3a
JCfc«
*vo I a.ct|L»_*>« - w #/
&cc|iulm-4u«, #
•A :
Wm/
fce r|bHi
*k?
4tLiiaA po
*hfci
nvj
^ .
^Tpibo
**> rifotn
*e *» skill
1*h7
»ni>
1
2186
DPTC*
W*4>3
fcW S")fel«H
fcb
«jo ill t» I \1
i?a.n
1
*188
ber*
foc^ad w>el*Ui
SJfa^7
ik
485b
SBlPlfoi.
^ *1^7
ja)<) H<»|V1
^ vytuJUhpUix'1 AsiWrV
bh->
* Volatile Data Only
9RVRfW3MF0ftMM.RRUNtCXl.t3OC (t/IMI)
Transcribed Data
Dated Signature/Initials Required
Page |g.0_
-------
Triangle Laboratories, Inc.
Run Log
Column Type
Column #
Analysis*
Acquisition
Method
OC Method*
Find DBs*
Other*
T>fc£'(o2«"
2* *r*
l*t 1 I J X>k> J
. rv-s
Standards
Internal / Sunroaate / Recovery
Internal / Surrogate / Recovery
Analyte
40 lop sw qhi-n
s*^l 8
* Volatile Data Only
SRVRnnAtFOflMSULRRUNLCXI DOC
Transcribed Data
Dated Signature/Initials Required
Pagt_£jy.
to
C4
late"
Time**
Project
Sample#
Client ID
Filename
pH*
Operator/Date
Backup*
Proc
Comments***
i
•HiSo
SS'Tdi lots
wmw
on
Go
(St*
£
sSTbot b
ypqn
Kte>
SlbHl
#£l
ssfbtlo
r>e
Vr?
%
SSfbofito
K%?
fyhi
U^S'3
ssii) ogro
yr42J0
t)0 bM*»7
Vp
iew>
435^
o2-6
ypmt
W &le>hi
W
Cv~rv^ passed jar tTH
* U> 6hfa
¦¦ *Mii
Wot
%
*
SCXAJ^Ur fctPrtJVt-
0? a|wh7
tt>
•tMWfl
%
cmwi ,
^pqz3
&Q 8|bhT
to
4t4b48
US- ZF-II
73i"? fcJW HimoS^iASKS
Wz4,
vo &,ble'1
op
2J2J4
ns-v-iz
"*32S u>w muosmmugs
^425
ft) elbfri
w
-------
Triangle Laboratories, Inc.
Run Log
r-
CM
Column Type
Column #
Analysis*
Acquisition
Method
GC Method*
Find DBS*
Other*
4 Whilst
(V)
'
^ N Standards
<&teroaW Surrogate / Recovery
Internal / Surra
pale / Recovery
Analyte
£> mI*vJ
A
tv
Extract / Sample volume
«?
a
leunit
pL.) mL
Date**
Time**
Project
Sample#
Client ID
Filename
pH*
Operator/Date
Backup*
Proc
Comments***
Olio
V
o« 4
flj)
ilil/J w hfi^y
m
1
»
AW
VP W
» »|u
k
\K)
WMl~ W4|iJ fc|u
#tlo
W i
\
itf
W
I " 1
Hi
ID It
1
4M\
6^7\Z0
# 111
(to "I*/
M)
"H;
|0^»>
i
mi
66fD0fcD
VF1U
#D ^
IDfi
•fiu
ItW
i
6SfOO®
\|f'I12>
l» 11"
W
i
1?
1223
*
bMQ020
\HH
Wlfl 1
('it
ffl
Cxmk na<&c1 oWn'ti
I'M
i
jqee
.
1f1l£
f'
OfD\d\u
Mi
\
»
%r
l4#
j
j
^£53
($ bktlw
yo
m%(A fiv Mifcki
|52>0
4n%
J/*
u*s
-------
Triangle Laboratories, Inc.
Run Log
Column Type
Column #
Analysis*
Acquisition
Method
GC Method*
Find DBs*
Other*
9&SbV$
dC wo
Standards
t CTnlemal* Surrogate / Recovery
Internal / Surrogate 1 Recovery
Anaiyte
itZO* tsyp
¦-Jfrnti * Bill..jS.|i LffiTSH ngf*
J) d/*
•%
—Circle unit
Extract / Sample volume Ipl) fjit mL
Oo
~ate**
Time**
Project
Sample#
Client ID
Filename
pH*
Operator/Date
Backup'
Proc
Comments***
|36l»
4
3^68
V
fy? ilW-
»l*ii
I4I2-
i
mpjp
'1
i^P
i
V6?igj
i>o
%
tela
i
w
oiiu
"L
3188
ft? ^Jl|A1
Q-fti
1 T
*1
54^
t>srcD^t)
x/e,iS't|
(j?
iw
h
O^HO
i
*k
ICS
V6i£B
I I
%> lliki
w
(ft*A
%
IjCS PUP
,,M -* 1 '"i"- - —"
pc
^>7
t*I
/A
*1
A
SCU^iOT
mw?.
flp
A.
m
Mr
tww
-------
Triangle Laboratories, Inc.
Run Log
CD
C4
Column Type
Column #
Analysis*
Acquisition
Method
GC Method*
Find DBs*
Other*
9£Bk?2£
434^7 or
.
Standards
rlhlernatV Surrogate / Recovery
Internal / Surrogate / Recovery
Analyte
-fVz.of =Xflh|5-|
%
le unit
Extract / Sample volume \(50 (tiL J mL
no
3ate**
Tims"
Project
Sample#
Client ID
Filename
pH*
Operator/Date
Backup'
Proc
Comments*"
"to*
\\W
te>i
W ^11
Xfi
1707
lH-'rc-rtfrc-*
t^i
V6iWd
Po
—
fttooc-kdl vuxt. $t
o^irKn
—
—
423f3oe>
»H
/"111* "*&<>£
SC el|
^GiKtS'
0®
|S32-
%fT
H «¥
\Ti%2Ac*
zj,
V2AJUf
^Ffw.
VO 4 zf'i 1
pp
M#
4iiw.&
mm-tktrt
5^ r
- j/.Ie n>»
£dN nt»M
\igi m
W °ijt) c» *
Ifar
noa
4W
at ep'Me | rll?_ Ifi7
*30
* Volatile Data Only
SRVR1WQA\FOnMS\l-RRUNtOQ.DOC (t/23^7)
Transcribed Data
Dated Signature/Initials Required
Page 1
-------
Triangle Laboratories^??
Run Log
Column Type
Column #
Analysis*
Acquisition
Method
GC Method*^
Find DBs*_
Other*
ok&uqz
(P"
C£Xm> I-
-------
Triangle l aboratories, Inc.
Run tog
Column Type
Column §
Analysis*
Acqitlslllon
Method
GC Method*
Find DBs*
Other*
-fHn&fear
cc.ii ivi
— -
———Standards
Jnternal / SJjrroaate t Recoveiv
Internal / Surroaale / Recovery
Analyte
Wo 6
(5) & "3 fcj1 1
*A_
ii/k
Exlracl / Sample volume /in)
rtkliirA *
unll
JtJJ mL
Jato"
Tim#**
Proiaet
Sample#
ciientlO
rilenaruo
JdL
Olierator/Date
Backup*
Proc
Comments"*
42AD&^
»k
tes tx^3
1F5U3
.J# n|^
k; ql*hi
QQ
Hi
/ 4 0*7
Amooc
vH
t<4U&
' W- - Pfc'1 • C
ZJA
IpS^
Wo 1(3/4.7
W
%
MS*
•
4W0DC *
V"W-k*
11 tAUU&K EAAtfiL-
W)
%
1512-
$
eaPW
yp^io
ft? ^41
w
%
1532.
"A-
6514
S£<0GSD
t
W im/ij
w
%
(4*3
430 B*}
%
ICS
; frS72_
14?
w
* Volatile Dala Only ** Transcribed Dala
9RVRnKMVOnMS4.RnUNLOa.DOC 3*ri
Dated Signature/Initials Required
Papa 4*3^-
-------
Triangle Laboratories, Inc.
Run Log
Column Type
Column #
Analysis*
Acquisition
Method
GC Method*
Find DBs*
Other*
Q2S
Standards
Mernal/ Surrogate t Recovery
Internal 1 Surrogate / Recovery
Analyte
tttoc,
SxJ lO l»>J)
%
Extract / Sample volume | Si
PO
Clrcto
2
•y*
'V*
A0Wfo»T
W *1#)
w
fa#)
iPSis
to
l»
/7^
-tao&j
ZJ^VO
^PSTfc
to?
IV
<* r*/ ts. ^i/
W)
tH|*i
fV£5
429?te> '
ftf.'ltlte*
fcUNt
ip5ig
P\ to/c
op f»h(.4i
'iW»i
tr»-n%wtf
WMJ
ypst'i
tip ctlt{(<~j)
D« kAc J IQ/t
OO
429*08
$0^3 '
VC5%D
\XI fNfoi
1W
IHU-ckd lo^
42ft3q&
L-t
4
If&SI
m)
ftf
DO llqM
lllk
42320B
119
: ^fS»z-
ft}
w
\ihU-cWcA »o/
OP
* Volatile Data Only
SRvnt\vc*¥om«\umuM.oo.ooc (insni)
** Transcribed Data
Dated Signature/Initials Required
Page_4H
-------
Triangle Laboratories, Inc.
Run Log
flnternaW Surrogate I Recovery
J I i M
Standards
ATOo Oi
frvJi.
Internal / Surrogate / Recovery
rooat
Analyte
-V/
'A
Extract / Sample volume
l«unlt
mL
* Volatile Data Only ** Transcribed Data
snvRinaA\FORMStt.nRUNLOO.DOC (V2M?)
Dated Slgnature/lnlllais Required
Page
tTo
c~i
CO
Column Type
Column #
Analysis*
Acquisition
Method
GC Method*
Find DBs'
Other*
cc t«<4-. iv>
3ate*«
Tlma"
Project
Sample#
Client ID
Filename
pH*
Operator/Date
Backup*
Proc
Comments***
rMt
0OM'
1P6B
m lUWi
Of
DiImW 106)(
oo 4lqi*n
73V\
4zto&e>
rwrii
tons
^ flltiUl
f '
M
t^VuJU'^ K
v»o
'ty,
©on
1 't '
W 4|i|fo
M
Oi LuJ^cl iOPf<
"5"|
a&
4Z%)0
mm-iu-*
ipssb
w
mutW t-OD/
«to liwfqi
i%i
Ol*M
a/a
Va
3nm!&47 fc>LAWK-
1
ff^S7
V0
%
ow
;
yps%*
W °i\${{n
W
Hi
lB -
62ncj
S5lD05o
fer?
W 1(51*1
W
if .I fili, !¦<
»1
-------
MB flHflBI jhhhb
^WanylWSiboil^Pes, WP
Run tog
Column Type
Column #
Analysis*
Acquisition
Method
GC Method4
Find DBs*
Other*
T>fcS Q>l£
MWa/3
rct(4 0°
Standards
Ctrcteun*
«4waniil^8urrooali 1 Recoverv
Internal 1 Surrogate / Recovery
Analyte
Extract / Sample volume
hL mL
4..YSt| yalfaJ!
Va
JalB"
Wi
1!
%1
linn-
I05D
M
iM.
Project
4 iW£>
4i?im
¦4'yfeofc
Sample#
»yi m-i
m 7Ac^6
Client ID
WK) 1
fr)N3
WM
Uu«^
Filename
1f&~0
i£§2i
Vps^
Mil
Slgnaluta
Oil*
Operator/Dale
it 4^1
Off 'ib(oi
Backup
Proo
Comments*
OiUti my M^oln
* Volatile Data Only " Transcribed Data *" Dated Signature/Initials Required Page d-fyt.
9nvn HWA*ORM94BRUMtOO OCX? (M»f) T*J
-------
I
I
I
I
I
I
I
I
I
^x,
I
I
I
I
I
I
I
I
Project Number: 42930B
Sample File: YP579
Method 8270A MM5
Sample ID: RUN1
Client Pi
TXJID;]
:oj€
L79-
ct: Ire
•98-1.4
Dilution Factor: 20.00
Amount
«*S
FLAG
•::RT
Det Limit
:
Quan. Limit
Naphthalene-dg
IS 2
11.74
Naphthalene
3021,86
B
11.79
200
2-Methylnaphthalene
2500.94
13.21
200
Acenaphthene-d
IS 3
15.35
2-Chloronaphthaiene
17.48
J
14.21
200
Acenaphthylene
214.30
15.05
200
Acenaphthene
128.95
J
15-41
200
Fluorene
262.63
16.49
200
Phenanthrene-d
to
IS 4
18.42
Phenanthrene
1478.60
18.47
200
Anthracene
264.52
18.58
200
Fluoramhene
782.14
20.93
200
Chrysene-d(2
IS 5 High
23.90
Pyrene
350.18
21.40
200
Benzo(a)anthracene
175.06
J
23.89
200
Chrysene
283.24
23.96
200
Perylene-d
IS 6 High
27.64
Benzo(b)fluoranthene
91.76
J
26.60
200
Benzo(k)fluoranthene
26.11
J
26.67
200
Benzo(e) pyrene
43.41
J
27.35
200
Benzo(a) pyrene
21.55
J
27.48
200
Perylene
5-34
J
27.69
200
Indeno(l ,2,3-cd)pyrene
U
2.35
i 200
Dibenz{a,h)anthracene
u
3.2;
i 200
Benzo(g,h,i) perylene
3.43
J
30.98
200
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax; (919) 544-5491
Savar v35
Printed; 09/12/1997
-------
Project Number 42930B
Sample File: YP579
Method 8270A MM5
Sample ID: RUN1
Dilution Factor: 20.00
Amount RT TSRef %KEC
Anthraoene-d 81.52 18.54 4 82
10
Pyrene-d 69.89 21.36 5 70
' 10
Reviewed by
Date ^ I 12-/ f-?
NA- Not Applicable; Det. Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated* Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTF, Inc. Savar v3.5
801 Capitola Drive • Durham, North Carolina 27713 Printed: 16:00 09/12/1997
Phone: (919) 544-5729 • Fax: (919) 544-5491
36
-------
Data File: /chem/Y.i/09-04-97.Li/YP579,d
Date : 04-SEP-1997 19:42
Instrument : Y.i
Sample ID : RUN1
Column phase : DB-5
Volume Injected -0.8-
00
CM
U_
_Q
0.4-
: :c
0.3-
-g
0.2-
0.1-
0.0
-------
Data File: /chetn/Y,i/09-04-97.b/YP579.d
Date : 04-SEP-1997 19:42
Instrument : Y.i
Sample ID : RUN1
Column phase : DB-5
Volume Injected (uL) : 1.0
Trlanglt Uberateriw
o! RTP, Inc.
Column diameter : 0.32
Page 10
GO
CO
/chem/Y,i/09-04-97,b/YP579,d (Part 2 of 2)
>-0.8
CM
"O
I
0/
c
0/
w
3)
1_
-C
(_)
kO
CM
CM
H
T5
3)
i_
-------
Data File: /chem/Y.i/09-04-97.b/YP579.d
Report Date: 05-Sep-1997 07:39
Page 1
TRIANGLE LABORATORIES, INC.
Data file :
Lab. Id. :
Inj Date :
Operator :
Smp Info :
Misc Info :
Comment :
Method :
Meth Date :
Cal Date :
Als bottle:
Dil Factor:
Integrator:
SEMI-VOLATILE QUANTITATION REPORT
/chem/Y. i/09-04-97.b/YP579.d
42930B
04-SEP-1997 19:42 Autotune Date: 06-Sep-99 14:30:1
DD Inst ID: Y.i
RUN1
179-98-1AC-E
/chem/Y. i/09-04-97.b/ccli3t.m
05-Sep-1997 07:30 target
04-SEP-1997 13:32
8
20.000
HP RTE
Sample Type: AIR
Cal File: YP571.d
Target Version: Target 2.20
Compound Sublist: pah.sub
QUANT SI0
ON-COLUMN
FINAL
Compounds
MASS
RT (REL RT)
RESPONSE
( ng)
( ug)
1
1,4-Dichlorobenzene-d4
152.00
9.245(1.000)
600222
40 .00
2
Naphthalan*-d8
136.00
11.745(1.000)
1965821
40 .00
3
Acenaphthene-dl0
164.00
15.346 (1.000)
1291303
40 .00
4
Phenanthrene-dlO
188.00
18.423 (1.000)
2256393
40 .00
5
Chrysene-dl2
240.00
23.904 (1.000)
2323924
40 .00
6
Perylene-dl2
264.00
27.641(1.000)
2876838
40.00
7
2-Fluorophenol
112.00
6.791(0.735)
2509
0.17
3.31UQR)
8
Phenol-d5
99.00
8.592(0.929)
99549
4.56
91.16(aQ)
9
2-Chlorophenol-d4
132.00
9.159(0.991)
1279
0.07
1.48 (aQR)
10
1/2-Dichlorobenzene-d4
152.00
9.589(1.037)
675
0.05
1.01 (aQR)
11
Nitrobenzene-d5
82.0 0
10.307(0.878)
67643
3.70
74.07 (aQ)
12
1,3,5-Trichlorobenzene-d3
185.00
10.989(0.936)
72268
3.98
79.67(a)
13
l,4-Dibromobenzene-d4
239.80
11.853(1.282)
68179
5.91
118.24(a)
14
2-Fluorobipheny1
172.00
13.980(0.911)
191274
4.93
98.59(a)
15
2,4,6-Tribromophenol
329.80
16.992(1.107)
42270
6.39
127.77(a)
16
Anthracene-dlO
188.00
18.540(1.006)
233385
4.08
81.55(aQ)
17
Pyrene-dlO
212.00
21.358(0.893)
274271
3.49
69.87(a)
18
Terpheny1-dl4
244.00
21.783(0.911)
2045
0.05
0.93(aQR)
42
Naphthalene
128.00
11.788(1.004)
6824083
151.15
3023.02
46
2-Methylnaphfchalene
142.00
13.208(1.125)
3920823
125.12
2502.31
50
2-Chloronaphthalene
162.00
14.211(0.926)
30105
0.87
17.48(aQ)
56
Ac enaph thy1ene
152.00
15.050(0.981)
577662
10.72
214.36
58
Acenaphthene
154.00
15.412(1.004)
193161
6.45
128.95(a)
65
Fluorene
166.00
16.491(1.075)
470967
13.13
262.55
73
Phenanthrene
178.00
18.474(1.003)
4412268
73.91
1478.26
74
Anthracene
178.00
18.576(1.008)
734127
13 .23
264.50
77
Fluoranthene
202.00
20.934 (1.136)
1967760
39.11
782.25
78
Pyrene
202.00
21.402(0.895)
1457699
17.51
350.22
83
Benzo(a)anthracene
228.00
23.889(0.999)
533453
8.75
175.06(a)
84
Chrysene
228.00
23.956(1.002)
754503
14.16
283.12
86
Benzo(b)fluoranthene
252.00
26.603(0.962)
307219
4.59
91.74(a)
33
-------
Data File: /chem/Y.i/09-04-97.b/YP579.d Page 2
Report Date: 05-Sep-1997 07:39
COKCBHTftATXOHS
Compound*
87 B*zixo (k) ilxiozmnthmnm
88 Baqzo(•}pyr*n«
89 B*nzo(a)pyr«a«
90 P«ryl«ix«
91 Xnd«no(l,2,3-cd)pyr«n*
92 Dib«nz(a,h) *nthr*c«n«
93 B«nzo (g,fa,i)p«ryl«a«
QC Flag Legend
Q0AKT S10
UKSS
RT CRSL RT)
ON-COLUMN
RESPONSE ( ng)
252.00 Off ** ffmn ar3) f** 4.sa
252.00 27.349 CO.983} 152040 2.17
252.00 27.480£0,994) 69292 1.08
252.00 27.692(1.002) 18137 0.27
a?t.oo-
38.368(1ii96)
¦wwtrwff
G?C8
SfiS
"9. qy
n.m..
276.00
JAW
>».i »?!iii.tati
0.05
a - Target compound detected but, quantitated amount
Below Limit Of Quantitation(BLOQ).
Q - Qualifier signal failed the ratio test.
R - Spike/Surrogate failed recovery limits.
< «g>
91.61(a)
43.39(a)
21.SS(«)
5.35 UJ
*•»«(«*> J/toftj
a.>8<»8)^ 9^ pa*3
• 03 t*Q> {/h)f40
40
-------
Data File: /chetn/Y.i/09-04-97.b/YP579.d
Date : 04-SEP-1997 19:42
Instrument : Y.i
Sample ID : RUN1
Column phase : DB-5
Volume Injected <1.5-:
g2.0
>-1.0-
j1 i -i 'j | i i i j i i i | r" r ¦> j
80 120 160 200 240 280 320 360 400 440
Mass/Charge
Scan 1131 <11.788 min) of YP579.d (Subtracted)
3.5
3.0
2.5
<
2.0
X
1.5
>-
1.0
0.5
0.0-
¦UvO-
40
120 160
i' | 'i i i pn vt "j r
200 240 280
Mass/Charge
-i—I—i—¦—T
T
320 360 400 440
42 Naphthalene (PBM Reference Spectrum)
8.0
.6.0-
ro
^4.0-
2.04
0.0
^ i 11 i I I 1 1 I I I | 1 1—I—| 1 1 1—]—I—I 1—|—I—I 1 | I—T—1 Jill—p
80 120 160 200 240 280 320 360 400 440
Mass/Charge
100
75-3
50
251
£ 0-j-
S-25H
x
-50-j
-75-1
-100-
Scan 1131 (11.788 min) of YP579.d (Z DIFFERENCE)
40
'I 1 1 1 I
... i—r.r
120 160
I 1 ' 1 I 1 1 1 I 1
200 240 280
Mass/Charge
320 360 400 440
11.40 11.60 11.80 12.00 12.20
Time (min.)
Mass 129.00
I 1 1 'T ' ' ' I 1 1 ' i ' 1 1 i
11.40 11.60 11.80 12.00 12.20
Time (min.)
5.0-
4.5-
4.0-
3.5-
^ 3.0-
o 2.5-
X
~2.0-
>-
1.5-
1.0-
0.5-
0.0-
Mass 127.00
-00
00
[ 'I 0 I I T1 T1 I1 "i~? 1 I I'i 11 'I I
11.40 11.60 11.80 12.00 12.20
Time (min.)
J
41
-------
Data File: /chem/Y.i/09-04-97.b/YP579.d
Date : 04-SEP-1997 19:42
Instrument : Y.i
Sample ID : RUN1
Column phase : BB-5
Volume Injected (uL> : 1.0
Column diameter : 0.32
Page 12
46 2-Methy1naphtha1ene
Scan 1328 (13.208 min) of YP579.d
Mass 142.00
b 1.0
21.0
i ¦ ¦ • I
200 240 280
Mass/Charge
Scan 1328 (13,208 min) of YP579.d (Subtracted)
o 1.0
80 120 160 200 240 280 320 360 400 440
Mass/Charge
46 2-Methy1naphthalene (PBM Reference Spectrum)
8.0-
.6.0-
>
!4.oH
2.0-
0.0-
{ I 4 ¦¦ ¦
40
80
120 160
T
' I 1
200 240
Mass/Charge
'i j r i—i | i i i |"
360 400 440 480
100-
75-
50-
25-
: °"
« -25-
-50-
-75-
-100-
Scan 1328 <13.208 min) of YP579.d (2 DIFFERENCE)
40
T
T
T
'"I ' ' ' I
I 11 1 I
T
80 120 160 200 240 280 320 360 400 440 480
Mass/Charge
12.80 13.00 13.20 13.40 13.60
Time (min.)
Mass 141.00
vol.0
i 'i | ni i
12^80 13^00 13i20 13.40 13.60
Time (win.)
d?
-------
Data File: /chem/Y. i/09-04-97.b/YP579.d
Date : 04-SEP-1997 19:42
Instrument : Y.i
Sample ID : RUN1
Column phase : DB-5
Volume Injected of YP579.d
¦» 3.0
120 140 160
Mass/Charge
I 1 1 1
240 260
Scan 1467 (14.211 min) of YP579.d (Subtracted)
1.0-
0.8-;
0.6-
0
.
X
0.4-
>-
-
0.2-
0.0J
40
i—n-
60
I 1
100
I. . I.
120 140 160
Mass/Charge
180 200 220
1 I 1
240
50 2-Chloronaphthalene (PBM Reference Spectrum)
3.0-
~ 6.0-
ro
<
o
34.0-
^2.0-
0.0-
>1.till > .1
40
60
100-
75-
50-
25-
{£ 0-
S-25-
-50'
-75'
-100
Scan 1467 <14.211 min) of YP579.d -1.
0.
0.
0.
I^L!
i
•3
\jy
1 1 ¦ 1 1 < ¦ ¦ 1 ¦ 1
13. SO 14.00 14.20 14.40 14.60
Time
-------
Data File: /chem/Y.1/09-04-97.b/YP579.d Page 14
Date : 04-SEP-1997 19:42
Instrument : Y.i
Sample ID : RUN1
Column phase : DB-5 Column diameter : 0.32
Volume Injected (uL) : 1.0
56 ficenaphthylene
2.8-
2.4-j
2.0-:
S 1.6-
|i.2-i
>- 0.8-;
0.4-:
0.0-
Scan 1583 (15.050 min) of YP579.d
jMJ#
50 75 100 125
I r'' 1 ' I " 1 11 1 " ' 11 " 1 i' 1 " I " 1 11 "
150 175 200 225 250 275 300 325 350
Mass/Charge
Scan 1583 (15.050 min) of YP579.d (Subtracted)
2.4-
2.0-
1.6-j
! 1.2-;
X
>. 0.8-
0.4-
0.0-
i11
I1"1 I 1 1 1 1 I 1 1 1 1 I 1 1 1 1 I 1 ' 1 1 I ' 1 " I ' 1 1 ' I " '
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charge
56 ftcenaphthylene (PBM Reference Spectrum)
8.0-
, 6.0-
ro
^ 4.0-
' ^ 2.0-
0.0-
U
4,
"f i p i i » } i i » i | i » i i } i i i i | i M-i j r r > r p ri t i | » » »
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charge
100-
75-
50-
25-
: 0-
' -25-
' -50-
-75-
-100-
Scan 1583 (15.050 min) of YP579.d (2 DIFFERENCE)
-*-.•—mL —...i.. i. ••*[ ...J
I I I I I I ' I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charge
Mass 152.00
I ' 1 1 I ' 1 1 I 1 ' ' I 1 ' ' I '
14.60 14.80 15.00 15.20 15.40
Time (min.)
Mass 151.00
ro
14.60 14.80 15.00 15.20 15.40
Time (min.)
Mass 153.00
I 1 ' 1 I ' ' 1 I 1 1 ¦ I ¦ 1 ¦ I
14.60 14.80 15.00 15.20 15.40
Time (min.)
44
-------
Data File: /chetn/Y. 1 /09-04-97.b/YP579.d Page 15
Date : 04-SEP-1997 19:42
Instrument : Y.i
Sample ID : RUN1
Column phase : DB-5 Column diameter : 0.32
Volume Injected (uL> : 1.0
58 Acenaphthene
Scan 1633 (15.412 min> of YP579.d
Mass 154.00
1.0
0.9
0.8
1.0-
o
<
o
X
CM
0.2-
0.0
50 75 100 125 150 175 200 225 250 275 300 325 350 375
Mass/Charge
Scan 1633 (15.412 min) of YP579.d (Subtracted)
.0-
15.00 15.20 15.40 15.60 15.30
15.00 15.20 15.40 15.60 15.
Time (min.)
2.0-
hass 152.00
in
0.0
IT)
Scan 1633 (15.412 min) of YP579.d (Z DIFFERENCE)
100 q
75-j
504
25-1
15.00 15.20 15.40 15.60 15.!
Time (min.)
Mass/Charge
-------
Data File: /chem/Y.i/09-04-97.b/YP579.d Pa?e 16
Date : 04-SEP-1997 19:42
Instrument : Y.i
Sample ID : RUN1
Column phase : DB-5 Column diameter : 0.32
Volume Injected (ut) : 1.0
65 Fluorene
Scan 1782 (16.491 rain) of YP579.d
2.4-
2.0-
,1.6-
ID
11.2-
X
;o.s-
0.4-
0.0-
40 80
ill
120
f
160
200 240 280
Mass/Charge
320
r1 pr i t [¦¦¦ r-i i | i
360 400 440
Scan 1782 (16.491 min) of YP579.d (Subtracted)
2.4-
2.0-
1.6-
in
<
O J
X
0.4-
0.0-
1} f.1.1
.L,., . ,1i| ,i|, J.
JU
40
120 160
200 240 :
Mass/Charge
T'J"'r I > | II I | 1
360 400 440
65 Fluorene (P1M Reference Spectrum)
8.0-
<
o
.6.0-
•5 4.0-j
'2.0-
0.0-
4-44^
1—,—|—,—1 1 | 1 1 i | 1 1—1 | 1 1—ijiii—| 1 i j | 1
40 80 120 160 200 240 280 320 360 400 440
liass/Charge
100-
75-
50-i
25r
i °
5-25-
**
-50-
-75-
-100-
Scan 1782 (16.491 min) of YP579.d (2 DIFFERENCE)
>,» jjL,. ¦! 1 — 1. JL >
"i"1"' 1 1 1
40 80
120
T
-n-
160 200 240 280
Mass/Charge
I 1 1—1—|—1 i 1 |"
T
T
320 360 400 440
Mass 166.00
wW\A
1' 1
16.2 16.4 16.6
Time (min.)
Mass 165.00
1.
1.
1.
10 1
O
ifH A
X 1<
>- 0,
0.
0,
0.
0.
.2-.
.o-i
8-i
6-i
4-i
2-i
0
8*3
6
4
2-3
CO
¦9
CD
& ^
CD
" '1 ' ' ¦ I ' 1 ' I"' 1 1 l 1
16.0 16.2 16.4 16.6
Time (min.)
16.8
Mass 167.00
-------
Data File: /chem/Y. i/09-04-97.b/YP579.d Page 17
Date : 04-SEP-1997 19:42
Instrument : Y.i
Sample ID : RUN1
Column phase : DB-5 Column diameter : 0.32
Volume Injected (uL> : 1.0
73 Phenanthrene
Scan 2055 (18.474 rnin) of YP579.d
Mass 178.00
2.2-:
2.0
CO
1.3-
1.6-j
1.4-i
0.4-
LD
CO
0.0
120
160 200 240 280 320 360
Mass/Charge
400
440
Scan 2055 (18.474 min) of YP579.d (Subtracted)
2.0
1.6-
co
2.4-
0.0
2.0-
120
160 200 240 280 320 360
Mass/Charge
400
440
31.6
73 Phenanthrene (PBM Reference Spectrum)
1.2-
0.4-
4.0-
Time (min.)
2.0-
Mass 176.00
0.0
CO
120
160
200 240
Mass/Charge
280
320
360
400
440
Scan 2055 (18.474 min) of YP579.d (Z DIFFERENCE)
100 "q
X
>-
1.2
0.8
0.4
0.0
18.0 18.2 18.4 18.6 18.8
Time (min.)
120
160 200 240 280 320 360
Mass/Charge
400
440
47
-------
Data File: /chem/Y.1/09-04-97.b/YP579.d Page 18
Date : 04-SEP-1997 19:42
Instrument : Y„i
Sample ID : RUN1
Column phase : DB-5 Column diameter : 0.32
Volume Injected : 1.0
74 Anthracene
Scan 2069 <18.576 min) of YP579.d
Mass 178.00
f 1.2-
H
160 200
Mass/Charge
Scan 2069 <18.5/6 mn> of YP579.d -1.0
160 200 240
Hass/Charge
74 Anthracene
Mass 179.00
I ' 1 ' I
160 200 240
Mass/Charge
« -
100-
75-i
50-
25-
• 0-
25-i
-50-
-75-
-100-
Scan 2069 <18.576 min) of YP579.d <2 DIFFERENCE)
'T
T_r.
40
80
120
"T
T_P.
160 200 240
Mass/Charge
1 \ I
280
320
360
3.2-
2.8~
o
¦"ST
OD
-1*2™
in
CD
•ri
0*8-
i
0.4-
J
\A
0.0-
^r-r-r-r-i t t -r-r-r-r
18.2 18.4 18.6
Time
-------
Data File: /chem/Y.i/09-04-97.b/YP579.d
Date : 04-SEP-199? 19:42
Instrument : Y.i
Sample ID : RUN1
Column phase : BB-5
Volume Injected (ul) : 1.0
Column diameter : 0,32
Page 19
77 Fluorarithene
Scan 2392 <20.934 win) of YP579.d
1.0-
0.3-|
0.6-
O
-
X
0.4-
>-
-
0.2-
o.oj
't
| f !" I I l | I l I | I I l | i r i | i i i | i l l | '' l | l
200 240 280 320 360 400 440 480 520
Mass/Charge
40 80 120 160
Scan 2392 (20.934 min) of YP579.d (Subtracted)
1.0-
0.8-
3 0.6-
<
o
3o.4-
>-
0.2-
0.0-
'f f
¦¥ f ikr
i1 i j—r-5—r-|—i—t'l ; i i—j | i i i j t i r | i i—i | i—i i ""| )—r-
40 80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
77 Fluoranthene (PBH Reference Spectrum)
8.0
, 6.OH
r-o
^ 4.0-
2.0-
0.0
40
120 160 200
240 280 320 360
Mass/Charge
400 440 480
100-3
75-j
50-1
25-i
g. o-j--
® -25-;
-
"50":
-75 4
-100
Scan 2392 <20.934 min) of YP579.d <2 DIFFERENCE)
¦n-
40
i i ^ i i i | * i'-f i j i i i | i i i t i i i ( i i i j i i i j1 i t i | t i i | i i i | i—t i | i—p-
80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
2 0.5
Mass 202.00
I 5?
o
CM
o
CM
CM
O
•rr
ij
i i i ( ir i i" "r"i i
20.60 20.30 21.00 21.20 21.40
Time (min.)
Mass 101.00
«H.O
r I 11 i 11—J—s—i I I i : i j i I I }
20.60 20.80 21.00 21.20 21.40
Time (min.)
Mass 100.00
1.4-n
s
as
1*2-;
1.0-J
0.8-
in
O "
3 0.6-
1
o
A
20.634
0.2-
A
0.0:
20.60 20.80 21.00 21.20 21.40
Time (min.)
43
-------
Data File: /chem/Y.i/09-04-97.b/YP579.d
Date : 04-SEP-1997 19:42
Instrument : Y.i
Sample ID : RUN1
Column phase : DB-5
Volume Injected (uL> : 1.0
Column diameter : 0.32
Page 20
78 Pyrene
Scan 2456 (21.402 min> of YP579.d
Mass 202.00
<*0
S 0.5
" 1 i 1 1 1 1 1 1 i 1 1 1 I 1 1 1 I 1 1 1 i 1 1 1 i 1
120 160 200 240 280 320 360 400
Mass/Charge
Scan 2456 (21.402 min> of YP579.d (Subtracted)
21.00 21.20 21.40 21.60 21.80
Time (min.)
Mass 101.00
78 Pyrene (PBM Reference Spectrum)
i . . . | i i i | i . i | i i i |
21.00 21.20 21.40 21.60 21.
Time (win.)
x 4.0-
Mass 100.00
80 120 160 200 240 280 320 360 400 440 480
Mass/Charge
Scan 2456 (21.402 min) of YP579.d (Z DIFFERENCE)
21.00 21.20 2U40 21^60 2l!80
Time (min.)
50
-------
Data File: /chem/Y.i/09-04-97.b/YP579.d Page 21
Date : 04-SEP-1997 19:42
Instrument : Y.i
Sample ID : RUN1
Column phase : DB-5 Column diameter : 0.32
Volume Injected (uL) : 1.0
83 Benzo(a)anthracene
Scan 2795 <23
min> of YP579.d
Mass 228.00
CM
5.0
1.8
1.0
CD
Scan 2795 <23.889 min> of YP579.d (Subtracted)
0.2
23.40 23.60 23.80 24.00 24.20
Time (min.)
Mass 229.00
0.5
4.0-
Mass/£har2|_
83 Benzo(a)anthracene (PBH Reference Spectrum)
T-i
><3.0
00
2.0
1.0-
6.0-
r^o
0.0
4.0-
23.40 23.60 23.80 24.00 24.20
Time (min.)
2.0-
tlass 226.00
0.0
CM
Scan 2795 (23.889 min) of YP579.d (Z DIFFERENCE)
CM
6.0
100-3
2.0
1.0-j
0.0
23.40 23.60 23
24.00 24.20
Mass/Charge
51
-------
Data File: /che»/Y,i/09-04-97.b/YP5?9.d
Date : 04-SEP-1997 19:42
Instrument : Y.i
Sample ID : RUN1
Column phase : DB-5
Volume Injected : 1.0
84 Chrysene
Page 22
Column diameter : 0.32
I
I
I
Scan 2804 (23.956 mm) of YP579.d
2.8-
2.4-3
2.0-
^1.6-i
o n
^1.2-
200 240 280
Mass/Charge
320 360
I 1 11 I
400 440
Scan 2804 <23.956 nun) of YP579.d (Subtracted)
2.0
1.6
m
<
o
1.2
0.8
>•
0.4
0.0
40
80
f-
T
'i11 f 'i* i "i *:—^ i * i j ' 'i' i—r—j—t r i—j—i—r—i—j—i
120 160 200 240 280 320 360 400 440
Mass/Chanre
84 Chrysene | ' i i | i i i | ) ' i j i i i ; i i i | i i i j i
120 160 200 240 280 320 360 400 440
Mass/Charge
Mass 228.00
< 1.5
>•1.0
23.60 23.80 24.00 24.20 24.40
Time (min.)
Mass 226.00
23.60 23.80 24.00 24.20 24.40
Time
-------
Data File: /chem/Y.1/09-04-97.b/YP579.d
Date : 04-SEP-1997 19:42
Instrument : Y.i
Sample ID : RUN1
Column phase : DB—5
Volume Injected (uL) : 1.0
Column diameter : 0.32
Page 23
86 Benzo(b)fluoranthene
Scan 3165 (26.603 min> of YP579.d
Mass 252.00
o 4.0-
m
160 200 240
Hass/Charge
Scan 3165 (26.603 min> of YP579.d (Subtracted)
6.0-:
5.0-:
-rT
4.0H
0
3.0H
X
2-°i
«
O
0.0-3
1
40
L-f~-r
4-1' 'i"1! 'f ''vff V
80 120 160 200 240
Mass/Charge
4w4
280
320
i' )'"| !¦ i
360
400
86 Benzo(b>fluoranthene (PBM Reference Spectrum)
8.0-
6.0-
r>o
34.H
^ 2.0-
0.0-
i
40
80
120 160 200 240
Hass/Charge
280
320
i—1—1-
360
400
100-
75-
50-
25-
£ 0-
= -25-
-50-
-75-
-100-
Scan 3165 (26.603 min) of YP579.d (Z DIFFERENCE)
— .... .JL. IJ ..
I
40
I 1
80
i—[—1—1—1—j—1—1—1—|—1—1—1—j—1—1—1—j—1—1—1—|—1—1—1—|—1—1 1 |
120 160 200 240 280 320 360 400
Hass/Charge
-]—1—1—!—]—1—1—1—|—1—1—1—|—r-
26.20 26.40 26.b0 26.30 27.00
Time (min.)
Mass 253.00
>- 0.6
-pi—1—r—]—t—i—1—pi—r-i—| 1 1—1—[-
26.20 26.40 26.60 26.80 27.00
Time (min.)
Mass 125.00
1 1 I 1 1 1 I 1—1—1—p
26.20 26.40 26.60 26.80 27.00
Time (min.)
53
-------
Bata File: /che^.i/09HJ4-97.b/YP579.d
Date I 04-SEP-1997 19;42
Instrument : Y.i
Sample 10 : RUN1
ColuMn phsse : BB-5
Volume Injected fluoranthene
Page 16
CoIumd diameter : 0.32
!
I
I
Scan 3174 (26.669 nin> of YP579.d
Hass 252.00
>"i.0-f
Scan 3174 (2b»669 min) of YP579^d (Subtracted)
j—i t i { i » « ] i i i | i i i |
26.20 26.40 26.60 26.80 27.00
Tine (win.)
Mass 253.00
*0.6-
>-0.4
a 0.8
87 Benzo-U0-.
! I | I I I j I I I | I 1 I | I
26.20 26.40 26.60 26.80 27.00
Tine
54
-------
Data File: /chem/Y.i/09-Q4-97.b/YP579.d
Date : 04-SEP-1997 19:42
Instrument : Y.i
Sample IB : RUN1
Column phase : DB-5
Volume Injected : 1.0
Column diameter : 0.32
Page 25
88 Benzo-
1.0-
0.0-
40
LuilfJ
«.l.» l
160 200 240
Mass/Charge
280
320
-f-V-i—J—t
360
Scan 3267 <27.349 min) of YP579.d (Subtracted)
4.0-
3.0-:
<
"
r—<
X
2.0^
>-
:
1.0-j
0.0
^ItL
Ullll^l hi,11 I.till)
40
80
120
160 200 240
li ass/Charge
+4^
280
7—[—I
320
88 Benzo
-------
Data File: /chem/Y.i/09-04-97.b/YP579.d Page 26
Date : 04-SEP-1997 19:42
Instrument : Y.i
Sample ID : RUN1
Column phase : DB-5 Column diameter : 0.32
Volume Injected - :
0.4-
0.0-
.» 'ifi '[y-*;. ¦
f-W
40 80 120 160 200 240 280 320 360 400
Mass/Charge
440
89 Benzo(a)pyrene -
2.0-
0.0-
il
I I I
T
| I I—I—[¦—I—I T |—I 1 I |
40 80 120 160 200 240 280 320 360 400
Mass/Charge
»¦¦¦ r1
440
100-
75-
50-
25-
: °"
<=>-25-
**
-50-
-75-
-100-
Scan 3285 (27.480 min) of YP579.d <2 DIFFERENCE)
.iJa. l i I J "l-i u >hbl ¦
M ...
-r—!—|—i r i i i 1 i i
l—i—i—j—j—i—i i |—i—i—r-p-i—i i |—iii[
40 80 120 160 200 240 280 320 360 400
Mass/Charge
Mass 252.00
4.8
4.4-
4.0
3.6
3.2
2.8
2.4
2.0
1.6
1.2
0.8
0.4
0.0
27
CM
CT»
kO
CM
1 ' ' ' I ' 11 I ' ' ' 1 ' ' ' I
.00 27.20 27.40 27.60 27.80
Time (win.)
Mass 253.00
i r i1 ( i ' 1 1—i ' j ' ' i |
'.00 27.20 27.40 27.60 27.80
Time (win.)
! ) 1 >
440
Mass 125.00
"*!' '!¦<'» | I » i | i—i—i | 'i i r |
27.00 27.20 27.40 27.60 27.80
Time (win.)
56
-------
Data File: /chem/Y.i/09-04-97.b/YP579.d
Late : 04-SEP-1997 19:42
Instrument : Y.i
Sample ID : RUN1
Column phase : DB-5
Volume Injected (uL) : 1.0
Column diameter : 0.32
Page 27
90 Perylene
Scan 3314 (27.692 min) of YP579.d
2.3
2.4-
2.0-|
: 1.6-E
j 1.2-|
¦ 0.8-.
0.4-;
0.0
II
m1'.' f"l "l 'I 1
40 30 120 160 200 240
Mass/Charge
7.0-i
6.0-i
5.OH
4.0-j
3.0-j
2.0-j
1.0-j
0.0J
40
8.0-
.6.0-
ro
<
o
34.0-
^ 2.0-
0.0
1—
40
100-
75-
50-
251
t oJ
3-25-
-50-
-75-i
-100 J
280
320 360
400
Scan 3314 (27.692 min) of YP579.d (Subtracted)
120
HUr4-
aHJI I
160
200 240
Mass/Charge
280
320
360
400
90 Perylene (PBM Reference Spectrum)
'¦ * J I'"'1 ' 1 1 ¦' ' ' 1 ' I '' '
| I I I | I I I | I I 1 | I I
120 160 200 240 280 320 360 400
Jjg§§/£hangg_
Scan 3314 (27.692 min) of YP579.d (% DIFFERENCE)
J > I.I J. .ill u r I J J- LillliJj.1 1 L .11 Jil jI _.i L
Ijll.L. ji 1 11 11
I I
| r r t f i 1 1 | T" j ¦ r 11 j 1 1 i i" | 1 r* r '| !—i r,,,| ¦ r-r "r" | i i r p—r"i i | i
40 80 120 160 200 240 280 320 360 400
Mass/Charge
Mass 252.00
4,
4,
4.
3.
3,
£2,
S2.
*2.
^1.
1.
0.
0,
0.
a-.
4-!
0-!
64
2i
8-i
4-i
0-i
6 -j
2 4
4-i
0-^£
27.2
o
QO
A
"T *
27.4 27.6 27.8
Time (min.)
23.0
Mass 253.00
27.2 27.4 27.6 27.8 28.0
Time (min.)
57
-------
Data File: /che*/Y.i/09-04-97.b/YP579.d
Date : 04-SEP-1997 19:42
Instrument : Y.i
Sample ID : RUtt
Column phase : DB-5
Volume Injected •
160 200 240
280
320
360
400 ~
93 Benzo(g,h,i)perylene (PBH Reference Spectrum)
2.0-
0.0 "^ | i 'i i* | f i'^i—i—J—i i i—| 'i r i—| *i i i i i | i i i | i—i i | i
40 80 120 160 200 240 280 320 360 400
Hass/Charge
100-q
75-j
50-j
25-j
: 0 -j
«-25-i
**-50-i
-75-1
Scan 3767 (30.979 min) of YP579.d (Z DIFFERENCE)
JliiUlliuiljjlLlllii
V
iniii i
-1(B i i ii |
¦ i ¦ ¦ ¦ i ¦ ¦ ¦ i » ¦' i ¦' ¦i '¦ ¦ i * ¦ ¦ i ¦ ¦ ¦ i ¦
40 80 120 160 200 240 280 320 360 400
Hass/Charge
Mass 276.00
30.60 30.80 31.00 31.20
Time (win.)
Mass 138.00
81.5-
30.60 30.80 31.00
Tine (win.)
31.40
Mass 277.00
s-0.6-
' P | 1 I 1 | ¦ ¦ ¦ i ¦ • ¦ i
30.60 30.80 31.00 31.20 31.40
Tine (win.)
53 |
-------
Eastern Research G roup
Project Number 42930B Method 8270A MM5
Sample File: YP578 Sample ID: RUN2
TU ID: I79-98-2AOE
Steel-Yt
Date Received:
Da£e Extracted;
Date Analyzed
08/25/97
: 09/04/97
Respti
mse
Dilution Factor: 20.00
Anaiyte
Amount FLAG
RT
Defc Limit
Quan. limit
Qg
tig
Naphthalene-dg
Naphthalene
2-Methylnaphthalene
Acenaphthene-dio
2-Chloronaphchalene
Acenaphthyiene
Acenaphthene
Fluorene
Phenanthrene-d
10
Phenanthrene
Anthracene
Fluoranthene
Chrysene-d
Pyrene
Benzo(a)anthracene
Chrysene
Perylene-d^
Benzo(b)fluoranthene
Benzo(k) fl uoran the ne
Benzo(e) pyrene
Benzo(a)pyrene
Perylene
Indeno( 1,2,3-cd)pyrene
Dibenz(a,h)anchracene
Benzo(g,h ,i) perylene
IS 2
1395.59 B
1144.50
IS 3
U
90.66 J
50.32 ]
112.49 J
IS 4
679.06
114.34 J
285-67
IS 5
175.13 J
68.54 J
112.78 J
IS 6
34.80 J
11.72 J
16.20 J
8.18 J
U
U
u
u
11.74
11.79
13.21
15.35
15.05
15.41
16.49
18.42
18.47
18.58
20.93
23-90
21.39
23-89
23.94
27.64
26.60
26.67
27.36
27.48
5.99
5.09
4.06
5-62
4.49
200
200
2»0
200
200
20!)
200
200
200
200
200
200
200
200
200
200
200
200
200
200
NA- Not Applicable; Dei Limit: Detection Limit; Quart. Limit: Quantitation Limit
IS: Internal Standard; V: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTP, Inc. Savar v3.5
801 Capitola Drive • Durham, North Carolina 27713 Printed: 15-38 09/12/1997
Phone: (919) 344-5729 • Fax: (919) 544-5491
-------
t EastonReseardj Gfoap!
Project Number 42930B
Sample File: YP578
Method 8270A MM5
Sample ID: RUN2
Client Project Iron & Steel-Yt
TLI ID: 179-98-2AC-E
Date Received: 08/19/97
Date Extracted: 08/25/97
Date Analyzed: 09/04/97
Response File: YP571
Dilution Factor: 20.00
Surrogate Summary
Amount
RT
ISRef
. %KEC
in g>
Anthracene-d
10
81.00
18.54
4
81
Pyrene-d
' 10
79.33
21.35
5
79
(PcoQ,
_ Date
Reviewed by
NA- Not Applicable; Det. Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTP, Inc. Savar v3.5
801 Capitola Drive • Durham, North Carolina 27713 Printed: 15:38 09/12/1997
Phone: (919) 544-5729 • Fax: (919) 544-5491
60
-------
Data File: /chem/Y.i/09-04-97.b/YP578.d
Date : 04-SEP-1997 18:55
Instrument : Y.i
Sample ID : RUN2
Column phase : DB-5
Volume Injected (uL) : 1.0
Triangle UbomforlM
o IRTP, ino.
Page 9
Column diameter
0.32
CD
1.8-
1.7-;
1.6-;
1.5
1.4-
1.3^
1.2:
i.l:
l.o-f
Lo.9^
X
^0.8-
0J-_
0.6
0.5-
0.4-
0.3
0.2
0.1
0.0
/chem/Y.i/09-04-97.b/YP578,d (Part 1 of 2)
','f 'pijiii'iAii
ro
o
ro
Oi
c
Oi
N
C
Qj
.£3
O
1_
4->
ro
-a
i
Oj
c
Oi
N
c
Hi
_Q
O
L.
O
"•J1
"•J1
r>-
oo
oo •
10 Ji
_ca>
•Pf
ft
o
00
3)
c
Qj
.c
Q_
•H
_Q
O
L.
O
3
O
in
K)
-a
i
-
.c
Q.
155
a o
o
ON
ON
o
c
Hi
-C
Q.
O
£
O
_Q
10 11
Time (min«)
-------
Data File: /chem/Y.i/09-04-97.b/YP578.d
Date : 04-SEP-1997 18:55
Instrument : Y.i
Sample ID : RUN2
Column phase : DB-5
Volume Injected -0.8-
0.7-
0,6-
0,5-
0.4-
0.3-
0.2-
O.l-j
0.0
m
CM
B S
ri
~Hi CM
I f
Si p
p
I;
—J—V
19
I—i—r—r—r
21
/chem/Y,i/09-04-97 ~b/YP578~d (Part 2 of 2)
o
o
OS
m
cm
CM
*
c
d>
w
3>
t-
.c
o
I '
23
I ' 1 ' ' I
25 26
Time (min«)
¦t——i—t—r—
—I—»—»—r-
I
20
22
24
27
28
29
30
31
32
-------
Data File: /chem/Y.i/09-04-97.b/YP578.d
Report Date: 05-Sep-1997 07:37
Page 1
TRIANGLE LABORATORIES, INC.
Data file :
Lab. Id. :
Inj Date :
Operator :
Smp Info :
Misc Info :
Comment :
Method ;
Meth Date :
Cal Date :
Als bottle:
Dil Factor:
Integrator:
Sample Type
SEMI-VOLATILE QUANTITATION REPORT
/chem/Y.i/09-04-97,b/YP578.d
42930B
04-SEP-1997 18:55 Autotune Date: 06-Sep-99 14:30:1
DD Inst ID; Y.i
RUN 2
179-98-2AC-E
/chem/Y.i/09-04-97.b/cclist.m
05-Sep-1997 07:30 target
04-SEP-1997 13:32
7
20.000
HP RTE
AIR
Cal File: YP571,d
Target Version: Target 2.20
Compound Sublist: pah.sub
CONCENTRATIONS
QUANT SIQ
ON-COLUMN
FINAL
Compounds
HASS
RT CREL RT)
RESPONSE
t sg)
( ug)
~
1
1,4-Dichlorob*nz«n*-d4
152.00
9.244 CI.000}
585825
40.00
*
2
Naphthalan*-d8
136.00
11.744 (1.000)
1845208
40.00
*
3
Ac*naphth«>n*-dlO
164,00
15.350 (1.000)
1251771
40.00
*
4
Ph*nanthr*n»-dl0
188.00
18.423 CI.000)
192S243
40.00
*
5
Chrysan«-dl2
240.00
23.900 CI.0003
1360616
40.00
*
6
P*ryl*n*~dl2
264.00
27.637 (1.000)
1664422
40,00
$
7
2 - Fluoroph*no 1
112.00
6.866(0.743)
676
0.05
0.91UQR)
$
8
Ph«nol-d5
93.00
8.586 (0.929)
96612
4.53
90.64 UQ)
$
9
2-Chloroph*nol-d4
132.00
9.172(0.992)
403
0.02
0.48 UQR)
$
10
1,2-Dichlorob*ni«n«-d4
Compound Not D«t*ct*d.
$
11
Nitrob*ns*a*-d5
82.00
10.310 E0.878)
84722
4.94
98.83(a)
$
12
1,3,5-Trichlorob*ai*a«-d3
185.00
10.991(0.336)
61114
3.59
71.78(a)
$
13
1,4-DibT
-------
Data File: /chem/Y.i/09-04-97.b/YP578.d
Report Date: 05-Sep-1997 07:37
Page 2
Compound#
87 B«nzo(k)£luoranth«n«
89 B«azo(•)pyr*n«
89 B«nzo
-------
Data File: /chem/Y.i/09-04-97.b/YP578.d
Date : 04-SEP-1997 18:55
Instrument : Y.i
Sample ID : RUN2
Column phase : DB-5
Volume Injected (uL) : 1.0
Column diameter : 0.32
Page 11
42 Naphthalene
Scan 1151 (11.787 min) of YP578.d
Mass 128.00
o 0.8-
240 280 320
Mass/Charge
Scan 1151 (11.787 min) of YP578.d (Subtracted)
1.6-j
1.4-1
i.2-=
csi-o-j
o0.8:
-0.6-1
^ 0.4-1
0.2-1
0.0-='
rri'y i i i j it i" j i i"i' | »¦¦¦» » | i i i j » i i j v r » i t > ;
' ¦ ¦ I ¦
40 80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
42 Naphthalene (PBM Reference Spectrum)
8.0-
.6.0-
>
\ 4.0-
'2.0-
0.0-
V
40 80
i k . 1
r-i"p'r r1 r | ^ r r'y i i » j i i i |' i—r r j r i i | i i i | i ttjt i i j i i i j i i i—p-r
120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
100-q
75 t
50 i
25-1
£ °i
S-25H
X
-50 i
-75-i
-100
Scan 1151 (11.787 min> of YP578.d (2 DIFFERENCE)
40
—i—| i i—i—j—i—i i j i—i—i—j—r-i—i—j—i—i—i—|—
T
T
-i—i—i—r—i—i—r
T
120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
0.0 Vr^ iii | t l*i
11.4 11.6 11.8 12.0 12.2
Time (min.)
Mass 129.00
~1.0
11.4
11.6 11.8
Time (min.)
12.0 12.2
2.4-
2.2
2.0
1.8
1.6
^ 1.4'
Ln
fel.2'
31.0
>-0.8
0.6
0.4
0.2
0.0
Mass 127.00
11.4
r-i ¦ r^*T r
11.6 11.8
Time (min.)
T1 I | f I I |" I 1
12.0 12.2
63
-------
Data File: /chem/Y.i/09-04-97.b/YP578.d
Date ; 04-SEP-1997 18:55
Instrument : Y.i
Sample ID : RIIN2
Column phase : DB-5
Volume Injected i | i « i j t i"q,n i { i i
40 80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
40 80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
Mass 142.00
-2
8.
7.
6.
ID e
< 5*
o *
t-4
>- _
CM
ro
o
-ST
N")
¦f-yV'i" i i t | <"rMt | r'r"f| i i t | "i ; » | t t » j i i i \ i i > \ i iff * i""i
40 80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
Scan 1349 (13.210 min) of YP578.d
<
o J
X
>- 3,
•°i
.o-i
.0-
.0-
0-
0-
CM
fo
T
T
12.8 13.0 13.2
Time (min.)
AW
13.4 13.6
6^
o
-------
Data File: /chern/Y. i/09-04-97.b/YP578.d
Date ; 04-SEP-1997 18:55
Instrument : Y.i
Sample ID : RUN2
Column phase : DB-5
Volume Injected (uL> : 1.0
56 Acenaphthylene
Page 14
Column diameter ; 0.32
Scan 1605 <15.054 rnin) of YP578.d
.2
.0-3
ID
s°
X
~0
1
1
0.
6-3
4
0.2
0.0
40 80 120 16C
I 1 1 ¦' 'i 1 11 1 I 1 ' 1 l ' >' 1 i 1 1 1 i 1 1 ' I 1 1 ' l 1 ' '"""i 1
80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
Scan 1605 <15.054 win) of YP578,d Subtracted)
1.2-j
i.o-:
^0.8~
in
o0.6^
0.2-
0.0-
U-
ijliM
40
i, ij. M I !—)¦ f |—,—r-r-j—r—i—r—pi—r~
I ' '' ' I ' ' ' I ' ' 1 I ' ' ' I ' 1 ' I '
80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
56 Acenaphthylene -
2.0-
0.0-
40 80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
100-
75-
50-
25-
£ 0-
«-25-
-50-
-75-
-100-
Scan 1605 <15.054 nin) of YP5?8.d <2 DIFFERENCE)
r ' * • i
i 1 1 1 i
- ^ > J l') V J f*l » T ) I I' I' j I I I [ l"l I | I I I | 'I I "t i j l I 1 l l j—f I 1 I i I I I I
I ¦' ' ' I ' I | I I I | ' 1 M 1 ' ' I 1 ' ' I ' ' ' I
40 80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
rutss 152.00
fX.
14.60 14.80 15,00 15.20 15.40
Time (win.)
Mass 151.00
14.80 15.00 15.20
Time (min.)
Mass 153.00
3 CD
o 3.0
14.60 14.80 15.00 15.20 15.40
Time (miri.)
67
-------
Data File: /chem/Y.i/09-04-97.b/YP578.d Page 15
Date : 04-SEP-1997 18:55
Instrument : Y.i
Sample ID : RUN2
Column phase : DB-5 Column diameter : 0.32
Volume Injected (uL) : 1,0
58 Acenaphthene
Scan 1655 <15.415 min) of YP578.d
-3.0
x 2.0-
iWi",
200 240 280 320
Mass/Charge
360
400 440 480 520
Scan 1655 <15.415 min) of YP578.d (Subtracted)
4.0-j
3.5-1
3.0-j
. 2.5-j
o 2.0-1
Sl.5-j
^1.0-j
0.54
0.0
r+-
40
80
-+-r*V+-
120 160 200
240 280 320
Mass/Charge
-+-
360 400 440
1 I 1 1 1 I 1
480 520
58 Acenaphthene (PBM Reference Spectrum)
8.0-
. 6.0-
ro
34.0-1
|9~2.o-
0.0
11*1 *11' 11 ^11
T1-
40
| I I t | I !!{ I 1 I | I I I |
1—1—I—J—1—1—;—r
80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
100 ^
75-i
50-j
25-i
t °r
= -25-!
-50-j
-75-i
-100
Scan 1655 <15.415 min) of YP578.d (Z DIFFERENCE)
j, , .. .1.-1
J
1 • ¦ • 1 ¦ ¦ • 1 • • ¦ 1 ¦ • • 1 • ¦ • 1 ¦ ¦ ¦ 1 ¦ 1 1 1 ' 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1
40 80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
Mass 154.00
—in
If rO rn
LDlO
15.00 15.20 15.40 15.60 15.30
Time (min.)
Mass 153.00
—i" 1 « | 1 -ri"p 1 1 |
15.00 15.20 15.40 15.60 15.80
Time (min.)
Mass 152.00
Lf?in
I ' 1 ' I ' 11 I 11 1 I ' 11 I
15.00 15.20 15.40 15.60 15.80
Time (min.)
63
-------
Data File: /chem/Y.i/09-04-97.b/YP57S.d Page 16
Date : 04-SEP-1997 18:55
Instrument : Y.1
Sample ID : RUN2
Column phase : DB-5 Column diameter : 0.32
Volume Injected (uL) : 1.0
65 Fluorene
Scan 1804 (16.491 min) of YP578.d
1.0-
0.8^
in
<
0 6-
0
X
0.4-
>
-
0.2-
0.0^
f-T-r-r-
1 1 | ' 1 i | 1 1 1 I 1 1 1 I 1 r
40 80 120 160 200 240 280 320 360 400
Mass/Charge
Scan 1804 (16.491 min) of YP578.d (Subtracted)
1.0-
0.8-|
0.6-
O
.
X
0.4-
>
-
0.2-
0.0^
,til|l ii^in.1,11 .fl|, ,1| ..1.1
t-4
40 80
r | > "i i | i i r |" "i'"i i • j' ii i—| I i i 1 j1 r
120 160 200 240 280 320 360 400
Mass/Charge
65 Fluorene (PBM Reference Spectrum)
8.0-
^ 6.0-
ro
§4.0-
>-
2.0-
0.0-
'l I' ,< i'j", , , 1
I ' ' 1 I
t—i—i—|—i—r-
1 I1 ' 1 | | ¦ 1 1 | 1
40 80 120 160 200 240 280 320 360 400
Mass/Charge
100-
75-
50
25
0
S-25
x
-50
-75
-100
Scan 1804 (16.491 min) of YP578.d (Z DIFFERENCE)
f . , ... | ...
1—1-1—r-|—1 1 1 |—1 1 1—|—1—1—1—| 1 1 1 | 1 1—1—|—1 1 1—|—1—1—1—|—1 1 1—|—1—1—r-
40 80 120 160 200 240 280 320 360 400
Mass/Charge
Mass 166.00
1 1 1 1 1
16.00 16.20 16.40 16.60 16.S
Time (min.)
Mass 165.00
o->
16.00 16.20 16.40 16.60 16.80
Time (min.)
Mass 167.00
1 1 ' I 1 1 1 I 1 ' 1 I 1 1 1 I
.00 16.20 16.40 16.60 16.80
Time (min.)
63
-------
Data File: /chetn/Y.i/09-04-97.b/YP578.a Page 17
Date : 04-SEP-1997 18:55
Instrument : Y.i
Sample ID : RUN2
Column phase : DB-5 Column diameter : 0.32
Volume Injected (uL) : 1.0
73 Phenanthrene
Scan 2077 (18.467 min) of YP578.d
I"1—T ; I I 1 > I 1 I 1 I
80 120 160 200 240 280 320 360 400 440
Mass/Charge
Scan 2077 <18.467 min) of YP578,d (Subtracted)
3.0-
6.0-
4.0-
2.0-
0.0-
f-t-
40
il
* | 1 I I | ! ! I | ! ! ! j I I I J I !—I | I I I J—! I""
120 160 200 240 280 320 360 400 440
Mass/Charge
73 Phenanthrene (PBM Reference Spectrum)
8.0-
.6.0-
<
o
154.0-
2.o:
0.0-
LH-
40
iM S ¦ I -I I !¦
80
*t t f'
120
-r-r
160
I { ! I I j 1 1 I
200 240
Hass/Charge
320
i" i i '"j-r1
360
1 | I I I | 1
400 440
100 r
75-i
50-
25-
: °"
S-25-i
-50r
-75-
-100-
Scan 2077 (18.467 min) of YP578.d <2 DIFFERENCE)
r-r"
40
'"I 1 ' r1 1 ¦ i "* 11 I ¦ 1 1 i 1 ' 1 i 1 ' 1 i ¦ ¦ ' i ¦ i"1 ¦
120 160 200 240 280 320 360 400 440
Hass/Charge
(lass 178.00
9.0-d
T
8.0-1
CO
—H
7*°i
6.0-1
[q 5.OH
§4.0 J
in
3.0-d
2.0-3
in
00
rH
1
1.0-1
A
ITT
O
O
18.00 18.20 18.40 18.60 18.80
Tine (min.)
Mass 179.00
5 0.6-
1 ' 1 1 I ' ' ' I 1'1 1 I
18.00 18.20 18.40 18.60 18.8
Time (win.)
1.6-
1.4-
1.2-
^1.0-
S 0.8-3
>- 0.6-
0.4^
0.2:
0.0
Mass 176.00
-*ar
CO
ID
r«-
GO
t-4
r
rT-rf
18.00 18.20 18.40 18.60 18.80
Time (win.)
70
-------
Data File: /chetn/Y.i/09-04-97.b/YP578.d
Date : 04-SEP-1997 18:55
Instrument : Y.i
Sample ID : RUN2
Column phase : DB-5
Volume Injected (uL> : 1.0
Column diameter : 0.32
Page 18
74 Anthracene
Scan 2092 (18.575 mm) of YP578.d
Mass 178.00
"P 0.8-
x 0.6-
0.4-
i 1 * 1 i 1 i 1 i 1 1 1 i 1 '* I
120 160 200 240 280 320 360
Mass/Charge
440 480
Scan 2092 (18.575 min) of YP578.d (Subtracted)
18.20 18.40 18.60 18.80 19.00
Time (min.)
Mass 176.00
u
200 240 280
Mass/Charse
74 Anthracene (PBM Reference Spectrum)
hfwTr^V' I ' 1 1 I ' 11 I • • ¦ i
18.20 18.40 18.60 18.80 19.00
Time (min.)
Mass 179.00
a
200 240 280
Mass/Charge
Scan 2092 (18.575 min) of YP578.d (Z DIFFERENCE)
° -25
i | i—i—i—p r i i | i
18.20 18.40 18.60 18.80 19.00
Time (min.)
i 1 1 1 I
120 160
i r j1 r - T r r 1 ' ' i ' * • i *
320 360 400
I 1 ' 1 I 1
440 480
200 240 280
Mass/Charge
71
-------
Data File: /chem/Y.i/09-04-97.b/YP578.d
Date ; 04-SEP-199? 18:55
Instrument : Y.i
Sample IB : RUN2
Column phase : DB-5
Volume Injected CuL) : 1.0
77 Fluoranthene
Page 19
Column diameter : 0.32
I
I
I
3.2-
2.8-
2.4-
,2.0-
isi .
o ^
31-2"
>"0.8-
0.4-
Scan 2417 <20.933 min) of YP578.d
40
0.0 'I I j' ;*1 f" t" f v ¦) i i i | r i i
1 I < j I t I j I I 1 j I t l—| I I ! | I I
120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
Scan 2417 (20.933 nn) of YPS78.d (Subtracted)
2.8
2.4-i
.2.0-:
jl.6-
Sl.2-f
=~o.e-;
0.4--
0.0
40 80
rT*
120
4_
f-> "T t
160 200
I I | I I V") I
240 280 320
Mass/Charge
-T-J-T-
360
400
_ri_r.
440
480
1 i 1
520
77 Fluor anthene (PBM Reference Spectrum)
8.0-
.6.0-
ro
<
o
^4.0-
2.0-
0.0-
J
4V ' W ' 120 ' 160 ' *200 ' 240 ' 280 ' 320 ' 360 ' 400 ' 440 ' 480 ' 520
Hass/Charge
100-
75-;
50-j
25i
: °1
* -25-j
'-SOi
-75-=
-100-
Scan 2417 <20.933 Bin) of YP578.d (Z DIFFERENCE)
t
"T
T
T J H1 1 | I I T"J
40 80 120 160 200 240 280 320 360 400 440 480 520
Hass/Charge
5.0-
4.5-
4.0-
3.5-
53.0-
S2.5-
~2.0-
1.5-
1.0-
0.5-
0.0-
Mass 202.00
I—
m
us
o
CM
ID
PO
\D
20.6 20.3 21.0
Time (min.)
21.
21.4
Mass 101.00
o 3.0
20.6 20.8 21.0 21.2 21.4
Ti«e (win.)
Hass 100.00
T
T-l
vO
O
CM
htLp*.
CM
O
CM
V T I'
20.6 20.8 21.0
Time (min.)
21.2 21.4
72
I
-------
Data File: /chem/Y.i/09-04-97.b/YP578.d Page 20
Date : 04-SEP-1997 18:55
Instrument : Y.i
Sample IB : RUN2
Column phase : DB-5 Column diameter : 0.32
Volume Injected J » t \
440
Scan 2480 <21.391 min) of YP578.d (Subtracted)
2.0-
1.8-j
1.5-i
^ 1.2-
ID
^1.0-i
So.s
^0.5-
0.2-
0.0-
40 80
±1
f 1
120 160 200 240 280 320 360 400 440
Mass/Charge
78 Pyrene (PBH Reference Spectrum)
8.0-
6.0-
ro
¦
O
.
tH
X
4.0-
5_
¦
2.0-
0.0-
40
120 160
' I ¦'"?
| t 'i—r-
200 240 2
Hass/Charge
-j—; f t |"'-f
560 400
440
100-
75-
50-
25-i
£
® -25-i
-50-;
-75-i
-ioo-V
40
Scan 2480 <21.391 min) of YP578.d <2 DIFFERENCE)
i.A
1 r \ imi i ( i i k | iTi'j'r i i | i—ft i—rnr-i—{—i -tt {' i v T-pr
120 160 200 240 280 320 360 400 440
Hass/Charge
Mass 202.00
21.0 21.2 21.4
Time (min.)
21.6 21.8
Mass 101.00
6.0|
ro
|
5.5-1
o
CM
C5>
ro
5.0-1
T-i
CM
4.5-|
4.0-1
— 3.5-1
o 3.0-1
>2 2.5-|
2.0-|
1.5*3
1.0I
j
0.5-1.
y/
0.0'J*-»-"r_'—r"r i r
oiv
r-r_r
21.2 21.4
Time (mirt.)
21.6
Mass 100.00
21.2 21.4
Time (min.)
21.6
-------
Data File: /chem/Y.i/09-04-97.b/YP578.d page 21
Date : 04-SEP-1997 18:55
Instrument : Y.i
Sample ID : RUN2
Column phase : DB-5 Column diameter : 0.32
Volume Injected (uL) : 1.0
83 Benzo(a)anthracene
Scan 2823 (23.
min) of YP578.d
Mass 228.00
6.0
2.4
2.0
f>
ksi
1.2
0.8
0.4
2.0
1.5
1.0
120 160 200 240 280 320 360 400 440 480
Mass/Charge
Scan 2823 <23
min) of YP578.d (Subtracted)
23.6 23.3 24.0 24.2
0.0
1.2
1.0
Mass 229.00
1.8-
1.6-
1.4-j
1.2t
CM
do
( 3
r i
0.2
0.0
120 160 200 240 280 320 360 400 440 480
Mass/Charge
83 Benzo(a)anthracene (PBM Reference Spectrum)
8.0-
0.2
6.0-
fO
0.0
4.0-
24.0 24.2
0.6-j
74
-------
Data File: /chem/Y.i/09-04-97.b/YP578.d Page 22
Date : 04-SEP-1997 18:55
Instrument : Y.1
Sample ID : RUN2
Column phase : DB-5 Column diameter : 0.32
Volume Injected (uL) : 1.0
84 Chrysene
Scan 2831 (23.944 min) of YP578.d
o 3.0
i' i" \ ( i i i
j- ¦! i r | i 1 i i j it
120 160 200 240 280 320 360 400 440
Mass/Charge
Scan 2831 (23.944 min) of YP578.d (Subtracted)
4.0-
3.0-
2.0-
1.0-
0.0-
I,lJ MJll
W+-
4uJ
40
'* * I* 1 ' ' I 1 ' 1 I 1'1 ' I 1
120 160 200 240 280 320 360 400 440
Mass/Charge
84 Chrysene (PBM Reference Spectrum)
8.0-
~6.0-
ro
§4.0-
2.0-
0.0-
r-t
40
i' i»i vi J
|a i i—f j' l " i 11 ^ i—r~f—]—i—r—!—]—I i I—[—I—I—I—|—I—I—I—|—I—I—I—|—I—r
80 120 160 200 240 280 320 360 400 440
Mass/Charge
100-3
75-i
50-.
25-E
u.
n-
u.
a
-25-:
.
-50-:
-75";
100-3
Scan 2831 (23.944 min) of YP578.d (Z DIFFERENCE)
>. .« .r ^ |L jib .it i . ill ..
jl.
I ' 1 ' I
I 1 ' 1 I 1 '
l | i—t—i—|—i—i—r—|—r—i—r—|—i—r—i—|—i—i—i—|—l—i—i—]—i
40 80 120 160 200 240 280 320 360 400 440
Mass/Charge
Mass 228.00
1.8-
1.6-
1.4
1.2
•tr
1.0
0
X
0.8
>-
0.6
0.4
0.2
0.0
23.6 23.8 24.0
Mass 226.00
24.4
1 I ' ' ' I '
23.6 23.8 24.0
Time (min.)
I 1 1 ' I
24.2 24.4
Mass 229.00
23.6 23.8 24.0 24.2 24.4
Time (min.)
75
-------
Data File: /chen/Y.i/09-04-97.b/YP578.d
Date : 04-SEP-1997 18:55
Instrument : Y.i
Sample ID : RUN2
Column phase : DB-5
Volume Injected : 1.0
Column diameter : 0.32
Page 23
86 BenzcKMfluoranthene
Scan 3198 <26.604 min) of YP578.d
o 1.0-
M
150 175 200 225
Mass/Charge
T
250
iji,
1111 11 i i
275 300 325
I ! | 'l I I! l'
350
Scan 3198 (26.604 min) of YP578.d (Subtracted)
1.6-j
1.4-1
1.2-j
S0.8-!
^0.4-j
0.2-=
0.0
,41,1,1 M\j h1* <|iH t JI'Ji,
i'l'p I'l ^"J'T * 'l'^ '1*1 *l*f ! ]"l'f I"?') Y»"f^ 'f iMY T'f I". V i i 'j'i ,') , I J n l { } l i l
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charge
Jrr-
86 Benzo¦
2.0-
0.0-
i 1 f i t n i ^ i *i
4
| 1 n i| 1 1 rr*f \ i i q I i I i"pi i up i"»' ryrt r 'r \ t t i t \
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charge
100-|
75i
50-1
25-^
0
0-25.
-50'
-75-3
-100
Scan 3198 (26.604 min) of YP578.d <2 DIFFERENCE)
iii >. itil lit. 1 ii. .,J ...t 4m >* i li* . I >1.1. I 'bill J I* 1^1 III A
Mass 252.00
2.0-1
i.sl I
O
<^3
\D
CM
1.6-5
i
ru2i
si.o|
X j
^0.8|
0.6-3
^ 1ST)
[ CO
0.4-j
1 sO
\ "
°*21 J
0 01 ,^/vwA/Mu,
,WA
1 . 1 . .
26.20 26.40 26.60 26.80 27.00
Time (min.)
t I [1 1 1 I { l I 1 1 \ I I I I | I 1 I I { 1 I I ) | J I I I | 1 M 1 | ) I I I j 1 I 1 1 j 1 I I I | I I I I | I I I I [ I 1 i )
50 75 100 125 150 175 200 225 250 275 300 325 350
Hass/Charge
Mass 253.00
26.20 26.40 26.60 26.80 27.00
Time (min.)
Mass 125.00
¦ T, |... ,.|—j , j | i—1 r,-),-'t
26.20 26.40 26.60 26.80 27.00
Time (min.)
78
-------
Data File: /che*/Y.i/09-W-97.b/YP578.d Page 16
Date ; Q4-SEP-1997 18:55
Insfcrunent : f.i
Sample IB : RUN2
CaliMn phase : DB-5 Colunn dianeter : 0.32
VoluMe Injected -0.4-
0.2-
0.0-
jiiiifv(ih||[,n|l|il
nvmii|W
i
Hllllj'UHp
50 75 100 125 150 175 200 225 250 275 300 325 350
Hass/Char?e
5.0-
4.0-
-3.0-
ro
<
o
*2.0-
s-
1.0-
0.0-
Scan 3207 <26.669 »in> of YP578,d (Subtracted)
87 Benzo(k)fluoranthene -25-2
-rp
50 75 100 125 150 175 200 225 250 275 300 325 SO
Mass/Charge
Scan 3207 <26.669 »in) of YP578.d i 11 i i » | i i » i | r i r i j m i| i m | i
50 75 100 125 150 175 200 225 250 275 300 325 350
Mass/Charge
^ j t r11
26.20 26.40 26.60 26.80 27.00
Time (min.)
Hass 125.00
| > i i I i i r [ ¦» i i { i
26.20 26.40 26.60 26.80 27.00
Tine (win.)
: i
-------
Data File: /cWY.iA>9-04-S7.b^PS78.d
Date : 04-5EP-193? 18:K
Instrument : Y.i
Sample ID : RUN2
Column phase : DB-5
Volume Injected : 1.0
88 Bersrapyrene
Page 17
Coluwi diameter : 0.32
I
I
1
Scan 3303 <27.362 min> of YP578.d
Mass 252.00
>•0.4
"d 0.5
Scan 3303 <27.362 »in> of YP578.d (Subtracted)
I > i ; i i I I |
27.20 27.30 27.40
Time (win.)
Mass 253.00
.20.4--
"1.5
27.20 27.30 27.40
Tiwe <*in.)
d
Mass 125.00
0^0 'l t »' i'|"r 1 P'f'f » l i r*"i i ^ f t*i | ^ I* i '| i i i ; i i i ; > > > j i i i j i I I
40 80 120 160 200 240 280 320 360 400 440
Mass/Charge
Scan 3303 <27.362 min) of YP578.d
-------
Data File: /chem/Y.1/09-04-97.b/YP578.d
Date : 04-SEP-1997 18:55
Instrument : Y.i
Sample ID : RUN2
Column phase : DB-5
Volume Injected (uL) : 1.0
Column diameter : 0.32
Page 26
89 Benzo(a)pyrene
8.0-
.6.0-
ro
<
o
^4.0-
2.0-
0.0-
Scan 3320 (27.484 min) of YP578.d
200 240
Mass/Charge
Scan 3320 (27.484 min) of YP578.d (Subtracted)
x 2.0-
200 240
Mass/Charge
I I | I I
400
89 Benzo(a)pyrene (PBM Reference Spectrum)
TT
a
-r
i ' ' 1 i
¦ i-1 i
40 80 120 160 200 240 280 320 360 400
Mass/Charge
7—' 1 1 I I I
100-
75-
50-
25-
fc 0-
S-25-
-50-
-75-
-100-
Scan 3320 (27.484 min) of YP578.d (2 DIFFERENCE)
Il.iJ.LLLiiIII III I . Llliliji I 111 I
J ¦ r 1 T "I ' | I "I" T— J" T > I '[ "7 ¦ r ¦ I | I I I | I I I | I I I | I 1 I | I I I | 1 '!' V 1 1
40 80 120 160 200 240 280 320 360 400
Mass/Charge
Mass 252.00
27.20 27.40 27.60 27.80
Time (min.)
Mass 25o.00
r°1.5-
27.20 27.40 27.60 27.80
Time (min.)
Mass 125.00
< 4.0
I ¦ ¦ ' I 1 ¦ ' I 1 1 ¦ I 1 ¦ 1 I ' 1 1
27.00 27.20 27.40 27.60 27.80
Time (min.)
73
-------
Project Number 42930B
Sample File: YP580
Method 8270A MM5
Sample ID: RUN3
Date Analyzed: 09/04/97
Mil!
Dilution Factor: 20.00
Naphthalene-dg
IS 2
11.74
Naphthalene
2924.95
B
11.79
200
2-Methylnaphthalene
2324.33
13.21
200
Acenaphchene-dio
IS 3
15-34
2-Chloronaphthalene
U
5.54
200
Acenaphthvlene
189.14
J
15.05
200
Acenaphthene
110.39
J
15.42
200
Fluorene
222.20
16.49
200
Phenanthrene-d
10
IS 4
18.42
Phenanthrene
1476.65
18.47
200
Anthracene
256.87
18.57
200
Fluoranthene
773.00
20.93
200
Chrysene-d^
IS 5 High
23.90
Pyrcne
316.13
21.39
200
Benzo(a)anthraoene
119.35
J
23.89
200
Chrysene
176.92
J
23.95
200
Perylene-d
12
IS 6 High
27.64
Benzo(b)fluoran thene
46.44
J
26.61
200
Benzo{k)fluoranthene
19.08
J
26.64
200
Benzo(e)pyrene
22.29
J
27.34
200
Benzo(a)pyrene
8.89
J
27.49
200
Perylene
U
2.94
200
Indeno(l .2,3-cd)pvrene
U
2.35
200
Dibenz(a,h)anthracene
u
3.24
200
Benzo(g,h,i) perylene
1.72
J
30.97
200
NA- Not Applicable; Det Omit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; O: Undetected; B: Present In Blank; Js Estimated- Below Quantitation Limit; E; Estimated- Above Calibration Range
Triangle Laboratories of RTP, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.5
Printed: 16:00 09/12/1997
SO
-------
Eastern Research Group
Project Number: 42930B Method 8270A MM5
Sample File: YP580 Sample ID: RUN3
Client Project: Ir
TLI ID: 179-98-3;
Date Received:
Date Extracted:
Date Analyzed
08/19/97 Ri
08/25/97
lii
iSpOl
i
e Fil
s
1
T571
Dilution Factor: 20.00
Surrogate Seminary
. Amount
RT
ISRef
%REC
Anthracerie-d 87.66 18.54
10
Pyrene-d 68.99 21.36
' 10
Reviewed by Date *9* / [ "2j ^ ~3-
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS; Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangl e Laboratories of RTP, Inc. Savar v3.5
801 Capitola Drive • Durham, North Carolina 27713 Printed; 16:00 09/12/1997
Phone: (919) 544-5729 • Fax: (919) 544-5491 4
8
-------
Data File: /chem/Y,i/O9-04-97.b/YP58O,d
Date : 04-SEP-1997 20:26
Instrument : Y.i
Sample ID : RUN3
Column phase : DB-5
Volume Injected ; 1.0
Page 9
Of RTP, Inc.
Column diameter : 0,32
Ol
00
1.6-
1.5-
1.4-
1.3-
1,2-
1,1-
i.°:
o,9:
i
£0.8:
H
k ;
0,7-
0&:
0.5-
0,4-
0,3™
0,2-J
0,1-^
0,0-
/chem/Y. i/09-04-97,b/YP580,d (Part 1 of 2>
GO
h-
O
C
11
0
3
It.
1
CvJ
—r • i1 j 11" i—I- i j i i » i—["I i i i
)
wmm
itr
Q1
5|
B B
D Q
-------
Data File: /chem/Y.J/09-04-97.b/YP580.d
Date : 04-SEP-1997 20:26
Instrument : Y.i
Sample ID ; RUN3
Column phase : DB-5
Volume Injected : i.O
Page 10
Triangle Laboratory
of RTP, Inc.
Column diameter : 0*32
/chem/Y.i/09-04-97,b/YP580*d (Part 2 of 2)
l.H
1*5-
1.3-
1.2-
14-
1*0-
o
o
CP>
ro
CM
CM
CM
ro
kD
«
r-
CM
0.6
0.5-
BO
JH
0.4-
a.
- I
0.3-
0.2-
0.1-
0.0
-------
Data File: /chea/Y. i/09-04-97.b/YP580.d
Report Date: 05-Sep-1997 07:41
Page 1
TRIANGLE LABORATORIES, INC.
Data file
Lab. Id.
Inj Date
Operator
Snip Info
Misc Info
Comment
Method
Meth Date
Cal Date
Als bottle
Dil Factor
Integrator
Sample Type
SEMI-VOLATILE QUANTITATION REPORT
/chem/Y.i/09-04-97.b/YP5 80.d
42930B
04-SEP-1997 20:26 Autotune Date: 06-Sep-99 14:30:1
DD Inst ID: Y.i
RUN 3
179-98-3AC-E
/chem/Y.i/09-04-97 .b/cclist .m
05-Sep-1997 07:30 target
04-SEP-1997 13:32
9
20.000
HP RTE
AIR
Cal File: YP571.d
Target Version: Target 2.20
Compound Sublist: pah.sub
CONCEKTRATIONS
QTJAHT SIQ
ok-columh
FINAL
Compound*
MASS
RT (REL RT)
RESPONSE
; ( ng)
( tig)
.
1
l,4-Dichlorob«xiz«n»~-d4
152.aa
9.244(1.000)
651163
40.00
•
2
N*phthal«ra«~d8
136.00
11.743(1.000)
1900787
40 * 00
»
3
Ac •nmph th«n«-dlQ
164.OS
IS.343 (1.S00)
1352919
40.00
•
4
Ph<»nantiir«a«-dl0
188.00
18.419(1.000}
1980996
40.00
~
5
Chry8«Q«-dl2
240.00
23.900(1.000)
2249798
40.00
*
6
P«ryl«na>-dl2
264.00
27.639(1.000)
2880382
40.00
%
7
2-Fluorophano1
112.00
6.784(0.734)
8004
0.49
9.74 UQR)
$
8
Phanol-dS
99.OS
8.585(Q.929)
104355
4.40
88.08 U)
$
9
2-Chloroph«nol~d4
132.00
9.158(0.3913
1897
o.ia
2.02 UQR)
$
10
l,2-Dichlorob«as»n«-d4
152.00
9.552(1.033)
369
0.03
0.SI UQR)
$
11
Nitrob«nz*n«-d5
82.00
10.305 (0.878)
105671
5.98
119. 67 UQ J
$
12
1, 3,5-Trichlorob«nz«ra»-d3
185.00
10.988(0.936)
72198
4.12
82.32 U>
$
13
1,4-Dibromob«nz«n*-d4
239.80
11.851(1.282)
58669
4.69
93.79 U!
s
14
2-Fluorobiphtnyl
172.00
13.985(0.911)
185233
4.56
91.13(a)
$
15
2,4,6-Tr ibroaophwciol
329.80
16.981(1.107)
40685
5.87
117.38 UQ)
$
16
Anthrac«m*-dl0
188.00
18.535(1.006)
220318
4.38
87.69(a)
$
17
Pyr«n«-dl0
212.00
21.358(0.894)
262133
3.45
68.98(a)
$
18
T«rph*nyl-dl4
244.00
21.775(0.911)
802
0.02
0 .33 <«CR)
42
Naphthalan®
128.00
11.786(1.0043
6386709
146.30
2926.07
4 S
5 0
2-UrnthyInaphtha1mam
142.00
13.213(1.125)
3523407
4 I C A
116.28
2325.61
56
2 'ChloroQApbthslmc
Ac ®naphthy1
152.00
15.054(0.981)
534181
9.46
189.19(a!
58
Ac*naphth«n«
154.00
15.416(1.005)
173240
5.52
110.38(a)
65
Fluoren*
166.00
16.487(1.0753
417485
11.11
222.14
73
Ph«aamthr*o*
178.00
18.470(1.003)
3868614
73.82
1476.31
74
Ant&rac«a«
178.00
18.571(1.008)
625886
12.84
256.85
77
Fluora»th«n#
202.00
20.934 (1.137)
1707409
38.66
773.11
78
Pyr«n«
202.00
21.395(0.895)
1273985
15.81
316.17
83
Btazo{«) anthraciwo,*
228.00
23.885(0.9993
352078
5.97
119.35(a)
84
Chry««n*
228.00
23.951(1.0023
456257
8.84
176.84 (a)
86
B«nzo(b)fluoranth«n«
252.00 Qki&\
24.76 (a)//
Data Review*
Date:
84
-------
Data File: /chem/Y.i/09-04-97.b/YP580.d
Report Date: 05-Sep-1997 07:41
Page 2
Compounds
87 B«nzo()c) £luoranth«n«
88 B«nzo(•)pyr«n«
89 Banzo(a)pyran*
90 P«ryl»n#
91 Ind#no(1,2,3-cd)pyr»n«
92 Dib«nz(a,h)anthr*c*n*
93 B«nzo(g,h,i)p#ryl«n«
QC Flag Legend
QUANT SIO
MASS
RT (RKL RT)
CONCENTRATIONS
ON-COLUMN FINAL
RESPONSE ( ng) ( ug)
252.00 19<(0i7gai
252.00 27.341(0.989)
252.00 27.486(0.994)
asa.QQ 27 .1839 (1.001)
-***& 1.24
78157 1.11
28617 0.44
»7n 0.09
«fl7f¦00
aioioo
3e.aoid.oj6)
30 . 370 (11 099)
£03?
cai
8.03
0 . 01
2*3?
50.98 4 (1.121)1
198'8
0.03
Q
R
Target confound detected but, quantitated amount
Below Limit Of Quantitation(BLOQ).
Qualifier signal failed the ratio test.
Spike/Surrogate failed recovery limits.
24 . 73 (a) C#>)/iZ/3>
22.28(a)
8.89U)
i-«*(¦»- Pa/s
—a.coua) -ff> fOeuS
n -""ip'
0.52 (aQ)
-------
Data File: /chem/Y.i/09-04-97.b/YP580.d Page 11
Date : 04-SEP-1997 20:26
Instrument : Y.i
Sample ID : RUN3
Column phase : DB-5 Column diameter : 0.32
Volume Injected -1.0-
0.5-
0.0-
j" J '»•) '* 4 i j ^ "-1— "r 1 |11 r—i t [ i i i—i—i—i—r™]—r—r—i—j—i i i | i i—i—p~r
40 80 120 160 200 240 280 320 360 400
Hass/Charge
3.5-
3.0-
2.5-
$2.0-
o
>51.5'
-1.0
0.5
0.0
40
8.0-
,6.0-
ro
<
o
34.0-
>¦
2.0-
0.0-
100-
75-
50-
25-
t 0-
3-25-
ht
-50"
-75-
-100-
Scan 1131 <11.786 min) of YP580.d (Subtracted)
J«V» "i
120
{ I \ 1 { » I 1 | 1 1 I I
160 200 240
Hass/Charge
280
SO
¦ t ' 1 ' I '
360 400
42 Naphthalene (P1H Reference Spectrum)
j ^ I 'l 1^-
40
' I"' 1 ' "i ' ' I ' » ' 1 '
120 160 200 240
Hass/Charge
360
400
Scan 1131 (11.786 min) of YP580.d (2 DIFFERENCE)
40
i_r-r
120
1 1 1 1 ' 1 ' 1 ' 1 »
160 200 240
Hass/Charge
280
320
360
1 ¦"
400
Hass 128.00
1"1 | 1 t
11.40 11.60 11.80 12.00 12.20
Time
11.40 11.60 11.80 12.00 12.20
Time (min.)
Hass 127.00
4.8-
4.4-
4.0-
3.6-
3.2-
£> 2.8-
3 2.4-
x « ^
~2.0-
*"1.6-
1.2-
0.8-
0.4-
0.0-
few
-fi
I'n I j T IT1] TfT'l ( I "I1 1
11.40 11.60 11.80 12.00 12.20
Time (min.)
86
-------
Data File; /chem/Y.i/09-04-97.b/YP580.d
Date ; 04-SEP-1997 20:26
Instrument ; Y.i
Sample ID : RUN3
Column phase : DB-5
Volume Injected : 1.0
Column diameter : 0.32
Page 12
46 2-Methylnaphthalene
Scan 1329 <13.213 mm) of YP580.d
Mass 142.00
^1.0
vol.0-
I 1 I 'r | ' T 7 T | f 1
200 240 280 320
Mass/Charge
' 0.8
>-0.5
0.2
0.0 T MM*-"**
Scan 1329 (13.213 min) of YP580.d (Subtracted)
;°j
^0.5-:
0.24
0.0
jL ^ I,it
i 1 ' 1 i 1 1 1 I 1 1 1 I 1 1 1 I ' r ¦ i i ' ¦ i ' ¦ i i '
40 80 120 160 200 240 280 320 360 400
Mass/Charge
440
46 2-Methylnaphthalene (P1M Reference Spectrum)
200 240
Mass/Charge
100-
75-i
50-i
25-
£
= -25-
-50r
-75-i
-100-
Scan 1329 <13.213 win) of YP580.d « DIFFERENCE)
"I""
40
120 160
200 240
Mass/Charge
320 360 400 440
1.6-
1.4
1.2
^ i.O
vD
o 0.8
X
~0.6-j
0.4
0.2^
0.0
1 |fl T 1 ''I r * ' I 1
12.80 13.00 13.20 13.40 13.60
_T«e_(mini|_
Mass 141.00
r—in
o
04
o
T
ro
—t
i
SrSTl3,0 13.40 13.60
Time
-------
Data File: /chem/Y.i/09-04-97.b/YP580.d
Date : 04-SEP-1997 20:26
Instrument : Y.i
Sample IB : RUN3
Column phase : BB-5
Volume Injected • 0
0
0
.4-;
Or
,6
.2-1
.|[„i p.., f,
t. f "!•"•( |
40
60
80 100
120
A
140 160
Mass/Charge
180
200
220 240 260
56 ftcenaphthylene (PBM Reference Spectrum)
f-O
<
o
8.0-
,6.0-
I
14.0-
2.0-
0.0-
40
60
|-»jlLyyiill|' |.
80 100
1 i'"1 1 1 I ' l|"1' I 1 ' ' i > ' 1 i
120 140 160 180 200
liass/Charge
¦ i ' ' ' i 1 '¦ 1I
220 240 26<
100-
75-
50-j
25-i
: °1
« -25-i
-50-
-75-
-100-
Scan 1584 (15.054 min) of YP580.d it DIFFERENCE)
40
60
80
I-1-
J I i t |
100 120 140 160 180 200
Mass/Charge
Mass 152.00
>-1.0
!"'i 'j" ir "i i | i
14.60 14.80 15.00 15.20 15.40
Time (min.)
| I I I { I I I j 1 I I |
220 240 260
Mass 151.00
I 1 1 1 I 1 ' 1 I > • ¦ i ¦ ¦ 'I
14.60 14.80 15.00 15.20 15.40
Time (win.) __
Mass 153.00
°0.6
I ' ' 'I ' ' ¦ I ' ' 1 I
14.60 14.80 15.00 15.20 15.<
Time (lain.)
83
-------
Data File: /chem/Y.i/09-04-97.b/YP580.d Page 15
Date : 04-SEP-199? 20:26
Instrument : Y.i
Sample ID : RUN3
Column phase : BB-5 Column diameter : 0.32
Volume Injected -
2.0-
0.0-
4 J i Ji i |
1 ' ' I ' 1 ' I ' ' 1 t ' 1 1 I 1 1 ' I 1 ' 1 I '
40 80 120 160 200 240 280 320 360 400
Mass/Charge
100-
75-
50-
25-
• 0-
<=-25-
-50-
-75-
-100-
Scan 1634 <15.416 min) of YP580,d <2 DIFFERENCE)
1 -r t|
•* ' •1~'
1—1 1 1 t |
40
120 160 200 240 280 320
Mass/Charge
y-j"—t—f t mn\—r-r"
360 400
Hass 154.00
-I—J—i—l ' l"" J " i I—P"
15.00 15.20 15.40 15.60 15.80
Time (win.)
Mass 153.00
O 00
» 00
If)
I ' ' ' I ' ' ' i ' 1 ' !
15.00 15.20 15.40 15.60 15.80
Time (win.)
Mass 152.00
15.00 15.20 15.40 15.60 15.80
Time (win.)
89
-------
Data File: /chem/Y.1/09-04-97.b/YP580.d Page 16
Date : 04-SEP-1997 20:26
Instrument : Y.i
Sample ID : RUN3
Column phase : DB-5 Column diameter : 0.32
Volume Injected (uL) : 1.0
65 Fluorene
Scan 1782 <16.487 min) of YP580.d
Mass 166.00
o 1.2-
^"T"1,111 I ' 1 1 I 1 1 I I I I ' I ' T ' I I ¦ • I ' I 1 I I ¦ r I
80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
Scan 1782 <16.487 min) of YP580.d Subtracted)
16.0 16.2 16.4 16.6 16
Time (min.)
Mass 165.00
80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
65 Fluorene
-------
Data File: /chem/Y.i/09-04-97.b/YP580.d
Date : 04-SEP-1997 20:26
Instrument : Y.i
Sample ID : RUN3
Column phase : BB-5
Volume Injected : 1.0
Column diameter : 0,32
Page 17
73 Phenanthrene
2.0-
1.6-
;i.2-
• 0.8-
0.4-
0.0-
Scan 2055 <18.470 min) of YP580.d
T" [**1 "* i'|'*ti*'|—i—i—i—|—i—i i' ]—i—i—i—|—i—i—r—J—i—i—i—|—i—i—i—|—i—i—i | l )
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charge
Scan 2055 (18.470 mm) of YP580.d (Subtracted)
2.0-
1.6-
^1.2-
o
•0.8-
0.4-
0.0-
i > s t'i ¦> i" r rr f) i i v ( i i i | i i i [ . i i i i i i | i . i j i ¦ i t i i
40 80 120 160 200 240 280 320 360 400 440 480
Hass/Charge
U
73 Phenanthrene (PBM Reference Spectrum)
8.0
.6.OH
r-o
14.0-1
2.0'
0.0-
t+-
40
4—t f '1—r r ; i1
I 1 ' 1 I ' 1 1 I 1 11 I '-'""'""I ' 1 ' I ' ' 1 I ' 1 '"I 1
120 160 200 240 280 320 360 400 440 480
Hass/Charge
Scan 2055 (18.470 min) of YP580.d <2 DIFFERENCE)
75-.
50-1
25-i
0-3--
<=-25-
-50-;
-75-!
-100
r^-
40
n—f—|--r-
""I' 1 '
80 120 160 200 240 280 320 360 400 440 480
Mass/Charge
Mass 178.00
f"*=T
1 1 1 1 1 1 • i > « « 1 ->
18.2 18.4 18.6
Tine (min.)
Mass 179.00
0I.6
18.0 18.2 18.4 18.6 18.3
Time (win.)
Mass 176.00
4.0-
3.6-
3.2-
2.8-
_2.4-
S 2.0-
31.6-
3>—
1.2-
0.8-
0.4-
0.0-
*frvr y '>
18.0 18.2 18.4 18.6
Time (win.)
-------
Data File: /chem/Y.i/09-04-97,b/YP580.d Page 13
Date : 04-SEP-1997 20:26
Instrument : Y.i
Sample ID : RUN3
Column phase : DB-5 Column diameter : 0.32
Volume Injected (uL) : 1.0
74 Anthracene
Scan 2069 (18.571 min) of YP580.d
3.2-
2.8-
2.4-
^2«°-
ol.6-
*1.2-
^0.8-
0.4-
0.0-
l*r*pj'j-i-f i f|T i 111 M ¦ 111 1111 111 111 111 111 ¦ 111
50 75 100 125 150 175 200 225 250 275 300 325 350 375
Mass/Charge
Scan 2069 <18.571 min) of YP580.d (Subtracted)
3.2-
2.8-
2.4-
.2.0-
ol.6-
rH
£1.2-
>"0.8-
0.4-
0.0-
4-rfr-
50
iM
75
-f*
100 125 150 175 200' 225 250 275 300 325 350 375
Mass/Charge
nn
74 Anthracene (PBM Reference Spectrum)
8.0-
.6.0-
ro
^4.0-J
2.0-
0.0-
"rtr
50
'"iM 'V
-h
i
75 100 125 150
175 200 225
Hass/Charge
nr
rr
250 275
300
325
350
375
100-
75-
50-
25-
: 0-
«-25-
X
-50-
-75-
-100-
Scan 2069 (18.571 min) of YP580.d (2 DIFFERENCE)
I' | M I I | I I I I | I I I I ] I
50
"P
I " 111 1 " 1 I " " I " ' 111 1' ¦ I " ¦ 111 " 1 I " ¦11 ¦
75 100 125 150 175 200 225 250 275 300 325 350 375
Mass/Charge
2.2-i
r-~
2.0-;
GO
1.Q-.
1.6-=
1.4-3
£l.2-;
^i.o-=
>. 0.8-E
0.6-:
18.571
0.4-=
1
0.2-:
A
0.0-
11 11 1 1 V11
40.
18.2 18.4 18.6
Time (min.)
Mass 176.00
ID
U. 2.0
1 1 I
18.2 18.4 18.6 18.8
Time (min.)
Mass 179.00
3.2-
1—0
2.8-j
00
rH
2.4~.
. 2.0-;
ID
Si-*-
tH
^1.2-j
If)
00
rH
0.8-3
0.4-;
lA
0*0-
! . 1 t , » J , , , ,
18.2 18.4 18.6
Time (min.)
18.8
11 I '
19.0
92
-------
Data File: /chem/Y.i/09-04-?7.b/YP580.d
Date : 04-SEP-1997 20:26
Instrument : Y.i
Sample ID : RUN3
Column phase : DB-S
Volume Injected
T "fl "J" T" I I j J I I j I I
160 200 240 280 320
Mass/Charge
Tr-
360
* i 1
400
440 480
Scan 2393 (20.934 min) of YP580.d (Subtracted)
8.0-
6.0-
4.0-
2.0-
0.0-
i ' '• 'V' '*•' 'k( 'T' ¦ ¦ i ' » ¦ i 1 1 1 i ¦ 1 ¦ i ¦ 1 ' i 1 1 1 i < ' 1 i 1
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charge
77 Fluoranthene (PBH Reference Spectrum)
8.0-
6.0-
fO
"
o
.
tH
X
4.0-
>-
"
2.0-
0.0-
X
40
T
t
i ' 1 1 i
i""} |—t i "T p i i i r i i1 j 1
80 120 160 200 240 280 320 360 400 440 480
Mass/Charge
Scan 2393 <20.934 min> of YP580.d <2 DIFFERENCE)
100-
75-
50-
25-
& -
0.4-
0.2-
0.0-
Mass 202.00
in 5.0
o
CM
CO
CM
vD
O
CM
—p~i"^ i 1";
20.60 20.30 21.00 21.20 21.40
Time (min.)
Mass 101.00
>-0.6
20.60 20.80 21.00 21.20 21.40
Time (roin.)
Mass 100.00
©
CM
00
eg
SD
o
CM
&
I ' 1 ' I ' ' I ' ' ' t ' ' 'T
20.60 20.80 21.00 21.20 21.40
Time (min.)
93
-------
Data File: /chem/Y.i/09-O4-97.b/YPS8C.d
Date : 04-SEP-1997 20:26
Instrument : Y.i
Sample ID : RUN3
Column phase : BB-5
Volume Injected ; 1.0
Column diameter : 0.32
Page 20
I
I
I
78 Pyrene
Scan 2456 <21.395 min) of YP580.d
6.0-
5.0-
5>4.0-
|3.0i
>. 2.0-
1.0-
O.O^f-W'
160 200
240 280 320 360
Mass/Charge
Scan 2456 (21.395 win) of YP580.d (Subtracted)
6.0-
5.0-i
^4.0-
S 3.0-
X
^2.0-
1.0-
0.0 *'ti 'i*
40 80
T_T_r.
120
r
160 200
""t ; i—i i ] i i i | i
240 280 320
Mass/Charge
360
_ri_r_
400
• i *
440
-T-T-r-
480
520
78 Pyrene (PBM Reference Spectrum)
8.0-
.6.0-
r-
2.0-
0.0 ^ > i' '* i *
40 80
-i-pr-
120
t I i
160
200
240 280
Mass/Charge
320
360
400
440
T-j-r-
480
Tr-
520
100 q
75
50
25
**• 0
® -25-:
-50-3
-75
-100-^r
Scan 2456 (21.395 rain) of YP580.d (Z DIFFERENCE)
' \ I I I j 1 1 ' I } 1 I 1 { I 1 I \ I I J | I 1 I I 1
40 80 120 160 200 240 280 320
Mass/Charge
T-r-
I | I
400
i | tt'i { > i > ; i
440 480 520
Mass 202.00
9.0-:
pn
J
8.0-i
o
CM
7.0-f
6.0-j
CM
S 5.0-:
o
^4.0:
^3.0-^
2.0-:
[
1.0-i
o.o-i
-^VyVyr-^iLrj | V;
21.00 21.20 21.40 21.60 21.80
Time (min.)
Mass 101.00
>- 0.6-
l 1 !"i' I1""1"' 1 l ' 1 ' i
21.00 21.20 21.40 21.60 21.S
Time (min.)
Mass 100.00
1.4-
1.2-
1.0-
30.8-
b
2 0.6-
>-
0.4-
0,2-
0,0-
o
CM
1—in
CT>
I fo
21.00 21.20 21.40 21.60 21.80
Time (min.)
94
I
-------
Data File: /chem/Y,i/09-04-97.b/YP580.d Page 21
Date : 04-SEP-1997 20:26
Instrument : Y.i
Sample ID : RUN3
Column phase : DB-5 Column diameter : 0,32
Volume Injected -1.0-
0.5-
0.0-
¦nJijLiJMpj
J
' ^ ^
¦T¦ <¦L|—r'lTl"i"],Tl 'i"T"f"i—i—r-]—i—i—r—i—r-
80 120 160 200 240 280 320 360
Mass/Charge
400
T
440
83 Benzo(a)anthracene
<
o
tH ,
X *
8.0-
.6.0-
t
!4.0-
2.0-
0.0-
-+¦
/ * , f
rl
W ' t ¦
40 80 120 160 200 240 280 320 360
Mass/Charge
1 i 1 ' 1 1
400 440
100-
75-
50-
25-
: °-
® -25-
M
-50-
-75-
-100-
Scan 2796 (23.885 min) of YPSSO.d <2 DIFFERENCE)
1
i
¦p r-n '"I % t
| » i >| » i i | '
40 80 120 160 200 240 280 320 360
Hass/Charge
T1r
400
I
440
Mass 228.00
1.8-
1.6-
—t ")
P 3
1.4-
F >
r J
1.2-
<
So.8-^
>-0.b-;
LO
•Tf
0.4^
ro
CM
j
0.2t
A j
^i-j ^
0.0-
T"r"
23.40 23.60 23.80 24.00 24.20
Time (min.)
Mass 229.00
1 I \ "|' lM,l 1 I | i I ' 1' j I I""!1"
.40 23.60 23.80 24.00 24.20
Time (min.)
Mass 226.00
! I I | i I I [ 1 i i i | t j i i
.40 23.60 23.80 24.00 24.20
Time (min.)
-------
Data File: /chem/Y.i/09~04-97.b/YP580.d Page 22
Date : 04-SEP-1997 20:26
Instrument ; Y.i
Sample IB : RUN3
Column phase : DB-5 Column diameter : 0.32
Volume Injected (uL> : 1.0
84 Chrysene
Scan 2805 <23.951 mini of YP580.d
LO 1.0
4 j~[~v 11 | i i t [ i i t | i j
¦1 1 i 1 1 ¦ i
80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
Scan 2805 (23.951 nun) of YP580.d (Subtracted)
1.4-
1.2-
i.o-i
ui 0.8-
<
^0.6-
^0.4^
0,2-
0.0 i'11'; VIM'1)*'i'H I ['i'1!') f i' i*i" i'y i" i'i '|"r i'i | i i i | i i i [ i > i ( i i i |
40 80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
¦M
4,
84 Chrysene (PBH Reference Spectrum)
8.0-
K>
<
o
.6.0-
*4.0^
"2.0-
0.0-
d
1 I'11 ' T ' I ' ' ' I 1 1 ' I '' ' 1 1 ' ' ' I ' ' ¦ I 1 1 1 I ' 1 ' I
40 80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
100-
75-i
50-i
25-i
£
3-25-
F*
-50-.
-75-
-100-
Scan 2805 (23.951 Bin) of YP580.d
-------
Data File; /chenfl.i/09-04-97.b/YPS80.d Page 15
Date : 04-SEP-1997 20:26
Instrument : Y.i
Sanple ID ; RUK3
Coluan phase : BB-5 Cbluwt dianeter : 0.32
Volune Injected fluoranthene
Scan 3169 <26.608 mm) of YP580.d
4.0-
3.0:
2.0-
1.0:
o.o-
¦IJiXi
3,-
3.0-
2.5-
p 2.0-
O
351.5-
^1.0-
0.5-
0.0* v i
8.0-
~6.0-
to
^4.0-
|>-r.
i i i | i i i | i i i | i I
80 120 160 200 240 280 320 360 400 440 480 520
Jte§§/Chaa£_
Scan 3169 (26.608 «in> of YP580.d (Subtracted)
ft»» f i v t ^ 'i* •#vJy4'1> 'i" fr i
T | ' t I | I I I | I I
40 80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
86 Berizofluoranthene (PBH Reference Spectruw)
I ' 11 I ' 11 1 11 ' I ' ' ' I ' ' 1 ' ' ' ! ' ' 1 1 1 ' 1 I ' "'" 1 ''"' ' I ' 1 * I
80 120 160 200 240 280320360400440480520
Hass/Charge
100 T
75-=
50i
25i
i 0-1*
'-25-i
'-50-:
-754
Scan 3169 <26.608 «in> of YP580.d <2 BIFFERENCE)
II dial J, jLm.ni b>i • 4.H. *
—100 | I I I | I I I ) I I I | I I I |
Tr"
I i i i I i i i I i
I 111 1 ' 11 I
40 80 120 160 200 240 280320360400440480520
Hass/Charge
Hass 252.00
as
26.4 26.6
Tine (win.)
Mass 253.00
1 II I" I
0.0
1.4-
t ¦ ¦ i I ¦ »"¦ i'» ' ¦> '• i1
26.2 26.4 26.6 26.8 27.0
Hass 125.00
vfl
CM
0.0 'i i | i i i | » i i | i i i | i
26.2 26.4 26.6 26.8
Tine
-------
Data File; /che«/Y.i/09-le IB : RUN3
Coiuwn phase : BB-5
Volune Injected (uL) : 1.0
87 Benzo of YP580.d (Subtracted)
M
0.0 TTW|Vft
50 75 100 125 150 175 200 225 250 275 300 325 350
Hass/Charte
87 Benzofluoranthene (PBM Reference Spectru*)
0.0J *i ¦ f» i^ ifi ti n iy i 11 i 11 11 |» i"i i*) i »i 11 11'fi 111 [ i 11 11 11 11 11 11 i 11 11 i
50 75 100 125150 175 200225250 275 300325SO
Hass/Qiartre
Scan 3174 (26.645 »in> of WWO.d (Z DIFFERENCE)
DHilIh hL lil I III
100-,
75-i
50-
25|
: -25-
t
-50-
—75-i
—100 ' I |*»*l «"l ) I I M | I I I I | I I I I | I I' I 'I | I I I I | I 1 I I | I I I I | I I I I | I I I I | I I I I | I I I I ) I I I I
50 75 100 125150 175 200225250 275 300325350
Hass/Chargc
26.2 26.4 26.6
Time (win.)
26.8 27.0
Hass 253.00
9.0-
8.0
7.0
6.0
15.°'
o
tH
«24.0'
>¦
2.0
1.0
0.0
i
—
s
i
*
CM
-
-f
l fc
~
If, GO
1 f
iJVy
26.2 26.4 26.6 26.8 27.0
Time (win.)
Mass 125.00
T 0.8-
0.0 'i i i i i i i
26.2 26.4 26.6 26.8 27.0
Tine (win.)
98
-------
Data File: /chem/Y.i/09-04-97.b/YP580.d
Date : 04-SEP-1997 20:28
Instrument : Y.i
Sample ID : RUN3
Column phase : DB-5
Volume Injected : 1.0
Column diameter : 0.32
Page 25
88 Benzo(e)pyrene
Scan 3270 <27.341 nin> of YP580.d
2.4-
2.0-
1.6-
Sl.2-
X
^0.8-
0.4-
0.0-
50
l^l^l|Ujjl I l|ll|l|Htt|ll|l\li|j|l|tjll[ll|l1|lifl|l|l\l]l^ll^l| I|ll l^llj , ijl jl I, I |l ,1 , | , ] l|l ! , | |l
75 100 125 150 175 200 225 250 275 300 325
Mass/Charge
Scan 3270 <27.341 min> of YP580.d t i 'I' \ Py i
50
Ji
hh-
i1lh, f 4
'm- i-l'fi'l i'i | i ii
,'3 100 125 150 175 200 225 250 275
Mass/Charge
300 325
Benzopyrene
.
2.0-
0.0-
i i [ i i"i i"^ I'fi i'| i r'l'i1' i'i i i | i i i i} i i i i¦[ i i' i 1 i i i 'i
I I" I 'f'l1 I T
50 75 100 125 150 175 200 225 250 275 300 325
Mass/Charge
100-
75-
50-
25-
£ 0-
® -25-
-50-
-75-
-100-
Scan 3270 <27.341 min> of YP580.d <2 DIFFERENCE)
uiL a il... 11,1 all.. >¦ t1 . W J ¦ * * Ja >J..a ..ball .J J. a
.*!.> a ala a a^,, ,Ja a, a . . a
I 1 j 1 i I I I I I I j « I I I | I i I i | I I I 1 j t 1 i I ) t I 1 I ] I I 1 I j I ) 1 I ) I i 1 \ [ 1 1 I I [ I
50 75 100 125 150 175 200 225 250 275 300 325
Mass/Charge
Mass 252.00
27.20 27.30 27.40
Time (win.)
Mass 253.00
•fr—)¦ i' i [ i i i—i—p
27.20 27.30 27.40 27.50
Time (min.)
Mass 125.00
27l2o' 27^30 '27^40' * 27ls0
Time
-------
Data File: /chem/Y.i/09-04-97.b/YP580.d page 26
Date : 04-SEP-1997 20:26
Instrument : Y.i
Sample ID : RUN3
Column phase : DB-5 Column diameter : 0.32
Volume Injected (uL) : 1.0
89 Benzo-0.4
8.0-
6.0-
4.0-
2.0-
0.0-
40
ro
<
o
8.0-
.6.0-
>
! 4.0-J
2.0-
30 120 160 200 240 280 320 360 400 440
Mass/Charge
Scan 3290 <27.486 min) of YP580.d .
Wn
11™
ft
J
27.0 27.2 27.4 27.6 27.3
Time (min.)
Mass 255.00
27.0 27.2 27.4 27.6
Time
-------
Data File: /dw*/nr.i/09-04-97.b/YP580.d Page 22
Date : 04-SEP-1997 20:26
Instruwent : Y.i
Sanple ID : RUN3
CoIuni phase : DB-5 Coliwr dianeter : 0.32
Volune Injected (uL) : 1.0
93 BensEo{e,h,i>perylene
Scan 3773 (30.973 »in> of YP580.d
Mass 276.00
ri 0.6
40 80 120160 200 240 280 320 360 400
2.4-
2.0-
1.6-
ys
Sl.2-
* 0.8-
0.4-
0.0-
8.0-
.6.0-
34.0-
*~2.0'
-7Si
-100J-r*r
Scan 3773 (30.973 ««in> of YP580.d (Subtracted)
t t r I "
40 90 120 160 200 240 280 320 360 400
__i____ii__iK22s/2>jj22__^^_
93 Benzo(g,h,i)perylene (PBH Reference Spectrin*)
JL
0.0 'I <"¦ I- I -ft f I'l'l I I ' > I t" I •! I- I I "I I I I I I | I I I I I I 1 I I
40 80 120 160 200 240 280 320 360 400
Hass/Charge
Scan 3773 (30.973 Bin) of YP580.d (2 DIFFERENCE)
II! I I
' 1
40 80 120 160 200 240 280 320 360 400
Hass/Charge
0.4-
0.2-
0.0-
"tip1) f 'I !' f1 "j
30.6 30.8 31.0 31.2 31.4
Time .)
Mass 138.00
c > ©
o 1.0
Hass 277.00
i i i I i i i I i i ) I i i i I i i i I i i i I i
900
800-;
700-^
600
500
'400
300-3
200
100-;
0-=
T
30.60 30.80 31.00 31.20 31.40
Tiff? <»!".>
inJ
JLm, " <**'
-------
Project Number: 42930B
Sample File: YP581
Method 8270A MM5
Sample ID: RUN4
Tli ID: 179-98-6AC-E
DaJei Received 0&19/97
[ ;;:D^;Extmcted::a8/2S/97 .
RfiSJKHISiB;
Miiii 111
Dilution Factor: 20.00
IfPlllfilf?
ag
Naphthalene-dg
IS 2
11.74
Naphthalene
2632.85
B
11.79
200
2-Methylnaphthalene
2201.60
13.21
200
Acenaphthene-d[o
IS 3
15.35
2-Chloronaphthalene
17.86
J
14.21
200
Acenaphthylene
187.38
J
15.05
200
Acenaphthene
101.60
J
15.42
200
Fluorene
206.64
16.49
200
Phenanthrene-d
10
IS 4
18.43
Phenanthrene
1208.86
18.47
200
Anthracene
185.68
J
18.57
200
Fluoranthene
523.19
20.93
200
Chrysene-d
IS 5
23.90
Pyrene
303.27
21.40
200
Benzo(a)anthracene
117.73
J
23.89
200
Chrysene
228.82
23.95
200
Perylene-d^
IS 6 High
27.63
Benzo(b)fluoranthene
53-41
J
26.60
200
Benzo(k)fluorandiene
23.01
J
26.66
200
Benzo(e) pyrene
28.92
J
27.34
200
Benzo(a)pyrene
11.63
J
27.48
200
Perylene
U
3.18
200
Indenof 1,2,3-cd)pyrene
u
2.54
200
Dibenz(a,h)anthracene
u
3.51
200
Benzo(g,h,i) perylene
u
2.80
200
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; B Estimated- Above Calibration Range
Triangle Laboratories of RTP, Inc. Savar v3.5
801 Capitola Drive • Durham, North Carolina 27713 Printed: 15:39 09/12/1997
Phone: (919) 544-5729 • Fax: (919) 544-5491 ^
-------
Project Number 42930B
Sample File: YP581
Method 8270A MM5
Sample ID: RUN4
Client Project:
TU ID: 179-98-
Iron & Steel-Y)
Dilution Factor. 20.00
Amount
Mate
%REC
Anthracene-d
Pyrene-d
Reviewed by.
Date
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTP, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.5
Printed: 15:39 09/12/1997
r\
J
10
-------
Data File; /chem/Y,i/09-04-97,b/YP58i,d
Date : 04-SEP-1997 21;11
Instrument : Y.i
Sample ID I RUN4
Column phase : B8-5
Volume Injected (uL> : 1.0
Page 9
Triangle Uboratortes
CoIum0liHf#r'^C* 0.32
• r
o
/chem/Y,i/09~04~97.b/YP581.d (Part 1 of 2)
3.3
3.2^
341
3.0
2.9-i
2.8-j
2.7 i
2M
2.5
2.4-:
2,3-=
2.2*3
2.ii
2.01
1.9-1
1.8
^1.7i
°jl.6i
'l.5i
1.41
1.3-i
1.2-1
1.1
1.01
0.9-i
0.81
0.7":
0.6-i
0.5-:
0.4-j
0.3-i
0.2-^
0.1
0.0
X J I I lllllJJv
YR^rl*Te:,M'i i 1 |—i i t* T j—r~—r~
o
tH
ro
rH
*T3
o
i
ro
a;
c
o
au
x~i
Kl
"NX
C
in
_Q
I
O
t.
I
o
1 C
1 ^
_c
I N
u
1 c
1
I
1—
1 °
IT)
1 t-
1 i
I -H I
li
1 Z N
l T~~
Li
j i T" i ¦ t—j—r
10 11
Time €mim>
r--
CO
(T>
3)
c
JZ
a.
*p~4
S3
a
L.
O .
3 j
"13
£
JZ
+->
JZ
a
§
Bo
q a
4
"¦ i
13
' 1 I
14
15
-r~
16
_r-
17
—5—
18
-------
Data File: /cliem/Y.i/09-04-97,b/YP581.d
Date : 04-SEP-1W 21:11
Instrument : Y.i
Sample ID : RUN4
Column phase : DB-5
Volume Injected : 1.0
Page 10
Triangle Uiwraterigg
of RTP, Inc.
Column diameter : 0.32
\o
o
/chem/Y.i/09-04-97.b/YP581.d (Part 2 of 2>
ol
ro
r>-
ZT)
C
01
_c
Q_
O
O
CT>
"O
I
c
o
_c
<_)
ID I
-MvW W\Jv\
KB
r>-
cnj
I 1 1—1 1 I
19 20
21
22
' i
23
24
I 1 1 1 1 I
25 26
Time (min.)
27
28
29
30
31
32
33
-------
Data File: /chem/Y. i/09-04-97 .b/YP581 .d
Report Date; 05-Sep-1997 07:13
Page 1
TRIANGLE LABORATORIES, INC.
Data file
Lab. Id.
Inj Date
Operator
Smp Info
Misc Info
Comment
Method
Meth Date
Cal Date
Als bottle
Dil Factor
Integrator
Sample Type
SEMI-VOLATILE QUANTITATION REPORT
/chem/Y. i/09-04-97,b/YF581.d
42930B
04-SEP-1997 21:11 Autotune Date: 06-Sep-99 14:30:1
DD Inst ID: Y.i
RTJN4
179-98-6AC-E
/chem/Y. i/09-04-97.b/cclist.m
04-Sep-1997 14:21 target
04-SEP-1997 13:32
10
20.000
HP RTE
: AIR
Cal File: YP571.d
Target Version: Target 2.20
Compound Sublist: pab.sub
CONCENTRATIONS
QUANT SIQ
OH-COLUMN
PXNAl
Compound*
MASS
RT
12
1,3, 5-Trichlorob«nz»n«-d3
185.00
10.986(0.935)
86343
4.58
91-SKa)
13
l,4-Dlbroaob«nz*n«-d4
239.80
11.853 El.282)
75728
6.46
129.10 la!
14
2 - Fluor ob iph«xiy 1
172.00
13.987(0.911)
196674
4.54
90.86(a)
IS
2,4,6-Yribre®oph«no 1
329.80
16.989 (1.107)
44579
6. 04
120,7S (a)
IS
Anthrac«n»-dl0
188.00
18.537 (1.006)
240456
4.08
81.54(aQ)
IT
Pyr«n«-dl0
212.00
21.361(0.8943
286006
4.40
88.08(a)
18
T«rph«nyl-dl4
244.00
21.$73(0.911)
1727
0.05
0.95UQR)
42
Naphthalan#
128.00
11.788(1.004)
6184760
131.69
2633.8S
46
2-M«thyln*phth*l«n*
142,00
13.213(1.125)
3590373
110.14
2202.80
SO
2-Chloronaphthal«n«
162.00
14.211(0.9263
34312
0.89
17.86(aQ)
55
Ac«n*phthyl«n«
152.00
15.054(0.981)
563531
9.37
187.43(a)
S8
Ac«naphtJi*n«
154.00
15.416(1.0043
169797
5.08
101.60(a)
65
Fluor«n«
166.00
16.486(1.0743
413443
10.33
206.58
73
Ph*nanthr«n«
178,00
18.471(1.0023
3717138
60.43
1208.59
74
Anthra.c«n«
178.00
18.574(1.008}
531024
9.28
185.67(a)
77
Fluora&thain*
202.00
20.934(1.136)
1356347
26.16
523.27
78
Pyz«m
202.00
21.398(0.8953
1044320
IS. 17
303.31
83
B
-------
Data File: /chem/Y.i/09-04-97.b/YP581.d
Report Date: 05-Sep-1997 07:13
Page
Compound*
QUANT SIQ
MASS
RT (RZL RT)
CONCENTRATIONS
ON-COLUMN FINAL
RESPONSE ( ng) ( ug)
252.00
252.00
252.00
>sai se-
ra nn
26.663(0.965)
27.342(0.989)
27.481(0.994)
71556
93881
34659
—D170-
—aaai
Compound Not D«tact«d.
37G; 00 3fl.9M (1.13111)
1.15
1.45
0.58
U.UB"
r*4-
87 B«nzo (k) £luoranth«n*
88 B«nzo(•)pyr«n®
89 B«ozo(a)pyr«n«
90 P*ryl«n«
91 Indano(1,2,3-cd)pyr«n«
92 Dibanz(»,h)anthrac«n*
93 B«o2o(g,h,i)p«ryl*n*
QC Flag Legend
a - Target compound detected but, quantitated amount
Below Limit Of Quantitation(BLOQ).
Q - Qualifier signal failed the ratio test.
R - Spike/Surrogate failed recovery limits.
23.03 UQ)
28.91(a)
11.63(a)
—a.o«(ao)
107
-------
Data File: /chem/Y.i/09-04-97.b/YP581.d
Date : 04-SEP-1997 21:11
Instrument t Y.i
Sample ID ; RUN4
Column phase : DB-5
Volume Injected (uL> : 1.0
42 Naphthalene
Page 11
Column diameter : 0,32
Scan 1129 <11.788 min) of YPSBl.d
Mass 128.00
t f | i r i | "vmrf ^ i » ¦r-yi—rmt | r"i i ] t t r y t ¦r-r | » "tt
80 120 160 200 240 280 320 360 400 440 480
Mass/Charsre
Scan 1129 <11.788 min) of YPiil.d (Subtracted)
[ ¦ ¦ ¦ i ¦ - - i
11.40 11.60 11.80 12.00 12.20
Time -
2.0-
0.0
'l 1 I I I 1 I I I
1—I I" I "I 'I ft I I I I I !¦" r ! I | 1 I I—| I I I | I I I | I I I [ I I I | I I 1 ) I I I
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charee
100-
75-
50-i
25-
& °"
® -25-
-50-
-75-
-100-
Scan 1129 <11.788 min) of YP581.d <2 DIFFERENCE)
40
T
i i |
T
T
T
80 120 160 200 240 280 320 360 400 440 480
Mass/Charge
>-1.2-
11.40 11.60 11.80 12.00 12.20
Time (win.)
4.8-
4.4-
4.0-
3.6-
3.2-
— 2.8-
LO
o2.4-
*2.0-
>-1.6-
1.2-
0.8-
0*4-
0.0-
Mass 127.00
CD
AV-
|t'wn|,f*n | r t*7*"i
11.40 11.60 11.80 12.00 12.20
Time (win.)
108
-------
Data File: /chem/Y.i/09-04-97.b/YP581.d
Date : 04-SEP-1997 21:11
Instrument : Y.i
Sample ID : RUN4
Column phase : DB-5
Volume Injected
-------
Data File: /chem/Y.i/09-04-97.b/YP581.d Page 13
Date : 04-SEP-1997 21:11
Instrument : Y.i
Sample ID : RUN4
Column phase : DB-5 Column diameter : 0.32
Volume Injected : 1.0
50 2-Ch1oronaphtha1ene
Scan 1464 <14.211 min) of YP581.d
^3.0-
o
1.0-
0.8-
£0.6-
O
;«.4.
0.2-
0.0
40
8.0-
.6.0-
<
©
34.0-
>"*
2.0-
0.0-
100-
75-
50-
25-
Sfc °"
«-25-
**
-50-
-75-
-100-
l T 'f" 1
x
-+-1-
i ¦». ; 1 ¦
' 1 1 111 ¦ 1 1
120 160 200 240 280 320 360 400 440
Mass/Charge
Scan 1464 <14.211 min) of YP581.d I lii I.11 1 1
! 1 i
| > i t | 1 1 1 ) I111 T"'» ) r t '» | '"l
r [ 1 | |
40 80 120 160 200 240 280 320 360 400 440
Mass/Charge
Mass 162.00
13.30 14.00 14.20 14.40 14.60
Time (win.)
Mass 127.00
6.0-=
5.5-i
5.0
4.5
4.0-|
5 3.5
<23,0-;
3 2.5-j
2.0-i
1.54
i.o4
0.
0.0-
r I'-p-i—1'T-| 1 r 1 'q-i1 1 » [ •i
13.80 14.00 14.20 14.40 14.60
Time
-------
Data File: /chem/Y.i/09-04-97.b/YP581.d
Date : 04-SEP-1997 21:11
Instrument : Y.i
Sample ID : RUN4
Column phase : DB-5
Volume Injected (uL> : 1.0
Column diameter
0.32
Page 14
56 Acenaphthylene
Scan 1580 (15.054 min> of YP581.d
2.
2.
2.
;i.
I1-
>Io.
o.
0.
3
4
0
6
2-.
8-;
4-:
0-
-h
J'ml f'T'T'l' t | I I I fT' l'l1
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charge
Scan 1580 <15.054 min> of YP581.d (Subtracted)
4-
¦j*'r*i'p | 11 r' J | ft i"f rr -i p't1 i | i i i | i r r j i i
40
80 120 160 200 240 280 320 360 400 440 480
Mass/Charge
56 Acenaphthylene (PBM Reference Spectrum)
8.0-
.6.0-
>
'?4.o-|
2.0-
0.0-V+
i 1^1 'i V i—j"'i i—1 —]—i—i—i—|—i—i—i—[—i—i—i—|—i—r-i—| i i—i | i i—i | i—:—i—]—i—i—r-
I 1 ' '
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charge
100-q
75-j
50-i
25j
0-
«-25-l
N :
-50-j
-75-1
-100-
Scan 1580 (15.054 min) of YP581.d (Z DIFFERENCE)
jJu
1 ¦¦ —I l.i .. .
'I 1 1 ' I 1 11 I 1 ' ' I 1 11 1 ' 11 I ' ' 1 I 1 1 ' I 1 11 I ' ' ' I
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charge
Mass 152.00
4UAA
14.6 14.3 15.0 15.2
Time (min.)
Mass 151.00
.6 14.8 15.0 15.2 15.4
Time (min.)
Mass 153.00
.6 14.8 15.0 15.2
Time (min.)
15.4
111
-------
Data File: /chem/Y.i/09-04-97.b/YP581.d Page 15
Date : 04-SEP-1997 21:11
Instrument : Y.i
Sample ID : RUN4
Column phase : DB-5 Column diameter : 0.32
Volume Injected i | i i i |—i-1 r
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charge
100-
75-
50-
25-
¦ 0-
<=-25-
-50-
-75-
-100-
Scan 1630 (15.416 min) of YP581.d (Z DIFFERENCE)
* " 1
I 1 ' 1 I
« I 1
T
"I" 1 11 I
-p-i—i j | i
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charge
Mass 154.00
15.0 15.2 15.4 15.6
Time (ruin.)
15.8
Mass 153.00
15.2 15.4 15.6
Time (win.)
Mass 152.00
f 1.5
15.2 15.4 15.6
Time (min.)
112
-------
Data File: /chem/Y.i/09-04-97.b/YP581.d
Date : 04-SEP-1997 21:11
Instrument : Y.i
Sample IB : RUN4
Column phase : Bl-5
Volume Injected (uL> : 1.0
Column diameter : 0.32
Page 16
65 Fluorene
Scan 1777 <16.486 min) of YP581.d
f | 1 i -'i* i j—i—r-t—f—r
200 240 280
Mass/Charge
" I'"' ' ' I 1 1 1 I '
320 360 400
440
Scan 1777 <16.486 win) of YP581»d Subtracted)
o 1.0
200 240 280
Mass/Charge
320 360
1 i '
400
440
65 Fluorene CP1M Reference Spectrum)
8.0-
6.0-
4.0-
2.0-
0.0-
4—4—J 1 H—t—| i I—i—^ i—r
> ''""T' i I ' ' ' I ' J ' I i 1 '' I ' 1 1 I 1
40 80 120 160 200 240 280 320 360 400 440
Mass/Charge
100-
75-
50-
25-
£ 0-
= -25-
-50-
-75-
-100-
Scan 1777 <16.486 min) of YP581.d <2 DIFFERENCE)
j. j
pj.iL i-L-1 L...
.1
40
T { f I t | g t !
80 120
160
1 1 ' 1 ' I 1 1 1
200 240
Mass/Charge
320 360 400 440
Mass 166.00
rv.
r^
o
o
CO ^
vp
O.O^f
16.00
. s ^ V
\J
i 'r I '< i i i i i i i i i i
I ' 1 ' ! ' 1 1 I 1 1 1 I
16.20 16.40 16.60 16.30
Time (win.)
Mass 165.00
CD rO
o.o^r
16.00
I 111 I 1 11 I ' 11 i
16.20 16.40 16.60 16.£
Time (win.)
Mass 167.00
t | I f » '"I
16.00 16.20 16.40 16.60 16.80
Time (min.)
11
-------
Data File: /chem/Y.i/09-04-97.b/YP581.d
Date : 04-SEP-1997 21:11
Instrument : Y.i
Sample ID : RUN4
Column phase : DB-5
Volume Injected '» f '"T"
80 120 160 200 240 280
Mass/Charge
T
T
T
320 360 400 440
T
480
100-
75-
50-
25-
:
<=-25-
-50-
-75-
-100-
Scan 2049 <18.471 min> of YP581.d <2 DIFFERENCE)
; i t t—| 11 i
-l—| i11 Ml i—|—r~
T
—i—i—i | i i » |
40 80 120 160 200 240 280 320 360 400
Mass/Charge
' I"' ''' I
440 480
Mass 178.00
2.0-:
1 T
1.8-
CO
—1
1.6-;
1.
-------
Data File: /che«/Y.i/09-04~97.b/YP581.d
Date : 04-SEP-1997 21:11
Instrument : Y.i
Sample ID : RUN4
Column phase : BB-5
Volume Injected (uL> : 1.0
Column diameter : 0.32
Page 18
74 Anthracene
2.8-
2.4-
2.0-
£n 1,6-
|l.2-
>- 0.3-
0.4-
0.0-
40
^llJ
80 120
Scan 2063 (18.574 min> of YP581.d
200 240 280
Mass/Charge
Scan 2063 <18.574 min) of YP581.d (Subtracted)
2.4-
2.0-
-1.6-
LO
S1.2:
X
0.4-
0.0-
T~i
40
^"f ^1
1^1 .il«j i
120 160
A
4-4-
i - ' ' 1 ' ' t ¦
200 240 280
Mass/Charge
320 360
! '
400
—I—r
440
74 Anthracene (PBM Reference Spectrum)
8.0-
-6.0-
rr>
§4.0-
>-
2.0-J
0.0
1r+-
40
"i ^ 1 ^
4-
| j 11 'J"1 1—f r 11'1—1—1—t -—1—|—1—1—r—j—r-
80 120 160 200 240 280 320 360 400 440
Mass/Charge
100
75
50
25
-------
Data File: /chetn/Y»i/09-04-97.b/YP581.d Page 19
Date : 04-SEP-1997 21:11
Instrument : Y.i
Sample ID : RUN4
Column phase : DB-5 Column diameter : 0.32
Volume Injected : 1.0
77 Fluoranthene
Scan 2367 (20.934 rain) of YP581.d
7.0-
6.0-
5.0-
ui 4.0-
S3.0-
>- 2.0-
1.0-
0.0-
I
fLlf' ]"i '1 f~ ja i ryi r
40 80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
7.0-
6.0-
5.0-
;4.o-
^5.0-
s--
^2.0-
1.0-
0.0-
Scan 2367 <20.934 mm) of YP581»d (Subtracted)
1^
.» p,... H ^ y,, > r | i11'i ) 1 1 1 | 1 1 t | 1 1 1 | 1 i i | 1 1 1 ( 1 1 1 |
40 80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
77 Fluoranthene (PBM Reference Spectrum)
8.0-
.6.0-
<
o
34.0d
>*
2.0-
0.0-
f-f-
40
[III P"I t I 1 1 '' ' I 1 1 '' ! I 1 1 I I 1 . I 1 ' 1 ! . ¦ 1 1 I 1 ' 1 ' 1 I ( '
80 120 160 200 240 280 320 360 400 440 480 520
liass/Charge
100-
75-
50-
25-
: 0-
a-25-
**
-50-
-75-
-100-
Scan 2367 <20.934 min) of YP581.d (2 DIFFERENCE)
"T"
r-t-
40
T
1 1 1 I i 1 r I 1 (
T
120 160 200 240 280 320 360 400 440 480 520
liass/Charge
Mass 202.00
20.6 20.3 21.0 21.2 21.4
Time (win.)
Mass 101.00
'> ¦» 1 | » 1 » p"»"ri i 1 rr"fi'TT
20.6 20.8 21.0 21.2 21.4
. Time (min.)
Mass 100.00
1.2-
1.1-
1.0-
0.9-
0.8-
~0.7-
go.6-
*0.5-
=-0.4-
0.3-
0.2-
0.1-
0.0-
I—oc
I
20.6 20.8 21.0 21.2 21.4
Time (min.)
118
-------
Data File: /chem/Y.i/09-04-97.b/YP581.d
Date : 04-SEP-1997 21:11
Instrument : Y.i
Sample ID : RUN4
Column phase : DB-5
Volume Injected (uL) : 1.0
Column diameter : 0.32
Page 20
78 Pyrene
Scan 2430 (21.398 min) of YP581.d
5.0-
4.0-;
ID
3.0-
O
-
X
2.0-;
I
1.0-
0.0-
40
80 120 160 200
n~
240 280 320
Mass/Charge
360 400 440 480 520
Scan 2430 <21.398 min) of YP581.d (Subtracted)
5.
4.
?3.
o
£2.
>-
1.
1 t l1*!^
Jr
>¦
At4-
u
40
30 120 160 200
240 280 320
Mass/Charge
1 I 1 ' ' I 1
360 400
1 I 1
440
1 I 1 11 I 1
480 520
78 Pyrene (PBM Reference Spectrum)
8.0-
-6.0-
ro
34.0-
^2.0-
0.0
'1'f ''1^ r r1 ¦11|L|
111
1 I 1 1 1 1 1 1 1 1 1 1
40
80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
100-
75-
50-
25-
£ 0-
= -25-
-50-
-75-
-100-
Scan 2430 (21.398 min) of YP581.d (Z DIFFERENCE)
L...
f rr'T]1! 1 i yiTT)1 i i r | t T" t1 | ri'T'yi i i | » i \ | I'T'fp'i » | i » » ) » » i | »
40 80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
Mass 202.00
x 3.0-
I 1 11 I 1 1 1 I : 1 ' I 1 1 1 I
21.00 21.20 21.40 21.60 21.30
Time (min.)
Mass 101.00
' I ' 1 1 I ' 1 1 I 1 1 1 I 1 1 ' I
21.00 21.20 21.40 21.60 21.80
Time (min.)
Mass 100.00
k 0.6
0.4
21.00 21.20 21.40 21.60 21.80
Time (min.)
-------
Data File: /chem/Y.i/09-04-97.b/YP581.d Page 21
Date ; 04-SEP-1997 21:11
Instrument : Y.i
Sample ID : RUN4
Column phase : DB-5 Column diameter : 0.32
Volume Injected (uL) : 1.0
83 lenzo(a)anthracene
Scan 2768 (23.885 mm) of YP581.d
s-1.0
i i 11 « > i | i i i—j i i i j i i—i j i i i | > ) i (
80 120 160 200 240 280 320 360 400 440 480 520
Hass/Charge
Scan 2768 (23.885 min) of YP581.d (Subtracted)
1.0-
0.8-
.0.6-
in
<
o
3°.4-
>-
0.2-
0.0-
¦f-hh-
U iiii| i
40 80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
83 Benzo(a)anthracene (PBIi Reference Spectrum)
8.0-
.6.0-
ro
<
o
^4.0-
2.0-
0.0-
t-+
40
f' T1 j'^l j j I
"+J
, r ]' i l r | i i I i' i'i i ^ i n | i I i""| i i i | i i i [ i i i | i r i [' i i i | i i i | i
80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
100-q
75-i
50i
25 j
¦ 0-. • -*¦
«-25-i
N
-50-=
-75-i
-100
Scan 2768 <23.885 min) of YP581.d <2 DIFFERENCE)
*, jikjlJl.,..
• il _
40
T
t t i I—i r > [
I ' ' ' I
80 120 160 200 240 280 320 360 400 440 480 520
Hass/Charee
Mass 228.00
23.6 23.8 24.0
Time (win.)
Mass 229.00
"I1"! t I | »
<3 2.5
23.6 23.8 24.0
Time (min.)
Mass 226.00
6.0-;
5.51
5.0-j
4.51
4.0
£3.5^
~2.5^
5"2.0
1.5'
1.0-
0.0-
in
CD
GO
~
r-o
CM
—<33
LD
N")
CSJ
0*5*= r—
23.4 23.6 23.8 24.0 24.2
Time (win.)
lis
-------
Data File: /chem/Y.i/09-04-97.b/YP581.d
Date : 04-SEP-1997 21:11
Instrument : Y.i
Sample ID : RUN4
Column phase : DB-5
Volume Injected (uL) : 1.0
Column diameter : 0.32
Page 22
84 Chrysene
Scan 2777 <23.951 min> of YP581.d
240 280 320
Mass/Charge
Scan 2777 <23.951 min> of YP581.d (Subtracted)
1.6-
1.4-j
1*2i
1.0-i
0.3-i
0.6-1
0.4-;
0.2-i
0.0
J
MfH*'
"Mi
I1 1 s r '-'l I ' 11 I ' r rl 1 '"I I 1 1 I I i i I I i 11 I i 1 1 '| I-
40 80 120 160 200 240 280 320 360 400 440 480 520
Hass/Charge
84 Chrysene (PBM Reference Spectrum)
8.0-
6.0-
4.0-
2.0-
0.0-
li
J
I ' 1 1 I ' I' ' ' ' 1 T 1 1-1 I 11 1 I ' 1 1 I 1 1 ' I ' 1 1 I ' 1 1 I ' 11 I ' 1 ' I
40 80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
100-
75-
50-
25-
: 0-
= -25-
-50-
-75-
-100-
Scan 2777 <23.951 min) of YP581.d -
2.0t
1.5-:
1.0-=
0.5":
0.0-
Mass 226.00
|—1CD
J ID
0s
ro
CM
i \ j'T ¦» i | i i i "r i i | i i i | i
23.6 23.8 24.0 24.2 24.4
Time_^;igi2=
Mass 229.00
5.0-1
J IT>
-
1.5-:
l.o-i
0.5-f
0.0-
i I | r i i -1 ¦ it
' I '
23.6 23.8 24.0
Time (min.)
1 I 1 1 1 I 1
24.2 24.4
113
-------
Data File: /che./Y.i/09-04-97.b/YP581.d
Bate : 04-SEP-1997 21:11
Instrument : Y.i
Sanple IB : RUN4
Coluwi phase : DB-5
Volume Injected of YP581.d
IiMmU
i^-i If'f i i ) t \ | i i ¦ | > ¦¦¦
120160 200 240 280 320 360 400 440 480 520
Scan 3139 <26.604 *in> of YP581.d (Subtracted)
3.5
3,0-i
2.5 i
72.0-1
o :
^1.5-=
s/ ;
>-1.0-;
0.5-=
0.0
il
> ft 4'4*1*1' »• i fcf »-i I'lM i J
) ¦ I 1 I ¦ I ¦ I . ¦ .'I'l'Wfl I * ) "I'| i I'l'l'l'i I ii'fi i I I I l i 1 I I I I I
40 80 120160200 240 280320360400440480520
Hass/Charge
86 Benzo(b)fluoranthene (PBH Reference Spectru*)
PO
<
o
¦54.0-
"2.0-
0.0-
40
90 120 160 200 240 280 320 360 400 440 480 520
Hass/Charge
100-g
75-1
50-i
25
*: 0-jj
s-25-
M
-50-;
-75-!
-100-
Scan 3139 (26.604 min) of YP581.d •1.6-;
1.2-1
0.8-
0.4-
0.0-
1 t*! y*i r) i i i | \
26.2 26.4 26.6 26.8 27.0
Tine (»in.>
Hass 253.00
tfffc*t*fr
26.2 26.4 26.6 26.8 27.0
Tine (win.)
Hass 125.00
"I > i" i | ii i | i
26.2 26.4 26.6
Tine (win.)
'I ' 11 1 1
26.8 27.0
120
-------
Data File: /chem/Yu/09-04-97.b/YP581.d
Date ; 04-SEP-1997 21:11
Instrument : Y.i
Sample ID : RUN4
Column phase : DB-5
Volume Injected : 1.0
Column diameter : 0.32
Page 24
87 Benzo of YP581.d
Mass 252.00
f> 2.0
>-1.0
lybaji
ll
240 280
Hass/Charge
Scan 3147 <26.663 win) of YP581.d ^ i' 1*1 | i i [ i'i i"; i i'i1 "|'i r"T )'i "i "i j i i i | i i i | i i
40 80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
100-
75":
50-
25-
5£
-------
Data File: /chen/Y.i/09-04-97.b/YP581.d
Date : 04-SEP-1997 21:11
Instrument : Y. i
Sample ID : RUN4
Column phase : DB-5
Volume Injected :
o3.°"
^2.0-;
1.0-
0.0 T1'** Afi1"! t
A-
T'K-1'1 )¦! ¦¦ r tt f, [4 I 1- f I¦ I . I"! ' l'| I I ! ; I
40 80 120 160 200 240 280 320 360 400
Mass/Charge
440 480 520
Scan 3240 <27.342 min) of YP581.d Subtracted)
4.0-
_ 3.0-
ifi
s 2.0-3
>-
1.0-
1^1 ^' 1-^ I
0.0 f f j 'i' t 'f ^ i ^—j—r-i—r ) 'I i "( | i'i i | "i—t i" | i—i—i T ;—i—i | i t i |—i—i—r-p
40 80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
88 Benzo•
0.4-
0.2-
0.0-
UV
t ' 'i r't—i" »"T*
27.20 27.30 27.40 27.50
Tiwe
-------
Data File: /chem/Y.i/09-04-97.b/YP581.d
Date : 04-SEP-1997 21:11
Instrument : Y.i
Sample ID : RUN4
Column phase : DB-5
Volume Injected (uL) : 1.0
Column diameter
0.32
Page 26
89 Benzo -
2.0-
0.0—r
40
( r i't—i i | i i i ^ 'i—At—|-^ L
i i | i i—i—f—!—r—i—|—n—i | i—i i |—r-i—i—j—p-i—i—]—r
120 160 200 240 280 320 360 400 440 480 520
Hass/Charge
100
75-
504
25i
:
= -25H
-50-;
-75H
Scan 3259 <27.481 min) of YP581.d <2 DIFFERENCE)
il.l ..IJjy.laJiJ.ly Ilk i ll. 1..41 id.ill.Li .UJ^k. i til ill In ,n
I . i
-100 —i—i—i ) »—i i |—i—r-i—[—i—i—i—[—1—i—i—|—i—n—[--!—i i | i i i—| i i i—|—i—i—t—|—i—i—i | i i i—]—r
40 80 120 160 200 240 280 320 360 400 440 480 520
Hass/Charge
Mass 252.00
min,)
Mass 253.00
27.2 27.4 27.6
Time
-------
I
Method 8270A MM5 |
Sample ID: RUNS
Project Number 42930B
Sample File: YP596
Pient Project: Iron & Steel-Yt
Date Analyzed: 09/05/97
Dilution Factor 20.00
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Amoimt
ng
FLAG
RT
Defc Limit
m^
Naphthalene-d^
IS 2
11.56
Naphthalene
2965.67
B
11.61
200
2-MethyInaphthalene
2284.46
13.02
200
Acenaphthene-dio
IS 3
15.15
2-Chloronaphthalene
U
7.50
200
Acenaphthylene
238.95
14.86
200
Acenaphthene
127.47
I
15.22
200
Fluorene
289.91
16.29
200
Phenanchrene-d
10
Phenanthrene
IS 4
18.22
1765.05
18.27
200
Anthracene
345.94
18.38
200
Fluoranthene
887.81
20.73
200
Chrysene-d^
IS 5
23.69
Pyrene
356.63
21.19
200
Benzo(a)anthracene
140.32
J
23.67
200
Chrysene
209.79
23.74
200
Perylene-d^
IS 6 High
27.31
Benzo(b)fluoranthene
57.11
J
26.27
200
Benzo(k)fluoranthene
7.76
J
26.35
200
Benzo(e) pyrene
24.95
J
27.03
200
Benzo(a)pyrene
16.29
J
27.14
200
Perylene
U
3.81
200
Indeno( 1,2,3-cd)pyrene
u
2.83
200
Dibenz(a,h)anthracene
u
3.77
200
Benzo(g,h,i) perylene
u
2.93
200
NA- Not Applicable; Det Limit: Detection Limit; Quart. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTP, Inc.
Ml Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax (919) 544-5491
Savar v3.5
Printed: 16:00.09/12/1997
124
-------
Eastern Research Group
Project Number 4293QB
Sample File: YP596
Method 8270A MM5
Sample ID: RUNS
Client Project: Iron & Steel-Yt
...: Date Received: 08/19/97 '¦ ¦, : Res;
SWlliSilfilli'
Dilution Factor: 20.00
, Ajapi^||I| 1 , ¦ RX i ISRef
Anthracene-d
to
Fvrene-d
10
111.43 18.34
84.09 21.15
4 111
5 84
Reviewed by.
Date_2jJ2j3!%
NA- Not Applicable; Det Limit; Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTP, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 ~ Fax: (919) 544-5491
Savar v3.5
Printed; 16:00 09/12/1997
123
-------
Data File: /chen/Y.i/09-05-97,b/YP5%.d
Date : 05-SEP-1997 13:03
Instrument : Y.i
Sample ID : RUNS
Column phase : DB-5
Volume Injected : 1,0
Page 9
Triangle laboratories
ot RTP, inc.
Column diameter : 0.32
CO
Ol
1,2
1.1
1.0
0,9-
0,8-
0.7-
<
o
*0.6-
0.5-
0.4-
0,3-
0,2-
0.1-
0.0 'TT|
/chem/Y, i/09-05-97,b/YP596.d (Part 1 of 2)
a>
|4-
o
"lO"
©
« ..
5 M
Q Q
10 11
Time (win.)
-------
Data File: /ehen/Y.1/09-05-97.b/YP5%,d
Date : 05-SEP-1997 13:03
Instrument : Y.i
Sample ID : RUH5
Column phase : DB-5
Volume Injected
-------
Data Pile: /chem/Y.i/09-05-97.b/YPS96.d
Report Date: 05-Sep-1997 14:18
Page 1
TRIANGLE LABORATORIES, INC.
Data file
Lab. Id.
Inj Date
Operator
Smp Info
Misc Info
Comment
Method
Meth Date
Cal Date
Als bottle
Dil Factor
Integrator
Sample Type
SEMI-VOLATILE QUANTITATION REPORT
/ch.em/Y. i/09-05-97 ,b/YP596 .d
4293 OB
05-SEP-1997 13:03 Autotune Date: 06-Sep-99 14:30:1
DD Inst ID: Y.i
RUN 5
179-98-7AC-E
/cbem/Y.i/09-05-97.b/cclist.m
05-Sep-1997 08:40 target
05-SEP-1997 07:53
7
20.000
HP RT1
: AIR
Cal Pile: YP589.d
Target Version: Target 2.20
Compound Sublist; pah.sub
Compound*
QUANT SZQ
KASS
CONCENTRATIONS
ON-COLUMN FINAL
RT (RKL RT) RESPONSE
tag)
ug)
1
l,4-Dichlorobenzene-d4
152.00
9.073 (1.000)
453294
*
o
o
o
~
2
Naphthalene-d8
136.00
11.563(1.000)
1499507
40.00
•
3
Acenaphthene-dlO
164.00
15.154(1.000)
998934
40.00
~
4
Phenanthrene-dlO
188.00
18.220(1.000)
1506177
40.00
•
5
Chryaene~dl2
240.00
23.686 £1.000)
1643996
40.00
•
6
Perylene-dl2
264.00
27,310(1.000)
2175724
40.00
$
7
2-Fluoropheaol
112.00
6.613 CO.729)
5271
0.45
9.03CaQR)
%
8
Phenol-d5
99.00
8.428 (0 »929)
91335
5.31
106.15(a)
$
9
2-Chlorophenol-d4
132.00
8.972(0.989)
280
0.02
0.42 CaQR)
$
10
1,2-Dichlorobenzene-d4
152.00
9.402(1.036)
603
0.06
1.22CaQR)
$
11
Nitrob«nzene-d5
82.00
10.140(0.877)
79860
S. 67
113.49(aQ)
%
12
1,3,5-Trichlorobenzene-d3
185.00
10.808<0.935)
60382
4.48
89.63(a)
$
13
1,4-Dibromob enzene - d4
239.80
11.671(1.286)
53677
6.09
121.84(a)
$
14
2-Fluorobipheny1
172.00
13.796(0.910)
146401
4.77
95.42(a)
$
IS
2,4, 6-Tribroiaophenol
329.80
16.783(1.107)
31844
6.35
127.01 (aQ)
s
16
Anthracene-dlO
188.00
18.336(1.006)
206856
5.57
111.42(aQ)
$
17
Pyrene-dlO
212.00
21.149(0.893)
223448
4.20
84.08(a)
$
18
Terphenyl-dl4
244.00
21.573C0.911)
621
0.02
0 .41 (aQR)
42 Naphthalene
128.00
11.606(1.004)
5286416
148.32
2966.49
46
2-Methylnaphthalene
142.00
13.024(1.126)
2851783
114.28
2285.63
50
56
2-Chloronaphthalene
Aceaaphthyleae
i£2.Qn
152.00
, ii.oimo.ius) 1
14.865 <0.981)
.3 bxa i
476489
IX.95
239.01
58 Acenaphthene
154.00
15.219(1.004)
146121
6.38
127.53(a)
65
Fluorene
166.00
16.290(1.075)
382276
14.50
290.01
73
Pheaanthrene
178.00
18.270(1.003)
3495895
88.26
1765.23
74
Anthracene
178.00
18.379(1.009)
625262
17.29
345.78
77
Fluoranthene
202.00
20.725(1.138)
1434139
44.37
887.34
78
Pyrene
202.00
21.185C0.894)
1050203
17.83
356.66
83
Benzo (a) anthracene
228.00
23.672C0.999)
294979
7.02
140.35(a)
84
Chryaene
228.00
23.738(1.002)
423780
10.49
209.88
86
Benzo (b) fluoranthene
252.00
26.267(0.962)
150670
2.86
57.11(a)
Data Review;
Date:
123
-------
Data File: /chem/Y.i/09-05-97.b/YP596.d
Report Date: 05-Sep-1997 14:18
Page 2
CONCENTRATIONS
QUANT sia
ON-COLTJKN
FINAL
Compound®
MASS
RT (RKL RT)
RESPONSE
( ng)
C ug)
87
B«nzo(k)£luor*nth«n«
252.00
26.354C0.9fi5)
19699
0.39
7.76U)
88
Banzo{«)pyr«n«
252.00
27.027C0.990)
68257
1.25
24.94{«Q)
89
90
91
B«nzo(«)pyr«ra«
P«ryl«n«
Ind*no(1,2,3-cd)pyr«n®
252-00
•fS •> nn
27.143 £0.994)
40349
0.81
16.29 (a)
J. » v i v«*J
U. U5
92
Dib*nz(a,h) »nthrmc«ii«
Compound Not D<*t«ct«d.
93
B«nzoCg,h,i)p«ryl*n«
Compound Not D«t«ct«d.
QC
Flag Legend
a -
Q -
R -
Target compound detected but, quantitated amount
Below Limit Of Quantitation(BLOQ).
Qualifier signal failed the ratio test.
Spike/Surrogate failed recovery limits.
f>QJ3 ?//oJ?f
-------
Data File: /chew/Y.i/09-05-97.b/YP596.d
Date : 05-SEP-1997 13:03
Instrument : Y.i
Sample IB : RUN5
Column phase : DB-5
Volume Injected : 1.0
42 Naphthalene
Page 11
Column diameter : 0.32
I
I
I
Scan 1142 (11.606 min) of YP5%.d
Mass 128.00
>* 0«8~
('I | * \' r yi i t "{¦¦< f""i |" r-r r" r i > 'i"|"r > ¦ r ;1 r "i i 'j— r-v-i—y ¦«
80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
Scan 1142 (11.606 min) of YP596.d (Subtracted)
! , , , i , , , I
11.20 11.40 11.60 11.80 12.00
Time (min v
Mass 129.00
120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
>-1.0
_Av^t-W
r-r r , , .yi
3 4.0-
11.20 11.40 11.60 11
Time (min.)
Mass 127.00
j t i i j f" i » ¦ | I'T'i |""r t "T | iMMi i | i i i | t y"^|-r,t t \ i" t » { i i • r | i t t j >
80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
Scan 1142 (U.606 min) of YP596.d (2 DIFFERENCE)
£ 2.0-
I 'PTr t * 'i' r ; "i
T
11.20 11.40 11.60 11.80 12.00
Time (min.)
120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
130
-------
Data File: /chem/Y.i/09-05-97.b/YP596.d
Date : 05-SEP-1997 13:03
Instrument : Y.i
Sanple ID : RUN5
Column phase : DB-5
Volume Injected (uL) : 1.0
Column diameter : 0.32
Page 12
46 2-Methylnaphthalene
200 240 280
Mass/Charge
I 1 1 1 I
400 440
Scan 1339 (13.024 min) of YP596.d (Subtracted)
1.6-
1.4-
1.2-
-1.0-
vO
o 0.8-
3 0.6-
0.4-
0.2-
0.0-
V-MA-
40
120 160
200 240 280
Mass/Charge
320 360 400 440
46 2-Methylnaphthalene (PBM Reference Spectrum)
8.0-
-6.0-
ro
<
o
¦x 4.0-
2.0—1
o.o^ 11,1.1*, 4 II, , ¦ ¦ ,
| i*i i |"1 r* r ¦ !¦ j" i i i1]1 ir rji" i i | i i i j
40 80 120 160 200 240 280 320 360 400 440
Mass/Charge
100-q
75
50-j
25-i
: 0-j*
= -25-1
N
-50-j
-75-i
Scan 1339 (13.024 min) of YP596.d (2 DIFFERENCE)
-100 J-r
40
80
T
T
120 160
'I 1 11 I 1 1 ' I 1
200 240 280
Mass/Charge
320
' I 1 ' 1 I 1
360 400
1 1 I 1
440
Scan 1339 (13.024 min) of YP596.d
Mass 142.00
12.
i "1 r -i' '|
J4
i}],,
60 12.80 13.00 13.20 13.40
Time (min.)
Mass 141.00
I 1 1 1 I
12.60 12.80 13.00 13.20 13.40
Time (min.)
131
-------
Data File: /chem/Y.i/09-05-97.b/YP596.d Page 14
Date : 05-SEP-1997 13:03
Instrument : Y.i
Sample ID : RUNS
Column phase : Dl-5 Column diameter : 0,32
Volume Injected (uL) : 1.0
56 flcenaphthylene
Scan 1594 (14.865 win) of YP596.d
2.4-
2.0-
1.6-
?1 2-
•r
X -i
;o.8-
0.4-
0.0-
40
80 120
"f<¦"' '
160
1" 1,1 l '
200 240
Hass/Charee
280
' I '
320
360
—t—i—j1 i i
400
2.4-
2.0-
1.6-
3 0.8-
>-
0.4-
0.0-
Scan 1594 <14.8® min) of YP596.d {Subtracted)
LjL
40
80
120
160
200 240
Mass/Charge
280 320
-r-f—r
360
11 I 1
400
56 flcenaphthylene (PBH Reference Spectrum)
8.0-
.6.0-3
K)
<
o
34.H
>-
2.0-
0.0-
- f ) y \ . 1.
T
T
""I""'' ' ' I 1 ' 1 I
T
40 80 120 160 200 240 280 320 360
Mass/Charge
400
100-
75-
50-
25-
: °'
*=» -25-
-50-
-75-
-100-
Scan 1594 (14.865 lain) of YP5%.d <2 DIFFERENCE)
, .J—1_
J J.
-j—1—1—1 | 1 1 1 | 1 1—1 [ "i" 1 1 | 1—1—1 | 11 1 |
T
40 80 120 160 200 240 280 320 360
Mass/Charge
400
Mass 152.00
LOO _
c-J
' I ' 1 1 I 1 • 1 t
.40 14.60 14.80 15.00 15.20
Time (min.)
Mass 151.00
14.40 14.60 14.80 15.00
Time (min.)
15.20
Mass 153.00
' I e 1 1 j I 1 1 j 1 1 1 ] 1
14.40 14.60 14.80 15.00
Tiwe (win.)
I I | I
15.20
132
-------
Data File: /chem/Y.i/09-05-97.b/YP5%.d
Date : 05-SEP-1997 13:03
Instrument : Y.i
Sample ID : RUN5
Column phase : DB-5
Volume Injected
-------
Data File: /chem/Y.i/09-05-97.b/YP5%.d Page 16
Date : 05-SEP-1997 13:03
Instrument : V.i
Sample ID : RUN5
Column phase : Bl-5 Column diameter : 0.32
Volume Injected (uL) : 1.0
65 Fluorene
Scan 1791 (16.290 min) of YP5%.d
i-8i
1.5-j
1.2-i
-0,5-
0.2-i
0.0-
40
80 120 160 200
| » > r y i—i | i » i ) i i i'; *
200 240 280 320 360 400 440 480
Mass/Charge
Scan 1791 <16.290 win) of YP596.d (Subtracted)
1.3-
1.5-
1.2-
f 1.0-
I0-8"
>- 0.5-
0.2-
0.0-
1,1 it,
"'TTy^'Tl ["f ^ ^ j H I > » > I | i i' I | » I I j 1 f r | r "i" t | ; i i * |' i
40 80 120 160 200 240 280 320 360 400 440 480
Mass/Charge
65 Fluorene (PBM Reference Spectrum)
8.0-
.6.0-
K)
^ 4.0-1
>"
2.0-
0.0-
*! > Jl^'n , 11,
40
120 160
1 l 11 1 l 1 11 l ' 1 1 I 1 ' i [ ' 1 ' 1 ' ' ' l '
200 240 280 320 360 400 440
Mass/Charge
480
100-g
75-j
504
254
£ o4 —
o-25
-50 i
-754
-100
Scan 1791 <16.290 win) of YP596.d (Z DIFFERENCE)
lL i ^ •
r
40
80
-I—I"1 t "i" i—p-r
120 160
T
I I I I I I
T
200 240 280 320 360 400
Mass/Charge
440 480
Mass 166.00
*0.8-
0.6-
rjs
• jD t*i
15.80 16.00 16.20 16.40 16.60
Time (win.)
Mass 165.00
1.8-
1.6-
1.4-i
1.2-
pi.o-
o
,2 0.8-
*" 0.6-
0.4^
0.2
0.0 1 ' ' ' ' I I ' 1 I 11 ' | ' 1 ' I
15.80 16.00 16.20 16.40 16.60
Time (win.)
Mass 167.00
"I '''• ¦' I1"' 1 ' I"'
15.80 16.00 16.20 16.40 16.60
Time (min.)
134
-------
Data File: /chem/Y.i/09-05-97.b/YP5%.d Page 17
Date : 05-SEP-1997 13:03
Instrument : Y.i
Sample ID : RUNS
Column phase : DB-5 Column diameter : 0.32
Volume Injected -0.5-:
0.2-j
0,0-
T1
40
60
|i.y. ,<11,,, , f,, pp, ii i'"i | ¦ i , v'j|r'i
80 100 120 140 160 180
Mass/Charge
Scan 2064 (18.270 min) of YP5%.d (Subtracted)
1..8-E
1.5-j
_ 1.2-i
J 1-°i
3 0.8-j
>-0.5-!
°-2i
o.o-=-
t 1]*"
-ill
40
60
80 100
120
i i
140 160
Mass/Charge
T'' ' + I 1
180 200
220
240
73 Phenanthrene (PBM Reference Spectrum)
ro
<
o
. 6.0-
¦x 4.0-
' 2.0-
o.o:
px
40
60
80 100
120 140 160
Mass/Charge
180 200 220 240
100 ¦:
75-i
50-i
25-i
0"
« -25^
X
-50-
-75-i
-100 J
Scan 2064 (18.270 min) of YP5%.d M\i
18.0 18.2 18.4
Time (min.)
Mass 179.00
2.8-
2.5-
2.2-!
2.0-
^ 1.8-
g 1.5-j
31.2-
>-1.0-1
0.8-
0.5-i
0.2-i
0.0J
cr-
IN-
ro
18.0 18.2 18.4
Time (min.)
Mass 176.00
3.6-
3.2-
2.8^
2.4-
55 2.0-
o
31.6-
^ 1.2-i
0.8-
0.4-
0.0'
/J* * «
-------
Data File: /chem/Y.i/09-05-97.b/YP5%.d
Date : 05-SEP-1997 13:03
Instrument : Y.i
Sample ID : RUNS
Column phase : DB-5
Volume Injected (uL) : 1.0
74 Anthracene
Page 13
Column diameter
Scan 2079 <18.379 min) of YP596.d
Mass 178.00
200 240 280
Hass/Charge
Scan 2079 <18.379 min) of YP596
(Subtracted)
n~>
18.0 18.2
Time (win.)
Mass 176.00
>-0.8
80 120 160 200 240 280 320
Mass/Charge
440 480
360 400
f 2.0
o
74 Anthracene -1.0-:
0 -25
X
-50
80 120 160 200 240 280 320 360 400 440 480
Hass/Charge
I' '! "T" \
18.0 18.2 18.4
Time (win.)
135
-------
Data File: /chem/Y.i/09-05-97.b/YP5%.d
Date : 05-SEP-1997 13:03
Instrument : Y.i
Sample ID : RUN5
Column phase : DB-5
Volume Injected (uL) : 1.0
Column diameter : 0.32
Page 19
77 Fluoranthene
Scan 2401 (20.725 min> of YP596.d
7.0-;
6.0-1
5.0]
£>4.0-;
|3.°i
>- 2.0-j
1.0-E
0.0-
'll f¦
¦HL>T»firt vrf'rrf i11'h'T fi
W-rr
50 75 100 125
150 175 200
Mass/Charge
T"
225
250
275
300
' 11 ' 1 1 1 I '
325 350
Scan 2401 (20.725 min> of YP596.d (Subtracted)
7.0-3
6.0
5.0
lt5 4.0j
< H
o
33.0-3
>• 2.0-^
1.0
0.0
l| ^ ,1. 1.1 V I Ifl|.| |. I ,.p
50 75 100 125
¦t1' ¦ ¦
150 175 200
Mass/Charge
1 1 1 1
225
250
275
300
325 350
77 Fluoranthene (PBM Reference Spectrum)
8.0-
.6.0-
ro
<
o
34.0-
2.0-
0.0-
50
-rJL
75 100 125
t'< ¦ "V
150 175 200
Mass/Charge
225
250
1 I " ' ' I ' ' 1 ¦ I ' 1 1 1 I 1
275 300 325 350
100-
75-
50-
25-
: °"
>-25-
t
-50-
-75-
-100-
Scan 2401 (20.725 min) of YP596.d -
2.0-
1.0-
Mass 202.00
0.0 VY> ,
20.4
A .VrSrrrV1
20.6 20.8
Time (min.)
21.0 21.2
Mass 101.00
1.4-
1-2:
1.0-
'0.8
0.4-j
0.2-
0.0-
it r |t r 1 ;
. , 1 | ¦ T " J"
20.4 20.6 20.8 21.0 21.2
Time (min.)
Mass 100.00
1.2-
1.1-
1.0-
0.9-
0.8-
L?5 0.7-
S0.6-
* 0.5-
*~0.4-
0.3-
0.2-
0.1-
0.0-
20.4 20.6 20.8 21.0 21.2
Time (min.)
137
-------
Data File: /chem/Y.i/09-05-97.b/YP5%.d Page 20
Date : 0S-SEP-1997 13:03
Instrument : Y.i
Sample IB : RUN5
Column phase : BB-5 Column diameter : 0.32
Volume Injected •
1.0-
0.0-
1 '<* f f ¦
4.
40 80 120 160 200 240
Mass/Charge
280 320
360
78 Pyrene (PBH Reference Spectrum)
8.0-
>6.0-
i-o
<
o
34.0-
>-
2.0-
0.0-
"1—'—I1 I1 I *1 *—f f 1—1 I I I' I—I f 1—I I I I—I I I I I—I I I I' I " I—I I I I I 1
40 80 120 160 200 240 280 320 360 400
Mass/Charge
100-
75-
50-
25-
: °"
« -25-
*«
-50-
-75-
-100-
Scan 2464 (21.185 min) of YP5%.d (Z DIFFERENCE)
..L
l' ' ' 1 i""' ' 1 l ' 1 1 l 1 11 l ' ' l '
40 80 120 160 200 240
Mass/Charge
280
T1-
320
400
360 400
Mass 202,00
7.0-:
|—LTS
1 ^
I N"
6.0-i
O
1 CM
5.0-j
S 4.0-
O I
3 3.0-j
>¦ :
2.0-
1.0-i
o.o4
-iK_v
' 1 »
r 1 [ 1 r-rf-p~ r i i i | i ti
20.80 21.00 21.20 21.40 21.60
Time (win.)
Mass 101.00
1.4-
1.2:
1.0-
^0.8-
'0.6-
0.4-
0.2-
0.0
I—ID
CM
N
O
CM
—cr>
CD
*iM" r- pT""i 1 [""i » M | h i' » ; "t 1 1 | 1
20.80 21.00 21.20 21.40 21.60
Time (win.)
Mass 100.00
-in
ao
1.2-
1.1-3 I £>¦ i ^
UQ-;
0.9-=
0.81
£ 0.7 H
S 0.6-i
-0.5-
^0.4-j
0.3-i
0.2-i
0.0 ^ 1 Vtyy
20.80 21.00 21.20 21.40 21.60
Time (win.)
133
-------
Data Filet /chem/Y.i/09-05-97.b/YP5%.d
Date : 05-SEP-1997 13:03
Instrument ; Y.i
Sample IB : RUNS
Column phase : DB-5
Volume Injected : 1.0
Column diameter : 0.32
Page 21
83 Benzo(a)anthracene
Scan 2804 <23.672 win) of YP5%.d
Mass 228.00
W4
200 240 280 320 360 400 440
Mass/Charge
120 160
Scan 2804 <23.672 min) of YP5%.d (Subtracted)
j II I J I II j » r I j 1 1 I J ! I I
23.20 23.40 23.60 23.30 24.00
Tine (miri.)
Mass 229.00
f 'f '« J 1
200 240 280 320
Mass/Charere
I ' 1 I
400 440
31.6-
83 Benzo(a)anthracene j i ! i ' i t 1—1—1 1 T ' 'i t—i—f i i » |
80 120 160 200 240 280 320 360 400 440
Mass/Charge
Scan 2804 <23.672 min) of YP5%.d <2 DIFFERENCE)
-A J.
°-25
~41 /•—
-100 ^
23.20 23.40 23.60 23.80 24.00
Time (min.)
80 120 160 200 240 280 320 360 400 440
Mass/Charge
133
-------
Data File: /che*/Y.i/09-05-97.b/YP5%.d
Bate : 05-SEP-1997 13:03
Instrument : Y.i
Sample ID : RUN5
Column phase : DB-5
Volume Injected : 1,0
84 Chrysene
Scan 2813 <23.738 min) of YP596.d (Subtracted)
1.2-
1.0-
,0-8"
in
o 0.6-
k,
0.2-
0.0-
lp i tpd j ^ I I' I ^ I ^
80 120 160
40
•r-f
240
Mass/Charge
'T V t "I [¦
400 440
84 Chrysene (PHI Reference Spectrum)
8.0-
,6.0-
fO
<
^4.0-
*2.0-
0.0'
40
80
ii
[' 1 i ? y 1 i1^ | i i i \ r ¦'! 1 | i i i1 ) i
120 160 200 240 280 320 360
Mass/Charge
f-yr
400
100-
75-
50-
25-
*- 0-
4-
3-25-
-50-
-75-
-100-
Scan 2813 (23.738 win) of YP5%.d <% DIFFERENCE)
1 „u
r-'
40
» } « » I | I 1 " f "f "f
80 120 160
'I 1 11 l 1 1 ' 1 '
200 240 280
Mass/Charge
320 360
1 » 1 ; 1
400
-T-TT
440
Page 22
I
I
Column diameter : 0.32
t \ » I
440
Scan 2813 (23.738 min) of YP5%.d
i. 0.8
0.4
CO
m
fs-
1.4-
FO
1.2-j
sD
ro
Csl
1.0-
§0.8-
O
X
^0.6-
>- •
0.4-
0.2-:
o.o-
1 1
23.40 23.60 23.80 24.00 24.20
Tine (min.)
Mass 226.00
n
32.0-
-r r | » 1 1 j 1 i » | 1 1 1 | 1 < ¦ t
23.40 23.60 23.80 24.00 24.20
Time (win.)
Mass 229.00
rfi
-^[i 'i | 1 i i | i i 1 |
23.40 23.60 23.80 24.00 24.20
Time (min.)
140
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
-------
Data File: /chem/Y. 1 /09-05-97.b/YP5%.d
Date : 05-SEP-1997 13:03
Instrument : Y.i
Sample IB : RUN5
Column phase : BB-5
Volume Injected : 1.0
Column diameter : 0,32
Page 23
36 Benzo < b > f1uorantHene
Scan 3160 (26.267 min> of YP5%.d
<_ 2.0-:
>< 1.5-:
. >LJ
200 240 280
Mass/Charge
t | V"
320
J I 1 1 I
400
Scan 3160 <26.267 nun) of YP596.d (Subtracted)
3.2
2.8-3
2.4
. 2.0-:
o 1.6-
Si.2-i
** 0.8-;
0.4-=
0.0
JU fi , ».j ,l I I A
l ^ li; li'; i jlll j i ^ ,1 ll|) J A I, ll,
"i j —j—i—j—i—|—i—i—r—j—
120 160 200 240 280 320 360 400 440
Mass/Charge
-+-
40
86 Eenzo(b>f1uoranthene (PBM Reference Spectrum)
8.0-
.6.0-
fO
<
O
^4.0-
>-
2.0-
0.0-
-I ^ P |'|—I—I—[—I ¦ I !¦ ¦[. , p, | T I ' I—|—<—I I I I I I' I I—r—«—[III—I—P
40 80 120 160 200 240 280 320 360 400 440
Mass/Charge
100-
75-
50-
25-
o: 0-
5-25-
-50-
-75-i
-100-
Scan 3160 (26.267 win) of YP5%.d (2 DIFFERENCE)
L». .
I.. ...» h k.
T-T-r-
40 80
¦)—J—i—i—i—|—r
120 160
-i—j—i—i—i—r-T~
200 240 280 320 360 400 440
Hass/Charge
Mass 252,00
26.0 26.2 26.4
Time (win.)
Mass 253.00
26.0 26.2 26.4
Time (min.)
Mass 125.00
0.0 ' | i ii—|—r—i—i | i—r-r—|" i i—i—p
25.8 26.0 26.2 26.4 26.6
Time (min.)
141
-------
Data File: /che«/Y. i/09-05-97.b/YP5%.d
Date : OS-SEP-199? 13:03
Instrument : Y.i
Sample ID : RUN5
Column phase : DB-5
Volume Injected (uL> : 1.0
87 Benzo-2.0
i • 'I 1 11 t ' 11 I ' 1 ' I ' 1 ' I 1 11 I
40 80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
87 Benzofluoranthene < i | i i i i i i i [ i i" i i" i "i i | i i i | i i i [ i i i | i i i | i i i | i
40 80 120 160 200 240 280 320 360 400 440 480 520
Mass/Charge
1.6-
r
CD
CM
1.4-
CNJ
1.2-
in
CM
ro
¦
\0
CM
Jl
i.o-i
§0.8-
X
~0.6-
0.4-f
0.2^
0,0-
-f—r-
26.0 26.2 26.4
Time (min.)
26.6 26.8
142
-------
Data File: /chem/Y. i/09-05-97.b/YP5% .d Page 25
Date : 05-SEP-1997 13:03
Instrument : Y.i
Sample ID : RUNS
Column phase : 1B-5 Column diameter : 0.32
Volume Injected (ul> : 1.0
88 Benzo(e)pyrene
Scan 3265 <27.027 run) of YP5%.d
ll,jl|l-JII, { I,
200 240
Mass/Charge
280
320
360
Scan 3265 (27.027 min) of YP596.d (Subtracted)
2.01
1.8-i
1.5-:
Q1.2H
Sl.O"
*o.8-i
^0.5-
0.2-i
0.0-
y '¦ *»lll^i' 1
40
80
JlUi.L|iii,Jiii^iLi^.iiiii^itoif ifi
120 160 200 240
200 240
Mass/Charge
•r-Tr
2B0
320
t | ' I
360
88 Benzo(e>pyrene (PBM Reference Spectrum)
8.0-
6.0-
r0
0
tH
X
4.0-
2.0-
0.0-
r~<-
40
jl
120
1 i ¦
160
-t"
i.
240
200
Mass/Charge
280
320
360
400
400
400
100-
75-
50-
25-
t 0-
® -25-
-50-
-75-
-100-
Scan 3265 (27.027 min) of YP596.d (2 DIFFERENCE)
ill.
-jr-r*
|—"T m"i—j—r—i—i—p
40
120
1 i 1 1 ' I ' 1 1 i 1
160 200 240
Mass/Charge
320
400
Mass 252.00
26.90 2?loO * 27ll0' 27120
Time (win.)
Mass 253.00
1 ! |
26.90 27.00 27.10
Time (min.)
27.20
Mass 125.00
26.90 27.00 27.10 27.20
Time (min.)
143
-------
Data File: /chem/Y.i/09-05-97.b/YP596.d
Date : 05-SEP-1997 13:03
Instrument : Y.i
Sample IB : RUN5
Column phase : DB-5
Volume Injected (uL) : 1.0
Column diameter : 0.32
Page 26
89 Benzo(a)pyrene
Scan 3281 <27.143 min) of YP596.d
30.6
iiiiiHlitHi iim 111
160 200 240
Mass/Charge
1.2-
1.0-
0.8-
^0.6-
i
' 0.4-
0.2-
0.0-
Scan 3281 (27.143 mn> of YP596.d (Subtracted)
W
40
iji, 1Iii,.|iU^^ih^
Ml,i,i , H ,i, ,i, i , ,'
120
160 200 240
Mass/Charge
89 Benzo
2.0-
0.0-
r~
40
80
, .it, , 1
T—pH 1 1 1 I I 1 ^1 11 l "f I |—yP"T' I 1 1
120 160 200 240 280
=—-J|ilS==iC£L____====
320
100-
75-
50^
25-
:
«-25-
-50-
-75-i
-100-
Scan 3281 (27.143 min) of YP596.d (Z DIFFERENCE)
. .J 111 l 1,1 it LlJi . Ik .„t,IU,ll,W
-r~T—i—r-
360
r-r-t
360
I I I J 1 I I | 1 ! 1 | I I 1 | 1
40 80 120 160 200 240 280 320 360
Hass/Charge
Mass 252.00
•"H 1.0
26.80 27.00 27.20 27.40 27.60
Time (win.)
Mass 253.00
¦rS
o
r>- o
CM ID
*2.0-i
>-1.6-
26.80 27.00 27.20 27.40 27.60
Time (win.)
Mass 125.00
26.80 27.00 27.20 27.40 27.60
Tine
-------
¦Project Number: 42930B
Sample File: VG194
Eastern Research Group
Method 8270A MM5
Sample ID: FBI
el-Yt
08/19/97
Dilution Factor: 2.00
Analyte
Amount ELAG
RT
Det limit
Quan. limit
«g
ag
Qg
Naphthalene-ds
IS 2
10.55
Naphthalene
1.72 B]
10.58
20
2-Methylnaphthalene
U
1.61
20
Acenaphthene-dio
IS 3
. 14.08
2-Chloronaphthalene
U
1.45
20
Acenaphthylene
u
0.97
20
Acenaphthene
u
1.71
20
Fluorene
u
1.44
20
Phenanthrene-d
i0
IS 4
17.08
Phenanthrene
U
1.01
20
Anthracene
U
1.05
20
Fluoranthene
U
1.18
20
Chrysene-d^
IS 5
22.44
Pyrene
U
1.36
20
Benzo(a)anthracene
u
1.69
20
Chrysene
u
1.94
20
Perylene-d
12
IS 6
25.35
Benzo(b)fluoranthene
U
1.80
20
Benzo (k) fluoran thene
u
1.85
20
Benzo(e)pyrene
u
1.86
20
Benzo(a)pyrene
u
1.99
20
Perylene
u
1.97
20
Indeno(! ,2,3-cd)pyrene
u
2.12
20
Dibenz(a,h)anthracene
u
2.77
20
Benzo(g,h,i) perylene
u
2.40
20
NA- Not Applicable; Det, Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTP, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.5
Printed: 1538 09/12/1997
14 o
-------
Eastern; Re^ardiGmttp
Project Number 42930B
Sample File: VG194
Method 8270A MM5
Sample ID: FBI
Client Project: Iron & Steel-Yt
TLI ID: 179-98-4AC-E
Date Received: 08/19/97
Date Extracted: 08/25/97
Date Analyzed: 09/02/97
Response File VG184
Dilution Factor: 2.00
Surrogate Summary
Amount
RT
FSRef
%REC
(og)
Anthracene-d 77.34 17.19 4 77
10
Pyrene-d)o 114.22 19.94 5 114
_ Date
Reviewed by
NA- Not Applicable; Defc Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTP, Inc. Savar v3.5
801 Capitola Drive • Durham, North Carolina 27713 Printed: 15:38 09/12/1997
Phone: (919) 544-5729 • Fax: (919) 544-5491
143
-------
Data File: /cbem/V.i/09-O2-97.b/VG194.d
Bate : 02-SEP-97 14|i0
Instrument : V.i
Sample ID : FBI
Column phase ; DB-5
Volume Injected
Trltngl# Ubdmterftg
of RIP, Inc.
Column diameter : 0,32
/chem/V.i A)9-02-97,b/VG194.d
-------
Data File: /chew/V.l/09-02-97.l»/VG194.d
Date ; 02-SEP-97 14:10
Instrument | V.l
Sample ID : FBI
Column phase i DB-5
Volume Injected J 1,0
/chen/V. 1/09-02-97.b/VG194.d
0,9-
0,8-
0.6-
O.
0,3-
0.1-
0,0
Page 10
f rlanglt Ubwatarfw
of RTP, Inc.
Column diameter : 0.32
-------
Data File: /chem/V.i/09-02-97.b/VG194.d
Report Date: 02-Sep-1997 14:52
Page 1
TRIANGLE LABORATORIES, INC.
Data file
Lab. Id.
Inj Date
Operator
Smp Info
Misc Info
Comment
Method
Meth Date
Cal Date
Als bottle
Dil Factor
Integrator
Sample Type
SEMI-VOLATILE QUANTITATION REPORT
/chem/V.i/09-02-97.b/VG194.d
42930B
02—SEP—97 14:10 Autotune Date: 03-Jul-97 12:11:2
DD Inst ID: V.i
FBI
179-98-4AC-E
/chem/V.i/09-02-97.b/cclist.m
02—Sep—1997 08:14 target
02-SEP—1997 07:31
2
2.000
HP RTE
: AIR
Cal File: VG184.d
Target Version: Target 2.20
Compound Sublist: pah.sub
CONCENTRATIONS
QUANT SIG
ON-COLUMN
FINAL
Compounds
MASS RT (REL RT)
RESPONSE
C ng)
C ug)
*
1 1,4-D >' ch I orobenzene-d4
152.00 8.103(1.000)
181607
40.00
*
2 NaphthaLene-d8
136.00 10.547(1.000}
709931
40.00
*
3 Acenaphthene-d10
164.00 14.078(1.000}
503609
40.00
*
4 Phenarithrerve-d10
188.00 17.077(1.000)
809055
40.00
*
5 Chrysene-d12
240.00 22.441(1.000)
459737
40.00
h
6 Perylene-d12
264.00 25.354(1.000)
417409
40.00
$
7 2-Fluorophenol
Compound Not Detected.
$
8 Phenol-cB
99.00 7.523(0.9285
237925
31.00
62.01
s
9 2-CJUorophenot-d4
Compound Not Detected.
%
10 1,2-Dichtorobenzene-d4
Compound Hot Detected.
$
11 Nitrobenzene-d5
82.00 9.158(0.868}
205557
32.11
64.21
%
12 1,3,5-Trichlorobenzene-d3
185.00 9.816(0.931)
183965
26.69
53.38
%
13 1,4-Dibromobenzene-d4
240.00 10.660(1.316}
268462
55.69
111.38
$
14 2-Fluorobiphenyl
172.00 12.776(0.907)
488538
32.13
64.25
s
15 2,4,6-Tribromophenot
329.80 15.677(1.114)
192772
49.44
98.88
s
16 Anthraeene-dIO
188.00 17.191(1.007)
843140
38.66
77.32
$
17 Pyrene-d10
212.00 19.938(0.888)
792912
57.12
114.24
$
18 Terphenyl-d14
Compound Not Detected.
42 Naphthalene
128.00 10.582(1.003}
16369
0.86
1.72(a)
46 2-Nethylnaphthalene
Compound Not Detected.
50 2-Chloronaphthalene
Compound Not Detected.
56 AcenaphthyLene
Compound Not Detected.
58 Acenaphthene
Compound Not Detected.
65 Fluorene
Compound Not Detected.
73 Phenanthrene
Compound Not Detected.
74 Anthracene
Compound Not Detected.
77 Fluoranthene
Compound Not Detected.
78 Pyrene
Compound Not Detected.
83 Benzo(a)anthracene
Compound Not Detected.
84 Chrysene
Compound Not Detected.
86 Benzo(b)fluoranthene
Compound Not Detected.
Data Review.
Date: q]lo[^
143
-------
Data File: /chem/V.i/09-02-97.b/VG194 .d
Report Date: 02-Sep-1997 14:52
CONCENTRATIONS
QUANT SIG ON-COLUHM FINAL
Compounds MASS RT (REL RT) RESPONSE < ng) ( ug)
87 Benzo(k)fluoranthene
Compound
Not
Detected.
88 Benzo(e)pyrene
Compound
Not
Detected.
89 Benzo(a)pyrene
Compound
Not
Detected.
90 Perylene
Compound
Not
Detected.
91 Indeno(1,2,3-cd)pyrene
Compound
Not
Detected.
92 Dibenz(a,h)anthracene
Compound
Not
Detected.
93 Benzo(g,h,i)perylene
Compound
Not
Detected.
QC Flag Legend
a - Target compound detected but, quant it ated amount
Below Limit Of Quantitation(BLOQ).
Page 2
150
-------
Data File: /che«/^.i/09-02-97.b/VG194.d Page 11
Date : 02-SEP-97 14:10
Instrument : V.i
Sample ID : FBI
Colwn phase : DB-5 Colunn dianeter : 0.32
Volute Injected (uL) : 1.0
42 Naphthalene
Scan 502 <10.582 *in) of VG194.d
8.0-
7.0-
6.0-
¦ 5.0-
fO
o 4.0-
*-3.0-
="2.0-
1.0-
0.0-
40
50
> 1' [ I
60
70
l i i i i I i
80 90
Hass/Charge
100
110
T-J-l-
120
r1-
130
Scan 502 <10.582 win) of VG194.d
m
8.0-
7.0-
6.0-
.5.0-
)
©4.0-
^3.0-
•2.0-
1.0-
0.0-
nass 128.00
10.20 10|40 lolso lolso llloo
Tiwe 0.6-
So.5-
>-0.4-
0.3-
0.2-
0.1-
0.0-
CM
s
I
m
in
1 i | 1 i t') 1 » 1 | 1 f > | 1
10.20 10.40 10.60 10.80 11.00
Time
-------
Project Number: 42930B
Sample File: VG195
Method 8270A MM5
Sample ID: FB2
Dilution Factor: 2.00
Naphthalene-d^
IS 2
10.55
Naphthalene
1.74 BJ
10.58
20
2-Methylnaphthalene
U
1.40
20
Acenaphthene-d(o
IS 3
14.07
2-Chloronaphthalcne
U
1.30
20
Acenaphthylene
U
0.87
20
Acenaphthene
U
1.54
20
Fluorene
u
1.30
20
Phenanthrcnc-d
10
IS 4
17.08 •
Phenanthrene
U
0.88
20
Anthracene
u
0.92
20
Fluoranthene
u
1.03
20
Chrysene-d^
IS 5
22.44
Pyrene
U
1.19
20
Benzo (a) an thracene
u
1.48
20
Chrysene
u
1.70
20
Perylene-d^
IS 6
25.36
Benzo(b)fluoranthene
U
1.61
20
Benzo(k)fluoranthene
u
1.65
20
Benzo(e) pyrene
u
1.66
20
Benzo (a) pyrene
u
1.78
20
Perylene
u
1.76
20
Indeno{l ,2,3-cd)pyrene
u
1.89
20
Dibenz(a,h)an thracene
u
2.47
20
Benzo(g,h,i) perylene
u
2.15
20
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; I: Estimated- Above Calibration Range
Triangle Laboratories of RTP, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.5
Printed: 15:42 09/12/1997
152
-------
I
I
I
I
I
I
I
I
I
I
I
Project Number 42930B
Sample File: VG195
Method 8270A MM5
Sample ID: FB2
Client Project Iron
Hi ID: 179-98-8AC
&SI
:-e^
Dilution Factor. 2.00
Airaotart
mm
fSRef.
Anchracene-d
U
Pyrene-d
J m
73.02
120.15
17.19
19.93
4
5
73
120
Date SjVL9i
Reviewed by
NA- Not Applicable; Det. Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTP, Inc. Savar v3.5
801 Capitola Drive • Durham, North Carolina 27713 Printed: 15:42 09/12/1997
Phone: (919) 544-5729 • Fax: (919) 544-5491 153
-------
Data Filet /cWV.l/09-02-97.b/VG195.d
Date : 02-SEP-97 14:47
Instrument J V.i
Sample ID J FB2
Column phase J DB-5
Volune Injected (uL> : 1.0
Triangle Uboratorlw
of RTP, Inc.
Column diameter : 0.32
Page 9
'¦T
m
/chem/V.i/09-02-97.b/VG195.d (Part 1 of 2)
m
8
o
*
in
S3
GO
O
1.1-
1.0-
0.9-
CM
CM
0.8-
0.7-
£ '¦
I*-6:
>-
0.5-
m
0.4-
0.3-
0.2
0.1-
r, V i"]1")'fn "!1 , iMH -W
o.o
s:
o
-------
Data File: /chem/V.i/09-02-97.b/VG195.d
Date : 02-SEP-97 14:47
Instrument : V.i
Sample ID : FD2
Column phase : DD-5
Volume Injected (uL) : 1.0
Page 10
Triangle Laboratories
of RTP, Inc.
Column diameter : 0,32
lO
in
/chem/V.i/09-02-97.b/VG195.d (Part 2 of 2>
1.2-
1.1-
1.0-
0.9-
0.8-
0.7-
>-
0.5
0.4
0.3
0.2
0.1
26 27
Time (mln.)
0.0
-------
Data File: /chem/V.i/09-02-97.b/VG195.d
Report Date: 03-Sep-1997 07:03
Page 1
Data file
Lab. Id.
Inj Date
Operator
Smp Info
Misc Info
Comment
Method
Meth Date
Cal Date
Als bottle
Dil Factor
Integrator
Sample Type:
TRIANGLE LABORATORIES, INC.
SEMI-VOLATILE QUANTITATION REPORT
/chem/V.i/09—02-97.b/VG195.d
42930B
02—SEP—97 14:47 Autotune Date: 03-Jul-97
DD Inst ID: V.i
FB2
179—98—8AC-E
12:11:2
/chem/V.i/09—02—97.b/cclist.m
02—Sep—1997 08:14 target
02—SEP—1997 07:31
3
2.000
HP RTE
AIR
Cal File: VG184.d
Target Version: Target 2.20
Compound Sublist: pah.sub
CONCENTRATIONS
QUANT SIG
ON-COLUMN
FINAL
Compounds
MASS
RT (REL RT)
RESPONSE
( ng)
( ug)
1
1,4-Dichlorobenzene-d4
152.00
8.103(1.000)
238211
40.00
2
Naphthalene-d8
136.00
10.546(1.000)
818298
40.00
3
Acenaphtherte-d10
164.00
14.071(1.000)
560084
40.00
4
Phenanth rerte-d10
188.00
17.077(1.000)
929600
40.00
5
Chrysene-d12
240.00
22.441(1.000)
525406
40.00
6
Perylene-d12
264.00
25.359(1.000)
467320
40.00
7
2-Fluorophenol
Compound
Not Detected.
8
Phenol-d5
99.00
7.523(0.928)
321958
31.99
63.97
9
2-ChIorophenoI-d4
Compound
Not Detected.
10
1,2-0ichIorobenzene-d4
Compound
Not Detected.
11
Nitrobenzene-d5
82.00
9.158(0.868)
213268
28.90
57.80
12
1t3,5-Trichlorobenzene-d3
185.00
9.816(0.931)
177479
22.34
44.68
13
1,4-Dibrcmobenzene-d4
240.00
10.653(1.315)
292770
46.30
92.60
14
2-FIuorobipheny I
172.00
12.776(0.908)
461482
27.29
54.57
15
2,4,6-Tribroniophenol
329.80
15.676(1.114)
208806
48.15
96.30
16
Anthracene-d10
188.00
17.190(1.007)
914693
36.50
73.00
17
Pyrene-d10
212.00
19.935(0.888)
953192
60.09
120.17
18
Terphenyl-d14
Compound
Not Detected.
42
Naphthalene
128.00
10.582(1.003)
19057
0.87
1.74(
46
2-Methylnaphthalene
Compound
Not Detected.
50
2-Chloronaphthalene
Compound
Not Detected.
56
Acenaphthylene
Compound
Not Detected.
58
Acenaphthene
Compound
Not Detected.
65
Fluorene
Compound
Not Detected.
73
Phenanthrene
Compound
Not Detected.
74
Anthracene
Compound
Not Detected.
77
Fluoranthene
Compound
Not Detected.
78
Pyrene
Compound
Not Detected.
83
Benzo(a)anthracene
Compound
Not Detected.
84
Chrysene
Compound
Not Detected.
86
Benzo(b)fIuoranthene
Compound
Not Detected.
Data Review:
Date:
156
-------
Data File: /chem/V.i/09-02-97.b/VG195.d
Report Date: 03-Sep-1997 07:03
CONCENTRATIONS
QUANT SIG 0N-C0LUMH FINAL
Compounds MASS RT (REL RT) RESPONSE (rig) < ug)
87 Berao(k)fluoranthene
83 8erao(e)pyrene
89 8enzo(a)pyrene
90 Perylerte
91 lnderw(1,2,3-cd)pyrene
92 Dibenz(a,h)anthracene
93 B«nzo(g,h,i Jperylene
Compound Not Detected.
Compound Not Detected.
Compound Not Detected.
Compound Not Detected.
Compound Not Oetected.
Compound Not Detected.
Compound Not Detected.
QC Flag Legend
a - Target compound detected but, quantitated amount
Below Limit Of Quantitation(BLOQ),
Page 2
-------
Bata File: /chwA'.i/0W»2-97.bAiG195.d
Bate : 02-5EP-97 14:47
Instrument : V.l
Sample IB : FB2
CoIumi phase : OB-5
Volume Injected : 1.0
Coluan diameter : 0.32
Page U
42 Naphthalene
Mass 128.00
Scan 502 <10.582 xin) of VG195.d
*0.4-
S0.5
m
| I 1 I I \ I I » » | 1 I 1 T 'J »' I 1 I [ I 1 » T I | I t I F |
50 60 70 80 90 100 110 120 130
HasgyChggw
Scan 502 <10.582 «in> of VG195.d 1.2
| t i i ; i » > } i i i } t i » | i
10.20 10.40 10.60 10.80 11.00
Tine I I I I I I i I 1 I
100 110 120 130
Scan 502 <10.582 din) of VG195.d <2 1IFFESBCE)
>-0.4
= -25
I I I | 1 I I I 1 I t { I 1 I | I
10.20 10.40 10.60 10.80 11.00
Tine
-------
Eastern Research Group
Project Number 42930B Method 8270A MM5
Sample File; VG189 Sample ID: RBI
Client ]
'rojecfc Iron & i
179-9S-5AOF;
n>
lliiiiil
DateKeceivei:08fl5/97 Resf
w>ns
ie:F
iie:
VC
<11
ill
Dilution Factor: 2.00
Analyte
A
mount RAG
Naphthaiene-d^
IS 2
10.55
Naphthalene
1.16 BJ
10.59
20
2-Methylnaphthalene
U
1.37
20
Acenaphthene-d^
IS 3
14.08
2-Chloronaphthaiene
U
1.35
20
Acenaphthylene
u
0.90
20
Acenaphthene
u
1.60
20
Fluorene
u
1.35
20
Phenanchrene-d
10
Phenanthrene
IS 4
17.08
u
0.89
20
Anthracene
u
0.93
20
Fluoranthene
u
1.04
20
Chrysene-d^
IS 5
22.44
Pyrene
u
1.10
20
Ben2o(a)anthracene
u
1.36
20
Chrysene
u
1.56
20
Perylene-d^
IS 6
25.35
Benzo(b)fluoranthene
u
1.44
20
Benzo(k)fluoranthene
u
1.47
20
Benzo(e) pyrene
u
1.48
20
Benzo(a) pyrene
u
CO
20
Perylene
u
1.57
20
Indeno(l ,2,3-cd)pyrene
u
1.68
20
Dibenz(a.h) an thracene
u
2.20
20
Benzo(g,h,i) perylene
u
1.91
20
NA- Not Applicable; Det Limit: Detection Limit; Quail. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank;): Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTP, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 * Fax: (919) 544-5491
Savar v3,S
Printed: 15-38 09/12/1997
153
-------
Project Number; 4293QB
Sample File: VG189
Method 8270A MM5
Sample ID: RBI
Client Project Iron & Steel-Yi
TU ID: 179-98-5AC-F
Dale Received: 08/19/97
Date Extracted: 08/25/97
Date Analyzed: 09/02/97
Response File; VG184
Dilution Factor 2.00
Anthracene-d 73.66 17.19 4 74
1Q
Pyrene-do 111.29 19-94 5 111
Reviewed by _ rnX& Date / \Zi°rt
NA- Not Applicable; Det Limit: Detection Limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTP, Inc. Savar v3.5
801 Capitola Drive • Durham, North Carol
Phone: (919) 544-5729 • Fax: (919) 544-5491
801 Capitola Drive • Durham, North Carolina 27713 Printed|l^!8yj)9/12/1997
-------
Data File: /chem/V.1/09-02-97.b/VG189»d
Date : 02-SEP-97 llt25
Instrument J V.i
Sample ID J RBI
Column phase J DB-S
Volume Injected : 1.0
Triangle UboratoriM
of RTF, Inc.
Page 9
Column diameter J 0,32
v4
03
/chen/V.i/09-02-97.b/VG189.d (Part 1 of 2)
3
jt
fO
i
T
9 10
Ttw? <3T
1D
C si
- — HH
no
I ¦ "I""'1")" I1"
16
-------
Data Flits /chen/V.i/09-02-97.b/¥G189.d Trififlfll® LflbOrfitOrleS pa*e 10
Bate ; 02-SEP-97 11:25 gf R*|*p |f|0.
Instrument : V.i
Sample 10 : RBI
Column phase 5 DB-5 Column dianeter i 0.32
Volume Injected -
0.5
0.4-
0.3-
0.2-
0.1
ilil 11 ^ i> jl« |ii l|f 11 r ^1 "| | r* ^
0.0
Tine
-------
Data File: /chem/V.i/09-02-97.b/VG189.d
Report Date: 02-Sep-1997 12:05
Page 1
Data file
Lab. Id.
Inj Date
Operator
Smp Info
Misc Info
Comment
Method
Meth Date
Cal Date
Als bottle
Dil Factor
Integrator
TRIANGLE LABORATORIES, INC.
SEMI-VOLATILE QUANTITATION REPORT
/chem/V.i/09-02-97.b/VG189.d
42930B
02—SEP—97 11:25 Autotune Date: 03-Jul-97 12:11:2
DD Inst ID: V.i
RBI
179-98—5AC—F
/chem/V.i/09-02-97.b/cclist .m
02—Sep—1997 08:14 target
02-SEP—1997 07:31
5
2.000
HP RTE
Sample Type: AIR
Cal File: VG184.d
Target Version: Target 2.20
Compound Sublist: pah.sub
CONCENTRATIONS
QUANT SIG ON-COLUMN FINAL
Compounds MASS RT (REL RT) RESPONSE ( ng) ( ug)
*
1
1,4-Dichlorobenzene-d4
152.00
8.100(1.000)
247842
40.00
*
2
Naphthalene-d8
136.00
10.549(1.000)
836099
40.00
*
3
Acenaphthene-d10
164.00
14.081(1.000)
538978
40.00
*
4
Phenanthrene-d10
188.00
17.079(1.000)
919766
40.00
*
5
Chrysene-d12
240.00
22.442(1.000)
571049
40.00
*
6
Perylene-d12
264.00
25.352(1.000)
524574
40.00
s
7
2-Fluorophenol
Compound
Not Detected.
s
8
Phenol-d5
99.00
7.512(0.927)
303062
28.94
57.88
s
9
2-Chlorophenol-d4
Compound
Not Detected.
s
10
1<2-Dichlorobenzene-d4
Compound
Not Detected.
s
11
Nitrobenzene-d5
82.00
9.154(0.868)
167348
22.19
44.39
s
12
1,3,5-Trichlorobenzene-d3
185.00
9.819(0.931)
156120
19.23
38.46
s
13
1,4-Dibroinobenzene-d4
240.00
10.663(1.316)
205528
31.24
62.48
s
14
2-Fluorobiphenyl
172.00
12.786(0.908)
471379
28.96
57.93
$
15
2,4,6-Tribroniophenol
329.80
15.679(1.113)
195018
46.73
93.47
$
16
Anthracene-dIO
188.00
17.193(1.007)
912984
36.82
73.65
s
17
Pyrene-d10
212.00
19.937(0.888)
959596
55.65
111.31
s
18
Terphenyl-d14
Compound
Not Detected.
42
Naphthalene
128.00
10.592(1.004)
13056
0.58
1.16(a)
46
2-Methylnaphthalene
Compound
Not Detected.
50
2-ChIoronaphthaIene
Compound
Not Detected.
56
Acenaphthylene
Compound
Not Detected.
58
Acenaphthene
Compound
Not Detected.
65
Fluorene
Compound
Not Detected.
73
Phenanthrene
Compound
Not Detected.
74
Anthracene
Compound
Not Detected.
77
Fluoranthene
Compound
Not Detected.
78
Pyrene
Compound
Not Detected.
83
Benzo(a)anthracene
Compound
Not Detected.
84
Chrysene
Compound
Not Detected.
86
Benzo(b)fluoranthene
Compound
Not Detected.
Data Review: (Po~&
Date:
163
-------
Data File: /chem/V.i/09-02~97.b/VG189.d
Report Date: 02-Sep-l997 12:05
Page 2
CONCENTRATIONS
CCTHpfHllfte
87 BenioCtOfluoranthene
88 Benzo(e)pyrerte
89 Benzo(a)pyrene
90 Perylene
91 Indeno(1,2,3-cd)pyrene
92 Dibenz(a,h)anthraeene
93 Benzo(g,h,i)perylene
QC Flag Legend
a - Target compound detected but, quantitated amount
Below Limit Of Quantitation(BLOQ).
QUANT SIG OK-COLUMN FINAL
MASS RT (REL RT) RESPONSE ( ng) < ug)
Compound Not Detected.
Compound Not Detected.
Compound Not Detected.
Compound Not Detected.
Compound Not Detected.
Compound Not Detected.
Compound Not Detected.
164
-------
Data File: /che«/V.i/09-02-97.b/VG189.d Page 11
Sate t 02-SEP-97 11:25
Instrument : V.i
Sanple 10 : RBI
Column phase : DB-5 Colunn dianeter : 0.32
Volune Injected <3.0-:
>-2.0-E
arse
Scan 1158 <10.592 nin) of VG189.d (Subtracted)
1 f r l ; i > i | i i > \ I
10.20 10.40 10.60 10.80 11.00
Tine -2.0-i
70 80 90
Hass/Charge
42 Naphthalene I i i
110
I I I
120
n-
130
Nass/Charge
100-
75-
50-
25-
t o-
3-25-
-50-
-75-
-100-
Scai 1158 <10.592 nin) of VG189.d
-------
Project Number: 42930B
Sample File: VG188
Method 8270A XAD/H20
Sample ID: SBLK 082597
Dilution Factor: 2.00
Naphthalene-dg
IS 2
10.55
Naphthalene
12.39 J
10.58
20
2-Methylnaphthalene
U
1.33
20
Acenaphthene-d
r 10
IS 3
14.07
2-Chloronaph thalene
U
1.32
20
Acenaphthylene
u
0.88
20
Acenaphthene
u
1.57
20
Fluorene
u
1.32
20
Phenanthrene-d
»o
Phenanthrenc
IS 4
17.07
u
0.84
20
Anthracene
u
0.87
20
Fluoranthene
u
0.98
20
Chrysene-d^
IS 5
22.44
Pyrene
u
1.01
20
Benzo(a)anthracene
u
1.26
20
Chrysene
u
1.45
20
Perylene-d^
IS 6
25.35
Benzo(b) fluoranthene
u
1.35
20
Benzo(k)fluoranthene
u
1.39
20
Benzo(e) pyrene
u
1,39
20
Benzo(a)pyrene
u
1.49
20
Perylene
u
1.48
20
Indeno(l ,2,3-cd) pyrene
u
1-59
20
Dibenz(a,h)anthracene
u
2.07
20
Benzo(g.h.i) perylene
u
1.80
20
NA- Not Applicable; Det Limit: Detection limit; Quan. Limit: Quantitation Limit
IS: Internal Standard; U; Undetected; B: Present In Blank; J: Estimated- Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTP, Inc. Savar v3.5
801 Capitola Drive • Durham, North Carolina 27713 Printed: 15:37 09/12/1997
Phone: (919) 544-5729 • Fax: (919) 544-5491 4 n n
loo
-------
Eastern Research Group
Project Number: 4293GB
Sample File; VG188
Method 8270A XAD/H20
Sample ID: SBLK 082597
RT
Dilution Factor: 2.00
Anthracene-d
i<
Pyrene-d
J in
72.10
104.67
17.19
19.93
4
5
72
105
Reviewed by Date jf I
NA- Not Applicable; Det Limit: Detection Limit; Quart. Limit: Quantitation Limit
IS: Internal Standard; U: Undetected; B: Present In Blank; J: Estimated* Below Quantitation Limit; E: Estimated- Above Calibration Range
Triangle Laboratories of RTP, Inc. Savar v3.5
801 Capitola Drive • Durham, North Carolina 27713 Printed: 15-37 09/12/1997
Phone:(919)544-5729 .Fax:(919)544-5491 ^
16 #
-------
Data File: /chwi/V,i/09-02-97,b/VG188.d
Date ; 02-SEP-97 10:39
Instrument : V.i
Sample ID : SBLK 082597
Column phase : DB-S
Volume Injected -
0.9-
0.8-
0.7-
0.6-
0.5-
0.4-
0.3-
0.2-
1
0.1-
Li
3
/chem/V.t/09-02-97.b/VG188.d (Part 1 of 2>
W,
-r-r
5
t
&
1
9 10
Time (mlrt.)
ijm [ urn ltytltytlfJI[-i
11
-------
Data File: /che«/V.l/09-02-97.b/VG188.d
Date : 02-SEP-97 10:39
Instrument | V.I
Sample ID : SBIK 082597
Column phase : DB-5
Volume Injected
2.1*:
2.0-
1.9:
1.8-i
1.7:
1,6:
o
1.5
1.4
1.3
0.9:
0.8:
0.7
0.6-i
0,5:
0.4:
0.3:
0,2:
0.1:
|iip,
23 24
Time (rcln.)
0,0
-------
Data File: /chem/V.i/09-02-97.b/VG188.d
Report Date: 02-Sep-1997 11:23
Page 1
TRIANGLE LABORATORIES, INC.
Data file
Lab. Id.
Inj Date
Operator
Smp Info
Misc Info
Comment
Method
Meth Date
Cal Date
Als bottle
Dil Factor
Integrator
Sample Type
SEMI-VOLATILE QUANTITATION REPORT
/chem/V.i/09-02-97.b/VG188.d
42930B
02—SEP—97 10:39 Autotune Date: 03-Jul-
DD Inst ID: V.i
SBIiK 082597
¦97 12:11:
/chem/V.i/09-02-97.b/cclist.m
02-Sep-1997 08:14 target
02-SEP-1997 07:31
4
2.000
HP RTE
: AIR
cal File: VGi84.d
Target Version: Target 2.20
Compound Sublist: pah.sub
Compounds
WANT SIG
MASS
CONCENTRATIONS
ON-COLUMN FINAL
RT (REL RT) RESPONSE C ng) ( ug)
1 1,4-0ichlorobenzene-d4
2 NaphthaIene-d8
3 Acenaphthene-d10
4 Phenanthrerie-d10
5 Chrysene-d12
6 Perylene-d12
7 2-Fluorophenol
8 Phenol-d5
9 2-Chlorophenol-d4
10 1,2-Dfchlorobenzene-d4
11 Nitrobenzene-d5
12 1,3,5-Trichlorobeniene-d3
13 1,4-Dibrtxnobenzene-d4
14 2-Fluorobiphenyl
15 2,4,6-Tribromophenol
16 Anthracene-d10
17 Pyrene-d10
18 Terphenyl-d14
42 Naphthalene
46 2-Nethylnaphthalene
SO 2-Chloronaphthalene
56 Acenaphthylene
58 Acenaphthene
65 Fluorene
73 Phenanthrene
74 Anthracene
77 Fluoranthene
78 Pyrene
83 Benzo(a)anthracene
84 Chrysene
86 Bemo(b)f luoranthene
152.00
136.00
164.00
188.00
240.00
264.00
Compound
99.00
Compound
Compowd
82.00
185.00
240.00
172.00
329.80
188.00
212.00
Compound
128.00
Compound
Compound
Compound
Compound
Compound
Compound
Compound
Compound
Compouid
Compound
Compound
Compound
8.090(1.000)
10.548(1.000)
14.072(1.000)
17.070(1.000)
22.439(1.000)
25.348(1.000)
Not Detected.
7.510(0.928)
Not Detected.
Not Detected.
9.158(0.868)
9.818(0.931)
10.655(1.317)
12.778(0.908)
15.678(1.114)
17.191(1.007)
19.935(0.888)
Not Detected.
10.584(1.003)
Not Detected.
Not Detected.
Not Detected.
Not Detected.
Not Detected.
Not Detected.
Not Detected.
Not Detected.
Not Detected.
Not Detected.
Not Detected.
Not Detected.
259476
861412
551060
976291
617028
556414
340502
223410
195811
260900
466686
192255
948522
975243
143145
40.00
40.00
40.00
40.00
40.00
40.00
31.06
28.76
23.41
37.88
28.05
45.06
36.04
52.35
6.20
62.11
57.51
46.82
75.76
56.09
90.12
72.08
104.69
12.39(a)
Data Review: (PaB
Date;
170
-------
Data File: /chem/V.i/09-02-97.b/VG188.d
Report Date; 02-Sep-1997 11:23
Page 2
CONCENTRATIONS
OUANT SIG ON-COLUMN FINAL
Compounds MASS RT CREL RT) RESPONSE ( ng) < ufl)
87 BenzoClOf Luortmthene
Compound
Not
Detected.
88 Benzo(e)pyrene
Conpound
Not
Detected.
89 Bemo
-------
Data File: /chem/V.i/09-02-97.b/VG188.d
Date : 02-SEP-97 10:39
Instrument : V.i
Sample ID : SBLX 082597
Column phase : DB-5
Volume Injected (ti.) : 1.0
42 Naphthalene
Page 11
Column diameter : 0.32
I
I
I
Scan 1157 <10.584 min) of VG188.d
Hass 128.00
*3.0r
A
Scan 1157 <10.584 min) of VG188.d
-------
Triangle Laboratories of RTP, Inc.
Continuing Calibration Curve
CCAL File: VG184
Date of Analysis :09/02/97
Analyte List: PAH
ICAL File: ICALV616
Naphthalene-d8
I
Naphthalene
1.073
1.140
5.9
2-Methylnaphthalene
0.698
0.706
1.1
Acenaphthene-d 10
I
2-Chioronaphthalene
1.097
1.030
-6.5
Acenaphthylene
1.642
1.819
9.7
Acenaphthene
C
0.927
1.089
14.9
Fluorene
1.100
1.193
7.8
Phenanth rene-d 10
I
Phenanthrene
0.981
1.029
4.7
Anthracene
0.940
0.988
4.9
Fluoranthene
C
0.837
0.937
10.7
Chrysene-dl2
I
Pyrene
1.279
2.162
40.8
Benzo(a)anthracene
1.031
1.234
16.5
Chrysene
0.896
1.162
22.9
Perylene-dl2
I
Benzo(b)fluoranthene
1.062
1.160
8.4
Benzo( k)fluoranthene
1.035
1.110
6.8
Benzo(e)pyrene
1.033
0.961
-7.5
Benzo(a)pyrene
c
0.964
0.989
2.5
Perylene
0.974
0.848
-14.9
Indeno(l,23-cd)pyrene
0.906
0.978
7.4
Dibenz(a,h)anthracene
0.693
0.733
5.5
Benzo(g,h,i)perylene
0.797
0.880
9.4
Anthracene-dlO
s
1.078
0.826
-30.5
Pyrene-dlO
s
1.208
1.943
37.8
Approved by:.
CiA Date
• Fails QC Criteria for %D;«- Rfless than minimum QC RF;»- RF greater than maximum QC RF
Triangle Laboratories of RTP, Inc Savar v3.5
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 * Fax: (919) 544-5491
17
-------
Triangle Laboratories of RTP, Inc.
Initial Calibration Curve
ICAL File: ICALV616
Date of Analysis -.06/16/97
Analyte List: PAH
RF20 VF714
RF50 VF713
RF80 VF712
RF120 VF711
RF160 VF710
Rag ¦ RF20 RF50 RE80
Naphthalerie-d8
I
Naphthalene
1.226
1.158
1.069
1.135
1.110
1.140
5.2
2-Methylnaphthalene
0.756
0.715
0.661
0.707
0.690
0.706
5.0
Acenaphthene-d 10
I
2-Chloronaphthalene
1.104
1.039
0.977
1.030
0.998
1.030
4.7
Acenaphthyiene
1.977
1.841
1.735
1.801
1.744
1.819
5.4
Acenaphthene
C 1.170
1.107
1.060
1.077
1.032
1.089
4.8
Fluorene
1304
1203
1.128
1.183
1.147
1.193
5.7
Phenanthrene-dlO
I
Phenanthrene
1.132
1.042
0.979
1.010
0.985
1.029
6.1
Anthracene
1.058
1.007
0.950
0.983
0.943
0.988
4.7
Fluoranthene
C 1.053
0.996
0.909
0.905
0.823
0.937
9.5
Chrysene-dl2
I
Pyrene
2.186
2.061
2.070
2.288
2.204
2.162
4.4
Benzo(a)anthracene
1.295
1.225
1.200
1.237
1.216
1.234
2.9
Chrysene
1.219
1.181
1.092
1.175
1.143
1.162
4.1
Perylene-dl2
I
Benzo(b)fluoranthene
1.221
1.161
1.093
1.181
1.143
1.160
4.1
Benzo(k)fluoranthene
1.190
1.137
1.060
1.114
1.048
1.110
5.2
Benzo(e)pyrene
1.029
0.968
0.901
0.971
0.934
0.961
5.0
Benzo(a)pyrene
C 1.002
1.001
0.953
1.016
0.973
0.989
2.5
Perylene
0.870
0.844
0.812
0.869
0.844
0.848
2.8
Indeno( 1,2,3-cd )pyrene
0.896
0.995
0.950
1.033
1.017
0.978
5.7
Dib enz(a, h)anthracene
0.646
0.761
0.722
0.778
0.759
0.733
7.2
Benzo(g,h,i)perylene
0.826
0.878
0.849
0.927
0.919
0.880
4.9
Surrogate
i|gp£ ¦; V;; RF2G; RF50 RBiSO
RB120 R£!60 Mean %RSD
Anthracene-dlO
S 0.890
0.830
0.792
0.819
0.799
0.826
4.7
Pyrene-dlO
S 1.957
1.841
1.854
2.067
1.998
1.943
4.9
Approved by: _ QnS Date_fL/_i2./£l
*- Fails QC Criteria for %RSD;« - Rf less than minimum QC RF;»- RJF greater than maximum QC RF
Triangle Laboratories of RTP, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5779 • Fax: (919) 544r5491
Savar v3.5
174
-------
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Triangle Laboratories of RTP, Inc.
Continuing Calibration Curve
CCAL File: YP571
Date of Analysis :09/04/97
Analyte List: PAH
ICAL File: ICALY806
RF5Q RFMEAN
mm.
Naphthalene-d8
I
Naphthalene
0-919
1.104
16.8
2-Methylnaphthalene
0.638
0.718
11.1
Acenaphthene-dlO
I
2-Chloronaphthalene
1.067
1.121
4.8
Acenaphthvlene
1.670
1.860
10.2
Acenaphthene
C
0.928
1.060
12.5
Fluorene
1.111
1.226
9.4
Phenanthrene-dIO
I
Phenanthrene
1.058
1.173
9.8
Anthracene
0.984
1.139
13.6
Fluorantherte
C
0.892
1.132
21.2
Chrysene-dl2
I
Pyrene
1.433
1.475
2.8
Benzo(a)anthracene
1.049
1.257
16.5
Chrysene
0.917
1.216
24.6
Perylene-dl2
I
Benzo(b)fluoranthene
0.931
1.120
16.9
Benzo(k)fluoranthene
0.933
1.112
16.1
Benzo(e)pyrene
0.974
0.966
-0.8
Benzo(a)pyrene
C
0.894
1.056
153
Perylene
0.944
0.926
-1.9
Indeno(l,23-cd)pyrene
1.183
1.376
14.0
Dibenz(a,h)anthracene
0.856
1.088
21.3
Benzo(g,h,i)per\'lene
1.071
1.273
15.9
Anthracene-dlO
S
1.015
0.899
-12.9
Pyrene-dlO
S
1.351
1.221
-10.6
I
Approved by:.
.Date
£j12j32
*- Fails QC Criteria for %D;« - Rf less than minimum QC RF;»- RF greater than maximum QC RF
Triangle Laboratories of RTP, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3.5
175
-------
Triangle Laboratories of RTP, Inc.
Continuing Calibration Curve
CCAL File: YP589
Date of Analysis :09/05/97
Analyte List: PAH
ICAL File: ICALY806
Naphthalene-d8
i
Naphthalene
0.951
1.104
13.9
2-Methylnaphthalene
0.666
0.718
7.2
Acenaphthene-dlO
i
2-Chloronaphthalene
1.068
1.121
4.7
Acenaphthylene
1.597
1.860
14.1
Acenaphthene
c
0.918
1.060
13.4
Fluorene
1.056
1.226
13.9
Phenanthrene-d 10
I
Phenanthrene
1.052
1.173
10.3
Anthracene
0.960
1.139
15.7
Fluoranthene
c
0.858
1.132
24.2
Chrysene-dl2
I
Pyrene
1.433
1.475
2.8
Benzo(a)anthracene
1.023
1.257
18.6
Chrysene
0.983
1.216
19.2
Perylene-dl2
I
Benzo(b)fluoranthene
0.970
1.120
13.4
Benzo(k)fluoranthene
0.934
1.112
16.0
Benzo(e)pyrene
1.006
0.966
-4.1
Benzo(a)pyxene
c
0.911
1.056
13.7
Pervlene
0.964
0.926
-4.1
Indeno( 1,2,3-cd )pyrene
1.301
1.376
5.5
Dibenz(a,h)anthracene
0.976
1.088
10.3
Benzo(g,h,i)perylene
1.257
1.273
1.3
:;S«ri^pte
Anthracene-dlO
s
0.986
0.899
-9.7
Pyrene-dlO
s
1.293
1.221
-5.9
Approved by: (?gjR _ Date JL/JiL/Xl
*- Fails QC Criteria for %D;« - Rf less titan minimum QC RF; »- RF greater than maximum QC RF
Triangle Laboratories of RTP, Inc.
801 Capitola Drive • Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax: (919) 544-5491
Savar v3,S
175
-------
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Triangle Laboratories of RTP, Inc.
Initial Calibration Curve
ICAL File: ICALY806
Date of Analysis ;09/06/99
Analyte List: PAH
RF20 YP421
RF50 YP420
RF80 YP419
RF120 YP418
RF160 YP416
Analyte
Mag
RF20
RF50
RP80
RJbl20
RF16G MEAN
%RSD
Naphthalene-d8
I
Naphthalene
1.108
1.161
1.083
1.117
1.052
1.104
3.7
2-MethyLnaphthalene
0.716
0.772
0.706
0.716
0.683
0.718
4.6
Acenaphthene-d 10
I
2-Chloronaphthalene
1.086
1.157
1.102
1.177
1.083
1.121
3.8
Acenaphthylene
1.875
1.862
1.763
1.963
1.836
1.860
3.9
Acenaphthene
C
1.065
1.095
0.991
1.124
1.025
1.060
5.0
Fluorene
1.243
1.295
1.113
1.312
1.165
1.226
6.9
Phenanthrene-dlO
I
Phenanthrene
1.180
1.251
1.102
1.200
1.131
1.173
5.0
Anthracene
1.104
1.191
1.120
1.200
1.079
1.139
4.7
Fluoranthene
c
1.012
1.041
1.040
1.275
1.294
1.132
12.3
Chrysene-dl2
I
Pyrene
1.721
1.808
1.441
1.185
1.221
1.475
19.2
Benzo(a)anthracene
1.280
1.302
1.203
1.223
1.274
1.257
3.3
Chrysene
1.189
1.250
1.148
1.207
1.287
1.216
4.4
Perylene-dl2
I
Benzo(b)fluoranthene
1.103
1.148
1.055
1.166
1.130
1.120
3.9
Benzo(k)fluoranthene
1.124
1.133
1.037
1.131
1.134
1.112
3.8
Benzo(e)pyrene
0.976
0.979
0.912
0.969
0.996
0.966
3.3
Benzo{a)pyrene
c
1.020
1.075
0.993
1.085
1.108
1.056
4.5
Perylene
0.925
0.921
0.890
0.955
0.939
0.926
2.6
Indeno(l,23-cd)pyrene
1.119
1.475
1.393
1.447
1.449
1.376
10.7
Dibenz(a,h)anthracene
0.991
1.098
1.078
1.134
1.137
1.088
5.5
Benzo(g,h,i)perylene
1.238
1.313
1.248
1.283
1.285
1.273
2.4
Anthracene-dlO
s
0.871
0.918
0.868
0.939
0.899
0.899
3.4
Pyrene-dlO
s
1374
1.460
1229
1.010
1.034
1.221
16.4
Approved by:.
.Date_fL/jLL/-5-?*
*- Fails QC Criteria for %RSD; « - Rf less than minimum QC RF;»- RF greater than maximum QC RF
Triangle Laboratories of RTP, Inc.
801 Capitola Drive * Durham, North Carolina 27713
Phone: (919) 544-5729 • Fax; (919) 544-5491
Savarv3,5
IT
------- |